ILLINOIS

POLLUTION CONTROL BOARD

October

12,

1984

IN

THE

~4ATTE:R

OF:

)

HAZARDOUS

WASTE

LISTINGS

AND

TEST

)

R84—34

MF~HOE~

TCR

THL

IDENTIFICATION OF

)

TETRACHLOROL~IBENZO-p—DIOXINS

PROPOSED

RULE.

ORDER

OF

THE BOARD

(by

J.

D.

Dumelle);

Public

Act 83—1235, which became law on July

30,

1984,

contains

the following mandate for the adoption of Board

regul

ations:

~Section

22.4

(d)

The Board shall adopt regulations within 120

days

after the effective date of this amendatory Act

which list tetrachlorodibenzo—p—dioxins as hazardous

wastes and which provide test methods for identifying

the presence of tetrachlorodibenzo-p-dioxins in waste

unless

a federal regulation listing

such dioxins as

hazardous wastes

and

establishing test methods has been

promulgated

by the U.S. Environmental Protection Agency

prior

to

adoption of

such regulations.

Any

such

federal

regulations

adopted

pursuant

to subsection

(a)

shall

supersede

Board

regulations adopted pursuant to

this

subsection,

The provisions of Title VII of this Act and

Section 5 of the Illinois Administrative Procedure Act

shall not apply to regulations adopted pursuant to this

subsection,”

(Ill.

Rev. Stat.

1984,

ch. 111½

par.

1022.4.)

This language evinces dual legislative purposes.

It

demonstrates

an

intent

to

list

these

dioxins

as

hazardous

wastes

and

adopt

test

methods

under

Illinois

law

as

quickly

as

possible,

and

in

addition,

an

intent,

to

have

these

listings

and

test

methods

conform

to

any

federal

rule

on

the

same

subject.

The

effect of this listing is

to

require

handlers

of

wastes

con-

taining

these

dioxins

to comply with the Board~shazardous waste

regulatory

standards,

A

federal

rule

containing

a

listing

and

test

methods

for

tetrachlorodibenzo—p—dioxins

(as

well

as

other

listings)

was

proposed

on

April

4,

1983

in

the

Federal

Register.

At

the

tii~ie

that

P,A.

83—1235 was enacted,

it

was

anticipated

that the U.S. Environmental

Protection

Agency

(U.S.

EPA)

would

complete

its proposed rulemaking and adopt a final rule listing

these dioxins as hazardous wastes very shortly.

iowever,

as of

this date,

U.S. EPA has indicated that

a final rule will not be

published before early 1985.

P.A. 83-1235 must be interpreted as

8O~3O7

---

—2—

h~ingforeseen the possiblity that final federal rulemaking

would be delayed~

In the event of

such

a delay,

the statutory

language requires that Board rules be

adopted to meet

the

immediate concern about the regulation of dioxins and to fill the

~gap” until federal regulations are adopted~

The Board delayed opening a docket

in this proceeding until

it could determine whether U.S. EPA would finalize its proposal

before the~120 day deadline

or

by November 27,

1984.

Having now

received information that U.S. EPA will not act before that date,

it is the Board~sintention to proceed quickly to adopt regulations

establishing this listing.

In an effort to address the dual intent of P.A.

83—1235,

the

Board

on its own motion hereby proposes that the federal proposal

published in the Federal Register on April

4,

1983

(48 Fed, Reg.

14514-14529)

in

so far as it relates to tetrachlorodibenzo-p-dioxins

be adopted as an Interim Rule,

The

logic underlying this approach

is obvious.

An interim rule

should parallel the anticipated

final federal rule

as closely as possible

in

order

to

minimize

disruption of the system when

a final rule is promulgated.

Absent any further

indication from U.S. EPA as to the content

of

their final

rule,

the April

4,

1983 proposed rule is our best

information

as

to

the

content

of

the

final

rule.

The

April

4,

1983 proposed federal rule addresses quite

a

hit more than the legislature has instructed the Board to adopt

in

this

rulemaking.

For example,

the federal proposal

lists

chlorinated

dibenzofurans as well

as a great many more isomers of

dioxin

than

are

encompassed by the tetrachlorodibenzo-p-dioxin

structure~

In

addition,

the federal proposal prescribes special

~RCRA~

operating

standards for the handling of wastes containing

these

materials.

It is the Board’s intention to adopt only that

portion of the federal proposal which is necessary

to

accomplish

the

purposes

of

P.A.

83—1235.

A preliminary review of the federal

proposal indicates that this will require

amending four sections

and three appendices of the Illinois “RCRA” rules,

as well as the

adoption of

a new Appendix

I

containing the test

method,

The

Board particularly solicits comment

on the

scope

and

adequacy

of

these

amendments

in

accomplishing

the

purposes

of

P.A,

83—1235.

The

Board

notes that

P,A.

83—1235

provides that neither the

rulemaking provisions of the Illinois Administrative Procedure

Act

nor

Title

VII of the Illinois Environmental Protection Act

apply

to

this rulemaking.

The “waiver” of these procedures,

as

well

as

the

limited review period,

support the position that full

Board

review

of

the merits of the federal proposal was not intended.

Nonetheless,

the

Board

will accept public comment on this proposal

until

Monday,

November

12,

1984.

Adoption of this Interim rule

is expected to take place

at the November 21,

1984 Board Meeting.

60-308

---

—3—

TEXT OF PROPOSED RULE

1.

Section 721.105

is

amended

as

follows:

Section 721.105

Special

Requirements

for

Razardou.s

Waste

Generated by Small Quantity Generators

a)

A generator is a small quantity generator in a calendar month

if

he generates

less

than 1000 kilograms of hazardous waste

in that month.

Part 700 explains the relation

of

this to the

100

kg/mo

exception of

Chapter 9.

b)

Except for those

wastes

identified

in

paragraphs

(e)

and

(f)

of this section,

a small

quantity generator~shazardous wastes

are not subject to regulation under Parts

722

through 725 and

40 CFR Parts 122 and

124,

and

the

notification

requirements

of Section 3010 of

RCRA,

provided

the

generator

complies

with

the requirements of

paragraph

(g)

of

this

section,

c)

Hazardous waste that is beneficially used

or re—used or

legitimately recycled or reclaimed and that is excluded from

regulation by §721,106(a)

is not included

in the quantity

determinations of this section,

and

is not subject to any

requirements of this section,

Hazardous waste that is

subject

to the special requirements of §721,106(b) is included in the

quantity determinations

of

this section and is subject to the

requirements of this section.

d)

In determining the quantity of hazardous waste he generates,

a

generator

need not include:

1)

His

hazardous waste when it is removed from on—site

storage; or

2)

Hazardous waste produced

by

on—site

treatment of his

hazardous waste,

e)

If

a small quantity

generator

generates

acutely

hazardous

waste in a calendar

month in quantities greater than set

forth below,

all quantities of that acutely hazardous waste

are

subject to regulation under Parts 722 through 725 and

40 CFR Parts 122 and 124,

and the notification requirements

of Section 3010 of RCRA:

1)

A total

of one kilogram

of

~

~

gene

~

~

~

~

~~1hazardous

wastes Xi

stea inSections~21.131,

or

---

2)

A

total

of

100

kilograms

of any residue or contaminated

soil,

water

or

other

debris

resulting

from

the

clean-up

of

a

spi1

1,

into

or

on

any

land

or

water,

of

any

~

~

~

~

acutely

hazardous

wastes

listed

in

Sections

721.131,

7~TT~T

or

72i~133~e),

f)

~

small

quantity

generator

may

accumulate

hazardous

waste

on—site.

If

he

accumulates

at any

time

more than a total

of

1000 kilograms of

his

hazardous

waste,

or his acutely

hazardous wastes in

quantities greater than set forth in

paragraphs

(e)(i)

or

(e)(2)

of this section,

all of those

accumulated

wastes

for

which the accumulation limit was

exceeded

are

subject to

regulation

under Parts 722 through

725

and 40 CFR

Parts

122

and

124,

and the notification

requirements

of

Section 3010 of RCRA.

The time

period

of

§722,134 for accumulation

of wastes on—site begins for

a

small quantity

generator when the accumulated wastes exceed

the

applicable

exclusion

level.

g)

In order

for hazardous waste generated by a small quantity

generator to he excluded from full regulation under this

section,

the generator must:

1)

Comply

with §722.111;

2)

If

he

stores

his

hazardous

waste

on—site,

store

it

in

compliance with

the

requirements of

paragraph

(f)

of

this

section;

and

3)

Either

treat

or

dispose

of

his

hazardous

waste

in

an

on—

site

facility,

or

ensure

delivery

to

an

off—site

storage,

treatment

or

disposal

facility,

either

of which is:

A)

Permitted

under

40

CFR Part 122;

B)

In interim

status

under

Part

725

and

40

CFR

Part

122;

C)

Authorized

to

manage

hazardous

waste

by

a

State

with a hazardous

waste

management

program

approved

under

40 CFR Part 123~

0)

Permitted,

licensed

or

registered

by

a

State

to

manage municipal

or

industrial

solid

waste;

or

60-310

---

—5—

B)

A

facility

which:

1)

Beneficially

uses

or

re—uses,

or

legitimately

recycles

or

reclaims

his

waste;

or

ii)

Treats

his

waste

prior

to

beneficial

use

or

re—use,

or legitimate recycling or reclamation.

h)

Hazardous

waste

subject

to

the

reduced

requirements

of

this

section

may

be

mixed

with

non—hazardous

waste

and

remain

sub-

ject

to

these

reduced

requirements

even

though

the

resultant

mixture

exceeds

the

quantity

limitations

identified

in

this

section,

unless

the

mixture

meets

any

of

the

characteristics

of

hazardous

wastes

identified

in

Subpart

C.

i)

If

a

small

quantity

generator

mixes

a

solid

waste

with

a

hazardous

waste

that

exceeds

a

quantity

exclusion

level

this

section,

the

mixture

is

subject

to

full

regulation.

(Source:

Amended

at

6

Ill.

Reg.

4828,

effective

as

noted

in

§700,106;

amended

at

________Ill.

Reg.________

,

2.

Section

72L107

is

amended

as

Section

721.107

Residues

of

Hazardous

Waste

In

Containers

a)

1)

Any

hazardous

waste

remaining

in

either

an

empty

container

or

an

inner

liner

removed

from

an

empty

container,

as

defined

in

paragraph

bi

of

this

section,

is

not

subject

to

regulation

under

Parts

721

through

725

or

40

CFR

Part

122

or

124

or

to

the

notification

requirements

of

Section

3010

of

RCRA.

2)

Any

hazardous

waste

in

either

a

container

that

is

not

empty

or

an

inner

liner

removed

from

a

container

that

is

not

empty,

as

defined

in

paragraph

Eb

of

this

section,

is

subject

to

regulations

under

Parts

721

through

725

and

40

CFR

Parts

122

and

124

and

to

the

notification

requirements

of

Section

3010

of

RCRA.

b)

1)

A

container

or

an

inner

liner

removed

from

a

container

that

has

held

any

hazardous

waste,

except

a

waste

that

is

compressed

gas

or

that

is

identified

~n-Seet~ert

~~4e+

as

an

acutely

hazardous

waste

listed

in

Sections

721.131,

721.132,

or

721,133(e)

iiempty

if:

A)

All

wastes

have

been

removed

that

can

be

removed

using

the

practices

commonly

employed

to

remove

materials

from

that

type

of

container,

e.g.,

pouring,

pumping,

and

aspirating,

and

---

—6—

B)

No

more

than

2.5

centimeters

(one

inch)

of

residue

remain on the bottom of the

container or inner

liner,

2)

A

container that has held

a hazardous wast& that is

a

compressed

gas

is

empty

when

the

pressure in the

container approaches atmospheric.

