1. THIS FILING IS BEING SUBMITTED ON RECYCLED PAPER
      2. STANDARD FOR GRANT OF VARIANCE RELIEF
      3. THIS FILING IS BEING SUBMITTED ON RECYCLED PAPER
      4. CERTIFICATE OF SERVICE
      5. SERVICE LIST
      6. VIA HAND DELIVERY
      7. ATTACHMENT A
      8. 2. PROCESS DESCRIPTION

RECE
WED
CLERK’S OFFICF
BEFORE THE POLLUTION CONTROL
BOARD
OF THE STATE OF ILLINOIS
MAR
1 ~2005
STATE
OF ILUNOIS
IN THE MATTER OF:
)
Pollution
Control
Boarc~
)
CITGO PETROLEUM CORPORATION and
)
PDV MIDWEST REFINING, L.L.C.,
)
)
PCB
05-85
Petitioners,
)
(Variance
Water)
)
V.
)
)
ILLINOIS ENVIRONMENTAL
)
PROTECTION AGENCY,
)
)
Respondent.
)
NOTICE OF FILING
To:
See Attached Service List
Please take notice that
on March
14,
2005,
we filed with the Office of the Clerk of the
Illinois
Pollution
Control
Board,
an
original
and
nine
copies
each
of
the
following
PETITIONERS’ POST-HEARING BRIEF REGARDING PETITION FOR
VARIANCE IN
CONNECTION WITH DISCHARGE OF
TOTAL DISSOL VED SOLIDS AND RESPONSES
TO ADDITIONAL
QUESTIONS FROM BOARD’S
TECHNICAL UNIT
copies ofwhich
are
hereby served upon you.
CITGO PETROLEUM CORPORATION and
PDV MIDWEST REFINING, L.L.C.
Jeffrey C. Fort
Letissa Carver Reid
SONNENSCHEINNATH & ROSENTHAL LLP
8000 Sears Tower
233
S. Wacker Drive
Chicago, IL
60606-6404
(312) 876-8000 (Phone)
(312) 876-7934 (Facsimile)
One of Its
THIS FILING IS BEING SUBMITTED
ON
RECYCLED PAPER

RE
C E ~V ED
CLERK’S
OFF~cF
BEFORE THE POLLUTION CONTROL BOARD
OF THE
STATE OF ILLINOIS
MAR
142005
STATE OF ILLINOIS
Pülj~t~on
Control Board
IN THE MATTER OF:
)
)
CITGO PETROLEUM CORPORATION and
)
PDV MIDWEST REFINING, L.L.C.,
)
)
PCB 05-85
Petitioners,
)
(Variance
Water)
)
v.
)
)
ILLiNOIS ENVIRONMENTAL
)
PROTECTION AGENCY,
)
)
Respondent.
)
PETITIONERS’
POST-HEARING
BRIEF
REGARDING
PETITION
FOR
VARIANCE
IN
CONNECTION WITH
DISCHARGE OF TOTAL DISSOLVED SOLIDS
AND
RESPONSES TO
ADDITIONAL QUESTIONS
FROM BOARD’S TECHNICAL UNIT
CITGO
Petroleum
Corporation
(“CITGO”)
and
PDV
Midwest
Refining,
L.L.C.
(“PDVMR”)
(hereinafter
collectively
referred
to
as
“CITGO”)
have
petitioned
the
Illinois
Pollution Control Board (the “Board”) for a variance that would
authorize the discharge of Total
Dissolved
Solids
(“TDS”)
subject to
certain conditions
that
have been approved by the Illinois
Environmental Protection Agency
(the “IEPA” or the “Agency”).
CITGO is
seeking
this water
variance
as
part
of a
significant
environmental
project.
CITGO
has
entered
into
a
Consent
Decree
with
the
United
States
Environmental
Protection
Agency
(the
“U.S.
EPA”)
and
the
environmental
authorities
for
four
other
states
including
Illinois
in
order
to
resolve
certain
alleged air quality violations
and
substantially reduce emissions of sulfur dioxide
(“SO2”)
and
nitrous
oxide (“NOx”).
The
Lemont Refinery
is
among three
refineries
for which
substantial
emission reductions will be
achieved as required by the Consent Decree.
The estimated annual
SO2
and
NOx
emission
reductions
for
the
Lemont
Refinery
are
15,000
and
1,100
tons

