ILLINOIS POLLUTION CONTROL BOARD

November 21,

1984

IN THE MATTER OF:

)

FIAZARDOUS WASTE LISTINGS AND TEST

)

R84-34

METHODS FOR TUE IDENTIFICATION OF

)

TETRACHLORODIBENZO—p-DIOXINS

FINAL RULE.

OPINION

AND

ORDER

OF

THE

BOARD

(by

J.

D.

Dumelle);

Public

Act

83—1235,

which

became

law

on

July

30,

1984,

contains the following mandate for the adoption of Board

regulations.

“Section 22.4

(d)

The Board shall

adopt regulations within

120

days

after the effective date of this amendatory

Act

which

list tetrachlorodibenzo-p-dioxins as

hazardous wastes and which provide test methods

for

identifying

the

presence

of

tetrachlorodibenzo-

p-dioxins in

waste

unless

a

federal

regulation

listing such dioxins as hazardous wastes and

establishing test methods has been promulgated by

the U.S. Environmental Protection Agency prior

to

adoption

of

such

regulations.

Any

such

federal

regulations adopted p.lrsuant to subsection

(a)

shall

supersede

Board

regulations

adopted

~irsuant

to this subssaction.

The provisions of Title VII

of this Act and Section

5 of the Illinois Admin-

istrative Procedure Act shall not apply to

regulations adopted ~irsuant to this subsection.”

(Ill.

Rev.

Stat.

1984,

ch.

111½ par.

1022.4.)

This language evinces

dual. legislative ~iirposes. It

demonstrates

an

intent

to

list

these

dioxins

as

hazardous

wastes and adopt test methods under Illinois law

as quickly as

possible,

and,

in addition,

an intent to have these listings

and test methods conform to any

federal

rule

on

the

same

subject.

The

effect

of

this listing is to require handlers of

wastes containing these dioxins to comply with the Board’s

hazardous

waste

regulatory

standards.

A

federal

rule

contain-

ing

a

listing

and

test

methods

for

tetrachlorodibenzo-p-dioxins

(as

well,

as

other

listings)

was

proposed

on

April

4,

1983

in

the Federal Register.

At the time that P.A.

83—1235

was

enacted,

61-247

---

2—

it was anticipated that the U.S. Environmental Protection

Agency

(U.S.

EPA) would complete its proposed rulemaking and

adopt a

final rule listing these dioxins as hazardous wastes

~,eryshortly.

However,

as of this date,

U.S.

EPA has in-

dicated that a final rule will not be published before early

1985.

P.A.

83—1235 must be interpreted as having foreseen the

possiblity that final

federal rulemaking would be delayed.

In

the

elent

of

such

a

delay,

the

statutory

language

requires

that Board rules be adopted by November

27,

1984 to meet the

immediate concern

about the regulation

of dioxins and to breach

the “gap” until

federal regulations are adopted.

In an effort to address the dual intent of

P.A.

83-1235,

the Board on its own motion proposed that the federal proposal

which was published in the Federal Register on April

4,

1983

(48 Fed.

Reg.

14514—14529) be adopted as an Interim Rule, bit

only

in

so far

as it relates to tetrachlorodibenzo—p-dioxins.

The logic underlying this approach is obvious.

As

a rule

which is “ear-marked”

to be

superseded in the near

future,

this rule should parallel the anticipated final

federal

rule

as closely as possible

in order to minimize disruption

of the

system once a final rule is promulgated,

The April

4,

1983

proposed federal rule is our best information

as to the con-

tent of the final

federal

rule.

The April

4,

1983 proposed federal rule addressed signi-

ficantly more than the listings and test methods the General

Assembly instructed the Board to adopt

in this rulemaking.

For example,

the federal proposal

listed chlorinated dibenzo-

furans as well as many more isomers of dioxin than are

encompassed by the tetrachlorodibenzo—p-dioxin

structure.

In

addition,

the federal proposal prescribed special

“RCRA”

operating standards for

the

handling

of

wastes

containing

these

materials.

In

todays

action

the

Board

adopts

only

that

portion

of

the

federal

proposal

which

is

necessary

to

accomplish

the

purposes of PA.

83-1235,

i.e.,

the portion relating to the

listing and test methods for tetrachlorodibenzo-p-dioxins.

This requires amending

four

sections

and

three

appendices

of

the

Illinois “RCRA” rules,

as well

as the adoption

of a new

Appendix

I containing the test method.

The Board notes that P.A. 83—1235 provides that neither

the rulemaking provisions of the Illinois Administrative Pro-

cedure Act nor Title VII of the Illinois Environmental

Protection Act apply to this rulemaking.

The “waiver” of

these procedures,

as well as the limited review period,

support the position that full Board review of the merits of

the federal proposal was not intended.

Nonetheless,

the Board

gave notice of its intended action in the Environmental

Register,

as well as to persons on

an extensive notice

list,

and provided 30 days for public comment.

61-248

---

Four

comments

were

received

during

or

shortly

after

the

close

of

the announced comment period.

All motions and requests

to

file

comments

Instanter

are

granted.

Each

of

these

is

dis-

cussed

below.

The Illinois State Fabricare Association

(P.C.

#1)

pointed out that the wording of the April

4,

1983 federal

proposal

(which is parallelled

in the Board’s October

12,

1984 proposal)

implies that the small

quantity exclusion for

acutely hazardous wastes

(i.e.

1 kilogram) would now apply to

all matsrials listed in Sections 721.131 and 721.132,

as well

as the P list contained in 721.133(e).

This would extend

the

effect of that very limited exclusion for acute

hazardous

wastes to a number of wastes that are listed in Sections

721.131 and 721.132

for reasons other than acute toxicity.

e.g. ignitability, toxicity, reactivity,

corrosivity.

The

proposed language

in Section 721.105(e)(1), the small

quantity exclusion for acute hazardous wastes, refers to

“acute

hazardous wastes listed in Sections 721.131, 72i.i32~

or

721.133(e)”.

To

avoid

enlarging

the

effect

of

this

proposed

amendment beyond the scope

of

either

this

rulemaking

or

the

federal

proposal,

one must interpret this phrase

as meaning

that only those materials

in Sections 721.131 and

721. 132

which are identified as “acute hazardous waste” are subject to

this particular exclusion,

Clarifying language has been added

to remedy this problem.

The

same

question

was

raised

by

Chemical

Waste

Management,

Inc.

(P.C.

#4) regarding Section

721.107(b)(3), which addresses

residues in empty containers,

Again,

the reference to Sections

721.131 and 721. 132 in this section is confusing and could

be

interpreteted as going beyond “acute hazardous wastes”.

CiarlEy-

ing

language

has

been

added

to

this

section

as

well.*

Chemical Waste Management’s comments also address two

other points that they preceive to be logical deficiencies

in

the federal proposal,

i.e.

the decontamination of equipment

referred to in F022 and the exclusion

of wastewater and spent

carbon from hydrogen chloride purification.

While these may

be

valid

points,

the

record

before

the

Board

in

this

proceedinq

has

inadequate

technical documentation to support that deter-

mination.

Finally,

the

Board

received

a

comment

from

Marcia

A.

Kuehi

of the

U.S.

Environmental

Protection

Agency,

Region

V,

*Ilinois

Power Company (P.C.

#3) pointed out a typo-

graphical error

in this same section

(721.107(b)(3)) involving

the

inadvertant

dropping

of

the

word

“acutely.”

The

Board

regrets

this

error

which

certainly

may

have

increased

confusion

as

to

the

scope

of

this

Section.

61-249

---

—4—

Environmental Services Division

(P.C. #2),

on the adequacy of

Test Method 8280.

Ms.

Kuehi points out that

a more precise

method is “due out” within the month.

She also notes that

certain steps in the method relate only to dibenzofuran detection

and could be deleted for purposes of tetrachlorodibenzo-p-dioxirt

detection.

The Board very much appreciates Ms.

Kuehi’s review

of this particular aspect of this rulemaking.

Unfortunately,

the Board is statutorily required to act in this rulemaking by

November 27,

1984.

Promulgation of a new federal rule

on Method

8280 is likely to require a new federal

proposal and to take

six

months

to

a

year.

Once

such

a

change

is

promulgated

as

a

federal

rule,

the

Board

is

authorized

and

required

to

adopt

it

as a superseding method.

(See Ill. Rev.

Stat.

1983,

ch.

111½,

pars.

1022.4(a)

and

(c).)

Therefore,

the language

of Method

8280 as proposed in the April

3,

1984 Federal Register, which

remains

our

best

information

as

to

the

content

of

the

final

federal

rule,

is

adopted

herein.

The Board recognizes that Method 8280 was designed to

detect

a

broaderrange

of

contaminants

than

simply

tetrachlorodibenzo-p-dioxins.

However,

the

Board

believes

it

is

wiser

to

leave

this

highly

technical

method

“intact”,

rather

than

to

make

revisions

without

a

thorough

technical

record.

Footnote

#1

to

Method

8280

states

that

“this

method

is

appropriate

for

the

analysis

of

Tetra-,

penta-

and

hexachlorinated

dibenzo-p—dioxins

and

dibenzofurans.”

This

rulemaking

authorizes

the

use

of

this

methodology

for

the

detection

of

tetrachlorodibenzo-p-dioxins.

At

this

time,

there

is no need to utilize the provisions which are designed

to

detect

other

contaminants.

ORDER

The

Board

hereby

orders

that

the

text

of

Part

721

and

accompanying

Appendices

be

amended

as

follows:

1.

Section 721.105

is amended

as follows:

Section

721. 105

Special Requirements for Hazardous Waste

Generated by Small Quantity Generators

a)

A generator is

a small

quantity generator in

a calendar month

if he generates less than 1000 kilograms of hazardous waste

in

that

month.

Part

700

explains

the

relation

of

this

to

the

100

kg/mo

exception

of

Chapter

9.

b)

Except

for

those

wastes

identified in paragraphs

(e)

and

(f)

of this section,

a small quantity generator’s hazardous wastes

are not subject to regulation under Parts 722 through 725 and

40 CFR Parts 122 and

124,

and the notification requirements

of

Section

3010

of

RCRA,

provided

the

generator

complies

with

the

requirements

of

paragraph

(g)

of

this

section.

61-250

---

-.5—

C)

Hazardous waste that is beneficially used or re-used or

legitimately

recycled

or

reclaimed

and

that

is

excluded

from

regulation by §721,106(a)

is not included in the quantity

determinations of this section,

and is not

sub-ject

to

any

requirements of this section.

Hazardous waste that

is subject

to the special requirements of §721.106(b)

is included in the

quantity determinations of this section and is subject to th~’

requirements of this section.

d)

In determining the quantity of hazardous waste he generates,

a

generator

need

not

include:

1)

His hazardous waste when

it

is removed from on-site

storage;

or

2)

Hazardous waste produced by on-site treatment of his

hazardous waste.

e)

If a small quantity generator generates acutely hazardous

waste

in a calendar month in quantities greater than set

forth below,

all quantities of that acutely hazardous waste

are subject to regulation under Parts

722 through 725 and

40 CFR Parts 122 and 124,

and the notification requirements

of Section 3010 of RCRA:

1)

A total

of one kilogram of ~

~

ates-~—~e

~

4n

~

~

hazardous

wastes

which

are

identified

as

acute

haz-

ardous wastes

(H)

in Sections 721.131,_721.13~7or

721.133(e)

or

2)

A total of 100 kilograms of any residue

or contaminated

soil, water or other debris resulting from the clean—up

of

a spill,

into or on any

land

or

water,

of

any

~

e~

~

~

~

~

~

~

haz-

ardous wastes which are identified as hazardous

wastes

(1~T

in Sections 721.131, 721TT~6F72T.133(e).

f)

A small

quantity generator may accumulate hazardous waste

on-site.

If he accumulates at any time more than

a total

61-251

---

—6—

of

1000

kilograms of his hazardous waste,

or his acutely

hazardous

wastes

in

quantities

greater

than

set

forth

in

paragraphs

(e)(1)

or

(e)(2)

of

this

section,

all

of

those

accumulated

wastes

for

which

the accumulation limit was

exceeded

are

subject

to

regulation

under

Parts

722

through

725 and 40 CFR Parts 122 and

124,

and the notification

requirements of Section 3010 of RCRA.

The time period of

§722. 134 for accumulation

of wastes on—site begins

for

a

small quantity generator when the accumulated wastes exceed

the applicable exclusion level.

g)

In

order

for hazardous waste generated by

a small quantity

generator to be excluded from full regulation under

this

section,

the generator

crust:

1)

Comply

with

§722,111;

2)

If he stores his hazardous waste on—site,

store

it

inì

compliance

with

the

requirements

of

paragraph

(f)

of

this section;

and

3)

Either treat or dispose of his hazardous waste

in

an on—

site facility,

or ensure delivery to

an off-site

storage,

treatment or disposal

facility, either of which

IS:

A)

Permitted under

40 CFR Part 122;

B)

In interim status under Part 725 and 40 CFR Part

122;

C)

Authorized to manage hazardous waste by a State

with a hazardous waste

management program aporoved

under

40 CFR Part 123;

D)

Permitted,

licensed or registered by a State

to

manage municipal

or

industrial

solid waste;

or

E)

A facility which:

i)

Beneficially uses or re—uses,

or legitimately

recycles or reclaims his waste;

or

ii)

Treats his waste prior to beneficial use

or

re—use,

or legitimate recycling or reclamation.

h)

Hazardous waste subject to the reduced requirements of this

section may be mixed

with

non—hazardous

waste

and

remain

sub-

ject

to these reduced requirements even though the resultant

mixture

exceeds

the

quantity

limitations

identified

in

this

section, unless the mixture meets any of the characteristics

of hazardous wastes identified in Subpart C.

61-252

---

—7—

i)

If

a small

quantity generator mixes

a solid waste with

a

hazardous waste that exceeds a quantity exclusion

level of

this section,

the mixture

is subject to full regulation.

~Source.

Amended

at

6 Ill.

Reg.

4828, effective

as noted

in

5700.106; amended at

__Ill. Reg.__,

effective

.)

2.

Section

721. 107 is amended as follows,

Section 721.107

Residues of Hazardous Waste

In Empty

Containers

a)

1)

Any

hazardous

waste

remaining

in

either

an

empty

container

or

an

inner

liner

removed

from

an

empty

container,

as

defined

in

paragraph

Eb

of

this

section,

is

not

subject

to

regulation

under

Parts

721

through

725

or

40

CFR

Part

122

or

124

or

to

the

notification

requirements

of

Section

3010

of

RCRA.

