1. May 29, 2003
    1. RECEIVED
      1. SERVICE LIST
      2. BEFORE THE ILLINOIS POLLUTION CONTROL BOARD
      3. I. PROCEDURAL HISTORY
      4. II. 35 ILL. ADM. Code Section 104.406
      5. A. Standard From Which Relief Is Sought (Section 104.406(a))
      6. B. Nature of Regulation of General Applicability (Section 104.406(b))
      7. F. Proposed Adjusted Standard (35 JAC 104.406(1))
      8. G. The Quantitative and Qualitative Impact of CROMWELL’S Activity (35
      9. IAC 104.406(g))
      10. H. Justification (Section 104.406(h))
      11. K. Supporting Documents (Section 104.406(k))
      12. Ill. SECTION 28.1(C) FACTORS
      13. A. The Factors Relating To CROMWELL Are Substantially and Significantly
      14. Different
      15. Impact or Health Effect
      16. May 29, 2003
      17. EXHIBIT A
  1. Reasonably Available Control
      1. C-PRACT Cost Analysis.xls 5/16/2003
      2. C-PRACT Cost Ana!ysis.xls 5/16/2003
      3. C-PRACT Cost Analysis.xls 5/16/2003
      4. C-P RACT Cost Analysis.xls 5/16/2003
      5. C-PRACT Cost Analysis.xls 5/16/2003
      6. C-PRACT Cost Analysis.xls 5/16/2003
      7. C-PRACT Cost Analysis.xls 5/16/2003
      8. C-PRACT Cost Analysis.xls 5/16/2003
      9. C-PRACT Cost Analysis.xls 5/16/2003
      10. 5/16/2003 C-P RACT Cost Analysis.xls
      11. C-P RACT Cost Analysis.xls 5/16/2003
      12. C-P RACT Cost Analysis.xls 5/16/2003
    1. IIUIHX2L
  2. TRADE SECRET
      1. AFFIDAVIT OF FRANCIS HOULIHAN IN SUPPORT
      2. OF CROMWELL-PHOENIX, INC.’S
      3. PETITION FOR AN ADJUSTED STANDARD

LER~(’c
flflrr~
BEFORE THE
ILLINOIS POLLUTION CONTROL BOAJA
~ 2 ~
2093
STATE OF
Con
trt~J
~
AS
03’
)
(Adjusted Standard-Air)
IN THE MATTER OF:
PETITION OF CROMWELL-PHOENIX,
INC.
FOR AN ADJUSTED
STANDARD FROM 35
III. Adm.
Code Subpart F, Section 218.204
(c)
(the “Paper Coating Rule”)
To:
See Attached
Service List
)
)
)
NOTICE OF FILING
PLEASE TAKE NOTICE that
I have today filed with the Office ofthe
Clerk of the
Illinois
Pollution Control Board the PETITION
FOR ADJUSTED STANDARD OF
CROMWELL-PHOENIX, INC., and APPEARANCE OF QUARLES &
BRADY, copies of
which are herewith served upon you.
PROOF OF SERVICE
1, the undersigned,
on oath state that I have served the attached
PETITION FOR
ADJUSTED STANDARD OF CROMWELL-PHOENIX,
INC.
and APPEARANCE by
U.S. Mail
upon the persons listed on the attached service list this
29th
day ofMay, 2003.
$1~r~~/flv
~
~frine
M. Landow-Esser
Janine M. Landow-Esser
Monica M.
Tynan
QUARLES & BRADY LLC
500 W. Madison Street, Suite 3700
Chicago, Illinois 60661
312.715.5055
This filing
is submitted on recycled paper.
~ser,Attorney
May 29, 2003
QBCH!\307772.
I

RECEIVED
CLERR’~
OFFICF.
BEFORE THE ILLINOIS POLLUTION CONTROL BOARD
MAY
292003
STATE OF
ILLINOIS
Pollution
Contra! Board
IN
THE MATTER OF:
)
)
AS
______
PETITION OF CROMWELL-PHOENIX,
INC.
)
(Adjusted Standard-Air)
FOR AN ADJUSTED STANDARD FROM
35
)
Ill.
Adin, Code Subpart F, Section 218.204 (c)
)
(the “Paper Coating Rule”)
)
APPEARANCE
Quarles & Brady
LLC
by its
attorneys, Janine M. Landow-Esser and Monica Tynan,
hereby files its
APPEARANCE in this proceeding, on behalfofCromwell-Phoenix, Inc.
Mrnne M. Lando’I-Esser
May 29, 2003
Janine M. Landow-Esser
Monica Tynan
QUARLES
& BRADY LLC
500 W. Madison
Street
Suite 3700
Chicago, Illinois 60661
312.715.5055
This filing
is submitted on recycled paper.
Qnc,-1h307740. i

SERVICE LIST
Illinois Pollution Control Board
James R. Thompson Center
Suite 11-500
100 West Randolph Street
Chicago, Illinois 60601
David BloonTherg
Air Quality Planning Section
MC39
Illinois
Environmental Protection Agency
1021 North Grand Avenue East
Springfield, IL 62794
Bureau of Air
Illinois Environmental Protection Agency
1021
North Grand Avenue East
Springfield, Illinois 62794
Division of Legal Counsel
Illinois Environmental Protection Agency
1021
North Grand Avenue East
Springfield,
Illinois 62794-9276
Qi3CHI\338463.1
This filing is submitted
on recycled
paper

RECEIVED
TRADE
SECRET
CLERKS OFFICE
(st~
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CONFIDENTIAL
___
_____________
BEFORE THE ILLINOIS
POLLUTION CONTROL BOARD
IN THE MATTER OF:
)
AS
____
Petition of Cromwell-Phoenix, Inc.
)
(Adjusted Standard)
for an Adjusted Standard from 35
)
Ill. Adm. Code Subpart F, Section
2 18.204 (c)
)
(the “Paper Coating
Rule”)
)
PETITION
FOR
ADJUSTED STANDARD
CROMWELL-PHOENIX,
Inc.
(“CROMWELL”),
through
its
attorneys,
Quarks
&
Brady
LLC,
pursuant
to
35
III. Adm.
Code
Subpart
ft
Section
104.400
et
seq., and
Section
28.1
of the Illinois
Environmental Protection
Act,
415
ILCS
5/28.1
(the “Act”), respectfully
submits
this
Petition
for
Adjusted
Standard
(“Petition”)
to
the
Illinois
Pollution
Control
Board
(the
“Board”)
seeking
an
adjusted
standard from the VOM
content
Limitations of
35111. Adm.
Code
Subpart
F
Section
218.204(c)
as
those
rules
apply
to
the
emissions of
volatile
organic
material
(“VOM”)
from
CROMWELL’s
corrosion
inhibiting
(“Cl”)
packaging
materials
production
facility in Alsip, Cook County, Illinois.
I.
PROCEDURAL HISTORY
CROMWELL
began
production
at
its
Alsip
facility
in
early
2001.
Following
an
inspection
by
the
Illinois
Environmental
Protection
Agency
(“IEPA”)
and
an
exchange
of
correspondence,
IEPA
issued
Violation
Notice
A-2001-00265
dated
November
20,
2001.
Among
other
things,
the
Violation
Notice
alleged
that
CROMWELL
had
failed
to
demonstrate
compliance with
the
reasonably available
control
technology (“RACT”) emission limitations
set
forth
in 35111. Adm.
Code 218, Subpart F,
applicable to paper coating operations.
338419.1
This
filing is submitted
on
rccyclcd
paper

CROMWELL
held
telephonic
meetings
with
representatives
of
the
Illinois
Environmental
Protection
Agency
(“IEPA”)
to
discuss
the Violation
Notice,
and
submitted
its
Compliance
Commitment
Agreement
to
IEPA
on
February
19,
2002.
The
Compliance
Commitment Agreement explained that the VOM
in
CROMWELL’S
products acts as more than
a mere carrier for active
ingredients.
The VOM acts as a paper softener, improves paper folding
qualities,
dissolves
and
retains
corrosion
inhibitor
compounds
and
facilitates
their
gradual
migration
to
the customer’s
wrapped
metal
parts
over
a prolonged period of time.
Thus
while
CROMWELL
advised
IEPA
that
it
was
attempting
to
find
coating
formulations
that
would
comply
with
the
applicable
RACT
standards,
it
also
advised
that
reformulation
was
likely
to
impair product quality
and
could, because ofthe need to utilize
dryers to
drive off added water,
ironically have
the undesirable
effect
of increasing
emissions of VOM.
CROMWELL
noted,
additionally,
that
because it prints
on
the
majority of its products before
applying
the corrosion
inhibiting
solutions,
its
printing/coating operations
are regulated by
35
Ill.
Adm.
Code
Subpart
H,
Section 218.401
governing printing.
IEPA responded
by
issuing
its
Notice of Intent to
Pursue
Legal
Action
on
March
19,
2002.
CROMWELL
held
another
telephonic
meeting
with
IEPA
and
strongly
urged
that
a
representative of IEPA visit its
facility so
that the agency could
view
first hand the operations
in
question.
Mr.
David
B.
Bloomberg,
a
coatings
specialist
with
IEPA’s
Air
Quality
Plaiming
Section,
visited
the
facility
on
May
9,
2002.
Following
the
facility
visit
and
subsequent
discussions with IEPA, both parties agreedthat CROMWELL would file this Petition.
CROMWELL
submitted
a
Clean
Air
Act
Permit
Program
(“CAAPP”)
application
to
IEPA
on
March
29,
2002.
That application
demonstrates
that
CROMWELL
is
a
true
minor
-9-

source.
CROMWELL has requested that IEPA issue a lifetime air operating permit. The CAAPP
application currently is under review at IEPA.
II.
35 ILL. ADM. Code Section 104.406
A.
Standard
From Which Relief Is Sought (Section 104.406(a))
CROMWELL requests
that
the
Board
grant CROMWELL
an
adjusted
standard
from
35
Ill.
Adm.
Code
Subpart
F,
Section
218.204(c)
(the “Paper Coating
Rule”) as this
rule
applies
to
the
emissions
of
VOM
from
CROMWELL’S
operations
in
Alsip,
Cook
County,
Illinois.
These rules became effective on August
16,
1991.
The Paper
Coating
Rule
from
which
CROMWELL
seeks and
adjusted standard
requires paper coaters
to
utilize coating
materials containing no more than
2.3
pounds of VOM
per
gallon of coating
applied
(excluding
water).
In
the
alternative,
the
source
may
utilize
a
capture
system
and
control device which
achieves
an
81
reduction
in the
overall
emissions of
VOM
from
the coating line,
and
a
90
reduction
of the captured
VOM emissions,
or achieve
VOM reductions that are equivalent to the limitations
of 35
IAC 2 18.204.
See 35
Ill.
Adm.
Code
Subpart F,
Section
2 18.207.
As will be demonstrated herein, CROMWELL cannot use compliant coatings, and
the approved control technologies will work only at unreasonable costs
and
with nominal
VOM
reduction
benefit;
as such, they are not RACT for CROMWELL.
B.
Nature of Regulation
of General Applicability (Section 104.406(b))
The
regulations
from
which
CROMWELL
seeks
an
adjusted
standard
were
among those promulgated
to
implement Section
182(d) of the Clean Air Act,
42
U.S.C.
7401
et
seq.
which,
among
other things,
requires
individual
states
with
severe
ozone
non-attainment
areas
to
adopt RACT
regulations
applicable
to
sources of VOM within the non-attainment area.
-3-

As mandated by the Clean Air Act, the Board
established the requirements described in the Paper
Coating Rule.
The
Chicago-area severe
ozone non-attainment
area includes
sources located
in
Cook,
DuPage,
Kane,
Lake,
and Will
counties, Oswego
Township
in
Kendall County,
and
Aux
Sable and
Goose
Lake Townships in
Grundy County.
CROMWELL is
located
in
Cook
County
which is part of the Chicago-area designated severe ozone
non-attainment area.
CROMWELL is a minor source and is seeking a lifetime air operating permit.
C.
Level ofJustification (Section 104.406(c))
The
regulations
of
general
applicability
from
which
CROMWELL
seeks
an
adjusted standard
do not specify a level ofjustification for
an adjusted standard.
D.
Facility and Process Description (Section 104.406(d))
1.
General Information
CROMWELL
is
an
Illinois
corporation
located
in
Alsip,
Cook
County,
Illinois.
CROMWELL employs
31
people and operates in
a
98,000 square
foot building.
The building was constructed
in
1965;
CROMWELL began operations
in
the building in
early
2001,
CROMWELL’S equipment
is
approximately
40
years
old.
CROMWELL
believes
that
it
is
the
only
manufacturer of corrosion
inhibiting
packaging
materials
in
Illinois.
2.
Process Description
CROMWELL
produces
corrosion
inhibiting
packaging
materials
by
-4-