respectively.
(A
copy of the
Consent
Decree
executed
on
January
26,
2005
was
submitted
previously with CITGO’s pre-filed testimony as Exhibit 1.)’
In order to
comply with the emission requirements ofthe Consent Decree, CITGO must
install
a
wet
gas
scrubber
in
the
Fluidized
Catalytic
Cracking
Unit
(“FCCU”)
in
addition
to
substantial support equipment and controls.
Accordingly, a major construction project extending
approximately 20 months is
required.
(See Exhibit 2 (a copy of the compliance schedule for the
Lemont
Refinery
in
connection with
the Consent
Decree).
See
~
Exhibit
3,
which
contains
construction permit drawings depicting the new equipment
to
be
installed
and
a description of
the
same.)
CITGO
has
included
a
substantial
amount
of
equipment
design
adjustments
to
minimize
the
environmental
effect
of
wastewater
discharges
from
the
wet
gas
scrubber.
Nevertheless, installation ofthe wet gas scrubber will increase the amount of TDS in the treated
wastewater at the Lemont Refinery.
(Exhibit 4
is a copy ofthe petition for a TDS water variance
filed with the Board on November 8, 2004.)
One ofthe critical path items
is to obtain a construction permit from the water division of
the IEPA.
Exhibit
5
is
a copy ofthe application for that construction permit.2
On December 3,
2004,
CITGO
submitted
the
construction
permit
application,
consistent
with
the
overall
construction schedule.
In preliminary conversations with the water division ofthe IEPA, CITGO
learned of two
critical
issues
that
pose challenges for the Consent Decree schedule.
First,
the
IEPA will not
grant the construction permit without
also
issuing
a modified
National Pollutant
Discharge
Elimination
System
(“NPDES”)
permit.
Second,
because
there
has
been
an
exceedance ofthe TDS standard in
the past,
in association with snow
melt runoff, carrying road
salt and
similar compounds
into the streams, the IEPA could not
issue a NPDES
permit for this
All
exhibits
referred
to
herein
were
submitted
previously
with
CITGO
‘S
pre-filed
testimony
on
February 17,
2005,
unless otherwise indicated.
2
Page
3
(inadvertently
omitted
from
the
previously
filed
Exhibit
5)
of
the
Construction
Permit
Application for the Purge Treatment Unit (December 2004) is attached hereto as Exhibit
5.
2

project
unless
CITGO obtained
a
variance
from
the
Board.
Hence, the
variance petition was
filed soon after the Consent Decree was lodged.
Finally,
a negotiated compliance plan has been completed
to the satisfaction ofthe
IEPA
and was submitted as Exhibit 7.
This compliance plan requires that extensive TDS databe taken
from
the Des Plaines
River at the
1-55
Bridge
during
the winter months.
Subsequent
to
two
seasons of stream testing,
the Lemont Refinery will be able to
size the required holding tank or
basin
for the wet
gas scrubber discharge during periods of high salinity if that option is
needed.
The
project
for
the
retention
system
would
be
scheduled
to
begin
by
March
1,
2009,
with
completion
expected by
the winter season beginning December
1,
2009.
During the February
24,
2005 hearing, the IBPA expressed its support for the variance and its
conditions based upon
the supplemental information submitted
by CITGO
and
entered
into this
record.
Accordingly,
CITGO
requests
that
the
Board
find
that:
(1)
if the
instant
variance petition
is
not
granted,
CITGO will incur an arbitrary
and unreasonable hardship;
and
(2) the variance, if granted, will
not result in
significant injury to the public
or the environment.
STANDARD FOR GRANT OF VARIANCE RELIEF
Pursuant
to
Section
35(a)
of
the
Environmental
Protection
Act,
the
Board
has
the
authority
to
grant a variance from
one
of its
regulations whenever immediate compliance
with
such regulation would impose an
arbitrary or unreasonable hardship on the petitioner.
415
ILCS
5/35(a)
(2004);
City of Canton v.
Illinois Environmental
Protection Agency,
2002
WL
560970,
at
*1(111. Pollution
Control
Bd.
April 4,
2002).
In granting or denying
a variance,
the Board
must
balance
the
hardship
of compliance
with
its
regulations
on
petitioner
against
adverse
environmental impacts.
Marathon Oil Co.
v.
Environmental Protection Agency, 242 Ill.
App. 2d
200, 206, 610 N.E.2d 789, 793
(5th
Dist.
1993); Monsanto
Co.
v. Pollution Control Bd., 67 Iii.
2d
276,
292,
367 N.E.2d
684,
691
(1977).
The petitioner must
establish
that
the hardship it will
3

