ILLINOIS POLLUTION CONTROL BOARD

February 28,

1991

IN THE MATTER OF:

)

PACT DEFICIENCIES IN THE

)

CHICAGO AREA:

 AMENDMENTS

)

 R91-7

TO 35 ILL.ADM.CODE

PART

215

)

 (Rulemaking)

AND THE ADDITION OF PART 218

)

Proposed Rule.

 First Notice.

ORDER OF THE BOARD

 (by J. Theodore Meyer):

On January 17,

 1991,

 the Illinois Environmental Protection

Agency

 (Agency) filed this proposal for rulemaking.

 The proposal

seeks to correct deficiencies identified by the United States

Environmental Protection Agency

 (USEPA)

 in Illinois’ state

implementation plan

 (SIP)

 for ozone in the Chicago area,

and

contains regulations requiring the implementation of reasonably

available control technology

 (PACT)

 for certain sources of

volatile organic material

 (VOM).

 The Board accepted the proposal

for hearing on February 7,

 1991.

 The Board also accepted the

Agency’s certification that this rulemaking is federally required

pursuant to Section 28.2 of the Environmental Protection Act

(Act)

 (Ill.Rev.Stat.

 1989,

ch.

 111 1/2, par. 1028.2),

 as amended

by P.A. 86—1409.

Today the Board sends this proposal to first notice,

as

required by Section 5.01 of the Illinois Administrative Procedure

Act.

 (Ill.Rev.Stat.

 1989,

ch.

 127,

 par. 1005.01.)

 The proposal

is submitted as filed by the Agency, with no alterations.

The

Board emphasizes that in sending this proposal to first notice,

it adopts

 substantive position on the merits of the proposal.

The Board believes that publishing the proposal at this time will

maximize the opportunity for public comment on the proposal.

Additionally,

 the Board has already stated that it places

 a very

high priority on the quick resolution of this rulemaking.

Beginning the statutorily-required first notice period at this

time will allow for the most expeditious resolution of the

proceeding.

The Board notes that two hearings have been scheduled in

this proceeding.

 These hearings are consolidated hearings with

docket P91-8 PACT Deficiencies in the Metro-East Area:

Amendments

 t’~’ 35 Ill.Adm.Code 215 and the Addition of Part 219.

A hearing will be held in Chicago on Wednesday, April 10,

 1991,

and a second hearing will be conducted in Granite City on Monday,

April

15,

 1991.

 Please note that the Chicago hearing will be

limited to discussion of proposed amendments to Part 215 and to

119—237

2

the proposed addition of Part 218.

 The Granite City hearing will

be limited to discussion of the proposed amendments to Part 215

and to the proposed addition of Part 219.

 Please contact the

hearing officer for further information about required pre-

filing of testimony and other hearing matters.

Finally,

 on February 19,

 1991,

 the Agency moved that the

Board allow the incorporation by reference of an exhibit from

P91-B into the docket from the federal implementation plan

 (FIP).

The FIP docket was filed as supporting material in this

proceeding,

 and the Agency asks that the Board refer to IEPA

Exhibit 1-g in R91-8

 in its use of the FIP docket at index item

XVI-3.

 The Agency’s motion is granted.

The Board directs the Clerk to cause first notice

publication in the Illinois Register of the following amendments:

TITLE 35:

 ENVIRONMENTAL PROTECTION

SUBTITLE B:

 AIR POLLUTION

CHAPTER

I:

 POLLUTION CONTROL BOARD

SUBCHAPTER

c:

 EMISSIONS STANDARDS AND LIMITATIONS FOR STATIONARY SOURCES

PART 218

ORGANIC MATERIAL EMISSION STANDARDS AND LIMITATIONS

FOR THE CHICAGO AREA

SUBPART A:

 GENERAL PROVISIONS

Section

218.100

 Introduction

218.101

 Clean-up and Disposal Operations

218.102

 Abbreviations and Conversion Factors

218.103

 Applicability

218.104

 Definitions

218.105

 Test Methods and Procedures

218.106

 Compliance Dates

218.107

 Afterburners

218.108

 Exemptions, Variations, and Alternative Means of

Control or Compliance Determinations

218.109

 Vapor Pressure of Volatile Organic Liquids

218.110

 Vapor Pressure of Organic Material or Solvents

218.111

 Vapor Pressure of Volatile Organic Material

218.112

 Incorporations by Reference

SUBPART B:

 ORGANIC EMISSIONS FROM STORAGE AND LOADING OPERATIONS

Section

218.121

 Storage Containers

218.122

 Loading Operations

218.123

 Petroleum Liquid Storage Tanks

119—238

3

218.124

 External Floating Roofs

218.125

 Compliance Dates

218.126

 Compliance Plan

218.127

 Emissions Testing

218.128

 Measurement of Seal Gaps

SUBPART C:

 ORGANIC EMISSIONS FROM MISCELLANEOUS EQUIPMENT

Section

218.141

 Separation Operations

218.142

 Pumps and Compressors

218.143

 Vapor Blowdown

218.144

 Safety Relief Valves

SUBPART

E:

 SOLVENT CLEANING

Section

218.181

 Solvent Cleaning in General

218.182

 Cold Cleaning

218.183

 Open Top Vapor Degreasing

218.184

 Conveyorized Degreasing

218.185

 Compliance Schedule

218.186

 Test Methods

SUBPART F:

 COATING OPERATIONS

Section

218.204

 Emission Limitations for Manufacturing Plants

218.205

 Daily—Weighted Average Limitations

218.206

 Solids Basis Calculation

218.207

 Alternative Emission Limitations

218.208

 Exemptions from Emission Limitations

218.209

 Exemption from General Rule on Use of Organic Material

218.210

 Compliance Schedule

218.211

 Recordkeeping and Reporting

SUBPART G:

 USE OF ORGANIC MATERIAL

Section

218.301

 Use of Organic Material

218.302

 Alternative Standard

218.303

 Fuel Combustion Emission Sources

218.304

 Operations with Compliance Program

SUBPART

H:

 PRINTING AND PUBLISHING

Section

218.401

 Flexographic and Rotogravure Printing

218.402

 Applicability

218.403

 Compliance Schedule

218.404

 Recordkeeping and Reporting

218.405

 Heatset Web Offset Lithographic Printing

119—239

SUBPART

Q:

 LEAKS FROM SYNTHETIC ORGANIC CHEMICAL AND POLYMER

MANUFACTURING EQUIPMENT

Section

218.421

 General Requirements

218.422

 Inspection Program Plan for Leaks

218.423

 Inspection Program for Leaks

218.424

 Repairing Leaks

218.425

 Recordkeeping for Leaks

218.426

 Report for Leaks

218.427

 Alternative Program for Leaks

218.428

 Open—ended Valves

218.429

 Standards for Control Devices

218.430

 Compliance Date

SUBPART R:

 PETROLEUM REFINING AND RELATED INDUSTRIES; ASPHALT

MATERIALS

Section

218.441

 Petroleum Refinery Waste Gas Disposal

218.442

 Vacuum Producing Systems

218.443

 Wastewater

 (Oil/Water) Separator

218.444

 Process Unit Turnarounds

218.445

 Leaks:

 General Requirements

218.446

 Monitoring Program Plan for Leaks

218.447

 Monitoring Program for Leaks

218.448

 Recordkeeping for Leaks

218.449

 Reporting for Leaks

218.450

 Alternative Program for Leaks

218.451

 Sealing Device Requirements

218.452

 Compliance Schedule for Leaks

218.453

 Compliance Dates

SUBPART

S:

 RUBBER AND MISCELLANEOUS PLASTIC PRODUCTS

Section

218.461

 Manufacture of Pneumatic Rubber Tires

218.462

 Green Tire Spraying Operations

218.463

 Alternative Emission Reduction Systems

218.464

 Emission Testing

218.465

 Compliance Dates

218.466

 Compliance Plan

SUBPART T:

 PHARMACEUTICAL MANUFACTURING

Section

218.480

 Applicability of Subpart T

218.481

 Control of Reactors, Distillation Units, Crystallizers,

Centrifuges and Vacuum Dryers

218.482

 Control

 of Air Dryers, Production Equipment Exhaust

Systems and Filters

119—240

5

218.483

218.484

218.485

218.486

218.487

218.488

218.489

Section

218.521

218.525

218.526

218.527

Section

218.541

Section

218. 581

218.582

218.583

218.584

218.585

Section

218. 601

218. 602

218. 603

218.604

218.605

218.606

218.607

218.608

218.609

218.610

218.611

Material Storage and Transfer

In—Process Tanks

Leaks

Other Emission Sources

Testing

Monitoring and Recordkeeping for Air Pollution Control

Equipment

Recordkeeping for Air Pollution Control Equipment

SUBPART V:

 AIR OXIDATION PROCESSES

Definitions

Emission Limitations for Air Oxidation Processes

Testing and Monitoring

Compliance Date

SUBPART W:

 AGRICULTURE

Pesticide Exception

SUBPART X:

 CONSTRUCTION

Architectural Coatings

Paving Operations

Cutback Asphalt

Bulk Gasoline Plants

Bulk Gasoline Terminals

Gasoline Dispensing Facilities

Gasoline Delivery Vessels

Gasoline Volatility Standards

SUBPART

Z:

 DRY CLEANERS

Perchloroethylene Dry Cleaners

Exemptions

Leaks

Compliance Dates

Compliance Plan

Exception to Compliance Plan

Standards for Petroleum Solvent Dry Cleaners

Operating Practices for Petroleum Solvent Dry Cleaners

Program for Inspection and Repair of Leaks

Testing and Monitoring

Exemption for Petroleum Solvent Dry Cleaners

Section

218.561

218.562

218.563

SUBPART Y:

 GASOLINE DISTRIBUTION

119—24 1

6

218.612

 Compliance Dates

218.613

 Compliance Plan

SUBPART AA:

 PAINT AND INK

MANUFACTURING

Section

218.620

218.621

218. 623

218.624

218.625

218.626

218.628

218.630

218.636

218.637

Section

218.875

218.877

218.879

218.881

218.883

218.886

SUBPART PP:

Section

218.920

218.923

218.926

218.927

218.928

Applicability

Exemption for Waterbase Material and Heatset Offset Ink

Permit Conditions

Open—top Mills, Tanks,

 Vats or Vessels

Grinding Mills

Storage Tanks

Leaks

Clean Up

Compliance Schedule

Recordkeeping and Reporting

SUBPART BB:

 POLYSTYRENE PLANTS

Applicability of Subpart BB

Emissions Limitation at Polystyrene Plants

Compliance Date

Compliance Plan

Special Requirements for Compliance Plan

Emissions Testing

MISCELLANEOUS FABRICATED PRODUCT MANUFACTURING PROCESSES

Applicability

Permit Conditions

Control Requirements

Compliance Schedule

Testing

SUBPART

QQ:

 MISCELLANEOUS FORMULATION MANUFACTURING PROCESSES

Section

218.940

218.943

218.946

218.947

218.948

Applicability

Permit Conditions

Control Requirements

Compliance Schedule

Testing

Applicability

Permit Conditions

Control Requirements

Compliance Schedule

Section

218.960

218.963

218.966

218.967

SUBPART

PR:

 MISCELLANEOUS ORGANIC CHEMICAL MANUFACTURING PROCESSES

119—242

7

218.968

 Testing

SUBPART TT:

 OTHER EMISSION SOURCES

Section

218.980

 Applicability

218.983

 Permit Conditions

218.986

Control

Requirements

218.987

 Compliance Schedule

218.988

Testing

SUBPART

UU:

 RECORDKEEPING AND REPORTING FOR

NON-CTG

SOURCES

Section

218.990

Exempt

Emission

Sources

218.991

 Subject Emission Sources

Appendix A:

 List of Chemicals Defining Synthetic Organic

Chemical and Polymer Manufacturing

Appendix

B:

VOM

Measurement

Techniques

for

Capture

Efficiency

Appendix

Reference

Methods

and

Procedures

Appendix

Coefficients

for

the

Total

Resource

Effectiveness

Index

(TRE)

Equation

AUTHORITY:

Implementing

Section

 and authorized by Section

28.2 of the Environmental Protection Act

(Ill.

Rev.

Stat.

1989,

ch.

 111 1/2, pars.

 1010 and 1028.2)

SOURCE:

 Adopted

 in R9l-7 at 15

 Ill. Reg.

_____,

 effective

SUBPART A:

 GENERAL PROVISIONS

Section 218.100

 Introduction

a)

 This Part contains standards and limitations for

emissions of organic material from stationary sources

located

 in the Chicago area,

 which is comprised of

Cook,

 DuPage, Kane,

 Lake, McHenry and Will Counties.

b)

 Sources subject to this Part may be subject to the

following:

1)

 Permits required under

35

 Ill.

 Adm. Code 201;

2)

 Air quality standards under 35 Ill. Adm.

 Code 243;

c)

 This Part is divided into Subparts which are grouped as

follows:

119—243

1)

 Subpart A:

 General Provisions

Subparts

B-F:

Emissions

from

equipment

and

operations

common

than

one

industry;

Subpart

Emissions

from

use

organic

material;

Subparts

H—end:

Special

rules

for

various

industry

groups.

Section

218.101

Cleanup

and

Disposal

 Operation

Emission of organic material released during clean—up operations

 and disposal shall be included with other emissions of organic

material

from

the

emission

source

air

pollution

control

equipment

determining

total

emissions.

Section

218.102

Abbreviations

and

Conversion

Factors

The

following

abbreviations

are

used

this

Part:

ASTM

American

Society

for

Testing

and

Materials

bbl

barrels

(42

gallons)

degrees

Celsius

centigrade

centimeters

in.

 cubic inches

degrees

Fahrenheit

FIP

 Federal Implementation Plan

feet

ft2

square

feet

g

 grams

gpm

 gallons per minute

g/mole

 grams per mole

gal

 gallons

hr

 hours

inches

degrees

Kelvin

kcal

kilocalories

kilograms

kg/hr

 kilograms per hour

kPa

 kilopascals; one thousand newtons per square

meter

liters

1/sec

liters

per

second

lbs

pounds

lbs/hr

pounds

per

hour

lbs/gal

pounds

per

gallon

LEL

lower

explosive

 limit

meters

square

meters

119—2 44

9

in3

 cubic meters

milligrams

Mg

 Megagrains, metric tons or tonnes

ml

 milliliters

minutes

megajoules

mItt

millimeters

mercury

ppm

parts

per

million

ppinv

parts

per

million

volume

psi

pounds

per

square

 inch

psia

pounds

per

square

inch

absolute

psig

pounds

per

square

 inch gauge

scf

standard

cubic

feet

scm

standard

cubic

meters

sec

seconds

SIP

State

Implementation

Plan

TTE

 temporary total enclosure

sq cm

 square centimeters

sq in

 square inches

T

 English ton

ton

 English ton

USEPA

United

 States Environmental Protection

Agency

VOC

 volatile organic compounds

VOL

volatile

organic

liquids

VOM

 volatile organic materials

The

following

conversion

factors

are

used

this

Part.

English

Metric

gal

3.785

1,000

gal

3,785

3.785

psia

6.897

kPa

(51.71

Hg)

2.205

lbs

1 bbl

 159.0

1

1

16.39

1 lb/gal

 119,800 mg/i

1

ton

 0.907 Mg

1

T

 0.907 Mg

Section

218.103

Applicability

The

provisions

this

Part

shall

apply

all

sources

located

Cook,

DuPage,

Kane,

Lake,

McHenry

Will

County.

The

provisions

this

Part

shall

become

effective

sixty days after a final decision by the federal

appellate court of the general appeal

 (Illinois

Environmental Regulatory Group v. USEPA, No. 90-2778

(and consolidated cases)

 (7th Cir.))

 of the federal

119—245

implementation plan

 (FIP)

 for the Chicago area

promulgated by the U.S. Environmental Protection Agency

(55 Fed. Reg. 26184,

 June 29,

 1990; 55 Fed. Reg.

 31981,

August

6,

 1990;

55

 Fed. Peg.

 39774, September 28,

1990), provided, however, that

if a provision of the

FIP is voided or made ineffective by a federal court,

the corresponding provision in this proceeding shall

not become effective.

b)

 The provisions of this Part specifically applicable to

each appellant who appealed the FIP for the Chicago

area shall become effective sixty days after a final

decision of that appellant’s appeal by the federal

appellate court; provided, however, that if the

provisions of the FIP applicable to that party are

voided or made ineffective by a federal court,

the

corresponding provisions in this proceeding shall not

become effective.

Section 218.104

 Definitions

The following terms are defined for the purpose of this Part.

“Accelacota” means a pharmaceutical coating operation

which consists of a horizontally rotating perforated

drum in which tablets are placed,

 a coating is applied

by spraying, and the coating is dried by the flow of

air across the drum through the perforations.

“Accumulator” means the reservoir of a condensing unit

receiving the condensate from a surface condenser.

“Acid Gases” means for the purposes of Section 9.4 of

the Environmental Protection Act

 (the Act)

 (Ill.

 Rev.

Stat.

 1987,

ch.

 111 1/2, par.

 1009.4), hydrogen

chloride, hydrogen fluoride and hydrogen bromide, which

exist as gases,

 liquid mist,

 or any combination

thereof.

“Actual emissions” means the actual quantity of

VOM

emissions from an emission source during a particular

time period.

“Actual

Heat

Input”

means

the

quantity

heat

produced

by the combustion of fuel using the gross heating value

of the fuel.

“Adhesive” means any substance or mixture of substances

intended to serve as a joining compound.

“Afterburner” means a control device in which materials

in gaseous effluent are combusted.

119—246

11

“Air

contaminant”

means

any

solid,

liquid,

gaseous

matter,

any

odor,

any

form

energy,

that

capable

being

released

into

the

atmosphere

from

emission

source.

“Air

dried

coatings”

means

any

coatings

that

dry

use

air

forced

air

temperatures

363.15

(194

oF)

“Air pollution” means the presence in the atmosphere of

one

air

contaminants

sufficient

quantities

and

such

characteristics

and

duration

injurious

human,

plant,

animal

life,

health,

property,

unreasonably

interfere

with

the

enjoyment

life

property.

“Air

pollution

control

equipment”

means

any

equipment

facility

type

intended

eliminate,

prevent,

reduce

control

the

emission

specified

air

contaminants to the atmosphere.

“Air suspension coater/dryer” means a pharmaceutical

coating operation which consists of vertical chambers

in which tablets or particles are placed, and a coating

is applied and then dried while the tablets or

particles are kept in a fluidized state by the passage

of air upward through the chambers.

“Airless spray” means

 a spray coating method in which

the coating is atomized by forcing it through a small

opening at high pressure.

 The coating liquid is not

mixed with air before exiting from the nozzle.

“Air-assisted airless spray” means a spray coating

method which combines compressed air with hydraulic

pressure to atomize the coating material into finer

droplets than is achieved with pure airless spray.

Lower hydraulic pressure is used than with airless

spray.

“Allowable emissions” means the quantity of VOM

emissions during a particular time period from a

stationary source calculated using the maximum rated

capacity of the source

 (unless restricted by federally

enforceable limitations on operating rate, hours of

operation,

 or both)

 and the most stringent of:

the

applicable standards in 40 CFR Parts 60 and 61; the

applicable implementation plan; or a federally

enforceable permit.

“Ambient air quality standards” means those standards

119—24 7

designed

protect

the

public

health

and

welfare

codified

CFR

Part

and

promulgated

from

 time

time

the

USEPA

pursuant

authority

contained

in

Section

108

the

Clean

Air

Act,

U.S.C.

7401

seq.,

amended

from

time

time.

“Applicator”

means

device

used

coating

line

apply

coating.

“As

applied”

means

the

exact

formulation

coating

during

application

impregnation

into

substrate.

“Architectural

Coating”

means

any

coating

used

for

residential

commercial

buildings

their

appurtenances,

for

industrial

buildings,

which

is

site applied.

“Asphalt”

means

the

dark—brown

black

cementitious

material

(solid,

semisolid,

liquid

consistency)

which

the

main

constituents

are

bitumens

which

occur

naturally

residue

petroleum

 refining.

“Asphalt

Prime

Coat”

means

low-viscosity

liquid

asphalt

applied

absorbent

surface

the

first

than

one

asphalt

coat.

“Automobile”

means

motor

vehicle

capable

carrying

than

passengers.

“Automobile

light-duty

truck

assembly

plant”

means

facility

where

parts

are

assembled

finished

for

eventual

inclusion

into

finished

automobile

light-duty

truck

ready

for

sale

vehicle

dealers,

but

not

including

customizers,

body

shops,

and

other

repainters.

“Automobile

light-duty

truck

refinishing”

means

the

repainting

used

automobiles

and

light-duty

trucks.

“Baked

coatings”

means

any

coating

which

cured

dried

oven

where

the

oven

air

temperature

exceeds

90°C (l94oF).

“Batch Loading” means the process of loading a number

individual

parts

the

same

time

for

degreasing.

“Bead-Dipping”

means

the

dipping

assembled

tire

bead

into

solvent—based

cement.

“Binders”

means

organic

materials

and

resins

which

not

contain

VOM.

119—248

“Bituminous coatings” means black or brownish coating

materials which are soluble in carbon disulfide,

 which

consist mainly of hydrocarbons,

 and which are obtained

from natural deposits or as residues from the

distillation of crude oils or of low grades of coal.

“British Thermal Unit” means the quantity of heat

required to raise one pound of water from 60°Fto 61°F

(abbreviated btu).

“Brush or wipe coating” means a manual method of

applying a coating using

 a brush,

 cloth,

 or similar

object.

“Bulk gasoline plant” means a gasoline storage and

distribution facility with an average throughput

of

76,000

1

 (20,000 gal)

 or less on a 30—day rolling

average that distributes gasoline to gasoline

dispensing facilities.

“Bulk Gasoline Terminal” means any gasoline storage and

distribution facility that receives gasoline by

pipeline,

 ship or barge, and distributes gasoline to

bulk gasoline plants or gasoline dispensing facilities.

“Can” means any metal container, with or without

 a top,

cover,

 spout or handles,

 into which solid or liquid

materials are packaged.

“Can coating” means any coating applied on a single

walled container that is manufactured from metal sheets

thinner than 29 gauge

 (0.0141 in.).

“Can coating facility” means a facility that includes

 one or more can coating line(s).

“Can coating line” means a coating line in which any

protective,

 decorative,

 or functional coating

is

applied onto the surface of cans or can components.

“Capture” means the containment or recovery of

emissions from a process for direction into a duct

which may be exhausted through a stack or vent to

a

control device.

 The overall abatement of emissions

from a process with an add—on control device is a

function both of the capture efficiency and of the

control device.

“Capture device” means a hood, enclosed room floor

sweep or other means of collecting solvent or other

pollutants into a duct.

 The pollutant can then be

directed to a pollution control device such as an

119—249

afterburner

carbon

adsorber.

Sometimes

the

term

is

used

loosely

include

the

control

device.

“Capture

efficiency”

means

the

fraction

all

VON

generated

process

that

are

directed

abatement

recovery

device.

“Capture

system”

means

all

equipment

(including,

but

not

limited

to,

hoods,

ducts,

fans,

ovens,

dryers,

etc.)

used

contain,

collect

and

transport

air

pollutant

control

device.

“Clean

Air

Act”

means

the

Clean

Air

Act

1963,

amended,

including

the

Clean

Air

Act

Amendments

1977,

(42

U.S.C.

7401

seq.),

and

the

Clean

Air

Act

Amendments

1990,

(P.A.

101549).

“Clear

coating”

means

coatings

that

lack

color

and

opacity

are

transparent

using

the

undercoat

ref lectant

base

undertone

color.

“Clear

topcoat”

means

the

final

coating

which

contains

binders,

but

not

opaque

pigments,

and

specifically

formulated

form

transparent

translucent

solid

protective

film.

“Closed

Purge

System”

means

system

that

not

open

the

atmosphere

and

that

composed

piping,

connections,

and,

necessary,

flow

inducing

devices

that

transport

liquid

vapor

from

piece

pieces

equipment

control

device,

return

the

liquid

vapor

the

process

line.

“Closed

vent

system”

means

system

that

not

open

the

atmosphere

and

composed

piping,

connections,

and,

necessary,

flow

inducing

devices

that

transport

gas

vapor

from

emission

source

control

device.

“Coating”

means

material

applied

onto

impregnated

into

substrate

for

protective,

decorative,

functional

purposes.

Such

materials

include,

but

are

not

limited

to,

paints,

varnishes,

sealers,

adhesives,

thinners,

diluents,

and

inks.

“Coating

applicator”

means

equipment

used

apply

coating.

“Coating

line”

means

operation

consisting

series

one

coating

applicators

and

any

associated

flash—off

areas,

drying

areas,

and

ovens

wherein

surface

coating

applied,

dried,

cured.

119—250

(It

is not necessary for an operation to have an oven,

flash—off

area,

drying

area

included

this

definition.)

“Coating

plant”

means

any

plant

that

contains

one

coating

line(s).

“Coil”

means

any

flat

metal

sheet

strip

that

rolled

wound

concentric

rings.

“Coil

coating”

means

any

coating

applied

any

flat

metal

sheet

strip

that

comes

rolls

coils.

“Coil

coating

facility”

means

facility

that

includes

one

coil

coating

line(s).

“Coil

coating

line”

means

coating

line

which

any

protective,

decorative

functional

coating

applied

onto

the

surface

flat

metal

sheets,

strips,

rolls,

coils

for

industrial

commercial

use.

“Cold

cleaning”

means

the

process

cleaning

and

removing

soils

from

surfaces

spraying,

brushing,

flushing,

immersion

while

maintaining

the

organic

solvent

below

its

boiling

point.

Wipe

cleaning

not

included

this

definition.

“Complete

Combustion”

means

process

which

all

carbon

contained

fuel

gas

stream

converted

carbon

dioxide.

“Component”

means,

with

respect

synthetic

organic

chemical

and

polymer

manufacturing

equipment,

and

petroleum

refining

and

industries,

any

piece

equipment

which

has

the

potential

leak

VON

including,

but

not

limited

to,

pump

seals,

compressor

seals,

seal

oil

degassing

vents,

pipeline

valves,

pressure

relief

devices,process

drains,

and

open

ended

pipes.

This

definition

excludes

valves

which

are

not

externally

regulated,

flanges,

and

equipment

heavy

liquid

service.

For

purposes

Subpart

Q

this

Part,

this

definition

also

excludes

bleed

ports

gear

pumps

polymer

service.

“Concrete

curing

compounds”

means

any

coating

applied

freshly

poured

concrete

retard

the

evaporation

water.

“Condensate”

means

volatile

organic

liquid

separated

from

its

associated

gases,

which

condenses

due

changes

the

temperature

pressure

and

remains

liquid

standard

conditions.

119—25 1

“Continuous

process”

means,

with

respect

polystyrene

resin,

 a method of manufacture in which the styrene raw

 material is delivered on a continuous basis to the

reactor

which

the

styrene

polymerized

polystyrene.

“Control

device”

means

equipment

(such

afterburner

adsorber)

used

remove

prevent

the

emission

air

pollutants

from

contaminated

exhaust

stream.

“Control

device

efficiency”

means

the

ratio

the

pollution

prevented

control

device

and

the

pollution

introduced

the

control

device,

expressed

percentage.

“Conveyorized

degreasing”

means

the

continuous

process

cleaning

and

removing

soils

from

surfaces

utilizing

either

cold

vaporized

solvents.

“Crude

oil”

means

naturally

occurring

mixture

which

consists

hydrocarbons

and

sulfur,

nitrogen,

oxygen

derivatives

hydrocarbons

and

which

liquid

at standard conditions.

“Crude oil gathering” means the transportation of crude

oil or condensate after custody transfer between a

production

facility

and

reception

point.

“Custody transfer” means the transfer of produced

petroleum

and/or

condensate

after

processing

and/or

treating

the

producing

operations,

from

storage

tanks

automatic

transfer

facilities

pipelines

any other forms of transportation.

“Cutback Asphalt” means any asphalt which has been

liquified

blending

with

petroleum

solvents

other

than

residual

fuel

oil

and

has

not

been

emulsified

 with

water.

“Daily—weighted

average

VON

content”

means

the

average

VON content of

two

coatings

applied

coating

line

during

any

day,

taking

into

account

the

fraction

total

coating

volume

that

each

coating

represents,

calculated

with

the

following

equation:

VOMW

~

 ViCiJ/VT

119—25 2

17

where:

VOMW

The

average

VOM

content

two

coatings

applied

each

day

coating line

 in units of kg VOM/l

 (lbs

VON/gal)

 of coating (minus water and any

compounds which are specifically

exempted from the definition of VON),

n

 The number of different coatings as

applied each day on a coating line,

V~

 The volume of each coating

 (minus water

and any compounds which are specifically

exempted from the definition of VON)

as

applied each day on a coating line in

units of

1

 (gal).

C~

 The VOM content of each coating as

applied each day on a coating line in

units of kg VOM/l

 (lbs VON/gal)

of

coating

 (minus water and any compounds

which are specifically exempted from the

definition of VON),

and

VT

 The total volume of all coatings

 (minus

water and any compounds which are

specifically exempted from the

definition of VON)

 as applied each day

on a coating line in units of

1

 (gal).

“Day” means the consecutive 24 hours beginning at 12:00

AN

 (midnight)

 local time.

“Degreaser” means any equipment or system used in

solvent cleaning.

“Delivery vessel” means any tank truck or trailer

equipped with a storage tank that is used for the

transport of gasoline to a stationary storage tank at a

gasoline dispensing facility, bulk gasoline plant,

or

bulk gasoline terminal.

“Dip coating” means a method of applying coatings in

which the part is submerged in a tank filled with the

coating.

“Distillate Fuel Oil” means fuel oils of grade No.

 1 or

2 as specified in detailed requirements for fuel oil

ASTM D—369—69

 (1971)

119—253

18

“Dry

Cleaning

Facility”

means

facility

engaged

the

cleaning of fabrics using an essentially nonaqueous

solvent by means of one or more solvent washes,

extraction of excess solvent by spinning and drying

by

 tumbling in an airstream.

 The facility includes, but

is not limited to, washers, dryers, filter and

purification systems, waste disposal systems, holding

tanks, pumps and attendant piping and valves.

“Effluent Water Separator” means any tank,

 box, sump or

other apparatus in which any organic material floating

on or entrained or contained in water entering such

tank,

 box,

 sump or other apparatus is physically

separated and removed from such water prior to outfall,

drainage or recovery of such water.

“Electrostatic bell or disc spray” means an

electrostatic spray coating method in which a

rapidly-spinning bell- or disc-shaped applicator is

used to create a fine mist and apply the coating with

high transfer efficiency.

“Electrostatic spray” means a spray coating method

in

which opposite electrical charges are applied to the

substrate and the coating.

 •The coating

 is attracted to

the object due to the electrostatic potential between

them.

“Emission Rate” means total quantity of any air

contaminant discharge into the atmosphere in any

one—hour period.

“Emission source” and “source” mean any facility from

which VON is emitted or capable of being emitted into

the atmosphere.

“Enamel” means a coating that cures by chemical

cross—linking of its base resin.

 Enamels can be

distinguished from lacquers because enamels are not

readily resoluble in their original solvent.

“Enclose” means to cover any VOL surface that is

exposed to the atmosphere.

“End sealing compound coat” means a compound applied to

can ends which functions as a gasket when the end

is

assembled onto the can.

“Excess Air” means air supplied in addition to the

theoretical quantity necessary for complete combustion

of all fuel and/or combustible waste material.

119—254

19

“Excessive

release”

means

discharge

than

295

(0.65

lbs)

mercaptans

and/or

hydrogen

sulfide

into

the

atmosphere

any

5—minute

period.

“Exterior

base

coat”

means

coating

applied

the

exterior

can

body,

flat

sheet

provide

protection to the metal or to provide background for

any lithographic or printing operation.

“Exterior end coat” means a coating applied to the

exterior end of a can to provide protection to the

metal.

“External—floating

roof”

means

cover

over

open

top

 storage tank consisting of a double deck or pontoon

single

deck

which

rests

upon

and

supported

the

volatile organic liquid being contained and is equipped

with

 a closure seal or seals to close the space between

the roof edge and tank shell.

“Extreme environmental conditions” means exposure to

any or all of the following:

 ambient weather

conditions;

 temperatures consistently above 95°C

(203oF); detergents; abrasive and scouring agents;

solvents; or corrosive atmospheres.

“Extreme performance coating” means any coating which

during intended use

 is exposed to extreme environmental

conditions.

“Fabric coating” means any coating applied on textile

fabric.

 Fabric coating includes the application of

coatings by impregnation.

“Fabric coating facility” means a facility that

includes one or more fabric coating lines.

“Fabric coating line” means a coating line in which any

protective, decorative,

 or functional coating or

reinforcing material is applied on or impregnated into

a textile fabric.

“Federally enforceable” means all limitations and

conditions which are enforceable by the Administrator

including those requirements developed pursuant to 40

CFR Parts

 60 and 61; requirements within any applicable

implementation plan;

 and any permit requirements

 established pursuant to 40 CFR 52.21 or under

regulations approved pursuant to 40 CFR Part 51 Subpart

I and 40 CFR 51.166.

“Final repair coat” means the repainting of any topcoat

119—255

which is damaged during vehicle assembly.

“Firebox”

means

the

chamber

compartment

boiler

or furnace in which materials are burned, but not the

combustion chamber or afterburner of an incinerator.

“Fixed—roof

tank”

means

cylindrical

shell

with

permanently

affixed

roof.

“Flexographic

printing”

means

the

application

words,

designs,

and

pictures

substrate

means

roll

printing

technique

which

the

pattern

applied

raised

above

the

printing

roll

and

the

image

carrier

is made of elastoineric materials.

“Flexographic printing line” means a printing line

in

which each roll printer uses

 a roll with raised areas

 for applying an image such as words, designs,

or

pictures to a substrate.

 The image carrier on the roll

is made of rubber or other elastomeric material.

“Floating roof” means a roof on a stationary tank,

reservoir,

 or other container which moves vertically

upon change in volume of the stored material.

“Fountain solution” means the solution which is applied

to the image plate to maintain hydrophilic properties

of the non—image areas.

“Freeboard Height” means for open top vapor degreasers,

the distance from the top of the vapor zone to the top

of the degreaser tank.

 For cold cleaning degreasers,

the distance from the solvent to the top of the

degreaser tank..

“Fuel combustion emission source” means any furnace,

boiler, or similar equipment used for the primary

purpose of producing heat or power by indirect heat

transfer.

“Fuel gas system” means a system for collection of

refinery fuel gas including,

 but not limited to, piping

for collecting tail gas. from various process units,

mixing drums and controls, and distribution piping.

“Gas service” means that the component contains process

fluid that is in the gaseous state at operating

conditions.

“Gas/gas method” means either of two methods for

determining capture which rely only on gas phase

measurements.

 The first method requires construction

119—256

21

of a temporary total enclosure (TTE)

 to ensure that all

would—be fugitive emissions are measured.

 The second

method uses the building or room which houses the

facility as an enclosure.

 The second method requires

that all other VOM sources within the room be shut down

while the test is performed, but all fans and blowers

within the room must be operated according to normal

procedures.

“Gasoline” means any petroleum distillate or petroleum

distillate/alcohol blend having a Reid vapor pressure

of 27.6 kPa or greater which is used as a fuel for

internal combustion engines.

“Gasoline dispensing facility” means any site where

gasoline is transferred from a stationary storage tank

to a motor vehicle gasoline tank used to provide fuel

to the engine of that motor vehicle.

“Green Tire Spraying” means the spraying of green

tires,

 both inside and outside, with release compounds

which help remove air from the tire during molding and

prevent the tire from sticking to the mold after

curing.

“Green Tires” means assembled tires before molding and

curing have occurred.

“Gross vehicle weight” means the manufacturer’s gross

weight rating for the individual vehicle.

“Gross vehicle weight rating” means the value specified

by the manufacturer as the maximum design loaded weight

of a single vehicle.

“Heated airless spray” means an airless spray coating

method in which the coating is heated just prior to

 application.

“Heatset”

means

class

web—offset

lithography

which

requires a heated dryer to solidify the printing inks.

“Heatset-web-offset lithographic printing line” means a

lithographic printing line in which a blanket cylinder

is used to transfer ink from a plate cylinder to a

substrate continuously fed from a roll or an extension

process and an oven is used to solidify the printing

inks.

“Heavy liquid” means

 liquid with a true vapor pressure

of less than 0.3 kPa

 (0.04 psi)

at

294.3oK

 (70°F)

established in a standard reference text or as

119—257

determined

ASTN

method

D2879-86

(incorporated

reference

Section

218.112);

which

has

0.1

Reid

Vapor

Pressure

determined

ASTM

method

D323-82

(incorporated

reference

Section

218.112);

which when distilled requires a temperature of

421.95oK

(300°F) or greater to recover 10 percent of the liquid

as determined by ASTM method D86-82

 (incorporated

by

reference in Section 218.112).

“Heavy off—highway vehicle products” means,

 for the

purpose of Subpart F of this Part, heavy construction,

mining,

 farming, or material handling equipment; heavy

industrial engines; diesel—electric locomotives and

associated power generation equipment; and the

components of such equipment or engines.

“Heavy off-highway vehicle products coating facility”

means a facility that includes one or more heavy

off-highway vehicle products coating line(s).

“Heavy off—highway vehicle products coating line” means

a coating line in which any protective, decorative,

or

functional coating is applied onto the surface of heavy

off-highway vehicle products.

“High

temperature aluminum coating” means a coating

that is certified to withstand a temperature of

537.8°C

(l000oF)

 for 24 hours.

“Hood” means a partial enclosure or canopy for

capturing and exhausting,

 by means

 of a draft,

the

organic vapors or other fumes rising from a coating

process

other

source.

“Hood capture efficiency” means the emissions from a

process which are captured by the hood and directed

into a control device, expressed as

percentage

all

emissions.

“Hot well” means the reservoir of a condensing unit

receiving the condensate from a barometric condenser.

“Hour” means a block period of 60 minutes

 (e.g.,

 1:00am

to 2:00am).

“In—process tank” means a container used for mixing,

blending, heating,

 reacting, holding, crystallizing,

evaporating or cleaning operations

 in the manufacture

of pharmaceuticals.

“In—situ Sampling Systems” means nonextractive samplers

or in—line samplers.

119—258

“In

vacuum

service”

means,

for

the

purpose

Subpart

this

Part,

equipment

which

operating

internal pressure that is at least

 5 kPa (0.73 psia)

below ambient pressure.

“Incinerator” means a combustion apparatus in which

refuse is burned.

“Indirect heat transfer” means transfer of heat in such

a way that the source of heat does not come into direct

contact with process materials.

“Ink” means a coating used in printing,

 impressing,

or

transferring an image onto a substrate.

“Interior body spray coat” means a coating applied by

spray to the interior of a can body.

“Internal—floating roof” means

 a cover or roof

in

a

fixed-roof tank which rests upon and is supported by

the volatile organic liquid being contained and is

 equipped with a closure seal or seals to close the

space between the roof edge and tank shell.

“Lacquers” means any clear wood finishes formulated

with nitrocellulose or synthetic resins to dry

by

evaporation without chemical reaction,

 including clear

lacquer sanding sealers.

“Large appliance” means any residential and commercial

washers, dryers, ranges, refrigerators, freezers, water

heaters,

 dishwashers, trash compactors,

air

conditioners, and other similar products.

“Large appliance coating” means any coating applied to

the component metal parts

 (including,

 but not limited

to,

 doors, cases,

 lids, panels,

 and interior support

parts)

 of residential and commercial washers, dryers,

ranges,

 refrigerators, freezers, water heaters,

dishwashers, trash compactors,

 air conditioners,

and

other similar products.

“Large appliance coating facility” means a facility

that includes one or more large appliance coating

line(s).

“Large appliance coating line” means a coating line in

which any protective,

 decorative, or functional coating

is applied onto the surface of large appliances.

“Light liquid”

means VON in the liquid state which

is

119—259

24

not

defined

heavy

liquid.

“Light—duty truck” means any motor vehicle rated at

3,850 kg gross vehicle weight or less, designed mainly

to transport property.

“Liquid/gas method” means either of two methods for

determining capture which require both gas phase and

liquid phase measurements and analysis.

 The first

method requires construction of a TTE.

 The second

method uses the building or room which houses the

facility as an enclosure.

 The second method requires

that all other VON sources within the room be shut down

while the test is performed,

 but all fans and blowers

within the room must be operated according to normal

procedures.

“Liquid—Mounted Seal” means

 a primary seal mounted in

continuous contact with the liquid between the tank

wall and the floating roof edge around the

circumference of the roof.

“Liquid service” means that the equipment or component

contains process fluid that is in a liquid state at

operating conditions.

“Liquids Dripping” means any visible leaking from a

seal including spraying, misting, clouding and ice

formation.

“Lithographic printing line” means a printing line,

except that the substrate is not necessarily fed from

an unwinding roll,

 in which each roll printer uses a

roll where both the image and non—image areas are

essentially in the same plane (planographic).

“Low Solvent Coating” means

 a coating which contains

less organic solvent than the conventional coatings

used by the industry.

 Low solvent coatings include

water-borne,

 higher solids,

 electro—deposition and

powder

coatings.

“Magnet

wire”

means

aluminum

copper

wire

formed

into

an electromagnetic

 coil.

“Magnet wire coating” means any coating or electrically

insulating varnish or enamel applied to magnet wire.

“Magnet wire coating facility” means a facility that

includes one or more magnet wire coating line(s).

“Magnet wire coating line” means a coating line in

119—260

25

which

any

protective,

decorative,

functional

coating

applied

onto

the

surface

magnet

wire.

“Malfunction”

means

any

sudden

and

unavoidable

failure

air

pollution

control

equipment,

process

equipment,

process

operate

normal

usual

manner.

Failures

that

are

caused

entirely

part

poor

maintenance,

careless

operation,

any

other

preventable upset condition or preventable equipment

breakdown shall not be considered malfunctions.

“Manufacturing process” means a method whereby

a

process emission source or series of process emission

sources is used to convert raw materials,

 feed stocks,

subassemblies, or other components into a product,

either for sale or for use as a component in a

subsequent manufacturing process.

“Material Recovery Section” means any equipment

designed to transport and recover styrene monomer and

other impurities from other products and by-products in

a polystyrene plant,

 including but not limited to the

styrene devolatilizer unit and styrene recovery unit.

“Maximum theoretical emissions” means the quantity of

volatile organic material emissions that theoretically

could be emitted by a stationary source before add—on

controls based on the design capacity or maximum

production capacity of the source and

8760 hours per

year.

 The design capacity or maximum production

capacity includes use of coating(s)

 or ink(s) with the

highest

volatile

organic

material

content

actually

used

in practice by the source.

“Metal furniture” means a furniture piece including,

 but not limited to,

 tables, chairs, waste baskets,

beds,

 desks,

 lockers, benches,

 shelving,

 file cabinets,

lamps,

 and room dividers.

“Metal furniture coating” means any non—adhesive

coating applied to any furniture piece made of metal or

any metal part which is or will be assembled with other

metal, wood,

 fabric, plastic or glass parts to form a

furniture piece including, but not limited to,

 tables,

chairs, waste baskets, beds,

 desks,

 lockers, benches,

shelving, file cabinets,

 lamps,

 and room dividers.

This definition shall not apply to any coating line

coating miscellaneous metal parts or products.

“Metal furniture coating facility” means

 a facility

that includes one or more metal furniture coating

line(s)

119—26 1

“Metal furniture coating line” means a coating line

in

which any protective, decorative, or functional coating

is applied onto the surface of metal furniture.

“Metallic shoe—type seal” means a primary or secondary

seal constructed of metal sheets

 (shoes) which are

joined together to form a ring,

 springs,

 or levers

which attach the shoes to the floating roof and hold

the shoes against the tank wall,

and

 a coated fabric

which is suspended from the shoes to the floating roof.

“Miscellaneous fabricated product manufacturing

process” means:

A manufacturing process involving one or more of

the following applications,

 including any drying

and curing of formulations, and capable of

emitting VOM:

Adhesives to fabricate or assemble components

or products

Asphalt solutions to paper or fiberboard

Asphalt to paper or felt

Coatings or dye to leather

Coatings to plastic

Coatings to rubber or glass

Disinfectant material to manufactured items

Plastic foam scrap or “fluff” from the

manufacture of foam containers and packaging

material to form resin pallets

Resin solutions to fiber substances

Viscose solutions for food casings

The storage and handling of formulations

associated with the process described above,

and

the use and handling of organic liquids and other

substances for clean—up operations associated with

the process described in this definition.

“Miscellaneous formulation manufacturing process”

means:

119—262

27

A manufacturing process which compounds one or

more of the following and is capable of emitting

VON:

Adhesives

Asphalt solutions

Caulks,

 sealants,

 or waterproofing agents

Coatings, other than paint and ink

Concrete curing compounds

Dyes

Friction materials and compounds

Resin solutions

Rubber solutions

Viscose solutions

The storage and handling of formulations

associated with the process described above,, and

the use and handling of organic liquids and other

substances for clean—up operations associated

with

the process described in this definition.

“Miscellaneous metal parts or products” means any metal

part or metal product, even if attached to or combined

with a nonmetal part or product, except cans,

 coils,

metal furniture, large appliances,

 magnet wire,

automobiles,

 ships, and airplane bodies.

“Miscellaneous metal parts and products coating” means

any coating applied to any metal part or metal product,

even if attached to or combined with a nonmetal part or

product, except cans,

 coils, metal furniture,

 large

appliances,

 and magnet wire.

 Prime coat,

 prime

surfacer coat,

 topcoat, and final repair coat for

automobiles and light—duty trucks are not miscellaneous

metal parts and products coatings.

 However, underbody

anti-chip

 (e.g., underbody plastisol)

 automobile,

and

light-duty truck coatings are miscellaneous metal parts

and products coatings.

 Also,

 automobile or light-duty

truck refinishing coatings, coatings applied to the

exterior of marine vessels, coatings applied to the

exterior of airplanes, and the customized topcoating of

 automobiles and trucks

 if production is less than 35

vehicles per day are not miscellaneous metal parts and

119—263

28

products

coatings.

“Miscellaneous metal parts or products coating

facility” means a facility that includes one or more

miscellaneous metal parts or products coating lines.

“Miscellaneous metal parts or products coating line”

means a coating line in which any protective,

decorative,

 or functional coating is applied onto the

surface of miscellaneous metal parts or products.

“Miscellaneous organic chemical manufacturing process”

means:

A manufacturing process which produces by chemical

reaction, one or more of the following organic

compounds or mixtures of organic compounds and

which is capable of emitting VON:

Chemicals listed in Appendix A of this

section

Chlorinated and sulfonated compounds

Cosmetic, detergent,

 soap, or surfactant

intermediaries or specialties and products

Disinfectants

Food additives

Oil and petroleum product additives

Plasticizers

Resins or polymers

Rubber additives

Sweeteners

Varnishes

The storage and handling of formulations

associated with the process described above and

the use and handling of organic liquids and other

substances for clean—up operations associated with

 the process described in this definition.

“Monitor” means to measure and record.

“Multiple package coating” means a coating made from

119—264

more than one different ingredient which must be mixed

prior to using and has a limited pot life due to the

chemical reaction which occurs upon mixing.

“No Detectable Volatile Organic Material Emissions”

means a discharge of volatile organic material into the

atmosphere as indicated by an instrument reading of

less than 500 ppm above background as determined in

accordance with 40 CFR 60.485(c).

“Offset” means, with respect to printing and publishin~

operations,

 use of a blanket cylinder to transfer ink

from the plate cylinder to the surface to be printed.

“Opaque stains” means all stains that are not

semi—transparent stains.

“Open top vapor degreasing” means the batch process of

cleaning and removing soils from surfaces by condensing

hot solvent vapor on the colder metal parts.

“Open—ended valve” means any valve,

 except pressure

relief devices, having one side of the valve

 in contact

with process fluid and one side open to the atmosphere,

either directly or through open piping.

“Operator of Gasoline Dispensing Facility” means any

person who is the lessee of or operates, controls or

supervises a gasoline dispensing facility.

“Organic compound” means any compound of carbon,

 excluding carbon monoxide, carbon dioxide, carbonic

acid,

 metallic carbides or carbonates,

 and aminonium

carbonate.

