ILLINIOIS POLLUTION CONTROL BOARD

May 30, 1985

tN THE ~4ATTEROF:

VOLATILB ORGANIC ~4ATERIAL

)

R82-l4

~4ISSIOt~SFROM STATIONARY

)

Dockets A & B

SOURCES: RACT III

PROPOSED ORDER:

SECOND NOTICE.

OPINION At~1DORDER OF THE BOARD (by B. Forcade):

On August 10, 1984, the Board adopted for First Notice

language amending 35 Iii. Adm. Code 215: Organic Emission

Standards and Limitations. The proposed rules, which pertained

to four industrial categories, appeared on August 31, 1984, in

Volume 8, Issue 35 of the Illinois Register at page 15864. Since

that time, thirteen public comments have been received by the

Board. This Opinion for Second Notice will address those

comments and explain the changes made in the proposed regulations

as they appear in the attached Order.

With its original proposal in this matter (Ex. 1), the

kgency sought to amend Section 215.205 as adopted in R78—3, 4:

R~CTI. That Section contains emission standards, based on

capture and destruction efficiencies, as alternatives to the

volatile organic material limitations for surface coating

operations contained in Section 215.204. This amendment was not

included at First Notice due to an improperly perceived

nexus

with the amendments proposed for Section 215.207, which are

discussed below. However, the Agency’s public comments submitted

during First Notice served to distinguish the proposed amendments

(P.C. 57). Because an entire rule, Section 215.205, was not

included at first notice, it will be necessary to submit this

rule to the Administrative Code Unit for first notice

publication, in order to comply with Illinois rulemaking

procedures. 1 Iii Adm, Code 100.110 defines “rule,” in pertinent

part, as “a Section of a Part.” Since all “rules” must be

published in the Illinois Register, the Board will, in a separate

order, direct Section 215.205 to first notice.

The Agency also originally proposed amending Section

215.207, which contains the internal offset rule for surface

coating operations achieving compliance pursuant to Section

215.204. The amendments proposed by the Agency were offered for

purposes of clarification and to satisfy problems raised by the

USEPA subsequent to SIP review (Ex. 1 and 15, R. 16, 289; 1018;

1025). At hearing, several participants argued that the

amendments proposed would have substantive effects. The Agency

agreed, and at this time, it is studying the effects the

amendments as proposed might have on facilities currently using

64-177

---

—2—

the internal offset rule. Until that study is completed, the

7~gency requested that no action be taken on amending that rule

(P.C. 52). The Board does not have sufficient information to

amend the rule resolving federal problems, while satisfactorily

addressing the participants~ concern. Therefore, no action will

be taken on Section 215.207.

Two commenters requested that the list of exempt compounds

contained in the definition of volatile organic materials be

expanded to include seven additional compounds (P.C. 33, 63).

The basis for expanding the exemption list is that the seven

compounds, all chlorofluorocarbons (“CFC”) or fluorocarbons

(“FC”), are not photochemically reactive arid are recognized by

USEPA as such. Accordingly, (JSEPA recommended on July 22, 1980,

(45 FR 48981) that these seven compounds be exempted from

emission control to attain or maintain ozone standards. The

record indicates that the Agency, itself, believes that CFC’s as

a group are not photochemicaily reactive (R. 2516), The Agency

contended at hearing, however, that these substances should be

regulated because of their possible contribution to ozone

depletion (R. 2463). This rationale is beyond the scope of RACT—

III, a proceeding designed to control the formation of ozone as a

criteria pollutant. Therefore, the following compounds will be

added to the list of exempt substances within the definition of

VOM: trichlorofluoromethane, dichiorodifluoromethane,

chlorodifluoromethane, trifluoromethane, trichioro—

trifluoroethane, dichlorotetrafluoroethane and

chioropentafluoroethane.

Several comments were submitted pertaining to Subpart K:

Use of Organic Material, First, some commenters were concerned

about the elimination of the viscose exemption (P.C. 53, 65).

That exemption from the general rule, which was already adopted

as final under this rulemaking on June 14, 1984, anticipated that

amendments more stringent than the general rule would be

adopted. Such amendments, commonly known as the Generic Rule,

were not adopted. Therefore, at First notice, the viscose

exemption was proposed to be repealed as unnecessary, if the

respective companies’ positions remained unchanged. As was the

situation before this rulemaking began, those Illinois companies

manufacturing viscose casings using carbon disulfide are subject

to the general rule contained in Subpart K. Nothing in this

rulemaking, that is the adoption and subsequent repeal of the

exemption, alters the regulation of these facilities as sources

of air pollution.

Another group, the Chicago Paint and Coating Association

(Association), requested that the exemption discussed at hearing

and in its public comment submitted prior to First Notice be

reconsidered (P.O. l9)~ The Association sought an exemption from

Subpart K for portable open—top mixing tanks and processing

equipment used to manufacture compliance coatings. At hearing,

the exemption was considered from the terms of the proposed

Generic Rule (R. 1532--1534; 1542; 1547—1550; 1560). The

64- 178

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—3—

Association asserted that the volatile organic materials emitted

“are very small in amount much less than the 8 lbs. per hour

limitation in Rule 205(f)(a)” and that it would not be

technically and economically feasible to constantly measure such

emissions (P.C. 19). Since Subpart K was not amended to include

the proposed Generic Rule, and according to the Association these

sources already comply with Section 215.301, of the general rule

contained in Subpart K, the Board finds no reason to adopt the

exemption suggested.

Five comments were submitted pertaining •to Subpart ~:

Synthetic Organic Chemical and Polymer Manufacturing. The first

commentator requested that hexadecyl alcohol be removed from the

substances list in Appendix D, the manufacture of which subjects

facilities to the Subpart Q requirements. In the alternative,

the commentator requested an exemption from the regulations for

those concerns manufacturing the substance from natural fatty

acids or using no volatile organics, which is, in fact, the

manufacturing method used by the commentator (P.C. 55). Given

these circumstances, there appears to be no volatile organics to

be detected under the leak inspection program. Therefore, such

an exemption is inserted at Section 215,420. The exemption

rather than the delisting of just one substance, will serve to

exempt similar manufacturi~igprocesses.

Three other commenters requested that the applicability of

Subpart Q be limited to sources located in counties designated as

nonattainment for ozone (P.C. 58, 59 & 61). As one commentator

reiterated, only an estimated 3,650 tons of emission reductions

are anticipated annually if all facilities statewide are subject

to regulations (P.C. 59). There is no way, unfortunately, to

separate this figure into subtotals of emission reductions

attributable to the 43 facilities located in nonattainment

counties, the five facilities in counties contiguous thereto, and

the 16 facilities in attainment counties but not contiguous. That

commentator still asserts that it will cost approximately $50 to

$75 million the first year and $lB—$35 million each year after to

comply, at a cost of $5 to $7 per component. This figure is much

greater than the estimate of $1.00 to $1.50 per component

presented at hearing (R. I977)~ Notwithstanding the difficulty

of estimating compliance costs, the rule proposed at first notice

and directed to second notice today, eliminates many costly

requirements contained in the original rule proposed by the

Agency and analyzed in the EcIS. Double block sealing mechanisms

on open—ended lines are not required and inspection and

monitoring is geared towards the ozone season rather than on a

quarterly basis. Additionally, compliance costs can be reduced

through the increased use of ball and plug valves, which are

exempt from the definition cf component.

RACT III has developed as a statewide control program.

Pollution control is rarely inexpensive but where there ate

unique circumstances and special hardships remedies are available

through variances and site—specific regulation. These options

64-179

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—4—

are, as always, available to the regulated community. The Board

will retain the staged two compliance date application of these

rules on a statewide basis.

