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at Cof{{jqn 
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Foorl llab i ts 
o 
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and 
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Areas 
of 
Qoffeorr 
Laka. Dennis 
L. 
Ner*rrarr.
Focrl 
llabits 
of 
Fir'st:, 
Year 
l.argemouth 
Bass 
f 
rrrn
lleaLed 
and,/\rrrbicnt'Areas 
of 
'Cif 
fecn 
l.ake, 
Dennis
L . Ncr,anan and 
Lance G. Per-ry,
DisLrillutional 
Ecology 
ancl 
RelaLive 
Alruntiorrce
of 
Icht,hyop'lankton. 
Dennis 
L. 
Nerrrnan
Abunrlance 
of Littoral 
Fish 
Larvae in 
Coffcen 
t.ake
as' Deterrni 
ncd 
t)y 
Li 
ght 
-Trapping. 
l-arrce 
G. nerry,
ImpingernenL 
anrl Entrainment. 
'[Jennis L, 
Newnan.,
Species 
Compositlon, 
AburrcJance, 
trntl 
r)istribuLion
of Cof f een 
Lake 
F 
j 
shes. 
Lallcc G. 
Per 
,.y 
and
John 
A. 
Tranquilli. 
" 
.
Standing Crop 
Estimates 
of 
Coffeen 
t.ake Fjshes.
Lance 
G, 
Perry 
and tiohn 
A. Tranquill 
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,
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.
Periphylon on 
Artiflcial 
Substr,rles in 
Sho.tl 
C,.eqk.
[-drrll.l.Coutant, 
,.   
]
fJenthic 
Invest'igations 
of Shoa 
I 
Cregk. 
Gary 
t..
Warren 
and 
Jarnes H. fJuckl 
er.. 
:
Effect of a Thermal 
Discharge 
0n 
Fishes 
of 
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Creek 
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Iltinois 
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leilrn 
rlf 
bioloqists 
and 
cltcntisLs 
in 
tlte ,lrr)fls 
of 
w,il-cr 
qrrllil.v, 
clri,rni,-,ll
consLiLuent.s, 
phytopl,tnkLorr, 
nr-,riohyl.,rrr, 
zrropldrlktorl 
, 
henl.rrur, 
;rrrl 
f 
i.;ir.
Resrtlts 
of lha fit";t. 
yrar 
jnvesliqaLions 
orl eoff{-', 
Lni(e arrd 
Shoal 
Cri:ek.r,:r.rj'
orescrlLed 
in a 
rep,)rt 
cnt 
iLled 
"EnvirorrrnerrL,ll 
St trdias 
of 
Cnf 
f 
er-.rr 
LdkC,, wltictr 
w,ls
submibl-ed by 
the Il lino 
js 
llaLur^al llistory 
Survey in 
(lclotrer- 
1979. 
A 
sccorrd
annrtal rellort 
encompassed daLa 
collecLed f rorn 
Cotfecn 
Lakc 
tlrrouglr 
Ju 
ly 
l9B0 
a,rrj
I 
rrdcs 
a Lltr'L)e 
-yLrdr
biological 
analysis of 
Coffeen 
Lake anrl resulls 
of a 
one-yedr 
invcsl.igation 
of
Shoal Cr.eek, 
its: 
receivinq strcarn, 
, 
Ouring the 
second 
yedr 
of 
sl-trdy, 
a I 
-yearr:
irnpingement and 
entrainment 
prc.ject 
and a 
l 
arval { ish rlisLr:illution 
sLucly 
were 
-
aclded 
bo the 
sarnpling 
progranr 
to 
assess 
the irnp6sL 
of 
t,lrc 
cool 
ing 
wdLer 
inLake
system 
on the Coffeen'Lake 
f 
ishery. 
Reglorbs 
on 
Llrese 
inves:tiqat.ions 
ar.e
inc-lurJecl herejn. Data appendices 
were 
inclutJecl 
wiLh 
t,he 
Lwo 
previols 
anrrual
reports,i 
0n1y 
data 
whjclt 
..:
were not 
previously 
subrnitLed 
is 
jncludad 
in 
t,lre 
,:'
Appendix 
associated with 
this 
final report.
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i..irr: 
i:-, 
l:rr-,:lr: 
i
utl li?ltL-Colorerl 
9{}il5 
rtCvq'l 
ripr:rl 
fr+,r 
l.}rii. 
jhrl 
li+q:n,:r-=Et:t.y:'.t{lrr 
riiil 
l
iCSOC 
i 
al iOn f 
OUnrJ tltgre 
f 
grrreCt 
ljridef 
fs;r:*ll, 
vt.lt!-nt 
iBrr 
,rnrl il..{rJr'i 
Crl 
rtr},li 
l_r'
leve! 
t.r slrongly 
5lcpinq lplnnds 
ii:ehr-*r:hachr:r 
ei 
,ri. 
lq6l). 
:  
.
{lof 
fr.:en 
Lak+: is 
d 
relativr:ly 
{leep 
irnporlc,trnenl in 
cq,nFaris{jil L* 
uther- 
!!lirroi.,
i^Lrsf!'voir's. 
The f,?4 
ilqiitd, 
lglBD)' 
I irferl 
sr:lee 
terl 
p.lrdrreL,:rs 
for, 
353 lliinli..
lakCS ,ind 
|'Clt0rtrl/l IltaL 
Cilffrtfrr 
lrarl 
,'| 
qr'rtdttr 
rnrarr 
dr:1rth 
(ti.i.'r 
) 
.inrl 
;1,11jr11,rr
ilr,'llt.it 
( 
l/,7 
,'r) 
[ir.rn 
95 
p,trcent 
nf 
Llrt-, lakes 
latlrlial.r]rj. 
'j 
rr,l 
l 
ikri 
.r'l 
sri 
rra,i ,r
relative!y lriqlr 
volrJrnc 
dfvelopillcnt 
raLio 
(0,g/) 
..lrl(l 
nr, 
rjr.Lcrlsivr: 
slrorel 
ir-rr.:
(7/.1 
knr).
The 
coal-fired Coffeen P0wer 
St,rLion 
cornple.t is 
located;rrljacrlnL 
Lrt,rrrr! 
rrbtrrjns,
'ntsL 
of 
iLs ftrel 
(lto. 
6 
ller,'n) 
frorrr 
ConsolidaLc<i 
Hillsboro 
Coal 
eo,npanys,
undergroun(l 
coal rnine. The first 
of 
Lwo 
units 
aL thc'Coffeen 
Power 
SLaLiorr
hegan 
operation 
in 
1965. 
UniL 
I 
has 
a 
gencrnLing 
capacity 
of 350 
t'let; 
wilr 
an
rlsSociat.erl 
circrtlating 
water 
purnp 
disclrarge 
0f 146,500 
qpr4, 
lJniL 
2, which 
heqarr
electric 
generalion 
in 
1972, 
provirles 
595 
l'le|.l 
and hds,t 
circulat.irrq 
wat.cr 
pullp
discharrle 
of 253,000 
gprn. 
These 
Lwo 
units,_!$e,l 
on,a 
70 
percent 
loacl 
factor,
have a maximum 
heat rejection 
o(4.36 
.-.-.-...
BTU hr-l alnd 
establ ish 
<tr't rrvcrdQe 
lZ"
C 
ri 
se in vlater 
temperature 
across-          
n50rs.
gno 
esLaDtlsh 
art rtvcrdQe 
lz-
,ors. 
The 
therrnal 
effluent 
leaves
I
I
I
I
I
I
I
T
T
I
I
l-
t
I
T
.r,he 
g-enetating 
f 
acility 
via a 
0.9-km-long 
discharge 
canal 
and'enters.Cof 
feerr
l-ake by 
flowing 
over 
a hot darn. 
The discharge 
t,lrcn 
tollols 
a 
clockrvise 
paLtern
:  
-: 
", 
:  
:
'.alon, 
a 
6.6-km cooling loop. 
151s,'-provides 
324 ha of 
c0oling 
area 
(73'per.cen1 
,'
l 
:      
' 
,: 
t,
,.of 
th9.,l.gkp surface) 
and 
produces 
a 
total 
'lake 
loacling 
raLe 
of 
0.86 
Mer.t
r"ro-1 
i
CTLI'E 
^
:,: 
,,,i 
t 
', 
' 
fr| 
'
:jr:   
:. 
.:.:: 
t. 
",',    
': 
,t,
l'
l'
-,,
l=
l,'.,-,,,
-':.'
!..,.,,:
..;.:,': 
,,';: 
,,.
:: 
':| 
j.
l''-
.... 
. 
:
I 
.:.
T
,l-'' 
'
,1,''"t-',"'
i,-
,l 
,";.
Tallle 
l,l,  Physical 
tharacteristics 
of 
Cr:f 
feen 
Lake
1,,'
l'-
Surface 
areal
llean 
dept 
h:
l,lax 
i 
mum 
depth 
;
ShoreI ine 
Iength:
Storaqe 
capaclty:
l,latershed 
dra i nage:
Bottom 
slope rndex
Shorel 
i ne developrnent 
i 
nrJex
0rainage 
area/lake 
capaciLy ratio
Annual 
loss in 
capaci 
ty:
Volume 
develormerrt 
index
446 ha
5.7 
m
l't 
,7 
n
71. I 
km
2,7? x 
107 
rn3
.4,q5 
x 
l03'ha
.3206 
:
10,6
,6
.05 
percent'
,97
l.:
I.:
I:
1,,
-.. 
i 
',
l'.,',r,',
I:"
:'
;
r
I.:
I
:i
r..-
1,..'',
;:'
l
^r.\)
[r'
\J
"::t:i.. 
.. 
.
.:: 
, 
aaa 
:.: 
,:.
::;:::.',
_t'
1.3
I
I
t
I
',1
I
I
T
I
I
I
t
I
I
ti::_: 
:
z:
=,
::! 
:
a::r'
:':,,
a:a 
.
a::i
i!:':
='':':
aa:'
::.'
-,'a
:::
\-.
-:::. 
':
.:..
:?::
l:.
aa
:::-.
i:'
='
,:.:
::
l::,,
:i:l
:-: 
:
:.
:
:r,'
6ross 
electrical'output 
of ilre 
Coff 
een 
6eneratiqq 
.rt 
ii.i{.tn i{n!; 
luite 
tdr.iaiilr:
(Fig. 
l,l) 
as 
is 
typical 
0f rnost 
c0dl-f irerj 
units. 
[\rr'i4r3 
thr] nrrrtht 
iyf 
;igrr'ri,
May, 
November 
and 
0ecclnber 
of 
l9/9 
and i980, 
oulprit- 
itis reiliic{.j(1 
hrc 
t,rsrl 
,ri
scheduled 
maintenance,tnd 
repair 
work 
at thc 
power- 
planl. 
Sirrc.c 
the 
enset cf
this 
studyr 
max{rnum 
stimrner 
and 
wirtter 
rt isclrarr;e 
Lemper-,tl.rrr'f:s, 
oij(t1,lre11 
at 
the
enrJof'nu.*'Xingzone';:ii'1:',..io?6'crrC5PeCLive]y,
Several 
Inodif 
ications 
of 
:ilastewaler' 
treatment 
f 
aciliLies 
aL the 
pow,..:t. 
sLaticn
were 
conlDleted 
after 
this 
environmental 
study 
began. 
lnclurJed 
were 
isolation 
of
aslt 
disposal 
prntts 
frorn 
the 
lake 
basin 
{completerJ 
in 
Auqusl 
lgTg), 
consLr.ucLion
of a 
settlirrg 
basin for 
coal 
pile 
run-off 
(conrpleLed 
in 
February 
l97g), 
ancl
construction 
of,an 
equalization 
tank 
for 
rnixing 
of 
brine 
anrt 
rlernineralizer 
wasLe
products 
(Fig..l.2). 
These facilities 
served 
to l) 
pievent 
ash 
pon<1 
effluents
fro'n 
entering 
the 
lake, 
2) 
prevenb 
coal 
pile 
frartictrlates 
f1616 
1-'1lg1.inq 
ilrtr
lake, 
and 
i) buffer 
brine 
and 
demineral:izer 
wastes 
(a 
soldtio,r 
of brinp
sttlfuric 
acirJ, 
and 
s0diun hyrtt'oxicla) 
from 
pll 
extremes 
prior 
Lo relrlt'tsr, 
inlr: 
tht
lake,
Fottr rnajor 
satnpl 
ing 
stations 
were 
estdbi 
ished t.o represent 
arc.1s 
(-)xposcrl 
to
various 
therrnal 
regimes 
and 
were 
sampled 
by 
all invesLigators. 
Stdtion 
I 
was
Iocatecl 
irr the 
thermal 
clischarge 
aril, 
Station 
2 was 
established 
near 
the
midpoint 
of 
the 
cooling 
loop,'station 
3 
was 
situatecl 
norlh 
of the 
intake 
hay 
as
a 
thermal 
transition 
area, 
and 
Station 
4 
(which 
was 
partially 
isolated 
frcrn 
lhe
rest 
of the 
Iake 
by a raiIroacl 
causeway) 
was 
regardcrl 
as 
ilre 
ambient 
area.
Approxirnate 
djstances from 
the 
thermal 
outfalI 
to 
stations 
i 
throuqh 
4,
respectiveiy, 
were 
0.8, 4.0, 
6.9, 
and 
8.4 
Km. 
In 
aclditiorr, 
ancillary 
staLjons
for 
certain 
aspects 
of the 
strtdy were 
located 
near the 
inLake 
ancl 
rtisclarge
structures, 
at two 
other 
interrnediate 
points 
witlrin 
tlre 
cooling 
loop, 
ancl 
at 
thc
north 
end 
of 
the 
lake 
where McDavid Rranch 
enters 
the lake 
llasin 
(Figure 
l.Z),       
I
I
I
I
a.a.
-1,
.|,.4
:-'
,,
-:.
t:.
I
1.
{J
^
tp 
v)
Uqr
c)d
F1
Qt.
r-t 
L:
fiq)
at 
0r 
")
c)
.i
qJ
ti
t
ol)
i 
,a.;:,.
I 
,r.1,.
I 
.l
I
I
I
. 
I
I
t,'
I
-
I
,.
!
I
I
I
I
I
I
I
I.
fum Infloxing 
Strearn                                     
t
t
I
I
I
t
I
I
I
I
I
I
I
I
I
I
I
I
I
Coffeen 
Loke
I    
too   
looo
M.t. r 
I
11"--..-.:
N
t
tt..
\
L, 
= 
Moior Sompling 
Srorion
Last 
Arm 
'
Inflowing 
Stre;un
Slag 
, 
Pnnrl
Yhormo 
I
Outflow3
3i,l;t""'
:r
loperation
2op;udi;,t
3operation
ceased Feb.,
Degan I.eD.,
..
ceased 
Aug.,
1979
r979. 
i
t979
Sanrpl 
ing 
s ta 
tions 
on Co f f een 
I,ake.
]:
::t. 
. 
::.4'.,         
.:  
,l
. 
llr
,1.. 
v
F:"gure 
1;2
''.t 
' 
'
[_J: 
Ancillory Sompling 
Srorion
--
::I
f:
,I
:-
:I
::   
. 
LITIRAIURTCIII.O
Central 
Coffeen 
Illinoia 
Power 
Public 
Station 
Service 
Urtits 
Company, 
r 
iriJ"i, 
197l. 
'iuoniifoo'to 
Thermal 
Denronstralon 
f0r
ure 
iiitnoii 
poiiurion
Control 
Board, Ma-v 
1927. 
.
Fehrenbach€f1.,1. 
?.r-!r 
0, 
l.latker, 
anrl ll, 
L, 
l.tascher. 
1967. sails 
of 
Illinois.
':'Unlversityof 
'47 
pp
Illinois 
Agricultural 
,[xper.i'neni 
Srution. 
grii.ti" 
ji;','-'
Il 
linois,Environmental 
Protection 
Agency, 
l97Ba. 
AssessrnenL 
and 
Cl assification
of 
Illinois 
Lakes, 
Vorume 
I. 
208 witer 
Quat 
iry 
raan.gur.nf-pi;;;i;s 
p;;;;:;,n
, 
,!tafr 
!gpirrt. 
state 
of 
Il linois, 
tnvironmentai 
proriirion 
ngency,
Spr 
i ngf 
iel 
d, 
I 
I 
I 
ino.is 
.
Il 
I 
inois 
of 
Il 
Environmental 
linois 
Lakes, 
Protectiorr 
v0lume 
l 
l. 
Agrncy, 
"zgg.Hater 
l97Bb. 
Qualiiy 
Assessment 
i,lanagement 
anrl 
planning
Cl assification
frogral.Staff 
Report. 
state 
or 
ir 
t inois,-E;;ii6nmentit 
prorection 
Agescy,
Springfield, 
Ill inois.
Il 
linois 
Natural 
History 
Suryey, 
1glg, 
[nvironrnental 
Studies 
of 
Coffeen 
Lake.
'First 
Iext; 
Annuat 
Vol. 
I 
I, 
Report 
Appendices
to 
centrat 
Illinois 
public 
Service 
ccn[int; 
1l;;.'';;"'
Lopinot, 
DepartnentofConservation,Springlietd,.IIljnois..}l9pp;
A.- 
c.. 
l?79., r,lontgornery 
county 
surface 
water 
resou.css'. 
Iilinois
Schweqman, 
'J.^E.. 
19i3. 
Comprehensive plan 
for 
the 
Il 
I inois 
l,lature 
preserv,ls
System, 
Part 
2. 
Tlte 
Natural 
Divisions 
of Illinois. 
lllino'is 
Natu;e 
.'-
Preser"ves 
Conmi 
ss ion. 
32 
pp
.l
;l
I
ll
,l
aa 
.'
I
I 
.. 
ti:.-
.: 
:.:.' 
:.
::-;.:,
:.'            
):" 
1: 
:
,. 
t 
. 
.t 
:
..: 
i.i. 
a
:: 
' 
. 
,':': 
'': 
' 
,:::
"'
.:l, 
:. 
::rr     
. 
,.-:
ii.'.. 
'
,..:t=   
.,:...- 
.-:
Ii ,.
l'': 
..'
:            
5Ecil0lf 
? 
,
: 
I 
TlttRi4AL 
--     
--  
I'tApptHG 
"         
0F 
C0rrttfi L&ri[
a
: 
: 
Sarah 
t.iehr-Storck
ABSTRAC 
I
.
''
Thermal 
mappino 
was 
conductert,q'larlerly 
at 
Cof 
feen 
Lrke 
dtlring 
the 
period 
f rom
september 
l9/B through 
Sepiemoer 1979, 
and 
semi-drflrrdlly during 
the two
fol 
lowing 
years. 
Little variation 
was 
found in 
surfdce ternperotures melsurerj
{lcross 
transects 
located at known 
rJistances 
from 
the discharge. 
The only 
rnajcr
exception 
occurred in 
l'larch 
l9B0 and 
February 
lg8l when the thernal 
plume 
stayed,
close 
to 
the 
east bank north 
of 
the 
darn f 
or a 
rlistance 
of 
l.0 
to L5 ki lomer-ers.
'\++:5'1-:1l#-+:-*+E4
The 
dischargc' 
arm 
of 
the 
'!rke 
usual 
ly had 
dif 
ferent 
vert 
ical 
ternperature
distributions. 
:4u1t.r
!.[rgn 
!he-1g$-*of-.-tne 
lake, 
with 
a distincI 
change occurring 
in 
Lhe
vicinity 
of t\q!U. 
.'r*-
lhe 
rJischarge 
arm 
of 
the 
iake'-ien,ieA 
ts 
itay 
tfiFrmilly-
stratifieC'at'a 
depth 
of 
about 
tro 
meters, 
with 
much 
warnrer 
water in the 
top
layer. 
In 
the 
vicinity 
of the 
,.''
clarn, 
greater 
rrixing 
and 
larqer 
water 
v0lume
c-qused a distinct decrease in 
surf ac6-watei 
ternperaturas. 
rrJater 
temperatures in
the 
---*
cooling loop diti not 
vary 
greatly 
between 
the 
dam 
an<J 
the 
intake 
canal 
cove.
A 
distinct decrease in 
temperature 
occurred 
at the railroad 
causeway! 
inJlcating-
that 
water temperatutes 
north 
of 
the 19!lroarl 
causeway 
were 
not 
6ffs61ed oy 
the
--' 
-'-----:.-------'--       
'--''..=.
thermal 
discharqe 
!o 
the 
sarlg_extent 
as 
_w_a-t*er ,t,empgratures 
souilr 
of the
l4q:91g.. 
Vertica'l 
temperattre 
distributions 
did not 
correspond 
to 
normal 
,.
stratification 
patterns. 
thermal 
discharges 
prerented 
winter 
stratification, 
and
ice formation 
except for the 
area north 
of the railroarl 
causeway. 
Both 
winter
temperatures and summer hypolimnetic.temperatures 
were 
hiqhcr 
than 
norrnal in 
the
iower 
region 
of 
the 
lake, 
possibly 
allowing 
greater,bacterial 
activity 
anrt 
thus 
'
greater 
rates 
of 
cyclinq 
of 
nutrients 
and other mlnerals. 
!n the sLtmftre!" 
neii) 
,
the dam, 
rather than 
the 
normal 
situatlon 
of 
two 
isotheimal layers 
of 
water 
ttt
separated 
by 
a 
therrnocline', 
ihere were three isotherrnal 
layers 
separated fry 
tw{ 
\
. 
.:...
thermocl 
:.:. 
ines.: 
j 
The 
to_p,.layerr.r:eq.g,]:ted,frq-nr 
, 
;.      
,..:,,t 
tt     
'- 
warr,ri'water 
fr:bm the'discharge 
arnr 
/
.: 
. 
t/
stayingonthesurfacer.ttherthaImjxing...
,: 
l,,t 
l,i
:! 
'. 
:      
Ctl
I
I
I
rli
!\';lrj
il{In00tJcr 
tOti
blater 
temperature 
is 
an 
irnportant 
p0rdmeter 
af f 
r:ctin,J 
l,rke., 
bcr.,rusrr 
i 
i
infltlences 
not 
only their 
phyrical 
characterisLics, 
but rt\0 
!.h4ir 
r.ricmical lnrl
biological 
choracteristics. 
Becarrse 
differenr. 
i:larit 
and 
lni{ral 
species 
have
dif ferent 
temperature 
tolerance 
I imits 
anrl 
Itrnperdture 
optima, tcmperdl(rrc 
citrl
af 
fect 
'the 
biota 
directly 
by l imiting 
tlre 
rJistribulion 
of species 
or 
by
dctermininq 
the 
species 
composition 
of 
cofimunities. 
Temperalure 
also affec.ts
tlte rete 
of 
biological 
activities, 
and lhus 
dlfects factor^s 
srtch 
as 
growth,
deconipositiort, 
oxygen 
consunption 
and 
evolution, anrl 
nutrient 
and other 
nrinrlral
cycl ing thaf 
delermine 
the 
biological 
clraracteristics 
of 
a lake. 
Also, 
becausq
of 
the relatianstrip 
betwer:n 
water 
ternperature 
arrd r!ensity, 
tenperature
distribution 
deterrniles. 
circulation 
poiiurnr, 
anrl thrrt 
o^yn*n 
levr,ls, in 
parts
of 
the 
lake 
whicn 
rneli 
restrict 
anirnal 
l,ife 
anrl alter bacteriol 
,ictivity,
:.; 
: 
.,:
-TItt;rcfo5e,'a 
tltorough 
understanding 
of 
teinpera',lure 
dist.r'ibut,iorr 
is 
essenlial lo
assessinq 
the impact. 
of tlterrnal 
ef 
f luents 
on 
the 
cherrrical 
a*d 
bioloqical
clraracteristics 
of 
a lake. 
' 
',' 
r1 
,,. 
",11 
,. 
',,.,, 
,. 
'
Cof 
f een 
Lake woulrl be 
cxpected to 
have 
tI 
i 
f 
ferent 
tempr.'rature 
patlr:rns 
iltan 
nost
lakes 
in this 
geographical 
area because 
ib 
is 
a 
cooling 
lake 
which 
cir.culates
I 
arge 
quant 
i t ies 
of water and receives 
a' heaLetl 
cffl uent. 
Temperalur.e
distribtrtions 
were 
alstl 
affectetl 
by 
climatological 
events 
anrt by 
t)ower 
plant
generation (Fiq. 
l.l).  
The 
purpose 
of 
this 
study 
is 
to 
provirJe 
backgrounrl
information 
cn 
annual ternperature 
patterns 
in 
Coffeen 
Lake so ihat the 
chemical
;:j,:H:l;:r' 
,". 
can'be 
interpreted in 
the 
conlexr 
of rheir 
rhermal
I
t
t
I
I
l
::: 
-
i:,
:,::j-:
I
I
t
I
I
I
T
I
I
T
?-,2
::)!:- 
'.:
.':-
-i.
I:rj
l,t'
,.3..
l,:..,
I.
l--t-
-a.-:,:
j,-..-
1,..
I,r:,
I,,,
: 
i-i:::,:-
..t 
;,r,1.:, 
..
:,1:
t,.:
I:  
I
,,:': 
I"
-- 
,
I 
I
lr,
'i 
t'''
'-r.,
r.,
r...
-1',
glr:-:-:
I::
r.lAr[R 
lA[S 
AND r4tTr10i]S
Ihq 
ther,mal 
plume 
wis 
$easured 
at: 
qilarterly 
intcrvals 
dur^ing 
the 
f 
irst 
.r,ear 
of
sampl'in13, 
and at 
semi -dnnual 
interval 
s 
durinq 
thc 
secr.lnrt 
,tnd 
thirrl 
years.
.Vertjibtit'proflles Here 
measrrred 
at 
l-meter 
depth 
intervals 
along 
transects at
known 
ttlstances 
from the thermal 
discharge, 
Tt'o 
to five 
vertical 
profiles 
were
measure..J: 
along 
eachr 
traniect, 
depending 
on 
the 
length of that transect. 
Three
boats 
Here 
used 
when 
possible 
to 
complete 
medsurements 
over 
the 
entire 
lake 
in
as little 
time 
as possible, 
Temperatures 
werc medsurer, 
with 
YSI 
r{odel 
57
d i 
sso I ved 
oxygen and YS 
I 
l'lode 
I 
33 
S-C-T 
meters 
.
i)rofiles 
of temperature and 
dissolved 
0xygen 
were 
measured twice 
per 
rnonth 
at
l<neter 
rlepth intervals from 
mid-lake locations 
at 
Stations 
i, 1.5, 2, 2.5,3
anrl 
4 
(F'ig, 
'1.2). 
These 
measurements 
were 
taken 
with 
a YSI 
tlodel 
57 
dissolved
oxygen meter.
.:
'.' 
,   
Therrnal mapping data 
col 
lected,during 
al I 
three 
years 
of
,...  
in Appendices to dnnual report.s 
(Liehr 
l9i9; 
Liehr-Storck
lgBl 
). 
Ternperature 
anrl dissolved 
oxygen 
profi 
le data 
are
, 
Appendices to these'reports
..I.  
TEMPERATURE DII-FERENCTSACROSS IRAf{STCTS
ln 
general, 
very 1 ittle variation in 
temperature 
occurred
linking one 
side of 
the 
lake 
with 
the 
other. 
There were
1,1.,.' 
I 
ake, however, 
where 
sorne dif ferences were observed.
tlris 
ttudy 
can be found
1980; 
Li ehr-Storck
also 
listed 
in
across t 
rarlsects
two 
locations 
irr the
In 
the'main 
arm 
of 
the 
lake, 
temperatures 
were substantially 
higher 
along-the
east bank on 
the 
dates of 4 
lllarch 
'1930 
and 
16 
February 
l9t]1 . 
The 
clif 
ference 
in
surface 
temperatures 
between the.east 
and west hanks 
just 
north 
of the,dam 
was
6.7,'C 
'oir; 
4 
tlarch 
lgB0land 
5.4?C on 
l6 
February: 
l9Bl 
. Temperatures 
remainert
,-.1
a,,:::,-.:..
:..::::.':t'r.:
2.3
dif 
ferent 
for,, 
a. 
distance 
of 
1.0 
to- 
1.5 
kilornetr:rs. 
i,linds 
were 
f 
airly 
stronq on
both 
of 
these 
sampling clays 
at 
alrout 
l0implr f 
rorn 
thr: 
touth anr, sou1rrwcst,
llowever, 
strong 
iinrJs f rom the 
'soutlr 
and 
soublrwest were 
also 
presenL 
orr:olher
days that 
thermal 
rnapping 
qreasurements 
were taken, 
and 
thesr, 
large 
lempcrature
rtlfferences 
were' 
n0t 
observerj.
A 
much 
less 
pt'onounced 
difference.,in 
temperaturc 
across a 
lakcwide 
Lransect
occurred 
just 
north of 
the rai 
lroad 
causeway. 
Tcmperatures 
were 
sl 
ightly 
higher
in 
the 
middle'of 
the 
transect'on 
z0 
November 
l978 
and l6 February 1981.
Slightly 
higher temperatures 
were 
observed 
on 
thc 
east sicle 
of the 
transect 
on
B Augttst 
l979,and 
22 
August 
1980, 
0peninqs 
(culverts) 
are locate<J in 
ilre middle
and on the 
east 
side 
of the 
railroacl 
causeway, 
and these temperature 
variaIions
may be the 
result 
of 
water movement 
through 
these 
culverts. 
Again, 
wind rtaLa
were inconclusive 
as 
a causative 
agent, 
since this 
phenomenon 
ylas 
not always
observetl 
under 
s imi I ar 
wi nd 
cond 
i 
t i 
ons 
. If w,iter 
exchange 
was 
occurr i,rg 
ilrrouqh
the 
culverts, 
hoi{ever, 
it 
was 
either 
at 
a 
very 
slow rate, 
0F rnixing 
was r-apid 
ly
occurring, 
as temperature 
clifferences 
were difficult 
to 
detect.
TEI.IPIiRATURE 
DIFFERENCES 
|.lITH DISTANCE 
FROM 
DISCI{ARGE
Since temperatures 
were 
fairly 
uniform 
across transects, 
mean 
ternperatures 
at 
0,
2,5, 
l0 
and l5 
meter 
depth 
intervals 
were 
calculaterl 
Lo 
observe 
seasonal
patterns 
of distributjon 
of waste 
heat 
with 
depth 
and 
rlislance 
from 
the
di scharge.: 
, 
femperature di 
stribution 
i 
n 
the 
summer 
season 
was notably 
di fferent
fromtherntaldistributionjnthewinterseason.i
Thermal 
mappings 
comp'letect 
on l2'september 
1978, 
B 
August 
1979, 
ancl 
22 
August
l9B0 indicated that temperature 
djstributions 
were 
simi lar 
during 
the 
hottest
times 
of 
the 
year (Fig. 
2.1). 
Thermal 
stratification 
(a 
barrier 
to rnixing 
as
defined 
on 
paqe 
2.8) occurred at,a deptlr 
of about 
two 
meters 
in the 
area 
of the
lake 
between the 
discharge 
and 
the.dam. 
Stratification 
at nine 
to ten 
meters
occurred 
at 
locations in the lake that 
were at least 
ten 
meters 
deep. The
temperature in 
the top 
two 
meters 
of 
the 
water 
column decreasecl gradually
thrbughout the lelgth 
of the discharge arm. 
A 
more 
drarnatic 
decrease 
in
2.4
T
I
I
I
I
t
I
I
I
I
I
I
:l
.l
'l
' 
::.:t;
t
l
25
eo
t!
o
F
(D
E
trl
o
I
L,l
F
c
ul
ul
G|
DlSTAllcE 
FRoM 
DIS0HARGE 
( 
xu 
)
SURFTC€
2 
r€rEFS
3 
ETERS
IO 
I'€TEFEI
It 
TETERS
Lake 
in 
relation 
to
:
I2 
September 1978,
,
ol
F
:Ct
F-
6
^  
(t
I-'      
f
I
o
lrJ
E
f,
F
c
(L
lrl
l!
>
F.
q,
o
O)
F
o
ct
)
3
N
o,
Figure
l 
,''''
Temperature 
di.strlbutlon 
in Coffeen
depth and dlstance from discharge on
8 
August 1979, and 22 August 1980.
2.5
ffi'''-
ffi.-''
kl: 
:
F''
H:,
Fir
lTli:
FJ
ffi:';.
si:.,
li:,
#t'
Fi,.
k;..
f;:
Fi.''.'
b:t::: 
:: :
::>t.-r 
:'
fi:::;:::: *
i.li: 
.,,
f:-i''.:'.:,
F:'::1: 
..:
[i:'ir' 
- 
'
ili 
i,.':.:
.''' 
,:
Ii:1, 
' 
..
'F1r;1;1',,.,'
tj):.:: . 
. 
.
"il:'i.,,1,
ff:.::l 
' :
-l.';:,,-'''
!':-::, 
:
:;:..:.,-'
;iir. 
' 
.1
i'li-
i;:r;:,;: 
,
i!,:'.",t.,,
fti,,,:- 
i1.:. 
. 
''",
.
f..'.'- 
'
';:.1;,;.,:'. 
,
l.lt,:.::," 
'
"?i.,,
lilo',:,:;;,'
+1.,-,
;j-,,':.:
J
rr" 
: 
')
i',tt,''-
:i:l:.: 
:.':' 
:'
;{j::::::i.  
' :
'i7'):tt:.-
6l:;r:l;..,.
!i 
l
7:;::'.:. 
'
ii'"
';:, 
!i:: 
t. 
'.'-
.l
It:: 
'
i, 
'-:
*-i*. 
''l
i::::: 
" 
:'
i:i;'.: ,
temperature 
occurred 
at the 
darn (except 
on 
Z? 
Augrlst 
l9B0 
when 
planL 
gener,rtion
was 
reduced) 
followed 
by 
only 
slight decreases 
in 
water 
ternperalure 
nlong 
llic
retnaining 
length 
of Ltte 
cool 
ing loop. 
Tenrperatrrres 
dccreasert 
nore rapidly 
in
the'area 
of the 
lake 
rreyoird 
the 
intake 
cove, 
arlrl then 
a rapid:dc,cline 
occurrcd
at,the 
rai 
lr:oarJ 
causeway. 
t.later, 
temperatures 
al f 
ive 
anrl 
Len 
rnelcr 
rjeoLhs 
did
not,change 
fiuch along 
the 
coolinq 
loop 
or heyond 
to the railrcart 
cduseway.
The 
winter 
therrnal 
'nappings 
also 
showed 
simi 
lar 
temperatur.e 
distriLru.r.ions
(Fig. 
?-.2). 
Data 
frorn 
B 
March 
I979 
were 
not included 
liecause 
the 
l)ower 
plant
was n0l 
operatinq 
on that date. 
Thermal 
stratificalion 
occrrrred 
at a 
Cepth 
of
one,to 
two'meters 
in the 
area 
of the 
Iake between 
the 
rJischarge 
antJ 
the 
:
spilluray, 
with temperatu,res 
in the 
top two 
meters 
aqain 
decreasing 
qr.ariual)y
with increasinq 
distance 
from 
the 
discharge point. 
A-." the 
spil 
lway, 
.lrowever, 
a
very 
rapid.'temperatttre 
drop 
occurred. 
During 
winter, 
the 
resl 
of 
the lake 
was
not stratif 
ied, 
and 
surf 
ace 
ternperatures 
decreased 
onl-y 
slighily 
within 
Lhe
remaincler 
of the 
cooling 
loop. 
0ther 
temperature 
difierences 
occurr.erj 
at 
the
intake 
cove 
and 
at the 
railroad 
causeway. 
!Jater 
ternperaturcs 
at five 
and ten
meter 
depths 
increased 
in the 
reqion 
of the lake 
between 
the 
spillway 
arrl the
intake 
cove 
as 
a 
result 
of 
more 
even 
winter 
verLical 
dist,ribuLion 
of heat
thruughout 
the 
water column 
in 
areas 
beyond 
the 
rJischarge 
arnr.
ldater 
t. 
ternperatures 
: 
that 
were 
2 to 
3"C 
cooler 
were 
found 
at the 
rajlroad 
-
causeway
at 
'6'11 
times 
that 
rneasurements 
were taken 
beyond 
that'st/uctur:e 
excepL 
22 August
l9B0 
when 
the 
decrease 
llas 
only 
about 
l"C. 
These 
data 
inclicai,ecl 
that 
the 
rnixing
of 
w.ater fr"orn tlre.north,and 
south sides'of 
the:causelay 
was 
considerably 
slowed,
anc 
that 
the 
portion 
of the 
lake 
on the 
north 
side 
of the 
causeway 
was
noliceably 
Iess 
impacted 
by 
thermal 
effluents from 
the 
power 
plant 
than 
was 
the
por:tion,.of..thelakeonthesouthside...:
THERMAL STRATIF 
ICATION 
.
Aphysical.qropertyofwateristhatits.densityincreaseswithc|ecr.easing
ternperatures 
(to 
a 
ternperature 
of 
4'C). 
Because 
of 
this 
property, 
Iakes 
Seconre
stra.tif 
!ed,,when 
so11e 
I 
ayers 
change temperature 
,more 
rapidly 
than 
other 
layers.
ln,rcmpeiate.regiq'ns, 
thi.s'phenomenon 
is 
a cornmon 
occurrence 
in most.lakes
'_l
...
I
t
I
,l
I
I
I
I
.l
I
I
.T
:
I
't,
:'
I
'1.
't
a:, 
,:
"1.
2,6
''.
o
@
ol
!'
(J
q-r3
r::,
ct0
AO
()
,o
€
\
\
SPILLWAY
:
DISTANOE 
FROM
suRt 
cE
----2 
fTETERS,
-'-i-r 
- 
'lO 
IIETERS
89
IIIYAKE 
RAILROAO
UJ
G
l
F
G
o-
ru6
=
Fg
c
l
e.
,@
tr.|
l!
@
30
23
t5
to
5
o
1,-r ;  
.. 
.f'lgure 
2.2.
DTscHAROE 
(xu)
Temperature:distrlbutlon 
:.':       
.    
.
in Coffeen 
Lake in 
relatton 
to
depth"and 
dLstance 
f rorn dlscharge 
on 
/r 
lrlarch''1980 
and
16 February 
1981.
:,';. . .
l,
.
ourln9 
!he 
surmer. 
ond 
winter, 
A ternperature 
drop 
of 1.C 
Der 
nieler 
rjr:pth 
is
generdl 
ly 
cortsidered 
to 
cause 
a 
rjensiLy 
qrarlienL 
suf 
f 
ic'ienl 
to 
act 
ds 
o 
bar.rier
to 
mixing, 
arrcl 
will 
herein 
be 
used 
as the 
rtef 
iniI 
ion 
of 
Lhe 
rrn36l 
qns. 
Sincc
Cof 
feen 
Lake 
is 
subjected 
to 
temperature 
jnf 
luences 
oilrer thr.)n 
c.l 
imorological
ones' i.e', 
it 
rcceives 
---i.   
--
a heated 
efflrrent, 
this 
lake 
would nof 
be 
expecle(t 
Lo
stratify 
in 
t'he 
same 
patterns 
as 
other 
lakes 
in 
tlre 
same 
geo!r-a0hical 
area Lhat
are 
subjected 
to 
only 
climatological 
influences. 
Stratificaiicrn 
patt.erns 
were
studied 
by 
means 
of 
temperature 
profiles 
measured 
twice 
per 
monLh. 
Dissolved
oxygen 
concentrations 
were also 
studied 
to 
help 
determine 
the 
stability 
of the
t.herrnal 
strat 
i 
f ications 
observed
Stratification 
in 
the 
winter 
norrnally,occurs 
when 
Lhe 
water 
cools lo 
below 
4"C.
i'Jater 
at 
4'C 
has the greatest 
density 
and therefore 
stays 
aL 
the 
bottom 
while
water 
above 
jt 
continues 
to 
cool 
until it 
freezes 
at 
0.C. 
tjn<Jer 
the 
ice,
biological processes 
continue, 
although 
at 
a reduced 
rate, 
and 
oxygen 
can 
llccorne
depleted 
since 
there 
is no 
exchange 
with the 
atmosphere. 
In 
Coffeen 
Lake, 
this
type 
of 
stratification 
rvas 
observed 
only 
at Station 
4, and 
no 
oxygen 
depletion
was 
observed 
during 
periods 
of ice 
cover. 
Consistent 
stralification 
was 
also
ob'served 
in 
winter 
at 
Station 
I 
at 
a 
aepth 
of 
one'tc 
three 
meters, 
where 
thermal
effluents 
frorn 
the 
povrer 
plant 
caused 
water at 
the 
surface 
Lo 
be 
considerably
warmer than 
water 
at 
the bottorn. 
In 
spite 
of this 
winter 
st,ratification
P,*a.!tern 
ilr 
the 
discharge 
arm, 
however, 
dissolved 
oxygen 
levels 
were 
fairly
unifortn throughout 
the 
water 
column. 
The 
water 
colurnn at 
the 
oLher 
statiorts 
was
qeiteral 
ly 
cornp'letely 
mixed 
wjth'.temperatu'res 
mosfly 
in the 
range 
of 
6 to 
14.C.
anrl 
oxygen 
levels 
in the 
range 
of B to l?. 
nq/1.
The norrnal 
process 
of summer 
stratification 
begins 
in the 
spring 
as the 
ice
millts 
and 
the 
water 
warms. 
l,lhen 
the 
temperature 
reaches 
4"C, 
the 
water 
colurnn
coinpletely 
,nixes 
(spring 
turnover). 
l.larrning 
c<lntinues 
and the 
cooler, 
more
dense'water 
stays: 
at the 
bottom 
while 
surface'temperatures 
continue 
to 
rise. 
A
thermo'ilihe 
develops, 
with 
water abov'e 
(epilimnion) 
able to 
mix 
f'reely 
causing
it 
to 
be fairly 
uniform 
in temperature. 
The 
water 
below 
(hypoljrnnion) 
is 
not
able 
'
to 
mix with the 
upper layer, 
and thus 
receives 
no 
new 
supplics 
of 
oxygen.
DegomRosition 
of organic 
material 
at 
the 
bottom 
of the 
lake 
consunes 
oxygen, 
anrl
t:1"
In 
rnosE 
'''' 
\
euEropnlc 
lakes, 
oxyqen 
becomes 
depleted.
2.8
l'
T
I
t
I
I
T
I.
t-
t
l'
,1'' 
.? ,
, 
::
I
T
I
I
I
t
I 
:1
I
Variatior;s 
of 
thls 
typical 
surnmer 
therrnal 
stratificaf 
ion 
pattern 
were observerl
in 
Coffeen 
Lake. 
The 
water 
column 
at 
Station 
I 
was 
sLratified 
!hroughout 
the
Sunrner 
at a depth 
of one to 
three 
meters. 
