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    I
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    a Lltr'L)e
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    t,he
    Lwo
    previols
    anrrual
    reports,i
    0n1y
    data
    whjclt
    ..:
    were not
    previously
    subrnitLed
    is
    jncludad
    in
    t,lre
    ,:'
    Appendix
    associated with
    this
    final report.
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    'nortJholo,lie
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    [i]!-
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    ,i..lirr:.
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    ,rnrl il..{rJr'i
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    rtr},li
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    leve!
    t.r slrongly
    5lcpinq lplnnds
    ii:ehr-*r:hachr:r
    ei
    ,ri.
    lq6l).
    :
    .
    {lof
    fr.:en
    Lak+: is
    d
    relativr:ly
    {leep
    irnporlc,trnenl in
    cq,nFaris{jil L*
    uther-
    !!lirroi.,
    i^Lrsf!'voir's.
    The f,?4
    ilqiitd,
    lglBD)'
    I irferl
    sr:lee
    terl
    p.lrdrreL,:rs
    for,
    353 lliinli..
    lakCS ,ind
    |'Clt0rtrl/l IltaL
    Cilffrtfrr
    lrarl
    ,'|
    qr'rtdttr
    rnrarr
    dr:1rth
    (ti.i.'r
    )
    .inrl
    ;1,11jr11,rr
    ilr,'llt.it
    (
    l/,7
    ,'r)
    [ir.rn
    95
    p,trcent
    nf
    Llrt-, lakes
    latlrlial.r]rj.
    'j
    rr,l
    l
    ikri
    .r'l
    sri
    rra,i ,r
    relative!y lriqlr
    volrJrnc
    dfvelopillcnt
    raLio
    (0,g/)
    ..lrl(l
    nr,
    rjr.Lcrlsivr:
    slrorel
    ir-rr.:
    (7/.1
    knr).
    The
    coal-fired Coffeen P0wer
    St,rLion
    cornple.t is
    located;rrljacrlnL
    Lrt,rrrr!
    rrbtrrjns,
    'ntsL
    of
    iLs ftrel
    (lto.
    6
    ller,'n)
    frorrr
    ConsolidaLc<i
    Hillsboro
    Coal
    eo,npanys,
    undergroun(l
    coal rnine. The first
    of
    Lwo
    units
    aL thc'Coffeen
    Power
    SLaLiorr
    hegan
    operation
    in
    1965.
    UniL
    I
    has
    a
    gencrnLing
    capacity
    of 350
    t'let;
    wilr
    an
    rlsSociat.erl
    circrtlating
    water
    purnp
    disclrarge
    0f 146,500
    qpr4,
    lJniL
    2, which
    heqarr
    electric
    generalion
    in
    1972,
    provirles
    595
    l'le|.l
    and hds,t
    circulat.irrq
    wat.cr
    pullp
    discharrle
    of 253,000
    gprn.
    These
    Lwo
    units,_!$e,l
    on,a
    70
    percent
    loacl
    factor,
    have a maximum
    heat rejection
    o(4.36
    .-.-.-...
    BTU hr-l alnd
    establ ish
    <tr't rrvcrdQe
    lZ"
    C
    ri
    se in vlater
    temperature
    across-
    n50rs.
    gno
    esLaDtlsh
    art rtvcrdQe
    lz-
    ,ors.
    The
    therrnal
    effluent
    leaves
    I
    I
    I
    I
    I
    I
    I
    T
    T
    I
    I
    l-
    t
    I
    T
    .r,he
    g-enetating
    f
    acility
    via a
    0.9-km-long
    discharge
    canal
    and'enters.Cof
    feerr
    l-ake by
    flowing
    over
    a hot darn.
    The discharge
    t,lrcn
    tollols
    a
    clockrvise
    paLtern
    :
    -:
    ",
    :
    :
    '.alon,
    a
    6.6-km cooling loop.
    151s,'-provides
    324 ha of
    c0oling
    area
    (73'per.cen1
    ,'
    l
    :
    '
    ,:
    t,
    ,.of
    th9.,l.gkp surface)
    and
    produces
    a
    total
    'lake
    loacling
    raLe
    of
    0.86
    Mer.t
    r"ro-1
    i
    CTLI'E
    ^
    :,:
    ,,,i
    t
    ',
    '
    fr|
    '
    :jr:
    :.
    .:.::
    t.
    ",',
    ':
    ,t,
    l'
    l'
    -,,
    l=

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    -':.'
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    ..;.:,':
    ,,';:
    ,,.
    ::
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    j.
    l''-
    ....
    .
    :
    I
    .:.
    T
    ,l-''
    '
    ,1,''"t-',"'
    i,-
    ,l
    ,";.
    Tallle
    l,l, Physical
    tharacteristics
    of
    Cr:f
    feen
    Lake
    1,,'
    l'-
    Surface
    areal
    llean
    dept
    h:
    l,lax
    i
    mum
    depth
    ;
    ShoreI ine
    Iength:
    Storaqe
    capaclty:
    l,latershed
    dra i nage:
    Bottom
    slope rndex
    Shorel
    i ne developrnent
    i
    nrJex
    0rainage
    area/lake
    capaciLy ratio
    Annual
    loss in
    capaci
    ty:
    Volume
    develormerrt
    index
    446 ha
    5.7
    m
    l't
    ,7
    n
    71. I
    km
    2,7? x
    107
    rn3
    .4,q5
    x
    l03'ha
    .3206
    :
    10,6
    ,6
    .05
    percent'
    ,97
    l.:
    I.:
    I:
    1,,
    -..
    i
    ',
    l'.,',r,',
    I:"
    :'
    ;
    r
    I.:
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    :i
    r..-
    1,..'',
    ;:'
    l
    ^r.\)
    [r'
    \J
    "::t:i..
    ..
    .
    .::
    ,
    aaa
    :.:
    ,:.
    ::;:::.',
    _t'
    1.3

    I
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    I
    ',1
    I
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    ti::_:
    :
    z:
    =,
    ::!
    :
    a::r'
    :':,,
    a:a
    .
    a::i
    i!:':
    ='':':
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    :-:
    :
    :.
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    6ross
    electrical'output
    of ilre
    Coff
    een
    6eneratiqq
    .rt
    ii.i{.tn i{n!;
    luite
    tdr.iaiilr:
    (Fig.
    l,l)
    as
    is
    typical
    0f rnost
    c0dl-f irerj
    units.
    [\rr'i4r3
    thr] nrrrtht
    iyf
    ;igrr'ri,
    May,
    November
    and
    0ecclnber
    of
    l9/9
    and i980,
    oulprit-
    itis reiliic{.j(1
    hrc
    t,rsrl
    ,ri
    scheduled
    maintenance,tnd
    repair
    work
    at thc
    power-
    planl.
    Sirrc.c
    the
    enset cf
    this
    studyr
    max{rnum
    stimrner
    and
    wirtter
    rt isclrarr;e
    Lemper-,tl.rrr'f:s,
    oij(t1,lre11
    at
    the
    enrJof'nu.*'Xingzone';:ii'1:',..io?6'crrC5PeCLive]y,
    Several
    Inodif
    ications
    of
    :ilastewaler'
    treatment
    f
    aciliLies
    aL the
    pow,..:t.
    sLaticn
    were
    conlDleted
    after
    this
    environmental
    study
    began.
    lnclurJed
    were
    isolation
    of
    aslt
    disposal
    prntts
    frorn
    the
    lake
    basin
    {completerJ
    in
    Auqusl
    lgTg),
    consLr.ucLion
    of a
    settlirrg
    basin for
    coal
    pile
    run-off
    (conrpleLed
    in
    February
    l97g),
    ancl
    construction
    of,an
    equalization
    tank
    for
    rnixing
    of
    brine
    anrt
    rlernineralizer
    wasLe
    products
    (Fig..l.2).
    These facilities
    served
    to l)
    pievent
    ash
    pon<1
    effluents
    fro'n
    entering
    the
    lake,
    2)
    prevenb
    coal
    pile
    frartictrlates
    f1616
    1-'1lg1.inq
    ilrtr
    lake,
    and
    i) buffer
    brine
    and
    demineral:izer
    wastes
    (a
    soldtio,r
    of brinp
    sttlfuric
    acirJ,
    and
    s0diun hyrtt'oxicla)
    from
    pll
    extremes
    prior
    Lo relrlt'tsr,
    inlr:
    tht
    lake,
    Fottr rnajor
    satnpl
    ing
    stations
    were
    estdbi
    ished t.o represent
    arc.1s
    (-)xposcrl
    to
    various
    therrnal
    regimes
    and
    were
    sampled
    by
    all invesLigators.
    Stdtion
    I
    was
    Iocatecl
    irr the
    thermal
    clischarge
    aril,
    Station
    2 was
    established
    near
    the
    midpoint
    of
    the
    cooling
    loop,'station
    3
    was
    situatecl
    norlh
    of the
    intake
    hay
    as
    a
    thermal
    transition
    area,
    and
    Station
    4
    (which
    was
    partially
    isolated
    frcrn
    lhe
    rest
    of the
    Iake
    by a raiIroacl
    causeway)
    was
    regardcrl
    as
    ilre
    ambient
    area.
    Approxirnate
    djstances from
    the
    thermal
    outfalI
    to
    stations
    i
    throuqh
    4,
    respectiveiy,
    were
    0.8, 4.0,
    6.9,
    and
    8.4
    Km.
    In
    aclditiorr,
    ancillary
    staLjons
    for
    certain
    aspects
    of the
    strtdy were
    located
    near the
    inLake
    ancl
    rtisclarge
    structures,
    at two
    other
    interrnediate
    points
    witlrin
    tlre
    cooling
    loop,
    ancl
    at
    thc
    north
    end
    of
    the
    lake
    where McDavid Rranch
    enters
    the lake
    llasin
    (Figure
    l.Z),
    I
    I
    I
    I
    a.a.
    -1,
    .|,.4

    :-'
    ,,
    -:.
    t:.
    I
    1.
    {J
    ^
    tp
    v)
    Uqr
    c)d
    F1
    Qt.
    r-t
    L:
    fiq)
    at
    0r
    ")
    c)
    .i
    qJ
    ti
    t
    ol)
    i
    ,a.;:,.
    I
    ,r.1,.
    I
    .l
    I
    I
    I
    .
    I
    I
    t,'
    I
    -
    I
    ,.
    !
    I
    I
    I
    I
    I
    I
    I

    I.
    fum Infloxing
    Strearn
    t
    t
    I
    I
    I
    t
    I
    I
    I
    I
    I
    I
    I
    I
    I
    I
    I
    I
    I
    Coffeen
    Loke
    I
    too
    looo
    M.t. r
    I
    11"--..-.:
    N
    t
    tt..
    \
    L,
    =
    Moior Sompling
    Srorion
    Last
    Arm
    '
    Inflowing
    Stre;un
    Slag
    ,
    Pnnrl
    Yhormo
    I
    Outflow3
    3i,l;t""'
    :r
    loperation
    2op;udi;,t
    3operation
    ceased Feb.,
    Degan I.eD.,
    ..
    ceased
    Aug.,
    1979
    r979.
    i
    t979
    Sanrpl
    ing
    s ta
    tions
    on Co f f een
    I,ake.
    ]:
    ::t.
    .
    ::.4'.,
    .:
    ,l
    .
    llr
    ,1..
    v
    F:"gure
    1;2
    ''.t
    '
    '
    [_J:
    Ancillory Sompling
    Srorion

    --
    ::I
    f:
    ,I
    :-
    :I
    ::
    .
    LITIRAIURTCIII.O
    Central
    Coffeen
    Illinoia
    Power
    Public
    Station
    Service
    Urtits
    Company,
    r
    iriJ"i,
    197l.
    'iuoniifoo'to
    Thermal
    Denronstralon
    f0r
    ure
    iiitnoii
    poiiurion
    Control
    Board, Ma-v
    1927.
    .
    Fehrenbach€f1.,1.
    ?.r-!r
    0,
    l.latker,
    anrl ll,
    L,
    l.tascher.
    1967. sails
    of
    Illinois.
    ':'Unlversityof
    '47
    pp
    Illinois
    Agricultural
    ,[xper.i'neni
    Srution.
    grii.ti"
    ji;','-'
    Il
    linois,Environmental
    Protection
    Agency,
    l97Ba.
    AssessrnenL
    and
    Cl assification
    of
    Illinois
    Lakes,
    Vorume
    I.
    208 witer
    Quat
    iry
    raan.gur.nf-pi;;;i;s
    p;;;;:;,n
    ,
    ,!tafr
    !gpirrt.
    state
    of
    Il linois,
    tnvironmentai
    proriirion
    ngency,
    Spr
    i ngf
    iel
    d,
    I
    I
    I
    ino.is
    .
    Il
    I
    inois
    of
    Il
    Environmental
    linois
    Lakes,
    Protectiorr
    v0lume
    l
    l.
    Agrncy,
    "zgg.Hater
    l97Bb.
    Qualiiy
    Assessment
    i,lanagement
    anrl
    planning
    Cl assification
    frogral.Staff
    Report.
    state
    or
    ir
    t inois,-E;;ii6nmentit
    prorection
    Agescy,
    Springfield,
    Ill inois.
    Il
    linois
    Natural
    History
    Suryey,
    1glg,
    [nvironrnental
    Studies
    of
    Coffeen
    Lake.
    'First
    Iext;
    Annuat
    Vol.
    I
    I,
    Report
    Appendices
    to
    centrat
    Illinois
    public
    Service
    ccn[int;
    1l;;.'';;"'
    Lopinot,
    DepartnentofConservation,Springlietd,.IIljnois..}l9pp;
    A.-
    c..
    l?79., r,lontgornery
    county
    surface
    water
    resou.css'.
    Iilinois
    Schweqman,
    'J.^E..
    19i3.
    Comprehensive plan
    for
    the
    Il
    I inois
    l,lature
    preserv,ls
    System,
    Part
    2.
    Tlte
    Natural
    Divisions
    of Illinois.
    lllino'is
    Natu;e
    .'-
    Preser"ves
    Conmi
    ss ion.
    32
    pp
    .l
    ;l
    I
    ll
    ,l
    aa
    .'
    I
    I
    ..
    ti:.-
    .:
    :.:.'
    :.
    ::-;.:,
    :.'
    ):"
    1:
    :
    ,.
    t
    .
    .t
    :
    ..:
    i.i.
    a
    ::
    '
    .
    ,':':
    '':
    '
    ,:::
    "'
    .:l,
    :.
    ::rr
    .
    ,.-:
    ii.'..
    '
    ,..:t=
    .,:...-
    .-:
    Ii ,.
    l'':
    ..'

    :
    5Ecil0lf
    ?
    ,
    :
    I
    TlttRi4AL
    --
    --
    I'tApptHG
    "
    0F
    C0rrttfi L&ri[
    a
    :
    :
    Sarah
    t.iehr-Storck
    ABSTRAC
    I
    .
    ''
    Thermal
    mappino
    was
    conductert,q'larlerly
    at
    Cof
    feen
    Lrke
    dtlring
    the
    period
    f rom
    september
    l9/B through
    Sepiemoer 1979,
    and
    semi-drflrrdlly during
    the two
    fol
    lowing
    years.
    Little variation
    was
    found in
    surfdce ternperotures melsurerj
    {lcross
    transects
    located at known
    rJistances
    from
    the discharge.
    The only
    rnajcr
    exception
    occurred in
    l'larch
    l9B0 and
    February
    lg8l when the thernal
    plume
    stayed,
    close
    to
    the
    east bank north
    of
    the
    darn f
    or a
    rlistance
    of
    l.0
    to L5 ki lomer-ers.
    '\++:5'1-:1l#-+:-*+E4
    The
    dischargc'
    arm
    of
    the
    '!rke
    usual
    ly had
    dif
    ferent
    vert
    ical
    ternperature
    distributions.
    :4u1t.r
    !.[rgn
    !he-1g$-*of-.-tne
    lake,
    with
    a distincI
    change occurring
    in
    Lhe
    vicinity
    of t\q!U.
    .'r*-
    lhe
    rJischarge
    arm
    of
    the
    iake'-ien,ieA
    ts
    itay
    tfiFrmilly-
    stratifieC'at'a
    depth
    of
    about
    tro
    meters,
    with
    much
    warnrer
    water in the
    top
    layer.
    In
    the
    vicinity
    of the
    ,.''
    clarn,
    greater
    rrixing
    and
    larqer
    water
    v0lume
    c-qused a distinct decrease in
    surf ac6-watei
    ternperaturas.
    rrJater
    temperatures in
    the
    ---*
    cooling loop diti not
    vary
    greatly
    between
    the
    dam
    an<J
    the
    intake
    canal
    cove.
    A
    distinct decrease in
    temperature
    occurred
    at the railroad
    causeway!
    inJlcating-
    that
    water temperatutes
    north
    of
    the 19!lroarl
    causeway
    were
    not
    6ffs61ed oy
    the
    --'
    -'-----:.-------'--
    '--''..=.
    thermal
    discharqe
    !o
    the
    sarlg_extent
    as
    _w_a-t*er ,t,empgratures
    souilr
    of the
    l4q:91g..
    Vertica'l
    temperattre
    distributions
    did not
    correspond
    to
    normal
    ,.
    stratification
    patterns.
    thermal
    discharges
    prerented
    winter
    stratification,
    and
    ice formation
    except for the
    area north
    of the railroarl
    causeway.
    Both
    winter
    temperatures and summer hypolimnetic.temperatures
    were
    hiqhcr
    than
    norrnal in
    the
    iower
    region
    of
    the
    lake,
    possibly
    allowing
    greater,bacterial
    activity
    anrt
    thus
    '
    greater
    rates
    of
    cyclinq
    of
    nutrients
    and other mlnerals.
    !n the sLtmftre!"
    neii)
    ,
    the dam,
    rather than
    the
    normal
    situatlon
    of
    two
    isotheimal layers
    of
    water
    ttt
    separated
    by
    a
    therrnocline',
    ihere were three isotherrnal
    layers
    separated fry
    tw{
    \
    .
    .:...
    thermocl
    :.:.
    ines.:
    j
    The
    to_p,.layerr.r:eq.g,]:ted,frq-nr
    ,
    ;.
    ,..:,,t
    tt
    '-
    warr,ri'water
    fr:bm the'discharge
    arnr
    /
    .:
    .
    t/
    stayingonthesurfacer.ttherthaImjxing...
    ,:
    l,,t
    l,i
    :!
    '.
    :
    Ctl

    I
    I
    I
    rli
    !\';lrj
    il{In00tJcr
    tOti
    blater
    temperature
    is
    an
    irnportant
    p0rdmeter
    af f
    r:ctin,J
    l,rke.,
    bcr.,rusrr
    i
    i
    infltlences
    not
    only their
    phyrical
    characterisLics,
    but rt\0
    !.h4ir
    r.ricmical lnrl
    biological
    choracteristics.
    Becarrse
    differenr.
    i:larit
    and
    lni{ral
    species
    have
    dif ferent
    temperature
    tolerance
    I imits
    anrl
    Itrnperdture
    optima, tcmperdl(rrc
    citrl
    af
    fect
    'the
    biota
    directly
    by l imiting
    tlre
    rJistribulion
    of species
    or
    by
    dctermininq
    the
    species
    composition
    of
    cofimunities.
    Temperalure
    also affec.ts
    tlte rete
    of
    biological
    activities,
    and lhus
    dlfects factor^s
    srtch
    as
    growth,
    deconipositiort,
    oxygen
    consunption
    and
    evolution, anrl
    nutrient
    and other
    nrinrlral
    cycl ing thaf
    delermine
    the
    biological
    clraracteristics
    of
    a lake.
    Also,
    becausq
    of
    the relatianstrip
    betwer:n
    water
    ternperature
    arrd r!ensity,
    tenperature
    distribution
    deterrniles.
    circulation
    poiiurnr,
    anrl thrrt
    o^yn*n
    levr,ls, in
    parts
    of
    the
    lake
    whicn
    rneli
    restrict
    anirnal
    l,ife
    anrl alter bacteriol
    ,ictivity,
    :.;
    :
    .,:
    -TItt;rcfo5e,'a
    tltorough
    understanding
    of
    teinpera',lure
    dist.r'ibut,iorr
    is
    essenlial lo
    assessinq
    the impact.
    of tlterrnal
    ef
    f luents
    on
    the
    cherrrical
    a*d
    bioloqical
    clraracteristics
    of
    a lake.
    '
    ','
    r1
    ,,.
    ",11
    ,.
    ',,.,,
    ,.
    '
    Cof
    f een
    Lake woulrl be
    cxpected to
    have
    tI
    i
    f
    ferent
    tempr.'rature
    patlr:rns
    iltan
    nost
    lakes
    in this
    geographical
    area because
    ib
    is
    a
    cooling
    lake
    which
    cir.culates
    I
    arge
    quant
    i t ies
    of water and receives
    a' heaLetl
    cffl uent.
    Temperalur.e
    distribtrtions
    were
    alstl
    affectetl
    by
    climatological
    events
    anrt by
    t)ower
    plant
    generation (Fiq.
    l.l).
    The
    purpose
    of
    this
    study
    is
    to
    provirJe
    backgrounrl
    information
    cn
    annual ternperature
    patterns
    in
    Coffeen
    Lake so ihat the
    chemical
    ;:j,:H:l;:r'
    ,".
    can'be
    interpreted in
    the
    conlexr
    of rheir
    rhermal
    I
    t
    t
    I
    I
    l
    :::
    -
    i:,
    :,::j-:
    I
    I
    t
    I
    I
    I
    T
    I
    I
    T
    ?-,2

    ::)!:-
    '.:
    .':-
    -i.
    I:rj
    l,t'
    ,.3..
    l,:..,
    I.
    l--t-
    -a.-:,:
    j,-..-
    1,..
    I,r:,
    I,,,
    :
    i-i:::,:-
    ..t
    ;,r,1.:,
    ..
    :,1:
    t,.:
    I:
    I
    ,,:':
    I"
    --
    ,
    I
    I
    lr,
    'i
    t'''
    '-r.,
    r.,
    r...
    -1',
    glr:-:-:
    I::
    r.lAr[R
    lA[S
    AND r4tTr10i]S
    Ihq
    ther,mal
    plume
    wis
    $easured
    at:
    qilarterly
    intcrvals
    dur^ing
    the
    f
    irst
    .r,ear
    of
    sampl'in13,
    and at
    semi -dnnual
    interval
    s
    durinq
    thc
    secr.lnrt
    ,tnd
    thirrl
    years.
    .Vertjibtit'proflles Here
    measrrred
    at
    l-meter
    depth
    intervals
    along
    transects at
    known
    ttlstances
    from the thermal
    discharge,
    Tt'o
    to five
    vertical
    profiles
    were
    measure..J:
    along
    eachr
    traniect,
    depending
    on
    the
    length of that transect.
    Three
    boats
    Here
    used
    when
    possible
    to
    complete
    medsurements
    over
    the
    entire
    lake
    in
    as little
    time
    as possible,
    Temperatures
    werc medsurer,
    with
    YSI
    r{odel
    57
    d i
    sso I ved
    oxygen and YS
    I
    l'lode
    I
    33
    S-C-T
    meters
    .
    i)rofiles
    of temperature and
    dissolved
    0xygen
    were
    measured twice
    per
    rnonth
    at
    l<neter
    rlepth intervals from
    mid-lake locations
    at
    Stations
    i, 1.5, 2, 2.5,3
    anrl
    4
    (F'ig,
    '1.2).
    These
    measurements
    were
    taken
    with
    a YSI
    tlodel
    57
    dissolved
    oxygen meter.
    .:
    '.'
    ,
    Therrnal mapping data
    col
    lected,during
    al I
    three
    years
    of
    ,...
    in Appendices to dnnual report.s
    (Liehr
    l9i9;
    Liehr-Storck
    lgBl
    ).
    Ternperature
    anrl dissolved
    oxygen
    profi
    le data
    are
    ,
    Appendices to these'reports
    ..I.
    TEMPERATURE DII-FERENCTSACROSS IRAf{STCTS
    ln
    general,
    very 1 ittle variation in
    temperature
    occurred
    linking one
    side of
    the
    lake
    with
    the
    other.
    There were
    1,1.,.'
    I
    ake, however,
    where
    sorne dif ferences were observed.
    tlris
    ttudy
    can be found
    1980;
    Li ehr-Storck
    also
    listed
    in
    across t
    rarlsects
    two
    locations
    irr the
    In
    the'main
    arm
    of
    the
    lake,
    temperatures
    were substantially
    higher
    along-the
    east bank on
    the
    dates of 4
    lllarch
    '1930
    and
    16
    February
    l9t]1 .
    The
    clif
    ference
    in
    surface
    temperatures
    between the.east
    and west hanks
    just
    north
    of the,dam
    was
    6.7,'C
    'oir;
    4
    tlarch
    lgB0land
    5.4?C on
    l6
    February:
    l9Bl
    . Temperatures
    remainert
    ,-.1
    a,,:::,-.:..
    :..::::.':t'r.:
    2.3

    dif
    ferent
    for,,
    a.
    distance
    of
    1.0
    to-
    1.5
    kilornetr:rs.
    i,linds
    were
    f
    airly
    stronq on
    both
    of
    these
    sampling clays
    at
    alrout
    l0implr f
    rorn
    thr:
    touth anr, sou1rrwcst,
    llowever,
    strong
    iinrJs f rom the
    'soutlr
    and
    soublrwest were
    also
    presenL
    orr:olher
    days that
    thermal
    rnapping
    qreasurements
    were taken,
    and
    thesr,
    large
    lempcrature
    rtlfferences
    were'
    n0t
    observerj.
    A
    much
    less
    pt'onounced
    difference.,in
    temperaturc
    across a
    lakcwide
    Lransect
    occurred
    just
    north of
    the rai
    lroad
    causeway.
    Tcmperatures
    were
    sl
    ightly
    higher
    in
    the
    middle'of
    the
    transect'on
    z0
    November
    l978
    and l6 February 1981.
    Slightly
    higher temperatures
    were
    observed
    on
    thc
    east sicle
    of the
    transect
    on
    B Augttst
    l979,and
    22
    August
    1980,
    0peninqs
    (culverts)
    are locate<J in
    ilre middle
    and on the
    east
    side
    of the
    railroacl
    causeway,
    and these temperature
    variaIions
    may be the
    result
    of
    water movement
    through
    these
    culverts.
    Again,
    wind rtaLa
    were inconclusive
    as
    a causative
    agent,
    since this
    phenomenon
    ylas
    not always
    observetl
    under
    s imi I ar
    wi nd
    cond
    i
    t i
    ons
    . If w,iter
    exchange
    was
    occurr i,rg
    ilrrouqh
    the
    culverts,
    hoi{ever,
    it
    was
    either
    at
    a
    very
    slow rate,
    0F rnixing
    was r-apid
    ly
    occurring,
    as temperature
    clifferences
    were difficult
    to
    detect.
    TEI.IPIiRATURE
    DIFFERENCES
    |.lITH DISTANCE
    FROM
    DISCI{ARGE
    Since temperatures
    were
    fairly
    uniform
    across transects,
    mean
    ternperatures
    at
    0,
    2,5,
    l0
    and l5
    meter
    depth
    intervals
    were
    calculaterl
    Lo
    observe
    seasonal
    patterns
    of distributjon
    of waste
    heat
    with
    depth
    and
    rlislance
    from
    the
    di scharge.:
    ,
    femperature di
    stribution
    i
    n
    the
    summer
    season
    was notably
    di fferent
    fromtherntaldistributionjnthewinterseason.i
    Thermal
    mappings
    comp'letect
    on l2'september
    1978,
    B
    August
    1979,
    ancl
    22
    August
    l9B0 indicated that temperature
    djstributions
    were
    simi lar
    during
    the
    hottest
    times
    of
    the
    year (Fig.
    2.1).
    Thermal
    stratification
    (a
    barrier
    to rnixing
    as
    defined
    on
    paqe
    2.8) occurred at,a deptlr
    of about
    two
    meters
    in the
    area
    of the
    lake
    between the
    discharge
    and
    the.dam.
    Stratification
    at nine
    to ten
    meters
    occurred
    at
    locations in the lake that
    were at least
    ten
    meters
    deep. The
    temperature in
    the top
    two
    meters
    of
    the
    water
    column decreasecl gradually
    thrbughout the lelgth
    of the discharge arm.
    A
    more
    drarnatic
    decrease
    in
    2.4
    T
    I
    I
    I
    I
    t
    I
    I
    I
    I
    I
    I
    :l
    .l
    'l
    '
    ::.:t;
    t
    l

    25
    eo
    t!
    o
    F
    (D
    E
    trl
    o
    I
    L,l
    F
    c
    ul
    ul
    G|
    DlSTAllcE
    FRoM
    DIS0HARGE
    (
    xu
    )
    SURFTC€
    2
    r€rEFS
    3
    ETERS
    IO
    I'€TEFEI
    It
    TETERS
    Lake
    in
    relation
    to
    :
    I2
    September 1978,
    ,
    ol
    F
    :Ct
    F-
    6
    ^
    (t
    I-'
    f
    I
    o
    lrJ
    E
    f,
    F
    c
    (L
    lrl
    l!
    >
    F.
    q,
    o
    O)
    F
    o
    ct
    )
    3
    N
    o,
    Figure
    l
    ,''''
    Temperature
    di.strlbutlon
    in Coffeen
    depth and dlstance from discharge on
    8
    August 1979, and 22 August 1980.
    2.5

    ffi'''-
    ffi.-''
    kl:
    :
    F''
    H:,
    Fir
    lTli:
    FJ
    ffi:';.
    si:.,
    li:,
    #t'
    Fi,.
    k;..
    f;:
    Fi.''.'
    b:t:::
    :: :
    ::>t.-r
    :'
    fi:::;:::: *
    i.li:
    .,,
    f:-i''.:'.:,
    F:'::1:
    ..:
    [i:'ir'
    -
    '
    ili
    i,.':.:
    .'''
    ,:
    Ii:1,
    '
    ..
    'F1r;1;1',,.,'
    tj):.:: .
    .
    .
    "il:'i.,,1,
    ff:.::l
    ' :
    -l.';:,,-'''
    !':-::,
    :
    :;:..:.,-'
    ;iir.
    '
    .1
    i'li-
    i;:r;:,;:
    ,
    i!,:'.",t.,,
    fti,,,:-
    i1.:.
    .
    ''",
    .
    f..'.'-
    '
    ';:.1;,;.,:'.
    ,
    l.lt,:.::,"
    '
    "?i.,,
    lilo',:,:;;,'
    +1.,-,
    ;j-,,':.:
    J
    rr"
    :
    ')
    i',tt,''-
    :i:l:.:
    :.':'
    :'
    ;{j::::::i.
    ' :
    'i7'):tt:.-
    6l:;r:l;..,.
    !i
    l
    7:;::'.:.
    '
    ii'"
    ';:,
    !i::
    t.
    '.'-
    .l
    It::
    '
    i,
    '-:
    *-i*.
    ''l
    i:::::
    "
    :'
    i:i;'.: ,
    temperature
    occurred
    at the
    darn (except
    on
    Z?
    Augrlst
    l9B0
    when
    planL
    gener,rtion
    was
    reduced)
    followed
    by
    only
    slight decreases
    in
    water
    ternperalure
    nlong
    llic
    retnaining
    length
    of Ltte
    cool
    ing loop.
    Tenrperatrrres
    dccreasert
    nore rapidly
    in
    the'area
    of the
    lake
    rreyoird
    the
    intake
    cove,
    arlrl then
    a rapid:dc,cline
    occurrcd
    at,the
    rai
    lr:oarJ
    causeway.
    t.later,
    temperatures
    al f
    ive
    anrl
    Len
    rnelcr
    rjeoLhs
    did
    not,change
    fiuch along
    the
    coolinq
    loop
    or heyond
    to the railrcart
    cduseway.
    The
    winter
    therrnal
    'nappings
    also
    showed
    simi
    lar
    temperatur.e
    distriLru.r.ions
    (Fig.
    ?-.2).
    Data
    frorn
    B
    March
    I979
    were
    not included
    liecause
    the
    l)ower
    plant
    was n0l
    operatinq
    on that date.
    Thermal
    stratificalion
    occrrrred
    at a
    Cepth
    of
    one,to
    two'meters
    in the
    area
    of the
    Iake between
    the
    rJischarge
    antJ
    the
    :
    spilluray,
    with temperatu,res
    in the
    top two
    meters
    aqain
    decreasing
    qr.ariual)y
    with increasinq
    distance
    from
    the
    discharge point.
    A-." the
    spil
    lway,
    .lrowever,
    a
    very
    rapid.'temperatttre
    drop
    occurred.
    During
    winter,
    the
    resl
    of
    the lake
    was
    not stratif
    ied,
    and
    surf
    ace
    ternperatures
    decreased
    onl-y
    slighily
    within
    Lhe
    remaincler
    of the
    cooling
    loop.
    0ther
    temperature
    difierences
    occurr.erj
    at
    the
    intake
    cove
    and
    at the
    railroad
    causeway.
    !Jater
    ternperaturcs
    at five
    and ten
    meter
    depths
    increased
    in the
    reqion
    of the lake
    between
    the
    spillway
    arrl the
    intake
    cove
    as
    a
    result
    of
    more
    even
    winter
    verLical
    dist,ribuLion
    of heat
    thruughout
    the
    water column
    in
    areas
    beyond
    the
    rJischarge
    arnr.
    ldater
    t.
    ternperatures
    :
    that
    were
    2 to
    3"C
    cooler
    were
    found
    at the
    rajlroad
    -
    causeway
    at
    '6'11
    times
    that
    rneasurements
    were taken
    beyond
    that'st/uctur:e
    excepL
    22 August
    l9B0
    when
    the
    decrease
    llas
    only
    about
    l"C.
    These
    data
    inclicai,ecl
    that
    the
    rnixing
    of
    w.ater fr"orn tlre.north,and
    south sides'of
    the:causelay
    was
    considerably
    slowed,
    anc
    that
    the
    portion
    of the
    lake
    on the
    north
    side
    of the
    causeway
    was
    noliceably
    Iess
    impacted
    by
    thermal
    effluents from
    the
    power
    plant
    than
    was
    the
    por:tion,.of..thelakeonthesouthside...:
    THERMAL STRATIF
    ICATION
    .
    Aphysical.qropertyofwateristhatits.densityincreaseswithc|ecr.easing
    ternperatures
    (to
    a
    ternperature
    of
    4'C).
    Because
    of
    this
    property,
    Iakes
    Seconre
    stra.tif
    !ed,,when
    so11e
    I
    ayers
    change temperature
    ,more
    rapidly
    than
    other
    layers.
    ln,rcmpeiate.regiq'ns,
    thi.s'phenomenon
    is
    a cornmon
    occurrence
    in most.lakes
    '_l
    ...
    I
    t
    I
    ,l
    I
    I
    I
    I
    .l
    I
    I
    .T
    :
    I
    't,
    :'
    I
    '1.
    't
    a:,
    ,:
    "1.
    2,6

    ''.
    o
    @
    ol
    !'
    (J
    q-r3
    r::,
    ct0
    AO
    ()
    ,o
    \
    \
    SPILLWAY
    :
    DISTANOE
    FROM
    suRt
    cE
    ----2
    fTETERS,
    -'-i-r
    -
    'lO
    IIETERS
    89
    IIIYAKE
    RAILROAO
    UJ
    G
    l
    F
    G
    o-
    ru6
    =
    Fg
    c
    l
    e.
    ,@
    tr.|
    l!
    @
    30
    23
    t5
    to
    5
    o
    1,-r ;
    ..
    .f'lgure
    2.2.
    DTscHAROE
    (xu)
    Temperature:distrlbutlon
    :.':
    .
    .
    in Coffeen
    Lake in
    relatton
    to
    depth"and
    dLstance
    f rorn dlscharge
    on
    /r
    lrlarch''1980
    and
    16 February
    1981.
    :,';. . .

    l,
    .
    ourln9
    !he
    surmer.
    ond
    winter,
    A ternperature
    drop
    of 1.C
    Der
    nieler
    rjr:pth
    is
    generdl
    ly
    cortsidered
    to
    cause
    a
    rjensiLy
    qrarlienL
    suf
    f
    ic'ienl
    to
    act
    ds
    o
    bar.rier
    to
    mixing,
    arrcl
    will
    herein
    be
    used
    as the
    rtef
    iniI
    ion
    of
    Lhe
    rrn36l
    qns.
    Sincc
    Cof
    feen
    Lake
    is
    subjected
    to
    temperature
    jnf
    luences
    oilrer thr.)n
    c.l
    imorological
    ones' i.e',
    it
    rcceives
    ---i.
    --
    a heated
    efflrrent,
    this
    lake
    would nof
    be
    expecle(t
    Lo
    stratify
    in
    t'he
    same
    patterns
    as
    other
    lakes
    in
    tlre
    same
    geo!r-a0hical
    area Lhat
    are
    subjected
    to
    only
    climatological
    influences.
    Stratificaiicrn
    patt.erns
    were
    studied
    by
    means
    of
    temperature
    profiles
    measured
    twice
    per
    monLh.
    Dissolved
    oxygen
    concentrations
    were also
    studied
    to
    help
    determine
    the
    stability
    of the
    t.herrnal
    strat
    i
    f ications
    observed
    Stratification
    in
    the
    winter
    norrnally,occurs
    when
    Lhe
    water
    cools lo
    below
    4"C.
    i'Jater
    at
    4'C
    has the greatest
    density
    and therefore
    stays
    aL
    the
    bottom
    while
    water
    above
    jt
    continues
    to
    cool
    until it
    freezes
    at
    0.C.
    tjn<Jer
    the
    ice,
    biological processes
    continue,
    although
    at
    a reduced
    rate,
    and
    oxygen
    can
    llccorne
    depleted
    since
    there
    is no
    exchange
    with the
    atmosphere.
    In
    Coffeen
    Lake,
    this
    type
    of
    stratification
    rvas
    observed
    only
    at Station
    4, and
    no
    oxygen
    depletion
    was
    observed
    during
    periods
    of ice
    cover.
    Consistent
    stralification
    was
    also
    ob'served
    in
    winter
    at
    Station
    I
    at
    a
    aepth
    of
    one'tc
    three
    meters,
    where
    thermal
    effluents
    frorn
    the
    povrer
    plant
    caused
    water at
    the
    surface
    Lo
    be
    considerably
    warmer than
    water
    at
    the bottorn.
    In
    spite
    of this
    winter
    st,ratification
    P,*a.!tern
    ilr
    the
    discharge
    arm,
    however,
    dissolved
    oxygen
    levels
    were
    fairly
    unifortn throughout
    the
    water
    column.
    The
    water
    colurnn at
    the
    oLher
    statiorts
    was
    qeiteral
    ly
    cornp'letely
    mixed
    wjth'.temperatu'res
    mosfly
    in the
    range
    of
    6 to
    14.C.
    anrl
    oxygen
    levels
    in the
    range
    of B to l?.
    nq/1.
    The norrnal
    process
    of summer
    stratification
    begins
    in the
    spring
    as the
    ice
    millts
    and
    the
    water
    warms.
    l,lhen
    the
    temperature
    reaches
    4"C,
    the
    water
    colurnn
    coinpletely
    ,nixes
    (spring
    turnover).
    l.larrning
    c<lntinues
    and the
    cooler,
    more
    dense'water
    stays:
    at the
    bottom
    while
    surface'temperatures
    continue
    to
    rise.
    A
    thermo'ilihe
    develops,
    with
    water abov'e
    (epilimnion)
    able to
    mix
    f'reely
    causing
    it
    to
    be fairly
    uniform
    in temperature.
    The
    water
    below
    (hypoljrnnion)
    is
    not
    able
    '
    to
    mix with the
    upper layer,
    and thus
    receives
    no
    new
    supplics
    of
    oxygen.
    DegomRosition
    of organic
    material
    at
    the
    bottom
    of the
    lake
    consunes
    oxygen,
    anrl
    t:1"
    In
    rnosE
    ''''
    \
    euEropnlc
    lakes,
    oxyqen
    becomes
    depleted.
    2.8
    l'
    T
    I
    t
    I
    I
    T
    I.
    t-
    t
    l'
    ,1''
    .? ,
    ,
    ::
    I
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    I
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    t

