ILLINOIS POLLUTION CONTROL BOARD

September

8,

1988

IN THE MATTER OF:

PROPOSED AMENDMENTS TO PART

)

 R88-23

211 AND 215, LEAKS FROM

)

SYNTHETIC ORGANIC CHEMICAL

AND POLYMER MANUFACTURING

EQUIPMENT

PROPOSED RULE.

 FIRST NOTICE.

ORDER OF THE BOARD

 (by J.

D.

 Dumelle):

This matter comes before the Board upon

 an August 24,

 1988,

Joint Proposal filed simultaneously with

 a Joint Motion by the

Illinois Environmental Protection Agency (Agency), Amoco Chemical

Company (Amoco), the Dow Chemical Company (Dow), Mobil Chemical

Company,

 Inc.

 (Mobil), and Stepan Company (Stepan), all of whom

will

 be generally referred

 to as “Joint Proponents”

or

 “Joint

Movants”.

 The joint motion requests the Board

 to conduct an

expedited rulemaking on the joint proposal.

The Board

 is amenable to expediting the rulemaking process

as much as possible consistent with the Administrative Procedure

Act; however, the Board notes that

a

 rulemaking proceeding can be

expedited only inasmuch as the proponents and participants

demonstrate

 a willingness

 to cooperate.

For

 its part, the Board

today sends the proposal

 to First Notice.

 However, due

 to the

expedited nature of this proceeding,

 the Board takes no position

at this time on the substance of the proposed text.

The Hearing Officer

 is directed

 to schedule hearings as soon

as practicable.

ORDER

The Board hereby proposes the following amendments to 35

Ill. Adm. Code 211 and 215 for

 First Notice publication.

The

Clerk

 is directed

 to submit these proposed amendments to the

Secretary of State’s Office for publication

 in the Illinois

Register.

92—441

—2—

TITLE

35:

 ENVIRONMENTAL PROTECTION

SUBTITLE

B:

 AIR POLLUTION

CHAPTER

I:

 POLLUTION CONTROL BOARD

SUBCHAPTER C:

 EMISSION STANDARDS AND LIMITATIONS FOR STATIONARY

SOURCES

PART 211

DEFINITIONS AND GENERAL PROVISIONS

SUBPART B:

 DEFINITIONS

Section 211.122

 Definitions

“Closed Purge System”:

 A system that is not open

 to the

atmosphere and that

 is composed of piping,

 connections,

 and,

if

necessary, flow inducing devices that transport liquid

 or vapor

from

 a piece or pieces of equipment to

 a control device,

or

return the liquid or vapor

 to the process line.

“Closed Vent System”:

 A system that

 is not open

 to the

atmosphere and that

 is composed of piping,

 connections,

 and,

if

necessary, flow inducing devices that transport gas or vapor from

a piece or pieces of equipment

 to a control device,

 or return the

gas or vapor

 to the process line.

“Component”:

 Any piece of equipment which has the potential to

leak volatile organic material including,

 but not limited

to,

pump seals, compressor

 seals,

 seal oil degassing vents, pipeline

valves, pressure relief devices, process drains and open ended

p4pesvalves.

 This definition excludes valves which are not

externally regulated,

 flanges, and equipment

 in heavy liquid

service.

 For purposes of Subpart

Q

 (35 111.

 Adm. Code 215),

 this

definition also excludes bleed ports of gear pumps

 in polymer

service.

“Control Device”:

 For purposes of Subpart

Q,

 an enclosed

combustion device, vapor

 recovery system, flare,

 or closed

container.

0In~~situSampling Systems”:

 nonextractive samplers or in—line

samplers.

“Light Liquid”:

 Volatile organic material

 in the liquid state

which

 is not defined

as

 a heavy liquid.

“Liquids Dripping”:

 Any visible leaking from

 a seal including

 spraying, misting, clouding and ice formation.

“Pressure Release”:

 The emission of materials resulting from

~ystem pressure being greater than set pressure of the pressure

92—442

—3—

relief device.

“Process Unit”:

 Components assembled

 to produce,

 as intermediate

or final products, one or more of the chemicals listed

in

Appendix D.

 A process unit can operate

 independently if supplied

with sufficient feed or raw materials and sufficient storage

facilities

 for the product.

“Process Unit Shutdown”:

 A work practice or operational

procedure that stops production from

 a process unit or part

of

a

process unit.

 An unscheduled work practice or operational

procedure that stops production from

 a process unit or part

 of a

process unit for less than

 24 hours

 is not

 a process unit

shutdown.

 The use of spare components and technically feasible

bypassing

 of components without stopping production are not

process unit shutdowns.

“Purged Process Fluid”:

 liquid

 or vapor from

 a process unit that

contains volatile organic material and that results from flushing

or cleaning the sample

 line(s)

of

 a process unit so that

a

uncontaminated sample may then be taken

 for testing or analysis.

“Sensor”:

 A device

 that measures

 a physical quantity or the

change

 in a physical quantity such as temperature, pressure, flow

rate, pH,

 or liquid level.

“Synthetic Organic Chemical or Polymer Manufacturing Plant”:

A

plant that produces, as intermediates or

 final products, one or

more of the chemicals or polymers listed

 in Appendix

D.

