ILLINOIS POLLUTION CONTROL BOARD
    February 7,
    1991
    MARATHON PETROLEUM COMPANY,
    )
    Petitioner,
    v.
    )
    PCB 90—126
    )
    (Permit Appeal)
    ILLINOIS ENVIRONMENTAL
    )
    PROTECTION AGENCY,
    )
    )
    Respondent.
    OPINION AND ORDER OF THE BOARD
    (by J. Anderson):
    This matter comes before the Board on Marathon Petroleum
    Company’s (“Marathon”) permit modification appeal filed on July
    3,
    1990.
    On September
    28, 1988 Marathon was granted a RCRA
    (Resource Conservation and Recovery Act) Part B permit pursuant
    to Section
    39(d) of the Act for a land treatment facility
    in
    regards to its Robinson oil refinery located in Crawford
    County.
    On January
    26,
    1990 Marathon submitted a number
    of
    modifications
    to the Illinois Environmental Protection Agency
    (“Agency”)
    in an attempt to alter some of the terms and
    conditions of that permit.
    Many of these highly technical issues
    were negotiated and subsequently resolved and, as a result,
    the
    parties filed a partial settlement agreement with the Board on
    November
    1,
    1990.
    Having only two disputed issues remaining,
    Marathon filed this appeal pursuant to
    35 Ill.
    Adm. Code Section
    705.128 and hearing was held on October
    30,
    1990.
    For the
    following reasons,
    the Board affirms the Agency’s decision to
    retain the permit conditions which Marathon contests.
    Before the Board addresses the permit conditions at issue
    in
    today’s case, We will briefly touch upon the partial settlement
    agreement
    filed by the parties.
    While Section 40 of the Act
    provides for Board review of permit appeals,
    the Agency is
    charged with the initial determination as to whether the permit
    conforms with the Act and the regulations thereto.
    ...the applicant shall apply to the Agency for
    such permit and it shall be the duty of the
    Agency to issue such a permit upon proof by
    the applicant that the facility,...will
    not
    cause a violation of this Act or of
    regulations hereunder.
    Ill.
    Rev.
    Stat. 1989, Chap. l11~,par.
    1039(a).
    Accordingly,
    when the Agency and a permittee enter
    into an
    agreement as
    it
    relates to a factual
    issue
    for
    a permit or
    a
    condition thereof,
    ratification by the Board
    is unnecessary.
    118—239

    —2—
    With regard to those challenges properly before
    the Board,
    Marathon’s first
    issue of concern involves the measurement of two
    specific volatile organics.
    Marathon states that methyl ethyl
    ketone (“MEK”) and tetrahydrofuran
    (“THF”) are being detected in
    unsaturated zone samples of pore water during quarterly
    monitoring.
    Marathon alleges that the source of these volatile
    organics
    stern from the polyvinylchloride
    (PVC)
    cement used in the
    lysimeter construction, as opposed to the wastestream
    constituents generated by the oil refinery.
    Based on this,
    Marathon’s request
    is to incorporate a permit modification
    precluding MEK and THF from being compared with the respective
    background concentrations
    *
    In support
    of this contention, Marathon introduced a study
    performed by its consultant Radian Corporation
    (Petitioner’s
    Exhibit #2).
    This exhibit was introduced into evidence by the
    hearing officer over the Agency’s objection.
    The Agency
    contended that the only admissible evidence
    is that which was
    before the IEPA at the time the decision was made to deny the
    permit request.
    We agree.
    Therefore,
    the ruling of the hearing
    officer
    is overruled and the objection is sustained.
    35
    Ill. Adm. Code Section 705.128 governs modifications of
    RCRA permit modifications.
    Subsection
    (b)
    of the Code states:
    If the Agency decides the request
    is not
    justified,
    it shall send the requester
    a brief
    written response giving a reason for the
    decision.
    Denials of requests for
    modification are not subject to public notice,
    comment or hearings.
    Denial of the request to
    modify may be appealed to the Board pursuant
    to 35
    Ill. Adm. Code 105.
    The courts as well as the Board have had ample opportunity to
    interpret the provisions of
    35
    Ill. Mm.
    Code Section 105.
    It
    is
    well-settled that at a hearing before the Board to contest a
    denial of
    a permit,
    the sole question before the Board is whether
    the applicant proves that the application, as submitted to the
    Agency, demonstrated that no violation of the Act would have
    occurred if the requested permit had been issued.
    EPA v.
    Pollution Control Board, 104 Ill.
    Dec.
    786
    (1986); Joliet Sand
    and Gravel
    v. Pollution Control Board, PCB 86—139
    (February
    5,
    1987), affm,
    516 N.E.2d 955 (3rd Dist.
    1987).
    See also,
    35
    Ill.
    Adm. Code 105.103(2).
    Accordingly,
    the only evidence the Board
    will review is that which the Agency had access to at the time of
    its decision.
    Even without Petitioner’s Exhibit
    2,the Agency did have
    before
    it Marathon’s assertion that the presence of MEK and THF
    is being caused by
    the PVC glue used in lysimeter construction.
    Marathon represents that MEK has not been detected
    in any wastes
    118—240

