BEFORE THE
~
OF THE STATE OF ILLINOIS
OCT 82004
IN THE MATTER OF:
)
REVISIONS TO RADIUM WATER
QUALITY STANDARDS: PROPOSED
NEW
35
ILL. ADMIN. CODE
302.307
AND AMENDMENTS TO 35 ILL. ADMIN.
CODE
302.207 AND 302.525
)
)
)
)
)
)
STATE OF
ILUNO~S
PoLtution ControL Board
R04-21
Rulemaking
-
Water
NOTICE OF FILING
To:
See Attached Service List
Please take notice that on October 8, 2004, we filed with the Office of the Clerk
of the Illinois Pollution Control Board, an original and ten copies of the attached
Supplemental Testimony Of Theodore
G. Adams
On Behalf Of Water Remediation
Technology, LLC
a copy ofwhich is served upon you;
Jeffrey C. Fort
Letissa Carver Reid
Sonnenschein Nath & Rosenthal LLP
8000 Sears Tower
233 S. Wacker Drive
Chicago, IL 60606-6404
WRT Environmental Illinois LLC
One of Its Attorneys
THIS FILING IS BEING SUBMITTED ON RECYCLED PAPER
BEFORE
~ A~
BOARD
OCT-8
OFF~E~
2004
STATE OF ILLJNOIS
IN THE MATTER OF:
)
POllUtiOn Control Board
)
REVISIONS TO RADIUM WATER
)
QUALITY STANDARDS: PROPOSED
)
R04-21
NEW
35
ILL. ADMIN. CODE 302.307
)
Rulemaking —Water
AND AMENDMENTS TO
35
ILL. ADMIN.
)
CODE 302.207
AND
302.525
)
SUPPLEMENTAL TESTIMONY OF THEODORE G. ADAMS
ON BEHALF OF WATER REMEDIATION TECHNOLOGY, LLC
I, Theodore G. Adams, President of T. G. Adams and Associates, Inc., hereby
respectfully submit supplemental testimony to address questions raised by the Illinois
Pollution Control Board (the “Board”) and the Illinois Environmental Protection Agency
(the “IEPA” or the “Agency”) during the prior hearing in this matter held on
August 11,2004.
I previously submitted testimony to the Board. Certain areas of my prior
testimony were the subject of questioning, and the purpose of this supplemental
testimony is to address any ambiguities for the record.
I.
WHAT WOULD BE A SAFE LEVEL OF
RADIUM IN GENERAL USE
WATERS
OF ILLINOIS?
(August 11, 2004 Hearing Transcript at pp. 62-63.)
The existing standard of 1 pCi/L for Radium 226 generally is recognized as a
background condition in surface waters of Illinois.1 Given that radium is a recognized
carcinogen, and a degradation product of uranium and thorium, it is not surprising that
the Board set such a level. By doing so, any variations from that standard would require
careful consideration. From the analyses I have performed, it appears that any increase
over the existing standard could result in an excessive radium exposure. Clearly, the
Biota-Dose Assessment Committee approach would not allow for a general increase over
these background levels without a careful data collection and site by site analysis and
justification.
But the effect of the Agency’s proposal is to eliminate ANY water quality
standard for this carcinogen from most Illinois waters. Attachment A hereto is a map
compiled from the Agency’s exhibits 1 and 2; the public water supply wells with known
1
Jacqueline Michel, Predicting the Occurrence of 228Ra in Ground Water, Health Physics Vol. 51, No. 6
(December), pp. 715-721 (1986).
1
radium levels over
5
pCi/L are shown in red, and the downstream receiving waters are
shown in yellow. Clearly, the effect ofthe proposal is to wipe out any radium limits for
Illinois waters, even those receiving levels over background.
The Biota-Dose Assessment Committee (“BDAC”) approach demonstrates that
adverse effects from radium in waters may occur at levels slightly above background.
Using the BDAC approach, I have calculated that beginning at levels in the range of 1.4
to 1.88 pCi/L for Radium 226, the water quality would exceed the general biota dose
limit.. Attachment B to my supplemental testimony is a summary of the approach used,
and the calculations I have performed. These show that even if there is no radium
contamination in the sediment, the general biota dose limits would be exceeded at
1.88 pCi/L of Radium 226, in the presence of 1.88 pCi/L of Radium 228. Using the
combined radium limit approach put forth by the Agency for drinking water standards,
the safe limit could be
3.75
pCi/L.
(~
Attachment B at p. 2.) But if sediment levels are
12.2 pCi/g (as documented by the Florida studies in Attachment D), then the safe level
would fall to 1.4 pCi/L for each. Clearly, there is very little room to relax the existing
water quality standard without further data and analysis. And clearly, the expected
effluent of
5
-
10 pCi/L, from several ofthe example POTWs contained in C. Williams
Testimony Table
5,
would fail the BDAC criteria. (S~Attachment B, cases 3 through
6.)
I believe that the approach taken by the BDAC merits considerable weight. The
Department of Energy (“DOE”) is responsible for managing and controlling, at its
facilities, a large portion of the country’s radioactive materials, subject to oversight by
EPA, the Nuclear Regulatory Commission (“NRC”) and the states, and has devoted
substantial resources to protecting the environment from radiation. The BDAC approach
is based on the DOE order to its contractors, which has been recognized by EPA and
other states, an important criteria for avoiding impact to human health and the
environment. (See attachment C.) If the Board wants to have water quality standards
that protect aquatic life and the environment, it would appear that the existing standard
may be appropriate.
Moreover, new information arising out of sampling and investigations done in
Florida, including data just published in August of this year, would indicate that radium
levels in the very range that meet the BDAC biota dose limit may adversely affect
mussels, including mussels such as those listed as endangered or threatened in Illinois.
Attachment D hereto is a letter from one ofthe Florida researchers who has evaluated the
bio-concentration in sediments and mussels from various lakes in Florida. These lakes
must be replenished by pumping groundwater, which has radium at the levels I consider
background
i.e., 1-2 pCi/L. The recently published data show that the mussels in
these lakes bio-accumulate radium to levels at 200 pCi/g.
Illinois has many endangered mussels which inhabit the waters threatened to be
de-regulated by the proposed rule. Attachment E hereto are maps taken from the IDNR
website showing river basins where these endangered species may be found. I do not
know if there is a relationship between the “background” radium and these endangered
species, but clearly the effect ofthis proposed rule has not been adequatelyconsidered.
2
In conclusion, radium can cause adverse effects on aquatic life and riparian
animals. It is a carcinogen to humans. And it bio-accumulates in mussels and up the
aquatic food chain.
Though the current standard may be virtually the same as
“background,” I would urge that a compelling case is required before relaxing the general
water quality standard for such a material.
II.
ARE
THERE OTHER SOURCES OF RADIUM DISCHARGING?
The explicit assumption made by the IEPA was that an exceedance ofthe existing
standard would occur ONLY as a result ofthe presence of elevated radium in drinking
water or the treatment of drinking water. I would note that the
goal
ofthe EPA drinking
water standard is zero; the
5
pCi/L reflects a risk of 1 in 10,000. But left unaddressed in
this proceeding is the question, “who else could be a source?”
My prior testimony showed that radium is a degradation or breakdown product of
other nuclear radioactive materials. These include thorium and uranium. But there is no
evidence presented in this proceeding of who or where those potential or actual sources
are, whether industrial, commercial or municipal. It seems likely that other discharges of
radium exist.
At least one of the participating facilities in the AMSA study was a publicly
owned treatment works (“POTW”) in the northeastern Illinois area. This POTW is in an
area that has a high concentration ofradium in groundwater withdrawals. Because ofthe
confidentiality terms in the AMSA and ISCORS study, I am not at liberty to divulge the
name of the plant. But I can testify that, given the groundwater levels known to exist in
that locale, the sludge levels reported for that POTW are consistent with the predicted
sludge levels and worker exposure levels presented in my prior testimony.
This observation led me to seek information about other documented dischargers
of radium. Time did not permit a review of radium dischargers in Illinois. But we did
find that at least one nuclear power plant reported radium discharge levels exceeding the
current standard. For the LaSalle plant, Radium 226 was reported for two outfalls at 2.6
pCi/L, and total radium values were 4.1 and 9.0 pCi/L. In a couple of instances, it
appeared that the amount ofradium increased across specific wastewater processes. (S~
Attachment I.)
The record in this proceeding does not identify other sources beside municipal
drinking water treatment plants might be the beneficiary of this de-regulation. There may
be others. Indeed, even among the group that was identified as needing regulatory relief
—
communities that need to treat their groundwater supply to meet the new drinking
water standard
—
some already have decided that they do not need to flush their
treatment water filtrate down the sewer and still can save hundreds of thousands of
dollars.
3
III.
ARE THERE OTHER IMPACTS ON PUBLICLY OWNED TREATMENT
WORKS BEYOND THOSE IN AGENCY EXHIBIT 11?
The JEPA suggests in its Exhibit 11 that the POTWs will benefit by avoiding
certain costs if this proposed rule were adopted. But there are other costs that will result
from the adoption of the proposed rule. The overall costs appear actually to be much
greater when one considers all the implications ofthe Agency’s proposal.
The IEPA has not provided this proceeding with evidence concerning testing or
monitoring of any sewage sludge levels for radium. Yet, the economic and operational
impacts of radiologically contaminated influent/sludge on POTWs are well documented.
For example, in Cleveland, Ohio, Advanced Medical Systems, a NRC licensee,
discharged minute amounts ofnon-soluble radioactive particles ofCo-60 over a period of
20 years into the sewer system. These minute radioactive particles contaminated the
POTW and the resulting sludge. The aggregate radioactivity disposed of into the sewer
system over the 20-year period was less than
0.5
Curie (i.e., 0.445 Curie).
(See Attachment F.) Nevertheless, the NEORSD incurred more than $2 million in clean-
up costs when these elevated radiation levels were discovered by chance. An enormous
amount of radioactive contaminated material which occurred as a result of a “miniscule”
amount of radioactivity is still present at the NEORSD. Co-60 has a half-life of
approximately five to six years, and Co-60 does not produce radon as a by-product. In
contrast, Ra226 has a half-life of 1600 years, and does produce radon as a by-product.
In comparison, a moderately-sized city with elevated radium levels may exceed
this quantity in its sludge. I have completed a calculation for the amount of radium
contamination found in sewer sludge from the City of Joliet’s sewer system for a period
of one year. The amount ofradium contamination found in Joliet’s sewer sludge over the
course ofjust a single year was 0.29399 Curie. (See Attachment G, page 12 of Agency
Exhibit 12.) The amount of radium contamination found in Joliet’s sewer sludge over a
period ofone year was more than half the amount ofradioactive contamination (for a 20-
year period) found in the sewer system in Cleveland, Ohio. Thus, over a similar 20-year
period, the Joliet POTWs would appear to generate more than 10 times the quantity of
radiation that caused substantial injury to the sewer system in Cleveland, Ohio. And the
Radium 226 will take longer to degrade than would the Cobalt.
On the other hand, if the radium-laden residuals (j~, Technically Enhanced
Naturally Occurring Radioactive Material (“TENORM”)) are disposed of into the sewer,
then the public water systems, the POTWs, and the State of Illinois can expect to have the
following increased costs:
•
The uncontrolled discharge ofradium residuals wouldlcould be a liability
issue to municipalities/POTWs (as cited in Cleveland, Ohio);
•
POTW workers will require training, personnel exposure monitoring and
medical monitoring as occupational radiation workers;
•
Sewer sludge and handling areas will require on-going testing;
4
•
The POTW maybe required to obtain a radioactive materials license;
•
Application of sewer sludge to farm land will require on-going
monitoring; and
•
Sewer pipes and the POTW itself (or parts thereof) may require
decontamination.
These costs are the practical result ofthe Agency’s proposal.
There is another environmental cost of the proposal.. The Agency expects that
water treatment plants will flush filtrate materials down the sewer. This activity requires
the pumping of additional groundwater to carry out the backflushing operation. The
amount of groundwater may be on the order of
5
to 25 percent of the quantity of water
being pumped for human consumption. Areas already relying on deep aquifers for
potable water supply are in the same areas where the groundwater resource is being
depleted. As an example, although Joliet was already extracting the largest quantity of
well water from deep aquifers in
1995,
there continues to be a further drawdown in the
groundwater level by over 25 feet. This is among the largest drawdowns since 1995 in
the northeastern Illinois area.
($~
“A Comparison of Potentiometric Surfaces for the
Cambrian-Ordovician Aquifers of Northeastern Illinois”,
1995
and 2000, Table 2 and
Figure 9 attached hereto as Attachment H.) For Joliet, backflushing would therefore
increase the groundwater drawdown by
0.5
to
2.5
million gallons per day. Moreover,
Kane County shows the largest growth in deep well pumping of any county in the area.
j~at Table 1. This is not surprising in light of its growth. At the same time, Kane
County communities have some of the highest radium levels in groundwater. Thus, the
amount of water containing elevated levels of radium being extracted from the deep
aquifers seems likely to continue to increase. Allowing the use ofbackflushing in these
areas, would only increase the demand on the deep aquifer resources. And the discharge
to surface waters will carry increased amounts of radium.
IV.
CONCLUSION
The existing standard represents background conditions. Interestingly, the BDAC
approach, required of all DOE facilities, would require site specific data and further
analysis on any water quality condition over this general background level. There is
clearly no basis to remove radium as a general water quality criterion withoutmore data..
Removing the radium standard, without first imposing a control on storm and
sewer discharges of radium comparable to those required of facilities regulated by the
IEMA allows TENORM radium to be backwashed down sewers. This not only re-
introduces a carcinogen back into the environment, it potentially exposes POTW workers
to radium levels above that allowed even for workers in a nuclear plant. And it results in
radium being applied to crop soils as part of the municipal sludge.
