1. THIS FILING IS SUBMITTED ON RECYCLED PAPER
  1. Water Quality Standard
      1. Scenario 1:
      2. Scenario 2:
      3. CERTIFICATE OF SERVICE
      4. R02-19 Service ListAmmonia Nitrogen Standards

RECEIVED
CLERK’S
OFFICE
BEFORE THE ILLINUIStOLLUTION COINIROL BOARD
JUL
1 7
2002
IN
THE MATTER OF:
)
)
PROPOSED AMENDMENTS TO
)
AMMONIA
NITROGEN STANDARDS
35 III. Adm.
Code
)
R02-19
)
(Rulemaking
Water)
STATE OF ILLIriQIS
Pollution
Control Board
TO:
Illinois Enviromnental Protection Agency
1021
North Grand Avenue East
P.O. Box
19276
Springfield,
IL
62794-9276
Office ofthe Attorney General
Division Chief ofEnvironmental Enforcement
188 West Randolph Street
Chicago, IL
60610
See Attached Service List
Division ofLegal Counsel
Illinois Environmental Protection Agency
1021
North Grand Avenue East
P.O. Box
19276
Springfield, IL
62794-9276
PLEASE TAKE
NOTICE
today that I have filed with the Clerk of the Illinois
Pollution
Control Board
Public Comment of Michael Callahan
on Behalf of The Illinois
Assndationnf
Wastewater Agencies a copy of which is herewith served upon you.
Respectfully
submitted,
Dated:
July
17, 2002
Roy M. Harsch
Sheila H. Deely
GARDNER, CARTON & DOUGLAS
321
North Clark Street
-
Suite 3400
Chicago, Illinois
606 10-4795
(312) 644-3000
One of Attorneys for Petitioner0’
NOTICE
OF FILING
4~AC
THIS FILING IS SUBMITTED
ON RECYCLED PAPER

RECEIVED
CLERK’S
OFFICE
BEFORE THE
ILLINOIS POLLUTION CONTROL
BOARDJUL
1
7
2002
IN THE
MATTER OF:
)
STATE OF IWNOIS
)
Pollution
Control Board
PROPOSED AMENDMENTS TO
)
R 02-19
AMMONIA NITROGEN
STANDARDS
)
35
III.
Adm.
Code
)
)
PUBLIC COMMENT
OF MICHAEL
CALLAHAN
ON
BEHALF OF THE ILLINOIS ASSOCIATION OF WASTEWATER AGENCIES
On behalfof the Illinois Association of Wastewater Agencies (IAWA), I am hereby
providing comment on the First Opinion and Order of the Board in
the current ammonia nitrogen
rulemaking procedure, Docket R02-l9.
The IAWA appreciates the substantial
agreement of the
Board with
IAWA in both the interpretation of the USEPA
1999 Ammonia National Criteria
Document (NCD) and
the manner in which the NCD
should be applied to the water quality
standards of Illinois.
As the Board noted
in
its First
Opinion and Order, the IAWA advocates
the consideratinn
of the seasonal period of March through October as being the time during a ycarin which
the
waters of Illinois can be expected to contain early life stages of fish.
The presence of such early
life stages is recognized by the NCD
and accepted by IAWA as requiring addifiorrahprutectiuir
from ammonia beyond that required during the absence of such early life stages.
The overall
effect ofthis consideration of the seasonality of the proposed regulation is to effedively consider
the month ofMarch as
a warm season month as opposed to
its present considieratiorras awiriter
month.
This consideration extends seasonal protection from ammonia beyond that
existing
under the current regulation.
In its First Opinion and Order, the Board also recognized the
additional
fish early life stage ammonia protection advocated by IAWA through inciusicinof
Section 302.212(e) in the proposed regulation.
The intention of IAWA in
considering the

seasonal impact of ammonia was to
provide maximum cost beneficial protection
to
fish early life
stages.
Both the early life stage present period and
Section 302.2 12(e) were proposed with the
intention of providing this maximum potential protection.
The IAWA is grateful
for the Board’s
recognition and specific mention of this conservatism in the proposed regulation.
The JAWA continues to
support the repeal ofthe Effluent Modified Waters (BMW) as
proposed by the Board in its First Opinion
and Order.
The BMW concept was intended to be
a
procedure by which relief could be
extended to
the regulated community from extremely low
NPDES permit ammonia limits.
Regrettably, the contention which surrounded this concept
ultimately rendered it impractical.
The proposed standard should result in
few NPDBS permit
ammonia limits that are low enough to present attainability problems with existing technology.
The BMW concept is
therefore not needed with
the proposed regulation.
The Board has chosen to modify the original IAWA proposal in terms of the frequency of
sampling required to determine attainment with the chronic ammonia water quality standard.
Unfortunately, the modification made to the sampling requirements ofSection 302.212(c)(2)
by
the Board after Second
Hearing contains a mathematical conflict among the acute
standard, the
sub-chronic standard and the chronic standard.
Determination ofcompliance with the chronic
standard by one sampling within a thirty day period mathematically nullifies the acute
standard
and the sub-chronic standard.
The Illinois Environmental Protection Agency (Agency) requested that the 30 day
average chronic standard sampling procedure be structured as proposed by IAWA.
Questions
arose during Second Hearing regarding this issue.
It was the opinion of IAWA at the conclusion
of Second Hearing that the issue had been substantially addressed by discussion at that time
and

