ILLINOIS POLLUTION CONTROL BOARD
    January
    7,
    1988
    IN THE MATTER OF:
    PROPOSAL OF MOBIL OIL CORPORATION
    TO AMEND THE WATER POLLUTION
    )
    R84-16
    REGULATIONS
    ADOPTED RULE.
    FINAL ORDER.
    OPINION AND ORDER OF THE BOARD
    (by
    J.
    Marlin):
    This matter comes before the Board upon the May 1,
    1984
    filing
    of
    a proposal by Mobil Oil Corporation
    (Mobil)
    requesting
    site—specific relief from the ammonia nitrogen effluent standard
    (35
    Ill. Adm. Code 304.122(b)).
    Relief
    is also requested
    from
    the requirement that no effluent shall cause
    a violation of
    a
    water quality standard
    (Section 304.105)
    as
    it
    concerns the
    general use ammonia nitrogen water quality standard
    (WOS)
    (Section 302.212), the secondary ammonia nitrogen WQS
    (Section
    302.407), the general use dissolved oxygen
    (DO) WQS
    (Section
    302.206)
    and the secondary DO WQS
    (Section 302.405).
    Mobil
    discharges
    into the Des Plaines River.
    Hearing was held
    in Joliet, Will County, on July 26, 1984.
    On October 30 and December
    13,
    1984, Mobil filed responses to
    the
    written inquiries of the Illinois Department of Energy and
    Natural Resources (DENR).
    The DENR concluded that an economic
    impact study was unnecessary and filed its negative declaration
    on February 22,
    1985.
    The Economic Technical Advisory Committee
    agreed with this finding, filing its concurrence on March
    12,
    1985.
    The last brief was filed on June
    4,
    1985.
    The Board by
    Interim Order dated September
    5,
    1985, requested that the
    participants address the question of whether the Board has
    authority to grant site—specific relief
    from
    35
    Ill. Mm. Code
    304.105.
    On February
    4,
    1986,
    the Agency moved
    to file United
    States
    Environmental Protection Agency
    (USEPA) comments, and on
    February
    7,
    1986,
    Mobil moved
    to file its response to USEPA
    comments.
    Mobil’s response contained a proposal
    to amend
    the
    language of the proposed rule.
    Both motions were granted by the
    Hearing Officer on February 24, 1986.
    The Agency on March
    20
    filed
    its response to Mobil’s response and modified proposal.
    On
    April
    10,
    1986, Mobil moved
    for leave to file its reply to the
    Agency’s response to the modified proposal.
    That motion was
    granted.
    On July 7,
    1986,
    Mobil
    filed
    a motion for leave to file
    Comment
    in Opposition
    to Applicability of Central
    Illinois
    Public
    Service Company
    v.
    PCB to this cause.
    In the Agency’s response,
    filed on July 17,
    1986,
    the Agency did not object to Mobil’s
    motion.
    Mobil’s motion was granted.
    85—103

    2
    On February
    5,
    1987,
    the Board adopted
    a proposed rule for
    First Notice.
    This proposed rule was published in the Illinois
    Register on March 13,
    1987.
    11
    111.
    Reg.
    4210.
    On April
    27,
    1987,
    Mobil
    filed comments cited herein as “P.C.
    #1”.
    On June
    5,
    1987,
    Mobil
    filed
    a supplement to its comments.
    The Agency filed
    its comments, cited herein as
    “P.C.
    #2”, on June
    7, 1987.
    Although these latter two filings were filed subsequent
    to the
    closing of
    the 45—day comment period, the Board accepted and
    fully considered these late filings.
    The Board adopted the proposed rule
    for Second Notice on
    October
    29,
    1987.
    In that version of the rule,
    the Board deleted
    the annual average effluent limitation, which was
    a part of the
    First Notice proposal, but added
    a provision stating
    that the
    effect
    of. the rule terminates on December 31,
    1993.
    On December
    22,
    1987,
    the Joint Committee on Administrative Rules
    (JCAR)
    filed
    its Certification of No Objection to Proposed Rulemaking
    for this matter.
    Today the Board will adopt,
    as final,
    substantively the same version of the rule that it adopted for
    Second Notice.
    Mobil
    is currently operating under
    a variance from
    3 mg/I
    ammonia nitrogen effluent standard of 35
    111. Adm. Code
    304.122(b)
    until July 1,
    1988 or until
    final action
    is taken
    in
    this matter, whichever occurs first.
    Under this variance, the
    ammonia nitrogen concentration in Mobil’s discharge must not
    exceed
    a monthly average concentration of 25 mg/l and
    a daily
    maximum of
    35 mg/l.
    Mobil Oil Company v.
    Illinois Environmental
    Protection Agency, PCB 86—45,
    slip Opinion and Order
    at
    4
    (August
    14,
    1986).
    Mobil has been granted five previous variances from
    the ammonia nitrogen standard:
    PCB 77—22,
    PCB 78—97, PCB 80—54,
    PCB 82—36
    and PCB 84—37.
    Mobil has incorporated by reference the
    proceedings of the five variances in this regulatory proceeding.
    (R.
    114).
    Mobil owns and operates
    a conventional
    fuels petroleum
    refinery with
    a rated capacity of 180,000 barrels per day located
    in Joliet,
    in Will County.
    The refinery discharges 2.74 million
    gallons of effluent per day.
    Stormwater, noncontact cooling
    water
    and process water are discharged from the facility into the
    Des Plaines River.
    The process water
    and contaminated surface
    runoff
    (1600
    gpm)
    are treated
    in Mobil’s wastewater treatment
    plant
    (WWTP) which consists of an API separator,
    a dissolved air
    flotation unit, an equilization basin
    for primary treatment and
    a
    conventional activated
    sludge facility for secondary treatment.
    Treated effluent from the final clarifier
    is routed through
    a
    4.98 million gallon guard basin where
    it
    is retained
    for
    approximately 51 hours and then aerated
    in the final
    aeration
    cone prior
    to release
    to the Des Plaines River.
    The effluent
    meets all discharge standards other than ammonia nitrogen.
    Mobil
    Oil Company, PCB 86—45
    at 1—2.
    85—104