Iemperatures in the 
uppcr layr:r of
water 
were often 
extremely 
high 
(once 
reaching 
43'C 
in 
l9B0), 
because this
station 
was located 
close to 
the 
pohrer 
plant 
rlischarge. 
r,.lhile 
a thermocline
does 
not 
normally 
appear 
that close 
to lhe 
surface, 
it 
was likely caused 
by 
the
warm 
wator 
discharged 
from 
the 
plant 
tending 
to 
stay 
at 
the 
surface,
Hypolimnetic 
dissolved 
oxygen concentrations 
were 
'low 
(frequently 
below 
3 
mg/l 
)
but 
oxyqen did 
not 
become depleterl. 
0xygerr 
in th€ lower layer 
could 
have been
present 
as 
a 
result 
of 
unstable 
stratification 
orr 
more likely, replacement of
the 
water 
caused by the 
current 
from the 
discharge.
Station 
2 was 
stratified 
from 
May through 
september 
in 1929. 
r,ro 
stable
stratification 
developed 
in that 
region during'1980. 
At Station 
2.5 
there was
no con^r.inuous 
stratif'cation 
for extended 
periods, 
although thermocl ines did
appear 
on occasions 
in 
the 
summer. 
Stratification ctid 
not occur at a 
consistent
depth' 
but occurred 
anywhere from three 
to 
eleven meters. 
Oxygen depletion
occurred 
at 
Stations 2 anti 
2.5 
fro,n 
June 
to 
September 
in 
1979 and from 
llay to
August 
in 
1980, 
inrljcating that 
stratification, 
though 
unstable, 
was sufficient
to 
prevent 
consistent 
mix:ing 
of the 
entire 
water column.
i 
Station 
1.5,'located 
near the 
dam, 
was 
adjacent to the 
discharge 
arm and was
also the 
deepest 
part 
of the 
lake. 
Continuous 
stratification 
was observed 
in
this region 
from lrlay through 
0ctober 
of 
both 
1979 
and 1980. 
At 
the 
beginning 
of
the 
summer, 
for example in l9B0 
on 
June 
3, 
the typical 
seasonal 
vertical
temperature 
distribution 
developed 
(Fi 
g. 
2.3), althouqh 
hypoiirnnetic
temperatures 
were higher than 
norrnal because 
spring 
circulation 
had occurred 
at
a 
temperature 
much 
higher than 
4'C. 
ft 
the 
dgpth where 
the 
temperature 
began 
to
decrease 
rapidly, dissolved oxygen levels 
also began to 
decline 
rapidly. 
As the
summer 
progressed, 
however, two thermoclines 
developed. 
0ne thermoc'line 
at 
a
, 
rtepth 
bf 
bne'to three meters, 
resulted 
fiorn 
heated water 
from the 
discharge 
arm
staying on 
the 
surface rather 
than mixing. The 
other occurred 
at a depth 
of
, 
seven 
to 
dleven 
meter:s 
(Fig. 
2.3). 
0xygen 
was f airly.urriforrn 
or increased
.',slightly 
with 
depth 
in 
the 
upper 
layer and 
becarne 
depleted in 
the 
lowest 
layer.
l,
2.9
. 
:.:
I
:,...,.
i.l
I 
.:
I.
T
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I
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,l
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'u
Fi
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.J 
,q.|
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ts,tr
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c'r 
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tU::.
F.
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t*
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=l
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(fi 
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Be!pen.the]tw-othermoclines,oxy9enrapidlydecreas€din.concentrationwith.i
:                       
r,
lncredsing 
depth 
but 
did not 
become 
depleted, 
whereas 
ternperatures in 
gris 
zose
were 
fairly 
uniform 
(Fig. 
?.3). 
Ihese 
thrce 
layers 
of 
[he lake, 
which 
wert,
partltioned 
by 
the 
thermoclines, 
possibly 
did 
not 
mix rith 
oach 
other during 
the
entire 
sumnr, 
Since 
the 
mi<Jdle 
layer 
was 
at 
least 
partially 
in 
the 
euphotic
zoner 
oxygen 
was 
generatecl 
by 
algal 
photosynthesis 
thus 
cornpensating 
for 
oxygen
consumed 
by 
organic 
decomposition 
arrd 
preventing 
oxygen 
depletion, 
Oxygen in
that 
-:'
layer 
might 
also 
have 
been 
present 
as 
a 
result 
of 
occasional 
mixing 
with
the 
upper 
iayer 
if instability 
occurred 
from 
interruptions 
in 
power plent
gener 
at 
i 
on .
.t::
l
a.:,  
,::.
r-  
ai:i:l
:,,:. 
=: 
:
::tti,';*,1
', 
:.aa  
::
.::',.:.,:::
2.t I
'a" 
.:i:.     
, 
i't.' 
r 
r'l 
, 
,
:
L 
lIi 
RAIIJRE C I 
IIt)
.,:       
a:, 
. 
l 
' 
: 
,i,i
Liehr, S. 
19i9. 
Thermal 
mappi'tg. 
In: J. A. 
Tranquill 
i 
rrnd 
R, 
!i. 
Larino''e
(eds,). 
Envlrorlrnental 
s'tudies oFCoffeen Lake: 
'First 
Annual 
Repcrt 
io 
:.
-. 
Central 
Illinois 
Public'ServiCe 
Company, Illinois 
Natural 
tlisLory 
Survey.,,
Liehr-Storck, 
S. 
1980. 
lhermal 
mrpping, In: 
J. 
A. 
Tranqui I 
] 
i 
and 
lt. ll.
Lar imore 
(eds. 
). 
[nvironmental studies-i-f Coffeerr 
Laxe: 
Second 
A.nnual
::,Report 
to 
Central 
Illinois lubli: Service 
Company, I'llinois 
l{atural. 
Histor-y
Survev.        
.:                            
l
-- 
- 
-!
-1,
2.,12
il.
1I
,:l.i
7;i:,' 
,
, 
,,:=. 
SECI l0ll 
l
,IATIR 
qUALtTY 
0F 
COf Fff.f{ LF,K[
l'', 
by
Sarah 
Liehr-Storck
ABS IRA{.7
llater 
quality 
was 
studied in 
Coffeen 
Lake 
from 
August l9/0 
throrrgh 
Oecernber
1980. 
Total dissolvect 
sol 
ids 
ancl 
sulfate 
concentrat 
ions 
decreased 
rluring 
tire
.spring 
flood 
of 1979, and 
then 
qradually 
increased 
to the 
end of 
1980. The 
.
total 
arnount 
of dissolved 
solids 
arrcl 
sulfate 
in the 
lakc 
also increased 
frorn
,June 
1979 
to 
December 
1980. 
Perior1ic 
flushing 
of water frorn 
tne lake was
apparently 
necessary to 
maintain 
c0nstant su'lfate 
levels, 
Aiknlinity increosed
from 
l9't9 
Lo 
19u0, 
providing 
additiona'l 
bcnef 
icial brrf 
f 
ering capacity 
against 
pll
chan9es.Turbid.itywashiqhestatthenorthenc|ofthe]akeafLerper.iotJsoi
heavy 
precipitation. 
lhe 
railroad 
causeway 
with 
two 
small 
culverts through it
served as 
a 
barrier, 
Ftrcventing 
much of thc turbirJity 
entering fronr 
the
l
watershed at 
the 
upper 
end 
of 
the 
lake from reaching tire 
lower 
part. 
of 
the lake;
Totai 
phosphorus 
ievels 
r.Jele general 
ly highest in tlre upper 
end of 
the I 
ake. 
' 
',.
Inorganic 
nitr'ogen 
c,onccntrations increaserj 
<lramat 
jcally 
at al 
I stations in late
1979 
anrl I980. 
The 
greatest 
increases 
of 
inorganic 
rritrogerr 
occurrer'l aL
,stations 
nearest 
the 
pohen 
plant 
discharge, 
and 
r,orrnal 
seasonal 
nitrogen 
cycles,
:,were 
disrupted. 
Chlorophyl 
I g concentrations 
were corrsistently 
highost 
at 
the
north 
end of 
the 
lake.above the 
railroad 
causeway and lowest in the 
dischargc
drm. The 
conclusion 
that the 
north 
encl of 
the 
lake supportecl 
greater 
standing
'crops 
of aigae 
was 
consistent 
with 
observations of higher 
pH 
value 
ancl 
greater
'sat,uration 
of dissolverl 
oxygen 
there. 
jlf'ecf--:Ipggi 
glgaqer--A.Iaof-eff.Lreqt5-qr
l_ 
t. 
Lowconcentrationsofdissolvedoxygen
were,observecl for 
extendert 
perjods 
in 
deeper 
areas of 
the 
lake 
during sumnter
rnonths. 
0xygen 
was depleted for 
most 
of 
the sunmer throughout 
extensive areas.
-of:the 
lake 
indicating eutrophic conclitioni. 
In 
wirrter, 
cornplete 
rnixing of 
.rrrost
of 
the.lake beyond the 
discharge arm 
prevented 
oxygen 
depletion frorn 
occurrting.
3.r
I
I
I
I
I
I
I
T
I
t
T
I
I
I
I
:: 
:-:
ra:-::::'
't:::.
j.li'.:::
'i,:::=::
:-:t::l
1:::r:.
i'::.
=:
:.;: 
: 
:- 
::
,ir:;t:, 
;
t 
r..a 
.
!:: 
'.::..
i r:a:a..'
!::-:: 
t-'
:!-.1:t
t:i::::
-: 
-- ra:
.:-,: 
:
:.:::
,ri: 
. 
:.
I r{tR00ucT 
t0N
The 
water 
qual 
ity 
invest 
igation 'rras 
undertaken 
with 
the 
purpose 
of 
evaitrat 
in,.;
brater quality 
in 
Coffeen 
Lake after 
the installation 
of 
net,r 
HdsLervater 
treatrnenL
-'iacil,itjes'at 
the 
po'ler 
pldnt 
dnd 
with 
more norndl 
precipitation 
patLerns. 
, Tlr€:
investigation 
included 
(l) 
monitoring 
wdter 
qudlity 
param€ters 
irr 
th€ 
lake',anrl 
:
determilring 
the 
cause 
of changes, 
and 
(z) 
determining 
hovl 
temperature
,, 
distribution,resulting 
from 
the 
discharge 
of 
a thermal 
effluent 
affecterl 
waler"
qual 
ity. 
The 
investiqation 
includerl 
studies 
of circulation 
patterns 
in 
the
lake, 
cl 
irnatological 
events, 
and 
chemical 
inpur-s 
to 
ilre 
I 
ake. These 
claLa 
were
used 
to 
assess 
the 
relative 
impacts 
of climatological 
events and 
plant 
operation
on therlake, 
and to 
determine 
hovJ 
the 
temperature 
distribution 
affected 
mineral
cyclingandeutrophication.t.Jaterqualityparametersthataffectedthebiota
are.discussed 
with 
particular 
reference 
to affect.s 
on 
a)gal populations.' 
",'
'l
.T
T
. 
.'r.          
I
- 
:.::: 
::. 
: 
.:
3,2
:::
l{A'i[,i 
I 
;115 
Af{0 
l.lf 
Til0l,S
SAI4PL 
IN6 
SCIIEOIJLE
l'later 
samplcs 
were 
coi 
locted nronthly 
at Staticns 
l, 
z, 3, anc 4 
ar. 
the top,
nidrJ 
le, 
antl b,ottom 
of 
'Lne 
wdtu. 
colri,nrl anrj 
at StoLion 5, 
Lhe 
slag 
ponrt 
outf 
low,
the 
coal 
pile 
runoff, 
the 
c.ral 
pile 
runoff 
seLtlinq 
pond 
ortfl6r1, tile 
easL.lrin
inf 
lowing 
stream, 
ancl the 
west 
arrn 
inf 
lo*ing 
stream 
(see 
Fiq. 
l,?). 
Sampl 
ing 
.rL
the51agpondwas'discotltinuer|afteritwasa|ronr|onediliAugust1979.Ine
station 
at 
the coal 
pile 
runoff 
was 
changed 
Lo the 
settling 
ltond 
o,.rtf 
low in 
the
'ni'lrl 
le 
of 
tha f irst 
year 
when 
settl 
rng 
porrd 
operation 
begarr. Af 
L,jr opr.:r.ttion
began, 
direct runoff from 
t.he 
coal 
pile 
no 
lonSer 
ran into 
Lhr.: lake. 
SLrearns
f 
lowing 
into 
the 
east and 
west 
arns 
of the 
lake 
were both 
irrLerrnrltent., 
arril 
ilrey
could 
only 
be 
sampled 
in 
the 
sprinq.
The following 
pararneters 
were 
Ineflsured 
d[ 
'nonLhly 
irrtervals 
f 
rorn 
AugusL lgZB
through 
Decernber 
1979: 
turbirJity, 
total 
alkalinity, f 
r-ee 
carbon rlioxirle, 
t0IA
hardrtess, 
total 
phosphorus, 
soluble 
orthophosphate! 
arilnoni.l 
, 
nitrate, 
niLrite,
total 
iron,:soluble iron, 
ferrous'jron, 
sulfate, 
sulf 
itr?, 
161sl 
sulf irle,
dissolved 
hydrogen sulfide, un-ionized 
hydrogen 
strlfirtc, clrlr)rirle,,tnrl 
f 
lrrorirje.
At 
quarterly 
intervals 
water 
samples 
,,{ere 
dlso analyzed 
for 
or 
q.lnic 
rriLrogen.
total 
organic 
carbon, 
particulate 
organic 
carborr, 
rJissolved 
organic 
cartron, and
clternical 
oxygen 
demand. 
After 
0ecemtrer 
1979, fluoride, 
sulfite, irqn forrns,
chernical oxygert demartd, 
anrl 
particulate 
anrt 
soluble 
organic 
carbo,r.leru,
elilninated 
from 
the 
pararneter 
I 
ist. 
Sulf ide forrns 
were measured 
only when
oxygen was depleted 
in 
the 
hypolinnion. 
Chlorophyll 
g, 
pheophytirr 
g, and t,;tal
and 
particulate 
organic:carbon t{ere 
measured 
nronthly f rom 
rlupl 
icaLe 
intr:oraLed
sar.nples 
of 
the eufiirot 
ic 
zonc at the f 
our 
iriaj0r 
lake sLat 
ions .rntJ 
at the 
i 
ntake
of 
tlre 
power plant.
::..5
i.Il:
:'.'I,:
,.-
,.I.a 
. 
.,a
,l
Pr,of 
i les of,,temperature, 
dissolved 
oxygen, 
ald toLal rlissolvetl 
solids 
r+ere
rneasured 
twice 
monthly at 
I<n 
depth intervals 
dL 
Llte 
four,najor 
sLations 
lnd 
at
Stations 
1.5 
.:' 
'and 
2.5 
(Fiq. 
1.2). At the 
s,rme tir€, 
prt 
wils 
Inr-,(.tsi,red 
at 
Lhe
surf 
ace, 
rniddle, 
and bottom 
of 
the 
water 
col 
rlnn 
at 
those 
st.aL ions.
. 
1,'.:.
:.-::a:
. ,.,':.:,., 
a,
,.;. 
.
.:.:--:.;.:.
3.3
::' 
, 
ti'
I
"jl": 
" 
' 
.:.:
I
I
I
I
I
I-
I
T
I
t
I
,t,
.j.
I
I 
:,
,.',,,' 
I
,
'a.
I
T
.'a-='t;'a
3.4
:
Iahle 
.l.l 
I'l*thods 
us{:d 
to 
trlnlyze 
r:he;nical 
par,l:r,eLers.
Parannter                            
l'le 
thod
Turbldity
total 
alkal inity
Free 
carbon dioxide
lotal 
phosphorus
So 
I 
uirl e orthoplrosphate
EDTA hardness
Anrnonia 
nitrogen
I{rtrate 
nrtrogen
Nitrite nitroqerr
Sul 
f 
ate
Chloride
Fl uor i de
Ir.on 
(total 
, 
sol 
ubl 
e, 
and
ferrous 
)
Sulfide 
' 
.. 
(totat 
and un-ionized
and dissolved
hydroqen 
sul 
f 
ide)
urqanlc nrE,roqen
0r:ganic 
carbon 
(total,
r. 
' 
particulate, 
and
<lissolved)
Chemical 
oxyqen dernand
Chlorophyl 
I 
a, 
pheophytin 
a
i'aiiitek 
i4odr:l 
2l 
nephelom,:ter
'l'
Stondard 
l4etlrorJs 
l4th 
ed,, Lilrdtecl 
to 
plt 
4.60
Ca 
lcul ated by 
method of 
l'larvey 
{ 
I960) and Park 
i 
1969)
Stannous 
chloride 
method 
,        
' 
'
:.
SLahnouschloriderne[hod(Autoanaly.zer)
E0TA colorirnetric rnethod              
, 
"
l.lodj 
f 
ierl 
phenate 
nethorl 
(Autoanaiyzer)    
.'
Cadmirrrn rerluction 
method 
(AuLoanalyzer,)
0l 
azoti zat ion nethod 
(Autoana 
lyaer)
Turbidimetric rnethod
:
Argentometric 
method
,Electrode 
method 
on 0riorr fudel 
601'nretcr 
, 
, 
.,1
Pherranthrolinenrethocl 
r         
,,
Methylene 
blue visual 
color 
matching 
rnethod
Total 
Kjeldahl rnetnod 
(Autoanalyzer)     
' 
r..:.i'
.  
: 
'...1'
Direqt 
.injection 
metho<J 
on 0ceanography 
International
Carbon 
Systern
llach 
Reactor 0i 
gestion 
COD method 
(J 
j 
rka 
and Carter.',,1975)
St 
andarcl 
irlethods
'l
-:' 
:: i
t
I
T
I
I
I
I
I
t
I
I
I
t
I
T
I
I
RI 
SI,lL iS AI{O 
I) 
ISC{JSS 
I 
Of{
Data 
f 
rom 
the 
f inal 
col 
lection 
period 
of 
July 
l9B0 through 
fucernher 
l9B0 
are
cotttairtcd 
in 
Appcndices 
3.l -3.ii. 
Previously 
col 
lecLatJ tJata 
are I 
isLe<l in
1979) antl 
Appendices
3.1-3.'3 
of 
the second 
annual 
repori|- 
(Liehr-Storck 
l9B0). 
. 
, 
:, 
:
DISSOLVED 
SOLIUS
Coffeen 
Lake had .1 
much 
greatcr 
concentration 
of 
Lotal 
rJissolved 
rol 
itls 
(TDS)
than 
rJid 
five 
other lakes 
in 
this 
geoqraphical 
area. 
the 
rilcdn 
concentraLiorr of
TDS in 
Coffeen 
Lake on l7 
June 
l9B0 
was 
853 
nrgi'1 
as 
NaCl, 
'rvhile 
fivc 
other^ 
lakes
in 
the 
area sampled 
on 
lB 
June 
l9B0 
(Liehr-Storck 
l980) 
hatl 
c0nce'tlrati0ns'?n
the 
range 
frorn 
l33 
to 
321 
mg/l as ltaCl 
(table 
3.2). Lake Sangclrr'is, 
anoLher'
cooling lake in 
central 
Illinois, 
ltad 
a mean 
TDS 
concerrtration of 
319 
nrg/l 
as
NaCl 
(Iable 
3.2) 
(Brigharn 
lg8l 
).
,:
Little 
variaLiort 
j
in 
TDS 
occurrerl 
arnong 
stations at 
rrrosL 
tirnes 
of 
thc 
ycrr 
during
this study. 
ln 
the 
spring, however, 
concentrations 
at Station 
4, in 
the upper'
enrl of 
the 
lake, 
clropper.l consirJerab)y 
relative to Lhc 
other 
sLaLions,
corresponding to 
increased 
rainfall and runoff 
creating 
higher 
lakc 
elevation
(Fig.'3,'l). 
The largest 
tlrop 
in iOS at Station 
4 occurred'il 
the 
spring 
of 1979
when 
t.he 
rnost 
dramatic 
increas€ 
in 
lake 
elevation 
occurred. 
The 
concentr'ation
at 
Station 
4 also decreased 
relative to the 
other stations'in:Augrst 
l9:zg rturing
a 
lrerioci 
of 
heavy rains.
Tlte overal 
,'::.
I concentration 
of 
Tl)S 
varieit considerably during Lhis 
sludy, with 
a
l..g--qg.j9gg1.9-e 
.q.cjurring, 
in.the spring 
of 
1979 
followed by 
a 
progressive'
ii-i-,t:Sgr-q,' 
Since the'volume of the'.lake 
also varied, 
however, the 
toLal 
imounb
of 
dissolved solids,in the lake may be 
a 
more 
rneaningful 
parameter 
for
cteter:;rrining 
whether dissolved sol.ids actr.ral ly 
increased 
or decreasr:<.|. 
Us''ing .r
lakc 
: 
'. 
elevation-volurne 
'.:a,,:              
: 
,' 
relationship 
, 
.:. 
(Fig. 
3.2; 
Sargent 
onrl 
Lundy) 
the 
arnourrt 
: 
, 
'
of
dissolVecl solids wa5-calculated 
rdrrd 
plotted 
against tirne 
(Fig. 
3.3). A large
decrease was observeJ in 
the 
spring of 1979 when water 
stored in Lhe reservoir
was 
,f.l 
uil
uslled 
over 
the 
spi'llway asr,-lar.ge 
amounts'of rain 
and:runoff 
waler,entered
. 
""tl
,:'i:t:i-.1. 
::
1    
:.   
.:-,a.     
I
3.5
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\h
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+J
P{J
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l- 
l-,
F.F
aJ, 
(uJ
a)o
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-.:
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cr.=
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a7'
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500
580
560
570
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Vofume
15    
20
In 
Thousonds 
Ol
25
Acre Feel
- 
at 
:'. 
-         
- 
:.      
. a--
Figure 3.2. 
Relatlonship 
of
, 
'.t 
,  
surface area 
1n
Report SL 
1990)
lake 
elevatlon
Cof 
f een 
l,ake.
3.9
with 
storage 
volume 
and
(Source: 
Sargent and 
Luncly
I
It
t,'
'I'
'l"
l'
l-
:
l'
' 
t.
'l'
a:
l=
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U
u
m
r\
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the.lake.Frornlatesunrnet.of'l979r:nt,|ltheenr|oft|it,::,|'i,rt|y,liL||e
orklitional 
water was 
f lushed 
f rom 
the l,rke, 
trntl 
a 
f 
airly c0flstdnt 
increase 
in
total 
dissolvecl 
solids 
was 
otrservecl. This 
iilr.rease 
can 
l)c:al.i.riblterJ 
Lo 
:i;rplLs
frorn 
precipitabiort 
anrl 
runof 
f as 
well 
as 
f 
rom 
deminr:ralieer 
ivastes enrl 
c0al 
pi 
le
runof 
f 
porrd 
ef 
f 
luerrts. 
'
Even thouqh 
t.otal 
dissolverJ 
solirls 
concentr-ations chanqed 
during 
lhe sturiy,
per:iod, 
the 
relative 
composition 
of lhe 
anion 
components changed 
on'ly 
slightly
during 
that 
time 
(Fig, 
3.4), excepl 
at stati0n 4 
rluring 
the 
spring 
flood 
of
l?79, an.!, to 
o lesser 
extent, 
during 
the spring flood of 1980. Instead of the
carlionate-bicarbonite 
anions 
expected to 
tre'dominant 
in 
trodies 
r,,f 
water 
irr
ternperate 
rregions'lHutchinson 
1957)', sulf'ate was ttre rjorninant 
anion. 
Sulfate
concentrations 
were much h:igher 
in Coffeen 
Lake 
than in 
five lakes 
cf 
the
suriounding area 
oi 
in 
Lake 
Sangchris 
(Table 
3.2). 
Both the 
high 
conceritration
of sulfate'and 
the 
extreme domindnce 
of 
the 
sulfate 
anion sugcest Lhat 
Coffeen
Lake contained 
sulfate 
concentrations that 
are corisiderably 
great,er 
than normal.
The 
increase in 
sulfate 
concentration 
over,firne 
is,illustrated 
by data 
collectecl
and 
provided 
by 
the 
power 
plant 
sjnce 
.|966 
(fig. 
3.5). 
ihe rnost 
rapid 
increase
occurred 
cluring the 
period 
f 
rom 
.|975-1976, 
wiith 
a 
decrease f 
ollovrirrg 
in 
1977.
Sulfate 
levels 
in the 
lake 
generally 
corresponcletl to 
sulfate 
levels in 
the 
asn
ponds 
(Fig. 
3.5). 
These 
ponds 
were 
taken 
out of use in 1978, 
,rnd apparently
sulfate levels 
in the 
lake 
have 
dropped 
substantially as a result.
Sulfate 
concentrations were 
found to 
be significantly 
differenL 
amontl stat,ioirs
(Station 
3 vs. 
4 and 
Stations I 
+ 
2 vs. 
3 
+ 
4), 
rnonths, 
and 
sLations by 
months
interaction 
(faUte 
l.l).  
These 
differences 
were mostly 
caused by the 
large
decrease in sulf ate,concer'rtrat,ions at Slation 
4 
during thri 
springs 
of 
1979 
and
1980 
(Tables 
3.4 
and 
3.5). 
At other tirnes 
of the:year there 
was 
ljttle
difference among 
stations 
(Fig, 
3.6). 
Significantl.y 
lower 
sulfate 
levels
ocaurred 
in 
.|979 
than 
in l-q8f) 
(Table 
3.6) ai a restrl'l 
of frorn 
the 
spring 
floorJ
.::"
of,1979. 
:A 
substant'ial 
drop in the lakewide 
sulfate means 
occurred in the
spring of 1g79, 
from 
596 
mg/l in January 1979 to 3'10 
mg/l in 
May i979. 
Afler
thai time, however, sulfate 
concentrations increaserl 
steaclily 
(Fi9. 
3.6) 
untii
.:" 
they 
:.,'
reached,512 mg/l in December 
1980. This increase 
was 
acconrpaniecl 
by 
an 
l
,ovir.al'l.decrrease 
iri, 
lake eleVation't(Fig.'3.''l). Therefore,"fo 
cleter,rnine i6'',the
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quantity 
of 
Sulfate'in the 
lake 
had increagcrj 
0r 
decreasrr,, Lhe'clevation-volume
relationshlp (Fig. 
3.2) 
,ias 
.igain 
used. Ihere 
was 
.l 
subsfnntial' ctecline 
in 
the
sulfate 
content of the 
lake 
in the 
spring 
of 
l9l9 
*hon a 
consirlerallle 
rlrnrrirnL of
ilater 
store{, in 
the reservoir 
vJas 
f 
lushed 
over the spi 
ll,*ay. 
l'rorn rhat 
Lirne
until 
the 
end 
of the 
stutly, the amount 
of sulfate iri 
Coffeen Lake 
incredsed
fairly 
steadily. tlhen the 
study 
enrJed 
in December 
I980, 
the 
sulfate content of
the'lake 
hatJ 
not 
increased to 
the 
amount 
present 
at the 
beginning 
of 
the 
study,
so the 
amount 
lost by 
flushing 
in 
the 
spring of 1979 
hacl not 
yet 
been replaced
(Fig. 
3,7), 
[his 
pattern 
of decreasing 
sulfate 
with a subsequent increose 
was
very 
sinrilar 
to 
the 
pattern 
observed 
for 
total 
dissolved 
solids. 
Tlre 
percent 
of
sulf 
at.e in 
the 
composition 0f anions 
did not 
change drarnal'ical'ly 
throughout the
study, 
except 
at'station 4 in 
the 
spring as 
alreddy 
discussed. 
Prior 
to 
the
spring 
of 
1979, 
sulfate comprised 
about 
84% of 
Lhe 
ani0n 
content 
by weight.
Fron 
June 
.|979 
through 
the 
remainder 
of 
the 
study, 
sulfate',*as 
about 
BOX by
we'ight, 
with little variation.,                 
' 
:
Sulfate 
concentrations 
were 
significantly 
lower 
(p 
<0.02) 
:'in 
the 
hypol irnnion
when 
rlissolverl 
oxygen:concentrations 
were low. 
Sulfate 
is 
reduced 
to 
sulfide
untler 
low 
oxygen 
cortditioris, but 
hydrogen 
sulf 
ide was 
not 
rtetectetj. 
Al 
I 
sulf 
ide
produced 
was apparent'ly 
precipitated 
as iron 
suifide. 
Lack of 
stratification 
irr
winter 
protrahly prevented 
sul f irJe f 
rom bei 
ng f 
ormetl at that 
t 
ime.
Alkaljn.ity levels 
were 
lower 
in 
Coffeen 
Lake 
than in 
most 
of the 
five 
lakes 
in
the 
sarne 
geo<;raphical 
area 
and lower 
than in 
Lake Sarrgchris 
(Iable 
3.2).
Statistical 
differences were 
similar 
to differences 
for 
sulfaLe 
concerrtrations
(Table 
3,3). AlI statiorrs had about 
the 
same alkatinity 
tevels, 
with the
exception of Station 
4 
rlurinE 
the 
spring 
of 1979 and 
.l980. 
Alkalinity 
was
probably 
more djluted 
at Station 4 than the 
other stabions 
as 
a result 
of sprirrg
rains 
and 
runoff, 
although alkalinity 
levels decreased 
at all 
stations 
aL Llrat
tirne. 
0vcrall,.hovlever, 
alkalinity 
increased 
in 
Coffeen 
Lake 
during 
this 
sturly.
The 
mean 
alkalinity 
in 
1979 
was 65.5 
mg/l 
as CaC03,:arrcl 
the 
mean 
in 
l9B0 was
82,6 
ngt/1 
as CaC03;(Table 3.6). 
These 
levels 
were 
arr 
improvement 
since
1g75-76 when 
data 
collectecl 
at 
the 
power planb 
indicated 
that 
alkalinity 
levels
plunged 
dramat.ical 
ly 
to abnormal 
ly 
low 
levels 
(f 
ig. 
3.S)., The,lrigher 
alkal 
inily
is 
a desirable characteristic because 
it 
provides 
greater 
buffering 
capacity
. .., 
,,_r, 
.  
: 
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spec.ies    
.t 
lgarl
t
against ptl 
chances                                                                     
l
(K 
i ng 
I 
97ri) .
0f
The 
.iwo 
other 
rnaJor 
components 
of totdl 
disso'lverj 
sol 
iris 
in 
Cof 
f 
een [-ai:e wer'r-'
hardness:lcalcium 
anrj 
maqnesiwr) 
anrl 
chlorirje. llarrjness 
levels were 
lower 
Lh0n
inlthe 
f 
i've lakgs in 
the 
same ,tred,'uut 
higher than 
levels 
ir; 
Lake Sarrgchris,
whil,e 
chloride levels 
were lower 
than 
levels at 
Lake 
Sangchris but higher 
than
in 
the 
other 
five lakes 
(l'able 
3.2). 
Ihe 
ctata for 
these 
paraneLers 
were
observed 
in 
pattcrns 
sirnilar to the 
patterns 
of 
sulfate and alkaliniLy 
(Tablc
3.3I. 
llardness 
was not 
signlficantly 
different 
betwoen 
yedrs, 
but 
chlor'ide was
significantly 
higher 
in i9B0 
than 
in 
1979 
(Table 
3.6), although 
chloride 
did noL
reach 
levels 
as hiqh 
as 
those 
observed at the 
beginning 
of this 
study.,
Decreased 
concentrations 
of 
botn 
parameters 
tvere 
observed 
at Station 
4'during
the 
springs 
with the 
biggest 
decline occurring 
in the 
spring 
of l9/9. 
,As 
pith
the 
other two 
TDS 
parameters, 
there 
was little 
variatiorr 
among 
stations at 
other
timesoftheyear.'  
'      
: 
i 
, 
.
:j
TURBIDITY
Statistical 
differences in 
tur.bidity 
(Table 
3.3) were 
causerl to 
a large 
extent
by 
extremely 
high levels 
(rnean 
143.6 
NTU) 
at Station 
4 
in 
the 
spring 
of t9/9.
Tltjs 
occurrence 
resulted 
in 
h,igher'levels 
at Station 
4 
(Table 
3.4) in 
the 
spring
rnonths 
(Table 
3.5), and also resu'lted 
in significintly 
higher 
turbirtity 
levels 
-
in 
1979 than in 
1980 
(Table 
3.6). The high turbidity 
corresponded 
to 
heavy
precipitation 
and high 
lake 
levels at 
that time.':lncreaseci 
turbidity 
levels
wet'e also-observed at 
Station 
4 
in 
Auguit 1929 
(mean 
.|4.0 
NTU) and 
during 
the
spring 
of 
l9B0 
(mean 
20.0 NTU), which 
were 
also associated 
wiilr heavy
precipitation 
and rapid increases 
in lake 
elevation 
(Fig. 
3.1 
). 
Turbidity 
at
the'::other, down'-'lake 
stations 
did 
not increase 
to the 
sarne extent 
as at SLaiion 
4
located at 
the 
upper 
end 
of the 
reservoir. 
'Durlng 
the 
spring 
of'1979 
the 
nrean
turbjtJiti 
at 
the thr 
ee down-lake 
s.tations was 
only 1 
5.6 NTtl. Apparently
tnovement of water through 
the railroad 
causeway that 
separates 
Station 
4 
from
the'othei'staiions.'was 
slowed 
enough to 
allow 
much 
of the 
particu:late"matter 
to
settle before the 
water 
mixed 
with other 
parts 
of 
the 
lake. 
l{igh 
turbidity
levels 
were 
generally 
associated 
with 
high 
l.eve'ls'of to'tal 
phosphorus'arrd 
total
T
I
I
I
t
I
T
' 
.1
,i:
i
--.:',,,i,,.,;:-
I
l
I'
I
l'
I
il'
il
ill
il'
a';,..',
tl-
t,?
Plt0spt{0Rus
.. 
, 
:
The 
form 
of 
phosphorus 
useri 
by 
ptants 
as 
i 
nutricn!- 
is 
s0lut)le 0rlhDphosDhJr.,J.
lJocausc 
this 
form 
is 
rapidly 
cyclerJ 
and 
convl)rted L0 
olher 
forms, 
it 
is 
rrot a
g00d 
lndlcator 
of avai 
lablc phosphorus 
in 
tho 
sysLern. 
IoLal 
phosphorus 
is
considered 
t0 
be a 
more r[liabld 
osti'r6td 
df availabl6 
phosph6r.us 
{Foai6/oy
i 
e6o) 
.
:
:::
i\
A large 
insrease 
in 
toia'l 
phosphorus 
at all 
s[aIrons in 
August 
)g79 eould not 
ba
exlilained. 
Therefore, 
t0 
exclude 
possibly 
errone0us c,ata, 
thc 
data from 
that
mortth 
were 
not 
used 
in the 
statistical 
analysis 
(Tabie 
3.3). 
Phosphorus 
was 
not
significantly 
different 
in 
197,9 and 
1980, 
with 
annual 
means 
of 
0.051 ng 
p/l 
ancj
0.054 
ng P/1, 
respectively 
(Table 
3.6). Station 
differences (Sration 
3 
vs. 
4
and 
Stations 
I 
+ 
2 vs. 
: 
+ 
4) were 
mostly 
accounted 
for 
by 
higher 
levels 
at
Station 
4 
(Table 
3.4). 
Increase 
in 
ptrosphorus 
at Station 
4 
qeneral 
Iy
d the 
highest levels 
were founrl in 
the 
spring
(Table 
3.5), 
with maximum 
concentrations 
of .277 
ng 
P/l' in 
Ap:r"i I 
lg79 anrt 0..|73
rng 
Pll 
in 
April 
1980. 
Frorn 
the 
spring 
of 1979 
untit 
tt. rottowing 
spring,"
phosphorus 
levels at 
all 
stations 
were 
simjlar, 
witir stations 
3 ancl 
4 
cenerally
having 
slightly 
h'igher 
levels 
than 
Stations 
r 
and 
2. 
In 1980, 
however,
phosphorus 
level s' 
rentained 
higher 
at Station 
4 throughout 
the'suslmer.. 
'
Phosphorus 
levels 
were 
sintilar 
at the three 
stations in 
Lhe 
lower 
end 
of tlre
lake, 
and 
gradually 
rose 
throughout 
the 
sumrner. 
phosphorus 
levels 
then
decreased 
at all 
four 
st,atjons 
in the 
fal l.
N 
I 
TROGEN
The 
nitrogen 
content 
of water 
is 
cornposed 
of 
organic 
ancl inorganic 
forrrrs. 
The
inorganic 
forms found in 
natural 
water 
are 
ammonia, 
nitrate, 
and 
nitrite,
although 
nitrite is 
usual ly found 
in only 
small 
amorrnts.
The 
typica-|,. 
seasona'l 
pattern 
for 
unstratif ied 
I akes i 
s 
a sumnler 
rnaximurn 
of
anrynonia 
(Hutchinson 
1957). Stations 
l, 
3, 
ancl 
4 
were 
not 
typically 
stratifiecl,
and.,Stat ion, 2, althoug!r.,it 
was 
t.herrnally 
stratif ied in 
the 
sutnmer, 
diC 
not 
nave
significantly 
different 
arrmonia 
concentrations 
at the 
srrrface 
ancl 
botLorn 
during
3.25
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ii.:5.:.:
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++a
4i.-l
Et:
::.-ta:..!
:r-:; 
, 
-
Fli;i=:::,
Ithe'months 
thdt 
stratification 
occurrecl. 
The annoni,l 
cycic 
olrserved r.luririg 
lg/9
l{as basically 
the 
typical 
pattern 
FriLh 
drrmonia 
concentrdti0n., 
irrcrcasing 
ilrrr:Lrqh
.the'.5unfiEr 
and the 
maximum 
occrrrring 
at 
al I 
staLions in 
Auqur'". 
Tlrc 
onl.y
apparent 
deviation 
from 
this 
pattern 
was 
the 
incrc,rsc 
dt 
5tdLlor,4 
in 
lhc
sprinq' 
which 
can 
prol)ably 
be 
expl,rin0d by 
the r'api{'l 
irrflow 
of runoff 
w,tLer 
at
that 
time. 
During 
1980, 
however, 
the 
typical 
arrurrorria 
pattern 
was not 
0bserveil.
Anrnonia 
levels 
began 
to 
rise 
at 
all 
statlons 
in 
late 1979 
with the 
s,naiiesL
. 
increase 
occurring 
at 
Station 
4. 
Levels 
continued 
to rise 
until Harch, 
with
Stations 
I and 
2 having 
the 
highest 
concentrations 
(l.0li 
and 1.107 
mg N/1,
respcctively), 
and 
Station 
4 the 
lowest 
(0.41i 
mg 
N/1). The 
may.irnum 
amrncnia
conccntration 
of 
1.150 
mg 
tlll 
was observed 
in May l9B0 
at 
Station 
l, 
located 
in
the discharge 
arm. 
In 
June, 
anmoni 
a 
level 
s droppe<l 
at 
al 
I 
stat,i6ns, 91ith
concentrations 
subsequently 
increasing 
at 
Station 
I but 
continuing 
to 
decrease
at 
the 
other 
stations 
(Fig. 
3.9). 
The 
extrernely 
high concentrations 
( 
Z.lB0 
ng
N/l) observed 
at 
Station 
I 
in 
December 
l9B0 
were 
apparently 
affecLerl 
by
operations 
al the 
power 
plant. 
Significant 
differences 
of 
anrnonia 
concentration
among 
stations 
for 
all 
station 
contrasts 
(Table 
3.3) 
dre 
explained 
by 
Llre
gradient 
around the 
lake, 
with 
highest 
levels 
founri 
at Station 
I ancl 
lowcst
levels 
at 
Station 
4 
(Table 
3.4). l4onthly 
nleans 
were 
hiqhest 
in the 
spri6U
Inonths 
and in 
December 
(Table 
3.5), 
contrary 
to the 
rrormal 
cycle in 
which
' 
maxitnum 
levels 
occur 
in late 
summer. 
Arnmonia 
concentrations 
were 
signif 
icanily
'lower 
at all stations 
during 
.l979 
than 
during 
1980 
(Tab)e 
3.6). Devjation 
frgnr
the 
typical 
atlnual 
pattern 
of 
armonia 
cycl ing 
plus 
the 
rapid 
increase 
in 
arnnronia
concentrations 
in 
1980, 
which 
were 
significantly 
higher 
at the 
sampling 
statiorrs
nearest 
the 
power 
plant'discharge'indicated 
that 
amtorria 
levols 
were-affected 
by
the 
power p)ant.
The typical 
seasonal 
pattern 
for nitrate 
is 
a maximunr 
in 
r,vinter 
dnd 
spring 
wherr
the.rate 
of nitrification, 
i.e., 
the 
oxidation 
of 
reduced 
njtrogen 
compounds, 
is
most:rapidr and 
min'imum 
in 
July and 
August 
when tlre rabe 
of nitrate 
reduction 
is
the 
greatest 
(Hutchinson 
1957). Again, the 
pattern 
observecl in 
Coffeen 
Lake in
1979 
appro*]r.::o 
:n:."*ou:,ed 
pattern 
(F'is. 
3.10). 
Nirrate 
concenrrari0ns
increased 
at all stations 
beginning 
jn 
the 
fall 
of 
1978, 
and reached 
a Inaxirnurn
'in 
itlarch:of 
0.B08 rng 
i'lll. Concentrations 
starte'd 
to 
decrease 
in 
Apri'l, 
ancl 
the
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r$:* 
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;ii.;:r,r 
iiaiil,: 
j.,tr.  
i. 
: 
',
Signif 
iCant 
dif 
fgreflCe 
belween ye,lrt 
.r,ri ,J4iic 
{.,,!,'l.iirrr;ii 
t;-t 
.,,ti:,,iuri...}ii;. 
r;r.]fri..r.
ConcLlrltraticr:, rlurinq 
ljilC 
tnan 
rlilrii.,l 
\.).t,.1 
:.iair 
jr 
.:.tr,.
Nitrite 
levr:l; 
/rerr.. 
,llS0 
hitner 
lrl 
': 
{tlrj 
r-lr,tr, 
in 
i{.ii,i, 
arl 
it 
::it.
incrLrdsinq 
f rorn 
,04j 
n1 
:l/1 
rrr l<J/,1 
.,r 
.lr"'rj 
ri,; 
li,, 
I 
rn 
lrf 
:;r1 
j:
hiqhest 
fictlft 
o itr i 
te 
cr)lctlrtrat 
liJn 
*t", 
r:it,,t1r,,rl 
it 
,rt,il 
r..irr 
l
StaLirln 
/t 
dur 
inq 
bOth 
yC,lr,,. 
iht:: 
rJrir-l+.:r. 
,nr:rit.i,r,!, 
.i1;ri;. 
'strr 
irii;!.r
lmonLhS 
wittr 
lhe higheSL 
nitrr!-g 
(;r,rr{:rtnlr,l!-rr:r:, 
{1.::tirr 
}.,:i.
j
.:!i 
il--,jrlt-( rr? 
f 
=li 
i 
i}4.,.'
,Ji:r.r 
,,,b 
j. 
ii)l'
tr;.j 
!.hrt 
It**:: 
t 
,t 
r.