From an
environmental view point, all radium TENORM, especially radioactive solids, should not
be permitted down sewers, regardless if one is a licensee of IEMA ornot.
5
CERTIFICATE OF SERVICE
RECE~VED
CLERK’S OFFICE
OCT 8 2004
STATE OF ILLINOIS
Pollution Control Board
The undersigned, an attorney, certify that I have served upon the individuals
named on the attached Notice of Filing true and correct copies of the
Supplemental
Testimony Of Theodore G. Adams On Behalf Of Water Remediation Technology,
LLC
and First Class Mail, postage prepaid on October 8, 2004.
SERVICE LIST
Dorothy Gunn
Clerk ofthe Board
Illinois Pollution Control Board
100 West Randolph Street
Suite 11-500
Chicago, IL 60601
Amy Antoniolli
Hearing Officer
Illinois Pollution Control Board
100 West Randolph Street
Suite 11-500
Chicago, IL 60601
Deborah J. Williams
Stefanie N. Diers
Illinois Environmental Protection Agency
1021 North Grand Avenue East
P.O. Box 19276
Springfield, IL 62794-9276
Joel J. Sternstein, Assistant Attorney General
Matthew J. Dunn, Division Chief
Office ofthe Illinois Attorney General
Environmental Bureau
188 West Randolph
20t~~Floor
Chicago, IL 60601
Jonathan Furr, General Counsel
Illinois Department ofNatural Resources
One Natural Resources Way
Springfield, IL 62701
Richard Lanyon
Metropolitan Water Reclamation District
100 East Erie Street
Chicago, IL 60611
Roy M. Harsch
Sasha M. Engle
Gardner Carton & Douglas
191 North Wacker Drive
Suite 3700
Chicago, IL 60606-1698
Claire A. Manning
Posegate & Denes
111 North Sixth Street
Springfield, IL 62701
Lisa Frede
CICI
2250 East Devon Avenue
Suite 239
Des Plaines, IL 60018
William Seith
Total Environmental Solutions
631 East Butterfield Road
Suite 315
Lombard, IL 60148
Albert F. Ettinger
Environmental Law and Policy Center
35 East Wacker Drive
Suite 1300
Chicago, IL 60601
John McMahon
Wilkie & McMahon
8 East Main Street
Champaign, IL 61820
Dennis L. Duffield
City ofJoliet
Department ofPublic Works and Utilities
921 East Washington Street
Joliet, IL 60431
Abdul Khalique
Metropolitan Water Reclamation District of
Greater Chicago
6001 West Pershing Road
Cicero, IL 60804
R04-21
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Exhibit B
ATTACHMENT B TO SUPPLEMENTAL TESTIMONY OF
THEODORE G. ADAMS ON BEHALF OF WATER REMEDIATION
TECHNOLOGY, LLC
The purpose of this Attachment is to provide background on the guidance cited in my
prior testimony in this matter.
The federal Department of Energy (“DOE”), Office of
Environmental Policy and Guidance together with the Biota Dose Assessment Committee
(“BDAC”) has prepared and made available a DOE technical standard, “A Graded Approach For
Evaluating Radiation Doses to Aquatic and Terrestrial Biota” (DOE
—
STD. 1153-2002) (the
“Biota Protection Standard”).
($~
Attachment C). The BDAC is sponsored and chaired by the
DOE Office of Environmental Policy and Guidance, Air, Water and Radiation Division; it is
multidisciplinary and brings together expertise in health physics, ecology, radio ecology,
environmental monitoring, and risk assessment.
The DOE Memorandum dated August 27, 2002, (also part ofAttachment C) states: “The
technical standard provides screening methods and, if needed, methods for more detailed
analysis within the general framework that can be used for demonstrating compliance with
requirements contained in DOE Order 5400.5” “Radiation Protection Of The Public And The
Environment”. “DOE Order 5400.5 specifies the radiation protection requirements that DOE
and DOE contractor employees must meet to protect aquatic animals.” These limits are less than
1.0 RAD per day for aquatic animals and less than 0.1 RAD per day for terrestrial and riparian
animals.
-
The 0.1 RAD per day for riparian animals is a relatively high radiation dose. It is the
equivalent of 730,000 mrem per year exposure to man. In my earlier testimony, I stated that
radiation workers are limited to an exposure of 5,000 mrem per year and that this dose must be
kept as low as reasonably achievable (“ALARA”). In fact, the average nuclear plant worker
receives a small fraction of this amount. One hundred (100) mrem is the maximum allowable
exposure to a member ofthe public.
The Biota Protection Standard provides a screening method to determine whether or not
the 1.0 RAD per day (aquatic animals) and the 0.1 RAD per day (terrestrial and riparian animals)
DOE standard will be exceeded in any situation.
Assessment is done by reference to specific Biota Concentration Guides (“BCGs”) for
both water and sediment for aquatic and riparian animals and to the “Organism Responsible for
Limiting Dose” for each ofwater and sediment.
-
Each BCG is specifically referenced to the applicable radionuclide. Table 6.2 of
Attachment C shows the following:
Nuclide
BCG
Organism Responsible for Limiting Dose in Water
Radium 226
4 pCi/L
Riparian Animal
Radium 228
3 pCi/L
Riparian Animal
Attachment B
And for sediment, Table 6.2 provides:
Nuclide
BCG
Organism Responsible forLimiting Dose in Water
Radium 226
100 pCi/g
Riparian Animal
Radium 228
90 pCi/g
Riparian Animal
During the screening level process, each of the BCGs is calculated based on the
assumption that it is the only radiation to which the Biota is exposed, and that exposure at the
BCG level is equal to the DOE mandated level of maximum exposure for a terrestrial and/or
riparian animal of 0.1 RAD per day and for an aquatic animal of 1.0 RAD per day. Divide the
actual level by the BCG. Ifthe result is greater than 1.0, the screening level has been exceeded~
Where more than one radionuclide (i.e., Radium 226 and Radium 228) is involved and
where there is more than one source of radiation (i.e., water plus sediment), then divide each
BCG by the actual radiation level for each radionuclide for each ofwater and sediment resulting
in four fractions. Ifthe aggregate sum of these four fractions is more than 1.0, then the screening
level has been exceeded
Sample Calculations of Water Quality Using the BCG Approach
In the pages following the text of this Attachment, I have presented calculations ofhow
the BCGs could be applied to the water quality situation for POTWs receiving water from wells
with elevated radium levels. Page B-S presents the basic formula for Radium 226 and 228 from
the DOE Guidance. The next page then illustrates a sample calculation that provides an estimate
of the water quality level at which the DOE Guidance would deem to be safe for purposes of
protection of aquatic life. As one can see from that page, at a combined radium level of 3.75
pCi/L, without any contribution from total radium in the sediments, the water quality is deemed
acceptable. (I then proceeded to examine the various cases described in Table
5
of Charles
Williams’ August testimony to document that cases 3, 4,
5
and 6 all result in an exceedance of
the bio-dose criteria adopted by the BDAC.)
These calculations may understate the risk to aquatic life, since they include no calculated
contribution from radium deposited in sediment. The IEPA has provided no figures -for the
present or expected radiation levels in the sediment. However, it is my opinion that
-
the
radiation in the
sediment will increase due
to the continued discharge of radium into low-
flow and no-flow streams.
Radioactive Contamination of Sediments
It is instructive to consider the potential effect on the “safe” calculation by adding in a
value for radium in sediments. The information provided by Attachment D provides data on-not
only the uptake of radium by benthic organisms, but also on the accumulation ofradium in the
surficial sediments.
-
In that case, lake levels were augmented by input water from deep water wells, the
introduction oflow radioactive input water (2 to 3 pCi/L ofRadium 226). According to the 2000
2
and 2004 Technical Report to the Southwest Florida Water Management District, the resulting
sediment contamination averaged 12.1 pCi/g of Radium 226; and the mussels had radiation
levels in the flesh in excess of 205 pCi/g (and a RAD dose of
5.5
RAD per day). ~
Attachment D.) These mussels contain radiation at levels higher than acceptable for
disposal anywhere, but at a low level radioactive waste disposal site.
Although lakes differ from streams, in my opinion, the constant, daily, incremental
discharge ofradium into low-flow or no-flow streams, year after year, will cause an increase in
the radioactive content ofthe sediment over time. Further studies would- have to be undertaken
to project the future levels of radioactive contamination in each particular stream. However,
assuming that the ultimate contamination was 20 pCi/g combined radium (split
50/50),
then (as
shown in the final page of this Attachment B) any radium in the water in excess of 2.72 pCi/L
would cause the screening level to be exceeded. And, on a combined radium basis, based on
these assumptions, the level
of Radium
226
needed to exceed the screening level ranges
drops from 1.88
pCi/L to 1.36 pCi/L.
- -
These calculations indicate that the existing general water standard of 1.0 pCi/L of
Radium 226 water is not unreasonably low on a general, state-wide basis, and is very close to the
level needed to avoid exceeding the screening level provided by the Biota Protection Standard.
It is important to remember that, in radiation matters, the fundamental principle is that all
radiation should be kept ALARA
—
this is especially true with radium for which the maximum
contaminant level goal ofboth the U.S. EPA and the IEPA is zero, which has a lengthy half-life,
and for which, under both U.S. and Illinois state regulations, there is no allowable exempt
amount and no allowable exempt concentration. The DOE committee’s approach reflects this
approach and is supportive ofthe basis ofIllinois water quality standard for Radium 226.
3
Case
3- AVG 6~4pCi/L- 50/50
Aquatic BCG Report for Level I
Sum of Total Ratio: 1.73E+OO
Sum of Water Ratio: 1.73E+OO
Sum of Sediment Ratio: 4.77E-03
Water
•‘
H
Concentration PBCG
Limiting
(pCIIL)
(pCi/L)
I°~LJSJ
Organism
Ra-226
3.20E+OO
4.08E+OO
7.85E-
Riparian
Ra-228
3.20E+OO
3.40E+OO
9.42E-
Ripanan
-•
Nuclide Concentration(pCilg)
(pCi/g)BCG
Ratio
Or9anismLimiting
Ra-226
F
2.24E-O1
LO1E+O2
2.22E-
Riparian
I
03
Animaf
Ra-228
2.24E-01
r8.78E+Ol
2.55E-03
RiparianAnimal
I
Case 3-
MAX
II pGilL- 50/50
Aquatic BCG Report for Level I
Sum of Total Ratio: 2.98E+OO
Sum of Water Ratio: 2.97E+OO
Sum of Sediment Ratio: 8.19E-03
aer-~
•~•
~~ide Concentration(pCiIL)
• (pCi/L)
BCG
Ratio
Organism
Limiting
Ra-226
5.50E+00
4.08E+00
Riparian
Ra-228
5.50E+00
3.40E+00 ~
~
¼
-
Nuclide
Concentration(PCI!9)
r
(pCi!g)
BCG
Ratio
OrganismLimiting
______
_____~+~
3.8iB~R~ari:n
Ra.228
3.85E01
~8E+o1 ~
~
Case 4- AVG 4.3 pCi/L- 50/50
Aquatic BCG Report for Level I
Sum of Total Ratio: 1.16E+OO
Sum of Water Ratio: 1.1 6E+OO
Sum of Sediment Ratio: 3.20E-03
1~~lideConcentration
BCG
Ratio
Limiting
(pC1IL)
(pCi/L)
••
Organism
Ra~226
2.15E+00
4.08E+00
5.27E-
Riparian
Ra-228
2.15E+00
3.40E+00 6~E ,~
~
~iuclide Concentration
-
BCG
Ratio
Limiting
I
•
(pcwg)
~p~Wg~
I
Organism
~a12~...
1.51~-01
~+o2~ 1.49E~FR~arian
r~
~
1.71E~-r ~
Case 4-
MAX
7.5 pCi/L- 50/50
Aquatic BCG Report for Level I
Sum of Total Ratio: 2.03E+OO
Sum of Water Ratio: 2.02E+OO
Sum of Sediment Ratio: 5.59E-03
U
Vvater
NucIide~
C0~~ ~~tb0t1
Ratio
cgnisn
Case 5- AVG 10 pCi/L- 50/50
Aquatic BCG Report for Level I
Sum of Total Ratio: 2.71E+0O
Sum of Water Ratio: 2.70 E+00
Sum of Sediment Ratio: 7.45E-03
e
i
Nuclide Concentration
BCG
Ratio
Limiting
(pCi/L)
(pCi!L)
Organism
Ra-22’3
5.OOE+O0
-
I
Riparian
Animal
e
‘Nuclide ~concentration
BCG
Ratio
-~ - Limiting
~pCi/g~
~p~i!g~
j
Organism
I .OiEi-02
34tE-
Rip~rian
03
,hII~maI
8 78E÷01 3.99E-
Riparian
I
03
Anim3l
5.OOE+00
Case 6- AVG 6.8 pCi/L- 50/50
Aquatic BCG Report for Level I
Sum of Total Ratio: 1.84E+00
Sum of Water Ratio: I .84E+00
Sum of Sediment Ratio: 5.06E-03
P~uclide Concentration ~~G
Ratio
•
Limiting
(pCIIL)
1 (pCi!L)
-
Organism
-
Ra-226
3.40E+00
-~ 4.08E+00
8.34E-01
Ra 228
3 40E+00
40E+00 ~
~
Se
Nuclide Concentration
BCG
.
