1. Leachate Sampling-90.92

BEFORE THE ILLINOIS POLLUTION CONTROL BOARD
IN THE MATTER OF:
PETITION OF
BFI
WASTE SYSTEMS
OF NORTH AMERICA, INC. FOR AN
ADJUSTED STANDARD WASTE
DELISTING
NOTICE OF FILING
To:
Clerk ofthe Board
lllinois Pollution Control Board
James
R.
Thompson Center
100 West Randolph Street -Suite 11-500
Chicago,
IL
6060I
(Electronic Filing)
AS 08-05
(Adjusted Staudard - Land)
(Waste Delisting)
Bradley
P. Halloran, Hearing Officer
lllinois Pollution Control Board
James
R. Thompson Center
100 West Randolph St., Suite 11-500
Chicago,
IL
6060I
(Email)
Mary
A. Gade, Regional Administrator
U.S. Environmental Protection Agency
Region 5
77 West Jackson Boulevard
Chicago,
IL
60604
(First Class
U. S. Mail)
Paul Jagiello, Assistant Counsel
Division
of Legal Counsel
lllinois Environmental Protection Agency
9511 West Harrison Street
Des Plaines,
IL
60016
(Email)
Mr. William Ingersoll, Manager
Enforcement Programs
lllinois Environmental Protection Agency
1021 North Grand Avenue East
Post Office Box 19276
Springfield,
IL
62794-9276
(Email)
Please take notice that
on June 30, 2008 the undersigned caused to be filed with the Clerk
of the Illinois Pollution Control Board Petitioner's Post-Hearing Brief, Petitioner's Proposed
Second Amendment to Petition for Adjusted Standard and Motion to Amend Petition fir
Adjusted Standard Waste Delisting, copies
of which are herewith served upon you.
Patricia F. Sharkey
McGuireWoods LLP
77 West Wacker, Suite 4100
Chicago,
IL 60601
Telephone: 312/849-8100
\6378349.1
PRINTED ON RECYCLED PAPER
Electronic Filing - Received, Clerk's Office, June 30, 2008

CERTIFICATE OF SERVICE
I,
Patricia F. Sharkey, hereby certify that I served a copy of the above-listed document
upon those listed on the attached Notice
of Filing on June 30, 2008 via email and First Class
United States Mail, postage prepaid.
McGuireWoods LLP
77 West Wacker, Suite 4100
Chicago, Illinois 60601
Telephone: 312/849-8100
\6378349.1
PRINTED ON RECYCLED PAPER
Electronic Filing - Received, Clerk's Office, June 30, 2008

PRIVILEGED ATTORNEY WORK PRODUCT
BEFORE THE ILLINOIS POLLUTION CONTROL BOARD
IN
THE MATTER OF:
PETITION OF BFI WASTE SYSTEMS
OF NORTH AMERICA, INC. FOR
AN
ADJUSTED STANDARD WASTE
DELISTING
AS 08-05
(Adjusted Staudard
- Laud)(Waste
Delistiug)
PETITIONER'S POST HEARING BRIEF
OVERVIEW
OF THE PETITION
The Petition for Adjusted Standard Waste Delisting ("Petition") filed by
BFI Waste Systems
of Norton America, Inc. ("BFI") will allow leachate
generated at BFI's long-closed Davis Junction Landfill Phase I Unit
to be treated
as non-hazardous waste under certain very limited circumstances which are
specified in the Adjusted Standard.
See Petition, pp.
14-16. Also see BFI's
revised Adjusted Standard language in the
Proposed Second Amendment to
Petition
for Adjusted Standard,
which his being filed with this brieftoday. This is
considered a "conditional delisting" under USEPA guidance.
See USEPA
"National Policy
for Hazardous Waste Delistings,
"
July
1, 1998.
Attachment 1.
The Adjusted Standard will allow BFI to transport this leachate over a shorter
distance to a closer wastewater treatment facility ("WWTF") which will provide
equal or better treatment than this leachate is currently receiving as a listed
hazardous waste.
Tr. pp. 83.
All the while, from cradle to grave, this leachate will be covered by a
regulatory program - either the RCRA Subtitle C hazardous waste program prior
to being loaded into the tanker truck, the Illinois Special Waste Manifest program
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Electronic Filing - Received, Clerk's Office, June 30, 2008

while being transported, or the Clean Water Act pretreatment and NPDES
discharge requirements for treatment prior to discharge from the WWTF.
If a spill
occurs or the leachate is not disposed
of in a permitted and approved pretreatment
WWTF, the delisting does not apply and the leachate will be subject to RCRA
Subtitle C regulation just
as it is now. Thus, unlike unconditional delistings, the
conditions in BFI's proposed Adjusted Standard will not allow this leachate to
exit governmental oversight --- the concern expressed by USEPA in justifying
conservative generic delisting assumptions (e.g. DRAS modeling assuming land
disposal in an unlined landfill or surface impoundment). See discussion in
Transcript at
Tr.
pp.
75-78, and
Attachment 1,
at p. 1.
This leachate is currently required to be treated as a listed hazardous
waste (F039) solely because the Phase I unit in which it was generated accepted 2
%
hazardous waste.
It
does contain some of the constituents for which F039 was
listed
as a hazardous waste. But, the analysis provided in the Petition
demonstrates that the Phase I Unit leachate does not contain concentrations
of
those constituents which meet the criterion for listing (and delisting) F039 as a
toxic waste in
35 Ill. Adm. Code nl.lll(a)(3), i.e. "that the waste is capable of
posing a substantial present or potential hazard to human health or the
enviromnent when improperly treated, stored, transported, or disposed of, or
otherwise managed." Thus, this leachate qualifies for delisting under
35 Ill. Adm.
Code
nO.122.
The nature
of the leachate
in
this case is well known. As the Phase I Unit
was a RCRA regulated landfill, BFI maintained documentation
of every load of
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Electronic Filing - Received, Clerk's Office, June 30, 2008

hazardous waste accepted by the Phase I Unit since the RCRA Subtitle C
regulations became effective. The volumes and types
of waste are provided in
Appendix A
to the Petition. The Phase I Unit ceased accepting waste in 1983 and
was closed in 1984.
In
1999, the original compacted soil cover was replaced with
an improved composite soil!geomembrane cover. Thus, this Petition involves a
waste stream that will continue to be generated in the future, but which should not
vary significantly in constituents or concentrations. To support this conclusion,
BFI has provided nine years
of leachate data demonstrating the stable character of
this waste stream. See
Appendices
C
and D,
respectively, to the Petition.
In
response to a question from the Board'sTechnical Personnel, BFI also performed
a statistical analysis which confirms the lack
of significant variability in this waste
stream. With respect to the amount
of sampling data and analysis provided, BFI
believes this may
be the most well documented delisting petition the Board has
ever received.
This Petition may also present the most conservative delisting analysis
that the Board has ever reviewed. This leachate will not
be land disposed and will
only
be deemed delisted if it is transported for treatment to a permitted
wastewater treatment facility ("WWTF") which has a USEPA approved
pretreatment program. Thereafter, the WWTF wastewater is discharged
to the
Rock River Reclamation District, a publicly owned treatment works ("POTW"),
which monitors its discharge for compliance with both federal pretreatment and
NPDES permit requirements. Nonetheless, BFI has modeled the risk
of a worst
case spill on route to the WWTF using: the highest level
of the constituents
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Electronic Filing - Received, Clerk's Office, June 30, 2008

detected over nine years of data collection, USEPA'srecommended DRAS Model
for disposal in an unlined surface impoundment, and Illinois'
10-
6
risk level. The
selection
of and support for the use of these inputs was discussed extensively in
the Pre-Filed Testimony (pp.4-8) and at the hearing (Tr. pp. 69-78). Since the
leachate will not be considered delisted should such a spill occur and RCRA
Subtitle C hazardous waste regulations will apply to the leachate immediately
upon such an occurrence, this modeling and the levels proposed should be
considered very conservative.
The DRAS modeled limits are proposed as conservative delisting limits
and are stated in the Adjusted Standard, with the exception
of two constituents for
which the highest data point exceeded the calculated DRAS limits. For those two
constituents,
BFI
has proposed limits specified in other relevant regulatory
programs, consistent with
35
Ill.
Adm. Code 721.111(a)(3)(J). Specifically,
USEPA's characteristic toxicity limit is proposed as the delisting level for vinyl
cWoride Illinois' site specific remediation objective for lA-dioxane is proposed as
the delisting level for 1A-dioxane. See the Illinois EPA Toxicity Assessment
Unit's Groundwater Remediation Objectives for Chemicals Not Listed in TACO"
at
http://www.epa.state.il.usllandltaco!chemicals-not-in-taco-l-tables.html.
The
selection
of and support for these limits was discussed at length in BFI's
Technical Support Document accompanying its Petition, at pp. 32-36, BFI's Pre-
Filed Testimony
(pp.l6-l8), and at the hearing (Tr. pp. 40-43, 119-123).
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Electronic Filing - Received, Clerk's Office, June 30, 2008

ILLINOIS EPA RECOMMENDATION
Although Illinois EPA originally reconunended denial of this petition
(March 25,2008, Illinois EPA Response to Petition for Adjusted Standard Waste
Delisting), it later reversed its position based on revisions to the Adjusted
Standard language making it clear that the leachate will only be considered
delisted when it
is being transported to and received by a WWTF with a USEPA
approved pretreatment program. See IEPA revised recommendation dated April
21,2008 and testimony of Mark Crites at
Tr.
pp.
87-91. The amendments in the
proposed Second Amendment to Petition for Adjusted Standard, which is being
filed today with this brief, maintain that concept.
TESTIMONY AT HEARING
At the Illinois Pollution Control Board ("Board") hearing held in this
matter on May
15, 2008, BFI presented testimony on the background, rationale
and technical merits
of its petition by Ms. Elizabeth Steinhour and Mr. Michael
Maxwell, both
of Weaver Boos Consultants, Inc..
Tr.
pp.
14-21, 34-43. BFI's
attorney, Ms. Patricia Sharkey
of McGuireWoods, LLP, also presented a
discussion
of the applicability of state and federal delisting regulations, state and
federal delisting precedent, and various EPA guidance documents to this Adjusted
Standard delisting petition and the Board's decision in this case.
Tr.
pp.
44-54.
As this is not a contested matter and the testimony provided at hearing was quite
complete, rather than repeat that testimony, BFI would simply direct the Board to
the testimony in the record on these points.
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Electronic Filing - Received, Clerk's Office, June 30, 2008

RESPONSE TO BOARD'SPRE-HEARING QUESTIONS
On April
4, 2008, the Hearing Officer issued an order which directed BFI
to submit responses to eight questions posed by the Board'stechnical personnel in
Attachment A
to that order. On May 5, 2008, BFI filed
Petitioner's Pre-Filed
Testimony Responding
to Questions from Board's Technical Personnel
("Pre-
Filed Testimony") which includes detailed answers to those questions and several
attachments. BFI believes those questions and answers are very pertinent to the
Board's review
of this Petition and would direct the Board's attention to its Pre-
Filed Testimony as well as the BFI witnesses' additional responses to those
questions at the hearing.
RESPONSE
TO ADDITIONAL QUESTONS POSED AT THE HEARING
At the hearing, a number
of additional questions were raised. Although
each
of these points was addressed at the hearing, BPI offers the following
additional responses:
1.
In
light of the fact that the
cm
treatment facility in Calumet
City, Illinois
had notified BFI that it no longer has the capacity to accept the
Phase I Unit leachate, the
Board requested that BFI update its costs for
disposing
of the leachate as a listed waste based on the longer hauling
distance to the next closest liquid hazardous waste
treatment facility (in
Ohio). See
Tr. p. 29.
Since the date of the hearing, the
crn
hazardous waste water treatment
facility in Calumet City, lllinois - approximately 100 miles from the Davis
Junction Landfill
-- has informed BFI that it can once again accept its leachate
for treatment. However, BFI has no assurance as to how long
crn
will continue to
accept it. As discussed at the hearing, the next closest facility which is permitted
to accept liquid hazardous waste is located in Vickery, Ohio, approximately 268
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Electronic Filing - Received, Clerk's Office, June 30, 2008

miles from the Davis Junction Landfill. See attached MapQuest Driving Direction
providing a map and mileage.
Attachment
2. The cost BFI incurred for
transporting the Phase I Unit leachate
to the Vickery, Ohio facility (after
crn
notified BFI that it could no longer accept its waste due to capacity restrictions)
was approximately $2,250 / 5,000 gallon tanker truck.
2.
The Board asked that BFI comment on the consistency of its
Petition with USEPA delisting decisions
in other cases, including the Shell
case. See
Tr. p. 51-52.
In support of its Petition, BFI reviewed a number of USEPA delisting
approvals. Copies
of Federal Register publications of USEPA's proposed and
final delisting for each
of eight federal delistings are included in
Attachment 3
hereto. In an effort to identify relevant cases, BFI focused on relatively recent
delistings involving listed liquid hazardous waste, especially leachate.
Of the nine
delistings identified as relevant in our research, we found two delistings involving
the disposal
of F039 (Shell Oil Company, 70 Fed. Reg. 49187 (Aug. 23, 2005)
and Department
of Energy (Hanford), 70 Fed. Reg. 44496 (Aug. 3, 2005). BFI
also reviewed the Board's actions in two recent Adjusted Standard delisting
proceedings in which the Board rejected the petitions (Waste Management, Inc.,
IPCB No. 05-07 (Dec. 15,2005) and BP Amoco, Inc., IPCB No. 07-(01) Feb. 15,
2007).
From BFI's review
of the Federal de1isting cases, some general
observations and comparisons can be made:
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Electronic Filing - Received, Clerk's Office, June 30, 2008