that the Agency would
provide additional input to the Board further explaining its request.
The
IAWA did not thus subsequently
comment further on the matter.
As the Board has noted
in the First Opinion and Order, this request was madebythe
Agency to facilitate determination of compliance with the chronic standard within the framework
of the existing ambient water quality monitoring program.
The Board
has correctly noted the
correlation between the four day
sub-chronic standard and
the 30 day
chronic standard as
specified in the NCD.
The NCD was based on thirty days ofcompliance with the chronic
standard in conjunction with the four day consecutive sampling requirement ofthe sub-chronic
standard considered within the 30 day chronic period.
The chronic sampling frequency requested by the Agency in the regulation proposed by
the IAWA indicated four samples
collected over
a period ofat least 30 days.
This
proposal
allowed for two important considerations.
First, any 30 day period was thus
proposed to be
evaluated by
at least four non-consecutive samples thereby addressing the chronic and sub-
chronic relationship as established
in the NCD.
Secondly,
such a sample regime would
allow the
Agency to use its
ambient water quality monitoring network
sampling frequency ofsix
weeks to
determine long term chronic compliance.
This original proposal by the Agency and
IAWA
allowed the latitude for both a concerted
30 day
sampling frequency surrounding a four day sub-
chronic sampling
event if non-compliance were suspected while also
allowing
a long term
evaluation ofchronic compliance which could be addressed by the existing ambient water
quality monitoring program frequency.
In effect, two
different chronic assessment potentials
were established by the sampling procedure contained in the original proposal.
Since the Board issued its First
Opinion and Order in this matter the IAWA lrarftxrther
discussed the chronic standard averaging period with
the Agency.
The IAWA now understands

the Agency intends
to provide comment to the Board with
which it will advocate an outright
adoption ofthe thirty day average sampling period as presented
in the NCD.
The
JAWA concurs
with and
endorses this
action.
This modification of the original IAWA proposal should address
the concerns expressed by the Board in
its First Opinion and
Order.
However, the IAWA wishes to
propose a modification to the concept of the thirty day
chronic averaging period as described by the NCD that may be particularly helpful in addressing
the issues which have been raised in
this rulemaking procedure.
Hopefully, this proposed
modification will both assure water quality protection and facilitate the compliance assessment
ofthe ammonia standard.
The chronic and sub-chronic
relationship are intertwined as the Board
has noted.
The underlying concept of the two
standards maintains that the chronic standard
provides
long term (30 day) protection from ammonia providing that
the sub-chronic standard is
the maximum allowable average
short term ammonia exposure during the chronic exposure
averaging period.
The accompanying worksheet entitled Attachment A indicates the
mathematical nature ofthe relationship between the allowable chronic and
sub-chronic
concentrations.
Effectively, as shown by Attachment A,
Scenario
1:
if the sub-chronic standard
is realized as a four consecutive day average (5.57 mg/I total ammonia), the remainder of the 26
days of the 30 day averaging period must be considerably less
than the allowable chronic
standard if the chronic standard were to be
considered independently from the sub-chronic
standard.
This difference
is indicated by comparison of the allowable 30 day chronic standardof
2.23
mg/I total
ammonia with
the allowable
26 day
average of 1.71
mg/I total ammonia.
The 30
day averaging of (1) a 26 day weighted component of 1.71
mg/I total ammonia and
(2) a 4
day
weighted component of 5.57 mg/I equal the allowable 30 day chronic standard of2.23
mg/l total
ammonia.