/.!i 
!.:."iit.'r' 
I 
'e{.rq-r1
Ihe 
total 
inorqartic 
nitroqr:rl 
ci)ncqrtlrat irrn 
rr4., 
,, 
irlrr!r lf, 
lrlr. 
l./ 
ii 
r 
,'ipr' 
rrr 
i r",.
(Iallle 
.3.3), 
ritlr a rre,rn 
of 
i.60B 
rqq 
ltl1. 
tt,rrt 
rrr 
1,r/(j, 
,r?1 
,r 
:ri.,irr 
rif 
.ii 
1, 
::,;
N/l 
(Iablc' 
J.6). 
The rJre,ltelL 
incrr,rt.t? 
tco'., 
irl.lrr: 
ijrrrir',1 
thr. 
!t,]r 
i,j,l 
f 
r-..,:1
SepLenrber 
l9/? Lo l4arcrt 
l9t-10, 
wiLh 
the rndvi,,rurrr,)LCur:'irr4 
tn 
l,larr:rr 
lgBrl. 
i)rlr.irrg
t:ttat 
period' 
ihe 
tneitn 
concenIrat. 
ion'*f 
lnar.ltalrlc 
!iiLrr;,lt:n 
inr;rrj,t!i](i 
f'r,:i:ri'.:O.l o;n
N/l to 
2,273 
nrq lll1. 
0,rrinrr 
the last holf 
,'rf 
llJ! 
,ttttt 
0rrrinr; 
rli 
rf 
lljlr].
levels 
of inor'9anic rritroqen 
#er',' 
crlnsirte,',thly irl,/Ti-,r' ,rl. 
(,t,tr- 
i0r; 
ri 
r.ntil 
:i. 
t 
lle
otlter staLions 
(Fi 
g. 
3. 
I 
l). 
SLation l, loc;Lerr 
in 
the 
rlis,.ir,irrJij 
,)r:ii, 
lr.: 
J ilre
vittt 
signif 
icantly 
irirlirrir 
lrvr:1,, 
itr,ln 
Sldti0n 
?
(Table 
3.3). 
ThL: rnean 
inorganic 
nitroqen 
ccncenlrlLion 
irr 
l9B0,il 
StcLiun 
4 
wac
1,126 
mg 
il/l dnd at Station l:was 
2,046 
rn,1'il./1, 
i.c, 
tlrt:r't 
,rr/u,.r 
il 
jnrosL 
twi4i: 
i-he
concentrdlion 
of 
inorganic 
nitrogen 
at 
Stdtion 
I 
,.r',.rt 
i>Lrrlron 
ri 
dur-in,y 
lgBi).
,'Both 
the 
increased 
levels 
in'1980 
drtd 
the 
rligLurtrer! 
sGdsorlil 
cyr:l'-1 
0f ni'ir.ogc:rr: 
.
in the 
lake indicaLe 
that 
a significant 
loarJirrg 
of 
niLroq,.,o 
occdrrc(1, 
;rr.rlbably
:::::' 
starting 
:  
: 
-
in 
late 
1979, tlhi 
le 
the 
ratc 
of cyclirtty 
of niLrogr:n 
f 
rsin 
sr-g,l1ic forrns
3.29
a.--:.:: 
a.
't
t:
t:
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'1 
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,:f
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,-
r-' 
i
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nri 
liitri=l,: 
.rtl',1:t4:t\,')::',t1:.,'.:1.;:jrt 
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:rf 
!1t:
nitrOggrr inp,lf 
il 
rrnL,rt,rn.
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nitr0rjttq 
ir-.velt 
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i 
tlrll,-,jn,Litr-,.r, 
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J:-r.r..i; 
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j 
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forl(entf 
l!.irlti ,i.!t 
friliir:rt  
tr,'t,.ti 
l'ji.', 
-'.. 
1!'i .=; 
.:.; 
'i,;i. *rq.1 
1r1,.
| 
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Aurlr;r',* 
i9i'l 
in4.lrf 
li.!i 
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.. 
,r;i,.,t!., iri 
l.!:,j 
{rjr.j
i:, 
the rJtlge 
D€liyccn 
ij,t6-il 
.{lj 
rrri 
ri/i,  
,-ir,+"-l-,1 
! 
i, 
,,!:t 
irr*4!: 
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i$.'t0 
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r:iJ 
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i-ittl+  
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1, n.jl 
frir,!{.)''r.,ir} 
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nilprlggn 
levr!: 
nt dif {r:rer,r. \t 
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rqrr,,
ti:1) 
R,iIl05
*at,irrs 
sf 
tol*1 
nitrrrSen 
t* 
irtl+tph{}!"!r! 
ieri:'{!eni:r.al 
1,r 
1r,;.-1i!jr 
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i?,
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phospit0rriS 
t,J hl: 
Lh€. 
ltqiillrrl 
iutrif:nt 
fr;r 
.ll{,il 
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r 
1r. 
l;,.r' 
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tliLr(rqrlrl 
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I 
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5tat 
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4 
r.rfiirrtryrrt 
I 
J, 
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llt' 
l,id(,,rt 
\:i)
raLios, 
xhiclt 
CJrt 
be 
dccountr.rij 
for'try 
br;tlr rr:Jatrve!.y'l 
<;* 
nitr.r]-lrrr 
lrrrl 
\.i 
:;ir
ilh0sphgrir-r, 
lr:vgl:. 
ibrevr:r, 
lSt,tl 
nilrogCl* 
ixay 
**t 
tju 
ri 
!,r1]rt.rrt 
i!tLl 
i,:+r_lr.irf
dvailable 
tiitrogen 
as 
totai inorganic 
nrtro(len. 
jlr. 
r,!.ri 
ir',ri 
.i 
irr i9/g. 
^;1,^'1
inorgartic rtitroqetl 
iydt 
gc;nsi{ered 
r'.ltlrr:r 
l.lt.tri 
I 
rit,il 
nilr'r'.rtlr-,rr. 
ll:P 
r,1l 
ii11 
sr.,1g
less 
than l2 
f 
ttr 
mosl 
uf the 
year 
(t.larch 
!.r!",J'r'jil ii'r./crnbitr'l, 
In 
igii0, 
?;3 
r' 
1';1! 
ier,
were 
less 
Ltl,rl 
I 
Z 
.rt 
':t 
at iOrt 4 
only dur 
ing 
thr, 
rrri;rrins 
fif 
,rlir 
i I 
, 
f1xg11,1r,, 
61rt
5ePtemb€r, 
ivhieh 
were'the 
months whcn maxirlttrfr 
pht;;plloru:':]4v,Ji 
i 
,t{curr{ii 
dt
Station 
4. Ratios 
of 
lass 
Ihan 
l2 
wtltr] nevrr 
ob:r;r-vert 
,ir, 
thrr 
ot.irr;r 
tirr.r:i-.
stations 
rturinl 
lgBfJ, 
but 
occL'rred 0ccnsinnrlly 
{t4a-v, 
leptr-r:nl)(.,!', 
,trrrl 
llovernher 
i
al. t,hese 
stationg in'i979. the 
increaserl 
nitr,;gp11 
'!r:vcl,, 
in 
Ct:!'f*r:n 
Lak4 
app,:,rr.
t'o have'caused 
tltc north 
en{, of the lake 
to 
change from beinq 
nii-rlqerr lirnited'
[o tieirrg 
pnospholus-.lirnited. 
ilowever, 
the, loxer 
'p*rL 
of 
tlre 
laie 
lppr,are(l 
to
Itave 
been 
phosphorus-lirniled,inost 
of., 
lhe 
t.irue 
even 
br:for-e 
rritrorren 
lev,:!9 
:.
ihCreose{, 
,      
':                        
,,  
1,:
3. 3l
::.-=,"          
'ta':, 
..,t, 
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,'::'."
: 
t:ri :         
... 
. 
'a 
' 
'i' 
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. 
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: 
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.
,,':, 
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, 
t, 
'
CttLilt].lti{Yli ir 
. 
pit 
, 
'J 
!i,'.iil 
if 
:; 
,ii 
v 
j;i 
:i
I
I
I
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Chl€t*gpltyl 
I 
A:c+nCrt*{r;l!o*t 
:a1"1yi1 
,1r'11;i.1.,i .:i 
.1 
;':.;.=, 
i !,t,1: 
:
dr,f 
lnrj 
ail 
rn-i4lnt 
gg'npieri lilu&,"J)d.r' l'iJ? 
ll!7.r;,r 'i 
,,:,:,...  
i
:-i'.1 tf- 
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a 
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J 
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lr,rii.i-;irir.r:r;!{+tr'! 
;r1., ';',.1 ' 
^r.r 
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Iltt<Jr.e.rt4.1|.{{j|iftin1t..a!'iijq''4i.}!.i'":+::,1{.i!=':::];::!'iri!:.:
brhi lf. 
Lhr-? 
!?f-r-:dt€lrl 
i-+!]ta-rn!-r,lLt+41 
,i!, 
.':i.4!. 
t1lri 
! 
rr-:e 
1. 
:::i,-:.:r 
;r 
; 
r:-r
-i.lil,   
Ilre t'eilurr: 
+i 
ilartl,'-i.riate 
arri 
'rr:! 
1'l 
,,r'r;tntr 
...i"fi 
', 
1
P,f 
!- 
l{tt'li 
5Ugilf'.,trj(t 
th,lt 
.)r 
qin 
\l 
r..,tri}\iti 
,r.1,, 
rr.}t 
.: 
1.,., 
j 
?i!., 
i. 
j, 
'. 
,i
trii
:" 
:
Ir
a-.:
1:t
r, 
i
Alq+!'a*f 
ivily 
''cas 
ref 
li:clr-'d: 
in 
lhr: 
iiii. 
4ii1i;!itj  
i-:r:Jtr=:4, 
.]ri:.: 
;:::rl 
r:'::- 
:.t:.;'r'- 
--:
Of 
rJ!gfOlverl 
r:ry'.;cn. 
4l I 
statl{jfrS 
ir+'J ti,tr!.ir- 
li! 
l!i 
i,i:i: 
'...r,*'rx,ri 
:i.fi:.r-i'> 
::i.', 
i 
i
thg 
t{ifller.  
ilt 
Statir:tt 
4, thert r€!-t 
!a:i.t:ri!' li.,i*: 
ju-trr 
I 
l';.- 
',;r1::--r', !i1 
.1i 
i.t..:.:.
pH 
was'above 
9.0, inrtiicatinq 
vigtirou.r; 
j)!r{il-;-rt1i,l.:1ilij1, 
I 
i1 
1'! 
r,,i'!,7 
},i.'l 
,rii::!,",
195il). 
Low 
pH 
{as 
ir(irtn{l 
orrly 
irt 
tht, 
ilt}.:p 
'{att:r 
.!? 
iht:r'+.ii; 
r 
.!"? :i 
ll 
r,,,t
SLatiOns. StatlOrlS 1.5nrtrl 
?n*+?re.!tr4tlf1r:r! 
rjrlrrri'"l 
r]/{tt.;l'!r.\,.t'ri:,e;! 
Ih.l
'l 
ow 
pH (lest 
lhari 
7.5,1 
oc{il'red 
nL th€ 
i}.Jr"l{:irrl,;:f !nr-r:;t i{i?-irrr:t-. lli,r'..: i** 
1;l;.
vdltles 
corresporl0td 
L,l 
lriqit 
r-rlrrr.r:ntf,0t 
ionS 
ilf 
L4rli,irr 
(!?i;).i,:i: 
i'!,r! 
*,.,, 
r, 
,ir'.:'! 
i'., I
by 
rleCOrnprrsil iolt 
1rf 
ort;anic 
,:r.ri.ter 
tln{t 
4r'.cr,iv*ii:!,..,! 
rrr 
r.ilr: iry;t';i,,rrl 
rrif 
; 
.i 
r. 
i;,,;
5traf.if 
icatio*.  
During 
the 
.'urtrrfr 
r-r{ !9ltl 
, 
pii 
i.il.ji:,:'*.,,,',: 
al!il:!-r 
t,l 
!'i!,- 
.,,,'r1i,,--
wa[er' and 
lti,rer in tht 
dur:p 
water 
Lhan 
in 
l]Bi],  
!tri! 
ri(.i,.irt:t'tt.r: 
t.,ttt,ti 
i.',: 
:
!rr,.
resrrlt 
of 
Iiqher 
at\alinity, and Lhrrs, 
grlrati-'r' 
l>rrf 
14e'!rri| 
r,ri.ri.i::L{, rrl l:!4,1. 
- 
,'
Flucttratior;s 
in 
pll 
ciid 
not.]ppear 
unrra!(rrdl, 
.tnC,lir,:l'.- 
i:tp,1,;f 
i-:f pon'a:.:;'|irir:..
ef 
f 
luents 
,rn 
lake 
w,rLer 
pll 
*,'ts apparently 
mini;nnl.
,'
0issolved 
oxygen 
(0.0.) 
./as 
depleted 
in tht hypol i*nlrlrr 
of 
llu rtr:cp 
t.l.utif 
i*d
stations during 
most 
ilf 
bobh sumnrers 
{,.|979 
trii 
!930i, 
thr}(, 
r,i.,Lritlirt.; 
a 
!,rrqt:
parL 
0f 
lirc deep 
section 
of [h€ I rkc to 
'n,rg1 lnirrrnl 
lif 
e 
f 
or 
-r 
rintir!ur'311 ],r
period 
of 
time. 
Surf.acr: 0.0. levels worc loder 
in 
t.ir:.,5rJ:lrrgir'! 
ttr,iri 
in 
trl'.,
tvinters, 
rlue 
to 
warmer 
t:emperatures 
causing'lailcr 
o{ygrn 
sr:lrllri 
ity 
i* 
iirrr
surnmeas. 
At'all 
times of the 
yedr 
0.0. 
aonan,llratiun'g werr Lhf 
hrqirq,;:i 
,1.
Station 
4, 
reflecting cooler 
temperatures 
and'gr:edl.er.rlqal ar:Livity. ilr:irolvr.,l
oxygen 
became 
l'airly 
low 
(les5 
thdn 
4 
mg/l 
) 
irt 
Llre sumrturr's 
,tt St,ll.iorr 
I ivhi-,rr
water',temperdtures eere very 
high. 
llowever,:fJ.0. lnvels 
w*:r'e,',rl'#ayi 
dirirvr-, 
d?'
near saturdtion 
at SLation 
I 
at 
the surf 
ace. 
ltilh 
sdturaticlr lcVt:1.; 
,,rr'r., lif:u!;,
: 
,,:l 
'',, 
,       
,.           
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! 
Ake tn 
hAv!:.,a 
lli'r{*r' 
ineAn 
p,:rcrlr!t 
Sit.rjrdt 
iCn 
ei. 
i-!t;: 
'-,rrf 
,i;11 
j17'i,1,;
i9i; 
thon r1.:r'iti! 
thLr 
ri,{nrtr 
r{ 
l9/q. 
Thrt 
obrtr'r 
}l 
irjn 
,;it;ifxj?'t,) 
Lrtij
th,t' 
niUhcr 
pil 
tur'ifrq 
ihe 
sr;:nrn:r' of 
:9/9 
af 
9t.lt 
i{.)fr 
,1 
;vr\ 
;r.llial: 
:.i
buf 
f 
er 
ing 
capacity 
raItrer 
than 
1re+Ler 
,rlqa! 
ae t 
i';iiy.
!
Al thilugh 
5tatign 
4, 
lrrcat"ed 
no!:lh 
of 
lhe 
rai lr*erj r,a:is(':wryt 
itllip{}rteri tirf
9r'eate5t 
5l&nrli'tq crop lf 
,rlqae, 
.irf 
itr:r 
r,rt.{}S 
of 
pririi'try 
lrr0r,rrr-t 
it 
il 
y 
of t,-rr
occrrrrCd 
nt SLatitin 
I, 
locaterl 
in 
thr: 
,rrra1.t3rr;ri ar;ir 
iir:,;t,irrt 
i!tli-ii.' 
,ffr!s,
phenomcnon 
uay:i.tdicatr 
greaLer:rar-e 
of 
nutrient 
r+'jeneralicr'! 
at 1L*llrin !, rtuc
to 
warrner Lenperdtrrr'(f5 
artd 
polcr' plant r)pernl itr)t. 
Thc 
l,alrrnt 
qf 
rrirtr'ir,ol.;
present 
ef 
ltcts 
lhe arnourtt 
o{ 
bio'trass 
I 
horever, th,-, 
raLe 
ll 
r-,1r;r-,nr--r.tr- 
iort 
Lrf
,.1,
l-
't'
I
I
Tlre 
physical 
and chernic.tl 
factors.responsihle 
fer li:rri';ing alqa'l 
.;rr'*'lh 
n! 
€
diff 
icull to ns5ess. 
Although h:iglter 
i{at.?r 
Lerrp{:r'alures 
afr{J 
i}i)vre!- 
plnnt
operation 
appeared to 
have 
aftected 
aloal activity, 
t,he 
irnpact 
of lhes* 
factors
is 
rJifficult 
to 
dgsess 
because the statitln 
in 
tttis 
coolinq 
I'rke 
thaL.rras 
li:.rst
affecte<J by 
tlre 
power 
plant, 
SLation 
4, 
wds 
very 
dif 
tcrent 
f 
rorn 
Ihe 
olirer
,l
,:;,.. 
:' 
slalions 
in 
ol.her #ays, 
rnaking 
conparisoris 
<Jifficult. LighL 
inLensiLy.was
.r.':'',j,' 
was by 
far the 
gr:eatr:s1", Nutrients were illgo dif 
ferenl 
at Slation 
4 since
phosphorus, 
rriLrogen arirl cdrb0n 
(alkal 
irrity) 
conccrltraIioris 
at 
Station 4 
lll
..-.::.,," 
varied 
frorn tlle 
other 
l.hree staL,ions. ln 
addiLion, some 
of thcse 
par'arnettrs
,:l:::.'.1: 
'
=_.,- 
between 
the,.tuo 
years. 
Alkal 
iniLy'wds 
increased 
1n l9B0 
over 
1979, 
lirus
=,.,,,,-..-,.:providing 
a'gr:eaLer 
carhon sourCe''dg 
well ds 
!n0re 
adeqriatcly brrf 
fer'ed,'vla'Ler'.
,' 
.' 
'  
Al so at 
StaLion 
4, 
turbldity was Inuch 
less irt 
l9B0 
tlran 
irr 1979, 
anrt 
Lhe
.j.':.
'' 
',
,:..,. ,r- 
.,..',..4      
,. 
:::' 
: 
t,',''t' 
, 
; 
t;" 
:. 
.. 
: 
" 
''
:,;;',:,t,,": 
,",::,                                      
a'.,-'it'
l:
nutrient 
I lmit,ing,facto, 
r, 
shif 
ted 
f 
rom 
nltrogen 
lo 
phosplrorirs. 
Ai 
I 
of 
lre:,e
factors 
could have beert 
important In 
determining 
Lhe arnount 
of 
algal 
activiry
l
a1d,in 
determining 
the 
composition 
of the algal spr-'cies 
presenL. 
tlowever, 
the
!le,af 
gradient 
-or'9h]-o-19.phyt] 
g 
present 
from tlie discharge:ar"ln,!q.lhe.101. 
11 
uf.! 
.
of tlte 
11rg 
(ris,.- 
3.1?). strongly 
suqgests a 
direct 
irnpacL 
of 
power plant
operations 
on 
algal 
activity.
3.35
:: 
::.
':l
. 
'l
:a.
,l
r 
''l               
L'iT[llAillR[ 
C'ITIO 
'
Barr,.f,.l,l 
J.li,_Coodnig!!,.J.p. 
Sall, 
arrd 
,).T. 
tlr:lwig. 
l97fi. 
A 
r;r,cr,r 
guirtr
.Los.As/6,SASInstitute,Inc,,.Aaleiqh,r{C.]2qpp
Brigham, 
A'.R, 
lg8l-. 
l{ater 
quality 
in 
a 
cooling 
watcr rsservoir. 
In 
R,t,l.
..of,.anlllinoiscoolinglake..:|llinois{atur.altlisLorySurveyllrilletin
' 
Larirnore'and 
J.A. h"anqtiilli, 
eds., 
Ilre 
Lj[e iiug.iriii 
iir,ry' 
-do*n 
hisrory
3?(a):290-319.
Coutantr 
L'!. 
1980. 
Algal 
investigai;ions 
of 
Coffeen 
Lake. 
ln J.A.. 
t,-unqoitti
'. and 
R'!,l. 
Larim0re, 
6ds,, 
Envir6nmental 
Studies:of 
Coireun 
rii*, 
SecLion 
5,
flatural 
History 
Survey,
Dif 
f 
on: 
l:i:, 
and,F.H. 
Rigler. 
lgl4. 
The 
phosphorus 
- 
chlorophylt 
reiationstrip
in 
lakes. 
Limnol. 
0ceanogr. 
l9(5):l6t-773.
Harvey, 
l{.tI. 
.l960. 
Tle 
chemistry 
antl 
fertil 
iLy 
of 
sea 
water-s. 
cambridqe 
univ.
Press. 
, 
London 
. 240 
ttp.
tlutchirrson, 
G.E. 
1957. 
A Treatise 
on Limnology. 
\,o1. 
I, 
part 
2.
and 
Sorrs, 
Inc , 
, 
l,lew 
york. 
l0l 
5 
pp
Jirka, 
/r.14., 
and 
M.J. 
Carter. 
lglS. 
Anai. 
Che;n.47(B):139/.
King,,:[J.1. 
1970. 
The 
role 
of 
carboir in 
eutrophication. 
Jourrral 
!later
Pol lution 
Control 
Federation 
4Z:2035-2051
Liehr,,,s. 
1979. 
cof 
feen 
Lake water 
qua'i 
ity. 
In 
J.A. rran'qui 
ll 
i
' 
Larirnore, 
eds. 
, 
Envirorrrnental 
studies 
br cd-f,reen 
Lake: 
' 
First
to 
central 
Il linois 
Public 
service 
cornpany. 
Il 
linois tiaLural
Survey
,)ohn 
i,liley
and 
R.t,l.
Annual lieport
Hi 
story
t
I
I
I
I
t
t
I
Liehr-stor:ck, 
s. 
.l980. 
coffeen 
Lake 
water 
quality,. 
In 
J.A. Tranquilli 
arrd
!.ri,. 
-Larirnore, 
eds. 
, 
Environmental 
Studi'es 
of-CofT-een 
Lake: ieconO 
nnnuaf
' 
fl9n9.t 
to 
Central Il 
I 
inojs 
Publ 
ic Service 
Ccrnpany. 
Il 
I inois 
Natur.al 
. 
.,
l{i 
s 
tory 
Survey.
Park,.P.K. 
.1969. 
0ce1n c02 
systenr: 
An 
cvaluation 
of ten 
rnethorls 
of
investigation. 
Linrno 
l. 0ce.rnogr. 
i4:119,
.', 
,,1.
Pomeroy, 
: 
Science:131:1731-1732. 
L.R. 
.l?60. 
Residence 
time 
' 
of 
: 
rlissolved plrosphaLe 
: 
irr 
naLur.dl 
:  
,
waters.
Riglea, 
, 
, 
Li 
mno 
F.H. 
l ogy 
'' 
lsJ!, 
263-?7 
-!!osphorus 
3. 
cycling 
. 
:: 
in 
lakes. 
:- 
In 
F. 
[luther., 
Funrlarnent]ats:of
-
I 
1,.
T
I 
.
:
I
I
i
I
.. 
:':                                                                                
I
3.36
sotso,ql-l:l.!yl{l, 
fteport 
1". 
lg!!, 
r.97t 
, 
l1 
[e+1o9y 
'{,1n.",uttanrs 
r, 
tnc. 
'. Inrr-;.r.:.rl
oemons[ratlonpur5Uantto..,Jllinoisl'olTJt-icin{]onil,':lB+ar.Jt,u|esart,J
l!sulations, 
Centrol 
tllj.nois,public 
Servir_e 
li:,np,iny.,-iofir,r,n 
po"r,i'
]:..Stalion,..unit5.lanr|?,Hay3.|,|g77,-
Stanrlard 
lrtethoris. 
f or 
the 
Examinat 
ion 
of 
'daler 
cnrl
.rynerican 
Puhl 
ic. l{ealth 
Ass'sciation, 
Aner icrrn
,', 
l.lash 
i ngton, 
0C 
. 
874 
pp.
lJatf 
ewater 
, 
I 
4Llt 
rrl, 
197 
6 .
i.later 
'r'lorks 
Astor; 
iat 
itin,
I'letzel, 
R.G, 
1975. 
Limnology. 
l,J,B. 
Saunrlers 
Conrpony. Phila6elpiria. 
/,11 
pp.
.: 
.:'
3. 37
t-=-
il-' 
:
tl, 
t-=, 
''
I
' 
SECTI0ll 
il
Cllil'l 
I CAL,C0ll5T 
ITLtl,lt 
I5
ul
h'Y
. ':: 
,' . 
, 
,., 
Susanne 
G. 
l.lood 
'and 
Teresa 
A. Schu 
l 
ler 
i'  
,"
ABST 
RAC 1
A, 
three-year stutiy 
of the 
chemical c'onstituents 
presenl 
in 
Coffeen Lake 
was 
'.
undertaken 
as 
part 
of 
a 
multi-disciplinary 
3-year investigati0n 
t0 
evaluate 
" 
.
the 
enviionnrental effects 
of CIPS Coffeen Power 
Statjon 
on 
Coffeen Lake. 
Major
changes 
in the disposal of 
coal combust'ion wastes and the discharge of 
waste-
water 
at 
the 
povrer 
plant 
were irnplemented 
between 
l4arch 
l97B 
and 
llovcrnber'1979
for 
the 
purpose 
of 
reducing the amount.rf 
pollutants 
eriterirrg the lake. The
major obiective 
of thjs study 
was to 
determine 
how effective 
these changes 
wer-C.
f,later, 
sediments, sediment 
cortss, two species 
of macrophyes, 
dncl'six 
species 
'
of fishes 
were analyzed 
for thei r contents,:of 
chemical consti 
tuents.
The 
concentrations 
of chemical 
constituents that sornetimes accurnulate 
to 
unde-
sirable 
levels 
in 
aquatic 
ecosystems 
(Cd, 
Cr, llg, Pb, and Se) 
were corrsidercd 
to
,be 
of 
pat'amount'importance. 
Pb 
concentrations 
were Lrelow 
the 
detection 
linrit 
of
the analytical'irrstrutnent for most of the samples. 
0f 
the 
four:ecosystem 
con-,
ponents 
showing measurable Pb concentrations 
cluring 
the first 
year (pondrveed 
an,l
three species 
of fish), on'ly one fish 
species 
conLajnecl 
measurable 
aruounts. during
the second 
year. 
None of the ecosystem cornponents 
contained measur^ab1e 
levels
of 
Pb 
during the 
final 
year, 
a, 
gratifying 
fin<ling 
when 
improvenent 
in 
environ-'
mental 
quality 
is 
the 
aim.
,, 
.'ln 
the 
present 
,study, 
the 
steady 
decrease 
'in 
Cd concen 
tra t 
ions 
i 
n 
a 1 
I ecosys 
tem
conrponents 
rluring 
the 3-year 
period 
is 
indicative 
of 
improvement in 
environ-
mantal 
quality. 
The 
same 
conclusion 
can 
be 
drawn for 
Cr antJ 
tlg. These 
decreas-
ing trends 
are reflections of similar 
decreases 
in 
the 
surrounding nrilieu.
l,-
1""
!,. 
,.
'.a
I
'l
:.
.,1
t
'l'
l' 
''
T.
. 
:.:
1.,' 
' 
,
I 
'"'
..' 
.:
l 
I''"',
I 
.:
I
'l
There has 
been:,concern 
aboutr,the reported 
,reproductive 
f a,i 
lure 
,in 
f 
ishe.s inhabi 
t-
ing 
lakes 
that 
are 
subject to 
expoiure 
to 
industrial 
wastes. lrr 
the 
piesent,t'
study, the 
annual 
nrean 
concentrations 
of 
Se in six 
species 
of 
fish 
taken 
Frorn
,: 
::; 
:,
. 
a: 
'.:a:a,: 
:
4.1
rr':::
j:::
cof 
feen 
Lake 
between' 
lg/B 
and 
lg8l ra'nge,J 
from less 
lhan ilrr.r 
rierccLion 
l inr.it of
the analytical 
instrument 
(0.29 
pfrn) 
to 
1.B9 
ppn. 
All of 
these 
levels are 
well
within 
the 
range 
of 
concentrations 
(0.5-i,0 
pm) 
repcrted 
for fishes 
frcrl
another 
lake 
wherc 
fish 
reproduction 
was 
norrnal. Ihus, 
thc 
reproducljvc 
:,urcers
of 
fishes in 
coffeen 
Lake should 
not 
be 
affected 
by 
5e 
at 
the 
presen[.
The 
overall 
conclusion 
for 
this 
3-year 
study 
of 
the clrenrical 
conslituents 
in
Coffeen 
Lake might 
best 
be stated 
as: 
improvanents 
in 
the disposal 
of 
the 
coal
cotnbustion 
wastes and 
the discharge 
of 
the wastewater 
generaterl 
by the 
power
'plant 
have ied 
to a 
s.ignificant improvement 
i'n 
the 
unuironnun*, 
nruiiry 
or 
lru
I 
ake' s 
ecosystem.
I
I
t
I
t
t
I
I
I
I
I
I 
: 
]::
T
I
I
I
:.
:.
:.:
: 
.l::.
:..::.
l.'
4,2
.-;:;:
t 
:.:,
-.,
I.
' 
-lt: 
:
l.
'I
t:
.:..:
a"r 
: 
,.
I.
-l
,::,r,:
!,
r
I.
a-
-,
I:
::a'a.::
::-:i.
-:
IT:
:1:-;::i
:t: 
'                                           
:l: 
l
t,, 
' 
::;
'--' 
j 
:        
:.   
:..,
-',
-'i
i    
: 
lliiftI--:0ucl 
l0li            
, 
'
::
The 
neerl 
for large 
quantities 
of 
waLci 
to caoJ 
etea$ 
in 
i:lecLric-qeficr*?.j,t!
statjonS 
has 
resulted 
in 
constructiorr 
of 
nlany 
lal:cs 
in re{cnt yeaf5. 
',.lhen 
Lhe
j.'...
generating 
stations 
dsSociated 
with 
these 
latres are 
fucied 
vdith 
{odl, csrbustion'
wastes 
are 
a 
source 
of 
trace 
metdl 
c0ntamination 
t0 
boLh 
the latres 
an<! 
the
surroundjng 
ldnds. 
'Coffeen 
Lal,e, 
which was 
bui lt in 
i963 
to 
provide 
wate'r 
for ',
Central 
Il'linois 
Public 
Service 
Conpany's.Cof 
feen.Power Plant, 
is one 
such''lake,l
Because 
little 
outflotr 
nonnally 
occurs, 
this lake retains 
almost all 
of 
the 
,
i.hemical 
constjtuents 
entering 
by 
means 
ot': both 
the 
thermal effluent 
frcm 
the
Power 
plant 
and 
the 
inflowing 
waterfroin 
the'lake's:watershed. 
Loss of 
water 
'
from 
the lake via 
evaporation 
concentrates 
the chemjcal constituenLs. 
Dressen
eta,|'(l9i7}andGriffineta.|'(l97B)<lemonstratedthatnanymetalsin.s.la9
.:
and 
fly ash - 
waste 
products 
of burned 
coal 
- 
have substantial 
solubjlities when
leached 
by water. 
Sjnce 
these leachates 
entered Coffeen 
Lake 
frorn 
1965 
to
1,978, enhalcemelt 
of 
the lake's chemicaJ 
constituent 
conLent 
and 
concoritant
deter:ioration 
of i 
ts, 
water 
qual 
i ty were distjnct 
possitri 
I i ti 
es. 
- 
l
,.fvl6j6l.changes 
in 
thc 
disposal of 
coal combustion vrastes and 
the dischlrge 
of
wastewater at 
the 
Coffeen 
Ponel 
Plant, 
which 
were 
nrade 
betryealr 
l4arch 
l97B and
November 
1979, 
great'ly 
reduced 
the 
anrount 
of 
pollutants 
entering 
Coffeen,Lake,
Because of these 
changes, the overal'l 
qual'ity 
of 
Lhe lake's 
water, 
sedinrents,
and biota 
may 
have 
begun 
to improve,. In 
particular, 
concentrations 
of chsnical
, 
constituentslin sedinrents 
and biota 
rnay 
have begun 
to 
clecljne. 
Thus, 
the 
objec.
tives of this study 
were twofold: 
(l) 
to deterrnine 
concentrations 
of 
cher,rjcal
constituents in selected components of 
the lake's 
ecosystem during 
the 
Lime dis-
posal 
of combustion wastes and wastewater 
was irnprovecl, 
ancl 
(2) 
to assess 
the
recovery 
of the lake 
by 
tnoniloting 
changes 
in concentrations 
of 
cheinical 
con-
stituents cluring the 
following two 
years. 
The first objective 
was 
addressed
'between 
September 
and ,lune 
Lglg, the 
results 
of vrhich 
r.Jere reported 
by 
Smith 
and
Duda 
(1979). 
The 
second report 
analyzed 
and 
interpretecl 
data 
coliecterJ fronr
,'.'July 
i979 to,June 
1980, i.e,, 
the 
first 
year 
of 
recovery 
of 
the lake 
follovling:-
modifications 
of 
the 
combustion waste disposal 
and 
the 
wastewater 
discharge 
into
t.'the 
,lake 
(Anderson 
-et 
al. 
.19S0). 
The 
preient 
report 
ana'lyzes 
and interprets 
::
the data collected 
from July 
1980 
to December 
1980, i.e., 
the second 
year 
of
4.3
: 
: 
,,. 
.j-. 
| 
:
recotery 
of 
the 
'lake''. 
.Ihis 
report,also 
jntarpt"cts,thB 
rcsul Ls 
of 
the 
3-yeai'
investigatjon 
of 
tlre lake's ccosystem.
Samples 
j 
of water, 
sediment, macrophytes, 
and fishes 
vrere 
andlyzerJ 
for 
silver'
:: 
,. 
i 
:
(Ag),., 
arsenic 
(As), 
boron 
(B), 
bariunt 
(tla), 
calciuru 
(Ca), 
cadniunr 
{Cd), 
chranium
(Cr), 
copper 
(Cu), 
iron 
(Fe), 
nrercury 
(119), 
potassium 
(K), 
rnagnesirrnr 
(l,lg),
manganese 
(Mn), 
sodium 
(Na), 
nickel 
,,(f,li), 
lead 
(Pb) 
, 
selenium 
(Se), 
antj 
z'inc
(Zn)., 
Coal, 
slag, 
,a'nd 
f ly ash samples 
were analyzed for tlr. 
abo'..e 
constituents
plus 
aluminum 
(Al), 
cobalt 
(Co), phosphorus 
(P).'silicon 
(Si), 
and 
titiinium 
(Ti),
Water' 
r*as 
also 
analyzed for 
cyani'de.(Ct'I. 
) 
,    
'.
CTUDY 
J I 
VU 
I  
AREA
arllLrr
The 
Coffeen Power Plant 
is a 945-H|.J 
generating 
station 
located in southeastern
Montgonery 
County of central Illinojs, The 
first unif 
(350-l'ltl) 
began 
generating
electricity 
for corunercial consumption 
jn 
1965, 
and, 
the second unjt''(595-MI,l) went
on 
line 
in 
1972. Fuel 
burned at this 
facility 
is'primarjly 
Nurrrber G coal 
that
.isobtainedfromashaftmjne(Consoll1i]lsboroMine)locate<lac|jacenttothe
plant. 
Number 
6 
(Herrin) 
coal 
is 
fhe 
most 
extensi'vely 
rnined 
coal 
in 
I 
ll 
jnoi 
s 
l
(Ruc.hetal.1971).Thep1antconsunted2.0Bmil]iontonsofhigh.su.lfur(3'.4
percent) 
Number 6 coal and 
2.21 
mjllion 
tons 
of 
total:coal 
in 
1978:(Lin and
Dotter 
1979). 
Coal 
burned 
in the 
Coffeen 
Plant is reduced 
to approximately 23
percent 
of its original 
nrass; 
about 70 
percent 
of 
the 
residue 
is slag 
(bottcnr
ash)..andtheremainderisf1yash(JanetKennedy'pers.conn').Thef1yashis
removed 
fronr 
thersnroke 
by electrostatic 
precipitators. 
From 1965 
to 1978, 
the 
i,
:::
slag.and 
fly ash were 
sluiced 
to 
an'area 
located to the east of the'power 
plant 
.
and:in close 
proxim'ity,to 
the east 
(heated) 
arnr of 
the 
lake. 
Leachates in 
the
returned 
sluice 
water entered 
the lake unabated near 
the 
thermal discharge.
Because 
of changes 
beginning 
jn 
March 
1978 
and completed 
in 
Novemb'er 1979, 
the
slag'-'is 
now 
dewatered 
in 
bins 
and:then transported'by 
truck 
to 
a slag 
storage 
,',.
area 
(formerly 
the 
slag 
pond), 
and fly ash is 
accurltulated in 
a 
silo ancl 
then
trucked 
several 
mi'les to 
an approved 
landfill site'.                
.:.
T
I
I
t
T
I
I
T
t
t
I
I
l,
I
t 
'
T
a man-made 
impoundment 
with 420 ha,'of surface 
area, and 
a 
water           
t
.'...:...
.1,, 
x 10/ 
mJ. 
For 
a 
' 
nrore 
:-. 
detailed 
description 
, 
, 
of the,.rnorpho-
1::1
,tl. 
t,, 
.        
' 
'..a 
, 
'., 
:i
4.4
I
t,
I
l 
- 
:.
I
,l
t',
I
:
I
,l
,.,]'
,l
:,
,I
.''.
I
:l
'l
logical 
chardcteristics 
of 
the lakc, 
the reader is refen'ed 
to 
Sccticn I
of 
this 
docunent. 
ln accordance 
witlr 
tlre 
interdiscipl 
inary approach 
to
conducting 
investigations 
at the lake, four majo!'sarrrplin{] 
siat'ions 
vrera,
estal 
ished 
by mutual 
agrecment 
with other 
researchers. 
StaLir.,ri 
I rvas 
iocdLed
in 
the 
thenna) discharfe 
ann, 
Stdtion 
2 
yras 
est(rbl 
j 
shed 
near 
the 
r,ridpoint 
of 
the
cooling 
loop, Station 
3 
lvas 
situate'd'north 
of 
the 
intak.e 
bay 
alr<J is consjdered 
a
transition 
zone, 
and 
Station 4 
was located 
north of thr railroao 
cduseway'and 
is'
regarded 
as 
the ambient 
area 
(Fig. 
1.2). In 
addition, ancillary 
stations vrere
nrJ'3 
for 
scne 
aspecLs 
of
this 
stud.v; 
these 
were designated 
Statjon 
1,5 and 
Sration 
2.5, respectively.
"
Materials and 
methods 
for this study:wera 
nodified foliowinq 
the 
first 
year 
of
investigation. 
The 
four 
maior 
sfations 
reoajned 
the same throughcut 
the 
sturly's
duration, 
but two ancillary 
stations,1.5 
and 
2.5 
(see 
Fig. 
l;2), werc added
during 
lhe 
second 
and 
thjrd 
years 
of"study. 
0ther minop 
changes inclutjecli 
(l)
reducing 
the collection 
of 
water samples 
to 
once 
a nronth, 
(2) 
elinrinatingrthe
fjltering 
of 
the water sarples, 
(3) 
discontinuing 
the cyanide analysls 
following
the June 
l9B0 water collection, 
(4) 
adding 
three'spec.ies of fish 
during 
the
third 
year 
of study, 
(5) 
obtaining 
a 
nrore 
thorough 
collection of nracrophytes
during the 
second 
and 
third 
years 
of 
investjgaLion, 
(6) 
collecting ancl analyzing
sedirnent core samples 
in 
the 
third 
year, (i) 
collecting and analyzing 
coal,
slag, and fly 
ash samples from 0ctober 
1980 through 
February 
1981, 
(B) 
con-
ducting 
Na 
and 
K analyses by enlission 
spectrophotonretry, 
and 
(9) 
nroclifying 
the..l
thi 
r<J 
year.
SMPLE 
COLLECTI 
ON
Table 4.1 
lists 
the total nunrber of samples 
collected for 
the chernjcal
constituents 
portion 
of 
this study 
frorn Septernber 
1978'.through 
l'|ay,.l9B1. 
'' 
hlatct",
samples were collected 
daily 
"during 
one 
week each in Septenrt,'r 
and 0ctober 
1978.
Duplicate unfiltered and 
filtered 
(0.45-micron) 
vtater 
sarnplcs 
were 
collectecl
monthly from 
Novernber 
1978 through June i979. 
Quadruplicatc 
unfjltered 
rvater
samples were collected monthly fronr July 
1979 
through 
Decerrrber 
1980, All 
water
4.5
a... 
''r:.
: 
.;
: 
:   
' 
I       
:,.
Tabl,e 
4. 
1 . 
Tota 
l, nurnber
: 
. 
constituents
:,
of 
sanrp'.ies.col 
lecterl,:and 
.tn,Jiyred 
f 
or chen 
jcal
frorn 
September 
197[J 
i,hr.ourltr 
.].rly 
l9Bl,
'l
I
I
r 
978-79
't9 
I
79- 
B0      
tq*0-8t    
Tolal,by,:lype
l{a 
ter
/.rl-
t, ll
Macrophyte 
s
--___-
A.mer 
lcan 
Pondweed
C''cep 
inq l,laterpr 
i 
mrose
Sed 
iment
330
120
I
t
1
B
50
33
t6
tB?.
96
oA
6il8
?48
(5
35
6B
t)
2l
30
v
ll
JIJ
Fish 
,:
, 
La'rgemouth 
Bass
:
:, 
6i 
zzard Shad
.
, 
Bl 
ack BuI 
Ihead
Car 
p
' 
Bluegill
: Channel 
Catfish
Cores
,coil-
Fly 
nsn
Yearly 
Totals
Grand,Total
40
40
20
40
40
t2
2A
?0
20
30
20
3?
30
453
r30
il3
.:i
4B
:
20
?0
20
30
.20
:
,30
56t          
428
1 
,447
4.6
I
I
I
I
I
I
t
samples col 
leCLt:d fOr 
chenicai con:tituent r:rr,ri;',ii; 
i;i:i'i ,lirl;-,r;l t;i'iert' 
:.lmi:le:
and we re 
preserved 
with 
rtitric 
a|i rJ 
i0.iji 
f 
iriir I 
i':",:.q', 
f 
r',tt'ii r:;. 
r,ltllr' 
:rr;:tl,ie:
fOr.=Cyanide 
(Cl|-) 
analySi5'dere 
Z,liler 
5y1-f,3r--11 
Sitrlijrlei 
r-*iiti,lilj 
i:-r .: ,. 