Ratio
Limiting
(pCilg)
(pCilg)
Organism
Ra-226
2.38E.01
1.01 E+02
2.35E-
Riparian
03
Animal
Ra-228
2.38E-01
8.78E+01
2.71E-
Riparian
I
m
•
03
Animal
Case 6- MAX 12.0 pCi/L- 50/50
Aquatic BCG Report for Level I
Sum of Total Ratio: 3.25E+00
Sum of Water Ratio: 3.24E+00
Sum of Sediment Ratio: 8.94E-03
Nuclide concentration
~atio
Ra-226
6.OOE+00
4.08E+00
Ar
Ra-228
3.40E+00 ~~“L
~
-,
rNuclide
concentration
BCG
F~ati
Limiting
I
•
(pCiIg)
(pCi!g)
Organism
Ra.226r
4.20E-01
~~E+02 4.15E-
Piparian
Ra~228 r
4.20E01
Case 5-MAX-I 8.0 pCi/L-50/50
Aquatic BCG Report for Level I
Sum of Total Ratio: 4.87E+00
Sum of Water Ratio: 4.86E+00
Sum of Sediment Ratio: 1 .34E-02
~
0:0
1
-
~jcBde Concentration
BçG
-
Rato
I
(pCi!L)
(pCIIL)
-
‘
LOrganism
Ra-226
9.OOE+00
4.08E+00 ~
Ra-228
9.OOE+00
~~E÷00~_ ~
Nuclide Concentration,(pCilg)
(pCiIg)
m
BCG
-~
~
Ratio
-
Organism
Limiting
T Ra-226
r
6.30E-01
1.O1E+02
6.23E-
Riparian
I
I
m
03
Animal
~Ra~228E~01
~~
CASE
1-With Sediment Concentration of 12.2
pCi/g and a Resultant Water Concentration of 1.38
pCi/I to meet the BCG (or = 1)
Sum of Total Ratio: 1.OOE+00
Sum of Water Ratio: 7.45E-O1
Sum of Sediment Ratio: 2.60E-O1
-0
~uclide
________________________
Ra-226
I -
•
‘:•~‘•-.~
•
n--~’
.
~
~-ooC.
Concentration
(pCiIL)
BCG
Ratio
(pCi!L)
Limiting
Organism
1.38E+00
4.08E+00
fliParian
Ra228
t22E+0i~&78E+O1!
Ra-228
1.38E+00
3.40E+00
4.06E.
Riparian
•
01
Animal
-
k~
~
Concentration
I
BCG
.
Limiting
Nuclide
(pCilg)
.
m
(pCi!g)
.
Ratio
Organism
r Ra-226 r~1.22E+01
1.OIE+02
1.21E- I~~iPanan
-
DOE
/ Biota Dose Assessment Committee
Biota Protection Screening Levels
BDAC established a screening formula to establish the allowable level of
radium in water for protection of aquatic biota
Water
Water
Sediments
Sediments
Ra-226
Ra-228
R-a-226
I
Ra-228
4.08
3.4
101
87.8
•Tf:
-
- —
X is greater than 1, biota is at risk and site specific studies must
be done
—
X is less than 1, no additional studies are required
A Graded Approach for Evaluating Radiation Doses to Aquatic
and Terrestrial Biota DOE — STD — 1153-2002
DOE / Biota Dose Assessment Committee
Biota Protection Screening Levels
Example:
Ra-226
=
2.04, Ra-228
=
1.7;
.5 Ra-226 and .5 Ra-228
in
sedimen~.s
2.04
+
1.7
+
.5
-F-
=
1
01
4.08
3.4
101
87.8
(
.5
+
.5
+
.005
+
.005
)
• Therefore:
—
If Ra-226
+
Ra-228 is greater than
3.75
pCi/L, the result will
always be greater than 1, biota is at risk and additional studies
are required
-r_____________
Case 1- AVG 1.3 pCi/L- 50/50
Aquatic BCG Report for Level I
Sum of Total Ratio: 3.52E-O1
Sum of Water Ratio: 3.51 E-O1
Sum of Sediment Ratio: 9.68E-04
~
Ratio
Ra-226
6.50E01
4.08E+0O
1.59E-
Riparian
~i28~
6.50E-01
3.40E+00 1.9iE~ ~~na~
Nuclide
~t~ion1
~
j
Ratio
Ra-226
4.55E-02
1.OIE+02
4.50E~I Riparian
04
Animal
Ra-228
4.55B02
~8E+01 ~
I ~paci:n
Case 1- MAX 2.2 pCi/L- 50/50
Aquatic BCG Report for Level I
Sum of Total Ratio: 5.95E-O1
Sum of Water Ratio: 5.94E-O1
Sum of Sediment Ratio: 1 .64E-03
Concentration
BCG
R
Limiting
Nuclide
(pCiIL)
(pCiIL)
at!o Organism
l.1OE+00
1.1OE+00
:~
~
Nuclide Concentration
BCG
Limiting
(pCi!g)
(pCilg)
Organism
I Ra226 f
7.70E-02
~1E+02 ~
Ir Ripari:n
-
Ra~228
7.7OE~02
~
Case 2- AVG .86 pCi/L- 50/50
Aquatic BCG Report for Level I
Sum of Total Ratio: 2.33E-O1
-
Sum of Water Ratio:
2.32E-O1
Sum of Sediment Ratio:
6.40E-04
-
WaeT
Nucllde Concentration
BCG
Ratior Limiting
~pci/L~
~p~i!L~
Organism
Ra-226
4.30E-01
4.08E+00
1.05E-
Riparian
-
Ra-228
4.30E-01
3.40E+00
1.27E-
Riparian
Nuclide Concentration
BCG
Ratio
Limiting
(pCilg)
(pCilg)
Organism,
~:;—• 30~02 r1~02r2~rRipari:n
~a.228~3.01E..02
~
3.43B
Pipari:n
Case 2- MAX 1.5 pCi/L- 50/50
Aquatic BCG Report for Level I
Sum of Total Ratio: 4.06E-O1
Sum of Water Ratio: 4.05E-01
Sum of Sediment Ratio: 1 .12E-03
Nuclide rconcentration
BCG ~tio
Limiting
I
(pCiIL)
(pCiIL)
Organism
Ra-226
7.50E.01
4.08E+00
1.84E-01
RiparianAnimal
Ra-228
7.50E-01
j3.40E+00 ~2.21E- ~Parian
n
Nuclide Concentration
BCG
Ratio
-
Limiting
(pCilg)
(pCi/g)
Organism
Ra-226
5.25E-02
-~01E+02 5.19~
Riparian
04
Animal
Ra.228~525E..02~E+01
j ~
Piparian
m
C)
-
----
—
-
H---------------
-----z-
-
DOE-STD-1 153-2002
A Graded Approach for
-
Evaluating Radiation Doses to
Aquatic and Terrestrial Biota
MODULE I
PRINCIPLES AND
APPLICATION
Attachment C
DOE-STD-i 153-2002
I Introduction
The U.S. Department of Energy (DOE) is accountable to Congress and the public for the safe
conduct of its
activities, including facility operation, waste management and disposal activities,
and
remediation
of environmental contamination. These
routine activities
may result in
releases of radionuclides to the air and water, accumulation of radionuclides in soil and
sediment, and the potential for plants, animals, and members of the public to be exposed to
radiation. DOE Order 5400.5, “Radiation Protection of the Public and the Environment”
(1990a), lists the environmental radiation protection requirements that DOE and DOE-
contractor employees must meet to protect aquatic animals. In addition, dose limits below
which deleterious effects on populations of aquatic and terrestrial organisms have not been
observed, as discussed by the National Council on Radiation Protection and Measurements
(NCRP 1991), and the International Atomic Energy Agency (IAEA 1992), are considered by
DOE to be relevant to the protection of all aquatic and terrestrial biota on DOE sites.
1.1
Purpose
This DOE technical standard provides a graded approach (including screening methods-and
methods for detailed analyses) and related guidance that DOE and DOE contractors may use
to evaluate compliance with specified limits on radiation dose to populations of aquatic animals,
terrestrial plants, and terrestrial animals due to anthropogenic sources at DOE sites.
Specifically, the technical standard provides dose evaluation methods that can be used to meet
the requirements for protection of biota in DOE Orders 5400.1, “General Environmental
Protection Program” (DOE 1990b), 5400.5 (DOE 1990a), and the dose limits for protection of
biota developed or discussed by the NCRP (1991) and IAEA (1992) Accordingly, this technical
standard uses the biota dose limits specified below within a graded approach to demonstrate
that populations of plants and animals are adequatelyprctected’ftam the effects of ionizing
radiation:
Aquatic Animals. The absorbed dose to aquatic animals should not exceed I rad/d
(10 mGy/d) from exposure to radiation or radioactive material releases into the aquatic
environment. This dose limit is specified in DOE Order 5400.5.
Terrestrial Plants. The
absorbed dose to terrestrial plants should not exceed I rad/d
(10 mGy/d) from exposure to radiation or radioactive material releases into the terrestrial
environment.
Terrestrial Animals. The absorbed dose to terrestrial animals should not exceed 0.1 rad/d
(1 mGy/d) from exposure to radiation or radioactive material releases into the terrestrial
environment.
Avoiding measurable impairment of reproductive capability is deemed to be the critical
biological endpoint of concern in establishing the dose limits for aquatic and terrestrial biota.
Module 1, Section 1.2.2 discusses this issue further. Guidance for interpreting and applying
Mi-i
DOE-STD-I 153-2002
these dose limits with respect to the length oftime and geographic area over which actual
doses should be compared with the limits is provided in Module 2, Section 3.
DOE has proposed these dose limits for aquatic and terrestrial biota under proposed rule
Title 10, Code of Federal Regulations, Part 834 (10 CFR 834), “Radiation Protection of the
Public and the Environment” (DOE 1993). DOE has decided not to promulgate these dose
limits until guidance for demonstrating compliance has been developed. Consequently, this
technical standard was developed, in part, in response to comments and recommendations
received by DOE through the proposed rule comment period. Principal themes in the
comments included: (1) requests for development of cost-effective methods to support the use
of DOE’s existing and proposed biota dose limits, (2) support for a multi-tiered approach to
include screening, (3) requests for guidance on biota monitoring, and (4) requests for
development of a generic method to promote consistency, while retaining some flexibility for
site-specific methods and information. These themes served as the guiding principles for
development ofthe methods contained in this technical standard.
The specific methods and guidance in this technical standard are acceptable for use by DOE
and DOE-contractors when evaluating doses to biota in relation to the above dose limits.
The methods and guidance in this technical standard should also be useful to ecological risk
assessors who must evaluate risks to biota from radionuclides that occur on DOE sites. Using
the graded approach provided in this technical standard, risk assessors can use soil, sediment,
and water radionuclide concentration data to determine whether radionuclide concentrations at
a site are likely to result in doses in excess of those listed above and would, therefore, have the
potential to impact resident populations of plants and animals. The methods can also give risk
assessors an immediate qualitative assessment of the importance of doses of ionizing radiation
to the resident receptors. The dose equations in this technical standard also provide methods
of estimating upper-bound (e.g., conservatively derived) doses to specific plants and animals.
Refer to Module 1, Section 3, for a description of intended and potential applications of the
DOE graded approach.
1.2
Background
1.2.1 Increasing Interest and Need for Biota Dose Evaluation Methods
There is growing national and international interest in establishing a regulatory framework (e.g.,
to include standards or criteria) and supporting evaluation methodologies for demonstrating
protection of the environment from the effects of ionizing radiation. Regarding environmental
protection, the ICRP statement that
“. . .
if man is adequately protected then other living things
are also likely to be sufficiently protected” (ICRP 1977; 1991) uses human protection to infer
environmental protection from the effects of ionizing radiation. This assumption is most
appropriate in cases where humans and other biota inhabit the same environment and have
common routes of exposure, and less appropriate in cases where human access is restricted or
pathways exist that are much more important for biota than for humans. The inclusion of
-
M1-2
-
DOE-STD-1 153-2002
radiation as a stressor within ecological risk assessments is also a consideration. Ecological
risk assessments at contaminated sites being considered for remediatiori under-the
Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) generally
require an assessment of all stressors, including radiation. Assessments of radiation impacts
on contaminated ecosystems are currently underway in the U.S. under CERCLA regulations
(EPA 1988).
Nationally and internationally, no
standardized methods have been
adopted for evaluating doses and
demonstrating protection of plants and
animals from the effects of ionizing
radiation. In 1999, the IAEA convened
a technical committee examining
protection of the environment from the
effects of ionizing radiation and
provided recommendations and
discussion points for moving forward
with the development of protection
frameworks and dose assessment
methods. The resulting IAEA
Technical Document, “Protection of
the Environment from the Effects of
Ionizing Radiation” (1999) references
multi-tiered screening as a potentially
cost-effective and easy way of
demonstrating compliance with
radiation criteria for protection of biota.
The IAEA has subsequently hosted a
series of Specialists’ Meetings on radiological protection of the environment, and the Nuclear
Energy Agency (NEA) and the ICRP have sponsored a series of fora on this issue. It is hoped
that the methods and guidance provided in this DOE technical standard will serve as a platform
for national and international discussion of radiation protection frameworks, standards, and
dose assessment methods for biota.
