ILLINOIS POLLUTION CONTROL BOARD

August

10,

1984

VOLATILE

ORGANIC

MATERIAL

R82~14

EMISSIONS

FROM

STATIONARY

Dockets

A

&

B

SOURCES:

RACT

III

ORDER

OF

THE

BOARD

(by

J~ Theodore

Meyer):

Having, in part, adopted regulations pursuant to original

proposal in this rulemaking,

specifically those pertaining to

the

vegetable oil processing industry (Board Or&..rs of June 14 and

29, 1984), the Board now adopts for First Notice

language

further

amending

35 I1l~Ada0

Code 215:

Organic Emission Standards

and

Limitations0

Proposed are rules pertaining to four industrial

categories:

Wood Furniture Coating, Heatset Web

Offset

Litho~

graphy

Printing, Syrthetic

Organic

ChemIcal and Polymer Manu~

facturing and

Coke

By~Product

Recovery Plants,

It is

also proposed

that the

exemption previously

adopted

for the

viscose casing industry at Section 215~305be deleted,

That

exemption

was

provided

in

anticipation

that

a

general

rule,

more

restrictive

than

that

already

found

12

Subpart

K,

would

be

adopted0

Since no amendment is proposed at Subpart K:

Use of

Organic Material,

the previously adopt.ed exemption is unnecessary.

It

is the order of the Board that the attached language be

sent to First Notice in accordance with the Administrative Pro~

cedure Act

Ill,

Revs Stat,

1983,

cii,

127, par~ 1005,01(a),

IT IS SO ORDERED,

Messrs~Nega and Dumelle dissented,

I,

Dorothy N.