    I
    :1
    I
    Variatior;s
    of
    thls
    typical
    surnmer
    therrnal
    stratificaf
    ion
    pattern
    were observerl
    in
    Coffeen
    Lake.
    The
    water
    column
    at
    Station
    I
    was
    sLratified
    !hroughout
    the
    Sunrner
    at a depth
    of one to
    three
    meters.
    Iemperatures in the
    uppcr layr:r of
    water
    were often
    extremely
    high
    (once
    reaching
    43'C
    in
    l9B0),
    because this
    station
    was located
    close to
    the
    pohrer
    plant
    rlischarge.
    r,.lhile
    a thermocline
    does
    not
    normally
    appear
    that close
    to lhe
    surface,
    it
    was likely caused
    by
    the
    warm
    wator
    discharged
    from
    the
    plant
    tending
    to
    stay
    at
    the
    surface,
    Hypolimnetic
    dissolved
    oxygen concentrations
    were
    'low
    (frequently
    below
    3
    mg/l
    )
    but
    oxyqen did
    not
    become depleterl.
    0xygerr
    in th€ lower layer
    could
    have been
    present
    as
    a
    result
    of
    unstable
    stratification
    orr
    more likely, replacement of
    the
    water
    caused by the
    current
    from the
    discharge.
    Station
    2 was
    stratified
    from
    May through
    september
    in 1929.
    r,ro
    stable
    stratification
    developed
    in that
    region during'1980.
    At Station
    2.5
    there was
    no con^r.inuous
    stratif'cation
    for extended
    periods,
    although thermocl ines did
    appear
    on occasions
    in
    the
    summer.
    Stratification ctid
    not occur at a
    consistent
    depth'
    but occurred
    anywhere from three
    to
    eleven meters.
    Oxygen depletion
    occurred
    at
    Stations 2 anti
    2.5
    fro,n
    June
    to
    September
    in
    1979 and from
    llay to
    August
    in
    1980,
    inrljcating that
    stratification,
    though
    unstable,
    was sufficient
    to
    prevent
    consistent
    mix:ing
    of the
    entire
    water column.
    i
    Station
    1.5,'located
    near the
    dam,
    was
    adjacent to the
    discharge
    arm and was
    also the
    deepest
    part
    of the
    lake.
    Continuous
    stratification
    was observed
    in
    this region
    from lrlay through
    0ctober
    of
    both
    1979
    and 1980.
    At
    the
    beginning
    of
    the
    summer,
    for example in l9B0
    on
    June
    3,
    the typical
    seasonal
    vertical
    temperature
    distribution
    developed
    (Fi
    g.
    2.3), althouqh
    hypoiirnnetic
    temperatures
    were higher than
    norrnal because
    spring
    circulation
    had occurred
    at
    a
    temperature
    much
    higher than
    4'C.
    ft
    the
    dgpth where
    the
    temperature
    began
    to
    decrease
    rapidly, dissolved oxygen levels
    also began to
    decline
    rapidly.
    As the
    summer
    progressed,
    however, two thermoclines
    developed.
    0ne thermoc'line
    at
    a
    ,
    rtepth
    bf
    bne'to three meters,
    resulted
    fiorn
    heated water
    from the
    discharge
    arm
    staying on
    the
    surface rather
    than mixing. The
    other occurred
    at a depth
    of
    ,
    seven
    to
    dleven
    meter:s
    (Fig.
    2.3).
    0xygen
    was f airly.urriforrn
    or increased
    .',slightly
    with
    depth
    in
    the
    upper
    layer and
    becarne
    depleted in
    the
    lowest
    layer.
    l,
    2.9

    .
    :.:
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    :,...,.
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    :
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    'oB
    oIith
    'u
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    ..{
    U,
    :(!:.c
    OIJ
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    ACJ
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    v(0
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    o0:.tr
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    .J
    ,q.|
    :lJrJ
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    ts,tr
    O.:k
    eo
    o0,
    m
    :
    c'r
    ':
    .
    tU::.
    F.
    J
    t*
    (\l
    o
    a
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    o
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    F.
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    (9
    =':
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    ,o
    (fi
    ) Hld30

    Be!pen.the]tw-othermoclines,oxy9enrapidlydecreas€din.concentrationwith.i
    :
    r,
    lncredsing
    depth
    but
    did not
    become
    depleted,
    whereas
    ternperatures in
    gris
    zose
    were
    fairly
    uniform
    (Fig.
    ?.3).
    Ihese
    thrce
    layers
    of
    [he lake,
    which
    wert,
    partltioned
    by
    the
    thermoclines,
    possibly
    did
    not
    mix rith
    oach
    other during
    the
    entire
    sumnr,
    Since
    the
    mi<Jdle
    layer
    was
    at
    least
    partially
    in
    the
    euphotic
    zoner
    oxygen
    was
    generatecl
    by
    algal
    photosynthesis
    thus
    cornpensating
    for
    oxygen
    consumed
    by
    organic
    decomposition
    arrd
    preventing
    oxygen
    depletion,
    Oxygen in
    that
    -:'
    layer
    might
    also
    have
    been
    present
    as
    a
    result
    of
    occasional
    mixing
    with
    the
    upper
    iayer
    if instability
    occurred
    from
    interruptions
    in
    power plent
    gener
    at
    i
    on .
    .t::
    l
    a.:,
    ,::.
    r-
    ai:i:l
    :,,:.
    =:
    :
    ::tti,';*,1
    ',
    :.aa
    ::
    .::',.:.,:::
    2.t I

    'a"
    .:i:.
    ,
    i't.'
    r
    r'l
    ,
    ,
    :
    L
    lIi
    RAIIJRE C I
    IIt)
    .,:
    a:,
    .
    l
    '
    :
    ,i,i
    Liehr, S.
    19i9.
    Thermal
    mappi'tg.
    In: J. A.
    Tranquill
    i
    rrnd
    R,
    !i.
    Larino''e
    (eds,).
    Envlrorlrnental
    s'tudies oFCoffeen Lake:
    'First
    Annual
    Repcrt
    io
    :.
    -.
    Central
    Illinois
    Public'ServiCe
    Company, Illinois
    Natural
    tlisLory
    Survey.,,
    Liehr-Storck,
    S.
    1980.
    lhermal
    mrpping, In:
    J.
    A.
    Tranqui I
    ]
    i
    and
    lt. ll.
    Lar imore
    (eds.
    ).
    [nvironmental studies-i-f Coffeerr
    Laxe:
    Second
    A.nnual
    ::,Report
    to
    Central
    Illinois lubli: Service
    Company, I'llinois
    l{atural.
    Histor-y
    Survev.
    .:
    l
    --
    -
    -!
    -1,
    2.,12

    il.
    1I
    ,:l.i
    7;i:,'
    ,
    ,
    ,,:=.
    SECI l0ll
    l
    ,IATIR
    qUALtTY
    0F
    COf Fff.f{ LF,K[
    l'',
    by
    Sarah
    Liehr-Storck
    ABS IRA{.7
    llater
    quality
    was
    studied in
    Coffeen
    Lake
    from
    August l9/0
    throrrgh
    Oecernber
    1980.
    Total dissolvect
    sol
    ids
    ancl
    sulfate
    concentrat
    ions
    decreased
    rluring
    tire
    .spring
    flood
    of 1979, and
    then
    qradually
    increased
    to the
    end of
    1980. The
    .
    total
    arnount
    of dissolved
    solids
    arrcl
    sulfate
    in the
    lakc
    also increased
    frorn
    ,June
    1979
    to
    December
    1980.
    Perior1ic
    flushing
    of water frorn
    tne lake was
    apparently
    necessary to
    maintain
    c0nstant su'lfate
    levels,
    Aiknlinity increosed
    from
    l9't9
    Lo
    19u0,
    providing
    additiona'l
    bcnef
    icial brrf
    f
    ering capacity
    against
    pll
    chan9es.Turbid.itywashiqhestatthenorthenc|ofthe]akeafLerper.iotJsoi
    heavy
    precipitation.
    lhe
    railroad
    causeway
    with
    two
    small
    culverts through it
    served as
    a
    barrier,
    Ftrcventing
    much of thc turbirJity
    entering fronr
    the
    l
    watershed at
    the
    upper
    end
    of
    the
    lake from reaching tire
    lower
    part.
    of
    the lake;
    Totai
    phosphorus
    ievels
    r.Jele general
    ly highest in tlre upper
    end of
    the I
    ake.
    '
    ',.
    Inorganic
    nitr'ogen
    c,onccntrations increaserj
    <lramat
    jcally
    at al
    I stations in late
    1979
    anrl I980.
    The
    greatest
    increases
    of
    inorganic
    rritrogerr
    occurrer'l aL
    ,stations
    nearest
    the
    pohen
    plant
    discharge,
    and
    r,orrnal
    seasonal
    nitrogen
    cycles,
    :,were
    disrupted.
    Chlorophyl
    I g concentrations
    were corrsistently
    highost
    at
    the
    north
    end of
    the
    lake.above the
    railroad
    causeway and lowest in the
    dischargc
    drm. The
    conclusion
    that the
    north
    encl of
    the
    lake supportecl
    greater
    standing
    'crops
    of aigae
    was
    consistent
    with
    observations of higher
    pH
    value
    ancl
    greater
    'sat,uration
    of dissolverl
    oxygen
    there.
    jlf'ecf--:Ipggi
    glgaqer--A.Iaof-eff.Lreqt5-qr
    l_
    t.
    Lowconcentrationsofdissolvedoxygen
    were,observecl for
    extendert
    perjods
    in
    deeper
    areas of
    the
    lake
    during sumnter
    rnonths.
    0xygen
    was depleted for
    most
    of
    the sunmer throughout
    extensive areas.
    -of:the
    lake
    indicating eutrophic conclitioni.
    In
    wirrter,
    cornplete
    rnixing of
    .rrrost
    of
    the.lake beyond the
    discharge arm
    prevented
    oxygen
    depletion frorn
    occurrting.
    3.r

    I
    I
    I
    I
    I
    I
    I
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    I
    t
    T
    I
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    :-:
    ra:-::::'
    't:::.
    j.li'.:::
    'i,:::=::
    :-:t::l
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    i'::.
    =:
    :.;:
    :
    :-
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    !::
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    -:
    -- ra:
    .:-,:
    :
    :.:::
    ,ri:
    .
    :.
    I r{tR00ucT
    t0N
    The
    water
    qual
    ity
    invest
    igation 'rras
    undertaken
    with
    the
    purpose
    of
    evaitrat
    in,.;
    brater quality
    in
    Coffeen
    Lake after
    the installation
    of
    net,r
    HdsLervater
    treatrnenL
    -'iacil,itjes'at
    the
    po'ler
    pldnt
    dnd
    with
    more norndl
    precipitation
    patLerns.
    , Tlr€:
    investigation
    included
    (l)
    monitoring
    wdter
    qudlity
    param€ters
    irr
    th€
    lake',anrl
    :
    determilring
    the
    cause
    of changes,
    and
    (z)
    determining
    hovl
    temperature
    ,,
    distribution,resulting
    from
    the
    discharge
    of
    a thermal
    effluent
    affecterl
    waler"
    qual
    ity.
    The
    investiqation
    includerl
    studies
    of circulation
    patterns
    in
    the
    lake,
    cl
    irnatological
    events,
    and
    chemical
    inpur-s
    to
    ilre
    I
    ake. These
    claLa
    were
    used
    to
    assess
    the
    relative
    impacts
    of climatological
    events and
    plant
    operation
    on therlake,
    and to
    determine
    hovJ
    the
    temperature
    distribution
    affected
    mineral
    cyclingandeutrophication.t.Jaterqualityparametersthataffectedthebiota
    are.discussed
    with
    particular
    reference
    to affect.s
    on
    a)gal populations.'
    ",'
    'l
    .T
    T
    .
    .'r.
    I
    -
    :.:::
    ::.
    :
    .:
    3,2

    :::
    l{A'i[,i
    I
    ;115
    Af{0
    l.lf
    Til0l,S
    SAI4PL
    IN6
    SCIIEOIJLE
    l'later
    samplcs
    were
    coi
    locted nronthly
    at Staticns
    l,
    z, 3, anc 4
    ar.
    the top,
    nidrJ
    le,
    antl b,ottom
    of
    'Lne
    wdtu.
    colri,nrl anrj
    at StoLion 5,
    Lhe
    slag
    ponrt
    outf
    low,
    the
    coal
    pile
    runoff,
    the
    c.ral
    pile
    runoff
    seLtlinq
    pond
    ortfl6r1, tile
    easL.lrin
    inf
    lowing
    stream,
    ancl the
    west
    arrn
    inf
    lo*ing
    stream
    (see
    Fiq.
    l,?).
    Sampl
    ing
    .rL
    the51agpondwas'discotltinuer|afteritwasa|ronr|onediliAugust1979.Ine
    station
    at
    the coal
    pile
    runoff
    was
    changed
    Lo the
    settling
    ltond
    o,.rtf
    low in
    the
    'ni'lrl
    le
    of
    tha f irst
    year
    when
    settl
    rng
    porrd
    operation
    begarr. Af
    L,jr opr.:r.ttion
    began,
    direct runoff from
    t.he
    coal
    pile
    no
    lonSer
    ran into
    Lhr.: lake.
    SLrearns
    f
    lowing
    into
    the
    east and
    west
    arns
    of the
    lake
    were both
    irrLerrnrltent.,
    arril
    ilrey
    could
    only
    be
    sampled
    in
    the
    sprinq.
    The following
    pararneters
    were
    Ineflsured
    d[
    'nonLhly
    irrtervals
    f
    rorn
    AugusL lgZB
    through
    Decernber
    1979:
    turbirJity,
    total
    alkalinity, f
    r-ee
    carbon rlioxirle,
    t0IA
    hardrtess,
    total
    phosphorus,
    soluble
    orthophosphate!
    arilnoni.l
    ,
    nitrate,
    niLrite,
    total
    iron,:soluble iron,
    ferrous'jron,
    sulfate,
    sulf
    itr?,
    161sl
    sulf irle,
    dissolved
    hydrogen sulfide, un-ionized
    hydrogen
    strlfirtc, clrlr)rirle,,tnrl
    f
    lrrorirje.
    At
    quarterly
    intervals
    water
    samples
    ,,{ere
    dlso analyzed
    for
    or
    q.lnic
    rriLrogen.
    total
    organic
    carbon,
    particulate
    organic
    carborr,
    rJissolved
    organic
    cartron, and
    clternical
    oxygen
    demand.
    After
    0ecemtrer
    1979, fluoride,
    sulfite, irqn forrns,
    chernical oxygert demartd,
    anrl
    particulate
    anrt
    soluble
    organic
    carbo,r.leru,
    elilninated
    from
    the
    pararneter
    I
    ist.
    Sulf ide forrns
    were measured
    only when
    oxygen was depleted
    in
    the
    hypolinnion.
    Chlorophyll
    g,
    pheophytirr
    g, and t,;tal
    and
    particulate
    organic:carbon t{ere
    measured
    nronthly f rom
    rlupl
    icaLe
    intr:oraLed
    sar.nples
    of
    the eufiirot
    ic
    zonc at the f
    our
    iriaj0r
    lake sLat
    ions .rntJ
    at the
    i
    ntake
    of
    tlre
    power plant.
    ::..5
    i.Il:
    :'.'I,:
    ,.-
    ,.I.a
    .
    .,a
    ,l
    Pr,of
    i les of,,temperature,
    dissolved
    oxygen,
    ald toLal rlissolvetl
    solids
    r+ere
    rneasured
    twice
    monthly at
    I<n
    depth intervals
    dL
    Llte
    four,najor
    sLations
    lnd
    at
    Stations
    1.5
    .:'
    'and
    2.5
    (Fiq.
    1.2). At the
    s,rme tir€,
    prt
    wils
    Inr-,(.tsi,red
    at
    Lhe
    surf
    ace,
    rniddle,
    and bottom
    of
    the
    water
    col
    rlnn
    at
    those
    st.aL ions.
    .
    1,'.:.
    :.-::a:
    . ,.,':.:,.,
    a,
    ,.;.
    .
    .:.:--:.;.:.
    3.3

    ::'
    ,
    ti'
    I
    "jl":
    "
    '
    .:.:
    I
    I
    I
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    I
    I-
    I
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    I
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    ,t,
    .j.
    I
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    :,
    ,.',,,'
    I
    ,
    'a.
    I
    T
    .'a-='t;'a
    3.4

    :
    Iahle
    .l.l
    I'l*thods
    us{:d
    to
    trlnlyze
    r:he;nical
    par,l:r,eLers.
    Parannter
    l'le
    thod
    Turbldity
    total
    alkal inity
    Free
    carbon dioxide
    lotal
    phosphorus
    So
    I
    uirl e orthoplrosphate
    EDTA hardness
    Anrnonia
    nitrogen
    I{rtrate
    nrtrogen
    Nitrite nitroqerr
    Sul
    f
    ate
    Chloride
    Fl uor i de
    Ir.on
    (total
    ,
    sol
    ubl
    e,
    and
    ferrous
    )
    Sulfide
    '
    ..
    (totat
    and un-ionized
    and dissolved
    hydroqen
    sul
    f
    ide)
    urqanlc nrE,roqen
    0r:ganic
    carbon
    (total,
    r.
    '
    particulate,
    and
    <lissolved)
    Chemical
    oxyqen dernand
    Chlorophyl
    I
    a,
    pheophytin
    a
    i'aiiitek
    i4odr:l
    2l
    nephelom,:ter
    'l'
    Stondard
    l4etlrorJs
    l4th
    ed,, Lilrdtecl
    to
    plt
    4.60
    Ca
    lcul ated by
    method of
    l'larvey
    {
    I960) and Park
    i
    1969)
    Stannous
    chloride
    method
    ,
    '
    '
    :.
    SLahnouschloriderne[hod(Autoanaly.zer)
    E0TA colorirnetric rnethod
    ,
    "
    l.lodj
    f
    ierl
    phenate
    nethorl
    (Autoanaiyzer)
    .'
    Cadmirrrn rerluction
    method
    (AuLoanalyzer,)
    0l
    azoti zat ion nethod
    (Autoana
    lyaer)
    Turbidimetric rnethod
    :
    Argentometric
    method
    ,Electrode
    method
    on 0riorr fudel
    601'nretcr
    ,
    ,
    .,1
    Pherranthrolinenrethocl
    r
    ,,
    Methylene
    blue visual
    color
    matching
    rnethod
    Total
    Kjeldahl rnetnod
    (Autoanalyzer)
    '
    r..:.i'
    .
    :
    '...1'
    Direqt
    .injection
    metho<J
    on 0ceanography
    International
    Carbon
    Systern
    llach
    Reactor 0i
    gestion
    COD method
    (J
    j
    rka
    and Carter.',,1975)
    St
    andarcl
    irlethods

    'l
    -:'
    :: i
    t
    I
    T
    I
    I
    I
    I
    I
    t
    I
    I
    I
    t
    I
    T
    I
    I
    RI
    SI,lL iS AI{O
    I)
    ISC{JSS
    I
    Of{
    Data
    f
    rom
    the
    f inal
    col
    lection
    period
    of
    July
    l9B0 through
    fucernher
    l9B0
    are
    cotttairtcd
    in
    Appcndices
    3.l -3.ii.
    Previously
    col
    lecLatJ tJata
    are I
    isLe<l in
    1979) antl
    Appendices
    3.1-3.'3
    of
    the second
    annual
    repori|-
    (Liehr-Storck
    l9B0).
    .
    ,
    :,
    :
    DISSOLVED
    SOLIUS
    Coffeen
    Lake had .1
    much
    greatcr
    concentration
    of
    Lotal
    rJissolved
    rol
    itls
    (TDS)
    than
    rJid
    five
    other lakes
    in
    this
    geoqraphical
    area.
    the
    rilcdn
    concentraLiorr of
    TDS in
    Coffeen
    Lake on l7
    June
    l9B0
    was
    853
    nrgi'1
    as
    NaCl,
    'rvhile
    fivc
    other^
    lakes
    in
    the
    area sampled
    on
    lB
    June
    l9B0
    (Liehr-Storck
    l980)
    hatl
    c0nce'tlrati0ns'?n
    the
    range
    frorn
    l33
    to
    321
    mg/l as ltaCl
    (table
    3.2). Lake Sangclrr'is,
    anoLher'
    cooling lake in
    central
    Illinois,
    ltad
    a mean
    TDS
    concerrtration of
    319
    nrg/l
    as
    NaCl
    (Iable
    3.2)
    (Brigharn
    lg8l
    ).
    ,:
    Little
    variaLiort
    j
    in
    TDS
    occurrerl
    arnong
    stations at
    rrrosL
    tirnes
    of
    thc
    ycrr
    during
    this study.
    ln
    the
    spring, however,
    concentrations
    at Station
    4, in
    the upper'
    enrl of
    the
    lake,
    clropper.l consirJerab)y
    relative to Lhc
    other
    sLaLions,
    corresponding to
    increased
    rainfall and runoff
    creating
    higher
    lakc
    elevation
    (Fig.'3,'l).
    The largest
    tlrop
    in iOS at Station
    4 occurred'il
    the
    spring
    of 1979
    when
    t.he
    rnost
    dramatic
    increas€
    in
    lake
    elevation
    occurred.
    The
    concentr'ation
    at
    Station
    4 also decreased
    relative to the
    other stations'in:Augrst
    l9:zg rturing
    a
    lrerioci
    of
    heavy rains.
    Tlte overal
    ,'::.
    I concentration
    of
    Tl)S
    varieit considerably during Lhis
    sludy, with
    a
    l..g--qg.j9gg1.9-e
    .q.cjurring,
    in.the spring
    of
    1979
    followed by
    a
    progressive'
    ii-i-,t:Sgr-q,'
    Since the'volume of the'.lake
    also varied,
    however, the
    toLal
    imounb
    of
    dissolved solids,in the lake may be
    a
    more
    rneaningful
    parameter
    for
    cteter:;rrining
    whether dissolved sol.ids actr.ral ly
    increased
    or decreasr:<.|.
    Us''ing .r
    lakc
    :
    '.
    elevation-volurne
    '.:a,,:
    :
    ,'
    relationship
    ,
    .:.
    (Fig.
    3.2;
    Sargent
    onrl
    Lundy)
    the
    arnourrt
    :
    ,
    '
    of
    dissolVecl solids wa5-calculated
    rdrrd
    plotted
    against tirne
    (Fig.
    3.3). A large
    decrease was observeJ in
    the
    spring of 1979 when water
    stored in Lhe reservoir
    was
    ,f.l
    uil
    uslled
    over
    the
    spi'llway asr,-lar.ge
    amounts'of rain
    and:runoff
    waler,entered
    .
    ""tl
    ,:'i:t:i-.1.
    ::
    1
    :.
    .:-,a.
    I
    3.5

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    . a--
    Figure 3.2.
    Relatlonship
    of
    ,
    '.t
    ,
    surface area
    1n
    Report SL
    1990)
    lake
    elevatlon
    Cof
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    3.
    10

    the.lake.Frornlatesunrnet.of'l979r:nt,|ltheenr|oft|it,::,|'i,rt|y,liL||e
    orklitional
    water was
    f lushed
    f rom
    the l,rke,
    trntl
    a
    f
    airly c0flstdnt
    increase
    in
    total
    dissolvecl
    solids
    was
    otrservecl. This
    iilr.rease
    can
    l)c:al.i.riblterJ
    Lo
    :i;rplLs
    frorn
    precipitabiort
    anrl
    runof
    f as
    well
    as
    f
    rom
    deminr:ralieer
    ivastes enrl
    c0al
    pi
    le
    runof
    f
    porrd
    ef
    f
    luerrts.
    '
    Even thouqh
    t.otal
    dissolverJ
    solirls
    concentr-ations chanqed
    during
    lhe sturiy,
    per:iod,
    the
    relative
    composition
    of lhe
    anion
    components changed
    on'ly
    slightly
    during
    that
    time
    (Fig,
    3.4), excepl
    at stati0n 4
    rluring
    the
    spring
    flood
    of
    l?79, an.!, to
    o lesser
    extent,
    during
    the spring flood of 1980. Instead of the
    carlionate-bicarbonite
    anions
    expected to
    tre'dominant
    in
    trodies
    r,,f
    water
    irr
    ternperate
    rregions'lHutchinson
    1957)', sulf'ate was ttre rjorninant
    anion.
    Sulfate
    concentrations
    were much h:igher
    in Coffeen
    Lake
    than in
    five lakes
    cf
    the
    suriounding area
    oi
    in
    Lake
    Sangchris
    (Table
    3.2).
    Both the
    high
    conceritration
    of sulfate'and
    the
    extreme domindnce
    of
    the
    sulfate
    anion sugcest Lhat
    Coffeen
    Lake contained
    sulfate
    concentrations that
    are corisiderably
    great,er
    than normal.
    The
    increase in
    sulfate
    concentration
    over,firne
    is,illustrated
    by data
    collectecl
    and
    provided
    by
    the
    power
    plant
    sjnce
    .|966
    (fig.
    3.5).
    ihe rnost
    rapid
    increase
    occurred
    cluring the
    period
    f
    rom
    .|975-1976,
    wiith
    a
    decrease f
    ollovrirrg
    in
    1977.
    Sulfate
    levels
    in the
    lake
    generally
    corresponcletl to
    sulfate
    levels in
    the
    asn
    ponds
    (Fig.
    3.5).
    These
    ponds
    were
    taken
    out of use in 1978,
    ,rnd apparently
    sulfate levels
    in the
    lake
    have
    dropped
    substantially as a result.
    Sulfate
    concentrations were
    found to
    be significantly
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    Stations I
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    2 vs.
    3
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    4),
    rnonths,
    and
    sLations by
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    and
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    in l-q8f)
    (Table
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    of frorn
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    May i979.
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    l.
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    -:':
    t:..
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    ::;:.:',:.
    ,
    r:.,=:
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    l'
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    l.
    I.
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    ,
    I,
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    -
    I
    -
    quantity
    of
    Sulfate'in the
    lake
    had increagcrj
    0r
    decreasrr,, Lhe'clevation-volume
    relationshlp (Fig.
    3.2)
    ,ias
    .igain
    used. Ihere
    was
    .l
    subsfnntial' ctecline
    in
    the
    sulfate
    content of the
    lake
    in the
    spring
    of
    l9l9
    *hon a
    consirlerallle
    rlrnrrirnL of
    ilater
    store{, in
    the reservoir
    vJas
    f
    lushed
    over the spi
    ll,*ay.
    l'rorn rhat
    Lirne
    until
    the
    end
    of the
    stutly, the amount
    of sulfate iri
    Coffeen Lake
    incredsed
    fairly
    steadily. tlhen the
    study
    enrJed
    in December
    I980,
    the
    sulfate content of
    the'lake
    hatJ
    not
    increased to
    the
    amount
    present
    at the
    beginning
    of
    the
    study,
    so the
    amount
    lost by
    flushing
    in
    the
    spring of 1979
    hacl not
    yet
    been replaced
    (Fig.
    3,7),
    [his
    pattern
    of decreasing
    sulfate
    with a subsequent increose
    was
    very
    sinrilar
    to
    the
    pattern
    observed
    for
    total
    dissolved
    solids.
    Tlre
    percent
    of
    sulf
    at.e in
    the
    composition 0f anions
    did not
    change drarnal'ical'ly
    throughout the
    study,
    except
    at'station 4 in
    the
    spring as
    alreddy
    discussed.
    Prior
    to
    the
    spring
    of
    1979,
    sulfate comprised
    about
    84% of
    Lhe
    ani0n
    content
    by weight.
    Fron
    June
    .|979
    through
    the
    remainder
    of
    the
    study,
    sulfate',*as
    about
    BOX by
    we'ight,
    with little variation.,
    '
    :
    Sulfate
    concentrations
    were
    significantly
    lower
    (p
    <0.02)
    :'in
    the
    hypol irnnion
    when
    rlissolverl
    oxygen:concentrations
    were low.
    Sulfate
    is
    reduced
    to
    sulfide
    untler
    low
    oxygen
    cortditioris, but
    hydrogen
    sulf
    ide was
    not
    rtetectetj.
    Al
    I
    sulf
    ide
    produced
    was apparent'ly
    precipitated
    as iron
    suifide.
    Lack of
    stratification
    irr
    winter
    protrahly prevented
    sul f irJe f
    rom bei
    ng f
    ormetl at that
    t
    ime.
    Alkaljn.ity levels
    were
    lower
    in
    Coffeen
    Lake
    than in
    most
    of the
    five
    lakes
    in
    the
    sarne
    geo<;raphical
    area
    and lower
    than in
    Lake Sarrgchris
    (Iable
    3.2).
    Statistical
    differences were
    similar
    to differences
    for
    sulfaLe
    concerrtrations
    (Table
    3,3). AlI statiorrs had about
    the
    same alkatinity
    tevels,
    with the
    exception of Station
    4
    rlurinE
    the
    spring
    of 1979 and
    .l980.
    Alkalinity
    was
    probably
    more djluted
    at Station 4 than the
    other stabions
    as
    a result
    of sprirrg
    rains
    and
    runoff,
    although alkalinity
    levels decreased
    at all
    stations
    aL Llrat
    tirne.
    0vcrall,.hovlever,
    alkalinity
    increased
    in
    Coffeen
    Lake
    during
    this
    sturly.
    The
    mean
    alkalinity
    in
    1979
    was 65.5
    mg/l
    as CaC03,:arrcl
    the
    mean
    in
    l9B0 was
    82,6
    ngt/1
    as CaC03;(Table 3.6).
    These
    levels
    were
    arr
    improvement
    since
    1g75-76 when
    data
    collectecl
    at
    the
    power planb
    indicated
    that
    alkalinity
    levels
    plunged
    dramat.ical
    ly
    to abnormal
    ly
    low
    levels
    (f
    ig.
    3.S)., The,lrigher
    alkal
    inily
    is
    a desirable characteristic because
    it
    provides
    greater
    buffering
    capacity
    . ..,
    ,,_r,
    .
    :
    3.Zl
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    3. 23

    i;:':.
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    dnd
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    dssirablr,'
    spec.ies
    .t
    lgarl
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    against ptl
    chances
    l
    (K
    i ng
    I
    97ri) .
    0f
    The
    .iwo
    other
    rnaJor
    components
    of totdl
    disso'lverj
    sol
    iris
    in
    Cof
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    een [-ai:e wer'r-'
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    anrl
    chlorirje. llarrjness
    levels were
    lower
    Lh0n
    inlthe
    f
    i've lakgs in
    the
    same ,tred,'uut
    higher than
    levels
    ir;
    Lake Sarrgchris,
    whil,e
    chloride levels
    were lower
    than
    levels at
    Lake
    Sangchris but higher
    than
    in
    the
    other
    five lakes
    (l'able
    3.2).
    Ihe
    ctata for
    these
    paraneLers
    were
    observed
    in
    pattcrns
    sirnilar to the
    patterns
    of
    sulfate and alkaliniLy
    (Tablc
    3.3I.
    llardness
    was not
    signlficantly
    different
    betwoen
    yedrs,
    but
    chlor'ide was
    significantly
    higher
    in i9B0
    than
    in
    1979
    (Table
    3.6), although
    chloride
    did noL
    reach
    levels
    as hiqh
    as
    those
    observed at the
    beginning
    of this
    study.,
    Decreased
    concentrations
    of
    botn
    parameters
    tvere
    observed
    at Station
    4'during
    the
    springs
    with the
    biggest
    decline occurring
    in the
    spring
    of l9/9.
    ,As
    pith
    the
    other two
    TDS
    parameters,
    there
    was little
    variatiorr
    among
    stations at
    other
    timesoftheyear.'
    '
    :
    i
    ,
    .
    :j
    TURBIDITY
    Statistical
    differences in
    tur.bidity
    (Table
    3.3) were
    causerl to
    a large
    extent
    by
    extremely
    high levels
    (rnean
    143.6
    NTU)
    at Station
    4
    in
    the
    spring
    of t9/9.
    Tltjs
    occurrence
    resulted
    in
    h,igher'levels
    at Station
    4
    (Table
    3.4) in
    the
    spring
    rnonths
    (Table
    3.5), and also resu'lted
    in significintly
    higher
    turbirtity
    levels
    -
    in
    1979 than in
    1980
    (Table
    3.6). The high turbidity
    corresponded
    to
    heavy
    precipitation
    and high
    lake
    levels at
    that time.':lncreaseci
    turbidity
    levels
    wet'e also-observed at
    Station
    4
    in
    Auguit 1929
    (mean
    .|4.0
    NTU) and
    during
    the
    spring
    of
    l9B0
    (mean
    20.0 NTU), which
    were
    also associated
    wiilr heavy
    precipitation
    and rapid increases
    in lake
    elevation
    (Fig.
    3.1
    ).
    Turbidity
    at
    the'::other, down'-'lake
    stations
    did
    not increase
    to the
    sarne extent
    as at SLaiion
    4
    located at
    the
    upper
    end
    of the
    reservoir.
    'Durlng
    the
    spring
    of'1979
    the
    nrean
    turbjtJiti
    at
    the thr
    ee down-lake
    s.tations was
    only 1
    5.6 NTtl. Apparently
    tnovement of water through
    the railroad
    causeway that
    separates
    Station
    4
    from
    the'othei'staiions.'was
    slowed
    enough to
    allow
    much
    of the
    particu:late"matter
    to
    settle before the
    water
    mixed
    with other
    parts
    of
    the
    lake.
    l{igh
    turbidity
    levels
    were
    generally
    associated
    with
    high
    l.eve'ls'of to'tal
    phosphorus'arrd
    total
    T
    I
    I
    I
    t
    I
    T
    '
    .1
    ,i:
    i
    --.:',,,i,,.,;:-
    I
    l
    I'
    I
    l'
    I

    il'
    il
    ill
    il'
    a';,..',
    tl-
    t,?
    Plt0spt{0Rus
    ..
    ,
    :
    The
    form
    of
    phosphorus
    useri
    by
    ptants
    as
    i
    nutricn!-
    is
    s0lut)le 0rlhDphosDhJr.,J.
    lJocausc
    this
    form
    is
    rapidly
    cyclerJ
    and
    convl)rted L0
    olher
    forms,
    it
    is
    rrot a
    g00d
    lndlcator
    of avai
    lablc phosphorus
    in
    tho
    sysLern.
    IoLal
    phosphorus
    is
    considered
    t0
    be a
    more r[liabld
    osti'r6td
    df availabl6
    phosph6r.us
    {Foai6/oy
    i
    e6o)
    .
    :
    :::
    i\
    A large
    insrease
    in
    toia'l
    phosphorus
    at all
    s[aIrons in
    August
    )g79 eould not
    ba
    exlilained.
    Therefore,
    t0
    exclude
    possibly
    errone0us c,ata,
    thc
    data from
    that
    mortth
    were
    not
    used
    in the
    statistical
    analysis
    (Tabie
    3.3).
    Phosphorus
    was
    not
    significantly
    different
    in
    197,9 and
    1980,
    with
    annual
    means
    of
    0.051 ng
    p/l
    ancj
    0.054
    ng P/1,
    respectively
    (Table
    3.6). Station
    differences (Sration
    3
    vs.
    4
    and
    Stations
    I
    +
    2 vs.
    :
    +
    4) were
    mostly
    accounted
    for
    by
    higher
    levels
    at
    Station
    4
    (Table
    3.4).
    Increase
    in
    ptrosphorus
    at Station
    4
    qeneral
    Iy
    d the
    highest levels
    were founrl in
    the
    spring
    (Table
    3.5),
    with maximum
    concentrations
    of .277
    ng
    P/l' in
    Ap:r"i I
    lg79 anrt 0..|73
    rng
    Pll
    in
    April
    1980.
    Frorn
    the
    spring
    of 1979
    untit
    tt. rottowing
    spring,"
    phosphorus
    levels at
    all
    stations
    were
    simjlar,
    witir stations
    3 ancl
    4
    cenerally
    having
    slightly
    h'igher
    levels
    than
    Stations
    r
    and
    2.
    In 1980,
    however,
    phosphorus
    level s'
    rentained
    higher
    at Station
    4 throughout
    the'suslmer..
    '
    Phosphorus
    levels
    were
    sintilar
    at the three
    stations in
    Lhe
    lower
    end
    of tlre
    lake,
    and
    gradually
    rose
    throughout
    the
    sumrner.
    phosphorus
    levels
    then
    decreased
    at all
    four
    st,atjons
    in the
    fal l.
    N
    I
    TROGEN
    The
    nitrogen
    content
    of water
    is
    cornposed
    of
    organic
    ancl inorganic
    forrrrs.
    The
    inorganic
    forms found in
    natural
    water
    are
    ammonia,
    nitrate,
    and
    nitrite,
    although
    nitrite is
    usual ly found
    in only
    small
    amorrnts.
    The
    typica-|,.
    seasona'l
    pattern
    for
    unstratif ied
    I akes i
    s
    a sumnler
    rnaximurn
    of
    anrynonia
    (Hutchinson
    1957). Stations
    l,
    3,
    ancl
    4
    were
    not
    typically
    stratifiecl,
    and.,Stat ion, 2, althoug!r.,it
    was
    t.herrnally
    stratif ied in
    the
    sutnmer,
    diC
    not
    nave
    significantly
    different
    arrmonia
    concentrations
    at the
    srrrface
    ancl
    botLorn
    during
    3.25

