ILLINOIS POLLUTION CONTROL BOARD
    April 11,
    1991
    IN
    THE
    MATTER OF:
    )
    R91—1O
    EXEMPTIONS FROM THE
    )
    (Identical
    in Substance Rules)
    DEFINITION OF VOM
    )
    PROPOSAL FOR PUBLIC COMMENT
    PROPOSED OPINION AND ORDER OF THE BOARD
    (by J. Anderson):
    The Board hereby proposes to amend its rules
    in response to
    USEPA additions to the list of chemicals exempted from the
    definition of volatile organic materials
    (VOMs)1.
    At 56
    Fed.
    Reg.
    11418, March 18,
    1991,
    USEPA added five compounds and four
    classes
    of compounds to the list of negligibly photoreactive
    compounds exempt from regulation under state implementation plans
    (SIPS).
    Those compounds constitute additions to those compounds
    exempted in R89-8, effective January
    1,
    1990.
    The Board directs
    attention to that prior docket for information relating to the
    original listing of exempted compounds.
    This Proposal for Public Comment
    is adopted pursuant to the
    identical-in-substance mandate under Section 9.1(e)
    of the
    Environmental Protection Act,
    Ill.
    Rev.
    Stat.
    1989,
    ch. 1ll~,
    par.
    1009.1(e).
    Section 9.1(e) provides for quick adoption of
    regulations which are “identical in substance” to certain
    published federal policy statements and that Title VII of the Act
    and Section 5 of the Administrative Procedure Act
    (APA)
    shall not
    apply.
    Because this rulemaking
    is not subject to Section
    5 of
    the APA,
    it is not subject to first notice or to second notice
    review by the Joint Committee on Administrative Rules
    (JCAR).
    The Federal Register citation to the revision in the federal
    policy statement used in this Opinion and Order is as follows:
    56
    Fed. Reg.
    11418
    March
    18, 1991
    The revision to USEPA’s “Recommended Policy on the Control
    of Volatile organic Compounds” adds five compounds and four
    classes of compounds to the list of negligibly-photochemically-
    reactive compounds exempted from regulation as volatile organic
    compounds.
    SUBMITTING
    PUBLIC
    COMMENTS
    The
    Board
    will
    submit
    this
    proposal
    for
    public
    comment
    in
    the Illinois Register.
    The statutory public comment period will
    1
    USEPA
    consistently
    designates
    these
    “volatile
    organic
    compounds1’ or “VOCs.”
    Both designations refer to the same matter,
    and all references in this Opinion and Order to “VON” refer to what
    USEPA calls
    “VOC.”
    12 1—557

    2
    end 45 days after the date of publication in the Illinois
    Register.
    In the course of the following discussion,
    the Board
    invites comment on several specific aspects of this proposal.
    It
    is important that commenters make their submissions promptly and
    directly to the Board,
    so the Board can obtain the benefit of
    their input.
    HISTORICAL SUMMARY
    The Board adopted the original federal recommended policy
    statements and several subsequent revisions in October,
    1989:
    R89—8
    104 PCB 505, October
    18,
    1989;
    13
    Ill.
    Reg.
    17457,
    effective October 27,
    1989.
    The Federal Register issues included
    in that docket are recited
    in that Opinion and Order.
    DISCUSSION
    At
    56 Fed.
    Reg.
    11418, March 18,
    1991, USEPA announced
    a
    change in its “Recommended Policy on the Control of Volatile
    Organic
    Compounds,”
    adding
    five
    halocarbon
    compounds
    and
    four
    classes
    of
    perfluorocarbon
    compounds
    to
    the
    list
    of
    negligibly
    photoreactive
    compounds
    exempt
    from
    regulation
    under
    state
    implementation
    plans.
    Those
    compounds
    are
    as
    follows:
    1.
    2-chloro-1,l,1,2—tetrafluoroethane
    (HCFC-124)
    2.