A.
Nature of Waste Generating Activity
i.
Types of Processes and Listed Wastes
The types
of listed wastes involved in these cases were: metal treating
sludges and filter cake (F019); Refinery landfill leachate missed with other
refinery wastewater (F039); Leachate, condensate and other wastewater generated
in the course
of a clean-up of a hazardous waste landfill that accepted F-, U- and
P - listed wastes (F039); Sludge from electroplating operations (F006);
Dewatered sludge from a plastics and chemical manufacturer's wastewater
treatment plant
(F-, U- and K-listed wastes); Leachate from landfilling of electric
arc furnace dust and wastewater (K061); Residues from the treatment
of multiple
metal-bearing waste streams
(F- and K- listed wastes).
While the two F039 listed waste streams are
of obvious relevance,
leachates and sludges associated with metals manufacturing should also be
considered relevant because 96%
of the 2% hazardous waste accepted in the BFI
Phase I Unit was heavy metal sludges. See Technical Support Document to the
Petition,
p. 6 and Appendix A thereto for a description and listing of the wastes
received
at the Phase I Unit.
ii.
Multi-Year Delisting vs. One-Time Delisting
With the exception
of the one-time Tenneco and USG delistings, all of
these delistings are multi-year delistings. Yet, as is discussed further in response
to Question No.2 below, none of these delistings required testing of every waste
load.
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Electronic Filing - Received, Clerk's Office, June 30, 2008

iii.
Active Source vs. Inactive Source
The one-time Tenneco and USG delistings each involved a fixed quantity
of a known waste stored in contairnnent cells. The DOE (Hanford) waste stream,
like the BFI waste stream in this Petition, is F039 wastewater which is derived
from a closed landfill, but which will be generated over a period
of years. The
DOE F039 waste stream has a greater potential for variability than does the BFI
leachate because it includes not only leachate but also a variety
of wastewater
generated from waste management and cleanup activities at the Hanford mixed
waste site.
The other five delistings involve waste streams generated by on-going
industrial activities, and thus should be presumed to have the potential for greater
variability than does the leachate generated at the long-closed Phase I Unit
at the
BFI Davis Junction Landfill.
B.
Scope of Sampling and Analysis
As discussed in the Pre-Filed Testimony at pp. 1-4. BFI believes
the large amount
of data and the lengthy period over which it was obtained
provides a high level
of assurance regarding the nature of the Phase I Unit
leachate. The following table provides a quick comparison
of the historical data
supporting BFI's Petition compared to that supporting those other eight USEPA
approval petitions.
Number of Sampling Events
I
Period of Time
Delisting
Number of
Period Over
Constituents
Company
Sampling Events
Which Samples
Analyzed
Collected
BFI-Davis
14 samples
9 vears
App. IX and F039
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Electronic Filing - Received, Clerk's Office, June 30, 2008

Junction Landfill
constituent list
Phase/Unit
(with some
exceptions)
Auto Alliance
One composite
Samples for
FO19 constituents
International
sample from each
composite to be
(including
("AAI")
of six roll-off
collected over 6
volatiles, semi-
boxes
week period
volatiles and
metals, cyanide,
Sulfide, Fluoride,
formaldehyde,
pH)
Shell Oil
4 samples
of
Collected over a 5
App. IX (with
Company
primary leachate;
month period
some additions)
4 samples
of
secondary
leachate
Dept.
ofEnergy
Historic data from Three years of
To be proposed in
(Hanford)
operation
of
prior effluent data
a sampling plan
treatment unit;
from prior
Sampling for this
delisting;
waste stream to
be Sampling for this
proposed in a
waste stream to be
sampling plan
proposed in a
sampling plan
Nissan
Onetime
OneTime
App. IX ( with
composite and
some additions)
grab samples from
different process
waste sources
Tenneco
One
One Time
App.
IX (with
some exceptions)
Eastman
One
OneTime
App. IX (with
some exceptions)
Chaparral
Unspecified
Not stated
App. IX (with
historic data and
some
bench tests
of
addtions,including
treated leachate
reactive sulfide,
reactive cyanide)
usa
Not stated
Not stated
Not stated-
(included historic
(included historic
presume FOl9
groundwater
groundwater
constituents
monitoring)
monitoring)
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Electronic Filing - Received, Clerk's Office, June 30, 2008

C.
Modeling Assumptions
i.
Volume of Leachate Modeled
All
of these USEPA delistings either require or allow post-delisting
management
of the waste in a land-based disposal unit. Therefore, its not
surprising that USEPA's conservative assumption that 100%
ofthe delisted waste
could potentially be disposed
of on the land at one location is triggered in these
cases.
In contrast, BFI's petition does not allow land disposal. Therefore,
USEPA's conservative land-based mismanagement scenario should not apply in
this case. USEPA's 1998
National Policy for Hazardous
Waste Delistings
expressly authorizes non-traditional, "conditional" delistings, such as this, as long
as the delisting is based on modeling that reflects the potential exposure from the
post-delisting management scenario and contains appropriate conditions. See
Attachment
1. USEPA's RCRA Delisting Program - - Guidance Manual for the
Petitioner also focuses on appropriate modeling:
"In our technical evaluation, we often use appropriate fate
and transport models that rely on waste-specific
information (e.g., waste volume, constituent concentration
data) to predict the potential enviromnental impact
of the
petitioned waste.
In
selecting appropriate models, we
choose a reasonable worst-case management scenario and
consider plausible exposure routes for the hazardous
constituents found to be present." (pp. 12-13).
The actual regulatory factor that the Board must consider is whether the
model has included the risk associated with all "plausible types
of improper
management to which the waste could be subjected."
35 Ill. Adm. Code
721.111(a)(3)(G).
In
this case, even though land disposal is expressly
disallowed
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Electronic Filing - Received, Clerk's Office, June 30, 2008

under the BPI Adjusted Standard and the delisting would not apply ifthe leachate
were spilled on route to the pre-treatment facility,
BFI has used DRAS to model a
worst case land disposal scenario, focusing on the maximum mismanagement
land disposal volume reasonably possible under this delisting, i.e. a full tanker
truck spill.
ii.
Nnmber of Years of Disposal Assnmed
Although it
is not expressly stated, we presume that each of these
delistings used the DRAS default periods
of one year or twenty years. As stated
above, these lengthy periods are not relevant to the conditional delisting in this
case. Nonetheless, BPI conservatively used the DRAS default period
of one year
in its modeling.
iii.
Target Carcinogenic Risk Modeled
Many
of the USEPA delistings used a cancer rate of IxlO-
5
in their DRAS
modeling.
In
comparison, BFI used the more conservative Illinois standard of
lxlO-
6
.
iv.
Modeling of Non-Detected Constitnents
The question
of how to model non-detectable constituents was not
discussed
in six of the eight USEPA approved delistings reviewed by BPI, and
there is no evidence that the data relied upon in those delistings included
modeling
of non-detected constituents.
In
two of the USEPA delistings, USEPA
expressly stated that it was inappropriate to model using detection limits. See
discussion in Question No.
12 below.
In
one case
(Nissan),
EPA discussed the
fact that Nissan modeled one constituent (arsenic) using a concentration
of
Yz
of
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Electronic Filing - Received, Clerk's Office, June 30, 2008

the detection limit. However, from EPA's discussion, it appears that Nissan
didn't model hexavalent chromium using the detection level, even though it was
also measured at non-detect. See
Attachment 3-4.
D.
Limits in Delisting: Land Disposal Allowed vs. No Land
Disposal
Each
of the eight USEPA delistings either specified or allowed land
disposal
of the delisted waste. The Chaparral delisting allowed onsite and off-site
land disposal
as well as the management of the waste water in on-site cooling
ponds. (See
Attachment
3-7, 65 Fed. Reg. 8874, 8875 (Feb. 23,2000).) The Shell
delisting allows management
of the delisted waste in an on-site biotreatment unit
including treatment in sludge aeration basins. (See Shell Petitioner's description
of the North Effluent Theater,
Attachment
4 at pp. 14-15 and in Figure 4-1. The
DOE (Hanford) delisting specifies disposal in a State Authorized Land Disposal
Unit which is described as an "effluent infiltration gallery" and as being
functionally equivalent to an unlined surface impoundment. (See
Attachment 3-3,
60 Fed. Reg. 6061 and 70 Fed. Reg. 44499.) The remainder of the eight USEPA
delistings all specify disposal in a Subtitle D solid waste landfill.
In contrast, the BFI Petition does not allow land disposal, and only applies
to the transportation to and disposal at a permitted and USEPA approved
pretreatment facility.
3.
The Board asked whether BFI is aware of any other delistings
where USEPA has allowed a similar monitoring frequency as
is proposed in
this Petition for
an F039 leachate from a landfill that had accepted many
different types
of hazardous waste over a period of time for which the waste
types, including
raw materials, are not fully documented.
See Tr.
p.
62.
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Yes. The chart below shows that USEPA has taken different approaches
to testing frequency based upon the types
of operations and waste streams
involved and the anticipated or historic variability
of the waste stream. In the case
of BFI's Phase I Unit leachate, there is a static source and there has been minimal
historic variability in the leachate constituents or concentrations. The initial,
quarterly and semi-annual frequency
of testing originally proposed by BPI, and as
proposed
to be modified in the Second Amendment to the Proposed Adjusted
Standard, should be deemed consistent with and even more stringent than
USEPA's approved sampling regimes.
Delisting
Generating
Initial Testing
Long-Term
Source
Testing
BFI Davis Junction
Multi-Year/
One test of
Quarterly for first
Landfill -Phase I
Closed
leachate storage
year; Annual
Unit
Landfill
tank
thereafter
Auto Alliance
Multi-Year/
None
Quarterly'
International
On-going
("AAI")
Process
Shell Oil Company
Multi-year/
One test within 60
Quarterly for the
Ongoing
days
of delisting
first year; Annual
Process
effective date and
thereafter
two quarters
thereafter
Dept.
of Energy
Multi-Year /
One test of effluent Every lS
tn
tank"
(Hanford)
Closed landfill discharge tank
leachate but
also on-oing
remediation
waste water
Nissan
Multi-Year /
One test
Annual
On-going
, In
comments, AAI requested annual testing, but USEPA replied that since the waste had shown
significant variation
on a quarterly basis, annual sampling would not detect such variations. This is
not the case with the BFI Phase I Unit leachate, which has not shown seasonal variation.
2 The DOE (Hanford) waste consisted ofboth leachate and other remediation wastewaters and
therefore could be expected to
be far more variable than the BFI Phase I Unit leachate.
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Electronic Filing - Received, Clerk's Office, June 30, 2008