“Organic material” means any chemical compound of

carbon including diluents and thinners which are

liquids at standard conditions and which are used as

dissolvers, viscosity reducers, or cleaning agents, but

excluding methane, carbon monoxide, carbon dioxide,

carbonic acid, metallic carbonic acid, metallic

carbide, metallic carbonates,

 and ammonium carbonate.

“Organic vapor” means the gaseous phase of an organic

material or a mixture of organic materials present

in

the atmosphere.

“Oven” means a chamber within which heat is used for

one or more of the following purposes:

 dry,

 bake,

cure,

 or polymerize a coating or ink.

“Overall control” means the product of the capture

119—265

efficiency and the control device efficiency.

“Overvarnish” means a transparent coating applied

directly over ink or coating.

“Owner of Gasoline Dispensing Facility” means any

person who has legal or equitable title to a stationary

storage tank at a gasoline dispensing facility.

“Owner or operator” means any person who owns,

operates,

 leases, controls, or supervises an emission

source or air pollution control equipment.

“Packaging rotogravure printing” means rotogravure

 printing upon paper, paper board,

 metal foil,

 plastic

film, and other substrates, which are,

 in subsequent

operations,

 formed into packaging products or labels

for articles to be sold.

“Packaging rotogravure printing line” means a

rotogravure printing line

 in which surface coatings are

applied to paper, paperboard,

 foil,

 film,

 or other

substrates which are to be used to produce containers,

packaging products,

 or labels for articles.

“Paint manufacturing plant” means a plant that mixes,

blends, or compounds enamels, lacquers, sealers,

shellacs, stains, varnishes,

 or pigmented surface

coatings.

“Paper coating” means any coating applied on paper,

plastic film, or metallic foil to make certain

products,

 including (but not limited to)

 adhesive tapes

and labels, book covers, post cards, office copier

paper, drafting paper, or pressure sensitive tapes.

Paper coating includes the application of coatings by

impregnation and/or saturation.

“Paper coating facility” means a facility that includes

one or more paper coating lines.

“Paper coating line” means a coating line in which any

protective,

 decorative,

 or functional coating

is

applied on, saturated into,

 or impregnated into paper,

plastic film,

 or metallic foil to make certain

products,

 including (but not limited to)

 adhesive tapes

and labels, book covers, post cards,

 office copier

paper,

 drafting paper, and pressure sensitive tapes.

“Parts per million (volume)” means a volume/volume

ratio which expresses the volumetric concentration of

gaseous air contaminant in a million unit volume of

119—266

gas.

“Person”

means

any

individual,

corporation,

partnership,

association,

State,

municipality,’

political

subdivision

State;

any

agency,

department,

 or instrumentality of the United States;

and any officer,

 agent,

 or employee thereof.

“Petroleum” means the crude oil removed from the earth

and the oils derived from tar sands,

 shale,

 and coal.

“Petroleum Liquid” means crude oil, condensate or any

finished or intermediate product manufactured at a

petroleum refinery, but not including Number

 2 through

Number

 6 fuel oils as specified in ASTN D—396-69, gas

turbine fuel oils Numbers 2-GT through 4-GT as

specified in ASTM D-2880—7l or diesel fuel oils Numbers

2-D and 4—D,

 as specified in ASTM D-975—68.

“Petroleum refinery” means any facility engaged in

producing gasoline, kerosene, distillate fuel oils,

residual fuel oils,

 lubricants,

 or other products

through distillation of petroleum,

 or through

redistillation, cracking,

 or reforming of unfinished

petroleum derivatives.

“Pharmaceutical” means any compound or mixture,

 other

than food, used in the prevention,

 diagnosis,

alleviation, treatment,

 or cure of disease in human and

animal.

“Pharmaceutical coating operation” means a device in

which a coating is applied to a pharmaceutical,

including air drying or curing of the coating.

“Photochemically Reactive Material” means any organic

material with an aggregate of more than 20 percent of

its total volume composed of the chemical compounds

classified below or the composition of which exceeds

any of the following individual percentage composition

limitations.

 Whenever any photochemically reactive

material or any constituent of any organic material may

be classified from its chemical structure into more

than one of the above groups of organic materials it

shall be considered as a member of the most reactive

group, that

 is, the group having the least allowable

percent of the total organic materials.

A combination of hydrocarbons, alcohols,

aldehydes,

 esters,

 ethers or ketones having an

olefinic or cyclo—olefinic types of unsaturation:

5 percent.

 This definition does not apply to

119—26 7

perchloroethylene

trichloroethylene.

A

combination

aromatic

compounds

with

 eight

or

carbon

atoms

the

molecule

except

ethylbenzene:

percent.

combination

ethylbenzene,

ketones

having

branched

hydrocarbon

structures

toluene:

percent.

“Pigmented

coatings”

means

opaque

coatings

containing

binders and colored pigments which are formulated to

conceal the wood surface either as an undercoat or

topcoat.

“Plant” means all of the pollutant-emitting activities

which belong to the same industrial grouping, are

located on one or more contiguous or adjacent

properties,

 and are under the control of the same

person

 (or persons under common control),

 except the

activities of any marine vessel.

 Pollutant-emitting

activities shall be considered as part of the same

industrial grouping if they belong to the same “Major

Group”

 (i.e., which have the same two—digit code)

as

described in the “Standard Industrial Classification

Manual,

 1987”

 (incorporated by reference in Section

218.112).

“Plasticizers” means a substance added to a polymer

 composition to soften and add flexibility to the

product.

“Pneumatic Rubber Tire Manufacture” means the

production of pneumatic rubber tires with a bead

diameter up to but not including 20.0 inches and cross

section dimension up to 12.8 inches, but not including

specialty tires for antique or other vehicles when

produced on equipment separate from normal production

lines for passenger or truck type tires.

“Polystyrene Plant” means any plant using styrene to

manufacture polystyrene resin.

“Polystyrene Resin” means substance consisting of

styrene polymer and additives which is manufactured at

a polystyrene plant.

“Pressure Release” means the emission of materials

resulting from system pressure being greater than set

pressure of the pressure relief device.

“Pressure Tank” means a tank in which fluids are stored

119—268

pressure

greater

than

atmospheric

pressure.

“Prime

coat”

means

the

first

two

coatings

applied

surface.

“Prime surfacer coat” means a coating used to touch up

areas on the surface of automobile or light—duty truck

bodies not adequately covered by the prime coat before

application of the top coat.

 The prime surfacer coat

 is applied between the prime coat and topcoat.

An

anti-chip coating applied to main body parts

 (e.g.,

rocker panels, bottom of doors and fenders, and leading

edge of roof)

 is a prime surfacer coat.

“Primers” means any coatings formulated and applied to

substrates to provide a firm bond between the substrate

and subsequent coats.

“Printing” means the application of words, designs,

and

pictures to a substrate using ink.

“Printing line” means an operation consisting of a

series of one or more roll printers and any associated

roll coaters, drying areas, and ovens wherein one or

more coatings are applied, dried, and/or cured.

“Process” means any stationary emission source other

than a fuel combustion emission source or an

incinerator.

“Process Unit” means components assembled to produce,

as intermediate or final products, one or more of the

chemicals listed in 35 Ill. Adm. Code 218 Appendix A.

A process unit can operate independently if supplied

with sufficient feed or raw materials and sufficient

storage facilities for the product.

“Process Unit Shutdown” means a work practice or

operational procedure that stops production from a

process unit or part of a process unit.

 An unscheduled

work practice or operational procedure that stops

production from a process unit or part of a process

unit for less than 24 hours is not a process unit

shutdown.

 The use of spare components and technically

 feasible bypassing of components without stopping

production is not a process unit shutdown.

“Production equipment exhaust system” means a system

for collecting and directing into the atmosphere

emissions of volatile organic material from reactors,

centrifuges, and other process emission sources.

119—269

34

“Publication

rotogravure

printing

line”

means

rotogravure printing line in which coatings are applied

to paper which is subsequently formed into books,

magazines,

 catalogues, brochures,

 directories,

newspaper supplements, or other types

 of printed

material.

“Purged Process Fluid” means liquid or vapor from a

process unit that contains volatile organic material

and that results from flushing or cleaning the sample

line(s)

 of a process unit so that an uncontaminated

sample may then be taken for testing or analysis.

“Reactor” means a vat, vessel, or other device

 in which

chemical reactions take place.

“Reasonably Available Control Technology

 (PACT)” means

the lowest emission limitation that an emission source

is capable of meeting by the application of control

technology that is reasonably available considering

technological and economic feasibility.

“Refiner” means any person who owns,

 leases,

 operates,

 controls,

 or supervises a refinery.

“Refinery Fuel Gas” means any gas which is generated by

a petroleum refinery process unit and which is

combusted at the refinery, including any gaseous

mixture of natural gas and fuel gas.

“Refinery unit, process unit or unit” means a set of

components which are a part of a basic process

operation such as distillation, hydrotreating,

cracking, or reforming of hydrocarbons.

“Refrigerated condenser” means a surface condenser in

which the coolant supplied to the condenser has been

cooled by a mechanical device,

 other than by a cooling

tower or evaporative spray cooling, such as

refrigeration unit or steam chiller unit.

“Reid vapor pressure” means the standardized measure of

the vapor pressure of a liquid in pounds per square

inch absolute

 (Psia) at 100°F(37.8°C).

“Repair coatings” means coatings used to correct

imperfections or damage to furniture surface.

“Repaired” means,

 for the purpose of Subpart

Q

of this

Part,

 that equipment component has been adjusted,

or

otherwise altered, to eliminate a leak.

119—270

35

“Residual

Fuel

Oil”

means

fuel

oils

grade

No.

and

specified

detailed

requirements

for

fuel

oils

A.S.T.M.

D—396—69

(1971).

“Retail

Outlet”

means

any

gasoline

dispensing

facility

which

gasoline

sold

offered

for

sale

for

use

motor

vehicles.

“Roll

coater”

means

apparatus

which

uniform

layer

coating

applied

means

one

rolls across the entire width of a moving substrate

“Roll printer” means an apparatus used in the

application of words, designs,

 or pictures to a

substrate, usually by means of one or more rolls each

with only partial coverage.

“Roll printing” means the application of words,

designs,

 and pictures to a substrate usually by means

of a series of hard rubber or metal rolls each with

only partial coverage.

“Roller coating” means a method of applying a coating

to a sheet or strip in which the coating is transferred

by a roller or series of rollers.

“Rotogravure printing” means the application of words,

designs, and pictures to a substrate by means of a roll

printing technique in which the pattern to be applied

 is recessed relative to the non—image area.

“Rotogravure printing line” means a printing line in

which each roll printer uses a roll with recessed areas

for applying an image to a substrate.

“Safety relief valve” means a valve which

 is normally

closed and which is designed to open in order to

relieve excessive pressures within a vessel or pipe.

“Sanding sealers” means any coatings formulated for and

applied to bare wood for sanding and to seal the wood

for subsequent application of varnish.

 To be

considered a sanding sealer a coating must be clearly

labelled as such.

“Sealer” means a coating containing binders which seals

wood prior to the application of the subsequent

coatings.

“Sensor” means a device that measures a physical

quantity or the change in a physical quantity such as

temperature, pressure, flow rate,

 pH, or liquid level.

119—27 1

“Semi—transparent

stains”

means

stains

containing

dyes

or semi— transparent pigments which are formulated to

enhance wood grain and change the color of the surface

but not to conceal the surface,

 including,

 but not

limited to,

 sap stain, toner, non—grain raising stains,

pad stain,

 or spatter stain.

“Set of safety relief valves” means one or more safety

relief valves designed to open in order to relieve

 excessive pressures in the same vessel or pipe.

“Sheet basecoat” means a coating applied to metal when

the metal is

 in sheet form to serve as either the

exterior or interior of a can for either two—piece or

three-piece cans.

“Side—seam spray coat” means

 a coating applied to the

seam of a three—piece can.

“Single coat” means one coating application applied to

a metal surface.

“Solvent” means a liquid substance that is used to

dissolve or dilute another substance.

“Solvent cleaning” means the process of cleaning soils

from surfaces by cold cleaning, open top vapor

degreasing,

 or conveyorized degreasing.

“Specified air contaminant” means any air contaminant

as to which this Part contains emission standards or

other specific limitations.

“Splash loading” means a method of loading a tank,

railroad tank car, tank truck,

 or trailer by use of

other than

 a submerged loading pipe.

“Stack” means a flue or conduit,

 free—standing or with

exhaust port above the roof of the building on which it

is mounted, by which air contaminants are emitted into

the atmosphere.

“Standard conditions” means a temperature of 70°Fand a

pressure of 14.7 psia.

“Standard cubic foot (scf)” means the volume of one

cubic foot of gas at standard conditions.

“Standard Industrial Classification Manual” means the

Standard Industrial Classification Manual

 (1987),

Superintendent of Documents,

 U.S. Government Printing

119—272

37

Office, Washington,

 DC 20402

 (incorporated by reference

in Section 218.112).

“Start—up” means the setting in operation of an

emission source for any purpose.

“Stationary emission source” and “Stationary source”

mean an emission source which is not self—propelled.

“Storage tank or storage vessel” means any stationary

tank,

 reservoir or container used for the storage of

VOL.

“Styrene Devolatilizer Unit” means equipment performing

the function of separating unreacted styrene monomer

and other volatile components from polystyrene in a

vacuum devolatilizer.

“Styrene Recovery Unit” means equipment performing the

function of separating styrene monomer from other less

volatile components of the styrene devolatilizer unit’s

output.

 The separated styrene monomer may be reused as

a raw material

 in the polystyrene plant.

“Submerged loading pipe” means any discharge pipe or

nozzle which meets either of the following conditions:

Where the tank is filled from the top, the end of

the discharge pipe or nozzle must be totally

submerged when the liquid level is

 15 cm

(6

 in.)

above the bottom of the tank.

Where the tank is filled from the side,

the

discharge pipe or nozzle must be totally submerged

when the liquid level is 46 cm

 (18 in.) above the

bottom of the tank.

“Substrate” means the surface onto which a coating is

applied or into which a coating

 is impregnated.

“Surface condenser” means a device which removes a

substance from

 a gas stream by reducing the temperature

of the stream, without direct contact between the

coolant and the stream.

“Synthetic Organic Chemical or Polymer Manufacturing

Plant” means a plant that produces,

 as intermediates or

final products, one or more of the chemicals or

polymers listed in 35 Ill.

 Adm. Code 218 Appendix A.

“Tablet coating operation” means a pharmaceutical

coating operation in which tablets are coated.

119—273

“Thirty—day rolling average” means any value

arithmetically

averaged

over

any

consecutive

thirty-days.

“Three—piece

can”

means

can

which

made

from

rectangular

sheet

and

two

circular

ends.

“Topcoat”

means

coating

applied

multiple

coat

operation

other

than

prime

coat,

final

repair

coat,

prime surfacer coat.

“Topcoat operation” means all topcoat spray booths,

flash—off areas, and bake ovens at

 a facility which are

used to apply,

 dry, or cure the final coatings (except

final off—line repair)

 on components of automobile or

light-duty truck bodies.

“Transfer efficiency” means the ratio of the amount of

coating solids deposited onto a part or product to the

total amount of coating solids used.

“Tread End Cementing” means the application of a

solvent—based cement to the tire tread ends.

“True vapor pressure” means the equilibrium partial

pressure exerted by a volatile organic liquid as

determined in accordance with methods described

in

American Petroleum Institute Bulletin 2517,

“Evaporation Loss From Floating Roof Tanks,” second

edition, February 1980 (incorporated by reference in

Section 218.112).

“Turnaround” means the procedure of shutting down an

operating refinery unit,

 emptying gaseous and liquid

contents to do inspection,

 maintenance and repair work,

and putting the unit back into production.

“Two-piece can” means a can which is drawn from a

shallow cup and requires only one end to be attached.

“Undercoaters” means any coatings formulated for and

applied to substrates to provide a smooth surface for

subsequent coats.

“Undertread Cementing” means the application of a

solvent—based cement to the underside of

 a tire tread.

“Unregulated safety relief valve” means a safety relief

 valve which cannot be actuated by a means other than

high pressure in the pipe or vessel which it protects.

119—274

“Vacuum producing system” means any reciprocating,

rotary,

 or centrifugal blower or compressor or any jet

ejector or device that creates suction from a pressure

below atmospheric and discharges against a greater

pressure.

“Valves not externally regulated” means valves that

have no external controls, such as in—line check

valves.

“Vapor balance system” means any combination of pipes

or hoses which creates a closed system between the

vapor spaces of an unloading tank and a receiving tank

such that vapors displaced from the receiving tank are

transferred to the tank being unloaded.

“Vapor collection system” means all piping,

 seals,

hoses, connections, pressure—vacuum vents,

 and other

possible sources between the gasoline delivery vessel

and the vapor processing unit and/or the storage tanks

and vapor holder.

“Vapor control system” means any system that limits or

prevents release to the atmosphere of organic material

in the vapors displaced from a tank during the transfer

of gasoline.

“Vapor—Mounted Primary Seal” means a primary seal

mounted with an air space bounded by the bottom of the

primary seal, the tank wall,

 the liquid surface and the

floating roof.

“Vapor recovery system” means a vapor gathering system

 capable of collecting all VON vapors and gases

discharged from the storage tank and a vapor disposal

system capable of processing such VON vapors and gases

so as to prevent their emission to the atmosphere.

“Vehicle” means a device by which any person or

property may be propelled, moved,

 or drawn upon a

highway, excepting a device moved exclusively by human

power or used exclusively upon stationary rails or

tracks.

“Vinyl coating” means any topcoat or printing ink

applied to vinyl coated fabric or vinyl sheets.

 Vinyl

coating does not include plastisols.

“Vinyl coating facility” means a facility that includes

one or more vinyl coating line(s).

“Vinyl coating line” means a coating line in which any

119—275

40

protective, decorative or functional coating

 is applied

onto vinyl coated fabric or

vinyl

sheets.

“Volatile organic liquid” means any substance which is

liquid at storage conditions and which contains

volatile organic compounds.

“Volatile organic material

 (VON)

 or volatile organic

compound (VOC)” means any organic compound which

participates

 in atmospheric photochemical reactions.

This includes any organic compound other than the

following compounds:

 methane,

 ethane, methyl

chloroform (l,1,l—trichloroethane), CFC-l13

 (trichlorotrifluoroethane), methylene chloride

(dichloromethane), CFC-ll

 (trichlorofluoromethane),

CFC-12

 (dichiorodifluoromethane), CFC-22

(chlorodifluoromethane), FC—23

 (trifluoromethane),

CFC-114 (dichlorotetrafluoroethane), CFC-1l5

(chloropentafluoroethane), HCFC—l2

(dichlorotrifluoroethane), HFC-134a

(tetrafluoroethane), HCFC-l4lb (dichlorofluoroethane)

and HCFC-l42b (chlorodifluoroethane).

 These compounds

have been determined to have negligible photochemical

reactivity.

In addition, for the 3M Bedford Park facility in Cook

County, the following compounds shall not be considered

as volatile organic material or volatile organic

compounds

 (and are, therefore, to be treated as water

for the purpose of calculating the “less water”

part of

the coating or ink composition)

 for a period of time

not to exceed one year after the date USEPA acts on

3M’s petition, pending as of the date of promulgation

of this rule,

 which seeks to have these compounds

classified as exempt compounds:

(1)

 cyclic,

 branched,

or linear, completely fluorinated alkanes,

(2)

 cyclic,

branched,

 or linear, completely fluorinated ethers

with

no unsaturations,

(3)

 cyclic,

 branched,

 or linear,

completely fluorinated tertiary amines with no

unsaturations, and

(4)

sulfur containing

perfluorocarbons with no unsaturations and with

sulfur

bonds only to carbon and fluorine.

For purposes of determining compliance with emission

limits, VOC will be measured by the approved test

methods.

 Where such a method also inadvertently

measures compounds with negligible photochemical

reactivity,

 an owner or operator may exclude these

negligibly

reactive

compounds

when

determining

compliance

with

emissions

standard.

“Volatile

Petroleum

Liquid”

means

any

petroleum

liquid

119—276

41

with a true vapor pressure that is greater than 1.5

psia

 (78 millimeters of mercury) at standard

conditions.

“Wash coat” means a coating containing binders which

seals wood surfaces, prevents undesired staining, and

controls penetration.

“Wastewater (Oil/Water) Separator” means any device or

piece of equipment which utilizes the difference in

density between oil and water to remove oil and

associated chemicals of water,

 or any device, such as

a

flocculation tank or a clarifier,

 which removes

petroleum derived compounds from waste water.

“Web” means a substrate which is printed in continuous

 roll—fed presses.

“Wood furniture” means room furnishings including

cabinets

 (kitchen,

 bath,

 and vanity),

 tables,

 chairs,

beds,

 sofas,

 shutters,

 art ob,jects, wood paneling, wood

flooring, and any other coated furnishings made of

wood, wood composition, or fabricated wood materials.

“Wood furniture coating facility” means

 a facility that

includes one or more wood furniture coating line(s).

“Wood furniture coating line”

 mean’s a coating line in

which any protective, decorative,

 or functional coating

is applied onto wood furniture.

“Woodworking” means the shaping,

 sawing, grinding,

smoothing,

 polishing, and making into products of any

form or shape of wood.

Section 218.105

 Testing Methods and Procedures

a)

 Coatings, Inks and Fountain Solutions

The following test methods and procedures shall be used

to determine compliance of applied coatings,

 inks,

and

fountain solutions with the limitations set forth

in

this Part.

1)

 Sampling:

 Samples collected for analyses shall

be

one—liter taken into a one—liter container at a

location and time such that the sample will be

representative of the coating as applied

 (i.e.,

the sample shall include any dilution solvent or

other VOM added during the manufacturing process).

The container must be tightly sealed immediately

 after the sample is taken.

 Any solvent or other

119—277

VOM

added

after

the

sample

taken

must

measured and accounted for in the calculations

in

subsection

(a)

(3).

For

multiple

package

coatings,

separate

samples

each

component

shall

obtained.

 A mixed sample shall not be obtained as

it will cure in the container.

 Sampling

procedures shall follow the guidelines presented

in:

A)

 ASTM D3925—81(1985) standard practice for

sampling liquid paints and related pigment

coating. This practice is incorporated by

reference in Section 218.112.

B)

 ASTM E300—86 standard practice for sampling

industrial chemicals.

 This practice is

incorporated by reference in Section 218.112.

2)

 Analyses:

 The applicable analytical methods

specified below shall be used to determine the

composition of coatings,

 inks, or fountain

solutions as applied.

A)

 Method 24 of 40 CFR 60, Appendix A,

incorporated by reference in Section 218.112,

shall be used to determine the VON content

and density of coatings.

 If it

is

demonstrated to the satisfaction of the

Agency and the USEPA that plant coating

formulation data are equivalent to Method 24

results,

 formulation data may be used.

In

the event of any inconsistency between a

Method 24 test and a facility’s formulation

data, the Method 24 test will govern.

B)

 Method 24A of 40 CFR Part 60, Appendix A,

incorporated by reference in Section 218.112,

shall be used to determine the VON content

and density of rotogravure printing inks and

related coatings.

 If it is demonstrated to

the satisfaction of the Agency and USEPA that

the plant coating formulation data are

equivalent to Method 24A results, formulation

data may be used.

 In the event of any

inconsistency between a Method 24A test and a

facility’s formulation data,

 the Method 24A

test will govern.

C)

 The following ASTM methods are the analytical

procedures for determining VOM:

i)

 ASTN Dl475-85: Standard test method for

119—278

43

density of paint,

 varnish, lacquer and

related products.

 This test method is

incorporated by reference in Section

218.112.

ii)

ASTM

D2369—87:

Standard

test

method

for

volatile

content

coating.

This

test

method

incorporated

reference

Section

218.112.

iii)

ASTM

D3792—86:

Standard

test

method

for

water content of water—reducible ‘paints

by direct injection into a gas

chromatograph. This test method is

incorporated by reference in Section

218.112.

iv)

ASTM

D4017—81(l987):

Standard

test

method

for

water

 content in paints and

paint

materials

the

Karl

Fischer

method.

 This test method is incorporated

reference

Section

218.112.

v)

 ASTM D4457-85: Standard test method for

determination of dichloromethane and

1,1,1, trichloroethane in paints and

coatings by direct injection into a gas

chromatograph.

 (The procedure

delineated above can be used to develop

protocols for any compounds specifically

exempted from the definition of VOM.)

This test method is incorporated by

reference in Section 218.112.

vi)

 ASTM D2697-86:

 Standard test method for

volume non—volatile matter in clear

or

pigmented coatings.

 This test method

is

 incorporated by reference in Section

218.112.

vii)

ASTM

D3980—87:

Standard

practice

for

interlaboratory

testing

paint

and

materials.

 This practice is

incorporated by reference in Section

218.112.

viii)

ASTM

El80—85:

Standard

practice

for

determining

the

precision

data

ASTN

methods

for

analysis

 of and testing of

industrial chemicals. This practice is

incorporated by reference in Section

218.112.

119—279

44

ix)

ASTM

D2372-85:

Standard

method

separation of vehicle from

solvent-reducible paints. This method

is

incorporated by reference in Section

218. 112.

D)

 Use of an adaptation to any of the analytical

methods specified in subsections

 (a) (2) (A),

(B), and

 (C) may not be used unless approved

by the Agency and USEPA.

 An owner or

operator must submit sufficient documentation

for the Agency and USEPA to find that the

analytical methods specified in subsections

(a) (2) (A),

 (B), and

 (C) will yield inaccurate

 results and that the proposed adaptation is

appropriate.

3)

 Calculations:

 Calculations for determining the

VON content, water content and the content of

any

compounds which are specifically exempted from the

definition of VON of coatings,

 inks and fountain

solutions as applied shall follow the guidance

provided in the following documents.

A)

 “A Guide for Surface Coating Calculation”,

EPA-340/1-86-0l6, incorporated by reference

in Section 218.112.

B)

 “Procedures for Certifying Quantity of

Volatile Organic Compounds Emitted by Paint,

Ink and Other Coatings” (revised June 1986),

EPA-450/3—84—0l9,

 incorporated by reference

in Section 218.112.

C)

 “A Guide for Graphic Arts Calculations”,

August 1988,

 EPA-340/1-88-003,

 incorporated

by reference in Section 218.112

b)

 Automobile or Light-Duty Truck Test Protocol

The.

 protocol for testing, including determining the

transfer

efficiency,

of, coating

applicators

topcoat

coating

operations

automobile

assembly

facility

shall

the

procedure

in:

“Protocol

for

Determining

the

Daily

Volatile

Organic

Compound

Emission

Rate

Automobile

and

 Light-Duty Truck

Topcoat Operations”, December 1988, EPA—450/3-88-018,

incorporated by reference in Section 218.112.

c)

 Capture System Efficiency Test Protocols

119—280

45

Applicability

The

requirements

subsection

(C)

(2)

shall

apply

to all VON emitting processes employing capture

equipment (e.g., hoods,

 ducts), except those cases

noted below.

A)

 If a source installs a permanent total

enclosure

 (PTE)

 that meets Agency and USEPA

specifications, and which directs all VON to

a control device, then the source is exempted

from the requirements described in subsection

(c) (2).

 The Agency and USEPA specifications

to determine whether a structure is

considered a PTE are given in Procedure T of

Appendix B of this Part.

 In this instance,

the capture efficiency is assumed to be 100

percent and the source is still required to

measure control efficiency using appropriate

test methods as specified in subsection

 (d).

B)

 If a source uses a control device designed to

collect and recover VON (e.g.,

 carbon

adsorber),

 an explicit measurement of capture

 efficiency is not necessary provided that the

conditions given below are met.

 The overall

control of the system can be determined by

directly comparing the input liquid VON to

the recovered liquid VON.

 The general

procedure for use in this situation is given

in 40 CFR 60.433, incorporated by reference

in Section 218.112, with the following

additional restrictions:

i)

 The source must be able to equate

solvent usage with solvent recovery on a

24-hour (daily)

 basis,

 rather than a

30-day weighted average, within 72 hours

following the 24-hour period.

In

addition, one of the following two

criteria must be met:

ii)

 The solvent recovery system

 (i.e.,

capture and control system) must be

dedicated to a single process line

(e.g.,

 one process line venting to a

carbon

adsorber

system),

iii)

the

solvent

recovery

system

controls

multiple process lines, then the source

must be able to demonstrate that the

overall control

 (i.e., the total

119—28 1

46

recovered

solvent

VOM

divided

the

sum

of liquid VOM input to all process lines

venting

the

control

system)

meets

exceeds

the

most

stringent

standard

applicable

for

any

process

line

venting

the

control

system.

Specific

Requirements

The

capture

efficiency

process

line

shall

be

measured

using

one

the

four

protocols

given

below.

Any

error

margin

associated

with

test

protocol

may

not

incorporated

into

the

results

capture

efficiency

test.

 If these techniques

are

not

suitable

for

particular

 process, then

the

source

may

use

 alternative capture

efficiency protocol, provided that the alternative

protocol is approved by the Agency and approved

by

the USEPA as a SIP revision.

A)

 Gas/gas method using temporary total

enclosure

 (TTE).

 The Agency and USEPA

specifications to determine whether a

 temporary enclosure is considered a TTE are

given in Procedure T of Appendix B of this

Part.

 The capture efficiency equation to be

used for this protocol is:

CE

 Gw/(Gw

Fw)

where:

CE

 capture efficiency, decimal

fraction

Gw

 mass of VOM captured and delivered

to control device using a TTE

Fw

 mass of fugitive VON that escapes

from

TTE

Procedure

G.2

contained

Appendix

this

Part

used

obtain

Gw.

Procedure

F.1

Appendix

this

Part

used

obtain

Fw.

Liquid/gas

method

using

TTE.

The

Agency

and

USEPA specifications to determine whether a

temporary

enclosure

considered

TTE

are

given

Procedure

Appendix

this

Part.

The

capture

efficiency

equation

used

for

this

protocol

is:

CE

(L

F)/L

119—282

47

where:

CE

 capture efficiency, decimal

fraction

 mass of liquid VOM input to

process

Fw

 mass of fugitive VON that escapes

from

TTE

Procedure

contained

Appendix

this

Part

used

obtain

Procedure

F.1

Appendix

this

Part

used

obtain

Fw.

Gas/gas

method

using

the

building

room

(building

room

enclosure)

which

the

affected

source

located

the

enclosure

and

which

“F”

and

“G”

are

 measured while

operating

only

the

affected

facility.

All

fans

and

blowers

the

 building or room must

operated

they

would

under

normal

production.

 The capture efficiency equation

to be used for this protocol is:

CE

G/(G

Fa)

where:

CE

capture

efficiency,

decimal

fraction

G

 mass of VON captured and

delivered to control device

FB =mass of fugitive VON that escapes

from building enclosure

Procedure G.2 contained in Appendix B of

this

Part is used to obtain G.

 Procedure F.2 in

Appendix B of this Part is used to obtain F~.

D)

 Liquid/gas method using the building or room

(building or room enclosure)

 in which the

affected source is located as the enclosure

and in which “F” and “L” are measured while

operating only the affected facility.

All

fans and blowers in the building or room must

be operated as they would under normal

production.

 The capture efficiency equation

to be used for this protocol is:

(L

F~)/L

where:

capture

efficiency,

decimal

119—283

48

fraction

mass

liquid

VON

input

process

F~=mass

fugitive

VOM

that

escapes

from

building

enclosure

Procedure

contained

Appendix

this

section

used

obtain

Procedure

F.2

Appendix

this

section

used

obtain

F~.

Recordkeeping

and

Reporting

All

affected

facilities

must

maintain

copy

the

capture

efficiency

protocol

submitted

the

Agency

and

the

USEPA

file.

All

results

the

appropriate

test

methods

and

capture

efficiency

protocols

must

reported

the

Agency

within

sixty

(60)

days

the

test

date.

copy

the

 results must be

kept

file

with

the

source

for

period

three

(3)

years.

any

changes

are

made

 capture or control

equipment, then the source is required to

notify the Agency and the USEPA of these

changes and a new test may be required by the

Agency or the USEPA.

C)

 The source must notify the Agency 30 days

prior to performing any capture efficiency or

control test.

 At that time,

 the source must

notify the Agency which capture efficiency

protocol and control device test methods

will

be used.

D)

 Sources utilizing a PTE must demonstrate that

this enclosure meets the requirement given in

Procedure T

 (in Appendix B of this Part)

for

a PTE during any testing of their control

device.

E)

 Sources utilizing a TTE must demonstrate that

their TTE meets the requirements given in

Procedure T (in Appendix B of this Part)

for

a TTE during testing of their control device.

The source must also provide documentation

that the quality assurance criteria for a

TTE

have been achieved.

119—284

49

d)

 Control

Device Efficiency Testing and Monitoring

1)

 The control device efficiency shall be determined

by simultaneously measuring the inlet and outlet

gas phase VON concentrations and gas volumetric

flow rates in accordance with the gas phase test

methods specified in subsection

 (f).

2)

 Any owner or operator that uses an afterburner or

carbon adsorber to comply with any Section of this

Part shall use USEPA approved continuous

monitoring equipment which is installed,

calibrated,

 maintained, and operated according to

vendor specifications at all times the afterburner

or carbon adsorber is in use.

 The continuous

monitoring equipment must monitor the following

parameters:

A)

 Combustion chamber temperature of each

afterburner.

Temperature

rise

across

each

catalytic

afterburner

bed

VON

concentration

exhaust.

The

VON

concentration

each

carbon

adsorption

bed

exhaust.

Overall

Efficiency

1)

 The overall efficiency of the emission control

system shall be determined as the product of the

capture system efficiency and the control device

 efficiency or by the liquid/liquid test protocol

as specified in 40 CFR 60.433, incorporated by

reference in Section 218.112,

 (and revised by

subsection

 (c) (1) (B)

 for each solvent recovery

system.

 In those cases in which the overall

efficiency is being determined for an entire

 line,

the capture efficiency used to calculate the

product of the capture and control efficiency is

the total capture efficiency over the entire

 line.

2)

 For coating lines which are both chosen by the

owner or operator to comply with Section

218.207(a),

 (d),

 (e),

 (f), or

(g)

 by the

alternative in Section 218.207(b) (2) and meet the

criteria allowing them to comply with Section

218.207 instead of Section 218.204, the overall

efficiency of the capture system and control

device, as determined by the test methods and

119—285

50

procedures

specified

subsections

(c),

(d)

and

(e)

(1),

shall

less

than

the

equivalent

overall efficiency which shall be calculated by

the following equation:

E

 (LVOM

 VOM1:J/VOMa) x 100

where:

E

 Equivalent overall efficiency of the

capture system and control device as a

percentage,

VOMa

 Actual VOM content of a coating,

 or the

daily-weighted average VOM content of

two or more coatings

 (if more than one

coating

 is used),

 as applied to the

subject coating line as determined by

the applicable test methods and

procedures specified in subsection

(a)

in units of kg VOM/l

 (lb VON/gal)

of

coating solids as applied,

VOM1

 The VON emission limit specified in

Section 218.207(a) or

(b)

 in units of kg

VON/l

 (lb VOM/gal)

 of coating solids as

applied.

f)

 Volatile Organic Material Gas Phase Source Test Methods

The methods in 40 CFR Part 60, Appendix A,

 incorporated

by reference in Section

218.112 delineated below shall

be used to determine control device efficiencies.

CFR

Part

60,

Appendix

Method

18,

25A,

incorporated

reference

Section

218.112

appropriate

the

conditions

the

site,

shall

used

determine

VON

concentration.

Method

selection

shall

based

 consideration of the

diversity

organic

species

present

and

their

total

concentration

and

consideration

the

potential

presence

interfering

gases.

Except

indicated

subsections

(f)

(1)

(A)

and

(B)

below,

the

test

shall

consist

 three separate

runs,

each

lasting

minimum

mm,

unless

the

Agency

and

the

USEPA

determine

that

process

variables

dictate

shorter

sampling

times.

When

the

method

used

determine

the

efficiency

carbon

adsorption

system

with

common

exhaust

stack

for

all

the

119—286

51

individual

adsorber

vessels,

the

test

shall

consist

three

separate

runs,

each

coinciding

with

one

complete

sequences

through

the

adsorption

cycles

all

the

individual

adsorber

vessels.

When

the

method

used

determine

the

efficiency

carbon

adsorption

system

with

individual

exhaust

stacks

for

each

adsorber

vessel,

each

adsorber

vessel

shall

tested

individually.

The

test

for

each

adsorber

vessel

shall

consist

 three

separate

runs.

Each

run

 shall coincide with

one

complete

adsorption

cycles.

CFR

Part

60,

Appendix

Method

1A,

incorporated

 by reference in Section 218.112,

shall be used for sample and velocity traverses.

3)

 40 CFR Part 60, Appendix A, Method

2,

2A,

 2C or

2D,

 incorporated by reference in Section 218.112,

shall be used for velocity and volumetric flow

rates.

4)

 40 CFR Part 60, Appendix A, Method

 3, incorporated

by reference in Section

218.112, ‘shall be used for

gas

analysis.

CFR

Part

60,

Appendix

Method

incorporated

reference

Section

218.112,

shall

used

for

stack

gas

 moisture.

CFR

Part

60,

Appendix

Methods

2A,

2C,

2D,

and

incorporated

reference

Section

218.112,

shall

performed,

applicable,

least

twice

during

each

test

run.

Use

adaptation

any

the

test

methods

specified

subsections

(f)

(1),

(2),

(3),

(4)

(5)

and

(6)

may

not

used

unless

approved

the

Agency

and

the

USEPA.

owner

operator

must

submit

sufficient

documentation

for

the

Agency

and

the

USEPA

find

that

the

test

methods

specified

subsections

(f)(1),

(2),

(3),

(4),

(5)

and

(6)

will

yield

inaccurate

results

and

that

the

proposed

adaptation

appropriate.

‘g)

Leak

Detection

Methods

for

Volatile

Organic

Material

Owners

operators

required

this

Part

carry

out

a leak detection monitoring program shall comply with

the following requirements:

119—28 7

52

1)

 Leak Detection Monitoring

A)

Monitoring

shall

comply

with

CFR

60,

Appendix

Method

21,

incorporated

reference

Section

218.112.

The

detection

instrument

shall

meet

the

performance

criteria

Method

21.

The

instrument

shall

calibrated

before

use

each

day

its

use

the

methods

specified

Method

21.

Calibration

gases

shall

be:

Zero

air

(less

than

loppm

hydrocarbon

air);

and

ii)

mixture

methane

 n-hexane and air

concentration

approximately,

but

less

than,

 10,000 ppm methane or

n—hexane.

E)

 The instrument probe shall be traversed

around all potential leak interfaces as close

to the interface as possible as described in

Method

21.

2)

 When equipment is

tested

for

compliance

with

detectable emissions as required, the test shall

comply with the following requirements:

A)

 The requirements of subsections

 (g) (1) (A)

through

 (g) (1) (E) above shall apply.

B)

 The background level shall be determined as

set forth in Method 21.

3)

 Leak detection tests shall be performed consistent

with:

“APTI

Course

417

controlling

Volatile

Organic

Compound

Emissions

from

Leaking

Process

Equipment”,

EPA—450/2—82—0l5,

incorporated

reference

Section

218.112.

“Portable

Instrument

User’s

Manual

for

Monitoring

VOC

Sources”,

EPA—340/ 1—86-015,

incorporated

reference

Section

218.112.

C)

 “Protocols

 ~-GeneratingUnit-Specific

119—288

Emission

Estimates

for

Equipment

Leaks

VOC

and

VHAP”,

 EPA—450/3—88-010,

 incorporated by

reference

Section

218.112.

“Petroleum

Refinery

Enforcement

Manual”,

EPA-340/1—8O-008,

incorporated

reference

Section

218.122.

Bulk

Gasoline

Delivery

 System Test Protocol

The

method

for

determining

the

emissions

gasoline

from

vapor

recovery

system

are

delineated

CFR

60,

Subpart

XX,

 Section

60.503,

incorporated

reference

Section

218.112.

Other

tests

 shall be performed consistent with:

“Inspection

Manual

for

Control

Volatile

Organic Emissions from Gasoline Marketing

Operations:

 Appendix D”, EPA-340/l-80-012,

incorporated by reference in Section 218.112.

B)

 “Control of Hydrocarbons from Tank Truck

Gasoline Loading Terminals:

 Appendix A”,

EPA-450/2-77-026,

 incorporated by reference

in Section 218.112.

Section 218.106

 Compliance Dates

a)

 Compliance with the requirements of all rules

is

required by July

1,

 1991,

 or sixty days after a final

decision by a federal court of the general appeal of

the FIP

 (Illinois Environmental Regulatory Group

V.

USEPA,

 No. 90-2778

 (and consolidated cases)

 (7th

Cir.)), whichever is later, consistent with the

provisions of Section 218.103.

b)

 Compliance with the requirements of provisions of this

Part specifically applicable to a category of sources

which

 is the same as any of the individual appeals of

the FIP shall be required by July 1,

 1991,

 or sixty

days following a final decision by a federal court of

the appeal of the FIP impacting the specific category

of sources, whichever is later,

 consistent with the

provisions of Section 218.103.

Section 218.107

 Afterburners

The operation of any natural gas fired afterburner and capture

system used to comply with this Part is not required during the

period of November

 1 of any year to April

 1 of the following year

119—289

54

provided

that

the

operation

such

devices

not

required

for

purposes

occupational

safety

health,

for

the

control

toxic

substances,

odor

nuisances,

other

regulated

pollutants.

Section

218.108

Exemptions,

Variations,

and

Alternative

Means

Control

Compliance

Determinations

Notwithstanding

the

provisions

any

other

Sections

this

Part,

any

 exemptions,

 variations or alternatives to the control

requirements, emission limitations, or test methods set forth in

this Part shall be effective only when approved by the Agency and

approved by the USEPA as a SIP revision.

Section 218.109

 Vapor Pressure of Volatile Organic Liquids

a)

 If the VOL consists of only a single compound, the

vapor pressure shall be determined by ASTM Method

D2879—86 (incorporated by reference in Section 218.112)

or the vapor pressure may be obtained from a published

source such as:

 Boublik, T.,

 V. Fried and E.

 Hala,

“The Vapor Pressure of Pure Substances,” Elsevier

Scientific Publishing Co., New York

 (1973); Perry’s

Chemical Engineer’s Handbook, McGraw—Hill Book Company

(1984); CRC Handbook of Chemistry and Physics, Chemical

Rubber Publishing Company

 (1986-87); and Lange’s

Handbook of Chemistry,

 John A. Dean,

 editor,

McGraw-Hill Book Company

 (1985).

b)

 If the VOL is a mixture, the vapor pressure shall be

determined by ASTM Method D2879-86 (incorporated by

reference in Section 218.112)

 or by the following

equation:

n

P~rol

 SP~X~

where:

t’VOl

Total

vapor

pressure

the

mixture,

Number

components

the

mixture,

Subscript

denoting

individual

component,

Vapor

pressure

component

determined

accordance

with

Subpart

this

Part

119—290

Mole

fraction

the

component

the

total

mixture.

Section

218.110

Vapor

Pressure

Organic

Material

Solvent

the

organic

material

solvent

consists

only

single

compound,

the

vapor

pressure

shall

determined

ASTM

Method

D2879-86

(incorporated

reference

Section

218.112)

the

vapor

pressure

may

obtained

from

published

source

such

as:

Boublik,

T.,

Fried

and

Hala,

“The

Vapor

Pressure

Pure

 Substances,”

Elsevier Scientific Publishing Co., New York

 (1973);

Perry’s Chemical Engineer’s Handbook, McGraw-Hill Book

Company

 (1984); CRC Handbook of Chemistry and Physics,

Chemical Rubber Publishing Company

 (1986-87);

and

Lange’s Handbook of Chemistry, John A.

 Dean,

 editor,

McGraw-Hill Book Company (1985).

b)

 If the organic material or solvent is in a mixture made

up of both

organic

material

compounds

and

compounds

which are not organic material, the vapor pressure

shall be determined by the following equation:

n

Spixi

~om

i1

where:

P

Total vapor pressure of the portion of the

mixture which is composed of organic

material,

Number

 organic material components in

the

mixture,

I

Subscript

denoting

individual

component,

P~ =Vapor pressure of an organic material

component determined in accordance with

Subpart A of this Part,

X1

 =Mole fraction of the organic material

component

the

total

mixture.

119—291

56

C)

the

organic

material

solvent

mixture

made

up of only organic material compounds, the vapor

pressure shall be determined by ASTM Method D2879-86

(incorporated

reference

Section

218.112)

the

above

equation.

Section 218.111

 Vapor Pressure of Volatile Organic Material

the

VON

consists

only

single

compound,

the

vapor

pressure

shall

determined

ASTM

Method

D2879-86

(incorporated

reference

Section

218.112)

the

vapor

pressure

may

obtained

from

published

source

such

as:

Boublik,

T.,

Fried

and

Hala,

“The Vapor Pressure of Pure Substances,” Elsevier

Scientific

Publishing

Co.,

New

York

(1973);

Perry’s

Chemical Engineer’s Handbook,

McGraw-Hill

Book

Company

(1984);

CRC

Handbook

Chemistry

and

Physics,

Chemical

Rubber

Publishing

Company

(1986-87);

and

Lange’s

Handbook of Chemistry, John A.

 Dean,

 editor,

McGraw-Hill

Book

Company

(1985).

the

VON

mixture

made

both

VON

compounds and compounds which are not VON,

 the vapor

pressure shall be determined by the following equation:

Spixi

~vom

i1

SX1

where:

Total

vapor

pressure

the

portion

the

mixture

which

composed

VON,

Number

VON

components

the

mixture,

 Subscript denoting an individual

component,

Vapor

pressure

VON

component

determined in accordance with Subpart A

this

Part,

Mole

fraction

the

VON

component

the

total

mixture.

the

VON

mixture

made

only

VOM

119—292

57

compounds,

the

vapor

pressure

shall

 be determined by

ASTM Method D2879-86 (incorporated by reference in

Section

 218.112)

 or by the above equation.

Section 218.112

 Incorporations by Reference

The

following

materials

are

incorporated

reference:

a)

 American Society for Testing and Materials,

 1916 Race

Street,

Philadelphia,

19103:

ASTM

D2879—86

ASTM

D323—82

3)

 ASTM D86—82

4)

 ASTM D—369—69

 (1971)

5)

 ASTM D—396—69

6)

 ASTM D2880—71

7)

 ASTM D—975—68

8)

 ASTM D3925—81

 (1985)

9)

 ASTM E300—86

10)

 ASTM D1475—85

11)

 ASTN D2369—87

12)

ASTM

D3792—86

13)

 ASTN D4017—8l

 (1987)

14)

 ASTM D4457—85

15)

 ASTM D2697—86

16)

ASTM

D3980—87

17)

 ASTN E180—85

18)

 ASTM D2372—85

19)

 ASTN D97—66

20)

 ASTM E—168

21)

 ASTM E—l69

22)

 ASTM E—260

23)

 ASTM D2504—83

24)

 ASTN D2382—83

b)

 Standard Industrial Classification Manual, published by

Executive Office of the President, Office of Management

and Budget, Washington,

 D.C.,

 1987.

c)

 American Petroleum Institute Bulletin 2517,

“Evaporation Loss From Floating Roof Tanks”, Second

ed.,

 February,

 1980.

CFR

(July

1990).

CFR

61

 (July 1,

 1990).

CFR

(July

1989).

g)

 40 CFR 51

 (July

1,

 1989).

119—2 93

CFR

 (July 1,

 1989).

 United States Environmental Protection Agency,

Washington,

 D.C.,

 EPA—340/1—86—0l6.

j)

United

States

Environmental

Protection

Agency,

Washington D.C., EPA—450/3—84-019.

k)

 United States Environmental Protection Agency,

Washington D.C., EPA—340/1-88-003.

1)

 United States Environmental Protection Agency,

Washington

D.C.,

EPA—450/3—88—0l8.

m)

 United States Environmental Protection Agency,

Washington,

 D.C.,

 EPA—450/2—78-029.

n)

 United States Environmental Protection Agency,

Washington,

 D.C.,

 EPA—450/2—78—05l.

o)

 United States Environmental Protection Agency,

Washington,

 D.C.,

EPA-450/3—82—009.