Gunn, Clerk of the Illinois Pollution Control

Board hereby certify that the above Order was adopted on the

~~~day

~

1984 by a vote ~

~othG’,U~k~

Illinois Pollution Control

Board

---

Section 215.104

Definitions

The definitions of

35 Ill. Ada.

Code 201 and 211 apply to this

Part,

as

well as the definition contained

in this Section,

Where

the definition contained in this Section is more specific than

that found in Parts 201 or 211,~it shall take precedence in

application of this Part,

“Binders”:

Orqanic materials and resins which do_not include

~aterials,

To coat”:

The

final coatin

which contains binders, bu

t

~ueimentsandissecificallformu1~dtoforma

arent

or translucent solid

rotectlye

film

“Conventional

Soybean Crushing Source~: Any hexane extraction

soybean

crushing equipment that uses direct contact steam for

desolventizing

and producing toasted soya meals.

~nent”:

~iece

of e ui ment

:qhich has the

otential

to

latile

or anic material includin

but not Urnited to

urn

seals

corn ressor seals

seal oil de~as~~a

yen

iellne

~

~Thjsdef~desval’~eswhicharenotexternall

~

~

~iturecoatinAlicationLine~Thecombinati~oatin

~

~,andothereuirnentoeratedinapredeterrnine~ce

~

class of web of

lithorahwUch

re uires

a

erintin

inks,

~Liuid”:Liuidwithatruevaorressure~than

O4si)at294,3°K(7O°F~established~standard

~

Va

or

Pres~~reas ~eterrn

med

by

AS TM

method

D-~3;

or

wMch

~ist

illed r

uires

~er

ture of 300

orre ater to

~rl0oftheliuidasdeterrninedb’ASTMrnethodD~

Li

id

“:

Volatile

anic material

in ~e

Ii

id

etate

is not

defin~e

av

Ii

id

htOil”:

AU

onden

S

ed or a~o bed

ke oven

a

S

~edofbenzene,tolueneandx~.

59~342

---

—

3-.

“Offset”:

Use

of a blanket cylinder to transfer ink from

the

5late

qy).inder

to

the

surface to be printed.

‘~p~g~e

Stains”:

All

stains containing ~igments not classifLed

asse.ransparent

stains including stains,

glazes and

other

—

~e.~aterial

to give character to wood.

~~4~entsCoatinas:

Opaque coatings containing binders and

colored

igments

~hich

are formulated to conceal the wood

surface either as an undercoat or topcoat.

2~pair

Coatings:

Coatings to correct imperfections or damage

to furniture surface.

“Sealer”:

Coating containing binders which seals the wood

prior

to application to subsequent coatings.

“Semi—transparent Stains”:

Stains containing dyes or

semi.-’

transparent pigments which are formulated to enhance wood grain

and

chanq~the color of the surface but not to conceal

the

suiface~

including sap stain, toner, non-grain raising stains, pad

stain1

spatter stain, and other semi—transparent stains.

“Specialty Soybean Crushing Source”:

Any hexane extraction

soybean crushing equipment using indirect steam heat in

flash or vapor desolventizers as the primary method of desol’-

ventizing and producing specialty solvent extracted soy flakes~

grits or flour.

“Volatile Organic Material”:

Any

organic material which has

a

vapor pressure of 17.24 kPa

(2.5 psia) or greater at 294.3°K

(70°F).

~

~

~

~

~

me

ny—c

a

c—s

e

~

~

For

purposes

of

this

definition,

the

following

are

volatile

organic

materials:

Methane

Ethane

1,1, 1—~trichioroethane

Methylene chloride

For purposes of the following Sections, volatile organic

materials are any organic materials having the corresponding

59-343

---

4—

“Wash Coat”:

Coating containing binders which seals wood

surfaces,prevents undesired staining and controls penetration.

“Web”:

A substrate which is printed in continuous roll—fed

presses.

“Wood Furniture”;

Room

furnishings

including cabinets

(kitchen,

bath

and

vanity,

tables, chairs, beds, sofas,

shutters,

art

objects, wood paneling, wood flooringf and any other coated

~iirnishingsmade of wood, wood composition or simulated wood

Section 215.105

The following materials are incorporated by reference:

a)

American Society for Testing and Materials,

1916 Race Street,

Philadelphia, PA

19103:

1)

ASTM

2)

ASTM B 1475—60

3)

ASTM D

2369—73

~

ASTM B

2879

5)

ASTM B

323

6)

ASTM B 86

7)

AS~M

E

260,

168,

169

b)

Federal Standrd 141a,

Method 4082.1

C)

National Fire Codes, National Fire Protection Associa-

tion, Battery March Park,

Quincy, Massachusetts

02269

(1979)

Sections

~porPres

sure

2:15.181

215.184

0.013

kPa

(.0019 psia)

2.15.104

—

215.209

0.013 kPa

(.0019 psia)

215.340

—

2i5~345

0.013

kPa

(.0019 psia)

215.401

•-

215.408

0.013

kPa

(.0019 psia)

215.420

~15.441

-~

~

215.428

215.444

0.013

10.34 kPa

(.0019 psia)

(1.5

psia)

215.445

—

215.451

0.013 kPa

(.0019 psia)

215,461.

—

215.464

0.013 kPa

(.0019 psia)

215.510

215.513

0.013 kPa

(.0019 psia)

215.601

-.

215.603

0.013 kPa

59-344

---

d)

United States Environmental Protection Agency,

Washingtor~~D.C.,

EPA~450/2—77—026,

Appendix A

~3UBPAItTF~ COATING OPERATIONS

Section 215.204

Emission Limitations

for Manufacturing

~iants

No

owner

or

operator

of

a

coating

line

stall

cause

or

allow

the

emission

of

volatlU

organic

material

to

exceed

the

following

limitations on coating materials

excluding

water,

delivered

to the coating applicator:

(Subparagraphs

(a)

through

(k)

remain unchanged.

W

~urniture~oa~in

~/aal

1)

~rt2~oat

0.67

(5.6)

2)

Q~~estain

0.56

(4.7)

3)

~mented

coat

(5.0)

4fl

~~at

0.67

(5~

5)

Sealer

1~5~6)

6)

Semi~tra~~ren~tain

(6.6)

7)

Wash coat

0,73

(6.1)

(BoardNote:Thereairco&:.hasanoverall

tran~erefficienc’of30~rcent~’

all

others have

~

Section

215.211

Compliance

Dates

and

Geographical

Ares

a)

Except as

otherwise

stated

in

subsection

(b),

every

owner

or

operator

of an emission source

subject

to

Section

215.204(j),

e~é

(k) and(1)

shall

comply with

those sections in accordance with the

following

dates:

1)

For Section 215,204(j)

and

(IC),

by

December

31,

1983..

2)

For Section

2:15,204(k)(2),

in

accordance

with

Section

215.210.

59-345

---

3)

o~E~ction21~2~)1l

1.e~nber~~1985.

b)

If

an

o~r~

~

sour

~c

~

r

cOU~

I

~‘t

u~ he~ ~r

ee~~

~

of

J’~

,i~it oou~.

regul.

~.

:

¶ SectltM

no

laF~,

~

r

~

Du~

i.

Greer

J~k~r

Johr so

Kant.

Kei

di~

mi;

~

~

mn

one

of

the

~

ee~-.amy

operator

~hthe

or

(k)

or_(U

a

S

ii

Orion

Wa~h~j~cr

W

1

~aion

(Board

rc te’

~heUSEPA

ncteo

r

tredesi~2p

rulemaar~~a~itwiU~

~j

~akin

notice

on

WiUiarwon

County

u

att

i~re t

~tatus,

(45

Fed,

~

t~.6.

~33

louli

~

be

re

~

i

~a

itainri

~

ror

to

December

31,

-~

:

~c~ur

tie

to

it

will

be

coneL

e.~

;

c.cmeted

from

t

~

~

list

)

c)

Notwi~L.l-ndin~

~ur~oct,t~o~

ry

county

is

desig’

‘u

u~2natt~zi~.me

USSIA

at

any

time

~nt

ro

tho

~f

s...

v~ d

tu

of

this

rule,

the

ownor

e.perutt~r of

t.

er~s~on

‘ource

located

in

tha~

~

cr

ury

cou

ti

u

n~aguous to

that

county

mr

u~

Id

othm.

~

h

act

to

the

complia~

~ate

in

suh~cta

i

s~a1l

comply

with

the

ruqua~ ~u~ts

..

I

),

e~ (k)

or(l)

withir

.~.m~car

fron

~

a..

~d’a

gnation

but

in

no

ca~c ~~‘r

than

Occepra

t

Section

215.212

a)

The

~

~

opera to:~

ra;

to

~

~15

~

Agencj

a

mnl,~an n

hy’~aa.

~ehe8rI

~aare’~ap~’

9

1983.

.a.ton

source

subject

ii

submit

to

the

~a

~~

~~~ore

August

19,

---

7.~

b)

!I~

£!P~iS~.

2:a~2flt2r~L,

9ect~~~

2i3.~211(a(~)

;lnriceni: Ton or~iE~

b+ c)

~c

r;~

~

c~er-Cor ~

to

‘c~.

1~E 211(3

compi

a~cr~:!~r,

4ne4~

eehedai

3986

e+

d.)