    3
    Mobil
    is requesting
    that its effluent limits
    for ammonia
    nitrogen be set at
    25 mg/l for
    a monthly average and 40 mg/l
    for
    a daily maximum.
    (Pet. Brief,
    p.
    3).
    In the past
    13 years, Mobil has expended considerable time
    and effort
    in its attempt
    to reach ultimate compliance with the
    ammonia standards.
    The total cost of ammonia related capital
    expenditures
    is
    in excess of $2.1 million.
    The average annual
    operating cost for ammonia reduction projects during the last
    five years has been $1,801,000, including amortization of capital
    investments.
    Equalization system improvements and continuous
    dissolved oxygen monitoring
    in the aeration basins cost an
    additional $64,000 between 1982 and 1985.
    Projects have included
    the purchase and installation of
    a nitrification pilot plant,
    nitrification inhibition studies, mutant bacteria trials,
    alkalinity addition and temperature control
    in the aeration
    basins.
    Since
    1973,
    these efforts have reduced Mobil’s
    discharged ammonia concentration by 96 percent.
    Mobil Oil
    Company,
    PCB 86—45 at
    2.
    Mobil investigated
    six alternative nitrification
    technologies.
    Three biological systems (activated sludge,
    trickling filter
    and rotating biological contactor) were rejected
    because of their inability to consistently achieve the ammonia
    nitrogen effluent standard
    of
    3 mg/l
    (R.
    97—8,
    See Pet.
    Exh.
    2,
    p.
    59,
    60).
    Three chemical processes were also addressed.
    Breakpoint chlorination and
    ion exchange processes would
    consistently meet the
    3 mg/l standard
    (R. 94—5).
    However,
    breakpoint chlorination was not recommended because of the
    formation and release of toxic chlorinated byproducts
    (R.
    94).
    The
    ion
    exchange
    process
    would
    entail
    a
    7—8
    million
    dollar
    capital
    cost
    with
    a
    $450,000
    annual
    operating
    cost,
    plus
    an
    added
    cost for activated carbon treatment
    if organic fouling occurred
    (R.
    95).
    The third chemical process, ammonia stripping, would
    not enable Mobil
    to reduce
    its effluent concentration enough
    to
    achieve the
    3 mg/l standard.
    In addition,
    it has relatively high
    capital and operating costs as well as potential operational
    problems.
    (R.
    96).
    After assessing the available control
    alternatives,
    an expert witness for Mobil concluded that absolute
    compliance with the 3 mg/l standard could only be achieved by the
    ion exchange process.
    He stated that “ijn
    the absence of a
    beneficial influence on receiving water quality,
    it
    is difficult
    to recommend the expenditure of several million dollars
    to
    achieve further reduction
    in effluent ammonia at the Joliet
    refinery.”
    (R.
    103).
    Environmental Impact
    Water quality standards for ammonia nitrogen and dissolved
    oxygen are being exceeded
    in the Des Plaines River
    at the point
    of Mobil’s discharge, river mile 278.
    (R.
    157—8).
    Mobil asserts,
    and the Agency agrees,
    that the condition of the river
    is
    primarily due
    to the discharges of three Metropolitan Sanitary
    85—105

    4
    District of Greater Chicago
    (MSDGC)
    sewage treatment plants
    located upstream of Mobil.
    (Pet. Brief,
    p.
    6—7; Ag. Brief,
    p.
    3).
    Based on an annual average,
    calculated from data taken frdm
    July,
    1982 through December 31,
    1983, Mobil’s discharge
    constitutes 0.3 percent of the river’s
    total point source loading
    of ammonia nitrogen.
    (R.
    139).
    Th MSDGC sewage treatment plants
    discharges make up 96 percent of the ammonia nitrogen loading.
    (Pet. Exh.
    #7,
    p.
    8).
    The Agency concurs with Mobil that Mobil’s current
    discharges of ammonia nitrogen have “no significant environmental
    impact.”
    The Agency states that “continued discharges by Mobil
    at its present rate and concentration will have no discernible
    effect upon the biota
    in the lower Des Plaines and upper
    Illinois
    Rivers.”
    (Ag. Brief,
    p.
    3).
    In addition, the nearest actual
    or proposed public water
    supply downstream of Mobil’s outfall
    is the City of Peoria which
    is 110
    river miles away.
    Because of the distance and the
    relative amount of the discharge,
    a witness
    for Mobil stated
    that
    the ammonia nitrogen added by Mobil would have “appreciable time
    for degradation” by the time
    it reaches Peoria.
    (R.
    182).
    Economic Impact
    An expert witness for Mobil
    stated that
    if the lower Des
    Plaines and upper Illinois rivers improved greatly in quality
    such that
    it would become a combined sport and commercial
    fishery,
    its value would be $51,633 per mile per year.
    (R.
    187).
    If Mobil discharged
    3 MGD at
    40 mg/l into the river during
    a seven—day,
    ten—year low flow of 1186 MGD,
    the river’s
    concentration of ammonia nitrogen would rise by 0.101 mg/l near
    the discharge point.
    (R.
    145—6).
    The river would flow
    approximately 1.85 miles before returning
    to the original ammonia
    nitrogen concentration.
    (R.
    187—88).
    If
    it
    is assumed that a
    0.101
    rng/l
    increase
    in ammonia nitrogen would completely destroy
    the value of the river’s potential
    in being
    a sport and
    commercial fishery (within that 1.85 mile stretch), the impact
    would equate to
    a loss of $95,521 per year.
    When figuring
    Mobil’s relative contribution to an overall 1.6 mg/l
    river
    concentration, the monetary loss directly attributable
    to Mobil
    would
    be $6,448 per year.
    (R.
    188)
    It was estimated that
    if
    Mobil
    is granted relief,
    it would save,
    at the minimum, $420,000
    per year.
    Based upon
    these assumptions, the ratio of Mobil’s
    savings to society’s cost would be
    65 to
    1.
    (R.
    189—90).
    It
    is
    Mobil’s position that a treatment plant expansion, required
    to
    achieve complIance with the existing standard
    is not economically
    justified.
    (Pet. Brief,
    p.
    10).
    The Agency concurs with Mobil
    that “the ratio of likely cost expansion to likely beneficial
    impact would be extremely high, and thus economically
    unjustified.”
    (Ag. Brief,
    p. 4).
    85—106