In most
cases
various
images
are printed on
the kraft paper
prior to
the
application
of
the
CI
solutions.
These
images
include
the
CROMWELL
logo,
lot
number, product usage
instructions,
and graduated
lines for measurement purposes.
The
images
are
applied
using
an
in-line
flexographic
printing
cylinder
and
water
based
tiexographic inks.
3.
~issions
The
only
emissions
of
regulated
pollutants
from
the
production
of
the
corrosion inhibiting packaging materials are the relatively low emissions of VOM.
None
of the
VOM
compounds
used
are
defined
as
Hazardous
Air
Pollutants
under
Section
112(b) of the Clean Air Act.
CROMWELL selects the impregnation coating and
carrier
constituents
based upon
their ability
to be
retained
in the product for a prolonged period
-5-

of time.
Therefore, the emissions of VOM are
very
low
by design.
Low vapor
pressure
VOM carrier compounds
are utilized,
and the finished packaging material
is rewound on
a
cylindrical
core
immediately
after
the
solutions
are
applied,
thereby
physically
encapsulating
the product
and
further
impeding
the
volatilization of the
liquid
fraction
components.
In
addition,
the
vast
majority
of
the
packaging
products
are
produced
without
using
dryers.
Less
than
10
of CROMWELL’S
products
require
the use
of
infra-red
(“IR”)
dryers.
IR
drying
is
required
when
the
CI
solution
contains
a
greater
percentage of water.
The
excess
water must
be
driven off using
the IR
dryers.
It
is
important
to
note
that
since
both
water and
VOM will
be
driven off concurrently,
VOM
emissions
will increase
as the amount
of drying that
is
required increases.
Gravimetric
tests
have
been
performed
to
determine
the
weight
loss
and
emissions
from
the
CI
packaging production processes,
including storage.
In the most
recent tests,
the weight of
the
virgin
paper
used.
CI
solution
applied,
and
the
final
products
produced
were
determined over
periods
that represent their
typical holding
times
in
the CROMWELL
facility.
The gravimetric data demonstrate that the overall
VOM emissions
are less
than
5
of the weight
of CI
solution
applied.
This
emission
factor
assumes that
the
VOM losses are proportional to their composition in the liquid fraction of the CI solution.
In fact, the water will likely preferentially volatilize relative to
the VOM components due
to its
higher vapor pressure.
Therefore, the VOM emission factors usedby CROMWELL
can be
considered worst case.
It is clear that the VOM emissions
from the CI solution are
very low due to
their low volatility
and their effective retention in the paper substrate.
-6-

Based
on
these
emission
factors,
total
VOM
emissions
from
the
CROMWELL facility were no more than approximately
5
to 6
tons per year for calendar
years 2001
and 2002.
Typical hours of operation are approximately 2900 hours per year.
Projecting operations
to
8760 hours per
year,
and
continuous
full
web width
maximum
operation of all
production units,
potential
emissions
from
the
facility are
less
than
25
tons
per
year,
including
ancillary
mixing
and
handling
operations.
Therefore,
the
CROMWELL facility is
a simple minor source.
CROMWELL
has
been
working
on
Cl
solution
reformulations
in
an
attempt
to
reduce
the
as-applied
VOM
content
(less
water)
to
as
great
a
degree
as
practicable,
while
still
providing
sufficient
solids
dissolution,
retention,
and
migration.
However, as the amount of water in
the solutions is
increased,
so does the need to
utilize
the IR
dryers
to
drive offthe excess water.
Along with the increased
evolution of water
will
be
an
associated
proportionate
increase
in
VOM
emissions
for
the
equivalent CI
product produced. This
is counterproductive to the goal ofVOM emissions reduction.
4.
Pollution Control Equipment
CROMWELL does not employ the use of any pollution control equipment
in its operations.
5.
Permit Status
At the request of
IEPA, CROMWELL submitted a Clean Air Act
Permit
Program
(“CAAPP”)
application
on
March 29,
2002.
Although
a
CAAPP application
was submitted,
CROMWELL
is a minor source.
Accordingly,
in its CAAPP application
CROMWELL
requested
that
a
lifetime
air
operating
permit
be
issued
for
the
CROMWELL facility.
The
CAAPP
application
is
under
review
within IEPA.
During
-7-

the
course
of
discussions
between
IEPA
and
CROMWELL
concerning
the
CAAPP
application
and Notice of Violation A-2001 -00265, IEPA and
CROMWELL
agreed that
CROMWELL should
submit
this
Petition
for Adjusted
Standard.
It
is
CROMWELL’s
understanding that
its air operating permit will be
issued upon the Board’s issuance of its
Opinion and Order on this
Petition.
6.
General Description of the Local
Non-Attainment Area
CROMWELL
is
located
in
an
industrial
area
in
Alsip,
Illinois
on
Ridgeway
Avenue.
The nearest school
or residential area is
approximately
I
mile
from
the CROMWELL facility.
The city ofAlsip
is
located in
Cook County, Illinois,
which is
part of the Greater Chicagoland
Severe-17 Ozone
non-attainment area designated under
40 CFR
81.314, as defined by USEPA pursuant to
Section
107 ofthe Clean Air Act.
E.
Cost of Compliance and Compliance Alternatives (35 IAC 104.406(e))
Achieving compliance with the applicable limitations of 35
IAC Part 218
Subpart
F requires that either the VOM content ofthe CI Solutions
be reduced, or that add-on
controls be
applied.
The
technical
and
economic
feasibility
of these
two
options
for
the
CI
packaging
production operations
at CROMWELL are discussed below.
I.
CROMWELL’s Operations Were Not Contemplated by Applicable Rules
Achieving the VOM content
levels
in
the CI coatings that are called for in
the
applicable
section
of
35
IAC
Part
218
Subpart
F
(35
IAC
2 18.204(c))
is
not
practicable for functional, environmental, and economic reasons.
Unlike
conventional coating operations, where
VOM solvents
are used as
carriers
of
pigments
and
other
solids,
and
the
VOM
solvents
are
intended
to
be
evaporated, the VOM components in CROMWELL’S
CI solutions
are intended to remain
-8-

in
the
CI
packaging
products
in
order
to
perform
their
essential
corrosion
inhibiting
functions.
As
such,
CROMWELL
has
inherent
economic
and
product
performance
incentives
to
ensure
that
the
VOM
components
are
retained
in
the
product
and
not
emitted.
Therefore,
the high
molecular weight,
low
volatility VOM components in the CI
Solutions
are
selected
by
CROMWELL
to
enhance retention
in
the product,
and
not
be
emitted, by design.
It
is
important
to
note that
the
35
IAC
Part
218
Subpart
F paper coating
standards
are
based
on
the
Control
Techniques
Guideline
(CTG)
titled
“Control
of
Volatile
Organic
Emissions
from
Existing
Stationary
Sources
Volume
II:
Surface
Coating
of Cans,
Coils,
Paper,
Fabric,
Automobiles
&
Light
Duty
Trucks” dated
May
1977
(EPA-450/2-77-008).
In Section
5.0 of this
document (Paper Coating),
it describes
the paper coating process as follows (Page
5-1):
“In organic solvent paper coating, resins
are dissolved
in
an
organic
solvent or
solvent mixture
and
this
solution
is
applied
to
a
web
(continuous roll)
of paper.
As the coated web is
dried,
the solvent evaporates and
(lie coating cures.”
(Emphasis
added).
Clearly,
for conventional coaters, the purpose of
the
solvent is to
act
as
a carrier
for the pigments
and resins.
In such a case the intent is
for
the
solvent
to
be
evaporated,
leaving
the
solids
to
dry
and/or
cure
as
the
surface
coating
on
the
paper
substrate.
In
the
case
of
CROMWELL,
the
liquid
organic
components
are
intended
to
be
impregnated
into
and
remain
with
the
paper product.
They are intended to
become an integral
component ofthe product.
This
type ofproduct
clearly was
not contemplated at the time the CTG for paper coating was developed.
Further, on page
5-13 of the paper coating CTG,
it describes how the vast
majority of solvents
used in conventional paper coating operations are evolved during the
-9-

application,
drying,
and
curing
steps.
“Many
plants
report
that
96
percent of solvent
introduced
to
the coating
line
is recovered.
Part of the solvent remains with the finished
product
after it
has
cured
in
the
oven.
Some
coaters
estimate that
2
or
3
percent
of
solvent
remains
in
the
product.”
This
again
differentiates
the
conventional
coating
operations
contemplated
by
the
paper
coating
CTG
from
the
type
of
CI
packaging
production operation at CROMWELL.
CROMWELL applies the CI solution to
the kraft
paper substrate
with
the
intent
that
the
vast
majority of the CI
solution constituents
will
remain in
and
become
an
integral part of the
final product.
While
conventional coating
operations drive off96 percent or more ofthe solvent applied, the CI packaging materials
produced by
CROMWELL
retain
over
95
of
the organic
liquids applied,
since these
organic
liquid
components
are
an
integral
part
of
the
product.
It
is
clear
that
CROMWELL’S type of operation
and
their products were
not
contemplated
in the
CTG
for the paper coating industry.
It is
important to understand that the presence ofthe VOM components in
the
CI
solutions
and
CI
products
provides
an
essential
corrosion
inhibiting
function.
These VOM components are themselves corrosion
inhibiting,
and they serve to
facilitate
the
gradual
migration
of other corrosion
inhibiting
solids
present
in
the
CI
packaging
products onto the customer’s wrapped metal parts over
a prolonged period oftime.
In
addition,
it
is
undesirable
for
the
CI
products
manufactured
by
CROMWELL
to
contain
excess
water,
as
the
presence
of residual
water
in
the
CI
products
promotes
corrosion.
Excess
water
also
causes
unacceptable
expansion
of the
paper
fibers
resulting
in
the product
becoming
wrinkled
and
welted,
as well as
the cut
sheets
becoming
curled.
This
makes
the
products
very
difficult
to
handle
by
-
10-

