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JCAR35O61 1-0814065r01
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2
3
4
5
6
7
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9
TITLE
35:
ENVIRONMENTAL
PROTECTION
SUBTITLE
F:
PUBLIC
WATER
SUPPLIES
CHAPTER
I: POLLUTION
CONTROL
BOARD
PART
611
PRIMARY
DRINKING
WATER
STANDARDS
SUBPART
A:
GENERAL
CLErK’s
OFFtcr
UC
27
2Oe
10
Section
STATE
O
!LLN
11
611.100
Purpose,
Scope,
and
Applicability
POIIt
CQiwo
12
611.101
Definitions
13
611.102
Incorporations
by
Reference
14
611.103
Severability
15
611.105
Electronic
Reporting
16
611.107
Agency
Inspection
of PWS
Facilities
17
611.108
Delegation
to
Local
Government
18
611.109
Enforcement
19
61
1.1 10
Special
Exception
Permits
20
611.111
Relief
Equivalent
to
SDWA
Section
14 15(a)
Variances
21
611.112
Relief
Equivalent
to SDWA
Section
1416
Exemptions
22
611.113
Alternative
Treatment
Techniques
23
611.114
Siting
Requirements
24
611.115
Source
Water
Quantity
25
611.120
Effective
Dates
26
611.121
Maximum
Contaminant
Levels
and
Finished
Water
Quality
27
611.125
Fluoridation
Requirement
28
611.126
Prohibition
on Use
of Lead
29
611.130
Special
Requirements
for
Certain
Variances
and
Adjusted
Standards
30
611.131
Relief
Equivalent
to SDWA
Section
1415(e)
Small
System
Variance
31
611.160
Composite
Correction
Program
32
611.161
Case-by-Case
Reduced
Subpart
Y Monitoring
for Wholesale
and
Consecutive
33
Systems
34
35
SUBPART
B:
FILTRATION
AND
DISIM’ECTION
36
37
Section
38
611.201
Requiring
a
Demonstration
39
611.202
Procedures
for
Agency
Determinations
40
611.211
Filtration
Required
41
611.212
Groundwater
under
Direct
Influence
of
Surface
Water
42
611.213
No
Method
of
HPC
Analysis
43
611.220
General
Requirements
JCAR35O61
l-0814065r01
Point-of-Entry
Devices
Use
of
Point-of-Use Devices
or Bottled
Water
63
64
SUBPART
D: TREATMENT
TECHNIQUES
65
General Requirements
Acrylamide
and
Epichlorohydrin
Corrosion
Control
SUBPART
F: MAXIMUM
CONTAMINANT
LEVELS
(MCLs)
ANT)
MAXIIVWM
RESIDUAL DISINFECTANT
LEVELS
(MRDL5)
Old MCLs for
Inorganic Chemical
Contaminants
Revised
MCLs
for
Inorganic
Chemical
Contaminants
State-Only
Maximum Contaminant
Levels (MCLs)
for Organic Chemical
Contaminants
Revised MCLs
for Organic Chemical
Contaminants
Maximum Contaminant
Levels
(MCLs) for Disinfection
Byproducts
(DBP5)
Maximum Residual
Disinfectant
Levels (MRDLs)
Turbidity
(Repealed)
Microbiological Contaminants
Maximum
Contaminant
Levels
for Radionuclides
Beta Particle
and Photon
Radioactivity
(Repealed)
44
611.230
45
611.231
46
611.232
47
611.233
48
611.240
49
611.241
50
611.242
51
611.250
52
611.261
53
611.262
54
611.271
55
611.272
56
611.276
57
Filtration
Effective Dates
Source
Water
Quality
Conditions
Site-Specific
Conditions
Treatment
Technique Violations
Disinfection
Unfiltered
PWSs
Filtered
PWSs
Filtration
Unfiltered
PWSs:
Reporting and
Recordkeeping
Filtered PWSs: Reporting
and
Recordkeeping
Protection
during
Repair Work
Disinfection Following
Repair
Recycle Provisions
60
Section
61
611.280
62
611.290
58
SUBPART C: USE
OF
NON-CENTRALIZED
TREATMENT DEVICES
59
66
Section
67
611.295
68
611.296
69
611.297
70
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
86
Section
611.300
611.301
611.3 10
611.3 11
611.3
12
611.3 13
611.320
611.325
611.330
611.33 1
JCAR35O61
1-0814065r01
87
SUBPART
G:
LEAD
AND
COPPER
88
89
Section
90
611.350
General
Requirements
91
611.351
Applicability
of
Corrosion
Control
92
6
11.352
Corrosion
Control
Treatment
93
611.353
Source
Water
Treatment
94
611.354
Lead
Service
Line
Replacement
95
611.355
Public
Education
and
Supplemental
Monitoring
96
611.356
Tap
Water
Monitoring
for Lead
and
Copper
97
611.357
Monitoring
for
Water
Quality
Parameters
98
611.358
Monitoring
for
Lead
and
Copper
in
Source
Water
99
611.359
Analytical
Methods
100
611.360
Reporting
101
611.361
Recordkeeping
102
103
SUBPART
I:
DISINFECTANT
RESIDUALS,
DISINFECTION
BYPRODUCTS,
104
AND
DISINFECTION
BYPRODUCT
PRECURSORS
105
106
Section
107
611.380
General
Requirements
108
611.381
Analytical
Requirements
109
611.382
Monitoring
Requirements
110
611.383
Compliance
Requirements
111
611.384
Reporting
and
Recordkeeping
Requirements
112
611.385
Treatment
Technique
for
Control
of
Disinfection
Byproduct
(DBP)
Precursors
113
114
SUBPART
K:
GENERAL
MONITORING
AND
ANALYTICAL
REQUIREMENTS
115
116
Section
117
611.480
Alternative
Analytical
Techniques
118
611.490
Certified
Laboratories
119
611.491
Laboratory
Testing
Equipment
120
611.500
Consecutive
PWSs
121
611.510
Special
Monitoring
for
Unregulated
Contaminants
(Repealed)
122
123
SUBPART
L:
MICROBIOLOGICAL
MONITORING
124
AND
ANALYTICAL
REQUIREMENTS
125
126
Section
127
611.52
1
Routine
Coliform
Monitoring
128
611.522
Repeat
Coliform
Monitoring
129
6
11.523
Invalidation
of
Total
Coliform
Samples
JCAR35O61
1-0814065r01
130
611.524
SanitarySurveys
131
611.525
Fecal
Coliform
and E.
Coli Testing
132
611.526
Analytical
Methodology
133
611.527
Response
to Violation
134
611.531
Analytical
Requirements
135
611.532
UnfilteredPWSs
136
611.533
FilteredPWSs
137
138
SUBPART
M:
TURBIDITY
MONITORING
AND ANALYTICAL
REQUIREMENTS
139
140
Section
141
611.560
Turbidity
142
143
SUBPART
N:
INORGANIC
MONITORING
AND
ANALYTICAL
REQUIREMENTS
144
145
Section
146
611.591
Violation
of
a State
MCL
147
611.592
Frequency
of State Monitoring
148
611.600
Applicability
149
611.601
Monitoring
Frequency
150
611.602
Asbestos
Monitoring
Frequency
151
611.603
Inorganic
Monitoring
Frequency
152
611.604
Nitrate Monitoring
153
6 11.605
Nitrite
Monitoring
154
611.606
Confirmation
Samples
155
6
11.607
More
Frequent Monitoring
and Confirmation
Sampling
156
611.608
Additional
Optional
Monitoring
157
611.609
Determining
Compliance
158
611.610
Inorganic
Monitoring
Times
159
611.611
Inorganic
Analysis
160
611.612
Monitoring
Requirements
for Old
Inorganic
MCLs
161
611.630
Special Monitoring
for Sodium
162
611.631
Special
Monitoring
for
Inorganic
Chemicals
(Repealed)
163
164
SUBPART
0: ORGANIC
MONITORING
AND
ANALYTICAL
REQUIREMENTS
165
166
Section
167
611.640
Definitions
168
611.641
OldMCLs
169
611.645
Analytical
Methods
for
Organic Chemical
Contaminants
170
611.646
Phase
I,
Phase
II, and
Phase V
Volatile
Organic
Contaminants
171
611.647
Sampling
for
Phase I
Volatile
Organic
Contaminants
(Repealed)
172
611.648
Phase
II,
Phase
JIB, and
Phase V
Synthetic
Organic
Contaminants
JCAR35O61
1-0814065r01
173
611.650
Monitoring
for 36 Contaminants
(Repealed)
174
611.657
Analytical
Methods
for
36 Contaminants
(Repealed)
175
611.658
Special Monitoring
for
Organic
Chemicals
(Repealed)
176
177
SUBPART
P: THM
MONITORING
AND ANALYTICAL REQUIREMENTS
178
179
Section
180
611.680
Sampling,
Analytical,
and
other Requirements
181
611.683
Reduced
Monitoring
Frequency
(Repealed)
182
611.684
Averaging
(Repealed)
183
611.685
Analytical
Methods
(Repealed)
184
611.686
Modification
to
System
(Repealed)
185
611.687
Sampling
for THM
Potential
(Repealed)
186
611.688
Applicability
Dates
(Repealed)
187
188
SUBPART
Q: RADIOLOGICAL
MONITORING
AND
ANALYTICAL
REQUIREMENTS
189
190
Section
191
611.720
Analytical
Methods
192
611.731
Gross
Alpha
193
611.732
Beta Particle
and Photon
Radioactivity
194
611.733
General
Monitoring
and Compliance
Requirements
195
196
SUBPART
R:
ENHANCED
FILTRATION
AND
DISIN}’ECTION:
197
SYSTEMS
THAT SERVE
10,000
OR MORE
PEOPLE
198
199
Section
200
611.740
General
Requirements
201
611.741
Standards
for Avoiding
Filtration
202
611.742
Disinfection
Profiling
and
Benchmarking
203
611.743
Filtration
204
611.744
Filtration
Sampling
Requirements
205
611.745
Reporting
and
Recordkeeping
Requirements
206
207
SUBPARTS:
GROUNDWATER
RULE
208
Section
209
611.800
General
Requirements
and
Applicability
210
611.801
Sanitary
Surveys for
GWS
Suppliers
211
6
11.802
Groundwater
Source
Microbial
Monitoring
and Analytical
Methods
212
6 11.803
Treatment
Technique
Requirements
for
GWS
Suppliers
213
6 11.804
Treatment
Technique
Violations
for
GWS Suppliers
214
611.805
Reporting
and
Recordkeeping
for
GWS Suppliers
215
JCAR35O61
1-0814065r01
216
SUBPART
T:
REPORTING
AND RECORDKEEPING
217
218
Section
219
611.830
Applicability
220
611.831
Monthly Operating
Report
221
611.832
Notice
by Agency
(Repealed)
222
611.833
Cross
Connection
Reporting
223
611.840
Reporting
224
611.851
Reporting
MCL,
MRDL, and
other Violations
(Repealed)
225
611.852
Reporting
other Violations
(Repealed)
226
611.853
Notice
to
New Billing
Units
(Repealed)
227
611.854
General
Content of
Public Notice
(Repealed)
228
611.855
Mandatory
Health Effects
Language
(Repealed)
229
611.856
Fluoride
Notice
(Repealed)
230
611.858
Fluoride
Secondary
Standard
(Repealed)
231
611.860
Record
Maintenance
232
611.870
List
of
36 Contaminants
(Repealed)
233
234
SUBPART
U:
CONSUMER
CONFIDENCE
REPORTS
235
236
Section
237
611.881
Purpose
and
Applicability
238
611.882
Compliance
Dates
239
611.883
Content
of the Reports
240
611.884
Required
Additional
Health
Information
241
611.885
Report Delivery
and
Recordkeeping
242
243
SUBPART
V: PUBLIC
NOTIFICATION
OF
DRINKiNG
WATER
VIOLATIONS
244
245
Section
246
611.901
General Public
Notification
Requirements
247
611.902
Tier 1
Public
Notice:
Form, Manner,
and
Frequency
of
Notice
248
6 11.903
Tier 2
Public
Notice:
Form,
Manner,
and
Frequency
of Notice
249
611.904
Tier
3
Public
Notice:
Form, Manner,
and
Frequency
of
Notice
250
611.905
Content of
the Public
Notice
251
611.906
Notice
to New
Billing
Units or
New Customers
252
611.907
Special Notice
of the
Availability
of Unregulated
Contaminant
Monitoring
253
Results
254
611.908
Special Notice
for
Exceedence
of the Fluoride
Secondary
Standard
255
611.909
Special
Notice
for Nitrate
Exceedences
above the
MCL
by
a Non-Community
256
Water
System
257
611.910
Notice
by the Agency
on Behalf
of a
PWS
258
611.911
Special
Notice
for Cryptosporidium
JCAR35O61 1-0814065r01
259
260
SUBPART
W: INITIAL
DISTRIBUTION
SYSTEM
EVALUATIONS
261
Section
262
611.920
General
Requirements
263
611.921
Standard Monitoring
264
611.922
System-Specific
Studies
265
611.923
40/30 Certification
266
611.924
Very Small
System Waivers
267
611.925
Subpart
Y
Compliance
Monitoring
Location
Recommendations
268
269
SUBPART
X:
ENHANCED
FILTRATION
ANT) DISINFECTION
-
270
SYSTEMS
SERVING
FEWER
THAN
10,000
PEOPLE
271
Section
272
611.950
General
Requirements
273
611.951
Finished Water
Reservoirs
274
611.952
Additional
Watershed
Control
Requirements
for Unfiltered Systems
275
611.953
Disinfection
Profile
276
611.954
Disinfection
Benchmark
277
611.955
Combined Filter Effluent
Turbidity
Limits
278
611.956
Individual
Filter
Turbidity
Requirements
279
611.957
Reporting and
Recordkeeping Requirements
280
281
SUBPART
Y:
STAGE
2
DISINFECTION
BYPRODUCTS REQUIREMENTS
282
Section
283
611.970
General Requirements
284
611.971
Routine
Monitoring
285
611.972
SubpartY Monitoring
Plan
286
611.973
Reduced
Monitoring
287
611.974
Additional
Requirements
for Consecutive
Systems
288
611.975
Conditions Requiring
Increased
Monitoring
289
611.976
Operational
Evaluation
Levels
290
611.977
Requirements for
Remaining
on Reduced
TTHM and HAA5
Monitoring Based
291
on Subpart
I Results
292
611.978
Requirements for
Remaining
on Increased
TTHM and HAA5
Monitoring Based
293
on Subpart
I Results
294
611.979
Reporting and Recordkeeping
Requirements
295
296
SUBPART Z:
ENHANCED
TREATMENT
FOR
CRYPTOSPORIDIUM
297
Section
298
611.1000
General
Requirements
299
611.1001
Source
Water Monitoring
Requirements:
Source Water
Monitoring
300
611.1002
Source
Water
Monitoring
Requirements:
Sampling
Schedules
301
611.1003
Source
Water
Monitoring
Requirements:
Sampling
Locations
JCAR35O61 1-0814065r01
302
611.1004
Source
Water Monitoring
Requirements:
Analytical
Methods
303
611.1005
Source
Water Monitoring
Requirements:
Approved
Laboratories
304
611.1006
Source Water Monitoring
Requirements:
Reporting
Source Water Monitoring
305
Results
306
611.1007
Source Water
Monitoring Requirements:
Grandfathering
Previously
Collected
307
Data
308
611.1008
Disinfection
Profiling and Benchmarking
Requirements:
Requirements
When
309
Making a
Significant Change
in Disinfection
Practice
310
611.1009
Disinfection
Profiling and
Benchmarking
Requirements: Developing
the
311
Disinfection
Profile and Benchmark
312
611.1010
Treatment
Technique Requirements:
Bin
Classification
for
Filtered
313
SuppliersSystems
314
611.1011
Treatment
Technique Requirements:
Filtered
System Additional
315
Cryptosporidium
Treatment
Requirements
316
611.1012
Treatment Technique
Requirements:
Unfiltered
System Cryptosporidium
317
Treatment
Requirements
318
611.1013
Treatment Technique
Requirements:
Schedule
for Compliance with
319
Cryptosporidium
Treatment Requirements
320
611.1014
Treatment Technique
Requirements:
Requirements
for Uncovered
Finished
321
Water
Storage Facilities
322
611.1015
Requirements
for Microbial Toolbox
Components:
Microbial Toolbox
Options
323
for Meeting Cryptosporidium
Treatment Requirements
324
611.1016
Requirements
for Microbial
Toolbox Components:
Source
Toolbox Components
325
611.1017
Requirements
for Microbial
Toolbox
Components:
Pre-Filtration
Treatment
326
Toolbox Components
327
611.1018
Requirements
for Microbial
Toolbox Components:
Treatment
Performance
328
Toolbox Components
329
611.1019
Requirements
for Microbial
Toolbox Components:
Additional
Filtration Toolbox
330
Components
331
611.1020
Requirements
for Microbial
Toolbox
Components:
Inactivation
Toolbox
332
Components
333
611.1021
Reporting and
Recordkeeping
Requirements:
Reporting Requirements
334
611.1022
Reporting
and
Recordkeeping
Requirements:
Recordkeeping
Requirements
335
611.1023
Requirements to
Respond to
Significant Deficiencies
Identified
in Sanitary
336
Surveys Performed
by USEPA
or the Agency
337
338
611 .APPENDIX
A
Regulated
Contaminants
339
611 .APPENDIX
B
Percent
Inactivation
of G. Lamblia
Cysts
340
611 .APPENDIX
C
Common
Names
of Organic
Chemicals
341
611 .APPENDIX D
Defined Substrate
Method for the
Simultaneous
Detection of Total
342
Coliforms and Eschericia
Coli
from Drinking
Water
343
611 .APPENDJX E
Mandatory Lead
Public
Education
Information
for Community
Water
344
Systems
JCAR35O61
1-0814065r01
Mandatory
Lead Public
Education
Information
for
Non-Transient
Non-
Community
Water Systems
NPDWR Violations
and
Situations
Requiring
Public
Notice
Standard
Health Effects
Language
for Public
Notification
Acronyms
Used
in
Public
Notification
Regulation
Total Coliform
Monitoring
Frequency
Fecal
or
Total Coliform
Density
Measurements
Frequency
of RDC
Measurement
Number
of Lead
and Copper
Monitoring
Sites
Lead
and Copper
Monitoring
Start Dates
Number
of Water
Quality
Parameter
Sampling
Sites
Summary
of Section
611.357
Monitoring
Requirements
for
Water Quality
Parameters
CT Values
(mgminJ)
for Cryptosporidium
Inactivation
by
Chlorine
Dioxide
CT
Values
(mgmintC)
for Cryptosporidium
Inactivation
by
Ozone
UV
Dose Table
for Cryptosporidium,
Giardia
lamblia,
and
Virus
Inactivation
Credit
Federal
Effective
Dates
364
AUTHORITY:
Implementing
Sections
7.2, 17,
and
17.5 and
authorized
by
Section
27 of the
Environmental
Protection
Act [415
ILCS 5/7.2,
17, 17.5,
and 27].
SOURCE:
Adopted
in R88-26
at 14
Iii.
Reg.
16517,
effective
September
20, 1990;
amended
in
R90-21
at 14111. Reg.
20448,
effective December
11,
1990;
amended
in R90-13
at 15111. Reg.
1562,
effective
January
22,
1991; amended
in R91-3
at 16 111.
Reg.
19010,
effective
December
1,
1992; amended
in
R92-3 at 17
Ill. Reg.
7796,
effective
May
18, 1993;
amended
in R93-1 at
17
Ill. Reg.
12650,
effective
July
23, 1993;
amended
in R94-4
at 18
Iii.
Reg.
12291,
effective
July
28, 1994;
amended
in R94-23
at 19 Ill. Reg.
8613,
effective
June 20,
1995;
amended
in R95-17
at 20
111. Reg.
14493,
effective October
22, 1996;
amended
in R98-2
at
22 Ill. Reg.
5020,
effective
March 5,
1998;
amended
in R99-6
at 23 Ill.
Reg. 2756,
effective
February
17, 1999;
amended
in R99-12 at
23
Ill. Reg.
10348,
effective August
11, 1999;
amended
in
R00-8 at 23
Ill.
Reg. 14715,
effective December
8, 1999;
amended
in R00-10
at 24 Ill.
Reg.
14226,
effective
September
11,2000;
amended
in
R01-7 at
25 Ill. Reg.
1329,
effective
January
11,2001;
amended
in
R01-20 at
25 Ill. Reg.
13611, effective
October 9,
2001; amended
in R02-5
at 26
Ill.
Reg. 3522,
effective
February
22,
2002; amended
in R03-4
at 27
Ill. Reg.
1183,
effective
January
10, 2003;
amended
in
R03-15
at 27 Ill. Reg.
16447,
effective October
10,
2003; amended
in
R04-3
at
28
Ill.
Reg.
5269, effective
March
10,
2004;
amended
in R04-13
at 28 Ill.
Reg. 12666,
effective
August 26,
2004; amended
in
R05-6
at 29
Ill. Reg. 2287,
effective
January
28, 2005;
amended
in R06-15
at
30 Ill.
Reg. 17004,
effective
October
13, 2006; amended
in
R07-2/R07-1
1
at 31111.
Reg.
11757,
effective
July
27, 2007; amended
in
R08-5/R08-71R08-13
at 32 Ill. Reg.
effective
345
346
347
348
349
350
351
352
353
354
355
356
357
358
359
360
361
362
363
611.APPENDIX
F
61
1.APPENDIX
G
611
.APPENDIX
H
611
.APPENDIX
I
611.TABLE
A
611.TABLE
B
611.TABLE
C
611.TABLE
D
611.TABLE
B
611.TABLE
F
611.TABLE
G
611.TABLE
H
611.TABLE
I
611.TABLE
J
611.TABLE
Z
365
366
367
368
369
370
371
372
373
374
375
376
377
378
379
380
381
382
383
384
385
386
387
JCAR35O61
1-0814065r01
388
SUBPART
A:
GENERAL
389
390
Section
611.102
Incorporations
by
Reference
391
392
a)
Abbreviations
and
short-name
listing of
references.
The following
names
and
393
abbreviated
names,
presented
in
alphabetical
order,
are
used
in this
Part to refer
to
394
materials
incorporated
by
reference:
395
396
“ASTM
Method”
means
a
method
published
by
and
available
from
the
397
American
Society
for
Testing and
Materials
(ASTM).
398
399
“Colisure
Test” means
“Colisure
Presence/Absence
Test
for
Detection
and
400
Identification
of Coliform
Bacteria
and
Escherichia
Coli in Drinking
401
Water,”
available
from
Millipore
Corporation,
Technical
Services
402
Department.
403
404
“Colitag®
Test”
means “Colitag®
Product
as
a
Test
for Detection
and
405
Identification
of Coliforms
and
E. coli Bacteria
in
Drinking Water
and
406
Source Water
as Required
in National
Primary
Drinking
Water
407
Regulations,”
available
from
CPI International.
408
409
“Detennination
of
Inorganic
Oxyhalide”
means
“Detennination
of
410
Inorganic
Oxyhalide
Disinfection
By-Products
in
Drinking
Water
Using
411
Ion Chromatography
with
the Addition
of a Postcolumn
Reagent
for
Trace
412
Bromate
Analysis,”
available
from
NTIS.
413
414
“Dioxin
and Furan
Method
1613”
means “Tetra-
through
Octa-Chlorinated
415
Dioxins
and Furans
by
Isotope-Dilution
HRGC/HRMS,” available
from
416
NTIS.
417
418
“E*Colite
Test”
means “Charm
E*Colite
Presence/Absence
Test for
419
Detection
and Identification
of Coliform
Bacteria
and Escherichia
coli
in
420
Drinking
Water,”
available
from Charm
Sciences,
Inc. and
USEPA,
Water
421
Resource
Center.
422
423
“EC-MUG”
means
“Method
9221
F:
Multiple-Tube
Fermentation
424
Technique
for Members
of
the Coliform
Group,
Escherichia
coli
425
Procedure
(Proposed),”
available
from
American
Public Health
426
Association
and
American
Waterworks
Association.
427
428
“Enterolert”
means “Evaluation
of
Enterolert
for
Enumeration
of
429
Enterococci
in
Recreational
Waters,”
available
from
American
Society
for
430
Microbiology.
JCAR35O61
1-0814065r01
431
432
“Georgia
Radium
Method”
means “The
Determination
of
Radium-226
and
433
Radium-228
in
Drinking
Water
by
Gamma-ray
Spectrometry
Using
HPGE
434
or
Ge(Li)
Detectors,”
Revision
1.2,
December
2004,
available from
the
435
Environmental
Resources
Center,
Georgia
Institute
of
Technology.
436
437
“GLI
Method
2”
means
GLI
Method 2,
“Turbidity,”
Nov.
2, 1992,
438
available
from Great
Lakes
Instruments,
Inc.
439
440
“Hach FilterTrak
Method
10133”
means
“Determination
of
Turbidity
by
441
Laser
Nephelometry,” available
from Hach
Co.
442
443
“HASL Procedure
Manual”
means
HASL
Procedure
Manual,
HASL 300,
444
available
from ERDA
Health
and
Safety Laboratory.
445
446
“ITS
Method
D99-003”
means Method
D99-003,
Revision
3.0,
“Free
447
Chlorine
Species
(HOCk
and
0C1)
by Test
Strip,” available
from
448
Industrial
Test
Systems,
Inc.
449
450
“Kelada
01” means
“Kelada
Automated
Test
Methods
for
Total Cyanide,
451
Acid Dissociable
Cyanide,
And Thiocyanate,”
Revision
1.2, August
2001,
452
EPA
821/B-01/009,
available
from
the
National
Technical
Information
453
Service (NTIS).
454
455
“m-ColiBlue24
Test”
means
“Total Coliforms
and
E.
coli Membrane
456
Filtration
Method
with m-ColiBlue24®
Broth,”
available
from
Hach
457
Company
and USEPA,
Water
Resource
Center.
458
459
“Membrane
Filter
Technique
using Chromocult
Doliform
Agar”
means
460
“Chromocult
Coliform
Agar Presence/Absence
Membrane
Filter
Test
461
Method
for
Detection
and Identification
of Coliform
Bacteria
and
462
Escherichia
coli in Finished
Waters,”
available
from
EMD Chemicals
Inc.
463
464
“NA-MUG”
means
“Method
9222
G: Membrane
Filter
Technique
for
465
Members
of
the Coliform
Group,
MF
Partition
Procedures,”
available
466
from
American
Public
Health
Association
and American
Waterworks
467
Association.
468
469
“NCRP”
means “National
Council
on Radiation
Protection.”
470
471
“NTIS”
means
“National
Technical
Information
Service.”
472
473
“New
Jersey
Radium Method”
means
“Determination
of
Radium 228
in
JCAR35O61
1-0814065r01
474
Drinking
Water,”
available
from the New
Jersey
Department
of
475
Environmental
Protection.
476
477
“New
York Radium
Method”
means
“Determination
of Ra-226
and
Ra
478
228
(Ra-02),” available
from
the New
York
Department
of Public
Health.
479
480
“01
Analytical
Method
OIA-1677”
means
“Method
OIA-1677,
DW
481
Available
Cyanide by
Flow
Injection,
Ligand
Exchange,
and
482
Amperometry,”
available
from ALPKEM,
Division
of
01 Analytical.
483
484
“ONPG-MUG
Test” (meaning
“minimal
medium
ortho-nitrophenyl-beta
485
d-galactopyranoside-4-methyl-umbelliferyl
-beta-d-glucuronide
test”),
486
also
called
the
“Autoanalysis
Colilert
System,”
is Method
9223, available
487
in
“Standard Methods
for
the
Examination
of Water
and
Wastewater,”
488
l8’,
19
th
20
th
or
21
st
ed.,
from American
Public
Health
Association
and
489
the American
Water
Works Association.
490
491
“Palintest
Method
1001”
means
“Method
Number
1001,”
available from
492
Palintest,
Ltd. or
the Hach
Company.
493
494
“QuikChem
Method
lO-204-00-l-X”
means
“Digestion
and distillation
of
495
total
cyanide
in
drinking
and wastewaters
using
MICRO
DIST and
496
determination
of cyanide
by flow
injection analysis,”
available
from
497
Lachat
Instruments.
498
499
“Readycult
Coliforms
100
Presence/Absence
Test” means
“Readycult
500
Coliforms
100 Presence/Absence
Test
for
Detection
and
Identification
of
501
Coliform
Bacteria and
Escherichia
coli in
Finished Waters,”
available
502
from
EMD
Chemicals
Inc.
503
504
“SimPlate
Method”
means
“IDEXX
SimPlate
TM
HPC
Test Method
for
505
Heterotrophs
in Water,”
available from
IDEXX
Laboratories,
Inc.
506
507
“Radiochemical
Methods”
means “Interim
Radiochemical
Methodology
508
for Drinking
Water,”
available
from
NTIS.
509
510
“Standard
Methods”
means
“Standard
Methods
for
the
Examination
of
511
Water
and Wastewater,”
available
from the
American
Public Health
512
Association
or the American
Waterworks
Association.
513
514
“Standard
Methods
Online” means
the website
maintained
by
the Standard
515
Methods
Organization
(at
www.standardmethods.org)
for purchase
of
the
516
latest versions
of
methods in
an electronic
format.
JCAR35O61
1-0814065r01
517
518
“Syngenta
AG-625”
means
“Atrazine
in Drinking
Water
by
519
Immunoassay,
February
2001
is available
from
Syngenta
Crop
520
Protection,
Inc.
521
522
“Technical
Bulletin
601”
means
“Technical
Bulletin
601, Standard
523
Method
of
Testing
for
Nitrate
in
Drinking
Water,”
July
1994,
available
524
from
Analytical
Technology,
Inc.
525
526
“Technical
Notes
on Drinking
Water
Methods”
means
the
USEPA
527
document
by
that
title, October
1994,
USEPA
document
number
EPA
528
600/R-94/173,
available
from NTIS.
529
530
“Technicon
Methods”
means
“Fluoride
in Water
and
Wastewater,”
531
available
from
Bran
& Luebbe.
532
533
“USDOE
Manual”
means
“EML
Procedures
Manual,”
available
from
the
534
United
State
Department
of
Energy.
535
536
“USEPA
Asbestos
Methods-100.1”
means
Method
100.1,
“Analytical
537
Method
for
Determination
of Asbestos
Fibers
in
Water,”
September
1983,
538
available
from
NTIS.
539
540
“USEPA
Asbestos
Methods-100.2”
means
Method
100.2,
“Determination
541
of
Asbestos
Structures
over
10-mm
in
Length
in Drinking
Water,”
June
542
1994,
available
from
NTIS.
543
544
“USEPA
Environmental
Inorganics
Methods”
means
“Methods
for
the
545
Determination
of
Inorganic
Substances
in Environmental
Samples,”
546
August
1993,
available
from NTIS.
547
548
“USEPA
Environmental
Metals
Methods”
means
“Methods
for
the
549
Determination
of Metals
in Environmental
Samples,”
available
from
550
NTIS.
551
552
“USEPA
Inorganic
Methods”
means
“Methods
for Chemical
Analysis
of
553
Water
and
Wastes,”
March
1983,
available
from
NTIS.
554
555
“USEPA
Interim
Radiochemical
Methods”
means
“Interim
Radiochemical
556
Methodology
for
Drinking
Water,”
EPA 600/4-75/008
(revised),
March
557
1976.
Available
from
NTIS.
558
JCAR35O61
1-0814065r01
559
“USEPA
Method
1600”
means
“Method
1600:
Enterococci
in
Water
by
560
Membrane
Filtration
Using
Membrane-Enterococcus
Indoxyl-b-D
561
Glucoside
Agar
(mET),”
available
from USEPA,
Water
Resource
Center.
562
563
“USEPA
Method
1601”
means “Method
1601:
Male-specific
(Frn)
and
564
Somatic
Coliphage
in Water by
Two-step
Enrichment
Procedure,”
565
available
from USEPA,
Water
Resource
Center.
566
567
“USEPA
Method
1602” means
“Method
1602: Male-specific
(F) and
568
Somatic
Coliphage
in Water
by
Single
Agar Layer
(SAL)
Procedure,”
569
available
from USEPA,
Water
Resource
Center.
570
571
“USEPA
Method
1604”
means “Method
1604:
Total Coliforms
and
572
Escherichia
coli in Water
by Membrane
Filtration
Using
a Simultaneous
573
Detection Technique
(MT
Medium),”
available
from USEPA,
Water
574
Resource
Center.
“USEPA
NERL
Method
200.5
(rev.
4.2)”
means
Method
200.5, Revision
4.2,
“Determination
of
Trace Elements
in Drinking
Water
by Axially
Viewed
Inductively-Coupled Plasma
— Atomic
Emission
Spectrometry,”
October 2003,
EPA 600/R-06/1
15.
Available
from the
USEPA, Office
of
Research
and Development.
“USEPA
Method 1622
(05)”
means
“Method
1622:
Cryptosporidium
in
Water
by
FiltrationllMS/FA,”
December
2005, available
from
USEPA,
Office
of Ground
Water
and Drinking
Water.
“USEPA
Method
1622
(01)” means
“Method
1622:
Crtosporidium
in
Water
by Filtration/IMS/FA,”
April 2001,
available
from USEPA,
Office
of Ground
Water
and
Drinking
Water.
575
576
577
578
579
580
581
582
583
584
585
586
587
588
589
590
591
592
593
594
595
596
597
598
599
600
601
“USEPA
Method 1622
(99)”
“Method
1622:
Cr idium
in
Water
by Fi1tratiom’TMSA,”
January
1999,
available
from USEPA,
Office of
Ground Water
and Drinking
Water.
“USEPA
Method 1623
(05)”
means
“Method
1623:
Crytosporidium
and
Giardia in
Water
by
Filtration/S/FA,”
December
2005,
available
from
the
US
EPA,
Office
of Ground
Water
and
Drinking Water.
“USEPA
Method
1623 (01)”
means “Method
1623:
Crtosporidium
and
Giardia
in Water
by
Fi1tration/SA,”
April
2001, available
from
USEPA,
Office
of
Ground
Water
and Drinking
Water.
JCAR35O61
1-0814065r01
602
“USEPA Method
1623
(99)”
means “Method 1623:
Cryptosporidium
and
603
Giardia
in Water by FiltrationS/FA,”
April
1999, available from
the
604
USEPA,
Office of Ground
Water and Drinking
Water.
605
606
“USEPANERL
Method
415.3
(rev. 1.1)”
means Method 415.3,
Revision
607
1.1, “Determination
of
Total Organic Carbon
and Specific
UV
Absorbance
608
at 254
nm
in Source
Water and Drinking
Water,”
USEPA,
February
2005,
609
EPA
600/R-05/055.
Available from
the USEPA,
Office
of Research
and
610
Development.
611
612
“USEPA
OGWDW
Methods” means one
of the methods
listed as
613
available
from the USEPA,
Office
of Ground Water and
Drinking Water
614
(Methods
317.0
(rev.
2.0),
326.0
(rev.
1.0), 327.0
(rev.
1.1),
515.4
(rev.
615
1.0), 531.2
(rev. 1.0),
ad-552.3 (rev. 1.0),
1622
(99),
1622
(01),
1622
616
(05),
1623
(99),
1623
(01),
and 1623
(05)).
617
618
“USEPA
Organic Methods”
means “Methods
for
the Determination
of
619
Organic
Compounds in Drinking
Water,” July
1991,
for
Methods
502.2,
620
505, 507,
508,
508A, 515.1,
and
531.1; “Methods
for
the Determination
of
621
Organic
Compounds in
Drinking Water — Supplement
I,”
July 1990, for
622
Methods
506, 547, 550, 550.1,
and
551;
“Methods for the Determination
623
of Organic
Compounds
in Drinking Water
— Supplement
II,” August
624
1992,
for Methods 504.1,
508.1,
515.2,
524.2, 525.2, 548.1,
549.1,
552.1,
625
552.2,
and
555; a4-”Methods
for
the Determination of
Organic
626
Compounds
in Drinking
Water — Supplement
III,” August
1995, for
627
Methods 502.2, 524.2,
551.1, and
552.2. Method 515.4,
“Determination
628
of Chlorinated
Acids
in Drinking Water
by Liquid Liquid
629
Microextraction, Derivatization
and
Fast Gas Clomatography
with
630
Electron
Capture
Detection,”
Revision
1.0,
April 2000,
EPA 815/B
631
00/001, and Method
531.2, “Measurement
of
N
methylcarbamoyloximes
632
and
N
methylcarbamates
in
Water by Direct
Aqueous
Injection HPLC
633
with Postcolumn
Derivatization,”
Revision
1.0, September
2001, EPA
634
815/B
01/002, are both available
on line
from USEPA,
Office of Ground
635
Water and
Drinking
Water.
636
637
“USEPA
Organic
and
Inorganic Methods”
means “Methods
for the
638
Determination
of Organic
and Inorganic
Compounds
in Drinking Water,
639
Volume
1,” EPA 815/R-00/014,
PB2000-106981,
August
2000. Available
640
from
NTIS.
641
642
“USEPA Radioactivity
Methods”
means “Prescribed
Procedures
for
643
Measurement
of Radioactivity in
Drinking Water,”
EPA 600/4-80/032,
644
August 1980.
Available from
NTIS.
JCAR35O61
1-0814065r01
645
646
“USEPA
Radiochemical
Analyses”
means
“Radiochemical
Analytical
647
Procedures
for
Analysis
of
Environmental
Samples,” March
1979.
648
Available
from
NTIS.
649
650
“USEPA Radiochemistry
Methods”
means
“Radiochemistry
Procedures
651
Manual,”
EPA
520/5-84/006,
December
1987.
Available
from
NTIS.
652
653
“USEPA
Technical
Notes”
means
“Technical Notes
on
Drinking
Water
654
Methods,”
available
from
NTIS.
655
656
“USGS
Methods”
means
“Methods
of
Analysis
by
the
U.S.
Geological
657
Survey
National
Water
Quality
Laboratory
—
Determination
of
Inorganic
658
and
Organic
Constituents
in
Water
and Fluvial
Sediments,”
available
from
659
NTIS
and
USGS.
660
661
“Waters
Method
B-lOll”
means
“Waters Test Method
for
the
662
Determination
of
Nitrite/Nitrate
in Water
Using
Single
Colunm
Ion
663
Chromatography,”
available
from
Waters
Corporation,
Technical
Services
664
Division.
665
666
b)
The
Board
incorporates
the
following
publications
by
reference:
667
668
ALPKEM,
Division
of
UI Analytical,
P.O.
Box
9010.
College
Station,
TX
669
77842-9010, telephone:
979-690-1711,
Internet:
www.oico.com.
670
671
“Method
OLk-1677
DW,
Available
Cyanide
by
Flow
Injection,
672
Ligand
Exchange,
and
Amperometry,”
EPA
821/R-04/001,
673
January
2004
(referred
to as
“01
Analytical
Method
OIA-1677”),
674
referenced
in Section
611.611.
675
BOARD
NOTE:
Also
available
online
for
download
from
676
www.epa.
gov/waterscience/methods/methodlcyanide!1
677-
677
2004.pdf.
678
679
APHA.
American
Public
Health
Association,
1015
Fifteenth
Street
NW,
680
Washington,
DC
20005
202-777-2742.
681
682
“Standard
Methods
for
the
Examination
of
Water
and
683
Wastewater,”
17
th
Edition,
1989
(referred
to as
“Standard
Methods,
684
17
th
ed.”).
See
the
methods
listed
separately
for
the
same
685
references
under
American
Waterworks
Association.
686
687
“Standard
Methods
for
the Examination
of Water
and
JCAR35O61
1-0814065r01
688
Wastewater,
18
th
Edition,
1992,
including
“Supplement
to the
18
th
689
Edition
of
Standard Methods
for
the Examination
of Water
and
690
Wastewater,”
1994
(collectively
referred
to as “Standard
Methods,
691
18
th
ed.”).
See
the methods
listed separately
for the
same
692
references
under
American
Waterworks
Association.
693
694
“Standard
Methods
for the
Examination
of Water
and
695
Wastewater,”
19
th
Edition,
1995
(referred
to
as “Standard
696
Methods,
19
th
ed.”). See
the methods
listed separately
for
the
697
same
references
under American
Waterworks
Association.
698
699
“Standard
Methods
for the Examination
of
Water
and
700
Wastewater,”
20
th
Edition,
1998
(referred
to
as
“Standard Methods,
701
2O’
ed.”).
See the
methods
listed separately
for the
same
702
references
under American
Waterworks
Association.
703
704
“Standard
Methods
for the Examination
of Water and
705
Wastewater,”
21
st
Edition,
2005
(referred
to
as “Standard
Methods,
706
21
st
ed.”).
See the
methods listed
separately
for the
same
707
references
under
American
Waterworks
Association.
708
709
American
Society
for Microbiology,
1752 N Street
N.W.,
Washington,
710
DC
20036,
202-737-3600:
711
712
“Evaluation
of
Enterolert
for Enumeration
of Enterococci
in
713
Recreational
Waters,”
Applied
and
Environmental
Microbiology,
714
Oct.
1996,
vol.
62, no. 10,
p.
3881
(referred
to as
“Enterolert”),
715
referenced
in
Section
611.802.
716
717
BOARD
NOTE:
At the table
to 40
CFR
141.402(c)(2),
USEPA
718
approved
the
method
as described
in
the above
literature review.
719
The
method
itself
is embodied
in the
printed
instructions
to
the
720
proprietary
kit
available
from
LDEXX Laboratories,
Inc.
721
(accessible
on-line
and
available
by download
from
www.asm.org,
722
as
“EnterolertTM
Procedure”).
ASTM approved
the
method
as
723
“Standard
Test Method
for
Enterococci
in
Water
Using
724
Enterolert
TM
,”
which
is available
in two
versions
from ASTM:
725
ASTM
D
6503-99
(superceded)
and
ASTM
D 6503-99
(2005).
726
While
it is more
conventional
to incorporate
the
method as
727
presented
in
the
kit
instructions
or
as approved
by ASTM
by
728
reference,
the
Board
is constrained
to incorporate
the
version that
729
appears
in
the
technical
literature
by
reference,
which
is the
730
version that
USEPA
has explicitly
approved.
JCAR35O61
1-0814065r01
731
732
AWWA.
American
Water
Works Association
et
al.,
6666 West
Quincy
733
Ave., Denver,
CO 80235
(303-794-771
1).
734
735
“National
Field
Evaluation
of a Defined
Substrate
Method
for
the
736
Simultaneous
Enumeration
of Total
Coliforms
and Escherichia
coli
737
for Drinking
Water:
Comparison
with
the Standard
Multiple
Tube
738
Fermentation
Method,”
S.C.
Edberg,
M.J.
Allen
& D.B.
Smith,
739
Applied
Environmental
Microbiology,
vol.
54, iss.
6,
pp
1595-
740
1601
(1988), referenced
in
Appendix
D to
this Part.
741
742
“Standard
Methods
for the
Examination
of
Water and
743
Wastewater,”
13
th
Edition, 1971
(referred
to
as
“Standard
Methods,
744
13
th
ed.”).
745
746
Method
302,
Gross Alpha
and Gross
Beta
Radioactivity
in
747
Water
(Total,
Suspended,
and
Dissolved),
referenced
in
748
Section
611.720.
749
750
Method
303,
Total Radioactive
Strontium
and Strontium
90
751
in Water,
referenced
in Section
611.720.
752
753
Method 304,
Radium
in Water
by
Precipitation,
referenced
754
in Section
611.720.
755
756
Method
305, Radium
226 by
Radon
in Water
(Soluble,
757
Suspended,
and Total),
referenced
in
Section
611.720.
758
759
Method
306,
Tritium
in
Water,
referenced
in Section
760
611.720.
761
762
“Standard
Methods
for the Examination
of
Water and
763
Wastewater,”
17
th
Edition, 1989
(referred
to
as “Standard
Methods,
764
17
th
ed.”).
765
766
Method
7110
B, Gross
Alpha
and Gross
Beta
Radioactivity
767
in
Water
(Total, Suspended,
and
Dissolved),
referenced
in
768
Section
611.720.
769
770
Method
7500-Cs B,
Radioactive
Cesium,
Precipitation
771
Method,
referenced
in Section
6
11.720.
772
773
Method
7500-
3
H
B, Tritium
in
Water,
referenced
in Section
JCAR35O61
1-0814065r01
774
611.720.
775
776
Method
7500-I
B,
Radioactive
Iodine, Precipitation
777
Method,
referenced
in
Section 611.720.
778
779
Method
7500-I
C,
Radioactive
Iodine,
Ion-Exchange
780
Method,
referenced
in
Section
611.720.
781
782
Method
7500-I
D,
Radioactive
Iodine,
Distillation
Method,
783
referenced
in
Section
611.720.
784
785
Method
7500-Ra
B,
Radium
in
Water
by
Precipitation,
786
referenced
in
Section
611.720.
787
788
Method
7500-Ra
C,
Radium
226
by
Radon
in Water
789
(Soluble,
Suspended,
and
Total),
referenced
in
Section
790
611.720.
791
792
Method
7500-Ra
D,
Radium, Sequential
Precipitation
793
Method
(Proposed),
referenced
in
Section
611.720.
794
795
Method
7500-Sr
B,
Total
Radioactive
Strontium
and
796
Strontium
90
in
Water,
referenced
in
Section
611.720.
797
798
Method
7500-U
B,
Uranium,
Radiochemical
Method
799
(Proposed),
referenced
in
Section
611.720.
800
801
Method
7500-U
C,
Uranium,
Isotopic Method
(Proposed),
802
referenced
in
Section
611.720.
803
804
“Standard Methods
for
the
Examination
of
Water
and
805
Wastewater,”
18
th
Edition,
1992
(referred
to
as
“Standard
Methods,
806
18thed.).
807
808
Method
2130
B,
Turbidity,
Nephelometric
Method,
809
referenced
in Section
611.531.
810
811
Method
2320
B,
Alkalinity,
Titration
Method,
referenced
in
812
Section6ll.611.
813
814
Method
2510
B,
Conductivity,
Laboratory
Method,
815
referenced
in
Section
611.611.
816
JCAR35061
1-0814065r01
817
Method 2550,
Temperature,
Laboratory and Field
Methods,
818
referenced
in Section 611.611.
819
820
Method 3111
B, Metals
by Flame Atomic Absorption
821
Spectrometry,
Direct
Air-Acetylene
Flame
Method,
822
referenced
in Sections 611.611
and 611.612.
823
824
Method
3111 D, Metals
by Flame Atomic
Absorption
825
Spectrometry,
Direct
Nitrous Oxide-Acetylene
Flame
826
Method,
referenced in Section
611.611.
827
828
Method 3112
B, Metals
by Cold-Vapor
Atomic Absorption
829
Spectrometry,
Cold-Vapor
Atomic Absorption
830
Spectrometric
Method,
referenced in Section
611.611.
831
832
Method 3113
B, Metals
by Electrothermal Atomic
833
Absorption
Spectrometry, Electrothermal
Atomic
834
Absorption
Spectrometric
Method, referenced
in Sections
835
611.611 and 611.612.
836
837
Method
3114 B, Metals by
Hydride
Generation!Atomic
838
Absorption
Spectrometry,
Manual Hydride
839
GeneratiorilAtomic
Absorption
Spectrometric
Method,
840
referenced
in Section 611.611.
841
842
Method
3120 B, Metals
by Plasma Emission
Spectroscopy,
843
Inductively-Coupled
Plasma
(ICP)
Method,
referenced
in
844
Sections
611.611 and 611.612.
845
846
Method
3500-Ca D, Calcium,
EDTA
Titrimetric Method,
847
referenced
in Section
611.611.
848
849
Method
3500-Mg E, Magnesium,
Calculation
Method,
850
referenced
in
Section 611.611.
851
852
Method 4110
B, Determination
of Anions
by Ion
853
Chromatography,
Ion
Chromatography with
Chemical
854
Suppression
of Eluent Conductivity,
referenced
in Section
855
611.611.
856
857
Method 4500-CN
C, Cyanide, Total
Cyanide after
858
Distillation, referenced
in
Section
611.611.
859
JCAR35061
l-0814065r01
860
Method 4500-CN
E,
Cyanide,
Colorimetric
Method,
861
referenced
in Section
611.611.
862
863
Method
4500-CN
F,
Cyanide,
Cyanide-Selective
Electrode
864
Method,
referenced
in Section
611.611.
865
866
Method
4500-CN
G,
Cyanide, Cyanides
Amenable
to
867
Chlorination
after Distillation,
referenced
in
Section
868
611.611.
869
870
Method
4500-Cl
D, Chlorine,
Amperometric
Titration
871
Method,
referenced
in Section
611.531.
872
873
Method
4500-Cl
E, Chlorine,
Low-Level
Amperometric
874
Titration
Method,
referenced
in Section
611.531.
875
876
Method 4500-Cl
F, Chlorine,
DPD Ferrous
Titrimetric
877
Method,
referenced
in Section
611.53 1.
878
879
Method
4500-Cl
G,
Chlorine,
DPD
Colorimetric
Method,
880
referenced
in Section
611.531.
881
882
Method
4500-Cl
H, Chlorine,
Syringaldazine
(FACTS)
883
Method,
referenced
in Section
611.53
1.
884
885
Method
4500-Cl
I, Chlorine,
lodometric
Electrode
Method,
886
referenced
in
Section 611.531.
887
888
Method
4500-Cl0
2
C,
Chlorine Dioxide,
Amperometric
889
Method
I,
referenced
in
Section 611.531.
890
891
Method
4500-Cl0
2
D, Chlorine
Dioxide,
DPD
Method,
892
referenced
in Section
611.531.
893
894
Method
4500-C10
2
E, Chlorine
Dioxide,
Amperometric
895
Method
II
(Proposed),
referenced
in
Section 611.531.
896
897
Method
4500-F
B, Fluoride,
Preliminary
Distillation
Step,
898
referenced
in
Section 611.611.
899
900
Method
4500-F
C,
Fluoride,
Ion-Selective
Electrode
901
Method,
referenced
in Section
611.611.
902
JCAR35O6I
1-0814065r01
903
Method 4500-V
D,
Fluoride,
SPADNS
Method,
referenced
904
in Section
611.611.
905
906
Method
4500-V E,
Fluoride,
Complexone
Method,
907
referenced
in Section
611.611.
908
909
Method
4500-Hf
B, pH
Value, Electrometric
Method,
910
referenced
in
Section
611.611.
911
912
Method
4500-N0
2
B,
Nitrogen
(Nitrite),
Colorimetric
913
Method,
referenced
in
Section 611.611.
914
915
Method
4500-N0
3
D,
Nitrogen (Nitrate),
Nitrate
Electrode
916
Method,
referenced
in Section
611.611.
917
918
Method
4500-N0
3
E,
Nitrogen
(Nitrate),
Cadmium
919
Reduction
Method,
referenced
in Section
611.611.
920
921
Method
4500-N0
3
F, Nitrogen
(Nitrate),
Automated
922
Cadmium
Reduction
Method,
referenced
in Section
923
611.611.
924
925
Method
4500-03
B,
Ozone
(Residual)
(Proposed),
Indigo
926
Colorimetric
Method,
referenced
in
Section 611.531.
927
928
Method
4500-P
E, Phosphorus,
Ascorbic
Acid
Method,
929
referenced
in
Section 611.611.
930
931
Method
4500-P
F, Phosphorus,
Automated
Ascorbic
Acid
932
Reduction
Method,
referenced
in Section
611.611.
933
934
Method
4500-Si
D, Silica,
Molybdosilicate
Method,
935
referenced
in Section
611.611.
936
937
Method
4500-Si
E, Silica,
Heteropoly
Blue Method,
938
referenced
in
Section 611.611.
939
940
Method
4500-Si
F, Silica,
Automated
Method
for
941
Molybdate-Reactive
Silica,
referenced
in Section
611.611.
942
943
Method
6651,
Glyphosate
Herbicide
(Proposed),
referenced
944
in Section
611.645.
945
JCAR35061
1-0814065r01
946
Method
7110
B,
Gross
Alpha
and Beta
Radioactivity
947
(Total, Suspended,
and
Dissolved),
Evaporation
Method
for
948
Gross
Alpha-Beta,
referenced
in Section
611.720.
949
950
Method
7110
C,
Gross
Alpha
and
Beta
Radioactivity
951
(Total,
Suspended,
and Dissolved),
Coprecipitation
Method
952
for
Gross
Alpha
Radioactivity
in Drinking
Water
953
(Proposed),
referenced
in Section
611.720.
954
955
Method
7500-Cs
B,
Radioactive
Cesium, Precipitation
956
Method,
referenced
in Section
611.720.
957
958
Method
7500-
3
H
B, Tritium,
Liquid
Scintillation
959
Spectrometric
Method,
referenced
in
Section 611.720.
960
961
Method 7500-I
B,
Radioactive
Iodine,
Precipitation
962
Method,
referenced
in Section
611.720.
963
964
Method
75 00-I
C,
Radioactive
Iodine, Ion-Exchange
965
Method,
referenced
in Section
611.720.
966
967
Method
7500-I
D, Radioactive
Iodine,
Distillation
Method,
968
referenced
in
Section 611.720.
969
970
Method
7500-Ra
B, Radium,
Precipitation
Method,
971
referenced
in
Section 611.720.
972
973
Method
7500-Ra
C, Radium,
Emanation
Method,
974
referenced
in
Section 611.720.
975
976
Method
7500-Ra
D, Radium,
Sequential
Precipitation
977
Method
(Proposed),
referenced
in
Section
611.720.
978
979
Method
7500-Sr
B, Total Radioactive
Strontium
and
980
Strontium
90, Precipitation
Method,
referenced
in
Section
981
611.720.
982
983
Method
7500-U
B,
Uranium,
Radiochemical
Method
984
(Proposed),
referenced
in
Section 611.720.
985
986
Method 7500-U
C, Uranium,
Isotopic
Method
(Proposed),
987
referenced
in Section
611.720.
988
JCAR35O61
1-0814065r01
989
Method 9215
B, Heterotrophic
Plate
Count,
Pour Plate
990
Method,
referenced
in Section
611.531.
991
992
Method 9221
A, Multiple-Tube
Fermentation
Technique
993
for Members
of
the
Coliform Group, Introduction,
994
referenced
in Sections
611.526
and 611.531.
995
996
Method
9221
B,
Multiple-Tube Fermentation
Technique
997
for
Members
of the
Coliform
Group,
Standard Total
998
Coliform
Fermentation
Technique, referenced
in Sections
999
611.526
and
611.531.
1000
1001
Method
9221
C, Multiple-Tube
Fermentation
Technique
1002
for Members
of the Coliform
Group,
Estimation of
1003
Bacterial
Density, referenced
in Sections
611.526
and
1004
611.531.
1005
1006
Method 9221
D,
Multiple-Tube
Fermentation
Technique
1007
for Members
of the Coliform
Group, Presence-Absence
(P
1008
A) Coliform
Test, referenced
in Section 611.526.
1009
1010
Method 9221
E,
Multiple-Tube
Fermentation
Technique
1011
for Members
of the
Coliform Group,
Fecal Coliform
1012
Procedure,
referenced
in Sections 611.526
and 611.531.
1013
1014
Method
9222
A,
Membrane Filter Technique
for Members
1015
of the
Coliform Group,
Introduction,
referenced in Sections
1016
611.526and611.531.
1017
1018
Method
9222 B,
Membrane Filter Technique
for
Members
1019
of the
Coliform
Group,
Standard
Total Coliform Membrane
1020
Filter
Procedure, referenced
in Sections
611.526
and
1021
611.531.
1022
1023
Method
9222
C, Membrane
Filter Technique
for
Members
1024
of the
Coliform Group,
Delayed-Incubation
Total Coliform
1025
Procedure,
referenced
in Sections
611.526 and 611.531.
1026
1027
Method
9222 D,
Membrane Filter
Technique for Members
1028
of
the
Coliform
Group,
Fecal
Coliform Membrane
Filter
1029
Procedure,
referenced in Section
611.531.
1030
1031
Method 9223,
Chromogenic
Substrate Coliform
Test
JCAR35O61
1-0814065r01
1032
(Proposed)
(also
referred
to as
the variations
“Autoanalysis
1033
Colilert
System”
and
“Colisure
Test”),
referenced
in
1034
Sections
611.526,
and 611.531.
1035
1036
Method
9223
B,
Chromogenic
Substrate
Coliform
Test
1037
(Proposed),
referenced
in Section
611.1004.
1038
1039
“Supplement
to the
l8t
Edition
of
Standard
Methods
for
the
1040
Examination
of Water
and Wastewater,”
American
Public
Health
1041
Association,
1994.
1042
1043
Method
6610,
Carbamate
Pesticide
Method,
referenced
in
1044
Section
611.645.
1045
1046
“Standard
Methods
for
the Examination
of Water
and
1047
Wastewater,”
l9’
Edition,
1995
(referred
to
as “Standard
Methods,
1048
19
th
ed.”).
1049
1050
Method
2130
B,
Turbidity,
Nephelometric
Method,
1051
referenced
in Section
611.53
1.
1052
1053
Method
2320
B,
Alkalinity,
Titration
Method,
referenced
in
1054
Section6ll.611.
1055
1056
Method
2510
B,
Conductivity,
Laboratory
Method,
1057
referenced
in
Section
611.611.
1058
1059
Method
2550,
Temperature,
Laboratory,
and Field
1060
Methods,
referenced
in
Section
611.611.
1061
1062
Method
3111
B, Metals
by
Flame Atomic
Absorption
1063
Spectrometry,
Direct Air-Acetylene
Flame
Method,
1064
referenced
in
Sections
611.611
and
611.612.
1065
1066
Method
3111
D, Metals
by
Flame Atomic
Absorption
1067
Spectrometry,
Direct
Nitrous
Oxide-Acetylene Flame
1068
Method,
referenced
in Section
611.611.
1069
1070
Method
3112
B,
Metals
by
Cold-Vapor
Atomic
Absorption
1071
Spectrometry,
Cold-Vapor
Atomic
Absorption
1072
Spectrometric
Method,
referenced
in Section
611.611.
1073
1074
Method
3113 B,
Metals
by Electrothermal
Atomic
JCAR35061
1-0814065r01
1075
Absorption
Spectrometry,
Electrothermal
Atomic
1076
Absorption
Spectrometric
Method,
referenced
in Sections
1077
611.611 and
611.612.
1078
1079
Method
3114
B, Metals
by
Hydride
GenerationlAtomic
1080
Absorption
Spectrometry,
Manual
Hydride
1081
GenerationlAtomic
Absorption
Spectrometric
Method,
1082
referenced
in Section
611.611.
1083
1084
Method
3120 B,
Metals
by
Plasma
Emission
Spectroscopy,
1085
Inductively-Coupled
Plasma
(ICP) Method,
referenced
in
1086
Sections
611.611
and 611.612.
1087
1088
Method
3500-Ca
D, Calcium,
EDTA Titrimetric
Method,
1089
referenced
in Section
611.611.
1090
1091
Method 3500-Mg
E,
Magnesium,
Calculation
Method,
1092
referenced
in Section
611.611.
1093
1094
Method
4110
B, Determination
of
Anions
by
Ion
1095
Chromatography,
Ion
Chromatography
with
Chemical
1096
Suppression
of Eluent
Conductivity,
referenced
in
Section
1097
611.611.
1098
1099
Method
4500-Cl
D, Chlorine,
Amperometric
Titration
1100
Method,
referenced
in Sections
611.381
and 611.531.
1101
1102
Method
4500-Cl
E, Chlorine,
Low-Level
Amperometric
1103
Titration
Method,
referenced
in Sections
611.381
and
1104
611.531.
1105
1106
Method
4500-Cl F,
Chlorine,
DPD
Ferrous
Titrimetric
1107
Method,
referenced
in Sections
611.381 and
611.531.
1108
1109
Method
4500-Cl
G, Chlorine,
DPD
Colorimetric
Method,
1110
referenced
in Sections
611.381
and
611.531.
1111
1112
Method
4500-Cl
H,
Chlorine,
Syringaldazine
(FACTS)
1113
Method,
referenced
in Sections
611.381
and 611.53
1.
1114
1115
Method
4500-Cl
I, Chlorine,
lodometric
Electrode
Method,
1116
referenced
in
Sections
611.381
and
611.531.
1117
JCAR35O61
1-0814065r01
1118
Method
4500-dO
2
C,
Chlorine
Dioxide,
Amperometric
1119
Method
I, referenced
in
Section
611.531.
1120
1121
Method
4500-C10
2
D,
Chlorine
Dioxide,
DPD
Method,
1122
referenced
in
Sections
611.381
and
611.531.
1123
1124
Method
4500-C10
2
E,
Chlorine
Dioxide,
Amperometric
1125
Method
II,
referenced
in
Sections
611.381
and
611.531.
1126
1127
Method
4500-CN
C,
Cyanide,
Total
Cyanide
after
1128
Distillation,
referenced
in
Section
611.611.
1129
1130
Method
4500-CN
E,
Cyanide,
Colorimetric
Method,
1131
referenced
in
Section
611.611.
1132
1133
Method
4500-CN
F,
Cyanide,
Cyanide-Selective
Electrode
1134
Method,
referenced
in
Section
611.611.
1135
1136
Method
4500-CN
G,
Cyanide,
Cyanides
Amenable
to
1137
Chlorination
after
Distillation,
referenced
in
Section
1138
611.611.
1139
1140
Method
4500-V
B, Fluoride,
Preliminary
Distillation
Step,
1141
referencedin
Section
611.611.
1142
1143
Method
4500-V
C,
Fluoride,
Ion-Selective
Electrode
1144
Method,
referenced
in
Section
611.611.
1145
1146
Method
4500-V
D,
Fluoride,
SPADNS
Method,
referenced
1147
in
Section
611.611.
1148
1149
Method
4500-V
E,
Fluoride,
Complexone
Method,
1150
referenced
in
Section
611.611.
1151
1152
Method
4500-H
B,
pH
Value,
Electrometric
Method,
1153
referenced
in
Section
611.611.
1154
1155
Method
4500-N0
2
B,
Nitrogen
(Nitrite),
Colorimetric
1156
Method,
referenced
in
Section
611.611.
1157
1158
Method
4500-N0
3
D,
Nitrogen
(Nitrate),
Nitrate
Electrode
1159
Method,
referenced
in
Section
611.611.
1160
JCAR35O61
1-0814065r01
1161
Method
4500-N0
3
E, Nitrogen
(Nitrate),
Cadmium
1162
Reduction
Method,
referenced
in
Section
611.611.
1163
1164
Method
4500-N0
3
F,
Nitrogen (Nitrate),
Automated
1165
Cadmium
Reduction
Method,
referenced
in
Section
1166
611.611.
1167
1168
Method
4500-03
B,
Ozone
(Residual)
(Proposed),
Indigo
1169
Colorimetric
Method,
referenced
in
Section
611.531.
1170
1171
Method
4500-P
E, Phosphorus,
Ascorbic
Acid
Method,
1172
referenced
in Section
611.611.
1173
1174
Method
4500-P
F, Phosphorus,
Automated
Ascorbic
Acid
1175
Reduction
Method,
referenced
in Section
611.611.
1176
1177
Method
4500-Si
D, Silica,
Molybdosilicate
Method,
1178
referenced
in
Section 611.611.
1179
1180
Method
4500-Si
E, Silica,
Heteropoly
Blue
Method,
1181
referenced
in
Section 611.611.
1182
1183
Method 4500-Si
F, Silica,
Automated
Method
for
1184
Molybdate-Reactive
Silica,
referenced
in Section
611.611.
1185
1186
Method
5910 B, UV
Absorbing
Organic
Constituents,
1187
Ultraviolet
Absorption
Method,
referenced
in Section
1188
611.381.
1189
1190
Method
6251
B,
Disinfection
Byproducts:
Haloacetic
1191
Acids and
Trichlorophenol,
Micro
Liquid-Liquid
1192
Extraction
Gas Chromatographic
Method, referenced
in
1193
Section
611.381.
1194
1195
Method
6610,
Carbamate
Pesticide
Method,
referenced
in
1196
Section
611.645.
1197
1198
Method
6651,
Glyphosate
Herbicide
(Proposed),
referenced
1199
in
Section
611.645.
1200
1201
Method
7110 B,
Gross Alpha
and Gross
Beta
1202
Radioactivity,
Evaporation
Method
for Gross
Alpha-Beta,
1203
referenced
in Section
611.720.
JCAR35O61
1-0814065r01
1204
1205
Method
7110 C,
Gross
Alpha
and
Beta
Radioactivity
1206
(Total,
Suspended,
and
Dissolved),
Coprecipitation
Method
1207
for Gross
Alpha
Radioactivity
in
Drinking
Water
1208
(Proposed),
referenced
in Section
611.720.
1209
1210
Method
7120
B,
Gamma-Emitting
Radionuclides,
Gamma
1211
Spectrometric
Method,
referenced
in
Section
611.720.
1212
1213
Method
7500-Cs
B,
Radioactive
Cesium,
Precipitation
1214
Method,
referenced
in Section
611.720.
1215
1216
Method
7500-
3
H
B,
Tritium,
Liquid
Scintillation
1217
Spectrometric
Method,
referenced
in
Section
611.720.
1218
1219
Method
7500-I
B, Radioactive
Iodine,
Precipitation
1220
Method,
referenced
in Section
611.720.
1221
1222
Method
7500-I
C,
Radioactive
Iodine,
Ion-Exchange
1223
Method,
referenced
in
Section
6
11.720.
1224
1225
Method
7500-I
D, Radioactive
Iodine,
Distillation
Method,
1226
referenced
in
Section
611.720.
1227
1228
Method
7500-Ra
B,
Radium,
Precipitation
Method,
1229
referenced
in
Section
611.720.
1230
1231
Method
7500-Ra
C,
Radium,
Emanation
Method,
1232
referenced
in Section
611.720.
1233
1234
Method
7500-Ra
D,
Radium,
Sequential
Precipitation
1235
Method,
referenced
in
Section
611.720.
1236
1237
Method
7500-Sr
B, Total
Radiactive
Strontium
and
1238
Strontium
90,
Precipitation
Method,
referenced
in
Section
1239
611.720.
1240
1241
Method
7500-U
B,
Uranium,
Radiochemical
Method,
1242
referenced
in Section
611.720.
1243
1244
Method
7500-U
C,
Uranium,
Isotopic
Method,
referenced
1245
in
Section
611.720.
1246
JCAR35O61 1-0814065r01
1247
Method
9215 B, Heterotrophic
Plate Count,
Pour Plate
1248
Method,
referenced in Section
611.531.
1249
1250
Method
9221 A, Multiple-Tube
Fermentation
Technique
1251
for
Members of the
Coliform
Group,
Introduction,
1252
referenced
in Sections
611.526 and
611.531.
1253
1254
Method
9221 B,
Multiple-Tube
Fermentation Technique
1255
for Members
of the Coliform Group,
Standard
Total
1256
Coliform Fermentation
Technique,
referenced in Sections
1257
611.526and611.531.
1258
1259
Method 9221
C,
Multiple-Tube
Fermentation
Technique
1260
for
Members of the
Coliform Group,
Estimation
of
1261
Bacterial
Density, referenced
in Sections
611.526
and
1262
611.531.
1263
1264
Method
9221 D, Multiple-Tube
Fermentation
Technique
1265
for Members
of the
Coliform Group,
Presence-Absence
(P
1266
A)
Coliform Test, referenced
in Section
611.526.
1267
1268
Method
9221 E,
Multiple-Tube Fermentation
Technique
1269
for Members of the
Coliform Group,
Fecal Coliform
1270
Procedure,
referenced
in Sections
611.526
and 611.53
1.
1271
1272
Method 9222 A,
Membrane
Filter Technique for Members
1273
of the
Coliform
Group, Introduction,
referenced
in Sections
1274
611.526and611.531.
1275
1276
Method 9222 B,
Membrane
Filter
Technique for Members
1277
of the Coliform Group,
Standard
Total Coliform
Membrane
1278
Filter
Procedure,
referenced in Sections
611.526
and
1279
611.531.
1280
1281
Method 9222
C,
Membrane
Filter
Technique
for Members
1282
of
the Coliform
Group, Delayed-Incubation
Total
Coliform
1283
Procedure, referenced
in Sections
611.526
and 611.531.
1284
1285
Method 9222
D, Membrane Filter
Technique
for Members
1286
of the Coliform
Group, Fecal
Coliform
Membrane
Filter
1287
Procedure,
referenced
in
Section 611.531.
1288
JCAR35O61
1-0814065r01
1289
Method
9222
G,
Membrane
Filter
Technique
for Members
1290
of the
Coliform
Group,
MF
Partition
Procedures,
1291
referenced
in Section
611.526.
1292
1293
Method
9223,
Chromogenic
Substrate
Coliform
Test
(also
1294
referred
to as the
variations
“Autoanalysis
Colilert
System”
1295
and
“Colisure
Test”),
referenced
in
Sections
6
11.526,
and
1296
611.531.