    5
    The Department of Energy & Natural Resources (DENR)
    concluded that the “cost of making
    a formal study is economically
    unreasonable
    in relation
    to the value of the study to the Board
    in determining the adverse economic impacts of the regulation.”
    (DENR Negative Declaration, p.
    2).
    Consequently,
    it issued
    a
    negative declaration
    in this matter.
    Ammonia Nitrogen Limitations
    Mobil
    requested that the Board
    set limitations of a
    25 mg/l
    monthly average and a 40 mg/l daily maximum.
    These limitations
    were determined by evaluating
    the historical performance data of
    the WWTP.
    According to Mobil,
    these limits are necessary to
    account for fluctuations
    in the effluent concentrations.
    Studies
    indicate that the WWTP consistently removes a 17 mg/l increment
    from the WWTP influent.
    Consequently, Mobil concludes that the
    effluent fluctuations are due
    to higher crude nitrogen and
    production levels.
    Due
    to these variations, Mobil states that
    the requested limitations are necessary to “insure consistent
    compliance.”
    (Pet.
    Reply, p.
    6).
    Pursuant to a Hearing Officer Order dated August
    13,
    1985
    in
    this proceeding
    and the variance conditions of PCB 86—45,
    Mobil
    has submitted bi—monthly reports which cover effluent data from
    January,
    1983 to August,
    1987.
    The data from these bi—monthly
    reports can be summarized
    as follows:
    AMMONIA NITROGEN CONCENTRATIONS
    (MG/L)
    Yearly Avg. of
    Highest Monthly
    Highest Daily
    Year
    the Monthly Avg’s.
    Avg.
    Maximum
    1983
    4.35
    15
    27
    1984
    2.58
    8
    19
    1985
    3.33
    16
    25
    1986
    4.00
    11
    32
    19871
    1.89
    (8 month
    avg.)
    3.5
    13.1
    The Board recognizes that
    in 1973 Mobil’s monthly discharge
    averaged 77 mg/I
    and that
    in 1979 and 1980,
    it averaged 13 and 17
    mg/l respectively.
    Mobil Oil Company, PCB 86—45 at
    2.
    However,
    1
    The values for 1987 are derived from data concerning Mobil’s
    discharges during the period from January,
    1987
    to August,
    1987.
    This data was filed by Mobil
    on September 17
    as
    a part of
    its Bi—monthly Progress Report.
    85—107

    6
    data from the past
    4 2/3 years indicates that Mobil’s actual
    performance
    level,
    when
    calculating
    an
    annual
    average,
    of
    the
    monthly
    figures,
    is
    quite
    close
    to the
    3
    mg/l
    standard.
    The Board finds that
    if Mobil
    is granted relief, the
    resulting environmental and economic impact would be minimal.
    Considering the available alternatives
    for Mobil, compliance with
    the
    3 mg/l standard, although technically feasible, would
    be
    economically unreasonable given Mobil’s current performance
    levels.
    Consequently,
    the Board will grant Mobil
    relief from
    Section 304.122(b).
    The Agency is concerned that
    if the Board grants Mobil
    the
    limits that it is requesting, Mobil may relax
    its present control
    methods thereby increasing
    the ammonia nitrogen concentration in
    its discharge.
    The Agency proposed
    a 10 mg/l monthly average,
    a
    30 mg/l daily maximum, and
    a
    5 mg/l annual average.
    The Board
    shares the Agency’s concern
    in light of the fact that limits
    requested by Mobil are considerably higher
    (sometimes by a factor
    of two)
    than its actual discharge.
    As
    a result,
    the Board proposed for First Notice that
    Mobil’s discharge not exceed
    the
    following limitations:
    monthly
    average,
    20 mg/l;
    daily composite,
    35 mg/l; and and yearly
    average,
    8 mg/l.
    The daily composite limit was set to allow
    Mobil
    the day to day fluctuations of effluent concentrations that
    it periodically experiences.
    The monthly average limit was set
    to account for the impact that these daily fluctuations have upon
    a monthly average calculation.
    The yearly average of
    8 mg/l was
    set to allow for considerable deviation from current performance
    due
    to anticipated problems and varying feedstocks without
    allowing Mobil
    to significantly decrease
    its control efforts.
    Even after recognizing the fact that Mobil experiences periodic
    losses of nitrification, the Board viewed Mobil’s current
    performance levels as falling within the proposed effluent
    limits.
    However,
    in
    its
    first Notice comments,
    Mobil disagrees.
    Mobil
    first claims that the Board
    is without authority to
    impose
    an annual average.
    Secondly, Mobil asserts that the
    annual average imposed by the Board
    is unsupported by the
    record.
    The Board will address this second argument first.
    Mobil claims that the Board imposed the annual average only
    because the Board was concerned that
    if Mobil was granted relief
    it might
    relax
    its treatment efforts in the future.
    (P.C.
    #1,
    p.
    5).
    Mobil
    is partially correct.
    The Board fashioned
    relief with
    a monthly average, daily maximum,
    and yearly average
    so as to
    keep Mobil’s discharge as close
    as possible to
    the
    3 mg/l
    value.
    Also,
    the combination of these
    three limits would allow
    for
    some variability
    in
    the discharge due
    to periodic losses of
    nitrification.
    The
    Board
    viewed
    the
    annual
    average
    limit
    as
    providing added
    incentive for Mobil
    to work to keep its discharge
    concentrations low.
    As stated above,
    the ammonia concentrations
    85—108

