ILLINOIS POLLUTION CONTROL BOARD
    October
    29, 1987
    IN THE MATTER OF:
    PROPOSAL OF MOBIL OIL CORPORATION
    TO AMEND THE WATER POLLUTION
    )
    R84-l6
    REGULATIONS
    PROPOSED RULE.
    SECOND NOTICE.
    PROPOSED OPINION AND ORDER OF THE BOARD
    (by J. Marlin):
    This matter comes before the Board upon the May
    1,
    1984
    filing
    of a proposal
    by Mobil Oil Corporation
    (Mobil)
    requesting
    site—specific relief
    from the ammonia nitrogen effluent standard
    (35 Ill. Adm. Code 304.122(b)).
    Relief
    is also requested
    from
    the requirement that no effluent shall cause
    a violation of
    a
    water quality standard
    (Section 304.105)
    as
    it concerns the
    general use ammonia nitrogen water quality standard (WQS)
    (Section 302.212),
    the secondary ammonia nitrogen WQS
    (Section
    302.407),
    the general use dissolved oxygen
    (DO) WQS (Section
    302.206) and the secondary DO WQS
    (Section 302.405).
    Mobil
    discharges
    into the Des Plaines River.
    Hearing was held
    in Joliet, Will County,
    on July
    26,
    1984.
    On October
    30 and December
    13,
    1984,
    Mobil filed responses
    to the
    written inquiries
    of the Illinois Department
    of Energy and
    Natural Resources
    (DENR).
    The DENR concluded that an economic
    impact study was unnecessary and filed
    its negative declaration
    on February 22,
    1985.
    The Economic Technical Advisory Committee
    agreed with this finding, filing its concurrence on March
    12,
    1985.
    The last brief was filed
    on June
    4,
    1985.
    The Board by
    Interim Order dated September
    5,
    1985,
    requested that the
    participants address
    the question of whether
    the Board
    has
    authority
    to grant site—specific relief from 35
    Ill. Adm. Code
    304.105.
    On February
    4,
    1986,
    the Agency moved
    to file United
    States Environmental Protection Agency
    (tJSEPA)
    comments,
    and
    on
    February
    7,
    1986,
    Mobil filed
    its response
    to USEPA comments
    which contained amended proposed
    language.
    Both motions were
    granted by the Hearing Officer
    on February 24,
    1986.
    The Agency
    on March
    20 filed
    its response
    to Mobil’s
    response and modified
    proposal.
    On April
    10, 1986,
    Mobil moved
    for leave
    to file
    its
    reply to the Agency’s response
    to the modified proposal.
    That
    motion
    is granted.
    On July
    7,
    1986, Mobil
    filed
    a motion
    for
    leave
    to file Comment in Opposition
    to Applicability of Central
    Illinois Public Service Company
    v.
    PCB
    to this cause.
    In the
    Agency’s response,
    filed on July
    17,
    1986,
    the Agency did not
    object
    to Mobil’s motion.
    Mobil’s motion is granted.
    82—575

    2
    On
    February
    5,
    1987,
    the Board adopted
    a proposed rule
    for
    First Notice.
    This proposed rule was published
    in the Illinois
    Register
    on March
    13,
    1987.
    11
    Iii.
    Reg.
    4210.
    On April
    27,
    1987,
    Mobil
    filed
    comments cited
    herein as
    “P.C.
    #1”.
    On June
    5,
    1987,
    Mobil
    filed
    a supplement
    to
    its comments.
    The Agency filed
    its comments, cited herein as “P.C.
    #2”, on June
    7,
    1987.
    Although these latter two filings were filed subsequent
    to the
    closing of the 45—day comment period,
    the Board has accepted and
    fully considered
    these
    late
    filings.
    Mobil
    is currently operating under
    a variance from
    3
    mg/l
    ammonia nitrogen effluent standard of 35
    Ill. Adm. Code
    304.122(b)
    until July
    1,
    1988 or until
    final action
    is taken
    in
    this matter, whichever occurs first.
    Under this variance, the
    ammonia nitrogen concentration
    in Mobil’s discharge must not
    exceed
    a monthly average concentration of
    25 mg/i and
    a daily
    maximum of
    35 mg/l.
    Mobil
    Oil Company
    v.
    Illinois Environmental
    Protection Agency, PCB 86—45, slip Opinion and Order
    at
    4
    (August
    14,
    1986).
    Mobil has been granted
    five previous variances from
    the ammonia nitrogen standard:
    PCB 77—22, PCB 78—97,
    PCB
    80—54,
    PCB 82—36
    and PCB 84—37.
    Mobil has incorporated by reference the
    proceedings
    of the five variances in this regulatory proceeding.
    (R.
    114).
    Mobil
    owns and operates
    a conventional fuels petroleum
    refinery with
    a rated capacity of 180,000 barrels per day located
    in Joliet,
    in Will County.
    The refinery discharges
    2.74 million
    gallons of effluent per day.
    Stormwater, noncontact cooling
    water and process water
    are discharged from the facility into
    the
    Des Plaines River.
    The process water and contaminated surface
    runoff
    (1600 gpm)
    are treated
    in Mobil’s wastewater treatment
    plant (&~TP)which consists of an API
    separator,
    a dissolved air
    flotation unit, an equilization basin
    for primary treatment and
    a
    conventional activated sludge facility for secondary treatment.
    Treated effluent from the final clarifier is routed through
    a
    4.98 million gallon guard basin where
    it
    is retained
    for
    approximately
    51 hours and
    then aerated
    in the final aeration
    cone prior
    to release
    to the Des Plaines River.
    The effluent
    meets
    all discharge standards other
    than ammonia nitrogen.
    Mobil
    Oil Company, PCB 86—45 at 1—2.
    Mobil
    is requesting that its effluent limits for ammonia
    nitrogen be
    set at
    25 mg/l for
    a monthly average and 40 mg/i
    for
    a daily maximum.
    (Pet. Brief,
    p.
    3).
    In the past 13 years, Mobil has expended considerable
    time
    and effort in
    its attempt
    to reach ultimate compliance with the
    ammonia standards.
    The total cost of ammonia related capital
    expenditures
    is
    in excess of
    $2.1 million.
    The average annual
    operating cost
    for ammonia reduction projects during the last
    five years has been $1,801,000,
    including amortization of capital
    investments.
    Equalization system improvements and continuous
    dissolved oxygen monitoring
    in the aeration basins cost an
    82—576