    —3—
    applied to the land treatment facility and that a literature
    search indicated that PVC cement used in lysimeter construction
    had as common constituents both MEK and THF.
    Marathon maintains
    that, although the soil—pore liquid sample never comes in contact
    with the PVC cemented joints,
    the polyethylene tubing used for
    sample collection
    is permeable to MEK and THF resulting
    in
    contamination of
    the soil—pore samples.
    Based on the conclusion that the detection of MEK and THF in
    soil—pore samples
    is due to the PVC cement, Marathon requested
    a
    modified protocol
    for sampling
    in its permit application.
    According
    to this modified protocol, the first samples to be
    collected from the lysimeters are to be tested for metals,
    total
    organic carbon and semi—volatile organics, but not for volatile
    organics
    (which include MEK and THF).
    Before a sample for
    volatile organics is collected, distilled water
    is to be drawn
    through the lysimeter.
    The first action is
    intended to flush the
    lysimeter and remove MEK which has accumulated in the vacuum
    lines and lysimeter body.
    The second distilled water wash is
    intended to flush out the remaining MEK from the system.
    The
    protocol also included some additional details of how the
    flushing
    is
    to be carried out.
    Prior to
    the Agency decision, an Agency reviewer had
    attempted to obtain information from Marathon regarding the MEK
    detection.
    On April 19, 1990, Agency reviewer,
    listed as DWD,
    spoke with David Saad and Vicki May of Marathon to ask about
    the
    MEK problem.
    The reviewer was told that MEK had not been
    analyzed prior
    to 1988 and that he did not know off—hand what the
    measured concentrations were,
    but
    it was suggested that he speak
    with Mike Holder of Radian Corporation.
    (See Agency Record pp.
    620).
    A second conversation was held on April 19,
    1990 by DWD
    with Mike Holder and Lynn Zimmerman from Radian Corporation who
    said that MEK was being detected in concentrations no greater
    than
    5 times
    the detection limit and provided the same reasons as
    in this petition for a modification
    to the sampling protocol.
    It
    was also indicated that they (Holder
    & Zimmerman) had
    4 tables
    showing that the MEK was from the tubing, and not from the water,
    would be faxed to the Agency.
    (Agency Record pp.
    621).
    It is
    not clear
    if any tables were sent by Marathon or
    received by the
    Agency and whether such information was utilized in the Agency’s
    decision.
    The review notes from DWD also note that he questions
    the modified protocol and that after speaking with Cindy Davis
    and Ken Liss
    (also Agency permit reviewers), he thought that the
    proposed protocol for flushing out MEK would result
    in the loss
    of volatile organics.
    In the Agency letter, approving some modifications and
    disapproving others, dated May
    29, 1990
    (Agency Exhibit 8),
    the
    Agency states that Marathon did not provide all of the background
    data collected to date
    to show that the problem
    (of MEK
    detection) has been reoccuring and that Marathon had not proved
    118—24 1

    —4—
    that the problem is due to the cement from the PVC pipe.
    The
    Agency recommended the replacement of the PVC pipe and tubing,
    use ofthreaded connections for PVC pipe and use of Teflon
    for
    the tubing.
    The testimony of Cindy Davis—Vilson, who reviewed
    the application, repeated the recommendation and indicated that
    the sampling protocol requested by Marathon would not provide a
    representative sample of the volatiles present in the soil—pore
    liquid.
    (Tr. pp. 75—77).
    Ms. Davis also testified that while
    waste analysis shows no MEK, such waste analysis was not
    conducted prior
    to 1984.
    The absence of MEK in the refinery wastestream coupled with
    the literature review regarding PVC cement constituents provides
    some indication for suspecting the cement as the source of the
    MEK and the THF in the soil—pore samples.
    Even assuming that
    enough information was given to
    identify the cement as the cause
    of the MEK and THF present
    in soil-water,
    however, Marathon has
    not shown that the sampling protocol modification requested will
    be effective
    in completely removing all the MEK and THF and that
    it would not affect the representativeness of samples so
    collected with regard to the volatile components
    in the soil—pore
    water.
    Based upon the information within the record,
    the Board
    is satisfied that the petitioner failed to carry its burden
    pursuant to Section
    40 of the Act
    in addition to the Board’s
    rules
    (Ill.
    Adm. Code 105.102;) regarding permit reviews of
    hazardous waste disposal sites.
    As such,
    the Agency’s denial of
    the permit modifications as
    it pertains
    to Marathon’s request
    for
    an alternative protocol for the sampling of MEK and THF
    in the
    soil—pore samples
    is affirmed.
    Lastly,
    in their Brief dated December
    11, 1990, Marathon has
    asked that any measurements of MEK not be statistically compared
    with the background values.
    This
    is not part of the sampling
    protocol modification requested in the original application.
    Further such a change would only be possible if Marathon had
    shown that the presence of MEK and THF
    in the lysimeter samples
    do not affect the representativeness of the collected sample or
    the concentration of other constituents of interest.
    The second issue that could not be settled arises because,
    under the present permit, the Agency requires that Marathon use a
    statistical procedure called the average replicate t—test
    (“t—
    test”)
    for groundwater analysis and comparison with the
    background.
    Marathon characterizes the t—test as “essentially a
    probability equation which predicts one event
    into the future”
    (Tr. pp.
    46—48).
    Marathon alleges that
    a “moving window”
    analysis would be more appropriate
    in that
    it would provide for
    necessary change during the life of the facility.
    The company
    further argues that the “moving window” procedure would allow for
    potential changes
    in background levels by averaging the four most
    current samples and prevent the inappropriate use of the t—test,
    which presently requires the samples to be measured against the
    original background.
    118—242