    Pentafluoroethane
    (HFC—l25)
    3.
    l,l,2,2-tetrafluoroethane
    (HFC-134)
    4.
    1,1, 1-trifluoroethane
    (HFC-143a)
    5.
    1,l-difluoroethane
    (HFC-152a)
    Those
    classes
    of
    compounds
    are
    as
    follows:
    1.
    Cyclic,
    branched,
    or
    linear,
    completely
    fluorinated
    alkanes.
    2.
    Cyclic,
    branched,
    or
    linear,
    completely
    fluorinated
    ethers
    with
    no
    unsaturations.
    3.
    Cyclic,
    branched,
    or
    linear,
    completely
    fluorinated
    tertiary
    amines
    with
    no
    unsaturations.
    4.
    Sulphur-containing
    perfluorocarbons
    with
    no
    unsaturations
    and
    with
    sulfur
    bonds
    only
    to
    carbon
    and
    fluorine.
    121—558

    3
    Under
    this
    policy,
    states
    may
    not
    take
    credit
    for
    controlling
    these
    compounds in their ozone state implementation plans.
    USEPA
    simultaneously proposed to amend the federal implementation plan
    (FIP)
    for Chicago and to amend 40 CFR 51 to add a general
    definition of VOM consistent with its policy revision.
    56
    Fed.
    Reg.
    11387
    (Mar.
    18,
    1991).
    USEPA stated that it would withdraw
    its policy revision as moot when it finally adopts such a
    definition of VOM as a regulation.
    56 Fed. Reg.
    at 11388
    &
    11419.
    The federal revision of its recommended policy raises an
    initial issue relating to whether the Board should proceed with
    adoption of the proposed rule pursuant to Section 9.1(e).
    As
    discussed
    in the Board’s October
    18,
    1989 Opinion and Order in
    R89-8, the initial adoption of exemptions from the definition of
    VOM
    resulted
    from
    a
    specific
    legislative mandate.
    At that time,
    the legislative mandate arose out of a desire to include in Board
    rules the then-current list of chemicals exempted by USEPA under
    its recommended policy statements.
    The language of the
    authorizing legislation was open—ended, mandating future action
    in
    response
    to
    any
    future
    USEPA
    policy
    revisions:
    The
    Board
    shall
    exempt
    from
    regulation
    under
    the
    State
    Implementation Plan for ozone the volatile organic
    compounds which have been determined by the U.S.
    Environmental Protection Agency to be exempt from
    regulation under state implementation plans for ozone
    due to negligible photochemical reactivity.
    In
    accordance with subsection
    (b)
    of Section
    7.2, the
    Board shall adopt regulations identical in substance to
    the U.S. Environmental Protection Agency exemptions
    or
    deletion
    of
    exemptions
    published
    in
    policy
    statements
    on the control of volatile organic compounds in the
    Federal
    Register
    by
    amending
    the
    list
    of
    exemptions
    to
    the Board’s definition of volatile organic material
    found
    at
    35
    Ill.
    Adm.
    Code
    Part
    211.
    .
    .
    .
    The
    Board
    i-nay
    consolidate
    into
    a
    single
    rulemaking
    under
    this
    subsection
    all
    such
    federal
    policy
    statements
    published
    in the Federal Register within a period of time not to
    exceed
    6
    months.
    Ill.
    Rev.
    Stat.
    1989,
    ch.
    111~, par.
    1009.1(e).
    USEPA effected the revision to its recommended policy
    statement
    and
    simultaneously
    proposed
    a
    general
    definition
    of
    “volatile
    organic
    compound”
    on
    the
    same
    date.
    See
    56
    Fed.
    Reg.
    11387
    &
    11418
    (Mar.
    18,
    1991).
    The
    proposed
    general
    definition
    would
    codify
    the
    substance
    of
    the
    recommended
    policy
    statement.