Additionally, because the February 28, 1985, compliance date

in Section 215.427 a) has passed, it will be extended to October

31, 1985.

The Agency, in its comments, pointed out that the Board’s

extrapolation of the use of ball or plug valves throughout the

synthetic organic chemical industry rests on the testimony of one

Monsanto Company employee (P.C.. 57). While the 95 per cent usage

rate of ball and plug valves experienced at Monsanto may not be

typical throughout the industry, the rationale for excluding ball

and plug valves is well supported. Ball and plug valves are

utilized by the industry specifically because of their low leak

rate, in order to comply with Occupational Safety and Health

Administration (OSHA) regulations (R, 1806). The emission

factors for ball valves are 200 times smaller than for gate and

globe valves (R, 1215

—

1217), Also, by allowing their exclusion

from the definition of component and consequently from the 1,500

component threshold, there will be an incentive for industry to

increase the use of these low leak valves. However, the Board

will subject the ball and plug valves to the identification

provisions of Section 215.421(d) so that these exempted valves

are obvious to the monitoring or inspecting personnel (P.C. 57).

A final note on Subpart Q; one commenter requested that four

polymers be deleted from Appendix D. The commenter, however,

provides no basis for this deletion and so no action will be

taken at this time.

The steel groups submitted a public comment on Subpart U:

Coke Manufacturing and By-Product Recovery (P.C. 56). The

editorial corrections suggested at Sections 215.512 and 215.514

are added with this Second ~1otice, The steel group also asked

that the inapplicability of Subpart K, given this new series of

rules, be clarified. As previously worded, the general rules

contained in that Subpart would have possibly been applicable to

the industry’s fugitive emission sources, such as its cooling

towers. The Board agrees that this was not intended; Section

215.500 has been reworded accordingly.

Finally, the steel group requests that the compliance dates

be extended to avoid expenditures by

the steel industry to comply

which may prove unnecessary subsequent to the adoption of benzene

regulations currently under consideration by the USEPA.

Likewise,

it is

argued

that the

proposed state regulations should

terminate when the federal standards are adopted.

In the event

that the federal regulations are

incompatible, a rulemaking to

repeal those adopted in this rulemaking will be perfunctory since

the state~sscheme cannot be less stringent or incompatible.

However, there is no way at this time to anticipate that the

regulations adopted will be covered by the federal scheme

or

that

64-180

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—5—

they will be incompatible. It may be that they are comparable,

and no additional performance will be required by the industry.

However, to insure that there are no unnecessary expenditures,

the compliance date for reducing emissions at the four sources

identified in Section 215.510 has been extended to December 31,

1986.

A number of comments were received regarding the Subpart P

heatset web offset rules (P.C. 54, 57 & 62). It has become

apparent, upon rc~.~ewof the record and comments, that the rules

proposed at first otice need substantial revision. It is also

apparent that thE: ‘urrent record, in this area, is inadequate in

several areas to ::~,elop satisfactory language. Therefore, the

Board will withdr~

i

the heatset web offset rules and resubmit

them for first non-ce in a separate order, The record in this

area will be reopened and ~ public hearing will be scheduled in

order to supplement the existing record.

ORDER

In response

to

public comments received during first notice,

the Board amends language in 35 Ill. Mm, Code Part 215, Subparts

Q, U and Appendix D. The Board also deletes proposed amendments

to Subpart P and will repropose language regulating the heatset

web offset printing industry for first notice in a separate

order, as well as propose Section 215.205 of Subpart K. The

following rules are directed

to

the Joint Committee on

~dministrative Rules for second notice:

PART 213

ORGAt~IC MATERIAL EMISSION STANDARDS AND LIMITATIONS

SUBPART A: GENERAL PROVISIONS

Section

215.100 Introduction

215,101 Clean—up and Disposal Operations

215.102 Testing Methods

215.103 Abbreviations and Conversion Factors

215.104 Definitions

215.105

Incorporations by Reference

215.106

Afterburners

SUBPART B:

ORGANIC EMISSIONS FROM STORAGE

MID LOADING OPERATIONS

Section

215.121 Storage i~ontainers

215. 122

Loadin’;

perations

215,123 Petro:~~I~iquid

Storage Tanks

215.124 ~xtern ~1oating

Roofs

64-181

---

215.125 compliance Dates and Geographical Areas

215.126 compliance Plan

SUBPART C: ORGANIC EMISSIONS

FROM

215.141 separation Operations

215.142 Pumps and Compressors

215.181 Solvent Cleaning in General

215.182 Cold Cleaning

215.183 Open Top Vapor Degreasing

215.184 Conveyorized Degreasing

Section

215.202 Compliance Schedules

215. 204 Emission Limitations for Manufacturing Plants

215.206 ExemptIons from Emission Limitations

215.207 Internal Offsets

215.208 Testtng Methods for Solvent Content

215.209 Exemption from General Rule on Use of Organic Material

215.211 Compliance Dates and Geographical Areas

Section

215.301 Use of Organic Material

215.302 Alternative Standard

215.303 Fuel Combustion Emission Sources

215.304 Operations with Compliance Program

04-182

---

—7—

flexane Extraction Corn Oil Processing

Recordkeeping for Vegetable Oil Processes

Compliance Determination

Compliance Dates and Geographical Areas

Compliance Plan

Flexoq:c

~: and Rotoqravure Printing

S xcmp

t:

Appiic~

~y

of

Subpart K

Testiriç~ ~ Monit.oririq

Compiia~

Dates and

Geographical Areas

A1terna~

‘~

Compliance Plan

Complian:

Plan

SUBPART Q~

SYNTHETIC ORGANIC CHEMICAL AND POLYMER

MANU FACTU RING

Section

215.420

215.421

215.422

215.423

213.424

215.425

215.426

215.427

215.428

General Requirements

Inspection

Proqram

Plan for Leaks

Inspection Program for Leaks

Repairing Leaks

Recordkeeping for Leaks

~!P2~

tlfl9 for

Leaks

Alternative Program for Leaks

P~~~eoraohicalArea~

SUBPART

~

~ETROLEUM REFINING AND RELATED

:ccJ~T~tIE~3;~½SPHALTMATERIALS

Petroleur~ :~r~:vWaste

Gas Disposal

Vacuum Pr ~

g Sys

:~ems

Was tewat~r ~ i~:~/Water~Separator

Process TJo:~.: ~:rr~a~cunds

Leaks: c~en~e~ ~auirements

Monitor ~ni ~~i:

~ Plan ~or Leaks

Monitor~icI

:air for Leaks

Recordkeeoti’i

:~

L~~ks

Report:inq

:~.

A1terna1v~ Prooran ~or Leaks

Sealinq

~ ~,

~

~

~~rer

Comp1i~:~~~

~

£)L~ Leaks

Compii~

:e~ and

Leo~raphica1

Areas

215.342

215.344

215.345

215.346

215.347

Section

215. 40?

215.40

215.403

215.404

215.405

215

.