encounter
from
denial of the requested
variance will
outweigh any
injury
to
the public
or the
environment
from
the
grant
of the
same,
“.
.
.
and
only
if
hardship
outweighs
injury
does
evidence
rise to
the level of arbitrary or unreasonable.”
Marathon Oil
Co.,
242
Ill.
App.
2d
at
206, 610 N.E.2d at 793.
THERE
ARE
NO PRACTICAL ALTERNATIVES
THAT
WOULD REDUCE
THE
TDS
DISCHARGE
CAUSED
BY
INSTALLATION
OF
THE
REQUIRED
WET
GAS
SCRUBBER;
THEREFORE,
COMPLIANCE
WITH
THE
BOARD’S
EXISTING
TDS
WATER
QUALITY
STANDARD
WOULD
IMPOSE
AN
ARBITRARY
AND
SIGNIFICANT HARDSHIP
ON CITGO
Section
35(a)
of the
Environmental
Protection
Act
requires
the
Board
to
determine
whether CITGO has presented adequate proof that
it would
suffer an
arbitrary or unreasonable
hardship if required to comply with the Board’s TDS water quality standard.
415
ILCS
5/35(a)
(2004);
Marathon
Oil
Co.,
242
Iii.
App.
2d at
206,
610 N.E.2d at
793.
CITGO,
the U.S.
EPA
and
the IEPA
are parties
to
a
Consent Decree
to
substantially reduce
air
emissions.
CITGO
agreed
to
these
reductions
and
will
invest
more than
$120
million
at
the
Lemont
Refinery.
CITGO
is
subject
to
substantial
penalties
if
it does
not
meet
the
Consent
Decree
schedule.
Installation of the wet gas scrubber will increase the amount of TDS in the Lemont
Refinery’s
treated wastewater.
CITGO has investigated methods of avoiding the release
ofwastewater from the FCCU
to
the existing wastewater treatment system,
including a managed release program with the use
of
a
storm
water
basin
for
retention,
deep
well
disposal,
and
installation
of
evaporation
wastewater treatment technology.
None ofthese alternatives are practical.
At this time, the only option for a managed release program would
entail using the
storm
water basin
(“SWB”)
for retention.
The
SWB
is
used
to
collect
site storm
water
runoff and
drainage
from
naturally
existing
waterways.
A
marked
increase
in
storm
water volume
has
occurred due to
residential developments near the northwest facility boundary.
The runofffrom
4