1297
1298
Method
9223
B, Chromogenic
Substrate
Coliform
Test
1299
(Proposed),
referenced
in Section
611.1004.
1300
1301
“Supplement
to the
19
th
Edition
of Standard
Methods
for
the
1302
Examination
of
Water
and Wastewater,”
American
Public
Health
1303
Association,
1996.
1304
1305
Method
5310
B,
TOC,
Combustion-Infrared
Method,
1306
referenced
in Section
611.381.
1307
1308
Method
5310
C,
TOC,
Persulfate-Ultraviolet
Oxidation
1309
Method,
referenced
in Section
611.381.
1310
1311
Method
5310
D, TOC,
Wet-Oxidation
Method,
referenced
1312
inSection6ll.381.
1313
1314
“Standard
Methods
for
the
Examination
of
Water
and
1315
Wastewater,”
20
th
Edition,
1998
(referred
to
as
“Standard
Methods,
1316
20thed.I).
1317
1318
Method
2130
B,
Turbidity,
Nephelometric
Method,
1319
referenced
in
Section
611.531.
1320
1321
Method
2320
B, Alkalinity,
Titration
Method,
referenced
in
1322
Section
611.611.
1323
1324
Method
2510
B,
Conductivity,
Laboratory
Method,
1325
referenced
in
Section
611.611.
1326
1327
Method
2550,
Temperature,
Laboratory,
and Field
1328
Methods,
referenced
in Section
611.611.
1329
JCAR35O61
1-0814065r01
1330
Method
3120
B,
Metals
by
Plasma
Emission
Spectroscopy,
1331
Inductively:Coupled
Plasma
(ICP)
Method,
referenced
in
1332
Sections
611.611
andSection6ll.612.
1333
1334
Method
3500-Ca
B, Calcium,
EDTA
Titrimetric
Method,
1335
referenced
in
Section
611.611.
1336
1337
Method
3500-Mg
B,
Magnesium,
EDTA
Titrimetric
1338
Method,
referenced
in Section
611.611.
1339
1340
Method
4110
B,
Determination
of Anions
by Ion
1341
Chromatography,
Ion
Chromatography
with
Chemical
1342
Suppression
of
Eluent
Conductivity,
referenced
in
Section
1343
611.611.
1344
1345
Method
4500-CN
C,
Cyanide,
Total
Cyanide
after
1346
Distillation,
referenced
in Section
611.611.
1347
1348
Method
4500-CN
E,
Cyanide,
Colorimetric
Method,
1349
referenced
in
Section
611.611.
1350
1351
Method
4500-CN
F,
Cyanide,
Cyanide-Selective Electrode
1352
Method,
referenced
in
Section
611.611.
1353
1354
Method
4500-CN
G, Cyanide,
Cyanides
Amenable
to
1355
Chlorination
after Distillation,
referenced
in Section
1356
611.611.
1357
1358
Method
4500-Cl
D,
Chlorine,
Amperometric Titration
1359
Method,
referenced
in
Section
611.53
1.
1360
1361
Method
4500-Cl
E, Chlorine,
Low-Level
Amperometric
1362
Titration
Method,
referenced
in
Section
611.531.
1363
1364
Method
4500-Cl
F, Chlorine,
DPD Ferrous
Titrimetric
1365
Method,
referenced
in Section
611.531.
1366
1367
Method
4500-Cl
G,
Chlorine,
DPD
Colorimetric
Method,
1368
referenced
in
Section
611.53
1.
1369
1370
Method
4500-Cl
H,
Chlorine,
Syringaldazine
(FACTS)
1371
Method,
referenced
in Section
611.531.
1372
JCAR35O61 1-0814065r01
1373
Method
4500-Cl
I,
Chlorine, Jodometric
Electrode
Method,
1374
referenced
in Section
611.531.
1375
1376
Method
4500-C102
C, Chlorine Dioxide,
Amperometric
1377
Method
I, referenced
in Section
611.53 1.
1378
1379
Method 4500C10
2
D, Chlorine
Dioxide, DPD
Method,
1380
referenced
in Section
61 1.531.
1381
1382
Method 4500-C102
E, Chlorine
Dioxide, Amperometric
1383
Method II
(Proposed), referenced
in Section aEr4-61
1.53
1.
1384
1385
Method 4500-V B,
Fluoride, Preliminary
Distillation
Step,
1386
referenced
in
Section
611.611.
1387
1388
Method
4500-V
C, Fluoride, Ion-Selective
Electrode
1389
Method,
referenced
in Section
611.611.
1390
1391
Method
4500-V
D,
Fluoride, SPADNS
Method, referenced
1392
in
Section 611.611.
1393
1394
Method
4500-V
B, Fluoride,
Complexone
Method,
1395
referenced in Section
611.611.
1396
1397
Method 4500-H
B, pH Value,
Electrometric
Method,
1398
referenced
in Section
611.611.
1399
1400
Method 4500-NOj
B, Nitrogen
(Nitrite), Colorimetric
1401
Method, referenced
in Section
611.611.
1402
1403
Method 4500-N03
D, Nitrogen
(Nitrate),
Nitrate
Electrode
1404
Method,
referenced
in Section
611.611.
1405
1406
Method
4500-N0
3
E, Nitrogen
(Nitrate), Cadmium
1407
Reduction
Method,
referenced
in
Section 611.611.
1408
1409
Method 4500-N0
3
F, Nitrogen
(Nitrate),
Automated
1410
Cadmium
Reduction
Method,
referenced in Section
1411
611.611.
1412
1413
Method 4500-03
B, Ozone
(Residual) (Proposed),
Indigo
1414
Colorimetric
Method, referenced
in Section
611.531.
1415
JCAR35061
1-0814065r01
1416
Method
4500-P
E,
Phosphorus,
Ascorbic
Acid
Method,
1417
referenced
in Section
611.611.
1418
1419
Method
4500-P
F,
Phosphorus,
Automated
Ascorbic
Acid
1420
Reduction
Method,
referenced
in
Section
611.611.
1421
1422
Method
4500-Si
C,
Silica,
Molybdosilicate
Method,
1423
referenced
in Section
611.611.
1424
1425
Method
4500-Si
D,
Silica,
Heteropoly
Blue
Method,
1426
referenced
in
Section
611.611.
1427
1428
Method
4500-Si
E, Silica,
Automated
Method
for
1429
Molybdate-Reactive
Silica,
referenced
in
Section
611.611.
1430
1431
Method
5910
B, UV-Absorbing
Organic
Constituents,
1432
Ultraviolet
Absorption
Method,
referenced
in Sections
1433
611.381
and
611.382.
1434
1435
Method
6251,
Disinfection
By-Products:
Haloacetic
Acids
1436
and
Trichiorophenol,
referenced
in
Section
611.381.
1437
1438
Method
6610,
Carbamate
Pesticide
Method,
referenced
in
1439
Section
611.645.
1440
1441
Method
6651,
Glyphosate
Herbicide
(Proposed),
referenced
1442
in Section
611.645.
1443
1444
Method
7110
B,
Gross
Alpha
and
Gross
Beta
1445
Radioactivity,
Evaporation
Method
for
Gross
Alpha-Beta,
1446
referenced
in
Section
611.720.
1447
1448
Method
7110
C,
Gross
Alpha
and
Beta
Radioactivity
1449
(Total,
Suspended,
and
Dissolved),
Coprecipitation
Method
1450
for
Gross
Alpha
Radioactivity
in Drinking
Water
1451
(Proposed),
referenced
in
Section
611.720.
1452
1453
Method
71207120
B,
Gamma-Emitting
Radionuclides,
1454
Gamma
Spectrometric
Method,
referenced
in
Section
1455
611.720.
1456
1457
Method
7500-Cs
B,
Radioactive
Cesium, Precipitation
1458
Method,
referenced
in
Section
611.720.
JCAR35061
1-0814065r01
1459
1460
Method 7500-
3
H
B,
Tritium, Liquid
Scintillation
1461
Spectrometric
Method,
referenced
in Section
611.720.
1462
1463
Method
7500-I B,
Radioactive
Iodine, Precipitation
1464
Method,
referenced
in Section
611.720.
1465
1466
Method
7500-I
C,
Radioactive
Iodine,
Ion-Exchange
1467
Method,
referenced
in Section
611.720.
1468
1469
Method
7500-I D,
Radioactive
Iodine,
Distillation
Method,
1470
referenced
in Section
611.720.
1471
1472
Method
7500-Ra
B, Radium,
Precipitation
Method,
1473
referenced
in
Section
611.720.
1474
1475
Method
7500-Ra
C, Radium,
Emanation
Method,
1476
referenced
in Section
611.720.
1477
1478
Method 7500-Ra
D,
Radium, Sequential
Precipitation
1479
Method,
referenced
in Section
611.720.
1480
1481
Method
7500-Sr B,
Total
Radiactive
Strontium
and
1482
Strontium
90, Precipitation
Method,
referenced
in
Section
1483
611.720.
1484
1485
Method
7500-U
B, Uranium,
Radiochemical
Method,
1486
referenced
in Section
611.720.
1487
1488
Method
7500-U
C,
Uranium,
Isotopic
Method,
referenced
1489
in
Section
611.720.
1490
1491
Method
9215 B, Heterotrophic
Plate
Count,
Pour Plate
1492
Method,
referenced
in Section
611.531.
1493
1494
Method
9221 A,
Multiple-Tube
Fermentation
Technique
1495
for Members
of the
Coliform
Group,
Introduction,
1496
referenced
in Sections
611.526
and
611.53
1.
1497
1498
Method
9221 B,
Multiple-Tube
Fermentation
Technique
1499
for
Members
of the
Coliform
Group,
Standard
Total
1500
Coliform
Fermentation
Technique,
referenced
in Sections
1501
611.526and611.531.
JCAR35O61
l-0814065r01
1502
1503
Method
9221
C,
Multiple-Tube
Fermentation
Technique
1504
for Members
of the Coliform
Group,
Estimation
of
1505
Bacterial
Density,
referenced
in Sections
611.526
and
1506
611.531.
1507
1508
Method
9221
D, Multiple-Tube
Fermentation
Technique
1509
for Members
of the
Coliform
Group, Presence-Absence
(P
1510
A)
Coliform
Test, referenced
in
Sections 611.526.
1511
1512
Method 9221
E,
Multiple-Tube
Fermentation
Technique
1513
for Members
of the
Coliform
Group,
Fecal
Coliform
1514
Procedure,
referenced
in Sections
611.526
and 611.531.
1515
1516
Method
9221
F, Multiple-Tube
Fermentation
Technique
for
1517
Members
of the
Coliform
Group,
Escherichia
Coli
1518
Procedure
(Proposed),
referenced
in
Section 611.802.
1519
1520
Method
9222
A, Membrane
Filter Technique
for
Members
1521
of
the Coliform
Group,
Introduction,
referenced
in
Sections
1522
611.526
and 611.531.
1523
1524
Method 9222
B, Membrane
Filter
Technique
for Members
1525
of the Coliform
Group,
Standard
Total
Colifonn Membrane
1526
Filter Procedure,
referenced
in
Sections 611.526
and
1527
611.531.
1528
1529
Method
9222
C,
Membrane
Filter Technique
for Members
1530
of
the
Coliform
Group,
Delayed-Incubation
Total
Coliform
1531
Procedure,
referenced
in Sections
611.526
and
611.531.
1532
1533
Method
9222
D,
Membrane
Filter
Technique
for Members
1534
of the Colifonn
Group,
Fecal Coliform
Membrane
Filter
1535
Procedure,
referenced
in Section
611.531.
1536
1537
Method
9222
G,
Membrane
Filter
Technique
for
Members
1538
of the Coliform
Group,
MF Partition
Procedures,
1539
referenced
in
Section
611.526.
1540
1541
Method
9223, Chromogenic
Substrate Coliform
Test
(also
1542
referred
to
as the
variations
“Autoanalysis
Colilert
System”
1543
and
“Colisure
Test”), referenced
in
Sections 611.526,
1544
611.531.
JCAR35O61
1-0814065r01
1545
1546
Method
9223
B,
Chromogenic
Substrate
Coliform
Test
1547
(also
referred
to
as
the
variations
“Autoanalysis
Colilert
1548
System” and
“Colisure
Test”),
referenced
in
Sections
1549
611.802
and
611.1004.
1550
1551
Method
9230
B,
Fecal
Streptococcus
and
Enterococcus
1552
Groups,
Multiple
Tube
Techniques,
referenced
in
Section
1553
611.802.
1554
1555
Method
9230
C,
Fecal
Streptococcus
and
Enterococcus
1556
Groups,
Membrane
Filter
Techniques,
referenced
in
1557
Section 611.802.
1558
1559
“Standard
Methods
for
the
Examination
of
Water
and
1560
Wastewater,”
21
st
Edition,
2005
(referred
to
as
“Standard
Methods,
1561
21s
t
ed.).
1562
1563
Method
2130
B,
Turbidity,
Nephelometric
Method,
1564
referenced
in
Section
611.531.
1565
1566
Method
2320
B,
Alkalinity,
Titration
Method,
referenced
in
1567
Section
611.611.
1568
1569
Method
2510
B,
Conductivity,
Laboratory
Method,
1570
referenced
in
Section
611.611.
1571
1572
Method
2550,
Temperature,
Laboratory,
and
Field
1573
Methods,
referenced
in
Section
611.611.
1574
1575
Method
3111
B,
Metals
by
Flame
Atomic
Absorption
1576
Spectrometry,
Direct
Air-Acetylene
Flame
Method,
1577
referenced
in
Sections
611.611
and
611.612.
1578
1579
Method
3111
D.
Metals
by
Flame
Atomic
Absorption
1580
Spectrometry,
Direct
Nitrous
Oxide-Acetylene
Flame
1581
Method,
referenced
in
Section
611.611.
1582
1583
Method
3112
B,
Metals
by
Cold-Vapor
Atomic
Absorption
1584
Spectrometry,
Cold-Vapor
Atomic
Absorption
1585
Spectrometric
Method,
referenced
in
Section
611.611.
1586
JCAR35O61
1-0814065r01
1587
Method 3113
B, Metals
by
Electrothermal
Atomic
1588
Absorption
Spectrometry,
Electrothermal
Atomic
1589
Absorption
Spectrometric
Method, referenced
in Sections
1590
611.611
and
611.612.
1591
1592
Method 3114 B,
Metals by Hydride
GenerationlAtomic
1593
Absorption
Spectrometry,
Manual
Hydride
1594
GenerationlAtomic
Absorption
Spectrometric
Method,
1595
referenced in Section
611.611.
1596
1597
Method 3120 B,
Metals
by
Plasma Emission Spectroscopy,
1598
Inductively-Coupled
Plasma
(ICP)
Method,
referenced
in
1599
Sections
611.611
and 611.612.
1600
1601
Method
3500-Ca
B, Calcium, EDTA
Titrimetric
Method,
1602
referenced
in Section
611.611.
1603
1604
Method
3500-Ca D,
Calcium, EDTA
Titrimetric
Method,
1605
referenced
in Section
611.611.
1606
1607
Method
3500-Mg
B, Magnesium, Calculation
Method,
1608
referenced in Section
611.611.
1609
1610
Method 4110
B, Determination
of Anions
by
Ion
1611
Chromatography,
Ion Chromatography
with
Chemical
1612
Suppression
of Eluent Conductivity,
referenced
in Section
1613
611.611.
1614
1615
Method 4500-Cl
D, Chlorine,
Amperometric Titration
1616
Method,
referenced
in Section 611.381.
1617
1618
Method 4500-Cl
B, Chlorine, Low-Level
Amperometric
1619
Titration
Method,
referenced in
Section 611.381.
1620
1621
Method 4500-Cl
F, Chlorine, DPD
Ferrous Titrimetric
1622
Method,
referenced
in Section 611.381.
1623
1624
Method
4500-Cl
G,
Chlorine, DPD
Colorimetric
Method,
1625
referenced
in Section 611.381.
1626
1627
Method
4500-Cl H,
Chlorine, Syringaldazine
(FACTS)
1628
Method,
referenced in Section
611.381.
1629
JCAR35061
1-0814065r01
1630
Method
4500-Cl
I,
Chlorine,
Jodometric
Electrode
Method,
1631
referenced
in Section
611.381.
1632
1633
Method
4500-ciQ2
C,
Chlorine
Dioxide,
Amperometric
1634
Method
I,
referenced
in
Section
611.53
1.
1635
1636
Method
4500-C10
2
E,
Chlorine
Dioxide,
Amperometric
1637
Method
II (Proposed),
referenced
in
Section
an4-611.381.
1638
1639
Method
4500-CN
E,
Cyanide,
Colorimetric
Method,
1640
referenced
in Section
611.611.
1641
1642
Method
4500-CN
F, Cyanide,
Cyanide-Selective Electrode
1643
Method,
referenced
in Section
611.611.
1644
1645
Method
4500-CN
G,
Cyanide,
Cyanides
Amenable
to
1646
Chlorination
after Distillation,
referenced
in Section
1647
611.611.
1648
1649
Method
4500-V
B,
Fluoride,
Preliminary Distillation
Step,
1650
referenced
in Section
611.611.
1651
1652
Method
4500-V
C,
Fluoride,
Ion-Selective Electrode
1653
Method,
referenced
in
Section
611.611.
1654
1655
Method
4500-V
D, Fluoride,
SPADNS
Method,
referenced
1656
inSection6ll.611.
1657
1658
Method
4500-V
E, Fluoride,
Complexone
Method,
1659
referenced
in Section
611.611.
1660
1661
Method
4500-H
B,
pH
Value,
Electrometric
Method,
1662
referenced
in Section
611.611.
1663
1664
Method
4500-NOr
B, Nitrogen
(Nitrite),
Colorimetric
1665
Method,
referenced
in
Section
611.611.
1666
1667
Method
4500-NOr
D,
Nitrogen
(Nitrate),
Nitrate
Electrode
1668
Method,
referenced
in Section
611.611.
1669
1670
Method
4500-NOr
E,
Nitrogen
(Nitrate),
Cadmium
1671
Reduction
Method,
referenced
in
Section
611.611.
1672
JCAR35O61 1-0814065r01
1673
Method
4500-NOr
F,
Nitrogen
(Nitrate),
Automated
1674
Cadmium
Reduction
Method,
referenced
in
Section
1675
611.611.
1676
1677
Method
4500-03
B,
Ozone
(Residual)
(Proposed),
Indigo
1678
Colorimetric
Method,
referenced
in
Section
611.531.
1679
1680
Method
4500-P
E,
Phosphorus,
Ascorbic
Acid
Method,
1681
referenced
in
Section
611.611.
1682
1683
Method 4500-P
F,
Phosphorus,
Automated
Ascorbic
Acid
1684
Reduction
Method,
referenced
in
Section
611.611.
1685
1686
Method
4500-Si0
2
C, Silica,
Molybdosilicate
Method,
1687
referenced
in Section
611.611.
1688
1689
Method
4500-Si0
2
D,
Silica,
Heteropoly
Blue
Method,
1690
referenced
in
Section
611.611.
1691
1692
Method
4500-Si0
2
E,
Silica, Automated
Method
for
1693
Molybdate-Reactive
Silica,
referenced
in
Section
611.611.
1694
1695
Method
5310
B, TOC,
Combustion-Infrared
Method,
1696
referenced
in
Section
611.381.
1697
1698
Method
5310
C,
TOC,
Persulfate-Ultraviolet
Oxidation
1699
Method,
referenced
in
Section
611.381.
1700
1701
Method
5310
D,
TOC,
Wet-Oxidation
Method,
referenced
1702
in
Section
611.381.
1703
1704
Method
5910
B, UV-Absorbing
Organic
Constituents,
1705
Ultraviolet
Absorption
Method,
referenced
in
Sections
1706
611.381
and
611.382.
1707
1708
Method
6251,
Disinfection
By-Products:
Haloacetic
Acids
1709
and
Trichiorophenol,
referenced
in
Section
611.381.
1710
1711
Method
6610,
Carbamate
Pesticide
Method,
referenced
in
1712
Section6ll.645.
1713
JCAR35O61
1-0814065r01
1714
Method 7110
B, Gross Alpha and
Gross Beta
1715
Radioactivity,
Evaporation
Method for Gross Alpha-Beta,
1716
referenced
in Section 611.720.
1717
1718
Method 7110
C,
Gross
Alpha and Beta Radioactivity
1719
(Total,
Suspended, and Dissolved),
Coprecipitation
Method
1720
for Gross
Alpha Radioactivity
in Drinking
Water
1721
(Proposed),
referenced
in Section 611.720.
1722
1723
Method
7120, Gamma-Emitting
Radionuclides,
referenced
1724
in Section
611.720.
1725
1726
Method 7500-Cs
B,
Radioactive
Cesium,
Precipitation
1727
Method, referenced
in Section
611.720.
1728
1729
Method H
3
7500-
B,
Tritium,
Liquid Scintillation
1730
Spectrometric
Method,
referenced
in Section
611.720.
1731
1732
Method
7500-I
B, Radioactive
Iodine, Precipitation
1733
Method, referenced
in
Section
611.720.
1734
1735
Method
7500-I
C,
Radioactive
Iodine,
Ion-Exchange
1736
Method, referenced
in Section
611.720.
1737
1738
Method
7500-ID, Radioactive
Iodine,
Distillation Method,
1739
referenced
in
Section
611.720.
1740
1741
Method
7500-Ra
B,
Radium, Precipitation
Method,
1742
referenced
in Section 6
11.720.
1743
1744
Method 7500-Ra
C,
Radium,
Emanation
Method,
1745
referenced
in Section 611.720.
1746
1747
Method
7500-Ra D, Radium,
Sequential
Precipitation
1748
Method, referenced
in Section
611.720.
1749
1750
Method 7500-Sr
B, Total
Radioactive
Strontium and
1751
Strontium
90, Precipitation
Method, referenced
in Section
1752
611.720.
1753
1754
Method
7500-U
B, Uranium, Radiochemical
Method,
1755
referenced in Section
611.720.
1756
JCAR35O61
1-0814065r01
1757
Method
7500-U
C, Uranium,
Isotopic
Method,
referenced
1758
in
Section 611.720.
1759
1760
Method
9221
A,
Multiple-Tube
Fermentation
Technique
1761
for
Members
of the Coliform
Group,
Introduction.
1762
referenced
in Sections
611.526
and
611.531.
1763
1764
Method 9221
B, Multiple-Tube
Fermentation
Technique
1765
for Members
of the
Coliform
Group, Standard
Total
1766
Coliform
Fermentation
Technique,
referenced
in
Sections
1767
611.526and611.531.
1768
1769
Method
9221
C, Multiple-Tube
Fermentation
Technique
1770
for Members
of the
Coliform Group,
Estimation
of
1771
Bacterial
Density,
referenced
in
Sections
611.526
and
1772
611.531.
1773
1774
Method
9221
D,
Multiple-Tube
Fermentation
Technique
1775
for
Members
of the Coliform
Group,
Presence-Absence
(P
1776
A)
Coliform
Test,
referenced
in
Section 611.526.
1777
1778
Method 9221
E,
Multiple-Tube
Fermentation
Technique
1779
for Members
of the
Coliform
Group, Fecal
Coliform
1780
Procedure,
referenced
in Sections
611.526
and 611.531.
1781
1782
Method
9221 F,
Multiple-Tube
Fermentation
Technique
for
1783
Members
of the Coliform
Group,
Escherichia
Coli
1784
Procedure
(Proposed),
referenced
in Section
611.802.
1785
1786
Method
9222
A,
Membrane
Filter
Technique
for
Members
1787
of the Coliform
Group,
Introduction,
referenced
in
Sections
1788
611.526and611.531.
1789
1790
Method 9222
B, Membrane
Filter
Technique
for
Members
1791
of the Coliform
Group,
Standard
Total
Coliform
Membrane
1792
Filter Procedure,
referenced
in Sections
611.526
and
1793
611.531.
1794
1795
Method
9222
C,
Membrane
Filter
Technique
for
Members
1796
of the
Coliform
Group, Delayed-Incubation
Total
Coliform
1797
Procedure,
referenced
in
Sections 611.526
and
611.531.
1798
JCAR35O61
1-0814065r01
1799
Method
9222
D,
Membrane
Filter
Technique
for
Members
1800
of
the
Coliform
Group,
Fecal
Coliform
Membrane
Filter
1801
Procedure,
referenced
in
Section
611.53
1.
1802
1803
Method
9222
G,
Membrane
Filter
Technique
for
Members
1804
of the
Coliform
Group,
MF
Partition
Procedures,
1805
referenced
in
Section
611.526.
1806
1807
Method
9223,
Chromogenic
Substrate
Coliform
Test
(also
1808
referred
to
as
the
variations
HAutoanalysis
Colilert
System”
1809
and
“Colisure
Test”),
referenced
in
Sections
6
11.526
and
1810
611.531.
1811
1812
Method
9223
B, Chromogenic
Substrate
Coliform
Test
1813
(also
referred
to
as
the
variations
“Autoanalysis
Colilert
1814
System”
and
“Colisure
Test”),
referenced
in
Sections
1815
611.802and611.1004.
1816
1817
BOARD
NOTE:
Individual
Methods
from
Standard
Methods
areis
1818
available
online
at
www.standardmethods.org.
1819
1820
Analytical
Technology,
Inc.
ATI
Orion,
529
Main
Street,
Boston,
MA
1821
02129.
1822
1823
Technical
Bulletin
601,
“Standard
Method
of
Testing
for
Nitrate
in
1824
Drinking
Water,”
July,
1994,
PN
221890-001
(referred
to as
1825
“Technical
Bulletin
601”),
referenced
in
Section
611.611.
1826
1827
ASTM.
American
Society
for
Testing
and
Materials,
100
Barr
Harbor
1828
Drive,
West
Conshohocken,
PA
19428-2959
(610-832-9585).
1829
1830
ASTM
Method
D51
1-93
A
and
B,
“Standard Test
Methods
for
1831
Calcium
and
Magnesium
in
Water,”
“Test
Method
A
—
1832
Complexometric
Titration”
&
“Test
Method
B
— Atomic
1833
Absorption
Spectrophotometric,”
approved
1993,
referenced
in
1834
Section6ll.611.
1835
1836
ASTM
Method
D51
1-03
A
and
B,
“Standard
Test
Methods
for
1837
Calcium
and
Magnesium
in
Water,”
“Test
Method
A
—
1838
Complexometric
Titration”
&
“Test
Method
B
—
Atomic
1839
Absorption
Spectrophotometric,”
approved
2003,
referenced
in
1840
Section6ll.611.
1841
JCAR35O61
1-0814065r01
1842
ASTM Method
D515-88
A, “Standard Test
Methods for
1843
Phosphorus
in Water,” “Test
Method
A
— Colorimetric Ascorbic
1844
Acid Reduction,”
approved
August 19, 1988,
referenced in
Section
1845
611.611.
1846
1847
ASTM
Method
D859-94D859
88, “Standard
Test
Method
for
1848
Silica in Water,”
approved l994August
19, 1988, referenced
in
1849
Section6ll.611.
1850
1851
ASTM Method D859-00,
“Standard
Test Method
for
Silica in
1852
Water,” approved 2000,
referenced
in Section 611.611.
1853
1854
ASTM
Method
D859-05,
“Standard
Test
Method for Silica
in
1855
Water,”
approved 2005,
referenced in Section
611.611.
1856
1857
ASTM
Method
D1067-92
B, “Standard
Test Methods for Acidity
1858
or Alkalinity
in Water,”
“Test
Method B — Electrometric
or Color-
1859
Change
Titration,”
approved
May 15,
1992,
referenced in Section
1860
611.611.
1861
1862
ASTM
Method D1067-02
B, “Standard Test
Methods
for
Acidity
1863
or Alkalinity
in Water,”
“Test Method B
— Electrometric or
Color-
1864
Change
Titration,” approved
in 2002,
referenced in Section
1865
611.611.
1866
1867
ASTM Method D1125-95
(1999)D1125
91 A, “Standard
Test
1868
Methods
for
Electrical
Conductivity
and Resistivity
of Water,”
1869
“Test Method A —
Field
and Routine
Laboratory Measurement
of
1870
Static
(Non-Flowing)
Samples,” approved
June 15,
1995,
1871
reapproved l999June
15, 1991,
referenced in Section
611.611.
1872
1873
ASTM
Method Dl
179-93 B, “Standard
Test
Methods
for Fluoride
1874
in
Water,” “Test Method
B
— Ion Selective
Electrode,” approved
1875
1993,
referenced
in
Section 611.611.
1876
1877
ASTM
Method
Dl
179-99 B, “Standard
Test
Methods
for Fluoride
1878
in
Water,” “Test Method
B — Ion Selective
Electrode,” approved
1879
1999, referenced in
Section 611.611.
1880
1881
ASTM Method
D1179-04 B, “Standard
Test Methods
for
Fluoride
1882
in Water,” “Test
Method
B
— Ion Selective Electrode,”
approved
1883
2004,
referenced
in Section
611.611.
1884
JCAR35O61 1-0814065r01
1885
ASTM
Method
D1253-86,
“Standard
Test
Method for
Residual
1886
Chlorine
in
Water,”
reapproved 1992,
referenced
in
Section
1887
611.381.
1888
1889
ASTM Method
D1253-96, “Standard
Test
Method
for Residual
1890
Chlorine in Water,”
reapproved
1996, referenced
in
Section
1891
611.381.
1892
1893
ASTM
Method
D1253-03,
“Standard Test
Method
for Residual
1894
Chlorine in
Water,”
reapproved
2003,
referenced
in
1895
SectionsSection
611.381 and
611.531.
1896
1897
ASTM Method
D1293-95 A or
BD1293 84,
“Standard Test
1898
Methods
for pH
of Water,”
“Test Method A — Precise
Laboratory
1899
Measurement”
& “Test Method
B — Routine or Continuous
1900
Measurement,”
approved l995October
26, 1984,
referenced in
1901
Section
611.611.
1902
1903
ASTM
Method D1293-99
A
or
B, “Standard Test Methods
for
pH
1904
of
Water,”
“Test
Method A — Precise
Laboratory
Measurement”
&
1905
“Test Method B
— Routine or Continuous
Measurement,”
approved
1906
1999,
referenced
in Section
611.611.
1907
1908
ASTM Method
D1688-95D1688
90 A or
C, “Standard Test
1909
Methods
for Copper in
Water,” “Test Method
A — Atomic
1910
Absorption,
Direct”
&
“Test
Method
C
—Atomic
Absorption,
1911
Graphite
Furnace,”
approved
l995March 15,
1990, referenced
in
1912
Section6ll.611.
1913
1914
ASTM Method
D1688-02
A or
C,
“Standard
Test
Methods for
1915
Copper in
Water,” “Test Method
A
— Atomic
Absorption, Direct”
1916
& “Test Method
C — Atomic
Absorption, Graphite
Furnace,”
1917
approved 2002,
referenced in Section
611.611.
1918
1919
ASTM Method
D2036-98D2036
91 A
or B,
“Standard Test
1920
Methods for Cyanide
in
Water,”
“Test Method A
— Total
Cyanides
1921
after Distillation”
&
“Test Method
B — Cyanides
Amenable to
1922
Chlorination
by
Difference,”
approved l998September
15, 1991,
1923
referenced
in Section
611.611.
1924
1925
ASTM
Method D2036-06
A or B,
“Standard
Test
Methods
for
1926
Cyanide
in
Water,”
“Test Method A
— Total Cyanides
after
1927
Distillation”
&
“Test Method B
— Cyanides
Amenable
to
JCAR35O61
1-0814065r01
1928
Chlorination
by
Difference,”
approved
2006,
referenced
in Section
1929
611.611.
1930
1931
ASTM
Method
D2459-72,
“Standard
Test
Method
for
Gamma
1932
Spectrometry
in
Water,”
approved
July
28, 1972,
discontinued
1933
1988,
referenced
in Section
611.720.
1934
1935
ASTM
Method
D2460-90,
“Standard
Test Method
for
1936
Radionuclides
of Radium
in Water,”
approved
1990,
referenced
in
1937
Section
611.720.
1938
1939
ASTM
Method
D2907-91,
“Standard
Test Methods
for
1940
Microquantities
of Uranium
in
Water
by
Fluorometry,”
“Test
1941
Method
A
— Direct
Fluorometric”
&
“Test
Method
B
—
1942
Extraction,”
approved
June
15, 1991,
referenced
in Section
1943
611.720.
1944
1945
ASTM
Method
D2972-97D2972
93 B
or
C,
“Standard
Test
1946
Methods
for
Arsenic
in Water,”
“Test Method
B
—
Atomic
1947
Absorption,
Hydride
Generation”
&
“Test
Method
C
—
Atomic
1948
Absorption,
Graphite
Furnace,”
approved
19971993,
referenced
in
1949
Section
611.611.
1950
1951
ASTM
Method
D2972-03
B or
C,
“Standard
Test Methods
for
1952
Arsenic
in Water,”
“Test
Method
B —
Atomic
Absorption,
Hydride
1953
Generation”
&
“Test
Method
C
— Atomic
Absorption,
Graphite
1954
Furnace,”
approved
2003,
referenced
in Section
611.611.
1955
1956
ASTM
Method
D3223-97D3223
91,
“Standard
Test
Method
for
1957
Total
Mercury
in Water,”
approved
l997September
23, 1991,
1958
referenced
in Section
611.611.
1959
1960
ASTM
Method
D3223-02,
“Standard
Test
Method
for
Total
1961
Mercury
in Water,”
approved
2002,
referenced
in Section
611.611.
1962
1963
ASTM
Method
D3454-91,
“Standard
Test Method
for
Radium-226
1964
in Water,”
approved
1991,
referenced
in
Section
611.720.
1965
1966
ASTM
Method
D3559-96
D,
“Standard
Test
Methods
for
Lead in
1967
Water,”
“Test
Method
D — Atomic
Absorption,
Graphite
Furnace,”
1968
approved
August
6,
1990,
referenced
in Section
611.611.
1969
JCAR35O61
1-0814065r01
1970
ASTM Method
D3559-03 D, “Standard
Test
Methods
for Lead in
1971
Water,”
“Test
Method
D —
Atomic Absorption, Graphite
Furnace,”
1972
approved 2003,
referenced in
Section 611.611.
1973
1974
ASTM
Method
D3645-97
B, “Standard
Test Methods for
1975
Beryllium
in Water,” “Method
B — Atomic
Absorption,
Graphite
1976
Furnace,”
approved
19971993,
referenced
in Section 611.611.
1977
1978
ASTM
Method D3645-03
B,
“Standard
Test Methods for
1979
Beryllium
in Water,”
“Method B — Atomic
Absorption,
Graphite
1980
Furnace,”
approved 2003,
referenced
in Section 611.611.
1981
1982
ASTM Method
D3649-91,
“Standard Test
Method for High-
1983
Resolution
Gamma-Ray
Spectrometry
of
Water,” approved 1991,
1984
referenced
in Section 611.720.
1985
1986
ASTM Method
D3649-98a,
“Standard Test
Method for High-
1987
Resolution Gamma-Ray
Spectrometry
of
Water,” approved 1998,
1988
referenced
in Section 611.720.
1989
1990
ASTM
Method
D3697-92,
“Standard Test Method
for
Antimony
in
1991
Water,”
approved June 15,
1992,
referenced
in Section 611.611.
1992
1993
ASTM
Method D3697-02,
“Standard Test
Method
for
Antimony in
1994
Water,”
approved 2002,
referenced
in Section 611.611.
1995
1996
ASTM
Method D3859-98D3
859 93
A, “Standard Test Methods
1997
for Selenium
in Water,”
“Method A
— Atomic Absorption,
Hydride
1998
Method,”
approved 19981993,
referenced
in Section 611.611.
1999
2000
ASTM Method
D3859-03
A, “Standard
Test Methods for
2001
Selenium
in Water,” “Method
A — Atomic
Absorption,
Hydride
2002
Method,”
approved 2003,
referenced in
Section 611.611.
2003
2004
ASTM
Method
D3867-90
A and B, “Standard
Test
Methods
for
2005
Nitrite-Nitrate
in Water,” “Test
Method
A — Automated Cadmium
2006
Reduction”
& “Test Method
B — Manual
Cadmium
Reduction,”
2007
approved
January 10,
1990, referenced
in Section
611.611.
2008
2009
ASTM
Method D3972-90,
“Standard
Test Method for
Isotopic
2010
Uranium
in
Water
by
Radiochemistry,”
approved
1990, referenced
2011
in Section 611.720.
2012
JCAR35O61
1-0814065r01
2013
ASTM
Method
D3972-02,
“Standard
Test Method
for Isotopic
2014
Uranium
in Water
by Radiochemistry,”
approved
2002, referenced
2015
in
Section 611.720.
2016
2017
ASTM
Method
D4107-91,
“Standard
Test
Method for
Tritium
in
2018
Drinking Water,”
approved
1991,
referenced
in Section
611.720.
2019
2020
ASTM
Method
D4107-98,
“Standard Test
Method
for Tritium
in
2021
Drinking
Water,”
approved
1998
(reapproved
2002),
referenced
in
2022
Section
611.720.
2023
2024
ASTM
Method
D4327-97D4327
91, “Standard
Test Method
for
2025
Anions
in
Water by
Ion Chromatography,”
approved
l997October
2026
15, 1991,
referenced
in Section
611.611.
2027
2028
ASTM Method
D4327-03,
“Standard
Test
Method for
Anions in
2029
Water
by
Ion
Chromatography,”
approved
2003,
referenced
in
2030
Section6ll.611.
2031
2032
ASTM Method
D4785-88,
“Standard
Test
Method for
Low-Level
2033
Iodine-131
in
Water,”
approved
1988,
referenced
in Section
2034
611.720.
2035
2036
ASTM
Method
D4785-OOa,
“Standard
Test
Method
for
Low-Level
2037
Iodine-131
in
Water,”
approved
2000,
referenced
in
Section
2038
611.720.
2039
2040
ASTM
Method D5174-91,
“Standard
Test
Method
for Trace
2041
Uranium
in Water
by
Pulsed-Laser
Phosphorimetry,”
approved
2042
1991,
referenced
in Section
611.720.
2043
2044
ASTM
Method
D5 174-02,
“Standard Test
Method for
Trace
2045
Uranium
in Water
by Pulsed-Laser
Phosphorimetry,”
approved
2046
2002, referenced
in Section
611.720.
2047
2048
ASTM Method
D5317-93,
“Standard Test
Method for
2049
Determination
of
Chlorinated
Organic Acid
Compounds
in Water
2050
by Gas
Chromatography
with
an Electron
Capture
Detector,”
2051
approved
1993, referenced
in Section
611.645.
2052
2053
ASTM
Method
D5317-98,
“Standard
Test
Method
for
2054
Determination
of Chlorinated
Organic
Acid
Compounds
in Water
JCAR35O61
1-0814065r01
2055
by Gas
Chromatography
with
an
Electron
Capture
Detector,”
2056
approved
1998
(reapproved
2003),
referenced
in Section
611.645.
2057
2058
ASTM
Method
D5673-03,
“Standard
Test
Method
for Elements
in
2059
Water
by
Tnductively:Coupled
Plasma
— Mass
Spectrometry,”
2060
approved
2003,
referenced
in
Section
611.720.
2061
2062
ASTM
Method
D5673-05,
“Standard
Test
Method for
Elements
in
2063
Water
by Inductively-Coupled
Plasma
— Mass
Spectrometry,”
2064
approved
2005,
referenced
in
Section
611.720.
2065
2066
ASTM
Method
D6508-00(2005)e2
(rev.
2), “Standard
Test
2067
Method
for
Determination
of
Dissolved
Inorganic
Anions
in
2068
Aqueous
Matrices
Using
Capillary
Ion Electrophoresis
and
2069
Chromate
Electrolyte,”
approved
2000
(revised
2005),
referenced
2070
in Section
611.611.
2071
2072
ASTM
Method
D6581-00,
“Standard Test
Method
for
Bromate,
2073
Bromide,
Chlorate,
and Chlorite
in Drinking
Water
by
Chemically
2074
Suppressed
Ion
Chromatography,”
approved
2000,
referenced
in
2075
Section6ll.381.
2076
2077
ASTM
Method
D6919-03,
“Standard Test
Method
for
2078
Determination
of Dissolved
Alkali
and Alkaline
Earth
Cations
and
2079
Ammonium
in Water
and
Wastewater
by
Ion
Chromatography,”
2080
approved
2003,
referenced
in
Section
6 11.611.
2081
2082
ASTM
Method
D6888-04,
“Standard
Test Method
for
Available
2083
Cyanide
with
Ligand
Displacement
and
Flow
Injection
Analysis
2084
(FIA)
Utilizing
Gas
Diffusion
Separation
and
Amperometric
2085
Detection,”
approved
2004,
referenced
in Section
6
11.611.
2086
2087
Bran
&
Luebbe,
1025
Busch
Parkway,
Buffalo
Grove,
IL
60089.
2088
2089
“Fluoride
in
Water
and
Wastewater,”
Industrial
Method
#129-
2090
71W,
December
1972
(referred
to
as
“Technicon
Methods:
Method
2091
#129-71W”).
See
40 CFR
141
.23(k)(1),
footnote
11 (2007)(2006),
2092
referenced
in
Section
611.611.
2093
2094
“Fluoride
in
Water
and
Wastewater,”
#380-75
WE,
February
1976
2095
(referred
to
as “Technicon
Methods:
Method
#380-75WE”).
See
2096
40 CFR
141.23(k)(1),
footnote
11 (2007)(2006),
referenced
in
2097
Section
611.611.
JCAR35O61
1-0814065r01
2098
2099
Charm
Sciences,
Inc.,
659
Andover
St.,
Lawrence,
MA
01843-1032:
2100
2101
“Charm
E*Colite
Presence/Absence
Test for Detection
and
2102
Identification
of
Coliform
Bacteria
and
Escherichia
coli in
2103
Drinking
Water,”
January
9,
1998
(referred
to as
E*Colite
Test”),
2104
referenced
in
Section 611.802
(also
available
from USEPA,
Water
2105
Resource
Center).
2106
2107
CPI
International,
Inc.,
5580
Skylane Blvd.,
Santa
Rosa,
CA
95403
2108
(800-878-7654
/fax:
707-545-790
1/Internet
address:
2109
www.cpiinternationa1.com).
2110
2111
“Colitag®
Product
as a Test for
Detection
and Identification
of
2112
Coliforms
and E. coli
Bacteria in
Drinking
Water and
Source
2113
Water
as Required
in National
Primary
Drinking
Water
2114
Regulations,”
August 2001,
referenced
in Section
611.526.
2115
2116
EMD
Chemicals
Inc. (an
affiliate
of Merck
KGgA,
Darmstadt,
Germany),
2117
480
S.
Democrat
Road,
Gibbstown,
NJ
08027—1297.
(800-222-0342/e-
2118
mail:
adellenbusch@emscience.com).
2119
2120
“Chromocult
Coliform
Agar Presence/Absence
Membrane
Filter
2121
Test Method
for
Detection
and
Identification
of Coliform
Bacteria
2122
and Escherichia
coli in Finished
Waters,”
November
2000,
Version
2123
1.0, referenced
in
Section
611.526.
2124
2125
“Readycult
Coliforms
100 Presence/Absence
Test for
Detection
2126
and Identification
of Coliform
Bacteria
and
Escherichia
coli
in
2127
Finished
Waters,”
November
2000,
Version
1.0, referenced
in
2128
Section
611.526.
2129
2130
Environmental
Resources
Center,
Georgia
Institute
of Teclmology,
620
2131
Cherry
Street, Atlanta,
GA
30332-0335
(404-894-3776.
2132
2133
“The Determination
of Radium-226
and
Radium-228
in
Drinking
2134
Water
by
Gamma-ray
Spectrometry
Using
HPGE or Ge(Li)
2135
Detectors,”
Revision
1.2, December
2004
(called “Georgia
Radium
2136
Method”),
referenced
in Section
611.720.
2137
2138
ERDA
Health
and Safety
Laboratory,
New
York,
NY.
2139
2140
HASL
Procedure
Manual,
HASL
300, 1973.
See
40
CFR
JCAR35O61
1-0814065r01
2141
141.25(b)(2)
(2007)(2006),
referenced
in Section
611.720.
2142
2143
Great
Lakes
Instruments,
Inc.,
8855
North
5S
Street,
Milwaukee,
WI
2144
53223.
2145
2146
GLI
Method
2,
“Turbidity,”
Nov.
2,
1992,
referenced
in
Section
2147
611.531.
2148
2149
The
Hach
Company,
P.O.
Box
389,
Loveland,
CO
80539-0389
(800-227-
2150
4224).
2151
2152
“Lead
in
Drinking
Water
by
Differential
Pulse
Anodic
Stripping
2153
Voltammetry,”
Method
1001,
August
1999,
referenced
in
Section
2154
611.611.
2155
2156
“Determination
of
Turbidity
by
Laser
Nephelometry,”
January
2157
2000,
Revision
2.0
(referred
to as
“Hach
FilterTrak
Method
2158
10133”),
referenced
in
Section
611.531.
2159
2160
“Total
Coliforms
and
E. coli
Membrane
Filtration
Method
with
m
2161
ColiBlue24®
Broth,”
Method
No.
10029,
Revision
2,
August
17,
2162
1999
(referred
to
as
“m-ColiBlue24
Test”),
referenced
in
Section
2163
611.802
(also
available
from
USEPA,
Water
Resource
Center).
2164
2165
[DEXX
Laboratories,
Inc.,
One
IDEXX
Drive,
Westbrook,
Maine
04092
2166
(800-321-0207).
2167
2168
“IDEXX
SimPlate
TM
HPC
Test
Method
for
Heterotrophs
in
2169
Water,”
November
2000
(referred
to
as “SimPlate
method”),
2170
referenced
in Section
611.53
1.
2171
2172
Industrial
Test
Systems,
Inc.,
1875
Langston
St.,
Rock
Hill,
SC
29730.
2173
2174
Method
D99-003,
Revision
3.0.
“Free
Chlorine
Species
(HOCf
2175
and
OC1)
by
Test
Strip,”
November
21,
2003
(referred
to
as “ITS
2176
Method
D99-003”),
referenced
in
Section
611.381.
2177
2178
Lachat
Instruments,
6645
W.
Mill
Rd.,
Milwaukee,
WI
53218
(414-358-
2179
4200).
2180
2181
“Digestion
and
distillation
of total
cyanide
in
drinking
and
2182
wastewaters
using
MICRO
DIST
and
determination
of
cyanide
by
2183
flow
injection
analysis,”
Revision
2.1,
November
30, 2000
JCAR35O61
1-0814065r01
2184
(referred
to
as “QuikChem
Method
10-204-00-1-X”),
referenced
in
2185
Section
611.611.
2186
2187
Millipore
Corporation,
Technical
Services
Department,
80
Ashby
Road,
2188
Milford,
MA
01730
(800-654-5476).
2189
2190
Colisure
Presence/Absence
Test
for
Detection
and
Identification
of
2191
Coliform
Bacteria
and
Escherichia
Coli
in
Drinking
Water,
2192
February
28, 1994
(referred
to
as “Colisure
Test”),
referenced
in
2193
Section
611.526.
2194
2195
NCRP.
National
Council
on
Radiation
Protection,
7910 Woodmont
Ave.,
2196
Bethesda,
MD
(301-657-2652).
2197
2198
“Maximum
Permissible
Body
Burdens
and
Maximum
Permissible
2199
Concentrations
of
Radionuclides
in
Air
and in
Water for
2200
Occupational
Exposure,”
NCRP
Report
Number
22,
June
5, 1959,
2201
referenced
in Section
611.101.
2202
2203
NSF.
National
Sanitation
Foundation
International,
3475
Plymouth
Road,
2204
P0 Box
130140,
Ann
Arbor,
Michigan
48113-0140
(734-769-8010).
2205
2206
NSF
Standard
61,
section
9, November
1998,
referenced
in
2207
Sections
611.126
and
611.356.
2208
2209
NTIS.
National
Technical
Information
Service,
U.S.
Department
of
2210
Commerce,
5285
Port
Royal
Road,
Springfield,
VA
22161
(703-487-4600
2211
or
800-553-6847).
2212
2213
“Interim
Radiochemical
Methodology
for Drinking
Water,”
EPA
2214
600/4-75-008
(revised),
March
1976
(referred
to as
“USEPA
2215
Interim
Radiochemical
Methods”),
referenced
in Section
611.720.
2216
(Pages
1, 4,
6, 9,
13, 16,
24, 29,
34)
2217
2218
“Kelada
Automated
Test
Methods
for
Total Cyanide,
Acid
2219
Dissociable
Cyanide,
andAn4
Thiocyanate,”
Revision
1.2,
August
2220
2001,
EPA
821/B-01-009
(referred
to
as “Kelada
01”),
referenced
2221
in
Section
611.611.
2222
2223
“Maximum
Permissible
Body
Burdens
and
Maximum
Permissible
2224
Concentrations
of Radionuclides
in Air
and
in
Water for
2225
Occupational
Exposure,”
NBS
(National
Bureau
of
Standards)
2226
Handbook
69, as
amended
August
1963,
U.S.
Department
of
JCAR35O61
1-0814065r01
2227
Commerce,
referenced
in
Section 611.330.
2228
2229
Method
100.1,
“Analytical
Method for
Determination
of Asbestos
2230
Fibers
in Water,”
EPA
600/4-83-043,
September
1983, Doc.
No.
2231
PB83-26047
1
(referred to
as
“USEPA
Asbestos
Methods-
100.1
“),
2232
referenced
in
Section 611.611.
2233
2234
Method
100.2,
“Determination
of Asbestos
Structures
over
10-mm
2235
in Length
in Drinking
Water,” EPA
600/R-94-134,
June
1994,
2236
Doc.
No.
PB94-20
1902
(referred
to as “USEPA
Asbestos
2237
Methods-100.2”),
referenced
in
Section 611.611.
2238
2239
“Methods
for Chemical
Analysis
of Water
and Wastes,”
March
2240
1983,
EPA 600/4-79-020,
Doc. No.
PB84-128677
(referred
to
as
2241
“USEPA
Inorganic
Methods”).
(Methods
150.1,
150.2,
and
245.2,
2242
which
formerly
appeared
in this reference,
are
available
from
2243
USEPA
EMSL.),
referenced
in Section
611.611.
2244
2245
“Methods
for the
Determination
of Inorganic
Substances
in
2246
Environmental
Samples,”
August
1993, EPA
600/R-93-100,
Doc.
2247
No.
PB94-120821
(referred
to as
“USEPA
Environmental
2248
Inorganic
Methods”),
referenced
in
Sections
611.381, 611.53
1,
and
2249
611.611.
(Formethods
180.1,300.0,335.4,353.2,and365.1.)
2250
2251
“Methods
for
the
Determination
of
Metals
in Environmental
2252
Samples,”
June 1991,
EPA 600/4-91-010,
Doc. No.
PB91-231498
2253
and “Methods
for
the
Determination
of
Metals
in Environmental
2254
Samples
— Supplement
I,” May
1994, EPA
600/R-94-111,
Doc.
2255
No. PB95-125472
(referred
to as
“USEPA
Environmental
Metals
2256
Methods”),
referenced
in
Sections
611.611,
611.612,
and 611.720.
2257
(For methods
200.7,
200.8, 200.9,
and 245.1.)
2258
2259
“Methods
for the
Determination
of Organic
and Inorganic
2260
Compounds
in Drinking
Water, Volume
1”
August
2000,
EPA
2261
815/R-00/014,
Doc.
No.
PB2000-106981
(referred
to
as “USEPA
2262
Organic
and
Inorganic
Methods”),
referenced
in Section
611.381.
2263
(Formethods
300.1 and
321.8.)
2264
2265
“Methods
for
the
Determination
of
Organic
Compounds
in
2266
Drinking
Water,” December
1988,
revised
July 1991,
EPA 600/4-
2267
88/039,
Doc. No.
PB91-23 1480
(referred
to
as “USEPA
Organic
2268
Methods”),
referenced
in
Sections 611.645
and
611.648. (For
2269
methods
502.2, 505,
507,
508, 508A,
515.1,
and
531.1.)
JCAR35O61
1-0814065r01
2270
2271
“Methods
for the Determination
of Organic
Compounds
in
2272
Drinking
Water — Supplement
I,” July 1990,
EPA 600/4-90/020,
2273
Doc.
No.
PB91-146027
(referred
to as
“USEPA Organic
2274
Methods”),
referenced
in Section
611.645.
(For
methods 506,
547,
2275
550,
550.1,
and 551.)
2276
2277
“Methods
for
the
Determination
of
Organic Compounds
in
2278
Drinking
Water
— Supplement
II,”
August
1992,
EPA
600/R-
2279
92/129,
Doc.
No.
PB92-207703
(referred
to
as
“USEPA
Organic
2280
Methods”),
referenced
in
Sections
611.381
and
611.645. (For
2281
methods
515.2, 524.2,
548.1,
549.1,
552.1,
and 555.)
2282
2283
“Methods
for
the
Determination
of Organic
Compounds
in Drinking
2284
Water —
Supplement
III,” August
1995,
EPA
600/R-95/131,
Doc.
2285
No. PB95-261616,
(referred
to as “USEPA
Organic
Methods”),
2286
referenced
in Sections
611.381
and 611.645.
(For methods
502.2,
2287
524.2, 551.1,
and
552.2.)
2288
2289
“Prescribed
Procedures
for
Measurement
of Radioactivity
in
2290
Drinking
Water,”
EPA
600/4-80/032,
August
1980
(Doc.
No.
PB
2291
80-224744)
(referred
to as “USEPA
Radioactivity
Methods”),
2292
referenced
in Section
611.720.
(For
methods 900,
901,
901.1,
902,
2293
903,
903.1,
904,
905, 906,
908, 908.1)
2294
2295
“Procedures
for
Radiochemical
Analysis
of
Nuclear
Reactor
2296
Aqueous
Solutions,”
H.L.
Krieger
and
S.
Gold,
EPA-R4-73-014,
2297
May
1973, Doe.
No.
PB222-154/7BA,
referenced
in Section
2298
611.720.
2299
2300
“Radiochemical
Analytical
Procedures
for
Analysis
of
2301
Environmental
Samples,”
March
1979,
Doc.
No.
EMSL
LV
2302
053917
(referred
to
as
“USEPA
Radiochemical
Analyses”),
2303
referenced
in Section
611.720.
(Pages
1, 19,
33,
65,
87,
92)
2304
2305
“Radiochemistry
Procedures
Manual,”
EPA
520/5-84-006,
August
2306
1984,
Doc. No.
PB84-215581
(referred
to
as “USEPA
2307
Radiochemistry
Methods”),
referenced
in Section
611.720.
2308
(Methods
00-01,
00-02, 00-07,
H-02,
Ra-03,
Ra-04,
Ra-05,
Sr-04)
2309
2310
“Technical
Notes
on
Drinking Water
Methods,”
EPA
600/R-
2311
94/173,
October
1994,
Doe. No.
PB95-104766
(referred
to as
2312
“USEPA Technical
Notes”),
referenced
in Sections
611.53 1,
JCAR35O61
1-0814065r01
2313
611.611,and6ll.685.
2314
2315
BOARD
NOTE:
USEPA
made
the
following
assertion
with
2316
regard
to
this reference
at 40 CFR
141.23(k)(1)
and 141.24(e)
and
2317
(n)(1 1)
(2007)E2OO6:
“This
document
contains other
analytical
2318
test procedures
and
approved
analytical
methods
that remain
2319
available
for compliance
monitoring
until
July
1, 1996.”
Also
2320
available
online
at http://nepis.epa.gov/EPA/html/Pubs/
2321
pubtitleORD.htm
under
the
document
designation
“600R94173.”
2322
2323
“Method
1613: Tetra-
through
Octa-Chlorinated
Dioxins
and
2324
Furans
by Isotope
Dilution
HRGC/HRMS,”
October
1994,
EPA
2325
821/B-94/005,
Doc.
No. 94-104774
(referred
to
as “Dioxin
and
2326
Furan Method
1613”),
referenced
in
Section 611.645.
2327
2328
USEPA
Method 326.0,
Revision
1.0, “Determination
of Inorganic
2329
Oxyhalide
Disinfection
By-Products
in
Drinking
Water
Using
Ion
2330
Chromatography
Incorporating
the Addition
of a
Suppressor
2331
Acidified
Postcolumn
Reagent
for Trace
Bromate
Analysis,”
2332
USEPA,
June 2002,
EPA 815/R-03/007,
Doc.
No.
PB2003-107402
2333
(referred
to as “OGWDW
Methods,
Method
326.0,
rev. 1.0”),
2334
referenced
in Sections
611.381
and 611.382.
2335
2336
BOARD
NOTE:
Also available
from
United States
Environmental
2337
Protection
Agency,
Office
of Ground
Water and
Drinking
Water.
2338
2339
New
Jersey
Department
of Environment,
Division of
Environmental
2340
Quality, Bureau
of
Radiation
and
Inorganic
Analytical
Services,
9
Ewing
2341
Street,
Trenton,
NJ
08625.
2342
2343
“Determination
of
Radium
228
in
Drinking Water,”
August
1990
2344
(referred
to as
“New Jersey
Radium
Method”),
referenced
in
2345
Section
611.720.
2346
2347
New
York
Department
of
Health, Radiological
Sciences
Institute,
Center
2348
for
Laboratories
and Research,
Empire
State
Plaza, Albany,
NY
12201.
2349
2350
“Determination
of
Ra-226
and Ra-228
(Ra-02),”
January
1980,
2351
Revised
June
1982 (referred
to as
“New York
Radium
Method”),
2352
referenced
in Section
611.720.
2353
2354
Palintest,
Ltd., 21
Kenton
Lands
Road,
P.O. Box
18395,
Erlanger, KY
2355
(800-835-9629).
JCAR35O61
1-0814065r01
2356
2357
“Lead
in
Drinking
Water by Differential
Pulse Anodic
Stripping
2358
Voltammetry,”
Method
1001, August
1999 (referred to as
2359
“Palintest
Method
1001”), referenced
in Section 611.611.
2360
2361
Standard
Methods Online,
available online
from the Standard
Methods
2362
Organization
at
www.standardmethods.org.
2363
2364
Method
6610
B-04, Carbamate
Pesticides,
High-Performance
2365
Liquid Chromatographic
Method,
referenced
in Section 6 11.645.
2366
2367
Method 9230 B-04,
Fecal Streptococcus
and Enterococcus
Groups,
2368
Multiple
Tube
Techniques,
referenced
in Section
611.802.
2369
2370
Syngenta
Crop Protection, Inc.,
410
Swing
Road, Post Office Box
18300,
2371
Greensboro,
NC
27419
(336-632-6000).
2372
2373
“Atrazine
in Drinking
Water by Irnmunoassay,”
February
2001
2374
(referred
to as “Syngenta
AG-625”),
referenced in Section
2375
611.645.
2376
2377
United States
Department
of Energy, available
at the Environmental
2378
Measurements
Laboratory,
U.S.
Department
of Energy,
376 Hudson
2379
Street,
New York, NY 10014-3621.
2380
2381
“EML Procedures
Manual,”
27
th
Edition,
Volume
1, 1990 (referred
2382
to as “USDOE
Manual”),
referenced
in Section 611.720.
2383
2384
United
States
Environmental
Protection
Agency, Office
of Ground
Water
2385
and
Drinking Water (accessible
on-line
and available
by download from
2386
http
://www.epa.gov/safewater/rnethods/).
2387
2388
USEPA
OGWDW
Methods, Method
317.0, Revision
2.0,
2389
“Determination
of
Inorganic
Oxyhalide
Disinfection
By-Products
2390
in
Drinking
Water
Using Ion Chromatography
with
the Addition
of
2391
a Postcolumn Reagent
for
Trace
Bromate Analysis,”
USEPA, July
2392
2001,
EPA
815/B-01/001
(referred
to as “OGWDW
Methods,
2393
Method 317.0, rev.
2.0”),
referenced
in
SectionsSection
611.381
2394
and 611.382.
2395
2396
USEPA
OGWDW Methods,
Method 326.0,
Revision 1.0,
2397
“Determination
of Inorganic
Oxyhalide
Disinfection By-Products
2398
in Drinking
Water Using
Ion Chromatography
Incorporating
the
JCAR35O61 1-0814065r01
2399
Addition
of a
Suppressor Acidified
Postcolumn
Reagent
for Trace
2400
Bromate Analysis,”
USEPA, June
2002, EPA
815/R-03/007
2401
(referred
to as
“OGWDW
Methods, Method
326.0,
rev. 1.0”),
2402
referenced in
Sections 611.381
and 611.382.
2403
2404
BOARD
NOTE:
Also
available from NTIS.
2405
2406
USEPA
OGWDW Methods,
Method
327.0,
Revision 1.1,
2407
“Determination
of
Chlorine Dioxide and
Chlorite Ion in
Drinking
2408
Water Using
Lissamine
Green B and
Horseradish Peroxidase
with
2409
Detection
by Visible
Spectrophotometry,”
USEPA,
May 2005,
2410
EPA 815/R-05/008
(referred
to as “OGWDW
Methods, Method
2411
327.0, rev.
1.1”), referenced
in SectionsSection
611.381 and
2412
611.531.
2413
2414
USEPA
OGWDW
Methods, Method
515.4,
Revision 1.0,
2415
“Determination
of
Chlorinated
Acids in Drinking
Water
by Liquid-
2416
Liquid Microextraction,
Derivatization
and
Fast
Gas
2417
Chromatography
with
Electron
Capture Detection,”
April 2000,
2418
EPA 815/B-00/001
(document
file name
“metSlS_4.pdf’)
2419
(referred to as
“OGWDW
Methods,
Method 515.4,
rev. 1.0”),
2420
referenced
in Section 611.645.
2421
2422
US
EPA
OGWDW Methods,
Method
531.2,
Revision 1.0,
2423
“Measurement
of
N-methylcarbamoyloximes
and
N-
2424
methylcarbamates
in Water
by
Direct
Aqueous Injection
HPLC
2425
with
Postcolumn
Derivatization,”
September
2001,
EPA
815/B-
2426
01/002
(document file
name “metS3l_2.pdf’)
(referred to
as
2427
“OGWDW
Methods,
Method 531.2, rev.
1.0”), referenced
in
2428
Section 611.645.
2429
2430
USEPA OGWDW
Methods,
Method
552.3,
Revision
1.0,
2431
“Determination
of Haloacetic
Acids and
Dalapon in Drinking
2432
Water by
Liquid-liquid
Microextraction, Derivatization,
and
Gas
2433
Chromatography
with Electron
Capture Detection,”
USEPA,
July
2434
2003,
EPA
815/B-03/002
(referred to as “OGWDW
Methods,
2435
Method
552.3, rev. 1.0”), referenced
in
SectionsSection 611.381
2436
and 611.645.
2437
2438
USEPA
OGWDW Methods,
Method
1622 (05), “Method
1622:
2439
Cryptosporidium
in Water
by
FiltrationllMS/FA,”
December
2005,
2440
EPA
815/R-05/001
(referred to as “USEPA
Method
1622
(05)”),
2441
referenced in Sections
611.1004
and 611.1007.
JCAR35O61
1-0814065r01
2442
2443
USEPA
OGWDW
Methods,
Method
1622
(01), “Method
1622:
2444
Cryptosporidium
in
Water
by Filtration/IMS/FA,”
April
2001,
2445
EPA
821/R-01/026,
(referred
to as “USEPA
Method
1622 (01)”),
2446
referenced
in Section
611.1007.
2447
2448
USEPA
OGWDW
Methods,
Method 1622
(99),
“Method
1622:
2449
Cryptosporidium
in
Water
by FiltrationllMS/FA,”
April 1999,
2450
EPA
821tR-99/001,
(referred
to
as
“USEPA
Method
1622
(99)”),
2451
referenced
in Section
611.1007.
2452
2453
USEPA
OGWDW
Methods,
Method
1623 (05),
“Method
1623:
2454
Cryptosporidium
and
Giardia
in Water
by
Filtration/IMS/FA,”
2455
December
2005,
EPA
815/R-05/002
(referred
to as
“USEPA
2456
Method 1623
(05)”),
referenced
in Sections
611.1004
and
2457
611.1007.
2458
2459
USEPA
OGWDW
Methods,
Method
1623
(01), “Method
1623:
2460
Cryptosporidium
and
Giardia in
Water
by
FiltrationllMS/FA,”
2461
April
2001,
EPA
821/R-01/025
(referred
to as “USEPA
Method
2462
1623 (01)”),
referenced
in
Section
611.1007.
2463
2464
USEPA
OGWDW
Methods,
Method 1623
(99), “Method
1623:
2465
Cryptosporidium
and
Giardia
in Water
by FiltrationllMS/FA,”
2466
January
1999, EPA
821/R-99/006
(referred
to as
“USEPA
Method
2467
1623
(99)”),
referenced
in
Sections 611.1007.
2468
2469
United
States Environmental
Protection
Agency,
EMSL,
Cincinnati,
OH
2470
45268
(513-569-7586).
2471
2472
“Interim
Radiochemical
Methodology
for
Drinking
Water,”
EPA
2473
600/4-75/008
(revised),
March
1976
(referred
to
as “USEPA
2474
Interim
Radiochemical
Methods”),
referenced
in
Section 611.720.
2475
See NTIS.
2476
2477
“Methods
for the Determination
of Organic
Compounds
in
2478
Drinking
Water,”
December
1988, revised
July 1991,
EPA
600/4-
2479
88/039 (referred
to
as
“USEPA
Organic
Methods”),
referenced
in
2480
Sections
611.645
and 611.648.
(For
methods
504.1, 508.1,
and
2481
525.2
only.) See
NTIS.
2482
2483
“Procedures
for
Radiochemical
Analysis
of
Nuclear Reactor
2484
Aqueous
Solutions,”
referenced
in Section
611.720.
See NTIS.
JCAR35O61
1-0814065r01
2485
2486
USEPA,
Office
of Research
and Development,
National Exposure
2487
Research Laboratory,
Microbiological
& Chemical
Exposure
Assessment
2488
Research
Division
(accessible
on-line
and available by download
from
2489
http
://www.epa.gov/nerlcwww/ordmeth.htm).
2490
2491
USEPA
Method
200.5, Revision
4.2, “Determination
of Trace
2492
Elements
in Drinking
Water
by
Axially
Viewed
Inductively-
2493
Coupled
Plasma
— Atomic
Emission Spectrometry,”
October
2003,
2494
EPA
600/R-06/1
15
(referred
to
as
“USEPA
NERL Method
2495
200.5”),
referenced
in Sections
611.611 and 611.612.
2496
2497
USEPA
Method
415.3, Revision
1.1, “Determination
of Total
2498
Organic
Carbon and
Specific UV
Absorbance at 254
nm in
Source
2499
Water
and Drinking
Water,” February
2005,
EPA
600/R-05/055
2500
(referred
to
as “USEPANERL
Method 415.3 (rev. 1.1)”),
2501
referenced
in Section
611.381.
2502
2503
USEPA,
Science
and Technology
Branch,
Criteria and Standards
2504
Division,
Office
of Drinking
Water, Washington,
D.C. 20460.
2505
2506
“Guidance
Manual
for
Compliance
with the Filtration
and
2507
Disinfection
Requirements
for
Public Water Systems
using
Surface
2508
Water Sources,”
October 1989,
referenced
in
Sections 611.111 and
2509
611.212.
2510
2511
USEPA
Water Resource
Center (RC-4100T),
1200 Pennsylvania
Avenue,
2512
NW,
Washington,
DC 20460:
2513
2514
“Charm
E*Colite
Presence/Absence
Test for
Detection and
2515
Identification
of Coliform
Bacteria and Escherichia
coli in
2516
Drinking Water,”
January 9, 1998
(referred to
as
“E*Colite
Test”),
2517
referenced
in
Section 611.802
(also
available from
Charm
2518
Sciences, Inc.).
2519
2520
“Total Coliforms
and E. coli Membrane
Filtration
Method with m
2521
ColiBlue24®
Broth,” Method
No. 10029, Revision
2, August
17,
2522
1999 (referred
to as “m-ColiBlue24
Test”), referenced
in Section
2523
611.802 (also
available
from
The
Hach Company).
2524
2525
“EPA
Method 1600: Enterococci
in Water
by Membrane Filtration
2526
Using
Membrane-Enterococcus
Jndoxyl-b-D-Glucoside
Agar
2527
(mEl),”
September 2002,
EPA 821/R-02/022
(referred
to as
JCAR35O61
1-0814065r01
2528
“USEPA
Method
1 600)
is an approved
variation
of
Standard
2529
Methods,
Method
9230
C,
“Fecal
Streptococcus
and Enterococcus
2530
Groups, Membrane
Filter
Techniques”
(which
has not
itself been
2531
approved
for use
by USEPA)
(accessible
on-line
and available
by
2532
download
from
http ://www.epa.gov/nerlcwww/
1600sp02
.pdf),
2533
referenced
in Section
611.802.