    In
    both
    the
    respective
    discussions
    of
    the policy revision and the
    proposed
    definition,
    USEPA
    stated
    that
    its
    intent
    is
    to
    withdraw
    the recommended policy statement as moot when it adopts the
    general
    definition.
    121—559

    4
    Although withdrawal of the recommended policy after final
    adoption of the general definition would have no effect on the
    status
    of
    any
    of
    the
    exempted
    compounds
    in
    the
    federal
    scheme,
    the withdrawal raises several issues,
    including whether the Board
    should proceed with adoption of this rulemaking.
    The mandate of
    Section
    9.1(e) pertains to the recommended federal policy,
    not
    to
    federal rules.
    If USEPA withdraws its policy statements as moot,
    must the Board then repeal the exemptions from the definition of
    volatile organic materials?
    Further,
    if USEPA should add or
    delete exempt compounds by future rulemakings, do those actions
    fall within the scope of the Section 9.1(e) mandate?
    If not,
    should the
    Board
    seek
    a
    revision
    in
    the
    language
    of
    Section
    9.1(e)?
    If the Board should pursue
    a legislative amendment, what
    statutory language should it pursue?
    The Board
    invites comment
    on these issues.
    USEPA
    effected
    part
    of
    the
    revision
    to
    its
    policy
    statement
    in response to
    a petition by the Alliance for Responsible CFC
    Policy.
    On
    January
    18,
    1989,
    at
    54
    Fed.
    Reg.
    1987,
    USEPA
    partially
    responded
    to
    the
    petition
    by
    adding
    four
    non—fully-
    halogenated CFCs to the list of negligibly-reactive compounds.
    That
    was,
    in
    part,
    the
    subject
    of
    R89-8.
    The
    Alliance
    stated
    in
    justification of its petition that these CFC substitutes are less
    photochemically reactive than others already on USEPA’s list of
    negligibly—reactive compounds and that USEPA must remove barriers
    to the use of CFC substitutes
    if the U.S.
    is to meet its
    commitments
    under
    the
    Montreal
    Protocol
    on
    Substances
    that
    Deplete
    the
    Ozone
    Layer.
    Minnesota
    Mining
    and
    Manufacturing
    Co.
    (3M)
    submitted
    a
    petition
    to
    USEPA
    requesting
    addition
    of
    the
    four
    classes
    of
    compounds
    included
    as
    the
    other
    part
    of
    the
    policy
    statement
    revision.
    3M
    also
    requested
    that
    USEPA
    take
    action
    to
    include
    these
    classes
    as
    part
    of
    the
    Chicago
    FIP
    and
    act
    to
    assure
    that
    they become part of any future SIP.
    3M justified its petition by
    asserting
    that
    these
    classes
    of
    compounds
    are
    not
    photochemically
    reactive
    in
    the
    troposphere,
    that
    they
    do
    not
    deplete
    stratospheric
    ozone,
    that
    they
    are
    generally
    non—toxic
    to
    humans
    and
    the
    environment,
    and
    that
    they
    can
    act
    as useful CFC
    substitutes.
    In effecting the revision, USEPA stated that only one
    compound
    (HCFC-l24) had any chlorine or bromine atoms
    which
    contribute
    to
    stratospheric
    ozone
    depletion.
    USEPA
    agreed
    that
    there
    is
    a
    need
    to
    remove
    barriers
    to
    the
    use
    of
    acceptable
    CFC
    substitutes like those in the petitions.
    On
    this
    basis,
    USEPA
    revised its policy and exempted the five compounds and four
    classes of compounds.
    Therefore,
    USEPA’S policy is not to
    enforce or approve controls on these compounds,
    and it “will rely
    on the revised policy
    in considering all future approvals or
    promulgations of implementation plan provisions
    .
    .
    .
    .“
    56 Fed.
    121—560

    5
    Reg.
    at
    11419.
    However,
    the
    USEPA
    policy
    revision
    raises
    other
    important
    issues for the Board.