1.2.2 Basis for Biota Dose Limits Applied in this Technical Standard
A dose limit for controlling radiological impacts from DOE activities to native aquatic animals is
specified in DOE Order 5400.5. At present, DOE Orders do not specify dose limits for
terrestrial organisms. However, an intended objective of DOE Orders 5400.1 and 5400.5 is to
protect the aquatic and terrestrial environment, including populations of plants and animals,
within and beyond the boundaries of DOE sites from impacts of routine DOE activities. The
dose limits in this technical standard are consistent with (a) the intent of DOE Orders 5400.1
Benefits of a Screening Process
“A multi-tiered screening approach is normally used in
ecologicalrisk assessments. Screening may also be a
potentially cost-effective and easy way of
demonstrating compliance with radiation criteria or
standards forprotection of the environment. Screening
values should be used to identify radionuclides in
situations of concern, and to determine whether these
radionuclides warrant further assessment, or if they are
at levels that require no further attention. In practice,
this initial screening isexpected to be sufficient in the
majority of cases. When initial screening falls,
additional analysis or assessment may be needed. A
two- or three-tiered scheme would help ensure that the
magnitude of the assessment effort would be scaled to
the likelihood and severity of environmental impacts.”
From: IAEA-TECDOC-1091, Protection of the
Environment from the Effects of Ionizing Radiation:A
Report forDiscussion (July 1999)
Mi-3
DOE-STD-1 153-2002
and 5400.5, (b) the dose limit for aquatic animals specified in DOE Order 5400.5, and
(c) findings of the IAEA and NCRP regarding doses below which deleterious effects on
populations of aquatic and terrestrial organisms have not been observed. They are also
consistent with the intent of the IAEA document, ‘The Principles of Radioactive Waste
Management” (IAEA 1995), in which Principle 2 states that “radioactive waste shall be managed
in such a way as to provide an acceptable level of environmental protection.” The background
for the dose limits for aquatic and terrestrial biota is briefly discussed below. These dose limits
represent expected safe levels of exposure, and are- consensus No Adverse Effects Levels
(NOAEL5) for effects on population-relevant attributes in natural populations of biota.
1.2.2.1 Aquatic Organisms
At the request of DOE, the NCRP (1991) reviewed the literature on the effects of radiation on
aquatic organisms and prepared a report on the then-current understanding of such effects.
The report also provided guidance for protecting populations of aquatic organisms, concluding
that a chronic dose of no greater than 1 rad/d (0.4 mGy/h) to the maximally exposed individual
in a population of aquatic organisms would ensure protection of the population.
The IAEA examined and summarized the conclusions regarding aquatic organisms of several
previous reviews (IAEA 1992):
Aquatic organisms are no more sensitive than other organisms; however, because they
are poikilothermic animals, temperature can control the time of expression of radiation
effects.
The radiosensitivity of aquatic organisms increases with increasing complexity, that is,
as organisms occupy successively higher positions on the phylogenetic scale.
The radiosensitivity of many aquatic organisms changes with age, or, in the case of
unhatched eggs, with the stage of development.
•
Embryo development in fish and the process of gametogenesis appearto be the most
radiosensitive stages of all aquatic organisms tested.
• The radiation-induced mutation rate for aquatic organisms appears to be between that
for
Drosophila
(fruit flies) and mice.
Furthermore, the 1992 review found that the conclusions of an earlier IAEA review (1976) were
still supported; namely, that appreciable effects in aquatic populations would not be expected at
doses lower than I rad/d (10 mGy/d) and that limiting the dose to the maximally exposed
individuals to less than I rad/d would provide adequate protection ofthe population.
MI-4
DOE-STD-1 153-2002
1.2.2.2 Terrestrial Organisms
The IAEA (1992) summarized information about the effects of acute ionizing radiation on
terrestrial organisms as follows:
•
Reproduction (encompassing the processes from gametic formation through embryonic
development) is likely to be the most limiting endpoint in terms of survival of the
population.
• Lethal doses vary widely among different species, with birds, mammals, and a few tree
species being the most sensitive among those considered.
• Acute doses of 10 rad (100 mGy) or less are very unlikely to produce persistent and
measurable deleterious changes in populations or communities of terrestrial plants or
-
animals.
The IAEA (1992) also summarized information about the effects of chronic radiation on
terrestrial organisms:
• Reproduction (encompassing the processes from gametogenesis through embryonic
development) is likely to be the most limiting endpoint in terms of population
maintenance.
•
Sensitivity to chronic radiation varies markedly among different taxa; certain mammals,
birds, reptiles, and a few tree species appear to be the most sensitive.
•
In the case of invertebrates, indirect responses to radiation-induced changes in
vegetation appear more critical than direct effects.
• Irradiation at chronic dose rates of I rad/d (10 mGy/d) or less does not appear likely to
cause observable changes in terrestrial plant populations.
•
Irradiation at chronic dose rates of 0.1 rad/d (1 mGy/d) or less does not appear likely to
cause observable changes in terrestrial animal populations. The assumed threshold for
effects in terrestrial animals is less than that for terrestrial plants, primarily because
some species of mammals and reptiles are considered to be more radiosensitive.
•
Reproductive effects on long-lived species with low reproductive capacity may require
further consideration.
The NCRP and IAEA concluded for aquatic organisms and the IAEA concluded forterrestrial
organisms that the statement by the ICRP (1977; 1991), “...if man is adequately protected, then
other living things are also likely to be sufficiently protected” was reasonable within the
M1-5
DOE-STD-1 153-2002
limitations of the generic exposure scenarios examined. A similar assessment was made at a
DOE-sponsored workshop (Barnthouse 1995) held to evaluate the adequacy of existing effects
data and approaches to radiation protection of aquatic and terrestrial organisms to support
moving forward with setting regulatory limits. DOE workshop participants agreed that
protecting humans generally protects biota, except under the following conditions: (I) human
access to a contaminated area is restricted but access by biota is not restricted, (2) unique
exposure pathways exist for plants and animals that do not affect exposure of humans, (3) rare
or endangered species are present, or (4) other stresses on the plant or animal population are
significant.
1.2.2.3 Additional Summaries and
Reviews
of Radiation Effects Data on Biota Confirming
NCRP and IAEA Findings
UNSCEAR.
In 1996, the United Nations Scientific Committee on the Effects ofAtomic
Radiation (UNSCEAR) summarized and reviewed information on the responses to acute and
chronic radiation of plants and animals, both as individuals and as populations (UNSCEAR
1996). The conclusions from the UNSCEAR reviewwere consistent with findings and
recommendations made earlier by the NCRP and IAEA concerning biota effects data and
appropriate dose limits for protection of biota. In 2002, UNSCEAR reported that these dose
rate criteria (1 rad/d for aquatic animals and terrestrial plants; 0.1 rad/d for terrestrial animals)
remain defensible for protection of populations of plants and animals. The UNSCEAR plans to
develop a new scientific annex to further address radioecology and effects of radiation on the
environment (Gentner 2002).
UK Environment Agency.
In 2001,
the
Environment Agency of the United Kingdom (UK)
conducted a review of the available body of radiation effects data on biota (Copplestone et al.
2001). They concluded that it is unlikely that there will be any significant effects in:
• populations of freshwater and coastal organisms at chronic dose rates below 400 uGy/h (or
1 rad/d; 10 mGy/d);
•
terrestrial plant populations at chronic dose rates below 400 uGylh (or I rad/d; 10 mGy/d);
and
• terrestrial animal populations at chronic dose rates below 40 uGy/h (or 0.1 rad/d; 1 mGy/d).
It is noteworthy that the UK Environment Agency’s review findings are largely consistent with
the findings and biota dose recommendations of the NCRP, the IAEA, and UNSCEAR cited
above. Additionally, they concluded that it is unlikely that there will be any significant effects in
populations of organisms in the deep ocean at chronic dose rates below 1,000 uGy/h (or 2.5
rad/d; 25 mGy/d).
M1-6
DOE-STD-l 153-2002
ACRP. In 2002, the Advisory Committee on Radiation Protection (ACRP), charged with
providing advice to the Canadian Nuclear Safety Commission (CNSC) regarding approaches
needed for the radiological protection of the environment, provided recommendations
concerning appropriate dose rate criteria for protection of biota. The ACRP recommended that
the generic dose rate criterion for protecting biota should be in the range of 1-10 mGy/d (0.1-I
rad/d). The ACRP indicated that this dose rate criterion is based on population-level effects
and, given the current state of knowledge and consensus views of radiation effects on biota,
represents the level at which ecosystems will suffer no appreciable deleterious effects. The
criterion is specified in terms of daily dose rather than annual dose. The intent is to avoid, for
example, what would be the annual dose at this dose rate criterion being received in a few
days. The ACRP further recommended that there should be some flexibility in the averaging
time used in interpreting this dose rate criterion (CNSC-ACRP 2002).
1.2.2.4 Application of Biota Dose Limits as “Dose Rate Guidelines” for Evaluating Doses
to Biota
The biota dose limits specified in this technical standard are based on the current state of
science and knowledge regarding effects of ionizing radiation on plants and~anima!s.They
should not be interpreted as a “bright line” that, if exceeded, would trigger a mandatory
regulatory or remedial action. Rather, they should be interpreted and applied more as “Dose
Rate Guidelines” that provide an indication that populations of plants and animals could be
impacted from exposure to ionizing radiation and that further investigation and action is likely
necessary.
1.2.3 Protection of Populations
The intent of the graded approach (i.e., the screening and analysis methods) in this technical
standard is to protect populations of aquatic animals, terrestrialanimals, and terrestrial plants
from the effects of exposure to anthropogenic ionizing---r-adiation. As noted above, certain taxa
are more sensitive to ionizing radiation than others. Based on this observation, it is generally
assumed that protecting the more sensitive taxa will adequately protect other, less sensitive
taxa. Hence, in cases where site-specific evaluations may be required, receptors should be
selected that (1) are important to the structure and function of the community, (2) are expected
to receive a comparatively high degree of exposure (e.g., expected to receive a radiation dose
to reproductive tissues which is relatively high per unit of radionuclide present in the ecosystem,
in comparison with other receptors in the same community), and (3) have a comparatively high
degree of radiosensitivity (e.g., radiation effects of concern occur at relatively low doses, in
comparison with other receptors in the same community). Figure 1.1 shows the relative
radiosensitivity of various taxa for both aquatic and terrestrial systems.
Participants at the DOE-sponsored workshop to evaluate the adequacy of existing effects data
and approaches to radiation protection of aquatic and terrestrial organisms (Barnthouse 1995)
concluded that existing data support the application of recommended dose limits to
Ml-7
Table 6.2 Blota Concentration Guides (BCGs) for Water and Sediment (In Special Units) for Use in Aquatic System
Evaluations. For use with measured radionuclide concentrations from co-located water and sediment.
144Ce
2E+03
Aquatic Animal
3E.i-03
Riparian Animal
135CS
5E+02
Riparian Animal
4E+04
Riparian Animal
137Cs
4E÷01
Riparian Animal
3E+03
Riparian Animal
60Co
4E+03
Aquatic Animal
-
1 E÷03
Riparian Animal
154Eu
2E+04
Aquatic Animal
3E+03
Riparian Animal
155Eu
3E+05
Aquatic Animal
3E÷04
Riparian Animal
3H
-
3E÷08
Riparian Animal
-
4E+05
Riparian Animal
1291
-
4E+04
Riparian Animal
3E+04
Riparian Animal
1311
-
1 E+04
Riparian Animal
5E+03
Riparian Animal
239Pu
2E+02
Aquatic Animal
6E+03
Riparian Animal
~6Ra
4E+00
Riparian Animal
1
E+02
Riparian Animal
-
~8Ra
3E+00
Riparian Animal
9E+O1
Riparian Animal
125sb
4E+05
Aquatic Animal
7E+03
Riparian Animal
90Sr
99Tc
232Th
233jj
3~+0-2
7~+05
3ç+02
2Et+02
Riparian Animal
Riparian Animal
Aquatic Animal
Aquatic Animal
6E÷02
4E+04
1 ~+03
5E~+03
Riparian Animal
Riparian Animal
Riparian Animal
Riparian Animal
234(J
21+o2
Aquatic Animal
5F+03
Riparian Animal
235~J
2E+02
Aquatic Animal
-
4E~+03
Riparian Animal
238~J
2~+02
Aquatic Animal
2~+O3
Riparian Animal
65Zn
1 E:+01
Riparian Animal
1
Riparian Animal
95Zr
7:+03
Aquatic Animal
2÷03
Riparian Animal
241Am
4E÷02
Aquatic Animal
5E+03
Riparian Animal
-1
United States. Government.. ~-
Deba~n~eflt~Eflcr~Y
rem-~o..-ra:n-durn
DATE:
August 27, 2002
REF’LYTO
ATTN OF:
Office ofEnvironmental Policy and Guidance: Domotor: 6-0871
SUBJECT:
Availability ofDOE-Approved Technical Standard, “A Graded Approach forEvaluating
Radiation Doses to
Aqi.tatic
and Terresirial Biota (DOB~STD-1153-2002),” for Use in
DOE
Compliance and Risk Assessment Activities
TO:
Distribution
The purpose of this memorandum is to inform you on the availability ofthe recently
approved Department of Energy (DOE) technical standard, “A Graded Approach for
EvalUating RadiationDoses to Aquatic and TerrestrialBiota (DOE-S1D-1153-.2002).”
The technical standard provides methods arid guidance within
a graded approach
for use
In demonstrating protection ofbiota (plants and animals) from potential effects of
ionizing radiation. This voluntary consensus technical standard was prepared by the Air,
Water, and Radiation Division (EH-412) and the Department’s Biota Dose Assessment
Committee, an approved DOE Technical Standards Program topical committee
comprised ofrepresentatives from across the DOE complex.
The technical standard provides screening methods and, if needed, methods for more-
detailed analysis within a graded framework that can be used for demonstrating
compliance with re uirements contained in DOE Order
5400.~,
“Radiation Protecti9~of
-
the Public and the Environment.” it can also be use o support environine~italprotection
program elements within Enviromnental Management Systems at
DOE
sites, and for
conducting ecological risk assessments ofradiological impact. DOE Order
5400.5
specifies the radiation -protection requirements that IDOE and
DOE contractor
employees
must meet to protect aquatic animais. In addition, dose rate guidelines below which
deleterious effects have not
been
observed in populations of aquatic or terrestrial
organisms, as
recommended
by tin National Council on Riidiation Protection and
—Measurements, and the International Atomic Energy Agency, are considered by DOE to
be relevant for the protection ofaquatic and terrestrial biota at DOE sites.