Process
Tenneco
OneTime
None
-Qne time
None
Delisting
notification
Eastman
Multi-Year /
Quarter!y for 1
st
Annual
On-going
year
Process
Chaparral
Multi-Year /
8 batches
of
Annual
Ongoing
wastewater
Process
USG
OneTime
One time sampling
None
Delisting
at six locations
in
sludge pond
4.
The Board asked whether BFI has performed a statistical
analysis
of the nine years of monitoring data presented to see demonstrate
the lack of statistical variability in the data. See
Tr.
pp.
67-68.
In response to the Board's question, Weaver Boos performed a statistical
analysis to assess variability in the historical leachate data.
Attachment 5.
Specifically, the variance and standard deviation were calculated for each
parameter analyzed in the historical record. The variance was calculated as:
Li
X
n-I
-
xY
)
Where:
X
is the sample concentration
xis
the mean
n
is the number of sample concentrations
The standard deviation
is simply the square root of the variance.
A summary
of the mean, variance, and standard deviation for the
parameters analyzed over the period from 1999 - 2007 is presented on the
attached Table
1. Only 9 out of over 250 constituents exhibited a variance greater
than 1.0 mg/L. The average variance encompassing all
of the parameters slightly
exceeded I mg/L. However, this average variance was heavily influenced by two
parameters with a variance well above 1.0 mg/L. The variance for 1,4 dioxane
was
111 mgIL and the variance for isobutyl alcohol was 46
mgIL.
If the single
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Electronic Filing - Received, Clerk's Office, June 30, 2008

highest vanance is removed from the average calculation, then the average
variance is almost half
of variance using all the data (0.60 mgIL). If the two
highest variances are removed, the average variance is reduced
to less than half
the value using all the data (0.43 mgIL). The average standard deviation for all
parameters is even lower (0.346 mg/L).
Variability with respect to the two above constituents should not be a
significant issue because both
of these constituents are proposed to be analyzed on
a regular basis
as part of the proposed adjusted standard language. If the
variability becomes an issue
to the point where concentrations exceed the
proposed delisting levels, this condition will be identified
by future monitoring
and the leachate will not meet the delisting requirements, and will be considered a
hazardous waste.
Note that for purposes
of the calculation of the mean, variance, and
standard deviation, Weaver Boos used the reporting limits for parameters for
which the analytical results were "non-detect." The minor variability in the
historical data as evidenced by the above statistical analysis suggests that it is
reasonable
to conclude that the non-detected constituents are unlikely to present a
significant concern.
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5.
The Board also asked whether a statistical analysis supports
BFl's conclusion that certain high constituent readings were "outliers."
Tr.
p.67.
The conclusion
that
various historical data points were outliers was
previously based more on a visual scan
of the data, rather than a quantitative
analysis.
In
response to this question, Weaver Boos performed a quantitative
evaluation
of the analytical results for methylene chloride, trichloroethylene, and
vinyl chloride to assess whether select historical data points are appropriately
considered outliers.
As shown in
Attachment
5, the attached Table I, in the case of
each of these three constituents one historical analytical result does not fit the
pattern established by the rest
of the data:
1.
In
the case of methylene chloride, the mean of the data is 0.095
mg/L. However, one data point from April 2003 was reported as
0.58 mglL, which is over six times higher than the mean;
2. For trichloroethylene, the mean of the data is 0.089 mg/L.
However, one data point from March 2006 was reported as 0.53
mglL, which is nearly six times higher than the mean; and
3.
In
the case of vinyl chloride, the mean of the data is 0.118 mglL.
One data point from March 2006 was reported as 0.44 mglL,
which
is nearly four times higher than the mean.
Because each
of the individual concentrations referenced above represent a
significant departure from the mean, each
of these points are appropriately
considered
as outliers, not representative of the pattern established by the many
other data points in the data set. We note that the amount
of data BFI has
compiled on these constituents exceeds the amount provided by most
if not all
other delisting applicants. Therefore, it is possible to determine a pattern and
outliers in this case. Furthermore,
as the Adjusted Standard is written, if these
17
Electronic Filing - Received, Clerk's Office, June 30, 2008

constituents are found to exceed the delisting levels, BFI will be forced to handle
the leachate as hazardous. Thus, the conclusion that these instances
of high
concentrations are "outliers" and the proposal
of lower delisting levels is a
conclusion made at BFI'sown risk.
6.
The Board asked BFI to verify the volume of leachate that Shell Oil
used in its DRAS modeling to
support its federal delistiug and to discuss its
relevance to
BFI's petition. See
Tr. p. 79.
From the petition filed in the Shell Oil delisting proceeding, it appears that
Shell used an annual volume
of 3.36 million gals/yr (14,000 tons/yr or 16,619
cy/yr)
in its DRAS modeling. See pp. 7-8, 59 of the Shell Petition,
Attachment 4.
While there are many similarities between the Shell Oil delisting and the delisting
proposed in this case, one significant difference is that Shell's delisting is based
on routing its F039 leachate through its North Effluent Biotreatment System,
which includes treatment in on-site land units (including activated sludge basins)
prior to discharge via Shell'sNPDES permitted outfall. See the Shell Oil delisting
Final Rule 70 Fed. Reg. 49187, at 49188,
Attachment
3-2. Also see Shell Petition,
pp.
9, 16- 17, and Figure 4-1 "NET Biotreatment System,"
Attachment 4.
As previously stated, where land-based disposal is allowed under a
delisting it is appropriate to use the DRAS model worst case assumption that
100%
of the delisted waste will be disposed of in an unlined landfill or surface
impoundment. Although the Shell delisting anticipated ultimate disposal
of the
leachate under Shell's own NPDES permit, it also involved on-site land-based
treatment prior to disposal via the NPDES permit. Therefore, the conservative
18
Electronic Filing - Received, Clerk's Office, June 30, 2008

assumption that the leachate might percolate into the ground through the land-
based treatment units is appropriate. Notably, neither the petition, the delisting
documents, nor the language
of the delisting itself in the Shell case describe the
point at which the F039 leachate is considered delisted. This, plus the fact that
Shell was waiting to obtain the delisting before construction
of the piping to route
the leachate
to the North Effluent Treater, indicate that the leachate would be
considered delisted as it leaves the landfill. Given the fact that no regulatory
program would govern the handling and treating
of the leachate on-site, EPA's
worst case assumptions regarding 100% land disposal were justified.
In
contrast, the proposed BFI delisting does not authorize any contact of
the leachate with land. The leachate will be transported in 5,000 gallon tanker
trucks and will not be considered delisted until it
is loaded into the truck.
It
is
extremely unlikely that there would be a spill of two tanker trucks at the exact
same location.
In
fact, there has never been a spill during the transport of leachate
from the Davis Junction landfill, even hauling the leachate over 100 miles for
treatment.
Tr. pp.
66-67. Rather than this delisting resulting in a loss of
governmental control of the fate of the leachate, the BFI delisting provides cradle-
to-grave control.
Furthermore, the BFI delisting can be distinguished as ensuring a much
broader level
of control than USEPA required for Shell's leachate in that two
independent Clean Water Act permitted WWTF's will receive and confirm the
treatability
of the leachate to CWA standards before it is ultimately released to the
environment.
19
Electronic Filing - Received, Clerk's Office, June 30, 2008

7.
The Board asked BFI to verify the maximum volume of waste
and number of years of waste generation covered by the Shell Oil delisting
and to discuss its relevance to BFl's petition. See
Tr.
p.
80.
From the petition filed in the Shell Oil delisting proceeding, it appears that
Shell used the DRAS default
of twenty years as the time period in the DRAS
model. See
Attachment
4.
8.
The Board asked whether there is any need for USEPA's
approval of this delisting? See
Tr.
p.
92.
BFI
is not aware of any reason that USEPA approval would be required
for this delisting. BFI is not requesting a change to any federally approved water
quality standard nor will this delisting affect any discharge
to a water of the State
or a water
of the United States. As stated, upon delisting, this leachate must be
sent to a WWTF with a federally approved pretreatment program and the
wastewater from that WWTF will be discharged
to a POTW that also must
comply with federal pretreatment and NPDES standards. USEPA and lllinois
authorize WWTF's and POTW's to accept wastewater for treatment under their
approved pretreatment programs and NPDES permits without requiring pre-
approval
of individual wastewater streams by USEP
A.
Furthermore, the State of lllinois and the lllinois Pollution Control Board
have been delegated the authority to delist a hazardous waste stream
as long as the
waste will be disposed
of within lllinois. lllinois EPA confirmed this point at the
hearing.
Tr.
pp.
92- 93. BFI also confirmed this point with USEPA prior to filing
its Petition before the Board.
Tr.
pp.
94.
20
Electronic Filing - Received, Clerk's Office, June 30, 2008

9.
In its pre-hearing qnestions, the Board asked why BFI had not
provided analytical data for eleven constituents that are included
in the F039
list.
BFI
responded in its pre-filed testimony and
at
the hearing, saying that
BFI
had not realized that its laboratory had not included these constituents in the
analyses. Upon further inquiry
of BFI's normal lab and two other labs, BFI was
told that these constituents are deemed unusual and are not normally analyzed for
when a customer requests analysis for F039 constituents. Furthermore, BFI found
that,
of the three labs it contacted, no single lab had the capability to analyze for
all
of these constituents. BFI raised concern about getting data from different labs
and asked the Board for guidance on how to respond.
At the hearing, Ms. Liu indicated that the parameter
of particular
relevance was pthalic anhydrite, because pthalic anhydrite waste was specifically
mentioned as being included in the 2%
of hazardous waste accepted at the Phase I
Unit.
Tr.
pp.
100-102.
Since the hearing, BFI has obtained an analysis of a
leachate sample for pthalic anhydrite (from the same laboratory that it normally
uses). The results indicate that this constituent was below the detection level. See
Attachment
6. BFI has inquired, but has not yet received an answer, as to whether
it is possible to obtain an analysis of any more of these unusual constituents from
this same lab at this time.
If this is possible, BFI will provide this analysis before
the end
of the briefing period.
BFI also continues to believe that, with the exception
of pthalic anhydrite
(for which there is a specific reason to test this leachate), it is unnecessary to test
for these unusual constituents.
In
fact, in the USEPA has not required testing for
21
Electronic Filing - Received, Clerk's Office, June 30, 2008

unusual constituents which are unlikely to be present in a particular leachate.
Most notably in the Shell Oil delisting USEPA did not require Shell to test for
these unusual F039 constituents.
In
fact, USEPA only required testing for the
constituents listed in 40 CFR Part 264, Appendix IX . See
Attachment
4. Thus,
even without testing for these other unusual constituents, the scope
of BFI's
sampling data and analysis exceeds that which USEPA has required for delisting
an F039 waste.
10.
The Board asked BFI to address any additional parameters or
information that is referenced in USEPA npdates to the DRAS software.
See
Tr.
pp.
105 -111.
Pursuant to communications with Mr. Todd Ramaly of the USEPA on
May
6, 2008, the backward calculation of the delisting levels for the fish ingestion
and air volatiles pathway were evaluated. (See DRAS Version 2.0 User Alert,
Item 3.) The results
of this evaluation are summarized in a table in
Attachment
7.
Each parameter was evaluated with respect to the fish ingestion and air
volatiles pathway, under both a carcinogenic risk and noncarcinogenic scenario.
If one of these pathways contributed to the aggregate risk, then the attached
spreadsheet was used to calculate a delisting level based upon the equation
contained in the User Alert. Note that the fish ingestion pathway was not part
of
the overall risk or hazard quotient for any of the constituents included on the final
list, while the air volatiles pathway was part
of the overall risk and/or hazard
quotient for certain organic constituents and mercury.
The delisting level for the air volatiles pathway calculated usmg the
equation in the User Alert was then compared to the delisting level proposed in
22
Electronic Filing - Received, Clerk's Office, June 30, 2008