SUBPART

B:

 ORGANIC EMISSIONS FROM STORAGE AND LOADING OPERATIONS

Section 218.121

Storage

Containers

No person

shall cause or allow the storage of any VOL with a

 vapor pressure of 17.24 kPa

 (2.5 psia)

 or greater at 294.3 K

(7OoF)

 or any gaseous organic material

 in any stationary tank,

reservoir

other

container

than

 151 cubic meters

(40,000

gal)

capacity

unless

such

tank,

 reservoir or other

container:

a)

Is

pressure

tank

capable

withstanding

the

vapor

pressure of such liquid or the pressure of the gas,

so

as to prevent vapor or gas loss to the atmosphere at

all times; or,

b)

 Is designed and equipped with one of the following

vapor

loss

control

devices:

1)

 A floating roof which rests on the surface of the

VOL and is equipped with a closure seal or seals

between the roof edge and the tank wall.

 Such

floating

roof

shall

not

permitted

the

VOL

has

vapor

pressure

 86.19 kPa

 (12.5

psia)

greater at

294.3oK

 (7OoF).

No

person shall cause

allow

the

emission

air

contaminants

into

the

atmosphere

from

any

gauging

sampling

devices

attached

such

tanks,

except

during

sampling

maintenance

operations.

119—294

59

2)

 A vapor recovery system consisting of:

vapor

gathering

system

capable

collecting 85

 or more of the uncontrolled

VOM that would be otherwise emitted to

the

atmosphere;

 and,

B)

 A vapor disposal system capable of processing

such VOM so as to prevent its emission to the

atmosphere.

 No person shall cause or allow

the

emission

air

contaminants

into

the

atmosphere from any gauging or sampling

devices

attached

such

 tank,

 reservoir or

other container except during sampling.

3)

 Other equipment or means of equal efficiency

approved by the Agency according to the provisions

of

35 Ill. Adm.

 Code 201, and further processed

consistent with

Section 218.108.

Section 218.122

 Loading Operations

a)

 No person shall cause or allow

the discharge of more

than 3.6 kg/hr

 (8 lbs/hr)

 of organic material into the

atmosphere during the loading of any organic material

from the aggregate loading pipes of any loading

facility having through-put of greater than 151 cubic

meters

per

day

(40,000

gal/day)

into

any

railroad

tank

car, tank truck or trailer unless such loading facility

is equipped with submerged loading pipes,

 submerged

fill or a device that is equally effective in

controlling emissions and is approved by the Agency

according to the provisions of

35 Ill. Adm. Code 201,

and further processed consistent with Section 218.108.

b)

No

person

shall

cause

 allow the loading of any

organic

material

into

any

 stationary tank having a

storage capacity of greater than 946

1

 (250 gal),

unless such tank

 is equipped with

 a permanent submerged

loading pipe,

 submerged fill or an equivalent device

approved by the Agency according to the provisions of

35

 Ill.

 Adm. Code 201, and further processed consistent

with

Section

218.108,

unless

such

tank

pressure

tank as described in Section 218.121(a)

 or is fitted

with a recovery system as described in Section

218.121(b)(2).

c)

 Exception:

 If no odor nuisance exists the limitations

this

Section

shall

only

apply

the

VOL

with a vapor pressure of 17.24 kPa

 (2.5 psia)

or

greater at 294.3oK (70°F).

119—295

60

Section 218.123

 Petroleum Liquid Storage Tanks

a)

 The requirements of subsection

(b)

 shall not apply

to

any stationary storage tank’:

1)

 Equipped before January

1,

 1979 with one of the

vapor loss control devices specified in Section

218.121(b), except Section 218.121(b) (1);

2)

 With a capacity of less than 151.42 cubic meters

(40,000 gal);

3)

 With a capacity of less than

1,600

 cubic meters

(422,400 gal)

 and used to store produced crude

oil

and condensate prior to custody transfer;

4)

 With a capacity of

 less than 1,430 cubic meters

(378,000 gal) and used to store produced oil or

condensate in crude oil gathering;

5)

 Subject to new source performance standards for

storage vessels of

petroleum liquid,

 35 Ill. Adm.

Code 230;

6)

 In which volatile petroleum liquid

 is not stored;

or

7)

 Which is a pressure tank as described in Section

218.121(a).

b)

 Subject to subsection

 (a) no owner or operator of a

stationary storage tank shall cause or allow the

storage of any volatile petroleum liquid in the tank

unless:

1)

 The tank is equipped with one of the vapor loss

control devices specified in Section 218.121(b);

2)

 There are no visible holes, tears or other defects

in the seal or any seal fabric or material of any

floating roof;

3)

 All openings of any floating roof deck,

 except

stub drains, are equipped with covers,

 lids or

seals such that:

A)

 The cover,

 lid or seal

 is in the closed

position at all times except when petroleum

liquid is transferred to or from the tank;

B)

 Automatic bleeder vents are closed at all

119—296

61

times except when the roof

 is floated off or

landed on the roof leg supports; and

C)

 Rim vents,

 if provided, are set to open when

 the roof

 is being floated of

f the roof leg

supports or at the manufacturer’s recommended

setting;

4)

 Routine inspections of floating roof seals are

conducted through roof hatches once every six

months;

5)

 A complete inspection of the cover and seal of any

floating roof tank is made whenever the tank is

emptied for reasons other than the transfer of

petroleum liquid during the normal operation of

the

tank,

whenever

repairs

are

made

result

of any semi—annual inspection or incidence of roof

damage or defect; and

6)

 A record of the results of each inspection

conducted under subsection

 (b) (4)

or

 (b) (5)

is

maintained.

C)

 Owners and operators of petroleum liquid storage tanks

were required to have compliance schedules as

summarized in Appendix C, to 35 Ill Adm. Code 215.

Section

218.124

 External Floating Roofs

a)

 In addition to meeting the requirements of Section

218.123(b),

 no owner or operator of a stationary

storage tank equipped with an external floating roof

shall cause or allow the storage of any volatile

petroleum liquid in the tank unless:

1)

 The tank has been fitted with a continuous

secondary seal extending from the floating roof to

the tank wall

 (rim mounted secondary seal)

 or any

other device which controls VON emissions with an

effectiveness equal to or greater than a rim

mounted secondary seal;

2)

 Each seal closure device meets the following

requirements:

A)

 The seal

 is intact and uniformly in place

around the circumference of the floating roof

between the floating roof and tank wall;

and

B)

 The accumulated area of gaps exceeding 0.32

centimeter

 (1/8 inch)

 in width between the

119—29

62

secondary

seal

and

the

tank

wall

 shall not

exceed 21.2 square centimeters per meter of

tank

diameter (1.0 square inches per foot of

tank diameter).

3)

 Emergency roof drains are provided with slotted

membrane fabric covers or equivalent covers across

at least 90 percent of the area of the opening;

4)

 Openings are equipped with projections into the

tank which remain below the liquid surface at all

times;

5)

 Inspections are conducted prior to Nay 1 of each

year to insure compliance with subsection

 (a);

6)

 The secondary seal gap is measured prior to May

1

of each year;

7)

 Records of the types of volatile petroleum liquid

stored, the maximum true vapor pressure of the

liquid as stored, the results of the inspections

and the results of the secondary seal gap

measurements are maintained and available to the

Agency, upon verbal or written request, at any

reasonable time for a minimum of two years after

the date on which the record was made.

b)

 Subsection

 (a) does not apply to any stationary storage

tank

equipped

 with an external floating roof:

1)

 Exempted under Section 218.123 (a) (2)

 through

218.123 (a) (6);

2)

 Of welded construction equipped with a metallic

type

shoe

seal

 having a secondary seal from the

top

the

shoe

seal

the

tank

wall

(shoe-mounted secondary seal);

3)

 Of welded construction equipped with a metallic

type shoe seal,

 a liquid—mounted foam seal,

a

liquid—mounted liquid—filled—type seal,

 or other

closure device of equivalent control efficiency

approved by the Agency in which

 a petroleum liquid

with a true vapor pressure less than 27.6 kPa

 (4.0

psia)

at

294.3oK

(70°F)

 is stored; or

4)

 Used to store crude oil with a pour point of 50°F

 or higher as determined by ASTM Standard D97-66

incorporated by reference in Section 218.112.

Section 218.125

 Compliance Dates

119—298

63

Every owner or operator of an emission source subject to 35

 Ill.

Adin.

 Code 215,

 Subpart B,

 as of December 31,

 1987 shall have

complied with its standards and limitations by December 31,

 1987.

Section 218.126

 Compliance Plan

a)

 The owner or operator of an emission source previously

subject to Section 215.125 shall have submitted to the

Agency a compliance plan as required by 35 Ill.

 Adm.

Code 201.241, including a project completion schedule

where applicable, no later than April

21,

 1983.

b)

 Unless the submitted compliance plan or schedule was

disapproved by the Agency, the owner or operator of a

facility or emission source subject to the rules

specified in subsection

 (a) may operate the emission

source according to the plan and schedule as submitted.

c)

 The plan and schedule shall meet the requirements of

35

Ill.

 Adm. Code 201.241 including specific interim dates

as required in 35 Ill.

 Adm. Code 201.242.

SUBPART

C:

 ORGANIC EMISSIONS FROM MISCELLANEOUS EQUIPMENT

Section 218.141

 Separation Operations

a)

 No person shall use any single or multiple compartment

effluent water separator which receives effluent

water

containing 757 I/day

 (200 gal/day) or more of organic

material from any equipment processing,

 refining,

treating,

 storing or handling organic material unless

such effluent water separator is equipped with air

pollution control equipment capable of reducing by 85

percent

the

uncontrolled

organic

material

emitted to the atmosphere.

 Exception:

 If no odor

nuisance exists the limitations of this subsection

shall not apply if the vapor pressure of the organic

material

 is below 17.24 kPa (2.5 psia)

 at 294.3oK

(70

oF)

b)

 Subsection

(a)

 shall not apply to water and crude oil

separation in the production of Illinois crude oil,

if

the vapor pressure of such crude oil is less than 34.5

kPa

(5

psia).

Section 218.142

 Pumps and Compressors

No

person shall cause or allow the discharge of more than 32.8

ml

(2 cu in)

 of VOL with vapor pressure of 17.24 kPa

 (2.5 psia)

or

greater at 294.3°K(70°F) into the atmosphere from any pump or

compressor

 in any 15 minute period at standard conditions.

119—299

64

Section 218.143

 Vapor Blowdown

No

person shall cause or allow the emission of organic material

into the atmosphere from any vapor blowdown system or any

safety

relief valve, except such safety relief valves not capable of

causing an excessive release, unless such emission is controlled:

a)

 To 10 ppm equivalent methane (molecular weight 16.0)

or

less;

or,

b)

 By combustion in a smokeless flare;

or,

c)

 By other air pollution control equipment approved by

the Agency according to the provisions of

 35 Ill.

 Adm.

Code 201, and further processed consistent with Section

218.108.

Section 218.144

 Safety Relief Valves

Section 218.143 shall not apply to any set of unregulated safety

relief valves capable of causing excessive releases, provided the

owner or operator thereof,

 by October

1,

 1972,

 supplied the

Agency with the following:

a)

 A historical record of each such set

 (or,

 if such

records were unavailable,

 of similar sets which,

by

virtue of operation under similar circumstances, may

reasonably have been presumed to have the same or

greater frequency of excessive releases)

 for a

three-year period immediately preceding October

1,

1972,

 indicating:

1)

 Dates on which excessive releases occurred from

each such set; and,

2)

 Duration

minutes

each

 such excessive

release; and,

3)

 Quantities

 (in pounds)

 of mercaptans and/or

hydrogen sulfide emitted into the atmosphere

during each such excessive release.

b)

 Proof,

 using such three-year historical records, that

no excessive release is likely to occur from any such

set either alone or in combination with such excessive

releases from other sets owned or operated by the same

person and located within a ten—mile radius from the

center point of any such set, more frequently than

3

times in any 12 month period;

c)

 Accurate maintenance records pursuant to the

119—300

65

requirements of subsection

 (a); and,

d)

 Proof, at three—year intervals,

 using such three—year

historical records, that such set conforms to the

requirements

subsection

(c).

SUBPART E:

 SOLVENT CLEANING

Section 218.181

 Solvent Cleaning in General

The requirements of this Subpart shall apply to all cold

cleaning, open top vapor degreasing,

 and conveyorized degreasing

operations.

Section 218.182

 Cold Cleaning

a)

 Operating Procedures:

 No person shall operate

 a cold

cleaning degreaser unless:

1)

 Waste solvent is stored in covered containers only

and not disposed of in such a manner that more

than 20

 of the waste solvent (by weight)

is

allowed to evaporate into, the atmosphere;

2)

 The cover of the degreaser is closed when parts

are not being handled; and

3)

 Parts are drained until dripping ceases.

b)

 Equipment Requirements:

 No person shall operate a cold

cleaning degreaser unless:

1)

 The degreaser is equipped with a cover which is

closed whenever parts are not being handled in the

cleaner.

 The cover shall be designed to be easily

operated with one hand or with the mechanical

assistance of springs, counter—weights or a

powered system if:

 The solvent vapor pressure is greater than 2

kPa

(15

 nunHg

or 0.3 psi) measured at 38°C

(100°F);

B)

 The solvent

 is agitated; or

C)

 The solvent is heated above ambient room

temperature.

2)

 The degreaser is equipped with a facility for

draining cleaned parts.

 The drainage facility

shall be constructed so that parts are enclosed

under the cover while draining unless:

119—301

66

A)

 The solvent vapor pressure is less than 4.3

kPa

(32

minHg

or 0.6 psi) measured at

38oC

(lOOoF); or

B)

 An internal drainage facility cannot be

fitted into the cleaning system,

 in which

case the drainage facility may be external.

3)

 The degreaser is equipped with one of the

following control devices if the vapor pressure of

the solvent is greater than 4.3 kPa

(32

mmHg or

0.6 psi) measured at 38°C(100°F)or if the

solvent is heated above

5OoC

 (120°F)or its

boiling point:

A)

 A freeboard height of 7/10 of the inside

width of the tank or 91 cm

 (36 in), whichever

is less; or

B)

 Any other equipment or system of equivalent

emission control as approved by the Agency

and further processed consistent with Section

218.108.

 Such a system may include

 a water

cover,

 refrigerated chiller or carbon

adsorber.

4)

 A permanent conspicuous label summarizing the

operating procedure is affixed to the degreaser;

and

5)

 If a solvent spray is used, the degreaser is

equipped with

 a solid fluid stream spray,

 rather

than a fine, atomized or shower spray.

Section 218.183

 Open Top Vapor Degreasing

a)

 Operating Requirements:

 No person shall operate an

open top vapor degreaser unless:

1)

 The cover of the degreaser is closed when

workloads are not being processed through the

degreaser;

2)

 Solvent carryout emissions are minimized by:

A)

 Racking parts to allow complete drainage;

B)

 Moving parts in and out of the degreaser at

less than 3.3 m/min

 (11 ft/mm);

C)

 Holding the parts

 in the vapor zone until

119—302

67

condensation ceases;

D)

 Tipping out any pools of solvent on the

cleaned parts before removal from the vapor

zone; and,

E)

 Allowing parts to dry within the degreaser

until visually dry.

3)

 Porous or absorbent materials, such as cloth,

leather, wood or rope are not degreased;

4)

 Less than half of the degreaser’s open top area is

occupied with a workload;

 The degreaser is not loaded to the point where the

vapor

level

would

drop

than

in)

 when

the

workload

removed

from

the

vapor

zone;

6)

 Spraying is done below the vapor level only;

7)

 Solvent leaks are repaired immediately;

8)

 Waste solvent is stored in covered containers only

and not disposed of in such a manner that more

than 20

 of the waste solvent

 (by weight)

is

allowed to evaporate into the atmosphere;

9)

 Water is not visually detectable in solvent

exiting

from

the

water

separator;

and

10)

 Exhaust ventilation exceeding 20 cubic meters per

minute per square meter

 (65 cubic feet per minute

per square foot)

 of degreaser open area is not

used, unless necessary to meet the requirements of

the Occupational Safety and Health Act

 (29 U.S.C.

Section 651 et seq.).

b)

 Equipment Requirements:

 No person shall operate an

open

top

vapor

degreaser

unless:

1)

 The degreaser is equipped with a cover designed to

open and close easily without disturbing the vapor

zone;

2)

 The degreaser is equipped with the following

switches:

A)

 A device which shuts off the sump heat source

if the amount of condenser coolant is not

sufficient to maintain the designed vapor

level; and

119—303

68

B)

 A device which shuts off the spray pump if

the

vapor

level

drops

than

in)

below the bottom condenser coil; and

C)

 A device which shuts off the suinp heat source

when the vapor level exceeds the design

level.

3)

 A permanent conspicuous label summarizing the

operating procedure is affixed to the degreaser;

The

degreaser

equipped

with

one

the

following devices:

A)

 A freeboard height of 3/4 of the inside width

of the degreaser tank or 91 cm

 (36 in),

whichever is less; and if the degreaser

opening is greater than

 1 square meter

 (10.8

square feet),

 a powered or mechanically

assisted cover; or

B)

 Any other equipment or system of equivalent

emission control as approved by the Agency

and

further

processed

consistent

with

Section

218.108.

 Such equipment or system may

include

 refrigerated chiller,

 an enclosed

design or a carbon adsorption system.

Section 218.184

 Conveyorized Degreasing

a)

 Operating Requirements:

 No person shall operate

a

conveyorized degreaser unless:

1)

 Exhaust ventilation exceeding 20 cubic meters per

minute per square meter

 (65 cubic feet per minute

per square foot)

 of area of loading and unloading

opening is not used,

 unless necessary to meet the

requirements of the Occupational Safety and Health

Act

 (29 U.S.C. Section 651 et seq.).

2)

 Solvent carryout emissions are minimized by:

A)

 Racking parts for best drainage; and

B)

 Maintaining the vertical conveyor speed at

less

than

3.3

rn/mm

 (11 ft/mm);

3)

 Waste solvent

 is stored in covered containers only

and not disposed of in such a manner that more

than 20

 of the waste solvent

 (by weight)

is

allowed

evaporate

into

the

 atmosphere;

119—304

69

4)

 Solvent leaks are repaired immediately;

5)

 Water is not visually detectable in solvent

exiting from the water separator; and

6)

 Downtime covers are placed over entrances and

exits of conveyorized degreasers immediately after

the conveyors and exhausts are shut down and not

removed until just before start—up.

b)

 Equipment Requirements:

 No person shall operate a

conveyorized degreaser unless:

1)

 The degreaser is equipped with a drying tunnel,

rotating (tumbling)

 basket or other equipment

sufficient to prevent cleaned parts from carrying

out solvent liquid or vapor;

2)

 The degreaser is equipped with the following

switches:

A)

 A device which shuts of

the

sump

heat

source

if the amount of condenser coolant

 is not

sufficient to maintain the designed vapor

level;

B)

 A device which shuts off the spray

pump or

the conveyor if the vapor level drops more

than 10 cm

(4

 in) below the bottom condenser

coil; and

C)

 A device which shuts off the sump heat source

when the vapor level exceeds the design

level;

3)

 The degreaser is equipped with openings for

entrances and exits that silhouette workloads so

that the average clearance between the parts and

the edge of the degreaser opening is less than 10

cm

(4

 in) or less than 10 percent of the width of

the opening;

4)

 The degreaser is equipped with downtime covers for

closing off entrances and exits when the degreaser

is shut down;

and

5)

 The degreaser is equipped with one of the

following control devices,

 if the air/vapor

interface

 is larger than 2.0 square meters

 (21.6

square feet):

119—305

70

A)

 A carbon adsorption system with ventilation

greater than or equal to 15 cubic meters per

minute per square meter

 (50 cubic feet per

minute per square foot)

 of air/vapor area

when downtime covers are open, and exhausting

less than 25 ppm of solvent by volume

averaged over a complete adsorption cycle; or

B)

Any

other equipment or system of equivalent

emission control as approved by the Agency,

and further processed consistent with Section

218.108.

 Such equipment or system may

include a refrigerated chiller.

Section 218.185

 Compliance Schedule

Every

owner or operator of an emission source which was

previously exempt from the requirements of Subpart E of

 35 Ill.

Adm.

 Code 215

(Sections 215.182—215.184)

 because it satisfied the

criteria in either 35

 Ill.

 Adm. Code 215.181(a)

 or 35 Ill.

 Adin.

Code 215.181(b),

 shall comply with the requirements of this

Subpart on and after a date consistent with Section 218.106.

A

source which did not satisfy the criteria in either 35

 Ill.

 Adm.

Code 215.181(a)

 or 35

 Ill.

 Adm. Code 215.181(b)

 shall comply with

the requirements of this Subpart upon adoption.

Section 218.186

 Test Methods

The following test methods shall be used to demonstrate

 compliance with this Subpart:

a)

 Vapor pressures shall be determined by using the

procedure specified in Section 218.110.

b)

 Exhaust ventilation rates shall be determined by using

the procedures specified in Section ‘218.105(f) (3).

c)

 The performance of control devices shall be determined

by using the procedures specified in Section

218.105(f).

SUBPART

F:

 COATING OPERATIONS

Section

218.204

Emission

Limitations

for

Manufacturing

Plants

Except as provided in Section 218.208, no owner or operator of

a

coating line shall apply at any time any coating in which the VON

content exceeds the following emission limitations for the

specified coating.

 The following emission

limitations

are

expressed in units of VON per volume of coating

 (minus water and

any compounds which are specifically exempted from the definition

of

VON)

 as applied at each coating applicator,

 except where

119—306

71

noted.

 Compounds which are specifically exempted from the

definition of VOM should be treated as water for the purpose of

calculating the “less water” part of the coating composition.

Compliance with this Subpart must be demonstrated through the

applicable coating analysis test methods and procedures specified

 in Section 218.105(a) and the recordkeeping and reporting

requirements specified in Section

218.211(c).

(Note:

The

equation presented in Section 218.206 shall be used to calculate

emission limitations for determining compliance by add—on

controls, credits for transfer efficiency,

 emissions trades and

cross—line averaging.)

 The emission limitations are as follows:

a)

 Automobile or Light-Duty

 k~/l

 lb/gal

Truck Coating

Prime

coat

0.14

(1.2)

2)

 Prime surfacer coat

 0.34

 (2.8)

(Note:

 The prime surfacer coat limitation is based

upon a transfer efficiency of 30 percent.

 The use

of

transfer

efficiency

credits

can

allowed

only

if

approved by the Agency and approved by the USEPA as

a

SIP

revision.

3)

 Topcoat

 1.81

 (15.1)

(Note:

 The topcoat limitation is

units

(lbs)

of VON per

1

 (gal)

 of coating solids deposited.

Compliance with the limitation shall be based on the

daily—weighted average VON content from the entire

topcoat operation (all topcoat spray booths, flash-off

areas and bake ovens).

 Compliance shall be

demonstrated in accordance with the topcoat protocol

for automobiles and light—duty trucks referenced in

Section 218.105(b).

 Section 218.205 does not apply to

the topcoat limitation.)

 At least

 180 days prior to

the initial compliance date,

 the owner or operator of a

coating line subject to the topcoat limitation shall

have submitted to the USEPA

 a detailed proposal

specifying the method of demonstrating compliance with

the protocol.

 The proposal shall have included,

 at a

minimum,

 a comprehensive plan (including a rationale)

for determining the transfer efficiency at each booth

through the use of in-plant, or pilot testing; the

selection of coatings to be tested (for the purpose of

determining transfer efficiency)

 including the

rationale for coating groupings; and the method for

determining the analytic VON content of as

appliedcoatings

and

the

formulation

solvent

content

of

as applied coatings.

 Upon approval of the protocol by

119—307

72

the USEPA, the source may proceed with the compliance

demonstration

k~/l

 lb/gal

4)

 Final repair coat

 0.58

 (4.8)

b)

 Can Coating

 kg/i

 lb/gal

1)

 Sheet basecoat and

 0.34

 (2.8)

overvarnish

2)

 Exterior basecoat and

 0.34

 (2.8)

overvarnish

3)

 Interior body spray coat 0.51

 (4.2)

Exterior

end

coat

0.51

(4.2)

5)

 Side seam spray coat

0.66

(5.5)

End

sealing

compound

coato.44

(3.7)

k~/l

 lb/gal

Paper

Coating

0.35

(2.9)

(Note:

 The paper coating limitation shall not apply to

any owner or operator of any paper coating line on

which printing

 is performed if the paper coating line

complies with the emissions limitations in Subpart H:

Printing

and

Publishing,

Sections

218.401

through

218.404.)

k~/l

 lb/gal

d)

 Coil Coating

 0.31

 (2.6)

e)

 Fabric Coating

 0.35

 (2.9)

f)

Vinyl

Coating

0.45

(3.8)

g)

 Metal Furniture Coating

 0.36

 (3.0)

h)

 Large

Appliance Coating

 0.34

 (2.8)

(Note:

 The limitation shall not apply to the use of

quick-drying lacquers for repair of scratches and nicks

 that occur during assembly, provided that the volume of

coating

does

not

exceed

0.95

quart)

 in any one

rolling eight-hour period.)

119—308

73

1)

 Wood

1)

3)

4)

5)

6)

7)

k~/1

0.20

0.52

0.42

0.42

0.36

kg/i

0.67

0.56

0.60

0.67

0.67

0.79

0.73

lb/gal

(1.7)

(4.3)

(3.5)

(3.5)

(3.0)

lb/gal

(5.6)

(4.7)

(5.0)

(5.6)

(5.6)

(6.6)

(6.1)

i)

 Magnet Wire Coating

 Miscellaneous Metal Parts and

Products

Coating

1)

 Clear coating

Air-dried

coating

3)

 Extreme performance

coating

4)

 All other

coatings

Heavy

Off-Highway

Vehicle

Products Coating

1)

 Extreme performance

 0.42

 (3.5)

prime

coat

2)

 Extreme performance top-

 0.42

 (3.5)

coat

(air

 dried)

Final

repair

coat

0.42

 (3.5)

(air dried)

4)

All

other coatings are subject to the emission

limitations for miscellaneous metal parts

 and’

products coatings in subsection

(j)

 above.

kg/i

 lb/gal

Furniture Coating

Clear

topcoat

Opaque stain

Pigmented coat

Repair coat

Sealer

Semi—transparent stain

Wash coat

119—309

74

(Note:

 An owner or operator of a wood furniture

coating operation subject to this Section shall apply

all coatings, with the exception of no more than 37.8

1

(10 gal)

 of coating per day used for touch-up and

repair operations, using one or more of the following

application systems:

 airless spray application system,

air—assisted airless spray application system,

electrostatic spray application system, electrostatic

bell or disc spray application system, heated airless

spray application system,

 roller coating, brush or wipe

coating application system,

 or dip coating application

system.)

m)

 Existing Diesel-Electric Locomotive Coating Lines

in

Cook County

k~Jl

lb/gal

1)

 Extreme performance prime

 0.42

 (3.5)

coat

2)

 Extreme performance top-

 0.42

 (3.5)

coat

 (air dried)

Final

repair

coat

0.42

(3.5)

(air dried)

4)

 High-temperature aluminum

 0.72

 (6.0)

coating

5)

 All other coatings

 0.36

 (3.0)

Section 218.205

 Daily—Weighted Average Limitations

No owner or operator of a coating line subject to the limitations

of Section 218.204 and complying by means of this Section shall

operate

the

subject

coating

line

unless

the

owner

operator

has

demonstrated compliance with subsection

 (a),

 (b),

 (c),

 (d),

(e)

or

(f)

 (depending upon the source category) through the

applicable

coating

analysis

test

methods

and

procedures

specified

in Section 218.105(a)

 and the recordkeeping and reporting

requirements specified in Section 218.211(d):

a)

 No owner or operator of a coating line subject to only

one of the limitations from among Section

218.204(a)(l),

 (a)(2),

 (a)(4),

 (C),

 (d),

 (e),

 (f),

 (g),

(h),

or

(i)

 shall apply coatings on any such coating

line, during any day, whose daily-weighted average VON

content exceeds the emission limitation to which the

coatings are subject.

119—310

75

b)

 No owner or operator of a miscellaneous metal parts and

products coating line subject to the limitations of

Section 218.204(j)

 shall apply coatings to

miscellaneous metal parts or products on the subject

coating line unless the requirements in subsection

(b) (1) or

 (b) (2) below are met.

1)

 For each coating line which applies multiple

coatings, all of which are subject to the same

numerical emission limitation within Section

218.204(j)

 above, during the same day

 (e.g.,

all

coatings used on the line are subject to 0.42 kg/i

3.5

 lbs/gal),

 the daily-weighted average VON

content shall not exceed the coating VON content

limit corresponding to the category of coating

used,

or

2)

 For each coating line which applies coatings from

than

one

the

four

coating

categories

in

Section 218.204(j)

 above,

 during the same day, the

owner or operator shall have a site—specific

proposal approved by the Agency and approved by

the

USEPA

SIP

revision.

receive

approval,

the

requirements

USEPA’s

Emissions

Trading

Policy Statement

 (and related policy) must be

satisfied.

c)

 No owner or operator of a can coating facility subject

to the limitations of Section 215.204(b)

 shall operate

the subject coating facility using a coating with a

VOM

content in excess of the limitations specified in

Section

215.204(b)

 unless all of the following

requirements are met:

1)

 An alternative daily emission limitation shall be

determined according to subsection

 (c) (2)

 below.

Actual daily emissions shall never exceed the

alternative daily emission limitation and shall be

calculated

use

 the following equation.

U

E

S

 V.C.

d

i=1

~

where:

Ed

 Actual VON emissions for the day in

units of kg/day

 (lbs/day),

i

Subscript

denoting

specific

coating

applied,

119—311

76

n

 Total number of coatings applied in the

can coating operation,

V~

 Volume of each coating applied for the

day in units of i/day (gal/day)

of

coating (minus water and any compounds

which are specifically exempted from the

definition of VOM),

and

C~

 The VON content of each coating as

applied in units of kg VON/i

 (lbs

VOM/gal)

coating

(minus

water

and

any

compounds which are specifically

exempted

from

the

definition

VON).

2)

 The alternative daily emission limitation

 (Ad)

shall be determined on a daily basis as follows:

Ad

 S V~L~LQ1

C~j

(D~

—

L~)

where:

Ad

 The VON emissions allowed for the day

in

units of kg/day

 (lbs/day),

i

 Subscript denoting a specific coating

applied,

n

 Total number of surface coatings applied

in the can coating operation,

C~

 The VOM content of each surface coating

as applied in units of kg VON/i

 (lbs

VON/gal)

 of coating (minus water and any

compounds which are specifically

exempted from the definition of VOM),

 The density of

VOM

each

coating

applied.

 For the purposes of

calculating Ad, the density

is

0.882 kg VON/i VON (7.36 lbs VON/gal

VOM),

 Volume of each surface coating applied

for the day in units of

1

 (gal)

of

coating (minus water and any compounds

which are specifically exempted from the

definition of VON),

119—312

77

The

VON

emission

limitation

for

each

surface coating applied as specified in

Section 218.204(b)

 in units of kg VON/i

(lbs

VON/gal)

coating

(minus

water

and any compounds which are specifically

exempted from the definition of VON).

d)

 No owner or operator of a heavy off—highway vehicle

products coating line subject to the limitations of

Section

 218.204(k)

 shall apply coatings to heavy

off-highway vehicle products on the subject coating

line unless the requirements of subsection

 (d) (1)

or

(d) (2) below are met.

I)

For

each

coating

 line which applies multiple

coatings, all of which are subject to the same

numerical

emission

limitation

within

Section

218.204(k)

above,

during

the

same

day

(e.g.,

all

coatings used on the line are subject to 0.42 kg/i

3.5

 lbs/gal),

 the daily-weighted average VON

content shall not exceed the coating VON content

limit corresponding to the category of coating

used,

or

2)

 For each coating line which applies coatings

subject

than

 one numerical emission

limitation

Section

218.204(k)

above,

during

the

same

day,

the

owner

operator

shall

have

site

specific

proposal

approved

the

Agency

and

approved by the USEPA as a SIP revision.

To

receive approval, the requirements of USEPA’s

Emissions Trading Policy Statement (and related

 policy) must be satisfied.

e)

 No owner or operator of a wood furniture coating line

subject to the limitations of Section 218.204(1)

 shall

apply coatings to wood furniture on

the

subject

coating

line

unless

the

requirements

subsection

(e)

(1)

(e) (2),

 in addition to the requirements specified in

the note to Section 218.204(1),

 are met.

1)

 For each coating line which applies multiple

coatings, all of which are subject to the same

numerical emission limitation within Section

218.204(1)

 above, during the same day (e.g., all

coatings used on the line are subject to 0.67 kg/i

5.6

 lbs/gal)),

 the daily-weighted average VON

content shall not exceed the coating VOM content

limit corresponding to the category of coating

used,

or

119—313

78

For

each

coating

line

which

applies

coatings

subject

than

one

numerical

emission

limitation

Section

218.204(1)

above,

during

the

same day, the owner or operator shall have a site

 specific proposal approved by the Agency and

approved by the USEPA as a SIP revision.

To

receive approval, the requirements of USEPA’s

Emissions Trading Policy Statement (and related

policy) must be satisfied.

f)

 No owner or operator of an existing diesel—electric

locomotive coating line in Cook County, subject to the

limitations of Section 218.204(m)

 shall apply coatings

to diesel—electric locomotives on the subject coating

line unless the requirements of subsection

 (b) (1)

or

(b) (2)

 are met.

1)

 For each coating line which applies multiple

coatings, all of which are subject to the same

numerical

emission

limitation

within

Section

218.204(m)

 above, during the same day

 (e.g.,

all

coatings

used

the

line

are

subject

0.42

kg/i

3.5

 lbs/gal),

 the daily—weighted average VON

content shall not exceed the coating VON content

limit corresponding to the category of coating

used,

For

each

coating

 line which applies coatings

subject

than

one

numerical

emission

limitation in Section 218.204(m)

 above,

 during the

 same day, the owner or operator shall have a site

specific

proposal

approved

the

Agency

and

approved

the

USEPA

SIP

revision.

receive

approval,

the

requirements

USEPA’s

Emissions Trading Policy Statement

 (and related

policy)

must

 satisfied.

Section 218.206

 Solids Basis Calculation

Limitations in terms of kg

 (lbs) of VON emissions per

1

 (gal)

of

solids as applied at each coating applicator shall be determined

by the following equation:

5=

C

1

—

 (C/D)

where:

S

 The limitation on VON emissions in terms

of kg VON/i

 (lbs VON/gal)

 of solids,

119—3 14

79

C

The

limitation

VON

emissions

terms

of kg/l

 (lbs/gal)

 of coating (minus

water and any compounds which are

specifically

excluded

from

the

definition of VON)

 specified in Section

218.204,

D

The

density

VON

the

coating.

For

the purposes of calculating

 5, the

density is 0.882 kg VOM/l VON (7.36 lbs

VOM/gal VON).

Section

218.207

 Alternative Emission Limitations

Any

owner

operator

coating

line

subject

Section 218.204 may comply with this Section, rather

than with Section 218.204,

 if a capture system and

control

device

are

operated

all

times

and

the

owner

operator

demonstrates

compliance

with

 subsections

(c),

 (d),

 (e),

 (f),

(g)

or

(h)

 (depending upon the

source category) through the applicable coating

analysis

and

capture

system

and

control

 device

efficiency

test

methods

and

 procedures specified in

Section 218.105 and the recordkeeping and reporting

requirements specified in Section 218.211(e); and the

control device is equipped with the applicable

monitoring equipment specified in Section 218.105(d)

and the monitoring equipment is installed,

 calibrated,

operated and maintained according to vendor

specifications

all

times

the

control

device

use.

 A capture system and control device, which does

not demonstrate compliance with subsection

 (c),

 (d’),

(e),

 (f),

(g)

or

 (h) may be used as an alternative to

compliance with Section 218.204 only if the alternative

is approved by the Agency and approved by the USEPA as

a SIP revision.

b)

 Alternative Add-On Control Methodologies

1)

 The coating line is equipped with a capture system

and control device that provides 81 percent

reduction in the overall emissions of VOM from the

coating line and the control device has

 a 90

percent efficiency,

or

2)

 The system used to control VOM from the coating

line is demonstrated to have an overall efficiency

sufficient to limit VON emissions to no more than

what is allowed under Section 218.204.

 Use of any

control system other than an afterburner, carbon

adsorption,

 condensation, or absorption scrubber

system

can

allowed

only

approved

the

119—315

80

Agency and approved by the USEPA as a SIP

 revision.

 The use of transfer efficiency credits

can be allowed only if approved by the Agency and

approved by the USEPA as a SIP revision.

 Baseline

transfer efficiencies and transfer efficiency test

methods must be approved by the Agency and the

USEPA.

Such overall efficiency is to be determined as

follows:

obtain

the

emission

limitation

from

the

appropriate

subsection

Section

218.204,

B)

 calculate “S” according to the equation

in

Section

218.206,

3)

 calculate the overall efficiency required

according to Section 218.105(e).

 For the purposes

of calculating this value, according to the

equation in Section 218.105(e) (2), VON1

 is equal

to the value of “S” as determined above

in

subsection

 (b) (2) (B).

c)

 No owner or operator of a coating line subject to

only

one

the

emission

 limitations from among Section

218.204 (a) (1),

 (a) (2),

 (a) (4),

(c)

(d)

(e)

(f)

(g)

(h)

or

 (i) and equipped with a capture system and

control device shall operate the subject coating line

unless

the

requirements

subsection

(b) (1)

(b) (2)

above are met.

 No owner or operator of a coating line

subject to Section 218.204(a) (3)

 and equipped with a

capture system and control device shall operate the

coating line unless the owner or operator demonstrates

compliance

with

the

topcoat

limitation

accordance

with

the

topcoat

protocol

 for automobile or light-duty

trucks referenced in Section 218.105(b).

d)

 No owner or operator of a miscellaneous metal parts and

products coating line which applies one or more

coatings during the same day, all of which are subject

to the same numerical emission limitation within

Section

218.204(j)

(e.g.,

all

coatings

used

the

line

are subject to 0.42 kg/i 3.5

 lbs/gal)), and which

is

equipped with a capture system and control device shall

operate

the

subject

coating

line

unless

the

requirements in subsection

 (b) (1)

or

 (b) (2)

 above are

met.

e)

 No owner or operator of a heavy off—highway vehicle

products coating line which applies one or more

119—316

81

coatings during the same day, all of which are subject

to the same numerical emission limitation within

Section

218.204(k)

 (e.g., all coatings used on the line

are subject to 0.42 kg/l

3.5

 lbs/gal),

 and which

is

equipped with a capture system and control device

shall

operate the subject coating line unless the

requirements

subsection

(b)

(1)

or

 (b) (2)

 above are

met.

f)

 No owner

or operator of an existing diesel—electric

locomotive

coating

line

 Cook County which applies

one

coatings

during

the

same

day,

all

which

are subject to the same numerical emission limitation

within

Section

218.204(m)

(e.g.,

all

coatings

used

the line are subject to 0.42 kg/l

3.5

 lbs/gal),

and

which

equipped

with

capture

system

and

control

device shall operate the subject coating line unless

the requirements in subsection

 (b) (1)

or

 (b) (2)

are

met.

g)

 No owner or operator of a wood furniture coating line

which applies one or more coatings during the same day,

all

of which are

subject to the same numerical emission

limitation within Section 218.204(1)

 (e.g.,

all

coatings used on the line are subject to 0.67 kg/i

5.6

lbs/gal),

 and which is equipped with a capture

system

and control device shall operate the subject coating

line

unless

the

requirements

subsection

(b) (1)

(b) (2) are met.

 If compliance is achieved by meeting

the

requirements

subsection

(b) (2),

then

the

provisions in the note to Section 218.204(1)

 must also

be met.

h)

 No owner or operator of a can coating facility and

equipped with a capture system and control device shall

operate the subject coating facility unless the

requirements in subsection

 (h) (1) or

 (h) (2) below are

met.

1)

 An alternative daily emission limitation shall be

determined according to Section 218.205(c) (2).

Actual daily emissions shall never exceed the

alternative

daily

emission

limitation

and

shall

calculated by use of the following equation:

Ed

~

C1

 (1-Ft)

where:

119—317

82

Ed

 Actual VON emissions for the day in

units of kg/day

 (lbs/day),

i

 Subscript denoting the specific coating

applied,

n

 Total

number

of surface coatings as

applied in the can coating operation,

 Volume of each

coating

applied

for

the

day

units

1/day

(gal/day)

coating (minus water and any compounds

which

are specifically

exempted from the

definition of VON),

C1

 The VON content of each coating as

applied in units of kg VON/i

 (lbs

VON/gal)

 of coating (minus water and any

compounds which are specifically

exempted from the definition of

VON),

and

F~

 Fraction, by weight,

 of VON emissions

from the surface coating,

 reduced

or

prevented from being emitted to the

 ambient air. This is the overall

efficiency of the capture system and

control device.

2)

 The coating line is equipped with a capture system

and control device that provide 75 percent

reduction in

the

overall

 emissions of VON from the

coating line and the control device has a 90

percent efficiency.

Section 218.208

 Exemptions From Emission Limitations

a)

 Exemptions for all source categories except wood

furniture coating.

 The limitations of this Subpart

shall not apply to coating lines within a facility,

that otherwise would be subject to the same subsection

of Section 218.204

 (because they belong to the same

source category,

 e.g. can coating), provided that

combined actual emissions of VON from all lines at

the

facility subject to that subsection never exceed

6.8 kg/day

 (15 lbs/day) before the application of

capture systems and control devices.

 (For example, can

coating

lines

within

plant

would

 not be subject to

the limitations of Section 218.204(b)

 if the combined

actual emissions of VON from the can coating lines

never exceed 6.8 kg/day

 (15 lbs/day) before the

119—3 18

83

application of capture systems and control devices.)

 Volatile organic material emissions from heavy

off-highway vehicle products coating lines must be

combined with VON emissions from miscellaneous metal

parts and products coating lines to determine

applicability.

 Any owner or operator of a coating

facility shall comply with the applicable coating

analysis test methods and procedures specified in

Section 218.105(a) and the recordkeeping and reporting

requirements specified in Section 218.211(a)

 if total

VOM emissions from the subject coating lines are always

less than or equal to 6.8 kg/day

 (15 lbs/day) before

the application of capture systems and control devices

and, therefore, are not subject to the limitations of

Section 218.204.

 Once a category of coating lines at a

facility

 is subject to the limitations in Section

218.204, the coating lines are always subject to the

limitations

 in Section 218.204.

b)

 Applicability for wood furniture coating

1)

 The limitations of this Subpart shall apply to a

plant’s wood furniture coating lines

 if the plant

contains process emission sources, not regulated

by Subparts B,

E,

 F (excluding Section

218.204(1)), H

 (excluding Section 218.405),

Q,

R,

S,

V,

X,

1,

or

 Z of this Part,

 which as a group

both:

A)

 have maximum theoretical emissions of 91

Mg

(100 tons) or more per calendar year of VON

if no air pollution control equipment were

used,

and

B)

 are not limited to less than 91 Mg

 (100 tons)

of VON per calendar year if no

 air pollution

control equipment were used, through

production or capacity limitations contained

in a federally enforceable construction

permit or SIP revision.

2)

If

 a plant ceases to fulfill the criteria of

subsection

 (b) (1), the limitations of Section

218.204(1)

 shall continue to apply to any wood

furniture coating line which was ever subject to

the limitations of Section 218.204(1).

3)

 For the purposes of subsection

 (b), an emission

source shall be considered regulated by a Subpart

if it

 is subject to the limitations of that

Subpart.

 An emission source is not considered

regulated by a Subpart

 if its emissions are

below

119—319

84

the applicability cutoff level or if the source

is

covered by an exemption.

4)

 Any owner or operator of a wood furniture coating

line

which

the

limitations

this

Subpart

are

not applicable due to the criteria in subsection

(b)

 shall,

 upon request by the Agency or the

USEPA, submit records to the Agency and the USEPA

within 30 calendar days from the date of the

request

that

document

that

the

 coating line is

exempt from the limitations of this Subpart.

Section 218.209

 Exemption From General Rule on Use of Organic

Material

No owner or operator

coating

line

subject

the

limitations

of Section 218.204 is required to meet the limitations of

Subpart

(Section

218.301

218.302)

this

Part,

after

the

date by which the coating line

 is required to meet Section

218 .204.

Section 218.210

 Compliance Schedule

Every owner or operator of a coating

line

 (of a type included

within

Section 218.204)

 shall comply with the requirements of

Section 218.204,

218.207 or 218.208 and Section 218.211 in

accordance with the appropriate compliance schedule as specified

in subsection

 (a),

 (b),

(c)

or

 (d) below:

a)

 No owner or operator of a coating line which

 is exempt

from the limitations of Section 218.204 because of the

criteria

Section

218.208(a)

shall

operate

said

coating line on or after a date consistent with Section

218.106, unless the owner or operator has complied

with,

 and continues to comply with,

 Section 218.211(b).

Wood furniture coating lines are not subject to Section

218.211(b).

b)

 No owner or operator of a coating line complying by

means of Section 218.204 shall operate said coating

line on or after a date consistent with Section

218.106, unless the owner or operator has complied

with,

 and continues to comply with, Sections 218.204

and 218.211(c).

c)

 No owner or operator of a coating line complying by

means

 of Section 218.205 shall operate said coating

line on or after a date consistent with Section

218.106, unless the owner or operator has complied

with, and continues to comply with, Sections 218.205

and 218.211(d).

119—320

85

d)

 No owner or operator of a coating line complying by

means

Section

218.207

shall

operate

said

coating

line on or after a date consistent with Section

218.106, unless the owner or operator has complied

with,

 and continues to comply with,

 Sections 218.207

and

218.211(e).

Section 218.211

 Recordkeeping and Reporting

The

VON

content

each

coating

and

the

efficiency

of

each capture system and control device shall be

determined by the applicable test methods and

procedures specified

 in Section 218.105 to establish

the records required under this Section.

b)

 Any owner or operator of a coating line which

is

exempted from the limitations of Section 218.204

because of Section 218.208(a)

 shall comply with the

following:

date

consistent

with

Section

218.106,

the

owner or operator of a facility referenced in this

subsection

shall

certify

the

Agency

that

the

facility is exempt under the provisions of Section

218.208(a).

 Such certification shall

 include:

A)

 A declaration that the facility is exempt

from the limitations of Section 218.204

because

Section

218.208(a);

and

B)

 Calculations which demonstrate that the

combined VON emissions from all coating lines

at the facility never exceed 6.8 kg

 (15 lbs)

per day before the application of capture

systems

and

control

devices.

The

following

equation shall be used to calculate total VON

emissions:

~

 (A~B~)~

j=1

i=1

where:

Te

 =Total VON emissions from coating lines

at a facility each day before the

application of capture systems and

control devices in units of kg/day

(lbs/day),

m

 Number of coating lines at the

119—321

86

facility,

 Subscript denoting an individual

coating line,

n

 Number of different coatings as

applied each day on each coating

line at the facility,

i

 Subscript denoting an individual

coating,

 Weight of VON per volume of each coating

(minus water and any compounds which are

specifically exempted from the

definition of VON)

 as applied each day

on each coating line at the facility

in

units of kg VON/i

 (lbs VON/gal), and

B1

 Volume of each coating (minus water and

any compounds which are specifically

exempted from the definition of

VON)

as

applied each day on each coating line

at

the facility in units of 1/day

(gal/day).

 The instrument or method

by

which the owner or operator accurately

measured or calculated the volume of

each coating

applied

each

coating

line each day shall be described in the

certification to the Agency.

and

after

date

consistent

with

Section

218.106, the owner or operator of a facility

referenced in this subsection shall collect and

record

all

the

following

information

each

day

for each coating line and maintain the information

at the facility for a period of three years:

A)

 The name and identification number of each

coating as applied on each coating line.

B)

 The weight of VON per volume and the volume

of each coating (minus water and any

compounds which are specifically exempted

from the definition of VON)

 as applied each

day on each coating line.

