specifically
applicable
“Air suspension cocitor/dryor” means
~er&-4-~- which consists of
a pharmaceutical
on facility
distri
g applied
and any
applied each day on a coating line,
which arc specifically exempted from
of VON), and
definition
water and any comp
from the
applied -day
high transfer efficiency.
conditions.
a faoility thating lines.
“Extreme cnvi~any or all ofconditions; t~(203SF); dctcj
nt weather
“Croon Tires” moans assembled tires before molding andcuring have occurred.
~oduot~ coating facility”
“internal-floating roof” moans a paver or roof in a
fixed-roof tank which reststhe volatile organic liquid
upon and is supported
being contained and is
evaporation without chornioal reaction, including clearlacquer sanding scalers.
u~ccrm
liquid
gas phase and
The first
within the room
according
or component
circumference of the roof.
operating conditions.
ring, springa, or 1...
“Miscellaneous fabricated product
process” means~
manufacturing
itting VON~
curing
clean-up operations associated with the proocasdescribed in this definition.
“Miscellaneous organic chemiosi manufacturing process”means:
and the usc and
means to measure and record.
package coating” -moans a ooating made from
“Monitor”
prior to
one different ingredient which must beusing and has a limited pot life due to
chemical reaction which occurs upon mixing.
materi...
“Oven” means a chamber within which heat is used for
Ott1t~ u~Jyior
of organic materials it
“Prime goat” moans the first of two or more coatingsapplied to a surface.
“Production equipment exhaust system” means a system
“Cinglo coat” moans one coating application applied—to
‘~-Standard conditions” means a temperature of 70~Fand apressure of 14.7 psia.
edition, February 1980 (incorporated by reference in
primary seal, the tank wall, the liquid surface and the
“Web” means a substrate which is printed in continuousroll—f cd presses.
1) The control device efficiency shall be determined
~j The period of such adsorber operation does
~ The total of all hours in the calendar year
daily-weighted average VON content of
C) The instrument shall be calibrated before use
B) The background level shall be determined as
C) “Protocols for Generating Unit-Specific
total mixture.
c) If the VON is in a mixture made up of only VON
2) A vapor recovery system consisting of:
A) A vapor gathering system capable of
b) Subject to subsection (a) of this Section no owner or
in the seal or any seal fabric or material of anyfloating roof;
3) All openings of any floating roof deck, except
A) The cover, lid or seal is in the closed
were rcquired to havo compliance achedul
5) Inspections are conducted prior to May 1 of each
4) Used to store crude oil with a pour point of 50°F
b) Unless the submitted ~omplianoe plan or schedule was
a) No person shall use any single or multiple compartment
less; or,
b) By combustion in a smokeless flare; or,
each such set; and,-
d) Proof, at three—year intervals, using such three—year
1) The cover of the degreaser is closed when
A) A dcviocQjj~which shuts off the sump heat
coil; and
4) The degreaser is equipped with downtime covers for
kg/l lb/gal
and the method
kg/l lb/gal
b) Can Coating kg/l lb/gal
kg/i lb/gal
e) Fabric Coating 0.35 (2.9)
3) Extreme performance 0.42 (3.5)
3) Pigmented coat 0.60 (5.0)
4) High-temperature aluminum
2) For each coating line which applies coatings
units of kg/day (lbs/day)~.~
coating appliedrj..
applied in the can coating
specifically exempted from thedefinition of VON)7~.
d) No owner or operator of a heavy off-highway vehicle
e) No owner or operator of a wood furniture coating line
1) For each coating line which applies multiple
Section 218.207 Alternative Emission Limitations
c) No owner or operator of a coating line subject to only
g) No owner or operator of a wood furniture coating line
tification
the Agency’s approva.L
Iof the propoca.~..
Section 218.302 Alternative Standard
b) A vapor recovery system which adsorbs and/or condenses
if the weighted average VON content of all
all coatings and inks (minus waterand any compounds which are
2) A federally enforceable construction permit or SIP
2) Any owner or operator of any heatset—web—of feet
4) The control device is operated at all times when
Section 218.879 Compliance Date (Repealed)
A descriptionemiot3ions
of each processlimitation;
Quantification of the emissions from each process;
A description of the procedures and methods used to
4)- A description of the methods which will be used to
th1.IhUUJ.~ILXOfl or measurement.
d) For the purposes of this Subpart, an emission
e) For the purposes of this Subpart, uncontrolled VON

ILLINOIS POLLUTION CONTROL BOARD

July 22, 1993

IN THE MATTER OF:

OMNIBUS CLEANUP OF THE VOLATILE

ORGANIC MATERIAL RACT RULES    

)

R93-9

APPLICABLE TO OZONE NONATTAINMENT 

)

(Rule Making)

AREAS: AMENDMENTS TO 35 ILL. ADM. 

)

CODE PARTS 203, 211, 218 AND 219. 

)

PROPOSED RULE.     

SECOND NOTICE.

ORDER OF THE BOARD (by B. Forcade):

On March 16, 1993, the Illinois Environmental Protection

Agency (Agency) filed this proposal for rule making. This

proposal was filed pursuant to section 28.5 of the Environmental

Protection Act. (415 ILCS 5/28.5 (1992).) The proposal

represents one part of Illinois’ submittal of a complete state

implementation plan (SIP). Pursuant to section 182(a) of the

Clean Air Act (CAA), as amended in 1990, Illinois was to adopt

and submit its plan by November 15, 1992. The Board adopted the

First Notice Opinion and Order in this proceeding without comment

on the substance of the rule on March 25, 1993. The proposed

amendments were published in the Illinois Register on April 9,

1993 at 17 Ill. Reg. 4782 (Part 211), 17 Ill. Reg. 4898 (Part

203), 17 Ill. Reg. 4905 (Part 218) and 17 Ill. Reg. 5169 (Part

219). A correction to the proposed rules, adding some pages of

the proposed rule that were omitted from the initial publication,

was published in the Illinois Register on April 23, 1993 at 17

Ill. Reg. 6520 (Part 218) and 17 Ill. Reg. 6539 (Part 219).

Today the Board acts to send this proposal to second notice

under the Illinois Administrative Procedure Act. This order is

supported by a separate opinion adopted on the same day.

The Board directs the Clerk of the Board to cause the filing

of the following proposal for Second Notice with the Joint

Committee on Administrative Rules. The complete text of the

proposed rules follows.

IT IS SO ORDERED.

I, Dorothy M. Gunn, Clerk of the Illinois Pollution Control

Board, do hereby ~ert~fy that thef~bov~order was adopted by the

Board on the 

day of 

________________,

1992, by a vote

of

________.

/~~ ~‘

Dorothy M. Gu~1n~Clerk

Illinois Po11~(ition Control Board

2

TITLE 35: ENVIRONMENTAL PROTECTION

SUBTITLE B: AIR POLLUTION

CHAPTER I: POLLUTION CONTROL BOARD

SUBCHAPTER a: PERMITS AND GENERAL PROVISIONS

PART 203

MAJOR STATIONARY SOURCES CONSTRUCTION AND MODIFICATION

SUBPART A: GENERAL PROVISIONS

Section

203.101

203. 103

203. 104

203.107

203. 110

203.112

203.113

203.116

203.117

203.119

203.121

203

122

203.123

203. 124

203

125

203 .126

203.127

203.128

203.131

203.134

203.136

203.145

203.150

203.155

Definitions

Actual Construction

Actual Emissions

Allowable Emissions

Available Growth Margin

Building, Structure and Facility

Commence

Construction

Dispersion Enhancement Techniques

Emission Baseline

Emission Offset

Emissions Unit

Federally Enforceable

Fugitive Emissions

Installation

Lowest Achievable Emission Rate

Nonattaintnent Area

Potential to Emit

Reasonable Further Progress

Secondary Emissions

Stationary Source

Volatile Organic Material (Repealed)

Public Participation

Severability (Repealed)

SUBPART B: MAJOR STATIONARY SOURCES IN NONATTAINNENT AREAS

Section

203

201

203.202

203.203

203 .204

203

205

203.206

203.207

203.208

203.209

203.210

203.211

Prohibition

Coordination with Permit Requirement and Application

Pursuant to 35 Iii. Adm. Code 201

Construction Permit Requirement and Application

Duration of Construction Permit (Repealed)

Effect of Permits

Major Stationary Source

Major Modification of a Source

Net Emission Determination

Significant Emissions Determination

Relaxation of a Source—Specific Limitation

Permit Exemption Based on Fugitive Emissions

3

SUBPART C: REQUIREMENTS FOR MAJOR STATIONARY SOURCES IN

NONATTAINNENT AREAS

203.301 Lowest Achievable Emission Rate

203.302 Maintenance of Reasonable Further Progress and Emission

Offsets

203.303 Baseline and Emission Offsets Determination

203.304 Exceptions from Emissions Offset Requirement (Repealed)

203.305 Compliance by Existing Sources

203.306 Analysis of Alternatives

SUBPART F: OPERATION OF A MAJOR STATIONARY SOURCE OR MAJOR

MODIFICATION

Section

203.601 Lowest Achievable Emission Rate Compliance Requirement

203.602 Emission Offset Maintenance Requirement

203.603 Ambient Monitoring Requirement (Repealed)

SUBPART G: GENERAL MAINTENANCE OF EMISSION OFFSETS

Section

203.701 General Maintenance of Emission Offsets

SUBPART H: OFFSETS FOR EMISSION INCREASES FROM ROCKET ENGINES

AND MOTOR FIRING

Section

203.801 Offsets for Emission Increases from Rocket Engines and

Motor Firing

AUTHORITY: Implementing Section 9.1 and 10 and authorized by

Section 27 and 28.5 of the Environmental Protection Act (Ill.

Rev. Stat. 1991, ch. 111½, pars. 1009.1, 1010 and 1027) (P.A. 87—

1213, effective September 26, 1992) 415 ILCS 5/9.1, 10, 27, and

28.5

SOURCE: Adopted and codified at 7 Ill. Reg. 9344, effective July

22, 1983; codified at 7 Iii. Reg. 13588; amended in R85—20 at 12

Ill. Reg. 6118, effective March 22, 1988; amended in R9l—24 at 16

Ill. Reg. 13551, effective August 24, 1992; amended in R92—21 at

17 Ill. Reg. 6973, effective April 30, 1993; amended in R93— 

_____

at 17 Ill. Reg. 