2)

Any hazardous waste

in either a container that

is

not empty or

an inner

liner removed from a container

that is not empty,

as defined in paragraph

(b

of this

section,

is subject to regulations under Parts 721

through 725 and 40 CFR Parts 122 and 124 and to the

notification requirements of

Section 3010

of RCRA.

b)

1)

A

container

or

an inner liner removed

from a container

that has held any hazardous waste,

except a waste that

is compressed gas or that is identified ~n—See~e~

~

as

an acute hazardous waste

(H)

in

Sections 721.131, 721.132,or721.133(e),

is empty if~

A)

All wastes have been removed that can

be removed

using the practices commonly employed to remove

materials

from that type of container,

e.g.,

pouring,

pumping,

and aspirating,

and

B)

No more than 2.5 centimeters (one inch) of residue

remain on the bottom of the container or inner

liner.

2)

A container that has held a hazardous waste that is

a compressed gas is empty when the pressure

in the

container approaches atmospheric.

3)

A container

or

an inner liner removed from a container

that has held a hazardous waste ~

which is identified as

an acute hazardous waste

(H)

in

Sections 721.131, 721.132

or 721.133(e)

is empty if~

61-253

---

8—

A)

the

container

or

inner

liner

has been triple rinsed

using

a

solvent

capable

of

removing

the

commercial

chemical product or manufacturing chemical

intermediate;

B)

the container or inner

liner has been cleaned by

another method that has been

shown in the scientific

literature,

or by tests conducted by the generator,

to achieve equivalent removal; or

C)

in the case of a container,

the inner liner that

prevented contact of the commercial chemical

product or manufacturing chemical intermediate

with the container,

has been removed.

(Source:

Amended at 6

Iii,

Reg.

4828,

effective as noted

in

§700.106; amended at

_______

Ill.

Reg.

effective

.)

3.

Section 721, 131 is amended as follows:

Section 721.131

Hazardous Wastes From Nonspecific Sources

Industry

and

EPA

Sazardous

Waste

Hazard

code

hazardous

waste

No.

Generic;

POOl

The following spent

halogenated

solvents

used

in

degreasing:

(T)

tetrachloroethylene,

trichioroethylene,

methylene

chloride,

1,1 ,1—tr ichl

oroethane,

carbon

tetr achloride,

and

chlorinated

fluorocarbons;

and

sludges

from

the

recovery

of

these

solvents

in degreasing

operations.

P002

The following

spent

halogenated

solvents:

tetrachioroethylene,

(T)

methylene

chloride,

trichioroethylene,

1, 1,

1—trichioroethane,

chlorobenzene,

1, l,2—trichloro—l,2,2-trifluoroethane,

ortho—

dichlorobenzene,

and

trichlorofluoromethane;

and

the still

bottoms

from

the

recovery

of

these

solvents.

P003

The

following

spent

non—halogenated

solvents:

xylene,

acetone,

ethyl

(I)

acetate,

ethyl

benzene,

ethyl

ether,

methyl

isolxtyl

ketone,

n—botyl

alcohol,

cyclohexanone,

and methanol;

and

the

still

bottoms

from

the

recovery

of

these

solvents.

P004

The

following

spent

non—halogenated

solvents:

cresols

and

cresylic

(T)

acid,

and

nitrobenzene;

and

the

still

bottoms

from

the

recovery

of

these

solvents.

P005

The

following

spent

non—halogenated

solvents:

toluene,

methyl

ethyl

(I,

T)

ketone,

carbon

disulfide,

isoxitanol,

and

pyridine;

and

the

still

bottoms

from

the

recovery

of

these

solvents.

P006

Wastewater

treatment

sludges

from

electroplating

operations

except

(T)

from

the

following

processes:

(1)

sulfuric

acid

anodizing

of

aluminum;

(2)

tin

plating

on

carbon

steel;

(3)

zinc

plating

(segregated

basis)

on

carbon

steel;

(4)

aluminum

or

zinc—

aluminum plating cc carbon steel;

(5) cleaning/stripping

associated with tin,

zinc

and

aluminum plating on

carbon

steel;

and

(6) chemical etching

and

milling of aluminum.

P01.9

Wastewater treatment sludges from the chemical conversion coating

(T)

of aluminum.

P007

Spent cyanide plating bath solutions from electroplating operations

(R,

T)

(except

for

precious

metals electroplating

spent

cyanide

plating

bath solutions).

P008

Plating bath sludges

from

the bottom of plating baths from

(R,

T)

electroplating operations where cyanides

are

used

in

the process

(except for

precious

metals electroplating plating bath sludges).

61-254

---

9—

Industry

and

EPA

——

Hazardous

Waste

Hazard

code

hazardous

waste

No.

_______________

_________

______________________________________

Generic.

P009

Spent

stripping

and

cleaning

bath

solutions

from

electroplating

(R,

T)

operations where cyanides

are

used

in the

process

(except for

precious metals electroplating

spent

stripping and cleaning bath

solutions).

POlO

Qienching bath sludge from oil baths from

metal

heat

treating

(R,

T

operations where

cyanides

are

used

in

the

process

(except

for precious metals heat-~treatingq~ienchingbath sludges).

P011.

Spent cyanide solutions

from salt bath

pot

cleaning from

metal

(R,

T)

heat treating operations (except

for

precious

metals heat

treating

spent

cyanide solutions from salt bath

pot

cleaning).

P012

~enching wastewater treatment sludges from

metal

heat treating

(T)

operations

where

cyanides

are

used

in

the

process

(except

for

precious

metals

heat

treating

qienching

wastewater

treatment

sludges).

P020

Wastes

(except

wastewater

and

spent

carbon

from

hydrogen

(H)

chloride

pirification)

from

the

production

or manu-

facturing use (as

a

reactant,

chemical

intermediate,

or

component

in

a

formulating

process)

of tri~-, tetra—,

~~entachlorophenol

or

of

intermediates

used

to

produce

~their

derivatives.

tThis

‘isting

does

not include wastes

from

the

production

of Rexachlorophene from highly pirified

~

5—trichlorophenoL)

P021

Wastes (except

wastewater

and

spent

carbon

from

hydroqen

chloride

(H)

—

p~rification)from

the

manufacturing

use

(as

a

reactant,

chemical

intermediates

or

component

in

a

formulating

process)

of

tetra—,

penta—,

or hexachlorobenzenes under

alkaline

conditions.

P022

Wastes (except wastewat

d

sent

carbon

from

hydrogen

(H)

—

chloride

pirification)

from the production

of materials

on

equipment

previously

used

for

the

production

or

manufacturing

use

(as

a

reactant,

chemical

intermediate

or

component

in

a

formulating

process)

of

materials

listed

under

P020

and

P021.

P023

Discarded

unused

formulations

containing

tn--,

tetra—,

or

(H)

—

pentachlor~~enol or

discarded

unused

formulations

containing

compounds

derived

from

these

chlorophenols

(Comment:

The

pnima~ hazardous

prqperties

of

these

materials

have

been

indicated

by

the

letters

T

(Toxicity),

B

(Reactivity),

I

(Ignitability),

and

C (Corrosivity).

The

letter

H

indicates

Acute

Hazardous

Waste.)

4.

Section 721.133 is amended as follows:

Section

721.133

Discarded

Commercial

Chemical

Products,

Of

f-

Specification

Species,

Containers

and

Spill

Residues

The following materials or items

are

hazardous wastes if

and

when

they

are

discarded or intended to be discarded:

a)

Any commercial chemical product,

or manufacturing

chemical intermediate having the generic name listed

in paragraphs

(e)

or

(f).

61~-255

---

—10—

b)

Any

off—specification commercial chemical product

or

manufacturing chemical intermediate which,

if it met

specifications, would have the generic

name

listed

in

paragraphs

(e)

or

(f).

c)

Any

container

or inner liner removed from a container

that

has

been

used

to hold any commercial chemical

product

or

manufacturing

chemical

intermediate

having

the

generic

names

listed

in

paragraph

fe),

or

any

container

or

inner

liner

removed

from

a

container

that

has

been

used

to

hold

any

off-specification

chemical

product

and

manufacturing

chemical

intermediate

which,

if

it

met

specifications,

would

have

the

generic

name

listed

in

paragraph

(e),

unless:

1)

The container

or inner liner has been triple rinsed

using

a solvent capable

of removing the commercial

chemica!

product

or manufacturing

cheinic a!

intermediate;

2)

The

container

or

inner

liner

has

been

cleansed

by

another

method

that

has

been

shown

in

the

scientific

literatures

or

by

tests

conducted

by

the

generat.or,

to

achieve

equivalent

removal;

or

3)

In

the

case

of

a

container,

the

inner

liner

that

prevented

contact

of

the

commercial

chemical

product

or

manufacturing

chemical

intermediate

with

the

container,

has

been

removed.

d)

Any

residue

or

contaminated

soil,

water

or

other

debris

resulting

from

the

cleanup

of

a

spill,

into

or

on

any

land

or

water

of

any

commercial

chemical

product

or

manufacturing

chemical

intermediate

having

the

generic

name

listed

in

paragraph

(e)

or

(f),

or

any

residue

or

contaminated

soil,

water

or

other

debris

resulting

from

the

cleanup

of

a

spill,

into

or

on

any

land

or

water,

of any off—specification chemical product or

manufacturing

chemical

intermediate

which,

if

it

met

specifications, would have the generic name listed

in paragraph (e)

or

(f).

(Comment:

The phrase ucommercial chemical product or

manufacb~irirt~

chemical intermediate having the generic

name

listed

in

.

refers to a chemical

substance which is manufactured or formulated

for commercial

or manufacturing use which consists of the com-

mercially pire grade of

the

chemical,

any

technical grades of the

chemical that are produced or marketed,

and

all

formulations

in

which the chemical

is the sole active ingredient.

It does not

refer to a material,

such as a manufacturing process waste,

that

contains any of the substances listed

in paragraphs

(e) or

(f).

61-256

---

-11—

Where

a manufacturing process waste

is deemed to

be

a

hazardous

waste because

it contains a substance listed in paragraphs

(e)

or

(f),

such waste will

be

listed in either §~721.131or 721.132

or will

be identified

as

a hazardous waste by the characteristics

set forth in Subpart C of this part.)

e)

The commercial chemical products, manufacturing chemical

intermediates

or

off—specification

commercial

chemical

products

or

manufacturing

chemical

intermediates

referred

to

in

paragraphs

(a)

through

(ci)

of

this

section,

are

identified

as

acute

hazardous

waste

(H)

and

are

subject

to

the

small

quantity exclusion defined in

§721.105(e).

(Comment:

For the convenience of the regulated community the

primary hazardous properties of these materials have been indi-

cated by the letters T (Toxicity),

and

P. (Reactivity).

~bsence

of

a letter indicates

that the

compound

only

is

listed

for

acute

toxicity.

These

wastes

and

their

corresponding

EPA

Hazardous

Waste

Numbers

are:)

Hazardous

waste No.

Substance

P023

Acetaldehyde, chioro-

P002

Acetamide, N-(aminothioxomethyl)-

P057

Acetamide,

2-fluoro-

P058

Acetic

acid,

fluoro—, sodium salt

P066

Acetimedic

acid,

N— (methylcarbamoyl)oxythio-,

methyl ester

POOl

3—(alpha—acetonylbenzyl)—4—hydroxycoumarin

and

salts

P002

1-Acetyl--2—thiourea

P003

Acrolein

P070

Aldicarb

P004

Aldrin

P005

Allyl

alcohol

P006

Aluminum phosphide

P007

5—(Aminomethyl)—3--isoxazolol

P008

4-Aminopyridine

P009

Ammonium picrate

(R)

P119

Axnmonium vanadate

POlO

Arsenic acid

P012

Arsenic

(III)

oxide

P011

Arsenic

(V)

oxide

P011

Arsenic pentoxide

P012

Arsenic trioxide

P038

Arsine, diethyl—

P054

Aziridine

P013

Barium cyanide

P024

Benzenamine,

4-chloro-

P077

Benzenamine, 4—nitro—

61-257

---

-12—

Hazardous

waste No.

Substance

P028

Benzene,

(chioromethyl)—

P042

1,2-Benzenedioi,

4- (1—hydroxy—2-(methylamino)ethyl—

P014

Benzenethiol

P028

Benzyl

chloride

P015

Beryllium

dust

P016

Bis(chloromethyl) ether

P017

l3romoacetone

P018

Brucine

P021

Calcium cyanide

P123

Camphene, octachloro-

P103

Carbamidoselenoic

acid

P022

Carbon hisulfide

P022

Carbon disulfide

P095

Carbonyl chloride

P033

Chlorine cyanide

P023

Chloroacetaidehyde

P024

p—Chloroariiline

P026

1—(o-Chlorophenyl)thiourea

P027

3-Chioropropiortitrile

P029

Copper cyanides

P030

Cyanides

(soluble

cyanide

salts),

not

elsewhere

speci~tec1

P031

Cyanogen

P033

Cyanogen chloride

P036

Dichiorophenylarsine

P037

Dieldrin

P038

Diethylarsine

P039

0,0-Diethyl

S- 2-(ethylthio)ethyll

phosphorodithioate

P041

Diethyl -p-nitrophenyl

phosphate

P040

0,0-Diethyl 0-pyrazinyl phosphorothioate

P043

Diisopropyl

fluorophosphate

P044

Dimethoate

p045

3,3—Dimethyl—1—(methylthio)—2-butanone,

O—((methylarnino)

carbonyll

oxime

P071

0,0-Dimethyl

O-p-nitrophenyl

phosphorothioate

P082

Dimethylnitrosamine

P046

alpha,

alpha-Dimethylphenethylamine

P047

4,6—Dinitro-o-cresol

and

salts

P034

4, 6-Dinitro-o-cyclohexylphenol

P048

2, 4—Dinitrophenol

P020

Dinoseb

P085

Diphosphorainide, octanethyl-

P039

Disulfoton

P049

2, 4—Dithiobiuret

P109

Dithiopyrophosphoric

acid,

tetraethyl

ester

P050

Endosuifan.

P088

Endothail

P051

Endrin

61-258

---

—13—

Hazardous

waste No.