3)

 On and after a date consistent with Section

218.106, the owner or operator of a facility

exempted from the limitations of Section 218.204

because of Section 218.208(a)

 shall notify the

119—322

87

Agency of any record showing that total VOM

emissions from the coating facility exceed 6.8 kg

(15 ibs)

 in any day before the application of

capture

systems

and

control

devices

sending

copy of such record to the Agency within

 30 days

after the exceedance occurs.

c)

 Any owner or operator of a coating line subject to the

limitations of Section 218.204 and complying by means

of Section 218.204 shall comply with the following:

1)

 By a date consistent with Section 218.106,

 or upon

initial

start—up

new

coating

line,

upon

changing the method of compliance from an existing

subject coating line from Section 218.205 or

Section 218.207 to Section 218.204; the owner or

operator of a subject coating line shall certify

to the Agency that the coating line will be in

compliance with Section 218.204 on and after

a

date consistent with Section 218.106,

 or on and

after the initial start-up date.

 Such

certification

shall

include:

A)

 The name and identification number of each

coating as applied on each coating line.

B)

 The weight of VOM per volume of each coating

(minus water and any compounds which are

specifically exempted from the definition of

VOM)

 as applied each day on each coating

line.

C)

 For coating lines subject to Section

218.2,04 (a) (3), certification shall include:

i)

 The name and identification number of

each coating line which will comply by

means of Section 218.204(a) (3),

ii)

 The name and identification number of

each coating as applied on each coating

line,

iii) The weight of VON per volume of each

coating as applied on each coating line,

iv)

 The instrument or method by which the

owner or operator will accurately

measure or calculate the volume of each

coating as applied each day on each

coating line,

119—323

88

v)

 The method by which the owner or

operator will create and maintain

records each day as required in

subsection

 (c) (2) below for coating

lines subject to Section 218.204(a) (3),

vi)

 An example format in which the records

required in subsection

 (c) (2)

 below for

coating lines subject to Section

218.204 (a) (3).

2)

 On and after a date consistent with Section

218.106,

 or on and after the initial start-up

date,

 the owner or operator of a coating line

subject to the limitations of Section 218.204 and

complying by means of Section 218.204 shall

 collect and record all of the following

information each day for each coating line and

maintain the information at the facility for a

period of three years:

A)

 The name and identification number of each

coating as applied on each coating line.

B)

 The weight of VON per volume of each coating

(minus water and any compounds which are

specifically exempted from the definition

of

VON)

 as applied each day on each coating

line.

C)

 For coating lines subject to Section

218.204(a) (3), the owner or operator shall

maintain all records necessary to calculate

the daily-weighted average VON content from

the coating line in accordance with the

proposal submitted,

 and approved by the

USEPA,

pursuant

Section

218.204(a)

(3).

3)

 On and after a date consistent with Section

218.106,

the

owner

operator

subject

coating

line

shall

notify

the

Agency

the

following instances:

A)

 Any record showing violation of Section

218.204 shall be reported by sending a copy

of such record to the Agency within 30 days

following the occurrence of the violation,

except that any record showing a violation of

Section 218.204(a) (3)

 shall be reported by

sending a copy of such record to the Agency

within

 15 days from the end of the month in

which the violation occurred.

119—324

89

B)

 At least 30 calendar days before changing the

method of compliance with Section 218.204

from Section 218.204 to Section 218.205 or

Section 218.207, the owner or operator shall

comply with all requirements of subsection

(d) (1)

or

 (e) (1) below, respectively.

 Upon

changing the method of compliance with

Section 218.204 from Section 218.204 to

Section 218.205 or Section 218.207, the owner

or operator shall comply with all

requirements of subsection

(d)

or

 (e),

respectively.

C)

 For coating lines subject to Section

218.204(a) (3), the owner or operator shall

notify the Agency of any change to the

topcoating operation at least 30 days before

the change is effected.

 The Agency shall

determine whether or not recertification

testing is required.

 If the Agency

determines that recertification testing is

required, then the owner or operator shall

submit a proposal to the Agency to test

within 30 days and retest within 30 days of

the Agency’s approval of the proposal.

d)

 Any owner or operator of a coating line subject to the

limitations of Section 218.204 and complying by means

of Section 218.205 shall comply with the following:

1)

 By a date consistent with Section 218.106,

 or upon

initial start—up of a new coating line,

 or upon

changing the method of compliance for an existing

subject coating line from Section 218.204 or

Section 218.207 to Section 218.205; the owner or

operator of the subject coating line shall certify

to the Agency that the coating line will be

in

compliance with Section 218.205 on and after a

date consistent with Section 218.106, or on and

after the initial start-up date.

 Such

certification shall include:

A)

 The name and identification number of each

coating line which will comply by means of

Section 218.205.

B)

 The name and identification number of each

coating as applied on each coating line.

C)

 The weight of VON per volume and the volume

each

coating

(minus

 water and any

119—325

90

compounds which are specifically exempted

from the definition of VON)

 as applied each

day on each coating line.

D)

 The instrument or method by which the owner

operator

will

accurately

measure

calculate the volume of each coating as

applied each day on each coating line.

E)

 The method by which the owner or operator

will create and maintain records each day as

required in subsection

 (d) (2).

F)

 An example of the format in which the records

required in subsection

 (d) (2) will be kept.

2)

 On and after a date consistent with Section

218.106,

 or on and after the initial start—up

date,

 the owner or operator of a coating line

subject to the limitations of Section 218.204 and

complying by means of Section 218.205,

 shall

collect and record all of the following

information each day for each coating line and

maintain the information at the facility for a

period of three years:

A)

 The name and identification number of each

coating

applied

each

coating

line.

B)

 The weight of VON per volume and the volume

of each coating (minus water and any

compounds which are specifically exempted

from the definition of VON)

 as applied each

day on each coating line.

C)

 The daily-weighted average VON content of all

coatings as applied on each coating line as

defined

Section

218.104.

3)

 On and after a date consistent with Section

218.106, the owner or operator of a subject

coating line shall notify the Agency in the

following instances:

A)

 Any record showing violation of Section

218.205 shall be reported by sending a copy

of such record to the Agency within 30 days

following the occurrence of the violation.

B)

 At least 30 calendar days before changing the

method of compliance with this subpart from

Section

218.205

Section

218.204

Section

119—326

91

218.207, the owner or operator shall comply

with all requirements of subsection

 (c) (1) or

(e) (1), respectively.

 Upon changing the

method of compliance with this subpart from

Section 218.205 to Section 218.204 or Section

218.207, the owner or operator shall comply

with all requirements of subsection

(c)

or

(e), respectively.

e)

 Any owner or operator of a coating line subject to the

limitations of Section 218.207 and complying by means

of Section 218.207(c),

 (d),

 (e),

 (f),

(g)

or

(h)

 shall

comply with the following:

1)

 By a date consistent with Section 218.106,

 or upon

initial start—up of a new coating line,

 or upon

changing the method of compliance for an existing

coating line from Section 218.204 or Section

218.205 to Section 218.207, the owner or operator

of the subject coating line shall perform all

 tests and submit to the Agency the results of all

tests and calculations necessary to demonstrate

that the subject coating line will be in

compliance with Section 218.207 on and after a

date consistent with Section 218.106,

 or on and

after the initial start-up date.

2)

 On and after a date consistent with Section

218.106,

 or on and after the initial start-up

date,

 the owner or operator of a coating line

subject to the limitations of Section 218.207 and

complying

means

Section

218.207(c),

(d),

(e),

 (f),

 (g), or

(h)

 shall collect and record all

of the following information each day for each

coating line and maintain the information at the

facility for a period of three years:

A)

 The weight of VON per volume of coating

solids as applied each day on each coating

line,

 if complying pursuant to Section

218.207(b) (2).

B)

 Control device monitoring data.

C)

 A log of operating time for the capture

system,

 control device, monitoring equipment

and the associated coating line.

maintenance

log

for

the

capture

system,

control device and monitoring equipment

detailing all routine and non—routine

maintenance performed including dates and

119—327

92

duration of any outages.

3)

 On and after a date consistent with Section

218.106, the owner or operator of a subject

coating line shall notify the Agency in the

following instances:

A)

 Any record showing violation of Section

218.207 shall be reported by sending a copy

of such record to the Agency within 30 days

following the occurrence of the violation.

B)

 At least 30 calendar days before changing the

method of compliance with this Subpart from

Section 218.207 to Section 218.204 or Section

218.205, the owner

 or operator shall comply

with all requirements of subsection

 (c) (1)

or

(d) (I)

 of this Section, respectively.

 Upon

changing the method of compliance with this

subpart from Section 218.207 to Section

218.204 or Section 218.205, the owner or

operator shall comply with all requirements

of subsection

(c)

or

(d)

 of this Section,

respectively.

SUBPART

G:

 USE OF ORGANIC MATERIAL

Section 218.301

 Use of Organic Naterial

No person shall

cause or allow the discharge of more than 3.6

kg/hr

 (8 lbs/hr)

 of organic material into the atmosphere from any

emission source,

 except as provided in Sections 218.302,

 218.303,

218.304 and the following exception:

 If no odor nuisance exists

the limitation of this Subpart shall apply only to

photochemically reactive material.

Section 218.302

 Alternative Standard

Emissions of organic material in excess of those permitted by

Section 218.301 are allowable if such emissions are controlled by

one of the following methods:

a)

 Flame, thermal or catalytic incineration so as either

to reduce such emissions to 10 ppm equivalent methane

(molecular weight

 16) or less,

 or to convert 85 percent

of the hydrocarbons to carbon dioxide and water; or,

b)

 A vapor recovery system which adsorbs and/or condenses

at least 85 percent of the total uncontrolled organic

material that would otherwise be emitted to the

atmosphere;

or,

119—328

93

c)

 Any other air pollution control equipment approved by

the Agency and approved by the USEPA as a SIP revision

capable of reducing by 85 percent or more the

uncontrolled organic material that would be otherwise

emitted to the atmosphere.

Section 218.303

 Fuel Combustion Emission Sources

The provisions of Sections 218.301 and 218.302 shall not apply to

fuel combustion emission sources.

Section 218.304

 Operations with Compliance Program

The provisions of Sections 218.301 and 218.302 shall not apply

to

any owner,

 operator, user or manufacturer of paint, varnish,

lacquer, coatings or printing ink whose compliance program and

project completion schedule, as required by 35 Ill.

 Adm. Code

201, provided for the reduction of organic material used in such

process to 20 percent or less of total volume by Nay 30,

 1977.

SUBPART H:

 PRINTING

AND

PUBLISHING

Section 218.401

 Flexographic and Rotogravure Printing

a)

 No owner or operator of a subject flexographic,

packaging rotogravure or publication rotogravure

printing line shall apply at any time any coating or

ink unless the VON content does not exceed the

limitation specified in either subsection

 (a) (1)

or

(a) (2)

 below.

 Compliance with this Section must be

demonstrated through the applicable coating or ink

analysis test methods and procedures specified in

Section 218.105(a)

 and the recordkeeping and reporting

requirements specified in Section 218.404(c).

 As an

alternative to compliance with this subsection,

a

subject printing line may meet the requirements of

subsection

 (b) or

(c)

 below.

1)

 Forty percent VON by volume of the coating and ink

(minus water and any compounds which are

specifically exempted from the definition of VON),

or

2)

 Twenty-five percent VON by volume of the volatile

 content in the coating and ink.

b)

No

owner or operator of a subject flexographic,

packaging rotogravure or publication rotogravure

printing line shall apply coatings or inks on the

subject printing line unless the weighted average, by

volume, VON content of all coatings and inks as applied

each day on the subject printing line does not exceed

119—329

94

the limitation specified in either subsection

 (a) (1)

(as determined by subsection

 (b) (1)

 or subsection

(a) (1))

 (as determined by subsection

 (b) (2).

Compliance with this subsection must be demonstrated

through the applicable coating or ink analysis test

methods and procedures specified in Section 218.105(a)

and the recordkeeping and reporting requirements

specified in Section 218.404(d).

1)

 The following equation shall be used to determine

the

weighted

average

VON

content

all

coatings and inks as applied each day on the

subject printing line exceeds the limitation

specified in subsection

 (a) (1).

S

 C~L~(V~~

+

 VV0M.)

i=i

VON.

________________

(i)(A)

 L~(V~~

+

 VVOMj)

i=i

Where:

VON(I)(A)

 The weighted average VON content in

units of percent VOM by volume of

all coatings and inks (minus water

and any compounds which are

specifically exempted from the

definition of VON) used each day,

i

 Subscript denoting a specific

coating or ink as applied,

The number of different coatings

and/or inks as applied each day on

a printing line,

C1

 The VON content in units of percent

VON by volume of each coating or

ink as applied (minus water and any

compounds which are specifically

exempted from the definition of

VON),

L1

 The liquid volume of each coating

or ink as applied in units of

1

(gal),

~

 The volume fraction of solids in

119—330

95

each coating or ink as applied,

and

VVOMI

 The volume fraction of VOM in each

coating or ink as applied.

2)

 The following equation shall be used to determine

if the weighted average VON content of all

coatings and inks as applied each day on the

subject printing line exceeds the limitation

specified in subsection

 (a) (2).

 C~L~V~1

(i)(B)

—

L~V~1

where:

VOM(i)(B)

 The weighted average VON content in

units of percent VON by volume of

the volatile content of all

coatings and inks used each day,

i

 Subscript denoting a specific

coating or ink as applied,

The number of different coatings

and/or inks as applied each day on

each printing line,

C1

 The VON content

 in units of percent

VOM by volume of the volatile

matter in each coating or ink as

applied,

L~

 The liquid volume of each coating

or ink as applied in units of

1

(gal), and

 The volume fraction of volatile

matter in each coating or ink as

applied.

c)

 No owner or operator of a subject flexographic,

packaging rotogravure or publication rotogravure

printing line equipped with a capture system and

control device shall operate the subject printing line

unless the owner or operator meets the requirements in

subsection

 (c) (1),

 (c) (2), or

 (c) (3) and subsections

119—33 1

96

(c)(4),

 (c)(5)

and

 (c)(6) below.

1)

 A carbon adsorption system is used which reduces

the captured VON emissions by at least 90 percent

by weight,

or

2)

 An incineration system is used which reduces the

captured VON emissions by at least 90 percent by

weight,

or

3)

 An alternative VON emission reduction system is

used which is demonstrated to have at least

a

90 percent control device efficiency, approved by

the Agency and approved by USEPA as a SIP

revision, and

4)

 The printing line is equipped with a capture

system and control device that provides an overall

reduction in VON emissions of at least:

A)

 75 percent where a publication rotogravure

printing line is employed, or

B)

 65 percent where a packaging rotogravure

printing line is employed,

or

C)

 60 percent where a flexographic printing line

is employed, and

4)

 The control device is equipped with the applicable

monitoring equipment specified in Section

218.105(d) (2) and the monitoring equipment is

installed,

 calibrated, operated and maintained

according to vendor specifications at all times

the control device is in use, and

5)

 The capture system and control device are operated

at all times when the subject printing line is

in

operation.

 The owner or operator shall

demonstrate compliance with this subsection by

 using the applicable capture system and control

device test methods and procedures specified in

Section 218.105(c) through Section 218.105(f)

and

by complying with the recordkeeping and reporting

requirements specified in Section 218.404(e).

Section 218.402

 Applicability

a)

 The limitations of Section 218.401 apply to all

flexographic and rotogravure printing lines at a

subject facility.

 All facilities with flexographic

and/or rotogravure printing lines are subject

119—33 2

97

facilities unless:

1)

 Total maximum theoretical emissions of VON from

all flexographic and rotogravure printing line(s)

at the facility never exceed 90.7 Mg

 (100 tons)

per calendar year before the application of

capture systems and control devices, or

2)

 A federally enforceable construction permit or SIP

revision for all flexographic and rotogravure

printing line(s)

 at a facility requires the owner

or operator to limit production or capacity of

these printing line(s)

 to reduce total VON

emissions from all flexographic and rotogravure

printing line(s) to 90.7 Mg (100 tons)

 or less per

calendar year before the application of capture

systems and control devices.

b)

 Upon achieving compliance with this Subpart, the

emission source is not required to meet Subpart G

(Sections 218.301 or 218.302)..

 Emission sources exempt

from this Subpart are subject to Subpart G (Sections

218.301 or 215.802).

 Rotogravure or flexographic

equipment used for both roll printing and paper coating

is subject to this Subpart.

c)

 Once subject to the limitations of Section 218.401,

a

flexographic or rotogravure printing line

 is always

subject to the limitations of Section 218.401.

d)

 Any owner or operator of any flexographic or

rotogravure printing line that is exempt from the

limitations of Section 218.401 because of the criteria

in this Section is subject to the recordkeeping and

reporting requirements specified in Section 218.404(b).

Section 218.403

 Compliance Schedule

Every owner or operator of a flexographic and/or rotogravure

printing line shall comply with the applicable requirements of

Section 218.401 and Section 218.404

 in accordance with the

applicable compliance schedule specified in subsection

 (a),

 (b),

(c)

or

(d)

 below:

a)

 No owner or operator of a flexographic or rotogravure

printing line which

 is exempt from the limitations of

Section 218.401 because of the criteria in Section

218.402 shall operate said printing line on or after a

date consistent with Section 218.106, unless the owner

or operator has complied with, and continues to

comply

with,

 Section 218.404(b).

119—333

98

b)

 No owner or operator of a flexographic or rotogravure

printing line complying by means of Section 218.401(a)

shall operate said printing line on or after

 a date

consistent with Section 218.106, unless the owner or

operator has complied with,

 and continues to comply

with,

 Section 218.401(a)

 and Section 218.404(c).

c)

 No owner or operator of a flexographic or rotogravure

printing line complying by means of Section 218.401(b)

shall operate said printing line on or after a date

consistent with Section 218.106, unless the owner or

operator has complied with,

 and continues to comply

with,

 Section 218.401(b)

 and Section 218.404(d).

d)

 No owner or operator of a flexographic or rotogravure

printing line complying by means of Section 218.401(c)

shall operate said printing line on or after a date

consistent with Section 218.106, unless the owner or

operator has complied with,

 and continues to comply

with,

 Section 218.401(c)

 and Section 218.404(e).

Section 218.404

 Recordkeeping and Reporting

a)

 The VON content of each coating and ink and the

efficiency of eachcapture system and control device

shall be determined by the applicable test methods and

procedures specified in Section 218.105 to establish

 the records required under this Section.

b)

 Any owner or operator of a printing line which

is

exempted from the limitations of Section 218.401

because of the criteria in Section 218.402 shall comply

with the following:

1)

 By a date consistent with Section 218.106,

the

owner or operator of a facility to which this

subsection is applicable shall certify to the

Agency that the facility is exempt under the

provisions of Section 218.402.

 Such certification

shall include:

A)

 A declaration that the facility is exempt

from the limitations of the criteria in

Section 218.401 because of Section 218.402,

and

B)

 Calculations which demonstrate that total

maximum theoretical emissions of VON from all

flexographic and rotogravure printing lines

at the facility never exceed 90.7 Mg

(100 tons)

 per calendar year before the

application of capture systems and control

119—334

99

devices.

 Total maximum theoretical emissions

of VOM for a flexographic or rotogravure

printing facility is the sum of maximum

theoretical emissions of VON from each

flexographic and rotogravure printing line at

the facility.

 The following equation shall

be used to calculate total maximum

theoretical emissions of VON per calendar

year before the application of capture

 systems and control devices for each

flexographic and rotogravure printing line

the facility:

E~

 A x B

where:

 Total maximum theoretical emissions of

VON from one flexographic or rotogravure

printing line in units

 of kg/year

(lbs/year),

A

 Weight of VON per volume of solids of

the coating or ink with the highest

VON

content as applied each year on the

printing line in units of kg VOM/l

 (lbs

VON/gal)

 of coating or ink solids,

and

B

 Total volume of solids for all coatings

and inks that can potentially be applied

each year on the printing line in units

of 1/year

 (gal/year).

 The instrument

and/or method by which the owner or

operator accurately measured or

calculated the volume of each coating

and ink as applied and the amount that

can potentially be applied each year on

the printing line shall be described in

the certification to the Agency.

2)

 On and after a date consistent with Section

218.106, the owner or operator of a facility

referenced in this subsection shall collect and

record all of the following information each year

for each printing line and maintain the

information at the facility for

 a period of three

years:

A)

 The name and identification number of each

coating and ink as applied on each printing

119—335

100

line.

B)

 The VOM content and the volume of each

coating and ink as applied each year on each

printing line.

3)

 On and after a date consistent with Section

218.106, the owner or operator of a facility

exempted from the limitations of Section 218.401

because of the criteria in Section 218.402 shall

notify the Agency of any record showing that total

maximum theoretical emissions of VOM from all

printing lines exceed 90.7 Mg

 (100 tons)

 in any

calendar year before the application of capture

systems and control devices by sending a copy of

such record to the Agency within 30 days after

the

exceedance occurs.

c)

 Any owner or operator of a printing line subject to

the

limitations of Section 218.401 and complying by means

of Section 218.401(a)

 shall comply with the following:

1)

 By a date consistent with Section 218.106, or upon

initial start-up of a new printing line,

 or upon

changing the method of compliance from an existing

subject printing line from Section 218.401(b)

or

Section 218.401(c)

 to Section 218.401(a), the

owner or operator of a subject printing line shall

certify to the Agency that the printing line will

 be in compliance with Section 218.401(a)

 on and

after a date consistent with Section 218.106,

or

on and after the initial start-up date.

 Such

certification shall include:

A)

 The name and identification number of each

coating and ink as applied on each printing

line.

B)

 The VON content of each coating and ink as

applied each day on each printing line.

2)

 On and after a date consistent with Section

218.106, or on and after the initial start-up

date,

 the owner or operator of a printing line

subject to the limitations of Section 218.401 and

complying by means of Section 218.401(a)

 shall

collect and record all of the following

information each day for each coating line and

maintain the information at the facility for

a

period of three years:

A)

 The name and identification number of each

119—336

101

coating and ink as applied on each printing

line.

B)

 The VON content of each coating and ink as

applied each day on each printing line.

3)

 On and after a date consistent with Section

218.106,

 the owner or operator of a subject

printing line shall notify the Agency in the

following instances:

A)

 Any record showing violation of Section

218.401(a)

 shall be reported by sending a

copy of such record to the Agency within 30

days following the occurrence of the

violation.

B)

 At least 30 calendar days before changing the

method of compliance with Section 218.401

from Section 218.401(a)

 to Section 218.401(b)

or

 (c), the owner or operator shall comply

with

all requirements of subsection

 (b) (1)

or

(c) (1),

respectively.

 Upon changing the

method of compliance with Section 218.401

from Section 218.401(a)

 to Section 218.401(b)

or

 (c), the owner or operator shall comply

with all requirements of subsection

(b)

or

(c), respectively.

d)

 Any owner or operator of a printing line subject to the

limitations of Section 218.401 and complying by means

of Section 218.401(b)

 shall comply with the following:

1)

 By a date consistent with Section 218.106,

 or upon

initial start-up of a new printing line,

 or upon

changing the method of compliance for an existing

subject printing line from Section 218.401(a)

or

(c) to Section 218.401(b),

 the owner or operator

of the subject printing line shall certify to the

Agency that the printing line will be in

compliance with Section 218.401(b)

 on and after a

date consistent with Section 218.106, or on and

after the initial start-up date.

 Such

certification shall include:

A)

 The name and identification number of each

printing line which will comply by means of

Section 218.401(b).

B)

 The name and identification number of each

coating and ink available for use on each

printing line.

119—337

102

C)

 The VON content of each coating and ink as

applied each day on each printing line.

D)

 The instrument or method by which the owner

or operator will accurately measure or

calculate the volume of each coating and ink

as applied each day on each printing line.

E)

 The method by which the owner or operator

will create and maintain records each day as

required in subsection

 (b) (2).

F)

 An example of the format in which the records

required in subsection

 (b) (2) will be kept.

2)

 On and after a date consistent with Section

218.106,

 or on and after the initial start-up

date, the owner or operator of a printing line

subject to the limitations of Section 218.401 and

complying by means of Section 218.401(b)

 shall

collect and record all of the following

information each day for each printing line and

maintain the information at the facility for a

period of three years:

A)

 The name and identification number of each

coating and ink as applied on each printing

line.

B)

 The VON content and the volume of each

coating and ink as applied each day on each

printing line.

C)

 The daily-weighted average VON content of

all

coatings and inks as applied on each printing

line.

3)

 On and after a date consistent with Section

218.106, the owner or operator of a subject

printing line shall notify the Agency in the

following instances:

A)

 Any record showing violation of Section

218.401(b)

 shall be reported by sending a

copy of such record to the Agency within 30

days following the occurrence of the

violation.

B)

 At least 30 calendar days before changing the

method of compliance with Section 218.401

from Section 218.401(b)

 to Section 218.401(a)

119—338

103

or 218.401(c), the owner or operator shall

comply with all requirements of subsection

(c)(1) or (e)(1), respectively.

 Upon

changing the method of compliance with

Section 218.401 from Section 218.401(b)

to

Section 218.401(a) or

 (c), the owner or

operator shall comply with all requirements

of subsection

(c)

or

 (e), respectively.

e)

 Any owner or operator of a printing line subject to the

limitations of Section 218.401 and complying by means

of Section 218.401(c)

 shall comply with the following:

1)

By

 a date consistent with Section 218.106,

 or upon

initial start-up of a new printing line,

 or upon

changing the method of compliance for an existing

printing line from Section 218.401(a)

or

 (b) to

Section 218.401(c), the owner or operator of the

subject printing line shall perform all tests and

submit to the Agency the results of all tests and

calculations necessary to demonstrate that the

subject printing line will be in compliance with

Section 218.401(c) on and, after a date consistent

with Section 218.106,

 or on and after the initial

start—up date.

2)

 On and after

 a date consistent with Section

218.106, or on and after the initial start—up

date, the owner or operator of a printing line

subject to the limitations of Section 218.401 and

complying by means of Section 218.401(c)

 shall

collect and record all of the following

information each day for each printing line and

maintain the information at the facility for a

period of three years:

A)

 Control device monitoring data.

B)

 A log of operating time for the capture

system, control device, monitoring equipment

and the associated printing line.

C)

 A maintenance log for the capture system,

control device and monitoring equipment

detailing all routine and non—routine

maintenance performed including dates and

 duration of any outages.

3)

 On and after a date consistent with Section

218.106,

 the owner or operator of a subject

printing line shall notify the Agency in the

following instances:

119—339

104

A)

 Any record showing violation of Section

218.401(c),

 shall be reported by sending a

copy of such record to the Agency within 30

days following the occurrence of the

violation.

B)

 At least 30 calendar days before changing the

method of compliance with Section 218.401

from Section 218.401(c)

 to Section 218.401(a)

or

 (b), the owner or operator shall comply

with all requirements of subsection

 (c) (1)

or

(d)(l), respectively.

 Upon changing the

method of compliance with Section 218.401

from Section 218.401(c)

 to Section 218.401(a)

or

 (b), the owner or operator shall comply

with all requirements of subsection

(c)

or

(d), respectively.

Section 218.405

 Heatset-Web-Offset Lithographic Printing

a)

 Applicability

1)

 The limitations of subsection

 (b) below apply to

all heatset-web-offset lithographic printing lines

at a subject facility.

 All facilities with

heatset-web-offset lithographic printing lines are

subject facilities unless:

A)

 Total maximum theoretical emissions of VON

from all heatset-web-offset lithographic

printing lines at the facility never exceed

90.7 Mg

 (100 tons)

 per calendar year in the

absence of air pollution control equipment,

or

B)

 A federally enforceable construction permit

or SIP revision for all heatset-web-offset

lithographic printing lines(s) at a facility

requires the owner or operator to limit

production or capacity of these printing

line(s) to reduce total VON emissions from

all heatset-web-offset lithographic printing

line(s) to 90.7 Mg

 (100 tons)

 per calendar

year or less in the absence of air pollution

control equipment,

and

2)

 Any owner or operator of any heatset—web—offset

lithographic printing line that is exempt from the

limitations in subsection

 (b) because of the

criteria in subsection

 (a) (1)

 shall be subject to

the recordkeeping and reporting requirements in

119—340

105

subsection

 (c) (1).

b)

 Specific Provisions.

 No owner or operator of a subject

heatset—web— offset printing line may cause or allow

the operation of the subject heatset-web-offset

printing line unless the owner or operator meets the

requirements in subsection

 (b) (1)

or

 (b) (2)

 and the

requirements in subsections

 (b) (3) and

 (b) (4)

 below.

1)

 An afterburner system is installed and operated

that reduces 90 percent of the VON emissions from

the dryer exhaust, or

2)

 The fountain solution contains no more than

8 percent,

 by weight,

 of VON and a condensation

recovery system is installed and operated that

removes at least 75 percent of the non—isopropyl

alcohol organic materials from the dryer exhaust,

and

3)

 The control device

 is equipped with the applicable

monitoring equipment specified in Section

218.105(d) (2) and the monitoring equipment is

installed,

 calibrated, operated and maintained

according to vendor specifications at all times

the control device is in use, and

4)

 The control device is operated at all times when

the subject printing line is in operation.

The

owner or operator shall demonstrate compliance

with this Section by using the applicable test

methods and procedures specified in Section

218.105(a),

 (d), and

 (f) and by complying with the

recordkeeping and reporting requirements specified

in subsection

 (c) below.

c)

 Recordkeeping and Reporting.

 The VON content of each

fountain solution and ink and the efficiency of each

control device shall be determined by the applicable

test methods and procedures specified in Section

 218.105 to establish the records required under this

subsection.

1)

 Any owner or operator of a printing line which is

exempted from the limitations of subsection

(b)

because of the criteria in subsection

(a)

 shall

comply with the following:

A)

 By a date consistent with Section 218.106,

the owner or operator of a facility to which

subsection

 (c) (1)

 is applicable shall certify

to the Agency that the facility is exempt

119—34 1

106

under the provisions of subsection

 (a).

 Such

certification shall include:

i)

 A declaration that the facility is

exempt from the limitations of

subsection

(b)

 because of the criteria

in subsection

 (a), and

ii)

 Calculations which demonstrate that

total maximum theoretical emissions of

VON from all heatset-web-offset

lithographic printing lines at the

facility never exceed 90.7 Mg (100 tons)

per calendar year before the application

of air pollution control equipment.

Total maximum theoretical emissions of

VON for a heatset-web-offset

lithographic printing facility is the

sum of maximum theoretical emissions of

VOM from each heatset-web-offset

lithographic printing line at the

facility.

 The following equation shall

 be used to calculate total maximum

theoretical emissions of VON per

calendar year in the absence of air

pollution control equipment for each

heatset-web-offset lithographic printing

line at the facility.

E

 (A x B)

+

 (C x D)

p

100

where:

 Total maximum theoretical emissions

of VON from one heatset—web—offset

printing line in units of kg/year

(lbs/year),

A

 Weight of VON per volume of solids

of ink with the highest VON content

as applied each year on the

printing line in units of kg VON/i

(lbs VON/gal)

 of solids, and

B

 Total volume of solids for all inks

that can potentially be applied

each year on the printing line in

units of 1/year (gal/year).

The

instrument or method by which the

owner or operator accurately

119—342

107

measured or calculated the volume

of each ink as applied and the

amount that can potentially be

applied each year on the printing

line shall be described in the

certification to the Agency.

C

 The weight percent VON of the

fountain solution with the highest

VON content.

D

 The total volume of fountain

solution that can potentially be

used each year on the printing line

in units of 1/year

 (gal/year).

The

instrument and/or method by which

the owner or operator accurately

measured or calculated the volume

of each fountain solution used and

the amount that can potentially be

used each year on the printing line

shall be described in the

certification to the Agency.

B)

 On and after a date consistent with Section

218.106, the owner or operator of a facility

to which subsection

 (c) (1)

 is applicable

shall collect and record all of the following

information each year for each printing line

and maintain the information at the facility

for a period of three years:

i)

 The name and identification of each

fountain solution and ink as applied on

each printing line.

ii)

 The VON content and the volume of each

fountain solution and ink as applied

each year on each printing line.

C)

 On and after a date consistent with Section

218.106, the owner or operator of a facility

exempted from the limitations of subsection

(b) because of the criteria in subsection

(a)

shall notify the Agency of any record showing

that total maximum theoretical emissions of

VON from all printing lines exceed 90.7 Mg

(100 tons)

 in any calendar year in the

absence of air pollution control equipment by

sending a copy of such record to the Agency

within 30 days after the exceedance occurs.

119—343

108

2)

 Any owner or operator of a printing line subject

to the limitations of subsection

 (b) and complying

by means of subsection

 (b) (1)

 shall comply with

the following:

A)

 By a date consistent with Section 218.106,

or

upon initial start-up of a new printing line,

or upon changing the method of compliance for

an existing printing line from subsection

(b) (2) to subsection

 (b) (1); the owner or

operator of the subject printing line shall

perform all tests and submit to the Agency

the results of all tests and calculations

necessary to demonstrate that the subject

printing line will be in compliance with

subsection

 (b) (1) on and after a date

consistent with Section 218.106,

 or on and

after the initial start-up date.

B)

 On and after

 a date consistent with Section

218.106, or on and after the initial start-up

date,

 the owner or operator of a printing

line subject to the limitations of subsection

(b) and complying by means of subsection

(b) (1)

 shall collect and record the following

information each day for each printing line

and maintain the information at the facility

 for a period of three years:

i)

 Control device monitoring data.

ii)

 A log of operating time

 for the control

device, monitoring equipment and the

associated printing line.

iii) A maintenance log for the control device

and monitoring equipment detailing all

routine and nonroutine maintenance

performed including dates and duration

of any outages.

C)

 On and after

 a date consistent with Section

218.106, the owner or operator of a subject

printing line shall notify the Agency in the

following instances:

i)

 Any record showing violation of

subsection

 (b) (1) shall be reported by

sending a copy of such record to the

Agency within 30 days following the

occurrence of the violation.

119—344

109

ii)

 At least 30 calendar days before

changing the method of compliance with

subsection

 (b) from subsection

 (b) (1)

to

(b) (2), the owner or operator shall

comply with all requirements of

subsection

 (c) (3) (A).

 Upon changing the

method of compliance with subsection

(b)

from subsection

 (b) (1) to

 (b) (2), the

owner or operator shall comply with all

requirements of subsection

 (c) (3).

3)

 Any owner or operator of a printing line subject

 to the limitations of subsection

(b)

 and complying

by means of subsection

 (b) (2)

 shall comply with

the following:

A)

 By a date consistent with Section 218.106,

or

upon initial start-up of a new printing line,

or upon changing the method of compliance for

an existing printing line from subsection

(b)(1)

 to (b)(2); the owner or operator of

the subject printing line shall perform

all

tests and submit to the Agency and the USEPA

the results of all tests and calculations

necessary to demonstrate that the subject

printing line will be in compliance with

subsection

 (b) (2)

 on and after a date

consistent with Section 218.106,

 or on and

after the initial start-up date.

B)

 On and after a date consistent with Section

218.106, or on and after the initial start-up

date,

 the owner or operator of a printing

line subject to the limitations of subsection

(b)

 and complying by means of subsection

(b) (2)

 shall collect and record the following

information each day for each printing line

and maintain the information at the facility

for a period of three years:

i)

 The VON content of the fountain solution

used each day on each printing line.

ii)

 A log of operating time for the control

device and the associated printing line.

iii) A maintenance log for the control device

 detailing all routine and non—routine

maintenance performed including dates

and duration of any outages.

C)

 On and after a date consistent with Section

119—345

110

218.106, the owner or operator of a subject

printing line shall notify the Agency

 in the

following instances:

i)

 Any record showing violation of

subsection

 (b) (2)

 shall be.reported by

sending a copy of such record to the

Agency within 30 days following the

occurrence of the violation.

ii)

 At least 30 calendar days before

changing the method of compliance

with

subsection

 (b) from subsection

 (b) (2)

to

(b) (1), the owner or operator shall

comply with all requirements of

subsection

 (c) (2) (A).

 Upon changing

the

method of compliance with subsection

(b)

from subsection

 (b) (2) to

 (b) (1), the

owner or operator shall comply with all

requirements of subsection

 (c) (2).

d)

 Compliance Schedule.

 Every owner or operator of a

heatset-web-offset lithographic printing line shall

comply with the applicable requirements of subsections

(b) and

(c)

 in accordance with the applicable

compliance schedule specified in subsection

 (d) (1),

 (d)(2), or

 (d)(3) below:

1)

 No owner or operator of

 a heatset—web—offset

lithographic printing line which is exempt from

the limitations of subsection

 (b) because of the

criteria in subsection

(a)

 shall operate said

printing line on or after a date consistent with

Section 218.106, unless the owner or operator has

complied with, and continues to comply with,

subsection

 (b) (1) and

(C)

(1).

2)

 No owner or operator of

 a heatset—web—offset

lithographic printing line complying by means of

subsection

 (b) (1)

 shall operate said printing line

on or after a date consistent with Section

218.106, unless the owner or operator has complied

with,

 and continues to comply with,

 subsection

(b) (2) and

 (c) (2)

3)

 No owner or operator of a heatset—web—offset

lithographic printing line complying by means of

subsection

 (b) (2) shall operate said printing line

on or after a date consistent with Section

218.106, unless the owner or operator has complied

with, and continues to comply with,

 subsection

(c) (3)

119—346

111

SUBPART Q:

 LEAKS FROM SYNTHETIC ORGANIC CHEMICAL

AND

POLYMER MANUFACTURING EQUIPMENT

Section 218.421

 General Requirements

The owner or operator of

 a plant which processes more than 3660

mg/yr

 (4033 tons/year) gaseous and light liquid VON, and whose

components are used to manufacture the synthetic organic

chemicals or polymers listed in Appendix A,

 shall comply with

this Subpart.

 The provisions of this Subpart are applicableto

components containing 10 percent or more by weight VON as

determined by ASTN method E-168,

 E-169 and E-260,

 incorporated by

reference in Section 218.112.

 Those components that are not

process unit components are exempt from this Subpart.

A

component shall be considered to be leaking if the VON is equal

to, or

 is greater than 10,000 ppmv

as methane or hexane as

determined by USEPA Reference Method

 21, as specified at 40 CFR

60, Appendix A,

 incorporated by reference

 in Section 218.112,

indication of liquids dripping, or indication by a sensor that

a

seal or barrier fluid system

has failed.

 The provisions of this

Subpart are not applicable

 if the equipment components are used

to produce heavy liquid chemicals only from heavy liquid feed or

raw materials.

Section 218.422

 Inspection Program Plan for Leaks

The owner or operator of a synthetic organic chemical or polymer

manufacturing plant subject to Section 218.421 shall prepare an

inspection program plan which contains, at a minimum:

a)

 An identification of all components and the period in

which each will be monitored pursuant to Section

218.423.

b)

 The format for the monitoring log required by Section

218.425.

c)

 A description of the monitoring equipment to be used

when complying with Section 218.423, and

d)

 A description of the methods to be used to identify all

pipeline valves, pressure relief valves in gaseous

service, all leaking components, and components

exempted under Section 218.423(i)

 such that they are

obvious and can be located by both plant personnel

performing monitoring and Agency personnel performing

inspections.

section 218.423

 Inspection Program for Leaks

The owner or operator of a synthetic organic chemical or

polymer

119—347

112

manufacturing plant subject to this subpart shall,

 for the

purposes of detecting leaks, conduct a component inspection

program using the test methods specified in Method 21,

 40 CFR 60,

Appendix A

 (1986), incorporated by reference in Section 218.112,

consistent with the following provisions:

a)

 Test annually those components operated near extreme

temperature or pressure such that they would be unsafe

to routinely monitor and those components which would

require the elevation of monitoring personnel higher

than two meters above permanent worker access

 structures or surfaces.

b)

 Test quarterly all other pressure relief valves in gas

service, pumps

 in light liquid service, valves in light

liquid service and in gas service, and compressors.

c)

 If less than or equal to 2 percent of the valves in

light liquid service and in gas service tested pursuant

to subsection

 (b) are found not to leak for

five consecutive quarters, no leak tests shall be

required for three consecutive quarters.

 Thereafter,

leak tests shall resume for the next quarter.

 If that

test shows less than or equal to

 2 percent of the

valves in light liquid service and in gas service are

leaking, then no tests are required for the next

three quarters.

 If more than

 2 percent are leaking,

then tests are required for the next five quarters.

d)

 Observe visually all pump seals weekly.

e)

 Test immediately any pump seal from which liquids are

observed dripping.

f)

 Test any relief valve within 24 hours after it has

vented to the atmosphere.

g)

 Routine instrument monitoring of valves which are not

externally regulated,

 flanges, and equipment in heavy

liquid service,

 is not required.

 However, any valve

which is not externally regulated,

 flange or piece of

equipment in heavy liquid service that is found to be

leaking on the basis

 of. sight,

 smell or sound shall be

 repaired as soon as practicable but no later than

30 days after the leak is found.

h)

 Test immediately after repair any component that was

found leaking.

i)

 Within one hour of its detection,

 a weatherproof,

readily visible tag,

 in bright colors such as red or

yellow, bearing an identification number and the date

119—348

113

on which the leak was detected must be affixed on the

leaking component and remain

 in place until the leaking

component is repaired.

j)

 The following components are exempt from the monitoring

requirements in this Section:

1)

 Any component that is in vacuum service, and

2)

 Any pressure relief valve that is connected to an

operating flare header or vapor recovery device.

Section 218.424

 Repairing Leaks

All leaking components must be repaired and retested as soon as

practicable but no later than 15 days after the leak is found

unless the leaking component cannot be repaired until the process

unit is shut down.

 Records of repairing and retesting must be

maintained in accordance with Section 218.425 and 218.426.

Section 218.425

 Recordkeeping for Leaks

a)

 The owner or operator of a synthetic organic chemical

or polymer manufacturing plant shall maintain a leaking

components monitoring log which shall contain, at a

 minimum, the following information:

1)

 The name of the process unit where the component

is located;

2)

 The type of component (e.g., valve,

 seal);

3)

 The identification number of the component;

4)

 The date on which a leaking component is

discovered;

5)

 The date on which a leaking component is repaired;

6)

 The date and instrument reading of the recheck

procedure after a leaking component is repaired;

7)

 A record of the calibration of the monitoring

instrument;

8)

 The identification number of leaking components

which cannot be repaired until process unit

shutdown; and

9)

 The total number of valves in light liquid service

and in gas service inspected; the total number and

the percentage of these valves found leaking

119—349

114

during the monitoring period.

b)

 Copies of the monitoring log shall be retained by the

owner or operator for a minimum of two years after the

date on which the record was made or the report was

prepared.

c)

 Copies of the monitoring log shall be made available to

the Agency upon verbal or written request prior to or

at the time of inspection pursuant to Section 4(d)

of

the Environmental Protection Act

 (Act)

 (Ill. Rev.

 Stat.

1989,

ch.

 111 1/2,

 pars.

 1001 et seq.)

 at any

reasonable time.

Section 218.426

 Report for Leaks

The owner or operator of a synthetic organic chemical or polymer

manufacturing plant subject to Section 218.421 through 218.430

shall:

a)

 Submit quarterly reports to the Agency on or before

March

 31, June 30, September 30, and December 31 of

each year,

 listing all leaking components identified

pursuant to Section 218.423 but not repaired within 15

days,

 all leaking components awaiting process unit

shutdown, the total number of components inspected,

the

type of components inspected, and the total number of

components found leaking, the total number of valves

in

light liquid service and in gas service inspected and

the number and percentage of valves

 in light liquid

service and in gas service found leaking.

b)

 Submit a signed statement with the report attesting

that all monitoring and repairs were performed as

required under Section 218.421 through 218.427.

Section 218.427

 Alternative Program for Leaks

The Agency shall approve an alternative program of monitoring,

recordkeeping,

 or reporting to that prescribed

 in this Subpart

upon a demonstration by the owner or operator of such plant that

the alternative program will provide plant personnel and Agency

personnel with an equivalent ability to identify and repair

 leaking components.

 Any alternative program can be allowed if

approved by the Agency and approved by the USEPA as a SIP

revision.

Section 218.428

 Open-Ended Valves

a)

 Each open-ended valve shall be equipped with a cap,

blind flange, plug,

 or a second valve,

 except during

operations requiring fluid flow through the open-ended

119—350

115

valve.

b)

 Each open—ended valve equipped with a second valve

shall be operated in a manner such that the valve on

the process fluid end is closed before the second valve

is closed.

C)

 Components which are open—ended valves and which serve

as a sampling connection shall be controlled such that:

1)

 A closed purge system or closed vent system shall

return purged process fluid to the process line

with no detectable VON emissions to the

atmosphere,

or

2)

 A closed purge system or closed vent system shall

collect and recycle purged process fluid to the

process line with no detectable VON emissions to

the atmosphere,

or

3)

 Purged process fluid shall be transported to a

control device that complies with the requirements

of Section 218.429.

d)

 In—situ sampling systems are exempt from subsection

(c).

Section 218.429

 Standards for Control Devices

Control devices used to comply with Section 218.428(c)

 shall

comply with the following:

a)

 If the control device is a vapor recovery system (for

example,

 condensers and adsorbers),

 it shall be

designed and operated to recover the VON emissions

vented to it with an efficiency of 95 percent or

greater.

b)

 If the control device is an enclosed combustion device,

it shall be designed and operated to reduce the VOM

emissions vented to it with an efficiency of 95 percent

or greater,

 or to provide a minimum residence time of

0.75 seconds at a minimum temperature of 816°C.

c)

 If the control device is a flare,

 it shall:

1)

 Be designed for and operated with no visible

emissions as determined by USEPA Reference Method

22,

 40 CFR 60, Appendix A (1986), incorporated by

reference in Section 218.112, except for periods

not to exceed a total

of

 5 minutes during any

2

consecutive hours.

119—35 1

116

2)

 Be operated with a pilot flame present at all

times and shall be monitored with a thermocouple

or any other equivalent device to detect the

presence of the pilot flame.

3)

 Be steam—assisted, air assisted,

 or nonassisted.

4)

 Be used only with the net heating value of the gas

being combusted being 11.2 NJ/scm

 (300 Btu/scf)

or

greater if the flare is steam—assisted or

air-assisted; or with the net heating value of the

gas being combusted being 7.45 NJ/scm or greater

if the flare is nonassisted.

 The net heating

value of the gas being combusted shall be

calculated using the following equation:

H

K

S

 C.H.

Where:

Hr

 Net heating value of the sample in NJ/scm;

where the net enthalpy per mole of offgas is based

on combustion at

25oC

 and 760 mm Hg, but the

standard temperature for determining the volume

corresponding to one mole is 20°C.

K

 Constant,

1.740 x 10~ (1/ppm) (g—mole/scm) (MJ/Kcal)

where

standard temperature for (g—mole/scm)

 is 20°C.

C1

 Concentration of sample component

i,

 in ppm,

as measured by USEPA Reference Method 18,

40

CFR 60, Appendix A

 (1986), and ASTN D

2504-83, both incorporated by reference in

Section 218.112.

H1

 Net heat of combustion of sample component

i,

kcal/g mole.

 The heats of combustion may be

determined using ASTN D 2382-83, incorporated

by reference in Section 218.112,

 if published

values are not available or cannot be

calculated.

5)

 Steam—assisted and nonassisted flares shall be

119—352

117

designed and operated with an exit velocity, as

determined by dividing the volumetric flowrate

(in

units of standard temperature and pressure),

as

determined by USEPA Reference Method

 2 or

2A,

CFR 60, Appendix A

 (1986)

 incorporated by

reference in Section 218.112, as appropriate;

by

the unobstructed

 (free) cross sectional area of

the flare tip, less than 18 m/sec

 (60 ft/sec).

6)

 Air-assisted flares shall be designed and operated

with an exit velocity less than the maximum

permitted velocity, V~, as determined by the

following equation:

Va

 8.706

+

O•7O84(Hr)~

Vmax

 Maximum permitted velocity, m/sec.

8.706

 Constant.

0.7084

 Constant.

Hr

 The net heating value as determined in

subsection

 (c) (4)

 of this section.

d)

 If the control device is a closed container,

 it shall

be designed and operated to reduce the VON emissions,

vented from purged process fluid after transfer,

 to no

detectable VON emissions as determined by USEPA

Reference Method 21 as specified at 40 CFR 60, Appendix

A (1986), incorporated by reference in Section 218.112.