CROMWELL
personnel
and
their customers,
and
results
in
the
inability
to
achieve
a
good
wrap on
the
metal
items
that
are being protected
by
the
CI
papers.
Therefore,
if
additional
water was utilized
in lieu of some of the VOM components
in the
CI
solution,
additional
supplemental heated
drying operations would be required
in
order to
drive off
the
excess
water.
Not
only
would
additional
energy
be
consumed
in
doing
this,
but
additional VOM would be
evolved in the process.
The VOM would evaporate
along with
the
excess
water,
thus
increasing
the
net
overall
emissions
from
the
facility.
CROMWELL asserts that this would result in
a detriment to
the environment,
and would
negatively impact the economic viability ofthe CI production operations.
A projection of VOM emissions
changes
was made
in
order
to
approximate
the
emissions impact
resulting
from
a reformulation of the
CI
solutions
to
the 2.3
lbs
VOM
per gallon
level
required under
35
IAC
218.204(c).
The emissions
projection was
based
on
an
extrapolation of the VOM emissions
factor established
at the current CI
solution
VOM
contents,
vapor
pressures
and
ambient
operating
conditions,
and
applying
the
increased
constituent
vapor
pressures
at
the
elevated
temperatures,
and
the
decreased
VOM contents ofthe CI
solutions.
Based on heating the substrate
to a minimum of 54°C
(129°F),the VOM emissions of the reformulated
CI solutions are projected
to increase by
a
factor of approximately
7.8
times
above
that of the current
formulations.
In such
a
case, annual VOM emissions would
increase from the current
5
or
6 tons per year,
up to
approximately
39
tons per year, or higher.
Actual substrate temperatures will likely need
to
be
considerably
higher than
54°C,probably
in
excess of 65°C (150°F),in
order
to
sufficiently drive off the excess water.
Therefore, VOM emissions would
accordingly be
even
higher.
Again,
it
is
important
to
emphasize
that
the
intent
of the
CI
solution
-11-

impregnation
process
is
to
retain
the
VOM
constituents
in
the
substrate.
The
use
of
elevated process temperatures
is counterproductive
to this goal.
2.
Add-On Controls Are Not Economically Reasonable
CROMWELL’S
consultant,
ERM,
Inc.,
analyzed
the
technical
and
economic feasibility
of the application of add-on
control
devices to
CROMWELL’S
CI
coating
operations.
See
Reasonably Available Control
Technology
(“RACT”) Analysis
by ERM,
Inc.
at Exhibit A attached hereto.
The technically feasible control options were
determined
to be oxidation and a combination carbon adsorption/oxidation system.
As
can be
seen
in
the RACT
analysis
in
Exhibit
A, the
costs of installing
add-on oxidation or carbon adsorption/oxidation controls at CROMWELL are excessive.
Table
2 of Exhibit A summarizes the annualized costs
associated with the application of
these control technologies.
The annual cost per ton of VOM controlled for each of these
options ranges from
approximately
$25,000
to
$70,000.
This
is well above the level that
would
be considered reasonable under
a
conventional RACT demonstration.
Also, these
costs
do not
consider the costs
associated with
compliance demonstration
testing,
which
likely
would
be
on
the
order
of $40,000
to
$50,000.
In addition,
while the annualized
costs
are themselves
excessive, the initial capital outlay would also be prohibitive and the
ongoing
annual
cost
of the controls
would
be
on
the
order
of $375,000
to
$560,000.
These
costs
are clearly excessive,
given
that
the
actual
level
of VOM emissions
to
be
controlled is on the order of 5
or 6 tons per year.
F.
Proposed Adjusted Standard (35 JAC
104.406(1))
CROMWELL
proposes
the
following
adjusted
standard
for
adoption
by
the
Board:
-
12-

CROMWELL
may
continue
to
operate
its
corrosion
inhibiting
packaging
materials production operations as long as:
1.
The total
actual
VOM emissions
from
the CROMWELL
facility do
not
exceed 25 tpy.
2.
The
Versil
Pak
wax
laminating
coatings continue
to
meet
the applicable
VOM content limitations under
35
IAC Part 218
Subpart F.
3.
The
web
fed
and
sheet
fed
Cl
coating
and
printing
lines
use
only
Corrosion
Inhibiting
solutions
whose
as-applied
VOM
contents do
not
exceed
8.3
lbs
VOM per gallon,
less water.
4.
CROMWELL shall
operate
in
full
compliance
with
all
other
applicable
provisions of 35
IAC Part 218
Subpart F.
5.
CROMWELL shall
continue
to
investigate viable
reduced
VOM content
CI
coatings
and,
where
practicable,
shall
substitute
such
coatings
as
long
as
such
substitution
does
not
result
in
a
net
increase
in
VOM
emissions.
An
annual
report
summarizing the activities
and
results
of these investigatory
efforts
will be
prepared by
CROMWELL and submitted to the IEPA.
6.
CROMWELL shall operate in full compliance with the Clean Air Act.
7.
CROMWELL shall continue to report all annual emissions
to
the IEPA.
-
13
-

G.
The
Quantitative
and
Qualitative
Impact
of
CROMWELL’S
Activity
(35
IAC 104.406(g))
Due
to
the
nature
of
the
VOM
components
used
in
the
CI
solutions
at
CROMWELL,
less
than
5
tons
of actual
VOM per
year
are
emitted
from
that
portion of their
production operations.
Approximately
5
to
6 tons
per year ofactual VOM are typically
emitted
from
the entire
plant,
including
the Versil
Pak
wax laminating
operations.
This
is
a relatively
small contribution
to
the
local
air shed
when compared to
the hundreds of thousands
of tons of
VOM emitted each year in the Chicagoland Nonattainment Area.
In addition, if CROMWELL were to
attempt to
utilize reduced VOM content CI
coatings,
VOM
emissions
would
actually
increase.
As
previously
described,
if water
were
utilized
in
the
CI
solutions
in
lieu
of some of the VOM components,
additional
supplemental
heated drying would be
required
in order
to
drive off the
excess
water.
This
would result
in
an
increase
in
VOM
emissions
for
the
same
product
produced,
since
there
would
be
additional
VOM
driven
off
along
with
the
excess
water.
Also,
there
would
be
additional
energy
consumption required to perform the increased supplemental drying.
As described in Exhibit
A at page 9, if the most economical add-on controls were
applied
to
the
CI
coating
operations
at CROMWELL, the associated
energy
and
environmental
impacts would
be
substantial
in
comparison
to
the
small
net reduction
in
VOM
emissions.
In
order
to
control
the
15.21
tons
per
year
of potential
VOM
emissions
from
the
CI
coating
operations,
approximately
13.5
million
cubic
feet
of natural
gas
will
be
burned,
resulting
in
emissions of over 800
tons of CO2
(a greenhouse gas), 0.67 tons of NO~(an acid rain precursor,
criteria
pollutant,
and
an
ozone
precursor),
and
0.57
tons
of CO
(an
acute
toxic
and
criteria
pollutant).
In
addition,
over
120,000
kWhr
of
electricity
would
be
consumed
annually.
-
14-

Therefore,
the
deleterious
energy
and
environmental
impacts
would
be
substantial,
while
the
benefits ofVOM reduction would be minimal.
H.
Justification (Section
104.406(h))
As
previously described, the Paper Coating
Rule
did
not
contemplate the
issues
pertaining
to
manufacturers
of
CI
materials
when
the
rule
was
promulgated.
Moreover,
compliance
with
the
Paper
Coating
Rule
would
undermine
the
quality
and
efficacy
of
CROMWELL’s
products.
Compliance
would
necessitate
the
addition
of
water
to
CROMWELL’s
formulae.
As
residual
water
is,
obviously,
undesirable
for
CROMWELL’s
products,
CROMWELL would
be
forced
to
use supplemental
IR
dryers to
drive offthe
excess
water.
This
extra step
in
the manufacturing process would
have the unintended
and
unwanted
effect of driving off additional VOM and
increasing the net overall emissions
from
the facility.
Thus,
CROMWELL’s
compliance
with
the RACT
standards
is
not
feasible
without incurring
extraordinary cost
and
expense, compromising product quality
and
functionality,
and
increasing
the
overall
VOM
emissions
from
the
facility.
The
RACT
adjusted
standard
proposed
by
CROMWELL
is justified
because
it
is
technically feasible,
economically
reasonable,
and
will
have
no
significant
adverse
impact
on
the
ambient
air
quality
in
the
Greater
Chicagoland
Nonattainment Area.
I.
Consistency
with
Federal Procedural Requirements (Section
104.406(i))
I.
Consistency with Federal Law
By granting the proposed adjusted standard, the Board will not violate any
provisions of the Clean Air Act.
CROMWELL’s operations
and
the appropriate RACT
requirements
applicable
to CROMWELL are subject to
this
proceeding.
Pursuant to
the
Act
and the Clean Air Act, the Board
is empowered to
determine what constitutes RACT
-
15-

for
CROMWELL.
Accordingly,
under
its
authority
to
adopt
RACT
regulations,
the
Board may grant the requested relief consistent with
federal law.
2.
Federal Procedural Requirements
Under federal law, the Board’s grant ofthe adjusted standard requested by
CROMWELL
will be submitted
to
the USEPA
for inclusion as
a RACT rule specific
to
CROMWELL
in
the
State
Implementation
Plan
for
Illinois.
As
such,
the
adjusted
standard will comport with federal
procedural requirements.
J.
Hearing (Section 104.406(j))
CROMWELL requests a hearing in this matter before the Board.
K.
Supporting Documents (Section
104.406(k))
Supporting documents cited in
this Petition
are
attached hereto as Exhibits A
and
B.
Ill.
SECTION 28.1(C)
FACTORS
Under
Section
28.1(c)
of
the
Act,
415
ILCS
5/28.1,
the
Board
may
grant
individual
adjusted
standards
upon
adequate
proof
that:
1)
the
factors
relating
to
the
petitioner
are
substantially and
significantly different from the factors relied
upon by the Board in adopting the
general
regulation
applicable
to
the
petitioner;
2)
the
existence of those
factors
justifies
an
adjusted
standard;
3)
the requested
standard
will not
result
in
environmental or
health
effects
substantially and
significantly more adverse than the effects considered by the Board in adopting
the rule of general
applicability;
and
4) the adjusted standard
is
consistent
with any
applicable
federal law.
-
16-

A.
The
Factors
Relating
To
CROMWELL
Are
Substantially
and
Significantly
Different
CROMWELL’S
operations
are
unique
in
Illinois.
Examination
of the
CTG
published for the paper coating industry demonstrates
clearly that CROMWELL’S operations are
distinct
from
those
that
the
IEPA sought
to
regulate
when it promulgated
35
Ill.
Adm.
Code,
Subpart
F, Section
2 18.204 (c).
Thus the factors relating to CROMWELL are substantially and
significantly different than those pertaining to typical paper coaters.
B.
The Existence ofThose Factors JustifIes an Adjusted Standard
As
discussed
fully
in
this
Petition,
CROMWELL
has
investigated
a
number
of
compliance
options.
The
compliance
alternatives
investigated
include
experiments
with
reformulated
CI
coatings
and
the installation of add-on
controls.
These alternatives
have
not
proven
to
be
technically
feasible
or economically
reasonable.
Under
the
circumstances,
the
requested adjusted standard
is technically and economically justified as the only means available.
C.
The
Adjusted
Standard
Will
Not
Result
in
an
Adverse
Environmental
Impact or Health Effect
As
discussed
previously
in
this
Petition, the requested
adjusted standard will not
have
an
adverse environmental
impact or health
effect.
CROMWELL
is
a
minor
source,
and,
based
upon
information
and
belief,
is
the
only
CI
material
manufacturing
facility
located
in
Illinois.
By definition, CROMWELL’s
emissions
will have only a minor impact on
air quality
within the Greater Chicagoland Nonattainment Area.
-
17-

U.
The
Proposed Standard is Consistent
with Applicable Federal Law
The proposed adjusted standard
is consistent with
federal
law as discussed
in this
Petition.
The granting of the adjusted standard will
not
violate
any
provision of the
Clean Air
Act
because
no
federal
RACT
standards
have
been
established
that
are
applicable
to
CROMWELL’s
specific operations as a manufacturer ofCI materials.
IV.
CONCLUSION
CROMWELL
requests
that
the
Board
grant
the
proposed
adjusted
standard
as
an
alternative to
the RACT regulations adopted
by the Board in the Paper Coating Rule.
To require
CROMWELL
to
comply
with
the
requirements
of
35
III..
Adm.
Code
Subpart
F,
Section
218.204(c)
et
seq.
would
result
in
substantial
economic
hardship
to
CROMWELL
with
no
corresponding
environmental
benefit.
It
is
not
technically feasible
to
comply
with
the
Paper
Coating Rule as compliant coatings do not meet CROMWELL’s
product efficacy standards, and
because
compliance
could
have
the
reverse
effect
of
creating
increased
emissions
and
environmental
detriment.
Finally,
add-on
controls
are
unreasonably
expensive,
provide
little
environmental benefit, and
have associated significant adverse ancillary environmental impacts.
Pursuant
to
35
Ill.
Adm.
Code
104.406,
CROMWELL
submits
the
technical
report
prepared
by
Environmental
Resources
Management,
Inc.
(Exhibit
A),
and
the
Affidavit
of
CROMWELL (Exhibit B) to verify the facts asserted in this Petition.
-
18-

WHEREFORE,
Cromwell-Phoenix,
Inc.
respectfully
requests
that
the
Board
grant
CROMWELL
the
proposed
adjusted
standard
from
35
Ill.
Adm.
Code,
Subpart
F,
Section
18.204(c)
as
those
rules
apply
to
the
emissions
of
VOM
from
Cromwell-Phoenix,
Inc.’s
operations
in Alsip, Cook County, Illinois.
CROMWELL-PHOENIX,
INC.
Janine
M. Landow-Esser
QUARLES
& BRADY LLC
500
W. Madison Street
Suite 3700
Chicago, Illinois 60661
312.715.5055
May 29, 2003
-
19-

EXHIBIT A

Cromwell-Phoenix,
Inc.