3)

A

container

or

an

inner

liner

removed

from

a

container

that has held

a

hazardous

waste

ent4e&—~—S~2~~4e3

listed

in

Sections

721.131,

721,132

or

721.133(e)

is

empty if~

A)

the container or inner liner has been triple rinsed

using

a solvent capable of removing the commercial

chemical

product

or

manufacturing

chemical

intermediate;

B)

the

container

or

inner

liner

has

been

cleaned

by

another

method

that

has been

shown

in

the

scientific

literature,

or

by

tests

conducted

by

the

generator,

to

achieve

equivalent

removal;

or

C)

in the

case

of

a

container,

the

inner

liner

that

prevented

contact

of

the

commercial

chemical

product

or

manufacturing

chemical

intermediate

with

the

container,

has

been

removed.

(Source:

Amended at

6

Ill.

Reg.

4828,

effective

as

noted

in

S700,106;

amended at _______Ill.

Reg.

_effective

3,

Section 721.131 is

amended

as

follows:

Section

721.131

Hazardous

Wastes

From

Nonspecific

Sources

Industry

and

EPA

-Hazardous

Waste

Hazard

code

hazardoun

waste

No.

~

Generic

FOOl

The

following

spent

halogenated solvents used

in degreasing:

(T)

tetraohloroethylene,

trichioroethylene, methylene chloride,

1,1,1-trichioroethane,

carbon tetrachioride,

and chlorinated

fluorocarbons;

and

sludges

from the recovery

of

these

solvents

in degreasing operations.

P002

The following

spent

halogenated solvents: tetrachioroethylene,

CT)

methylene

chloride,

trichioroethylene,

1,1, 1—trichloroethane,

chlorobenzene,

1, l,2—trichloro—l,2,2—trifluoroethane,

ortho—

dichlorobenzene,

and

trichiorofluoromethane;

and the still

bottoms

from the recovery of these solvents.

P003

The following

spent

non—halogenated

solvents:

xylene,

acetone, ethyl

(I)

acetate,

ethyl benzene,

ethyl ether,

methyl isobutyl ketone,

n-hutyl

alcohol,

cyclohexanone,

and methanol;

and the ~till

bottoms

from the recover~/of these

solvents.

P004

The following

spent

non-halogenated

solvents:

cresols and cresylic

(T)

acid,

and nitrobenzene~

and

the

still bottoms from the recovery

of these solvents,

P005

The following spent non—halogenated

solvents:

toluene, methyl

ethyl

(I,

T)

ketone,

carbon disulfide,

isobutanol,

and

pyridine;

and

the

still

bottoms from the recovery

of these solvents.

60-312

---

—7—

Industry and

EPA

Hazardous Waste

Hazard code

haz

ardou

swasteNO,

—~

Generic:

P006

Wastewater treatment sludges from electroplating operations

except

(T)

from the following processes:

(1)

sulfuric

acid anodizing

of

aluminum;

(2)

tin plating on carbon steel;

(3)

zinc plating

(segregated basis) on carbon

steel;

(4) aluminum or zinc—

aluminum plating on carbon

steel;

(5) cleaning/stripping

associated with tin,

zinc

and aluminum plating on carbon

steel;

and

(6) chemical etching and milling of

aluminum.

P019

Wastewater treatment sludges

from

the

chemical

conversion

coating

(T)

of aluminumS

P007

Spent cyanide ~1atln~bath solutions from electroplating

operations

(R,

T)

(except

for precious metals electroplating

spent

cyanide

plating

bath solutions).

P008

Plating bath sludges from the

bottom of plating baths from

(p.,

T)

electroplating operations where cyanides

are used in the

process

(except for precious metals electroplating plating bath

sludges).

P009

Spent stripping

and cleaning

bath

solutions from electroplating

(R,

T)

operations where

cyanides

are

used

in

the

process

(except for

precious metals electroplating spent stripping and cleaning

bath

solutions).

POlO

~isnching

bath

sludge

from

oil baths from metal heat treating

(R,

T)

operations

where

cyanides

are

used in the process (except

for

precious

metals

heat-’treating

quenching

bath

sludges).

FOil

Spent

cyanide

solutions

from

salt

bath

pot

cleaning

from

metal

CR,

T)

heat treating

operations

(except

for

precious

metals heat

treating

spent

cyanide

solutions

from

salt

bath

pot cleaning).

P012

~ienching

wastewater

treatment

sludges

from

metal

heat

treating

(T)

operations

where

cyanides

are

used

in

the

process

(except

for

precious

metals

heat

treating

quenching

wastewater

treatment

sludges).

P020

Wastes

(exce

t

wastewater

and

s

nt carbon from h dro en

fl!j

~

uctionor

manU~’

facturjr.

use

(as

a

reactant

chemical

intermediate,

pr co~pp~ntma

orsuat pg~

process

otr

or

ntachloro

henol

or

of

intermediates_used

to

reduce

~

s

not

incue

wastes

from the

oduction of Hexachioro hene

from hi

hl

rified

~oroeno.

P021

Wastes

(exce

t

wastewater

and

8

nt

carbon

from

dro

en

chloride

ion

r orn te manu

actur n

use

as

a reactan

t

chemical

intermediate

or com

nent

in

a

formulatin

ocess

9ra~,p~ta-orhexachlorobenzenesundera1kane

conditions.

P022

Wastes

exee

t

wastewater

and

s

nt carbon

from

dro en

1~LL

~

uct on a

materials

on

e

i

ment

eviousl

used

for

the

reduction

or

~acturn

use__asa~eactant,

cemca

n~r~e4~te

______

~ocess)

of

materials

listed

P023

Disca~~used

formulations

containing tri~,tetra—, or

~~henplordisear~~nused

forsu1ations~~~inin

~erivedfromthesech1orohenols,

Rfl~i~

---

—es—

4,

Section 721.133

is

amended

as

follows:

Section

721.133

Discarded

Commercial

Chemical

Products,

Of

f—

Specification

Species,

Containers

and

Spill

Residues

The following

materials

or

items

are

hazardous

wastes

if

and

when

they

arc

discarded

or

intended

to

be

discarded:

a)

Any

commercial

chemical

product,

or

manufacturing

chemical

intermediate

having

the

generic

name

listed

ifl

paraqralhs

(e)

or

(f)

h)

Any off-specification commercial chemical product or

manufacturing chemical intermediate which,

if it

met

specifications,

would

have

the

generic

name

listed

in

paragraphs

(e)

or

(f).

C)

Mv

container

or

inner

liner

removed

from

a

container

that:

has

been

used

to

hold

any

commercial

chemical

product

or

manufacturing

chemical intermediate having

the

qeneric

names

listed

in

paragraph

(e),

or

any

container

or

inner

liner

removed

from

a

container that

has

been

used

to

hold

any

off—specification

chemical

product

and

manufacturing chemical intermediate which,

if

it met specifications,

would have the generic name

listed in paragraph

(e), unless:

I)

The

container

or inner

liner

has

been

triple

rinsed

using

a solvent capable

of

removing

the

commercial

chemical

product or manufacturing

chemical

intermediate;

2)

The container

or

inner

liner

has

been

cleansed

by

another

method

that

has

been

shown

in

the

scientific

literature,

or by tests conducted by the generator,

to

achieve equivalent

removal;

or

3)

in the

case

of

a

container,

the

inner

liner

that

prevented

contact

of

the

commercial

chemical

product

or

manufacturing

chemical

intermediate

with

the

container,

has

been

re’noved,

d)

Any

residue

or

contaminated

soil,

water

or

other

debris

resulting

from

the

cleanup

of

a

spill,

into

or

on

any

land or water

of

arty

commercial

chemical

product

or

manufacturing

chemical

intermedi.

ate

having

the

generic

name

listed in paragraph

(e)

or

(f),

or

any

residue

or

contaminated

soil,

water

or

othe:~ debris

re&ilting

from

the

cleanup

of

a

spill,

into

or

on

any

land

or

water,

of

any

off—specification

chemical

product

or

manufacturing

chemical

intermediate

which,

if

it

met

specifications,

would

have

the

generic

name

listed

in paragraph

(e) or

(f),

80-314

---

—9—

(Comment:

The phrase ~commercial chemical product or

manufacturing

chemical

intermediate

having the generic name listed

in

,..“

refers to a chemical

substance which is

manufactured

or formulated

for commercial or manufacturing use which consists

of the

com-

mercially pure grade of the chemical,

any

technical

grades

of

the

chemical

that

are

produced or marketed,

and

all formulations in

which the

chemical

is the sole active

ingredient.

It

does

not

refer to a

material,

such

as

a

manufacturing

process

waste,

that

contains

any

of

the

substances listed

in

paragraphs

(e)

or

(f).

Where

a

manufacturing

process waste

is deemed to be a hazardous

waste

because

it

contains

a substance

listed in

paragraphs

(e)

or

(f),

such

waste

will

be

listed

in either §~721.131or 721,132

or

will

be

identified

as a hazardous waste by the characteristics

set

forth

in

Subpart

C

of

this part.)

e)

The

commercial chemical products, manufacturing chemical.

intermediates or off—specification commercial chemical

products or manufacturing chemical intermediates referred

to in paragraphs

(a)

through

(d)

of

this

section,

are

identified

as

acute

hazardous

waste

(H)

and

are

subject

to the small quantity exclusion defined in §721,105(e),

(Comment:

For the convenience of the regulated community the

primary hazardous properties of these materials have been indi-

cated by the

letters

T

(Toxicity),

and

R

(Reactivity).

Absence

of

a letter indicates that the

compound

only

is listed for

acute

toxicity.

These wastes

and

their corresponding EPA Hazardous

Waste

Numbers

are:)

Hazard on s

waste No.

Substance

P023

Acetaldehyde,

chloro—

P002

Acetamide,

N-(

aminothioxomethyl

)-

P057

Acetamide,

2—fluoro—

P058

Acetic

acid,

fluoro—,

sodium

salt

P066

Acetimedic

acid,

N- (methylcarbamoyl

)oxyl thio-,

methyl

ester

POOl

3-(alpha—acetonylbenzyl)-4-hydroxycoumarin

and

salts

P002

1—Acetyl—2—thiourea

P003

Acrolein

P070

Aldicarb

P004

Aldrin

P005

Ally?

alcohol

P006

Aluminum

phosphide

P007

5~(Aminomethyl)—3—isoxazolol

P008

4-Aminopyridine

P009

Aramonium

picrate

(R)

P119

Ammonium

vanadate

---

—10—

Hazard

waste

ou s

No,

Substance

P010

Arsenic

acid

P012

Arsenic

(III)

oxide

POll

Arsenic

(V) oxide

POll

Arsenic

pentoxide

P012

Arsenic

trioxide

P038

Arsine,

diethyl—

P054

Aziridine

P013

Barium

cyanide

P024

Benzenamine,

4—chioro—

P077

Benzenamine,

4—nitro—

P028

Benzene,

(chloromethyl)—

P042

i,2-Benzenediol,

4-l—hydroxy-2-(methylamino)ethylj—

P014

Benzenethiol

P028

Benzyl chloride

P015

Beryllium

dust

P016

Bis(chloromethyl)

ether

P017

Bromoacetone

P018

Brucine

P021

Calcium

cyanide

P123

Camphene,

octachloro—

P103

Carbamidoselenoic

acid

P022

Carbon

bisulfide

P022

Carbon

disulfide

P095

Carbonyl chloride

P033

Chlorine cyanide

P023

Chioroacetaldehyde

P024

p-Chloroaniline

P026

1-(e-Chlorophenyl

)thiourea

P027

3-Chloropropionitrile

P029

Copper cyanides

P030

Cyanides

(soluble

cyanide

salts), not elsewhere

specified

P031

Cyanogen

P033

Cyanogen

chloride

P036

Dichlorophenylarsine

P037

Dieldrin

P038

Diethylarsine

P039

0,0-Diethyl

s-

2-(ethy.thio)ethyl

phosphorodithioate

P041

Diethyl-p-nitrophenyl

phosphate

P040

0,0-Diethyl

0-pyrazinyl

phosphorothioate

P043

Diisopropyl

fluorophosphate

P044

Dimethoate

P045

3,3-Dimethyl-l-(methylthio)-2-butanone,

O-(methylamino)

carbonyl

oxime

P071

0,0-Dimethyl O-p-nitrophenyl

phosphorothioate

P082

Dimethyinitrosamine

P046

alpha,

alpha-Dimethylphenethylamine

P047

4,6—Dinitro—o—cresol

and

salts

P034

4, 6-Dinitro-o—cyclohexylphenol

60-316

---

—11—

Hazardous

waste No.