For purposes of this Section, the phrase “after

transfer” shall refer to the time at which the entire

amount of purged process fluid resulting from a

flushing or cleaning of the sample line enters the

closed container or containers including the final’

container(s) prior to disposal.

e)

 The owner or operator of a control device shall monitor

the control device to ensure that it is operated and

maintained in conformance with the manufacturer’s

specifications, modified to the particular process

design.

f)

 The control device shall be operated at all times when

emissions may be vented to it.

Section 218.430

 Compliance Date

The

owner

operator

synthetic

organic

chemical

polymer

manufacturing

plant

subject

Ill.

Adm.

Code

215.430

through

215.438

December

31,

1987

shall

have

complied

with

the

standards

and

limitations

those

Sections

later

than

December

31,

1987.

119— 353

118

SUBPART

R:

 PETROLEUM REFINING AND RELATED INDUSTRIES; ASPHALT MATERIAL

Section 218.441

 Petroleum Refinery Waste Gas Disposal

a)

 Except as provided in subsection

(b)

or

 (c),

 no person

shall cause or allow the discharge of organic materials

in excess of 100 ppm equivalent methane

 (molecular

weight 16.0)

 into the atmosphere from:

1)

 Any catalyst regenerator of a petroleum cracking

system;

or

2)

 Any petroleum fluid coker; or

3)

 Any other waste gas stream from any petroleum or

petrochemical manufacturing process.

b)

 Exception.

 Existing sources subject to subsection

(a) (3) may, alternatively,

 at their election, comply

with the organic material emission limitations imposed

by 35 Ill. Adm. Code 215.301 or 215.302;

 provided,

however,

 that there shall be no increase in emissions

from such sources above the level of emissions in

existence on May

3,

 1979.

c)

 New Sources.

 Sources subject to subsection

 (a) (3),

construction of which commenced on or after January

1,

1977,

 may, at their election, comply with the following

emission limitations:

1)

 A maximum of eight pounds per hour of organic

material;

or

2)

 Emission of organic material in excess of the

limitation of subsection

 (c) (1)

 is allowable

if

such emissions are controlled by air pollution

control methods or equipment approved by the

Agency capable of reducing by 85 percent or more

the uncontrolled organic material that would

otherwise be emitted to the atmosphere.

 Such

methods or equipment must be approved by the

Agency and approved by the USEPA as a SIP

revision.

Section 218.442

 Vacuum Producing Systems

No owner or operator of a petroleum refinery shall cause or allow

the operation of any vacuum producing system unless the

condensers, hot wells and accumulators of any such system are

equipped with vapor loss control equipment including,

 but not

limited to,

 piping, valves,

 flame arrestors and hot wellcovers,

119—354

119

to vent any VOM with a vapor pressure of 10.34 kPa

 (1.5 psia) or

greater at 294.3oK (70°F) to a heater, fire box, flare, refinery

fuel gas system, or other equipment or system of equal emission

control as approved by the Agency and approved by the USEPA as

a

SIP revision.

 This Section shall not apply to vacuum producing

systems on lube units.

Section 218.443

 Wastewater (Oil/Water)

 Separator

No owner or operator of a petroleum refinery shall operate any

wastewater

 (oil/water) separator at a petroleum refinery unless

the separator is equipped with air pollution control equipment

capable of reducing by 85 percent or more the uncontrolled

organic material emitted to the atmosphere.

 If no odor nuisance

exists, the limitation of this Section shall not apply if the

vapor pressure of the organic material

 is below 10.34 kPa

 (1.5

psia)

 at 204.3oK (70°F) at all times.

Section 218.444

 Process Unit Turnarounds

a)

 No owner or operator of a petroleum refinery shall

cause or allow a refinery process unit turnaround

except

 in compliance with an operating procedure as

approved by the Agency.

b)

 Unless

 a procedure was already on file with the Agency

as part of an approved operating permit no later than

November

1,

 1979,

 the owner or operator of a petroleum

refinery shall submit to the Agency for approval a

detailed procedure for reducing emissions of VON during

refinery process unit turnarounds from organic material

with a vapor pressure of 10.34 kPa (1.5 psia)

or

greater at 294.3oK (70°F). The Agency shall not

approve the procedure unless it provides

 for:

1)

 Depressurization of the refinery process unit or

vessel to a flare, refinery fuel gas system,

or

other equipment or system of equal emission

 control,

 as approved by the Agency and approved by

the USEPA as a SIP revision, until the internal

pressure from the vessel or unit is less than 5.0

psig before allowing the vessel to be vented to

the atmosphere;

2)

 Recordkeeping of the following items:

A)

 Each date that a refinery unit or vessel

is

shut down; and

B)

 The total estimated quantity of VON emitted

to the atmosphere and the duration of the

emission in hours.

119—355

120

Section 218.445

 Leaks:

 General Requirements

a)

 The owner or operator of a petroleum refinery shall:

1)

 Develop a monitoring program plan consistent with

the provisions of Section 218.446;

2)

 Conduct a monitoring program consistent with the

provisions of Section 218.447;

3)

 Record all leaking components which have a

volatile organic material concentration exceeding

10,000 ppm consistent with the provisions of

Section 218.448;

4)

 Identify each component consistent with the

monitoring program plan submitted pursuant to

Section 218.446;

5)

 Repair and retest the leaking components as soon

as possible within 22 days after the leak

is

found, but no later than June

 1 for the purposes

of Section 218.447(a) (1), unless the leaking

 components cannot be repaired until the unit is

shut down for turnaround; and

6)

 Report to the Agency consistent with the

provisions of Section 218.449.

Section 218.446

 Monitoring Program Plan for Leaks

The owner or operator of a petroleum refinery shall prepare a

monitoring program plan which contains, at a minimum:

a)

 An identification of all refinery components and

the

period in which each will be monitored pursuant to

Section 218.447;

b)

 The format for the monitoring log required by Section

218.448;

c)

 A description of the monitoring equipment to be used

pursuant to Section 218.447; and

d)

 A description of the methods to be used to identify all

pipeline valves, pressure relief valves in gaseous

service and all leaking components such that they are

obvious to both refinery personnel performing

monitoring and Agency personnel performing inspections.

Section

218.447

Monitoring

Program

for

Leaks

119—356

121

a)

 The owner or operator of a petroleum refinery subject

to Section 218.445 shall, for the purpose of detecting

leaks,

 conduct a component monitoring program

consistent with the following provisions:

1)

 Test once between March

 1 and June

 1 of each

year,

by methods referenced in Section 218.105(g),

all

pump seals, pipeline valves in liquid service and

process drains.

2)

 Test once each quarter of each calendar year,

by

methods referenced in Section 218.105(g),

all

pressure relief valves in gaseous service,

pipeline valves in gaseous service and compressor

seals.

3)

 Inaccessible valves may be tested once each

calendar year instead of once each quarter

 of each

calendar year.

4)

 Observe visually all pump seals weekly.

5)

 Test immediately any pump seal from which liquids

are observed dripping,

6)

 Test any relief valve within 24 hours after it has

vented to the atmosphere,

and

7)

 Test immediately after repair any component that

was found leaking.

b)

 Storage tank valves and pressure relief devices

connected to an operating flare header or vapor

recovery device are exempt from the monitoring

requirements in subsection

 (a).

c)

 The Agency or the USEPA may require more frequent

monitoring than would otherwise be required by

subsection

(a)

 for components which are demonstrated to

have a history of leaking.

Section 218.448

 Recordkeeping for Leaks

a)

 The owner or operator of a petroleum refinery shall

maintain a leaking components monitoring

 log which

shall contain, at a minimum, the following information:

1)

 The name of the process unit where the component

is located;

2)

 The type of component

 (e.g., valve, seal);

119—357

122

3)

 The identification number of the component;

4)

 The date on which a leaking component is

discovered;

5)

 The date on which a leaking component is repaired;

6)

 The date and instrument reading of the recheck

procedure after a leaking component is repaired;

7)

 A record of the calibration of the monitoring

instrument;

8)

 The identification number of leaking components

which cannot be repaired until turnaround; and

9)

 The total number of components inspected and the

total number of components found leaking during

that monitoring period.

b)

 Copies of the monitoring log shall be retained by the

owner or operator for a minimum of two years after the

date on which the record was made or the report

prepared.

c)

 Copies of the monitoring log shall be made available to

the Agency, upon verbal or written request, at any

reasonable time.

Section 218.449

 Reporting for Leaks

The owner or operator of a petroleum refinery shall:

a)

 Submit a report to the Agency prior to the 1st day of

both July and September listing all leaking components

identified pursuant to Section 218.447 but not repaired

within 22 days,

 all leaking components awaiting unit

turnaround,

 the total number of components inspected

and the total number of components found leaking;

b)

 Submit a signed statement with the report attesting

that all monitoring and repairs were performed as

required under Sections 218.445 through 218.448.

Section 218.450

 Alternative Program for Leaks.

The Agency may approve an alternative program of monitoring,

recordkeeping or reporting to that prescribed in Sections 218.446

through 218.449 upon a demonstration by the owner or operator of

a petroleum refinery that the alternative program will provide

refinery, Agency and USEPA personnel with an equivalent ability

119—358

123

to identify and repair leaking components.

 Any alternative

program can be allowed only if approved by the USEPA as a SIP

revision.

Section 218.451

 Sealing Device Requirements

Except for safety pressure relief valves, no owner or operator

of

a petroleum refinery shall install or operate a valve at the end

of a pipe or line containing VOM5 unless the pipe or line is

sealed with a second valve, blind flange,

 plug, cap or other

sealing device.

 The sealing device may be removed only when

a

sample is being taken or during maintenance operations.

Section 218.452

 Compliance Schedule for Leaks

The owner or operator of a petroleum refinery shall adhere to the

increments of progress contained in the following schedule:

a)

 Have submitted to the USEPA a monitoring program

consistent with Section 218.446 prior to September

1,

1990.

b)

 Have submitted to the USEPA the first monitoring

report

pursuant to Section 218.449 prior to October

1,

 1990.

Section 218.453

 Compliance Dates

Every owner or operator of a petroleum refinery subject to

35

Ill.

Adm.

 Code 215, Subpart R as of December

31,

 1987 shall have

complied with its standards and limitations by December 31,

 1987.

SUBPART

S:

 RUBBER AND MISCELLANEOUS PLASTIC PRODUCTS

Section 218.461

 Manufacture of Pneumatic Rubber Tires

The owner or operator of an undertread cementing,

 treadend

cementing or bead dipping operation at a pneumatic rubber tire

manufacturing facility shall install and operate:

a)

 A capture system, with minimum capture efficiency of 65

percent by weight of VON for treadend cementing or bead

dipping operations and a capture system with a minimum

capture efficiency of 55.5 percent by weight of VON for

undertread cementing; and

b)

 A control device that meets the requirements of one of

the following:

1)

 A carbon adsorption system designed and operated

 in a manner such that there is at least a 90

percent removal of VON by weight from the gases

ducted to the control device;

119—359

124

2)

 An afterburning system that oxidizes at least 90

percent of the captured nonmethane VOM5

 (VON

measured as total combustible carbon)

 to carbon

dioxide and water; and

3)

 An alternative VON emission reduction system

demonstrated to have at least a 90 percent overall

reduction efficiency and approved by the Agency

and approved by the USEPA as a SIP revision.

Section 218.462

 Green Tire Spraying Operations

The

owner

operator

green

tire

spraying

operation

pneumatic

rubber

tire

manufacturing

facility

shall:

Install

and

operate:

capture

system

with

minimum

capture

efficiency

of 90 percent by weight of VON; and

2)

 A control device that meets the requirements of

one of the following:

carbon

adsorption

system

designed

and

operated in a manner such that there

 is at

least

percent

removal

VON

weight

from the bases ducted to the control device;

afterburning

system

that

oxidizes

least

90 percent of the captured nonmethane VON

(measured as total combustible carbon) to

carbon dioxide and water;

or

C)

 An alternative VOM emission reduction system

demonstrated to have at least a 90 percent

overall reduction efficiency and approved by

the Agency and approved by the USEPA as

 a SIP

revision.

Substitute

for

the

normal

solvent-based

mold

release

compound water—based sprays containing:

1)

 No more than five percent by volume of VON as

applied for the inside of tires;

2)

 No more than ten percent by volume of VON as

applied for the outside of tires.

Section 218.463

 Alternative Emission Reduction Systems

In lieu of complying with Section 218.461 or 218.462, the owner

119—360

125

or operator of an emission source may utilize an alternative

volatile organic emission reduction system, including an

alternative production process, which is demonstrated to be

equivalent to Section 218.461 or 218.462 on the basis of

emissions of volatile organic matter.

 A treadend cementing

operation shall be considered equivalent to Section 218.461 or

218.462 for the purposes of this Section if the total volatile

organic emission from such operation is 10 grams or less per

tire.

Section 218.464

 Testing and Monitoring

Upon

reasonable

request

the

Agency,

the

owner

operator of a VON emission source required to comply

with a limit of Sections 218.461 through 218.464 shall

conduct emissions testing,

 at such person’s own

expense,

 to demonstrate compliance.

b)

 A person planning to conduct a VON emission test to

demonstrate compliance shall notify the Agency of that

intent not less than 30 days before the planned

initiation of the tests so the Agency may observe the

test.

Section 218.465

 Compliance Dates

Every owner or operator of an emission source subject to

35

 Ill.

Adm. Code 215, Subpart

 S, as of December 31,

 1987 shall have

complied with its standards and limitations by December 31,

 1987.

Section 218.466

 Compliance Plan

a)

 The owner or operator of an emission source shall have

submitted to the Agency a compliance plan, pursuant to

35

 Ill.

 Adm. Code 201, Subpart H, including a project

completion schedule where applicable,

 no later than

 April

21,

 1983.

b)

 Unless the submitted compliance plan or schedule was

disapproved by the Agency, the owner or operator of a

facility or emission source may operate the emission

source according to the plan and schedule as submitted.

c)

 The plan and schedule shall meet the requirements of

35

Ill.

 Adm. Code 201, Subpart H, including specific

interim dates as required in 35 Ill. Adm. Code 201.242.

SUBPART

PHARMACEUTICAL

MANUFACTURING

Section 218.480

 Applicability

a)

 The rules of this Subpart, except for Sections 218.483

119—361

126

through 218.485,

 apply to all emission sources of VON,

including but not limited to reactors, distillation

units, dryers,

 storage tanks for VOL, equipment for the

transfer of VOL1 filters, crystallizers, washers,

laboratory hoods, pharmaceutical coating operations,

mixing operations and centrifuges used in

manufacturing,

 including packaging,

 of pharmaceuticals,

and emitting more than 6.8 kg/day

 (15 lbs/day) and more

than 2,268 kg/year

 (2.5 tons/year)

 of VON.

 If an

emission source emits less than 2,268 kg/year

 (2.5

tons/year)

 of VON, the requirements of this Subpart

still apply to the emission source

 if VON emissions

from the emission source exceed 45.4 kg/day

(100 lbs/day).

b)

 Notwithstanding subsection

 (a), the air suspension

coater/dryer, fluid bed dryers, tunnel dryers, and

Accelacotas located in Libertyville Township, Lake

County, Illinois shall be exempt from the rules of this

Subpart, except for Sections 218.483 through 218.485,

if emissions of VON not vented to air pollution control

equipment do not exceed the following levels:

1)

 for the air suspension coater/dryer: 2,268 kg/year

(2.5 tons/year);

2)

 for each fluid bed dryer:

 4,535 kg/year

(5.0 tons/year);

3)

 for each tunnel dryer:

 6,803 kg/year

 (7.5

tons/year); and

4)

 for each Accelacota:

 6,803 kg/year

(7.5 tons/year).

c)

 Sections 218.483 through 218.485 apply to a plant

having one or more emission sources that:

1)

 Are used to manufacture pharmaceuticals,

and

2)

 Emit more than 6.8 kg/day

 (15 lbs/day)

 of VON and

more than 2,268 kg/year

 (2.5 tons/year)

 of VON,

or,

 if less than 2,268 kg/year

 (2.5 tons/year),

these Sections still apply if emissions from one

or more sources exceed 45.4 kg/day (100 lbs/day).

d)

 No owner or operator shall violate any condition in a

permit when the condition results in exclusion of an

emission source from this Subpart.

e)

 Any pharmaceutical manufacturing source that becomes

subject to the provisions of this Subpart at any time

119—36 2

127

shall remain subject to the provisions of this Subpart

at all times.

f)

 Emissions subject to this Subpart shall be controlled

at all times consistent with the requirements set forth

in this Subpart.

g)

 Any control device required pursuant to this Subpart

shall be operated at all times when the source it is

controlling

 is operated.

h)

 Determinations of daily and annual emissions for

purposes of this Section shall be made using both data

on the hourly emission rate

 (or the emissions per unit

of throughput)

 and appropriate daily and annual data

from records of emission source operation

 (or material

throughput or material consumption data).

 In the

absence of representative test data pursuant to Section

218.487

 for the hourly emission rate (or the emissions

per unit of throughput), such items shall be calculated

using engineering calculations, including the methods

described in Appendix B of “Control of Volatile Organic

Emissions from Manufacturing of Synthesized

Pharmaceutical Products”

 (EPA—450/2—78—029),

incorporated by reference in Section 218.112.

 (This

subsection shall not affect the Agency’s or the USEPA’s

authority to require emission tests to be performed

 pursuant to Section 218.487.)

Section 218.481

 Control of Reactors, Distillation Units,

Crystallizers, Centrifuges and Vacuum Dryers

a)

 The owner or operator shall equip all reactors,

distillation units, crystallizers, centrifuges and

vacuum dryers that are used to manufacture

pharmaceuticals with surface condensers or other air

pollution control equipment listed in subsection

 (b).

If a surface condenser is used,

 it shall be operated

such that the condenser outlet gas temperature does not

exceed:

1)

 248.2oK (-13°F)when condensing VON of vapor

pressure greater than 40.0 kPa

 (5.8 psi)

at

294.3oK

(70°F),

or

258.2oK

(5°F)

 when condensing VON of vapor

pressure greater than 20.0 kPa (2.9 psi) at

294.3oK

(70°F),

or

3)

273.2oK

(32°F)

 when condensing VON of vapor

pressure greater than 10.0 kPa (1.5 psi)

at

294.3oK

(70°F),

or

119—3 63

128

4)

 283.2°K (50°F)

when condensing VON of vapor

pressure greater than 7.0 kPa (1.0 psi) at

294.3oK

(70°F), or

5)

 298.2oK (77°F)when condensing VON of vapor

 pressure greater than 3.45 kPa

 (0.5 psi) at

294.3oK

(70°F).

b)

If

 a scrubber, carbon adsorber, thermal afterburner,

catalytic afterburner,

 or other air pollution control

equipment other than a surface condenser is used, such

equipment shall provide a reduction in the emissions of

VON of 90 percent or more.

c)

 The owner or operator shall enclose all centrifuges

used to manufacture pharmaceuticals and that have an

exposed VOL surface, where the VON in the VOL has a

vapor pressure of 3.45 kPa

 (0.5 psi) or more at

294.3oK

(70°F),except as production,

 sampling, maintenance,

or

inspection procedures require operator access.

Section 218.482

 Control of Air Dryers, Production Equipment

Exhaust Systems and Filters

a)

 The owner or operator of an air dryer or production

equipment exhaust system used to manufacture

pharmaceuticals shall control the emissions of VON from

such emission sources by air pollution control

equipment which reduces by 90 percent or more the VON

that would otherwise be emitted into the atmosphere.

b)

 The owner or operator shall enclose all rotary vacuum

filters and other filters used to manufacture

pharmaceuticals and that have an exposed VOL surface,

where the VON in the VOL has a vapor pressure of 3.45

kPa

 (0.5 psi)

 or more at 294°K

(7OoF),

except as

production,

 sampling, maintenance, or inspection

procedures require operator access.

Section 218.483

 Material Storage and Transfer

The owner or operator of a pharmaceutical manufacturing plant

shall:

a)

 Provide a vapor balance system that is at least

90

percent effective in reducing VON emissions from

truck or railcar deliveries to storage tan~cswith

capacities equal to or greater than 7.57 m

 (2,000 gal)

that store VOL with vapor pressures greater than

28.0 kPa

 (4.1 psi)

 at 294.3°K(70°F),and

119—364

129

b)

 Install,

 operate, and maintain pressure/vacuum

conservation vents set at 0.2 kPa

 (0.03 psi)

 or greater

on all storage tanks that store VOL with vapor

pressures

greater

than

kPa

 (1.5

 psi)

 at 294.3°K

(70°F)

Section 218.484

 In-Process Tanks

The owner or operator shall install covers on all in-process

tanks used to manufacture pharmaceuticals and containing a VOL at

any time.

 These covers must remain closed, except as production,

sampling, maintenance or inspection procedures require operator

access.

Section 218.485

 Leaks

The owner or operator of a pharmaceutical manufacturing plant

 shall repair any component from which a leak of VOL can be

observed.

 The repair shall be completed as soon as practicable

but no later than 15 days after the leak is found.

 If the

leaking component cannot be repaired until the process unit is

shut down,

 the leaking component must then be repaired before the

unit is restarted.

Section 218.486

 Other Emission Sources

The

 owner or operator of a washer, laboratory hood,

 tablet

coating operation,

 mixing operation or any other process emission

source not subject to Sections 218.481 through 218.485, and used

to manufacture pharmaceuticals shall control the emissions of VON

from such emission sources by:

a)

 Air pollution control equipment which reduces by

81 percent or more the VON that would otherwise be

emitted to the atmosphere,

or

b)

 A surface condenser which captures all the VON which

would otherwise be emitted to the atmosphere and which

meets the requirements of Section 218.481(a)

and

 (b).

Section 218.487

 Testing

a)

 Upon request by the Agency or the USEPA, the owner or

operator of any VON emission source subject to this

Subpart or exempt from this Subpart by virtue of the

provisions of Section 218.480 shall,

 at his own

expense, demonstrate compliance to the Agency and the

USEPA by the methods or procedures listed in Section

218.105(f) (1).

b)

A

person planning to conduct a VON emissions test to

119—365

130

demonstrate compliance with this Subpart shall notify

the Agency and the USEPA of that intent not less than

30 calendar days before the planned initiation of the

test.

Section 218.488

 Monitoring for Air Pollution Control

Equipment

a)

 At a minimum, continuous monitors for the following

parameters shall be installed on air pollution control

equipment used to control sources subject to this

Subpart:

1)

 Destruction device combustion temperature.

2)

 Temperature rise across a catalytic afterburner

bed.

3)

 VON concentration on a carbon adsorption unit to

determine breakthrough.

4)

 Outlet gas temperature of a refrigerated

condenser.

5)

 Temperature of a non—refrigerated condenser

coolant supply system.

b)

 Each monitor shall be equipped with a recording device.

c)

 Each monitor shall be calibrated quarterly.

d)

 Each monitor shall operate at all times while the

associated control equipment is operating.

Section 218.489

 Recordkeeping for Air Pollution Control

Equipment

a)

 The owner or operator of a pharmaceutical manufacturing

facility shall maintain the following records:

1)

 Parameters listed in Section 218.488(a) (1)

 shall

be recorded.

2)

 For sources subject to Section 218.481, the vapor

pressure of VON being controlled shall be recorded

for every process.

b)

 For any leak subject to Section 218.485 which cannot be

readily repaired within one hour after detection, the

following records shall be kept:

1)

 The name of the leaking equipment,

119—36 6

131

2)

 The date and time the leak is detected,

3)

 The action taken to repair the leak,

and

4)

 The data and time the leak is repaired.

c)

 The following records shall be kept for emission

sources subject to Section 218.484 which contain VOL:

1)

 For maintenance and inspection:

A)

 The date and time each cover is opened,

B)

 The length of time the cover remains open,

and

C)

 The reason why the cover

 is opened.

2)

 For production and sampling, detailed written

procedures or manufacturing directions specifying

the circumstances under which covers may be opened

and the procedures for opening covers.

d)

 For each emission source used in the manufacture of

pharmaceuticals for which the owner or operator

of a

pharmaceutical manufacturing plant claims emission

standards are not applicable,

 because the emissions are

below the applicability cutoffs in Section 218.480(a)

or 218.480(b), the owner or operator shall:

1)

 Maintain a demonstration including detailed

engineering calculations of the maximum daily and

annual emissions for each such emission source

showing that the emissions are below the

applicability cutoffs in Section 218.480(a)

or

218.480(b),

 as appropriate,

 for the current and

prior calendar years;

2)

 Maintain appropriate operating records for each

such emission source to identify whether the

applicability cutoffs in Section 218.480(a)

or

218.480(b),

 as appropriate,

 are ever exceeded; and

3)

 Provide written notification to the Agency and the

USEPA

within 30 days of a determination that such

an emission source has exceeded the applicability

cutoffs in Section 218.480(a)

 or 218.480(b),

as

appropriate.

e)

 Records required under subsection

(a)

 shall be

maintained by the owner or operator for a minimum of

119—36 7

132

two years after the date on which they are made.

 Copies of the records shall be made available to the

Agency or the USEPA upon verbal or written request.

SUBPART V:

 AIR OXIDATION PROCESSES

Section 218.521

 Definitions

addition

the

definitions

Ill.

Adm.

Code

211,

the

following

definitions

apply

this

Subpart:

“Air

Oxidation

Process”:

any

unit

process

including

aminoxidation and oxychlorination which uses air or a

combination of air and oxygen as an oxidant in

combination

with

one

organic

reactants

produce

one

organic

compounds.

“Cost

Effectiveness”:

the

annual

expense

for

cost

control of a given process stream divided by the

reduction in emissions of organic material of that

stream.

“Flow

 (F)”:

 Vent stream flowrate (scm/mm)

 at a

standard temperature of 20°C.

“Full

Operating Flowrate”:

 Maximum operating capacity

of the facility.

“Hourly Emissions

 (E)”:

 Hourly emissions reported in

kg/hr

measured

full

operating

flowrate.

“Net Heating Value

 (H)”:

 Vent stream net heating valuE

(NJ/scm), where the net enthalpy per mole of offgas

is

based on combustion at 25°Cand 760 mm Hg, but the

standard temperature for determining the volume

corresponding to one mole is 20°C,as in the definitior

of

 “Flow.”

“Process Vent Stream”:

 An emission stream resulting

from an air oxidation process.

“Total Resource Effectiveness Index

 (TRE)”:

 Cost

effectiveness in dollars per megagram of controlling

any gaseous stream vented to the atmosphere from an

au

oxidation process divided by $1600/Mg, using the

criteria and methods set forth in this Subpart and

Appendices C and D.

Section 218.525

 Emission Limitations for Air Oxidation

Processes

119—368

133

a)

 No person shall cause or allow the emission of VON from

any process vent stream unless the process vent stream

is vented to a combustion device which is designed and

operated either:

1)

 To reduce the volatile organic emissions vented

it with an efficiency of at least ninety eight

percent

 (98)

 by weight; or

2)

 To emit VON at a concentration less than twenty

parts

per

million

volume,

dry

basis.

b)

 Air oxidation facilities for which an existing

combustion device is employed to control process VON

emissions are not required to meet the 98 percent

emissions limit until the combustion device is replaced

for other reasons, which shall be considered to

include,

 but not be limited to, normal maintenance,

malfunction, accident, and obsolescence.

The

combustion device is considered to be replaced when:

1)

All

of the device

 is replaced; or

2)

 When the cost of the repair of the device or the

cost of replacement of part of the device exceeds

50

 of the cost of replacing the entire device

with a device which complies.

c)

 The limitations of subsection

 (a) do not apply to any

process vent stream or combination of process vent

streams which has a Total Resource Effectiveness Index

(TRE)

 greater than 1.0,

 as determined by the following

methods:

1)

If

an air oxidation process has more than one

process vent stream, TRE shall be based upon a

combination of the process vent streams.

2)

 TRE of a process vent stream shall be determined

according to the following equation:

TRE

E1

a

 + bF~

+

cF

+

dFH

+

e(FH)~

+

fF05

where:

n

 0.88

TRE

Total

resource

effectiveness

index.

F

 Vent stream flowrate (scm/mm),

 at a

standard temperature of 20°C.

119—369

134

E

 Hourly measured emissions in kg/hr.

H

 Net heating value of vent stream

(NJ/scm), where the net enthalpy per

mole of offgas

 is based on combustion at

25°Cand 760 mm Hg, but the standard

temperature for determining the volume

corresponding to one mole is 2OoC,

as

in

the definition of “Flow”.

a, b,c,d,

e and f

 Coefficients obtained by use of Appendix

F.

3)

 For nonchlorinated process vent streams,

 if the

net heating value, H,

 is greater than 3.6 NJ/scm,

F shall be replaced by F’ for purposes of

calculating TRE.

 F1 is computed as follows:

F1

FH

/

3.6

where F and H are as defined in subsection

 (c) (2).

4)

 The actual numerical values used in the equation

described in subsection

 (c) (2)

 shall be determined

as follows:

A)

 All reference methods and procedures for

 determining the flow,

 (F), hourly emissions,

(E), and net heating,

 (H), value shall be in

accordance with Appendix C.

B)

 All coefficients described in subsection

(C)

(2)

 shall be in accordance with Appendix

D.

Section 218.526

 Testing and Monitoring

a)

 Upon reasonable request by the Agency, the owner or

operator of an air oxidation process shall demonstrate

compliance with this Subpart by use of the methods

specified in Appendix C.

 This Section does not limit

the USEPA’s authority, under the Clean Air Act, to

require demonstrations of compliance.

b)

 A person planning to conduct a VON emissions test to

demonstrate compliance with this Subpart shall notify

the Agency of that intent not less than 30 days before

the planned initiation of the tests so that the Agency

may observe the test.

119—370

135

Section

218.527

 Compliance Date

Each

owner

 or operator of an emission source subject to’35

 Ill.

Adm. Code

 215, Subpart V,

 as of December 31,

 1987 shall have

complied with the standards and limitations of 35 Ill. Adm. Code

215, Subpart V, by December 31,

 1987.

SUBPART W:

 AGRICULTURE

Section 218.541

 Pesticide Exception

The provisions of Sections 218.301 and 218.302

shall not apply to

the spraying or use of insecticides, herbicides or other

pesticides.

SUBPART

X:

 CONSTRUCTION

Section

218.561

 Architectural Coatings

No

person shall cause or allow the sale or use of any

architectural coating containing more than 20 percent by volume

of

photo-chemically reactive material in containers having a

capacity of more than one gallon.

Section 218.562

 Paving Operations

The provisions of Sections 218.301 and 218.302 shall not apply to

the application of paving asphalt and pavement marking paint from

sunrise to sunset.

Section 218.563

 Cutback Asphalt

a)

 No person shall cause or allow the use or application

of cutback asphalt for paving, resurfacing,

reconditioning, repairing or otherwise maintaining a

roadway unless:

1)

 The use or application of the cutback asphalt

commences on or after October

 1 of any year and

such use or application is completed by April

30

of the following year;

or

2)

 The cutback asphalt is a long—life stockpile

material which remains in stock after April 30 of

each year and as such it may be used until

depleted for patching potholes and for other

similar repair work; or

3)

 The cutback asphalt is to be used solely as an

 asphalt prime coat.

119—37 1

136

b)

 Sources subject to this Section are not required to

submit or obtain an Agency approved compliance plan or

project completion schedule under 35 Ill. Adm. Code

201, Subpart H.

SUBPART

Y:

 GASOLINE DISTRIBUTION

Section 218.581

 Bulk Gasoline Plants

a)

 Subject to Subsection

 (e), no person may cause or allow

the transfer of gasoline from a delivery vessel into a

stationary storage tank located at a bulk gasoline

plant unless:

1)

 The delivery vessel and the stationary storage

tank are each equipped with a vapor collection

system that meets the requirements of subsection

(d) (4),

2)

 Each vapor collection system is operating,

3)

 The delivery vessel displays the appropriate

sticker pursuant to the requirements of Sections

218.584

(b)

or

 (d),

4)

 The pressure relief valve(s) on the stationary

storage tank and the delivery vessel are set to

release at no less than 0.7 psi or the highest

pressure allowed by state or local fire codes or

the guidelines of the National Fire Prevention

Association, and

5)

 The stationary storage tank is equipped with a

submerged loading pipe.

b)

 Subject to subsection

 (f), no person may cause or allow

 the transfer of gasoline from a stationary storage tank

located at a bulk gasoline plant into a delivery vessel

unless:

1)

 The requirements set forth in subsections

 (a) (1)

through

 (a) (4)

 are met, and

2)

 Equipment is available at the bulk gasoline plant

to provide for the submerged filling of the

delivery vessel or the delivery vessel is equipped

for bottom loading.

c)

 Subject to subsection

 (e), each owner of

 a stationary

storage tank located at a bulk gasoline plant shall:

1)

 Equip each stationary storage tank with a vapor

119—37 2

137

control system that meets the requirements of

subsection

(a)

or

 (b), whichever is applicable,

2)

 Provide instructions to the operator of the bulk

gasoline plant describing necessary maintenance

operations and procedures for prompt notification

of the owner in case of any malfunction of a vapor

control system,

and

3)

 Repair, replace or modify any worn out or

malfunctioning component or element of design.

d)

 Subject to subsection

 (e), each operator of

 a bulk

gasoline

plant

shall:

1)

 Maintain and operate each vapor control system in

accordance

with

the

owner’s

instructions,

2)

 Promptly notify the owner of any scheduled

maintenance

malfunction

requiring

replacement

or repair of a major component of a vapor control

system, and

3)

 Maintain gauges, meters or other specified testing

devices in proper working order,

4)

 Operate the bulk plant vapor collection system and

gasoline

equipment

manner

that

prevents:

A)

 Gauge pressure from exceeding 45.7 cm

(18

in.)

 of water and vacuum from exceeding 15.2

cm

(6

 in.) of water,

 as measured as close as

possible to the vapor hose connection, and

B)

A

reading equal to or greater than 100

percent of the lower explosive limit

 (LEL

measured as propane) when tested in

accordance with the procedure described in

“Control of Volatile Organic Compound Leaks

from

Gasoline

Tank

Trucks

and

Vapor

Collection

Systems”,

Appendix

EPA

450/2—78—051,

(incorporated

reference

Section

218.112),

and

Avoidable

leaks

liquid

during

unloading operations.

5)

 Provide a pressure tap or equivalent on the bulk

plant

vapor

collection

system

order

allow

the determination of compliance with subsection

(d) (4) (A), and

119—373

138

6)

 Within 15 business days after discovery of any

leak by the owner, the operator, the Agency or the

USEPA,

repair and retest

 a vapor collection system

which exceeds the limits of subsection

 (d) (4) (A)

or

 (B).

e)

 The requirements of subsections

 (a),

 (c) and

(d)

 shall

not apply to:

1)

 Any stationary storage tank with a capacity of

less than 2,177

1

 (575 gal),

or

2)

 Any bulk gasoline plant whose daily gasoline

throughput is less than 15,140

1

 (4,000 gal/day)

on a thirty-day rolling average.

f)

The

requirements of subsection

(b)

 shall apply only to

bulk

gasoline plants whose daily gasoline throughput

is

greater than or equal to 15,140

1

 (4,000 gal/day)

 on a

thirty-day rolling average.

g)

 Any bulk gasoline plant which is ever subject to

subsections

 (a),

 (b),

 (c), or

(d)

 shall always be

subject to these paragraphs.

Section 218.582

 Bulk Gasoline Terminals

a)

 No person shall cause or allow the transfer of gasolinE

into any delivery vessel from any bulk gasoline

terminal unless:

1)

 The bulk

gasoline

terminal

equipped

with

vapor control system that limits emission of VON

to 80 mg/1 (0.00067 lbs/gal)

 of gasoline loaded;

2)

 The vapor control system is operating and all

vapors displaced in the loading of gasoline to thE

delivery vessel are vented only to the vapor

control system;

3)

 There is no liquid drainage from the loading

device when it is not in use;

4)

All

loading and vapor return lines are equipped

with

fittings

which

are

vapor

tight;

and

5)

The

delivery vessel displays the appropriate

sticker pursuant to the requirements of Section

218.584(b)

or

 (d); or,

 if the terminal is

driver—loaded, the terminal owner or operator

shall be deemed to be in compliance with this

119—3 74

139

Section when terminal access authorization is

limited to those owners and/or operators of

delivery vessels who have provided a current

certification as required by Section

218.584(c) (3).

b)

 Bulk

gasoline terminals were required to take certain

actions to achieve compliance which are summarized in

35 Ill.

 Adm.

 Code 215, Appendix C.

c)

 The operator of a bulk gasoline terminal shall:

1)

 Operate the

terminal

vapor

collection

system

and

gasoline

equipment

manner

that

prevents:

A)

 Gauge pressure from exceeding

 18 inches of

water and vacuum from exceeding 6 inches of

water as measured as close as possible to the

vapor hose connection; and

B)

 A reading equal to or greater than 100

percent of the lower, explosive limit

 (LEL

measured as propane) when tested in

accordance with the procedure described in

EPA 450/2—78-051 Appendix B incorporated by

reference in Section 218.112; and

C)

 Avoidable leaks of liquid during loading or

unloading operations.

2)

 Provide a pressure tap or equivalent on the

terminal vapor collection system in order to allow

the determination of compliance with Section

218.582(d) (1) (A); and

3)

 Within 15 business days after discovery of the

leak by the owner,

 operator,

 or the Agency repair

and retest a vapor collection system which exceeds

the limits of subsection

 (c) (1) (A)

or

 (B).

Section 218.583

 Gasoline Dispensing Facilities

a)

 Subject to subsection

 (b), no person shall cause or

allow the transfer of gasoline from any delivery vessel

into any stationary storage tank at a gasoline

dispensing facility unless:

1)

 The tank is equipped with a submerged loading

pipe; and

2)

 The vapors displaced from the storage tank during

119—375

140

filling are processed by a vapor control system

that includes one or more of the following:

A)

 A vapor collection system that meets the

requirements of subsection

 (d) (4);

or

B)

 A refrigeration—condensation system or any

other

system

approved

the

Agency

and

approved by the USEPA as a SIP revision,

that

recovers at least 90 percent by weight of all

vaporized organic material from the equipment

being

controlled;

and

C)

 The delivery vessel displays the appropriate

sticker pursuant to the requirements of

Section 218.584(b)

or

 (d).

b)

 The requirements of subsection

 (a) (2)

 shall not apply

to transfers of gasoline to a stationary storage tank

at a gasoline dispensing facility if:

1)

 The tank is equipped with a floating roof,

or

other system of equal or better emission control

approved

the

Agency

and

approved

the

 USEPA

as a SIP revision;

2)

 The tank has a capacity of less than 2000 gallons

and was in place and operating before January

1,

1979;

or

3)

 The tank has a capacity of less than 575 gallons.

c)

 Subject to subsection

 (b), each owner of a gasoline

dispensing facility shall:

1)

 Install all control systems and make all process

modifications required by subsection

 (a);

2)

 Provide instructions to the operator of the

gasoline dispensing facility describing necessary

maintenance operations and procedures for prompt

notification

the

owner

case

any

malfunction of a vapor control system; and

3)

 Repair, replace or modify any worn out or

malfunctioning component or element of design.

d)

 Subject to subsection

 (b), each operator of

 a gasoline

dispensing facility shall:

1)

 Maintain and operate each vapor control system in

accordance with the owner’s instructions;

119—376

141

Promptly

notify

the

owner

any

scheduled

maintenance or malfunction requiring replacement

or repair of a major component of a vapor control

system;

3)

 Maintain gauges, meters or other specified testing

devices in proper working order;

4)

 Operate the vapor collection system and delivery

vessel unloading points in a manner that prevents:

A)

 A reading equal to or greater than 100

percent of the lower explosive limit

 (LEL

measured as propane) when tested in

accordance with the procedure described in

EPA 450/2-78—051 Appendix B, and

B)

 Avoidable leaks of liquid during the filling

of storage tanks; and

5)

 Within 15 business days after discovery of the

leak by the owner,

 operator, or the Agency,

 repair

and retest a vapor collection system which exceeds

the limits of subsection

 (d) (4) (A).

e)

 Gasoline dispensing facilities were required to take

certain actions to achieve compliance which are

summarized in 35 Ill. Adm.

 Code 215, Appendix C.

Section 218.584

 Gasoline Delivery Vessels

a)

 Any delivery vessel equipped for vapor control by use

of vapor collection equipment:

1)

 Shall have a vapor space connection that is

equipped with fittings which are vapor tight;

2)

 Shall have its hatches closed at all times during

loading or unloading operations, unless a top

loading vapor recovery system is used;

3)

 Shall not internally exceed a gauge pressure of 18

inches of water or a vacuum of

 6 inches of water;

4)

 Shall be designed and maintained to be vapor tight

at all times during normal operations;

5)

 Shall not be refilled in Illinois at other than:

A)

 A bulk gasoline terminal that complies with

the requirements of Section 218.582 or

119—377

142

B)

 A bulk gasoline plant that complies with the

requirements of Section 218.581(b).

6)

 Shall be tested annually in accordance with Method

27,

 40 CFR 60, Appendix A,

 incorporated by

reference

Section

218.105.

Each

vessel

must

repaired and retested within

 15 business days

after

discovery

the

leak

the

owner,

operator,

 or the Agency, when it fails to sustain:

pressure

drop

than

three

inches

of water in five minutes; and

vacuum

drop

than

three

inches

water

five

minutes.

Any

delivery

vessel

meeting

the

requirements

subsection

(a)

shall

have

sticker

affixed

the

 tank

adjacent to the tank manufacturer’s data plate

which

contains the tester’s name, the tank identification

number and the date of the test.

 The sticker shall be

in a form prescribed by the Agency,

 and,

 for those

delivery vessels subject to 35 Ill. Adm. Code 215 as of

December 31,

 1987 shall have been displayed no later

than December 31,

 1987.

c)

 The owner or operator of a delivery vessel shall:

1)

 Maintain copies of any test required under

subsection

 (a) (6)

 for a period of

 3 years;

2)

 Provide copies of these tests to the Agency upon

request; and

3)

 Provide annual test result certification to bulk

gasoline plants and terminals where the delivery

vessel is loaded.

d)

 Any delivery vessel which has undergone and passed a

 test in another state which has a USEPA-approved leak

testing and certification program will satisfy the

requirements of subsection

 (a).

 Delivery vessels must

display a sticker, decal or stencil approved by the

state where tested or comply with the requirements of

subsection

 (b).

 All such stickers, decals or stencils

shall have been displayed no later than December 31,

1987,

 for delivery vessels subject to 35 Ill.

 Adm. Code

215 as of December 31,

 1987.

Section 218.585

 Gasoline Volatility Standards

119—3 78

143

a)

 No person shall sell,

 offer for sale, dispense,

 supply,

offer for supply, or transport for use in Illinois

gasoline whose Reid vapor pressure exceeds the

applicable limitations set forth in subsections

(b)

and

(c) during the regulatory control periods, which shall

be July

 1 to August 31 for retail outlets, wholesale

purchaser—consumer facilities,

 and all other

facilities.

b)

 The Reid vapor pressure of gasoline,

 a measure of its

volatility,

 shall not exceed 9.5 psi (65.5 kPa) during

the regulatory control period in 1990 and each year

thereafter.

C)

 The Reid vapor pressure of ethanol blend gasolines

shall not exceed the limitations for gasoline set forth

in subsection

 (b) by more than 1.0 psi

 (6.9 kPa).

Notwithstanding this limitation, blenders of ethanol

blend gasolines whose Reid vapor pressure

 is less than

1.0 psi above the base stock gasoline immediately after

blending with ethanol are prohibited from adding butane

or any product that will increase the Reid vapor

pressure of the blended gasoline.

d)

 All sampling of gasoline required pursuant to the

provisions of this Section shall be cOnducted by

 •one or

more of the following approved methods or procedures

which are incorporated by reference in Section 215.105.

1)

 For manual sampling, ASTM D4057;

2)

 For automatic sampling, ASTN D4l77;

3)

 Sampling procedures for Fuel Volatility,

 40 CFR 80

Appendix D.

e)

 The Reid vapor pressure of gasoline shall be measured

in accordance with either test method ASTN D323

 or a

modification of ASTN D323 known as the “dry method” as

set forth in 40 CFR 80, Appendix E, incorporated by

reference in 35 Ill. Adm. Code 215.105.

 For gasoline

oxygenate blends which contain water—extractable

oxygenates,

 the Reid vapor pressure shall be measured

using the dry method test.

f)

 The ethanol content of ethanol blend gasolines shall be

determined by use of one of the approved testing

methodologies specified in 40 CFR 80, Appendix

F,

incorporated by reference in 35 Ill.

 Adin.

 Code 215.105.

g)

 Any alternate to the sampling or testing methods or

procedures contained in subsections

 (d),

 (e), and

(f)

119—379

144

must be approved by the Agency, which shall consider

data comparing the performance of the proposed

alternative to the performance of one or more approved

test methods or procedures.

 Such data shall accompany

any request for Agency approval of any alternate test

procedure.

 If the Agency determines that such data

demonstrates that the proposed alternative will achieve

results equivalent to the approved test methods or

procedures,

 the Agency shall approve the proposed

alternative.

h)

 Each refiner or supplier that distributes gasoline or

ethanol blends shall:

1)

 During the regulatory control period, state that

the Reid vapor pressure of all gasoline or ethanol

blends leaving the refinery or distribution

facility for use in Illinois complies with the

Reid vapor pressure limitations set forth in

35

Ill. Adm.

 Code 215.585(b)

and

 (c).

 Any facility

receiving this gasoline shall be provided with

a

copy of an invoice, bill of lading,

 or other

documentation used in normal business practice

stating that the Reid vapor pressure of the

gasoline complies with the State Reid vapor

 pressure standard.

2)

 Maintain records for a period of one year on the

Reid vapor pressure, quantity shipped and date of

delivery of any gasoline or ethanol blends leaving

the refinery or distribution facility for use

in

Illinois.

 The Agency shall be provided with

copies of such records

 if requested.

SUBPART

Z:

 DRY CLEANERS

Section 218.601

 Perchloroethylene Dry Cleaners

The owner or operator of a dry cleaning facility which uses

perchloroethylene shall:

a)

 Vent the entire dryer exhaust through a properly

designed and functioning carbon adsorption system or

equally effective control device; and

b)

 Emit no more than 100 ppmv of VOM from the dryer

control device before dilution, or achieve a 90 percent

average reduction before dilution; and

c)

 Immediately repair all components found to be leaking

liquid VON; and

119—380

145

d)

 Cook or treat all diatomaceous earth filters so that

the residue contains 25 kg

 (55 lb)

 or less of VOM per

100 kg

 (220 lb)

 of wet waste material; and

e)

 Reduce the VON from all solvent stills to 60 kg (132

1b)

less

per

100

(220

lb)

wet

waste

material;

and

f)

 Drain all filtration cartridges in the filter housing

other

sealed

container

for

least

hours

before

discarding

the

cartridges;

and

g)

 Dry all drained filtration cartridges in equipment

connected to an emission reduction system or in a

manner that will eliminate emission of VON to the

atmosphere.

Section 218.602

 Exemptions

The provisions of Section 218.601 are not applicable to

perchloroethylene dry cleaning operations which are coin-operated

or to dry cleaning facilities consuming less than 30 gal per

month

 (360 gal per year)

 of perchloroethylene.

Section 218.603

 Leaks

The presence of leaks shall be determined for purposes of Section

218.601(c)

 by a visual inspection of the following: hose

connections, unions, couplings and valves; machine door gaskets

and seatings; filter head gasket and seating; pumps;

 base tanks

and storage containers; water separators;

 filter sludge recovery;

distillation unit; diverter valves; saturated lint from lint

baskets; and cartridge filters.

Section 218.604

 Compliance Dates

Every owner or operator of an emission source previously subject

to 35

 Ill. Adm. Code 215, Subpart

Z,

 shall have complied with its

standards and limitations in accordance with the applicable dates

 set forth

 in 35 Ill. Adm. Code 215.604.

Section 218.605

 Compliance Plan

a)

 The owner or operator of an emission source subject to

this Subpart shall have submitted to the Agency a

compliance plan, pursuant to 35 Ill.

 Adm. Code 201,

Subpart H, including

 a project completion schedule

where applicable, no later than,

 for Section 218.601 (a)

and

 (b), April

21,

 1983.

b)

 Unless the submitted compliance plan or schedule was

disapproved by the Agency, the owner or operator of

a

119—38 1

146

facility or emission source may operate the emission

source according to the plan and schedule as submitted.