these developments
feeds
into the naturally existing waterways that terminate within the Lemont
Refinery’s boundaries
and
ultimately
end
up
in
the
SWB.
Due
to
a
special
condition
in
the
Groundwater Management Zone Approval
Letter, issued by the Bureau ofWater Permit section,
the SWB water level must be maintained below
12 ‘9” due to the groundwater gradient.
Because
of the
existing
difficulties
associated
with
maintaining
the water
level
below
12’9”
with
the
additional
burden
created
by
the
increased
storm
water
runoff
volume
from
residential
developments,
to
try
to
retain
the
wet
gas scrubber
effluent
during
periods
of snowmelt
and
deicing would not be a viable option.
As discussed in CITGO’s variance petition (Exhibit
7), deep well disposal is not a viable
alternative because deep well disposal would constitute a Class I injection well.
($~
Exhibit 13;
see
also
February 24,
2005 Hearing Transcript
at 39:9
-
39:24.)
Class
I injection
wells are not
permittable in
northeastern
Illinois
because no
cap rock
exists
over
the depth
where disposal
wells
are drilled.
($~
Exhibit
13.)
Technologies
for removal of sodium
sulfate from
a
dilute
aqueous
stream
are
limited.
Electrodialysis
has
in
no
case
been applied
in
the
chemical
or
refinery industries on
the scale required at
the
Lemont Refinery.
Biological
sulfate reduction
theoretically
is possible;
however,
biological
sulfate reduction will not
reduce the overall
TDS
concentration
simply by
replacing
the sulfate ions
with
carbonate ions.
The concentration
of
sodium sulfate is too high for reverse osmosis concentration, as scaling problems would
develop.
The
only
technology
potentially
available
would
be
evaporation.
Evaporation
is
an
energy intensive
approach, which
would
result in
increased
carbon dioxide
emissions
into the
atmosphere.
The
evaporation
process
would
require
a
multi-effect
evaporator
to
minimize
energy consumption.
A falling
film evaporator with mechanical vapor recompression (“MVR”)
is
the most
energy efficient approach.
Subsequent crystallization would produce a dry sodium
sulfate by-product.
Whether this
by-product would
be of sufficient purity to
have
any market
5

value has not been determined.
~
Exhibit
7,
attachment A (CITGO’s
Petition
for Variance
filed November
8,
2004),
which
depicts
a
conceptual process
flow
diagram of a
falling
film
evaporator with MVR; ~
~
Exhibit
14
(a description of evaporation costs) and February 24,
2005 Hearing Transcript at 40:12
-
40:18.)
The capital cost in 2004 dollars for the application of such technology to this wastewater
stream
is
on
the order of $7
million.
Operating costs,
including depreciation,
are
estimated at
$1
million per year.
Forty percent of this $1
million amount represents energy costs.
This cost
estimate assumes the Lemont Refinery has sufficient
steam capacity, and
it also
assumes that
a
new
boiler will not
be
required.
Moreover,
CITGO
is
not
aware
of a
situation where
such
a
massive evaporation system has been constructed or operated.
CITGO
also
notes the increased
energy demand and emission impact that such an
evaporation system would require.
Additional
investigation would be necessary before such an approach could be pursued.
($~
Exhibit 14.)
Requiring
CITGO
to
install
evaporation wastewater treatment for the wet
gas
scrubber
discharges into the wastewater system
would
impose an
arbitrary
and
unreasonable
hardship.
Such
installation
is
not
practical,
and
such
installation
certainly
is
not
practical
on
the
time
schedule dictated by the Consent Decree.
CITGO is not the cause of any water quality standard
exceedance.
Further,
CITGO is
investing
substantial monies in
the Lemont Refinery to
reduce
air
emissions
as
well
as
significantly
reducing
the
overall
environmental
releases
from
the
Lemont Refinery.
In addition,
the wastewater discharge at issue
is relatively modest; indeed, the
relative
contribution
of
this
project
is
within
error
range
of
the
sampling
method.
(See February 24,
2005
Hearing
Transcript
at
35:5
-
36:8.)
Hence,
requiring
control of the
increased
wastewater
discharge
would
impose
an
arbitrary
and
unreasonable
hardship
on
CITGO.
6