    3
    additional $64,000 between
    1982 and 1985.
    Projects have included
    the purchase and installation of
    a nitrification pilot plant,
    nitrification inhibition studies, mutant bacteria trials,
    alkalinity addition and temperature control
    in the aeration
    basins.
    Since
    1973, these efforts have reduced Mobil’s
    discharged
    ammonia concentration by
    96 percent.
    Mobil Oil
    Company, PCB 86—45 at
    2.
    Mobil
    investigated
    six alternative nitrificatiori
    technologies.
    Three biological systems (activated sludge,
    trickling filter and rotating biological contactor) were rejected
    because of their
    inability to consistently achieve the ammonia
    nitrogen effluent standard
    of
    3 mg/i
    (R.
    97—8,
    See Pet.
    Exh.
    2,
    p.
    59, 60).
    Three chemical processes were also addressed.
    Breakpoint chlorination and ion exchange processes would
    consistently meet the
    3 mg/i standard
    (R.
    94—5).
    However,
    breakpoint chlorination was not recommended because of the
    formation and release of toxic chlorinated byproducts
    (R.
    94).
    The
    ion
    exchange
    process
    would
    entail
    a
    7—8
    million
    dollar
    capital
    cost
    with
    a
    $450,000
    annual
    operating
    cost,
    plus
    an
    added
    cost
    for
    activated
    carbon
    treatment
    if
    organic
    fouling
    occurred
    (R.
    95).
    The third chemical process, ammonia stripping, would
    not enable Mobil
    to reduce
    its effluent concentration enough to
    achieve the
    3 mg/i standard.
    In addition,
    it has relatively high
    capital and operating costs as well
    as potential operational
    problems.
    (R.
    96).
    After
    assessing
    the
    available
    control
    alternatives, an expert witness for Mobil
    concluded that absolute
    compliance with the
    3 mg/i standard could only be achieved by the
    ion
    exchange
    process.
    He
    stated
    that
    “fun
    the
    absence
    of
    a
    beneficial
    influence on receiving water quality,
    it
    is difficult
    to recommend the expenditure of several million dollars to
    achieve further reduction in effluent ammonia at the Joliet
    refinery.”
    (R.
    103).
    Environmental
    Impact
    Water quality standards for ammonia nitrogen and dissolved
    oxygen are being exceeded
    in the Des Plaines River
    at the point
    of Mobil’s discharge, river mile 278.
    (R.
    157—8).
    Mobil asserts,
    and the Agency agrees,
    that the condition of the river
    is
    primarily due
    to the discharges of three Metropolitan Sanitary
    District of Greater Chicago
    (MSDGC)
    sewage treatment plants
    located upstream of Mobil.
    (Pet.
    Brief, p.
    6—7;
    Ag. Brief,
    p.
    3).
    Based on an annual average, calculated from data taken from
    July,
    1982 through December
    31,
    1983, Mobil’s discharge
    constitutes 0.3 percent of the river’s total point source loading
    of ammonia nitrogen.
    (P.
    139).
    Th MSDGC sewage treatment plants
    discharges make
    up
    96 percent of the ammonia nitrogen loading.
    (Pet.
    Exh.
    #7,
    p.
    8).
    The Agency concurs with Mobil that Mobil’s current
    discharges
    of ammonia nitrogen have “no significant environmental
    impact.”
    The Agency states that “continued discharges by Mobil
    82—57 7

    4
    at its present rate and concentration
    will
    have
    no
    discernible
    effect upon the biota
    in the lower Des Plaines and upper Illinois
    Rivers.”
    (Ag. Brief,
    p.
    3).
    In addition,
    the nearest actual or proposed public water
    supply downstream of Mobil’s outfall
    is the City of Peoria which
    is 110 river miles
    away.
    Because of the distance and the
    relative amount of the discharge,
    a witness
    for Mobil stated that
    the ammonia nitrogen added
    by Mobil would have “appreciable time
    for degradation”
    by the time it reaches Peoria.
    (P.
    182).
    Economic Impact
    An expert witness for Mobil
    stated that
    if the lower Des
    Plaines and upper Illinois rivers improved greatly in quality
    such
    that
    it would become
    a combined sport and commercial
    fishery,
    its value would be $51,633 per mile per year.
    (R.
    187).
    If
    Mobil
    discharged
    3 MGD at
    40 mg/i
    into the river during
    a seven—day,
    ten—year low flow of 1186 MGD,
    the river’s
    concentration of ammonia nitrogen would
    rise by 0.101 mg/l near
    the discharge point.
    (P.
    145—6).
    The
    river
    would
    flow
    approximately 1.85 miles before returning
    to
    the original ammonia
    nitrogen
    concentration.
    (P.
    187—88).
    If
    it
    is
    assumed
    that
    a
    0.101 mg/i
    increase in ammonia nitrogen would completely destroy
    the value of the river’s potential
    in being
    a sport and
    commercial fishery (within that 1.85 mile stretch), the impact
    would
    equate to
    a loss of $95,521 per year.
    When figuring
    Mobil’s
    relative
    contribution
    to
    an
    overall
    1.6
    mg/i
    river
    concentration,
    the
    monetary
    loss
    directly
    attributable
    to
    Mobil
    would
    be $6,448 per year.
    (P.
    188)
    It was estimated that if
    Mobil
    is granted
    relief,
    it would
    save,
    at the minimum, $420,000
    per
    year.
    Based
    upon
    these
    assumptions, the ratio of Mobil’s
    savings
    to
    society’s
    cost
    would
    be
    65
    to
    1.
    (P.
    189—90).
    It
    is
    Mobil’s
    position
    that
    a
    treatment
    plant
    expansion,
    required
    to
    achieve compliance with the existing standard
    is not economically
    justified.
    (Pet.
    Brief,
    p.
    10).
    The
    Agency
    concurs
    with
    Mobil
    that
    “the
    ratio
    of
    likely
    cost
    expansion
    to
    likely
    beneficial
    impact
    would
    be
    extremely
    high,
    and
    thus
    economically
    unjustified.”
    (Ag.
    Brief,
    p.
    4).
    The
    Department
    of
    Energy
    &
    Natural
    Resources
    (DENR)
    concluded
    that
    the
    “cost
    of
    making
    a
    formal
    study
    is
    economically
    unreasonable
    in relation to the value of the study to the Board
    in determining
    the adverse economic impacts of the regulation.”
    (DENR Negative Declaration,
    p.
    2).
    Consequently,
    it issued
    a
    negative declaration
    in this matter.
    Ammonia Nitrogen Limitations
    Mobil
    requested that the Board
    set limitations of
    a
    25 mg/i
    monthly average and
    a
    40 mg/i daily maximum. These limitations
    were determined
    by evaluating
    the historical performance data of
    the WWTP.
    According
    to Mobil, these limits are necessary to
    82—578