Substance

P048

2,4—Dinitrophenol

P020

Dinoseb

P085

Diphosphoramide,

octamethyl-

P039

Disulfoton

P049

2, 4-Dithiobiuret

P109

Dithiopyrophosphoric

acid, tetraethyl ester

P050

Endosuif an

P088

Endothall

P051

Endrin

P042

Epinephrine

P046

Ethanamine,

1,

1-dimethyl—2-phenyl—

P084

Ethenamine,

N-methyl--N-nitroso-

P101

Ethyl cyanide

P054

Ethylenimine

P097

Famphur

P056

Fluorine

P057

Fluoroacetamide

P058

Fluoroacetic

acid,

sodium

salt

P065

Fulminic

acid,

mercury

(II)

salt

(R,T)

P059

Heptachlor

P051

l,2,3,4,10,10—Hexachloro-6,7—epoxy--1,4,4a,5,6,7,8,

8a-octahydro-endo,endo-1, 4:5,

8-dimethanonaphthalene

P037

1,2,3,4,10,

10—Hexachloro—6,

7—epoxy—1,4, 4a,5,6,

7,8,

8a-octahydro-endo,exo—1,4:5,8—dimethanonaphthalene

P060

1,2,3,4,10,10—Hexachloro—1,4,4a,5,8,8a—hexahydro—

1, 4:5,

8-endo,

endo—dimethanonaphthalene

P004

1,2,3,4,10,10,—Hexachloro—1,4,4a,5,8,8a—hexahydro—

1,4:5,

8-endo,exo—dimethanonaphthalene

P060

Hexachlorohexahydro—exo, exo-dimethanonaphthalene

P062

Hexaethyl

tetraphosphate

P116

Hydrazinecarbothioaniide

P068

Hydrazine,

methyl-

P063

Hydrocyanic

acid

P063

Hydrogen

cyanide

P096

Hydrogen

phosphide

P064

Isocyanic

acid,

methyl

ester

P007

3(2H)-Isoxazolone,

5—(aminomethyl)-

P092

Mercury,

phenyl—,

acetate

P065

Mercury

fulminate

(R,T)

P016

Methane,

oxybis(chloro—

P112

Methane,

tetranitro—

(R)

P118

Methanethiol,

trichloro—

P059

4,7—Methano—1H—indene,

1,4,5,6,7,8,8—heptachioro—

3a, 4, 7,

7a-tetrahydro—

P066

Methomyl

P067

2—Methylaziridine

P068

Methyl

hydrazine

P064

Methyl

isocyanate

---

—12—

Hazard

waste

ou

S

No.

Substance

P069

2-Methyllactonitrile

P071

Methyl parathion

P072

alpha-Naphthylthiourea

P073

Nickel

carbonyl

P074

Nickel

cyanide

P074

Nickel(II)

cyanide

P073

Nickel

tetracarbonyl

P075

Nicotine

and

salts

9076

Nitric

oxide

p077

p—Nitroaniline

P078

Nitrogen

dioxide

P076

Nitrogen(II)

oxide

P078

Nitrogen(IV)

oxide

P081

Nitroglycerine

(R)

9082

N-Nitrosodimethylamine

P084

N-Nitrosomethylvinylamine

P050

5-Norbornene-2, 3-dimethanol,

1,4,5,6,7,7-hexachioro,

cyclic

sulfite

9085

Octamethylpyrophosphoramide

9087

Osmium

oxide

9087

Osmium

tetroxide

9088

7~~Oxabicyclo(2.2.1heptane—2,3—diCarbOxyliC

acid

P089

Parathion

9034

Phenol,

2-cyclohexyl—4,

6—dinitro—

9048

Phenol,

2,4—dinitro—

9047

Phenol,

2, 4,

—dinitro—6—methyl—

P020

Phenol,

2, 4-dinitro—6—(1—methylpropyl

)-

P009

Phenol, 2,4,6—trinitro—,

ammonium

salt

(R)

P036

Phenyl

dichloroarsine

P092

Phenylmercuric

acetate

P093

N-Phenylthiourea

P094

Phorate

9095

Phosgene

9096

Phosphine

9041

Phosphoric

acid,

diethyl

p—nitrophenyl

ester

P044

Phosphorodithioic

acid,

0,0—dimethyl

S—(2—(methylamino)-

2—oxoethyl Jester

9043

Phosphorofluoric

acid,

bis(1—methylethyl)ester

9094

Phosphorothioic

acid,

0,0—diethyl

S—(ethylthio)methyl

ester

9089

Phosphorothioic

acid,

0,0—diethyl O—(p—nitrophenyl)

ester

P040

Phosphorothioic

acid,

0,0—diethyl

0—pyraziny.

ester

P097

Phosphorothioic

acid,

0,0—dimethyl

0— p—((dimethylamino)—

sulfonyl)phenylester

P110

Plumbane,

tetraethyl—

9098

Potassium

cyanide

9099

Potassium silver cyanide

60-318

---

—13--

Hazard

waste_No,

on s

Substance

9070

Propanal,

2-’methyl-2-(methylthio)-,

0-(methylamino)

carbonyl

oxime

P101

Propanenitrile

9027

Propanentrile,

3-chloro-

9069

Propanenitrile,

2-hydroxy—2-methyl-

P081

1,2,3—Propanetriol,

trinitrate—

(R)

P017

2-Propanone,

1—bromo-

P102

Propargyl

alcohol

P003

2—Propenal

P005

2—Propen—1—ol

9067

1,

2—Propylenimine

P102

2—Propyn—1—ol

9008

4—Pyridinamine

P075

Pyridine,

(S)—3--(l—methy—2—pyrrolidinyl)—,

and salts

P111

Pyrophosphoric

acid,

tetraethyl ester

P103

Selenourea

P104

Silver

cyanide

P105

Sodium

azide

P106

Sodium

cyanide

9107

Strontium sulfide

9108

Strychnidin-lO-one,

and

salts

P018

Strychnidin-lO—one,

2,

3—dimethoxy—

P108

Strychnine

and salts

P115

Sulfuric

acid, thallium(I)

salt

9109

Tetraethyldithiopyrophosphate

P110

Tetraethyl

lead

Pill

Tetraethylpyrophosphate

P112

Tetranitromethane

(R)

P062

Tetraphosphoric

acid,

hexaethyl ester

9113

Thallic

oxide

P113

Thallium(III)

oxide

P114

Thallium(I)

selenite

P115

Thallium(I)

sulfate

P045

Thiofanox

P049

Thioimidodicarbonic

diamide

9014

Thiophenol

P116

Thiosemicarbazide

P026

Thiourea,

(2—chlorophenyl)—

9072

Thiourea,

1—naphthalenyl—

P093

Thiourea,

phenyl-

P123

Toxaphene

P118

Trichloromethanethiol

9119

Vanadic

acid,

ammonium

salt

P120

Vanadium

pentoxide

9120

Vanadium(V)

oxide

POOl

Warfarin

P121

Zinc

cyanide

9122

Zinc phosphide

(R,

T)

---

—14—

f)

The commercial chemical

products,

manufacturing

chemical

intermediates

or

off—specification

comn~rcial

chemical

products

referred

to

in

paragraphs

(a)

through

(d),

are

identified

as

toxic

wastes

(T)

unless

otherwise

designated

and

are

subject to

the

small

quantity

exclusion

defined

in

Section

721,105(a)

and

(f).

(Comment:

For

the

convenience

of

the

regulated

community,

the

primary

hazardous

properties

of

these

materials have been indicated

by

the

letters

T (Toxicity), R

(Reactivity),

I

(Ignitability)

and

C

(Corrosivity).

Absence

of

a

letter

indicates that the compound

is

only

listed

for

toxIcity.

These wastes and their corresponding

EPA

Hazardous

Waste

Numbers

are:)

Hazard one

waste

No.

0001

Acetaldehyde

(I)

0034

Acetaldehyde,

trichloro—

0187

Acetamide,

N- (4—ethoxyphenyl)—

0005

Acetamide,

N-’9H-fluoren—2—yl—

0112

Acetic

acid,

ethyl

ester

(I)

0144

Acetic

acid, lead

salt

0214

Acetic acid,

thallium(I)

salt

U002

Acetone

(I)

0003

Acetonitrile

(I,?)

0004

Acetophenone

0005

2-Anetylaminofluorene

0006

Acetyl chloride

(C,R,T)

0007

Acrylarnide

U008

Acrylic acid

(I)

0009

Acrylontrile

0150

Alanine,

3-p-bis(2-chloroethyl)amiflo

phenyl—,

L—

0011

Amitrole

0012

Aniline

(I,T)

0014

Auramine

0015

Azaserine

0010

Azirino(2’,3~

:3,4)pyrrolo(1,2—a)indole—4,7—diOfle,

6-amino-8-(((aminocarbonyl)oxy)methyll-1, la,

2,8,

8a,

8b-hexahydro-8a-methoxy-5-methyl-,

Benz j

aceanthrylene,

1, 2—dihydro—3—methyl—

Benz (c

)

acridine

3, 4-Bertzacridine

Benzal chloride

Benz a

anthracene

I, 2—Berizanthracene

1, 2-Benzanthracene,

7, 12—dimethyl—

Benzenamine

(I,T)

Benzenamine,

4,4~—carbonimidoylbis(N,N—dimethyl—

60-320

---

Hazard

waste

ou s

No.