BFI's Delisting Petition. In each case except for cis- 1,3-dichloropropene and
heptachlor, the delisting level calculated using this method was higher than the
delisting level proposed within BFI's Delisting Petition. Therefore, the proposed
delisting levels for the majority
of the constituents are unaffected by these
calculations. However, in the case
of these two parameters, the delisting level
calculated using this method was lower than the delisting level proposed in BFI's
Delisting Petition.
In
the case of these two parameters, BFI is proposing that the delisting
level be revised. The proposed new delisting level for cis- 1,3-dichloropropene is
1,206 mg/L, which corresponds to the manually calculated value for the air
volatiles pathway.
In
the case of heptachlor, the manually calculated delisting
level for the air volatiles pathway is greater than the toxicity level under 40 CFR
261.24. Therefore, the proposed delisting level for heptachlor will default
to the
toxicity level
of 0.008 mg/L. These results are generally consistent with the
technical literature on the DRAS software and the expectation
of Mr. Ramaly, as
he indicated that in most cases, the groundwater pathway would be the most
sensitive pathway controlling the delisting levels.
11.
The Board asked whether the DRAS modeled delisting level
for lead should default
to the toxicity characteristic concentration, since the
DRAS number
is higher than the toxicity characteristic concentration?
Tr. p.
124.
BFI agrees that more stringent characteristic toxicity limits trump the
DRAS calculated limits and has substituted the toxicity characteristic limits for
the calculated limits not only for lead, but also for barium, chromium, mercury,
methylethyl ketone, and silvex in the revised Adjusted Standard language
23
Electronic Filing - Received, Clerk's Office, June 30, 2008

contained in BFI's "Proposed Second Amendment to Petition for Adjusted
Standard which is being filed with this brieftoday.
12.
The Board noted that EPA's DRAS modeling guidance "states
that all risk assessments are conducted twice, once including those chemicals
specified with concentrations
that are detection limits and once omitting
them." The Board requested
BFI's justification for not running the DRAS
model a second time using the detection limits for the non-detected
constitutents.
Tr.
pp
125-128.
As discussed at the hearing, the modeling
of every undetected constituent at its
detection level would be an enormous task
in this case because of the number of
constituents which were initially test for, i.e. all of the Appendix IX and additional F039
constituents.
Tr .p.125-128.
The data presented with this Petition contains greater than
10,000 individual data points. The vast majority
of the many constituents tested for were
found to
be non-detect over nine years of sampling and analysis using USEPA-approved
analytical methods. Therefore, there is very strong evidence that a non-detect reading in
this case is an accurate reading. Furthermore, where a constituent has not been detected in
multiple sampling events over many years, there is a strong indication that the constituent
is not present in the leachate or is not present at a level that would present a "substantial
present or potential hazard to human health or the environment," the criterion for
delisting under
35
Ill.
Adm. Code 721.111(a)(3).
USEPA itself does not require that all non-detected constituents
be
modeled.
In
its approval of the delisting for Chaparral, USEPA stated:
"The EPA believes that it is inappropriate to evaluate
nondetectable concentrations
of a constituent of concern in its
delisting modeling efforts
if the nondetectable value was obtained
using the appropriate analytical method.
If a constituent carmot be
detected (when using the appropriate analystical method with an
adequate detection limit), EPA, for delisting purposes, assumes
that thte constituent is not present and therefore does not present a
24
Electronic Filing - Received, Clerk's Office, June 30, 2008

threat to human health of the environment.
In
the delisting
program, EPA believes that it is inappropriate to evaluate
constituents undetected in the waste samples." 64 Fed. Reg. 46,
166, 171.
(Attachment 3-7.)
Also see USEPA'sstatement in the USG delisting:
"We believe it is inappropriate to evaluate a constituent in our modeling
efforts
if the constituent was not detected using an appropriate analytical
method."
65 Fed. Reg. 58015, 58018.
(Attachment 3-8.)
The reference to modeling non-detected constituents in USEPA DRAS Modeling
Guidance is an example
of a statement made in a USEPA guidance document that should
not
be interpreted by the Board as a federal rule or as a regulatory mandate. The USEPA
DRAS Guidance Manual was intended to
be guidance. USEPA does not interpret every
word in that Guidance Manual as binding for delisting decisions. In fact, in BFI's review
of eight USEPA delistings, we never found a reference to the DRAS Guidance Manual.
The Board should interpret the USEPA guidance the way USEPA interprets it
- as a
document that is relevant, but not binding in every case.
In
this case, modeling of non-
detected constituents has been expressly repudiated as not being USEPA policy in several
delisting cases. Furthermore,
BFI's Petition includes enough data over a long enough
period
of time to provide confidence in the results obtained.
PROPOSED REVISIONS TO ADJUSED STANDARD LANGUAGE
1.
The Board asked BFI to clarify the Adjusted Standard
language to clearly reflect the intent that the point at which the leachate will
be deemed
delisted
is the point at which it is transferred from RCRA
regulated on-site storage into a tanker truck for transport to a permitted
WWTF with a USEPA approved pretreatment program. See
Tr. p. 31.
25
Electronic Filing - Received, Clerk's Office, June 30, 2008

BFI is submitting herewith a
Proposed Second Amendment to Petition for
Adjusted Standard
which is designed
to clarify the point at which the leachate is
designated as delisted pursuant to this Adjusted Standard.
2.
The Board noted that in the Shell
Oil
delisting, EPA allowed
Shell
"to manage and dispose of multi-landfill leachate as nonhazardous
waste only
after the initial verification and testing was completed to
demonstrate compliance with
the delisting levels." The Board asked BFI to
state its rationale for allowing disposal
nnder this delisting prior to
completion
of the initial testing.
Tr. pp.
129 -132.
BFI does not object to a pre-disposal sampling event. BFI did not initially
propose that the leachate be tested prior
to disposal because I) it believed it had
already provided extensive data documenting the constituents and concentrations
in the Phase I Unit leachate, and 2) it had reached an agreement with Illinois EPA
to sample the first three tanker truck loads. As explained at the hearing and in the
Pre-Filed Testimony, it is impractical
to fill a tanker truck, sample the leachate,
and then hold the truck on-site until such time as a laboratory analysis for the
relevant constituents is completed.
Pursuant to the discussion which took place at the hearing
(Trpp 129-
132), BFI is submitting herewith a
Proposed Second Amendment to Petition for
Adjusted Standard
which provides, in a new subsection (g), that BFI will submit
to lllinois EPA the results
of a test of a representative sample of the leachate
demonstrating compliance with the requirements
of the Adjusted Standard at least
thirty days prior to transporting the first load
of delisted leachate. BFI will obtain
this sample from the
ReRA
regulated leachate storage tank in lieu of sampling
individual tanker trucks.
26
Electronic Filing - Received, Clerk's Office, June 30, 2008

3.
The Board asked BFI to comment on whether the Adjusted
Standard should require BFI to notify IEPA "of the initial sampling and
verification to comply with the delisting levels or any other subsequent
exceedances
in the delisting levels are exceeded."
Tr. p 114.
As stated above, BFI agrees with this suggestion and has proposed a new
subsection (g) which requires such a submittal to Illinois EPA at least 30 days
prior to initial transportation and disposal pursuant
to this delisting.
4.
The Board asked whether the Adjusted Standard language
should
require that the testing demonstrate that the leachate does not exhibit
any hazardous waste characteristics before testing is allowed on only a semi-
annual basis?
Tr. p. 135.
BFI agrees that testing and/or an analysis based upon operator knowledge,
as is allowed under RCRA for certain characteristics, should demonstrate that no
RCRA hazardous characteristic is present in the leachate during each prescribed
test. We note that for constituents for which the toxicity characteristic is more
stringent than the DRAS calculated limit, the more stringent toxicity characteristic
has now been incorporated into the delisting levels. BFI also agrees that quarterly
sampling should continue until compliance has been demonstrated by four
quarters
of compliant tests. BFI has proposed to amend the Adjusted Standard
language to reflect these points.
S.
The Board noted that the Adjusted Standard requires that the
leachate be handled as a hazardous waste
if it exceeds the stated delisting
levels
or characteristic levels until the verification sampling procedure
demonstrates
it to be below those standards. The Board asked whether that
prohibition was intended to apply to both the initial testing and the ongoing
semi-annual testing.
Tr. pp.135-136.
BFI intends the prohibition to apply following a failed Verification Test
and to continue until Confirmatory Testing performed pursuant to paragraph (d)
demonstrates compliance. BFI intends the prohibition to apply to all
of the initial,
27
Electronic Filing - Received, Clerk's Office, June 30, 2008

quarterly, and on-going semi-annual testing. BFI has proposed to amend the
Adjusted Standard language to make this clear.
6.
The Board asked whether Subsection E of the Adjusted
Standard should refer to Table A constituents rather than all F039
constituents.
Tr.
pp.
136-137.
BFI intended this language to refer to the constituents listed in Table A in
the Adjusted Standard. To make this clear, BFI has proposed
to delete the
reference to F039 constituents. We have also proposed to amend the language
throughout the Adjusted Standard to consistently refer to the requirements
of
paragraph (c), which references both the Table A constituents and hazardous
characteristics.
CONCLUSION
In
closing, BFI believes it has presented a very conservative delisting
petition. This Petition does not fit neatly within USEP
A's standard land-based
delisting assumptions, but it doesn't have to because BFI is not proposing and
would not
be allowed under this delisting to land-dispose of this waste stream.
USEPA itself does not treat the DRAS Users' Manual or the Manual for the
Petitioner as binding and the Board should not extend the use
of a federal
guidance document beyond the scope to which it is applied
by the USEPA itself.
The Board's decision in this case should be bounded by the factors stated
in
35
Ill.
Adm. Code 721.111(a)(3), and the practical consideration that pursuant
to this delisting the Phase I Unit leachate will
be transported a shorter distance
and receive the same or better treatment at a WWTF than it is currently receiving
as a listed waste under the RCRA Subtitle C program. The Board should also take
28
Electronic Filing - Received, Clerk's Office, June 30, 2008

comfort in the knowledge that the many years of data supporting this Petition
indicate that this is a stable waste stream that
is highly unlikely to change over the
remainder
ofthe post-closure period for the Phase I Unit.
Ultimately, the Board's decision in this case should rest upon the
conditions in the Adjusted Standard, which have been tightened and improved
based on the Illinois EPA's and Board's input and discussion at the hearing.
While BFI believes the language in the "Proposed Second Amendment to Petition
for Adjusted Standard" (which is being filed with this brief today) is clear and
complete, BFI is willing to consider any reasonable additional conditions that the
Board may deem necessary to finalize and approve this delisting.
BFI would like to express its gratitude to the Board for its consideration
of
this Petition. We would also like to thank the Illinois EPA personnel and the
Board's Technical Personnel who have closely reviewed this Petition and
provided helpful questions and comments.
Respectfully submitted,
p~;S;;;
On Behalf of
BFI Waste Systems ofNorth America, Inc.
Date: June 30, 2008
Patricia
F. Sharkey, Esq.
McGuireWoods, LLP
77 W. Wacker Drive
Suite 4100
Chicago, IL
60601
312/849-8100
\6362956.1
29
Electronic Filing - Received, Clerk's Office, June 30, 2008

BEFORE THE ILLINOIS POLLUTION CONTROL BOARD
IN
THE MATTER OF:
PETITION OF BFI WASTE SYSTEMS
OF NORTH AMERICA, INC. FOR AN
ADJUSTED STANDARD WASTE
DELISTING
AS 08-05
(Adjusted Standard
-Land)
(Waste Delisting)
MOTION TO AMEND
PETITION FOR ADJUSTED STANDARD
WASTE DELISTING
NOW COMES BFI Waste Systems ofNorth America, Inc. ("BFI"), by its
attorneys McGuireWoods LLP, moves the Illinois Pollution Control Board ("Board") to
accept the attached Proposed Second Amendment to the Petition for Adjusted Standard
filed
in this matter on November 21,2007 for consideration in this proceeding.
In
support thereof, BFI states:
1.
On November 21,2007, BFI filed a Petition for Adjusted Standard in this
matter which included proposed language for the Adjusted Standard. That language was
desigued to expressly limit the scope
ofthe hazardous waste delisting which is the subject
of the Petition to leachate which is transported pursuant to an Illinois Special Waste
Manifest to a permitted wastewater treatment plant.
2.
Based upon the recommendation
ofthe Illinois Environmental Protection
Agency ("Illinois EPA") and conversations with Illinois
EPA personnel, BFI proposed to
amend the language
of the Adjusted Standard on Apri114, 2008.
Electronic Filing - Received, Clerk's Office, June 30, 2008

3.
Today, based upon additional comments and questions from the Illinois
EPA and the Board'sTechnical Personnel at the May 15,2008 hearing, BFI is proposing
additional amendatory language
to improve and clarify the Adjusted Standard.
4.
An
explanation of each of the changes proposed in the attached Proposed
Second Amendment to Petition for Adjusted Standard is provided in the Petitioner's Post-
Hearing Briefwhich is being filed with the Board today.
WHEREFORE, BFI respectfully requests that the Board accept the attached
Proposed Amendment to Petition for Adjusted Standard for consideration
in
this
proceeding.
Respectfully submitted,
BFI Wa te anagement Sy ems
ofNorth America
By One of Its Attorneys
June 30, 2008
Patricia
F. Sharkey
McGuireWoods LLC
Suite 4100
77 West Wacker Drive
Chicago, Illinois 60601
(312) 849-8100
16378309.1
Electronic Filing - Received, Clerk's Office, June 30, 2008