Substance

P042

Epinephrine

P046

Ethanamine,

1, 1-dimethyl—2-phenyl-

P084

Ethenamine, N-methyl-N—nitroso—

P101

Ethyl

cyanide

9054

Ethylenimine

9097

Famphur

P056

Fluorine

9057

Fluoroacetamide

P058

Fluoroacetic

acid,

sodium

salt

P065

Fulminic

acid,

mercury

(II)

salt

(R,T)

P059

Heptachior

9051

1,2,3,4,10,1O—Hexachloro—6,7—epoxy—1,4,4a,5,6,7,8,

8a-octahydro-endo,

endo-1,

4:5, 8-dimethanonaphthalene

P037

1,2,3,4,10,10—Hexachloro—6,7—epoxy—1,4,4a,5,6,7,8,

8a-octahydro-endo,

exo—1, 4:5, 8-dimethanonaphthalene

P060

1,2,3,4,10,10-Hexachloro-1,4,4a,5,8,8a—hexahydro—

1,4:5, 8-endo, endo-dimethanonaphthalene

P004

1,2,3,4,10,

10,—Hexachloro—1,4,

4a,5,

8, 8a—hexahydro—

1,4:5,

8-endo,exo—dimethanonaphthalene

P060

Hexachlorohexahydro-exo,exo-dimethanonaphthalene

P062

Hexaethyi tetraphosphate

P116

Hydrazinecarbothioamide

9068

Hydrazine, methyl-

P063

Hydrocyanic

acid

P063

Hydrogen

cyanide

P096

Hydrogen

phosphide

P064

Isocyanic

acid,

methyl

ester

9007

3(2H)—Isoxazolone,

5—(axninomethyl)—

P092

Mercury,

phenyl—,

acetate

P065

Mercury

fulminate

(R,T)

9016

Methane,

oxybis(chloro—

9112

Methane,

tetranitro-

(R)

P118

Methanethiol,

trichioro-

P059

4,7—Methano-1H-indene,

1,4,5,6,7,8,8—heptachioro-

3a, 4,7,7a—tetrahydro-

9066

Methomyl

9067

2—Methylaziridine

P068

Methyl

hydrazine

P064

Methyl isocyanate

P069

2—Methyl1actonitrile

P071

Methyl parathion

9072

alpha-Naphthy. thiourea

9073

Nickel carbonyl

9074

Nickel cyanide

P074

Nickel(II)

cyanide

9073

Nickel

tetracarbonyl

9075

Nicotine

and

salts

61-259

---

—14-

H

azardou s

waste

No.

Substance

9076

Nitric

oxide

P077

p—Nitroanilinc

P078

Nitrogen

dioxide

9076

Nitrogen(II) oxide

9078

Nitrogen(IV)

oxide

P081

Nitroglycerine

(R)

9082

N—Nitrosodimethyiamine

P084

N--Nitrosornethyivinyl

amine

P050

5—Norbornene—2,3--dimethanol,

1,4,5,6,7,7—hexachloro,

cyclic

sulfite

9085

Octamethylpyrophosphorami~e

P087

Osmium oxide

9087

Osmium tetroxide

P088

7-Oxabicyclof2.2 1heptane-2,3—dicarboxylic

acid

P089

Parathion

9034

Phenol, 2—cyclohexyl-4, 6—dinitro—

9048

Phenol,

2,4—dinitro—

9047

Phenol,

2,4,

—dinit-ro—6-methyl—

9020

Phenol,

2,4—dinitro—6—(

1—methyipropyl)—

9009

Phenol,

2,4,6--trinitro—,

ammonium

salt

(R)

9036

Phenyl dichloroarsine

P092

Phenylmercuric acetate

P093

N-Phenyithiourea

P094

Phorate

P095

Phosgene

9096

Phosphine

9041

Phosphoric

acid,

diethyl

p-nitrophenyl

ester

P044

Phosphorodithioic

acid,

0,0—dimethyl

S—(2—(methylamino)-

2-oxoethyl Jester

9043

Phosphorofluoric

acid,

bis(

1-methylethyl)ester

9094

Phosphorothioic

acid, 0,0—diethyl S—(ethylthio)methyl

ester

P089

Phosphorothioic

acid, 0,0-diethyl O-(p-nitrophonyl)

ester

P040

Phosphorothioic

acid, 0,0-diethyl 0-pyrazinyl ester

P097

Phosphorothioic

acid,

0,

0-dimethyl

0- p-(

(dimethylamino)-

sul

fonyl

)phenyl Jester

P110

Plumbane,

tetraethyl-

P098

Potassium

cyanide

P099

Potassium silver cyanide

9070

Propane,

2-methyl—2—(methylthio)—,

0—

(methylamino)

carbonyl

I

oxime

9101

Propanenitrile

P027

Propanentrile,

3—chloro—

9069

Propanenitrile~2—hydroxy—2—methyl—

9081

1,2,3—Proparietriol,

trinitrate—

(R)

P017

2—Propanone; 1—bromo—

61~260

---

—15—

Hazardous

waste No.

____

Substance

9102

Propargyl

alcohol

9003

2—Propenal

P005

2—Propen-1--ol

9067

1,2—Propylenimine

9102

2—Propyn—i—ol

9008

4—Pyridinamine

9075

Pyridine,

(S)—3—(1-methy-2—pyrrolidinyl)—,

and salts

9111

Pyrophosphoric acid,

tetraethyl ester

9103

Selenourea

P104

Silver cyanide

9105

Sodium azide

9106

Sodium cyanide

9107

Strontium sulfide

9108

Strychnidin—lO—one,

and salts

9018

Strychnidin—lO-one, 2,3—dimethoxy-

P108

Strychnine and salts

9115

Sulfuric

acid.

thallium(I)

salt

9109

Tetraethyl dithiopyrophosphate

P110

Tetraethyl

lead

Pill

Tetraethyl

pyrophosphate

P112

Tetranitromethane

(R)

.062

Tetraphosphoric

acid,

hexaethyl

ester

P113

Thallic

oxide

9113

Thallium(III)

oxide

P114

Thallium(I)

selenite

9115

Thallium(I)

sulfate

9045

Thiofanox

P049

Thioimidodicarbortic

diamide

9014

Thiophenol

9116

Thioseraicarbazide

P026

Thiourea,

(2—chiorophenyl)—

9072

Thiourea,

1-naphthalenyl-

9093

Thiourea, phenyl-

P123

Toxaphene

P118

Trichlorornethanethiol

P119

Vanadic

acid,

ammonium

salt

9120

Vanadium pentoxide

P120

Vanadium(V)

oxide

POOl

Warfarin

P121

Zinc

cyanide

P122

Zinc

phosphide

(R,

T)

f)

The

commercial

chemical

products,

manufacturing

chemical

intermediates or off—specification commercial

chemical products referred to in paragraphs

(a) through

(ci),

are identified as toxic wastes

(T) unless otherwise

designated

and

are

subject

to

the

small

quantity

exclusion defined in Section 721.105(a)

and

(f).

61-261

---

—16—

(Comment:

For

the

convenience

of

the

regulated

community,

the

primary

hazardous

properties

of

these

materials

have

been

indicated

by

the

letters

T

(Toxicity),

R

(Reactivity),

I

(Ignitability)

and

C

(Corrosivity).

Absence of

a letter indicates that the compound

is

only listed for toxicity.

These wastes and their correspondinq

EPA Hazardous Waste Numbers are:)

Hazard

waste

otis

No.

Substance

13001

Acetaldehyde

(I)

1J034

Acetaldehyde,

trichioro-

0187

Acetamide,

N-(

4—ethoxyphenyl

)—

0005

Acetaxnide,

N—9H--fluoren—2—yl—

13112

Acetic

acid,

ethyl

ester

(I)

0144

Acetic

acid,

lead

salt

13214

Acetic

acid,

thallium(I)

salt

0002

Acetone

(I)

13003

Acetonitrile

(I,T)

0004

Acetophenone

0005

2—Acetylaminofluorene

0006

Acetyl chloride

(C,R,T)

0007

Acrylamide

13008

Acrylic

acid

(I)

0009

Acrylontrile

0150

Alanine,

3— p-bis(2-chloroethyl)axnino

phenyl-,

L-

13011

Amitrole

0012

Aniline

(I,T)

13014

Auramine

0015

Azaserine

13010

Azirino(2~,3~;3,4)pyrrolo(1,2—a)indole—4,7—dione,

6-amino-8—

(

(aminocarbonyl )oxy)methyl-l,

la,

2,8,8a,8b-hexahydro-8a-methoxy-5-methyl-,

0157

Benz jiaceanthrylene,

1,2—dihydro-3—methyl—

0016

Benz(c)acridine

0016

3, 4—Beuzacridine

0017

Benzal

chloride

13018

Benz

a

anthracene

13018

l,2—Benzanthracene

13094

1,2—Ben

zanthracene,

7, 12—dimethyl—

U012

Benzenamine

(I,T)

13014

Benzenamine, 4,4~—carbonimidoylbis(N,N-dimethyl-

0049

Benzenamine,

4-chloro-2-methyl-

0093

Benzenarnine, N,N’—dimethyl—4-phenylazo-

0158

Benzenamine,

4,

4’—methylenebis(2—chloro-

0222

Benzenamine,

2-methyl--, hydrochloride

13181

Benzenamine,

2—methyl-5—nitro

13019

Benzene

(I,T)

0038

Benzeneacetic

acid, 4—chloro-alpha-( 4-chiorophenyl

)-

alpha-hydroxy,

ethyl

ester

61-262

---

—17—

Hazardous

waste

No.

Substance

Benzene,

1—hromo-4-phenoxy—

Benzene,

chioro-

1,2—l3enzenedicarboxylic

1,2—Benzenedicarboxylic

1, 2—Benzenedicarboxylic

1,2—Benzenedicarboxylic

1, 2—Benzenedicarboxylic

1, 2—Benzenedicarboxylic

Benzene,

1, 2—dichioro-

Benzene,

1,3-dichioro—

Benzene,

1, 4-dichioro—

Benzene,

(dichloromethyl)-

Benzene,

1, 3-duisocyanatornethyl—(R,T)

Benzene,

dimethyl—(I,T)

1, 3-Benzenediol

Benzene, hexachioro—

Benzene,

hexahydro-

(

I)

Benzene, hydroxy-

Benzene, methyl-

Benzene,

1—methyl--2, 4-dinitro-

Benzene,

1—methyl-2, 6—dinitro—

Benzene,

1,2—rnethylenedioxy—4—allyl—

Benzene,

1, 2-methylenedioxy-4-propenyl-

Benzene,

1, 2-methylenedioxy-4-propyl—

Benzene,

(1—methylethyl)-

(I)

Benzene, nitro-

(I,T)

Benzene, pentachloro—

Benzene,

pentachioronitro-

Benzenesulfonic

acid

chloride

(C,R)

Benzenesulfonyl

chloride

(C,R)

Benzene,

1,2,

4,5—tetrachioro—

Benzene,

(trichloromethyl)—(C,R,T)

Benzene, 1,3,5-trinitro—

(R,T)

Benzidirie

1,2—Benzisothiazolin—3—orie, 1,1—dioxide

Benzo j,k

fluorene

Benzo

(alpyrene

3, 4—Benzopyrene

p-Benzoquinone

Benzotrichloride

(C,R,T)

1, 2—Benzphenanthrene

2,2~—Bioxirane(I,T)

(1,1~—Biphenyl)-4,4’—diamine

(1,1’—Bipheriyl)-4,4’—diamine,

3,3’—dichloro—

(1,1~—Biphenyl)-4,4’—diamine,

3,3’—dimethoxy—

(l,1’—Biphenyl)—4,4’—diamine, 3,3’—dimethyl—

Bis(2-chioroethoxy)

methane

acid anhydride

acid,

tbis(2—ethylhexyi)1

ester

acid,

dibutyl

ester

acid,

diethyl

ester

acid,

dimethyl ester

acid,

di—n—octyl

ester

13030

0037

13190

0028

0069

0088

0102

0107

0070

0071

13072

0017

0223

0239

0201

13127

13056

0188

0220

13105

U106

0203

0141

0090

0055

0169

0183

LJiO

0020

13020

0207

0023

0234

13021

0202

13120

13022

U022

1319 7

0023

0050

0085

0021

0073

1309 1

0095

TJ

024

61-263

---

—18—

Hazard

waste

Otis

No.

Substance

13027

Bis(2—chioroisopropyl)

ether

0244

Bis(dimethylthiocarbamoyl) disulfide

13028

Bis(2-ethylhexyl)

phthalate

0246

Bromine cyanide

0225

Bromoform

0030

4-Bromopheriyl phenyl ether

0128

1,3—Butadiene,

1,l,2,3,4,4—hexachloro—

11172

1—Butanamine,

N—butyl—N—nitroso—

0035

Butanoic

acid,

4—Bis(2—chloroethyl)aminoj

benzene-

13031

1—l3utanol

(I)

0159

2—Butanone

(I,T)

0160

2—Butanone

peroxide

(R,T)

13053

2—Butenal

0074

2—Butene,

1,4—dichloro—

(I,T)

0031

n—Butyl

alcohol

(I)

0136

Cacodylic acid

13032

Calcium chromate

13238

Carbamic

acid,

ethyl

ester

13178

Carbamic

acid,

methylnitroso-,

ethyl

ester

0176

Carbamide,

N--ethyl—N-nitroso—

0177

Carbamide,

N--methyl-N—nitroso-

13219

Carbamide,

thio-

13097

Carbamoyl

chloride,

dimethyl

13215

Carbonic

acid,

dithallium

(I)

salt

13156

Carbonochloridic

acid,

methyl ester

(I,T)

13033

Carbon

oxyfluoride

(R,T)

(3211

Carbon tetrachioride

13033

Carbortyl fluoride (R,T)

0034

Choral

U035

Chlorarahucil

13036

Chlordane,

technical

13026

Chiornaphazine

0037

Chlorobenzene

(3039

4-Chloro—m--cresol

13041

l—Chloro--2, 3-epoxypropane

0042

2—Chloroethyl

vinyl

ether

13044

Chloroform

0046

Chioromethyl

methyl

ether

13047

beta-Chloronapthalene

(3048

o-Chlorophenol

13049

4-Chloro-o-toiuidine,

hydrochloride

13032

Chromic

acid,

calcium

salt

13050

Chrysene

(3051

Creosote

13052

Cresols

0052

Cresylic acid

0053

Crotonaldehyde

61-264

---

—19—

Hazardous

waste No.