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    f..:':a::.:
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    ii.:5.:.:
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    4i.-l
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    ::.-ta:..!
    :r-:;
    ,
    -
    Fli;i=:::,
    Ithe'months
    thdt
    stratification
    occurrecl.
    The annoni,l
    cycic
    olrserved r.luririg
    lg/9
    l{as basically
    the
    typical
    pattern
    FriLh
    drrmonia
    concentrdti0n.,
    irrcrcasing
    ilrrr:Lrqh
    .the'.5unfiEr
    and the
    maximum
    occrrrring
    at
    al I
    staLions in
    Auqur'".
    Tlrc
    onl.y
    apparent
    deviation
    from
    this
    pattern
    was
    the
    incrc,rsc
    dt
    5tdLlor,4
    in
    lhc
    sprinq'
    which
    can
    prol)ably
    be
    expl,rin0d by
    the r'api{'l
    irrflow
    of runoff
    w,tLer
    at
    that
    time.
    During
    1980,
    however,
    the
    typical
    arrurrorria
    pattern
    was not
    0bserveil.
    Anrnonia
    levels
    began
    to
    rise
    at
    all
    statlons
    in
    late 1979
    with the
    s,naiiesL
    .
    increase
    occurring
    at
    Station
    4.
    Levels
    continued
    to rise
    until Harch,
    with
    Stations
    I and
    2 having
    the
    highest
    concentrations
    (l.0li
    and 1.107
    mg N/1,
    respcctively),
    and
    Station
    4 the
    lowest
    (0.41i
    mg
    N/1). The
    may.irnum
    amrncnia
    conccntration
    of
    1.150
    mg
    tlll
    was observed
    in May l9B0
    at
    Station
    l,
    located
    in
    the discharge
    arm.
    In
    June,
    anmoni
    a
    level
    s droppe<l
    at
    al
    I
    stat,i6ns, 91ith
    concentrations
    subsequently
    increasing
    at
    Station
    I but
    continuing
    to
    decrease
    at
    the
    other
    stations
    (Fig.
    3.9).
    The
    extrernely
    high concentrations
    (
    Z.lB0
    ng
    N/l) observed
    at
    Station
    I
    in
    December
    l9B0
    were
    apparently
    affecLerl
    by
    operations
    al the
    power
    plant.
    Significant
    differences
    of
    anrnonia
    concentration
    among
    stations
    for
    all
    station
    contrasts
    (Table
    3.3)
    dre
    explained
    by
    Llre
    gradient
    around the
    lake,
    with
    highest
    levels
    founri
    at Station
    I ancl
    lowcst
    levels
    at
    Station
    4
    (Table
    3.4). l4onthly
    nleans
    were
    hiqhest
    in the
    spri6U
    Inonths
    and in
    December
    (Table
    3.5),
    contrary
    to the
    rrormal
    cycle in
    which
    '
    maxitnum
    levels
    occur
    in late
    summer.
    Arnmonia
    concentrations
    were
    signif
    icanily
    'lower
    at all stations
    during
    .l979
    than
    during
    1980
    (Tab)e
    3.6). Devjation
    frgnr
    the
    typical
    atlnual
    pattern
    of
    armonia
    cycl ing
    plus
    the
    rapid
    increase
    in
    arnnronia
    concentrations
    in
    1980,
    which
    were
    significantly
    higher
    at the
    sampling
    statiorrs
    nearest
    the
    power
    plant'discharge'indicated
    that
    amtorria
    levols
    were-affected
    by
    the
    power p)ant.
    The typical
    seasonal
    pattern
    for nitrate
    is
    a maximunr
    in
    r,vinter
    dnd
    spring
    wherr
    the.rate
    of nitrification,
    i.e.,
    the
    oxidation
    of
    reduced
    njtrogen
    compounds,
    is
    most:rapidr and
    min'imum
    in
    July and
    August
    when tlre rabe
    of nitrate
    reduction
    is
    the
    greatest
    (Hutchinson
    1957). Again, the
    pattern
    observecl in
    Coffeen
    Lake in
    1979
    appro*]r.::o
    :n:."*ou:,ed
    pattern
    (F'is.
    3.10).
    Nirrate
    concenrrari0ns
    increased
    at all stations
    beginning
    jn
    the
    fall
    of
    1978,
    and reached
    a Inaxirnurn
    'in
    itlarch:of
    0.B08 rng
    i'lll. Concentrations
    starte'd
    to
    decrease
    in
    Apri'l,
    ancl
    the
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    fuetrt
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    p1t.+irr,,i,,
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    COnCenLrntionS
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    il-t-rtr.
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    rilir._!.ir.i,1
    .1
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    djf fercnl:es
    in
    nitr,n,:
    ii,,l1qtl,it-!-4',
    rr.!,!,r
    .ii;.a!.rii
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    ;
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    ln0SIly te
    exp.!:ai n(:d
    \]I'ConSi5irl..'ltlV
    l,;rrr'r
    if,,.+1
    1,,
    it
    i:!,::.i:,,:;:
    ,i
    :t
    -.t.
    .i.-iijl
    .
    Thr,=
    oLlt'ri'thr'eg
    sla|.iotlE,
    which
    arre
    l,-rtiLeri
    ri+r*,''..ii.ri;,r,,;11;*Lrr.;,iii::!,,
    ili.!,r.:.!
    rr,r;r:
    nitrdte
    levclr
    SiJbstnntiall;l
    <Iif
    frrrtir"rl
    f
    r$:*
    r:Jrir
    ;ii.;:r,r
    iiaiil,:
    j.,tr.
    i.
    :
    ',
    Signif
    iCant
    dif
    fgreflCe
    belween ye,lrt
    .r,ri ,J4iic
    {.,,!,'l.iirrr;ii
    t;-t
    .,,ti:,,iuri...}ii;.
    r;r.]fri..r.
    ConcLlrltraticr:, rlurinq
    ljilC
    tnan
    rlilrii.,l
    \.).t,.1
    :.iair
    jr
    .:.tr,.
    Nitrite
    levr:l;
    /rerr..
    ,llS0
    hitner
    lrl
    ':
    {tlrj
    r-lr,tr,
    in
    i{.ii,i,
    arl
    it
    ::it.
    incrLrdsinq
    f rorn
    ,04j
    n1
    :l/1
    rrr l<J/,1
    .,r
    .lr"'rj
    ri,;
    li,,
    I
    rn
    lrf
    :;r1
    j:
    hiqhest
    fictlft
    o itr i
    te
    cr)lctlrtrat
    liJn
    *t",
    r:it,,t1r,,rl
    it
    ,rt,il
    r..irr
    l
    StaLirln
    /t
    dur
    inq
    bOth
    yC,lr,,.
    iht::
    rJrir-l+.:r.
    ,nr:rit.i,r,!,
    .i1;ri;.
    'strr
    irii;!.r
    lmonLhS
    wittr
    lhe higheSL
    nitrr!-g
    (;r,rr{:rtnlr,l!-rr:r:,
    {1.::tirr
    }.,:i.
    j
    .:!i
    il--,jrlt-( rr?
    f
    =li
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    i}4.,.'
    ,Ji:r.r
    ,,,b
    j.
    ii)l'
    tr;.j
    !.hrt
    It**::
    t
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    /.!i
    !.:."iit.'r'
    I
    'e{.rq-r1
    Ihe
    total
    inorqartic
    nitroqr:rl
    ci)ncqrtlrat irrn
    rr4.,
    ,,
    irlrr!r lf,
    lrlr.
    l./
    ii
    r
    ,'ipr'
    rrr
    i r",.
    (Iallle
    .3.3),
    ritlr a rre,rn
    of
    i.60B
    rqq
    ltl1.
    tt,rrt
    rrr
    1,r/(j,
    ,r?1
    ,r
    :ri.,irr
    rif
    .ii
    1,
    ::,;
    N/l
    (Iablc'
    J.6).
    The rJre,ltelL
    incrr,rt.t?
    tco'.,
    irl.lrr:
    ijrrrir',1
    thr.
    !t,]r
    i,j,l
    f
    r-..,:1
    SepLenrber
    l9/? Lo l4arcrt
    l9t-10,
    wiLh
    the rndvi,,rurrr,)LCur:'irr4
    tn
    l,larr:rr
    lgBrl.
    i)rlr.irrg
    t:ttat
    period'
    ihe
    tneitn
    concenIrat.
    ion'*f
    lnar.ltalrlc
    !iiLrr;,lt:n
    inr;rrj,t!i](i
    f'r,:i:ri'.:O.l o;n
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    ,'rf
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    levels
    of inor'9anic rritroqen
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    (,t,tr-
    i0r;
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    r.ntil
    :i.
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    otlter staLions
    (Fi
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    I
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    rlis,.ir,irrJij
    ,)r:ii,
    lr.:
    J ilre
    vittt
    signif
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    irirlirrir
    lrvr:1,,
    itr,ln
    Sldti0n
    ?
    (Table
    3.3).
    ThL: rnean
    inorganic
    nitroqen
    ccncenlrlLion
    irr
    l9B0,il
    StcLiun
    4
    wac
    1,126
    mg
    il/l dnd at Station l:was
    2,046
    rn,1'il./1,
    i.c,
    tlrt:r't
    ,rr/u,.r
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    jnrosL
    twi4i:
    i-he
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    I
    ,.r',.rt
    i>Lrrlron
    ri
    dur-in,y
    lgBi).
    ,'Both
    the
    increased
    levels
    in'1980
    drtd
    the
    rligLurtrer!
    sGdsorlil
    cyr:l'-1
    0f ni'ir.ogc:rr:
    .
    in the
    lake indicaLe
    that
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    loarJirrg
    of
    niLroq,.,o
    occdrrc(1,
    ;rr.rlbably
    :::::'
    starting
    :
    :
    -
    in
    late
    1979, tlhi
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    year
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    only dur
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    thr,
    rrri;rrins
    fif
    ,rlir
    i I
    ,
    f1xg11,1r,,
    61rt
    5ePtemb€r,
    ivhieh
    were'the
    months whcn maxirlttrfr
    pht;;plloru:':]4v,Ji
    i
    ,t{curr{ii
    dt
    Station
    4. Ratios
    of
    lass
    Ihan
    l2
    wtltr] nevrr
    ob:r;r-vert
    ,ir,
    thrr
    ot.irr;r
    tirr.r:i-.
    stations
    rturinl
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    but
    occL'rred 0ccnsinnrlly
    {t4a-v,
    leptr-r:nl)(.,!',
    ,trrrl
    llovernher
    i
    al. t,hese
    stationg in'i979. the
    increaserl
    nitr,;gp11
    '!r:vcl,,
    in
    Ct:!'f*r:n
    Lak4
    app,:,rr.
    t'o have'caused
    tltc north
    en{, of the lake
    to
    change from beinq
    nii-rlqerr lirnited'
    [o tieirrg
    pnospholus-.lirnited.
    ilowever,
    the, loxer
    'p*rL
    of
    tlre
    laie
    lppr,are(l
    to
    Itave
    been
    phosphorus-lirniled,inost
    of.,
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    t.irue
    even
    br:for-e
    rritrorren
    lev,:!9
    :.
    ihCreose{,
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    nL th€
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    the
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    r-r{ !9ltl
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    -
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    in
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    ef
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    ,'
    0issolved
    oxygen
    (0.0.)
    ./as
    depleted
    in tht hypol i*nlrlrr
    of
    llu rtr:cp
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    most
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    {,.|979
    trii
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    a
    !,rrqt:
    parL
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    section
    of [h€ I rkc to
    'n,rg1 lnirrrnl
    lif
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    f
    or
    -r
    rintir!ur'311 ],r
    period
    of
    time.
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    in
    t.ir:.,5rJ:lrrgir'!
    ttr,iri
    in
    trl'.,
    tvinters,
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    to
    warmer
    t:emperatures
    causing'lailcr
    o{ygrn
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    i*
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    surnmeas.
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    times of the
    yedr
    0.0.
    aonan,llratiun'g werr Lhf
    hrqirq,;:i
    ,1.
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    4,
    reflecting cooler
    temperatures
    and'gr:edl.er.rlqal ar:Livity. ilr:irolvr.,l
    oxygen
    became
    l'airly
    low
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    mg/l
    )
    irt
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    I ivhi-,rr
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    high.
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    d?'
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    at SLation
    I
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    the surf
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    capacity
    raItrer
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    ,rlqa!
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    4,
    lrrcat"ed
    no!:lh
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    lhe
    rai lr*erj r,a:is(':wryt
    itllip{}rteri tirf
    9r'eate5t
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    I,
    locaterl
    in
    thr:
    ,rrra1.t3rr;ri ar;ir
    iir:,;t,irrt
    i!tli-ii.'
    ,ffr!s,
    phenomcnon
    uay:i.tdicatr
    greaLer:rar-e
    of
    nutrient
    r+'jeneralicr'!
    at 1L*llrin !, rtuc
    to
    warrner Lenperdtrrr'(f5
    artd
    polcr' plant r)pernl itr)t.
    Thc
    l,alrrnt
    qf
    rrirtr'ir,ol.;
    present
    ef
    ltcts
    lhe arnourtt
    o{
    bio'trass
    I
    horever, th,-,
    raLe
    ll
    r-,1r;r-,nr--r.tr-
    iort
    Lrf
    ,.1,
    l-
    't'
    I
    I
    Tlre
    physical
    and chernic.tl
    factors.responsihle
    fer li:rri';ing alqa'l
    .;rr'*'lh
    n!
    diff
    icull to ns5ess.
    Although h:iglter
    i{at.?r
    Lerrp{:r'alures
    afr{J
    i}i)vre!-
    plnnt
    operation
    appeared to
    have
    aftected
    aloal activity,
    t,he
    irnpact
    of lhes*
    factors
    is
    rJifficult
    to
    dgsess
    because the statitln
    in
    tttis
    coolinq
    I'rke
    thaL.rras
    li:.rst
    affecte<J by
    tlre
    power
    plant,
    SLation
    4,
    wds
    very
    dif
    tcrent
    f
    rorn
    Ihe
    olirer
    ,l
    ,:;,..
    :'
    slalions
    in
    ol.her #ays,
    rnaking
    conparisoris
    <Jifficult. LighL
    inLensiLy.was
    .r.':'',j,'
    was by
    far the
    gr:eatr:s1", Nutrients were illgo dif
    ferenl
    at Slation
    4 since
    phosphorus,
    rriLrogen arirl cdrb0n
    (alkal
    irrity)
    conccrltraIioris
    at
    Station 4
    lll
    ..-.::.,,"
    varied
    frorn tlle
    other
    l.hree staL,ions. ln
    addiLion, some
    of thcse
    par'arnettrs
    ,:l:::.'.1:
    '
    =_.,-
    between
    the,.tuo
    years.
    Alkal
    iniLy'wds
    increased
    1n l9B0
    over
    1979,
    lirus
    =,.,,,,-..-,.:providing
    a'gr:eaLer
    carhon sourCe''dg
    well ds
    !n0re
    adeqriatcly brrf
    fer'ed,'vla'Ler'.
    ,'
    .'
    '
    Al so at
    StaLion
    4,
    turbldity was Inuch
    less irt
    l9B0
    tlran
    irr 1979,
    anrt
    Lhe
    .j.':.
    ''
    ',
    ,:..,. ,r-
    .,..',..4
    ,.
    :::'
    :
    t,',''t'
    ,
    ;
    t;"
    :.
    ..
    :
    "
    ''
    :,;;',:,t,,":
    ,",::,
    a'.,-'it'
    l:

    nutrient
    I lmit,ing,facto,
    r,
    shif
    ted
    f
    rom
    nltrogen
    lo
    phosplrorirs.
    Ai
    I
    of
    lre:,e
    factors
    could have beert
    important In
    determining
    Lhe arnount
    of
    algal
    activiry
    l
    a1d,in
    determining
    the
    composition
    of the algal spr-'cies
    presenL.
    tlowever,
    the
    !le,af
    gradient
    -or'9h]-o-19.phyt]
    g
    present
    from tlie discharge:ar"ln,!q.lhe.101.
    11
    uf.!
    .
    of tlte
    11rg
    (ris,.-
    3.1?). strongly
    suqgests a
    direct
    irnpacL
    of
    power plant
    operations
    on
    algal
    activity.
    3.35

    ::
    ::.
    ':l
    .
    'l
    :a.
    ,l
    r
    ''l
    L'iT[llAillR[
    C'ITIO
    '
    Barr,.f,.l,l
    J.li,_Coodnig!!,.J.p.
    Sall,
    arrd
    ,).T.
    tlr:lwig.
    l97fi.
    A
    r;r,cr,r
    guirtr
    .Los.As/6,SASInstitute,Inc,,.Aaleiqh,r{C.]2qpp
    Brigham,
    A'.R,
    lg8l-.
    l{ater
    quality
    in
    a
    cooling
    watcr rsservoir.
    In
    R,t,l.
    ..of,.anlllinoiscoolinglake..:|llinois{atur.altlisLorySurveyllrilletin
    '
    Larirnore'and
    J.A. h"anqtiilli,
    eds.,
    Ilre
    Lj[e iiug.iriii
    iir,ry'
    -do*n
    hisrory
    3?(a):290-319.
    Coutantr
    L'!.
    1980.
    Algal
    investigai;ions
    of
    Coffeen
    Lake.
    ln J.A..
    t,-unqoitti
    '. and
    R'!,l.
    Larim0re,
    6ds,,
    Envir6nmental
    Studies:of
    Coireun
    rii*,
    SecLion
    5,
    flatural
    History
    Survey,
    Dif
    f
    on:
    l:i:,
    and,F.H.
    Rigler.
    lgl4.
    The
    phosphorus
    -
    chlorophylt
    reiationstrip
    in
    lakes.
    Limnol.
    0ceanogr.
    l9(5):l6t-773.
    Harvey,
    l{.tI.
    .l960.
    Tle
    chemistry
    antl
    fertil
    iLy
    of
    sea
    water-s.
    cambridqe
    univ.
    Press.
    ,
    London
    . 240
    ttp.
    tlutchirrson,
    G.E.
    1957.
    A Treatise
    on Limnology.
    \,o1.
    I,
    part
    2.
    and
    Sorrs,
    Inc ,
    ,
    l,lew
    york.
    l0l
    5
    pp
    Jirka,
    /r.14.,
    and
    M.J.
    Carter.
    lglS.
    Anai.
    Che;n.47(B):139/.
    King,,:[J.1.
    1970.
    The
    role
    of
    carboir in
    eutrophication.
    Jourrral
    !later
    Pol lution
    Control
    Federation
    4Z:2035-2051
    Liehr,,,s.
    1979.
    cof
    feen
    Lake water
    qua'i
    ity.
    In
    J.A. rran'qui
    ll
    i
    '
    Larirnore,
    eds.
    ,
    Envirorrrnental
    studies
    br cd-f,reen
    Lake:
    '
    First
    to
    central
    Il linois
    Public
    service
    cornpany.
    Il
    linois tiaLural
    Survey
    ,)ohn
    i,liley
    and
    R.t,l.
    Annual lieport
    Hi
    story
    t
    I
    I
    I
    I
    t
    t
    I
    Liehr-stor:ck,
    s.
    .l980.
    coffeen
    Lake
    water
    quality,.
    In
    J.A. Tranquilli
    arrd
    !.ri,.
    -Larirnore,
    eds.
    ,
    Environmental
    Studi'es
    of-CofT-een
    Lake: ieconO
    nnnuaf
    '
    fl9n9.t
    to
    Central Il
    I
    inojs
    Publ
    ic Service
    Ccrnpany.
    Il
    I inois
    Natur.al
    .
    .,
    l{i
    s
    tory
    Survey.
    Park,.P.K.
    .1969.
    0ce1n c02
    systenr:
    An
    cvaluation
    of ten
    rnethorls
    of
    investigation.
    Linrno
    l. 0ce.rnogr.
    i4:119,
    .',
    ,,1.
    Pomeroy,
    :
    Science:131:1731-1732.
    L.R.
    .l?60.
    Residence
    time
    '
    of
    :
    rlissolved plrosphaLe
    :
    irr
    naLur.dl
    :
    ,
    waters.
    Riglea,
    ,
    ,
    Li
    mno
    F.H.
    l ogy
    ''
    lsJ!,
    263-?7
    -!!osphorus
    3.
    cycling
    .
    ::
    in
    lakes.
    :-
    In
    F.
    [luther.,
    Funrlarnent]ats:of
    -
    I
    1,.
    T
    I
    .
    :
    I
    I
    i
    I
    ..
    :':
    I
    3.36

    sotso,ql-l:l.!yl{l,
    fteport
    1".
    lg!!,
    r.97t
    ,
    l1
    [e+1o9y
    '{,1n.",uttanrs
    r,
    tnc.
    '. Inrr-;.r.:.rl
    oemons[ratlonpur5Uantto..,Jllinoisl'olTJt-icin{]onil,':lB+ar.Jt,u|esart,J
    l!sulations,
    Centrol
    tllj.nois,public
    Servir_e
    li:,np,iny.,-iofir,r,n
    po"r,i'
    ]:..Stalion,..unit5.lanr|?,Hay3.|,|g77,-
    Stanrlard
    lrtethoris.
    f or
    the
    Examinat
    ion
    of
    'daler
    cnrl
    .rynerican
    Puhl
    ic. l{ealth
    Ass'sciation,
    Aner icrrn
    ,',
    l.lash
    i ngton,
    0C
    .
    874
    pp.
    lJatf
    ewater
    ,
    I
    4Llt
    rrl,
    197
    6 .
    i.later
    'r'lorks
    Astor;
    iat
    itin,
    I'letzel,
    R.G,
    1975.
    Limnology.
    l,J,B.
    Saunrlers
    Conrpony. Phila6elpiria.
    /,11
    pp.
    .:
    .:'
    3. 37

    t-=-
    il-'
    :
    tl,
    t-=,
    ''
    I
    '
    SECTI0ll
    il
    Cllil'l
    I CAL,C0ll5T
    ITLtl,lt
    I5
    ul
    h'Y
    . '::
    ,' .
    ,
    ,.,
    Susanne
    G.
    l.lood
    'and
    Teresa
    A. Schu
    l
    ler
    i'
    ,"
    ABST
    RAC 1
    A,
    three-year stutiy
    of the
    chemical c'onstituents
    presenl
    in
    Coffeen Lake
    was
    '.
    undertaken
    as
    part
    of
    a
    multi-disciplinary
    3-year investigati0n
    t0
    evaluate
    "
    .
    the
    enviionnrental effects
    of CIPS Coffeen Power
    Statjon
    on
    Coffeen Lake.
    Major
    changes
    in the disposal of
    coal combust'ion wastes and the discharge of
    waste-
    water
    at
    the
    povrer
    plant
    were irnplemented
    between
    l4arch
    l97B
    and
    llovcrnber'1979
    for
    the
    purpose
    of
    reducing the amount.rf
    pollutants
    eriterirrg the lake. The
    major obiective
    of thjs study
    was to
    determine
    how effective
    these changes
    wer-C.
    f,later,
    sediments, sediment
    cortss, two species
    of macrophyes,
    dncl'six
    species
    '
    of fishes
    were analyzed
    for thei r contents,:of
    chemical consti
    tuents.
    The
    concentrations
    of chemical
    constituents that sornetimes accurnulate
    to
    unde-
    sirable
    levels
    in
    aquatic
    ecosystems
    (Cd,
    Cr, llg, Pb, and Se)
    were corrsidercd
    to
    ,be
    of
    pat'amount'importance.
    Pb
    concentrations
    were Lrelow
    the
    detection
    linrit
    of
    the analytical'irrstrutnent for most of the samples.
    0f
    the
    four:ecosystem
    con-,
    ponents
    showing measurable Pb concentrations
    cluring
    the first
    year (pondrveed
    an,l
    three species
    of fish), on'ly one fish
    species
    conLajnecl
    measurable
    aruounts. during
    the second
    year.
    None of the ecosystem cornponents
    contained measur^ab1e
    levels
    of
    Pb
    during the
    final
    year,
    a,
    gratifying
    fin<ling
    when
    improvenent
    in
    environ-'
    mental
    quality
    is
    the
    aim.
    ,,
    .'ln
    the
    present
    ,study,
    the
    steady
    decrease
    'in
    Cd concen
    tra t
    ions
    i
    n
    a 1
    I ecosys
    tem
    conrponents
    rluring
    the 3-year
    period
    is
    indicative
    of
    improvement in
    environ-
    mantal
    quality.
    The
    same
    conclusion
    can
    be
    drawn for
    Cr antJ
    tlg. These
    decreas-
    ing trends
    are reflections of similar
    decreases
    in
    the
    surrounding nrilieu.
    l,-
    1""
    !,.
    ,.
    '.a
    I
    'l
    :.
    .,1
    t
    'l'
    l'
    ''
    T.
    .
    :.:
    1.,'
    '
    ,
    I
    '"'
    ..'
    .:
    l
    I''"',
    I
    .:
    I
    'l
    There has
    been:,concern
    aboutr,the reported
    ,reproductive
    f a,i
    lure
    ,in
    f
    ishe.s inhabi
    t-
    ing
    lakes
    that
    are
    subject to
    expoiure
    to
    industrial
    wastes. lrr
    the
    piesent,t'
    study, the
    annual
    nrean
    concentrations
    of
    Se in six
    species
    of
    fish
    taken
    Frorn
    ,:
    ::;
    :,
    .
    a:
    '.:a:a,:
    :
    4.1

    rr':::
    j:::
    cof
    feen
    Lake
    between'
    lg/B
    and
    lg8l ra'nge,J
    from less
    lhan ilrr.r
    rierccLion
    l inr.it of
    the analytical
    instrument
    (0.29
    pfrn)
    to
    1.B9
    ppn.
    All of
    these
    levels are
    well
    within
    the
    range
    of
    concentrations
    (0.5-i,0
    pm)
    repcrted
    for fishes
    frcrl
    another
    lake
    wherc
    fish
    reproduction
    was
    norrnal. Ihus,
    thc
    reproducljvc
    :,urcers
    of
    fishes in
    coffeen
    Lake should
    not
    be
    affected
    by
    5e
    at
    the
    presen[.
    The
    overall
    conclusion
    for
    this
    3-year
    study
    of
    the clrenrical
    conslituents
    in
    Coffeen
    Lake might
    best
    be stated
    as:
    improvanents
    in
    the disposal
    of
    the
    coal
    cotnbustion
    wastes and
    the discharge
    of
    the wastewater
    generaterl
    by the
    power
    'plant
    have ied
    to a
    s.ignificant improvement
    i'n
    the
    unuironnun*,
    nruiiry
    or
    lru
    I
    ake' s
    ecosystem.
    I
    I
    t
    I
    t
    t
    I
    I
    I
    I
    I
    I
    :
    ]::
    T
    I
    I
    I
    :.
    :.
    :.:
    :
    .l::.
    :..::.
    l.'
    4,2
    .-;:;:

    t
    :.:,
    -.,
    I.
    '
    -lt:
    :
    l.
    'I
    t:
    .:..:
    a"r
    :
    ,.
    I.
    -l
    ,::,r,:
    !,
    r
    I.
    a-
    -,
    I:
    ::a'a.::
    ::-:i.
    -:
    IT:
    :1:-;::i
    :t:
    '
    :l:
    l
    t,,
    '
    ::;
    '--'
    j
    :
    :.
    :..,
    -',
    -'i
    i
    :
    lliiftI--:0ucl
    l0li
    ,
    '
    ::
    The
    neerl
    for large
    quantities
    of
    waLci
    to caoJ
    etea$
    in
    i:lecLric-qeficr*?.j,t!
    statjonS
    has
    resulted
    in
    constructiorr
    of
    nlany
    lal:cs
    in re{cnt yeaf5.
    ',.lhen
    Lhe
    j.'...
    generating
    stations
    dsSociated
    with
    these
    latres are
    fucied
    vdith
    {odl, csrbustion'
    wastes
    are
    a
    source
    of
    trace
    metdl
    c0ntamination
    t0
    boLh
    the latres
    an<!
    the
    surroundjng
    ldnds.
    'Coffeen
    Lal,e,
    which was
    bui lt in
    i963
    to
    provide
    wate'r
    for ',
    Central
    Il'linois
    Public
    Service
    Conpany's.Cof
    feen.Power Plant,
    is one
    such''lake,l
    Because
    little
    outflotr
    nonnally
    occurs,
    this lake retains
    almost all
    of
    the
    ,
    i.hemical
    constjtuents
    entering
    by
    means
    ot': both
    the
    thermal effluent
    frcm
    the
    Power
    plant
    and
    the
    inflowing
    waterfroin
    the'lake's:watershed.
    Loss of
    water
    '
    from
    the lake via
    evaporation
    concentrates
    the chemjcal constituenLs.
    Dressen
    eta,|'(l9i7}andGriffineta.|'(l97B)<lemonstratedthatnanymetalsin.s.la9
    .:
    and
    fly ash -
    waste
    products
    of burned
    coal
    -
    have substantial
    solubjlities when
    leached
    by water.
    Sjnce
    these leachates
    entered Coffeen
    Lake
    frorn
    1965
    to
    1,978, enhalcemelt
    of
    the lake's chemicaJ
    constituent
    conLent
    and
    concoritant
    deter:ioration
    of i
    ts,
    water
    qual
    i ty were distjnct
    possitri
    I i ti
    es.
    -
    l
    ,.fvl6j6l.changes
    in
    thc
    disposal of
    coal combustion vrastes and
    the dischlrge
    of
    wastewater at
    the
    Coffeen
    Ponel
    Plant,
    which
    were
    nrade
    betryealr
    l4arch
    l97B and
    November
    1979,
    great'ly
    reduced
    the
    anrount
    of
    pollutants
    entering
    Coffeen,Lake,
    Because of these
    changes, the overal'l
    qual'ity
    of
    Lhe lake's
    water,
    sedinrents,
    and biota
    may
    have
    begun
    to improve,. In
    particular,
    concentrations
    of chsnical
    ,
    constituentslin sedinrents
    and biota
    rnay
    have begun
    to
    clecljne.
    Thus,
    the
    objec.
    tives of this study
    were twofold:
    (l)
    to deterrnine
    concentrations
    of
    cher,rjcal
    constituents in selected components of
    the lake's
    ecosystem during
    the
    Lime dis-
    posal
    of combustion wastes and wastewater
    was irnprovecl,
    ancl
    (2)
    to assess
    the
    recovery
    of the lake
    by
    tnoniloting
    changes
    in concentrations
    of
    cheinical
    con-
    stituents cluring the
    following two
    years.
    The first objective
    was
    addressed
    'between
    September
    and ,lune
    Lglg, the
    results
    of vrhich
    r.Jere reported
    by
    Smith
    and
    Duda
    (1979).
    The
    second report
    analyzed
    and
    interpretecl
    data
    coliecterJ fronr
    ,'.'July
    i979 to,June
    1980, i.e,,
    the
    first
    year
    of
    recovery
    of
    the lake
    follovling:-
    modifications
    of
    the
    combustion waste disposal
    and
    the
    wastewater
    discharge
    into
    t.'the
    ,lake
    (Anderson
    -et
    al.
    .19S0).
    The
    preient
    report
    ana'lyzes
    and interprets
    ::
    the data collected
    from July
    1980
    to December
    1980, i.e.,
    the second
    year
    of
    4.3

    :
    :
    ,,.
    .j-.
    |
    :
    recotery
    of
    the
    'lake''.
    .Ihis
    report,also
    jntarpt"cts,thB
    rcsul Ls
    of
    the
    3-yeai'
    investigatjon
    of
    tlre lake's ccosystem.
    Samples
    j
    of water,
    sediment, macrophytes,
    and fishes
    vrere
    andlyzerJ
    for
    silver'
    ::
    ,.
    i
    :
    (Ag),.,
    arsenic
    (As),
    boron
    (B),
    bariunt
    (tla),
    calciuru
    (Ca),
    cadniunr
    {Cd),
    chranium
    (Cr),
    copper
    (Cu),
    iron
    (Fe),
    nrercury
    (119),
    potassium
    (K),
    rnagnesirrnr
    (l,lg),
    manganese
    (Mn),
    sodium
    (Na),
    nickel
    ,,(f,li),
    lead
    (Pb)
    ,
    selenium
    (Se),
    antj
    z'inc
    (Zn).,
    Coal,
    slag,
    ,a'nd
    f ly ash samples
    were analyzed for tlr.
    abo'..e
    constituents
    plus
    aluminum
    (Al),
    cobalt
    (Co), phosphorus
    (P).'silicon
    (Si),
    and
    titiinium
    (Ti),
    Water'
    r*as
    also
    analyzed for
    cyani'de.(Ct'I.
    )
    ,
    '.
    CTUDY
    J I
    VU
    I
    AREA
    arllLrr
    The
    Coffeen Power Plant
    is a 945-H|.J
    generating
    station
    located in southeastern
    Montgonery
    County of central Illinojs, The
    first unif
    (350-l'ltl)
    began
    generating
    electricity
    for corunercial consumption
    jn
    1965,
    and,
    the second unjt''(595-MI,l) went
    on
    line
    in
    1972. Fuel
    burned at this
    facility
    is'primarjly
    Nurrrber G coal
    that
    .isobtainedfromashaftmjne(Consoll1i]lsboroMine)locate<lac|jacenttothe
    plant.
    Number
    6
    (Herrin)
    coal
    is
    fhe
    most
    extensi'vely
    rnined
    coal
    in
    I
    ll
    jnoi
    s
    l
    (Ruc.hetal.1971).Thep1antconsunted2.0Bmil]iontonsofhigh.su.lfur(3'.4
    percent)
    Number 6 coal and
    2.21
    mjllion
    tons
    of
    total:coal
    in
    1978:(Lin and
    Dotter
    1979).
    Coal
    burned
    in the
    Coffeen
    Plant is reduced
    to approximately 23
    percent
    of its original
    nrass;
    about 70
    percent
    of
    the
    residue
    is slag
    (bottcnr
    ash)..andtheremainderisf1yash(JanetKennedy'pers.conn').Thef1yashis
    removed
    fronr
    thersnroke
    by electrostatic
    precipitators.
    From 1965
    to 1978,
    the
    i,
    :::
    slag.and
    fly ash were
    sluiced
    to
    an'area
    located to the east of the'power
    plant
    .
    and:in close
    proxim'ity,to
    the east
    (heated)
    arnr of
    the
    lake.
    Leachates in
    the
    returned
    sluice
    water entered
    the lake unabated near
    the
    thermal discharge.
    Because
    of changes
    beginning
    jn
    March
    1978
    and completed
    in
    Novemb'er 1979,
    the
    slag'-'is
    now
    dewatered
    in
    bins
    and:then transported'by
    truck
    to
    a slag
    storage
    ,',.
    area
    (formerly
    the
    slag
    pond),
    and fly ash is
    accurltulated in
    a
    silo ancl
    then
    trucked
    several
    mi'les to
    an approved
    landfill site'.
    .:.
    T
    I
    I
    t
    T
    I
    I
    T
    t
    t
    I
    I
    l,
    I
    t
    '
    T
    a man-made
    impoundment
    with 420 ha,'of surface
    area, and
    a
    water
    t
    .'...:...
    .1,,
    x 10/
    mJ.
    For
    a
    '
    nrore
    :-.
    detailed
    description
    ,
    ,
    of the,.rnorpho-
    1::1
    ,tl.
    t,,
    .
    '
    '..a
    ,
    '.,
    :i
    4.4
    I
    t,
    I

    l
    -
    :.
    I
    ,l
    t',
    I
    :
    I
    ,l
    ,.,]'
    ,l
    :,
    ,I
    .''.
    I
    :l
    'l
    logical
    chardcteristics
    of
    the lakc,
    the reader is refen'ed
    to
    Sccticn I
    of
    this
    docunent.
    ln accordance
    witlr
    tlre
    interdiscipl
    inary approach
    to
    conducting
    investigations
    at the lake, four majo!'sarrrplin{]
    siat'ions
    vrera,
    estal
    ished
    by mutual
    agrecment
    with other
    researchers.
    StaLir.,ri
    I rvas
    iocdLed
    in
    the
    thenna) discharfe
    ann,
    Stdtion
    2
    yras
    est(rbl
    j
    shed
    near
    the
    r,ridpoint
    of
    the
    cooling
    loop, Station
    3
    lvas
    situate'd'north
    of
    the
    intak.e
    bay
    alr<J is consjdered
    a
    transition
    zone,
    and
    Station 4
    was located
    north of thr railroao
    cduseway'and
    is'
    regarded
    as
    the ambient
    area
    (Fig.
    1.2). In
    addition, ancillary
    stations vrere
    nrJ'3
    for
    scne
    aspecLs
    of
    this
    stud.v;
    these
    were designated
    Statjon
    1,5 and
    Sration
    2.5, respectively.
    "
    Materials and
    methods
    for this study:wera
    nodified foliowinq
    the
    first
    year
    of
    investigation.
    The
    four
    maior
    sfations
    reoajned
    the same throughcut
    the
    sturly's
    duration,
    but two ancillary
    stations,1.5
    and
    2.5
    (see
    Fig.
    l;2), werc added
    during
    lhe
    second
    and
    thjrd
    years
    of"study.
    0ther minop
    changes inclutjecli
    (l)
    reducing
    the collection
    of
    water samples
    to
    once
    a nronth,
    (2)
    elinrinatingrthe
    fjltering
    of
    the water sarples,
    (3)
    discontinuing
    the cyanide analysls
    following
    the June
    l9B0 water collection,
    (4)
    adding
    three'spec.ies of fish
    during
    the
    third
    year
    of study,
    (5)
    obtaining
    a
    nrore
    thorough
    collection of nracrophytes
    during the
    second
    and
    third
    years
    of
    investjgaLion,
    (6)
    collecting ancl analyzing
    sedirnent core samples
    in
    the
    third
    year, (i)
    collecting and analyzing
    coal,
    slag, and fly
    ash samples from 0ctober
    1980 through
    February
    1981,
    (B)
    con-
    ducting
    Na
    and
    K analyses by enlission
    spectrophotonretry,
    and
    (9)
    nroclifying
    the..l
    thi
    r<J
    year.
    SMPLE
    COLLECTI
    ON
    Table 4.1
    lists
    the total nunrber of samples
    collected for
    the chernjcal
    constituents
    portion
    of
    this study
    frorn Septernber
    1978'.through
    l'|ay,.l9B1.
    ''
    hlatct",
    samples were collected
    daily
    "during
    one
    week each in Septenrt,'r
    and 0ctober
    1978.
    Duplicate unfiltered and
    filtered
    (0.45-micron)
    vtater
    sarnplcs
    were
    collectecl
    monthly from
    Novernber
    1978 through June i979.
    Quadruplicatc
    unfjltered
    rvater
    samples were collected monthly fronr July
    1979
    through
    Decerrrber
    1980, All
    water
    4.5

    a...
    ''r:.
    :
    .;
    :
    :
    '
    I
    :,.
    Tabl,e
    4.
    1 .
    Tota
    l, nurnber
    :
    .
    constituents
    :,
    of
    sanrp'.ies.col
    lecterl,:and
    .tn,Jiyred
    f
    or chen
    jcal
    frorn
    September
    197[J
    i,hr.ourltr
    .].rly
    l9Bl,
    'l
    I
    I
    r
    978-79
    't9
    I
    79-
    B0
    tq*0-8t
    Tolal,by,:lype
    l{a
    ter
    /.rl-
    t, ll
    Macrophyte
    s
    --___-
    A.mer
    lcan
    Pondweed
    C''cep
    inq l,laterpr
    i
    mrose
    Sed
    iment
    330
    120
    I
    t
    1
    B
    50
    33
    t6
    tB?.
    96
    oA
    6il8
    ?48
    (5
    35
    6B
    t)
    2l
    30
    v
    ll
    JIJ
    Fish
    ,:
    ,
    La'rgemouth
    Bass
    :
    :,
    6i
    zzard Shad
    .
    ,
    Bl
    ack BuI
    Ihead
    Car
    p
    '
    Bluegill
    : Channel
    Catfish
    Cores
    ,coil-
    Fly
    nsn
    Yearly
    Totals
    Grand,Total
    40
    40
    20
    40
    40
    t2
    2A
    ?0
    20
    30
    20
    3?
    30
    453
    r30
    il3
    .:i
    4B
    :
    20
    ?0
    20
    30
    .20
    :
    ,30
    56t
    428
    1
    ,447
    4.6