Substance

Bensenamine,

4—chloro—2—methyl—

Benzenamine, N,N~-dimethyl-4-phenylazo—

Benzenamine,

4, 4~—methylenebis(2—chloro—

Benzenaniine,

2-methyl-,

hydrochloride

Beuzenamine,

2—methyl--5—nitro

Benzene

(I,T)

Benseneacetic acid,

4-chloro--alpha-

(

4-chlorophenyl

)—

alpha-hydroxy,

ethyl ester

Benzene,

1-bromo—4—phenoxy—

Benzene,

chloro—

1, 2-Benzenedicarboxylic

1,2-Ben zenedic

arboxylic

I, 2-Benzenedicarboxylic

1,

2-Benzenedicarboxylic

1,

2-Benzenedicarboxylic

1, 2—Benzenedicarboxylic

Benzene,

1, 2—dichloro—

F3enzene,

1, 3—dichloro-

Benzene,

1, 4—dichloro—

Benzene,

(dichloromethyl)-

Benzene,

1, 3-diisocyanatomethyl-(R,T)

Benzene, dimethyl-(I,T)

1, 3Benzenediol

Benzene, hexachioro—

Benzene,

hexahydro—

( I)

Benzene, hydroxy—

Benzene, methyl—

Benzene,

l-methyl—2,

4-dinitro-

Benzene,

l-methyl—2,

6-dinitro-

Benzene,

1,

2-methylenedioxy-4-allyl-

Benzene,

1,

2-methylenedioxy-4-propenyl—

Benzene,

I,

2—methylenedioxy-4-propyl-

Benzene,

(1-methylethyl)-

(I)

Benzene, nitro—

(I,T)

Benzene,

pentachioro—

Benzene,

pentachloronitro—

Benzenesulfonic

acid

chloride

(C,R)

Benzenesulfonyl

chloride

(C,R)

Benzene,

1,2,4,

5-tetrachloro—

Benzene,

(trichloromethyl)-(C,R,T)

Benzene, 1,3,5—trinitro—

(R,T)

Benzidine

1, 2—Benzisothiazolin—3—one,

1,1—dioxide

Benzo (3

,k fluorene

Benzo a

pyrene

3,4—Ben zopyrene

p-Benzoquinone

Benzotrichloride

(C, R,T)

acid anhydride

acid,

bis(2—ethylhexyl)

ester

acid, dihutyl ester

acid, diethyl ester

acid, dimethyl

ester

acid,

di-ri-octyl

ester

0049

0093

13158

0222

T11

01

U

U J~

0019

13038

0030

0037

13190

0028

0069

0088

TI

I

Uj~

0107

13070

0071

0072

0017

0223

0239

13201

13127

13056

0188

0220

13105

13106

0203

13141

0090

13055

13169

0183

13185

13020

13020

0207

0023

0234

13021

13202

0120

0022

0022

13197

0023

---

—16—

Hazard one

waste

No,

Substance

13050

1,

2~Berizphenanthrene

0085

2,2~Bioxirane

(I,T)

0021

(1,i’—Biphenyl)—4,4~—diamine

0073

(1,l~—Biphenyl)—4,4~-’diamine,

3,3~—dichloro—

13091

(1,1 —Biphenyl)—4, 4 —diamine,

3, 3~—dimethoxy—

13095

(1, 1~—Biphenyl)—4,U—diamine,

3,

3~—dimethyl—

13024

Bis(2-chloroethoxy)

methane

13027

Bis(2~chloroisopropyl)

ether

13244

Bis(dimethylthiocarbamoyl)

disulfide

0028

Bis(2-ethylhexyl)

phthalate

0246

Bromine

cyanide

13225

Bromoform

0030

4—Bromophenyl

phenyl

ether

13128

1,3—Butadiene,

1,1,2,3,4,4—hexachioro—

0172

1-Butanamine,

N-butyl-N-nitroso—

0035

Butanoic

acid,

4—Bis(2—chloroethyl)amino

benzene—

0031

1—Butanol

(I)

0159

2—Butanone

(I,T)

:3160

2-Butanone

peroxide

(R,T)

13053

2—Butenal

13074

2—Butene,

1,4-’dichloro—

(I,T)

13031

n—Butyl

alcohol

(I)

0136

Cacodylic

acid

:3032

Calcium chromate

0238

Carbamic

acid,

ethyl.

ester

0178

Carbamic

acid,

methylnitroso—,

ethyl

ester

0176

Carbamide,

N-ethyl—N-nitroso—

0177

Carbamide,

N—methyl—N-nitroso—

13219

Carbamide,

thio—

13097

Carbamoyl

chloride, dimethyl

0215

Carbonic acid,

dithallium

(I)

salt

(3156

Carbonochloridic

acid, methyl ester

(I,T)

13033

Carbon

oxyfluoride

(R,T)

13211

Carbon

tetrachloride

13033

Carbonyl

fluoride

(R,T)

13034

Chloral

0035

Chlorambucil

13036

Chlordane,

technical

13026

Chlornaphazine

13037

Chlorobenzene

0039

4-Chloro—m—cresol

0041

1-Chloro-2,

3-epoxypropane

0042

2-Chloroethyl vinyl ether

13044

Chloroform

13046

Chloromethy.

methyl

ether

13047

beta-Chloronapthalene

U048

o-Chlorophenol

0049

4-Chloro-o-toluidine,

hydrochloride

---

—17—

Hazard

waste

one

No,

Substance

13032

Chromic

acid,

calcium salt

13050

Chrysene

13051

Creosote

0052

Cresois

13052

Cresylic

acid

0053

Crotonaldehyde

13055

Curnene

(I)

13246

Cyanogen

bromide

13197

1, 4-Cyclohexadienedione

1)056

Cyclohexane

(I)

13057

Cyclohexanone

(I)

0130

1,3—Cyclopentadiene,

1,2,3,4,5,5-hexachioro—

13058

Cyclophosphamide

13240

2,4—13,

salts

and

esters

0059

Daunomycin

0060

DOD

13061

DOT

0142

Decachlorooctahydro-1,

3,4-metheno-2H--

cyclohutac,d

-pentalen-2—one

13062

Dialiate

0133

Diarnine

(R,T)

0221

Diaminotoluene

13063

Dibenz (a,hl

anthracene

13063

l,2:5,6—Dibenzanthracene

(3064

1,2 :7, 8—Dibenzopyrene

13064

Dibenz(a,ipyrene

0066

1, 2—Dibromo—3—chloropropane

0069

Dibutyl

phthalate

0062

S—(2,3-Dichloroallyl)

diisopropylthiocarbamate

13070

o-Dichlorobenzene

0071

m-Dichlorobenzene

0072

p-DichlorobeflZene

0073

3, 3~—Dichlorobenzidine

1)074

i,4—Dichloro—2—butene

(I,T)

13075

Dichlorodifluoromethane

0192

3,5-Diehloro-N-(1,1-dimethyl-2-propyflyl)

bertzamide

0060

Dichioro

diphenyl

dichloroethane

0061

Dichloro

diphenyl

trichloroethane

13078

1, l-’Dichloroethylene

(3079

1, 2-Dichloroethylene

0025

Dichloroethyl

ether

0081

2, 4—Dichlorophenol

0082

2, 6-Dichlorophenol

0240

2,4-Dichlorophenoxyacetic

acid,

salts and esters

0083

1,

2—Dichloropropane

13084

1,3-Diehloropropene

13085

1,2:3,4—Diepoxybutane

(I,T)

13108

1,4-Diethylene

dioxide

60-323

---

-‘18—

Hazard

waste

on s

No,

Substance

13086

N,N-Diethylhydrazine

1)087

0

,O~Diethyl-S-methyl-dithiophosphate

13088

Diethyl

phthalate

13089

Diethylstilbestrol

13148

1, 2-Dihydro-3,

6—pyradizinedione

1)090

Dihydrosafrole

1)091

3, 3’—Dimethoxybenzidine

1)092

Dimethylamine

(I)

1)093

Dimethyl aminoazobenzene

1)094

7, 12-dimethylbenz

a

anthracene

3095

3,

3~—Dimethylbenzidine

UO96

alpha,

alpha-Dimethylbenzylhydroperoxide

(R)

1)097

t)imethylcarbamoyl

chloride

1)093

l,l—Dimethylhydrazine

3099

1, 2-Dimethylhydrazine

1)101

2, 4-’Dimethylphenol

1)102

Dimethyl phthalate

3103

Dimethyl

sulfate

0105

2, 4-Dinitrotoluene

13106

2, 6-Dinitrotoluene

13107

Di-n-octyl phthalate

13108

1,4-Dioxane

3109

1, 2—Diphenylhydrazine

(3110

Dipropylamine

(I)

13111

Di-N-propylnitrosoamine

3001

Ethanal

(I)

13174

Ethanamine,

N—ethyl—N—nitroso—

0067

Ethane,

1,2-dibromo—

U076

Ethane,

1,1-dichioro—

1)077

Ethane,

1,2—dichloro—

0114

1, 2-Ethanediylbiscarbamodithioic

acid

0131

Ethane,

l,1,1,2,2,2—hexachloro—

13024

Ethane,

1,1’- (methylenebis(oxy)bis(2—chloro—

3247

Ethane,

1,l,1—trichloro—2,2—bis(p—methoxyphenyl)—

(3003

Ethanenitrile

(I,T)

(3117

Ethane,

l,1’—oxybis—

(I)

3025

Ethane,

1,

1’—oxybis(2—chloro—

0184

Ethane,

pentachloro—

13208

Ethane,

1,1,1,

2—tetrachloro—

1)209

Ethane,

l,1,2,2—tetrachloro—

13218

Ethanethioamide

13227

Ethane, l,1,2—trichloro—

0043

Ethene,

chloro—

0042

Ethene, 2-chloroethoxy—

1)078

Ethene,

1,l—dichloro—

0079

Ethene,

trans—1,2—dichloro—

0210

Ethene,

l,1,2,2—tetrachloro—

0173

Ethanol,

60-324

---

—19

—

Hazard

waste

ous

No,

Substance

13004

Ethanone,

1—phenyl—

0006

Ethanoyl chloride

(C,R,T)

(3112

Ethyl

acetate

(I)

0113

Ethyl

acrylate

(I)

(3238

Ethyl carbamate

(urethan)

13038

Ethyl

4,4~—dichlorobenzilate

0114

Ethylenebis(dithiocarbamic acid)

3067

Ethylene

dibromide

0077

Ethylene

dichloride

13115

Ethylene

oxide

(I,T)

13116

Ethylene

thiourea

0117

Ethyl

ether

(I)

0076

Ethylidene

dichloride

0118

Ethylmethacrylate

0119

Ethyl

methanesulfonate

1139

Ferric dextran

3120

Fluoranthene

0122

Formaldehyde

13123

Formic acid

(C,T)

1)124

Furan

(I)

(3125

2-Furancarboxaldehyde

(I)

13147

2,5-Furandione

13213

Furan,

tetrahydro—

(I)

(3125

Furfural

(I)

0124

Furfuran

(I)

3206

D-Glucopyranose,

2—deoxy—2- (3-methyl—3—ni—

trosoureido

1—

13126

Glycidylaldehyde

0163

Guanidine,

N—nitroso—N-methyl—N’—nitro

3127

Hexachlorobenzene

1)128

Hexachiorobutadiene

0129

Hexachlorocyclohexane

(gamma

isomer)

1)130

Hexachlorocyclopentadiene

U131

Hexachioroethane

13132

Hexachlorophene

13243

Hexachloropropene

0133

Hydrazine

(R,T)

(3086

Hydrazine,

1,2—diethyl—

1)098

Hydrazine,

l,1-dimethyl-

0099

Hydrazine,

1,2—dimethyl—

0109

Hydrazine,

1,2—diphenyl—

3134

Hydrofluoric

acid

(C,T)

(3134

Hydrogen

fluoride

(C,T)

(3135

Hydrogen

sulfide

0096

Hydroperoxide,

1-methyl—1—phenylethyl—

(R)

Ul36

Hydroxydimethylarsine

oxide

13116

2—Imidazolidinethione

13137

Indeno1,2,3—cdpyrene

---

-20—

Hazard

waste

on

s

No.

