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Areas
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L.
Ner*rrarr.
Focrl
llabits
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Year
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rrrn
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and,/\rrrbicnt'Areas
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'Cif
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l.ake,
Dennis
L . Ncr,anan and
Lance G. Per-ry,
DisLrillutional
Ecology
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RelaLive
Alruntiorrce
of
Icht,hyop'lankton.
Dennis
L.
Nerrrnan
Abunrlance
of Littoral
Fish
Larvae in
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as' Deterrni
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t)y
Li
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l-arrce
G. nerry,
ImpingernenL
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'[Jennis L,
Newnan.,
Species
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AburrcJance,
trntl
r)istribuLion
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Lake
F
j
shes.
Lallcc G.
Per
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John
A.
Tranquilli.
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.
Standing Crop
Estimates
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Lance
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[-drrll.l.Coutant,
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fJenthic
Invest'igations
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Gary
t..
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and
Jarnes H. fJuckl
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leilrn
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bioloqists
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in
tlte ,lrr)fls
of
w,il-cr
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clri,rni,-,ll
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A
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annrtal rellort
encompassed daLa
collecLed f rorn
Cotfecn
Lakc
tlrrouglr
Ju
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l9B0
a,rrj
I
rrdcs
a Lltr'L)e
-yLrdr
biological
analysis of
Coffeen
Lake anrl resulls
of a
one-yedr
invcsl.igation
of
Shoal Cr.eek,
its:
receivinq strcarn,
,
Ouring the
second
yedr
of
sl-trdy,
a I
-yearr:
irnpingement and
entrainment
prc.ject
and a
l
arval { ish rlisLr:illution
sLucly
were
-
aclded
bo the
sarnpling
progranr
to
assess
the irnp6sL
of
t,lrc
cool
ing
wdLer
inLake
system
on the Coffeen'Lake
f
ishery.
Reglorbs
on
Llrese
inves:tiqat.ions
ar.e
inc-lurJecl herejn. Data appendices
were
inclutJecl
wiLh
t,he
Lwo
previols
anrrual
reports,i
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data
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previously
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is
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in
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,:'
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i
utl li?ltL-Colorerl
9{}il5
rtCvq'l
ripr:rl
fr+,r
l.}rii.
jhrl
li+q:n,:r-=Et:t.y:'.t{lrr
riiil
l
iCSOC
i
al iOn f
OUnrJ tltgre
f
grrreCt
ljridef
fs;r:*ll,
vt.lt!-nt
iBrr
,rnrl il..{rJr'i
Crl
rtr},li
l_r'
leve!
t.r slrongly
5lcpinq lplnnds
ii:ehr-*r:hachr:r
ei
,ri.
lq6l).
:
.
{lof
fr.:en
Lak+: is
d
relativr:ly
{leep
irnporlc,trnenl in
cq,nFaris{jil L*
uther-
!!lirroi.,
i^Lrsf!'voir's.
The f,?4
ilqiitd,
lglBD)'
I irferl
sr:lee
terl
p.lrdrreL,:rs
for,
353 lliinli..
lakCS ,ind
|'Clt0rtrl/l IltaL
Cilffrtfrr
lrarl
,'|
qr'rtdttr
rnrarr
dr:1rth
(ti.i.'r
)
.inrl
;1,11jr11,rr
ilr,'llt.it
(
l/,7
,'r)
[ir.rn
95
p,trcent
nf
Llrt-, lakes
latlrlial.r]rj.
'j
rr,l
l
ikri
.r'l
sri
rra,i ,r
relative!y lriqlr
volrJrnc
dfvelopillcnt
raLio
(0,g/)
..lrl(l
nr,
rjr.Lcrlsivr:
slrorel
ir-rr.:
(7/.1
knr).
The
coal-fired Coffeen P0wer
St,rLion
cornple.t is
located;rrljacrlnL
Lrt,rrrr!
rrbtrrjns,
'ntsL
of
iLs ftrel
(lto.
6
ller,'n)
frorrr
ConsolidaLc<i
Hillsboro
Coal
eo,npanys,
undergroun(l
coal rnine. The first
of
Lwo
units
aL thc'Coffeen
Power
SLaLiorr
hegan
operation
in
1965.
UniL
I
has
a
gencrnLing
capacity
of 350
t'let;
wilr
an
rlsSociat.erl
circrtlating
water
purnp
disclrarge
0f 146,500
qpr4,
lJniL
2, which
heqarr
electric
generalion
in
1972,
provirles
595
l'le|.l
and hds,t
circulat.irrq
wat.cr
pullp
discharrle
of 253,000
gprn.
These
Lwo
units,_!$e,l
on,a
70
percent
loacl
factor,
have a maximum
heat rejection
o(4.36
.-.-.-...
BTU hr-l alnd
establ ish
<tr't rrvcrdQe
lZ"
C
ri
se in vlater
temperature
across-
n50rs.
gno
esLaDtlsh
art rtvcrdQe
lz-
,ors.
The
therrnal
effluent
leaves
I
I
I
I
I
I
I
T
T
I
I
l-
t
I
T
.r,he
g-enetating
f
acility
via a
0.9-km-long
discharge
canal
and'enters.Cof
feerr
l-ake by
flowing
over
a hot darn.
The discharge
t,lrcn
tollols
a
clockrvise
paLtern
:
-:
",
:
:
'.alon,
a
6.6-km cooling loop.
151s,'-provides
324 ha of
c0oling
area
(73'per.cen1
,'
l
:
'
,:
t,
,.of
th9.,l.gkp surface)
and
produces
a
total
'lake
loacling
raLe
of
0.86
Mer.t
r"ro-1
i
CTLI'E
^
:,:
,,,i
t
',
'
fr|
'
:jr:
:.
.:.::
t.
",',
':
,t,
l'
l'
-,,
l=
l,'.,-,,,
-':.'
!..,.,,:
..;.:,':
,,';:
,,.
::
':|
j.
l''-
....
.
:
I
.:.
T
,l-''
'
,1,''"t-',"'
i,-
,l
,";.
Tallle
l,l, Physical
tharacteristics
of
Cr:f
feen
Lake
1,,'
l'-
Surface
areal
llean
dept
h:
l,lax
i
mum
depth
;
ShoreI ine
Iength:
Storaqe
capaclty:
l,latershed
dra i nage:
Bottom
slope rndex
Shorel
i ne developrnent
i
nrJex
0rainage
area/lake
capaciLy ratio
Annual
loss in
capaci
ty:
Volume
develormerrt
index
446 ha
5.7
m
l't
,7
n
71. I
km
2,7? x
107
rn3
.4,q5
x
l03'ha
.3206
:
10,6
,6
.05
percent'
,97
l.:
I.:
I:
1,,
-..
i
',
l'.,',r,',
I:"
:'
;
r
I.:
I
:i
r..-
1,..'',
;:'
l
^r.\)
[r'
\J
"::t:i..
..
.
.::
,
aaa
:.:
,:.
::;:::.',
_t'
1.3
I
I
t
I
',1
I
I
T
I
I
I
t
I
I
ti::_:
:
z:
=,
::!
:
a::r'
:':,,
a:a
.
a::i
i!:':
='':':
aa:'
::.'
-,'a
:::
\-.
-:::.
':
.:..
:?::
l:.
aa
:::-.
i:'
='
,:.:
::
l::,,
:i:l
:-:
:
:.
:
:r,'
6ross
electrical'output
of ilre
Coff
een
6eneratiqq
.rt
ii.i{.tn i{n!;
luite
tdr.iaiilr:
(Fig.
l,l)
as
is
typical
0f rnost
c0dl-f irerj
units.
[\rr'i4r3
thr] nrrrtht
iyf
;igrr'ri,
May,
November
and
0ecclnber
of
l9/9
and i980,
oulprit-
itis reiliic{.j(1
hrc
t,rsrl
,ri
scheduled
maintenance,tnd
repair
work
at thc
power-
planl.
Sirrc.c
the
enset cf
this
studyr
max{rnum
stimrner
and
wirtter
rt isclrarr;e
Lemper-,tl.rrr'f:s,
oij(t1,lre11
at
the
enrJof'nu.*'Xingzone';:ii'1:',..io?6'crrC5PeCLive]y,
Several
Inodif
ications
of
:ilastewaler'
treatment
f
aciliLies
aL the
pow,..:t.
sLaticn
were
conlDleted
after
this
environmental
study
began.
lnclurJed
were
isolation
of
aslt
disposal
prntts
frorn
the
lake
basin
{completerJ
in
Auqusl
lgTg),
consLr.ucLion
of a
settlirrg
basin for
coal
pile
run-off
(conrpleLed
in
February
l97g),
ancl
construction
of,an
equalization
tank
for
rnixing
of
brine
anrt
rlernineralizer
wasLe
products
(Fig..l.2).
These facilities
served
to l)
pievent
ash
pon<1
effluents
fro'n
entering
the
lake,
2)
prevenb
coal
pile
frartictrlates
f1616
1-'1lg1.inq
ilrtr
lake,
and
i) buffer
brine
and
demineral:izer
wastes
(a
soldtio,r
of brinp
sttlfuric
acirJ,
and
s0diun hyrtt'oxicla)
from
pll
extremes
prior
Lo relrlt'tsr,
inlr:
tht
lake,
Fottr rnajor
satnpl
ing
stations
were
estdbi
ished t.o represent
arc.1s
(-)xposcrl
to
various
therrnal
regimes
and
were
sampled
by
all invesLigators.
Stdtion
I
was
Iocatecl
irr the
thermal
clischarge
aril,
Station
2 was
established
near
the
midpoint
of
the
cooling
loop,'station
3
was
situatecl
norlh
of the
intake
hay
as
a
thermal
transition
area,
and
Station
4
(which
was
partially
isolated
frcrn
lhe
rest
of the
Iake
by a raiIroacl
causeway)
was
regardcrl
as
ilre
ambient
area.
Approxirnate
djstances from
the
thermal
outfalI
to
stations
i
throuqh
4,
respectiveiy,
were
0.8, 4.0,
6.9,
and
8.4
Km.
In
aclditiorr,
ancillary
staLjons
for
certain
aspects
of the
strtdy were
located
near the
inLake
ancl
rtisclarge
structures,
at two
other
interrnediate
points
witlrin
tlre
cooling
loop,
ancl
at
thc
north
end
of
the
lake
where McDavid Rranch
enters
the lake
llasin
(Figure
l.Z),
I
I
I
I
a.a.
-1,
.|,.4
:-'
,,
-:.
t:.
I
1.
{J
^
tp
v)
Uqr
c)d
F1
Qt.
r-t
L:
fiq)
at
0r
")
c)
.i
qJ
ti
t
ol)
i
,a.;:,.
I
,r.1,.
I
.l
I
I
I
.
I
I
t,'
I
-
I
,.
!
I
I
I
I
I
I
I
I.
fum Infloxing
Strearn
t
t
I
I
I
t
I
I
I
I
I
I
I
I
I
I
I
I
I
Coffeen
Loke
I
too
looo
M.t. r
I
11"--..-.:
N
t
tt..
\
L,
=
Moior Sompling
Srorion
Last
Arm
'
Inflowing
Stre;un
Slag
,
Pnnrl
Yhormo
I
Outflow3
3i,l;t""'
:r
loperation
2op;udi;,t
3operation
ceased Feb.,
Degan I.eD.,
..
ceased
Aug.,
1979
r979.
i
t979
Sanrpl
ing
s ta
tions
on Co f f een
I,ake.
]:
::t.
.
::.4'.,
.:
,l
.
llr
,1..
v
F:"gure
1;2
''.t
'
'
[_J:
Ancillory Sompling
Srorion
--
::I
f:
,I
:-
:I
::
.
LITIRAIURTCIII.O
Central
Coffeen
Illinoia
Power
Public
Station
Service
Urtits
Company,
r
iriJ"i,
197l.
'iuoniifoo'to
Thermal
Denronstralon
f0r
ure
iiitnoii
poiiurion
Control
Board, Ma-v
1927.
.
Fehrenbach€f1.,1.
?.r-!r
0,
l.latker,
anrl ll,
L,
l.tascher.
1967. sails
of
Illinois.
':'Unlversityof
'47
pp
Illinois
Agricultural
,[xper.i'neni
Srution.
grii.ti"
ji;','-'
Il
linois,Environmental
Protection
Agency,
l97Ba.
AssessrnenL
and
Cl assification
of
Illinois
Lakes,
Vorume
I.
208 witer
Quat
iry
raan.gur.nf-pi;;;i;s
p;;;;:;,n
,
,!tafr
!gpirrt.
state
of
Il linois,
tnvironmentai
proriirion
ngency,
Spr
i ngf
iel
d,
I
I
I
ino.is
.
Il
I
inois
of
Il
Environmental
linois
Lakes,
Protectiorr
v0lume
l
l.
Agrncy,
"zgg.Hater
l97Bb.
Qualiiy
Assessment
i,lanagement
anrl
planning
Cl assification
frogral.Staff
Report.
state
or
ir
t inois,-E;;ii6nmentit
prorection
Agescy,
Springfield,
Ill inois.
Il
linois
Natural
History
Suryey,
1glg,
[nvironrnental
Studies
of
Coffeen
Lake.
'First
Iext;
Annuat
Vol.
I
I,
Report
Appendices
to
centrat
Illinois
public
Service
ccn[int;
1l;;.'';;"'
Lopinot,
DepartnentofConservation,Springlietd,.IIljnois..}l9pp;
A.-
c..
l?79., r,lontgornery
county
surface
water
resou.css'.
Iilinois
Schweqman,
'J.^E..
19i3.
Comprehensive plan
for
the
Il
I inois
l,lature
preserv,ls
System,
Part
2.
Tlte
Natural
Divisions
of Illinois.
lllino'is
Natu;e
.'-
Preser"ves
Conmi
ss ion.
32
pp
.l
;l
I
ll
,l
aa
.'
I
I
..
ti:.-
.:
:.:.'
:.
::-;.:,
:.'
):"
1:
:
,.
t
.
.t
:
..:
i.i.
a
::
'
.
,':':
'':
'
,:::
"'
.:l,
:.
::rr
.
,.-:
ii.'..
'
,..:t=
.,:...-
.-:
Ii ,.
l'':
..'
:
5Ecil0lf
?
,
:
I
TlttRi4AL
--
--
I'tApptHG
"
0F
C0rrttfi L&ri[
a
:
:
Sarah
t.iehr-Storck
ABSTRAC
I
.
''
Thermal
mappino
was
conductert,q'larlerly
at
Cof
feen
Lrke
dtlring
the
period
f rom
september
l9/B through
Sepiemoer 1979,
and
semi-drflrrdlly during
the two
fol
lowing
years.
Little variation
was
found in
surfdce ternperotures melsurerj
{lcross
transects
located at known
rJistances
from
the discharge.
The only
rnajcr
exception
occurred in
l'larch
l9B0 and
February
lg8l when the thernal
plume
stayed,
close
to
the
east bank north
of
the
darn f
or a
rlistance
of
l.0
to L5 ki lomer-ers.
'\++:5'1-:1l#-+:-*+E4
The
dischargc'
arm
of
the
'!rke
usual
ly had
dif
ferent
vert
ical
ternperature
distributions.
:4u1t.r
!.[rgn
!he-1g$-*of-.-tne
lake,
with
a distincI
change occurring
in
Lhe
vicinity
of t\q!U.
.'r*-
lhe
rJischarge
arm
of
the
iake'-ien,ieA
ts
itay
tfiFrmilly-
stratifieC'at'a
depth
of
about
tro
meters,
with
much
warnrer
water in the
top
layer.
In
the
vicinity
of the
,.''
clarn,
greater
rrixing
and
larqer
water
v0lume
c-qused a distinct decrease in
surf ac6-watei
ternperaturas.
rrJater
temperatures in
the
---*
cooling loop diti not
vary
greatly
between
the
dam
an<J
the
intake
canal
cove.
A
distinct decrease in
temperature
occurred
at the railroad
causeway!
inJlcating-
that
water temperatutes
north
of
the 19!lroarl
causeway
were
not
6ffs61ed oy
the
--'
-'-----:.-------'--
'--''..=.
thermal
discharqe
!o
the
sarlg_extent
as
_w_a-t*er ,t,empgratures
souilr
of the
l4q:91g..
Vertica'l
temperattre
distributions
did not
correspond
to
normal
,.
stratification
patterns.
thermal
discharges
prerented
winter
stratification,
and
ice formation
except for the
area north
of the railroarl
causeway.
Both
winter
temperatures and summer hypolimnetic.temperatures
were
hiqhcr
than
norrnal in
the
iower
region
of
the
lake,
possibly
allowing
greater,bacterial
activity
anrt
thus
'
greater
rates
of
cyclinq
of
nutrients
and other mlnerals.
!n the sLtmftre!"
neii)
,
the dam,
rather than
the
normal
situatlon
of
two
isotheimal layers
of
water
ttt
separated
by
a
therrnocline',
ihere were three isotherrnal
layers
separated fry
tw{
\
.
.:...
thermocl
:.:.
ines.:
j
The
to_p,.layerr.r:eq.g,]:ted,frq-nr
,
;.
,..:,,t
tt
'-
warr,ri'water
fr:bm the'discharge
arnr
/
.:
.
t/
stayingonthesurfacer.ttherthaImjxing...
,:
l,,t
l,i
:!
'.
:
Ctl
I
I
I
rli
!\';lrj
il{In00tJcr
tOti
blater
temperature
is
an
irnportant
p0rdmeter
af f
r:ctin,J
l,rke.,
bcr.,rusrr
i
i
infltlences
not
only their
phyrical
characterisLics,
but rt\0
!.h4ir
r.ricmical lnrl
biological
choracteristics.
Becarrse
differenr.
i:larit
and
lni{ral
species
have
dif ferent
temperature
tolerance
I imits
anrl
Itrnperdture
optima, tcmperdl(rrc
citrl
af
fect
'the
biota
directly
by l imiting
tlre
rJistribulion
of species
or
by
dctermininq
the
species
composition
of
cofimunities.
Temperalure
also affec.ts
tlte rete
of
biological
activities,
and lhus
dlfects factor^s
srtch
as
growth,
deconipositiort,
oxygen
consunption
and
evolution, anrl
nutrient
and other
nrinrlral
cycl ing thaf
delermine
the
biological
clraracteristics
of
a lake.
Also,
becausq
of
the relatianstrip
betwer:n
water
ternperature
arrd r!ensity,
tenperature
distribution
deterrniles.
circulation
poiiurnr,
anrl thrrt
o^yn*n
levr,ls, in
parts
of
the
lake
whicn
rneli
restrict
anirnal
l,ife
anrl alter bacteriol
,ictivity,
:.;
:
.,:
-TItt;rcfo5e,'a
tltorough
understanding
of
teinpera',lure
dist.r'ibut,iorr
is
essenlial lo
assessinq
the impact.
of tlterrnal
ef
f luents
on
the
cherrrical
a*d
bioloqical
clraracteristics
of
a lake.
'
','
r1
,,.
",11
,.
',,.,,
,.
'
Cof
f een
Lake woulrl be
cxpected to
have
tI
i
f
ferent
tempr.'rature
patlr:rns
iltan
nost
lakes
in this
geographical
area because
ib
is
a
cooling
lake
which
cir.culates
I
arge
quant
i t ies
of water and receives
a' heaLetl
cffl uent.
Temperalur.e
distribtrtions
were
alstl
affectetl
by
climatological
events
anrt by
t)ower
plant
generation (Fiq.
l.l).
The
purpose
of
this
study
is
to
provirJe
backgrounrl
information
cn
annual ternperature
patterns
in
Coffeen
Lake so ihat the
chemical
;:j,:H:l;:r'
,".
can'be
interpreted in
the
conlexr
of rheir
rhermal
I
t
t
I
I
l
:::
-
i:,
:,::j-:
I
I
t
I
I
I
T
I
I
T
?-,2
::)!:-
'.:
.':-
-i.
I:rj
l,t'
,.3..
l,:..,
I.
l--t-
-a.-:,:
j,-..-
1,..
I,r:,
I,,,
:
i-i:::,:-
..t
;,r,1.:,
..
:,1:
t,.:
I:
I
,,:':
I"
--
,
I
I
lr,
'i
t'''
'-r.,
r.,
r...
-1',
glr:-:-:
I::
r.lAr[R
lA[S
AND r4tTr10i]S
Ihq
ther,mal
plume
wis
$easured
at:
qilarterly
intcrvals
dur^ing
the
f
irst
.r,ear
of
sampl'in13,
and at
semi -dnnual
interval
s
durinq
thc
secr.lnrt
,tnd
thirrl
years.
.Vertjibtit'proflles Here
measrrred
at
l-meter
depth
intervals
along
transects at
known
ttlstances
from the thermal
discharge,
Tt'o
to five
vertical
profiles
were
measure..J:
along
eachr
traniect,
depending
on
the
length of that transect.
Three
boats
Here
used
when
possible
to
complete
medsurements
over
the
entire
lake
in
as little
time
as possible,
Temperatures
werc medsurer,
with
YSI
r{odel
57
d i
sso I ved
oxygen and YS
I
l'lode
I
33
S-C-T
meters
.
i)rofiles
of temperature and
dissolved
0xygen
were
measured twice
per
rnonth
at
l<neter
rlepth intervals from
mid-lake locations
at
Stations
i, 1.5, 2, 2.5,3
anrl
4
(F'ig,
'1.2).
These
measurements
were
taken
with
a YSI
tlodel
57
dissolved
oxygen meter.
.:
'.'
,
Therrnal mapping data
col
lected,during
al I
three
years
of
,...
in Appendices to dnnual report.s
(Liehr
l9i9;
Liehr-Storck
lgBl
).
Ternperature
anrl dissolved
oxygen
profi
le data
are
,
Appendices to these'reports
..I.
TEMPERATURE DII-FERENCTSACROSS IRAf{STCTS
ln
general,
very 1 ittle variation in
temperature
occurred
linking one
side of
the
lake
with
the
other.
There were
1,1.,.'
I
ake, however,
where
sorne dif ferences were observed.
tlris
ttudy
can be found
1980;
Li ehr-Storck
also
listed
in
across t
rarlsects
two
locations
irr the
In
the'main
arm
of
the
lake,
temperatures
were substantially
higher
along-the
east bank on
the
dates of 4
lllarch
'1930
and
16
February
l9t]1 .
The
clif
ference
in
surface
temperatures
between the.east
and west hanks
just
north
of the,dam
was
6.7,'C
'oir;
4
tlarch
lgB0land
5.4?C on
l6
February:
l9Bl
. Temperatures
remainert
,-.1
a,,:::,-.:..
:..::::.':t'r.:
2.3
dif
ferent
for,,
a.
distance
of
1.0
to-
1.5
kilornetr:rs.
i,linds
were
f
airly
stronq on
both
of
these
sampling clays
at
alrout
l0implr f
rorn
thr:
touth anr, sou1rrwcst,
llowever,
strong
iinrJs f rom the
'soutlr
and
soublrwest were
also
presenL
orr:olher
days that
thermal
rnapping
qreasurements
were taken,
and
thesr,
large
lempcrature
rtlfferences
were'
n0t
observerj.
A
much
less
pt'onounced
difference.,in
temperaturc
across a
lakcwide
Lransect
occurred
just
north of
the rai
lroad
causeway.
Tcmperatures
were
sl
ightly
higher
in
the
middle'of
the
transect'on
z0
November
l978
and l6 February 1981.
Slightly
higher temperatures
were
observed
on
thc
east sicle
of the
transect
on
B Augttst
l979,and
22
August
1980,
0peninqs
(culverts)
are locate<J in
ilre middle
and on the
east
side
of the
railroacl
causeway,
and these temperature
variaIions
may be the
result
of
water movement
through
these
culverts.
Again,
wind rtaLa
were inconclusive
as
a causative
agent,
since this
phenomenon
ylas
not always
observetl
under
s imi I ar
wi nd
cond
i
t i
ons
. If w,iter
exchange
was
occurr i,rg
ilrrouqh
the
culverts,
hoi{ever,
it
was
either
at
a
very
slow rate,
0F rnixing
was r-apid
ly
occurring,
as temperature
clifferences
were difficult
to
detect.
TEI.IPIiRATURE
DIFFERENCES
|.lITH DISTANCE
FROM
DISCI{ARGE
Since temperatures
were
fairly
uniform
across transects,
mean
ternperatures
at
0,
2,5,
l0
and l5
meter
depth
intervals
were
calculaterl
Lo
observe
seasonal
patterns
of distributjon
of waste
heat
with
depth
and
rlislance
from
the
di scharge.:
,
femperature di
stribution
i
n
the
summer
season
was notably
di fferent
fromtherntaldistributionjnthewinterseason.i
Thermal
mappings
comp'letect
on l2'september
1978,
B
August
1979,
ancl
22
August
l9B0 indicated that temperature
djstributions
were
simi lar
during
the
hottest
times
of
the
year (Fig.
2.1).
Thermal
stratification
(a
barrier
to rnixing
as
defined
on
paqe
2.8) occurred at,a deptlr
of about
two
meters
in the
area
of the
lake
between the
discharge
and
the.dam.
Stratification
at nine
to ten
meters
occurred
at
locations in the lake that
were at least
ten
meters
deep. The
temperature in
the top
two
meters
of
the
water
column decreasecl gradually
thrbughout the lelgth
of the discharge arm.
A
more
drarnatic
decrease
in
2.4
T
I
I
I
I
t
I
I
I
I
I
I
:l
.l
'l
'
::.:t;
t
l
25
eo
t!
o
F
(D
E
trl
o
I
L,l
F
c
ul
ul
G|
DlSTAllcE
FRoM
DIS0HARGE
(
xu
)
SURFTC€
2
r€rEFS
3
ETERS
IO
I'€TEFEI
It
TETERS
Lake
in
relation
to
:
I2
September 1978,
,
ol
F
:Ct
F-
6
^
(t
I-'
f
I
o
lrJ
E
f,
F
c
(L
lrl
l!
>
F.
q,
o
O)
F
o
ct
)
3
N
o,
Figure
l
,''''
Temperature
di.strlbutlon
in Coffeen
depth and dlstance from discharge on
8
August 1979, and 22 August 1980.
2.5
ffi'''-
ffi.-''
kl:
:
F''
H:,
Fir
lTli:
FJ
ffi:';.
si:.,
li:,
#t'
Fi,.
k;..
f;:
Fi.''.'
b:t:::
:: :
::>t.-r
:'
fi:::;:::: *
i.li:
.,,
f:-i''.:'.:,
F:'::1:
..:
[i:'ir'
-
'
ili
i,.':.:
.'''
,:
Ii:1,
'
..
'F1r;1;1',,.,'
tj):.:: .
.
.
"il:'i.,,1,
ff:.::l
' :
-l.';:,,-'''
!':-::,
:
:;:..:.,-'
;iir.
'
.1
i'li-
i;:r;:,;:
,
i!,:'.",t.,,
fti,,,:-
i1.:.
.
''",
.
f..'.'-
'
';:.1;,;.,:'.
,
l.lt,:.::,"
'
"?i.,,
lilo',:,:;;,'
+1.,-,
;j-,,':.:
J
rr"
:
')
i',tt,''-
:i:l:.:
:.':'
:'
;{j::::::i.
' :
'i7'):tt:.-
6l:;r:l;..,.
!i
l
7:;::'.:.
'
ii'"
';:,
!i::
t.
'.'-
.l
It::
'
i,
'-:
*-i*.
''l
i:::::
"
:'
i:i;'.: ,
temperature
occurred
at the
darn (except
on
Z?
Augrlst
l9B0
when
planL
gener,rtion
was
reduced)
followed
by
only
slight decreases
in
water
ternperalure
nlong
llic
retnaining
length
of Ltte
cool
ing loop.
Tenrperatrrres
dccreasert
nore rapidly
in
the'area
of the
lake
rreyoird
the
intake
cove,
arlrl then
a rapid:dc,cline
occurrcd
at,the
rai
lr:oarJ
causeway.
t.later,
temperatures
al f
ive
anrl
Len
rnelcr
rjeoLhs
did
not,change
fiuch along
the
coolinq
loop
or heyond
to the railrcart
cduseway.
The
winter
therrnal
'nappings
also
showed
simi
lar
temperatur.e
distriLru.r.ions
(Fig.
?-.2).
Data
frorn
B
March
I979
were
not included
liecause
the
l)ower
plant
was n0l
operatinq
on that date.
Thermal
stratificalion
occrrrred
at a
Cepth
of
one,to
two'meters
in the
area
of the
Iake between
the
rJischarge
antJ
the
:
spilluray,
with temperatu,res
in the
top two
meters
aqain
decreasing
qr.ariual)y
with increasinq
distance
from
the
discharge point.
A-." the
spil
lway,
.lrowever,
a
very
rapid.'temperatttre
drop
occurred.
During
winter,
the
resl
of
the lake
was
not stratif
ied,
and
surf
ace
ternperatures
decreased
onl-y
slighily
within
Lhe
remaincler
of the
cooling
loop.
0ther
temperature
difierences
occurr.erj
at
the
intake
cove
and
at the
railroad
causeway.
!Jater
ternperaturcs
at five
and ten
meter
depths
increased
in the
reqion
of the lake
between
the
spillway
arrl the
intake
cove
as
a
result
of
more
even
winter
verLical
dist,ribuLion
of heat
thruughout
the
water column
in
areas
beyond
the
rJischarge
arnr.
ldater
t.
ternperatures
:
that
were
2 to
3"C
cooler
were
found
at the
rajlroad
-
causeway
at
'6'11
times
that
rneasurements
were taken
beyond
that'st/uctur:e
excepL
22 August
l9B0
when
the
decrease
llas
only
about
l"C.
These
data
inclicai,ecl
that
the
rnixing
of
w.ater fr"orn tlre.north,and
south sides'of
the:causelay
was
considerably
slowed,
anc
that
the
portion
of the
lake
on the
north
side
of the
causeway
was
noliceably
Iess
impacted
by
thermal
effluents from
the
power
plant
than
was
the
por:tion,.of..thelakeonthesouthside...:
THERMAL STRATIF
ICATION
.
Aphysical.qropertyofwateristhatits.densityincreaseswithc|ecr.easing
ternperatures
(to
a
ternperature
of
4'C).
Because
of
this
property,
Iakes
Seconre
stra.tif
!ed,,when
so11e
I
ayers
change temperature
,more
rapidly
than
other
layers.
ln,rcmpeiate.regiq'ns,
thi.s'phenomenon
is
a cornmon
occurrence
in most.lakes
'_l
...
I
t
I
,l
I
I
I
I
.l
I
I
.T
:
I
't,
:'
I
'1.
't
a:,
,:
"1.
2,6
''.
o
@
ol
!'
(J
q-r3
r::,
ct0
AO
()
,o
€
\
\
SPILLWAY
:
DISTANOE
FROM
suRt
cE
----2
fTETERS,
-'-i-r
-
'lO
IIETERS
89
IIIYAKE
RAILROAO
UJ
G
l
F
G
o-
ru6
=
Fg
c
l
e.
,@
tr.|
l!
@
30
23
t5
to
5
o
1,-r ;
..
.f'lgure
2.2.
DTscHAROE
(xu)
Temperature:distrlbutlon
:.':
.
.
in Coffeen
Lake in
relatton
to
depth"and
dLstance
f rorn dlscharge
on
/r
lrlarch''1980
and
16 February
1981.
:,';. . .
l,
.
ourln9
!he
surmer.
ond
winter,
A ternperature
drop
of 1.C
Der
nieler
rjr:pth
is
generdl
ly
cortsidered
to
cause
a
rjensiLy
qrarlienL
suf
f
ic'ienl
to
act
ds
o
bar.rier
to
mixing,
arrcl
will
herein
be
used
as the
rtef
iniI
ion
of
Lhe
rrn36l
qns.
Sincc
Cof
feen
Lake
is
subjected
to
temperature
jnf
luences
oilrer thr.)n
c.l
imorological
ones' i.e',
it
rcceives
---i.
--
a heated
efflrrent,
this
lake
would nof
be
expecle(t
Lo
stratify
in
t'he
same
patterns
as
other
lakes
in
tlre
same
geo!r-a0hical
area Lhat
are
subjected
to
only
climatological
influences.
Stratificaiicrn
patt.erns
were
studied
by
means
of
temperature
profiles
measured
twice
per
monLh.
Dissolved
oxygen
concentrations
were also
studied
to
help
determine
the
stability
of the
t.herrnal
strat
i
f ications
observed
Stratification
in
the
winter
norrnally,occurs
when
Lhe
water
cools lo
below
4"C.
i'Jater
at
4'C
has the greatest
density
and therefore
stays
aL
the
bottom
while
water
above
jt
continues
to
cool
until it
freezes
at
0.C.
tjn<Jer
the
ice,
biological processes
continue,
although
at
a reduced
rate,
and
oxygen
can
llccorne
depleted
since
there
is no
exchange
with the
atmosphere.
In
Coffeen
Lake,
this
type
of
stratification
rvas
observed
only
at Station
4, and
no
oxygen
depletion
was
observed
during
periods
of ice
cover.
Consistent
stralification
was
also
ob'served
in
winter
at
Station
I
at
a
aepth
of
one'tc
three
meters,
where
thermal
effluents
frorn
the
povrer
plant
caused
water at
the
surface
Lo
be
considerably
warmer than
water
at
the bottorn.
In
spite
of this
winter
st,ratification
P,*a.!tern
ilr
the
discharge
arm,
however,
dissolved
oxygen
levels
were
fairly
unifortn throughout
the
water
column.
The
water
colurnn at
the
oLher
statiorts
was
qeiteral
ly
cornp'letely
mixed
wjth'.temperatu'res
mosfly
in the
range
of
6 to
14.C.
anrl
oxygen
levels
in the
range
of B to l?.
nq/1.
The norrnal
process
of summer
stratification
begins
in the
spring
as the
ice
millts
and
the
water
warms.
l,lhen
the
temperature
reaches
4"C,
the
water
colurnn
coinpletely
,nixes
(spring
turnover).
l.larrning
c<lntinues
and the
cooler,
more
dense'water
stays:
at the
bottom
while
surface'temperatures
continue
to
rise.
A
thermo'ilihe
develops,
with
water abov'e
(epilimnion)
able to
mix
f'reely
causing
it
to
be fairly
uniform
in temperature.
The
water
below
(hypoljrnnion)
is
not
able
'
to
mix with the
upper layer,
and thus
receives
no
new
supplics
of
oxygen.
DegomRosition
of organic
material
at
the
bottom
of the
lake
consunes
oxygen,
anrl
t:1"
In
rnosE
''''
\
euEropnlc
lakes,
oxyqen
becomes
depleted.
2.8
l'
T
I
t
I
I
T
I.
t-
t
l'
,1''
.? ,
,
::
I
T
I
I
I
t
I
:1
I
Variatior;s
of
thls
typical
surnmer
therrnal
stratificaf
ion
pattern
were observerl
in
Coffeen
Lake.
The
water
column
at
Station
I
was
sLratified
!hroughout
the
Sunrner
at a depth
of one to
three
meters.
Iemperatures in the
uppcr layr:r of
water
were often
extremely
high
(once
reaching
43'C
in
l9B0),
because this
station
was located
close to
the
pohrer
plant
rlischarge.
r,.lhile
a thermocline
does
not
normally
appear
that close
to lhe
surface,
it
was likely caused
by
the
warm
wator
discharged
from
the
plant
tending
to
stay
at
the
surface,
Hypolimnetic
dissolved
oxygen concentrations
were
'low
(frequently
below
3
mg/l
)
but
oxyqen did
not
become depleterl.
0xygerr
in th€ lower layer
could
have been
present
as
a
result
of
unstable
stratification
orr
more likely, replacement of
the
water
caused by the
current
from the
discharge.
Station
2 was
stratified
from
May through
september
in 1929.
r,ro
stable
stratification
developed
in that
region during'1980.
At Station
2.5
there was
no con^r.inuous
stratif'cation
for extended
periods,
although thermocl ines did
appear
on occasions
in
the
summer.
Stratification ctid
not occur at a
consistent
depth'
but occurred
anywhere from three
to
eleven meters.
Oxygen depletion
occurred
at
Stations 2 anti
2.5
fro,n
June
to
September
in
1979 and from
llay to
August
in
1980,
inrljcating that
stratification,
though
unstable,
was sufficient
to
prevent
consistent
mix:ing
of the
entire
water column.
i
Station
1.5,'located
near the
dam,
was
adjacent to the
discharge
arm and was
also the
deepest
part
of the
lake.
Continuous
stratification
was observed
in
this region
from lrlay through
0ctober
of
both
1979
and 1980.
At
the
beginning
of
the
summer,
for example in l9B0
on
June
3,
the typical
seasonal
vertical
temperature
distribution
developed
(Fi
g.
2.3), althouqh
hypoiirnnetic
temperatures
were higher than
norrnal because
spring
circulation
had occurred
at
a
temperature
much
higher than
4'C.
ft
the
dgpth where
the
temperature
began
to
decrease
rapidly, dissolved oxygen levels
also began to
decline
rapidly.
As the
summer
progressed,
however, two thermoclines
developed.
0ne thermoc'line
at
a
,
rtepth
bf
bne'to three meters,
resulted
fiorn
heated water
from the
discharge
arm
staying on
the
surface rather
than mixing. The
other occurred
at a depth
of
,
seven
to
dleven
meter:s
(Fig.
2.3).
0xygen
was f airly.urriforrn
or increased
.',slightly
with
depth
in
the
upper
layer and
becarne
depleted in
the
lowest
layer.
l,
2.9
.
:.:
I
:,...,.
i.l
I
.:
I.
T
'l
I
:,l
,l
t
:iJ
c
0r:
c,l
:o
:
u
.rJ
Y{
:
crJ
.
@..
.o
o\
a.6
a
:oT{
:tgF
lFl
!
:(J
!JO
E.'
5c)
O,C
,o
rJg
u
'..1
L)
.F'.{
'oB
oIith
'u
Fi
..{
U,
:(!:.c
OIJ
l.t
:O.
ACJ
i
NAJ
O!
v(0
o
d
lFi
c'
'"o
.
o0:.tr
>'
X
"l
oq
,3
,aC
O
(0!.
:{
3'.'
F-'
,l{€
o(r'
.J
,q.|
:lJrJ
,
ts,tr
O.:k
eo
o0,
m
:
c'r
':
.
tU::.
F.
J
t*
(\l
o
a
c)
R
o
I
:t
=l
i
o
st
I
t,
F.
J
(9
=':
z
,o
(fi
) Hld30
Be!pen.the]tw-othermoclines,oxy9enrapidlydecreas€din.concentrationwith.i
:
r,
lncredsing
depth
but
did not
become
depleted,
whereas
ternperatures in
gris
zose
were
fairly
uniform
(Fig.
?.3).
Ihese
thrce
layers
of
[he lake,
which
wert,
partltioned
by
the
thermoclines,
possibly
did
not
mix rith
oach
other during
the
entire
sumnr,
Since
the
mi<Jdle
layer
was
at
least
partially
in
the
euphotic
zoner
oxygen
was
generatecl
by
algal
photosynthesis
thus
cornpensating
for
oxygen
consumed
by
organic
decomposition
arrd
preventing
oxygen
depletion,
Oxygen in
that
-:'
layer
might
also
have
been
present
as
a
result
of
occasional
mixing
with
the
upper
iayer
if instability
occurred
from
interruptions
in
power plent
gener
at
i
on .
.t::
l
a.:,
,::.
r-
ai:i:l
:,,:.
=:
:
::tti,';*,1
',
:.aa
::
.::',.:.,:::
2.t I
'a"
.:i:.
,
i't.'
r
r'l
,
,
:
L
lIi
RAIIJRE C I
IIt)
.,:
a:,
.
l
'
:
,i,i
Liehr, S.
19i9.
Thermal
mappi'tg.
In: J. A.
Tranquill
i
rrnd
R,
!i.
Larino''e
(eds,).
Envlrorlrnental
s'tudies oFCoffeen Lake:
'First
Annual
Repcrt
io
:.
-.
Central
Illinois
Public'ServiCe
Company, Illinois
Natural
tlisLory
Survey.,,
Liehr-Storck,
S.
1980.
lhermal
mrpping, In:
J.
A.
Tranqui I
]
i
and
lt. ll.