'ri.tte
lrorn 
Septenber 
l97B through.]une 1979 and 
1;r^eir:r'verj 
uiilr 
,,crjl.-r:'- 
i;-,,dr"+r. 
i')r 
'..;.?.
final 
concentration). All 
salripies 
for rjicrlsurel0(:fri-i, 
{,f 
iili.:::ii,1 i 
c,lr,rLltL;rlri1
were|efri:::1.-1.untilana-ly:ad;.:aix|]e5l*rc.viltii;j8.1t:!.€r'lr'i:iiLj0l.iwi:t.t
ana1yzedwithin24hoursafterco'ilect.ion,
Bottorn 
serlintent 
sanples were collacted ir, tha 
falI 
af i978 
at 
the 
four 
rr;aji:r'
stations 
(Fig. 
1.2). llrring spring 
an,J 
f al I of lrij.ii, 
b0ttcn sr-^dinrr,nI 
salnpies
r,rere 
collected at the 
four 
major anrj Lhe 
t''/c 
dncil).rry 
staiiorrs 
itig. 
i.;i]. 
A
15,2-cm x 
15,Z-cn x 15,2-cm 
Eknan drecJge wjih a 
chaniller 
volunre 
of 
i540 
*,3 
was
used to col 
lect sedimqnt 
frorn 
tlre 
lahe botLom; 
the Loli 
? crn 
c{ 
nrat.c.ri.r 
I wer'e
retained for 
analysis, 
Shore line sanrplcs 
cofrtaininr.; 
trinrari 
ly 
sand 
vtere
disallowed during 
the final tvro 
yedrs 
of 
the 
sLurty. 
All 
srmples r,rere 
fr'0ren
un 
ti 
I 
prepdred 
for ana 
lys i s ,
.
The 
species 
and 
numbers 
af 
macrophyLe 
sampies collecte<l 
Flel 
year 
dre 
givc.n 
in
Table 
4.1. 
Creeping waterprjmrose 
(Ju-s_s_g_qa 
.LqIg$,) 
vra, 
co'llccted 
dt Str!'r'ons
1, 2, and 
4 
in 
September 1978, 
at all four 
inajor 
stations 
.in 
Sr" 
itefl;ber 
1979, 
and
at 
al I four 
rnajor an<l 
the 
tvro anci'llary stalions in Septerlbcr' 
l9ll0. 
l,io
waterprimrose 
rvas 
found 
at Station 
3 tlurinS 
Lhe 
i97B 
colleutiorr 
period.
Anerican 
pondweed 
(Potanrogeton 
ry-{gs-qs) 
was 
collected at, only Station 3 
in
September 1978, 
at 
Stations 
2,3, and 4 in SepLeniber 
1979, 
and 
at 
Srdtions 
2,3,
and 
4 and the 
two 
ancjllary stations 
in 
Selltember 1'980. This 
macrophyle 
was
not found at 
Station I during 
any of 
the 
collecting 
periods. 
The 
sarnples 
were
stored in,polyethylene 
bags urider 
refrigeration 
until 
prepared 
for'analysis,
Species of 
fish collected 
for 
this 
st,udy 
inclurJed: 
gizzard 
shad 
(Dprulg1g
cepedianunr), 
a forage 
fish; 
black,bullhead 
(tctaluigs- 
ntelas), 
a low trophic
level omnbVoie; 
and laigeinouth 
hiass 
(l4jclgrle_t"q,s_ 
_g_l!Ul_d3_t), 
a 
higlt'trophic
level 
carnivore. 
,ln 
addition 
to 
the above 
speciesr, tha 
following 
fishes were
collected 
during the 
third 
year 
of 
the 
study: 
carp 
(lpf11uf 
-c-ajpl-g.), 
a low
trophic 
level 
oinivore; 
bluegill 
(Lep-omtt 
rullqdfrutj";;;tl;0il 
ono 
channel
:''a            
::                                                      
, 
: 
i
,l
t
:l
'
T
I
'l
I
I
I
q.7
ii'i 
rlr::=';
:: 
.' .r::, 
,'
:;,,t 
r',;,
.:i.:.a'':                                                                                
I
T
I
Cdtf 
i5h 
i 
k_t{lU_':J.3 
lijlilila-trtr,. 
'r 
loyr 
',-rr-)l)n:i: 
ir.yr, I 
}:r 
:, 
,-i,. 
',.f 
: 
,r-1iir.i,t , 
.;r
th€ 
..=.
f 
islre: Here, 
col 
lecte:J 
by 
elee lra;'ishinrj- l,rl;ir-' 
i.I 
i:,.j,t,, 
..i\,i:i 
! 
irtrr.., 
:,-,.
SpgcieSranrJ 
nunliel' 
coll*ctcd 
iier 
/ear'+i 
litr: 
tnr{-.,,ii,'lnl-': 
.r!":. 
.:.,:,i 
r...;t,.rrr-r'i'i 
: 
l
::
the 
date and 
point 
of 
col lcct,iqn dre 
tjrr: 
s{-:ritec 
:rr 
i,il;lr 
.i,.:. ,i:i 
! r',r;t.-,. 
i{ir!'i.f
5'L$red 
fIozcn 
unlll 
praparerl 
for 
anii.yiis. 
'    
: 
,,'
Sedintertt 
cores we re 
collectsdrin 
June 
19i::0 
u.iing 
d 
c0rcl' 
:norJeileri 
irf 
Ler'liilrles*-
Ba'llchek 
Sinqle Tube 
Cqre Sanipler 
l4odel 
2ill 
rvi th 
3-$-slr-didircLr-,r' 
5y 6l-r,ir- 
icng.
plastic 
col 
laction 
tubes dnrJ 5 llg 
of 
counLer!,rlighls 
iFiq. 
,t.l 
, 
. Ttre sarrrgles 
yrsre
co'lecled 
by 
means 
of 
a 
winch anrl 
pulley 
system 
rnounted 
cn 
a 
porrahrle 
l;cat 
crarre
wi".h 
a 
6-foot 
hourr. 
Iive 
santples 
per 
sLatisn were 
calleci.ed alorrg 
tran5ects 
at
Stations 
I, 
1.5, 2, 
2.5,3, 
and 
4. The 
tubcs were 
lrbelc<t. 
corl:ed, drrcl 
frozen
un 
tr I 
prepared 
for 
ana 
lys 
i 
s,
Coal 
, 
slag, arttl 
f ly ash 
samples 
vrere col 
lected 
f 
rom 
0ctobcr, 
17, 
l9B0 Lhrougti
Febt'uary 
2l, lg8l. 
Coal santples 
wc.re 
taken 
frun 
conveyor 
belts cltering,the 
'
power 
plant, 
slag 
from 
the dewaterjng 
bins, an<l f 
ly aslr fisn 
thc',f ly aslr'silo. 
i 
'
Col lections were 
made 
by 
CIPS 
personnel 
from 
zero to 
[hree 
t-inres 
per 
r.reett
during 
tlte above-mentioned 
periocl. 
Sanrples vicre 
individual 
ly 
storcd in 
scolr.,d
po.|.yethy.|enebagsuntiiprepar.edforanalysis,
','
SAI4PLI 
PREPARATI 
OI.I 
I'
lhe 
water satnpleS required no additional 
preparati0n 
prior'to 
analysis.', 
'.,,. 
,',1
Sedinrent satnples were freed of 
excess water 
by 
decantation; 
the sanples 
wcre     
I
then 
placed 
in 150- or 300-rnl Virtis bottles 
and freeze-clried. 
The freeze-dryer 
I
used 
in 
sample 
preparat'ion 
was a 
Virtis 
Unitrap 
i0-100 with 
a l.telch 
Duo-Seal 
t
Moclel 
iil402 vacuunl 
puntp. 
The sediment cores 
werc spliL 
iengthwise 
and 
sectioned
into 
six 
3-to-B-cm segments, representing 
recent sedinrent, 
four interrnediate 
I
sedimentation deposits, and an 
origina.l 
sediment. The seqments 
yrere 
thelt
iieeie-aried 
'as'above.- 
A'nibrtaF arrd: 
oer
pestlo 
was 
uSeid- to 
grjnd 
and-lronogen]ze 
- 
the sedirnent 
t:: 
and''sediment 
:
core'sample'i. sufficiontl.y 
to 
pass 
a 
1O0-nresh 
1y1on 
,'
I
sieve. 
For 
ntacrophytes, a 
thorough 
washing with 
tap 
water-ren,oved nrud 
and 
other
ex'traneous 
naterial. 
fhe sanples 
were rinsed 
several 
t'imes wjth 
deionjzed
:'.,                
, 
,:,                                                                                
i
waier 
and,:'thoroughly 
diainedi,,ghg 
leaves and 
stenrs were 
separated,' weighecl,
,.: 
.. 
i.
4.8
il
.T
I
t
T
I
I
.T
,l
I
:l
.l
't
..' 
.:
'l
-::l
I
I
I
I
I
Iable 
4,2. 
Cr:llee 
llon 
rtate, 
i*1lr::?trirl 
pti:1.-! 
* 
i:,;r,!;;r,
: 
{)hl 
a i 
nq:El 
f 
ro{ 
Cr; 
f {eeir 
:,-t 
i:€ 
.
0ate 
Col 
lecterj
i.if i 
Ir'r? 
ii:fi 
tir,it,r 
..
5t at. 
i 
*r: 
!        
5l 
at 
ir,:ri 
?
','i 
if 
i 
rr1 
1
i,i;l 
ii:n
t
T
t
I
I
I
' 
ll78- 
l 
97e-
0etober 
l97B
.f{o'rernber 
l97B
March 
I 979
,rel9:l 
iqQ
Novernber 
'1979
January 
l 
9B0 
,
March 
I 980
I 
980-t 9Bl '
May 
1 980
September 
l9B0
November 
I 
980
4 
'Ll4u
5 
SHAO
5 LI4B
IO 
LMB
IO SHAD
I BLKBIJ
,3 
BLKBLI
I BLKBH
l0.tMB
IO SHAD
5 CARP
5 
BGILL
5 CCAT
5 
Lr4ti
6 
5|fAS.
2 BLKBi!
l0 
Ll,lB 
.
l0 
5ttA0 
,
2 
llLXBtl
3 
BLKBH
IO LMB
IO SHAD
1 
BLKBH
5.CARP 
.
5 
EGItL
5 CCAT
5 
Lflii
5 SliAii
5 
Sl{A3
5 
ftLKgr{
IO 
LMB.
r0 
SHA|
4 
llLKBl.{
l0 
LMU
I 
O SHAD
I 
BLKBH
5 CARP
5 
BGILL
5 CCAT
2[r 
L 
t4tl
& 
:;iiA'J
'i 
gi 
l,titl
5 
Lf.lB
5 
SiJAtr
5 BLKB}I
l0 Lf'tB
l0 
5t{Ac
6 
SLKSrj
I 
O 
BLKBH
l0 silA0
iO LMB
5 
CARP
5 
BGILL
5 
CCAT
-LMB 
= 
Largemouth 
Bass, 
SHAD 
= 
Giizarcl Shact, 
BLKBIJ 
= 
Ulack 
Bullhead, 
CARP 
= 
Carp,
BGILL=Bluegi.!l'CCAT=Channe]..Catfish.::
:-.'1, 
I
-
i 
tl
:,,,.,
t
I
!;;':
i
4.s
..a.: 
ra 
' 
.
I
I
I
I
I
t
I
!
I
t
I
l 
J
a
'i
'I
:i
''=l
:l
!
{
. 
'_:f:!P:.'ir'^ 
::I
. 
:l
,t
,  
rl
:.,
I 
:
:l
T
T
I
I
I
!
I
'l
I
l-'
. 
t.ii"
l-=
1",
I::'
I::
I:':
-:
and 
f 
f0czt-,-drig.:j 
ln 
,il'l:i\j1:tt:. 
t,:i'l 
i'jd:,..  
,,,t:i 
: 
,-t..     
, 
t,, 
.r..r. 
,t 
'':t.
itrvastigation, lenf 
altd 
tLi::!i !'tii;rlt?'j Hr:r"{. 
l,rr',,,:., 
,,.t 
i,i 
; 
,: 
.:,, 
,.r.;3 1,..
iitrji.v'idua]}7irrta;ic;;,11i1.;;e!jEhJt,'di!il.r;,.1.Jl!l:r:,1ir''}:iil'lj.i].ilr..:Jlii..?':
mdnipulatinq 
lry 
iiand. 
[r.iri611 
llir. 
riii]',r 
.i.'.1'- 
:': 
i]r. 
1: ,,ti, 
..r,i;:.,, 
ri,,!.!r 
i..t 
,, 
1
ln 
-polystyrcne'. 
litlttig:  wiLti 
ie';t,r'rtl 
i..i.r<.ti{- 
irr}*:irt 
,rr=i,: l,i:.-i.;:,.rrr 
/r-.-t 
,',i:;r: 
J 
-=i:Br 
,
fJCt0'J'll rni;ter/ntil.   
l'isri 
i{t:re 
ttrowtrjr 
:i_i
il}r.,d!:j,'rr'l 
,irjl:jtt: , 
riirl 
r{.:,1,1..1 
. 
,i 
r 
iljet
(muscle 
tissuei ir,ts 
rein0vprj 
frcsn 
earh 
f 
iih 
iiler:i.',(rri, 
iui 
i,,,;,.:-rlrr,r,,. 
i, 
l;rcr..l 
rr:
plastiC 
rcighiltg 
ba*ls, 
and 
i,hen 
frer:re-.lr'ic,,J. 
ihr: 
!rt:rille l.::.rnr'igr.:rii,l,lr-',ori
proceclure 
duplrcate,J 
thof 
of 
11.,s 
lrdclcpirytes, 
irl l 
J r.,-,rzc-4rir,rj 
.,;r:;,.ii:s 
wflfE
LoierJ 
in 
pOlyethylenr-i 
tioltlcs 
at 
r0rr:r 
tei:iucr',if 
rrr'r, 
,,rrlLil 
*li.ruL,t9 i{Fli1 
nte{jrjrJ
ror. rligestion.
Coal, slag, and 
fly 
ash 
sanples were 
nir-dr'jerl. 
ecrnblr':erl 
b1 
l.;rpe, and Lhen 
r,
sorted by means 
of 
a riffie 
to obtain reirr'esenlative 
ruLisanples l-cr.anaJ;ti,-s.
Four 
subsantpl 
es 
of edch type wet'c 
prep,rrccl 
L{r 
re 
prescn 
t 
i-he 
f nrir 
orru-r'lont h
perio<ls 
(0ctobcr 
17, l9fj0-tlovcmber 15, 
l9B0; 
Novernber 
l{r, lgti0-Uecenber 
15,
l9B0; Decernber 
16, i9ll0-Janua,'y 
tS, 
igBl; 
,rnrJ 
January 
16, 
lgtjl-l'uhrrraly ?i,
lg8l 
) 
of Lhis subpro.iecL. 
Tltese 
fou:' 
subsatnples 
of 
etclr type werc 
qraurtrt 
'.*o
tncet 
[he specifications 
for 
analysis 
of 
thc Illjrrois SLdLe 
G*oloili,.,il 
5ur'vey.
SAI4PLIDIGISTION 
: 
. 
:  
:]        
: 
.
All.sarnplesweredigestedandanalyzed.in<lup|icaLet'hroughouttlrestudy'Tlre
vrater samples required digestion only for 
rnercury 
(llg) 
analysis. PoLassiurr
persul 
fate 
(K2S20g) 
solution t,lds 
aclderl 
to 
the sanrples 
to 
f ree 
arry llg 
thaL
was 
adsorbed 
on 
particu'late 
matter in 
the watcr 
(il-Awarly 
eL 
dl, 
1976). Af 
ter
one'. hour, the samples 
r{ere analyzed for 
}lg 
as 
descnilled below. 
The
deterrninatjon,of total CN- 
in 
vrater'samples 
fronr Septernber 
lgTB 
through 
June 
:
l9B0 
vras 
perforrned 
accorc.ling 
t,o the 
U.S. EPA 
standarri 
rncLhorl 
(Kopp 
ant l.lcKee
LgTg), ihe 
cyanide was 
released in the fontr 
ol' hydrogen 
cy{lridr.: 
(t{CN) 
fronr 
the
a
the
r-,
I::-:i:
I:::
I:
-.
t'-
I,
I.,
l=
I,'
t
E
: 
:.:..
I
l,::
I.r
I:',
:'
I.
t:: 
,
I..
I.:
f.
-t,
I
:::.
I
I
Il
l- 
r,
I.
Hater-by-reflux--distillation 
chloride',(Fig',4.2). 
The cyanide 
in the-presence 
as 
the cyanide 
of 
srJlfurjc 
ion.was 
acid 
then obsorbed 
and 
coDper
in
scrubber 
containing sodium 
hydroxide. 
Cyanicle standards 
were 
treatcd 
in
.:        
.. 
,: 
t 
::
sanre 
-, 
:. 
manner,
:: 
:
... 
, 
: 
,
:.                        
l
- 
4.11
c0fi.tr{ff 
ilHtn
ll{[t 
I IiJBt 
*
lltllt[ 
*
SCetif 
ctAHP
'I
I
,I0 
l.{}tt 
VtCUUll
,   
$0uRct
' 
lBson8[R
1 
0tsIil.t 
llt0, 
tLAs|(
IH
0ut
"l
-'l
.'l,l', 
t,,,
,' 
'.1'
' 
''l
t;;.;','
' 
:j.    
:
"I
::r. 
"' 
l'
,
: 
'-l
:'j 
'.
"l
., 
.....
l
T
....:.
'l
'-'l
--t
:1_
I
,' 
..1
: .:: ::
c0rt0il{stR
-'-l
Figure 4.2.
.:'
Diagram of 
distillation 
apparatus
frorn 
water 
samples.
r: 
'
used 
for 
recovering 
cyanide
4.12
,' 
, ,-il-i::
'''. 
:':.':
Il,:
I::'r'
Ir, 
j
:,a
l,r.,
I:','
:'. .'
l,
f 
.: 
i.:
l' 
'"
I
I
t
I
I
I
I
,l
I
I
I
I
3he 
*aLt+= 
9ef 
irec 
t: 
;:n,:i 
5!:r":: 
i:-?€; 
!. 
, 
,:r-r, 
..,1-'; 
i 
; 
' 
, 
,
ilorl'>tituetrl 
drn}ySii rigirt* { 
;::*-'jiIt'a1 
1!'rtr 
i-, 
:,r,
f'ertln-[ir+*' 
ii'l;L,.  
,1 
,jll,itl 
ir,'j 
.it\:t:.., 
f 
r,;:'
(ti75*4i 
acrd;'nd,. a,-rdrd 
t* 
:,-': 
.:cr':;ilr.,:'rr:
trthff 
tO Qr l?'dc i 
Orr 
I 
7 
tlrv 
r 
a 
1i;:J1 
i 
441rr;'l,r'ri
lrntfllt 
cf the 
'ledlF{:rit 
i 
i,-.,F} 
f 
. 
ilir: 
sc-i;1+,r
BrrtngxiCl: 
rotar'' 
Shahrtr 
dnd 
iilr:ri 
r:(jf:irltu4r:.j
Tan-nl 
fr] 
i.tuotg 
Of 
ihe sup{:rndtdilt-t nr,rq 
di i
stored in 
polyethyl 
enr: 
b0fi ini 
rlrrt 
i 
'l 
atl I 
y1, 
l
I 
1 
i:r-::l:
. 
.;::,:1
;r'!:':1
,;t 
t?: 
:1+
1:) 
: 
i=f
l-
lxtraction 
of 
iig 
frocn 
the 
Sedi*irjnt5 
Joil 
i€i:i!:;rr. 
l rqrir 
',n.riii,-,,. 
,r.]i, arir;;:i;l 
i!nrr:
usirlt n 
r.r?odjf 
icaLion 
of 
the 
mtrlrarl rie'rcritird 
tr;,. 
Jrrcebs 
,lrrd 
i.{jsrej' 
i 
!,ji 
I 
j. Li:y*
regifl 
(UCt:lttfOr, 
l:l bI vol. 
i 
H.1s aCCar! 
t$ 2-q 
<,11:r1i'l 
i,i 
iri 
z-ti0-:;.! 
w!4r:,ri,{r;i-li
Erlenmeyer 
f 
lasks. 
The 
.,amples 
uL)r'r 
boiltrC 
l,irlrtroul 
j 
/ 
f c' 
ono 
';irrui.r:.
Af 
uer the saml, les 
hdd 
cooled, 
al iquots 
of 
i 
ilorJsTirlr'! 
fJ0ri;iJitri,lnitL(: 
{i1..Ir,0,1 
i
ond 
X2S20g 
solutions 
were 
odtJcrl 
Lo lhr 
f 
larhs, i,.ihich 
rirrr'r-, 
lhf,fi 
trlrrruij 
irr 
tr
qSoC 
nalu" 
bath 
for'30 
minuLes, 
l)rrring 
this 
r1i,;esti(,r) 
i)eriod 
Enall 
iiilal1trlr*s
of 
crystallinc 
lJ'ln0.,t r./er'c 
addet! to the 
531npler 
lrr 
maintair' tr!r 
()r,itjieirr,r
environment. 
The 
sarnples 
were 
coolad 
r 
cafltlifugerl 
, 
diluLeri 
Lo a l:no,*n 
voiirllc
(100 
ml 
), 
an<l 
analyzed within 
a 
few 
horrrs ds dnqcriber! 
belorv.
lcr analyi'e 
nacrophytc 
and f ish'samples for 
chslir:al c0rlsLituents wi 
th tlre
exception 
oF llg, 
a toLal cligest ion 
was 
required. 
/i 
5:l nrixturc 
of 
nitr.ic 
acid
(l{N03) 
and 
per.chloric 
acid 
(llCl04) 
vras addeqJ 
lo 
l-g 
samples wlri:ch 
haiJ been
preweighed 
into 
150-rnl 
round-bottonr 
di 
sti'l lation 
f lasks. The 
f 
lasks rer.e
hea.tedonaKontesRotary.KjeldahlDistjl.|ationApparatusuntiJthel{N03had
decomposed 
(clisappearance 
of rerldish-brown 
funres) 
and rJense 
whi 
Le l.|C104 
funles
appeared. 
Af ter cool 
ing, 
the 
santples 
wcrc 
di 
luted 
Lo arr apgrropriaLa 
volurne 
(25
or 
50 nrl). Thjs 
final 
volume 
was 
zBX, 
12i, and 
5?.with 
respecL 
to 
ltCl04 
con-
centration 
in the 
first, 
second, 
ancl 
third 
years! 
respectively, 
of 
the 
investj-
gl!,ion: 
-The 
macroplryte 
di 
ges 
ts 
were 
cen 
tri f 
uged Lo retnove 
i 
nsol 
ub'le 
s i 
I i c'ates 
.'
;s 
ol 
ved w 
i th t 
ime 
, 
nra k'i ng
I 
centri 
fugation unnecessary.
,l
i; 
':
iI
*
.:,.:,.:-rt1; 
l t:.,1,1. 
..,
,".,;-1:., 
..,:...,i;',.,, 
.',.,.
4.13
iJiqgSli$fiS 
Of 
t-:itCfgtrhytrl 
t1{i t'ifr 
,,C.i:riq,, 
r1_,. 
.r. 
rlf.,,ir 
..., 
,,.,:.. 
.;..: 
,.r..i., 
t-,r.,, 
.
trSint 
d 
nO,Jif 
ifaliOn 
q,1 
ihr: 
*,i'il;r;:! 
ui 
l.iiiii.1*,:,,, 
,i.,) 
.:.-,rr: 
rl 
r.,.. 
,.i:.,,; 
:.i
t{2504, tlf{03, 
dnC 
a 
tr' 
/l!n$.i 
tolrlt.igii 
Acr.(, ,lii:+.j 
| 
1 
. 
--,; 
., 
1:.;.:,, 
r,, 
.,1
If 
lf.ni**yer f 
la:i:s in 
Ar'; 
'iae 
i:rrlli. 
jtf 
l|r :ha;r.:::;{;l: 
.rir1r1.; 
.-, 
,_,.,- 
i. 
rii 
:.,]!r
ten,Lgn 
the 
fln5i1 
htrc tf{i*yg,,i 
fr*rc= 
ir:e 
tf.ii 
ir.rii:. 
ir:l; 
,..r,-; 
.,i. 
_ir:;rld.l,i.,:r,',
of 
ihe 
rcdctiOfi 
usudllT 
ii 
:ilr),Jlr-.! 
ct 
r'6,rl.,, 
ir.'li;r'r-.:t.,,; 
ri, .rlr.;,rii,, 
(rf 
,r 
..r
r*25201. 
solution 
rr-rre 
.]dded 
r-o 
tn* 
liasr,, 
xhrr-r,: 
H,ar,-. 
rrr..,, 
i 
.,r..,,j 
i,-i 
,r 
ibG,.
Hatef 
bath 
fOr 
about 
an 
D-hour 
rti{rs!.}on 
peri*i:. 
l,j::air?cirr 
ar; 
lt:iJt..ir-;it
onvironmenl 
but 
prevent 
ndn?anr:se *isrioe 
for:r.rii*n, 
r=a1i 
.inoiinrl 
*i
C"ygtalllna 
li!1n04'#ore,!dde{t 
to 
ilre 
fiasl, 
co*irrlt,t 
lhrsjJgi-rout 
lfrc dierr.,trdr=
t;:riod. 
ThiS 
periorJ 
yral 
assrJ.T€d 
!.o 
br 
cCIiltllr.tr. 
when 
lht, 
prrr{}le 
r.fi}or. 
(if 
}tir.'lli;
remainedcon9tantfor30mirtutes.1ltesam;ileEwere.oo;Pd,tr'tln5ferrerl
c0tnpletOly 
tO 
100-nrl 
volumelric f ldtl:s, 
arirl 
r.r,f 
rigeratcr.j 
uniii anal,/.rriit 
llre
fol 
lowing 
day.
coal, 
slag, and 
f ly 
ash s.lmples 
wci'e rJigestt'rl 
accor.dinl 
L0 
rrr.oe 
edrlrcr 
out lirreil
in 
Apperrrlix 
C cf 
a repcr.t 
by Ruch 
et al. 
(llll;,
l
ANALYT 
ICAL 
AI{ALYStS
The 
vroter s.rmples. 
sediment 
and scdiment 
corc 
extricts, 
anct rnao.oplryte 
anil fish
digests 
vrere 
analyzed 
for. 
Ag, 
As, 
B, 
Bd. 
Ca, 
Cr!, Cr, 
Cu, 
f 
e, l,lrt 
, 
Mrt, lli, 
ptr, 
Se,
and 
Zn by direct-reading 
emission 
spectrophotometry 
wi 
[h .rn inrJtrcLjve).y-couple6
argon 
radio-frequency plasma 
torch source 
uni 
t 
( 
ICAp). 
The instr.ument 
usect 
was
a 
Jarrel 
I -Ash 
t'loclel 
975 
Pi 
irsma 
AtomComp 
( 
Fig. 
a. 
3 
) 
. The 
rracrophytc 
and f 
.istr
,  
digests 
were 
diiuted 
l:5, 
1:2, and 
0 rluring 
the fir.st, 
second, 
ond'third 
years,
respectively, in 
order 
to bring 
ths l{C104 
concentrrrLion 
[o an analyzable 
lcve]
I 
' 
standards 
of about 5!,. 
which 
:Analysis 
r,Iere run. 
adcuracy 
approximately 
wits 
chccked 
every 
by 
iix 
nreans 
sarnples.
of rlatrix-matc6ed 
, 
"
Sodiun and 
potass 
juln 
in al 
) 
samp'les 
during 
the 
f irst, 
yedr 
of 
the 
sturly rvere 
de-
'  
term'ined 
by 
a+"omic 
emission 
spectrophotornetryron 
an 
tnstrumentatjon 
L.rbor.ato1,y
,1, 
Mode.l, 
253 
Atonlic 
Absorption-Atontic 
tnrission 
Spetrophotonreter 
as clescr 
j 
becl 
in.,, 
,
the Atornic Absorption 
Procerlure 
l4anual 
(lnstrurlcrrtation 
[.aborcrtory, 
Inc. 
lgTZ).
'l
I
T
t
T
I
'l
I
t
I
I
I
I
T
I
I
I
4,14
.r l!r
.l
t
a
I 
t
I
I
I
I
t
I
I
fi
I
t
7
t
I
:
(
&
I 
a
I
u
--
tl
T
a
6
o
2
t
q
t
s
g
6E
o9
8;
E9
yc
<E
oQ
NU
oo
t
t
I
t
+r 
.g
.-(}-, 
ctncra
() 
'- 
t^ 
a)'<
)  
I
{J 
C) 
>rf,i 
F-
.- 
c).
E: 
4J 
rj 
C,
l-rOt:(^L
TJLroCL
6 
crr  
C 
(J^r
,u ru 
L 
u.) 
cr)
If 
'-  
C) 
vl\
-(]tgr 
Ol
:O 
tu 
(r'_
o)-v1) 
(J 
(u
q-Ou1 
'F 
U 
oJ.F-- 
Ec)_C)c
'rF   
3 
Or 
E.-
F.D 
.c 
'lJ 
t,
C).  
C!. 
(J 
r.a 
.-
E!c{
'r  
f,L)rt-   
C.r
(,/) 
rO ts-r 
O 
.- 
Cl
rn
<:l
(U
t-
5
(t)
LJ-
i 
;gEiiiiii;isiiui 
ili,iil 
i'i 
'j;ri
iiiillfililiiilii;iiluiirliiiir
t
T
I
I
T
i:.'
!,
4.15
5At$ll]** 
ner'e 
rJili;LCd |t!}FJt 
li{.rrt'}!14t'l 
'.iril 
j 
i 
!i;r] 1. 
,;q.r'1, 
'il'.r,:i; 
':r- 
i.,.rl:1!*,r' 
,-,i.1':.-.
ol- 
f,i.it*, 
instr'uiieltt. 
l'or 
Lht 
irlrorrC 
,liitj 
ir..ir-<i 
7:.:.rrr 
l;{ 
,.fir- 
.r'r',i..,t 
:-.-,,r 
-i::ir 
fi,r 
.:4..1
F. 
were 
analyzetl 
bl !CirP 
as 
sld?-r:{ ib*vs:
!4crCury 
cOnccrt"raliOnb 
ttErfi 
df 
lor'nined 
blt 
i$ld:y:il){.}r 
ril-(E-ir 
.11,,1,1|ir 
ig,rr
Spectrophotcl{fie 
tt'y 
{f 
ig. 
a.,i). 
Ior 
nar.rophyt{. 
Jrrrl 
f irli 
.j 
t]:r.,,..... 
,r 
I'i-'i 
*lr:l,ir:r.
of the 
dirlested 
5ampl, wds 
tFdfl5ferrr:d 
to 
tht 
rra(ti0rr,,,rgir-,j 
.irrrl d 
lr:,* 
rjr':i,)!
of 
,ltydroxylamine 
hyclrochloritle 
(tll{gSil.l{Cl} 
,,re 
r:e atlt!arl 
r-c 
ra{rcvr 
a&ji
rcfndining 
Kl'1n04. 
Stannous 
clrloriqje 
was 
ad<Jetl 
t0 
rc.rlur-e 
tha 
llg 
t* 
i:,! 
1r,.tror'
forrn 
(llgo), 
and 
the 
vapsf' 
was 
suept onto an acLivaled 
si 
l,;er wool 
i-'!uq 
bih*re 
:
the llg 
was 
trapped 
as 
an 
amalgam 
(Long 
ct 
al. 
lt/li.  
l-oj 
lowin.l 
a 
?-ririure
co'llection 
period, 
the 
si 
lver 
vrool 
plug 
was 
hcaterJ 
to 
tic-amaiqariiaLti 
thr 
riig. ,'rrir!
the 
vapor wEs 
swept 
through 
the 
absorption 
ccl I of 
a Fisher 
llercur.r 
r'rrralyier.
A Varian l'lorJel 485 
Digi 
tal 
lnLegraLor 
wds 
useri 
to 
rnedsurc 
peok 
,irc,r; 
rvhich.
when 
cotnparerJ 
to the 
peak 
areas of 
llg 
stanclards 
t 
corresporrdcd to 
lig 
ronclrrtla-
t,iotts. 
Waler 
samplcs were 
treaterJ 
similarly with thcr 
excc,pt' 
'r 
thdl thc 
arltJition
Cyanicle 
concentraLions in tlte water 
s,rrnples 
were 
deternrirrecl 
by analyzing 
fhc
scrubber 
solutions 
(after 
the 
reflux-disLill.rtion) 
coloriinetrically 
using 
rr
Spectronic 100 Spectrophotometer. 
An al 
iquoL 
of 
chloramine-1 soluLion at a
plt>B 
was 
acJcled 
to converl the CN- to c,yanogen 
chloride 
(CNCI 
). 
l'lrc 
color'
(various 
shacJes of 
purple) 
rvas forrned 
by adding 
pyrirline-barbi 
turil 
acjcl
reagent; 
readings 
were 
taken 
at 578 nrn r+ithin 
15 
mjrrutes. 
The 
concentration
of 
CN- in 
the.sanlples 
t,tas calculated by 
comparing 
the 
sanrple rea<lings 
wiblr
those 
of standat"d 
CN- 
solutions treated 
in 
an,identical nianner, 
The 
plo135rirnt
cyanide standard solutjon was standardized 
by 
titratiorr 
vrith a 
prinrary 
silver
ni trate solution.
Coal, 
slag, 
and fly 
ash samples were analyzed:for 
the 
aforementioned 
elernents,,
plus 
a'luminum 
(Al 
), 
cobalt 
(Co), 
molybdenunr 
(Mo), 
phosphorus 
(|'>), 
an<J 
vanadiunr
(V). 
Methods 
of 
analysis included neutron 
activatjon analysis, 
ncutron
actjvationanaiys.iswithradjoche[}icalsc,parationforl|g,optjcalenission
spectrochemical 
ana.lysis 
(both 
direct-rea<ling 
and 
photograph 
ic), aLonric
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rt,r 
f luirl.es(cn(.o;
A <Jescription 
of eaclr 
jnsLrumcnL, 
not:nal 
opcraLing 
cgnriiLif;ri.,, 
arrrJ 
r-csL
refel'ence 
mdterial 
s 
are 
c0nla irtecJ'.in 
Appen.Jir 
C 
of 
,r 
rcporL 
liy 
p,ilclr 
aL ti 
I .
( 
ters; .
,t'
DATA 
AT{ALYSIS 
:
During 
statistical:treatment 
of 
tiie 
chemical 
const'itucnt. 
data from 
the 
fiq-st
year of 
the 
project, 
all 
concentration 
yalues 
less 
than the detection 
linriit,of
the 
analytical 
instrunrent 
were disregartlecl 
(Smith 
and Ouda 
1979). 
Tlris, 
in
ef 
f 
ecLi, 
:bi'aserl 
'the 
appropriate 
means 
in an 
upward 
rJi 
rect 
jon,,,'.on,nrrmes 
to,:
unrealistic 
levels, 
During 
the 
second 
year 
of 
tlre 
investigation, 
values that
were 
less 
than 
the'cletection 
linii,t'vler'e 
consitlered 
to 
be "0" 
(Anclerson 
et,lal,
1980)',. 
Though 
more 
realistic 
than the former 
approach, 
this 
pr.oduced 
a bias 
in
the 
downward 
direction. 
The 
present 
approaclr 
has 
been 
t,o 
set 
all values 
less
than the detectiort 
linri'u 
equal 
[o one-half 
of 
the cJeLection 
lirlit. 
|^lher.e 
thc
rnajority 
of 
the values 
for a 
particular 
element 
(such 
as 
Pb or 
Se) in 
a 
partic-
ular 
set 
of sanples 
(such 
as 
gizzard 
sharl) 
are less 
than 
the detectjon 
limit 
of
the 
instrument 
for 
that elemettt, 
the 
sarnple 
nrean would 
be r.epor-ted 
as 
less 
than
the ,cle'tect'ion 
I 
jmi 
t-.',: 
ln such 
cases, 
Lhe 
hal f-detection 
I 
inri 
L', approach 
has 
"no
relevance. 
Hovrever, 
it becomes 
important 
for 
statistical 
considerations 
in
those 
cases 
where 
be'low-detection-.limi 
t values:.are 
reported 
for a 
few 
of 
the 
:
total 
'nuntber 
of sample values for a 
'particular':elernent 
(such 
as Na 
in 
the ia'se
of 
nacrophytes 
or 
tlg 
in 
the 
case 
of 
fish 
or 
macroplrybes),
The third-year 
data 
have been calculate<i 
an<J 
statistjcally 
analyzetrusing 
the
half-Jetection limit approach. 
In addition, 
t,he 
data for 
tlre firsL 
an<l 
second
years 
have 
been 
recalculatecl and re-analyzed 
statistically 
using 
Lhe half-
. 
detection 
t', 
'. 
I 
irnit approaclt. 
:
These 
r-esul 
ts 
for 
the' 
inr.liv 
jclual 
years 
are 
llrc,senterl
intabu,IarforrnintheAppendixorthisrepoi't(tables4.A-4.'V).
A check of the 
first-year 
sedintent 
extraction 
rnethod 
jnclicaLecl 
that 
unriuly 
harsh
con-rli,Ciohs 
prevai 
led''which 
tended.,to' destroy tlre 
integri 
ty 
of thc set'lirnent 
i
itself':,rather thanim€ie1y desorb 
th; 
cations froiir 
the sedirnent'''parL'ic:le
:,: 
,
.j 
:=
T
,:1.
I
I
I
I
T
I
I
'l
I
'l
i
I
I
'l
, 
',t.1,,1 
,:. 
'
:a 
ta:'
: 
.r 
:i-:'
I 
,''  .,:::::l 
ii. :,
:..' 
,' 
,l',
;;tt,:;::     
i:i:- 
:, 
-.- 
,
4 
.18
,: 
'"" 
'
:                   
,:        
,:
:: 
:
surf 
aces. 
Fresh 
al 
lquots 
of 
'f 
irst-year 
5erJiilents 
were 
subjficled 
Lo 
Llrtl s+.
digestion 
regirnen 
used 
for 
sediments 
frorn 
the 
iol 
lowinq 
twc 
years. 
The
resul'ting 
rtat'a 
were 
;;lculaterl 
antJ 
stat 
lstical 
ty 
analyzed 
ds 
pdrt 
af 
the 
f
year'data 
and.are 
therefore 
inc luded'in 
the'rAppenrci 
x, 
as 
referred 
t0 
above
(Iarrle 
4. A) 
.
Al 
I statistica'l 
analyses 
and.comparisors 
of 
'Jata 
fot' 
the 
three 
years 
have heen
carried 
out 
using 
starrdard 
analysis 
of variance 
packages 
available 
on the
llniversity 
crf 
Il 
linois Cyber 
175 
comprrter.
RiSULT 
S
SED 
I MINTS
Major'trer,,is 
in 
the 
concentrations 
or 
severdt 
chemical 
c0nstituents 
in Coifeen
Lake 
sedimi.'nt 
occurred 
over 
the 
course 
of 
the 
3-year 
study. 
Eoth 
Ca 
anri 
lt
exhibited 
significant 
increases 
in arrnual 
mean 
concentration 
during 
the 
3-year
peniod, 
and 
Hg 
shcwed 
a 
sjgnificant 
rjecrease 
(Table 
4.3, Fiq. 
4.S). 
Sirnilar
trends 
for 
these 
three 
elements 
were 
evident 
at the 
staLion 
level 
(Table 
4.4),
Comparison 
of annudl 
mean 
concentrations 
aL incJjvidual 
stations 
indicated
significant 
increases 
for 
Ca and 
l,lg 
at mosL 
stations 
and 
non-significant
increases 
at 
the 
remaining 
stations. 
In 
the 
case 
of 
llg, 
three 
or 
ttle 
si*
stations 
showed signif 
icant, 
decreases 
during 
the 
3-year^ 
per:iod; 
the 
oilrer 
thr.€€
also showed 
decreases, 
though 
not sjgnificartt. 
The'.annual 
rnean 
concentr,ation 
of
one adrljtional 
element, 
Cd, 
decreased 
significantly 
at 
Stations 
I 
and 
Z between
the 
first 
and 
second 
yeilrs 
of the 
stucly 
(Table 
4.4), but 
remained 
relatively
constant 
at 
the 
other 
stations 
during the 
same 
perioO, 
,
:,
There were significant 
changes 
in the 
station 
distribution 
of 
some 
of the
chemical 
constituent.s 
in 
the 
lake sediment 
from 
vear to 
year, 
but 
none 
of the
ionsfituents'showed 
progressive 
increasa, 
ort decreases 
jn 
concentratiorr fronr
Station'I 
to'station 
4,(Appendix 
Tables 
4.A-.4.C). 
During 
the 
firsf:Jfear 
of 
the
study, the 
concentrations 
..
of both 
cd and 
cu were 
significant'ly 
greater 
at
Stations 
I 
and 
2 than at 
Stations 
3 
and 
4. The 
djfferences,in 
succceding 
years
-},ere 
much 
less.marked. 
.For 
.all 
three 
years,,of 
the 
study, the 
concenlrations 
of
' 
.4:'19
,.1 
.:
.: 
-:.
.,::..4,
':i.ia::.:::...., 
.
e 
4,3. /vrntral 
meon 
conccnLrafiorts 
(m!/tQ 
rjr./ a11 
i.;hr_i 
of 
crren,i cal
'' 
constiLuents 
in 
bottom 
sediment 
col 
lecteri 
lL 
ecf 
f 
cen 
Like 
f 
r+::r
SeptembCr. 
l97B 
throrrglr 
0ecembtr igftr-j. 
iarii 
lr-' 
{lu;t,it 
i.,. 
rrr5 
1r-,,
{ 
n 
parentheses 
,
t.
..
I
I
_lr}-
r 
97S-79      
I 
979-80
I
-TTOT
*:|]ur
l 
980-Br
i/re 
an
ry             
t
A9
As
B
8a
Ca
cd
0r
Cu
Fe
Hgc
K
l'lg
Mn
Na
Ni
Pb
Se
7-n
7,58
<0.80
s.82
I 
:32
1 686.
I 
.98
o: 56
B.38
t?r.
r 
34.
r 
60.
337,
l 06.', 
I
I 
75,
:
I .73
<2,78
.:
<0.67
23.7
b
<0.76
, 
B.B3'
1.63
?.398.
I 
.21
<0.22
2.41
?.97 
,
7 
4.3
l6't.
:488.
,405. 
,
:
207 .
' 
2 .05,,
<0. 
90
(0.68
21.5 
,
b
{.0. 
7B
, 
7.04
I 
.00
3??4.
I 
.35 
,.
.
i0. 
l6 
,.
6.08
l!6,.: 
r. 
,':'r-
53.5 
,
i
121. 
.
61 
].  
,.1
,,.  