    5
    account for fluctuations
    in the effluent concentrations.
    Studies
    indicate
    that the WWTP consistently removes
    a
    17 mg/i increment
    from the WWTP influent.
    Consequently,
    Mobil concludes that the
    effluent fluctuations are due
    to higher crude nitrogen and
    production levels.
    Due
    to these variations, Mobil states
    that
    the requested limitations are necessary to “insure consistent
    compliance.”
    (Pet.
    Reply,
    p.
    6).
    Pursuant
    to
    a Hearing Officer Order dated August
    13,
    1985 in
    this proceeding and the variance conditions of PCB 86—45, Mobil
    has submitted bi—monthiy reports which cover effluent data from
    January, 1983 to August,
    1987.
    The data from these bi—monthly
    reports can be summarized
    as follows:
    AMMONIA NITROGEN CONCENTRATIONS (MG/L)
    Yearly Avg.
    of
    Highest Monthly
    Highest Daily
    Year
    the Monthly Avg’s.
    Avg.
    Maximum
    1983
    4.35
    15
    27
    1984
    2.58
    8
    19
    1985
    3.33
    16
    25
    1986
    4.00
    11
    32
    19871
    1.89
    (8 month
    avg.)
    3.5
    13.1
    The Board recognizes that
    in 1973
    Mobil’s
    monthly
    discharge
    averaged 77 mg/i
    and that
    in 1979 and 1980,
    it
    averaged
    13
    and
    17
    mg/i respectively.
    Mobil Oil Company, PCB 86—45
    at
    2.
    However,
    data from the past
    4 2/3 years indicates that Mobil’s actual
    performance level, when calculating an annual
    average, of the
    monthly figures,
    is quite close to the
    3 mg/i standard.
    The Board finds that
    if Mobil
    is granted relief,
    the
    resulting environmental and economic impact would
    be minimal.
    Considering the available alternatives for Mobil,
    compliance with
    the
    3 mg/l standard, although technically feasible, would
    be
    economically unreasonable given Mobil’s current performance
    levels.
    Consequently, the Board will grant Mobil relief from
    Section 304.122(b).
    The Agency is concerned that if the Board grants Mobil the
    limits that it is requesting, Mobil may relax its present control
    1*
    The values
    for 1987 are derived from data concerning Mobil’s
    discharges during the period from January,
    1987
    to August,
    1987.
    This data was filed by Mobil on September 17 as
    a
    part of its Bi—monthiy Progress Report.*
    82—579

    6
    methods thereby increasing
    the ammonia nitrogen concentration
    in
    its discharge.
    The Agency proposed
    a
    10 mg/i monthly average,
    a
    30 mg/i daily maximum,
    and
    a
    5 mg/i annual
    average.
    The Board
    shares
    the Agency’s concern in light of the
    fact that limits
    requested by Mobil are considerably higher
    (sometimes by
    a factor
    of two)
    than its actual discharge.
    As
    a result, the Board proposed
    for First Notice that
    Mobil’s discharge not exceed the following limitations:
    monthly
    average,
    20 mg/i;
    daily composite,
    35 mg/i;
    and and yearly
    average,
    8 mg/i.
    The daily composite limit was set
    to allow
    Mobil the day to day fluctuations of effluent concentrations that
    it periodically experiences.
    The monthly average limit was set
    to account for the
    impact that these daily fluctuations have upon
    a monthly average calculation.
    The yearly average of
    8
    ing/l was
    set
    to allow for considerable deviation from current performance
    due to anticipated problems and varying feedstocks without
    allowing Mobil
    to significantly decrease its control efforts.
    Even after
    recognizing the fact that Mobil
    experiences periodic
    losses of nitrification, the Board viewed Mobil’s current
    performance levels
    as
    falling within the proposed effluent
    limits.
    However,
    in its first Notice comments, Mobil disagrees.
    Mobil first claims that the Board
    is without authority to
    impose
    an annual average.
    Secondly, Mobil asserts that the
    annual average imposed by the Board
    is unsupported by the
    record.
    The Board will address this second argument first.
    Mobil claims that the Board imposed the annual average only
    because the Board was concerned that
    if Mobil was granted relief
    it might relax
    its treatment efforts
    in the future.
    (P.C.
    #1,
    p.
    5).
    Mobil
    is partially correct.
    The Board fashioned relief with
    a monthly
    average,
    daily maximum, and yearly average
    so as to
    keep Mobil’s discharge
    as close
    as possible
    to the
    3 mg/i
    value.
    Also,
    the combination of these three limits would allow
    for some variability
    in the discharge due to periodic losses
    of
    nitrification.
    The Board viewed
    the annual average limit as
    providing added
    incentive for Mobil
    to work
    to keep its discharge
    concentrations low.
    As stated above,
    the ammonia concentrations
    of Mobil’s discharges,
    for the years
    1983 through August 1987,
    were at levels significantly lower than the 35/40 level, which
    Mobil has
    requested.
    It naturally follows, then, that
    if Mobil was granted
    relief
    as
    it has requested,
    it could discharge effluents with
    significantly greater concentrations of ammonia than
    it has
    discharged during the past
    4 2/3 years.
    By taking this position,
    the Board
    is not suggesting
    that Mobil would deliberately seek to
    decrease its ammonia control efforts, but rather without the
    annual average,
    there would
    be no legal incentive for Mobil
    to
    keep the discharge at levels it has attained since 1983.
    82—580