The

plan

and

schedule

shall

meet

the

requirements

Ill. Adm. Code 201,

 Subpart H,

 including specific

interim dates as required in 35 Ill. Adm. Code 201.242.

Section 218.606

 Exception to Compliance Plan

coin-operated dry cleaning operations and dry cleaning facilities

consuming less than 30 gal per month (360 gal per year)

of

perchloroethylene are not required to submit or obtain an Agency

approved compliance plan or project completion schedule.

Section 218.607

 Standards for Petroleum Solvent Dry Cleaners

a)

 The owner or operator of a petroleum solvent dry

cleaning dryer shall either:

1)

 Limit emissions of VON to the atmosphere to an

average

3.5

kilograms

VON

per

100

kilograms

dry weight of articles dry cleaned,

or

2)

 Install and operate a solvent recovery dryer in a

manner such that the dryer remains closed and the

recovery phase

 continues until a final solvent

flow rate of 50 milliliters per minute is

attained.

b)

 The owner or operator of a petroleum solvent filtration

system shall either:

1)

 Reduce the VOM content in all filtration wastes to

1.0 kilogram or less per 100 kilograms dry weight

of articles dry cleaned, before disposal, and

exposure to the atmosphere,

or

2)

 Install and operate a cartridge filtration system,

and drain the filter cartridges in their sealed

housings for 8 hours or more before their removal.

Section 218.608

 Operating Practices for Petroleum Solvent

Dry

Cleaners

In order to minimize fugitive solvent emissions,

 the owner or

operator of a petroleum solvent dry cleaning facility shall

employ good housekeeping practices including the following:

a)

 General Housekeeping Requirements

I)

 Equipment containing solvent

 (washers, dryers,

extractors and filters)

 shall remain closed at all

119—382

147

times except during load transfer and maintenance.

Lint filter and button trap covers shall remain

closed except when solvent—laden material

 is being

removed.

Cans,

buckets,

barrels

and

other

containers

solvent or of solvent—laden material shall be

covered except when in use.

3)

 Solvent-laden material shall be exposed to the

atmosphere

only

for

the

minimum

time

necessary

for

load transfer.

b)

 Installation and operation of equipment:

1)

 All cartridge filters shall be enclosed and

operated in accordance with the procedures and

specifications recommended by the manufacturer for

the cartridge filter.

 After installation, the

cartridges shall be inspected, monitored and

maintained in accordance with the manufacturer’s

recommendations;

and

2)

 Vents on containers for new solvent and for

solvent—containing waste shall be constructed and

maintained so as to minimize solvent vapor

emissions.

 Criteria for the minimization of

solvent vapor emissions include the elimination of

solvent buckets and barrels standing open to the

atmosphere,

 and the repair of gaskets and seals

 that expose solvent—rich environments to the

atmosphere,

 to be determined through visual

inspection.

Section 218.609

 Program for Inspection and Repair of

Leaks

a)

 The owner or operator of

 a petroleum solvent dry

cleaning facility shall conduct the following visual

inspections on a weekly basis:

1)

 Washers, dryers, solvent filters, settling tanks,

vacuum stills and containers and conveyors of

petroleum solvent shall be inspected for visible

leaks of solvent liquid.

2)

 Pipes,

 hoses and fittings shall be inspected for

active dripping or dampness.

3)

 Pumps and filters shall be inspected for leaks

around seals and access covers.

119—383

148

4)

 Gaskets and seals shall be inspected for wear and

defects.

b)

 Leaks of petroleum solvent liquid and vapors shall be

repaired within three working days of detection, unless

necessary

replacement

parts

are

not

site.

1)

 If necessary, repair parts shall be ordered within

three working days of detection of the leak.

2)

 The leak shall be repaired within three days of

delivery of necessary parts.

Section 218.610

 Testing and Monitoring

a)

 Compliance with Sections 218.607(b) (2), 215.608 and

 215.609 shall be determined by visual inspection; and

b)

 Compliance with Sections 218.607(a) (2) and

 (b) (1)

 shall

be determined by methods described in EPA-450/3-82-009

(1982)

 incorporated by reference in Section 218.112.

c)

 If a control device

 is used to comply with Section

218.607(a) (1), then compliance shall be determined

using 40 CFR 60 Appendix A, Method 25

 (1984)

incorporated by reference in Section 218.112.

Section 218.611

 Exemption for Petroleum Solvent Dry Cleaners

The provisions of Sections 218.607 through 218.610 shall not

apply to petroleum solvent dry cleaning facilities whose

emissions of VON do not exceed 91 megagrams (100 tons)

 per year

in the absence of pollution control equipment or whose emissions

of VON,

 as limited by the operating permit, will not exceed 91

megagrams

 (100 tons)

 per year in the absence of pollution control

equipment.

Section 218.612

 Compliance Dates

Owners and operators of emission sources subject to

35 Ill. Adm.

Code 215.607 through 215.609 as of December 31,

 1987 shall have

complied with the requirements set forth therein no later than

December 31,

 1987.

Section 218.613

 Compliance Plan

a)

 The owner or operator of an emission source subject to

35

 Ill. Adm. Code 215.610(a)

 as of May 31,

 1987 shall

have submitted to the Agency a compliance plan,

 including a project completion schedule where

applicable, no later than May 31,

 1987.

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149

b)

 The plan and schedule shall meet the requirements of

35

Ill. Adm. Code 201.

SUBPART AA:

 PAINT

AND

INK

 MANUFACTURING

Section 218.620

 Applicability

a)

 This subpart shall apply to all paint and ink

manufacturing plants which:

1)

 Include process emission sources not subject to

Subparts B,

E,

 F (excluding Section 218.204(1)), H

excluding Section 218.405),

 Q, R,

5,

V1

X,

 Y or

Z

of this Part; and which as a group both:

A)

 have maximum theoretical emissions of 91 Mg

(100 tons)

 or more per calendar year of VON

if no air pollution control equipment were

used, and

B)

 are not limited to less than 91 Mg (100 tons)

of VON emissions per calendar year in the

absence of air pollution control equipment,

through production or capacity limitations

contained in a federally enforceable

construction permit or a SIP revision,

or

2)

 Produce more than 7,570,820

1

 (2,000,000 gal) per

calendar year of paint or ink formulations, which

contain less than 10 percent (by weight)

 water,

 and ink formulations not containing as the primary

solvents water, Nagie oil or glycol.

b)

 For the purposes of this Subpart, uncontrolled VON

emissions are the emissions of VON which would result

if no air pollution control equipment were used.

Section 218.621

 Exemption for Waterbase Material and

Heatset-Offset Ink

The requirements of Sections 218.624 and 218.625 and Section

218.628(a)

 shall not apply to equipment while it

 is being used to

produce either:

a)

 paint or ink formulations which contain 10 percent or

more (by weight) water,

or

b)

 inks containing Magie oil and glycol as the primary

solvent.

Section 218.623

 Permit Conditions

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150

No person shall violate any condition in a permit when the

condition results in exclusion of the plant or an emission source

from this Subpart.

Section 218.624

 Open-top Mills, Tanks, Vats or Vessels

No person shall operate an open—top mill,

 tank, vat or vessel

with a volume of more than 45

1

 (12 gal) for the production of

paint or ink unless:

a)

 The mill,

 tank, vat or vessel is equipped with a cover

which completely covers the mill,

 tank, vat or vessel

opening except for an opening no larger than necessary

to allow for safe clearance for a mixer shaft.

 Such

cover shall extend at least 1.27 cm

 (0.5 in) beyond the

outer rim of the opening or be attached to the rim.

b)

 The cover remains closed except when production,

sampling, maintenance or inspection procedures require

access.

c)

 The cover

 is maintained in good condition such that,

when in place,

 it maintains contact with the rim of

the

opening for at least 90 percent of the circumference

of

the rim.

Section 218.625

 Grinding Mills

a)

 No person shall operate a grinding mill for the

production of paint or ink which is not maintained in

accordance with the manufacturer’s specifications.

b)

 No person shall operate a grinding mill fabricated or

modified after the effective date of this Subpart

which

is not equipped with fully enclosed screens.

c)

 The manufacturer’s specifications shall be kept on

file

at the plant by the owner or operator of the grinding

mill and be made available to any person upon verbal or

written request during business hours.

Section 218.626

 Storage Tanks

a)

 The owner or operator shall equip tanks storing VOL

with a vapor pressure greater than 10 kPa (1.5 psi)

at

20°C (68°F)with pressure/vacuum conservation vents set

as a minimum at +/—0.2 kPa

 (0.029 psi).

 These controls

shall be operated at all times.

 An alternative air

pollution control system may be used if it results in a

greater emission reduction than these controls.

Any

alternative control system can be allowed only

if

approved by the Agency and approved by the USEPA as

a

119—386

151

SIP revision.

b)

 Stationary VOL storage containers with a capacity

greater than 946

1

 (250 gal)

 shall be equipped with a

submerged-fill pipe or bottom fill.

 These controls

shall be operated at all times.

 An alternative control

system can be allowed only if approved by the Agency

and approved by the USEPA as a SIP revision.

Section 218.628

 Leaks

The owner or operator of a paint or

ink

manufacturing plant

shall,

 for the purpose of detecting leaks,

 conduct an equipment

monitoring program as set forth below:

a)

 Each pump shall be checked by visual inspection each

calendar week for indications of leaks, that is,

liquids dripping from the pump seal.

 If there are

indications of liquids dripping from the pump seal, the

pump shall be repaired as soon as practicable, but no

later than 15 calendar days after the leak is detected.

b)

 Any pump,

 valve, pressure relief valve, sampling

connection,

 open—ended valve and flange or connector

containing a fluid which is at least

 10 percent VON by

weight which appears to be leaking on the basis of

sight,

 smell

sound

shall

repaired

soon

practicable, but no later than 15 ‘calendar days after

the leak is detected.

weather

proof,

readily

visible

tag,

bright

colors

such as red or yellow, bearing an identification number

and the date on which the leak was detected shall be

attached to leaking equipment.

 The tag may be removed

upon repair, that is, when the equipment is adjusted or

otherwise altered to allow operation without leaking.

d)

 When a leak

 is detected, the owner or operator shall

record the date of detection and repair and the record

shall be retained at the plant for at least two years

from the date of each detection or each repair attempt.

The record shall be made available to any person upon

verbal or written request during business hours.

Section 218.630

 Clean Up

a)

 No person shall clean paint or ink manufacturing

equipment with organic solvent unless the equipment

being cleaned is completely covered or enclosed except

for an opening no larger than necessary to allow safe

clearance for proper operation of the cleaning

equipment,

 considering the method and materials being

119—387

152

used.

b)

 No person shall store organic wash solvent in other

than closed containers,

 unless closed containers are

demonstrated to be a safety hazard, or dispose of

organic

wash

solvent

manner

such

that

than

percent by weight is allowed to evaporate into the

atmosphere.

Section 218.636

 Compliance Schedule

Every owner or operator of an emission source subject to the

control requirements of this Subpart shall comply with the

requirements thereof on and after a date consistent with Section

218. 106.

Section 218.637

 Recordkeeping and Reporting

a)

 Upon request by the Agency, the owner or operator of an

emission source which claims to be exempt from the

requirements of this Subpart shall submit records to

the Agency within 30 calendar days from the date of

the

request which document that the emission source

 is in

fact exempt from this Subpart.

 These records shall

include

 (but are not limited to) the percent water

(by

weight)

 in the paint or ink being produced and the

quantity of Magie oil, glycol and other solvents in the

ink being produced.

b)

 Every owner or operator of an emission source which is

 subject to the requirements of this Subpart shall

maintain all records necessary to demonstrate

compliance with those requirements at the facility for

three years.

SUBPART SB:

 POLYSTYRENE PLANTS

Section 218.875

 Applicability of Subpart BB

The provisions of this Subpart shall apply to polystyrene plants:

a)

 Which use continuous processes to manufacture

polystyrene

 polybutadiene co-polymer; and

b)

 Which fall within Standard Industrial Classification

Group No.

 282, Industry No.

 2821, except that the

manufacture of polystyrene resins need not be the

primary manufacturing process at the plant.

Section 218.877

 Emissions Limitation at Polystyrene Plants

No person shall cause or allow the emissions of VON from the

119—388

153

material recovery section to exceed 0.12 kg of Volatile Organic

Material per 1000 kg of polystyrene resin produced.

Section 218.879

 Compliance Date

Every owner and operator of an emission source subject to 35

 Ill.

Adm. Code 215, Subpart BB,

 as of December 31,

 1987,

 shall have

complied with its standards and limitations by December 31,

 1987.

Section 218.881

 Compliance Plan

a)

 The owner or operator of an emission source formerly

subject to the requirements of 35

 Ill. Adm. Code 215

Subpart BB shall have submitted to the Agency

a

compliance plan in accordance with 35 Ill.

 Adin.

 Code

201, Subpart H,

 including a project completion schedule

on or before December

1,

 1987.

b)

 Unless the submitted compliance plan or schedule was

disapproved by the Agency, the owner or operator of a

facility or emission source subject to this Subpart may

operate the emission source according to the plan and

schedule as submitted.

C)

 The plan and schedule shall meet the requirements of

35

Ill.

 Adm. Code 201, Subpart H and Section 218.883.

Section 218.883

 Special Requirements for Compliance Plan

For sources subject to this Subpart, an approvable compliance

plan shall include:

a)

 A description of each process which is subject to an

emissions limitation;

b)

 Quantification of the emissions from each process;

c)

 A description of the procedures and methods used to

determine the emissions of VON;

d)

 A description of the methods which will be used to

demonstrate compliance with the allowable plantwide

emission limitation (Section 215.877),

 including a

method of inventory, recordkeeping and emission

calculation or measurement.

Section 218.886

 Testing and Monitoring

a)

 Upon a reasonable request by the Agency, the owner or

 operator of a polystyrene plant subject to this Subpart

shall at his own expense demonstrate compliance by use

of the following method:

 40 CFR 60, Appendix A, Method

119—389

154

25

—

Determination

Total

Gaseous

Non—Methane

Organic

Emissions as Carbon

 (1984), incorporated by reference

Section

218.112.

person

planning

conduct

VON

emissions

test

demonstrate

compliance

with

this

Subpart

shall

notify

the Agency of that intent not less than 30 days before

the planned initiation of the tests so the Agency may

observe the test.

SUBPART PP:

 MISCELLANEOUS FABRICATED PRODUCT MANUFACTURING PROCESSES

Section 218.920

 Applicability

a)

 The requirements of this Subpart shall apply to a

plant’s miscellaneous fabricated product manufacturing

process emission sources which are not included within

any of the source categories specified in Subparts B,

E,

F,

H,

Q,

R,

5,

V,

X,

 Y or

Z

 if the plant is subject

to this Subpart.

 A plant

 is subject to this Subpart if

 it contains process emission sources, not regulated

by

Subparts B,

E,

F

 (excluding Section 218.204(a)),

H

(excluding Section 218.405),

Q,

R,

S,

V,

X,

 Y or

 Z of

this Part; which as a group both:

1)

 have maximum theoretical emissions of 91 Mg

 (100

tons)

 or more per calendar year of VON if no air

pollution control equipment were used,

and

2)

 are not limited to less than 91 Mg (100 tons)

of

VON emissions per calendar year in the absence of

air pollution control equipment,

 through

production or capacity limitations contained in a

federally enforceable construction permit or a SIP

revision.

b)

 If a plant ceases to fulfill the criteria of subsection

(a), the requirements of this Subpart shall continue to

apply to a miscellaneous fabricated products

manufacturing process emission source which was ever

subject to the control requirements of Section 218.926.

c)

 No limits under this Subpart shall apply to emission

sources with emissions of VOM to the atmosphere less

than or equal to 0.91 Mg (1.0 ton) per calendar year if

the total emissions from such sources not complying

with Section 218.926 does not exceed 4.5 Mg

 (5.0 tons)

per calendar year.

d)

 For the purposes of this Subpart, an emission source

shall be considered regulated by a Subpart if

 it is

119—390

155

subject to the limits of that Subpart.

 An emission

source

 is not considered regulated by a Subpart if its

emissions are below the applicability cutoff level

or

if the source is covered by an exemption.

e)

 For the purposes of this Subpart, uncontrolled VOM

emissions are the emissions of VON which would result

if no air pollution control equipment were used.

Section 218.923

 Permit Conditions

No person shall violate any condition in a permit when the

condition results in exclusion of the plant or an emission source

from this Subpart.

Section 218.926

 Control Requirements

Every owner or operator of an emission source subject to this

Subpart shall comply with the requirements of subsection

 (a),

(b)

or

 (c):

a)

 Emission capture and control techniques which achieve

an overall reduction in uncontrolled VON emissions of

at least 81 percent, or

b)

 For coating lines, the daily-weighted’ average VON

content shall not exceed 0.42 kg VON/l (3.5 lbs

VON/gal)

 of coating as applied

 (minus water and any

compounds which are specifically exempted from the

definition of VON)

 during any day.

 Owners and

operators complying with this Section are not required

to comply with Section 218.301, or

c)

 An alternative control plan which has been approved by

the Agency and approved by the USEPA as

 a SIP revision.

Section 218.927

 Compliance Schedule

Every owner or operator of an emission source subject to the

control requirements of this Subpart shall comply with the

requirements thereof on and after a date consistent with Section

218.106.

Section 218.928

 Testing

Any owner or operator of a VON emission source which is subject

to this Subpart shall demonstrate compliance with Section 218.926

by using the applicable test methods and procedures specified in

Section 218.105.

SUBPART QQ:

 MISCELLANEOUS

FORMULATION

MANUFACTURING

PROCESSES

119—39 1

156

Section 218.940

 Applicability

a)

 The requirements of this Subpart shall apply to a

plant’s miscellaneous formulation manufacturing process

emission sources, which are not included within any of

the source categories specified in Subparts B,

E,

F,

H,

Q,

R,

5,

V,

X,

 Y or

 Z of this Part if the plant is

subject to this Subpart.

 A plant is subject to this

Subpart if it contains process emission sources, not

regulated by Subparts

B,

 E, F (excluding Section

218.204(1)),

(excluding

Section

218.405),

 Y or

 Z of this Part; which as a group both:

have

maximum

theoretical

emissions

(100

tons)

 or more per calendar year of VON if no air

pollution control equipment were used,

and

are

not

limited

less

than

(100

tons)

VOM emissions per calendar year in the absence of

air pollution control equipment,

 through

production or capacity limitations contained in a

federally enforceable construction permit or a SIP

or FIP revision.

b)

 If a plant ceases to fulfill the criteria of subsection

(a), the requirements of this Subpart shall continue to

apply to a miscellaneous formulation manufacturing

process emission source which was ever subject to the

control requirements of Section 218.946.

c)

 No limits under this Subpart shall apply to emission

sources with emissions of VON to the atmosphere less

than or equal to 2.3 Mg (2.5 tons)

 per calendar year if

the total emissions from such sources not complying

with this Section does not exceed 4.5 Mg

 (5.0 tons)

per

calendar year.

d)

 For the purposes of this Subpart, an emission source

 shall be considered regulated by a Subpart if

 it is

subject to the limits of that Subpart.

 An emission

source is not considered regulated by a Subpart if its

emissions are below the applicability cutoff level or

if the source is covered by an exemption.

e)

 For the purposes of this Subpart, uncontrolled VON

emissions are the emissions of VON which would result

if no air pollution control equipment were used.

Section 218.943

 Permit Conditions

No

person shall violate any condition in a permit when the

condition results

 in exclusion of the plant or an emission source

119—392

157

from this Subpart.

Section 218.946

 Control Requirements

Every owner or operator of an emission source subject to this

Subpart shall comply with the requirements of subsection

(a)

or

(b)

 below.

a)

 Emission capture and control techniques which achieve

an overall reduction in uncontrolled VON emissions of

at least 81 percent, or

b)

 An alternative control plan which has been approved by

the Agency and approved by the USEPA as a SIP revision.

Section 218.947

 Compliance Schedule

Every owner or operator of an emission source subject to the

control requirements of this Subpart shall comply with the

requirements thereof on and after a date consistent with Section

 218.106.

Section 218.948

 Testing

Any

owner or operator of a VON emission source which is

 subject

to this Subpart shall demonstrate compliance with Section 218.946

by using the applicable test methods and procedures specified in

Section 218.105.

SUBPART RR:

 MISCELLANEOUS ORGANIC CHEMICAL MANUFACTURING PROCESSES

Section 218.960

 Applicability

a)

 The requirements of this Subpart shall apply to a

plant’s miscellaneous organic chemical manufacturing

process emission sources which are not included within

any of the source categories specified in Subparts B,

E,

F,

H,

Q,

R,

S,

V,

X,

 I or

 Z of this Part,

 if the

plant is subject to this Subpart.

 A plant is subject

to this Subpart if it contains process emission

sources, not regulated by Subparts B,

E,

F

 (excluding

Section 218.204(1)), H (excluding Section 218.405),

Q,

R,

5,

V,

 X, Y or

 of this Part; which as a group both:

1)

 have maximum theoretical emissions of 91 Mg

 (100

tons) or more per calendar year of VON if no air

pollution control equipment were used,

and

2)

 are not limited to less than 91 Mg

 (100 tons)

of

VON emissions per calendar year in the absence of

air pollution control equipment, through

119—393

158

production or capacity limitations contained in a

federally enforceable construction permit or a SIP

revision.

b)

 If a plant ceases to fulfill the criteria of Subsection

(a), the requirements of this Subpart shall continue to

apply to a miscellaneous organic chemical manufacturing

process emission source which was ever subject to the

control requirements of Section 218.966.

c)

 No limits under this Subpart shall apply to emission

sources with emissions of VON to the atmosphere less

than or equal to 0.91 Mg

 (1.0 ton) per calendar year

if

the total emissions from such sources not complying

with Section 218.966 does not exceed 4.5 Mg

 (5.0 tons)

per calendar year.

d)

 For the purposes of this Subpart, an emission source

shall be considered regulated by a Subpart if it

is

subject to the limits of that Subpart.

 An emission

source is not considered regulated by a Subpart

 if its

emissions are below the applicability cutoff level or

if the source

 is covered by an exemption.

e)

 For the purposes of this Subpart, uncontrolled VON

emissions are the emissions of VON which would result

if no air pollution control equipment were used.

Section 218.963

 Permit Conditions

No person shall violate any condition in a permit when the

 condition results

 in exclusion of the plant or an emission source

from this Subpart.

Section 218.966

 Control Requirements

Every owner or operator of an emission source subject to this

Subpart shall comply with the requirements of subsection

(a)

or

(b) below.

a)

 Emission capture and control techniques which achieve

an overall reduction in uncontrolled VOM emissions of

at least 81 percent, or

b)

 An alternative control plan which has been approved by

the Agency and approved by the USEPA as a SIP revision.

Section 218.967

 Compliance Schedule

Every owner or operator of an emission source subject to the

control requirements of this Subpart shall comply with the

requirements of this Subpart on and after a date consistent

with

119—394

159

Section 218.106.

Section 218.968

 Testing

Any owner or operator of a VON emission source which is subject

to this Subpart shall demonstrate compliance with Section 218.966

by using the applicable test methods and procedures specified in

Section 218.105.

SUBPART TT:

 OTHER EMISSION SOURCES

Section 218.980

 Applicability

a)

 The requirements of this Subpart shall apply to a

plant’s VON emission sources, which are not included

within any of the source categories specified in

Subparts B,

E,

F,

H,

Q,

R,

S,

V,

X,

Y,

 Z, AA,

 PP, QQ,

or

 R.R of this Part,

 if the plant is subject to this

Subpart.

 A plant is subject to this Subpart

 if it

contains process emission sources, not regulated by

Subparts B,

E,

 F (excluding Section 218.204(7)), H

(excluding Section 218.405),

Q,

R,

S,

V,

X,

 Y or

 Z of

this Part, which as a group both:

1)

 have maximum theoretical emissions of 91 Mg

 (100

tons)

 or more per calendar year of VON if no air

pollution control equipment were used,

and

2)

 are not limited to less than 91 Mg

 (100 tons)

of

VON emissions per calendar year in the absence of

air pollution control equipment, through

production or capacity limitations contained in

a

federally enforceable construction permit or a SIP

revision.

b)

 If a plant ceases to fulfill the criteria of subsection

(a), the requirements of this Subpart shall continue to

apply to an emission source which was ever subject to

the control requirements of Section 218.986.

C)

 No limits under this Subpart shall apply to emission

sources with emissions of VON to the atmosphere less

than or equal to 2.3 Mg

 (2.5 tons) per calendar year if

 the total emissions from such sources not complying

with Section 218.986 does not exceed 4.5 Mg

 (5.0 tons)

per calendar year.

d)

 For the purposes of this Subpart, an emission source

shall be considered regulated by a Subpart

if

it

is

subject to the limits of that Subpart.

 An emission

source is not considered regulated by a Subpart if

its

emissions are below the applicability cutoff level or

119—395

160

if the source

 is covered by an exemption.

e)

 The control requirements in Subparts QQ,

BR,

 SS and

TT

shall not apply to sewage treatment plants, vegetable

oil processing plants, coke ovens

 (including by-product

recovery plants),

 fuel combustion sources,

 bakeries,

barge loading facilities,

 jet engine test cells,

pharmaceutical manufacturing, production of polystyrene

foam insulation board (including storage and extrusion

of scrap where blowing agent is added to the

polystyrene resin at the plant), production of

polystyrene foam packaging (not including storage and

extrusion of scrap where blowing agent

 is added to the

polystyrene resin at the plant), and iron and steel

production.

Section 218.983

 Permit Conditions

No

person shall violate any condition in a permit when the

 condition results

 in exclusion of the plant or an emission source

from this Subpart.

Section 218.986

 Control Requirements

Every owner or operator of an emission source subject to this

Subpart shall comply with the requirements of subsection

 (a),

(b)

or

 (c) below.

a)

 Emission capture and control equipment which achieve an

overall reduction in uncontrolled VON emissions of at

least 81 percent, or

b)

 For coating lines, the daily-weighted average VOM

content shall not exceed 0.42 kg VON/i

 (3.5 lbs

VON/gal)

 of coating

 (minus water and any compounds

which are specifically exempted from the definition of

VON)

 as applied during any day.

 Owners and operators

complying with this Section are not required to comply

with Section 218.301,

or

c)

 An alternative control plan which has been approved by

the Agency and approved by the USEPA as a SIP revision.

Section 218.987

 Compliance Schedule

Every owner or operator of an emissions source which is subject

to this Subpart shall comply with the requirements of this

Subpart on and after a date consistent with Section 218.106.

Section 218.988

 Testing

Any owner or operator of a VOM emission source which is subject

119—39 6

161

to this Subpart shall demonstrate compliance with Section 218.986

 by using the applicable test methods and procedures specified in

Section 218.105.

SUBPART UU:

 RECORDKEEPING AND REPORTING FOR NON-CTG SOURCES

Section 218.990

 Exempt Emission Sources

Upon request by the Agency, the owner or operator of an emission

source which is exempt from the requirements of Subparts PP,

QQ,

RR, TT or Section2l8.208(b)

 shall submit records to the Agency

within 30 calendar days from the date of the request that

document that the emission source is exempt from those

requirements.

Section 218.991

 Subject Emission Sources

a)

 Any owner or operator of a VON emission source which

is

subject to the requirements of Subpart PP, QQ, RB or

TT

and complying by the use of emission capture and

control equipment shall comply with the following:

1)

 By a date consistent with Section 218.106,

 or upon

initial start—up of a new emission source, the

owner or operator of the subject VON emission

source shall perform all tests and submit to the

Agency the results of all tests and calculations

necessary to demonstrate that the subject emission

source will be in compliance on and after a date

consistent with Section 218.106,

 or on and after

the initial start-up date.

2)

 On and after a date consistent with Section

218.106,

 or on and after the initial start-up

date,

 the owner or operator of a subject

VON

emission source shall collect and record all

of

the following information each day and maintain

the information at the facility for a period of

three years:

A)

 Control device monitoring data.

B)

 A log of operating time for the capture

system, control device, monitoring equipment

and the associated emission source.

C)

 A maintenance log for the capture system,

control device and monitoring equipment

detailing all routine and non—routine

maintenance performed including dates and

duration of any outages.

119—397

162

3)

 On and after a date consistent with Section

218.106, the owner or operator of a subject VON

emission source shall notify the Agency in the

following instances:

A)

 Any record showing a violation of the

requirements of Subpart PP, QQ, RB or TT

shall be reported by sending a copy of such

record to the Agency within 30 days following

the occurrence of the violation.

B)

 At least 30 calendar days before changing the

method of compliance with Subpart PP or TT

from the use of capture systems and control

devices to the use of complying coatings, the

owner or operator shall comply with all

requirements of subsection

 (b) (1).

 Upon

changing the method of compliance with

Subpart PP or TT from the use of capture

 systems and control devices to the use of

complying coatings, the owner or operator

shall comply with all requirements of

subsection

 (b).

b)

 Any owner or operator of a coating line which is

subject to the requirements of Subpart PP or TT and

complying by means of the daily-weighted average VON

content limitation shall comply with the following:

1)

 By a date consistent with Section 218.106,

 or upon

initial start-up of a coating line subject to

Subpart PP or TT, the owner or operator of the

subject coating line shall certify to the Agency

that the coating line will be in compliance on and

after a date consistent with Section 218.106, or

on and after the initial start-up date.

 Such

certification shall include:

A)

 The name and identification number of each

coating line which will comply by means of

the daily-weighted average VON content

limitation.

B)

 The name and identification number of each

coating as applied on each coating line.

C)

 The weight of VON per volume and the volume

of each coating

 (minus water and any

compounds which are specifically exempted

from the definition of VON)

 as applied each

day on each coating line.

119—3 98

163

D)

 The instrument or method by which the owner

or operator will accurately measure or

calculate the volume of each coating as

applied each day on each coating line.

E)

 The method by which the owner or operator

will create and maintain records each day as

required in subsection

 (b) (2).

F)

 An example of the format in which the records

required in subsection

 (b) (2) will be kept.

2)

 On and after

 a date consistent with Section

218.106,

 or on and after the initial start—up

date, the owner or operator of a subject coating

line shall collect and record all of the following

information each day for each coating line and

maintain the information at the facility for a

period of three years:

A)

 The name and identification number of each

coating as applied on each coating line.

B)

 The weight of VOM per volume and the volume

of each coating (minus water and any

compounds which are specifically exempted

from the definition of VON)

 as applied each

day on each coating line.

C)

 The daily-weighted average VOM content of all

coatings as applied on each coating line as

defined in Section 218.104.

3)

 On and after a date consistent with Section

218.106, the owner or operator of a subject

coating line shall notify the Agency in the

following instances:

A)

 Any record showing violation of the

requirements of Subpart PP or TT shall be

reported by sending a copy of such record to

 the Agency and the USEPA within 30 days

following the occurrence of the violation.

B)

 At least 30 calendar days before changing the

method of compliance with Subpart PP or TT

from the use of complying coatings to the use

capture systems and control devices, the

owner or operator shall comply with all

requirements of subsection

 (a) (1).

 Upon

changing the method of compliance with

Subpart PP or TT from the use of complying

119—39

9

164

coatings to the use capture systems and

control devices, the owner or operator shall

comply with all requirements of subsection

(a).

c)

 Any owner or operator of a VON emission source which

is

subject to the requirements of Subpart PP,

 QQ, RB or TT

and complying by means of an alternative control plan

which has been approved by the Agency and approved by

the USEPA as a SIP revision shall comply with the

recordkeeping and reporting requirements specified in

the alternative control plan.

119—4 00

165

APPENDIX A

LIST

CHEMICALS

DEFINING

SYNTHETIC

ORGANIC CHEMICAL AND POLYMER

MANUFACTURING

CAS

No.

a

 Chemical

105—57—7

Acetal

75-07-0

Acetaldehyde

107-89-1

Acetaldol

60-35-5

Acetamide

103-84-4

Acetanilide

64-19-7

Acetic

acid

108-24-7

 Acetic anhydride

67-64-1

Acetone

75-86-5

 Acetone cyanohydrin

75-05-8

Acetonitrile

98-86-2

Acetophenone

75-36-5

 Acetyl chloride

74-86-2

 Acetylene

107—02—8

Acrolein

79-06-1

Acrylamide

79-10-7

Acrylic

acid

&

 esters

107-13-1

Acrylonitrile

124—04-9

Adipic

acid

111-69-3

Adiponitrile

(b)

Alkyl

naphthalenes

107—18—6

Allyl

alcohol

107-05-1

Allyl

chloride

1321-11-5

Aminobenzoic

acid

111-41-1

Aminoethylethanolamine

123-30-8

p—aminophenol

628-63-7,

Amyl

 acetates

123—92—2

7l~4l~Oc

Amyl

alcohols

110—58—7

Amyl

 amine

543-59-9

Amyl

 chloride

llO~68~7c

Amyl

 mercaptans

1322-06—1

Amyl

 phenol

62—53—3

Aniline

142-04-1

Aniline

hydrochloride

29191—52—4

Anisidine

100—66—3

Anisole

118-92-3

Anthranilic

acid

84-65-1

Anthraquinone

100-52-7

Benzaldehyde

55-21-0

Benzamide

71-43-2

Benzene

98-48-6

Benzenedisulfonic

acid

98-11-3

Benzenesulfonic

acid

11 Q_L.fll

166

134—81—6

 Benzil

76-93-7

 Benzilic acid

65-85—0

 Benzoic acid

119—53—9

 Benzoin

100-47-0

Benzonitrile

119-61-9

 Benzophenone

98-07-7

 Benzotrichloride

98-88-4

Benzoyl

chloride

100-51—6

Benzyl

alcohol

100-46-9

 Benzyiamine

120-51-4

 Benzyl benzoate

100-44-7

 Benzyl chloride

98-87-3

Benzyl

dichloride

92—52—4

 Biphenyl

80-05-7

Bisphenol

10-86-1

 Bromobenzene

27497-51-4

 Bromonaphthalene

106-99-0

 Butadiene

106—98—9

 l—butene

123-86-4

 n-butyl acetate

141-32-2

 n-butyl acrylate

71-36-3

 n-butyl alcohol

78-92-2

s-butyl

alcohol

75-65-0

t-butyl

alcohol

109-73-9

 n-butylamine

13952-84-6

 s-butylamine

75-64-9

 t-butylamine

98-73-7

p-tert-butyl

benzoic

acid

107-88-0

 1,3-butylene glycol

123-72-8

 n-butyraldehyde

107-92-6

 Butyric acid

106-31-0

 Butyric anhydride

109-74-0

Butyronitrile

105-60-2

 Caprolactam

75-1-50

Carbon

disulfide

558-13-4

Carbon

tetrabromide

55-23-5

Carbon

tetrachloride

9004-35-7

 Cellulose acetate

79-11-8

Chloroacetic

acid

108-42-9

m—chloroaniline

95-51-2

 o-chloroaniline

106-47-8

 p-chloroaniline

35913-09-8

Chlorobenzaldehyde.

108-90-7

 Chlorobenzene

118-91-2,

Chlorobenzoic

acid

535—80—8,

74—l1—3c

2136-81-4,

 Chlorobenzotrichloride

2136—89—2

5216—25—1

1321-03-5

 Chlorobenzoyl chloride

119—402

167

75-45-6

 Chlorodifluoroethane

25497-29—4

 Chlorodifluoromethane

 67-66-3

 Chloroform

25586-43—0

 Chloronaphthalene

88—73—3

 o—chloronitrobenzene

100-00-5

p-chloronitrobenzene

25167-80—0

 Chlorophenols

126-99-8

 Chloroprene

7790—94-5

 Chlorosulfonic acid

108-41-8

 m—chlorotoluene

95-49-8

 o-chlorotoluene

106-43-4

 p-chlorotoluene

75-72-9

Chlorotrifluoromethane

108—39-4

 m—cresol

95—48—7

 o—cresol

106-44—5

 p—cresol

1319-77-3

 Mixed cresols

1319-77—3

 Cresylic acid

4170-30-0

 Crotonaldehyde

3724-65-0

 Crontonic acid

98-82-8

 Cumene

80-15-9

 Cumene hydroperoxide

372-09-8

 Cyanoacetic acid

506-77-4

 Cyanogen chloride

108-80-5

 Cyanuric acid

108-77-0

 Cyanuric chloride

110-82-7

 Cyclohexane

108-93-0

 Cyclohexanol

108-94-1

 Cyclohexanone

110-83-8

 Cyclohexene

108-91-8

 Cyclohexylamine

111-78-4

 Cyclooctadiene

112-30—1

 Decanol

123-42-2

 Diacetone alcohol

27576-04-1

 Diaminobenzoic acid

95-76-1,

 Dichloroaniline

95—82—9,

554—00—7,

608—27—5,

608—31—1,

626—43—7,

27l34—27—6~

573 11—92—9

541-73-1

 m-dichlorobenzene

95-50-1

 o-dichlorobenzene

106-46-7

 p—dichlorobenzene

75-71-8

 Dichlorodifluoromethane

111-44-4

Dichloroethyl

ether

107-06-2

 l,2-dichloroethane

 (EDC)

96-23-1

Dichlorohydrin

26952-23-8

 Dichloropropene

119—403

168

101-83-7

Dicyclohexylamine

109-89-7

Diethylamine

111-46-6

 Diethylene glycol

112-36-7

 Diethylene glycol diethyl ether

111-96-6

Diethylene

glycol

dimethyl

ether

112-34-5

 Diethylene glycol monobutyl ether

124-17-7

 Diethylene glycol mononbutyl ether

acetate

111-90-0

 Diethylene glycol monoethyl ether

112-15-2

 Diethylene glycol monoethyl ether acetate

111-77-3

 Diethylene glycol monomethyl ether

64-67-5

 Diethyl sulfate

75-37-6

 Difluoroethane

25167-70-8

 Diisobutylene

26761-40-0

 Diisodecyl phthalate

27554-26-3

 Diisooctyl phthalate

674-82-8

 Diketene

124-40-3

 Dimethylamine

121-69-7

 N,N-dimethylaniline

115-10-6

 N,N-dimethyl ether

 68-12-2

 N,N-dimethylformamide

57-14-7

 Dimethylhydrazine

77-78-1

 Dimethyl sulfate

75-18-3

 Dimethyl sulfide

67-68-5

 Dimethyl sulfoxide

120-61-6

 Dimethyl terephthalate

99-34-3

 3,5-dinitrobenzoic acid

51-28-5

 Dinitrophenol

Dinitrotoluene

123-91-1

 Dioxane

646-06-0

 Dioxilane

122-39-4

 Diphenylamine

101-84-4

 Diphenyl oxide

102-08-9

 Diphenyl thiourea

25265-71-8

 Dipropylene glycol

25378-22-7

 Dodecene

28675-17-4

 Dodecylaniline

27193-86-8

 Dodecylphenol

106-89-8

 Epichlorohydrin

64-17-5

 Ethanol

Ethanolamines

141-78-6

 Ethyl acetate

141-97-9

 Ethyl acetoacetate

140-88-5

 Ethyl acrylate

75-04-7

 Ethylamine

100-41-4

 Ethylbenzene

74-96-4

 Ethyl bromide

9004-57-3

 Ethylcellulose

75-00-3

 Ethyl chloride

105-39-5

 Ethyl chloroacetate

105-56-6

 Ethylcyanoacetate

119—404

169

74-85-1

 Ethylene

96-49—1

 Ethylene carbonate

107-07-3

 Ethylene chlorohydrin

107-15-3

 Ethylenediamine

106-93-4

 Ethylene dibromide

107-21—1

 Ethylene glycol

111-55-7

 Ethylene glycol diacetate

110-71-4

 Ethylene glycol dimethyl ether

111-76-2

 Ethylene glycol monobutyl ether

112-07-2

 Ethylene glycol monobutyl ether acetate

110-80-5

 Ethylene glycol monoethyl ether

111-15-9

 Ethylene glycol monoethyl ether acetate

109-86-4

 Ethylene glycol monoethyl ether

110-49-6

 Ethylene glycol monomethyl ether acetate

122-99-6

 Ethylene glycol monophenyl ether

2807-30-9

 Ethylene glycol monopropyl ether

75-21—8

 Ethylene oxide

60-29-7

 Ethyl ether

104-76-7

 2-ethylhexanol

122-51-0

 Ethyl orthoformate

95-92-1

 Ethyl oxalate

41892-71-1

 Ethyl sodium oxaloacetate

50-00-0

 Formaldehyde

75-12-7

 Formamide

64-18-6

 Formic acid

110-17-8

 Fumaric acid

98-01-1

 Furfural

56-81—5

 Glycerol

 (Synthetic)

26545-73-7

 Glycerol dichlorohydrin

25791-96-2

 Glycerol triether

56—40—6

 Glycine

107—22—2

 Glyoxal

118-74-1

 Hexachlorobenzene

67-72-1

 Hexachloroethane

36653-82-4

 Hexadecyl alcohol

 124-09-4

 Hexamethylenediamine

629-11-8

 Hexamethylene glycol

100-97-0

 Hexamethylenetetramine

74-90-8

 Hydrogen cyanide

123-31-9

 Hydroquinone

99-96-7

 p-hydroxybenzoic acid

26760-64—5

 Isoamylene

78-83-1

 Isobutanol

110-19-0

 Isobutyl acetate

115-11-7

 Isobutylene

78-84-2

 Isobutyraldehyde

79-31-2

 Isobutyric acid

25339-17-7

 Isodecanol

26952-21-6

 Isooctyl alcohol

78-78-4

 Isopentane

78-59-1

 Isophorone

121-91-5

 Isophthalic acid

119—405

170

78-79-5

 Isoprene

67-63-0

 Isopropanol

108-21-4

 Isopropyl acetate

75-31-0

 Isopropylamine

75-29-6

 Isopropyl chloride

25168-06-3

 Isopropylphenol

463-51-4

 Ketene

(b)

 Linear alkyl sulfonate*

123-01-3

 Linear alkylbenzene

110-16-7

 Maleic acid

108-31-6

 Maleic anhydride

6915—15—7

 Malic acid

141-79-7

 Mesityl oxide

121-47-1

 Metanilic acid

79-41-4

 Methacrylic acid

563-47-3

 Methallyl chloride

67-56-1

 Methanol

79-20-9

 Methyl acetate

105-45-3

Methyl

acetoacetate

74-89-5

Methylamine

100-61-8

n-methylaniline

74-83-9

Methyl

bromide

37365-71-2

Methyl

butynol

74-87-3

Methyl

chloride

108-87-2

Methyl

cyclohexane

1331-22-2

Methyl

cyclohexanone

75-09-2

 Methylene chloride

101-77-9

 Methylene dianiline

101-68-8

Methylene

diphenyl

diisocyanate

78-93-3

Methyl

ethyl

ketone

107-31-3

Methyl

formate

108-11-2

Methyl

isobutyl

carbinol

108-10-1

Methyl

isobutyl

ketone

80-62-6

Methyl

methacrylate

77-75-8

Methylpentynol

98-83-9

B-methylstyrene

110-91-8

Morpholine

85-47-2

a-naphthalene

sulfonic

acid

120-18-3

B-naphthalene

sulfonic

acid

90-15-3

a—naphthol

135-19-3

 B—naphthol

75-98-9

Neopentanoic

acid

88-74—4

 o-nitroaniline

100-01-6

 p—nitroaniline

91-23—6

 o—nitroanisole

100-17-4

 p—nitroanisole

98-95-3

 Nitrobenzene

Nitrobenzoic acid

(0,

m

&

p)

79-24-3

 Nitroethane

75-52-5

 Nitromethane

88-75-5

 Nitrophenol

119—406

171

25322-01—4

 Nitropropane

1321-12—6

 Nitrotoluene

27215958

‘

 Nonene

25154—52—3

 Nonylphenol

27193-28—8

 Octyiphenol

123—63-7

 Paraldehyde

115-77-5

Pentaerythritol

109—66-0

n-pentane

109-67-1

1-pentene

127-18-4

 Perchloroethylene

594-42-3

 Perchloromethyl mercaptan

94-70-2

o-phenetidine

156-43-4

 p-phenetidine

108—95—2

 Phenol

98-67-9,

 Phenolsulfonic acids

585—38—6,

609—46—1

133_39_76

91-40-7

 Phenyl anthranilic acid

(b)

 Phenylenediamine

75-44-5

Phosgene

85-44-9

 Phthalic anhydride

85—41-6

Phthalimide

108—99—6

b—picoline

110—85—0

Piperazine

9003-29-6,

Polybutenes

25322-68-3

Polyethylene

glycol

25322-69-4

Polypropylene

glycol

123-38-6

Propionaldehyde

79-09-4

 Propionic acid

71-23-8

n-propyl

alcohol

107-10-8

Propylamine

540-54-5

 Propyl chloride

115-07-1

Propylene

127-00-4

Propylene

chlorohydrin

78-87-5

 Propylene dichloride

57-55-6

 Propylene glycol

75-56-9

Propylene

oxide

110—86—1

 Pyridine

106-51-4

 Quinone

108—46—3

 Resorcinol

27138-57-4

 Resorcylic acid

69—72—7

 Salicylic acid

127-09-3

 Sodium acetate

532-32-1

 Sodium benzoate

9004-32-4

 Sodium carboxymethyl cellulose

3926-62-3

 Sodium chloroacetate

141-53-7

 Sodium formate

139-02-6

 Sodium phenate

110-44-1

 Sorbic acid

119—40 7

172

100-42-5

 Styrene

110-15-6

 Succinic acid

110—61—2

 Succinitrile

121—57—3

 Sulfanilic acid

126—33—0

 Sulfolane

1401—55-4

 Tannic acid

100-21-0

 Terephthalic acid

Tetrachloroethanes

117-08-8

 Tetrachlorophthalic anhydride

78-00-2

 Tetraethyllead

119-64-2

 Tetrahydronaphthalene

85-43-8

 Tetrahydrophthalic anhydride

75-74-1

 Tetramethyllead

110-60-1

 Tetramethylenediamine

110-18-9

 Tetramethylethylenediamine

108-88-3

 Toluene

95-80-7

 Toluene-2

4—diamine

584-84-9

 Toluene—2, 4-diisocyanate

26471-62-5

 Toluene diisocyanates

 (mixture)

1333-07-9

 Toluene sulfonamide

lO4~lS~4c

 Toluenesulfonic acids

98-59-9

 Toluene sulfonyl chloride

26915—12—8

 Toluidines

87-61-6,

 Trichlorobenzenes

108—70—3,

l20—82—lc

71-55-6

 1,1,l-trichloroethane

79-00-5

 1,1,2-trichloroethane

79-01-6

 Trichloroethylene

75-69-4

 Trichlorofluoromethane

96-18-4

 1,2,3—trichloropropane

76—13-1

 1,l,2—trichloro—l,2,2—trifluoroethane

121-44-8

 Triethylamine

112-27-6

 Triethylene glycol

112-49-2

 Triethylene glycoldimethyl ether

7756-94-7

 Triisobutylene

75-50-3

 Trimethylamine

57-13-6

 Urea

108-05-4

 Vinyl acetate

75-01-4

 Vinyl chloride

75-35-4

 Vinylidene chloride

25013-15-4

 Vinyl toluene

1330-20-7

 Xylenes

 (mixed)

95-47-6

 o—xylene

106-42-3

 p-xylene

1300—71—6

 Xylenol

1300—73—8

 Xylidine

(b)

 methyl tert-butyl ether

 9002-88-4

 Polyethylene

(b)

 Polypropylene

9009-53-6

 Polystyrene

119—408

173

a) CAS numbers refer to the Chemical Abstracts Registery numbers

assigned to specific chemicals, isomers or mixtures of

chemicals.

 Some isomers or mixtures that are covered by the

standards do not have CAS numbers assigned to them.

The

standards apply to all of the chemicals listed, whether CAS

numbers have been assigned or not.

b) No CAS number(s) have been assigned to this chemical, to its

isomers,

 or mixtures containing these chemicals.

c) CAS numbers for some of the isomers are listed:

 the standards

apply to all of the isomers and mixtures, even if CAS numbers

have not been assigned.

119—409

174

APPENDIX B

VON MEASUREMENT

TECHNIQUES FOR CAPTURE EFFICIENCY

Procedure G.1

 Captured VOC Emissions

1.