The o&~r

c

~oeta,

to Cee~ic~i.4211(

)

r

plan

~?nc

iang~a~paa~

witLi

0 dajs after thn

but

in n~

t~se

lator tn~

8+ e)

~

4e—easappaeaed~by—the~

1~°.

e~—a—Eactltt*y—ea-~em*ase

aez

esnoe±Eaed—tns~e~.

epeaabe~thc*em4ssten—i

i~r~

end-~seheduae—as~ewbm&Et

‘d~

The owno~cir os~f!~c2rof

en

to

Section

L15e21l(C)

sh

I

Stibifltct

COIrPlianCQ~pjaI

af ter

Leoouter

31,

198

orcjQfl~e9~tc

se~9aacom~

r~e subject

Igency a

-3e?eea

)ecether

31,

a

s bject

at

a-

a,

~1

r—epexa’bef

~-i-~

“Ue’ttI~e

a +e~~ray

~-i~1en

o~r”e

~ject

~ra-ci

to

LO)

occux s

e+

f)

The p1

r

~‘~c3.~chethie

thc~

of

IS

~i

~dm~

Code

‘I

speri~r.

U1-~c:

a:

USE UL

-~

ee-~43wemp?4ez

9?he—p~ev4Meas ef

s~a-axt-It--tha11

e?aee~eaete?rpeLi~~

Ssae-~-eae4nçp’~w

v4seeee~p~eeeeev

~

SUESPRI

P:

PRINTI7G

Section 215~402Exemptions

The

limitations

of

t’ho~ Subpaot

s.

-

-

aS

/

Si

3,

---

a)

A

an~ facility

whose

aqgreg~at-~

~t

—

and/or

l’~xoaraphic

printirj

it~

tile

~

~ctic

nater~al

are

cond

ti

DtF

:0

907

Mg

10Lt

t

absei

a

c

air

pollutioc

c

-

actu

-

c~

scions

:n

it

~

-~

-

contr~1

~uipment

wouta

4~

-

907

~ia

000

tons)

per

yct’

rh’-

prec~-~

~hLre

cale’d

x

1a-

whooe

a

volat’

-

0nic

mat

na

~~ar

c r

ess

in

the

aLa

contt~,

~j~o~jx

1,

p~9titccndinions~

-,

I

o~

b),

every

-

-

ca-

sub~ectto:

1)

:,~n205~40istall

corrpl’

ith its standards

and

limitations

by

December

3

,

t983~

2)

Section 215~408_shallcomply

—

tL

its

standards

rQiJ~t!~ionsbD!gemb~

1

385~

b)

If

ar en aaron source

is not

-

Cd

i

one

of

the

counties listed below ai,de—~’a+ae--neE—~eeated—4n

aay~eeuvty-eenttg~eas--here1as, I

-

)8ra0 or operator

of the amic~sJonsource shall coraYj dth the

requir ~:‘r

of

thra

tt’bparv

to

rr

rrlan

becea~

ber

3~

~

Li’

~

0

lIck

T~/

‘C Dr

‘Jo

at

0(1

0Ofl~fl

Fra~J-~in

2L~

Pit

Jckean

~a

~

Jer~tp~

Srtg~

fl

St

dali

Kane

odor

Kerc3all

Wet

Lake

Macoopin

non

-utrol

ed

rotogravure

~-mrssions

of

vola~

:‘

perating

permit

t.

y-ear

or

less

in

the

Ltipn~nL

or

whose

-

V

pollution

o.

egaal

to

aver&c ad

o’er

the

-

leatset

web

i)a

0

-

‘~

tons)

r

‘-illution

I-’

-

C--

-

‘

Areas

Section 2l5~40b

r-

:-~-~aceLaths

an

a)

Except.

-

-

oerviso

stated

:

owner

-~

nt

rctor

of

an

emiesi~’

594)45

---

8e~!na$~e8-asei~etamey~e-41S~PA-

~

(Board_note:

The

USEPA

noted

in

itsi

nation

~ak

in

that

jt~

ub

I

js~mak

in

notice

~

45 Fed.

1849

Ma

16

19!

ho

d

Wililams

on Count

to December 31,

~

Will

be

considered deleted from the above

list,)

c)

Notwithstanding subsection (b)~if any county is

g~a~ed

~4~i

nated

as

nonattainment by the USEPA

at

any time subsequent to the effective date of this

S~paftSection, the owner

or

operator of an emission

source located in that county or any county contiguous

to that county who would otherwise be subject to the

compliance date

in subsection

(b)

shall comply with the

requirements of this Subpart within one year from the

date of redesignation but in no case later than

December 31, 1987.

Section

215.407

Compliance Plan

a)

The owner or operator of an emission source subject

to Section 215.405(a)

(1) shall submit to the

Agency

a

compliance plan,

~fanteSA4mT~?e~e

~

~

~

no

later than April

21,

1983.

~

~

~

~

~

c)

The owner or operator of an emission source subject

to Section 215,405(b)

shall submit to the Agency a

compliance plan, ~

~

no later than December 31,

1986.

d)

The owner or operator of an emission source

subject

to Section 215.405(c) shall submit a compliance

plan, including a project completion schedule

within 90 days after the

date of redesignation,

but in no case later than December 31,

1986.