Lar imore
(eds.
).
[nvironmental studies-i-f Coffeerr
Laxe:
Second
A.nnual
::,Report
to
Central
Illinois lubli: Service
Company, I'llinois
l{atural.
Histor-y
Survev.
.:
l
--
-
-!
-1,
2.,12
il.
1I
,:l.i
7;i:,'
,
,
,,:=.
SECI l0ll
l
,IATIR
qUALtTY
0F
COf Fff.f{ LF,K[
l'',
by
Sarah
Liehr-Storck
ABS IRA{.7
llater
quality
was
studied in
Coffeen
Lake
from
August l9/0
throrrgh
Oecernber
1980.
Total dissolvect
sol
ids
ancl
sulfate
concentrat
ions
decreased
rluring
tire
.spring
flood
of 1979, and
then
qradually
increased
to the
end of
1980. The
.
total
arnount
of dissolved
solids
arrcl
sulfate
in the
lakc
also increased
frorn
,June
1979
to
December
1980.
Perior1ic
flushing
of water frorn
tne lake was
apparently
necessary to
maintain
c0nstant su'lfate
levels,
Aiknlinity increosed
from
l9't9
Lo
19u0,
providing
additiona'l
bcnef
icial brrf
f
ering capacity
against
pll
chan9es.Turbid.itywashiqhestatthenorthenc|ofthe]akeafLerper.iotJsoi
heavy
precipitation.
lhe
railroad
causeway
with
two
small
culverts through it
served as
a
barrier,
Ftrcventing
much of thc turbirJity
entering fronr
the
l
watershed at
the
upper
end
of
the
lake from reaching tire
lower
part.
of
the lake;
Totai
phosphorus
ievels
r.Jele general
ly highest in tlre upper
end of
the I
ake.
'
',.
Inorganic
nitr'ogen
c,onccntrations increaserj
<lramat
jcally
at al
I stations in late
1979
anrl I980.
The
greatest
increases
of
inorganic
rritrogerr
occurrer'l aL
,stations
nearest
the
pohen
plant
discharge,
and
r,orrnal
seasonal
nitrogen
cycles,
:,were
disrupted.
Chlorophyl
I g concentrations
were corrsistently
highost
at
the
north
end of
the
lake.above the
railroad
causeway and lowest in the
dischargc
drm. The
conclusion
that the
north
encl of
the
lake supportecl
greater
standing
'crops
of aigae
was
consistent
with
observations of higher
pH
value
ancl
greater
'sat,uration
of dissolverl
oxygen
there.
jlf'ecf--:Ipggi
glgaqer--A.Iaof-eff.Lreqt5-qr
l_
t.
Lowconcentrationsofdissolvedoxygen
were,observecl for
extendert
perjods
in
deeper
areas of
the
lake
during sumnter
rnonths.
0xygen
was depleted for
most
of
the sunmer throughout
extensive areas.
-of:the
lake
indicating eutrophic conclitioni.
In
wirrter,
cornplete
rnixing of
.rrrost
of
the.lake beyond the
discharge arm
prevented
oxygen
depletion frorn
occurrting.
3.r
I
I
I
I
I
I
I
T
I
t
T
I
I
I
I
::
:-:
ra:-::::'
't:::.
j.li'.:::
'i,:::=::
:-:t::l
1:::r:.
i'::.
=:
:.;:
:
:-
::
,ir:;t:,
;
t
r..a
.
!::
'.::..
i r:a:a..'
!::-::
t-'
:!-.1:t
t:i::::
-:
-- ra:
.:-,:
:
:.:::
,ri:
.
:.
I r{tR00ucT
t0N
The
water
qual
ity
invest
igation 'rras
undertaken
with
the
purpose
of
evaitrat
in,.;
brater quality
in
Coffeen
Lake after
the installation
of
net,r
HdsLervater
treatrnenL
-'iacil,itjes'at
the
po'ler
pldnt
dnd
with
more norndl
precipitation
patLerns.
, Tlr€:
investigation
included
(l)
monitoring
wdter
qudlity
param€ters
irr
th€
lake',anrl
:
determilring
the
cause
of changes,
and
(z)
determining
hovl
temperature
,,
distribution,resulting
from
the
discharge
of
a thermal
effluent
affecterl
waler"
qual
ity.
The
investiqation
includerl
studies
of circulation
patterns
in
the
lake,
cl
irnatological
events,
and
chemical
inpur-s
to
ilre
I
ake. These
claLa
were
used
to
assess
the
relative
impacts
of climatological
events and
plant
operation
on therlake,
and to
determine
hovJ
the
temperature
distribution
affected
mineral
cyclingandeutrophication.t.Jaterqualityparametersthataffectedthebiota
are.discussed
with
particular
reference
to affect.s
on
a)gal populations.'
",'
'l
.T
T
.
.'r.
I
-
:.:::
::.
:
.:
3,2
:::
l{A'i[,i
I
;115
Af{0
l.lf
Til0l,S
SAI4PL
IN6
SCIIEOIJLE
l'later
samplcs
were
coi
locted nronthly
at Staticns
l,
z, 3, anc 4
ar.
the top,
nidrJ
le,
antl b,ottom
of
'Lne
wdtu.
colri,nrl anrj
at StoLion 5,
Lhe
slag
ponrt
outf
low,
the
coal
pile
runoff,
the
c.ral
pile
runoff
seLtlinq
pond
ortfl6r1, tile
easL.lrin
inf
lowing
stream,
ancl the
west
arrn
inf
lo*ing
stream
(see
Fiq.
l,?).
Sampl
ing
.rL
the51agpondwas'discotltinuer|afteritwasa|ronr|onediliAugust1979.Ine
station
at
the coal
pile
runoff
was
changed
Lo the
settling
ltond
o,.rtf
low in
the
'ni'lrl
le
of
tha f irst
year
when
settl
rng
porrd
operation
begarr. Af
L,jr opr.:r.ttion
began,
direct runoff from
t.he
coal
pile
no
lonSer
ran into
Lhr.: lake.
SLrearns
f
lowing
into
the
east and
west
arns
of the
lake
were both
irrLerrnrltent.,
arril
ilrey
could
only
be
sampled
in
the
sprinq.
The following
pararneters
were
Ineflsured
d[
'nonLhly
irrtervals
f
rorn
AugusL lgZB
through
Decernber
1979:
turbirJity,
total
alkalinity, f
r-ee
carbon rlioxirle,
t0IA
hardrtess,
total
phosphorus,
soluble
orthophosphate!
arilnoni.l
,
nitrate,
niLrite,
total
iron,:soluble iron,
ferrous'jron,
sulfate,
sulf
itr?,
161sl
sulf irle,
dissolved
hydrogen sulfide, un-ionized
hydrogen
strlfirtc, clrlr)rirle,,tnrl
f
lrrorirje.
At
quarterly
intervals
water
samples
,,{ere
dlso analyzed
for
or
q.lnic
rriLrogen.
total
organic
carbon,
particulate
organic
carborr,
rJissolved
organic
cartron, and
clternical
oxygen
demand.
After
0ecemtrer
1979, fluoride,
sulfite, irqn forrns,
chernical oxygert demartd,
anrl
particulate
anrt
soluble
organic
carbo,r.leru,
elilninated
from
the
pararneter
I
ist.
Sulf ide forrns
were measured
only when
oxygen was depleted
in
the
hypolinnion.
Chlorophyll
g,
pheophytirr
g, and t,;tal
and
particulate
organic:carbon t{ere
measured
nronthly f rom
rlupl
icaLe
intr:oraLed
sar.nples
of
the eufiirot
ic
zonc at the f
our
iriaj0r
lake sLat
ions .rntJ
at the
i
ntake
of
tlre
power plant.
::..5
i.Il:
:'.'I,:
,.-
,.I.a
.
.,a
,l
Pr,of
i les of,,temperature,
dissolved
oxygen,
ald toLal rlissolvetl
solids
r+ere
rneasured
twice
monthly at
I<n
depth intervals
dL
Llte
four,najor
sLations
lnd
at
Stations
1.5
.:'
'and
2.5
(Fiq.
1.2). At the
s,rme tir€,
prt
wils
Inr-,(.tsi,red
at
Lhe
surf
ace,
rniddle,
and bottom
of
the
water
col
rlnn
at
those
st.aL ions.
.
1,'.:.
:.-::a:
. ,.,':.:,.,
a,
,.;.
.
.:.:--:.;.:.
3.3
::'
,
ti'
I
"jl":
"
'
.:.:
I
I
I
I
I
I-
I
T
I
t
I
,t,
.j.
I
I
:,
,.',,,'
I
,
'a.
I
T
.'a-='t;'a
3.4
:
Iahle
.l.l
I'l*thods
us{:d
to
trlnlyze
r:he;nical
par,l:r,eLers.
Parannter
l'le
thod
Turbldity
total
alkal inity
Free
carbon dioxide
lotal
phosphorus
So
I
uirl e orthoplrosphate
EDTA hardness
Anrnonia
nitrogen
I{rtrate
nrtrogen
Nitrite nitroqerr
Sul
f
ate
Chloride
Fl uor i de
Ir.on
(total
,
sol
ubl
e,
and
ferrous
)
Sulfide
'
..
(totat
and un-ionized
and dissolved
hydroqen
sul
f
ide)
urqanlc nrE,roqen
0r:ganic
carbon
(total,
r.
'
particulate,
and
<lissolved)
Chemical
oxyqen dernand
Chlorophyl
I
a,
pheophytin
a
i'aiiitek
i4odr:l
2l
nephelom,:ter
'l'
Stondard
l4etlrorJs
l4th
ed,, Lilrdtecl
to
plt
4.60
Ca
lcul ated by
method of
l'larvey
{
I960) and Park
i
1969)
Stannous
chloride
method
,
'
'
:.
SLahnouschloriderne[hod(Autoanaly.zer)
E0TA colorirnetric rnethod
,
"
l.lodj
f
ierl
phenate
nethorl
(Autoanaiyzer)
.'
Cadmirrrn rerluction
method
(AuLoanalyzer,)
0l
azoti zat ion nethod
(Autoana
lyaer)
Turbidimetric rnethod
:
Argentometric
method
,Electrode
method
on 0riorr fudel
601'nretcr
,
,
.,1
Pherranthrolinenrethocl
r
,,
Methylene
blue visual
color
matching
rnethod
Total
Kjeldahl rnetnod
(Autoanalyzer)
'
r..:.i'
.
:
'...1'
Direqt
.injection
metho<J
on 0ceanography
International
Carbon
Systern
llach
Reactor 0i
gestion
COD method
(J
j
rka
and Carter.',,1975)
St
andarcl
irlethods
'l
-:'
:: i
t
I
T
I
I
I
I
I
t
I
I
I
t
I
T
I
I
RI
SI,lL iS AI{O
I)
ISC{JSS
I
Of{
Data
f
rom
the
f inal
col
lection
period
of
July
l9B0 through
fucernher
l9B0
are
cotttairtcd
in
Appcndices
3.l -3.ii.
Previously
col
lecLatJ tJata
are I
isLe<l in
1979) antl
Appendices
3.1-3.'3
of
the second
annual
repori|-
(Liehr-Storck
l9B0).
.
,
:,
:
DISSOLVED
SOLIUS
Coffeen
Lake had .1
much
greatcr
concentration
of
Lotal
rJissolved
rol
itls
(TDS)
than
rJid
five
other lakes
in
this
geoqraphical
area.
the
rilcdn
concentraLiorr of
TDS in
Coffeen
Lake on l7
June
l9B0
was
853
nrgi'1
as
NaCl,
'rvhile
fivc
other^
lakes
in
the
area sampled
on
lB
June
l9B0
(Liehr-Storck
l980)
hatl
c0nce'tlrati0ns'?n
the
range
frorn
l33
to
321
mg/l as ltaCl
(table
3.2). Lake Sangclrr'is,
anoLher'
cooling lake in
central
Illinois,
ltad
a mean
TDS
concerrtration of
319
nrg/l
as
NaCl
(Iable
3.2)
(Brigharn
lg8l
).
,:
Little
variaLiort
j
in
TDS
occurrerl
arnong
stations at
rrrosL
tirnes
of
thc
ycrr
during
this study.
ln
the
spring, however,
concentrations
at Station
4, in
the upper'
enrl of
the
lake,
clropper.l consirJerab)y
relative to Lhc
other
sLaLions,
corresponding to
increased
rainfall and runoff
creating
higher
lakc
elevation
(Fig.'3,'l).
The largest
tlrop
in iOS at Station
4 occurred'il
the
spring
of 1979
when
t.he
rnost
dramatic
increas€
in
lake
elevation
occurred.
The
concentr'ation
at
Station
4 also decreased
relative to the
other stations'in:Augrst
l9:zg rturing
a
lrerioci
of
heavy rains.
Tlte overal
,'::.
I concentration
of
Tl)S
varieit considerably during Lhis
sludy, with
a
l..g--qg.j9gg1.9-e
.q.cjurring,
in.the spring
of
1979
followed by
a
progressive'
ii-i-,t:Sgr-q,'
Since the'volume of the'.lake
also varied,
however, the
toLal
imounb
of
dissolved solids,in the lake may be
a
more
rneaningful
parameter
for
cteter:;rrining
whether dissolved sol.ids actr.ral ly
increased
or decreasr:<.|.
Us''ing .r
lakc
:
'.
elevation-volurne
'.:a,,:
:
,'
relationship
,
.:.
(Fig.
3.2;
Sargent
onrl
Lundy)
the
arnourrt
:
,
'
of
dissolVecl solids wa5-calculated
rdrrd
plotted
against tirne
(Fig.
3.3). A large
decrease was observeJ in
the
spring of 1979 when water
stored in Lhe reservoir
was
,f.l
uil
uslled
over
the
spi'llway asr,-lar.ge
amounts'of rain
and:runoff
waler,entered
.
""tl
,:'i:t:i-.1.
::
1
:.
.:-,a.
I
3.5
\a
\h
+J
+J
P{J
E].('
l-
l-,
F.F
aJ,
(uJ
a)o
l,
E,t-,
o-.16
-.:
o).=-
cr.=
4
o, )-
a7'
|
-l:
.t,
:}
.'lctc('lfna\r
or
o
ala
rD
ftr
g
s?@cocuGl
d'=t
9
:t
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{.;
t1r
.rn
:;
,
(.r'
fi)
\O
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C-o
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fr)
<l
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;
fw
rn
aqg<rm
C!
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(3
fr?
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:
f.\
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(\J
fr.)
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,,..:
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'',5!
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a
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{b
(D
HH
tr)
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'l
3.8
l:,::
r000
I
500
580
560
570
o
-tr
o
f
,tl
q,
o
3
o
c
o
,o
o
tlr
5
:;
'rl0
Sloroge
Vofume
15
20
In
Thousonds
Ol
25
Acre Feel
-
at
:'.
-
-
:.
. a--
Figure 3.2.
Relatlonship
of
,
'.t
,
surface area
1n
Report SL
1990)
lake
elevatlon
Cof
f een
l,ake.
3.9
with
storage
volume
and
(Source:
Sargent and
Luncly
I
It
t,'
'I'
'l"
l'
l-
:
l'
'
t.
'l'
a:
l=
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u
m
r\
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ca
an
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o
bo
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3.
10
the.lake.Frornlatesunrnet.of'l979r:nt,|ltheenr|oft|it,::,|'i,rt|y,liL||e
orklitional
water was
f lushed
f rom
the l,rke,
trntl
a
f
airly c0flstdnt
increase
in
total
dissolvecl
solids
was
otrservecl. This
iilr.rease
can
l)c:al.i.riblterJ
Lo
:i;rplLs
frorn
precipitabiort
anrl
runof
f as
well
as
f
rom
deminr:ralieer
ivastes enrl
c0al
pi
le
runof
f
porrd
ef
f
luerrts.
'
Even thouqh
t.otal
dissolverJ
solirls
concentr-ations chanqed
during
lhe sturiy,
per:iod,
the
relative
composition
of lhe
anion
components changed
on'ly
slightly
during
that
time
(Fig,
3.4), excepl
at stati0n 4
rluring
the
spring
flood
of
l?79, an.!, to
o lesser
extent,
during
the spring flood of 1980. Instead of the
carlionate-bicarbonite
anions
expected to
tre'dominant
in
trodies
r,,f
water
irr
ternperate
rregions'lHutchinson
1957)', sulf'ate was ttre rjorninant
anion.
Sulfate
concentrations
were much h:igher
in Coffeen
Lake
than in
five lakes
cf
the
suriounding area
oi
in
Lake
Sangchris
(Table
3.2).
Both the
high
conceritration
of sulfate'and
the
extreme domindnce
of
the
sulfate
anion sugcest Lhat
Coffeen
Lake contained
sulfate
concentrations that
are corisiderably
great,er
than normal.
The
increase in
sulfate
concentration
over,firne
is,illustrated
by data
collectecl
and
provided
by
the
power
plant
sjnce
.|966
(fig.
3.5).
ihe rnost
rapid
increase
occurred
cluring the
period
f
rom
.|975-1976,
wiith
a
decrease f
ollovrirrg
in
1977.
Sulfate
levels
in the
lake
generally
corresponcletl to
sulfate
levels in
the
asn
ponds
(Fig.
3.5).
These
ponds
were
taken
out of use in 1978,
,rnd apparently
sulfate levels
in the
lake
have
dropped
substantially as a result.
Sulfate
concentrations were
found to
be significantly
differenL
amontl stat,ioirs
(Station
3 vs.
4 and
Stations I
+
2 vs.
3
+
4),
rnonths,
and
sLations by
months
interaction
(faUte
l.l).
These
differences
were mostly
caused by the
large
decrease in sulf ate,concer'rtrat,ions at Slation
4
during thri
springs
of
1979
and
1980
(Tables
3.4
and
3.5).
At other tirnes
of the:year there
was
ljttle
difference among
stations
(Fig,
3.6).
Significantl.y
lower
sulfate
levels
ocaurred
in
.|979
than
in l-q8f)
(Table
3.6) ai a restrl'l
of frorn
the
spring
floorJ
.::"
of,1979.
:A
substant'ial
drop in the lakewide
sulfate means
occurred in the
spring of 1g79,
from
596
mg/l in January 1979 to 3'10
mg/l in
May i979.
Afler
thai time, however, sulfate
concentrations increaserl
steaclily
(Fi9.
3.6)
untii
.:"
they
:.,'
reached,512 mg/l in December
1980. This increase
was
acconrpaniecl
by
an
l
,ovir.al'l.decrrease
iri,
lake eleVation't(Fig.'3.''l). Therefore,"fo
cleter,rnine i6'',the
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quantity
of
Sulfate'in the
lake
had increagcrj
0r
decreasrr,, Lhe'clevation-volume
relationshlp (Fig.
3.2)
,ias
.igain
used. Ihere
was
.l
subsfnntial' ctecline
in
the
sulfate
content of the
lake
in the
spring
of
l9l9
*hon a
consirlerallle
rlrnrrirnL of
ilater
store{, in
the reservoir
vJas
f
lushed
over the spi
ll,*ay.
l'rorn rhat
Lirne
until
the
end
of the
stutly, the amount
of sulfate iri
Coffeen Lake
incredsed
fairly
steadily. tlhen the
study
enrJed
in December
I980,
the
sulfate content of
the'lake
hatJ
not
increased to
the
amount
present
at the
beginning
of
the
study,
so the
amount
lost by
flushing
in
the
spring of 1979
hacl not
yet
been replaced
(Fig.
3,7),
[his
pattern
of decreasing
sulfate
with a subsequent increose
was
very
sinrilar
to
the
pattern
observed
for
total
dissolved
solids.
Tlre
percent
of
sulf
at.e in
the
composition 0f anions
did not
change drarnal'ical'ly
throughout the
study,
except
at'station 4 in
the
spring as
alreddy
discussed.
Prior
to
the
spring
of
1979,
sulfate comprised
about
84% of
Lhe
ani0n
content
by weight.
Fron
June
.|979
through
the
remainder
of
the
study,
sulfate',*as
about
BOX by
we'ight,
with little variation.,
'
:
Sulfate
concentrations
were
significantly
lower
(p
<0.02)
:'in
the
hypol irnnion
when
rlissolverl
oxygen:concentrations
were low.
Sulfate
is
reduced
to
sulfide
untler
low
oxygen
cortditioris, but
hydrogen
sulf
ide was
not
rtetectetj.
Al
I
sulf
ide
produced
was apparent'ly
precipitated
as iron
suifide.
Lack of
stratification
irr
winter
protrahly prevented
sul f irJe f
rom bei
ng f
ormetl at that
t
ime.
Alkaljn.ity levels
were
lower
in
Coffeen
Lake
than in
most
of the
five
lakes
in
the
sarne
geo<;raphical
area
and lower
than in
Lake Sarrgchris
(Iable
3.2).
Statistical
differences were
similar
to differences
for
sulfaLe
concerrtrations
(Table
3,3). AlI statiorrs had about
the
same alkatinity
tevels,
with the
exception of Station
4
rlurinE
the
spring
of 1979 and
.l980.
Alkalinity
was
probably
more djluted
at Station 4 than the
other stabions
as
a result
of sprirrg
rains
and
runoff,
although alkalinity
levels decreased
at all
stations
aL Llrat
tirne.
0vcrall,.hovlever,
alkalinity
increased
in
Coffeen
Lake
during
this
sturly.
The
mean
alkalinity
in
1979
was 65.5
mg/l
as CaC03,:arrcl
the
mean
in
l9B0 was
82,6
ngt/1
as CaC03;(Table 3.6).
These
levels
were
arr
improvement
since
1g75-76 when
data
collectecl
at
the
power planb
indicated
that
alkalinity
levels
plunged
dramat.ical
ly
to abnormal
ly
low
levels
(f
ig.
3.S)., The,lrigher
alkal
inily
is
a desirable characteristic because
it
provides
greater
buffering
capacity
. ..,
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.
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ll:i::::::
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;i_::
:.-,t,
dnd
is
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hy mnre
dssirablr,'
spec.ies
.t
lgarl
t
against ptl
chances
l
(K
i ng
I
97ri) .
0f
The
.iwo
other
rnaJor
components
of totdl
disso'lverj
sol
iris
in
Cof
f
een [-ai:e wer'r-'
hardness:lcalcium
anrj
maqnesiwr)
anrl
chlorirje. llarrjness
levels were
lower
Lh0n
inlthe
f
i've lakgs in
the
same ,tred,'uut
higher than
levels
ir;
Lake Sarrgchris,
whil,e
chloride levels
were lower
than
levels at
Lake
Sangchris but higher
than
in
the
other
five lakes
(l'able
3.2).
Ihe
ctata for
these
paraneLers
were
observed
in
pattcrns
sirnilar to the
patterns
of
sulfate and alkaliniLy
(Tablc
3.3I.
llardness
was not
signlficantly
different
betwoen
yedrs,
but
chlor'ide was
significantly
higher
in i9B0
than
in
1979
(Table
3.6), although
chloride
did noL
reach
levels
as hiqh
as
those
observed at the
beginning
of this
study.,
Decreased
concentrations
of
botn
parameters
tvere
observed
at Station
4'during
the
springs
with the
biggest
decline occurring
in the
spring
of l9/9.
,As
pith
the
other two
TDS
parameters,
there
was little
variatiorr
among
stations at
other
timesoftheyear.'
'
:
i
,
.
:j
TURBIDITY
Statistical
differences in
tur.bidity
(Table
3.3) were
causerl to
a large
extent
by
extremely
high levels
(rnean
143.6
NTU)
at Station
4
in
the
spring
of t9/9.
Tltjs
occurrence
resulted
in
h,igher'levels
at Station
4
(Table
3.4) in
the
spring
rnonths
(Table
3.5), and also resu'lted
in significintly
higher
turbirtity
levels
-
in
1979 than in
1980
(Table
3.6). The high turbidity
corresponded
to
heavy
precipitation
and high
lake
levels at
that time.':lncreaseci
turbidity
levels
wet'e also-observed at
Station
4
in
Auguit 1929
(mean
.|4.0
NTU) and
during
the
spring
of
l9B0
(mean
20.0 NTU), which
were
also associated
wiilr heavy
precipitation
and rapid increases
in lake
elevation
(Fig.
3.1
).
Turbidity
at
the'::other, down'-'lake
stations
did
not increase
to the
sarne extent
as at SLaiion
4
located at
the
upper
end
of the
reservoir.
'Durlng
the
spring
of'1979
the
nrean
turbjtJiti
at
the thr
ee down-lake
s.tations was
only 1
5.6 NTtl. Apparently
tnovement of water through
the railroad
causeway that
separates
Station
4
from
the'othei'staiions.'was
slowed
enough to
allow
much
of the
particu:late"matter
to
settle before the
water
mixed
with other
parts
of
the
lake.
l{igh
turbidity
levels
were
generally
associated
with
high
l.eve'ls'of to'tal
phosphorus'arrd
total
T
I
I
I
t
I
T
'
.1
,i:
i
--.:',,,i,,.,;:-
I
l
I'
I
l'
I
il'
il
ill
il'
a';,..',
tl-
t,?
Plt0spt{0Rus
..
,
:
The
form
of
phosphorus
useri
by
ptants
as
i
nutricn!-
is
s0lut)le 0rlhDphosDhJr.,J.
lJocausc
this
form
is
rapidly
cyclerJ
and
convl)rted L0
olher
forms,
it
is
rrot a
g00d
lndlcator
of avai
lablc phosphorus
in
tho
sysLern.
IoLal
phosphorus
is
considered
t0
be a
more r[liabld
osti'r6td
df availabl6
phosph6r.us
{Foai6/oy
i
e6o)
.
:
:::
i\
A large
insrease
in
toia'l
phosphorus
at all
s[aIrons in
August
)g79 eould not
ba
exlilained.
Therefore,
t0
exclude
possibly
errone0us c,ata,
thc
data from
that
mortth
were
not
used
in the
statistical
analysis
(Tabie
3.3).
Phosphorus
was
not
significantly
different
in
197,9 and
1980,
with
annual
means
of
0.051 ng
p/l
ancj
0.054
ng P/1,
respectively
(Table
3.6). Station
differences (Sration
3
vs.
4
and
Stations
I
+
2 vs.
:
+
4) were
mostly
accounted
for
by
higher
levels
at
Station
4
(Table
3.4).
Increase
in
ptrosphorus
at Station
4
qeneral
Iy
d the
highest levels
were founrl in
the
spring
(Table
3.5),
with maximum
concentrations
of .277
ng
P/l' in
Ap:r"i I
lg79 anrt 0..|73
rng
Pll
in
April
1980.
Frorn
the
spring
of 1979
untit
tt. rottowing
spring,"
phosphorus
levels at
all
stations
were
simjlar,
witir stations
3 ancl
4
cenerally
having
slightly
h'igher
levels
than
Stations
r
and
2.
In 1980,
however,
phosphorus
level s'
rentained
higher
at Station
4 throughout
the'suslmer..
'
Phosphorus
levels
were
sintilar
at the three
stations in
Lhe
lower
end
of tlre
lake,
and
gradually
rose
throughout
the
sumrner.
phosphorus
levels
then
decreased
at all
four
st,atjons
in the
fal l.
N
I
TROGEN
The
nitrogen
content
of water
is
cornposed
of
organic
ancl inorganic
forrrrs.
The
inorganic
forms found in
natural
water
are
ammonia,
nitrate,
and
nitrite,
although
nitrite is
usual ly found
in only
small
amorrnts.
The
typica-|,.
seasona'l
pattern
for
unstratif ied
I akes i
s
a sumnler
rnaximurn
of
anrynonia
(Hutchinson
1957). Stations
l,
3,
ancl
4
were
not
typically
stratifiecl,
and.,Stat ion, 2, althoug!r.,it
was
t.herrnally
stratif ied in
the
sutnmer,
diC
not
nave
significantly
different
arrmonia
concentrations
at the
srrrface
ancl
botLorn
during
3.25
,t:.1.-::
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::;:.
l'.,..
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.-
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I
.:
I
I
I
:'
I
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I
t
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i7;.:':
51:,-
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i.;::.Jj:,
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t:::ii..
'-.,::::.
,:
i:.:'.'
t:.J::.'
.:,:i-::':: :
i',:::l
.;.i.
';.,
i:.:: r.
'ii'.i''
::,,',.:
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,,,:.,1l
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i..,,lr:',
::,::.:-J
i:l::::l
'aal,',tt,t'
--
iir:::
-..
!.:::..
:
:':.:':
t:::,-a
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-
'j't,::.:.
: .
a-,1
j
:r'j:..;.
::::':-.
{:r:a:.'
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,.t:.,:,,',
i:a:'...
f..:':a::.:
ii=j.r:.'
iil
:i
a.:::ta
ii.:5.:.:
;g.i'.+:
++a
4i.-l
Et:
::.-ta:..!
:r-:;
,
-
Fli;i=:::,
Ithe'months
thdt
stratification
occurrecl.
The annoni,l
cycic
olrserved r.luririg
lg/9
l{as basically
the
typical
pattern
FriLh
drrmonia
concentrdti0n.,
irrcrcasing
ilrrr:Lrqh
.the'.5unfiEr
and the
maximum
occrrrring
at
al I
staLions in
Auqur'".
Tlrc
onl.y
apparent
deviation
from
this
pattern
was
the
incrc,rsc
dt
5tdLlor,4
in
lhc
sprinq'
which
can
prol)ably
be
expl,rin0d by
the r'api{'l
irrflow
of runoff
w,tLer
at
that
time.
During
1980,
however,
the
typical
arrurrorria
pattern
was not
0bserveil.
Anrnonia
levels
began
to
rise
at
all
statlons
in
late 1979
with the
s,naiiesL
.
increase
occurring
at
Station
4.
Levels
continued
to rise
until Harch,
with
Stations
I and
2 having
the
highest
concentrations
(l.0li
and 1.107
mg N/1,
respcctively),
and
Station
4 the
lowest
(0.41i
mg
N/1). The
may.irnum
amrncnia
conccntration
of
1.150
mg
tlll
was observed
in May l9B0
at
Station
l,
located
in
the discharge
arm.
In
June,
anmoni
a
level
s droppe<l
at
al
I
stat,i6ns, 91ith
concentrations
subsequently
increasing
at
Station
I but
continuing
to
decrease
at
the
other
stations
(Fig.
3.9).
The
extrernely
high concentrations
(
Z.lB0
ng
N/l) observed
at
Station
I
in
December
l9B0
were
apparently
affecLerl
by
operations
al the
power
plant.
Significant
differences
of
anrnonia
concentration
among
stations
for
all
station
contrasts
(Table
3.3)
dre
explained
by
Llre
gradient
around the
lake,
with
highest
levels
founri
at Station
I ancl
lowcst
levels
at
Station
4
(Table
3.4). l4onthly
nleans
were
hiqhest
in the
spri6U
Inonths
and in
December
(Table
3.5),
contrary
to the
rrormal
cycle in
which
'
maxitnum
levels
occur
in late
summer.
Arnmonia
concentrations
were
signif
icanily
'lower
at all stations
during
.l979
than
during
1980
(Tab)e
3.6). Devjation
frgnr
the
typical
atlnual
pattern
of
armonia
cycl ing
plus
the
rapid
increase
in
arnnronia
concentrations
in
1980,
which
were
significantly
higher
at the
sampling
statiorrs
nearest
the
power
plant'discharge'indicated
that
amtorria
levols
were-affected
by
the
power p)ant.
The typical
seasonal
pattern
for nitrate
is
a maximunr
in
r,vinter
dnd
spring
wherr
the.rate
of nitrification,
i.e.,
the
oxidation
of
reduced
njtrogen
compounds,
is
most:rapidr and
min'imum
in
July and
August
when tlre rabe
of nitrate
reduction
is
the
greatest
(Hutchinson
1957). Again, the
pattern
observecl in
Coffeen
Lake in
1979
appro*]r.::o
:n:."*ou:,ed
pattern
(F'is.
3.10).
Nirrate
concenrrari0ns
increased
at all stations
beginning
jn
the
fall
of
1978,
and reached
a Inaxirnurn
'in
itlarch:of
0.B08 rng
i'lll. Concentrations
starte'd
to
decrease
in
Apri'l,
ancl
the
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in
nitr,n,:
ii,,l1qtl,it-!-4',
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.ii;.a!.rii
i.i:ir;
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ln0SIly te
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l,;rrr'r
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it
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sla|.iotlE,
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l,-rtiLeri
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rr,r;r:
nitrdte
levclr
SiJbstnntiall;l
<Iif
frrrtir"rl
f
r$:*
r:Jrir
;ii.;:r,r
iiaiil,:
j.,tr.
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Signif
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dif
fgreflCe
belween ye,lrt
.r,ri ,J4iic
{.,,!,'l.iirrr;ii
t;-t
.,,ti:,,iuri...}ii;.
r;r.]fri..r.
ConcLlrltraticr:, rlurinq
ljilC
tnan
rlilrii.,l
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:.iair
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.:.tr,.
Nitrite
levr:l;
/rerr..
,llS0
hitner
lrl
':
{tlrj
r-lr,tr,
in
i{.ii,i,
arl
it
::it.
incrLrdsinq
f rorn
,04j
n1
:l/1
rrr l<J/,1
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ri,;
li,,
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rn
lrf
:;r1
j:
hiqhest
fictlft
o itr i
te
cr)lctlrtrat
liJn
*t",
r:it,,t1r,,rl
it
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r..irr
l
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bOth
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rJrir-l+.:r.
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wittr
lhe higheSL
nitrr!-g
(;r,rr{:rtnlr,l!-rr:r:,
{1.::tirr
}.,:i.
j
.:!i
il--,jrlt-( rr?
f
=li
i
i}4.,.'
,Ji:r.r
,,,b
j.
ii)l'
tr;.j
!.hrt
It**::
t
,t
r.
/.!i
!.:."iit.'r'
I
'e{.rq-r1
Ihe
total
inorqartic
nitroqr:rl
ci)ncqrtlrat irrn
rr4.,
,,
irlrr!r lf,
lrlr.
l./
ii
r
,'ipr'
rrr
i r",.
(Iallle
.3.3),
ritlr a rre,rn
of
i.60B
rqq
ltl1.
tt,rrt
rrr
1,r/(j,
,r?1
,r
:ri.,irr
rif
.ii
1,
::,;
N/l
(Iablc'
J.6).
The rJre,ltelL
incrr,rt.t?
tco'.,
irl.lrr:
ijrrrir',1
thr.
!t,]r
i,j,l
f
r-..,:1
SepLenrber
l9/? Lo l4arcrt
l9t-10,
wiLh
the rndvi,,rurrr,)LCur:'irr4
tn
l,larr:rr
lgBrl.
i)rlr.irrg
t:ttat
period'
ihe
tneitn
concenIrat.
ion'*f
lnar.ltalrlc
!iiLrr;,lt:n
inr;rrj,t!i](i
f'r,:i:ri'.:O.l o;n
N/l to
2,273
nrq lll1.
0,rrinrr
the last holf
,'rf
llJ!
,ttttt
0rrrinr;
rli
rf
lljlr].
levels
of inor'9anic rritroqen
#er','
crlnsirte,',thly irl,/Ti-,r' ,rl.
(,t,tr-
i0r;
ri
r.ntil
:i.
t
lle
otlter staLions
(Fi
g.
3.
I
l).
SLation l, loc;Lerr
in
the
rlis,.ir,irrJij
,)r:ii,
lr.:
J ilre
vittt
signif
icantly
irirlirrir
lrvr:1,,
itr,ln
Sldti0n
?
(Table
3.3).
ThL: rnean
inorganic
nitroqen
ccncenlrlLion
irr
l9B0,il
StcLiun
4
wac
1,126
mg
il/l dnd at Station l:was
2,046
rn,1'il./1,
i.c,
tlrt:r't
,rr/u,.r
il
jnrosL
twi4i:
i-he
concentrdlion
of
inorganic
nitrogen
at
Stdtion
I
,.r',.rt
i>Lrrlron
ri
dur-in,y
lgBi).
,'Both
the
increased
levels
in'1980
drtd
the
rligLurtrer!
sGdsorlil
cyr:l'-1
0f ni'ir.ogc:rr:
.
in the
lake indicaLe
that
a significant
loarJirrg
of
niLroq,.,o
occdrrc(1,
;rr.rlbably
:::::'
starting
:
:
-
in
late
1979, tlhi
le
the
ratc
of cyclirtty
of niLrogr:n
f
rsin
sr-g,l1ic forrns
3.29
a.--:.::
a.
't
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d
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ri..
$athnbllf
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r.r;1,j*r"
i'+Ir:irr.
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liitri=l,:
.rtl',1:t4:t\,')::',t1:.,'.:1.;:jrt
f
-;,:::.1110;:.,1,,-1
:rf
!1t:
nitrOggrr inp,lf
il
rrnL,rt,rn.
,lrgAniC
nitr0rjttq
ir-.velt
,rer*
i
tlrll,-,jn,Litr-,.r,
I
J:-r.r..i;
..?:i:.:r,..
:'.
j
-ts..rir.,(,
-,dfiilled.
IhA
forl(entf
l!.irlti ,i.!t
friliir:rt
tr,'t,.ti
l'ji.',
-'..
1!'i .=;
.:.;
'i,;i. *rq.1
1r1,.
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itt
Aurlr;r',*
i9i'l
in4.lrf
li.!i
rit
ti,t,l,,
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:,?ir,,,'
:i..r/i
l:,:,1
.
..
,r;i,.,t!., iri
l.!:,j
{rjr.j
i:,
the rJtlge
D€liyccn
ij,t6-il
.{lj
rrri
ri/i,
,-ir,+"-l-,1
!
i,
,,!:t
irr*4!:
r,1\
..i{1i,:..i:r
i:;
l1*ii
i$.'t0
tn{ fl/l}
ltran in
l'l19
i{s,77
r:iJ
if:'i).
i-ittl+
z-ltitt,r+-,.1
1, n.jl
frir,!{.)''r.,ir}
.rllyjri,i
iJf
90niC
nilprlggn
levr!:
nt dif {r:rer,r. \t
i,.
rqrr,,
ti:1)
R,iIl05
*at,irrs
sf
tol*1
nitrrrSen
t*
irtl+tph{}!"!r!
ieri:'{!eni:r.al
1,r
1r,;.-1i!jr
!.*.1f:
i?,
inrticaLirrg
phospit0rriS
t,J hl:
Lh€.
ltqiillrrl
iutrif:nt
fr;r
.ll{,il
,trar{Ltt
r
1r.
l;,.r'
.,ft311
tliLr(rqrlrl
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I
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,tniJ
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l'il4),
5tat
iorr
4
r.rfiirrtryrrt
I
J,
,,a,l
llt'
l,id(,,rt
\:i)
raLios,
xhiclt
CJrt
be
dccountr.rij
for'try
br;tlr rr:Jatrve!.y'l
<;*
nitr.r]-lrrr
lrrrl
\.i
:;ir
ilh0sphgrir-r,
lr:vgl:.
ibrevr:r,
lSt,tl
nilrogCl*
ixay
**t
tju
ri
!,r1]rt.rrt
i!tLl
i,:+r_lr.irf
dvailable
tiitrogen
as
totai inorganic
nrtro(len.
jlr.
r,!.ri
ir',ri
.i
irr i9/g.
^;1,^'1
inorgartic rtitroqetl
iydt
gc;nsi{ered
r'.ltlrr:r
l.lt.tri
I
rit,il
nilr'r'.rtlr-,rr.
ll:P
r,1l
ii11
sr.,1g
less
than l2
f
ttr
mosl
uf the
year
(t.larch
!.r!",J'r'jil ii'r./crnbitr'l,
In
igii0,
?;3
r'
1';1!
ier,
were
less
Ltl,rl
I
Z
.rt
':t
at iOrt 4
only dur
ing
thr,
rrri;rrins
fif
,rlir
i I
,
f1xg11,1r,,
61rt
5ePtemb€r,
ivhieh
were'the
months whcn maxirlttrfr
pht;;plloru:':]4v,Ji
i
,t{curr{ii
dt
Station
4. Ratios
of
lass
Ihan
l2
wtltr] nevrr
ob:r;r-vert
,ir,
thrr
ot.irr;r
tirr.r:i-.
stations
rturinl
lgBfJ,
but
occL'rred 0ccnsinnrlly
{t4a-v,
leptr-r:nl)(.,!',
,trrrl
llovernher
i
al. t,hese
stationg in'i979. the
increaserl
nitr,;gp11
'!r:vcl,,
in
Ct:!'f*r:n
Lak4
app,:,rr.
t'o have'caused
tltc north
en{, of the lake
to
change from beinq
nii-rlqerr lirnited'
[o tieirrg
pnospholus-.lirnited.
ilowever,
the, loxer
'p*rL
of
tlre
laie
lppr,are(l
to
Itave
been
phosphorus-lirniled,inost
of.,
lhe
t.irue
even
br:for-e
rritrorren
lev,:!9
:.
ihCreose{,
,
':
,,
1,:
3. 3l
::.-=,"
'ta':,
..,t,
'..,t'
,'::'."