406

215. 407

Sur~r:~RTP~

PRINTIMG AND

PUBLISHING

Section

215. 441

215.442

215.443

215. 444

215. 445

215.446

215.447

215.448

215.449

215.450

215.451

215.452

215.453

64-183

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—8—

SUBPART 5: RUBBER AND MISCELLANEOUS

PLASTIC PRODUCTS

Manufacture of Pneumatic Rubber Tires

Green Tire Spraying Operations

Alternative

Emission Reduction Systems

Testing and Monitoring

Compliance

Dates

and Geographical Areas

Compliarce Plan

SUBPART

U: COKE MANUFACTURE AND

BY-PRODUCT RECOVERY

Section

215.500

215.510

215. 512

215. 513

215. 514

215.515

215. 516

215.517

Exception

Coke By—Product Recovery Plants

Coke

By—Product

Recove~y P:lant Leaks

Inspection Program

Recordkeeping Reç~jrements

~inRe~iirement~3

Cm~~iane~ae

Compliance Plan

Section

215.541 Pesticide Exception

Architectural

Coatings

Paving Operations

Cutback

Asphalt

Bulk Gasoline P1~nLs

Bulk Gasoline TeLr~inais

Gasoline

Dispensirr

Facilities

?~

DRY

CLEANERS

Perch1cr;rethy1en~ Dry C±eariers

Exemoti ~:

Testing ~nd ~cr~.tcrir:g

Section

215.461

215.462

215.463

215. 464

215.465

215. 466

SUBPART W:

AGRICULTURE

SUBPART X:

CONSTRUCTION

Section

215. 561

215. 562

215. 563

Section

215. 581

215.582

215.583

Section

215.601

215.602

215.603

SUBPART

:~

GASOLINE

DISTRIBUTION

---

—9—

215.604 Compliance Dates and Geographical Areas

215.605 Compliance Plan

215.606 Exception to Compliance Plan

Appendix A Rule into Section Table

Appendix B Section into Rule Table

Appendix C Past Compliance Dates

~ppendix D List of Chemicals Defining Synthetic Organic

Chemical and Polymer Manufacturing

AUTHORITY: Implementing Section 10 and authorized by Section 27

of the Environmental Protection Act (Ill. Rev. Stat. 1983, ch.

1111/2, pars. 1010 and 1027).

SOURCE: Adopted as Chapter 2: Air Pollution, Rule 205:

Organic Material Emission Standards and Limitations, R7l—23,

4 PCB 191, filed and

effective

~pril 14, 1972; amended in

R77—3, 33 PCB 357, at. 3

Iii. Reg.

18, p. 41, effective

May 3, 1979; amended in R78—3 and R78—4, 35 PCB 75, at 3 Iii.

Reg. 30, p. 124, effective

July

28, 1979; amended in R80—5

at 7 Iii. Reg. 1244, effective January 21, 1983; codified

at 7 Ill. Reg. 13601; Notice of Corrections at 7 Ill.

Reg. 14575; amended in R82—l4 at B Ill. Reg. 13254, effective

July 12, 1984; amended in R83—36 at 9 Ill. Reg.

________

effective

________________,

1985; amended in R82—14 at 9 Ill.

Reg.

_______,

effective

_____________

1985.

SUBPART A: GBN~RAL PROVISIONS

Section 215.104 Definitions

The definitions of 35 111. Adm, Code 201 and 211 apply to this

Part, as well as the definition contained in this Section. Where

the definition contained in this Section is more specific than

that found in Parts 201 or 211, it shall take precedence in

application of this Part~

“Binders”: Organic materials and resins which do not include

volatile organic materials.

“Clear Topcoat”: The final coating which contains binders,

but not opaque p~gmentsand is specifically formulated to

form a transparent or translucent

solid

protective film.

“Conventional Soybean Crushing Source~: Any hexane

extraction soybean crushing equipment that uses direct

contact steam for desolventizing and producing toasted soya

meals.

84485

---

—10—

1Contponent~v: Ani

piece of

e~i~entwhich has the potential

to leak vole or anic material inc:Luding, but not limited

to, pump seals, corn sor ala, seal ii. degassing vents,

pipeline valves, pressure relief devices, process drains and

open ended pipes. This definition excludes valves which are

not externally regulated, flanges, dequipment in heavy

~~quid service

r

ur

of Sub ar

Q,

this definition

also exc1udes~~1andiuc,alves.

“Furniture Corc~9~JDp1ication

Linen: The combination of

coating applic~,~ione~ii~men clash—off

area, spray

booths,

ovens, conveyc:.9, and other eqr~~ntoperated in a

predetermined

cefrourpose of

apply coating materials

to wood furniture.

“Heatset”: A class

of web

offset

lithography which requires

a heated dryer to solidify th~printing

inks.

“Heavy Liquid

uid with true

ye

or 2ressure of less

than 0.3 kPa (0,04 psi)

at 294.3 K (70 F) established in a

standard reference text or as determined b~yASTM

method D—

2879; or 0.1 Reid

Vapor Pressure as determined by ASTM method

D-323; or which when_distiUed~~Lresatem2eratureof

300

or greater to recover l0~of the

licuid as determined by ASTM

method D—86..

“Light Liqui&: Volatile organic material in the liquid

state which is not defined as heavy liquid.

“Lig~ht Oil”:

Aliquid condensed or

absorbed

from coke oven

gas composed of benzene,_toiu~and~i~e.

“Offset”:

Use of a blanket._c’llnder

to transfer ink from the

plate cylinder

to the surface

to bepr :inted.

“Opaque Stains”:

~istainscor:taininUj~i~rnentsnot

classified as semi~-transparent stains including stains,

glazes and other opaque material ~~g~ve

character to wood.

“Pigments Coating~:

Oa2~_coatin~j~containing

binders and

colored

p~gmentswhich

are formulated to

conceal the wood

surface

either as an undercoat or toocoat.~

“Repair Coatinqs’~:

Coatings

to correct imperfections or

damage to furniture surface.