 INTRODUCTION

1.1

 Applicability.

 This procedure is applicable

 £or determining

the volatile organic compounds

 (VOC)

 content of captured gas

streams.

 It is intended to be used as a segment in the

development of liquid/gas or gas/gas protocols for determining

VOC capture efficiency

 (CE)

 for surface coating and printing

operations.

 The procedure may not be acceptable in certain

site-specific situations,

 e.g., when:

 (1) direct fired heaters or

other circumstances affect the quantity of VOC at the control

device inlet; and

 (2) particulate organic aerosols are formed in

the process and are present in the captured emissions.

1.2

 Principle.

 The amount of VOC captured

(G)

 is calculated as

the sum of

the

products of the VOC content (C~~),the flow rate

(Q~), and the sample time

 (Ta)

 from each captured emissions

point.

1.3

 Estimated Measurement Uncertainty.

 The measurement

uncertainties are estimated for each captured or fugitive

emissions point as follows:

Q0~

 5.5 percent and

 ±5.0percent.

 Based on these numbers, the probable

uncertainty for G

 is estimated at about ±7~4

 percent.

1.4

 Sampling Requirements.

 A capture efficiency test shall

consist of at least three sampling runs.

 The sampling time for

each run should be at least

 8 hours, unless otherwise approved.

1.5

 Notes.

 Because this procedure is often applied in highly

explosive areas,

 caution and care should be exercised in choosing

appropriate equipment and installing and using the equipment.

Mention of trade names

 or company products does not constitute

endorsement.

 All gas concentrations

 (percent, ppm)

 are by

volume,

 unless otherwise noted.

2.

 APPARATUS AND REAGENTS

2.1

 Gas VOC Concentration.

 A schematic of the measurement

system

 is shown in Figure

1.

 The main components are described

below:

2.1.1

 Sample Probe.

 Stainless steel,

 or equivalent.

 The probe

shall be heated to prevent VOC condensation.

119—410

175

2.1.2

 Calibration Valve Assembly.

 Three—way valve assembly at

the outlet of sample probe to direct the zero and calibration

gases to the analyzer.

 Other methods, such as quick—connect

lines,

 to route calibration gases to the outlet of the sample

probe are acceptable.

2.1.3

 Sample Line.

 Stainless steel or Teflon tubing to

transport the sample gas to the analyzer.

 The sample line must

be heated to prevent condensation.

2.1.4

 Sample Pump.

 A leak-free pump,

 to pull the sample gas

through the system at a flow rate sufficient to minimize the

response time of the measurement system.

 The components of the

pump that contact the gas stream shall be constructed of

stainless steel or Teflon.

 The sample pump must be heated to

 prevent condensation.

2.1.5

 Sample Flow Rate Control.

 A sample flow rate control

valve and rotameter,

 or equivalent,

 to maintain a constant

sampling rate within 10 percent.

 The flow rate control valve and

rotameter must be heated to prevent condensation.

 A control

valve may also be located on the sample pump bypass loop to

assist

 in controlling the sample pressure and flow rate.

2.1.6

 Sample Gas Manifold.

 Capable of diverting a portion of

the sample gas stream to the flame ionization analyzer

 (FIA),

and

the remainder to the bypass discharge vent.

 The manifold

components shall be constructed of stainless steel or Teflon.

If

captured or fugitive emissions are to be measured at multiple

locations,

 the measurement system shall be designed to use

separate sampling probes, lines, and pumps for each measurement

location and a common sample gas manifold and FIA.

 The sample

gas manifold and connecting lines to the FIA must be heated to

prevent condensation.

2.1.7

 Organic Concentration Analyzer.

 An FIA with a span value

of 1.5 times the expected concentration as propane; however,

other span values may be used if it can be demonstrated that they

would provide more accurate measurements.

 The system shall be

capable of meeting or exceeding the following specifications:

2.1.7.1

 Zero Drift.

 Less than ±3.0percent of the span value.

2.1.7.2

 Calibration Drift.

 Less than ±3.0percent of the span

value.

2.1.7.3

 Calibration Error.

 Less than ±5.0percent of the

calibration gas value.

2.1.7.4

 Response Time.

 Less than 30 seconds.

119—4

11

176

2.1.8

 Integrator/Data Acquisition System.

 An analog or digital

device or computerized data acquisition system used to integrate

the FIA response or compute the average response and record

measurement data.

 The minimum data sampling frequency for

computing average or integrated values is one measurement value

every

 5 seconds.

 The device shall be capable of recording

average values at least once per minute.

2.1.9

 Calibration and Other Gases.

 Gases used for calibration,

fuel, and combustion air

 (if required) are contained in

compressed gas cylinders.

 All calibration gases shall be

traceable to NIST standards and shall be certified by the

manufacturer to ±1percent of the tag value.

 Additionally, the

manufacturer of the cylinder should provide a recommended shelf

life for each calibration gas cylinder over which the

concentration does not change more than ±2percent from the

certified value.

 For calibration gas values not generally

available,

 alternative methods for preparing calibration gas

 mixtures, such as dilution systems, may be used with prior

approval.

2.1.9.1

 Fuel.

 A 40 percent H2/60 percent He or 40 percent H2/60

percent N2 gas mixture is recommended to avoid an oxygen

synergism effect that reportedly occurs when oxygen concentration

varies significantly from a mean value.

2.1.9.2

 Carrier Gas.

 High purity air with less than 1 ppm of

organic material

 (as propane or carbon equivalent)

 or less than

0.1 percent of the span value, whichever is greater.

2.1.9.3

 FIA Linearity Calibration Gases.

 Low-, mid—,

and

high—range gas mixture standards with nominal propane

concentrations of 20-30,

 45—55,

 and 70-80 percent of the span

value

 in air, respectively.

 Other calibration values and other

span values may be used if it can be shown that more accurate

measurements would be achieved.

2.1.10

 Particulate Filter.

 An in—stack or an out—of—stack glass

fiber filter is recommended if exhaust gas particulate loading is

significant.

 An out-of-stack filter must be heated to prevent

any condensation unless it can be demonstrated that no

condensation occurs.

2.2

 Captured Emissions Volumetric Flow Rate.

2.2.1

 Method

 2 or 2A Apparatus.

 For determining volumetric flow

rate.

2.2.2

 Method

 3 Apparatus and Reagents.

 For determining

molecular weight of the gas stream.

 An estimate of the molecular

weight of the gas stream may be used if it can be justified.

119—4 12

177

2.2.3

 Method

 4 Apparatus and Reagents.

 For determining moisture

content,

 if necessary.

3.

 DETERMINATION OF VOLUMETRIC FLOW RATE OF CAPTURED EMISSIONS

3.1

 Locate all points where emissions are captured from the

affected facility.

 Using Method

 1, determine the sampling

points.

 Be sure to check each site for cyclonic or swirling

flow.

3.2

 Measure the velocity at each sampling site at least once

every hour during each sampling run using Method

 2 or 2A.

4.

 DETERMINATION OF VOC CONTENT OF CAPTURED EMISSIONS

4.1

 Analysis Duration.

 Measure the VOC responses at each

captured emissions point during the entire test run or,

if

applicable,

 while the process is operating.

 If there are

multiple captured emission locations, design a sampling system to

allow a single FIA to be used to determine the VOC responses at

all sampling locations.

4.2

 Gas VOC Concentration.

4.2.1

 Assemble the sample train as shown in Figure

1.

 Calibrate

the FIA according to the procedure in Section 5.1.

4.2.2

 Conduct a system check according to the procedure in

Section 5.3.

4.2.3

 Install the sample probe so that the probe

 is centrally

located in the stack, pipe,

 or duct,

 and is sealed tightly at

the

stack port connection.

4.2.4

 Inject zero gas at the calibration valve assembly.

 Allow

the measurement system response to reach

 zero.

 Measure the

system response time as the time required for the system to reach

the effluent concentration after the calibration valve has been

returned to the effluent sampling position.

4.2.5

 Conduct a system check before and a system drift check

after each sampling run according to the procedures in Sections

5.2 and 5.3.

 If the drift check following a run indicates

unacceptable performance,

 the run

 is not valid.

 The tester may

elect to perform system drift checks during the run not to exceed

one drift check per hour.

4.2.6

 Verify that the sample lines,

 filter, and pump

temperatures are 120 ±5°C.

11 9—L~i~

178

4.2.7

 Begin sampling at the start of the test period and

continue to sample during the entire run.

 Record the starting

and ending times and any required process information as

appropriate.

 If multiple captured emission locations are sampled

using a single FIA, sample at each location for the same amount

of time

 (e.g.,

 2 minutes)

 and continue to switch from one

location to another for the entire test run.

 Be sure that total

sampling time at each location is the same at the end of the test

run.

 Collect at least

 4 separate measurements from each sample

point during each hour of testing.

 Disregard the measurements at

each sampling location until two times the response time of the

measurement system has elapsed.

 Continue sampling for at least

1

minute and record the concentration measurements.

4.3

 Background Concentration.

4.3.1

 Locate all NDO’s of the TTE.

 A sampling point shall be

centrally located outside of the TTE at

 4 equivalent diameters

from each NDO,

 ifpossible.

 If there are more than

 6 NDO’S,

choose

 6 sampling points evenly spaced among the NDO’s.

4.3.2

 Assemble the sample train as shown in Figure

2.

 Calibrate

the FIA and conduct a system check according to the procedures

in

Sections 5.1 and 5.3.

 NOTE:

 This sample train shall be a

separate sampling train from the one to measure the captured

emissions.

4.3.3

 Position the probe at the sampling location.

4.3.4

 Determine the response time,

 conduct the system check and

sample according to the procedures described in Sections 4.2.4 to

4.2.7.

4.4

 Alternative Procedure.

 The direct interface sampling and

analysis procedure described in Section 7.2 of Method 18 may be

used to determine the gas VOC concentration.

 The system must be

designed to collect and analyze at least one sample every 10

minutes.

5.

 CALIBRATION AND QUALITY ASSURANCE

5.1

 FIA Calibration and Linearity Check.

 Make necessary

adjustments to the air and fuel supplies for the FIA and ignite

the burner.

 Allow the FIA to warm up for the period recommended

by the manufacturer.

 Inject a calibration gas into the

measurement system and adjust the back—pressure regulator to the

value required to achieve the flow rates specified by the

manufacturer.

 Inject the zero— and the high—range calibration

gases and adjust the analyzer calibration to provide the proper

responses.

 Inject the low- and mid—range gases and record the

responses of the measurement system.

 The calibration and

linearity of the system are acceptable if the responses for all

119—4 14

179

four gases are within 5 percent of the respective gas values.

the performance of the system is not acceptable,

 repair or adjust

the system and repeat the linearity check.

 Conduct a calibration

and linearity check after assembling the analysis system and

after a major change is made to the system.

5.2

 Systems Drift Checks.

 Select the calibration gas that most

closely approximates the concentration of the captured emissions

for conducting the drift checks.

 Introduce the zero and

calibration gas at the calibration valve assembly and verify that

the appropriate gas flow rate and pressure are present at the

FIA.

 Record the measurement system responses to the zero and

calibration gases.

 The performance of the system is acceptable

if the difference between the drift check measurement and the

value obtained

 in Section 5.1

 is less than

 3 percent of the span

value.

 Conduct the system drift checks at the end of each run.

5.3

 System Check.

 Inject the high range calibration gas at the

inlet of the sampling probe and record the response.

The

performance of the system is acceptable if the measurement system

response is within 5 percent of the value obtained in Section 5.1

for the high range calibration gas.

 Conduct a system check

before and after each test run.

5.4

 Analysis Audit.

 Immediately before each test analyze an

audit cylinder as described in Section 5.2.

 The analysis audit

must agree with the audit cylinder concentration within 10

percent.

6.

 NOMENCLATURE

A1

 area of NDO

i,

 ft2.

 total area of all NDO’s in the enclosure,

 ft2.

C51

 corrected average VOC concentration of background

emissions at point

 i, ppm propane.

CB

 average background concentration, ppm propane.

 corrected average voc concentration of captured

emissions at point

j,

ppm propane.

 average measured concentration for the drift check

calibration gas, ppm propane.

CDO

 average system drift check concentration for zero

concentration gas, ppm propane.

C5

 actual concentration of the drift check calibration

gas, ppm propane.

119—4 15

180

C~

uncorrected

average

background

VOC

concentration

measured at point

 i, ppm propane.

uncorrected

average

VOC

concentration

 measured at point

j,

ppm propane.

G

 total VOC content of captured emissions,

kg.

K1

 1.830 x

io6

 kg/(m3—ppm).

n

 number of measurement points.

 average effluent volumetric flow rate corrected to

standard conditions at captured emissions point

j,

m3/min.

Te

 total duration of captured emissions sampling run, mm.

7.

 CALCULATIONS

7.1

 Total VOC Captured Emissions.

G

j=1

 (CGj

C3)

~

 Tc K1

Eq.

1

7.2

 VOC Concentration of the Captured Emissions at Point

j.

C0~

(C~

—

 CDO)

C5

Eq.

2

—

7.3

 Background VOC Concentration at Point

i.

C51

(C1

—

 CDO)

C5_

Eq.

3

CDH

—

CDO

7.4

 Average Background Concentration.

S

 C.A.

 —1

CB=

Eq.

nAN

NOTE:

 If the concentration at each point is within 20 percent of

the average concentration of all points, the terms

 “A,” and

may be deleted from Equation 4.

119—4 16

181

Procedure G.2

 Captured VOC Emissions

 (Dilution Technique)

1. INTRODUCTION

1.1

 Applicability.

 This procedure is applicable for determining

the volatile organic compounds

 (VOC)

 content

 of captured gas

streams.

 It is intended to be used as a segment in the

development of a gas/gas protocol in which fugitive emissions are

measured for determining VOC capture efficiency

 (CE)

 for surface

coating and printing operations.

 A dilution system is used to

reduce the VOC concentration of the captured emission to about

the same concentration as the fugitive emissions.

 The procedure

may not be acceptable in certain site-specific situations,

 e.g.,

when:

 (1) direct fired heaters or other circumstances affect the

quantity of VOC at the control device inlet; and

 (2) particulate

organic aerosols are formed in the process and are present in the

captured emissions.

1.2

 Principle.

 The amount of VOC captured

(G)

 is calculated as

the sum of the products of the VOC content

 (CGj)~the flow rate

and the sampling time

 (Ta) from each captured emissions

point.

1.3

 Estimated Measurement Uncertainty.

 The measurement

uncertainties are estimated for each captured or fugitive

emissions point as follows:

Q~

±55 percent and CGj

±5

percent.

 Based on these numbers, the probable uncertainty for G

is estimated at about ±74 percent.

1.4

Sampling

Requirements.

capture

efficiency

test

shall

consist

least

three

sampling

runs.

The

sampling

time

for

each

run

should

least

hours,

unless

otherwise

approved.

1.5

Notes.

Because

this

procedure

often

applied

highly

explosive

areas,

caution

and

care

 should be exercised in choosing

appropriate equipment and installing and using the equipment.

Mention of trade names or company products does not constitute

endorsement.

 All gas concentrations (percent,

 ppm) are by

volume, unless otherwise noted.

2.

 APPARATUS AND REAGENTS

2.1

 Gas VOC Concentration.

 A schematic of the measurement

system is shown in Figure

1.

 The main components are described

below:

2.1.1

 Dilution System.

 A Kipp in-stack dilution probe and

controller or similar device may be used.

 The dilution rate may

be changed by substituting different critical orifices or

119—417

182

adjustments of the aspirator supply pressure.

 The dilution

system shall be heated to prevent VOC condensation.

 Note:

An

out-of-stack dilution device may be used.

2.1.2

 Calibration Valve Assembly.

 Three-way valve assembly at

the outlet of sample probe to direct the zero and calibration

gases to the analyzer. Other methods, such as quick—connect

lines, to route calibration gases to the outlet of the sample

probe are acceptable.

2.1.3

 Sample Line.

 Stainless steel or Teflon tubing to

transport the sample gas to the analyzer.

 The sample line must

be heated to prevent condensation.

2.1.4

 Sample Pump.

 A leak-free pump,

 to pull the sample gas

through the system at a flow rate sufficient to minimize the

response time of the measurement system.

 The components of the

pump that contact the gas stream shall be constructed of

stainless steel or Teflon.

 The sample pump must be heated to

prevent condensation.

2.1.5

 Sample Flow Rate Control.

 A sample flow rate control

valve and rotameter,

 or equivalent, to maintain a constant

sampling rate within 10 percent.

 The flow control valve and

rotameter must be heated to prevent condensation.

 A control

valve may also be located on the sample pump bypass loop to

assist in controlling the sample pressure and flow rate.

2.1.6

 Sample Gas Manifold.

 Capable of diverting a portion of

the sample gas stream to the flame ionization analyzer

 (FIA),

and

the remainder to the bypass discharge vent.

 The manifold

components shall be constructed of stainless steel or Teflon.

If

captured or fugitive emissions are to be measured at multiple

locations, the measurement system shall be designed to use

separate sampling probes,

 lines,

 and pumps for each measurement

location and a common sample gas manifold and FIA.

 The sample

gas manifold and connecting lines to the FIA must be heated to

prevent condensation.

2.1.7

 Organic Concentration Analyzer.

 An FIA with a span value

of 1.5 times the expected concentration as propane; however,

other span values may be used if it can be demonstrated that they

would provide more accurate measurements.

 The system shall be

capable of meeting or exceeding the following specifications:

2.1.7.1

 Zero Drift.

 Less than ±3.0percent of the span value.

2.1.7.2

 Calibration Drift.

 Less than ±3•Qpercent of the span

value.

2.1.7.3

 Calibration Error.

 Less than ±5.0percent of the

119—418

183

calibration gas value.

2.1.7.4

 Response Time.

 Less than 30 seconds.

2.1.8

 Integrator/Data Acquisition System.

 An analog or digital

device or computerized data acquisition system used to integrate

the FIA response or compute the average response and record

 measurement data.

 The minimum data sampling frequency for

computing average or integrated values is one measurement value

every 5 seconds.

 The device shall be capable of recording

average values at least once per minute.

2.1.9

Calibration

and

Other

Gases.

Gases

used

for

calibration,

fuel, and combustion air (if required) are contained in

compressed gas cylinders.

 All calibration gases shall be

traceable to NIST standards and shall be certified by the

manufacturer to ±1percent of the tag value.

 Additionally,

the

manufacturer of the cylinder should provide a recommended shelf

life for each calibration gas cylinder over which the

concentration does not change more than ±2percent from the

certified value.

 For calibration gas values not generally

available,

 alternative methods for preparing calibration gas

mixtures, such as dilution systems, may be used with prior

approval.

2.1.9.1

 Fuel.

 A 40 percent H2/60 percent He or 40 percent H2/60

percent N2 gas mixture is recommended to avoid an oxygen

synergism effect that reportedly occurs when oxygen concentration

varies significantly from a mean value.

2.1.9.2

 Carrier Gas and Dilution Air Supply.

 High purity air

with less than

 1 ppm of organic material

 (as propane or carbon

equivalent)

 or less than 0.1 percent of the span value, whichever

 is greater.

2.1.9.3

 FIA Linearity Calibration Gases.

 Low-,

 mid-, and

high—range gas mixture standards with nominal propane

concentrations of 20-30,

 45—55, and 70—80 percent of the span

value in air, respectively.

 Other calibration values and other

span values may be used if it can be shown that more accurate

measurements would be achieved.

2.1.9.4

 Dilution Check Gas.

 Gas mixture standard containing

propane in air, approximately half the span value after dilution.

2.1.10

 Particulate Filter.

 An in-stack or an out-of-stack glass

fiber filter is recommended if exhaust gas particulate loading is

significant.

An

out-of—stack filter must be heated to prevent any condensation

unless it can be demonstrated that no condensation occurs.

119—419

184

2.2

 Captured Emiásions Volumetric Flow Rate.

2.2.1

 Method

 2 or 2A Apparatus.

 For determining volumetric flow

rate

2.2.2

 Method

 3 Apparatus and Reagents.

 For determining

molecular weight of the gas stream.

 An estimate of the molecular

weight of the gas stream may be used if it can be justified.

2.2.3

 Method

 4 Apparatus and Reagents.

 For determining moisture

content,

 if necessary.

3.

 DETERMINATION OF VOLUMETRIC FLOW RATE OF CAPTURED EMISSIONS

3.1

 Locate all points where emissions are captured from the

affected facility. Using Method 1, determine the sampling points.

Be sure to check each site for cyclonic or swirling flow.

3.2

 Measure the velocity at each sampling site at least once

every hour during each sampling run using Method

 2 or 2A.

DETERMINATION

VOC

CONTENT

CAPTURED

EMISSIONS

4.1

 Analysis Duration.

 Measure the VOC responses at each

captured emissions point during the entire test run or,

if

applicable,

 while the process is operating.

 If there are a

multiple captured emissions locations, design a sampling system

to allow a single FIA to be used to determine the VOC responses

at all sampling locations.

4.2

 Gas VOC Concentration.

4.2.1

 Assemble the sample train as shown in Figure

1.

 Calibrate

the FIA according to the procedure in Section 5.1.

4.2.2

 Set the dilution ratio and determine the dilution factor

according to the procedure in Section 5.3.

4.2.3

 Conduct a system check according to the procedure in

Section 5.4.

4.2.4

 Install the sample probe so that the probe is centrally

located in the stack,

 pipe,

 or duct,

 and is sealed tightly at the

stack port connection.

4.2.5

Inject

zero

gas

the

calibration

valve

assembly.

Measure

the

system

response

time

the

time

required

for

the

system to reach the effluent concentration after the calibration

valve has been returned to the effluent sampling position.

4.2.6

 Conduct a system check before and a system drift check

after each sampling run according to the procedures

 in Sections

119—4 20

185

5.2 and 5.4.

 If the drift check following a run indicates

unacceptable performance, the run is not valid.

 The tester may

elect to perform system drift checks during the run not to exceed

one drift check per hour.

4.2.7

 Verify that the sample lines,

 filter,

 and pump

temperatures are 120 ±

SoC.

4.2.8

 Begin sampling at the start of the test period and

continue to sample during the entire run.

 Record the starting

and ending times and any required process information as

appropriate.

 If multiple captured emission locations are sampled

using a single FIA, sample at each location for the same amount

of time

 (e.g.,

 2 minutes) and continue to switch from one

location to another for the entire test run.

 Be sure that total

sampling time at each location is the same at the end of the test

 run.

 Collect at least

 4 separate measurements from each sample

point during each hour of testing.

 Disregard the measurements at

each sampling location until two times the response time of the

measurement system has elapsed.

 Continue sampling for at least

1

minute and record the concentration measurements.

4.3

 Background Concentration.

4.3.1

 Locate all NDO’s of the TTE.

 A sampling point shall be

centrally located outside of the TTE at

 4 equivalent diameters

from each NDO,

 if possible.

 If there are more than

 6 NDO’s,

choose

 6 sampling points evenly spaced among the NDO’s.

4.3.2

 Assemble the sample train as shown in Figure 2.

 Calibrate

the FIA and conduct a system check according to the procedures

in

Sections 5.1 and 5.4.

4.3.3

 Position the probe at the sampling location.

4.3.4

 Determine the response time,

 conduct the system check and

sample according to the procedures described in Sections 4.2.4

to

4.2.8.

4.4

 Alternative Procedure.

 The direct interface sampling and

analysis procedure described in Section 7.2 of Method 18 may be

used to determine the gas VOC concentration.

 The system must be

designed to collect and analyze at least one sample every 10

minutes.

5.

 CALIBRATION AND QUALITY

ASSURANCE

5.1

 FIA Calibration and Linearity Check.

 Make necessary

adjustments to the air and fuel supplies for the FIA and ignite

the burner.

 Allow the FIA to warm up for the period recommended

by the manufacturer.

 Inject a calibration gas into the

119—42 1

186

measurement system after the dilution system and adjust the back-

pressure regulator to the value required to achieve the flow

rates specified by the manufacturer.

 Inject the zero— and the

high—range calibration gases and adjust the analyzer calibration

to provide the proper responses.

 Inject the low- and mid-range

gases and record the responses of the measurement system.

The

calibration and linearity of the system are acceptable if the

responses for all four gases are within

 5 percent of the

respective gas values.

 If the performance of the system is not

acceptable,

 repair or adjust the system and repeat the linearity

check.

 Conduct a calibration and linearity check after

assembling the analysis system and after a major change is made

to the system.

5.2

 Systems Drift Checks.

 Select the calibration gas that most

closely approximates the concentration of the diluted captured

emissions for conducting the drift checks.

 Introduce the zero

and calibration gas at the calibration valve assembly and verify

 that the appropriate gas flow rate and pressure are present at

the FIA.

 Record the measurement system responses to the zero and

calibration gases.

 The performance of the system is acceptable

if the difference between the drift check measurement and the

value obtained in Section 5.1

 is less than

 3 percent of the span

value.

 Conduct the system drift check at the end of each run.

5.3

 Determination of Dilution Factor.

 Inject the dilution check

gas into the measurement system before the dilution system and

record the response.

 Calculate the dilution factor using

Equation

3.

5.4

 System Check.

 Inject the high range calibration gas at

the

inlet to the sampling probe while the dilution air is turned off.

Record the response.

 The performance of the system is acceptable

if the measurement system response is within

 5 percent of the

value obtained in Section 5.1 for the high range calibration gas.

Conduct a system check before and after each test run.

5.5

 Analysis Audit.

 Immediately before each test analyze an

audit cylinder as described in Section 5.2.

 The analysis audit

must agree with the audit cylinder concentration within

10

percent.

6.

 NOMENCLATURE

A~

 area of NDO i,

 ft2.

AN

 total area of all NDO’S

 in the enclosure,

 ft2.

CA

 actual concentration of the dilution check gas, ppm

propane.

119—422

187

C31

 corrected average VOC concentration of background

emissions at point

 i, ppm propane.

CB

 average background concentration, ppm propane.

CDB

 average measured concentration for the drift check

calibration gas, ppm propane.

CDO

 average system drift check concentration for zero

concentration gas, ppm propane.

C5

 actual concentration of the drift check calibration

gas, ppm propane.

C1

 uncorrected average background VOC concentration

measured at point

 i, ppm propane.

C~

 uncorrected average VOC concentration measured

at

point

j,

ppm propane.

CM

 measured concentration of the dilution check gas,

ppm

propane.

DF

 dilution factor.

G

 total VOC content of captured emissions,

kg.

K1

 1.830

x

io_6

kg/(m3-ppm).

n

 number of measurement points.

 average effluent volumetric flow rate corrected to

standard conditions at captured emissions point

j,

in3/niin.

T0

 total duration of capture efficiency sampling run,

mm.

7.

 CALCULATIONS

7.1

 Total VOC Captured Emissions.

G

~

C0~

~G

 T0 K1

Eq.

1

7.2

 VOC Concentration of the Captured Emissions at Point

j.

C0~

 DF (C~

 C~0)

C5

Eq.

2

CDH

—

CDO

119—423

188

7.3

 Dilution Factor.

 —CA—

Eq.

3

CM

7.4

 Background VOC Concentration at Point

i.

CBI

(C1

—

 CDO)

C5

Eq.

4

CDH

CDO

7.5

 Average Background Concentration.

SC

A.

BJ

C3

Eq.

5

nAN

NOTE:

 If the concentration at each point is within 20 percent of

the average concentration of all points, the terms “A1” and “AN”

may be deleted from Equation 4.

Procedure F.2

 Fugitive VOC Emissions from Building Enclosures

1.

 INTRODUCTION

1.1

 Applicability.

 This procedure is applicable for determining

the fugitive volatile organic compounds

 (VOC)

 emissions from a

building enclosure (BE).

 It is intended to be used as a segment

in the development of liquid/gas or gas/gas protocols for

determining VOC capture efficiency

 (CE)

 for surface coating and

printing operations.

1.2

 Principle.

 The total amount of fugitive VOC emissions

 (FB)

from the BE is calculated as the sum of the products of the

VOC

content

 (CF.)

 of each fugitive emissions point,

 its flow rate

and ~ime

 (TF).

1.3

 Measurement Uncertainty.

 The measurement uncertainties are

estimated for each fugitive emissions point as follows:

±5.0percent and CFj

±5.0percent.

 Based on these numbers,

the

probable uncertainty for FB is estimated at about ±11.2percent.

1.4

 Sampling Requirements.

 A capture efficiency test shall

consist of at least three sampling runs.

 The sampling time for

each run should be at least

 8 hours,

 unless otherwise approved.

1.5

 Notes.

 Because this procedure is often applied in highly

explosive areas, caution and care should be exercised in choosing

appropriate equipment and installing and using the equipment.

119—424

189

Mention of trade names or company products does not constitute

endorsement.

 All gas concentrations (percent,

 ppm) are by

volume, unless otherwise noted.

2.

 APPARATUS AND REAGENTS

2.1

 Gas VOC Concentration.

 A schematic of the measurement

system is shown in Figure

1.

 The main components are described

below:

2.1.1

 Sample Probe.

 Stainless steel,

 or equivalent.

 The probe

shall be heated to prevent VOC condensation.

2.1.2

 Calibration Valve Assembly.

 Three—way valve assembly at

the outlet of sample probe to direct the zero and calibration

gases to the analyzer.

 Other methods, such as quick—connect

lines, to route calibration gases to the outlet of the sample

probe are acceptable.

2.1.3

 Sample Line.

 Stainless steel or Teflon tubing to

transport the sample gas to the analyzer.

 The sample line must

be heated to prevent condensation.

2.1.4

 Sample Pump.

 A leak-free pump, to pull the sample gas

through the system at a flow rate sufficient to minimize the

response time of the measurement system.

 The components of the

pump that contact the gas streamshall be constructed of stainless

steel or Teflon.

 The sample pump must be heated to prevent

condensation.

2.1.5

 Sample Flow Rate Control.

 A sample flow rate control

valve and rotameter,

 or equivalent, to maintain a constant

sampling rate within 10 percent.

 The flow rate control valve and

rotameter must be heated to prevent condensation.

 A control

valve may also be located on the sample pump bypass loop to

assist in controlling the sample pressure and flow rate.

2.1.6

 Sample Gas Manifold.

 Capable of diverting a portion of

the sample gas stream to the flame ionization analyzer (FIA),

and

the remainder to the bypass discharge vent.

 The manifold

components shall be constructed of stainless steel or Teflon.

If

emissions are to be measured at multiple locations,

the

measurement system shall be designed to use separate sampling

probes,

 lines, and pumps for each measurement location and a

common sample gas manifold and FIA.

 The sample gas manifold must

be heated to prevent condensation.

2.1.7

 Organic Concentration Analyzer.

 An FIA with a span value

of 1.5 times the expected concentration as propane; however,

 other span values may be used if it can be demonstrated that they

would provide more accurate measurements.

 The system shall be

capable of meeting or exceeding the following specifications:

119—425

190

2.1.7.1

 Zero Drift.

 Less than ±3.0percent of the span value.

2.1.7.2

 Calibration Drift.

 Less than ±3.0percent of the span

value.

2.1.7.3

 Calibration Error.

 Less than ±5.0percent of the

calibration gas value.

2.1.7.4

 Response Time.

 Less than 30 seconds.

2.1.8

 Integrator/Data Acquisition System.

 An analog or digital

device or computerized data acquisition system used to integrate

the FIA response or compute the average response and record

measurement data.

 The minimum data sampling frequency for

computing average or integrated values is one measurement value

every

 5 seconds.

 The device shall be capable of recording

average values at least once per minute.

2.1.9

 Calibration and Other Gases.

 Gases used for calibration,

fuel, and combustion air

 (if required) are contained in

compressed gas cylinders.

 All calibration gases shall be

traceable to NIST standards and shall be certified by the

manufacturer to ±1percent of the tag value.

 Additionally, the

manufacturer of the cylinder should provide a recommended shelf

life

for

each

calibration

gas

cylinder

over

which

the

concentration

does

not

change

than

±2percent

from

the

certified

value.

For

calibration

gas

values

not

generally

available,

alternative

methods

for

preparing

calibration

gas

mixtures,

such

dilution

systems,

may

used

with

prior

approval.

2.1.9.1

Fuel.

percent

H2/60

percent

H2/60

percent

gas

mixture

recommended

avoid

oxygen

synergism

effect

that

reportedly

occurs

when

oxygen

concentration

varies significantly from a mean value.

2.1.9.2

 Carrier Gas.

 High purity air with less than 1 ppm of

organic material

 (propane or carbon equivalent)

 or less than 0.1

percent of the span value, whichever is greater.

2.1.9.3

 FIA Linearity Calibration Gases.

 Low-,

 mid-,

and

high—range gas mixture standards with nominal propane

 concentrations of 20-30,

 45—55, and 70—80 percent of the span

value in air, respectively.

 Other calibration values and other

span values may be used if it can be shown that more accurate

measurements would be achieved.

2.1.10

 Particulate Filter.

 An in-stack or an out-of-stack glass

fiber filter is recommended if exhaust gas particulate loading is

significant.

 An out-of-stack filter must be heated to prevent

119— 42 6

191

any condensation unless it can be demonstrated that no

condensation occurs.

2.2

 Fugitive Emissions Volumetric Flow Rate.

2.2.1

 Flow Direction Indicators.

 Any means of indicating inward

or outward flow,

 such as light plastic film or paper streamers,

smoke tubes,

 filaments,

 and sensory perception.

2.2.2

 Method

 2 or 2A Apparatus.

 For determining volumetric

flow

rate.

 Anemometers or similar devices calibrated according to the

manufacturer’s instructions may be used when low velocities are

present.

 Vane anemometers

 (Young—maximum response propeller),

specialized pitots with electronic manometers

 (e.g., Shortridge

Instruments Inc., Airdata Multimeter 860) are commercially

available with measurement thresholds of

 15 and 8 mpm

 (50 and

25 fpm), respectively.

2.2.3

 Method

 3 Apparatus and Reagents.

 For determining

molecular weight of the gas stream.

 An estimate of the molecular

weight of the gas stream may be used if it can be justified.

2.2.4

 Method

 4 Apparatus and Reagents.

 For determining moisture

content,

 if necessary.

3.

 DETERMINATION OF VOLUMETRIC FLOW RATE OF FUGITIVE EMISSIONS

3.1

 Preliminary Determinations.

 The purpose of this exercise

is

to determine which exhaust points should be measured for

volumetric flow rates and VOC concentrations.

3.1.1

 Forced Draft Openings.

 Identify all forced draft

openings.

 Determine the volumetric flow rate according to Method

2.

3.1.2

 NDO’s Exhaust Points.

 The NDO’s in the roof of

 a facility

are considered to be exhaust points.

 Determine volumetric flow

rate from these NDO’s.

 Divide the cross—sectional area according

to Method

 1 using

 12 equal areas.

 Use the appropriate velocity

measurement devices,

 e.g., propeller anemometers.

3.1.3

 Other NDO’s.

3.1.3.1

 This step is optional.

 Determine the exhaust flow rate,

including that of the control device, from the enclosure and the

intake air flow rate.

 If the exhaust flow rate divided by the

intake air flow rate is greater than 1.1, then all other IWO’s

are not considered to be significant exhaust points.

3.1.3.2

 If the option above is not taken, identify all other

NDO’s and other potential points through which fugitive emissions

may escape the enclosure.

119—42 7

192

Then use the following criteria to determine whether flow rates

and VOC concentrations need to be measured:

3.1.3.2.1

 Using the appropriate flow direction indicator,

determine the flow direction.

 An NDO with zero or inward flow is

not an exhaust point.

3.1.3.2.2

 Measure the outward volumetric flow rate from the

remainder of the NDO’s.

 If the collective flow rate is

2

percent, or less, of the flow rate from Sections 3.1.1 and 3.1.2,

then these NDO’s, except those within two equivalent diameters

(based on NDO opening)

 from VOC sources, may be considered to be

non-exhaust points.

3.1.3.2.3

 If the percentage calculated in Section 3.1.3.2.2

is

greater than 2 percent, those NDO’s

 (except those within

two

equivalent diameters from VOC sources) whose volumetric flow rate

total

 2 percent of the flow rate from Sections 3.1.1 and 3.1.2

may be considered as non—exhaust points.

 All remaining NDO’s

shall be measured for volumetric flow rate and VOC concentrations

during the CE test.

3.1.3.2.4

 The tester may choose to measure VOC concentrations at

the forced exhaust points and the NDO’s.

 If the total VOC

emissions from the NDO’s are less than

 2 percent of the emissions

from the forced draft and roof NDO’s, then these NDO’s may be

eliminated from further consideration.

3.2

 Determination of Flow Rates.

3.2.1

 Measure the volumetric flow rate at all locations

identified as exhaust points in Section 3.1.

 Divide each exhaust

opening into

 9 equal areas for rectangular openings and 8 for

circular openings.

3.2.2

 Measure the velocity at each site at least once every hour

during each sampling run using Method

 2 or

2A,

 if applicable,

or

using the low velocity instruments in Section 2.2.2.

4.

 DETERMINATION OF VOC CONTENT OF FUGITIVE EMISSIONS

4.1

 Analysis Duration.

 Measure the VOC responses at each

fugitive emission point during the entire test run or,

if

applicable, while the process is operating.

 If there are

multiple emissions locations,

 design a sampling system to

allow

single FIA to be used to determine the VOC responses at all

sampling locations.

4.2

Gas

VOC

Concentration.

4.2.1

Assemble

the

sample

train

shown

Figure

Calibrate

the

FIA

and

conduct

system

check

according

the

procedures

119—42 8

193

Sections 5.1 and 5.3, respectively.

4.2.2

 Install the sample probe so that the probe is centrally

located in the stack, pipe,

 or duct, and is sealed tightly at the

stack port connection.

4.2.3

 Inject zero gas at the calibration valve assembly.

 Allow

the measurement system response to reach zero.

 Measure the

system response time as the time required for the system to reach

the effluent concentration after the calibration valve has been

returned to the effluent sampling position.

4.2.4

 Conduct a system check before and a system drift check

after each sampling run according to the procedures in Sections

5.2 and 5.3.

 If the drift check following a run indicates

unacceptable performance, the run is not valid.

 The tester may

elect to perform drift checks during the run not to exceed one

drift check per hour.

4.2.5

 Verify that the sample lines,

 filter, and pump

temperatures are 120

±50C.

4.2.6

 Begin sampling at the start of the test period and

continue to sample during the entire run.

 Record the starting

and ending times and any required process information as

appropriate.

 If multiple emission locations are sampled using a

single FIA, sample at each location for the same amount of time

 (e.g.,

 2 minutes)

 and continue to switch from one location to

another for the entire test run.

 Be sure that total sampling

time at each location

 is the same at the end of the test run.

Collect at least

 4 separate measurements from each sample point

during each hour of testing.

 Disregard the response measurements

at each sampling location until two times the response time of

the measurement system has elapsed.

 Continue sampling for at

least

 1 minute and record the concentration measurements.

4.3

 Alternative Procedure

 The direct interface sampling and

analysis procedure described in Section 7.2 of Method 18 may be

used to determine the gas VOC concentration.

 The system must be

designed to collect and analyze at least one sample every 10

minutes.

 CALIBRATION

AND

QUALITY

ASSURANCE

5.1

 FIA Calibration and Linearity Check.

 Make necessary

adjustments to the air and fuel supplies for the FIA and ignite

the burner.

 Allow the FIA to warm up for the period recommended

by the manufacturer.

 Inject a calibration gas into the

measurement system and adjust the back—pressure regulator to the

value required to achieve the flow rates specified by the

manufacturer.

 Inject the zero— and the high—range calibration

119—429

194

gases and adjust the analyzer calibration to provide the proper

responses.

 Inject the low— and mid—range gases and record the

responses of the measurement system.

 The calibration and

linearity of the system are acceptable

 if the responses for all

four gases are within 5 percent of the respective gas values.

If

the performance of the system is not acceptable,

 repair or adjust

the system and repeat the linearity check.

 Conduct a calibration

and linearity check after assembling the analysis system and

after a major change is made to the system.

5.2

 Systems Drift Checks.

 Select the calibration gas that most

closely approximates the concentration of the captured emissions

for conducting the drift checks.

 Introduce the zero and

calibration gas at the calibration valve assembly and verify that

the appropriate gas flow rate and pressure are present at the

FIA.

 Record the measurement system responses to the zero and

calibration gases.

 The performance of the system is acceptable

if the difference between the drift check measurement and the

value obtained in Section 5.1 is less than 3 percent of the span

value.

 Conduct a system drift check at the end of each run.

5.3

 System Check.

 Inject the high range calibration gas at the

inlet of the sampling probe and record the response.

The

performance of the system is acceptable if the measurement system

 response is within

 5 percent of the value obtained in Section

5.1

for the high range calibration gas.

 Conduct a system check

before each test run.

5.4

 Analysis Audit.

 Immediately before each test analyze an

audit cylinder as described in Section 5.2.

 The analysis audit

must agree with the audit cylinder concentration within 10

percent.

6.

 NOMENCLATURE

 average measured concentration for the drift check

calibration gas, ppm propane.

CDO

 average system drift check concentration for zero

concentration gas, ppm propane.

 corrected average VOC concentration of fugitive

emissions at point

j,

ppm propane.

C5

 actual concentration of the drift check calibration

gas, ppm propane.

C~

 uncorrected average VOC concentration measured at point

j,

ppm propane.

FB

 total VOC content of fugitive emissions from the

119—430

195

building, kg.

K1

 1.830 x

io6

 kg/(m3—ppm).

n

 number of measurement points.

 average effluent volumetric flow rate corrected to

 standard conditions at fugitive emissions point

j,

m3/min.

TF

 total duration of capture efficiency sampling run, mm.

7.

 CALCULATIONS

7.1

 Total VOC Fugitive Emissions From the Building.

FB

j=1

CFj

~

TF

K1 Eq.

1

7.2

 VOC Concentration of the Fugitive Emissions at Point

j.

CFj

(C~

 CDO)

C5

Eq.

2

—

CDO

Procedure F.1

—

 Fugitive VOC Emissions from Temporary Enclosures

1.

 INTRODUCTION

1.1

 Applicability.

 This procedure is applicable for determining

the fugitive volatile organic compounds (VOC)

 emissions from a

temporary total enclosure (TTE).

It

 is intended to be used as a

segment in the development of liquid/gas or gas/gas protocols for

determining VOC capture efficiency

 (CE) for surface coating and

printing operations.

1.2

 Principle.

 The amount of fugitive VOC emissions

(F)

 from

the TTE is calculated as the sum of the products of the VOC

content

 (CF.),

 the flow rate (Q~),and the sampling time

 (TF)

from each f~igitiveemissions point.

1.3

 Estimated Measurement Uncertainty.

 The measurement

uncertainties are estimated for each fugitive emission point as

follows:

 ~5.5 percent and CF~

 ±5.0percent.

 Based on

these numbers, the probable uncertainty for F is estimated at

about ±7~4percent.

1.4

 Sampling Requirements.

 A capture efficiency test shall

consist of at least three sampling runs.

 The sampling time for

119—43 1

196

each run should be at least

 8 hours, unless otherwise approved.

1.5

 Notes.

 Because this procedure is often applied in highly

explosive areas,

 caution and care should be exercised in choosing

appropriate equipment and installing and using the equipment.

Mention of trade names or company products does not constitute

endorsement.

 All gas concentrations (percent, ppm) are by

volume, unless otherwise noted.

2.

 APPARATUS AND REAGENTS

2.1

 Gas VOC Concentration.

 A schematic of the measurement

system is shown in Figure

1.

 The main components are described

below:

2.1.1

 Sample Probe.

 Stainless steel,

 or equivalent.

 The probe

shall be heated to prevent VOC condensation.

2.1.2

 Calibration Valve Assembly.

 Three-way valve assembly at

the outlet of sample probe to direct the zero and calibration

 gases to the analyzer.

 Other methods, such as quick—connect

lines, to route calibration gases to the outlet of the sample

probe are acceptable.

2.1.3

 Sample Line.

 Stainless steel or Teflon tubing to

transport the sample gas to the analyzer.

 The sample line must

be heated to prevent condensation.

2.1.4

 Sample Pump.

 A leak-free pump,

 to pull the sample gas

through the system at a flow rate sufficient to minimize the

response time of themeasurement system.

 The components of the

pump that contact the gas stream shall be constructed of

stainless steel or Teflon.

 The sample pump must be heated to

prevent condensation.

2.1.5

 Sample Flow Rate Control.

 A sample flow rate control

valve and rotameter,

 or equivalent,

 to maintain a constant

sampling rate within 10 percent.

 The flow control valve and

rotameter must be heated to prevent condensation.

 A control

valve may also be located on the sample pump bypass 1oop to

assist in controlling the sample pressure and flow rate.

2.1.6

 Sample Gas Manifold.

 Capable of diverting a portion of

the sample gas stream to the flame ionization analyzer

 (FIA),

and

the remainder to the bypass discharge vent.

 The manifold

components shall be constructed of stainless steel or Teflon.

If

emissions are to be measured at multiple locations, the

measurement system shall be designed to use separate sampling

 probes,

 lines, and pumps for each measurement location and a

common sample gas manifold and FIA.

 The sample gas manifold and

connecting lines to the FIA must be heated to prevent

condensation.

119—432

197

2.1.7

 Organic Concentration Analyzer.

 An FIA with a span value

of 1.5 times the expected concentration as propane; however,

other span values may be used if

 it can be demonstrated that they

would provide more accurate measurements.

 The system shall be

capable of meeting or exceeding the following specifications:

2.1.7.1

 Zero Drift.

 Less than ±3.0percent of the span value.

2.1.7.2

 Calibration Drift.

 Less than ±3.0percent of the span

value.

2.1.7.3

 Calibration Error.

 Less than ±50percent of the

calibration gas value.

2.1.7.4

 Response Time.

 Less than 30 seconds.

2.1.8

 Integrator/Data Acquisition System.

 An analog or digital

device or computerized data acquisition system used to integrate

the FIA response or compute the average response and record

measurement data.

 The minimum data sampling frequency for

computing average or integrated values is one measurement value

every

 5 seconds.

 The device shall be capable of recording

average values at least once per minute.

2.1.9

Calibration

and

Other

Gases.

Gases

used

for

calibration,

fuel,

and

combustion

air

(if

required)

are

contained

compressed gas cylinders.

 All calibration gases shall be

traceable to NIST standards and shall be certified by the

manufacturer to ±1percent of the tag value.

 Additionally, the

manufacturer

the

cylinder

should

provide

recommended

shelf

life

for

each

calibration

gas

cylinder

over

which

the

concentration

does

not

change

than

±2 percent

from

the

certified

value.

For

calibration

gas

values

notgenerally

available,

 alternative methods for preparing calibration gas

mixtures,

such

dilution

systems,

may

used

with

prior

approval.

2.1.9.1

Fuel.

percent

H2/60

percent

H2/60

percent

gas

mixture

recommended

avoid

oxygen

synergism effect that reportedly occurs when oxygen concentration

varies significantly from a mean value.

2.1.9.2

 Carrier Gas.

 High purity air with less than

 1 ppm of

organic material

 (as propane or carbon equivalent)

 or less than

0.1 percent of the span value, whichever is greater.

2.1.9.3

 FIA Linearity Calibration Gases.

 Low-,

 mid-, and

high—range gas mixture standards with nominal propane

concentrations of 20-30,

 45—55,

 and 70—80 percent of the span

value

 in air, respectively.

 Other calibration values and other

119—433

198

span values may be used if it can be shown that more accurate

measurements would be achieved.

2.1.10

 Particulate Filter.

 An in-stack or an out—of-stack glass

fiber filter is recommended if exhaust gas particulate loading is

significant.

 An out-of-stack filter must be heated to prevent

any condensation unless it can be demonstrated that no

condensation occurs.

2.2

 Fugitive Emissions Volumetric Flow Rate.

2.2.1

 Method

 2 or 2A Apparatus.

 For determining volumetric flow

rate.

2.2.2

 Method

 3 Apparatus and Reagents.

 For determining

molecular weight of the gas stream.

 An estimate of the molecular

weight of the gas stream may be used if it can be justified.

2.2.3

 Method

 4 Apparatus and Reagents.

 For determining moisture

content,

 if necessary.

2.3

 Temporary Total Enclosure.

 The criteria for designing a TTE

are discussed in Procedure T.