: 
'
3r 
5,
?4?. 
.
'_1.94 
:
<0.70
l
.'{0.60 
l
:
24.5
|,68
t 
.l2
267 8,.
t 
.36
4.77
:
23?.'.
'r2,1
:
143.
525.,
330,
?r 5.
'l 
.,96
23. 
I
2.8
<il,
"1.j
?LJ
1.2
1.4
1,5
-?1,-q
.1.!_
10. 
?
4.9
1.5
0.2
T
I
l'
T
I 
.::
I
l'
l'
I
I
0,1
t'
':.a 
' 
: 
"r:::
i 
,- 
' 
,t'.,'
...',ll' 
rr,'.
i;!;,,. 
.',:- 
:
::,. 
i.-i'. 
t-.-' 
'
i!,' 
: 
.::.,....:::-
*,,,, 
'- 
"t-
tt.,,
lir'i 
' 
'
!ii',, 
,,. ;,
aValues 
that: are' underscor:ed
. 
between 
years.
DAt 
the time 
of 
analysis 
the
measurement 
of this element.
cConcentrations 
are 
in 
ug/kg
indicate 
significant: 
differerrces 
(p<0.05)
Instrument 
yJas 
not f 
unctiorring 
optimal ly
dry weight.
:
, 
',i 
4,20
,:,.;
f 
or'
a. 
t: :-'.:'
:,::'.,.
:: 
. ;';':::.r
tlr 
i=
,'I
',i,,
',,jI-:
I'
,,:' 
.::
,!: 
"    
,'' 
'' 
':
t).!},(n
x 
4,.x
nl
ltl
||t
tll
I  
t 
't   
I
tttl
|  | 
:l 
I
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3
Pondweed
Fil- 
-
l?1" 
;;
ll
il
il
I   H
Ittl
Iltt
g
t23
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?
tt
ll
tt
I   l.
tl
123
Pondweed
aq 
en 
n1
xx><
ra*l=r 
il=,
i-l
ll
IJ
Jl
Bi le-
siit
I 
Sed lmen 
t
:l 
2 
3
Pr 
i 
mrose
1,23  
l?3
Sediment 
Primrese
| 
2 
3 
.t 
2 
3
Sediment 
Primrose
rufl
123
Si 
zrard
rha 
d
L]
l
Iarp
J
Channe I
ca 
t-f 
i 
sh
n 
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caLfish
l?1   
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Elaell Lar:gr-nouH:
brr I 
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r
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ul 
itt
xxx
li
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t,l  
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l, 
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:
I
t 
t,,:
tj, 
t-
l.', 
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i-',,
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:il
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Largc+nouth
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hul 
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l
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tr}(ftrn
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I,,,?, 
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brr I 
I head
fti],
t? 3
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th
bass
3.'  
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Corp 
Blue-
,r  
q.iII
1 
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3 
' 
I 
? 3
Sedlrnent 
Pt'imrose
. 
.1i!    
.itA
llF-r-t-1__
l2 
3 
123  
t?3
Gizzard 
Blacl, 
Lar.gmrouth
shod 
bu 
I I 
head 
lta ss
cf
{
Carp
4{
;
JJ
Bl ue- 
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qi 
I 
1 
catfish
iFiiure,4.is.
',t,' 
, 
,-t.'. 
,'
I   
. 
: 
::i 
i:       
::..t. .
..-
.  
.  
. 
..:
..;,,.t--a,. 
;'.,;. 
.,        
t
Annual 
mean concentratlons 
(mg/kg 
fresh 
or dry 
weight)
constltuents 
in 
samples collecteri 
at 
Coffeen 
Lake 
fram
1978 
through Oecamber 
1980. 
(continucd)
..:
of 
che,rnica I
5eptember
...
I 
t,       
...a
l 
.l 
.cl
^r
i=::.:. 
':'::'::     
.::- 
,,,',:a, 
' 
,,
f$(\cv
xxx
da
tlnLhnnn
l-,2 
3 
tlI 
2 3'
Gizzard 
[}lact
shad bu I 
'l 
head
c.J
x
ll
tl
rt
tl
il
ll'
Ll-rr
r?3
Pondweed
CV GJ 
GJ
xxx
n
il
ll
tl
tl
ln1
I23
Pondweed
3 
xxx
3:3
n
tl
lt
tt
ll
ll
I 
l--rt
n
I
I l.
Lt_-
t23
Pr i 
mrose
tr, 
rorf).
xxx
n
tt
|l
tl
LIL
r 2 3,
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-? 
3
iment
-r-xx
l"
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(t) 
l
,x
,123
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bass
r 
1
J
Ca 
rp
llL_,
tt    
tl
rr
3 
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B.l ue- 
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gi 
1l catf:ish
nLrD
3   
3   
3'
Carp Blue- Channel
gill 
catfish
I
I
I
I
I
T
I
c)o
r') 
tn
'xx
a
tt)
x
ml'f,fL', 
t23  t? 3 
tt-
t?3
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Black:Largonouth
shad bul I head bass
n
lnl       
,f
J
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" 
"'tn
t'23  
L2 3' 
t23  
r,2 
3
Sedimerrt 
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shad
n
Llr== m== 
It-{r
,r,2,3 
t2 
3 123  
123
Sediirnent 
Primrose 
Pondweed 
G 
i zzard
shad
r23
Bl ack
bul I head
r-f-t-:f
t23
Largenrou 
th
ba ss
tf   
[-l 
,
3 
,'3'
Ul 
ue- 
Channe I
gill 
catfish
d'
dJ
t2 3, 12 
3   
3   
3   
3
Blackl Largemouth Carp B'lue- 
Channel
bul lhead 
: 
bass  
.   
gi 
1 I 
catfi sh
a
i:! 
:
:: 
: 
j 
::,...
..: 
j
Ftgure.
:a 
1 
",::
' 
:::-.r:.::
4i5, 
Annual, 
man concentratlons 
(rng/kg 
fresh or 
dry weight). .. 
(continued)
\.,,.,? 
3
Sediment
ro 
tr) 
io
tx.!X:r.t<.
4.?2
f'l 
xxx.,
fv1 fn :
n
il
IIII
tl
n
tl
ttIt
tf
tt
{l
r--l 
r{l| 
|
re3
Bl ac!'.
bu 
i t head
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t-
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r 
LrilllL-llh
ntil 
rt 
th 
lll
:-
ilL
'oo1-LLJ 
L2 
3 
LLn 
123 
LjI 
123 
rrll 
t2 
3 
r-r-lt 
123 
m 
t2l 
r 
I 
n
3
Sediment 
Primrose 
Pondweed 
Gi 
znrd 
o,l,r,l.J.o 
,urfl:T:rrn 
Carp 
rJl;
qlqcn    
rt1rn 
Lr) rn!oir)
xxxxxxxx>r.
I
h
::.
'(t)'
x,
tl
ll
tl
tl
Il
tl
II
I t,
tl
L_J
anne
tfi s
xx
.
nn
tttl
il 
ttil
rl
tltt
ilil
LJ 
LJ
33
Carp 
Blue- 
Ch
gill 
ca
Sed imen 
t
t{b
r23
Bl ack
bu 
I 
I 
head
T 
? 
3
La 
rgemou 
th
bass
r-1 
-
rl
l4
t 
a 
J
Largemou 
th
, 
bas 
s
: 
-:
r--1
tl
L--l
{
Channel
catfi 
Sh
tr 
EI,,
3 
.3 
..:,
Blue- 
Channel
gill 
catfish
o 
s 
xxx
@@
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Mn
123  
r23
Sediment 
Primrose
| 23
Gi 
zzard
s 
had
tl
3
Carp
*. 
1
,rrLt[
123  t2 3
Sediment Primrose
t-Tlr 
nll n-r-l
r2 
3 123
Bl ack 
Largemou 
th
bul 
lhead 
, 
bass
n
3
Ca 
rp
l',,2 3  
I 2 
3
Pondweed 
Gi 
zzard
" 
.', 
l 
shad
,'.'.i 
, 
,
.:
I 
- 
;,
J
Bl 
ue-
gill
tl
LJ
J.
Charrne'l:'
ca 
tfi sh
:': 
'
''''1"
:'
:'r'tll
' 
::.: 
.
:   
':
l?3  
.,t'.2 
3 123
Primrose 
: 
: 
Pondweed Gi 
rzard
sha 
d
o(fo
€@@
xxx
l--t
tl
tl
lrn
tl
tl
| 
2 
3
Pondweed
Annual 
, mean:cohcentiations 
(ms/kg 
f resh 
-.'r,'dryl 
weight) . 
. . 
(continued) 
-
aa
l=i-L,      
r*l 
..
't 
2 
3 
123
Gi 
zzard 
Bl 
ack
shad 
bu'l 
I 
head
da
I/,J
L 
arg 
anou t 
h
. 
[i455 
'
E    
,,',.
i..:
, 
:l::
JJ
Blue- 
' 
Channel
gi 
) 
1 
''catfish
u,it- 
gi11 
ca'tfish
;;*..,
aa          
a
3
Ca 
rp
I 
:
t
I
I
I
I
I
I
I
I
T
I
I
I
t
l,
I
'l ?3
Pr 
i 
mrose
t?.3
Pondweed
123  
123  
123
Sedinrent 
Primrose 
Pondweed
Ln
x
I 
2 3  
I 2 
3  t'2,3
Gi 
zzard 
tjl ack 
Largernouth
shad 
bul 
I 
head . bass
aa 
a
| 2 
3,
Primrose
r--l
tl
I lu 
u
Ll_--
t23
Primrose
!
aa
123
Gizzard
shad
a
rll_
t23
Bl ack
bul 
lhead
Y
{
Channe 
I
catfi 
sh
a
Carp
',L 
2 
3
Sed 
i 
men t
,l'23
Sediment
r 23
Pondweed
I'Z.3
Pondweed
t23
G i 
zzard
' 
shad
123
Bl ack
bu I 
I head
7 
..2 
'3
Largemou 
th
'bass
ba ss
tl
LI
?
Bl 
ue-
gi 
1l
|f,ilrttjn 
r{ 
n
I r{ L- 
_JL 
Li 
r--r 
Ll
n  
IItl
tl
tl
3: 
.'
Channel
catfi 
sh
J
Carp
3
Bl ue-
silr
fresh or 
dry weight)... 
(continued)
:.:a::'a'.','., 
a,a 
:':': 
.
:. ::.':: 
' 
'
_.'j..-
. 
-1.. 
: 
,.a:. 
'!'.a:.
aa
C\l 
(\l
xx
Table 
4.4. 
Annugl.rnedn 
concentrdtions (rng/kg 
dry 
weight) 
of 
chemical
', 
. 
anci 
I'lary.Llltions 
at 
Cof 
f ecn 
Lake 
f rorn 
Septcrr,ber 
lgig 
rtrrougtr
December 
J 
980.
,         
Stat 
ion 
I
-Tg-/6--E---Ttrg-B--d---rqAn--ar=wr"
A9
As
B
Ba
Ca
cd
Cr
l,
LU
Fe
Hgc
t\
.
Mg
i,ln
Na
Ni
Pb
:
Se
:
Zn
B. 
82
'<0.80
' 
:
5.93
:
, 
1.70
2,225.
2tzg
4.44
0.58
, 
8.93
17 
2.
I 
00.
2r B.
I 
BB.
I 45.
l.l7
<2,78
<0.67
.:
12"0
b
<0,76
7.46
1.40
2,936.
1.22
<0,2?
<0 
.46
.
42.8
89. 
I
79.0
543.
245.
ll7.
I 
.35
<0. 
90
, 
<0.68
,
14.7 
,
..0
<0. 
78
3. B7
.l 
.03
:
3,369.
'0.27.
.a
<0.16
(0.I2
78. 
0
43.9
::
49.r 
,
540.
208. 
.
I 
43.
0 
.0s
<0.70
<0.60
5.23
s. 
7l
1 
.?9
:l
2,997 
,
'l'.00
51,. 
B
B4;1
70.0
487.
220.
) 
26.
0. 
96
10.3
6;4
3.5
lt.0
l4.q
l.l
43. 
I
1.3
2.4
I 
'5
1.1
3.8
3.6
:I 
"': 
:t:::
:: 
, 
;;' 
:::
'::.a.. 
,.:      
::.
l':   
,.
i-:,            
:
.t'i,, 
t"'
::::-  
.:::
4.25
a. 
t, 
- 
,
', 
Table 
4.4.  
Annual 
mean 
concentratlons 
(rng/kg 
ciry 
weight) 
of
chemical 
constituents 
ln 
lrott6rn 
ierJlment 
iol iecIed 
at
four 
major 
and 
tno 
ancillary 
stations 
at Coffeen-iai.
f rom 
sept'ember 
l97B 
throrgh 
Decernber^ 
1980. 
(cont 
i.uecl 
)
:         
Station 
I 
.5
__-Td
Ag
As
B
,Ba
,Ca
,cd
,Cr
Cu
,l'Fe
' 
Hgc
K
:
'Mg
.
,Mn
:
Na
Ni
,, 
Pb
Se
.
''7n
b
' 
<0.76
12.6
:
1 .48
I 
,99 
.4.
l 
.0'l
<0.?2
3.7 
5
l
659.
6r .l
17 9.
4l 
l.
523.
240.
?_.72
<0.90
<0.68
23.8
, 
[:
<0.78
9.46
:' 
0.7?
3,261 
'
, 
2.16
,, 
(0.1,6
. 
l.4s
' 
72.8, 
,
, .ai-
' 
57.7
,150. ,
:
693. 
.
556. 
.
,321 
. 
,'
2.54
<0.70
(0.60
. 
29.4
I t.0
.1.10
2,628.
I 
.58
?.59
366.
59. 
4
r 
64.
552.
540.
27s.
2.63
26.6
1.3
,7.3
,"
2.3
0. B'
,l8.6,
',, 0,1
| 
.2.
._i.
143.
0.04
',0.9
0.0 5
:T
I
T
T
I
I
I 
:-
I 
..
I
I
0.2
.4.26
( 
cont 
inued 
)
Table 
4.4. 
Annual 
mean 
concentrations (rnq/kg 
tlry 
welqht) 
of 
chernical
constituents 
in 
bottom 
sedirnent 
iollicted at four major 
and twtr
ancil 
lary 
stations 
at 
Cof 
f een 
Lake 
f rorn 
September 
l97B 
tnrr:Lrqtr
Oecember 
1980. 
(continued)
'-Tfm:/g---
r 
9/9-U0      
I9BO-BI
Stat 
ion 
2
-Tedn 
-Fd
Ag
As
B
Ba
Ca
cd
Cr
Cu
Fe
Hgc
K
Mg
Mn 
.,
Na,
Ni
Pb
Se
Zn
il.1
<0.80
4. 
9B
0.99
I 
,1 
85.
4.20
0.67
32.5
397.
I 20.
I 
70.
208.
112.
I 
60.
3.58
<2.78
<0.67
66.8
b
<0. 
/6
I1.0
I 
.49
|,927.
I 
.71
<0.22
4.74
676.
56.9
17 
4.
384.
456.
" 
20g.
3. 
45
<0. 
90
<0.68
36.0
b
<0, 
78
8.53
0.58
2,7 7 
6.
t.84
<0.|6
?4.6
531.
59.2
I 
69.
606.
5l 
6.
299.
3.24
<0.70
<0.60
39. I
a, 98
1.03
2, 
I 53.
2. 
rB
17 
.7
569.
69.4
r 
it.
447 
,
4?4.
234.
3.38
0.7
6.1
4.0
4.t
2.7
0.4
l4. 
t
0.03
6.B
la
0.5
0il
r.3
' 
'' 
'';
'i,:.-'
4.27
42.4
( 
cont i nued 
)
: 
- 
' 
..::.
. 
,: 
:r..=.: 
,. 
a
: 
.:1.: 
,:.
Tab'le 
4.4.
l.t
:.
l:
I
&rnual 
mean 
concenfr.ations 
(mq/ke 
dry 
wejoht) of
chemical 
const 
i 
tuents i 
n bottom 
ied 
iment 
do 
r 
i 
ectad 
ar
four 
maJor 
and'two 
ancilrary 
staiions 
ar 
csffeen-ior,u
f rom 
September 
t 
97B 
through- 
[hcernber 
lgB0. 
(ionr 
in,,e,f 
t
I
!
l
Ag,
As
$
Ba
r 
l.
Ca
cq,
..
cF,
ct
Fel
.: 
:
Hgc
K
Mg.-
Mni
l{a.
'.
r{i
b
<0.76
9.98
1 
.09
2,A53,
I .79
<0;22
4.02
222.
68.0
:
162.
522.
762.
236. 
,
2.55
<0. 
90
<0.68
:
33. 7
.' 
<0.78
B.03
.
'   
0.62
?,923.
2.93
,  
<0.1 
6
:
. 
. 
9.85
366.
: 
50.0
. 
: 
l39.
. 
725.
.., 
438.
_'1t,.1
'i  
<0.70
'. 
<0.60
,- 
60.9
9.01
0. 
85
2,4BB.
2.36
.
6. 
9l
294.
58.0,
rf,t.
624.
600.
2?4.,..
3.34
47,3
3.8
3.2
'I 
1 r
;
I
t
t
t
I
I
t
I
I
I
Pb
Sel
0.7
0.9
t.?
3.t
PJ
l_9.0.
0.04
3.8
'1In.
3.3
it]
a. 
'a.'.:
:
(continued)
,,, 
'.,:
l.+
4.28
i'"' 
' 
-
"
fr',, 
'
:: 
Il: 
. 
.
l
I 
'::
:::r.' 
: 
.,
t.-:.: 
- 
,,,,   
' 
. 
,t'                                 
'
j:r..:    
: 
:. 
: 
::
Table'4.4. 
Annual 
mean 
concentrations 
(rng/k 
g'dry 
weight) 
of chernical
." 
constituents 
in bottom 
sedimeit 
dollected'at 
four 
rnajor 
and lwo
,' 
':    
dnci 
I lary 
stations 
at 
Cof 
feen 
Lake 
f 
rom 
Septernber 
lgiU 
th'"origh
.: 
,  
December 
1980. 
(continued)
liJ_
,0.3
9-r-1,
1,.2
l,
I.r
1,,
....:
I
! 
. 
'.:
I,
!:
a:..  
I
:.. 
, 
,:' 
.
I
I:
l,
l,
l:r'i: 
I,'
-
I
I
I
:;l;'.:
lr
!'
.-. ,i 
i
r
l',
Stat,ion 
3
-Tg/S.79. 
]lff/9:r60' 
-- 
an
Ag-'
As,
B.
Ba:'
.
c;.
cd'-
Cr
,r, 
,
Fe,,
Hgc
K,
Mg'
'I .
lln.
Na 
,1
Ni 
,:
Pb
5" 
-.-
Zn.:'
3. 
B3
0.95
3.40
0.93
I 
,560.
0.96
0.56
<0.38
34.0
7l 
.5
90.5
562.
79. 
B
't05.
I .20
<2.78
<0.6 
7
l0.l
'b
<0.76
5.7 
2
I 
.00
2,073,
1 
.50
' 
t<o.z?
I 
.37
l 4s.
:
73.3
, 
140.
623.
31 9.
I 83.
I 
.93
,. 
(0.90
, 
(0.68
:
' 
,20;2
b
<0.78
6, 
BB
I 
.20
2,978,
0.i84
<0.r6
0. 
37
:
108. 
,,
50. 
I
124.
710. 
:
l3l.
257'.
.:
1.06
<01 
70
<0.60
12.4
5, 
81
I,07
2, 365.
l.l3
0,7 
4
r 
ll.
63.3
1 
2s.
649.
201 
.
1 
98.
L44
0.5
0.5
).7
2,3
oq
8.5
3.6
'2,f
G.9
4.29
r 
5.3
( 
cont i 
nued 
)
Table 
4.4.  
Annual.meal 
concentrdt.ions 
(mg/kq 
dry we.ighti 
of chemical
const'ltuents 
in 
bottom 
sr:diment 
col !ecLerJ 
at f 
our arajor 
and 
Lwo
ancillary 
st-ations 
at 
coffeen 
Lake 
f 
roni 
scpiemuer 
lgi8 Lhrorrtrlr
December 
I 
980. 
(cont 
i 
nue<J 
)
I
I
t
-.-l-q"ro':79
Stat ion 
4
t
r 979-80      
t9urJ-81          
llle 
a n             
Fd
I
I
I
I
T
T
I
I
,A9
As
rl
Ba
Ca
cd
Cr
Cu
re
Hgc
K
, 
i',|9
,'tln
Na
Ni
Pb
5u
,7-n
6. 
64
(0,80
9.00
I .68
1,775.
<0. 
B0
0.57
<0.38
46.4
171 
.
280.
365.
45.7
289,1;,.
0.97
<2.78
<0.67
5. Bl
l1
, 
(0. 
i6
6.18
3.35
3,404.
<0 
.08
' 
<0.22
<0.46
39. 
5
. 
92.B
233.
,. 
444
126.
,256.
' 
0.33
<0.90
.<0.68
- 
'0.27
t)
<0. 
iB
5,46
l.B4
4,045.
<0. 
l0
<0.16
0.14
20, 
B
60.0
94.2
393.
42.3
215.
<0.28
<0.70
<0.60
0.1 4
6.35
2.44
3,4 
00.
32.9
92.2
r 
83.
409.
'77.6
244.
0.36
1.14
3.8
30
l-1, 
/.
0.5
4.3
44. 
5
0.8
I 0.0
2.2
_1L.0
I
t
57 4.
aValues 
that are
, 
between 
years.
DAt 
the tirne of
for 
, 
measuremerrt
cConcentrat 
i 
ons
-...:: 
:' 
:
t
t
I
underscored'indicate 
signif 
icanf differerrces (p<0.05)
anlly.s 
js 
.t!e 
instrument 
was not f 
unctioning 
opti.rnal 
ly
of this 
element.
are 
in 
ug/kg dry 
weight.      
.
:
' 
_: 
:': 
''" 
'
a
'-      
. 
4 
.30
lj
-
I
r
| 
:r 
'
. 
, ,::..
-:,
I.:
Il,'
I-
i.':.
'Ir'
I:
:I
t:
::,. 
:I,. 
" 
,
.r,.
jl: 
' 
'.
:l:: 
:.
iE
}I
r,r
iI
*'' 
,
r-_-
,-.
F-
!11
1I
both 
Fe and 
Zn 
were 
reldtively 
low at SLaticn 
I 
anrl 
hirlh 
o. Statlon 
2, compared
to the 
concentrations 
at 
most 
of the 
other 
stdtions,
c0Rt 
s
Sedimelrt 
cores were 
collected 
and 
analyzed 
for 
corrcentration'-r 
of 
chemical
constltuents 
only 
during 
the third 
year 
of 
the 
investigatir..rri', 
cores were
collected 
at fjve 
polnts 
along a 
transect 
across the 
lake 
at each 
of 
the 
four
rnajor 
and 
the 
two 
ancil lary 
stations. 
Statistical 
analy,sis 
of 
the 
elemental
corlcentration 
data 
inrlicates 
that 
the 
concentratiorrs 
of certain elernenis
differed 
significantly'between 
stations 
(Tab'le 
4.5). 
The 
concentrat ions 
of B,
Cd, 
and 
Hg 
in the 
cores decreased 
steadily 
anrt 
signif 
icantly 
f rom Str:tion 
I t.o
Station 
4. 
In contrast, 
the 
concentrations 
of As, cr, 
and cu wei.e 
hiqher 
in
cores from 
Station 
2 
than 
frorn 
other 
stations
A comparison 
of 
concentrations 
of 
chemical 
constitituents 
in 
t,he 
five 
cores
, 
obtained 
along 
a transect 
at a 
given 
station 
(one 
near 
each bank, 
one 
in the
center 
of the 
lake, 
and two 
at intermediate 
points) 
indjcates 
a 
fair ctegree 
of
homogeneity 
in concentrations 
at 
points 
alonq 
each transect 
(Table 
4.6).
. Although some 
of 
the 
differences 
in concentrations 
between 
points 
are
statistically 
significant, 
there 
tppear 
to 
be 
obvious 
trends 
for 
oniy three
elements. 
Ihe 
Fe concentrations 
in the 
cores decreased 
nrarkedly 
and rhe Ba
concentrations 
decreased 
moderately at the 
center 
of the 
lake 
(at 
each 
station)
conversely, the Mg 
concen.trations 
increased 
at 
the 
same 
locatjon
The 
cores 
rere 
separated 
into 
six segrnents to 
represent 
recent 
sediment, four
intermediar:e 
deposits, 
and 
original sediment. 
A cornparison 
of the.
concentrations 
of chemical 
constituents 
in 
the 
six 
segrnents 
averagerl 
across 
the
five 
cores 
along 
each 
transect 
(at 
a 
given 
station) 
indicates 
a fair 
degree 
of
,,-,homogeneity 
in concentrations 
of about half 
of the 
elernents 
in 
the 
segments 
of
,cpr€s 
collected at 
each 
station 
(Table 
4.7). Exceptions 
are B, 
Cd, Cu, Hg, 
Ni,
and 
Zn, 
who59 concentrations 
tended 
to decrease 
as the 
depth 
of the segrnent 
in
the 
core increased, and Fe, the 
concentration of 
whjch tended 
to 
jncrease 
with
. 
increasing 
depth 
into the 
core.
4 .31
,-.t 
't 
' 
' 
'" 
li:
,.-:.r    
r' 
i:          
, 
:-'
,,Iible 
':4r5;. 
Pean 
concentrat 
ions 
lmcr/k(1 
drv relaht) 
+f
''...r:l'...-....t9s0..(l980-8l)....
col lect€d 
at 
four 
majoi 
aria 
two 
anii I 
iary
.    
.:                  
:
aa. 
::        
':
ehe,aical 
canst ituerrts, 
lrr 
cores
siat 
ions 
at Cof f 
uer: 
l.ake 
i 
n Ju.re
''
:
tle an             
r
Ni 
,1,
10;6
l:'
Pb 
'' 
' 
<2,?)
Se 
..:, 
<2:32
Zn 
" 
Il8. 
l
:a- 
nValues 
that 
are
<37,7 
-'<37.7
6.23 
I 
0.1
zti,.6  
?3.9
34. 
B   
3?,7
514.  
55?-.
5.94  
7.48
15.?  
14.2
30.6  
48.5
I 
t432, 
' 
2,133,
44.8  
50.2
22.1
57?.
2,?,64.
28.7
, 
529,.
| 
;757 
.
l
12.9
I 6.6
: 
12.21
<7-.32
167.
13.9
r3.4.
<2.21
/,2.32
<37 
,7
, 
6 
.:,
.96
19.0
49.7
520.
3,7 3
17.9
I8,5
I 
,960.
46.2
26.0
434;
2',136.
il.0
:
I 
3.6
<2.21
<2.32
97.4
<37 
.7
5.1 4
2t.0
qt 
,t
538.
I 
4.ll
15.9
26.7
I,639.
', 
38.2
25.?
498.
I,4gB-
r 
0.5
I 4.5
(2:21
'<2.32
,104.
<37.3
4. 
l0
19.4
34.3
465.
:
I . 
il
I1.2
2.27
I,505.
3r.5
?1.9
586.
I 
,050.
18.3
9.72
<2,2]
<2.32
60.3
6.34
24.7
39. 
I
527.
5. 
t3
l-1. 
/
22.?
1,627
48.0
,'
23.5
532' 
i,
I,684.
t2.9
I 3.0
I 12.
168
t6B
r6B
166
l6B
l6B
l6B
l6B
r6B
163
t68
l6B
r6B
t6B
t68
l6B
l6B
168
?.5
7.q
r.B
1.5
?,1_
3.4
?.-!_
L9
7,7
5.0
1.4
6.9
2.3
2.7
'l
'!
G
I
I
I
I
I
:l
I
I
I
,l
I
,l
I
1.7
underscored indicate 
significant 
differences 
(p<0.05) 
between
.      
.t.
are in 
u1/k dry 
weight.
ria
t,:.,
| 
'.c:!., 
L.
:ir: 
.
4.3?
,i 
. 
:, 
.,,i.1i, 
;il.- 
,,, 
. 
. 
, 
,, 
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lj
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:; 
tl; 
: 
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j 
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rr 
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S
Theie 
H&s 
a 
significant 
downwar<l trend 
in 
annuaj 
mean 
cOncrritfrrtions 
of'Lhc'
maJoiity 
'of 
the 
chemical constituents 
present 
in 
the'leavr.rs 
and stems 
of 
,lbofh'
creeping 
rraterprimrose dnd 
funerican 
pondweed 
during Lhe 
3-yeor sLudy 
period
(taUles 
4.8 and 
4.9, Fig. 4.5). The 
exceptions were 
B, 
K,,rncl 
lla. If, 
based
on'insufficient numbers of specimens 
coi'lected, data 
from 
the 
first 
year"of
the'froject are disregarded, both 
B and 
lta 
show significant 
decreases in' 
:
concentration in 
both 
species, 
and 
K a significant,decrease in 
pondweed,"
during 
the 
reinaining 
two 
years. 
The 
only anornalous 
trend 
appears 
to 
be 
for K
in waterprimrose.
Snith',and Duda,:(1979) and 
Antierson 
ef 
al. 
(teeO1 
observed 
for 
the 
f 
irst 
and
second 
years 
of 
the 
investigatjon, 
respectively, 
that 
the 
plant 
stems usually
contain 
higher concentrations 
of elements than 
the'leaves 
(tatr'les 
4.8,'rnd 
4.9),
Appendix Tables 4.D 
and 4.E),,,.In 
contrast, data 
forthe 
third 
year 
of the
investigation 
show a fairly equal 
distribution 
of 
concerrtr<rtions of five 
,
etements 
between stems and leaves for 
both species;.the majority 
of 
the.
remainingelementsoccurredinhigherconcentrationsinthe]eavescrfboth
,pq"i",(Tables4.Band4.9,AppendixTable4.F)...Thisclisparityofdis-
thib'utions 
could 
ref.lect 
yearly 
technical tlifferences in 
the 
procetiure 
use-d
fo'i 
separation 
of leaves 
and 
stens. 
Regardless of 
these 
"discrepancies,." 
16s
present 
authors have 
elected 
to 
consider average 
values 
(representing 
the toLal
plant) 
for 
the 
preparation 
of 
Fig- 
4.5.
I 
Statistical 
comparison 
of concentrations of chemical consti 
tuents 
in 
plants
, 
_ 
collected 
at 
different stations 
during 
the 
second'and 
third 
years 
of 
the 
study
I 
indicated that 
the 
location 
(station) 
of 
the 
plants 
had 
little 
bearing 
on most
,.1 
of the 
elemental 
concentrations 
(Appendix 
Tables 4.G-4.J). 
(there 
were too 
few
I 
specimens 
collected 
during the 
first 
year 
to 
warrant statistical 
ccmparison.) 
A
' 
I 
few 
exceptions 
were 
noted for waterprimrose during 
ihe 
second 
year 
of 
the 
study
I 
(Appendix 
Table 4.G). Both 
stems 
and leaves 
of 
plants 
co'llected at 
Station 
3
I     
contained 
significantly 
higher K 
and Zn 
concentrations 
than those collected 
at
- 
other 
stations. 
Stems 
of 
plants 
collected at Stations 
I and 2 haci higher Ca and
1j=.1 
,.,..:'1.,, 
I i:.$6:-:g6i1r
centrations, 
respectively, than those collected at other, 
stations. No
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l,
,l;t 
.
,.j 
statisticaliy 
signit'icant 
tJiffercrrces 
in 
clemenLol 
concentrations 
wer.c 
not.ed
i,: 
for 
waterprimrose 
collected 
at dif 
f erent 
stations 
during 
the thir.rl 
year 
of Lire
i 
', 
s 
tudy.
:
,
at
.,    
There 
were 
also 
a 
few 
exceptions 
for 
pondwee<! 
collected riuring 
tiot.h 
ilrc 
second
.l 
and 
the 
third 
years (Appendix 
Tables 
4,1 
anrJ 
4.J). 
It should 
be 
stressed 
that
;     
no 
pondweed 
was found 
at 
Station 
I during 
any 
of 
the 
three 
years. 
Ccnnpared 
to
: 
specimens 
collected 
at 
other stations, 
specimens 
collected 
at 
Station Z 
contained
i, 
higher 
Cd concentrations 
in both 
stems 
and 
leaves 
during 
both 
years, 
higher Se
.i' 
i'i.
cottcentrations 
in 
the 
leaves 
during 
the 
second 
year, 
higher 
Cu, 
l4n, 
Ni, 
and Zn
l' 
cottcentrations 
in 
both 
stems 
and 
leaves 
during 
the 
third 
year, 
and 
higher 
Ca
i,..,,,, 
j.'
concentrations 
in 
the 
leaves during 
the 
third 
year.' 
Leaves 
of 
pondvreed'collected
tr. 
at Station 
3 during 
the second 
year 
contained 
higher 
Zn 
concentrat'ions 
than 
those
Xl 
of 
pondweed 
collectecl 
at 
other 
stations.
ii.
,i
F.'.'., 
FISH 
r-; 
,, 
' 
. 
:
,t 
'l
f..,,= 
,           
'                               
: 
: 
ii
i'    
Three species 
of 
fish 
were 
collected 
cluring 
the 
first 
two 
years 
of 
the investi-
i:...,.. 
gation (table'4.2). 
An addjtional 
three 
species 
were 
collected 
duringlthe 
thjro
it,
i,', 
' 
collecting 
periods, 
and 
only 
one each 
at 
Stations 
2 
arrd 
3 
during 
the thircl 
year.
i' 
I'han 
lengths 
and 
weights for 
the fishes 
collected 
during 
the 
individual 
years 
are
l:;::..',,',:.t.,. 
presented.ih 
Appendix 
Tables 
4.K-4.1'1. 
Statistica'l 
cornpar.isons 
of 
fish 
sizes 
at
,. 
the 
four stations 
indicated 
that variation 
in 
size 
at the 
different 
stations 
in
1.. 
any of 
the 
years 
was 
generaily 
non-significant. 
Howeverr 
a 
co{nparjson 
of 
sjzes
i,, 
during 
the entire 
3-year 
period 
showed 
sign'ificant 
increases 
in both 
weight 
and
ii..;.,..,,,, 
lglgth of 
gizzird 
shad 
and black bullheads 
between 
the first 
and 
secondr 
years
i, 
of 
collection and 
lesser increases 
for 
largemouth 
bass 
durjng 
this 
period
l*t' 
(taute4,lo)-' 
. 
,''',
i' 
:
i.': 
, 
:
il.,-,. 
Cunparisons 
of 
annual 
mean 
concentrations 
of 
chernical 
constituents 
in 
g.izzard
$i..,r',. 
, 
shad, black bullheads, 
and 
largemouth 
bass in 
Coffeen 
Lake 
over 
the 
3-year
Fil' 
, 
'period 
are 
presented 
in 
Tables 4.ll-4.13. 
Sirnilar 
comparisons 
for 
indjvidual
fl11 
..: 
istations 
in 
the 
lake 
are 
shown 
in 
Tables 4.14-4.16. 
A 
significant 
overall
*:t.= 
' 
trend 
was noted for 
only one element, 
K. 
There 
was 
a 
significant 
increase.in
f,!i'i
F",:: 
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ai:
Table 
4.1 
1, Annual 
mean 
concentrations 
(rnq/kg 
fresh
it, 
constitugnts' 
in 
musCle 
tissrie:.of-gizzard
, 
, 
!i 
., 
quantities 
Cof feen 
t.ake 
are 
f 
rom 
in 
parentheses.
Septernber 
l978 
{hrotrqh
t issue) 
of 
chernical
shatJ 
co I 
I 
ec 
Led 
at
0ecember 
1980, 
5arnple
l97B-79
( 
33)
1979,80
( 
40)
I 
980=Bl
( 
40)
Me 
an           
Fa
'A9
"As
,B
:Ba:
' 
Ca'
:.:
.cd
Cr
:
LU
FA
Hgo
i-,
K.
rMg
. 
l4n
,Na
.Ni
Pb'
$,
', 
Zn'
<l 3.7
(0;49
, 
.l,50
0.42
1,298.
0.29
0. 56
0.66
l6'.7
54.1 
,
'l 
,174.
223.
3: 
96
5l 5.
0.1 3
0.24
0.54
<l 
.60
<0.56
0.56
0,3'l
I,235. 
'
0.33
<0.12
:
0.58
l0;0
:
28.B
4,09 
5.
2l 
5.
2.90
,7 
35.
<0.t4
(0.1,7
, I 
"59
:
14.6
<3.07
<0.6 
3
, 
0.93
0.39
:
I 
,4 
36.
0.09
, 
.0.51
, 
0.53
, 
1.I. 
2
37.5
16,923.'
'.,'"n'
3.03
553.
<0.1 
2
<0:28
,1.54
:'
, 
'5.90
0.9i
: 
:0'37
| 
,324,
0.23
0.37
0.58
12 
4
34.7
7,783,
247.
3.25
6 35.,
1 ,,27
9.47
(.t 
. 
t
---
3.0
.,J
t2.B
?.6.7
--:---l
1.2
7A
3.6
48 
5.
40. 
B
1
,l.q
8.5
t
I
l'.
I 
l
l'
I
l'
I 
.:
I
aVaJ 
ues., that 
- 
are
. 
between 
yeais.
DConcentrat 
i ons
underscored
ilr€ 
,i 
o ug/kg
indicate 
significant 
differences 
(p<0.05)
fresh 
weight.
4.44
ti... 
.
'
. 
:.a
Table 
4' 
12. 
Annual. 
me0n 
concentr'nt 
fons 
(mg/k9 
fresh 
I 
issue) 
oi 
chernical
:        
constituents 
ln 
muscle 
t{ssue-of 
bldck 
bul lhead 
collect.ed 
,:t
!orf9'i1.Lake 
from 
Septemtrer 
lgTB through 
ftcembcr: 
lgB0, ra'.rrple
quantiiles 
are 
ln 
parentheses,
| 
978-79
( 
t6)
l9i9-80
( 
20),
I 
980-8t
{12)
i4e 
an           
Fa
Aq
:
As
B.
<.|3.7
<0.49
I 
.80
o:5 
3
218.
0,07
1.03
0.73
10.2
994.
207.
0.50
61 3.
0.16
0.54
0.36
7.36
<1.60
<0. 
56
I .20
0,?l
267.
<0.04
0.34
.
0.70,
::
8.45
38. 
5
2.,757,
164. 
,
, 
I,00,
568. 
,i
<0.1 
4
r 
0.40
0.38
:
l 
t.0
<3.0i
<0.5 
3
,
?.. 
?l
' 
0.44
228,
(0.09
]
. 
0.36
' 
0.29
6.04
B?.6
.l4,354.
235.
1 
0.61
:
,'.700.
.<0.14
, 
<0,28
,<0,29
' ' 
'6.46
1.65
, 
0.40
?41 ,
Ba
Cu
cd
Cr
Cu
Fe
Hgb
(:,
.
t'l9
Mn
Na.
Ni
Pb
Se
7.n'
3.6
3.5
0.4
I
, 
0.57
l
0,60
.
, 8.43
50.4
::
5,069:
I 
96.
0.7 4
6r 6.
19.4
1.6
l.l'
4.2
f19, 
''
6.5"
2,8,'
q.u
2.7
0.3.
6.5
0.37
0.35
8.6 
5
. 
between 
years.
lffi.re6.out=...
bconcentritions 
ulg 
in 
gglts 
fresh 
wcight; 
rnissing 
value 
= 
sarnple
quantities 
insufficient-foi 
analysis. 
" 
'r - 
.
I:ri:
I
Iallle 
4.13. 
futnual 
mean 
concentrat ions (rng/kg
I
'  
: 
.   
constituents 
Coffeen 
Lakc 
from,Saptember 
in 
muscle 
tissue-of-
lgZB
,quantities 
are 
ln 
parentheses.
fr-esh 
Lissuci 
of 
chernical
large,nouth 
bass 
collecteC at
thrcugh 
{hcember 
1980. 
Senp )c
t97B-79
(so1
I 979-B0
( 
40)
I 
980-Bl
( 
40)
l1e 
on
r'
Aq
As
' 
<i 
3.7
<0.49
I .6t
0,13
260.
0.17
0.49
:
0.7 
5
,
2:.|3
5l ;0
I 
,1 
25.
267.
0.30
523.
' 
a.23
0.77
1.89
6.1B
<t.60
<0.56
4.6 
3
0.01
:' 
l4l.
<0.04
<0.1 
2
0. 
r 
3
3. 
l9
3t .9
4 
, 
368.
240.
0.75
417.
<0.1 
3
<0.1 
7
l.84
8.,50
<3.07
<0.6 
3
0.55
0.05
J(q.
<0.09
0.60
0.32
2,36
23.1
17,?-3,g.
293.
0.57
438.
<0.12
<0.?-7
I .38
5.47
2,21
0.07
243.
0.08
0.39
0.42
2. s3
36.5
7,08.|.
267 
,
0.52
464.
7t-a
?.0
1l.Q
5.4
17.2
- 
5.1
?-.6
1 
5.8
I9r
, 
28.3
2,?
20. 
B
'l
:l
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l.
.
'l'
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t:
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l 
I,
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1,.
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B
Ba
Ca
Cd
Cr
Cu
Fe
Hgb
K
14g
Mn
Na
Ni
Pb
Se
Zn
0.37
t.72
6.68
il.5
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r 
9.0
aValues 
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between 
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DConcentrations 
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, , 
-a
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,
K concentt'ation 
in,, ul 
I 
t,hree 
'specie.s 
during 
the 
3-year' 
periocl; 
this overall
inctnase 
was a 
ref 
lection 
of tha 
increase 
0t 
caeh 
of 
the 
incliyi<lu,rl st.rt 
iLrr*s.
eonsiden'in9.the 
species,of 
f 
ish 
inclividual 
ly, thcrc 
are 
severai 
elemental 
coli-
tentration 
trends. In 
gizzard 
shad 
{Tables 
4. 
}'l 
and',4.14)', theie 
were 
signif 
i-
.
cant 
: 
. 
decreases 
.:  
: 
in 
the overall 
: 
:
concentrations 
of B, fe, 
and l{g between 
the 
first
and 
second 
years 
of 
the'stud),. 
The 
rjecrease 
inl [J 
concentratiorr 
wds e'/ident 
at
each of the 
four 
stations; 
the 
level of 
Fe 
was 
decreased 
only 
af stations 
I
and 
2,, 
and 
that 0f Hg 
at 
Stations 
i; 3, 
and 
4. 
In 
addition, 
although not
sevbre,enough 
to 
affect 
their-overall levels 
during lhis 
same 
periocl, 
the 
con-
centrations of Cd, Cr, and 
Cu 
in 
gizzard 
shad 
decreased 
at Station 2, Statiorrs
3 
and 4, and, 
Stations 
I and 2, respectively. 