    7
    In
    support
    of
    its
    position,
    Mobil
    points
    to
    a
    statement
    made
    at
    hearing
    by
    James
    Patterson,
    Ph.D.
    In
    its
    comment,
    Mobil
    quotes Patterson:
    As
    I
    testified,
    at
    the
    limits
    that
    I
    mentioned,
    35 daily and
    25
    monthly,
    there
    is
    a
    five
    percent
    probability
    that
    they
    would
    violate
    those standards based
    upon
    the
    1982—
    83 data.
    They would have
    to actually improve
    their
    performance
    in
    order
    to
    not
    violate
    those standards.
    (emphasis added)
    (P.
    104—5).
    It is important to note that this statement was made on July
    26, 1984 and was based solely on the effluent data of 1982 and
    1983.
    Mobil
    seems to ignore
    the performance levels attained by
    Mobil since
    1983.
    Mobil
    also quotes the Board’s Opinion from PCB
    86—45.
    Mobil
    has made admirable progress
    in reducing
    its
    nitrogen
    discharge,
    and
    there
    is
    no
    reason
    to believe
    it will
    lessen its control
    efforts
    during
    the
    period
    of
    this variance.
    (emphasis
    added)
    Mobil
    Oil
    Corporation
    v.
    EPA,
    PCB
    86—45,
    slip.
    op
    at
    3
    (August
    14,
    1986).
    The Board
    is at
    a loss
    to determine how this statement is
    inconsistent with the concerns the Board has expressed
    in this
    site—specific rulemaking.
    A variance proceeding deals with
    temporary relief and its corresponding impacts.
    A plan for
    ultimate compliance
    is also essential
    in such a proceeding.
    In
    a
    site—specific rulemaking,
    the issues are much more sweeping.
    The
    Board must determine whether permanent relief from
    a requirement
    is justified.
    Therefore,
    the Board must consider the far
    reaching consequences that are incidental
    to permanent relief.
    In general, the Board does not believe that
    the deliberations in
    a site—specific rulemaking are necessarily bound by
    determinations
    made
    in
    an
    earlier
    variance
    proceeding.
    In
    particular, even if the Board viewed
    the quoted statement as
    controlling,
    it would
    still not contravene the Board’s present
    concerns.
    The statement
    is qualified by the phrase “during the
    variance period.”
    That is,
    the statement would not preclude the
    Board from considering
    in
    this rulemaking,
    situations which could
    arise subsequent
    to the variance period.
    Mobil’s statistical argument for dropping the annual average
    is much more convincing.
    As Exhibit B to its Comments, Mobil has
    submitted
    a report written by James Patterson entitled
    “Evaluation of
    Proposed Ammonia Discharge Limitations
    (PCB P84—
    16)”.
    In that report, Patterson critiques the effluent limits
    proposed by the Board at First Notice.
    82—581

    B
    Patterson concludes that the use of
    a daily maximum plus
    a
    monthly average
    limit is sufficient to describe the performance
    level
    of
    a treatment facility.
    He also asserts that the
    additional imposition of an annual average limit
    is “redundant
    if
    internally consistent with the statistical profile
    of
    performance
    ,
    and could
    render one or more of
    the other limits
    moot if
    the
    annual average
    is
    internally inconsistent.”
    Specifically, Patterson claims that the annual average
    of
    8 mg/i,
    as proposed by the Board
    at First Notice,
    is “statistically
    inappropriate” when considering Mobil’s operations during
    the
    period from 1982
    to
    1986.
    Based
    on such data,
    Patterson
    concludes that there
    is “an approximate 15 to
    20 percent
    possibility that the
    annual
    average
    limit would
    be exceeded in
    any one year.”
    (P.C.
    #1, Exh.
    B,
    p.
    27).
    Specific effluent limits can be correlated with percentile
    levels which characterize past performance levels.
    For example,
    a particular limit at the 50th percentile,
    for
    a given period,
    indicates that during that period half the values were below that
    limit
    and
    half
    the
    values
    exceeded
    that
    limit.
    (P.C.
    ~l,
    Exh.
    B,
    p.
    4).
    Based
    on data taken from January,
    1982 through June 1984,
    Patterson suggested,
    at hearing,
    a daily maximum of 35 mg/i.
    This limit equates to
    a 95th percentile level for that data
    base.
    That is,
    95 percent of the daily effluent concentrations,
    for the period
    from January 1982 through June 1984,
    fell at or
    below the
    35 mg/i level.
    (P.C.
    #1,
    Exh. B,
    p.
    1,
    13).
    The Board
    proposed
    this limit at First Notice.
    Patterson
    had
    also
    recommended,
    at
    hearing,
    a
    25
    mg/I
    monthly average,
    based on data from January 1982 through June
    1984.
    However, when that period is expanded to include data
    through December 1986, the
    95 percentile value
    is
    22 mg/i.
    The
    Board has proposed
    a 20 mg/i monthly standard, which according to
    Patterson,
    is equivalent to
    the 94th percentile value
    for that
    expanded data base.
    (P.C.
    fl, Exh.
    B,
    p. 10,
    15).
    Patterson
    has
    also
    figured
    the
    percentile
    level
    for
    an
    annual average limit of
    8 mg/i.
    The data base he has used
    in
    this calculation are the discharge levels from January,
    1982
    through December, 1986.
    However,
    instead of calculating an
    annual average according to the calendar year,
    Patterson has
    plotted 12 month rolling averages.
    Specifically,
    he has plotted
    seventeen 12—month averages with each subsequent 12—month period
    beginning
    3 months after
    the previous 12—month period.
    That is,
    the first period covers the time from January
    1,
    1982
    to December
    31,
    1982.
    The second 12—month period covers the time from April
    1,
    1982 through March
    31,
    1983.
    The procedure goes on until
    17,
    12—month periods are defined.
    From the plotting of these 12—
    month averages, Patterson has calculated that the
    8 mg/i annual
    average represents
    the 85th percentile
    for this data base.
    (P.C.
    #1,
    Exh. B,
    p.
    22).
    However,
    the Board notes that section
    82—582