Substance

13055

Cumene

(I)

(3246

Cyanogen bromide

13197

1, 4—Cyciohexadienedione

13056

Cyclohexane

(I)

(3057

Cyclohexanone ~I)

13130

1,3—Cyclopentadiene, 1,2,3,4,5,5—hexachioro—

0058

Cyclophospharnide

13240

2,4—D,

salts and esters

0059

Daunomycin

13060

DDD

(1061

DDT

(3142

Decachlorooctahydro-1, 3, 4—metheno—2H—

cyclohuta

c,d

-pentalen—2-one

13062

Diallate

(3133

Diamine

(R,T)

13221

Diaminotoluene

U063

Dibenz a,h

anthracene

U063

1,2:5,

6—Dibenzanthracene

U064

1,2:7,8-Dibenzopyrene

U064

Dibenzta,iipyrene

(3066

1, 2—Dibromo-3—chloropropane

13069

Dibutyl

phthaiate

tJ062

S—(2,3—Dichloroallyl)

duisopropylthiocarbamate

(3070

o—Dichlorobenzene

13071

m-Dichlorobenzerte

(3072

p—Dichlorobenzene

13073

3,31—Dichlorobenzidine

0074

1,4—Dichloro-2---butene

(I,T)

(3075

Dichlorodifluoromethane

(3192

3,5—Dichloro—N-(1,

i-dimethyl—2—propynyl)

bertzamide

(3060

Dichloro diphenyl dichloroethane

(3061

Dichioro diphenyl

trichioroethane

0078

1, i—Dichloroethylene

0079

1, 2-Dichioroethylene

U025

Dichioroethyl ether

(3081

2, 4—Dichlorophenol

(3082

2, 6-Dichiorophenol

0240

2,4—Dichlorophenoxyacetic

acid,

salts

and

esters

0083

1, 2-Dichloropropane

(3084

1, 3—Dichioropropene

0085

1,2:3,4—Diepoxybutane

(I,T)

0108

1,4—Diethylene dioxide

(3086

N,N—Diethylhydrazine

(3087

0,0-Diethyl-S--rnethyl-dithiophosphate

(3088

Diethyl phthalate

(3089

Diethyl stilbestrol

(3148

1, 2—Dihydro-3, 6-pyradizinedione

61-265

---

—20—

Hazardous

waste No.

Substance

0090

Dihydrosafrole

(3091

3,3~—Dimethoxybenzidine

11092

Dimethylamine

(I)

0093

Dimethyl aminoazobenzene

11094

7, 12—durnethylbenz a

anthracene

(3095

3,3 ‘—Dimethylbertzidine

13096

alpha,

alpha’-Dimethylbenzylhydroperoxide

(R)

13097

Dimethylcarbamoyl chloride

0098

1, 1—Dimethylhydrazine

13099

1,2—Dimethylhydrazine

13101

2,

4—Dimethyl phenol

0102

Dimethyl

phthalate

13103

Dimethyl

sulfate

13105

2,4—Dinitrotoluene

13106

2, 6-Dinitrotoluene

13107

Di—n—octyl phthalate

0108

i,4—Dioxane

(3109

1, 2-Diphenyihydrazine

(1110

Dipropylamine

(I)

13111

Di-N-propylnitrosoaxnine

13001

Ethanal

(I)

13174

Ethanamine,

N-ethyl-N-nitroso-

13067

Ethane,

1,2—dibromo-

13076

Ethane,

1,1—dichioro—

13077

Ethane,

1,2-dichioro—

13114

1,2—Ethanediylbiscarbamodithioic acid

0131

Ethane,

l,1,i,2,2,2—hexachloro—

0024

Ethane,

1,l~-methylenebis(oxy)1bis(2—chloro—

(3247

Ethane,

1,1,1—trichloro—2,2—bis(p—methoxyphenyl)-

U003

Ethanenitrile

(I,T)

U117

Ethane,

1,l’—oxybis—

(I)

(3025

Ethane, 1,1’-oxybis(2—chloro—

ul84

Ethane, peritachioro-

(3208

Ethane,

1,l,1,2—tetrachloro—

13209

Ethane,

1,1,2,2-tetrachloro—

0218

Ethanethioamide

(3227

Ethane,

1,l,2—trichloro—

0043

Ethene, chioro—

0042

Ethene,

2-chloroethoxy—

0078

Ethene,

1,1—dichloro—

0079

Ethene, trans-1,2—dichloro-

U210

Ethene,

1,1,2,2—tetrachioro—

0173

Ethanol,

2,2’—(nitrosoimino)bis—

13004

Ethanone, 1-phenyl-

13006

Ethanoyl

chloride

(C,R,T)

13112

Ethyl acetate

(I)

13113

Ethyl

acrylate

(I)

61-266

---

—21—

Hazardous

waste No.

Substance

(3238

Ethyl carbamate

(urethan)

(3038

Ethyl 4,4~—dichlorobenzilate

13114

Ethylenebis(dithiocarbamic

acid)

(3067

Ethylene dibromide

0077

Ethylene dichloride

0115

Ethylene oxide

(I,T)

(3116

Ethylene

thiourea

13117

Ethyl

ether

(I)

(3076

Ethylidene

dichioride

0118

Ethylmethacryl

ate

U119

Ethyl

methanesuifonate

0139

Ferric dextran

13120

Fluoranthene

(3122

Formaldehyde

11123

Formic

acid

(C,T)

0124

Furan

(I)

13125

2-Furancarboxaldehyde

(I)

(3147

2,5—Furandione

(1213

Furan,

tetrahydro—

(I)

3125

Furfural

(I)

13124

Furfurari

(I)

13206

D-Glucopyranose,

2-deoxy-2-(

3-methyl -3—ni-

trosoureido)—

0126

Glycidylaldehyde

(3163

Guanidine, N-nitroso—N—methyl—N’—nitro

13127

Hexachlorobenzene

(3128

Hexachiorobutadiene

0129

Hexachlorocyclohexane

(gamma isomer)

13130

Hexachlorocyclopentadiene

0131

Hexachioroethane

13132

Hexachiorophene

3243

Hexachloropropene

0133

Hydrazine

(R,T)

0086

Hydrazine,

l,2—diethyl—

11098

Hydrazine,

1,1—dimethyl—

0099

Hydrazine,

1,2-dimethyl-

0109

Hydrazine,

1,2—diphenyl—

13134

Hydrofluoric acid (C,T)

(3134

Hydrogen fluoride (C,T)

(3135

Hydrogen sulfide

0096

Hydroperoxide, 1-methyl-1-phenylethyl—

(R)

0136

Hydroxydimethylarsine

oxide

13116

2—Imidazolidinethione

0137

Indeno

1,2,3—cd

pyrene

(3139

Iron

dextran

0140

Isobutyl

alcohol

(I,T)

0141

Isosafrole

61-267

---

—22—

Hazardous

waste No.

Substance

(1142

Kepone

13143

Lasiocarpene

0144

Lead

acetate

13145

Lead phosphate

13146

Lead subacetate

13129

Lindane

13147

Maleic arAhydride

(3148

Maleic hydrazide

(3149

Malononitrile

3150

Melphalan

0151

Mercury

(1152

Methacrylonitrile

(I,T)

13092

Methanamine~ N--methyl—

(I)

(3029

Methane,

bromo---

(3045

Methane,

chloro—

(I,T)

13046

Methane,

chioromnethoxy-

U068

Methane,

dibromo-

3080

Methane,

dichloro—

(3075

Methane, dichiorodifluoro-

0138

Methane,

iodo—

(3119

Methanesulfonic

acid,

ethyl ester

0211

Methane, tetrachloro-

(3121

Methane,

trichiorofluoro—

0153

Methanethiol

(I,T)

0225

Methane, tribromo-

13044

Methane,

trichioro—

0121

Methane, trichlorofluoro-

13123

Methanoic acid (C,T)

0036

4,7—Methanoindan,

1,2,4,5,6,7,8,8—octa—

chloro-3a, 4,7,7a-tetrahydro-

(3154

Methanol

(I)

13155

Methapyrilene

(3154

Methyl

alcohol

(I)

11029

Methyl bromide

3186

1—Methylbutadiene

(I)

0045

Methyl chloride

(I,T)

0156

Methyl chiorocarbonate

(I,T)

(1226

Methylchloroform

3157

3-Methyicholanthrene

(3158

4, 4’—Methylenehis(2—chloroaniline)

U132

2,

2’-Methylenebis(3,4,6—trichlorophenol)

1068

Methylene bromide

0080

Methylene chloride

(3122

Methylene oxide

3159

Methyl

ethyl

ketone

(I,T)

(3160

Methyl ethyl ketone peroxide

(R,T)

(1138

Methyl

iodide

61-268

---

—23--

11

azardou

S

waste No.

Substance

(3161

Methyl

isohutyl.

ketone

(I)

Y.J162

Methyl methacrylate

(I,T)

(3163

N—Methyl—N~--nitro-N-nitrosoguanidine

(1161

4—Methyi—2—pentanone

(I)

0164

Methylthiouracil

(3247

Methoxychior

nOb

Mitornycin C

13059

5, 12—Naphthacenedione,

(8S—cis)—8—acetyl—

10—(3—amino-2,3,6—trideoxy—alpha—L—lyxo—

hexapyranosyl )oxyl 1-7,8,9,lO—tetrahydro—

6,8, 11—trihydroxy-1—methoxy-

13165

Naphthalene

Y3047

Naphthalene,

2—chioro—

0166

1, 4-Naphthalenedione

(3236

2,7—Naphthalenedisulfonic

acid,

3,3’—(3,3’—

dimethyl—( :L, i’1—hiphenyl )—4, 4’—diyl)l—bis

(azo)bis(5-amino-4-hydroxy)—, tetrasodium salt

13166

1,4-Naphtha~i

inane

(3167

1-Naphthylamine

0168

2-Naphthylamine

13167

alpha-Naphthylamine

(1168

beta—Naphthy. amine

(3026

2-Naphthylamine, N,N’-bis(2—chloromethyl)—

13169

Nitrobenzene

(I,T)

(3170

p-Nitrophenol

13171

2—Nitropropane

(I)

1)172

N—Nitrosodi-—ri-butylamine

13173

N—Nitrosodiethanol

amine

13174

N-Nitrosodiethylamine

13111

N—Nitroso--N-propylamine

13176

N—Nitroso—N--ethylurea

13177

N—Nitroso-N—methylurea

13178

N—Nitroso—N-me

thylurethane

1179

N—Nitrosopiperidine

(3180

N—Nitrosopyrrolidine

13181

5—Nitro-o-toluidine

13193

1,2—Oxathiolane,

2,2—dioxide

(3058

2H—1, 3, 2-Oxazaphosphorine,

2— bis(2—

chioroethyl)aminotetrahydro-,

oxide 2—

13115

Oxirane

(I,T)

13041

Oxarane,

2-(chloromethyl)-

(3182

Paraldehyde

(1183

Pentachlorobenzene

(1184

Pentachloroethane

13185

Pentachloronitrobenzene

(3186

1,3—penta.diene

(I)

61-269

---

—24—

Hazardous

waste No.

Substance

13187

Phenacetiri

0188

Phenol

(3048

Phenol,

2—chioro-

(3039

Phenol,

4—chloro--3--methyl—

13081

Phenol, 2,4—dichloro—

(3082

Phenol,

2,6—dichioro-

(3101

Phenol,

2,4-dimethyl—

(3170

Phenol,

4—nitro—

Pkefte~7-pe~ae~ef

0-

~

~

~

0137

1,10— (1, 2-phenylene)pyrene

(3145

Phosphoric

acid,

lead salt

3087

Phosphorodithioic

acid,

0,0—diethyl—,

S—

methyl ester

(3189

Phosphorous

sulfide

(R)

13190

Phthalic anhydride

U191

2—Picoline

(3192

Pronamide

13194

1—Propanamine

(I,T)

(3110

1—Propanamine~N-propyl-

(I)

(3066

Propane,

1, 2—dibromo—3—chloro—

(3149

Propanedinitrile

13171

Propane, 2—nitro—

(I)

0027

Propane,

2,2 —oxybis 2—chioro—

13193

1,3-Propane sultone

(3235

1—Propanol,

2,3—dibromo—, phosphate (3:1)

(3126

1—Propanol,

2,3—epoxy—

13140

1—Propanol,

2—methyl—

(I,T)

(3002

2—Propanone

(I)

13007

2—Propenamide

(3084

Propene, 1,3—dichloro—

0243

l—Propene,

1,1,2,3

3, 3—hexachloro—

13009

2-Propenenitrile

13152

2—Propenenitrile,

2—methyl— (I,T)

(3008

2-Propenoic

acid

(I)

3113

2—Propenoic

acid,

ethyl ester

(I)

(3118

2-Propenoic

acid,

2—methyl-,

ethyl ester

(3162

2-Propertoic

acid,

2—methyl—,

methyl ester

(I,T)

(3194

n—Propylamine

(I,T)

13083

Propylene dichioride

13196

Pyridine

13155

Pyridine,

2- 2-(dimethylamino)-2—pheny.amino—

13179

Pyridine,

hexahydro-N-nitroso—

0191

Pyridine,

2—methyl—

61-270

---

—25—

Ti

azardou s

waste

No.

Substance

3164

4(1H)—Pyrimidinone, 2,3—dihydro—6—methyl—

2-thioxo-

(3180

Pyrrole,

tetrahydro-N—nitroso-

13200

Reserpine

(3201

Resorcinol

3202

Saccharin and salts

(3203

Safrole

U204

Selenious acid

0204

Selenium dioxide

3205

Selenium disulfide

(R,T)

(3015

L—Sermne, diazoacetate (ester)

S~vex

0089

4, 4’—Stilbenediol,

alpha,

alpha’—diethyl—

1)206

Streptozotocin

13135

Sulfur hydride

U103

Sulfuric

acid,

dimethyl ester

0189

Sulfur phosphide

(R)

0205

Sulfur selenide

(R,T)

~747~—~

3207

1,2,4,5—Tetrachlorobenzene

0208

1,1,1,2—Tetrachloroethane

13209

1,l,2,2—Tetrachloroethane

0210

Tetrachloroethylene

~

(1213

Tetrahydrofurari

(I)

3214

Thallium

(I) acetate

13215

Thallium

(I) carbonate

3216

Thallium

(I) chloride

1217

Thallium

(I)

nitrate

(3218

Thioacetamide

(3153

Thiomethanol

(I,T)

13219

Thiourea

(3244

Thiram

0220

Toluene

(3221

Toluenediamine

3223

Toluene diisocyanate

(R,T)

(3222

o—Toluidine

hydrochloride

1011

1H—1,2,4—Triazol—3—amine

1)226

1, 1, 1—Trichloroethane

3227

1,1,2—Trichloroethane

0228

Trichloroethene

(3228

Trichloroethylene

0121

Trichloromonofluoromethane

~

~74T?—erep~ene~

~

0234

sym-Trinitrobenzene (R,T)

61-271

---

—26—

Hazardous

waste No.