    7
    of Mobil’s discharges,
    for the years 1983 through August
    1987,
    were at levels significantly lower than the 35/40
    level, which
    Mobil has requested.
    It naturally follows, then,
    that
    if Mobil was granted relief
    as
    it has requested,
    it could discharge effluents with
    significantly greater concentrations of ammonia than
    it has
    discharged during
    the past
    4 2/3 years.
    By taking this position,
    the Board
    is not suggesting that Mobil would deliberately seek to
    decrease
    its ammonia control efforts, but rather without the
    annual average, there would
    be no legal incentive for Mobil
    to
    keep the discharge at levels
    it has attained since
    1983.
    In support of its position, Mobil points
    to
    a statement made
    at hearing by James Patterson,
    Ph.D.
    In its comment, Mobil
    quotes Patterson:
    As
    I
    testified,
    at
    the
    limits
    that
    I
    mentioned,
    35
    daily
    and 25
    monthly,
    there
    is
    a
    five
    percent
    probability
    that
    they
    would
    violate
    those
    standards based
    upon the
    1982—
    83 data.
    They would have
    to actually improve
    their
    performance
    in
    order
    to
    not
    violate
    those standards.
    (emphasis added)
    (R.
    104—5).
    It is important to note that this statement was made on July
    26,
    1984 and was based solely on the effluent data of 1982 and
    1983.
    Mobil
    seems to ignore
    the performance levels attained by
    Mobil
    since
    1983.
    Mobil
    also quotes the Board’s Opinion from PCB 86—45,
    a
    variance proceeding.
    Mobil has made admirable progress
    in reducing
    its
    nitrogen
    discharge,
    and
    there
    is
    no
    reason
    to believe
    it will lessen
    its control
    efforts
    during
    the period
    of
    this variance.
    (emphasis
    added)
    Mobil
    Oil
    Corporation
    v.
    EPA,
    PCB
    86—45,
    slip.
    op
    at
    3
    (August
    14,
    1986)
    The Board
    is at
    a loss
    to determine how this statement is
    inconsistent with the concerns the Board has expressed in this
    site—specific rulemaking.
    A variance proceeding deals with
    temporary relief
    and its corresponding
    impacts.
    A plan for
    ultimate compliance
    is also essential
    in such
    a proceeding.
    In
    a
    site—specific~rulemaking,
    the issues are much more sweeping.
    The
    Board must determine whether permanent relief from
    a requirement
    is justified.
    Therefore,
    the Board must consider the far
    reaching consequences that are incidental
    to permanent relief.
    In general,
    the Board does not believe that the deliberations
    in
    a site—specific rulemaking
    are necessarily bound
    by
    determinations made in an earlier variance proceeding.
    In
    85—109

    8
    particular, even
    if the Board viewed
    the quoted statement as
    controlling,
    it would
    still not contravene
    the Board’s present
    concerns.
    The statement is qualified by the phrase “during
    the
    variance period.”
    That is,
    the statement would not preclude the
    Board
    from considering
    in this rulemaking, situations which could
    arise subsequent to the variance period.
    Mobil’s statistical
    argument for dropping the annual average
    is much more convincing.
    As Exhibit B to
    its Comments, Mobil has
    submitted
    a report written by James Patterson entitled
    “Evaluation of Proposed Ammonia Discharge Limitations
    (PCB R84—
    16)”.
    In that report, Patterson critiques the effluent limits
    proposed by the Board at First Notice.
    Patterson concludes that the use of a daily maximum plus
    a
    monthly average limit
    is sufficient to describe the performance
    level
    of
    a treatment facility.
    He also asserts that the
    additional imposition of an annual
    average limit is “redundant
    if
    internally consistent with
    the statistical profile
    of
    performance,
    and could render one or more of the other limits
    moot if
    the
    annual average
    is
    internally inconsistent.”
    Specifically, Patterson claims that the annual
    average of
    8 mg/l,
    as proposed by the Board
    at
    First Notice,
    is “statistically
    inappropriate” when considering Mobil’s operations during the
    period from 1982 to 1986.
    Based
    on such data, Patterson
    concludes that there
    is “an approximate 15
    to 20 percent
    possibility that the
    annual
    average
    limit would be exceeded
    in
    any one year.”
    (P.C.
    #1, Exh.
    B,
    p.
    27).
    Specific effluent limits can be correlated with percentile
    levels which characterize past performance levels.
    For example,
    a particular limit at the 50th percentile,
    for
    a given period,
    indicates that during that period half the values were below that
    limit and half the values exceeded that limit.
    (P.C.
    #1, Exh.
    B,
    p. 4).
    Based
    on
    data
    taken
    from
    January,
    1982
    through
    June
    1984,
    Patterson suggested, at hearing,
    a daily maximum of 35 mg/l.
    This limit equates to
    a 95th percentile level
    for that data
    base.
    That
    is,
    95 percent of the daily effluent concentrations,
    for the period from January 1982 through June 1984,
    fell at or
    below the 35 mg/l level.
    (P.C.
    #1, Exh. B,
    p.
    1,
    13).
    The Board
    proposed this limit at First Notice.
    Patterson had also recommended, at hearing,
    a 25 mg/l
    monthly average, based
    on data from January 1982 through June
    1984.
    However, when that period
    is expanded
    to
    include data
    through December
    1986, the 95 percentile value
    is
    22 mg/I.
    The
    Board proposed
    a
    20 mg/l monthly standard, which according
    to
    Patterson,
    is equivalent to the 94th percentile value for that
    expanded data base.
    (P.C.
    #1,
    Exh.
    B,
    p.
    10, 15).
    85—110