594349

---

~I0—

&*

~

~

sac

~

e)

The

owner or .~p~~tpr

of

an em

is

s

ion source

sub~ect

to_Section_215~j~d)shallno~j~er~uiredto

~bmit:acomiiance

plan

if redesignation

occurs

after Decembe~~19~~

~

f)

The plan and schedule

shall meet

the

requirements

of 35

111, Adm. Code 2017

•pay-4e~ë.4~g

~

ee~e2e~v~4~

Section

215~408 Heatset

Web

Offset

Lithographic

Printinj

No owner

or

operator

of

a

heatset

web

offset Iith2~~hic

printing

press

subject

to

this

rule

may

cause

or allow

the

operation of such press

unless:

a)

An afterburner system

is installed

and

operated

which

oxidizes at least 90 percent of

the

c~ptured

non-

methane volatile organic materials

(measured as total

combustible

carbon) to carbon

monoxide

and water; or

b)

The

fountainsolutioncontaiq~nc~m9~ethan5ercent

by

weig~it~

of

volatile

organic

mater~l

and

1)

~

and

ated~zhic~~emovesat

lea st~j~J~ercentof~e

vo~ti1eor~n

ic

materials

from

the a:ir~tream

or

2)

The volatile

fraction of

the

ink

as

it

is

applied

~the

web

less

wa

ter

is

25

ercent or

less

bi

volume; or

c)

An

alternative

emission control sy~em

demonstrated

~eatota1reductioneffic~ienceua1to

that

ed

in subsect

ions

(

a) or

(

b

)

abo

ye

NIC C

~~EM

IC

AND

POLYMER

MANUFACTURING

Section

215.420

ç~era1Reuirements

owner

or

ra

Lof

a

lant mc

tur

mt

the

thet ic

59-350

---

or

an

ic ~

~ethan1,50Ocomonentsinasorlihtliuidservice

shall

conduct

leak ins ection

and

re

air

ro rams in

accordance

w

t

th

s

~

~t~,olatileorqanicmaterialasdeterminedbASTMmethod

E~20

~

ea in

if

the

volatile

or

anic

material

concentration

exceeds

~whenmeasuredatadistanceof0cmfromthecomonent.

Section

215

421

~

The

owner

or

operator

of

a

synthetic

orqarii~c~

ci

chemical

o~po1ymer

hufacturing~p1ant

shall prep~e

an

insp~q~o~program

plan which

co!tains,

at

a

minimum:

~j

Anidentificationofall

~

~heachwillbemonitoredursuanttoSection

215~422

~J

~

Section

2l5~423

~j

~

~rsuanttoSection2150422;and

d)

~

~esin

service

and

all

le

akin

c

om onents

sueh

~heareobvioustobothlantersonne1

form-

~sections~

Section 215~422

~2tion

Pro

ram

for

Leaks

~oroeratorofasntheticoranicchemicaloro1er

~acturin1antsub~ecttoSection215~420sha11forthe

~sofdetectinleaksconductacomonentinsection

~ons

is tent

with

the

follow in

r ovis

ions

~j

~

~ture

or

res su

re

and

those

C

om

ne nts

be ated

an

two

meters

above

or

awa

fr

om

ermanent

access

S

t

ructures

or

surfaces b

methods

edure

s a

roved b

the A

enc

I~

~

~ce

urn

seals

ieline

valve s~

rocess

drains

and

cornpressor

seals

by

methods~

~procedures

approved

~y

the

Aq~y~not earlier

than

March

br

later

than

~ofeachear~

59-351

---

c)

Ifmore~an2ercent

of~~on~~

tested

pursuant

—

to subsection

(b) are found

to

leak1

again

test

all

~~sure

relief

valves in

aseous service,

i eline

valves

aseous service

and

compressor

sea.

S

y

methods

and

procedures

approved by the Agency not

~a~l

ier than June

br

later than

S~t emberbof

each

d)

Observe

visua~al

I

______

~

Test_imji~ediate

,

ap~~

seal from

which

liids

are

obsej~ddriin

f)

Test

~

elief

valve

within 24 hours after

it

has

vented

to the atmosphere;

and~

Test

imme~

tel~ afterr

ir an

omppnent

that

~tindleakin~

h)

Ball and plug valves, inaccessible valves,

storage tank

valves,

pumps

eq~4pped

with mechanical seals, pressure

relief

devices

connected to an~irating flare header or

~co~ery

device are exempt from the monitoring

£~m~tsinth

is

Section

Section 215.423

~irira

Leaks

All leakin

corn

onents

must

he

reair2d

and

retested as

soon

as

~poss

be~

ut nol

erthan

22 dasafter

the

leak

is

found

tinless the ~

coin oncut

cannot

be

re

aired

unt.

he

process

uni~

utdown

or

the re air j~t

i~~ed~

Records

of

r~pair~g~ndretesting

must be maintained in

accordance

wfth

Sections

215.424 and 215.425.

Section

215.424

RecoeiriforL~s

a)

The

owneroro~~~ynthetic

o~ganicchemical

or

1

er rnanufacturin

lant shall maintain aleakin

com~~sj~nitor

i~

___

hallcontain~

at

a

~mum~:hefollowin~a~on:

fl

The

narne~gL~erocessunitwe~~2m-

is

beated

~

j~ecfcomn~J~..,valveseal)~

~

~

59-352

---

4)

The

date

on

!~chaleakin

corn

onentis

di~cover~

5)

The

late

2~~i~aleakincomo~ntis

6)

The date and ~

~ed~

~

7)

A

record

~

instr~ merit

8)

The

identif

icat jon

number

of_lead

rig

corn

o—

nents

wiiich

~

unit

~own~

9)

~

hel

number

of

corn

çnents

inspected

and

the

tot a

umbeL~L corn

orients

if ound

leak

in

~

1~)

~9~s

of the moni~~nloshallbe~~nedb

the

owneror.