BEFORE THE ILLINOIS POLLUTION CONTROL BOARD
IN THE MATTER OF:
PETITION OF BFI WASTE SYSTEMS
OF NORTH AMERICA, INC. FOR AN
ADJUSTED STANDARD
WASTE
DELISTING
AS 08-05
(Adjusted Standard -Laud)
(Waste Delisting)
PROPOSED SECOND AMENDMENT TO
PETITION FOR ADJUSTED STANDARD
As discussed in Petitioner'sPost-Hearing Brief, BPI proposes the following
SECOND AMENDMENT
to the Adjusted Standard language which was originally
contained in the Petition on pp. 14-
16 and subsequently proposed to be amended on
April 14, 2008.
Proposed Adjusted Standard Language
Leachate generated at the closed Phase I Unit at the BPI Waste Systems ofNorth
America, Inc. ("BPI") Davis Junction Landfill in Davis Junction, Ogle County,
Illinois shall not be deemed a hazardous waste pursuant to
35 Ill. Adm. Code 721
under the following circumstances:
a)
The Phase I Unit is subject to an Illinois Environmental Protection Agency
RCRA Post -Closure Permit which prohibits the disposal
of any new solid or
liquid waste in the Phase I Unit, requires maintenance
of the landfill cap and liner,
and requires operation of a leachate collection system;
b)
The leachate is hard-piped directly from the landfill
to an on-site storage
tank which is regulated under the RCRA Post-Closure Permit and is not stored or
managed in a surface impoundment, conveyed
by ditches or otherwise managed
prior to transportation for off-site disposal;
c)
The leachate does not exhibit any characteristic of hazardous waste as
defined in
35
Ill.
Adm. Code 721.121, 721.122, 721123 and 721.124 and also
does not exceed the delisting level concentrations in Table A below. Other than
for the toxicity characteristics which are reflected
in the delisting level
concentrations in Table A below, compliance with a hazardous characteristic may
be demonstrated based upon BPI'sknowledge of the leachate characteristics.
Electronic Filing - Received, Clerk's Office, June 30, 2008

d)
Prior to commencing initial transportation and disposal ofthe leachate
pursuant to this Adjusted Standard, and quarterly thereafter for the first 12 months
following the effective date
of this Adjusted Standard, BFI shall test a
representative sample
of the leachate and submit test results demonstrating
compliance with the requirements
ofparagraph (c) above to the Illinois
Environmental Protection Agency. Quarterly sampling shall continue until such
time
as BFI has demonstrated compliance (including, ifnecessary, a compliance
demonstrated
by a verification test) in four consecutive quarters. Thereafter, such
testing
shaH continue on a semi-annual basis. For any such initial, quarterly, or
annual testing,
if an original sample fails to meet the requirements ofparagraph
(c), then a verification sample will be coHected within 7 days and Verification
Testing
shaH be performed for the constituent(s) which failed to meet the
requirements
ofparagraph (c). A verified failure to meet the requirements in
paragraph (c) will
be deemed present ifboth the original and verification sample
fail to meet such requirements.
e)
If a failure to meet the requirements in paragraph (c) is verified pursuant
to the verification procedures in paragraph (d), BFI shaH notify the Illinois EPA
and the leachate shaH not
be transported or disposed of except as a hazardous
waste until such time as
it is demonstrated by the Confirmatory Testing
procedures below to meet the requirements
ofparagraph (c). Prior to re-initiating
transportation and disposal pursuant to this Adjusted Standard, BFI must perform
Confirmatory Testing, including testing
of a minimum of four representative
samples taken over not less than a 14 day period, each
of which confirms that the
leachate meets the requirements
ofparagraph (c), and BFI shall submit such
results to the Illinois Environmental Protection Agency with a notification it
intends to re-initiate transportation and disposal pursuant to the Adjusted
Standard.
f)
The leachate is transported in compliance with the requirements applicable
to an Illinois Special Waste (35
Ill.
Adm. Code Part 809) to and received by a
permitted waste water treatment facility located in Illinois which has a
Pretreatment Program which has been approved
by the United States
Environmental Protection Agency.
g)
At least 30 days prior to transporting the first load of delisted leachate,
BFI shall provide the Illinois Environmental Protection Agency with the results
of
a test of a representative sample of the leachate demonstrating compliance with
the requirements
ofparagraph (c) and a one-time written notification stating that it
intends to commence transportation of delisted leachate pursuant to this delisting
and the name
of the waste water treatment facility to which the leachate will be
transported.
If BFI changes disposal facilities, it shaH provide to Illinois
Environmental Protection Agency a one-time written notification
of such change;
and
Electronic Filing - Received, Clerk's Office, June 30, 2008

h)
BFI shall not transport the leachate pursuant to this Adjusted Standard
outside ofthe State of Illinois.
i)
This adjusted standard waste delisting shall apply once the leachate is
loaded for transport at the BFI Davis Junction Landfill in Davis Junction, Ogle
County, Illinois and during any subsequent transportation and handling, but shall
not apply to any leachate from the Davis Junction facility which is released from
the tanker truck to the environment (at the Davis Junction facility or at any other
location) prior
to delivery to a permitted waste water treatment facility as
described in paragraph
(f) above.
j)
Any such leachate released to the environment as described in paragraph
(i) above shall
be considered a Resource Conservation and Recovery Act
("RCRA) listed hazardous waste and any such released leachate shall be
addressed in accordance with applicable RCRA requirements.
Table A
Arsenic
0.525
Barium
100
Benzene
0.153
Cadmium
0.409
Carbon Disulfide
118
Chromium
5.0
Dichloropropene, cis-I, 3-
1,206
Cobalt
118
Copper
24,700
Diethyl phthalate
1,270
Endrin
32,700
Ethylbenzene
57.2
Isobutyl alcohol
299
Lead
5.0
Mercury
0.2
Methanol
499
Methyl ethyl ketone
200
Methylene chloride
0.198
Methyl isobutyl ketone
79.8
Naphthalene
6.51
Nickel
76.8
Cresol, p-
5.37
Phenol
645
Selenium
1.57
Styrene
6.2
Tetrachloroethylene
0.174
Tin
1180
Toluene
40.2
Trichloroethylene
0.164
Vanadium
57.1
Electronic Filing - Received, Clerk's Office, June 30, 2008

Vinyl cWoride
0.2
Xvlenes (total)
160
Zinc
760
DicWoroethane, 1-1-
99.8
DicWoroethane, 1,2-
0.0354
Dichlorobenzene, 1,4-
0.473
Dioxane, 1,4-
100
HeotacWor
0.008
TCDD,2,3,7,8-
0.00000147
Trichloroohenoxvoripionic acid, 2,4, 5- (Silvex)
1.0
DicWoroohenoxyacetic acid, 2,4- (2,4-D)
1.86
Dimethylphenol, 2,4-
27.6
Acetone
898
Respectfully submitted,
BFI aste Management Sys ems
ofNorth America
By One of lis Attomeys
June 30, 2008
Patricia F. Sharkey
McGuireWoods LLC
Suite 4100
77 West Wacker Drive
Chicago, Illinois 60601
(312) 849-8100
\6371344.1
Electronic Filing - Received, Clerk's Office, June 30, 2008

 
CAS No.
Units
Mean
Variance
Standard
Deviation
+ 1,1,1,2-Tetrachloroethane
630-20-6
< 0.005
< 0.005
< 0.01
< 0.01
< 0.1
< 0.01
< 0.01
< 0.01
mg/L
0.020
0.001
0.032
+ 1,1,1-Trichloroethane
71-55-6
< 0.005
< 0.005
< 0.01
< 0.01
< 0.1
< 0.01
< 0.01
< 0.01
mg/L
0.020
0.001
0.032
+ 1,1,2,2-Tetrachloroethane
79-34-5
< 0.005
< 0.005
< 0.01
< 0.01
< 0.1
< 0.01
< 0.01
< 0.01
mg/L
0.020
0.001
0.032
+ 1,1,2-Trichloroethane
79-00-5
< 0.005
< 0.005
< 0.01
< 0.01
< 0.1
< 0.01
< 0.01
< 0.01
mg/L
0.020
0.001
0.032
+ 1,1-Dichloroethane
75-34-3
< 0.005
0.023
0.013
0.068
< 0.1
0.037
0.097
< 0.01
0.042
< 0.01
< 0.05
< 0.1
0.021
0.013
mg/L
0.042
0.001
0.036
+ 1,1-Dichloroethylene
75-35-4
< 0.005
< 0.005
< 0.01
< 0.01
< 0.1
< 0.01
mg/L
0.023
0.001
0.038
+ 1,2,3,4,6,7,8,9 - OCDD
< 6E-07
< 6E-07
2E-06
5.7E-06
< 0.01
mg/L
0.002
0.000
0.004
+ 1,2,3,4,6,7,8,9 - OCDF
< 6E-07
< 5E-07
< 2E-07
< 3E-07
mg/L
0.000
0.000
0.000
+ 1,2,3,4,6,7,8-HpCDD
< 4E-07
< 4E-07
2E-07
3.8E-07
mg/L
0.000
0.000
0.000
+ 1,2,3,4,6,7,8-HpCDF
< 3E-07
< 3E-07
< 1E-07
< 1E-07
mg/L
0.000
0.000
0.000
+ 1,2,3,4,7,8,9-HpCDF
< 3E-07
< 3E-07
< 1E-07
< 2E-07
mg/L
0.000
0.000
0.000
+ HxCDDs (all hexachlorodibenzo-p-dioxins)
< 3E-07
< 3E-07
< 1E-07
< 1E-07
mg/L
0.000
0.000
0.000
+ HxCDFs (all hexachlorodibenzofurans)
< 3E-07
< 3E-07
< 8E-07
< 1E-07
mg/L
0.000
0.000
0.000
+ PeCDDs (all pentachlorodibenzo-p-dioxins)
< 2E-07
< 4E-07
< 2E-07
< 2E-07
mg/L
0.000
0.000
0.000
+ PeCDFs (all pentachlorodibenzofurans)
< 2E-07
< 2E-07
< 2E-07
< 1E-07
mg/L
0.000
0.000
0.000
+ TCDDs (all tetrachlorodibenzo-p-dioxins)
< 1E-07
< 2E-07
< 2E-07
2E-07
< 1E-07
< 2E-07
< 1E-07
mg/L
0.000
0.000
0.000
+ TCDFs (all tetrachlorodibenzofurans)
< 1E-07
< 2E-07
1E-07
< 8E-08
mg/L
0.000
0.000
0.000
+ 1,2,3-Trichloropropane
96-18-4
< 0.005
< 0.015
< 0.01
< 0.01
< 0.1
< 0.01
< 0.01
< 0.01
mg/L
0.021
0.001
0.032
+ 1,2,4,5-Tetrachlorobenzene
95-34-3
< 0.1
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.192
0.026
0.163
+ 1,2,4-Trichlorobenzene
120-82-1
< 0.1
< 0.005
< 0.25
< 0.5
<0.1
<0.1
mg/L
0.176
0.031
0.177
+ 1,2-Dibromo-3-chloropropane
96-12-8
< 0.01
< 0.026
< 0.02
< 0.02
< 0.2
< 0.02
< 0.02
< 0.02
mg/L
0.042
0.004
0.064
+ 1,2-Dibromoethane
106-93-4
< 0.005
< 0.005
< 0.01
< 0.01
< 0.1
< 0.01
< 0.01
mg/L
0.021
0.001
0.035
+ 1,2-Dichlorobenzene
95-50-1
< 0.1
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.192
0.026
0.163
+ 1,2-Dichloroethane
107-06-2
< 0.005
< 0.005
< 0.01
0.023
< 0.1
< 0.01
< 0.01
< 0.01
mg/L
0.022
0.001
0.032
+ 1,2-Dichloropropane
78-87-5
< 0.005
< 0.005
< 0.01
< 0.01
< 0.1
< 0.01
< 0.01
< 0.01
mg/L
0.020
0.001
0.032
+ 1,3-Dichlorobenzene
541-73-1
< 0.1
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.192
0.026
0.163
+ 1,3-Dinitrobenzene
99-65-0
< 0.5
< 2
< 1.3
< 2.5
< 0.5
< 0.5
< 0.5
mg/L
1.114
0.708
0.841
+ 1,4-Dichlorobenzene
106-46-7
< 0.1
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.192
0.026
0.163
1,4-Dichlorobenzene, TCLP
106-46-7
< 0.05
mg/L
0.050
0.000
0.000
+ 1,4-Dioxane
123-91-1
<1
<1
15
<2
< 20
17
17
24
20
33
26
5.2
21
<2
mg/L
14.586
111.049
10.538
+ 1,4-Naphthoquinone
130-15-4
< 0.5
< 2
< 1.3
< 2.5
< 0.5
< 0.5
< 0.5
mg/L
1.114
0.708
0.841
+ 1-Naphthylamine
134-31-7
< 0.5
< 2
< 1.3
< 2.5
< 0.5
< 0.5
< 0.5
mg/L
1.114
0.708
0.841
+ 2-Naphthylamine
91-59-8
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ 2,3,4,6-Tetrachlorophenol
58-90-2
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ 2,4,5-T
93-76-5
< 0.001
< 0.02
< 0.01
< 0.01
< 0.1
mg/L
0.028
0.002
0.041
+ 2,4,5-TP (Silvex)
93-72-1
0.0049
< 0.02
< 0.01
< 0.1
0.058
< 0.1
< 0.2
< 0.2
< 0.5
< 0.01
0.024
< 0.02
mg/L
0.104
0.020
0.143
2,4,5-TP (Silvex), TCLP
93-72-1
0.022
< 0.5
< 0.1
< 0.2
< 0.5
< 0.01
0.083
< 0.01
mg/L
0.178
0.043
0.208
+ 2,4,5-Trichlorophenol
95-95-4
< 0.1
< 0.01
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.166
0.027
0.163
+ 2,4,6-Trichlorophenol
88-06-2
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ 2,4-D
94-75-7
< 0.01
< 0.2
< 0.01
< 0.01
< 0.01
< 0.1
< 0.04
< 0.04
< 0.1
< 0.01
0.11
< 0.04
mg/L
0.057
0.004
0.059
2,4-D TCLP
94-75-7
< 0.005
< 0.5
<1
<2
<5
< 0.1
0.39
< 0.1
mg/L
1.137
2.869
1.694
+ 2,4-Dichlorophenol
120-83-2
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ 2,4-Dimethylphenol
105-67-9
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
<0.1
0.14
mg/L
0.227
0.027
0.164
+ 2,4-Dinitrophenol
51-28-5
< 0.5
< 0.4
< 1.3
< 2.5
< 0.5
< 0.5
< 0.5
mg/L
0.886
0.601
0.776
+ 2,4-Dinitrotoluene
121-14-2
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ 2,6-Dichlorophenol
87-65-0
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ 2,6-Dinitrotoluene
606-20-2
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
mg/L
0.242
0.030
0.174
+ 2-Acetylaminofluorene
53-96-3
< 0.1
< 0.4
< 0.25
< 0.1
< 0.1
< 0.1
mg/L
0.175
0.016
0.125
+ 2-Chloronaphthalene
91-58-7
< 0.1
< 0.4
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.244
0.028
0.168
+ 2-Chlorophenol
95-57-8
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ 2-Hexanone
591-78-6
< 0.01
< 0.05
< 0.02
< 0.02
< 0.2
< 0.02
< 0.1
mg/L
0.060
0.005
0.069
+ 2-Methylnaphthalene
91-57-6
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.2
< 0.1
mg/L
0.236
0.026
0.160
+ 2-Nitrophenol
88-75-5
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ 2-Picoline
109-06-8
< 0.5
< 2
< 1.3
< 2.5
< 0.5
< 0.5
< 0.5
mg/L
1.114
0.708
0.841
+ 2-sec-butyl-4,6-dinitrophenol (dinoseb)
88-85-7
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ 3,3'-Dichlorobenzidine
91-94-1
< 0.2
< 0.8
< 0.25
<1
< 0.2
< 0.2
< 0.2
mg/L
0.407
0.117
0.342
+ 3,3'-Dimethylbenzidine
119-93-7
< 0.2
< 0.8
< 0.5
<1
< 0.2
< 0.2
mg/L
0.483
0.122
0.349
3-Chloropropene (allyl chloride)
107-05-1
< 0.04
< 0.4
< 0.04
< 0.04
< 0.04
mg/L
0.112
0.026
0.161
+ 3-Methylchloranthrene
56-49-5
< 0.25
< 0.1
< 0.1
mg/L
0.150
0.008
0.087
+ 4,4'-DDD
72-54-8
< 0.005
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.176
0.031
0.177
+ 4,4'-DDE
72-55-9
< 0.0005
< 0.001
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.150
0.031
0.175
+ 4,4'-DDT
50-29-3
< 0.0005
< 0.001
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.150
0.031
0.175
+ 4-6-Dinitro-o-cresol
534-52-1
< 0.4
< 1.3
< 2.5
< 0.5
< 0.5
< 0.5
mg/L
0.950
0.687
0.829
+ 4-Aminobiphenyl
92-67-1
< 0.1
< 0.4
< 0.25
< 0.1
< 0.1
< 0.1
mg/L
0.175
0.016
0.125
4/4/2001
2/27/2002
5/3/2005
5/25/2005
1/29/2007
4/3/2003
2/16/2005
4/14/2005
4/20/2005
1/12/2006
3/22/2006
Phase I (Hazardous) Leachate
11/4/1999
Parameter
3/13/2001
2/18/2004
6/23/2005
Table I
Davis Junction Landfill
Summary Historical Data from Phase I Landfill Leachate and Variability Assessment
AS 08-5,063008
Att 5.xls
Page 1 of 5
Electronic Filing - Received, Clerk's Office, June 30, 2008