“Sealer”:Co~ncontaininh:~.nders which seals the wood

~~~oa~plicaticn_tosubsecuentcoatinus.

“Semi—transparent Stains”: Stains can~:aining

dyes or semi-

transparent

pigments which are formulated to enhance wood

2rain and change

the color_of

the surface

but not to conceal

the surface, including

sap stain,

toner, non—grain raising

stains, pad

ctain,_spatter stain, and

other semi—transparent

64-186

---

—11—

“Specialty Soybean Crushing Sourc&:

Any hexane extraction

soybean crushing equipment using indirect steam heat in flash

or vapor deso:Lventizers as the primary method of

desolventizing and producing specialty solvent extracted soy

flakes, grits or flour,

“Volatile Organic Material”: Any organic material which has

a vapor pressure of 17,24 kPa (2.5 psia) or greater at

294.3 K (70 F). Fo~ ~ee~ e~-3~

~

A~im~ee~e2~5-44~

th~eti~t~5-4447 ~e~e

e~ge&~em e~4&6n~ea~a~ye~at~e

me~a~ w~-ieh ~as a ‘~p~ p~ee~~ree~ -i8~34 3~Pe~

a~~94~-3—H~‘O—F~ Fei~ p poc~e~e~35 3.~-1~h~Mm~ ee~e~5-~8~

~I’t~et~h2~5~847

~r44~

~E~t~g~i

~

~5-;~2O4~et~l~t

~5-2O97

5-~46~

~~3~5~34O~57464e~ig~

aitc~

5~34~7576k~~h~etiq~5-4~flt~i~ot~i~5-6O3Q~S-484~ 7

e~a~ie~ftete~a-1meene enj

e jenle me~t-~

~

~as a vepe~

p~eeee~e e&~e~then~t E~-9l3 ~Pr~ +-~9O~9 ie~ a~

~94~S—K

For

purposes of this definition,

uhe following are not

volatile organic materials:

Methane

E the ne

l,l,—~ trichloroethane

Methylene chloride

Tr ichlorofluoromethane

Dichiorod if luoromethane

Chiorodifluorornethano

-

Trifluorcmethane

Tr i.chlorotr

ifluoroethane

Di chic rote t rci I u or cc than a

Chioropentafluoroethane.

For purposes

of 1: ici:Lo’~inc

ections,

volatile organic

materials are an~ organic materia~haX~fl~_~!

co rresponding v~orpressures at

294.3 K (70 F):

Sections

\?apor Pressure

215.181

215.184

0.013

kPa

(.0019 psia)

215.104

—

215.209

0.013 kPa

(.0019 psia)

215.340

—

215.345

0.013 kPa

(.0019 psia)

215.401

—

~57494 215,408

0.013

kPa

(.0019 psia)

215.420

—

215.428

0.013 kPa

(.0019 psia)

215.441

—

215.441

:Lo.~4 kPa

(1.5

psia)

215.445

—

2l5~451

0~013 kPa (.0019 psia)

215.461

-.

215.464

0~t3 tpa

(.0019 psia)

215.510

—

215.513

0~C3 kpu

(.0019 psia)

215.601

—

215,603

O.0.3 kPa

(.0019 psia)

“Wash Coat”:

Coating containing hinde~r which seals wood

surfaces, prevents undesired staininq:~oontrols

penetration.

—___________

64-187

---

—12--

“Web”: A substrate which is printed in continuous roll—fed

presses.

“Wood Furniture”:

Room furnishings including cabinets

(kitchen, bath and vanity), tables, chairs, beds, sofas,

shutters, a hects, wood paneling, wood flooring, and any

other coat furnish~nsmade of woed,

wood composition or

simulated wood materials.

(Source:

Ai~’,erded at 9

Iii,,

Req.

effective

_________,

1985)

Section 215.105 Incorpotations by

Reference

The following

materials are incorporated

by reference:

a) American Society for Testing and Materials, 1916 Race

Street, Philadelphia,

PA 19103:

I)

ASTM

r)

:1633~~59Method A

2)

ASTM 1) 1475—60

3) ASTM D 2369—73

4) ASTM 0 2879

5) ASTM 0 323

6)

ASTM 0 86

7)

ASTM E 260, ~‘68,

69

b) Federal ,tandard !4ia, Method 4082.1

c) National Fire Codes, Nat:Lonal Fire Protection

Association,

Battery March

Park, Quincy, Massachusetts

02269 (1979)

d)

United States E~uvironmenta1 Protection Agency,

Washingron, D.C, EP1~—43Q/2--77—026,

Appendix A

(Source: Amended at 9111. Req.

____,

effective

,

1985)

SUBPART ~:

COATING OPERATIONS

Section 215.204

Emiasicu Lirt

:ionc for Manufacturing Plants

t~oowner or op~atni: of a ecuttn~1 ins ntaiTL cause or allow

the emissior~

;..

~‘~1

utile

.~.

~U. aatar:Lcl to exceed the

following 1i::.~:ntions on ccat:~c r•7aterials, excluding water,

delivered

to

;•:•~

coatinc E~r4aicator

64-188

---

1) In Cook County

kg/l

Prime coat

0.14

(1.2)

Prime surfacer coat

0.34

(2.8)

(Board tIotes The prime surfacer coat limitation is

based upon a transfer efficiency of 30 percent.

The prime surfacer coat limitation shall not apply

Top coat

0.34

(2.8)

(Board Note: The limitation is based upon a

transfer efficiency of 30 percent. The top coat

limitation shall not apply until December 31,

Final repair coat

0.58

2) In Boone County

kg/i

lb/gal

Prime Coat

0.14

(1.2)

Prime coat surfacer

0.34

(2.8)

Top coat

0.34

(2.8)

(Board Note : The top coat limitation shall not

apply if by December 31, 1984, a limitation of 0.43

kg/I (3.6 lb/gal) is achieved and the top coat is

applied with a transfer efficiency of not less than

55 percent and by December 31, 1986, the top coat

is applied with a transfer tfficiency of not less

Final npair coat

0.58

3) In the remaining

counties

kg/i

lb/gal

Prime cost

0.14

(1.2)

Prime surfacer coat

0.34

(2.8)

Top coat

0.34

(2.8)

Final repair coat

0.58

b) Can Coating

lb/gal

1) Sheet basecoat

and

Overvarnish

O.S6

(2.8)

2) Exterior basecoat

and overvarnish

0.34

(2.8)

04-189

---

—14—

lb/gal

3)

Interior body spray

coat

0.51

(4.2)

4)

Exterior end coat

0,51

(4.2)

5)

Side seam spray coat

0.66

(5.5)

6)

End sealing

coie~:u::dcoat

0,44

(3.7)

c)

Paper Co~~;g

0.35

(2.9)

(Board No~

The limitation shall not apply to

equipment used for both printing and paper coating)

kg/l

lb/gal

d)

Coil Coating

0,31

(2.6)

e) Fabric Coating

0~35

(2.9)

f)

Vinyl Coating

0.45

(3.8)

g)

Metal Furniture Coating

0.36

(3.0)

h)

T~argeAppliance Coating

0.34

(2.8)

(Board Note:

The limitation shall not apply to the use

of quick--drying lacquers for repair

of scratches and

nicks that occur

during assembly, provided that the

volume of

coatirt~ does

not

exceed 0.95 liters (1 quart)

in any one eight--hour period)

kg/I

lb/gal

1)

Magnet Wire Coating

0.20

(1.7)

fl

Miscellaneous

Metal

Parts

and Products Coating

1) Clear coating

0.52

(4.3)

2) Air dries coating

0.42

(3.5)

3) Extreme performance

coating

0.42

(3.5)

4) All other

coatings

0,36

(3.0)

(Board Not~•c The least restrictive limitation shall

apply if c~irethan one limitation pertains to a specific

coating)

84-190

---

—15—

k) Heavy Off-highway Vehicle

Products

lb/gal

1)

Extreme performance

prime coat

0.42

(3.5)

2) Extreme performance

top coat—air dried

0.52

(4.3)

3) ~inal repair coat—

air dried

0.58

(4.8)

fl,

Wood Furniture Coating

kg/I

lb/gal

~j_ Clear topcoat

0.67

(5.6)

2) ppaque stain

0.56

(4.7)

3)

Pigmented coat

0.60

(5.0)

4) Repair coat

0.67

(5.6)

~1

Sealer

0.67

(5.6)

6) Semi—transparent stain 0.79

(6.6)

7) Wash coat

0.73

(6.1)

ç3oard Note: The reoair coat has overall transfer

efficienc~~0 percent; all others have an overall

transfer efficiency of 65 percent.)

(Sources

Amended at 9 Ill. Reg.

____,

effective

________,

1985)

3ectton

215.211 Compliance Dates and Geographical Areas

a)

Except as otherwise stated in subsection (b), every

owner or operator of an emission source subject to

Section 215.204(j), a~ (k) and (1) shall comply with

those sections in accordance with the following dates:

1) For Section 215.204(j) and (k), by December 31,

1983.

2) For Section 215.204(k)(2), in accordance with

Section 215.210.

3) For Section 215.204(1), by December 31, 1985.

b)

If an emission source is not located in one of the

counties listed below ~

a~e ne4~ ~eea~e~ ~ afty

ee~m~yee ~guetisthe~ete,

the

owner or operator of the

64-191

---

—16—

emission source shall comply with the requirements of

Section 215.204(j) e~,(k) or (1) no later than December

31, 1987:

Bond

Madison

Clinton

McHenry

Cook

Monroe

DeKaib

Montgomery

DuPage

Franklin

Pope

Greene

Randolph

Jackson

Saline

Jersey

Sagamon

Johnson

St. Clair

Kane

Union

Kendall

Washington

Lake

Will

Macoupin

Williamson

(Board note: The United States Environmental Protection

Agency (TJSEPA) noted in its redesignation rulemaking,

that it will publish a rulemaking notice on Williamson

County~sattainment status. (45 Fed. Reg. 21949, May

16, 1983.) Should Williamson Count be redesignated as

attainment prior to October 31, 1985, it and the

counties contiguous to it will be considered deleted

from the above list.)

c) Notwithstanding subsection (b), if

any county is

designated as nonattainment by the (JSEPA at any time

subsequent to the effective date of this

rule, the owner

or

operator

of

an

emission

source located

in that county

or any county contiguous to that count.y who would other-

wise be subject to the compliance date in subsection (b)

shall comply with the requirements of Section

215.204(j), e~(k) or (1) within one year from the date

of redesignation but in rio case later than December 31,

1987.

(Source: Amended at 9 Iii. Reg.

____,

effective

________,

1985)

Section 215.212 Compliance Plan

~)

The owner or operator of an emission source subject to

Section 215.211(a)

(1) or (2) shall submit to the Agency

a compliance plan ~t eceei’danee ~-i1~h?~5

~

~ ?e~e

~O~7 Subpa~ H7 ~ric~ud-in~a p~o~ecteemp~e~e~se~edu~e

whefe

tcah~e-T on

or before

August

19, 1983.

b) The owner or operator of an emission source subject to

Section 2l5.2ll(a)(3) shall submit to the Agency a

compliance plan on pr before December 31, 1984.

04-192

---

—17—

bl

~J_

The owner or operator of an emission source subject to

Section 215,211(b) shall submit to

the Agency a

compliance plan,

e~~g a p~e~e~eomp~e~ert

seI~ted~e

whei~e p~±eeb~e7no later than December 31, 1986.

41

The owner or operator of an emission source subject to

Sectione~n~215,211(c)a

pt~ejee~shalleoMp~e~o~~tsubmit~ehe~t~rea

compliancewithinplan907days

after the date of redesignation, but in no case later

than DeceFh~r 31, 1986.

d~ e) ~t~ess the ~bm~k~e~

eemp~4ai~~ee

p~ar~ei~’ sthe~u3e4s

~app~e~e~ ~y the Agerteyy the ew~ie~

e~ eper’a~e~of a

e43~~yei~

4ss4ei~ ee~ee sub~eekt~e the

~~es

4u sa ee~4ene +a+7 ‘(-~r ~

+e+ may epefa~e the

em~ss~ret’~so~ee a~eo~’~Ng~o

the ~I-art at~d

sehe~.~e as

~e ~

-

The owner or operator of an emission source subject to

Section 215.211(c) shall not be required to submit a

compliance plan if redesignation occurs after December

31, 1986.

e+

11.

The plan and schedule shall meet the requirements of 35

Ill. Adm. Code 201. ~ Sth~af~H ed~~ spee~f4e

~er~m ~a~es as ee~e~ ~ 35 ~ ~m eode ~

(Source:

Amended at

9

Ill. Reg,

____,

effective

________,

1985)

SUBPART K:

USE OF ORGANIC MATERIAL

Section

215.305 Viscose Exemption (Repealed)