Substance

_____

U182

1,3,5—Trioxane,

2, 4,5—trimethyl—

0235

Tris(2,3—dibromopropyl)

phosphate

0236

Trypan blue

(3237

Uracil,

S fbis( 2--chioromethyl.

)

amino—

0237

Uracil

mustard

(3043

Vinyl

chloride

13239

Xylene

(I)

U200

Yohimban—16-carboxylic acid,

11,17—di—

methoxy-18-- (3,4, 5—trimethoxy—

benzoyl)oxyl—,

methyl

ester

(Source:

Amended at

7 Ill.

Reg.

2518, effective February 22,

1983.)

5.

Appendix C of

Part

721, which formerly referenced

Appendix

III to 40 CFR 261,

is printed out and amended as

follows:

Appendix

C-~-3hemical Analysis Test Methods

Tables

1,

2,

and

3

specify the appropriate analytical

procedures described

in

~Test Methods for Evaluating Solid

Waste,

Physical/Chemical Methods” (incorportated by refer-

ence,

see 5 260.11), which

shall be used in determining

whether the waste

in

question contains a given toxic con-

stituent.

Table

1 identifies the analytical class and the

approved measurement techniques

for each organic chemical

listed

in Appendix VIL

Table

2 identifies the correspond-

ing methods for the inorganic species.

Table

3 identifies

the specific sample preparation and measurement instrument

introduction techniques which may be suitable for both the

organic and inorganic species as well as the matrices of

concern.

Prior to final

selection of the analytical method the

operator should consult the specific method descriptions in

SW-846 for additional

guidance on which of the approved methods

should be employed for

a specific waste analysis situation.

T~E

I—Analytical

~racteritica

of C~~ic

øi~nica1s

Se~1eha~d11ng

ci ass/fractias

~tJrx~

Meaa1r~~t_t~1~ig3es

~tact~

~st~itTi1e

Volatile

8.24

8.03

~

Wsia~tiie

8.24

803

~

~ryl~ni&

Volatile

8.24

8.01

rzn

~ylcr~it-ile

Volatile

8.24

8.03

~G

Volatile

8.24

8.02

PTh

z(a)a~t1r~*

~xtractthle/a~

$.10(HPW)

8.25

8.10

FID

~mzo(s)p~?e~e

~t~is/~

8. 10(EPLC)

8.25

8.10

FID

3ezotrichl cride

tr~tth1efa~

8.25

8.32

61-272

---

27—

~a~leh~d1ing

ci

as/f~~tio~

t~-~

n~thcx~s

Measar~ent

tach~iqies

Coi

~iticna1

~X

Detectcr

Benzyl

chlrida

Volatile

or

8.24

8.01

H&)

E~tractabie/~

8.25

8.12

B~z(b)flua~~theae

~tr~t~blef~

8.10(HPIC)

8.25

8.10

FID

flis(2-chlaroet1~yn~tha~e)

Volatile

8.24

8.01.

HS)

8is(2-hlctl~’l)eth~r

Volatile

8.24

8.01

H9~

Bis(2-chloroisqrcpyl)

~letile

8.24

8.01

H9

etJ~r

carton

diailfide

Volatile

8.24

8.01

C3rh~

thtx~hlcride

Volatile

8.24

8.01

Chlorda~e

r~ctthle/~

8.25

8.08

ebicrinated

dihe~zo

Extractth1e/~

8.25

8.08

diczins

thiorinated

di1~rtzo—p-

l~tra~tthle/~

8280

dioxins

chiorthated

hiphenyls

r&~tablef~

8.25

8.08

53)

chlcro~etal~’de

Volatile

8.24

8.01

53)

chlor~enzene

Volatile

8.24

8.01

53)

8.02

P~

CIcZ-OfOrin

Volatile

8.24

8.01

53)

cMorar~tha~e

Volatile

8

•

24

8.01

53)

2-Chlorcphenol

xact~ble/R~

8.25

8.04

Fm,

Clrysene

L~’rat~tle/~4

8.10(HPT.C)

~8.25

8.10

P11)

CreosotE

Thctr~’ctable/5~1

‘8.25

8.10

B~)

Cresol(s)

Ebctract~ble/A

8.25

8.04

P11),

PXD

Cresylic

~id(s)

traotable/A

8.25

8.04

F~,~)

Dichlorcbenzene(s)

acraetible/&N

8,25

8.01

H3)

8.02

P11)

8.12

~D

Dichlctoethm~e(s)

Volatile

8.24

8.01

53)

Dichloro~tha~e

Vc~1atile

8.24

8.01

53)

Dichl~ophenozy-~etic

~id

~ctiblefA

8.25

8.40

59)

Dichlorc~rcç~anol

ra,t~blef~

8.25

8.12

~)

2,

4—Dinethyiphenci

~ctra~table/2l

8.25

0.04

P11), ~)

Dthitrcienzene

r~~b1e/~

8.25

8.09

P11), ~)

4,

6—Dinitro—o--cresol

~l~~aUe/A

8.25

8.04

FIT),

2,

4-Dinitrotolueie

1~tr&fteble/~

8.25

8.09

LID,

~)

F.ndr±n

Extract~*ge/P

8.25

8.08

53)

Et1~’1ether

Volatile

8.24

8.01

P11)

8.02

LID

Fanna1deh~

Volatile

8.24

8.01

FIT)

Fcumdc arid

E~txatthle/8N

8.25

8.06

FIT)

Reptathlcr

E~ctxzr~table/P

8.25

8.06

59)

Hexahlorcbenzene

~ctr~t~le/E~

8.25

8.12

PXI)

Hexa~hlc~cb.itthi~e

1~~-a~table/~

8.25

8.12

~LD

x~Moroetha~e

r~tthle/5N

8.25

8.12

~I)

Hexsohloro~lo~entadi~e

P~ctr~table/~4

8.25

8.12

Lindane

F~ctract~tle/?

8.25

8.08

59)

Maleic

&ihydrida

~~t~le/5N

8.25

8.06

a~,

LID

Metha~ol

Volatile

8.24

8.01

FID

Methcznyi

1~~actable/~1

0.32

(HPLC

Methyl

ethyl

)~ta~e

Vol ati.le

8.25

8.01

FIT)

8.02

P11)

Methyl

iscb.itly

)~etcee

8.25

8.01

P11)

8.02

FIT)

Naphthal~ne

bactthle/~

8.25

8.10

FIT)

Napth~q~ina~e

1ctractthle/~

8.25

8.06

~,

FIT)

8.09

F~

Nirc~en~ene

~c~racteble/~fl

8.25

8.09

BD,

FL)

4-Nitr~1~öI

F21tr~table/A

8.24

8.04

~,

FL)

Paraiclehyde

(tririer

of

Volatile

8.24

8.01

P11)

&etal ~hyda).

61-27~3

---

--28—

Measirasent

techeiqies

Cceçcimd

S~1e

handling

1~-Oz

Cai

.antiu~al

netheda

TMS

U~ ~tectcr

Ptachiópheno~

F~xtractthlefA

8.25

8.04

a~

P)~dL

Extractthle/A

8.25

8.04

~XD,FL)

Pharate

~tt~otIthe/~

8.22

PPD

Phaspl~odithioic

acid

~traetable/9~

8.06

~,

FIT)

eaters

8.09

Fl),

F)

8.22

F~

~

~*iydrj~~

~tx~tthle/i~

8.25

8.06

el),

FIT)

8.09

~,

LID

2—Picoline

E~tractable/~

8.25

8.06

~,

FL)

8.09

Fl),

FIT)

Pyridine

5ztractable/~

8.25

8.06

~,

FIT)

8.09

~),

LID

~etra~hlarc~ze~e(

a)

ractthle/a’~

8.25

8.12

EQ)

Te~hioroethane(s)

Volatile

8.24

8.01

59)

L’etrachlcrcet1~e

Volatile

8.24

8.01

59)

achlarcç*enol

E~tract~le/A

8.24

8.04

Toluene

Volatile

8.24

8.02

pm

Toldianine

i~r~ab1ef~

8.25

Toluene

diiscyanate(s~

l~tct~le/ncnag~eo,s

8.06

LID

Toxexhene

i~tr~~bie/p

8.25

8.08

59)

Trichloroeth&ie

Volatile

8.24

8.01

09)

Trichlor~tl~e(a)

Volatile

8.24

8.01

09)

Trichloroflucr~tethane

Volati~e

8,24

8.01

59)

Tricbic~rq~ol(a)

Fxtractthle/A

8.25

8.04

59)

2,4,5-’TP (Silvex)

~ct~le/2~.

8.40

59)

Trichlorcçrcpane

~k~atile

8.24

8.01

09)

Vinyl chiori~

V~l~til~

8.24

8.01

59)

V.thylidene chloride

Volatile

8.24

8.01

09)

Xylene

Volatile

8.24

8.02

P11)

~Anaiy~

Icr

antlrene

~d

z~erbazole;

if tiese

in

Iresent

a

ratio

between

1.4~).r~dS~i,crec~otesha.~1d~o

~‘cn~iderol

~

EXD

Electrai

capture data~

!I)

-

Fl~eicnizatios

datectar;

F~)

-

Flwe

p~r~toretricdatectar;

53)

-

Hal~a

a~ecific c~tectr;

SPIC

Sigh

Iresaire licpid

clratography;

09)

-

Nitro~-sosoific

datectcr;

PIT)

a

Phatoicnizaticn

detector.

Tthle

2—Analytical

characteristics

of

Inorganic

Species

.•.

••.~

~

.•.~

.~.

.~

•_•_•.~

._.~

._

•.••. •.

.•.

•.•.•.

•••~•..~

~.•.•~_.••.•.

Species

Sarçae handling class

Measerenent

techeicpe

Metixx~

TEwber

Antinrr~y

Digestien

Atanic

~sorti~-~rnace/fl~

8.50

Arsenic

Hydride

Atanic

bsorbtian-flane

8.51.

Barium

Digestia,

Atanic

~so~ti

n-ft rnace/fl~

8.52

Cthlmiwn

Digestirn

Atcinic

thsorbtia-~rr~ace/fl~

8.53

C1ra,uixn

Digesticr~

Atanic

thsorbtia~rna~e/fl~

8.54

Cyanides

Hydrolysis

Atcinic

absorbtian-spectrosoc~r

8,55

Atanic

thexbtjan-f~irnace/fl~

8.56

Mercury

Cold Vaper

Atomic

absorbtia,

8.57

Nickel

O~gestiom

Atomic

~sorbtiom-frn~e/fl~

8.5B

Selenium

Hydride

digestiom

Atomic abs

rbtiom-f

ace/flare

8.59

Silver

Diqesticn

Atomic

thsorbticn-furn~/f1~

61-274

---

—29—

‘rABLE

3—Sarçle

PeparatiofS~1e

IMxodectiom ~c1v&iq~es

SançbIe

handling class

~‘sical

fluid

characteristics

of waste1

Pasta

Solid

Volatile

Ikirge

and tr~.

Direct

injecticri.

‘arge and t~.

5e”~.p~e.

flea~epacs.

Semivol

stile

and

nom~olatile

Direct

injectice.

Shake czit.

Shake

ait.

Shake

oit.

Soxhiet.

Sceicatirn.

Inorganic

Direct

injectice.

Digestice,

Hydride.

Digestice.

Hydride.

Digeaticm.

Hydride.

1tcr pirp~sesof this

Table,

fluid

refers

to readily p~ur~1e

liqiids, which may or

may not

ccntain

aispended particles.

Paste-like

materials,

while

fluid in tha ~ee

of

fl~thility.

can ha thcl3ght of as haing thixo~c~ic

cr

plastic In

nature, e.g.

paints.

Solid

materials

are these

wastes which can ha

handled withcut

a cantainer

(i.e., can ha

piled

up

with~tappeciable

s~ging).

~tx~eEt~re

and Metheds

!3i,~r(s)

Digesticm—See

~croFiate

ircx~eãareIcr

elenent of

interest.

Direct

injectian—8.

80.

Beadspace—8. 82.

Hydride--See aç~rc~riate

Frcxethre

for

elesent

of

interest.

P~rge

& 1~ap—8.83.

Shake

cut——8.84.

Sanicaticm—8.

85.

Sachlet——8.86.

(Source:

Amended

at

7

111.

Reg.

13999,

effective

October

12,

1983,

amended at__

Ill. Reg.

_____________,

effective

6.

Appendix

C of Part 721, which formerly referenced

Appendix VII to

40

CFR

261,

is

printed

out

and

amended

follows:

61-275

---

‘-30—

Appendix C--Basis

for

Listing Hazardc~isWastes

EPA

hasardcus

Hazardous canstit,tents

for

which listed

waste

~b.

___

______________________

POOl

~acMaromthylene,

enthjlene chloride,

~icMorcethylene,

1,1,1-trichicroethane,

carb~

tetrachioride,

chlorinated

fluorecariu~s.

P002

rachlarcethylene, irethylerte

chloride,

trichlorcetlylene,

1,1,

1—trichioroethane,

chlorc~xn~e,

1,1,

2-trichloro-1,

2,

2—triflucz’oethane,

orthe-dichlorthenma~e,

trichioroflu oraiethane.

P003

HA.

P004

C~eenls

and

cresylic aci&

nitrcbenzene.

P005

Toluene,

methyl

ethyl

ket~e,

cartxn

disilfide,

iethitanol,

pyridfxke.

P006

Cadmium,

~xa~ralent

chratuim,

nickel,

cyanide

(camplexed).

P007

Cyanide

(salts).

£008

Cyanide (salts).

P009

Cyanide

(salts).

P01.0

Cyanide

(salts).

£011

Cyanide

(salts).

£012

Cyanide

(camplexed).

FO~9

Mexa-alent

chrceium,

cyanide

(cci~çlexed).