    I
    I
    I
    I
    I
    I
    t
    samples col
    leCLt:d fOr
    chenicai con:tituent r:rr,ri;',ii;
    i;i:i'i ,lirl;-,r;l t;i'iert'
    :.lmi:le:
    and we re
    preserved
    with
    rtitric
    a|i rJ
    i0.iji
    f
    iriir I
    i':",:.q',
    f
    r',tt'ii r:;.
    r,ltllr'
    :rr;:tl,ie:
    fOr.=Cyanide
    (Cl|-)
    analySi5'dere
    Z,liler
    5y1-f,3r--11
    Sitrlijrlei
    r-*iiti,lilj
    i:-r .: ,.
    'ri.tte
    lrorn
    Septenber
    l97B through.]une 1979 and
    1;r^eir:r'verj
    uiilr
    ,,crjl.-r:'-
    i;-,,dr"+r.
    i')r
    '..;.?.
    final
    concentration). All
    salripies
    for rjicrlsurel0(:fri-i,
    {,f
    iili.:::ii,1 i
    c,lr,rLltL;rlri1
    were|efri:::1.-1.untilana-ly:ad;.:aix|]e5l*rc.viltii;j8.1t:!.€r'lr'i:iiLj0l.iwi:t.t
    ana1yzedwithin24hoursafterco'ilect.ion,
    Bottorn
    serlintent
    sanples were collacted ir, tha
    falI
    af i978
    at
    the
    four
    rr;aji:r'
    stations
    (Fig.
    1.2). llrring spring
    an,J
    f al I of lrij.ii,
    b0ttcn sr-^dinrr,nI
    salnpies
    r,rere
    collected at the
    four
    major anrj Lhe
    t''/c
    dncil).rry
    staiiorrs
    itig.
    i.;i].
    A
    15,2-cm x
    15,Z-cn x 15,2-cm
    Eknan drecJge wjih a
    chaniller
    volunre
    of
    i540
    *,3
    was
    used to col
    lect sedimqnt
    frorn
    tlre
    lahe botLom;
    the Loli
    ? crn
    c{
    nrat.c.ri.r
    I wer'e
    retained for
    analysis,
    Shore line sanrplcs
    cofrtaininr.;
    trinrari
    ly
    sand
    vtere
    disallowed during
    the final tvro
    yedrs
    of
    the
    sLurty.
    All
    srmples r,rere
    fr'0ren
    un
    ti
    I
    prepdred
    for ana
    lys i s ,
    .
    The
    species
    and
    numbers
    af
    macrophyLe
    sampies collecte<l
    Flel
    year
    dre
    givc.n
    in
    Table
    4.1.
    Creeping waterprjmrose
    (Ju-s_s_g_qa
    .LqIg$,)
    vra,
    co'llccted
    dt Str!'r'ons
    1, 2, and
    4
    in
    September 1978,
    at all four
    inajor
    stations
    .in
    Sr"
    itefl;ber
    1979,
    and
    at
    al I four
    rnajor an<l
    the
    tvro anci'llary stalions in Septerlbcr'
    l9ll0.
    l,io
    waterprimrose
    rvas
    found
    at Station
    3 tlurinS
    Lhe
    i97B
    colleutiorr
    period.
    Anerican
    pondweed
    (Potanrogeton
    ry-{gs-qs)
    was
    collected at, only Station 3
    in
    September 1978,
    at
    Stations
    2,3, and 4 in SepLeniber
    1979,
    and
    at
    Srdtions
    2,3,
    and
    4 and the
    two
    ancjllary stations
    in
    Selltember 1'980. This
    macrophyle
    was
    not found at
    Station I during
    any of
    the
    collecting
    periods.
    The
    sarnples
    were
    stored in,polyethylene
    bags urider
    refrigeration
    until
    prepared
    for'analysis,
    Species of
    fish collected
    for
    this
    st,udy
    inclurJed:
    gizzard
    shad
    (Dprulg1g
    cepedianunr),
    a forage
    fish;
    black,bullhead
    (tctaluigs-
    ntelas),
    a low trophic
    level omnbVoie;
    and laigeinouth
    hiass
    (l4jclgrle_t"q,s_
    _g_l!Ul_d3_t),
    a
    higlt'trophic
    level
    carnivore.
    ,ln
    addition
    to
    the above
    speciesr, tha
    following
    fishes were
    collected
    during the
    third
    year
    of
    the
    study:
    carp
    (lpf11uf
    -c-ajpl-g.),
    a low
    trophic
    level
    oinivore;
    bluegill
    (Lep-omtt
    rullqdfrutj";;;tl;0il
    ono
    channel
    :''a
    ::
    ,
    :
    i
    ,l
    t
    :l
    '
    T
    I
    'l
    I
    I
    I
    q.7

    ii'i
    rlr::=';
    ::
    .' .r::,
    ,'
    :;,,t
    r',;,
    .:i.:.a'':
    I
    T
    I
    Cdtf
    i5h
    i
    k_t{lU_':J.3
    lijlilila-trtr,.
    'r
    loyr
    ',-rr-)l)n:i:
    ir.yr, I
    }:r
    :,
    ,-i,.
    ',.f
    :
    ,r-1iir.i,t ,
    .;r
    th€
    ..=.
    f
    islre: Here,
    col
    lecte:J
    by
    elee lra;'ishinrj- l,rl;ir-'
    i.I
    i:,.j,t,,
    ..i\,i:i
    !
    irtrr..,
    :,-,.
    SpgcieSranrJ
    nunliel'
    coll*ctcd
    iier
    /ear'+i
    litr:
    tnr{-.,,ii,'lnl-':
    .r!":.
    .:.,:,i
    r...;t,.rrr-r'i'i
    :
    l
    ::
    the
    date and
    point
    of
    col lcct,iqn dre
    tjrr:
    s{-:ritec
    :rr
    i,il;lr
    .i,.:. ,i:i
    ! r',r;t.-,.
    i{ir!'i.f
    5'L$red
    fIozcn
    unlll
    praparerl
    for
    anii.yiis.
    '
    :
    ,,'
    Sedintertt
    cores we re
    collectsdrin
    June
    19i::0
    u.iing
    d
    c0rcl'
    :norJeileri
    irf
    Ler'liilrles*-
    Ba'llchek
    Sinqle Tube
    Cqre Sanipler
    l4odel
    2ill
    rvi th
    3-$-slr-didircLr-,r'
    5y 6l-r,ir-
    icng.
    plastic
    col
    laction
    tubes dnrJ 5 llg
    of
    counLer!,rlighls
    iFiq.
    ,t.l
    ,
    . Ttre sarrrgles
    yrsre
    co'lecled
    by
    means
    of
    a
    winch anrl
    pulley
    system
    rnounted
    cn
    a
    porrahrle
    l;cat
    crarre
    wi".h
    a
    6-foot
    hourr.
    Iive
    santples
    per
    sLatisn were
    calleci.ed alorrg
    tran5ects
    at
    Stations
    I,
    1.5, 2,
    2.5,3,
    and
    4. The
    tubcs were
    lrbelc<t.
    corl:ed, drrcl
    frozen
    un
    tr I
    prepared
    for
    ana
    lys
    i
    s,
    Coal
    ,
    slag, arttl
    f ly ash
    samples
    vrere col
    lected
    f
    rom
    0ctobcr,
    17,
    l9B0 Lhrougti
    Febt'uary
    2l, lg8l.
    Coal santples
    wc.re
    taken
    frun
    conveyor
    belts cltering,the
    '
    power
    plant,
    slag
    from
    the dewaterjng
    bins, an<l f
    ly aslr fisn
    thc',f ly aslr'silo.
    i
    '
    Col lections were
    made
    by
    CIPS
    personnel
    from
    zero to
    [hree
    t-inres
    per
    r.reett
    during
    tlte above-mentioned
    periocl.
    Sanrples vicre
    individual
    ly
    storcd in
    scolr.,d
    po.|.yethy.|enebagsuntiiprepar.edforanalysis,
    ','
    SAI4PLI
    PREPARATI
    OI.I
    I'
    lhe
    water satnpleS required no additional
    preparati0n
    prior'to
    analysis.',
    '.,,.
    ,',1
    Sedinrent satnples were freed of
    excess water
    by
    decantation;
    the sanples
    wcre
    I
    then
    placed
    in 150- or 300-rnl Virtis bottles
    and freeze-clried.
    The freeze-dryer
    I
    used
    in
    sample
    preparat'ion
    was a
    Virtis
    Unitrap
    i0-100 with
    a l.telch
    Duo-Seal
    t
    Moclel
    iil402 vacuunl
    puntp.
    The sediment cores
    werc spliL
    iengthwise
    and
    sectioned
    into
    six
    3-to-B-cm segments, representing
    recent sedinrent,
    four interrnediate
    I
    sedimentation deposits, and an
    origina.l
    sediment. The seqments
    yrere
    thelt
    iieeie-aried
    'as'above.-
    A'nibrtaF arrd:
    oer
    pestlo
    was
    uSeid- to
    grjnd
    and-lronogen]ze
    -
    the sedirnent
    t::
    and''sediment
    :
    core'sample'i. sufficiontl.y
    to
    pass
    a
    1O0-nresh
    1y1on
    ,'
    I
    sieve.
    For
    ntacrophytes, a
    thorough
    washing with
    tap
    water-ren,oved nrud
    and
    other
    ex'traneous
    naterial.
    fhe sanples
    were rinsed
    several
    t'imes wjth
    deionjzed
    :'.,
    ,
    ,:,
    i
    waier
    and,:'thoroughly
    diainedi,,ghg
    leaves and
    stenrs were
    separated,' weighecl,
    ,.:
    ..
    i.
    4.8
    il
    .T
    I
    t
    T
    I
    I
    .T
    ,l
    I
    :l
    .l
    't
    ..'
    .:
    'l

    -::l
    I
    I
    I
    I
    I
    Iable
    4,2.
    Cr:llee
    llon
    rtate,
    i*1lr::?trirl
    pti:1.-!
    *
    i:,;r,!;;r,
    :
    {)hl
    a i
    nq:El
    f
    ro{
    Cr;
    f {eeir
    :,-t
    i:€
    .
    0ate
    Col
    lecterj
    i.if i
    Ir'r?
    ii:fi
    tir,it,r
    ..
    5t at.
    i
    *r:
    !
    5l
    at
    ir,:ri
    ?
    ','i
    if
    i
    rr1
    1
    i,i;l
    ii:n
    t
    T
    t
    I
    I
    I
    '
    ll78-
    l
    97e-
    0etober
    l97B
    .f{o'rernber
    l97B
    March
    I 979
    ,rel9:l
    iqQ
    Novernber
    '1979
    January
    l
    9B0
    ,
    March
    I 980
    I
    980-t 9Bl '
    May
    1 980
    September
    l9B0
    November
    I
    980
    4
    'Ll4u
    5
    SHAO
    5 LI4B
    IO
    LMB
    IO SHAD
    I BLKBIJ
    ,3
    BLKBLI
    I BLKBH
    l0.tMB
    IO SHAD
    5 CARP
    5
    BGILL
    5 CCAT
    5
    Lr4ti
    6
    5|fAS.
    2 BLKBi!
    l0
    Ll,lB
    .
    l0
    5ttA0
    ,
    2
    llLXBtl
    3
    BLKBH
    IO LMB
    IO SHAD
    1
    BLKBH
    5.CARP
    .
    5
    EGItL
    5 CCAT
    5
    Lflii
    5 SliAii
    5
    Sl{A3
    5
    ftLKgr{
    IO
    LMB.
    r0
    SHA|
    4
    llLKBl.{
    l0
    LMU
    I
    O SHAD
    I
    BLKBH
    5 CARP
    5
    BGILL
    5 CCAT
    2[r
    L
    t4tl
    &
    :;iiA'J
    'i
    gi
    l,titl
    5
    Lf.lB
    5
    SiJAtr
    5 BLKB}I
    l0 Lf'tB
    l0
    5t{Ac
    6
    SLKSrj
    I
    O
    BLKBH
    l0 silA0
    iO LMB
    5
    CARP
    5
    BGILL
    5
    CCAT
    -LMB
    =
    Largemouth
    Bass,
    SHAD
    =
    Giizarcl Shact,
    BLKBIJ
    =
    Ulack
    Bullhead,
    CARP
    =
    Carp,
    BGILL=Bluegi.!l'CCAT=Channe]..Catfish.::
    :-.'1,
    I
    -
    i
    tl
    :,,,.,
    t
    I
    !;;':
    i
    4.s

    ..a.:
    ra
    '
    .
    I
    I
    I
    I
    I
    t
    I
    !
    I
    t
    I
    l
    J
    a
    'i
    'I
    :i
    ''=l
    :l
    !

    {
    .
    '_:f:!P:.'ir'^
    ::I
    .
    :l
    ,t
    ,
    rl
    :.,
    I
    :
    :l
    T
    T
    I
    I
    I
    !
    I
    'l
    I


    l-'
    .
    t.ii"
    l-=
    1",
    I::'
    I::
    I:':
    -:
    and
    f
    f0czt-,-drig.:j
    ln
    ,il'l:i\j1:tt:.
    t,:i'l
    i'jd:,..
    ,,,t:i
    :
    ,-t..
    ,
    t,,
    .r..r.
    ,t
    '':t.
    itrvastigation, lenf
    altd
    tLi::!i !'tii;rlt?'j Hr:r"{.
    l,rr',,,:.,
    ,,.t
    i,i
    ;
    ,:
    .:,,
    ,.r.;3 1,..
    iitrji.v'idua]}7irrta;ic;;,11i1.;;e!jEhJt,'di!il.r;,.1.Jl!l:r:,1ir''}:iil'lj.i].ilr..:Jlii..?':
    mdnipulatinq
    lry
    iiand.
    [r.iri611
    llir.
    riii]',r
    .i.'.1'-
    :':
    i]r.
    1: ,,ti,
    ..r,i;:.,,
    ri,,!.!r
    i..t
    ,,
    1
    ln
    -polystyrcne'.
    litlttig: wiLti
    ie';t,r'rtl
    i..i.r<.ti{-
    irr}*:irt
    ,rr=i,: l,i:.-i.;:,.rrr
    /r-.-t
    ,',i:;r:
    J
    -=i:Br
    ,
    fJCt0'J'll rni;ter/ntil.
    l'isri
    i{t:re
    ttrowtrjr
    :i_i
    il}r.,d!:j,'rr'l
    ,irjl:jtt: ,
    riirl
    r{.:,1,1..1
    .
    ,i
    r
    iljet
    (muscle
    tissuei ir,ts
    rein0vprj
    frcsn
    earh
    f
    iih
    iiler:i.',(rri,
    iui
    i,,,;,.:-rlrr,r,,.
    i,
    l;rcr..l
    rr:
    plastiC
    rcighiltg
    ba*ls,
    and
    i,hen
    frer:re-.lr'ic,,J.
    ihr:
    !rt:rille l.::.rnr'igr.:rii,l,lr-',ori
    proceclure
    duplrcate,J
    thof
    of
    11.,s
    lrdclcpirytes,
    irl l
    J r.,-,rzc-4rir,rj
    .,;r:;,.ii:s
    wflfE
    LoierJ
    in
    pOlyethylenr-i
    tioltlcs
    at
    r0rr:r
    tei:iucr',if
    rrr'r,
    ,,rrlLil
    *li.ruL,t9 i{Fli1
    nte{jrjrJ
    ror. rligestion.
    Coal, slag, and
    fly
    ash
    sanples were
    nir-dr'jerl.
    ecrnblr':erl
    b1
    l.;rpe, and Lhen
    r,
    sorted by means
    of
    a riffie
    to obtain reirr'esenlative
    ruLisanples l-cr.anaJ;ti,-s.
    Four
    subsantpl
    es
    of edch type wet'c
    prep,rrccl
    L{r
    re
    prescn
    t
    i-he
    f nrir
    orru-r'lont h
    perio<ls
    (0ctobcr
    17, l9fj0-tlovcmber 15,
    l9B0;
    Novernber
    l{r, lgti0-Uecenber
    15,
    l9B0; Decernber
    16, i9ll0-Janua,'y
    tS,
    igBl;
    ,rnrJ
    January
    16,
    lgtjl-l'uhrrraly ?i,
    lg8l
    )
    of Lhis subpro.iecL.
    Tltese
    fou:'
    subsatnples
    of
    etclr type werc
    qraurtrt
    '.*o
    tncet
    [he specifications
    for
    analysis
    of
    thc Illjrrois SLdLe
    G*oloili,.,il
    5ur'vey.
    SAI4PLIDIGISTION
    :
    .
    :
    :]
    :
    .
    All.sarnplesweredigestedandanalyzed.in<lup|icaLet'hroughouttlrestudy'Tlre
    vrater samples required digestion only for
    rnercury
    (llg)
    analysis. PoLassiurr
    persul
    fate
    (K2S20g)
    solution t,lds
    aclderl
    to
    the sanrples
    to
    f ree
    arry llg
    thaL
    was
    adsorbed
    on
    particu'late
    matter in
    the watcr
    (il-Awarly
    eL
    dl,
    1976). Af
    ter
    one'. hour, the samples
    r{ere analyzed for
    }lg
    as
    descnilled below.
    The
    deterrninatjon,of total CN-
    in
    vrater'samples
    fronr Septernber
    lgTB
    through
    June
    :
    l9B0
    vras
    perforrned
    accorc.ling
    t,o the
    U.S. EPA
    standarri
    rncLhorl
    (Kopp
    ant l.lcKee
    LgTg), ihe
    cyanide was
    released in the fontr
    ol' hydrogen
    cy{lridr.:
    (t{CN)
    fronr
    the
    a
    the
    r-,
    I::-:i:
    I:::
    I:
    -.
    t'-
    I,
    I.,
    l=
    I,'
    t
    E
    :
    :.:..
    I
    l,::
    I.r
    I:',
    :'
    I.
    t::
    ,
    I..
    I.:
    f.
    -t,
    I
    :::.
    I
    I
    Il
    l-
    r,
    I.
    Hater-by-reflux--distillation
    chloride',(Fig',4.2).
    The cyanide
    in the-presence
    as
    the cyanide
    of
    srJlfurjc
    ion.was
    acid
    then obsorbed
    and
    coDper
    in
    scrubber
    containing sodium
    hydroxide.
    Cyanicle standards
    were
    treatcd
    in
    .:
    ..
    ,:
    t
    ::
    sanre
    -,
    :.
    manner,
    ::
    :
    ...
    ,
    :
    ,
    :.
    l
    -
    4.11

    c0fi.tr{ff
    ilHtn
    ll{[t
    I IiJBt
    *
    lltllt[
    *
    SCetif
    ctAHP
    'I
    I
    ,I0
    l.{}tt
    VtCUUll
    ,
    $0uRct
    '
    lBson8[R
    1
    0tsIil.t
    llt0,
    tLAs|(
    IH
    0ut
    "l
    -'l
    .'l,l',
    t,,,
    ,'
    '.1'
    '
    ''l
    t;;.;','
    '
    :j.
    :
    "I
    ::r.
    "'
    l'
    ,
    :
    '-l
    :'j
    '.
    "l
    .,
    .....
    l
    T
    ....:.
    'l
    '-'l
    --t
    :1_
    I
    ,'
    ..1
    : .:: ::
    c0rt0il{stR
    -'-l
    Figure 4.2.
    .:'
    Diagram of
    distillation
    apparatus
    frorn
    water
    samples.
    r:
    '
    used
    for
    recovering
    cyanide
    4.12

    ,'
    , ,-il-i::
    '''.
    :':.':
    Il,:
    I::'r'
    Ir,
    j
    :,a
    l,r.,
    I:','
    :'. .'
    l,
    f
    .:
    i.:
    l'
    '"
    I
    I
    t
    I
    I
    I
    I
    ,l
    I
    I
    I
    I
    3he
    *aLt+=
    9ef
    irec
    t:
    ;:n,:i
    5!:r"::
    i:-?€;
    !.
    ,
    ,:r-r,
    ..,1-';
    i
    ;
    '
    ,
    ,
    ilorl'>tituetrl
    drn}ySii rigirt* {
    ;::*-'jiIt'a1
    1!'rtr
    i-,
    :,r,
    f'ertln-[ir+*'
    ii'l;L,.
    ,1
    ,jll,itl
    ir,'j
    .it\:t:..,
    f
    r,;:'
    (ti75*4i
    acrd;'nd,. a,-rdrd
    t*
    :,-':
    .:cr':;ilr.,:'rr:
    trthff
    tO Qr l?'dc i
    Orr
    I
    7
    tlrv
    r
    a
    1i;:J1
    i
    441rr;'l,r'ri
    lrntfllt
    cf the
    'ledlF{:rit
    i
    i,-.,F}
    f
    .
    ilir:
    sc-i;1+,r
    BrrtngxiCl:
    rotar''
    Shahrtr
    dnd
    iilr:ri
    r:(jf:irltu4r:.j
    Tan-nl
    fr]
    i.tuotg
    Of
    ihe sup{:rndtdilt-t nr,rq
    di i
    stored in
    polyethyl
    enr:
    b0fi ini
    rlrrt
    i
    'l
    atl I
    y1,
    l
    I
    1
    i:r-::l:
    .
    .;::,:1
    ;r'!:':1
    ,;t
    t?:
    :1+
    1:)
    :
    i=f
    l-
    lxtraction
    of
    iig
    frocn
    the
    Sedi*irjnt5
    Joil
    i€i:i!:;rr.
    l rqrir
    ',n.riii,-,,.
    ,r.]i, arir;;:i;l
    i!nrr:
    usirlt n
    r.r?odjf
    icaLion
    of
    the
    mtrlrarl rie'rcritird
    tr;,.
    Jrrcebs
    ,lrrd
    i.{jsrej'
    i
    !,ji
    I
    j. Li:y*
    regifl
    (UCt:lttfOr,
    l:l bI vol.
    i
    H.1s aCCar!
    t$ 2-q
    <,11:r1i'l
    i,i
    iri
    z-ti0-:;.!
    w!4r:,ri,{r;i-li
    Erlenmeyer
    f
    lasks.
    The
    .,amples
    uL)r'r
    boiltrC
    l,irlrtroul
    j
    /
    f c'
    ono
    ';irrui.r:.
    Af
    uer the saml, les
    hdd
    cooled,
    al iquots
    of
    i
    ilorJsTirlr'!
    fJ0ri;iJitri,lnitL(:
    {i1..Ir,0,1
    i
    ond
    X2S20g
    solutions
    were
    odtJcrl
    Lo lhr
    f
    larhs, i,.ihich
    rirrr'r-,
    lhf,fi
    trlrrruij
    irr
    tr
    qSoC
    nalu"
    bath
    for'30
    minuLes,
    l)rrring
    this
    r1i,;esti(,r)
    i)eriod
    Enall
    iiilal1trlr*s
    of
    crystallinc
    lJ'ln0.,t r./er'c
    addet! to the
    531npler
    lrr
    maintair' tr!r
    ()r,itjieirr,r
    environment.
    The
    sarnples
    were
    coolad
    r
    cafltlifugerl
    ,
    diluLeri
    Lo a l:no,*n
    voiirllc
    (100
    ml
    ),
    an<l
    analyzed within
    a
    few
    horrrs ds dnqcriber!
    belorv.
    lcr analyi'e
    nacrophytc
    and f ish'samples for
    chslir:al c0rlsLituents wi
    th tlre
    exception
    oF llg,
    a toLal cligest ion
    was
    required.
    /i
    5:l nrixturc
    of
    nitr.ic
    acid
    (l{N03)
    and
    per.chloric
    acid
    (llCl04)
    vras addeqJ
    lo
    l-g
    samples wlri:ch
    haiJ been
    preweighed
    into
    150-rnl
    round-bottonr
    di
    sti'l lation
    f lasks. The
    f
    lasks rer.e
    hea.tedonaKontesRotary.KjeldahlDistjl.|ationApparatusuntiJthel{N03had
    decomposed
    (clisappearance
    of rerldish-brown
    funres)
    and rJense
    whi
    Le l.|C104
    funles
    appeared.
    Af ter cool
    ing,
    the
    santples
    wcrc
    di
    luted
    Lo arr apgrropriaLa
    volurne
    (25
    or
    50 nrl). Thjs
    final
    volume
    was
    zBX,
    12i, and
    5?.with
    respecL
    to
    ltCl04
    con-
    centration
    in the
    first,
    second,
    ancl
    third
    years!
    respectively,
    of
    the
    investj-
    gl!,ion:
    -The
    macroplryte
    di
    ges
    ts
    were
    cen
    tri f
    uged Lo retnove
    i
    nsol
    ub'le
    s i
    I i c'ates
    .'
    ;s
    ol
    ved w
    i th t
    ime
    ,
    nra k'i ng
    I
    centri
    fugation unnecessary.
    ,l
    i;
    ':
    iI
    *
    .:,.:,.:-rt1;
    l t:.,1,1.
    ..,
    ,".,;-1:.,
    ..,:...,i;',.,,
    .',.,.
    4.13

    iJiqgSli$fiS
    Of
    t-:itCfgtrhytrl
    t1{i t'ifr
    ,,C.i:riq,,
    r1_,.
    .r.
    rlf.,,ir
    ...,
    ,,.,:..
    .;..:
    ,.r..i.,
    t-,r.,,
    .
    trSint
    d
    nO,Jif
    ifaliOn
    q,1
    ihr:
    *,i'il;r;:!
    ui
    l.iiiii.1*,:,,,
    ,i.,)
    .:.-,rr:
    rl
    r.,..
    ,.i:.,,;
    :.i
    t{2504, tlf{03,
    dnC
    a
    tr'
    /l!n$.i
    tolrlt.igii
    Acr.(, ,lii:+.j
    |
    1
    .
    --,;
    .,
    1:.;.:,,
    r,,
    .,1
    If
    lf.ni**yer f
    la:i:s in
    Ar';
    'iae
    i:rrlli.
    jtf
    l|r :ha;r.:::;{;l:
    .rir1r1.;
    .-,
    ,_,.,-
    i.
    rii
    :.,]!r
    ten,Lgn
    the
    fln5i1
    htrc tf{i*yg,,i
    fr*rc=
    ir:e
    tf.ii
    ir.rii:.
    ir:l;
    ,..r,-;
    .,i.
    _ir:;rld.l,i.,:r,',
    of
    ihe
    rcdctiOfi
    usudllT
    ii
    :ilr),Jlr-.!
    ct
    r'6,rl.,,
    ir.'li;r'r-.:t.,,;
    ri, .rlr.;,rii,,
    (rf
    ,r
    ..r
    r*25201.
    solution
    rr-rre
    .]dded
    r-o
    tn*
    liasr,,
    xhrr-r,:
    H,ar,-.
    rrr..,,
    i
    .,r..,,j
    i,-i
    ,r
    ibG,.
    Hatef
    bath
    fOr
    about
    an
    D-hour
    rti{rs!.}on
    peri*i:.
    l,j::air?cirr
    ar;
    lt:iJt..ir-;it
    onvironmenl
    but
    prevent
    ndn?anr:se *isrioe
    for:r.rii*n,
    r=a1i
    .inoiinrl
    *i
    C"ygtalllna
    li!1n04'#ore,!dde{t
    to
    ilre
    fiasl,
    co*irrlt,t
    lhrsjJgi-rout
    lfrc dierr.,trdr=
    t;:riod.
    ThiS
    periorJ
    yral
    assrJ.T€d
    !.o
    br
    cCIiltllr.tr.
    when
    lht,
    prrr{}le
    r.fi}or.
    (if
    }tir.'lli;
    remainedcon9tantfor30mirtutes.1ltesam;ileEwere.oo;Pd,tr'tln5ferrerl
    c0tnpletOly
    tO
    100-nrl
    volumelric f ldtl:s,
    arirl
    r.r,f
    rigeratcr.j
    uniii anal,/.rriit
    llre
    fol
    lowing
    day.
    coal,
    slag, and
    f ly
    ash s.lmples
    wci'e rJigestt'rl
    accor.dinl
    L0
    rrr.oe
    edrlrcr
    out lirreil
    in
    Apperrrlix
    C cf
    a repcr.t
    by Ruch
    et al.
    (llll;,
    l
    ANALYT
    ICAL
    AI{ALYStS
    The
    vroter s.rmples.
    sediment
    and scdiment
    corc
    extricts,
    anct rnao.oplryte
    anil fish
    digests
    vrere
    analyzed
    for.
    Ag,
    As,
    B,
    Bd.
    Ca,
    Cr!, Cr,
    Cu,
    f
    e, l,lrt
    ,
    Mrt, lli,
    ptr,
    Se,
    and
    Zn by direct-reading
    emission
    spectrophotometry
    wi
    [h .rn inrJtrcLjve).y-couple6
    argon
    radio-frequency plasma
    torch source
    uni
    t
    (
    ICAp).
    The instr.ument
    usect
    was
    a
    Jarrel
    I -Ash
    t'loclel
    975
    Pi
    irsma
    AtomComp
    (
    Fig.
    a.
    3
    )
    . The
    rracrophytc
    and f
    .istr
    ,
    digests
    were
    diiuted
    l:5,
    1:2, and
    0 rluring
    the fir.st,
    second,
    ond'third
    years,
    respectively, in
    order
    to bring
    ths l{C104
    concentrrrLion
    [o an analyzable
    lcve]
    I
    '
    standards
    of about 5!,.
    which
    :Analysis
    r,Iere run.
    adcuracy
    approximately
    wits
    chccked
    every
    by
    iix
    nreans
    sarnples.
    of rlatrix-matc6ed
    ,
    "
    Sodiun and
    potass
    juln
    in al
    )
    samp'les
    during
    the
    f irst,
    yedr
    of
    the
    sturly rvere
    de-
    '
    term'ined
    by
    a+"omic
    emission
    spectrophotornetryron
    an
    tnstrumentatjon
    L.rbor.ato1,y
    ,1,
    Mode.l,
    253
    Atonlic
    Absorption-Atontic
    tnrission
    Spetrophotonreter
    as clescr
    j
    becl
    in.,,
    ,
    the Atornic Absorption
    Procerlure
    l4anual
    (lnstrurlcrrtation
    [.aborcrtory,
    Inc.
    lgTZ).
    'l
    I
    T
    t
    T
    I
    'l
    I
    t
    I
    I
    I
    I
    T
    I
    I
    I
    4,14

    .r l!r
    .l
    t
    a
    I
    t
    I
    I
    I
    I
    t
    I
    I
    fi
    I
    t
    7
    t
    I
    :
    (
    &
    I
    a
    I
    u
    --
    tl
    T
    a
    6
    o
    2
    t
    q
    t
    s
    g
    6E
    o9
    8;
    E9
    yc
    <E
    oQ
    NU
    oo
    t
    t
    I
    t
    +r
    .g
    .-(}-,
    ctncra
    ()
    '-
    t^
    a)'<
    )
    I
    {J
    C)
    >rf,i
    F-
    .-
    c).
    E:
    4J
    rj
    C,
    l-rOt:(^L
    TJLroCL
    6
    crr
    C
    (J^r
    ,u ru
    L
    u.)
    cr)
    If
    '-
    C)
    vl\
    -(]tgr
    Ol
    :O
    tu
    (r'_
    o)-v1)
    (J
    (u
    q-Ou1
    'F
    U
    oJ.F--
    Ec)_C)c
    'rF
    3
    Or
    E.-
    F.D
    .c
    'lJ
    t,
    C).
    C!.
    (J
    r.a
    .-
    E!c{
    'r
    f,L)rt-
    C.r
    (,/)
    rO ts-r
    O
    .-
    Cl
    rn
    <:l
    (U
    t-
    5
    (t)
    LJ-
    i
    ;gEiiiiii;isiiui
    ili,iil
    i'i
    'j;ri
    iiiillfililiiilii;iiluiirliiiir
    t
    T
    I
    I
    T
    i:.'
    !,
    4.15

    5At$ll]**
    ner'e
    rJili;LCd |t!}FJt
    li{.rrt'}!14t'l
    '.iril
    j
    i
    !i;r] 1.
    ,;q.r'1,
    'il'.r,:i;
    ':r-
    i.,.rl:1!*,r'
    ,-,i.1':.-.
    ol-
    f,i.it*,
    instr'uiieltt.
    l'or
    Lht
    irlrorrC
    ,liitj
    ir..ir-<i
    7:.:.rrr
    l;{
    ,.fir-
    .r'r',i..,t
    :-.-,,r
    -i::ir
    fi,r
    .:4..1
    F.
    were
    analyzetl
    bl !CirP
    as
    sld?-r:{ ib*vs:
    !4crCury
    cOnccrt"raliOnb
    ttErfi
    df
    lor'nined
    blt
    i$ld:y:il){.}r
    ril-(E-ir
    .11,,1,1|ir
    ig,rr
    Spectrophotcl{fie
    tt'y
    {f
    ig.
    a.,i).
    Ior
    nar.rophyt{.
    Jrrrl
    f irli
    .j
    t]:r.,,.....
    ,r
    I'i-'i
    *lr:l,ir:r.
    of the
    dirlested
    5ampl, wds
    tFdfl5ferrr:d
    to
    tht
    rra(ti0rr,,,rgir-,j
    .irrrl d
    lr:,*
    rjr':i,)!
    of
    ,ltydroxylamine
    hyclrochloritle
    (tll{gSil.l{Cl}
    ,,re
    r:e atlt!arl
    r-c
    ra{rcvr
    a&ji
    rcfndining
    Kl'1n04.
    Stannous
    clrloriqje
    was
    ad<Jetl
    t0
    rc.rlur-e
    tha
    llg
    t*
    i:,!
    1r,.tror'
    forrn
    (llgo),
    and
    the
    vapsf'
    was
    suept onto an acLivaled
    si
    l,;er wool
    i-'!uq
    bih*re
    :
    the llg
    was
    trapped
    as
    an
    amalgam
    (Long
    ct
    al.
    lt/li.
    l-oj
    lowin.l
    a
    ?-ririure
    co'llection
    period,
    the
    si
    lver
    vrool
    plug
    was
    hcaterJ
    to
    tic-amaiqariiaLti
    thr
    riig. ,'rrir!
    the
    vapor wEs
    swept
    through
    the
    absorption
    ccl I of
    a Fisher
    llercur.r
    r'rrralyier.
    A Varian l'lorJel 485
    Digi
    tal
    lnLegraLor
    wds
    useri
    to
    rnedsurc
    peok
    ,irc,r;
    rvhich.
    when
    cotnparerJ
    to the
    peak
    areas of
    llg
    stanclards
    t
    corresporrdcd to
    lig
    ronclrrtla-
    t,iotts.
    Waler
    samplcs were
    treaterJ
    similarly with thcr
    excc,pt'
    'r
    thdl thc
    arltJition
    Cyanicle
    concentraLions in tlte water
    s,rrnples
    were
    deternrirrecl
    by analyzing
    fhc
    scrubber
    solutions
    (after
    the
    reflux-disLill.rtion)
    coloriinetrically
    using
    rr
    Spectronic 100 Spectrophotometer.
    An al
    iquoL
    of
    chloramine-1 soluLion at a
    plt>B
    was
    acJcled
    to converl the CN- to c,yanogen
    chloride
    (CNCI
    ).
    l'lrc
    color'
    (various
    shacJes of
    purple)
    rvas forrned
    by adding
    pyrirline-barbi
    turil
    acjcl
    reagent;
    readings
    were
    taken
    at 578 nrn r+ithin
    15
    mjrrutes.
    The
    concentration
    of
    CN- in
    the.sanlples
    t,tas calculated by
    comparing
    the
    sanrple rea<lings
    wiblr
    those
    of standat"d
    CN-
    solutions treated
    in
    an,identical nianner,
    The
    plo135rirnt
    cyanide standard solutjon was standardized
    by
    titratiorr
    vrith a
    prinrary
    silver
    ni trate solution.
    Coal,
    slag,
    and fly
    ash samples were analyzed:for
    the
    aforementioned
    elernents,,
    plus
    a'luminum
    (Al
    ),
    cobalt
    (Co),
    molybdenunr
    (Mo),
    phosphorus
    (|'>),
    an<J
    vanadiunr
    (V).
    Methods
    of
    analysis included neutron
    activatjon analysis,
    ncutron
    actjvationanaiys.iswithradjoche[}icalsc,parationforl|g,optjcalenission
    spectrochemical
    ana.lysis
    (both
    direct-rea<ling
    and
    photograph
    ic), aLonric
    -
    I
    I
    I
    t
    I
    I
    I
    I
    I
    I
    I
    I
    I
    T
    I
    I
    I
    ,l
    '
    :a-.
    :
    4.16
    t

    '.r
    l:'
    :'l
    o
    .i
    r
    I
    fr
    I
    f
    L
    -:
    a
    I
    I
    4
    +J
    {
    --
    t
    I
    t
    f"
    F.:
    ii.
    ,
    a:::
    ='
    i,
    ,l
    il
    .T
    B
    E
    &
    I
    o
    o
    C
    q
    o
    6
    t
    q
    =
    a5€
    og
    ir ,a
    UY'
    E1
    {E
    9t'
    rg
    co
    ig
    I
    t
    lit
    ''l
    tll
    '
    p.g
    .F
    =!rCt,/|{)
    l+-
    'F
    l,
    (r<
    :J
    I
    jJ
    o
    >rfJ
    F
    ta
    -.P
    P
    --EOrrOJ
    L.tJ
    (JL,ur:L
    C r.n
    L
    'n
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    ::
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    4.r7

    abSorption
    dnalysis
    (botlr
    f
    lame
    arrd
    qrafrhite
    f,irnacr
    anrJ i4-r
    rt,r
    f luirl.es(cn(.o;
    A <Jescription
    of eaclr
    jnsLrumcnL,
    not:nal
    opcraLing
    cgnriiLif;ri.,,
    arrrJ
    r-csL
    refel'ence
    mdterial
    s
    are
    c0nla irtecJ'.in
    Appen.Jir
    C
    of
    ,r
    rcporL
    liy
    p,ilclr
    aL ti
    I .
    (
    ters; .
    ,t'
    DATA
    AT{ALYSIS
    :
    During
    statistical:treatment
    of
    tiie
    chemical
    const'itucnt.
    data from
    the
    fiq-st
    year of
    the
    project,
    all
    concentration
    yalues
    less
    than the detection
    linriit,of
    the
    analytical
    instrunrent
    were disregartlecl
    (Smith
    and Ouda
    1979).
    Tlris,
    in
    ef
    f
    ecLi,
    :bi'aserl
    'the
    appropriate
    means
    in an
    upward
    rJi
    rect
    jon,,,'.on,nrrmes
    to,:
    unrealistic
    levels,
    During
    the
    second
    year
    of
    tlre
    investigation,
    values that
    were
    less
    than
    the'cletection
    linii,t'vler'e
    consitlered
    to
    be "0"
    (Anclerson
    et,lal,
    1980)',.
    Though
    more
    realistic
    than the former
    approach,
    this
    pr.oduced
    a bias
    in
    the
    downward
    direction.
    The
    present
    approaclr
    has
    been
    t,o
    set
    all values
    less
    than the detectiort
    linri'u
    equal
    [o one-half
    of
    the cJeLection
    lirlit.
    |^lher.e
    thc
    rnajority
    of
    the values
    for a
    particular
    element
    (such
    as
    Pb or
    Se) in
    a
    partic-
    ular
    set
    of sanples
    (such
    as
    gizzard
    sharl)
    are less
    than
    the detectjon
    limit
    of
    the
    instrument
    for
    that elemettt,
    the
    sarnple
    nrean would
    be r.epor-ted
    as
    less
    than
    the ,cle'tect'ion
    I
    jmi
    t-.',:
    ln such
    cases,
    Lhe
    hal f-detection
    I
    inri
    L', approach
    has
    "no
    relevance.
    Hovrever,
    it becomes
    important
    for
    statistical
    considerations
    in
    those
    cases
    where
    be'low-detection-.limi
    t values:.are
    reported
    for a
    few
    of
    the
    :
    total
    'nuntber
    of sample values for a
    'particular':elernent
    (such
    as Na
    in
    the ia'se
    of
    nacrophytes
    or
    tlg
    in
    the
    case
    of
    fish
    or
    macroplrybes),
    The third-year
    data
    have been calculate<i
    an<J
    statistjcally
    analyzetrusing
    the
    half-Jetection limit approach.
    In addition,
    t,he
    data for
    tlre firsL
    an<l
    second
    years
    have
    been
    recalculatecl and re-analyzed
    statistically
    using
    Lhe half-
    .
    detection
    t',
    '.
    I
    irnit approaclt.
    :
    These
    r-esul
    ts
    for
    the'
    inr.liv
    jclual
    years
    are
    llrc,senterl
    intabu,IarforrnintheAppendixorthisrepoi't(tables4.A-4.'V).
    A check of the
    first-year
    sedintent
    extraction
    rnethod
    jnclicaLecl
    that
    unriuly
    harsh
    con-rli,Ciohs
    prevai
    led''which
    tended.,to' destroy tlre
    integri
    ty
    of thc set'lirnent
    i
    itself':,rather thanim€ie1y desorb
    th;
    cations froiir
    the sedirnent'''parL'ic:le
    :,:
    ,
    .j
    :=
    T
    ,:1.
    I
    I
    I
    I
    T
    I
    I
    'l
    I
    'l
    i
    I
    I
    'l
    ,
    ',t.1,,1
    ,:.
    '
    :a
    ta:'
    :
    .r
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    I
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    ii. :,
    :..'
    ,'
    ,l',
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    :,
    -.-
    ,
    4
    .18

    ,:
    '""
    '
    :
    ,:
    ,:
    ::
    :
    surf
    aces.
    Fresh
    al
    lquots
    of
    'f
    irst-year
    5erJiilents
    were
    subjficled
    Lo
    Llrtl s+.
    digestion
    regirnen
    used
    for
    sediments
    frorn
    the
    iol
    lowinq
    twc
    years.
    The
    resul'ting
    rtat'a
    were
    ;;lculaterl
    antJ
    stat
    lstical
    ty
    analyzed
    ds
    pdrt
    af
    the
    f
    year'data
    and.are
    therefore
    inc luded'in
    the'rAppenrci
    x,
    as
    referred
    t0
    above
    (Iarrle
    4. A)
    .
    Al
    I statistica'l
    analyses
    and.comparisors
    of
    'Jata
    fot'
    the
    three
    years
    have heen
    carried
    out
    using
    starrdard
    analysis
    of variance
    packages
    available
    on the
    llniversity
    crf
    Il
    linois Cyber
    175
    comprrter.
    RiSULT
    S
    SED
    I MINTS
    Major'trer,,is
    in
    the
    concentrations
    or
    severdt
    chemical
    c0nstituents
    in Coifeen
    Lake
    sedimi.'nt
    occurred
    over
    the
    course
    of
    the
    3-year
    study.
    Eoth
    Ca
    anri
    lt
    exhibited
    significant
    increases
    in arrnual
    mean
    concentration
    during
    the
    3-year
    peniod,
    and
    Hg
    shcwed
    a
    sjgnificant
    rjecrease
    (Table
    4.3, Fiq.
    4.S).
    Sirnilar
    trends
    for
    these
    three
    elements
    were
    evident
    at the
    staLion
    level
    (Table
    4.4),
    Comparison
    of annudl
    mean
    concentrations
    aL incJjvidual
    stations
    indicated
    significant
    increases
    for
    Ca and
    l,lg
    at mosL
    stations
    and
    non-significant
    increases
    at
    the
    remaining
    stations.
    In
    the
    case
    of
    llg,
    three
    or
    ttle
    si*
    stations
    showed signif
    icant,
    decreases
    during
    the
    3-year^
    per:iod;
    the
    oilrer
    thr.€€
    also showed
    decreases,
    though
    not sjgnificartt.
    The'.annual
    rnean
    concentr,ation
    of
    one adrljtional
    element,
    Cd,
    decreased
    significantly
    at
    Stations
    I
    and
    Z between
    the
    first
    and
    second
    yeilrs
    of the
    stucly
    (Table
    4.4), but
    remained
    relatively
    constant
    at
    the
    other
    stations
    during the
    same
    perioO,
    ,
    :,
    There were significant
    changes
    in the
    station
    distribution
    of
    some
    of the
    chemical
    constituent.s
    in
    the
    lake sediment
    from
    vear to
    year,
    but
    none
    of the
    ionsfituents'showed
    progressive
    increasa,
    ort decreases
    jn
    concentratiorr fronr
    Station'I
    to'station
    4,(Appendix
    Tables
    4.A-.4.C).
    During
    the
    firsf:Jfear
    of
    the
    study, the
    concentrations
    ..
    of both
    cd and
    cu were
    significant'ly
    greater
    at
    Stations
    I
    and
    2 than at
    Stations
    3
    and
    4. The
    djfferences,in
    succceding
    years
    -},ere
    much
    less.marked.
    .For
    .all
    three
    years,,of
    the
    study, the
    concenlrations
    of
    '
    .4:'19
    ,.1
    .:
    .:
    -:.
    .,::..4,
    ':i.ia::.:::....,
    .