CAS No.
Units
Mean
Variance
Standard
Deviation
4/4/2001
2/27/2002
5/3/2005
5/25/2005
1/29/2007
4/3/2003
2/16/2005
4/14/2005
4/20/2005
1/12/2006
3/22/2006
Phase I (Hazardous) Leachate
11/4/1999
Parameter
3/13/2001
2/18/2004
6/23/2005
Table I
Davis Junction Landfill
Summary Historical Data from Phase I Landfill Leachate and Variability Assessment
+ 4-Bromophenyl phenyl ether
101-55-3
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ 4-Chloro-3-methylphenol
59-50-7
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.210
0.031
0.175
+ 4-Chlorophenyl phenyl ether
7005-72-3
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+
60-11-7
<0.1
<0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.192
0.026
0.163
+ 4-Nitrophenol (p-nitrophenol)
100-02-7
< 0.5
< 2
< 1.3
< 2.5
< 0.5
< 0.5
< 0.5
mg/L
1.114
0.708
0.841
+ 4-Nitroquinoline-N-oxide
56-57-5
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ 5-Nitro-o-toluidine
99-55-8
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ 7,12-Dimethylbenzo(a)anthracene
57-97-6
< 0.2
< 0.8
< 0.5
< 1.0
< 0.2
< 0.2
< 0.2
mg/L
0.443
0.113
0.336
+ Acenaphthene
83-32-9
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ Acenaphthylene
208-96-8
< 0.1
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.192
0.026
0.163
+ Acetone
67-64-1
0.75
6.9
3
20
12
6.6
7
4.2
4.8
7.7
4.1
< 1
3
0.44
mg/L
5.821
26.644
5.162
+ Acetonitrile
75-05-8
< 0.05
< 0.2
< 1.0
<0.1
<1
mg/L
0.470
0.237
0.487
+ Acetophenone
98-86-2
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ Acrolein
107-02-8
< 0.05
< 0.026
< 0.1
< 0.1
< 1.0
< 0.1
< 0.2
< 0.1
mg/L
0.210
0.105
0.323
+ Acrylonitrile
107-13-1
< 0.07
< 0.05
< 0.14
< 0.14
< 1.4
< 0.14
< 0.1
< 0.14
mg/L
0.273
0.209
0.457
Alachlor
< 0.001
< 0.0005 < 0.001
< 0.0005
mg/L
0.001
0.000
0.000
+ Aldrin
309-00-2
< 0.00025
< 0.0005
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.150
0.031
0.175
+ alpha-BHC
319-84-6
< 0.00025
< 0.0005
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.150
0.031
0.175
+ Aniline
62-53-4
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ Anthracene
120-12-7
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ Antimony, Total
7440-36-0
< 0.03
< 0.012
< 0.04
< 0.05
< 0.02
< 0.05
< 0.02
< 0.2
mg/L
0.053
0.004
0.061
+ Aramite
140-57-8
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ Aroclor 1016
< 0.5
< 0.005
< 1.3
< 2.5
< 0.5
< 0.5
< 0.001
< 0.0005 < 0.001
< 0.0005
< 0.5
mg/L
0.528
0.587
0.766
+ Aroclor 1221
< 0.5
< 0.005
< 1.3
< 2.5
< 0.5
< 0.5
< 0.001
< 0.0005 < 0.001
< 0.0005
< 0.5
mg/L
0.528
0.587
0.766
+ Aroclor 1232
< 0.5
< 0.005
< 1.3
< 2.5
< 0.5
< 0.5
< 0.001
< 0.0005 < 0.001
< 0.0005
< 0.5
mg/L
0.528
0.587
0.766
+ Aroclor 1242
< 0.5
< 0.005
< 1.3
< 2.5
< 0.5
< 0.5
< 0.001
< 0.0005 < 0.001
< 0.0005
< 0.5
mg/L
0.528
0.587
0.766
+ Aroclor 1248
< 0.5
< 0.005
< 1.3
< 2.5
< 0.5
< 0.5
< 0.001
< 0.0005 < 0.001
< 0.0005
< 0.5
mg/L
0.528
0.587
0.766
+ Aroclor 1254
< 0.5
< 0.01
< 1.3
< 2.5
< 0.5
< 0.5
< 0.002
< 0.0005 < 0.002
< 0.001
< 0.5
mg/L
0.529
0.587
0.766
+ Aroclor 1260
< 0.5
< 0.01
< 1.3
< 2.5
< 0.5
< 0.5
< 0.002
< 0.0005 < 0.002
< 0.001
< 0.5
mg/L
0.529
0.587
0.766
Arsenic, TCLP
< 0.05
< 0.05
< 0.05
< 0.05
< 0.05
< 0.05
< 0.05
0.05
< 0.05
mg/L
0.050
0.000
0.000
+ Arsenic, Total
7440-38-2
0.011
0.054
< 0.04
< 0.05
0.02
< 0.05
0.012
0.016
< 0.0012
0.021
0.016
0.013
< 0.02
< 0.2
mg/L
0.037
0.002
0.050
Barium, TCLP
7440-39-3
0.93
0.6
0.81
0.6
0.39
0.46
0.55
0.64
0.62
0.0009
mg/L
0.560
0.063
0.250
+ Barium, Total
7440-39-3
0.19
< 0.14
0.48
1.2
1.1
0.86
1.3
0.68
0.56
0.8
0.55
0.66
0.79
< 0.88
mg/L
0.728
0.115
0.340
+ Benzene
71-43-2
< 0.005
0.02
0.012
< 0.01
< 0.1
0.027
< 0.011
mg/L
0.026
0.001
0.033
+ Benzo(a)anthracene
56-55-3
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ Benzo(a)pyrene
50-32-8
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ Benzo(b)fluoranthene
205-99-2
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ Benzo(g,h,i)perylene
191-24-2
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ Benzo(k)fluoranthene
207-08-9
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ Benzyl alcohol
100-51-6
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ Beryllium, Total
7440-41-8
< 0.004
< 0.01
< 0.02
< 0.02
< 0.008
< 0.01
< 0.008
< 0.08
mg/L
0.020
0.001
0.025
+ beta-BHC
319-85-7
< 0.00025
< 0.0005
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.150
0.031
0.175
+ bis (2-chloro-1-methylethyl) ether
108-60-1
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.200
0.040
0.200
+ bis(2-Chloroethoxy)methane
111-91-1
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ bis(2-Chloroethyl)ether
111-44-4
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
bis(2-Chloroisopropyl)ether
39638-32-9
< 0.1
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.192
0.026
0.163
+ bis(2-Ethylhexyl)phthalate
117-81-7
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ Bromodichloromethane
75-27-4
< 0.005
< 0.01
< 0.01
< 0.1
< 0.01
< 0.01
< 0.01
mg/L
0.022
0.001
0.034
+ Bromoform
75-25-2
< 0.005
< 0.005
< 0.01
< 0.01
< 0.1
< 0.01
< 0.01
< 0.01
mg/L
0.020
0.001
0.032
+ Bromomethane (methyl bromide)
74-83-9
< 0.01
< 0.01
< 0.02
< 0.02
< 0.2
< 0.02
< 0.02
< 0.02
mg/L
0.040
0.004
0.065
+ Butyl Benzyl Phthalate
85-68-7
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
Cadmium, TCLP
7440-43-9
< 0.025
< 0.025
< 0.025
< 0.025
< 0.025
< 0.025
< 0.025
< 0.025
< 0.025
< 5E-05
mg/L
0.023
0.000
0.008
+ Cadmium, Total
7440-43-9
0.0027
0.0025
< 0.02
< 0.025
< 0.01
< 0.01
0.018
0.0088
0.0069
0.0071
0.0048
0.0048
< 0.01
< 0.01
mg/L
0.010
0.000
0.007
+ Carbon disulfide
75-15-0
0.061
< 0.005
< 0.01
< 0.01
< 0.1
< 0.01
< 0.01
< 0.01
mg/L
0.027
0.001
0.035
+ Carbon tetrachloride
56-23-5
< 0.005
< 0.005
< 0.01
< 0.01
< 0.1
< 0.01
< 0.01
< 0.01
mg/L
0.020
0.001
0.032
+ Chlordane
57-74-9
< 0.003
< 0.005
< 1.3
< 2.5
< 0.5
< 0.5
< 0.005
< 0.001
< 0.0005
< 0.005
< 0.001
< 0.0005
< 0.5
mg/L
0.409
0.543
0.737
Chlordane, TCLP
57-74-9
< 0.0005
< 0.0005
< 0.004
< 0.004
< 0.004
< 0.004
< 0.004
< 0.004
< 0.0025
mg/L
0.003
0.000
0.002
+ Chlorobenzene
108-90-7
< 0.005
< 0.005
< 0.01
< 0.01
< 0.1
< 0.01
< 0.01
< 0.01
mg/L
0.020
0.001
0.032
+ Chlorobenzilate
510-15-6
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ Chlorodibromomethane
124-48-1
< 0.005
< 0.01
< 0.01
< 0.1
< 0.01
< 0.01
< 0.01
mg/L
0.022
0.001
0.034
+ Chloroethane
75-00-3
< 0.01
< 0.01
< 0.02
< 0.02
< 0.2
< 0.02
< 0.02
0.02
mg/L
0.040
0.004
0.065
+ Chloroform
67-66-3
< 0.005
< 0.005
< 0.01
< 0.01
< 0.1
< 0.01
< 0.01
< 0.01
mg/L
0.020
0.001
0.032
+ Chloroprene
126-99-8
< 0.005
< 0.01
< 0.1
< 0.01
< 0.01
mg/L
0.027
0.002
0.041
4-(Dimethylamino)azobenzene
(p-(dimethylamino) azobenzene)
AS 08-5,063008
Att 5.xls
Page 2 of 5
Electronic Filing - Received, Clerk's Office, June 30, 2008