P020

____

f?a~

ach~o

P022

~trach1orci3i1enzo-p-dicxins

P023

T~dioris~s

9001

~ntachlorcphanol,

1*enol

2-cMcrcpI~ol~

p-chloro-m-creaol,

2,

4-ethyl~*enyl,

2,

4-dinitrophenol,

txichlcrc~~ols,tetrachior

~Is,

2,4—dinitrcç)~ol,

cre~sote, chrysene,

naphthalene,

flucrant)~e, hanzo (1~)

-fluoranthane,

benzo(

a)pyrene,

th~o(

1,2,

3-’cd)pyrene,

)~z(

a)anthracene,

dibenz(

a)enthracene,

acenaphthalene.

P002

Hexwaient

chromium,

lead.

9003

Bexaislent

chromium,

lead.

9004

Hexavalent

chra?uUm,

9005

flexwaient

chromium,

lead.

9006

Hexa~alent

chromium.

9007

Cyanide

(complexed),

hexa~’aientchromium.

9008

Hexaralent chromium.

9009

Chloroform,

formaldehyde,

uethjlene

chloride,

methyl

chloride,

paraldehyde,

formic

acid.

9010

Chloroform,

10

~thyde,

nuthylene chloride,

methyl

chloride,

peraldehyde,

formic

acid,

chlcroacetaldehyde.

K03.1

Anrvlanitriie,

acetanitrile,

hydrcx~yanic

acid.

9013

Hydrcuyanic

acid,

acrylcuitrile,

acetanitrile.

9014

Pcetanitrile,

acrylamide,

9015

Henzyl

chloride,

chlcrc~zene,toluene, benzo~ichlcride.

9016

Hexachi

or~nzene, hexachlorcthtaiiene,

car~xmtetrachioride,

lexachioroethane,

parchiorcethylene.

9017

Epichiarchydriri,

chioroethers

!bis(chloromethyl)

ethar

and

his

(2-chicroethyl)

etiers,

trichlorojrcçane,

dichlorolrcc~anol

B.

9013

1,

2—dichloroethane,

trichicroethylene,

hexachlcrt*utadiene, haxacblorthenzene.

9019

Ethylene

dichlcride,

1,1,

1-trichioroethane,

1,

1,2—trichlcroethane,

tetrachlcro

ethanes (1,1,2,2tetrachlorcethane

and

1,1,1,2—tetrachlaroethane),

trzchlcro-

ethylene,

tetrachiorcethylene,

car)xm

t.etxachloride,

chloroform,

vinyl

chloride,

vinylidene

chloride.

9020

!thylene

dichioride,

1,1,

1-trichicroethane,

1,1,

2—trichiorcethane,

tetrachicro-

ethaies

(1,1,

2,2-tetrachlorcethane

aid

1,1,1,

2—tetrachicroethane),

trichiarcethylene,

tetrachiorcethylene,

car)xxi

tetxachicride,

chlcrofomn,

vinyl

chloride,

vinylidene

chloride.

9021

Antimx~y,carbx~tetrachicride,

chloroform.

9022

~meiol,

tars

(pel

ycyclic

aromatic hydrcuarbces).

9023

Ththalic

anhydride,

maleic

athydride.

*124

~thalic

athydride,

1,

4-naphthcqincee.

9025

Meta-dinitrctmnem~e,2,4-din itrotoluene.

*126

Paraldehyde, Fflidines,

2-picoline.

61-276

---

EI~

h~rdou3

Hazardous

cc

tents

for

whic*~

listed

waste No.

_____

______

________

______

9027

Tc~.uenc

dii~yanatn~

t~ueou~~2,

4-dia~i~.

9028

1,~,1-trichlorôethane,vi~~yl

cthlcz~ide.

90Z1

1,

2-diehiorcethane,

1,1, 1~trLchlcroetl~e,vinyl

chloride,

vinyl idene

chloride,

chloroform

1(030

Hexa1oer~a,

~a~hicrchitediane,

haxachiaroethane,

1,1,1,

2-tetrachicro-

ethane,

1,1, 2~

2-~ti~tr3ch1oroetiiane,

ethylene

dichicride.

9031

Arsanic.

9032

~exah1arc ~1opo~ta5ic~rte.

9033

~1cxech1crceyclc~x’nta&ene.

9034

!chlorc~yclopentadiene.

1(035

~recs~ote,

chrysene,

~sphthe~tene, i~l

ant1~e, hanzo(b)

f1ucrant1~ie,

lmnzo(a)-

pyrene,

inãano( 1,2~

3—ed)

pyrene,

lzanzo(a)anthracene,

dihanzo(a)anthracene,

acen~hthalene,

K~)36

Toluene,

~sphrc&thioic

and ~~s~xrothioic

acid

esters.

9037

Toluer~e,~o

~odith~oic

and

phosp~xothioic

acid

esters.

9038

Plxycate,

fonmaldehyde,

phnsphcrcdithioic

and

ç*~sphrrothioic

acid esters.

9039

?1-~sphcrodithioicand phosphcrothioic

acid

esters.

9040

r1iorate,

fona1del~yde,.~osphrzrodithioic

and

ç**~spixrothioic

acid

esters.

9041

Toxap~ane.

9042

iexachior~enzene,

ortho~dich1orth~nzene.

9043

2,4—dich1arc~~hsnol,

~‘ficrcç4~,

2,4,6—trichlcrcç~tol.

9044

LA.

9045

9046

Lead

9047

LA.

9048

~ewalent

chromium,

lead.

904)

Hcx~walentchromium.

lead.

9050

Hctxavalent

chromium,

9051

Hexavalent

chromium,

lead,

14)52

Lead

1(060

Cyanide,

n~thalene, phenc~iccompounds,

arsenic.

9061

flexavalent

chromium,

lead,

caAr~ium,

9062

Hexavalent

chromium,

lead.

9089

!lexavaient chromium,

lead,

cadmium,

9071

Meroury.

1(073

Chloroform,

cartxr~tetrachioride,

hexachioroethane,

trichi oroethane,

tetrachi cr0-

ethylene,

dichioroathylene,

1,1,2,

2-tetrachicroethane.

K0S3

?niline,

henylin~

nitrdoenrene,

~*~enylenedianine.

1(084

7~rmenic.

9095

Henzene, dichiorcbenzenes,

trichlorciienzenes,

tetrachlorctenzenes, ixantachior~-

zene,

IxaxachlorOben zene,

banzyl

chloride.

1(086

Lead,

haxavalent

chromium,

1(087

Phenol,

naphthalene.

9093

Phthalic

athydride,

maleic

anhydride.

9094

Phthalic

enhydri&.

9095

1,1,

2-tzichlaroethane,

1,1,1,2-tetrachioroethane,

1,1,2,

2~-tetrach1

oroethzne.

9096

1,

2-dichlcrcethane,

1,1,

1-triehlcroethane,

1,1,

2—trichloroethane.

9097

thlcrdarte,

haptaahlor.

9098

Toxap~~e.

14)99

2,4—dichlarcçhenc~,2,4,6~trich1oc~t~ol.

1(100

~1exava1entchromium,

lead,

eafM~ium.

1(101

Arsenic.

1(102

Arsenic.

1(103

Anil the,

nitrcixanzene,

phenylenedianine.

1(104

AntI the,

heazene,

diphenyl amine,

nitre

~

phenylenediamine.

1(105

Benzene,

n~oehlorcbenzene, dichlorchenmenes,

2,4,

6-trichlorcp~d.

1(106

lieroury.

N.A.-4lastc

~s

hazar&z~isb~arne

it

fails

tIe

test

for

tIe

characteristic

of

ignitthii it~’.cczrosivity,

or

reactivity.

(Source;

i~ended

at

7 Iii.

Req.

13999,

effective October

12,

1983;

amended at

~,_

Ill.

Reg.

—___

,

effective

---

7~ Appendix H of Part 721 is amended

as follows~

Section 721.Appendix H

Hazardous Constituents

acetonitrile

(ethanenitrile)

acetophen

one

(ethanone,

1

-phenyl

—)

3-(alpha—acetonylbenzyl)—4-hydroxycoumarin

and salts

(warfarin)

2-acetylaminofluorene

(acetamide, N—(9H.~fluoren~2-yi)—)

acetyl chloride (ethanoyl chloride)

I -acetyl

-2-thiourea

(acetamide,

N-

(

aminothioxomethyl

)—)

acrolein

(2-propenal)

acrylamide

(2-pr open ainide)

acrylonitrile

(2-propenenitrile)

afi atoxins

aidrin

(1,2,3,

4,iO,1O-hexachloro—l

,4, 4a,5,

8,

8a—hexahydro—

endo, exo-l ,4:5

8-dimethanonaphthaiene)

ailyl

alcohol

(2—propen—i~ol)

aluminum phosphide

4-aminobiphenyl

(1,1

~biphenyl-4-amine)

6-amino-i, 1 a, 2, 8, 8a,

8b~hexahydro—8—

(

hydroxymethyl

)

-8a-methoxy—

5—methyicarbamate

azirino2~

,3~:3,4pyrrolol,2a)indo1e—

4, 7-dione,

(ester)

(mitomycin

C)

(azirino(2~

,3~

:3,4pyrrolo(l

,2a)indoie—4,7—dione,

6—amino-8-((aminocarbonyl)oxy)methyi—i,ia,2,8,Oa,Sb-

hexahydro-8a-methoxy-’5-methyi-)

5—(aminomethyl)—3—isoxazoiol

(3(2H)-isoxazolone,

5~(aminomethy1)—)

4—aminopyridine

(4—pyridinamine)

amitrole

(1H-l,2,4—triazol-3—amine)

aniline

(benzenamine)

antimony

and

compounds,

N,O,S.

(not

otherwise

specified)

aramite

(suleurous

acid,

2—chioroethyl—,

2—4—(l,l—

dimethyiethyl

)phenoxy

-1-methylethyl

ester)

arsenic

and

compounds,

N,O.S,

arsenic

acid

(orthoarsenic

acid)

arsenic

pentoxide

(arsenic

(V)

oxide)

arsenic

trioxide

(arsenic

(III)

oxide)

aurarnine

(benzenamine, 4,4~—carbonimidoyibisN,N—dimethyi—,

monohydrochloride)

azaserine

(L—serine,

diazoacetate

(ester))

barium and compounds, NOO.S~

barium cyanide

benz

(cacridine

(3,4-benzacridine)

benz

aanthracene

(1, 2—henzanthracene)

61~278

---

*33*

benzene

(cyclohexatriene)

benzenearsonic

acid

(arsonic

acid,

phenyl—)

benzene,

dichioromethyl-

(benzal chloride)

benzenethioi

(thiophenol)

benzidine (i,l~—biphenyi—4,4~—diamine)

benzo(b

fiuoranthene

(2,3-benzofluoranthene)

benzojfluoranthene

(7,8-benzofluoranthene)

benzo apyrene

~3,

4-benzopyrene)

p—benzoguinone

(I ,4—cyclohexadienedione)

benzotrichloride

(benzene,

trichloromethyl—)

benzyl

chloride

(benzene,

(chioromethyl)—)

beryllium and compounds,

N.Q.S.

bis(

2-chioroethoxy)methane

(ethane,

l,1’—methylenebis(oxyflbis2--chloro—)

bis(2-chioroethyl)

ether

(ethane,

1,1~—oxybis2-chioro—)

N,N-bis(2-chloroethyl )-2-naphthylamine

(chiornaphazine)

bis(2—chloroisopropyl)

ether

(propane,

2, 2~—oxybis2-chioro~-)

bis(chloromethyl) ether

(methane,

oxybis Echioro-)

bis(

2-ethyl

hexyl)

phthalate

(1 ,2-benzenedicarboxylic acid, bis(2—ethylhexyl)

ester)

bromoacetone

(2-propanone,

l-bromo-)

bromomethane

(methyl

bromide)

4-bromophenyl

phenyl

ether

(benzene,

l-bromo-4-phenoxy—)

brucine

(strychnidin—lO-one,

2, 3—dimethoxy—)

2-butanone

peroxide

(methyl

ethyl

ketone,

peroxide)

butyl

benzyl

phthalate

(l,2-benzenedicarboxylic

acid,

bityl phenylmethyl ester)

2-sec—butyl-4,6-dinitrophenol (DNBP)

(phenol, 2,4-dinitro~-6-(1-methylpropyl)-)

cadmium and compounds,

N.O.S.

calcium

chromate

(chromic

acid,

calcium

salt)

calcium cyanide

carbon disulfide (carbon bisulfide)

carbon oxyfluoride (carbonyl

fluoride)

chlorai

(acetaldehyde, trichioro—)

chlorambucil

(butanoic

acid,

4— bis(2—chloroethyl)aminolbenzene—)

chiordarie (alpha

and

gamma isomers)

(4,7-methanoindan,1,2,4,5,6,7,8,8—octachloro—

3,4,7,7a—tetrahydro—)

(alpha

and gamma isomers)

chlorinated

benzenes,

N,O.S.

chlorinated

ethane,

N.O,S.

chlorinated

fluorocarbons,

N.O.S.

chlorinated

naphthalene,

N,O.S.

chlorinated phenol, N.O.S,

chioroacetaldehyde

(acetaldehyde,

chloro—)

A1~e”Q

---

—34_

chioroalkyl

ethers,

N.O.S~

p-chloroaniiine

(benzeneamine,

4-chioro—)

chl orobenzene

(benzene,

chi oro—)

chlorobenzilate

(benzeneacetic

acid,

4—chloro—alpha—(

4-chlorophenyl

)-

aipha—hydroxy-,

ethyl

ester)

p-chl oro—m—cresol

(phenol,

4-chioro-3-methyl-)

i-chloro-2,

3—epoxypropane

(oxirane,

2—(chloromethyl)-)

2-chloroethyl

vinyl

ether

(ethene,

(2-chioroethoxy)-)

chloroform

(methane,

trichloro-)

chloromethane

(methyl

chloride)

chloromethyl

methyl

ether

(methane,

chloromethoxy—)

2-chloronaphthalene

(naphthalene,

beta—chloro—)

2-chlorophenol

(phenol,

o-chloro-)

l-(o-chlorophenyl)thiourea

(thiourea,

(2-chiorophenyl)-)

3-chloropropionitriie

(propanenitrile,

3-chloro-)

chromium

and

compounds,

N.O.S.

chrysene

(1, 2-benzphenanthrene)

citrus red No.