In con,trdst,: 
during 
this 
sante
:
period 
(between 
the first and seconrJ 
years), 
the concentration 
of 
Se 
in 
gizrard
shad 
increased 
at all four 
stations, significantly at Stations I 
and 2 
and
non-significantly 
at 
the 
other 
two. 
The 
single' overal I 
concentration 
, 
trend
.(decrease) 
noted 
in 
gizzard 
shad between,:ihe second and third 
yeal's 
occurred 
in
,the 
case of'Cdi 
the'location:contributinq nost 
notably to the overall'concen-
tration 
decrease was 
Station'1. 
There 
were 
significant 
changes 
in 
the 
station
distributions of some 
of 
the chemical 
constituents 
in 
gizzard 
shad 
from 
year
ro 
year 
(Appenorx.,Tables 
4.N-4.P). 
The 
elgnents showing 
progressive 
decreases
in 
concentration fronr 
Station 
1 
to Station 
4 were 
prinrarily 
those referred t,o
above.
Concentration trencls 
in the case 
of black,bullheacJs 
(Tabies,4.12 
and 
4.i5) 
,'
are sonpwhat 
difficult 
to 
assess, 
since these fish 
were 
not available 
at
,station 
l 
(the 
heated 
station) 
during 
the firs't'and 
third 
years.' 
0nly'Cr 
showed
a significant 
decrease in 
overal'l 
concentration 
between 
the 
first and 
second:
years,,and 
this 
decrease tllas evident 
at each of 
tlre three stations 
(?-,,3, 
.'
and 4). 
Hg 
registered 
a signifjcant 
overall 
concentration increase between 
'
,ihe 
second 
and third 
years, 
and 
th'is 
inorease was 
primarily 
a 
reflection of,.
' 
the 
increases 
..:  
.:.
at Stations 
2 
and 3. Thcrgh not sufficient to 
affect 
the 
overal'l
'eoncentrations 
of"these'elements, 
Ba, 
Ca, and Na increased 
in concentfation 
at
Stations 
2 and 
3 during the 
three 
years. 
The differences 
in 
elernental concerr-
:::: 
L
'lrritions 
between:s'tations 
for' individual 
years'are presenled 
in Appendix 
Tables
,l: 
.' 
..    
'.':
4.0- 
4. S .
::: 
''.. 
, 
j:. 
-." 
,,, 
,:i 
':        
'.        
,. 
:'                 
' 
: 
,
.:
=
4 
.53
T=
':::.
l 
: 
, 
:                                 
, 
,'-, 
,
l,
In 
largc.rnoulh 
bass 
(Tables 
4,13 
and 
4,16), 
tlre 
overal I conccntration 
of' 
lig
.:', 
..                
:    
'
decreased 
significantly 
during 
the three 
years, 
a 
reflection 
of the 
decrr:ased
levels at Stations I and 2 during 
these 
years. 
There 
rrel:e 
significant 
de-
creases 
in 
the 
overall 
levels of 
Cu, 
lla, 
and Pb 
between 
l"hc 
fjrsL a')d second
years; 
Stations 
3 and 
4 were 
the 
prinrary 
locations 
of the 
decreasetJ concen-
trations 
of'the 
three elements, 
The 
overall 
concehtr.ation 
of Se decreased
significantly between 
the second 
and 
thipfl.:years;'this was 
probably 
a 
reflec-
tioh,'of 
the decreased levels 
at Stations 
3.and 4 between these 
years, 
Se 
was
one'of 
the,few elernents 
in'larganouth 
bass'that 
showed d 
progressive 
decrease
in,concentration 
frun 
Station 
I to.Station 4 
(Appendix 
Tables 
4.T-4.V):
',,, 
' 
. 
'.' 
.: 
i
The 
main 
cunparisons 
to 
be 
made 
foi 
carp, 
b'luegill.s, anti 
channel 
catfish,
since 
they 
were collected only during 
the.third 
year 
of the study, 
are 
.''''
between-station 
cornparisons 
of elernental 
concentrations 
(Tables 
4.17-4,Ig).
There 
was 
no significant difference between stations for most 
of 
the
elements. 0f the 
feu 
exceptions, 
I 
and 
Se,.'general]y decreased 
in concen-
:: 
,           
,'.          
. 
.., 
....- 
, 
t 
:.          
,  
:
tration 
proqressively 
from Station I to Station 
4; 
this 
trend 
occurred
for"al I three 
species. There 
was 
no appaient trend 
for 
'rlg 
concentrati 
on:,ljn
!t.     
:
any,.of the 
species, although 
the 
differences 
between stations 
in 
the case
of 
carp 
and 
bluegills 
were fairly large.
I
l
I
l.
I
:: 
:l
': 
l.
.. 
:::
,:,
:
..::
a        
: 
l:.-:.,
jI'
't 
l'
'' 
I'
l
l=
l'
t",-.:
f'
',:'t.,..
l=
:- 
;:--
'}
.   
.:::
a::"::   
.:::::
.:
4.54
:::.::
.a:' 
.
c     
i tuents
980-81 
.
=
l.
I
2,
2.
l.l
.l-g-
4.r
'1.(
l.
0.;
*:
{t.
0.;
on5 
t
in I
_;
_;
z0
2A
20
20
20
2A
20
20
2D
20
20
20
20
20
,20
2A
20
a.?
1.6
t.B
?,o
2.7,
0,6
1.0
4{
4.0
j
t:0
1.3
0.2
3,5.
0.2
I.
aValues 
that,are 
underscored
between 
stations.
bConcentrations 
are in 
ug/kg
indicate 
significant 
differences (p<0.05)
r 
resn 
wel 
gnt 
.
.                                  
i.
4. 
55
iir 
': 
,,.
;:1., 
.,,;.., 
'
?,,1.'1:,,; 
'' ,
i;,, ,'; ,
il'.','
i;,;":,' 
'' 
,t
fi','',. 
',.'
i:.,
i.;t 
,.,
i-i::li' 
' 
:' 
1
ir: 
tt,  
t 
''
:':,], 
I   
,
.l. 
,.
_ 
tt.--.'. 
. 
.
Tab.le,.4.lB,  
l"lean 
concentrat,i'ons 
{mq/kg 
fresh
in 
bluegill 
co'l'lected 
at iarious
r 
980-Bl 
.
tissus) 
of 
chernical constituenis
statiorrs 
at 
Coffeen Lake 
in
Stat 
lon 
I     
St 
at ion 
2     
Statlon 
3     
St at 
lon 
4       
i4rl a n               
Fa
Ag.'r 
<3.07
' 
I:'
Ar 
, . 
<0.63
3 
'- 
, 
5,7?
Ba 
: 
0.10
Ca 
,' 
' 
922,
cd 
-,,-
<0.09
cr 
,' 
'  
0.47
'.t:
Cu   
0.24
Fe' 
, 
3.78
i
Hgb 
.  
35.0
K 
,,,. 
15,277.
Mq  
279.
','t. 
. 
'''
Mn''.' 
1.06
Na 
: 
.
737.
Ni 
.   
<0.1 2
.:
Pb:.':r. 
' 
<0.?_7
Se,. 
.  
1.. 
.'. 
.  
i
I.38
...
2n;,;. , 
,; 
8.22
<3.,07
<0.63
5.37
0.12
956,
:
<0.09
0.50
0.3?
3,4?
74.3.
l5,BB4. 
,,
286.
l.14
772.
<0.12
:
<0,27
:
I .37
9.'83
<3.04
<0.63
5.12
0.06
BBO.
, 
<0.09
0.35
0.r0
4. 96
I 
02.
t 
3,09/.
241 
,
0. 75
782.
<0.1 
2
<0.27
1.42
9.49
<3.07
<0.63
5.24
. 
0,16
I,062.
0.10
0,:34
0,13
:
3.'90
72.9 
.
| 2,427 .,' 
,
238.,
.0.'93'
. 
: 
::
792,' 
' 
'
::'
0.,]9
<0.27
. a, 
-'
0,6?
8" 67
?0
?Q
5.36 20
0.!r 20
9s5. 
20
'20
0.42 
20
0.20 
20
4.0r 
20
6?.. 
|  
2A
l4,t7l. 
20
261. 
20
0,97 
20
771. 
20
2A
20
l.l9 
20
9.05 20
6.I
t.J
I
I
I
t
I
I
I
t
I
t
I
t
I
I
I
u,f,
I:-3
:
0.?
I\
,:
::-
:
3.9
0.4,
2.0
'4 
.4
:-:::
s.1
0.4
'0.'3
.afalues 
that^ 
are underscored 
ind'icate 
signi 
f 
icant dif 
ferences 
($0.05)
between 
stations.
bConcentrations 
are 
in 
uglkg fresh 
weight.                                       
I
l'
l
.:l 
:
4. 56
i:,:t):;i,:.::
.a 
:
Tabl 
e 
4. 
:..' 
| 
9. Hean 
i n 
channel 
concentr 
c af'f 
at 
.i 
i 
on 
sh
s
.::  
,  
in 
l9B0-Bl. 
,'
(nq/fq, 
fresh 
Lirsue)
col lected at 
var''ioirs
of 
ch*oical 
constituentE
slaLlons at Coffeen 
Lake
Station'l   
Statlon 
2     
5t 
at ion 
3     
St 
at 
ion 
4      
Mean
t-t
Ag
As
cd  
. 
0.12
<3. 
07
(0.6 
3
, 
5.43
0. 21
I 
60.
, 
0.69
0. 
s0
, 
5.09
. 
14.7
I 
8,770.
?.76.
,0.49
658.
0.14
<0.27,
0.9?
10.2
' 
<3.07
'<0.63
4.71
0.05
, 
136.
,, 
<0.09
0.44
', 
0.34
6.63-
. 
30.2'
,
I 6,1 45.
..
232.
' 
o.52
631 
.
, 
<0.1 
2
<0.27
, 
0.98
. 
7.31
,, 
, 
(3.04
, 
<0.63
,, 
4,76
0. 
t6
',282.
.
0. 
r0
0.59
:
0.47
'. 
-:
. 
10.r.
' 
35.4 
'
I 
5,850.
221. 
,
' 
0.51
61 
0.
.t 
: :
0.14
' 
<0.27
0. 
70
.rr 7. 
40
. 
<3.07
, 
,0.6,3
4.67
, 
0.r0
16 
3.
, 
(0.09
, 
0.57
0.37
'' 
25.4
I 
6,891 .
' 
zil.
0.34
,802.
<0..l 
2
,', 
<0,27
0.59
' 
7.39
ti
LV
:
20
5.t 
4 2A
I
0. 13 
20
' 
185. 
,., 
2A
2A
LV
' 
0.58 
20
0.42 ?0
6.67 
20
, 
26.9 
2A
I 6,194. 
20
235. ?-0
:
4.47 20
675. 
20
0.1 2 
20'
2A
0.80 ?0
.
B.0B 
2A
Ba
Ca
Cr
UU
Fe.
Hgb
K,
Mg
Mn
',
N;.
Ni
Pb
Se
7n'
9:'5
l;B
l?
2.?
,
0.6
0,8
0.5
.t.
2.8
l-9-
0.9
4:l
=:_
0,4
:
2..5
3,7
aValues,that 
are underscored
between stations.
bConcentrations 
are in ug/kg
iindicate 
signif 
icant differences 
($O.OS;
:"
fresh 
wei 
ght 
.
4.57
: 
-  
t. 
:
.:l: 
. 
j
.:,i;l:,=;;;..:.r;,-: 
. 
r.'-,.:..,.,
:,'. 
,' 
,:;.t'rti:
:.:
.:
0tscrJSSt0H
t-. 
,,1. 
,1.
Two 
of 
the 
questions 
addressed 
in 
the 
second-year 
repot't 
(Andar.son 
eL 
dl, 
lg{iO)
are 
applicable 
to the 
final 
report. First, 
did 
the 
concentrat.ions 
oi 
any 
of
the 
chemical 
constituents 
in 
the 
lake's 
ecosystenr 
increase 
or decreasc durinq
', 
the 
J-year 
period? 
Second, are 
any 
of 
the 
constituents 
present 
in sufficientiy 
:
,high'concentration 
to be 
environrnentally 
damaging, 
to contaminate 
fish, 
or 
to
'pose, 
a 
human 
heal th 
problem?
l'li tli 
regard 
to 
the f irst 
question, 
the 
changes 
in 
concentration 
of 
chem'ical
'constituents 
over 
the 3-year 
period 
are rlepicted 
in Fig. 
4.5. The 
levels 
of
the constituents 
in 
the various 
types 
of 
samples analyzed 
(setliments, 
two
species 
of 
plants, 
and 
six species 
of 
fish) were 
quite 
variable. Five 
clements
'(Cd, 
cr,iCu, 
Hg, and 
Ni) showed moderate 
to strong 
decreasing 
concentration
trends 
in most 
components 
of 
the lake's 
ecosysten 
during 
the 3-year 
period.
Three 
of these 
elements, 
Cd, 
Cr, 
and 
Hg, are 
recognized 
environmental 
contanri-
nants 
(they 
appear 
on the U.S. 
Environmen'tal"Protection 
Agency's 
ljst 
of
:priority 
polJutants; 
callahan 
et al.'1979); 
therefore, any 
reductjon 
in their
concentrations 
points 
toward 
effective 
c)ean-up 
procedures. 
0rr 
the other 
hand,
',the"concentration 
of one 
element, 
K, 
increased 
inlalI 
.samples 
except 
sedjment
duringthesameperiod.Pbconcentrationswerebelowthedetectionlirnitof..
the analytical 
instrument 
for 
most 
of the 
samples; 
the 
detection 
l.imit 
varies
with the 
type of sample 
being 
analyzed.
,          
..  
:
,Equal'ly 
impor:tant 
in answering 
:th" 
first'question'.is 
the 
trend 
in 
concentrations
oi chemical constituents 
from Station 
1 to Station 
4. 
Since 
the discharge 
from
.'theslag.and..flyashpondswasa]lowedtodra.inintothelake.nearStation1.
:,.during 
the 
period',which 
ended 
vrith the completion 
of 
the fjrst 
year 
of 
this study,
l,'it 
seemed likely 
that 
contponents 
of 
the 
lake's 
ecosysten at 
this station 
would
contain 
higher 
concentrations 
of 
some, if 
not all, 
chemical 
constituents 
than
ecosystem components 
elsewhere 
jn 
the 
lake. 
Only a few 
constituents 
showed 
con-
'icentration 
trends, 
andl'these 
trends were 
quite 
variable in rnagnitude. 
During
the 
first 
year, 
Cd and Cu 
concentrations 
in 
sedinpnt and 
gizzard 
shad 
clecreased
.fron 
the cooling'loop-to the arnbient 
area. 
The fact 
that 
the same.trend 
occurred
in shad 
as in sediment is not 
surprising, 
since 
this fish 
is 
a forage 
fish.
.-- 4. 
58
:      
:l:
i:-
T
l,
t
T
'a
t
T
I
t
I
t
I
I
I
T
T
:'  
r 
: 
:l
Some 
additional 
decreasing 
Lrentls flon 
SLation 
I 
to StoLion 
/r 
riere noLed 
tluring
the 
thiid 
year:tB, 
Cd, and 
l{g 
in 
se<ilnent 
cores; 
So 
in 
largemouth bass, bltie-
gills, 
and 
channel 
cat.fish; 
and 
K 
in 
carp, l:lucgiljs, and 
charinel catfish.
t{hy 
sotne 
of these 
trenrls 
showed up 
as late 
o's the 
fhird 
Tear 
is 
iruze'ling', 
since
the'conditions 
to enhance 
lake ecosystem 
quality 
were 
implementetJ 
jlrnost 
trro
yearS 
earlier. 
However, 
in 
the 
case cf 
sedi:!1ent 
cores, 
the 
layers 
(referred 
to
ds segments 
in the 
present 
report) 
of 
sediment 
were 
laid down 
during the whole
period 
of 
evolutjon of 
the 
lake. l{evertheless, 
the 
greatest 
increases in 
con-
centration 
of 
the three 
constituents 
in 
qucstion 
occurred in 
the upper 
one 0r
two 
segments, 
representing 
recent 
deposits. 
!,lhen 
one 
consjders that the ldke
is a 
relative)y 
deep impoundment 
and 
therefore sedjments 
nray not be subject 
to
wind and utave 
action 
to the 
extent 
found 
in 
a 
shallower lake, 
it is 
possible
;egments 
represent 
more 
than 
just 
the 
rnost 
recent 
year 
0r two.
Several 
other 
factors contributed 
to the 
lack of sufficient 
trend 
evidence
betleen 
the 
first and 
second 
years 
and 
between 
Stations 
I and 
4. Too 
few macro-
phyte 
samples 
were 
collected during 
ttre iirst 
year, 
a 
iritical 
year 
jn 
the
'ibefore-after" 
evaluation 
of 
the r,raste 
disposal 
inrproventents, 
for 
valid statis-
tical 
comparison 
with 
samples 
collected during 
subsequent 
years. 
ilo 
Arnerican
pondweed 
was found at Station 
l 
during 
any 
of the.yea)'s, and 
no black 
bullheads
durring 
the first and 
thjrd 
years, 
naking 
it impossible 
to 
determine 
what 
effect
this 
station nright 
have had on the 
chernical 
constituent 
concentrations of 
these
two ecosystem 
components. 
Based on 
the frndings 
of Mayes 
et 
al. 
(1972) 
and
l'ludroch 
and 
Capobianco 
(1979), 
we 
might 
expect 
to have found 
that 
the concentra-
tion 
trends between stations evident 
in 
the'sediments 
cluring 
the fjrst 
year 
were
reflected 
in 
the macrophytes.
Considering 
the 
general 
decreasing concentration 
trends 
in the various 
com-
ponents 
of the lake's ecosystem over 
the 3-year 
period, 
an adjunct 
to 
the
first'question.is: l,lhere 
did these:elentents 
go? 
The outflow 
fronr 
the lake 
'is
nonnally'not 
very:1arge'and 
probably,would 
not 
account 
for 
the apparent 
decrease
in 
elenentall concentrations. However', tltu 
flood 
concli tions 
that 
w'ere 
prevalcnt
in 
the'spring 
of tgZg 
(see 
Section.3) resulted 
in 
dilution 
of the 
elenents-dii-
'
9ol.ved, 
in'th.e lake 
water. 
Subsequent discharge of 
the'excess 
volume.of 
water
oveithe.spil]wayin.effeitdepletedihe.]akeof:aiign.ificantquantityofits
:i-  
:
I
ihenrical 
constituents. 
tn 
[ur-n, 
the uptak,e 
of these cner*ical const 
j 
tuents hry 
_
I
other 
components 
of the 
laLe's 
ecosystem 
was 
reduced. 
I
There 
are 
at 
least two 
other factors 
that 
may 
have 
contributer! to the 
decr.easing
trends. 
Thus 
far, 
r.ro 
yearly 
measurements 
have been 
conrJucted 
on ihe standing
crop of 
macrophytes 
in 
the 
lake. 
l,lhile 
the elsnenf.al 
concentrations in these
plants 
have decrease<i 
from 
year 
to 
year, 
it is 
possible 
that the total biomass
of 
the 
plants 
may 
have increased 
during 
the same 
period. 
Distribution 
of 
a
constant 
guantity 
of elements 
within 
the 
increased 
bicrnass 
vtould 
result 
in 
an
apparent 
decrease 
in 
concentration 
of the 
elements.
Another 
alternative 
might 
involve 
the number. 
of fishes 
taken 
by fishennen. 
Al-
though 
the 
lake 
js 
c'tosed 
to 
public 
fishing, 
a large number 
of 
"trespassing''
fishermen 
avail 
ihemselves 
of the opportunity 
in 
any 
given 
season. 
If 
large
quantities 
of 
fish are 
taken from 
the lake, and 
if 
there is a 
reduction in 
the
quantities 
of 
chemical constituents 
being added 
to 
the'lake's 
ecosystenr 
(by
virLue of 
the recent modifications 
of 
discharge 
disposol at 
the 
power 
plant),
there would be 
a 
gradual 
reductiort 
in 
elemental 
concentrations 
in 
the 
fishes,
especiall;,as 
nelv 
crops 
of 
fishes 
appear.
, The answer 
to the 
second 
question 
can 
be 
approached 
by considering 
the 
concentra-
tions of chemical 
constituents 
that sometimes 
accumulate 
to undesirable levels
in 
aquatic 
ecosystems; 
these 
include 
cd, 
cr, Hg, Pb, 
and se, 
As nrentioned 
above,
Pb 
concentrations 
were below 
the 
detection 
limit 
of 
the 
analytical 
instrument 
for
most 
of 
the 
samples. 0f 
the four ecosysten 
components 
showing nreasurable 
Pb 
con-
centratjons during 
the 
first 
year (pondweed, 
gizzard 
shad, black 
bullheads, 
and
largemouth bass), 
on'ly the bullheads 
contained 
measurable 
concerrtrations 
during
of 
the ecosystem 
components 
contajnect 
measur-
ahr. levels of Pb during 
the 
final 
year 
of 
the investigatior, 
n 
gratifying
, 
findin^g 
when improvement 
in'enviionmental 
quality 
is 
the 
aim.,
.
..rAtchiion 
et 
al. 
(1977) 
and 
Murphy'et al. 
(lgi8) 
have 
pointed 
out 
that fishes 
in.
:ecosystems 
contaminated 
with 
high levels of 
Cd and Zn take 
up substantially
lhigher 
quantities 
of,,these 
elements than 
do 
fishes'in 
uncontanrinated 
ecosystens.
They 
conclude 
that the relative 
levels of 
these elements 
in fishes 
correlate
I
t
I 
:i
t
I
I
I
I 
:
I
t
I
I
I 
,
t
:l: 
j
,,:: 
r: 
::
r 
: 
,.1:
.:'....-
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rlrli 
r 
i i 
,.. 
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-i'r:r: 
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for 
Cr; 
althtruglr 
the decraases 
<jjii 
ni-rl ;i;r[:!-r:;;r:i! 
ti;i- 
:i:-..i,,
abiltty. 
'lltese 
decreaskrg, 
Lrc,rrds 
jrre 
r€f :ec{.ir:!::; r,: 
:,i;,..,: 
;.r:, 
.ir-,,
occurred 
in 
the 
surrsurdinp- 
milieu.
ltre 
rgnaitiing 
t-wrr elenents 
eif 
envirorr''snt..rl 
{.lr.'lr:.ur-r 
;rrrt 
if'.u.'ej 
ir.. 
&l e-,"jris=i 
i;-,
Fig; 
4.5, llg 
concencration-s 
decreased 
ln 
all 
ecr.rs.ii;rrj:.i 
crnrrl:ir{.r?,r 
{:ricff, 
l,i;ir_k
buLlheads 
during 
rhe 3-year periocl 
. 
Jhcsc trrgrds..rir:lrt.*i.-.ll 
ii',,,5,1- 
!,:rt.i.t. 
;rr.r'
prosented 
nurrerically 
in 
thble 
4.20, 
Se..'cral 
ln.sr];ii.il,itt.t-it'J, 
r,iliid 
c..r ,.1 
i. 
::i{+,
Speyer 
1980) 
had indicateJ 
rlrac 
Se 
lwly sr;pr:-r:ss 
tlie l:jr;;ir.'r:r-r:r.rl.,i!"jr*i:-,1 
i!: 
.:i':rr.r.i
be 
proteccive 
againsr 
roxic 
effecrs trf lir-i 
in 
fishes. 
'i'l:e 
ri,r:..r 
i:: 
T;:ir!e 
i 
j*:irsTiesis
rhat 
j-n 
coffeen 
lake 
se may 
srpFrcss 
thc bitxrcn-ur.:l;lri(!r 
r:f 
lil 
i,,', 
ir.izt,tz.i! 
s!:,ri, 
l;r.:.,
not in 
largonxfh 
bass.
ltrere 
has 
beett concent 
ahottt 
the rcl>rcxluc'-ivc 
l'irilurc 
cj'Jlisi:c-s 
i::lr,.ilrir-i:i1: 
i;ii1,1
confaminaced 
witfi Se. 
Itt l.a!<es 
not 
sub.ject 
Ln cxlxlslrr(r 
lti in,hl;iri.rl 
;$lijir.,i 
r:lrt-
tnercial 
wastes, 
the 
concentr;rtion 
of 
Se in 
fish 
nr.:.scJc r.rl'ri,,. 
e:r.rc.e<l.s 
I nir:
(I'akkala 
er al 
. L972, May 
antl 
llcKinney lgSl). 
!'islr 
rep:',;,rJuci 
ir.::.i in s;r.:r:ii 
i;:i<r..,r 
jr,,
usually 
nonnaL. 
Ctlrbie and V;rn 
Honr 
(1978) 
rerxir.rcrj 
tixrt 
l:i.,rlx.s 
fr.rn: 
ilrc 
mjn
portion 
of a ccnl-ing 
lake 
fcrr 
a coal-fircd 
lr.:rr'er 
pl;rnt 
in li-.rrtli 
(l-::rr.ljjni 
i-ri.x";: 
riinei:
Se aclevels rangirrg 
frsn 10 
to 
50 
prm. 
Rcprtxlucticar 
irr 
thtrsr-: !'isirc:;'^'as 
rr,rrke.ci:...,
reducecl 
. C,onversely, 
Chese investi.p,ators 
fotsld 
th.rt 
the Su 
ccl';c(:ntrar-il!.:s 
ii-l
fishes frcrn 
a 
renote 
(urrconcamlnated) 
frurrion 
of thc 
l;tkc r'ruu'.rrrl 
!'rtrn 
6.] 
i,1 i.{l
ppn. 
Ttrese fish 
reproduced 
norm:lly.
Since 
both Coffeen lake 
(rhe 
subjcct 
of the 
prescnt 
;itu(ly) atxl 
l;rkc 
Sani,,clrris
(located 
approximately: 45 miles 
north 
of C.of 
feen l-lke) 
are 
crxrl i.rrg 
l;ikes 
f(rr t:c.',r 
j 
-
fired 
pourer plancs, 
tlrere is 
concenr Lhac 
thc fj.shc.s 
irr 
lxrrh 
of 
rhese 
l;rkcs rnry
contajl high 
levels 
of Se ancl 
nury 
thtr-s 
pose 
a hrrnu'r 
he.utcir 
lrroblsn. As 
er,rirlcnt
in Table 
4.20, 
the annual 
IIEan concentrations 
of Se in si-x 
spoci.cs 
r;t. 
fish 
take-n
frqn Coffeen Iake 
beueen 
1978 
and 1981. 
rang,,ed l:rrnr 
less 
tlun 
tlrc 
cJeccction 
lirnit
fil
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rrnrl*:rt;ir:rr 
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ili,iqy 
i:rii.r 
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determine 
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conslderable 
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qroups 
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5rlen
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effects 
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stress situationg 
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the lriotd 
nrc 
often r0 
srlbli'; 
Inal
sturlying 
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orgdnisms 
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conclition of 
that 
borly 
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it 
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qrrile 
irnporLant 
Lc
stirtly 
groups 
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f 
rom dif 
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trophic levels 
to 
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nn assassrrent uf
an aquatic 
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important 
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as 
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they 
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much 
of 
the 
organ 
i 
c 
mater i 
a 
l 
consumed 
lr.y the 
"h 
iglr0r 
" 
Ir'opn 
ic
levels. Algae, including 
phytoplankton 
('isuspenderl" 
algae) anrl 
peripliylorr
(attached 
algae)t 
dre 
not 
only useful as 
water 
qualit-v 
indicators anrl 
as 
prinary
producerstlfoxygeniltaquaticenvironments,ttuttheyalsoait|indeLermininq
the 
trophic state 
of a 
body 
of 
water. Based 
on 
thosc 
concepts, 
invesLigalions'
of 
the 
phytoplankton 
and 
periphyton 
corffrrulriLies 
of 
Coffeen 
Lake 
were underlaken.
io 
satisfy 
the following 
objectives: 
(l 
) 
to delerrnine 
rlifferences beiween
'phytoplankton 
species c'rnposilion and abunrJance 
in 
clifferent 
areas 
of 
Coffeen
Lake, 
(2) 
to 
evaluate 
periphyton 
colonization of 
glass 
slirles 
in tire 
intoke and
rlischarge 
areas of 
the 
lake, 
(3) 
to 
estimate 
prirnary 
protlucLion 
raLes 
in heated
and 
ambient areas of Coffeen Lake, 
(a) 
to 
r;se 
data on 
phytoplankton, 
periphyton,
and 
prirnary 
production 
to 
characterize Coffeen 
l-ake 
in 
relation 
to other
t'llinois lakes, 
and 
(5) 
to determine 
the 
cffects of 
power 
plant 
operation orr 
the
phytop'lankton, 
periphyton, 
and 
primary 
production 
in 
Coffeen 
Lake.
Hfiltil 
iALS 
Ar{il 
f4l:ii!ii*-c,
PI,IYIOPLANKTON
Iriplicate 
phytoplankton 
sarnples 
wer0 
c0llcct.r:rl 
rrorilr!.y 
frrrir 
?l{,ltrly l.l/ll
through 
l5 
Septernber 
l9B0 
aL f 
our 
lake 
statiorrr 
(i.e,, 
StaIions l, 
Z, 
j, 
ctnci 
4,
respectively) 
(Figure 
1.2). 
A 
phyloolankLon 
sample 
consistarj 
of 
,r 
rnc,-i 
iter
': 
',. 
sample 
of 
rteptlr-integrated 
water 
taken from 
Lhe 
surface 
to 
[he bottam 
of thr:
euph0tic 
rone. 
0ne-l 
iter 
samples 
were 
also 
lakerr 
near the 
lake 
bot.tom 
wiLh a
, 
' , 
Kcitrnerer 
watet' 
sampler 
at the four 
major I 
ake 
stations 
durinq the 
sdile tinte
pr:riod 
ancl 
al a depth 
of 6m at the 
power 
planL 
inLake 
frorn 
Sepleqrber l9/9
witlr 
l0 
ml of acidjf 
ied 
Lugol's 
solution. 
The 
sa,nples 
were retrrrnerl 
to 
lre
-i-,"laboratory 
where they 
were 
allowed 
i,o 
settle 
for 
approximaLely 
Z 
days. 
The
- 
',' 
water 
that 
the 
was 
final:volume 
t^ernoved f 
rom 
of 
each 
water 
sanrple. 
and 
organisms 
usinq 
a suction 
was 50 
hose 
rn'1. 
anct 
Three 
a 
,,j,, 
subsamples 
siiapetl 
tube 
from
so
,.:, 
each 
of 
two 
replicate 
sarnples 
f 
rorn 
each 
stat ion 
were 
place<l 
in 
Lhree
',':'Palmer-Maloney 
nannoplankton 
cells 
and 
l'our 
visible f 
ielrJs 
from 
each 
cell werc
examined 
at 
400x. 
AlI non-diatom 
algae 
were identifed 
Lo 
tire lowest 
possiblt:
taxon 
and 
cliatoms bJere 
recorded 
as 
centric, 
penrlatL', 
or 
[9lq!-Ua 
spp,, 
with 
Lhe
exception 
of Rhizosolenia 
spp. 
and Skeletonema. 
potarnos 
whiclr 
r.rer.e 
jrjenlif 
iecl 
to
:'.,'sP€cjes 
when 
possible. 
Perrnanent 
diatom 
slides 
wele 
prepared 
for 
spccific
identifications 
by 
cleaning 
a 
suhsample 
of a 
qiven 
sample 
slurry 
acc6rrlipg 
to
modified 
methods 
of Van 
der tlerff 
(1953) 
and mounting 
the 
diatoms 
in 
Hyrax.
0iatorn 
valves 
were 
counted 
and identified 
at 
1,000x 
or 
I,250x in 
ranrlom
transects 
and 
the 
densities 
of cliatoms 
in the 
original 
sarnples 
were 
comprrted 
by
.,,,'-combirting 
relative 
abundance 
est'imates 
f 
rorn 
diatom 
sl itjes 
with 
centric,, 
1)ennate,
and Melosira 
spp. 
counts f 
rom the 
Palmer-Maloney 
charnbers. 
Non-di 
atorn rlens 
ities
in 
the 
original'samples 
were 
comprlted 
using the 
appf"opriaLe 
multipl 
ication
factors. 
Phytoplankton 
were 
reported 
in 
algal 
units 
per 
liter; 
an 
algal 
unit
:
was ctef ined as 
f 
ol lows:
:1:',':,,1.:;:1; 
' 
:'t 
t 
tl 
'
,, 
.=,;-'',;,,;: 
; 
,:' 
:',,':'                    
: 
.,'
'".1' 
5.4
I
I
I
t
I
T
T
I
I
T
I
I
T
I
t
I
-'l'
':, 
',
-'-
i,-, 
.l:.,
..J
ALGAL 
FORH
itil ce'llul 
a'r
Colonial,
,t 
i
F,i 
l amentous
:- 
ciiLLS' 
PEn iJf{l 
?
*e 
ac 
h,ceTT-6i 
tliaia6-Tr 
irs t','i 
c
-4 
ccIIs 
cxcept 
bIueqre,.rn 
,f 
i1nl
witlr"'eel 
ls'less 
Lhan 
trwcr 
Elricrcrn:
in 
rlianrcLcr 
ln 
50 cell 
unri.s
-100 
m'icron 
lengLhs ,   
'
rl
Taxonomic keys 
used 
for 
algal 
irlentif icatiorrs 
inclu,JecJ 
H,isttrlt 
(lg3C), 
Snith
(1950), 
Prescott 
{1962}', 
Patrick 
uno''R*imer' 
(1966}, 
Iif 
f 
arry 
onrJ 
itrirton 
(l9zl 
),
anrJ' 
Patrick 
and 
Reimer 
(1975). 
'
': 
I                     
: 
, 
t 
- 
',
',
PRII4ARY 
PRODUCTION 
:        
:
Pritnary 
production 
measurements 
were made 
at. Staf 
ions 
I 
, 
?-, a.vJ 
frorn 
the intake
area 
(Figure 
1.2) 
bintonthly 
from 
September 
l97B through 
January lgSl 
arrrl 
aL 
l'
staiiorr 
4'birnonthly 
fr:om 
March 
1979 througlr 
Januar-y 
lg8l 
using oxyqenl 
.
methodolooy. 
Integrated 
water 
sarnples 
collected 
fr:om 
the 
euphotic 
zone 
were
pl 
aced 
in 
'l 
ight 
(c 
lear 
) 
ancl 
dark 
(opaque) 
bot,t 
l esi" and 
tlre rJ issolvcrt 
orygun 
:' 
,
concentrations 
were deterrnined 
using 
a 
YSI oxygen 
meter 
(,SepLemher 
l97B) and
l'linkler 
methods' 
(Novernber 
l978 ttrrouglr 
Jarruary 
lgBl 
) 
accord 
ing 
lo 
Standard 
'
l'let,hods (APHA 
et al. 
1976). 
The I iqht 
and' dark 
bottles 
were 
suspended 
jn 
the
water 
at the 
surface, 
l-meter, 
and 
2+neter depths, 
After 
J 
Lo 
5 hours 
of
incubation, 
the 
oxygen 
concentrations 
were 
determinec.l 
again. 
The rates 
of neL
productionrwere'determined 
using methods 
<Jescribed 
by APIIA 
et 
al. 
( 
19i6). 
Ihe
euphotic'zone 
depth 
and 
an 
pyranometel. 
chart of 
sotar rarJiation 
durirrg 
each day
used 
for 
prirnary productivity 
were 
userl to 
calculaLe 
the net 
er:photic 
zone
primary 
prorluctivit.y 
in 
o2/n2/aay 
ancJ i n 
02/g.Kcar 
of solar 
rasli'at 
ion. 
.
PER I 
PHYTON
Periphyton,was 
co'llected 
quarterly 
oh'glass 
slides 
suspenOert 
for 
28 
clays 
in
floating 
periphyton 
samplers 
at a depth 
of approximatel.y 
0.025 rn. 
Quarterly
collections were 
made from August 
l97B 
through 
February 
l9Bl. 
Triplicate 
slides
wer'e' col le-cted at each''of 
tworsamp'ling 
s'uations 
locate 
d 
near 
tlte 
Discharge 
an'd
.
Intake areas 
of Coffeen 
Lake on 
all eleverr 
sampling 
dates 
ancl 
at Statjon 
I 
and
. 
.,..-: 
):. .:,:
the 
dam area 
on 
the 
last 
six'samplihg'dates. 
At the 
time 
of collection, 
eac5,
,:..:
.,tr
:':t:,4
,i 
l=
:..:
slide 
t{as 
preser-verJ 
intdcl,,in 
hottles 
corrLaining 
? 
ml 
of 
,aciitif 
ied,Lur1ol,s
solution, 
and 
O: 
mt 
of 
water'. 
Scrapings f 
rorn 
Cuplicale 
lglirles';rerrr:sti.r,,ij.i,r
llaring-blender 
and 
diluterl 
te 
a 
known 
volume 
(e.!., 
b0rnli. 
ii,*.algae 
irr 
itr:e
sarnples 
werc 
Lhen 
irJerrtif 
ied 
,rnrJ 
counted by ilic 
,u,,,a 
n.o.odures 
ort 
Iine,l rol.
phytoplankton 
samples 
exceot that 
the 
dppropriatc 
rnultiplic.rtiorlifoeluru 
onio
used 
to 
give 
densitios 
in algal rrnits per 
l0 
cn2.
Af.IC I 
LLARY MEASUREMENIS
.:
,:'
:
t\ncillOry 
medsrrrernents 
including 
temperature,,pH, 
salinity, 
r!issolved 
oxygen,
liqht 
penetratiott, 
light 
intensity, 
and 
conductivity'*ere 
taken 
at the 
surface
at 
the time 
of sampling 
for 
phytoplankton 
collections 
and 
primary 
prorluctivit.y
measurements 
and twice 
during 
e)/.posure 
of 
periphyton 
slides.
STATI 
SI ICAL 
PROCEDURES
Data 
for 
phytoplankton 
totdl 
anct 
major 
group 
rJensities, 
phytoplankton 
prirnary
productivity, 
periphyton 
major 
group 
ancl 
total 
rlensities, 
water 
temperature, 
dnd
nutrients 
were statistically 
analyzerl 
usirtg a two-way 
analysis 
of 
variance 
(by
station 
and rnonth) 
follorved'by 
a 
Duncan's multiple range 
test 
according 
to'i6e
General 
Linear Model 
procedure 
of 
lJarr 
et al. 
(.|976) 
available 
on 
the
9tatistjcal 
Analysis 
Systern 
at 
the 
University.of. 
Il l 
inojs, 
Urbana-Charnpaign;
Data 
for 
chlorophyll 
a statistical 
analyses 
were the 
same 
as those 
data
presented 
in Section 
3, 
Part 
l, 
here-in 
ancl daLar,for 
total 
inorganic 
niLrogen,
soluble 
orthophosphate, 
and total 
phosphorus 
were 
obta'inerl 
frorn 
Section 
3, 
part
I, herein. 
Data from the 
top 
and rniddle 
sampling 
locations 
were 
averaged 
for
the 
vat^ious 
nutrients 
since it 
was 
felt 
that 
those 
two 
levels 
would 
better
repres'ent tlre 
nutrients available 
to the 
phytoplankton 
that 
were 
actively
photosynthesizing 
than, for- 
exarnple,'only 
surface 
nutrients. 
A1so, 
only
nutrient datd 
from 
months in 
which 
phytoplankton 
were sanrpled 
(i.e., 
during 
the
period:from 
July-197B through 
September 
'1980) 
were analyzetl 
statistical 
ly. 
Al I
tests 
for significance 
discussed 
in the results 
and 
rJiscussion 
section 
were 
nrade
;;rs,,0.05 
level.' 
'
I
I
I
I
I
I
I
t
I
I
I
I
I
I
I
I
I
:,:: 
. 
" 
',,
l:',' 
. 
'..-
a:'. 
:: 
'
'i;1;:',' 
;,..:
',"//        
:j':
:.;,:', 
', 
'
l-
T.
::::-i:r
5.6
'l
:;l-'
..: 
,,..
.-.''.,
.. 
:,:
.::
P0I{ER,'PLAHT 
Rf[AfEO 
|ARA]4[TERS 
' 
'.:,.
Temperature 
,'            
-
Since the 
addition 
of iaste 
heat, 
ort a 
cooling 
lake 
is 
one 
of rne mdjor 
eff,ects
of 
pomr 
pl,lnt 
operatiorr, 
temperatures 
at d 
if f 
erent stations in the 
lake 
were 
of
particular 
importance 
to 
this study. 
For tlre 
phytoplankton 
and 
periphyton,
',vater 
temperatures 
in 
the 
euphotic 
zone 
(zone 
of active 
photosynthesis) 
were 
of
greatest 
interest. 
Temperature 
data 
taken at. 
tite 
surface 
ancl 
mirl-depth 
in
conjunction 
with 
the 
water 
chemis-try 
data 
(Section 
3, herein) at.stations 
l, 
Z,
3, 
and 
4 
were.averaged for 
each 
month 
frorii:July, 
197B through 
September 
l9B0 
arrd
els 
procedure 
followed 
by a Duncanrs muitiple
range 
test 
to 
detect differences'betrveen 
stations and betwecn 
months.
[.later ternperatures 
in 
Coffeen Lake 
were 
significantly greater 
at 
Station 
I
(heated) 
tnan 
all 
other 
stations, 
significantly 
lower 
at 
Statiorr 
4 
(ambienL)
than,al 
I 
other,stations and 
not s1$rrif icantl,y 
different 
between 
Stations 
Z,:ancJ J
(Table 
5.1).
,,,Table 
5.].     
:
Mean 
water temperatures ("C) 
of surface 
and 
mid-depth
locations 
for four 
stations 
sampled,monthly 
in,Coffeen 
Lake
frorn,August 
l97B 
through 
September 
'1980. 
l'1eans 
underscoied
by the 
same 
I ine 
are 
not signi ficantly 
different.
ll''
,jl 
.'-
il'
,l
tl'
l'-
Stations
'-f-,:   
2--- 
--j---l--4-:-
X               
25.4
,|9. 
B          
r9.I      
l7.t
r,l': 
,'
l,:.: 
. 
''
i 
ii:.,r
'-::,.='.
:.::.;: 
' 
:
.:..
' :'.,r
..,:
I
I
I
I
I
I
I
I
I
I
I
t
I
I
I
T
I
t
PIiYTOPLAI{K 
TOII
-l 
r' 
:::
Data for 
phytoplankton 
densit 
ies, 
spee.ies,
July 
'1978 
thiough 
June 
l9B0 
are 
contained
de'ns 
i t 
i 
es 
,:.number 
o f occurrences 
of 
,: 
t 
ax,r,
phytopldnkLon 
c0l lected 
from 
July through
A5,il 
, 
A5.2,'A5.3, 
and 
AS,4, 
respectively,
Dominant 
taxa
rlt)d 
d iver,ii 
I 
ier 
f 
'Jr 
col lecL iorrs 
, 
ron
irr 
CoutanL 
(tgeOa). 