    9
    304.104(b) (1) defines
    a monthly average as
    “numerical average of
    all daily composites taken during
    a calendar month.” (emphasis
    added).
    By analogy,
    the Board would expect the annual average to
    b~computed on the basis of
    a calendar
    year.
    Using these percentile figures,
    Patterson has made further
    calculations to demonstrate the feasibility of achieving the
    proposed limits
    under
    certain scenarios.
    Since
    the Board has the
    daily maximum at 35 mg/l, which according to Patterson is the 95
    percentile
    for performance, Patterson reasons that
    in one year,
    approximately 18 daily effluent values will exceed the
    35 mg/i
    level.
    Patterson claims that
    if those
    18 days occur all
    in one
    month,
    it would be impossible
    for Mobil
    to meet
    a monthly average
    of
    25 mg/i as well
    as an annual average of
    8 mg/I.
    If those
    18
    days of daily exceedances occurred in
    two months, at
    9 days for
    each month,
    Patterson concludes that Mobil could meet the monthly
    standard but that
    it would be impossible to achieve the annual
    average.
    (P.C.
    #1,
    Exh.
    B,
    p.
    20).
    Patterson
    also
    asserts
    that
    data
    show
    “that
    when
    higher
    ammonia discharge levels occur,
    they persist for several
    consecutive
    days.”
    In
    other
    words,
    when
    significantly
    higher
    ammonia
    concentrations
    appear
    in
    Mobil’s
    effluent,
    such
    concentrations tend
    to last.
    In light of this fact, combined
    with the analysis just discussed,
    Patterson concludes:
    For
    hypothetical
    but
    realistic
    situations
    wherein
    Mobil
    might
    meet
    the
    proposed daily
    maximum
    and
    monthly
    average
    limits,
    the
    imposition
    of
    the
    proposed
    annual
    average
    limit
    would
    result
    in
    circumstances
    ranges
    sic
    from
    an
    impossibility
    of
    compliance
    with the annual average,
    to having
    to achieve
    an annual average far
    less than that achieved
    in
    Mobil’s
    best
    year
    of
    record.
    (P.C.
    #1,
    Exh.
    B,
    p.
    28)
    Mobil,
    itself, characterizes Patterson’s study:
    More
    alarmingly,
    he
    Patterson
    forecast
    reasonable
    situations,
    based
    upon
    Mobil’s
    actual
    historical performance data, where
    the
    Joliet
    Refinery
    discharge
    would
    likely
    violate
    the
    proposed
    annual
    standard
    even
    though
    the
    treatment
    plant
    performed
    within
    the
    admittedly
    restrictive
    daily
    maximum/monthly
    average
    standards
    now
    being
    proposed
    by
    the
    Board.
    (Mobil’s
    emphasis)
    (P.C.
    #1,
    p.
    1172).
    82—583

    10
    Mobil
    is clearly taking
    the position that
    it would be
    difficult,
    if not impossible,
    to comply with an annual average
    limitation of
    8 mg/i.
    The Board
    is reluctant to impose
    a
    limitation on the proponent of
    a site—specific rulemaking when
    the proponent believes that compliance with the limit
    is not
    achievable.
    In light of this and the environmental impact at
    issue
    in this proceeding,
    the Board will delete
    the annual
    average
    limit
    of
    B
    mg/l
    from
    the
    proposed
    rule.
    Since
    the
    Board
    will
    not
    utilize
    an annual average limit,
    it
    is
    unnecessary
    to
    specifically
    answer
    Mobil’s
    arguments
    that
    the
    imposition of such
    a limit is beyond
    the Board’s authority.
    However,
    at this point,
    the Board believes that
    it does have the
    authority to impose an annual average effluent limitation.
    The
    annual
    average
    used
    in
    combination
    with
    the
    monthly
    and
    daily maximum limits,
    as previously proposed, would have
    effectively
    required
    a
    more
    stringent
    performance
    level
    when
    compared with what would
    have
    been
    required
    if only monthly and
    daily limits were set.
    This position is supported by Mobil’s own
    claim
    that situations could exist where Mobil
    could meet the
    monthly
    and
    daily
    limits
    and
    at
    the
    same
    time
    violate
    the
    annual
    average.
    With
    the
    removal
    of
    the
    annual
    average,
    Mobil
    will
    be
    able
    to
    discharge
    effluent
    at
    higher
    ammonia
    concentrations
    than
    what
    would
    have
    been
    allowed
    with
    the
    annual
    average.
    Because
    the
    new
    proposed
    rule
    has
    the
    effect
    of
    allowing
    Mobil
    to
    discharge
    more
    ammonia
    when
    compared
    to
    the
    previous
    proposal,
    the
    Board
    will
    include
    a
    sunset
    provision
    in
    this
    new
    proposal.
    In
    its First Notice Opinion the Board discussed the
    possibility of
    a
    sunset
    provision
    and
    concluded
    that
    a
    sunset
    was
    unnecessary.
    Finally,
    it
    is
    the
    Board’s
    position
    that
    the
    record
    supports
    the
    granting
    of
    permanent
    relief
    from
    the
    ammonia
    nitrogen
    effluent
    standard.
    In
    re
    Union
    Oil
    Company
    of
    California,
    P
    84—13,
    January
    8,
    1987,
    the
    Board
    also
    granted
    Union
    Oil
    relief
    from
    the
    ammonia
    nitrogen
    effluent
    standard
    with
    regard
    to
    its
    Lemont Refinery.
    However,
    the
    Board
    limited
    the
    relief
    to
    seven
    years.
    Such
    a
    “sunset
    provision”,
    though,
    is
    not
    necessary
    in
    this
    matter.
    The
    data
    shows
    that
    Mobil,
    unlike
    Union,
    has
    largely
    been
    successful
    in
    reducing
    the
    concentration
    of
    ammonia
    nitrogen
    in
    its
    discharge.
    The
    Board
    notes
    that
    on
    an
    annual
    average
    Mobil’s
    discharge
    has
    been
    quite
    close
    to
    the
    3
    mg/i
    standard.
    This
    is
    true
    even
    in
    recent
    years
    when
    the
    nitrogen
    content
    of
    the
    oil
    feedstocks
    have
    been
    82—584