Substance

3139

Iron

dextran

(3140

isobutyl

alcohol

(I,T)

13141

Isosafrole

(3142

Kepone

1)143

Lasiocarpene

(3144

Lead

acetate

13145

Lead

phosphate

(3146

Lead

subacetate

0129

Lindane

0147

Maleic

anhydride

13148

Maleic

hydrazide

1)149

Malononitrile

1)150

Melphalan

0151

Mercury

1)152

Methacrylonitrile

(I,T)

3092

Methanamine,

N—methyl—

(I)

(3029

Methane,

bromo-

0045

Methane, chioro—

(I,T)

13046

Methane,

chloromethoxy—

0068

Methane, dibromo-

0080

Methane,

dichloro—

1)075

Methane,

dichlorodifluoro—

0138

Methane, iodo-

3119

Methanesulfonic

acid,

ethyl

ester

0211

Methane,

tetrachloro—

(3121

Methane, trichlorofluoro—

0153

Methanethiol

(I,T)

(3225

Methane,

tribromo—

13044

Methane,

trichloro—

0121

Methane,

trichlorofluoro—

0123

Methanoic acid

(C,T)

(3036

4,7—Methanoindan,

1,2,4,5,6, 7, 8, 8—octa—

chloro—3a,

4,7,

7a—tetrahydro—

3154

Methanol

(I)

13155

t4ethapyrilene

13154

Methyl

alcohol

(I)

0029

Methyl bromide

13186

1-Methylbutadiene

(I)

0045

Methyl

chloride

(I,T)

13156

Methyl

chlorocarbonate

(I,T)

0226

Methylchloroform

0157

3-’Methylcholanthrene

0158

4,4

‘-‘Methylenebis(2—chloroaniline)

0132

2,2~-Methylenebis(3,

4,6—trichioropheno)

(3068

Methylene

bromide

3080

Methylene

chloride

U122

Methylene oxide

(3159

Methyl ethyl

ketone

(I,T)

60-326

---

—21—

Hazardous

waste No,

___

Substance

0160

Methyl

ethyl

ketone

peroxide

(R,T)

1138

Methyl

iodide

0161

Methyl isobutyl

ketone

(I)

13162

Methyl

methacrylate

(I,T)

13163

N—Methyl-N

-nitro-N-nitrosoguanidine

(3161

4—Methyl-2—pentanone

(I)

13164

Methylthiouracil

0247

Methoxychlor

3010

Mitomycin

C

0059

5,12—Naphthacenedione,

(8S—cis)—8—acetyl—

10- ((3-amino-2,

3, 6—trideoxy-alpha—L—lyxo—

hexapyranosyl

) oxyl) -7,8,9,10—tetrahydro—

6,8,11-trihydroxy-1-methoxy—

13165

Naphthalene

(3047

Naphthalene,

2—chloro—

13166

1,

4-Naphthalenedione

0236

2,7—Naphthalenedisulfonic

acid,

3,3’—((3,3’—

dimethyl—(l,

19—biphenyl)—4,4’—diyl)—bis

(azo)bis(5-amino-4-hydroxy)—,

tetrasodium

salt

0166

1,

4—Naphthaquinone

(3167

i-’Naphthylamine

0168

2-Naphthylamine

3167

alpha-’Naphthylamine

13168

beta-Naphthylamine

13026

2—Naphth~lamine,

N,N’—bis(2—chlorornethyl)—

0169

Nitrobenzene

(I,T)

0170

p—Nitrophenol

(3171

2—Nitropropane

(I)

13172

N-Nitrosodi-n-butylamine

13173

N-Nitrosodjethanolamjne

0174

N-Nitrosodiethylamine

(Jill

N-Nitroso-N—propylamine

(3176

N-Nitroso-N-ethylurea

0177

N-Nitroso-N—methylurea

0178

N-’Nitroso-N-methylurethane

13179

N-Nitrosopiperidine

0180

N-Nitrosopyrrolidine

13181

5-Nitro-”o-toluidine

(3193

1,2—Oxathiolane,

2,2—dioxide

(3058

2H—1,

3,

2-Oxazaphosphorine,

2— (bis(2—

chloroethyl) amino

tetrahydro—, oxide 2—

(1115

Oxirane

(I,T)

0041

Oxarane,

2-”(chloromethyl)—

13182

Paraldehyde

0183

Pentachlorobenzene

13184

Pentachloroethane

0185

Pentachloronitrobenzene

---

—22—

Hazardous

waste

No,

Substance

0186

1,3—pentadiene

(I)

0187

Phenacetin

3188

Phenol

(3048

Phenol,

2-’chloro—

0039

Phenol,

4-chloro—3—methyl-

1081

Phenol,

2,4-’dichloro—

0082

Phenol,

2,6—dichloro—

0101

Phenol, 2,4—dimethyl—

0170

Phenol,

4-nitro-

~49------P~ene3cy-pe~aeh~efe-

0137

1,10-(1,2—phenylene)pyrene

13145

Phosphoric

acid,

lead

salt

0087

Phosphorodithioic

acid, 0,0—diethyl—,

S—

methyl

ester

0189

Phosphorous

sulfide

(R)

0190

Phthalic

anhydride

0191

2—Picoline

13192

Pronamide

0194

1—Propanamine

(I,T)

13110

1-Propanamine,

N—propyl-

(I)

3066

Propane,

1,

2-dibromo—3—chloro—

0149

Propanedinitrile

(3171

Propane,

2-nitro—

(I)

13027

Propane,

2,2~—oxybis2—chloro—

1193

1,3-Propane sultone

0235

1—Propanol,

2,3—dibromo—,

phosphate

(3:1)

0126

1—Propanol,

2,3—epoxy—

13140

1—Propanol,

2—methyl.—

(I,T)

0002

2-Propanone

(I)

(3007

2-Propenamide

0084

Propene,

l,3—dichloro—

3243

l—Propene,

1,1,2,3,3,3—hexachioro—

0009

2—Propenenitrile

13152

2-Propenenitrile,

2—methyl—

(I,T)

13008

2-Propenoic

acid

(I)

0113

2—Propenoic

acid,

ethyl

ester

(I)

13118

2-Propenoic

acid,

2-methyl—,

ethyl ester

13162

2-Propenoic

acid,

2—methyl—,

methyl

ester

(I,T)

0194

n-Propylamine

(I,T)

(3083

Propylene

dichloride

(3196

Pyridine

(3155

Pyridine,

2-(2—(dimethylamino)—2—~henylamino—

(3179

Pyridine,

hexahydro—N-nitroso—

0191

Pyridine, 2—methyl—

60-328

---

Hazardous

waste No.

____

13164

4 (1H)-Pyrimidinone,

2-thioxo-

0180

Pyrrole, tetrahydro—N—nitroso—

U200

Reserpine

0201

Resorcinol

(3202

Saccharin and salts

0203

Safrole

0204

Selenious

acid

3204

Selenium

dioxide

0205

Selenium disulfide (R,T

3015

L—Serine,

diazoacetate

(ester)

Sex

3089

4, 4’-Stilbenediol,

alpha, alpha’—diethyl—

(3206

Streptozotocin

0135

Sulfur hydride

0103

Sulfuric acid, dimethyl ester

(3189

Sulfur phosphide

U205

Sulfur selenide

(R,T)

(3207

1,2,4, 5—Tetrachlorobenzene

13208

1, 1, 1, 2—Tetrachloroethane

13209

1,1,2, 2-Tetrachioroethane

3210

Tetrachioroethylene

3213

Tetrahydrofuran

(I)

(3214

Thallium

(I)

acetate

(1215

Thallium

(I) carbonate

(3216

Thallium

(I)

chloride

3217

Thallium

(I) nitrate

(3218

0153

Thiomethanol

(I,T)

0219

Thiourea

13244

Thiram

3220

Toluene

(3221

Toluenediamine

3223

Toluene diisocyanate (R,T)

(3222

o—Toluidine hydrochloride

1)011

1H—1, 2, 4—Triazol—3—amine

(3226

1, 1, 1—Trichloroethane

0227

1,1,2—Trichloroethane

3228

Trichioroethene

0228

Trichloroethylene

13121

~4

~

0234

sym-Trinitrobenzene

(R,T)

3182

1,3,5-Trioxane,

60-329

---

—24—

Hazardous

waste No.

Substance

_____

(1235

Tris(2, 3-dibromopropyl)

(1236

Trypan blue

(1237

Uracil, S(bis(2—chloromethyl)amino~—

13237

r3racil

mustard

(1043

Vinyl

chloride

(3239

Xyletis

(I)

(3200

?ohimban—16—carboxylic

acid,

11,

17—di—

methoxy—18—

(3,

4, 5—trimethoxy—

benzoyi)oxy-,

methyl

ester

(Source;

Amended

at

7

Ill.

Reg.

2518,

effective

February

22,

1983.)

5.

Appendix C of Part

721,

which references Appendix III to

40

CFR 261,

will

be

printed

out

and

amended

by

the

addition

of

the

following:

Appendix C--Chemical Analysis Test Methods

TABLE 1~---AnalyticalCharacteristics of Organic Chemicals

C~pc*m~i

Sauple

harx3.ling

ciass/fr

~tion

~n—O

~aairenenttecIT~iq1es

(1/MS

C~venticnal

Q

T~tector

*

*

*

*

*

Chlorinated

dthenz~~ns

~tra~tthle/~4

8280

(Source:

Amended

at

7

Ill.

Reg.

13999, effective October

12,

1983,

amended at

—

Ill.

Reg.

_________,

effective

—~______

6.

Appendix G of Part 721, which references Appendix VII to

40 CFR 261,

will

be printed out

and amended

Appendix G-—Basis for Listing Hazardous Wastes

EPA

hazardous

Hazardous constituents for which listed

waste

No.

F020

tetr

achlorodibenzo-p—dioxins

F02 1

tetrachlorodibenzo—p—dioxins

F022

tetrachloro~ibenzo-p-dioxins

F023

tetrachlorodibenzo—p—dioxins

60-330

---

—25—

7,

Appendix

H

of

Part 721 is amended

as

follows:

Section 72l~Appendix

H

Hazardous

Constituents

acetonitrile

(ethanenitrile)

acetopher~one (ethanone,

l—phenyl-)

3-(alpha-aeetonylbenzyl)-4-hydroxycoumarin

and

salts

(warfarin)

2—acetyl aminofluorene

(acetamide,

N-(911-fluoren—2—yl)—)

acetyl

chloride

(ethanoyl

chloride)

l-acetyl—2—thiourea

(acetamide,

N-

(

aminothioxomethyl

)—)

acrolein

(2—propenal)

acrylamide

(2—propenaxnide)

acrylonitrile

(2—propenenitrile)

aflatoxins

aidrin

(1,2,3,4,10,

lO-hexachloro—l

,

4, 4a,5,8,8a—hexahydro—

endo, exo-1 ,4:5,

8-dimethanonaphthalene)

allyl

alcohol

(2—propen—l—ol)

aluminum phosphide

4-amiriobiphenyl

((1,1

~—biphenyl-4--amine)

6-amino-I,

la, 2,

8, 8a,

8b-hexahydro-8—

(hydroxymethyl)—8a—methoxy—

5-methylcarbamate

azirino2’

,

3~:3,4pyrrolo(l,2alindole—

4,7—dione,

(ester)

(mitomycin

C)

(azirino(2~,3~

:3,4pyrrolo(l,2a)indole—4,7—dione,

6—amino--8’(((aminocarbonyl)oxy)methyl—l,la,2,8,8a,8b—

hexahydro-’8a’-methoxy-5-methyl-)

5- (aminomethyl

)—3—isoxazolol

(3(2H)-isoxazolone,

5—(aminomethyl)—)

4-aminopyridine

(4-pyridinamine)

amitrole

(lH—l ,2,

4—triazol—3—amine)

aniline

(benzenamine)

antimony and

compounds,

N.O.S.