“Zero Volatile Organic Material Emissions”:

 A discharge of

volatile organic material

 into the atmosphere as indicated by an

instrument reading of less than 500 ppm above background

as

determined

 in accordance with 40 CFR Section 60.485(c).

(Source:

 Amended

at

______

 Ill.

 Reg.

_______

effective

____________)

92—443

—4—

TITLE

35:

 ENVIRONMENTAL PROTECTION

SUBTITLE B:

 AIR POLLUTION

CHAPTER

I:

 POLLUTION CONTROL BOARD

SUBCHAPTER C:

 EMISSIONS STANDARDS AND LIMITATIONS FOR

STATIONARY SOURCES

PART 215

ORGANIC MATERIAL EMISSION STANDARDS AND LIMITATIONS

SUBPART

A:

 GENERAL PROVISIONS

Section 215.104

 Definitions

The definitions of 35

 Iii. Adm.

 Code 201

 arid 211 apply to this

 Part, as well as the definition contained in this Section.

 Where

the definition contained

 in this Section

 is more specific than

that found

 in Parts

 201 or 211,

 it shall take precedence

in

application of this Part.

~

 t,4~-~Ve~~e e~g~~emer4~

 4r~~J’~e44~t~4d

~t~e

w~e1~

4~

t’~e~

~ef4rie~

(Source:

 Amended at

_____

 Ill. Reg.

___________

effective

_____________).

Section 215.105

 Incorporation by Reference

The following materials are incorporated by reference:

a)

 American Society for Testing and Materials,

 1916 Race

Street, Philadelphia,

 PA 19103:

1)

 ASTM D 1644—59 Method A

2)

 ASTM D 1475—60

3)

 ASTM D 2369—73

4)

 ASTM D 2879—83

 (Approved 1983)

5)

 ASTM D 323—82

 (Approved 1982)

6)

 ASTM D 86—82

 (Approved 1982)

7)

 ASTM

 E 260—73

 (Approved 1973),

 E 168—67

(Reapproved 1977),

 E 169—63

 (Reapproved 1981),

E

20

(Approved 1985)

8)

 ASTM

 D 97—66

9)

 ASTM D 1946—67

9 2—444

—5—

10)

 ASTM D 2382—76

11)

 ASTM 0 2504—83

12)

 ASTM D 2382—83

b)

 Federal Standard l4la, Method 4082.1

 National Fire Codes, National Fire Prevention

Association, Battery March Park,

 Quincy, Massachusetts

02269

 (1979)

d)

 United States Environmental Protection Agency,

Washington,

 D.C., EPA—450/2—77—026, Appendix A

 (October

1977)

e)

 United States Environmental Protection Agency,

Washington,

 D.C.,

 EPA—450/2—78—051 Appendix A and

Appendix B (December 1978).

f)

 Standard Industrial Classification Manual, published by

Executive Office of the President, Office of Management

and Budget, Washington,

 D.C.,

1972

g)

 40 CFR 60, Appendix

A,

1986

h)

 United States Environmental Protection Agency,

Washington D.C.,

 EPA—450/2—78—04l.

(Board Note:

 The incorporations by reference listed above

contain

 no later amendments or editions.)

(Source:

 Amended at

_____

 Ill.

 Reg.

________

effective

______________).

SUBPART

Q:

 LEAKS FROM SYNTHETIC ORGANIC CHEMICAL AND POLYMER

MANUFACTURING EQUIPMENT

Section 215.420

 Applicability

The provisions of Sections 215.421 through 215.429

 of this

subpart shall apply to all plants

 in the State of Illinois which

manufacture synthetic organic chemicals and polymers,

 except

those located

 in any of the following counties:

 Will,

 McHenry,

Cook, DuPage, Lake, Kane,

 Madison, St.

 Clair, Macoupin, and

Monroe.

 The provisions of Section 215.430 through ~5-438

215.329 shall apply to the counties specifically enumerated

above.

In addition,

 if any county

 is redesignated as non—attainment by

the USEPA subsequent

 to December 31,

 1987,

 the owner or operator

92—445

—6—

of a plant

 located

in

 that county shall comply with the

requirements of Sections 215.430

 through 2~5748 215.439 upon the

effective date of the redesignation.

(Source:

 Amended

at

_____

 Ill.

 Reg.

_______

effective

_______________

Section 215.430

 General Requirements

The owner

 or operator of a plant which processes more than 3660

Mg/yr

 (4033

 tons/year)

 gaseous e~and

 light liquid volatile

organic material, and whose components are used

 to manufacture

the synthetic organic chemicals or polymers listed

 in Appendix

0,

shall eo~th~e~

 ~e&~

 ee~4et~a~

~

~

fOf

~

4t~t

~eeef~1~ee

w4~1~

 ~th4~

S~r~ comply with Sections

215.430

 to 215.439.

 E~e&~

 ee~4ei~

~nd

fep~4f

~

 ~+i~H ~e

eet~e~e~

 fef ~th~ter~e~

 The provisions of Sections 215.430

to 215.439 are applicable

 to components containing

 10 percent or

more by weight volatile organic material as determined by ASTM

method E—l68, E—169

 and E—260,

 incorporated by reference

in

Section 215.105.