    e
    4,3. /vrntral
    meon
    conccnLrafiorts
    (m!/tQ
    rjr./ a11
    i.;hr_i
    of
    crren,i cal
    ''
    constiLuents
    in
    bottom
    sediment
    col
    lecteri
    lL
    ecf
    f
    cen
    Like
    f
    r+::r
    SeptembCr.
    l97B
    throrrglr
    0ecembtr igftr-j.
    iarii
    lr-'
    {lu;t,it
    i.,.
    rrr5
    1r-,,
    {
    n
    parentheses
    ,
    t.
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    I
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    r
    97S-79
    I
    979-80
    I
    -TTOT
    *:|]ur
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    980-Br
    i/re
    an
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    t
    A9
    As
    B
    8a
    Ca
    cd
    0r
    Cu
    Fe
    Hgc
    K
    l'lg
    Mn
    Na
    Ni
    Pb
    Se
    7-n
    7,58
    <0.80
    s.82
    I
    :32
    1 686.
    I
    .98
    o: 56
    B.38
    t?r.
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    34.
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    337,
    l 06.',
    I
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    :
    I .73
    <2,78
    .:
    <0.67
    23.7
    b
    <0.76
    ,
    B.B3'
    1.63
    ?.398.
    I
    .21
    <0.22
    2.41
    ?.97
    ,
    7
    4.3
    l6't.
    :488.
    ,405.
    ,
    :
    207 .
    '
    2 .05,,
    <0.
    90
    (0.68
    21.5
    ,
    b
    {.0.
    7B
    ,
    7.04
    I
    .00
    3??4.
    I
    .35
    ,.
    .
    i0.
    l6
    ,.
    6.08
    l!6,.:
    r.
    ,':'r-
    53.5
    ,
    i
    121.
    .
    61
    ].
    ,.1
    ,,.
    :
    '
    3r
    5,
    ?4?.
    .
    '_1.94
    :
    <0.70
    l
    .'{0.60
    l
    :
    24.5
    |,68
    t
    .l2
    267 8,.
    t
    .36
    4.77
    :
    23?.'.
    'r2,1
    :
    143.
    525.,
    330,
    ?r 5.
    'l
    .,96
    23.
    I
    2.8
    <il,
    "1.j
    ?LJ
    1.2
    1.4
    1,5
    -?1,-q
    .1.!_
    10.
    ?
    4.9
    1.5
    0.2
    T
    I
    l'
    T
    I
    .::
    I
    l'
    l'
    I
    I
    0,1
    t'
    ':.a
    '
    :
    "r:::
    i
    ,-
    '
    ,t'.,'
    ...',ll'
    rr,'.
    i;!;,,.
    .',:-
    :
    ::,.
    i.-i'.
    t-.-'
    '
    i!,'
    :
    .::.,....:::-
    *,,,,
    '-
    "t-
    tt.,,
    lir'i
    '
    '
    !ii',,
    ,,. ;,
    aValues
    that: are' underscor:ed
    .
    between
    years.
    DAt
    the time
    of
    analysis
    the
    measurement
    of this element.
    cConcentrations
    are
    in
    ug/kg
    indicate
    significant:
    differerrces
    (p<0.05)
    Instrument
    yJas
    not f
    unctiorring
    optimal ly
    dry weight.
    :
    ,
    ',i
    4,20
    ,:,.;
    f
    or'
    a.
    t: :-'.:'
    :,::'.,.
    ::
    . ;';':::.r
    tlr
    i=
    ,'I
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    .::

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    -
    l?1"
    ;;
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    Iltt
    g
    t23
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    ?
    tt
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    tl
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    Pondweed
    aq
    en
    n1
    xx><
    ra*l=r
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    i-l
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    IJ
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    siit
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    2
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    l?3
    Sediment
    Primrese
    |
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    2
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    Sediment
    Primrose
    rufl
    123
    Si
    zrard
    rha
    d
    L]
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    J
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    t-f
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    sh
    n
    -:..i.
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    caLfish
    l?1
    1-23
    Elaell Lar:gr-nouH:
    brr I
    I hea'1
    ba 1;
    r
    r^r
    ul
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    xxx
    li
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    fl_n
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    I2 3
    12 3
    i23:
    Gizzard
    Black
    Largc+nouth
    shad
    :
    hul
    ]lread Uass
    l
    E]
    333
    Carp Elue-
    Channel
    CIOC:}
    tr}(ftrn
    gill
    cdrfish
    dddd-{d
    x:<xxy,*,
    I,,,?,
    3,
    Pohdweed
    173
    BIact
    brr I
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    fti],
    t? 3
    Largemou
    th
    bass
    3.'
    3'
    Corp
    Blue-
    ,r
    q.iII
    1
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    '
    I
    ? 3
    Sedlrnent
    Pt'imrose
    .
    .1i!
    .itA
    llF-r-t-1__
    l2
    3
    123
    t?3
    Gizzard
    Blacl,
    Lar.gmrouth
    shod
    bu
    I I
    head
    lta ss
    cf
    {
    Carp
    4{
    ;
    JJ
    Bl ue-
    Cha.nnel
    qi
    I
    1
    catfish
    iFiiure,4.is.
    ',t,'
    ,
    ,-t.'.
    ,'
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    :
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    i:
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    ..-
    .
    .
    .
    ..:
    ..;,,.t--a,.
    ;'.,;.
    .,
    t
    Annual
    mean concentratlons
    (mg/kg
    fresh
    or dry
    weight)
    constltuents
    in
    samples collecteri
    at
    Coffeen
    Lake
    fram
    1978
    through Oecamber
    1980.
    (continucd)
    ..:
    of
    che,rnica I
    5eptember
    ...
    I
    t,
    ...a
    l
    .l
    .cl
    ^r
    i=::.:.
    ':'::'::
    .::-
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    '
    ,,
    f$(\cv
    xxx

    da
    tlnLhnnn
    l-,2
    3
    tlI
    2 3'
    Gizzard
    [}lact
    shad bu I
    'l
    head
    c.J
    x
    ll
    tl
    rt
    tl
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    ll'
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    r?3
    Pondweed
    CV GJ
    GJ
    xxx
    n
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    Pondweed
    3
    xxx
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    n
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    t23
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    mrose
    tr,
    rorf).
    xxx
    n
    tt
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    r 2 3,
    Primrose
    -?
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    -r-xx
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    (t)
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    ,123
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    bass
    r
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    nLrD
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    gill
    catfish
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    tn
    'xx
    a
    tt)
    x
    ml'f,fL',
    t23 t? 3
    tt-
    t?3
    Gizrard
    Black:Largonouth
    shad bul I head bass
    n
    lnl
    ,f
    J
    Carp
    "
    "'tn
    t'23
    L2 3'
    t23
    r,2
    3
    Sedimerrt
    Primrose Pondweed Gizzard
    shad
    n
    Llr== m==
    It-{r
    ,r,2,3
    t2
    3 123
    123
    Sediirnent
    Primrose
    Pondweed
    G
    i zzard
    shad
    r23
    Bl ack
    bul I head
    r-f-t-:f
    t23
    Largenrou
    th
    ba ss
    tf
    [-l
    ,
    3
    ,'3'
    Ul
    ue-
    Channe I
    gill
    catfish
    d'
    dJ
    t2 3, 12
    3
    3
    3
    3
    Blackl Largemouth Carp B'lue-
    Channel
    bul lhead
    :
    bass
    .
    gi
    1 I
    catfi sh
    a
    i:!
    :
    ::
    :
    j
    ::,...
    ..:
    j
    Ftgure.
    :a
    1
    ",::
    '
    :::-.r:.::
    4i5,
    Annual,
    man concentratlons
    (rng/kg
    fresh or
    dry weight). ..
    (continued)
    \.,,.,?
    3
    Sediment
    ro
    tr)
    io
    tx.!X:r.t<.
    4.?2

    f'l
    xxx.,
    fv1 fn :
    n
    il
    IIII
    tl
    n
    tl
    ttIt
    tf
    tt
    {l
    r--l
    r{l|
    |
    re3
    Bl ac!'.
    bu
    i t head
    *l
    t-
    I
    r
    LrilllL-llh
    ntil
    rt
    th
    lll
    :-
    ilL
    'oo1-LLJ
    L2
    3
    LLn
    123
    LjI
    123
    rrll
    t2
    3
    r-r-lt
    123
    m
    t2l
    r
    I
    n
    3
    Sediment
    Primrose
    Pondweed
    Gi
    znrd
    o,l,r,l.J.o
    ,urfl:T:rrn
    Carp
    rJl;
    qlqcn
    rt1rn
    Lr) rn!oir)
    xxxxxxxx>r.
    I
    h
    ::.
    '(t)'
    x,
    tl
    ll
    tl
    tl
    Il
    tl
    II
    I t,
    tl
    L_J
    anne
    tfi s
    xx
    .
    nn
    tttl
    il
    ttil
    rl
    tltt
    ilil
    LJ
    LJ
    33
    Carp
    Blue-
    Ch
    gill
    ca
    Sed imen
    t
    t{b
    r23
    Bl ack
    bu
    I
    I
    head
    T
    ?
    3
    La
    rgemou
    th
    bass
    r-1
    -
    rl
    l4
    t
    a
    J
    Largemou
    th
    ,
    bas
    s
    :
    -:
    r--1
    tl
    L--l
    {
    Channel
    catfi
    Sh
    tr
    EI,,
    3
    .3
    ..:,
    Blue-
    Channel
    gill
    catfish
    o
    s
    xxx
    @@
    ()o
    Mn
    123
    r23
    Sediment
    Primrose
    | 23
    Gi
    zzard
    s
    had
    tl
    3
    Carp
    *.
    1
    ,rrLt[
    123 t2 3
    Sediment Primrose
    t-Tlr
    nll n-r-l
    r2
    3 123
    Bl ack
    Largemou
    th
    bul
    lhead
    ,
    bass
    n
    3
    Ca
    rp
    l',,2 3
    I 2
    3
    Pondweed
    Gi
    zzard
    "
    .',
    l
    shad
    ,'.'.i
    ,
    ,
    .:
    I
    -
    ;,
    J
    Bl
    ue-
    gill
    tl
    LJ
    J.
    Charrne'l:'
    ca
    tfi sh
    :':
    '
    ''''1"
    :'
    :'r'tll
    '
    ::.:
    .
    :
    ':
    l?3
    .,t'.2
    3 123
    Primrose
    :
    :
    Pondweed Gi
    rzard
    sha
    d
    o(fo
    €@@
    xxx
    l--t
    tl
    tl
    lrn
    tl
    tl
    |
    2
    3
    Pondweed
    Annual
    , mean:cohcentiations
    (ms/kg
    f resh
    -.'r,'dryl
    weight) .
    . .
    (continued)
    -

    aa
    l=i-L,
    r*l
    ..
    't
    2
    3
    123
    Gi
    zzard
    Bl
    ack
    shad
    bu'l
    I
    head
    da
    I/,J
    L
    arg
    anou t
    h
    .
    [i455
    '
    E
    ,,',.
    i..:
    ,
    :l::
    JJ
    Blue-
    '
    Channel
    gi
    )
    1
    ''catfish
    u,it-
    gi11
    ca'tfish
    ;;*..,
    aa
    a
    3
    Ca
    rp
    I
    :
    t
    I
    I
    I
    I
    I
    I
    I
    I
    T
    I
    I
    I
    t
    l,
    I
    'l ?3
    Pr
    i
    mrose
    t?.3
    Pondweed
    123
    123
    123
    Sedinrent
    Primrose
    Pondweed
    Ln
    x
    I
    2 3
    I 2
    3 t'2,3
    Gi
    zzard
    tjl ack
    Largernouth
    shad
    bul
    I
    head . bass
    aa
    a
    | 2
    3,
    Primrose
    r--l
    tl
    I lu
    u
    Ll_--
    t23
    Primrose
    !
    aa
    123
    Gizzard
    shad
    a
    rll_
    t23
    Bl ack
    bul
    lhead
    Y
    {
    Channe
    I
    catfi
    sh
    a
    Carp
    ',L
    2
    3
    Sed
    i
    men t
    ,l'23
    Sediment
    r 23
    Pondweed
    I'Z.3
    Pondweed
    t23
    G i
    zzard
    '
    shad
    123
    Bl ack
    bu I
    I head
    7
    ..2
    '3
    Largemou
    th
    'bass
    ba ss
    tl
    LI
    ?
    Bl
    ue-
    gi
    1l
    |f,ilrttjn
    r{
    n
    I r{ L-
    _JL
    Li
    r--r
    Ll
    n
    IItl
    tl
    tl
    3:
    .'
    Channel
    catfi
    sh
    J
    Carp
    3
    Bl ue-
    silr
    fresh or
    dry weight)...
    (continued)
    :.:a::'a'.','.,
    a,a
    :':':
    .
    :. ::.'::
    '
    '
    _.'j..-
    .
    -1..
    :
    ,.a:.
    '!'.a:.
    aa
    C\l
    (\l
    xx

    Table
    4.4.
    Annugl.rnedn
    concentrdtions (rng/kg
    dry
    weight)
    of
    chemical
    ',
    .
    anci
    I'lary.Llltions
    at
    Cof
    f ecn
    Lake
    f rorn
    Septcrr,ber
    lgig
    rtrrougtr
    December
    J
    980.
    ,
    Stat
    ion
    I
    -Tg-/6--E---Ttrg-B--d---rqAn--ar=wr"
    A9
    As
    B
    Ba
    Ca
    cd
    Cr
    l,
    LU
    Fe
    Hgc
    t\
    .
    Mg
    i,ln
    Na
    Ni
    Pb
    :
    Se
    :
    Zn
    B.
    82
    '<0.80
    '
    :
    5.93
    :
    ,
    1.70
    2,225.
    2tzg
    4.44
    0.58
    ,
    8.93
    17
    2.
    I
    00.
    2r B.
    I
    BB.
    I 45.
    l.l7
    <2,78
    <0.67
    .:
    12"0
    b
    <0,76
    7.46
    1.40
    2,936.
    1.22
    <0,2?
    <0
    .46
    .
    42.8
    89.
    I
    79.0
    543.
    245.
    ll7.
    I
    .35
    <0.
    90
    ,
    <0.68
    ,
    14.7
    ,
    ..0
    <0.
    78
    3. B7
    .l
    .03
    :
    3,369.
    '0.27.
    .a
    <0.16
    (0.I2
    78.
    0
    43.9
    ::
    49.r
    ,
    540.
    208.
    .
    I
    43.
    0
    .0s
    <0.70
    <0.60
    5.23
    s.
    7l
    1
    .?9
    :l
    2,997
    ,
    'l'.00
    51,.
    B
    B4;1
    70.0
    487.
    220.
    )
    26.
    0.
    96
    10.3
    6;4
    3.5
    lt.0
    l4.q
    l.l
    43.
    I
    1.3
    2.4
    I
    '5
    1.1
    3.8
    3.6
    :I
    "':
    :t:::
    ::
    ,
    ;;'
    :::
    '::.a..
    ,.:
    ::.
    l':
    ,.
    i-:,
    :
    .t'i,,
    t"'
    ::::-
    .:::
    4.25

    a.
    t,
    -
    ,
    ',
    Table
    4.4.
    Annual
    mean
    concentratlons
    (rng/kg
    ciry
    weight)
    of
    chemical
    constituents
    ln
    lrott6rn
    ierJlment
    iol iecIed
    at
    four
    major
    and
    tno
    ancillary
    stations
    at Coffeen-iai.
    f rom
    sept'ember
    l97B
    throrgh
    Decernber^
    1980.
    (cont
    i.uecl
    )
    :
    Station
    I
    .5
    __-Td
    Ag
    As
    B
    ,Ba
    ,Ca
    ,cd
    ,Cr
    Cu
    ,l'Fe
    '
    Hgc
    K
    :
    'Mg
    .
    ,Mn
    :
    Na
    Ni
    ,,
    Pb
    Se
    .
    ''7n
    b
    '
    <0.76
    12.6
    :
    1 .48
    I
    ,99
    .4.
    l
    .0'l
    <0.?2
    3.7
    5
    l
    659.
    6r .l
    17 9.
    4l
    l.
    523.
    240.
    ?_.72
    <0.90
    <0.68
    23.8
    ,
    [:
    <0.78
    9.46
    :'
    0.7?
    3,261
    '
    ,
    2.16
    ,,
    (0.1,6
    .
    l.4s
    '
    72.8,
    ,
    , .ai-
    '
    57.7
    ,150. ,
    :
    693.
    .
    556.
    .
    ,321
    .
    ,'
    2.54
    <0.70
    (0.60
    .
    29.4
    I t.0
    .1.10
    2,628.
    I
    .58
    ?.59
    366.
    59.
    4
    r
    64.
    552.
    540.
    27s.
    2.63
    26.6
    1.3
    ,7.3
    ,"
    2.3
    0. B'
    ,l8.6,
    ',, 0,1
    |
    .2.
    ._i.
    143.
    0.04
    ',0.9
    0.0 5
    :T
    I
    T
    T
    I
    I
    I
    :-
    I
    ..
    I
    I
    0.2
    .4.26
    (
    cont
    inued
    )

    Table
    4.4.
    Annual
    mean
    concentrations (rnq/kg
    tlry
    welqht)
    of
    chernical
    constituents
    in
    bottom
    sedirnent
    iollicted at four major
    and twtr
    ancil
    lary
    stations
    at
    Cof
    f een
    Lake
    f rorn
    September
    l97B
    tnrr:Lrqtr
    Oecember
    1980.
    (continued)
    '-Tfm:/g---
    r
    9/9-U0
    I9BO-BI
    Stat
    ion
    2
    -Tedn
    -Fd
    Ag
    As
    B
    Ba
    Ca
    cd
    Cr
    Cu
    Fe
    Hgc
    K
    Mg
    Mn
    .,
    Na,
    Ni
    Pb
    Se
    Zn
    il.1
    <0.80
    4.
    9B
    0.99
    I
    ,1
    85.
    4.20
    0.67
    32.5
    397.
    I 20.
    I
    70.
    208.
    112.
    I
    60.
    3.58
    <2.78
    <0.67
    66.8
    b
    <0.
    /6
    I1.0
    I
    .49
    |,927.
    I
    .71
    <0.22
    4.74
    676.
    56.9
    17
    4.
    384.
    456.
    "
    20g.
    3.
    45
    <0.
    90
    <0.68
    36.0
    b
    <0,
    78
    8.53
    0.58
    2,7 7
    6.
    t.84
    <0.|6
    ?4.6
    531.
    59.2
    I
    69.
    606.
    5l
    6.
    299.
    3.24
    <0.70
    <0.60
    39. I
    a, 98
    1.03
    2,
    I 53.
    2.
    rB
    17
    .7
    569.
    69.4
    r
    it.
    447
    ,
    4?4.
    234.
    3.38
    0.7
    6.1
    4.0
    4.t
    2.7
    0.4
    l4.
    t
    0.03
    6.B
    la
    0.5
    0il
    r.3
    '
    ''
    '';
    'i,:.-'
    4.27
    42.4
    (
    cont i nued
    )

    :
    -
    '
    ..::.
    .
    ,:
    :r..=.:
    ,.
    a
    :
    .:1.:
    ,:.
    Tab'le
    4.4.
    l.t
    :.
    l:
    I
    &rnual
    mean
    concenfr.ations
    (mq/ke
    dry
    wejoht) of
    chemical
    const
    i
    tuents i
    n bottom
    ied
    iment
    do
    r
    i
    ectad
    ar
    four
    maJor
    and'two
    ancilrary
    staiions
    ar
    csffeen-ior,u
    f rom
    September
    t
    97B
    through-
    [hcernber
    lgB0.
    (ionr
    in,,e,f
    t
    I
    !
    l
    Ag,
    As
    $
    Ba
    r
    l.
    Ca
    cq,
    ..
    cF,
    ct
    Fel
    .:
    :
    Hgc
    K
    Mg.-
    Mni
    l{a.
    '.
    r{i
    b
    <0.76
    9.98
    1
    .09
    2,A53,
    I .79
    <0;22
    4.02
    222.
    68.0
    :
    162.
    522.
    762.
    236.
    ,
    2.55
    <0.
    90
    <0.68
    :
    33. 7
    .'
    <0.78
    B.03
    .
    '
    0.62
    ?,923.
    2.93
    ,
    <0.1
    6
    :
    .
    .
    9.85
    366.
    :
    50.0
    .
    :
    l39.
    .
    725.
    ..,
    438.
    _'1t,.1
    'i
    <0.70
    '.
    <0.60
    ,-
    60.9
    9.01
    0.
    85
    2,4BB.
    2.36
    .
    6.
    9l
    294.
    58.0,
    rf,t.
    624.
    600.
    2?4.,..
    3.34
    47,3
    3.8
    3.2
    'I
    1 r
    ;
    I
    t
    t
    t
    I
    I
    t
    I
    I
    I
    Pb
    Sel
    0.7
    0.9
    t.?
    3.t
    PJ
    l_9.0.
    0.04
    3.8
    '1In.
    3.3
    it]
    a.
    'a.'.:
    :
    (continued)
    ,,,
    '.,:
    l.+
    4.28

    i'"'
    '
    -
    "
    fr',,
    '
    ::
    Il:
    .
    .
    l
    I
    '::
    :::r.'
    :
    .,
    t.-:.:
    -
    ,,,,
    '
    .
    ,t'
    '
    j:r..:
    :
    :.
    :
    ::
    Table'4.4.
    Annual
    mean
    concentrations
    (rng/k
    g'dry
    weight)
    of chernical
    ."
    constituents
    in bottom
    sedimeit
    dollected'at
    four
    rnajor
    and lwo
    ,'
    ':
    dnci
    I lary
    stations
    at
    Cof
    feen
    Lake
    f
    rom
    Septernber
    lgiU
    th'"origh
    .:
    ,
    December
    1980.
    (continued)
    liJ_
    ,0.3
    9-r-1,
    1,.2
    l,
    I.r
    1,,
    ....:
    I
    !
    .
    '.:
    I,
    !:
    a:..
    I
    :..
    ,
    ,:'
    .
    I
    I:
    l,
    l,
    l:r'i:
    I,'
    -
    I
    I
    I
    :;l;'.:
    lr
    !'
    .-. ,i
    i
    r
    l',
    Stat,ion
    3
    -Tg/S.79.
    ]lff/9:r60'
    --
    an
    Ag-'
    As,
    B.
    Ba:'
    .
    c;.
    cd'-
    Cr
    ,r,
    ,
    Fe,,
    Hgc
    K,
    Mg'
    'I .
    lln.
    Na
    ,1
    Ni
    ,:
    Pb
    5"
    -.-
    Zn.:'
    3.
    B3
    0.95
    3.40
    0.93
    I
    ,560.
    0.96
    0.56
    <0.38
    34.0
    7l
    .5
    90.5
    562.
    79.
    B
    't05.
    I .20
    <2.78
    <0.6
    7
    l0.l
    'b
    <0.76
    5.7
    2
    I
    .00
    2,073,
    1
    .50
    '
    t<o.z?
    I
    .37
    l 4s.
    :
    73.3
    ,
    140.
    623.
    31 9.
    I 83.
    I
    .93
    ,.
    (0.90
    ,
    (0.68
    :
    '
    ,20;2
    b
    <0.78
    6,
    BB
    I
    .20
    2,978,
    0.i84
    <0.r6
    0.
    37
    :
    108.
    ,,
    50.
    I
    124.
    710.
    :
    l3l.
    257'.
    .:
    1.06
    <01
    70
    <0.60
    12.4
    5,
    81
    I,07
    2, 365.
    l.l3
    0,7
    4
    r
    ll.
    63.3
    1
    2s.
    649.
    201
    .
    1
    98.
    L44
    0.5
    0.5
    ).7
    2,3
    oq
    8.5
    3.6
    '2,f
    G.9
    4.29
    r
    5.3
    (
    cont i
    nued
    )

    Table
    4.4.
    Annual.meal
    concentrdt.ions
    (mg/kq
    dry we.ighti
    of chemical
    const'ltuents
    in
    bottom
    sr:diment
    col !ecLerJ
    at f
    our arajor
    and
    Lwo
    ancillary
    st-ations
    at
    coffeen
    Lake
    f
    roni
    scpiemuer
    lgi8 Lhrorrtrlr
    December
    I
    980.
    (cont
    i
    nue<J
    )
    I
    I
    t
    -.-l-q"ro':79
    Stat ion
    4
    t
    r 979-80
    t9urJ-81
    llle
    a n
    Fd
    I
    I
    I
    I
    T
    T
    I
    I
    ,A9
    As
    rl
    Ba
    Ca
    cd
    Cr
    Cu
    re
    Hgc
    K
    ,
    i',|9
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    S
    Theie
    H&s
    a
    significant
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    in
    annuaj
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    cOncrritfrrtions
    of'Lhc'
    maJoiity
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    present
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    based
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    coi'lected, data
    from
    the
    first
    year"of
    the'froject are disregarded, both
    B and
    lta
    show significant
    decreases in'
    :
    concentration in
    both
    species,
    and
    K a significant,decrease in
    pondweed,"
    during
    the
    reinaining
    two
    years.
    The
    only anornalous
    trend
    appears
    to
    be
    for K
    in waterprimrose.
    Snith',and Duda,:(1979) and
    Antierson
    ef
    al.
    (teeO1
    observed
    for
    the
    f
    irst
    and
    second
    years
    of
    the
    investigatjon,
    respectively,
    that
    the
    plant
    stems usually
    contain
    higher concentrations
    of elements than
    the'leaves
    (tatr'les
    4.8,'rnd
    4.9),
    Appendix Tables 4.D
    and 4.E),,,.In
    contrast, data
    forthe
    third
    year
    of the
    investigation
    show a fairly equal
    distribution
    of
    concerrtr<rtions of five
    ,
    etements
    between stems and leaves for
    both species;.the majority
    of
    the.
    remainingelementsoccurredinhigherconcentrationsinthe]eavescrfboth
    ,pq"i",(Tables4.Band4.9,AppendixTable4.F)...Thisclisparityofdis-
    thib'utions
    could
    ref.lect
    yearly
    technical tlifferences in
    the
    procetiure
    use-d
    fo'i
    separation
    of leaves
    and
    stens.
    Regardless of
    these
    "discrepancies,."
    16s
    present
    authors have
    elected
    to
    consider average
    values
    (representing
    the toLal
    plant)
    for
    the
    preparation
    of
    Fig-
    4.5.
    I
    Statistical
    comparison
    of concentrations of chemical consti
    tuents
    in
    plants
    ,
    _
    collected
    at
    different stations
    during
    the
    second'and
    third
    years
    of
    the
    study
    I
    indicated that
    the
    location
    (station)
    of
    the
    plants
    had
    little
    bearing
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    ,.1
    of the
    elemental
    concentrations
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    (there
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    I
    specimens
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    first
    year
    to
    warrant statistical
    ccmparison.)
    A
    '
    I
    few
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    I
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    3
    I
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    and Zn
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    -
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    stations.
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    1j=.1
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    ?1.0
    :'
    b.i
    o.oo4
    t8.5
    9.5
    atban
    and
    !value
    rere calculafed for.
    pars
    197F80 and
    l98CF8l
    only; Insutilclont
    numbars
    ol
    .
    samples rero ol
    lesied dur Ing 1978-79
    to idrront stet lsf lcal
    compar lson.
    bval,res
    that
    aro un,Jersorod
    Indlcoto
    slgnll lcant dlllerences
    (P<0.05)
    botrooq
    ./oars.
    tnt
    ttrtltl*
    of
    analysls
    the
    lnsiirment
    las'not functlon'lng opt-lmolly
    for
    rsasrrromnt
    ot thls
    e lensnt.
    O*"-"ir"t
    lons In
    €/kg
    f
    resh ro lght.
    1.41

    'l
    T
    I
    I
    ;i.,-..
    ..
    .
    ,,
    .
    i
    i
    l,
    l,
    ,l;t
    .
    ,.j
    statisticaliy
    signit'icant
    tJiffercrrces
    in
    clemenLol
    concentrations
    wer.c
    not.ed
    i,:
    for
    waterprimrose
    collected
    at dif
    f erent
    stations
    during
    the thir.rl
    year
    of Lire
    i
    ',
    s
    tudy.
    :
    ,
    at
    .,
    There
    were
    also
    a
    few
    exceptions
    for
    pondwee<!
    collected riuring
    tiot.h
    ilrc
    second
    .l
    and
    the
    third
    years (Appendix
    Tables
    4,1
    anrJ
    4.J).
    It should
    be
    stressed
    that
    ;
    no
    pondweed
    was found
    at
    Station
    I during
    any
    of
    the
    three
    years.
    Ccnnpared
    to
    :
    specimens
    collected
    at
    other stations,
    specimens
    collected
    at
    Station Z
    contained
    i,
    higher
    Cd concentrations
    in both
    stems
    and
    leaves
    during
    both
    years,
    higher Se
    .i'
    i'i.
    cottcentrations
    in
    the
    leaves
    during
    the
    second
    year,
    higher
    Cu,
    l4n,
    Ni,
    and Zn
    l'
    cottcentrations
    in
    both
    stems
    and
    leaves
    during
    the
    third
    year,
    and
    higher
    Ca
    i,..,,,,
    j.'
    concentrations
    in
    the
    leaves during
    the
    third
    year.'
    Leaves
    of
    pondvreed'collected
    tr.
    at Station
    3 during
    the second
    year
    contained
    higher
    Zn
    concentrat'ions
    than
    those
    Xl
    of
    pondweed
    collectecl
    at
    other
    stations.
    ii.
    ,i
    F.'.'.,
    FISH
    r-;
    ,,
    '
    .
    :
    ,t
    'l
    f..,,=
    ,
    '
    :
    :
    ii
    i'
    Three species
    of
    fish
    were
    collected
    cluring
    the
    first
    two
    years
    of
    the investi-
    i:...,..
    gation (table'4.2).
    An addjtional
    three
    species
    were
    collected
    duringlthe
    thjro
    it,
    i,',
    '
    collecting
    periods,
    and
    only
    one each
    at
    Stations
    2
    arrd
    3
    during
    the thircl
    year.
    i'
    I'han
    lengths
    and
    weights for
    the fishes
    collected
    during
    the
    individual
    years
    are
    l:;::..',,',:.t.,.
    presented.ih
    Appendix
    Tables
    4.K-4.1'1.
    Statistica'l
    cornpar.isons
    of
    fish
    sizes
    at
    ,.
    the
    four stations
    indicated
    that variation
    in
    size
    at the
    different
    stations
    in
    1..
    any of
    the
    years
    was
    generaily
    non-significant.
    Howeverr
    a
    co{nparjson
    of
    sjzes
    i,,
    during
    the entire
    3-year
    period
    showed
    sign'ificant
    increases
    in both
    weight
    and
    ii..;.,..,,,,
    lglgth of
    gizzird
    shad
    and black bullheads
    between
    the first
    and
    secondr
    years
    i,
    of
    collection and
    lesser increases
    for
    largemouth
    bass
    durjng
    this
    period
    l*t'
    (taute4,lo)-'
    .
    ,''',
    i'
    :
    i.':
    ,
    :
    il.,-,.
    Cunparisons
    of
    annual
    mean
    concentrations
    of
    chernical
    constituents
    in
    g.izzard
    $i..,r',.
    ,
    shad, black bullheads,
    and
    largemouth
    bass in
    Coffeen
    Lake
    over
    the
    3-year
    Fil'
    ,
    'period
    are
    presented
    in
    Tables 4.ll-4.13.
    Sirnilar
    comparisons
    for
    indjvidual
    fl11
    ..:
    istations
    in
    the
    lake
    are
    shown
    in
    Tables 4.14-4.16.
    A
    significant
    overall
    *:t.=
    '
    trend
    was noted for
    only one element,
    K.
    There
    was
    a
    significant
    increase.in
    f,!i'i
    F",::
    ',
    I
    T
    "1.
    ,',',
    :
    ,
    I
    -r
    :t,:
    ..
    :
    '-:l'
    t.
    :
    ::.
    1,
    :
    ,
    :.
    ,

    ;
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    L
    o)
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    al
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    +J
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    o
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    ()
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    16
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    ,
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    rF
    ':::
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    :
    '|!:.
    j
    1:]l
    .
    ai:
    Table
    4.1
    1, Annual
    mean
    concentrations
    (rnq/kg
    fresh
    it,
    constitugnts'
    in
    musCle
    tissrie:.of-gizzard
    ,
    ,
    !i
    .,
    quantities
    Cof feen
    t.ake
    are
    f
    rom
    in
    parentheses.
    Septernber
    l978
    {hrotrqh
    t issue)
    of
    chernical
    shatJ
    co I
    I
    ec
    Led
    at
    0ecember
    1980,
    5arnple
    l97B-79
    (
    33)
    1979,80
    (
    40)
    I
    980=Bl
    (
    40)
    Me
    an
    Fa
    'A9
    "As
    ,B
    :Ba:
    '
    Ca'
    :.:
    .cd
    Cr
    :
    LU
    FA
    Hgo
    i-,
    K.
    rMg
    .
    l4n
    ,Na
    .Ni
    Pb'
    $,
    ',
    Zn'
    <l 3.7
    (0;49
    ,
    .l,50
    0.42
    1,298.
    0.29
    0. 56
    0.66
    l6'.7
    54.1
    ,
    'l
    ,174.
    223.
    3:
    96
    5l 5.
    0.1 3
    0.24
    0.54
    <l
    .60
    <0.56
    0.56
    0,3'l
    I,235.
    '
    0.33
    <0.12
    :
    0.58
    l0;0
    :
    28.B
    4,09
    5.
    2l
    5.
    2.90
    ,7
    35.
    <0.t4
    (0.1,7
    , I
    "59
    :
    14.6
    <3.07
    <0.6
    3
    ,
    0.93
    0.39
    :
    I
    ,4
    36.
    0.09
    ,
    .0.51
    ,
    0.53
    ,
    1.I.
    2
    37.5
    16,923.'
    '.,'"n'
    3.03
    553.
    <0.1
    2
    <0:28
    ,1.54
    :'
    ,
    '5.90
    0.9i
    :
    :0'37
    |
    ,324,
    0.23
    0.37
    0.58
    12
    4
    34.7
    7,783,
    247.
    3.25
    6 35.,
    1 ,,27
    9.47
    (.t
    .
    t
    ---
    3.0
    .,J
    t2.B
    ?.6.7
    --:---l
    1.2
    7A
    3.6
    48
    5.
    40.
    B
    1
    ,l.q
    8.5
    t
    I
    l'.
    I
    l
    l'
    I
    l'
    I
    .:
    I
    aVaJ
    ues., that
    -
    are
    .
    between
    yeais.
    DConcentrat
    i ons
    underscored
    ilr€
    ,i
    o ug/kg
    indicate
    significant
    differences
    (p<0.05)
    fresh
    weight.
    4.44

    ti...
    .
    '
    .
    :.a
    Table
    4'
    12.
    Annual.
    me0n
    concentr'nt
    fons
    (mg/k9
    fresh
    I
    issue)
    oi
    chernical
    :
    constituents
    ln
    muscle
    t{ssue-of
    bldck
    bul lhead
    collect.ed
    ,:t
    !orf9'i1.Lake
    from
    Septemtrer
    lgTB through
    ftcembcr:
    lgB0, ra'.rrple
    quantiiles
    are
    ln
    parentheses,
    |
    978-79
    (
    t6)
    l9i9-80
    (
    20),
    I
    980-8t
    {12)
    i4e
    an
    Fa
    Aq
    :
    As
    B.
    <.|3.7
    <0.49
    I
    .80
    o:5
    3
    218.
    0,07
    1.03
    0.73
    10.2
    994.
    207.
    0.50
    61 3.
    0.16
    0.54
    0.36
    7.36
    <1.60
    <0.
    56
    I .20
    0,?l
    267.
    <0.04
    0.34
    .
    0.70,
    ::
    8.45
    38.
    5
    2.,757,
    164.
    ,
    ,
    I,00,
    568.
    ,i
    <0.1
    4
    r
    0.40
    0.38
    :
    l
    t.0
    <3.0i
    <0.5
    3
    ,
    ?..
    ?l
    '
    0.44
    228,
    (0.09
    ]
    .
    0.36
    '
    0.29
    6.04
    B?.6
    .l4,354.
    235.
    1
    0.61
    :
    ,'.700.
    .<0.14
    ,
    <0,28
    ,<0,29
    ' '
    '6.46
    1.65
    ,
    0.40
    ?41 ,
    Ba
    Cu
    cd
    Cr
    Cu
    Fe
    Hgb
    (:,
    .
    t'l9
    Mn
    Na.
    Ni
    Pb
    Se
    7.n'
    3.6
    3.5
    0.4
    I
    ,
    0.57
    l
    0,60
    .
    , 8.43
    50.4
    ::
    5,069:
    I
    96.
    0.7 4
    6r 6.
    19.4
    1.6
    l.l'
    4.2
    f19,
    ''
    6.5"
    2,8,'
    q.u
    2.7
    0.3.
    6.5
    0.37
    0.35
    8.6
    5
    .
    between
    years.
    lffi.re6.out=...
    bconcentritions
    ulg
    in
    gglts
    fresh
    wcight;
    rnissing
    value
    =
    sarnple
    quantities
    insufficient-foi
    analysis.
    "
    'r -
    .