:
t:ri :
...
.
'a
'
'i'
',:
.
--
,,
,,,,',.
-'
i,,
:
,
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l,t
..:
.
.
.
,,':,
1..-
,i,,
t-
,
t,
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CttLilt].lti{Yli ir
.
pit
,
'J
!i,'.iil
if
:;
,ii
v
j;i
:i
I
I
I
'l
'l
Chl€t*gpltyl
I
A:c+nCrt*{r;l!o*t
:a1"1yi1
,1r'11;i.1.,i .:i
.1
;':.;.=,
i !,t,1:
:
dr,f
lnrj
ail
rn-i4lnt
gg'npieri lilu&,"J)d.r' l'iJ?
ll!7.r;,r 'i
,,:,:,...
i
:-i'.1 tf-
';1
T
t
t
T
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t
I
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t
t
l
t
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,:- I
.
a
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l$llii.,
eit,tt
irlri:;
? ac*
J
!r.:ni:r'i?
iy
lr,rii.i-;irir.r:r;!{+tr'!
;r1., ';',.1 '
^r.r
'
Iltt<Jr.e.rt4.1|.{{j|iftin1t..a!'iijq''4i.}!.i'":+::,1{.i!=':::];::!'iri!:.:
brhi lf.
Lhr-?
!?f-r-:dt€lrl
i-+!]ta-rn!-r,lLt+41
,i!,
.':i.4!.
t1lri
!
rr-:e
1.
:::i,-:.:r
;r
;
r:-r
-i.lil,
Ilre t'eilurr:
+i
ilartl,'-i.riate
arri
'rr:!
1'l
,,r'r;tntr
...i"fi
',
1
P,f
!-
l{tt'li
5Ugilf'.,trj(t
th,lt
.)r
qin
\l
r..,tri}\iti
,r.1,,
rr.}t
.:
1.,.,
j
?i!.,
i.
j,
'.
,i
trii
:"
:
Ir
a-.:
1:t
r,
i
Alq+!'a*f
ivily
''cas
ref
li:clr-'d:
in
lhr:
iiii.
4ii1i;!itj
i-:r:Jtr=:4,
.]ri:.:
;:::rl
r:'::-
:.t:.;'r'-
--:
Of
rJ!gfOlverl
r:ry'.;cn.
4l I
statl{jfrS
ir+'J ti,tr!.ir-
li!
l!i
i,i:i:
'...r,*'rx,ri
:i.fi:.r-i'>
::i.',
i
i
thg
t{ifller.
ilt
Statir:tt
4, thert r€!-t
!a:i.t:ri!' li.,i*:
ju-trr
I
l';.-
',;r1::--r', !i1
.1i
i.t..:.:.
pH
was'above
9.0, inrtiicatinq
vigtirou.r;
j)!r{il-;-rt1i,l.:1ilij1,
I
i1
1'!
r,,i'!,7
},i.'l
,rii::!,",
195il).
Low
pH
{as
ir(irtn{l
orrly
irt
tht,
ilt}.:p
'{att:r
.!?
iht:r'+.ii;
r
.!"? :i
ll
r,,,t
SLatiOns. StatlOrlS 1.5nrtrl
?n*+?re.!tr4tlf1r:r!
rjrlrrri'"l
r]/{tt.;l'!r.\,.t'ri:,e;!
Ih.l
'l
ow
pH (lest
lhari
7.5,1
oc{il'red
nL th€
i}.Jr"l{:irrl,;:f !nr-r:;t i{i?-irrr:t-. lli,r'..: i**
1;l;.
vdltles
corresporl0td
L,l
lriqit
r-rlrrr.r:ntf,0t
ionS
ilf
L4rli,irr
(!?i;).i,:i:
i'!,r!
*,.,,
r,
,ir'.:'!
i'., I
by
rleCOrnprrsil iolt
1rf
ort;anic
,:r.ri.ter
tln{t
4r'.cr,iv*ii:!,..,!
rrr
r.ilr: iry;t';i,,rrl
rrif
;
.i
r.
i;,,;
5traf.if
icatio*.
During
the
.'urtrrfr
r-r{ !9ltl
,
pii
i.il.ji:,:'*.,,,',:
al!il:!-r
t,l
!'i!,-
.,,,'r1i,,--
wa[er' and
lti,rer in tht
dur:p
water
Lhan
in
l]Bi],
!tri!
ri(.i,.irt:t'tt.r:
t.,ttt,ti
i.',:
:
!rr,.
resrrlt
of
Iiqher
at\alinity, and Lhrrs,
grlrati-'r'
l>rrf
14e'!rri|
r,ri.ri.i::L{, rrl l:!4,1.
-
,'
Flucttratior;s
in
pll
ciid
not.]ppear
unrra!(rrdl,
.tnC,lir,:l'.-
i:tp,1,;f
i-:f pon'a:.:;'|irir:..
ef
f
luents
,rn
lake
w,rLer
pll
*,'ts apparently
mini;nnl.
,'
0issolved
oxygen
(0.0.)
./as
depleted
in tht hypol i*nlrlrr
of
llu rtr:cp
t.l.utif
i*d
stations during
most
ilf
bobh sumnrers
{,.|979
trii
!930i,
thr}(,
r,i.,Lritlirt.;
a
!,rrqt:
parL
0f
lirc deep
section
of [h€ I rkc to
'n,rg1 lnirrrnl
lif
e
f
or
-r
rintir!ur'311 ],r
period
of
time.
Surf.acr: 0.0. levels worc loder
in
t.ir:.,5rJ:lrrgir'!
ttr,iri
in
trl'.,
tvinters,
rlue
to
warmer
t:emperatures
causing'lailcr
o{ygrn
sr:lrllri
ity
i*
iirrr
surnmeas.
At'all
times of the
yedr
0.0.
aonan,llratiun'g werr Lhf
hrqirq,;:i
,1.
Station
4,
reflecting cooler
temperatures
and'gr:edl.er.rlqal ar:Livity. ilr:irolvr.,l
oxygen
became
l'airly
low
(les5
thdn
4
mg/l
)
irt
Llre sumrturr's
,tt St,ll.iorr
I ivhi-,rr
water',temperdtures eere very
high.
llowever,:fJ.0. lnvels
w*:r'e,',rl'#ayi
dirirvr-,
d?'
near saturdtion
at SLation
I
at
the surf
ace.
ltilh
sdturaticlr lcVt:1.;
,,rr'r., lif:u!;,
:
,,:l
'',,
,
,.
'
':t::'i:'
-:.,a
:i
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af
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buf
f
er
ing
capacity
raItrer
than
1re+Ler
,rlqa!
ae t
i';iiy.
!
Al thilugh
5tatign
4,
lrrcat"ed
no!:lh
of
lhe
rai lr*erj r,a:is(':wryt
itllip{}rteri tirf
9r'eate5t
5l&nrli'tq crop lf
,rlqae,
.irf
itr:r
r,rt.{}S
of
pririi'try
lrr0r,rrr-t
it
il
y
of t,-rr
occrrrrCd
nt SLatitin
I,
locaterl
in
thr:
,rrra1.t3rr;ri ar;ir
iir:,;t,irrt
i!tli-ii.'
,ffr!s,
phenomcnon
uay:i.tdicatr
greaLer:rar-e
of
nutrient
r+'jeneralicr'!
at 1L*llrin !, rtuc
to
warrner Lenperdtrrr'(f5
artd
polcr' plant r)pernl itr)t.
Thc
l,alrrnt
qf
rrirtr'ir,ol.;
present
ef
ltcts
lhe arnourtt
o{
bio'trass
I
horever, th,-,
raLe
ll
r-,1r;r-,nr--r.tr-
iort
Lrf
,.1,
l-
't'
I
I
Tlre
physical
and chernic.tl
factors.responsihle
fer li:rri';ing alqa'l
.;rr'*'lh
n!
€
diff
icull to ns5ess.
Although h:iglter
i{at.?r
Lerrp{:r'alures
afr{J
i}i)vre!-
plnnt
operation
appeared to
have
aftected
aloal activity,
t,he
irnpact
of lhes*
factors
is
rJifficult
to
dgsess
because the statitln
in
tttis
coolinq
I'rke
thaL.rras
li:.rst
affecte<J by
tlre
power
plant,
SLation
4,
wds
very
dif
tcrent
f
rorn
Ihe
olirer
,l
,:;,..
:'
slalions
in
ol.her #ays,
rnaking
conparisoris
<Jifficult. LighL
inLensiLy.was
.r.':'',j,'
was by
far the
gr:eatr:s1", Nutrients were illgo dif
ferenl
at Slation
4 since
phosphorus,
rriLrogen arirl cdrb0n
(alkal
irrity)
conccrltraIioris
at
Station 4
lll
..-.::.,,"
varied
frorn tlle
other
l.hree staL,ions. ln
addiLion, some
of thcse
par'arnettrs
,:l:::.'.1:
'
=_.,-
between
the,.tuo
years.
Alkal
iniLy'wds
increased
1n l9B0
over
1979,
lirus
=,.,,,,-..-,.:providing
a'gr:eaLer
carhon sourCe''dg
well ds
!n0re
adeqriatcly brrf
fer'ed,'vla'Ler'.
,'
.'
'
Al so at
StaLion
4,
turbldity was Inuch
less irt
l9B0
tlran
irr 1979,
anrt
Lhe
.j.':.
''
',
,:..,. ,r-
.,..',..4
,.
:::'
:
t,',''t'
,
;
t;"
:.
..
:
"
''
:,;;',:,t,,":
,",::,
a'.,-'it'
l:
nutrient
I lmit,ing,facto,
r,
shif
ted
f
rom
nltrogen
lo
phosplrorirs.
Ai
I
of
lre:,e
factors
could have beert
important In
determining
Lhe arnount
of
algal
activiry
l
a1d,in
determining
the
composition
of the algal spr-'cies
presenL.
tlowever,
the
!le,af
gradient
-or'9h]-o-19.phyt]
g
present
from tlie discharge:ar"ln,!q.lhe.101.
11
uf.!
.
of tlte
11rg
(ris,.-
3.1?). strongly
suqgests a
direct
irnpacL
of
power plant
operations
on
algal
activity.
3.35
::
::.
':l
.
'l
:a.
,l
r
''l
L'iT[llAillR[
C'ITIO
'
Barr,.f,.l,l
J.li,_Coodnig!!,.J.p.
Sall,
arrd
,).T.
tlr:lwig.
l97fi.
A
r;r,cr,r
guirtr
.Los.As/6,SASInstitute,Inc,,.Aaleiqh,r{C.]2qpp
Brigham,
A'.R,
lg8l-.
l{ater
quality
in
a
cooling
watcr rsservoir.
In
R,t,l.
..of,.anlllinoiscoolinglake..:|llinois{atur.altlisLorySurveyllrilletin
'
Larirnore'and
J.A. h"anqtiilli,
eds.,
Ilre
Lj[e iiug.iriii
iir,ry'
-do*n
hisrory
3?(a):290-319.
Coutantr
L'!.
1980.
Algal
investigai;ions
of
Coffeen
Lake.
ln J.A..
t,-unqoitti
'. and
R'!,l.
Larim0re,
6ds,,
Envir6nmental
Studies:of
Coireun
rii*,
SecLion
5,
flatural
History
Survey,
Dif
f
on:
l:i:,
and,F.H.
Rigler.
lgl4.
The
phosphorus
-
chlorophylt
reiationstrip
in
lakes.
Limnol.
0ceanogr.
l9(5):l6t-773.
Harvey,
l{.tI.
.l960.
Tle
chemistry
antl
fertil
iLy
of
sea
water-s.
cambridqe
univ.
Press.
,
London
. 240
ttp.
tlutchirrson,
G.E.
1957.
A Treatise
on Limnology.
\,o1.
I,
part
2.
and
Sorrs,
Inc ,
,
l,lew
york.
l0l
5
pp
Jirka,
/r.14.,
and
M.J.
Carter.
lglS.
Anai.
Che;n.47(B):139/.
King,,:[J.1.
1970.
The
role
of
carboir in
eutrophication.
Jourrral
!later
Pol lution
Control
Federation
4Z:2035-2051
Liehr,,,s.
1979.
cof
feen
Lake water
qua'i
ity.
In
J.A. rran'qui
ll
i
'
Larirnore,
eds.
,
Envirorrrnental
studies
br cd-f,reen
Lake:
'
First
to
central
Il linois
Public
service
cornpany.
Il
linois tiaLural
Survey
,)ohn
i,liley
and
R.t,l.
Annual lieport
Hi
story
t
I
I
I
I
t
t
I
Liehr-stor:ck,
s.
.l980.
coffeen
Lake
water
quality,.
In
J.A. Tranquilli
arrd
!.ri,.
-Larirnore,
eds.
,
Environmental
Studi'es
of-CofT-een
Lake: ieconO
nnnuaf
'
fl9n9.t
to
Central Il
I
inojs
Publ
ic Service
Ccrnpany.
Il
I inois
Natur.al
.
.,
l{i
s
tory
Survey.
Park,.P.K.
.1969.
0ce1n c02
systenr:
An
cvaluation
of ten
rnethorls
of
investigation.
Linrno
l. 0ce.rnogr.
i4:119,
.',
,,1.
Pomeroy,
:
Science:131:1731-1732.
L.R.
.l?60.
Residence
time
'
of
:
rlissolved plrosphaLe
:
irr
naLur.dl
:
,
waters.
Riglea,
,
,
Li
mno
F.H.
l ogy
''
lsJ!,
263-?7
-!!osphorus
3.
cycling
.
::
in
lakes.
:-
In
F.
[luther.,
Funrlarnent]ats:of
-
I
1,.
T
I
.
:
I
I
i
I
..
:':
I
3.36
sotso,ql-l:l.!yl{l,
fteport
1".
lg!!,
r.97t
,
l1
[e+1o9y
'{,1n.",uttanrs
r,
tnc.
'. Inrr-;.r.:.rl
oemons[ratlonpur5Uantto..,Jllinoisl'olTJt-icin{]onil,':lB+ar.Jt,u|esart,J
l!sulations,
Centrol
tllj.nois,public
Servir_e
li:,np,iny.,-iofir,r,n
po"r,i'
]:..Stalion,..unit5.lanr|?,Hay3.|,|g77,-
Stanrlard
lrtethoris.
f or
the
Examinat
ion
of
'daler
cnrl
.rynerican
Puhl
ic. l{ealth
Ass'sciation,
Aner icrrn
,',
l.lash
i ngton,
0C
.
874
pp.
lJatf
ewater
,
I
4Llt
rrl,
197
6 .
i.later
'r'lorks
Astor;
iat
itin,
I'letzel,
R.G,
1975.
Limnology.
l,J,B.
Saunrlers
Conrpony. Phila6elpiria.
/,11
pp.
.:
.:'
3. 37
t-=-
il-'
:
tl,
t-=,
''
I
'
SECTI0ll
il
Cllil'l
I CAL,C0ll5T
ITLtl,lt
I5
ul
h'Y
. '::
,' .
,
,.,
Susanne
G.
l.lood
'and
Teresa
A. Schu
l
ler
i'
,"
ABST
RAC 1
A,
three-year stutiy
of the
chemical c'onstituents
presenl
in
Coffeen Lake
was
'.
undertaken
as
part
of
a
multi-disciplinary
3-year investigati0n
t0
evaluate
"
.
the
enviionnrental effects
of CIPS Coffeen Power
Statjon
on
Coffeen Lake.
Major
changes
in the disposal of
coal combust'ion wastes and the discharge of
waste-
water
at
the
povrer
plant
were irnplemented
between
l4arch
l97B
and
llovcrnber'1979
for
the
purpose
of
reducing the amount.rf
pollutants
eriterirrg the lake. The
major obiective
of thjs study
was to
determine
how effective
these changes
wer-C.
f,later,
sediments, sediment
cortss, two species
of macrophyes,
dncl'six
species
'
of fishes
were analyzed
for thei r contents,:of
chemical consti
tuents.
The
concentrations
of chemical
constituents that sornetimes accurnulate
to
unde-
sirable
levels
in
aquatic
ecosystems
(Cd,
Cr, llg, Pb, and Se)
were corrsidercd
to
,be
of
pat'amount'importance.
Pb
concentrations
were Lrelow
the
detection
linrit
of
the analytical'irrstrutnent for most of the samples.
0f
the
four:ecosystem
con-,
ponents
showing measurable Pb concentrations
cluring
the first
year (pondrveed
an,l
three species
of fish), on'ly one fish
species
conLajnecl
measurable
aruounts. during
the second
year.
None of the ecosystem cornponents
contained measur^ab1e
levels
of
Pb
during the
final
year,
a,
gratifying
fin<ling
when
improvenent
in
environ-'
mental
quality
is
the
aim.
,,
.'ln
the
present
,study,
the
steady
decrease
'in
Cd concen
tra t
ions
i
n
a 1
I ecosys
tem
conrponents
rluring
the 3-year
period
is
indicative
of
improvement in
environ-
mantal
quality.
The
same
conclusion
can
be
drawn for
Cr antJ
tlg. These
decreas-
ing trends
are reflections of similar
decreases
in
the
surrounding nrilieu.
l,-
1""
!,.
,.
'.a
I
'l
:.
.,1
t
'l'
l'
''
T.
.
:.:
1.,'
'
,
I
'"'
..'
.:
l
I''"',
I
.:
I
'l
There has
been:,concern
aboutr,the reported
,reproductive
f a,i
lure
,in
f
ishe.s inhabi
t-
ing
lakes
that
are
subject to
expoiure
to
industrial
wastes. lrr
the
piesent,t'
study, the
annual
nrean
concentrations
of
Se in six
species
of
fish
taken
Frorn
,:
::;
:,
.
a:
'.:a:a,:
:
4.1
rr':::
j:::
cof
feen
Lake
between'
lg/B
and
lg8l ra'nge,J
from less
lhan ilrr.r
rierccLion
l inr.it of
the analytical
instrument
(0.29
pfrn)
to
1.B9
ppn.
All of
these
levels are
well
within
the
range
of
concentrations
(0.5-i,0
pm)
repcrted
for fishes
frcrl
another
lake
wherc
fish
reproduction
was
norrnal. Ihus,
thc
reproducljvc
:,urcers
of
fishes in
coffeen
Lake should
not
be
affected
by
5e
at
the
presen[.
The
overall
conclusion
for
this
3-year
study
of
the clrenrical
conslituents
in
Coffeen
Lake might
best
be stated
as:
improvanents
in
the disposal
of
the
coal
cotnbustion
wastes and
the discharge
of
the wastewater
generaterl
by the
power
'plant
have ied
to a
s.ignificant improvement
i'n
the
unuironnun*,
nruiiry
or
lru
I
ake' s
ecosystem.
I
I
t
I
t
t
I
I
I
I
I
I
:
]::
T
I
I
I
:.
:.
:.:
:
.l::.
:..::.
l.'
4,2
.-;:;:
t
:.:,
-.,
I.
'
-lt:
:
l.
'I
t:
.:..:
a"r
:
,.
I.
-l
,::,r,:
!,
r
I.
a-
-,
I:
::a'a.::
::-:i.
-:
IT:
:1:-;::i
:t:
'
:l:
l
t,,
'
::;
'--'
j
:
:.
:..,
-',
-'i
i
:
lliiftI--:0ucl
l0li
,
'
::
The
neerl
for large
quantities
of
waLci
to caoJ
etea$
in
i:lecLric-qeficr*?.j,t!
statjonS
has
resulted
in
constructiorr
of
nlany
lal:cs
in re{cnt yeaf5.
',.lhen
Lhe
j.'...
generating
stations
dsSociated
with
these
latres are
fucied
vdith
{odl, csrbustion'
wastes
are
a
source
of
trace
metdl
c0ntamination
t0
boLh
the latres
an<!
the
surroundjng
ldnds.
'Coffeen
Lal,e,
which was
bui lt in
i963
to
provide
wate'r
for ',
Central
Il'linois
Public
Service
Conpany's.Cof
feen.Power Plant,
is one
such''lake,l
Because
little
outflotr
nonnally
occurs,
this lake retains
almost all
of
the
,
i.hemical
constjtuents
entering
by
means
ot': both
the
thermal effluent
frcm
the
Power
plant
and
the
inflowing
waterfroin
the'lake's:watershed.
Loss of
water
'
from
the lake via
evaporation
concentrates
the chemjcal constituenLs.
Dressen
eta,|'(l9i7}andGriffineta.|'(l97B)<lemonstratedthatnanymetalsin.s.la9
.:
and
fly ash -
waste
products
of burned
coal
-
have substantial
solubjlities when
leached
by water.
Sjnce
these leachates
entered Coffeen
Lake
frorn
1965
to
1,978, enhalcemelt
of
the lake's chemicaJ
constituent
conLent
and
concoritant
deter:ioration
of i
ts,
water
qual
i ty were distjnct
possitri
I i ti
es.
-
l
,.fvl6j6l.changes
in
thc
disposal of
coal combustion vrastes and
the dischlrge
of
wastewater at
the
Coffeen
Ponel
Plant,
which
were
nrade
betryealr
l4arch
l97B and
November
1979,
great'ly
reduced
the
anrount
of
pollutants
entering
Coffeen,Lake,
Because of these
changes, the overal'l
qual'ity
of
Lhe lake's
water,
sedinrents,
and biota
may
have
begun
to improve,. In
particular,
concentrations
of chsnical
,
constituentslin sedinrents
and biota
rnay
have begun
to
clecljne.
Thus,
the
objec.
tives of this study
were twofold:
(l)
to deterrnine
concentrations
of
cher,rjcal
constituents in selected components of
the lake's
ecosystem during
the
Lime dis-
posal
of combustion wastes and wastewater
was irnprovecl,
ancl
(2)
to assess
the
recovery
of the lake
by
tnoniloting
changes
in concentrations
of
cheinical
con-
stituents cluring the
following two
years.
The first objective
was
addressed
'between
September
and ,lune
Lglg, the
results
of vrhich
r.Jere reported
by
Smith
and
Duda
(1979).
The
second report
analyzed
and
interpretecl
data
coliecterJ fronr
,'.'July
i979 to,June
1980, i.e,,
the
first
year
of
recovery
of
the lake
follovling:-
modifications
of
the
combustion waste disposal
and
the
wastewater
discharge
into
t.'the
,lake
(Anderson
-et
al.
.19S0).
The
preient
report
ana'lyzes
and interprets
::
the data collected
from July
1980
to December
1980, i.e.,
the second
year
of
4.3
:
:
,,.
.j-.
|
:
recotery
of
the
'lake''.
.Ihis
report,also
jntarpt"cts,thB
rcsul Ls
of
the
3-yeai'
investigatjon
of
tlre lake's ccosystem.
Samples
j
of water,
sediment, macrophytes,
and fishes
vrere
andlyzerJ
for
silver'
::
,.
i
:
(Ag),.,
arsenic
(As),
boron
(B),
bariunt
(tla),
calciuru
(Ca),
cadniunr
{Cd),
chranium
(Cr),
copper
(Cu),
iron
(Fe),
nrercury
(119),
potassium
(K),
rnagnesirrnr
(l,lg),
manganese
(Mn),
sodium
(Na),
nickel
,,(f,li),
lead
(Pb)
,
selenium
(Se),
antj
z'inc
(Zn).,
Coal,
slag,
,a'nd
f ly ash samples
were analyzed for tlr.
abo'..e
constituents
plus
aluminum
(Al),
cobalt
(Co), phosphorus
(P).'silicon
(Si),
and
titiinium
(Ti),
Water'
r*as
also
analyzed for
cyani'de.(Ct'I.
)
,
'.
CTUDY
J I
VU
I
AREA
arllLrr
The
Coffeen Power Plant
is a 945-H|.J
generating
station
located in southeastern
Montgonery
County of central Illinojs, The
first unif
(350-l'ltl)
began
generating
electricity
for corunercial consumption
jn
1965,
and,
the second unjt''(595-MI,l) went
on
line
in
1972. Fuel
burned at this
facility
is'primarjly
Nurrrber G coal
that
.isobtainedfromashaftmjne(Consoll1i]lsboroMine)locate<lac|jacenttothe
plant.
Number
6
(Herrin)
coal
is
fhe
most
extensi'vely
rnined
coal
in
I
ll
jnoi
s
l
(Ruc.hetal.1971).Thep1antconsunted2.0Bmil]iontonsofhigh.su.lfur(3'.4
percent)
Number 6 coal and
2.21
mjllion
tons
of
total:coal
in
1978:(Lin and
Dotter
1979).
Coal
burned
in the
Coffeen
Plant is reduced
to approximately 23
percent
of its original
nrass;
about 70
percent
of
the
residue
is slag
(bottcnr
ash)..andtheremainderisf1yash(JanetKennedy'pers.conn').Thef1yashis
removed
fronr
thersnroke
by electrostatic
precipitators.
From 1965
to 1978,
the
i,
:::
slag.and
fly ash were
sluiced
to
an'area
located to the east of the'power
plant
.
and:in close
proxim'ity,to
the east
(heated)
arnr of
the
lake.
Leachates in
the
returned
sluice
water entered
the lake unabated near
the
thermal discharge.
Because
of changes
beginning
jn
March
1978
and completed
in
Novemb'er 1979,
the
slag'-'is
now
dewatered
in
bins
and:then transported'by
truck
to
a slag
storage
,',.
area
(formerly
the
slag
pond),
and fly ash is
accurltulated in
a
silo ancl
then
trucked
several
mi'les to
an approved
landfill site'.
.:.
T
I
I
t
T
I
I
T
t
t
I
I
l,
I
t
'
T
a man-made
impoundment
with 420 ha,'of surface
area, and
a
water
t
.'...:...
.1,,
x 10/
mJ.
For
a
'
nrore
:-.
detailed
description
,
,
of the,.rnorpho-
1::1
,tl.
t,,
.
'
'..a
,
'.,
:i
4.4
I
t,
I
l
-
:.
I
,l
t',
I
:
I
,l
,.,]'
,l
:,
,I
.''.
I
:l
'l
logical
chardcteristics
of
the lakc,
the reader is refen'ed
to
Sccticn I
of
this
docunent.
ln accordance
witlr
tlre
interdiscipl
inary approach
to
conducting
investigations
at the lake, four majo!'sarrrplin{]
siat'ions
vrera,
estal
ished
by mutual
agrecment
with other
researchers.
StaLir.,ri
I rvas
iocdLed
in
the
thenna) discharfe
ann,
Stdtion
2
yras
est(rbl
j
shed
near
the
r,ridpoint
of
the
cooling
loop, Station
3
lvas
situate'd'north
of
the
intak.e
bay
alr<J is consjdered
a
transition
zone,
and
Station 4
was located
north of thr railroao
cduseway'and
is'
regarded
as
the ambient
area
(Fig.
1.2). In
addition, ancillary
stations vrere
nrJ'3
for
scne
aspecLs
of
this
stud.v;
these
were designated
Statjon
1,5 and
Sration
2.5, respectively.
"
Materials and
methods
for this study:wera
nodified foliowinq
the
first
year
of
investigation.
The
four
maior
sfations
reoajned
the same throughcut
the
sturly's
duration,
but two ancillary
stations,1.5
and
2.5
(see
Fig.
l;2), werc added
during
lhe
second
and
thjrd
years
of"study.
0ther minop
changes inclutjecli
(l)
reducing
the collection
of
water samples
to
once
a nronth,
(2)
elinrinatingrthe
fjltering
of
the water sarples,
(3)
discontinuing
the cyanide analysls
following
the June
l9B0 water collection,
(4)
adding
three'spec.ies of fish
during
the
third
year
of study,
(5)
obtaining
a
nrore
thorough
collection of nracrophytes
during the
second
and
third
years
of
investjgaLion,
(6)
collecting ancl analyzing
sedirnent core samples
in
the
third
year, (i)
collecting and analyzing
coal,
slag, and fly
ash samples from 0ctober
1980 through
February
1981,
(B)
con-
ducting
Na
and
K analyses by enlission
spectrophotonretry,
and
(9)
nroclifying
the..l
thi
r<J
year.
SMPLE
COLLECTI
ON
Table 4.1
lists
the total nunrber of samples
collected for
the chernjcal
constituents
portion
of
this study
frorn Septernber
1978'.through
l'|ay,.l9B1.
''
hlatct",
samples were collected
daily
"during
one
week each in Septenrt,'r
and 0ctober
1978.
Duplicate unfiltered and
filtered
(0.45-micron)
vtater
sarnplcs
were
collectecl
monthly from
Novernber
1978 through June i979.
Quadruplicatc
unfjltered
rvater
samples were collected monthly fronr July
1979
through
Decerrrber
1980, All
water
4.5
a...
''r:.
:
.;
:
:
'
I
:,.
Tabl,e
4.
1 .
Tota
l, nurnber
:
.
constituents
:,
of
sanrp'.ies.col
lecterl,:and
.tn,Jiyred
f
or chen
jcal
frorn
September
197[J
i,hr.ourltr
.].rly
l9Bl,
'l
I
I
r
978-79
't9
I
79-
B0
tq*0-8t
Tolal,by,:lype
l{a
ter
/.rl-
t, ll
Macrophyte
s
--___-
A.mer
lcan
Pondweed
C''cep
inq l,laterpr
i
mrose
Sed
iment
330
120
I
t
1
B
50
33
t6
tB?.
96
oA
6il8
?48
(5
35
6B
t)
2l
30
v
ll
JIJ
Fish
,:
,
La'rgemouth
Bass
:
:,
6i
zzard Shad
.
,
Bl
ack BuI
Ihead
Car
p
'
Bluegill
: Channel
Catfish
Cores
,coil-
Fly
nsn
Yearly
Totals
Grand,Total
40
40
20
40
40
t2
2A
?0
20
30
20
3?
30
453
r30
il3
.:i
4B
:
20
?0
20
30
.20
:
,30
56t
428
1
,447
4.6
I
I
I
I
I
I
t
samples col
leCLt:d fOr
chenicai con:tituent r:rr,ri;',ii;
i;i:i'i ,lirl;-,r;l t;i'iert'
:.lmi:le:
and we re
preserved
with
rtitric
a|i rJ
i0.iji
f
iriir I
i':",:.q',
f
r',tt'ii r:;.
r,ltllr'
:rr;:tl,ie:
fOr.=Cyanide
(Cl|-)
analySi5'dere
Z,liler
5y1-f,3r--11
Sitrlijrlei
r-*iiti,lilj
i:-r .: ,.
'ri.tte
lrorn
Septenber
l97B through.]une 1979 and
1;r^eir:r'verj
uiilr
,,crjl.-r:'-
i;-,,dr"+r.
i')r
'..;.?.
final
concentration). All
salripies
for rjicrlsurel0(:fri-i,
{,f
iili.:::ii,1 i
c,lr,rLltL;rlri1
were|efri:::1.-1.untilana-ly:ad;.:aix|]e5l*rc.viltii;j8.1t:!.€r'lr'i:iiLj0l.iwi:t.t
ana1yzedwithin24hoursafterco'ilect.ion,
Bottorn
serlintent
sanples were collacted ir, tha
falI
af i978
at
the
four
rr;aji:r'
stations
(Fig.
1.2). llrring spring
an,J
f al I of lrij.ii,
b0ttcn sr-^dinrr,nI
salnpies
r,rere
collected at the
four
major anrj Lhe
t''/c
dncil).rry
staiiorrs
itig.
i.;i].
A
15,2-cm x
15,Z-cn x 15,2-cm
Eknan drecJge wjih a
chaniller
volunre
of
i540
*,3
was
used to col
lect sedimqnt
frorn
tlre
lahe botLom;
the Loli
? crn
c{
nrat.c.ri.r
I wer'e
retained for
analysis,
Shore line sanrplcs
cofrtaininr.;
trinrari
ly
sand
vtere
disallowed during
the final tvro
yedrs
of
the
sLurty.
All
srmples r,rere
fr'0ren
un
ti
I
prepdred
for ana
lys i s ,
.
The
species
and
numbers
af
macrophyLe
sampies collecte<l
Flel
year
dre
givc.n
in
Table
4.1.
Creeping waterprjmrose
(Ju-s_s_g_qa
.LqIg$,)
vra,
co'llccted
dt Str!'r'ons
1, 2, and
4
in
September 1978,
at all four
inajor
stations
.in
Sr"
itefl;ber
1979,
and
at
al I four
rnajor an<l
the
tvro anci'llary stalions in Septerlbcr'
l9ll0.
l,io
waterprimrose
rvas
found
at Station
3 tlurinS
Lhe
i97B
colleutiorr
period.
Anerican
pondweed
(Potanrogeton
ry-{gs-qs)
was
collected at, only Station 3
in
September 1978,
at
Stations
2,3, and 4 in SepLeniber
1979,
and
at
Srdtions
2,3,
and
4 and the
two
ancjllary stations
in
Selltember 1'980. This
macrophyle
was
not found at
Station I during
any of
the
collecting
periods.
The
sarnples
were
stored in,polyethylene
bags urider
refrigeration
until
prepared
for'analysis,
Species of
fish collected
for
this
st,udy
inclurJed:
gizzard
shad
(Dprulg1g
cepedianunr),
a forage
fish;
black,bullhead
(tctaluigs-
ntelas),
a low trophic
level omnbVoie;
and laigeinouth
hiass
(l4jclgrle_t"q,s_
_g_l!Ul_d3_t),
a
higlt'trophic
level
carnivore.
,ln
addition
to
the above
speciesr, tha
following
fishes were
collected
during the
third
year
of
the
study:
carp
(lpf11uf
-c-ajpl-g.),
a low
trophic
level
oinivore;
bluegill
(Lep-omtt
rullqdfrutj";;;tl;0il
ono
channel
:''a
::
,
:
i
,l
t
:l
'
T
I
'l
I
I
I
q.7
ii'i
rlr::=';
::
.' .r::,
,'
:;,,t
r',;,
.:i.:.a'':
I
T
I
Cdtf
i5h
i
k_t{lU_':J.3
lijlilila-trtr,.
'r
loyr
',-rr-)l)n:i:
ir.yr, I
}:r
:,
,-i,.
',.f
:
,r-1iir.i,t ,
.;r
th€
..=.
f
islre: Here,
col
lecte:J
by
elee lra;'ishinrj- l,rl;ir-'
i.I
i:,.j,t,,
..i\,i:i
!
irtrr..,
:,-,.
SpgcieSranrJ
nunliel'
coll*ctcd
iier
/ear'+i
litr:
tnr{-.,,ii,'lnl-':
.r!":.
.:.,:,i
r...;t,.rrr-r'i'i
:
l
::
the
date and
point
of
col lcct,iqn dre
tjrr:
s{-:ritec
:rr
i,il;lr
.i,.:. ,i:i
! r',r;t.-,.
i{ir!'i.f
5'L$red
fIozcn
unlll
praparerl
for
anii.yiis.
'
:
,,'
Sedintertt
cores we re
collectsdrin
June
19i::0
u.iing
d
c0rcl'
:norJeileri
irf
Ler'liilrles*-
Ba'llchek
Sinqle Tube
Cqre Sanipler
l4odel
2ill
rvi th
3-$-slr-didircLr-,r'
5y 6l-r,ir-
icng.
plastic
col
laction
tubes dnrJ 5 llg
of
counLer!,rlighls
iFiq.
,t.l
,
. Ttre sarrrgles
yrsre
co'lecled
by
means
of
a
winch anrl
pulley
system
rnounted
cn
a
porrahrle
l;cat
crarre
wi".h
a
6-foot
hourr.
Iive
santples
per
sLatisn were
calleci.ed alorrg
tran5ects
at
Stations
I,
1.5, 2,
2.5,3,
and
4. The
tubcs were
lrbelc<t.
corl:ed, drrcl
frozen
un
tr I
prepared
for
ana
lys
i
s,
Coal
,
slag, arttl
f ly ash
samples
vrere col
lected
f
rom
0ctobcr,
17,
l9B0 Lhrougti
Febt'uary
2l, lg8l.
Coal santples
wc.re
taken
frun
conveyor
belts cltering,the
'
power
plant,
slag
from
the dewaterjng
bins, an<l f
ly aslr fisn
thc',f ly aslr'silo.
i
'
Col lections were
made
by
CIPS
personnel
from
zero to
[hree
t-inres
per
r.reett
during
tlte above-mentioned
periocl.
Sanrples vicre
individual
ly
storcd in
scolr.,d
po.|.yethy.|enebagsuntiiprepar.edforanalysis,
','
SAI4PLI
PREPARATI
OI.I
I'
lhe
water satnpleS required no additional
preparati0n
prior'to
analysis.',
'.,,.
,',1
Sedinrent satnples were freed of
excess water
by
decantation;
the sanples
wcre
I
then
placed
in 150- or 300-rnl Virtis bottles
and freeze-clried.
The freeze-dryer
I
used
in
sample
preparat'ion
was a
Virtis
Unitrap
i0-100 with
a l.telch
Duo-Seal
t
Moclel
iil402 vacuunl
puntp.
The sediment cores
werc spliL
iengthwise
and
sectioned
into
six
3-to-B-cm segments, representing
recent sedinrent,
four interrnediate
I
sedimentation deposits, and an
origina.l
sediment. The seqments
yrere
thelt
iieeie-aried
'as'above.-
A'nibrtaF arrd:
oer
pestlo
was
uSeid- to
grjnd
and-lronogen]ze
-
the sedirnent
t::
and''sediment
:
core'sample'i. sufficiontl.y
to
pass
a
1O0-nresh
1y1on
,'
I
sieve.
For
ntacrophytes, a
thorough
washing with
tap
water-ren,oved nrud
and
other
ex'traneous
naterial.
fhe sanples
were rinsed
several
t'imes wjth
deionjzed
:'.,
,
,:,
i
waier
and,:'thoroughly
diainedi,,ghg
leaves and
stenrs were
separated,' weighecl,
,.:
..
i.
4.8
il
.T
I
t
T
I
I
.T
,l
I
:l
.l
't
..'
.:
'l
-::l
I
I
I
I
I
Iable
4,2.
Cr:llee
llon
rtate,
i*1lr::?trirl
pti:1.-!
*
i:,;r,!;;r,
:
{)hl
a i
nq:El
f
ro{
Cr;
f {eeir
:,-t
i:€
.
0ate
Col
lecterj
i.if i
Ir'r?
ii:fi
tir,it,r
..
5t at.
i
*r:
!
5l
at
ir,:ri
?
','i
if
i
rr1
1
i,i;l
ii:n
t
T
t
I
I
I
'
ll78-
l
97e-
0etober
l97B
.f{o'rernber
l97B
March
I 979
,rel9:l
iqQ
Novernber
'1979
January
l
9B0
,
March
I 980
I
980-t 9Bl '
May
1 980
September
l9B0
November
I
980
4
'Ll4u
5
SHAO
5 LI4B
IO
LMB
IO SHAD
I BLKBIJ
,3
BLKBLI
I BLKBH
l0.tMB
IO SHAD
5 CARP
5
BGILL
5 CCAT
5
Lr4ti
6
5|fAS.
2 BLKBi!
l0
Ll,lB
.
l0
5ttA0
,
2
llLXBtl
3
BLKBH
IO LMB
IO SHAD
1
BLKBH
5.CARP
.