    11
    high.
    The
    Board
    fully
    expects
    Mobil
    to
    continue
    its
    high
    performance
    level
    concerning
    ammonia
    nitrogen
    concentrations.
    The
    Board,
    therefore,
    grants
    Mobil
    a
    permanent
    relief
    from
    Section
    304.122(b)
    within
    the
    conditions
    listed
    in
    the
    Order.
    (emphasis added).
    Opinion
    and
    Order,
    P84—16,
    slip.
    op.
    at
    7—B
    (February
    5,
    1987).
    Although
    the
    Board
    still
    expects
    Mobil
    to
    continue
    its
    high
    performance
    levels,
    without
    the
    annual
    average
    limit
    there
    is
    no
    legal
    requirement for Mobil
    to continue
    to produce an effluent
    whose
    annual
    average
    would
    be
    close
    to
    3
    mg/i.
    With
    only
    the
    monthly
    and
    daily
    limits,
    set
    at
    20
    and
    35
    mg/i
    respectively,
    Mobil
    is only legally required
    to produce an effluent to meet
    those standards.
    Consequently, Mobil will be allowed
    to
    discharge an effluent of such quality that
    a yearly average of
    the
    monthly
    averages
    could
    be
    as
    high
    as
    20
    mg/i.
    This
    is
    in
    great
    contrast
    to
    the
    yearly
    averages
    of
    the
    monthly
    averages
    for
    the years
    1983 through 1987 which are set forth
    on page
    5 of this
    Opinion.
    It
    is obvious that with monthly and daily limits set at
    20/35,
    Mobil
    will
    not
    be
    required
    to
    maintain the level
    of
    performance
    that
    it
    has
    achieved
    in
    the
    past
    4
    2/3
    years.
    Consequently,
    factors,
    which
    the Board relied upon at First
    Notice to omit
    a sunset, have changed such that the Board will
    now impose
    a sunset.
    As
    in Union, the Board will terminate this rule on December
    31,
    1993.
    The
    six
    years
    will
    allow
    time
    for
    improvement
    of
    the
    Des Plairies’ condition.
    As the Board noted
    in
    Union,
    upstream
    activities
    by
    the
    MSDGC
    might
    greatly
    enhance water quality.
    in
    re Union Oil Company, R84—13 slip.
    op. at 11
    (March
    19,
    1987).
    The
    Board
    may
    then
    be
    in
    a
    better
    position
    to
    accurately
    evaluate
    the environmental impact
    that
    would
    result
    from
    granting
    Mobil
    permanent
    relief.
    Also,
    the six years will give Mobil further
    time
    to
    monitor
    its
    effluent
    and
    perhaps
    discover
    a
    technically
    feasible and economically reasonable method
    for achieving the
    general
    3
    mg/i
    limitation.
    Mobil has asserted that an
    increase in the nitrogen content
    of the crude oil
    it refines correspondingly increases
    its
    effluent concentration.
    In particular,
    it claims that nitrogen
    content of the crudes have increased over the years.
    The crude
    oil
    nitrogen
    content
    at
    the
    Joliet
    refinery
    has
    gone
    from
    a
    low
    of about 680 parts
    per
    million
    (ppm)
    in
    1976
    to
    a high of about
    1450 ppm in 1984.
    In 1985,
    it dropped
    to
    a level
    of 1120 ppm.
    Mobil
    01.
    Company,
    PCB
    86—45
    at
    3.
    If Mobil finds
    in the future
    that
    it
    exceeds
    the
    standards
    on
    a regular basis,
    it can come
    before
    the
    Board
    under
    another
    docket
    to
    seek
    relief.
    However,
    even
    though
    in
    recent years Mobil’s crude feedstocks have had
    a
    high nitrogen content,
    its effluent has been within the limits
    set
    herein.
    82—585

    12
    Mobil will
    be required
    to monitor
    and report its effluent
    concentration.
    However, procedures
    for monitoring and reporting
    effluent concentrations, will also be set forth
    in
    the permit.
    Mobil will be required
    to report on an annual basis the nitrogen
    content of its feedstock.
    Water Quality Standard Relief
    Mobil has also requested relief
    from being liable for
    causing
    the violation of various water quality standards (WQS).
    In response
    to
    a US.
    Environmental Protection Agency
    (USEPA)
    Review Statement submitted by the Agency,
    Mobil modified its
    original proposed
    language addressing
    the water quality standards
    issue.
    Essentially, the modified language states that 35 Ill.
    Adrn.
    Code 304.105 will apply to Mobil with respect
    to general use
    and secondary contact WQS
    for ammonia nitrogen and dissolved
    oxygen,
    “unless
    such discharge does not cause or contribute
    significantly to the violation”
    of the WQS.
    (Mobil Response, p.
    1).
    Mobil’s discharge is located approximately 200 feet upstream
    of the 1—55 bridge.
    The river upstream of the bridge is
    classified
    as secondary contact, whereas downstream of the
    bridge,
    the river
    is considered general use.
    (P.
    125—26).
    Consequently, Mobil’s discharge may,
    in theory,
    impact upon both
    secondary
    contact
    and
    general
    use
    streams.
    The general use water quality standard for total ammonia
    nitrogen, given the river’s pH and temperature,
    is 1.5 mg/i
    (35
    Ill.
    Mm.
    Code
    302.212).
    The
    general
    use
    water
    quality
    standard
    for
    dissolved
    oxygen
    is
    6
    mg/i
    (35
    Ill.
    Adm.
    Code
    302.206).
    Mobil’s impact upon these standards
    is discussed in Petitioner’s
    Exhibit
    3,
    a report prepared by an expert witness for Mobil.
    The report shows that the general use standard for ammonia
    nitrogen
    is exceeded downstream of Mobil’s discharge.
    However,
    it
    is concluded that under worst case conditions
    (Mobil
    discharging
    3 MGD at 40 mg/i into the river
    flowing at a low
    level
    of 1,186 MGD), Mobil’s discharge would extend by only 1.85
    miles the reach of the river which did not meet the
    ammonia
    nitrogen
    standards.
    (Pet.
    Exh.
    ~3,
    p.
    16).
    Similarly,
    the dissolved oxygen standard
    is currently
    exceeded downstream of Mobil.
    However, under
    the same worst case
    conditions,
    Mobil’s discharge would extend by no more than one
    mile the reach of the river which did not meet the dissolved
    oxygen
    standard.
    (Id.
    at
    19).
    The
    secondary
    contact
    ammonia
    nitrogen
    standard
    is
    2.5
    mg/i
    for April through
    October,
    (35 Ill. Mm. Code 302.407).
    It is
    apparent from data reported
    in Petitioner’s Exhibit
    #3 that this
    standard
    is exceeded upstream of Mobil’s discharge.
    (Pet.
    Exh.
    #3,
    p.
    17).
    82—586