 Those components

 that are not process unit

components are exempt from Sections 215.430

 to 215.439.

A

component shall

 be considered

 to be leaking

 if the volatile

organic material

 is equal to,

or

 is greater than 10,000 ppmv as

methane or

 hexane as determined by USEPA Reference Method

 21, as

specified

 at 40 CFR 60, Appendix

A,

 incorporated by reference in

Section 215.105, indication of liquids dripping,

 or indication by

a sensor that a seal or barrier fluid system has failed.

The

provisions of this Subpart are not applicable

 if the equipment

components are used

 to produce heavy liquid chemicals only from

 heavy liquid feed or

 raw materials.

(Source:

 Amended at

_____

 Ill. Reg.

_______

effective

____________

Section 215.432

 Inspection Program for Leaks

The owner

 or operator of

 a synthetic organic chemical or polymer

manufacturing plant subject

 to Section 215.430 through ~5~-438,

215.439,

 shall

 for the purposes of detecting leaks, conduct

a

component

 inspection program utilizing

 the test methods specified

in Reference Method 21,

 40 CFR 60, Appendix

 A (1986),

incorporated

 by reference

 in Section 215.105, consistent with the

following provisions:

a)

 Test annually those components operated

 near extreme

temperature

 or pressure such that they would be unsafe

to routinely monitor, and those components located more

than two meters above permanent worker

 access structures

or surfaces;

92—44 6

—7—

b)

 Test quarterly all other pressure relief valves in gas

service, pumps

 in light

 liquid service, valves

 in light

liquid service and

 in gas service,

 and compressors.

c)

 If less than or equal

to

 2 percent of the valves

in

light liquid service and

 in gas service tested pursuant

to subsection

(b)

 are found not to leak for

5

consecutive quarters, no leak tests shall

 be required

for three consecutive quarters.

 Thereafter,

 leak tests

shall resume

for

the

 next quarter.

 If that test shows

less than or equal to

 2 percent of the valves

 in light

liquid service and

 in gas service are leaking, then no

tests are required

 for the Next

 3 quarters.

 If more

than

 2 percent are leaking, then tests are required for

the next

 5 quarters.

d)

 Observe visually all pump seals weekly.

e)

 Test immediately any pump seal

 in light liquid service

from which liquids are observed dripping.

f)

 Test any relief valve within 24 hours after

 it has

vented

 to the atmosphere.

g)

 Routine instrument monitoring of valves which are not

externally regulated,

 flanges, and e~e~

 components

in heavy liquid service,

 is not required.

 However,

any

valve which is not externally regulated,

 flange, or

p4eee cf e~prt~en~

 component

 in heavy liquid service

that is found to be leaking on the basis of sight, smell

or sound shall be repaired as soon as practicable but no

later than 30 days after

 the leak

is

 found.

h)

 Test immediately after

 repair

 any component that was

found

 leaking.

i)

 Within

 1 hour of its detection,

 a weátherp~oof,rëadily

visible tag,

 in bright colors such as red or yellow,

bearing

an

 identification number

 and the date on which

the leak was detected must be affixed on the leaking

component and remain

 in place

 until the leaking

component

 is repaired.

 Any component that

is

 in vacuum service7

 or any pressure

relief devices connected

 to an operating flare header or

to

 a vapor recovery devices ~e

 is exempt from the

monitoring requirements

 in this Section.

(Source:

 Amended at

_____

 Ill.

 Reg.

_______

effective

)

92—44

—8—

Section 215.435

 Report for Leaks

The owner or operator of

 a synthetic organic chemical

 or polymer

manufacturing plant subject

 to Section 215.430 through ~S7438

215.439 shall:

a)

 Submit quarterly reports

 to the Agency on or before

March 31, June 30, September 30, and December 31 of each

year, listing all leaking components

 identified pursuant

 to Section 215.432 but not repaired within 15 days,

all

leaking components awaiting process unit shutdown, the

total number

 of components inspected,

 the type of

components

 inspected,

 and the total number of components

found leaking,

the

 total number of valves

 in light

liquid and

 in gas service inspected and the number and

percentage of valves

 found leaking.

b)

 Submit

 a signed statement with the report attesting that

all monitoring and repairs were preformed as required

under Section 215.430 through 215.436.

(Source:

 Amended at

_____

 Ill.

 Reg.

_______

effective

____________).

Section 215.437

 Open—Ended Valves

a)

 Each open—ended Valve shall be

 equipped with a cap,

blind

 flange, plug,

or

 a second valve, except during

operations requiring fluid flow through the open—ended

valve.

b)

 Each open—ended valve equipped with

 a second

 valve shall

be operated

in

 a manner such that the valve on the

process

 fluid

end

 is closed before the second valve

is

closed.