2

(2-naphthol,

1-

(2,.5-dimethoxyphenyl

)azo-)

coal

tars

copper

cyanide

creosote

(creosote,

wood)

cresols

(cresylic

acid)

(phenol,

methyl—)

crotonaldehyde

(2—butenal)

cyanides (soluble

salts

and

complexes),

N,O.S.

cyanogen

(ethanedinitrile)

cyanogen bromide (bromine cyanide)

cyanogen chloride

(chlorine

cyanide)

cycasin

(beta-D-glucopyranoside,

(methyl—ONN—azoxy)methyl-)

2—cyclohexyl—4, 6—dinitrophenol

(phenol, 2—cyclohexyl-4,6-dinitro—)

cycl ophosphamide

(2H-l,3,2-oxazaphosphorine,

bis(2—chloroethyl)amino-

tetrahydro-, 2-oxide)

daunomycin

(5,l2—naphthacenedione, (8S—cis)—8—acetyl—lO—

(3-amino’-2,

3, 6-trideoxy)-alpha-L-lyxo—hexopyranosyl

)oxy-

7, 8,9

,

lO-tetrahydro-6, 8, ll-trihydroxy—l-methoxy—)

DOD (dichiorodipheny. dichloroethane)

(ethane,

l,l-dichloro—2,2—bis(p—chlorophenyl)—)

DDE

(ethylene,

l,l—dichloro—2,2—bis(4—chlorophenyl)—)

DOT (dichlorodiphenyltrichloroethane)

(ethane, l,l,l-trichloro-2,2—bis(p—chlorophenyl)-)

diallate

(S—(2, 3—dichioroallyl )diisopropylthiocarbamate)

dibenzfa,hacridine

(1~

2,5,6—dibenzacridine)

61-280

---

-35—

dibenz

a,’jacridine

(1

,2,7,8—dibenzacridine)

dibenz(a,hanthracene

(1

2,5,6—dibenzanthracene)

7H—dibenzoc,gcarbazole

(3,4,5,6—dibenzcarhazole)

dibenzoa,elpyrene

(1,2, 4,5—dibenzpyrene)

dibenzoa,hpyrene

(l,2,5,6—dihenzpyrene)

dibenzoa,ipyrene

(1,2, 7,8—dibenzpyrene)

1 ,2—dibrorno-3-chloropropane

(propane,

l,2—dibrorno-3-chloro-)

1 ,2—dibromoethane (ethylene dibromide)

dibromomethane

(methylene bromide)

di-n-butyl

phthalate

(1 ,2-’benzenedicarboxylic

acid,

dibutyl

ester)

o—dichlorobenzene

(benzene,

1 ,2-dichloro—)

m—dichlorobenzene

(benzene,

1

,

3—dichioro—)

p—dichiorobenzene

(benzene,

1, 4—dichloro—)

dichlorobenzene,

N.O.S.

(benzene, dichloro—, N.O.S.)

3, 3~~-dichlorobenzidine

1 ,1’—biphenyi)--4,4”-diamine, 3,3’—dichloro—)

1, 4—dichloro-2-hutene (2-hutene,

1, 4—dichioro—)

dichiorodifluoromethane

(methane,

dichlorodifluoro—)

1 ,l—dichloroethane

(ethylidine

dichioride)

1, 2-dichloroethane

(ethylene

dichioride)

trans—i,

2—dichloroethene

(1,

2—dichloroethylene)

dichloroethylene, N,O.S,

(ethene,

dichioro—,

N.O..S.)

l,l—dichloroethylene

(ethene,

1,1—dichioro—)

dichioromethane

(methylene chloride)

2, 4—dichlorophenol

(phenol,

2, 4-dichloro—)

2,6—dichlorophenol

(phenol,

2,6-dichloro—)

2,4—dichiorophenoxyacetic

acid

(2,4—D),

salts

and

esters

(acetic acid,

2,4-dichiorophenoxy—,

salts and

esters)

dichlorophenyi arsine

(phenyl

dichioroarsine)

dichioropropane, N.0.S,

(propane,

dichioro—,

N.O.S.)

1, 2—dichloropropane (propylene dichloride)

dichloropropanol, N.O.S.

(propanol,

dichioro—, N.O.S.)

dichloropropene,

N.O.S.

(propene,

dichioro-,

N.O.S.)

1 ,3—dichloropropene

(l—propene, 1,3—dichioro—)

dieldrin

(l,2,3,4,lO,l0—hexachloro—6,7—epoxy—l,4,4a,5,6,7,8,8a—

octahydro-endo,

exo—l ,4:5,

8-dimethanonaphthalene)

1,2:3,4-diepoxybutane (2,2’—bioxirane)

diethylarsine

(arsine,

diethyi—)

N,N’—diethylhydrazine

(hydrazine,

1,2—diethyl—)

0,0-diethyl

S—methyl ester of phosphorodithioic acid

(phosphorodithioic acid,

0,0-diethyl S—methyl ester)

0,0-diethyiphosphoric

acid,

O-p—rtitrophenyl

ester

(phosphoric

acid,

diethyl

p-nitrophenyl

ester)

diethyl

phthalate

(1 ,2—benzenedicarboxylic

acid,

diethyl

ester)

0,0-diethyl

0-2-pyraziriyi phosphorothioate

(phosphorothioic acid,

0,0-diethyl 0-pyrazinyl ester)

diethylstilbestrol

(4,4

—stil benediol,

al pha, aipha—diethyl,

bis(dihydrogen phosphate,

(E)-)

61-281

---

‘-36—

dihydrosafrole

(benzene,

I

,2—methylenedioxy-4-’propyl-)

3, 4—dihydroxy-aipha-(methylamino)methyl benzyl

alcohol

(1 ,2-benzenedioi,

4—

(1—hydroxy—2-(methylamino)ethyl—)

c3iisopropylfluorophosphate

(DFP)

(phosphorofluoridic acid,

bis(l-methylethyl)

ester)

dimethoate

(phosphorodithioic acid,

0,0-dimethyl

B- (2-(methylamino)~~2-oxoethy1ester)

3,31

-dimethoxybenzidine

(1,l~—bipheny1-4,4~-diamine,

3,3’—dimethoxy—)

o—dimethylaminoazohenzene

(benzenamine, N,N-dimethyl--4-(phenylazo)-)

7,12—dimethylbenz aanthracene

(1 ,2—benzanthracene, 7,L2—dimethyl—)

33’ -dimethyibenzidine

(1,1~—hiphenylI—4,4~—diamine,

3,3’—dimethyl—)

dimethylcarhamoyl

chloride

(carbamaoyl

chloride,

dimethyl-)

1,1—dimethyihydrazine

(hydrazine,

1,1—dimethyl—)

1,2-dimethyihydrazine

(hydrazine,

l,2—dimethyl—)

3, 3-dimethyl-l-(methylthio)-2-butanone,

0— (methyl amino)carbonyl

I

oxime

(thiofanox)

alpha,

alpha-dime thyiphenethyl

amine

(ethanamine,

1, 1-dimethyl~-2-phenyl-)

2,4-dimethyiphenol

(phenol, 2,4—dimethyl—)

ditnethyl phthal ate

(1,2—benzenedicarboxylic acid,

dimethyl

ester)

dimethyl sulfate

(sulfuric

acid,

dimethyl

ester)

dinitrobenzene,

N.C.S.

(benzene,

dinitro—,

N.O.S.)

4,6-dinitro-o—cresol

and salts

(phenol,

2,4—dinitro—6-methyl—,

and salts)

2,4-dinitrophenol

(phenol,

2, 4-dinitro-)

2, 4-diriitrotoluene

(benzene,

l—methyl—2, 4—dinitro—)

2,6-dinitrotoluene (benzene, 1—methyl—2,6—dinitro—)

di-n-octyl

phthalate

(1,2-benzenedicarboxylic acid, dioctyl ester)

1,4-dioxane

(1,4-diethylene

oxide)

di phenyl amine

(benzenamine,

N-phenyl

-)

1,2-diphenyihydrazine

(hydrazine,

l,2—diphenyl—)

di-n-propylnitrosamine (N-nitroso—di—n—propylamine)

disul

foton

(0,0-diethyl

S-2-(ethylthio)ethyl

phosphorodithioate

2, 4-dithiobiuret (thioimidodicarbonic diamide)

endosu1 fan

(5—norbornene,

2,3—dimethanol,

1,4,5,6,7,7—hexachioro—,

cyclic

sulfite)

endrin

and

metabolites

(1,,2,3,4,l0,lO—hexachloro—6,7—epoxy—1,4,4a,5,6,7,8,8a—

octahydro-endo,endo-I

,4:5,

8-dimethanonaphthalene,

and

metabolites)

6 1-282

---

—37—

athyl carbamate

(urethan)

(carbamic acid,

ethyl ester)

ethyl

cyanide

(propanenitrile)

ethylenebisdithiocarbamic

acid,

salts and esters

(l,2-’ethanediylbiscarbamodithioic

acid,

salts

and

esters)

ethyleneimine

(aziridine)

ethylene oxide

(oxirane)

e thylenethiourea (2-imidazol idinethione)

ethyl methacrylate

(2—propenoic

acid,

2-methyl-,

ethyl ester)

ethyl

methanesulfonate (methanesulfonic acid,

ethyl ester)

fluoranthene (benzo!j,kfluorene)

fluorine

2—fluoroacetamide (acetamide,

2—fluoro—)

fluoroacetic

acid,

sodium

salt

(acetic

acid,

fluoro—,

sodium

salt)

formaldehyde

(methylene oxide)

formic

acid (methanoic acid)

glycidyl aidehyde

(l-propanal,

2,3—epoxy-)

halomethane, N.0,S

heptachior

(4,7—methano—.H—indene,

1,4,5,6,

7,8,8—heptachioro—

3a,

4,7,7a-tetrahydro-)

heptachlor

epoxide

(alpha,

beta and

gamma

isomers)

(4,7-methano-lH-inder~e, 1,4,5,6,7,8,8—heotachioro—

2,3-epoxy—3a,4,7,7-tetrahydro—,

alpha,

beta

and

gamma

isomers)

hexachlorobenzene

(benzerie,

hexachloro—)

hexachlorohutadiene

(1, 3--hutadiene,

hexachioro—)

hexachiorocyclohexane

(all isomers)

(lindane and isomers)

hexachiorocyclopentadiene

(cyclopentadiene,

hexachloro—)

hexachioroethane

(ethane,

hexachloro—)

l,2,3,4,lO,10—hexachloro—l,4,4a,5,8,8a—hexahydro—l,4:5,8—

endo, ertdo—dimethanonaphthalene

(hexachlorohexahydro-endo,endo-dimethanonaphthalene)

hexachiorophene

2,2 ‘—methylenebis( 3, 4, 6—trichlorophenol)

hexachloropropene

(propene,

hexachloro—)

hexaethyl tetraphosphate

(tetraphosphoric acid,

hexaethyl ester)

hydrazine

(diarnine)

hydrocyanic

acid

(hydrogen

cyanide)

hydrofluoric

acid (hydrogen fluoride)

hydrogen

sulfide

hydroxydimethylarsine oxide

(cacodylic acid)

indeno(1, 2, 3-cd)pyrene

(1,l0—(1 ,2—phenylene)pyrene)

iodomethane

(methyl

iodide)

iron

dextran

(ferric

dextran)

isocyanic

acid,

methyl ester

(methyl isocyanate)

isobutyl alcohol

(l-propanol, 2—methyl—)

61-283

---

—38—

isosafrole

(benzene,

3,

2-methylenedioxy—4—allyl—)

kepone

(decachlorooctahydro—i

,

3,

4—metheno—2H—

cyclobuta (cdipentaien-2-one)

Iasiocarpine

(2—butenoic

acid,

2-methyl—,

7—(2,3—dihydroxy—

2-(1-methoxyethyl )-3-methyl-l-oxobutoxy)methyl-

2,3,5,7a—tetrahydro--1H—pyrrolizin—l—yl

ester)

lead and compounds,

N.0~S,

lead acetate

(acetic acid, lead

salt)

lead phosphate

(phosphoric

acid,

lead salt)

lead suhacetate

(lead, bis(acetato—0)tetrahydroxytri—)

maleic

anhydride (2,5—furandione)

maleic hydrazide

(I ,2—dihydro—3,6—pyridazinedione)

malononitrile (propanedinitrule)

mel phal an

(alanine,

3—(p-bis(2”-chloroethyl)aminolphenyl—,

L—)

mercury fulminate

(fulmInic

acid,

mercury

salt)

mercury and compounds,

N,0.S.

methacrylonitrile (2—propenenitrile,

2—methyl—)

methanethiol

(thiomethanol)

methapyriiene

(pyridine,

2- (2-dimethylamino)ethyl)—2-thenylamino—)

methol myl

(acetimidic

acid,

N- ((methylcarbamoyl)oxylthio—,

methyl ester)

methoxychior

(ethane,

1,1 ,1-trichloro-2, 2’-bis(p-methoxyphenyi

)-)

2—methylaziridine

(3, 2-propylenimine)

3-methylcholanthrene

(benz jaceanthrylene,

l,2-dihydro—3—methyl—)

methylchi

or

ocarbonate

(carbanochioridic acid,

methyl ester)

4, 4‘—methylenebi s( 2—chloroanilme)

(4,4’—methylenebis(2—chlorobenzenamine))

methyl

ethyl

ketone

(MEK)

(2-butanone)

methyl hydrazine (hydrazine,

methyl—)

2-methyllactonitrile (propanenitrile, 2-hydroxy—2—methyl-)

methyl

methacrylate

(2-propenoic

acid,

2—methyl—,

methyl

ester)

methyl

methanesulfonate

(methanesulfonic

acid,

methyl ester)

2-methyl-2-(methylthio)propional dehyde-0-

(methylcarbonyl)

oxime

(propanal,

2—methyl-2-(iuethylthio)—,

0- E(methylamino)carbonyiloxime)

N-methyl-N -nitro-N-nitrosoguanidine

(guanidine, N—nitroso-N-methyl-N’—nitro-)

methyl parathion

(0,0—dimethy.