2534
2535
“Method
1601:
Male-specific
(F) and
Somatic
Coliphage
in
2536
Water
by Two-step
Enrichment
Procedure,”
April
2001, EPA
2537
821/R-01/030
(referred
to
as “USEPA
Method
1601”)
(accessible
2538
on-line
and
available
by download
from
2539
http ://www.epa.gov/nerlcwww/1
601
apO 1
.pdf), referenced
in
2540
Section
611.802.
2541
2542
“Method
1602:
Male-specific
(F) and
Somatic
Coliphage
in
2543
Water
by
Single
Agar Layer
(SAL)
Procedure,”
April 2001,
EPA
2544
821/R-01/029
(referred
to as “USEPA
Method
1602”)
(accessible
2545
on-line
and
available
by download
from
2546
http ://www.epa.gov/nerlcwww/1
602ap0 1 .pdf),
referenced
in
2547
Section
611.802.
2548
2549
“Method
1604: Total
Coliforms
and Escherichia
coli
in
Water
by
2550
Membrane
Filtration
Using
a Simultaneous
Detection
Technique
2551
(MI
Medium),”
September
2002,
EPA
8211R-02/024
(referred
to
2552
as “USEPA
Method
1604”)
(accessible
on-line and
available
by
2553
download
from
http
://www.epa.gov/nerlcwww/1
604sp02.pdf),
2554
referenced
in
Section
611.802.
2555
2556
USGS.
Books
and Open-File
Reports
Section,
United States
Geological
2557
Survey,
Federal
Center,
Box
25286,
Denver,
CO
80225-0425.
2558
2559
Methods
available
upon
request
by method
number
from “Methods
2560
for Analysis
by
the
U.S. Geological
Survey
National Water
2561
Quality
Laboratory
— Determination
of
Inorganic
and
Organic
2562
Constituents
in
Water
and
Fluvial
Sediments,”
Open File
Report
2563
93-125,
1993,
or
Book
5, Chapter
A-i, “Methods
for
2564
Determination
of
Inorganic
Substances
in
Water
and
Fluvial
2565
Sediments,”
3rd
ed.,
Open-File
Report
85-495,
1989,
as
2566
appropriate
(referred
to as
“USGS
Methods”).
2567
2568
1-1030-85,
referenced
in Section
611.611.
2569
2570
1-1601-85,
referenced
in Section
611.611.
JCAR35O61 1-0814065r01
2571
2572
1-1700-85,
referenced
in
Section
611.611.
2573
2574
1-2598-85,
referenced
in Section
611.611.
2575
2576
1-2601-90,
referenced
in Section
611.611.
2577
2578
1-2700-85,
referenced
in Section
611.611.
2579
2580
1-3300-85,
referenced
in
Section
611.611.
2581
2582
Methods
available
upon
request
by
method
number
from
“Methods
2583
for
Determination
of
Radioactive
Substances
in
Water
and
Fluvial
2584
Sediments,”
Chapter
AS
in Book
5 of “Techniques of
Water
2585
Resources
Investigations
of the
United
States
Geological
Survey,”
2586
1997.
2587
2588
R-1110-76,
referenced
in
Section
611.720.
2589
2590
R-1111-76,
referenced
in
Section
611.720.
2591
2592
R-1120-76,
referenced
in
Section
611.720.
2593
2594
R-1140-76,
referenced
in
Section
611.720.
2595
2596
R-1
141-76,
referenced
in
Section
611.720.
2597
2598
R-1
142-76,
referenced
in
Section
611.720.
2599
2600
R-1
160-76,
referenced
in
Section
611.720.
2601
2602
R-1171-76,
referenced
in
Section
611.720.
2603
2604
R-1 180-76,
referenced
in
Section
611.720.
2605
2606
R-1
18 1-76,
referenced
in
Section
611.720.
2607
2608
R-1
182-76,
referenced
in
Section
611.720.
2609
2610
Waters
Corporation,
Technical
Services
Division,
34
Maple
St.,
Milford,
2611
MA 01757
(800-252-4752
or 508-482-2131,
fax: 508-482-3625).
2612
2613
“Waters
Test
Method
for
Determination
of
Nitrite/Nitrate
in Water
JCAR35O61
1-0814065r01
2614
Using Single
Column Ion
Chromatography,”
Method B-101 1,
2615
August 1987
(referred
to as “Waters Method
B-101 1”), referenced
2616
in Section
611.611.
2617
2618
c)
The Board
incorporates
the
following
federal regulations
by reference:
2619
2620
40 CFR 3.2
(2007)(2006)
(How Does
This Part Provide for
Electronic
2621
Reporting?),
referenced
in Section 611.105.
2622
2623
40
CFR
3.3 (2007(2006)
(What Definitions
Are Applicable
to This
2624
Part?), referenced
in Section
611.105.
2625
2626
40
CFR 3.10
(2007)(2006)
(What Are the
Requirements for
Electronic
2627
Reporting to
EPA?), referenced
in Section
611.105.
2628
2629
40
CFR 3.2000 (2007)(2006)
(What Are the
Requirements Authorized
2630
State, Tribe,
and
Local Programs’
Reporting Systems
Must Meet?),
2631
referenced in Section
611.105.
2632
2633
40
CFR 136.3(a)
(2007)(2006),
referenced
in Section 611.1004.
2634
2635
Appendix
B to 40 CFR 136 (2007)(2006),
referenced in Sections
611.359,
2636
611.609, and
611.646.
2637
2638
d)
This Part incorporates
no later amendments
or
editions.
2639
2640
(Source:
Amended
at
32
Ill.
Reg.
effective
2641
2642
SUBPART G: LEAD
AND
COPPER
2643
2644
Section
611.350 General
Requirements
2645
2646
a)
Applicability and Scope
2647
2648
1)
Applicability.
The
requirements
of this Subpart
G
constitute
national
2649
primary
drinking water regulations
for lead
and copper. This Subpart
G
2650
applies to all
community
water systems
(CWSs)
and non-transient,
non
2651
community
water
systems
(NTNCWS5).
2652
2653
2)
Scope.
This
Subpart
G
establishes
a treatment technique
that includes
2654
requirements
for
corrosion control treatment,
source
water treatment, lead
2655
service line replacement,
and public
education.
These requirements are
2656
triggered,
in some
cases,
by lead
and copper action
levels
measured
in
JCAR35O61
l-0814065r01
2657
samples
collected at
consumers’
taps.
2658
2659
b)
Definitions.
For
the purposes
of only
this Subpart
G, the
following
terms
have the
2660
following
meanings:
2661
2662
“Action
level”
means
that
concentration
of lead
or
copper in water
2663
computed
pursuant
to subsection
(c) of
this Section
that determines,
in
2664
some
cases, the
treatment
requirements
of this
Subpart
G
that a supplier
2665
must
complete.
The
action
level
for lead
is
0.0 15
mg!e. The
action level
2666
for
copper is
1.3 mg!E.
2667
2668
“Corrosion
inhibitor”
means
a
substance
capable
of
reducing
the
2669
corrosivity
of water
toward
metal plumbing
materials,
especially
lead
and
2670
copper,
by forming
a protective
film on
the interior
surface of
those
2671
materials.
2672
2673
“Effective
corrosion
inhibitor residual”
means
a
concentration
of
inhibitor
2674
in the
drinking
water sufficient
to form
a passivating
film
on
the interior
2675
walls of
a pipe.
2676
2677
“Exceed,”
as
this
term
is
applied
to either
the lead
or
the copper
action
2678
level,
means
that
the
90th
percentile
level
of the
supplier’s
samples
2679
collected
during
a six-month
monitoring
period
is
greater
than
the action
2680
level for
that
contaminant.
2681
2682
“First
draw sample”
means
a one-liter
sample
of tap
water,
collected
in
2683
accordance
with
Section
611
.356(b)(2),
that
has
been standing
in
2684
plumbing
pipes
for
at least
six hours
and which
is
collected
without
2685
flushing
the tap.
2686
2687
“Large
system”
means a water
system
that regularly
serves
water to more
2688
than 50,000
persons.
2689
2690
“Lead
service line”
means a
service line
made
of
lead
that
connects
the
2691
water
main to the
building
inlet,
including
any lead
pigtail,
gooseneck,
or
2692
other fitting
that is
connected
to
such
lead
line.
2693
2694
“Maximum
permissible
concentration”
or “MPC”
means that
2695
concentration
of
lead
or
copper
for
finished
water
entering
the supplier’s
2696
distribution
system,
designated
by
the Agency
by
a
SEP
pursuant to
2697
Sections 611.110
and
611.353(b)
that reflects
the contaminant
removal
2698
capability
of the
treatment
properly
operated
and
maintained.
2699
BOARD NOTE:
Derived
from 40
CFR
141.83(b)(4)
(2007)(2002).
(See
JCAR35O61
1-0814065r01
2700
Section
611.353(b)(4)(B).)
2701
2702
“Medium-sized
system”
means
a water
system
that
regularly
serves
water
2703
to more
than
3,300 up
to
50,000
or
fewer persons.
2704
2705
“Meet,”
as
this
term
is applied
to
either
the lead
or
the
copper
action
level,
2706
means
that the
90
th
percentile
level
of
the
supplier’s
samples
collected
2707
during
a six-month
monitoring
period
is
less than
or equal
to the
action
2708
level
for
that
contaminant.
2709
2710
“Method
detection
limit”
or
“MDL”
is
as defined
at Section
6
11.646(a).
2711
The
MDL
for lead
is 0.00
1 mg/F.
The MDL
for
copper
is 0.00
1 mg/F,
or
2712
0.020
mg/F
by atomic
absorption
direct aspiration
method.
2713
BOARD
NOTE:
Derived
from
40
CFR
141
.89(a)(1)(iii)
(2007)(2002).
2714
2715
“Monitoring
period”
means
any
of the
six-month
periods
of time
during
2716
which
a
supplier
must
complete
a
cycle of
monitoring
under
this
Subpart
2717
G.
2718
BOARD
NOTE:
USEPA
refers
to
these
as “monitoring
periods.”
The
2719
Board
uses “six-month
monitoring
period”
to
avoid
confusion
with
2720
“compliance
period,”
as used
elsewhere
in
this Part
and
defined
at
Section
2721
611.101.
2722
2723
“Multiple-family
residence”
means
a building
that
is currently
used as
a
2724
multiple-family
residence,
but
not
one
that is
also a “single-family
2725
structure.”
2726
2727
,,
90
th
percentile
level”
means
that
concentration
of lead
or copper
2728
contaminant exceeded
by
ten percent
or
fewer
of all
samples
collected
2729
during
a
six-month
monitoring
period
pursuant
to Section
611.356
(i.e.,
2730
that concentration
of
contaminant
greater
than
or
equal
to the
results
2731
obtained
from
90
percent
of the
samples).
The
90
th
percentile
levels
for
2732
copper
and
lead
must
be determined
pursuant
to
subsection
(c)(3)
of this
2733
Section.
2734
BOARD
NOTE:
Derived
from
40
CFR 141.80(c)
(2007)(2002).
2735
2736
“Optimal
corrosion
control
treatment”
means
the
corrosion
control
2737
treatment
that
minimizes
the lead
and
copper
concentrations
at
users’
taps
2738
while
ensuring
that
the treatment
does
not cause
the water
system
to
2739
violate
any
national
primary
drinking
water
regulations.
2740
2741
“Practical
quantitation
limit”
or “PQL”
means
the lowest
concentration
of
2742
a contaminant
that a
well-operated
laboratory
can
reliably
achieve
within
JCAR35O61
1-0814065r01
2743
specified
limits
of
precision
and
accuracy
during
routine
laboratory
2744
operating
conditions.
The
PQL for
lead
is
0.005
mg/C.
The
PQL
for
2745
copper
is 0.050
mg/C.
2746
BOARD
NOTE:
Derived
from
40 CFR
141.89(a)(1)(ii)
and
(a)(1)(iv)
2747
(2007)(2002).
2748
2749
“Service
line sample”
means
a
one-liter
sample
of water,
collected
in
2750
accordance
with
Section
61 1.356(b)(3),
that
has been
standing
for at
least
2751
six
hours
in
a service
line.
2752
2753
“Single-family
structure”
means
a building
that
was
constructed
as
a
2754
single-family
residence
and
which
is
currently
used
as either
a
residence
2755
or
a place
of business.
2756
2757
“Small
system”
means
a water
system
that
regularly
serves
water
to 3,300
2758
or
fewer persons.
2759
BOARD
NOTE:
Derived
from
40
CFR
141.2
(2007)(2002).
2760
2761
c)
Lead
and
Copper
Action
Levels.
2762
2763
1)
The
lead
action
level
is
exceeded
if
the
90
th
percentile
lead
level
is greater
2764
than
0.0
15
mg/C.
2765
2766
2)
The copper
action
level
is
exceeded
if the 9O
percentile
copper
level
is
2767
greater
than
1.3
mg/C.
2768
2769
3)
Suppliers
must
compute
the
90
th
percentile
lead
and
copper
levels
as
2770
follows:
2771
2772
A)
List
the
results
of all
lead
or
copper
samples
taken
during
a
six-
2773
month
monitoring
period
in ascending
order,
ranging
from
the
2774
sample
with
the
lowest
concentration
first
to
the sample
with
the
2775
highest
concentration
last. Assign
each
sampling
result
a
number,
2776
ascending
by
single
integers
beginning
with the
number
1 for
the
2777
sample
with the
lowest
contaminant
level. The
number
assigned
to
2778
the
sample
with
the
highest
contaminant
level
must
be
equal
to the
2779
total
number
of
samples
taken.
2780
2781
B)
Determine
the
number
for
the 9O
percentile
sample
by
2782
multiplying
the
total
number
of
samples
taken
during
the
six
2783
month
monitoring
period
by
0.9.
2784
2785
C)
The
contaminant
concentration
in the
sample
with the
number
JCAR35O6I
1-0814065r01
2786
yielded
by
the
calculation
in subsection
(c)(3)(B)
of this Section
is
2787
the
90
th
percentile
contaminant
level.
2788
2789
D)
For
suppliers
that
collect
five samples
per
six-month
monitoring
2790
period, the
90
th
percentile
is computed
by
taking
the average
of the
2791
highest
and
second
highest concentrations.
2792
2793
)
For a supplier
that
has been allowed
by the
Agency
to collect fewer
2794
than
five
samples
in
accordance
with Section
611.356(c),
the
2795
sample
result
with
the highest
concentration
is considered
the
90
th
2796
percentile
value.
2797
2798
d)
Corrosion
Control
Treatment
Requirements.
2799
2800
1)
All
suppliers
must
install and
operate optimal
corrosion
control
treatment.
2801
2802
2)
Any supplier
that
complies
with
the applicable
corrosion
control treatment
2803
requirements
specified
by
the Agency
pursuant
to
Sections
611.351
and
2804
611.352
is deemed
in
compliance
with
the
treatment
requirement
of
2805
subsection
(d)(1)
of this
Section.
2806
2807
e)
Source
water
treatment
requirements.
Any supplier
whose
system
exceeds
the
2808
lead or
copper
action
level
must
implement
all
applicable
source water
treatment
2809
requirements
specified
by
the Agency
pursuant
to Section
611.353.
2810
2811
f)
Lead
service
line
replacement
requirements.
Any supplier
whose
system exceeds
2812
the
lead action
level
after implementation
of applicable
corrosion
control and
2813
source
water
treatment
requirements
must complete
the
lead service
line
2814
replacement
requirements
contained
in Section
611.354.
2815
2816
g)
Public
education
requirements.
Pursuant
to
Section
611.355,
the
supplier
must
2817
provide
a consumer
notice
of the
lead
tap
water
monitoring
results
to the persons
2818
served
at each
site
(tap)
that is
tested.
Any supplier
whose
system exceeds
the
2819
lead
action
level
must
implement
the
public
education
requirements
contained
in
2820
Section
611.355.
2821
2822
h)
Monitoring
and analytical
requirements.
Suppliers
must
complete
all
tap water
2823
monitoring
for lead and
copper, monitoring
for
water quality
parameters,
source
2824
water
monitoring
for
lead and copper,
and
analyses of
the monitoring
results
2825
under
this
Subpart
Gin
compliance
with
Sections 611.356,
611.357,
611.358,
and
2826
611.359.
2827
2828
i)
Reporting
requirements.
Suppliers
must
report
to
the Agency
any information
JCAR35O61
1-0814065r01
2829
required
by
the
treatment
provisions
of this
Subpart
G
and
Section
6
11.360.
2830
2831
j)
Recordkeeping
requirements.
Suppliers
must
maintain
records
in accordance
with
2832
Section
611.361.
2833
2834
k)
Violation
of
national
primary
drinking
water
regulations. Failure
to
comply
with
2835
the applicable
requirements
of this
Subpart
G,
including
conditions
imposed
by
2836
the
Agency
by SEP
pursuant
to these
provisions
and
Section
611.110,
will
2837
constitute
a
violation
of
the
national
primary
drinking
water
regulations
for
lead
2838
or
copper.
2839
2840
BOARD
NOTE:
Derived
from
40
CFR
141.80
(2007),
as
amended at 72
Fed.
Reg.
2841
57782
(October
10,
2007)(2002).
2842
2843
(Source:
Amended
at
32
Ill.
Reg.
effective
2844
2845
Section
611.351
Applicability of
Corrosion
Control
2846
2847
a)
Corrosion
control
required. Suppliers
must
complete
the
applicable
corrosion
2848
control
treatment
requirements
described
in
Section
611.352
on
or before
the
2849
deadlines
set forth
in
this Section.
2850
2851
1)
Large
systems.
Each
large
system
supplier
(one
regularly
serving
more
2852
than
50,000
persons)
must
complete
the corrosion
control
treatment
steps
2853
specified
in
subsection (d)
of
this
Section,
unless
it is
deemed
to
have
2854
optimized
corrosion
control
under
subsection
(b)(2)
or
(b)(3)
of
this
2855
Section.
2856
2857
2)
Medium-sized and
small
systems.
Each
small
system
supplier
(one
2858
regularly
serving
3,300
or
fewer
persons)
and each
medium-sized
system
2859
(one
regularly
serving
more
than
3,300
up to
50,000
persons)
must
2860
complete
the
corrosion
control
treatment
steps
specified
in
subsection
(e)
2861
of
this Section,
unless
it is
deemed
to
have
optimized
corrosion
control
2862
under
one
of
subsections (b)(1),
(b)(2),
or
(b)(3)
of this
Section.
2863
2864
b)
Suppliers
deemed
to have
optimized
corrosion
control.
A supplier
is deemed
to
2865
have
optimized
corrosion
control, and
is not
required
to
complete
the applicable
2866
corrosion
control
treatment
steps
identified
in this
Section,
if
the supplier
satisfies
2867
one
of
the criteria
specified
in
subsections
(b)(1)
through
(b)(3)
of
this Section.
2868
Any
such
system
deemed
to have
optimized
corrosion
control
under
this
2869
subsection,
and
which
has
treatment
in
place,
must
continue
to
operate
and
2870
maintain
optimal
corrosion
control
treatment
and
meet
any
requirements
that
the
2871
Agency
detennines
are appropriate
to
ensure
optimal
corrosion
control
treatment
JCAR35O61
1-0814065r01
2872
is maintained.
2873
2874
1)
Small-
or
medium-sized
system
meeting action
levels.
A small
system or
2875
medium-sized
system
supplier
is deemed
to
have optimized
corrosion
2876
control
if
the
system
meets the
lead and
copper
action
levels during
each
2877
of two
consecutive
six-month
monitoring
periods with
monitoring
2878
conducted
in accordance
with
Section
611.356.
2879
2880
2)
SEP
for equivalent
activities
to corrosion
control.
The Agency
must,
by a
2881
SEP granted
pursuant to
Section
6 11.110,
deem
any
supplier
to have
2882
optimized
corrosion
control
treatment
if it
determines
that
the
supplier
has
2883
conducted
activities
equivalent
to the corrosion
control
steps
applicable
2884
under this
Section.
Tn
making
this determination,
the
Agency must
specify
2885
the
water
quality
control parameters
representing
optimal
corrosion
2886
control in
accordance
with Section
611.352(f).
A
water
supplier
that is
2887
deemed
to have
optimized
corrosion
control
under
this
subsection
(b)(2)
2888
must
operate
in compliance
with
the Agency-designated optimal
water
2889
quality
control parameters
in accordance
with
Section
611.352(g)
and
2890
must continue
to conduct
lead
and
copper
tap and
water
quality
parameter
2891
sampling
in accordance
with Sections
611.356(d)(3)
and
611.357(d),
2892
respectively.
A
supplier
must
provide
the
Agency
with
the following
2893
information
in order
to
support
an Agency
SEP determination
under
this
2894
subsection
(b)(2):
2895
2896
A)
The
results of
all
test
samples
collected
for
each
of
the water
2897
quality
parameters
in
Section
61 1.352(c)(3);
2898
2899
B)
A report
explaining
the
test
methods
the
supplier
used
to evaluate
2900
the
corrosion
control
treatments
listed
in
Section 61
1.352(c)(1),
the
2901
results
of all tests
conducted,
and the basis
for the supplie?s
2902
selection
of optimal
corrosion
control treatment;
2903
2904
C)
A report
explaining
how
the supplier
has
installed
corrosion
2905
control and
how the
supplier maintains
it to
insure minimal
lead
2906
and copper
concentrations
at
consume?s
taps;
and
2907
2908
D)
The results
of tap water
samples
collected
in accordance
with
2909
Section
611.356
at least
once every
six
months
for one
year after
2910
corrosion
control
has
been installed.
2911
2912
3)
Results less
than practical
quantitation
level
(PQL)
for
lead.
Any supplier
2913
is
deemed
to have
optimized
corrosion
control
if it
submits
results of
tap
2914
water
monitoring
conducted
in accordance
with
Section
6 11.356
and
JCAR35O61
1-0814065r01
2915
source
water
monitoring
conducted
in accordance
with
Section 611.358
2916
that
demonstrate
that
for two
consecutive six-month
monitoring
periods
2917
the
difference
between
the 90th percentile tap
water lead
level, computed
2918
pursuant
to Section 61 1.350(c)(3),
and
the highest source water
lead
2919
concentration
is less
than the practical
quantitation level
for lead specified
2920
in
Section
611 .359(a)(1)(B)(i).
2921
2922
A)
Those
systems
whose highest
source water lead
level
is below the
2923
method detection
limit (MDL)
may also be deemed
to have
2924
optimized
corrosion
control
under this subsection
(b) if the 90th
2925
percentile tap
water
lead level
is less than or equal
to
the PQL
for
2926
lead for
two
consecutive six-month
monitoring
periods.
2927
2928
B)
Any water system
deemed to have
optimized corrosion
control
in
2929
accordance
with
this subsection
(b)
must
continue
monitoring for
2930
lead
and
copper at
the tap no
less
frequently than once
every three
2931
calendar
years
using the reduced number
of sites
specified in
2932
Section
611.356(c)
and collecting
the samples at times
and
2933
locations
specified
in Section 61 1.356(d)(4)(D).
Any such system
2934
that
has
not conducted
a round
of monitoring pursuant
to Section
2935
611.356(d)
since
September 30, 1997,
must have
completed a
2936
round of monitoring
pursuant to
this subsection
(b) no later than
2937
September 30,
2000.
2938
2939
C)
Any water
system deemed
to have optimized
corrosion control
2940
pursuant
to this subsection
(b) must notify the
Agency in writing
2941
pursuant to
Section 61 1.360(a)(3)
of any
upcoming long-term
2942
change
in
treatment or the addition
of a new
source, as described
in
2943
that Section.
The
Agency
must
review and approve
the addition
of
2944
a new
source
or any long-term
change
in water
treatment before
2945
the addition or
long-term
change
is implemented
by
the water
2946
system require
any such system
to conduct
additional
monitoring
2947
or
to take other
action if the Agency
determines
that the additional
2948
monitoring is
necessary and appropriate
to ensure
that the supplier
2949
maintains
minimal
levels of corrosion
in its distribution
vtm
2950
2951
D)
AAs of July 12,
2001, a
supplier
is not deemed to
have optimized
2952
corrosion
control
under this subsection
(b), and
must implement
2953
corrosion control
treatment
pursuant to subsection
(b)(3)(E) of
this
2954
Section, unless
it
meets
the copper action level.
2955
2956
E)
Any
supplier
triggered
into
corrosion
control because it is
no
2957
longer
deemed
to
have optimized corrosion
control under
this
JCAR35O61
1-0814065r01
2958
subsection
must
implement
corrosion
control treatment
in
2959
accordance
with
the deadlines
in subsection
(e)
of this Section.
2960
Any such
large
system
supplier
must
adhere to
the schedule
2961
specified
in
that
subsection
(e) for
a medium-sized
system
supplier,
2962
with
the time periods
for
completing
each
step
being triggered
by
2963
the date
the
supplier
is
no longer deemed
to
have
optimized
2964
corrosion
control
under
this subsection
(b).
2965
2966
c)
Suppliers
not required
to
complete
corrosion
control
steps
for having
met
both
2967
action
levels.
2968
2969
1)
Any
small
system or
medium-sized
system
supplier,
otherwise
required
to
2970
complete
the
corrosion
control steps
due
to its
exceedence
of
the lead or
2971
copper
action
level,
may
cease
completing
the
treatment
steps after
the
2972
supplier
has
fulfilled both
of the
following conditions:
2973
2974
A)
It has met
both
the
copper
action
level
and
the lead
action
level
2975
during
each
of
two
consecutive
six-month
monitoring
periods
2976
conducted
pursuant
to Section
611.356;
and
2977
2978
B)
The
supplier has
submitted
the results
for
those
two
consecutive
2979
six-month
monitoring
periods
to the
Agency.
2980
2981
2)
A
supplier
that has ceased
completing
the
corrosion
control
steps pursuant
2982
to
subsection
(c)(1)
of this Section
(or the
Agency,
if appropriate)
must
2983
resume
completion
of the
applicable
treatment
steps,
beginning
with the
2984
first
treatment
step
that the supplier
previously
did
not complete
in its
2985
entirety,
if the
supplier
thereafter
exceeds
the lead
or
copper
action level
2986
during
any
monitoring
period.
2987
2988
3)
The
Agency
may,
by SEP,
require
a supplier
to repeat
treatment
steps
2989
previously
completed
by
the supplier
where
it
determines
that
this
is
2990
necessary
to
properly
implement
the treatment
requirements
of
this
2991
Section.
Any such SEP
must explain
the
basis
for
this
decision.
2992
2993
4)
The
requirement
for
any
small-
or medium-sized
system
supplier
to
2994
implement
corrosion control
treatment
steps in accordance
with
subsection
2995
(e)
of this
Section (including
systems
deemed
to
have optimized
corrosion
2996
control
under subsection
(b)(1)
of this Section)
is triggered
whenever
any
2997
small- or
medium-sized
system
supplier
exceeds
the lead
or copper
action
2998
level.
2999
3000
d)
Treatment
steps
and
deadlines for
large systems.
Except as
provided in
JCAR35O61 1-0814065r01
3001
subsections
(b)(2) and
(b)(3)
of this
Section, large
system
suppliers
must complete
3002
the
following
corrosion
control
treatment
steps (described in the
referenced
3003
portions
of
Sections 611.352,
611.356,
and
611.357) on orbefore
the indicated
3004
dates.
3005
3006
1)
Step 1: The
supplier must have conducted
initial
monitoring (Sections
3007
611.356(d)(1)
and
611.357(b))
during two
consecutive six-month
3008
monitoring
periods
on or
before January 1, 1993.
3009
3010
2)
Step 2:
The
supplier must
have
completed corrosion
control studies
3011
(Section 611.352(c))
on or before
July
1,
1994.
3012
3013
3)
Step
3: The Agency
must have
approved
optimal corrosion
control
3014
treatment (Section
611.352(d)) by
a SEP
issued
pursuant to Section
3015
611.110
on or before
January
1,
1995.
3016
3017
4)
Step
4: The
supplier
must have installed
optimal corrosion
control
3018
treatment
(Section
611.352(e))
by
January 1, 1997.
3019
3020
5)
Step 5: The supplier
must have completed
follow-up sampling
(Sections
3021
611.356(d)(2)and6ll.357(c))byJanuaryl,
1998.
3022
3023
6)
Step 6: The Agency
must have
reviewed installation
of treatment
and
3024
approve
optimal
water
quality
control parameters
(Section
611.352(f))
by
3025
July 1, 1998.
3026
3027
7)
Step 7:
The supplier must
operate in compliance
with
the Agency-
3028
specified optimal
water
quality
control parameters
(Section
611.352(g))
3029
and
continue
to conduct tap sampling
(Sections
611 .356(d)(3) and
3030
611.357(d)).
3031
3032
e)
Treatment
steps and
deadlines for small-
and medium-sized
system suppliers.
3033
Except
as provided in subsection
(b)
of this Section, small-
and
medium-sized
3034
system
suppliers
must
complete the following
corrosion
control treatment steps
3035
(described
in the referenced
portions
of Sections 611.352, 611.356,
and
611.357)
3036
by the
indicated
time
periods.
3037
3038
1)
Step
1: The
supplier
must
conduct initial tap sampling
(Sections
3039
611.356(d)(1)
and 611.357(b))
until the supplier
either exceeds the
lead
3040
action level
or the copper
action
level
or
it becomes eligible
for reduced
3041
monitoring
under
Section
61 1.356(d)(4).
A supplier
exceeding
the lead
3042
action
level or the
copper action level
must recommend optimal
corrosion
3043
control
treatment (Section
611.352(a))
within six months
after the end
of
JCAR35O61 1-0814065r01
3044
the monitoring
period
during which it exceeds
one of the
action levels.
3045
3046
2)
Step 2:
Within 12
months
after
the
end of the monitoring
period
during
3047
which
a supplier exceeds
the
lead action
level
or
the
copper action level,
3048
the Agency
may
require
the supplier
to perform corrosion
control studies
3049
(Section
611.352(b)).
If the
Agency
does not require
the supplier to
3050
perform
such
studies, the Agency
must,
by a SEP
issued pursuant to
3051
Section
611.110,
specify
optimal
corrosion
control
treatment (Section
3052
6 11.352(d)) within
the appropriate
of the following
timeframes:
3053
3054
A)
Forfer medium-sized
systems,
within 18
months after the end
of
3055
the
monitoring
period
during which such supplier
exceeds
the lead
3056
action level or
the copper action
leve1
3057
3058
B)
Forfef
small systems,
within
24 months after the
end of the
3059
monitoring period
during which
such supplier
exceeds the lead
3060
action
level
or
the copper action
level.
3061
3062
3)
Step 3:
If the
Agency
requires
a
supplier
to perform corrosion
control
3063
studies
under step 2
(subsection (e)(2)
of this
Section),
the supplier must
3064
complete
the studies
(Section
611.352(c))
within 18 months
after the
3065
Agency
requires
that such studies
be conducted.
3066
3067
4)
Step
4:
If the supplier
has
performed
corrosion
control
studies under
step
3068
2 (subsection
(e)(2) of this Section),
the
Agency
must,
by
a SEP issued
3069
pursuant
to Section
611.110, approve
optimal
corrosion
control treatment
3070
(Section
611.352(d))
within
six months after completion
of step
3
3071
(subsection
(e)(3)
of this Section).
3072
3073
5)
Step
5: The supplier
must
install
optimal corrosion
control treatment
3074
(Section 611.352(e))
within 24 months
after
the
Agency approves such
3075
treatment.
3076
3077
6)
Step
6: The
supplier
must complete
follow-up sampling
(Sections
3078
611.35
6(d)(2) and 611.357(c))
within
36 months
after the Agency
3079
approves
optimal
corrosion
control
treatment.
3080
3081
7)
Step
7: The Agency
must
review
the supplier’s installation
of treatment
3082
and,
by a SEP
issued pursuant
to Section 611.110,
approve
optimal
water
3083
quality control
parameters (Section
611.352(f))
within six months
after
3084
completion of
step
6 (subsection
(e)(6)
of this Section).
3085
3086
8)
Step 8:
The supplier must
operate in compliance
with
the Agency-
JCAR35O61
1-0814065r01
3087
approved
optimal
water
quality
control
parameters
(Section
6
11.352(g))
3088
and
continue
to conduct
tap
sampling
(Sections
611
.356(d)(3)
and
3089
611.357(d)).
3090
3091
BOARD
NOTE:
Derived
from
40
CFR
141.81
(2007),
as
amended
at 72
Fed.
Reg.
3092
57782
(October
10, 2007)(2003).
3093
3094
(Source:
Amended
at 32
Ill.
Reg.
effective
3095
3096
Section
611.353
Source
Water
Treatment
3097
3098
Suppliers
must
complete
the applicable
source
water
monitoring
and
treatment
requirements
3099
(described
in
the
referenced
portions
of
subsection
(b) of this
Section,
and
in Sections
611.356
3100
and
611.358)
by
the
following
deadlines.
3101
3102
a)
Deadlines
for
completing
source
water
treatment
steps.
3103
3104
1)
Step
1:
A
supplier
exceeding
the lead
action
level or
the copper
action
3105
level
must
complete
lead
and
copper
and
source
water
monitoring
(Section
3106
611.358(b))
and
make
a treatment
recommendation
to the Agency
3107
(subsection
(b)(1)
of
this
Section)
within
180
dayssix
months
after the
end
3108
of
the monitoring
period
during
which
the
supplier
exceeded
exceeding
3109
the
pertinent
action
level.
3110
3111
2)
Step 2:
The
Agency
must,
by
a SEP
issued
pursuant
to
Section
6
11.110,
3112
make
a determination
regarding
source
water
treatment
(subsection
(b)(2)
3113
of this
Section)
within
six
months
after
submission
of
monitoring
results
3114
understepl.
3115
3116
3)
Step
3: If
the Agency
requires
installation
of
source
water
treatment,
the
3117
supplier
must
install
that treatment
(subsection
(b)(3)
of this
Section)
3118
within
24
months
after
completion
of step
2.
3119
3120
4)
Step
4:
The
supplier
must
complete
follow-up
tap
water
monitoring
3121
(Section
61 1.356(d)(2))
and
source
water monitoring
(Section
611.358(c))
3122
within
36
months
after
completion
of step
2.
3123
3124
5)
Step
5: The
Agency
must,
by
a SEP
issued
pursuant
to
Section
611.110,
3125
review
the
supplier’s
installation
and operation
of source
water
treatment
3126
and
specify
MPCs
for lead
and copper
(subsection
(b)(4)
of
this
Section)
3127
within
six
months
after completion
of
step 4.
3128
3129
6)
Step
6:
The supplier
must
operate
in
compliance
with
the Agency-
JCAR35O61
1-0814065r01
3130
specified
lead
and
copper
MPCs
(subsection
(b)(4)
of this Section)
and
3131
continue
source
water
monitoring
(Section
611.358(d)).
3132
3133
b)
Description
of Source
Water Treatment
Requirements.
3134
3135
1)
System
treatment
recommendation.
Any
supplier
that exceeds
the
lead
3136
action level
or the
copper
action
level must
recommend
in writing
to the
3137
Agency
the
installation
and
operation
of one
of the
source
water
3138
treatments
listed
in
subsection
(b)(2)
of
this Section.
A
supplier may
3139
recommend
that no
treatment be
installed
based
on
a demonstration
that
3140
source
water
treatment
is
not necessary
to minimize
lead
and copper
levels
3141
at
users’
taps.
3142
3143
2)
Agency
determination
regarding
source
water
treatment.
3144
3145
A)
The Agency
must
complete
an evaluation
of the
results
of
all
3146
source water
samples
submitted
by the
supplier
to determine
3147
whether
source water
treatment
is necessary
to
minimize
lead
or
3148
copper levels
in
water
delivered
to users’
taps.
3149
3150
B)
If the
Agency
determines
that treatment
is
needed, the
Agency
3151
must,
by a SEP
issued
pursuant
to
Section
611.110,
either require
3152
installation
and
operation
of the source
water treatment
3153
recommended
by
the supplier
(if any)
or
require the
installation
3154
and
operation
of
another
source water
treatment
from among
the
3155
following:
3156
3157
i)
ion exchange;
3158
3159
ii)
reverse
osmosis;
3160
3161
iii)
lime
softening;
or
3162
3163
iv)
coagulationlfiltration.
3164
3165
C)
The
Agency
may
request
and the
supplier
must submit
such
3166
additional
information,
on
or
before
a certain date,
as the Agency
3167
determines
is
necessary
to aid in its
review.
3168
3169
D)
The Agency
must notify
the
supplier
in
writing
of its determination
3170
and
set
forth the
basis
for its decision.
3171
3172
3)
Installation
of
source water
treatment.
Each
supplier
must properly
install
JCAR35O61
1-0814065r01
3173
and operate
the
source
water treatment
approved
by
the Agency
under
3174
subsection
(b)(2) of
this Section.
3175
3176
4)
Agency review
of source
water
treatment
and specification
of maximum
3177
permissible
source
water levels
(MPCs).
3178
3179
A)
The
Agency
must
review
the
source
water
samples
taken by
the
3180
supplier
both before
and after
the supplier
installs
source water
3181
treatment,
and
determine
whether
the
supplier
has
properly
3182
installed
and operated
the approved
source
water treatment.
3183
3184
B)
Based on
its review,
the Agency
must,
by a
SEP issued
pursuant
to
3185
Section
611.110,
approve
the
lead and
copper
MPCs
for finished
3186
water
entering
the
supplier’s
distribution
system. Such
levels must
3187
reflect
the
contaminant
removal
capability
of the treatment
3188
properly
operated
and maintained.
3189
3190
C)
The
Agency
must
explain
the
basis
for its
decision
under
3191
subsection
(b)(4)(B)
of this Section.
3192
3193
5)
Continued
operation
and maintenance.
Each
supplier
must maintain
lead
3194
and copper
levels
below
the
MPCs approved
by the
Agency
at each
3195
sampling
point monitored
in
accordance
with
Section 611.358.
The
3196
supplier
is out of
compliance
with
this subsection
if
the level
of lead
or
3197
copper
at
any
sampling point
is greater
than
the MPC
approved
by the
3198
Agency
pursuant
to
subsection
(b)(4)(B)
of
this Section.
3199
3200
6)
Modification
of Agency
treatment
decisions.
3201
3202
A)
On its own
initiative,
or in
response
to a
request
by
a
supplier,
the
3203
Agency
may, by
a
SEP
issued
pursuant
to
Section
611.110, modify
3204
its determination
of
the source
water
treatment
under
subsection
3205
(b)(2) of this
Section,
or
the
lead and copper
MPCs
under
3206
subsection
(b)(4) of
this Section.
3207
3208
B)
A request
for modification
by
a
supplier
must be in
writing,
3209
explain why
the
modification
is appropriate,
and provide
3210
supporting
documentation.
3211
3212
C)
The
Agency
may,
by a SEP
issued
pursuant
to
Section 611.110,
3213
modify
its determination
where it
concludes that
such
change
is
3214
necessary
to
ensure
that
the supplier
continues
to
minimize
lead
3215
and
copper concentrations
in
source
water.
JCAR35O61
1-0814065r01
3216
3217
D)
A revised
determination
made
pursuant
to
subsection
(b)(6)(C)
of
3218
this Section
must
set forth the
new treatment
requirements,
explain
3219
the
basis
for
the
Agency’s
decision, and
provide
an implementation
3220
schedule
for completing
the
treatment
modifications.
3221
3222
E)
Any
interested
person
may
submit
information
to the Agency,
in
3223
writing,
that
bears
on whether
the
Agency
should, within
its
3224
discretion,
issue
a SEP
to modify its
determination
pursuant
to
3225
subsection
(h)(1)
of this
Section.
An Agency
determination
not to
3226
act
on a
submission
of
such information
by
an
interested
person
is
3227
not
an Agency
determination
for
the
purposes of
Sections
39 and
3228
40 of
the
Act
[415
ILCS
5/39 and
40].
3229
3230
7)
Treatment
decisions
by
USEPA. Pursuant
to the
procedures
in 40
CFR
3231
142.19,
the USEPA
Regional
Administrator
reserves the
prerogative
to
3232
review
treatment
determinations
made
by the
Agency under
subsections
3233
(b)(2),
(b)(4), or
(b)(6)
of
this
Section
and issue
federal treatment
3234
determinations
consistent
with
the
requirements
of
40 CFR
141.83(b)(2),
3235
(b)(4),
and
(b)(6),
where
the
Administrator
finds
that
the
following
is true:
3236
3237
A)
the
Agency has
failed
to issue
a treatment
determination
by
the
3238
applicable
deadline
contained
in subsection
(a)
of this Section;
3239
3240
B)
the
Agency has
abused
its discretion
in
a
substantial
number
of
3241
cases
or in
cases
affecting
a substantial
population;
or
3242
3243
C)
the
technical
aspects
of the Agency’s
determination
would
be
3244
indefensible
in an
expected
federal
enforcement
action taken
3245
against
a supplier.
3246
3247
BOARD
NOTE:
Derived
from 40
CFR
141.83
(2007),
as
amended at
72 Fed. Reg.
3248
57782
(October 10,
2007)(2002).
3249
3250
(Source:
Amended
at 32 Ill.
Reg.
effective
3251
3252
Section
611.354
Lead
Service
Line Replacement
3253
3254
a)
Suppliers
required
to replace
lead
service
lines.
3255
3256
1)
If the results
from
tap samples
taken
pursuant
to
Section 61
1.356(d)(2)
3257
exceed
the lead
action
level
after the
supplier
has installed
corrosion
3258
control
or source
water treatment
(whichever
sampling
occurs
later),
the
JCAR35O61
1-0814065r01
3259
supplier
must
recommence
replacing
lead service
lines
in accordance
with
3260
the
requirements
of subsection
(b)
of
this
Section.
3261
3262
2)
If
a supplier
is in
violation
of
Section
611.35
1 or Section
611.353
for
3263
failure to install
source
water or
corrosion
control
treatment,
the Agency
3264
may,
by
a SEP issued
pursuant
to Section
611.110,
require
the supplier
to
3265
commence
lead service
line
replacement
under
this
Section after
the date
3266
by which
the
supplier
was required
to
conduct
monitoring
under
Section
3267
611.356(d)(2)
has
passed.
3268
3269
b)
Annual
replacement
of lead
service
lines.
3270
3271
1)
Initiation
of a lead
service
line
replacement
program.
3272
3273
A4-)
A supplier
that
is required
to
commence
lead service
line
3274
replacement
pursuant
to
subsection
(a) of
this
Section must
3275
annually
replace
at least seven
percent
of
the initial
number
of lead
3276
service
lines
in its
distribution
system.
3277
3278
B2)
The
initial
number
of
lead
service
lines is
the
number of
lead lines
3279
in place
at
the
time
the replacement
program
begins.
3280
3281
C)
The supplier
must
identify
the initial
number
of lead service
lines
3282
in
its distribution
system,
including
an
identification
of the
portions
3283
of the system
owned
by the supplier,
based
on a materials
3284
evaluation,
including
the evaluation
required
under
Section
3285
611.356(a)
and
relevant
legal
authorities
(e.g.,
contracts,
local
3286
ordinances)
regarding
the portion
owned
by
the
system.
3287
3288
D4)
The first
year of
lead
service
line
replacement
must begin
on the
3289
first
day following
the
end of the
monitoring
period in
which 4ate
3290
the
supplier
exceeded
the
action
level
pursuant
to in tap
sampling
3291
referenced
in
subsection
(a) of this
Section.
3292
3293
If monitoring
is
required
annually
or less
frequently,
the
end
of the
3294
monitoring
period
is September
30 of the
calendar
year
in which
3295
the sampling
occurs.
3296
3297
D
If the Agency
has
established
an alternate
monitoring
period
by a
3298
SEP issued
pursuant
to Section
611.110,
then
the end
of the
3299
monitoring
period
will be the
last day
of that period.
3300
3301
Resumption
of
a lead service
line
replacement
program after
cessation.
JCAR35O61 l-0814065r01
3302
3303
A supplier
that is resuming a program
after cessation of its lead
3304
service line replacement
program, as allowed pursuant
to
3305
subsection
(f)
of this Section,
must update its inventory of lead
3306
service
lines to include those
sites that it had
previously
3307
determined
did not require replacement
pursuant to the sampling
3308
provision of
subsection (c) of this Section.
3309
3310
)
The supplier
will then divide the updated number
of remaining
3311
lead service lines
by
the
number of remaining years in the program
3312
to determine
the number of lines that must be replaced per year
3313
(seven
percent lead service line replacement
is based on a 15-year
3314
replacement program,
so that, for example, a supplier resuming
3315
lead service
line replacement after previously conducting two
years
3316
of replacement would divide the updated
inventory
by
13).
3317
3318
For
a supplier that has completed a 15-year lead
service
line
3319
replacement program,
the Agency must, by a SEP issued pursuant
3320
to
Section 611.110, determine a schedule for replacing
or
retesting
3321
lines that were previously
tested out under the completed
3322
replacement program, whenever
the supplier has re-exceeded the
3323
action level.
3324
3325
c)
Service lines not needing replacement.
A supplier is not required to replace any
3326
individual
lead service line for which the lead concentrations
in all service line
3327
samples taken from that line pursuant
to Section 611 .356(b)(3) are less than
or
3328
equal
to 0.015 mg!R.
3329
3330
d)
A water
supplier must replace
that portion
of
the lead
service line that it owns. In
3331
cases where the supplier does not
own
the entire lead service line, the supplier
3332
must notify the
owner
of the line, or the owner’s authorized agent, that the
3333
supplier will replace the portion of the service line
that it owns and must offer to
3334
replace the owner’s portion
of the line. A supplier is not required to bear the
cost
3335
of
replacing
the privately-owned portion of the line, nor
is it required to replace
3336
the privately-owned portion where
the owner chooses not to pay the cost of
3337
replacing
the privately-owned portion of the
line, or where replacing the
3338
privately-owned
portion
would
be precluded
by
State, local, or common law.
A
3339
water supplier that does not replace
the entire length of the service line also must
3340
complete
the following tasks:
3341
3342
1)
Notice
Prior to Commencement of Work.
3343
3344
A)
At least 45 days prior
to commencing the partial replacement of a
JCAR35O61
1-0814065r01
3345
lead
service
line,
the
water
supplier
must
provide
notice
to the
3346
residents
of all
buildings
served
by
the
line explaining
that
they
3347
may
experience
a temporary
increase
of lead
levels
in
their
3348
drinking
water,
along
with
guidance
on
measures
consumers
can
3349
take to
minimize
their
exposure
to
lead.
3350
3351
B)
The
Agency,
by issuing
an
appropriate
SEP,
may
allow
the
water
3352
supplier
to provide
notice
under
the
previous
sentence
less
than
45
3353
days
prior
to
commencing
partial
lead service
line
replacement
3354
where
it determines
that such
replacement
is in conjunction
with
3355
emergency
repairs.
3356
3357
C)
In
addition,
the
water
supplier
must
inform
the
residents
served
by
3358
the
line
that
the
supplier
will,
at the
supplier’s
expense,
collect
a
3359
sample
from
each partially-replaced
lead service
line
that
is
3360
representative
of the
water
in
the
service
line
for
analysis
of
lead
3361
content,
as prescribed
by Section
61
1.356(b)(3),
within
72
hours
3362
after
the
completion
of
the partial
replacement
of
the
service
line.
3363
The supplier
must
collect
the
sample
and report
the
results
of the
3364
analysis
to the
owner
and
the
residents
served
by
the line
within
3365
three business
days
of
receiving
the
results.
3366
3367
D)
Mailed
notices
post-marked
within
three
business
days
of
receiving
3368
the results
must
be
considered
“on
time.”
3369
3370
2)
The
water
supplier
must
provide
the
information
required
by
subsection
3371
(d)(1)
of this
Section
to the
residents
of
individual
dwellings
by
mail
or
by
3372
other
methods
approved
by
the Agency
by a SEP
issued
pursuant
to
3373
Section
611.110.
In instances
where
multi-family
dwellings
are
served
by
3374
the
service
line,
the
water supplier
must
have
the
option
to post
the
3375
information
at
a
conspicuous
location.
3376
3377
e)
Agency
determination
of
shorter
replacement
schedule.
3378
3379
1)
The
Agency
must,
by a SEP
issued
pursuant
to
Section
611.110,
require
a
3380
supplier
to
replace
lead
service
lines
on a
shorter
schedule
than
that
3381
otherwise
required
by this
Section
if it determines,
taking
into
account
the
3382
number
of
lead
service
lines
in
the
system,
that
such
a shorter
replacement
3383
schedule
is
feasible.
3384
3385
2)
The
Agency
must
notify
the supplier
of its finding
pursuant
to subsection
3386
(e)(1)
of this
Section
within
six
months
after
the
supplier
is
triggered
into
3387
lead
service
line
replacement
based
on monitoring,
as referenced
in
JCAR35O61
1-0814065r01
3388
subsection
(a)
of this Section.
3389
3390
f)
Cessation
of service
line replacement.
3391
3392
1)
Any supplier
may cease replacing
lead
service lines whenever
it fulfills
3393
both of
the following
conditions:
3394
3395
A)
First draw tap
samples
collected
pursuant to Section
611.356(b)
(2)
3396
meet the lead
action level during
each
of two
consecutive six-
3397
month monitoring
periods;
and
3398
3399
B)
The
supplier has
submitted those
results to the Agency.
3400
3401
2)
If any of
the supplier’s
first draw tap samples
thereafter
exceed the lead
3402
action level,
the
supplier
must recommence
replacing
lead service
lines
3403
pursuant
to subsection
(b)) of this Section.
3404
3405
g)
To
demonstrate
compliance with subsections
(a) through
(d) of this Section,
a
3406
supplier must report
to
the Agency
the information
specified in Section
3407
611.360(e).
3408
3409
BOARD
NOTE: Derived
from 40
CFR
141.84
(2007),
as
amended
at
72 Fed. Reg.
3410
57782
(October 10, 2007)(2003).
3411
3412
(Source: Amended
at 32 Iii.
Reg.
effective
3413
3414
Section 611.355
Public Education
and Supplemental
Monitoring
3415
3416
A supplier
that exceeds the
lead
action
level based on tap water
samples collected
in accordance
3417
with Section
611.356 must
deliver the public
education
materials
required
by
3418
subsectioncubsections
(a)
and (b) of this
Section
in accordance
with
the requirements
of
3419
subsection
of this Section.
A
supplier
that exceeds the
lead action level
must sample
the
3420
tap water of any
customer
who requests it in accordance
with
subsection
(c)
of this Section. A
3421
supplier
must
deliver
a consumer
notice
of
lead tap water monitoring
results
to
persons who are
3422
served
by
the
supplier at
each
site that the supplier
has tested,
as
specified
in
subsection
(d)
of
3423
this Section.
3424
3425
a)
Content
of
written
public education
materials.
3426
3427
1)
Community water
systems and non-transient
non-community
water
3428
systems. A
CWS
or
NTNCWS
supplier
must
include the following
3429
elements
in printed
materials
(e.g., brochures
and pamphlets)
in the same
3430
order
as
listed
in subsections
(a)(1)(A)
through
(a(1)(F).
In
addition,
the
f).
I.).
)
)
c
I
+
)
I
)
H
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CD
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H
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C
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+
C
(
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C
C
+
+
1.
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C
C
C,
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Cl)
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CD
Cl)
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CD
C,)
CD
C)
C)
I
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CD
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C)
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CD
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C)
0
Cd)
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Cd)
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00
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-t
C
F.
JCAR35O61
1-0814065r01
3473
)
Health
effects
of lead.
Lead
can cause
serious
health
problems
if
3474
too
much enters
your
body from
drinking
water or other
sources.
3475
It can cause
damage
to
the brain
and
kidneys,
and
can interfere
3476
with
the
production
of red
blood cells
that
carry oxygen
to
all parts
3477
of your
body. The
greatest
risk of lead
exposure
is
to infants,
3478
young children,
and
pregnant
women.
Scientists
have linked
the
3479
effects
of lead
on
the brain
with
lowered
10
in
children.
Adults
3480
with
kidney
problems
and
high blood
pressure
can
be
affected
by
3481
low levels
of
lead
more
than healthy
adults.
Lead is stored
in
the
3482
bones,
and it can
be released
later
in life.
During
pregnancy,
the
3483
child
receives lead
from
the
mother’s
bones, which
may
affect
3484
brain
development.
3485
3486
BOARD
NOTE:
The
supplier
must
use the verbatim
text
set
forth
3487
in
this
subsection
(a)(1)(B).
3488
3489
c)
Sources
of Lead.
3490
3491
Explain
what
lead is.
3492
3493
jf
Explain possible
sources
of lead
in
drinking
water
and how
3494
lead enters
drinking
water.
Include
information
on
home
3495
and building
plumbing
materials
and
service lines
that
may
3496
contain
lead.
3497
3498
jjj
Discuss
other important
sources of
lead
exposure
in
3499
addition
to drinking
water
(e.g.,
paint).
3500
3501
BOARD
NOTE:
The supplier
must
use
text
that provides
the
3502
information
described
in
this
subsection
(a)(l)(C).
3503
3504
Discuss
the steps
the
consumer
can
take to
reduce
his
or
her
3505
exposure
to
lead
in drinking
water.
3506
3507
Encourage
running
the
water
to flush
out
the lead.
3508
3509
ii)
Explain
concerns
with using
hot water
from the
tap
and
3510
specifically
caution
against
the use
of hot
water
for
3511
preparing
baby
formula.
3512
3513
ilil
Explain
that
boiling water
does not
reduce
lead
levels.
3514
JCAR35O61
1-0814065r01
3515
jy)
Discuss
other options
consumers
can
take
to reduce
3516
exposure
to lead in
drinking
water,
such as
alternative
3517
sources
or
treatment
of water.
3518
3519
y)
Suggest
that
parents
have
their child’s
blood tested
for lead.
3520
3521
BOARD
NOTE:
The
supplier
must
use
text
that provides
the
3522
information
described in
this subsection
(a)(1)(D).
3523
3524
j)
Explain
why
there
are elevated
levels
of
lead in the
supplier’s
3525
drinking water
(if
known)
and
what the
supplier
is doing
to reduce
3526
the
lead
levels in
homes
and buildings
in
this
area.
3527
3528
BOARD
NOTE:
The supplier
must
use
text
that
provides
the
3529
information
described
in this
subsection
(a)(1)(E).
3530
3531
)
For
more
information,
call
us at [INSERT
THE
SUPPLIER’S
3532
NUMBER1
[(LF
APPLICABLE),
or
visit our
Web
site at
[INSERT
3533
THE
SUPPLIER’S
WEB
SITE
HERE11.
For more
information
on
3534
reducing
lead
exposure
around your
home/building
and
the health
3535
effects
of
lead.
visit
USEPA’s
Web
site at
http://www.epa.gov/lead
3536
or
contact
your
health care
provider.
3537
3538
BOARD
NOTE:
The
supplier
must use
the
verbatim
text
set forth
3539
in this
subsection
(a)(1)(F),
with the
exception
that the
supplier
3540
must insert
its name
in place of
the first segment
of
bracketed text,
3541
and it
must add
the second
segment
of
bracketed
text
and
substitute
3542
its Web
address for
the internal
bracketed
text.
3543
3544
2)
Community
Non
transient
non
community
water
systems.
In addition
to
3545
including
the elements
A
NTNCWS
must
either
include
the text
specified
3546
in subsection
(a)(1)
of
this Section1
or
must include
the
text
set
forth
in
3547
Appendix
F of this
Part in all
of the printed
materials
it distributes
though
3548
its lead public
education
program.
A
water
supplier
may delete
3549
information
pertaining
to
lead
service lines
upon approval
by
the Agency
3550
by a
SEP
issued
pursuant
to Section
611.110
if no
lead
service lines
exist
3551
anywhere
in the water
system
service area.
Aiy
additional
information
3552
presented
by
a supplier
must
be consistent
with
the information
below
and
3553
be in plain
English
that
can be
understood
by
lay
persons.
a CWS supplier
3554
must
do both of
the following:
3555
3556
)
It must
tell consumers
how
to get their
water tested
and
3557
JCAR35O61
1-0814065r01
3558
)
It must discuss
lead
in
plumbing components
and the difference
3559
between
low-lead
and
lead-free components.
3560
3561
)
Agency review
and approval
of written public education
materials.
3562
3563
The
supplier must
submit
all written
public education
materials
to
3564
the
Agency
for
review
at least
60
days
prior
to its
planned date for
3565
delivery
of the materials
to the
public.
3566
3567
If the Agency determines
that the
form and content
of
the
3568
supplier’s
written
public education materials
is adequate,
it may
3569
issue
a SEP pursuant
to Section
611.110
that expressly
approves
of
3570
the
materials.
3571
3572
)
A
supplier may immediately
distribute
its written public education
3573
materials
afier
receipt
of a SEP or a revised
SEP that expressly
3574
approves
those materials.
3575
3576
If
the Agency determines
that the form
or content of the written
3577
public
education
materials
submitted by
the supplier does
not
3578
comply
with the requirements
of this
Section, it must issue
a
SEP
3579
pursuant to Section
611.110.
The
Agency may issue
a revised
SEP
3580
that
expressly
supercedes
a SEP previously
issued
under this
3581
subsection
(a)(1).
Any SEP or
revised SEP issued
by
the Agency
3582
must identify
any deficiencies
in the written public
education
3583
materials
with specificity sufficient
to guide the
supplier to correct
3584
the
deficiencies
in
a way that
would
address the
Agency’s
3585
concerns.
3586
3587
The Agency
must
issue any SEP
or
revised SEP under
subsection
3588
(a)(3)(D)
of this
Section no later than
30 days after
the date on
3589
which it received
a copy of the
supplier’s prospective
written
3590
public
education
materials,
unless the
Agency and
the supplier
3591
have agreed to a later
date pursuant
to subsection
(a)(3’)(F)
of
this
3592
Section.
The
Agency and the supplier
may agree
to a longer time
3593
within which the Agency
may
issue a SEP or a revised
SEP. in
3594
which
case the
Agency must issue the
SEP or revised
SEP before
3595
expiration
of the agreed longer
time.
3596
3597
BOARD
NOTE: The Board
has
provided
that
the Agency and
the
3598
supplier
may agree to a longer
time before
the Agency issues
a
3599
SEP
and for the Agency
to issue a revised SEP
that supercedes
an
3600
3601
3602
3603
3604
3605
3606
3607
3608
3609
3610
3611
3612
3613
3614
3615
3616
3617
3618
3619
3620
3621
3622
3623
3624
3625
3626
3627
3628
3629
3630
3631
3632
3633
3634
3635
3636
3637
3638
3639
3640
3641
3642
2
mohave
public health
supplier).
JCAR35O61
1-0814065r01
already-issued
SEP,
in
order
to allow
for negotiation
of any
issues
and
the
quickest
possible
distribution
of the
materials.
If the
supplier
has
not received
a SEP
from the
Agency
within
45
days
after the date
on which
the
Agency
received
its
written
public
education
materials,
those
materials
are
deemed
approved,
and
the
supplier
may
immediately
proceed
to distribute
them.
Once
the supplier
has
revised its
written public
education
materials
exactly
as described
by
the
Agency
in a SEP
issued
under
subsection
(a)(3)(D)
of this Section,
those
materials
are
deemed
approved,
and
the
supplier
may
immediately
proceed
to distribute
them.
BOARD
NOTE:
At corresponding
40
CFR
141.85(a)(1)
(2007), USEPA
allowed
the State
to require
prior
approval
of written
public information
materials.
Rather than
require prior
Agency
approval,
the Board has
chosen
to require
submission
to
the Agency
for
review
sufficiently
in
advance
of
distribution
to allow the
Agency
to raise any
deficiencies
that
it
may
perceive.
The
Board
has used
the mechanism
of
the SEP for
the
Agency
to communicate
its concerns,
as
this
would allow
the
supplier to
petition
the
Board for
review of
the Agency’s
determination
pursuant
to
Section
611.110(c).
b}
Content
of broadcast
materials.
A supplier
must
include
the
following
information
in all
public service
announcements
submitted
under its
lead public
education
program
to television
and
radio stations
for
broadcast:
Why
should
everyone
want to
know the
facts
about
lead and drinking
water?
Because
unhealthy
amounts
of
lead can enter
drinking
water
through
the plumbing
in your
home. That’s
why
I
urge you to
do what
I
did.
I had
my water
tested for
(insert
“free” or the
cost
per
sample). You
can
contact
the (insert
the name
of the city
or supplier)
for information
on
testing
and
on simple
ways to reduce
your
exposure
to
lead in drinking
water.
“ater
tested for
lead, or to
get
more
information
about this
concern,
please call
(insert
the phone
number
of the city
or
be)
Delivery
of a-public
education
materialsprogram.
1)
The
public education
materials
of a supplier
that serves
In communities
JCAR35O61
1-0814065r01
3643
where
a largesiguificant proportion
of the population
specs
a
language
3644
other
than non-English
speaking consumers, public education materials
3645
must contain information
be communicated in the appropriate languages
3646
regarding the importance of the
notice, or it must contain a
telephone
3647
number
or address where a person served may contact the supplier to
3648
obtain a translated
copy of the public education materials or to request
3649
assistance in the appropriate
language.
3650
3651
2)
A
CWS
supplier that
exceeds the lead action level on the basis of tap
3652
water samples collected in accordance with Section 611.356 and which
is
3653
not already conducting
repeating public education tasks pursuant to
3654
subsection
(c)(3), (c)(7), or (c)(8) of this Section must, within 60 days
3655
afier the end of the monitoring
period in
which the exceedance occurred,
3656
do each of the following
complete
the public education tasks
according
to
3657
the following
requirements:
3658
3659
The
CWS supplier must deliver printed materials that meet the
3660
content requirements
of
subsection
(a)
of this Section to all of its
3661
bill-paying
customers.
3662
3663
Methods of delivery for a
CWS
supplier.
3664
3665
The
CWS supplier must contact customers who
are most
at
3666
risk by delivering education materials that meet the content
3667
requirements of subsection (a) of this Section to local
3668
public health
agencies,
even
if
the agencies are not located
3669
within the supplier’s service area, along with an
3670
informational
notice
that
encourages distribution to all
of
3671
the agencies’ potentially affected customers or the supplier’s
3672
users. The supplier must contact the local public health
3673
agencies directly by phone or in person. The local public
3674
health agencies may
provide
a specific list of additional
3675
community-based
organizations
that
serve the
target
3676
populations, which may include organizations outside the
3677
service area
of the
supplier.
If such
lists are provided,
the
3678
supplier must deliver education materials that meet the
3679
content
requirements of subsection (a) of this Section to
3680
each of the organizations on the provided lists.
3681
3682
jjI
The CWS supplier must contact customers who are most at
3683
risk
by delivering materials that meet the content
3684
requirements
of subsection
(a)
of this Section to the
3685
organizations listed in subsections
(b)(2)(H)(i)
through
JCAR35O61
1-0814065r01
3686
(b)(2)(H)(vi)
that
are
located
within
the
supplier’s
service
3687
area,
along with
an informational
notice
that encourages
3688
distribution
to all the organization’s
potentially
affected
3689
customers
or
supplier’s
users.
3690
3691
BOARD
NOTE:
The
Board found
it necessary
to move
the
3692
text of
40
CFR
141.85(b)(2)(ii)(B)(])
through
3693
(b)(2)(ii)(B)(6)
(2007),
as
added at
72 Fed.
Reg. 57782
3694
(Oct. 10,
2007),
to
appear as
subsection
(b)(2)(H)(i)
3695
through subsection
(b)(2)(H)(vi)
of
this Section,
in order
to
3696
comport
with
Illinois
Administrative
Code
codification
3697
reciuirements
relating
to allowed
indent
levels
in rules.
3698
3699
jji
The CWS
supplier
must
make
a good faith
effort to locate
3700
the
organizations
listed
in subsections
(b)(2)(I)(i)
through
3701
(b)(2)(I)(iii)
of
this
Section that
are
located within
the
3702
service
area
and
deliver
materials
that meet
the content
3703
requirements
of subsection
(a)
of
this
Section
to them,
3704
along
with
an informational
notice
that encourages
3705
distribution
to
all potentially
affected
customers
or users.
3706
The
good
faith
effort
to
contact at-risk
customers
may
3707
include requesting
a
specific contact
list of
these
3708
organizations
from
the local
public
health agencies,
even
if
3709
the agencies
are not
located within
the supplier’s
service
3710
area.
3711
3712
BOARD
NOTE:
The Board
found
it necessary
to
move the
3713
text
of 40
CFR
14L85(’b)(2)(ii)(C)(T
through
3714
(b)(2)(ii)(C)(3)
(2007),
as added
at
72 Fed.
Reg. 57782
3715
(Oct.
10,
2007),
to appear
as
subsection
(b)(2)(I)(i)
through
3716
subsection
(b)(2)(I)(iii)
of this
Section,
in order to
comport
3717
with Illinois
Administrative
Code
codification
requirements
3718
relating
to
allowed
indent
levels
in
rules.
3719
3720
No less
often than
quarterly,
the CWS
supplier
must
provide
3721
information
on or
in each water
bill
as long
as the
system
exceeds
3722
the action
level
for
lead.
The message
on
the water
bill must
3723
include
the following
statement
exactly
as
written,
except
for
the
3724
text
in brackets
for which
the supplier
must include
system
3725
specific
information:
3726
3727
TINSERT
NAME
OF
SUPPLIER]
found
high levels
of
lead
3728
in
drinking water
in some
homes. Lead
can cause
serious
JCAR35O61
1-0814065r01
3729
health problems.
For
more
information
please
call
3730
[INSERT
NAME
OF
SUPPLIER] [or visit
(INSERT
3731
SUPPLIER’S
WEB
SITE
HERE)1.
The
message
or
3732
delivery
mechanism
can
be
modified
in consultation
with
3733
the Illinois
Environmental
Protection
Agency,
Division
of
3734
Public
Water
Supply;
specifically,
the Agency
may
allow
a
3735
separate
mailing
of public
education
materials
to
customers
3736
if the
water
system
cannot
place
the information
on
water
3737
bills.
3738
3739
The
CWS
supplier
must
post material
meeting
the
content
3740
requirements
of
subsection
(a) of
this
Section
on
the
supplier’s
3741
Web
site
if the CWS
supplier
serves
a
population
greater
than
3742
100,000.
3743
3744
j)
The
CWS
supplier
must
submit
a press
release
to
newspaper,
3745
television,
and
radio
stations.
3746
3747
In
addition
to
subsections
(b)(2)(A)
through
(b)(2)(E)
of
this
3748
Section,
the
CWS
supplier
must
implement
at least
three
activities
3749
from
one
or
more
of
the categories
listed
below.
The
educational
3750
content
and
selection
of these
activities
must be
determined
in
3751
consultation
with
the Agency.
3752
3753
Public
Service
Announcements.
3754
3755
j
Paid
advertisements.
3756
3757
liii
Public
Area
Information
Display
3758
3759
jy)
E-mails
to
customers.
3760
3761
y)
Public
Meetings.
3762
3763
yj)
Household
Deliveries.
3764
3765
yjj)
Targeted
Individual
Customer
Contact.
3766
3767
yjjj)
Direct
material
distribution
to
all multi-family
homes
and
3768
institutions.
3769
3770
jç)
Other
methods
approved
by
the
State.
3771
JCAR35O61
1-0814065r01
3772
For
a
CWS
supplier that
is required
to conduct monitoring
3773
annually
or less frequently,
the
end
of the monitoring
period
is
3774
September 30 of the
calendar year in
which
the sampling
occurs,
3775
r,jf
the Agency
has established
an alternate monitoring
period, by
3776
a SEP
issued
pursuant
to Section
611.110, the last
day of that
3777
period.
3778
3779
fl
Organizations
that the
CWS
supplier must contact
when required
3780
to do so pursuant
to subsection
(b)(2)(B)(ii)
of this Section.
3781
3782
j)
Public
and private
schools or school
boards.
3783
3784
iii
Women,
Infants and
Children
(WIC)
and
Head Start
3785
programs.
3786
3787
jjj)
Public and
private
hospitals
and medical clinics.
3788
3789
yji
Pediatricians.
3790
3791
y
Family planning
clinics.
3792
3793
iI
Local welfare
agencies.
3794
3795
BOARD
NOTE: This subsection
(b)(2)(H) coffesponds
with 40
3796
CFR 141 .85(b)(2)(ii)(B)(])
through (b)(2)(ii)(B)(6)
(2007), as
3797
added at
72
Fed. Reg. 57782
(Oct.
10,
2007).
The Board found
it
3798
necessary
to move the text
of those
federal
provisions to comport
3799
with Illinois
Administrative
Code codification
requirements
3800
relating to allowed
indent
levels in rules.
3801
3802
Organizations
that
the
CWS
supplier must contact
when required
3803
to do
so
pursuant
to subsection
(b)(2)(B)(iii)
of this Section.
3804
3805
Licensed
childcare centers.
3806
3807
jj
Public
and private preschools.
3808
3809
iJil
Obstetricians,
gynecologists
and midwives.
3810
3811
BOARD
NOTE:
This
subsection (b)(2)(H)
corresponds
with
40
3812
CFR
141.85(b)(2)(ii)(C)(1)
through (b)(2)(ii)(C)(3)
(2007),
as
3813
added
at 72 Fed. Reg.