Back to top


Reasonably Available
Control
Technology
(RACT) Analysis
IlPinois
EPA
JO No. 031
003 AOP
May2003
Alsip, Illinois
TRADE
SECRET
Delivering sustainable solutions
~na more competitive
world
/~9,ili2
~)
S
ERM

Cromwell-Phoenix, Inc.
May 2003
RACT Analysis
Page
1
REASONABLY
AVAILABLE
CONTROL
TECHNOLOGY
(RACT) ANALYSIS
A
source specific
RACT
analysis
is
presented herein in support
of a demonstration
of
technological
and
economic
feasibility
of
add-on
pollution
controls
at
the
Cromwell-
Phoenix,
Inc.
(Cromwell-Phoenix)
manufacturing
facility
in
Alsip,
Illinois.
RACT
is
defined as “the lowest
emission limitation that
a particular source is capable of meeting
by
the
application
of
control
technology
that
is
reasonably
available
considering
technological and economic feasibility” (44 FR 53761, September 17,
1979).
Cromwell-Phoenix
is
a manufacturer of corrosion inhibiting packaging materials for the
metal parts
industry.
The corrosion inhibiting packaging materials are produced by
impregnating kraft paper with corrosion inhibiting (Cl) solutions.
The
first
step
in
the
RACT
analysis
is
to
determine
for
the
pollutants
in
question
applicable
control
technologies
that
have
practical
potential
for
this
type
of
manufacturing
operation.
The
control
technologies
are
ranked
in
order
of
overall
control
effectiveness.
If
it
can
be
shown
that
the
most
stringent
level
of
control
is
infeasible on
the
basis
of technical
and
economic factors,
then
the
next most stringent
level
of control
is
identified
and
similarly evaluated.
This iterative
process continues
until
the RACT
level under consideration
is
not eliminated by
technical
and economic
factors.

Cromwell-Phoenix,
Inc.
May 2003
RACT Analysis
Page 2
This
RACT analysis generally
follows the “top-down”
BACT analysis process described
in
the
USEPA’s
Office
of
Air
Quality
Planning
and
Standards
(OAQPS)
guidance
documents, and is summarized as follows:
Applicable
emission
control
technologies
are
identified
that
have
practical
potential for application to the above described manufacturing operations.
An efficiency level
is proposed for add-on
controls that would
constitute RACT.
Technically infeasible control options are eliminated.
The
remaining
control
technologies
are
ranked
in
the
order
of
overall
control
effectiveness.
The
most
effective
control
technology
options
are
evaluated
considering
economic impacts.
The most effective control option not eliminated is selected as RACT.
Each of the above steps
is detailed in the following sections.
A.
Identification of Applicable VOC Control Technologies
1.
Condensation
Condensation
is
a
basic separation technique
in
which
a gas stream
containing
VOCs
is first brought to saturation and then the VOCs are condensed to a liquid.
The conversion of
a vapor phase VOC
to its
liquid phase can be accomplished by
sufficiently
lowering
the
gas
stream
temperature
and/or
by
increasing
its
pressure.
The
most
common
approach
is
to
reduce the
temperature
of the
gas
stream at constant pressure.
Condensation
systems
are
effective
only
for
gas
streams
containing
high
concentrations of high molecular weight
VOCs
(e.g.
heavy
oils).
The minimum
VOC
concentration
achievable
at
the
outlet
of
a
condensation
system
is
the
saturation concentration for that particular VOC.
Water is the most common and
cost effective coolant. Therefore,
even moderate VOC removal efficiencies
(50)
are
not
achievable
unless
the
vapors
will
condense
at
relatively
high
temperatures.
The exhaust
stream
at
Cromwell-Phoenix
contains
very
low
concentrations
of
relatively
low
molecular weight
(75
145
lbs/lb-mole)
VOCs
which
condense
only
at
very
low
temperatures.
Such
temperatures
are
achievable
only
by

Cromwell-Phoenix, Inc.
May 2003
RACT Analysis
Page 3
energy-intensive mechanical
refrigeration of the exhaust
gas
stream. Therefore,
condensation is not a technically feasible option.
2.
Adsorption
Adsorption
is
a process by
which compounds such as VOCs
are retained
on the
surface of a solid.
Physical adsorption is a phenomenon where gaseous or liquid
compounds
adhere
to
the
surface
of a
bed of solid
adsorbent particles
that
are
highly porous
and have
very large surface to
volume
ratios.
Activated carbon
is
one
of
the
most
effective
and
most
common
adsorbents
used
for
removal
of
gaseous VOCs
from industrial
exhaust streams. VOC adsorption
onto
activated
carbon
is
a
physical
process
based
upon
attractive
forces
known
as
Van
der
Waals forces.
The magnitude of these attractive
forces
is
primarily
a
function of
the surface area
of the
gaseous molecules and the amount
of surface area of the
solid
that
is
available
for
adsorption.
Other intermolecular
forces
of
attraction
also affect adsorption
ability. At
equilibrium,
the quantity
of gas that
is
adsorbed
onto
activated
carbon
is
a function of the
adsorption temperature
and pressure,
the VOC
being adsorbed,
and the carbon characteristics such as particle size and
pore structure. Activated carbon
is a particularly
effective adsorbent
for gaseous
VOCs
due
to
its extremely high surface area to weight ratio, and
its pronounced
capillary action.
Carbon
adsorption
removal
systems
are
most
effective
for
VOCs
having
molecular weights between approximately
60 and 180.
The molecules need
to
be
“large”
enough
to develop
sufficient
Van der
Waals forces
with
the
adsorbing
media,
yet they can’t be
so large
that the Van
der Waals
forces are so great that
the molecule cannot be
removed
during
the
desorption cycle.
Therefore,
higher
molecular weight
compounds are too
difficult
to
desorb while lower
molecular
weight compounds experience little to no adsorption. The majority of VOCs used
by
Cromwell-Phoenix
have
molecular
weights
in
this
range,
therefore
they
would
be amenable to effective adsorption and desorption.
Also,
given
the
variety
of the
materials utilized
at Cromwell-Phoenix,
it
is
not
practical
to
recover the
solvents
for
reuse.
Solvent recovery
and
reuse
is
most

Cromwell-Phoenix,
Inc.
May
2003
RACT Analysis
Page 4
feasible
for
single
solvent
systems.
Also,
it
is
not
feasible
to
recover
such
a
solvent mixture
via
decantation
since the solvents
are water soluble. Therefore,
the
only
technically
feasible
control
option
would
be
to
utilize
an
activated
carbon adsorption
system
as
a
pre-concentrator, and
then thermally
desorb the
solvents,
directing
the
concentrated
stream
to
a
thermal
oxidizer
for
VOC
destruction.
In such a scenario, the volumetric flow rate of the desorption stream
is typically
10
of the volumetric flow rate of the adsorption stream.
While
the limitations
described above
will
reduce the effectiveness
of a
carbon
adsorption
system
and
will
present
some
safety
hazards,
a
carbon
adsorption
concentrator
in
conjunction
with
a
thermal
oxidation
control
device,
for
the
purpose
of
this
RACT
analysis,
will
be
considered
a
technologically
feasible
control option that will be further evaluated.
3.
Liquid Absorption
The process of absorption generally
refers
to
the intimate contact of a mixture of
gases
with
a
liquid
sorbate
(typically aqueous)
so
that
a part of one or more of
the constituents
in
the
gas stream
will dissolve
in the liquid.
These devices are
referred
to
generally
as
wet
scrubbers
and
they
include
packed
bed,
plate,
counter current and cross-current designs.
The
most
effective transfer
result
for an
infinite
scrubber column
is
to
achieve
equilibrium
between
the
gas-phase
and
liquid-phase
compounds.
While
the
VOCs
used
at
Cromwell-Phoenix
are
soluble
in
an
aqueous
sorbate,
their
exhaust concentrations
are
so
low
that
the scrubber
would
exhibit
a
very
low
transfer
efficiency of the gaseous VOCs into the liquid sorbate.
Also, given the polar nature of the organic materials at Cromwell-Phoenix, these
compounds
would not
be readily separable from
the sorbate liquid
for purposes
of recovery.
Therefore, the only practical
means of disposal would
be discharge
to
the
sewer,
where
some
or
most
of
the
VOCs
that
were
absorbed
may re-
volatilize en route to or at the POTW.
For these reasons, it is concluded that
gas
absorption is not a technically feasible control option.
4.
Oxidation
Complete oxidation
converts
gaseous VOCs
to carbon
dioxide,
water and other
various
products
of
combustion.
Oxidation
systems
include
direct
combustion
flares, as well as two
types
of commercially available oxidation control systems
-
catalytic and thermal. These systems are described separately below.
a.
Flares

Cromwell-Phoenix, Inc.
May 2003
RACT Analysis
PageS
A flare is
a
direct combustion
device
in
which air and the combustible gases
in
the
exhaust
stream
react
at
the
burner.
Combustion
must
occur
instantaneously
since
there
is
no
residence
combustion
chamber.
The
principal
factors
affecting
flare
combustion
efficiency
are
the
exhaust
gas
heating
value,
flammability
limits,
density
and
effectiveness
of
flame
zone
mixing.
If the concentration
of VOCs
in the exhaust
is at
or above the lower
flammability
level,
then
utilization
of
a
flare
may
be
appropriate.
For
this
reason,
flares
are
typically
used
only
in
the
steel,
petroleum
and
petrochemical industries, as they are inappropriate for most other industries
due
to lower hydrocarbon concentrations. Since the
expected exhaust stream
VOC concentrations
at Cromwell-Phoenix
will be very
low
(roughly
10
-
15
ppmv), flares are not
a technically feasible
option.
b.
Catalytic Oxidation
Catalytic
oxidation
devices
employ
a
catalyst
bed
that
initiates
oxidation
reactions
at
relatively
low
temperatures.
The
exhaust
stream
is
heated
to
approximately 650°Fand passed through the catalyst bed where the oxidation
reactions are initiated without alteration of the catalyst itself.
For
the catalyst
to
be effective, the active sites upon
which
the VOCs
react must
be
accessible,
and
the catalyst must
be
active.
The
build up
of non-combustible particles,
polymerized
materials,
or reaction
of the catalyst with certain
elements can
either
“mask”
or
“poison”
the
catalyst,
thus
making
it
unavailable
for
initiating oxidation
reactions.
While
it would
be
difficult
to
impossible
to design
a
catalytic oxidation
system
to
preclude
the
possibility
of
the
catalyst
being
masked
or
poisoned,
it
is
unlikely
that
the
materials
utilized
by
Cromwell-Phoenix
would
render
a
catalytic control
device
ineffective.
However,
given the low
concentrations of
VOCs
in
the exhaust stream, the temperature
rise
across the catalyst bed
(AT)
would be so low that a poisoned or masked catalyst would likely go undetected,
since there may not
be
a significantly
discernible
change in the AT.
Therefore,
the ongoing
performance of a catalytic oxidation system could not be effectively
ascertained. Despite these technical concerns, and
for purposes of completeness,
catalytic oxidation
will be
considered
a
technically
feasible control
option that
will be further evaluated.
c.
Thermal Oxidation
Thermal oxidation is
a reliable and
effective control technology
that converts
gaseous
VOCs
to
carbon
dioxide,
water
and
various
other
products
of
combustion
at
relatively
high
temperatures,
typically
1350
-
1800°F. The
exhaust gases
are
preheated
in
a heat exchanger and
then
directed
into
the
high temperature
combustion chamber where
the VOCs
are oxidized. In the
case
of
Cromwell-Phoenix,
the
VOC
concentration
will
be
well
below
the
level
that
is
necessary
to
provide
any
appreciable
degree
of self-sustained
combustion.
Therefore,
a
supplemental
fuel
burner
system must
be utilized.