_________

effective 

_____________________

4

Section 203.145  

Volatile Organic Material (Repealed)

means any compuui-iu 

on

inunoxiac,

oar~ondioxide, carbonic ac~a

des or carbonates, and aininoniuin arbonate, which

atmospheric photoohcniical reactions.

‘.Lnic~ lnc.Luacs 

Quen organic compouna ocncr tnan 

following, which have been determined to have

negligible photochcmical reactivity! Methane; ethcinc;

mcthylcnc chloride (dichlormcthanc), 1,1,1

trichiorethanc (methyl chloroform), 1,1,1 trichioro

2,2,2 trifluoroethane (CFC 113)7 triahlorofluoromethanc

(CFC 11), dichlorodifluoromcthanc (CFC 12);

chlorodifluoromethanc (CFC 22); trifluoromcthane (FC

23); 1,2 dichloro 1,1,2,2 tctrafluorocthanc (CFC 114);

cloropcntafluorocthane (CFC 115); 1,1,1 trifluoro 2,2

dichloroethanc (HCFC 123); 1,1,12 tctrafluorocthane

(HFC 134a); 1,1 dichloro 1 fluorocthanc (HCFC l4lb); 1

chioro 1,1 difluorocthanc (HCFC 142b); 2 chioro 1,1,1,2

tctrafluorocthanc (HCFC 124); pentafluorocthane (HFC

125); 1,1,2,2 tctrafluorocthanc

(HFC 134); 1,1,1

trifluorocthanc (HFC 143a); 1,1 difluroethanc (HFC

152a); and perfluorocarbon compounds which fall into

th~~r~~

-1-)    Cyclic, branched, or linear, completely

fluorinated alkanc s;

Cyclic, branched, or linear, completely

fluorinated ethers with no unsaturation~,

3)  Cyclic, branched, or linear, co~plctcly

4)  Sulfur containing Pcrf 1 rocarbons 

with no

_~.I_

A__

____t~

For purposes of determining VON emissions and

compliance with emissions limits, VON will be measured

by the test methods in the approved implementation plan

or 40 CFR Part 60, Appendix A, incorporated by

reference at Sections 215.105, 218.112, and 219.112, as

applicable or by source specific test methods which

have bcen established pursuant to a permit issucd

r~r,-~r~rnm r~n -11vrci

c~rpromulgated under

—

under 

alfl (PP Pnrt ci

-a-:~t t

~ the Clean Ai~ ~

Appendix C, ~~cd

by rcf~

Beotions

218.112

-S4-~

and

219.112

or under

flj

Fr’rtinn~

40 CFR Part21~L112

r~l

C.~L—~——.~.—+—

‘r

~r~-~’

“Volatile orga

excluding carb

metallic carbi

participates

i.

material” (VON)         

-“~

-f carbon,

5

-x

and 219.112, as applicable. Where such a method also

measures compounds with negligible photochemical

reactivity, these negligibly reactive compounds may be

excluded as VON if the amount of ouch compounds is

accurately quantified, and ouch exclusions is approved

and .csults

to the satisfaction of ~

amount of negligibly reactive oompouna~in ~nc

sources’s emissions 

d)  The UCEPA shall not be bound by any State determination

as to appropriate methods for testing or monitoring

negligibly reactive compounds if such determination is

not reflcctea in ‘~v or tne rnovisions or paragrapn

(Source: Repealed at 

_____

Ill. Reg. 

_____,

effective___________

cgligibly

rcactlvc

the Agency

compounds

may

as VOM 

or at

require an owner

any

or

tiiuc

operator

cncrcaftcr,

to

provide

monitoring or testina ‘--~thods

-~emons’’’~

Agency, th~

)

6

TITLE 35:

ENVIRONMENTAL PROTECTION

SUBTITLE B:

AIR POLLUTION

CHAPTER I: POLLUTION CONTROL BOARD

SUBCHAPTER

c: EMISSION STANDARDS AND LIMITATIONS

FOR STATIONARY SOURCES

PART 211

DEFINITIONS AND 

GENERAL PROVISIONS

SUBPART

A: GENERAL PROVISIONS

Incorporations by Reference

Abbreviations and Units

Other Definitions

Definitions (Repealed)

Accelacota

Accumulator

Acid Gases

Actual Heat Input

Adhesive

Aeration

Afterburner

Air Contaminant

Air Dried Coatings

Air Oxidation Process

Air Pollutant

Air Pollution

Air Pollution Control Equipment

Air Suspension Coater/Dryer

Airless Spray

Air Assisted Airless Spray

Annual Grain Through-Put

Application Area

Architectural

Coating

As Applied

Asphalt

Asphalt Prime Coat

Automobile

Automobile or Light-Duty Truck Assembly Source or

Automobile or Light-Duty Truck Manufacturing Plant

Automobile or Light—Duty Truck Refinishing

Baked Coatings

Batch Loading

Bead-Dipping

Linde rs

British Thermal Unit

Brush or Wipe Coating

SUBPART B:

DEFINITIONS

Section

211.101

211.102

Section

211.121

211.122

211.130

211 .150

211. 170

211.210

211.230

211.250

2iJ.

.290

111. 310

211.330

211.350

211.370

211. 

390

111.410

111.430

211.450

211.470

111.490

211.510

211.530

211.550

211. 570

211.590

211.610

211.630

211.650

111.670

23.1.690

111.710

111

730

211.750

111.770

7

211.790

211.810

211.830

211.850

211. 870

211.890.