57782
(Oct.
10,
2007).
The Board
found it
3814
necessary
to move
the text
of those
federal provisions
to
comport
[P
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3858
3859
3860
3861
3862
3863
3864
3865
3866
3867
3868
3869
3870
3871
3872
3873
3874
3875
3876
3877
3878
3879
3880
3881
3882
3883
3884
3885
3886
3887
3888
3889
3890
3891
3892
3893
3894
3895
3896
3897
3898
3899
3900
JCAR35O61
1-0814065r01
n’tnn
lvl
Such
a
water
.lier
must
also
include
the
“alert”
language
specified
in
this subsection
(c)(2)(A);
B
Submit
the information
required
by
.1
subsection
(a)(fl
I
nfthi
Section
to the
editorial
departments
of
the
m
or daily
and
weekly
newspapers
circulated
tiffoughout
the community;
Deliver
pamphlets
or brochures
that contain
the public
education
materials
in
paragraphs
(2)
and
(4) of
Appendix
E
of
this Part
to
facilities
and
organizations,
including
the
following:
j-
Public
schools
or
local school
boards;
i4
The city
or
county
health
department;
i44
Women,
Infants,
and
Children
(WIC)
and
Head
Start
programs,
whenever
available;
i
Public
and
private
hospitals
and clinics;
Pediatricians;
4)
Family
planning
clinics;
and
44
Local
welfare
agencies;
and
Submit
the
public
seice
announcement
in
subsection
(b)
of
this
Section
to
at least
five
of
the
radio
and
television
stations
with
the
largest
audiences
within
the community
se’ed
by
the
supplier.
A
(‘WTQ
the tasks
contained
in subsections
(c)(2)(A)
though
(c)(2)(D)
of this
Section
for as long
as
the
supplier
exceeds
the
lead
action level,
at
the following
minimum
frequency:
A
Those
of subsections
(c)(2)(A
tou
(c)(2)(C)
of this
Section,
every
12
months;
and
Those
of subsection
(c)(2)(D)
of this
Section,
even’
six
months.
4)
Within
60
days after
the
end of
the monitoring
period
in
which
a
NTNCWS
supplier
it-exceeds
the
lead
action
level
(unless
it
already
is
repeating
public
education
tasks
pursuant
to subsection
(b)(5Xe)(5)
of
this
Section),
ftp NTNCWS
supplier
must
deliver
the
public
education
JCAR35O61
1-0814065r01
3901
materials specified
by
subsection
(a)
of this
Sectioncontained
in Appendix
3902
E
or F
of
this
Part,
as
in
subsections
(b)(4)(A)
and (b)(4)(B)
of this
3903
Section, subject
to the
limitation
set forth in
subsection
(b)(4)(C)
of this
3904
Sectionfollows:
3905
3906
A)
The NTNCWS
supplier
must post
Post
informational
posters
on
3907
lead in drinking
water
in a public
place
or
common
area in
each
of
3908
the buildings
served
by
the
supplier;
and
3909
3910
B)
The NTNCWS
supplier
must
distribute
Distribute
informational
3911
pamphlets
or
brochures
on lead
in drinking
water
to
each person
3912
served by
the NTNCWS
supplier.
The
Agency
may, by
a SEP
3913
granted pursuant
to Section
611.110,
allow the
system to utilize
3914
electronic
transmission
in lieu of or
combined
with
printed
3915
materials
as long
as it achieves
at least
the same
coverage.
3916
3917
)
For
a
NTNCWS
supplier
that
is required
to
conduct
monitoring
3918
annually
or
less
frequently,
the end
of the
monitoring
period
is
3919
September
30 of
the calendar
year in
which
the
sampling
occurs,
3920
or,
if the Agency
has established
an
alternate
monitoring
period,
by
3921
a SEP issued
pursuant
to
Section
611.110,
the last
day of that
3922
period.
3923
3924
5)
A NTNCWS
supplier
must
repeat
the
tasks set
forthcontained
in
3925
subsection
(be)(4)
of this
Section
at least
once during
each calendar
year
3926
in which
the supplier
exceeds
the lead
action level.
The
Agency
must,
on
3927
a case-by-case
basis, by
a
SEP
issued
pursuant
to
Section 611.110,
extend
3928
the time
for the
supplier
to
complete
the public
education
tasks
set forth
in
3929
subsection
(b)(2)
of this
Section
beyond
the
60-day
limit if it
determines
3930
that
the extended
time is needed
for implementation purposes; however,
3931
the
Agency must
issue
the SEP
granting
any
extension
prior
to expiration
3932
of the
60-day deadline.
3933
3934
6)
A supplier
may
discontinue
delivery
of
public
education
materials
after
it
3935
has met
the lead action
level
during the
most
recent
six-month
monitoring
3936
period
conducted
pursuant
to Section
611.356.
Such
a supplier
must begin
3937
public
education
anew in accordance
with
this Section
if it subsequently
3938
exceeds
the
lead
action
level
during any
six-month
monitoring
period.
3939
3940
7)
A CWS supplier
may
apply
to the Agency,
in
writing,
to use
only
the
text
3941
specified
in subsection
(a)(1)
of this
Section
Appendix
F of this
Part in
3942
lieu
of the
text in subsections
(a)(1)
and
(a)(2)
of
this Section
Appendix
E
3943
of this Part
and to perform
the
tasks listed
in
subsections
(b)(4)(c)(4)
and
JCAR35O61
1-0814065r01
3944
(b)(5)(c)(5)
of
this Section
in
lieu
of the
tasks
in
subsections
(b)(2)(c)(2)
3945
and
(b)(3)(c)(3) of this
Section
if the following
are
true:
3946
3947
A)
The
supplier
is a
facility,
such
as
a
prison
or a
hospital,
where
the
3948
population
served
is
not
capable
of
or is
prevented
from
making
3949
improvements
to plumbing
or installing
point
of use
treatment
3950
devices;
and
3951
3952
B)
The
system
provides
water
as part
of
the cost
of
services
provided,
3953
and
it
does
not
separately
charge
for
water
consumption.
3954
3955
)
A
CWS
supplier
that
serves
3,300 or
fewer
people
may
limit
certain
3956
aspects
of
its
public
education
programs
as follows:
3957
3958
)
With
respect
to
the requirements
of
subsection
(b)(2)(F)
of this
3959
Section,
a supplier
that
serves
3,300
or
fewer
people
must
3960
implement
at least
one
of
the
activities
listed in
that subsection.
3961
3962
j
With
respect
to
the
requirements
of
subsection
(b)(2)(B)
of this
3963
Section,
a
supplier
that
serves
3,300
or
fewer
people
may
limit
the
3964
distribution
of
the public
education
materials
required
under that
3965
subsection
to
facilities
and
organizations
that
it serves
which
are
3966
most
likely
to be
visited
regularly
by
pregnant
women
and
3967
children.
3968
3969
)
With
respect
to the
requirements
of
subsection
(b)(2)(E)
of
this
3970
Section,
the
Agency
may,
by a SEP
issued pursuant
to
Section
3971
611.110,
waive
this
requirement
for a
supplier
that
serves
3,300
or
3972
fewer
persons,
as long
as
the
supplier
distributes
notices
to
every
3973
household
that
it
serves.
3974
3975
Reduced
requirements
for certain
smaller
CWS
suppliers.
3976
3977
A)
A
CWS
supplier
serving
3,300
or fewer
people
may
omit the
task
3978
contained
in subsection
(c)(2)(D)
of
this Section.
As
long
as
it
3979
distributes
notices
containing
the
infoation
contained
in
3980
Appendix
E
of this
Part
to even’
household
served
by
the
system,
3981
such
a
supplier
may
ffirther
limit its
public
education
programs
as
3982
follows:
3983
3984
i)
A
supplier
serving
500
or
fewer
people
may
forego
the
task
3985
contained
in
subsection
(c)(2)(B)
of this
Section.
Such
a
3986
system
may
limit
the distribution
of the
public
education
JCAR35O61
1-0814065r01
3987
materials
required
under
subsection
(c)(2)(C)
of this
3988
Section to
facilities
and organizations
served
by
the
3989
supplier
that
are
most
lilcely to
be
visited regularly
by
3990
pregnant
women
and
children,
unless
it is
notified by
the
3991
Agency
in ting
that it must
make a broader
distribution.
3992
3993
i-i
If
approved
by
the
Agency
by a SEP
issued
pursuant
to
3994
Section
611.110,
a system
serving 501
to 3,300 people
may
3995
omit
the task
in
subsection
(c)(2)(B)
of
this Section
or
limit
3996
the
distribution
of the public
education
materials
required
3997
under
subsection
(c)(2)(C)
of this Section
to
facilities
and
3998
organizations
served
by the
system
that
are most
lilcely to
3999
be
visited
regularly
by pregnant
women
and children.
4000
4001
B
A
CWS
supplier
serving
3,300 or fewer
people
that delivers
public
4002
education
in
accordance
with
subsection
(c)(8)(A)
of this Section
4003
must
repeat the
required public
education
tasks at least
once during
4004
each calendar
year
in which
the supplier
exceeds
the lead action
4005
level.
4006
4007
cd)
Supplemental
monitoring
and
notification
of results.
A supplier
that fails
to meet
4008
the lead
action level
on the
basis of tap
samples collected
in
accordance
with
4009
Section
611.356
must offer
to
sample
the
tap
water
of any
customer
who
requests
4010
it.
The
supplier
is not
required
to pay
for collecting
or analyzing
the sample,
nor
4011
is the
supplier
required to
collect and
analyze the
sample
itself.
4012
4013
cD
Requirement
for
consumer
notice of
tap water
monitoring
results.
4014
4015
Consumer
notice
requirement.
A supplier
must provide
a notice
of
the
4016
individual
tap results
from
lead
tap water
monitoring
carried out
under the
4017
requirements
of Section
611.356
to the
persons
served
by
the water
system
4018
at the specific
sampling
site from
which the
sample was
taken (e.g.,
the
4019
occupants
of the
residence
where
the
tap
was
tested).
4020
4021
Timing
of consumer
notice.
The
supplier
must
provide
the consumer
4022
notice as
soon as practical,
but
no later than
30 days
after it learns
of
the
4023
tap monitoring
results.
4024
4025
)
Content
of consumer
notice.
The consumer
notice
must
include
the results
4026
of lead
tap
water
monitoring
for the tap
that was
tested,
an
explanation
of
4027
the
health effects
of lead,
steps
consumers
can
take
to reduce
exposure
to
4028
lead
in drinking
water,
and
contact information
for
the water
utility. The
4029
notice
must also
provide
the maximum
contaminant
level
goal and the
JCAR35O61
1-0814065r01
4030
action level
for lead
and
the definitions
for these
two terms
from
Section
4031
611.883(c).
4032
4033
4)
Delivery
of consumer
notice. The
consumer
notice
must
be provided
to
4034
persons served
at
the
tap
that
was tested,
either
by
mail or by
another
4035
method
approved
by the Agency,
by a
SEP issued
pursuant
to Section
4036
611.110.
For
example, upon
approval
by the
Agency,
a
NTNCWS
4037
supplier
could post
the
results
on a bulletin
board
in
the facility
to allow
4038
users to
review
the information.
The
supplier
must
provide
the notice
to
4039
customers
at sample
taps
tested,
including
consumers
who
do not receive
4040
water
bills.
4041
4042
BOARD NOTE:
Derived
from
40
CFR
141.85
(2007),
as
amended
at 72 Fed.
Reg.
4043
57782
(October
10, 2007)(2002).
4044
4045
(Source:
Amended
at 32
III. Reg.
effective
4046
4047
Section
611.356
Tap
Water
Monitoring
for
Lead
and Copper
4048
4049
a)
SamplingSample
site location.
4050
4051
1)
Selecting
a pool
of targeted
sampling
sites.
4052
4053
A)
By the applicable
date
for
commencement
of monitoring
under
4054
subsection
(d)(1)
of this Section,
each
supplier
must
complete
a
4055
materials
evaluation
of its distribution
system
in order
to identify
a
4056
pool of
targeted
sampling sites
that meets
the requirements
of
this
4057
Section.
4058
4059
B)
The
pooi of
targeted
sampling
sites
must
be
sufficiently
large to
4060
ensure
that the
supplier
can
collect the
number
of
lead
and copper
4061
tap
samples
required
by
subsection
(c) of
this Section.
4062
4063
C)
The supplier
must
select the sites
for collection
of first
draw
4064
samples
from this
pool
of targeted
sampling
sites.
4065
4066
D)
The supplier
must not
select
as
sampling
sites
any faucets
that have
4067
point-of-use
or point-of-entry
treatment devices
designed
to
4068
remove
or capable
of removing
inorganic
contaminants.
4069
4070
2)
Materials
evaluation.
4071
4072
A)
A
supplier must
use the
information
on lead,
copper, and
JCAR35O61
1-0814065r01
4073
galvanized
steel
collected
pursuant
to
40 CFR
141.42(d)
(special
4074
monitoring
for corrosivity
characteristics)
when
conducting
a
4075
materials
evaluation.
4076
4077
B)
When
an
evaluation
of
the
information
collected
pursuant
to
40
4078
CFR
141.42(d)
is
insufficient
to
locate
the
requisite
number
of lead
4079
and copper
sampling
sites
that meet
the
targeting
criteria
in
4080
subsection
(a) of this
Section,
the
supplier
must review
the
4081
following
sources
of
information
in order
to identify
a
sufficient
4082
number
of
sampling
sites:
4083
4084
i)
All plumbing
codes,
permits,
and records
in
the
files
of the
4085
building
departments
that
indicate
the
plumbing
materials
4086
that are
installed
within
publicly-
and
privately-owned
4087
structures
connected
to
the distribution
system;
4088
4089
ii)
All inspections
and records
of
the distribution system
that
4090
indicate
the
material
composition
of the
service
4091
connections
which
connect
a
structure
to the
distribution
4092
system;
4093
4094
iii)
All existing
water
quality
information,
which
includes
the
4095
results
of all
prior analyses
of
the system
or
individual
4096
structures
connected
to
the system,
indicating
locations
that
4097
may
be particularly
susceptible
to
high lead
or
copper
4098
concentrations;
and
4099
4100
iv)
The
supplier
must
seek to
collect
such
information where
4101
possible
in the
course
of its
normal
operations
(e.g.,
4102
checking
service
line materials
when
reading
water
meters
4103
or performing
maintenance
activities).
4104
4105
3)
Tiers
of sampling
sites.
Suppliers
must
categorize
the
sampling
sites
4106
within
their
pool
according
to
the following
tiers:
4107
4108
A)
CWS
Tier 1 sampling
sites.
“CWS
Tier 1
sampling
sites”
must
4109
include
the
following
single-family
structures:
4110
4111
i)
Those
that
contain
copper
pipes
with
lead
solder
installed
4112
after
1982
or
which
contain
lead
pipes;
or
4113
4114
ii)
Those that
are
served
by a lead
service
line.
4115
JCAR35O61
1-0814065r01
4116
BOARD
NOTE:
Subsection
(a)(3)(A)
was
derived
from
segments
4117
of 40
CFR
141.86(a)(3)
(2007)(2003). This
allows the pool of
4118
CWS
tier 1 sampling sites
to consist
exclusively of structures
4119
served
by lead service
lines.
4120
4121
B)
CWS Tier 2 sampling
sites. “CWS
Tier 2 sampling sites”
must
4122
include
the following
buildings,
including multiple-family
4123
structures:
4124
4125
i)
Those
that contain copper
pipes with lead solder
installed
4126
after 1982
or contain
lead pipes; or
4127
4128
ii)
Those
that are served
by
a lead
service line.
4129
4130
BOARD
NOTE:
Subsection (a)(3)(B)
was
derived from
segments
4131
of 40
CFR 141.86(a)(4)(2007)(2003).
This allows
the
pool of
4132
CWS
tier 2 sampling
sites to consist
exclusively of structures
4133
served
by lead service
lines.
4134
4135
C)
CWS Tier 3 sampling
sites.
“CWS
Tier
3
sampling
sites
T’
must
4136
include
the
following
single-family
structures: those that
contain
4137
copper pipes with
lead solder installed
before
1983.
4138
4139
BOARD
NOTE: Subsection (a)(3)(C)
was derived from
segments
4140
of 40 CFR
141.86(a)(5)
(2007)(2003).
4141
4142
D)
NTNCWS
Tier 1 sampling
sites. “NTNCWS Tier
1 sampling
4143
sites” must
include the following
buildings:
4144
4145
i)
Those
that contain copper
pipes with
lead solder
installed
4146
after 1982
or which
contain lead pipes; or
4147
4148
ii)
Those
that are served
by a
lead
service line.
4149
4150
BOARD NOTE:
Subsection
(a)(3)(D) was derived
from segments
4151
of 40
CFR
141.86(a)(6) (2007)(2003).
This allows the
pool
of
4152
NTNCWS tier
1 sampling
sites to consist exclusively
of buildings
4153
served by
lead service lines.
4154
4155
E)
Alternative
NTNCWS
sampling
sites. “Alternative
NTNCWS
4156
sampling
sites”
must
include the following
buildings: those that
4157
contain
copper pipes with
lead
solder
installed before 1983.
4158
JCAR35O61
1-0814065r01
4159
BOARD
NOTE:
Subsection
(a)(3)(E)
was
derived
from segments
4160
of
40
CFR 141
.86(a)(7)
(2007)(2003).
4161
4162
4)
Selection
of
sampling
sites.
Suppliers
must
select
sampling
sites
for
their
4163
sampling
pool
as follows:
4164
4165
A)
CWS
Suppliers.
CWS
suppliers
must
use
CWS
tier
1
sampling
4166
sites,
except
that
the
supplier
may
include
CWS
tier 2
or CWS
tier
4167
3
sampling
sites
in its sampling
pool as
follows:
4168
4169
i)
If
multiple-family
residences
comprise
at
least 20
percent
4170
of
the structures
served
by
a supplier,
the
supplier
may
use
4171
CWS
tier
2
sampling
sites
in
its
sampling
pool;
or
4172
4173
BOARD
NOTE:
Subsection
(a)(4)(A)(i)
was
derived
from
4174
a segment
of 40
CFR
141.86(a)(3)(ii) (2007)(20O3.
4175
4176
ii)
If the
CWS
supplier
has
an
insufficient
number
of
CWS
tier
4177
1 sampling
sites on
its
distribution
system,
the
supplier
may
4178
use
CWS
tier 2
sampling
sites in
its
sampling
pool;
or
4179
4180
BOARD
NOTE:
Subsection
(a)(4)(A)(ii)
was derived
from
4181
a
segment
of 40
CFR
141.86(a)(4) (2007)(2003).
4182
4183
iii)
If
the
CWS
supplier
has
an
insufficient
number
of CWS
tier
4184
1
and CWS
tier 2
sampling
sites
on its
distribution
system,
4185
the
supplier
may
complete
its
sampling
pool
with
CWS
tier
4186
3 sampling
sites.
4187
4188
BOARD
NOTE:
Subsection
(a)(4)(A)(iii)
was
derived
4189
from
a
segment
of
40
CFR
141.86(a)(5)
(2007)(2003).
4190
4191
iv)
If
the CWS
supplier
has
an
insufficient
number
of CWS
tier
4192
1 sampling
sites,
CWS
tier
2
sampling
sites, and
CWS
tier
4193
3
sampling
sites, the
supplier
must
use those
CWS
tier
1
4194
sampling
sites,
CWS
tier
2 sampling
sites,
and
CWS
tier
3
4195
sampling
sites
that
it has
and
complete
its
sampling
pool
4196
with
representative
sites
throughout
its
distribution
system
4197
for
the balance
of its sampling
sites. For
the
purpose
of this
4198
subsection
(a)(4)(A)(iv),
a
representative
site
is a
site
in
4199
which
the plumbing
materials
used at
that
site
would
be
4200
commonly
found
at
other
sites
served
by the
water
system.
4201
JCAR35O61 1-0814065r01
4202
BOARD NOTE:
Subsection
(a)(4)(A)(iv) was
derived
4203
from segments
of 40 CFR 141.86(a)(5)
(2007)(2003).
4204
4205
B)
NTNCWS suppliers.
4206
4207
i)
An
NTNCWS supplier
must select
NTNCWS tier 1
4208
sampling
sites
for its sampling pool.
4209
4210
BOARD
NOTE:
Subsection (a)(4)(B)(i)
was derived
from
4211
segments of 40 CFR
141.86(a)(6)
(2007)(2003).
4212
4213
ii)
If
the NTNCWS supplier
has an insufficient
number of
4214
NTNCWS
tier 1 sampling
sites, the
supplier may complete
4215
its sampling
pooi with
alternative NTNCWS
sampling
4216
sites.
4217
4218
BOARD
NOTE:
Subsection
(a)(4)(B)(ii) was
derived
from
4219
segments
of 40 CFR 141.86(a)(7)
(2007)(2003).
4220
4221
iii)
If the
NTNCWS
supplier
has an insufficient
number of
4222
NTNCWS
tier 1 sampling
sites and
NTNCWS
alternative
4223
sampling
sites, the
supplier must use representative
sites
4224
throughout
its
distribution system. For
the purpose of this
4225
subsection (a)(4)(B)(ii),
a representative
site is a site in
4226
which
the plumbing
materials used at
that site would
be
4227
commonly found
at other sites served
by the water system.
4228
4229
BOARD NOTE:
Subsection (a)(4)(B)(iii)
was derived
4230
from
segments
of 40 CFR 141.86(a)(7)
(2007)(2003).
4231
4232
C)
Suppliers
with lead
service
lines. Any supplier
whose distribution
4233
system
contains lead service
lines must draw samples
during
each
4234
six-month
monitoring
period from sampling
sites as follows:
4235
4236
i)
50
percent of the samples
from sampling
sites that contain
4237
lead
pipes or from
sampling sites that have
copper pipes
4238
with
lead
solder;
and
4239
4240
ii)
50 percent of those
samples
from sites
served by
a lead
4241
service line.
4242
4243
iii)
A supplier
that
cannot
identify
a sufficient number
of
4244
sampling
sites served
by
a lead
service
line
must collect
JCAR35O61
1-0814065r01
4245
first-draw
samples from
all
of the sites
identified as being
4246
served
by such lines.
4247
4248
BOARD
NOTE: Subsection
(a)(4)(C)
was derived from segments
4249
of 40 CFR
141.86(a)(8)
(2007)(2003).
This allows the pool
of
4250
sampling
sites to consist
exclusively of
structures or buildings
4251
served
by lead service
lines.
4252
4253
b)
Sample
collection
methods.
4254
4255
1)
All tap samples
for lead and copper
collected
in accordance with
this
4256
Subpart
G, with
the exception
of lead service line
samples collected
under
4257
Section 611.354(c)
and samples
collected under
subsection (b)(5)
of this
4258
Section,
must be
first-draw
samples.
4259
4260
2)
First-draw tap samples.
4261
4262
A)
Each first-draw
tap sample
for lead and copper
must be one liter
in
4263
volume
and
have stood
motionless in the plumbing
system of each
4264
sampling site
for at least six
hours.
4265
4266
B)
First-draw
samples from
residential housing
must be collected
4267
from the
cold
water kitchen
tap or
bathroom
sink tap.
4268
4269
C)
First-draw
samples from
a non-residential
building must
be one
4270
liter
in volume
and
must be collected
at an interior tap
from which
4271
water
is typically drawn
for consumption.
4272
4273
D)
Non-first-draw
samples
collected in
lieu of first-draw samples
4274
pursuant
to
subsection
(b)(5) of this Section
must be
one
liter in
4275
volume
and must be collected
at an
interior tap from which
water
4276
is typically
drawn
for consumption.
4277
4278
E)
First-draw
samples may
be collected by
the supplier or the supplier
4279
may allow
residents to
collect first-draw
samples after instructing
4280
the
residents
of the
sampling procedures
specified in this
4281
subsection
(b).
4282
4283
i)
To avoid
problems of residents
handling
nitric acid,
4284
acidification
of first-draw
samples may be done
up to 14
4285
days after
the sample is
collected.
4286
4287
ii)
After
acidification
to resolubilize the metals,
the sample
JCAR35O61 1-0814065r01
4288
must stand
in the
original
container for the time
specified
in
4289
the approved
USEPA method
before the
sample can be
4290
analyzed.
4291
4292
F)
If a supplier
allows residents
to perform sampling
under subsection
4293
(b)(2)(D) of this
Section,
the
supplier may
not challenge the
4294
accuracy
of sampling results
based on alleged
errors in
sample
4295
collection.
4296
4297
3)
Service line samples.
4298
4299
A)
Each service
line sample must
be one liter
in volume and have
4300
stood motionless
in the lead
service line for
at least six hours.
4301
4302
B)
Lead service
line samples must
be collected
in one of the following
4303
three
ways:
4304
4305
i)
At the
tap after flushing that
volume of water
calculated as
4306
being
between
the tap and
the lead service line
based
on the
4307
interior
diameter and
length of the pipe between
the tap and
4308
the
lead service line;
4309
4310
ii)
Tapping
directly into
the
lead service
line; or
4311
4312
iii)
If
the
sampling
site is a single-family
structure, allowing
4313
the water to run until
there is a significant
change in
4314
temperature
that
would
be indicative
of water that
has been
4315
standing in the lead
service
line.
4316
4317
4)
Follow-up
first-draw
tap samples.
4318
4319
A)
A supplier
must collect each
follow-up
first-draw
tap sample
from
4320
the same
sampling
site from
which it collected
the previous
4321
samples.
4322
4323
B)
If, for any
reason, the supplier
cannot gain entry
to a
sampling
site
4324
in order to
collect a
follow-up
tap sample, the
supplier may collect
4325
the follow-up
tap sample from
another
sampling
site in its
4326
sampling
pool,
as long
as the new site meets
the
same
targeting
4327
criteria
and is within
reasonable proximity
of the original site.
4328
4329
5)
Substitute
non-first-draw
samples.
4330
JCAR35O61
1-0814065r01
4331
A)
A NTNCWS
supplier or
a
CWS
supplier
that
meets the
criteria
of
4332
Sections
611
.355(be)(7)(A)
and
(be)(7)(B),
that does
not
have
4333
enough
taps
that
can
supply first-draw
samples,
as
defined
in
4334
Section
6 11.102,
may
apply
to the Agency
in
writing
to substitute
4335
non-first-draw
samples
by a
SEP granted
under Section
611.110.
4336
4337
B)
A supplier
approved
to
substitute
non-first-draw
samples
must
4338
collect
as many
first-draw
samples
from
appropriate
taps as
4339
possible
and identify
sampling
times
and locations
that
would
4340
likely
result
in the
longest standing
time for
the remaining
sites.
4341
4342
C)
The
Agency
may
grant a SEP
that
waives
the requirement
for
prior
4343
Agency
approval
of
non-first-draw
samplingsample
sites selected
4344
by the
system.
4345
4346
c)
Number of
samples.
4347
4348
1)
Suppliers
must
collect at
least
one
sample from
the
number of
sites listed
4349
in the
first colunm
of Table
D of this
Part (labelled
“standard
monitoring”)
4350
during
each six-month
monitoring
period specified
in subsection
(d) of
4351
this
Section.
4352
4353
2)
A supplier
conducting
reduced
monitoring
pursuant
to subsection
(d)(4)
of
4354
this
Section
must
collect
one sample
from
the
number of
sites specified
in
4355
the second
column
of
Table D of
this Part (labelled
“reduced
monitoring”)
4356
during each
reduced
monitoring
period specified
in
subsection
(d)(4)
of
4357
this
Section.
Such
reduced
monitoring
sites
must
be representative
of the
4358
sites
required
for
standard
monitoring.
A
supplier
whose
system has
fewer
4359
than five drinking
water
taps that
can be used
for
human
consumption
and
4360
which can
meet the
sampling
site
criteria
of
subsection
(a)
of this Section
4361
to reach the
required number
of sampling
sites
listed
in this
subsection
(c)
4362
must
collect multiple
samples
from
individual
taps.
To accomplish
this,
4363
the supplier
must
collect
at
least
one sample
from
each tap,
then it must
4364
collect
additional
samples
from
those
same taps
on
different
days during
4365
the monitoring
period,
in
order
to
collect
a total
number of
samples
that
4366
meets
the
required
number
of sampling
sites.
Alternatively,
the Agency
4367
must, by a
SEP issued
pursuant
to
Section 611.110,
allow
a
supplier
4368
whose
system
has fewer
than five drinking
water
taps
to
collect a number
4369
of samples
that is fewer
than the
number of
sites specified
in this
4370
subsection
(c)
if it determines
that 100 percent
of all
taps that
can
be used
4371
for human
consumption
are
sampled and
that the
reduced
number
of
4372
samples
will produce
the
same
results
as
would
the
collection
of
multiple
4373
samples
from
some
taps.
Any
Agency
approval
of
a reduction
of the
JCAR35O61
1-0814065r01
4374
minimum
number
of samples
must
be based
on a
request
from
the supplier
4375
or
on on-site
verification
by
the
Agency.
The
Agency
may,
by
a
SEP
4376
issued
pursuant
to Section
611.110,
specify
sampling
locations
when a
4377
system
is conducting
reduced
monitoring.
4378
4379
d)
Timing
of
monitoring.
4380
4381
1)
Initial tap
sampling.
4382
4383
The first
six-month
monitoring
period
for
small,
medium-sized
and
large
4384
system
suppliers must
begin
on the
dates specified
in
Table
E of this
Part.
4385
4386
A)
All
large
system
suppliers
must
monitor
during
each
of two
4387
consecutive
six-month
periods.
4388
4389
B)
All
small-
and
medium-sized
system
suppliers
must
monitor during
4390
each
consecutive
six-month
monitoring
period
until the
following
4391
is true:
4392
4393
i)
The supplier
exceeds
the lead
action
level
or
the copper
4394
action level
and
is therefore
required
to implement
the
4395
corrosion
control
treatment
requirements
under
Section
4396
611.351,
in which
case the
supplier
must
continue
4397
monitoring
in accordance
with subsection
(d)(2)
of
this
4398
Section;
or
4399
4400
ii)
The
supplier
meets the
lead action
level and
the
copper
4401
action
level
during each
of two
consecutive
six-month
4402
monitoring
periods,
in which case
the
supplier
may reduce
4403
monitoring
in accordance
with
subsection
(d)(4) of
this
4404
Section.
4405
4406
2)
Monitoring
after installation
of corrosion
control
and source
water
4407
treatment.
4408
4409
A)
Any
large
system supplier
that
installs optimal
corrosion
control
4410
treatment
pursuant
to
Section
611.351 (d)(4)
must
have monitored
4411
during each
of two
consecutive
six-month
monitoring
periods
4412
before
January 1,
1998.
4413
4414
B)
Any small-
or
medium-sized
system
supplier
that installs
optimal
4415
corrosion
control
treatment
pursuant
to Section
611.35
1(e)(5) must
4416
monitor
during
each of
two consecutive
six-month
monitoring
JCAR35O61
l-0814065r01
4417
periods
before 36
months
after
the Agency
approves
optimal
4418
corrosion
control treatment,
as
specified
in
Section
611.351
(e)(6).
4419
4420
C)
Any
supplier that
installs
source
water treatment
pursuant
to
4421
Section
61 1.353(a)(3)
must
monitor
during
each of
two
4422
consecutive
six-month
monitoring
periods
before
36 months
after
4423
completion
of step
2, as specified
in Section
611.353(a)(4).
4424
4425
3)
Monitoring
after the
Agency
specification
of water quality
parameter
4426
values
for optimal
corrosion
control.
4427
After
the
Agency
specifies
the values
for
water quality
control parameters
4428
pursuant
to
Section 611.352(f),
the
supplier
must
monitor
during
each
4429
subsequent
six-month
monitoring
period,
with the
first six-month
4430
monitoring
period to
begin
on the
date the Agency
specifies
the
optimal
4431
values.
4432
4433
4)
Reduced
monitoring.
4434
4435
A)
Reduction
to
annual
for
small-
and
medium-sized
system suppliers
4436
meeting
the
lead
and
copper action
levels.
A
small-
or
medium-
4437
sized
system supplier
that meets
the lead
and copper
action levels
4438
during
each of
two
consecutive
six-month
monitoring
periods
may
4439
reduce
the
number
of samples
in
accordance
with
subsection
(c) of
4440
this
Section,
and
reduce the
frequency
of
sampling
to once
per
4441
year.
A small-
or
medium-sized
system
supplier
that collects
4442
fewer
than
five
samples as
specified
in
subsection
(c)
of
this
4443
Section
and
which meets
the lead
and copper
action levels
during
4444
each
of two
consecutive
six-month
monitoring
periods
may reduce
4445
its
frequency
of
sampling
to once
per
year.
In
no case can
the
4446
supplier
reduce
the number
of samples
required
below the
4447
minimum
of
one
sample
per available
tap. This
reduced
sampling
4448
may
only begin
during the
calendar
year immediately
following
4449
the
end of the
second
consecutive
six-month
monitoring
period.
4450
4451
B)
SEP
allowing
reduction
to annual
for
suppliers
maintaining
water
4452
quality
control
parameters.
4453
4454
i)
Any supplier
that
meets
the lead
action
level and which
4455
maintains
the range
of values
for
the
water quality
control
4456
parameters
reflecting
optimal
corrosion
control
treatment
4457
specified by
the
Agency
under Section
611.352(f)
during
4458
each
of
two consecutive
six-month
monitoring
periods
may
4459
reduce
the
frequency
of monitoring
to once
per year and
the
JCAR35O61 1-0814065r01
4460
number of lead and
copper samples to that specified by
4461
subsection (c) of this Section if it receives written approval
4462
from
the
Agency
in the form of a SEP granted pursuant to
4463
Section 611.110. This reduced
sampling may oniy begin
4464
during the calendar year immediately following the end
of
4465
the second consecutive six-month monitoring period.
4466
4467
ii)
The Agency must review monitoring, treatment, and
other
4468
relevant
information submitted by the water system in
4469
accordance with Section 611.360, and
must notify
the
4470
system
in writing by a SEP granted pursuant to Sections
4471
611.110 when it determines the system is eligible to reduce
4472
its monitoring frequency
to
once
every three years pursuant
4473
to this
subsection (d)(4).
4474
4475
iii)
The Agency must review, and where
appropriate,
revise
its
4476
determination
under
subsection (d)(4)(B)(i) of this Section
4477
when the supplier submits new monitoring
or
treatment
4478
data,
or when other data relevant to the number and
4479
frequency of tap sampling becomes
available to the
4480
Agency.
4481
4482
C)
Reduction to triennial for small-
and
medium-sized system
4483
suppliers.
4484
4485
i)
Small- and medium-sized
system suppliers meeting lead
4486
and copper action levels. A small- or medium-sized system
4487
supplier that meets the lead
action
level
and
which meets
4488
the lead
and
copper action levels during three consecutive
4489
years of monitoring may reduce the
frequency
of
4490
monitoring
for lead and copper from annually to once every
4491
three years.
4492
4493
ii)
SEP
for suppliers meeting optimal corrosion control
4494
treatment. Any supplier
that maintains the
range
of values
4495
for
the water quality control parameters reflecting optimal
4496
corrosion
control treatment specified by the Agency under
4497
Section 611.352(f) during three
consecutive
years
of
4498
monitoring may reduce its monitoring frequency from
4499
annual
to once every three years if it receives written
4500
approval from
the Agency in the form of a SEP granted
4501
pursuant to Section 611.110.
Samples
collected once every
4502
three
years must be collected no later than every third
JCAR35O61
1-0814065r01
4503
calendar year.
4504
4505
iii)
The Agency must
review, and where appropriate,
revise
its
4506
determination under subsection
(d)(4)(C)(ii) of
this Section
4507
when the supplier submits new monitoring or treatment
4508
data,
or when other data relevant to the number and
4509
frequency
of
tap sampling
becomes available to
the
4510
Agency.
4511
4512
D)
Sampling at a reduced frequency. A supplier that reduces the
4513
number and frequency
of
sampling
must
collect these samples
4514
from
representative sites included in the pool of targeted sampling
4515
sites identified in subsection (a) of this Section, preferentially
4516
selecting those sampling sites
from the highest tier first. Suppliers
4517
sampling
annually or less frequently must conduct the lead and
4518
copper tap sampling during the months
of
June, July, August, or
4519
September,
unless
the
Agency
has approved a different sampling
4520
period in accordance with subsection (d)(4)(D)(i) of this Section.
4521
4522
i)
The Agency may grant a SEP pursuant to Section 611.110
4523
that approves a different period for conducting the lead and
4524
copper
tap
sampling
for systems collecting a reduced
4525
number of samples. Such a
period must be
no longer than
4526
four consecutive months and must represent a time of
4527
normal
operation
where the highest levels of lead are most
4528
likely to occur. For a NTNCWS
supplier
that does not
4529
operate during the months of June through September and
4530
for which the period of normal
operation
where the highest
4531
levels of lead are most likely to occur is not known, the
4532
Agency must designate a period that represents a time of
4533
normal operation
for the system. This reduced
sampling
4534
may only begin during the period approved or designated
4535
by the Agency in the calendar
year immediately
following
4536
the
end of the second consecutive six-month monitoring
4537
period for systems initiating annual
monitoring
and during
4538
the three-year period following the end of the third
4539
consecutive calendar year
of annual monitoring
for a
4540
supplier initiating triennial monitoring.
4541
4542
ii)
A
supplier
monitoring
annually that has been collecting
4543
samples during the months
of June through
September
and
4544
which receives Agency approval
to
alter
its
sample
4545
collection period under subsection (d)(4)(D)(i) of this
JCAR35O61
1-0814065r01
4546
Section
must
collect
its next
round
of samples
during
a time
4547
period
that
ends no later
than 21
months after
the
previous
4548
round of
sampling.
A supplier
monitoring
once every
three
4549
years that
has been collecting
samples
during
the
months of
4550
June through
September
and
which receives
Agency
4551
approval
to alter
the
sampling
collection
period
as
provided
4552
in subsection
(d)(4)(D)(i)
of this Section
must
collect its
4553
next
round of samples
during
a
time
period
that ends
no
4554
later
than
45
months
after
the
previous
round
of
sampling.
4555
Subsequent
rounds
of sampling
must
be collected
annually
4556
or
once
every
three
years,
as
required
by this Section.
A
4557
small
system supplier
with
a waiver granted
pursuant
to
4558
subsection
(g)
of this
Section
that
has
been
collecting
4559
samples
during
the months
of June
through
September
and
4560
which
receives
Agency
approval
to alter
its sample
4561
collection
period
under
subsection
(d)(4)(D)(i)
of this
4562
Section
must
collect
its next
round of
samples
before
the
4563
end of the
nine-year
compliance
cycle (as
that term is
4564
defined
in
Section
611.101).
4565
4566
E)
Any
water system
that demonstrates
for two consecutive
six-month
4567
monitoring
periods
that
the tap water
lead
level
computed
under
4568
Section
611.350(c)(3)
is less
than
or equal
to 0.005
mg!2 and
that
4569
the
tap
water
copper level
computed
under
Section
61 1.350(c)(3)
is
4570
less
than or
equal
to
0.65
mg/C may
reduce
the
number
of samples
4571
in
accordance
with subsection
(c) of this
Section
and reduce
the
4572
frequency
of sampling
to once every
three
calendar years.
4573
4574
F)
Resumption
of standard
monitoring.
4575
4576
i)
Small-
or
medium-sized
suppliers
exceeding
lead
or copper
4577
action
level. A
small- or medium-sized
system supplier
4578
subject
to
reduced
monitoring
that
exceeds
the lead
action
4579
level
or the
copper
action
level
must resume
sampling
in
4580
accordance
subsection
(d)(3)
of this
Section
and collect
the
4581
number
of samples
specified
for standard
monitoring
under
4582
subsection
(c) of this
Section.
Such
a
supplier
must also
4583
conduct
water quality
parameter
monitoring
in accordance
4584
with
Section 611.357(b),
(c), or
(d)
(as appropriate)
during
4585
the six-month
monitoring
period
in
which
it
exceeded the
4586
action
level.
Any
such
supplier
may
resume
annual
4587
monitoring
for lead and
copper
at
the tap at
the reduced
4588
number of
sites specified
in subsection
(c)
of this Section
JCAR35O61
1-0814065r01
4589
after it
has completed two subsequent consecutive
six-
4590
month rounds of monitoring that meet the criteria of
4591
subsection
(d)(4)(A) of this Section. Any such supplier
4592
may resume
monitoring once every three years for
lead
and
4593
copper at the reduced number of sites after it demonstrates
4594
through subsequent rounds of monitoring that it meets the
4595
criteria
of either subsection (d)(4)(C) or (d)(4)(E) of this
4596
Section.
4597
4598
ii)
Suppliers failing
to
operate within water quality control
4599
parameters. Any supplier subject to reduced monitoring
4600
frequency that fails to meet the lead action level during any
4601
four-month
monitoring
period
or
that
fails to
operate within
4602
the
range of values for the water quality control parameters
4603
specified pursuant to Section 611.352(f) for more than nine
4604
days in any
six-month
period specified
in
Section
4605
611.357(d) must conduct tap water sampling for lead and
4606
copper at
the
frequency specified
in subsection (d)(3) of
4607
this Section, must collect the number of samples specified
4608
for standard
monitoring
under
subsection (c) of
this
4609
Section, and must resume monitoring for water quality
4610
parameters within the distribution system in accordance
4611
with
Section 611.357(d). This standard tap water sampling
4612
must begin no later than the six-month period beginning
4613
January 1 of the calendar year following the lead action
4614
level
exceedance or water
quality
parameter excursion. A
4615
supplier may resume reduced monitoring for lead and
4616
copper
at the tap and for water quality parameters within
4617
the distribution system only if it fulfills the conditions set
4618
forth in subsection
(d)(4)(H) of this Section.
4619
4620
BOARD NOTE: The Board moved the material from the last
4621
sentence
of
40
CFR 141.86(d)(4)(vi)(B) and
40
CFR
4622
141.
86(d)(4)(vi)(B)(1
)
through
(d)(4)(vi)(B)(3)
(2007)
to
4623
subsections
(dX4)(H)
and
(d)(4)(H)(i) through
(d)(4)(H)(iii),
since
4624
Illinois Administrative Code codification requirements allow
4625
subsections only to four indent levels.
4626
4627
G)
Any water supplier subject to a reduced monitoring frequency
4628
under subsection (d)(4) of this Section that either adds a new
4629
source of water
or changes any water treatment must notify info
4630
the
Agency in
writing in accordance with Section 61 1.360(a)(3)of
4631
any upcoming long-term change in treatment or addition of a new
JCAR35O61
1-0814065r01
4632
source
as
described
in that
Section.
The
Agency
must
review
and
4633
approve
the
addition
of a
new
source
or
long-term
change
in
water
4634
treatment
before
it
is
implemented
by
the supplier.
The
Agency
4635
may,
by a
SEP
granted
pursuant
to Section
611.110,
require
the
4636
system
to
resume
sampling
in accordance
with subsection
(d)(3)
of
4637
this
Section
and
collect
the
number
of
samples
specified
for
4638
standard
monitoring
under
subsection
(c) of
this Section
or take
4639
other
appropriate
steps
such
as increased
water quality
parameter
4640
monitoring
or
re-evaluation
of its
corrosion
control
treatment
given
4641
the potentially
different
water
quality
considerations.
4642
4643
H)
A
supplier
required
under
subsection
(d)(4)(F)
of
this Section
to
4644
resume
monitoring
in
accordance
with
Section
611.357(d)
may
4645
resume
reduced
monitoring
for
lead
and
copper
at the
tap
and
for
4646
water
quality
parameters
within
the
distribution
system
under
the
4647
following
conditions:
4648
4649
i)
The
supplier
may
resume
annual
monitoring
for lead
and
4650
copper
at
the
tap
at the
reduced
number
of
sites
specified
in
4651
subsection
(c)
of this
Section
after it
has completed
two
4652
subsequent
six-month
rounds
of
monitoring
that
meet
the
4653
criteria
of subsection
(d)(4)(B)
of this
Section
and
the
4654
supplier
has received
written
approval
from
the
Agency
by
4655
a SEP pursuant
to Section
611.110
that it
is appropriate
to
4656
resume
reduced
monitoring
on
an annual
frequency.
This
4657
sampling
must
begin
during
the calendar
year immediately
4658
following
the
end
of the
second
consecutive
six-month
4659
monitoring
period.
4660
4661
ii)
The
supplier
may resume
monitoring
for
lead
and
copper
4662
once
every
three
years
at
the tap
at
the reduced
number
of
4663
sites
after it
demonstrates
through
subsequent
rounds
of
4664
monitoring
that
it meets
the
criteria
of either
subsection
4665
(d)(4)(C)
or
(d)(4)(E)
of this
Section
and
the system
has
4666
received
a SEP
under
Section
611.110
from
the
Agency
4667
that it is
appropriate
to resume
monitoring
once
every three
4668
years.
4669
4670
iii)
The
supplier
may reduce
the number
of
water quality
4671
parameter
tap
water
samples
required
in
accordance
with
4672
Section
61
1.357(e)(1)
and the
frequency
with which
it
4673
collects
such
samples
in
accordance
with
Section
4674
61
1.357(e)(2).
Such
a
system
may not
resume
monitoring
JCAR35O61
1-0814065r01
4675
once
every three years for water quality
parameters
at the
4676
tap until it demonstrates, in accordance with the
4677
requirements of Section 61 1.357(e)(2), that it has
re
4678
qualified for monitoring once every
three
years.
4679
4680
BOARD NOTE: Subsections
(d)(4)(H)
and (d)(4)(H)(i)
through
4681
(d)(4)(H)(iii) are derived from the last sentence of
40 CFR
4682
141.86(d)(4)(vi)(B)
and
40
CFR
141.86 (d)(4)(vi)(B)(1) through
4683
(d)(4)(vi)(B)(3) (2007)(2003), since Illinois
Administrative Code
4684
codification
requirements allow only four
indent
levels of
4685
subsections.
4686
4687
e)
Additional monitoring.
The results of any monitoring
conducted in addition to
4688
the minimum requirements of this Section must be considered by the
supplier and
4689
the
Agency in making any determinations (i.e., calculating the
90
th
percentile lead
4690
action level or the
copper level) under this Subpart G.
4691
4692
f)
Invalidation of lead
or copper tap water samples. A sample
invalidated under this
4693
subsection does not count toward determining lead or copper
percentile
levels
4694
under Section 61 1.350(c)(3)
or
toward meeting the minimum
monitoring
4695
requirements of subsection
(c) of this
Section.
4696
4697
1)
The Agency must invalidate a lead or copper tap water
sample if it
4698
determines
that one of the following conditions
exists:
4699
4700
A)
The laboratory establishes that improper sample
analysis caused
4701
erroneous
results;
4702
4703
B)
The sample
was
taken
from
a site that did not meet the site
4704
selection criteria of this Section;
4705
4706
C)
The
sample
container was damaged in
transit; or
4707
4708
D)
There is substantial
reason to
believe that the sample was subject
4709
to tampering.
4710
4711
2)
The supplier must report the results of all samples to the Agency and all
4712
supporting documentation for samples the supplier believes
should
be
4713
invalidated.
4714
4715
3)
To invalidate a sample under subsection (f)(1) of this Section, the decision
4716
and
the rationale for the decision must be documented in
writing. The
4717
Agency may
not invalidate a sample solely on the grounds
that a follow-
JCAR35O61 1-0814065r01
4718
up sample
result
is
higher
or
lower
than
that
of the
original
sample.
4719
4720
4)
The water
supplier
must
collect
replacement
samples
for any
samples
4721
invalidated
under
this
Section
if,
after
the
invalidation
of
one
or
more
4722
samples,
the supplier
has
too few
samples
to
meet
the
minimum
4723
requirements
of
subsection
(c)
of this
Section.
Any
such
replacement
4724
samples
must
be taken
as
soon
as
possible,
but
no
later
than
20
days
after
4725
the
date
the Agency
invalidates
the
sample
or
by the
end
of the
applicable
4726
monitoring
period,
whichever
occurs
later.
Replacement
samples
taken
4727
after
the
end
of the
applicable
monitoring
period
must
not
also
be
used
to
4728
meet
the
monitoring
requirements
of a
subsequent
monitoring
period.
The
4729
replacement
samples
must
be
taken
at the
same
locations
as the
4730
invalidated
samples
or, if
that
is
not
possible,
at
locations
other
than
those
4731
already
used
for
sampling
during
the
monitoring
period.
4732
4733
g)
Monitoring waivers
for
small
system
suppliers.
Any
small
system
supplier
that
4734
meets
the
criteria
of
this
subsection
(g)
may
apply
to the
Agency
to reduce
the
4735
frequency
of
monitoring
for
lead
and
copper
under
this
Section
to
once
every
nine
4736
years
(i.e.,
a
“full waiver”)
if
it
meets
all of
the materials
criteria
specified
in
4737
subsection
(g)(1)
of this
Section
and
all
of the
monitoring
criteria
specified
in
4738
subsection
(g)(2)
of this
Section.
Any
small
system
supplier
that
meets
the
4739
criteria
in subsections
(g)(1)
and
(g)(2)
of
this Section
only
for lead,
or
only
for
4740
copper,
may
apply
to
the State
for
a waiver
to reduce
the
frequency
of
tap
water
4741
monitoring
to once
every
nine
years
for that
contaminant
only
(i.e.,
a
“partial
4742
waiver”).
4743
4744
1)
Materials
criteria.
The
supplier
must
demonstrate
that its
distribution
4745
system
and service
lines
and
all
drinking
water
supply
plumbing,
4746
including
plumbing conveying
drinking
water
within
all
residences
and
4747
buildings
connected
to the
system,
are
free
of
lead-containing
materials
or
4748
copper-containing
materials,
as
those
terms
are
defined
in
this
subsection
4749
(g)(1),
as
follows:
4750
4751
A)
Lead.
To
qualify
for
a full
waiver,
or
a waiver
of
the tap
water
4752
monitoring
requirements
for
lead
(i.e.,
a
“lead
waiver”),
the
water
4753
supplier
must
provide
certification
and
supporting
documentation
4754
to
the Agency
that
the
system
is
free
of all
lead-containing
4755
materials,
as
follows:
4756
4757
i)
It
contains
no
plastic
pipes
that
contain
lead plasticizers,
or
4758
plastic
service
lines
that
contain
lead
plasticizers;
and
4759
4760
ii)
It is free
of
lead
service
lines,
lead
pipes,
lead
soldered
pipe
JCAR35O61
1-0814065r01
4761
joints,
and
leaded
brass
or
bronze
alloy
fittings
and
fixtures,
4762
unless
such
fittings
and
fixtures
meet
the
specifications
of
4763
NSF Standard
61, section
9,
incorporated
by
reference
in
4764
Section
611.102.
4765
4766
BOARD
NOTE:
Corresponding 40
CFR
4767
141 .86(g)(1)(i)(B)
specifies
“any
standard
established
4768
pursuant
to
42
USC
300g-6(e)
(SDWA
section
1417(e)).”
4769
USEPA
has
stated
that the
NSF
standard
is that
standard.
4770
See 62
Fed.
Reg.
44684
(Aug.
22,
1997).
4771
4772
B)
Copper.
To qualify
for a full
waiver,
or a waiver
of the tap
water
4773
monitoring
requirements
for copper
(i.e.,
a “copper
waiver”),
the
4774
water
supplier
must
provide
certification
and
supporting
4775
documentation
to the Agency
that the
system
contains
no
copper
4776
pipes
or copper
service
lines.
4777
4778
2)
Monitoring
criteria
for waiver
issuance.
The
supplier
must have
completed
4779
at
least
one
six-month
round
of
standard
tap
water
monitoring
for lead
and
4780
copper
at
sites approved
by
the
Agency
and from
the
number
of
sites
4781
required
by subsection
(c) of
this Section
and
demonstrate
that
the
4782
percentile
levels
for any
and
all
rounds
of
monitoring
conducted
since
the
4783
system
became
free
of all
lead-containing
or
copper-containing
materials,
4784
as appropriate,
meet
the following
criteria:
4785
4786
A)
Lead
levels.
To qualify
for
a full waiver,
or
a lead
waiver,
the
4787
supplier
must
demonstrate
that the
percentile
lead
level
does
4788
not
exceed
0.005
mg!€.
4789
4790
B)
Copper
levels.
To
qualify
for
a full
waiver,
or a copper
waiver,
the
4791
supplier
must
demonstrate
that
the
90
th
percentile
copper
level
does
4792
not exceed
0.65
mg!e.
4793
4794
3)
State
approval
of waiver
application.
The
Agency
must notify
the supplier
4795
of
its waiver
determination
by
a SEP
issued
pursuant
to Section
611.110,
4796
in writing,
setting
forth
the basis
of
its decision
and
any condition
of
the
4797
waiver.
As
a
condition
of
the
waiver,
the Agency
may
require
the
supplier
4798
to perform
specific
activities
(e.g., limited
monitoring,
periodic
outreach
4799
to customers
to remind
them
to avoid
installation
of materials
that
might
4800
void
the
waiver)
to
avoid
the risk
of lead
or
copper
concentration
of
4801
concern
in
tap
water.
The
small system
supplier
must
continue
monitoring
4802
for
lead
and
copper
at
the tap
as
required
by
subsections
(d)(1)
through
4803
(d)(4)
of
this Section,
as
appropriate,
until
it receives
written
notification
JCAR35O61
1-0814065r01
4804
from
the
Agency
that
the waiver
has
been approved.
4805
4806
4)
Monitoring
frequency
for suppliers
with waivers.
4807
4808
A)
A supplier
with
a
full
waiver
must
conduct
tap
water
monitoring
4809
for
lead
and
copper
in
accordance
with
subsection
(d)(4)(D)
of this
4810
Section
at
the reduced
number
of
sampling
sites
identified
in
4811
subsection
(c)
of
this Section
at
least once
every
nine
years
and
4812
provide
the
materials
certification
specified
in
subsection
(g)(1)
of
4813
this Section
for
both
lead
and copper
to
the Agency
along
with
the
4814
monitoring
results.
Samples
collected
every
nine
years
must
be
4815
collected
no
later
than
every
ninth
calendar
year.
4816
4817
B)
A
supplier
with
a partial
waiver
must
conduct
tap
water
monitoring
4818
for
the
waived
contaminant
in accordance
with
subsection
4819
(d)(4)(D)
of
this Section
at
the reduced
number
of
sampling
sites
4820
specified
in subsection
(c) of
this Section
at
least
once
every
nine
4821
years
and
provide
the
materials
certification
specified
in
subsection
4822
(g)(l)
of
this
Section
pertaining
to the
waived
contaminant
along
4823
with
the
monitoring
results.
Such
a supplier
also
must continue
to
4824
monitor
for the
non-waived
contaminant
in
accordance
with
4825
requirements
of subsections
(d)(1)
through
(d)(4)
of
this
Section,
4826
as appropriate.
4827
4828
C)
jyIf-a
supplier
with
a full
or partial
waiver
adds
a
new
source
of
4829
water
or changes
any
water
treatment,
the supplier
must
notify
the
4830
Agency
in
writing
in
accordance
with
Section
61 1.360(a)(3)
of any
4831
upcoming
long-term
change
in
treatment
or addition
of
a new
4832
source,
as
described
in
that
Section.
The
Agency
must
review
and
4833
approve
the
addition
of
a new source
or
long-term
change
in
water
4834
treatment
before
it
is implemented
by
the
supplier.
The
Agency
4835
has the
authority
to
require
the
supplier
to
add
or modify
waiver
4836
conditions
(e.g., require
recertification
that
the
supplier’s
system
is
4837
free
of
lead-containing
or copper-containing
materials, require
4838
additional
rounds
of monitoring),
if it deems
such
modifications
4839
are
necessary
to address
treatment
or
source
water
changes
at
the
4840
system.
4841
4842
D)
If a
supplier
with
a
full or
partial
waiver
becomes
aware
that
it is
4843
no
longer
free of
lead-containing
or
copper-containing
materials,
4844
as
appropriate
(e.g.,
as
a result
of
new
construction
or
repairs),
the
4845
supplier
must
notify
the Agency
in
writing
no later
than 60
days
4846
afler
becoming
aware
of
such
a change.
JCAR35O61
1-0814065r01
4847
4848
5)
Continued
eligibility.
If the supplier
continues
to satisfy
the
requirements
4849
of
subsection
(g)(4)
of
this Section,
the
waiver
will
be renewed
4850
automatically,
unless
any
of
the
conditions
listed
in subsection
(g)(5)(A)
4851
through
(g)(5)(C)
of
this Section
occur.
A
supplier
whose
waiver
has
been
4852
revoked
may
re-apply
for a
waiver
at such
time
as
it again
meets
the
4853
appropriate
materials
and monitoring
criteria
of
subsections
(g)(1)
and
4854
(g)(2)
of
this Section.
4855
4856
A)
A
supplier
with
a full
waiver
or a
lead
waiver
no longer
satisfies
4857
the materials
criteria
of subsection
(g)(1)(A)
of
this Section
or
has
4858
a
90
th
percentile
lead
level
greater
than 0.005
mg/e.
4859
4860
B)
A
supplier
with
a full
waiver
or a
copper
waiver
no longer
satisfies
4861
the
materials
criteria
of subsection
(g)(1)(B)
of this
Section
or
has
4862
a
90
th
percentile
copper
level
greater
than
0.65 mg/i.
4863
4864
C)
The
State
notifies
the
supplier,
in
writing,
that
the
waiver
has
been
4865
revoked,
setting
forth
the
basis
of its
decision.
4866
4867
6)
Requirements
following
waiver
revocation.
A
supplier
whose
full
or
4868
partial
waiver
has
been
revoked
by
the Agency
is
subject
to the
corrosion
4869
control
treatment
and
lead and
copper
tap
water
monitoring
requirements,
4870
as
follows:
4871
4872
A)
If the
supplier
exceeds
the
lead
or
copper
action
level,
the
supplier
4873
must
implement
corrosion
control
treatment
in
accordance
with
the
4874
deadlines
specified
in
Section
611.351(e),
and
any other
applicable
4875
requirements
of this
Subpart
G.
4876
4877
B)
If the
supplier
meets
both
the lead
and the
copper
action
level,
the
4878
supplier
must
monitor
for
lead and
copper
at the
tap
no
less
4879
frequently
than
once
every three
years
using
the
reduced
number
of
4880
samplingsample
sites
specified
in
subsection
(c)
of this
Section.
4881
4882
7)
Pre-existing
waivers.
Small
system
supplier
waivers
approved
by
the
4883
Agency
in writing
prior
to
April
11,
2000
must
remain
in effect
under
the
4884
following
conditions:
4885
4886
A)
If
the
supplier
has
demonstrated
that it
is both
free of
lead
4887
containing
and copper-containing
materials,
as
required
by
4888
subsection
(g)(1)
of
this
Section
and
that
its
90
th
percentile
lead
4889
levels
and
90th
percentile
copper
levels
meet
the criteria
of
JCAR35O61
1-0814065r01
4890
subsection
(g)(2) of this
Section,
the
waiver
remains in
effect
so
4891
long as
the
supplier
continues
to meet the
waiver eligibility
criteria
4892
of
subsection
(g)(5) of
this
Section. The
first
round
of
tap water
4893
monitoring
conducted
pursuant
to subsection
(g)(4)
of this Section
4894
must
be
completed
no later
than nine years
after the
last
time
the
4895
supplier
monitored
for
lead
and
copper
at
the
tap.
4896
4897
B)
If the
supplier
has met the
materials
criteria
of
subsection
(g)(l) of
4898
this
Section
but
has
not met
the monitoring
criteria
of subsection
4899
(g)(2)
of this Section,
the
supplier must
conduct
a round of
4900
monitoring
for
lead
and
copper
at
the tap
demonstrating
that it met
4901
the
criteria
of
subsection
(g)(2) of this
Section
no
later than
4902
September
30, 2000.
Thereafter,
the waiver
must
remain in
effect
4903
as long
as the supplier
meets
the continued
eligibility
criteria
of
4904
subsection
(g)(5)
of this
Section.
The
first
round of
tap water
4905
monitoring
conducted
pursuant
to subsection
(g)(4)
of this Section
4906
must be completed
no
later than
nine years
after
the
round
of
4907
monitoring
conducted
pursuant
to subsection
(g)(2)
of this Section.
4908
4909
BOARD
NOTE:
Derived
from
40 CFR
141.86
(2007),
as amended
at 72
Fed. Reg.
4910
57782 (October
10, 2007)(2003).
4911
4912
(Source:
Amended
at 32 Ill.
Reg.
effective
4913
4914
Section
611.357
Monitoring
for
Water Quality
Parameters
4915
4916
All
large
system
suppliers,
and all
small-
and
medium-sized
system
suppliers
that exceed
the
4917
lead
action
level or
the
copper action
level, must
monitor
water
quality
parameters
in addition
to
4918
lead
and
copper
in
accordance
with
this Section.
The requirements
of this
Section are
4919
summarized
in Table G
of
this Part.
4920
4921
a)
General
Requirements.
4922
4923
1)
Sample
collection
methods.
4924
4925
A)
Use of
tap
samples.
The
totality of all
tap samples
collected
by a
4926
supplier
must
be
representative
of
water
quality throughout
the
4927
distribution
system
taking
into account
the number
of persons
4928
served,
the
different
sources
of
water,
the different
treatment
4929
methods
employed
by the
supplier,
and
seasonal
variability.
4930
Although
a supplier
may
conveniently
conduct
tap sampling
for
4931
water quality
parameters
at sites
used
for
coliform
sampling
4932
performed
pursuant
to Subpart
L of this
Part, it is not
required
to
JCAR35O61
l-0814065r01
4933
do
so,
and a
supplier is
not required
to perform
tap sampling
4934
pursuant to
this Section
at taps targeted
for
lead and
copper
4935
sampling
under Section
611.356(a).
4936
4937
B)
Use of entry
point
samples. Each
supplier
must
collect samples
at
4938
entry
points to the
distribution
system
from
locations
4939
representative
of
each
source
after
treatment.
If
a supplier
draws
4940
water
from
more
than one
source and
the
sources
are combined
4941
before
distribution,
the supplier
must
sample at
an entry
point to
4942
the distribution
system
during
periods
of normal
operating
4943
conditions
(i.e.,
when water
is representative
of
all sources
being
4944
used).
4945
4946
2)
Number
of samples.
4947
4948
A)
Tap samples.
Each supplier
must collect
two tap
samples for
4949
applicable
water quality
parameters
during
each
six-month
4950
monitoring
period
specified
under
subsections
(b)
through (e)
of
4951
this Section
from the
number
of sites indicated
in the
first colunm
4952
of
Table
E of this
Part.
4953
4954
B)
Entry
point samples.
4955
4956
i)
Initial monitoring.
Except
as
provided
in subsection
(c)(3)
4957
of this
Section, each
supplier
must
collect
two
samples for
4958
each
applicable
water quality
parameter
at each entry
point
4959
to
the
distribution
system
during
each
six-month
4960
monitoring
period
specified
in subsection
(b) of
this
4961
Section.
4962
4963
ii)
Subsequent
monitoring.
Each
supplier must
collect
one
4964
sample
for
each applicable
water
quality
parameter
at each
4965
entry
point
to
the
distribution
system during
each six-month
4966
monitoring
period
specified
in
subsections
(c) through
(e)
4967
of this
Section.
4968
4969
b)
Initial
Sampling.
4970
4971
1)
Large
systems.
Each
large system
supplier
must
measure
the
applicable
4972
water
quality
parameters
specified
in
subsection
(b)(3) of this
Section
at
4973
taps
and at
each entry
point to
the distribution
system
during
each
six
4974
month monitoring
period specified
in
Section
611
.356(d)(1).
4975
JCAR35O61
1-0814065r01
4976
2)
Small- and
medium-sized
systems.
Each
small-
and medium-sized
system
4977
supplier
must
measure
the applicable
water
quality parameters
specified
in
4978
subsection
(b)(3)
of this
Section
at the locations
specified
in this
4979
subsection
during
each
six-month
monitoring
period
specified in
Section
4980
611 .356(d)(1)
during
which
the supplier
exceeds the
lead action
level or
4981
the copper
action
level.
4982
4983
3)
Water
quality
parameters.
4984
4985
A)
pH;
4986
4987
B)
Alkalinity;
4988
4989
C)
Orthophosphate,
when
an
inhibitor
containing
a phosphate
4990
compound
is used;
4991
4992
D)
Silica,
when
an
inhibitor
containing
a silicate
compound
is used;
4993
4994
E)
Calcium;
4995
4996
F)
Conductivity;
and
4997
4998
G)
Water temperature.
4999
5000
c)
Monitoring
after installation
of
corrosion
control.
5001
5002
1)
Large
systems.
Each large
system
supplier that
installs optimal
corrosion
5003
control
treatment
pursuant
to Section
611.35
1(d)(4)
must measure
the
5004
water
quality
parameters
at the
locations
and frequencies
specified
in
5005
subsections
(c)(4)
and
(c)(5)
of this Section
during
each six-month
5006
monitoring
period
specified
in Section
61
1.356(d)(2)(A).
5007
5008
2)
Small-
and medium-sized
systems.
Each
small-
or
medium-sized
system
5009
that
installs optimal
corrosion
control
treatment
pursuant to
Section
5010
611.35
1(e)(5) must
measure
the water quality
parameters
at the
locations
5011
and
frequencies
specified
in
subsections
(c)(4) and
(c)(5) of
this Section
5012
during
each six-month
monitoring
period specified
in Section
5013
611 .356(d)(2)(B)
in which
the supplier
exceeds
the
lead action
level
or
the
5014
copper
action
level.
5015
5016
3)
Any
groundwater
system
can limit
entry
point
sampling described
in
5017
subsection
(c)(2) of
this
Section to
those
entry
points that
are
5018
representative
of water
quality
and treatment
conditions
throughout
the
JCAR35O61
1-0814065r01
5019
system.
If
water
from
untreated
groundwater
sources
mixes
with
water
5020
from
treated
groundwater
sources,
the
system
must
monitor
for water
5021
quality
parameters
both
at
representative
entry
points
receiving
treatment
5022
and
representative
entry
points
receiving
no
treatment.
Prior
to
the
start
of
5023
any
monitoring
under
this
subsection,
the
system
must
provide
to
the
5024
Agency
written
information
identifying
the
selected
entry
points
and
5025
documentation,
including
information
on
seasonal
variability,
sufficient
to
5026
demonstrate
that
the
sites
are
representative
of
water
quality
and
treatment
5027
conditions
throughout
the
system.
5028
5029
4)
Tap water
samples,
two samples
at
each tap
for each
of
the
following
5030
water
quality
parameters:
5031
5032
A)
pH;
5033
5034
B)
Alkalinity;
5035
5036
C)
Orthophosphate,
when
an inhibitor
containing
a
phosphate
5037
compound
is used;
5038
5039
D)
Silica, when
an
inhibitor
containing
a
silicate
compound
is
used;
5040
and
5041
5042
E)
Calcium,
when
calcium
carbonate
stabilization
is
used
as
part of
5043
corrosion
control.
5044
5045
5)
Entry
point
samples,
except
as provided
in
subsection
(c)(3)
of
this
5046
Section,
one
sample
at each
entry
point
to the
distribution
system
every
5047
two
weeks
(bi-weekly)
for
each
of
the following
water quality
parameters:
5048
5049
A)
pH;
5050
5051
B)
When
alkalinity
is
adjusted
as part
of
optimal
corrosion
control,
a
5052
reading
of the
dosage
rate
of
the chemical
used to
adjust
alkalinity,
5053
and
the
alkalinity
concentration;
and
5054
5055
C)
When
a corrosion
inhibitor
is used
as part
of optimal
corrosion
5056
control,
a reading
of
the
dosage
rate
of
the
inhibitor
used,
and the
5057
concentration
of
orthophosphate
or
silica
(whichever
is
applicable).
5058
5059
d)
Monitoring
after
the
Agency
specifies
water quality
parameter
values
for optimal
5060
corrosion
control.
5061
JCAR35O61
l-0814065r01
5062
1)
Large
system
suppliers.
After
the Agency
has
specified
the values
for
5063
applicable
water
quality control
parameters
reflecting
optimal
corrosion
5064
control
treatment
pursuant
to
Section
611.352(f),
each
large
system
5065
supplier
must measure
the
applicable
water
quality
parameters
in
5066
accordance
with
subsection
(c) of this
Section
and determine
compliance
5067
with
the requirements
of
Section
611.352(g)
every
six
months with
the
5068
first
six-month
period
to
begin on either
January
1
or
July 1, whichever
5069
comes
first,
afterthe date
the AgencyState
specifies
the
optimal values
5070
under
Section
611.352(f).
5071
5072
2)
Small-
and
medium-sized
system
suppliers.
Each small-
or
medium-sized
5073
system
supplier
must
conduct
such
monitoring
during each
six-month
5074
monitoring
period
specified
in this
subsection
(d) in
which
the supplier
5075
exceeds
the lead
action
level
or the
copper action
level.