    13
    The
    secondary
    contact
    standard
    for
    dissolved
    oxygen
    is
    4
    mg/i
    (35 Ill.
    Adrn.
    Code 302.405).
    Data shows that this standard
    is exceeded
    in the river mile where Mobil discharges.
    (Pet.
    Exh.
    #3,
    p.
    18).
    Consequently,
    it
    is
    likely,
    given
    the
    upstream
    exceedances of the ammonia nitrogen standard,
    that
    the dissolved
    oxygen standard
    is also being violated upstream of Mobil’s
    discharge point.
    In
    the
    USEPA’s
    Review
    Statement,
    the
    USEPA
    stated
    that
    Mobil’s addition
    to the river
    is “insignificant” with respect to
    water quality violations.
    It concluded:
    Mobil
    should
    not
    be
    granted
    relief
    from
    Section
    304.105
    but
    should
    be
    required
    in
    their NPDES permit
    to,
    in addition
    to standard
    effluent
    monitoring,
    conduct
    upstream
    and
    downstream
    ammonia—N
    monitoring
    at
    representative
    sampling
    points
    to
    clearly
    ascertain whether
    or
    not they are responsible
    for
    water
    quality
    standards
    violations
    for
    ammonia—N.
    In
    its First Notice Opinion, the Board classified Mobil’s
    current impact on water quality as
    “de
    minimus”.
    In
    their
    First
    Notice comments, Mobil
    and
    the Agency both object
    to the Board’s
    deminimus characterization.
    Upon reconsideration, the Board
    finds
    the
    de
    ininimus
    language
    to
    be
    inappropriate
    and
    hereby
    rescinds
    it.
    In
    its
    First
    Notice
    comments,
    Mobil requests that the Board
    clarify when Section
    304.105
    would apply to Mobil’s discharge.
    (P.C.
    #1,
    p. 12—13).
    Evidently, Mobil
    is referring to
    its
    modified
    language
    that
    Section
    304.105 will not apply unless
    Mobil “causes or contributes significantly”
    to
    a WQS violation.
    The Agency suggests that the Board rule that “compliance with the
    proposed
    effluent
    limits
    shall
    be
    considered
    adequate
    compliance
    with
    the
    water
    quality
    standards
    for
    the
    purposes
    of
    Section
    304.105.”
    (P.C.
    #2,
    p.
    4). The Board disagrees with both
    positions.
    The Board first adopted the language of Section
    304.105 as
    Rule 402
    in 1972.
    In its adopting Opinion, the Board discussed
    the purpose behind
    the rule:
    402
    Violation
    of
    Water
    Quality
    Standards.
    The
    numerical
    effluent
    standards
    adopted
    today are intended
    as basic requirements that
    should
    be
    met
    everywhere
    as
    representing
    ordinary
    good
    practice
    in
    keeping
    potentially
    harmful
    materials
    out
    of
    the
    waters.
    In
    some
    cases,
    because
    of
    the
    low
    volume
    of
    the
    receiving
    stream
    or
    the
    large
    quantities
    of
    treated
    wasted
    discharged,
    meeting
    these
    82—587

    14
    standards may
    not suffice
    to
    assure
    that the
    stream complies
    with water
    quality standards
    set
    on
    the
    basis
    of
    what
    is
    necessary
    to
    support
    various
    water
    uses.
    In
    such
    cases,
    the
    very
    nature
    of
    water
    quality
    standards
    requires
    that
    additional
    measures
    be
    taken
    beyond
    those
    required
    by
    ordinary
    good
    practice
    to
    reduce
    further
    the
    discharge
    of
    contaminants
    to
    the
    stream.
    This would
    not
    be
    so
    if
    effluents
    were
    all
    required
    to
    be
    as
    clean
    as
    the
    receiving
    stream,
    but
    in
    recognition
    of
    economic
    hardship
    we
    have
    refrained
    from
    imposing
    such
    a
    requirement
    across
    the
    board.
    What
    additional
    measures
    are
    required
    can
    be
    determined
    only
    on
    the
    basis
    of more detailed consideration
    of each
    stream
    in
    accordance
    with
    the
    statutory
    requirement
    that different needs may dictate
    different
    standards.
    Rule
    402
    states
    the
    principle that discharges causing violations
    of the water quality standards are forbidden,
    as
    was
    the
    case
    under
    the
    earlier
    regulations,
    and
    states
    basic
    considerations
    for
    determining
    which
    of
    a
    number
    of
    contributors
    to
    an
    overloaded
    stream
    must
    take measures
    to abate
    the problem
    (emphasis
    added).
    In re:
    Effluent Criteria; Water Quality
    Standards Revisions; and Water Quality
    Standards
    Revisions
    for
    Intrastate
    Waters, P70—8;
    P71—14;
    R71—20,
    3 PCB
    401,
    405
    (January
    6,
    1972).
    The
    record
    indicates
    96
    percent
    of
    the
    ammonia
    loading
    in
    the
    Des
    Plaines
    is
    due
    to
    the discharges from MSDGC sewage
    treatment
    plants.
    Mobil,
    itself
    accounts
    for
    0.3
    percent
    of
    the
    point source loading.
    Therefore,
    the Des Plaines is
    a type of
    river expressly contemplated by the Board when it adopted Rule
    402.
    “In some cases,...because of large quantities of treated
    wastewater discharged, meeting these
    effluent
    standards may not
    suffice
    to assure that the stream complies with water quality
    standards....
    In such cases,
    as
    with this particular stretch of
    the Des Piaines
    the very nature of water quality standards
    requires that additional measures be taken....”
    These
    “additional measures” equate to the enforcement of Section
    304.105.
    The
    reasoning
    behind
    Section
    304.105
    is
    just
    as
    valid
    today
    as
    it
    was
    in
    1972
    when
    it
    was
    adopted
    as
    Rule
    402.
    In
    its
    1972
    Opinion,
    the Board clearly described two lines
    of defense
    in the protection of
    a
    stream’s water quality.
    The
    first line entails the regulation of effluents.
    The second line,
    which
    is just as important as the first,
    involves enforcement
    82—588