GRANT
OF
THE
REQUESTED
VARIANCE
WILL
NOT
RESULT
IN
SIGNIFICANT
INJURY TO
THE PUBLIC OR THE ENVIRONMENT
The hardship to
CITGO ofcompliance with the TDS water quality standard is substantial.
At the same time, there is no
cognizable benefit to
the public or the environment by compelling
such compliance.
TDS
is
composed of a variety of anions and
cations, thus,
there are no “toxicity” values
that
can be applied to
the generic
TDS parameter.
For
General
Use
waters,
TDS, sulfates
and
chlorides are regulated.
The IEPA has indicated that technical data supported elimination of the
TDS water quality standard and increasing the sulfate
General
Use
limit to
approximately
1,800
mg/L.
(~
Exhibit
10
(information provided to
the stakeholders by
the
IEPA on this issue)).
Additional
toxicity testing
is
being completed by the
U.S.
EPA.
If these results
are consistent
with
the
JEPA’s
previous
research,
the
IEPA
may
propose
these
changes
in
water
quality
standards in the fourth quarter of2005.
Sodium sulfate, at the proposed levels discharged, will not impact the aquatic community
in
the Chicago Sanitary
and
Ship
Canal or in
the Des Plaines River.
(~
February 24,
2005
Hearing Transcript at 37:4
-
38:4.)
There
is no
adverse effect on
aquatic life due
to TDS
and
sulfate levels projected here.
Therefore,
the grant of the requested variance will not
result
in
significant
injury
to
the
public
or the
environment.
(See
~
Exhibit
6
(James
E.
Huff’s
December 2004 report titled “Impact of CITGO’s Proposed Discharge on Water Quality”)).
Investigations
related
to
water
quality
standards
for TDS
have
been conducted
by
the
IEPA
and
are
ongoing
by
the
U.S.
EPA.
The
IEPA
has proposed that
TDS
be
removed
as a
water quality parameter and
sulfate water quality
standards be
increased to
1,800 mg/L.
Under
these proposed standards,
there would
be
no
water quality
exceedance
even during
snow
melt
conditions.
Therefore, there may be no
need for further controls on
CITGO’s
TDS wastewater
discharge.
7

Further
responses
to
questions
from
the
Board’s
technical
unit
are
included
in
Attachment A hereto.
WHEREFORE,
CITGO
requests
that
the
Board
find
that:
(1)
adequate
proof that
immediate compliance with
the Board’s TDS water quality
standard would impose an
arbitrary
and
unreasonable
hardship;
and
(2) grant
of the requested variance
would pose no
significant
injury
to
the public
or the
environment.
Finally,
CITGO
requests
that
the
Board
grant
the
requested variance.
Dated: March 14, 2005
Respectfully submitted,
By:
Jeffrey C. Fort
Letissa Carver Reid
SONNENSCHEIN NATH & ROSENTHAL LLP
8000 Sears Tower
233
South Wacker Drive
Chicago, Illinois
60606-6404
(312) 876-8000 (Phone)
(312) 876-7934 (Facsimile)
14425764.6
THIS FILING IS BEING SUBMITTED
ON RECYCLED PAPER
for CITGO PETROLEUM
CORPORATION and PDV MIDWEST
REFINING, L.L.C.
8

CERTIFICATE OF SERVICE
The undersigned, an attorney, certifies that I have served upon the individuals named on
the attached Notice ofFiling true and correct copies of
PETITIONERS’ POST-HEARING
BRIEF REGARDING PETITION FOR VARIANCEIN CONNECTION WITH
DISCHARGE OF TOTAL DISSOLVED SOLIDS AND RESPONSES TO ADDITIONAL
QUESTIONS FROM BOARD’S TECHNICAL
UNIT via
Federal Express, on March
14, 2005.
__.11
,~--•——)
-.---—
7
\
/
\
.;~-~_
f_~_—’
(
_____________________________
‘ffrey
C~Foa~\
Letissa Carver Reid

SERVICE LIST
VIA HAND DELIVERY
Dorothy Gunn
Clerk ofthe Board
Illinois Pollution Control Board
100 West Randolph Street
-
Suite 11-500
VIA
FEDERAL EXPRESS
Bradley Halloran
Hearing Officer
Illinois Pollution Control Board
100 West Randolph Street
Suite 11-500
Chicago, Illinois 60601
James Allen Day, Esq.
Illinois EPA
1021
Grand Avenue east
P.O. Box 19276
Springfield, Illinois 62794-9276