    I:ri:
    I
    Iallle
    4.13.
    futnual
    mean
    concentrat ions (rng/kg
    I
    '
    :
    .
    constituents
    Coffeen
    Lakc
    from,Saptember
    in
    muscle
    tissue-of-
    lgZB
    ,quantities
    are
    ln
    parentheses.
    fr-esh
    Lissuci
    of
    chernical
    large,nouth
    bass
    collecteC at
    thrcugh
    {hcember
    1980.
    Senp )c
    t97B-79
    (so1
    I 979-B0
    (
    40)
    I
    980-Bl
    (
    40)
    l1e
    on
    r'
    Aq
    As
    '
    <i
    3.7
    <0.49
    I .6t
    0,13
    260.
    0.17
    0.49
    :
    0.7
    5
    ,
    2:.|3
    5l ;0
    I
    ,1
    25.
    267.
    0.30
    523.
    '
    a.23
    0.77
    1.89
    6.1B
    <t.60
    <0.56
    4.6
    3
    0.01
    :'
    l4l.
    <0.04
    <0.1
    2
    0.
    r
    3
    3.
    l9
    3t .9
    4
    ,
    368.
    240.
    0.75
    417.
    <0.1
    3
    <0.1
    7
    l.84
    8.,50
    <3.07
    <0.6
    3
    0.55
    0.05
    J(q.
    <0.09
    0.60
    0.32
    2,36
    23.1
    17,?-3,g.
    293.
    0.57
    438.
    <0.12
    <0.?-7
    I .38
    5.47
    2,21
    0.07
    243.
    0.08
    0.39
    0.42
    2. s3
    36.5
    7,08.|.
    267
    ,
    0.52
    464.
    7t-a
    ?.0
    1l.Q
    5.4
    17.2
    -
    5.1
    ?-.6
    1
    5.8
    I9r
    ,
    28.3
    2,?
    20.
    B
    'l
    :l
    .:
    ,l
    l.
    .
    'l'
    ,1,
    ':!
    t:
    :l
    l
    I,
    I
    1,.
    'l-
    t'
    ''
    J'
    B
    Ba
    Ca
    Cd
    Cr
    Cu
    Fe
    Hgb
    K
    14g
    Mn
    Na
    Ni
    Pb
    Se
    Zn
    0.37
    t.72
    6.68
    il.5
    Lq
    r
    9.0
    aValues
    that
    are
    underscored
    .
    between
    years.
    DConcentrations
    are in
    ug/kg
    ::
    ,..;
    , ,
    -a
    indicate
    signif
    icant'differences
    (!<
    0.05)
    fresh
    weight.:
    ::'

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    =r
    i-.:
    r.l
    ,.t
    t'
    jiI
    at..
    :::!
    i:i
    ,
    K concentt'ation
    in,, ul
    I
    t,hree
    'specie.s
    during
    the
    3-year'
    periocl;
    this overall
    inctnase
    was a
    ref
    lection
    of tha
    increase
    0t
    caeh
    of
    the
    incliyi<lu,rl st.rt
    iLrr*s.
    eonsiden'in9.the
    species,of
    f
    ish
    inclividual
    ly, thcrc
    are
    severai
    elemental
    coli-
    tentration
    trends. In
    gizzard
    shad
    {Tables
    4.
    }'l
    and',4.14)', theie
    were
    signif
    i-
    .
    cant
    :
    .
    decreases
    .:
    :
    in
    the overall
    :
    :
    concentrations
    of B, fe,
    and l{g between
    the
    first
    and
    second
    years
    of
    the'stud),.
    The
    rjecrease
    inl [J
    concentratiorr
    wds e'/ident
    at
    each of the
    four
    stations;
    the
    level of
    Fe
    was
    decreased
    only
    af stations
    I
    and
    2,,
    and
    that 0f Hg
    at
    Stations
    i; 3,
    and
    4.
    In
    addition,
    although not
    sevbre,enough
    to
    affect
    their-overall levels
    during lhis
    same
    periocl,
    the
    con-
    centrations of Cd, Cr, and
    Cu
    in
    gizzard
    shad
    decreased
    at Station 2, Statiorrs
    3
    and 4, and,
    Stations
    I and 2, respectively.
    In con,trdst,:
    during
    this
    sante
    :
    period
    (between
    the first and seconrJ
    years),
    the concentration
    of
    Se
    in
    gizrard
    shad
    increased
    at all four
    stations, significantly at Stations I
    and 2
    and
    non-significantly
    at
    the
    other
    two.
    The
    single' overal I
    concentration
    ,
    trend
    .(decrease)
    noted
    in
    gizzard
    shad between,:ihe second and third
    yeal's
    occurred
    in
    ,the
    case of'Cdi
    the'location:contributinq nost
    notably to the overall'concen-
    tration
    decrease was
    Station'1.
    There
    were
    significant
    changes
    in
    the
    station
    distributions of some
    of
    the chemical
    constituents
    in
    gizzard
    shad
    from
    year
    ro
    year
    (Appenorx.,Tables
    4.N-4.P).
    The
    elgnents showing
    progressive
    decreases
    in
    concentration fronr
    Station
    1
    to Station
    4 were
    prinrarily
    those referred t,o
    above.
    Concentration trencls
    in the case
    of black,bullheacJs
    (Tabies,4.12
    and
    4.i5)
    ,'
    are sonpwhat
    difficult
    to
    assess,
    since these fish
    were
    not available
    at
    ,station
    l
    (the
    heated
    station)
    during
    the firs't'and
    third
    years.'
    0nly'Cr
    showed
    a significant
    decrease in
    overal'l
    concentration
    between
    the
    first and
    second:
    years,,and
    this
    decrease tllas evident
    at each of
    tlre three stations
    (?-,,3,
    .'
    and 4).
    Hg
    registered
    a signifjcant
    overall
    concentration increase between
    '
    ,ihe
    second
    and third
    years,
    and
    th'is
    inorease was
    primarily
    a
    reflection of,.
    '
    the
    increases
    ..:
    .:.
    at Stations
    2
    and 3. Thcrgh not sufficient to
    affect
    the
    overal'l
    'eoncentrations
    of"these'elements,
    Ba,
    Ca, and Na increased
    in concentfation
    at
    Stations
    2 and
    3 during the
    three
    years.
    The differences
    in
    elernental concerr-
    ::::
    L
    'lrritions
    between:s'tations
    for' individual
    years'are presenled
    in Appendix
    Tables
    ,l:
    .'
    ..
    '.':
    4.0-
    4. S .
    :::
    ''..
    ,
    j:.
    -."
    ,,,
    ,:i
    ':
    '.
    ,.
    :'
    '
    :
    ,
    .:
    =
    4
    .53

    T=
    ':::.
    l
    :
    ,
    :
    ,
    ,'-,
    ,
    l,
    In
    largc.rnoulh
    bass
    (Tables
    4,13
    and
    4,16),
    tlre
    overal I conccntration
    of'
    lig
    .:',
    ..
    :
    '
    decreased
    significantly
    during
    the three
    years,
    a
    reflection
    of the
    decrr:ased
    levels at Stations I and 2 during
    these
    years.
    There
    rrel:e
    significant
    de-
    creases
    in
    the
    overall
    levels of
    Cu,
    lla,
    and Pb
    between
    l"hc
    fjrsL a')d second
    years;
    Stations
    3 and
    4 were
    the
    prinrary
    locations
    of the
    decreasetJ concen-
    trations
    of'the
    three elements,
    The
    overall
    concehtr.ation
    of Se decreased
    significantly between
    the second
    and
    thipfl.:years;'this was
    probably
    a
    reflec-
    tioh,'of
    the decreased levels
    at Stations
    3.and 4 between these
    years,
    Se
    was
    one'of
    the,few elernents
    in'larganouth
    bass'that
    showed d
    progressive
    decrease
    in,concentration
    frun
    Station
    I to.Station 4
    (Appendix
    Tables
    4.T-4.V):
    ',,,
    '
    .
    '.'
    .:
    i
    The
    main
    cunparisons
    to
    be
    made
    foi
    carp,
    b'luegill.s, anti
    channel
    catfish,
    since
    they
    were collected only during
    the.third
    year
    of the study,
    are
    .''''
    between-station
    cornparisons
    of elernental
    concentrations
    (Tables
    4.17-4,Ig).
    There
    was
    no significant difference between stations for most
    of
    the
    elements. 0f the
    feu
    exceptions,
    I
    and
    Se,.'general]y decreased
    in concen-
    ::
    ,
    ,'.
    .
    ..,
    ....-
    ,
    t
    :.
    ,
    :
    tration
    proqressively
    from Station I to Station
    4;
    this
    trend
    occurred
    for"al I three
    species. There
    was
    no appaient trend
    for
    'rlg
    concentrati
    on:,ljn
    !t.
    :
    any,.of the
    species, although
    the
    differences
    between stations
    in
    the case
    of
    carp
    and
    bluegills
    were fairly large.
    I
    l
    I
    l.
    I
    ::
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    ':
    l.
    ..
    :::
    ,:,
    :
    ..::
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    :
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    jI'
    't
    l'
    ''
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    l
    l=
    l'
    t",-.:
    f'
    ',:'t.,..
    l=
    :-
    ;:--
    '}
    .
    .:::
    a::"::
    .:::::
    .:
    4.54

    :::.::
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    c
    i tuents
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    .
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    2,
    2.
    l.l
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    1.0
    4{
    4.0
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    1.3
    0.2
    3,5.
    0.2
    I.
    aValues
    that,are
    underscored
    between
    stations.
    bConcentrations
    are in
    ug/kg
    indicate
    significant
    differences (p<0.05)
    r
    resn
    wel
    gnt
    .
    .
    i.
    4.
    55

    iir
    ':
    ,,.
    ;:1.,
    .,,;..,
    '
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    i;,;":,'
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    .
    .
    Tab.le,.4.lB,
    l"lean
    concentrat,i'ons
    {mq/kg
    fresh
    in
    bluegill
    co'l'lected
    at iarious
    r
    980-Bl
    .
    tissus)
    of
    chernical constituenis
    statiorrs
    at
    Coffeen Lake
    in
    Stat
    lon
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    at ion
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    lon
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    Ag.'r
    <3.07
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    <0.63
    3
    '-
    ,
    5,7?
    Ba
    :
    0.10
    Ca
    ,'
    '
    922,
    cd
    -,,-
    <0.09
    cr
    ,'
    '
    0.47
    '.t:
    Cu
    0.24
    Fe'
    ,
    3.78
    i
    Hgb
    .
    35.0
    K
    ,,,.
    15,277.
    Mq
    279.
    ','t.
    .
    '''
    Mn''.'
    1.06
    Na
    :
    .
    737.
    Ni
    .
    <0.1 2
    .:
    Pb:.':r.
    '
    <0.?_7
    Se,.
    .
    1..
    .'.
    .
    i
    I.38
    ...
    2n;,;. ,
    ,;
    8.22
    <3.,07
    <0.63
    5.37
    0.12
    956,
    :
    <0.09
    0.50
    0.3?
    3,4?
    74.3.
    l5,BB4.
    ,,
    286.
    l.14
    772.
    <0.12
    :
    <0,27
    :
    I .37
    9.'83
    <3.04
    <0.63
    5.12
    0.06
    BBO.
    ,
    <0.09
    0.35
    0.r0
    4. 96
    I
    02.
    t
    3,09/.
    241
    ,
    0. 75
    782.
    <0.1
    2
    <0.27
    1.42
    9.49
    <3.07
    <0.63
    5.24
    .
    0,16
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    0.10
    0,:34
    0,13
    :
    3.'90
    72.9
    .
    | 2,427 .,'
    ,
    238.,
    .0.'93'
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    :
    ::
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    '
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    . a,
    -'
    0,6?
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    ?0
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    9s5.
    20
    '20
    0.42
    20
    0.20
    20
    4.0r
    20
    6?..
    |
    2A
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    20
    261.
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    20
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    20
    9.05 20
    6.I
    t.J
    I
    I
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    t
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    :
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    :
    3.9
    0.4,
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    '4
    .4
    :-:::
    s.1
    0.4
    '0.'3
    .afalues
    that^
    are underscored
    ind'icate
    signi
    f
    icant dif
    ferences
    ($0.05)
    between
    stations.
    bConcentrations
    are
    in
    uglkg fresh
    weight.
    I
    l'
    l
    .:l
    :
    4. 56
    i:,:t):;i,:.::
    .a
    :

    Tabl
    e
    4.
    :..'
    |
    9. Hean
    i n
    channel
    concentr
    c af'f
    at
    .i
    i
    on
    sh
    s
    .::
    ,
    in
    l9B0-Bl.
    ,'
    (nq/fq,
    fresh
    Lirsue)
    col lected at
    var''ioirs
    of
    ch*oical
    constituentE
    slaLlons at Coffeen
    Lake
    Station'l
    Statlon
    2
    5t
    at ion
    3
    St
    at
    ion
    4
    Mean
    t-t
    Ag
    As
    cd
    .
    0.12
    <3.
    07
    (0.6
    3
    ,
    5.43
    0. 21
    I
    60.
    ,
    0.69
    0.
    s0
    ,
    5.09
    .
    14.7
    I
    8,770.
    ?.76.
    ,0.49
    658.
    0.14
    <0.27,
    0.9?
    10.2
    '
    <3.07
    '<0.63
    4.71
    0.05
    ,
    136.
    ,,
    <0.09
    0.44
    ',
    0.34
    6.63-
    .
    30.2'
    ,
    I 6,1 45.
    ..
    232.
    '
    o.52
    631
    .
    ,
    <0.1
    2
    <0.27
    ,
    0.98
    .
    7.31
    ,,
    ,
    (3.04
    ,
    <0.63
    ,,
    4,76
    0.
    t6
    ',282.
    .
    0.
    r0
    0.59
    :
    0.47
    '.
    -:
    .
    10.r.
    '
    35.4
    '
    I
    5,850.
    221.
    ,
    '
    0.51
    61
    0.
    .t
    : :
    0.14
    '
    <0.27
    0.
    70
    .rr 7.
    40
    .
    <3.07
    ,
    ,0.6,3
    4.67
    ,
    0.r0
    16
    3.
    ,
    (0.09
    ,
    0.57
    0.37
    ''
    25.4
    I
    6,891 .
    '
    zil.
    0.34
    ,802.
    <0..l
    2
    ,',
    <0,27
    0.59
    '
    7.39
    ti
    LV
    :
    20
    5.t
    4 2A
    I
    0. 13
    20
    '
    185.
    ,.,
    2A
    2A
    LV
    '
    0.58
    20
    0.42 ?0
    6.67
    20
    ,
    26.9
    2A
    I 6,194.
    20
    235. ?-0
    :
    4.47 20
    675.
    20
    0.1 2
    20'
    2A
    0.80 ?0
    .
    B.0B
    2A
    Ba
    Ca
    Cr
    UU
    Fe.
    Hgb
    K,
    Mg
    Mn
    ',
    N;.
    Ni
    Pb
    Se
    7n'
    9:'5
    l;B
    l?
    2.?
    ,
    0.6
    0,8
    0.5
    .t.
    2.8
    l-9-
    0.9
    4:l
    =:_
    0,4
    :
    2..5
    3,7
    aValues,that
    are underscored
    between stations.
    bConcentrations
    are in ug/kg
    iindicate
    signif
    icant differences
    ($O.OS;
    :"
    fresh
    wei
    ght
    .
    4.57
    :
    -
    t.
    :
    .:l:
    .
    j
    .:,i;l:,=;;;..:.r;,-:
    .
    r.'-,.:..,.,

    :,'.
    ,'
    ,:;.t'rti:
    :.:
    .:
    0tscrJSSt0H
    t-.
    ,,1.
    ,1.
    Two
    of
    the
    questions
    addressed
    in
    the
    second-year
    repot't
    (Andar.son
    eL
    dl,
    lg{iO)
    are
    applicable
    to the
    final
    report. First,
    did
    the
    concentrat.ions
    oi
    any
    of
    the
    chemical
    constituents
    in
    the
    lake's
    ecosystenr
    increase
    or decreasc durinq
    ',
    the
    J-year
    period?
    Second, are
    any
    of
    the
    constituents
    present
    in sufficientiy
    :
    ,high'concentration
    to be
    environrnentally
    damaging,
    to contaminate
    fish,
    or
    to
    'pose,
    a
    human
    heal th
    problem?
    l'li tli
    regard
    to
    the f irst
    question,
    the
    changes
    in
    concentration
    of
    chem'ical
    'constituents
    over
    the 3-year
    period
    are rlepicted
    in Fig.
    4.5. The
    levels
    of
    the constituents
    in
    the various
    types
    of
    samples analyzed
    (setliments,
    two
    species
    of
    plants,
    and
    six species
    of
    fish) were
    quite
    variable. Five
    clements
    '(Cd,
    cr,iCu,
    Hg, and
    Ni) showed moderate
    to strong
    decreasing
    concentration
    trends
    in most
    components
    of
    the lake's
    ecosysten
    during
    the 3-year
    period.
    Three
    of these
    elements,
    Cd,
    Cr,
    and
    Hg, are
    recognized
    environmental
    contanri-
    nants
    (they
    appear
    on the U.S.
    Environmen'tal"Protection
    Agency's
    ljst
    of
    :priority
    polJutants;
    callahan
    et al.'1979);
    therefore, any
    reductjon
    in their
    concentrations
    points
    toward
    effective
    c)ean-up
    procedures.
    0rr
    the other
    hand,
    ',the"concentration
    of one
    element,
    K,
    increased
    inlalI
    .samples
    except
    sedjment
    duringthesameperiod.Pbconcentrationswerebelowthedetectionlirnitof..
    the analytical
    instrument
    for
    most
    of the
    samples;
    the
    detection
    l.imit
    varies
    with the
    type of sample
    being
    analyzed.
    ,
    ..
    :
    ,Equal'ly
    impor:tant
    in answering
    :th"
    first'question'.is
    the
    trend
    in
    concentrations
    oi chemical constituents
    from Station
    1 to Station
    4.
    Since
    the discharge
    from
    .'theslag.and..flyashpondswasa]lowedtodra.inintothelake.nearStation1.
    :,.during
    the
    period',which
    ended
    vrith the completion
    of
    the fjrst
    year
    of
    this study,
    l,'it
    seemed likely
    that
    contponents
    of
    the
    lake's
    ecosysten at
    this station
    would
    contain
    higher
    concentrations
    of
    some, if
    not all,
    chemical
    constituents
    than
    ecosystem components
    elsewhere
    jn
    the
    lake.
    Only a few
    constituents
    showed
    con-
    'icentration
    trends,
    andl'these
    trends were
    quite
    variable in rnagnitude.
    During
    the
    first
    year,
    Cd and Cu
    concentrations
    in
    sedinpnt and
    gizzard
    shad
    clecreased
    .fron
    the cooling'loop-to the arnbient
    area.
    The fact
    that
    the same.trend
    occurred
    in shad
    as in sediment is not
    surprising,
    since
    this fish
    is
    a forage
    fish.
    .-- 4.
    58
    :
    :l:
    i:-
    T
    l,
    t
    T
    'a
    t
    T
    I
    t
    I
    t
    I
    I
    I
    T
    T
    :'
    r
    :
    :l

    Some
    additional
    decreasing
    Lrentls flon
    SLation
    I
    to StoLion
    /r
    riere noLed
    tluring
    the
    thiid
    year:tB,
    Cd, and
    l{g
    in
    se<ilnent
    cores;
    So
    in
    largemouth bass, bltie-
    gills,
    and
    channel
    cat.fish;
    and
    K
    in
    carp, l:lucgiljs, and
    charinel catfish.
    t{hy
    sotne
    of these
    trenrls
    showed up
    as late
    o's the
    fhird
    Tear
    is
    iruze'ling',
    since
    the'conditions
    to enhance
    lake ecosystem
    quality
    were
    implementetJ
    jlrnost
    trro
    yearS
    earlier.
    However,
    in
    the
    case cf
    sedi:!1ent
    cores,
    the
    layers
    (referred
    to
    ds segments
    in the
    present
    report)
    of
    sediment
    were
    laid down
    during the whole
    period
    of
    evolutjon of
    the
    lake. l{evertheless,
    the
    greatest
    increases in
    con-
    centration
    of
    the three
    constituents
    in
    qucstion
    occurred in
    the upper
    one 0r
    two
    segments,
    representing
    recent
    deposits.
    !,lhen
    one
    consjders that the ldke
    is a
    relative)y
    deep impoundment
    and
    therefore sedjments
    nray not be subject
    to
    wind and utave
    action
    to the
    extent
    found
    in
    a
    shallower lake,
    it is
    possible
    ;egments
    represent
    more
    than
    just
    the
    rnost
    recent
    year
    0r two.
    Several
    other
    factors contributed
    to the
    lack of sufficient
    trend
    evidence
    betleen
    the
    first and
    second
    years
    and
    between
    Stations
    I and
    4. Too
    few macro-
    phyte
    samples
    were
    collected during
    ttre iirst
    year,
    a
    iritical
    year
    jn
    the
    'ibefore-after"
    evaluation
    of
    the r,raste
    disposal
    inrproventents,
    for
    valid statis-
    tical
    comparison
    with
    samples
    collected during
    subsequent
    years.
    ilo
    Arnerican
    pondweed
    was found at Station
    l
    during
    any
    of the.yea)'s, and
    no black
    bullheads
    durring
    the first and
    thjrd
    years,
    naking
    it impossible
    to
    determine
    what
    effect
    this
    station nright
    have had on the
    chernical
    constituent
    concentrations of
    these
    two ecosystem
    components.
    Based on
    the frndings
    of Mayes
    et
    al.
    (1972)
    and
    l'ludroch
    and
    Capobianco
    (1979),
    we
    might
    expect
    to have found
    that
    the concentra-
    tion
    trends between stations evident
    in
    the'sediments
    cluring
    the fjrst
    year
    were
    reflected
    in
    the macrophytes.
    Considering
    the
    general
    decreasing concentration
    trends
    in the various
    com-
    ponents
    of the lake's ecosystem over
    the 3-year
    period,
    an adjunct
    to
    the
    first'question.is: l,lhere
    did these:elentents
    go?
    The outflow
    fronr
    the lake
    'is
    nonnally'not
    very:1arge'and
    probably,would
    not
    account
    for
    the apparent
    decrease
    in
    elenentall concentrations. However', tltu
    flood
    concli tions
    that
    w'ere
    prevalcnt
    in
    the'spring
    of tgZg
    (see
    Section.3) resulted
    in
    dilution
    of the
    elenents-dii-
    '
    9ol.ved,
    in'th.e lake
    water.
    Subsequent discharge of
    the'excess
    volume.of
    water
    oveithe.spil]wayin.effeitdepletedihe.]akeof:aiign.ificantquantityofits
    :i-
    :

    I
    ihenrical
    constituents.
    tn
    [ur-n,
    the uptak,e
    of these cner*ical const
    j
    tuents hry
    _
    I
    other
    components
    of the
    laLe's
    ecosystem
    was
    reduced.
    I
    There
    are
    at
    least two
    other factors
    that
    may
    have
    contributer! to the
    decr.easing
    trends.
    Thus
    far,
    r.ro
    yearly
    measurements
    have been
    conrJucted
    on ihe standing
    crop of
    macrophytes
    in
    the
    lake.
    l,lhile
    the elsnenf.al
    concentrations in these
    plants
    have decrease<i
    from
    year
    to
    year,
    it is
    possible
    that the total biomass
    of
    the
    plants
    may
    have increased
    during
    the same
    period.
    Distribution
    of
    a
    constant
    guantity
    of elements
    within
    the
    increased
    bicrnass
    vtould
    result
    in
    an
    apparent
    decrease
    in
    concentration
    of the
    elements.
    Another
    alternative
    might
    involve
    the number.
    of fishes
    taken
    by fishennen.
    Al-
    though
    the
    lake
    js
    c'tosed
    to
    public
    fishing,
    a large number
    of
    "trespassing''
    fishermen
    avail
    ihemselves
    of the opportunity
    in
    any
    given
    season.
    If
    large
    quantities
    of
    fish are
    taken from
    the lake, and
    if
    there is a
    reduction in
    the
    quantities
    of
    chemical constituents
    being added
    to
    the'lake's
    ecosystenr
    (by
    virLue of
    the recent modifications
    of
    discharge
    disposol at
    the
    power
    plant),
    there would be
    a
    gradual
    reductiort
    in
    elemental
    concentrations
    in
    the
    fishes,
    especiall;,as
    nelv
    crops
    of
    fishes
    appear.
    , The answer
    to the
    second
    question
    can
    be
    approached
    by considering
    the
    concentra-
    tions of chemical
    constituents
    that sometimes
    accumulate
    to undesirable levels
    in
    aquatic
    ecosystems;
    these
    include
    cd,
    cr, Hg, Pb,
    and se,
    As nrentioned
    above,
    Pb
    concentrations
    were below
    the
    detection
    limit
    of
    the
    analytical
    instrument
    for
    most
    of
    the
    samples. 0f
    the four ecosysten
    components
    showing nreasurable
    Pb
    con-
    centratjons during
    the
    first
    year (pondweed,
    gizzard
    shad, black
    bullheads,
    and
    largemouth bass),
    on'ly the bullheads
    contained
    measurable
    concerrtrations
    during
    of
    the ecosystem
    components
    contajnect
    measur-
    ahr. levels of Pb during
    the
    final
    year
    of
    the investigatior,
    n
    gratifying
    ,
    findin^g
    when improvement
    in'enviionmental
    quality
    is
    the
    aim.,
    .
    ..rAtchiion
    et
    al.
    (1977)
    and
    Murphy'et al.
    (lgi8)
    have
    pointed
    out
    that fishes
    in.
    :ecosystems
    contaminated
    with
    high levels of
    Cd and Zn take
    up substantially
    lhigher
    quantities
    of,,these
    elements than
    do
    fishes'in
    uncontanrinated
    ecosystens.
    They
    conclude
    that the relative
    levels of
    these elements
    in fishes
    correlate
    I
    t
    I
    :i
    t
    I
    I
    I
    I
    :
    I
    t
    I
    I
    I
    ,
    t
    :l:
    j
    ,,::
    r:
    ::
    r
    :
    ,.1:
    .:'....-
    :.:.:,:
    ::.
    1.'a
    tt.it;.'
    ):
    ;
    i':
    ':,:,:,
    ,'
    r',
    :','
    :'-:li::.:
    :.
    .::
    ]
    z:i.:.,a,
    ,,,.:'.
    i;,
    ;,':.'
    ir::
    ll;:..:...
    '1.'t::
    .
    t:,
    :-
    '
    :::,
    .,-,
    :;'.;;:';::
    :-1:,..
    i;,,a::r..l
    :
    vil:,::
    :
    !i,:,'..,.
    7t.:'.',,'
    ;:a:
    -
    a:.
    -
    i.'1,;:
    i
    i.:1::t
    -
    ;a,:
    :.
    ;..'
    !:..,
    ..
    :
    i,:,:
    .'
    ':,'
    t
    :;1::1.,,
    !'::
    ::::.,a.'
    i
    i1:':,:':.'
    i:ta:.:.:.'
    t=.
    iji
    ::
    ::i'r
    : .
    -
    ii:i;:-:.::
    '
    :i::l'
    :
    ::.1
    t:..".'=: .
    :
    f==.,:,'
    I
    ::1
    i.i:'
    r::
    )'..'
    t!::i.;.::.:
    i.
    ,t.-
    -i
    .
    :|it1-.:. :
    #i-
    '-:';).,
    't
    .
    '
    {?+::
    -.
    *L:; a::'
    ::,
    4.60

    i.-'
    .:,1,
    €rl
    I'l
    ::<-.
    *
    i,:-:';i;
    *l
    it,. '
    FT
    i1r ,.'
    il
    ij.
    ll
    strongly'rith
    Che rOi;rCi!'f
    le',ris
    i.li
    f-ir.
    $;ct,
    rjt,tl::i::..:.:..:r;
    :.,:::
    ::r.'rr:..i.
    .::i.::
    sedirnnt phascs
    of the
    ecosysi(tri. In
    ltn'
    i,r'r:.!LT'ri
    :,i::rj':.
    :.i,i,
    .,,rr.!,:i...
    ,.:r
    1r'.':{:::r.
    Cd
    concen[ratl(trls
    in
    all
    e(-.()$f*:ftrii r:.riBl-rrirrji.:r
    qfi.;1.;;:u:,
    1!-r.;
    ,...r_
    ,:-
    to
    rhe
    gxterlt
    of
    beirrg
    bclr.r*'rhe
    rjerrtcr.iirr
    r.i;:,j!- i:r :;!',.r.-r.;,
    ',.t!
    lndlcative
    of
    imrt:ovtrrer,i
    in en':irg!ie!11-ri
    ]
    rlrli
    r
    i i
    ,..
    ,
    -i'r:r:
    ::.i1r. .
    ,
    drat^tn
    for
    Cr;
    althtruglr
    the decraases
    <jjii
    ni-rl ;i;r[:!-r:;;r:i!
    ti;i-
    :i:-..i,,
    abiltty.
    'lltese
    decreaskrg,
    Lrc,rrds
    jrre
    r€f :ec{.ir:!::; r,:
    :,i;,..,:
    ;.r:,
    .ir-,,
    occurred
    in
    the
    surrsurdinp-
    milieu.
    ltre
    rgnaitiing
    t-wrr elenents
    eif
    envirorr''snt..rl
    {.lr.'lr:.ur-r
    ;rrrt
    if'.u.'ej
    ir..
    &l e-,"jris=i
    i;-,
    Fig;
    4.5, llg
    concencration-s
    decreased
    ln
    all
    ecr.rs.ii;rrj:.i
    crnrrl:ir{.r?,r
    {:ricff,
    l,i;ir_k
    buLlheads
    during
    rhe 3-year periocl
    .
    Jhcsc trrgrds..rir:lrt.*i.-.ll
    ii',,,5,1-
    !,:rt.i.t.
    ;rr.r'
    prosented
    nurrerically
    in
    thble
    4.20,
    Se..'cral
    ln.sr];ii.il,itt.t-it'J,
    r,iliid
    c..r ,.1
    i.
    ::i{+,
    Speyer
    1980)
    had indicateJ
    rlrac
    Se
    lwly sr;pr:-r:ss
    tlie l:jr;;ir.'r:r-r:r.rl.,i!"jr*i:-,1
    i!:
    .:i':rr.r.i
    be
    proteccive
    againsr
    roxic
    effecrs trf lir-i
    in
    fishes.
    'i'l:e
    ri,r:..r
    i::
    T;:ir!e
    i
    j*:irsTiesis
    rhat
    j-n
    coffeen
    lake
    se may
    srpFrcss
    thc bitxrcn-ur.:l;lri(!r
    r:f
    lil
    i,,',
    ir.izt,tz.i!
    s!:,ri,
    l;r.:.,
    not in
    largonxfh
    bass.
    ltrere
    has
    beett concent
    ahottt
    the rcl>rcxluc'-ivc
    l'irilurc
    cj'Jlisi:c-s
    i::lr,.ilrir-i:i1:
    i;ii1,1
    confaminaced
    witfi Se.
    Itt l.a!<es
    not
    sub.ject
    Ln cxlxlslrr(r
    lti in,hl;iri.rl
    ;$lijir.,i
    r:lrt-
    tnercial
    wastes,
    the
    concentr;rtion
    of
    Se in
    fish
    nr.:.scJc r.rl'ri,,.
    e:r.rc.e<l.s
    I nir:
    (I'akkala
    er al
    . L972, May
    antl
    llcKinney lgSl).
    !'islr
    rep:',;,rJuci
    ir.::.i in s;r.:r:ii
    i;:i<r..,r
    jr,,
    usually
    nonnaL.
    Ctlrbie and V;rn
    Honr
    (1978)
    rerxir.rcrj
    tixrt
    l:i.,rlx.s
    fr.rn:
    ilrc
    mjn
    portion
    of a ccnl-ing
    lake
    fcrr
    a coal-fircd
    lr.:rr'er
    pl;rnt
    in li-.rrtli
    (l-::rr.ljjni
    i-ri.x";:
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    group
    of
    orgdnisms
    may
    give
    a
    biased viewpoint ol'tire
    conclition of
    that
    borly
    of
    water,
    For
    that reason,
    it
    is
    qrrile
    irnporLant
    Lc
    stirtly
    groups
    of organlsms
    f
    rom dif
    ferent
    trophic levels
    to
    make
    nn assassrrent uf
    an aquatic
    ecosystem, One
    important
    group
    is
    the
    3lr;nei
    as
    prirnary pr.rducersr
    they
    produce
    much
    of
    the
    organ
    i
    c
    mater i
    a
    l
    consumed
    lr.y the
    "h
    iglr0r
    "
    Ir'opn
    ic
    levels. Algae, including
    phytoplankton
    ('isuspenderl"
    algae) anrl
    peripliylorr
    (attached
    algae)t
    dre
    not
    only useful as
    water
    qualit-v
    indicators anrl
    as
    prinary
    producerstlfoxygeniltaquaticenvironments,ttuttheyalsoait|indeLermininq
    the
    trophic state
    of a
    body
    of
    water. Based
    on
    thosc
    concepts,
    invesLigalions'
    of
    the
    phytoplankton
    and
    periphyton
    corffrrulriLies
    of
    Coffeen
    Lake
    were underlaken.
    io
    satisfy
    the following
    objectives:
    (l
    )
    to delerrnine
    rlifferences beiween
    'phytoplankton
    species c'rnposilion and abunrJance
    in
    clifferent
    areas
    of
    Coffeen
    Lake,
    (2)
    to
    evaluate
    periphyton
    colonization of
    glass
    slirles
    in tire
    intoke and
    rlischarge
    areas of
    the
    lake,
    (3)
    to
    estimate
    prirnary
    protlucLion
    raLes
    in heated
    and
    ambient areas of Coffeen Lake,
    (a)
    to
    r;se
    data on
    phytoplankton,
    periphyton,
    and
    prirnary
    production
    to
    characterize Coffeen
    l-ake
    in
    relation
    to other
    t'llinois lakes,
    and
    (5)
    to determine
    the
    cffects of
    power
    plant
    operation orr
    the
    phytop'lankton,
    periphyton,
    and
    primary
    production
    in
    Coffeen
    Lake.

    Hfiltil
    iALS
    Ar{il
    f4l:ii!ii*-c,
    PI,IYIOPLANKTON
    Iriplicate
    phytoplankton
    sarnples
    wer0
    c0llcct.r:rl
    rrorilr!.y
    frrrir
    ?l{,ltrly l.l/ll
    through
    l5
    Septernber
    l9B0
    aL f
    our
    lake
    statiorrr
    (i.e,,
    StaIions l,
    Z,
    j,
    ctnci
    4,
    respectively)
    (Figure
    1.2).
    A
    phyloolankLon
    sample
    consistarj
    of
    ,r
    rnc,-i
    iter
    ':
    ',.
    sample
    of
    rteptlr-integrated
    water
    taken from
    Lhe
    surface
    to
    [he bottam
    of thr:
    euph0tic
    rone.
    0ne-l
    iter
    samples
    were
    also
    lakerr
    near the
    lake
    bot.tom
    wiLh a
    ,
    ' ,
    Kcitrnerer
    watet'
    sampler
    at the four
    major I
    ake
    stations
    durinq the
    sdile tinte
    pr:riod
    ancl
    al a depth
    of 6m at the
    power
    planL
    inLake
    frorn
    Sepleqrber l9/9
    witlr
    l0
    ml of acidjf
    ied
    Lugol's
    solution.
    The
    sa,nples
    were retrrrnerl
    to
    lre
    -i-,"laboratory
    where they
    were
    allowed
    i,o
    settle
    for
    approximaLely
    Z
    days.
    The
    -
    ','
    water
    that
    the
    was
    final:volume
    t^ernoved f
    rom
    of
    each
    water
    sanrple.
    and
    organisms
    usinq
    a suction
    was 50
    hose
    rn'1.
    anct
    Three
    a
    ,,j,,
    subsamples
    siiapetl
    tube
    from
    so
    ,.:,
    each
    of
    two
    replicate
    sarnples
    f
    rorn
    each
    stat ion
    were
    place<l
    in
    Lhree
    ',':'Palmer-Maloney
    nannoplankton
    cells
    and
    l'our
    visible f
    ielrJs
    from
    each
    cell werc
    examined
    at
    400x.
    AlI non-diatom
    algae
    were identifed
    Lo
    tire lowest
    possiblt:
    taxon
    and
    cliatoms bJere
    recorded
    as
    centric,
    penrlatL',
    or
    [9lq!-Ua
    spp,,
    with
    Lhe
    exception
    of Rhizosolenia
    spp.
    and Skeletonema.
    potarnos
    whiclr
    r.rer.e
    jrjenlif
    iecl
    to
    :'.,'sP€cjes
    when
    possible.
    Perrnanent
    diatom
    slides
    wele
    prepared
    for
    spccific
    identifications
    by
    cleaning
    a
    suhsample
    of a
    qiven
    sample
    slurry
    acc6rrlipg
    to
    modified
    methods
    of Van
    der tlerff
    (1953)
    and mounting
    the
    diatoms
    in
    Hyrax.
    0iatorn
    valves
    were
    counted
    and identified
    at
    1,000x
    or
    I,250x in
    ranrlom
    transects
    and
    the
    densities
    of cliatoms
    in the
    original
    sarnples
    were
    comprrted
    by
    .,,,'-combirting
    relative
    abundance
    est'imates
    f
    rorn
    diatom
    sl itjes
    with
    centric,,
    1)ennate,
    and Melosira
    spp.
    counts f
    rom the
    Palmer-Maloney
    charnbers.
    Non-di
    atorn rlens
    ities
    in
    the
    original'samples
    were
    comprlted
    using the
    appf"opriaLe
    multipl
    ication
    factors.
    Phytoplankton
    were
    reported
    in
    algal
    units
    per
    liter;
    an
    algal
    unit
    :
    was ctef ined as
    f
    ol lows:
    :1:',':,,1.:;:1;
    '
    :'t
    t
    tl
    '
    ,,
    .=,;-'',;,,;:
    ;
    ,:'
    :',,':'
    :
    .,'
    '".1'
    5.4
    I
    I
    I
    t
    I
    T
    T
    I
    I
    T
    I
    I
    T
    I
    t
    I
    -'l'
    ':,
    ',
    -'-
    i,-,
    .l:.,
    ..J

    ALGAL
    FORH
    itil ce'llul
    a'r
    Colonial,
    ,t
    i
    F,i
    l amentous
    :-
    ciiLLS'
    PEn iJf{l
    ?
    *e
    ac
    h,ceTT-6i
    tliaia6-Tr
    irs t','i
    c
    -4
    ccIIs
    cxcept
    bIueqre,.rn
    ,f
    i1nl
    witlr"'eel
    ls'less
    Lhan
    trwcr
    Elricrcrn:
    in
    rlianrcLcr
    ln
    50 cell
    unri.s
    -100
    m'icron
    lengLhs ,
    '
    rl
    Taxonomic keys
    used
    for
    algal
    irlentif icatiorrs
    inclu,JecJ
    H,isttrlt
    (lg3C),
    Snith
    (1950),
    Prescott
    {1962}',
    Patrick
    uno''R*imer'
    (1966},
    Iif
    f
    arry
    onrJ
    itrirton
    (l9zl
    ),
    anrJ'
    Patrick
    and
    Reimer
    (1975).
    '
    ':
    I
    :
    ,
    t
    -
    ',
    ',
    PRII4ARY
    PRODUCTION
    :
    :
    Pritnary
    production
    measurements
    were made
    at. Staf
    ions
    I
    ,
    ?-, a.vJ
    frorn
    the intake
    area
    (Figure
    1.2)
    bintonthly
    from
    September
    l97B through
    January lgSl
    arrrl
    aL
    l'
    staiiorr
    4'birnonthly
    fr:om
    March
    1979 througlr
    Januar-y
    lg8l
    using oxyqenl
    .
    methodolooy.
    Integrated
    water
    sarnples
    collected
    fr:om
    the
    euphotic
    zone
    were
    pl
    aced
    in
    'l
    ight
    (c
    lear
    )
    ancl
    dark
    (opaque)
    bot,t
    l esi" and
    tlre rJ issolvcrt
    orygun
    :'
    ,
    concentrations
    were deterrnined
    using
    a
    YSI oxygen
    meter
    (,SepLemher
    l97B) and
    l'linkler
    methods'
    (Novernber
    l978 ttrrouglr
    Jarruary
    lgBl
    )
    accord
    ing
    lo
    Standard
    '
    l'let,hods (APHA
    et al.
    1976).
    The I iqht
    and' dark
    bottles
    were
    suspended
    jn
    the
    water
    at the
    surface,
    l-meter,
    and
    2+neter depths,
    After
    J
    Lo
    5 hours
    of
    incubation,
    the
    oxygen
    concentrations
    were
    determinec.l
    again.
    The rates
    of neL
    productionrwere'determined
    using methods
    <Jescribed
    by APIIA
    et
    al.
    (
    19i6).
    Ihe
    euphotic'zone
    depth
    and
    an
    pyranometel.
    chart of
    sotar rarJiation
    durirrg
    each day
    used
    for
    prirnary productivity
    were
    userl to
    calculaLe
    the net
    er:photic
    zone
    primary
    prorluctivit.y
    in
    o2/n2/aay
    ancJ i n
    02/g.Kcar
    of solar
    rasli'at
    ion.
    .
    PER I
    PHYTON
    Periphyton,was
    co'llected
    quarterly
    oh'glass
    slides
    suspenOert
    for
    28
    clays
    in
    floating
    periphyton
    samplers
    at a depth
    of approximatel.y
    0.025 rn.
    Quarterly
    collections were
    made from August
    l97B
    through
    February
    l9Bl.
    Triplicate
    slides
    wer'e' col le-cted at each''of
    tworsamp'ling
    s'uations
    locate
    d
    near
    tlte
    Discharge
    an'd
    .
    Intake areas
    of Coffeen
    Lake on
    all eleverr
    sampling
    dates
    ancl
    at Statjon
    I
    and
    .
    .,..-:
    ):. .:,:
    the
    dam area
    on
    the
    last
    six'samplihg'dates.
    At the
    time
    of collection,
    eac5,
    ,:..:
    .,tr
    :':t:,4
    ,i
    l=
    :..:

    slide
    t{as
    preser-verJ
    intdcl,,in
    hottles
    corrLaining
    ?
    ml
    of
    ,aciitif
    ied,Lur1ol,s
    solution,
    and
    O:
    mt
    of
    water'.
    Scrapings f
    rorn
    Cuplicale
    lglirles';rerrr:sti.r,,ij.i,r
    llaring-blender
    and
    diluterl
    te
    a
    known
    volume
    (e.!.,
    b0rnli.
    ii,*.algae
    irr
    itr:e
    sarnples
    werc
    Lhen
    irJerrtif
    ied
    ,rnrJ
    counted by ilic
    ,u,,,a
    n.o.odures
    ort
    Iine,l rol.
    phytoplankton
    samples
    exceot that
    the
    dppropriatc
    rnultiplic.rtiorlifoeluru
    onio
    used
    to
    give
    densitios
    in algal rrnits per
    l0
    cn2.
    Af.IC I
    LLARY MEASUREMENIS
    .:
    ,:'
    :
    t\ncillOry
    medsrrrernents
    including
    temperature,,pH,
    salinity,
    r!issolved
    oxygen,
    liqht
    penetratiott,
    light
    intensity,
    and
    conductivity'*ere
    taken
    at the
    surface
    at
    the time
    of sampling
    for
    phytoplankton
    collections
    and
    primary
    prorluctivit.y
    measurements
    and twice
    during
    e)/.posure
    of
    periphyton
    slides.
    STATI
    SI ICAL
    PROCEDURES
    Data
    for
    phytoplankton
    totdl
    anct
    major
    group
    rJensities,
    phytoplankton
    prirnary
    productivity,
    periphyton
    major
    group
    ancl
    total
    rlensities,
    water
    temperature,
    dnd
    nutrients
    were statistically
    analyzerl
    usirtg a two-way
    analysis
    of
    variance
    (by
    station
    and rnonth)
    follorved'by
    a
    Duncan's multiple range
    test
    according
    to'i6e
    General
    Linear Model
    procedure
    of
    lJarr
    et al.
    (.|976)
    available
    on
    the
    9tatistjcal
    Analysis
    Systern
    at
    the
    University.of.
    Il l
    inojs,
    Urbana-Charnpaign;
    Data
    for
    chlorophyll
    a statistical
    analyses
    were the
    same
    as those
    data
    presented
    in Section
    3,
    Part
    l,
    here-in
    ancl daLar,for
    total
    inorganic
    niLrogen,
    soluble
    orthophosphate,
    and total
    phosphorus
    were
    obta'inerl
    frorn
    Section
    3,
    part
    I, herein.
    Data from the
    top
    and rniddle
    sampling
    locations
    were
    averaged
    for
    the
    vat^ious
    nutrients
    since it
    was
    felt
    that
    those
    two
    levels
    would
    better
    repres'ent tlre
    nutrients available
    to the
    phytoplankton
    that
    were
    actively
    photosynthesizing
    than, for-
    exarnple,'only
    surface
    nutrients.
    A1so,
    only
    nutrient datd
    from
    months in
    which
    phytoplankton
    were sanrpled
    (i.e.,
    during
    the
    period:from
    July-197B through
    September
    '1980)
    were analyzetl
    statistical
    ly.
    Al I
    tests
    for significance
    discussed
    in the results
    and
    rJiscussion
    section
    were
    nrade
    ;;rs,,0.05
    level.'
    '
    I
    I
    I
    I
    I
    I
    I
    t
    I
    I
    I
    I
    I
    I
    I
    I
    I
    :,::
    .
    "
    ',,
    l:','
    .
    '..-
    a:'.
    ::
    '
    'i;1;:','
    ;,..:
    ',"//
    :j':
    :.;,:',
    ',
    '
    l-
    T.
    ::::-i:r
    5.6