0,:Ia 
ior
djversit.ies, 
and 
r'edunr!ancies 
for-,.
Septernber 
l9B0 
are 
containeei in 
Tables
i rr 
, the 
append 
i 
x of 
th 
i s 
report 
.
l'wo 
hundretl 
and 
twenty 
six 
taxa 
were identified 
frorn 
plrytoplankton 
collect.ions
rnade 
in the 
euphotic 
zone 
at 
four 
staLi0ns 
ancj 
frorn the 
intake 
area at 
a 
rlepth
0f 
six 
meters 
(Table 
- 
A5.l). 
0f those 
taxa, 
qlore 
than 
60 occurrecl 
l0 
or 
rnorc
r:       
' 
- 
l'
tirnes 
at 
one 
or 
more 
stations (Table 
5.2). 
The f 
iagellatecl 
organisms 
tenrlecl 
to
be 
less 
coffinon 
in 
the 
Discharqe 
area 
(i.e.,,Station 
I 
) 
arrd 
increaserl,in
frequency 
at 
stations 
around 
the 
lake 
to 
SLatjon 
4 
(arnbienL). 
Apparently,
effects 
related 
to 
operation'of 
the.power plant 
were respopsihle 
for 
loyrer 
':",
frequencies 
of 
occurrence 
of 
most flagellates, 
This 
lorver 
frcquency 
coulrl have
beert 
a result 
of entrainntent 
and 
destruction 
of t,he 
cel 
ls 
o,-i,a 
r"esrlt 
of intake
of 
water 
vrith 
lower 
concentrations 
or less 
tliversjty 
of f lagellaLes. 
Ihe 
fact
tilat 
rnany 
pennate 
diatoms 
seerned to, 
occur 
nrore 
f retlrrenily 
at 
Stat ion,l 
and 
,
gcnerally 
decreased 
in 
frequency 
of 
occurrence 
at 
stations 
around 
tite 
llke 
to
Station 
4 
rnay 
be a result 
of additions 
of cliatorns 
frorn 
the 
periphyton 
growing
a1ongtheconcrete-lineddischargecanal..Notr:ends].forthefreqtrencyof
occurrence 
0f blueqreen 
algae 
werc 
apparent; 
althouqh 
slighily greater 
fretluency
of 
'occurrence 
was 
expected:in 
the 
area 
of lreated 
ef 
f 
luent, 
due 
to 
additions 
f r:om
coves 
,wh 
jch 
had 
continual 
ly. 
high 
ternperatures 
during 
I ate 
sum'rrer, 
l:luegr.eert
algal taxa:w€r€ 
sirnilarly 
abundant'in 
al1 
parts 
of tlre 
lake 
(Table 
5.2). I,lo
trends 
were 
apparent f 
or 
non-f 
I agel I ate<l 
mernbers of t.hc 
chloroplryta.
Abundance
During the 
study 
period 
frorn 
July 1978 through 
SepLernller 
.|980, 
the 
rneon
densities 
of 
phytoplankton 
were 
significantly 
greater 
at Station 
4 Lhan 
at 
all
other stations 
and significantly greater 
at 
Station 
3 
than 
at 
the 
intake 
area
.J,
5.8
Iable 
5.2.
','
Alqal 
tarl tlt<lL 
:ir.r:urr^r.il 
lrj 
')r'r,,rrr.
{.of 
f 
een 
Likr 
rl,rr'irr;i 
n,jrrlh'! 
7 
r; 
r;l 
i,.r 
'
5c'Dt(:rnbei' 
l9Eli. ti*rrel 
irl-i,-, ,r,',i 
,li.
'pcsEiltle 
oeg:urr'cii:i1-'> 
ia:, 
l;:1 
nl 
:il 
.i:
.nt 
tlre !nt+k*
Iirliqr1': 
jtl .1!,.i
i 
r':ll 
.; 
?'f 
+::':. 
.] 
I 
] 
r,
:.i11113!-ryl; 
:, 
l
i.:rrr- 
I  
::  
i
r,.., 
.1 
! r. 
i 
.e 
: 
,,
:'t:r 
'. 
l-i,-:i,ij'i
;1 
:i:: 
:l';ii:a:irr' 
i{
l:,.i 
i,ll!1: 
,'i.
TAXA
' 
i.t" 
al 
i..:,!.:1    
: 
,
'1-'' 
-r 
- 
- 
- 
l*_--Z--'1.;',l3Trl
Clt 
l 
orerplryla',
Green 
coccoids
., 
,6reen 
colonies
t- 
Ch 
lamydornonads
F: 
:' 
, 
:f,arterl 
ads
F 
Chlorogonium 
spp. 
[hr,
6len[Tnia radi 
atd 
Chodat
@T-Tl 
g.r. 
( 
Schrorler 
) 
t-e;nn.
@rff 
rd'll*iA*^ 
nasel 
i
v:--r. 
lreubaria 
letraedron 
setigerum 
mlnimum 
{4, 
(Archcr) 
Braun) 
-
6, 
f{ansgirg
tl.9nith
" 
@ 
(Korshikcv)"tliiret.rk
U. 
- 
_(Tfir,reT-Tn 
Breb 
) 
ttrrnr, 
-t.eqn 
.
Uon6TapF-ilIfirrr ry_l!-!rtq! 
( 
Nage 
I 
i 
) 
nom.,ti',;,,
@ur'pii) 
Lagertr. 
'
Scenedesnrus 
dinrorphus 
(Trrrpin) 
KuLz.
' 
" 
tGnedA3rluf 
ELgJFlr"f,!q 
(Tirrpin) 
tJe 
3re,t:isscn
)cenedesntus 
Lrainorii 
v. 
Lrainrri 
i 
Shrrir,:rt
' 
.@!g.TpilCoF,dJ- 
*].-_.    
:
Euglenophyta 
,
r 
lfglqlornonal 
spp.
F 
FugTeriq- 
spf,. 
Ehr.
Chrysophyta:              
,i 
.
F 
cf 
, 
ChrySochrorn_u.l 
int 
sJrp, Lackey
Bacil 
lariophyta 
, 
".    
' 
':,
, 
Centric.rliatoms 
",'.
4q
tz
l?
lb
'll
1",
IL
l6
?
Q
5,1
tl
t/
20
43
il
It
,i 
l]
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{t 
11
., l
ll 
:',
a
t4
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ll
l,
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l1
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lir 
.
t\
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& 
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a 
,oerninata 
Meneoh. 
i' 
i
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TTrme-TTfa 
Lernm 
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9f@E         
fritsch & 
Rjch
Cr:yptophyt,a 
1
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.:    
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t,,    
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riqnif icantly 
sJif 
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AnoLher 
differenca 
lletwean 
phyloplankLon 
rJcrrsities, 
crprlciel)y 
l)ctwccrl 
SLa'-ion I
(heated):antl 
Statiort 
rl'{ 
arnbirrnt) 
, 
was 
tlre 
rJramaLic 
f 
luctrratir:rrs 
in rjen,,itie., 
JL
fhe 
ambient: 
location 
jn 
conrpariEon 
to 
tlre unifrlrn 
rJensilies 
of 
phylopiankton: 
:
Iound 
in 
the 
rlischarge 
area 
(SLation'l 
),,{fiqur:e 
5.1}.'ln Lake'5anqctrris,
another 
cettfra'l 
lllinois 
fjonr:l. 
plant 
coolinq 
lake, 
lreaLer 
fluctrrations-in::algal
al)unddnce 
dlso occ.trt'rad 
at 
Lhe 
control 
staLiorr 
llrarr,tt 
thr-'sLaLion 
localeci irr
thedischargedre.adccordingtr'rCouLant(l9/9a)'Ihis.trendofmoreiutr!fr:rn
concentrations 
of-algae 
in 
the 
disch.ln;e 
area th.ln in 
the 
control:dr€d 
js
probablyrelaLerJ:tothesullsurfacein|akewhichwould:nirtirnize;tne.eireetor.
surface water 
"blootns". 
Essent.ially, 
the 
waLer 
passing 
t,hrouqh 
Lhe 
power 
plant
would 
be frorn deeper 
waters 
wltere 
active 
algal 
prorJuction 
wotrld 
be rer1uced 
and
populat 
iorrs 
would i:e 
generally 
lower,than 
at Lhc'srtrf 
ace            
:
:i::l
,, 
,nlorophyll'a,'anoth0r,rnedsrlr€,of 
phytoplankLon 
st.airding 
irop,'was 
als0.grrcatesL
at, 
Station 
4 
(2?,3,ng'nr-3; 
where 
concentratiorrs 
were 
significantly 
r;rr-.aLer
than 
all 
other stations. As 
ncted for 
phytoplankLon 
densjties, 
Station 
3 
also
ad signficantly 
greater 
concentrations 
nf 
chlorophyli 
a Lhan 
irrtt.^, 
f ur,,Z
::. 
. 
.and 
the intak-e 
area. 
Cortcentrations 
of 
''chlor'ophyll:l:at 
Station 
'l 
were' 
'-' 
.' 
. 
" 
i,
signi'i'icantly 
lovrer 
than concentrations 
at all 
othe" sarnplinq 
locaLions (Iallle
.. 
which 
water is 
taken 
into the 
power 
Or:n:.was 
foun<l 
to 
be 
1im. 
Tha fact 
that
:  
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::,
I
't,
I
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t
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rijiiii 
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5r3rl)lilr; 
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d0! 
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'.\1,:,;11,;,r 
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ir;rri 
ilrt{tt:f 
\t.tj((,it ll,./ 
i 
l;r.
difftr'tnt,',,i:rriii,,'.t;,,.. 
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t      
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'l'
'..
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;a,t
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ir4
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ii.'l
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)i
t
pOpt, 
I 
al ion levc 
ls 
ar- 
tite 
&l 
(leilth 
ifef'rr 
ii)!1,; 
i4rlr 
.ifi 
i'r 
'l 
{i*.r:r'' !f 
r..1:: 
!.hl1.r 
.:lt 
.)r, 
i.- 
lcnS
.l 
antJ 
4 
(Iatrles 
5.3 onrl 
5,4i 
suF,Cor?-.t'thr f irrtcrr_y ! ir,l! 
?.i1p:1r1y1.1381,:ri:l.,rn
dbundance'was. 
probably 
even i*5., 
,11 Lhr, 
1h,r 
i1{.,litir. 
itiilsf 
. 
ii..}nit:ie 
a*t 
}y 
i,:r*+r 
:
dertsif 
ies 
of 
.plryLoplankttln 
anri lrl'*er 
,e 
r-rnc,:cl?-,lt-ir.!!rs r,:f 
:t-ii-iiir'',:iitrlil a 
al,r,,l,]t ii;r;
lcoul<lbeexpiainerJby.t.heirtt'ake.lrtr!r|.i5{:h!l''':!:iii-w4{i]|'',t'i,-il5|].]r1f
phytop 
I 
ank'tcn 
popu 
I 
aL 
ions 
.
BaSed 
On altal 
abundance, 
lLal-iorr 
4 
Has'lrrri 
!-,l thr.qi: 
l.irlr,{,l! 
pr-l:lrlrict.i,re 
,rs,ril
obher stations 
j'n 
Cof 
feen 
Lake 
excepL 5t..rt. 
ion 
I 
{ 
t$rles 
5'. 
j 
arr,l 
5.,'ii. 
ltr,:
gt'eater 
standinq 
crop of 
plrytoplarrkLon 
at 
SlaLion 
4 w,r: 
inosl'l 
ikely rrillteri 
L,:
the 
greater 
concerrtrations 
of 
phosplrorus.available 
Lher"r 
,{ 
f 
aulr: 
5.51,
:',tt:::l
Nutrients'',":
Mean 
nutricnt 
concentraLiotts 
using 
Lhe surface 
drld 
nlirJ-clnnLlr 
locatir:rrs 
wcr.e
coflpared between stat ions 
and rnonLhs 
us 
ing 
a Lwo-way 
anJ 
lysi 
s 
0f v.rr 
iance
(gerreral 
I 
inear rnodels 
procedure), 
The mea,r 
concentraLiorr 
of irrorganic 
nitrogerl
greater 
al 
Station 
I t.lran 
at St.aLion 
4, 
LoLal 
phosphorus 
was
not significantly rlifferent between 
stations, 
anrl 
soluble 
orLligllhosllhaLe 
was
siqnif.icantly 
greater 
at 
Station 4 
tha'1:at 
Stations 
l, 
2r 
,tnd 
3 
(Tatrle',S.5). 
'ns
" 
t 
' 
a    
:
was 
pointed 
out. 
jn 
isection 
3 
.(her"ein), 
apparently 
tlrc 
power 
plant 
seplic tank's
and the seurage 
treatment 
plant 
infiow 
were 
potcntial 
sources 
of 
inorganic
nitroqen. 
Since a sign'ificantly-greater" 
stanrlino 
irop 
of 
'phytoplankto,r
. .':a:
'l'
: 
a:.4
l'
.,a.:' 
, ,.,a
.:. 
:: 
:-
:a:.::.: 
. 
:::
r..::i::'.:t.;,-:
; 
-: 
,,., 
s..t I
I
U,gi:: 
i-::ril-*,$t-{ 
lt 
i:.i1it 
i:...:, 
i 
: 
r                                                                                
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ir: 
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F. 
i{i':
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€,ilrl.li,. 
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ittltrr',.,1 
l'= 
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t,i 
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i*4trttllfrl 
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0..:''i${t. 
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lale+a:'J ! 
r:;:iiifi,l 
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!
'l? 
ir:n 
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r;rrl 
.l!,i:.r!. 
.:iq.:; 
liii;:'t,::;.i
{-i-}tli:er}t.rt!. 
i:)tt; 
t;{:s..= 
'. 
ir;l:i 
f 
!i..:rr!.,!,;
I 
.
T
I
I
those 
f oun4 
al'nl 
I 
ofircr 
staLjons. 
.:,!irrinq 
.r 
197J 
t,;1r-j,;;,,', 
i!r: 
!i.':..
ProLecL 
iort Arlcltcy 
( 
l9l5a) 
f 
orrnrJ Llr,rl. 
r"lof 
f 
,r.;rr 
i- 
r!.i' .r.ti 
t)hir\[Jrl,iIir., 
i
.lnd 
Auqust 
ltul lt itrogr:rt I 
irrr i 
ler! 
irr 
tlc 
Lob,]r.
Cornparison 
tq 
o_the 
r 
l_l 
l_i 
nti_s_ I 
tke:
5.14
, 
The 
mean, 
concenlrdtion of 
plty.lopl,rnk'Lon 
irr 
Cof 
fert{r:,l.akc 
i 
!?,1(J{) .r11al 
,rni 
ls
.,nl-l 
) 
r{d5 sl iryhtly 
lower Lhirr Lhc mridrl 
corrcentratiorr 
irr 
L,ri:r, 
i,hriilyvi 
llir
(15,600 
algal 
units 
.m1-11, 
an 
unhe,rte(l cenLral 
Illinois 
rr-,sr:ry,1 
ir, 
,lrirl irr
:.Lake 
Sangchris: 
{20,100 
alqdl units 
.rnl-11, 
annther ll linoi: 
inoliyrq lakr:,
..
based 
on 
datd 
prescnted 
for lhose 
Lwo 
lakcs by 
Corrlarrt 
(197<]a). 
il 
iglrt 
ly
different analysis 
and samplinq methods 
plus'thc 
lower 
rruLrienL 
loading 
oi
Coffeen 
t.ake 
(see 
EnvironmerrLal 
Protection 
Agency; 
l9/5a, lg/51r, 
,lnrl 
1975*,
:worrld 
seern 
t0, explain 
the 
0eneral 
ly,,lower cbltccnLrat 
jons 
o'f 
phyl0plarrkLon'
.:observedinCoflfeenLake. 
..                  
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Lakrl Sirelnyr"ill* 
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{ 
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piryLolrl4nk[ott 
in 
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f 
een 
Lak,: dn(t the 
di,tLrxir 
lrdit 
i'j5\rf i,.rplr,r,l!tr-rt 
irr 
Ltrt],. I 
ric,
v,hile 
the 
Cyarlrl;rhyta 
lrarl 
ri;ni 
lnr ibrJnddnce itr 
Ctrf 
fr:r:r: 
L<ie, 
!!t 
i+r.rtliriyj,l 
tu 
i.,]krl
Shelllyville 
and 
L.lke 
Scrnqcltris, Ihcsc four 
,tlgal 
diyi.,i+n1 
,,!i.-coirilLr:rJ 
fnr
approxirnatr:ly 
Bl't,861, 
and 
94'A of 
the 
Lotal 
phytoplarrtst*n'i:r 
lcfl,:t:n 
Laka, 
Lake
Shelbyvllle, 
and 
t-ake 
Sanlchris, 
respectivoly.  
, 
i 
' 
,i,
lert 
ica 
l 
tJ i f.f 
erences- 
I 
I 
i 
i,, 
.
t., 
, 
,
SLudent's 
L 
tests were used to 
deterlnine 
differences l)eL.*,rr:n 
euphotic 
zorre and
near bot,tom 
phytoplankton 
densities 
(Table 
5.7). 
As 
was':exile{ted, 
rnost 
sIot,ions
, 
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i,tpiir:irj.-rti,ii 
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f 
i11- 
.,,r.rr?.r,. 
1l 
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ll
l.trat 
rLat iorr.
0iversitv
:i-::.-'-r
:
Tha tliversiLy 
of 
phytoplanktort 
{it 
SLations 
l, 2i, 
-rrr,t 
3 llrl 
+L iii-ar-irlrir 
Z, 
}, 
-1,,j
4 
were 
not 
sigtlificdnt.ly 
different fr:orn 
onf 
,trroLll.ir 
t)d!*d 
o.1 
a 
L.rrr)-i{ny,lpniysjr
of vdrlanct 
ltf station 
dnd 
month 
dn(l d l)urrcanrs 
rtu,lLiplr: 
r'drtrJrl 
lrr11 
ii;rtrle 
5.ij).
5tation 4'hati 
:a 
signif icantly 
lOwer 
rnean:diver.iily 
{l,lt) 
!,lran 
Si.aLion 
I 
{1.j4}
accordirtq 
to the 
Uuncan's 
Lest. 
The facl 
l.haI 
St,rLion 
I 
hart gr.eoter 
diversiLy
than 
:statfon 
4' was 
expCcterl 
due,[o 
the f 
act 
tlraL 
tlre 
watr:r' 
sdnlplrd 
f ro6 
SLation
1: 
carue 
prirrrarily 
r-rlorn 
water',taken 
in.,'aL 
t,ha irltaP,t--:-ortld 
d 
srlor.L 
L 
ime 
bi:forlc. 
,.
:
5. 17
: 
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ir'1 
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:.--.,:rl 
i                 
1r'
"ii't**-tit" 
rl{ 
rlnll 
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4 
ir-'* 
E 
;lr.,l 
,
ih* 
:*t.rn 
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ii1.j 
t.:l,Jiji cr;,*put":-::j 
i':rr" 
L.rl{:: 
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il. 
i'jt 
..r,. 
r 
.=.!+.,r
1:::]ljChris 
i 
l..i9'J rr,:r,, 
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iar 
lr] tirg 
i:!.,iir4l 
l 
ritarr 
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l-ttf 
irt,tn 
i-.lia- 
i 
i,:it 
j 
..r 
!\rj.:j
+n 
tlaL,t 
rrf 
fqr*t,r+i 
{}9/Sa) 
i:-r.;,,i 
i+rlr' 
tl,rlirJns 
}6 
i.1ii' 
thtr;ryyi1i,: 
:*.f 
r*r}r.,:,1
staLions in 
L,l'(?.l*rrllchril 
frr;re 
J:la* 
1976 
t.lrr-trulft 
icig,i:i 
l,.l,'j. ili,: rdrriii!1,,.,{
rtivtlrSilies 
for 
L,tkrr 
Shelbyvillc 
itn'l 
Lake 
iianq, 
t17'i1 
n,i; 
,: 
f 
r.rj,,r 
I.iit 
t.l 
4.11 
r 
,Jrr,!
f 
rfi$ 
?.59 
ttl 4.?/, 
r+spectittly.  
r., 
['rf 
feelr 
i-,1hr, th.: 
r.tr]rlt 
,.]f 
Tr,tn 
i!ivr:r.rit r,i.,
f*r 
the 
lake 
*.t:, 
f r 
n 
I .ll9 to 4.7{r.
rln 
5rnl'nary, tlter* i{*r€ sevoral c, 
if 
f 
ernnces 
irr 
phy{9p1Jnir 
r",Jn 
co:rlprs'i't 
ie:4 
antl
dlritnddnCe ltet'rCenistaLions in 
Collcett 
t.ak*: 
ttia[ 
ilerc Jppalr-'rll.ly 
ri:laLed 
l.o 
Jrower-
Plant 
oper(rIion. ''Flagel laIerl 
plryloplankters 
ocevried 
learL 
{requcnt 
iy 
in 
the
ilred 
of heated discharge 
( 
StaUion I 
) 
and incrCased 
irr 
f 
r.ertrrt,ncy 
of 
occur.rerrcc 
rt.
succcssive 
sLat,ions 
arnound the 
laka Lo Lhe 
ambienl area 
(StaLi+n 
4). 
lhc
euphotlc 
zone 
phytopl0nkton 
densitjes 
and chlorophyl 
l a 
concenLraLiorrs 
wcr.tl
': 
i' 
'
si.thif lcantly 
greaterr 
at Station 
4 
(amlrienl.) 
and 
'gradudl 
ly 
decreascrl 
irr
successive 
order around 
tlte 
cool'ing'loop toward 
Stalion 
I 
(lreaterJ). 
0ivr:rsily
,t
5.lB                                        
I
I 
'l
rlt'phy?.OpiAnitilll 
,tt 
it,iirlt,t 
i 
,rlr 
.,:,lillii 
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fhege 
trr:.rtdg 
-{:r.: 
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i,}:;-ir}ll 
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t 
ire 
.,:;;1-.:it 
t, 
1;1 
,, 
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,
po'd€r 
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i,.,rr.-' 
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rurl,rent 
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E.,5 
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irlnt; 
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! 
. 
r11, 
I 
ir., 
.
Ihl5 
tt 
tifiit 
tntl 
hAve 
hcgrr 
rJrJrj 
to 
tht 
,trl<i 
l!',t.,r. .f 
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periphyt0fr 
groHin j 
dlOnq 
ilre 
Curr.;r,ttrt: 
rlirLrr,li 
1,, 
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ilterg 
Were 
('til'.:r 
trt'rii!s 
'rrhi-gn 
,i+r'f, 
not 
rr:!"t.-r,rJ 
,r:) 
{iilsi". 
1 pi 
i.'. 
..rr;.,r. 
1.,:{,,t, 
rn,,r-:
'l
'da5 
e+nsiderahle 
'rerticdl 
ni.rin:i of 
phyir.rpl,r!ti:i;)ri 
.!! 
.-i,.::,i 
!r:r-+i:r-:rr.l 
ar.r 
rtili
5tatian 
? 
rhich 
wt5 
Lhe 
deapest ta'. 
ion 
la 
rrple.l 
. 
i4,ac 
irlrylili): 
e.r:i?-srr.: 
dr.:rrti 
i, 
icr
antt 
chlorophyl la 
concentrations in 
Cflf 
ir-,rvr 
l.4kt.iijf'r., 
iirnrijr'l,j 
r-it;j.,,..fr...1::r 
1.3ir1
Shelbyville 
anrt 
Loke 
Sangchr:ir; 
the 
slirlhi ljr i,iwer 
ti.4+1 iii::i;i: 
ipt 
1n- 
i.1f f 
..1-,,'
Lake 
could he 
explrainecl tly:dif ferent 
melh0(,5 
+[ or!,tlyris 
,rnr! 
t./ 
i!r* i,.rrc,.
nuLrit:nt loarlirrg 
of that 
lale. 
,jhe 
dia[ofls lr+<1 
l{ixer 
rqi,rt.:rtr 
JbirntJ6n{e 
irr
Cof 
feen 
Lakt) 
thdn 
in 
Lake 
Slrelbyv i 
lle 
arrd 
Laki 
Santpclris; 
ilr-r-ilr] 
*li1.ril 
,rnJ 
i,rrt
Cryptoplryfa 
tlad 
lr.eat,er 
relitive 
obuatia{tte 
in 
t.offeen 
Laxii 
liran 
irr 
thr: 
r;t:ier- 
ixo
I 
rkes.
@',",,
t,- 
l
0ata 
for,flet 
prlrnary productivity 
(mg 
02'rrr-2.rtay-lJ 
coi 
lectert 
f r"cnr
':Septernber 
lllTB 
thr.ough f'lay.l980 
are 
containerJ in Coirtant 
(l9g0a). 
uata for 
net
primary productivrity 
col lecterj 
from 
Jrrly 1980 through 
.lanuary 
!gttl 
are 
cortairred
.inJut,|eA5.5initrea9pendixof.thi.5repor|.
,' 
Net. 
priinary 
productivity 
(rng 
02.gF-cal-l of solar r,rdi,rLiorri 
w,rs 
qreatr.rsL
,,intake 
area 
(0.73
Slation I'{0,59
;, 
,.'.: 
,, 
t-' 
-.1_-'- 
t.'. 
;tt,,t:. 
. 
,.
,. 
o.t 
,$-ta11ffi 
4 
r:(0:,91, 
ng02.gKcal.I1 
and"'lower 
at:: Ihe
Ii;1n902.$Kcal-l), 
Sliatlorr 
2 
(0,68 
mg02;gKcal-i; 
and1
nso2:itKgal'l),(Table 
5:n), 
": 
-,
',-.,.' 
'tt=,,. 
'.,,...,.,. 
','
,. 
. 
:      
itiri;,:r,i
l4i:,tlt 
riit!- 
ilri:r*t=;' 
frt-,;.i;s'- 
i, 
l 
,' 
! 
!,.y 
r,',-a 
; 
'r !
rnrti4t!'r:t;  
it.j.irtl  
i;tr: 
ilr,r,:lt,.r 
r 
; 
I 
.r.
i.,Of 
14,-"1 
:*.lti' 
l:1,,i.1, 
it. 
.i 
a' 
t 
, 
,,:1r;.. 
!,,ri
..i,in...r,^ 
/ 
1.1 
ii 
. 
vr;.ii',,. 
r'ti'5.,y 
.,. 
,r,,,; 
i.1
..i,1riif 
ir.':tri!. 
!? .:iif 
r-i!.!r!l: 
.
I
I
I
t
.;,!:- 
r:r                                                 
I
.-r---_'.T-5ai.5...-*.
rl 
;ri!-;1r:1;              
.
i!_*_
:.t, 
'.;'8
I
11.'ritt 
.rl("'l 
priiiltr 
j/ 
prr-itj,j,:L 
ir;tt r,l!-t,; 
,,rr-;r'{} 
rif 
}t 
":,lr; 
.i 
, 
ir-*rti. 
i;r 
:.!r..
StJtiOnS 
'tcr.ilf',!tnJ 
t,i titr.l 
,in,tlJri;q 
it ,Jrl 
)i. 
j. 
!,ri! 
.1,r:r 
;r; 
,.
ilatrle 
5..ii.    
, 
'''
i 
!11r1r;1 
i:i:i 
ai.,,'r
.:ia,=::;: 
| 
:;1 
! r:., 
t,.r
I
f,
t
I
I
I
t
I
;llr
I
'llllora!ly 
sp*aiirtg, 
'ri 
i{lL,tlr-' 
}.'}rxi}€r.lLrrrr:! 
r}i 
ii't, 
i-,,.. 
1,,,.i1' 
;i:++:,!r.;,.;.r 
.:i
[rt'itnary 
p]'rldili-i 
irin 
h,li 
I'1.-'lr 
i..l!\eay13rj, l;r1f ,rt irlt.rr:L 
l-q;::g,;;r1!,.;::,-1 
1g 
;r!)-:. 
:.r1 
i:.!:rri.i
ther'e hd5 
hc,ert irthillitron 
rlf 
[]rlrilct'jf lrr.)drtCl.ivit/ 
i1 
r.r,r 
i 
1:', 
r11,,iii, 
l:ri 
,r 
r..,r,.,
.nccordirtq 
t* rJarrirre r 
;rrrrl 
Srrh;nrr 
ila66i 
anrl 
i.t;r'i;il!l 
:1r14 
i:!r,i.ri 
i 
i.iit 
j.  
.1!.iir,r-
reS(ldrcher'5 
ltr.lvtl 
indieeied 
thnt itrl-/ 
(i)'ntiirl,lt 
ilrr 
irt' 
trll-6i:11 
1*,*-,p,';',tt,ir'.-, 
itfliJ 
f
llrat 
dirJ 
rt,:lt 
excec(l 
35'C 
wr'rrl 
sti,,rrrldlury 
!.a 
irrir'-'ar:v 
pr-i'.!:j::iivit,,r 
{f4ii 
ii:r 
rrL 
r}.
'I 
9lfi).  
Itrey 
tl';,1 
irriJir:.,tLutl 
tirat 
irrhihir-i,rrr 
*f 
1)ri,;14r-y 
?riitiuti.rvi,../ 
w,1,, 
rir,,lr-vrj,l
at 
rt 
isCttarile 
Lfrnpcrntrrres 
qreaLer 
t.lralr 
J4'C 
rrrJarJle=rg.rif 
i4bieal 
ie,!rpr:r,rl..;r.,:5.
0Lher 
restlJrchdrs 
have forlfid 
fh0t 
prirnary 
prtrCuclivil.r"rrt:r'ililcn 
inhihil::ti
regdrdless 
of 
intaker,Lernpclittures 
with 
t's 
of l0 l.;.3t]"F 
i6urtz 
anrl 
r{riss
rei4).
, 
,,
flor,lrl 
(in presr,) 
lfortnrl 
thaL 
prirnary 
protluct.ion 
by 
plrotopl,]rrkLlrr 
wds 
inhibilett 
in
the 
discltarge area 
of Lakersangchris, 
a 
cool 
ing 
lake, 
rlurirrg 
nerioils 
when 
wdter
tentlle ratures 
irt tlre 
d i 
scharge dred 
were 
in 
excess 
of 
30'C Jnd 
l,h,tL 
t.he 
;lrirnary
protluctivity 
vras significan:tly 
grea[er 
in 
the 
discharge 
area 
than 
in 
lhe irrtake
area 
duringl 
periods 
when 
water 
ternperatures 
were 
tlelow 
3rJ"C 
in 
the rlisclrarge
area. Though 
other 
reSearclteFs 
hdve 
found 
heat-related 
rlifferences 
in
productivity, 
no. 
significanL 
differences 
were 
found 
in 
this'sLudy, 
probably 
due
to 
infrequent sampling 
and few replicates 
or 
due Lo 
the 
real 
sirnilariLy 
beLween
stations,
:::::
,,: 
:
.a:..:: 
.:
j:l
=t.' 
:
=.,i.'
':r::::
:::::,: 
.
:;-: 
i.::
,i;.:::
:a:::1:'; 
::
i:r:r::l.
:-::i.r 
ji.::
1,';- 
::;: 
,
:;;-::- 
:.
i:ii:;::: 
:. 
:
r;.::
=t-a. 
a
!'-:
'::;r:::: 
.:, 
:,. 
:
a.a ::'- 
,
+1.=1:-:. r.::'l
It€:i_:ir,a.:i,:1,.i
I
!.
l.
5.20
[t{R 
I 
itirY lritci
iiaiar'fttr 
periphy'ron 
rjtaiilit!t  
i(]{ir-ir:!, 
+rril 
i:itr:L:",if.r*,, 
i.,r,:
.l.lly''! 
9iB 
thrOugh 
.]unr-'' 
\9t1i; 
arZ 
ct*teintrl 
ra 
i.{::i!_.jrir. 
i 
ili;-1 
,1;,,
dg{Cit'lcs, 
:pec: 
ies. 
diver-ciiiti} 
,iftrl 
rr?rjuf.!i.l4rjr.rr,..- 
f 
rr- 
l,-::.lr
IIBQ 
Lhr";iurlh 
JJnirar'y 
!9Ai 
+rr:'{flrlLrrrieil 
i'{r 
I.:}ii:c 
q!:.i, 
.\r,.1,
respectively, 
in 
tlre 
di.rpilntlrr 
+f 
rrrir 
repiir.i..
Conrpo-sition
Periphyton 
JCc,.nnulatiOns 
r:n 
glass 
llirjt:s 
0t 
fg117- 
st.it,iclnt
d 
if 
f 
ererrt b,rt'de4n 
locdt 
iofts 
(Tablr 
5. 
l0). 
l4iiarr 
f 
rtn,; 
it 
ir:c,
't i 
t1,, 
I :. 
:,.t: 
, 
,. 
rta:iii
,jl;rta !r.,r' 
,,
!.;nii ! rr;,ir 
.i::+,;t; 
!,
i-1 
.?., 
.atil 
lt.!,
I
tl
I
.:,f
.:I
','a
:.I
.':
:I
::I
ilne 
|tundred 
and 
lighly 
thre* 
L4ra wr:rr; 
irjent 
if 
rrtil 
f 
r1ilt 
,]er,t 
;rlr,ri_.r4 
colleCtfrj 
f 
r:*rr
qlass 
slides 
after 
quarterly 
28-rl.iy 
e\po3uri, 
perir.rrtr 
Jr. 
r,.;irr.sf. 
1l.i611 
5 
in 
l,tfir:.,4
Lake 
(Tahle 
A5'2). 
St.ations 
incllrlerl 
lh+ 
[nlrrt:e. 
iril.:hrr.qt, 
,]rrrl 
i]a.;r 
o.*.,, 
o,,n
Slation 
l 
{Fig, 
l.ei,    
,                  
, 
.
Abundanr:e 
j 
:        
: 
.
gerii 
.i 
irlni 
f 
icarrt,i-y
f*ltr*l 
unils:iC 
:
Tabltr 
5.lU
I'lean periphyton,derrsities 
{algal 
irnir,s 
. 
io 
c'o-2} 
on 
qlass 
slitles
gI?.?.eg 
for 
2iJ tlays 
quarterly-frorn'septerntrer 
tg;i 
itr,.iugn 
r=err,:uJ,rv
same 
l9til 
at 
I ine 
f 
ottr' 
are 
locat 
not 
sigrrificantly 
ions 
in 
Coif 
een 
rlifferent 
Lake. 
l'learrs 
,rnt,erscoilcrl 
with 
t[c
"- ','- ' 
"""
Stat 
icns
fiich 
a r 
g 
e 
-r*--* 
T 
-' 
-, 
-:--lm' 
- 
- 
-- 
*-*fiir. 
;kT 
- 
-
?15,000., 
_ 
.-ug!_q00   
t 
zttgq!
....
' 
cn'Z). 
were 
significanbly great,er'a:t 
the 
lntake 
area 
thari 
all 
other" 
sLations,
significantly 
greater 
at the 
Dam 
area 
than 
at 
Station 
I 
anrl 
the.'Discharge 
ar.eat
" 
and,nOt 
rsignif 
icanb:ly 
Oif 
ferent 
betweerr 
S[ation 
Lanrl 
Lhe 
Discttarge:area. 
As
can be 
seen in 
rio., 
S.Z, 
inhibirion 
of 
srowlh 
did 
;; 
;;;r;: 
;; 
;;,;"r;r;;;.n;'-
, 
area 
: 
only 
.:, 
. 
in the 
warnter 
rnonths 
:,
wlten 
ternperatures 
werg 
near 
40'C. 
The 
inhibition
t 
:
I
I
I 
:,,
I
I
I
I
I
t
I
t
I
I 
.
l'
I
I
l'
1.,
r+ 
{t
-1- 
f
.i 
L-'l
,: lf-:
)a 
,-.
i
l-  
.::-
1
j
.!
, 
i-.- 
.+
ri
't:
i
.l
I
't
t-.-,
'!
"t
.l
.l
':
.!
_!
'     
f- 
(
i,.
,1
i
i
:- 
-!'-
I
r"
I
I
I
I
I
>i:  
:
a 
a-       
:
F!:
tt
ad:        
.
' 
€  
('l
e5
;: 
, 
.,9'1     
-
u 
*. 
.
!E':
: 
:.ct'1. 
':i': 
. 
:'
"
c.
E6
.Y.r
€,i
:   
i, c. 
I
.E 
+;
.rL*
*q  
o,
cu
C>r
q|..
^ 
c:.
*1
- 
t t,
- 
E 
qt
:i 
Gq
;,: 
J 
: 
.8;eE
Li
,.F 
rrs4< 
L 
'
i0p
atj
?JA
:  
c:ti
4!-
Feti
vqt
JIl
u 
c!
'a:r,  
.J
_ce
sFa
d4
9ig
cac
q 
!G
g!
du
CJ
CE
u.o 
0t
l-!   
c
i:r.
d 
oF:
sCAj
! 
4r
!: i: 
.r
ja! 
f 
4
:d
6
&.
:, 
r
--*-
,/
rl
,/
/
--*-1-.T"*
rJ,      
i\.i      
{i
1
:
!
n""-
4
\-
\\,
-'\--
\
i
I
I
!
l
i
'i
;l-
I
I
,: 
i
:
i
9'
(n
?_
l::)
J
:i
(:)
rl,1 
L: Z 
: 
jt 
,-, 
,- 
.*  
' 
L\ 
-. 
ili il 
'-. 
: .' 
- 
.. 
u. 
'r 
.-- 
.--)   
ii 
i)    
-r 
.'  
.a\:
5,?2
''.,'.,..a
. 
i:.1
::: 
i: 
- 
:.1
of. 
periphytic 
algal 
growth 
in the 
Sischarge dred ira$ 
4pparent during 
,rll
sampling 
periods 
throughout 
the 
study; since t.t:mper6i.ure-lnduced 
inhibrlion 
cf
periphytic 
growth 
generaliy 
occurs 
only at 
tentperaLures 
over 30'C, olher 
faulors
must:have 
been 
responsib!e 
for the reduced 
growth rdt?s 
of 
periphyton 
in 
the
Di'scharge 
area. 
''Epparently, 
factors related 
to 
the 
power 
pl,rnt 
effiuerit ware
responsible 
for 
the reduced growth 
of 
periphyton 
in 
tlie 0ischarge area, 
It.
should' 
also 
be 
note:l 
that 
the 
jnhibitory 
effec.t 
on 
the 
periphyton 
was still
apparent at 
Station'l 
and 
that growth 
of 
periphyton 
at 
the 
Dam 
area was 
still
siqnificantly 
less than at the 
Intake area. 
There 
was 
a 
gradual 
recov€r.r 
0f
periphytic 
Arowth 
at successive 
stations 
from 
the 
discharge 
around 
the 
corling
i:
looptotheintake.Currentwa5aphysicalfactorwhichwasriifferent'at'the
intake 
and discharge areas 
and 
might have 
affected the 
colonization 
rates lf
periphyton. 
Current, 
was constantly 
greater 
at the 
rJischarge 
area 
than af the
intake 
area and Cecreased 
as 
it 
progressed 
around the 
cooling 
loop 
to the
intake. 
It is not likely that 
currerrt 
alone was 
responsible'Ior 
the 
observed
trendsbecauseperiphyticarowthratesargusuallypositivelyc0rrelat.edwith
current 
velocity; 
thrrs 
one would 
expect 
grcater 
accunulations 
jn 
the 
discharge
,:.::
are 
a.
The mean 
density 
of 
periphyton 
in 
the 
Kanl..akee R'iver was 
6,400,000 
algal 
unitl
,.10 
cm-2 
using the same sampling 
apparatus anci 
exposure 
periocls 
based 
orr
data 
collected 
in 
May, August, and 
November 
of 
1977, 1978, and 
1979 
by 
Coutant 
:
,(1978, 
'1979b, 
ancl l9B0b). A mean 
periphyton 
density for 
Coffeeri 
Lake 
based 
on,
ail 
data 
collected 
from 
l4ay, August, 
and 
November 
sarnplings 
in 1978, 
1979, 
and
1980,was 4,400,000 
algal units 
l0 cnr-2. 
The lower 
densities in 
Coffeen 
'
Lake 
ulorrld 
lie 
expected due 
to the 
generally 
nutrient 
rich 
environment 
of 
rnost
r^'iu.rr'lWittiams 1964), sucn 
as 
the 
Kankakee River, 
plu:; 
the 
positive 
irrfluence
oflgreater current 
in 
the 
river which would 
enhance 
nutrient 
mixing. 
Even so,
the intake 
area, 
which had the 
greatest 
periphyton 
growth 
in 
Coffeen Laka, 
had
mean 
periphyton 
densities of 6,400,000 algal uni 
ts l0 
crn-2,
approximately 
the 
same as 
that 
found 
on 
the Kankakee River 
substrates. 
The,
overall lower 
product:ion:of 
periphyton'in 
Coffeen Iake 
can 
be 
attributed 
to 
the
ieduced 
growth in the discharge 
area 
which w,t'l'apparently a result 
of 
some:: 
-
'$1owth 
-: 
J 
imiting 
or inhibiting 
f 
acfol 
jn 
that 
area 
of 
tlre 
lake
r.
:,.
:i':.
'a 
::::.
:i]:'::
s.23
:ii
.:
::i.
I
..:
I
I
I
T
.:
:'
Major groups
Ihre,e 
divjsions 
of 
algae fiere 
rcsponsible 
f 
or 
tli* 
ra;jrrrity 
r;t 
pr,r 
iplrylic 
ll 
: rl
growi.h 
on 
gltlss 
s'l 
ides 
in 
this sturJy. 
Thosc 
ar$r:ps 
rrere Ihe 
llriori:i:iryt,i,
Baci 
Ilirioplryta, and Cyanophyta 
( 
Iable 
5.1l.).1 
irt nac 
,0oin'rr:rt 
,ri;l 
f 
or tal,ri
densities 
of 
periphyton, 
t.he 
nean 
densities 
of these najor 
'1rr)rjps 
r:f 
,rlg,:e 
lerr:
always'lower 
.::
at tlre 
0ischarge 
area 
and 
increaserj 
as 
one 
proceiltie,l 
arounrl the'
coolinglooptowardStgtionl,tlte0amarea,andthclniakearea.T}rr:
periphyton 
riensitics 
were 
always 
significantly 
greater 
al 
tiie Intal:e area 
Lhar'r
at 
the 
Discharge area 
{Table 
5.11). 
Anong 
cach 
major 
<livision 
periphyLon
den:ities 
at 
StaLion 
I were 
not ri,;nif 
icantly 
dif ferent 
'f 
.L',,n 
lhos,l'cjensities 
at
the 
0ischarge area,
Table 
5.1 
I
l'lean'derrsities 
(alga1 
units 
. 
lO cm-2) 
(f) 
of 
the Chlorophy',a, 
:
Baci 
ll 
ariophyt,a, and 
Cyanoplryta in 
periphyton 
coll:cted 
af 
ter 
qrrarLerl 
y
ZB-day exposure 
periods 
at 
four 
stat.ions 
,in'Coffeen,Lakc 
fron Septernber
l97B 
through 
February 
l9Bl. 