211.910

211.930

211. 950

211.970

211.990

211. 1010

211. 1050

211. 1090

211.1110

211. 1130

211. 1150

211. 1170

211. 1190

211.1210

211. 1230

211. 1250

211.1270

211. 1290

211. 1310

211. 1330

211.1350

211.1370

211. 1390

211. 1410

211.1430

211.1470

211. 1490

211. 1510

211.1530

211. 1550

211.1570

211. 1590

211.1610

211. 1630

211.1650

211.1670

211.1690

211. 1710

211. 1730

211.1750

211.1770

211.1790

211.1810

211.1830

211.1850

211. 1870

Bulk Gasoline Plant

Bulk Gasoline Terminal

Can

Can Coating

Can Coating Line

Capture

Capture Device

Capture Efficiency

Capture System

Certified Investigation

Choke Loading

Clean Air Act

Cleaning and Separating Operation

Clear Coating

Clear Topcoat

Closed Purge System

Closed Vent System

Coal Refuse

Coating

Coating Applicator

Coating Line

Coating Plant

Coil Coating

Coil Coating Line

Cold Cleaning

Complete Combustion

Component

Concrete Curing Compounds

Concentrated Nitric Acid Manufacturing Process

Condensate

Condensible PM-3M

Continuous Process

Control Device

Control Device Efficiency

Conventional Soybean Crushing Source

Conveyorized Degreasing

Crude Oil

Crude Oil Gathering

Crushing

Custody Transfer

Cutback Asphalt

Daily-Weighted Average VON Content

Degreaser

Delivery Vessel

Dip Coating

Distillate Fuel Oil

Drum

Dry Cleaning Operation or Dry Cleaning Facility

Dump-Pit Area

Effective Grate Area

Effluent Water Separator

8

211.1890

211.1910

211. 1930

211.1950

211. 1970

211.1990

211.2010

211. 2050

211.2070

211.2090

211.2110

211.2130

211.2150

211.2170

211.2190

211.2210

211.2230

211.2250

211.2270

211.2310

211.2330

211.2350

211.2370

211.2390

211.2410

211.2430

211.2450

211.2470

211.2490

211. 2510

211.2530

211.2550

211.2570

211.2590

211.2650

211.2670

211.2690

211.2710

211.2730

211.2750

211.2770

211.2790

211.2810

211.2830

211.2850

211.2870

211.2890

211. 2910

211.2930

211.2950

Electrostatic Bell or Disc Spray

Electrostatic Spray

Emission Rate

Emission Unit

Ename

Enclose

End Sealing Compound Coat

Ethanol Blend Gasoline

Excess Air

Excessive Release

Existing Grain-Drying Operation

Existing Grain-Handling Operation

Exterior Base Coat

Exterior End Coat

External Floating Roof

Extreme Performance Coating

Fabric Coating

Fabric Coating Line

Federally Enforceable Limitations

and Conditions

Final Repair Coat

Firebox

Fixed-Roof Tank

Flexographic Printing

Flexographic Printing Line

Floating Roof

Fountain Solution

Freeboard Height

Fuel Combustion Emission Unit or Fuel Combustion

Emission Source

Fugitive Particulate Matter

Full Operating Flowrate

Gas Service

GasJ Gas Method

Gasoline

Gasoline Dispensing Operation or Gasoline Dispensing

Faci l~y

Grain

Grain-Drying Operation

Grain-Handling and Conditioning Operation

Grain-Handling Operation

Green-Tire Spraying

Green Tires

Gross Heating Value

Gross Vehicle Weight Rating

Heated Airless Spray

Heatset

Heatset-Web-Offset Lithographic Printing Line

Heavy Liquid

Heavy Metals

Heavy Off-Highway Vehicle Products

Heavy Off-Highway Vehicle Products Coating

Heavy Off-Highway Vehicle Products Coating Line

9

211.2970 High Temperature Aluminum Coating

211.2990 

High Volume Low Pressure (HVLP) Spray

211.3010

Hood

211.3030 Hot Well

211.3050 Housekeeping Practices

211.3070 Incinerator

211.3090 Indirect Heat Transfer

211.3110 

211.3130 In-Process Tank

211.3150 In—Situ Sampling SYstems

211.3170 Interior Body Spray Coat

211.3190 Internal-Floating Roof

211.3210 Internal Transferring Area

211.3230 Lacquers

211.3250 Large Appliance

211.3270

Large Appliance Coating

211.3290 Large Appliance Coating Line

211.3310

Light Liquid

211.3330 Light-Duty Truck

211.3350 Light Oil

211.3370

Liquid/Gas Method

211.3390 Liquid—Mounted Seal

211.3410 Liquid Service

211.3430 Liquids Dripping

211.3450 Lithographic Printing Line

211.3470 Load-Out Area

211.3490 Low Solvent Coating

211.3510 Magnet Wire

211.3530 Magnet Wire Coating

211.3550 Magnet Wire Coating Line

211.3570 Malor Dump Pit

211.3590 Malor Metropolitan Area (MMA)

211.3610 Major Population Area (NPA)

211.3630

Manufacturing Process

211.3650 Marine Terminal

211.3670 Material Recovery Section

211.3690 Maximum Theoretical Emissions

211.3710 Metal Furniture

211.3730

Metal Furniture Coating

211.3750 Metal Furniture Coating Line

211.3770 MetaLic_Shoe—Type Seal

211.3790 Miscej.),aneous Fabricated Product Manufacturing Process

211.3810 Miscellaneous Formulation Manufacturing Process

211.3830 Miscellaneous Metal Parts and Products

211.3850 Miscellaneous Metal Parts and Products Coating

211.3870 Miscellaneous Metal Parts or Products Coating Line

211.3890 Miscellaneous Organic Chemical Manufacturing Process

211.3910 Mixing Operation

211.3930 Monitor

211.3970 Multiple Package Coating

211.3990 New Grain-Drying Operation

211.4010 New Grain-Handling Operation

10

211.4030

211.4050

211.4070

211.4090

211.4110

211.4130

211.4150

211.4170

211.4190

211.4210

211.4230

211.4250

211.4270

211.4290

211.4310

211.4330

211.4350

211.4370

211.4390

211.4410

211.4430

211.4450

211.4470

211.4490

211.4510

211.4530

211.4550

211.4590

211.4610

211.4630

211.4650

211.4670

211.4690

211.4710

211.4730

211.4750

211.4770

211.4790

211.4810

211.4870

211.4890

211.4910

211.4930

211.4950

211.4990

211.5030

211.5050

211.5070

No Detectable Volatile Organic Material Emissions

Non—contact Process Water Cooling Tower

Offset

One Hundred Percent Acid

One-Turn Storage Space

Opacity

Opague Stains

Open Top Vapor Degreasing

Open-Ended Valve

Operator of a Gasoline Dispensing Operation or Operator

of a Gasoline Dispensing Facility

Organic Compound

Organic Material and Organic Materials

Organic Vapor

Oven

Overall Control

Overvarnish

Owner of a Gasoline Dispensing Operation or Owner of a

Gasoline Dispensing Facility

Owner or Operator

Packaging Rotogravure Printing

Packaging Rotogravure Printing Line

Pail

Paint Manufacturing Source or Paint Manufacturing Plant

Paper Coating

Paper Coating Line

Particulate

Matter

Parts Per Million (Volume) or PPM (Vol)

Person

Petroleum

Petroleum Liquid

Petroleum Refinery

Pharmaceutical

Pharmaceutical Coating Operation

Photochemically

Reactive Material

Pigmented Coatings

Plant

Plasticizers

PM-10

Pneumatic Rubber Tire Manufacture

Polybasic Organic Acid Partial Oxidation Manufacturing

Process

Polystyrene Plant

Polystyrene Resin

Portable Grain-Handling Equipment

Portland Cement Manufacturing Process Emission Source

Portland Cement Process or Portland Cement

Manufacturing Plant

Power Driven Fastener Coating

Pressure Release

Pressure Tank

Prime Coat

11

211.5090

211. 5110

211.5130

211.5150

211.5170

211.5185

211.5190

211.5210

211.5230

211.5250

211.5270

211.5310

211.5330

211.5350

211.5370

211.5410

211.5430

211.5450

211.5470

211.5490

211.5510

211.5550

211.5570

211.5590

211.5610

211.5630

211.5650

211.5670

211.5690

211.5710

211.5730

211.5750

211.5770

211.5790

211.5810

211.5830

211.5850

211.5870

211.5890

211.5910

211.5930

211.5950

211.5970

211.5990

211.6010

211.6030

211.6050

211.6070

211.6090

211.6130

211.6150

211. 6190

Primer Surfacer Coat

Primer Surfacer Operation

Primers

Printing

Printing Line

Process Emission Source

Process Emission Unit

Process Unit

Process Unit Shutdown

Process Weight Rate

Production Equipment Exhaust System

Publication Rotogravure Printing Line

Pur~ed Process Fluid

Reactor

Reasonably Available Control Technolo~v

(RACT)

Refiner

Refinery Fuel Gas

Refinery Fuel Gas System

Refinery Unit or Refinery Process Unit

Refrigerated Condenser

Reid Vapor Pressure

Repair Coat

Repaired

Residual Fuel Oil

Restricted Area

Retail Outlet

Ringelmann Chart

Roadway

Roll Coater

Roll Coating

Roll Printer

Roll Printing

Rotogravure Printing

Rotogravure Printing Line

Safety Relief Valve

Sandblasting

Sanding Sealers

Screening

Sealer

Semi—Transparent Stains

Sensor

Set of Safety Relief Valves

Sheet Basecoat

Shotblasting

Side-Seam Spray

Coat

Smoke

Smokeless Flare

Solvent

Solvent Cleaning

Source

Specialty High Gloss Catalyzed Coating

Specialty Soybean Crushing Source

12

211. 6210

211.6230

211.6270

211.6290

211. 6310

211.6330

211.6350

211.6370

211.6390

211.6410

211.6430

211.6450

211.6470

211.6490

211.6510

211.6530

211. 6550

211.6570

211.6590

211.6610

211.6670

211.6690

211.6730

211.6750

211.6770

211. 6790

211.6810

211.6850

211.6870

211.6890

211. 6910

211.6930

211.6950

211.6970

211.6990

211.7010

211.7030

211.7070

211.7090

211.7110

211.7130

211.7150

211.7170

211.7190

211.7210

211.7230

211.7250

211.7270

211.7290

211. 7310

Splash Loading

Stack

Standard Conditions

Standard Cubic Foot (scf)

Start -Up

Stationary Emission Source

Stationary Emission Unit

Stationary Source

Stationary Storage Tank

Storage Tank or Storage Vessel

Styrene Devolatilizer Unit

Styrene Recovery Unit

Submerged Loading Pipe

Substrate

Sulfuric Acid Mist

Surface Condenser

Synthetic Organic Chemical or Polymer Manufacturing

Plant

Tablet Coating Operation

Thirty-Day Rolling Average

Three-Piece Can

Topcoat

Topcoat Operation

Transfer Efficiency

Tread End Cementing

True Vapor Pressure

Turnaround

Two-Piece Can

Undertread Cementing

Unregulated Safety Relief Valve

Vacuum Producing System

Vacuum Service

Valves Not Externally Regulated

Vapor Balance System

Vapor Collection System

Vapor Control System

Vapor-Mounted Primary Seal

Vapor Recovery System

Vinyl Coating

Vinyl Coating Line

Volatile Organic Liquid (VOL)

Volatile Organic Material Content (VOMC)

Volatile Organic Material (VOM) or Volatile Organic

Compound (VOC)

Volatile Petroleum Liquid

Wash Coat

Wastewater (Oil/Water) Separator

Weak Nitric Acid Manufacturing Process

Web

Wholesale Purchase

Consumer

Wood_Furniture

Wood Furniture Coating

13

211.7330 Wood Furniture Coating Line

211.7350

Woodworking

211.Appendix A   

Rule into Section Table

211.Appendix B   

Section into Rule Table

AUTHORITY: Implementing Sections 9 and 10 and authorized by

Section 27 and 28.5 of the Environmental Protection Act (Ill.

Rev. Stat. 1991, ch. 111½, pars. 1009, 1010 and 1027), (P.A. 87—

1213, effective September 26, 1992) 415 ILCS 5/9, 10, 27 and

28.5).

SOURCE: Adopted as Chapter 2: Air Pollution, Rule 201:

Definitions, R71—23, 4 PCB 191, filed and effective April 14,

1972; amended in R74—2 and R75—5, 32 PCB 295, at 3 Ill. Reg. 5,

p. 777, effective February 3, 1979; amended in R78-3 and 4, 35

PCB 75 and 243, at 3 Ill. Reg. 30, p. 124, effective July 28,

1979; amended in R80-5, at 7 Ill. Reg. 1244, effective January

21, 1983; codified at 7 Ill. Reg. 13590; amended in R82—l (Docket

A) at 10 Ill. Reg. 12624, effective July 7, 1986; amended in

R85—21(A) at 11 Ill. Reg. 11747, effective June 29, 1987; amended

in R86—34 at 11 Ill. Reg. 12267, effective July 10, 1987; amended

in R86—39 at 11 Ill. Reg. 20804, effective December 14, 1987;

amended in R82-14 and R86-37 at 12 Ill. Reg. 787, effective

December 24, 1987; amended in R86—l8 at 12 111. Reg. 7284,

effective April 8, 1988; amended in R86—10 at 12 Ill. Reg. 7621,

effective April 11, 1988; amended in R88—23 at 13 Ill. Reg.

10862, effective June 27, 1989; amended in R89-8 at 13 Ill. Reg.

17457, effective January 1, 1990; amended in R89—16(A) at 14 Ill.

Reg. 9141, effective May 23, 1990; amended in R88—30(B) at 15

Ill. Reg. 5223, effective March 28, 1991; amended in R88—14 at 15

Ill. Reg. 7901, effective May 14, 1991; amended in R91—10 at 15

Ill. Reg. 15564, effective October 11, 1991; amended in R9l—6 at

15 Ill. Reg. 15673, effective

October 14, 1991; amended in R91—22

at 16 Ill. Reg. 7656, effective

May 1, 1992; amended in R91—24 at

16 Ill. Reg. 13526, effective August 24, 1992;

amended in R93—

at 17 Ill. Reg. 