    9
    Patterson
    has
    also
    figured
    the
    percentile
    level
    for
    an
    annual
    average
    limit
    of
    8
    mg/i.
    The
    data
    base
    he
    has
    used
    in
    this calculation includes the discharge levels from January,
    1982
    through December,
    1986.
    However,
    instead of calculating an
    annual average according
    to the calendar year, Patterson has
    plotted 12 month rolling averages.
    Specifically,
    he has plotted
    seventeen
    12—month averages with each subsequent 12—month period
    beginning
    3 months after the previous 12—month period.
    That is,
    the first period covers the time from January
    1,
    1982
    to December
    31,
    1982.
    The second 12—month period covers the time from April
    1,
    1982 through March 31,
    1983.
    The procedure goes on until
    17,
    12—month periods are defined.
    From the plotting of these 12—
    month averages, Patterson has calculated that the 8 mg/i annual
    average represents the 85th percentile
    for
    this data base.
    (P.C.
    #1,
    Exh.
    B,
    p.
    22).
    However, the Board notes that section
    304.104(b) (1) defines
    a monthly average as “numerical average of
    all daily composites taken during a calendar month.”
    (emphasis
    added).
    By analogy, the Board would expect the annual average
    to
    be
    computed
    on
    the
    basis
    of
    a
    calendar
    year.
    Using
    these percentile figures, Patterson has made further
    calculations
    to demonstrate
    the feasibility of achieving the
    proposed limits
    under certain scenarios.
    Since the Board set the
    daily maximum at 35 mg/i, which according
    to Patterson is the
    95
    percentile for performance, Patterson reasons that
    in one year,
    approximately 18 daily effluent values will
    exceed the 35 mg/i
    level.
    Patterson claims that
    if those
    18 days occur
    all
    in one
    month,
    it would
    be impossible
    for Mobil
    to meet a monthly average
    of 25 mg/i
    as well as an annual average of
    8 mg/i.
    If those
    18
    days of daily exceedances occurred
    in two months,
    at
    9 days
    for
    each month,
    Patterson concludes that Mobil could meet the monthly
    standard but that
    it would be impossible
    to achieve the annual
    average.
    (P.C.
    #1,
    Exh.
    B,
    p.
    20).
    Patterson also asserts that data show “that when higher
    ammonia discharge levels occur, they persist for several
    consecutive days.”
    In other words, when significantly higher
    ammonia concentrations appear
    in Mobil’s effluent, such
    concentrations tend
    to last.
    In light of this fact, combined
    with the analysis just discussed,
    Patterson concludes:
    For
    hypothetical
    but
    realistic
    situations
    wherein
    Mobil
    might meet
    the
    proposed daily
    maximum
    and
    monthly
    average
    limits,
    the
    imposition
    of
    the
    proposed
    annual
    average
    limit
    would
    result
    in
    circumstances
    ranges
    sic
    from
    an
    impossibility
    of
    compliance
    with the annual average,
    to
    having
    to achieve
    an annual average far less than that achieved
    in Mobil’s best year of record.
    (P.C.
    #1,
    Exh. B,
    p.
    28)
    85—111

    10
    Mobil,
    itself, characterizes Patterson’s study:
    More
    alarmingly,
    he
    Patterson
    forecast
    reasonable
    situations,
    based
    upon
    Mobil’s
    actual historical performance data, where the
    Joliet
    Refinery
    discharge
    would
    likely
    violate
    the
    proposed
    annual
    standard
    even
    though
    the
    treatment
    plant
    performed
    within
    the
    admittedly
    restrictive
    daily
    maximum/monthly
    average
    standards
    now
    being
    proposed by the Board.
    (Mobil’s emphasis)
    (P.C.
    #1,
    p.
    1172).
    Mobi.l
    is clearly taking the position that
    it would be
    difficult,
    if not impossible,
    to comply with an annual average
    limitation of
    B mg/i.
    In light of the above and the
    environmental impact at issue
    in this proceeding, the Board has
    deleted
    the annual average limit of 8 mg/l from the rule.
    Since
    the Board will not utilize an annual average limit,
    it
    is unnecessary to specifically answer Mobil’s arguments that the
    imposition of such a limit is beyond the Board’s authority.
    However, at this point,
    the Board believes that it does have the
    authority
    to
    impose
    an
    annual
    average effluent limitation.
    The
    annual
    average
    used in combination with the monthly and
    daily maximum limits, as previously proposed, would have
    effectively required
    a more stringent performance level when
    compared with what would have been required
    if only monthly and
    daily limits were set.
    This position is supported by Mobil’s own
    claim that situations could exist where Mobil could meet the
    monthly and daily limits and at the same time violate the annual
    average.
    With the removal of the annual average, Mobil will
    be
    able
    to discharge effluent at higher ammonia concentrations than
    what would have been allowed with the annual
    average.
    Because
    the new rule has the effect of allowing Mobil
    to discharge more
    ammonia when compared
    to the previous proposal, the Board will
    include
    a sunset provision in the rule.
    In its First Notice Opinion the Board discussed
    the
    possibility of
    a sunset provision and concluded that a sunset was
    unnecessary.
    Finally,
    it
    is the Board’s position that the
    record
    supports
    the
    granting
    of
    permanent
    relief
    from
    the
    ammonia
    nitrogen
    effluent
    standard.
    In
    re
    Union
    Oil
    Company
    of
    California,
    R
    84—13,
    January
    8,
    1987,
    the
    Board
    also
    granted
    Union
    Oil
    relief from the
    ammonia
    nitrogen
    effluent
    standard
    with
    regard
    to
    its
    Lemont
    Refinery.
    However,
    the
    Board
    limited
    the
    relief
    to
    seven
    years.
    85—112