CAS No.
Units
Mean
Variance
Standard
Deviation
4/4/2001
2/27/2002
5/3/2005
5/25/2005
1/29/2007
4/3/2003
2/16/2005
4/14/2005
4/20/2005
1/12/2006
3/22/2006
Phase I (Hazardous) Leachate
11/4/1999
Parameter
3/13/2001
2/18/2004
6/23/2005
Table I
Davis Junction Landfill
Summary Historical Data from Phase I Landfill Leachate and Variability Assessment
Chromium, TCLP
7440-47-4
< 0.078
0.079
0.087
0.1
0.096
0.077
0.071
0.099
0.064
0.0001
mg/L
0.075
0.001
0.029
+ Chromium, Total
7440-47-4
0.06
0.21
0.12
0.094
0.11
0.11
0.12
0.11
< 0.1
0.1
0.11
< 0.12
mg/L
0.114
0.001
0.035
+ Chrysene
218-01-9
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ cis-1,3-Dichloropropylene
10061-01-5
< 0.005
< 0.005
< 0.01
< 0.01
< 0.1
< 0.01
0.01
mg/L
0.021
0.001
0.035
+ Cobalt, Total
7440-48-4
0.032
0.1
3.0
0.12
< 0.5
1.7
2.1
mg/L
1.079
1.405
1.185
+ Copper, Total
7440-50-8
< 0.02
0.025
< 0.08
< 0.05
< 0.04
< 0.05
< 0.04
< 0.4
mg/L
0.088
0.016
0.127
+ Cyanide, Total
57-12-5
< 0.005
< 0.05
< 0.005
< 0.005
< 0.005
< 0.005
mg/L
0.013
0.000
0.018
Cyclohexanone
< 0.125
mg/L
0.125
0.000
0.000
+ delta-BHC
319-86-8
< 0.00025
< 0.0005
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.133
0.035
0.186
+ Diallate
2303-16-4
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ Dibenzo(a,h)anthracene
53-70-3
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ Dibenzofuran
132-64-9
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ Dibromomethane (methylene bromide)
74-95-3
< 0.005
< 0.005
< 0.01
< 0.01
< 0.1
< 0.01
< 0.01
< 0.01
mg/L
0.020
0.001
0.032
+ Dichlorodifluoromethane
75-71-8
< 0.01
< 0.005
< 0.02
< 0.02
< 0.2
< 0.02
< 0.02
mg/L
0.042
0.005
0.070
+ Dieldrin
60-57-1
< 0.0005
< 0.001
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.150
0.031
0.175
+ Diethyl phthalate
84-66-2
< 0.1
< 0.4
< 0.25
0.54
< 0.1
< 0.1
0.27
< 0.25
0.12
< 0.2
< 0.1
0.031
0.13
mg/L
0.199
0.020
0.143
+ Dimethoate
60-51-5
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+
< 0.2
< 0.8
< 0.5
< 1.0
< 0.2
< 0.2
< 0.2
mg/L
0.443
0.113
0.336
+ Dimethyl phthalate
131-11-3
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ Di-n-butyl phthalate
84-74-2
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ Di-n-octyl phthalate
117-84-0
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
Di-N-Propylnitrosamine
< 0.5
< 2.0
< 1.3
< 2.5
< 0.5
< 0.5
< 0.5
mg/L
1.114
0.708
0.841
+ Diphenylamine
122-39-4
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ Disulfoton
298-04-4
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ Endosulfan I
115-29-7
< 0.1
< 0.0005
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.164
0.027
0.165
+ Endosulfan II
115-29-7
< 0.1
< 0.001
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.164
0.027
0.165
+ Endosulfan sulfate
1031-07-8
< 0.1
< 0.001
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.164
0.027
0.165
+ Endrin aldehyde
7421-93-4
< 0.1
< 0.001
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.164
0.027
0.165
Endrin ketone
< 0.0005
mg/L
0.001
0.000
0.000
+ Endrin
72-20-8
< 0.0005
< 0.001
< 0.001
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.115
0.031
0.177
Endrin, TCLP
72-20-8
0.0015
< 0.0001
< 0.001
< 0.001
< 0.001
< 0.001
< 0.001
< 0.001
0.001
mg/L
0.001
0.000
0.000
+ Ethyl methacrylate
97-63-2
< 0.005
< 0.005
< 0.01
< 0.01
< 0.1
< 0.01
< 0.01
mg/L
0.021
0.001
0.035
+ Ethyl methanesulfonate
62-50-0
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
< 0.1
mg/L
0.206
0.026
0.161
+ Ethylbenzene
100-41-4
< 0.005
0.15
0.088
0.098
0.25
0.21
0.25
0.15
0.18
0.18
0.13
0.2
0.12
0.092
mg/L
0.150
0.005
0.068
+ Famphur
52-85-7
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
<0.1
<2
mg/L
0.493
0.467
0.683
Flash Point
> 200
> 200
> 200
> 200
> 200
> 200
> 200
> 200
> 200
> 200
Deg. F
200.000
0.000
0.000
+ Fluoranthene
206-44-0
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ Fluorene
86-73-7
< 0.1
< 0.4
< 0.25
< 0.1
< 0.1
< 0.1
mg/L
0.175
0.016
0.125
+ gamma-BHC (Lindane)
58-89-9
< 0.00025
< 0.0005
< 0.25
< 0.5
< 0.1
< 0.1
< 0.0005
< 0.0001 < 0.00005
< 5E-05 < 0.0001
< 0.00005
< 0.1
mg/L
0.081
0.021
0.146
gamma-BHC (Lindane), TCLP
58-89-9
< 0.0005
< 0.00005
< 0.001
< 0.001
< 0.001
< 0.001
< 0.001
< 0.001
< 0.0025
mg/L
0.001
0.000
0.001
+ Heptachlor
76-44-8
< 0.00025
< 0.0005
< 0.25
< 0.5
< 0.1
< 0.1
< 0.0005
< 0.0001 < 0.00005
< 5E-05 < 0.0001
< 0.00005
< 0.1
< 0.0025
mg/L
0.075
0.020
0.142
Heptachlor, TCLP
76-44-8
0.00053
< 0.00005
< 0.001
< 0.001
< 0.001
< 0.001
< 0.001
< 0.001
< 0.0025
mg/L
0.001
0.000
0.001
+ Heptachlor epoxide
1024-57-3
< 0.00025
< 0.0005
< 0.25
< 0.5
< 0.1
< 0.1
< 0.0005
< 0.0001 < 0.00005
< 5E-05 < 0.0001
< 0.00005
< 0.1
< 0.0025
mg/L
0.075
0.020
0.142
Heptachlor epoxide, TCLP
1024-57-3
< 0.0005
< 0.00005
< 0.001
< 0.001
< 0.001
< 0.001
< 0.001
< 0.001
< 0.0025
mg/L
0.001
0.000
0.001
+ Hexachlorobenzene
118-74-1
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ Hexachlorobutadiene
87-68-3
< 0.1
< 0.005
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.165
0.027
0.164
+ Hexachlorocyclopentadiene
77-47-4
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ Hexachloroethane
67-72-1
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ Hexachlorophene
70-30-4
<2
<8
<5
< 10
<2
<2
<2
mg/L
4.429
11.286
3.359
+ Hexachloropropene
1888-71-7
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ Indeno(1,2,3-cd)pyrene
193-39-5
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ Iodomethane
< 0.01
< 0.01
< 0.02
< 0.02
< 0.2
< 0.02
< 0.02
< 0.02
mg/L
0.040
0.004
0.065
+ Isobutyl alcohol
78-83-1
<1
<2
3.7
< 20
<2
<2
<2
mg/L
4.671
46.322
6.806
+ Isodrin
465-73-6
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ Isophorone
78-59-1
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ Isosafrole
120-58-1
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ Kepone
143-50-0
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
<0.1
<2
mg/L
0.493
0.467
0.683
Lead, TCLP
7439-92-1
< 0.05
< 0.05
< 0.05
< 0.05
< 0.05
< 0.05
< 0.05
< 0.05
< 0.1
mg/L
0.056
0.000
0.017
+ Lead, Total
7439-92-1
0.038
0.012
0.018
0.18
0.074
0.12
0.15
0.068
0.069
0.064
0.054
0.065
0.087
< 0.076
mg/L
0.077
0.002
0.047
+ m-Cresol
108-39-4
< 0.1
< 0.005
< 0.1
< 0.1
mg/L
0.076
0.002
0.048
Mercury, TCLP
7439-97-6
< 0.002
< 0.002
< 0.002
< 0.002
< 0.002
< 0.002
< 0.002
< 2E-06
< 0.002
< 0.002
mg/L
0.002
0.000
0.001
+ Mercury, Total
7439-97-6
< 0.0002
0.04
< 0.0002
< 0.0004
< 0.0002
< 0.0002
< 0.0002
< 0.0002 < 0.0002
< 0.0002 < 0.00005 < 0.0002
< 0.0002
< 0.002
mg/L
0.003
0.000
0.011
+ Methacrylonitrile
126-98-7
< 0.02
< 0.02
< 0.04
< 0.04
< 0.4
< 0.04
< 0.04
< 0.04
mg/L
0.080
0.017
0.130
Dimethyl benzeneethanamine
(alpha, alpha-Dimethylphenethylamine)
AS 08-5,063008
Att 5.xls
Page 3 of 5
Electronic Filing - Received, Clerk's Office, June 30, 2008