The

ev4s4erts of St~tbpaf~H sha~h

rte~ ap~y ‘ee the m~fae~re

0?

~egenei~a~e~ee~e~e eas~q t~s4~geathon ~t~f~e ~rt the

~4seeee

pfeeess

(Source:

Repealed at

9 Ill. Req.

_____ ,

effect.ive

1985)

SUBPART

Q:

SYNTHETIC ORGANIC CHEMICAL

AND

POLYMER MANUFACTURING

Section 215.420 General Requirements

The owner or operator of ~plant

which has more than 1,500

components in gas

or

light

LLtquid

service, which components are

used

to manufacture

the~yntthetic

organic chemicals or polymers

listed in

Appendix D~ shall conduct leak

inspection and repair

pro~ramsinaccordarv:a with this Subpart for that equipment

containing more than~jercent volatile organic material as

determined by ASTMsac~hod E-20, E—168,and E--169. A Component

84-193

---

—18—

shall be considered to be leaking if the volatile organic

material concentrat:Lon exceeds 10,000 ppm when measured at a

distance of 0 cm from the component.

The provisions of this Subpart are not applicable

if

the products

listed in Appendix 0

are

made from natural fatty acids for the.

production of

hex ~ec1alcoho1,

(Source: Added at 9 111. Reg.

effective

Section 215.421 Inspection Program Plan for Leaks

1985)

The owner or op~.~~crof a synthetic organic chemical

manufacturing pthth subject to Section 215.420 shall

or polymer

prepare an

inspection prog i: lan which contains, at a minimum:

a) An iden~~cationof all components arid the period in

which e~~-iiil be monitored pursuant to Section

215. 422

~j The forr~.::.. .~or the monitoring log required by Section

215,423;

A

descrip~onof the monitoring equipment to be used

pursuant ~:cSection 215.422; and

ii.

A description of the methods to be used to identify all

pipeline valves, pressure relief valves in gaseous

service, all leaking components, and the ball and plug

valves and pumps exempted under Section 215.422(h) such

that they are obvious to both plant personnel performing

monitoring

and Agency personnel performing inspections.

(Source: Added at ~ IlL

Reg.

_____,

effective

_________,

1985)

Section 215.422 In;~pectionProgram for Leaks

The owner or oper~.to~

of

a

synthetic organic ct~emical or polymer

manufacturing plant subject to Section 215.420 shall, for the

~urpàsès

of detect~ijJ~eaks,conduct a component inspection

program

consistent with the following provisions.

a) Test annually those components operated near extreme

temperaturec.r pressure, and those components located

more than twc. meters above or away from permanent worker

access structures or surfaces by methods and procedures

di~nc;

b)

Test

all other

pressure relief valves in gaseous

service-

~

compressor seals by methods and procedures approved by

the Aqeu-’;v not earlier ‘than March 1 or later than June 1

64-194

---

—19—

~gJ

If more than 2 percent of the components tested pursuant

to subsection (b) are found to leak, again test all

pressure relief valves in gaseous service, pipeline

valves in gaseous service and compressor seals by

methods and procedures approved by the Agency not

earlier than June 1 or later than September 1 of each

year

d) Observe visually all pump seals

weekly

e) Test immed.~’.~1any pump seal from which liquids are

observed ~

f) ~

ril~:efvalve within 24 hours after it has

vented to

~

atmosphere; and

~j Test immediu~elyafter repair any component that was

found leakin~

h) Ball and plug valves, inaccessible valves, storage tank

valves, pumps equipped with mechanical seals, pressure

relief devices connected to an operating flare header or

vapor recovery device are exempt from the monitoring

requirements in this Section,

(Source: Added at

9

Ill. Reg.

____,

effective

,

1985)

Section 215.423 Repairing Leaks

~1l

leaking

components must be repaired and retested as soon as

possible, but no later than

21

day~afterthe leak is found

unless the 1eakingcom~nent cannot he repaired until the process

unit is shutdown or the repair part is

received.

Records of

repairing and retesting must be maintained in accordance with

Sections 215.424 and

215,425.

(Source:

Added

at 9 Ill, Reg.

,

effect:Lve

_________,

1985)

Section 215.424 Recordkeeping for Leaks

a) The owner or operator of a synthetic organic chemical

or

polymer manufacturing plant shall maintain a leaking

components monitoring log which shall contain, at a

minimum, the following information:

1) The name of the rocess unit where the component is

located

2)

The type of component (e.g.,

valve, seal)

3)

The .ntification number of

the component

64-195

---

—20—

4) The date on which a leaking

component is

discovered

5) The date on which a leakin

conent is repaired

6) The date and instrument reading of the recheck

—

procedure after a leaking

component

is repaired

7)

A record

of

the calibration of

the

monitoring

instrument

8) The identificatior~number

of

:tething components

which cannot be repaired until process unit

shutdown; and

9)

The total number of components inspected

and the

total number of components

found

1~aking

during

that monitoring period.

b)

Copies of the monitoring log shall

be retained by the

owner or operator for a minimum of two years after the

date on which the record was made or the report

prepared.

C) Copies of the monitoring loq shall be made available to

—

the Agency, upon verbal or written request, at any

reasonable time,

(Source: Added

at 9 111. Reg~

~ effective

,

1985)

Section

215.425 Report for Leaks

The owner or

operator

of ~_~y~itheticorganic

chemical or polymer

manufacturing plant shall:

a)

Submit a

repo~ttotheA~j~cypji9r

to the 1st day of

~

all 1eakin9

components ithntified

pursuant

to Section 215.422 but

not repaired within 21 da~~all iea~irig components

awaiting process unit shutdown, the total number of

~

and the

total

number of components

found leaking

b) Submit

a si9ned

statement with the r~ortattesting that

all monitor:, and repairs were

performed as required

under

Sections 213, ~2O throuqh 215,426,

(Source: Added at 9 Ill. Reg.

____ ,

effective

,

,

1985)

---

—21—

Section 215.426 Alternative Program for Leaks

The

Agency may approve an alternative orogram of monitoring,

recordkeeping, and/or reporting to that prescribed in Sections

215.420 through 215.425, upon a demonstration by the owner or

operator

of such plant that the alternative program will provide

plant personnel and Agency personnel with sri equivalent ability

to

identify and repair leaking components. The owner or operator

utilizin~an alta::nat ye monftorin9 prog~m shall submit

to the

Agency

an alterr~.ive monitoring program plan consistent with the

provisions of Se~~on 215.421.

(Source: Added

9 Ill. Reg

,

effective

,

,

1985)

Section 215.427 Compliance Dates and Geographical Areas

a) Except

SL

otherwise stated in subsection (b), every

owner

or operator of a synthetic organic chemical or

p~ymer manufacturing plant subject to Sections 215.420

through 215.426 shall comply with the standards and

limitations of those Sections beginning October 31,1985.

b) If a plant is not located in one

of the counties listed

below, the owner or operator of the plant shall comply

with the requirements of Sections 215.420 through

215.426 no later than December 31, 1987:

Bond

Madison

Clinton

McHenry

Cook

Monroe

Montgomery

DuPaqe

Franklin

G reerie

____

ackson

Saline

Jersey

Sariaamon

Johnson

St. Clair

Kane

Union

Lake

Will

Macouøin

Williamson

(Board note: The USEPA noted in its redesignation

iiiIemaking, that it will publish a rulemaking notice on

‘~4i11iamson County’s attainment status. (45 Fed. Reg.

21949, May 16, 1983). Should Williamson County be

~èdesignated as attainment prior to October 31, 1985, it

and the

counties

contiguous

to

it will

be considered

deleted from the above list,)

c) Notwithstanding subsection (b),

if any county is

redesiqn:~:.edas nonattainment by the USEPA at any time

~~eta

to the effective date of this Section, the

owner or .oerator

of a plant located in that county who

64-197

---

—22--

would otherwise by subject to the

compliance date in

subsection (b) shall comply with the requirements of

Sections 215,420 through 215~426within one year from

the date of redesignation but

in no

case later than

December 31, 1987.

(Source: Added at 9 Ill, Reg.

_____,

efc~::L~/e

_________,

1985)

Section

2l5~42d

Th~o1iance Plan

a) The own~ or operator of a synthetic organic chemical or

polymer ~anufacturing

plant sublect to

Section

215.427(a) or (b) shall submit to,~A~~pca

comp1~nca plan, no later

thanD~smber 31, 1985.

b) The

owner or ooerato~

t3ubject to Section

215.427(c) shall submit a compliance plan within 90 days

after the date of redesignation~

out in

no case later

than December 31, 1986,

c) The owner or o~~atorof a plant

suhiect to Section

215.427(c) shall not be required

to

submit a compliance

jfre~es;ignationi occurs

after December 31, 1986.

d) The plan and schedule shall meet the

:~equirements of 35

Ill. Mm. Code 201.

(Source: Amended at 9 Ill. Reg.

____,

effective

________,

1985)

31J6P~RT U:

COKF~

MANUFt~CTU~L

AND

BY—PRODUCT RECOVERI

Section 215.500 Exceptions

The ~provisions of Uubpart ~

shall not aPpl~Ltocoke by—product

recovery plant.

(Source: Added at. 9 ElI. Reg.

effecatta

_______

,

1985)

Section 215.510 Coke

B~Product Recover~’ ~iari

The

owner or oDerator of Q~ke hv—prodoct recovery plant shall

reduce

the uncon’nrDli.ed emissions of v at~.e

organic materials

~y!~~85ne2:cent

from the fot1~wino

cources,

as defined:

a) Tar dec;u~ter, which

is a

rectar: :~rvessel used to

se~ratc tar

and flushin~1u~n~meansof9ravity

64-198

---

—23—

b) ~ht oil

sump,

which receives wastewater from process

~ipment.from the light oil recovery portion of a coke

~y~product

recovery plant

C)

Light o:Ll condensor/separator, which is a device used to

—

condense

or separate light oil

from

which the non—

condensable constituents are vented; and

d) Tar condensate sump, which receives water condensate

stream~

from the tar recovery process equipment.

(Source:

Adde

9 Ill. Reg.

_____,

effective

1985)

Section 215.51

Coke

By—Product Recovery Plant Leaks

a)

The o~3er or

operator of

a coke by—product recovery

—

~Thnt shall conduct a visual inspection program designed

to detect,

identify,

and facilitate repair of leaks from