    11
    Such
    a
    “sunset
    provision”,
    though,
    is
    not
    necessary
    in
    this
    matter.
    The
    data
    shows
    that
    Mobil,
    unlike
    Union,
    has
    largely
    been
    successful
    in
    reducing
    the
    concentration
    of
    ammonia
    nitrogen
    in
    its
    discharge.
    The
    Board notes that on an annual
    average
    Mobil’s
    discharge
    has
    been
    quite
    close
    to
    the
    3
    mg/l standard.
    This
    is
    true
    even
    in
    recent
    years
    when
    the
    nitrogen
    content
    of
    the
    oil
    feedstocks
    have
    been
    high.
    The
    Board
    fully
    expects
    Mobil
    to
    continue
    its
    high
    performance
    level
    concerning
    ammonia
    nitrogen
    concentrations.
    The
    Board,
    therefore,
    grants
    Mobil
    a
    permanent
    relief
    from
    Section
    304.122(b)
    within
    the
    conditions
    listed
    in
    the
    Order.
    (emphasis added).
    Opinion and Order,
    R84—l6, slip.
    op. at
    7—8
    (February
    5,
    1987).
    Although the Board
    still expects Mobil
    to continue its high
    performance levels, without the annual average limit there is no
    legal requirement for Mobil
    to continue
    to produce an effluent
    whose annual average would be close to
    3 mg/i.
    With only the
    monthly and daily limits, set at
    20 and
    35 mg/l respectively,
    Mobil
    is only legally required
    to produce an effluent to meet
    those standards.
    Consequently, Mobil will be aliowed
    to
    discharge an effluent of such quality that a yearly average of
    the monthly averages could be as high as 20 mg/i.
    This
    is
    in
    great contrast to the yearly averages of the monthly averages
    for
    the years 1983 through 1987 which are set forth on page
    5 of this
    Opinion.
    It
    is obvious that with monthly and daily limits set at
    20/35,
    Mobil will not be required
    to maintain the level of
    performance that it has achieved
    in the past
    4 2/3 years.
    Consequently, factors, which the Board relied upon at First
    Notice
    to omit a sunset, have changed such that the Board will
    now impose
    a sunset.
    As in Union,
    the Board will terminate this rule on December
    31,
    1993.
    The six years will allow time for improvement of the
    Des Plaines’
    condition.
    As the Board
    noted
    in Union, upstream
    activities by the MSDGC might greatly enhance water quality.
    In
    re Union Oil Company,
    R84—13 slip.
    op.
    at ii
    (March
    19,
    1987).
    The Board may then be
    in a better
    position to accurately evaluate
    the environmental
    impact that would result from granting Mobil
    permanent relief.
    Also,
    the six years will give Mobil further
    time
    to monitor its effluent and perhaps discover
    a
    technically
    feasible and economically reasonable method
    for achieving
    compliance with the general
    3 mg/l limitation.
    85—113

    12
    Mobil
    has
    asserted
    that
    an
    increase
    in
    the nitrogen content
    of
    the
    crude
    oil
    it
    refines
    correspondingly
    increases
    its
    effluent concentration.
    In particular,
    it claims that nitrogen
    content of the crudes have increased over the years.
    The crude
    oil nitrogen content at the Joliet refinery has gone from a low
    of about 680 parts per million
    (ppm)
    in 1976
    to a high of about
    1450 ppm
    in 1984.
    In
    1985,
    it dropped
    to
    a level of 1120 ppm.
    Mobil Oil Company, PCB 86—45 at
    3.
    If Mobil finds
    in the future
    that
    it exceeds the standards on a regular basis,
    it can come
    before the Board
    under another docket to seek relief.
    However,
    even though
    in recent years Mobil’s crude feedstocks have had
    a
    high nitrogen content, its effluent has been within the limits
    set herein.
    Mobil will be required to monitor and report its effluent
    concentration.
    However, exact procedures for monitoring and
    reporting effluent concentrations shall
    be set forth in the
    permit.
    Also, Mobil will
    be required
    to report on an annual
    basis the nitrogen content of its feedstock.
    Water Quality Standard Relief
    Mobil has also requested relief from being liable for
    causing the violation of various water quality standards (WQS).
    In response to
    a U.S. Environmental Protection Agency (USEPA)
    Review Statement submitted by the Agency, Mobil modified its
    original proposed language addressing the water quality standards
    issue.
    Essentially, the modified language states that 35
    Ill.
    Adm. Code 304.105 will apply to Mobil with respect to general use
    and secondary contact WQS
    for ammonia nitrogen and dissolved
    oxygen, “unless such discharge does not cause or contribute
    significantly to the violation” of the WQS.
    (Mobil Response,
    p.
    1).
    Mobil’s discharge is located approximately 200 feet upstream
    of the 1—55 bridge.
    The river upstream of the bridge
    is
    classified as secondary contact, whereas downstream of the
    bridge,
    the river
    is considered general
    use.
    (R.
    125—26).
    Consequently, Mobil’s discharge may,
    in theory,
    impact upon both
    secondary contact and general use streams.
    The general use water quality standard for total ammonia
    nitrogen, given the river’s pH and temperature,
    is 1.5 mg/i
    (35
    Ill.
    Adm. Code 302.212).
    The general use water quality standard
    for dissolved oxygen is
    6 mg/l
    (35 Ill. Mm. Code 302.206).
    Mobil’s impact upon these standards
    is discussed in Petitioner’s
    Exhibit
    3,
    a report prepared by an expert witness
    for Mobil.
    The report shows that the general use standard for ammonia
    nitrogen
    is exceeded downstream of Mobil’s discharge.
    However,
    it
    is concluded that under worst case conditions
    (Mobil
    discharging
    3 MGD at 40 mg/i into the river flowing at a low
    level of 1,186 MGD), Mobil’s discharge would extend by only 1.85
    miles the reach of the river which did not meet the ammonia
    nitrogen
    standards.
    (Pet.
    Exh.
    #3,
    p.
    16).
    85—114