______

effective

_____________________

Section 211.102

Abbreviations and Units

a)  Abbreviations used in this Part include the following:

ASTM     

American Society for Testing and

Materials

barrels (42 gallons)

btu

British thermal units (60°F)

degrees Celsius or centigrade

centimeters

cu in      

cubic inches

°F

degrees Fahrenheit

fl~

Federal Implementation Plan

14

ft

feet

ft2

square feet

g

grams

gallons per minute

g/mole    

grams per mole

~l1ons

hr

hours

in

inch

°K

degrees Kelvin

kcal     

kilocalories

kg

kilograms

kg/hr     

kilograms per hour

kPa

kilopascals; one thousand newtons per

square meter

1

liters

1/sec     

liters per second

lbs

pounds

lbs/hr    

pounds per hour

lbs/gal    

pounds per gallon

LEL

lower explosive limit

3fl

meters

in2

square meters

In3

cubic meters

milligrams

Mg

Megagrams. metric tons or tonnes

ml

milliliters

mm

minutes

megaloules

mmHg     

millimeters of mercury

~IQQ    

natural draft opening

ppm (vol)   

parts per million

ppmv     

parts per million by volume

psi

pounds per square inch

psia     

pounds per square inch absolute

psig     

pounds per square inch gauge

RACT     

reasonably available control technology

scf

standard cubic feet

scm

standard cubic meters

sec

seconds

SIP

State Implementation Plan

TTE

temporary total enclosure

sq cm     

square centimeters

sq in      

sguare inches

T

short ton (2.000 Ibs)

ton

short ton (2,000 lbs)

USEPA     

United States Environmental Protection

Agency

VOC

volatile organic compounds

~LQJd   

volatile organic liquids

VOM

volatile organic materials

b)  The following conversion factors are used in this Part.

English    

Metric

1 gal     

3.785 1

1.0001

psia

~al

6.8973,785 kPa1

or

(51.713.785 

mntHg)

in3

2.205 lbs

1 kg

32°    

0°C 

(273.150

K)

1 bbl     

159.0 1

1 Cu in     

16.39 ml

1 lb/gal   

119,800 mg/l

1 ton    

0.907 Mg

iT

0.907 Mg

(Source: Amended at  

Ill. Reg. 

______,

effective 

________

SUBPART B: DEFINITIONS

Section 211.121  

Other Definitions

All terms defined in 35 Ill. Adin. Code 201 which appear in 35

Ill. Adin. Code 211 

—

217 through 219 have the definitions

specified by 35 Ill. Adm.

Code 201.102. Otherwise the

definitions in 

Section

211.122 this Part shall apply.

(Source: Amended at  

Ill. Reg. 

______,

effective 

________

Section 211.122  

Definitions (Repealed)

“Accclacota”: a pharmaceutical coating operation 

which

consists of a horizontally 

rotating perforated drum in

which tablets are placed, a coating is 

applied by

spraying and the coating is dried by the flow of air

across the drum through the perforations.

“Accumulator”: The reservoir of a condensing unit

receiving the condensate from a surface condenser.

“Acid Cases”: For the purposes of Ccction 9.4 of the

Environmental Protection Act (thc Act) (Ill. Rcv. Stat.

1987, oh. 111½, par. 1009.4), hydrogen chloride,

hydrogen fluoride and hydrogen bromide, which exist as

gases, liquid mist, or any combination thereof.

“Actual Heat Input”: The quantity of

heat produced by

the combustion of fuel using the gross hooting

value of

the fuel.

16

“Aeration”:

The practice of

forcing air through bulk

stored grain to maintain the condition of the grain.

“Afterburner”: A device in which materials in gaseous

effluents arc combustcd.

IT •1

I~~fl I

‘‘

sating”:

air at ~

“Air suspension coatcr/drycr”: a pharmaceutical

coating operation which consists of vertical chambers

in which tablets or particles arc placed, arid a coating

is applied and then dried while the tablets or

particles arc kept in a fluidized state by the passage

of air upward through the chambers.

“Annual Grain Through-Put”: Unless otherwise shown by

the owner or operator, annual grain through-put for

grain-handling operations, which have been in operation

for threc consecutive years- prior 

to June 30, 1975,

shall be determined by adding grain receipts and

shipments for the three previous fiscal years and

dividing the total by 6. The annual grain through-put

for grain-handling operations in operation for less

than three consecutive years prior to June 

30, 1975,

shall bc determined by a reasonable three—year

estimate; the owner or

operator shall document the

reasonableness of his three-year estimate.

“Architectural Coating”:

Any coating used for

residential

or commercial buildings or their

appurtenances,

or for industrial

buildings which is

site applied.

“Asphalt”: The dark—brown to black ccmcntitious

material (solid, semisolid or 

liquid in

consistcncv’~ r~F

i.zh~h tlit’

m~ ~  -‘-~-1~ucntsarc bituincns

-LI

naturally or as a residue of petroleum refining.

‘tAspha It Pr i

1 4-

viscosity

liquid asphalt

~Automobi1c”: 

Any fi rot division motor vchiolo as that

term is defined in the Illinois

Vehicle Code (Ill.

Rev.

Stat. 1987, oh. 95½, pars 1—100 et seq.).

“AutomobiL..  Light-Duty Truck Nanufa ~  

Plant”.

A facility where parts are manufactured or finished for

eventual inclusion into a finished automobile or

li-ght-duty truck ready for ~a1e to vehicle dealers,

but

~oati..

e.nrncra

~gr

tna’c 

dry by the usc of

~ to 363.15° K

(194°

not including customizers, body

rcpaintcrs.

“Automobile or Light Duty Truck Ref iniohing”:

The

repainting of used automobiles or

light duty trucks.

“Batch Loading”: The process of loading 

a number of

individual parts at the same time 

for dcgrcasing.

“Bead-Dipping”:

The dipping of an aasoinblcd tire bead

into a solvcnt—bascd cement.

“British Thermal Unit”: The quantity of heat required

to raise one pound of water from 60°F to 

610

F

(abbreviated btu).

“Bulk Gasoline Plant”: Any gasoline storage and

distribution facility that receives gasoline from bulk

gasoline terminals by delivery vessels and distributes

gasoline to gasoline dispensing facilities.

“Bulk Casoline Terminal”: Any gasoline storag.c and

distribution facility that receives gasoline by

pipeline, ship or barge, and distributes gasoline to

bulk gasoline plants or gasoline dispensing facilities.

“Can Coating”:

The application of a coating material

to a single walled container that is manufactured from

metal sheets thinner than 29 gauge (0.0141 in).

..r

1 (1Ti

rc’

1 r

ririr’tl by Illirtr~ii’~

‘

“Ccr~4~edIn4-g~t~..”

Environmental Protection Agency (Agency, personnc...

certifying whether a grain-handling operation (or

portion thereof) or grain—drying operation is causing

or tending to cause air pollution. Such report must

describe the signatory’s investigation, including a

summary of those facts on which

he relics to certify

whether the grain-handling or grain-drying operation is

causing or threatening or allowing the discharge or

omission 

of any contaminant into

the environment so as

to cause or tend to cause air pollution in Illinois,

either alone or in combination with contaminants from

other sources, or so as to violate regulations or

~tn~d~

i-trir~fr’d by 

thr~

Pollution Control Board

(Board) und the EnvL    

Protection Act (Act).

The certified investigation shall be open to a

reasonable public inspection and may be copied 

payment of the actual cost of reproducing the original.

“Choke Loading”: That method of transferring grain

from the grain-handling operation to any vehicle for

shipment or delivery which precludes a free fall

18

velocity of grain from ~

receiving container.

ge spout into the

“Cleaning and Separating Opcr

L..Jt_rI’

-~—,-—...‘

~gf~

,.....~

“-Coating Plant”: Any building, structure or

installation that contains a coating line and which is

located on one or more contiguous or adjacent

properties and which is- owned or operated by the same

-common

control’~

-unacoircu

~.~~ances are removed r~~mm

the grain.

“Clear Coating”: Coatings that lack color and opacity

or arc transparent using the undercoat as a reflcctant

base or undertone color.

“Closed Purge System”: A system that is not open to

the atmosphere and that is composed of piping,

connections, and, if necessary, flow inducing devices

that transport liquid or vapor from a piece or pieces

of equipment to ~ control device, or return the liquid

or vapor to the process line.

“Closed Vent 

System”: 

A system that is not 

O~Cfl

to the

atmosphere and that is composed of piping, connections,

and, if necessary, flow inducing devices that transport

gas

-or

vapor from a piece or pieces of equipment to a

control device,

or return the gas or vapor to the

process line.

‘tCoal Refuse”: Waste products of coal mining, cleaning

arid coal preparation operations containing coal, matrix

material, clay arid other organic and inorganic

material.

“Cociting”: For

p”~~rn~

z-~

th~

coating

.~atcri..... applied to a substrate for

decorative, protcctivc or other functional purposes.

Such material shall include, but arc not limited to

paints, varnishes, scalers, adhesives, diluents and

t-hinncrs.

“Coating Applicator”: Equipment used to apply a

surface coating.

“-Coating Line”: An operation where a surface coating

is applied to a material and subsequently the. coating

is dried and/or curod.

pe~-’-~i(or by ~e-r

19

“Coil Coating”: The application of -a coating mate-rial

to any flat metal sheet or strip that comes in rolls or

coils.

“Cold Clcaning”~ The process of cleaning and removing

soils from surfaces by spraying, brushing, flushing or

immersion while maintaining the organic solvent-below

its boiling point, Wipe cleaning is not included in

this definition.

“Complete Combustion”: A process in which all carbon

contained in a fuel or gas stream is converted to

carbon dioxide.

“Component”: Any piece of equi-pnuent which has the

potential to leak volatile organic material including,

but not limited to, pump seals, compressor scale, seal

oil dcgassing vents, pipeline valves, pressure relief

devices, process drains and open ended valves. This

definition excludes valves which are not externally

regulated, flanges, and equipment in heavy

liquid

s-crvice. For purposes of 35 Ill. Mm. Code 215.

Subpart Q, this definition also excludes bleed ports of

gear pumps in polymer service.

“Concentrated Nitric Acid Manufacturing Process”: Any

acid producing facility manufacturing nitric acid with

a concentration equal to or greater than 70 percent by

weight.

“Condensate

associated

“:

Hydrocar

gasses which

hon

con

liquid separated

denses due to ch

from its

angcs in the

temperature or pressure and remains liquid 

at standard

conditions.

“Condcnsiblc PM 10”! PH-b formed immediately or

shortly after discharge to the atmosphere, 

as measured

by the ~applicabletest method specified in 35 Ill. Adm.