Cromwell-Phoenix, Inc.
May
2003
RACT Analysis
Page 6
Primary
heat
exchangers
can
be used
to
raise
the
inlet
temperature
of the
exhaust stream, thus reducing the amount of supplemental fuel required.
Two
categories
of
thermal
oxidizers
are
generally
used:
Recuperative
and
Regenerative.
A recuperative thermal oxidizer uses either a shell-and-tube or
a
plate-to-plate
heat
exchanger
for
heat
recovery,
while
a
regenerative
thermal oxidizer uses a ceramic medium that
is usually stored
in two or more
separate chambers.
Some regenerative
thermal oxidizers employ
a single bed
design with
a
mobile high temperature
oxidation zone. The recuperative-type
thermal oxidizers
operate
with
a
heat
exchanger
effectiveness of up
to
70,
while
regenerative
thermal
oxidizers
employ
heat
exchangers
having
an
effectiveness of up
to 95.
Both
of
these
types
of
thermal
oxidizers
are
technologically
feasible
for
application
at
Cromwell-Phoenix.
Since
the
exhausts
will
contain
low
concentrations
of
VOCs
at
ambient
temperatures,
the
regenerative
thermal
oxidizer
will likely
be
the
more appropriate
control option
from
an
economic
stand point. This is due to its
greater energy recovery capability. However, both
recuperative
and
regenerative
control
systems
will
be
further
evaluated
as
technologically feasible options.
Also, the recuperative system will be evaluated
for use in
conjunction with the carbon adsorption pre-concentrator.
B.
Froposed Efficiency Level of Add-on Controls Which Constitute RACT
Based
on
the majority
of RACT determinations, and
on the control device
efficiency
requirements
of 35
IAC
Part
218
Subparts
F and
H,
a minimum
90
VOC control
efficiency
will
be required
of
an
add-on
control
device.
In
addition,
a
minimum
overall
control
efficiency
of
81
is
required
to
meet
the
Subpart
F
RACT
requirements,
therefore
the
capture
efficiency
should
be
at
least
90
(Overall
Control
Efficiency
(81)
=
Capture
Efficiency
(90)
x
Control
Device
Efficiency
(90)).
To
ensure
the
achievement
of
a
minimum
90
capture
efficiency,
a
permanent
total enclosure
(PTE)
would
likely need
to
be
established
for
the three
coating operations, and perhaps also
to include
the mixing tank.
The costs
for such
an
enclosure are included
in
order
to present
a complete RACT
cost
analysis.
An
approximation of the
cost to fabricate a Permanent
Total Enclosure is
$137,000.
For
purposes of this RACT analysis, it is
assumed
that a control device efficiency of 90
with
100
VOC
capture
efficiency
are
achieved,
and
the costs
of fabricating
and
exhausting a Permanent Total Enclosure are included.
C.
Elimination of Technically Infeasible VOC Control Options
On the basis
of the criteria described above in
Section C,
the following VOC control
options have been determined to be technically infeasible:

Cromwell-Phoenix, Inc.
May 2003
RACT Analysis
Page 7
1.
Condensation
2.
Liquid Absorption
3.
Flares
Therefore, these control options will not be further evaluated.
D.
Ranking of Remaining Control Technologies
The remaining three control technologies are ranked below
in Table I in the order of
control effectiveness:
Table I
Range of Control
Control Level for
Pollutant
Technology
Efficiency
(°/o)
RACT Analysis
O/~
VOC
Recuperative Thermal
90
-
99
?
90
Oxidation
VOC
Regenerative Thermal
90
-
98
?
90
Oxidation
VOC
Catalytic Oxidation
90
-
98
?
90
VOC
Carbon Adsorption
90
-
98
?
90
Concentrator with
Thermal Oxidation
Control
F.
Evaluation of the Most Effective Control Technologies Not Eliminated
The
most
effective
remaining
control
options
were
evaluated
relative
to
energy,
environmental and
economic impacts.
I.
Economic Impacts
The economic impacts of the above control options were evaluated in accordance
with
the
USEPA’s
OAQPS
Control
Cost
Manual,
by
William
M.
Vatavuk.
Economic
analyses
were
calculated
using
the
most
current
(1999)
version
worksheets
provided
by
Mr.
Vatavuk.
The economic
analysis
anticipates
the
installation of a
single control device for all
controlled processes since this
is
the
most
cost
effective
means
of
control.
It
should
be noted
that,
while
a
single
control device
will
exhibit
the
lowest
economic
costs
for add-on
controls
on
a
$/ton
of
pollutant
controlled
basis,
such
a
configuration
poses
potential

Cromwell-Phoenix, Inc.
May
2003
RACT Analysis
Pages
problems
from
an
operational
standpoint.
For
example,
it
would
be
unacceptable to have to shut
down
all
of the controlled operations
if the control
device
requires
preventive
maintenance,
or should
it
malfunction.
Also,
some
costs
such
as ductwork
are
more substantial for
a
central unit than for multiple
control
devices.
Ductwork costs
have not
been included
in this RACT
analysis.
Therefore,
while
a
single central
device
is
the most
cost
effective configuration,
operational and
ancillary factors need
to
be considered
for an
overall
feasibility
determination.
Given
the outcome
of this report, such further in-depth
analysis
is not warranted at this time.
Total annual costs
were determined for the purchase, installation and
operation
of each of the control devices considered.
The total exhaust air flow rate is based
on
the
sum
of the exhaust requirements
of each of the controlled
sources.
The
annual
cost
calculations
for
each
of
the
control
technologies
evaluated
are
included herein.
The
results of the economic cost analyses
for the control
options
evaluated
are
summarized
below
in Table
2.
The annual costs for the control devices are based
on
an
expected life of
10
years and
an
annual interest rate of 7.0.
All
analyses
are
based
on
90
control
of
the
allowed
(potential)
VOC
emissions
that
were
reflected in the March
2002 CAAPP permit
application (Exhibit
200-1) for the
CI
coating operations,
including
the flexo inks
and mixing tanks
(Total
=
16.9
tpy).
Therefore, the annual controlled amount of VOCs is calculated at 15.21
tons.
Table
2
RACT Analysis
-
Overall Plant
Annual Cost per
Ton
Control Option
Total Annual Cost
($)
of VOC Controlled
($)
Recuperative Thermal
1,075,713
70,724
Oxidizer
Regenerative Thermal
468,412
30,796
Oxidizer
558,670
36,730
Catalytic Oxidizer
Carbon Adsorber
376,942
24,783
Concentrator with
a Thermal Oxidizer

Cromwell-Phoenix, Inc.
May
2003
RACT
Analysis
Page 9
Based
on
the
annual
costs
per
ton
of
VOCs
controlled
for each of the
control
options
described
above,
none
of
the
control
options
are
deemed
to
be
economically
feasible.
Including
the costs for
the
installation
of ductwork
and
compliance
demonstration
of the control
device and the total
enclosures would
only add
to
the economic infeasibility of each option. Therefore, the actual costs
per
ton of implementing any of the
above control
options
will
be even
higher.
Finally,
as
was
stated
earlier,
while
the
utilization
of
a
single centrally-located
control
device
is
the
most
economically
feasible
option,
it
may
not
be
operationally
feasible
due
to both anticipated
and unanticipated
shut
downs
of
the
control
device.
If
only
a
single
control
device
were
employed,
normal
preventive
maintenance
requirements
or
an
equipment
malfunction
would
require
the shutdown
of
all
CI
coating
operations.
Clearly,
this
would
not
be
acceptable
from
a
production and customer requirement standpoint.
Therefore,
for operational
purposes,
multiple
control
devices would
have
to
be employed
whose costs will be higher than the lowest cost option described above.
2.
Environmental and Energy Impacts
To accomplish
the annual control of
the 15.21
potential
tons
of VOCs
using
the
most
economical control option, approximately
13.5 million cubic feet of natural
gas will
be burned,
resulting in emissions of over 800
tons
of CO2
(a greenhouse
gas),
0.67
tons
of NO~(an
acid
rain
precursor,
criteria pollutant and
an ozone
precursor) and
0.57
tons of CO (an acute
toxic and criteria pollutant). In addition,
over
120,000
kWhr
of
electricity
will
be
consumed
annually.
Therefore,
the
deleterious energy
and
environmental
impacts
would
be
substantial,
while
the
benefits of VOC reduction would
be
minimal.
F.
Selection of the Most Effective Control Option Not Eliminated
All of the most
effective control
technology options
not technically eliminated have
been
shown
to
be
economically
infeasible
since
the
total
annual
costs
for
the
installation
and operation of the least costly option is approximately
$25,000 per ton
of VOC controlled.
It should
be
recalled that
this cost does not
include
the
cost of
ductwork nor does it reflect compliance demonstration
costs (which could
approach
$40,000
-
$50,000) or operationally necessary multiple control devices. Therefore, the
actual control costs
will be considerably
higher.
In
addition, the initial
capital cost
and the substantial annual operating costs would put Cromwell-Phoenix at a serious
economic
competitive
disadvantage.
Therefore,
the
application
of
such
add-on
controls
would
be
detrimental
to
the
viability
of
this
plant.
Finally,
there
are
substantial
environmental
impacts
from
even
the
least
energy
intensive
control
option, including
substantial
emissions
of CO2 from the combustion
of
the natural
gas fuel and VOCs.
G.
Alternative Strategy to Achieve RACT

Cromwell-Phoenix, Inc.
May 2003
RACT Analysis
Page 10
Since
the use of add-on controls has been shown
to
be economically
infeasible, it
is
proposed
to minimize
VOC emissions by
continuing to
use Cl coatings that
contain
the lowest
levels
of
VOM possible,
while
still
achieving product
functionality and
quality,
and minimizing VOM emissions from supplemental drying.
The use of non-
VOC solvents such as water, acetone and methyl acetate will
be used to the greatest
degree practicable.

C-P RACT
Cost Analysis.xls
5/I
6/2003
Company Name:
Cromwell-phoenix,
Inc.
Location:
Alsip,
Illinois
Process:
CI Paper Coating Operations
TOTAL ANNUAL COST SPREADSHEET PROGRAM
--
RECUPERATIVE THERMAL OXIDIZERS
Describes
the annual operating costs for purchasing,
installing and
operating a recuperative thermal oxidizer to control the above process.
COST BASE DATE: April 1988
ti)
VAPCCI
~2)
3rd Quarter 2001
107.8
INPUT PARAMETERS
--
Gas flowrate
(scfm)
:
20000
--
Reference temperature
(oF)
:
77
--
Inlet gas temperature
(oF)
:
80
--
Inlet gas density
(lb/scf)
:
0.0739
--
Primary heat recovery
(fraction)
:
0.70
--
Waste gas heat content
(BTU/scf)
:
0.061
--
Waste gas heat content
(ETU/ib)
:
0.83
--
Gas heat capacity
(BTU/lb-oF):
0.255
--
Combustion temperature
(OF)
:
1600
--
Preheat temperature
(OF)
:
1144
--
Fuel heat of combustion
(ETU/ib)
:
21502
--
Fuel density
(lb/ftj)
:
0.0408
DESIGN PARAMETERS
--
Auxiliary Fuel Reqrmnt (lb/mm):
10.842
(scfm)
:
265.7
--
Total Gas Flowrate
(scfm)
:
20266
CAPITAL COSTS
Page 1 of
4
Recuperative

C-P RACT Cost Analysis.xls
5/16/2003
Equip~nentCosts
($)
Incinerator:
~
0
heat
recovery:
0
© 35
heat recovery:
0
~ 50
heat recovery:
0
5
70
heat recovery:
254,639
PTE Containment or other capital costs
Total Equipment Cost--base:
254,639
--escalated:
343,344
Instrumentation:
0
Sales Tax:
10,300
Freight:
17,167
Purchased Equipment Cost
($)
:
405,145
Direct
Installation Costs:
Foundations
& Supports:
32,412
Handling
& Erection:
56,720
Electrical:
16,206
Piping:
8,103
Ductwork and Insulation:
4,051
Painting:
4,051
Direct Installation Cost:
121,544
Site Preparation:
0
Buildings or PTE:
137,000
Total Direct Cost:
663,689
Page
2 of
4
Recuperative