~

after

the

date

on

which

the

record

was

made

or

the

~reared,

~J

~~sof

the

mon

~n

I

hallbe

made

availab

be

ercv

verbal

or

writ ten

re

ue

St,

at

~1~s2p~able

time.

Section

215.425

Re~or~in~forLeaks

The owner

o~

ernt2r

ofas~~ani~ernicaborol~

manufactu~~g~t

shall

~j

Subrnitar~heAencriort~4he1std~

of

Ju

and

October,

if

necessa~~ting

all leaking

corn

onents identified

ursuant to Section

215.422

re

air ed

with in

22

da

S

al

be

akin

~nts

await in

rocess Unit shutdo~ the

total

of

c em

onents

ins

ccted

and

the

totab

of

e on

o

nents

f

ound beakin

1~

~tasi

r.ed statement

with

the

i~eort

attestin

in

and re airs were

erformed

as

~

Section

215.426

Alte rnative~ggr~~g~Leaks

---

;~erria~-thepi’~.,

~.

~

~

edin

Sections

fl4~0throu~h2i~~

~der~onstr~t~

r

~

the

owner

22~atprofencth

.~

r~itheanter~

.‘~

.~

~~wiji

~

~..

~‘

‘

enc~~j~er~g:

~.

.~

~alentabi3~i~’t

‘~

~

~

~o~~ents.

~

~

.iiv~

an

ci her

~

~.

~Jrr~corin

~

.

.J~i~h:thth:

.,

~~j7rovisi&.

•

tion

Section

215~

427

Cernp~

.~

.~

3ates

and

Gec~

•

~

•~j~j

~

~

...LL~.

.~.

~.

~...

owner

or~7peLator

asvnUet~.

~

~:~hemical

or

~

~.

i

~ectIona

215.420

throuqh

21r.47E

~nali

~~on~p3y~

t~andards

and

1985.

b)

~

~ounties

listed

~

rr

Dr~2~rat

it

~

ehal I

..~

;~uirements

L~

:

~

2lS~420

~nt

io 1ate~

than

~

,

i987:

n~r~

-L

-.

:j,1~

:~r

~

Kane

.,;~,

~.