For any such
5076
small and
medium-size
system
that
is subject to
a reduced
monitoring
5077
frequency
pursuant
to
Section
611 .356(d)(4)
at the
time
of the
action
level
5078
exceedence,
the
startend
of the
applicable
six-month
monitoring
period
5079
under
this
subsection
ç)
must
coincide
with
the
startend
of
the applicable
5080
monitoring
period
under
Section
611.3
56(d)(4).
5081
5082
3)
Compliance
with
Agency-designated
optimal
water quality
parameter
5083
values
must
be
determined
as
specified
under
Section 611.352(g).
5084
5085
e)
Reduced
monitoring.
5086
5087
1)
Reduction
in
tap
monitoring.
A
supplier
that has
maintained
the range of
5088
values
for
the water
quality
parameters
reflecting
optimal
corrosion
5089
control
treatment
during
each of two
consecutive
six-month
monitoring
5090
periods
under
subsection
(d)
of
this Section
must
continue
monitoring
at
5091
the entry
points
to the
distribution
system
as
specified in
subsection
(c)(4)
5092
of
this Section.
Such
a
supplier
may collect
two samples
from
each
tap for
5093
applicable
water
quality
parameters
from the
reduced number
of sites
5094
indicated
in the
second column
of Table
E
of this
Part
during each
5095
subsequent
six-month
monitoring
period.
5096
5097
2)
Reduction
in
monitoring
frequency.
5098
5099
A)
Staged
reductions
in monitoring
frequency.
5100
5101
i)
Annual
monitoring.
A supplier
that
maintains
the range
of
5102
values
for
the water
quality
parameters
reflecting
optimal
5103
corrosion
control
treatment
specified
pursuant
to Section
5104
611.352(f)
during three
consecutive
years
of monitoring
JCAR35O61
1-0814065r01
5105
may
reduce
the
frequency
with
which
it collects
the number
5106
of
tap
samples
for
applicable
water
quality
parameters
5107
specified
in
subsection
(e)(1)
of
this Section
from
every
six
5108
months
to annually.
This
reduced
sampling
may oniy
begin
5109
during
the
calendar
year
immediately
following
the end
of
5110
the
monitoring
period
in which
the third
consecutive
year
5111
of six-month
monitoring
occurs.
5112
5113
ii)
Triennial
monitoring.
A supplier
that
maintains
the
range
5114
of values
for
the water
quality
parameters
reflecting
5115
optimal
corrosion
control
treatment
specified
pursuant
to
5116
Section
611.352(f)
during
three
consecutive
years
of
annual
5117
monitoring
under
subsection
(e)(2)(A)(i)
of
this Section
5118
may reduce
the
frequency
with
which
it collects
the
number
5119
of
tap
samples
for
applicable
water
quality
parameters
5120
specified
in subsection
(e)(1)
of
this
Section
from
annually
5121
to
once every
three
years.
This
reduced
sampling
may
only
5122
begin no
later
than
the
third
calendar
year
following
the
end
5123
of
the monitoring
period
in which
the
third consecutive
5124
year of
monitoring
occurs.
5125
5126
B)
A
water
supplier
may
reduce
the frequency
with which
it collects
5127
tap
samples
for
applicable
water
quality
parameters
specified
in
5128
subsection
(e)(1)
of
this Section
to
every
three
years
if it
5129
demonstrates
that
it
has
fulfilled
the
conditions
set
forth in
5130
subsections
(e)(2)(B)(i)
through
(e)(2)(B’)(iii)
of
this Section-the
5131
following
during
two
consecutive
monitoring
periods,
subject
to
5132
the
conditions
of subsection
(e)(2)(B)(iv)
of this
Section.
5133
5134
i)
That
its tap
water
lead
level
at
the
9O’ percentile
is
less
5135
than or
equal
to the PQL
for
lead
specified
in Section
5136
611.359(a)(1)(B);
5137
5138
ii)
That its
tap water
copper
level
at the
90
th
percentile
is less
5139
than
or
equal
to 0.65
mg/i for
copper
in Section
5140
611.350(c)(2);
and
5141
5142
iii)
That
it also
has maintained
the
range
of values
for
the
water
5143
quality
parameters
reflecting
optimal
corrosion
control
5144
treatment
specified
by the
Agency
under
Section
5145
611.352(f).
5146
JCAR35O61
1-0814065r01
5147
j
Monitoring conducted
every
three
years must be done
no
5148
later
than
every
third calendar year.
5149
5150
3)
A supplier that
conducts sampling
annually
or every three years
must
5151
collect
these
samples
evenly
throughout
the calendar
year so
as to reflect
5152
seasonal
variability.
5153
5154
4)
Any
supplier
subject
to a reduced monitoring
frequency
pursuant to this
5155
subsection
that fails to operate
at or above
the
minimum value
or
within
5156
the
range
of values
for
the water quality parameters
specified
pursuant to
5157
Section
611.352(f)
for more
than nine
days in any six-month
period
5158
specified
in Section
611.352(g)
must resume
tap water
sampling
in
5159
accordance
with
the number
and frequency requirements
of
subsection
(d)
5160
of this Section.
Such a system
may resume
annual monitoring for
water
5161
quality
parameters
at the
tap at the reduced number
of sites specified
in
5162
subsection (e)(1)
of this Section
after
it has
completed two subsequent
5163
consecutive
six-month rounds
of monitoring that
meet
the
criteria
of that
5164
subsection
or may
resume monitoring
once every
three years for
water
5165
quality parameters
at the tap
at the reduced number
of sites
after
it
5166
demonstrates through
subsequent
rounds of
monitoring that it meets
the
5167
criteria
of either
subsection
(e)(2)(A) or (e)(2)(B)
of this Section.
5168
5169
f)
Additional monitoring
by suppliers.
The results
of any monitoring conducted
in
5170
addition
to the minimum
requirements
of this Section
must be considered
by the
5171
supplier and
the Agency in making
any determinations
(i.e., determining
5172
concentrations
of water
quality
parameters) under
this Section or
Section 611.352.
5173
5174
BOARD NOTE:
Derived
from
40
CFR 141.87
(2007),
as amended
at 72 Fed.
Reg. 57782
5175
(October
10,
2007)(2002).
5176
5177
(Source:
Amended at 32 Ill.
Reg.
effective
5178
5179
Section 611.358
Monitoring
for Lead
and Copper in Source
Water
5180
5181
a)
Sample
location,
collection
methods,
and number
of samples.
5182
5183
1)
A supplier that
fails to meet
the lead action
level or the copper
action
level
5184
on the basis
of tap
samples
collected in accordance
with
Section 611.356
5185
must
collect lead and copper
source water
samples
in accordance with the
5186
following
requirements
regarding
sample location,
number of samples,
5187
and
collection
methods:
5188
5189
A)
A groundwater
supplier
must take a minimum
of one sample
at
JCAR35O61
1-0814065r01
5190
every
entry
point
to
the
distribution
system
that
is
representative
of
5191
each
well
after
treatment
(hereafter
called
a
sampling
point).
The
5192
supplier
must
take
one
sample
at
the
same
sampling
point
unless
5193
conditions
make
another
sampling
point
more
representative
of
5194
each
source
or
treatment
plant.
5195
5196
B)
A surface
water
supplier
must
take
a
minimum
of
one
sample
at
5197
every
entry
point
to
the distribution
system
after
any
application
of
5198
treatment
or in
the
distribution
system
at
a point
that
is
5199
representative
of each
source
after
treatment
(hereafter
called
a
5200
sampling
point).
The
system
must
take
each
sample
at the
same
5201
sampling
point
unless
conditions
make
another
sampling
point
5202
more
representative
of
each
source
or
treatment
plant.
5203
5204
BOARD
NOTE:
For
the
purposes
of
this
subsection
(a)(1)(B),
5205
surface
water
systems
include
systems
with
a combination
of
5206
surface
and
ground
sources.
5207
5208
C)
If
a
supplier
draws
water
from
more
than
one
source
and
the
5209
sources
are
combined
before
distribution,
the
supplier
must
sample
5210
at an
entry
point
to the
distribution
system
during
periods
of
5211
normal
operating
conditions
(i.e.,
when
water
is
representative
of
5212
all
sources
being
used).
5213
5214
D)
The
Agency
may,
by
a
SEP issued
pursuant
to
Section
611.110,
5215
reduce
the
total
number
of
samples that must
be
analyzed
by
5216
allowing
the
use of
compositing.
Compositing
of samples
must
be
5217
done
by
certified
laboratory
personnel.
Composite
samples
from
a
5218
maximum
of
five
samples
are
allowed,
provided
that
if the
lead
5219
concentration
in
the
composite
sample
is
greater
than
or equal
to
5220
0.00
1 mg/C
or
the
copper
concentration
is greater
than
or
equal
to
5221
0.160
mg/C,
then
the
supplier
must
do
either
of
the following:
5222
5223
i)
The
supplier
must
take
and analyze
a
follow-up
sample
5224
within
14
days
at
each
sampling
point
included
in the
5225
composite;
or
5226
5227
ii)
If
duplicates
of
or
sufficient
quantities
from
the
original
5228
samples
from
each
sampling
point
used
in
the
composite
5229
are
available,
the
supplier
may
use these
instead
of
5230
resampling.
5231
5232
2)
SEP
requiring
an
additional
sample.
JCAR35O61
1-0814065r01
5233
5234
A)
When
the Agency
determines
that the
results of
sampling
indicate
5235
an exceedence
of
the
lead
or copper
MPC
established
under
5236
Section
611
.353(b)(4),
it
must,
by
a SEP
issued
pursuant to
Section
5237
611.110,
require
the supplier
to collect
one
additional
sample
as
5238
soon as possible
after
the initial
sample
at the
same
sampling
point,
5239
but
no later
than
two
weeks after
the
supplier
took the initial
5240
sample.
5241
5242
B)
If a supplier
takes
an
Agency-required
confirmation
sample
for
5243
lead
or
copper,
the
supplier must
average
the
results obtained
from
5244
the initial
sample with
the results
obtained
from the confirmation
5245
sample
in
determining
compliance
with
the
Agency-specified
lead
5246
and
copper
MPCs.
5247
5248
i)
Any analytical
result
below
the MDL
must
be considered
5249
as zero
for
the
purposes
of
averaging.
5250
5251
ii)
Any
value
above
the MDL
but
below
the
PQL must
either
5252
be considered
as the
measured
value
or
be
considered
one-
5253
half
the PQL.
5254
5255
b)
Monitoring
frequency
after
system exceeds
tap water
action
level. A supplier
that
5256
exceeds
the
lead
action level
or
the copper
action
level
in
tap sampling
must
5257
collect
one source
water
sample from
each entry
point
to
the
distribution
system
5258
no
later thanwithin
six
months
after
the end
of the monitoring
period
during
5259
which
the lead
or
copper
action level
was exceeded.
For
monitoring
periods
that
5260
are
annual or less
frequent,
the
end of
the monitoring
period
is September
30
of
5261
the
calendar
year in which
the sampling
occurs,
or if the
Agency has
established
5262
an
alternate
monitoring
period
by
a
SEP issued
pursuant
to
Section 611.110,
the
5263
last
day
of that period.
exceedence.
5264
5265
c)
Monitoring
frequency
after
installation
of
source
water
treatment.
A supplier
that
5266
installs
source
water treatment
pursuant
to Section
611.353(a)(3)
must
collect an
5267
additional
source
water sample
from each
entry
point to
the
distribution
system
5268
during
each
of
two consecutive
six-month
monitoring
periods
on or before
36
5269
months
after
completion
of step
2, as specified
in Section
61
1.353(a)(4).
5270
5271
d)
Monitoring
frequency
after the Agency
has specified
the
lead
and
copper MPCs
5272
or has
determined
that
source
water
treatment
is not needed.
5273
5274
1)
A
supplier must
monitor
at the frequency
specified
by subsection
5275
(d)(1)(A)
or
(d)(1)(B)
of
this Section
where
the Agency
has specified
the
JCAR35O61
1-0814065r01
5276
MPCs
pursuant
to Section
61 1.353(b)(4)
or has
determined
that
the
5277
supplier
is not
required
to install
source
water
treatment
pursuant
to
5278
Section
61
1.353(b)(2).
5279
5280
A)
GWS
suppliers.
5281
5282
i)
A
GWS
supplier
required
to sample
by
subsection
(d)(1)
of
5283
this
Section
must
collect
samples
once
during the
three-
5284
year
compliance
period
(as that
term
is
defined
in
Section
5285
611.101)
during
which
the
Agency
makes
its determination
5286
pursuant
to Section
611
.353(b)(4)
or 611
.353(b)(2).
5287
5288
ii)
A GWS
supplier
required
to
sample
by subsection
(d)(1)
of
5289
this
Section
must
collect
samples
once
during
each
5290
subsequent
compliance
period.
5291
5292
ffl
Triennial
samples
must
be
collected
every
third
calendar
5293
year.
5294
5295
B)
A SWS
or mixed
system
supplier
must
collect
samples
once
during
5296
each
calendar
yearannually,
the first
annual
monitoring
period
to
5297
begin
during
the year
mon
the
date
on
which
the
Agency
makes
its
5298
determination
pursuant
to
Section
61
1.353(b)(4)
or
61
1.353(b)(2).
5299
5300
2)
A supplier
is
not
required
to conduct
source
water
sampling
for
lead
or
5301
copper
if
the
supplier
meets
the action
level
for
the specific
contaminant
in
5302
all
tap water
samples
collected
during
the entire
source
water
sampling
5303
period
applicable
under subsection
(d)(1)(A)
or
(d)(1)(B)
of
this
Section.
5304
5305
e)
Reduced
monitoring
frequency.
5306
5307
1)
A GWS
supplier
may
reduce
the
monitoring
frequency
for lead
and
copper
5308
in source
water
to once
during
each
nine-year
compliance
cycle
(as that
5309
term
is
defined
in
Section
611.101),
provided
that
the
samples
are
5310
collected
no
later than
every
ninth
calendar
year,
and only
if
the
supplier
5311
meets
one
of
the
following
criteria:
5312
5313
A)
The
supplier
demonstrates
that finished
drinking
water
entering
the
5314
distribution
system
has
been maintained
below
the maximum
5315
permissible
lead
and copper
concentrations
specified
by
the
State
5316
in Section
61
1.353(b)(4)
during
at
least
three
consecutive
5317
compliance
periods
under
subsection
(d)(1)
of this
Section;
or
5318
JCAR35O61
1-0814065r01
5319
B)
The
Agency
has
determined,
by
a SEP
issued
pursuant
to
Section
5320
611.110,
that
source
water
treatment
is
not
needed
and
the
system
5321
demonstrates
that, during
at
least
three
consecutive
compliance
5322
periods
in
which
sampling
was conducted
under
subsection
(d)(1)
5323
of
this
Section,
the
concentration
of lead
in source
water
was
less
5324
than
or equal
to
0.005
mg/e
and
the
concentration
of
copper
in
5325
source
water
was
less than
or equal
to
0.65
mgI.
5326
5327
2)
A SWS
or
mixed
system
supplier
may
reduce
the
monitoring
frequency
in
5328
subsection
(d)(1)
of this
Section
to once
during
each
nine-year
5329
compliance
cycle
(as that
term
is
defined
in Section
611.101),
provided
5330
that the
samples
are
collected
no later
than every
ninth
calendar
year, and
5331
çpjy
if
the
supplier
meets
one of
the following
criteria:
5332
5333
A)
The
supplier
demonstrates
that finished
drinking
water
entering
the
5334
distribution
system
has been
maintained
below the
maximum
5335
permissible
lead
and
copper
concentrations
specified
by
the
5336
Agency
under
Section
61 1.353(b)(4)
for
at least
three
consecutive
5337
years;
or
5338
5339
B)
The
Agency
has
determined,
by
a SEP
issued
pursuant
to
Section
5340
611.110,
that
source
water
treatment
is
not
needed
and
the supplier
5341
demonstrates
that,
during
at least
three
consecutive
years,
the
5342
concentration
of
lead
in
source
water
was
less
than or
equal
to
5343
0.005
mg!2
and the
concentration
of
copper
in
source
water was
5344
less
than
or equal
to 0.65
mg/R.
5345
5346
3)
A
supplier
that
uses
a new
source
of water
is
not eligible
for
reduced
5347
monitoring
for lead
or
copper
until
it demonstrates
by
samples
collected
5348
from
the
new
source
during
three
consecutive
monitoring
periods,
of
the
5349
appropriate
duration
provided
by
subsection
(d)(1)
of
this Section,
that
5350
lead
or
copper
concentrations
are
below
the MPC
as
specified
by
the
5351
Agency
pursuant
to Section
611
.353(a)(4).
5352
5353
BOARD
NOTE:
Derived
from 40
CFR
141.88
(2007),
as amended
at
72 Fed.
Reg.
5354
57782
(October
10.
2007)(2003).
5355
5356
(Source:
Amended
at 32
Iii.
Reg.
effective
5357
5358
Section
611.359
Analytical
Methods
5359
5360
Analyses
for lead,
copper,
pH,
conductivity,
calcium,
alkalinity,
orthophosphate,
silica,
and
5361
temperature
must
be conducted
using
the
methods
set
forth
in Section
611.611(a).
JCAR35O61
1-0814065r01
5362
5363
a)
Analyses
for
lead
and copper
performed
for
the purposes
of
compliance
with
this
5364
Subpart
G
must only
be
conducted
by
laboratories
that have
been
certified
by
5365
USEPA
or
the
Agency.
To obtain
certification
to
conduct
analyses
for
lead
and
5366
copper,
laboratories
must
do
the following:
5367
5368
1)
Analyze
performance
evaluation
samples
that
include
lead and
copper
5369
provided
by
USEPA
Environmental
Monitoring
and
Support
Laboratory
5370
or
equivalent
samples
provided
by
the Agency;
and
5371
5372
2)
Achieve
quantitative
acceptance
limits
as
follows:
5373
5374
A)
For
lead:
+30
percent
of the
actual
amount
in
the
performance
5375
evaluation
sample
when
the actual
amount
is greater
than
or
equal
5376
to
0.005
mg/2
(the
PQL
for
lead is
0.005 mg/e);
5377
5378
B)
For
copper:
±10
percent
of the
actual
amount
in the
performance
5379
evaluation
sample
when
the
actual
amount
is
greater
than
or
equal
5380
to
0.050 mg/€
(the
PQL
for
copper
is 0.050
mg!e);
5381
5382
C)
Achieve
the
method
detection
limit
(MDL)
for lead
(0.00
1 mg/E,
5383
as
defined
in Section
611.350(a))
according
to the
procedures
in
35
5384
Ill.
Adm.
Code
186 and
appendix
B to
40 CFR
136:
“Definition
5385
and
Procedure
for the
Determination
of
the
Method
Detection
5386
Limit
— Revision
1.11
(2005)”,
incorporated
by
reference
in
5387
Section
611.102(c).
This need
only
be
accomplished
if
the
5388
laboratory
will
be
processing
source
water
composite
samples
5389
under
Section
611.358(a)(1)(D)611.358(a)(1)(C);
and
5390
5391
D)
Be
currently
certified
by USEPA
or the
Agency
to perform
5392
analyses
to the
specifications
described
in
subsection
(a)(1)(a)(2)
5393
of
this Section.
5394
5395
BOARD
NOTE:
Subsection
(a) is
derived
from
40 CFR
141.89(a)
and
(a)(1)
5396
(2007),
as
amended
at 72
Fed.
Reg.
57782
(October
12,
2007)(2005).
5397
5398
b)
The
Agency
must,
by
a SEP
issued
pursuant
to
Section
6
11.110,
allow
a supplier
5399
to
use previously
collected
monitoring
data
for the
purposes
of
monitoring
under
5400
this
Subpart
G
if the data
were
collected
and analyzed
in accordance
with
the
5401
requirements
of this
Subpart
G.
5402
5403
BOARD
NOTE:
Subsection
(b)
is derived
from
40
CFR
141.89(a)(2)
5404
(2007)(2005).
JCAR35O61
1-0814065r01
5405
5406
c)
Reporting
lead and
copper
levels.
5407
5408
1)
All
lead
and copper
levels
greater than
or
equal
to
the lead
and
copper
5409
PQL
(Pb
0.005
mgle and
Cu 0.050
mg/i)
must be reported
as
5410
measured.
5411
5412
2)
All lead
and
copper levels
measured
less than
the PQL
and greater
than
5413
the
MDL
(0.005 mg/i>
Pb> MDL
and 0.050
mg/1?
>
Cu > MDL)
must be
5414
either
reported
as measured
or as
one-half
the PQL
set
forth in subsection
5415
(a)
of this Section
(i.e.,
reported
as 0.0025
mg/i for
lead
or
0.025
mg/e for
5416
copper).
5417
5418
3)
All lead
and
copper
levels
below
the lead and
copper
MDL
(MDL
> Pb)
5419
must be
reported
as zero.
5420
5421
BOARD
NOTE:
Subsection
(c) is derived
from
40
CFR
141.89(a)(3)
and
(a)(4)
(2007)(2005).
5422
5423
(Source:
Amended
at
32 Ill.
Reg.
effective
5424
5425
Section 611.360
Reporting
5426
5427
A
supplier
must
report
all
of the following
information
to
the
Agency
in
accordance
with
this
5428
Section.
5429
5430
a)
Reporting
for
tap,
lead,
and
copper,
and
water
quality
parameter
monitoring.
5431
5432
1)
Except as provided
in
subsection
(a)(1)(viii)
of this
Section,
a supplier
5433
must
report
the following
information
for
all
samples
specified
in Section
5434
611.356 and
for
all
water
quality
parameter
samples
specified
in Section
5435
611.357
within
ten
days
of the
end of each
applicable
sampling
period
5436
specified in
Sections 611.356
and
611.357 (i.e.,
every
six months,
5437
annually,
every
three
years,
or every
nine
years).
For a monitoring
period
5438
with
a duration
less than
six months,
the end
of the
monitoring
period
is
5439
the
last
date on
which samples
can
be
collected
during
that
period, as
5440
specified
in
Sections 611.356
and
611.357.
5441
5442
A)
The
results of
all
tap samples
for lead
and copper,
including
the
5443
location
of each
site and
the criteria
under Section
61 1.356(a)(3)
5444
through (a)(7)
under
which the
site was
selected
for
the
supplier’s
5445
sampling
pool;
5446
5447
B)
Documentation
for
each tap water
lead
or
copper sample
for which
JCAR35O61
1-0814065r01
5448
the
water supplier
requests
invalidation
pursuant
to
Section
5449
611.356(0(2);
5450
5451
C)
This subsection
(a)(1)(C)
corresponds
with
40
CFR
5452
141.90(a)(1)(iii),
a
provision that
USEPA
removed
and marked
5453
“reserved.”
This
statement
preserves structural
parity
with the
5454
federal
rules;
5455
5456
D)
The
90
th
percentile
lead
and
copper concentrations
measured
from
5457
among
all
lead
and
copper tap
samples
collected
during
each
5458
sampling
period
(calculated
in accordance
with
Section
5459
61 1.350(c)(3)),
unless
the
Agency
calculates
the
system’s
90
th
5460
percentile
lead
and
copper
levels under
subsection
(h) of this
5461
Section;
5462
5463
E)
With the exception
of
initial
tap sampling
conducted
pursuant
to
5464
Section
61
1.356(d)(1),
the supplier
must
designate
any site that
5465
was not sampled
during
previous
sampling
periods,
and include
an
5466
explanation
of
why
sampling
sites have changed;
5467
5468
F)
The results
of all tap
samples
for
pH,
and
where
applicable,
5469
alkalinity,
calcium,
conductivity,
temperature,
and
orthophosphate
5470
or
silica
collected
pursuant
to Section
611.357(b)
through
(e);
5471
5472
G)
The
results of
all samples
collected
at entry
points
for applicable
5473
water
quality
parameters
pursuant
to Section
611.357(b)
through
5474
(e).
5475
5476
H)
A water
supplier
must report
the
results of
all water
quality
5477
parameter
samples
collected
under
Section 611.357(c)
through
(0
5478
during
each
six-month
monitoring
period
specified
in Section
5479
611.357(d)
within
the first
10
days
following
the
end of
the
5480
monitoring
period,
unless
the
Agency
has
specified,
by a SEP
5481
granted
pursuant
to Section
611.110,
a
more frequent
reporting
5482
requirement.
5483
5484
2)
For a
NTNCWS
supplier,
or
a CWS
supplier
meeting
the
criteria
of
5485
Sections
611
.355(be)(7)(A)
and
(be)(7)(B),
that
does
not have enough
taps
5486
which
can provide
first-draw
samples,
the
supplier
must
do either
of the
5487
following:
5488
5489
A)
Provide
written
documentation
to the Agency
that identifies
5490
standing times
and locations
for enough
non-first-draw
samples
to
JCAR35O61
1-0814065r01
5491
make
up
its
sampling
pool
under
Section
61 1.356(b)(5)
by the
start
5492
of the
first
applicable
monitoring
period
under
Section
611.356(d)
5493
that
commenced
after
April
11, 2000,
unless
the Agency
has
5494
waived
prior
Agency
approval
of
non-first-draw
samplingsample
5495
sites
selected
by the
supplier
pursuant
to
Section
61
1.356(b)(5);
or
5496
5497
B)
If
the Agency
has
waived
prior
approval
of
non-first-draw
5498
samplingsample
sites
selected
by
the
supplier,
identify,
in writing,
5499
each
site
that
did
not
meet
the six-hour
minimum
standing
time
5500
and
the
length
of
standing
time
for
that
particular
substitute
sample
5501
collected
pursuant
to
Section
61
1.356(b)(5)
and
include
this
5502
information
with
the lead
and
copper
tap
sample
results
required
to
5503
be
submitted
pursuant
to
subsection
(a)(1)(A)
of
this
Section.
5504
5505
3)
At
a
time
specified
by
the
Agency,
by
a SEP
issued
pursuant
to
Section
5506
611.110,
or if no
specific
time
is
designated
by
the
Agency,
then
as
early
5507
as possible
prior
toNo
later
than
60
days after
the
addition
of a
new source
5508
or
any
change
in
water
treatment,
unless
the
Agency
requires
earlier
5509
notification,
a water
supplier
deemed
to have
optimized
corrosion
control
5510
under
Section
61
1.351(b)(3),
a
water
supplier
subject
to
reduced
5511
monitoring
pursuant
to
Section
61 1.356(d)(4),
or
a water
supplier
subject
5512
to a
monitoring
waiver
pursuant to
Section
611
.356(g)
must
submitsei4
5513
written
documentation
to
the Agency
describing
the
change
or
addition.
5514
Tn those
instances
where
prior
Agency
approval
of
the treatment
change
or
5515
new
source
is
not required,
USEPA
has
stated
that
it encourages
water
5516
systems
to provide
the notification
to the
Agency
beforehand
to
minimize
5517
the
risk the
treatment
change
or new
source
will
adversely
affect
optimal
5518
corrosion
control.
5519
5520
4)
Any
small
system
supplier
applying
for
a
monitoring
waiver
under
Section
5521
611.356(g),
or
subject
to
a
waiver
granted
pursuant
to Section
5522
611
.356(g)(3), must
provide
the
following
information
to
the Agency
in
5523
writing
by
the
specified
deadline:
5524
5525
A)
By
the
start
of the
first
applicable
monitoring
period
in
Section
5526
611.356(d),
any
small
water
system
supplier
applying
for a
5527
monitoring
waiver
must
provide
the documentation
required
to
5528
demonstrate
that
it meets
the
waiver
criteria
of
Sections
5529
611.356(g)(1)
and
(g)(2).
5530
5531
B)
No later
than
nine
years
after
the
monitoring
previously
conducted
5532
pursuant
to Section
611.356(g)(2)
or Section
611.356(g)(4)(A),
5533
each
small
system
supplier
desiring
to maintain
its
monitoring
JCAR35O61 1-0814065r01
5534
waiver
must
provide
the
information
required
by
Sections
5535
611.356(g)(4)(A)
and
(g)(4)(B).
5536
5537
C)
No
later
than
60 days
afler it
becomes
aware
that
it is no
longer
5538
free of
lead-containing
or copper-containing
material,
as
5539
appropriate,
each small
system
supplier
with
a monitoring waiver
5540
must
provide
written
notification
to the
Agency,
setting
forth
the
5541
circumstances
resulting
in
the lead-containing
or
copper-containing
5542
materials
being
introduced
into the
system
and
what
corrective
5543
action,
if any,
the supplier
plans to
remove
these
materials.
5544
5545
D)
By October
10, 2000,
any
small
system
supplier
with
a
waiver
5546
granted
prior
to April
11, 2000
and
that
had
not previously
met the
5547
requirements
of
Section
61 1.356(g)(2)
must
have
provided
the
5548
information
required
by
that
subsection.
5549
5550
5)
Each
GWS
supplier
that
limits
water
quality
parameter
monitoring to
a
5551
subset
of
entry
points
under Section
61
1.357(c)(3)
must
provide,
by
the
5552
commencement
of such
monitoring,
written
correspondence
to
the
Agency
5553
that
identifies
the
selected
entry
points
and includes
information
sufficient
5554
to demonstrate
that the
sites
are representative
of water
quality
and
5555
treatment
conditions
throughout
the
system.
5556
5557
b)
Reporting
for
source
water
monitoring.
5558
5559
1)
A supplier
must
report
the
sampling
results
for
all
source
water
samples
5560
collected
in
accordance
with
Section
611.358
within
ten
days
of the end
of
5561
each
source
water sampling
period
(i.e., annually,
per
compliance
period,
5562
per
compliance
cycle)
specified
in
Section
611.358.
5563
5564
2)
With
the
exception
of the
first
round
of
source
water
sampling
conducted
5565
pursuant
to
Section
611.358(b),
a
supplier
must
specify
any site
that was
5566
not sampled
during
previous
sampling
periods,
and
include
an
explanation
5567
of
why
the
sampling
point
has
changed.
5568
5569
c)
Reporting
for
corrosion
control
treatment.
5570
5571
By
the
applicable
dates
under
Section
611.351,
a
supplier
must
report
the
5572
following
information:
5573
5574
1)
For
a supplier
demonstrating
that
it
has
already
optimized
corrosion
5575
control,
the
information
required
by
Section
61
1.352(b)(2)
or (b)(3).
5576
JCAR35O61
1-0814065r01
5577
2)
For a supplier
required
to optimize
corrosion
control,
its
recommendation
5578
regarding
optimal
corrosion
control
treatment
pursuant
to
Section
5579
611.352(a).
5580
5581
3)
For
a
supplier
required
to
evaluate
the
effectiveness
of
corrosion
control
5582
treatments
pursuant
to
Section
611.352(c),
the
information
required
by
5583
Section
611.352(c).
5584
5585
4)
For
a supplier
required
to
install
optimal
corrosion
control
approved
by the
5586
Agency
pursuant
to Section
611.352(d),
a copy
of the
Agency
permit
5587
letter,
which
acts
as certification
that the
supplier
has completed
installing
5588
the permitted
treatment.
5589
5590
d)
Reporting
for
source
water
treatment.
On
or before
the
applicable
dates
in
5591
Section
611.353,
a
supplier
must
provide
the
following
information
to
the
5592
Agency:
5593
5594
1)
If required
by
Section
61 1.353(b)(1),
its
recommendation
regarding
source
5595
water
treatment;
or
5596
5597
2)
For
suppliers
required
to
install
source
water
treatment
pursuant
to Section
5598
611.353(b)(2),
a copy
of
the
Agency
permit
letter,
which
acts as
5599
certification
that
the
supplier
has
completed
installing
the
treatment
5600
approved
by
the
Agency
within
24
months
after
the
Agency
approved
the
5601
treatment.
5602
5603
e)
Reporting
for lead
service
line replacement.
A
supplier
must
report
the
following
5604
information
to the
Agency
to demonstrate
compliance
with the
requirements
of
5605
Section
611.354:
5606
5607
1)
No
later than
12 months
after
the
end of
a monitoring
period
in
5608
whichWithin
12 months
after
a supplier
exceeds
the
lead action
level in
5609
sampling
referred
to in Section
611.354(a),
the
supplier
must
submitreport
5610
each
of the
following
to
the
Agency
in writing:
5611
5612
A)
The
materialA
demonstration
that
it has
conducted
a
materials
5613
evaluation,
including
the
evaluation
conducted
as required
by
5614
Section
611.356(a);
5615
5616
B)
Theldentify
the
initial
number
of lead
service
lines
in its
5617
distribution
system
at
the time
the supplier
exceeds
the lead
action
5618
level;
and
5619
JCAR35O61
l-0814065r01
5620
C)
TheProvide
the
Agency
with
the supplier’s
schedule
for
annually
5621
replacing
at least
seven percent
of the initial
number
of
lead
5622
service
lines
in its
distribution
system.
5623
5624
2)
Action
by
the supplier.
5625
5626
No
later
thanWithin
12
months
after the
end of a monitoring
period
5627
in which a
supplier exceeds
the
lead
action
level
in
sampling
5628
referred
to in Section
611.354(a),
and every
12 months
thereafter,
5629
the supplier
must
demonstrate
to the Agency
in
writing
that
the
5630
supplier
has done
either
of the
following:
5631
5632
jA)
Replaced
in the
previous
12 months
at
least
seven percent
5633
of
the
initial
number
of lead
service
lines in its
distribution
5634
system
(or any greater
number
of
lines
specified
by the
5635
Agency
pursuant to
Section
611.354(e));
or
5636
5637
iiB)
Conducted
sampling
that
demonstrates
that
the
lead
5638
concentration
in
all
service
line
samples
from
individual
5639
lines,
taken
pursuant
to Section
611
.356(b)(3),
is less than
5640
or equal
to 0.0 15
mgfl.
5641
5642
BG)
WhenWhere
the
supplier
makes
a
demonstration
under
subsection
5643
(e)(2)(AR)jj
of
this
Section, the
total
number
of
lines
that the
5644
supplier
has
replaced,
combined
with
the
total number
that meet
5645
the criteria
of
Section
611.354(c)611.354(b),
must
equal at least
5646
seven percent
of
the
initial number
of
lead
lines identified
pursuant
5647
to subsection
fç)f1)a
of this
Section (or
the percentage
specified
5648
by the Agency
pursuant
to Section
611.354(e)).
5649
5650
3)
The annual
letter submitted
to the Agency
pursuant
to subsection
(e)(2)
of
5651
this
Section
must
contain the
following
information:
5652
5653
A)
The number
of
lead
service
lines
originally
scheduled
to be
5654
replaced
during
the previous
year
of the
supplier’s
replacement
5655
schedule;
5656
5657
B)
The number
and location
of each
lead
service
line
actually replaced
5658
during the
previous
year of the
supplier’s
replacement
schedule;
5659
and
5660
5661
C)
If measured,
the
water lead
concentration
from
each lead
service
5662
line
sampled pursuant
to
Section
611 .356(b)(3)
and the
location
of
JCAR35O61
1-0814065r01
5663
each lead
service line
sampled,
the
sampling
method
used,
and the
5664
date
of sampling.
5665
5666
4)
Any
supplier
that collects
lead service
line
samples
following
partial
lead
5667
service
line
replacement
required
by
Section
611.354 must
report
the
5668
results
to
the Agency
within the
first ten days
of the
month following
the
5669
month in which
the supplier
receives
the
laboratory
results, or
as specified
5670
by
the
Agency.
The
Agency may,
by
a
SEP
granted
pursuant to
Section
5671
611 .110, eliminate
this requirement
to report
these
monitoring
results.
A
5672
supplier
must also report
any additional
information
as specified
by the
5673
Agency, and
in a
time
and manner
prescribed
by the
Agency,
to verify that
5674
all
partial
lead service
line replacement
activities
have
taken place.
5675
5676
f)
Reporting
for public
education
program.
5677
5678
1)
Any
water supplier
that
is subject to
the
public
education
requirements
in
5679
Section
611.355
must,
within
ten
days after
the end of
each period
in
5680
which
the supplier
is required
to perform
public
education
tasks in
5681
accordance
with
Section
61 1.355(b)611.355(c),
send written
5682
documentation
to the
Agency
that
contains
the
following:
5683
5684
A)
A
demonstration
that
the
supplier
has
delivered
the public
5685
education
materials
that meet
the
content
requirements
in
5686
SectionSections
611.355(a)
and
(b) and the
delivery
requirements
5687
in
Section
611.355(b)611.355(c);
and
5688
5689
B)
A list of all
the
newspapers,
radio
stations,
television
stations,
and
5690
facilities
and
organizations
to
which the
supplier
delivered
public
5691
education
materials
during
the period
in which
the supplier
was
5692
required
to perform
public
education
tasks.
5693
5694
2)
Unless
required
by the
Agency,
by a SEP
issued pursuant
to Section
5695
611.110, a
supplier
that
previously
has
submitted
the information
required
5696
by subsection
(f)(1)(B)
of this
Section need
not resubmit
the information
5697
required
by subsection
(f)(1)(B)
of this
Section, as
long
as
there have
been
5698
no
changes
in the distribution
list
and the
supplier certifies
that
the public
5699
education
materials
were
distributed
to
the same list
submitted
previously.
5700
5701
)
No later
than three
months
following
the
end
of
the
monitoring
period,
5702
each
supplier must
mail a
sample
copy
of the consumer
notification
of
tap
5703
results
to the
Agency,
along
with
a
certification
that the notification
has
5704
been
distributed
in a
manner
consistent
with
the
requirements
of Section
5705
611.355(d).
JCAR35O61 1-0814065r01
5706
5707
g)
Reporting
of
additional
monitoring
data. Any supplier
that
collects
sampling data
5708
in
addition to that
required
by
this
Subpart
G
must
report the results
of
that
5709
sampling
to the
Agency
within
the first
ten
days following the end
of the
5710
applicable
sampling
periods
specified by Sections
611.356
through 611.358
5711
during which
the samples are
collected.
5712
5713
h)
Reporting
of 90th percentile
lead and copper
concentrations
where
the Agency
5714
calculates a
system’s 90th
percentile
concentrations.
A water
supplier is
not
5715
required
to report the 90th
percentile
lead
and
copper concentrations
measured
5716
from among
all
lead and
copper tap
water
samples collected
during
each
5717
monitoring
period, as required
by subsection
(a)(1)(D)
of
this
Section if the
5718
following
is
true:
5719
5720
1)
The
Agency has previously
notified the
water supplier
that
it will calculate
5721
the water
system’s
90
th
percentile lead
and copper concentrations,
based
on
5722
the lead
and copper tap results
submitted
pursuant
to
subsection (h)(2)(A)
5723
of this Section,
and
has
specified a date
before the end of
the applicable
5724
monitoring
period by which
the supplier
must
provide
the results of lead
5725
and copper
tap
water
samples;
5726
5727
2)
The
supplier has provided
the following
information
to the Agency by
the
5728
date
specified
in
subsection (h)(1)
of this Section:
5729
5730
A)
The results
of all
tap samples
for lead and
copper including
the
5731
location
of each site and
the criteria under
Section 611
.356(a)(3),
5732
(a)(4), (a)(5),
(a)(6), or
(a)(7)
under which
the site was selected
for
5733
the system’s
sampling pool,
pursuant to
subsection
(a)(1)(A)
of this
5734
Section;
and
5735
5736
B)
An identification
of sampling
sites utilized
during the current
5737
monitoring
period that were
not
sampled
during
previous
5738
monitoring
periods, and
an
explanation why
sampling
sites
have
5739
changed; and
5740
5741
3)
The Agency has provided
the results
of the
90
th
percentile lead and copper
5742
calculations,
in writing,
to
the
water supplier before
the end of the
5743
monitoring
period.
5744
5745
BOARD NOTE: Derived
from 40
CFR 141.90
(2007), as amended at
72 Fed. Reg.
57782
5746
(October 10, 2007)(2003).
5747
5748
(Source:
Amended at 32
Ill.
Reg.
effective
JCAR35O61
1-0814065r01
5749
5750
SUBPART
I: DISINFECTANT
RESIDUALS,
DISINFECTION
5751
BYPRODUCTS,
AND
DISINFECTION
BYPRODUCT
PRECURSORS
5752
5753
Section
611.381
Analytical
Requirements
5754
5755
a)
A
supplier
must
use
only
the analytical
methods
specified
in
this Section
or their
5756
equivalents
as approved
by the
Agency
to
demonstrate compliance
with
the
5757
requirements
of
this Subpart
I
and with
the requirements
of
Subparts
W and
Y of
5758
this
Part.
5759
5760
b)
Disinfection
byproducts
(DBPs).
5761
5762
1)
A
supplier
must
measure
disinfection
byproducts
(DBPs)
by
the
appropriate
5763
of the
following
methods:
5764
5765
A)
TTHM:
5766
5767
i)
By
purge and
trap,
gas chromatography,
electrolytic
5768
conductivity
detector,
and
photoionization
detector:
5769
USEPA
Organic
Methods,
Method
502.2.
If TTHMs
are
5770
the
only
analytes
being
measured
in the
sample,
then
a
5771
photoionization
detector
is not
required.
5772
5773
ii)
By purge
and trap,
gas
chromatography,
mass
5774
spectrometer:
USEPA
Organic
Methods,
Method
524.2.
5775
5776
iii)
By
liquid-liquid
extraction,
gas
chromatography,
electron
5777
capture
detector:
USEPA
Organic
Methods,
Method
551.1.
5778
5779
B)
HAA5:
5780
5781
i)
By
liquid-liquid
extraction
(diazomethane),
gas
5782
chromatography,
electron
capture
detector:
Standard
5783
Methods,
19
th
or
21st
ed.,
Method
6251
B.
5784
5785
BOARD
NOTE:
On
January
4,
2006
(at
71
Fed. Reg.
5786
388),
USEPA
amended
the
entry
for
HAA5
by
liquid-liquid
5787
extraction
(diazomethane),
gas
chromatography,
electron
5788
capture
detector,
in the
table
at
corresponding
40
CFR
5789
141.13
1(b)(1)
to allow
the
use of
Standard
Methods
Online
5790
(at
www.standardmethods.org),
Method
6251
B
(as
5791
approved
in
1994).
The
Board
has
instead
cited
to the
21
st
JCAR35O61
1-0814065r01
5792
edition
of Standard
Methods
for
the Examination
of
Water
5793
and Wastewater
(the
printed
version of
Standard
Methods),
5794
since the
version of
Method
6251 that appears
in
that
5795
printed
volume
is that cited
by
USEPA
as acceptable
for
5796
use.
USEPA
later
added
Method 6251
B from
the
21st
5797
edition
of
Standard
Methods
as an
approved
alternative
5798
method
in appendix
A
to
subpart
C,
added on
June
3,
2008
5799
(at
73 Fed.
Reg.
31616).
5800
5801
ii)
By
solid
phase
extractor
(acidic methanol),
gas
5802
chromatography,
electron
capture
detector:
USEPA
5803
Organic
Methods,
Method
552.1.
5804
5805
iii)
By liquid-liquid
extraction
(acidic
methanol),
gas
5806
chromatography,
electron
capture
detector:
USEPA
5807
Organic
Methods,
Method
552.2
or
552.3.
5808
5809
C)
Bromate:
5810
5811
i)
By ion
chromatography:
USEPA
Organic
and Inorganic
5812
Methods,
Method
300.1.
5813
5814
ii)
By
ion chromatography
and post-column
reaction:
USEPA
5815
OGWDW
Methods,
Method
317.0,
rev 2.0,
or
326.0, rev.
5816
1.0.
5817
5818
iii)
By
inductively-coupled
plasma—/mass
spectrometer:
5819
USEPA
Organic
and Inorganic
Methods,
Method
321.8.
5820
5821
BOARD
NOTE:
Ion
chromatography
and
post column
reaction
or
5822
inductively-coupled
plasma—/mass
spectrometry
must
be used
for
5823
monitoring
of
bromate
for purposes
of
demonstrating
eligibility
of
5824
reduced
monitoring,
as prescribed
in Section
611 .382(b)(3)(B).
5825
For
inductively-coupled
plasma—/mass
spectrometry,
samples
5826
must
be preserved
at
the time of
sampling
with 50 mg
5827
ethylenediamine
(EDA)
per liter
of sample,
and
the
samples must
5828
be analyzed
within
28
days.
5829
5830
D)
Chlorite:
5831
5832
i)
By amperometric
titration:
Standard
Methods,
19
th
or
21
st
5833
ed., Method
4500-C1O
2
E.
5834
JCAR35O61
1-0814065r01
5835
BOARD
NOTE:
On January
4,
2006
(at
71 Fed.
Reg.
5836
388),
USEPA
amended
the
entry
for chlorite
by
5837
amperometric
titration,
in the
table
at
corresponding
40
5838
CFR
141.23(k)(1)
to
allow
the
use
of Standard
Methods
5839
Online
(at
www.standardmethods.org),
Method
4500-C1O
2
5840
E
(as
approved
in
2000).
The
Board
has instead
cited
to the
5841
21St
edition
of
Standard
Methods
for the
Examination
of
5842
Water and
Wastewater
(the printed
version
of Standard
5843
Methods),
since
the
version
of Method
4500-C1O
2
that
5844
appears
in that
printed
volume
is that
cited
by
USEPA
as
5845
acceptable
for
use.
USEPA
later
added
Method
4500-C1O
9
5846
E from
the
2lS
edition
of Standard
Methods
as an approved
5847
alternative
method
in
appendix
A
to subpart
C,
added
on
5848
June
3,2008
(at
73 Fed.
Reg.
31616).
5849
5850
ii)
By
spectrophotometry:
USEPA
OGWDW
Methods,
5851
Method
327.0,
rev.
1.1.
5852
5853
iii)
By
ion chromatography:
USEPA
Environmental
Inorganic
5854
Methods,
Method
300.0;
USEPA
Organic
and
Inorganic
5855
Methods,
Method
300.1;
USEPA
OGWDW
Methods,
5856
Method
317.0,
rev.
2.0,
or
326.0,
rev.
1.0; or
ASTM
5857
Method
D6581-00.
5858
5859
BOARD
NOTE:
Amperometric
titration
or
spectrophotometry
5860
may
be used
for routine
daily
monitoring
of chlorite
at
the
entrance
5861
to
the
distribution
system,
as
prescribed
in
Section
5862
611
.382(b)(2)(A)(i).
Ion chromatography
must
be used
for
routine
5863
monthly
monitoring
of
chlorite
and
additional
monitoring
of
5864
chlorite
in
the
distribution
system,
as prescribed
in Section
5865
611.3 82(b)(2)(A)(ii)
and (b)(2)(B).
5866
5867
2)
Analyses
under
this Section
for DBPs
must
be
conducted
by
laboratories
5868
that
have
received
certification
by USEPA
or
the Agency
except
as
5869
specified
under subsection
(b)(3)
of
this Section.
To
receive
certification
5870
to
conduct
analyses
for
the DBP
contaminants
listed
in Sections
611.312
5871
and
611.381
and
Subparts
W
and Y
of this Part,
the laboratory
must
fulfill
5872
the
requirements
of subsections
(b)(2)(A),
(b)(2)(C),
and
(b)(2)(D)
of this
5873
Section.
5874
5875
A)
The
laboratory
must
analyze
performance
evaluation
(PE)
samples
5876
that
are
acceptable
to
USEPA
or
the
Agency
at
least
once
during
5877
each
consecutive
12-month
period
by
each
method
for
which
the
5878
laboratory
desires
certification.
JCAR35O61
1-0814065r01
5879
5880
B)
This subsection
corresponds
with 40 CFR
141.131 (b)(2)(ii),
which
5881
has expired
by its own
terms.
This
statement maintains structural
5882
consistency
with
the
corresponding federal
rule.
5883
5884
C)
The
laboratory
must
achieve
quantitative
results
on the
PE sample
5885
analyses that are
within the acceptance
limits
set
forth in
5886
subsections
(b)(2)(C)(i)
through
(b)(2)(B)(xi)
of this
Section,
5887
subject to
the
conditions of subsections
(b)(2)(C)(xii)
and
5888
(b)(2)(C)(xiii) of
this
Section:
5889
5890
i)
Chloroform
(a
THM):
± 20% of true value;
5891
5892
ii)
Bromodichloromethane
(a THM):
± 20% of
true value;
5893
5894
iii)
Dibromochloromethane
(a THM):
± 20% of
true
value;
5895
5896
iv)
Bromoform (a
THM): + 20% of
true value;
5897
5898
v)
Monochloroacetic
Acid
(an HAA5):
± 40% of
true value;
5899
5900
vi)
Dichloroacetic
Acid
(an HAA5):
± 40% of true
value;
5901
5902
vii)
Trichloroacetic
Acid (an
HAA5):
±
40% of
true
value;
5903
5904
viii)
Monobromoacetic
Acid
(an HAA5):
± 40% of true value;
5905
5906
ix)
Dibromoacetic
Acid (an
HAA5):
±
40% of true value;
5907
5908
x)
Chlorite:
± 30% of true
value; and
5909
5910
xi)
Bromate:
±
30% of true
value.
5911
5912
xii)
The laboratory
must meet all
four of the individual
THM
5913
acceptance limits
set forth in
subsections
(b)(2)(B)(i)
5914
through (b)(2)(B)(iv)
of
this Section in order
to
5915
successfully
pass a PE sample
for
TTHM.
5916
5917
xiii)
The laboratory
must
meet
the acceptance
limits for four
out
5918
of
the five HAA5 compounds
set forth
in subsections
5919
(b)(2)(B)(v)
through
(b)(2)(B)(ix)
of this Section in order
to
5920
successfully
pass
a PB sample for HAA5.
5921
JCAR35O61
1-0814065r01
5922
D)
The laboratory must report
quantitative
data for concentrations
at
5923
least
as low as
the
minimum reporting
levels (MRLs)
listed in
5924
subsections (b)(2)(D)(i)
through (b)(2)(D)(xi)
of this Section,
5925
subject to the limitations
of subsections
(b)(2)(D)(xii)
and
5926
(b)(2)(D)(xiii)
of this Section,
for all DBP samples
analyzed
for
5927
compliance with
Sections 611.3
12 and
611.385
and
Subparts
W
5928
and Y of this
Part:
5929
5930
i)
Chloroform
(a THM):
0.0010
mg!e;
5931
5932
ii)
Bromodichloromethane
(a THM): 0.00 10
mg!e;
5933
5934
iii)
Dibromochloromethane
(a THM): 0.0010
mg!;
5935
5936
iv)
Bromoform
(a THM): 0.0010
mgJi;
5937
5938
v)
Monochloroacetic
Acid (an
HAA5): 0.0020 mg/i;
5939
5940
vi)
Dichloroacetic
Acid (an HAA5):
0.00 10 mg!e;
5941
5942
vii)
Trichloroacetic
Acid (an HAA5):
0.00 10
mg/i;
5943
5944
viii)
Monobromoacetic
Acid
(an HAA5): 0.0010
mg/i;
5945
5946
ix)
Dibromoacetic
Acid
(an HAA5): 0.0010
mg/€;
5947
5948
x)
Chlorite:
0.020
mg!€,
applicable
to monitoring as required
5949
by
Section
61 1.382(b)(2)(A)(ii)
and
(b)(2)(B); and
5950
5951
xi)
Bromate:
0.0050,
or 0.00 10 mg/f’ if
the laboratory uses
5952
USEPA
OGWDW
Methods, Method 317.0,
rev. 2.0,
or
5953
326.0
or USEPA Organic
and
Inorganic
Methods, Method
5954
321.8.
5955
5956
xii)
The calibration
curve
must encompass the
regulatory MRL
5957
concentration.
Data may
be
reported
for concentrations
5958
lower
than
the regulatory
MRL as long as
the precision
and
5959
accuracy
criteria
are met by analyzing
an MRL check
5960
standard at the lowest
reporting
limit chosen by the
5961
laboratory.
The
laboratory must verify
the accuracy
of the
5962
calibration
curve at the MRL concentration
by analyzing
an
5963
MRL check
standard with a
concentration less than
or
5964
equal to
110%
of the MRL with
each batch of
samples.
JCAR35O61
1-0814065r01
5965
The
measured
concentration
for
the
MRL
check
standard
5966
must
be ±50%
of the expected
value,
if any
field sample
in
5967
the
batch
has
a concentration
less
than five
times the
5968
regulatory
MRL.
Method
requirements
to analyze
higher
5969
concentration
check
standards
and
meet tighter
acceptance
5970
criteria
for them must
be
met
in addition
to the MRL
check
5971
standard
requirement.
5972
5973
xiii)
When
adding
the
individual
trihalomethane
or haloacetic
5974
acid concentrations,
for
the
compounds
listed in
5975
subsections
(b)(2)(D)(v)
through
(b)(2)(D)(ix)
of
this
5976
Section,
to calculate
the TTHM
or
HAA5
concentrations,
5977
respectively,
a zero
is
used
for any
analytical
result
that
is
5978
less
than
the
MRL
concentration
for that
DBP, unless
5979
otherwise
specified
by the Agency.
5980
5981
3)
A
party approved
by
USEPA
or the
Agency
must
measure
daily chlorite
5982
samples
at the
entrance
to
the
distribution
system.
5983
5984
c)
Disinfectant
residuals.
5985
5986
1)
A
supplier
must measure
residual
disinfectant
concentrations
for free
5987
chlorine,
combined chlorine
(chioramines),
and chlorine
dioxide
by the
5988
appropriate
of the
methods
listed
in subsections
(c)(l)(A)
through
(c)(1)(D)
5989
of this Section,
subject
to
the provisions
of
subsection
(c)(l)(E) of
this
5990
Section:
5991
5992
A)
Free Chlorine:
5993
5994
i)
Amperometric
titration using
Standard
Methods,
19
th, 20
th
5995
or
21
st
ed.,
Method
4500-Cl
D, or
ASTM
Method
1253-86,
5996
1253-96,
or 1253-03;
5997
5998
ii)
DPD ferrous
titration
using
Standard
Methods,
19
th, 20
th
or
5999
21
st
ed.,
Method
4500-Cl
F;
6000
6001
iii)
DPD
colorimetric
using
Standard
Methods,
19th1,
20
th
or
6002
21st
ed.,
Method 4500-Cl
G; or
6003
6004
iv)
Syringaldazine
(FACTS)
using Standard
Methods,
19
th,
6005
20
th
or
21st
ed., Method
4500-Cl
H.
6006
6007
B)
Combined
Chlorine:
6008
JCAR35O61
l-0814065r01
6009
i)
Amperometric
titration
using
Standard Methods,
19
th,
20
th
6010
or
21st
ed.,
Method 4500-Cl
D, or
ASTM
Method
1253-86,
6011
1253-96,
or
1253-03;
6012
6013
ii)
DPD ferrous
titration
using
Standard
Methods,
19
th,
20
th
or
6014
21st
ed.,
Method
4500-Cl
F; or
6015
6016
iii)
DPD
colorimetric
using
Standard
Methods,
19tl,
20
th
or
6017
21st
ed., Method
4500-Cl
G.
6018
6019
C)
Total
Chlorine:
6020
6021
i)
Amperometric
titration
using
Standard
Methods,
19
th,
20
th,
6022
or
21st
ed., Method
4500-Cl
D, or
ASTM
Method
1253-86,
6023
1253-96,
or
1253-03;
6024
6025
ii)
Low-level
amperometric
titration
using
Standard Methods,
6026
19
th
20
th
or
21st
ed.,
Method
4500-Cl
E;
6027
6028
iii)
DPD ferrous
titration
using
Standard
Methods,
19t1,
20
th
or
6029
21st
ed.,
Method 4500-Cl
F;
6030
6031
iv)
DPD colorimetric
using
Standard Methods,
19th,
20
th
or
6032
21st
ed.,
Method
4500-Cl
G;
or
6033
6034
v)
Jodometric
electrode
using
Standard
Methods,
l9,
20
th,
or
6035
2l5t
ed.,
Method
4500-Cl
I.
6036
6037
D)
Chlorine Dioxide:
6038
6039
i)
DPD
using Standard
Methods,
19th,
20
th
or
21st
ed.,
6040
Method
4500-C10
2
D;
6041
6042
ii)
Amperometric
Method
II
using Standard
Methods,
l9tI,
6043
20
th
or
21st
ed.,
Method
4500-Cl0
2
E; or
6044
6045
iii)
Lissamine
Green
spectrophotometric
using
USEPA
6046
OGWDW
Method
327.0
(rev. 1.1).
6047
6048
E)
The methods
listed
are approved
for
measuring
the
specified
6049
disinfectant
residual.
The supplier
may
measure
free chlorine
or
6050
total chlorine
for
demonstrating
compliance
with
the chlorine
JCAR35O61
1-0814065r01
6051
MRDL
and
combined
chlorine,
or
total
chlorine
may be
measured
6052
for
demonstrating
compliance
with the
chioramine
MRDL.
6053
6054
BOARD
NOTE:
On January
4, 2006
(at 71
Fed.
Reg.
388),
USEPA
6055
amended
the
entries
for
free
chlorine,
combined
chlorine,
and
chlorine
6056
dioxide
in
the table
at corresponding
40
CFR
141.23(k)(1)
to
allow
the use
6057
of
Standard
Methods
Online
(at
www.standardmethods.org),
Method
6058
4500-Cl
D, E,
F,
0, H,
or I or
Method
4500-dO
2
E
(as
approved
in
2000).
6059
The
Board
has
instead
cited to
the
21st
edition
of Standard
Methods
for
the
6060
Examination
of Water
and
Wastewater
(the
printed
version
of
Standard
6061
Methods),
since
the versions
of
Method
4500-Cl
and
Method
4500-C10
2
6062
that
appear
in that
printed
volume
is that
cited
by
USEPA
as
acceptable
6063
for
use.
USEPA
later
added
Method
4500-Cl
D,
F,
F, G, H,
or I
or
6064
Method
4500-C10
2
E from
the
21st
edition
of
Standard
Methods
as an
6065
approved
alternative
method
in appendix
A
to
subpart
C, added
on June
3,
6066
2008
(at
73
Fed. Reg.
31616).
6067
6068
2)
Test
strips.
6069
6070
ITS
Method
D99-003.
6071
6072
BOARD
NOTE:
USEPA
added
ITS Method
D99-003
as
an
6073
approved
alternative
method
in
appendix
A
to subpart
C,
added
on
6074
June
3, 2008
(at
73
Fed.
Reg.
31616).
6075
6076
)
If
approved
by
the
Agency,
a
supplier
may
also measure
residual
6077
disinfectant
concentrations
for
chlorine,
chloramines,
and chlorine
6078
dioxide
by using
DPD
colorimetric
test
kits.
6079
6080
3)
A
party
approved
by
USEPA
or
the
Agency
must
measure
residual
6081
disinfectant concentration.
6082
6083
d)
A
supplier
required
to analyze
parameters
not
included
in subsections
(b)
and
(c) of
6084
this
Section
must
use the
methods
listed
below.
A
party
approved
by
USEPA
or
6085
the
Agency
must
measure
the following
parameters:
6086
6087
6088
1)
Alkalinity.
All methods
allowed
in
Section
611.61
1(a)(21)
for
measuring
6089
alkalinity.
6090
6091
2)
Bromide:
6092
6093
A)
USEPA
Inorganic
Methods,
Method
300.0;
JCAR35061
1-0814065r01
6094
6095
B)
USEPA
Organic
and
Inorganic
Methods,
Method
300.1;
6096
6097
C)
USEPA
OGWDW
Methods,
Method
317.0 (rev.
2.0) or
Method
6098
326.0
(rev. 1.0);
or
6099
6100
D)
ASTM Method
D6581-00.
6101
6102
3)
Total
Organic
Carbon
(TOC),
by any
of the methods
listed
in subsection
6103
(d)(3)(A)(i),
(d)(3)(A)(ii),
(d)(3)(A)(iii),
or (d)(3)(B)
of this
Section, subject
6104
to the
limitations
of
subsection
(d)(3)(C)
of this
Section:
6105
6106
A)
Standard
Methods,
19
th,
20
th
or
21
st
ed., using
one of
the following
6107
methods:
6108
6109
i)
Method
5310
B
(High-Temperature
Combustion
Method);
6110
6111
ii)
Method 5310
C
(Persulfate-Ultraviolet
or Heated-
6112
Persulfate
Oxidation
Method);
or
6113
6114
iii)
Method
5310 D (Wet-Oxidation
Method).
6115
6116
BOARD
NOTE:
On
January
4,
2006 (at
71
Fed. Reg.
388),
6117
USEPA
amended
the entries
for
total organic
carbon,
high-
6118
temperature
combustion,
persulfate-ultraviolet
or
heated persulfate,
6119
and
wet
oxidation
at
corresponding
40
CFR
141.13
1(d)(3)
to
allow
6120
the use of
Standard Methods
Online
(at
ww.standardmethods.org),
6121
Method
5310 B, C,
or D
(as
approved
in
2000). The
Board
has
6122
instead cited
to the
21
st
edition
of Standard
Methods
for the
6123
Examination
of
Water
and Wastewater
(the
printed
version of
6124
Standard
Methods),
since
the
version
of
Method
5310
B,
C,
or D
6125
that
appears
in that printed
volume
is that
cited
by USEPA
as
6126
acceptable
for use. USEPA
later
added Method
5310
B,
C, or
D
6127
from
the
21
St
edition of
Standard
Methods
as
an
approved
6128
alternative
method
in
appendix
A to subpart
C,
added
on June
3,
6129
2008
(at
73 Fed.
Reg. 31616).
6130
6131
B)
USEPA
NERL
Method
415.3
(rev. 1.1).
6132
6133
C)
Inorganic
carbon
must
be removed
from
the
samples
prior
to
6134
analysis.
TOC
samples
may
not
be
filtered
prior
to analysis.
TOC
6135
samples
must be
acidified
at the time
of
sample
collection
to
6136
achieve
pH less than
or
equal to 2
with minimal
addition
of the
JCAR35O61 1-0814065r01
6137
acid
specified
in
the
method
or
by the
instrument
manufacturer.
6138
Acidified
TOC
samples
must
be
analyzed
within
28 days.
6139
6140
4)
Specific
Ultraviolet
Absorbance
(SUVA).
SUVA
is equal
to the
UV
6141
absorption
at 254
nm
(TiV
254
)
(measured
in
m’)
divided
by
the
dissolved
6142
organic
carbon
(DOC)
concentration
(measured
as
mg/E).
In
order
to
6143
determine
SUVA,
it
is necessary
to separately
measure
UV
254
and DOC.
6144
When
determining
SUVA,
a
supplier
must
use
the
methods
stipulated
in
6145
subsection
(d)(4)(A)
of this
Section
to
measure
DOC
and
the
method
6146
stipulated
in
subsection
(d)(4)(B) of
this Section
to
measure
UV
254
.
SUVA
6147
must
be determined
on
water
prior
to
the addition
of
disinfectants/oxidants
6148
by
the
supplier.
DOC
and
254
UV
samples
used
to
determine
a SUVA
value
6149
must
be taken
at
the
same
time
and
at
the
same
location.
6150
6151
A)
Dissolved
Organic
Carbon
(DOC).
Standard
Methods,
19
th
ed.,
20
th
6152
ed.,
or
21st
ed.,
Method
5310
B
(High-Temperature
Combustion
6153
Method),
Method
5310
C
(Persulfate-Ultraviolet
or Heated-
6154
Persulfate
Oxidation
Method),
or
Method
5310
D
(Wet-Oxidation
6155
Method)
or
USEPA
NERL
Method
415.3
(rev.
1.1).
Prior
to
6156
analysis,
DOC
samples
must
be filtered
through
the
0.45
pm
6157
pore-diameter
filter
as
soon
as practical
after
sampling,
not
to
6158
exceed
48
hours.
After
filtration,
DOC
samples
must
be
acidified
6159
to
achieve
pH
less
than
or equal
to 2
with
minimal
addition
of
the
6160
acid specified
in
the method
or by
the
instrument
manufacturer.
6161
Acidified
DOC
samples
must
be
analyzed
within
28 days
after
6162
sample
collection.
Inorganic
carbon
must
be
removed
from
the
6163
samples
prior
to
analysis.
Water
passed
through
the
filter
prior
to
6164
filtration
of
the
sample
must
serve
as
the
filtered
blank.
This
filtered
6165
blank
must
be analyzed using
procedures
identical to those
used
for
6166
analysis
of
the samples
and
must
meet
the following standards:
6167
DOC
less
than
0.5 mg/e;
and
6168
6169
BOARD
NOTE:
On
January
4, 2006
(at
71
Fed.
Reg.
388),
6170
USEPA
amended
the
entries
for
specific
ultraviolet
absorbance
6171
dissolved
organic
carbon
at
corresponding
40
CFR
6172
141.131(d)(4)(i)
to
allow
the
use
of Standard Methods
Online
(at
6173
www.standardmethods.org),
Method
5310
B,
C,
or
D (as
approved
6174
in 2000).
The
Board
has
instead
cited
to the
21st
edition
of
6175
Standard
Methods
for
the
Examination
of
Water
and
Wastewater
6176
(the
printed
version
of Standard Methods),
since
the version
of
6177
Method
5310
B, C,
or D
that
appears
in that
printed
volume
is
that
6178
cited
by
USEPA
as
acceptable
for
use.
USEPA later
added
6179
Method
5310
B,
C,
or D
from
the
21st
edition
of Standard
Methods
JCAR35O61 1-0814065r01
6180
as an approved alternative
method
in appendix
A
to
subpart
C,
6181
added on June
3, 2008 (at 73 Fed.
Reg. 31616).
6182
6183
B)
Ultraviolet Absorption
at 254
nm (TJV
254
).Method
5910 B
6184
(Ultraviolet
Absorption
Method).
UV absorption
must be
measured
6185
at 253.7 nm
(maybe rounded
off to 254
nm). Prior to analysis,
6186
UV
254 samples must
be filtered
through
a
0.45
im pore-diameter
6187
filter. The
pH
of 254
UV samples may
not be adjusted.
Samples
6188
must
be analyzed
as soon
as practical
after sampling,
not to exceed
6189
48
hours; and
6190
6191
BOARD
NOTE:
On January 4, 2006
(at
71 Fed.
Reg.
388),
6192
USEPA
amended
the entries for specific
ultraviolet
absorbance
6193
ultraviolet
absorption
at 254 nm
at
corresponding 40 CFR
6194
141.131(d)(4)(ii)
to allow
the use of Standard
Methods
Online
(at
6195
www.standardmethods.org),
Method
5910 B
(as
approved
in
6196
2000).
The Board has instead
cited to the
21St
edition
of Standard
6197
Methods
for the Examination
of Water
and Wastewater (the
6198
printed
version of Standard
Methods),
since
the version
of Method
6199
5910 B that
appears in
that printed
volume is that cited
by
USEPA
6200
as acceptable
for use.
USEPA later added
Method 5910
B from
6201
the
21
St
edition of Standard
Methods
as an approved alternative
6202
method
in
appendix
A to subpart
C, added on June 3,
2008
(at
73
6203
Fed.
Reg.
31616).
6204
6205
5)
pH. All
methods allowed
in Section 611.61
1(a)(17)
for measuring
pH.
6206
6207
6)
Magnesium.
All
methods
allowed in
Section 6 11.611(a)
for measuring
6208
magnesium.
6209
6210
BOARD
NOTE:
Derived
from 40 CFR
141.13
1
(2007)
and
appendix
A
to 40 CFR 141,
6211
as
added at 73 Fed. Reg.
31616
(June
3, 2008)(2006).
6212
6213
(Source:
Amended at 32
Ill. Reg.
effective
6214
6215
SUBPART L:
MICROBIOLOGICAL
MONITORING
AND
6216
ANALYTICAL
REQUIREMENTS
6217
6218
Section 611.526
Analytical Methodology
6219
6220
a)
The standard
sample volume
required
for total coliform
analysis, regardless
of
6221
analytical
method
used,
is 100 m.
6222
6223
b)
Suppliers
need
only
determine the
presence or absence
of total coliforms;
a
JCAR35O61
1-0814065r01
6224
determination
of total
coliform
density is
not required.
6225
6226
c)
Suppliers
must conduct
total
coliform
analyses
in accordance
with one
of the
6227
following
analytical
methods,
incorporated
by
reference
in
Section
611.102
(the
6228
time from
sample
collection
to initiation
of analysis
may
not
exceed
30
hours,
and
6229
the
supplier
is encouraged
but not
required to
hold samples
below
100
C
during
6230
transit):
6231
6232
1)
Total Coliform
Fermentation
Technique,
as set
forth in Standard
Methods,
6233
18
th,
19
th
20
th
or
21
st
ed.:
Methods
9221
A and B,
as
follows:
6234
6235
A)
Lactose
broth, as commercially
available,
may be used
in lieu
of
6236
lauryl tryptose
broth
if the supplier
conducts
at least
25 parallel
6237
tests
between
this
medium
and
lauryl
tryptose
broth
using the
6238
water
normally
tested
and this comparison
demonstrates
that
the
6239
false-positive
rate
and false-negative
rate
for
total
coliforms,
using
6240
lactose
broth,
is
less than
10 percent;
6241
6242
B)
If inverted
tubes
are
used
to detect
gas production,
the
media
6243
should
cover
these tubes
at least
one-half
to
two-thirds
after the
6244
sample is
added; and
6245
6246
C)
No
requirement
exists
to run
the completed
phase
on 10 percent
of
6247
all total
coliform-positive
confirmed
tubes.