5
EGItL
5 CCAT
5
Lflii
5 SliAii
5
Sl{A3
5
ftLKgr{
IO
LMB.
r0
SHA|
4
llLKBl.{
l0
LMU
I
O SHAD
I
BLKBH
5 CARP
5
BGILL
5 CCAT
2[r
L
t4tl
&
:;iiA'J
'i
gi
l,titl
5
Lf.lB
5
SiJAtr
5 BLKB}I
l0 Lf'tB
l0
5t{Ac
6
SLKSrj
I
O
BLKBH
l0 silA0
iO LMB
5
CARP
5
BGILL
5
CCAT
-LMB
=
Largemouth
Bass,
SHAD
=
Giizarcl Shact,
BLKBIJ
=
Ulack
Bullhead,
CARP
=
Carp,
BGILL=Bluegi.!l'CCAT=Channe]..Catfish.::
:-.'1,
I
-
i
tl
:,,,.,
t
I
!;;':
i
4.s
..a.:
ra
'
.
I
I
I
I
I
t
I
!
I
t
I
l
J
a
'i
'I
:i
''=l
:l
!
{
.
'_:f:!P:.'ir'^
::I
.
:l
,t
,
rl
:.,
I
:
:l
T
T
I
I
I
!
I
'l
I
l-'
.
t.ii"
l-=
1",
I::'
I::
I:':
-:
and
f
f0czt-,-drig.:j
ln
,il'l:i\j1:tt:.
t,:i'l
i'jd:,..
,,,t:i
:
,-t..
,
t,,
.r..r.
,t
'':t.
itrvastigation, lenf
altd
tLi::!i !'tii;rlt?'j Hr:r"{.
l,rr',,,:.,
,,.t
i,i
;
,:
.:,,
,.r.;3 1,..
iitrji.v'idua]}7irrta;ic;;,11i1.;;e!jEhJt,'di!il.r;,.1.Jl!l:r:,1ir''}:iil'lj.i].ilr..:Jlii..?':
mdnipulatinq
lry
iiand.
[r.iri611
llir.
riii]',r
.i.'.1'-
:':
i]r.
1: ,,ti,
..r,i;:.,,
ri,,!.!r
i..t
,,
1
ln
-polystyrcne'.
litlttig: wiLti
ie';t,r'rtl
i..i.r<.ti{-
irr}*:irt
,rr=i,: l,i:.-i.;:,.rrr
/r-.-t
,',i:;r:
J
-=i:Br
,
fJCt0'J'll rni;ter/ntil.
l'isri
i{t:re
ttrowtrjr
:i_i
il}r.,d!:j,'rr'l
,irjl:jtt: ,
riirl
r{.:,1,1..1
.
,i
r
iljet
(muscle
tissuei ir,ts
rein0vprj
frcsn
earh
f
iih
iiler:i.',(rri,
iui
i,,,;,.:-rlrr,r,,.
i,
l;rcr..l
rr:
plastiC
rcighiltg
ba*ls,
and
i,hen
frer:re-.lr'ic,,J.
ihr:
!rt:rille l.::.rnr'igr.:rii,l,lr-',ori
proceclure
duplrcate,J
thof
of
11.,s
lrdclcpirytes,
irl l
J r.,-,rzc-4rir,rj
.,;r:;,.ii:s
wflfE
LoierJ
in
pOlyethylenr-i
tioltlcs
at
r0rr:r
tei:iucr',if
rrr'r,
,,rrlLil
*li.ruL,t9 i{Fli1
nte{jrjrJ
ror. rligestion.
Coal, slag, and
fly
ash
sanples were
nir-dr'jerl.
ecrnblr':erl
b1
l.;rpe, and Lhen
r,
sorted by means
of
a riffie
to obtain reirr'esenlative
ruLisanples l-cr.anaJ;ti,-s.
Four
subsantpl
es
of edch type wet'c
prep,rrccl
L{r
re
prescn
t
i-he
f nrir
orru-r'lont h
perio<ls
(0ctobcr
17, l9fj0-tlovcmber 15,
l9B0;
Novernber
l{r, lgti0-Uecenber
15,
l9B0; Decernber
16, i9ll0-Janua,'y
tS,
igBl;
,rnrJ
January
16,
lgtjl-l'uhrrraly ?i,
lg8l
)
of Lhis subpro.iecL.
Tltese
fou:'
subsatnples
of
etclr type werc
qraurtrt
'.*o
tncet
[he specifications
for
analysis
of
thc Illjrrois SLdLe
G*oloili,.,il
5ur'vey.
SAI4PLIDIGISTION
:
.
:
:]
:
.
All.sarnplesweredigestedandanalyzed.in<lup|icaLet'hroughouttlrestudy'Tlre
vrater samples required digestion only for
rnercury
(llg)
analysis. PoLassiurr
persul
fate
(K2S20g)
solution t,lds
aclderl
to
the sanrples
to
f ree
arry llg
thaL
was
adsorbed
on
particu'late
matter in
the watcr
(il-Awarly
eL
dl,
1976). Af
ter
one'. hour, the samples
r{ere analyzed for
}lg
as
descnilled below.
The
deterrninatjon,of total CN-
in
vrater'samples
fronr Septernber
lgTB
through
June
:
l9B0
vras
perforrned
accorc.ling
t,o the
U.S. EPA
standarri
rncLhorl
(Kopp
ant l.lcKee
LgTg), ihe
cyanide was
released in the fontr
ol' hydrogen
cy{lridr.:
(t{CN)
fronr
the
a
the
r-,
I::-:i:
I:::
I:
-.
t'-
I,
I.,
l=
I,'
t
E
:
:.:..
I
l,::
I.r
I:',
:'
I.
t::
,
I..
I.:
f.
-t,
I
:::.
I
I
Il
l-
r,
I.
Hater-by-reflux--distillation
chloride',(Fig',4.2).
The cyanide
in the-presence
as
the cyanide
of
srJlfurjc
ion.was
acid
then obsorbed
and
coDper
in
scrubber
containing sodium
hydroxide.
Cyanicle standards
were
treatcd
in
.:
..
,:
t
::
sanre
-,
:.
manner,
::
:
...
,
:
,
:.
l
-
4.11
c0fi.tr{ff
ilHtn
ll{[t
I IiJBt
*
lltllt[
*
SCetif
ctAHP
'I
I
,I0
l.{}tt
VtCUUll
,
$0uRct
'
lBson8[R
1
0tsIil.t
llt0,
tLAs|(
IH
0ut
"l
-'l
.'l,l',
t,,,
,'
'.1'
'
''l
t;;.;','
'
:j.
:
"I
::r.
"'
l'
,
:
'-l
:'j
'.
"l
.,
.....
l
T
....:.
'l
'-'l
--t
:1_
I
,'
..1
: .:: ::
c0rt0il{stR
-'-l
Figure 4.2.
.:'
Diagram of
distillation
apparatus
frorn
water
samples.
r:
'
used
for
recovering
cyanide
4.12
,'
, ,-il-i::
'''.
:':.':
Il,:
I::'r'
Ir,
j
:,a
l,r.,
I:','
:'. .'
l,
f
.:
i.:
l'
'"
I
I
t
I
I
I
I
,l
I
I
I
I
3he
*aLt+=
9ef
irec
t:
;:n,:i
5!:r"::
i:-?€;
!.
,
,:r-r,
..,1-';
i
;
'
,
,
ilorl'>tituetrl
drn}ySii rigirt* {
;::*-'jiIt'a1
1!'rtr
i-,
:,r,
f'ertln-[ir+*'
ii'l;L,.
,1
,jll,itl
ir,'j
.it\:t:..,
f
r,;:'
(ti75*4i
acrd;'nd,. a,-rdrd
t*
:,-':
.:cr':;ilr.,:'rr:
trthff
tO Qr l?'dc i
Orr
I
7
tlrv
r
a
1i;:J1
i
441rr;'l,r'ri
lrntfllt
cf the
'ledlF{:rit
i
i,-.,F}
f
.
ilir:
sc-i;1+,r
BrrtngxiCl:
rotar''
Shahrtr
dnd
iilr:ri
r:(jf:irltu4r:.j
Tan-nl
fr]
i.tuotg
Of
ihe sup{:rndtdilt-t nr,rq
di i
stored in
polyethyl
enr:
b0fi ini
rlrrt
i
'l
atl I
y1,
l
I
1
i:r-::l:
.
.;::,:1
;r'!:':1
,;t
t?:
:1+
1:)
:
i=f
l-
lxtraction
of
iig
frocn
the
Sedi*irjnt5
Joil
i€i:i!:;rr.
l rqrir
',n.riii,-,,.
,r.]i, arir;;:i;l
i!nrr:
usirlt n
r.r?odjf
icaLion
of
the
mtrlrarl rie'rcritird
tr;,.
Jrrcebs
,lrrd
i.{jsrej'
i
!,ji
I
j. Li:y*
regifl
(UCt:lttfOr,
l:l bI vol.
i
H.1s aCCar!
t$ 2-q
<,11:r1i'l
i,i
iri
z-ti0-:;.!
w!4r:,ri,{r;i-li
Erlenmeyer
f
lasks.
The
.,amples
uL)r'r
boiltrC
l,irlrtroul
j
/
f c'
ono
';irrui.r:.
Af
uer the saml, les
hdd
cooled,
al iquots
of
i
ilorJsTirlr'!
fJ0ri;iJitri,lnitL(:
{i1..Ir,0,1
i
ond
X2S20g
solutions
were
odtJcrl
Lo lhr
f
larhs, i,.ihich
rirrr'r-,
lhf,fi
trlrrruij
irr
tr
qSoC
nalu"
bath
for'30
minuLes,
l)rrring
this
r1i,;esti(,r)
i)eriod
Enall
iiilal1trlr*s
of
crystallinc
lJ'ln0.,t r./er'c
addet! to the
531npler
lrr
maintair' tr!r
()r,itjieirr,r
environment.
The
sarnples
were
coolad
r
cafltlifugerl
,
diluLeri
Lo a l:no,*n
voiirllc
(100
ml
),
an<l
analyzed within
a
few
horrrs ds dnqcriber!
belorv.
lcr analyi'e
nacrophytc
and f ish'samples for
chslir:al c0rlsLituents wi
th tlre
exception
oF llg,
a toLal cligest ion
was
required.
/i
5:l nrixturc
of
nitr.ic
acid
(l{N03)
and
per.chloric
acid
(llCl04)
vras addeqJ
lo
l-g
samples wlri:ch
haiJ been
preweighed
into
150-rnl
round-bottonr
di
sti'l lation
f lasks. The
f
lasks rer.e
hea.tedonaKontesRotary.KjeldahlDistjl.|ationApparatusuntiJthel{N03had
decomposed
(clisappearance
of rerldish-brown
funres)
and rJense
whi
Le l.|C104
funles
appeared.
Af ter cool
ing,
the
santples
wcrc
di
luted
Lo arr apgrropriaLa
volurne
(25
or
50 nrl). Thjs
final
volume
was
zBX,
12i, and
5?.with
respecL
to
ltCl04
con-
centration
in the
first,
second,
ancl
third
years!
respectively,
of
the
investj-
gl!,ion:
-The
macroplryte
di
ges
ts
were
cen
tri f
uged Lo retnove
i
nsol
ub'le
s i
I i c'ates
.'
;s
ol
ved w
i th t
ime
,
nra k'i ng
I
centri
fugation unnecessary.
,l
i;
':
iI
*
.:,.:,.:-rt1;
l t:.,1,1.
..,
,".,;-1:.,
..,:...,i;',.,,
.',.,.
4.13
iJiqgSli$fiS
Of
t-:itCfgtrhytrl
t1{i t'ifr
,,C.i:riq,,
r1_,.
.r.
rlf.,,ir
...,
,,.,:..
.;..:
,.r..i.,
t-,r.,,
.
trSint
d
nO,Jif
ifaliOn
q,1
ihr:
*,i'il;r;:!
ui
l.iiiii.1*,:,,,
,i.,)
.:.-,rr:
rl
r.,..
,.i:.,,;
:.i
t{2504, tlf{03,
dnC
a
tr'
/l!n$.i
tolrlt.igii
Acr.(, ,lii:+.j
|
1
.
--,;
.,
1:.;.:,,
r,,
.,1
If
lf.ni**yer f
la:i:s in
Ar';
'iae
i:rrlli.
jtf
l|r :ha;r.:::;{;l:
.rir1r1.;
.-,
,_,.,-
i.
rii
:.,]!r
ten,Lgn
the
fln5i1
htrc tf{i*yg,,i
fr*rc=
ir:e
tf.ii
ir.rii:.
ir:l;
,..r,-;
.,i.
_ir:;rld.l,i.,:r,',
of
ihe
rcdctiOfi
usudllT
ii
:ilr),Jlr-.!
ct
r'6,rl.,,
ir.'li;r'r-.:t.,,;
ri, .rlr.;,rii,,
(rf
,r
..r
r*25201.
solution
rr-rre
.]dded
r-o
tn*
liasr,,
xhrr-r,:
H,ar,-.
rrr..,,
i
.,r..,,j
i,-i
,r
ibG,.
Hatef
bath
fOr
about
an
D-hour
rti{rs!.}on
peri*i:.
l,j::air?cirr
ar;
lt:iJt..ir-;it
onvironmenl
but
prevent
ndn?anr:se *isrioe
for:r.rii*n,
r=a1i
.inoiinrl
*i
C"ygtalllna
li!1n04'#ore,!dde{t
to
ilre
fiasl,
co*irrlt,t
lhrsjJgi-rout
lfrc dierr.,trdr=
t;:riod.
ThiS
periorJ
yral
assrJ.T€d
!.o
br
cCIiltllr.tr.
when
lht,
prrr{}le
r.fi}or.
(if
}tir.'lli;
remainedcon9tantfor30mirtutes.1ltesam;ileEwere.oo;Pd,tr'tln5ferrerl
c0tnpletOly
tO
100-nrl
volumelric f ldtl:s,
arirl
r.r,f
rigeratcr.j
uniii anal,/.rriit
llre
fol
lowing
day.
coal,
slag, and
f ly
ash s.lmples
wci'e rJigestt'rl
accor.dinl
L0
rrr.oe
edrlrcr
out lirreil
in
Apperrrlix
C cf
a repcr.t
by Ruch
et al.
(llll;,
l
ANALYT
ICAL
AI{ALYStS
The
vroter s.rmples.
sediment
and scdiment
corc
extricts,
anct rnao.oplryte
anil fish
digests
vrere
analyzed
for.
Ag,
As,
B,
Bd.
Ca,
Cr!, Cr,
Cu,
f
e, l,lrt
,
Mrt, lli,
ptr,
Se,
and
Zn by direct-reading
emission
spectrophotometry
wi
[h .rn inrJtrcLjve).y-couple6
argon
radio-frequency plasma
torch source
uni
t
(
ICAp).
The instr.ument
usect
was
a
Jarrel
I -Ash
t'loclel
975
Pi
irsma
AtomComp
(
Fig.
a.
3
)
. The
rracrophytc
and f
.istr
,
digests
were
diiuted
l:5,
1:2, and
0 rluring
the fir.st,
second,
ond'third
years,
respectively, in
order
to bring
ths l{C104
concentrrrLion
[o an analyzable
lcve]
I
'
standards
of about 5!,.
which
:Analysis
r,Iere run.
adcuracy
approximately
wits
chccked
every
by
iix
nreans
sarnples.
of rlatrix-matc6ed
,
"
Sodiun and
potass
juln
in al
)
samp'les
during
the
f irst,
yedr
of
the
sturly rvere
de-
'
term'ined
by
a+"omic
emission
spectrophotornetryron
an
tnstrumentatjon
L.rbor.ato1,y
,1,
Mode.l,
253
Atonlic
Absorption-Atontic
tnrission
Spetrophotonreter
as clescr
j
becl
in.,,
,
the Atornic Absorption
Procerlure
l4anual
(lnstrurlcrrtation
[.aborcrtory,
Inc.
lgTZ).
'l
I
T
t
T
I
'l
I
t
I
I
I
I
T
I
I
I
4,14
.r l!r
.l
t
a
I
t
I
I
I
I
t
I
I
fi
I
t
7
t
I
:
(
&
I
a
I
u
--
tl
T
a
6
o
2
t
q
t
s
g
6E
o9
8;
E9
yc
<E
oQ
NU
oo
t
t
I
t
+r
.g
.-(}-,
ctncra
()
'-
t^
a)'<
)
I
{J
C)
>rf,i
F-
.-
c).
E:
4J
rj
C,
l-rOt:(^L
TJLroCL
6
crr
C
(J^r
,u ru
L
u.)
cr)
If
'-
C)
vl\
-(]tgr
Ol
:O
tu
(r'_
o)-v1)
(J
(u
q-Ou1
'F
U
oJ.F--
Ec)_C)c
'rF
3
Or
E.-
F.D
.c
'lJ
t,
C).
C!.
(J
r.a
.-
E!c{
'r
f,L)rt-
C.r
(,/)
rO ts-r
O
.-
Cl
rn
<:l
(U
t-
5
(t)
LJ-
i
;gEiiiiii;isiiui
ili,iil
i'i
'j;ri
iiiillfililiiilii;iiluiirliiiir
t
T
I
I
T
i:.'
!,
4.15
5At$ll]**
ner'e
rJili;LCd |t!}FJt
li{.rrt'}!14t'l
'.iril
j
i
!i;r] 1.
,;q.r'1,
'il'.r,:i;
':r-
i.,.rl:1!*,r'
,-,i.1':.-.
ol-
f,i.it*,
instr'uiieltt.
l'or
Lht
irlrorrC
,liitj
ir..ir-<i
7:.:.rrr
l;{
,.fir-
.r'r',i..,t
:-.-,,r
-i::ir
fi,r
.:4..1
F.
were
analyzetl
bl !CirP
as
sld?-r:{ ib*vs:
!4crCury
cOnccrt"raliOnb
ttErfi
df
lor'nined
blt
i$ld:y:il){.}r
ril-(E-ir
.11,,1,1|ir
ig,rr
Spectrophotcl{fie
tt'y
{f
ig.
a.,i).
Ior
nar.rophyt{.
Jrrrl
f irli
.j
t]:r.,,.....
,r
I'i-'i
*lr:l,ir:r.
of the
dirlested
5ampl, wds
tFdfl5ferrr:d
to
tht
rra(ti0rr,,,rgir-,j
.irrrl d
lr:,*
rjr':i,)!
of
,ltydroxylamine
hyclrochloritle
(tll{gSil.l{Cl}
,,re
r:e atlt!arl
r-c
ra{rcvr
a&ji
rcfndining
Kl'1n04.
Stannous
clrloriqje
was
ad<Jetl
t0
rc.rlur-e
tha
llg
t*
i:,!
1r,.tror'
forrn
(llgo),
and
the
vapsf'
was
suept onto an acLivaled
si
l,;er wool
i-'!uq
bih*re
:
the llg
was
trapped
as
an
amalgam
(Long
ct
al.
lt/li.
l-oj
lowin.l
a
?-ririure
co'llection
period,
the
si
lver
vrool
plug
was
hcaterJ
to
tic-amaiqariiaLti
thr
riig. ,'rrir!
the
vapor wEs
swept
through
the
absorption
ccl I of
a Fisher
llercur.r
r'rrralyier.
A Varian l'lorJel 485
Digi
tal
lnLegraLor
wds
useri
to
rnedsurc
peok
,irc,r;
rvhich.
when
cotnparerJ
to the
peak
areas of
llg
stanclards
t
corresporrdcd to
lig
ronclrrtla-
t,iotts.
Waler
samplcs were
treaterJ
similarly with thcr
excc,pt'
'r
thdl thc
arltJition
Cyanicle
concentraLions in tlte water
s,rrnples
were
deternrirrecl
by analyzing
fhc
scrubber
solutions
(after
the
reflux-disLill.rtion)
coloriinetrically
using
rr
Spectronic 100 Spectrophotometer.
An al
iquoL
of
chloramine-1 soluLion at a
plt>B
was
acJcled
to converl the CN- to c,yanogen
chloride
(CNCI
).
l'lrc
color'
(various
shacJes of
purple)
rvas forrned
by adding
pyrirline-barbi
turil
acjcl
reagent;
readings
were
taken
at 578 nrn r+ithin
15
mjrrutes.
The
concentration
of
CN- in
the.sanlples
t,tas calculated by
comparing
the
sanrple rea<lings
wiblr
those
of standat"d
CN-
solutions treated
in
an,identical nianner,
The
plo135rirnt
cyanide standard solutjon was standardized
by
titratiorr
vrith a
prinrary
silver
ni trate solution.
Coal,
slag,
and fly
ash samples were analyzed:for
the
aforementioned
elernents,,
plus
a'luminum
(Al
),
cobalt
(Co),
molybdenunr
(Mo),
phosphorus
(|'>),
an<J
vanadiunr
(V).
Methods
of
analysis included neutron
activatjon analysis,
ncutron
actjvationanaiys.iswithradjoche[}icalsc,parationforl|g,optjcalenission
spectrochemical
ana.lysis
(both
direct-rea<ling
and
photograph
ic), aLonric
-
I
I
I
t
I
I
I
I
I
I
I
I
I
T
I
I
I
,l
'
:a-.
:
4.16
t
'.r
l:'
:'l
o
.i
r
I
fr
I
f
L
-:
a
I
I
4
+J
{
--
t
I
t
f"
F.:
ii.
,
a:::
='
i,
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il
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B
E
&
I
€
o
o
C
q
o
6
t
q
=
a5€
og
ir ,a
UY'
E1
{E
9t'
rg
co
ig
I
t
lit
''l
tll
'
p.g
.F
=!rCt,/|{)
l+-
'F
l,
(r<
:J
I
jJ
o
>rfJ
F
ta
-.P
P
--EOrrOJ
L.tJ
(JL,ur:L
C r.n
L
'n
gr
cl
('-.
aJ
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tJ.-t
@
TJ'-
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Tlrr-
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c'r
Af
'6
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C,
t{-
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(,/r
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(/'t
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C(JtA
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rf,
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1-
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r,'l
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ilEiiii,i
ititlti
iii'rii
i:i
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iiiiiiiliiiiiiii;iiiiii*iil
i
.:;.....::..:.'.=;.'':........-.;.;:..........;...
t
o
a
t
e
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c
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o
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:o
o
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::
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ii"
ai,
1:U
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4.15
::
1]
fo
C{t
LE=rl
F,g
rn
rn
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..'L
rt-
uf,
()L
c)
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OrO
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rr
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r-)
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o
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o
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o
q
ah
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ilt
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tr
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u"r
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=
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tlJ
ItJ
rd
l<
ta
3
lp
t!:
l-
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lH
lg
lfi
J\
til
(3
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ttt
cl
r
l
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(/,
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F-
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l'r
L,
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U)
rd
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__1
f u.r
a8
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E.
;>
([
l-
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tl,
t--
tu
c3
I
7u
il
r-
i:J
trl
',
UJ
cr:
tll
cl
oa
o
()
ul
u,
4.r7
abSorption
dnalysis
(botlr
f
lame
arrd
qrafrhite
f,irnacr
anrJ i4-r
rt,r
f luirl.es(cn(.o;
A <Jescription
of eaclr
jnsLrumcnL,
not:nal
opcraLing
cgnriiLif;ri.,,
arrrJ
r-csL
refel'ence
mdterial
s
are
c0nla irtecJ'.in
Appen.Jir
C
of
,r
rcporL
liy
p,ilclr
aL ti
I .
(
ters; .
,t'
DATA
AT{ALYSIS
:
During
statistical:treatment
of
tiie
chemical
const'itucnt.
data from
the
fiq-st
year of
the
project,
all
concentration
yalues
less
than the detection
linriit,of
the
analytical
instrunrent
were disregartlecl
(Smith
and Ouda
1979).
Tlris,
in
ef
f
ecLi,
:bi'aserl
'the
appropriate
means
in an
upward
rJi
rect
jon,,,'.on,nrrmes
to,:
unrealistic
levels,
During
the
second
year
of
tlre
investigation,
values that
were
less
than
the'cletection
linii,t'vler'e
consitlered
to
be "0"
(Anclerson
et,lal,
1980)',.
Though
more
realistic
than the former
approach,
this
pr.oduced
a bias
in
the
downward
direction.
The
present
approaclr
has
been
t,o
set
all values
less
than the detectiort
linri'u
equal
[o one-half
of
the cJeLection
lirlit.
|^lher.e
thc
rnajority
of
the values
for a
particular
element
(such
as
Pb or
Se) in
a
partic-
ular
set
of sanples
(such
as
gizzard
sharl)
are less
than
the detectjon
limit
of
the
instrument
for
that elemettt,
the
sarnple
nrean would
be r.epor-ted
as
less
than
the ,cle'tect'ion
I
jmi
t-.',:
ln such
cases,
Lhe
hal f-detection
I
inri
L', approach
has
"no
relevance.
Hovrever,
it becomes
important
for
statistical
considerations
in
those
cases
where
be'low-detection-.limi
t values:.are
reported
for a
few
of
the
:
total
'nuntber
of sample values for a
'particular':elernent
(such
as Na
in
the ia'se
of
nacrophytes
or
tlg
in
the
case
of
fish
or
macroplrybes),
The third-year
data
have been calculate<i
an<J
statistjcally
analyzetrusing
the
half-Jetection limit approach.
In addition,
t,he
data for
tlre firsL
an<l
second
years
have
been
recalculatecl and re-analyzed
statistically
using
Lhe half-
.
detection
t',
'.
I
irnit approaclt.
:
These
r-esul
ts
for
the'
inr.liv
jclual
years
are
llrc,senterl
intabu,IarforrnintheAppendixorthisrepoi't(tables4.A-4.'V).
A check of the
first-year
sedintent
extraction
rnethod
jnclicaLecl
that
unriuly
harsh
con-rli,Ciohs
prevai
led''which
tended.,to' destroy tlre
integri
ty
of thc set'lirnent
i
itself':,rather thanim€ie1y desorb
th;
cations froiir
the sedirnent'''parL'ic:le
:,:
,
.j
:=
T
,:1.
I
I
I
I
T
I
I
'l
I
'l
i
I
I
'l
,
',t.1,,1
,:.
'
:a
ta:'
:
.r
:i-:'
I
,'' .,:::::l
ii. :,
:..'
,'
,l',
;;tt,:;::
i:i:-
:,
-.-
,
4
.18
,:
'""
'
:
,:
,:
::
:
surf
aces.
Fresh
al
lquots
of
'f
irst-year
5erJiilents
were
subjficled
Lo
Llrtl s+.
digestion
regirnen
used
for
sediments
frorn
the
iol
lowinq
twc
years.
The
resul'ting
rtat'a
were
;;lculaterl
antJ
stat
lstical
ty
analyzed
ds
pdrt
af
the
f
year'data
and.are
therefore
inc luded'in
the'rAppenrci
x,
as
referred
t0
above
(Iarrle
4. A)
.
Al
I statistica'l
analyses
and.comparisors
of
'Jata
fot'
the
three
years
have heen
carried
out
using
starrdard
analysis
of variance
packages
available
on the
llniversity
crf
Il
linois Cyber
175
comprrter.
RiSULT
S
SED
I MINTS
Major'trer,,is
in
the
concentrations
or
severdt
chemical
c0nstituents
in Coifeen
Lake
sedimi.'nt
occurred
over
the
course
of
the
3-year
study.
Eoth
Ca
anri
lt
exhibited
significant
increases
in arrnual
mean
concentration
during
the
3-year
peniod,
and
Hg
shcwed
a
sjgnificant
rjecrease
(Table
4.3, Fiq.
4.S).
Sirnilar
trends
for
these
three
elements
were
evident
at the
staLion
level
(Table
4.4),
Comparison
of annudl
mean
concentrations
aL incJjvidual
stations
indicated
significant
increases
for
Ca and
l,lg
at mosL
stations
and
non-significant
increases
at
the
remaining
stations.
In
the
case
of
llg,
three
or
ttle
si*
stations
showed signif
icant,
decreases
during
the
3-year^
per:iod;
the
oilrer
thr.€€
also showed
decreases,
though
not sjgnificartt.
The'.annual
rnean
concentr,ation
of
one adrljtional
element,
Cd,
decreased
significantly
at
Stations
I
and
Z between
the
first
and
second
yeilrs
of the
stucly
(Table
4.4), but
remained
relatively
constant
at
the
other
stations
during the
same
perioO,
,
:,
There were significant
changes
in the
station
distribution
of
some
of the
chemical
constituent.s
in
the
lake sediment
from
vear to
year,
but
none
of the
ionsfituents'showed
progressive
increasa,
ort decreases
jn
concentratiorr fronr
Station'I
to'station
4,(Appendix
Tables
4.A-.4.C).
During
the
firsf:Jfear
of
the
study, the
concentrations
..
of both
cd and
cu were
significant'ly
greater
at
Stations
I
and
2 than at
Stations
3
and
4. The
djfferences,in
succceding
years
-},ere
much
less.marked.
.For
.all
three
years,,of
the
study, the
concenlrations
of
'
.4:'19
,.1
.:
.:
-:.
.,::..4,
':i.ia::.:::....,
.
e
4,3. /vrntral
meon
conccnLrafiorts
(m!/tQ
rjr./ a11
i.;hr_i
of
crren,i cal
''
constiLuents
in
bottom
sediment
col
lecteri
lL
ecf
f
cen
Like
f
r+::r
SeptembCr.
l97B
throrrglr
0ecembtr igftr-j.
iarii
lr-'
{lu;t,it
i.,.
rrr5
1r-,,
{
n
parentheses
,
t.
..
I
I
_lr}-
r
97S-79
I
979-80
I
-TTOT
*:|]ur
l
980-Br
i/re
an
ry
t
A9
As
B
8a
Ca
cd
0r
Cu
Fe
Hgc
K
l'lg
Mn
Na
Ni
Pb
Se
7-n
7,58
<0.80
s.82
I
:32
1 686.
I
.98
o: 56
B.38
t?r.
r
34.
r
60.
337,
l 06.',
I
I
75,
:
I .73
<2,78
.:
<0.67
23.7
b
<0.76
,
B.B3'
1.63
?.398.
I
.21
<0.22
2.41
?.97
,
7
4.3
l6't.
:488.
,405.
,
:
207 .
'
2 .05,,
<0.
90
(0.68
21.5
,
b
{.0.
7B
,
7.04
I
.00
3??4.
I
.35
,.
.
i0.
l6
,.
6.08
l!6,.:
r.
,':'r-
53.5
,
i
121.
.
61
].
,.1
,,.
:
'
3r
5,
?4?.
.
'_1.94
:
<0.70
l
.'{0.60
l
:
24.5
|,68
t
.l2
267 8,.
t
.36
4.77
:
23?.'.
'r2,1
:
143.
525.,
330,
?r 5.
'l
.,96
23.
I
2.8
<il,
"1.j
?LJ
1.2
1.4
1,5
-?1,-q
.1.!_
10.
?
4.9
1.5
0.2
T
I
l'
T
I
.::
I
l'
l'
I
I
0,1
t'
':.a
'
:
"r:::
i
,-
'
,t'.,'
...',ll'
rr,'.
i;!;,,.
.',:-
:
::,.
i.-i'.
t-.-'
'
i!,'
:
.::.,....:::-
*,,,,
'-
"t-
tt.,,
lir'i
'
'
!ii',,
,,. ;,
aValues
that: are' underscor:ed
.
between
years.
DAt
the time
of
analysis
the
measurement
of this element.
cConcentrations
are
in
ug/kg
indicate
significant:
differerrces
(p<0.05)
Instrument
yJas
not f
unctiorring
optimal ly
dry weight.
:
,
',i
4,20
,:,.;
f
or'
a.
t: :-'.:'
:,::'.,.
::
. ;';':::.r
tlr
i=
,'I
',i,,
',,jI-:
I'
,,:'
.::
,!:
"
,''
''
':
t).!},(n
x
4,.x
nl
ltl
||t
tll
I
t
't
I
tttl
| |
:l
I
| ?
3
Pondweed
Fil-
-
l?1"
;;
ll
il
il
I H
Ittl
Iltt
g
t23
Pondweed
?
tt
ll
tt
I l.
tl
123
Pondweed
aq
en
n1
xx><
ra*l=r
il=,
i-l
ll
IJ
Jl
Bi le-
siit
I
Sed lmen
t
:l
2
3
Pr
i
mrose
1,23
l?3
Sediment
Primrese
|
2
3
.t
2
3
Sediment
Primrose
rufl
123
Si
zrard
rha
d
L]
l
Iarp
J
Channe I
ca
t-f
i
sh
n
-:..i.
.
Channei
caLfish
l?1
1-23
Elaell Lar:gr-nouH:
brr I
I hea'1
ba 1;
r
r^r
ul
itt
xxx
li
I
!
r.
:
I
I
I
|l
I.
I
.a
::: :
t,l
'
I
!,
l,
..
,'
:
I
t
t,,:
tj,
t-
l.',
l'-
,,.,
i-',,
l,
::,
..
I
:il
':'
I"t'
-.
I
I
-
,
,.
I
'.'-,
I
..:.
fl_n
[]-rt
L]:=:=
I2 3
12 3
i23:
Gizzard
Black
Largc+nouth
shad
:
hul
]lread Uass
l
E]
333
Carp Elue-
Channel
CIOC:}
tr}(ftrn
gill
cdrfish
dddd-{d
x:<xxy,*,
I,,,?,
3,
Pohdweed
173
BIact
brr I
I head
fti],
t? 3
Largemou
th
bass
3.'
3'
Corp
Blue-
,r
q.iII
1
',2
3
'
I
? 3
Sedlrnent
Pt'imrose
.
.1i!
.itA
llF-r-t-1__
l2
3
123
t?3
Gizzard
Blacl,
Lar.gmrouth
shod
bu
I I
head
lta ss
cf
{
Carp
4{
;
JJ
Bl ue-
Cha.nnel
qi
I
1
catfish
iFiiure,4.is.
',t,'
,
,-t.'.
,'
I
.
:
::i
i:
::..t. .
..-
.
.
.
..:
..;,,.t--a,.
;'.,;.
.,
t
Annual
mean concentratlons
(mg/kg
fresh
or dry
weight)
constltuents
in
samples collecteri
at
Coffeen
Lake
fram
1978
through Oecamber
1980.
(continucd)
..:
of
che,rnica I
5eptember
...
I
t,
...a
l
.l
.cl
^r
i=::.:.
':'::'::
.::-
,,,',:a,
'
,,
f$(\cv
xxx
da
tlnLhnnn
l-,2
3
tlI
2 3'
Gizzard
[}lact
shad bu I
'l
head
c.J
x
ll
tl
rt
tl
il
ll'
Ll-rr
r?3
Pondweed
CV GJ
GJ
xxx
n
il
ll
tl
tl
ln1
I23
Pondweed
3
xxx
3:3
n
tl
lt
tt
ll
ll
I
l--rt
n
I
I l.
Lt_-
t23
Pr i
mrose
tr,
rorf).
xxx
n
tt
|l
tl
LIL
r 2 3,
Primrose
-?
3
iment
-r-xx
l"
Sed
(t)
l
,x
,123
La rgunou th
bass
r
1
J
Ca
rp
llL_,
tt
tl
rr
3
,J
B.l ue-
Channe I
gi
1l catf:ish
nLrD
3
3
3'
Carp Blue- Channel
gill
catfish
I
I
I
I
I
T
I
c)o
r')
tn
'xx
a
tt)
x
ml'f,fL',
t23 t? 3
tt-
t?3
Gizrard
Black:Largonouth
shad bul I head bass
n
lnl
,f
J
Carp
"
"'tn
t'23
L2 3'
t23
r,2
3
Sedimerrt
Primrose Pondweed Gizzard
shad
n
Llr== m==
It-{r
,r,2,3
t2
3 123
123
Sediirnent
Primrose
Pondweed
G
i zzard
shad
r23
Bl ack
bul I head
r-f-t-:f
t23
Largenrou
th
ba ss
tf
[-l
,
3
,'3'
Ul
ue-
Channe I
gill
catfish
d'
dJ
t2 3, 12
3
3
3
3
Blackl Largemouth Carp B'lue-
Channel
bul lhead
:
bass
.
gi
1 I
catfi sh
a
i:!
:
::
:
j
::,...
..:
j
Ftgure.
:a
1
",::
'
:::-.r:.::
4i5,
Annual,
man concentratlons
(rng/kg
fresh or
dry weight). ..
(continued)
\.,,.,?
3
Sediment
ro
tr)
io
tx.!X:r.t<.
4.?2
f'l
xxx.,
fv1 fn :
n
il
IIII
tl
n
tl
ttIt
tf
tt
{l
r--l
r{l|
|
re3
Bl ac!'.
bu
i t head
*l
t-
I
r
LrilllL-llh
ntil
rt
th
lll
:-
ilL
'oo1-LLJ
L2
3
LLn
123
LjI
123
rrll
t2
3
r-r-lt
123
m
t2l
r
I
n
3
Sediment
Primrose
Pondweed
Gi
znrd
o,l,r,l.J.o
,urfl:T:rrn
Carp
rJl;
qlqcn
rt1rn
Lr) rn!oir)
xxxxxxxx>r.
I
h
::.
'(t)'
x,
tl
ll
tl
tl
Il
tl
II
I t,
tl
L_J
anne
tfi s
xx
.
nn
tttl
il
ttil
rl
tltt
ilil
LJ
LJ
33
Carp
Blue-
Ch
gill
ca
Sed imen
t
t{b
r23
Bl ack
bu
I
I
head
T
?
3
La
rgemou
th
bass
r-1
-
rl
l4
t
a
J
Largemou
th
,
bas
s
:
-:
r--1
tl
L--l
{
Channel
catfi
Sh
tr
EI,,
3
.3
..:,
Blue-
Channel
gill
catfish
o
s
xxx
@@
()o
Mn
123
r23
Sediment
Primrose
| 23
Gi
zzard
s
had
tl
3
Carp
*.
1
,rrLt[
123 t2 3
Sediment Primrose
t-Tlr
nll n-r-l
r2
3 123
Bl ack
Largemou
th
bul
lhead
,
bass
n
3
Ca
rp
l',,2 3
I 2
3
Pondweed
Gi
zzard
"
.',
l
shad
,'.'.i
,
,
.:
I
-
;,
J
Bl
ue-
gill
tl
LJ
J.
Charrne'l:'
ca
tfi sh
:':
'
''''1"
:'
:'r'tll
'
::.:
.
:
':
l?3
.,t'.2
3 123
Primrose
:
:
Pondweed Gi
rzard
sha
d
o(fo
€@@
xxx
l--t
tl
tl
lrn
tl
tl
|
2
3
Pondweed
Annual
, mean:cohcentiations
(ms/kg
f resh
-.'r,'dryl
weight) .
. .
(continued)
-
aa
l=i-L,
r*l
..
't
2
3
123
Gi
zzard
Bl
ack
shad
bu'l
I
head
da
I/,J
L
arg
anou t
h
.
[i455
'
E
,,',.
i..:
,
:l::
JJ
Blue-
'
Channel
gi
)
1
''catfish
u,it-
gi11
ca'tfish
;;*..,
aa
a
3
Ca
rp
I
:
t
I
I
I
I
I
I
I
I
T
I
I
I
t
l,
I
'l ?3
Pr
i
mrose
t?.3
Pondweed
123
123
123
Sedinrent
Primrose
Pondweed
Ln
x
I
2 3
I 2
3 t'2,3
Gi
zzard
tjl ack
Largernouth
shad
bul
I
head . bass
aa
a
| 2
3,
Primrose
r--l
tl
I lu
u
Ll_--
t23
Primrose
!
aa
123
Gizzard
shad
a
rll_
t23
Bl ack
bul
lhead
Y
{
Channe
I
catfi
sh
a
Carp
',L
2
3
Sed
i
men t
,l'23
Sediment
r 23
Pondweed
I'Z.3
Pondweed
t23
G i
zzard
'
shad
123
Bl ack
bu I
I head
7
..2
'3
Largemou
th
'bass
ba ss
tl
LI
?
Bl
ue-
gi
1l
|f,ilrttjn
r{
n
I r{ L-
_JL
Li
r--r
Ll
n
IItl
tl
tl
3:
.'
Channel
catfi
sh
J
Carp
3
Bl ue-
silr
fresh or
dry weight)...
(continued)
:.:a::'a'.','.,
a,a
:':':
.
:. ::.'::
'
'
_.'j..-
.
-1..
:
,.a:.
'!'.a:.
aa
C\l
(\l
xx
Table
4.4.