C-PRACT Cost Analysis.xls
5/16/2003
Indirect Installation Costs:
Engineering:
40,515
Field Expenses:
20,257
Contractor Fees:
40,515
Start-Up:
8,103
Performance Test:
4,051
Contingencies:
12,154
Total Indirect Cost:
125,595
Total Capital Investment
($)
:
7e9,284
ANNUAL COST INPUTS
Operating factor
(hr/yr)
:
8760
Operating labor rate
($/hr)
:
16.48
Maintenance labor rate
($/hr)
:
18.13
Operating labor factor (hr/sh)
:
0.5
Maintenance labor factor
(hr/sh)
:
0.5
Electricity price
(s/kwh)
:
0.069
Natural gas price
($/mscf)
:
6.00
Annual
interest rate
(fraction):
0.070
Control system life
(years)
:
10
Capital recovery factor:
0.1424
Taxes,
insurance,
admin.
factor:
0.04
Pressure drop
(in. w.cJ:
19.0
ANNUAL COSTS
Item
Cost
($/yr)
Wt.
Factor
W.F. (cond.)
Operating labor
9,023
0.008
Supervisory labor
1,353
0.001
Maintenance labor
9,925
0.009
Maintenance materials
9,925
0.009
Natural gas
838,016
0.779
Electricity
45,387
0.042
Overhead
18,136
0.017
0.045
Taxes,
insurance,
administrative
31,571
0.029
Page 3 of
4
Recuperative

C-PRACT Cost Analysis.xls
5/16/2003
Capital recovery
112,376
0.104
0.134
Total Annual Cost
1,075,713
1.000
1.000
(1
Original equipment costs reflect this date.
2)
VAPCCI
=
Vatavuk Air Pollution Control Cost Index
(for thermal
incinerators)
corresponding to year and quarter shown.
original
equipment cost,
purchased equipment cost,
and
total capital investment
have been escalated to this data via
the VAPCCI and control equipment
vendor data.
Latest indexes included herein.
Costs
for
20000
RACT Cost Summary Table
acf~s.t.em
1 purchased Equipment Cost
(PEC)
405,145
2 Total Direct Cost
(includes
PEC)
663,689
3
Total
Indirect
Cost
4 Total Capital Investment
(=
2+3)
789,284
S Annual Direct Operating Costs
913,630
6 Annual Indirect Operating Costs
49,707
7 Annual Capital Recovery Costs
8 Total Annual Costs
(=
5+6+7)
1,075,713
Oxidizer VOC Control Efficiency
90
Annual VOC Input to the Control Device
16.9 tons
Annual VOC Emissions
Controlled
15.21
Annual VOC Emissions after controls
1.69
Annual Cost of Control Device
$
70,724
S/ton Controlled
Page 4
of
4
Recuperative

C-PRACT Cost Analysis.xls
5/16/2003
Company Name:
Cromwell-Phoenix,
Inc.
Location:
Alsip,
Illinois
Process:
CI Paper Coating Operations
TOTAL AN!~DALCOST SPREADSHEET PROGRAM- -REGENERATIVE THERMAL OXIDIZER
(RTO)
Describes the annual operating costs for purchasing,
installing and
operating a regenerative thermal oxidizer to control the above process.
COST BASE DATE:
December 1988
1)
VAPCcI
2)
3rdQuarter200l
110.8
INPUT
PARAMETERS
--
Gas
flowrate
(scfm)
:
20000
--
Reference
temperature
(oF)
:
77
--
Inlet
gas
temperature
(oF)
:
80
--
Inlet
gas
density
(lb/scf)
:
0.0739
--
Primary
heat
recovery
(fraction)
:
0.95
--
Waste
gas
heat
content
(BTU/scf)
:
0.061
--
Waste
gas
heat
content
(ETU/ib)
:
0.83
--
Gas
heat
capacity
(BTtJ/lb-oF)
:
0.255
--
Combustion
temperature
(oF)
:
2000
--
Heat
loss
(fraction)
:
0.01
--
Exit
temperature
(oF)
:
176
--
Fuel
heat
of
combustion
(BTU/lb)
:
21502
--
Fuel
density
(lb/ft3)
:
0.0408
DESIGN PARAMETERS
Auxiliary Fuel Requirement
(lb/mm)
:
1.966
(scfm)
:
48.2
Total
Gas
Flowrate
(scfm)
:
20048
Page1 of 4
Regenerative

C-PRACT Cost Analysis.xls
5/16/2003
TOTAL CAPITAL INVESTMENT
($)
3)
(Cost correlations range:
5000 to 500,000 scfm)
PTE Containment or other capital costs
137000
®
85
heat recovery--base:
0
-
-escalated:
0
®
95
heat
recovery--base:
1,016,304
I
I
--escalated:
1,368,558
ANNUAL
COST
INPUTS
Operating factor
(hr/yr)
:
8760
Operatmng labor rate ($/hr)
:
16.48
Maintenance labor rate
(s/br)
:
18.13
Operating labor factor
(hr/sb)
:
0.50
Maintenance labor factor
(hr/wk)
:
1.00
Electricity price
(S/kwh)
:
0.069
Natural gas price
($/mscf)
:
6.00
Annual interest
rate (fraction)
:
0.070
Control system life
(years)
:
10
Capital recovery factor:
0.1424
Taxes,
insurance,
admin.
factor:
0.04
Pressure drop
(in. w.cJ:
20.0
ANNUAL COSTS
Item
Cost
(5/yr)
Wt. Factor
W.F.(cond.)
Operating
labor
9,023
0.019
Supervisory
labor
1,353
0.003
Maintenance
labor
943
0.002
Maintenance
materials
943
0.002
Natural
gas
151,939
0.324
Electricity
47,260
0.101
Overhead
7,357
0.016
0.042
Taxes,
insurance,
administrative
54,742
0.117
Page 2 of
4
Regenerative

C-P RACT Cost Analysis.xls
5/16/2003
Capital
recovery
194,852
0.416
0.533
Total
Annual
Cost
468,412
1.000
1.000
(1)
Base
total
capital
investment
reflects
this
date.
2)
VAPCCI
Vatavuk Air Pollution Control Cost Index
(for regenerative
thermal oxidizers)
corresponding
to year and quarter shown.
Base
total capital investment
has been escalated to this date via VAPCCI and
control equipment vendor data.
Latest indexes included herein.
(3)
Source: Vatavuk,
William M. ESTIMATING COSTS OF AIR POLLUTION
CONTROL.
Boca Raton,
FL:
Lewis Publishers,
1990.
COMPARISON OF REECO/DUPONT, COsT-AIR, AND MANUAL RIO COSTS:
(1st
cUr.
‘91
$)
Flow (scfm)
REECo
($)
Manual
($)
a
Manual/REECo
COST-AIR
(5)
b
C-A/REECo
2,000
340,000
371,061
1.09
640,305
1.88
5,000
425,000
423,946
1.00
713,363
1.68
10,000
500,000
512,087
1.02
835,125
1.67
25,000
850,000
776,511
0.91
1,200,413
1.41
50,000
1,500,000
1,217,217
0.81
1,809,225
1.21
100,000
2,850,000
2,098,629
0.74
3,026,850
1.06
a
Escalated from
April.
‘88 to 1st
quarter ‘91
and
multiplied by installation factor
of 1.416
(1.2*1.18).
Range of correlation:
10,000 to
100,000 scfm.
b
Escalated from Dec. ‘88 to 1st quarter ‘91. Costs pertain to 95
heat recovery units.
Range of correlation: 5,000 to 500,000 scfm.
Page3 of 4
Regenerative

C-P RACT Cost Analysis.xls
5/16/2003
Costs
for
20000
RACT Cost Summary Table for RTO
scfm
system
1 Total Capital Investment
1,368,558
2 Annual Direct Operating Costs
211,461
3 Annual Indirect Operating Costs
62,099
4 Annual Capital Recovery Costs
194.Pc2
5 Total Annual
Costs
(=
2+3+4)
468,412
Oxidizer VOC Control Efficiency
90
Annual VOC
Input to the Control Device
16.9 tons
Annual VOC Emissions Controlled
15.21
Annual VOC Emissions after Controls
1.69
Annual Cost of Control Device
$
30,796
$/ton Controlled
Page 4 of 4
Regenerative

C-PRACT Cost Ana!ysis.xls
5/16/2003
Company
Name:
Cromwell-Phoenix,
Inc.
Location:
Alsip,
Illinois
Process:
CI Paper Coating Operations
TOTAL ANNUAL COST SPREADSHEET PROGRAM--CATALYTIC INCINERATORS
(FIXED)
Describes the annual operating costs for purchasing,
installing
and operating
a Catalytic Oxidizer to control the above process.
COST REFERENCE DATE:
April 1988
Cl
VAPCCI
2
3rdQuarter200l
109.8
INPUT
PARAMETERS
--
Gas
flowrate
(scfm)
:
20000
--
Reference temperature
(oF)
:
77
--
Inlet gas temperature
(oF)
:
80
Inlet gas density
(lb/scf)
:
0.0739
--
Primary heat recovery
(fraction)
:
0.70
--
Waste gas heat content
(BTU/scf)
:
0.061
--
Waste gas heat content
(ETU/ib)
:
0.83
--
Gas heat capacity
(BTU/lb-oF)
:
0.248
--
Combustion temperature
(oF)
:
650
--
Preheat temperature
(OF)
479
--
Fuel heat of combustion
(BTU/lb)
:
21502
--
Fuel density
(lb/ft3)
:
0.0408
DESIGN PARAMETERS
--
Auxiliary Fuel Reqrmnt (lb/mm)
3.870
(scfm)
:
94.9
--
Total
Gas Flowrate
(scfm)
:
20095
--
Catalyst Volume
(ft3)
:
38.9
Page
1 of
4
Catalytic

C-PRACT Cost Analysis.xls
5/16/2003
CAPITAL COSTS
Equipment Costs
(5)
--
Incinerator:
@
0
heat
recovery:
0
5
35
heat recovery:
0
5
50
heat recovery:
0
5
70
heat recovery:
344,811
--
Other
(auxiliary equipment,
etc.):
0
Total Equipment Cost--base:
344,811
--escalated:
409,261
Instrumentation
40,926
Sales Tax
12,278
Freight
20,463
Purchased
Equipment
Cost
($):
482,928
Direct Installation Costs:
Foundation
&
Supports
38,634
Handling & Erection
67,610
Electrical
19,317
Piping
9,659
Ductwork &
Insulation
4,829
Painting
4,829
Buildings or PIE:
137,000
Total
Direct
Cost:
764,807
Indirect
Installation
Costs:
Engineering
48,293
Field Expenses
24,146
Contractor
Fees
48,293
Start-Up
9,659
Performance Test
4,829
Contingencies
14,488
Total
Indirect
Costa:
149,708
Page 2
of
4
Catalytic

C-P RACT Cost Analysis.xls
5/16/2003
Total
Capital
Investment
($)
914,514
ANNUAL COST INPUTS
Operating
factor
(hr/yr)
:
8760
Operating
labor
rate
($/hr)
:
16.48
Maintenance labor rate
(5/br)
:
18.13
Operating labor factor
(hr/sh)
:
0.0
Maintenance labor factor
(hr/sh)
:
0.5
Electricity price
(S/kwh):
0.069
Catalyst price
($/ft3)
:
650
Natural gas price
(S/mscf)
:
6.00
Annual interest rate
(fraction):
0.07
Control system life
(years)
:
10
Catalyst life
(years)
:
2
Capital recovery factor
(system)
:
0.1424
Capital recovery factor
(catalyst)
:
0.5531
Taxes,
insurance,
admin.
factor:
0.04
Pressure drop
(in. w.cj:
21.0
ANNUAL COSTS
Item
Cost
($/yr)
Nt.
Factor
N.F.(cond.)
Operating labor
0
0.000
Supervisory labor
0
0.000
Maintenance labor
9,925
0.018
Maintenance materials
9,925
0.018
Natural gas
299,160
0.535
Electricity
49,742
0.089
Catalyst replacement
15,110
0.027
Overhead
11,910
0.021
0.057
Taxes,
insurance,
administrative
36,581
0.065
Capital recovery
126,317
0.226
0.292
Page 3
of
4
Catalytic