Code 212.110. Condensibic particulate i~attcrexists in

gaseous and/or vapor form prior to release to the

atmosphere, e.g., in the stack, and forms particulate

matter upon condensation when subject to conditions -ef

cooling and dilution in the atmosphere.

“Control Device”: Equipment, such as an afterburner,

adoorber, scrubber, condenser, cyclone or baghouse used

to remove or prevent the emission of air pollutants

from a contaminated exhaust stream. For purposes of 35

Ill. Adin. Code 215, Subpart Q, an enclosed combustion

device, vapor recovery system, flare, or closed

container.

20

“Cenvcyoriced Degrcasing”i The continuous process of

cleaning and removing soils from surfaces utilizing

cither cold or vaporized o-olvents.

“Crude Oil”: A naturally occurring mixture which

consists of hydrocarbons and sulfur, nitrogen or oxygen

derivatives of hydrocarbons and which is cx liquid at

standard conditions.

“Crude Oil Gathering”: The transportation of crude oil

or condensate after custody transfer between a

production facility and a reception point.

“Crushing”: The fragmentation of non-metallic minerals

by a machine such as a jaw, gyratory, cone, roll, rod,

mill, hammcrinill, and

irnpactor.

petT-~

~~ting in

“Cutback Asphalt”: Any asphalt which has been

liquified by blending with pctrolcum solvents other

than residual 

fuel oil and has riot been emulsified with

water.

“Degreaser”: Any equipment or system used in solvent

cleaning.

‘-‘flr~I 

4i.,i~rv Vr-~’tr’1

‘~

~tn-t~ f~ir,1-( tTr’Tr

c~r

trail

f-r_ 1~’

~quippcd

with a storage tank that is used for the transport of

gasoline to a stationary storage tank at a gasoline

dispensing facility, bulk gasoline plant or bulk

gasoline terminal.

“Distillate Fuel Oil”: Fuel oils of

grade No. 1 or 2

as specified in detailed requirements for fuel oil

A.C.T.N. D—369—69 (1971).

“Dry Cleaning Facility”: A facility engaged in the

cleaning of fabrics using an essentially nonaqucous

solvent by—means of one or more solvent washes,

extraction of excess solvent by spinning 

and drying

by

tumbling in an airotream. The facility includes, but

is not limited to, washers, dryers, filter and

purification systems, waste disposal systems, holding

tanks, pumps -end attendant piping and valves.

“Cu3tc~dy

Transfer”: The transfer of

r~rnm

onator conacnsatc aitcr

processing and/or ~

the producing operations, from storage tanks

automatic transfer facilities to pipelines or any other

forms of transportation.

“Dump-Pit Area”: Any area where grain is received at-a

grain-handling or grain—drying operation.

21

“Effective Crate Area”: That area of a dump-pit grate

through which air passes, or would pass, whe~n

aspirated.

“Effluent Water Separator”: Any tank, box, sump or

other apparatus in which any organic material floating

on or entrained or contained in water entering ouch

tank, box, suxnp or other apparatus is physically

separated and removed from such water prior to outfall,

drainage or recovery of such water.

-“Emission Rate”: Total quantity of any air contaminant

discharge into the atmosphere in any one-hour period.

“Enclose”: With respect to 35 Ill. Adm. Code 215

Subpart T, to cover any volatile organic liquid surface

that is exposed to the atmosphere.

“End Scaling Compound Coat”: A compound applied to can

endc

which funetionr~co ~ aacket when the end is

—

~__t~

.1 —

A_ 1~

‘F

4.—fl

•

4 ~

- 4 -~

4 4.~4

-“Exterior Base Coat”: An initial coating applied to

the exterior of a can after the can body has been

formed.

“Exterior 

End Coat”! A coating

+ri

I-br’

rI-r’i~4r,r

r’nr~ r~f

applied by rollers

or

sprayi..~

“External Floating Roof”! A storage vessel cover in an

open top tank consisting of a double dock or pontoon

aingir’ ~~r’r,k

uhir’h

rirt~’d

h’~r th~

petroleum liquid

being contained and 

i-s

equipped with ciosure 

secu.

between the deck edge and tank wall.

theoretical quantity ncccssary for complete combustion

of all fuel and/or combustible waste material.

“Excessive Release”: A discharge of more than 295g

(0.65 pounds) of mercaptans or hydrogen sulfide into

the atmosphere in any five minute period.

“Existing Grain-Drying Operation”: Any grain-drying

operation the construction or modification of which

cp~~~need nrior

te

June 30. 1975.

was

“Existing er.-~~i

grain-handling opcrcxtior

modification of which wc...~

1975.

4-..-

. --

commenced prior to June 30,

22

“Extrome Performance Coating”: Coatings designed for

exposure to any of the following: the ambient weather

conditions, temperatures above 366.150 K (203° F),

detergents, abrasive and scouring agents, solvents,

corrosive atmospheres, or other similar extreme

environmental conditions.

“Fabric Coating”: The coating of a textile substrate,

including operations where the coating impregnates the

substrate.

“Final Repair Coat”: The repainting of any coating

which is damaged during vehicle assembly.

“Firebox”: The chamber or compartment of a boiler or

furnace in which materials arc burned, but not the

combustion chamber or afterburner of an incinerator.

“Flcxographic Printing”: The application of words,

designs and pictures to a substrate by means of a roll

printing technique in which the pattern to be applied

is raised above the printing roll and the image carrier

is made of elastomcric materials.

“Floating Roof”: A roof on a stationary tank,

reservoir or other container which moves vertically

upon change in volume of the stored material.

“Freeboard Height”: For open top vapor degrcciriers, the

distance from the top of the vapor zone to the top of

the degreaser tank. For cold cleaning degreascre, the

distance from the solvent to the top of the degreaser

tank.

“Fuel Combustion

Emission Source”: Any furnace, boiler

or similar equipment used for the primary purpose of

producing heat or power by indirect heat transfer.

“Fuel Gas System”: A system for collection of refinery

fuel gas including, but not limited to, piping for

collecting tail gas from various process units, mixing

drums arid controls and distribution piping.

“Fugitive Particulate Matter”: Any particulate matt~

emitted into the atmosphere other than through a stack,

provided that nothing in this definition or in 35 111.

Adm. Code 212.Gubpart K shall exempt any source from

compliance with other provisions of 35 Ill. Adm. Code

212 otherwise applicable merely because of the absence

of a stack.

23

“Gas Service”: Means 

thr~I-

proues~ 

L.Luia

cn~ i~

intnega~3couS3tcLtc at operating

conditions.

“Casoline”: Any petroleum distillate having a Reid

vapor pressure of 4 pounds or greater.

“Casoline Dispensing Facility”: Any site where

gasoline is transferred from a stationary storage tank

to a motor vehicle gasoline tank used to provide fuel

to the engine of that motor ~vchiole.

“Cram”: The whole kernel or aced of porn, wheat,

oats, soybeans and any other cereal or oil seed plant;

and the normal fines, dust and foreign matter which

results from harvesting, handling or conditioning. The

grain shall be unaltered by grinding or processing.

“Cram-Drying Operation”: Any operation, excluding

aeration, by which moisture is removed from grain and

which typically

Uses

forced ventilation with the

~rfr1iI-ir~n

r~f

hr’nt-

“Grain

-~4~

and C C~tioni~C.~~c~&’-: ~

storage facility and its associate grain transfer,

cleaning, drying, grinding and mixing operations.

“Grain-Handling Operation”: Any operation where one or

more of the following grain—related processes (other

than grain-drying operation, portable grain-handling

equipment, one-turn storage space,

and excluding flour

mills and feed mills) are performed: receiving,

shipping, transferring, storing, mixing or treating of

grain or other processes pursuant to normal grain

operations.

“Crcen Tire Spraying”: The spraying of green tires,

both inside and outside, with release compounds which

help remove air from the tire during molding and

prevent the tire from sticking to the mold after

curing.

“Crecn Tires”: Assembled tires before molding rind

curing have occurred.

“Cross Heating Value”: Amount of heat produced when a

unit quantity of fuel is burned to carbon dioxide and

water vapor, and the water vapor condensed as described

in

A.C.T.M. 

D—20l5-66, D—900—55, D—1626-64 and

D—240—64

24

“Heavy Liquid”: Liquid with a true vapor pressure of

less than 0.3 kra (0.04 psi) at 

294.30

K (700 F) or 0.1

Reid Vapor Pressure as determined by 

A.C.T.H. 

method

D-323~ or which when distilled requires a temperature

of

3000

F or greater to recover 10 of the liquid as

determined by A.C.T.M. method D 66.

“Heavy Metals”: For the purposes of Section 9.4 of the

Act, elemental, ionic, or combined forms of arsenic,

cadmium, mercury, chromium, nickel and lead.

-“Heavy, Off-Highway Vehicle Products”: For the

purposes of Section 215.204(k), heavy off-highway

vehicle products ehall include: heavy construction,

mining, farming or material handling cquipmenty heavy

industrial engines; diesel-electric locomotives rind

associated power generation equipment; and the

component-s of such equipment or engines.

-“~HotWell”:

The reservoir of a condensing unit

r-eceiving the condensate from a barometric condenser.

“Housekeeping Practices”! Those activities

specifically defined in the list of housekeeping

practices developed by the Joint EPA 

—

Industry Task

Force and included herein under 35 Ill. Adm. Code

212.461.

_____A_.,

burned.

-“Indirect Heat Transfer”: Transfer of heat in such a

way that the source of heat does not come into direct

contact with process materials.

“In-Process Tank”: A container used for mixing,

blending, heating, reacting, holding, crystallizing,

evaporating, or cleaning operations in the manufacture

of pharmaceuticals.

“In-situ Sampling Systems”: Noncxtractive samplers or

in—1inr~

n1r~r~.

“Interior Body Spray       

ting applied by spray

to the interior of a can rifte

formed.

“Internal Transferring Area”:

r the can oc

Areas and

ay nas ~ccn

associated

equipment used for conveying grain among the various

..4..

.‘.‘-~“

25

“Large Appliance Coating”: 

The application of a

coating material to

(including but not

the com

limited

poncnt metal parts

to doors, cases, lids.

4....i..~,...4...,..