C)

 Components which are e2pen—ended valves and which serve

as a sampling connection shall be e4p~e~w4~he e4e~ed

~~ge

e~cse~

vera ~ys~em controlled

 such that:

1)

 A closed purge system or closed vent system

 shall

return Pt~fge~

 purged process fluid ~

fe~f~tedto the process line with zero ~eM volatile

organic material emissions

 to the atmosphere,

or

2)

 A closed purge system or closed vent system shall

collect and

 recycle P~f~e~

 purged process fluid

eeeete~

oi~

reeyeled to the process line

with zero volatile organic material emissions to

the

atmosphere,

92—448

—9—

3)

 Purged process

 fluid

 shall

 be transported

to

a

control device that complies with the requirements

of Section 215.438.

d)

 In—situ sampling systems are exempt from subsection

 (c).

(Source:

 Amended

at

 Ill. Reg.

__________

effective

______________

215.438

 Standards

for Control Devices

Control devices used to comply with Section 215.437(c)

 shall

comply with following:

a)

 If the control device

is

 a vapor recovery system

 (for

example, condensers and

 adsorbers)

 it shall

 be designed

and operated

 to recover

 the volatile organic material

emissions vented

to

 it with an

 efficiency of

 95 percent

or greater.

b)

 If the control device

 is an enclosed combustion device,

it

 shall

 be designed and operated

 to reduce

 the volatile

organic material emissions vented

to

 it with an

efficiency of 95 percent

 or greater,

or

 to provide

a

minimum residence time of

 0.75 seconds at

 a minimum

temperature of 816

C.

c)

 If the control cevice

is

a

 flare,

 it shall:

1)

 Be designed

for

 and operated with no visible

emissions as determined

 by USEPA Reference Method

22,

 40 CFR 60, Appendix

A,

 incorporated

by

reference

 in Section 215.105, except

 for periods

not to exceed

 a total

of

 5 minutes during any

2

consecutive

 hours.

2)

 Be operated with

 a pilot flame present

 at all

 times

and shall

 be monitored with

 a thermocouple or any

other equivalent device

 to detect

 the presence of

the pilot flame.

3)

 Be steam—assisted,

 air assisted, or nonassisted.

4)

 Be used only~with the net heating value of the gas

being combusted being 11.2 MJ/scm

 (300 Btu/scf)

or

greater

 if the flare

 is steam—assisted or air—

assisted;

 or with the net heating value of the gas

being combusted being

 7.45 MJ/scm or greater

 if the

flare

 is nonassisted.

 The net heating value of the

gas being combusted shall

 be calculated

 using

the

following equation:

92—449

—10—

n

Hr

 KZC1H~

i=l

Where:

H

—

 Net heating value

 of the sample, MJ/scm:

where

 the net enthalpy per mole

 of offgas

 is based

on combustion at

25

 C and 760 mm Hg,

 but the

standard temperature

 for determining the value

corresponding

 to one mole is 20

C.

K

 Consta9t,

1

 g mole

MJ

1.740

x

10

ppm

scm

 kcal

where

standard temperature

for

 g mole

is

20

C.

scm

C1

 Concentration of sample component

i,

in

ppm,

 as measured by USEPA Reference

 Method

18,

 40 CFR 60, Appendix A (1986),

and ASTM D 2504—83, both incorporated by

reference in Section 215.105.

H1

 Net heat of combustion

of

sample

component

i,

 kcal/g mole.

 The heats of

combustion may be

determined

 using ASTM D

2382—83,

 incorporated by reference

in

Section 215.105,

 values

 are not available

or cannot be calculated.

5)

 Steam—assisted and nonassisted flares shall be

designed and operated with an exit velocity,

as

determined by dividing the volumetric flowrate

(in

units of standard temperature

 and pressure),

as

determined by USEPA Reference Method

2

or

2A,

40

CFR 60, Appendix A

 (1986)

 incorporated by reference

in Section 215.105,

 as appropriate;

 by the

unobstructed

 (free)

 cross sectional area of the

flare

 tip, less than

18

 m/sec

 (60 ft/sec.).

6)

 Air—assisted

 flares shall

 be designed and operated

with an exit velocity less than the maximum

permitted velocity, ~

 as determined

 by the

following equation:

Vmax

 8.706

 O.7O84(Hr)

Vm~y=Maximum permitted velocity, rn/sec.

92—450

—11—

8.706

 Constant.

0.7084

 Constant.

Hr

 The net heating value

 as determined

in

subsection

 (c)(4)

 of this section.

d)

 If the control device

is

 a closed container,

 it shall

be

designed and operated

 to reduce

 the volatile organic

material emissions, vented from purged process fluid

after transfer,

 to zero volatile organic material

emissions as determined

 by USEPA Reference Method 21 as

specified at 40 CFR 60, Appendix

 A (1986),

 incorporated

by reference

 in Section 215.105.

 For purposes of this

Section,

 the phrase

 “after transfer” shall

 refer

 to the

time at which the entire amount of purged process fluid

resulting from

 a flushing or cleaning of the sample line

enters the closed container

 or containers including

the

final container(s)

 prior

 to disposal.

e)

 The owner

 or operator

of

 a control device shall monitor

the

 control device to ensure that it

 is operated and

maintained

 in conformance with its design.

f)

 The control device shall be operated

 at all times when

emissions may be vented

to

it.

(Source:

 Section 215.438

 renumbered

 to Section 215.439, new

Section 215.438 adopted at

_____

 Ill. Reg.