m

ATTACHMENT A
CITGO’S RESPONSES TO ADDITIONAL QUESTIONS FROM ILLINOIS
POLLUTION CONTROL BOARD’S
TECHNICAL UNIT
1.
Exh.
5,
the Construction Permit Application for
the Purge
Treatment
Unit
(December
2004),
appears to be missingpage
3from the original and copiesfiled with the Board.
Page
3
(inadvertently
omitted
from
the previously filed Exhibit
5)
of the
Construction Permit
Application for the Purge Treatment Unit (December 2004) is attached hereto as Exhibit
5.
2.
Flow valuesfor the PTU appear in
severalplaces in
the testimony and hearing exhibits.
Would you please reconcile
theflow
values
below,
indicating perhaps
which
represent
PTUinfluent or effluent...
In
designing
new process
facilities,
the
loadings are
refined
as
the
design
proceeds
through
various stages.
In addition, there are design loadings and anticipated actual loadings.
Treatment
facilities typically are designed with a safety factor, as occurred in the FCCU Wet Gas Scrubber,
and is
standard engineering practice.
Therefore,
design loadings typically are above anticipated
actual loadings
to
assure the
facilities will not be
undersized.
The different loadings identified
by
the
Board’s technical
staff reflect
these considerations.
Specifically,
the
331,000
gpd
and
0.33
MGD (which is the same value, just rounded to two
significant digits), is a DESIGN value,
used for sizing the equipment.
The 274,000
gpd
is the ACTUAL ANTICIPATED
AVERAGE
FLOW
from
the
FCCU
Wet
Gas
Scrubber,
based
on
the
historical
refinery production.
As
Mr. Harmon
testified, currently there are
no
plans
to
increase
the Lemont
Refinery production
from
the
historical
level.
The
0.38
MGD
(and
375,000
gpd,
which
is
the
same number, just
rounded to two significant digits) was one of the earlier DESIGN AVERAGE FLOW numbers,
which subsequently was revised down to 0.33
MGD (or 331,000 gpd), based on further process
design work, which allowed for a reduction in water consumption.
3.
Flow contributions
to
Outfall
001
in
addition
to
the
PTU also
appear
in
the
hearing
exhibits:...

Please
indicate
what flows
constitute
the
3.6
mgd
at
2,160
mg/L
TDS
referenced
in
Exh.
6.
In the remaining flows
to
Outfall
001
listed in
Exh.
11,
other
than
the 3.6 mgd
and 0.27 mgd shown in
Exh. 6footnote
2,
are there any TDS contributions?
If so, would
you please indicate concentration andflow?
The sources constituting the 3.6 MGD are the same sources listed in Exhibit
11, Pg
1
of4 ofthe
amended
NPDES
permit
renewal.
The
3.6
MGD
reflects
the
typical
discharge
at
low
flow
stream conditions.
4.
The TDS design loadingand concentration are referenced in the hearing exhibits...
The TDS
loadings
on the
PTU
of 215,000
lb/day
and
274,000
gpd
are
the anticipated
actual
average
values.
This
translates
into
a
TDS
concentration
of 94,000
mg/L.
The
system
is
designed,
as described above, to handle an
average
flow of331,000 gpd.
The Schedule N used
76,000 mgIL and a flow of331,000
gpd, which equates to 210,000 pounds per day ofTDS.
The
minor difference in pounds ofTDS per day is due to
refined design information.
The difference
in
flow
reflects
the
difference
in
DESIGN
(0.33 1
MGD)
versus
ACTUAL
ANTICIPATED
(0.274 MGD) flows.
In summary, the best estimate ofanticipated flow and loading at this point
is
274,000
gpd
containing
215,000
pounds
per
day
of
TDS.
The
sulfates
merely
are
a
stoichiometric fraction ofthis, 67
ofthe TDS.
Using the loadingfigures provided in Exh
6 at
2,
what would
be the
TDS
concentration
in the PTU effluent?
The 274,000 gpd is the same as 0.274 MGD.
The concentration from the PTU therefore will be:
(215,000 pounds/day)
/
(8.34)(0.274 MGD)
=
94,000 mg/L
What
is
the
expected
concentration
of
TDS
in
the
effluent from
the
PTU
before
it
combines with otherflows to
Outfall 001?
The 274,000
gpd is the same as 0.274 MGD.
The concentration from the PTU therefore will be:
(215,000 pounds/day) / (8.34)(0.274 MGD)
=
94,000 mg/L
2