.ipport parts) of rc3idential and

commercial wnshcrs, ctrycrB, rangos, rerr2gerat.JL-Ls,

trcczc~, 

...~aters, uj.G~W3sflCrO, 

compa~ur~,

air conditioners and other similar products.

“Light-Duty Truck”: Any second division motor vehicle,

as that term is defined in the Illinois Vehicle Code,

(Ill. Rev. Ctat. 1989, oh. 95~,pars. 1—100 at 

seq.-)

weighing less than 3854 kilograms (8500 pounds) gross.

“Liquid-Mounted 

Cecil”: 

A primary seal mounted in

continuous contact with the liquid between the tank

wall and the floatinci roef curse around the

circumference 

-~nc root.

“Liquid Service”: Means that the equipment or compo

contains process fluid that is in a liquid state at

operating conditions.

“Liquids Dripping”: Any visible

leaking from a seal

including spraying, misting, clouding and ice

formation.

“Load-Out Area”: Any area where

grain is transferred

from the grain—handling operation 

to any vehicle for

•I

“Low Solvent Coating” A coating which contains less

organic solvent than the conventional coatings used by

I-br’

inun~tr’~’

T.rtw ~ir~1vr’nI-

~ri~tir~r~ inr~’1nur’

-4-

powder cocitizuy~.

higher solids, ci

“Magnet Wire Coating”: The application

of a coating of

electrically insulating varnish or enamel to conducting

wire to be used in electrical machinery.

“Major Dump Pit”: Any dump pit with an annual grain

through—put of more than 300,000 bushels, or which

receives more than 40 of the annual grain through—put

of the grain-handling operation.

“Major Metropolitan Area (MMA)”s 

Any county or group

of counties which 

is defined by the following Table:

MAJOR METROPOLITAN AREAS IN ILLINOIS (MMA’s)

?O~A COUNTIES INCLUDED IN ~-~A

- - -

A..

- - --

26

Cook, Lake, Will, Durago,

Mdllcnry, Kane, Crundy,

Kendall, Kankakec

Peoria         

Peoria, Tacewell

Rockford      

Winnebago

Rock Island 

Moline  Rock Island

Springfield       

Cangamon

St. Louis (Illinois)   

St. Clair, Madison

Bloomington 

Normal  McLean

“Major Population Area (MPA)”:

concentration in Illinois, as

Areas of major pop

~scribed below:

The area within the counties of Cook; Lake; Duragc; Will;

the townships of Burton, Richmond, McHenry, Creonwood,

Nunda, Door, Algonquin, Crafton and the municipality of

Woodatock, plus a cone extending two miles beyond the

boundary of said municipality located in McHcnry County-;

the townships of Dundee, Rutland, Elgin, Plato, St.

Charles, Campton, Coneva, Blackberry, Batavia, Sugar

Creek and Aurora located in Kane County; and the

municipalities of Kankakec, Bradley and Bourbonnais, plus

a zone extending two miles beyond the boundaries of said

municipalities in Kankakcc County.

The area within the municipalities of Rockford and Loves

Park, plus a cone extending two miles beyond the

boundaries of said municipalities.

The circa within the municipalities of flock Island,

Nolinc, East Moline, Carbon Cliff, Milan, Oak Grove,

Cilvis, Hampton, Greenwood and Coal Valley, plus a zone

extending two miles beyond the boundaries of said

municipalities.

The

within the ~.~icipaliti~

of Calesburg and East

Calcsburg, plus a cone extending two miles beyond the

houndi~ri~-~

nf ~r~id

~i~ipauit....

1 LT~4

The area within the 

municipalities of Bartonville, Peon-a

and Peoria

beyond the

Heights, plus

boundaries of

a cone extending two

said municipalities.

miles

!rhr’ r~-r’..

within the municipauiti~ ef ~

Marquette Heights, Crevo Cocur and East Peoria, plus a

~nne

t~ndinrc tun mi1r~ hr’vnnd t~hr bnundriric~ of ~nid

)lrwI-h

~eki,,,

icipauit

27

The area within the municipalities of Bloomington 

and

Normal, plus a zone extending two miles beyond the

boundaries of said municipalities.

The area within the municipalities of Champaign, Urbana

onul F~ru~ir~.~

c~r,rur’ rPr-r,ii 

nri tt~n m’~

r’~

bcynn’l 

thr’

boundar1c~of paid 

muni~1~i~1~s.

The area within the municipalities of Decatur, Mt. Zion,

Harristown and Forsyth, plus a cone extending 

two miles

beyond the boundarics of said municipalities.

~he-

-~-‘~-‘-~—

the

~“~-‘~

Crove, Jerome, Southern View, Crandvicw, Chcrman rind

Chatham, plus a cone extending two miles beyond the

hounuaric~ of rnaid municiral itic~.

Cprinaficld. Leland

The area within the townships of Codfrey, Foster, Wood

River, Fort Russell, Choutoau, Edwardsville, Venice,

Nameoki, Alton, Cranite City and Collinaville located in

Madison County; and the townships of Ctitcs, Canteen,

Controvilic, Casoyville, Ct. Clair, Sugar Loaf and

Ctookcy located in St. Clair County.

“Manufacturing Process”: A process emission source or

~irri r’~ of r~rpcess cmi ~i on

~nurcc~

u~cd to nnnvcrt

raw

materials, feed stocks, subasscmblies or other components

into a product, either for sale or for use as a component in

a subsequent manufacturing process.

“Marine Terminal”: A facility primarily engaged in loading

and unloading watercraft.

“Metal Furniture Coating”: The application of a coating

material to any furniture piece made of metal or any metal

part which is or will be assembled with other metal, wood,

fabric, plastic or glass parts to form a furniture piece

including, but not limited to, tables, chairs, wastebaskets,

beds, desks, lookers, benches, shelving, file cabinets,

lamps and room dividers. This definition shall not apply—~e

any coating line coating metal parts or products that is

identified under the Standard Industrial Classification Code

for Major Groups 33, 34, 35, 36, 37, 38, 39, 40 or 41.

~1 —

Fabricated 

A manufacturing proc

following applicatio:

of formulations, and

material:

s involving one

including any

—‘—.44-4-4-

or more of the

ygCUr

28

Adhesi

colnpon,_.. 

-- - -

~ ......1_

—

a..

—

—, 

..~-

a.. -

cmbl

.~.!

Asphalt to paper or felt

Coatings or dye to leather

Coatings to plastic

Coatings to rubber or glass

Curing of furniture adhesives 

jn

in excess of 10 tons of volatile 

~r’c,.1r1

year if no air pollution control

Plastic foam

foam ~

pellets

Re-s i.. 

~..rl-~i~i—~_.z

ia-

n_si

The usc and handling of organic liquids and other

substances for clean-up operations associated with the

nrn~r’~~

uir’—~r’ri

hc’ri ~hnu-c’

—--~

——-..~-

i.rr~litilr’

which would emit

~  material per

~ment 

wcrc u~cu

4.1......

scrap or “fluff” fro-in the manufacture of

~tni~ ~

anti

packaging 

mafcr

ii

to form

yr-~ir,

to fiber ~ubtanue.

z~ui.wer ~

to molds

Viscose solutions for food ~

The storage and handling of formulations associated with

the process described above.

“Miscellaneous Formulation Manufacturing Process”:

A manufacturing process which compounds one or more of

the following and is capable of

enganic material:

Adhesives

Asphalt solutions

Caulks, scalants or waterproofing agents

Coatings, other than paint and ink

Dyes

Friction materials and

29

Rubber solutions

or~o~tc

noli,t-ion~,

The storage and handling of formulations associated with

the process described above.

The use rind handling of organic liquids and other

substances for clean—up operations associated with the

process described above.

“Miscellaneous Metal Parts and Products”: For the purpose

of 35 Ill. Adm. Code 215.204, miscellaneous metal parts and

products shall include farm machinery, garden machinery,

small appliances, commercial machinery, industrial

machinery, fabricated metal products and any other

industrial category which coats metal parts or products

under the Standard Industrial Classification Code for Major

Croups 33, 34, 35, 36, 37, 38 or 39 with the exception of

the following: coating lines subject to 35 Ill. Adm. Code

215.204-(a)-(i) and (k), automobile or light duty truck

refinishing, the exterior of marine vessels and the

customized top coating of automobiles and trucks if

production is less than thirty five vehicles per day.

“Miscellaneous Organic Chemical Manufacturing Process”:

A manufacturing process which produces by chemical

reaction, one or more of the following organic compounds

or mixtures of organic compounds and which is capable of

emitting volatile organic materials:

Chemicals listed in 35 Ill. Adm. Code 215. Appendix D.

Chlorinated and oulfonated compounds

(~o~imr’tir’

,is-trr-ir.nl-,

soap or surfactant intermediaries -O±~

specialties and proaucts

Disinfectants

Food additives

Oil and petrol

Plasticizers

Resins or polymers

Rubber additives

Sweeteners

Varnishes

30

The storage and handling of formulations associated with

the process described above.

The use and handling of organic liquids and other

substances for clean-up operations associated with the

process described above.

“Mixing Operation”: The operation of combining two or more

ingredients, of which at least one is a grain.

“New Cram-Drying Operation”: Any grain drying operation

the construction or modification of which is commenced on or

after June 30, 1975.

“New Cram-Handling Operation”: Any grain-handling

operation the construction of modification of which is

commenced on or after June 30, 1975.

“No Detectable Volatile Organic Material Emissions”: A

discharge of volatile organic material into the atmosphere

as indicated by an instrument reading of less than 500 ppm

above background as determined in accordance with 40 CFR

60.485(c).

“One Hundred Percent Acid”: Acid with a specific gravity of

1.8205 at 30° C in the case of sulfuric acid and 1.4952 at

~O° C in the case of nitric acid.

“One-Turn Storage Space”: That space used to store grain

with a total annual through-put not in excess of the total

bushel storage of that space.

Ilopacity”, A condition which renders material partially or

wholly imp-ervious to transmittance of light and causes

obstruction of an observer’s view. For the purposes of

these regulations, the following equivalence between opacity

rind Ringelmann shall be employed:

Opacity   

Ringclmann

.1.0

in

.1~.,

ACl

..~

60

3.

50

4.

1nr~

“Open Top Vapor Degreasing”: The batch process of cleaning

ai~dremoving soils from surfaces by condensing hot solvent

v~aporon the colder metal parts.