Annugl.rnedn
concentrdtions (rng/kg
dry
weight)
of
chemical
',
.
anci
I'lary.Llltions
at
Cof
f ecn
Lake
f rorn
Septcrr,ber
lgig
rtrrougtr
December
J
980.
,
Stat
ion
I
-Tg-/6--E---Ttrg-B--d---rqAn--ar=wr"
A9
As
B
Ba
Ca
cd
Cr
l,
LU
Fe
Hgc
t\
.
Mg
i,ln
Na
Ni
Pb
:
Se
:
Zn
B.
82
'<0.80
'
:
5.93
:
,
1.70
2,225.
2tzg
4.44
0.58
,
8.93
17
2.
I
00.
2r B.
I
BB.
I 45.
l.l7
<2,78
<0.67
.:
12"0
b
<0,76
7.46
1.40
2,936.
1.22
<0,2?
<0
.46
.
42.8
89.
I
79.0
543.
245.
ll7.
I
.35
<0.
90
,
<0.68
,
14.7
,
..0
<0.
78
3. B7
.l
.03
:
3,369.
'0.27.
.a
<0.16
(0.I2
78.
0
43.9
::
49.r
,
540.
208.
.
I
43.
0
.0s
<0.70
<0.60
5.23
s.
7l
1
.?9
:l
2,997
,
'l'.00
51,.
B
B4;1
70.0
487.
220.
)
26.
0.
96
10.3
6;4
3.5
lt.0
l4.q
l.l
43.
I
1.3
2.4
I
'5
1.1
3.8
3.6
:I
"':
:t:::
::
,
;;'
:::
'::.a..
,.:
::.
l':
,.
i-:,
:
.t'i,,
t"'
::::-
.:::
4.25
a.
t,
-
,
',
Table
4.4.
Annual
mean
concentratlons
(rng/kg
ciry
weight)
of
chemical
constituents
ln
lrott6rn
ierJlment
iol iecIed
at
four
major
and
tno
ancillary
stations
at Coffeen-iai.
f rom
sept'ember
l97B
throrgh
Decernber^
1980.
(cont
i.uecl
)
:
Station
I
.5
__-Td
Ag
As
B
,Ba
,Ca
,cd
,Cr
Cu
,l'Fe
'
Hgc
K
:
'Mg
.
,Mn
:
Na
Ni
,,
Pb
Se
.
''7n
b
'
<0.76
12.6
:
1 .48
I
,99
.4.
l
.0'l
<0.?2
3.7
5
l
659.
6r .l
17 9.
4l
l.
523.
240.
?_.72
<0.90
<0.68
23.8
,
[:
<0.78
9.46
:'
0.7?
3,261
'
,
2.16
,,
(0.1,6
.
l.4s
'
72.8,
,
, .ai-
'
57.7
,150. ,
:
693.
.
556.
.
,321
.
,'
2.54
<0.70
(0.60
.
29.4
I t.0
.1.10
2,628.
I
.58
?.59
366.
59.
4
r
64.
552.
540.
27s.
2.63
26.6
1.3
,7.3
,"
2.3
0. B'
,l8.6,
',, 0,1
|
.2.
._i.
143.
0.04
',0.9
0.0 5
:T
I
T
T
I
I
I
:-
I
..
I
I
0.2
.4.26
(
cont
inued
)
Table
4.4.
Annual
mean
concentrations (rnq/kg
tlry
welqht)
of
chernical
constituents
in
bottom
sedirnent
iollicted at four major
and twtr
ancil
lary
stations
at
Cof
f een
Lake
f rorn
September
l97B
tnrr:Lrqtr
Oecember
1980.
(continued)
'-Tfm:/g---
r
9/9-U0
I9BO-BI
Stat
ion
2
-Tedn
-Fd
Ag
As
B
Ba
Ca
cd
Cr
Cu
Fe
Hgc
K
Mg
Mn
.,
Na,
Ni
Pb
Se
Zn
il.1
<0.80
4.
9B
0.99
I
,1
85.
4.20
0.67
32.5
397.
I 20.
I
70.
208.
112.
I
60.
3.58
<2.78
<0.67
66.8
b
<0.
/6
I1.0
I
.49
|,927.
I
.71
<0.22
4.74
676.
56.9
17
4.
384.
456.
"
20g.
3.
45
<0.
90
<0.68
36.0
b
<0,
78
8.53
0.58
2,7 7
6.
t.84
<0.|6
?4.6
531.
59.2
I
69.
606.
5l
6.
299.
3.24
<0.70
<0.60
39. I
a, 98
1.03
2,
I 53.
2.
rB
17
.7
569.
69.4
r
it.
447
,
4?4.
234.
3.38
0.7
6.1
4.0
4.t
2.7
0.4
l4.
t
0.03
6.B
la
0.5
0il
r.3
'
''
'';
'i,:.-'
4.27
42.4
(
cont i nued
)
:
-
'
..::.
.
,:
:r..=.:
,.
a
:
.:1.:
,:.
Tab'le
4.4.
l.t
:.
l:
I
&rnual
mean
concenfr.ations
(mq/ke
dry
wejoht) of
chemical
const
i
tuents i
n bottom
ied
iment
do
r
i
ectad
ar
four
maJor
and'two
ancilrary
staiions
ar
csffeen-ior,u
f rom
September
t
97B
through-
[hcernber
lgB0.
(ionr
in,,e,f
t
I
!
l
Ag,
As
$
Ba
r
l.
Ca
cq,
..
cF,
ct
Fel
.:
:
Hgc
K
Mg.-
Mni
l{a.
'.
r{i
b
<0.76
9.98
1
.09
2,A53,
I .79
<0;22
4.02
222.
68.0
:
162.
522.
762.
236.
,
2.55
<0.
90
<0.68
:
33. 7
.'
<0.78
B.03
.
'
0.62
?,923.
2.93
,
<0.1
6
:
.
.
9.85
366.
:
50.0
.
:
l39.
.
725.
..,
438.
_'1t,.1
'i
<0.70
'.
<0.60
,-
60.9
9.01
0.
85
2,4BB.
2.36
.
6.
9l
294.
58.0,
rf,t.
624.
600.
2?4.,..
3.34
47,3
3.8
3.2
'I
1 r
;
I
t
t
t
I
I
t
I
I
I
Pb
Sel
0.7
0.9
t.?
3.t
PJ
l_9.0.
0.04
3.8
'1In.
3.3
it]
a.
'a.'.:
:
(continued)
,,,
'.,:
l.+
4.28
i'"'
'
-
"
fr',,
'
::
Il:
.
.
l
I
'::
:::r.'
:
.,
t.-:.:
-
,,,,
'
.
,t'
'
j:r..:
:
:.
:
::
Table'4.4.
Annual
mean
concentrations
(rng/k
g'dry
weight)
of chernical
."
constituents
in bottom
sedimeit
dollected'at
four
rnajor
and lwo
,'
':
dnci
I lary
stations
at
Cof
feen
Lake
f
rom
Septernber
lgiU
th'"origh
.:
,
December
1980.
(continued)
liJ_
,0.3
9-r-1,
1,.2
l,
I.r
1,,
....:
I
!
.
'.:
I,
!:
a:..
I
:..
,
,:'
.
I
I:
l,
l,
l:r'i:
I,'
-
I
I
I
:;l;'.:
lr
!'
.-. ,i
i
r
l',
Stat,ion
3
-Tg/S.79.
]lff/9:r60'
--
an
Ag-'
As,
B.
Ba:'
.
c;.
cd'-
Cr
,r,
,
Fe,,
Hgc
K,
Mg'
'I .
lln.
Na
,1
Ni
,:
Pb
5"
-.-
Zn.:'
3.
B3
0.95
3.40
0.93
I
,560.
0.96
0.56
<0.38
34.0
7l
.5
90.5
562.
79.
B
't05.
I .20
<2.78
<0.6
7
l0.l
'b
<0.76
5.7
2
I
.00
2,073,
1
.50
'
t<o.z?
I
.37
l 4s.
:
73.3
,
140.
623.
31 9.
I 83.
I
.93
,.
(0.90
,
(0.68
:
'
,20;2
b
<0.78
6,
BB
I
.20
2,978,
0.i84
<0.r6
0.
37
:
108.
,,
50.
I
124.
710.
:
l3l.
257'.
.:
1.06
<01
70
<0.60
12.4
5,
81
I,07
2, 365.
l.l3
0,7
4
r
ll.
63.3
1
2s.
649.
201
.
1
98.
L44
0.5
0.5
).7
2,3
oq
8.5
3.6
'2,f
G.9
4.29
r
5.3
(
cont i
nued
)
Table
4.4.
Annual.meal
concentrdt.ions
(mg/kq
dry we.ighti
of chemical
const'ltuents
in
bottom
sr:diment
col !ecLerJ
at f
our arajor
and
Lwo
ancillary
st-ations
at
coffeen
Lake
f
roni
scpiemuer
lgi8 Lhrorrtrlr
December
I
980.
(cont
i
nue<J
)
I
I
t
-.-l-q"ro':79
Stat ion
4
t
r 979-80
t9urJ-81
llle
a n
Fd
I
I
I
I
T
T
I
I
,A9
As
rl
Ba
Ca
cd
Cr
Cu
re
Hgc
K
,
i',|9
,'tln
Na
Ni
Pb
5u
,7-n
6.
64
(0,80
9.00
I .68
1,775.
<0.
B0
0.57
<0.38
46.4
171
.
280.
365.
45.7
289,1;,.
0.97
<2.78
<0.67
5. Bl
l1
,
(0.
i6
6.18
3.35
3,404.
<0
.08
'
<0.22
<0.46
39.
5
.
92.B
233.
,.
444
126.
,256.
'
0.33
<0.90
.<0.68
-
'0.27
t)
<0.
iB
5,46
l.B4
4,045.
<0.
l0
<0.16
0.14
20,
B
60.0
94.2
393.
42.3
215.
<0.28
<0.70
<0.60
0.1 4
6.35
2.44
3,4
00.
32.9
92.2
r
83.
409.
'77.6
244.
0.36
1.14
3.8
30
l-1,
/.
0.5
4.3
44.
5
0.8
I 0.0
2.2
_1L.0
I
t
57 4.
aValues
that are
,
between
years.
DAt
the tirne of
for
,
measuremerrt
cConcentrat
i
ons
-...::
:'
:
t
t
I
underscored'indicate
signif
icanf differerrces (p<0.05)
anlly.s
js
.t!e
instrument
was not f
unctioning
opti.rnal
ly
of this
element.
are
in
ug/kg dry
weight.
.
:
'
_:
:':
''"
'
a
'-
.
4
.30
lj
-
I
r
|
:r
'
.
, ,::..
-:,
I.:
Il,'
I-
i.':.
'Ir'
I:
:I
t:
::,.
:I,.
"
,
.r,.
jl:
'
'.
:l::
:.
iE
}I
r,r
iI
*''
,
r-_-
,-.
F-
!11
1I
both
Fe and
Zn
were
reldtively
low at SLaticn
I
anrl
hirlh
o. Statlon
2, compared
to the
concentrations
at
most
of the
other
stdtions,
c0Rt
s
Sedimelrt
cores were
collected
and
analyzed
for
corrcentration'-r
of
chemical
constltuents
only
during
the third
year
of
the
investigatir..rri',
cores were
collected
at fjve
polnts
along a
transect
across the
lake
at each
of
the
four
rnajor
and
the
two
ancil lary
stations.
Statistical
analy,sis
of
the
elemental
corlcentration
data
inrlicates
that
the
concentratiorrs
of certain elernenis
differed
significantly'between
stations
(Tab'le
4.5).
The
concentrat ions
of B,
Cd,
and
Hg
in the
cores decreased
steadily
anrt
signif
icantly
f rom Str:tion
I t.o
Station
4.
In contrast,
the
concentrations
of As, cr,
and cu wei.e
hiqher
in
cores from
Station
2
than
frorn
other
stations
A comparison
of
concentrations
of
chemical
constitituents
in
t,he
five
cores
,
obtained
along
a transect
at a
given
station
(one
near
each bank,
one
in the
center
of the
lake,
and two
at intermediate
points)
indjcates
a
fair ctegree
of
homogeneity
in concentrations
at
points
alonq
each transect
(Table
4.6).
. Although some
of
the
differences
in concentrations
between
points
are
statistically
significant,
there
tppear
to
be
obvious
trends
for
oniy three
elements.
Ihe
Fe concentrations
in the
cores decreased
nrarkedly
and rhe Ba
concentrations
decreased
moderately at the
center
of the
lake
(at
each
station)
conversely, the Mg
concen.trations
increased
at
the
same
locatjon
The
cores
rere
separated
into
six segrnents to
represent
recent
sediment, four
intermediar:e
deposits,
and
original sediment.
A cornparison
of the.
concentrations
of chemical
constituents
in
the
six
segrnents
averagerl
across
the
five
cores
along
each
transect
(at
a
given
station)
indicates
a fair
degree
of
,,-,homogeneity
in concentrations
of about half
of the
elernents
in
the
segments
of
,cpr€s
collected at
each
station
(Table
4.7). Exceptions
are B,
Cd, Cu, Hg,
Ni,
and
Zn,
who59 concentrations
tended
to decrease
as the
depth
of the segrnent
in
the
core increased, and Fe, the
concentration of
whjch tended
to
jncrease
with
.
increasing
depth
into the
core.
4 .31
,-.t
't
'
'
'"
li:
,.-:.r
r'
i:
,
:-'
,,Iible
':4r5;.
Pean
concentrat
ions
lmcr/k(1
drv relaht)
+f
''...r:l'...-....t9s0..(l980-8l)....
col lect€d
at
four
majoi
aria
two
anii I
iary
.
.:
:
aa.
::
':
ehe,aical
canst ituerrts,
lrr
cores
siat
ions
at Cof f
uer:
l.ake
i
n Ju.re
''
:
tle an
r
Ni
,1,
10;6
l:'
Pb
''
'
<2,?)
Se
..:,
<2:32
Zn
"
Il8.
l
:a-
nValues
that
are
<37,7
-'<37.7
6.23
I
0.1
zti,.6
?3.9
34.
B
3?,7
514.
55?-.
5.94
7.48
15.?
14.2
30.6
48.5
I
t432,
'
2,133,
44.8
50.2
22.1
57?.
2,?,64.
28.7
,
529,.
|
;757
.
l
12.9
I 6.6
:
12.21
<7-.32
167.
13.9
r3.4.
<2.21
/,2.32
<37
,7
,
6
.:,
.96
19.0
49.7
520.
3,7 3
17.9
I8,5
I
,960.
46.2
26.0
434;
2',136.
il.0
:
I
3.6
<2.21
<2.32
97.4
<37
.7
5.1 4
2t.0
qt
,t
538.
I
4.ll
15.9
26.7
I,639.
',
38.2
25.?
498.
I,4gB-
r
0.5
I 4.5
(2:21
'<2.32
,104.
<37.3
4.
l0
19.4
34.3
465.
:
I .
il
I1.2
2.27
I,505.
3r.5
?1.9
586.
I
,050.
18.3
9.72
<2,2]
<2.32
60.3
6.34
24.7
39.
I
527.
5.
t3
l-1.
/
22.?
1,627
48.0
,'
23.5
532'
i,
I,684.
t2.9
I 3.0
I 12.
168
t6B
r6B
166
l6B
l6B
l6B
l6B
r6B
163
t68
l6B
r6B
t6B
t68
l6B
l6B
168
?.5
7.q
r.B
1.5
?,1_
3.4
?.-!_
L9
7,7
5.0
1.4
6.9
2.3
2.7
'l
'!
G
I
I
I
I
I
:l
I
I
I
,l
I
,l
I
1.7
underscored indicate
significant
differences
(p<0.05)
between
.
.t.
are in
u1/k dry
weight.
ria
t,:.,
|
'.c:!.,
L.
:ir:
.
4.3?
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I4ACROP}tYTE
S
Theie
H&s
a
significant
downwar<l trend
in
annuaj
mean
cOncrritfrrtions
of'Lhc'
maJoiity
'of
the
chemical constituents
present
in
the'leavr.rs
and stems
of
,lbofh'
creeping
rraterprimrose dnd
funerican
pondweed
during Lhe
3-yeor sLudy
period
(taUles
4.8 and
4.9, Fig. 4.5). The
exceptions were
B,
K,,rncl
lla. If,
based
on'insufficient numbers of specimens
coi'lected, data
from
the
first
year"of
the'froject are disregarded, both
B and
lta
show significant
decreases in'
:
concentration in
both
species,
and
K a significant,decrease in
pondweed,"
during
the
reinaining
two
years.
The
only anornalous
trend
appears
to
be
for K
in waterprimrose.
Snith',and Duda,:(1979) and
Antierson
ef
al.
(teeO1
observed
for
the
f
irst
and
second
years
of
the
investigatjon,
respectively,
that
the
plant
stems usually
contain
higher concentrations
of elements than
the'leaves
(tatr'les
4.8,'rnd
4.9),
Appendix Tables 4.D
and 4.E),,,.In
contrast, data
forthe
third
year
of the
investigation
show a fairly equal
distribution
of
concerrtr<rtions of five
,
etements
between stems and leaves for
both species;.the majority
of
the.
remainingelementsoccurredinhigherconcentrationsinthe]eavescrfboth
,pq"i",(Tables4.Band4.9,AppendixTable4.F)...Thisclisparityofdis-
thib'utions
could
ref.lect
yearly
technical tlifferences in
the
procetiure
use-d
fo'i
separation
of leaves
and
stens.
Regardless of
these
"discrepancies,."
16s
present
authors have
elected
to
consider average
values
(representing
the toLal
plant)
for
the
preparation
of
Fig-
4.5.
I
Statistical
comparison
of concentrations of chemical consti
tuents
in
plants
,
_
collected
at
different stations
during
the
second'and
third
years
of
the
study
I
indicated that
the
location
(station)
of
the
plants
had
little
bearing
on most
,.1
of the
elemental
concentrations
(Appendix
Tables 4.G-4.J).
(there
were too
few
I
specimens
collected
during the
first
year
to
warrant statistical
ccmparison.)
A
'
I
few
exceptions
were
noted for waterprimrose during
ihe
second
year
of
the
study
I
(Appendix
Table 4.G). Both
stems
and leaves
of
plants
co'llected at
Station
3
I
contained
significantly
higher K
and Zn
concentrations
than those collected
at
-
other
stations.
Stems
of
plants
collected at Stations
I and 2 haci higher Ca and
1j=.1
,.,..:'1.,,
I i:.$6:-:g6i1r
centrations,
respectively, than those collected at other,
stations. No
,9#,,,'
.
'
..
,
:
,
....,:,.4:,:
a
.
,,.
,.,,
:
,
::
,
I
:
l
fablo
1.8.
Annilal
riu,ro
crrnonlrrtloos
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lrcsh
mlghtl
ol
drsntra!
cp.rslit,Jsnrs lo
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al
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to2.
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Indlcato
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of analysls thc
lnsfrurmnt
ius
not
fun"tfr^i^g-"ot;r"'r,
e
lomrnt.
CConontrat
lons aro
In
q/kg
fresh
ro lght.
.
,.
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,.,1:
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4;40
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at:folfqsn
loka lrrrn
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10
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%ptofFt)er
i?S0.
|
970- 79
Stros
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{'lr,
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t
A.s
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Ca
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Cr
Cu
Fe
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K
re
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r{l
Pb
So
Zn
'4.
I
<0.t
<1.5
<1.5
.,
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5q.6
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2t,
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ll.2
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to.z
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:'
b.i
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9.5
atban
and
!value
rere calculafed for.
pars
197F80 and
l98CF8l
only; Insutilclont
numbars
ol
.
samples rero ol
lesied dur Ing 1978-79
to idrront stet lsf lcal
compar lson.
bval,res
that
aro un,Jersorod
Indlcoto
slgnll lcant dlllerences
(P<0.05)
botrooq
./oars.
tnt
ttrtltl*
of
analysls
the
lnsiirment
las'not functlon'lng opt-lmolly
for
rsasrrromnt
ot thls
e lensnt.
O*"-"ir"t
lons In
€/kg
f
resh ro lght.
1.41
'l
T
I
I
;i.,-..
..
.
,,
.
i
i
l,
l,
,l;t
.
,.j
statisticaliy
signit'icant
tJiffercrrces
in
clemenLol
concentrations
wer.c
not.ed
i,:
for
waterprimrose
collected
at dif
f erent
stations
during
the thir.rl
year
of Lire
i
',
s
tudy.
:
,
at
.,
There
were
also
a
few
exceptions
for
pondwee<!
collected riuring
tiot.h
ilrc
second
.l
and
the
third
years (Appendix
Tables
4,1
anrJ
4.J).
It should
be
stressed
that
;
no
pondweed
was found
at
Station
I during
any
of
the
three
years.
Ccnnpared
to
:
specimens
collected
at
other stations,
specimens
collected
at
Station Z
contained
i,
higher
Cd concentrations
in both
stems
and
leaves
during
both
years,
higher Se
.i'
i'i.
cottcentrations
in
the
leaves
during
the
second
year,
higher
Cu,
l4n,
Ni,
and Zn
l'
cottcentrations
in
both
stems
and
leaves
during
the
third
year,
and
higher
Ca
i,..,,,,
j.'
concentrations
in
the
leaves during
the
third
year.'
Leaves
of
pondvreed'collected
tr.
at Station
3 during
the second
year
contained
higher
Zn
concentrat'ions
than
those
Xl
of
pondweed
collectecl
at
other
stations.
ii.
,i
F.'.'.,
FISH
r-;
,,
'
.
:
,t
'l
f..,,=
,
'
:
:
ii
i'
Three species
of
fish
were
collected
cluring
the
first
two
years
of
the investi-
i:...,..
gation (table'4.2).
An addjtional
three
species
were
collected
duringlthe
thjro
it,
i,',
'
collecting
periods,
and
only
one each
at
Stations
2
arrd
3
during
the thircl
year.
i'
I'han
lengths
and
weights for
the fishes
collected
during
the
individual
years
are
l:;::..',,',:.t.,.
presented.ih
Appendix
Tables
4.K-4.1'1.
Statistica'l
cornpar.isons
of
fish
sizes
at
,.
the
four stations
indicated
that variation
in
size
at the
different
stations
in
1..
any of
the
years
was
generaily
non-significant.
Howeverr
a
co{nparjson
of
sjzes
i,,
during
the entire
3-year
period
showed
sign'ificant
increases
in both
weight
and
ii..;.,..,,,,
lglgth of
gizzird
shad
and black bullheads
between
the first
and
secondr
years
i,
of
collection and
lesser increases
for
largemouth
bass
durjng
this
period
l*t'
(taute4,lo)-'
.
,''',
i'
:
i.':
,
:
il.,-,.
Cunparisons
of
annual
mean
concentrations
of
chernical
constituents
in
g.izzard
$i..,r',.
,
shad, black bullheads,
and
largemouth
bass in
Coffeen
Lake
over
the
3-year
Fil'
,
'period
are
presented
in
Tables 4.ll-4.13.
Sirnilar
comparisons
for
indjvidual
fl11
..:
istations
in
the
lake
are
shown
in
Tables 4.14-4.16.
A
significant
overall
*:t.=
'
trend
was noted for
only one element,
K.
There
was
a
significant
increase.in
f,!i'i
F",::
',
I
T
"1.
,',',
:
,
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Table
4.1
1, Annual
mean
concentrations
(rnq/kg
fresh
it,
constitugnts'
in
musCle
tissrie:.of-gizzard
,
,
!i
.,
quantities
Cof feen
t.ake
are
f
rom
in
parentheses.
Septernber
l978
{hrotrqh
t issue)
of
chernical
shatJ
co I
I
ec
Led
at
0ecember
1980,
5arnple
l97B-79
(
33)
1979,80
(
40)
I
980=Bl
(
40)
Me
an
Fa
'A9
"As
,B
:Ba:
'
Ca'
:.:
.cd
Cr
:
LU
FA
Hgo
i-,
K.
rMg
.
l4n
,Na
.Ni
Pb'
$,
',
Zn'
<l 3.7
(0;49
,
.l,50
0.42
1,298.
0.29
0. 56
0.66
l6'.7
54.1
,
'l
,174.
223.
3:
96
5l 5.
0.1 3
0.24
0.54
<l
.60
<0.56
0.56
0,3'l
I,235.
'
0.33
<0.12
:
0.58
l0;0
:
28.B
4,09
5.
2l
5.
2.90
,7
35.
<0.t4
(0.1,7
, I
"59
:
14.6
<3.07
<0.6
3
,
0.93
0.39
:
I
,4
36.
0.09
,
.0.51
,
0.53
,
1.I.
2
37.5
16,923.'
'.,'"n'
3.03
553.
<0.1
2
<0:28
,1.54
:'
,
'5.90
0.9i
:
:0'37
|
,324,
0.23
0.37
0.58
12
4
34.7
7,783,
247.
3.25
6 35.,
1 ,,27
9.47
(.t
.
t
---
3.0
.,J
t2.B
?.6.7
--:---l
1.2
7A
3.6
48
5.
40.
B
1
,l.q
8.5
t
I
l'.
I
l
l'
I
l'
I
.:
I
aVaJ
ues., that
-
are
.
between
yeais.
DConcentrat
i ons
underscored
ilr€
,i
o ug/kg
indicate
significant
differences
(p<0.05)
fresh
weight.
4.44
ti...
.
'
.
:.a
Table
4'
12.
Annual.
me0n
concentr'nt
fons
(mg/k9
fresh
I
issue)
oi
chernical
:
constituents
ln
muscle
t{ssue-of
bldck
bul lhead
collect.ed
,:t
!orf9'i1.Lake
from
Septemtrer
lgTB through
ftcembcr:
lgB0, ra'.rrple
quantiiles
are
ln
parentheses,
|
978-79
(
t6)
l9i9-80
(
20),
I
980-8t
{12)
i4e
an
Fa
Aq
:
As
B.
<.|3.7
<0.49
I
.80
o:5
3
218.
0,07
1.03
0.73
10.2
994.
207.
0.50
61 3.
0.16
0.54
0.36
7.36
<1.60
<0.
56
I .20
0,?l
267.
<0.04
0.34
.
0.70,
::
8.45
38.
5
2.,757,
164.
,
,
I,00,
568.
,i
<0.1
4
r
0.40
0.38
:
l
t.0
<3.0i
<0.5
3
,
?..
?l
'
0.44
228,
(0.09
]
.
0.36
'
0.29
6.04
B?.6
.l4,354.
235.
1
0.61
:
,'.700.
.<0.14
,
<0,28
,<0,29
' '
'6.46
1.65
,
0.40
?41 ,
Ba
Cu
cd
Cr
Cu
Fe
Hgb
(:,
.
t'l9
Mn
Na.
Ni
Pb
Se
7.n'
3.6
3.5
0.4
I
,
0.57
l
0,60
.
, 8.43
50.4
::
5,069:
I
96.
0.7 4
6r 6.
19.4
1.6
l.l'
4.2
f19,
''
6.5"
2,8,'
q.u
2.7
0.3.
6.5
0.37
0.35
8.6
5
.
between
years.
lffi.re6.out=...
bconcentritions
ulg
in
gglts
fresh
wcight;
rnissing
value
=
sarnple
quantities
insufficient-foi
analysis.
"
'r -
.
I:ri:
I
Iallle
4.13.
futnual
mean
concentrat ions (rng/kg
I
'
:
.
constituents
Coffeen
Lakc
from,Saptember
in
muscle
tissue-of-
lgZB
,quantities
are
ln
parentheses.
fr-esh
Lissuci
of
chernical
large,nouth
bass
collecteC at
thrcugh
{hcember
1980.
Senp )c
t97B-79
(so1
I 979-B0
(
40)
I
980-Bl
(
40)
l1e
on
r'
Aq
As
'
<i
3.7
<0.49
I .6t
0,13
260.
0.17
0.49
:
0.7
5
,
2:.|3
5l ;0
I
,1
25.
267.
0.30
523.
'
a.23
0.77
1.89
6.1B
<t.60
<0.56
4.6
3
0.01
:'
l4l.
<0.04
<0.1
2
0.
r
3
3.
l9
3t .9
4
,
368.
240.
0.75
417.
<0.1
3
<0.1
7
l.84
8.,50
<3.07
<0.6
3
0.55
0.05
J(q.
<0.09
0.60
0.32
2,36
23.1
17,?-3,g.
293.
0.57
438.
<0.12
<0.?-7
I .38
5.47
2,21
0.07
243.
0.08
0.39
0.42
2. s3
36.5
7,08.|.
267
,
0.52
464.
7t-a
?.0
1l.Q
5.4
17.2
-
5.1
?-.6
1
5.8
I9r
,
28.3
2,?
20.
B
'l
:l
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l.
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l
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1,.
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B
Ba
Ca
Cd
Cr
Cu
Fe
Hgb
K
14g
Mn
Na
Ni
Pb
Se
Zn
0.37
t.72
6.68
il.5
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r
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aValues
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.
between
years.
DConcentrations
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::
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, ,
-a
indicate
signif
icant'differences
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fresh
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K concentt'ation
in,, ul
I
t,hree
'specie.s
during
the
3-year'
periocl;
this overall
inctnase
was a
ref
lection
of tha
increase
0t
caeh
of
the
incliyi<lu,rl st.rt
iLrr*s.
eonsiden'in9.the
species,of
f
ish
inclividual
ly, thcrc
are
severai
elemental
coli-
tentration
trends. In
gizzard
shad
{Tables
4.
}'l
and',4.14)', theie
were
signif
i-
.
cant
:
.
decreases
.:
:
in
the overall
:
:
concentrations
of B, fe,
and l{g between
the
first
and
second
years
of
the'stud),.
The
rjecrease
inl [J
concentratiorr
wds e'/ident
at
each of the
four
stations;
the
level of
Fe
was
decreased
only
af stations
I
and
2,,
and
that 0f Hg
at
Stations
i; 3,
and
4.
In
addition,
although not
sevbre,enough
to
affect
their-overall levels
during lhis
same
periocl,
the
con-
centrations of Cd, Cr, and
Cu
in
gizzard
shad
decreased
at Station 2, Statiorrs
3
and 4, and,
Stations
I and 2, respectively.
In con,trdst,:
during
this
sante
:
period
(between
the first and seconrJ
years),
the concentration
of
Se
in
gizrard
shad
increased
at all four
stations, significantly at Stations I
and 2
and
non-significantly
at
the
other
two.
The
single' overal I
concentration
,
trend
.(decrease)
noted
in
gizzard
shad between,:ihe second and third
yeal's
occurred
in
,the
case of'Cdi
the'location:contributinq nost
notably to the overall'concen-
tration
decrease was
Station'1.
There
were
significant
changes
in
the
station
distributions of some
of
the chemical
constituents
in
gizzard
shad
from
year
ro
year
(Appenorx.,Tables
4.N-4.P).
The
elgnents showing
progressive
decreases
in
concentration fronr
Station
1
to Station
4 were
prinrarily
those referred t,o
above.
Concentration trencls
in the case
of black,bullheacJs
(Tabies,4.12
and
4.i5)
,'
are sonpwhat
difficult
to
assess,
since these fish
were
not available
at
,station
l
(the
heated
station)
during
the firs't'and
third
years.'
0nly'Cr
showed
a significant
decrease in
overal'l
concentration
between
the
first and
second:
years,,and
this
decrease tllas evident
at each of
tlre three stations
(?-,,3,
.'
and 4).
Hg
registered
a signifjcant
overall
concentration increase between
'
,ihe
second
and third
years,
and
th'is
inorease was
primarily
a
reflection of,.
'
the
increases
..:
.:.
at Stations
2
and 3. Thcrgh not sufficient to
affect
the
overal'l
'eoncentrations
of"these'elements,
Ba,
Ca, and Na increased
in concentfation
at
Stations
2 and
3 during the
three
years.
The differences
in
elernental concerr-
::::
L
'lrritions
between:s'tations
for' individual
years'are presenled
in Appendix
Tables
,l:
.'
..
'.':
4.0-
4. S .
:::
''..
,
j:.
-."
,,,
,:i
':
'.
,.
:'
'
:
,
.:
=
4
.53
T=
':::.
l
:
,
:
,
,'-,
,
l,
In
largc.rnoulh
bass
(Tables
4,13
and
4,16),
tlre
overal I conccntration
of'
lig
.:',
..
:
'
decreased
significantly
during
the three
years,
a
reflection
of the
decrr:ased
levels at Stations I and 2 during
these
years.
There
rrel:e
significant
de-
creases
in
the
overall
levels of
Cu,
lla,
and Pb
between
l"hc
fjrsL a')d second
years;
Stations
3 and
4 were
the
prinrary
locations
of the
decreasetJ concen-
trations
of'the
three elements,
The
overall
concehtr.ation
of Se decreased
significantly between
the second
and
thipfl.:years;'this was
probably
a
reflec-
tioh,'of
the decreased levels
at Stations
3.and 4 between these
years,
Se
was
one'of
the,few elernents
in'larganouth
bass'that
showed d
progressive
decrease
in,concentration
frun
Station
I to.Station 4
(Appendix
Tables
4.T-4.V):
',,,
'
.
'.'
.:
i
The
main
cunparisons
to
be
made
foi
carp,
b'luegill.s, anti
channel
catfish,
since
they
were collected only during
the.third
year
of the study,
are
.''''
between-station
cornparisons
of elernental
concentrations
(Tables
4.17-4,Ig).
There
was
no significant difference between stations for most
of
the
elements. 0f the
feu
exceptions,
I
and
Se,.'general]y decreased
in concen-
::
,
,'.
.
..,
....-
,
t
:.
,
:
tration
proqressively
from Station I to Station
4;
this
trend
occurred
for"al I three
species. There
was
no appaient trend
for
'rlg
concentrati
on:,ljn
!t.
:
any,.of the
species, although
the
differences
between stations
in
the case
of
carp
and
bluegills
were fairly large.
I
l
I
l.
I
::
:l
':
l.
..
:::
,:,
:
..::
a
:
l:.-:.,
jI'
't
l'
''
I'
l
l=
l'
t",-.:
f'
',:'t.,..
l=
:-
;:--
'}
.
.:::
a::"::
.:::::
.:
4.54
:::.::
.a:'
.
c
i tuents
980-81
.
=
l.
I
2,
2.
l.l
.l-g-
4.r
'1.(
l.
0.;
*:
{t.
0.;
on5
t
in I
_;
_;
z0
2A
20
20
20
2A
20
20
2D
20
20
20
20
20
,20
2A
20
a.?
1.6
t.B
?,o
2.7,
0,6
1.0
4{
4.0
j
t:0
1.3
0.2
3,5.
0.2
I.
aValues
that,are
underscored
between
stations.
bConcentrations
are in
ug/kg
indicate
significant
differences (p<0.05)
r
resn
wel
gnt
.
.
i.
4.
55
iir
':
,,.
;:1.,
.,,;..,
'
?,,1.'1:,,;
'' ,
i;,, ,'; ,
il'.','
i;,;":,'
''
,t
fi','',.
',.'
i:.,
i.;t
,.,
i-i::li'
'
:'
1
ir:
tt,
t
''
:':,],
I
,
.l.
,.
_
tt.--.'.
.
.
Tab.le,.4.lB,
l"lean
concentrat,i'ons
{mq/kg
fresh
in
bluegill
co'l'lected
at iarious
r
980-Bl
.
tissus)
of
chernical constituenis
statiorrs
at
Coffeen Lake
in
Stat
lon
I
St
at ion
2
Statlon
3
St at
lon
4
i4rl a n
Fa
Ag.'r
<3.07
'
I:'
Ar
, .
<0.63
3
'-
,
5,7?
Ba
:
0.10
Ca
,'
'
922,
cd
-,,-
<0.09
cr
,'
'
0.47
'.t:
Cu
0.24
Fe'
,
3.78
i
Hgb
.
35.0
K
,,,.
15,277.
Mq
279.
','t.
.
'''
Mn''.'
1.06
Na
:
.
737.
Ni
.
<0.1 2
.:
Pb:.':r.
'
<0.?_7
Se,.
.
1..
.'.
.
i
I.38
...
2n;,;. ,
,;
8.22
<3.,07
<0.63
5.37
0.12
956,
:
<0.09
0.50
0.3?
3,4?
74.3.
l5,BB4.
,,
286.
l.14
772.
<0.12
:
<0,27
:
I .37
9.'83
<3.04
<0.63
5.12
0.06
BBO.
,
<0.09
0.35
0.r0
4. 96
I
02.
t
3,09/.
241
,
0. 75
782.
<0.1
2
<0.27
1.42
9.49
<3.07
<0.63
5.24
.
0,16
I,062.
0.10
0,:34
0,13
:
3.'90
72.9
.
| 2,427 .,'
,
238.,
.0.'93'
.
:
::
792,'
'
'
::'
0.,]9
<0.27
. a,
-'
0,6?
8" 67
?0
?Q
5.36 20
0.!r 20
9s5.
20
'20
0.42
20
0.20
20
4.0r
20
6?..
|
2A
l4,t7l.
20
261.
20
0,97
20
771.
20
2A
20
l.l9
20
9.05 20
6.I
t.J
I
I
I
t
I
I
I
t
I
t
I
t
I
I
I
u,f,
I:-3
:
0.?
I\
,:
::-
:
3.9
0.4,
2.0
'4
.4
:-:::
s.1
0.4
'0.'3
.afalues
that^
are underscored
ind'icate
signi
f
icant dif
ferences
($0.05)
between
stations.
bConcentrations
are
in
uglkg fresh
weight.
I
l'
l
.:l
:
4. 56
i:,:t):;i,:.::
.a
:
Tabl
e
4.
:..'
|
9. Hean
i n
channel
concentr
c af'f
at
.i
i
on
sh
s
.::
,
in
l9B0-Bl.
,'
(nq/fq,
fresh
Lirsue)
col lected at
var''ioirs
of
ch*oical
constituentE
slaLlons at Coffeen
Lake
Station'l
Statlon
2
5t
at ion
3
St
at
ion
4
Mean
t-t
Ag
As
cd
.
0.12
<3.
07
(0.6
3
,
5.43
0. 21
I
60.
,
0.69
0.
s0
,
5.09
.
14.7
I
8,770.
?.76.
,0.49
658.
0.14
<0.27,
0.9?
10.2
'
<3.07
'<0.63
4.71
0.05
,
136.
,,
<0.09
0.44
',
0.34
6.63-
.
30.2'
,
I 6,1 45.
..
232.
'
o.52
631
.
,
<0.1
2
<0.27
,
0.98
.
7.31
,,
,
(3.04
,
<0.63
,,
4,76
0.
t6
',282.
.
0.
r0
0.59
:
0.47
'.
-:
.
10.r.
'
35.4
'
I
5,850.
221.
,
'
0.51
61
0.
.t
: :
0.14
'
<0.27
0.
70
.rr 7.
40
.
<3.07
,
,0.6,3
4.67
,
0.r0
16
3.
,
(0.09
,
0.57
0.37
''
25.4
I
6,891 .
'
zil.
0.34
,802.
<0..l
2
,',
<0,27
0.59
'
7.39
ti
LV
:
20
5.t
4 2A
I
0. 13
20
'
185.
,.,
2A
2A
LV
'
0.58
20
0.42 ?0
6.67
20
,
26.9
2A
I 6,194.
20
235. ?-0
:
4.47 20
675.
20
0.1 2
20'
2A
0.80 ?0
.
B.0B
2A
Ba
Ca
Cr
UU
Fe.
Hgb
K,
Mg
Mn
',
N;.
Ni
Pb
Se
7n'
9:'5
l;B
l?
2.?
,
0.6
0,8
0.5
.t.
2.8
l-9-
0.9
4:l
=:_
0,4
:
2..5
3,7
aValues,that
are underscored
between stations.
bConcentrations
are in ug/kg
iindicate
signif
icant differences
($O.OS;
:"
fresh
wei
ght
.
4.57
:
-
t.
:
.:l:
.
j
.:,i;l:,=;;;..:.r;,-:
.
r.'-,.:..,.,
:,'.
,'
,:;.t'rti:
:.:
.:
0tscrJSSt0H
t-.
,,1.
,1.