This technical standard is responsive to DOE’s needs and to increasing stakeholder and
regulator interest concerning protection ofthe environment (biota and ecosystems) from
the effects of radiation. Internationally, the general practice ofusing human radiation
protection to infer ecological protection is being re-considered for certain radiological
contamination scenarios. Accordingly, explicit guidelines arid methods for
demonstrating radiological protectionofthe environment are being considered or are
already under development by certain countries and international organizations. The
evaluation ofradIation as a stressor within ecological risk assessments is also a
consideration. Ecological risk assessments at contaminated sites being considered for
remediation (e.g., under the Comprehensive Environmental Response, Compensation,
and Liability Act, CERCLA) generally require an assessment ofall stressors, including
V~f~/U4
.L~.’;ZU !~AA
bU4 ~
14U5
V. B.
MCINTYRE LAW’ CORP.
1~Joo~
radi.ation.
Pinally,
DOE
long-term stewardship (LTS) planning documents at the local
and
national level
indicate
that protection of
natural resources is integral to a successftl
LTS program, and
cited radiological impact on wildlife as a public concern at
radiologically-contaminated sites requiring long-term stewardship.
The Department’s graded approach for evaluating doses to biota was designed for
flexibility and acceptabi1ity~It provides users with a tiered approach for demonstrating
compliance with biota dose rate guidelines that is cost-effective and easy to implement, it
allows for the use ofmeasured radionudilde concentrations in enviromnental media
typically collected as part ofDOE routine site environmental surveillance programs, it
incorporates ecological risk assessment concepts, and it provides guidance for site-
specific biôta dose assessments where needed. A copy ofthe technical standard and the
RAD-:BCG Calculator (a companion software progmm for use with the technical
standard) can be downloaded from the 3iota Dose Assessment Committee web site
(http://honier.ornj. gov/oepa/óubliofbdac) and.from the DOE Technical Stand~ds
Program home ‘page (http://tis.ehdoe~g~ov/techstds/standard/standfrmhtni1).
The Biota Dose Assessment Committee is available as a technical resource concerning
the implementation ofmethods arid guidance contained in this technical standard.
Requests for Committee assistance should be -coordinated through the chairperson (IVir~
Stephen Dornotor, EH-412,202-586-0871, tenhen.Domotor(~,eh.doe.gov).Questions
concerning thIs technical standard, requests for a copy ofthe technical standard, or
communication oflessons learned from its implementation should also be coordinated
through Mr. Domotor (E~-I-412).
fry ~
Andy Lawrence
Director
Office ofEnvironmental Policy and Guidance
Distribution:
Attached
cc:
Biota Dose Assessment Committee
Environmental Radiological Control
Coordinating CormnIttee
Annual Site Environmental Report
Points ofContact
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SJTE RE1~EDIAT1OMPLAN
FOR
THE
NORTJIEA$T
OHIO REGXOXAL SEWER DIST~i
- -
SOTJTKEBLY
WASTEWAEER TREATMENT PL.~NT
CUYAHOGA
BEIGflTS,
OHiO
conclusion can be drawn from the locations of the more highly contarnth~ttedm~ierial,nor is.
there any indication that other areas of higher concentrarion. exist.
The amount
of
Co-60 contained in the inciBerator-ash deposited in the
?~TA
an~the Old Sludge
Lagoon was calculated as
405.9
mCi. Additionally, the Northern
secC~.l~i
~f
the ~FA contains
38.5 mCi of Co-60 in the fom~of contaminated sludge (B. Kob. and-Associates. I~ic.,February
1995).
3.1.4.10
Main Plant
Based upon the -results of the radiological analyses performed by RSO, lri,,
levels of
Conta.mination associated with the Main Plant do not present radiological hazards to workers
exceeding the exposure limits specified .by the NRC in 10 CPR 20.
The estimated activity from the Fume Incinerator Tanks, Pume Incinerator Tank #1(104 ~.Ci),
FWDe
Incinerator Tank ~2 (12 ~Ci) and Fume Incinerator Tank
#3
(400 ~Cfl resulted in ~ total
activity of approximately 0~5
mCi.
3.2ALARA
-
-
NEORSD
is
committed
to keepIng
radiation exposure to employees and the general pubUc as low
as reasonably achievable (ALARA), commensurate with sound ~c~nomic and social
consideratioxis. The NEORSD management has demonstrated their comtiiitincn~‘Dy &SS2~D3fl~
b5~ltpriority to procedure changes arid work plans that will reasonably reduce personnel and
cnvironmentai radiation etpo~ures. Furthennore, NEORSD will place primary enapbasis on
design and engineering features to ixiairitain exposure ALARA. When practical, design fealnres
will be selected in lieu of administrative controls to iuai.ri.tain exposures ALARA. The exi.sting
NEORSD Radiological Control Plan (Dames & Moore, March 1993) promu.lgates :b.e NEORSD
BKA000I .NEO:NBO-Qj
Septertmer 1996,
P~EV.0
3-15
B Koh
an~
Asso~jares,Inc.
sw~p~~
d~:80 ~o co
da~
Attachment F
m
0~
-h
C)
‘WRT
December
17, 2003
12
-
ATTACHMENT
City ofJoliet
-
Water and Wastewater Plants
-
Radium Capture in Sewage Sludge
The following is a hypothetical analysis of radium being captured in sewage sludge assuming all
water pumped from city, wells reaches the sewage plant.
Water Supply
-
2003 data used (Source: September 2003 Engineering Evaluation Report)
Average Daily Pump age = 16 mgd
Average Radium Content
13.3 pCi/L (Range: 8.1 to 17 pCi/L)
Radium Production
Average Daily: 16 mgd x 3.785 L/gal. = 60.56 E±06L/day
60.56 E+06 L/day x13.3 pCifL = 805.45 E+06 pCilday
Annual:
805.45
E±06pCi/day x 365 days/year = 293.99 E-4-09 pCi/year
1 Ci = E+12 pCi
—
293.99 E+09 / E+12 293.99 E-03 = 0.294 Cilyear
Sewage Plant
(2002 data from DWPC data base)
West Plant
East Plant
Totals
Ave.Daily Flow
-
7.628 mgd
17.7986 mgd
-
25.4266 mgd
Annual Sludge
-
Production (2002)
988 dry tons
2400 dry tons
3388 dry tons
Approved
Application Rate
2.4-2.6 dry tons/acre
3.3-3.5 dry tons/acre
Proportionate Flow: West plant 7.628/25.4266 = 30; East Plant 17.7986/25.4266 70
Assume all radium from the water supply is captured in the sewage plant sludge.
Assume 1 gram radium = I Ci (original definition)
—
I pCi radium = 1.0 E-12 grams radium
Attachment G
WRT December 17, 2003
13
West Plant
Sludge: (988 dry tons)(2000 #/ton)(453.5924 gr/#) = 8.963 E+08 grams
Proportionate Radium: 293.99 E+09 pCi x 30 = 88.2 E+09 pCi radium
RadiumlSludge Mix: (88.2 E+09 pCi radium) /(8.963 E+08 gr Sludge) 98.40 pCi/gram
Sludge Loading: (2.5 dt/ac)( 000 #/ton~53.S924gr(#~=52.065 grams/sq.ft.
(1 acre)( 43560 sq.ft/ac)
Radium Loading: (98.40 pCi/gr) /(52.065 gr/sq.ft) = 1.8899
—
1.89 pCi/sq.ft.
Assume soil weight = 120
#Icu.ft.:
(120#fcu.ft) x (453.5924 grf~)= 54431.09 grams/cu.fi.
Assume 0.5 ft. plow down:
(1.89 pCi/sg.ft)
= 6.94 E-O5 pCi/gram Radium/Soil
(54431.09 gr/cu.ft)(0.5 fi)
Fie)d Mix
Application Area: (988 dry tons) / (2.5 thy tons! acre) = 395.2 acres
East Plant
Sludge: (2400 dry tons)(2000 ~/ton)(453.592-4gr/#) = 2.177 E+09 grams
Proportionate Radium: 293.99 E±09pCi x 70 = 205.79 E+09 pCi radium
Radium/Sludge Mix:(205.79E±09pCi radium)/(2. 177 E+09 gr Sludge) = 94.S3pCi!grarn
Sludge Loading: (3.4 dtfac)(2000 #!ton~53.5924gr/#) = 70. 809 grams! sq.ft.
-
(1 acre)( 43560 sq. ft/ac)
Radium Loading:
(94,53
pCi/gr) /(70.809 gr/sq.ft) = 1.33
5
pCi/sq.ft.
Assume soil weight = 120 #/cu.ft : (120#/cu.ft) x
(453.5924
gr/#)
34431.09 grams/cuff
Assume 0.5 ft. plow down: (1.335 pCi/sg.ft’)
= 4.90 E-05
pCi/gram
Radium/Soil
(5443 1.09 gr/cu.ft)(0.5 ft)
-
Field Mix
Application Area: (2400 dry tons) / (3.4 dry tons! acre) = 705.9 acres
Exhibit H
Data/Case Study 2002-02
A Comparison of Potentiometric Surfaces
for the Cambrian-OrdOvician Aquifers
of Northeastern Illinois,
-
1995 and 2000
by
Stephen L. Burch
Groundwater Section
Illinois State Water Survey
A Division of the
Illinois
Department
of Natural Resources
2002
Attachment H
A Comparison of Potentiometric Surfaces
for the Camb rian-Ordovician Aquifers
of Northeastern Illinois, 1995 and 2000
by
Stephen L. Burch
Illinois State Water Survey
Champaign,
IL
Table 1. Distribution ofPumpage from Deep Bedrock Wells in Northeastern Illinois, 1995-1999 (mgd)
Year
County
Public
-
Industrial
Total
Year
County
Public
Industrial
Total
1995
Cook
4.97
6.20
11.17
1998
Cook
4.43
6.74
11.17
DuPage
2.02
0.30
2.32
DuPage
1.52
0.25
1.77
Grundy
2.59
6.36
8.95
Grundy
2.66
6.96
9.62
Kane
13.77
0.40
14.17
Kane
16.10
0.30
16.40
Kendall
1.58
0.31
1.89
-
Kendall
2.03
0.30
2.33
Lake
2.46
1.07
-
3.53
Lake
2.89
0.94
3.83
McHenry
2.68
1.53
4.21
MeHenry
3.00
2.40
5.40
Will
15.18
5.91
21.09
Will
15.33
5.27
20.60
Total
45.25
22.08
67.33
-
Total
47.96
23.16
71.12
1996
Cook
4.42
-
6.58
11.00
1999
Cook
4.17
7.04
-
11.21
DuPage
2.27
0.25
2.52
DuPage
1.80
0.25
2.05
Grundy
2.58
6.98
9.56
Grundy
2.76
7.12
-
9.88
Kane
-
15.50
0.50
16.00
Kane
16.12
0.34
16.46
Kendall
1.65
0.29
1.94
Kendall
2.15
0.30
2.45
Lake
2.51
1.03
3.54
Lake
3.07
0.83
3.90
MeHenry
2.36
1.92
--
4.28
McHenry
3.53
2.09
-
5.62
Will
15.23
6.06
21.~9
Will
15.14
5.23
20.37
Total
46.52
23.61
70.13
Total
48.74
23.20
71.94
1997
Cook
3.80
6.43
10.23
DuPage
2.28
0.25
2.53
Grundy
2.56
6.78
9.34
Kane
15.57
0.32
15.89
Kendall
1.75
0.30
2.05
Lake
2.71
0.93
3.64
McHenry
3.20
2.35
5.55
-
Will
15.62
5.82
-
21.44
Total
47.49
23.18
70.67
--
—
~
Groundwater withdrawals from the deep bedrock aquifers declined and then steadied
briefly
at the end of the twentiethcentury,
as public water supplies in Cook, DuPage, and Lake
Counties switched to Lake Michiganwater. Demand on the deep bedrock aquifers increased
slowly in the southwest counties (Lake, McHenry, and Kane). During the 1995-1999 period,
pumpage for public and industrial supplies from deep bedrock wells (Cambrian-Ordovician) rose
slightly from 67.3 to about 72 mgd. Table 1 shows the distribution ofpumpage in the eight-
county Chicago region between 1995 and 1999, subdivided by public and industrial use
categories, and by counties.
The Chicago region has about 150 public water-supply facilities and another 100
industrial facilities. Most ofthese thcilities are small users and are not especially important when
consideredindividually. Consequently, it has been found convenient to examine the membership
ofthose public water-supply facilities pumping more than 1.0 mgd from the deep bedrock
aquifers in 1999. The number offacilities is the same as in the last report (Visocky, 1997). The
composition of the group has changedto include the communities ofLemont, Oswego,
Romeoville, and Plainfield, however. Bartlett, Beliwood, Elgin, and Lockport dropped offthe
list because their daily pumping rates decreased to less than 1.0 mgd. Pumpage at the other
facilities ranged from 1.15 to 10.05 mgd, as shown in Table 2. Joliet and Aurora are decidedly
the largest deep bedrock public water supplies in the Chicago region.