    These relate to the balance between the
    Board’s identical—in—substance mandate on the one hand and
    USEPA’s
    expressly-reserved
    flexibility
    to
    deviate
    from
    the
    policy
    on
    a case-by—case basis on the other.
    As
    noted
    below,
    USEPA
    is
    free
    to
    deviate
    from
    it
    and
    impose
    monitoring of emissions of the exempted compounds on a case—by-
    case basis, although USEPA has no present intent to do so.
    USEPA
    stated:
    Of course, because this revised policy statement is not
    a binding regulation,
    EPA remains free at this time to
    depart from it in evaluating the merits of any
    particular rule regarding control of tropospheric
    ozone.
    However, because EPA believes that such case—
    by—case consideration is unnecessary,
    in the proposal
    being published today, EPA is also proposing to codify
    in
    40
    CFR 51
    a general definition of VOC for all SIP
    development
    purposes
    that
    would
    exempt
    all
    of
    the
    compounds
    on
    the
    nonreactive
    list
    being
    revised
    by
    today’s
    policy
    statement.
    Should
    EPA
    adopt
    that
    proposal as a final regulation, there would be no need
    to consider reactivity of the listed compounds on a
    case—by—case
    basis
    .
    USEPA
    further
    stated:
    It
    is important to note that the proposed
    40
    CFR 51
    general definition of VOC includes a provision
    that allows EPA or the State to require a source owner
    or operator,
    as a precondition to excluding negligibly-
    reactive compounds for purposes of determining
    compliance,
    to
    provide
    monitoring
    methods
    and/or
    monitoring
    results
    demonstrating
    to
    the
    satisfaction
    of
    EPA
    or
    the
    State,
    the
    amount
    of
    negligibly-reactive
    compounds
    in
    the
    source’s
    emissions.
    .
    .
    .
    As
    discussed in the preamble to the proposed rule,
    the
    situations where such information may be needed
    typically involve emissions from streams where
    (1)
    VOC’s and negligibly—reactive compounds are mixed
    together,
    or
    (2)
    there are a large number of
    negligibly-reactive compounds or the chemical
    composition of some of the negligibly-reactive
    compounds
    is
    not
    known.
    56
    Fed.
    Reg. at 11419-20.
    A
    USEPA
    footnote
    on
    this
    section
    in
    the
    Federal
    Register
    states
    that
    “in
    any
    situation
    where
    a
    State
    allows
    a
    source
    to
    exclude
    121—561

    6
    any of these negligibly—reactive compounds,
    EPA would retain
    independent authority to request a source to provide monitoring
    methods
    and/or
    monitoring
    results
    demonstrating,
    to
    the
    satisfaction
    of
    EPA,
    the
    amount
    of
    negligibly-reactive
    compounds
    in the source’s emissions.”
    56
    Fed. Reg.
    at 11419,
    note
    1.
    Proposed
    40 CFR 51.100(s)
    states that volatile organic
    compounds include all compounds that participate in atmospheric
    photochemical
    reactions
    other
    than
    the
    several
    listed
    from
    the
    recommended policy statement.
    The definition goes on to state:
    An
    owner
    or
    operator
    may
    exclude
    these
    negligibly-
    reactive compounds when determining compliance with an
    emissions standard.
    However,
    USEPA
    or the State may
    require such owner or operator, as
    a precondition to
    excluding these compounds for purposes of determining
    compliance,
    to
    provide
    monitoring
    methods
    and
    monitoring
    results
    demonstrating
    .
    .
    .
    the
    amount
    of
    negligibly-reactive
    compounds
    in
    the
    source’s
    emissions.
    56
    Fed.
    Reg.
    at
    11390.
    Thus,
    USEPA
    can
    require
    monitoring
    for
    exempted
    compounds
    as
    a
    permit condition despite the general exemption,
    and the states
    may
    reserve
    such
    authority
    in
    their
    rules.
    This raises the issue as to whether it is desireable for the
    Board to include similar language in the text of its definition
    of volatile organic material at 35 Ill.