Conversely,
as the actual four day
exposure concentration decreases, the concentration of
the allowable 26 day
weighted component is allowed to increase and
yet maintain
overall
compliance with
the chronic standard.
This mathematical
effect is illustrated in
Attachment A,
Scenario 2.
If a four day sub-chronic exposure
averages 4.00 mg/I total
ammonia then the
allowable 26 day average becomes
1.95 mg/I total
ammonia.
The chronic value of 2.23 mg/I is,
however, conserved.
The mathematical relationship of4/30 and 26/30
is essential to the correlation of the
chronic and sub-chronic standard.
Attainment with
the sub-chronic standard during the chronic
averaging period is the component of the water quality standard established by the
1999 NCD
that Dr.
Sheehan indicated in his testimony provided additional ammonia protection beyond that
ofthe existing Illinois ammonia water quality
standard.
Consequently, the IAWA proposes that
the chronic water quality standard be determined by at least one
sample for each week of a
30
day chronic exposure assessment period in conjunction
with four consecutive days ofsampling
within
that chronic assessment period.
In determining the chronic attainment, the minimum of
four weekly samples are to be averaged with
the mean thus derived assigned a multiplier of
0.867 (i.e.
26/30).
The sub-chronic
four day average value is assigned a multiplier of0.133
(i.e.
4/30).
The weighted average thus determined must then comply with the chronic water quality
standard.
The IAWA suggests that the interaction of the chronic and sub-chronic standards
is not
optimally expressed by the original
format ofthe IAWA proposed regulation.
Therefore,
JAWA
proposes some wording changes
in the Board’s existing text and the addition of a fourth
paragraph to
Section
303.212(C) which
specifically defines the mathematical relationship ofthe
chronic and
sub-chronic standards.

The IAWA suggests the following language to modify the Board’s version ofSection
302.2 12(C)2:
The total ammonia nitrogen (in mg/I) must not exceed the chronic
standard (CS) except
in those waters in
which mixing
is allowed
pursuant to
Section 302.102 ofthis
part.
Attainment of the chronic
standard (CS) must be evaluated pursuant to
subsection (d) ofthis
Section by averaging at least four samples collected
at weekly
intervals or at other frequency distributions representative of a 30
day sampling period.
The sub-chronic standard, while defined as a function of the chronic standard,
is a third
independent concept
as presented in
the NCD.
Consequently, IAWA suggests the following
changes be
made to the Board’s modifications of Section 302.212(c)(3), whichsirengthenthis
autonomy ofthe sub-chronic standard:
Th
total ammonia nitrogen (in mg/l) must not
exceed the sub-chronic standard except in
those waters
in which mixing
is allowed pursuant to Section 302.102.
Attainment
ofthe
sub-chronic standard must be evaluated pursuant to subsection (d) of this Section-by
averaging daily sample results
collected over four (4) consecutive days.
As mentioned previously, the IAWA suggests adding an additional paragraph (Sedinri
302.2 12(c)(4) which specifically defines the relationship between the chronic and
sub-chronic
standard:
Attainment ofthe chronic and
sub-chronic standards
shall be determined by evaluating a
sub-chronic
exposure pursuant to subsection
(c) of this Section
in conjunction withiR
chronic exposure pursuant to subsection (b) of this Section.
Such an
evaluation shall
allocate an
averaging weight of 0.133 (4/30) to
the sub-chronic four day
mean and an
averaging weight of 0.867 (26/30) to the mean ofthe remaining days assessed in the 30
day chronic averaging
period.
The 30 day average thus determined shall not exceed the
chronic standard.
This proposed modification
to Section 302.2 12(c) does not alter the actual
mathematical
relationship ofthe chronic standard with the sub-chronic standard from that originally proposed
to the Board by IAWA and contained in the NCD.
Rather, this proposed modification

specifically elucidates the manner in which the two
standards are to
be jointly considered.
The
IAWA believes that this lack ofdefined association between the two standards was the basis of
the Board’s concern that led
to the Board’s modification of Section 302.212(c)(2).
With the exception of the chronic standard sampling frequency issue, the IAWA finds the
Board’s First
Opinion and Order to be
a very acceptable resolution ofthe ammonia water quality
issue
for Illinois.
The IAWA
is very appreciative ofthe Board’s consideration to date with this
proposed regulation and remains available at the Board’s request
for additional information or
comment.

Attachment A:
Mathematical
Interaction of the
Proposed
Chronic and Sub-Chronic Ammonia
Given:
Temperature 20C
pH:
7.8
Acute Standard:
12.1
mg/I
Chronic Standard:
2.23
mg/I

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Water Quality Standard
Sub Chronic Standard (2.23 mg/I) x 2.5
=
5.57
mg/I
Scenario
1:
With
4 days averaging the maximum sub chronic concentration of5.57 mg/l total
ammonia, the
remaining 26 days of a 30 day chronic averaging period must be of such a concentration that
compliance exists with the 30 day chronic standard of 2.23 mg/I.
(~days
x
5.57 mg/I)
+
(26 days x
(22.28
days mg/I
+
(26 days x
____
____
mg/I)) /30
=
2.23
mg/l
____
mg/l)
=
(2.23 mg/I x 30 days)
26 days x
____
mg/I
=
(66.90 days mg/I)
-
(22.28 days mg/I)
____
mg/l
=
(44.62 days mg/l) /26 days
____
mg/l
=
1.71
mg/I
The daily average ofthe remaining 26 days of the chronic averaging period
in this example must
be less than or equal to
1.71
mg/I to
achieve compliance with the chronic water qualitystandard
of 2.23 mg/I.