Table 2. Public- Water-Supply
Facilities in the
Chicago Region
Pumping More than
1.0 mgd from Deep Bedrock Aquifers, 1999
Community
Pumpage (mgd)
Joliet*
10.05
Aurora
5.80
Crystal Lake
2,25
Lake Zurich
-
1.95
-
Morris
-
1.81
Batavia
1.60
-
West Chicago
1.58
Montgomery
1.46
NorthAurora
1.40
Geneva
1.33
St. Charles
1.32
Lemont
1.27
Oswego
1.26
Western Springs
1.23
Romeoville
1.15
Plainfield
1.15
Note~
*This number reflects the last-report from Joliet for 1995 pump age.
15
Figure 9. Changes in groundwater level in deep bedrock wells
in northeastern Illinois between
1995
and 2000
-
30
m
0~
-1-
/
Form Approved.
0MB
No. 2040-0086.
FORM
U.S.
ENVINONMENTA~~P~~OT~~TJONAGENCY
I. EPA I.D. NUMuER
-
-.‘~ r~””’”.~
~r~’~’”~
$Ar~f~j
“I 1 Y
~
~enioJida~d P.m,itsProgram
-
F
~i LD 0
0 0 8 0 3 6 4 3
D
GENERAL
(R.cd
th~
~GenercI1nitna~ions”
bffor
•tartin5.)
‘
1.
-
I.
II. POLLUTANT CHARACTERISTICS
--
INSTRUCTIONS Complete A through
J
to
dst,nnlne
whether
you need to
submit any permit ipplication forms to
the EPA. If you
answer “yes”
to any
qussions, you must
submit this form and
the
supplemental
formTisted
ii~
the
psrentheiisfoil~wing
the
question; Mark “X” In the-
boxin the third column
If
the supplemental form Is attached It you
answer • no’ to each question you need
not
submitany
of these forms. You
may enst~~
“p0” If your activity
is excluded from permit
requirements; see
Section C of the
iintructioni. See also, Section a
:of di~
InstructiOàs
fqr
definitions ofbotd—faCId tenns.
.
--
-
.
-
SPECIFiC QUESTIONS
A. h this f~c4lityapubliCiy owned lrsatmant.woqlti
C. Is that
i
facility whiCh currently results
in.diicharg~
So waters of the IJ.5 ~th.r than those
descrebed
in
A or B
above? (FORM
2C)
vt,•
-~-
X
:ii:
L6J
no
~
,~
..~
A
~
spsciric QUESTIONS
8. ~-~‘‘t~:
diachargs
to
waters
of the
U.S.?
(FORM28)
0. Is this
a proposed
facIlity
(ether than those deaca-ib&
In A or B pbove~
which will result
In a dlechargs ~o
.
wetefi of
thiU.S.?
(FORM 2D1
-
MAR
~
~0
~
,,
~
—
X
~
K ~
~
,
,,
•
.
E.
Does
or will this facility treat, store, or
dimose
of
hazardous
waStes?
IFORM ~u)
-
~,
F.
Do
.yâu or
wItI.you inject at
thIi.tedItIty indUstrIal os~.
-
municipalteining,
wIthinefffumone
below
quertir
the
mile
lowermost
of thu
stttumcri
!N.lI
bore~.
undsrgroufld ources of drinking water? (FQRM 4i~~
—
X
.~
—
-
G
Do you or wall you inject at ths~taCilily any
oduced
th~
...
water or o
h
Cr
I
UI
“
S W
h
a
Ii Cr br
ought
th.
turf
H. DO
.
YOU or wi!
.
you
lnj.ct
.
at
.
at ac ~SYf ii
.
;
crap.-
--
in connacuon with conventional Oil or natural gas pro.
x
CR1 PVOCS
~
as
mining o Ma
ur y
x
-
- procese-~oluslonmining
of mineral,
ln.alttr conibus-:
ductici’. inject fluids uSed 0 Sfl aflCCU recovery ,o
.
;.-
.. .
.. ~
.
~-
.
-
oil or natural
gas
or inject flu.dt
for
storage of
liquid
—
~~of Jowl
,,~e or ~açovery o gao
hy9u(enerpv
—
hydrocerbOfll? (FORM 4)
a.-... -
~,
..
-
~i~•
~
.
:‘~.-$~
~
,, .
I.
~
is this facility -e
proposed Itetionary Iou,c.
which is
~J. a
this
facilIty:.
proposed itatlonary iourc~whIcfrw.
one of thu 28 ,ndu,ir,$l categorIes
~lsted
in the in
NOT one of the 2a
fndu,trial cetego,lef.U4$.d~~tie
Structions
and ~
potentially ,mil-;lOOgns
X
.:..insts~tjon~’vhlthwj!1potentially-i .2 ion,
X
per
year
of any air pollutant regUlated
under fIts
per
y~ar.of
I.e’
air po8qta t
regulated under~th.gJ.~p4
Clean
Air Act and rnay eRect or be
located~
nan.
~.Aiç
Act
~I~JOW,ffSMiW
b
located Iq in.~tte,flq~t
~
~ ~ ~
NoRMs)~fi~u~
.
~
~
~-
~
-III.
~.F_
flSNIPLASALLE
NAME OF
I
FACILITY~
I I I I I I I
COUNTY
I I I I 5 I
STATION
•
I 1 I I I I I I I I I I I I I I I
JIIIi~
-.
Ii ~
.,‘;
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•~~
-.
;..-.
.
. .4~_,_.,.
ii-
IV. FACILITY CONTACT.
A NAME & TITLE (lees
firJ ~
.~e
PHONr
(arI~u
codr&
nq;’
ci
I
Ii
i
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MGaR 8~1~5J4.1.5J 3~2~0~0
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V. FACILITY MAILING ADDRESS
I
A.-S1REET OR P.O. SOX
-
-
-
c
II
I
I
I
II
III
IIIiII
I
Iii
II
III
~260l NORTH 21ST ROAD
D. CITY OR TOWN
1C~57A1~
0. ZIP CODE
I
III
iiaiaaiiiaIIIII
ii
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I
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-
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61~3~4~1
VI. FACILITY LOCATION
A. STREET. ROUTE NO. OR OTHEI SPECIFIC IOEN.TIPIER
- - -
.
- -
~
•2•i~S•T :R:O.A.D.
: : : : : : :
fl COUNTY NAME
I
II
IIIII1
III
III
LASALLE
-
.
• ~ ~
~ •
~
C.CITYORTOWN
~
~
F.COINTY COOC
*ARSEI
•LL~E~S
~
L~ 1341J
L. .~
EPA Form 3510-1 (0-90)
CONTINUE ON REVERSE
-
Attac1in.iei~t
i
CONTINUED FDflM TI.IF PRONT
SIC CODES
(4.o’igir
in
order
I
I
I
(specIJy~
~4 ,91
iJ ELECTRICAL
GENERATION & DISTR
ii
~
.
Ii
I
I
(specify)
I. II
-
.
C. THIRD
0. FOURTH
I
I I
i(spec-ify~
7...j
S II
—
IS
I I I
(specify)
OS~..
7J...
It
VIII. OPERATOR INFORMATION
A. NAME
~.
lsthenams
tla~.d-)~
C
I
I I I I
I I I I I I I I I I I I S I I I I I i I I I II
I I
i
~ i I I i
j-
~ I
ItS1TtVIll.Aai,O-tIl~
~XELON
GENE,RAT ION COMPANY,
LLC
-J
fs
EJNO
C. STATUS OF OPERATOR
(Enter
the ,zppr ,priati~kiter into thc answer box; it~Ot1w’”.specify.)
0. PHONE
(a’Ta Code &
F
-
FEDERAL
M
-
PUBLIC
(Other than federal or nate)
~specij
-
-
S
-
STATE
0
=
OTHER
(sprcIf~j
- -
-
.
P
PRIVATE
-
0
-
C
I I
II
II
I
I
I
-
A
63 O~.5
321 5
II
~ •
ti
i.
a,
is
-
.
E. STREET OR PD. flOX
III IIIIIIIII IIIIII III IIIIIII I
4300
,_S•
WINF1ELD
F. CITY OR TOWN
ROAD
-
-
-
IS
H.ZIPCODE~
IXINDIANLAND
B~\VARRENVILLE
I I I I I I I I
.1
I I
I
I
IILI
60555
ts
IS
- --
-
-
-0
-
-II
£2
U
•
CS
X. EXISTING ENVIRONMENTAL PERMITS~
Isthef5clktylecstedotLlndianlsnds’
A. NPDES
(OLichalies to Surface W~I.r)
o.
p50 (~fIc
Eminlor.s
from
Fr6
posed Source:)
cvi
II
I Ii
I II
I I II
15,1,
•
cvi
I I I I II
II
III
I
?.I!1,,I..
•
-
e.
usc
(Linde,round
Injection
of
Fluids)
:~~
‘
:
:‘‘
‘
~
E. OTHER
(spec1fy~
~l.~.:l~5:o.0~4ioo816:
.
•
-
~.~~PERAT1NGPER1VIIT(FESOP)
C.
RCRA
~‘Hao,dOs&,Wastes)
5. OTHER
(specify)
~1~1,1~:_:5:1:4:
XI. MAP
—
: : :
:
~•
9:i.:J..’v
~—
j-~.:
: : : :
: : :~
(Sped/f)
~
Attach
to this
lfO~~.opogr~p
ié ma~~ Ui
ex~endingt~a1
k~i
~
the outline
of
the
faciIIty.1’tht~location
of each of its existing a~d
proposed
Intake end
dIscharge~strUC~téres
eacfiof its h~rdou,wa~
treatment storage, ‘~r
d~posaT
~acIIIt1eSand
each
Well
~whereIt Injects
fluids
underground. mci de~’aU.spt~ngs
~rI~.I s
*nd’dther
surface
-water-bodies
~
Xli NATURE OF BUSINESS
(proi~We.a
brief
d~,scr,pnon!
GENERATION
OF
ELECTRIC POWER..
XIII.
CER~rIFICATION(sce/nst,vctions)
-.
/ certify under penalty of law
that
/ have personally
exammed
and am familiar with theJnforrnation
s~ibmltted
in Ibis application andelf
attachments and that,
based
~n my inqui,y of
those
persons Immediately respoAsible br obtaining -the information contained/n
th~.
application, / believe that -the information is
true,
accurate and complete. / am aware that there are -significant penalties for submitting
false information, including thepossibility of fine and imprisonment.
--
A. NAME & OFFICIAL
TITLE.(tvpeorpthlt)
0.
SIGNATURE
C. DATE SIGNED
SUSAN R. LANDAFIL PLANT MANAGER
~
,i~
~/~L(
/0
-
V-
03
COMMENTS FOR OFFICIAL USE ONLY
c
I Il-I
41111-I
I-I-I
4--I--.I-.d.-I-.4.-~I.J.-L
11111111111
III
ii
I
I
lISflAkII
2_I
EPA Form 3510-1 (8-90)
Fomi Approved.
0MB No. 2000-0059 Approval
~
EPA I.D. NUMBER
(copy from Item I of
form
1)
~
FORM
U.S. ENVIRONMENTAL PROTECTION AGENCY
2C
E PA
EXISTING MANUFACTURING.APPLICATION
FORCOMMERCIAL,PERMIT TOMININGDISCHARGEAND
SILVICULTURALWASTEWATER OPERATIONS
NPDES
Consolidated
Permits
Program
I. OUTFALL LOCATION
For each outfall, list the latitude and Ion2itude to the nearest 15 seconds and the name of the receiving water.
A. OUTFALL
B. LATITUDE
LONGITUDE
0. RECEIVING WATER
(name)
NUMBER
~‘11sf~)
1. DEG.
2. MIN.
3. SEC.
1. DEG
2. MIN.
3. SEC.
001
AOl
41
18
38
88
39
58
Illinois River
41
18
-
38
88
39
58
Illinois River
BOl
COl
41-
18
38
68
39
58
Illinois River
41
18
38
88
39
58
Illinois River
DOl
E01
41
18
38
88
39
58
Ilinois River
41
18
38
88
39
58
Ilinois River
-
FOl
GOl
41
18
38
88-
39
58
Ilinois River
-
41
18
38
88
39
58
Ilinois River
H01
101
41
18
38
88
39
58
Ilinois River
41
18
38
88
39
58
lllnois River
002
41
18
40
88
39
46
Illinois River
II. FLOWS, SOURCES OF POLLUTION, AND TREATMENT TE~HNOLOGlES
A.
Attach a line drawing showing the water flow through the facility. Indicate sources of intake water,
operations contributing wastewater to the
effluent, and treatment units labeled to correspond to the more detailed
descriptionsirUtem-B.Qorlstructawateri~a1ance
on the line
drawing
by showingaverage flows
between
intakes, operations, treatment units, and outfalls. If a water balance cannot be determined
(e.g. for certain mining activities),
provide a pictorial description of the nature and amount of any source of water and any collection or
treatment measures
B.
For each outfall, provide a description of: (1) All operations contributing wastewater to the effluent, including process wastewater, sanitary
wastewater, cooling water, and storm water runoff; (2) The average flow contributed by each operation; and (3) The treatment received by
the wastewater. Continue on additional sheets if necessary.
I OUTFALL
NO
(list)
2. OPERATION(S) CONTRIBUTING FLOW
3.
TREATMENT
a. OPERATION
(list,)
b. AVERAGE FLOW
a. DESCRIPTION
b.
LIST
CODES FROM
001
Cooling Pond
Blowdown
(Main Cond. Cooling
34.98 MGD
Evaporative Heat Dissipation,
X-X
Water, Clean Condensate System Flushing
Discharge to Surface Water
4-A
Demineralizer Regenerant Wastes
-
House Service Water, Sewage Treatment
Plant Effluent, Radwaste Treatment System
Effluent, Wastewater Treatment System Effluent,
Auxiliary Reactor Equipment Cooling Water,
OCT 2 9 2flfl~
Reverse Osmosis System Reject Water
Water Softener Renerant Waste
.