C-P RACT Cost Analysis.xls
5/16/2003
Total Annual
Cost
558,670
1000
1.000
1
Original
equipment costs reflect this date.
2
VAPCcI
=
Vatavuk Air Pollution Control cost
Index
(for catalytic
incinerators)
corresponding
to year and quarter shown.
Original
equipment cost, purchased equipment cost,
and
total capital investment
have been escalated to this date via the VAPCcI and control equipment
vendor data.
PACT Cost Summary Table
1 Purchased Equipment Cost
(PEc)
482,928
2
Total Direct Cost
(includes
PEc)
764,807
3
Total Indirect Cost
149,708
4 Total
capital Investment
(=
2+3)
914,514
S Annual Direct Operating Costs
383,863
6 Annual
Indirect Operating Costs
48,491
7 Annual capital Recovery Costs
126,317
8
Total Annual Costs
(=
5+6+7)
558,670
Oxidizer VOC Control Efficiency
3)
90
Annual
VOC Input to the Control Device
16.9
tons
Annual VOC Emissions Controlled
15.21
tons
Annual VOC Emissions after
Controls
1.69 tons
Annual
Cost
of
Control
Device
$
36,730
perton controlled
Page 4 of
4
Catalytic

C-PRACT Cost Analysis.xls
5/16/2003
Company Name:
Cromwell-Phoenix,
Inc.
Location:
Alsip,
Illinois
Process:
CI Paper Coating Operations
TOTAL ANNUAL COST SPREADSHEET PROGRAM-- CARSON ADSORSER CONCENTRATOR W/THERMAL OXIDIZER
This spreadsheet describes the annual operating costs for a carbon adsorption concentrator system
operating
in
coniunction
with
a
recuperative
thermal
oxidizer
controlling
the
10
desorption
stream.
STAGE
I
VOCREMOVAT.
~CAPEON
AnSORPER
CONcEWrRAI0~
COST
BASE
DATE:
Third
Quarter
1989
2
VAPCCI
3
3rd Quarter 2001
105.7
INPUT PARAMETERS:
--
Inlet stream flowrate
(acfm)
:
20000
Inlet stream temperature
(oF)
:
80
--
Inlet stream pressure
(atm)
:
1
--
VOC to be condensed:
Propylene Glycol
--
Inlet hOC flowrate
(lb/hr)
:
3.86
--
hOC
molecular weight
(lb/lb-mole)
:
76.10
--
hOC
inlet volume fraction:
1.665572E05
--
hOC
inlet
concentration
(ppmv):
16.7
--
hOC inlet partial pressure
(psia)
:
0.0002
--
Required hOC removal
(fraction)
0.950
--
Freundlich isotherm equation constants for hOC
(see Table
1 below)
hOC number
(enter Table
1
# or zero,
i
lOll
K:
0.412
M:
0.389
--
Yaws isotherm equation constants
(see Table
2 below)
VOC number
(enter Table
2 #or zero,
if
84
1.40474
0.18738
—0.02663
--
Adsorption time
(hr)
:
8.0
--
Desorption time
(hr)
:
4.0
--
Number of adsorbing vessels:
2
--
Superficial carbon bed velocity (ft/mm)
:
75
--
Carbon price
($/lb)
:
3.00
Page
1 of
10
Carbon Adsorber
-
Recup

C-P RACT Cost Analysis.xls
5/16/2003
--
Material of construction
(see list below): 4)
1.3
DESIGN PARAMETERS:
--
Carbon equilibrium capacity--Freundlich
(lb vOC/lb
0.0162
0.3926
--
Carbon
working
capacity
(lb
hOC/lb
carbon):
0.0081
--
Number of desorbing vessels:
2
--
Total number of vessels:
4
--
Carbon requirement,
total
(lb)
7611
--
Carbon requirement per vessel
(lb)
:
1903
Gas flowrate per vessel
(acfm)
:
10000
--
Adsorber vessel diameter
(ft)
:
13.029
--
Adsorber vessel
length
(ft)
:
4.476
--
Adsorber vessel surface area
(ft2)
:
449.87
--
Carbon bed thickness
(ft)
:
0.476
--
Carbon bed pressure drop
(in.
w.cj:
5
1.609
CAPITAL COSTS
Equipment Costs
(5)
--
Adsorber vessels
163,333
--
Carbon
22,833
--
Other equipment
(condenser, decanter,
etc.)
135,321
Total equipment cost
($)--base:
290,259
--escalated:
340,246
Instrumentation:
34, 025
Sales Tax:
10,207
Freight:
17,012
Purchased Equipment Cost
(5)
:
401,490
Direct Installation Costs:
Foundations
&
Supports:
32,119
Handling
& Erection:
56,209
Electrical:
16, 060
Piping:
8,030
Ductwork and Insulation:
4,015
Painting:
4,015
Direct Installation Cost:
120,447
Page 2 of
10
Carbon Adsorber
-
Recup

C-PRACT Cost Analysis.xls
5/16/2003
Site Preparation:
Suildings or PTE Constr:
137,000
Total
Direct
Cost:
658,937
Indirect Installation Costs:
Engineering:
40,149
Field Expenses:
20,074
Contractor Fees:
40,149
Start-Up:
8,030
Performance Test:
4,015
Contingencies:
12,045
Total
Indirect
Cost:
124,462
Total
Capital
Investment
(5)
:
783,399
($/acfm)
:
39.2
ANNUAL COST INPUTS:
Operating factor
(hr/yr)
:
8760
Operating labor rate
($/hr)
:
16.48
Maintenance labor rate
($/hr)
:
18.13
Operating labor factor (hr/sh)
:
0.5
Maintenance labor factor
(hr/sh)
:
0.5
Electricity price
($/kwhr)
:
0.069
Recovered hOC value
($/lb):
0.0000
Steam price
(s/bOO
lb)
:
7.50
Cooling water price
(5/1000 gal)
:
0.20
Carbon replacement labor
($/lb)
:
0.05
Overhead rate
(fraction)
:
0.6
Annual interest rate
(fraction):
0.070
Control
system
life
(years)
:
10
Capital recovery factor
(system)
:
0.1424
Carbon life
(years)
:
5
Capital recovery factor
(carbon):
0.2439
Taxes,
insurance,
admin.
factor:
0.04
Page 3 of 10
Carbon Adsorber
-
Recup

C-P RACT Cost Analysis.xls
5/16/2003
ANNUAL
COSTS:
Item
Cost
($/yr)
Nt.
Factor
W.F. (cond.)
Operating labor
9,023
0.045
Supervisory labor
1,353
0.007
Maintenance labor
9,925
0.050
Maintenance materials
9,925
0.050
Electricity
3,785
0.019
Steam
887
0.004
Cooling water
81
0.000
Carbon replacement
6,107
0.031
Overhead
18,136
0.091
0.244
Taxes,
insurance,
administrative
31,336
0.158
Capital recovery
107,973
0.544
0.702
Sub-Total Carbon Adsorber Annual costs
198,531
1.000
0.964
Recovery credits
0
Carbon Adsorber Annual costs
(w/credit)
198,531
(5/million acf)
18.89
Notes:
1
This program has been based on data and procedures
in Chapter
4
of
the
OAQPS CONTROL COST MANUAL
(5th edition)
2
Sase equipment costs reflect this date.
3
VAPcCI
=
vatavuk Air Pollution Control Cost Index
(for carbon
adsorbers)
corresponding to year and quarter shown.
Sase equipment
cost,
purchased equipment cost,
and total capital investment have been
escalated to this date via the vAPcCI and control equipment vendor data.
4
Enter one of the following:
carbon steel--b’;
316 stainless steel--
‘1.3’; Carpenter 20
(CB-3)--’l.9’;
Monel-400--’2.3’;
Nickeb-200--’3.2’;
titanium--‘4.5’
5
This
is the carbon bed pressure drop ONLY.
There will be additional pressure drop
through the ductwork
.
For estimating ductwork pressure
losses,
see chapter 10
of
the
OAQPS CONTROL COST MANUAL
(5th edition)
Page 4 of
10
Carbon Adsorber
-
Recup

C-PRACT Cost Analysis.xls
5/16/2003
Table
1.
Freundlich Constants
for Selected Compounds
63
Correlation Range
(psia)
hOC
hOC
number
K
M
Temperature
(F)
Minimum
Maximum
Benzene
1001
0.597
0.176
77
0.0001
0.05
Chlorobenzene
1002
1.05
0.188
77
0.0001
0.01
cyclohexane
1003
0.508
0.210
100
0.0001
0.05
Dichloroethane
1004
0.976
0.281
77
0.0001
0.04
Phenol
1005
0.855
0.153
104
0.0001
0.03
Trichboroethane
1006
1.06
0.161
77
0.0001
0.04
Vinyl chloride
1007
0.200
0.477
100
0.0001
0.05
m-Xylene
(low-pressure
1008
0.708
0.113
77
0.0001
0.001
m-Xylene
(high-pressur
1009
0.527
0.0703
77
0.001
0.05
Acrylonitrile
1010
0.935
0.424
100
0.0001
0.015
Acetone
1011
0.412
0.389
100
0.0001
0.05
Toluene
1012
0.551
0.110
77
0.0001
0.05
63
These constants fit the following equation:
Q
=
K(P)~M
where:
Q
=
equilibrium adsorption capacity
(lb/lb carbon)
P
=
hOC
partial pressure
(psia at
1
atm
& listed temperature)
Table
2.
correlation Constants
for Yaws IsothCorrelation Ranges
(ppmv)
voc
hOC
number
A
B
C
Minimum
Maximum
Phosgene
6
-0.64469
0.60428
-0.02986
10
10000
Carbon
tetrachloride
9
1.07481
0.28186
-0.02273
10
10000
Chloroform
11
0.67102
0.36148
-0.02288
10
10000
Formaldehyde
18
-2.48524
0.69123
-0.00375
10
10000
Methyl chloride
21
-1.91871
0.62053
-0.00549
10
10000
Carbon
disulfide
35
-0.18899
0.47093
-0.01481
10
10000
Tetrachioroethylene
39
1.40596
0.20802
-0.02097
10
10000
Vinyl chloride
55
-0.98889
0.66564
-0.04320
10
10000
b,l,2-Trichloroethane
59
1.17163
0.27791
-0,02746
10
10000
Page
5 of
10
Carbon Adsorber
-
Recup

C-PRACT Cost Analysis.xls
5/16/2003
Acetonitrile
60
-0.79666
0.63512
-0.02598
10
10000
Methyl
isocyanate
61
-1.07579
0.85881
-0.06876
10
10000
Acetaldehyde
69
-1,17047
0.62766
-0.02475
10
10000
Ethylene glycol
84
1,40474
0.18738
-0.02663
10
121
Ethyl
mercaptan
87
0.00552
0.40506
-0.01802
10
10000
Acrybonitrile
93
0.07669
0.49986
-0.03500
10
10000
Acrolein
97
-0.29632
0.49437
-0.02471
10
10000
1,3-Butadiene
168
-0.03359
0.34764
-0.01297
10
10000
Methyl ethyl ketone
194
0.46525
0.37688
-0.02801
10
10000
n-Butane
213
0,03071
0.34304
-0.01596
10
10000
l,2,4-Trichlorobenzene
331
1.68304
0.09456
-0.00998
10
566
chlorobenzene
336
1.02705
0.30619
-0.03353
10
10000
Nitrobenzene
340
1.64859
0.06109
0
10
329
Benzene
341
0.81119
0.28864
-0.02378
10
10000
Phenol
345
1.45599
0.10349
-0.01086
10
10000
Toluene
466
1.11466
0.20795
-0.02016
10
10000
m-Cresol
469
1.61982
0.04926
0
10
149
o-Toluidine
474
1.58104
0.05475
0
10
339
Styrene
528
1.35701
0.13495
-0.01451
10
8044
m-Xylene
533
1.31522
0.14019
-0.01457
10
10000
o-Xylene
534
1.33404
0.13931
-0.01494
10
8722
p-Xylene
535
1.31115
0.14069
-0.01458
10
10000
71
Constants fit
the
following equation:
Q
=
O.01*1OAA
+
S(bogy
)
+
C(logy
)
A~
where:
Q
=
equilibrium adsorption capacity
(lb/lb carbon)
y
=
VOC concentration
(ppmv at 77
F,
1
atm)
Source:
Yaws,
Carl
L.
et al.,
“Determining VOC Adsorption Capacity,” Pollution Engineering,
February 1995,
pp.
34-37.
Page
6 of
10
Carbon Adsorber
-
Recup