6248
6249
2)
Total
Coliform
Membrane
Filter
Technique,
as set forth
in Standard
6250
Methods,
18
th
19
th
20
th
or
21st
ed.:
Methods
9222 A,
B, and
C.
6251
6252
3)
Presence-Absence
(P-A)
Colifonn
Test, as
set forth
in: Standard
Methods,
6253
18
th 19
th
20
th
or
21st
ed.:
Method
9221
D,
as
follows:
6254
6255
A)
No requirement
exists
to run the
completed
phase
on 10 percent
of
6256
all
total
colifonn-positive
confirmed
tubes;
and
6257
6258
B)
Six-times
formulation
strength
may be
used if the
medium is
filter-
6259
sterilized
rather than
autoclaved.
6260
6261
4)
ONPG-MUG
test:
Standard
Methods,
1
gth
19
th
20
th
or
21
st
ed.:
6262
Method
9223.
(The ONPG-MJJG
test
is
also
known as the
Autoanalysis
6263
Colilert
Systemj
6264
6265
5)
Colisure
Test
(Autoanalysis
Colilert
System).
(The
Colisure
Test may be
6266
read
after
an incubation
time of
24
hours.)
JCAR35O61
1-0814065r01
6267
6268
BOARD
NOTE:
USEPA
included
the P-A
Coliform and
Colisure
Tests
6269
for
testing
finished
water
under
the
coliform
rule,
but did
not
include
them
6270
for the
purposes
of the
surface
water
treatment
rule,
under
Section
6271
611.531,
for which
quantitation
of total coliforms
is
necessary.
For these
6272
reasons,
USEPA
included
Standard
Methods:
Method
9221
C
for the
6273
surface
water
treatment
rule, but
did not include
it
for
the purposes
of
the
6274
total
coliform
rule,
under
this
Section.
6275
6276
6)
E*Colite®
Test (Charm
Sciences,
Inc.).
6277
6278
7)
m-ColiBlue24®
Test
(Hatch
Company).
6279
6280
8)
Readycult
Coliforms
100 Presence/Absence
Test.
6281
6282
9)
Membrane
Filter
Technique
using
Chromocult
Coliform
Agar.
6283
6284
10)
Colitag®
Test.
6285
6286
BOARD
NOTE:
On
March 12,
2007
(at
72
Fed. Reg.
11200),
USEPA amended
6287
note 1 to the
table at
corresponding
40
CFR
141.21(f)(3)
to
allow the use
of
6288
Standard
Methods
Online
(at
www.standardmethods.org),
Method
9221
A, B, and
6289
D
(as
approved
in
1999)
or
Method
9222
A, B, and
C
(as
approved
in 1997);
and
6290
9223
B
(as approved
in
1997).
The Board
has
cited
to the
21st
edition
of Standard
6291
Methods
for the
Examination
of
Water
and
Wastewater
(the
printed version
of
6292
Standard
Methods)
for Methods
9221
and 9223,
since
the
cited
versions
of
the
6293
methods
appears
in that reference.
USEPA
later
added
Method
9221
A, B, and
D;
6294
Method
9222
A,
B, and
C:
Method
9223
from
the
21
st
edition
of Standard
6295
Methods
as an approved
alternative
method
in
appendix
A
to
subpart
C, added
on
6296
June
3,
2008
(at
73 Fed. Reg.
31616).
6297
6298
d)
This
subsection
corresponds
with
40
CFR
141
.21(f)(4),
which
USEPA
has
6299
marked “reserved.”
This
statement
maintains
structural
consistency
with
the
6300
federal
regulations.
6301
6302
e)
Suppliers
must conduct
fecal
coliform analysis
in accordance
with the
following
6303
procedure:
6304
6305
1)
When the
MTF Technique
or P-A
Coliform
Test
is used to
test for total
6306
coliforms,
shake the
lactose-positive
presumptive
tube
or
P-A vigorously
6307
and
transfer
the
growth with
a sterile
3-mm
loop or
sterile applicator
stick
6308
into brilliant
green
lactose
bile
broth
and EC medium,
defined
below,
to
6309
determine
the
presence
of
total and
fecal
coliforms,
respectively.
JCAR35O61
1-0814065r01
6310
6311
2)
For approved
methods
that
use
a
membrane
filter,
transfer
the
total
6312
coliform-positive
culture
by
one
of the following
methods:
remove
the
6313
membrane
containing
the
total
coliform
colonies
from
the substrate
with
6314
sterile
forceps
and
carefully
curl
and
insert the
membrane
into
a
tube
of
6315
EC
medium;
(the
laboratory
may
first
remove
a small
portion
of
selected
6316
colonies
for verification);
swab
the entire
membrane
filter
surface
with a
6317
sterile
cotton
swab
and
transfer
the
inoculum
to
EC
medium
(do
not
leave
6318
the
cotton
swab
in the
EC medium);
or inoculate
individual
total
coliform
6319
positive
colonies
into
EC medium.
Gently
shake the
inoculated
tubes
of
6320
EC
medium
to
insure
adequate
mixing
and incubate
in a waterbath
at 44.5
6321
±0.2°
C for
24
±2
hours.
Gas
production
of
any
amount
in
the
inner
6322
fermentation tube
of the
EC medium
indicates
a
positive
fecal
coliform
6323
test.
6324
6325
3)
EC
medium
is described
in Standard
Methods,
18
th
ed.,
19
th
ed.,
and
20t
6326
ed.:
Method
9221E.
6327
6328
4)
Suppliers
need
only
determine
the
presence
or
absence
of fecal
coliforms;
6329
a
determination
of
fecal
colifonn
density
is not
required.
6330
6331
f)
Suppliers
must conduct
analysis
of
B.
coli in accordance
with
one
of the
following
6332
analytical
methods,
incorporated
by
reference
in Section
611.102:
6333
6334
1)
EC
medium
supplemented
with
50 ig!2
of
MUG
(final
concentration).
6335
EC medium
is
as described
in subsection
(e)
of this
Section.
MUG
may
6336
be
added
to
BC
medium
before
autoclaving.
BC
medium
supplemented
6337
with 50
g/e MUG
is
commercially
available.
At
least 10
m of
BC
6338
medium
supplemented
with
MUG
must
be
used.
The
inner
inverted
6339
fermentation
tube
may
be
omitted.
The
procedure
for transferring
a
total
6340
coliform-positive
culture
to EC
medium
supplemented
with
MUG
is as in
6341
subsection
(e) of
this
Section
for
transferring
a
total colifonn-positive
6342
culture
to
EC
medium.
Observe
fluorescence
with
an ultraviolet
light
(366
6343
nm)
in
the
dark after
incubating
tube at
44.5 ±2°
C
for
24 ±2
hours;
or
6344
6345
2)
Nutrient
agar
supplemented
with
100 ug/e
MUG
(final
concentration),
as
6346
described
in Standard
Methods,
19
th
ed. and
20
th
ed.:
Method
9222
G.
6347
This
test
is
used
to
determine
if
a
total
coliform-positive
sample,
as
6348
determined
by
the MF
technique,
contains
B.
coli.
Alternatively,
Standard
6349
Methods,
l8t1
ed.: Method
9221
B
may be
used if
the
membrane
filter
6350
containing
a
total coliform-positive
colony
or
colonies
is
transferred
to
6351
nutrient
agar,
as described
in Method
9221
B (paragraph
3), supplemented
6352
with
100
Lg/2
MUG.
If
Method
9221
B is used,
incubate
the
agar
plate
at
JCAR35O61
l-0814065r01
6353
35°
Celsius
for four
hours,
then observe
the colony
or
colonies
under
6354
ultraviolet
light
(366-nm)
in the
dark
for fluorescence.
If fluorescence
is
6355
visible,
B. coli are
present.
6356
6357
3)
Minimal
Medium
ONPG-MIJG
(MMO-MUG)
Test,
as set forth
in
6358
Appendix
D of
this
Part.
(The Autoanalysis
Colilert
System
is a MMO
6359
MUG
test.) If
the MMO-MIJG
test
is total coliform
positive
after a
24-
6360
hour
incubation,
test the
medium
for fluorescence
with
a 366-nm
6361
ultraviolet
light
(preferably
with
a
six-watt lamp)
in the dark.
If
6362
fluorescence
is observed,
the
sample
is E.
coli-positive.
If
fluorescence
is
6363
questionable
(cannot
be
definitively
read) after
24 hours
incubation,
6364
incubate
the culture
for
an
additional
four hours
(but not to
exceed 28
6365
hours total),
and
again
test
the
medium
for
fluorescence.
The
MMO-MUG
6366
test
with
hepes
buffer is the
only approved
formulation
for
the detection
of
6367
E. coli.
6368
6369
4)
The Colisure
Test
(Autoanalysis
Colilert
System).
6370
6371
5)
The membrane
filter
method
with
MI agar.
6372
6373
6)
The
E*Colite®
Test.
6374
6375
7)
The
m-ColiBlue24®
Test.
6376
6377
8)
Readycult
Coliforms
100
Presence/Absence
Test.
6378
6379
9)
Membrane
Filter
Technique
using
Chromocult
Coliform
Agar.
6380
6381
10)
Colitag®
Test.
6382
6383
g)
As an option
to the method
set
forth in subsection
(f)(3) of
this Section,
a supplier
6384
with
a
total
coliform-positive,
MUG-negative,
MMO-MUG
test may
further
6385
analyze
the
culture for
the
presence
of E. coli
by transferring
a 0.1
m, 28-hour
6386
MMO-MUG
culture to
EC medium
+ MUG
with
a
pipet.
The formulation
and
6387
incubation
conditions
of the EC
medium
+
MUG, and
observation
of the results,
6388
are
described
in subsection
(f)(1)
of this Section.
6389
6390
h)
This
subsection
corresponds
with
40 CFR 141.21(f)(8),
a
central
listing of
all
6391
documents
incorporated
by
reference
into
the
federal
microbiological
analytical
6392
methods.
The
corresponding
Illinois incorporations
by
reference
are located
at
6393
Section
611.102.
This statement
maintains
structural
parity
with USEPA
6394
regulations.
6395
JCAR35061
1-0814065r01
6396
BOARD
NOTE:
Derived
from 40 CFR
141.21(f)
(2007)
and
appendix
A to
40 CFR 141,
6397
as added
at 73 Fed.
Reg.
31616
(June
3.
2008)(2003).
6398
6399
(Source:
Amended
at 32
ill. Reg.
effective
6400
6401
Section
611.531
Analytical
Requirements
6402
6403
The analytical
methods
specified
in this
Section
must
be
used to
demonstrate
compliance
with
6404
the requirements
of
only 61 1.Subpart
B; they do
not apply
to analyses
performed
for the
6405
purposes
of Sections
611.521
through
611.527 of
this
Subpart
L.
Measurements
for pH,
6406
temperature,
turbidity,
and RDCs
must
be
conducted
under
the supervision
of a
certified
6407
operator.
Measurements
for total
coliforms,
fecal
coliforms
and
HPC
must be conducted
by a
6408
laboratory
certified
by
the Agency
to do
such
analysis.
The
following
procedures
must be
6409
performed
by the
following
methods,
incorporated
by reference
in Section
611.102:
6410
6411
a)
A
supplier
shall
do as follows:
6412
6413
1)
Conduct
analyses
of pH
in accordance
with
one
of
the
methods
listed
at
6414
Section 611.611;
and
6415
6416
2)
Conduct
analyses
of total coliforms,
fecal
coliforms,
heterotrophic
6417
bacteria,
and
turbidity
in accordance
with one of
the following
methods,
6418
and
by
using analytical
test procedures
contained
in USEPA
Technical
6419
Notes,
incorporated
by
reference
in Section
611.102,
as follows:
6420
6421
A)
Total
Coliforms.
6422
6423
BOARD
NOTE:
The
time
from sample
collection
to initiation
of
6424
analysis
for source
(raw)
water
samples
required
by Sections
6425
611.521
and
611.532
and
Subpart B
of this
Part
only
must
not
6426
exceed
eight
hours.
The supplier
is encouraged
but
not required
to
6427
hold samples
below
100
C
during
transit.
6428
6429
i)
Total coliform
fermentation
technique:
Standard
Methods,
6430
18
th 19
th
20
th
or
21st
ed.:
Method
9221
A, B, and
C.
6431
6432
BOARD
NOTE:
Lactose
broth,
as commercially
available,
6433
maybe used
in lieu
of lauryl
tryptose
broth
if the supplier
6434
conducts
at least 25
parallel tests
between
this medium
and
6435
lauryl tryptose
broth
using the
water normally
tested
and
6436
this comparison
demonstrates
that the
false-positive
rate
6437
and false-negative
rate for
total
coliforms,
using
lactose
6438
broth,
is less than
10 percent.
If
inverted
tubes
are used
to
JCAR35O61 1-0814065r01
6439
detect
gas production,
the media should cover these tubes at
6440
least one-half
to two-thirds after the sample
is
added.
No
6441
requirement exists
to run the completed phase on 10
6442
percent of all total coliform-positive
confinned tubes.
6443
6444
ii)
Total coliform
membrane filter
technique: Standard
6445
Methods,
18
th 19
th
20
th
or
21st
ed.: Method 9222 A, B,
6446
and
C.
6447
6448
iii)
ONPG-MUG test (also known as the Autoanalysis
Colilert
6449
System):
Standard
Methods,
i8t1,
19
th20
th
or
21st
ed.:
6450
Method 9223.
6451
6452
BOARD NOTE:
USEPA included the P-A Coliform and
6453
Colisure Tests
for testing finished water under the coliform
6454
rule, under
Section 611.526, but did not
include them for
6455
the purposes of
the surface water treatment rule, under
this
6456
Section,
for which quantitation of total coliforms
is
6457
necessary. For these
reasons, USEPA included Standard
6458
Methods:
Method
9221
C for the
surface
water treatment
6459
rule, but did
not include it for the purposes
of
the
total
6460
coliform rule, under
Section 611.526.
6461
6462
B)
Fecal Coliforms.
6463
6464
BOARD
NOTE:
The time from
sample collection to initiation
of
6465
analysis for source
(raw) water samples required
by
Sections
6466
611.521
and 611.532 and Subpart
B of this Part only must not
6467
exceed eight hours.
The supplier is encouraged but not required
to
6468
hold samples
below
100
C
during transit.
6469
6470
i)
Fecal coliform
procedure: Standard Methods,
18
th, 19
th
6471
20
th
or
21st
ed.: Method 9221
E.
6472
6473
BOARD
NOTE: A-i broth
may be held up to seven
6474
ythree months
in a tightly closed screwcap
tube at
40
C
6475
(39° F).
6476
6477
ii)
Fecal Coliform
Membrane
Filter Procedure:
Standard
6478
Methods,
18
th
19
th20
th
or
21
st
ed.: Method 9222
D.
6479
6480
C)
Heterotrophic
bacteria.
6481
JCAR35O61
1-0814065r01
6482
i)
Pour
plate
method:
Standard
Methods,
18
th
19
th
20
th
6483
21ed.:
Method92l5B.
6484
6485
BOARD
NOTE:
The time
from
sample
collection
to
6486
initiation
of
analysis
must
not
exceed
eight
hours.
The
6487
supplier
is encouraged
but
not
required
to hold
samples
6488
below
100
C
during
transit.
6489
6490
ii)
SimPlate
method.
6491
6492
D)
Turbidity.
6493
BOARD
NOTE:
Styrene
divinyl
benzene
beads
(e.g.,
AMCO
6494
AEPA-l
or
equivalent)
and
stabilized
formazin
(e.g.,
Hach
6495
StablCalTM
or equivalent)
are
acceptable
substitutes
for
formazin.
6496
6497
6498
i)
Nephelometric
method:
Standard
Methods,
18
th,
l9t1
,-eF
6499
2Oth,or2lsted.:
Method2l3OB.
6500
6501
ii)
Nephelometric
method:
USEPA
Environmental
Inorganic
6502
Methods:
Method
180.1
6503
6504
iii)
GLI
Method
2.
6505
6506
iv)
Hach FilterTrak
Method
10133.
6507
6508
E)
Temperature:
Standard
Methods,
18
th,
19
th
20
th
or 2l
ed.:
6509
Method
2550.
6510
6511
BOARD
NOTE:
On
March
12, 2007
(at
72
Fed. Reg.
11200),
USEPA
amended
6512
the
entries
for total
coliforms,
fecal coliforms,
heterotrophic
bacteria,
turbidity,
6513
and
temperature
at
corresponding
40 CFR
141.74(a)(1)
to allow
the
use of
6514
Standard
Methods
Online
(at www.standardmethods.org),
Method
2130
B (as
6515
pproved
in 2001);
Method
9215
B
(as
approved
in
2000);
Method
9221 A,
B,
6516
and
C
(as approved
in
1999);
Method
9222
A,
B,
C,
and
D
(as
approved
in 1997);
6517
and
Method
9223
B
(as
approved
in
1997).
The
Board
has instead
cited
to
the
6518
21
st
edition
of Standard
Methods
for
the Examination
of Water
and
Wastewater
6519
(the
printed
version
of
Standard
Methods),
since the
versions
of Method
2130,
6520
Method
9215, Method
9221,
Method
9222, and
Method
9223
that
appear
in that
6521
printed
volume
are
those
cited
by
USEPA
as acceptable
for
use.
USEPA
later
6522
added
Method
2130
B; Method
9215
B; Method
9221
A,
B,
C,
and
E;
Method
6523
9222
A,
B,
C, and
D; and
Method
9223
from the
21
st
edition
of
Standard
Methods
JCAR35061 1-0814065r01
6524
as
an approved
alternative
method
in
appendix
A to
subpart
C,
added
on
June
3,
6525
2008
(at
73 Fed.
Reg.
31616).
6526
6527
b)
A
supplier
must
measure
residual
disinfectant
concentrations
with
one
of
the
6528
following
analytical
methods
from
Standard
Methods,
18
th_
19
th,
or
20
th
ed. (the
6529
method
for
ozone,
Method
4500
OB
appears
only in
the
18
th
and
19
th
editions):
6530
6531
1)
Free
chlorine.
6532
6533
A)
Amperometric
Titration:
Method
4500
Cl D.
6534
6535
j)
Standard
Methods,
18
th
19
th
20
th
or
21st
ed.: Method
6536
4500-C1D.
6537
6538
ASTM
Method
D 1253-03.
6539
6540
B)
DPD
Ferrous
Titrimetric:
Standard
Methods,
18
th,
19
th
20
th
or
6541
21st
ed.:
Method
4500-Cl
F.
6542
6543
C)
DPD
Colimetric:
Standard
Methods,
18
th,
19
th
20
th
or
21st
ed.:
6544
Method
4500-Cl
G.
6545
6546
D)
Syringaldazine
(FACTS):
Standard
Methods,
18t11,
19
th
20t1,
.
6547
21st
ed.:
Method
4500-Cl
H.
6548
6549
2)
Total
chlorine.
6550
6551
A)
Amperometric
Titration:
Method
4500
Cl D.
6552
6553
j)
Standard
Methods,
18
th
19
th
20t11,
or
21st
ed.:
Method
6554
4500-C1D.
6555
6556
j)
ASTMMethodD1253-03.
6557
6558
B)
Amperometric
Titration
(low
level
measurement):
Standard
6559
Methods,
18
th,
19
th
20
th
or
21st
ed.:
Method
4500-Cl
E.
6560
6561
C)
DPD
Ferrous
Titrimetric:
Standard
Methods,
18
th,
19
th
20
th,
or
6562
21st
ed.:
Method
4500-Cl
F.
6563
6564
D)
DPD
Colimetric:
Standard
Methods,
18
th
19
th
20
th
or
21st
ed.:
6565
Method
4500-Cl
G.
6566
JCAR35O61
1-0814065r01
6567
E)
lodometric
Electrode:
Standard
Methods,
18
th,
19
th 20
th
or
21st
6568
ed.:
Method 4500-Cl
I.
6569
6570
3)
Chlorine dioxide.
6571
6572
A)
Amperometric
Titration:
Standard
Methods,
18
th, 19
th
20
th
or
6573
ed.:
Method
4500-C10
2
C
or E.
6574
6575
B)
DPD Method:
Standard Methods,
18
th,
19
th 20
th
or
21st
ed.:
6576
Method
4500-C10
2
D.
6577
6578
Spectrophotometric:
USEPA
OGWDW
Methods,
Method
327.0.
6579
6580
4)
Ozone:
Indigo Method:
Standard
Methods,
18
th1,
19t1,
20
th
or
21st
ed.:
6581
Method
4500-03
B.
6582
6583
5)
Alternative
test methods:
The
Agency
may
grant
a SEP pursuant
to
6584
Section
611.110 that
allows
a supplier
to use
alternative
chlorine test
6585
methods
as follows:
6586
6587
A)
DPD
colorimetric
test
kits: Residual
disinfectant
concentrations
6588
for free
chlorine
and combined
chlorine
may
also
be measured
by
6589
using DPD
colorimetric
test
kits.
6590
6591
B)
Continuous
monitoring
for
free and
total chlorine:
Free and
total
6592
chlorine
residuals
may
be measured
continuously
by adapting
a
6593
specified
chlorine
residual
method
for use
with
a continuous
6594
monitoring
instrument,
provided the
chemistry,
accuracy,
and
6595
precision
remain
the same.
Instruments
used
for
continuous
6596
monitoring
must
be calibrated
with
a grab sample
measurement
at
6597
least every
five
days or as
otherwise
provided by
the Agency.
6598
6599
BOARD
NOTE:
Suppliers
may use
a five-tube
test or a 10-tube
6600
test.
6601
6602
BOARD
NOTE:
On
March 12,
2007
(at
72
Fed. Reg.
11200).
USEPA
amended
6603
the
entries
for
free chlorine,
total
chlorine,
chlorine
dioxide,
and
ozone at
6604
corresponding
40
CFR
141.74(a)(2)
to allow
the
use
of
Standard
Methods
Online
6605
(at
www.standardmethods.org),
Method
4500-Cl D,
E,
F,
G,
and
H
(as
approved
6606
in
2000)
Method
4500-dO
2
C
and
E
(as
approved
in
2000)
and Method
4500-
6607
03
B
(as
approved
in 1997).
The Board
has
instead
cited
to the
21st
edition
of
6608
Standard
Methods
for the Examination
of
Water
and
Wastewater
(the
printed
6609
version
of Standard
Methods),
since
the
versions
of
Method
4500-Cl,
Method
JCAR35O61
1-0814065r01
6610
4500-C10
2
,
and
Method
4500-03 that
appear in that printed
volume
are those
6611
cited
by USEPA as acceptable
for
use.
USEPA
later
added Method 4500-Cl
D, E,
6612
F,
G,
and
H;
Method
4500-Cl02
C and E; and Method
4500-03
B from
the
21
st
6613
edition
of Standard
Methods as an approved
alternative
method
in appendix A to
6614
subpart
C, added on
June
3,
2008
(at
73 Fed.
Reg.
31616).
6615
6616
BOARD
NOTE: Derived
from 40 CFR
141.74(a)
(2007)
and
appendix
A
to 40 CFR
6617
141, as
added at 73 Fed.
Reg.
31616
(June 3, 2008)(2002).
6618
6619
(Source:
Amended at 32
Ill.
Reg.
effective
6620
6621
SUBPART N:
INORGANIC
MONITORiNG
AI%1D
ANALYTICAL REQUIREMENTS
6622
6623
Section
611.600
Applicability
6624
6625
The
following
types
of suppliers must
conduct monitoring
to determine
compliance
with
the old
6626
MCLs
in Section 611.300
and
the revised
MCLs
in 611.301,
as appropriate, in accordance
with
6627
this
SubpartN:
6628
6629
a)
CWS
suppliers.
6630
6631
b)
NTNCWS
suppliers.
6632
6633
c)
Transient
non-CWS
suppliers
to determine
compliance
with the
nitrate and nitrite
6634
MCLs.
6635
6636
d)
Detection
limits.
The following
are detection
limits for purposes
of
this
Subpart
6637
N (MCLs from
Section
611.301
are
set forth
for information
purposes only):
6638
Detection
MCL
(mg!e,
Limit
Contaminant
except
asbestos)
Method
(mg/2)
Antimony
0.006
Atomic
absorption-furnace
0.003
technique
Atomic
absorption-furnace
0.0008
technique
(stabilized
temperature)
Inductively-coupled
plasma 0.0004
— mass spectrometry
Atomic absorption-gaseous
0.001
JCAR35O61
1-0814065r01
hydride
technique
Arsenic
0.0106
Atomic
absorption-furnace
0.001
technique
Atomic
absorption-furnace
0.O0005
technique
(stabilized
temperature)
Atomic
absorption-gaseous
0.00
1
hydride
technique
Inductively-coupled
plasma
0.00148
— mass
spectrometry
Asbestos
7 MFL’
Transmission
electron
0.01
microscopy
MFL
Barium
2
Atomic
absorption-furnace
0.002
technique
Atomic
absorption-direct
0.1
aspiration
technique
Inductively-coupled
plasma
0.002
arc
furnace
Inductively-coup
led plasma
0.001
Beryllium
0.004
Atomic
absorption-furnace
0.0002
technique
Atomic
absorption-furnace
0.00002
technique
(stabilized
temperature)
Inductively-coupled
0.0003
plasma2
Inductively-coupled
plasma
0.0003
— mass
spectrometry
Cadmium
0.005
Atomic
absorption-furnace
0.000
1
technique
Inductively-coupled
plasma
0.001
JCAR35O61
1-0814065r01
Chromium
0.1
Atomic
absorption-furnace
0.001
technique
Inductively-coupled
plasma
0.007
Inductively-coupled
plasma
0.001
Cyanide
0.2
Distillation,
0.02
spectrophotometric
3
Automated
distillation,
0.005
spectrophotometric
3
Distillation,
selective
0.05
electrode
3
UV,
distillation,
0.0005
spectrophotometric
Micro distillation,
flow
0.0006
inj ection,Distillation,
spectrophotometric
Ligand exchange
with
0.0005
amperometry
4
Mercury
0.002
Manual
cold
vapor
0.0002
technique
Automated
cold
vapor
0.0002
technique
Nickel
No MCL
Atomic
absorption-furnace
0.00
1
technique
Atomic absorption-furnace
0.0006
technique
(stabilized
temperature)
Inductively-coupled
0.005
plasma
2
Inductively-coupled
plasma
0.0005
— mass
spectrometry
JCAR35O61
1-0814065r01
Nitrate (as
N)
10
Manual cadmium
reduction
0.01
Automated hydrazine
0.01
reduction
Capillary
ion
0.076
electrophoresis
Automated
cadmium
0.05
reduction
Ion-selective
electrode
1
Ion chromatography
0.01
Nitrite
(as N)
1
Spectrophotometric
0.01
Automated
cadmium
0.05
reduction
Manual
cadmium
reduction
0.01
Ion
chromatography
0.004
Capillary
ion
0.103
electrophoresis
Selenium
0.05
Atomic
absorption-furnace
0.002
technique
Atomic
absorption-gaseous
0.002
hydride
technique
Thallium
0.002
Atomic
absorption-furnace
0.001
technique
Atomic
absorption-furnace
0.0007
technique
(stabilized
temperature)
Inductively-coupled
plasma
0.0003
— mass
spectrometry
Footnotes.
“MFL” means
millions
of
fibers
per liter
less than
10
m.
2
Using
a
2x
preconcentration
step
as noted
in Method 200.7.
Lower MDLs
may be achieved
when
using a 4x preconcentration.
Screening
method
for total
cyanides.
JCAR35O61
1-0814065r01
Measures
“free”
cyanides
when
distillation,
digestion,
or ligand exchange
is
omitted.
Lower MDLs
are
reported
using
stabilized
temperature
graphite
furnace
atomic
absorbtion.
6
The
value
for
arsenic is
effective
January
23, 2006.
Until then,
the MCL
is 0.05
mg!E.
The MDL
reported
for
USEPA
Method
200.9 (atomic
absorption-
platform
furnace
(stabilized
temperature))
was
determined
using a 2x
concentration
step during
sample
digestion.
The MDL
determined
for
samples
analyzed
using
direct
analyses
(i.e.,
no
sample digestion)
will
be
higher.
Using
multiple
depositions,
USEPA
Method
200.9
is capable
of
obtaining
an MDL
of
0.0001
mg/i.
8
Using
selective
ion
monitoring,
USEPA
Method
200.8
(ICP-MS)
is
capable
of obtaining
an
MDL
of 0.0001
mg!.
Measures
total cyanides
when
UV-digestor
is used,
and
“free”
cyanides
when UV-digestor
is
bypassed.
6639
6640
BOARD
NOTE:
Subsections
(a) through
(c)
of this
Section are
derived
from 40 CFR
141.23
6641
preamble
(2007)(2003)
and
subsection
(d) of
this
Section is
derived from
40
CFR
141.23
6642
(a)(4)(i)
(2007)
and
appendix
A
to
40
CFR
141, as
added at
73
Fed.
Reg.
31616 (June
3,
6643
2008)(2003).
See
the Board
Note at Section
611.301(b)
relating
to the
MCL for nickel.
6644
6645
(Source:
Amended
at 32 Iii.
Reg.
effective
6646
6647
Section
611.611 Inorganic
Analysis
6648
6649
Analytical
methods
are
from documents
incorporated
by
reference
in Section
611.102.
These are
6650
mostly referenced
by
a
short name
defined
by Section
611.102(a).
Other
abbreviations
are
6651
defined
in
Section
611.101.
6652
6653
a)
Analysis
for the following
contaminants
must be
conducted
using
the following
6654
methods or
an alternative
approved
pursuant
to Section
611.480.
Criteria for
6655
analyzing
arsenic,
chromium,
copper,
lead, nickel,
selenium,
sodium,
and
thallium
6656
with digestion
or directly
without
digestion,
and other
analytical
procedures,
are
6657
contained
in
USEPA Technical
Notes,
incorporated
by
reference in
Section
6658
611.102.
(This document
also contains
approved
analytical
test
methods that
6659
remained
available
for
compliance
monitoring
until
July
1,
1996.
These methods
6660
are not available
for
use after July
1, 1996.)
6661
6662
BOARD
NOTE:
Because MDLs
reported
in USEPA
Environmental
Metals
6663
Methods
200.7 and
200.9
were
determined
using
a
2x preconcentration
step
6664
during sample
digestion,
MDLs
determined
when samples
are analyzed
by
direct
6665
analysis
(i.e., no
sample
digestion)
will
be
higher.
For direct analysis
of
cadmium
JCAR35O61
1-0814065r01
6666
and
arsenic
by USEPA
Environmental
Metals
Method 200.7,
and arsenic
by
6667
Standard
Methods,
18
th
19
th
20
th
or
21st
ed., Method
3120
B
sample
6668
preconcentration
using
pneumatic
nebulization
may
be
required to
achieve
lower
6669
detection
limits. Preconcentration
may also
be required
for
direct
analysis
of
6670
antimony,
lead,
and
thallium
by USEPA
Environmental
Metals
Method 200.9;
6671
antimony
and lead
by Standard
Methods,
18tef
19
th
or
21st
ed.,
Method
3113 B;
6672
and lead
by ASTM
Method
D3559-96
D
or
D3559-03
D
unless
multiple
in-
6673
furnace depositions
are made.
6674
6675
1)
Alkalinity.
6676
6677
A)
Titrimetric.
6678
6679
i)
ASTM Method
D1067-92
B or
D1067-02
B; or
6680
6681
ii)
Standard
Methods,
18
th,
19
th,
0
f
20
th
or
21St
ed.: Method
6682
2320
B.
6683
6684
BOARD
NOTE:
On March
12, 2007
(at
72
Fed. Reg.
6685
11200),
USEPA
amended
the entry
for alkalinity
by
6686
titrimetric
alkalinity
in the table
at
corresponding
40
CFR
6687
141.23(k)(1)
to allow
the
use
of Standard
Methods
Online
6688
(at
www.standardmethods.org),
Method
2320 B (as
6689
approved
in 1997).
The Board
has instead
cited
to the
21st
6690
edition
of
Standard
Methods
for the
Examination
of Water
6691
and Wastewater
(the printed
version of
Standard
Methods),
6692
since
the
version
of Method
2320
that appears
in that
6693
printed
volume
is that cited
by
USEPA
as acceptable
for
6694
use.
USEPA
later
added
Method
2320
B
from
the
21st
6695
edition
of
Standard
Methods
as
an
approved
alternative
6696
method
in appendix
A
to
subpart
C,
added
on June
3, 2008
6697
(at
73
Fed.
Reg.
31616).
6698
6699
B)
Electrometric
titration:
USGS Methods:
Method
1-1030-85.
6700
6701
2)
Antimony.
6702
6703
A)
Inductively-coupled
plasma
— mass
spectrometry:
USEPA
6704
Environmental
Metals Methods:
Method 200.8.
6705
6706
B)
Atomic absorption,
hydride
technique:
ASTM
Method
D3697-92
6707
or D3697-02.
6708
JCAR35O61
1-0814065r01
6709
C)
Atomic
absorption,
platform
furnace
technique:
USEPA
6710
Environmental
Metals
Methods:
Method
200.9.
6711
6712
D)
Atomic
absorption,
furnace
technique:
Standard
Methods,
18
t1Øf
6713
l9th,or2lsted.:
Method3ll3B.
6714
6715
BOARD
NOTE:
On
March
12, 2007
(at
72
Fed.
Reg.
11200),
6716
USEPA
amended
the
entry
for
antimony
by atomic
absorption,
6717
furnace
technique,
in
the
table
at
corresponding
40
CFR
6718
141
.23(k)(1)
to
allow
the
use
of
Standard
Methods
Online
(at
6719
www.standardmethods.org),
Method
3113
B (as
approved
in
6720
1999).
The
Board
has
instead
cited
to
the
21st
edition
of
Standard
6721
Methods
for
the
Examination
of
Water
and
Wastewater
(the
6722
printed
version
of
Standard
Methods),
since
the
version
of Method
6723
3113
that
appears
in that
printed
volume
is
that
cited
by
USEPA
as
6724
acceptable
for
use.
USEPA
later
added
Method
3113
B
from
the
6725
21
st
edition
of
Standard
Methods
as
an approved
alternative
6726
method
in
appendix
A
to
subpart
C,
added
on June
3,
2008
(at
73
6727
Fed.
Reg.
31616).
6728
6729
)
Axially
viewed
inductively-coupled
plasma
—
atomic
emission
6730
spectrometry
(AVICP-AES):
USEPA
Methods:
Method 200.5.
6731
6732
BOARD
NOTE:
USEPA added
this
method
as
an
approved
6733
alternative
method
in
appendix
A
to
subpart
C
of 40
CFR
141,
6734
added
on
June
3,
2008
(at
73
Fed.
Reg.
31616).
6735
6736
3)
Arsenic.
6737
6738
BOARD
NOTE:
If
ultrasonic
nebulization
is
used
in
the
determination
of
6739
arsenic
by
Methods
200.7,
200.8,
or
Standard
Methods,
18
th
19
th
20
th
6740
or
21
st
ed.,
3120
B, the
arsenic
must
be
in
the
pentavalent
state
to
provide
6741
uniform
signal
response.
For
methods
200.7
and
3120
B, both
samples
6742
and
standards
must
be
diluted
in
the
same
mixed
acid
matrix
concentration
6743
of nitric
and
hydrochloric
acid
with
the
addition
of
100
e
of
30%
6744
hydrogen
peroxide
per
100
me
of
solution.
For
direct
analysis
of
arsenic
6745
with
method
200.8
using
ultrasonic
nebulization,
samples
and
standards
6746
must
contain
one
mg/e
of
sodium hypochlorite.
6747
6748
A)
Inductively-coupled
plasma.
6749
6750
BOARD
NOTE:
Effective
January
23,
2006,
a
supplier
may
no
6751
longer
employ
analytical
methods
using
the
ICP-AES
technology
JCAR35O61
1-0814065r01
6752
because
the detection
limits
for
these
methods
are 0.008
mg/i
or
6753
higher.
This
restriction
means
that
the two
ICP-AES
methods
6754
(USEPA
Environmental
Metals
Method
200.7
and Standard
6755
Methods,
Method
3120
B) approved
for
use
for
the
MCL
of
0.05
6756
mg!2
may
not
be
used
for
compliance determinations
for
the
6757
revised
MCL
of
0.010
mg/i.
However,
prior
to the
2005
through
6758
2007
compliance
period,
a supplier
may
have
compliance
samples
6759
analyzed
with
these
less
sensitive
methods.
6760
6761
i)
USEPA
Environmental
Metals
Methods:
Method
200.7;
or
6762
6763
ii)
Standard
Methods,
18
th,
19
th,
20
th
or
21st
ed.:
Method
6764
3120
B.
6765
6766
BOARD
NOTE: On
March
12,
2007
(at
72
Fed.
Reg.
6767
11200),
USEPA
amended
the
entry
for
arsenic
by
6768
inductively-coupled
plasma
in
the
table
at
corresponding
40
6769
CFR
141.23(k)(1)
to allow
the use
of Standard
Methods
6770
Online
(at
www.standardmethods.org),
Method
3120
B
(as
6771
approved
in
1999).
The
Board
has
instead
cited
to
the
21st
6772
edition
of
Standard
Methods for
the Examination
of Water
6773
and Wastewater
(the
printed
version
of Standard
Methods),
6774
since
the version
of Method
3120
that
appears
in
that
6775
printed
volume
is that
cited
by
USEPA
as
acceptable
for
6776
use.
USEPA
later
added
Method
3120
B
from
the
21st
6777
edition
of
Standard
Methods
as
an approved
alternative
6778
method
for
several
other
metals
in
appendix
A
to subpart
C,
6779
added
on
June
3,
2008
(at
73
Fed.
Reg.
31616).
USEPA,
6780
however,
did
not
specifically
add
Method
2130
B as
to
6781
arsenic
in
the
June
3,
2008
action.
6782
6783
B)
Inductively-coupled
plasma
— mass
spectrometry:
USEPA
6784
Environmental
Metals
Methods:
Method
200.8.
6785
6786
C)
Atomic
absorption,
platform
furnace
technique:
USEPA
6787
Environmental
Metals
Methods:
Method
200.9.
6788
6789
D)
Atomic
absorption,
furnace
technique.
6790
6791
i)
ASTM
Method
D2972-97
C
or
2972-03
C;
or
6792
6793
ii)
Standard
Methods,
l8tief
19
th
or
21st
ed.: Method
3113
6794
B.
JCAR35O61
1-0814065r01
6795
6796
BOARD
NOTE:
On
March
12,
2007
(at
72
Fed.
Reg.
6797
11200),
USEPA
amended
the
entry
for
arsenic
by
atomic
6798
absorption,
furnace
technique,
in
the
table
at
corresponding
6799
40
CFR
141.23(k)(1)
to
allow the
use
of
Standard
Methods
6800
Online
(at
www.standardmethods.org),
Method
3113
B
(as
6801
approved
in
1999).
The
Board
has
instead
cited
to
the
21st
6802
edition
of
Standard
Methods
for the
Examination
of
Water
6803
and
Wastewater
(the
printed
version
of
Standard
Methods),
6804
since
the
version
of
Method
3113
that
appears
in
that
6805
printed
volume
is
that
cited
by
USEPA
as
acceptable
for
6806
use.
USEPA
later
added
Method
3113
B
from the
21
st
6807
edition
of
Standard
Methods
as
an
approved
alternative
6808
method
in
appendix
A
to
subpart
C, added
on
June
3,
2008
6809
(at
73
Fed.
Reg.
31616).
6810
6811
E)
Atomic
absorption,
hydride
technique.
6812
6813
i)
ASTM
Method
D2972-97
B
or
2972-03
B;
or
6814
6815
ii)
Standard
Methods,
18
th
19
th
or
21st
ed.: Method
3114
6816
B.
6817
6818
BOARD
NOTE:
On
March
12,
2007
(at
72
Fed.
Reg.
6819
11200),
USEPA
amended
the
entry
for
antimony
by
atomic
6820
absorption,
hydride
technique,
in
the
table
at
corresponding
6821
40
CFR
141.23(k)(1)
to
allow
the
use
of
Standard
Methods
6822
Online
(at
www.standardmethods.org),
Method
3114
B
(as
6823
approved
in
1997).
The
Board
has
instead
cited
to
the
21
St
6824
edition
of
Standard
Methods
for
the
Examination
of
Water
6825
and
Wastewater
(the
printed
version
of
Standard
Methods),
6826
since
the
version
of
Method
3114
that
appears
in
that
6827
printed
volume
is
that
cited
by
USEPA
as
acceptable
for
6828
use. USEPA
later
added
Method
3114
B
from
the
21st
6829
edition
of
Standard
Methods
as
an
approved
alternative
6830
method
in
appendix
A
to
subpart
C,
added
on
June
3,
2008
6831
(at
73
Fed.
Reg.
31616).
6832
6833
D
Axially
viewed
inductively-coupled
plasma
—
atomic
emission
6834
spectrometry
(AVICP-AES):
USEPA
Methods:
Method
200.5.
6835
JCAR35O61
1-0814065r01
6836
BOARD
NOTE:
USEPA
added
this method
as an
approved
6837
alternative
method
in
appendix
A to
subpart
C
of 40
CFR
14j
6838
added
on
June
3, 2008
(at
73
Fed. Reg.
31616).
6839
6840
4)
Asbestos:
Transmission
electron
microscopy:
USEPA
Asbestos
6841
Methods-100.1
and
USEPA
Asbestos
Methods-100.2.
6842
6843
5)
Barium.
6844
6845
A)
liductively-coupled
plasma.
6846
6847
i)
USEPA
Environmental
Metals
Methods:
Method
200.7;
or
6848
6849
ii)
Standard
Methods,
18
th,
19
th
020
th,
or
21st
ed.:
Method
6850
3120
B.
6851
6852
BOARD
NOTE:
On
March
12,
2007
(at 72
Fed.
Reg.
6853
11200),
USEPA
amended
the
entry
for barium
by
6854
inductively-coupled
plasma
in
the
table at
corresponding
40
6855
CFR
141.23(k)(1)
to allow
the
use of
Standard
Methods
6856
Online
(at
www.standardmethods.org),
Method
3120
B
(as
6857
approved
in
1999).
The Board
has
instead
cited
to
the
21st
6858
edition
of
Standard
Methods
for
the
Examination of Water
6859
and
Wastewater
(the
printed
version
of
Standard
Methods),
6860
since
the
version
of Method
3120
that appears
in
that
6861
printed
volume
is that cited
by
USEPA
as
acceptable
for
6862
use.
USEPA
later
added
Method
3120
B from
the
21
6863
edition
of
Standard
Methods
as
an approved
alternative
6864
method
in
appendix
A
to
subpart
C,
added
on
June
3, 2008
6865
(at
73 Fed.
Reg.
31616).
6866
6867
B)
Inductively-coupled
plasma
— mass
spectrometry:
USEPA
6868
Environmental
Metals
Methods:
Method
200.8.
6869
6870
C)
Atomic
absorption,
direct
aspiration
technique:
Standard
Methods,
6871
18t19th,or215ted.:
Method
3111
D.
6872
6873
BOARD
NOTE:
On March
12,
2007
(at
72 Fed.
Reg.
11200),
6874
USEPA
amended
the
entry
for
barium
by
atomic
absorption,
direct
6875
aspiration
technique,
in
the
table
at corresponding
40
CFR
6876
141
.23(k)(1)
to
allow
the
use
of Standard
Methods
Online
(at
6877
www.standardmethods.org),
Method
3111
D
(as
approved
in
6878
1999).
The
Board
has
instead
cited
to
the
21
st
edition
of
Standard
JCAR35O61
1-0814065r01
6879
Methods
for the Examination
of Water
and
Wastewater
(the
6880
printed
version
of
Standard
Methods),
since
the
version
of Method
6881
3111 that
appears in
that
printed
volume
is
that
cited
by USEPA
as
6882
acceptable
for use.
USEPA
later
added
Method
3111
D from
the
6883
21
st
edition of
Standard Methods
as
an approved
alternative
6884
method
in
appendix
A to
subpart
C,
added on
June
3, 2008
(at
73
6885
Fed.
Reg.
31616).
6886
6887
D)
Atomic
absorption,
furnace
technique:
Standard
Methods,
18
th,
6888
l9th,or2lsted.:
Method3ll3B.
6889
6890
BOARD
NOTE:
On March
12, 2007
(at
72
Fed.
Reg.
11200),
6891
USEPA
amended
the entry
for barium
by
atomic
absorption,
6892
furnace
technique,
in
the
table
at
corresponding
40
CFR
6893
141.23(k)(1)
to
allow
the
use of Standard
Methods
Online
(at
6894
www.standardmethods.org),
Method 3113
B
(as
approved
in
6895
1999).
The Board
has instead
cited
to the
21st
edition
of Standard
6896
Methods
for the
Examination
of Water
and Wastewater
(the
6897
printed
version
of Standard
Methods),
since
the
version
of Method
6898
3113
that appears
in that
printed
volume
is that cited
by USEPA
as
6899
acceptable
for
use. USEPA
later added
Method
3113
B from
the
6900
21
st
edition
of
Standard
Methods as
an
approved
alternative
6901
method
in appendix
A to
subpart
C, added
on June
3, 2008
(at
73
6902
Fed.
Reg.
31616).
6903
6904
j
Axially
viewed
inductively-coupled
plasma —
atomic emission
6905
spectrometry
(AVICP-AES):
USEPA
Methods:
Method
200.5.
6906
6907
BOARD NOTE:
USEPA
added
this
method as
an approved
6908
alternative
method
in appendix
A
to subpart
C of 40 CFR
141,
6909
added on June
3,
2008 (at
73 Fed.
Reg.
31616).
6910
6911
6)
Beryllium.
6912
6913
A)
Inductively-coupled
plasma.
6914
6915
i)
USEPA
Environmental
Metals
Methods:
Method
200.7; or
6916
6917
ii)
Standard
Methods,
18
th, 19
th
20
th
or
21st
ed.:
Method
6918
3120B.
6919
6920
BOARD
NOTE:
On
March
12, 2007
(at
72
Fed. Reg.
6921
11200), USEPA
amended
the entry
for
beryllium
by
JCAR35O61
1-0814065r01
6922
inductively-coupled
plasma
in
the
table
at
corresponding
40
6923
CFR
141.23(k)(1)
to
allow
the
use
of Standard
Methods
6924
Online
(at
www.standardmethods.org),
Method
3120
B
(as
6925
approved
in
1999).
The
Board
has
instead
cited
to
the
21
st
6926
edition
of
Standard
Methods
for
the
Examination
of
Water
6927
and
Wastewater
(the
printed
version of
Standard
Methods),
6928
since
the version
of
Method
3120
that
appears
in that
6929
printed
volume
is
that cited
by USEPA
as acceptable
for
6930
use.
USEPA
later added
Method 3120
B from
the
21st
6931
edition
of
Standard
Methods
as an
approved
alternative
6932
method
in appendix
A to
subpart
C,
added
on
June 3, 2008
6933
(at
73 Fed.
Reg.
31616).
6934
6935
B)
Inductively-coupled
plasma
— mass
spectrometry:
USEPA
6936
Environmental
Metals Methods:
Method
200.8.
6937
6938
C)
Atomic
absorption,
platform
furnace
technique:
USEPA
6939
Environmental
Metals
Methods: Method
200.9.
6940
6941
D)
Atomic
absorption,
furnace
technique.
6942
6943
i)
ASTM
Method
D3645-97
B or D3645-03
B; or
6944
6945
ii)
Standard
Methods,
l8tIef
19
th
or
21st
ed.: Method
3113
6946
B.
6947
6948
BOARD
NOTE:
On
March 12,
2007
(at 72 Fed.
Reg.
6949
11200).
USEPA
amended
the
entry
for
beryllium
by
atomic
6950
absorption,
furnace
technique,
in the
table at
corresponding
6951
40
CFR
l41.23(k)(1)
to allow the
use of
Standard
Methods
6952
Online
(at
www.standardmethods.org), Method
3113 B
(as
6953
approved
in 1999).
The
Board has
instead
cited
to the
21St
6954
edition
of
Standard
Methods
for the
Examination
of
Water
6955
and
Wastewater
(the
printed
version of
Standard
Methods),
6956
since
the
version
of
Method
3113 that
appears
in
that
6957
printed
volume
is that
cited by USEPA
as
acceptable
for
6958
use.
USEPA
later
added
Method 3113
B
from
the
21
5t
6959
edition
of Standard
Methods
as
an
approved
alternative
6960
method
in
appendix
A to subpart
C,
added on
June 3,
2008
6961
L73
Fed.
Reg. 31616).
6962
6963
Axially
viewed
inductively-coupled
plasma
— atomic
emission
6964
spectrometry
(AVICP-AES):
USEPA
Methods:
Method 200.5.
JCAR35O61
1-0814065r01
6965
6966
BOARD
NOTE:
USEPA
added
this method
as
an
approved
6967
alternative
method
in appendix
A to subpart
C
of 40 CFR
141.
6968
added
on
June
3,2008
(at
73
Fed. Reg.
31616).
6969
6970
7)
Cadmium.
6971
6972
A)
Inductively-coupled
plasma
arc furnace:
USEPA
Environmental
6973
Metals
Methods:
Method
200.7.
6974
6975
B)
Inductively-coupled
plasma
— mass
spectrometry:
USEPA
6976
Environmental
Metals
Methods: Method
200.8.
6977
6978
C)
Atomic
absorption,
platform
furnace technique:
USEPA
6979
Environmental
Metals
Methods:
Method
200.9.
6980
6981
D)
Atomic
absorption,
furnace
technique:
Standard
Methods,
18
t11
10
f
6982
l9th,or2lsted.:
Method3ll3B.
6983
6984
BOARD
NOTE:
On March
12, 2007
(at
72
Fed.
Reg.
11200),
6985
USEPA
amended
the
entry
for cadmium
by
atomic
absorption,
6986
furnace
technique,
in the
table at corresponding
40 CFR
6987
141.23(k)(1)
to
allow the
use of
Standard
Methods
Online
(at
6988
www.standardmethods.org),
Method
3113
B
(as approved
in
6989
1999).
The
Board
has
instead cited
to
the
21St
edition
of Standard
6990
Methods
for
the Examination
of Water and
Wastewater
(the
6991
printed version
of Standard
Methods),
since
the version
of
Method
6992
3113
that appears
in that
printed
volume
is
that
cited
by USEPA
as
6993
acceptable
for use. USEPA
later
added
Method
3113
B from the
6994
21
5t
edition of
Standard
Methods
as an
approved
alternative
6995
method
in
appendix
A to
subpart
C,
added
on June 3,
2008
(at
73
6996
Fed.
Reg. 31616).
6997
6998
Axially
viewed
inductively-coupled
plasma —
atomic emission
6999
spectrometry
(AVICP-AES):
USEPA
Methods:
Method
200.5.
7000
7001
BOARD
NOTE:
USEPA
added
this method
as
an approved
7002
alternative
method
in
appendix
A to subpart
C
of 40
CFR
141,
7003
added
on
June
3,
2008
(at
73
Fed.
Reg.
31616).
7004
7005
8)
Calcium.
7006
7007
A)
EDTA
titrimetric.
JCAR35O61
1-0814065r01
7008
7009
i)
ASTM
Method
D511-93
AorD5ll-03
A; or
7010
7011
ii)
Standard
Methods,
l8thor
19
th
or
20th
ed.: Method
3500-
7012
Ca D or Standard
Methods,
2O’
or
21st
ed.:
Method
3500-
7013
CaB.
7014
7015
BOARD
NOTE:
On March
12,
2007 (at
72 Fed.
Reg.
7016
11200),
USEPA
amended
the entry for
calcium by
EDTA
7017
titrimetric
in the table
at
corresponding
40
CFR
7018
141.23(k)(1)
to allow
the
use
of Standard
Methods
Online
7019
(at
www.standardmethods.org),
Method
3500-Ca
D
(as
7020
approved
in
1997).
The
Board
has
instead
cited
to the
21
st
7021
edition
of
Standard
Methods
for the Examination
of
Water
7022
and
Wastewater
(the
printed version
of Standard
Methods),
7023
since
the version
of Method
3500-Ca
that appears
in
that
7024
printed
volume
is
that
cited by
USEPA as
acceptable
for
7025
use.
USEPA
later added
Method
3500-Ca
B
from the
21st
7026
edition
of
Standard
Methods
as
an approved
alternative
7027
method
in appendix
A
to subpart
C,
added
on June
3, 2008
7028
(at
73 Fed.
Reg.
31616).
7029
7030
B)
Atomic
absorption,
direct aspiration.
7031
7032
i)
ASTM
Method
D511-93 B
orD5ll-03
B; or
7033
7034
ii)
Standard
Methods,
18
th
19
th
or
21st
ed.: Method
3111
7035
B.
7036
7037
BOARD
NOTE:
On
March
12,
2007
(at
72 Fed.
Reg.
7038
11200),
USEPA
amended
the entry for
calcium by
atomic
7039
absorption,
direct
aspiration,
in the
table
at corresponding
7040
40 CFR 141.23(k)(1)
to
allow
the
use
of
Standard
Methods
7041
Online
(at
www.standardmethods.org),
Method 3111
B
(as
7042
approved
in 1999).
The
Board
has
instead
cited to
the
21
tt
7043
edition
of
Standard
Methods
for the Examination
of
Water
7044
and Wastewater
(the
printed
version of
Standard
Methods),
7045
since the
version
of
Method
3111
that appears
in
that
7046
printed
volume
is that cited
by
USEPA
as
acceptable
for
7047
use.
USEPA
later
added
Method
3111
B from
the
21
st
7048
edition
of
Standard
Methods
as an
approved
alternative
7049
method
in appendix
A to subpart
C,
added on
June
3,
2008
7050
(at
73 Fed.
Reg.
31616).
JCAR35O61
1-0814065r01
7051
7052
C)
Inductively-coupled
plasma.
7053
7054
i)
USEPA Environmental
Metals
Methods:
Method
200.7;
or
7055
7056
ii)
Standard
Methods,
18
th 19
th
20
th
or
21st
ed.: Method
7057
3120
B.
7058
7059
BOARD
NOTE:
On March
12,
2007 (at
72 Fed. Reg.
7060
11200),
USEPA amended
the
entry for
calcium by
7061
inductively-coupled
plasma
in the
table at
corresponding
40
7062
CFR
141.23(k)(1)
to allow the
use
of Standard
Methods
7063
Online
(at
www.standardmethods.org),
Method
3120
B (as
7064
approved in
1999).
The Board
has
instead cited
to the
21st
7065
edition of
Standard
Methods
for
the
Examination
of
Water
7066
and
Wastewater
(the
printed
version
of Standard
Methods),
7067
since the
version
of
Method
3120 that
appears
in that
7068
printed volume
is that
cited
by
USEPA
as acceptable
for
7069
use. USEPA
later
added
Method
3120
B from
the
21
st
7070
edition
of
Standard
Methods
as an
approved
alternative
7071
method in
appendix
A to
subpart
C,
added
on June 3,
2008
7072
(at
73 Fed.
Reg.
31616).
7073
7074
Ion
chromatography:
ASTM
Method
D69 19-03.
7075
7076
)
Axially
viewed
inductively-coupled
plasma — atomic
emission
7077
spectrometry
(AVICP-AES):
USEPA
Methods:
Method 200.5.
7078
7079
BOARD
NOTE:
USEPA
added this
method
as an
approved
7080
alternative
method
in appendix
A to
subpart
C
of 40 CFR
141,
7081
added
on June
3,2008
(at
73 Fed.
Reg.
31616).
7082
7083
9)
Chromium.
7084
7085
A)
Inductively-coupled
plasma.
7086
7087
i)
USEPA
Environmental
Metals
Methods:
Method 200.7;
or
7088
7089
ii)
Standard
Methods,
18
th 19
th
20
th
or
21st
ed.:
Method
7090
3120
B.
7091
7092
BOARD
NOTE:
On March
12, 2007
(at
72 Fed.
Reg.
7093
11200), USEPA
amended
the entry
for
chromium
by
JCAR35O61
1-0814065r01
7094
inductively-coupled
plasma
in the
table
at
corresponding
40
7095
CFR
141.23(k)(1)
to
allow
the
use of
Standard
Methods
7096
Online
(at
www.standardmethods.org),
Method
3120
B
(as
7097
approved
in 1999).
The
Board
has instead
cited
to the
21st
7098
edition
of Standard
Methods
for
the
Examination
of
Water
7099
and
Wastewater
(the
printed
version
of Standard
Methods),
7100
since the
version
of Method
3120
that
appears
in
that
7101
printed
volume
is that
cited
by
USEPA
as
acceptable
for
7102
use.
USEPA
later
added
Method
3120
B
from
the
21st
7103
edition
of Standard
Methods
as
an
approved
alternative
7104
method
in
appendix
A
to
subpart
C, added
on
June
3, 2008
7105
(at
73
Fed. Reg.
31616).
7106
7107
B)
Inductively-coupled
plasma
— mass
spectrometry:
USEPA
7108
Environmental
Metals
Methods:
Method
200.8.
7109
7110
C)
Atomic
absorption,
platform
furnace
technique:
USEPA
7111
Environmental
Metals
Methods:
Method
200.9.
7112
7113
D)
Atomic
absorption,
furnace
technique:
Standard
Methods,
l8e
7114
l9th,or2lsted.:
Method3ll3B.
7115
7116
BOARD
NOTE:
On
March
12, 2007
(at
72
Fed.
Reg.
11200),
7117
USEPA
amended
the
entry
for chromium
by atomic
absorption,
7118
furnace
technique,
in the table
at corresponding
40 CFR
7119
141.23(k)(1)
to
allow
the use
of
Standard
Methods
Online
(at
7120
www.standardmethods.org),
Method
3113
B
(as
approved
in
7121
1999).
The Board
has
instead
cited
to
the
21
st
edition
of
Standard
7122
Methods
for
the Examination
of
Water
and
Wastewater
(the
7123
printed
version
of
Standard
Methods),
since
the version
of
Method
7124
3113
that
appears
in
that
printed
volume
is that cited
by
USEPA
as
7125
acceptable
for
use. USEPA
later
added
Method
3113
B from
the
7126
21
st
edition
of
Standard
Methods
as an
approved
alternative
7127
method
in
appendix
A to subpart
C,
added
on June
3,
2008
(at
73
7128
Fed.
Reg.
31616).
7129
7130
Axially
viewed
inductively-coupled
plasma
— atomic
emission
7131
spectrometry
(AVICP-AES):
USEPA
Methods:
Method
200.5.
7132
7133
BOARD
NOTE:
USEPA
added
this method
as
an
approved
7134
alternative
method
in appendix
A to subpart
C
of 40
CFR
141,
7135
added
on
June
3, 2008
(at
73
Fed. Reg.
31616).
7136
JCAR35O61
1-0814065r01
7137
10)
Copper.
7138
7139
A)
Atomic
absorption,
furnace
technique.
7140
7141
i)
ASTM
Method
D1688-95
C
or
D1688-02
C;
or
7142
7143
ii)
Standard
Methods,
18t_ef
19
th,
or
21
St
ed.:
Method
3113
7144
B.
7145
7146
BOARD
NOTE:
On March
12,
2007
(at
72 Fed.
Reg.
7147
11200),
USEPA
amended
the
entry
for
copper
by
atomic
7148
absorption,
furnace
technique,
in the table
at
corresponding
7149
40
CFR
141.23(k)(1’)
to allow
the
use of
Standard
Methods
7150
Online
(at
www.standardmethods.org),
Method
3113 B
(as
7151
approved
in
1999).
The
Board
has
instead
cited
to
the
21St
7152
edition
of
Standard
Methods
for
the
Examination
of Water
7153
and Wastewater
(the
printed
version
of
Standard
Methods),
7154
since
the
version
of
Method
3113
that appears
in
that
7155
printed
volume
is
that cited
by USEPA
as
acceptable
for
7156
use.
USEPA
later
added Method
3113 B
from the
21St
7157
edition
of
Standard
Methods
as
an
approved
alternative
7158
method
in
appendix
A
to
subpart
C, added
on
June
3, 2008
7159
(at
73
Fed.
Reg.
31616).
7160
7161
B)
Atomic
absorption,
direct
aspiration.
7162
7163
i)
ASTM
Method
D1688-95
A
or 1688-02
A;
or
7164
7165
ii)
Standard
Methods,
l8t
1
er
19
th,
or
21
5t
ed.:
Method
3111
7166
B.
7167
7168
BOARD
NOTE:
On March
12,
2007
(at
72 Fed.
Reg.
7169
11200),
USEPA
amended
the
entry
for
copper
by
atomic
7170
absorption,
direct
aspiration,
in
the table
at
corresponding
7171
40
CFR 141.23(k)(1)
to
allow
the
use of
Standard
Methods
7172
Online
(at
www.standardmethods.org),
Method
3111
B
(as
7173
approved
in
1999).
The
Board
has
instead
cited
to the
21St
7174
edition
of
Standard
Methods
for
the Examination
of
Water
7175
and Wastewater
(the
printed
version
of Standard
Methods),
7176
since
the version
of Method
3111 that
appears
in
that
7177
printed
volume
is
that
cited
by USEPA
as
acceptable
for
7178
use.
USEPA
later
added
Method
3111
B
from
the
21St
7179
edition
of
Standard
Methods
as
an
approved
alternative
JCAR35O61
1-0814065r01
7180
method in appendix
A to subpart
C,
added on June
3, 2008
7181
(at
73 Fed. Reg.
31616).
7182
7183
C)
Inductively-coupled
plasma.
7184
7185
i)
USEPA Environmental
Metals
Methods: Method
200.7;
or
7186
7187
ii)
Standard
Methods,
th
18 19
th
20
th
or
21
st
ed.: Method
7188
3120B.
7189
7190
BOARD
NOTE:
On March
12, 2007 (at
72 Fed. Reg.
7191
11200),
USEPA
amended
the entry for copper
by
7192
inductively-coupled
plasma
in the
table
at
corresponding 40
7193
CFR
141.23(k)(1)
to allow
the use of Standard
Methods
7194
Online
(at
www.standardmethods.org),
Method 3120
B
(as
7195
approved
in
1999).
The Board
has instead cited
to the
21st
7196
edition of Standard
Methods
for the Examination
of Water
7197
and
Wastewater
(the
printed version
of Standard
Methods),
7198
since the version
of Method
3120 that appears in
that
7199
printed
volume
is that cited
by
USEPA
as acceptable
for
7200
use.
USEPA
later added Method
3120 B from the
21st
7201
edition of
Standard Methods
as an approved
alternative
7202
method
in appendix A to subpart
C, added
on
June 3, 2008
7203
(at
73 Fed.
Reg.
31616).
7204
7205
D)
Inductively-coupled
plasma — mass
spectrometry:
USEPA
7206
Environmental
Metals
Methods:
Method 200.8.
7207
7208
E)
Atomic absorption,
platform
furnace technique:
USEPA
7209
Environmental
Metals Methods:
Method 200.9.
7210
7211
Axially viewed inductively-coupled
plasma — atomic
emission
7212
spectrometry
(AVICP-AES):
USEPA
Methods:
Method
200.5.
7213
7214
BOARD
NOTE:
USEPA added this
method as
an approved
7215
alternative method
in
appendix
A to subpart
C
of 40
CFR 141,
7216
added
on June
3, 2008
(at
73 Fed.
Reg. 31616).
7217
7218
11)
Conductivity;
Conductance.
7219
7220
A)
ASTM
Method Dl 125-95(1999)_A;
or
7221
7222
B)
Standard
Methods,
th
18
19
th 20
th
or
21
st
ed.: Method 2510
B.
JCAR35O61
1-0814065r01
7223
7224
BOARD
NOTE:
On March
12, 2007
(at 72 Fed.
Reg. 11200),
7225
USEPA
amended
the entry
for conductivity
by
conductance
in the
7226
table
at corresponding
40
CFR
141.23(k)(1)
to
allow the use
of
7227
Standard
Methods
Online
(at www.standardmethods.org),
Method
7228
2510
B
(as
approved
in 1997).
The Board
has instead
cited to the
7229
21
St
edition
of Standard
Methods
for the
Examination
of Water
and
7230
Wastewater
(the printed
version
of Standard
Methods),
since
the
7231
version
of
Method
2510
that appears
in that
printed
volume is
that
7232
cited
by
USEPA
as acceptable
for use.
USEPA
later added
7233
Method
2510 B
from
the
21St
edition of Standard
Methods
as an
7234
approved
alternative
method in
appendix
A
to subpart
C,
added
on
7235
June
3, 2008
(at
73 Fed.
Reg.
31616).
7236
7237
12)
Cyanide.
7238
7239
A)
Manual
distillation
(ASTM
Method
D2036-98
A or Standard
7240
Methods,
18
th,
19
th
or
20
th
ed.:
Method
4500-CN
C),
followed
by
7241
spectrophotometric,
amenable.
7242
7243
i)
ASTM
Method
D2036-98
B or
2036-06
B; or
7244
7245
BOARD
NOTE:
USEPA
added
ASTM Method
2036-06
A
7246
as
an approved
alternative
method
in
appendix
A to
subpart
7247
C
of 40 CFR
141,
added
on June
3,
2008
(at
73 Fed. Reg.
7248
31616).
7249
7250
ii)
Standard
Methods,
18
th
19
th
20
th
or
21
st
ed.: Method
7251
4500-CNG.
7252
7253
BOARD
NOTE:
On
March
12, 2007
(at
72
Fed. Reg.
7254
11200),
USEPA
amended
the entry
for
cyanide
by
7255
spectrophotometric,
amenable,
in
the table at
corresponding
7256
40
CFR 141.23(k)(1)
to
allow
the
use
of Standard
Methods
7257
Online
(at
www.standardmethods.org),
Method
4500-CN
7258
G
(as
approved
in 1999).
The Board
has instead
cited
to
7259
the
21St
edition
of Standard
Methods
for the
Examination
of
7260
Water
and Wastewater
(the
printed
version
of
Standard
7261
Methods),
since
the version
of
Method
4500-CN
that
7262
appears in
that printed
volume
is
that cited
by USEPA
as
7263
acceptable
for
use.
USEPA
later added
Method 4500-CN
7264
G from
the
21St
edition of
Standard Methods
as an
approved
JCAR35O61
1-0814065r01
7265
alternative
method
in appendix
A to
subpart
C,
added
on
7266
June
3,2008
(at
73
Fed.
Reg.
31616).
7267
7268
B)
Manual
distillation
(ASTM
Method
D2036-98
A
or Standard
7269
Methods,
18th,
19th,
or 20th
ed.:
Method
4500-CN
C),
followed
7270
by
spectrophotometric,
manual.
7271
7272
i)
ASTM
Method
D2036-98
A
or
2036-06
A;
7273
7274
ii)
Standard
Methods,
18
th,
19
th,
20
th
or
21St
ed.:
Method
7275
4500-CNE;or
7276
7277
BOARD
NOTE:
On March
12, 2007
(at
72
Fed. Reg.
7278
11200),
USEPA
amended
the
entry
for cyanide
by
7279
spectrophotometric,
manual,
in
the
table
at corresponding
7280
40
CFR
141.23(k)(1)
to
allow
the use
of
Standard
Methods
7281
Online
(at
www.standardmethods.org),
Method
4500-CN
7282
B
(as
approved
in
1999).
The
Board
has
instead
cited
to
the
7283
21st
edition
of Standard
Methods
for
the
Examination
of
7284
Water
and
Wastewater
(the
printed
version
of
Standard
7285
Methods),
since
the
version
of Method
4500-CW
that
7286
appears
in
that
printed
volume
is that
cited
by
USEPA
as
7287
acceptable
for
use.
USEPA
later
added
Method
4500-CN
7288
E from
the
21
st
edition
of Standard
Methods
as an
approved
7289
alternative
method
in
appendix
A
to
subpart
C,
added
on
7290
June 3,
2008
(at
73 Fed.
Reg.
31616).
7291
7292
iii)
USGS
Methods:
Method
1-3300-85.
7293
7294
C)
Spectrophotometric,
semiautomated:Manual
distillation
(ASTM
7295
Method
D2036
98
A or
Standard
Methods,
18th,
19th,
or
20th
ed.:
7296
Method
4500
CN
C),
followed
by
semiautomated
7297
spectrophotometric:
USEPA
Environmental
Inorganic
Methods:
7298
Method
335.4.
7299
7300
D)
Selective electrode:
Standard
Methods,
18
th,
19
th
20
tb
or
21
st
7301
ed.:
Method
4500-CNF.
7302
7303
BOARD NOTE:
On
March
12,
2007
(at
72
Fed. Reg.
11200).