_______

effective

____________).

Section 2~5~4~82l5.439Compliance Date

The owner

 or operator of

 a synthetic organic chemical or polymer

manufacturing plant subject to Sections 215.430~through

~4B

215.439

 shall comply with the standards and

 limitations of those

Sections no later than December

31,

 1987.

(Source:

 Section 215.439 renumbered

 from Section 215.438

and

amended

at

_____

 Ill.

 Reg.

_______,

 effective

_________________

92—451

—12—

APPENDIX

LIST OF CHEMICALS DEFINING SYNTHETIC

ORGANIC

CHEMICAL

AND

 POLYMER MANUFACTURING

O~?BB

Ne~

 CAS No.

a

 Chemical

29

 105—57—7

 Acetal

75—07—0

Acetaldehyde

107—89—1

Acetaldol

60—35—5

Acetamide

103—84—4

Acetanilide

64—19—T

Acetic

acid

108—24—7

Acetic

anhydride

67—64—1

Acetone

499

75—86—5

Acetone

cyanohydrin

4~9

75—05—8

Acetonitrile

429

98-86—2

Acetophenone

425

 75-36—5

 Acetyl chloride

438

74—86—2

Acetylene

449

 107—02—8

 Acrolein

459

79—06—1

Acrylamide

468

 79—10~i

 Acrylic acid ~

107—13—1

 Acrylonitrile

488

 124—04—9

 Adipic acid

485

 111—69—3

 Adiponitrile

499

(b)

Alkyl

naphthalenes

298

107—18—6

Allyl

alcohol

249

107—05—1

Allyl

chloride

229

1321—11—5

Aminobenzoic

acid

239

111—41—1

Aminoethylethanolarnine

235

123—30—8

p—aminophenol

249

628—63—7,

Amyl

acetates

12 3—92—2

258

7l-4l—Oc

Amyl

alcohols

268

110—58—7

Amyl

amine

2~8

543—59—9

Amyl

chloride

288

l10—68—7c

Amyl

mercaptans

299

 1322-06—1

 Amyl phenol

399

 62—53—3

 Aniline

349

142—04—1

Aniline

hydrochloride

328

29191—52—4

Anisidine

338

100—66—3

Anisole

348

118—92—3

Anthranilic

acid

358

84—65—1

Anthraquinone

369

100—52—7

Benzaldehyde

3~9

55—21—0

Benzamide

388

71—43—2

Benzene

398

 98—48—6

 Benzenedisulfonic

 acid

489

98-11—3

Bee—s~4fon~e

Benzenesulfonic

 acid

449

 134—81—6

 Benzil

92—452

1.11

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rt

 (D()0P-h

 (D~~

00

ø~

~(DQ

P.’

 ~D(DQ-~OQ~

~-“

D

(Drr~

i-~-rto~(D

i-~

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Dr~.

r~o

Q~D

~(D~-’-

 ~—

(D

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(D

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c10)

i-~WWWWWWWWWWWWWWWWW

I

I

I

i

I

I

I

I

I

 I~i~D(DDD

~,~Cro-tro-tro-rro

~

c

c

 c~’

t~ ~

0’

~-t

 Cl 0 0 ~

(T)

~‘

 ~‘

~

 0 0 0 N 0 Q

~‘~~

0’(D

~4~-~

r1-~

0

(DP~(D~k

rt~)P)

~

 ~(D~

C)

rr(D

 O~~.O~~Or1

~T~D

~

‘-‘-C)

I(D(D(0000’rr

Ob~OO(D~-

O~--

 o*-~-w

Or~~

t~t’

OOO~rr

i-~.(D(D

QJ~

(D

i

 (D(D

(D

0

~-~ry

t-J

(D

0

s

fr’•

0

;~

(D

p.’

I-’.

—14—

939

940

9 S’O

95:1:

969

964

965

97~o

9~O

992

~i8

GO

-~928

~82~

1e30

~94G

-~:O~O

4960

~o~o

•1088

i~oo

~4O

~59

~68

422 ~i:

•i248

4:250

-1309

67—66—3

2 5586—43—0

88—73—3

100—00—5

25167—80—0

126—99—8

7790—94—5

108—41—8

9 5—4 9—8

106—43—4

75—72—9

10 8—3 9—4

95—48—7

106—44—5

1319—77—3

1319—77

—3

4170—30—0

3724—65—0

98—82—8

80—15—9

3 7 2—0 9—8

506—77—4

108—80—5

108—77—0

110—82—7

108—93—0

108—94--i

110—83—8

108—91—8

111—78—4

 112—30—1

123—42—2

27576—04—1

95—76—1,

95—82—9,

554—00—7,

608—27—5,

608—31—1,

626—43—7,

27134—27—6,

57 311—9 2—9

541—73—1

95—SO—i

106—46—7

75—71—8

114—44—4

107—06—2

96—23—1

26952—23—8

101—83—7

109—89—7

111—46—6

Chloroform

Chi oronaphthalene

o—chi or oni t robe n zen e

p— chi or o rii t robe n zen e

Chi orophenols

Chioroprene

Chiorosulfonic

acid

rn—c hi or o to 1 ue n e

o—chlorotol

uene

p—chlorotol

uene

Chlorotr

ifluoromethane

m— cr eso 1

0—

Cr eso 1

p—cresol

Mixed

cresols

Cresylic

acid

Crotonaldehyde

Crontonic acid

Cumene

Cumene hydroperoxide

Cyanoacetic acid

Cyanogen chloride

Cyanuric

acid

Cyanuric chloride

Cyclohexane

Cyclohexanol

Cyclohexanone

Cyclohexene

Cyci oh e x yl amine

Cyclooc tad lene

Decanol

Diacetone

alcohol

Diaminobenzoic

acid

Dichioroanil

m—d ichlorobenzerie

o—d ichlorobenzene

p— d Ic hi or o benz

erie

Dichiorodi

fluoromethane

Dichioroethyl

ether

1,2—dichioroethane

~~pC)

Dichlorohydr

Dichioropropene

Dicyclohexylamine

Diethylamine

Diethylerie glycol

92—4 54

—15—

Diethylene glycol diethyl

 ether

Diethylene glycol dimethyl ether

Diethylene

 yee~mer~eb~y~

 glycol

monobutyl ether

Diethylene

 yee’~mcrte~ti~y~

 glycol

morionbutyl ether acetate

Diethylerie

 yeMe~eethy~glycol

monoethyl

ether

Diethylene

 yee4menee~thyIglycol

moriomethyl

ether

acetate

Diethylene

yee~mencme~thy~

glycol

monomethyl

 ether

Diethyl sulfate

Di fluoroethane

Diisobutylene

Diisodecyl phthalate

Diisooctyl phthalate

Diketene

Dimethylamine

N,N—dimethylaniline

N,N—d~Mey~e~i~ter

 dimethyl ether

N,N—dimethylformamide

Dimethyihydrazine

Dirnethyl

sulfate

Dimethyl sulfide

B~Meyufe~~e Dimethyl sulfoxide

~

 Dimethyl

terephthalate

3,5—dinitrobenzoic acid

 Dinitrophenol

Diriitrotoluene

Dioxane

Dioxolane

Diphenylamirie

Diphenyl oxide

Diphenyl

thiourea

Dipropylene glycol

Dodecene

Dodecylanilme

Dodecyiphenol

Epichlorohydr

Ethanol

Ethanolamines

Ethyl acetate

Ethyl acetocetate

Ethyl acrylate

Ethylamine

Ethylbenzerie

Ethyl bromide

Ethylcellulose

Ethyl chloride

i304

~3OS

~49

112—36—7

111—96—6

~k~.~?~—34—5

124—17—7

~339

 111—90—0

4340

 112—15—2

~69

 111—77—3

~4~G

~4~9

~44G

~44~

~444

i459

3:469

i4~O

44&9

~49O

1495

~

~5~O

4S20

~53O

64—67—5

75—37—6

25167—70—8

26761—40—0

27554—26—3

674—82—8

124—40—3

121—69—7

115—10—6

68—12—2

57—14—7

77—78—1

75—18—3

67—68—5

120—61—6

.i540

~545

4560

~5~9

458G

~59O

i609

46

1628

*3:639

1640

i6SG

i669

I66~

46~9

46&9

~699

•i~G9

4~1O

~1~29

1~3O

4~4G

99—34—3

51—28—5

25321—14—6

123—91—1

646—06—0

122—39—4

101—84—4

1O2—O~~

25265—71—8

25378—22—7

28675—17—4

27193—86—8

106—89—8

64—17—5

141—43—5c

141—78—6

141—97—9

140—88—5

75—04—7

100—41—4

74—96—4

9004—57—3

75—00—3

92—455

—16—

4~6G

.3.~:;z

~9

~9

~8O9

~8~9

~84 G

~9O9

4948

~93O

194G

49&G

•1980

~990

2000

2929

~O3O

2849

29~O

2969

29~G

~9~3

Q~9G

2~O

~

2150

2~6S

~

9

~

~9O

2~4G

2268

226k

105—39—5

105—56—6

74—85—1

 96—49—1

107—07—3

107—15—3

106—93—4

107—21—1

111—55—7

110—71—4

111—76—2

112—07—2

110—80—5

111—15—9

109—86—4

110—49—6

122—99—6

2807—30—9

75—21—B

60—29—7

104—76—7

122—51—0

95—92—1

41892—71—1

50—00—0

75—12—7

64—18—6

110—17—8

98—01—1

56—81—5

26545—73—7

25791—96—2

56—40—6

107—22—2

118—74—1

67—72—1

36653—82—4

124—09—4

629—11—8

100—97—0

74—90—8

123—31—9

99—96—7

26760—64—5

78—83—1

110—19—0

115—11—7

glycolmonoethyl

 ether

glycolmonomethyl ether

glycol monophenyl

glycolmonopropyl ether

oxide

Ethyl chioroacetate

Ethylcyanoacetate

Ethylene

Ethylene carbonate

Ethylene Chiorohydrin

Ethylenediarnine

Ethylene dibromide

Ethylene glycol

Ethylene glycol diacetate

Ethylene glycol dimethyl ether

Ethylene glycol monobutyl ether

Ethylene

glycol

monobutyl

ether

acetate

Ethylene glycol morioethyl ether

Ethylene glycolmonoethyl ether

acetate

Ethylene

 Ethylene

acetate

Ethylene

ether

Ethylene

Ethylene

Ethyl ether

2—ethyihexanol

Ethyl orthoformate

Ethyl oxalate

Ethyl sodium oxaloacetate

Formaldehyde

Formamide

Formic

acid

Fumaric acid

Furfural

Glycerol

 (Synthetic)