Two
of
the
questions
addressed
in
the
second-year
repot't
(Andar.son
eL
dl,
lg{iO)
are
applicable
to the
final
report. First,
did
the
concentrat.ions
oi
any
of
the
chemical
constituents
in
the
lake's
ecosystenr
increase
or decreasc durinq
',
the
J-year
period?
Second, are
any
of
the
constituents
present
in sufficientiy
:
,high'concentration
to be
environrnentally
damaging,
to contaminate
fish,
or
to
'pose,
a
human
heal th
problem?
l'li tli
regard
to
the f irst
question,
the
changes
in
concentration
of
chem'ical
'constituents
over
the 3-year
period
are rlepicted
in Fig.
4.5. The
levels
of
the constituents
in
the various
types
of
samples analyzed
(setliments,
two
species
of
plants,
and
six species
of
fish) were
quite
variable. Five
clements
'(Cd,
cr,iCu,
Hg, and
Ni) showed moderate
to strong
decreasing
concentration
trends
in most
components
of
the lake's
ecosysten
during
the 3-year
period.
Three
of these
elements,
Cd,
Cr,
and
Hg, are
recognized
environmental
contanri-
nants
(they
appear
on the U.S.
Environmen'tal"Protection
Agency's
ljst
of
:priority
polJutants;
callahan
et al.'1979);
therefore, any
reductjon
in their
concentrations
points
toward
effective
c)ean-up
procedures.
0rr
the other
hand,
',the"concentration
of one
element,
K,
increased
inlalI
.samples
except
sedjment
duringthesameperiod.Pbconcentrationswerebelowthedetectionlirnitof..
the analytical
instrument
for
most
of the
samples;
the
detection
l.imit
varies
with the
type of sample
being
analyzed.
,
..
:
,Equal'ly
impor:tant
in answering
:th"
first'question'.is
the
trend
in
concentrations
oi chemical constituents
from Station
1 to Station
4.
Since
the discharge
from
.'theslag.and..flyashpondswasa]lowedtodra.inintothelake.nearStation1.
:,.during
the
period',which
ended
vrith the completion
of
the fjrst
year
of
this study,
l,'it
seemed likely
that
contponents
of
the
lake's
ecosysten at
this station
would
contain
higher
concentrations
of
some, if
not all,
chemical
constituents
than
ecosystem components
elsewhere
jn
the
lake.
Only a few
constituents
showed
con-
'icentration
trends,
andl'these
trends were
quite
variable in rnagnitude.
During
the
first
year,
Cd and Cu
concentrations
in
sedinpnt and
gizzard
shad
clecreased
.fron
the cooling'loop-to the arnbient
area.
The fact
that
the same.trend
occurred
in shad
as in sediment is not
surprising,
since
this fish
is
a forage
fish.
.-- 4.
58
:
:l:
i:-
T
l,
t
T
'a
t
T
I
t
I
t
I
I
I
T
T
:'
r
:
:l
Some
additional
decreasing
Lrentls flon
SLation
I
to StoLion
/r
riere noLed
tluring
the
thiid
year:tB,
Cd, and
l{g
in
se<ilnent
cores;
So
in
largemouth bass, bltie-
gills,
and
channel
cat.fish;
and
K
in
carp, l:lucgiljs, and
charinel catfish.
t{hy
sotne
of these
trenrls
showed up
as late
o's the
fhird
Tear
is
iruze'ling',
since
the'conditions
to enhance
lake ecosystem
quality
were
implementetJ
jlrnost
trro
yearS
earlier.
However,
in
the
case cf
sedi:!1ent
cores,
the
layers
(referred
to
ds segments
in the
present
report)
of
sediment
were
laid down
during the whole
period
of
evolutjon of
the
lake. l{evertheless,
the
greatest
increases in
con-
centration
of
the three
constituents
in
qucstion
occurred in
the upper
one 0r
two
segments,
representing
recent
deposits.
!,lhen
one
consjders that the ldke
is a
relative)y
deep impoundment
and
therefore sedjments
nray not be subject
to
wind and utave
action
to the
extent
found
in
a
shallower lake,
it is
possible
;egments
represent
more
than
just
the
rnost
recent
year
0r two.
Several
other
factors contributed
to the
lack of sufficient
trend
evidence
betleen
the
first and
second
years
and
between
Stations
I and
4. Too
few macro-
phyte
samples
were
collected during
ttre iirst
year,
a
iritical
year
jn
the
'ibefore-after"
evaluation
of
the r,raste
disposal
inrproventents,
for
valid statis-
tical
comparison
with
samples
collected during
subsequent
years.
ilo
Arnerican
pondweed
was found at Station
l
during
any
of the.yea)'s, and
no black
bullheads
durring
the first and
thjrd
years,
naking
it impossible
to
determine
what
effect
this
station nright
have had on the
chernical
constituent
concentrations of
these
two ecosystem
components.
Based on
the frndings
of Mayes
et
al.
(1972)
and
l'ludroch
and
Capobianco
(1979),
we
might
expect
to have found
that
the concentra-
tion
trends between stations evident
in
the'sediments
cluring
the fjrst
year
were
reflected
in
the macrophytes.
Considering
the
general
decreasing concentration
trends
in the various
com-
ponents
of the lake's ecosystem over
the 3-year
period,
an adjunct
to
the
first'question.is: l,lhere
did these:elentents
go?
The outflow
fronr
the lake
'is
nonnally'not
very:1arge'and
probably,would
not
account
for
the apparent
decrease
in
elenentall concentrations. However', tltu
flood
concli tions
that
w'ere
prevalcnt
in
the'spring
of tgZg
(see
Section.3) resulted
in
dilution
of the
elenents-dii-
'
9ol.ved,
in'th.e lake
water.
Subsequent discharge of
the'excess
volume.of
water
oveithe.spil]wayin.effeitdepletedihe.]akeof:aiign.ificantquantityofits
:i-
:
I
ihenrical
constituents.
tn
[ur-n,
the uptak,e
of these cner*ical const
j
tuents hry
_
I
other
components
of the
laLe's
ecosystem
was
reduced.
I
There
are
at
least two
other factors
that
may
have
contributer! to the
decr.easing
trends.
Thus
far,
r.ro
yearly
measurements
have been
conrJucted
on ihe standing
crop of
macrophytes
in
the
lake.
l,lhile
the elsnenf.al
concentrations in these
plants
have decrease<i
from
year
to
year,
it is
possible
that the total biomass
of
the
plants
may
have increased
during
the same
period.
Distribution
of
a
constant
guantity
of elements
within
the
increased
bicrnass
vtould
result
in
an
apparent
decrease
in
concentration
of the
elements.
Another
alternative
might
involve
the number.
of fishes
taken
by fishennen.
Al-
though
the
lake
js
c'tosed
to
public
fishing,
a large number
of
"trespassing''
fishermen
avail
ihemselves
of the opportunity
in
any
given
season.
If
large
quantities
of
fish are
taken from
the lake, and
if
there is a
reduction in
the
quantities
of
chemical constituents
being added
to
the'lake's
ecosystenr
(by
virLue of
the recent modifications
of
discharge
disposol at
the
power
plant),
there would be
a
gradual
reductiort
in
elemental
concentrations
in
the
fishes,
especiall;,as
nelv
crops
of
fishes
appear.
, The answer
to the
second
question
can
be
approached
by considering
the
concentra-
tions of chemical
constituents
that sometimes
accumulate
to undesirable levels
in
aquatic
ecosystems;
these
include
cd,
cr, Hg, Pb,
and se,
As nrentioned
above,
Pb
concentrations
were below
the
detection
limit
of
the
analytical
instrument
for
most
of
the
samples. 0f
the four ecosysten
components
showing nreasurable
Pb
con-
centratjons during
the
first
year (pondweed,
gizzard
shad, black
bullheads,
and
largemouth bass),
on'ly the bullheads
contained
measurable
concerrtrations
during
of
the ecosystem
components
contajnect
measur-
ahr. levels of Pb during
the
final
year
of
the investigatior,
n
gratifying
,
findin^g
when improvement
in'enviionmental
quality
is
the
aim.,
.
..rAtchiion
et
al.
(1977)
and
Murphy'et al.
(lgi8)
have
pointed
out
that fishes
in.
:ecosystems
contaminated
with
high levels of
Cd and Zn take
up substantially
lhigher
quantities
of,,these
elements than
do
fishes'in
uncontanrinated
ecosystens.
They
conclude
that the relative
levels of
these elements
in fishes
correlate
I
t
I
:i
t
I
I
I
I
:
I
t
I
I
I
,
t
:l:
j
,,::
r:
::
r
:
,.1:
.:'....-
:.:.:,:
::.
1.'a
tt.it;.'
):
;
i':
':,:,:,
,'
r',
:','
:'-:li::.:
:.
.::
]
z:i.:.,a,
,,,.:'.
i;,
;,':.'
ir::
ll;:..:...
'1.'t::
.
t:,
:-
'
:::,
.,-,
:;'.;;:';::
:-1:,..
i;,,a::r..l
:
vil:,::
:
!i,:,'..,.
7t.:'.',,'
;:a:
-
a:.
-
i.'1,;:
i
i.:1::t
-
;a,:
:.
;..'
!:..,
..
:
i,:,:
.'
':,'
t
:;1::1.,,
!'::
::::.,a.'
i
i1:':,:':.'
i:ta:.:.:.'
t=.
iji
::
::i'r
: .
-
ii:i;:-:.::
'
:i::l'
:
::.1
t:..".'=: .
:
f==.,:,'
I
::1
i.i:'
r::
)'..'
t!::i.;.::.:
i.
,t.-
-i
.
:|it1-.:. :
#i-
'-:';).,
't
.
'
{?+::
-.
*L:; a::'
::,
4.60
i.-'
.:,1,
€rl
I'l
::<-.
*
i,:-:';i;
*l
it,. '
FT
i1r ,.'
il
ij.
ll
strongly'rith
Che rOi;rCi!'f
le',ris
i.li
f-ir.
$;ct,
rjt,tl::i::..:.:..:r;
:.,:::
::r.'rr:..i.
.::i.::
sedirnnt phascs
of the
ecosysi(tri. In
ltn'
i,r'r:.!LT'ri
:,i::rj':.
:.i,i,
.,,rr.!,:i...
,.:r
1r'.':{:::r.
Cd
concen[ratl(trls
in
all
e(-.()$f*:ftrii r:.riBl-rrirrji.:r
qfi.;1.;;:u:,
1!-r.;
,...r_
,:-
to
rhe
gxterlt
of
beirrg
bclr.r*'rhe
rjerrtcr.iirr
r.i;:,j!- i:r :;!',.r.-r.;,
',.t!
lndlcative
of
imrt:ovtrrer,i
in en':irg!ie!11-ri
]
rlrli
r
i i
,..
,
-i'r:r:
::.i1r. .
,
drat^tn
for
Cr;
althtruglr
the decraases
<jjii
ni-rl ;i;r[:!-r:;;r:i!
ti;i-
:i:-..i,,
abiltty.
'lltese
decreaskrg,
Lrc,rrds
jrre
r€f :ec{.ir:!::; r,:
:,i;,..,:
;.r:,
.ir-,,
occurred
in
the
surrsurdinp-
milieu.
ltre
rgnaitiing
t-wrr elenents
eif
envirorr''snt..rl
{.lr.'lr:.ur-r
;rrrt
if'.u.'ej
ir..
&l e-,"jris=i
i;-,
Fig;
4.5, llg
concencration-s
decreased
ln
all
ecr.rs.ii;rrj:.i
crnrrl:ir{.r?,r
{:ricff,
l,i;ir_k
buLlheads
during
rhe 3-year periocl
.
Jhcsc trrgrds..rir:lrt.*i.-.ll
ii',,,5,1-
!,:rt.i.t.
;rr.r'
prosented
nurrerically
in
thble
4.20,
Se..'cral
ln.sr];ii.il,itt.t-it'J,
r,iliid
c..r ,.1
i.
::i{+,
Speyer
1980)
had indicateJ
rlrac
Se
lwly sr;pr:-r:ss
tlie l:jr;;ir.'r:r-r:r.rl.,i!"jr*i:-,1
i!:
.:i':rr.r.i
be
proteccive
againsr
roxic
effecrs trf lir-i
in
fishes.
'i'l:e
ri,r:..r
i::
T;:ir!e
i
j*:irsTiesis
rhat
j-n
coffeen
lake
se may
srpFrcss
thc bitxrcn-ur.:l;lri(!r
r:f
lil
i,,',
ir.izt,tz.i!
s!:,ri,
l;r.:.,
not in
largonxfh
bass.
ltrere
has
beett concent
ahottt
the rcl>rcxluc'-ivc
l'irilurc
cj'Jlisi:c-s
i::lr,.ilrir-i:i1:
i;ii1,1
confaminaced
witfi Se.
Itt l.a!<es
not
sub.ject
Ln cxlxlslrr(r
lti in,hl;iri.rl
;$lijir.,i
r:lrt-
tnercial
wastes,
the
concentr;rtion
of
Se in
fish
nr.:.scJc r.rl'ri,,.
e:r.rc.e<l.s
I nir:
(I'akkala
er al
. L972, May
antl
llcKinney lgSl).
!'islr
rep:',;,rJuci
ir.::.i in s;r.:r:ii
i;:i<r..,r
jr,,
usually
nonnaL.
Ctlrbie and V;rn
Honr
(1978)
rerxir.rcrj
tixrt
l:i.,rlx.s
fr.rn:
ilrc
mjn
portion
of a ccnl-ing
lake
fcrr
a coal-fircd
lr.:rr'er
pl;rnt
in li-.rrtli
(l-::rr.ljjni
i-ri.x";:
riinei:
Se aclevels rangirrg
frsn 10
to
50
prm.
Rcprtxlucticar
irr
thtrsr-: !'isirc:;'^'as
rr,rrke.ci:...,
reducecl
. C,onversely,
Chese investi.p,ators
fotsld
th.rt
the Su
ccl';c(:ntrar-il!.:s
ii-l
fishes frcrn
a
renote
(urrconcamlnated)
frurrion
of thc
l;tkc r'ruu'.rrrl
!'rtrn
6.]
i,1 i.{l
ppn.
Ttrese fish
reproduced
norm:lly.
Since
both Coffeen lake
(rhe
subjcct
of the
prescnt
;itu(ly) atxl
l;rkc
Sani,,clrris
(located
approximately: 45 miles
north
of C.of
feen l-lke)
are
crxrl i.rrg
l;ikes
f(rr t:c.',r
j
-
fired
pourer plancs,
tlrere is
concenr Lhac
thc fj.shc.s
irr
lxrrh
of
rhese
l;rkcs rnry
contajl high
levels
of Se ancl
nury
thtr-s
pose
a hrrnu'r
he.utcir
lrroblsn. As
er,rirlcnt
in Table
4.20,
the annual
IIEan concentrations
of Se in si-x
spoci.cs
r;t.
fish
take-n
frqn Coffeen Iake
beueen
1978
and 1981.
rang,,ed l:rrnr
less
tlun
tlrc
cJeccction
lirnit
fil
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fish.
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these
poidr?rr
$la*t-:
rfff:'Lr rt,*r*
r.,ltar*ii
li;
iiri=.
irrtrkij
of
water
frorn
,l deplh of
ep;lrorinrately
ll'n
*:h*re pup,-rlati.;nr
ci al!
gr,.i,r;rs
irf
al.lne Here
,rrore
spilrsc,
thut thf abrrnil-lnce
sf
al l
th,/t,)rri,i,r'rt,'.rr
irr
Urir
rlischarge
dreJ
vtere
alsr: r^rlrlrrceri. fhc
:.
ovcr-rli ;bltnrl.rnirr
,if
grliyt;i;ri
rrrkt::rl
.1ort
clrlorophy"l'i
g
c,i,rcentrations
'eere
wiii:in
Lh*'ranqi,'s
of ii;rri{i,tr}c'l'
in
L.rXc
'.
55gtOWi lle
lnd
lake
Sanqchris,
lwo
other
ei*trtl!
:li
linci,q
J,rlr:i.
phTtgp!antrrltli
prirnary prorluctiOo
rates In
thil:he,rle'rJ'-ar{:.a,./rere
rrot.
siq'r'if
ir.anl.iy
rl
iifererrL
f
rorn
those values al
ottter
locations.ln
thn, lake,
I}e
peripriylon
in
the
,l
discharge
area
of
Coffeen LakC
was stressed
such
t!tit.
r.rf,l1ls-u,i,;ru*lfr
rdr.tg
rnd
diversity
,t,
of
the
perlplryton
rrere
observed in:relati*n
to
those
+L
ilre
irluku"',
-"
l
are'i. Recovery'of,
the
periphylorr
was
nradual
aL
:!,rt
ions,
lccafstl
within the
--'::
cool
Ing
loop from
tho
point
of
dischnrge to
the intai:e
,]r0.t
whr:re
rnearr
jbunrlarrce
.
..
...
..
:
on..gl'ass: s!'ldes
was
more
than,iix
f
lmes
as
great
as
in
the disc.hargc
area,
:
'
:.:.
r,'i
,
'lli
i=
i:-;-rnl.
jtrii
,l
i1,.'.tjfi
;
:ii
.,,.
.
.
,,
i,,
.
5.1
::
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,:"
:
,
'Ja$tg
hgat,,,ind
erjrrrtn!:*ere
d
i
scharge
ilred
;
,rrlpdrent
I y
,
present
in, that
a'r"ea
of:'.the
n*l
,
thg.
trilf
.a
t'r:*ri.r-rs
;1{
iiei
ri:ttlt*!-1
t! rf
cr,--
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1i:r;i{=
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ra,!
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u-4,:
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irhr:.
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ttt.,
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l.
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l
.:.'
l-
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r
l"
:
-..:
.
T,
'ai
l:
I
a,
!l
tnlgoflilcl t0ii
lnvestigations
of
aqurtic
environmllnts
havc hcen
rrnrl*:rt;ir:rr
in
ili,iqy
i:rii.r
1;i
determine
the
ef
fects
of a
particular
stress
on fhc
!riut.a
within
!r,ir:li
:r-*l-€rq.
l
!'lany
tropltic
leve'l
s dre
present
in nrosL
arlu tt
ic
{:c(.}r,',/s!.{rns
..:rrrj llierrj ii
conslderable
conplerity
oncl
lnteraction
betwecn
qroups
0f 0rqaniso5
in
5rlen
systems.
The
effects
of
stress situationg
orr
the lriotd
nrc
often r0
srlbli';
Inal
sturlying
only one
group
of
orgdnisms
may
give
a
biased viewpoint ol'tire
conclition of
that
borly
of
water,
For
that reason,
it
is
qrrile
irnporLant
Lc
stirtly
groups
of organlsms
f
rom dif
ferent
trophic levels
to
make
nn assassrrent uf
an aquatic
ecosystem, One
important
group
is
the
3lr;nei
as
prirnary pr.rducersr
they
produce
much
of
the
organ
i
c
mater i
a
l
consumed
lr.y the
"h
iglr0r
"
Ir'opn
ic
levels. Algae, including
phytoplankton
('isuspenderl"
algae) anrl
peripliylorr
(attached
algae)t
dre
not
only useful as
water
qualit-v
indicators anrl
as
prinary
producerstlfoxygeniltaquaticenvironments,ttuttheyalsoait|indeLermininq
the
trophic state
of a
body
of
water. Based
on
thosc
concepts,
invesLigalions'
of
the
phytoplankton
and
periphyton
corffrrulriLies
of
Coffeen
Lake
were underlaken.
io
satisfy
the following
objectives:
(l
)
to delerrnine
rlifferences beiween
'phytoplankton
species c'rnposilion and abunrJance
in
clifferent
areas
of
Coffeen
Lake,
(2)
to
evaluate
periphyton
colonization of
glass
slirles
in tire
intoke and
rlischarge
areas of
the
lake,
(3)
to
estimate
prirnary
protlucLion
raLes
in heated
and
ambient areas of Coffeen Lake,
(a)
to
r;se
data on
phytoplankton,
periphyton,
and
prirnary
production
to
characterize Coffeen
l-ake
in
relation
to other
t'llinois lakes,
and
(5)
to determine
the
cffects of
power
plant
operation orr
the
phytop'lankton,
periphyton,
and
primary
production
in
Coffeen
Lake.
Hfiltil
iALS
Ar{il
f4l:ii!ii*-c,
PI,IYIOPLANKTON
Iriplicate
phytoplankton
sarnples
wer0
c0llcct.r:rl
rrorilr!.y
frrrir
?l{,ltrly l.l/ll
through
l5
Septernber
l9B0
aL f
our
lake
statiorrr
(i.e,,
StaIions l,
Z,
j,
ctnci
4,
respectively)
(Figure
1.2).
A
phyloolankLon
sample
consistarj
of
,r
rnc,-i
iter
':
',.
sample
of
rteptlr-integrated
water
taken from
Lhe
surface
to
[he bottam
of thr:
euph0tic
rone.
0ne-l
iter
samples
were
also
lakerr
near the
lake
bot.tom
wiLh a
,
' ,
Kcitrnerer
watet'
sampler
at the four
major I
ake
stations
durinq the
sdile tinte
pr:riod
ancl
al a depth
of 6m at the
power
planL
inLake
frorn
Sepleqrber l9/9
witlr
l0
ml of acidjf
ied
Lugol's
solution.
The
sa,nples
were retrrrnerl
to
lre
-i-,"laboratory
where they
were
allowed
i,o
settle
for
approximaLely
Z
days.
The
-
','
water
that
the
was
final:volume
t^ernoved f
rom
of
each
water
sanrple.
and
organisms
usinq
a suction
was 50
hose
rn'1.
anct
Three
a
,,j,,
subsamples
siiapetl
tube
from
so
,.:,
each
of
two
replicate
sarnples
f
rorn
each
stat ion
were
place<l
in
Lhree
',':'Palmer-Maloney
nannoplankton
cells
and
l'our
visible f
ielrJs
from
each
cell werc
examined
at
400x.
AlI non-diatom
algae
were identifed
Lo
tire lowest
possiblt:
taxon
and
cliatoms bJere
recorded
as
centric,
penrlatL',
or
[9lq!-Ua
spp,,
with
Lhe
exception
of Rhizosolenia
spp.
and Skeletonema.
potarnos
whiclr
r.rer.e
jrjenlif
iecl
to
:'.,'sP€cjes
when
possible.
Perrnanent
diatom
slides
wele
prepared
for
spccific
identifications
by
cleaning
a
suhsample
of a
qiven
sample
slurry
acc6rrlipg
to
modified
methods
of Van
der tlerff
(1953)
and mounting
the
diatoms
in
Hyrax.
0iatorn
valves
were
counted
and identified
at
1,000x
or
I,250x in
ranrlom
transects
and
the
densities
of cliatoms
in the
original
sarnples
were
comprrted
by
.,,,'-combirting
relative
abundance
est'imates
f
rorn
diatom
sl itjes
with
centric,,
1)ennate,
and Melosira
spp.
counts f
rom the
Palmer-Maloney
charnbers.
Non-di
atorn rlens
ities
in
the
original'samples
were
comprlted
using the
appf"opriaLe
multipl
ication
factors.
Phytoplankton
were
reported
in
algal
units
per
liter;
an
algal
unit
:
was ctef ined as
f
ol lows:
:1:',':,,1.:;:1;
'
:'t
t
tl
'
,,
.=,;-'',;,,;:
;
,:'
:',,':'
:
.,'
'".1'
5.4
I
I
I
t
I
T
T
I
I
T
I
I
T
I
t
I
-'l'
':,
',
-'-
i,-,
.l:.,
..J
ALGAL
FORH
itil ce'llul
a'r
Colonial,
,t
i
F,i
l amentous
:-
ciiLLS'
PEn iJf{l
?
*e
ac
h,ceTT-6i
tliaia6-Tr
irs t','i
c
-4
ccIIs
cxcept
bIueqre,.rn
,f
i1nl
witlr"'eel
ls'less
Lhan
trwcr
Elricrcrn:
in
rlianrcLcr
ln
50 cell
unri.s
-100
m'icron
lengLhs ,
'
rl
Taxonomic keys
used
for
algal
irlentif icatiorrs
inclu,JecJ
H,isttrlt
(lg3C),
Snith
(1950),
Prescott
{1962}',
Patrick
uno''R*imer'
(1966},
Iif
f
arry
onrJ
itrirton
(l9zl
),
anrJ'
Patrick
and
Reimer
(1975).
'
':
I
:
,
t
-
',
',
PRII4ARY
PRODUCTION
:
:
Pritnary
production
measurements
were made
at. Staf
ions
I
,
?-, a.vJ
frorn
the intake
area
(Figure
1.2)
bintonthly
from
September
l97B through
January lgSl
arrrl
aL
l'
staiiorr
4'birnonthly
fr:om
March
1979 througlr
Januar-y
lg8l
using oxyqenl
.
methodolooy.
Integrated
water
sarnples
collected
fr:om
the
euphotic
zone
were
pl
aced
in
'l
ight
(c
lear
)
ancl
dark
(opaque)
bot,t
l esi" and
tlre rJ issolvcrt
orygun
:'
,
concentrations
were deterrnined
using
a
YSI oxygen
meter
(,SepLemher
l97B) and
l'linkler
methods'
(Novernber
l978 ttrrouglr
Jarruary
lgBl
)
accord
ing
lo
Standard
'
l'let,hods (APHA
et al.
1976).
The I iqht
and' dark
bottles
were
suspended
jn
the
water
at the
surface,
l-meter,
and
2+neter depths,
After
J
Lo
5 hours
of
incubation,
the
oxygen
concentrations
were
determinec.l
again.
The rates
of neL
productionrwere'determined
using methods
<Jescribed
by APIIA
et
al.
(
19i6).
Ihe
euphotic'zone
depth
and
an
pyranometel.
chart of
sotar rarJiation
durirrg
each day
used
for
prirnary productivity
were
userl to
calculaLe
the net
er:photic
zone
primary
prorluctivit.y
in
o2/n2/aay
ancJ i n
02/g.Kcar
of solar
rasli'at
ion.
.
PER I
PHYTON
Periphyton,was
co'llected
quarterly
oh'glass
slides
suspenOert
for
28
clays
in
floating
periphyton
samplers
at a depth
of approximatel.y
0.025 rn.
Quarterly
collections were
made from August
l97B
through
February
l9Bl.
Triplicate
slides
wer'e' col le-cted at each''of
tworsamp'ling
s'uations
locate
d
near
tlte
Discharge
an'd
.
Intake areas
of Coffeen
Lake on
all eleverr
sampling
dates
ancl
at Statjon
I
and
.
.,..-:
):. .:,:
the
dam area
on
the
last
six'samplihg'dates.
At the
time
of collection,
eac5,
,:..:
.,tr
:':t:,4
,i
l=
:..:
slide
t{as
preser-verJ
intdcl,,in
hottles
corrLaining
?
ml
of
,aciitif
ied,Lur1ol,s
solution,
and
O:
mt
of
water'.
Scrapings f
rorn
Cuplicale
lglirles';rerrr:sti.r,,ij.i,r
llaring-blender
and
diluterl
te
a
known
volume
(e.!.,
b0rnli.
ii,*.algae
irr
itr:e
sarnples
werc
Lhen
irJerrtif
ied
,rnrJ
counted by ilic
,u,,,a
n.o.odures
ort
Iine,l rol.
phytoplankton
samples
exceot that
the
dppropriatc
rnultiplic.rtiorlifoeluru
onio
used
to
give
densitios
in algal rrnits per
l0
cn2.
Af.IC I
LLARY MEASUREMENIS
.:
,:'
:
t\ncillOry
medsrrrernents
including
temperature,,pH,
salinity,
r!issolved
oxygen,
liqht
penetratiott,
light
intensity,
and
conductivity'*ere
taken
at the
surface
at
the time
of sampling
for
phytoplankton
collections
and
primary
prorluctivit.y
measurements
and twice
during
e)/.posure
of
periphyton
slides.
STATI
SI ICAL
PROCEDURES
Data
for
phytoplankton
totdl
anct
major
group
rJensities,
phytoplankton
prirnary
productivity,
periphyton
major
group
ancl
total
rlensities,
water
temperature,
dnd
nutrients
were statistically
analyzerl
usirtg a two-way
analysis
of
variance
(by
station
and rnonth)
follorved'by
a
Duncan's multiple range
test
according
to'i6e
General
Linear Model
procedure
of
lJarr
et al.
(.|976)
available
on
the
9tatistjcal
Analysis
Systern
at
the
University.of.
Il l
inojs,
Urbana-Charnpaign;
Data
for
chlorophyll
a statistical
analyses
were the
same
as those
data
presented
in Section
3,
Part
l,
here-in
ancl daLar,for
total
inorganic
niLrogen,
soluble
orthophosphate,
and total
phosphorus
were
obta'inerl
frorn
Section
3,
part
I, herein.
Data from the
top
and rniddle
sampling
locations
were
averaged
for
the
vat^ious
nutrients
since it
was
felt
that
those
two
levels
would
better
repres'ent tlre
nutrients available
to the
phytoplankton
that
were
actively
photosynthesizing
than, for-
exarnple,'only
surface
nutrients.
A1so,
only
nutrient datd
from
months in
which
phytoplankton
were sanrpled
(i.e.,
during
the
period:from
July-197B through
September
'1980)
were analyzetl
statistical
ly.
Al I
tests
for significance
discussed
in the results
and
rJiscussion
section
were
nrade
;;rs,,0.05
level.'
'
I
I
I
I
I
I
I
t
I
I
I
I
I
I
I
I
I
:,::
.
"
',,
l:','
.
'..-
a:'.
::
'
'i;1;:','
;,..:
',"//
:j':
:.;,:',
',
'
l-
T.
::::-i:r
5.6
'l
:;l-'
..:
,,..
.-.''.,
..
:,:
.::
P0I{ER,'PLAHT
Rf[AfEO
|ARA]4[TERS
'
'.:,.
Temperature
,'
-
Since the
addition
of iaste
heat,
ort a
cooling
lake
is
one
of rne mdjor
eff,ects
of
pomr
pl,lnt
operatiorr,
temperatures
at d
if f
erent stations in the
lake
were
of
particular
importance
to
this study.
For tlre
phytoplankton
and
periphyton,
',vater
temperatures
in
the
euphotic
zone
(zone
of active
photosynthesis)
were
of
greatest
interest.
Temperature
data
taken at.
tite
surface
ancl
mirl-depth
in
conjunction
with
the
water
chemis-try
data
(Section
3, herein) at.stations
l,
Z,
3,
and
4
were.averaged for
each
month
frorii:July,
197B through
September
l9B0
arrd
els
procedure
followed
by a Duncanrs muitiple
range
test
to
detect differences'betrveen
stations and betwecn
months.
[.later ternperatures
in
Coffeen Lake
were
significantly greater
at
Station
I
(heated)
tnan
all
other
stations,
significantly
lower
at
Statiorr
4
(ambienL)
than,al
I
other,stations and
not s1$rrif icantl,y
different
between
Stations
Z,:ancJ J
(Table
5.1).
,,,Table
5.].
:
Mean
water temperatures ("C)
of surface
and
mid-depth
locations
for four
stations
sampled,monthly
in,Coffeen
Lake
frorn,August
l97B
through
September
'1980.
l'1eans
underscoied
by the
same
I ine
are
not signi ficantly
different.
ll''
,jl
.'-
il'
,l
tl'
l'-
Stations
'-f-,:
2---
--j---l--4-:-
X
25.4
,|9.
B
r9.I
l7.t
r,l':
,'
l,:.:
.
''
i
ii:.,r
'-::,.='.
:.::.;:
'
:
.:..
' :'.,r
..,:
I
I
I
I
I
I
I
I
I
I
I
t
I
I
I
T
I
t
PIiYTOPLAI{K
TOII
-l
r'
:::
Data for
phytoplankton
densit
ies,
spee.ies,
July
'1978
thiough
June
l9B0
are
contained
de'ns
i t
i
es
,:.number
o f occurrences
of
,:
t
ax,r,
phytopldnkLon
c0l lected
from
July through
A5,il
,
A5.2,'A5.3,
and
AS,4,
respectively,
Dominant
taxa
rlt)d
d iver,ii
I
ier
f
'Jr
col lecL iorrs
,
ron
irr
CoutanL
(tgeOa).
0,:Ia
ior
djversit.ies,
and
r'edunr!ancies
for-,.
Septernber
l9B0
are
containeei in
Tables
i rr
, the
append
i
x of
th
i s
report
.
l'wo
hundretl
and
twenty
six
taxa
were identified
frorn
plrytoplankton
collect.ions
rnade
in the
euphotic
zone
at
four
staLi0ns
ancj
frorn the
intake
area at
a
rlepth
0f
six
meters
(Table
-
A5.l).
0f those
taxa,
qlore
than
60 occurrecl
l0
or
rnorc
r:
'
-
l'
tirnes
at
one
or
more
stations (Table
5.2).
The f
iagellatecl
organisms
tenrlecl
to
be
less
coffinon
in
the
Discharqe
area
(i.e.,,Station
I
)
arrd
increaserl,in
frequency
at
stations
around
the
lake
to
SLatjon
4
(arnbienL).
Apparently,
effects
related
to
operation'of
the.power plant
were respopsihle
for
loyrer
':",
frequencies
of
occurrence
of
most flagellates,
This
lorver
frcquency
coulrl have
beert
a result
of entrainntent
and
destruction
of t,he
cel
ls
o,-i,a
r"esrlt
of intake
of
water
vrith
lower
concentrations
or less
tliversjty
of f lagellaLes.
Ihe
fact
tilat
rnany
pennate
diatoms
seerned to,
occur
nrore
f retlrrenily
at
Stat ion,l
and
,
gcnerally
decreased
in
frequency
of
occurrence
at
stations
around
tite
llke
to
Station
4
rnay
be a result
of additions
of cliatorns
frorn
the
periphyton
growing
a1ongtheconcrete-lineddischargecanal..Notr:ends].forthefreqtrencyof
occurrence
0f blueqreen
algae
werc
apparent;
althouqh
slighily greater
fretluency
of
'occurrence
was
expected:in
the
area
of lreated
ef
f
luent,
due
to
additions
f r:om
coves
,wh
jch
had
continual
ly.
high
ternperatures
during
I ate
sum'rrer,
l:luegr.eert
algal taxa:w€r€
sirnilarly
abundant'in
al1
parts
of tlre
lake
(Table
5.2). I,lo
trends
were
apparent f
or
non-f
I agel I ate<l
mernbers of t.hc
chloroplryta.
Abundance
During the
study
period
frorn
July 1978 through
SepLernller
.|980,
the
rneon
densities
of
phytoplankton
were
significantly
greater
at Station
4 Lhan
at
all
other stations
and significantly greater
at
Station
3
than
at
the
intake
area
.J,
5.8
Iable
5.2.
','
Alqal
tarl tlt<lL
:ir.r:urr^r.il
lrj
')r'r,,rrr.
{.of
f
een
Likr
rl,rr'irr;i
n,jrrlh'!
7
r;
r;l
i,.r
'
5c'Dt(:rnbei'
l9Eli. ti*rrel
irl-i,-, ,r,',i
,li.
'pcsEiltle
oeg:urr'cii:i1-'>
ia:,
l;:1
nl
:il
.i:
.nt
tlre !nt+k*
Iirliqr1':
jtl .1!,.i
i
r':ll
.;
?'f
+::':.
.]
I
]
r,
:.i11113!-ryl;
:,
l
i.:rrr-
I
::
i
r,..,
.1
! r.
i
.e
:
,,
:'t:r
'.
l-i,-:i,ij'i
;1
:i::
:l';ii:a:irr'
i{
l:,.i
i,ll!1:
,'i.
TAXA
'
i.t"
al
i..:,!.:1
:
,
'1-''
-r
-
-
-
l*_--Z--'1.;',l3Trl
Clt
l
orerplryla',
Green
coccoids
.,
,6reen
colonies
t-
Ch
lamydornonads
F:
:'
,
:f,arterl
ads
F
Chlorogonium
spp.
[hr,
6len[Tnia radi
atd
Chodat
@T-Tl
g.r.
(
Schrorler
)
t-e;nn.
@rff
rd'll*iA*^
nasel
i
v:--r.
lreubaria
letraedron
setigerum
mlnimum
{4,
(Archcr)
Braun)
-
6,
f{ansgirg
tl.9nith
"
@
(Korshikcv)"tliiret.rk
U.
-
_(Tfir,reT-Tn
Breb
)
ttrrnr,
-t.eqn
.
Uon6TapF-ilIfirrr ry_l!-!rtq!
(
Nage
I
i
)
nom.,ti',;,,
@ur'pii)
Lagertr.
'
Scenedesnrus
dinrorphus
(Trrrpin)
KuLz.
'
"
tGnedA3rluf
ELgJFlr"f,!q
(Tirrpin)
tJe
3re,t:isscn
)cenedesntus
Lrainorii
v.
Lrainrri
i
Shrrir,:rt
'
.@!g.TpilCoF,dJ-
*].-_.
:
Euglenophyta
,
r
lfglqlornonal
spp.
F
FugTeriq-
spf,.
Ehr.
Chrysophyta:
,i
.
F
cf
,
ChrySochrorn_u.l
int
sJrp, Lackey
Bacil
lariophyta
,
".
'
':,
,
Centric.rliatoms
",'.
4q
tz
l?
lb
'll
1",
IL
l6
?
Q
5,1
tl
t/
20
43
il
It
,i
l]
!d
{t
11
., l
ll
:',
a
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t\
49,
lll
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5*
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t/.
(ti
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ll
?-tl
tn
I i:
54
t0
aU
)ir
?{}
(t.lti
l0
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tJl
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t4
ir)
?
l5
52
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lil
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tl
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74
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4l
r9
Melosira
varians A(lardh
mTomTl;-
afornus
'iftrst
.
.
WcTdTEfid !'I6iiEFat
a Bachrnarr n
ffil
oteTl
a freneqtrl n'i-ana
Kut
z..
gvc
loTElF FaT,t,o-irflft
eJ
a
tru
s t
.
UyTf
of e'fle
sfen-Tgc,r,l Trun.
ffipnano?Tscus
splT-
Sfe-pFanoAiscus lrantzsch i i
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fr'tErros*136ffir
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e
7f,
45
c,
?/
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ll
o
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lz
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38,
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t
TAXA
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Pennate
rl
i
atoms
Synedra
rumpens
Kutz.
lfhffinThe"il-dETic
atu I
a
(
i(r.rr.z
.
)
Grun.
$en'rrdntles
eTl,i:g 6i,{,
@TTLeJ
mJSttTssjg
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NavlcuTa
ipp
lory-
favTcula capitaLa
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F?i?ttr@
v.
hglgqrrcd
(Glun.,)
Ross
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FroTr
acTa
Grufl--
mV-i?TId
sy-vrnrffiriea
Pat.
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:
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2i
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ll
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l4
16 ,
l4
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37
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r0
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38,
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1)
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l')
I
to
46
(l
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4'/
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a.{
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t7
7.9
)
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l;i
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fi
52
50
GiiiFfii-ilFna
cf.
f
iTzTdfi]Eipp.
-l{-iT7s?lriT
ilTt7sth'l7 srr,
sp.-
gg,stg!g!t
(KirLz.
)
Rablr.
,
Sf[EEh]T acfcuI dr
i
s
l,J.
S{ni
th
r,,,
XlTIicT'l
a
fiTifonnr-t
(!1.
5'nith
)
itust..
':
N'TTFcl[ia
lqmra-ftKrasske
XTtzscm a
p-ilea
JF*rtz
,
)
'lJ.
Snith
N-if zscliTt
Fo*sTEt
I ata
ltusL.
,
m-[r"IIE in6[taTa-Kutz.
i
Cyanophyt a
I
Bl
uerrcen
coccoir!
coionies
Bl
uegrcen cocco i
ris
,
:
,
,
Unidentified
bluegreen
fi larnents
-:
Aphanocapsa
del icati ssrna.l.Jest
&
|cest
'
GToAilFaceJpp
-
[aGTf-
MArrTmoperili
a
gl
auca
{thr.,)
Nagel
i,
[eTT,,ri6-lieTiT Ieii[TFs i
ma Lemn.
,..spirJiljEsppl111'piu
-, '
,
',
GEITliTdr.i
a
,oerninata
Meneoh.
i'
i
0s cTlTttoiTt
TTrme-TTfa
Lernm
.