~~~?~ents in li9ht oil liquid service. Components

servicing coke oven gas lines, operating flare headers

~~vapor recovery devices (including pressure relief

~ices) are exempt from the inspection program.

b) In conducting such a program, the owner or operator of a

coke

by--product recovery plant shall:

1) Develo~and conduct a weekly inspection program

consistent with the provisions of Section 215.513.

2) ~

oil

Ii uid service and identify

each

component observed

.~urs~.taent.

with

the provisions of Section

lb

iLJ.

3) ~j~air the leakiq

monentsas soon as

o~~icab1e,but

no later than 22 days after the

leak ie discovered unless the leaking component

cannot re ~aoaired

until

the unit is shut down or

~1~rts

needed

to correct the leak are

avaibabin~

(Source:

Added at. 9 III. Reg.

-

,

effective

_________,

1985)

Section

215.513 ~sectionProj~am

The owner or operator shall prepare and conduct an inspection

program which, atanin

~rri,crial1

require

the owner

or operator

to:

a) Obser n. ~uaI? for

leaks

from all

components subject

to Sen.

~ 215,312

on a weekly basis

64-199

---

—24—

b)

~f~p1

leaking components so that they are obvious

—

to plant pa~:sonnel performing visual inspections and

Agencyj~nonne1 performing inspections; and

C)

Record itt monitoring log, the information for each

—

~nccomoonent as required by the provisions

of

Sections

2t3,3I4

(Source: Added at 9 III. Reg.

____,

effective

,

1985)

Section 215.3l4

~nordkeeping Requirements

a) The own ~ ~perator of a coke by—product recovery

—

plant ~

.a:Lnbain a monitoring log that shall

contain, •m:Lnimum, the following information for

each con:.:. found leaking:

1) The :.:of the process unit where the observed

1ea~-;n n~pon~tis

located;

2)

Ident.~catiori of

the type of component (e.g.,

valve

.

neal);

3)

The da~a on

which the leaking component is first

observed

4)

The

date

on which a leaking component is repaired

5)

Identification

of the type of leaking components

whi~b cannot

he repaired until

unit shutdown; and

6)

EderLtiUcatLon

of compQnent leaks which are not

reo.rL~dwithin 22 day~ after discovery because of

toe

nn~~cilab:Liityof

replacement parts, including

:~~n~ttta

repair part

was ordered and the date

the .ntar sart was

redeived.

b)

The mort.~t

!nqj~~ shall he retained by the owner or

oiniinum of two years after the date on

which thc nenord

was

made.

c)

~s~fnr~eaonitoring log shall be made available to

the Agency, coon verbal or written request at a

reasonable :ic~e~

(Source: Added

at 9 lii. Reg.