“Operator of Casolino Dispensing Facility”t Any person who

is the lessee of or operates, controls or supervises a

gasoline dispensing facility.

“Organic Compound”: Any compound of carbon, excluding

carbon monoxide, carbon dioxide, carbonic acid, metal

carbides or carbonates, and anunonium carbonate.

“Organic Material”: Any chemical compound of carbon

in-eluding diluents and thinners which arc liquids at

standard conditions and which arc used as dissolvors,

viscosity reducers or cleaning agents, but excluding

methane, carbon monoxide, carbon dioxide, carbonic acid,

metallic carbonic acid, metallic carbide, metallic

e-arbonates and ammonium carbonate.

“Organic Materials”: For the purposes of Section 9.4 of the

A-e-t,

any chemical compound of carbon, including diluonts and

thinners which

arc liquids at standard conditions and which

arc used as dissolvers, viscosity reducers or cleaning

agents, and polychlorinated dibcnzo-p-dioxins,

pe-lychlorinatcd dibenzofurans and polynuclear aromatic

hydrocarbons arc organic materials, while methane, carbon

monoxide, carbon dioxide, carbonic acid, metallic carbonic

ge-id,

metallic carbide, metallic carbonates rind ammoniuri

e-a-rbonatc arc not organic materials.

Ilorganic Vapor”: Cascous phase of an organic material or a

m-3cture of organic materials present in the atmosphere.

1IOz.rprvarnish”l A coating applied directly over ink or

printing.

“-Owner of Gasoline Dispensing Facility”: Any person who has

-1-egal

or equitable title to a stationary storage tank at a

gasoline dispensing facility.

“Packaging Rotogravure Printing”: Rotogravure printing upe~

p-apcr, paper board, metal foil, plastic film and other

substrates, which are, in subsequent operations, formod i-ste

packaging products or labels for articles to be sold.

31

“Paint Manufacturing Plant”: A plant that mixes, blends, er

compounds enamels, lacquers, sealors, shollacs, stains,

varnishes or pigmented surface coatings.

“Paper Coating”: The application of a coating material to

paper or pressure sensitive tapes, regardless of substrateT

including web coating on plastic fibers and decorative

coatings on metal foil.

“-Particulate Matter”: Any solid or liquid material, other

than water, which exists in finely divided form.

“Petroleum Liquid”: Crude oil, condensate or any fIni~hcd

or intermediate product manufactured at a petroleum

refinery, but not including Number 2 through Number 6 fuel

oils as specified in A.C.T.H. D-396-69,gas turbine fuel oils

Numbers 2-CT through 4 CT as specified in A.C.TJI. D-2580-7l

or diesel fuel oils Numbers 2-D and 4-D, as specified in

A.S.T.M. D—975—68.

“Petroleum Refinery”: Any facility engaged in producing

i nc, 

kcr~r’nr~ - ti

i ~t i 1 1 

aFt’

fnt’l oi 1 

~z - rt’~I

i dna 1 fn~1

distillati~..,

e~.,.,, cxtractL.. or reformi....~, 

..~

unfinished petroleum

derivatives.

... ,

-‘~~o-auct

!~iT

ri, r~rnr r’

te-

materials it shall-

reactive group, that is,

,

A combination of hydrocarbons, alcohols, aldehydes,

esters, ethers or ketones having an olcfinic or

cyclo-olefinic types of unsaturation: 5 percent. This

definition does not apply to perchlorcthylene or

trichloroethylenc.

32

“Pharmaceutical”: Any compound or mixture, other than food,

used in the prevention, diagnosis, alleviation, treatment -or

cure of disease in man and animal.

“Pharmaceutical Coating Operation”:

A device in which a

c-oating is applied to a pharmaceutical, including any drying

or curing of the coating.

“Photochemically Reactive Material”: Any organic material

with an aggregate of more than 20 percent of its total

volume composed of the chemical compounds classified below

or the composition of which exceeds any of the following

individual percentage composition limitations. Whenever any

photochcmically reactive material or any constituent of any

organic material may be classified from its chemical

than one of the above groups of organic

be considered as a member of the most

c group beving the least

33

A combination of aromatic compounds with eight or more

carbon atoms to the molecule exoopt ethylbencene: 8

percent.

A combination of cthylbcnccno, ketonco having branched

hydrooarhon ~trueturr~i~or to1~inni~: 

20 neror~nt..

tilT

I!!LJITL.

l_JJ~~

Lilt:

U~1iUC

.1ous 

- --

1 IT 13 Li

ri

~ent

“Plant”: All of the

pollutant-emitting activities which

belong to the same industrial grouping, arc located on one

-~i~  

~djai proc 

control  

£..._

-p~

-pe

control~, ~  

~‘“

roonr~

under common

rit

‘~r

it:

uuvi  

of

any marine vessel.

1~0’

.li1Ti1nTT—~m1-c.LJ.ng

i-t.riti

nhrill

he~ r~oiv~4rir~rrdo~ riart of

tnc same inaustriaj. group~.ngif they belong to the same

major group (i.e., which have the same two-digit code) as

described in the “Standard Industrial Classification

Manual”. i!~7.

JortJL3A

and ~ro under th._

“PM-lO”: particulate matter with a..

less than or equal to a nominal 10

by the applicable test methods spec

air concentrations for PH-b arc uc

mirroarama

nr~r cmhir~ mt~tr~r

(ug/m~-)—

“Pneumatic Rubber Tire

pneumatic rubber tires

inr1udin~ 20.0 inches

.flCflCS, DUE not inciua..~_

....

other vehicles when produced on equipment separate from

~isr,

lines for ;~ng~

LJSSSC

or truck ty—~.......

“Polybasic Organic Acid Partial Oxidation Manufacturing

Process”: Any process involving partial oxidation of

hydrocarbons with air to manufacture polybasic acids or

their anhydridcs, such as maleic anhydride, phthalic

anhydrido, tcrephthalic acid, isophthalic acid, trimolbetic

anhydridc.

“Portable Grain-Handling Equipment”: Any equipment

(excluding portable grain dryers) that is designed and

maintained to be movable primarily for usc in a

non continuous operation for loading and unloading one-turn

storage space, and is not physically connected to the grain

elevator, provided that the manufacturer’s rated capacity of

the equipment does not exceed 10,000 bushels per hour.

“Portland Cement Manufacturing Process Emission Source”:

any items of process equipment or manufacturing

processes

used in or associated with the production of portland

cement, including, but

not limited to, a kiln, clinker

cooler, raw mill system, finish mill system, raw material

“~odynamic ~

if ied by rule. Ambient

ually expressed in

Manufacture”: The production of

with a bead diameter up to but not

~  ~cction diinensionup

34

dryer, matcriî-~l 

~itr~r-—-~

belt or other

traririfer

—~x

ot’-...

~$+~

,..~

b4.. 

.-..

-ey--

~._em,

t-~a~..~ersy 

ma.........ial convcyo...

,~...nt, bagging 

~

unlo-adin,

or bulk loading station.

L I

~II

1-,’---.~

“Portland Cement Process” or “Portland Cement rianurrioturing

Plant”: Any facility or plant manufacturing portland cement

either the wet or dry process.

“Power Driven Fastener Coating”i The coating of nail,

staple, brad and finish nail fasteners where ouch fasteners

arc fabricated from wire or rod of 0.0254 inch diameter or

greater, where such fasteners are bonded into coils or

strips, such coils and strips containing a number of such

fasteners, which fasteners are manufactured for use in power

tools, and which fasteners must conform with formal

standards for specific uses established by various federal

and national organizations including Federal Specification

FF-N-105b of the Cencral Cervices Administration dated

August 23, 1977 (does not include any later amendments or

editions; U.S. Army Armament Research and Development

Command, Attn: DRDAR-TCT, Rock Island, IL 61201), Bulletin

t.TH-25d of the U.S. Department of Housing and Urban

Development 

Federal -Housing Administration dated

September 5, 1973 (does not include any later amendments or

editions; Department of 

HUD, 547

W. Jackson Blvd., Room

1005, Chicago, IL 60606), and the Model Building Code of the

Council of American Building Officials, and similar

standards. For the purposes of this definition, the termo

“brad” and 

“finish nail” refer to single leg

fasteners

fabricated in the same manner as staples. The application

of coatings to staple, brad, and finish 

nail

fasteners may

be associated with the incremental forming of such fasteners

-in a cyclic or repetitious manner (incremental fabrication)

or with the forming of strips of such fasteners as a unit

from a band of wires (unit fabrication).

(Vol)

per ~

ratio which

expresses the volumetric concentration of

gaseous air contaminant   

million unit volumes of gu....

“Pressure Release”: The emission of materials resulting

from system pressure being greater than oct pressure of the

pressure relief device.

“Pressure Tank”: A tank in which fluids are stored at a

pressure greater than atmospheric pressure.

“Prime Coat”~ The first film of

a mu~tip1.r

r~nnt

nrn-~ra$-irin..

ig material applied4n

conveyor

belt

atation,

—

111 .~I

JI~ ~11Tflti

2&

~.rr,11imr’/’Lrrt111mD

“Purged Process Fluid”: Liquid or vapor from a process unit

that contains volatile organic material and that results

from flushing or cleaning the sample line(s) of -a process

unit so that an uncontaminated sample may then be taken for

35

“Prime Surfacer Coat”: A film of coating material that

.~ueL   

the surface not ad~uatcly

the prime coat before 

~-

covered by

.~J.I,_j.Ufl

i.dlL L.~Jp

coat.

“Process”: Any stationary emission source other than a fuel

combustion emission source or an incinerator.

“-Process Unit”: Components assembled to produce, as

or f~nm1 

nrprinr~I-~

- nnt’

mrir~

of

thr’

~

listed             

ADD CT15

Drocedure

4* ~—Ill ~ Code 215   

D.

.. -

eon operate independently if supplied with sufficient feed

or raw materials and sufficient storage facilities for the

product.                    

“Process Unit Shutdown”: A work practice or operational

trocoso unit

of a process unit. An

operational pro-~

stops

~‘oauct

—--~‘ -

par’

cdulcd work practice or

that stopo production from a procoso

unit u~ pu~ -ui a proc~ uni~ iui ~cUu

~uun ~ nour~ 

-a—process unit shutdown. The use of spare components and

nu’~

technically feasible bypassing of components without

stopping production is not a process unit shutdown.