7304
USEPA
amended
the
entry
for
cyanide
by
selective
electrode
in
the
7305
table
at
corresponding
40 CFR
141
.23(k)(1)
to
allow
the
use
of
7306
Standard
Methods
Online
(at
www.standardmethods.org), Method
7307
4500-CN
F
(as
approved
in
1999).
The
Board
has
instead
cited
to
JCAR35O61
1-0814065r01
7308
the
21
St
edition
of
Standard
Methods
for
the
Examination
of Water
7309
and
Wastewater
(the
printed
version
of Standard
Methods),
since
7310
the version
of
Method 4500-CN
that
appears in
that printed
7311
volume
is that
cited
by
USEPA as
acceptable
for use. USEPA
7312
later added
Method 4500-CN
F
from the
21st
edition
of Standard
7313
Methods
as an
approved
alternative
method
in
appendix
A to
7314
subpart
C, added
on
June 3,2008
(at
73
Fed.
Reg. 31616).
7315
7316
E)
UV/DistillationlSpectrophotometric:
Kelada
01.
7317
7318
F)
MicrodistillationfFlow
InjectionlSpectrophotometric:
7319
DistillationlSpectrophotometric:
QuickChem
10-204-00-1
-X.
7320
7321
Ligand
exchange
and amperometry.
7322
7323
ASTMMethodD6888-03.
7324
7325
jj
01 Analytical
Method
OIA-1677
DW.
7326
7327
13)
Fluoride.
7328
7329
A)
Ion
Chromatography.
7330
7331
i)
USEPA
Environmental
Inorganic
Methods:
Method 300.0
7332
or Method
300.1;
7333
7334
ii)
ASTM Method
D4327-97
or D4327M3;
or
7335
I
7336
iii)
Standard
Methods,
18
th
19
th
20
th
or
21st
ed.: Method
7337
4110
B.
7338
7339
BOARD
NOTE:
On March
12, 2007
(at
72
Fed. Reg.
7340
11200),
USEPA
amended
the entry
for fluoride
by
ion
7341
chromatography
in the
table at corresponding
40
CFR
7342
141.23(k)(1)
to allow the
use of
Standard
Methods
Online
7343
(at
www.standardmethods.org),
Method
4110
B
(as
7344
approved
in 2000).
The Board
has
instead cited
to the
21
st
7345
edition
of
Standard
Methods
for
the
Examination
of Water
7346
and Wastewater
(the
printed version
of Standard
Methods),
7347
since the
version
of Method
4110
that
appears
in that
7348
printed volume
is that
cited
by USEPA
as
acceptable
for
7349
use. USEPA
later
added
Method
4110
B from the
21st
7350
edition
of
Standard
Methods
as
an
approved
alternative
JCAR35O61
1-0814065r01
7351
method
in
appendix
A to subpart
C,
added
on June
3, 2008
7352
(at 73
Fed.
Reg.
31616).
7353
7354
B)
Manual
distillation,
colorimetric
SPADNS:
Standard
Methods,
7355
18
th,
19
th
20
th
or
21st
ed.:
Method
4500-F
B
and D.
7356
7357
BOARD
NOTE:
On
March
12,
2007 (at
72 Fed.
Reg.
11200),
7358
USEPA
amended
the
entry
for
fluoride
by
manual
distillation,
7359
colorimetry
SPADNS,
in
the table
at corresponding
40
CFR
7360
141.23(k)(1)
to
allow
the
use of
Standard
Methods
Online
(at
7361
www.standardmethods.org),
Method
4500-F
B
and D
(as
7362
approved
in
1997).
The Board
has
instead
cited
to the
21st
edition
7363
of Standard
Methods
for
the Examination
of Water
and
7364
Wastewater
(the
printed
version
of
Standard
Methods),
since the
7365
version
of
Method
4500-F
that
appears
in
that
printed
volume
is
7366
that
cited
by
USEPA
as acceptable
for use.
USEPA
later
added
7367
Method
4500-F
B
and
D from
the
21st
edition
of
Standard
7368
Methods
as
an approved
alternative
method
in appendix
A
to
7369
subpart
C,
added
on June
3,
2008
(at
73
Fed.
Reg.
31616).
7370
7371
C)
Manual
electrode.
7372
7373
i)
ASTM
Method
D1179-93
B, D1179-99
B,
orDll79-04B;
7374
or
7375
7376
BOARD
NOTE:
USEPA
added
ASTM
Method
Dl
179-04
7377
B
as an
approved
alternative
method
in appendix
A to
7378
subpart
C of
40
CFR 141,
added
on June
3,2008
(at
73
7379
Fed.
Reg.
31616).
7380
7381
ii)
Standard
Methods,
18
th,
19
th
20
th
or
21
st
ed.:
Method
7382
4500-F
C.
7383
7384
BOARD
NOTE:
On March
12,
2007
(at
72 Fed.
Reg.
7385
11200),
USEPA
amended
the
entry
for
fluoride
by
manual
7386
electrode
in
the
table at
corresponding
40 CFR
7387
141.23(k)(1)
to
allow
the
use
of
Standard
Methods
Online
7388
(at
www.standardmethods.org),
Method
4500-F
C (as
7389
approved
in 1997).
The
Board
has instead
cited
to
the
21st
7390
edition
of Standard
Methods
for the
Examination
of
Water
7391
and Wastewater
(the
printed
version
of Standard
Methods),
7392
since
the
version
of
Method
4500-F
that
appears
in that
7393
printed
volume
is that
cited
by
USEPA
as
acceptable
for
JCAR35O61
1-0814065r01
7394
use.
USEPA later
added
Method
4500-V
C
from
the
21
St
7395
edition of Standard
Methods as
an approved alternative
7396
method in appendix
A
to subpart
C,
added on June
3, 2008
7397
(at
73 Fed.
Reg.
31616).
7398
7399
D)
Automated electrode:
Technicon
Methods: Method
380-75
WE.
7400
7401
E)
Automated alizarin.
7402
7403
i)
Standard
Methods,
th,
18 19
th,
20
th
or
21St
ed.: Method
7404
4500-V
E; or
7405
7406
BOARD
NOTE: On March
12, 2007
(at
72
Fed. Reg.
7407
11200),
USEPA
amended
the entry for fluoride
by
7408
automated alizarin
in the table
at corresponding 40
CFR
7409
141.23(k)(1)
to allow the use
of Standard Methods
Online
7410
(at
www.standardmethods.org),
Method 4500-V E
(as
7411
pproved
in
1997).
The Board
has
instead
cited
to the
21st
7412
edition of Standard
Methods
for the Examination
of
Water
7413
and
Wastewater
(the
printed version
of Standard
Methods),
7414
since the
version
of Method
4500-V
that
appears in that
7415
printed volume
is
that cited
by USEPA as
acceptable
for
7416
use. USEPA
later
added Method
4500-V
E from the
21st
7417
edition
of Standard Methods
as an approved
alternative
7418
method
in appendix
A
to subpart
C,
added
on June
3,
2008
7419
(at
73 Fed. Reg. 31616).
7420
7421
ii)
Technicon
Methods: Method
129-71W.
7422
7423
Capillary ion
electrophoresis:
ASTM
Method
D6508-00(2005)e2
7424
(rev. 2).
7425
7426
BOARD
NOTE:
On March 12, 2007
(at
72
Fed.
Reg.
11200),
7427
USEPA amended
the entry
for
fluoride to add capillary
ion
7428
electrophoresis
in the table at corresponding
40 CFR
141
.23(k)(1)
7429
to allow the use of
“Waters Method
D6508, Rev. 2.”
The Board
7430
attempt to locate
a copy of the
method disclosed
that it is an
7431
ASTM method
originally approved
in
2000
and revised in 2005.
7432
The Board has
cited
to the
ASTM Method D6508-00(2005)e2.
7433
7434
14)
Lead.
7435
7436
A)
Atomic
absorption,
furnace technique.
JCAR35O61
1-0814065r01
7437
7438
i)
ASTM
Method
D3559-96
D
or D3559-03
D;
or
7439
7440
ii)
Standard
Methods,
18
t1
-ej
19
th,
or
21St
ed.:
Method
3113
7441
B.
7442
7443
BOARD
NOTE:
On March
12, 2007
(at
72
Fed.
Reg.
7444
11200),
USEPA
amended
the entry
for lead
by
atomic
7445
absorption,
furnace
technique,
in
the
table
at
corresponding
7446
40 CFR
141
.23(k)(1)
to allow
the
use of
Standard
Methods
7447
Online
(at
www.standardmethods.org),
Method
3113
B (as
7448
approved
in
1999).
The Board
has
instead
cited
to
the
21St
7449
edition
of
Standard
Methods
for the
Examination
of Water
7450
and Wastewater
(the
printed
version
of Standard
Methods),
7451
since
the version
of Method
3113
that
appears
in
that
7452
printed
volume
is that
cited
by
USEPA
as acceptable
for
7453
use. USEPA
later
added
Method
3113
B
from
the
21St
7454
edition
of
Standard
Methods
as
an approved
alternative
7455
method
in
appendix
A to
subpart
C,
added
on June
3,
2008
7456
(at
73 Fed.
Reg.
31616).
7457
7458
B)
Inductively-coupled
plasma
— mass
spectrometry:
USEPA
7459
Environmental
Metals
Methods:
Method
200.8.
7460
7461
C)
Atomic
absorption,
platfonn
furnace
technique:
USEPA
7462
Environmental
Metals
Methods:
Method
200.9.
7463
7464
D)
Differential
Pulse
Anodic
Stripping
Voltammetry:
Palintest
7465
Method
1001.
7466
7467
Axially
viewed
inductively-coupled
plasma
— atomic
emission
7468
spectrometry
(AVICP-AES):
USEPA
Methods:
Method
200.5.
7469
7470
BOARD
NOTE:
USEPA
added this
method
as
an
approved
7471
alternative
method
in
appendix
A to
subpart
C
of
40 CFR
141,
7472
added
on June
3, 2008
(at
73 Fed.
Reg.
31616).
7473
7474
15)
Magnesium.
7475
7476
A)
Atomic
absorption.
7477
7478
i)
ASTM
Method
D51 1-93
B
or
D5l 1-03
B;
or
7479
JCAR35O61
1-0814065r01
7480
ii)
Standard
Methods,
18teF19th,
or
21st
ed.:
Method
3111
7481
B.
7482
7483
BOARD
NOTE:
On
March
12,
2007
(at
72 Fed.
Reg.
7484
11200),
USEPA
amended
the entry
for
magnesium
by
7485
atomic
absorption
in the
table at
corresponding
40
CFR
7486
141.23(k)(1)
to
allow
the use
of
Standard
Methods
Online
7487
(at
www.standardmethods.org),
Method
3111
B
(as
7488
approved
in 1999).
The
Board
has
instead
cited
to the
21st
7489
edition
of
Standard
Methods
for
the Examination
of
Water
7490
and
Wastewater
(the
printed
version
of
Standard
Methods),
7491
since
the
version
of Method
3111
that
appears
in
that
7492
printed
volume
is
that cited
by
USEPA
as acceptable
for
7493
use.
USEPA
later
added
Method
3111
B from
the
21st
7494
edition
of
Standard
Methods
as
an approved
alternative
7495
method
in appendix
A to subpart
C,
added
on June
3, 2008
7496
(at
73 Fed.
Reg.
31616).
7497
7498
B)
Inductively-coupled
plasma.
7499
7500
i)
USEPA
Environmental
Metals
Methods:
Method
200.7;
or
7501
7502
ii)
Standard
Methods,
18
th,
19
th
20
th
or
21st
ed.:
Method
7503
3120
B.
7504
7505
BOARD
NOTE:
On
March
12,
2007
(at
72
Fed.
Reg.
7506
11200),
USEPA
amended
the
entry for
magnesium
by
7507
inductively-coupled
plasma
in
the table
at
corresponding
40
7508
CFR 141
.23(k)(1)
to allow
the
use of
Standard
Methods
7509
Online
(at
www.standardmethods.org),
Method
3120
B (as
7510
approved
in
1999).
The
Board
has
instead
cited
to the
21st
7511
edition
of
Standard
Methods
for
the Examination
of
Water
7512
and
Wastewater
(the
printed
version
of Standard
Methods),
7513
since
the
version
of Method
3120
that
appears
in
that
7514
printed
volume
is
that
cited by
USEPA
as
acceptable
for
7515
use.
USEPA
later
added
Method
3120
B from
the
21st
7516
edition
of Standard
Methods
as an
approved
alternative
7517
method
in
appendix
A
to
subpart
C,
added
on
June 3,
2008
7518
(at
73 Fed.
Reg.
31616).
7519
7520
C)
Complexation titrimetric.
7521
7522
i)
ASTM
Method
D511-93
A or
D511-03
A; or
JCAR35061
l-0814065r01
7523
7524
ii)
Standard
Methods,
18t1
or
19
th
ed.:
Method
3500-Mg
Eor
7525
Standard
Methods,
20t1
or
21st
ed.:
Method
3500-Mg
B.
7526
7527
BOARD
NOTE:
On March
12, 2007
(at
72
Fed.
Reg.
7528
11200),
USEPA
amended
the entry
for
magnesium
by
7529
complexation
titrimetric
in
the table at
corresponding
40
7530
CFR
141.23(k)(1)
to allow
the use
of Standard
Methods
7531
Online
(at
www.standardmethods.org).
Method
3500-Mg
B
7532
(as
approved
in
1997).
The
Board
has instead
cited to the
7533
21st
edition of Standard
Methods
for
the
Examination
of
7534
Water
and Wastewater
(the
printed
version
of
Standard
7535
Methods),
since
the version
of Method
3500-Mg
that
7536
appears
in
that
printed
volume
is that cited
by USEPA
as
7537
acceptable
for
use.
USEPA
later
added
Method
3500-Mg
7538
B from
the
21
st
edition
of Standard
Methods
as an
approved
7539
alternative
method in
appendix
A
to
subpart
C.
added
on
7540
June 3,
2008
(at
73
Fed. Reg.
31616).
7541
7542
i44
Standard
Methods,
20th ed.:
Method 3500
Mg B.
7543
7544
j)
Ion
chromatography:
ASTM
Method
D6919-03.
7545
7546
)
Axially viewed
inductively-coupled
plasma
— atomic
emission
7547
spectrometry
(AVICP-AES):
USEPA
Methods:
Method
200.5.
7548
7549
BOARD
NOTE:
USEPA
added
this
method
as an
approved
7550
alternative
method in
appendix
A to subpart
C of 40 CFR
141,
7551
added on
June
3,2008
(at
73
Fed. Reg.
31616).
7552
7553
16)
Mercury.
7554
7555
A)
Manual
cold
vapor technique.
7556
7557
i)
USEPA
Environmental
Metals
Methods:
Method
245.1;
7558
7559
ii)
ASTM
Method
D3223-97
or D3223-02;
or
7560
7561
iii)
Standard
Methods,
18
th
19
th
or
21st
ed.:
Method 3112
7562
B.
7563
7564
BOARD
NOTE: On
March 12,
2007
(at
72 Fed. Reg.
7565
11200),
USEPA amended
the
entry
for mercury
by
manual
JCAR35O61
1-0814065r01
7566
cold
vapor technique
in the table at corresponding
40
CFR
7567
141.23(k)(1)
to allow
the use of Standard
Methods
Online
7568
(at www.standardmethods.org),
Method
3112 B (as
7569
approved in
1999).
The Board has
instead cited to the
21st
7570
edition of Standard
Methods
for the
Examination of Water
7571
and Wastewater
(the
printed version
of Standard Methods),
7572
since the version
of Method
3112 that appears in
that
7573
printed volume
is that cited
by USEPA as
acceptable for
7574
use. USEPA
later added Method
3112 B from the
21st
7575
edition of
Standard
Methods
as an approved
alternative
7576
method
in appendix A to subpart
C,
added on June
3, 2008
7577
(at
73 Fed.
Reg.
31616).
7578
7579
B)
Automated
cold vapor
technique:
USEPA
Inorganic Methods:
7580
Method
245.2.
7581
7582
C)
Inductively-coupled
plasma
— mass spectrometry:
USEPA
7583
Environmental
Metals Methods:
Method
200.8.
7584
7585
17)
Nickel.
7586
7587
A)
Inductively-coupled
plasma.
7588
7589
i)
USEPA Environmental
Metals Methods:
Method 200.7;
or
7590
7591
ii)
Standard
Methods,
th,
18 19
th
20
th
or
21st
ed.:
Method
7592
3120
B.
7593
7594
BOARD
NOTE: On March
12, 2007 (at 72 Fed.
Reg.
7595
11200),
USEPA
amended
the entry for nickel
by
7596
inductively-coupled
plasma
in the table at corresponding
40
7597
CFR 141
.23(k)(1)
to allow the use
of
Standard Methods
7598
Online
(at
www.standardmethods.org),
Method 3120
B
(as
7599
approved in
1999). The Board has
instead cited to the
21
8t
7600
edition
of Standard Methods
for the Examination
of Water
7601
and Wastewater
(the
printed version
of
Standard Methods),
7602
since
the version of Method
3120 that appears in
that
7603
printed volume
is
that cited
by USEPA as acceptable
for
7604
use. USEPA
later added Method
3120
B
from the
21
st
7605
edition
of Standard Methods
as an
approved
alternative
7606
method in appendix
A
to subpart
C,
added
on June 3, 2008
7607
(at
73
Fed.
Reg.
31616).
7608
JCAR35O61
1-0814065r01
7609
B)
Inductively-coupled
plasma —
mass spectrometry:
USEPA
7610
Environmental
Metals
Methods:
Method
200.8.
7611
7612
C)
Atomic
absorption,
platform
furnace technique:
USEPA
7613
Environmental
Metals
Methods:
Method
200.9.
7614
7615
D)
Atomic
absorption,
direct
aspiration
technique:
Standard
Methods,
7616
18
th
19
th
or2lS
t
ed.:
Method
3111 B.
7617
7618
BOARD
NOTE:
On March
12, 2007
(at
72
Fed.
Reg. 11200),
7619
USEPA
amended
the
entry for nickel
by atomic
absorption,
direct
7620
aspiration
technique,
in
the table at
corresponding
40 CFR
7621
141.23(k)(1)
to
allow the
use
of
Standard
Methods
Online
(at
7622
www.standardmethods.org),
Method
3111 B
(as
approved
in
7623
1999).
The Board
has instead
cited
to the
21st
edition
of Standard
7624
Methods
for the
Examination
of Water
and
Wastewater
(the
7625
printed
version
of Standard
Methods),
since the
version of
Method
7626
3111
that appears
in that printed
volume
is
that cited
by
USEPA
as
7627
acceptable
for
use. USEPA
later added
Method
3111 B from
the
7628
21
St
edition
of
Standard
Methods
as
an
approved
alternative
7629
method
in appendix
A to
subpart
C, added
on June
3, 2008
(at
73
7630
Fed.
Reg.
31616).
7631
7632
E)
Atomic
absorption,
furnace
technique:
Standard
Methods,
18
t1
0
f
7633
l9th,or2lsted.:
Method3ll3B.
7634
7635
BOARD NOTE:
On
March 12,
2007
(at
72
Fed. Reg.
11200),
7636
USEPA
amended
the entry
for
nickel
by
atomic
absorption,
7637
furnace technique,
in
the table at
corresponding
40 CFR
7638
141
.23(k)(1)
to
allow the
use
of Standard
Methods
Online
(at
7639
www.standardmethods.org),
Method
3113
B
(as
approved
in
7640
1999).
The
Board has
instead cited
to
the
21st
edition of
Standard
7641
Methods
for
the
Examination
of
Water and
Wastewater
(the
7642
printed
version
of
Standard
Methods),
since the
version
of Method
7643
3113
that
appears
in that
printed
volume
is
that
cited by
USEPA
as
7644
acceptable
for
use. USEPA
later
added
Method
3113 B
from
the
7645
21
5t
edition
of Standard
Methods
as an approved
alternative
7646
method
in appendix
A
to subpart
C,
added
on
June
3,
2008
(at
73
7647
Fed.
Reg.
31616).
7648
7649
Axially
viewed inductively-coupled
plasma
— atomic
emission
7650
spectrometry
(AVICP-AES):
USEPA
Methods:
Method
200.5.
7651
JCAR35O61 1-0814065r01
7652
BOARD
NOTE:
USEPA
added
this
method
as an
approved
7653
alternative
method
in
appendix
A
to
subpart
C
of 40
CFR
141,
7654
added
on
June
3, 2008
(at
73
Fed. Reg.
31616).
7655
7656
18)
Nitrate.
7657
7658
A)
Ion
chromatography.
7659
7660
i)
USEPA
Environmental
Inorganic
Methods:
Method
300.0
7661
or Method
300.1;
7662
7663
ii)
ASTM
Method
D4327-97
or
D4327-03;
7664
7665
iii)
Standard
Methods,
18
th,
19
th
20
th
or
21st
ed.:
Method
7666
4110B;or
7667
7668
BOARD
NOTE:
On
March
12,
2007
(at 72
Fed.
Reg.
7669
11200),
USEPA
amended
the
entry
for
nitrate
by
ion
7670
chromatography
in the
table
at
coffesponding
40
CFR
7671
141.23(k)(1)
to
allow
the
use of
Standard
Methods
Online
7672
(at
www.standardmethods.org),
Method
4110
B (as
7673
approved
in
2000).
The Board
has
instead
cited
to
the
21st
7674
edition
of
Standard
Methods
for
the
Examination of Water
7675
and
Wastewater
(the
printed
version
of Standard
Methods),
7676
since
the version
of Method
4110
that appears
in
that
7677
printed
volume
is
that cited
by
USEPA
as
acceptable
for
7678
use.
USEPA
later
added
Method
4110
B
from
the
21st
7679
edition
of
Standard
Methods
as
an
approved
alternative
7680
method
in
appendix
A to
subpart
C,
added
on June
3,
2008
7681
(at
73 Fed.
Reg.
31616).
7682
7683
iv)
Waters
Test
Method
B-101
1,
available
from
Millipore
7684
Corporation.
7685
7686
B)
Automated
cadmium
reduction.
7687
7688
i)
USEPA
Environmental
Inorganic
Methods:
Method
353.2;
7689
7690
ii)
ASTM
Method
D3867-90
A;
or
7691
7692
iii)
Standard
Methods,
18
th
19
th
20
th
or
21st
ed.:
Method
7693
4500-N0
3
F.
7694
JCAR35O61
1-0814065r01
7695
BOARD
NOTE:
On March
12,
2007
(at 72 Fed.
Reg.
7696
11200),
USEPA
amended
the
entry for
nitrate
by
7697
automated
cadmium
reduction
in the
table
at
corresponding
7698
40 CFR
141.23(k)(1)
to allow
the use
of Standard
Methods
7699
Online
(at
www.standardmethods.org),
Method
4500-NO
7700
F
(as
approved
in 2000).
The
Board
has
instead
cited
to
the
7701
21St
edition
of
Standard
Methods
for
the Examination
of
7702
Water
and Wastewater
(the
printed
version
of Standard
7703
Methods),
since
the
version
of
Method
4500-NOr
that
7704
appears
in that
printed
volume
is
that cited
by
USEPA
as
7705
acceptable
for
use.
USEPA
later added
Method
4500-NO
7706
F
from
the
21
st
edition
of Standard
Methods
as an
approved
7707
alternative
method
in
appendix
A
to
subpart
C,
added
on
7708
June 3,2008
(at
73 Fed.
Reg.
31616).
7709
7710
C)
Ion
selective
electrode.
7711
7712
i)
Standard
Methods,
18
th,
19
th,
20
th
or
21st
ed.:
Method
7713
4500-NO
3
D;
or
7714
7715
BOARD
NOTE:
On
March
12,
2007
(at
72
Fed.
Reg.
7716
11200),
USEPA
amended
the
entry
for nitrate
by
ion
7717
selective
electrode
in
the
table
at corresponding
40
CFR
7718
141
.23(k)(1)
to
allow
the use
of Standard
Methods
Online
7719
(at www.standardmethods.org),
Method
4500-NOr
D
(as
7720
approved
in
2000).
The Board
has
instead
cited
to the
21st
7721
edition
of
Standard
Methods
for
the Examination of
Water
7722
and
Wastewater
(the
printed
version
of Standard
Methods),
7723
since
the version
of Method
4500-NOr
that
appears
in
that
7724
printed
volume
is that
cited
by
USEPA
as
acceptable
for
7725
use.
USEPA
later
added
Method
4500-NOr
D
from
the
7726
21
st
edition
of Standard
Methods
as an approved
alternative
7727
method
in
appendix
A to
subpart
C,
added
on June
3, 2008
7728
(at
73
Fed. Reg.
31616).
7729
7730
ii)
Techuical
Bulletin
601.
7731
7732
D)
Manual
cadmium
reduction.
7733
7734
i)
ASTMMethodD3867-90B;or
7735
7736
ii)
Standard
Methods,
18
th
19
th
20
th
or
21
st
ed.:
Method
7737
4500-NO
3
E.
JCAR35O61
1-0814065r01
7738
7739
BOARD
NOTE:
On March
12,
2007 (at
72 Fed.
Reg.
7740
11200),
USEPA
amended
the entry
for
nitrate
by
manual
7741
cadmium
reduction
in
the table
at
corresponding
40 CFR
7742
141.23(k)(1)
to
allow the
use
of
Standard
Methods
Online
7743
(at
www.standardmethods.org),
Method
4500-NOr
E
(as
7744
approved
in
2000).
The Board
has
instead
cited
to the
21st
7745
edition
of Standard
Methods
for
the
Examination
of
Water
7746
and Wastewater
(the
printed
version
of Standard
Methods),
7747
since
the
version
of
Method
4500-NOr
that
appears
in that
7748
printed
volume
is that
cited
by
USEPA
as
acceptable
for
7749
use. USEPA
later
added
Method
4500-NOr
E from
the
7750
21
st
edition
of
Standard
Methods
as an
approved
alternative
7751
method
in appendix
A
to subpart
C,
added on
June
3,
2008
7752
(at
73 Fed.
Reg.
31616).
7753
7754
Capillary
ion electrophoresis:
ASTM
Method
D6508-00(2005)e2
7755
(rev.
2).
7756
7757
BOARD
NOTE:
On
March
12,
2007
(at
72
Fed. Reg.
11200),
7758
USEPA
amended
the
entry
for
nitrate
to
add
capillary
ion
7759
electrophoresis
in
the
table at
corresponding
40 CFR
141.23(k)(1)
7760
to allow
the
use
of “Waters
Method
D6508,
Rev.
2.” The
Board
7761
attempt
to locate
a
copy of
the method
disclosed
that
it is an
7762
ASTM
method
originally
approved
in
2000
and revised
in
2005.
7763
The
Board has
cited
to the
ASTM
Method
D6508-00(2005)e2.
7764
7765
19)
Nitrite.
7766
7767
A)
Ion
chromatography.
7768
7769
i)
USEPA
Environmental
Inorganic
Methods:
Method
300.0
7770
or
Method
300.1;
7771
7772
ii)
ASTM
Method
D4327-97
or
D4327-03;
7773
7774
iii)
Standard
Methods,
l8t,
i9,
20
th
or
21St
ed.:
Method
7775
4110B;or
7776
7777
BOARD
NOTE:
On
March
12,
2007
(at
72 Fed.
Reg.
7778
11200),
USEPA
amended
the
entry
for
nitrite
by
ion
7779
chromatography
in the
table
at
corresponding
40
CFR
7780
141.23(k)(1)
to
allow
the use
of Standard
Methods
Online
JCAR35O61
1-0814065r01
7781
(at
www.standardmethods.org),
Method
4110 B (as
7782
approved
in
2000).
The Board
has
instead cited to the
21st
7783
edition
of
Standard
Methods for the
Examination
of Water
7784
and Wastewater (the
printed
version
of Standard Methods),
7785
since the version
of Method 4110
that appears in
that
7786
printed
volume
is that cited
by USEPA as acceptable
for
7787
use. USEPA
later
added Method
4110 B from the
21
st
7788
edition of
Standard Methods
as an approved
alternative
7789
method in
appendix A to subpart
C, added
on June 3, 2008
7790
(at
73 Fed.
Reg. 31616).
7791
7792
iv)
Waters Test
Method B-101
1, available from
Millipore
7793
Corporation.
7794
7795
B)
Automated
cadmium reduction.
7796
7797
i)
USEPA
Environmental
Inorganic Methods:
Method
353.2;
7798
7799
ii)
ASTM
Method
D3867-90 A; or
7800
7801
iii)
Standard
Methods,
th
18
19
th 20
th
or
21st
ed.:
Method
7802
4500-N0
3
F.
7803
7804
BOARD NOTE:
On March
12,
2007
(at
72 Fed.
Reg.
7805
11200),
USEPA amended the
entry
for nitrite
by automated
7806
cadmium
reduction
in the
table
at corresponding
40
CFR
7807
141.23(k)(1)
to allow the use
of Standard
Methods
Online
7808
(at
www.standardmethods.org),
Method
4500-NOr
F
(as
7809
approved
in
2000).
The Board
has
instead
cited to the
21st
7810
edition
of
Standard
Methods
for the Examination
of Water
7811
and Wastewater
(the
printed
version of Standard Methods),
7812
since
the
version
of Method
4500-NOr that appears
in that
7813
printed volume
is
that cited
by
USEPA as acceptable
for
7814
use.
USEPA
later
added Method
4500-NO
F from the
7815
21
St
edition of
Standard
Methods
as an approved alternative
7816
method
in
appendix A
to subpart C, added on
June
3, 2008
7817
(at 73 Fed. Reg.
31616).
7818
7819
C)
Manual cadmium
reduction.
7820
7821
i)
ASTMMethodD3867-90
B; or
7822
JCAR35O61
1-0814065r01
7823
ii)
Standard Methods,
18
th
19
th
20
th
or
21st
ed.:
Method
7824
4500-N0
3
E.
7825
7826
BOARD
NOTE: On
March 12,
2007
(at
72 Fed.
Reg.
7827
11200),
USEPA amended
the
entry
for nitrite
by
manual
7828
cadmium
reduction
in
the
table at
corresponding
40 CFR
7829
141.23(k)(1)
to allow
the
use
of
Standard
Methods
Online
7830
(at
www.standardmethods.org),
Method 4500-NO
E
(as
7831
approved
in
2000).
The
Board has
instead
cited to
the
21st
7832
edition
of
Standard
Methods
for the
Examination
of
Water
7833
and
Wastewater
(the
printed
version
of
Standard Methods),
7834
since
the
version
of Method
4500-NOr
that
appears
in that
7835
printed
volume is
that cited by
USEPA
as
acceptable
for
7836
use.
USEPA
later added
Method
4500-NO
E from
the
7837
21
st
edition
of
Standard
Methods
as
an approved
alternative
7838
method in
appendix
A
to subpart
C,
added
on
June 3, 2008
7839
(at
73 Fed.
Reg. 31616).
7840
7841
D)
Spectrophotometric:
Standard
Methods,
18
th,
19
th
20
th
or
21
st
7842
ed.: Method
4500-N0
2
B.
7843
7844
BOARD
NOTE:
On March
12, 2007
(at
72 Fed.
Reg.
11200),
7845
USEPA
amended
the
entry
for nitrite
by
spectrophotometric
in
the
7846
table
at corresponding
40
CFR 141
.23(k)(1)
to allow
the
use
of
7847
Standard
Methods
Online
(at
www.standardmethods.org),
Method
7848
4500-NOv
B
(as
approved
in
2000).
The Board
has instead
cited
7849
to the
21
st
edition
of
Standard Methods
for
the
Examination
of
7850
Water and
Wastewater
(the
printed
version
of
Standard
Methods),
7851
since the version
of Method
4500-NOr
that
appears
in that
printed
7852
volume
is
that
cited by
USEPA
as
acceptable
for
use.
USEPA
7853
later added
Method
4500-NOr
B
from the
21st
edition of
Standard
7854
Methods
as
an
approved
alternative
method
in appendix
A to
7855
subpart C,
added
on June
3,2008
(at
73
Fed. Reg.
31616).
7856
7857
Capillary
ion electrophoresis:
ASTM
Method
D6508-00(2005)e2
7858
(rev.
2).
7859
7860
BOARD
NOTE:
On March
12, 2007
(at
72
Fed. Reg.
11200),
7861
USEPA amended
the
entry for nitrite
to add
capillary
ion
7862
electrophoresis
in
the table
at
corresponding
40 CFR
141.23(kXl)
7863
to allow
the use
of Waters
Method
D6508,
Rev. 2.”
The
Board
7864
attempt
to locate
a
copy of the
method disclosed
that
it
is an
JCAR35061
1-0814065r01
7865
ASTM method
originally
approved
in 2000
and revised
in 2005.
7866
The Board
has cited to
the ASTM
Method
D6508-00(2005)e2.
7867
7868
20)
Orthophosphate
(unfiltered,
without
digestion
or hydrolysis).
7869
7870
A)
Automated
colorimetric,
ascorbic
acid.
7871
7872
i)
USEPA
Environmental
Inorganic
Methods:
Method
365.1;
7873
or
7874
7875
ii)
Standard
Methods,
18
th
19
th
20
th
or
21St
ed.:
Method
7876
4500-P
F.
7877
7878
BOARD
NOTE: USEPA
added
Method 4500-P
F
from the
7879
21
st
edition
of Standard
Methods
as
an
approved
alternative
7880
method in
appendix
A
to subpart
C
of 40
CFR 141, added
7881
on
June 3, 2008
(at
73
Fed.
Reg.
31616). USEPA
also
7882
added
Method
4500-P
F
(as
approved
in
1999)
as available
7883
from
Standard
Methods
Online
(at
7884
www.standardmethods.org).
The
Board has
instead
cited
7885
only
to
the
21st
edition
of Standard
Methods
for the
7886
Examination
of Water
and Wastewater
(the
printed
version
7887
of Standard
Methods),
since
the version
of Method
4500-P
7888
F
that
appears
in
the printed
volume is
the 1999
version
7889
available
from the
online
source.
7890
7891
B)
Single
reagent
colorimetric,
ascorbic
acid.
7892
7893
i)
ASTM
Method
D515-88
A; or
7894
7895
ii)
Standard
Methods,
18
t1,
1
th
20
th
or
21
st
ed.:
Method
7896
4500-PE.
7897
7898
BOARD
NOTE:
USEPA
added
Method
4500-P
E from
7899
the
21
5t
edition
of
Standard
Methods
as
an approved
7900
alternative
method
in appendix
A to subpart
C
of
40 CFR
7901
141, added
on June
3,2008
(at
73
Fed.
Reg.
31616).
7902
USEPA
also added
Method
4500-P E
(as
approved
in
7903
1999)
as
available
from
Standard Methods
Online
(at
7904
www.standardmethods.org).
The
Board
has
instead cited
7905
only
to the
21St
edition
of Standard
Methods
for the
7906
Examination
of Water
and
Wastewater
(the
printed version
7907
of
Standard
Methods),
since the
version of
Method 4500-P
JCAR35O61 1-0814065r01
7908
E that
appears in the printed volume is the
1999
version
7909
available from the online
source.
7910
7911
C)
Colorimetric,
phosphomolybdate:
USGS
Methods: Method
I-
7912
1601-85.
7913
7914
D)
Colorimetric, phosphomolybdate, automated-segmented flow:
7915
USGS
Methods:
Method
1-2601-90.
7916
7917
E)
Colorimetric,
phosphomolybdate, automated discrete:
USGS
7918
Methods: Method 1-2598-85.
7919
7920
F)
Ion Chromatography.
7921
7922
i)
USEPA Environmental Inorganic
Methods:
Method 300.0
7923
or Method
300.1;
7924
7925
ii)
ASTM
Method
D4327-97
or D4327-03; or
7926
7927
iii)
Standard
Methods,
th,
18 19
th 20
th
or
21
st
ed.:
Method
7928
4110B.
7929
7930
BOARD
NOTE:
On March 12, 2007
(at
72
Fed.
Reg.
7931
11200),
USEPA amended the
entry
for orthophosphate
by
7932
ion chromatography in the table
at corresponding 40 CFR
7933
141 .23(k)(1)
to allow the use of Standard
Methods
Online
7934
(at
www.standardmethods.org),
Method
4110 B
(as
7935
approved in 2000). The Board has
instead
cited
to
the
21
st
7936
edition of Standard Methods
for the Examination of Water
7937
and
Wastewater
(the
printed version of Standard Methods),
7938
since the version of Method 4110
that appears in that
7939
printed volume is that
cited by USEPA as acceptable for
7940
use. USEPA later added Method 4110
B from the
21st
7941
edition of Standard Methods
as an approved alternative
7942
method
in appendix A to subpart
C, added on
June
3,
2008
7943
(at
73 Fed. Reg. 31616).
7944
7945
Capillary ion
electrophoresis: Waters Method D6508, rev. 2.
7946
7947
BOARD NOTE: On March 12, 2007
(at 72 Fed. Reg. 11200),
7948
USEPA
amended the entry for orthophosphate
to add capillary ion
7949
electrophoresis
in the table at corresponding 40
CFR
l41.23(k)(1)
7950
to allow the use
of “Waters Method D6508, Rev. 2.” The Board
JCAR35O61
l-0814065r01
7951
attempt
to locate
a copy of the
method
disclosed
that
it is an
7952
ASTM
method
originally
approved
in
2000
and
revised in
2005.
7953
The Board
has cited
to the ASTM
Method
D6508-00(2005)e2.
7954
7955
21)
pH:
electrometric.
7956
7957
A
Electrometric.
7958
7959
4)
USEPA
Inorganic
Methods:
Method
150.1
or
Method 150.2;
7960
7961
Bi4)
ASTM
Method
D1293-95
or D1293-99;
or
7962
7963
Ciii)
Standard
Methods,
18
th, 19
th
20
th
or
21st
ed.:
Method
4500-
7964
H4500H+B.
7965
7966
BOARD
NOTE:
On March
12, 2007
(at 72 Fed.
Reg.
11200),
7967
USEPA
amended
the entry
for pH
by
electrometric
in the
table at
7968
corresponding
40 CFR
141.23(k)(1)
to allow the
use of Standard
7969
Methods
Online
(at www.standardmethods.org),
Method
4500-H
7970
B
(as
approved
in
2000).
The Board
has instead
cited to the
21
st
7971
edition
of Standard
Methods
for the
Examination
of Water
and
7972
Wastewater
(the
printed version
of Standard
Methods),
since
the
7973
version
of Method
4500-H
that appears
in
that
printed volume
is
7974
that
cited by
USEPA
as acceptable
for use.
USEPA later
added
7975
Method
4500-Hf
B from
the
21
st
edition
of
Standard
Methods
as
7976
an approved
alternative
method
in appendix
A to subpart
C,
added
7977
on
June
3,2008
(at 73 Fed.
Reg.
31616).
7978
7979
USEPA
Trnnn
Methods:
Method
150.2.
7980
7981
22)
Selenium.
7982
7983
A)
Atomic
absorption,
hydride.
7984
7985
i)
ASTM
Method
D3859-98
A or D3859-03
A; or
7986
7987
ii)
Standard
Methods,
18
th
0
f
19
th
or
21st
ed.:
Method 3114
7988
B.
7989
7990
BOARD
NOTE:
On
March 12,
2007
(at
72
Fed. Reg.
7991
11200),
USEPA
amended
the
entry
for selenium
by
atomic
7992
absorption,
hydride,
in the
table at
corresponding
40
CFR
7993
141.23(k)(1)
to
allow
the use
of Standard
Methods
Online
JCAR35O61
1-0814065r01
7994
(at www.standardmethods.org),
Method
3114 B
(as
7995
approved
in 1997).
The
Board
has
instead
cited
to
the
21st
7996
edition
of
Standard
Methods
for
the
Examination
of Water
7997
and
Wastewater
(the
printed
version
of
Standard
Methods),
7998
since
the
version
of Method
3114
that
appears
in
that
7999
printed
volume
is that
cited
by
USEPA
as
acceptable
for
8000
use.
USEPA
later
added
Method
3114
B from
the
21
st
8001
edition
of
Standard
Methods
as
an
approved
alternative
8002
method
in
appendix
A to
subpart
C,
added
on
June 3,
2008
8003
(at
73
Fed.
Reg.
31616).
8004
8005
B)
Inductively-coupled
plasma
—
mass
spectrometry:
USEPA
8006
Environmental
Metals
Methods:
Method
200.8.
8007
8008
C)
Atomic
absorption,
platform
furnace
technique:
USEPA
8009
Environmental
Metals
Methods:
Method
200.9.
8010
8011
D)
Atomic
absorption,
furnace
technique.
8012
8013
i)
ASTM
Method
D3859-98
B
or
D3859-03
B; or
8014
8015
ii)
Standard
Methods,
l8tef
19
th
or
21st
ed.: Method
3113
8016
B.
8017
8018
BOARD
NOTE:
On
March
12,
2007
(at 72
Fed.
Reg.
8019
11200),
USEPA
amended
the
entry
for selenium
by
atomic
8020
absorption,
furnace
technique,
in the
table
at
corresponding
8021
40
CFR
141.23(k)(1)
to allow
the
use
of Standard
Methods
8022
Online
(at
www.standardmethods.org),
Method
3113
B (as
8023
approved
in
1999).
The
Board
has instead
cited
to
the
21
st
8024
edition
of Standard
Methods
for
the Examination
of
Water
8025
and Wastewater
(the printed
version
of Standard
Methods),
8026
since
the
version
of
Method
3113
that
appears
in that
8027
printed
volume
is that
cited by
USEPA
as
acceptable
for
8028
use.
USEPA
later
added
Method
3113
B from
the
21st
8029
edition
of Standard
Methods
as an
approved
alternative
8030
method
in
appendix
A to
subpart
C,
added
on
June 3,
2008
8031
(at
73
Fed.
Reg.
31616).
8032
8033
Axially
viewed
inductively-coupled
plasma
— atomic
emission
8034
spectrometry
(AVICP-AES):
USEPA
Methods:
Method
200.5.
8035
JCAR35061
1-0814065r01
8036
BOARD
NOTE:
USEPA
added
this method
as an approved
8037
alternative
method
in appendix
A
to
subpart
C of
40
CFR
141,
8038
added
on June
3,2008
(at
73
Fed. Reg.
31616).
8039
8040
23)
Silica.
8041
8042
A)
Colorimetric,
molybdate
blue:
USGS
Methods:
Method 1-1700-
8043
85.
8044
8045
B)
Colorimetric,
molybdate
blue, automated-segmented
flow:
USGS
8046
Methods:
Method
1-2700-85.
8047
8048
C)
Colorimetric:
ASTM
Method
D859-94,
D859-00,
or D859-
8049
05D859
95.
8050
8051
BOARD
NOTE:
USEPA
added
ASTM
Method
D859-05
as an
8052
approved
alternative
method in
appendix
A
to subpart
C
of 40 CFR
8053
141. added
on June
3,2008
(at
73 Fed. Reg.
31616).
8054
8055
D)
Molybdosilicate:
Standard
Methods,
18
th
or
19
th
ed.:
Method
8056
4500-Si
D or Standard
Methods,
20
th
or
21st
ed.:
Method
4500-
8057
$jQ
2
4500
SiC.
8058
8059
BOARD
NOTE:
On March
12, 2007
(at
72 Fed.
Reg.
11200),
8060
USEPA
amended
the entry
for silica
by
molybdosilicate
in
the
8061
table
at corresponding
40
CFR 141.23(k)(1)
to
allow the use
of
8062
Standard
Methods
Online
(at
www.standardmethods.org),
Method
8063
4500-SiO
2
C
(as
approved
in
1997).
The
Board
has instead
cited
8064
to
the
21
5t
edition
of
Standard
Methods
for
the Examination
of
8065
Water
and Wastewater
(the
printed version
of Standard
Methods),
8066
since
the
version
of Method
4500-SiO
2
that
appears
in that
printed
8067
volume
is that
cited by USEPA
as acceptable
for
use. USEPA
8068
later
added
Method
4500-Si0
2
C
from
the
21St
edition
of Standard
8069
Methods
as an
approved
alternative
method
in appendix
A
to
8070
subpart
C, added
on June 3,
2008
(at
73
Fed. Reg.
31616).
8071
8072
E)
Heteropoly
blue:
Standard
Methods,
or
19
th
ed.: Method
8073
4500-Si
E or Standard
Methods,
20
th
or
21St
ed.:
Method 4500-
8074
SjQ4500
Si
D.
8075
8076
BOARD
NOTE:
On March
12, 2007
(at
72 Fed.
Reg. 11200),
8077
USEPA
amended
the
entry
for silica
by
heteropoly
blue
in the
8078
table at
corresponding
40 CFR
141.23(k)(1)
to allow
the
use of
JCAR35O61 1-0814065r01
8079
Standard
Methods
Online
(at
www.standardmethods.org),
Method
8080
4500-Si0
2D
(as
approved in
1997).
The Board has
instead
cited
8081
to
the
21
St
edition
of Standard Methods
for the Examination
of
8082
Water and
Wastewater
(the printed
version
of Standard
Methods),
8083
since the version
of Method 4500-SiO
2
that
appears in that printed
8084
volume
is that
cited by USEPA
as acceptable for
use. USEPA
8085
later
added
Method 4500-Si02
D from the
21St
edition of Standard
8086
Methods as
an approved alternative
method in
appendix A to
8087
subpart
C,
added
on June
3, 2008 (at 73 Fed.
Reg.
31616).
8088
8089
F)
Automated
method
for
molybdate-reactive silica:
Standard
8090
Methods, l8’
or
19
th
ed.:
Method 4500-Si F
or Standard
Methods,
8091
20
th
or
21
St
ed.: Method 4500
Si 4500-SiO
2
E.
8092
8093
BOARD
NOTE:
On March 12,
2007
(at
72 Fed. Reg.
11200),
8094
USEPA
amended
the entry for silica
by automated
method for
8095
molybdate-reactive
silica
in
the
table at corresponding
40 CFR
8096
141 .23(k)(1)
to allow the use of Standard
Methods
Online
(at
8097
www.standardmethods.org),
Method
2
4500-SiO E
(as
approved in
8098
1997).
The Board
has instead cited
to the
21
5t
edition
of Standard
8099
Methods for
the Examination of
Water and
Wastewater
(the
8100
printed version
of Standard
Methods), since the
version of
Method
8101
4500-SiO
2
that appears in that
printed volume
is that cited by
8102
USEPA
as acceptable for use.
USEPA later
added
Method
4500-
8103
$iQ2
E from
the
21
St
edition
of Standard Methods
as an approved
8104
alternative
method in appendix
A
to subpart
C,
added on June
3,
8105
2008
(at
73
Fed.
Reg.
31616).
8106
8107
G)
Inductively-coupled
plasma.
8108
8109
i)
USEPA
Environmental
Metals Methods:
Method 200.7;
or
8110
8111
ii)
Standard
Methods,
th
18 19
th 20
th
or
21St
ed.: Method
8112
3120B.
8113
8114
BOARD
NOTE:
On
March 12, 2007
(at
72 Fed. Reg.
8115
11200),
USEPA amended
the entry for
silica
by
8116
inductively-coupled
plasma in
the
table at corresponding
40
8117
CFR
141.23(k)(1)
to allow the use
of Standard Methods
8118
Online
(at
www.standardmethods.org),
Method 3120
B
(as
8119
approved in 1999).
The Board
has instead cited to
the
21
st
8120
edition of
Standard Methods
for the Examination
of Water
8121
and
Wastewater
(the printed
version
of Standard
Methods),
JCAR35O61
1-0814065r01
8122
since
the
version
of
Method
3120
that
appears
in that
8123
printed
volume
is that
cited
by
USEPA
as
acceptable
for
8124
use.
USEPA
later added
Method
3120
B
from
the
21st
8125
edition
of Standard
Methods
as
an approved
alternative
8126
method
in appendix
A
to subpart
C,
added
on June
3, 2008
8127
(at
73
Fed.
Reg.
31616).
8128
8129
)
Axially
viewed
inductively-coupled
plasma
— atomic
emission
8130
spectrometry
(AVICP-AES):
USEPA
Methods:
Method
200.5.
8131
8132
BOARD
NOTE:
USEPA
added
this
method
as
an
approved
8133
alternative
method
in appendix
A
to subpart
C
of
40 CFR
141,
8134
added
on June
3,2008
(at
73
Fed.
Reg.
31616).
8135
8136
24)
Sodium.
8137
8138
A)
Inductively-coupled
plasma:
USEPA
Environmental
Metals
8139
Methods:
Method
200.7.
8140
8141
B)
Atomic
absorption,
direct
aspiration:
Standard
Methods,
18
t
0
f
8142
19
th
or
21st
ed.:
Method
3111
B.
8143
8144
BOARD
NOTE:
On
March
12,
2007
(at 72
Fed.
Reg.
11200),
8145
USEPA
amended
the
entry
for
sodium
by
atomic
absorption,
direct
8146
aspiration,
in the
table at
corresponding
40 CFR
141.23(k)(1)
to
8147
allow
the
use of
Standard
Methods
Online
(at
8148
www.standardmethods.org),
Method
3111
B
(as
approved
in
8149
1999).
The
Board
has
instead
cited
to
the
21
tt
edition
of
Standard
8150
Methods
for
the Examination
of
Water
and Wastewater
(the
8151
printed
version
of
Standard
Methods),
since
the
version
of Method
8152
3111
that
appears
in that
printed
volume
is that
cited by
US EPA
as
8153
acceptable
for
use.
USEPA
later
added
Method
3111
B
from the
8154
21
st
edition
of Standard
Methods
as an
approved
alternative
8155
method
in appendix
A
to subpart
C,
added
on June
3, 2008
(at
73
8156
Fed.Reg.31616).
8157
8158
c)
Ion
chromatography:
ASTM
Method
D6919-03.
8159
8160
Axially
viewed
inductively-coupled
plasma
— atomic
emission
8161
spectrometry
(AVICP-AES): USEPA
Methods:
Method
200.5.
8162
JCAR35O61
1-0814065r01
8163
BOARD
NOTE:
USEPA
added this
method
as
an approved
8164
alternative
method
in appendix
A
to subpart
C
of 40
CFR
141,
8165
added
on June
3,
2008
(at
73 Fed. Reg.
31616).
8166
8167
25)
Temperature;
thermometric:
Standard
Methods,
18
th, 19
th
20
th
or
8168
ed.: Method
2550.
8169
8170
BOARD
NOTE:
On March 12, 2007
(at
72 Fed. Reg.
11200),
USEPA
8171
amended
the
entry
for
temperature
by thermometric
in the table at
8172
corresponding
40
CFR 141.23(k)(1)
to allow the use
of Standard
Methods
8173
Online
(at
www.standardmethods.org),
Method
2550
(as approved in
8174
2000).
The
Board
has instead cited
to the
21St
edition
of Standard
8175
Methods
for the
Examination
of Water
and Wastewater
(the printed
8176
version
of
Standard Methods),
since the
version
of Method
2550 that
8177
appears
in that printed
volume is that
cited
byUSEPA as
acceptable
for
8178
use. USEPA
later
added
Method
2550
from the
21
st
edition
of Standard
8179
Methods
as an approved
alternative method
in appendix
A to subpart
C,
8180
added on June
3,2008
(at
73 Fed.
Reg.
31616).
8181
8182
26)
Thallium.
8183
8184
A)
Inductively-coupled
plasma
— mass
spectrometry:
USEPA
8185
Environmental
Metals
Methods:
Method 200.8.
8186
8187
B)
Atomic absorption,
platform
furnace
technique:
USEPA
8188
Environmental
Metals
Methods: Method 200.9.
8189
8190
b)
Sample collection
for antimony,
arsenic
(effective January
22, 2004), asbestos,
8191
barium,
beryllium,
cadmium,
chromium,
cyanide,
fluoride,
mercury, nickel,
8192
nitrate,
nitrite,
selenium,
and thallium
pursuant
to Sections
611.600 through
8193
611.604 must
be
conducted using
the following
sample
preservation,
container,
8194
and
maximum
holding
time
procedures:
8195
8196
BOARD
NOTE:
For
cyanide
determinations
samples must
be adjusted
with
8197
sodium hydroxide
to pH 12 at
the
time of
collection.
When
chilling
is indicated
8198
the sample
must be
shipped and stored
at 4°
C
or less. Acidification
of nitrate or
8199
metals
samples maybe
with a concentrated
acid or
a dilute
(50%
by volume)
8200
solution
of the
applicable
concentrated
acid. Acidification
of samples
for metals
8201
analysis
is encouraged
and allowed
at the laboratory
rather than
at the time
of
8202
sampling provided
the shipping time
and other
instructions
in Section 8.3 of
8203
USEPA
Environmental
Metals
Method 200.7,
200.8, or 200.9
are followed.
8204
8205
1)
Antimony.
JCAR35O61
1-0814065r01
8206
8207
A)
Preservative:
Concentrated
nitric
acid
to
pH less
than
2.
8208
8209
B)
Plastic
or
glass
(hard
or soft).
8210
8211
C)
Holding
time:
Samples
must
be
analyzed
as
soon
after
collection
8212
as
possible,
but
in any
event
within
six
months.
8213
8214
2)
Arsenic.
8215
8216
A)
Preservative:
Concentrated
nitric
acid
to pH
less
than
2.
8217
8218
B)
Plastic
or
glass
(hard
or
soft).
8219
8220
C)
Holding
time:
Samples
must
be analyzed
as
soon
after
collection
8221
as
possible,
but
in
any
event
within
six
months.
8222
8223
3)
Asbestos.
8224
8225
A)
Preservative:
Cool
to
4° C.
8226
8227
B)
Plastic
or glass
(hard
or soft).
8228
8229
C)
Holding
time:
Samples
must
be
analyzed
as
soon
after
collection
8230
as possible,
but
in any
event
within
48
hours.
8231
8232
4)
Barium.
8233
8234
A)
Preservative:
Concentrated
nitric
acid
to pH
less
than
2.
8235
8236
B)
Plastic
or
glass
(hard
or soft).
8237
8238
C)
Holding
time:
Samples
must
be
analyzed
as soon
after
collection
8239
as possible,
but
in any
event
within
six
months.
8240
8241
5)
Beryllium.
8242
8243
A)
Preservative:
Concentrated
nitric
acid
to
pH less
than
2.
8244
8245
B)
Plastic
or
glass
(hard
or
soft).
8246
8247
C)
Holding time:
Samples
must
be
analyzed
as
soon
after
collection
8248
as
possible,
but
in
any event
within
six
months.
JCAR35O61
1-0814065r01
8249
8250
6)
Cadmium.
8251
8252
A)
Preservative:
Concentrated
nitric
acid to pH
less than 2.
8253
8254
B)
Plastic
or glass
(hard or
soft).
8255
8256
C)
Holding
time: Samples
must
be analyzed
as
soon after
collection
8257
as possible,
but in
any
event within
six
months.
8258
8259
7)
Chromium.
8260
8261
A)
Preservative:
Concentrated
nitric
acid to pH
less than
2.
8262
8263
B)
Plastic
or glass
(hard or
soft).
8264
8265
C)
Holding
time:
Samples must
be
analyzed
as soon
after collection
8266
as
possible,
but
in
any
event
within
six
months.
8267
8268
8)
Cyanide.
8269
8270
A)
Preservative:
Cool to
40
C.
Add
sodium
hydroxide
to pH
greater
8271
than 12. See
the analytical
methods
for infonnation
on
sample
8272
preservation.
8273
8274
B)
Plastic or
glass (hard
or soft).
8275
8276
C)
Holding
time: Samples
must
be analyzed
as soon after
collection
8277
as possible,
but
in
any
event
within 14
days.
8278
8279
9)
Fluoride.
8280
8281
A)
Preservative:
None.
8282
8283
B)
Plastic or
glass (hard
or soft).
8284
8285
C)
Holding time:
Samples
must
be
analyzed as
soon after
collection
8286
as possible,
but in
any event within
one month.
8287
8288
10)
Mercury.
8289
8290
A)
Preservative:
Concentrated
nitric acid
to
pH
less
than 2.
8291
JCAR35O61
1-0814065r01
8292
B)
Plastic
or glass (hard or
soft).
8293
8294
C)
Holding
time: Samples
must be analyzed
as soon
after
collection
8295
as
possible, but in any
event
within
28 days.
8296
8297
11)
Nickel.
8298
8299
A)
Preservative:
Concentrated nitric
acid to pH less
than 2.
8300
8301
B)
Plastic
or glass
(hard or soft).
8302
8303
C)
Holding
time:
Samples must be analyzed
as soon
after collection
8304
as
possible, but in
any event
within
six months.
8305
8306
12)
Nitrate, chlorinated.
8307
8308
A)
Preservative:
Cool
to
4°
C.
8309
8310
B)
Plastic
or glass
(hard
or soft).
8311
8312
C)
Holding
time:
Samples
must be
analyzed
as soon after
collection
8313
as
possible, but in
any event within
14
days.
8314
8315
13)
Nitrate,
non-chlorinated.
8316
8317
A)
Preservative:
Concentrated
sulfuric acid to pH less
than
2.
8318
8319
B)
Plastic
or glass
(hard or
soft).
8320
8321
C)
Holding
time:
Samples
must
be analyzed as soon
after collection
8322
as possible, but in
any event within
14 days.
8323
8324
14)
Nitrite.
8325
8326
A)
Preservative:
Cool
to
40
C.
8327
8328
B)
Plastic or glass (hard
or soft).
8329
8330
C)
Holding
time:
Samples must be
analyzed
as
soon after collection
8331
as possible,
but in any event
within 48
hours.
8332
8333
15)
Selenium.
8334
JCAR35O61 1-0814065r01
8335
A)
Preservative:
Concentrated nitric
acid to pH less than 2.
8336
8337
B)
Plastic or glass (hard or
soft).
8338
8339
C)
Holding time:
Samples must be analyzed as
soon after
collection
8340
as possible, but in any
event within six months.
8341
8342
16)
Thallium.
8343
8344
A)
Preservative:
Concentrated nitric acid
to pH less than
2.
8345
8346
B)
Plastic or glass (hard
or
soft).
8347
8348
C)
Holding time: Samples must
be analyzed as soon after collection
8349
as possible, but
in
any
event within six months.
8350
8351
c)
Analyses
under
this Subpart
N
must be
conducted by laboratories that received
8352
approval from USEPA or
the Agency. The Agency
must certify laboratories to
8353
conduct
analyses for antimony, arsenic
(effective January 23, 2006), asbestos,
8354
barium, beryllium, cadmium,
chromium, cyanide,
fluoride, mercury, nickel,
8355
nitrate, nitrite, selenium, and thallium
if the laboratory does as follows:
8356
8357
1)
It analyzes
performance evaluation (PE)
samples, provided by the Agency
8358
pursuant to 35 Ill.
Adm. Code 186, that include those
substances at levels
8359
not in excess of levels expected
in drinking water; and
8360
8361
2)
It achieves quantitative
results
on the analyses within the following
8362
acceptance
limits:
8363
8364
A)
Antimony:
± 30% at greater than
or equal to 0.006 mg/e.
8365
8366
B)
Arsenic: ±
30% at greater than or equal to
0.003
mg/2.
8367
8368
C)
Asbestos: 2 standard deviations
based on study statistics.
8369
8370
D)
Barium: ± 15% at greater
than or equal to 0.15 mg/e.
8371
8372
E)
Beryllium:
± 15% at greater than or equal to 0.00 1
mg/1?.
8373
8374
F)
Cadmium: ± 20% at greater
than
or equal to 0.002 mg/i.
8375
8376
G)
Chromium:
± 15% at greater than or equal to 0.01 mg!e.
8377
JCAR35O61
1-0814065r01
8378
H)
Cyanide:
+ 25%
at greater
than
or equal to
0.1 mg/e.
8379
8380
I)
Fluoride:
+ 10%
at 1
to 10 mg!2.
8381
8382
J)
Mercury:
±
30%
at
greater
than or equal
to
0.0005
mg/i?.
8383
8384
K)
Nickel:
± 15%
at
greater than
or equal
to
0.01 mg/E.
8385
8386
L)
Nitrate:
±
10%
at
greater than
or
equal
to
0.4 mg/s.
8387
8388
M)
Nitrite:
± 15%
at
greater than
or equal
to
0.4 mg/€.
8389
8390
N)
Selenium:
±
20%
at greater
than or equal
to 0.01
mgte.
8391
8392
0)
Thallium:
±
30%
at
greater
than
or equal
to
0.002 mg/2.
8393
8394
BOARD
NOTE:
Derived
from 40
CFR
141.23(k)
(2007)
and
appendix
A
to 40 CFR
141, as
8395
added
at 73
Fed. Reg.
31616
(June
3,
2008)(2003).
8396
8397
(Source:
Amended
at 32 Ill. Reg.
effective
8398
8399
Section
611.612
Monitoring
Requirements
for Old Inorganic
MCLs
8400
8401
a)
Analyses
for the purpose
of determining
compliance
with
the
old
inorganic
8402
MCLs
of Section
611.300
are
required
as follows:
8403
8404
1)
Analyses
for
all
CWSs
utilizing
surface water
sources must
be
repeated
at
8405
yearly
intervals.
8406
8407
2)
Analyses
for
all CWSs
utilizing
only groundwater
sources
must be
8408
repeated
at three-year
intervals.
8409
8410
3)
This
subsection
(a)(3)
corresponds
with 40
CFR
141 .23(1)(3),
which
8411
requires monitoring
for
the repealed
old MCL
for
nitrate
at a
frequency
8412
specified
by the state.
The
Board has
followed
the
USEPA
lead and
8413
repealed that
old
MCL.
This
statement
maintains
structural
consistency
8414
with
USEPA
rules.
8415
8416
4)
This subsection
(a)(4)
corresponds
with 40
CFR
141.23(1)(4)
,which
8417
authorizes
the
state
to determine
compliance
and
initiate
enforcement
8418
action.
This statement
maintains
structural
consistency
with USEPA
8419
rules.
8420
JCAR35O61
1-0814065r01
8421
b)
If the result
of an analysis
made
under subsection
(a)
of
this Section
indicates
that
8422
the
level of
any contaminant
listed
in
Section
611.300
exceeds
the old MCL,
the
8423
supplier must
report
to the Agency
within
seven days
and
initiate
three additional
8424
analyses
at the same
sampling
point within
one month.
8425
8426
c)
When
the
average
of four analyses
made
pursuant
to
subsection
(b) of
this
8427
Section,
rounded
to the same
number of
significant
figures
as
the old MCL
for the
8428
substance
in
question,
exceeds
the
old
MCL, the
supplier
must notify
the Agency
8429
and
give
notice to
the public
pursuant
to Subpart
V of this
Part.
Monitoring
after
8430
public
notification
must be
at a
frequency
designated
by
the
Agency
by a SEP
8431
granted
pursuant
to Section
611.110
and
must continue
until
the
old MCL
has
not
8432
been
exceeded
in
two successive
samples
or until
a
different
monitoring
schedule
8433
becomes
effective
as a condition
to a variance,
an
adjusted standard,
a
site
8434
specific
rule, an enforcement
action, or another
SEP
granted pursuant
to Section
8435
611.110.
8436
8437
d)
This
subsection
(d) corresponds
with 40 CFR
141.23(o),
which pertains
to
8438
monitoring
for the
repealed old
MCL for
nitrate. This
statement
maintains
8439
structural
consistency
with USEPA
rules.
8440
8441
e)
This
subsection
(e) corresponds
with 40
CFR 141.23(p),
which
pertains
to the use
8442
of
existing
data up
until
a
date
long
since
expired.
This
statement
maintains
8443
structural
consistency
with
USEPA
rules.
8444
8445
f)
Except
for arsenic,
for
which
analyses
must be
made in
accordance
with
Section
8446
611.611,
analyses
conducted
to determine
compliance
with
the old MCLs
of
8447
Section
6
11.300
must be
made in
accordance
with
the following
methods,
8448
incorporated
by
reference
in Section
611.102.
8449
8450
1)
Fluoride:
The
methods
specified
in Section
611.611(c)
must
apply for the
8451
purposes
of this
Section.
8452
8453
2)
Iron:
8454
8455
A)
Standard
Methods.
8456
8457
i)
Method
3111 B,
18te19tlI,or21sted.;
8458
8459
ii)
Method
3113
B,
18
th
19
th
or2ls
t
ed.;
8460
8461
iii)
Method
3120
B,
th
18 19
th
e20th
or
21st
ed.
8462
JCAR35O61
1-0814065r01
8463
BOARD
NOTE:
On March
12,
2007
(at
72 Fed.
Reg.
11200),
8464
USEPA
amended
the
entries
for
iron
in
the table
at 40
CFR
8465
143.4(b)
to allow
the
use
of Standard
Methods
Online
(at
8466
www.standardmethods.org),
Method
3111
B, Method
3113 B,
and
8467
Method
3120
B
(as
approved
in 1999).
The Board
has
instead
8468
cited
to the
21
St
edition
of Standard
Methods
for the
Examination
8469
of
Water
and
Wastewater
(the
printed
version
of Standard
8470
Methods’),
since
the
versions
of Method
3111,
Method
3113,
and
8471
Method
3120
that appear
in
that printed
volume
are
those
cited
by
8472
USEPA
as acceptable for
use.
IJSEPA
later
added
Method
3111
8473
B,
Method
3113
B,
and
Method
3120
B from
the
21St
edition
of
8474
Standard
Methods
as
approved
alternative
methods
in
appendix
A
8475
to subpart
C.
added on
June
3. 2008
(at
73 Fed.
Reg.
31616).
8476
8477
B)
USEPA
Environmental
Metals
Methods.
8478
8479
i)
Method
200.7;
or
8480
8481
ii)
Method
200.9.
8482
8483
)
Axially
viewed
inductively-coupled
plasma
—
atomic
emission
8484
spectrometry
(AVICP-AES):
USEPA
Methods:
Method
200.5.
8485
8486
BOARD
NOTE:
USEPA
added this
method
as an
approved
8487
alternative
method
in
appendix
A to
subpart
C
of
40 CFR
141,
8488
added
on June
3,2008
(at
73 Fed.
Reg.
31616).
8489
8490
3)
Manganese.
8491
8492
A)
Standard
Methods.
8493
8494
i)
Method
3111
B,
18tef19th,or215ted.;
8495
8496
ii)
Method
3113
B,
18
th
el9th
or
21St
ed.; or
8497
8498
iii)
Method
3120
B,
18
th
19
th
20
th
or
21St
ed.
8499
8500
BOARD
NOTE:
On
March
12, 2007
(at
72
Fed. Reg.
11200),
8501
USEPA
amended
the
entries
for
manganese
in the
table
at 40
CFR
8502
143
.4(b)
to
allow
the
use of
Standard
Methods
Online
(at
8503
www.standardmethods.org),
Method
3111
B, Method
3113
B, and
8504
Method
3120
B
(as
approved
in
1999).
The Board
has
instead
8505
cited to
the
21
st
edition
of
Standard
Methods
for
the Examination
JCAR35O61
1-0814065r01
8506
of Water
and
Wastewater
(the
printed
version
of Standard
8507
Methods),
since
the
versions
of
Method
3111,
Method
3113,
and
8508
Method
3120
that
appear
in
that printed
volume
are
those
cited
by
8509
USEPA
as
acceptable
for use.
USEPA
later
added
Method
3111
8510
B,Method3ll3B..andMethod3l20Bfromthe2lS
t
editionof
8511
Standard
Methods
as
approved
alternative
methods
in
appendix
A
8512
to
subpart
C,
added
on
June
3, 2008
(at
73
Fed.
Re.
31616).
8513
8514
B)
USEPA
Environmental
Metals
Methods.
8515
8516
i)
Method
200.7;
8517
8518
ii)
Method
200.8;
or
8519
8520
iii)
Method
200.9.
8521
8522
Axially
viewed
inductively-coupled
plasma
— atomic
emission
8523
spectrometry
(AVICP-AES):
USEPA
Methods:
Method
200.5.
8524
8525
BOARD
NOTE:
USEPA
added
this
method
as an
approved
8526
alternative
method
in
appendix
A
to
subpart
C of
40 CFR
141,
8527
added
on
June
3,2008
(at 73
Fed.
Reg.
31616).
8528
8529
4)
Zinc.
8530
8531
A)
Standard Methods.
8532
8533
i)
Method
3111
B,
18te19th,or21sted.;or
8534
8535
ii)
Method
3120
B,
18
th,
19
th
20
th
or
21st
ed.
8536
8537
BOARD
NOTE:
On
March
12,
2007
(at
72
Fed.
Reg.
11200),
8538
USEPA
amended
the
entries
for
zinc
in the
table
at
40
CFR
8539
143.4(b)
to allow
the
use
of Standard Methods
Online
(at
8540
www.standardmethods.org),
Method
3111
B and
Method
3120
B
8541
(as
approved
in
1999).
The
Board
has
instead
cited
to
the
21
st
8542
edition
of Standard
Methods
for
the
Examination
of Water
and
8543
Wastewater
(the
printed
version
of
Standard
Methods),
since
the
8544
versions
of
Method
3111
and
Method
3120
that
appear
in
that
8545
printed
volume
are
those
cited
by
USEPA
as
acceptable
for
use.