Glycerol

dichiorohydrin

Glycerol

triether

Glycme

Giyoxal

Hexachlorobenzene

Hexachioroethane

Hexadecyl alcohol

Hexamethylenediamine

Hexamethylene glycol

Uexamethylenete trarnine

hydrogen cyanide

Hydroquinone

p——be~e~e

 p—hydroxybenzoic

acid

Isoamylene

Isobutanol

Isobutyl acetate

Isobutylene

92—456

—17—

Isobutyraldehyde

Isobutyric

 acid

Isodecanol

Isooctyl alcohol

Isoperitane

Isophorone

Isophthalic

acid

Isoprene

Isopropanol

~O~f

 e~y~

Isopropyl acetate

Isopropylamine

Isopropyl chloride

Isopropyiphenol

Ketene

Linear ey~e~~e

 alkyl

sulfonate

Linear alkylbenzene

(Linear dodecylberizene)

Maleic acid

Maleic anhydride

Malic

 acid

Mesityl oxide

Metanilic acid

Methacrylic

 acid

Methallyl chloride

Methanol

Methyl acetate

Methyl acetoacetate

Methylamine

n—methylanil me

Methyl

bromide

Methyl butynol

Methyl chloride

Methyl cyclohexane

Methyl cyclohexartone

Methylerie chiôridè

Methylene dianiline

Methylene diphenyl diisocyanate

Methyl ethyl ketone

Methyl formate

Methyl

 isobutyl carbiriol

Methyl

 isobutyl ketone

Methyl methacrylate

Me~hy~~en~ync~1 Methylpentynol

a—methyistyrene

Morphol the

a—naphthalene sulfonic acid

B—naphthalene sulfonic acid

a—naphtho1

B—naphthol

Neopentanoic

 acid

22~8

 78—84—2

~288

 79-31—2

~38G

 25339—17—7

2320

 26952—21—6

232~

 78—78—4

~33G

 78—59—1

2340

 121—91—5

~SG

 78—79—5

~6G

 67—63—0

~3~G

2~&~

108—21—4

75—31—0

2~98

 75—29—6

~49G

 25168—06—3

~4~G

 463—51—4

~4~4

(b)

24~

 123—01—3

~4~O

 110—16—7

~43O

 108—31—6

244G

 6915—15—7

245G

 141—79—7

246O~

 121—47—1

~249

 79—41—4

~49G

 563—47—3

~5GO

 67—56—1

~S~9

 79—20—9

~S~9

 105—45—3

~539

 74—89--S

~549

 100—61—8

2545

 74—83—9

~55O

 37365—71—2

2560

 74—87—3

2S~O

 108—87—2

~S9G

 1331—22—2

~62O

 75—09—2

2639

 101—77—9

2635

 101—68—8

2648

 78—93—3

2644

 107—31—3

26&~

 108—11—2

266G

 108—10—1

26&S

 80—62—6

26~G

 77-75-8

~698

 98—83—9

Q~99

 110—91—8

85—47—2

120—18—3

23~

 90—15—3

2q49

 135—19—3

2~SO

 75—98—9

92—457

—18—

94—70—2

156—43—4

108—95—2

98—67--9,

585—38--6,

609—46--i,

133—39-~7c

91—40—7

(b)

75—44—5

85—44—9

85—41—6

 108—99—6

110—85—0

9003—29—6,

25036—29—7c

253 22—68—3

25322—69—4

123—38—6

79—09—4

71—23—8

107—10—8

540—54—5

115—07—1

127—00—4

78—87—5

57—55—6

75—56—9

110—86--i

106—51—4

o—nitroanil irie

p—nitroanilthe

o—nitroanisole

p—nitroanisole

Nitrobenzene

Nitrobenzoic

acid

(0,

Nitroetharie

Ni trometharie

2—Nitrophenol

Nitropropane

Nitrotoluerie

Nonene

Nei~’~phene~INonyiphenol

Oety~ ~iene~

Octyiphenol

Paraldehyde

Pentaerythritol

n—pentane

1—pentene

Perchloroethylene

Per~

Perchiorornethyl mercaptan

o—phenetid me

p—phenetidme

Phenol

Phenolsulfonic

acids

Phenyl

arithranilic

acid

Pheriylenediamine

Phosgene

Phthalic anhydride

Phthal imide

~b—p1co1 ine

Piperazine

Polybutenes

Polyethylene glyco.

Polypropylene glyco.