Cooling Pond Intake Screen Backwash,
North
-
.
Envmronmcntpl Protectic
WPC--Permjt Lc
i
Agenc
p In
Site Uncontaminated Storm Runoff, South Site
Uncontaminated Storm Runoff).
AOl
Demineralizer Regenerant Wastes
Intermittent
Equilization, Buffering with Circ-
XX
XX
(Make-up Demineralizer Regenerant Waste,
ulating Water or Neutralization,
2-K
Off-Spec Demineralized Water, MU Demin.
Treatment in Wastewater
XX
Maintenance Wastewater, Unit 1
Waterbox
Vacuum Pump Condensate (Lake Water),
Radwaste Treatment Acid/ Caustic System
Drains
BOl
Sewage Treatment Plant Effluent
0.020 MGD
Equalization, Activated Sludge,
X-X
3-A
(Sanitary Wastewater, Eyewash Station Waste-
Sedimentation,
1-U
water)
Sludge to Aerobic Digestion,
5-A
Drying Beds, On-Site Storage
5-H
X-X
OFFICIAL USE ONLY
(effluent guidelines sub-categories)
EPA
Form
3510-2C (Rev. 2-85)
PAGE 1 OF 4
CONTINUE ON
I(t~tI~bt
CONT!NUED FROM THE FRONT
C. except for storm runoff, leaks, or spills, are any of the discharges described in Items Il-A or B intermittent or seasonal?
X
IYES
(comolete the
foiowincs table)
I
INO
(qo
to Section III)
1. OUTFALL
2. OPERATION(s)
CONTRIBUTING FLOW
(list)
-
3.
FREQUENCY~
-
4. FLOW
a. DAYS
PER
WEEK
(specify
b. MONTHS
PER YEAR
(specify
a FLOW RATE
(in
mgd)
~
b. TOTAL VOLUME
(specify
W~t1I
units)
c.
DUR-ATION
i. LONG
TERM
2~
MAXIMUM
1.
LONG
TERM
2. MAXIMUM
(in days)
NUMBER
(l~)
averape)
avera9e)
AVERAGE
DAILY
AVERAGE
DAILY
AOl
Demineralizer Regenerant Wastes
0.047
0.047
1
1
1
E01
FOl
Unit I and 2 Radwaste Treatment System
0.011
0.027
Aux. Reactor Equip. Cooling and Flushing Water
55.58
002
II. River Make-Up Water Intake Screen Backwash
0.432
20
Ill. PRODUC’I ION
A. Does an effluent guideline limitation promulgated by EPA under Section
304 ofthe Clean Water Act apply to your facility?
I
X
IYES
(complete Item Ill-B)
IWO (go
to Section
IV)
B. Are limitations in the applicable effluent guideline expressed
in terms of production (or
othermeasure of operation)?
IYES
(complete Item Ill-C)
I
X
INO
(go to Section IV)
C. If you answered ~yes”to Item Ill-B, list the quantity
which
represents an actual measurement of your level of production, expre
used in the applicable effluent guideline, and
-
indicate1.
AVERAGEthe
affectedDAILYoutfalls.PRODUCTION
a. QUANTITY PER DAY
b. UNITS OF
-
MEASURE
C.
OPERATION. PRODUCT. MATERIAL. ETC.
(specify)
NA
NA
--
NA
IV. IMPROVEMENTS
ssed in terms and units
2. AFFECTED
OUTFALLS
(list
outfall
numbers
NA
A. Are you now required by any Federal, Stateor Local authority to meet any implementation schedule for the
construction, upgrading or operation
of
wastewater treatment equipment or practices orany other environmental programs which may affect the discharges described in this application? This
includes, but is not limited to, permit conditions, administrative or enforcement orders, enforcement compliance schedule letters, stipulations, court
orders, and grant or loan conditions.
___________
-
I
YES
~comøletethe followinq table)
I
X
INO
(~oto Item IV-B)
1. IDENTIFICATION OF
CONDITION,
-
AGREEMENT, ETC.
2. AFFECTED OUTFALLS
3. BRIEF DESCRIPTION OF PROJECT
-
-
4. FINAL COM-
PLIANCE DATE
a. NO.
b. SOURCE OF DISCHARGE
a. RE-QUIREDI
~
NA
NA
NA
NA
NA
B. OPTIONAL: You may wish to attach additional sheets describing any additional water pollution control programs
(or other enwonmentalprojects
which may affect your discharges)
you now have underway or which you plan. Indicate whether each program is now underway or planned, and indicate
your actual or planned schedules for construction.
I
IMARK
~X”IF DESCRIPTION OF ADDITIONAL CONTROL PROGRAMS IS ATTACHED.
EPA Form
3510-2C (Rev. 2-85)
PAGE 2 OF 4
CONTINUE ON PAGE 3
EPA 1.0. NUMBER
(copy from Item I ofform I)
I
FormApproved.
CONTINUED FROM PAGE 2
j
ILDUUu8U~643
expires
.-
12-31-85
~
~
V. INTAKE AND EFFLUENT CHARACTERISTICS
A, B,& C:
See
instructions before proceeding
-
Complete one set of tables for each outfall
-
Annota
NOTE: Tables V-A, V-B, and V-C are included on separate sheets numbered V-l throur~
te the outfall number in the space provided.
h V-9.
D.
Use the space below to list any of the pollutants listed in Table 2c-3 of the instructions, which you know or have reason to believe is
discharged or may be discharged
from any outfall. For every pollutant you list, briefly describe the reasons you believe it to be present and
report
any analytical data in your possession
POLLUTANT
2. SOURCE
1. POLLUTANT
2. SOURCE
NA
NA
NA
.
NA
/l. POTENTIAL DISCHARGES NOT COVERED BY ANALYSIS
Is any pollutant listed in Item
V-C
a substance or a component of a substance
which
you currently use or manufacture as an intermediate or final product
~rbyproduct?
-
-
__________
-
-
-
-
-
-
I
IYES
(11sf all such pollutants below)
I
X
INO
(go to Item VI-B)
-
EPA
Form
3510-2C (Rev.
2-85)
PAGE 3 OF 4
CONTINUE ON REVERSE
CONTINUED FROM THE FRONT
VII. BIOLOGICAL TOXICITY TESTING DATA
~
-
Do you
have
knc’~udge
or
reason
to heiic. tho:
any
b~oio~-caiiuo~~r auuth or ctiIcrn~
to~Jcityhos been mace on any o~you d~sth~gesoi on a
receiving water in relation to your discharge within the last 3 years?
I
IYES
(identify
the test(s) and describe their purposes below)
I
X
INO
(go to Section VIII)
VIII. CONTRACT ANALYSIS INFORMATION
Were any of the analyses reported in Item V performed by a contract laboratory orconsulting firm?
-
I
x
IYES
(list the name, address, and telephone number
of,
and
I
INO
(go to Section
IX)
pollutants
analyzed by, each such laboratory or
fi,m
below)
A. NAME
B~ADDRESS
C. TELEPHONE
(area code & no.)
D. POLLUTANTS ANALYZED
(list)
Test America
IX. CERTIFICATION
850 W. Bartlett Road, Bartlett, IL 60103
(847) 783-4960
All except pH, TRO, Oil & Grease, &
TSS
I
certify
under penalty of law that this document and all attachments were prepared tatdeFmy
direction orsupervisionin
accordance
with a
system
designedto assure that qualified personnel properlygather and evaluate the information submitted. Based on my inquiry of the person orpersons who
manage the system or those persons directly responsible for gathering the information submitted is, to the best of my knowledge and belief, true,
accurate, and complete. lam aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment
forknowing violations.
A~.NAME & OFFICIAL TITLE
(type orprint)
B. PHONE NO.
(area code & no.)
Susan Landahi
I
Station Manager
815-415-3700
C. SIGNATURE
0. DATE SIGNED
,L~u~1&~
,E?
-
/
c
-~
~ p ~
EPA Form 351 O-2C (Rev. 2-85)
PAGE
4 OF 4
Form Approved.
,~
~_~-~.cn
~—,--..,-.I
Please orint or tvoe in the unshaded areas only.
exoires 12-31-85
EPA ID. NUMBER
(copy from Item I of
form
I)
ILL)UUUOUjO4,~
FORM
2C
NPDES
U.S. ENVIRONMENTAL PROTECTION AGENCY
E
PA
EXISTING MANUFACTURING,APPLICATION FORCOMMERCIAL,PERMIT TOMININGDISCHARGEAND SILVICULTURALWASTEWATER OPERATIONS
Consolidated Permits Program
I OUTFALL
NO
(‘lLSt,l
2. OPERATION(S) CONTRIBUTING FLOW
3. TREATMENT
a. OPERATION
~‘list~
b. AVERAGE FLOW
a.
DESCRIPTION
b.
LIST CODES FROM
COl
Wastewater Treatment System Effluent
0.021 MGD
Oil/Water Separation,
X-X
(Turbine Building Fire and Miscellaneous Non-
Equalization, Coagulation,
X-X
2-0
Radioactive Waste Sump, Demineralizer Make-
Flocculation, Sedimentation,
1-G
1-U
up Water Filter Backwash, Diesel Fuel Storage
Multimedia Filtration,
1-Q
and Service Water Building Sump, Auxiliary
Sludge to Drying Beds,
5-H
Boiler Blowdown, Demineralizer Regenerant
On-Site Storage
X-X
::::::~::::~:tion
System Maintenance,
Service
Water System
Maintenance, Domestic Water System
-
-
-~
-.-
OCT 29
~UO3
Maintenance, Clean Condensate System
Maintenance, Laboratory Liquid Wastes,
Environmental Pro~
WPC-—Perm
~ctionA~
Log Ir~
iflC~
Station Heat System Condensate)
001
Cooling Water Intake Screen Backwash
Screening
I-T
(Cooling Pond)
E0l
Unit I and 2 Radwaste Treatment System
Intermittent
Fabric Filtration, Charcoal Filtration X-X
X-X
Effluent (Equipment Drains in the Turbine,
Equalization, Ion Exchange
X-X
2-J
Auxiliary and Reactor Buildings: Floor Drains
Reuse/Recycle of Treated Effluent
4-C
in the Turbine, Radwaste, Auxiliary
and Reactor Buildings:
Condensate Polisher Wastes from the Turbine
Building: Decontamination and LaundryWaste)
FOl
Auxiliary Reactor Equipment Cooling and
Intermittent
Evaporative Heat Dissipation
X-X
Flushing Water
GOl
~
North Site Storm Water Runoff (Fire Protection
Intermittent
Oil/Water Separation
X-X
System Flushing /Maint.,AIt. Route, Service
Sedimentation
1-U
Water System Flushingl Maint. Alt. Route,
.
Domestic Water System Flushing and Maint.
Alt. Route), Clean Condensate System
.
Flushing and Maint. Alt. Route North Site
Uncontaminated Stormwater Runoff)
HOl
South Site Storrnwater Runoff (Fire Protection
Intermittent
Oil/Water Separation
X-X
System Flushing/Maint.,Alt. Route, Service
Sedimentation
1-U
Water System Flushing/Maint. Alt. Route),
Domestic Water System Flushing and Maint.
Alt. Route, Clean Condensate System
Flushing and Maint. Alt.
Route
South Site
Uncontaminated Stormwater Runoff)
OFFICIAL USE ONLY
(effluent guidelines sub-categories)
EPA Form 3510-2C
(Rev.
2-85)
PAGE 1 OF 4 (CONTINUED FROM PA(i~1)
Form Approved.
0MB No. 2000-0059 Approval
Please print or tvoe in the unshaded areas oniy.
expires
12-31-~5
EPA I.D. NUMBER
(copy from Item I of form I)
1LD000803643
FORM
2C
NPDES
I
U.S. ENVIRONMENTAL PROTECTION AGENCY
APPLICATION FOR PERMIT TO DISCHARGE WASTEWATER
-
E PA
I
EXISTING MANUFACTURING, COMMERCIAL, MINING AND SILVICULTURAL OPERATIONS
I
Consolidated Permits Program
1.
OUTFALL
NO
(list)
2. OPERATION(S) CONTRIBUTING FLOW
3. TREATMENT
a. OPERATION (list)
b. AVERAGE FLOW
(include
units)
a. DESCRIPTION
I?. LIST CODES FROM
TABLE 2C-1
101
.
Reverse Osmosis System Reject Water
0.003 MGD
Multimedia Filtration,
1-Q
Reverse Osmosis
1-S
Electrodeionizatiori
X-X
002
Illinois River Make-up Water Intake Screen
Intermittent
Screening
1-T
Backwash
-
OFFICIAL USE ONLY
(effluent guidelines sub-categories)
EPA Form 351U-2( (Rev. 2-85)
PAGE 1 OF 4
~
ur.,.,Lu
r..jJIy,
~
I~
lTErl V-B CONTINUED FROM FRONT
1.O’OLLUTANT
AND CAS
~UMBER
(i1eva~abIe)
2. MARK ‘X’
3. EFFLUENT
.
4.UNITS
5. INTAKE
(oplionaiL
b~~-
LIEVED
PRE.
SENT
~~E-
LIEVED
AS-
SENT
a.
MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE
(itavaflable)
c.LONG TERM AVRG.
d. NO. OF
VALUE
‘~‘pypffatlel
ANAL-
(1)
(2)MASS
YSES
COt~CENTRATION
a. CONCEN
TRATION
b. MASS
~
a. LONG TERM
AVERAGE VALUE
d- N0.OF
AtL~\L.