Scenario 2:
If the 4 day sub-chronic
concentration averages 4.00 mg/I, the remaining 26 days of the 30 day
chronic averaging period can increase relevant to
Scenario
I
with
chronic compliance
maintained.
((4 days x 4.00 mg/I)
+
(26 days
x
____
mg/fl) /30
=
2.23
mg/I
(16.00 days mg/l)
+
(26 days x
____
mg/l)
=
(2.23 mg/I) x
30 days
26 days x
____
mg/I
=
(66.90 days mg/I)
-
(16.00 days mg/I)
____
mg/i
=
(50.90 days mg/l) /26
days
____
mg/l
=
1.96 mg/I
The reduction
in the sub-chronic 4 day
value from 5.57 mg/l
to
4.00 mg/I allows for an increase
in the mean of the remaining days in the chronic averaging period from
1.71
mg/l
to
1.96 mg/l.
CH02/22 I 97277.1

CERTIFICATE
OF SERVICE
The undersigned certifies
that a copy of the foregoing Notice of Filing
-
Public
Comment of Michael
Callahan on
Behalf of
The Illinois Association of Wastewater
Agencies were filed by hand
delivery with the Clerk ofthe Illinois
Pollution Control Board and served
upon
the parties to whom said Notice is directed by
first class mail, postage prepaid, by depositing in the
U.S. Mail at 321 North Clark Street, Chicago, Illinois
on Wednesday, July
17,
2002.
~iIa
H.
Deely
/
C
HO 1/1223692 8

R02-19 Service
List
Ammonia Nitrogen
Standards
Mike Callahan
Bloomington Normal Water Reclamation District
P.O. Box 3307
Bloomington, IL
61702-3307
Larry Cox
Downers
Grove Sanitary District
2710
Curtiss Street
Downers
Grove, IL
60515
Dennis Duffield
Department ofPublic Works
921
B.
Washington Street
Joliet,
IL
60433
City of Joliet
Albert Ettinger
Environmental Law & Policy Center
35
E.
Wacker Drive
-
Suite
1300
Chicago, IL
60601
Lisa M.
Frede
Chemical Industry Council
9801
W.
Higgens Rd,
-
Suite 515
Rosemont, IL
60018
James
T.
Harrington
Ross
& Hardies
150 North Michigan Avenue
Suite 2500
Chicago, IL
60601
Katherine Hodge
Hodge Dwyer Zeman
3150 Roland Avenue
Springfield,
IL
62705
Dorothy Gunn
Clerk, Pollution
Control Board
100
West Randolph
-
Suite 11-500
Chicago, IL
60601
Richard Lanyon
Metropolitan Water Reclamation
District
100 East Erie
Chicago, IL
60611
Margaret P. Howard
Hedinger & Howard
1225
5. Sixth Street
Springfield,
IL
62703
Robert A. Messina
Illinois Environmental
215
East Adams Street
Springfield,
IL
62701
Regulatory Group
Tom Muth
Fox
Metro Water Reclamation District
682
State Route 31
Oswego, IL
60543
Irwin Polls
Metropolitan Water Reclamation District OfChicago
6001
West
Cicero, IL
60804
Marie Tipsord
Attorney, Pollution Control Board
100 West Randolph,
Suite 11-500
Chicago, IL
60601
Sanjay Sofat
Illinois Environmental Protection Agency
1021
North Grand Avenue East
Springfield,
IL
62794-9276
Tim Bachman
Urbana/Champaign Sanitary District
1100 E. University Avenue -P.O. Box
669
Urbana, IL
61803

R02-19 Service List
Ammonia Nitrogen Standards
Jim Daugherty
Thom Creek Basin
Sanitary District
700 West End Avenue
Chicago Heights,
IL
60417
Catherine
F. Glenn
Illinois Pollution Control Board
100W.
Randolph Street
Suite
11-500
Chicago, IL
60601
David Zenz
CTE Engineers
303
East Wacker Drive
-
#600
Chicago, IL
60601
Susan M.
Franzetti
Sonnenschein Natha & Rosenthal
8000 Sears Tower
Chicago, IL
60606
Deborah J. Williams
Illinois Environmental Protection
Agency
1021
N.
Grand Avenue East
P0 Box
19276
Springfield,
IL
62794-9276
Michael Zima
DeKaIb Sanitary District
P0 Box 624
DeKalb,IL
60115
CIIOI/12209948I

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