P~4e~e~tyde

Propional

dehyde

Propionic

acid

n—propyl

alcohol

 Propylamine

Propyl chloride

Propylene

Propylene chlorohyc3rin

Propylene

dichioride

Propylene glycol

Propylene oxide

Pyridirie

Quirione

88—74—4

100—01—6

91—23—6

100—17—4

98—95—3

2717 8—8 3—2 c

79—24—3

75—52—5

88—75—5

25322—01—4

1321—12—6

27215—95—8

25154—52—3

27193—28—8

123—63—7

115—77—5

109—66—0

109—67—1

127—18—4

594—42—3

2Th6

~

2999

28~8

2828

2830

2849

~8~9

2855

28~8

~89~9

29~9

2939

~94G

29?9

29~6

~9G8

a e

3925

30&3

3066

3680

3999

a~8o

a~o

~3i49

92—458

—19—

87—61—6,

108—70—3,

120—82—ic

71—55—6

79—00—5

79—01—6

75—69—4

96—18 —4

76—13—1

Resorcinol

Resorcylic

acid

 Salicylic

 acid

Sodium acetate

Sodium benzoate

Sodium ~

carboxymethyl

cellulose

Sodium chioroacetate

Sodium formate

Sodium pheriate

Sorbic acid

Styrene

Succinic acid

Succinitr ile

Sulfanilic acid

Sulfolane

Tannic acid

Terephthalic acid

Tetr achioroethanes

Tetrachlorophthalic

 anhydride

Pe~f~e~hyHe~d

 Tetraethyi

 1ea5

Tetr ahydronaphthalene

Tetrahydrophthalic anhydride

Te~y~e~

 Tetramethyl lead

Tetramethylenediamine

Tetramethylethyleried iarnine

Toluene

Tol uene—2

4—diamirie

Toluene—2 ,4—diisocyanate

Toluene diisocyanates

 (mixture)

Toluene sulfonamide

Pe~efle

 ~?er~4e Toluenesulfonic

acids

Toluene

 eiiy~e’er4~e

sulfonyichioride

Toluidines

Tr ichioroberizenes

1,1, 1—trichioroethane

1,1, 2—tr ichioroethane

Tr ichioroethylene

Tr ichlorofluoromethane

1,2, 3—trichioroproparie

1,1,2—trich1oro~7—

1,2, 2—tn fluoroethane

Tr iethylamine

Triethylene glycol

Triethylene

 yeo~t~ethy~glycol

dimethyl ether

Tr i isobutylerie

3~5

 3~6~

3228

~239

3249

3259

a~s~

3260

32~9

329G

39G

~320

3330

3335

334G

34~

~349

3354

335S

10 8—4 6—3

27138—57—4

69—72—7

127—09—3

53 2—3 2—1

9004

—3 2—4

39 26—6 2—3

141—53—7

139—02—6

110—44—1

100—42—5

110—15—6

110—61—2

121—57—3

126—33—0

1401—55—4

100—21—0

79—34—5c

117—08—8

78—00—2

119—64—2

85—43—8

75—74—1

110—60--i

11O-18—9

10 8—8 8—3

95—80—7

584—84—9

264

7 1—6 2—5

133 3—0

7—9

104—15—4c

~&~

~8G

 98—59—9

26915—12--8

338~7 3399

~9S

3400

34~

3429

3439

345G

a4&e

.34~

121—44—8

112—27—6

112—49—2

775 6—94—7

92—459

—20—

___

methyl

tert

—butyl ether

__________

 Polyethylene

____

 Polypropylene

__________

 Polystyrene

Phe O~PBB

rttii~èers

~e

 referet’~e~4i~4ee~

 ~4gned

 ~e the

v4~et~she~e~r~

 4r~~he ergart4e ehem4e~4Predttee~Ba~

Be~edeveloped by ~A~teUS~FA~-

a)

 CAS numbers

 refer

 to the Chemical Abstracts

 Regist.ery

numbers assigned

 to specific chemicals,

 isonomers or

mixtures of chemicals.

 Some isomers or mixtures that

are covered by the standards do not have CAS numbers

assigned

 to them.

 The standards apply to all

 of the

chemicals listed, whether CAS numbers have been assigned

or

 not.

b)

 No CAS number(s)

 have been assigned

 to this chemical,

to

its isomers,,

 or mixtures containing

 these chemicals.

 CAS numbers

 for some of the isomers are listed:

the

standards

apply

 to all

 of the isomers and mixtures,

 even

if CAS numbers have not been assigned.

(Source:

Amended

Ill.

Reg.

_______

effective

____________

IT

 IS SO ORDERED.

I, Dorothy

 M. Guna, Clerk of

 the Illinois Pollution Control

Board

 hereby certif~th~tthe above Order was adopted on

the

_____

 day of

~

 1988,

 by a vote of

7_C

Y2~

/~~/

Dorothy M./Gunri, Clerk

Illinois Pollution Control Board

3499

~5~:9

35~8

~530

354°

S

3589

3S99

75—50—3

57—13—6

108—05—4

75—01—4

75—35—4

2 50 13—15—4

133 0—20—7

9 5—4 7—6

106—42—3

1300—71—6

1300—73—8

(b)

9002—88—4

(b)

9009—53—6

Trimethylamine

Urea

Vinyl

acetate

Vinyl chloride

Vinylidene chloride

Vinyl

 toluerie

Xylenes

 (mixed)

o—xylene

p-

xylene

Xylenol

Xylidine

92—460