-~

a

lenakin

notice

,e

..R

____

eon. ~ountv be

re-

it

will

~j

Notwith~thi~

-~

$subeectioriji:L

y

~

~t

~P~n~~me

~~~uent

~.

reefi~ective

••la

i~i

~ç~~on

the

ownero~

~pe~ator

oia~ant

lo~

en

~

that

county

who

(I~oardnz~L~.

~1a

USLPA

~..o:ed

rulemakin~

~

it

will

cubi:.

on

W:LitI~en

Cer~ty s

2194 9~J~a~l(i.

1983)

Shot ld~

:‘

:~

4~nat~d~te

tla

merit

~i9r

it

nn.t

.the

counties-

~::ori

be

cons idere

deleted

from

t~.

---

WOUld

Ot:hert1

~e

h~ !u~j~cttothex~p~

iance

date in

subsec~or

Th,

‘

c~~ithth~

~e

uirements

of

~

cu~215.426withi~f~arrom

the date

o.t

~L

i~nation

but

an

no

na~e later

than

Dc

~k~

~

Section

215~428

Cthra

~.

Plan

a)

The

owner

r

~ar

ic

chemical

229Y~~ m. u~atur~

n~j~alt~

section

t

.L~

t~J~

~

X-~~nt.~

2~~~nIro1atea

t1~

an

Februa ~

~i985,

The

~Wflg~~

~

~

~o

~g~ion

2

15~427(c

sILai1~ubmit ~~iane

~nth

in

90

~

h~d

te

of

~~sinaj~

o

inno

case

later_th&

Dec~mbc

r

31~1986.

c)

The ow

or

or

~c

ton

o~

t

~t

to

Section

215~

427(c

shall

n.t

be

req

ired

tc

~

t~~liance

~~renearg~p.atIono~curs_af

to

1)

r~1986.

d)

~

arid

schedu Ic

shall

meet

of

35

Ill.

Adr~,

ethe

ntl.

SJ~P~rT I

COKt

MMTJFAtI.

i”~

~.cr

P2CC’

R’

Section

215.500

E

~t

~

-

~

~aaltoc~)c~

~

-

u~r~~j~’an

Sect ion

215~5l0

Cobe

,~Product

Recovei~

Plan

~

Cr

~

reduce the

UricontioliLd

~maaeiona

of

volatr~

aa-~ac

materials

TIL

fl~Th~

~

a)

Tar

decant

~

th~

oh

~e

a

~e~~gt

lc~

~selusedto

~~te

t~-

a

~ id

flu

hir ~

~g~or

bj

rnaans

of

~~t;

b)

~~oi)aurr~

wti~~treceive’~asthx’~

f

m

tue

ii

~t

oil

racov~

portion

of a coke

Len

V~-ry~

lant,

c)

~

oii

o~~d4.

r/~para~ r~

r

~

a

device

used

toconde.~:e.

~-

~ar-~

lutt

~t

-

ach

the

non-

---

d)

Tarcondentesarr~whichreccIvtF

.,.~condensate

streana

~L’~tne

tar

reco~pi~E~.

Section

215.512

d~

~ProJuctPhantLca~

a)

The ownc.

a

a

facoke

~

a

t~~~er

pj~~

I

.

ai~L~L~

L1~2~

~~zed

~

~ta~~ir

of leaa~

~

C~~iriritr,_in

li~i

.~1~id

service.

rite

in

coke

oven

as

lii

eeoeratin

flare

headers

or

vapor

recoy~y~

devi,

at

fromthein~~,e..tae~

~

~J

Incondw

I.

uch

p~~~tt

‘~

L~~atorof

acokebv—j

a

~u~ct

~

~L’

1)

e

e~i

ndc~riri~uctaweeklj~

tio3~~

cons

i~

te~~i

h~jrova~ior

ri ~

~ction

215

313.

2)

Reca~

a1lvsiblebeakin~

c~

j~u

z~r~ic~

and ideathy ~

leakar

consistent

with

the

ii

215,

~

3)

P~

~.

La.

L~ooori~L

—

abL

~

,u~a

then

22

de

is

I

as

trio

~e~k

i

be

rat ut

d

tit,

ten unit ie

2!~lt5rC~~

to correct the J~

Section

215.513

Ins1ent~m ao~ram

t

~1ih~il

~tobserved

.~rsof

Section

1Lh~

!9~ic

~.

ten

leak

~.

~r~t

cannot

Y

dor~r or until

ctC

available.

~nerorp~ratoa

~

~

~eçueandcan~.

~uin~!ction

~hic~a~

aLuari& r~ha~~uixetn..

ror2~~or

~j

Observe via xalt~act leaketrom all

cu

imoone~b~ect

to

SE

~

2

onaweek~bas

c;

~J

~~ifal~eahi

g

an

ntes

t

~nej~

,are

obvious

t9~p1ar4-~

~

cvuaiin~2~~

tions

and

Aqen~yheraconel

porfouu

j~ertion~~

c)

Recodinthenoni*auingbop~tIe

a~

~~‘oi

for

each

leakin~j~.nneu.

ri~.

‘u~uiredb

~L

rcionsof

Section

21

.~14

to:

---

Section_215~5l4 Recordk~i~1Requirements

a)

The

owner

or

op~at

fa

coke

b—

rd

trecove

p

hal.

maintain a no itori~g~j~p

that

S

hail con-

~

for

each

corn-

~tfoundleaki~

1)

The

name

of

th~p~oeess

unit

where

the

observed

Ia akinq

C

nt

is

bc ated

~

~

3)

The dateo

rich the leakin~ ocr

nent is

first

observed;

4)

The

do to

on

whighale

akiomppt

is re

aired

;

5)

~

~

and

6)

Identification

corn onent lets which are not

~ir

within

22 da

S

af tea

di scove

be ause

of

the

~

the

date

the

r~ir

part

was

ordered

arid

the

date

the

repair

j~~artwas

received,

b)

The

~ndaorinq~l~shaU

be

-

rtdaned~ytheowne~r

~

ator foramininum of two yp~s attar the date

on

which_the

record

was

made,

c)

~es

of the monitorin

shall be made avaliable

to

~

rcason-

able

time.

Section

215.515

~portin~r~pts

~bant

shall

~

inq~~~~li

torin

and

airs

were

erfo

med

as

re

~

under

Sect ion

o

if it at

~a

and

Au

ust

of

aach

e

ar

Section

215.516

~

~

eror

car

of

an

emission

source

su~j~to

Section

215. 510

throu~

21~514

shall

~gppJ~y

with

the

standards

andlimitationshLDecembe~~985~~

---

-~18--

Section

215.517

C9pp~a~rceP~n

~eroroeratorofafacilitorernissionsourcesubect

to

~

ctcometi~edulebJul11985~

59-358

---

—19—

APPENDIX

D

LIST

CF

CHEMICALS

DEFINING

SYNTHETIC

ORGANIC