_____,

effective

,

1985)

Section 215.515 Reccrting Requirements

The owner

or oe;:~ ::nf

a coke by—product recovery plant shall

submit to

the 1~ç::: a siqned statement attesting that all

monitoring and nn:

.

al/crc performed as required under Section

64-200

---

—25—

215.512 prior

to at~

first

day of May and August of each year.

(Source: Added s~ 9 Ill. Reg.

_____,

effective

_________,

1985)

Section 215.516

Co~li~c~~!s

The owner or

opeianorcf

an emission source subject to:

a)

Section

2l.~bO

shall comply with that Section by

Decembe. :

~.,

1986;

~j Sectiorn~ 5~5~L2through 215.514 shall comply with those

Sectior:~ ~ ‘~Jecember 31, 1985

(Source:

Added

hil. Reg.

effective

1985)

Section

215.517

.ntpilance Plan

The

owner or oper

of a facility

or emission source subject to

this Subpart

shall

tctit to the

Agency, a compliance plan and

project completio: ~hedule

for:

a)

Section

~.

~l0

by August 31, 1986;

b)

Section 21.514 by October 31, 1985.

(Source: Added at

t

Ill.

Reg.

,

effective

,

1985)

64-201

---

—26—

APPENDIX D

LIST OF

CHEMICALS DEFINING SYNTHETIC

ORGANIC

CHEMICAL AND POLYMER

MANUFACTURING

OCPDB No.*

Chemical

OCPDB No. Chemical

20

Ac. Ii

270

Amyl chloride

30

A:n:taldehyde

280

Amyl mercaptans

40

Acen~nLdo1

290

Amyl phenol

50

Acetectide

300

Aniline

65

Ace :~nni1ide

310

Aniline

hydrochloride

70

Aoe~.

in acid

320

Anisidine

80

Ace

~

anhydride

330

Anisole

90

Ace.

~

340

Anthranilic acid

100

Ace : cc

cyanohydrin

350

Anthraguinone

110

Ac~.:.citrile

360

Benzaldehyde

120

Ace.cnhenone

370

Benzamide

125

Ace:~~.chloride

380

Benzene

130

Acant~.ene

390

Benzenedi—

sulfonic acid

140

Acrnlain

400

Benzene—

sulfonic acid

150

Acrylamide

410

Benzil

160

Acrylic acid

& esters

420

Benzilic acid

170

Acrylonitrile

430

Benzoic acid

180

Adipic acid

440

Benzoin

185

Adioonitrile

450

Bennzonitrile

190

Alkyl

naphthalenes

460

Benzophenone

200

A:Llvi alcohol

480

Benzotrjchloride

210

Allyl chloride

490

Benzoyl chloride

220

Aminoherizoic

acid

500

Benzyl alcohol

230

Aminoethylethanolamine

510

Benzyl amine

235

p—aminophenol

520

Benzyl benzoate

240

Amyl

acetates

530

Benzyl chloride

250

Amyl

alcohols

540

Benzyl

dichior ide

260

Amyl

amine

550

Biphenyl

*The OCPDB Numbere

are ref

erence indices assigned to the various

chemicals in the tnc~anic Chemical Producers Data Base developed

by the USEPA

64-202

---

—27--

OCPDB t~1o.

Chemical

OCPDB No.

Chemical

560

Bisphenol

A

905

Chlorobenzo—

trichloride

570

l3romobenzene

910

Chlorobenzoyl

chloride

580

Bromonaphthalene

920

Chlorodifluoro—

ethane

590

Bu~c~riiene

921

Chiorodifluoro—

methane

592

l~*’nene

930

Chloroform

600

n- ::n.ii~i. acetate

940

Chloronaph—

thalene

630

~

acrylate

950

o—chloronitro—

benzene

640

n-::n1il alcohol

951

p—chloronitro—

benzene

650

s ‘bat:’i alcohol

960

Chlorophenols

660

t--tc:7l alcohol

964

Chloroprene

670

n~hl:ni1ar~ine

965

Chlorosulfonic

acid

680

s—bu,.ylamine

970

m—chlorotoluene

690

t--butylamine

980

o—chlorotoluene

700

p—tert—hutyl benzoic

acid

990

p—chlorotoluene

710

l,3—but.ylene glycol

992

Chiorotrifluoro—

methane

750

ri—butyraldehyde

1000

m—cresol

760

Butyric

acid

1010

o—cresol

770

Butyric inhydride

1020

p—cresol

780

Butyronittile

1021

Mixed cresols

785

Caprolactam

1030

CresylIc acid

790

Carbon

disulfide

1040

Crotonaldehyde

800

Carbon tetrabromide

1050

Crontonic acid

810

Carbon tetrachloride

1060

Cumene

820

Cellulose

acetate

1070

Cumene

hydroperoxide

840

Chboroacetic

acid

1080

Cyanoacetic acid

850

m’chloroaniline

1090

Cyanogen

chloride

860

o-~chi.oroant1ine

1100

Cyanuric acid

870

p—chloroanil:ine

1110

Cyanuric

chloride

880

Chboroheazaldehyde

1120

Cyclohexane

890

Ct lo

rob en

zen e

1130

C y ci oh cx a no 1

900

Chlor•obenzoic

acid

1140

Cyclohexanone

64-203

---

—28—

OCPDB No.

1150

1160

1170

1180

1190

1200

1210

1215

1216

1220

1221

1240

1244

1250

1270

1280

1290

1300

1304

1305

1310

1320

1330

1340

1360

1420

1430

1440

1442

1444

1450

1460

Chemical

Cyclohexene

Cyclohexylamine

C yciooctad iene

Decanol

Diacetone alcohol

Diar,~enobenzoic acid

Dichl. roaniline

m—dichlorobenzene

o— di ch lo roben z e ne

p—di cli 10

roben zen e

Dichlorodifluoro—

methane

Dichloroethyi ether

1, 2--dichloroethane

(EDC)

Dichlorohydr in

Dichloropr opene

Dicyclohexylamine

Diethylamine

Diethylene glycol

Diethylene glycol

diethyl ether

Diethylene glycol

dimethyl ether

Diethylene

glycol

monohutyl ether

Diethylene glycol

monobutvl ether acetate

Diethylene glycol

monoethyl ether

Diethylene glycol

monoethyl ether acetate

Diethylene glycol

monoinethyl ether

Diethyl sulfate

Difluoroethane

Dfisobutylene

Diisodecyl phthalate

Diisooctyl phthalate

Dike

t ~ne

Dimethylamine

OCPDB No.