O-( 4—nitrophenyl) phosphorothioate)

methylthiouracil

(4-1H-pyrimidinone,

2 .3-dihydro-6-methyl-2-thioxo--)

mustard gas

(sulfide, bis(2—chloroethyl)—)

61-284

---

naphthalene

1

,4—naphthoquinone

(1, 4-naphthaienedione)

l—naphthyl amine

(alpha-n

aphthyl

amine)

2-naphthylamine

(beta—naphthylamine)

1—naphthyl-2—thiourea

(thiourea,

1—naphthalenyl—)

nickel

and compounds,

N.0,S,

nickel carbonyl

(nickel

tetracarbonyl)

nickel

cyanide

(nickel

(II)

cyanide)

nicotine and salts

(pyridine,

(S)—3—(i-methyl—2—pyrrolidinyl)—,

and

salts)

nitric

oxide

(nitrogen

(II)

oxide)

p-nitroanilme

(benzen

amine,

4—nitro—)

nitrobenzene (benzene,

nitro—)

nitrogen dioxide

(nitrogen

(IV) oxide)

nitrogen mustard and

hydrochloride

salt

(ethanamine,

2—chloro--,

N-’(2-chloroethyl)-N—methyl—,

and hydrochloride salt)

nitrogen mustard Noxide and hydrochloride salt

(ethanamine,

2-chioro--,

N—(2—chloroethyl)-N—methyl—,

N—oxide,

and

hydrochloride

salt)

nitroglycerin (1,2,3—propanetriol, trinitrate)

4—nitrophenol

(phenol,

4-nitro—)

4—nitroguinoline—l-oxide

(cininoline,

4—nitro-l—oxide—)

nitrosamine,

N.0.S.

N-nitrosodi—n-butyl

amine

(I

-butanamine,

N-butyl -N—nitroso-)

N-nitrosodiethanolamine (ethanol, 2,2’—(nitrosoimino)bis—)

N—nitrosodiethylamine

(ethanamine, N-ethyl-N-nitroso—)

N-nitrosodimethylamine

(dimethylnitrosamine)

N-nitroso-N-ethylurea

(carbamide,

N-ethyl—N-nitroso—)

N—nitrosomethylethylamine

(ethanamine, N-methyl-N—nitroso—)

N-nitroso-N-methylurea (carbamide, N-methyl-N—aitroso—)

N-ni troso-N—methylurethane

(carbamic

acid,

methylnitroso—,

ethyl ester)

N-riitrosomethylvinylamine

(ethenaniine,

N-methyl-N-nitroso-)

N-nitrosomorpholine (morpholine,

N-nitroso-)

N—nitrosonornicotine

(nornicotine, N—nitroso—)

N—nitrosopiperidine

(pyridine,

hexahydro—,

N—nitroso—)

N-nitrosopyrrolidine (pyrrole, tetrahydro-, N—nitroso-)

N—riitrososarcosine (sarcosine,

N—nitroso—)

5—nitro-o-toluidine (benzenaxnine, 2—methyl-5—nitro—)

octamethylpyrophosphoramide

(diphosphoramide,

octamethyl-)

osmium tetroxide (osmium (VIII)

oxide)

7—oxabicyclo2.2.l)heptane—2,3—dicarboxylic

acid

(endothal)

para. dehyde

(1,3,5—trioxane,

2,.4,6—trimethyl—)

parathion

(phosphorothioic

acid,

0,0-diethyl

O-(p-nitrophenyl)

ester)

pentachlorobenzene

(benzene,

pentachloro—)

pentachloroethane (ethane, pentachloro-)

61-285

---

—40—

pentachloronitrobenzene (PCNB)

(benzene, pentachioronitro—)

pentachi.or ophenol

(phenol,

pentachioro-)

phenacetin

(acetamide, N-(4-ethoxyphenyl)-)

phenol

(benzene, hydroxy-)

phenylenediamine (benzenediamine)

phenylmercury acetate

(mercury, acetatophenyl—)

N-phenylthiourea (thiourea,

phenyl-)

phosgene

(carbonyl chloride)

phosphirie

(hydrogen

phosphide)

phosphorodithioic

acid, 0,0—diethyl

S- (ethylthio)methyl

ester

(phorate)

phosphorothioic

acid,

0,0—dimethyl

0-p-((dimethylamino)sulfonyl)phenyl)

ester

(famphur)

phthalic acid esters,

N.O.S.

(benzene, 1,2—dicarboxylic

acid,

esters,

N.O.S..)

phthalic

anhydride

(1 ,2-benzenedicarboxylic

acid anhydride)

2-picoline

(pyridine,

2—methyl—)

polychiorinated

biphenyl,

N.0.S.

potassium

cyanide

potassium silver cyanide

(argentate(l—),

dicyano—, potassium)

prortamide

(3,5-dichloro—N—(l,l-dimethyl—2—propynyl)benzamide)

1,3—propane sultone

(1,2-oxathiolane

2,2-dioxide)

n—propylamine (1-propanamine)

propyithiouracil

(2,3—dihydro-6-propyi-2-thioxo-4(1H)—pyrimidinorte)

2-propyn-l-ol

(propargyl

alcohol)

pyridine

reserpine

(yohimban-16-carboxylic

acid,

11 ,l7—dimethoxy—

l8-(3,4,5-trimethoxybenzoyl)oxy-,

methyl

ester)

resorcinol

(1,3-benzenediol)

saccharin and salts

(1 ,2-benzoisothiazolin—3—one,

1,1—dioxide,

and

salts)

safrole

(benzene,

1,

2-methylenedioxy-4—allyl—)

selenious acid (selenium dioxide)

selenium and compounds,

N.O.S.

selenium sulfide (sulfur selenide)

seleriourea

(carbamimidoselenoic

acid)

silver and compounds,

N.0.S.

silver cyanide

sodium cyanide

streptozotocin

(D-glucopyranose,

2-deoxy-2-( 3-methyl—3—nitrosoureido)—)

strontium sulfide

strychnine and salts

(strychnidin—lO-one,

and

salts)

l,2,4,5-tetrachlorobenzene

(benzene, 1,2,4,5—tetrachioro—)

61-286

---

—41—

~~~benzçpo~ins

2,3,7, 8—tetrachlorodibenzo—p-dioxin

(TCDD)

(dihenzo—p-clioxin,

2,3,7,8—tetrachloro—)

tetrachloroethane,

N.0,S.

(etharie,

tetrachloro—,

N.0.S.)

1,1

,

1,

2—tetrachioroethane

(ethane,

1

,

1

,

1, 2—tetrachloro—)

l,i,2,2—tetrachloroethane (ethane,

l,l,2,2—tetrachloro—)

tetrachioroethene

(perchioroethylene)

tetrachioromethane

(carbon

tetrachloride)

2,3, 4, 6—tetrachiorophenol (phenol,

2,3, 4, 6-tetrachloro—)

tetraethyidithiopyrophosphate

(dithiopyrophosphoric

acid, tetraethyl ester)

tetraethyl

lead

(plumbane,

tetraethyl-)

tetraethylpyrophosphate (pyrophosphoric acid,

tetraethyl ester)

tetranitromethane (methane, tetranitro-)

thallium

and

compounds,

N0S

thallic oxide (thallium

(III)

oxide)

thallium

(I)

acetate

(acetic

acid, thallium

(I)

salt)

thallium

(I)

carbonate

~carbonic

acid,

dithallium

(I)

salt)

thallium

(I)

chloride

thallium

(I)

nitrate

(nitric

acid,

thallium (I)

salt)

thallium selenite

thallium

(I)

sulfate (sulfuric

acid, thallium

(I) salt)

thioacetamide

(ethanethioamide)

thiosemicarbazide

(hydrazinecarbothioamide)

thiourea

(carbainide,

thio-)

thiurain (bis(dimethylthiocarbamoyl)

disulfide)

toluene

(benzene, methyl-)

toluenediamine

(2, 4—diaminotoluene)

toluene diisocyanates,

N.0.S.

o-toluidine hydrochloride

(benzeneamine,

2-methyl-,

hydrochloride)

toxaphene (camphene,

octachioro-)

tribromomethane

(bromoform)

1 ,2,4—trichlorobenzene (benzene, l,2,4—trichloro—)

1,1,l—trichloroethane

(methyl chloroform)

l,1,2—trichloroethane

(ethane, l,1,2—trichloro—)

trichloroethene

(trichloroethylene)

trichioromethanethiol

(methanethiol, trichloro—)

trichloromonofluoromethane

(methane,

trichlorof.uoro—)

2,4,5—trichiorophenol

(phenol, 2,4,5—trichioro—)

2,4,6—trichlorophenol

(phenol,

2,4,6—trichloro—)

2,4,5—trichiorophenoxyacetic

acid

(2,4,5—T)

(acetic

acid,

2, 4, 5—trichlorophenoxy—)

2,4,5—trichlorophenoxypropionic acid (2,4,5—TP)

(silvex)

(propionic acid,

2-(2, 4,5—trichiorophenoxy)—)

trichloropropane, N.0.S,

(propane,

trichloro-,

N.,0.S.)

1

,

2, 3-trichloropropane

(propane,

1,2,

3-trichloro—)

---

42—

0,0 ,0—triethyl.

phosphorothioate

(phosphorothioic acid,

0,0,0-triethyl ester)

sym—trinitroberizene

(benzene,

1,3,5—trinitro—)

tris(1—aziridinyl) phosphine sulfide

(phosphine

sulfide, tris(l-aziridinyl)—)

tris( 2, 3-dibromopropyl) phosphate

(1-propanol,

2, 3-dibromo-,

phosphate)

trypan

blue

(2,7—naphthalenedisulfonic

acid,

3,3’—

(3,3’—

dimethyl(1,l~—biphenyl)—4,4’—diyl)bis(azo)bis(5—

amino—4—hydroxy—, tetrasodium salt)

undecamethylenediamine,

N,N’—bis(2—chlorohenzyl)—,

dihydrochloride

(N,N’-undecarnethylenebis(2-chlorobenzylamine),

dihydrochioride)

uracil

mustard

(uracil, 5—bis(2—chloroethyl)amino—)

~ianadic

acid,

ammonium

salt

(ammonium

vanadate)

c,anadium

pentoxide

(vanadium

(V)

oxide)

vinyl

chloride (ethene,

chloro—)

zinc cyanide

zinc phosphide

(Source:

Amended

at

7

Ill.

Reg.

13999,

effective

October

12,

1993;

amended at

____Ill. Reg._,__

,

effective____~_.)

8.

Appendix

I of Part 721 is added as follows:

Appendix

I--Method

of

Analysis

for

Chlo~~ted

dibenzo-p—dioxins and

dibenzofurans

Method 8280

1.

Scope

arid

Application

1.1

This method covers the determination of chlorinated

dibenzo-p-dioxins and chlorinated dibenzofurans in chemical

wastes including

still

bottoms,

filter

aids,

sludges,

spent carbon,

and reactor residues,

and in soils.

‘This

method

is

appropriate

for

the

analysis

of

tetra—,

penta-,

and hexachlorinated dibenzo—p—dioxins and -dibenzofurans.

2Analytical protocol

for determination of TCDDs in

phenolic chemical

wastes and soil

samples obtained from the

proximity of chemical

dumps.

T.

0. Tiernan and

£4.

Taylor,

l3rehm Laboratory, Wright State University,

Dayton,

OH 45435.

612-88

---

—43—

1.2

The

sensitivity

of

this

method

is

dependent

upon

the

level

of

interferences.

1.3

This

method

is

recommended

for

use

only

by

analysts

experienced with residue analysis and skilled in mass

spectral

analytical

techniques.

1.4

Because

of

the

extreme

toxicity

of

these

compounds

the analyst

must

take

necessary

precautions

to

prevent

exposure to himself,

or to others,

of materials

known

or

believed to contain CDDs

or CDFs.

2.

Summary of the

Method

2.1

This method is

an

analytical

extraction

cleanup

pro-

cedure,

and capillary

column

gas chromatography—low

resolution mass spectrometry method, using capillary

column GC/MS conditions and

internal

standard

techniques,

which allow

for the measurement of PCDDs and PCDFs in the

extract.

2.2

If interferences are encountered,

the method provides

selected

general

plrpose

cleanup

procedures

to

aid

the

analyst

in

their

elimination,

3.

Interferences

3.1

Solvent, reagents,

glassware,

and other sample

processing hardware

may

yield

discrete

artifacts

and/or

elevated

baselines

causing

misinterpretation

of

gas

chromatograms.

All

of

these materials must be demon-

~Footnote

continued from previous page.)

Analytical

protocol

for determination of chlorinated

dibenzo—p-dioxins and chlorinated deberizofurans

in river

water.

T,

o• Tiernan and

£4.

Taylor, Brehm Laboratory,

Wright State

University,

Dayton,

OH

45435.

41n general, the techniques that should be used to handle

these materials are those which are followed for radioactive

or infectious laboratory materials.

Assistance

in evaluating

laboratory practices may be

obtained

from

industrial

hygienists

and

persons

specializing

in

safe

laboratory

practice.

Typical

infectious waste incinerators are probably not satisfactory

devices for disposal of materials highly contaminated with

CDDs or

CDFs.

A laboratory

planning to use these compounds

should prepare

a disposal plan to

be reviewed

and

approved by

CPA’s Dioxin Task Force (Contact Conrad Kleveno, WII-548A,

u.S.

EPA,

401 M Street,

S.W., Washington,

D.C.

20460).

,:~1~!~QQ

---

-44—

strated to

be

free from interferences under the

conditions

of the analysis by running method blanks.

Specific selection of

reagents

and

~irification

of

solvents by distillation in all—glass systems may he

required.

3.2

Interferences co—extracted from the samples will

vary

considerably

from

source

to

source,

depending

upon

the

diversity

of

the

industry

being sampled.

PCDD is

often associated with other interfering chlorinated

compounds

such

as PCB’s which may

be at concentrations

several

orders of magnitude higher

than

that

of

PCOD.

While general cleanup techniques are provided as part of

this

method,

unique samples may require additonal cleanup

approaches to achieve the sensitivity stated

in Table

1.

3.3

The other isomers of

tetrachlorodibenzo—p-dioxin

may

interfere with the measurement of

2,

3,

7,

8—TCDD.

Capillary

column

gas chrornatograph is required to resolve

those isomers that yield virtually identical mass frag-

mentation patterns.

4.

Apparatus and

Materials

4.1

Sampling

equipment

for discrete or composite

camp.

ing.

4. 1. 1

Grab sample bottle—-amber glass,

1—liter or

1—quart volume.

French or Boston Round design is

recommended.

The

container

n~st

be

washed

and

solvent

rinsed before use to minimize interferences.

4.1.2

Bottle

caps—-threaded

to

screw

on

to

the

sample

bottles.

Caps

must

be lined with Teflon.

Solvent washed

foil,

used

with

the

shiny

side

towards

the

sample,

may be

substituted

for

the Teflon

if sample

is not corrosive.

4.1.3

Compositing equipment--automatic or manual

compositing system.

No tygon or rubber

tubing

may

be

used,

and the system

must

incorporate glass sample