CHEMICAL

AND

MANUFACTURING

~

!~!i~J.

0CP08

140.

Ch~1

cal

20

Acetal

230

~ainoethylethanolardfle

30

Ac~yde

235

p-a~minophenol

40

Acataldol

240

~yl acatates

SO

Acetamlde

250

~aylalcohols

55

Acetaniflde

260

~yl

amine

70

Acetic acid

270

~ayi

chloride

80

Acetic anhydride

280

ksyi

mercaptans

90

Acetone

290

~iyi

phenol

100

Acetone cyanohydrin

300

AMline

110

Acetonitrile

310

AnIline hydrocMOrlde

120

Acetophenone

320

AMsidine

125

Acetyl cMorlde

330

Anisole

130

Acetylene

340

Mthranillc acid

140

Acr~leir~

350

Anthraqul

none

150

AcryleMide

360

8enzaldehyde

Acrylic scid and esters

370

170

Acrylonltrile

380

Annzene

180

Adipic acid

390

B~anzenedisulfQflic

acid

LBS

Miponitriie

400

8enzenesulfonic

acid

190

Mkyl naphthalefles

410

~OO

Allyl ~lch~hol

420

genziflc

acid

210

Allyl chloride

430

~enzc1c

acid

220

~inoben~0iCacid

440

*The

OCPDB

Numbers

are

reference indices

assigned. to

the

various

chemicals in the Organic Chemical Producers

Data Base

developed

by the USEPA.

59-359

---

cc~os

~

~os

~.

~1i~J

450

860

*—chlorianIllne

460

8er7opnenone

970

p—ch~oroaniline

480

9er~otr1

c~

I

or ide

880

ch~

orodenzaldehyde

490

8enzoy~chlc~rIhe

890

Ccrohen~ane

500

Seozyl

~lcchol

900

CMoro~enzo1c

acid

510

Benzyl

waine

905

iorob~nzotrlchloride

520

Beozyl

ben~oate

910

Ch~benzoyi

chloride

530

Senzyl

chloride

920

ChiorodIfluo~oethane

540

Senzyl

dlchioride

921

ChiorodIf1uor~nethane

550

Slphanyl

930

CMorofo~n

560

8isphenol

A

940

CMcronaphthalene

570

Br~benzene

950

o~cMcritr~ben~ene

580

5r~naphtha~

ne

953

Iii

rcn1tro~enzene

590

8utadlena

960

C~l~cpher~ols

592

1—botena

964

Chioro~rene

600

n-buty~

acetate

965

~orosulfonic

acid

630

n-botyl

ccrylate

970

e~—chiorotol~ene

640

n-butyl

alcohol

950

chl~rotcluena

650

~—butyi alcohol

990

c~ltouana

660

t—bu~ylalcohol

992

Olrctr1f1unrc~ethane

670

n—butyiaaine

1000

a~creaol

680

s-butylamine

1010

690

t—butyiamine

1020

700

p-tert-botyi benzoic

acid

1021

~ftzed crasola

110

1~3—butyiene

glycol

1030

Cmyllc

acid

750

n-botyraldehyde

1040

Crotonaidehyde

760

8utyrlc acid

1050

Crotonic

acid

770

8utyrlc

anhydride

1060

C~ne

780

Sutyronltrile

1070

C~oehydroparoxide

785

Caprolact~

1080

i~yanoacatIc

acid

790

Carbon

disulflde

1090

Cyano~en

chloride

800

Carbon

tatrabr~e~lde

1100

Cyanuric

ac~d

810

Carbon

tetrachluride

1130

Cyanuric

chloride

820

Celi~lo~~

acetate

1120

Cyloha~ana

840

Chioroecetic

acid

1130

Cycloharanol

850

m-chloroanilioe

1140

Cyclohe~anone

59-360

---

~D8

Plo.

Chea~ical

1150

~yc1ohexene

1495

Dimethylhydruine

1260

Cyclohexylamine

1500

Otrothyl

au~fate

1170

Cyclooctadiene

1510

9An4t4y1

~u1i9de

1180

Oecanol

15(~0

Sirathyl

sul?Dx~de

1190

Diacetone

alcohol

1530

04a~thylterephthalRte

1200

Diaminobenroic

acid

1540

3,5—dinitrobenzeic

acid

1210

Olchloroenilinl?

1545

l3io1trO~,benol

1215

w,-dichlorobenzene

1550

Cirltrotoluene

1216

e—dlchl

orobeneene

1560

01oxena

1220

p.dichloroben~ene

1570

1221

D1ch~orodi

F

luorotaethana

1580

Ciphanyl a~ai

no

1244

1,2—dfchloroethane ~E0C)

1590

C1phar~yi oalde

1280

Dichloroethyl

ether

1600

CIphenyl

thiourea

1250

Dichlorohydrin

1620

Cthrcoylene

glycol

1270

Dichioropropena

1629

~odecena

1280

Di

cyc)ohexylemine

1630

rd?evianlllne

2290

Diethylamlne

1640

dt~cyi

phenol

1300

Diethylene

glycol

1650

Epichlorohydrin

1304

Dlethylene giyc~ldiethyl

ether

1660

1305

Diethylene

glycol

dimethyl

ether

1661

Lthenola~inea

1320

Diethylene gly~ol~nobutyl

ether

1670

Ethyl

acetate

1320

Dlethylene glycol

monbutyl

ether

acetate

2683

Ethyl

ecatoacatate

1330

Diethylene

glycol

~onoethyl

ether

2690

E2CYI

ecrylate

2340

Dlethylene glycol ~aonoethy1

ether acetate

1700

Ethyl

1360

Dlethylene

glycol

moncmethyl ether

1710

EtEylben~ene

1420

Diethyl

sul~ete

1720

Ethyl

bromide

1430

Difluoroethane

1730

Ethylcallulose

3440

Dlisabutylene

1740

~thyl

chloride

1442

Diisodecyl

phthelate

1750

Ethyl

chloroacetate

3444

D11soocty~phthalata

1760

Ethyicyanoacetate

3450

Diketene

17)0

Ethylene

1460

Dlmethylamine

1790

Ethy3~anecarbonate

1470

N~Pl—d1emthylaniI1ne

1793

Etkt~lenochl*rohydrfn

1480

fl,14—di~nothylether

1800

hyianedi~aine

1490

$,N-dimethylfor~nomide

1810

Ethylene

dtbr~ide

2830

Ethylene

glycol

59-361

---

—22—

~

~cal

~

1880

Ethylene

glycol

diacetate

2300

hodecanal

1870

Ethylene

glyc~1dinethyl

ether

2320

ieooctyl

alcohol

1990

Ethylene