5.
Exh.
6 at 2
indicates
the sulfate design
loadingfrom
the PTU to
the receiving stream
is
142,000
lbs/day.
Exh.
14
at
1
uses
a
sodium
sulfate
loading of 304,000
lbs/day
to
calculate costs for
a falling film
evaporator.
Would you please
describe
the reason
behind using a higher loading to calculate the evaporator costs?
Exhibit
6
presents
the anticipated
average
loadings
to
the receiving
stream.
Exhibit
14
is
the
DESIGN loading for the equipment.
The 304,000 pounds per day of sodium sulfate is equivalent
to
205,000 pounds per
day as
sulfate.
As
explained in
the earlier questions,
equipment design
takes into account maximum loadings, and not just the average loadings.
3

-‘N
m
03

2.
PROCESS DESCRIPTION
A
purge stream from the
WGS
containing ammonia will be directed to
a new building
(120
feet
long
and
45
feet
wide)
located
east
of the
existing
wastewater
treatment
plant.
The purge
treatment unit (PTU) is sized to
handile a maximum flow rate of 300 gpm, and
a design average
flow rate of 230
gpm.
Two
WGS
technologies
are
still
under
consideration.
One
system
includes sulfite oxidation
step
as an integral part ofthe WGS.
The second system
includes an
oxidation step external to
the WGS.
Ifthe later is selected, an
external air oxidation step will be
added
to
the
PTU
producing
sodium
sulfate.
The
WGS
that
includes
an
oxidation
system
integral to
the WGS is likely to be selected, so the process description presented herein assumes
describes this
system.
The conversion of sodium sulfite
to
sodium sulfate (sulfite oxidation)
occurs in the base of the
WGS instead of an external PTU.
Caustic
is
added
to the scrubbing
solution
and recirculated
through external educators that draw the required air for oxidation.
Caustic
is also used to adjust
the pH from the WGS operating range (6.2 to 9.0) to the range of
9-9.5.
The oxidation system
includes facilities to reliably control the pH ofthe oxidation
system.
The oxidized purge stream
from
the
WGS
is
sent
directly
to
the
Auto-Pulse
Tubular
Backpulse
Filter,
one
norrnaily
operating
and
one
spare
to
ensure
uninterrupted
service.
The
Auto-Pulse
Filter
removes
suspended solids
from
the purge
stream.
Internals for the filter will be made from
316L
SS.
Pl~i~2ir
will be supplied to
the filter to provide the pulsating necessary to accommodate solids
removal.
A bypass line is provided which will be utilized when the filter is being pulsated with
plart air.
The sludge from the Auto-Pulse Filter is
sent to a new Sludge Tank through a gravity flow line.
Two sludge pumps
(one spare) areprovided to pump the sludge from the tank to the two Oberlin
Filters, one
normally operating
and one spare to
ensure uninterrupted service.
Plant air will be
supplied
to
the
Oberlin
filter
to help
facilitate the
solids
dewatering.
The filtrate
from
the
Oberlin Filter will be sent through a new line to
a new DewateringBasin
Sump where it will be
collected and them pumped by two new Dewatering Basin Sump Pumps (one spare) back to the
line
going into the Auto-Pulse
Filters.
The Dewatering Basin Sump
and the associated
pumps
will have 316L SS
as the material of construction.
There is
also a recirculation line provided to
send the filtrate to
the inlet line of the Oberlin filters.
The Oberlin ifiter system is elevated such
that the
dry solid cake
discharge can be
collected
to
20
cu
yd roll off boxes that
can then be
trucked to a landfill for disposal.
All piping
around the Auto-Pulse Filter
system,
the Oberlin Filter system
and
the Dewatering
Basin sump will be 316L SS.
The effluent from the Auto-Pulse Filter, which will contain less than
15
mgfL Total
Suspended
Solids,
will be
sent
to
a new
open
top
PT(J Effluent
Tank
that
will be
equipped with
a new
Agitator.
Both the agitator and tank will have carbon steel as their material of construction.
A
new sodium hypochiorite storage tank will also be provided; The tank will be equipped with two
new metering pumps
(one
spare).
These
pumps
will
send sodium
hypochlorite
to
the
PT(J
Effluent
Tank.
Aimnonia
reduction
will
be
facilitated
through
the
breakpoint
chlorination
process
controlled by
Oxidation-Reduction
Potential
(ORP)
probes.
The
PTU effluent
will
3

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