8546
USEPA
later
added
Method
3111
B,
Method
3113
B, and
Method
8547
3120
B from
the
21
st
edition
of Standard
Methods
as
approved
JCAR35061
1-0814065r01
8548
alternative
methods in
appendix
A
to subpart
C,
added on
June
3,
8549
2008
(at
73 Fed. Reg.
31616).
8550
8551
B)
USEPA
Environmental
Metals
Methods.
8552
8553
i)
Method200.7;or
8554
8555
ii)
Method 200.8.
8556
8557
)
Axially
viewed
inductively-coupled
plasma
— atomic emission
8558
spectrometry
(AVICP-AES):
USEPA
Methods:
Method 200.5.
8559
8560
BOARD
NOTE:
USEPA added this
method as
an approved
8561
alternative
method
in appendix
A to subpart
C
of 40
CFR 141,
8562
added
on June 3,2008
(at
73 Fed. Reg.
31616).
8563
8564
BOARD
NOTE:
The provisions
of subsections (a) through
(f) of
this Section derive from
40
8565
CFR 141.23(1) through
(p)
(2007)(2002).
Subsections
(f)(2) through
(f)(4) of this
Section relate
8566
exclusively
to additional
State
requirements. The Board
retained
subsection (f) of this
Section
to
8567
set
forth methods
for the inorganic
contaminants
for which there is
a
State-only MCL.
The
8568
methods specified
are
those set
forth in 40 CFR 143
.4(b) (2007) and
appendix
A
to 40 CFR 141,
8569
as added at 73
Fed. Reg. 31616
(June
3, 2008)(2002),
for
secondary
MCLs.
8570
8571
(Source:
Amended
at 32 Ill. Reg.
effective
8572
8573
SUBPART 0: ORGANIC
MONITORING
AND
ANALYTICAL REQUIREMENTS
8574
8575
Section 611.645
Analytical Methods
for
Organic
Chemical
Contaminants
8576
8577
Analysis
for the Section 611.311(a)
VOCs
under Section 611.646;
the
Section
611.311(c)
SOCs
8578
under Section
611.648; the Section
611.310
old MCLs under
Section 611.641;
and for THMs,
8579
TTHMs, and
TTHM
potential
must
be conducted
using the methods
listed
in this Section or by
8580
equivalent
methods
as approved
by the Agency
pursuant to
Section 611.480. All
methods are
8581
from USEPA
Organic
Methods,
unless otherwise
indicated.
All methods are
incorporated by
8582
reference
in Section 611.102.
Other
required
analytical
test procedures
germane
to the conduct
8583
of
these
analyses
are
contained
in the USEPA
document, “Technical
Notes
of Drinking Water
8584
Methods,”
incorporated by reference
in Section
611.102.
8585
8586
Volatile
Organic Chemical
Contaminants
(VOCs).
8587
Contaminant
Analytical Methods
Benzene
502.2, 524.2
Carbon tetrachioride
502.2, 524.2,
551.1
JCAR35O61 1-0814065r01
Chlorobenzene
502.2, 524.2
1 ,2-Dichlorobenzene
502.2,
524.2
1,4-Dichlorobenzene
502.2, 524.2
1,2-Dichioroethane
502.2,
524.2
cis-Dichloroethylene
502.2, 524.2
trans-Dichioroethylene
502.2,
524.2
Dichioromethane
502.2, 524.2
1,2-Dichioropropane
502.2, 524.2
Ethylbenzene
502.2, 524.2
Styrene
502.2, 524.2
Tetrachloroethylene
502.2, 524.2,
551.1
1,1,1-Trichioroethane
502.2, 524.2, 551.1
Trichioroethylene
502.2, 524.2,
551.1
Toluene
502.2,
524.2
1
,2,4-Trichlorobenzene
502.2, 524.2
1,1-Dichioroethylene
502.2,
524.2
1,1,2-Trichloroethane
502.2,
524.2
Vinyl
chloride
502.2,
524.2
Xylenes
(total)
502.2,
524.2
8588
8589
Synthetic
Organic
Chemical
Contaminants
(SOCs).
8590
Contaminant
Analytical
Methods
2,3,7,8-Tetrachlorodibenzodioxin
(2,3,7,8-TCDD
or
Dioxin and Furan
Method
dioxin)
1613
2,4-D
515.2,
555,
515.1, 515.3,
OGWDW Methods,
Method
515.4, ASTM
Method D5317-93or
D5317-98
2,4,5-TP (Silvex)
515.2, 555,
515.1, 515.3,
OGWDW Methods,
Method
515.4,
ASTM
Method D5317-93or
D5317-98
Alachlor
505-, 507,
508.1, 525.2,
551.1
Atrazine
505*!,
507,
508.1, 525.2,
551.1,
Syngenta AG-625
Benzo(a)pyrene
525.2, 550,
550.1
JCAR35O61
1-0814065r01
Carbofuran
531.1, OGWDW
Methods,
Method 531.2,
Standard Methods,
l8
ed.
Supplement,
19
th
ed.,
or
20
th
ed.:
Method
6610 or
Standard
Methods
21st
ed.
or
Standard
Methods
Online:
Method
6610 B
Chiordane
505,
508,
508.1,
525.2
Dalapon
515.1,
552.1,
552.2,
515.3,
OGWDW
Methods,
Method
515.4,
OGWDW
Methods,
Method
552.3
Di(2-ethylhexyl)adipate
506,
525.2
Di(2-ethylhexyl)phthalate
506,
525.2
Dibromochioropropane
(DBCP)
504.1, 551.1
Dinoseb
515.1, 515.2,
515.3,
OGWDW
Methods,
Method 515.4,
555
Diquat
549.1
Endothall
548.1
Endrin
505,
508,
508.1,
525.2,
551.1
Ethylene
Dibromide
(EDB)
504.1,
551.1
Glyphosate
547,
Standard
Methods,
18
th
ed.,
19
th
ed., or
20
th
ed.:
Method
6651
Heptachlor
505,
508,
508.1,
525.2,
551.1
Heptachior
Epoxide
505,
508, 508.1,
525.2,
551.1
Hexachlorobenzene
505,
508, 508.1,
525.2,
551.1
Hexachiorocyclopentadiene
505,
508, 508.1,
525.2,
551.1
Lindane
505,
508, 508.1,
525.2,
551.1
Methoxychior
505,
508,
508.1,
525.2,
551.1
JCAR35O61
1-0814065r01
531.1,
OGWDW
Methods,
Method
531.2,
Standard
Methods,
18
th
ed.
Supplement,
19
th
ed.,
or
20t1
ed.: Method
6610
or
Standard
Methods
21st
ed.
or
Standard
Methods
Online: Method
6610
B
508A
505,
508,
508.1, 525.2
515.1, 515.2,
525.2,
555,
515.3,
OGWDW
Methods,
Method
515.4,
ASTM
Method
D5317-93
or D5317-98(2003)
515.1,
515.2,
555, 515.3,
OGWDW
Methods,
Method
515.4,
ASTM
Method
D5317-93or
D53
17-98(2003)
Simazine
505*1,
507,
508.1, 525.2,
551.2
Toxaphene
505, 508, 525.2,
508.1
8591
8592
Total
Trihalomethanes
(TTHMs).
8593
Contaminant
Total
Trihalomethanes
(TTHMs),
Trihalomethanes
(THMs),
and Maximum
Total Trihalomethane
Potential
8594
8595
State-Only
MCLs
(for which
a
method
is not
listed above).
8596
Contaminant
Analytical
Methods
505,
508,
508.1,
525.2
505, 508
505,
508,
508.1, 525.2
*!denotes
that,
for
the
particular
contaminant,
a nitrogen-phosphorus
detector
should
be
substituted
for the
electron
capture
detector
in
method 505
(or another
approved
method
should be
used)
to
determine
alachlor,
atrazine,
and
simazine
if
lower
detection
limits
are
required.
Oxamyl
PCBs (measured
for
compliance
purposes
as
decchlorobiphenyl)
PCBs
(qualitatively
identified
as Aroclors)
Pentachlorophenol
Picloram
Analytical
Methods
502.2,
524.2,
551.1
Aidrin
DDT
Dieldrin
8597
8598
8599
8600
8601
8602
JCAR35O61
1-0814065r01
8603
denotes
that
Syngenta
Method
AG-625
may not
be used
for
the
analysis
of
atrazine
in
any
8604
system
where
chlorine
dioxide
is
used for
drinking
water
treatment.
In samples
from
all
other
8605
systems,
any
result
for atrazine
generated
by
Syngenta
Method
AG—625
that
is
greater
than
8606
one-half
the
maximum
contaminant
level
(MCL)
(in
other
words,
greater
than
0.001
5mg/i
or
8607
1.5
,ug/)
must be
confirmed
using
another
approved
method
for
this
contaminant
and should
8608
use
additional
volume
of the
original
sample
collected
for
compliance
monitoring.
In
8609
instances
where
a result
from
Syngenta
Method
AG-625
triggers
such
confirmatory
testing,
8610
the confirmatory
result
is to
be
used
to determine
compliance.
8611
8612
BOARD
NOTE:
Derived
from
40 CFR
141.24(e)
(2007)
and
appendix
A
to
40
CFR
141,
as
8613
added
at 73
Fed.
Reg.
31616
(June
3,
2008)(2005).
8614
8615
(Source:
Amended
at 32
Ill.
Reg.
effective
8616
8617
SUBPART
Q: RADIOLOGICAL
MONITORiNG
ANT)
ANALYTICAL
REQUIREMENTS
8618
8619
Section
611.720
Analytical
Methods
8620
8621
a)
The methods
specified
below,
incorporated
by reference
in Section
611.102,
are
8622
to
be
used to
determine
compliance
with Section
611.330,
except
in
cases
where
8623
alternative
methods
have
been approved
in accordance
with
Section
611.480.
8624
8625
1)
Gross
Alpha
and
Beta.
8626
8627
A)
Standard
Methods.
8628
8629
i)
Method
302,
13
th
ed.;
or
8630
8631
ii)
Method
7110
B,
17
th
18
th
19
th
20
th
or
21
st
ed.;
8632
8633
BOARD
NOTE:
On March
12,
2007
(at
72
Fed. Reg.
8634
11200).
USEPA
amended
the
entry
for
gross
alpha and
beta
8635
by
evaporation
in
the
table at
corresponding
40 CFR
8636
141.25(a)
to allow
the use
of Standard
Methods
Online
(at
8637
www.standardmethods.org),
Method
7110 B
(as
approved
8638
in
2000).
The Board
has
instead
cited
to the
21
st
edition
of
8639
Standard
Methods
for
the Examination
of Water
and
8640
Wastewater
(the
printed
version
of
Standard
Methods),
8641
since the
version
of Method
7110
that
appears
in that
8642
printed
volume
is that
cited
by
USEPA
as
acceptable
for
8643
use.
USEPA
later
added Method
7110 B
from the
21
st
8644
edition
of
Standard
Methods
as
an
approved
alternative
JCAR35O61
1-0814065r01
8645
method
in
appendix
A to
subpart
C, added
on June
3, 2008
8646
(at 73
Fed.
Reg.
31616).
8647
8648
B)
USEPA
Interim
Radiochemical
Methods:
page
1;
8649
8650
C)
USEPA
Radioactivity
Methods:
Method
900.0;
8651
8652
D)
USEPA
Radiochemical
Analyses:
page.
1;
8653
8654
E)
USEPA
Radiochemistry
Methods:
Method
00-01;
or
8655
8656
F)
USGS
Methods:
Method
R-1 120-76.
8657
8658
2)
Gross
Alpha.
8659
8660
A)
Standard
Methods,
18
th
19
th
20
th
or
21
st
ed.:
Method
7110
C;
8661
or
8662
8663
BOARD
NOTE:
On
March
12,
2007 (at
72
Fed.
Reg.
11200),
8664
USEPA
amended
the
entry
for
gross
alpha
by
coprecipitation
in the
8665
table
at corresponding
40
CFR
141.25(a)
to allow
the
use
of
8666
Standard
Methods
Online
(at
www.standardmethods.org),
Method
8667
7110
C
(as
approved
in
2000).
The
Board
has
instead
cited
to the
8668
21st
edition
of
Standard
Methods
for
the
Examination
of
Water
and
8669
Wastewater
(the
printed
version
of
Standard
Methods),
since
the
8670
version
of
Method
7110
that
appears
in that
printed
volume
is
that
8671
cited by
USEPA
as
acceptable
for
use.
USEPA
later
added
8672
Method
7110
C
from
the
21st
edition
of
Standard
Methods
as an
8673
approved
alternative
method
in
appendix
A
to
subpart
C,
added
on
8674
June
3, 2008
(at
73 Fed.
Reg.
31616).
8675
8676
B)
USEPA
Radiochemistry
Methods:
Method
00-02.
8677
8678
3)
Radium-226.
8679
8680
A)
ASTM
Methods.
8681
8682
i)
Method
D2460-97D2460
90;
or
8683
8684
ii)
Method
D3454-97;
8685
8686
B)
New
York
Radium
Method;
8687
JCAR35O61
1-0814065r01
8688
C)
Standard
Methods.
8689
8690
i)
Method
304,
13th
ed.;
8691
8692
ii)
Method
305,
13
th
ed.;
8693
8694
iii)
Method
7500-Ra
B,
17
th
18
th 19
th
20
th
or
21st
ed.;
or
8695
8696
iv)
Method
7500-Ra
C,
17
th
18
th 19
th
20
th
or
21st
ed.;
8697
8698
BOARD
NOTE:
On March
12, 2007
(at
72
Fed.
Reg.
11200),
8699
USEPA
amended
the
entries for
radium-226
in the
table
at
8700
corresponding
40 CFR
141.25(a)
to allow
the use of Standard
8701
Methods
Online
(at www.standardmethods.org),
Method
7500-Ra
8702
B
and
C
(as
approved
in
2000).
The Board
has instead
cited to the
8703
21
st
edition
of
Standard
Methods
for the
Examination
of
Water and
8704
Wastewater
(the
printed version
of Standard
Methods),
since
the
8705
version
of Method
7500-Ra
that
appears
in
that
printed
volume is
8706
that
cited
by USEPA
as acceptable
for use.
USEPA later
added
8707
Method
7500-Ra
B and
C
from
the
21st
edition
of Standard
8708
Methods as
an approved
alternative
method
in appendix
A to
8709
subpart
C, added on
June 3, 2008
(at
73
Fed.
Reg.
31616).
8710
8711
D)
USDOE
Manual:
Method Ra-04;
8712
8713
E)
USEPA
Interim
Radiochemical
Methods:
pages 13
and 16;
8714
8715
F)
USEPA
Radioactivity
Methods:
Methods
903.0,
903.1;
8716
8717
G)
USEPA
Radiochemical
Analyses:
page
19;
8718
8719
H)
USEPA
Radiochemistry
Methods:
Methods
Ra-03,
Ra-04; or
8720
8721
I)
USGS
Methods.
8722
8723
i)
Method
R-1
140-76; or
8724
8725
ii)
MethodR-1141-76.
8726
8727
1)
Georgia
Radium
Method.
8728
8729
4)
Radium-228.
8730
JCAR35O61
1-0814065r01
8731
A)
Standard
Methods,
17
th
1
gth
19
th
20
th
or
21st
ed.: Method
8732
7500-RaD;
8733
8734
BOARD
NOTE:
On
March
12,
2007
(at
72 Fed.
Reg.
11200),
8735
USEPA
amended
the
entry
for radium-228
by
radiochemical
in
the
8736
table
at corresponding
40
CFR
141.25(a)
to allow
the
use
of
8737
Standard
Methods
Online
(at
www.standardmethods.org),
Method
8738
7500-Ra
D
(as
approved
in 2000).
The
Board
has instead
cited
to
8739
the
21
st
edition
of Standard
Methods
for the
Examination
of Water
8740
and
Wastewater
(the
printed
version
of
Standard
Methods),
since
8741
the
version
of Method
7500-Ra
that
appears
in
that
printed
volume
8742
is
that cited
by
USEPA
as acceptable
for use.
USEPA
later
added
8743
Method
7500-Ra
D
from
the
21st
edition
of Standard
Methods
as
8744
an
approved
alternative
method
in
appendix
A
to
subpart
C,
added
8745
on
June
3,2008
(at
73
Fed.
Reg.
31616).
8746
8747
B)
New
York
Radium
Method;
8748
8749
C)
USEPA
Interim
Radiochemical
Methods:
page
24;
8750
8751
D)
USEPA
Radioactivity
Methods:
Method
904.0;
8752
8753
E)
USEPA
Radiochemical
Analyses:
page
19;
8754
8755
F)
USEPA
Radiochemistry
Methods:
Method
Ra-05;
8756
8757
G)
USGS
Methods:
Method
R-1142-76;er
8758
8759
H)
New
Jersey
Radium
Method
8760
8761
Georgia
Radium
Method.
8762
8763
5)
Uranium.
8764
8765
A)
Standard
Methods,
17
th,
18
t,
19t1,
20
th
or
21St
ed.:
Method
8766
7500-U
C;
8767
8768
BOARD
NOTE:
On
March
12, 2007
(at 72 Fed.
Reg.
11200),
8769
USEPA
amended
the
entries
for uranium
by
radiochemical
and
8770
alpha
spectrometry
in
the table
at corresponding
40
CFR
14
1.25(a)
8771
to
allow
the
use
of
Standard
Methods
Online
(at
8772
www.standardmethods.org),
Method
7500-U
C
(as
approved
in
8773
2000).
The
Board
has
instead
cited to
the
21st
edition
of
Standard
JCAR35061
1-0814065r01
8774
Methods
for
the
Examination
of Water
and
Wastewater
(the
8775
printed
version
of
Standard
Methods),
since
the version
of Method
8776
7500-U
that
appears
in that
printed
volume
is that
cited
by
USEPA
8777
as
acceptable
for
use. USEPA
later
added
Method
7500-U
B from
8778
the
21
St
edition
of
Standard
Methods
as
an
approved
alternative
8779
method
in
appendix
A
to
subpart
C,
added
on June
3,
2008
(at
73
8780
Fed.
Reg.
31616).
8781
8782
B)
Standard
Methods,
20th
ed.: Method
3125;
8783
8784
C)
ASTM
Methods.
8785
8786
i)
Method
D2907-97;
8787
8788
ii)
Method
D3972-97
or D3972-02;
8789
8790
iii)
Method
D5174-97
or D5174-02;
or
8791
8792
iv)
Method
D5673-03
or Method
5673-05;
8793
8794
BOARD
NOTE:
USEPA
added this
method
as
an
approved
8795
alternative
method
in appendix
A
to subpart
C
of 40 CFR
141,
8796
added
on
June 3,
2008
(at
73 Fed.
Reg.
31616).
8797
8798
D)
USEPA
Radioactivity
Methods:
Methods
908.0,
908.1;
8799
8800
E)
USEPA
Environmental
Metals
Methods:
Method
200.8;
8801
8802
F)
USEPA
Radiochemical
Analyses:
page
33;
8803
8804
G)
USEPA
Radiochemistry
Methods:
Method
00-07;
8805
8806
H)
USDOE
Manual:
Method
U-02
or
U-04;
or
8807
8808
I)
USGS
Methods.
8809
8810
i)
MethodR-1180-76;
8811
8812
ii)
MethodR-1181-76;or
8813
8814
iii)
MethodR-1182-76.
8815
JCAR35O61
1-0814065r01
8816
BOARD
NOTE:
If uranium
(U)
is
determined
by
mass,
a conversion
8817
factor
of 0.67 pCi/jig
of
uranium
must be used.
This conversion
factor
is
8818
based
on the
1:1 activity
ratio of
234
U and
238
U
that
is characteristic
of
8819
naturally
occurring
uranium.
8820
8821
6)
Radioactive
Cesium.
8822
8823
A)
ASTM
Methods.
8824
8825
i)
Method
D2459-72;
or
8826
8827
ii)
Method
D3649-91
or D3649-98a;
8828
8829
B)
Standard
Methods.
8830
8831
i)
Method
7120,
19
th
20
th
or
21
st
ed.;
or
8832
8833
ii)
Method
7500-Cs
B,
th,
17
18
th
19
th
020
th
or
21st
ed.;
8834
8835
BOARD
NOTE:
On March
12, 2007
(at
72
Fed.
Reg.
11200),
8836
USEPA
amended
the entries
for radioactive
cesium
in the
table
at
8837
corresponding
40 CFR
141.25(a)
to allow the
use of Standard
8838
Methods
Online
(at www.standardmethods.org),
Method
7120
(as
8839
approved
in
1997)
and
Method
7500-Cs
B
(as approved
in 2000).
8840
The
Board
has
instead
cited to
the
21
st
edition
of Standard
Methods
8841
for the Examination
of
Water
and Wastewater
(the
printed version
8842
of Standard
Methods),
since the
versions
of
Method
7120 and
8843
Method
7500-Cs
that
appear
in that printed
volume
are those
cited
8844
by USEPA
as
acceptable
for use.
USEPA
later added
Method
8845
7120 and
Method
7500-Cs
B
from the
21st
edition of
Standard
8846
Methods
as an
approved
alternative
method
in appendix
A to
8847
subpart
C,
added on June
3,2008
(at
73
Fed.
Reg. 31616).
8848
8849
C)
USDOE
Manual:
Method
4.5.2.3;
8850
8851
D)
USEPA
Interim
Radiochemical
Methods:
page
4;
8852
8853
E)
USEPARadioactivityMethods:
Methods
901.0, 901.1;
8854
8855
F)
USEPA Radiochemical
Analyses:
page
92;
or
8856
8857
G)
USGS
Methods.
8858
8859
i)
MethodR-1110-76;or
JCAR35061 1-0814065r01
8860
8861
ii)
Method
R-1111-76.
8862
8863
7)
Radioactive
Iodine.
8864
8865
A)
ASTM
Methods.
8866
8867
i)
D3649-91
or
D3649-98a;
or
8868
8869
ii)
D4785-93
or
D4785-98;
8870
8871
B)
Standard
Methods.
8872
8873
i)
Method
7120,
19
th
20
th
or
21st
ed.;
8874
8875
ii)
Method
7500-I
B,
17
th
18
th
19
th
20
th
or
21st
ed.;
8876
8877
iii)
Method
7500-I
C,
17
th,
18
th
19
th
20
th
or
21st
ed.;
or
8878
8879
iv)
Method
7500-ID,
17
th,
1
gth
19
th
20
th
or
21st
ed.;
8880
8881
BOARD
NOTE:
On
March
12,
2007
(at
72
Fed.
Reg.
11200),
8882
USEPA
amended
the
entries
for
radioactive
iodine
in the
table
at
8883
corresponding
40 CFR
141.25(a)
to
allow
the use
of Standard
8884
Methods
Online
(at
www.standardmethods.org),
Method
7120
(as
8885
approved
in
1997)
and
Method
7500-I
B,
C,
and
D
(as
approved
in
8886
2000).
The
Board
has
instead
cited
to
the
21st
edition
of Standard
8887
Methods
for
the
Examination
of
Water
and
Wastewater
(the
8888
printed
version
of Standard
Methods), since
the versions
of
8889
Method
7120
and
Method
7500-I
that
appear
in
that
printed
8890
volume
are
those
cited
by
USEPA
as
acceptable
for use.
USEPA
8891
later
added
Method
7500-I
B,
C,
and
D
from
the
21st
edition
of
8892
Standard
Methods
as
an
approved
alternative
method
in
appendix
8893
A
to
subpart
C,
added
on
June 3,2008
(at
73
Fed.
Reg.
31616).
8894
8895
C)
USDOE
Manual:
Method
4.5.2.3;
8896
8897
D)
USEPA
Interim
Radiochemical
Methods:
pages
6, 9;
8898
8899
E)
USEPA
Radiochemical
Analyses:
page
92;
or
8900
8901
F)
USEPA
Radioactivity
Methods:
Methods
901.1,
902.0.
8902
JCAR35061 1-0814065r01
8903
8)
Radioactive
Strontium-89
& 90.
8904
8905
A)
Standard
Methods.
8906
8907
i)
Method
303,
13t1
ed.;
or
8908
8909
ii)
Method
7500-Sr
B,
17
th
1
gth
19
th
20
th
or
21st
ed.;
8910
8911
BOARD
NOTE:
On
March
12,
2007
(at
72
Fed.
Reg.
8912
11200),
USEPA
amended
the
entry
for
radioactive
8913
strontium
in
the
table
at corresponding
40 CFR
141.25(a)
to
8914
allow
the
use of
Standard
Methods
Online
(at
8915
www.standardmethods.org),
Method
7500-Sr
B
(as
8916
approved
in
2001).
The
Board
has
instead
cited
to
the
21st
8917
edition
of
Standard
Methods
for the
Examination
of
Water
8918
and
Wastewater
(the
printed
version
of
Standard
Methods),
8919
since
the
version
of
Method
7500-Sr
that
appears
in
that
8920
printed
volume
is
that
cited
by
USEPA
as
acceptable
for
8921
use.
USEPA
later
added
Method
7500-Sr
B
from
the
21st
8922
edition
of Standard
Methods
as an
approved
alternative
8923
method
in appendix
A
to
subpart
C, added
on
June
3,
2008
8924
(at
73
Fed. Reg.
31616).
8925
8926
B)
USDOE Manual
Methods.
8927
8928
i)
Method
Sr-01;
or
8929
8930
ii)
Method
Sr-02;
8931
8932
C)
USEPA Interim
Radiochemical
Methods:
page
29;
8933
8934
D)
USEPA Radioactivity
Methods:
Method
905.0;
8935
8936
E)
USEPA Radiochemical
Analyses:
page
65;
8937
8938
F)
USEPA Radiochemistry
Methods:
Method
Sr-04;
or
8939
8940
G)
USGS
Methods:
Method
R-1
160-76.
8941
8942
9)
Tritium.
8943
8944
A)
ASTM
Methods:
Method
D4107-91
or
D4107-98;
8945
JCAR35O61
1-0814065r01
8946
B)
Standard Methods.
8947
8948
i)
Method
306,
13
th
ed.;
or
8949
8950
ii)
Method
7500-
3
H
B,
17
th,
18
th 19
th 020
th
or
21
st
ed.;
8951
8952
BOARD
NOTE: On
March 12, 2007
(at
72 Fed. Reg.
8953
11200),
USEPA
amended
the entry for
tritium
in
the
table
8954
at corresponding 40
CFR 141.25(a)
to allow the use of
8955
Standard
Methods
Online
(at www.standardmethods.org),
8956
Method 7500-
3
HB
(as
approved
in
2000).
The Board
has
8957
instead
cited to the
21
st
edition of Standard
Methods
for the
8958
Examination
of Water
and Wastewater
(the
printed version
8959
of
Standard
Methods),
since
the
version
of Method 7500-
8960
3
H that
appears
in
that
printed volume is
that cited
by
8961
USEPA as
acceptable
for
use. USEPA
later added Method
8962
7500-
3
H
B from the
21st
edition of Standard
Methods
as an
8963
approved
alternative
method
in appendix
A to subpart
C,
8964
added
on June 3,2008
(at
73 Fed. Reg. 31616).
8965
8966
C)
USEPA Interim
Radiochemical
Methods: page
34;
8967
8968
D)
USEPA Radioactivity
Methods:
Method
906.0;
8969
8970
E)
USEPA
Radiochemical Analyses:
page
87;
8971
8972
F)
USEPA
Radiochemistry
Methods: Method
H-02; or
8973
8974
G)
USGS
Methods: MethodR-1171-76.
8975
8976
10)
Gamma Emitters.
8977
8978
A)
ASTM Methods.
8979
8980
i)
Method
D3649-91
or
D3649-98a;
or
8981
8982
ii)
Method
D4785-93
or
D4785-OOa;
8983
8984
B)
Standard
Methods.
8985
8986
i)
Method
7120,
19
th 20
th
or
21st
ed.;
8987
8988
ii)
Method 7500-Cs
B,
l7t1,
18
th
19
th
20
th
or
21
st
ed.; or
JCAR35O61
1-0814065r01
8989
8990
iii)
Method
7500-TB,
17
th,
18
th 19
th
20
th
or
21st
ed.;
8991
8992
BOARD
NOTE:
On March
12. 2007
(at 72 Fed.
Reg.
11200),
8993
USEPA
amended
the
entries
for
gamma
emitters
in the
table
at
8994
corresponding
40
CFR 141
.25(a)
to
allow
the use
of
Standard
8995
Methods
Online
(at www.standardmethods.org),
Method 7120
(as
8996
approved
in
1997),
Method
7500-Cs
B (as
approved
in
2000),
and
8997
Method
7500-I
B
(as
approved
in 2000).
The Board
has instead
8998
cited
to the
21
st
edition
of Standard
Methods
for
the Examination
8999
of Water
and
Wastewater
(the
printed
version
of
Standard
9000
Methods),
since
the versions
of Method
7120,
Method 7500-Cs,
9001
and
Method 75
00-I that appear
in that
printed
volume
are
those
9002
cited
by USEPA
as acceptable
for
use.
USEPA later
added
9003
Method
7150,
Method
7500-Cs
B, and
Method
7500-I B from
the
9004
21
st
edition
of Standard
Methods
as an
approved
alternative
9005
method
in appendix
A to subpart
C,
added
on June
3, 2008
(at
73
9006
Fed. Reg.
31616).
9007
9008
C)
USDOE
Manual:
Method Ga-01-R;
9009
9010
D)
USEPA
Radioactivity
Methods:
Methods
901.0,
901.1, or 902.0;
9011
9012
E)
USEPA
Radiochemical
Analyses:
page 92; or
9013
9014
F)
USGS
Methods:
Method
R-1 110-76.
9015
9016
b)
When
the
identification
and
measurement
of radionuclides
other
than those
listed
9017
in
subsection
(a) of this Section
are required,
the
following
methods,
incorporated
9018
by
reference
in Section
611.102,
are to
be used, except
in
cases
where
alternative
9019
methods
have been
approved
in
accordance
with
Section
6
11.480:
9020
9021
1)
“Procedures
for Radiochemical
Analysis
of
Nuclear Reactor
Aqueous
9022
Solutions,”
available
from
NTIS.
9023
9024
2)
HASL
Procedure
Manual,
HASL
300, available
from
ERDA Health
and
9025
Safety Laboratory.
9026
9027
c)
For
the
purpose
of monitoring
radioactivity
concentrations
in drinking
water, the
9028
required
sensitivity
of
the
radioanalysis
is defined
in terms
of a detection
limit.
9029
The
detection
limit must
be that
concentration
which
can
be counted
with a
9030
precision
of
plus or minus
100 percent
at the
95 percent
confidence
level (1.96u,
9031
where u is
the standard
deviation
of the net
counting
rate
of the
sample).
JCAR35O61
l-0814065r01
9032
9033
1)
To determine
compliance
with Section
611.330(b),
(c),
and (e),
the
9034
detection
limit
must not
exceed
the
concentrations
set
forth
in
the
9035
following
table:
9036
Contaminant
Detection
Limit
Gross
alpha
particle
3
pCi/2
activity
Radium-226
1 pCi/e
Radium-228
1
pCi/i?
Uranium
1
tg/
9037
9038
BOARD
NOTE:
Derived
from 40
CFR
141.25(c)
Table B(2007)(2005).
9039
9040
2)
To
determine
compliance
with Section
611.330(d),
the
detection
limits
9041
must
not exceed
the concentrations
listed
in the following
table:
9042
Radionuclide
Detection
Limit
Tritium
1,000 pCi/E
Strontium-89
10
pCi/2
Strontium-90
2 pCi/C
Iodine-131
1 pCi/f
Cesium-134
10
pCi/f
Gross
beta
4 pCi/f
Other radionuclides
1/10
of applicable
limit
9043
9044
BOARD
NOTE:
Derived from
40
CFR 141.25(c)
Table
C(2007)(2005).
9045
9046
d)
To
judge
compliance
with
the MCLs
listed
in Section
611.330,
averages
of
data
9047
must
be
used
and
must
be
rounded
to
the same
number
of
significant
figures
as
9048
the MCL
for the
substance
in
question.
9049
9050
BOARD
NOTE:
Derived
from 40
CFR
141.25
(2007)
and appendix
A
to
40
CFR
141, as
added
9051
at 73
Fed. Reg.
31616 (June
3,
2008)(2005).
9052
9053
(Source:
Amended
at 32
111. Reg.
effective
9054
9055
SUBPART
S: GROUNDWATER
RULE
9056
9057
Section
611.802
Groundwater
Source
Microbial
Monitoring
and
Analytical
Methods
9058
9059
a)
Triggered
source
water
monitoring.
9060
JCAR35O61 1-0814065r01
9061
1)
General
requirements.
A
GWS
supplier
must
conduct
triggered
source
9062
water
monitoring
if
the
following
conditions
exist:
9063
9064
A)
The
supplier
does
not
provide
at least
4-log
treatment
of
viruses
9065
(using
inactivation,
removal,
or an
Agency-approved
combination
9066
of
4-log
virus
inactivation
and
removal)
before
or
at the
first
9067
customer
for
each
groundwater
source;
and
9068
9069
B)
The supplier
is notified
that
a sample
collected
pursuant
to Section
9070
611.521
is
total
coliform-positive,
and
the
sample
is not
9071
invalidated
by
the
Agency
pursuant
to
Section
611.523.
9072
9073
2)
Sampling
requirements.
A GWS
supplier
must
collect,
within
24
hours
9074
after
notification
of
the total
coliform-positive
sample,
at
least
one
9075
groundwater
source
sample
from
each
groundwater
source
in use
at the
9076
time
the
total
coliform-positive
sample
was
collected
pursuant
to
Section
9077
611.521,
except
as provided
in
subsection
(a)(2)(B)
of
this
Section.
9078
9079
A)
The
Agency
may,
by
a SEP
issued
pursuant
to
Section
611.110,
9080
extend
the
24-hour
time
limit
on a
case-by-case
basis
if
it
9081
determines
that
the
supplier
cannot
collect
the
groundwater
source
9082
water
sample
within
24
hours
due
to circumstances
beyond
the
9083
supplier’s
control.
In
the
case
of
an extension,
the
Agency
must
9084
specify
how
much
time
the
supplier
has
to
collect
the sample.
9085
9086
B)
If approved
by
the
Agency,
a supplier
with
more
than
one
9087
groundwater
source
may
meet
the
requirements
of
this
subsection
9088
(a)(2)
by
sampling
a
representative
groundwater
source
or
sources.
9089
If directed
by
the
Agency
by
a SEP
issued
pursuant
to
Section
9090
611.110,
the
supplier
must
submit
for
Agency
approval
a
triggered
9091
source
water
monitoring
plan
that
identifies
one or
more
9092
groundwater
sources
that
are
representative
of each
monitoring
site
9093
in the
system’s
sample
siting
plan
pursuant
to Section
611.521
and
9094
that
the
system
intends
to use
for
representative
sampling
pursuant
9095
to this
subsection
(a).
9096
9097
C)
A
GWS
supplier
that
serves
1,000
or
fewer
people
may
use
a
9098
repeat
sample
collected from
a
groundwater
source
to
meet
both
9099
the requirements
of
Section
611.522
and
to satisfy
the
monitoring
9100
requirements
of
subsection
(a)(2)
of
this
Section
for that
9101
groundwater
source
only
if the
Agency
approves
the
use of
E. coli
9102
as
a fecal
indicator
for
source
water
monitoring
pursuant
to this
9103
subsection (a)
by
a SEP
issued
pursuant
to Section
611.110.
If
the
JCAR35O61
1-0814065r01
9104
repeat sample
collected
from
the
groundwater
source
is E.coli
9105
positive,
the system
must comply
with
subsection
(a)(3)
of this
9106
Section.
9107
9108
3)
Additional
requirements.
If the Agency
does
not
require
corrective
action
9109
pursuant
to Section
61 l.803(a)(2)
for a fecal
indicator-positive
source
9110
water
sample
collected
pursuant
to subsection
(a)(2)
of this Section
that
is
9111
not
invalidated
pursuant
to subsection
(d) of
this Section,
the
system must
9112
collect five
additional
source
water samples
from the
same source
within
9113
24
hours
after
being
notified of
the fecal indicator-positive
sample.
9114
9115
4)
Consecutive
and wholesale
systems.
9116
9117
A)
In addition
to
the
other requirements
of this subsection
(a),
a
9118
consecutive
GWS
supplier
that has a
total coliform-positive
sample
9119
collected
pursuant
to Section
611.521
must
notify
the
wholesale
9120
systems
within 24
hours
after
being
notified of
the total coliform
9121
positive
sample.
9122
9123
B)
In addition
to the
other requirements
of this
subsection
(a),
a
9124
wholesale
GWS
supplier
must comply
with the
following
9125
requirements:
9126
9127
i)
A wholesale
GWS
supplier
that receives
notice
from a
9128
consecutive
system
it serves
that a
sample collected
9129
pursuant
to Section
611.521
is total
coliform-positive
must,
9130
within
24 hours
after being
notified,
collect a
sample
from
9131
its groundwater
sources
pursuant
to
subsection
(a)(2) of
this
9132
Section
and analyze
it
for
a fecal indicator
pursuant
to
9133
subsection
(c) of
this Section.
9134
9135
ii)
If the
sample collected
pursuant
to
subsection
(a)(4)(B)(i)
9136
of
this
section
is fecal
indicator-positive,
the wholesale
9137
GWS
supplier must
notify
all consecutive
systems
served
9138
by that
groundwater
source
of the
fecal
indicator
source
9139
water
positive within
24 hours
of
being
notified
of the
9140
groundwater
source
sample
monitoring
result
and must
9141
meet
the requirements
of
subsection
(a)(3)
of
this Section.
9142
9143
5)
Exceptions
to
the
triggered
source water
monitoring
requirements.
A
9144
GWS
supplier
is not
required
to
comply
with
the source water
monitoring
9145
requirements
of
subsection
(a) of this
Section
if either
of the following
9146
conditions
exists:
JCAR35O61
l-0814065r01
9147
9148
A)
The
Agency determines,
and documents
in
writing,
by
a SEP
9149
issued
pursuant
to Section
611.110,
that the total
coliform-positive
9150
sample
collected
pursuant
to Section
611.52
1
is caused
by a
9151
distribution
system
deficiency;
or
9152
9153
B)
The
total
coliform-positive
sample
collected
pursuant
to Section
9154
611.521 is
collected
at a location
that meets
Agency
criteria
for
9155
distribution
system
conditions
that will cause
total coliform
9156
positive
samples.
9157
9158
b)
Assessment
source
water
monitoring.
If directed
by the
Agency
by
a SEP issued
9159
pursuant to
Section
611.110,
a GWS
supplier
must
conduct
assessment
source
9160
water monitoring
that meets
Agency-determined
requirements
for such
9161
monitoring.
A GWS
supplier
conducting
assessment
source
water monitoring
9162
may
use
a triggered
source
water
sample
collected
pursuant
to subsection
(a)(2)
of
9163
this Section
to
meet
the requirements
of subsection
(b)
of
this
Section.
Agency-
9164
determined
assessment
source
water monitoring
requirements
may include
the
9165
following:
9166
9167
1)
Collection
of a total
of
12 groundwater
source
samples
that
represent
each
9168
month the
system
provides groundwater
to the public;
9169
9170
2)
Collection
of samples
from
each
well,
unless
the
system
obtains
written
9171
Agency
approval
to conduct
monitoring
at
one
or
more wells
within
the
9172
GWS
that
are
representative
of multiple
wells
used by that
system and
9173
which
draw water
from
the
same hydrogeologic
setting;
9174
9175
3)
Collection
of a
standard sample
volume
of at
least
100 m
for fecal
9176
indicator
analysis,
regardless
of
the
fecal indicator
or analytical
method
9177
used;
9178
9179
4)
Analysis
of all
groundwater
source samples
using
one of the
analytical
9180
methods
listed
in
subsection
(c)(2) of
this Section
for the
presence of
E.
9181
coli, enterococci,
or
coliphage;
9182
9183
5)
Collection
of
groundwater
source samples
at
a
location
prior
to
any
9184
treatment
of the groundwater
source
unless the
Agency approves
a
9185
sampling
location
after
treatment;
and
9186
9187
6)
Collection
of groundwater
source
samples
at
the
well itself,
unless
the
9188
system’s
configuration
does not
allow
for
sampling at
the well itself
and
9189
the
Agency
approves
an
alternate
sampling
location
by a SEP
issued
JCAR35O61
1-0814065r01
9190
pursuant
to
Section
611.110
that is
representative
of
the
water quality
of
9191
that
well.
9192
9193
c)
Analytical
methods.
9194
9195
1)
A
GWS
supplier
subject
to the
source
water
monitoring
requirements
of
9196
subsection
(a) of
this
Section
must
collect
a standard
sample
volume
of
at
9197
least
100
m2 for
fecal
indicator
analysis,
regardless
of the
fecal
indicator
9198
or
analytical
method
used.
9199
9200
2)
A
GWS
supplier
must
analyze
all groundwater
source
samples
collected
9201
pursuant
to subsection
(a)
of
this
Section
using
one
of the analytical
9202
methods
listed in
subsections
(c)(2)(A)
through
(c)(2)(C)
of this
Section,
9203
subject
to
the
limitations
of subsection
(c)(2)(D)
of
this Section,
for
the
9204
presence
of E. coli,
enterococci,
or coliphage:
9205
9206
A)
E.
coli:
9207
9208
i)
Autoanalysis
Colilert
System,
Standard
Methods,
20t
9209
21ed.,
Method
9223
B.
9210
9211
ii)
Colisure
Test,
Standard
Methods,
20
th
or
21
st
ed.,
Method
9212
9223
B.
9213
9214
iii)
Membrane
Filter
Method
with
MI Agar,
USEPA
Method
9215
1604.
9216
9217
iv)
m-ColiBlue24
Test.
9218
9219
v)
E*Colite
Test.
9220
9221
vi)
EC-M1JG,
Standard
Methods,
20t
ed.,
Method
9221
F.
9222
9223
vii)
NA—IvIIJG,
Standard
Methods,
20
th
ed.,
Method
9222
G.
9224
9225
yjji
Colilert-18,
Standard
Methods,
20
th
or
21st
ed.,
Method
9226
9222
G.
9227
9228
BOARD
NOTE:
EC-MUG
(Standard
Methods,
Method
9221F)
or
9229
NA-MUG
(Standard
Methods,
Method
9222G)
can
be
used
for
E.
9230
coli
testing
step, as
described
in
Section
611.526(a)
or (b)
afler
use
9231
of
Standard
Methods,
Method
9221 B,
9221 D,
9222
B, or 9222
C.
9232
On
June 3,
2008
(at
73
Fed.
Reg.
31616),
USEPA
added
appendix
JCAR35O61
1-0814065r01
9233
A to subpart
C of
40
CFR 141, which
authorized
alternative
9234
methods
to
those
listed
for E.
coli by
Colilert
and Colisure
and
9235
added Colilert-18
in
the table
at
corresponding
40 CFR
9236
141.402(c)(2)
to allow
the use
of the
21st
edition of
Standard
9237
Methods
for the
Examination
of Water
and
Wastewater
and
9238
Standard
Methods
Online
(at
www.standardrnethods.org),
Method
9239
9223
B
(as
approved
in
1997).
The
Board
has instead
cited
only
to
9240
the
21
St
edition
of Standard
Methods
for the
Examination
of Water
9241
and Wastewater
(the
printed
version
of
Standard
Methods),
since
9242
the
version of
Method 9223
B that appears
in
that
printed
volume
9243
is that
cited
by USEPA
as acceptable
for
use. USEPA
also added
9244
the
version of
Method 9223
B that appears
in the
edition
of
9245
Standard
Methods
as to Colilert-18.
9246
9247
B)
Enterococci:
9248
9249
i)
Multiple-Tube
Technique,
Standard
Methods,
20
th
ed.,
9250
Method
9230
B or Standard
Methods
Online,
Method 9230
9251
B.
9252
9253
BOARD
NOTE: On
June 3, 2008
(at
73 Fed.
Reg.
31616),
9254
USEPA
added
appendix
A to
subpart C
of 40
CFR 141,
9255
which authorized
alternative
methods
to those
listed
for
9256
enterococci
by multiple-tube
technique
at corresponding
40
9257
CFR
141
.402(c)(2)
to
allow
the use
of the
Standard
9258
Methods
Online
(at
www.standardmethods.org),
Method
9259
9230
B
(as
approved
in
2004).
9260
9261
ii)
Membrane
Filter
Technique,
Standard
Methods,
20
th
ed.,
9262
Method
9230
C,
and
USEPA
Method
1600.
9263
9264
BOARD
NOTE:
The holding
time
and
temperature
for
9265
groundwater
samples
are specified
in subsection
(c)(2)(D)
9266
of this
Section,
rather
than as
specified
in
Section
8 of
9267
USEPA
Method
1600.
9268
9269
iii)
Enterolert.
9270
9271
BOARD
NOTE:
Medium
is available
through IDEXX
9272
Laboratories,
Inc., at the
address
set
forth in Section
9273
611.102(b).
Preparation
and use
of
the
medium
must be
as
9274
set forth
in
the
article
that
embodies
the method
as
9275
incorporated
by
reference
in Section
611.102(b).
JCAR35O61
1-0814065r01
9276
9277
C)
Coliphage:
9278
9279
i)
Two-Step
Enrichment
Presence-Absence
Procedure,
9280
USEPA
Method 1601.
9281
9282
ii)
Single
Agar Layer
Procedure,
USEPA Method
1602.
9283
9284
D)
Limitation
on
methods
use. The
time from
sample
collection
to
9285
initiation
of
analysis may
not exceed
30
hours.
The GWS
supplier
9286
is encouraged
but
is not required
to hold
samples
below 10°C
9287
during
transit.
9288
9289
d)
Invalidation
of a fecal
indicator-positive
groundwater
source sample.
9290
9291
1)
A
GWS supplier
may
obtain
Agency
invalidation
of a fecal
indicator-
9292
positive
groundwater
source
sample
collected
pursuant
to subsection
(a) of
9293
this
Section only
under either
of the
following
conditions:
9294
9295
A)
The supplier
provides
the Agency
with
written notice
from the
9296
laboratory
that
improper
sample
analysis
occurred;
or
9297
9298
B)
The
Agency determines
and
documents
in
writing
by a SEP
issued
9299
pursuant
to Section
611.110
that
there
is substantial
evidence
that a
9300
fecal
indicator-positive
groundwater
source
sample
is
not related
to
9301
source
water
quality.
9302
9303
2)
If the Agency
invalidates
a fecal
indicator-positive
groundwater
source
9304
sample,
the GWS
supplier must
collect
another
source
water
sample
9305
pursuant
to subsection
(a)
of this
Section
within
24 hours
after
being
9306
notified
by the Agency
of
its invalidation
decision,
and
the
supplier
must
9307
have it analyzed
for
the same fecal
indicator
using
the
analytical
methods
9308
in
subsection
(c) of
this Section.
The
Agency
may
extend
the 24-hour
9309
time
limit
on a case-by-case
basis
if the supplier
cannot
collect
the source
9310
water
sample
within
24
hours due
to
circumstances
beyond
its control.
In
9311
the
case of
an extension,
the Agency
must
specify how
much time
the
9312
system has
to collect
the
sample.
9313
9314
e)
Sampling
location.
9315
9316
1)
Any groundwater
source
sample
required
pursuant
to subsection
(a)
of this
9317
Section
must
be collected
at a location
prior
to any
treatment
of the
JCAR35O61
1-0814065r01
9318
groundwater
source
unless
the
Agency
approves
a
sampling
location
after
9319
treatment.
9320
9321
2)
If the supplier’s
system
configuration
does
not
allow
for
sampling
at
the
9322
well
itself,
it
may collect
a
sample
at
an
Agency-approved
location
to meet
9323
the requirements
of
subsection
(a)
of this
Section
if the
sample
is
9324
representative
of
the water
quality
of that
well.
9325
9326
f)
New
sources.
If
directed
by the
Agency
by a
SEP issued
pursuant
to
Section
9327
611.110,
a
GWS
supplier
that places
anew
groundwater
source
into
service
after
9328
November
30,
2009
must
conduct
assessment
source
water monitoring pursuant
9329
to
subsection
(b) of
this Section.
If directed
by the
SEP,
the system
must
begin
9330
monitoring
before
the
groundwater
source
is used
to
provide
water
to
the
public.
9331
9332
g)
Public
Notification.
A GWS
supplier
with
a groundwater
source
sample
collected
9333
pursuant
to subsection
(a) or
(b)
of
this
Section
that
is
fecal
indicator-positive
and
9334
which
is
not invalidated
pursuant
to
subsection
(d)
of this
Section,
including
a
9335
consecutive
system
supplier
served
by
the
groundwater
source,
must
conduct
9336
public
notification
pursuant
to Section
611.902.
9337
9338
h)
Monitoring
Violations.
A
failure
to
meet
the requirements
of subsections
(a)
9339
through
(f)
of this
Section
is a monitoring
violation
that
requires
the GWS
9340
supplier
to provide
public
notification
pursuant
to Section
611.904.
9341
9342
BOARD
NOTE:
Derived
from
40 CFR
141.402
(2007)
and
appendix
A
to
40 CFR
141,
9343
as
added
at
73 Fed.
Reg. 31616
(June 3,2008),
as added
at
71
Fed.
Reg. 65574
(No-8
9344
2006).
9345
9346
(Source:
Amended
at 32
Ill. Reg.
effective
9347
9348
SUBPART
U: CONSUMER
CONHDENCE
REPORTS
9349
9350
Section
611.884
Required
Additional
Health
Information
9351
9352
a)
All reports
must
prominently
display
the
following
language:
“Some
people
may
9353
be
more
vulnerable
to contaminants
in
drinking
water than
the
general
population.
9354
Immuno-compromised
persons
such as
persons
with
cancer undergoing
9355
chemotherapy,
persons
who
have
undergone
organ
transplants,
people
with
9356
HIV/AIDS
or other
immune
system
disorders,
some
elderly,
and
infants
can
be
9357
particularly
at risk
from
infections.
These
people
should
seek
advice
about
9358
drinking
water
from
their
health
care
providers.
USEPA
or Centers
for
Disease
9359
Control
and Prevention
guidelines
on appropriate
means
to lessen
the risk
of
9360
infection
by Cryptosporidium
and
other
microbial
contaminants
are
available
JCAR35O61
1-0814065r01
from
the
USEPA
Safe
Drinking
Water
Hotline
(800-426-4791).”
b)
A
supplier
that
detects
arsenic
above
0.005 mg!e
and up
to
and including
0.0 10
mg/2
must
do
the
following:
1)
The supplier
must
include
in
its report
a
short
informational
statement
about
arsenic,
using
the following
language:
“While
your
drinking
water
meets
USEPA’s
standard
for
arsenic,
it does
contain
low
levels
of
arsenic.
USEPA’s
standard
balances
the current
understanding
of
arsenic’s
possible
health
effects
against
the
costs of
removing
arsenic
from
drinking
water.
USEPA
continues
to
research
the
health
effects
of
low levels
of
arsenic,
which
is
a
naturally-occurring
mineral
known
to
cause
cancer
in
humans
at
high concentrations
and
is
linked
to other
health
effects
such
as skin
damage
and
circulatory
problems.”;
or
2)
The
supplier
may
write
its
own
educational
statement,
but
only in
consultation
with
the
Agency.
c)
A
supplier
that
detects
nitrate
at levels
above
5
mgte,
but below
the MCL,
must
do
the following:
1)
The supplier
must
include
a
short informational
statement
about
the
impacts
of
nitrate
on
children,
using
the following
language:
“Nitrate
in
drinking
water
at levels
above
10
ppm is
a
health
risk for
infants
of less
than
six months
of age.
High
nitrate
levels
in
drinking
water
can
cause
blue
baby
syndrome.
Nitrate
levels
may
rise quickly
for
short
periods
of
time
because
of rainfall
or
agricultural
activity.
If
you
are caring
for
an
infant
you
should
ask advice
from
your
health
care
provider”;
or
2)
The
CWS
supplier
may write
its
own educational
statement,
but
only
in
consultation
with
the
Agency.
4
A CWS
supplier
that
detects
lead above
the
action
level
in
more
than
five
percent,
and
up
to and
including
ten
percent,
of homes
sampled
must
do
the
following:
Every report
must
include
the
following
lead-specific
information:
The
CWS
supplier
must include
a short
informational
statement
about
the
special
impact
of lead
on
children,
using
the
following
language:
“Infants
and
young
children
are typically
more vulnerable
to
lead in
drinking
water
than
the
general
population.
It
is possible
that
lead levels
at your
home
may
be
higher
than
at
other homes
in
the
community
as a result
of
materials
used in
your
home’s
plumbing.
If
you are
concerned
about
9361
9362
9363
9364
9365
9366
9367
9368
9369
9370
9371
9372
9373
9374
9375
9376
9377
9378
9379
9380
9381
9382
9383
9384
9385
9386
9387
9388
9389
9390
9391
9392
9393
9394
9395
9396
9397
9398
9399
9400
9401
9402
9403
JCAR35O61
1-0814065r01
9404
elevated
lead
levels
in
your
home’s
water,
you
may
wish to
have your
9405
water
tested
and
flush
your
tap
for
30
seconds
to vo
minutes
before
using
9406
tap
water.
Additional
information
is available
from
the
USEPA
Safe
9407
Drinking
Water
Hotline
(800
426
4791)”;
or
9408
9409
jJ
A
short
informational
statement
about lead
in
drinking
water
and
its
9410
effects
on
children.
The
statement
must
include
the
following
9411
information:
9412
9413
If
present,
elevated
levels
of lead
can
cause
serious
health
9414
problems,
especially
for
pregnant
women
and
young
children.
9415
Lead
in drinking
water
is
primarily
from
materials
and
components
9416
associated
with
service
lines
and
home
plumbing.
[NAME
OF
9417
SIJPPLIER1
is responsible
for providing
high quality
drinking
9418
water,
but
cannot
control
the
variety
of
materials
used in
plumbing
9419
components.
When
your
water has
been
sitting
for
several
hours,
9420
you
can minimize
the
potential
for
lead exposure
by
flushing
your
9421
tap
for
30
seconds
to two
minutes
before
using
water for
drinking
9422
or
cooking.
If
you
are
concerned
about lead
in your
water,
you
9423
may
wish
to have
your
water
tested.
Information
on lead
in
9424
drinking
water, testing
methods,
and
steps
you
can
take
to
9425
minimize
exposure
is
available
from
the
Safe Drinking
Water
9426
Hotline
or
at http
://www.epa.
gov/safewater/lead.
9427
9428
The CWS
supplier
may
write its
own educational
statement,
but
only
in
9429
consultation
with
the Agency.
9430
9431
A
supplier
may
write its
own
educational
statement,
but only
in
9432
consultation
with
the
Agency.
9433
9434
e)
A
CWS
supplier
that detects
TTHM
above
0.080 mg/e,
but below
the
MCL
in
9435
Section
611.312,
as an
annual
average,
monitored
and
calculated
under
the
9436
provisions
of
former
Section
611.680,
must include
the
health
effects
language
9437
prescribed
by Appendix
A of
this Part.
9438
9439
f)
Until
January
22,
2006,
a CWS
supplier
that
detects
arsenic
above
0.010
mg/e
and
9440
up to and
including
0.05
mg/C
must
include
the
arsenic
health
effects
language
9441
prescribed
by
Appendix
A to
this Part.
9442
9443
BOARD
NOTE:
Derived
from
40
CFR
141.154
(2007),
as
amended
at 72
Fed. Reg.
9444
7782
(October
12,
2007)(2003).
9445
9446
(Source:
Amended
at 32
Ill. Reg.
effective
JCAR35O61
1-0814065r01
9447
9448
SUBPART
Z:
ENHANCED
TREATMENT
FOR CRYPTOSPORIDIUM
9449
9450
Section
611.1004
Source
Water
Monitoring
Requirements:
Analytical
Methods
9451
9452
a)
Cryptosporidium.
A
supplier
must analyze
for
Cryptosporidium
using
USEPA
9453
OGWDW
Methods,
Method
1623 (05)
or
USEPA
OGWDW
Methods,
Method
9454
1622
(05),
each
incorporated
by
reference
in Section
611.102.
9455
9456
1)
The
supplier
must
analyze at
least a 10
£
sample
or
a packed
pellet
volume
9457
of at least
2 m2
as
generated
by
the
methods
listed
in
subsection
(a) of
this
9458
Section.
A supplier
unable to
process a
10 £ sample
must analyze
as much
9459
sample volume
as can
be
filtered
by two
filters
approved
by USEPA
for
9460
the methods
listed
in
subsection
(a)
of this
Section,
up
to
a
packed
pellet
9461
volume
of
at least 2
m.
9462
9463
2)
Matrix
spike
(MS)
samples.
9464
9465
A)
MS samples,
as
required
by the methods
in
subsection
(a)
of this
9466
Section,
must
be
spiked and
filtered
by a
laboratory
approved
for
9467
Cryptosporidium analysis
pursuant
to Section
611.1005.
9468
9469
B)
If
the volume
of
the MS
sample is
greater
than
10 2, the
supplier
9470
may filter
all but 10 2
of the MS
sample
in
the field, and
ship the
9471
filtered
sample
and the
remaining
10 2 of
source
water
to the
9472
laboratory.
In
this case,
the laboratory
must
spike the
remaining
9473
10 2 of
water and filter
it through
the filter
used to collect
the
9474
balance
of the
sample
in the field.
9475
9476
3)
Flow cytometer-counted
spiking
suspensions
must
be used for
MS
9477
samples
and
ongoing
precision
and recovery
samples.
9478
9479
b)
E.
coli.
A supplier
must
use
methods
for
enumeration
of
E.
coli in
source water
9480
approved
in 40
CFR 136.3(a),
incorporated
by
reference in
Section 611.102.
9481
9482
1)
The
time
from sample
collection
to initiation
of analysis
may
not exceed
9483
30 hours,
unless
the
supplier meets
the
condition
of subsection
(b)(2)
of
9484
this Section.
9485
9486
2)
The
Agency may,
by a SEP
issued
pursuant to
Section 61
Li 10, approve
9487
on a
case-by-case
basis
the
holding
of an E.
coli
sample
for up to
48 hours
9488
between
sample
collection
and initiation
of
analysis
if it
determines
that
9489
analyzing
an
E. coli sample
within
30 hours
is not
feasible.
E. coli
JCAR35O61
1-0814065r01
9490
samples
held between
30
to 48
hours
must
be
analyzed
by the
9491
Autoanalysis
Colilert
System
reagent version
of Standard
Methods,
18
th,
9492
19
th,
or
20
th
ed.,
Method
9223
B,
as
listed
in 40
CFR 136.3(a),
9493
incorporated
by
reference
in
Section 611.102.
9494
9495
3)
A supplier
must
maintain
the
temperature
of its
samples
between
0°C and
9496
10°C
during storage
and transit
to the
laboratory.
9497
9498
41
The
supplier
may
use
the
membrane
filtration,
two—step
procedure
9499
described
in Standard
Methods,
20t
ed.,
Method
9222 D
and
G,
9500
incorporated
by
reference
in Section
611.102.
9501
9502
BOARD
NOTE:
On June
3, 2008
(at
73 Fed.
Reg.
31616),
USEPA
added
9503
appendix
A to
subpart
C
of 40
CFR
141,
which
authorized
alternative
9504
methods
to those
listed for
E. coli by
multiple-tube
technique
at
9505
corresponding
40
CFR
141.402(c)(2)
to
allow
the
use of Standard
9506
Methods
for the Examination
of Water
and Wastewater,
Method
9222
D
9507
andG.
9508
9509
c)
Turbidity.
A
supplier
must
use methods
for turbidity
measurement
approved
in
9510
Section6ll.531(a).
9511
9512
BOARD
NOTE:
Derived from
40 CFR
141.704
(2007) and
appendix
A to
40
CFR
141,
as
9513
added
at 73 Fed.
Reg. 31616
(June
3,
2008)(2006).
9514
9515
(Source:
Amended
at 32 Ill.
Reg.
effective
9516
9517
Section 611.1007
Source
Water
Monitoring
Requirements:
Grandfathering
Previously
9518
Collected
Data
9519
9520
a)
Initial
source
monitoring
and
Cryptosporidium
samples.
9521
9522
1)
A supplier
may
comply
with
the
initial source
water monitoring
9523
requirements
of Section
611.1001(a)
by
grandfathering
sample
results
9524
collected
before
the supplier
is
required
to begin
monitoring
(i.e.,
9525
previously
collected
data).
To be grandfathered,
the sample
results
and
9526
analysis
must meet
the
criteria
in
this Section
and the Agency
must
9527
approve
the
use
of
the
data
by a SEP
issued
pursuant
to Section
611.110.
9528
9529
2)
A
filtered
system
supplier
may
grandfather
Cryptosporidium
samples
to
9530
meet
the requirements
of Section
611.1001(a)
when
the supplier
does
not
9531
have corresponding
E.
coli and
turbidity
samples.
A supplier
that
9532
grandfathers
Cryptosporidium
samples
without
E.
coli
and
turbidity
JCAR35O61
1-0814065r01
9533
samples
is not
required to
collect E.
coli and
turbidity
samples
when
it
9534
completes
the
requirements
for Cryptosporidium
monitoring
pursuant
to
9535
Section
611.1001(a).
9536
9537
b)
E. coli
sample
analysis.
The
analysis of
E. coli samples
must
meet the
analytical
9538
method
and approved
laboratory
requirements
of Sections
611.1004
and
9539
611.1005.
9540
9541
c)
Cryptosporidium
sample
analysis.
The analysis
of Cryptosporidium
samples
must
9542
meet
the
criteria
in this subsection
(c).
9543
9544
1)
Laboratories
analyzed
Cryptosporidium
samples using
one of
the
9545
following
analytical
methods:
9546
9547
A)
USEPA
OGWDW
Methods,
Method
1623 (05),
incorporated
by
9548
reference
in Section
611.102;
9549
9550
B)
USEPA
OGWDW
Methods,
Method
1622
(05),
incorporated
by
9551
reference
in
Section 611.102;
9552
9553
C)
USEPA
OGWDW
Methods,
Method
1623
(01),
incorporated
by
9554
reference
in
Section 611.102;
9555
9556
D)
USEPA OGWDW
Methods,
Method 1622
(01), incorporated
by
9557
reference
in Section
611.102;
9558
9559
E)
USEPA
OGWDW
Methods,
Method
1623 (99),
incorporated
by
9560
reference
in Section
611.102;
or
9561
9562
F)
USEPA
OGWDW
Methods,
Method 1622
(99), incorporated
by
9563
reference
in Section
611.102.
9564
9565
2)
For each
Cryptosporidium
sample,
the
laboratory
analyzed
at least 10
£ of
9566
sample
or at least
2 m of packed
pellet
or as much
volume
as
could
be
9567
filtered
by
two
filters
that
USEPA
approved
for
the methods
listed in
9568
subsection
(c)(1)
of
this
Section.
9569
9570
d)
Sampling
location.
The
sampling
location
must meet
the conditions
in Section
9571
611.1003.
9572
9573
e)
Sampling
frequency.
Cryptosporidium
samples
were
collected
no less frequently
9574
than
each
calendar
month on
a
regular
schedule, beginning
no
earlier than
January
9575
1999. Sample
collection
intervals
may
vary for
the conditions
specified
in
JCAR35O61 1-0814065r01
9576
Section
611.1
002(b)(
1)
and
(b)(2)
if the
supplier
provides
documentation
of
the
9577
condition when
reporting
monitoring
results.
9578
9579
1)
The Agency
may,
by
a SEP
issued
pursuant
to Section
611.110,
approve
9580
grandfathering
of
previously
collected
data
where
there
are
time
gaps
in
9581
the
sampling
frequency
if
the
supplier
conducts
additional
monitoring
that
9582
the
Agency
has
specified
by
a SEP
issued
pursuant
to
Section
611.110
to
9583
ensure
that
the
data
used
to comply
with
the initial
source
water
9584
monitoring
requirements
of Section
611.1001(a)
are
seasonally
9585
representative
and
unbiased.
9586
9587
2)
A supplier
may
grandfather
previously
collected
data
where
the
sampling
9588
frequency
within
each
month
varied.
If the
Cryptosporidium
sampling
9589
frequency
varied,
the
supplier
must
follow
the monthly
averaging
9590
procedure
in Section
611.1010(b)(5)
or Section
611.1012(a)(3),
as
9591
applicable,
when
calculating
the
bin classification
for
a filtered
system
9592
supplier
or
the
mean
Cryptosporidium
concentration
for an
unfiltered
9593
system
supplier.
9594
9595
f)
Reporting
monitoring
results
for grandfathering.
A
supplier
that
requests
to
9596
grandfather
previously
collected
monitoring
results
must
report
the
following
9597
information
by
the
applicable
dates
listed
in
this
subsection.
A
supplier
must
9598
report
this
information
to
the
Agency.
9599
9600
1)
A
supplier
must
report
that
it
intends
to
submit
previously
collected
9601
monitoring
results
for
grandfathering.
This
report
must
specify
the
9602
number
of previously
collected
results
the
supplier
will
submit,
the
dates
9603
of
the
first
and
last
sample,
and
whether
a
supplier
will
conduct
additional
9604
source
water
monitoring
to meet
the
requirements
of
Section
611.1001(a).
9605
The
supplier
must
report
this
information
no
later
than
the
applicable
date
9606
set
forth
in Section
611.1002.
9607
9608
2)
A
supplier
must
report
previously
collected
monitoring
results
for
9609
grandfathering,
along
with
the
associated
documentation
listed
in
9610
subsections
(f)(2)(A)
through
(f)(2)(D)
of
this
Section,
no
later than
two
9611
months
after
the
applicable
date
listed
in
Section
611.1001(c).
9612
9613
A)
For
each
sample
result,
a
supplier
must
report
the
applicable
data
9614
elements
in
Section
611.1006.
9615
9616
B)
A supplier
must
certify
that
the
reported
monitoring
results
include
9617
all
results
that it
generated
during
the
time
period
beginning
with
9618
the
first reported
result
and
ending
with
the
final
reported
result.
JCAR35O61
1-0814065r01
9619
This
applies
to samples
that were
collected
from
the
sampling
9620
location
specified
for
source
water monitoring
pursuant
to
this
9621
Subpart
Z,
which
were
not spiked,
and
which
were
analyzed
using
9622
the
laboratory’s
routine
process
for
the
analytical
methods
listed
in
9623
this Section.
9624
9625
C)
The supplier
must
certify
that
the samples
were representative
of a
9626
plant’s
source
waters
and the
source
waters
have
not changed.
It
9627
must report
a
description
of
the
sampling
locations,
which
must
9628
address
the
position
of the
sampling
location
in
relation
to its water
9629
sources
and treatment
processes,
including
points
of
chemical
9630
addition
and
filter
backwash
recycle.
9631
9632
D)
For Cryptosporidium
samples,
the
laboratory
or
laboratories
that
9633
analyzed
the
samples
must provide
a
letter
certifying
that
the
9634
quality
control
criteria
specified
in the
methods
listed
in
subsection
9635
(c)(1)
of
this
Section
were
met
for
each
sample
batch
associated
9636
with
the
reported
results.
Alternatively,
the
laboratory
may
9637
provide
bench
sheets
and
sample
examination
report
forms
for
9638
each field,
matrix
spike,
initial
precision
and
recovery,
ongoing
9639
precision
and
recovery,
and
method
blank
sample
associated
with
9640
the
reported
results.
9641
9642
g)
If
the Agency
determines
that
a
previously
collected
data
set submitted
for
9643
grandfathering
was
generated
during
source
water
conditions
that were
not normal
9644
for
the
supplier,
such
as a drought,
the
Agency
may,
by
a SEP
issued
pursuant
to
9645
Section
611.110,
disapprove
the
data. Alternatively,
the
Agency
may,
by
a SEP
9646
issued
pursuant
to
Section
611.110,
approve
the
previously
collected
data
if
the
9647
supplier
reports
additional
source
water
monitoring
data,
as determined
by the
9648
Agency,
to ensure
that
the
data
set
used pursuant
to Section
611.1010
or
Section
9649
611.1012
represents
average
source
water conditions
for
the supplier.
9650
9651
h)
If
a
supplier
submits
previously
collected
data
that
fully
meet
the
number
of
9652
samples
required
for initial
source
water
monitoring
pursuant
to
Section
9653
611.1001(a),
and
some
of the
data are
rejected
due
to
not
meeting
the
9654
requirements
of this
Section,
the
supplier
must
conduct
additional
monitoring
to
9655
replace
rejected
data
on a schedule
that the
Agency
has
approved
by
a SEP
issued
9656
pursuant
to Section
611.110.
A supplier
is
not required
to
begin
this
additional
9657
monitoring
until
two
months
after
notification
that
data
have
been
rejected
and
9658
additional
monitoring
is
necessary.
9659
9660
BOARD
NOTE:
Derived
from
40 CFR
141.707
(2007)(2006).
9661
JCAR35O61
1-0814065r01
9662
(Source: Amended
at 32
Iii.
Reg.
effective