glycol

nenobutyl

ether

2321

leopantane

1900

Ethylene

glyC~i

monobutyl

ether

acetate

2330

hopberone

1910

Ethylene

~lyco1nonoethyl

ether

2340

hophthalic

acid

1920

Ethylene

giycol

nonoethyl

ether

acetate

2350

1930

Ethylene

91yc01

nonomethyl

ether

2360

isopropanol

1940

Ethylene

glycol

aarrnueethyl

ether

acetate

2370

Isopropyl acetate

1960

Ethylene

glycol

nonophenyl

ether

2380

lsoprDpy1~ine

1970

Ethylene

glycol

nonopropyl ether

2390

Isopropyl

chloride

1980

Ethylene

ozlde

2400

isopropylphenol

1990

Ethyl

ether

2410

2000

2—ethylhexanol

2414

LInear alkyl

sulfonate

2010

Ethyl

orthofc,iaate

2417

LInear

elkylbenzene

2020

Ethyl

ozalate

2420

PlaleIc

acid

2030

Ethyl

sodlue

oxalacetate

2430

Meleic

enhydride

2040

Fonealdehyde

2440

hello

acid

2050

Porommide

2450

Plasityl

oxide

2060

Fo~a1c

acId

2455

Metanllic

acid

2070

F~eaar1cacid

2450

Methacrylic

acid

2073

Furfural

3490

Methallyl

chloride

2090

Glycerol

(SynthetIc)

3500

Methanol

2091

Glycerol

dichlorohydrin

2510

Methyl

acetate

2100

Glycerol

trlether

2520

Methyl

acetoacetate

2110

Glyclne

2530

Methylaeir*

2120

Glyoxal

2540

e4aathylanlline

2145

Hexachlorobanzeae

2545

P~thylbromide

2150

Kexechlorcethane

2550

Methyl

butynol

2160

Nexedecyl

alcohol

2560

Methyl

chloride

2165

Nexomethyienedlaeine

2570

Methyl

cyclohexane

2170

I4ex~ethylene

glycol

2590

Methyl

cyclohexanone

2180

Nexanethylenatetremlne

2620

Methylene

chloride

2190

hydrogen

cyanide

2530

Methylene

dianiline

2200

ilydroqulnane

2535

Methylene diphenyl

dli

e~seate

2210

p—hydroxybenzolc

acId

3640

Methyl

ethyl

katcee

2240

Isoenjiene

3644

Methyl

fo~te

2250

hobutenol

2650

Methyl

Isobutyl

c*rbinol

2260

Isobutyl

acetate

2660

Methyl

i~obutylketone

2261

Isobutylene

2665

Methyl

nothacrylate

2270

Isobutyraldehyde

2670

Methyl

pantynol

2280

!aobutyrlc

acId

2690

a

~nethylatyrene

59-362

---

—23—

~

~caj

2700

Nerpholina

3000

Polybutenea

2710

~~naphtha

lane

sulfonic

acid

3010

Polyethylene

glycol

2720

8~naphthaleflesulfonic

acid

3025

Poiynrop~laneglycol

2730

~-naphtnol

3063

Propionaldehyde

2740

~-naphthol

3066

Proplonic

acid

2750

Pleopentanoic acid

3070

n~i~ro~l

alcohol

2756

o-nltro~niline

3015

Propy~amthe

2157

p~n1troaniline

3080

Propyl

chloride

2760

o-nitroenisole

3090

Propy~ena

2762

p—nitroanlsole

3100

Propylene

chlorohydrin

2170

hitrobenzene

3130

Propylene

dIchloride

2780

Plitnobentoic

acid

~

m,

and

~)

3111

Propylene

qlycol

2790

hitroethane

3120

Propylene

oxide

2791

Plitromethane

3130

Pyridi~e

2792

PlitrophCflOl

3140

2795

PlitropropanC

3350

R~~~rcinol

2800

$itrotoleune

3160

9a~o~cyl

~:

acid

2810

Nonene

3170

SaliLyl~cacId

2820

Plonyl

phenol

3180

Shalom

acetate

2830

OCtyl

phenol

3181

Sodi~rdenzoate

2840

Paraldehyde

3190

SoCiom carbozynethyl cellulose

2850

Pentaerythri

tol

3191

tod~um

thloroacetate

2851

n—pentane

3200

Sodiun

foricata

2855

1—pentene

3230

$odi~a

~henate

2850

Perchloroethylefle

3290

Sort~acId

2882

Perchloronethyi aaercaptan

3230

2890

o~phenetidine

3240

Succinlc acid

2900

p.phenetidine

3250

c~1omtri1e

2910

Phenol

3251

SuifanIlic acid

2920

Phenol&fGnic acids

3260

2930

Phenyl

anthrenilic

acid

270

lannic

acid

3280

Tarephthaiic

acid

2940

PhenylenedIami no

2950

Phosgene

3290

&

3291

Tetrechloroethanes

3300

~laareonlornphthal

Ic anhydride

2160

Phthalic anhydride

3310

Tetvaathyl

lead

2970

Phthalimlde

3320

Tetrahydronaphthalene

2913

~—picol

Inc

3330

7~trahydrophthaiiC

anhydride

2976

Piperazine

3335

tetreaxathyll~~d

59-363

---

0CP05*~

Chomica~

3340

Tetraoathyieoadiamine

3341

Tetrcuethyiathylenadlamine

3349

Toluene

3350

Tolueoa~2~4-dlae1ne

a4ethy

tert—butyl

ether

3354

toiuene-2

,1~d1

I socyanate

Polyethylene

3355

To~uene

dilsocyanates (mixture)

3360

Tohiene

sulfonamide

Polystyrene

3370

Toluane aulfonic acids

3380

Toluene

suifonyl

chloride

3382

1~luidInes

3390,

3391

lrlchlorobenzenes

~3393

3395

1j

~1-trichloroetnane

3400

1~i~2~trich1oroethane

3410

Trichlorot

~ylene

3411

TrIcilorofl~ioroinethene

3420

1 ,2~3~trlchlcropropane

3430

1

~3~2~crichioro~1,2,2—trIfluoroethane

3450

TrI~tiei~r~e

3460

Triethylene

glycol

3470

Idathylena gylcol dimethyl

ether

3480

TrIIs~hatylane

3490

Trlmethylamine

3510

Vinyl

acetate

3520

Vinyl

chloride

3530

VInyliCane chloride

3540

VINyl

toluene

3541

Xylene lathed)

3560

o-zylene

3570

3580

lylenol

3590

Xylidino

59-364