CAS No.
Units
Mean
Variance
Standard
Deviation
4/4/2001
2/27/2002
5/3/2005
5/25/2005
1/29/2007
4/3/2003
2/16/2005
4/14/2005
4/20/2005
1/12/2006
3/22/2006
Phase I (Hazardous) Leachate
11/4/1999
Parameter
3/13/2001
2/18/2004
6/23/2005
Table I
Davis Junction Landfill
Summary Historical Data from Phase I Landfill Leachate and Variability Assessment
Methanol
67-56-1
1.4
mg/L
1.400
0.000
0.000
+ Methapyrilene
91-80-5
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ Methoxychlor
72-43-5
< 0.0025
< 0.0005
< 0.25
< 0.5
< 0.1
< 0.1
< 0.005
< 0.001
< 0.0005
< 0.0005 < 0.001
< 0.0005
< 0.1
mg/L
0.082
0.021
0.146
Methoxychlor, TCLP
72-43-5
< 0.0005
< 0.0005
< 0.002
< 0.002
< 0.002
< 0.002
< 0.002
< 0.002
< 0.0025
mg/L
0.002
0.000
0.001
+ Methyl chloride (chloromethane)
74-87-3
< 0.01
< 0.005
< 0.02
< 0.02
< 0.2
< 0.02
mg/L
0.046
0.006
0.076
+ Methyl ethyl ketone
78-93-3
0.47
7.8
1.7
12
9.3
8.6
6.8
2.8
4.6
6.4
2.9
<2
< 0.1
mg/L
5.036
13.942
3.734
+ Methyl methacrylate
80-62-6
< 0.005
< 0.005
< 0.01
< 0.01
< 0.1
< 0.01
< 0.1
< 0.01
mg/L
0.031
0.002
0.042
+ Methyl methanesulfonate
66-27-3
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ Methyl parathion
298-00-00
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ Methylene chloride (dichloromethane)
75-09-2
< 0.005
0.031
< 0.01
0.58
< 0.1
< 0.01
0.01
< 0.01
mg/L
0.095
0.039
0.199
+
108-10-1
0.066
0.77
0.14
0.9
1.0
1.8
0.67
< 0.1
mg/L
0.681
0.345
0.588
+ Naphthalene
91-20-3
< 0.1
0.038
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.170
0.025
0.159
N-Butyl Alcohol
< 5
< 0.2
mg/L
2.600
11.520
3.394
+ Nickel, Total
7440-02-0
0.39
0.72
0.95
1
0.84
0.84
0.95
0.88
mg/L
0.821
0.038
0.195
+ Nitrobenzene
98-95-3
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ N-Nitrosodiethylamine
55-18-5
< 0.1
< 0.4
< 0.25
< 0.5
<0.1
<0.1
mg/L
0.242
0.030
0.174
+ N-Nitrosodimethylamine
62-75-9
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ N-Nitrosodi-n-butylamine
924-16-3
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ N-Nitrosodi-n-propylamine
621-64-7
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.242
0.030
0.174
+ N-Nitrosodiphenylamine
86-30-6
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ N-Nitrosomethylethylamine
10595-95-6
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ N-Nitrosomorpholine
59-89-2
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ N-Nitrosopiperidine
100-75-4
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ N-Nitrosopyrolidine
930-55-2
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ o,o,o-Triethyl phosphorothioate
126-68-1
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ o-Cresol
95-48-7
< 0.1
< 0.005
< 0.4
< 0.25
< 0.1
< 0.1
< 0.1
mg/L
0.151
0.017
0.131
+ o-Nitroaniline (2-Nitroaniline)
88-74-4
< 0.5
< 2.0
< 1.3
< 2.5
< 0.5
< 0.5
< 0.5
mg/L
1.114
0.708
0.841
+ m-Nitroaniline (3-Nitroaniline)
99-09-2
< 0.5
< 2
< 1.3
< 2.5
< 0.5
< 0.5
< 0.5
mg/L
1.114
0.708
0.841
+ p-Nitroaniline (4-Nitroaniline)
100-01-6
< 0.5
< 2
< 1.3
< 2.5
< 0.5
< 0.5
< 0.5
mg/L
1.114
0.708
0.841
+ o-Toluidine
95-53-4
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ Parathion
56-38-2
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ p-Chloroaniline (4-chloroaniline)
106-47-8
< 0.1
< 0.25
< 0.5
< 0.1
< 0.1
mg/L
0.210
0.031
0.175
+ p-Chloro-m-cresol
59-50-7
<0.1
<0.4
mg/L
0.250
0.045
0.212
+ p-Cresol
106-44-5
0.49
0.74
0.72
0.78
0.96
1.1
0.7
1.4
1.5
1.6
0.73
mg/L
0.975
0.139
0.373
+ Pentachlorobenzene
606-93-5
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ Pentachloroethane
76-01-7
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ Pentachloronitrobenzene
82-68-8
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ Pentachlorophenol
87-86-5
< 0.5
< 0.4
< 1.3
< 2.5
< 0.5
< 0.5
< 0.5
mg/L
0.886
0.601
0.776
pH (field)
6.5
6.8
SU
6.650
0.045
0.212
pH (Lab)
8.2
6.8
7.2
7.6
7.1
7.2
7.6
7.3
SU
7.375
0.179
0.423
+ Phenacetin
62-44-2
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ Phenanthrene
85-01-8
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ Phenol
108-95-2
0.16
< 0.4
< 0.25
0.91
0.14
0.31
0.27
< 0.25
0.2
0.24
0.28
0.1
0.14
mg/L
0.281
0.042
0.206
+ Phorate
298-02-2
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ p-Phenylenediamine
106-50-3
< 0.2
< 0.8
< 0.5
<1
< 0.2
< 0.2
mg/L
0.483
0.122
0.349
+ Pronamide
23950-58-5
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ Propionitrile
107-12-0
< 0.005
< 0.005
< 0.01
< 0.01
< 0.1
< 0.01
< 0.1
mg/L
0.034
0.002
0.045
+ Pyrene
129-00-0
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
+ Pyridine
110-86-1
< 0.5
< 0.05
< 1.3
< 2.5
< 0.5
< 0.5
< 0.5
mg/L
0.836
0.676
0.822
Reactive Cyanide
57-12-5
< 0.005
< 0.005
< 0.005
< 0.005
< 0.005
< 0.005
< 0.005
< 0.005
< 0.005
< 0.005
mg/L
0.005
0.000
0.000
+ Safrole
94-59-7
< 0.1
< 0.4
< 0.25
< 0.5
< 0.5
< 0.1
< 0.1
mg/L
0.279
0.035
0.187
Selenium, TCLP
< 0.05
< 0.05
< 0.05
< 0.05
< 0.05
< 0.05
< 0.05
< 0.05
< 0.05
< 0.1
mg/L
0.055
0.000
0.016
+ Selenium, Total
< 0.005
0.032
< 0.04
< 0.05
< 0.02
< 0.05
< 0.01
< 0.005
< 0.012
< 0.01
< 0.01
< 0.005
< 0.02
< 0.02
mg/L
0.021
0.000
0.016
Silver, TCLP
< 0.05
< 0.05
< 0.05
< 0.05
< 0.05
< 0.05
< 0.05
< 0.05
< 0.05
< 0.1
mg/L
0.055
0.000
0.016
+ Silver, Total
< 0.01
0.005
< 0.04
< 0.05
< 0.1
< 0.02
< 0.06
< 0.003
< 0.0075
< 0.006
< 0.006
< 0.003
< 0.02
< 0.02
mg/L
0.025
0.001
0.028
+ Styrene
100-42-5
< 0.005
< 0.017
0.087
< 0.01
< 0.1
< 0.01
< 0.01
< 0.01
mg/L
0.031
0.002
0.039
+ Sulfide as S
18496-25-8
4.4
< 0.001
< 10
< 1
< 10
<1
<1
<1
<1
<1
<1
< 7.1
0.5
mg/L
3.000
13.335
3.652
+ sym-Trinitrobenzene
99-35-4
< 0.2
< 0.8
< 0.5
<1
< 0.2
< 0.2
< 0.2
mg/L
0.443
0.113
0.336
+ Tetrachloroethylene
127-18-4
< 0.005
0.0059
< 0.01
< 0.01
< 0.1
< 0.01
< 0.01
< 0.01
mg/L
0.020
0.001
0.032
+ Tetraethyldithiopyrophosphate
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
Tetrahydrofuran
< 0.1
mg/L
0.100
0.000
0.000
+ Thallium, Total
< 0.5
< 0.012
< 0.04
< 0.05
< 0.2
< 0.1
< 0.2
mg/L
0.157
0.028
0.169
+ Thionazin
297-97-2
< 0.1
< 0.4
< 0.25
< 0.5
< 0.1
< 0.1
< 0.1
mg/L
0.221
0.028
0.168
Methyl-iso-butyl ketone
(4-Methyl-2-pentanone)
AS 08-5,063008
Att 5.xls
Page 4 of 5
Electronic Filing - Received, Clerk's Office, June 30, 2008

CAS No.
Units
Mean
Variance
Standard
Deviation
4/4/2001
2/27/2002
5/3/2005
5/25/2005
1/29/2007
4/3/2003
2/16/2005
4/14/2005
4/20/2005
1/12/2006
3/22/2006
Phase I (Hazardous) Leachate
11/4/1999
Parameter
3/13/2001
2/18/2004
6/23/2005
Table I
Davis Junction Landfill
Summary Historical Data from Phase I Landfill Leachate and Variability Assessment
+ Tin
7440-31-5
0.12
< 0.04
0.053
< 2.4
< 0.05
< 0.1
<1
mg/L
0.538
0.795
0.891
+ Toluene
108-88-3
0.073
0.26
0.25
0.13
< 0.59
0.42
0.47
0.23
0.27
0.26
0.27
0.3
0.26
0.13
mg/L
0.280
0.019
0.137
+ Toxaphene
8001-35-2
< 0.005
< 0.01
< 1.3
< 2.5
< 0.5
< 0.5
< 0.01
< 0.002
< 0.001
< 0.0001 < 0.002
< 0.001
< 0.5
mg/L
0.410
0.542
0.736
Toxaphene, TCLP
8001-35-2
< 0.001
< 0.001
< 0.04
< 0.04
< 0.04
< 0.04
< 0.04
< 0.04
< 0.005
mg/L
0.027
0.000
0.019
+ trans-1,2-Dichloroethylene
156-60-5
< 0.005
< 0.005
< 0.01
< 0.01
< 0.1
< 0.01
< 0.01
mg/L
0.021
0.001
0.035
+ trans-1,3-Dichloropropylene
10061-02-6
< 0.005
< 0.005
< 0.01
< 0.01
< 0.1
< 0.01
< 0.01
mg/L
0.021
0.001
0.035
+ trans-1,4-Dichloro-2-butene
110-57-6
< 0.02
< 0.005
< 0.04
< 0.04
< 0.4
< 0.04
< 0.04
mg/L
0.084
0.020
0.140
+ Trichloroethylene
79-01-6
< 0.005
0.017
< 0.01
0.026
< 0.1
< 0.01
0.53
< 0.01
mg/L
0.089
0.033
0.181
+ Trichlorofluoromethane
75-69-4
< 0.005
< 0.005
< 0.01
< 0.01
< 0.1
< 0.01
< 0.01
< 0.01
mg/L
0.020
0.001
0.032
+ Vanadium, Total
7440-62-2
< 0.01
0.036
< 0.04
< 0.05
< 0.02
< 0.02
< 0.02
< 0.2
mg/L
0.050
0.004
0.062
+ Vinyl acetate
108-05-4
< 0.01
< 0.05
< 0.02
< 0.02
< 0.2
< 0.02
< 0.02
mg/L
0.049
0.005
0.068
+ Vinyl chloride
75-01-4
< 0.01
< 0.01
< 0.02
0.16
< 0.2
< 0.02
0.44
0.087
mg/L
0.118
0.022
0.149
+ Xylenes (Total)
1330-20-7
0.014
0.38
0.34
0.53
1.10
0.98
1.1
0.5
0.77
0.64
0.61
0.64
0.45
0.37
mg/L
0.602
0.094
0.307
+ Zinc, Total
7440-66-6
1.4
0.3
1.3
10
< 0.04
0.81
1.3
0.53
mg/L
1.960
10.805
3.287
Average Variance and Standard Deviation:
1.015
0.346
+ Constituents listed in 35 IAC 724 Appendix I
Average Var/Stdev (w/ out two highest):
0.429
0.283
For landfill leachate (< 0.5% solids), total result (in mg/L) is equivalent to TCLP result in accordance with TCLP analytical method.
For non-detect results, the detection limit was used for purposes of calculating the mean, variance, and standard deviation.
AS 08-5,063008
Att 5.xls
Page 5 of 5
Electronic Filing - Received, Clerk's Office, June 30, 2008

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