9f@E
fritsch &
Rjch
Cr:yptophyt,a
1
:.
:!:
.:
,,.
-,,1
t,,
',.
.t.,
F
Cryptomonads
F
cf.
8!g!.rorr.-
spp.
Karsten
I
I
T
'10
I
ll)
tit
21.
B
44
4
ll
47
5
l,
:
I:
35
44
41i,, 50
53
53
23
7t
i
:
,::::::
,
l.::=
5,'l 0
:::
:.
::
.irvn,(ratth)
,iriil-:litat
ians i
crld
l.
,4r:,irlj;:n.:'jf-
iir<.
.:r!.
1'l-.t
r!
i:ri,.
r
j!):j
;i
.1,:,";
,.
1;r
't:::
lntdke
at-ea HCrc
t:Ot'
5lqniFiC:Ar:ll:l
n!f
f
{jr,efiL
ir-r,;r
r:,:r-h:rrt.ijr_r:
il+lrll
!.
:,.
T'th'l
1' 5' i
l
6rotlqinr.;s
,if
tn{t{tn
Fhytllt}:drtirttn
ll,'r1sili13.r.
itiqrii
:;nir..c
.jilj-l'}
at f
lvr:
saillplinq
staLir;ni irr
c4f
te
cn
i-,]t:,:
br.,rirj
()rr
t.illections
f
r'4m.
Juiy 19?11
tlrrc.rqlr
5epleflrb*r
l_o*{);rinr':rirrc,
uii*{.1:'-rco!-{.J
b7 tEt,
sarne
I ine
are
nal.
riqnif icantly
sJif
ferertt.,
5,rmplr:
si.zes
{n
j
.+rrd
rn4
drl
s
(T
)
a re
rl i
veri
n
I
T
I
I
.:54
54
1
9,370
l
?,980
ltt
ij
,g
lt.i
54
lt),
;11
){l
8,0?-0
AnoLher
differenca
lletwean
phyloplankLon
rJcrrsities,
crprlciel)y
l)ctwccrl
SLa'-ion I
(heated):antl
Statiort
rl'{
arnbirrnt)
,
was
tlre
rJramaLic
f
luctrratir:rrs
in rjen,,itie.,
JL
fhe
ambient:
location
jn
conrpariEon
to
tlre unifrlrn
rJensilies
of
phylopiankton:
:
Iound
in
the
rlischarge
area
(SLation'l
),,{fiqur:e
5.1}.'ln Lake'5anqctrris,
another
cettfra'l
lllinois
fjonr:l.
plant
coolinq
lake,
lreaLer
fluctrrations-in::algal
al)unddnce
dlso occ.trt'rad
at
Lhe
control
staLiorr
llrarr,tt
thr-'sLaLion
localeci irr
thedischargedre.adccordingtr'rCouLant(l9/9a)'Ihis.trendofmoreiutr!fr:rn
concentrations
of-algae
in
the
disch.ln;e
area th.ln in
the
control:dr€d
js
probablyrelaLerJ:tothesullsurfacein|akewhichwould:nirtirnize;tne.eireetor.
surface water
"blootns".
Essent.ially,
the
waLer
passing
t,hrouqh
Lhe
power
plant
would
be frorn deeper
waters
wltere
active
algal
prorJuction
wotrld
be rer1uced
and
populat
iorrs
would i:e
generally
lower,than
at Lhc'srtrf
ace
:
:i::l
,,
,nlorophyll'a,'anoth0r,rnedsrlr€,of
phytoplankLon
st.airding
irop,'was
als0.grrcatesL
at,
Station
4
(2?,3,ng'nr-3;
where
concentratiorrs
were
significantly
r;rr-.aLer
than
all
other stations. As
ncted for
phytoplankLon
densjties,
Station
3
also
ad signficantly
greater
concentrations
nf
chlorophyli
a Lhan
irrtt.^,
f ur,,Z
::.
.
.and
the intak-e
area.
Cortcentrations
of
''chlor'ophyll:l:at
Station
'l
were'
'-'
.'
.
"
i,
signi'i'icantly
lovrer
than concentrations
at all
othe" sarnplinq
locaLions (Iallle
..
which
water is
taken
into the
power
Or:n:.was
foun<l
to
be
1im.
Tha fact
that
:
::
::,
I
't,
I
::
t
I
I
I
I
.:,
I
I
:a:::.;
1
':.
,,.;':
','.,",'r'
11-1
.:.'.
.
il''t.,
:-
1.
.'''..
.
-.-
-
''t
!
-
.t
"
-.-,1
'./
.
:
1_.
:.
-:.
I
-
i
l,
.-
l,
r2
$1t
!t
rF:
LC
al-
a
&c
l{
c
ac
e
eG
!40
oE
c1s
=Ld
qp
Iq!
a.:3
!e
O
F!
r.
?z
etE
C?F
Ug
T
EX
a--=
r
cc
E
OG
L'
L*o
s4
c9
c
tF
N:
O
Q a-
ttu
cG
c
:!o
t;Ee
t-
;r
,.
.(l
i:
i:
:
i-.
l-1
iJ,
--..''
:
I
/'
\
i.,
i
.
'r-
/i
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.
--.'l
rl
U
1n
:
t,
:,
I
t
'l
u
Ir.
|
,"'
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:
,'
l-l'--',
l.'
u
-;---.-1
------;,-;-^
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/
:-
--:.;-
---:;-
-,
I
.:
'.-
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-
5.1
2
lft
t:j
I
Sr
r;17
i
rti1.,,
*
f
jt::ij,ifi
i.
i'.
:
ri
rijiiii
I
:
,lI
fiya
5r3rl)lilr;
r,'!
]i;r;fr.1
iq
d0!
lrll:t
!rln.,
!
rryly
'.\1,:,;11,;,r
'r'l
,;t
af.
ir;rri
ilrt{tt:f
\t.tj((,it ll,./
i
l;r.
difftr'tnt,',,i:rriii,,'.t;,,..
:.',
!;:
.-
'-,;
il
l,
fl
t
-!.
'l'
'..
,1,
;a,t
?f i
ir4
I
ii.'l
:"
)i
t
pOpt,
I
al ion levc
ls
ar-
tite
&l
(leilth
ifef'rr
ii)!1,;
i4rlr
.ifi
i'r
'l
{i*.r:r'' !f
r..1::
!.hl1.r
.:lt
.)r,
i.-
lcnS
.l
antJ
4
(Iatrles
5.3 onrl
5,4i
suF,Cor?-.t'thr f irrtcrr_y ! ir,l!
?.i1p:1r1y1.1381,:ri:l.,rn
dbundance'was.
probably
even i*5.,
,11 Lhr,
1h,r
i1{.,litir.
itiilsf
.
ii..}nit:ie
a*t
}y
i,:r*+r
:
dertsif
ies
of
.plryLoplankttln
anri lrl'*er
,e
r-rnc,:cl?-,lt-ir.!!rs r,:f
:t-ii-iiir'',:iitrlil a
al,r,,l,]t ii;r;
lcoul<lbeexpiainerJby.t.heirtt'ake.lrtr!r|.i5{:h!l''':!:iii-w4{i]|'',t'i,-il5|].]r1f
phytop
I
ank'tcn
popu
I
aL
ions
.
BaSed
On altal
abundance,
lLal-iorr
4
Has'lrrri
!-,l thr.qi:
l.irlr,{,l!
pr-l:lrlrict.i,re
,rs,ril
obher stations
j'n
Cof
feen
Lake
excepL 5t..rt.
ion
I
{
t$rles
5'.
j
arr,l
5.,'ii.
ltr,:
gt'eater
standinq
crop of
plrytoplarrkLon
at
SlaLion
4 w,r:
inosl'l
ikely rrillteri
L,:
the
greater
concerrtrations
of
phosplrorus.available
Lher"r
,{
f
aulr:
5.51,
:',tt:::l
Nutrients'',":
Mean
nutricnt
concentraLiotts
using
Lhe surface
drld
nlirJ-clnnLlr
locatir:rrs
wcr.e
coflpared between stat ions
and rnonLhs
us
ing
a Lwo-way
anJ
lysi
s
0f v.rr
iance
(gerreral
I
inear rnodels
procedure),
The mea,r
concentraLiorr
of irrorganic
nitrogerl
greater
al
Station
I t.lran
at St.aLion
4,
LoLal
phosphorus
was
not significantly rlifferent between
stations,
anrl
soluble
orLligllhosllhaLe
was
siqnif.icantly
greater
at
Station 4
tha'1:at
Stations
l,
2r
,tnd
3
(Tatrle',S.5).
'ns
"
t
'
a
:
was
pointed
out.
jn
isection
3
.(her"ein),
apparently
tlrc
power
plant
seplic tank's
and the seurage
treatment
plant
infiow
were
potcntial
sources
of
inorganic
nitroqen.
Since a sign'ificantly-greater"
stanrlino
irop
of
'phytoplankto,r
. .':a:
'l'
:
a:.4
l'
.,a.:'
, ,.,a
.:.
::
:-
:a:.::.:
.
:::
r..::i::'.:t.;,-:
;
-:
,,.,
s..t I
I
U,gi::
i-::ril-*,$t-{
lt
i:.i1it
i:...:,
i
:
r
I
'.+!
rj*
ir:
.=!,!r:itrtl-,=+li!!'l?
F.
i{i':
?"+? i1r',,,
lt
rir..
€,ilrl.li,.
:,ti
ittltrr',.,1
l'=
{
r::.,,
,'..;:1,1r,.'l
t,i
Jrl
H._f
.ffi.,
jt4,rr'.,r
l:r,'.1
rr
i
i
ii
r
i,;.
:!
1 f.'r.r'r..;!
:l
I
I
!
ai:,ii
r;
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iirrt,r'ig::'l
I
ftgr'iJ,]ti
ii
rt
i
t
r'.;tlljtl
iri
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t]
i:r
l
nt
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pht'rlpirJi*
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prr*rirhati:
1
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1
i
i. !
i
J;
i
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I,:,
ij.+: i
i-t.ti'i'l
T.=,1:'
-
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3'33r**
-
----ii,-
il1--
--,*
-
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_
ii-i,
I
I
I
;1Cri:l$pr;d nt
5t+iii:n
,1
iC{-n!'.iit}t
t+
iJr:tt',it!*...
..lrrr-{
i.:':'rl::r'r':ptr-i.iJ .r
r.+r;i
flhr)sphqr*9
''rnt
i*4trttllfrl
i9
i:iie
I
*f
thr:
!luir.'/
0..:''i${t.
Fltiispil'.Jr;t:
C0nCenlrdt
irt,l5
aerr_,
:y.ft.ltrrr
,ii
it
aL StaI
tr]rr
.i
rlt,-?rg
,'-zrlirgplrrrrptr,rtri
l:!!lrn(l
niiiai{ift1.
i':jr-
":rr-rl!-.
!.!.ll
itrli
I
lale+a:'J !
r:;:iiifi,l
ili::"4!J'"i:
li?i:r:riitit
:r:.!
!
'l?
ir:n
I, tltc
r;rrl
.l!,i:.r!.
.:iq.:;
liii;:'t,::;.i
{-i-}tli:er}t.rt!.
i:)tt;
t;{:s..=
'.
ir;l:i
f
!i..:rr!.,!,;
I
.
T
I
I
those
f oun4
al'nl
I
ofircr
staLjons.
.:,!irrinq
.r
197J
t,;1r-j,;;,,',
i!r:
!i.':..
ProLecL
iort Arlcltcy
(
l9l5a)
f
orrnrJ Llr,rl.
r"lof
f
,r.;rr
i-
r!.i' .r.ti
t)hir\[Jrl,iIir.,
i
.lnd
Auqust
ltul lt itrogr:rt I
irrr i
ler!
irr
tlc
Lob,]r.
Cornparison
tq
o_the
r
l_l
l_i
nti_s_ I
tke:
5.14
,
The
mean,
concenlrdtion of
plty.lopl,rnk'Lon
irr
Cof
fert{r:,l.akc
i
!?,1(J{) .r11al
,rni
ls
.,nl-l
)
r{d5 sl iryhtly
lower Lhirr Lhc mridrl
corrcentratiorr
irr
L,ri:r,
i,hriilyvi
llir
(15,600
algal
units
.m1-11,
an
unhe,rte(l cenLral
Illinois
rr-,sr:ry,1
ir,
,lrirl irr
:.Lake
Sangchris:
{20,100
alqdl units
.rnl-11,
annther ll linoi:
inoliyrq lakr:,
..
based
on
datd
prescnted
for lhose
Lwo
lakcs by
Corrlarrt
(197<]a).
il
iglrt
ly
different analysis
and samplinq methods
plus'thc
lower
rruLrienL
loading
oi
Coffeen
t.ake
(see
EnvironmerrLal
Protection
Agency;
l9/5a, lg/51r,
,lnrl
1975*,
:worrld
seern
t0, explain
the
0eneral
ly,,lower cbltccnLrat
jons
o'f
phyl0plarrkLon'
.:observedinCoflfeenLake.
..
I
',
I
T
I
I'
'l'
'a
.-
.
::..,1:
:'
:: :::
l
.-tt
l'.
,t
a
Itt*
=*Sl
i-a-!t+:.tarlLr.;r"
ri.,
.:.|
.'
ri'it,-.
.
r;
;,
:.
t
hf-.
;:+.1i*''t'
1{:
l{r:iy-.
,4;;,,
i:.141,1
!:=,_+:,
!::-:r:
+.
lrqhl=iy
4rr:*tiir
!l|.1't r';,:r.ii'{i4l,a.-:i
i{ii:!
ir:
::ii;i:
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i
ilnt
-f
f rt-;:r-;
1!ivi1;-r
,i*1, t
I
i!:.{,*,
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t".\:::
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;tl:::::jjl:
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i
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Trii:';::,139;"
4if
rf
l*qi iJ!
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ehl:rr":rpnytar
3,1{i
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i;r,tr:*pt,
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r-
r;.i,
lcnct:ni
iy
{+l
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A
5
i*i l;r
f
i?
liirsr
i;1r
1;,1;.f1
.i
i141
qredt*5t
it tt.rt
i+q
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arirJ
iltt!'*JiPri
iii
'.rt
{it?!-
tl{
'.t
,}i
f
roil
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J
to
Iir,j
trr!.lkr:
t+
'it,lt
itin
?.
t+
].t
r!
r,it
;
;
i!:
,rj'-.r.i:.-::i,.
,:;,:!r
I
i:
:-.!i.:
''j:
,.
;l'.'i
-'
1
ii'
't
:ii,,l:
.l
l.!
I,
f:
,:j,
I'
I
I
l
,':,
'l
T
I
t
i+lrl'.:5.f;
,:
fit'orrBirrris
r)f rnr:ar'i
plrytop'l
alk
r-on
rir-"r'j
j
Lits
.:i
'lt
vtt
.,,l"rpl
in1
statiortr
irr
C*f
f
eert Lake by ilivi.;irlrr
i:.-rlr:,J
rr:i
r:rt!
l':*lroag
f
rotn
*hly
l9/tl
lltrr;uglr
kptenlter
lJijti:
rn,tarrr, ilol'lq1
r
sr.r.r',.rrJ lly
lltu
sarne
lirre
.rre rroL
siqnif ic;:rl
l-y
t1
i'-f
tren,.
SLnt
i
on s
Di
vi
sions 4
3
'ln
tnke
')
I
I
I
Ch
I oro''
',
;rlryt
a,
'
llaci
i
oplryt
I
lar-
a
tr
yPt
o.
,,:
phyf
a'
4,490
3,8.l 0
3,0/0
3,
I ld
i,000
900
'1
,200
'i
,
100
I,950
740
2,490
300
4'l-19__
-
-3,?20
2,090
=j:
InLake
=::.
r'-'
-l
r'.:
I.
'.'::,::::
-:,:
r
!::4.:':
Cyano
-
4t590
,
',phyt.a
.l
2,290
?'t340
|,630
i.=r,.i.
140
5.ts
:i?*
r:
r.{"t:Pi
!:;14
11-.
irlt:
::i_::i€ia4
: 1€
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il
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.,,
,
t-il{:r{:
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i
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i-i=!=,
:,.
+::
l !
r.'-,rlrl.
l.i
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t.
11tt, ir:t;
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l::-!-l:ir:1i'.
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3,,.1
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lllr.rllrtr'ir;nlt7t
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r:t:l
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r'espectively,
itt
Lakrl Sirelnyr"ill*
,tnrj
!?{. J91
,
!,i{,
:nrj
j/iE,
/,-.ri,.r
}
r;,.11.;.
i,:
Lakr: Sanqclrrit,
two
gtiltr'{4n1,..1
1
l!!irtr.ris lak*:,
!:+tr:ti;:,r;'
i++i.r
ilf
it1!ln!lrj
rrv
ilorttant.
{
l9/.oa).
Ihi:
Chlrtr6pp1,r7i..l
dnd
Crypt,r;)ir;7t r
irirt
,1t
13;lgr.
ir4pc3r.,.
J?i.,r
ir}
!-'r.,.r
piryLolrl4nk[ott
in
Cof
f
een
Lak,: dn(t the
di,tLrxir
lrdit
i'j5\rf i,.rplr,r,l!tr-rt
irr
Ltrt],. I
ric,
v,hile
the
Cyarlrl;rhyta
lrarl
ri;ni
lnr ibrJnddnce itr
Ctrf
fr:r:r:
L<ie,
!!t
i+r.rtliriyj,l
tu
i.,]krl
Shelllyville
and
L.lke
Scrnqcltris, Ihcsc four
,tlgal
diyi.,i+n1
,,!i.-coirilLr:rJ
fnr
approxirnatr:ly
Bl't,861,
and
94'A of
the
Lotal
phytoplarrtst*n'i:r
lcfl,:t:n
Laka,
Lake
Shelbyvllle,
and
t-ake
Sanlchris,
respectivoly.
,
i
'
,i,
lert
ica
l
tJ i f.f
erences-
I
I
i
i,,
.
t.,
,
,
SLudent's
L
tests were used to
deterlnine
differences l)eL.*,rr:n
euphotic
zorre and
near bot,tom
phytoplankton
densities
(Table
5.7).
As
was':exile{ted,
rnost
sIot,ions
,
:,:.,,,,:,.
l:
-
,'
5.16
'aaa
'
,
':
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ri i,,,r
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:::f
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ii
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} I ir:
,lr!:,
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i7.
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.i
1,.
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lcntll,
it!iftit-{:!:{...}g
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.
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l
i
rjrl?.'t:.
i
tJ:p:.rir.i:!;1!+1
;
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i
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t-,:
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?rlrtie
ll
*lif fgr'r;qq.ijc
lf;.lft
r;!irrrr'
\!,.t1.!,]r:.,
11rp1:, 1.
!i,,"
.;-,.,ri..
:i..r
1..
j*,1:!ir
rl
Statitln
?
ll !;:=rri-rrl
iiiij!'t
llrltif {ijr-
t!q+e
..ii1f
I
iri,l
.,4!
,i
\,;i;:
*4t,:{
'r.,.r",,,.1711,
!.,,i'!}.,
,'
inqeiterl
ily
t'r,rpl,triktr)ri
4f
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j
I
i:i
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.,f...
tirt.r
rir.t,.
1,
.:j*j
{}fftgE
:'
tt,riir)nt,
itilrlatr
lrtlal
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x:,rr:
Jt}i;r,_isi-=tl.,ii
Z
,;.:.:
t:
-iriii,.r-ir.
',*!ii,.,
:r1.-,
p0'rdef
pl,lnt ,lilr:lt3r'l;{,
,rLl;ir! i).rvi: ,-rlrut.riil,rt,ir!
l,i :l.rn,!
li
-i.r!
:.r,r
l,
i-,. I r ",r.,
relaLively
sitaill;a
iJ,lflttl
,lt
itation
,i
i,tpiir:irj.-rti,ii
,r,
|*1,
tii,,.-,:iirirrti:
..
.:.
Sdtnpl*5
l{err:
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ly L.tk-r:+
:tl*y.r:l
tqr
ifrr:
lir:l!,i.r:::
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r;i:irr-l
,,
1:,;r}.rri,;
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"
rrr,r-.
Lhgru
werc
uf
Lrlfr
sdin(., frvtlr'l,Jp
irt
tltr: lrlrifj{
.r.llti}ir:il
f
i11-
.,,r.rr?.r,.
1l
,:,,,.1i1..!.,,1i..
ll
l.trat
rLat iorr.
0iversitv
:i-::.-'-r
:
Tha tliversiLy
of
phytoplanktort
{it
SLations
l, 2i,
-rrr,t
3 llrl
+L iii-ar-irlrir
Z,
},
-1,,j
4
were
not
sigtlificdnt.ly
different fr:orn
onf
,trroLll.ir
t)d!*d
o.1
a
L.rrr)-i{ny,lpniysjr
of vdrlanct
ltf station
dnd
month
dn(l d l)urrcanrs
rtu,lLiplr:
r'drtrJrl
lrr11
ii;rtrle
5.ij).
5tation 4'hati
:a
signif icantly
lOwer
rnean:diver.iily
{l,lt)
!,lran
Si.aLion
I
{1.j4}
accordirtq
to the
Uuncan's
Lest.
The facl
l.haI
St,rLion
I
hart gr.eoter
diversiLy
than
:statfon
4' was
expCcterl
due,[o
the f
act
tlraL
tlre
watr:r'
sdnlplrd
f ro6
SLation
1:
carue
prirrrarily
r-rlorn
water',taken
in.,'aL
t,ha irltaP,t--:-ortld
d
srlor.L
L
ime
bi:forlc.
,.
:
5. 17
:
'
!"J--
'
I
":r'tt'
>l=
t:
a'
*:arr tJirer!!{t i*rliIt:: I+,-
'i:.r;;r.t:.:l:i,t,rr
1.;r:
r:,;:
itl
l.rif
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t4Jr;t-nti
t.:t=
..-,,
l;
!,i!'1
'.zr::1
k,:rt"
rillt:L:l!al;1.."'!
'by
thi.:
;.1==
t,
r.;1iq
,,t
+1
.t.-.!.
,:
I
I
I
-!-'
I
-=
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tl:l
1 r:.
'a''
,'t
T
Yhq
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;f
t!i*i
!n'-nl,:
{ili
j
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ll
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r,;
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..;t,
tlitgr:tty
r,tlue
+f
j,'i
i
i-i!,,!li4*
4-:;l,j1*1
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t,:-;:
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.lti :: i i:'
f
fCt, n.lLUrl
l
!
f
.,)ai:Ut-ain<i
]*)r*r ;j!;+r'.
:!.
ir'1
-i1.1
:.--.,:rl
i
1r'
"ii't**-tit"
rl{
rlnll
,1;:
4
ir-'*
E
;lr.,l
,
ih*
:*t.rn
rliy'-:f
ii1.j
t.:l,Jiji cr;,*put":-::j
i':rr"
L.rl{::
ih*}i}:r--,f
:1i.-
il.
i'jt
..r,.
r
.=.!+.,r
1:::]ljChris
i
l..i9'J rr,:r,,
rirni
iar
lr] tirg
i:!.,iir4l
l
ritarr
!t,tr
l-ttf
irt,tn
i-.lia-
i
i,:it
j
..r
!\rj.:j
+n
tlaL,t
rrf
fqr*t,r+i
{}9/Sa)
i:-r.;,,i
i+rlr'
tl,rlirJns
}6
i.1ii'
thtr;ryyi1i,:
:*.f
r*r}r.,:,1
staLions in
L,l'(?.l*rrllchril
frr;re
J:la*
1976
t.lrr-trulft
icig,i:i
l,.l,'j. ili,: rdrriii!1,,.,{
rtivtlrSilies
for
L,tkrr
Shelbyvillc
itn'l
Lake
iianq,
t17'i1
n,i;
,:
f
r.rj,,r
I.iit
t.l
4.11
r
,Jrr,!
f
rfi$
?.59
ttl 4.?/,
r+spectittly.
r.,
['rf
feelr
i-,1hr, th.:
r.tr]rlt
,.]f
Tr,tn
i!ivr:r.rit r,i.,
f*r
the
lake
*.t:,
f r
n
I .ll9 to 4.7{r.
rln
5rnl'nary, tlter* i{*r€ sevoral c,
if
f
ernnces
irr
phy{9p1Jnir
r",Jn
co:rlprs'i't
ie:4
antl
dlritnddnCe ltet'rCenistaLions in
Collcett
t.ak*:
ttia[
ilerc Jppalr-'rll.ly
ri:laLed
l.o
Jrower-
Plant
oper(rIion. ''Flagel laIerl
plryloplankters
ocevried
learL
{requcnt
iy
in
the
ilred
of heated discharge
(
StaUion I
)
and incrCased
irr
f
r.ertrrt,ncy
of
occur.rerrcc
rt.
succcssive
sLat,ions
arnound the
laka Lo Lhe
ambienl area
(StaLi+n
4).
lhc
euphotlc
zone
phytopl0nkton
densitjes
and chlorophyl
l a
concenLraLiorrs
wcr.tl
':
i'
'
si.thif lcantly
greaterr
at Station
4
(amlrienl.)
and
'gradudl
ly
decreascrl
irr
successive
order around
tlte
cool'ing'loop toward
Stalion
I
(lreaterJ).
0ivr:rsily
,t
5.lB
I
I
'l
rlt'phy?.OpiAnitilll
,tt
it,iirlt,t
i
,rlr
.,:,lillii
,r.,r..r
.i:ri,.-
|
fhege
trr:.rtdg
-{:r.:
-agt,!ri+rtt:'.;
i,}:;-ir}ll
-:.;
t
ire
.,:;;1-.:it
t,
1;1
,,
'
,
po'd€r
plaflt
x{itctr
r.rtl:r}l.prl
in +lfiil,llr-:iir}ni .Lr
i,.,rr.-'
t..;-,.,:,,,
dltrtr.:rg*
-,)f
'!it*
5p{rlar
p+p;;1.}l
itJrrl::
lnr{i{.ji1r:
.1,:.
1r-
r:.:.;
i
,
.
.fefiPf,nl
l;"
;n+rq
r{i.S{",f,*
i:'r
t,5il'
r!i';f
hat-..:,:
rirfia
i'!?_
lr.:r=,'r
I
.
.:r.
leSS
f
rurl,rent
i;r
,l tuf
e
E.,5
!
t'r] 1l
tl.
irlnt;
,li
.rr;r;
!
.
r11,
I
ir.,
.
Ihl5
tt
tifiit
tntl
hAve
hcgrr
rJrJrj
to
tht
,trl<i
l!',t.,r. .f
.!1
!!.ir'.:r,
:.
periphyt0fr
groHin j
dlOnq
ilre
Curr.;r,ttrt:
rlirLrr,li
1,,
,1r;
!,,
ilterg
Were
('til'.:r
trt'rii!s
'rrhi-gn
,i+r'f,
not
rr:!"t.-r,rJ
,r:)
{iilsi".
1 pi
i.'.
..rr;.,r.
1.,:{,,t,
rn,,r-:
'l
'da5
e+nsiderahle
'rerticdl
ni.rin:i of
phyir.rpl,r!ti:i;)ri
.!!
.-i,.::,i
!r:r-+i:r-:rr.l
ar.r
rtili
5tatian
?
rhich
wt5
Lhe
deapest ta'.
ion
la
rrple.l
.
i4,ac
irlrylili):
e.r:i?-srr.:
dr.:rrti
i,
icr
antt
chlorophyl la
concentrations in
Cflf
ir-,rvr
l.4kt.iijf'r.,
iirnrijr'l,j
r-it;j.,,..fr...1::r
1.3ir1
Shelbyville
anrt
Loke
Sangchr:ir;
the
slirlhi ljr i,iwer
ti.4+1 iii::i;i:
ipt
1n-
i.1f f
..1-,,'
Lake
could he
explrainecl tly:dif ferent
melh0(,5
+[ or!,tlyris
,rnr!
t./
i!r* i,.rrc,.
nuLrit:nt loarlirrg
of that
lale.
,jhe
dia[ofls lr+<1
l{ixer
rqi,rt.:rtr
JbirntJ6n{e
irr
Cof
feen
Lakt)
thdn
in
Lake
Slrelbyv i
lle
arrd
Laki
Santpclris;
ilr-r-ilr]
*li1.ril
,rnJ
i,rrt
Cryptoplryfa
tlad
lr.eat,er
relitive
obuatia{tte
in
t.offeen
Laxii
liran
irr
thr:
r;t:ier-
ixo
I
rkes.
@',",,
t,-
l
0ata
for,flet
prlrnary productivity
(mg
02'rrr-2.rtay-lJ
coi
lectert
f r"cnr
':Septernber
lllTB
thr.ough f'lay.l980
are
containerJ in Coirtant
(l9g0a).
uata for
net
primary productivrity
col lecterj
from
Jrrly 1980 through
.lanuary
!gttl
are
cortairred
.inJut,|eA5.5initrea9pendixof.thi.5repor|.
,'
Net.
priinary
productivity
(rng
02.gF-cal-l of solar r,rdi,rLiorri
w,rs
qreatr.rsL
,,intake
area
(0.73
Slation I'{0,59
;,
,.'.:
,,
t-'
-.1_-'-
t.'.
;tt,,t:.
.
,.
,.
o.t
,$-ta11ffi
4
r:(0:,91,
ng02.gKcal.I1
and"'lower
at:: Ihe
Ii;1n902.$Kcal-l),
Sliatlorr
2
(0,68
mg02;gKcal-i;
and1
nso2:itKgal'l),(Table
5:n),
":
-,
',-.,.'
'tt=,,.
'.,,...,.,.
','
,.
.
:
itiri;,:r,i
l4i:,tlt
riit!-
ilri:r*t=;'
frt-,;.i;s'-
i,
l
,'
!
!,.y
r,',-a
;
'r !
rnrti4t!'r:t;
it.j.irtl
i;tr:
ilr,r,:lt,.r
r
;
I
.r.
i.,Of
14,-"1
:*.lti'
l:1,,i.1,
it.
.i
a'
t
,
,,:1r;..
!,,ri
..i,in...r,^
/
1.1
ii
.
vr;.ii',,.
r'ti'5.,y
.,.
,r,,,;
i.1
..i,1riif
ir.':tri!.
!? .:iif
r-i!.!r!l:
.
I
I
I
t
.;,!:-
r:r
I
.-r---_'.T-5ai.5...-*.
rl
;ri!-;1r:1;
.
i!_*_
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rif
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.i
,
ir-*rti.
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it ,Jrl
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ilatrle
5..ii.
,
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i
!11r1r;1
i:i:i
ai.,,'r
.:ia,=::;:
|
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! r:.,
t,.r
I
f,
t
I
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I
t
I
;llr
I
'llllora!ly
sp*aiirtg,
'ri
i{lL,tlr-'
}.'}rxi}€r.lLrrrr:!
r}i
ii't,
i-,,..
1,,,.i1'
;i:++:,!r.;,.;.r
.:i
[rt'itnary
p]'rldili-i
irin
h,li
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i..l!\eay13rj, l;r1f ,rt irlt.rr:L
l-q;::g,;;r1!,.;::,-1
1g
;r!)-:.
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i:.!:rri.i
ther'e hd5
hc,ert irthillitron
rlf
[]rlrilct'jf lrr.)drtCl.ivit/
i1
r.r,r
i
1:',
r11,,iii,
l:ri
,r
r..,r,.,
.nccordirtq
t* rJarrirre r
;rrrrl
Srrh;nrr
ila66i
anrl
i.t;r'i;il!l
:1r14
i:!r,i.ri
i
i.iit
j.
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reS(ldrcher'5
ltr.lvtl
indieeied
thnt itrl-/
(i)'ntiirl,lt
ilrr
irt'
trll-6i:11
1*,*-,p,';',tt,ir'.-,
itfliJ
f
llrat
dirJ
rt,:lt
excec(l
35'C
wr'rrl
sti,,rrrldlury
!.a
irrir'-'ar:v
pr-i'.!:j::iivit,,r
{f4ii
ii:r
rrL
r}.
'I
9lfi).
Itrey
tl';,1
irriJir:.,tLutl
tirat
irrhihir-i,rrr
*f
1)ri,;14r-y
?riitiuti.rvi,../
w,1,,
rir,,lr-vrj,l
at
rt
isCttarile
Lfrnpcrntrrres
qreaLer
t.lralr
J4'C
rrrJarJle=rg.rif
i4bieal
ie,!rpr:r,rl..;r.,:5.
0Lher
restlJrchdrs
have forlfid
fh0t
prirnary
prtrCuclivil.r"rrt:r'ililcn
inhihil::ti
regdrdless
of
intaker,Lernpclittures
with
t's
of l0 l.;.3t]"F
i6urtz
anrl
r{riss
rei4).
,
,,
flor,lrl
(in presr,)
lfortnrl
thaL
prirnary
protluct.ion
by
plrotopl,]rrkLlrr
wds
inhibilett
in
the
discltarge area
of Lakersangchris,
a
cool
ing
lake,
rlurirrg
nerioils
when
wdter
tentlle ratures
irt tlre
d i
scharge dred
were
in
excess
of
30'C Jnd
l,h,tL
t.he
;lrirnary
protluctivity
vras significan:tly
grea[er
in
the
discharge
area
than
in
lhe irrtake
area
duringl
periods
when
water
ternperatures
were
tlelow
3rJ"C
in
the rlisclrarge
area. Though
other
reSearclteFs
hdve
found
heat-related
rlifferences
in
productivity,
no.
significanL
differences
were
found
in
this'sLudy,
probably
due
to
infrequent sampling
and few replicates
or
due Lo
the
real
sirnilariLy
beLween
stations,
:::::
,,:
:
.a:..::
.:
j:l
=t.'
:
=.,i.'
':r::::
:::::,:
.
:;-:
i.::
,i;.:::
:a:::1:';
::
i:r:r::l.
:-::i.r
ji.::
1,';-
::;:
,
:;;-::-
:.
i:ii:;:::
:.
:
r;.::
=t-a.
a
!'-:
'::;r::::
.:,
:,.
:
a.a ::'-
,
+1.=1:-:. r.::'l
It€:i_:ir,a.:i,:1,.i
I
!.
l.
5.20
[t{R
I
itirY lritci
iiaiar'fttr
periphy'ron
rjtaiilit!t
i(]{ir-ir:!,
+rril
i:itr:L:",if.r*,,
i.,r,:
.l.lly''!
9iB
thrOugh
.]unr-''
\9t1i;
arZ
ct*teintrl
ra
i.{::i!_.jrir.
i
ili;-1
,1;,,
dg{Cit'lcs,
:pec:
ies.
diver-ciiiti}
,iftrl
rr?rjuf.!i.l4rjr.rr,..-
f
rr-
l,-::.lr
IIBQ
Lhr";iurlh
JJnirar'y
!9Ai
+rr:'{flrlLrrrieil
i'{r
I.:}ii:c
q!:.i,
.\r,.1,
respectively,
in
tlre
di.rpilntlrr
+f
rrrir
repiir.i..
Conrpo-sition
Periphyton
JCc,.nnulatiOns
r:n
glass
llirjt:s
0t
fg117-
st.it,iclnt
d
if
f
ererrt b,rt'de4n
locdt
iofts
(Tablr
5.
l0).
l4iiarr
f
rtn,;
it
ir:c,
't i
t1,,
I :.
:,.t:
,
,.
rta:iii
,jl;rta !r.,r'
,,
!.;nii ! rr;,ir
.i::+,;t;
!,
i-1
.?.,
.atil
lt.!,
I
tl
I
.:,f
.:I
','a
:.I
.':
:I
::I
ilne
|tundred
and
lighly
thre*
L4ra wr:rr;
irjent
if
rrtil
f
r1ilt
,]er,t
;rlr,ri_.r4
colleCtfrj
f
r:*rr
qlass
slides
after
quarterly
28-rl.iy
e\po3uri,
perir.rrtr
Jr.
r,.;irr.sf.
1l.i611
5
in
l,tfir:.,4
Lake
(Tahle
A5'2).
St.ations
incllrlerl
lh+
[nlrrt:e.
iril.:hrr.qt,
,]rrrl
i]a.;r
o.*.,,
o,,n
Slation
l
{Fig,
l.ei,
,
,
.
Abundanr:e
j
:
:
.
gerii
.i
irlni
f
icarrt,i-y
f*ltr*l
unils:iC
:
Tabltr
5.lU
I'lean periphyton,derrsities
{algal
irnir,s
.
io
c'o-2}
on
qlass
slitles
gI?.?.eg
for
2iJ tlays
quarterly-frorn'septerntrer
tg;i
itr,.iugn
r=err,:uJ,rv
same
l9til
at
I ine
f
ottr'
are
locat
not
sigrrificantly
ions
in
Coif
een
rlifferent
Lake.
l'learrs
,rnt,erscoilcrl
with
t[c
"- ','- '
"""
Stat
icns
fiich
a r
g
e
-r*--*
T
-'
-,
-:--lm'
-
-
--
*-*fiir.
;kT
-
-
?15,000.,
_
.-ug!_q00
t
zttgq!
....
'
cn'Z).
were
significanbly great,er'a:t
the
lntake
area
thari
all
other"
sLations,
significantly
greater
at the
Dam
area
than
at
Station
I
anrl
the.'Discharge
ar.eat
"
and,nOt
rsignif
icanb:ly
Oif
ferent
betweerr
S[ation
Lanrl
Lhe
Discttarge:area.
As
can be
seen in
rio.,
S.Z,
inhibirion
of
srowlh
did
;;
;;;r;:
;;
;;,;"r;r;;;.n;'-
,
area
:
only
.:,
.
in the
warnter
rnonths
:,
wlten
ternperatures
werg
near
40'C.
The
inhibition
t
:
I
I
I
:,,
I
I
I
I
I
t
I
t
I
I
.
l'
I
I
l'
1.,
r+
{t
-1-
f
.i
L-'l
,: lf-:
)a
,-.
i
l-
.::-
1
j
.!
,
i-.-
.+
ri
't:
i
.l
I
't
t-.-,
'!
"t
.l
.l
':
.!
_!
'
f-
(
i,.
,1
i
i
:-
-!'-
I
r"
I
I
I
I
I
>i:
:
a
a-
:
F!:
tt
ad:
.
'
€
('l
e5
;:
,
.,9'1
-
u
*.
.
!E':
:
:.ct'1.
':i':
.
:'
"
c.
E6
.Y.r
€,i
:
i, c.
I
.E
+;
.rL*
*q
o,
cu
C>r
q|..
^
c:.
*1
-
t t,
-
E
qt
:i
Gq
;,:
J
:
.8;eE
Li
,.F
rrs4<
L
'
i0p
atj
?JA
:
c:ti
4!-
Feti
vqt
JIl
u
c!
'a:r,
.J
_ce
sFa
d4
9ig
cac
q
!G
g!
du
CJ
CE
u.o
0t
l-!
c
i:r.
d
oF:
sCAj
!
4r
!: i:
.r
ja!
f
4
:d
6
&.
:,
r
--*-
,/
rl
,/
/
--*-1-.T"*
rJ,
i\.i
{i
1
:
!
n""-
4
\-
\\,
-'\--
\
i
I
I
!
l
i
'i
;l-
I
I
,:
i
:
i
9'
(n
?_
l::)
J
:i
(:)
rl,1
L: Z
:
jt
,-,
,-
.*
'
L\
-.
ili il
'-.
: .'
-
..
u.
'r
.--
.--)
ii
i)
-r
.'
.a\:
5,?2
''.,'.,..a
.
i:.1
:::
i:
-
:.1
of.
periphytic
algal
growth
in the
Sischarge dred ira$
4pparent during
,rll
sampling
periods
throughout
the
study; since t.t:mper6i.ure-lnduced
inhibrlion
cf
periphytic
growth
generaliy
occurs
only at
tentperaLures
over 30'C, olher
faulors
must:have
been
responsib!e
for the reduced
growth rdt?s
of
periphyton
in
the
Di'scharge
area.
''Epparently,
factors related
to
the
power
pl,rnt
effiuerit ware
responsible
for
the reduced growth
of
periphyton
in
tlie 0ischarge area,
It.
should'
also
be
note:l
that
the
jnhibitory
effec.t
on
the
periphyton
was still
apparent at
Station'l
and
that growth
of
periphyton
at
the
Dam
area was
still
siqnificantly
less than at the
Intake area.