(not

otherwise

specified)

at amite

(sulfurous

acid, 2—chloroethyl—, 2—(4—(l,l—

dimethylethyl)phenoxy-l-methylethyl

ester)

arsenic

and

compounds, N.O.S.

arsenic acid (orthoarsenic

acid)

arsenic

pentoxide

(arsenic

(V) oxide)

arsenic trioxide

(arsenic

(III)

oxide)

auraxnine

(henzenamine,

4,

4’-carbonimidoylbistN,N—dimethyl—,

monohydrochloride)

azaserine

(L-serine, diazoacetate

(ester))

barium and compounds, N.O.S.

barium cyanide

benz c

acridine

(3, 4—benzacridine)

benzaanthracene

(I,

2-benzanthracene)

80-331

---

26

benzene

(cyelohexatriene)

benzenearsonic

acid

(arsonic acid,

phenyl—)

benzene, dichioromethyl—

(benzal

chloride)

benzenethiol

(thiophenol)

benzidine (ji,I~—biphenyl—4,4~-’diamine)

benzob

fluoranthene

(2,

3-benzofluoranthene)

benzo

jfluoranthene

(7,

8-benzofluoranthene)

benzo aipyrene

(3,

4-benzopyrene)

p—benzoquinone

(1, 4-cyclohexadienedione)

benzotrichloride

(benzene,

trichioromethyl—)

henzyl chloride

(benzene,

(chloromethyl)—)

beryllium

and

compounds,

N.O.S.

bis(2-chloroethoxy)methane

(ethane,

1,l~-methylenebis(oxy)bis(2—chloro—))

bis(2—chloroethyl)

ether

(ethane,

1,11—oxybis2—chloro—)

N, N-bis(2-chloroethyl

)-2-naphthylamine

(chlornaphazine)

bis(2-chloroisopropyl)

ether

(propane,

2,2~-oxybis2—chloro—)

his(chloromethyl) ether

,

oxybis

chioro)

—)

bis(2-ethylhexyl)

phthalate

(l,2-benzenedicarboxylic

acid,

bis(2—ethylhexyl) ester)

bromoacetone

(2-pr opanone,

1—br

omo—)

bromomethane

(methyl

bromide)

4-bromophenyl phenyl ether

(benzene,

1—bromo—4—phenoxy—)

brucine

(strychnidin-lO—one,

2, 3—dimethoxy—)

2-butanone

peroxide

(methyl ethyl

ketone,

peroxide)

hutyl

benzyl

phthalate

(1 ,2-benzenedicarboxylic

acid, butyl phenylmethyl ester)

2-sec-butyl-4,6-dinitrophenol

(DNBP)

(phenol,

2, 4-dinitro-6-

(l—methylpropyl

)—)

cadmium

and

compounds,

N.O.S.

calcium

chromate (chromic

acid,

calcium salt)

calcium cyanide

carbon

disulfide

(carbon bisulfide)

carbon

oxyf luor ide

(c

arbonyl

fluoride)

chloral

(acetaldehyde,

trichloro—)

chlorarnbucil

(butanoic

acid,

4-bis(2—chloroethyl)aminolbenzene—)

chlordane

(alpha

and gamma isomers)

(4, 7—methanoindan,

1,2,4,5,6,7,8,

8—octachloro—

3, 4,

7,

7a-tetrahydro—)

(alpha and gamma isomers)

chlorinated benzenes, N,O.S,

chlorinated ethane, N.O,S,

chlorinated fluorocarbons, N.O.S.

chlorinated naphthalene,

N.O.S.

chlorinated phenol,

N,O,S.

chioroacetaldehyde

(acetaldehyde,

chloro—)

60-332

---

—27—

chloroalkyl

ethers,

NOO.S.

p-chloroaniline (henzeneamine,

4—chloro—)

chlorobenzene

(benzene,chioro—)

chlorobenzilate

(benzeneacetic acid,

4-chloro-alpha-(4-chlorophenyl)—

aipha—hydroxy-,

ethyl

ester)

p—chloro—m~cresal

(phenol,

4-chloro-3-methyl-)

1-chIoro~2, 3—epoxypropane

(oxirane,

2—

(chioromethyl

)-)

2-chloroethyl

vinyl

ether

(ethene,

(2-chioroethoxy)—)

chloroform

(methane,

trichloro—)

chioromethane

(methyl

chloride)

chloromethyl methyl ether

(methane, chioromethoxy—)

2-chloronaphthalene

(naphthalene,

beta-chloro-)

2-chlorophenol

(phenol,

o-chloro-)

1- (o-ehiorophenyl

)

thiourea

(thiourea,

(2-chlorophenyl)-)

3-chloropropionitrile

(propanenitrile,

3—chioro—)

chromium

and

compounds,

N.O.S.

chrysene

(I

,

2—benzphenanthrene)

citrus red No,

2

(2-naphthol,

I-

(2,5—dimethoxyphenyl)azol—)

coal tars

copper cyanide

creosote

(creosote,

wood)

cresols

(cresylic acid)

(phenol, methyl—)

crotonaldehyde

(2-butenal)

cyanides

(soluble

salts

and

complexes), N.O.S.

cyanogeri

(ethanedinitrile)

cyanogen bromide

(bromine

cyanide)

cyanogen chloride

(chlorine

cyanide)

cycasin

(beta-D-glucopyranoside,

(methyl-ONN—azoxy)methyl—)

2-cyclohexyl-4, 6-dinitrophenol

(phenol,

2-cyclohexyl-4,

6-dinitro—)

cyclophosphamide

(2H-l,3,2-oxazaphosphorine,

bis(2—chloroethyl)amino)—

tetrahydro-,

2-oxide)

daunomyc

in

(5,12-naphthacenedione,

(8S—cis)—8—acetyl—l0—

((3-amino-2, 3,

6-trideoxy)--alpha-L-lyxo-hexopyranosyl)oxy-

7,8,9,

lO-tetrahydro—6,

8, ll—trihydroxy—l—methoxy—)

DDD (dichlorodiphenyldichloroethane)

(ethane,

l,l-dichloro—2,2—bis(p—chlorophenyl)—)

DDE (ethylene,

l,l-dichloro-2,2—bis(4—chlorophenyl)—)

DDT (dichlorodiphenyltrichloroethane)

(ethane,

1,1,l—trichloro—2,

2—bis(p—chlorophenyl)—)

diallate

(5- (2, 3-dichloroal

lyl

)diisopropylthiocarbainate)

dibenz(a,hacridine

(l,2,5,6—dibenzacridine)

60-333

---

dibenz a,

~

dc~id~ne(1,2,7,

8—dibenzacridine)

diben~a,h

.~ti-racene

(1,2,5,6—dibenzanthracene)

7H—dibe~o

o

r~j~arhazole

(3,4,5,6—dibenzcarbazole)

diben~oa ‘~l~yrene

(l,2,4,5—dibenzpyrene)

dthe~~1~hpyrer~e

(l,2,5,6—dibenzpyrene)

diben~o~aJ~y~ne

(L2,7,8—dibenzpyrene)

1

,

2—~ib~

~mv

ohl oropropane

(~ucup~r~,

I

2—dibromo—3—chloro—)

I

,

2 ~diF

~oro~thaue

(ethylene

dibromide)

~1ibrom-r~

ane

(methylene

bromide)

d

I—’

h~~

~htha1

ate

i~i b~r~anediearboxylic

acid, dibutyl ester)

o—dict~~o~nze~ie

(henzene,

l,2—dichloro—)

m~’1~nio~zoenz

.~.

(benzene,

1,3—dichloro—)

p-d~ch1oLooen7ene

~benzene,

1,

4—dichioro—)

dich1oron~n7ene, N~O.S, (benzene,

dichioro—, N,O.S.)

3,

3 ‘~dic~orobenzidine

(

bipheny1—4,4~—diamine,

3,3~—dich1oro—)

l,4—d~c

.0

~

~~butene

(2—butene,

1,4—dichioro—)

dich

oodiZluoromeLhane

(methane, dichiorodifluoro—)

1,1—dicri

i~

~e~hane

(ethylidine

dichioride)

i,2’-’dictioroetha~xe

(ethylene

dichloride)

tran~-1,1dichloroethene

(l,2-dichloroethylene)

dichlorcet ylere, N.O~S.

(ethene,

dichloro—,

N.O.S.)

1,1—dic:

Lurocthylene

(ethene,

l,l—dichloro—)

dichloromethar

e

(methylene

chloride)

2, 4-dichlorophenol

(phenol,

2,

4—dichloro—)

2, 6-d_chiorophenol

(phenol,

2,

6-dichloro—)

2,4-dicn~oroohenoxyacetic

acid

(2,4—D),

salts and esters

(acetic a~id,

2,4-dichlorophenoxy—,

salts

and

esters)

dichlc

p3~i

arsine

(phenyl

dichloroarsine)

dichioropropane, N O.S.

(propane,

dichioro—,

N.O.S,)

I, 2-d_chloropropane

(propylene

dichloride)

dichlcro~ropanol,N,O,S,

(propanol, dichloro—,

N,O.S.)

dichlo~op~ope~.e,

N,O.S.

(propene, dichioro—, N.O.S.)

1 ,3-dichloropropene

(l-propene,

1,

3—dichloro—)

die

ldr in

(l,2,3,4,lO,l0—hexachloro—6,7—epoxy—l,4,4a,5,6,7,8,8a—

octanydro-endo,

exo-l

,4:5,

8-dimethanonaphthalene)

1,2:3 ~4—diepoxybutane

(2,2~—bioxirane)

diethyiars~ne

(arsine,

diethyl—)

N,N~-diethylhydrazine (hydrazine,

1,2-diethyl—)

0,0-diethyl

S-methyl

ester

of

phosphorodithioic

acid

(phosphorodithioic

acid,

0,0—diethyl S—methyl ester)

0,0-diathyiphosphoric

acid,

O—p—nitrophenyl ester

(phosphoric

acid,

diethyl

p—nitrophenyl ester)

diethy’~. phthsl~te

(i,~len~~nedicarboxy1ic

acid,

diethyl

ester)

O ,O-dietly

0-2-pyrazinyl

phosphorothioate

(priosplrothioic

acid,

0,0—diethyl

0—pyrazinyl ester)

diethyl

stilbestrol

(4,4~ stilbenediol,

alpha,alpha—diethyl,

bis(dihydrogen

phosphate,

(E)—)

60-334

---

—29—

dihydrosafrole

(benzene,

I,

2-methylenedioxy-4-propyl—)

3, 4-dihydroxy-aipha-

(methylamino)methyl

benzyl alcohol

(l,2-benzenediol,

4-1-hydroxy—2-(methylamino)ethyl—)

diisopropyfluorophosphate

(DFP)

(phosphorofluoridic

acid,

bis(1—methylethyl) ester)

d imetho ate

(phosphorodithioic

acid,

0,0—dimethyl

5- 2~(methylamino)—2—oxoethy1

ester)

3,

3

-dimethoxybenzidine

(l,l~-biphenyI—4,4~—diainine,

3,3~—dimethoxy—)

p—dimeth1l m.inoazohen zene

(benzer~amine,

N,N—dimethyl—4—(phenylazo)—)

7, 12-d.imethylbenz

a

anthracene

(I

~2-benzanthracene,

7,l2-dimethyl-)

3,3 ‘-dimsthylbenzidine

(l,i~—biphenyl—4,4~—diarnine,

3,3’—dimethyl—)

dimethylcarbarnoyl

chloride

(carhamaoyl

chloride,

dimethyl-)

l,l~dimethylhydrazine

(hydrazine,

1,1—dimethyl—)

l,2—dimethylhydrazine

(hydrazine,

1,2—dimethyl—)

3, 3-dimethyl-1-

(methylthio)-2-butanone,

0- (methylamino)carbonyloxime

(thiofanox)

alpha, alpha-dimethylphenethylamine

(ethan amine,

I,

l-dimethyl-2-phenyl-)

2,4-dimethylphenol

(phenol,

2,4-dimethyl-)

dimethyl

phthalate

(1, 2—benzenedicarboxylic

acid,

dimethyl

ester)

dimethyl sulfate

(sulfuric acid, dimethyl ester)

dinitrobenzene, N~O,S, (benzene,

dinitro—,

N.O.S.)