    Adm. Code 211.122.
    Illinois law requires the Board to codify its rules of general
    applicability.
    The Board risks appellate court invalidation of
    any policy the Agency attempts to apply without the formal
    process of codification.
    ~
    Senn Park Nursing Center
    v.
    Miller,
    118 Ill. App.
    3d 504,
    455 N.E.2d
    153
    (1st Dist.
    1983), aff’d
    104
    Ill.
    2d
    169,
    470 N.E.2d 1069
    (1984).
    Therefore,
    application of
    any policy on a case—by—case basis might require codification
    under Illinois law.
    If such codification of this case-by-case
    reservation is desireable, does the identical-in—substance
    authority of Section 9.1(e)
    extend to adoption of such a
    reservation, whether based on the text of the recommended policy
    statement,
    see 56 Fed.
    Reg. at
    11419—20, or on the text of the
    proposed federal rule when adopted?
    The Board proposes language expressly reserving the Agency’s
    prerogative to require monitoring under the conditions discussed
    by USEPA.
    The Board proposes incorporating this language in a
    new Section 215.108, among the general provisions
    of the Part of
    the Board’s rules that regulates volatile organic emissions.
    The
    Board further incorporates into the proposed amendments to
    Section 211.122 a Board note that references Section 215.108 and
    the recommended policy statement
    (or, alternatively,
    40 CFR
    121—562

    7
    51.100(s)
    if this rule is adopted by USEPA) wherein USEPA
    reserves the right
    in itself to require monitoring of exempted
    compounds as a precondition to exemption.
    In including an express authorization for the Agency to
    require monitoring for the exempted compounds among the general
    provisions of Part 215 for the purposes of public comment, the
    Board raises two issues relating to its identical—in-substance
    authority under Section 9.1(e).
    First,
    should the Board include
    the express USEPA reservations along with the general exemption
    that Section 9.1(e)
    requires the Board to adopt?
    Second,
    assuming the Board should include the express reservation, does
    Section 9.1(e)
    authorize the Board to adopt an amendment to Part
    215 that would embody the USEPA reservations?
    Third, assuming
    the Board should include the express reservation, should that
    reservation take the form of the conditions outlined in USEPA’s
    discussion
    of the situations in which it might require
    monitoring?
    The Board’s approach in drafting this proposal for
    public comment was the use of limiting terms in Section 215.108,
    based on the USEPA discussion of the situations under which it
    might impose a requirement for monitoring.
    USEPA’s discussion
    appears to use those situations as non—limiting examples,
    so
    other situations could cause USEPA to impose monitoring for the
    exempted compounds.
    Is there an alternative the Board could use
    in drafting this Section that would use non-limiting terms that
    are acceptable under Illinois administrative law?
    The Board
    invites comment on these issues.
    In the interest of cleaning up the present text of the
    definition,
    the Board notes that the names of compounds listed in
    the present definition appear in alphabetical order with one
    exception:
    Dichloromethane.
    This compound is out of order
    because the Board amended the entry in R89-8 to use the IUPAC
    name for Methylene Chloride, the.pre-existing entry.
    In the
    course of placing the instant five compounds in alphabetical
    order,
    the Board also places Dichloromethane in the proper order.
    ORDER
    The Board hereby proposes the following amendments to its
    definition of volatile organic material at 35 Ill. Adm. Code
    211.122 and new section 35 Ill. Adm. Code 215.108:
    Section 211.122
    Definitions
    “Volatile Organic Material” or “Volatile Organic
    Material Content (VONC)”:
    the emissions of volatile
    organic material which would result from
    the
    exposure
    of a coating, printing ink, fountain solution, tire
    spray, dry cleaning waste or other similar material to
    121—563

    8
    the air, including any drying or curing,
    in the absence
    of any control equipment.