    'l
    :;l-'
    ..:
    ,,..
    .-.''.,
    ..
    :,:
    .::
    P0I{ER,'PLAHT
    Rf[AfEO
    |ARA]4[TERS
    '
    '.:,.
    Temperature
    ,'
    -
    Since the
    addition
    of iaste
    heat,
    ort a
    cooling
    lake
    is
    one
    of rne mdjor
    eff,ects
    of
    pomr
    pl,lnt
    operatiorr,
    temperatures
    at d
    if f
    erent stations in the
    lake
    were
    of
    particular
    importance
    to
    this study.
    For tlre
    phytoplankton
    and
    periphyton,
    ',vater
    temperatures
    in
    the
    euphotic
    zone
    (zone
    of active
    photosynthesis)
    were
    of
    greatest
    interest.
    Temperature
    data
    taken at.
    tite
    surface
    ancl
    mirl-depth
    in
    conjunction
    with
    the
    water
    chemis-try
    data
    (Section
    3, herein) at.stations
    l,
    Z,
    3,
    and
    4
    were.averaged for
    each
    month
    frorii:July,
    197B through
    September
    l9B0
    arrd
    els
    procedure
    followed
    by a Duncanrs muitiple
    range
    test
    to
    detect differences'betrveen
    stations and betwecn
    months.
    [.later ternperatures
    in
    Coffeen Lake
    were
    significantly greater
    at
    Station
    I
    (heated)
    tnan
    all
    other
    stations,
    significantly
    lower
    at
    Statiorr
    4
    (ambienL)
    than,al
    I
    other,stations and
    not s1$rrif icantl,y
    different
    between
    Stations
    Z,:ancJ J
    (Table
    5.1).
    ,,,Table
    5.].
    :
    Mean
    water temperatures ("C)
    of surface
    and
    mid-depth
    locations
    for four
    stations
    sampled,monthly
    in,Coffeen
    Lake
    frorn,August
    l97B
    through
    September
    '1980.
    l'1eans
    underscoied
    by the
    same
    I ine
    are
    not signi ficantly
    different.
    ll''
    ,jl
    .'-
    il'
    ,l
    tl'
    l'-
    Stations
    '-f-,:
    2---
    --j---l--4-:-
    X
    25.4
    ,|9.
    B
    r9.I
    l7.t
    r,l':
    ,'
    l,:.:
    .
    ''
    i
    ii:.,r

    '-::,.='.
    :.::.;:
    '
    :
    .:..
    ' :'.,r
    ..,:
    I
    I
    I
    I
    I
    I
    I
    I
    I
    I
    I
    t
    I
    I
    I
    T
    I
    t
    PIiYTOPLAI{K
    TOII
    -l
    r'
    :::
    Data for
    phytoplankton
    densit
    ies,
    spee.ies,
    July
    '1978
    thiough
    June
    l9B0
    are
    contained
    de'ns
    i t
    i
    es
    ,:.number
    o f occurrences
    of
    ,:
    t
    ax,r,
    phytopldnkLon
    c0l lected
    from
    July through
    A5,il
    ,
    A5.2,'A5.3,
    and
    AS,4,
    respectively,
    Dominant
    taxa
    rlt)d
    d iver,ii
    I
    ier
    f
    'Jr
    col lecL iorrs
    ,
    ron
    irr
    CoutanL
    (tgeOa).
    0,:Ia
    ior
    djversit.ies,
    and
    r'edunr!ancies
    for-,.
    Septernber
    l9B0
    are
    containeei in
    Tables
    i rr
    , the
    append
    i
    x of
    th
    i s
    report
    .
    l'wo
    hundretl
    and
    twenty
    six
    taxa
    were identified
    frorn
    plrytoplankton
    collect.ions
    rnade
    in the
    euphotic
    zone
    at
    four
    staLi0ns
    ancj
    frorn the
    intake
    area at
    a
    rlepth
    0f
    six
    meters
    (Table
    -
    A5.l).
    0f those
    taxa,
    qlore
    than
    60 occurrecl
    l0
    or
    rnorc
    r:
    '
    -
    l'
    tirnes
    at
    one
    or
    more
    stations (Table
    5.2).
    The f
    iagellatecl
    organisms
    tenrlecl
    to
    be
    less
    coffinon
    in
    the
    Discharqe
    area
    (i.e.,,Station
    I
    )
    arrd
    increaserl,in
    frequency
    at
    stations
    around
    the
    lake
    to
    SLatjon
    4
    (arnbienL).
    Apparently,
    effects
    related
    to
    operation'of
    the.power plant
    were respopsihle
    for
    loyrer
    ':",
    frequencies
    of
    occurrence
    of
    most flagellates,
    This
    lorver
    frcquency
    coulrl have
    beert
    a result
    of entrainntent
    and
    destruction
    of t,he
    cel
    ls
    o,-i,a
    r"esrlt
    of intake
    of
    water
    vrith
    lower
    concentrations
    or less
    tliversjty
    of f lagellaLes.
    Ihe
    fact
    tilat
    rnany
    pennate
    diatoms
    seerned to,
    occur
    nrore
    f retlrrenily
    at
    Stat ion,l
    and
    ,
    gcnerally
    decreased
    in
    frequency
    of
    occurrence
    at
    stations
    around
    tite
    llke
    to
    Station
    4
    rnay
    be a result
    of additions
    of cliatorns
    frorn
    the
    periphyton
    growing
    a1ongtheconcrete-lineddischargecanal..Notr:ends].forthefreqtrencyof
    occurrence
    0f blueqreen
    algae
    werc
    apparent;
    althouqh
    slighily greater
    fretluency
    of
    'occurrence
    was
    expected:in
    the
    area
    of lreated
    ef
    f
    luent,
    due
    to
    additions
    f r:om
    coves
    ,wh
    jch
    had
    continual
    ly.
    high
    ternperatures
    during
    I ate
    sum'rrer,
    l:luegr.eert
    algal taxa:w€r€
    sirnilarly
    abundant'in
    al1
    parts
    of tlre
    lake
    (Table
    5.2). I,lo
    trends
    were
    apparent f
    or
    non-f
    I agel I ate<l
    mernbers of t.hc
    chloroplryta.
    Abundance
    During the
    study
    period
    frorn
    July 1978 through
    SepLernller
    .|980,
    the
    rneon
    densities
    of
    phytoplankton
    were
    significantly
    greater
    at Station
    4 Lhan
    at
    all
    other stations
    and significantly greater
    at
    Station
    3
    than
    at
    the
    intake
    area
    .J,
    5.8

    Iable
    5.2.
    ','
    Alqal
    tarl tlt<lL
    :ir.r:urr^r.il
    lrj
    ')r'r,,rrr.
    {.of
    f
    een
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    n,jrrlh'!
    7
    r;
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    ,li.
    'pcsEiltle
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    ia:,
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    rJcrrsities,
    crprlciel)y
    l)ctwccrl
    SLa'-ion I
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    Statiort
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    JL
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    location
    jn
    conrpariEon
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    phylopiankton:
    :
    Iound
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    rlischarge
    area
    (SLation'l
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    another
    cettfra'l
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    coolinq
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    lreaLer
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    al)unddnce
    dlso occ.trt'rad
    at
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    staLiorr
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    would
    be frorn deeper
    waters
    wltere
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    algal
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    wotrld
    be rer1uced
    and
    populat
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    would i:e
    generally
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    where
    concentratiorrs
    were
    significantly
    r;rr-.aLer
    than
    all
    other stations. As
    ncted for
    phytoplankLon
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    also
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    greater
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    a Lhan
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    ::.
    .
    .and
    the intak-e
    area.
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    of
    ''chlor'ophyll:l:at
    Station
    'l
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    '-'
    .'
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    "
    i,
    signi'i'icantly
    lovrer
    than concentrations
    at all
    othe" sarnplinq
    locaLions (Iallle
    ..
    which
    water is
    taken
    into the
    power
    Or:n:.was
    foun<l
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    lcoul<lbeexpiainerJby.t.heirtt'ake.lrtr!r|.i5{:h!l''':!:iii-w4{i]|'',t'i,-il5|].]r1f
    phytop
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    lLal-iorr
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    Has'lrrri
    !-,l thr.qi:
    l.irlr,{,l!
    pr-l:lrlrict.i,re
    ,rs,ril
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    j'n
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    I
    {
    t$rles
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    ltr,:
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    inosl'l
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    the
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    Lher"r
    ,{
    f
    aulr:
    5.51,
    :',tt:::l
    Nutrients'',":
    Mean
    nutricnt
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    using
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    drld
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    greater
    al
    Station
    I t.lran
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    4,
    LoLal
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    stations,
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    tha'1:at
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    t
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    a
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    l,i :l.rn,!
    li
    -i.r!
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    relaLively
    sitaill;a
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    {it
    SLations
    l, 2i,
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    Z,
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    4
    were
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    onf
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    L.rrr)-i{ny,lpniysjr
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    {l,lt)
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    I
    {1.j4}
    accordirtq
    to the
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    Lest.
    The facl
    l.haI
    St,rLion
    I
    hart gr.eoter
    diversiLy
    than
    :statfon
    4' was
    expCcterl
    due,[o
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    act
    tlraL
    tlre
    watr:r'
    sdnlplrd
    f ro6
    SLation
    1:
    carue
    prirrrarily
    r-rlorn
    water',taken
    in.,'aL
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    d
    srlor.L
    L
    ime
    bi:forlc.
    ,.
    :
    5. 17

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    staLions in
    L,l'(?.l*rrllchril
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    J:la*
    1976
    t.lrr-trulft
    icig,i:i
    l,.l,'j. ili,: rdrriii!1,,.,{
    rtivtlrSilies
    for
    L,tkrr
    Shelbyvillc
    itn'l
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    iianq,
    t17'i1
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    r+spectittly.
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    ['rf
    feelr
    i-,1hr, th.:
    r.tr]rlt
    ,.]f
    Tr,tn
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    f*r
    the
    lake
    *.t:,
    f r
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    I .ll9 to 4.7{r.
    rln
    5rnl'nary, tlter* i{*r€ sevoral c,
    if
    f
    ernnces
    irr
    phy{9p1Jnir
    r",Jn
    co:rlprs'i't
    ie:4
    antl
    dlritnddnCe ltet'rCenistaLions in
    Collcett
    t.ak*:
    ttia[
    ilerc Jppalr-'rll.ly
    ri:laLed
    l.o
    Jrower-
    Plant
    oper(rIion. ''Flagel laIerl
    plryloplankters
    ocevried
    learL
    {requcnt
    iy
    in
    the
    ilred
    of heated discharge
    (
    StaUion I
    )
    and incrCased
    irr
    f
    r.ertrrt,ncy
    of
    occur.rerrcc
    rt.
    succcssive
    sLat,ions
    arnound the
    laka Lo Lhe
    ambienl area
    (StaLi+n
    4).
    lhc
    euphotlc
    zone
    phytopl0nkton
    densitjes
    and chlorophyl
    l a
    concenLraLiorrs
    wcr.tl
    ':
    i'
    '
    si.thif lcantly
    greaterr
    at Station
    4
    (amlrienl.)
    and
    'gradudl
    ly
    decreascrl
    irr
    successive
    order around
    tlte
    cool'ing'loop toward
    Stalion
    I
    (lreaterJ).
    0ivr:rsily
    ,t
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    I

    I
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    .!1
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    periphyt0fr
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    rlirLrr,li
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    ('til'.:r
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    ni.rin:i of
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    i4,ac
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    e.r:i?-srr.:
    dr.:rrti
    i,
    icr
    antt
    chlorophyl la
    concentrations in
    Cflf
    ir-,rvr
    l.4kt.iijf'r.,
    iirnrijr'l,j
    r-it;j.,,..fr...1::r
    1.3ir1
    Shelbyville
    anrt
    Loke
    Sangchr:ir;
    the
    slirlhi ljr i,iwer
    ti.4+1 iii::i;i:
    ipt
    1n-
    i.1f f
    ..1-,,'
    Lake
    could he
    explrainecl tly:dif ferent
    melh0(,5
    +[ or!,tlyris
    ,rnr!
    t./
    i!r* i,.rrc,.
    nuLrit:nt loarlirrg
    of that
    lale.
    ,jhe
    dia[ofls lr+<1
    l{ixer
    rqi,rt.:rtr
    JbirntJ6n{e
    irr
    Cof
    feen
    Lakt)
    thdn
    in
    Lake
    Slrelbyv i
    lle
    arrd
    Laki
    Santpclris;
    ilr-r-ilr]
    *li1.ril
    ,rnJ
    i,rrt
    Cryptoplryfa
    tlad
    lr.eat,er
    relitive
    obuatia{tte
    in
    t.offeen
    Laxii
    liran
    irr
    thr:
    r;t:ier-
    ixo
    I
    rkes.
    @',",,
    t,-
    l
    0ata
    for,flet
    prlrnary productivity
    (mg
    02'rrr-2.rtay-lJ
    coi
    lectert
    f r"cnr
    ':Septernber
    lllTB
    thr.ough f'lay.l980
    are
    containerJ in Coirtant
    (l9g0a).
    uata for
    net
    primary productivrity
    col lecterj
    from
    Jrrly 1980 through
    .lanuary
    !gttl
    are
    cortairred
    .inJut,|eA5.5initrea9pendixof.thi.5repor|.
    ,'
    Net.
    priinary
    productivity
    (rng
    02.gF-cal-l of solar r,rdi,rLiorri
    w,rs
    qreatr.rsL
    ,,intake
    area
    (0.73
    Slation I'{0,59
    ;,
    ,.'.:
    ,,
    t-'
    -.1_-'-
    t.'.
    ;tt,,t:.
    .
    ,.
    ,.
    o.t
    ,$-ta11ffi
    4
    r:(0:,91,
    ng02.gKcal.I1
    and"'lower
    at:: Ihe
    Ii;1n902.$Kcal-l),
    Sliatlorr
    2
    (0,68
    mg02;gKcal-i;
    and1
    nso2:itKgal'l),(Table
    5:n),
    ":
    -,
    ',-.,.'
    'tt=,,.
    '.,,...,.,.
    ','

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    .
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    ,
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    i
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    sp*aiirtg,
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    }.'}rxi}€r.lLrrrr:!
    r}i
    ii't,
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    1,,,.i1'
    ;i:++:,!r.;,.;.r
    .:i
    [rt'itnary
    p]'rldili-i
    irin
    h,li
    I'1.-'lr
    i..l!\eay13rj, l;r1f ,rt irlt.rr:L
    l-q;::g,;;r1!,.;::,-1
    1g
    ;r!)-:.
    :.r1
    i:.!:rri.i
    ther'e hd5
    hc,ert irthillitron
    rlf
    []rlrilct'jf lrr.)drtCl.ivit/
    i1
    r.r,r
    i
    1:',
    r11,,iii,
    l:ri
    ,r
    r..,r,.,
    .nccordirtq
    t* rJarrirre r
    ;rrrrl
    Srrh;nrr
    ila66i
    anrl
    i.t;r'i;il!l
    :1r14
    i:!r,i.ri
    i
    i.iit
    j.
    .1!.iir,r-
    reS(ldrcher'5
    ltr.lvtl
    indieeied
    thnt itrl-/
    (i)'ntiirl,lt
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    irt'
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    1*,*-,p,';',tt,ir'.-,
    itfliJ
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    35'C
    wr'rrl
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    !.a
    irrir'-'ar:v
    pr-i'.!:j::iivit,,r
    {f4ii
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    'I
    9lfi).
    Itrey
    tl';,1
    irriJir:.,tLutl
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    *f
    1)ri,;14r-y
    ?riitiuti.rvi,../
    w,1,,
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    at
    rt
    isCttarile
    Lfrnpcrntrrres
    qreaLer
    t.lralr
    J4'C
    rrrJarJle=rg.rif
    i4bieal
    ie,!rpr:r,rl..;r.,:5.
    0Lher
    restlJrchdrs
    have forlfid
    fh0t
    prirnary
    prtrCuclivil.r"rrt:r'ililcn
    inhihil::ti
    regdrdless
    of
    intaker,Lernpclittures
    with
    t's
    of l0 l.;.3t]"F
    i6urtz
    anrl
    r{riss
    rei4).
    ,
    ,,
    flor,lrl
    (in presr,)
    lfortnrl
    thaL
    prirnary
    protluct.ion
    by
    plrotopl,]rrkLlrr
    wds
    inhibilett
    in
    the
    discltarge area
    of Lakersangchris,
    a
    cool
    ing
    lake,
    rlurirrg
    nerioils
    when
    wdter
    tentlle ratures
    irt tlre
    d i
    scharge dred
    were
    in
    excess
    of
    30'C Jnd
    l,h,tL
    t.he
    ;lrirnary
    protluctivity
    vras significan:tly
    grea[er
    in
    the
    discharge
    area
    than
    in
    lhe irrtake
    area
    duringl
    periods
    when
    water
    ternperatures
    were
    tlelow
    3rJ"C
    in
    the rlisclrarge
    area. Though
    other
    reSearclteFs
    hdve
    found
    heat-related
    rlifferences
    in
    productivity,
    no.
    significanL
    differences
    were
    found
    in
    this'sLudy,
    probably
    due
    to
    infrequent sampling
    and few replicates
    or
    due Lo
    the
    real
    sirnilariLy
    beLween
    stations,
    :::::
    ,,:
    :
    .a:..::
    .:
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    =.,i.'
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    l.
    5.20

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    i:itr:L:",if.r*,,
    i.,r,:
    .l.lly''!
    9iB
    thrOugh
    .]unr-''
    \9t1i;
    arZ
    ct*teintrl
    ra
    i.{::i!_.jrir.
    i
    ili;-1
    ,1;,,
    dg{Cit'lcs,
    :pec:
    ies.
    diver-ciiiti}
    ,iftrl
    rr?rjuf.!i.l4rjr.rr,..-
    f
    rr-
    l,-::.lr
    IIBQ
    Lhr";iurlh
    JJnirar'y
    !9Ai
    +rr:'{flrlLrrrieil
    i'{r
    I.:}ii:c
    q!:.i,
    .\r,.1,
    respectively,
    in
    tlre
    di.rpilntlrr
    +f
    rrrir
    repiir.i..
    Conrpo-sition
    Periphyton
    JCc,.nnulatiOns
    r:n
    glass
    llirjt:s
    0t
    fg117-
    st.it,iclnt
    d
    if
    f
    ererrt b,rt'de4n
    locdt
    iofts
    (Tablr
    5.
    l0).
    l4iiarr
    f
    rtn,;
    it
    ir:c,
    't i
    t1,,
    I :.
    :,.t:
    ,
    ,.
    rta:iii
    ,jl;rta !r.,r'
    ,,
    !.;nii ! rr;,ir
    .i::+,;t;
    !,
    i-1
    .?.,
    .atil
    lt.!,
    I
    tl
    I
    .:,f
    .:I
    ','a
    :.I
    .':
    :I
    ::I
    ilne
    |tundred
    and
    lighly
    thre*
    L4ra wr:rr;
    irjent
    if
    rrtil
    f
    r1ilt
    ,]er,t
    ;rlr,ri_.r4
    colleCtfrj
    f
    r:*rr
    qlass
    slides
    after
    quarterly
    28-rl.iy
    e\po3uri,
    perir.rrtr
    Jr.
    r,.;irr.sf.
    1l.i611
    5
    in
    l,tfir:.,4
    Lake
    (Tahle
    A5'2).
    St.ations
    incllrlerl
    lh+
    [nlrrt:e.
    iril.:hrr.qt,
    ,]rrrl
    i]a.;r
    o.*.,,
    o,,n
    Slation
    l
    {Fig,
    l.ei,
    ,
    ,
    .
    Abundanr:e
    j
    :
    :
    .
    gerii
    .i
    irlni
    f
    icarrt,i-y
    f*ltr*l
    unils:iC
    :
    Tabltr
    5.lU
    I'lean periphyton,derrsities
    {algal
    irnir,s
    .
    io
    c'o-2}
    on
    qlass
    slitles
    gI?.?.eg
    for
    2iJ tlays
    quarterly-frorn'septerntrer
    tg;i
    itr,.iugn
    r=err,:uJ,rv
    same
    l9til
    at
    I ine
    f
    ottr'
    are
    locat
    not
    sigrrificantly
    ions
    in
    Coif
    een
    rlifferent
    Lake.
    l'learrs
    ,rnt,erscoilcrl
    with
    t[c
    "- ','- '
    """
    Stat
    icns
    fiich
    a r
    g
    e
    -r*--*
    T
    -'
    -,
    -:--lm'
    -
    -
    --
    *-*fiir.
    ;kT
    -
    -
    ?15,000.,
    _
    .-ug!_q00
    t
    zttgq!
    ....
    '
    cn'Z).
    were
    significanbly great,er'a:t
    the
    lntake
    area
    thari
    all
    other"
    sLations,
    significantly
    greater
    at the
    Dam
    area
    than
    at
    Station
    I
    anrl
    the.'Discharge
    ar.eat
    "
    and,nOt
    rsignif
    icanb:ly
    Oif
    ferent
    betweerr
    S[ation
    Lanrl
    Lhe
    Discttarge:area.
    As
    can be
    seen in
    rio.,
    S.Z,
    inhibirion
    of
    srowlh
    did
    ;;
    ;;;r;:
    ;;
    ;;,;"r;r;;;.n;'-
    ,
    area
    :
    only
    .:,
    .
    in the
    warnter
    rnonths
    :,
    wlten
    ternperatures
    werg
    near
    40'C.
    The
    inhibition

    t
    :
    I
    I
    I
    :,,
    I
    I
    I
    I
    I
    t
    I
    t
    I
    I
    .
    l'
    I
    I
    l'
    1.,
    r+
    {t
    -1-
    f
    .i
    L-'l
    ,: lf-:
    )a
    ,-.
    i
    l-
    .::-
    1
    j
    .!
    ,
    i-.-
    .+
    ri
    't:
    i
    .l
    I
    't
    t-.-,
    '!
    "t
    .l
    .l
    ':
    .!
    _!
    '
    f-
    (
    i,.
    ,1
    i
    i
    :-
    -!'-
    I
    r"
    I
    I
    I
    I
    I
    >i:
    :
    a
    a-
    :
    F!:
    tt
    ad:
    .
    '
    ('l
    e5
    ;:
    ,
    .,9'1
    -
    u
    *.
    .
    !E':
    :
    :.ct'1.
    ':i':
    .
    :'
    "
    c.
    E6
    .Y.r
    €,i
    :
    i, c.
    I
    .E
    +;
    .rL*
    *q
    o,
    cu
    C>r
    q|..
    ^
    c:.
    *1
    -
    t t,
    -
    E
    qt
    :i
    Gq
    ;,:
    J
    :
    .8;eE
    Li
    ,.F
    rrs4<
    L
    '
    i0p
    atj
    ?JA
    :
    c:ti
    4!-
    Feti
    vqt
    JIl
    u
    c!
    'a:r,
    .J
    _ce
    sFa
    d4
    9ig
    cac
    q
    !G
    g!
    du
    CJ
    CE
    u.o
    0t
    l-!
    c
    i:r.
    d
    oF:
    sCAj
    !
    4r
    !: i:
    .r
    ja!
    f
    4
    :d
    6
    &.
    :,
    r
    --*-
    ,/
    rl
    ,/
    /
    --*-1-.T"*
    rJ,
    i\.i
    {i
    1
    :
    !
    n""-
    4
    \-
    \\,
    -'\--
    \
    i
    I
    I
    !
    l
    i
    'i
    ;l-
    I
    I
    ,:
    i
    :
    i
    9'
    (n
    ?_
    l::)
    J
    :i
    (:)
    rl,1
    L: Z
    :
    jt
    ,-,
    ,-
    .*
    '
    L\
    -.
    ili il
    '-.
    : .'
    -
    ..
    u.
    'r
    .--
    .--)
    ii
    i)
    -r
    .'
    .a\:
    5,?2

    ''.,'.,..a
    .
    i:.1
    :::
    i:
    -
    :.1
    of.
    periphytic
    algal
    growth
    in the
    Sischarge dred ira$
    4pparent during
    ,rll
    sampling
    periods
    throughout
    the
    study; since t.t:mper6i.ure-lnduced
    inhibrlion
    cf
    periphytic
    growth
    generaliy
    occurs
    only at
    tentperaLures
    over 30'C, olher
    faulors
    must:have
    been
    responsib!e
    for the reduced
    growth rdt?s
    of
    periphyton
    in
    the
    Di'scharge
    area.
    ''Epparently,
    factors related
    to
    the
    power
    pl,rnt
    effiuerit ware
    responsible
    for
    the reduced growth
    of
    periphyton
    in
    tlie 0ischarge area,
    It.
    should'
    also
    be
    note:l
    that
    the
    jnhibitory
    effec.t
    on
    the
    periphyton
    was still
    apparent at
    Station'l
    and
    that growth
    of
    periphyton
    at
    the
    Dam
    area was
    still
    siqnificantly
    less than at the
    Intake area.
    There
    was
    a
    gradual
    recov€r.r
    0f
    periphytic
    Arowth
    at successive
    stations
    from
    the
    discharge
    around
    the
    corling
    i:
    looptotheintake.Currentwa5aphysicalfactorwhichwasriifferent'at'the
    intake
    and discharge areas
    and
    might have
    affected the
    colonization
    rates lf
    periphyton.
    Current,
    was constantly
    greater
    at the
    rJischarge
    area
    than af the
    intake
    area and Cecreased
    as
    it
    progressed
    around the
    cooling
    loop
    to the
    intake.
    It is not likely that
    currerrt
    alone was
    responsible'Ior
    the
    observed
    trendsbecauseperiphyticarowthratesargusuallypositivelyc0rrelat.edwith
    current
    velocity;
    thrrs
    one would
    expect
    grcater
    accunulations
    jn
    the
    discharge
    ,:.::
    are
    a.
    The mean
    density
    of
    periphyton
    in
    the
    Kanl..akee R'iver was
    6,400,000
    algal
    unitl
    ,.10
    cm-2
    using the same sampling
    apparatus anci
    exposure
    periocls
    based
    orr
    data
    collected
    in
    May, August, and
    November
    of
    1977, 1978, and
    1979
    by
    Coutant
    :
    ,(1978,
    '1979b,
    ancl l9B0b). A mean
    periphyton
    density for
    Coffeeri
    Lake
    based
    on,
    ail
    data
    collected
    from
    l4ay, August,
    and
    November
    sarnplings
    in 1978,
    1979,
    and
    1980,was 4,400,000
    algal units
    l0 cnr-2.
    The lower
    densities in
    Coffeen
    '
    Lake
    ulorrld
    lie
    expected due
    to the
    generally
    nutrient
    rich
    environment
    of
    rnost
    r^'iu.rr'lWittiams 1964), sucn
    as
    the
    Kankakee River,
    plu:;
    the
    positive
    irrfluence
    oflgreater current
    in
    the
    river which would
    enhance
    nutrient
    mixing.
    Even so,
    the intake
    area,
    which had the
    greatest
    periphyton
    growth
    in
    Coffeen Laka,
    had
    mean
    periphyton
    densities of 6,400,000 algal uni
    ts l0
    crn-2,
    approximately
    the
    same as
    that
    found
    on
    the Kankakee River
    substrates.
    The,
    overall lower
    product:ion:of
    periphyton'in
    Coffeen Iake
    can
    be
    attributed
    to
    the
    ieduced
    growth in the discharge
    area
    which w,t'l'apparently a result
    of
    some::
    -
    '$1owth
    -:
    J
    imiting
    or inhibiting
    f
    acfol
    jn
    that
    area
    of
    tlre
    lake
    r.
    :,.
    :i':.
    'a
    ::::.
    :i]:'::
    s.23

    :ii
    .:
    ::i.
    I
    ..:
    I
    I
    I
    T
    .:
    :'
    Major groups
    Ihre,e
    divjsions
    of
    algae fiere
    rcsponsible
    f
    or
    tli*
    ra;jrrrity
    r;t
    pr,r
    iplrylic
    ll
    : rl
    growi.h
    on
    gltlss
    s'l
    ides
    in
    this sturJy.
    Thosc
    ar$r:ps
    rrere Ihe
    llriori:i:iryt,i,
    Baci
    Ilirioplryta, and Cyanophyta
    (
    Iable
    5.1l.).1
    irt nac
    ,0oin'rr:rt
    ,ri;l
    f
    or tal,ri
    densities
    of
    periphyton,
    t.he
    nean
    densities
    of these najor
    '1rr)rjps
    r:f
    ,rlg,:e
    lerr:
    always'lower
    .::
    at tlre
    0ischarge
    area
    and
    increaserj
    as
    one
    proceiltie,l
    arounrl the'
    coolinglooptowardStgtionl,tlte0amarea,andthclniakearea.T}rr:
    periphyton
    riensitics
    were
    always
    significantly
    greater
    al
    tiie Intal:e area
    Lhar'r
    at
    the
    Discharge area
    {Table
    5.11).
    Anong
    cach
    major
    <livision
    periphyLon
    den:ities
    at
    StaLion
    I were
    not ri,;nif
    icantly
    dif ferent
    'f
    .L',,n
    lhos,l'cjensities
    at
    the
    0ischarge area,
    Table
    5.1
    I
    l'lean'derrsities
    (alga1
    units
    .
    lO cm-2)
    (f)
    of
    the Chlorophy',a,
    :
    Baci
    ll
    ariophyt,a, and
    Cyanoplryta in
    periphyton
    coll:cted
    af
    ter
    qrrarLerl
    y
    ZB-day exposure
    periods
    at
    four
    stat.ions
    ,in'Coffeen,Lakc
    fron Septernber
    l97B
    through
    February
    l9Bl.
    ,
    l'learis
    underscored by the
    same I
    ine
    are
    not
    s
    i
    gni
    f icant ly
    di fferent.
    l!i
    T
    T
    t
    t
    rl:.r :
    t:':"
    i:'\j
    ?1=
    T
    l,
    T.
    Div,isions
    ,
    Stat ions
    D'rEliarge..
    l----.--ffim
    ---fiita[e
    Ch I oroplryt
    a
    x
    l}acillariophyta
    x
    Cyanophy.ta
    .
    ,X
    _
    572
    T
    t
    659 000
    000
    000
    517 000
    869 0c0
    1
    ,4
    27,,000
    tB0
    2; 22.9,
    Q00
    6B?,
    o0o
    !-reqg,ooo
    I
    75,000
    258,.000
    66 7,000
    I
    ",,t:
    Diversities
    Periphyton
    diversities
    computecl accordirtg:to
    tlre
    eqtiatiorts of
    Sndnnon
    (194S)
    were significantly
    different between sampling locaLions; tlre
    diversiLy
    cf,
    Iirc
    periphytic
    algae
    on
    glass
    slides
    at the
    lntake
    drea
    ''rat
    siqnif
    icanLly
    gr',rater'
    than the
    diversities,'at the,Dam'and at
    th'e
    0ischarge
    area
    (Table,5.l2).
    ..
    :
    ,.
    :'
    1.
    ,.:
    ,
    ;;'
    ,.a.
    :
    -
    l'
    i-.
    F.,''
    'ili-
    :,.
    r=
    1
    ,,-i
    i=
    5,24
    ::;..:

    j=
    l'
    ''
    i',.
    ..-'
    f''
    ;,.i;-,,,
    .,,i,
    0am
    I
    I
    I
    Iabte
    5.
    ll
    Mean
    dlversltles
    (3)
    for
    periphyton
    collect,r:rl
    f
    rom
    glass
    ,,1irj',..,
    after
    quarterly
    28iay
    exposuile-periorJs
    at
    four
    stations
    in
    Cof f
    een
    Lake
    f
    rom
    August
    l
    giB
    through
    February
    l9{tl
    .
    i'leans
    underscored
    with
    the
    same line
    are
    not
    significantly
    rlifferent.
    Stat
    ions
    Di
    scharge
    3. ?0
    3, 0l
    2.61
    2.42
    The
    gradual
    density increases
    noted for
    major
    divisions
    of
    algae
    ds
    one
    progressed
    around
    the
    cooling loop torard
    the
    intake
    were not apparent
    for
    diversity
    values. The rnean
    diversities
    increased
    from
    the
    discharge area
    (2.42)
    to the
    dam
    area
    (2.0f1
    to
    Station I
    (3,01)
    t.o
    the
    Intake area
    (3.20).
    lr
    is
    likely
    that
    the factors
    responsihle for
    the
    rer!ucer!
    grcwth
    at
    the
    Discharge
    area
    aiso
    were responsible
    fur" the
    reduced
    dlversity
    of aloae.rt that location.
    In strnunary, th€re ilere
    several differences in
    periphyton
    conposition
    and
    abundance
    be'tweett
    stations
    in
    Coffeen
    Lake
    that
    may
    havc beerr relaterJ
    to
    pov,er
    plant
    operation.
    Feriphyton
    accurnulations.on
    glass
    sl
    ider
    rere
    significantly
    lower
    in the discharge
    area than
    in
    the
    intake area. Since
    waste heat
    and
    current were
    ruled.,out
    as the
    sole
    causes of
    the lorer
    periphyton
    growth
    rates,
    growth
    inhibiting o;i limiting factors
    present
    in
    the discharge
    area
    seem likely
    ils a
    cause'for
    thE observed
    lorrer
    growtlt.
    DiversiLy
    of
    periphyton
    was
    also
    significantly lower in
    the
    discharge area
    than in
    tlre
    inlake,ared
    presumably
    due
    tothesame..factor.svlhichcausedthe.Iowerperiphyticalgalgrowthinthe
    discharle area.
    r
    j:1:

    Alerican'Publ
    i=c=ffii
    ntrof
    i*ui1rn,
    Arnerican !.laler
    ,,lo/ls',rssoiieticn,
    arril ,irtrrr
    Pollution
    contici
    fec-eratibn.'
    rgio,
    -
    irunii,.,r
    meulooi"i.,,:
    'ir,o
    ,ir;;;^;;io;
    of
    water
    and_wag[:l;t.ri--ii
    l4th
    erl,
    A.rcrican
    pub]ic
    tlealLir
    Association,
    t{ashingion,
    D,C.'
    )lg3
    pp.
    Barr,
    Al
    .J,.,
    J:-I.-Foglitlt,
    J,
    'P;
    fiall, anrt
    J.
    i.
    riclwirt.
    1926.
    A
    usrlr,s
    guide
    i,o
    SAS
    76,
    5AS
    Institute,
    lnc,, Raleigh,
    NC.
    .iZg
    pp,
    Brigham,
    A, 1977.
    t{ater
    qual
    ity investigations
    af"'udre
    .,.\sn_q[hris, section I.
    In'R. l{.
    Larirnore and
    J.
    A,
    Tranqlilf!
    ieds.)Annual
    re$p_rt
    fdr ijsra:l
    year
    Tg76,LakeSangchrispro.iect.I]linois.|latuialHisto'y,it,il'u*i
    (unpublishe<t).
    Clementr-K.,
    J.
    lasprowicz,
    and
    S.
    0.
    Sw.rdener.
    1979.
    Anrrual
    sunrnary
    of
    water
    '
    '
    Qudlity
    r€port
    Hi story
    to
    and
    Survey
    u.S.
    biological
    Army
    (
    unpub
    corps
    l
    i
    shed
    investigations
    of
    )
    .
    [nqineers,
    in
    st.
    Lake
    Louis,
    Slrelbyville
    M0.
    Il]irr,r.is.
    basi,n.-
    Natur,ll
    D-linJal
    ,,,,
    ,
    Coutant,
    L.
    !{.
    1978.
    Periphyton
    of the Kank,lkee
    ili,7q1,',';
    'ln
    R. W.
    Larirnor:e'aricl'
    ,
    M.
    J. Sule
    (eds.)
    construction
    an{.prg-Qper4t,ional
    aquatic
    monitoring''
    program
    lor
    the
    Kankakee River;,
    f.jirrs[
    .tnnual
    report
    hy il lrnois
    NaIur-al
    l__Evaluationof-acoolingl9kefislrery,"Vo1'Iv.|l.,.Nai.ilist.-iu'uey
    '
    r'rr':
    .:.a
    .,.::',:a'
    Histor-v
    .
    1979a.
    Survey
    Algal
    ':
    to
    rlynarnics
    f,onmonweaitir
    of
    Lake
    tdjson
    Sangchr'is
    Contpany,
    ancl
    Ctticagol
    Lake Shelbyville.
    IL.
    l;
    final
    report
    to
    Electric
    power
    Reseiictr
    Institute,
    palo
    Al
    to,
    cA.
    -
    ,
    . 1979b.
    Periphytorr
    of
    the
    Kankakee
    River.
    In R. w.
    larirnore
    and t4.
    l.rtu..(e9s.)
    Construction
    and
    preoperat
    ional
    aqua'tic
    monitorirrg
    progrd.l
    the
    Kankakee
    River.
    seconci
    annual report
    by
    illinojs
    Natural'Hjst5ry
    Survey to
    Conrnonwea'lth
    td
    i
    son Company',
    Ch
    icigo,
    I
    L:
    '.
    ,
    .
    '
    l9B0a"
    Alga!
    invesLigations
    of Coffeen
    Lake.
    In
    J.A., Tranqui
    I
    I i
    and
    -.._R.[.1.
    '
    Second
    Lar:irnore
    annual
    ,report:.from
    (erJs.
    )-Environmenbal
    lll inois l{atural
    Studies
    ltistory
    of CofTEerr
    Survey
    Uate,-SOition-5.
    i6
    CJniraf
    ,
    ll
    I
    inois
    ,Publ
    ic Service,Company
    (unputrl
    ished)
    _.
    lgtlOtr.
    Periphytort
    on artificial
    substrates
    in
    the
    Kankakee
    River
    and
    Horse Creek. ln
    R.
    il.
    Larinroro
    'and
    I',|.
    J. Sulc'
    (e
    ds.
    )
    Corrstruct
    ion ahrl
    ,'
    preoperationall?'quat
    jc
    monitoring
    progrdm
    for clie
    Karikakee
    River.
    Trrird
    annual report by
    Il I inois
    lt|atural
    Hi story
    Survey to
    Comnonrveal
    th
    tclison
    ,,
    Corlrpany,,.Chi'cago,
    IL
    (unpub'lished).
    Duf ford,
    lJ.
    H.
    ,
    L.
    ll.
    Coutant, s.
    0.
    swarjenero
    and
    S
    .
    'rl.
    lrJa
    it,g,
    lgll
    .
    irlater
    quality
    and
    biological investigations
    in the
    Lake Snelbyville
    basin.
    Annual
    report to
    UjS.
    Army Corps of
    Engineers,
    St.
    Louis,
    140.
    lllirrois
    t{aturai History Survey
    (unpubl
    ished).
    L
    lrtR^tiJRr-,
    ct lt0
    I
    for
    I
    t
    I
    T
    I
    I
    I
    I
    T
    I
    I
    I
    I
    I
    tt,
    l-
    l=
    t'-
    l'
    l,=.
    I:,..:
    ....:-'.
    5.2b

    il
    F.
    --Jiglosical
    .---t',s,
    f
    .'
    'r'laite,
    -investisatlons
    s:
    .0. lwadene
    in
    r,
    ine
    and
    iain
    L.
    !r.
    ir'urIyrl
    cor,.r.ln[,
    ri-
    r,iit,i,
    igzB,
    ilater
    il;;;l
    qua]iLy
    'repori
    arlrl
    ro
    !.s.
    ArTy
    colf]1
    9f [ngineers,
    St.
    Louis,
    r'10.
    lilinois
    r{arural
    nisri,,"y
    5itrvcy (unprrbl
    i
    she
    tt
    )
    Gurtz, l.l:
    l":..:
    lld
    g.14. f{eiss,
    1g74.
    tffrcr
    r;f
    Lherrnal
    sLress
    on
    phyt0plankLon
    prot|uctivityincondenserc0olingwa|r.'r.inJ.l,l'6ibborlsan<t''l.it.:
    ,
    ,)haritz,
    'Augusta,.
    GA.
    erls. Therrnal
    Ecology.
    €RDA synpoTTun
    series
    (c0HF-230505),.
    :
    llustedt,
    F,
    t930.
    tlaci
    I
    lariophyta
    (0i
    atomaceac).
    In
    pascher
    (ed.
    ).
    Die
    Susswasser
    Flora
    Mitteleuropas,
    tleft 10.
    G,tstaT-Fischer,
    jenol
    qt,O-pp.
    l'1i1ler,
    M.
    c:,
    G.
    H.
    ttater,
    I.
    H.
    Federic,
    arrd
    J.
    p.
    Reed,
    1926.
    tf
    fect,s
    of
    qowgr
    plalt
    operalion
    of
    the biota
    of
    ,a
    therrnal
    disclrarge
    canal.
    t1
    G.
    ti.
    '
    Esch
    and R.
    l{.
    l''lcFarlane,
    erls. lherrnal
    Ecology
    I
    I.
    fn6n Synposiufr
    series
    (C0NF
    -75A425),
    Augusta,
    GA.
    Horan,
    R.
    (in press),
    .
    qnytoplankton
    dynarnics
    in
    a
    cooling-na[er- reservoir.
    In
    R.
    hist9119f.an
    pp.
    l,l.
    320-341.
    Larimore-i!9
    Iilinois
    J: A..Tranqui
    coolinq
    iake.
    il i
    eds.
    il1,
    Lake
    NaL.
    sangctriis
    Hi;r.:
    surv.
    sttrdy:
    siil,-iZiql.
    case
    -
    l'lorgan,
    1:
    P.,
    ll,
    and
    R.
    G.
    st.ross.
    rg6g.
    0estruction
    of
    phyloplanktorr
    in
    the
    '
    !90_l
    't65-l7l
    ing
    water
    suptly
    of a steam-electric
    station.
    Crrcsipealb
    Sci.
    l0(j,4i;
    Patrick,
    Acad.
    .11.,
    Nat.
    and
    Sci.,
    C. Reirner.
    Philadelphia.
    I966.
    Tlre
    213
    d
    pp
    jaLorns
    of the
    tlrriLerl
    States,
    vol.
    I.
    _,
    and
    -Acatl.
    I[aT]-Sci.,
    Philadelphia.
    213
    pp
    Prescott,
    G. 1962,
    Algae
    of t,he
    western
    6reaL
    Lakes area,2nd
    etl. l.l.
    c.
    Brown,
    Dubuque,
    917
    pp.
    Shannon,
    C.E.
    .|948.
    A mathematical
    theory
    of
    conrnunication.
    Bel t
    System
    Tech
    .
    Jour .
    27:379-423,
    623-656.
    S.83
    smith,
    G.M. 1950.
    The fresh-water
    algae
    of
    the
    unitecr
    States,
    2ncl
    ed.
    I'1.
    C .
    Brown,
    Dubuque
    ,
    97
    7
    pp
    ,
    of
    I'l,linois,
    2nd
    ed. l.lc0raw-Hi
    Report
    on
    Coffeen
    Lake
    U.S.
    Environmental
    Protection
    Environ.
    Res.
    l-ab.,
    Corval lis.
    Report
    on
    Sanqchris
    Lake
    U.S.
    Environmental
    ProtecIion
    tnvjron.
    Res.
    Lab.,
    T
    i ffany,
    L.
    and M.
    Ur.
    i tton.
    l
    97l .
    The
    a
    I
    gae
    Book
    Co.,
    New York. 719
    pp.
    U.S.
    Environmental
    Protection
    Agency. l9i5a.
    I'bntgornery
    County Illinois
    EPA Region
    V.
    Agency
    tlorking
    Paper
    No.
    300. Corval
    I is
    ]'3
    PP'
    ':
    U.S.
    Environmental
    Protection
    Agency.
    l97Sb.
    Christian
    County Illino:is
    EPA
    Region V.
    ,igency
    t{or(ing
    iaper
    No.
    314.
    ',C6rvallis
    ll
    r::
    aa:,::

    U.S. Environmental
    Protection
    Agency.
    1975c.
    Report
    on
    Shelb.yvi
    I
    le
    1
    "
    leservoir'tbultrie
    and
    Sneiby
    Counties
    lllinbls €pA
    Reqion
    V,
    U,S.
    r
    ,
    ,.
    .
    I
    I
    :F.nvironment1lPrg!qction-Aqencytiorkinr1Paper|{o.3l5,.Corvallistnviron..
    Res,
    Lab.,
    Corvallis. l7
    pp.
    V.an.dert{erff'A.l953..A.newnrethodofconcentratingandcleaning
    .
    i
    diatoms
    attd
    otherr'organisms.l
    Verh. lnt. Ver.
    l-imno1, 12:276.
    '
    i..
    larriner,
    J.
    1,.,.and
    11.
    L. Brehmer.
    1966.
    Ihe
    effects of
    thermal'eff luents
    on,
    ....llldFineor.9anisms.Int.J.Air.l'IaterPollut,10:277-2B9,
    l{etzel,
    R.G. 1975.
    Limnology. t{.8. Saunders
    Co,,
    Philadelphia.
    743
    pp.
    t{illiams,
    L;
    G.
    '1964.
    Possible
    relationships between
    plankton-diatom
    species
    .
    I
    I
    I
    I
    I
    I
    I
    t
    I
    1,.
    I'
    ::
    ::
    l=
    I.
    l.
    I.
    .
    l'
    I'
    l-
    =
    li
    l.
    !.
    :=:
    5.28
    :::
    :;.-

    sEcTt0r{
    6
    Z0OPLA|{KTON
    0F C0l'ttliH L/iKt
    hy
    St
    ephen
    l{.
    l{a
    i
    t
    e
    ..
    ABSTRACT
    An,
    'investigftion
    of
    zooplankton
    rJynamics'at
    Cof
    feen
    Lake rvas
    conductecJ
    f
    rom
    '
    July 1978,to
    l{ovember 1980
    as
    part:of
    an
    jnterdiscipl
    inary
    effort
    to document
    ch.angesihwater..qualityinthecooling.lakeandreceivingstream'General
    information
    was obtaineO
    regardinq
    dynarniCs
    of
    zooplankton cormunities
    anrJ
    indi-'
    vidual
    species and
    of trends in
    standing'crop
    biomass.
    The
    overall structure
    qf
    zooplankton
    conmunities
    in Coffeen
    Lake closely
    resernbleJ-those
    reported
    for
    both
    Lake_ Sangchris,--a.cooling
    -lake,
    and'Lake
    She'lbyvi lle.
    That.the
    number
    or
    richness
    of
    species
    was lower within the cooling
    loop
    compared
    to cooler
    waters
    at'stations
    3
    and
    4
    may
    be
    the
    eonsequence
    of
    power plant
    perturbations,
    including
    heat,
    entrainment
    and increased water
    velocities. However, morpho-
    logical
    characteristics of the lake
    basin
    at
    Station
    4
    (e.9,
    the'railroad cause-
    wayi
    -.
    :
    p"oUubly
    promgted lit!ora'l
    cormunities
    that contained-taxa not
    found
    elsewhere
    in the lake.
    'There
    was
    little
    evidencg
    that the
    thermal
    gradient.
    .).,
    ristricts,
    '
    .
    ..-
    or
    '-
    -
    enhan-ceq
    _
    tfre- distribg!!on of taxa
    to
    any certain region of the
    ''i:'.
    l
    Iake-
    .:.::r-
    Lake
    morphology
    _'-1.---.-:
    and
    .
    --.
    year
    variations
    probably
    were
    the
    princjpal
    factors
    governing
    spatial
    distribution
    of
    species. Stations with high water tempera-
    ..:..
    --
    'tu.",
    during the warmeif
    months
    sustained unexpectedly high
    diversities
    of
    species,
    but
    probably
    a
    majority of
    those forms resided below the thermal
    plume.
    ,Rotifers
    were less
    tolerant
    of high
    temperatures:
    near
    the discharge
    than
    were
    '
    cladocerans and
    copepods.
    The organic
    fraction
    of
    plankton
    mass,
    increased
    with,
    distance
    from the
    discharge
    and
    reflected
    the
    settling characterstics
    of
    fly
    ash-slag
    particul.ates.
    The zooplankton, of
    Coffeen Lake
    were
    found,to,
    be
    produc--:
    tive and
    viable
    despite
    atypical
    temperature
    regimes,
    entrainment
    mortality,
    and
    ,unusual
    ::.:,,
    ''":"
    water chemistry.,:
    ,
    .-
    'Short-term
    projects
    investigated
    possible
    r,easons for',
    the
    paucity
    and
    infrequent
    occurrence
    of
    lgplglgg
    kindtU
    and
    Bosmila
    in
    ,Coffeen
    L:ake
    and,'assessed
    the usefulness
    of two.:methods for determinin.q zoo-
    '
    .:
    pJankton.entrainment.....]:.
    ,.
    ,'-.'.',
    ,,
    .:,
    .
    r
    :-l : :
    .',
    ,-
    '
    .i
    j
    6.1

    ',
    ,i
    '
    '
    ,,
    Itl
    IR0DUCT
    l0ll
    r,
    .
    "
    -----'--"
    Animal constituents::of
    the I
    imnoplankton
    that
    inhabit alectrical
    power
    planf
    coo!,ing
    lakes
    are
    subject
    to
    a wide
    variety
    of'unnaLurai
    conditions.
    .,Ireiquent
    concerns
    of environrnental
    studies
    of
    these systems:have
    cenl.ererJ
    on:
    (I) prob-
    lems'
    res'0ltinq frorn'additions of
    chlorine
    ancl
    other
    biocides
    to
    prevenL
    fotrl
    ing;
    (2)
    'effects
    of inter:nal-meehanical'forces
    within
    the
    plant,
    such as
    turbulence'
    pressure
    and'.vacuum;
    and,
    (3)
    excess
    heat containt'd
    in
    discharge
    cooling
    waters.
    These and
    other
    concerns,
    including:aslr.ponO
    etftuents,
    collllttu
    runoff,.
    and
    brine wastes,
    have led
    to
    a
    recent environmental
    studl'at
    Coffeen-Lake.
    This
    ,study
    wa's ch'arged
    with
    documenting'a
    change
    in'water
    quality
    conconvnitant
    with
    improvemgnts
    in
    water
    treatment
    procedures:;
    The overall
    purpose
    of
    the
    Coffeen
    Lake.study
    tvas
    to
    determine whether
    Coffeen
    Lake
    supports
    'aquat'ic'life
    c0nsis-
    tent
    with
    contemporary
    lake managemtint
    practi'ces
    and
    to
    assess
    the degree
    of
    '
    recovery.resultingfromtheconrr'rencementofnewwaste-watertreatmenLfaci|i...
    ties.
    .
    ,
    1
    .
    :,.
    'The
    scope of
    the
    first-year
    zooplankton
    work
    was
    oriented
    toward
    dssessinq
    the
    r
    -
    I i
    -L.
    ^a
    aL^
    :-
    status
    ot
    zooprankton
    communities
    in
    ljght,of
    the
    improvement.in
    the lakers
    :
    ::water
    qual
    ity.
    Specifical
    ly, information
    was obtained
    regarding
    numbers''
    com-
    position
    and
    distribution
    of species;
    species
    diversi+,y;
    absolute
    and
    relat ive
    abundance
    of
    rna'jor
    groups;
    and
    standing
    crop
    bjomass.'Although
    these
    calegor.ies
    were
    continued
    through
    Year
    2 for
    comparative
    purposes,
    additional
    efforts
    were
    directed
    toward
    several
    more
    specific
    ecological
    and
    methodoloqical
    questions
    which
    were
    developed
    as
    subprojects
    for
    this
    report.
    METHODS
    AI{D
    MATERIALS
    From
    July
    1978'through
    June
    1980,
    Coffeen
    Lake zooplankton
    communities
    were
    sam!teO
    monthly
    from
    six
    permanent locitions
    (fjg.
    l.2),
    four of
    which
    were
    intermutualjwithother..project...subgroups,i.e.,fi.sh,benthos,algae.T,9
    sampl
    inq
    stations
    were,,establ
    iihed
    within
    close
    proxirnity,of
    the
    plant;
    one
    was
    --".f
    .'..J
    ----
    locited'adjacent
    to.the
    intake'screens'and
    the
    other
    inmediately
    downstrean
    of
    the
    discharge'canal.
    0ccasionally,
    samples
    were
    procured
    from a
    6-m stratum
    at
    :.:
    ,.
    ,
    '-
    I
    ,
    ::
    '
    ,the,intake
    itation
    (Station
    X).
    ',::'
    !
    .:
    I
    .
    i:
    I
    I
    I
    -
    l
    I
    I
    I
    I
    I
    I
    ::
    -.:::
    f.
    I'
    i::,r
    :::::r:
    ,
    :
    :.:1:.-::
    :-
    :.
    a.
    :::
    ',:..::::-i
    ,:'
    .:
    /:',:a::,.
    .:.
    ';:.;!,':
    :..,'
    t:it,
    :!1::'.
    .;'
    ..'
    i::'
    ',
    :i+..:.. .:
    t"
    ;:,.:.
    "'
    :.
    i;fi..
    ,.
    -
    l;
    :::
    l-
    a.
    .
    ,,,,
    -
    -,,
    ll.,
    ,,
    li
    t,
    j-r-'
    -'
    .,
    ,,
    li,
    6.2
    ;'
    :

    i:l:.r:-:::
    a:..
    All
    monthly
    zooplankton
    collect{ons
    in
    Coffeen
    Lake
    consisted
    of
    tr-iplicate
    samples
    of the
    water
    column
    from
    lake
    bottrim
    to
    surface at
    each sraLion.
    Samples
    h,ere
    co
    I lected r+ith
    a
    submers
    ible.
    f i
    lter-pump
    apparatus
    {lf,r:i
    te, and
    0'Grady
    l9B0)
    that
    filtered
    BB
    llters
    of loke
    water
    per'minute,
    lt
    was lowered
    and
    raised
    such that
    all
    water
    strata were
    sampled
    equally. Ihe
    total volume
    filtered per
    sample
    was
    a
    function
    of
    time
    allottecl
    for
    pumping;
    in
    Coffeen
    Lake,
    a
    pumping
    duration
    of
    2
    minutes
    was
    adequate
    and
    thus
    the
    total volume
    filtered
    at
    each
    sampling
    location
    was dpproximately
    0.5
    m3.
    An
    ethanol-
    formalin
    solution
    was used
    in
    the field
    to
    kill
    and
    preserve
    the
    organisms
    irmediately
    af
    ter
    col lection.
    Analytical procedures
    began
    by diluting
    the
    concentrated
    field
    samples
    to 100-
    200
    ml, depending
    on
    organism density
    and
    amounts
    of debris
    and
    slag
    particles.
    Following
    sample
    homogenation,
    three
    1-ml
    subsamples
    were
    withdrawn
    and
    placecl
    in
    gridded
    Sedgewick-Rafter
    cel ls for icJentification
    and
    counts.
    Identifi66l 16n
    keys and
    other
    published
    literature
    usecl irr
    these
    analyses
    inclurled: Ahlstrom
    (1940,
    1943),
    Brooks
    (1957,
    le59;,
    {lhengalath
    (
    lgTt),
    tdmondson
    (1959).
    Goutden
    !t9qBl,
    Grothe
    and Grothe
    (lglt'),
    pennak
    (1978),
    smirnov
    (1924),
    t.,tilson
    (1959),
    l{i lson
    and
    Yeatfian
    (lgFg),
    a4d
    Yeat{n.l
    (1959).
    :
    Filtering,
    drying,
    and
    ashing
    procedures
    describecl
    by ApHA
    et al.
    (1976)
    were
    used
    to
    compute standing
    stocks
    of zoop)ankton
    biomass.
    The
    residues
    were
    reported
    in
    milligrams
    (mq)
    dry
    and ash-free
    weight
    per
    cubic
    meter
    (m3)
    or
    lake
    water.
    lile.thods
    palticular
    to
    the
    ancillary
    studies
    wi
    ll be brief
    ly descrioed
    within
    those'sub:sections
    of this report.
    '
    .:
    RE.qULTS AND
    DI
    SCUSS
    I ON
    COIiIPOSITIOf{,
    DISTRIBUTION
    Ai{D DIVERSITY
    OF
    SPECIES
    SpeciCs Cdmposition
    .'.
    :
    '
    ,
    The
    monthly
    structure
    of
    zooplankton'cormunities
    in Coffeen
    year
    study closely resembled
    those of both
    Lake Sangchris,
    a
    t
    ,::..-,:;
    -=,1
    ;,,,
    ;:a-.
    :
    ,"
    ,
    ,,',
    '
    '
    ..
    .
    6.3
    "
    ,
    '-
    Lake during
    this:2-
    cooling lake,
    and

    Lake Shelbyvi
    lle,:
    .
    f
    lood
    controlr,reservoir
    (both
    lokes are
    with
    jn
    B0
    krn of
    '
    '
    ',
    coffeeniLake),
    in 1976
    (uaite
    1979a)
    (Iable
    6.
    I
    ).
    The
    prerlominant
    tara
    in
    :
    Coffe€n
    Lake included
    32 rotifer5,
    25
    clarJocerans, and
    ll
    copepods.
    Althrluqtr
    the'.totals
    varied
    s'lightly from.Year:
    I to
    Year
    2,. they
    |rere
    well within
    thr
    expected range
    of
    year-to-year
    variatri
    lity.
    In
    compdrison lo
    year
    l,
    year
    -Z,.had
    fe*er
    total
    species
    at each
    station for
    all but
    fiye
    rnonthly
    coilections
    (Table
    6-Z)::,
    Except
    for September
    of
    Year
    2, the
    overall lake means for each npflth'
    ,
    were.greater
    in Year l. Furthermore,
    there
    was a significant difference
    in
    the
    overall
    lake
    medns
    of
    the
    two consecutive
    l-yea.
    periods (Student's
    t-test,0.0l
    levei).
    Lakewide
    comparisons
    of
    the
    number
    of zooplankton taxa in
    Coffeen:Lake
    showed
    that
    in virtually
    all
    collecting
    periods
    in
    Year 1,
    the numbers
    present
    at
    all
    stations
    in the
    cooling
    Ioop
    (discharee,
    Stations I
    and
    2,
    and intake)
    were
    lemarkably
    simi'lar'(Table 6.2).
    ,
    tlhile
    there weie
    fer.r trends
    ,showing'gradual
    increases
    or
    declines
    in species
    numbers
    in
    the direction
    of
    coolinq water flow,
    the mean
    numbers
    of species at the
    cooting
    loop
    stations, coliectively,
    were
    number of
    species at Stations
    3
    and
    4
    for
    any
    particular
    month. During
    Year
    2 the fewest
    number of
    taxa
    for all
    stations
    occurred in November
    and, with few
    exceptions, the
    qreatest
    number
    of
    taxa each
    month
    was at
    Station
    4"
    *h.ich was
    similar to
    the
    pattern
    reportecl
    for Year
    1,
    ",.'
    Contrary
    to observations in
    Year
    l,
    however,
    the
    species'numbers
    were highly
    variable throughout the
    cooling )oop
    in
    Year
    2. The
    lower
    overall number
    of
    species
    in
    the cooling loop
    (discharge,
    Stations
    I and 2,
    and intake)
    cornpared
    toithose
    drt
    Stat'io:ns:
    3,,and,,f,
    qlay.:
    be,the
    colseqgence of
    of heat,
    entrainment-
    '",
    related mortal
    ity, and
    water
    ueficity;'ai.i
    o1', which are
    synergistic
    conditions
    associated
    primarily
    with the former. 0n
    the other hand, the relatively
    shallow
    lt,''
    I::
    I.
    ...:
    l.,i:,r-:1
    I'.:,.:
    l.-"
    -::.
    I,:.
    I,::,'
    r..: l
    -:
    I
    I
    I
    I
    t
    I
    I
    I
    I
    I
    l'
    lrt
    I.:,:
    l,t'.
    '
    'tt'
    l,::
    r.r:.
    Ii'
    I.'..
    I!.1:
    I::.:::
    F
    l'=
    t:.,=
    t,,,'
    waters
    north of the
    railroad
    causeHay
    (Station
    4,and
    v'icinjty)
    appeared to
    l
    ,
    cooling
    loop.
    These
    observations were not
    unexi;ected due to,the
    unusual
    r
    morphology of
    the
    lake
    basin.
    0f:,the
    ,.'.:'
    rotiferan
    .l
    taxa
    r .,
    reported
    for.
    :
    Yeans
    :
    I and 2, more than 501
    belonged
    to,.the
    lor:jcate
    family
    Brachionidae. Dominant constituents from
    other
    families
    in-,
    ,,
    cluded
    the
    genera
    Synchaeta,
    poytiitttria,
    and
    Asplalchna.
    An
    unusually
    large
    .
    '
    6.4

    Table'6.1.
    Surmary
    of numbers of zooplanktor
    taxa
    collected
    in Coffeen
    Lake
    tn
    lJai te
    (1979a)
    .
    Coffeen
    Lake
    ffiFer/Tlle
    -
    YearT-
    rfen#fZ
    Lake
    Sanqchri
    s
    t-ake
    Shelbyvi
    lle
    Taxa
    Rot
    i fera
    C I
    adocera
    Copepoda
    Total''
    .
    30
    2A
    t2
    62
    27
    29
    9
    65
    28
    2A
    9
    57
    27
    22
    11
    60
    6.5

    t
    l'
    GJ
    !o
    v,
    o
    .l|
    $.
    u!
    (u
    0,
    .L
    !E
    s
    (J
    ,l',.|
    ..
    o)
    J
    .o
    !
    c
    :F
    0
    (l)
    p
    .(J
    !
    \rl
    tr)
    F{
    (o
    cl\
    r'.
    H
    o\
    co
    EJ
    crr
    F
    (?)
    T\J
    Ol
    d
    <t
    tr)
    cv
    N'
    ra
    cn
    H
    o
    (\J
    c!
    cv
    d
    cv
    ff)
    d
    sr
    d
    cv
    H
    N
    NI
    (\,
    Or
    arl
    .J|
    qo
    fr)
    F{
    (\,
    r{
    <t
    rf)
    il
    lf)
    r.o
    ra
    d
    d
    m
    d
    cv
    ro
    c\t
    F{
    {-7)
    .{
    (\J
    rc)
    F.
    d
    Ol
    i\
    Ol
    d
    I
    @
    l'-
    ctr
    F{
    I
    Fl
    q
    trJ
    is
    I
    I
    L
    i=
    I
    Is
    H
    ...
    c0
    r\
    q
    ':
    r{:
    :
    \.
    :.
    t..
    -a
    F)
    :t
    :
    :.
    :.
    (U
    ..
    .r.
    |l'
    J,'
    c
    (u
    :
    (l|,.
    ,i,
    tF:
    l+;
    :.O
    (.)
    ,:
    :o:
    T+.
    E
    L
    ''
    :
    ':.lf:
    .(Ul
    :tF
    r+-
    a-l
    ,o
    Ec
    :-
    :
    tlj
    ><
    riJ
    ,9
    .o-c
    f
    -x
    c
    -.lo
    r
    o_
    ::
    o
    N
    :$:.
    tn
    ,-o
    .(u
    :L
    E
    rC
    .rO
    .P
    €:
    o:
    ''
    'q1
    :
    c
    +,
    ||Q
    :
    'ch
    oco
    EFa
    .L
    o(u
    (ul:
    .l
    F>
    ,
    :
    .>€
    F(tl
    -cf,po
    ...
    .oc
    CL
    =+,
    ..:
    .
    .(\.t
    :
    ,
    ':'i
    (o
    '
    ,:
    ..o:
    '..a:
    t
    :.t!
    .F
    it.,
    ;l::l'.
    .:::a:.
    :a::i::a
    .:
    :::a:':'
    ;,:.1:,.r.,,
    'ii:
    ar:
    :
    ..:.=.
    ;,.:.a:..
    :aaaa.a
    .
    -''
    ::,i;,:'.
    :t:":l:
    :;.::.:
    :
    a.j:..
    '
    :::.
    :
    :::l:.
    1.:1
    :
    i::r::'
    ,i-:
    ;::,.,
    '.::::.
    Ort
    .
    ;"
    al6
    F{
    cr)
    Ol
    d
    I
    ('t
    r\
    ch
    i
    I
    (\j
    &
    trJ
    H
    ot..
    ,o
    I:i.:+:';
    '
    -:,:
    =-
    a,.:
    ',
    -:it::'
    :=.
    r-:a,:
    .
    a=:.
    ::.1:
    ::
    ar:.:
    :
    +1'.,:,.
    :',a::
    :
    ::,,
    ;.,:,..
    =,.
    t.:'tl
    a
    r'',;1!
    ::a::-,
    rl-':
    .
    r
    ':...-:,.:
    :,
    Vt:|l'
    I')
    c<i
    --
    O,
    I
    .-i
    C
    .
    t
    .-
    O
    It
    rI
    ru
    CF O.
    c+J
    c
    L
    (!,
    rd
    O c,
    i!
    rO
    rt'
    (UJ
    EC)--.r
    (u
    o
    o
    o!
    >
    'U
    =(.r)c')
    OJ
    :-<
    g,
    UI
    C<f
    F
    (u
    |t':
    Lit
    I C
    I
    O
    FEc,
    '-{
    ':F
    -lJ
    .
    (t
    C-o-
    C+rC,:L(U
    ru
    o
    o
    d
    |u
    |D
    o-!/ L
    -Q
    O
    O
    O.|',
    >
    ro'O
    =(-)-.1
    =v)rr)
    o-j|+.

    /.:.:'.
    :t:::.
    fraction'ol''the'Year
    2, rotifer
    fauna
    con-sisted
    af unkno'ln
    typcs,
    primari
    l.y
    unidentlf|ablemalesaJr$irrmature]ifelris.iory.sLaqes
    The:cladoe'eran.'fauna,of
    Lat,e
    Coffeen
    in Year
    2
    ras
    rspresentr:d
    by
    2Q species
    and
    a,:':
    sii f
    ami
    lies,
    tlowevei,
    ,.,,-
    t' of
    fhese taxa,
    particuloriy
    tlre
    chydorids,.
    occurred
    inf
    requenily.
    i:
    Oapt!nia
    parJu13,
    0iaphannsomq
    l'gus!tdnberg
    ianum,
    !gt&@g[U.a
    quadrangul
    a, and
    Chydorus
    f.g!fail-[u!
    rtere
    the domi nant f
    orms
    in
    both study
    yeais.
    The
    payc!ty
    of Lep*ttjdgfa rlurirtg.-Years
    I and Z of this
    stucJy,
    aiso no-.:'d
    in
    the
    Lake
    Sanqchris study,
    suggested
    that
    certain condjtions
    (biological
    .
    and/or
    physicochernicel
    )
    associated
    with
    cool
    ing
    lakes
    may
    have
    prevented
    the,
    o.au..erce
    of this otherwise conmon
    taxon.
    ::
    The dominant copepods
    of Coffeen
    Lake in both
    Years
    I and 2 included
    the ca'la-
    noid,
    LiaptomuS
    sLciloides,
    and
    to
    a
    lesier eitent
    two cyciopoids, l4esocy_clopJ
    edii
    and.
    Cycl-epjs vernil
    is.
    !-.
    !.j-c"s.gj-{gtg-
    ttrbmqs-i
    ,
    a coldwater species',
    is'ra
    typical
    *inter:
    form
    in
    several
    Il
    l'inois
    ,'reservoirs
    (includinq
    Lake Sangchris)',
    :
    '.
    .
    .,:.,
    :-
    r'
    'i,
    :
    but:was rarely
    collected
    in
    Coffeen'Lake-
    Parasitic
    cyclopoicls
    on fistr,
    such
    as
    f
    riasi,!qs, have
    not
    been
    col lected in
    their
    f r:ee-l
    ivirig
    planktonic
    forrn. The'
    ,.
    ttrirO
    grder
    of
    copepods,
    Harpacticoida,'typica-11y
    inlrabit
    the
    substrate,
    ancl
    consequently
    only
    several
    individuals
    were
    col
    lect.erJ in fhe
    plankton.
    ,
    -,
    ..t'
    :
    ,
    t
    itt
    ,
    ti
    Previous analyles
    of':zooplankton
    popul'Jtions
    in
    Lake'Sancr-chrjs
    (19/5-1978)
    revealed
    an annual
    "damping"
    of
    the number of
    species
    present
    in
    the
    cooling'
    loop
    (l,lq1te
    I979a).
    In
    general,
    the
    numbers
    of species in
    temperate
    lakes
    exhibit cycl
    ic
    pulsei,
    unless
    natural
    ,u...rr'ion
    and
    periociicity
    u"u *OAified': by
    synergistic
    effects'
    of variou.,
    biological and
    phys
    icochemjca'l
    parameters.
    The
    'annual
    ::
    f lue tuations
    of
    spec'ies
    numbers
    'in
    the cooling loop at
    Cofl"een
    Lake
    rnore
    nearl.yresembledthe.typica]situation.wtrichwasexhibitedbypopulat,ionsin
    unheated.LakeShelbyvilie::apulseinspringand/or.summe|.foI.lowedbya
    gradual decrease
    to a
    late-winter
    .:.
    low.
    In light
    of
    the
    L,ake
    Sangchris data,
    this was:lan
    unlikely.result
    becauie
    the
    therma'l load
    (in
    megawatts
    per
    acre)
    at
    Coffeen'L.ake
    was
    much
    greater
    than
    that':of
    Lake Sangchris. If
    the
    damping
    ':
    effect
    on
    zooplankton
    species
    is
    indeed
    a function of waste
    heat loarls
    as
    :'imp,lied.for
    Sangchris'{ata,.
    then.O sitnilar
    damping should have
    been obierved
    for
    't
    '
    ,..
    .
    .: :
    '
    :
    .
    zooplankton
    populatiotrs
    in
    Coffeen
    Lake:
    Unless
    the'latter:, is
    a,
    very:,unusual:
    6.7
    ,ll

    '
    'i.'
    :t
    :,
    '
    'l
    ,
    iistem,
    lt
    .is
    postulated
    'that
    other:ccnditlons,
    in
    adrl'ition
    to
    or combined'wjth
    ,heot
    l'oadst,are'important:,
    in
    regulat'ing'zoopiankton
    blology
    in
    cool
    ing
    lakes"
    Iimp0fil-Di
    str
    i
    but
    i
    on
    o-f
    ,Spec
    ies
    R;tiiaiu.
    ',One
    rotifer,
    Polyarthra
    vulgaris,
    occurred
    in
    near'ly
    al I col lections'
    duri'ng'both
    study
    years.
    ,'This,
    species
    anO Sy-qshag!i stylata
    were
    the
    dominant
    anquql,
    forns.in Year,,2. Althouqh
    the
    brachignlds
    were well
    represented,
    the
    occurrence
    of
    individual
    species
    nas clearly.season-r'elated.
    In
    both
    year's'
    ,9I..[LqLr-l'anguialii'inhabited:a]l
    .lake
    areas'from May
    t.hrough
    0ctober while
    l-
    cauddtus and
    B.
    patulus
    occurred
    for
    a
    s\orte'ned
    duration
    in
    late summer.
    .r*i*p'*r.'*''."r*coolerwater,B.urc-e.blqriswasco|monfromFebrua1y
    through April
    in.
    both
    years
    whi'le
    r+iphane:
    sp. wa3
    col lected
    at
    ,all
    stations
    .i.
    primar.i]y
    :in
    January
    of Year
    2,
    Jui3r,
    Septe,nber,
    'February,
    and
    l'1ay samples
    cOn.
    rodied
    Asplanchna
    in Year" 2,
    but in
    Year
    I this species
    occurred
    iontinual.Jy
    frorn l,larch fr-oor.
    '
    ,'
    'i.
    .9.].adoc.9ra-.Atypicalconstiruentofthe.surn.ilerfaunaofmostlakesinthis
    region,
    0iaphanosoqg
    leuchtenbergianum
    occurrert
    frorn
    May through
    Decernher at
    most
    sampling
    stations
    in
    Coffeen
    Lake
    during
    both
    study
    years.
    That taxon,
    in
    'iOCit'ion
    to Daphnia garvula,
    Ceriodaphnia
    Su4fglltrt3,
    and
    Chydorus
    :ql'raqr,ic.us
    ..:
    :
    :
    .*erethefourmostpersistent.cladoceransinthe.|akeduringthestudy.
    '.8r
    .!!gitg*I-l
    was
    limited
    in
    both
    yearls
    to the
    mid- to late-spring
    .
    period
    (see
    anci
    I
    I
    ary study
    on
    Bor,Jnina)r.
    Three
    taxa, Ljj-aphanosonla
    brachyurum,
    '
    Leydigi
    a
    quadrangul
    ar
    i
    1,
    and
    CamptocSrcu:.
    Iggl!'qstri
    s.'
    were observed
    only
    in
    ;i.il
    '-tt,...t,.l'i:
    Copepoda.,
    gther
    than
    naupl
    ii
    anct
    Copepodids,.the'calanoid
    copeporl Diaptomu,s
    :jSil"id
    .was,not
    only
    [he
    most
    comrnon
    copepod
    but
    was
    also
    the
    rnost
    persistent
    ,i-ooptant<ter;
    it
    occurred
    in every
    sanp'le.
    0f
    ttre
    cyc'lopoid
    fauna, Cyc,lops
    ,
    '!
    ..vetlnans
    occurred
    in at least
    one
    station
    thr.oughout
    the study
    period.
    Mesocy-
    ,
    Jtops
    edax
    was
    also
    a
    dorninant
    cyclopoid
    species.
    All
    remaining
    taxa were spor"
    iOi.,:'in
    occurrence
    and
    the
    harpacti.coids
    were
    prevalent
    only
    from mid-summer
    to
    ...i.s.-11tt'-.
    "
    :
    ,,,,===,.:--'
    ,.
    I
    I
    I
    T
    I
    I
    T
    I
    I
    I
    t
    :l
    I
    ::
    t
    I
    ...
    t
    I
    6.B

    .:
    I
    '1.
    :,-:,,:ra
    ;l
    rI
    T
    I
    sp
    a
    !l-a_!_
    g
    Elr
    t
    !!lj_q.!__9!_lp$
    i e
    t
    tspatlial.distributlon
    was stud'ed
    toi'dererrnrne
    -i
    f
    any.taxa
    'rierere0nsist*rr!
    i=v
    ',,
    limitecJ"to
    or
    €xclrtded
    frorn
    any
    par"licllar
    .ragion{s)
    of
    t}re
    iake,
    Rclal'ively,.
    ,few',taxa
    were restricted
    to
    one station
    or,even
    ofie
    qener(tl
    rsqr'on.
    ligg'
    '
    gllJ$alUns,
    a liitoral
    :a:
    clarJoceranr
    was
    found
    only
    in
    tne
    0ecemher
    coliection
    ,
    ,at
    the
    discharge
    s-tation
    in:Year
    l; it
    was
    nrobobly
    swcpt through the
    plant
    from
    the intake
    rherp it'was:presenl in
    extraordinarily
    higii
    densities'on arti-
    ficial
    substrate
    sarnpiers
    in November
    of
    Ycar'l
    {Buc}:ler
    I979),
    In'Year
    ?
    it
    |{as
    collected
    in
    December
    at
    Station
    4
    antJ in
    sonre cooling
    loop
    stations
    in May
    anct
    June
    1980.
    The brachionid
    roti:fers,
    Colur.ella
    sp. anrl
    Brac.hion.us
    variabjlis-
    were
    collected
    only at Stations
    I and 3,
    respectivelJ,
    rn
    Year
    l; neither
    were
    collected
    in
    Year
    2. ln Year I
    no
    species were
    founcJ
    exclusively
    at
    Station
    2
    or
    the
    intake
    canal,.
    In,Year
    2
    two claclocerans,
    f,loi.!1i
    Ul_L!1l
    anrl
    LgX[lg1g
    quadranqularis,
    were
    collected
    only
    at
    Station
    2, and two
    rotifers,
    !uclanis
    and
    '.Tricholria
    were collected in
    the
    intake
    regions exclu'sively;: Station
    4,
    ini.n
    was
    not a
    direct
    part
    of the
    coolinq lootr,
    favorerl
    the
    exclusive
    rlevelopment
    of
    several
    I
    ittoral
    species,
    including
    three
    copepod
    species,
    Leydigia
    acanthocer-
    cojdes,
    Brachionus rubeE, and
    0aph.nia
    lclodleri-.
    Species
    occurrinq
    only at
    Stations
    3
    and
    4
    combined were Alona
    g5!al,l,
    Ng[!g]gq
    sn. and
    !_qmp!g.g€_rcg:
    rectirostris,
    Qaphn-ia
    longj-r1eql-:_
    was
    thc only
    t-axon I
    imited
    to
    the
    f irst
    half
    'of
    the
    cooljng loop
    (discharge,
    stations
    1'and
    2) during Year
    1; it
    did
    not
    occur
    in
    Year 2.
    Taia collected
    only
    from
    cooling
    loop
    stations
    included
    .9.19[r-ryrbidentatg.(stations.land2),l4ytilinasp.(discharge,Stat.ion.2)'
    .'fr'lonostyla
    -[ll-q
    {
    intake,
    discharge,
    Station 2),
    A-lglg
    costata
    and
    A.-
    gutla_tq
    (stati.ons1and2)..The.occurrenceofthecyclopoidCyc.lops'/9II3.ij!-.was
    ,restricted
    to. the
    intake
    and
    stations
    3 and
    4.
    .
    tl"*__l*ears'to.be little
    conclusive
    evidence
    that the
    thermal
    gradient
    consjs-'
    ',tently
    restricts:or
    enhances the
    production
    o'f spec'if
    ic
    taxa within
    aiiy certain
    <-:
    -i^egion
    _'
    "
    of
    the lake.:'Rather,
    it
    is more
    likely that lake morphological featur'es
    h.'al.-'a
    .
    Cd6tip,
    pelagic
    versus
    shallow, littoral
    regions)
    and natural
    year-to-year
    varia-
    tions in
    population
    occurrence
    are
    the
    principal
    factors
    governing
    spatial
    dis-
    .
    tribut,ion. of
    species'.
    '-:.
    I:
    ',
    l.'
    t.,,lt
    ..,.
    '
    t:
    :i
    6.9

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