YSES
CONCENTRATION
(2)MASS
(1)
CONCENTRATION
-
(2)MASS
(1)CONCE~
TRATION
(2)MASS
g.N~vogen.Total
Orgsiic
(as N)
—
X
X
—
0.30
0.028
I
mg/L
lbs/day
~.
h. Ci: and Grease
9
0.826
3.9
0.35800 1
2.4
0.220308
1
mg/L
lbs/day
I. Ph usphorus
(as P),
Total
(772~--14-O)
x
0.32
0.029
1
mg/L
lbs/day
l~~Ioactivity
X
-
(1)Apha,Total
3
1
pCi/L
(2)Eta. Total
X
210.0
-‘
1
pCi/L
(3)Pdium.Total
-
X
9.0
1
pCIIL
—
(4)
P.dium
226.
Totai
x
X
0.3
1
pCi/L
k.Suate(asSO4)
(148(3-79-8)
8
0.734
1
mg/L
lbs/day
l.Su:de(asS)
..
X
x
m.S-:IIte(asSO3)
(1423-46.3)
n.Su—factants
0. Ak- ninum. Total
(~-9O-5)
-
x
0.20
0.018
1
mg/L
lbs/day
-
X
—
X
—
—
0.20
0.018
-
I
mg/L
lbs/day
Banum. Total
(~~39-3)
—
0.20
0.018
1
mg/L
lbs/day
q.Bc-on,Total
(7440 42-8)
X
0.20
0.018
1
mg/L
lbs/day
r.CoL-alt. Total
(744n18-4)
X
X
.
0.040
0.004
1
mg/L
lbs/day
-
strom Total
(743th89-6)
.
1.30
0.119
1
mg/L
lbs/day
t. Ma’ nesium. Total
~Z±~-35-4)
u.Moybdenum.
Total
m7439.98~7)
V.
Maganese. Total
(74~96-5)
X
X
X
X
——
0.55
0.030
-
0.03
-
0.05
0.003
0.003
-
-
~
~
I
1
1
mg/L
mg/L
mg/L
lbs/day
lbs/day
lbs/day
—
w. Tim. Total
(744G-31-5)
1.0
0.092
1
mg/L
lbs/day
x. Tik- mium. Total
(744(32-6)
X
_____________
0.5
_____________
0.046
_____________
_____________
_____________
_____________
________
1
___________
mg/L
__________
lbs/day
EPA orm 3510-2C (Rev. 2-85)
—
PAGE V-2
-
CONTINUE ON PAGE V-3
x. Tltaniu - , Total
(7440-32
-
EPA For 3510-2C (Rev.
2-85)
ITEM V~JCONTINUED FROM FRONT
I. POLLUTANT
ANL CAS
NUI~BER
(ifatn.Iable)
2. MARK ‘X’
08E-
~-~-
LIEVED
LIEVEO
PRE.
~
SENT
SENT
3. EFFLUENT
-
4.UNITS
a.
MAXIMUM DAILY VALUE
b. MAXIMUM 30 DAY VALUE
c.LONG TERM AVRG.
d. NO. OF a. CONCEN b. MASS
(if aveIabfe)
VALUE’
evateb!e)
ANAL-
TRATION
-
-
(1)
(2)MASS
(1)
(2)MA5S
(1)
(2)MAS5
YSES
-
CONCENTRATION
CONCENTRATION
CONCENTRATION
-
5. INTAKE
~opt~neQ,
a. LONGTERM
d. N ).
OF
AVERAGE VALUE
ANt -
--
(1)C0NcEN-
(2)MASS
~
~
TR.ATION
—
g. Nitrogen, Total
Organic(~sN)
X
X
—
0.50
0.059
-
-
I
mg/L
lbslday
h. Oil and Grease
7,7
0.905
5.3
0.622885
2.7
0.318298
12
mgIL
lbs/day
I.Phosph-irus(asP),Total
(7723-14--))
X
0.10
0.012
-
mg/L
lbs/day
RadIoa~ivity
—
(1)Alpha,Total
X
-
7.4
1
pCi/L
(2)Beta, -otat
)(
19.0
-
-~
1
pCIIL
(3)
Radiu ~. Total
X
X
4.1
1
pCi/L
-
(4)
Radiui 226,
Total
x
X
2.6
1
pCi/L
k. Sulfate
(as SO4)
(14808-7~-8)
152
-
17.9
1
mg/L
lbs/day
I. Sulfide (as S)
-
m.
Sulfite
(as SO3)
(14266-4~--3)
—
X
x
-
~_________
n. Surfac:jnts
0.03
0.004
1
mg/L
lbs/day
o.Alumfr-~m,Total
(7429-90-5)
X
X
X
X
X
—
0.1
0.012
I
mg/L
lbs/day
~.
Baiiurn
Total
(7440-39-i)
0.03
0.004
1
mg/L
-
lbs/day
q. Boron. Total
(7440-42
l)
0.28
0.033
1
mg/L
lbs/day
r. Cobalt. Total
(7440.48)
0.020
0.002
1
mg/L
lbs/day
S. Iron,
(7439-89-n)
0.10
0.012
1
mg/L
lbs/day
t.Magne~um,Total
(7439-95---~)
u.Mol~’bd~num,
Total (74m3-98-7)
X
—
X
X
X
—
27.1
--
3.18
I
--________
mg/L
lbs/day
-
0.020
0.002
-
-I
-
mg/L
lbs/day
V. Manga ase. Total
(7439-96-4
w.
Tin, Tm -~t
0.01
-2.0
0.001
0.235
1
1
mg/L
mg/L
lbs/day
(7440-31-9
lbs/day
0.020
0.002
1
mg/L
lbs/day
PAGE V-2
CONTINUE ON PAGE V-3
ITEM V-o CONTINUED FROM FRONT
1. POLl. UTANT
AND CAS
-
NUP~-3ER
(ifav~~.7abie)
2. MARK ‘X’
~-
~
LIEVED
SENT
SENT
—
—
X
—
X
3. EFFLUENT
a.
MAXIMUM
DAILY VALUE b. MAXIMUM 30 DAY VALUE
c.LONG TERM AVRG.
d. NO. OF
(ifaveable)
VALUE
‘~,pjeWp)
ANAL-
(2)MAS5
11)
(2)MASS
(1)
(2)MASS
-
YSES
CONCENTRATION
CONCENTRATION
CONCENTRATION
4.UNITS
-
a. CONCEN b. MASS
TRATION
-
-
-
5. INTAKE
(optioneQ
a. LONG TERM
d.
N~.OF
AVERAG ~VALUE AN/n
-
(1)CO~~
(2)MASS
YSE
TRATION
9.NitrogemkTotal
1.87
0.225
- - I
mg/L -
lbs/day
—-
h. Oil
and Grease
5
0.602
1
mg/L
lbs/day
(as P),
Total
x
5.28
0.635
1
mg/L
lbs/day
).
Radloamnvity
(1)Alpha, lotal
X
3
1
pCi/L
— -~
(2)
Beta, otal
X
36.0
-
I
pCi/L
(3)Radlumn,
Total
X
1.2
1
pCi/L
(4)
Radlu
226,
Total
X
0.4
-
I
.
pCI/L
k. Sulfate
as SO4)
X
212
25.5
1
mg/L
lbs/day
I.Sulfide~sS)
m.Sulfite
~sSO3)
(14266.41
3)
Surfacl nts
X
-
-
X
0.03
0.004
1
mg/L
lbs/day
-
~Aiumh-mnn.Total
x
0.10
0.012
I
mg/L
lbs/day
Total
x
0.02
0.002
1
mg/L
lbs/day
q.Boror~otal
X
0.31
0.037
1
mg/L
lbs/day
~,l~)tal
X
0.02
0.002
1
mg/L
lbs/day
X
0.11
0.013
1
mg/L
lbs/day
t.Magnesr~m,Total
x
34.9
--
4.20
-- I
mg/L
lbs/day
Totai(74~-98.7)
X
-
0.020
0.002
-
I
mg/L
lbs/day
n~~se.Total
X
0.06
0.008
I
mg/L
lbs/day
X
2.0
0.241
I
mg/L
lbs/day
-
x.Tltankjr. Total
x
0.020
0.002
I
mg/L
lbs/day
EPA Forn 3510-2C (Rev. 2-85)
-
PAGE V.2
CONTINUE ON PAGEV.3
x.
Titanim.
Total
(7440-3T -6)
EPA Fo~n3510-2C (Rev.
2-85)
ITEM
V-B
CONTINUED FROM FRONT
1. POLLUTANT
A~m)CAS
NUMBER
(if
a
,aieble,l
2. MARK ‘X’
b. RE-
C. RE-
UEVEO LIEVED
SENT
SENT
3. EFFLUENT
-
a.
MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE
c.LONGTERM AVRG.
d.
NO. OF
)‘ifava~fable~l
VAWE
‘~pyp~pble)
ANAL-
~
(2)
MASS
(1) -
(2)
MASS
(1)
(2)
MASS
YSES
CONCENTRATION
CONCENTRATION
CONCENTRATION
4.UNITS
a. CONCEN b. MASS
TRATION
-
-
-
-
--
-
5. INTAKE
(option8l)
a. LONG TERM
d. ‘IC. OF
AVERP~~VAWE A~mL-
(1)
CONCEN.
(2)
MASS
Y~S
TRATION
~Nltro~n,T~tat
X
0.40
0.157
1
mg/L
lbs/day
—
h.Oilar-I Grease
X
1
0.392
4
mgIL
lbs/day
LPhosp~orus(asP),TotaI
X
0.03
0.012
I
mg/L
lbs/day
l.
Radio--ntivity
(1)AIph, Total
X
3.00
1
pCi/L
(2)
Beta. Total
X
5.00
-
I
pCi/L
(3)Radirn,Total
X
2.20
-
I
pCWL
(4)Radi-rn 226,
Total
k.SuIIa (as
SOS)
I. Sulfide
(as
5)
y
‘
.
~n
i
.
p
I
X
X
680
266.7
-
I
mg/L
lbs/day
m. Sulfe.
(as
SO3)
(14266— s-3)
x
n. Surfa,ants
X
0.07
0.027
1
mg/L
lbs/day
o.AIumkurn,Total
p. Barb
Total
-
q.Boron Total
r.Cobah. Total
X
x
0.3
0.1
0.118
0.039
1
I
mg/L
mg/L
lbs/day
lbs/day
0.31
0.122
I
mg/L
lbs/day
—
X
0.05
0.020
1
mg/L
lbs/day
I
x
0.82
0.322
1
mg/L
lbs/day
LMagnJum, Total
x
15.4
--
6.040
I
-
mg/L
lbs/day
X
0.2
0.078
-
I
mg/L
lbs/day
V.
M8n9nese. Total
0.003
o.oo-~
-i
mg/L
lbs/day
w.Tln,T-jlal
X
0.8
0.314
1
mg/L
lbs/day
—.
—
0.8
0.314
I
mg/L
lbs/day
PAGE V-2
CONTINUE ON PAGE V.3
ITEM V-E CONTINUED FROM FRONT
1. POLUTANT
AND CAS
NUN .3ER
(ifeva--able)
2. MARK ‘X’
3. EFFLUENT
4.UNITS
5. INTAKE
~opfonaQ
=
a. LONG TERM
d. NO. -~F
- AVERAGE VALUE
ANAL-
(1)CONCEN-
(2)MA5S
YSES
TRATION
—
—
LIEVED
SENT
LIEVEO
SENT
a. MAXIMUM DAILY VALUE b.
MAXIMUM 30 DAY VALUE
(ifaveiable)
c.LONG
TERM AVRG.
VALUE
üf8va~ob1eI
-
d. NO. OF
a. CONCEN
ANAL-
TRATION
YSES
-
--
--
b. MASS
-
-
-
-
-
II)
CONCENTRATION
(2)MA5S
Ii)
CONCENTRATION
I2)MASS
Ii)
CONCENTRATION
(2)MASS
-
~Nltroge~ Total
X
0.69
272
1
-
-
mgIL
lbs/day
h.
Oiland Grease
X
5
1971
1
mg/L
lbs/day
I.
Phosphcus
(as P),
Total
(7723-14-~4
X
0.7
288
1
mg/L
lbs/day
j._Radtoac-vity
—
—
(1)Alpha.(otal
X
3
I
pCi/L
(2)Beta. )tal
X
15.7
1
pCi/L
-
(3)Radlun., Total
(4) Radiur 226,
Total
l.SuIfide1sS)
X
0.8
1
pCi/L
x
0 . 1
~I
-
X
94
37052
1
mg/L
lbs/day
X
m. Sulfite
ms SO3)
(14266-4L- 3)
n. Surfact. ~ts
o.Aiumffm. n~Total
p.
Barium
Total
X
0.03
12
1
mg/L
lbs/day
x
x
0.360
142
1
mg/L
lbs/day
0.028
11.0
1
mg/L
lbs/day
q. Boron. -ntal
x
0.235
93
1
mg/L
lbs/day
r.Cobaft, jlal
x
0.020
7.9
-
1
mg/L
lbs/day
—
S.IrOfl, Tc1,i
-
X
0.540
213
1
mg/L
lb~/day
—~
tMagnes~-rn,Total
Total(743--98-7)
x
X
21.5
0.020
--8475
7.9
--
I
I
mg/L
mg/L
lbs/day
lbs/day
V.
Mangerse. Total
X
0.031
12
1
mg/L
lbs/day
w Tir To. I
2.0
788
1
mg/L
lbs/day
x.Tltanlun
Total
x
0.02
8
1
mg/L
lbs/day
,
EPA
Fon3- 3510-2C
(Rev. 2-85)
PAGEV.2
CONTINUE ON PAGE
V-.,