C-PRACT Cost Analysis.xls
5/16/2003
TOTAL ANNUAL COST OF THERMAL OXIDIZER FOR DESTRUCTION OF VOcs IN cONCENTRATED DESORPTION EXHAUST STREAM
STAGE
II VOC DESTRUCTION
-
RECUPERATIVE THERMAL OXIDIZER
COST SASE DATE: April 1988
13
VAPCCI
2
3rd Quarter 2001
107.8
INPUT PARAMETERS
--
Gas
flowrate
(scfm)
:
2000
--
Reference temperature
(oF)
:
77
--
Inlet gas temperature
(OF)
:
150
--
Inlet gas density
(lb/scf)
:
0.0739
--
Primary heat recovery
(fraction):
0.70
--
Waste gas heat content
(BTU/scf)
:
0.061
--
Waste
gas heat content
(STU/lb)
:
0.83
--
Gas heat capacity
IBTU/ib-oF)
:
0.255
--
Combustion temperature
(oF)
:
1600
--
Preheat temperature
(OF)
:
1165
--
Fuel heat of combustion
(BTU/lb)
:
21502
--
Fuel density
(lb/ft3)
:
0.0408
DESIGN PARAMETERS
Auxiliary Fuel Reqrmnt
(lb/mm)
:
1.047
(scfm)
:
25.7
--
Total Gas Flowrate
(scfm)
:
2026
CAPITAL COSTS
Equipment Costs
(5)
--
Incinerator:
®
0
heat recovery:
0
Page 7 of
10
Carbon Adsorber
-
Recup

5/16/2003
C-P RACT Cost Analysis.xls
@ 35
heat recovery:
© 50
heat recovery:
© 70 ~ heat recovery:
Other Capital Costs
Total Equipment Cost--base:
I
I
--escalated:
Instrumentation:
Sales Tax:
Freight:
Purchased Equipment Cost
($)
143, 178
193, 054
0
5,792
9,653
Direct Installation Costs:
Foundations & Supports:
Handling & Erection:
Electrical:
Piping:
Ductwork
& Insulation:
Painting:
Direct Installation Cost:
Site Preparation:
Other
(Specify)
Total Direct
Cost:
Indirect Installation Costs:
Engineering:
Field Expenses:
Contractor Fees:
Start-Up:
Performance Test:
Contingencies:
Total
Indirect
Cost:
16,680
29,190
8,340
4, 170
2, 085
2,085
62,550
271,048
20,850
10,425
20, 850
4,170
2, 085
6,255
64,635
0
0
143,178
208,499
Total Capital Investment
($)
:
335,683
Page8of
10
Carbon Adsorber
-
Recup

C-P RACT Cost Analysis.xls
5/16/2003
ANNUAL
COST
INPUTS
Operating
factor
(hr/yr)
:
8760
Operating labor rate ($/hr)
:
16.48
Maintenance labor rate
($/hr)
:
18.13
Operating labor factor
(hr/sh)
:
0.0
Maintenance labor factor
(hr/sh)
:
0.5
Electricity price
($/kwh)
:
0.069
Natural gas price
($/mscf)
:
6.00
Annual interest rate
(fraction)
:
0.070
Control system life
(years)
:
10
Capital recovery factor:
0.1424
Taxes,
insurance,
admin.
factor:
0.04
Pressure drop
(in.
w.c.)
:
19.0
ANNUAL COSTS
Item
Cost
($/yr)
Mt.
Factor
W.F. (cond.)
Operating labor
0
0.000
Supervisory labor
0
0.000
Maintenance labor
9,925
0.056
Maintenance materials
9,925
0.056
Natural gas
80,893
0.453
Electricity
4,537
0.025
Overhead
11,910
0.067
0.178
Taxes,
insurance, administrative
13,427
0.075
Capital recovery
47,794
0.268
0.343
Total Annual Cost for Thermal Oxidizer
178,411
1.000
1.000
(1
Original equipment costs reflect this date.
2
VAPCCI
=
Vatavuk Air Pollution Control Cost Index
(for thermal
incinerators)
corresponding to year and quarter shown.
Original
equipment cost,
purchased equipment cost, and total capital investment
have been escalated to this data via the VAPCCI and control equipment
vendor data.
Page9 of 10
Carbon Adsorber
-
Recup

C-P RACT Cost Analysis.xls
5/16/2003
TOTAL ANNUAL COST:
CARBON ADSORBER CONCENTRATOR w/
THERMAL
OXIDIZER
Sub-Total Annual Cost Carbon Adsorber Concentrator
198,531
Sub-Total Annual Cost Thermal Oxidizer VOC Control
178,411
Total Annual Cost Carbon Adsorber/Thermal Oxidizer
376,942
Costs for One
20000
RACT Cost Summary Table
scfm system
1 Purchased Equipment Cost
(PEC)
609,989
2 Total Direct Cost
(includes
PEC)
929,985
3 Total Indirect Cost
189.096
4 Total Capital Investment
(=
2+3)
1,119,082
5 Annual Direct Operating Costs
146,366
6 Annual Indirect Operating Costs
74,809
7 Annual Capital Recovery Costs
155767
8 Total Annual Costs
(=
5÷6+7)
376,942
Oxidizer VOC Control Efficiency
90
Annual VOC Input to the Control Device
16.9 tons
Annual VOC Emissions Controlled
15.21
Annual VOC Emissions after Controls
1.69
Annual Cost of Control Device
$
24,783
$/ton Controlled
Page 10 of 10
Carbon Adsorber
-
Recup

U
IIUIHX2L

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TRADE
SECRET
C~O~
~
CONFIDENTIAL BUSINESS INFORMATION
BEFORE
THE ILLINOIS POLLUTION CONTROL BOARD
IN
THE MATTER OF:
)
AS_____
Petition of Cromwell-Phoenix, Inc.
)
(Adjusted Standard)
for
an Adjusted Standard from 35
)
Ill. Adm. Code Subpart F, Section
2 18.204 (c)
)
(the “Paper Coating Rule”)
)
AFFIDAVIT OF FRANCIS HOULIHAN IN
SUPPORT
OF CROMWELL-PHOENIX, INC.’S
PETITION FOR AN ADJUSTED STANDARD
I Francis Houlihan, declare under penalty ofperjury that the following is true and correct:
1.
I am the President ofCROMWELL-PHOENIX,
E~TC.(“CROMWELL”).
2.
I have served in that capacity since CROMWELL was formed.
3.
CROMWELL is an Illinois corporation located in
Alsip, Cook County, Illinois.
4.
CROMWELL
employs 31
people at this location.
5.
CROMWELL is a manufacturer ofcorrosion inhibiting (“CI”) packaging materials
for the metal parts industry.
6.
7.
CROMWELL believes that it is the only manufacturerofcorrosion inhibiting
packaging materials in Illinois.
8.
CROMWELL produces
CI packaging materials by impregnating kraft paper with
corrosion inhibiting solutions.
QBCHI\338495.
1

r
9.
10.
The carrier solution is comprised of high molecular weight Volatile Organic Material
(“VOM”) and water.
11.
The vapor pressures ofthe VOM components are very low
and therefore their
evaporation is minimal.
12.
13.
The purpose ofthe carrier solution is to transport the CI compounds into the paper,
retain them, and ultimately facilitate their gradual migration to the customer’s
wrapped metal parts over a prolonged period oftime.
CI packaging materials have up
to
a five year shelf life.
14.
The only regulated emissions from the production
of CI packaging materials are the
relatively low emissions ofVOM.
CROMWELL selects the impregnation coating
and carrier constituents based upon their ability to be retained in the product for a
prolonged period oftime.
Therefore, the emissions of VOM are very low by design.
15.
Low vapor pressure VOM carrier compounds are utilized and the finished packaging
material is rewound on a cylindrical core immediately after the solutions
are applied,
thereby physically encapsulating the product and
further impeding the volatilization
ofthe liquid
faction components.
In addition, the vast majority (90)
ofthe products
are produced without using dryers.
16.
Infra-red (“IR”) drying is only required when the CI solution contains a greater
percentage ofwater.
The excess water must be driven off using the IR dryers.
This
process also drives off some VOM.
17.
CROMWELL has attempted to
develop a CI solution reformulation which would
reduce the as-applied VOM content (less water) to the greatest degree practicable
while still providing sufficient solids dissolution, retention, and migration.
However,
as the amount ofwater in
the solution is increased, so does the need to utilize the IR
dryers to drive offexcess water.
Along with the increased evolution ofwater will be
an associated proportionate increase in VOM emissions for the equivalent CI product
produced.
18.
Achieving compliance with the applicable limitations of35 IAC Part 218 Subpart F
requires that either the VOM content ofthe CI solutions be reduced or that add-on
controls be applied.
QBCHI\33
8495.1

19.
Achieving the VOM content levels in the CI coatings that are called for in 35 IAC
Part 218 Subpart F
(35
IAC 2 18.204(c)) is not practicable for functional,
environmental, and economic reasons.
20.
In CROMWELL’S CI
solutions, VOM components are intended to remain in the CI
packaging products in order to perform their essential corrosion inhibiting functions.
The VOMs are themselves corrosion inhibitors and they facilitate the gradual
migration ofother corrosion inhibiting solids present in the CI packaging products
onto the customer’s wrapped metal parts
over a prolonged period oftime.
Therefore,
CROMWELL has economic and product performance incentives to
ensure that the
VOM components are retained in the product and not emitted.
21.
CROMWELL has experimented with reformulated coatings in an
attempt
to achieve
a coating which approximates the 2.3 pounds VOM per gallon required under 35 IAC
218.204 (c).
Such reformulations would require the substitution ofwater for some of
the VOM.
22.
It is undesirable for the CI products to contain excess water, as the presence of
residual water in the CI products promotes corrosion ofthe customer’s metal parts.
Excess water also causes unacceptable
expansion ofthe paper fibers resulting in the
CI paper product becoming wrinkled and welted, as well as the cut sheets becoming
curled.
This makes the CI paper very difficult to handle and results in the inability to
achieve a good wrap on the metal items that are being protected by the CI papers.
23.
Ifadditional water is substituted for some of the VOM compounds in the CI solution
additional heated drying operations would be required in order to drive off excess
water.
This would require additional energy consumption,
and would increase VOM
emissions above those currently produced by CROMWELL.
It would also reduce the
efficacy ofCROMWELL’S CI packaging material by driving offCI constituents
intended to be retained in the CI paper.
24.
CROMWELL has calculated that use ofa compliant CI solution would result in
VOM emissions
approximately 7.8 times greater than those associated with
the
current formulations.
CROMWELL’S emissions would rise from the current
approximately 6 tons per year to 39 tons per year or more.
25.
CROMWELL also analyzed the technical and economic feasibility ofadd-on control
devices to CROMWELL’S
CI coating operations.
26.
The technically feasible control options were determined to be oxidation and a
combination carbon adsorption/oxidation system.
CROMWELL’S
consultant, ERM,
Inc., determined that the annual cost per ton ofVOM controlled for each ofthese
options is well above the level that would be considered reasonable under a
conventional RACT demonstration.
As a small business, CROMWELL cannot afford
the initial capital outlay
and annual operating costs associated with add-on control
devices.
QBCHI\33 8495.1

,:
27.
CROMWELL reported air emissions of
5.4
tons
in 2001
and 6.03
tons in 2002.
28.
CROMWELL cannot use compliance coatings and such use would actually increase
rather than decrease emissions from the facility.
In addition, the approved control
technologies will work only at an unreasonable cost and with nominal VOM
reduction benefit.
29.
Therefore CROMWELL requires an adjusted standard.
/~ci
~~i~as
Houhhan, President
Cromwell-Phoenix, Inc.
Signed and sworn to before me
this
~7
day ofMay, 2Q03.
(TL
~t~ry
Public
“OFFICIAL
SEAL”
LORET~A
F. SCHULTZ
NOTARY PUBLIC, STATE
OF
ILLINOIS
MY COMMISSION
EXPIRES 9/4
2005
QBCHI\338495.1

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