    13
    Similarly,
    the dissolved oxygen standard
    is currently
    exceeded downstream of Mobil.
    However, under
    the same worst case
    conditions,
    Mobil’s discharge would extend by no more than one
    mile the reach of the river which did not meet the dissolved
    oxygen standard.
    (Id.
    at
    19).
    The secondary contact ammonia nitrogen standard
    is 2.5 mg/i
    for April
    through October,
    (35 Ill. Mm.
    Code 302.407).
    It is
    apparent from data reported
    in Petitioner’s Exhibit #3 that this
    standard
    is exceeded upstream of Mobil’s discharge.
    (Pet.
    Exh.
    #3,
    p.
    17).
    The secondary contact standard for dissolved oxygen is
    4
    mg/i
    (35 Ill. Adm. Code 302.405).
    Data shows that this standard
    is exceeded
    in the river mile where Mobil discharges.
    (Pet. Exh.
    #3,
    p.
    18).
    Consequently,
    it
    is likely, given the upstream
    exceedances of the ammonia nitrogen standard, that the dissolved
    oxygen standard
    is also being violated upstream of Mobil’s
    discharge point.
    In the USEPA’s Review Statement, the USEPA stated
    that
    Mobil’s addition
    to the river
    is “insignificant” with respect
    to
    water quality violations.
    It concluded:
    Mobil
    should
    not
    be
    granted
    relief
    from
    Section
    304.105
    but
    should
    be
    required
    in
    their NPDES permit to,
    in addition to standard
    effluent
    monitoring,
    conduct
    upstream
    and
    downstream
    ammonia—N
    monitoring
    at
    representative
    sampling
    points
    to
    clearly
    ascertain whether or
    not they are responsible
    for
    water
    quality
    standards
    violations
    for
    ammonia—N.
    In its First Notice Opinion, the Board
    classified Mobil’s
    current impact on water quality as “de minimus”.
    In their First
    Notice comments, Mobil
    and the Agency both object to
    the Board’s
    de minimus characterization.
    Upon reconsideration,
    the Board
    finds the de minimus language to be inappropriate and hereby
    rescinds
    it.
    In its First Notice comments, Mobil requests that the Board
    clarify when Section 304.105 would apply to Mobil’s discharge.
    (P.C.
    #1,
    p.
    12—13).
    Evidently,
    Mobil
    is referring
    to its
    modified language that Section 304.105 will not apply unless
    Mobil “causes
    or contributes significantly”
    to
    a WQS violation.
    The Agency suggests that the Board rule that “compliance with the
    proposed effluent limits shall
    be considered adequate compliance
    with the water quality standards for the purposes of Section
    304.105.”
    (P.C.
    #2,
    p.
    4). The Board disagrees with both
    positions.
    85—115

    14
    The Board
    first
    adopted
    the
    language
    of
    Section
    304.105
    as
    Rule 402 in
    1972.
    In its adopting Opinion, the Board discussed
    the purpose behind the rule:
    402
    Violation
    of
    Water
    Quality
    Standards.
    The
    numerical
    effluent
    standards
    adopted
    today are intended
    as basic requirements that
    should
    be
    met
    everywhere
    as
    representing
    ordinary good practice
    in keeping potentially
    -harmful materials out of the waters.
    In
    some
    cases,
    because
    of
    the
    low
    volume
    of
    the
    receiving
    stream
    or
    the
    large
    quantities
    of
    treated
    wasted
    sic
    discharged,
    meeting
    these
    standards
    may
    not
    suffice
    to
    assure
    that
    the
    stream
    complies with
    water
    quality
    standards
    set
    on
    the
    basis
    of
    what
    is
    necessary to
    support
    various water
    uses.
    In
    such cases,
    the very nature of water quality
    standards
    requires
    that
    additional
    measures
    be
    taken
    beyond
    those
    required
    by
    ordinary
    good practice
    to reduce further
    the discharge
    of
    contaminants
    to
    the
    stream.
    This
    would
    not
    be
    so
    if
    effluents
    were
    all
    required
    to
    be
    as
    clean
    as
    the receiving
    stream,
    but
    in
    recognition
    of
    economic
    hardship
    we
    have
    refrained
    from
    imposing
    such
    a
    requirement
    across
    the
    board.
    What
    additional measures
    are
    required
    can
    be
    determined
    only
    on
    the
    basis
    bf more detailed consideration
    of each
    stream
    in
    accordance
    with
    the
    statutory
    requirement that different needs may dictate
    different
    standards.
    Rule
    402
    states
    the
    principle
    that discharges causing violations
    of the water quality standards are forbidden,
    as
    was
    the
    case
    under
    the
    earlier
    regulations,
    and
    states basic
    considerations
    for
    determining
    which
    of
    a
    number
    of
    contributors
    to
    an
    overloaded
    stream
    must
    take measures
    to abate
    the problem
    (emphasis
    added).
    In re:
    Effluent Criteria; Water Quality
    Standards Revisions; and Water Quality
    Standards Revisions for
    Intrastate
    Waters, R70—8; R7l—i4;
    R7l—20,
    3 PCB 401,
    405
    (January
    6,
    1972).
    The record indicates 96 percent of the ammonia loading
    in
    the Des Plaines
    is due to the discharges from MSDGC sewage
    treatment plants.
    Mobil,
    itself accounts for 0.3 percent of the
    point source loading.
    Therefore,
    the Des Plaines is
    a
    type of
    river expressly contemplated by the Board when it adopted Rule
    402.
    “In some cases,...because of large quantities of treated
    85—116