    15
    against
    a source that causes
    a violation of
    a water quality
    standard.
    In the
    instance
    at hand,
    Mobil
    has justified relief as
    to
    its effluent discharge.
    Due to technical, economic, and
    environmental consideration,
    the Board will alter Mobil’s
    effluent limits.
    However, Mobil has not justified
    to the Board
    the necessity for abandoning completely,
    or even partially, this
    second line of defense.
    In the record, much has been made about the relatively poor
    quality
    of
    the
    Des
    Plaines
    River.
    The
    implication
    is
    that
    the
    Board
    should grant Mobil
    some sort of relief from Section 304.105
    because the water quality standards are already being exceeded.
    However, the Board
    is not
    in the position
    to merely preserve the
    status quo when water quality standards are being violated
    in a
    river.
    The
    Board
    is
    to
    adopt
    regulations
    “to
    promote
    the
    purposes
    and
    provisions”
    of
    the
    Act.
    Ill.
    Rev.
    Stat.
    1985,
    ch.
    111
    1/2
    ,
    par.
    1013
    (a).
    One of the purposes of the Act
    is to
    “restore,
    maintain
    and
    enhance
    the
    purity
    of
    the
    waters
    of
    this
    State
    in order
    to protect health, welfare, property, and
    the
    quality of
    life and
    to assure that no contaminants are discharged
    into
    the waters
    of the State.”
    Ill.
    Rev.
    Stat.
    1985,
    ch.
    ill 1/2 ~
    par. 1011(b).
    The Board
    is not convinced that
    it would
    be furthering the
    purposes
    of
    the
    Act
    by
    insulating
    Mobil
    from
    an
    enforcement
    action
    when
    Mobil
    is
    contributing
    to
    a
    WQS
    violation.
    Secondly,
    any
    relief
    from
    Section
    304.105
    could
    be
    considered
    a de facto WQS revision.
    Although the Board has the
    authority to revise
    a
    WQS,
    federal
    law,
    under
    the
    Federal
    Water
    Protection Control Act, requires that certain criteria be met in
    the
    case
    of
    such
    a
    revision.
    The
    record
    does
    not
    contain
    the
    necessary information that would
    be required before the Board
    could
    consider
    a
    WQS
    change.
    Also,
    no
    numerical
    WQS
    alternative
    is proposed.
    Mobil
    is merely requesting that Section 304.105 not
    apply to Mobil as it would apply to all other sources.
    For all
    of the above reasons,
    the Board will deny that part
    of
    Mobil’s
    proposal
    which
    requests
    partial
    relief
    from
    Section
    304.105.
    Finally, the Board
    also believes that the instream
    monitoring,
    as proposed by the USEPA,
    is
    a requirement suitable
    for
    consideration
    by
    the
    Agency
    as
    a
    permit
    condition.
    ORDER
    The Board directs that Second Notice of the following
    proposed
    rule be submitted
    to the Joint Committee on
    Administrative Rules.
    82—589

    16
    TITLE
    35:
    ENVIRONMENTAL PROTECTION
    SUBTITLE
    C:
    WATER
    POLLUTION
    CHAPTER
    I:
    POLLUTION CONTROL BOARD
    PART 304
    EFFLUENT STANDARDS
    SUBPART B:
    SITE—SPECIFIC RULES AND
    EXCEPTIONS NOT OF GENERAL APPLICABILITY
    Section 304.214
    Mobil Oil Refinery Ammonia Discharge
    a)
    This Section applies
    to discharges from Mobil
    Oil
    Corporation’s Refinery, located near Joliet,
    into the
    Des Plaines River.
    b)
    The requirements of Section 304.122(b)
    shall not apply
    to the discharge.
    Instead
    Mobil’s
    discharge
    shall
    not
    exceed
    the
    following
    limitations:
    CONSTITUENT
    CONCENTRATION (mg/i)
    Ammonia Nitrogen
    Monthly Average
    20
    Daily Composite
    35
    C)
    Section 304.104(a)
    shall not apply to this Section.
    Monthly average and daily composites are as defined in
    Section 304.104(b).
    d)
    Mobil shall monitor
    the nitrogen concentration of
    its
    oil
    feedstocks and report on an annual basis such
    concentrations
    to
    the
    Agency.
    The
    report
    shall
    be
    filed
    with the Agency by January
    31 of each year.
    e)
    The provisions of this Section shall terminate on
    December
    31,
    1993.
    (Source:
    Added at
    11 Iii. Reg.
    effective
    IT
    IS SO ORDERED.
    82—590

    17
    I, Dorothy
    M. Gunn,
    Clerk of the
    Illinois Pollution Control
    Board, hereby certify that the above Proposed Opinion and Order
    was adopted on the
    ~?~day
    of
    ~
    ,
    1987,
    by
    a
    vote
    of
    7
    -
    0
    Dorothy
    M.
    unn,
    Clerk
    Illinois
    Pollution
    Control
    Board
    82—591

    Back to top