    —5—
    The Agency, on theother hand, argues that the first year of
    background data was incorrectly collected and thus the period for
    ascertaining this information has been extended for one year.
    It
    is therefore the Agency’s position that this issue is not ripe
    for a decision until the full two years of background sampling is
    completed and statistically analyzed.
    The Agency also professes
    that theories of various statistical procedures can be argued
    anytime, but their actual application and effect on a particular
    site’s data cannot be known without the actual data and the
    analysis thereof.
    Once the two years of data are obtained,
    Marathon can propose to the Agency an alternative statistical
    procedure as allowed by Marathon’s
    RCRA
    Part B permit pursuant to
    35
    Ill. Adm. Code Section 724.197(h)
    and
    (i).
    The Board first notes that
    it is unable
    to see any reference
    to the “moving window” procedure
    in either Marathon’s application
    for modification within the Agency record.
    Assuming, however,
    that the “moving window” method for determining background was
    before the Agency
    in this modification request,
    the Board agrees
    with the Agency.
    The statistical procedure in dispute
    is
    designed
    to compare the measured concentration of
    a constituent
    in a sample with the background concentration of that
    constituent.
    Marathon’s characterization of the t-test as
    “essentially a probability equation which predicts one event
    into
    the future”
    is incorrect.
    Moreover, the present permit allows an
    alternative statistical procedure to be used upon a showing that
    the prescribed t—test
    is inappropriate or that the modification
    requested comports with Section 724.197 of the Administrative
    Code.
    In general, changes
    in concentration at a background
    monitoring well could stem from a wealth of sources.
    Thus,
    any
    change in the statistical procedure utilized should be premised
    upon specific information as to why the contamination in question
    is occuring.
    The Agency is correct in not allowing the automatic
    use of a “moving window” approach to establishing background
    in
    that Marathon failed to prove conformance with
    35
    Ill. Mm. Code
    Section 724.197.
    it would be more useful
    if data collection from
    the background monitoring well were continued
    (at least until a
    background is established)
    in order
    to detect any trends and,
    if
    warranted,
    request the Agency for
    a permit modification to change
    the background concentration.
    The “moving window” approach would
    potentially alter the statistically established background
    if new
    samples were collected in background wells showing a level of
    contamination greater than that originally measured.
    This would
    allow the background to be modified without a showing of the
    source of the contamination.
    Such a change
    in background might
    be warranted, for example,
    if the cause of the difference in the
    background is also the cause of an identical change in the
    background of a well that
    is being monitored for purposes of
    compliance
    (i.e., comparisons with the background).
    Marathon is
    currently required to use replicate samples
    to establish
    I 18—243

    —6—
    background and use the t—test to determine if there are any
    increases above this analysis which are based upon the originally
    established background.
    Marathon’s objection to this requirement
    appears to be philosophical
    rather than evidentiary.
    Since
    Marathon has not provided the Agency or
    the Board with any
    specific documentation as to why the background determination
    procedure should be changed,
    we decline
    to do so today.
    Because
    Marathon has failed to establish that the permit modifications
    requested would not violate the Act,
    the Agency’s denial of the
    permit modifications
    in the instant case
    is affirmed.
    This Opinion constitutes the Board’s findings of fact and
    conclusions of
    law.
    ORDER
    The conditions imposed by the Agency as
    to Marathon’s RCRA
    part
    B permit modification for its Robinson oil refinery are
    hereby affirmed.
    Section 41 of the Environmental Protection Act,
    Ill. Rev.
    Stat.
    1989 chap.
    111—1/2 par.
    1041,
    provides for appeal of Final
    Orders of the Board within
    35 days.
    The Rules of the Supreme
    Court of Illinois establish filing requirements.
    IT
    IS SO ORDERED.
    I, Dorothy M. Gunn,
    Clerk of the Illinois Pollution Control
    Board, hereby certi~y~
    that the ab~sieOpinion and Order was
    adopted on the
    7~-~-
    day of
    ~
    1991 by a vote
    of
    .
    7
    /~
    ~
    ,
    Dorothy M. Gu,~1, Clerk
    Illinois PolWtion Control Board
    118—244

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