    VOMC is typically expressed
    as kilogram
    (kg) VOM/liter
    (lb VON/gallon)
    of coating
    or coating solids,
    or kg VON/kg
    (lb VOM/ib)
    of coating
    material.
    Any organic material which participates in
    atmospheric photochemical reactions unless
    specifically exempted from this definition.
    Volatile organic material emissions shall be
    measured by the reference methods specified under
    40 CFR 60, Appendix A
    (1986)
    (no future amendments
    or editions are included),
    or,
    if no reference
    method is applicable, may be determined by mass
    balance calculations.
    For purposes of this definition,
    the following are
    not volatile organic materials:
    Chlorodifluoroethane (HCFC-142b)
    Chiorodifluoromethane
    (CFC-22)
    Chloropentafluoroethane (CFC-1l5)
    2—Chloro—1 ,1,1, 2-tetrafluoroethane (HCFC—l24)
    Dichlorodifluoromethane (CFC-l2)
    Dichlorofluoroethane
    (HCFC-l4lb)
    Dichloromethane
    (Methylene chloride)
    Dichiorotetrafluoroethane (CFC-1l4)
    Dichlorotrifluoroethane (HCFC-l23)
    1, 1-Difluoroethane
    (HFC—152a)
    Ethane
    Methane
    Dichioromethane
    (Mcthylenc chloride)
    Pentafluoroethane
    (HFC-125)
    Tetrafluoroethane
    (HFC-l34a)
    1,1,2,2—Tetrafluoroethane
    (HFC-l34)
    Trichloroethane
    (Methyl chloroform)
    Trichlorofluoromethane
    (CFC-11)
    Trichlorotrifluoroethane (CFC-113)
    1,1,1-Trifluoroethane (HFC-l43a)
    Trifluoromethane
    (FC-23)
    and the following classes of compounds:
    Cyclic,
    branched,
    or linear, completely
    ~luorinated alkanes.
    Cyclic, branched,
    or linear, completely
    fluorinated ethers with no
    unsaturations.
    Cyclic,
    branched,
    or linear~comp1e~~y
    fluorinated tertiary amines with no
    12 1—564

    9
    unsaturations.
    Sulphur—containing perfluorocarbons with
    no unsaturations and with sulfur bonds
    only to carbon and fluorine.
    BOARD NOTE:
    USEPA or the Agency may
    reguire monitoring to demonstrate the
    amount of an exempted compound in
    a
    source’s emissions on a case—by—case
    basis as a pre—condition to exemption of
    that compound under certain
    circumstances,
    such as where VOMs and
    exempted compounds are mixed together,
    there are a large number of exempted
    compounds,
    or the chemical composition
    of the exempted compounds is not known.
    See 35
    Ill. Adm. Code 215.108;
    56 Fed
    Reg. 11419—20.
    121—565

    10
    Section 215.108
    Monitoring for Negligibly-Reactive Compounds
    ~y
    provision
    of
    Part 211 notwithstanding,
    the Agency may require
    monitoring
    for any of the compounds listed at 35
    Ill.
    Adm. Code
    211.122 as exempted from the definitioD of “volatile organic
    material,” as a precondition to such exemption,
    under any of the
    following circumstances:
    ~j
    Where VOMs and exempted compounds are mixed together in
    the
    same
    emissions
    ki
    Where
    there
    are
    a
    large number of exempted compounds
    in
    the same emissions;
    or
    gj
    Where the chemical composition of the exempted
    compounds
    in the emissions is not known.
    IT IS SO ORDERED.
    I, Dorothy M.
    Gunn,
    Clerk of the Illinois Pollution Control
    Board,
    do
    hereby
    certif~j
    thji
    the above Order was
    adopted
    on
    the
    //~~
    day
    of
    _____________,
    1991,
    by a vote of
    ________
    ~7o~i~1
    ~
    /LI
    Dorothy N.
    9~(nn, C erk
    Illinois
    Pc~Ylution Control
    Board
    121—566

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