, 
l'learis 
underscored by the 
same I 
ine 
are 
not
s 
i 
gni 
f icant ly 
di fferent.
l!i
T
T
t
t
rl:.r :
t:':"
i:'\j
?1=
T
l,
T.
Div,isions
, 
Stat ions
D'rEliarge..   
l----.--ffim 
---fiita[e
Ch I oroplryt 
a
x
l}acillariophyta
x
Cyanophy.ta 
.
,X
_
572
T
t
659 000
000
000
517 000        
869 0c0    
1 
,4 
27,,000
tB0                          
2; 22.9, 
Q00
6B?, 
o0o
!-reqg,ooo
I 
75,000          
258,.000                      
66 7,000
I
",,t:
Diversities
Periphyton 
diversities 
computecl accordirtg:to 
tlre 
eqtiatiorts of 
Sndnnon 
(194S)
were significantly 
different between sampling locaLions; tlre 
diversiLy 
cf, 
Iirc
periphytic 
algae 
on 
glass 
slides 
at the 
lntake 
drea 
''rat 
siqnif 
icanLly 
gr',rater'
than the 
diversities,'at the,Dam'and at 
th'e 
0ischarge 
area 
(Table,5.l2).
..   
:  
,. 
:' 
1. 
,.:     
,     
;;'  
,.a. 
: 
-
l'
i-.
F.,''
'ili-
:,. 
r=
1 
,,-i
i=
5,24
::;..:
j=
l' 
''
i',. 
..-'
f''
;,.i;-,,, 
.,,i,
0am
I
I
I
Iabte 
5. 
ll
Mean 
dlversltles 
(3) 
for 
periphyton 
collect,r:rl 
f 
rom 
glass 
,,1irj',..,
after 
quarterly 
28iay 
exposuile-periorJs 
at 
four 
stations 
in
Cof f 
een 
Lake 
f 
rom 
August 
l 
giB 
through 
February 
l9{tl 
. 
i'leans
underscored 
with 
the 
same line 
are 
not 
significantly 
rlifferent.
Stat 
ions
Di 
scharge
3. ?0          
3, 0l     
2.61            
2.42
The 
gradual 
density increases 
noted for 
major 
divisions 
of 
algae 
ds 
one
progressed 
around 
the 
cooling loop torard 
the 
intake 
were not apparent 
for
diversity 
values. The rnean 
diversities 
increased 
from 
the 
discharge area 
(2.42)
to the 
dam 
area 
(2.0f1 
to 
Station I 
(3,01) 
t.o 
the 
Intake area 
(3.20). 
lr 
is
likely 
that 
the factors 
responsihle for 
the 
rer!ucer! 
grcwth 
at 
the 
Discharge 
area
aiso 
were responsible 
fur" the 
reduced 
dlversity 
of aloae.rt that location.
In strnunary, th€re ilere 
several differences in 
periphyton 
conposition 
and
abundance 
be'tweett 
stations 
in 
Coffeen 
Lake 
that 
may 
havc beerr relaterJ 
to 
pov,er
plant 
operation. 
Feriphyton 
accurnulations.on 
glass 
sl 
ider 
rere 
significantly
lower 
in the discharge 
area than 
in 
the 
intake area. Since 
waste heat 
and
current were 
ruled.,out 
as the 
sole 
causes of 
the lorer 
periphyton 
growth 
rates,
growth 
inhibiting o;i limiting factors 
present 
in 
the discharge 
area 
seem likely
ils a 
cause'for 
thE observed 
lorrer 
growtlt. 
DiversiLy 
of 
periphyton 
was 
also
significantly lower in 
the 
discharge area 
than in 
tlre 
inlake,ared 
presumably 
due
tothesame..factor.svlhichcausedthe.Iowerperiphyticalgalgrowthinthe
discharle area.
r
j:1:
Alerican'Publ 
i=c=ffii 
ntrof 
i*ui1rn, 
Arnerican !.laler 
,,lo/ls',rssoiieticn, 
arril ,irtrrr
Pollution 
contici 
fec-eratibn.' 
rgio, 
- 
irunii,.,r 
meulooi"i.,,: 
'ir,o 
,ir;;;^;;io;
of 
water 
and_wag[:l;t.ri--ii 
l4th 
erl, 
A.rcrican 
pub]ic 
tlealLir 
Association,
t{ashingion, 
D,C.' 
)lg3 
pp.
Barr, 
Al 
.J,., 
J:-I.-Foglitlt, 
J, 
'P; 
fiall, anrt 
J. 
i. 
riclwirt. 
1926. 
A 
usrlr,s
guide 
i,o 
SAS 
76, 
5AS 
Institute, 
lnc,, Raleigh, 
NC. 
.iZg 
pp,
Brigham, 
A, 1977. 
t{ater 
qual 
ity investigations 
af"'udre 
.,.\sn_q[hris, section I.
In'R. l{. 
Larirnore and 
J. 
A, 
Tranqlilf! 
ieds.)Annual 
re$p_rt 
fdr ijsra:l 
year
Tg76,LakeSangchrispro.iect.I]linois.|latuialHisto'y,it,il'u*i
(unpublishe<t).
Clementr-K., 
J. 
lasprowicz, 
and 
S. 
0. 
Sw.rdener. 
1979. 
Anrrual 
sunrnary 
of 
water
' 
' 
Qudlity 
r€port 
Hi story 
to 
and 
Survey 
u.S. 
biological 
Army 
( 
unpub 
corps 
l 
i 
shed 
investigations 
of 
) 
.
[nqineers, 
in 
st. 
Lake 
Louis, 
Slrelbyville 
M0. 
Il]irr,r.is. 
basi,n.- 
Natur,ll 
D-linJal 
,,,,
,
Coutant, 
L. 
!{. 
1978. 
Periphyton 
of the Kank,lkee 
ili,7q1,','; 
'ln 
R. W. 
Larirnor:e'aricl'
, 
M. 
J. Sule 
(eds.) 
construction 
an{.prg-Qper4t,ional 
aquatic 
monitoring''
program 
lor 
the 
Kankakee River;, 
f.jirrs[ 
.tnnual 
report 
hy il lrnois 
NaIur-al
l__Evaluationof-acoolingl9kefislrery,"Vo1'Iv.|l.,.Nai.ilist.-iu'uey
' 
r'rr': 
.:.a   
.,.::',:a'
Histor-v 
. 
1979a. 
Survey 
Algal 
':
to 
rlynarnics 
f,onmonweaitir 
of 
Lake 
tdjson 
Sangchr'is 
Contpany, 
ancl 
Ctticagol 
Lake Shelbyville. 
IL.
l;
final 
report 
to 
Electric 
power 
Reseiictr 
Institute, 
palo 
Al 
to, 
cA. 
- 
,
. 1979b. 
Periphytorr 
of 
the 
Kankakee 
River. 
In R. w. 
larirnore 
and t4.
l.rtu..(e9s.) 
Construction 
and 
preoperat 
ional 
aqua'tic 
monitorirrg 
progrd.l
the 
Kankakee 
River. 
seconci 
annual report 
by 
illinojs 
Natural'Hjst5ry
Survey to 
Conrnonwea'lth 
td 
i 
son Company', 
Ch 
icigo, 
I 
L: 
'.
, 
. 
' 
l9B0a" 
Alga! 
invesLigations 
of Coffeen 
Lake. 
In 
J.A., Tranqui 
I 
I i 
and
-.._R.[.1. 
' 
Second 
Lar:irnore 
annual 
,report:.from 
(erJs. 
)-Environmenbal 
lll inois l{atural 
Studies 
ltistory 
of CofTEerr 
Survey 
Uate,-SOition-5.
i6 
CJniraf
, 
ll 
I 
inois 
,Publ 
ic Service,Company 
(unputrl 
ished)
_. 
lgtlOtr. 
Periphytort 
on artificial 
substrates 
in 
the 
Kankakee 
River 
and
Horse Creek. ln 
R. 
il. 
Larinroro 
'and 
I',|. 
J. Sulc' 
(e 
ds. 
) 
Corrstruct 
ion ahrl
,' 
preoperationall?'quat 
jc 
monitoring 
progrdm 
for clie 
Karikakee 
River. 
Trrird
annual report by 
Il I inois 
lt|atural 
Hi story 
Survey to 
Comnonrveal 
th 
tclison
,, 
Corlrpany,,.Chi'cago, 
IL 
(unpub'lished).
Duf ford, 
lJ. 
H. 
, 
L. 
ll. 
Coutant, s. 
0. 
swarjenero 
and 
S 
. 
'rl. 
lrJa 
it,g, 
lgll 
. 
irlater
quality 
and 
biological investigations 
in the 
Lake Snelbyville 
basin.
Annual 
report to 
UjS. 
Army Corps of 
Engineers, 
St. 
Louis, 
140. 
lllirrois
t{aturai History Survey 
(unpubl 
ished).
L 
lrtR^tiJRr-, 
ct lt0
I
for
I
t
I
T
I
I
I
I
T
I
I
I
I
I 
tt,
l-
l=
t'-
l'
l,=.
I:,..:
....:-'.
5.2b
il
F.
--Jiglosical 
.---t',s, 
f 
.' 
'r'laite, 
-investisatlons 
s: 
.0. lwadene 
in 
r, 
ine 
and 
iain 
L. 
!r. 
ir'urIyrl 
cor,.r.ln[, 
ri- 
r,iit,i, 
igzB, 
ilater 
il;;;l 
qua]iLy 
'repori 
arlrl
ro
!.s. 
ArTy 
colf]1 
9f [ngineers, 
St. 
Louis, 
r'10. 
lilinois 
r{arural 
nisri,,"y
5itrvcy (unprrbl 
i 
she 
tt 
)
Gurtz, l.l: 
l":..: 
lld 
g.14. f{eiss, 
1g74. 
tffrcr 
r;f 
Lherrnal 
sLress 
on 
phyt0plankLon
prot|uctivityincondenserc0olingwa|r.'r.inJ.l,l'6ibborlsan<t''l.it.:
, 
,)haritz, 
'Augusta,. 
GA.
erls. Therrnal 
Ecology. 
€RDA synpoTTun 
series 
(c0HF-230505),. 
:
llustedt, 
F, 
t930. 
tlaci 
I 
lariophyta 
(0i 
atomaceac). 
In 
pascher 
(ed. 
). 
Die
Susswasser 
Flora 
Mitteleuropas, 
tleft 10. 
G,tstaT-Fischer, 
jenol 
qt,O-pp.
l'1i1ler, 
M. 
c:, 
G. 
H. 
ttater, 
I. 
H. 
Federic, 
arrd 
J. 
p. 
Reed, 
1926. 
tf 
fect,s 
of
qowgr 
plalt 
operalion 
of 
the biota 
of 
,a 
therrnal 
disclrarge 
canal. 
t1 
G. 
ti.
' 
Esch 
and R. 
l{. 
l''lcFarlane, 
erls. lherrnal 
Ecology 
I 
I. 
fn6n Synposiufr 
series
(C0NF 
-75A425), 
Augusta, 
GA.
Horan, 
R. 
(in press), 
. 
qnytoplankton 
dynarnics 
in 
a 
cooling-na[er- reservoir. 
In
R. 
hist9119f.an 
pp. 
l,l. 
320-341.
Larimore-i!9 
Iilinois 
J: A..Tranqui 
coolinq 
iake. 
il i 
eds. 
il1, 
Lake 
NaL. 
sangctriis 
Hi;r.: 
surv. 
sttrdy: 
siil,-iZiql.
case 
-
l'lorgan, 
1: 
P., 
ll, 
and 
R. 
G. 
st.ross. 
rg6g. 
0estruction 
of 
phyloplanktorr 
in 
the
' 
!90_l 
't65-l7l
ing 
water 
suptly 
of a steam-electric 
station. 
Crrcsipealb 
Sci. 
l0(j,4i;
Patrick, 
Acad. 
.11., 
Nat. 
and 
Sci., 
C. Reirner. 
Philadelphia. 
I966. 
Tlre 
213 
d 
pp
jaLorns 
of the 
tlrriLerl 
States, 
vol. 
I.
_, 
and
-Acatl. 
I[aT]-Sci., 
Philadelphia. 
213 
pp
Prescott, 
G. 1962, 
Algae 
of t,he 
western 
6reaL 
Lakes area,2nd 
etl. l.l. 
c.
Brown, 
Dubuque, 
917 
pp.
Shannon, 
C.E. 
.|948. 
A mathematical 
theory 
of 
conrnunication. 
Bel t 
System
Tech 
. 
Jour . 
27:379-423, 
623-656. 
S.83
smith, 
G.M. 1950. 
The fresh-water 
algae 
of 
the 
unitecr 
States, 
2ncl 
ed.
I'1. 
C . 
Brown, 
Dubuque 
, 
97 
7 
pp 
,
of 
I'l,linois, 
2nd 
ed. l.lc0raw-Hi
Report 
on 
Coffeen 
Lake
U.S. 
Environmental 
Protection
Environ. 
Res. 
l-ab., 
Corval lis.
Report 
on 
Sanqchris 
Lake
U.S. 
Environmental 
ProtecIion
tnvjron. 
Res. 
Lab.,
T 
i ffany, 
L. 
and M. 
Ur. 
i tton. 
l 
97l . 
The 
a 
I 
gae
Book 
Co., 
New York. 719 
pp.
U.S. 
Environmental 
Protection 
Agency. l9i5a.
I'bntgornery 
County Illinois 
EPA Region 
V.
Agency 
tlorking 
Paper 
No. 
300. Corval 
I is
]'3 
PP' 
':
U.S. 
Environmental 
Protection 
Agency. 
l97Sb.
Christian 
County Illino:is 
EPA 
Region V.
,igency 
t{or(ing 
iaper 
No. 
314. 
',C6rvallis
ll
r:: 
aa:,::
U.S. Environmental 
Protection 
Agency. 
1975c. 
Report 
on 
Shelb.yvi 
I 
le
1 
" 
leservoir'tbultrie 
and 
Sneiby 
Counties 
lllinbls €pA 
Reqion 
V, 
U,S. 
r 
, 
,. 
. 
I 
I
:F.nvironment1lPrg!qction-Aqencytiorkinr1Paper|{o.3l5,.Corvallistnviron..
Res, 
Lab., 
Corvallis. l7 
pp.
V.an.dert{erff'A.l953..A.newnrethodofconcentratingandcleaning
. 
i 
diatoms 
attd 
otherr'organisms.l 
Verh. lnt. Ver. 
l-imno1, 12:276.
'    
i..
larriner, 
J. 
1,.,.and 
11. 
L. Brehmer. 
1966. 
Ihe 
effects of 
thermal'eff luents 
on,
....llldFineor.9anisms.Int.J.Air.l'IaterPollut,10:277-2B9,
l{etzel, 
R.G. 1975. 
Limnology. t{.8. Saunders 
Co,, 
Philadelphia. 
743 
pp.
t{illiams, 
L; 
G. 
'1964. 
Possible 
relationships between 
plankton-diatom 
species
.
I
I
I
I
I
I
I
t
I
1,.
I'
::
::
l=
I.
l.
I.
.
l'
I'
l-
=
li
l.
!.
:=:
5.28
::: 
:;.-
sEcTt0r{ 
6
Z0OPLA|{KTON 
0F C0l'ttliH L/iKt
hy
St 
ephen 
l{. 
l{a 
i 
t 
e
.. 
ABSTRACT
An, 
'investigftion 
of 
zooplankton 
rJynamics'at 
Cof 
feen 
Lake rvas 
conductecJ 
f 
rom 
'
July 1978,to 
l{ovember 1980 
as 
part:of 
an 
jnterdiscipl 
inary 
effort 
to document
ch.angesihwater..qualityinthecooling.lakeandreceivingstream'General
information 
was obtaineO 
regardinq 
dynarniCs 
of 
zooplankton cormunities 
anrJ 
indi-'
vidual 
species and 
of trends in 
standing'crop 
biomass. 
The 
overall structure 
qf
zooplankton 
conmunities 
in Coffeen 
Lake closely 
resernbleJ-those 
reported 
for
both 
Lake_ Sangchris,--a.cooling 
-lake, 
and'Lake 
She'lbyvi lle. 
That.the 
number 
or
richness 
of 
species 
was lower within the cooling 
loop 
compared 
to cooler 
waters
at'stations 
3 
and 
4 
may 
be 
the 
eonsequence 
of 
power plant 
perturbations,
including 
heat, 
entrainment 
and increased water 
velocities. However, morpho-
logical 
characteristics of the lake 
basin 
at 
Station 
4 
(e.9, 
the'railroad cause-
wayi 
-. 
:
p"oUubly 
promgted lit!ora'l 
cormunities 
that contained-taxa not 
found
elsewhere 
in the lake. 
'There 
was 
little 
evidencg 
that the 
thermal 
gradient. 
.).,
ristricts, 
' 
. 
..- 
or 
'- 
- 
enhan-ceq 
_ 
tfre- distribg!!on of taxa 
to 
any certain region of the 
''i:'.
l
Iake- 
.:.::r- 
Lake 
morphology 
_'-1.---.-: 
and 
. 
--.
year 
variations 
probably 
were 
the 
princjpal 
factors
governing 
spatial 
distribution 
of 
species. Stations with high water tempera-
..:.. 
--
'tu.", 
during the warmeif 
months 
sustained unexpectedly high 
diversities 
of
species, 
but 
probably 
a 
majority of 
those forms resided below the thermal 
plume.
,Rotifers 
were less 
tolerant 
of high 
temperatures: 
near 
the discharge 
than 
were 
'
cladocerans and 
copepods. 
The organic 
fraction 
of 
plankton 
mass, 
increased 
with,
distance 
from the 
discharge 
and 
reflected 
the 
settling characterstics 
of 
fly
ash-slag 
particul.ates. 
The zooplankton, of 
Coffeen Lake 
were 
found,to, 
be 
produc--:
tive and 
viable 
despite 
atypical 
temperature 
regimes, 
entrainment 
mortality, 
and
,unusual 
::.:,, 
''":" 
water chemistry.,: 
, 
.-
'Short-term 
projects 
investigated 
possible 
r,easons for',
the 
paucity 
and 
infrequent 
occurrence 
of 
lgplglgg 
kindtU 
and 
Bosmila 
in
,Coffeen 
L:ake 
and,'assessed 
the usefulness 
of two.:methods for determinin.q zoo- 
'
.:
pJankton.entrainment.....]:.
,. 
,'-.'.', 
,, 
.:, 
. 
r 
:-l : : 
.', 
,- 
'
.i
j
6.1
', 
,i 
' 
' 
,, 
Itl 
IR0DUCT 
l0ll               
r, 
.
" 
-----'--"
Animal constituents::of 
the I 
imnoplankton 
that 
inhabit alectrical 
power 
planf
coo!,ing 
lakes 
are 
subject 
to 
a wide 
variety 
of'unnaLurai 
conditions. 
.,Ireiquent
concerns 
of environrnental 
studies 
of 
these systems:have 
cenl.ererJ 
on: 
(I) prob-
lems' 
res'0ltinq frorn'additions of 
chlorine 
ancl 
other 
biocides 
to 
prevenL 
fotrl 
ing;
(2) 
'effects 
of inter:nal-meehanical'forces 
within 
the 
plant, 
such as 
turbulence'
pressure 
and'.vacuum; 
and, 
(3) 
excess 
heat containt'd 
in 
discharge 
cooling 
waters.
These and 
other 
concerns, 
including:aslr.ponO 
etftuents, 
collllttu 
runoff,. 
and
brine wastes, 
have led 
to 
a 
recent environmental 
studl'at 
Coffeen-Lake. 
This
,study 
wa's ch'arged 
with 
documenting'a 
change 
in'water 
quality 
conconvnitant 
with
improvemgnts 
in 
water 
treatment 
procedures:; 
The overall 
purpose 
of 
the 
Coffeen
Lake.study 
tvas 
to 
determine whether 
Coffeen 
Lake 
supports 
'aquat'ic'life 
c0nsis-
tent 
with 
contemporary 
lake managemtint 
practi'ces 
and 
to 
assess 
the degree 
of
'
recovery.resultingfromtheconrr'rencementofnewwaste-watertreatmenLfaci|i...
ties.
. 
, 
1 
. 
:,.
'The 
scope of 
the 
first-year 
zooplankton 
work 
was 
oriented 
toward 
dssessinq 
the
r 
- 
I i 
-L. 
^a 
aL^   
:-
status 
ot 
zooprankton 
communities 
in 
ljght,of 
the 
improvement.in 
the lakers 
:
::water 
qual 
ity. 
Specifical 
ly, information 
was obtained 
regarding 
numbers'' 
com-
position 
and 
distribution 
of species; 
species 
diversi+,y; 
absolute 
and 
relat ive
abundance 
of 
rna'jor 
groups; 
and 
standing 
crop 
bjomass.'Although 
these 
calegor.ies
were 
continued 
through 
Year 
2 for 
comparative 
purposes, 
additional 
efforts 
were
directed 
toward 
several 
more 
specific 
ecological 
and 
methodoloqical 
questions
which 
were 
developed 
as 
subprojects 
for 
this 
report.
METHODS 
AI{D 
MATERIALS
From 
July 
1978'through 
June 
1980, 
Coffeen 
Lake zooplankton 
communities 
were
sam!teO 
monthly 
from 
six 
permanent locitions 
(fjg. 
l.2), 
four of 
which 
were
intermutualjwithother..project...subgroups,i.e.,fi.sh,benthos,algae.T,9
sampl 
inq 
stations 
were,,establ 
iihed 
within 
close 
proxirnity,of 
the 
plant; 
one 
was
--".f 
.'..J 
----
locited'adjacent 
to.the 
intake'screens'and 
the 
other 
inmediately 
downstrean 
of
the 
discharge'canal. 
0ccasionally, 
samples 
were 
procured 
from a 
6-m stratum 
at
:.: 
,.  
, 
'- 
I 
,                                                                           
::    
'
,the,intake 
itation 
(Station 
X).
',::'
!
.:
I 
.
i:
I
I
I 
-
l
I
I
I
I
I
I
::
-.:::
f.
I'
i::,r
:::::r: 
, 
:
:.:1:.-:: 
:-
:. 
a. 
:::
',:..::::-i 
,:' 
.:
/:',:a::,. 
.:.
';:.;!,': 
:..,'
t:it,
:!1::'. 
.;'
..'
i::' 
',
:i+..:.. .:
t" 
;:,.:. 
"'
:.
i;fi.. 
,. 
-
l;
:::
l-
a. 
. 
,,,, 
- 
-,, 
ll.,   
,,                                                                                
li
t, 
j-r-' 
-' 
., 
,,
li,
6.2
;' 
:
i:l:.r:-:::
a:..
All 
monthly 
zooplankton 
collect{ons 
in 
Coffeen 
Lake 
consisted 
of 
tr-iplicate
samples 
of the 
water 
column 
from 
lake 
bottrim 
to 
surface at 
each sraLion.
Samples 
h,ere 
co 
I lected r+ith 
a 
submers 
ible. 
f i 
lter-pump 
apparatus 
{lf,r:i 
te, and
0'Grady 
l9B0) 
that 
filtered 
BB 
llters 
of loke 
water 
per'minute, 
lt 
was lowered
and 
raised 
such that 
all 
water 
strata were 
sampled 
equally. Ihe 
total volume
filtered per 
sample 
was 
a 
function 
of 
time 
allottecl 
for 
pumping; 
in 
Coffeen
Lake, 
a 
pumping 
duration 
of 
2 
minutes 
was 
adequate 
and 
thus 
the 
total volume
filtered 
at 
each 
sampling 
location 
was dpproximately 
0.5 
m3. 
An 
ethanol-
formalin 
solution 
was used 
in 
the field 
to 
kill 
and 
preserve 
the 
organisms
irmediately 
af 
ter 
col lection.
Analytical procedures 
began 
by diluting 
the 
concentrated 
field 
samples 
to 100-
200 
ml, depending 
on 
organism density 
and 
amounts 
of debris 
and 
slag 
particles.
Following 
sample 
homogenation, 
three 
1-ml 
subsamples 
were 
withdrawn 
and 
placecl
in 
gridded 
Sedgewick-Rafter 
cel ls for icJentification 
and 
counts. 
Identifi66l 16n
keys and 
other 
published 
literature 
usecl irr 
these 
analyses 
inclurled: Ahlstrom
(1940, 
1943), 
Brooks 
(1957, 
le59;, 
{lhengalath 
( 
lgTt), 
tdmondson 
(1959). 
Goutden
!t9qBl, 
Grothe 
and Grothe 
(lglt'), 
pennak 
(1978), 
smirnov 
(1924), 
t.,tilson 
(1959),
l{i lson 
and 
Yeatfian 
(lgFg), 
a4d 
Yeat{n.l 
(1959).
:
Filtering, 
drying, 
and 
ashing 
procedures 
describecl 
by ApHA 
et al. 
(1976) 
were
used 
to 
compute standing 
stocks 
of zoop)ankton 
biomass. 
The 
residues 
were
reported 
in 
milligrams 
(mq) 
dry 
and ash-free 
weight 
per 
cubic 
meter 
(m3) 
or
lake 
water.
lile.thods 
palticular 
to 
the 
ancillary 
studies 
wi 
ll be brief 
ly descrioed 
within
those'sub:sections 
of this report. 
'
.:
RE.qULTS AND 
DI 
SCUSS 
I ON
COIiIPOSITIOf{, 
DISTRIBUTION 
Ai{D DIVERSITY 
OF 
SPECIES
SpeciCs Cdmposition
.'.       
: 
'   
,
The 
monthly 
structure 
of 
zooplankton'cormunities 
in Coffeen
year 
study closely resembled 
those of both 
Lake Sangchris, 
a
t 
,::..-,:; 
-=,1 
;,,, 
;:a-. 
: 
," 
, 
,,', 
' 
' 
..
. 
6.3 
"
,  
'-
Lake during 
this:2-
cooling lake, 
and
Lake Shelbyvi 
lle,: 
. 
f 
lood 
controlr,reservoir 
(both 
lokes are 
with 
jn 
B0 
krn of 
' 
' 
',
coffeeniLake), 
in 1976 
(uaite 
1979a) 
(Iable 
6. 
I 
). 
The 
prerlominant 
tara 
in 
:
Coffe€n 
Lake included 
32 rotifer5, 
25 
clarJocerans, and 
ll 
copepods. 
Althrluqtr
the'.totals 
varied 
s'lightly from.Year: 
I to 
Year 
2,. they 
|rere 
well within 
thr
expected range 
of 
year-to-year 
variatri 
lity. 
In 
compdrison lo 
year 
l, 
year 
-Z,.had
fe*er 
total 
species 
at each 
station for 
all but 
fiye 
rnonthly 
coilections 
(Table
6-Z)::, 
Except 
for September 
of 
Year 
2, the 
overall lake means for each npflth' 
,
were.greater 
in Year l. Furthermore, 
there 
was a significant difference 
in 
the
overall 
lake 
medns 
of 
the 
two consecutive 
l-yea. 
periods (Student's 
t-test,0.0l
levei).
Lakewide 
comparisons 
of 
the 
number 
of zooplankton taxa in 
Coffeen:Lake 
showed
that 
in virtually 
all 
collecting 
periods 
in 
Year 1, 
the numbers 
present 
at 
all
stations 
in the 
cooling 
Ioop 
(discharee, 
Stations I 
and 
2, 
and intake) 
were
lemarkably 
simi'lar'(Table 6.2). 
, 
tlhile 
there weie 
fer.r trends 
,showing'gradual
increases 
or 
declines 
in species 
numbers 
in 
the direction 
of 
coolinq water flow,
the mean 
numbers 
of species at the 
cooting 
loop 
stations, coliectively, 
were
number of 
species at Stations 
3 
and 
4 
for
any 
particular 
month. During 
Year 
2 the fewest 
number of 
taxa 
for all 
stations
occurred in November 
and, with few 
exceptions, the 
qreatest 
number 
of 
taxa each
month 
was at 
Station 
4" 
*h.ich was 
similar to 
the 
pattern 
reportecl 
for Year 
1, 
",.'
Contrary 
to observations in 
Year 
l, 
however, 
the 
species'numbers 
were highly
variable throughout the 
cooling )oop 
in 
Year 
2. The 
lower 
overall number 
of
species 
in 
the cooling loop 
(discharge, 
Stations 
I and 2, 
and intake) 
cornpared
toithose 
drt 
Stat'io:ns: 
3,,and,,f, 
qlay.: 
be,the 
colseqgence of 
of heat, 
entrainment- 
'",
related mortal 
ity, and 
water 
ueficity;'ai.i 
o1', which are 
synergistic 
conditions
associated 
primarily 
with the former. 0n 
the other hand, the relatively 
shallow
lt,''
I::
I.
...:
l.,i:,r-:1
I'.:,.:
l.-"
-::.
I,:.
I,::,'
r..: l
-:
I
I
I
I
t
I
I
I
I
I
l'
lrt
I.:,:
l,t'.
' 
'tt'
l,::
r.r:.
Ii'
I.'..
I!.1:
I::.:::
F
l'=
t:.,=
t,,,' 
waters 
north of the 
railroad 
causeHay 
(Station 
4,and 
v'icinjty) 
appeared to 
l
,    
cooling 
loop. 
These 
observations were not 
unexi;ected due to,the 
unusual
r 
morphology of 
the 
lake 
basin.
0f:,the 
,.'.:' 
rotiferan 
.l 
taxa 
r  ., 
reported 
for. 
: 
Yeans 
:
I and 2, more than 501 
belonged 
to,.the
lor:jcate 
family 
Brachionidae. Dominant constituents from 
other 
families 
in-, 
,,
cluded 
the 
genera 
Synchaeta, 
poytiitttria, 
and 
Asplalchna. 
An 
unusually 
large 
.
'
6.4
Table'6.1. 
Surmary 
of numbers of zooplanktor 
taxa 
collected 
in Coffeen 
Lake 
tn
lJai te 
(1979a)
. 
Coffeen 
Lake
ffiFer/Tlle 
-
YearT- 
rfen#fZ
Lake 
Sanqchri 
s         
t-ake 
Shelbyvi 
lle
Taxa
Rot 
i fera
C I 
adocera
Copepoda
Total'' 
.
30
2A
t2
62
27
29
9
65
28
2A
9
57
27
22
11
60
6.5
t
l'
GJ
!o
v,
o
.l|
$.
u!
(u
0,
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(J
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p
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tr)
F{
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r'.
H
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co
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F         
(?)
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Vt:|l'
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c<i 
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FEc,
'-{ 
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ro'O
=(-)-.1   
=v)rr) 
o-j|+.
/.:.:'.
:t:::.
fraction'ol''the'Year 
2, rotifer 
fauna 
con-sisted 
af unkno'ln 
typcs, 
primari 
l.y
unidentlf|ablemalesaJr$irrmature]ifelris.iory.sLaqes
The:cladoe'eran.'fauna,of 
Lat,e 
Coffeen 
in Year 
2 
ras 
rspresentr:d 
by 
2Q species 
and
a,:':
sii f 
ami 
lies, 
tlowevei, 
,.,,- 
t' of 
fhese taxa, 
particuloriy 
tlre 
chydorids,. 
occurred
inf 
requenily. 
i: 
Oapt!nia 
parJu13, 
0iaphannsomq 
l'gus!tdnberg 
ianum, 
!gt&@g[U.a
quadrangul 
a, and 
Chydorus 
f.g!fail-[u! 
rtere 
the domi nant f 
orms 
in 
both study
yeais. 
The 
payc!ty 
of Lep*ttjdgfa rlurirtg.-Years 
I and Z of this 
stucJy, 
aiso no-.:'d
in 
the 
Lake 
Sanqchris study, 
suggested 
that 
certain condjtions 
(biological 
.
and/or 
physicochernicel 
) 
associated 
with 
cool 
ing 
lakes 
may 
have 
prevented 
the,
o.au..erce 
of this otherwise conmon 
taxon.
::
The dominant copepods 
of Coffeen 
Lake in both 
Years 
I and 2 included 
the ca'la-
noid, 
LiaptomuS 
sLciloides, 
and 
to 
a 
lesier eitent 
two cyciopoids, l4esocy_clopJ
edii 
and. 
Cycl-epjs vernil 
is. 
!-. 
!.j-c"s.gj-{gtg- 
ttrbmqs-i 
, 
a coldwater species', 
is'ra
typical 
*inter: 
form 
in 
several 
Il 
l'inois 
,'reservoirs 
(includinq 
Lake Sangchris)',
: 
'. 
.  
.,:.,    
:-    
r'     
'i,            
:
but:was rarely 
collected 
in 
Coffeen'Lake- 
Parasitic 
cyclopoicls 
on fistr, 
such 
as
f 
riasi,!qs, have 
not 
been 
col lected in 
their 
f r:ee-l 
ivirig 
planktonic 
forrn. The' 
,.
ttrirO 
grder 
of 
copepods, 
Harpacticoida,'typica-11y 
inlrabit 
the 
substrate, 
ancl
consequently 
only 
several 
individuals 
were 
col 
lect.erJ in fhe 
plankton.
, 
-, 
..t'                                                       
: 
, 
t      
itt 
,
ti
Previous analyles 
of':zooplankton 
popul'Jtions 
in 
Lake'Sancr-chrjs 
(19/5-1978)
revealed 
an annual 
"damping" 
of 
the number of 
species 
present 
in 
the 
cooling'
loop 
(l,lq1te 
I979a). 
In 
general, 
the 
numbers 
of species in 
temperate 
lakes
exhibit cycl 
ic 
pulsei, 
unless 
natural 
,u...rr'ion 
and 
periociicity 
u"u *OAified': by
synergistic 
effects' 
of variou., 
biological and 
phys 
icochemjca'l 
parameters. 
The
'annual 
::
f lue tuations 
of 
spec'ies 
numbers 
'in 
the cooling loop at 
Cofl"een 
Lake 
rnore
nearl.yresembledthe.typica]situation.wtrichwasexhibitedbypopulat,ionsin
unheated.LakeShelbyvilie::apulseinspringand/or.summe|.foI.lowedbya
gradual decrease 
to a 
late-winter 
.:.
low. 
In light 
of 
the 
L,ake 
Sangchris data,
this was:lan 
unlikely.result 
becauie 
the 
therma'l load 
(in 
megawatts 
per 
acre) 
at
Coffeen'L.ake 
was 
much 
greater 
than 
that':of 
Lake Sangchris. If 
the 
damping 
':
effect 
on 
zooplankton 
species 
is 
indeed 
a function of waste 
heat loarls 
as
:'imp,lied.for 
Sangchris'{ata,. 
then.O sitnilar 
damping should have 
been obierved 
for
't 
'                   
,..   
.         
.: :    
'    
:
. 
zooplankton 
populatiotrs 
in 
Coffeen 
Lake: 
Unless 
the'latter:, is 
a, 
very:,unusual:
6.7  
,ll
' 
'i.'
:t 
:,      
'
'l 
,
iistem, 
lt 
.is 
postulated 
'that 
other:ccnditlons, 
in 
adrl'ition 
to 
or combined'wjth
,heot 
l'oadst,are'important:, 
in 
regulat'ing'zoopiankton 
blology 
in 
cool 
ing 
lakes"
Iimp0fil-Di 
str 
i 
but 
i 
on 
o-f 
,Spec 
ies
R;tiiaiu. 
',One 
rotifer, 
Polyarthra 
vulgaris, 
occurred 
in 
near'ly 
al I col lections'
duri'ng'both 
study 
years. 
,'This, 
species 
anO Sy-qshag!i stylata 
were 
the 
dominant
anquql, 
forns.in Year,,2. Althouqh 
the 
brachignlds 
were well 
represented, 
the
occurrence 
of 
individual 
species 
nas clearly.season-r'elated. 
In 
both 
year's'
,9I..[LqLr-l'anguialii'inhabited:a]l 
.lake 
areas'from May 
t.hrough 
0ctober while 
l-
cauddtus and 
B. 
patulus 
occurred 
for 
a 
s\orte'ned 
duration 
in 
late summer.
.r*i*p'*r.'*''."r*coolerwater,B.urc-e.blqriswasco|monfromFebrua1y
through April 
in. 
both 
years 
whi'le 
r+iphane: 
sp. wa3 
col lected 
at 
,all 
stations 
.i.
primar.i]y 
:in 
January 
of Year 
2, 
Jui3r, 
Septe,nber, 
'February, 
and 
l'1ay samples 
cOn.
rodied 
Asplanchna 
in Year" 2, 
but in 
Year 
I this species 
occurred
iontinual.Jy 
frorn l,larch fr-oor. 
' 
,' 
'i.
.9.].adoc.9ra-.Atypicalconstiruentofthe.surn.ilerfaunaofmostlakesinthis
region, 
0iaphanosoqg 
leuchtenbergianum 
occurrert 
frorn 
May through 
Decernher at
most 
sampling 
stations 
in 
Coffeen 
Lake 
during 
both 
study 
years. 
That taxon, 
in
'iOCit'ion 
to Daphnia garvula, 
Ceriodaphnia 
Su4fglltrt3, 
and 
Chydorus 
:ql'raqr,ic.us
..:    
:  
:
.*erethefourmostpersistent.cladoceransinthe.|akeduringthestudy.
'.8r   
.!!gitg*I-l 
was 
limited 
in 
both 
yearls 
to the 
mid- to late-spring
. 
period 
(see 
anci 
I 
I 
ary study 
on 
Bor,Jnina)r. 
Three 
taxa, Ljj-aphanosonla 
brachyurum, 
'
Leydigi 
a 
quadrangul 
ar 
i 
1, 
and 
CamptocSrcu:. 
Iggl!'qstri 
s.' 
were observed 
only 
in
;i.il
'-tt,...t,.l'i:
Copepoda., 
gther 
than 
naupl 
ii 
anct 
Copepodids,.the'calanoid 
copeporl Diaptomu,s
:jSil"id 
.was,not 
only 
[he 
most 
comrnon 
copepod 
but 
was 
also 
the 
rnost 
persistent
,i-ooptant<ter; 
it 
occurred 
in every 
sanp'le. 
0f 
ttre 
cyc'lopoid 
fauna, Cyc,lops 
,
'!
..vetlnans 
occurred 
in at least 
one 
station 
thr.oughout 
the study 
period. 
Mesocy-
, 
Jtops 
edax 
was 
also 
a 
dorninant 
cyclopoid 
species. 
All 
remaining 
taxa were spor"
iOi.,:'in 
occurrence 
and 
the 
harpacti.coids 
were 
prevalent 
only 
from mid-summer 
to
...i.s.-11tt'-. 
" 
:
,,,,===,.:--' 
,.
I
I
I
T
I
I
T
I
I
I
t
:l
I 
::
t
I 
...
t
I
6.B
.:
I
'1.
:,-:,,:ra
;l
rI
T
I
sp 
a 
!l-a_!_ 
g 
Elr 
t 
!!lj_q.!__9!_lp$ 
i e 
t
tspatlial.distributlon 
was stud'ed 
toi'dererrnrne 
-i 
f 
any.taxa 
'rierere0nsist*rr! 
i=v 
',,
limitecJ"to 
or 
€xclrtded 
frorn 
any 
par"licllar 
.ragion{s) 
of 
t}re 
iake, 
Rclal'ively,.
,few',taxa 
were restricted 
to 
one station 
or,even 
ofie 
qener(tl 
rsqr'on. 
ligg' 
'
gllJ$alUns, 
a liitoral 
:a: 
clarJoceranr 
was 
found 
only 
in 
tne 
0ecemher 
coliection
,
,at 
the 
discharge 
s-tation 
in:Year 
l; it 
was 
nrobobly 
swcpt through the 
plant
from 
the intake 
rherp it'was:presenl in 
extraordinarily 
higii 
densities'on arti-
ficial 
substrate 
sarnpiers 
in November 
of 
Ycar'l 
{Buc}:ler 
I979), 
In'Year 
? 
it
|{as 
collected 
in 
December 
at 
Station 
4 
antJ in 
sonre cooling 
loop 
stations 
in May
anct 
June 
1980. 
The brachionid 
roti:fers, 
Colur.ella 
sp. anrl 
Brac.hion.us 
variabjlis-
were 
collected 
only at Stations 
I and 3, 
respectivelJ, 
rn 
Year 
l; neither 
were
collected 
in 
Year 
2. ln Year I 
no 
species were 
founcJ 
exclusively 
at 
Station 
2
or 
the 
intake 
canal,. 
In,Year 
2 
two claclocerans, 
f,loi.!1i 
Ul_L!1l 
anrl 
LgX[lg1g
quadranqularis, 
were 
collected 
only 
at 
Station 
2, and two 
rotifers, 
!uclanis 
and
'.Tricholria 
were collected in 
the 
intake 
regions exclu'sively;: Station 
4, 
ini.n
was 
not a 
direct 
part 
of the 
coolinq lootr, 
favorerl 
the 
exclusive 
rlevelopment 
of
several 
I 
ittoral 
species, 
including 
three 
copepod 
species, 
Leydigia 
acanthocer-
cojdes, 
Brachionus rubeE, and 
0aph.nia 
lclodleri-. 
Species 
occurrinq 
only at
Stations 
3 
and 
4 
combined were Alona 
g5!al,l, 
Ng[!g]gq 
sn. and 
!_qmp!g.g€_rcg:
rectirostris, 
Qaphn-ia 
longj-r1eql-:_ 
was 
thc only 
t-axon I 
imited 
to 
the 
f irst 
half
'of 
the 
cooljng loop 
(discharge, 
stations 
1'and 
2) during Year 
1; it 
did 
not
occur 
in 
Year 2. 
Taia collected 
only 
from 
cooling 
loop 
stations 
included
.9.19[r-ryrbidentatg.(stations.land2),l4ytilinasp.(discharge,Stat.ion.2)'
.'fr'lonostyla 
-[ll-q 
{ 
intake, 
discharge, 
Station 2), 
A-lglg 
costata 
and 
A.- 
gutla_tq
(stati.ons1and2)..The.occurrenceofthecyclopoidCyc.lops'/9II3.ij!-.was
,restricted 
to. the 
intake 
and 
stations 
3 and 
4. 
.
tl"*__l*ears'to.be little 
conclusive 
evidence 
that the 
thermal 
gradient 
consjs-'
',tently 
restricts:or 
enhances the 
production 
o'f spec'if 
ic 
taxa within 
aiiy certain
<-: 
-i^egion 
_' 
"
of 
the lake.:'Rather, 
it 
is more 
likely that lake morphological featur'es
h.'al.-'a         
.
Cd6tip, 
pelagic 
versus 
shallow, littoral 
regions) 
and natural 
year-to-year 
varia-
tions in 
population 
occurrence 
are 
the 
principal 
factors 
governing 
spatial 
dis-
. 
tribut,ion. of 
species'.
'-:. 
I:
', 
l.'   
t.,,lt 
..,. 
'
t:  
:i
6.9