There
was
a
gradual
recov€r.r
0f
periphytic
Arowth
at successive
stations
from
the
discharge
around
the
corling
i:
looptotheintake.Currentwa5aphysicalfactorwhichwasriifferent'at'the
intake
and discharge areas
and
might have
affected the
colonization
rates lf
periphyton.
Current,
was constantly
greater
at the
rJischarge
area
than af the
intake
area and Cecreased
as
it
progressed
around the
cooling
loop
to the
intake.
It is not likely that
currerrt
alone was
responsible'Ior
the
observed
trendsbecauseperiphyticarowthratesargusuallypositivelyc0rrelat.edwith
current
velocity;
thrrs
one would
expect
grcater
accunulations
jn
the
discharge
,:.::
are
a.
The mean
density
of
periphyton
in
the
Kanl..akee R'iver was
6,400,000
algal
unitl
,.10
cm-2
using the same sampling
apparatus anci
exposure
periocls
based
orr
data
collected
in
May, August, and
November
of
1977, 1978, and
1979
by
Coutant
:
,(1978,
'1979b,
ancl l9B0b). A mean
periphyton
density for
Coffeeri
Lake
based
on,
ail
data
collected
from
l4ay, August,
and
November
sarnplings
in 1978,
1979,
and
1980,was 4,400,000
algal units
l0 cnr-2.
The lower
densities in
Coffeen
'
Lake
ulorrld
lie
expected due
to the
generally
nutrient
rich
environment
of
rnost
r^'iu.rr'lWittiams 1964), sucn
as
the
Kankakee River,
plu:;
the
positive
irrfluence
oflgreater current
in
the
river which would
enhance
nutrient
mixing.
Even so,
the intake
area,
which had the
greatest
periphyton
growth
in
Coffeen Laka,
had
mean
periphyton
densities of 6,400,000 algal uni
ts l0
crn-2,
approximately
the
same as
that
found
on
the Kankakee River
substrates.
The,
overall lower
product:ion:of
periphyton'in
Coffeen Iake
can
be
attributed
to
the
ieduced
growth in the discharge
area
which w,t'l'apparently a result
of
some::
-
'$1owth
-:
J
imiting
or inhibiting
f
acfol
jn
that
area
of
tlre
lake
r.
:,.
:i':.
'a
::::.
:i]:'::
s.23
:ii
.:
::i.
I
..:
I
I
I
T
.:
:'
Major groups
Ihre,e
divjsions
of
algae fiere
rcsponsible
f
or
tli*
ra;jrrrity
r;t
pr,r
iplrylic
ll
: rl
growi.h
on
gltlss
s'l
ides
in
this sturJy.
Thosc
ar$r:ps
rrere Ihe
llriori:i:iryt,i,
Baci
Ilirioplryta, and Cyanophyta
(
Iable
5.1l.).1
irt nac
,0oin'rr:rt
,ri;l
f
or tal,ri
densities
of
periphyton,
t.he
nean
densities
of these najor
'1rr)rjps
r:f
,rlg,:e
lerr:
always'lower
.::
at tlre
0ischarge
area
and
increaserj
as
one
proceiltie,l
arounrl the'
coolinglooptowardStgtionl,tlte0amarea,andthclniakearea.T}rr:
periphyton
riensitics
were
always
significantly
greater
al
tiie Intal:e area
Lhar'r
at
the
Discharge area
{Table
5.11).
Anong
cach
major
<livision
periphyLon
den:ities
at
StaLion
I were
not ri,;nif
icantly
dif ferent
'f
.L',,n
lhos,l'cjensities
at
the
0ischarge area,
Table
5.1
I
l'lean'derrsities
(alga1
units
.
lO cm-2)
(f)
of
the Chlorophy',a,
:
Baci
ll
ariophyt,a, and
Cyanoplryta in
periphyton
coll:cted
af
ter
qrrarLerl
y
ZB-day exposure
periods
at
four
stat.ions
,in'Coffeen,Lakc
fron Septernber
l97B
through
February
l9Bl.
,
l'learis
underscored by the
same I
ine
are
not
s
i
gni
f icant ly
di fferent.
l!i
T
T
t
t
rl:.r :
t:':"
i:'\j
?1=
T
l,
T.
Div,isions
,
Stat ions
D'rEliarge..
l----.--ffim
---fiita[e
Ch I oroplryt
a
x
l}acillariophyta
x
Cyanophy.ta
.
,X
_
572
T
t
659 000
000
000
517 000
869 0c0
1
,4
27,,000
tB0
2; 22.9,
Q00
6B?,
o0o
!-reqg,ooo
I
75,000
258,.000
66 7,000
I
",,t:
Diversities
Periphyton
diversities
computecl accordirtg:to
tlre
eqtiatiorts of
Sndnnon
(194S)
were significantly
different between sampling locaLions; tlre
diversiLy
cf,
Iirc
periphytic
algae
on
glass
slides
at the
lntake
drea
''rat
siqnif
icanLly
gr',rater'
than the
diversities,'at the,Dam'and at
th'e
0ischarge
area
(Table,5.l2).
..
:
,.
:'
1.
,.:
,
;;'
,.a.
:
-
l'
i-.
F.,''
'ili-
:,.
r=
1
,,-i
i=
5,24
::;..:
j=
l'
''
i',.
..-'
f''
;,.i;-,,,
.,,i,
0am
I
I
I
Iabte
5.
ll
Mean
dlversltles
(3)
for
periphyton
collect,r:rl
f
rom
glass
,,1irj',..,
after
quarterly
28iay
exposuile-periorJs
at
four
stations
in
Cof f
een
Lake
f
rom
August
l
giB
through
February
l9{tl
.
i'leans
underscored
with
the
same line
are
not
significantly
rlifferent.
Stat
ions
Di
scharge
3. ?0
3, 0l
2.61
2.42
The
gradual
density increases
noted for
major
divisions
of
algae
ds
one
progressed
around
the
cooling loop torard
the
intake
were not apparent
for
diversity
values. The rnean
diversities
increased
from
the
discharge area
(2.42)
to the
dam
area
(2.0f1
to
Station I
(3,01)
t.o
the
Intake area
(3.20).
lr
is
likely
that
the factors
responsihle for
the
rer!ucer!
grcwth
at
the
Discharge
area
aiso
were responsible
fur" the
reduced
dlversity
of aloae.rt that location.
In strnunary, th€re ilere
several differences in
periphyton
conposition
and
abundance
be'tweett
stations
in
Coffeen
Lake
that
may
havc beerr relaterJ
to
pov,er
plant
operation.
Feriphyton
accurnulations.on
glass
sl
ider
rere
significantly
lower
in the discharge
area than
in
the
intake area. Since
waste heat
and
current were
ruled.,out
as the
sole
causes of
the lorer
periphyton
growth
rates,
growth
inhibiting o;i limiting factors
present
in
the discharge
area
seem likely
ils a
cause'for
thE observed
lorrer
growtlt.
DiversiLy
of
periphyton
was
also
significantly lower in
the
discharge area
than in
tlre
inlake,ared
presumably
due
tothesame..factor.svlhichcausedthe.Iowerperiphyticalgalgrowthinthe
discharle area.
r
j:1:
Alerican'Publ
i=c=ffii
ntrof
i*ui1rn,
Arnerican !.laler
,,lo/ls',rssoiieticn,
arril ,irtrrr
Pollution
contici
fec-eratibn.'
rgio,
-
irunii,.,r
meulooi"i.,,:
'ir,o
,ir;;;^;;io;
of
water
and_wag[:l;t.ri--ii
l4th
erl,
A.rcrican
pub]ic
tlealLir
Association,
t{ashingion,
D,C.'
)lg3
pp.
Barr,
Al
.J,.,
J:-I.-Foglitlt,
J,
'P;
fiall, anrt
J.
i.
riclwirt.
1926.
A
usrlr,s
guide
i,o
SAS
76,
5AS
Institute,
lnc,, Raleigh,
NC.
.iZg
pp,
Brigham,
A, 1977.
t{ater
qual
ity investigations
af"'udre
.,.\sn_q[hris, section I.
In'R. l{.
Larirnore and
J.
A,
Tranqlilf!
ieds.)Annual
re$p_rt
fdr ijsra:l
year
Tg76,LakeSangchrispro.iect.I]linois.|latuialHisto'y,it,il'u*i
(unpublishe<t).
Clementr-K.,
J.
lasprowicz,
and
S.
0.
Sw.rdener.
1979.
Anrrual
sunrnary
of
water
'
'
Qudlity
r€port
Hi story
to
and
Survey
u.S.
biological
Army
(
unpub
corps
l
i
shed
investigations
of
)
.
[nqineers,
in
st.
Lake
Louis,
Slrelbyville
M0.
Il]irr,r.is.
basi,n.-
Natur,ll
D-linJal
,,,,
,
Coutant,
L.
!{.
1978.
Periphyton
of the Kank,lkee
ili,7q1,',';
'ln
R. W.
Larirnor:e'aricl'
,
M.
J. Sule
(eds.)
construction
an{.prg-Qper4t,ional
aquatic
monitoring''
program
lor
the
Kankakee River;,
f.jirrs[
.tnnual
report
hy il lrnois
NaIur-al
l__Evaluationof-acoolingl9kefislrery,"Vo1'Iv.|l.,.Nai.ilist.-iu'uey
'
r'rr':
.:.a
.,.::',:a'
Histor-v
.
1979a.
Survey
Algal
':
to
rlynarnics
f,onmonweaitir
of
Lake
tdjson
Sangchr'is
Contpany,
ancl
Ctticagol
Lake Shelbyville.
IL.
l;
final
report
to
Electric
power
Reseiictr
Institute,
palo
Al
to,
cA.
-
,
. 1979b.
Periphytorr
of
the
Kankakee
River.
In R. w.
larirnore
and t4.
l.rtu..(e9s.)
Construction
and
preoperat
ional
aqua'tic
monitorirrg
progrd.l
the
Kankakee
River.
seconci
annual report
by
illinojs
Natural'Hjst5ry
Survey to
Conrnonwea'lth
td
i
son Company',
Ch
icigo,
I
L:
'.
,
.
'
l9B0a"
Alga!
invesLigations
of Coffeen
Lake.
In
J.A., Tranqui
I
I i
and
-.._R.[.1.
'
Second
Lar:irnore
annual
,report:.from
(erJs.
)-Environmenbal
lll inois l{atural
Studies
ltistory
of CofTEerr
Survey
Uate,-SOition-5.
i6
CJniraf
,
ll
I
inois
,Publ
ic Service,Company
(unputrl
ished)
_.
lgtlOtr.
Periphytort
on artificial
substrates
in
the
Kankakee
River
and
Horse Creek. ln
R.
il.
Larinroro
'and
I',|.
J. Sulc'
(e
ds.
)
Corrstruct
ion ahrl
,'
preoperationall?'quat
jc
monitoring
progrdm
for clie
Karikakee
River.
Trrird
annual report by
Il I inois
lt|atural
Hi story
Survey to
Comnonrveal
th
tclison
,,
Corlrpany,,.Chi'cago,
IL
(unpub'lished).
Duf ford,
lJ.
H.
,
L.
ll.
Coutant, s.
0.
swarjenero
and
S
.
'rl.
lrJa
it,g,
lgll
.
irlater
quality
and
biological investigations
in the
Lake Snelbyville
basin.
Annual
report to
UjS.
Army Corps of
Engineers,
St.
Louis,
140.
lllirrois
t{aturai History Survey
(unpubl
ished).
L
lrtR^tiJRr-,
ct lt0
I
for
I
t
I
T
I
I
I
I
T
I
I
I
I
I
tt,
l-
l=
t'-
l'
l,=.
I:,..:
....:-'.
5.2b
il
F.
--Jiglosical
.---t',s,
f
.'
'r'laite,
-investisatlons
s:
.0. lwadene
in
r,
ine
and
iain
L.
!r.
ir'urIyrl
cor,.r.ln[,
ri-
r,iit,i,
igzB,
ilater
il;;;l
qua]iLy
'repori
arlrl
ro
!.s.
ArTy
colf]1
9f [ngineers,
St.
Louis,
r'10.
lilinois
r{arural
nisri,,"y
5itrvcy (unprrbl
i
she
tt
)
Gurtz, l.l:
l":..:
lld
g.14. f{eiss,
1g74.
tffrcr
r;f
Lherrnal
sLress
on
phyt0plankLon
prot|uctivityincondenserc0olingwa|r.'r.inJ.l,l'6ibborlsan<t''l.it.:
,
,)haritz,
'Augusta,.
GA.
erls. Therrnal
Ecology.
€RDA synpoTTun
series
(c0HF-230505),.
:
llustedt,
F,
t930.
tlaci
I
lariophyta
(0i
atomaceac).
In
pascher
(ed.
).
Die
Susswasser
Flora
Mitteleuropas,
tleft 10.
G,tstaT-Fischer,
jenol
qt,O-pp.
l'1i1ler,
M.
c:,
G.
H.
ttater,
I.
H.
Federic,
arrd
J.
p.
Reed,
1926.
tf
fect,s
of
qowgr
plalt
operalion
of
the biota
of
,a
therrnal
disclrarge
canal.
t1
G.
ti.
'
Esch
and R.
l{.
l''lcFarlane,
erls. lherrnal
Ecology
I
I.
fn6n Synposiufr
series
(C0NF
-75A425),
Augusta,
GA.
Horan,
R.
(in press),
.
qnytoplankton
dynarnics
in
a
cooling-na[er- reservoir.
In
R.
hist9119f.an
pp.
l,l.
320-341.
Larimore-i!9
Iilinois
J: A..Tranqui
coolinq
iake.
il i
eds.
il1,
Lake
NaL.
sangctriis
Hi;r.:
surv.
sttrdy:
siil,-iZiql.
case
-
l'lorgan,
1:
P.,
ll,
and
R.
G.
st.ross.
rg6g.
0estruction
of
phyloplanktorr
in
the
'
!90_l
't65-l7l
ing
water
suptly
of a steam-electric
station.
Crrcsipealb
Sci.
l0(j,4i;
Patrick,
Acad.
.11.,
Nat.
and
Sci.,
C. Reirner.
Philadelphia.
I966.
Tlre
213
d
pp
jaLorns
of the
tlrriLerl
States,
vol.
I.
_,
and
-Acatl.
I[aT]-Sci.,
Philadelphia.
213
pp
Prescott,
G. 1962,
Algae
of t,he
western
6reaL
Lakes area,2nd
etl. l.l.
c.
Brown,
Dubuque,
917
pp.
Shannon,
C.E.
.|948.
A mathematical
theory
of
conrnunication.
Bel t
System
Tech
.
Jour .
27:379-423,
623-656.
S.83
smith,
G.M. 1950.
The fresh-water
algae
of
the
unitecr
States,
2ncl
ed.
I'1.
C .
Brown,
Dubuque
,
97
7
pp
,
of
I'l,linois,
2nd
ed. l.lc0raw-Hi
Report
on
Coffeen
Lake
U.S.
Environmental
Protection
Environ.
Res.
l-ab.,
Corval lis.
Report
on
Sanqchris
Lake
U.S.
Environmental
ProtecIion
tnvjron.
Res.
Lab.,
T
i ffany,
L.
and M.
Ur.
i tton.
l
97l .
The
a
I
gae
Book
Co.,
New York. 719
pp.
U.S.
Environmental
Protection
Agency. l9i5a.
I'bntgornery
County Illinois
EPA Region
V.
Agency
tlorking
Paper
No.
300. Corval
I is
]'3
PP'
':
U.S.
Environmental
Protection
Agency.
l97Sb.
Christian
County Illino:is
EPA
Region V.
,igency
t{or(ing
iaper
No.
314.
',C6rvallis
ll
r::
aa:,::
U.S. Environmental
Protection
Agency.
1975c.
Report
on
Shelb.yvi
I
le
1
"
leservoir'tbultrie
and
Sneiby
Counties
lllinbls €pA
Reqion
V,
U,S.
r
,
,.
.
I
I
:F.nvironment1lPrg!qction-Aqencytiorkinr1Paper|{o.3l5,.Corvallistnviron..
Res,
Lab.,
Corvallis. l7
pp.
V.an.dert{erff'A.l953..A.newnrethodofconcentratingandcleaning
.
i
diatoms
attd
otherr'organisms.l
Verh. lnt. Ver.
l-imno1, 12:276.
'
i..
larriner,
J.
1,.,.and
11.
L. Brehmer.
1966.
Ihe
effects of
thermal'eff luents
on,
....llldFineor.9anisms.Int.J.Air.l'IaterPollut,10:277-2B9,
l{etzel,
R.G. 1975.
Limnology. t{.8. Saunders
Co,,
Philadelphia.
743
pp.
t{illiams,
L;
G.
'1964.
Possible
relationships between
plankton-diatom
species
.
I
I
I
I
I
I
I
t
I
1,.
I'
::
::
l=
I.
l.
I.
.
l'
I'
l-
=
li
l.
!.
:=:
5.28
:::
:;.-
sEcTt0r{
6
Z0OPLA|{KTON
0F C0l'ttliH L/iKt
hy
St
ephen
l{.
l{a
i
t
e
..
ABSTRACT
An,
'investigftion
of
zooplankton
rJynamics'at
Cof
feen
Lake rvas
conductecJ
f
rom
'
July 1978,to
l{ovember 1980
as
part:of
an
jnterdiscipl
inary
effort
to document
ch.angesihwater..qualityinthecooling.lakeandreceivingstream'General
information
was obtaineO
regardinq
dynarniCs
of
zooplankton cormunities
anrJ
indi-'
vidual
species and
of trends in
standing'crop
biomass.
The
overall structure
qf
zooplankton
conmunities
in Coffeen
Lake closely
resernbleJ-those
reported
for
both
Lake_ Sangchris,--a.cooling
-lake,
and'Lake
She'lbyvi lle.
That.the
number
or
richness
of
species
was lower within the cooling
loop
compared
to cooler
waters
at'stations
3
and
4
may
be
the
eonsequence
of
power plant
perturbations,
including
heat,
entrainment
and increased water
velocities. However, morpho-
logical
characteristics of the lake
basin
at
Station
4
(e.9,
the'railroad cause-
wayi
-.
:
p"oUubly
promgted lit!ora'l
cormunities
that contained-taxa not
found
elsewhere
in the lake.
'There
was
little
evidencg
that the
thermal
gradient.
.).,
ristricts,
'
.
..-
or
'-
-
enhan-ceq
_
tfre- distribg!!on of taxa
to
any certain region of the
''i:'.
l
Iake-
.:.::r-
Lake
morphology
_'-1.---.-:
and
.
--.
year
variations
probably
were
the
princjpal
factors
governing
spatial
distribution
of
species. Stations with high water tempera-
..:..
--
'tu.",
during the warmeif
months
sustained unexpectedly high
diversities
of
species,
but
probably
a
majority of
those forms resided below the thermal
plume.
,Rotifers
were less
tolerant
of high
temperatures:
near
the discharge
than
were
'
cladocerans and
copepods.
The organic
fraction
of
plankton
mass,
increased
with,
distance
from the
discharge
and
reflected
the
settling characterstics
of
fly
ash-slag
particul.ates.
The zooplankton, of
Coffeen Lake
were
found,to,
be
produc--:
tive and
viable
despite
atypical
temperature
regimes,
entrainment
mortality,
and
,unusual
::.:,,
''":"
water chemistry.,:
,
.-
'Short-term
projects
investigated
possible
r,easons for',
the
paucity
and
infrequent
occurrence
of
lgplglgg
kindtU
and
Bosmila
in
,Coffeen
L:ake
and,'assessed
the usefulness
of two.:methods for determinin.q zoo-
'
.:
pJankton.entrainment.....]:.
,.
,'-.'.',
,,
.:,
.
r
:-l : :
.',
,-
'
.i
j
6.1
',
,i
'
'
,,
Itl
IR0DUCT
l0ll
r,
.
"
-----'--"
Animal constituents::of
the I
imnoplankton
that
inhabit alectrical
power
planf
coo!,ing
lakes
are
subject
to
a wide
variety
of'unnaLurai
conditions.
.,Ireiquent
concerns
of environrnental
studies
of
these systems:have
cenl.ererJ
on:
(I) prob-
lems'
res'0ltinq frorn'additions of
chlorine
ancl
other
biocides
to
prevenL
fotrl
ing;
(2)
'effects
of inter:nal-meehanical'forces
within
the
plant,
such as
turbulence'
pressure
and'.vacuum;
and,
(3)
excess
heat containt'd
in
discharge
cooling
waters.
These and
other
concerns,
including:aslr.ponO
etftuents,
collllttu
runoff,.
and
brine wastes,
have led
to
a
recent environmental
studl'at
Coffeen-Lake.
This
,study
wa's ch'arged
with
documenting'a
change
in'water
quality
conconvnitant
with
improvemgnts
in
water
treatment
procedures:;
The overall
purpose
of
the
Coffeen
Lake.study
tvas
to
determine whether
Coffeen
Lake
supports
'aquat'ic'life
c0nsis-
tent
with
contemporary
lake managemtint
practi'ces
and
to
assess
the degree
of
'
recovery.resultingfromtheconrr'rencementofnewwaste-watertreatmenLfaci|i...
ties.
.
,
1
.
:,.
'The
scope of
the
first-year
zooplankton
work
was
oriented
toward
dssessinq
the
r
-
I i
-L.
^a
aL^
:-
status
ot
zooprankton
communities
in
ljght,of
the
improvement.in
the lakers
:
::water
qual
ity.
Specifical
ly, information
was obtained
regarding
numbers''
com-
position
and
distribution
of species;
species
diversi+,y;
absolute
and
relat ive
abundance
of
rna'jor
groups;
and
standing
crop
bjomass.'Although
these
calegor.ies
were
continued
through
Year
2 for
comparative
purposes,
additional
efforts
were
directed
toward
several
more
specific
ecological
and
methodoloqical
questions
which
were
developed
as
subprojects
for
this
report.
METHODS
AI{D
MATERIALS
From
July
1978'through
June
1980,
Coffeen
Lake zooplankton
communities
were
sam!teO
monthly
from
six
permanent locitions
(fjg.
l.2),
four of
which
were
intermutualjwithother..project...subgroups,i.e.,fi.sh,benthos,algae.T,9
sampl
inq
stations
were,,establ
iihed
within
close
proxirnity,of
the
plant;
one
was
--".f
.'..J
----
locited'adjacent
to.the
intake'screens'and
the
other
inmediately
downstrean
of
the
discharge'canal.
0ccasionally,
samples
were
procured
from a
6-m stratum
at
:.:
,.
,
'-
I
,
::
'
,the,intake
itation
(Station
X).
',::'
!
.:
I
.
i:
I
I
I
-
l
I
I
I
I
I
I
::
-.:::
f.
I'
i::,r
:::::r:
,
:
:.:1:.-::
:-
:.
a.
:::
',:..::::-i
,:'
.:
/:',:a::,.
.:.
';:.;!,':
:..,'
t:it,
:!1::'.
.;'
..'
i::'
',
:i+..:.. .:
t"
;:,.:.
"'
:.
i;fi..
,.
-
l;
:::
l-
a.
.
,,,,
-
-,,
ll.,
,,
li
t,
j-r-'
-'
.,
,,
li,
6.2
;'
:
i:l:.r:-:::
a:..
All
monthly
zooplankton
collect{ons
in
Coffeen
Lake
consisted
of
tr-iplicate
samples
of the
water
column
from
lake
bottrim
to
surface at
each sraLion.
Samples
h,ere
co
I lected r+ith
a
submers
ible.
f i
lter-pump
apparatus
{lf,r:i
te, and
0'Grady
l9B0)
that
filtered
BB
llters
of loke
water
per'minute,
lt
was lowered
and
raised
such that
all
water
strata were
sampled
equally. Ihe
total volume
filtered per
sample
was
a
function
of
time
allottecl
for
pumping;
in
Coffeen
Lake,
a
pumping
duration
of
2
minutes
was
adequate
and
thus
the
total volume
filtered
at
each
sampling
location
was dpproximately
0.5
m3.
An
ethanol-
formalin
solution
was used
in
the field
to
kill
and
preserve
the
organisms
irmediately
af
ter
col lection.
Analytical procedures
began
by diluting
the
concentrated
field
samples
to 100-
200
ml, depending
on
organism density
and
amounts
of debris
and
slag
particles.
Following
sample
homogenation,
three
1-ml
subsamples
were
withdrawn
and
placecl
in
gridded
Sedgewick-Rafter
cel ls for icJentification
and
counts.
Identifi66l 16n
keys and
other
published
literature
usecl irr
these
analyses
inclurled: Ahlstrom
(1940,
1943),
Brooks
(1957,
le59;,
{lhengalath
(
lgTt),
tdmondson
(1959).
Goutden
!t9qBl,
Grothe
and Grothe
(lglt'),
pennak
(1978),
smirnov
(1924),
t.,tilson
(1959),
l{i lson
and
Yeatfian
(lgFg),
a4d
Yeat{n.l
(1959).
:
Filtering,
drying,
and
ashing
procedures
describecl
by ApHA
et al.
(1976)
were
used
to
compute standing
stocks
of zoop)ankton
biomass.
The
residues
were
reported
in
milligrams
(mq)
dry
and ash-free
weight
per
cubic
meter
(m3)
or
lake
water.
lile.thods
palticular
to
the
ancillary
studies
wi
ll be brief
ly descrioed
within
those'sub:sections
of this report.
'
.:
RE.qULTS AND
DI
SCUSS
I ON
COIiIPOSITIOf{,
DISTRIBUTION
Ai{D DIVERSITY
OF
SPECIES
SpeciCs Cdmposition
.'.
:
'
,
The
monthly
structure
of
zooplankton'cormunities
in Coffeen
year
study closely resembled
those of both
Lake Sangchris,
a
t
,::..-,:;
-=,1
;,,,
;:a-.
:
,"
,
,,',
'
'
..
.
6.3
"
,
'-
Lake during
this:2-
cooling lake,
and
Lake Shelbyvi
lle,:
.
f
lood
controlr,reservoir
(both
lokes are
with
jn
B0
krn of
'
'
',
coffeeniLake),
in 1976
(uaite
1979a)
(Iable
6.
I
).
The
prerlominant
tara
in
:
Coffe€n
Lake included
32 rotifer5,
25
clarJocerans, and
ll
copepods.
Althrluqtr
the'.totals
varied
s'lightly from.Year:
I to
Year
2,. they
|rere
well within
thr
expected range
of
year-to-year
variatri
lity.
In
compdrison lo
year
l,
year
-Z,.had
fe*er
total
species
at each
station for
all but
fiye
rnonthly
coilections
(Table
6-Z)::,
Except
for September
of
Year
2, the
overall lake means for each npflth'
,
were.greater
in Year l. Furthermore,
there
was a significant difference
in
the
overall
lake
medns
of
the
two consecutive
l-yea.
periods (Student's
t-test,0.0l
levei).
Lakewide
comparisons
of
the
number
of zooplankton taxa in
Coffeen:Lake
showed
that
in virtually
all
collecting
periods
in
Year 1,
the numbers
present
at
all
stations
in the
cooling
Ioop
(discharee,
Stations I
and
2,
and intake)
were
lemarkably
simi'lar'(Table 6.2).
,
tlhile
there weie
fer.r trends
,showing'gradual
increases
or
declines
in species
numbers
in
the direction
of
coolinq water flow,
the mean
numbers
of species at the
cooting
loop
stations, coliectively,
were
number of
species at Stations
3
and
4
for
any
particular
month. During
Year
2 the fewest
number of
taxa
for all
stations
occurred in November
and, with few
exceptions, the
qreatest
number
of
taxa each
month
was at
Station
4"
*h.ich was
similar to
the
pattern
reportecl
for Year
1,
",.'
Contrary
to observations in
Year
l,
however,
the
species'numbers
were highly
variable throughout the
cooling )oop
in
Year
2. The
lower
overall number
of
species
in
the cooling loop
(discharge,
Stations
I and 2,
and intake)
cornpared
toithose
drt
Stat'io:ns:
3,,and,,f,
qlay.:
be,the
colseqgence of
of heat,
entrainment-
'",
related mortal
ity, and
water
ueficity;'ai.i
o1', which are
synergistic
conditions
associated
primarily
with the former. 0n
the other hand, the relatively
shallow
lt,''
I::
I.
...:
l.,i:,r-:1
I'.:,.:
l.-"
-::.
I,:.
I,::,'
r..: l
-:
I
I
I
I
t
I
I
I
I
I
l'
lrt
I.:,:
l,t'.
'
'tt'
l,::
r.r:.
Ii'
I.'..
I!.1:
I::.:::
F
l'=
t:.,=
t,,,'
waters
north of the
railroad
causeHay
(Station
4,and
v'icinjty)
appeared to
l
,
cooling
loop.
These
observations were not
unexi;ected due to,the
unusual
r
morphology of
the
lake
basin.
0f:,the
,.'.:'
rotiferan
.l
taxa
r .,
reported
for.
:
Yeans
:
I and 2, more than 501
belonged
to,.the
lor:jcate
family
Brachionidae. Dominant constituents from
other
families
in-,
,,
cluded
the
genera
Synchaeta,
poytiitttria,
and
Asplalchna.
An
unusually
large
.
'
6.4
Table'6.1.
Surmary
of numbers of zooplanktor
taxa
collected
in Coffeen
Lake
tn
lJai te
(1979a)
.
Coffeen
Lake
ffiFer/Tlle
-
YearT-
rfen#fZ
Lake
Sanqchri
s
t-ake
Shelbyvi
lle
Taxa
Rot
i fera
C I
adocera
Copepoda
Total''
.
30
2A
t2
62
27
29
9
65
28
2A
9
57
27
22
11
60
6.5
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/.:.:'.
:t:::.
fraction'ol''the'Year
2, rotifer
fauna
con-sisted
af unkno'ln
typcs,
primari
l.y
unidentlf|ablemalesaJr$irrmature]ifelris.iory.sLaqes
The:cladoe'eran.'fauna,of
Lat,e
Coffeen
in Year
2
ras
rspresentr:d
by
2Q species
and
a,:':
sii f
ami
lies,
tlowevei,
,.,,-
t' of
fhese taxa,
particuloriy
tlre
chydorids,.
occurred
inf
requenily.
i:
Oapt!nia
parJu13,
0iaphannsomq
l'gus!tdnberg
ianum,
!gt&@g[U.a
quadrangul
a, and
Chydorus
f.g!fail-[u!
rtere
the domi nant f
orms
in
both study
yeais.
The
payc!ty
of Lep*ttjdgfa rlurirtg.-Years
I and Z of this
stucJy,
aiso no-.:'d
in
the
Lake
Sanqchris study,
suggested
that
certain condjtions
(biological
.
and/or
physicochernicel
)
associated
with
cool
ing
lakes
may
have
prevented
the,
o.au..erce
of this otherwise conmon
taxon.
::
The dominant copepods
of Coffeen
Lake in both
Years
I and 2 included
the ca'la-
noid,
LiaptomuS
sLciloides,
and
to
a
lesier eitent
two cyciopoids, l4esocy_clopJ
edii
and.
Cycl-epjs vernil
is.
!-.
!.j-c"s.gj-{gtg-
ttrbmqs-i
,
a coldwater species',
is'ra
typical
*inter:
form
in
several
Il
l'inois
,'reservoirs
(includinq
Lake Sangchris)',
:
'.
.
.,:.,
:-
r'
'i,
:
but:was rarely
collected
in
Coffeen'Lake-
Parasitic
cyclopoicls
on fistr,
such
as
f
riasi,!qs, have
not
been
col lected in
their
f r:ee-l
ivirig
planktonic
forrn. The'
,.
ttrirO
grder
of
copepods,
Harpacticoida,'typica-11y
inlrabit
the
substrate,
ancl
consequently
only
several
individuals
were
col
lect.erJ in fhe
plankton.
,
-,
..t'
:
,
t
itt
,
ti
Previous analyles
of':zooplankton
popul'Jtions
in
Lake'Sancr-chrjs
(19/5-1978)
revealed
an annual
"damping"
of
the number of
species
present
in
the
cooling'
loop
(l,lq1te
I979a).
In
general,
the
numbers
of species in
temperate
lakes
exhibit cycl
ic
pulsei,
unless
natural
,u...rr'ion
and
periociicity
u"u *OAified': by
synergistic
effects'
of variou.,
biological and
phys
icochemjca'l
parameters.
The
'annual
::
f lue tuations
of
spec'ies
numbers
'in
the cooling loop at
Cofl"een
Lake
rnore
nearl.yresembledthe.typica]situation.wtrichwasexhibitedbypopulat,ionsin
unheated.LakeShelbyvilie::apulseinspringand/or.summe|.foI.lowedbya
gradual decrease
to a
late-winter
.:.
low.
In light
of
the
L,ake
Sangchris data,
this was:lan
unlikely.result
becauie
the
therma'l load
(in
megawatts
per
acre)
at
Coffeen'L.ake
was
much
greater
than
that':of
Lake Sangchris. If
the
damping
':
effect
on
zooplankton
species
is
indeed
a function of waste
heat loarls
as
:'imp,lied.for
Sangchris'{ata,.
then.O sitnilar
damping should have
been obierved
for
't
'
,..
.
.: :
'
:
.
zooplankton
populatiotrs
in
Coffeen
Lake:
Unless
the'latter:, is
a,
very:,unusual:
6.7
,ll
'
'i.'
:t
:,
'
'l
,
iistem,
lt
.is
postulated
'that
other:ccnditlons,
in
adrl'ition
to
or combined'wjth
,heot
l'oadst,are'important:,
in
regulat'ing'zoopiankton
blology
in
cool
ing
lakes"
Iimp0fil-Di
str
i
but
i
on
o-f
,Spec
ies
R;tiiaiu.
',One
rotifer,
Polyarthra
vulgaris,
occurred
in
near'ly
al I col lections'
duri'ng'both
study
years.
,'This,
species
anO Sy-qshag!i stylata
were
the
dominant
anquql,
forns.in Year,,2. Althouqh
the
brachignlds
were well
represented,
the
occurrence
of
individual
species
nas clearly.season-r'elated.
In
both
year's'
,9I..[LqLr-l'anguialii'inhabited:a]l
.lake
areas'from May
t.hrough
0ctober while
l-
cauddtus and
B.
patulus
occurred
for
a
s\orte'ned
duration
in
late summer.
.r*i*p'*r.'*''."r*coolerwater,B.urc-e.blqriswasco|monfromFebrua1y
through April
in.
both
years
whi'le
r+iphane:
sp. wa3
col lected
at
,all
stations
.i.
primar.i]y
:in
January
of Year
2,
Jui3r,
Septe,nber,
'February,
and
l'1ay samples
cOn.
rodied
Asplanchna
in Year" 2,
but in
Year
I this species
occurred
iontinual.Jy
frorn l,larch fr-oor.
'
,'
'i.
.9.].adoc.9ra-.Atypicalconstiruentofthe.surn.ilerfaunaofmostlakesinthis
region,
0iaphanosoqg
leuchtenbergianum
occurrert
frorn
May through
Decernher at
most
sampling
stations
in
Coffeen
Lake
during
both
study
years.
That taxon,
in
'iOCit'ion
to Daphnia garvula,
Ceriodaphnia
Su4fglltrt3,
and
Chydorus
:ql'raqr,ic.us
..:
:
:
.*erethefourmostpersistent.cladoceransinthe.|akeduringthestudy.
'.8r
.!!gitg*I-l
was
limited
in
both
yearls
to the
mid- to late-spring
.
period
(see
anci
I
I
ary study
on
Bor,Jnina)r.
Three
taxa, Ljj-aphanosonla
brachyurum,
'
Leydigi
a
quadrangul
ar
i
1,
and
CamptocSrcu:.
Iggl!'qstri
s.'
were observed
only
in
;i.il
'-tt,...t,.l'i:
Copepoda.,
gther
than
naupl
ii
anct
Copepodids,.the'calanoid
copeporl Diaptomu,s
:jSil"id
.was,not
only
[he
most
comrnon
copepod
but
was
also
the
rnost
persistent
,i-ooptant<ter;
it
occurred
in every
sanp'le.
0f
ttre
cyc'lopoid
fauna, Cyc,lops
,
'!
..vetlnans
occurred
in at least
one
station
thr.oughout
the study
period.
Mesocy-
,
Jtops
edax
was
also
a
dorninant
cyclopoid
species.
All
remaining
taxa were spor"
iOi.,:'in
occurrence
and
the
harpacti.coids
were
prevalent
only
from mid-summer
to
...i.s.-11tt'-.
"
:
,,,,===,.:--'
,.
I
I
I
T
I
I
T
I
I
I
t
:l
I
::
t
I
...
t
I
6.B
.:
I
'1.
:,-:,,:ra
;l
rI
T
I
sp
a
!l-a_!_
g
Elr
t
!!lj_q.!__9!_lp$
i e
t
tspatlial.distributlon
was stud'ed
toi'dererrnrne
-i
f
any.taxa
'rierere0nsist*rr!
i=v
',,
limitecJ"to
or
€xclrtded
frorn
any
par"licllar
.ragion{s)
of
t}re
iake,
Rclal'ively,.
,few',taxa
were restricted
to
one station
or,even
ofie
qener(tl
rsqr'on.
ligg'
'
gllJ$alUns,
a liitoral
:a:
clarJoceranr
was
found
only
in
tne
0ecemher
coliection
,
,at
the
discharge
s-tation
in:Year
l; it
was
nrobobly
swcpt through the
plant
from
the intake
rherp it'was:presenl in
extraordinarily
higii
densities'on arti-
ficial
substrate
sarnpiers
in November
of
Ycar'l
{Buc}:ler
I979),
In'Year
?
it
|{as
collected
in
December
at
Station
4
antJ in
sonre cooling
loop
stations
in May
anct
June
1980.
The brachionid
roti:fers,
Colur.ella
sp. anrl
Brac.hion.us
variabjlis-
were
collected
only at Stations
I and 3,
respectivelJ,
rn
Year
l; neither
were
collected
in
Year
2. ln Year I
no
species were
founcJ
exclusively
at
Station
2
or
the
intake
canal,.
In,Year
2
two claclocerans,
f,loi.!1i
Ul_L!1l
anrl
LgX[lg1g
quadranqularis,
were
collected
only
at
Station
2, and two
rotifers,
!uclanis
and
'.Tricholria
were collected in
the
intake
regions exclu'sively;: Station
4,
ini.n
was
not a
direct
part
of the
coolinq lootr,
favorerl
the
exclusive
rlevelopment
of
several
I
ittoral
species,
including
three
copepod
species,
Leydigia
acanthocer-
cojdes,
Brachionus rubeE, and
0aph.nia
lclodleri-.
Species
occurrinq
only at
Stations
3
and
4
combined were Alona
g5!al,l,
Ng[!g]gq
sn. and
!_qmp!g.g€_rcg:
rectirostris,
Qaphn-ia
longj-r1eql-:_
was
thc only
t-axon I
imited
to
the
f irst
half
'of
the
cooljng loop
(discharge,
stations
1'and
2) during Year
1; it
did
not
occur
in
Year 2.
Taia collected
only
from
cooling
loop
stations
included
.9.19[r-ryrbidentatg.(stations.land2),l4ytilinasp.(discharge,Stat.ion.2)'
.'fr'lonostyla
-[ll-q
{
intake,
discharge,
Station 2),
A-lglg
costata
and
A.-
gutla_tq
(stati.ons1and2)..The.occurrenceofthecyclopoidCyc.lops'/9II3.ij!-.was
,restricted
to. the
intake
and
stations
3 and
4.
.
tl"*__l*ears'to.be little
conclusive
evidence
that the
thermal
gradient
consjs-'
',tently
restricts:or
enhances the
production
o'f spec'if
ic
taxa within
aiiy certain
<-:
-i^egion
_'
"
of
the lake.:'Rather,
it
is more
likely that lake morphological featur'es
h.'al.-'a
.
Cd6tip,
pelagic
versus
shallow, littoral
regions)
and natural
year-to-year
varia-
tions in
population
occurrence
are
the
principal
factors
governing
spatial
dis-
.
tribut,ion. of
species'.
'-:.
I:
',
l.'
t.,,lt
..,.
'
t:
:i
6.9