1470

1480

1490

1495

1500

1510

1520

1530

1540

1545

1550

1560

1570

1580

1590

1600

1610

1620

1630

1640

1650

1660

1661

1670

1680

1690

1700

1710

1720

1730

1740

1750

Chemical

N ,N—dimethyl—

aniline

N ,N—dimethyl

ether

N ,N—dimethyl-

formamide

Dimethyl-

hydrazine

Dimethyl sulfate

Dimethyl sulfide

Dimethyl

sulfoxide

Dimethyl

terephthalate

3, 5—dinitro—

benzoic acid

Dinitrophenol

Din! trotoluene

Dioxane

Dioxoiane

Diphenylamine

Diphenyl oxide

Di pheny1

thiourea

Dipropylene

glycol

Dodecene

Dodecylaniline

Dodecyiphenol

Epichlorohydr in

Ethanol

Ethanolamines

Ethyl acetate

El

acetoacetate

Ethyl acrylate

Ethylamine

Ethylbenzene

Ethyl bromide

Ethylcellulose

Ethyl chloride

Ethyl

chloroacetate

64-204

---

—29—

OCPDB No.

Chemical

OCPDB No.

Chemical

1760

Ethylcyanoacetate

2120

Glyoxal

1770

Ethy:Lene

2145

Hexachloro—

benzene

1780

Ethylene

carbonate

2150

Hexachloroethane

1790

Ethylene Chlorohydrin

2160

Hexadecyl

alcohol

1800

Ethvlenediamine

2165

Hexamethylene—

diamine

1810

E~t

lane dibromide

2170

Hexamethyiene

glycol

1830

t’~y1ene

glycol

2180

Hexarnethylene—

tetramine

1840

:t~.

‘lene qlycol

2190

Hydrogen cyanide

c acetate

1870

hylene glycol

2200 Hydroquinone

thyl ether

1890

E~.h:Lene glycol

~

:butyl

ether

2210

p—hydroxy—

benzoic acid

1900

H n

lerie glycol

rrnccbutyl

ether acetate

2240

Isoamylene

1910

EL

lene glycol

mc: cethyl

ether

2250

Isobutanol

1920

Ethylene glycol

rnonoethyl

ether acetate

2260

Isobutyl acetate

1930

Ethylene glycol

2261

Isobutylene

morioethyl ether

2270

Isobutyraldehyde

1940

Ethylene glycol

monomethyl ether acetate 2280 Isobutyric acid

1960

Ethylene glycol mono—

pheny. ether

1970

Et:hy:Lene

glycol

nionooropyl

ether

2300

Isodecanol

1980

Ethylene oxide

2320 Isooctyl alcohol

1990

Ethyl ether

2321 Isopentane

2000

2~-etby1hexano1

2330 Isophorone

2010

Ethyl orthoformate

2340 Isophthalic acid

2020

Ethi oxalate

2350 Isoprene

2030

Ethyl

eodium

oxcl~cetate

2360

Isopropanol

2040

Formaldehyde

2370

Isopropyl

acetate

2050

Formamic3e

2380

Isopropylamine

2060

Fornic

acid

2390

Isopropyl

chloride

2070

Fumaric

acid

2400

Isopropyiphenol

2073

Furfural

2410 Ketene

2090

Glycerol (Synthetic)

2414 Linear alkyl

sulfonate

2091

Glycerol dichlorohydrin

2417

Linear

alkyibenzene

2100

G3.’nerol triether

2420

Maleic acid

2110

51

inc

2430

Maleic anhydride

64-205

---

—30—

OCPDB

No.

Chemical

OCPDB No.

Chemical

2440

Malic acid

2756 o—nitroaniline

2450

Mesityl oxide

2757 p—nitroaniline

2455

Metanilic acid

2760 o—nitroaniaole

2460

Methacrylic acid

2762 p—nitroanisole

2490

Methallyl chloride

2770 Nitrobenzene

2500

Metheaol

acid (o, m & p)

2510

Me~t:.t acetate

2790 Nitroethane

2520

Net:c. 1 acetoacetate

2791 Nitromethane

2530

Metn-:lamine

2792 Nitrophenol

2540

n—nt~cisylaniline

2795 Nitropropane

2545

Met?’l bromide

2800 Nitrotoluene

2550

Met~ibutynol

2810 Nonene

2560

Metn.’l chloride

2820 Nonyl phenol

2570

Methyl cyclohexane

2830 Octyl phenol

2590

Methyl cyclohexanone

2840 Paraldehyde

2620

Methylene chloride

2850 Pentaerythritol

2630

Methylene dianiline

2851 n—pentane

2635

Methylene diphenyl

diisocyanate

2640

Methyl ethyl ketone

2644

Methyl formate

mercaptan

2650

Methyl isobutyl carbinol 2890 o—phenetidine

2660

Methyl isobutyl ketone

2900 p—phenetidine

2665

Methyl methacrylate

2910 Phenol

2670

Methyl pentynol

2690

a-methylatyrene

2700

Morpholine

2940 Phenylenediamine

2710

acid

2950 Phosgene

2720

acid

anhydr ide

2730

a—naphthol

2970 Phthalimide

2740

B—naphthol

2973 s—picoline

2750

Neopentanoic acid

2976 Piperazine

64-206

---

—31—

OCPDB No.

Chemzcal

OCPDB No.

Chemical

3000

Polybutenes

3290 & Tetrachloro—

3010

Polyethc7lene glycol

3291

ethanes

3025

Polypropylene glycol

3300

Tetrachloroph—

3063

Propionalclehyde

thalic anhydride

3066

Propionie acid

3310

Tetraethyllead

3070

n—propyi

alcohol

3320

Tetrahydro—

3075

Propylamine

naphthalene

3080

Propyl chloride

3330

Tetrahydrophtha—

lic anhydride

3090

Prcc~iene

3335

Tetramethyllead

3100

PrcT~.ene

chlorohydrin

3340

Tetramethylene—

3110

Pro~,

~ene

dichioride

diamine

3341

Tetramethyl—

3111

Pro~ i~neglycol

ethylenediamine

3349

Toluene

3120

Pro~ ene oxide

3350

Toluene—2,4—

diamine

3130

Pyri~ne

3354

Toluene—2,4—

diisocyariate

3140

Quincie

3355

Toluene diiso—

cyanates

3150

Resorcinol

(mixture)

3160

Resorcylic acid

3360

Toluene

sulfonamide

3170

Salicylic acid

3370

Toluene

sulfonic acids

3180

Sodium

acetate

3380

Toluene sulfonyl

chloride

3181

Sodium benzoate

3381

Toluidines

3390 3391

&

3190

Sodium carboxymethyl

3393

Trichlorobenzenes

cellulose

3395

l,l,1—trichloro—

ethane

3191

Sodium

chioroacetate

3400

1,1,2—trichioro—

ethane

3200

Sodium formate

3410

Trichioro—

ethylene

3210

Sodium

phenate

3411

Trichiorofluoro—

methane

3220

Sorbic

acid

3420

1,2,3—trichioro—

propane

3230

Styrene

3430

1,l,2—trichloro—

1,2, 2—tr if luoro—

3240

Succinic

acid

ethane

3450

Triethylamine

3250

Succinitrile

3460

Triethylene

3251

Sulfanilic acid

glycol

3260

Suifolane

3470

Triethylerie

3270

Tannic acid

glycol

3280

Terephthalic

acid

dimethyl ether

64-207

---

—32—

OCPDB No.

Chemical

3480

Triisobutylene

3490

Trirnethylamine

3510

Vinyl acetate

3520

Vinyl chloride

3530

Vinvlidene

chlor ide

3540

Vinyl toluena

3541

Xyiene (mixed)

3560

o—xy1a:’~e

3570

p—xylene

35F30

Xylenol

3590

Xyliäine

methyl tertbutyi. ether

Polyethylene

Polypropylene

Polystyrene

IT IS SO ORDERED

I, Dorothy

M.

Gunn, Clerk of the Illinois Pollution Control

Board, hereby certify that the above Proposed Order/Second

Notice was adopted on the

~

day of _______________________

1985, by a vote of

~—O

,

Dorothy M. G~inn, Clerk

Illinois Pollution Control Board