4,6-dinitro—o—cresol

and

salts

(phenol,

2,4-dinitro-6—methyl—,

and salts)

2, 4-dinitrophenol

(phenol,

2,

4—dinitro—)

2,

4-dinitrotoluene

(benzene,

l-rnethyl-2, 4—dinitro—)

2,

6-dinitrotoluene

(benzene,

1—methyl—2, 6—dinitro—)

di-’n-octyl

phthalate

(1, 2-benzenedicarboxylic

acid,

diocty.

ester)

I,

4—dioxane

(1, 4—d.iethylene

oxide)

diphenylamine

(benzenamine,

N-phenyl—)

1, 2-diphenyihydrazine

(hydrazine,

1, 2—diphenyl—)

di-n-propylnitrosamine

(N-nitroso-di—n-propylamine)

disulfotori

(0,0-diethyl

5- 2—(ethylthio)ethyl)

phosphorodithioate

2 ,4-dithiohiuret

(thioimidodicarbonic

diamide)

endosulf

an

(5-norbornene,

2,

3—dimethanol,

1,4,5,6,7,

7—hexachloro—,

cyclic

sulfite)

endrin

and

metabolites

(l,2,3,4,I0,lO—hexachloro—6,7—epoxy—l,4,4a,5,6,7,8,8a—

octahydro-endo,

endo- 1,4

:5, 8—dimethanonaphthalene,

and metabolites)

60-335

---

—30—

ethyl

carbamate

(urethan)

(carbamic

acid,

ethyl

ester)

ethyl cyanide (propanenitrile)

ethylenebisdithiocarbamic

acid,

salts

and

esters

(l,2—ethanediylbiscarbamodithioic

acid,

salts and esters)

ethyleneirnine

(aziridthe)

ethylene

oxide

(oxirane)

ethylenethiourea

(2—imidazolidinethione)

ethyl methacrylate

(2—propenoic

acid,

2—methyl—, ethyl ester)

ethyl methanesulfonate

(methanesulfonic acid, ethyl ester)

fluoranthene

(benzo

(j

ki

fluorene)

fluotine

2-f luorcacetamide

(acetamide,

2-f luoro—)

ifluoroacetic

acid,

sodium salt

(acetic

acid,

ifluoro—,

sodium

salt)

formaldehyde

(methylene

oxide)

formic

acid

(methanoic

acid)

glycidylaldehyde

(1—propanal,

2,3—epoxy—)

halomethane, N,O S

heptachior

(4,

7—methano—lH—indene,

1,4,5,6,7,8,

8—heptachioro—

3a, 4,

7, 7a-tetrahydro-)

heptachlor epoxide

(alpha,

beta

and

gamma

isomers)

(4, 7-methano-lH-indene,

1,4,5,6,

7, 8,

8—heptachloro—

2, 3-epoxy-3a,

4,7,

7—tetrahydro-,

alpha, beta

and

gamma

isomers)

hexachlorobenzene

(benzene,

hexachloro—)

hexachlorobutadiene

(1,

3~-butadiene,

hexachloro—)

hexachiorocyclohexane

(all

isomers)

(lindane

and

isomers)

hexachiorocyc

Iopentadiene

(cyclopentadiene,

hexachloro—)

hexachloroethane

(ethane,

hexachloro—)

I,2,3,4,lO,lO—hexachloro—1,4,4a,5,8,8a—hexahydro—l,4:5,8—

endo, endo—dimethanonaphthalene

(hexachlorohexahydro-endo,

endo—dimethanonaphthalene)

hexachlorophene

(2,2~-methylenebis(3,4,6-trichlorophenol))

hexachloropropene

(propene,

hexachloro—)

hex

ae thy 1

tetr

aphosphate

(tetraphosphoric acid,

hexaethyl ester)

hydrazine

(diamine)

hydrocyanic

acid (hydrogen

cyanide)

hydrofluoric

acid

(hydrogen

fluoride)

hydrogen sulfide

hydroxydimethylarsine

oxide

(cacodylic

acid)

indeno(l, 2, 3-cd)pyrene

(I, l0-(l

,

2-phenylene)pyrene)

iodomethane

(methyl

iodide)

iron

dextran

(ferric

dextran)

isocvanic

acid,

methyl

ester

(methyl isocyanate)

isobutyl

alcohol

(1—propanol,

2—methyl—)

---

—

s

isosafrole

(benzene,

1

,2—methylenedioxy—4—allyl—)

kepone

(dec achior ooctahydro-i

,3,

4—metheno—2H—

cyciobuta

cdpentalen-

2—one)

lasiocarpirie

(2—butenoic

acid,

2—methyl—,

7—

(2,

3—dihydroxy—

2-(i-methoxyethyl)-3-methyl-l-oxobutoxy)methylj—

2,

3,5,7a-tetrahydro-lH—pyrrolizin—l—yl

ester)

lead

and

compounds,

N.O.S.

lead acetate

(acetic

acid,

lead

salt)

lead

phosphate

(phosphoric

acid,

lead salt)

lead

subacetate

(lesd,

bis(acetato-O)tetrahydroxytri—)

rnaleic

anhydride

(2,5-furandione)

maleir

hydrazide

(1

,2—dihydro—3,6—pyridazinedione)

rnalononitrile

(propanedinitrile)

melphal

an

(alanine,

3-p-bis(2-chloroethyl)aminophenyl—,

I.—)

mercury

fulminate

(fulminic

acid,

mercury

salt)

mercury and compounds,

N.O.S.

methacrylonitrile

(2—propenenitrile,

2—methyl—)

rnethanethiol

(thiamethanol)

methapyrilene

(pyridine,

2-

(2-dimethylamino)ethyl—2—thenylamino—)

metholrnyi

(acetimidic

acid,

N- ((methylearbamoyl)oxy

thio-,

methyl

ester)

inethoxyc hi or

(ethane,

l,i,l—trichloro—2,2~—bis(p—methoxyphenyl)—)

2-methylaziridine

(I,

2-propylenimine)

3-methyichol

anthrene

(benz

j

aceanthrylene,

I

2—dihydro—3—methyl—)

methylchlorocarbonate

(carbanochloridic

acid,

methyl

ester)

4,4

~-methyienebis(2—ch1oroaniline)

(4,4‘-methylenebis(2-chlorobenzenamine))

methyl ethyl ketone

(MEK)

(2-hutanone)

methyl hydrazine

(hydrazine,

methyl—)

2-methyllactonitrile

(propanenitrile, 2-hydroxy—2—methyl—)

methyl methacrylate

(2-propenoic acid,

2-methyl-, methyl ester)

methyl methanesulfonate

(methanesulfonic acid,

methyl ester)

2-methyl-2-(methylthio)propiorialdehyde—O—

(methylcarbonyl)

oxime

(propanal,

2-methyl-2-’(methylthio)-,

0- (methylamino)carbonyloxime)

N-methyl-N

-nitro-N-nitrosoguanidine

(guanidine,

N-nitroso-N-methyl-N’-nitro-)

methyl parathion

(0 ,0-dimethyl 0-

(4-nitrophenyl) phosphorothioate)

methylthiouracil

(4-lH-pyrimidinone,

2,

3-dihydro-6-methyl-2-thioxo—)

mustard gas (sulfide,

bis(2—chloroethyl)—)

---

—32—

n

aphthalene

I ,4-naphthoquinone

(1,

4—naphthalenedione)

I-naphthylamine

(alpha-naphthyl

amine)

2—naphthyiamine

(beta-naphthylamine)

1-naphthyl-2-thiourea

(thiourea,

l—naphthalenyl—)

nickel

and

compounds,

N.O.S.

nickel

carbonyl

(nickel

tetracarbonyl)

nickel

cyanide

(nickel

(II)

cyanide)

nicotine

and

salts

(nyridine,

(S)—3—(l—methyl—2—pyrrolidinyl)—,

and

salts)

nitric oxide (nitrogen

(II)

oxide)

p-nitroaniline

(benzenamine,

4-nitro-)

nitrobenzene

(benzene,

nitro—)

nitrogen

dioxide

(nitrogen

(IV)

oxide)

nitrogen

mustard

and

hydrochloride salt

(ethanamine,

2—chioro—,

N—(2—chloroethyl)—N—methyl—,

and hydrochloride

salt)

nitrogen

mustard

Noxide

and hydrochloride salt

(ethanamine,

2—chioro-,

N-(2—chloroethyl)—N—methyl—,

N-oxide,

and

hydrochloride salt)

nitroglycerin

(l,2,3—propanetriol,

trinitrate)

4-nitrophenol

(phenol,

4-nitro—)

4-nitroquinoiine-l-oxide

(quinoline,

4—nitro—l—oxide—)

nitrosamine,

N,O,S,

N-nitrosodi-n-butylamine

(1-butanamine, N-butyl-N—nitroso—)

N-nitrosodiethanolamine

(ethanol,

2, 2’—(nitrosoimino)bis—)

N—nitrosodiethylarnine

(ethanamine,

N-ethyl—N—nitroso—)

N-nitrosodimethyl

amine

(dimethylnitrosamine)

N-nitroso-N-ethylurea

(carbamide, N-ethyl—N—nitroso—)

N-nitrosomethylethylamine

(ethanamine,

N—methyl—N—nitroso—)

N-nitroso-N-methylurea

(carbamide,

N-methyl-N—nitroao—)

N-nitroso-N-methylurethane

(carbamic

acid,

methylnitroso-, ethyl ester)

N-nitro somethylviny

I amine

(ethenamine,

N-methyl-N-nitroso-)

N-nitrosomorpholine

(morpholine,

N—nitroso—)

N-nitrosonornicotine

(nornicotine,

N—nitroso—)

N-nitrosopiperidine

(pyridine,

hexahydro—, N—nitroso—)

N-nitrosopyrroiidirie

(pyrrole, tetrahydro—, N—nitroso—)

N-nitrososarcosine

(sarcosine,

N—nitroso—)

5-nitro-o’-toluidine

(benzenaznine, 2—methyl—5—nitro—)

octamethylpyrophosphoramide

(diphosphoramide,

octamethyl—)

osmium tetroxide

(osmium

(VIII) oxide)

7-~oxabicyclo2,2.lheptane-2,3—dicarboxyliC

acid

(endothal)

paraide

hyde

(1, 3,5—trioxane,

2,4,6—trimethyl—)

parathion

(phosphorothioic

acid,

0,0-diethyl

O—(p—nitrophenyl)

ester)

pentachlorobenzene

(benzene,

pentachloro—)

pentachioroethane

(ethane,

pentachloro—)

60-338

---

—33—

pentachloronitrobenzene

(PCNB)

(benzene, pentachloronitro—)

pentachlorophenol

(phenol, pentachloro’-)

phenacetin

(acetamIde,

N—

(4—ethoxyphenyl)—)

phenol

(benzene,

hydroxy—)

phenyleriediamine

(benzenediamine)

phenylmercury acetate

(mercury,

acetatophenyl—)

N-phenyithiourea

(thiourea,

phenyl-)

phosgene

(carbonyl

chloride)

phosphine

(hydrogen

phosphide)

phosphorodithioic

acid,

0,0-diethyl

S- ((ethylthio)methyl

ester

(phor ate)

phosphorothioic

acid,

O,O-dimëthyl

0- p-

(

(dimethylamino)

sulfonyl )phenyl

ester

(if

amphur)

phthalic

acid

esters,

N.O.S.