    15
    wasted
    sic
    discharged, meeting these
    effluent
    standards may
    not suffice to assure that the stream complies with water quality
    standards....
    In such cases,
    as
    with this particular stretch of
    the Des Plaines
    the very nature of water quality standards
    requires that additional measures be taken....”
    These
    “additional measures” equate to the enforcement of Section
    304.105.
    The reasoning behind Section 304.105
    is just as valid
    today as
    it was
    in 1972 when
    it was adopted
    as Rule 402.
    In its 1972 Opinion,
    the Board clearly described two lines
    of defense
    in the protection of a stream’s water quality.
    The
    first line entails the regulation of effiuents.
    The second line,
    which
    is just as important as the first,
    involves enforcement
    against a source that causes
    a violation of
    a water quality
    standard.
    In the instance at hand, Mobil has justified relief as
    to
    its effluent discharge.
    Due to technical, economic,
    and
    environmental consideration, the Board will alter Mobil’s
    effluent limits.
    However, Mobil has not justified
    to the Board
    the necessity for abandoning completely,
    or even partially, this
    second line of defense.
    In the
    record, much has been made about
    the relatively poor
    quality
    of
    the
    Des
    Piaines
    River.
    The
    implication
    is
    that
    the
    Board
    should
    grant
    Mobil some sort of relief from Section 304.105
    because the water quality standards are already being exceeded.
    However, the Board
    is not
    in the position
    to merely preserve the
    status quo when water quality standards are being violated
    in a
    river.
    The Board
    is to adopt regulations “to promote the
    purposes and provisions”
    of the Act.
    Iii.
    Rev. Stat.
    1985,
    ch.
    1111/2, par.
    1013
    (a).
    One of the purposes of the Act
    is to
    “restore, maintain and enhance the purity of the waters of this
    State
    in
    order
    to
    protect
    health, welfare, property, and the
    quality
    of
    life and
    to assure that no contaminants are discharged
    into
    the
    waters
    of
    the
    State.”
    Iii.
    Rev.
    Stat.
    1985,
    ch.
    ill
    1/2
    ~
    par.
    1011(b).
    The Board
    is not convinced
    that
    it
    would
    be
    furthering
    the
    purposes of the Act by insulating Mobil from an enforcement
    action when Mobil
    is contributing
    to
    a WQS violation.
    Secondly, any relief from Section 304.105 could be
    considered
    a de facto WQS revision.
    Although the Board has the
    authority to revise a WQS, federal law,
    under the Federal Water
    Pollution Control Act, requires that certain criteria be met
    in
    the case of such
    a revision.
    The record does not contain the
    necessary information that would be required before the Board
    could consider
    a WQS change.
    Also,
    no numerical WQS alternative
    is proposed.
    Mobil
    is merely requesting that Section 304.105 not
    apply to Mobil as
    it would apply to all other sources.
    For all
    of the above reasons, the Board will deny that part
    of Mobil’s proposal which requests partial relief
    from Section
    304.105.
    85—117

    16
    Finally,
    the Board also believes that the instream
    monitoring, as proposed by the USEPA,
    is a requirement suitable
    for consideration by the Agency as a permit condition.
    ORDER
    The Board adopts as final
    the following rule
    to be filed
    with the Secretary of State and published in the Illinois
    Register.
    TITLE
    35:
    ENVIRONMENTAL PROTECTION
    SUBTITLE C:
    WATER POLLUTION
    CHAPTER
    I:
    POLLUTION
    CONTROL
    BOARD
    PART
    304
    EFFLUENT
    STANDARDS
    SUBPART B:
    SITE—SPECIFIC RULES AND
    EXCEPTIONS NOT OF GENERAL APPLICABILITY
    Section 304.214
    Mobil Oil Refinery Ammonia Discharge
    a)
    This Section applies
    to discharges from Mobil
    Oil
    Corporation’s Refinery, located near Joliet,
    into the
    Des~Plaines River.
    b)
    The requirements of Section 304.122(b)
    shall not apply
    to Mobil’s discharge.
    Instead Mobil’s discharge shall
    not exceed the following limitations:
    CONSTITUENT
    CONCENTRATION (mg/i)
    Ammonia Nitrogen
    Monthly Average
    20
    Daily Composite
    35
    c)
    Section 304.104(a)
    shall
    not apply to this Section.
    Monthly average and daily composites are as defined
    in
    Section
    304.104(b).
    d)
    Mobil
    shall
    monitor
    the nitrogen concentration of its
    oil
    feedstocks
    and
    report
    on
    an
    annual
    basis
    such
    concentrations
    to
    the
    Agency.
    The
    report
    shall
    be
    filed
    with
    the
    Agency by January
    31
    of
    each
    year.
    e)
    The provisions of this Section shall
    terminate on
    December
    31,
    1993.
    (Source:
    Added
    at 12 Ill. Reg.
    effective
    )
    85—118

    17
    IT IS SO ORDERED.
    Section 41 of the Environmental Protection Act,
    Ill. Rev.
    Stat.
    1985 ch.
    111 1/2
    par.
    1041,
    provides
    for appeal of final
    Orders of the Board within 35 days.
    The Rules of the Supreme
    Court of
    Illinois establish filing requirements.
    I, Dorothy M.
    Gunn, Clerk of the Illinois Pollution Control
    Board,
    hereby certifZ~~tthe above Proposed Opinion and Order
    was adopted on the
    1~1~
    day of
    ________________,
    1988, by a
    vote of __________________________
    ~
    ~.
    L ~
    Dorothy M.~Gunn,Clerk
    Illinois Pollution Control Board
    85—119

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