3.

 DETERMINATION OF VOLUMETRIC FLOW RATE OF FUGITIVE EMISSIONS

3.1

 Locate all points where emissions are exhausted from the

TTE.

 Using Method

 1, determine the sampling points.

 Be sure to

check each site for cyclonic or swirling flow.

3.2

 Measure the velocity at each sampling site at least once

every hour during each sampling run using Method

 2 or 2A.

4.

 DETERMINATION OF VOC CONTENT OF FUGITIVE EMISSIONS

4.1

 Analysis Duration.

 Measure the VOC responses at each

fugitive emission point during the entire test run or,

if

applicable,

while

the

process

operating.

there

are

multiple emission locations, design a sampling system to allow a

single FIA to be used to determine the VOC responses at all

sampling locations.

4.2

 Gas VOC Concentration.

4.2.1

 Assemble the sample train as shown in Figure

1.

 Calibrate

the FIA and conduct a system check according to the procedures in

Sections

5.1

and

5.3,

respectively.

4.2.2

 Install the sample probe so that the probe is centrally

located in the stack, pipe,

 or duct,

 and is sealed tightly at the

stack port connection.

119—4 34

199

4.2.3

Inject

zero

gas

the

calibration

valve

assembly.

Allow

the

measurement

system

response

reach

zero.

Measure

the

system

response

time

the

time

required

for

the

system

reach

the

effluent

concentration

after

the

calibration

valve

has

been

returned

the

effluent

sampling

position.

4.2.4

Conduct

system

check

before

and

system

drift

check

after

each

sampling

run

according

the

procedures

Sections

5.2

and

5.3.

the

drift

check

following

run

indicates

unacceptable

performance,

the

run

not

valid.

The

tester

may

elect

perform

system

drift

checks

during

the

run

not

exceed

one

drift

check

per

hour.

4.2.5

Verify

that

the

sample

lines,

filter,

and

pump

temperatures

are

120 ±

SoC.

4.2.6

Begin

sampling

the

start

the

test

period

and

continue

sample

during

the

entire

run.

Record

the

starting

and

ending

times

and

any

required

process

information

appropriate.

multiple

emission

locations

are

sampled

using

single

FIA,

sample

each

location

for

the

same

amount

time

(e.g.,

minutes)

and

continue

switch

from

one

location

another

for

the

entire

test

run.

sure

that

total

sampling

time

each

location

the

same

the

end

the

test

run.

Collect

least

separate

measurements

from

each

sample

point

during

each

hour

testing.

Disregard

the

response

measurements

each

sampling

location

until

two

times

the

response

time

the

measurement

system

has

elapsed.

Continue

sampling

for

least

minute

and

record

the

concentration

measurements.

4.3

Background

Concentration.

4.3.1

 Determination of VOC Background Concentration.

4.3.1.1

 Locate all NDO’s of the TTE.

 A sampling point shall be

centrally located outside of the TTE at

 4 equivalent diameters

from each NDO,

 if possible.

 If there

 are. more than 6 NDO’s,

choose

 6 sampling points evenly spaced among the NDO’s.

4.3.1.2

 Assemble the sample train as shown in Figure 2.

Calibrate the FIA and conduct a system check according to the

procedures in Sections 5.1 and 5.3.

4.3.1.3

 Position the probe at the sampling location.

4.3.1.4

 Determine the response time, conduct the system check

and sample according to the procedures described in Sections

4.2.3 to 4.2.6.

4.4

 Alternative Procedure.

 The direct interface sampling and

analysis procedure described in Section 7.2 of Method 18 may be

used to determine the gas VOC concentration.

 The system must be

119—435

200

designed to collect and analyze at least one sample every 10

minutes.

CALIBRATION

AND

QUALITY

ASSURANCE

5.1

FIA

Calibration

and

Linearity

Check.

Make

necessary

adjustments

the

air

and

fuel

supplies

for

the

FIA

and

ignite

the

burner.

Allow

the

FIA

warm

for

the

period

recommended

the

manufacturer.

Inject

calibration

gas

into

the

measurement

system

and

adjust

the

back—pressure

regulator

the

value

required

achieve

the

flow

rates

specified

the

manufacturer.

Inject

the

zero—

and

the

high—range

calibration

gases

and

adjust

the

analyzer

calibration

provide

the

proper

responses.

Inject

the

low—

and

mid—range

gases

and

record

the

responses

the

measurement

system.

The

calibration

and

linearity

the

system

are

acceptable

the

responses

for

all

four

gases

are

within

percent

the

respective

gas

values.

the

performance

the

system

not

acceptable,

repair

adjust

the

system

and

repeat

the

linearity

check.

Conduct

calibration

and

linearity

check

after

assembling

the

analysis

system

and

after

major

change

made

the

system.

5.2

Systems

Drift

Checks.

Select

the

calibration

gas

concentration

that

most

closely

approximates

that

the

fugitive

gas

emissions

conduct

the

drift

checks.

Introduce

the

zero

and

calibration

gas

the

calibration

valve

assembly

and

verify

that

the

appropriate

gas

flow

rate

and

pressure

are

present

the

FIA.

Record

the

measurement

system

responses

the

zero

and

calibration

gases.

The

performance

the

system

acceptable

the

difference

between

the

drift

check

measurement

and

the

value

obtained

Section

5.1

less

than

percent

the

span

value.

Conduct

system

drift

check

the

end

each

run.

5.3

System

Check.

Inject

the

high

range

calibration

gas

the

inlet

the

sampling

probe

and

record

the

response.

The

performance

the

system

acceptable

the

measurement

system

response

within

percent

the

value

obtained

Section

5.1

for

the

high

range

calibration

gas.

Conduct

system

check

before

each

test

run.

5.4

Analysis

Audit.

Immediately

before

each

test

analyze

audit cylinder as described in Section 5.2.

 The analysis audit

must agree with the audit cylinder concentration within 10

percent.

6.

 NOMENCLATURE

A1

 area of NDO i,

 ft2.

 total area of all NDO’s in the enclosure,

 ft2.

119—436

201

CBI

 corrected average VOC concentration of background

emissions at point

 i, ppm propane.

C3

 average background concentration, ppm propane.

CDH

average

measured

concentration

for

the

drift

check

calibration gas, ppm propane.

CDO

 average system drift check concentration for zero

concentration gas, ppm propane.

CFj

 corrected average VOC concentration of fugitive

emissions at point

j,

ppm propane.

C5

 actual concentration of the drift check calibration

gas, ppm propane.

C1

 uncorrected average background VOC concentration at

point

 i, ppm propane.

C~

 uncorrected average VOC concentration measured at point

j,

ppm propane..

F

 total VOC content of fugitive emissions,

kg.

K1

 1.830 x 106 kg/(m3—ppm).

n

 number of measurement points.

 average effluent volumetric flow rate corrected to

 standard conditions at fugitive emissions point

j,

m3/min.

TF

 total duration of fugitive emissions sampling run, mm.

7.

 CALCULATIONS

7.1

 Total VOC Fugitive Emissions.

F

=1

 (CFj

—

 C3) Q~ TF K1

Eq.

1

7.2

 VOC Concentration of the Fugitive Emissions at Point

j.

CFj

(C~

 CDO)

 C5____

Eq.

2

C0~

—

CDO

119—437

202

7.3

 Background VOC Concentration at Point

i.

C31

(C1

—

 CDO)

C~

Eq.

3

CDH

—

CDO

7.4

 Average Background Concentration.

S

 C.A.

Bi.

CB

Eq.

~

nAN

NOTE:

 If the concentration at each point is within 20 percent of

the average concentration of all points, the terms

 “Ar” and

 “AN”

may be deleted from Equation 4.

Procedure L

 VOC Input

1.

 INTRODUCTION

1.1

 Applicability.

 This procedure is applicable for determining

the input of volatile organic compounds

 (VOC).

 It is intended to

be used as a segment in the development of liquid/gas protocols

for determining VOC capture efficiency

 (CE)

 for surface coating

and printing operations.

1.2

 Principle.

 The amount of VOC introduced to the process

(L)

is the sum of the products of the weight

(W)

 of each VOC

containing liquid

 (ink, paint,

 solvent, etc.) used and its VOC

content

 (V).

 A sample of each VOC containing liquid is analyzed

with a flame ionization analyzer

 (FIA) to determine V.

1.3

 Estimated Measurement Uncertainty.

 The measurement

uncertainties are estimated for each VOC containing liquid as

follows:

W

 ±2.0percent and V

 ±12.0percent.

 Based on these

numbers,

 the probable uncertainty for L is estimated at about

±12.2percent for each VOC containing liquid.

1.4

 Sampling Requirements.

 A capture efficiency test shall

consist of at least three sampling runs.

 The sampling time for

each run should be at least

 8 hours, unless otherwise approved.

1.5

 Notes.

 Because this procedure is often applied in highly

explosive areas, caution and care should be exercised in choosing

appropriate equipment and installing and using the equipment.

Mention of trade names or company products does not constitute

endorsement.

 All gas concentrations

 (percent,

 ppm) are by

volume, unless otherwise noted.

119—438

203

2.

 APPARATUS AND REAGENTS

2.1

 Liquid Weight.

2.1.1

 Balances/Digital Scales.

 To weigh drums of VOC containing

liquids to within 0.2

lb.

2. 1.2

 Volume Measurement Apparatus (Alternative).

 Volume

meters, flow meters, density measurement equipment,

 etc.,

as

needed to achieve same accuracy as direct weight measurements.

2.2

 VOC Content (Flame Ionization Analyzer Technique).

The

liquid sample analysis system is shown in Figures

 1 and 2.

The

following equipment is required:

2.2.1

 Sample Collection Can.

 An appropriately sized metal can

to be used to collect VOC containing materials.

 The can must be

constructed in such a way that it can be grounded to the coating

container.

2.2.2

 Needle Valves.

 To control gas flow.

2.2.3

 Regulators.

 For carrier gas and calibration gas

cylinders.

2.2.4

 Tubing.

 Teflon or stainless steel tubing with diameters

and lengths determined by connection requirements of equipment.

 The tubing between the sample oven outlet and the FIA shall be

heated to maintain a temperature of

 120 ±

SoC.

2.2.5

 Atmospheric Vent.

 A tee and 0— to 0.5—liter/mm

 rotameter

placed in the sampling line between the carrier gas cylinder and

the VOC sample vessel to release the excess carrier gas.

A

toggle valve placed between the tee and the rotameter facilitates

leak tests of the analysis system.

2.2.6

 Thermometer.

 Capable of measuring the temperature of the

hot water bath to within

bC.

2.2.7

 Sample Oven.

 Heated enclosure, containing calibration gas

coil heaters, critical orifice, aspirator,

 and other liquid

sample analysis components, capable of maintaining a temperature

of 120 ±5°C.

2.2.8

 Gas Coil Heaters.

 Sufficient lengths of stainless steel

or Teflon tubing to allow zero and calibration gases to be heated

to the sample oven temperature before entering the critical

orifice or aspirator.

2.2.9

 Water Bath.

 Capable of heating and maintaining a sample

vessel temperature of 100 ±SoC.

119—4 39

204

2.2.10

 Analytical Balance.

 To measure ±0.001g.

2.2.11

 Disposable Syringes.

 2-cc or 5—cc.

2.2.12

 Sample Vessel.

 Glass, 40—mb septum vial.

 A separate

vessel

 is needed for each sample.

2.2.13

 Rubber Stopper.

 Two-hole stopper to accommodate 3.2-mm

(1/8-in.) Teflon tubing, appropriately sized to fit the opening

of the sample vessel.

 The rubber stopper should be wrapped in

Teflon tape to provide a tighter seal and to prevent any reaction

of the sample with the rubber stopper.

 Alternatively, any

leak—free closure fabricated of non—reactive materials and

accommodating the necessary tubing fittings may be used.

2.2.14

 Critical Orifices.

 Calibrated critical orifices capable

of providing constant flow rates from 50 to 250 ml/min at known

pressure drops.

 Sapphire orifice assemblies

 (available from

O’Keefe Controls Company) and glass capillary tubing have been

found to be adequate for this application.

2.2.15

 Vacuum Gauge.

 0- to 760-mm

 (0- to 30-in.) Hg U-Tube

manometer or vacuum gauge.

2.2.16

 Pressure Gauge.

 Bourdon gauge capable of measuring the

maximum air pressure at the aspirator inlet

 (e.g.,

 100 psig).

2.2.17

 Aspirator.

 A device capable of generating sufficient

vacuum at the sample vessel to create critical flow through the

calibrated orifice when sufficient air pressure is present at the

aspirator inlet.

 The aspirator must also provide sufficient

sample pressure to operate the FIA.

 The sample is also mixed

with the dilution gas within the aspirator.

2.2.18

 Soap Bubble Meter.

 Of an appropriate size to calibrate

the critical orifices in the system.

2.2.19

 Organic Concentration Analyzer.

 An FIA with

 a span value

of 1.5 times the expected concentration as propane; however other

span values may be used if it can be demonstrated that they would

provide more accurate measurements.

 The system shall be capable

of meeting or exceeding the following specifications:

2.2.19.1

 Zero Drift.

 Less than ±3.0percent of the span value.

2.2.19.2

 Calibration Drift.

 Less than ±3.0percent of span

value.

2.2.19.3

 Calibration Error.

 Less than ±5.0percent of the

calibration gas value.

119—440

205

2.2.20

 Integrator/Data Acquisition System.

 An analog or digital

device or computerized data acquisition system used to integrate

the FIA response or compute the average response and record

measurement data.

 The minimum data sampling frequency for

computing average or integrated values

 is one measurement value

every

 5 seconds.

 The device shall be capable of recording

average values at least once per minute.

2.2.21

 Chart Recorder (Optional).

 A chart recorder or similar

device is recommended to provide a continuous analog display of

the measurement results during the liquid sample analysis.

2.2.22

 Calibration and Other Gases.

 For calibration,

 fuel,

and

combustion air

 (if required) contained in compressed gas

cylinders.

 All calibration gases shall be traceable to NIST

standards and shall be certified by the manufacturer to ±1

percent of the tag value.

 Additionally, the manufacturer of the

cylinder should provide a recommended shelf life for each

calibration gas cylinder over which the concentration does not

change more than ±2percent from the certified value.

For

calibration gas values not generally available,

 alternative

methods for preparing calibration gas mixtures, such as dilution

systems, may be used with prior approval.

2.2.22.1

 Fuel.

 A 40 percent H2/60 percent He or 40 percent

H2/60 percent N2 gas mixture is recommended to avoid an oxygen

synergism effect thatreportedly occurs when oxygen concentration

varies significantly from a mean value.

2.2.22.2

 Carrier Gas.

 High purity air with less than

 1 ppm of

organic material

 (as propane)

 or less than 0.1 percent of the

span value, whichever is greater.

2.2.22.3

 FIA Linearity Calibration Gases.

 Low-,

 mid-, and

high-range gas mixture standards with nominal propane

concentrations of 20-30,

 45-55, and 70-80 percent of the span

value

 in air, respectively.

 Other calibration values and other

span values may be used if it can be shown that more accurate

 measurements would be achieved.

2.2.22.4

 System Calibration Gas.

 Gas mixture standard

containing propane in air, approximating the undiluted VOC

concentration expected for the liquid samples.

3.

 DETERMINATION OF LIQUID INPUT WEIGHT

3.1

Weight

Difference.

Determine

the

amount

material

introduced

the

process

the

weight

difference

the

feed

material

before

and

after

each

sampling

run.

determining

the

total

VOC

containing

liquid

usage,

account

for:

(a)

the

initial

(beginning)

VOC

containing

liquid

mixture;

(b)

any

solvent

added

119—44 1

206

during the test run;

(c)

 any coating added during the test run;

and

 (d) any residual VOC containing liquid mixture remaining at

the end of the sample run.

3.1.1

 Identify all points where VOC containing liquids are

introduced to the process.

 To obtain an accurate measurement of

VOC containing liquids, start with an empty fountain

(if

 applicable).

 After completing the run, drain the liquid in the

fountain back into the liquid drum (if possible),

 and weigh the

drum again.

 Weigh the VOC containing liquids to ±0.5percent of

the total weight

 (full) or ±0.1percent of the total weight of

VOC containing liquid used during the sample run, whichever is

less.

 If the residual liquid cannot be returned to the drum,

drain the fountain into a preweighed empty drum to determine the

final weight of the liquid.

3.1.2

 If it is not possible to measure a single representative

mixture, then weigh the various components separately

 (e.g.,

if

solvent is added during the sampling run, weigh the solvent

before it is added to the mixture).

If

 a fresh drum of VOC

containing liquid is needed during the run, then weigh both

the

empty drum and fresh drum.

3.2

 Volume Measurement (Alternative).

 If direct weight

measurements are not feasible, the tester may use volume meters

and flow rate meters (and density measurements) to determine the

weight of liquids used if it can be demonstrated that the

technique produces results equivalent to the direct weight

measurements.

 If a single representative mixture cannot be

measured, measure the components separately.

4.

 DETERMINATION OF VOC CONTENT IN INPUT LIQUIDS

4.1

 Collection of Liquid Samples.

4.1.1

 Collect a 100-ml or larger sample of the VOC containing

 liquid mixture at each application location at the beginning and

end of each test run.

 A separate sample should be taken of each

VOC containing liquid added to the application mixture during the

test run.

 If a fresh drum is needed during the sampling run,

then obtain a sample from the fresh drum.

4.1.2

 When collecting the sample, ground the sample container

to

the coating drum.

 Fill the sample container as close to the rim

as possible to minimize the amount of headspace.

4.1.3

 After the sample is collected, seal the container so the

sample cannot leak out or evaporate.

4.1.4

 Label the container to identify clearly the contents.

119—442

207

4.2

 Liquid Sample VOC Content.

4.2.1

 Assemble the liquid VOC content analysis system as shown

in Figure

1.

4.2.2

 Permanently identify all of the critical orifices that

may

be used.

 Calibrate each critical orifice under the expected

operating conditions

 (i.e.,

 sample vacuum and temperature)

against a volume meter as described in Section 5.3.

4.2.3

 Label and tare the sample vessels (including the stoppers

and caps)

 and the syringes.

4.2.4

 Install an empty sample vessel and perform a leak test of

the system.

 Close the carrier gas valve and atmospheric vent and

 evacuate the sample vessel to 250 mm

 (10 in.) Hg absolute or less

using the aspirator.

 Close the toggle valve at the inlet to the

aspirator and observe the vacuum for at least one minute.

If

there is any change in the sample pressure, release the vacuum,

adjust or repair the apparatus as necessary and repeat the leak

test.

4.2.S

 Perform the analyzer calibration and linearity checks

according to the procedure in Section 5.1.

 Record the responses

to each of the calibration gases and the back—pressure setting of

the FIA.

4.2.6

 Establish the appropriate dilution ratio by adjusting the

aspirator air supply or substituting critical orifices.

 Operate

the aspirator at a vacuum of at least 25 mm

(1

 in.) Hg greater

than the vacuum necessary to achieve critical flow.

 Select the

dilution ratio so that the maximum response of the FIA to the

sample does not exceed the high—range calibration gas.

4.2.7

 Perform system calibration checks at two levels by

introducing compressed gases at the inlet to the sample vessel

while the aspirator and dilution devices are operating.

 Perform

these checks using the carrier gas

 (zero concentration) and the

system calibration gas.

 If the response to the carrier gas

exceeds ±0.5percent of span, clean or repair the apparatus and

repeat the check.

 Adjust the dilution ratio as necessary to

achieve the correct response to the upscale check, but do not

 adjust the analyzer calibration.

 Record the identification of

the orifice, aspirator air supply pressure, FIA back-pressure,

and the responses of the FIA to the carrier and system

calibration gases.

4.2.8

 After completing the above checks, inject the system

calibration gas for approximately 10 minutes.

 Time the exact

duration of the gas injection using a stopwatch.

 Determine the

119—443

208

area under the FIA response curve and calculate the system

response factor based on the sample gas flow rate, gas

concentration, and the duration of the injection as compared to

the integrated response using Equations

 2 and 3.

4.2.9

 Verify that the sample oven and sample line temperatures

are

120 ±5oC

and that the water bath temperature is

100 ±5oC.

4.2.10

 Fill a tared syringe with approximately

 1 g of the VOC

containing liquid and weigh it.

 Transfer the liquid to a tared

sample vessel.

 Plug the sample vessel to minimize sample loss.

Weigh the sample vessel containing the liquid to determine the

amount of sample actually received.

 Also,

 as a quality control

check, weigh the empty syringe to determine the amount of

material delivered.

 The two coating sample weights should agree

within ±002 g.

 If not, repeat the procedure until an acceptable

 sample is obtained.

4.2.11

 Connect the vessel to the analysis system.

 Adjust the

aspirator supply pressure to the correct value.

 Open the valve

on the carrier gas supply to the sample vessel and adjust

 it to

provide a slight excess flow to the atmospheric vent.

 As soon as

the

initial

response

the

FIA

begins

decrease,

immerse

the

sample

vessel

the

water

bath.

(Applying

heat

the

sample

vessel

too

soon

may

cause

the

FID

response

exceed

the

calibrated

range

the

instrument,

and

thus

invalidate

the

analysis.)

4.2.12

Continuously

measure

and

record

the

response

the

FIA

until all of the volatile material has been evaporated from the

sample

and

the

instrument

response

has

returned

the

baseline

(i.e.,

response

less

than

0.5

percent

the

span

value).

Observe

the

aspirator

supply

pressure,

FIA

back—pressure,

atmospheric

vent,

and

other

system

operating

parameters

during

the

run;

repeat

the

analysis

procedure

any

these

parameters

deviate

from

the

values

established

during

the

system

calibration

checks

Section

4.2.7.

After

each

sample

perform

the

drift

check

described

Section

5.2.

the

drift

check

results

are

acceptable,

calculate

the

VOC

content

the

sample

using

the

equations

Section

Integrate

the

area

under

the

FIA

response curve,

 ordetermine the average concentration response

and the duration of sample analysis.

CALIBRATION

AND

QUALITY

ASSURANCE

5.1

FIA

Calibration

and

Linearity

Check.

Make

necessary

adjustments to the air and fuel supplies for the FIA and ignite

 the burner.

 Allow the FIA to warm up for the period recommended

by the manufacturer.

 Inject a calibration gas into the

measurement system and adjust the back-pressure regulator to the

value required to achieve the flow rates specified by the

119—444

209

manufacturer.

 Inject the zero- and the high—range calibration

gases and adjust the analyzer calibration to provide the proper

responses.

 Inject the low— and mid—range gases and record the

responses of the measurement system.

 The calibration and

linearity of the system are acceptable if the responses for all

four gases are within 5 percent of the respective gas values.

If

the performance of the system is not acceptable,

 repair or adjust

the system and repeat the linearity check.

 Conduct a calibration

and linearity check after assembling the analysis system and

after a major change is made to the system.

5.2

 Systems Drift Checks.

 After each sample, repeat the system

calibration checks in Section 4.2.7 before any adjustments to the

FIA or measurement system are made.

 If the zero or calibration

drift exceeds ±3percent of the span value, discard the result

and repeat the analysis.

5.3

 Critical Orifice Calibration.

5.3.1

 Each critical orifice must be calibrated at the specific

operating conditions that it will be used.

 Therefore, assemble

all components of the liquid sample analysis system as shown in

Figure

3.

 A stopwatch is also required.

5.3.2

 Turn on the sample oven,

 sample line,

 and water bath

heaters and allow the system to reach the proper operating

temperature.

 Adjust the aspirator to a vacuum of 380 mm

(15

 in.)

Hg vacuum.

 Measure the time required for one soap bubble to move

a known distance and record barometric pressure.

5.3.3

 Repeat the calibration procedure at a vacuum of 406 mm

(16

in.) Hg and at 25-mm

 (1-in.) Hg intervals until three consecutive

determinations provide the same flow rate.

 Calculate the

critical flow rate for the orifice in ml/min at standard

conditions.

 Record the vacuum necessary to achieve critical

flow.

6.

 NOMENCLATURE

AL

 area under the response curve of the liquid sample,

area count.

A3

 area under the response curve of the calibration gas,

area count.

C3

 actual concentration of system calibration gas, ppm

propane.

K

 1.830 x 10~g/(ml-ppm).

L

 total VOC content of liquid input, kg.

119—445

210

ML

 mass of liquid sample delivered to the sample vessel,

g.

q

 flow rate through critical orifice,

 ml/min.

RF

 liquid analysis system response factor, g/area count.

Ts

 total gas injection time for system calibration gas

during integrator calibration, mm.

 final VOC fraction of VOC containing liquid

j.

V1~

 initial VOC fraction of VOC containing liquid

j.

VAj

 VOC fraction of VOC containing liquid

j

added during

the run.

V

 VOC fraction of liquid sample.

WFj

 weight of VOC containing liquid

j

remaining at end of

the run, kg.

W~

 weight of VOC containing liquid

j

at beginning of the

run,

kg.

 weight of VOC containing liquid

j

added during the run,

kg.

7.

 CALCULATIONS

7.1

 Total VOC Content of the Input VOC Containing Liquid.

L

 V1~W1~=~S

VFj

WF)~f

 S V~ WAj

Eq.

1

7.2

 Liquid Sample Analysis System Response Factor for Systems

 Using Integrators, Grams/Area Counts.

RF

 q Tsj~

Eq.

2

A3

7.3

 VOC Content of the Liquid Sample.

Eq.

3

ML

119—44 6

211

Procedure T

—

 Criteria for and Verification of a Permanent or

Temporary Total Enclosure

1.

 INTRODUCTION

1.1

 Applicability.

 This procedure is used to determine whether

a permanent or temporary enclosure meets the criteria of a total

enclosure.

1.2

 Principle.

 An enclosure is evaluated against a set of

criteria.

 If the criteria are met and if all the exhaust gases

are ducted to a control device, then the volatile organic

compounds

 (VOC)

 capture efficiency

 (CE)

 is assumed to be 100

percent and CE need not be measured.

 However,

 if part of the

exhaust gas stream is not ducted to a control device, CE must be

determined.

2.

 DEFINITIONS

2.1

 Natural Draft Opening

 (NDO)

 Any permanent opening in the

enclosure that remains open during operation of the facility and

is not connected to a duct in which a fan is installed.

2.2

 Permanent Total Enclosure

 (PTE)

 A permanently installed

enclosure that completely surrounds a source of emissions such

that all VOC emissions are captured and contained for discharge

through a control device.

2.3

 Temporary Total Enclosure

 (TTE)

 A temporarily installed

enclosure that completely surrounds a source of emissions such

that all VOC emissions are captured and contained for discharge

through ducts that allow for the accurate measurement of VOC

rates.

3.

 CRITERIA OF A TEMPORARY TOTAL ENCLOSURE

3.1

 Any NDO shall be at least

 4 equivalent opening diameters

from each VOC emitting point.

3.2

 Any exhaust point from the enclosure shall be at least

4

equivalent duct or hood diameters from each NDO.

3.3

 The total area of all NDO’s shall not exceed

 5 percent of

the surface area of the enclosure’s four walls,

 floor,

and

ceiling.

3.4

 The average facial velocity (FV)

 of air through all NDO’s

shall be at least 3,600 m/hr

 (200 fpm).

 The direction of air

through all NDO’s shall be into the enclosure.

119—44

212

3.5

 All access doors and windows whose areas are not included in

Section 3.3 and are not included in the calculation in Section

3.4 shall be closed during routine operation of the process.

 CRITERIA OF A

PERMANENT

 TOTAL ENCLOSURE

4.1

 Same as Sections 3.1 and 3.3

—

 3.5.

4.2

 All VOC emissions must be captured and contained for

discharge through a control device.

5.

 PROCEDURE

5.1

 Determine the equivalent diameters of the NDO’s and

determine the distances from each VOC emitting point to all

NDO’s.

 Determine the equivalent diameter of each exhaust duct or

hood and its distance to all NDO’s.

 Calculate the distances in

terms of equivalent diameters.

 The number of equivalent

diameters shall be at least 4.

5.2

Measure

the

total

area

(At)

the

enclosure

and

the

total

area

(AN)

all

NDO’s

the

enclosure.

Calculate

the

NDO

enclosure area ratio

 (NEAR) as follows:

NEAR

AN/At

The

NEAR

must

 0.05.

5.3

Measure

the

volumetric

flow

rate,

corrected

standard

conditions,

each

gas

stream

exiting

the

enclosure

through

exhaust

duct

or hood using EPA Method

2.

 In some cases

 (e.g., when the

building is the enclosure),

 it may be necessary to measure the

volumetric

flow

rate,

corrected

standard

conditions,

each

gas

stream

entering

the

enclosure

through

forced

makeup

air

duct

using

Method

Calculate

using

the

following

equation:

FV

Qo

Q1/

AN

where:

 the sum of the volumetric flow from all gas streams

exiting the enclosure through an exhaust duct or

hood.

the

sum

the

volumetric

flow

from

all

gas

streams

into

the

enclosure

through

forced

makeup

air

duct;

zero,

 if there

 is no forced makeup air into the

enclosure.

AN

 total area of all NDO’s in enclosure.

119—4 48

213

The FV shall be at beast 3,600 m/hr

 (200 fpm).

5.4

 Verify that the direction of air flow through all NDO’s

is

inward.

 Use streamers,

 smoke tubes,

 tracer gases,

 etc.

 Strips

of plastic wrapping film have been found to be effective.

Monitor the direction of air flow at intervals of at least

10

minutes for at least

 1 hour.

 QUALITY

ASSURANCE

6.1

 The success of this protocol lies in designing the TTE to

simulate the conditions that exist without the TTE,

 i.e.,

the

effect of the TTE on the normal flow patterns around the affected

facility or the amount of fugitive VOC emissions should be

minimal.

 The TTE must enclose the application stations, coating

reservoirs,

 and all areas from the application station to the

oven.

 The oven does not have to be enclosed if it

 is under

negative pressure.

 The NDO’s of the temporary enclosure and a

fugitive exhaust fan must be properly sized and placed.

6.2.

 Estimate the ventilation rate of the TTE that best

simulates the conditions that exist without the TTE,

 i.e.,

the

effect of the TTE on the normal flow patterns around the affected

facility or the amount of fugitive VOC emissions should be

minimal.

 Figure

 1 may be used as an aid.

 Measure the

concentration

 (CG) and flow rate

 (Q0)

 of the captured gas stream,

specify a safe concentration

 (C?) for the fugitive gas stream,

estimate the CE, and then use the plot in Figure

 1 to determine

the volumetric flowrate of the fugitive gas stream

A

fugitive VOC emission exhaust fan that has a variable flow

control

 is desirable.

6.2.1

 Monitor the concentration of VOC into the capture device

without the TTE.

 To minimize the effect of temporal variation on

the captured emissions, the baseline measurement should be made

over as long a time period as practical.

 However, the process

conditions must be the same for the measurement in Section 6.2.3

as they are for this baseline measurement.

 This may require

short measuring times for this quality control check before and

after the construction of the TTE.

6.2.2

 After the TTE is constructed, monitor the VOC

concentration inside the TTE.

 This concentration shall not

continue to increase and must not exceed the safe level according

to OSHA requirements for permissible exposure limits.

An

increase in VOC concentration indicates poor TTE design or poor

capture efficiency.

6.2.3

 Monitor the concentration of VOC into the capture device

with the TTE.

 To limit the effect of the TTE on the process, the

119—44 9

214

VOC concentration with and without the TTE must be within ±10

percent.

 If the measurements do not agree,

 adjust the

ventilation rate from the TTE until they agree within 10 percent.

119—450

215

APPENDIX C

REFERENCE METHODS AND PROCEDURES

Introduction

This Appendix presents the reference methods and procedures

required for implementing Reasonably Available Control Technology

(RACT).

 Methods and procedures are identified for two types of

ACT implementation:

a) Determination of VOC destruction efficiency

 for evaluating

compliance with the 98 weight percent VOC reduction or 20 ppmv

emission limit specified in Sections 215.520 through 215.527;

and

b) Determination of offgas fbowrate, hourly emissions and stream

net heating value for calculating TRE.

All

 reference methods identified in this Appendix refer

 to the

reference methods specified at 40 CFR 60, Appendix A,

incorporated by reference in Section 215.105.

VOC DESTRUCTION EFFICIENCY DETERMINATION

The

following

reference

methods

and

procedures

are

required

for

determining

compliance

with

the

percent

destruction

efficiency

specified in Sections 215.520 through 215.527.

Reference

Method

for

selection

the

sampling

site.

The

control

device

inlet

sampling

site

for

determination

vent

stream

molar

composition

total

organic

compound

destruction

efficiency

shall

prior

the

inlet

any

control

device

and

after

all

recovery

devices.

Reference

Methods

2A,

for

determination

the

volumetric

flowrate.

Reference

Method

measure

oxygen

concentration

the

air

dilution

correction.

The

emission

sample

shall

corrected

to

 3 percent oxygen.

d) Reference Method 18 to determine the concentration of total

organic

compounds

(minus

methane

and

ethane)

the

control

device outlet and total organic compound reduction efficiency

of the control device.

TRE DETERMINATION

The following reference methods and procedures are required for

determining the offgas flowrate, hourly emissions,

 and the net

heating value of the gas combusted to calculate the vent stream

TRE.

119—45 1

216

a) Reference Method

 1 or 1A for selection of the sampling site.

The sampling site for the vent stream fbowrate and molar

composition determination prescribed in

 (b) and

(c)

 shall be

prior

the

inlet

any

combustion

device,

prior

any

post—reactor dilution of the stream with air and prior to

any

post—reactor introduction of halogenated compounds into the

vent stream.

 Subject to the preceding restrictions on the

sampling

site,

shall

after

the

final

recovery

device.

 any gas stream other than the air oxidation vent stream is

normally conducted through the recovery system of the affected

facility, such stream shall be rerouted or turned off while

the vent stream is sampled, but shall be routed normally prior

to the measuring of the initial value of the monitored

parameters for determining compliance with the recommended

PACT.

the

air

oxidation

vent

stream

normally

routed

through

any

equipment

which

not

part

the

air

oxidation

process

defined

Ill.

Adm.

Code

211.122,

such

equipment

shall

bypassed

the

vent

stream

while

the

vent

stream

sampled,

but

shall

not

bypassed

during

the

measurement

the

initial

value

the

monitored

parameters

for

determining

compliance

with

Subpart

The

molar

composition

the

vent

stream

shall

determined

using

the

following

methods:

Reference

Method

measure

the

concentration

all

organics,

including

those

containing

halogens,

unless

significant

portion

the

compounds

interest

are

polymeric

(high

molecular

weight),

can

polymerize

before

analysis

have

low

vapor

pressures,

which

case

Reference

Method

25(a)

shall

used.

2)

 ASTN Db946-67

 (reapproved 1977),

 incorporated by reference

Section

215.105,

measure

the

concentration

carbon

monoxide

and

hydrogen.

3)

 Reference Method

 4 to measure the content of water vapor,

necessary.

The

volumetric

fbowrate

shall

determined

using

Reference

Method

2,

2A,

 2C or 2D,

 as appropriate.

d) The net heating value of the vent stream shall be calculated

using the following equation:

n

H=K

CiHi

i=1

119—452

217

Where:

H

 Net heating value of the sample, MJ/scm, where the net

enthabpy per mole of offgas is based on combustion at

2SoC and 760 mm Hg, but the standard temperature for

determining the volume corresponding to one mole is

2OoC, as in the definition of F (vent stream flowrate)

below.

K

Constant,

1.740

10~

(1/ppm)

(mole/scm)(MJ/kcal)

where standard temperature for mole/scm is 20°C.

Ci

Concentration

sample

component

 i, reported on a wet

basis,

 in ppm, as measured by Reference Method

 18 or

ASTM D1946-67

 (reapproved 1977),

 incorporated by

reference in Section 215.105.

Hi

 Net heat of combustion of sample component i,

kcal/mole based on combustion at 25 C and 760 mm Hg.

If published values are not available or cannot be

calculated, the heats of combustion of vent stream

components are required to be determined using ASTM

D2382-76, incorporated by reference in Section

215. 105.

e) The emission rate of total organic compounds in the process

vent stream shall be calculated using the following equation:

n

E=K

F

 CiMi

i= b

Where:

E

 Emission rate of total organic compounds (minus

methane and ethane)

 in the sample in kg/hr.

K

 Constant 2.494

 x bO_6

 (1/ppm)

 (mole/scm)

 (kg/g)

(min/hr), where standard temperature for (mole/scm)

is

20°C.

Mi

 Molecular weight of sample component i

 (g/mole).

F

 Vent stream flowrate (scm/mm), at a standard

temperature

20°C.

f) The total vent stream concentration

 (by volume)

 of compounds

containing halogens (ppmv,

 by compound)

 shall be summed from

the individual concentrations of compounds containing halogens

119—453

218

which were measured by Reference Method 18.

119—454

2b9

APPENDIX D

COEFFICIENTS

FOR

THE

TOTAL

RESOURCE

EFFECTIVENESS INDEX

 (TRE)

 EQUATION

This Appendix contains values for the total resource

effectiveness index

 (TRE)

 equation in Subpart V.

If a flow rate falls exactly on the boundary between the

indicated ranges,

 the operator shall use the row in which the

flow rate is maximum.

COEFFICIENTS FOR TRE EQUATION

FOR CHLORINATED PROCESS VENT STREAMS WITH

NET HEATING VALUE LESS THAN

OR EQUAL TO 3.5 MJ/scm

FLOW RATE

(scm/mm)

Mm.

 Max.

a

b

c

d

e

f

0.0

 13.5

 48.73

0.

0.

13.5

 700.

 42.35

0.

 0.0245

700.

 b400.

 84.38

0.

 0.0346

1400.2100.

 126.41

0.

 0.0424

2100.2800.

 168.44

0.

 0.0490

2800.3500.

 210.47

0.

 0.0548

COEFFICIENTS FOR TRE EQUATION

FOR CHLORINATED PROCESS VENT STREAMS WITH

NET HEATING VALUE GREATER THAN

3.5 MJ/scm

FLOW PATE

(scm/mm)

Mm.

 Max.

b

d

e

f

0.

 0.404

 —0.1632

0.624

 0.404

 —0.1632

0.678

 0.404

 —0.1632

0.712

 0.404

 —0.1632

0.747

 0.404

 —0.1632

0.758

 0.404

 —0.1632

a

c

0.

 13.5

 47.76

0.

 —0.292

0.

0.

0.

13.5

 700.

 41.58

 0.605—0.292

0.

0.

 0.0245

700.

 1400.

 82.84

 0.658 —0.292

0.

0.

 0.0346

1400.2100.

 123.10

 0.691 —0.292

0.

0.

 0.0424

2100. 2800.

 165.36

 0.715 —0.292

0.

0.

 0.0490

2800. 3500.

 206.62

 0.734 —0.292

0.

0.

 0.0548

119—45 5

220

COEFFICIENTS FOR TRE EQUATION

FOR NONCHLORINATED PROCESS VENT STREAMS WITH

NET HEATING VALUE LESS THAN

OR EQUAL TO 0.48 MJ/scm

FLOW RATE

(scm/mm)

Mm.

 Max.

a

b

c

d

e

f

0.

 13.5

 19.05

0.

 0.113

 —0.214

0.

0.

13.5 1350.

 16.61

 0.239

 0.113

 —0.214

0.

 0.0245

1350.2700.

 32.91

 0.260

 0.113

 —0.214

0.

 0.0346

2700.4050.

 49.21

 0.273

 0.113

 —0.214

0.

 0.0424

COEFFICIENTS FOR TRE EQUATION FOR NONCHLORINATED

PROCESS VENT STREAMS WITH NET HEATING VALUE

GREATER THAN

0.48

AND LESS THAN OR

EQUAL TO 1.9 MJ/scm

FLOW RATE

(scm/mm)

Mm.

 Max.

a

b

c

d

e

f

0.

 13.5

 19.74

0.

 0.400

 —0.202

0.

0.

13.5 1350.

 18.30

 0.138

 0.400

 —0.202

0.

 0.0245

1350.2700.

 36.28

 0.150

 0.400

 —0.202

0.

 0.0346

2700.4050.

 54.26

 0.158

 0.400

 —0.202

0.

 0.0424

119—456

221

COEFFICIENTS FOR TRE EQUATION FOR NONCHLORINATED

PROCESS VENT STREAMS WITH NET HEATING VALUE

GREATER THAN 1.9 AND LESS THAN

OR

EQUAL TO 3.6 MJ/scm

a

b

c

d

TITLE 35:

 ENVIRONMENTAL PROTECTION

SUBTITLE B:

 AIR POLLUTION

CHAPTER I:

 POLLUTION CONTROL BOARD

SUBCHAPTER c:

 EMISSIONS STANDARDS AND

LIMITATIONS

FOR STATIONARY SOURCES

PART

215

ORGANIC MATERIAL EMISSION STANDARDS AND LIMITATIONS

SUBPART A:

 GENERAL PROVISIONS

SUBPART A:

 GENERAL PROVISIONS

Section 215.100

 Introduction

a)

 This Part contains standards and limitations

for emissions of organic material from

stationary sources located in areas other than

the Chicago area counties of Cook, DuPage,

Kane,

 Lake, McHenry, and Will and the Metro

East area counties of Madison, Monroe,

 and St.

Clair.

 Standards and limitations a~plvingin

FLOW RATE

(scm/mm)

Mm.

 Max.

e

f

.0

 13.5

 15.24

0.

 0.033

0.

0.

0.

 13.5

 1190.

 13.63

 0.157

 0.033

0.

0.

 0.0245

1190.2380.

 26.95

 0.171

 0.033

0.

0.

 0.0346

2380.3570.

 40.27

 0.179

 0.033

0.

0.

 0.0424

COEFFICIENTS FOR TRE EQUATION

FOR NONCHLORINATED PROCESS VENT STREAMS WITH

NET HEATING VALUE GREATER THAN 3.6 MG/scm

FLOW RATE

(scm1min)

Mm.

 Max.

0.

 13.5

 15.24

0.

0.

 0.0090

0.

0.

13.5

 1190.

 13.63

0.

0.

 0.0090

 0.0503

 0.0245

1190.2380.

 26.95

0.

0.

 0.0090

 0.0546

 0.0346

2380.3570.

 40.27

0.

0.

 0.0090

 0.0573

 0.0424

a

b

c

d

e

f

119—45

222

the Chicago area are set forth in Part 218.

Standards and limitations applying in the

Metro East area are set forth in Part 219.

Notwithstanding any other provision of

this Part,

 the provisions of this Part

shall not apply to sources located

in

the Chicago area counties of Cook,

DuPage,

 Kane.

 Lake, McHenry and Will

unless the provisions of 35

 Ill.

 Adin.

Code Part 218 applicable to such sources

are voided or otherwise made ineffective

pursuant to Section 218.100 of 35

Ill.

Adm. Code Part 218.

21

 Notwithstanding any other provision of

this Part,

 the provisions of this Part

shall not apply to sources

 in the Metro

East area counties of Madison, Monroe

and St. Clair unless the provisions of

35 Ill. Adm. Code Part 219 applicable

to

such sources are voided or otherwise

made ineffective pursuant to Section

219.100 of 35

 Ill.

 Adm. Code Part

 219.

b)

 Sources subject to this Part may be subject to

the following:

1)

 Permits required under 35

 Ill.

 Adm. Code

201;

2)

 Air quality standards under 35 Ill.

 Adm.

Code 243.

c)

 This Part is divided into Subparts which are

grouped as follows:

1)

 Subpart A:

 General provisions;

2)

 Subparts B

J:

 Emissions from

equipment and operations in common to

more than one industry;

3)

 Subparts K

—

N:

 Emissions from use of

organic material;

4)

 Subparts N

—

 end:

 Special rules for

various industry groups.

(Source:

 Amended at 15

 Ill.

 Reg.

___________,

 effective

____________________________

119—458

223

SUBPART

 GASOLINE DISTRIBUTION

Section 215.581

 Bulk Gasoline Plants

a)

 Subject to subsection

 (e),

 no person may cause

or allow the transfer of gasoline from a

delivery vessel into a stationary storage tank

located at a bulk gasoline plant unless:

1)

 The delivery vessel and the stationary

storage tank are each equipped with a

vapor collection system that meets the

requirements of subsection

(d)

(4);

2)

 Each vapor collection system is

operating;

3)

 The delivery vessel displays the

appropriate sticker pursuant to the

requirements of Section 215.584(b)

or

(d);

4)

 The pressure relief valve(s)

 on the

stationary storage tank and the

delivery

vessel are set to release at no less

than 0.7 psi or the highest pressure

allowed by state or local fire codes or

the guidelines of the National Fire

Prevention Association; and

5)

 The stationary storage tank is equipped

with a submerged loading pipe.

b)

 Subject to subsection

 (f),

 no person may cause

or allow the transfer of gasoline from

a

stationary storage tank located at a bulk

gasoline plant into a delivery vessel unless:

1)

 The requirements set forth

in

subsections

 (a) (1) through

 (a) (4)

are

met; and

2)

 Equipment is available at the bulk

gasoline plant to provide for the

submerged filling of the delivery vessel

or the delivery vessel is equipped for

bottom loading.

c)

 Subject to subsection

 (e),

 each owner of a

stationary storage tank located at

 a bulk

gasoline plant shall:

119—459

224

1)

 Equip each stationary storage tank with

a vapor control system that meets the

requirements of subsection

(a)

or

 (b),

whichever is applicable;

2)

 Provide instructions to the operator of

the bulk gasoline plant describing

necessary maintenance operations and

procedures for prompt notification of

the owner in case of any malfunction of

a vapor control system; and

3)

 Repair, replace or modify any worn out

or malfunctioning component or element

of design.

d)

 Subject to subsection

 (e), each operator of a

bulk gasoline plant shall:

1)

 Maintain and operate each vapor control

system in accordance with the owner’s

instructions;

2)

 Promptly notify the owner of any

scheduled maintenance or malfunction

requiring replacement or repair of a

major component of a vapor control

system; and

3)

 Maintain gauges, meters or other

specified testing devices in proper

working order;

4)

 Operate the bulk plant vapor collection

system and gasoline loading equipment in

a manner that prevents:

A)

 Gauge pressure from exceeding 18

inches of water and vacuum from

exceeding 6 inches of water, as

measured as close as possible to

the vapor hose connection; and

B)

 A reading equal to or greater

than 100 percent of the lower

explosive limit

 (LEL measured as

propane) when tested in

accordance with the procedure

described in EPA 450/2—78—051

Appendix B; and

119—460

225

C)

 Avoidable leaks of liquid during

loading or unloading operations.

5)

 Provide a pressure tap or equivalent on

the bulk plant vapor collection system

in order to allow the determination

compliance with 215.581(d) (4) (A); and

6)

 Within 15 business days after discovery

of the beak by the owner, operator,

or

the Agency, repair and retest a vapor

collection system which exceeds the

limits of subsection

 (d) (4) (A)

or

 (B).

e)

 The requirements of subsections

 (a),

(c)

and

(d)

 shall not apply to:

1)

 Any stationary storage tank with a

capacity of less than 575 gallons;

or

2)

 Any bulk gasoline plant whose annual

gasoline throughput is less than 350,000

gallons as averaged over the preceding

three calendar years.

The

requirements

subsection

(b)

shall

only

apply to bulk gasoline plants:

1)

 That have an annual gasoline throughput

greater than or equal to 1,000,000

gallons,

 as averaged over the preceding

three calendar years; and

2)

 That either distribute gasoline to

gasoline dispensing facilities subject

to the requirements of Section

215.583(a) (2). 35 Ill. Adm. Code

218.583(b) (2) or 35 Ill.

 Adm. Code

219.583(a) (2) or that are located in the

following counties:

Boone,

 Cook, Durage,

 Kanc,

 Lake,

Madiaon, McHenry, Peoria, Rock Island,

St.

 Clair,

 Tazewell, Will or Winnebago.

g)

 Bulk gasoline plants were required to take

certain actions to achieve compliance

which

are summarized in Appendix C.

(Source:

Amended

Ill.

Reg.

_______________,

 effective

119—46 1

226

IT IS SO ORDERED.

I, Dorothy N. Gunn,

 Clerk of the Illinois Pollution Control

Board

 hereby certi~ythat the above Order was adopted ~n the

______

 day of

~

 1991, by a vote of

Illinois

 Control Board

119—46 2