(benzene,

I,2-dicarboxylic

acid,

esters,

N.O.S.)

phthalic anhydride

(I

,

2-benzenedicarboxylic

acid anhydride)

2—picoline

(pyridine,

2—methyl—)

polychlorinated biphenyl, N.O.S.

potassium cyanide

potassium

silver

cyanide

(argentate

(1-),

dicyano—,

potassium)

pronamide

(3, 5-dichioro-N-(l,

l-dimethyl—2-propynyl)benzamide)

1, 3-propane

sultone

(I, 2-oxathiolane

2,2—dioxide)

n-propyiamine

(1-propanamine)

propylthiouracil

(2, 3-dihydro-6-propyl-2-thioxo-4

(lH)—pyrimidinone)

2—propyn-l~ol

(propargyl

alcohol)

pyr .idins

re serpine

(yohimban—l6-’carboxylic

acid,

ll,17—dimethoxy—

l8-(3,4,5-’trimethoxybenzoyl)oxy)—,

methyl ester)

resorcinol

(1, 3—benzenediol)

saccharin

and

salts

(l,2-benzoisothiazolin-3—one,

1,1—dioxide,

and salts)

safrole

(benzene,

1,

2-methylenedioxy-4-allyl—)

selenious acid

(selenium

dioxide)

selenium and compounds,

N.O.S.

selenium sulfide

(sulfur

selenide)

selenourea (carbamimidoselenoic

acid)

silver

and compounds,

N.O.S.

silver cyanide

sodium

cyanide

streptozotocin

(D-glucopyranose,

2-deoxy—2—(3-methyl—3—nitrosoureido)—)

strontium

sulfide

strychnine

and

salts

(strychnidin—lO—one, and salts)

l,2,4,5-tetrachlorobenzene

60-339

---

‘-34—

~~ioxins

2,3,7, 8—Lctzachlorodibenzo—p—dioxin

(TCDD’

(d~ber~zo~p-dioxin,

2,3,7,8—tetrachioro—)

tetrm.lc~oethane,

N,0~S.

(&~thur

e

tetL achloro—,

N.O

.

S.)

1,1,1,

2~~er~dchioroethane

(ethane,

1,1,1,2—tetrachloro—)

1,1

2, 2-tetranhloroethane

(ethane,

1,1,2,

2—tetrachioro—)

teti achi

oroethene

(perchioroethylene)

tetr

act1 oromethane

(carbon

tetrachloride)

2,3,4,

tctrachlorophenol

(phenol,

2,3,4, 6—tetrachloro—)

tetrae

~hil

ithiopyrophosphate

~.

ti~opvrophosphoric

acid, tetraethyl ester)

tetraethyl

:ead

(plumbane,

tetraethyl-)

te tr as thy 1 pyr opho sphate

(pyr

opho sphor ic

acid,

tetr aethy 1

ester)

tetranitromethane

(methane,

tetranitro—)

thallium

~nd

compounds,

N.O.S.

thali

cr~de

(thallium

(III)

oxide)

tnalli

c

Ii

acetate

(acetic

acid,

thallium

(I)

salt)

tnailirn

I)

carbonate

(carbonic

acid,

dithallium

(I)

salt)

thail~um

(I)

chloride

thallium

(I

nitrate

(nitric

acid,

thallium

(I)

salt)

thallium

selenite

thailinrm

~i)

sulfate

(sulfuric

acid,

thallium

(I)

salt)

thLoacstamide

~ethanethioamide)

thiosemicarbazide

(hydrazinecarbothioamide)

thiourea

(carbamide,

thio—)

thiuram

(his(dimethylthiocarbamoyl)

disulfide)

toluero

(benzene,

methyl—)

toluened

~amine

(2,4-diaminotoluene)

toluene c~isocyanates,N.O,S,

o~toluid~ne hydrochloride

(henzene amine,

2-methyl-,

hydrochloride)

toxaphene

(camphene,

octachloro—)

tr ihr omomethane

(bromoform)

1,2,4 ~tr~chIorobenzene

(benzene,

l,2,4-trichloro—)

1,1,

l-trichloroethane

(methyl chloroform)

l,l,2—trichloroethane

(ethane,

l,1,2—trichloro—)

trichloroethene

(trichloroethylene)

tr ichl oromethanethiol

(methanethiol,

trich.oro—)

trichloromonofluoromethane

(methane, trichlorof.uoro—)

2,4,5—trichlorophenol

(phenol,

2,4,5—trichloro—)

2,4,

6-trichlorophenol

(phenol,

2,4,6—trichioro—)

2,4,5—trichiorophenoxyacetic acid

(2,4,5—T)

facet~c

acid,

2, 4,5—trichiorophenoxy—)

2,4,

5-trichlorophenoxypropionic

acid

(2,4, 5—TP)

(silvex)

(propionic

acid,

2-(2,4,5—trichlorophenoxy)—)

trichloropropane, N,O,S.

(propane,

trichloro—,

N.O.S.)

1,2,3-trichloropropane

(propane,

1, 2, 3’-trichloro—)

60-340

---

—35—

0,0

,0-triethyl

phosphorothioate

(phosphorOthiOic

acid,

0,0,0-triethyl ester)

sym-trinitrobeuzene

(benzene,

1,

3,5—trinitro—)

tris(l—aziridinyl)

phosphine

sulfide

(phosphine

sulfide,

tris(l—aziridinyl)’-)

tris(2,

3—dibromopropyl)

phosphate

(l-propanol,

2, 3-dibromo-, phosphate)

trypan

blue

(2,7—naphthalenedisulfOniC

acid, 3,3~—(3,3’—

dimethyl(1,l’—bipheflyl)—4,4’diYl)biS(aZo)bis(5

amnino-4-hydroxy-,

tetrasodium

salt)

undecamethylenediamifle,

N,N*~bis(2_ch1orobenzyl)~,

dihydrochloride

(N,Nt_undecanlethy1enebis(2~Ch1OrObeflZYlamifle),

dihydrochloride)

uracil

mustard

(uracil,

5—bis(2—chloroethyl)aminO3—)

vanadic

acid,

ammonium

salt (ammonium vanadate)

vanadium

pentoxide

(vanadium

(V)

oxide)

vinyl chloride

(ethene,

chloro—)

zinc

cyanide

zinc phosphide

(Source:

Amended

at

7

Ill. Reg.

13999, effective October

amended

at

Ill.

Reg.

,

effective____________

12,

1983;

8~ Appendix

I

of

Part 721 is added

as follows:

Appendix

I--Method

of

Analysis

for

Ch1o~~ted

dibenzo—p—dioxins

and debenzofurans

Method 8280

1.

Scope ~ndApplication.

1.1

This

method

covers

the

determination

of cMorins

ted

dibenzo-p-diaxins and

chlorinated dibenzofursr,s in chemical

wastes

incmuding still

bottoms.

biter

aids,

~Thismethod is ep

priste

fpr the

analy,is

of

tet~s~,

penis..

end h,xachloriisted diben,.o.p~

d~n~ins

and -clihenauf

crane.

~Analvticalprotocol for determination

of

TCDDe

in phenotic chsm~calwastes and ~~ilsamples

obiatned from

the

proximity of

chemical

dumpa,

TO. Tiarnan and M. Taylor

Erehm Laboratory,

Wright State

Univerany. Dayton, OH

45435.

~Analyticelprotocol for determination of

chlorinated dibenzo-p-dioxins

and

chlorinated

dibenzofurane in

river water. TO. Tiernan

and M.

Taylor.

Brehm Laboratory, Wright State

Univarsity.

Dayton. OH 4543.5.

‘In general, the techniques that

should be osed to

handle these materials are

those which

are

followed

for radioact~vaor infecttoua laboratory

materials.

Asetetance

in evaluatiflg laboratory

practices may

be obtatned from Industrial

hygienists and

persons

specializing in ~af~laboratory practice.

Typical

Infeotmut wade incinerator, are

probably

not

~etis1acto~v

devices for disposal of materials tri~hly

contaminated with

CODs or CDFs.

.~.

laboratory

planning to

oce these cooipounds

should prepare

a

dispoesl plan to be reviewed and approved

by

EPA’s Dioxin Tasl

Force

IContact

Conrad

Klevtao,

W1-548A.

U.S

EPA.

401

M Street, SW.,

washington. D.C.

2~eeO).

sludges, spent carbon,

end reactor r~cldues.

and in salle.

1.2

The sensitivity

of this

nwthud

Is

dependent upon the level

of lnterfer.ns~as,

1.3

This method

is recommended for one

only by analysts expertenced

with residue

analysis

and skilled in mess

spectral

analytical techniques.

1.4

Because

of the extreme

toxicity

of

these compounds.

the

analyst must

take

necessary

precautions

to

prevent

exposure

to

himself,

or to others,

of

materials known

or

belayed to cor.tairt CDI). orCDF~.

2.

Summary

of theMethod.

2.1

This

method Is

an analytical

,..~.treclinncleanup

procedure.

and

captil.i’y

columr. gas chromatographty-tow resolution

mass spectrometry method,

usinj.capiilary

colurr,n

CC/MS

condttlons and

internal

etande~dtechniques,

which

aLlow~for

the

measurement of PCDDsand

~DPs

in

the

extract.

22

if interferences

are

encountered,

the

methnd

provides

selected

general purpose

cleanup

proceduresto

aid

the

analyst in their

elimination.

3.

interferences.

3

Solvents, reagents,

glassware,

and

other sample processing hardware

may

yield

discrete artifacts and/or elevated baselines

causing misinterpretation

of gas

60-341

---

—36—

r,hro~natogranie.A

at t tern r,atanals must

be

o

mao~tc~ed

ir

be free

from

,itcrfrrencee

under ~he cmmdit one rf the analysis by

‘unr:ag

mrathod bla”ka

Spe~’fics&ec~3ott

of

rs’msgerte and

oun

,il’nr

rt

sfrve

its

by

ch~

~~8t’no

,,

pH-gsare sn~’~.r

i

may be

3.2

lnle,ferc, cc

cr

~x~actcd

from the

samples

WI!

very

‘re,~’derablyIron’ aource

to

aou~cedepe ‘id

rig

‘

is

he divercity of the

~nduetry

b

ing

.~

mr,~

~is

,‘J’m3 is

often

aseocinted w

Lb ri~hemtcrfcrftig

l’ioruiated

compounds such a

DCf

wis.~hmay

be at

earscent

shone ~nm rat oro

rt

f magnitude

higher thai

.rat ci ~CDU

While general

cleanup

act

iqv ,ti

are provided as pert

of

this

mat, ad

urtana eamples may require

additmonat cleertus, approaches to achieve

the

senaitivm.y

vied

I

lab”

1.

3.3

The

‘I

er

somers of

tetrachlorod’aenzo

p dioxin may interfere

with

hr

“ian.. urc’ne

f 2

3,7,&-~TCDD.

Capilla

y no nmo ga

chromatography Is

requt

ed to

nco~v

cc” isomers that yield

virtually idvr,ic

I

mace

fr

gmentation

pa Iterms,

4,

Appa”a

us and Materials.

41

Samp

rig

equipireni

for discreteor

composite sempling

4.1

1

Grub sample bottle—amber glass,

1-

liter or I~qua “vo urns. French or Boston

Rounc~

dr’mm’gr

is rerommendeci

The

container

irtust b~washed and aolvent rinsed before

uee

to rotc, mice

mnterferences.

4

1.2

Dot

me

..eps—threaded

to screw on

to

the sampfr I

~,lea

Caps nuat be

lined

with

Tafton, Solvent

washed

foil,

used with the

sh’riy side toward

the sample, may be

sibstituted fo

the Teflon if sample is

not

corroc’i

1.3

~o~pos’ttng

~quipmentutomatic

or manna

co’npo

Lang system.

No tygon or

rubber tubing may be used, and

the system

mud

incorporate

glass sample containers for

the

ocillac

ion of a minimum of 250 ml.

Sample

containers roust be kept refrigerated

after

sampling.

4..

Water beth—heated, with

concentric

ring

cover, ca~abIeof temperature control

(±

2” C), The bathshould be usedin a hood.

4.3

Gas chromatograph/maas

spectrometer data system

4.31

Gas chrornatograph. An analytical