“Process Weight Rate”: The actual weight or engineering

approximation thereof of all materials except liquid and

gaseous fuels and combustion air, introduced into any

process per hour. For a cyclical or batch operation, the

process weight rate shall be determined by dividing such

~i-n.-~1

weight or cngin~r~rnri

ari~rrnrimatinn

thr~ri-~gf

by the

numoer or nours or operation cxciuding any time auring

the equipment is idle. For continuous processes, the

process weight rate shall be determined by dividing such

actual weight or engineering approximation thereof by the

number of hours in 

one

complete operation, excluding any

time during which the equipment is idle.

“Production Equipment Exhaust System”: A system 

for

collecting and directing into the atmosphere emissions of

volatile organic material from reactors, centrifuges and

other process emission sources.

“publication Rotogravure Printing”: Rotogravure printing

tlnrin

nant-r

uhich is subsequently formed into hnnk~

~-iFa1ppucs.

brochur’~ 

r1irtririr~-i

supplement

materials.

types of     

ging

testing or analysis.

36

“Reactor”: A vat, vessel or other device in which ohoinica-l

reactions take place.

“Reasonably Available Control Technology (RACT)”: The

lowest omission limitation that an emission source is

capable of meeting by the application of control technology

that is reasonably available considering technological and

economic feasibility.

“Refinery Fuel Gas”: Any gas which is generated by a

petroleum refinery process unit and which is combusted cit

the refinery, including any gaseous mixture of natural gas

and fuel gas.

“Refinery Unit, Process Unit or Unit”: A sot of components

which arc a part of a basic process operation such as

distillation, hydrotreating, cracking or reforming of

hydrocarbons.

“Refrigerated Condenser”: A surface condenser in which the

coolant supplied to the condenser has been cooled by a

mechanical device, other than by a cooling tower or

evaporative spray cooling, such as a refrigeration unit or

steam chiller unit.

“Residual Fuel Oil”: Fuel oils of grade Ho. 4, 5 and 6 as

specified in detailed requirements for fuel oils A.6.T.M.

-D-—396—60 (1971)

“Restricted Area”: The area within the boundaries of any

“municipality” as defined in the Illinois Municipal C-ode,

plus a cone extending one mile beyond the boundaries of any

s-uch municipality having a population of 1000 or more

according to the latest federal census.

“Ringclinann Chart”: The chart-published and described in

the Bureau of Mines, U.S. Department of Interior,

Information Circular 8333 (Revision of 1C7718) May 1, 1967,

or

any

adaptation thereof which has been approved by the

Agency.

“Roadway”: Any street, highway, road, alley, sidewalk,

parking lot, airport, rail bed or terminal, bikeway,

pedestrian mall or other structure used for transportation

purposes.

“Roll Printing”: The application of words, designs and

pictures to a substrate usually by means of a series of hard

rubber or metal rolls each with only partial coverage.

“Rotogravure Printing”: The application of words, designs

and pictures to a substrate by moans of a roll printing

37

technique in which the pattern to be applied is recessed

1nti’~.’t~

to

thr

non—imsa~

r~ror.

+

rif-

~r’

~

f-Ti

__.A:.~_,

-‘

I~fl

~1Tin

material on the mesh surfaces (screens).

“Sensor”: A device that measures a physical quantity or 

the

change in a physical quantity such as temperature, pressure,

flow rate, pH, or liquid level.

“Cot of Safety Relief Valves”: One or more safety relief

valves designed to open in order to relieve excessive

pressures 

~ne

same vessel or 

fli~.

“Sheet Basecoat”: A coating applied to metal when the metal

is in sheet form to serve as either the exterior or interior

of a can for either two-piece or three-piece cans.

“Chotblasting”: The use of a mixture of any metallic or

non-metallic substance and air at high pressures for

cleaning and/or polishing any type of surface.

“Side-Scam Spray Coat”: A coating applied to the seam of a

three-piece can.

“Smoke”: Small gas-borne particles resulting from

incomplete combustion, consisting predominately but not

e-xclusivcly of carbon, ash and other combustible material,

that form a visible plume in the air.

“Smokeless Flare”: A combustion unit and the stack to which

it is affixed in which organic material achieves combustioi~

by burning in the atmosphere such that the smoke or other

particulate matter emitted to the atmosphere from such

combustion does not have an appearance density or shade

darker that No. 1 of the flinglemann Chart.

“Solvent Cleaning”: The process of cleaning soils from

surfaces by cold cleaning, open top vapor degrecising or

r’~rinvrvnri

~rr~   

rr’irii rfl-s

“Cafoty Relief Valve”: A valve which is normally closed and

which is designed to open in order to relieve excessive

pressures within a vessel or pipe.

“Candblariting”: The use of a mixture of sand and air at

high pressures for cleaning and/or polishing any type of

surface.

“Screening”: Separating material according to size by

pressing undersized material through one or more mesh

surfaces

-I rifT fTJf-rfi1

38

“Specialty High -Gloss Catalyzed Coating”: Commercial

contract finishing of material prepared for printers and

lithographers where the finishing process uses a

solvent-borne coating, formulated with a catalyst, in a

quantity of no more than 12,000 gallons/year as supplied,

where the coating machines arc shoot fed and the coated

shoots are brought to a minimum surface temperature of 190°

F, and whore the coated sheets arc to achieve the minimum

specular reflectance index of 65 measured at a 60 degree

angle with a gloss meter.

“Gplash Loading”i A method of loading 

a tank, railroad tank

car, tank truck or trailer by use of other than a submerged

loading pipe.

“Stack”: A flue or conduit, free—standing or with exhaust

port above the roof of the building on which it is mounted,

by which air contaminants arc emitted into the atmosphere.

“Standard Conditions”: A temperature of 70° F and a

pressure of 14.7 pounds per square inch absolute (psia).

-.-—-wt

“Stationary Storage Tank”: Any container of liquid or gas

which is designed and-constructed to remain at one site.

“Submerged Loading Pipe”: Any loading pipe the discharge

epcning of which is entirely submerged when the liquid level

-i-s 6 inches above the bottom of the tank. when applied to a

tank which

is loaded from the side, any loading pipe the

discharge of which is entirely submerged when the liquid

level is 18 inches or two times the loading pipe diameter,

whichever is greater, above the bottom of the tank. The

definition shall also apply to any loading pipe which is

continuously submerged during loading operations.

Cubic Foot (~cf)

“.--- -~

e#~

,.~.

cubic 

-foot

of gas at standard conditions.

“Stationary Emission Source”: An emission source which is

n-nt ~c1f-nrnoc~11r~cL

ilCulfuric Acid Mist”: Sulfuric acid mist as measured

according to the method specified in 35 Ill. Adm. Code

-214.101(b)

“Surface Condenser”: A device which removes a substance

from a gas stream by reducing the temperature of the stream-1-

without direct -contact between the coolant and the stream.

39

“&ynthetic Organic Chemical or Polymer Manufacturing Plant”:

A plant that produces, as intermediates or final products,

one or more of the chemicals or polymers listed in 35 Ill.

Adm. Code 215.Appendix D-.

“Tablet Coating Operation”: A pharmaceutical coating

operation in which tablets are coated.

“Top Coat”: A film of coating material applied in a

multiple coat operation other than the prime coat, final

repair coat or prime surfacer coat.

“Transfer Effioienoy”~ Ratio of the amount of coating

deposited onto a part or product to the total amount of

coating solids used.        

“Tread End Cementing”: The application of a solvent-based

cement to the tire tread ends.

“True Vapor Pressure”: The equilibrium partial pres2ure

exerted by a petroleum liquid as determined in accordance

with methods

described in American Petroleum Institute

Bulletin 2517, “Evaporation Loss From Floating Roof Tanks”

(1962). 

“Turnaround”:

The procedure of shutting down an operating

refinery unit, emptying gaseous and liquid contents to do

inspection, maintenance and repair work, and putting the

unit back into production.

“Und.ertrcad Cementing”: The application of a solvent-based

cement to the underside of a tire tread.

“Unregulated Safety Relief Valve”: A safety relief valve

which cannot be actuated by a means other than high pressure

in the pipe or vessel which it

protects.

“Vacuum Producing System”: Any reciprocating,

rotary or

centrifugal blower or compressor, or any jet ejector or

device that creates suction from a pressure below

atmospheric and discharges against a greater pressure.

“Valves Not Externally Regulated”: Valves that have no

external controls, such as in-line chock valves.

“Vapor Balance System”: Any combination of pipes or hoses

uhic~h 

c~rrntr”i n r~1t-irit-’ri ~-i1-s’m

h~rr’r~n

the vapor spao~ 

unloading tank and a receiving tank sucn   

vapors

displaced from the receiving tank are transferred to the

tank being unloaded.

40

“Vapor Collection System”: All piping, seals, hoops,

connections, pressure-vacuum vents, and other possible

sources between the gasoline delivery vessel and the vapor

processing unit and/or the storage tanks and vapor holder.

“Vapor Control System”: Any system that prevents release to

the atmosphere of organic material in the vapors displaced

from a tank during the transfer of gasoline.

“Vapor-Mounted Primary Cecil” ~ A primary seal mounted with

an air space bounded by the bottom of the primary seal, the

tank wall, the liquid surface

and the floating roof.

“Vinyl Coating”: The appi ication of a topcoat or printing

to vinyl coated fabric or

that the application of an

vinyl sheets;

organisol or

provided,

plastisol

however,

is not

viny

....s-.4-4..~~#

l.a

.

“Volatile Organic Liquid”:

irrilr~fH

it’

n~a-,nir~miff-ri~11

Any liquid which

“vot~lcorganicHatia:AnyorgQnio compound which

specifically exempted from this definition. For purpooco of

determining compliance with emission limits, volatile

organic material shall b-c measured by the reference test

methods incorporated by reference in 35 Ill. Adm. Code

215.105. Where such a method also inadvertently measures

compounds with negligible photochemical reactivity, an owner

or operator may exclude these negligibly reactive compounds.

For

purposes 

of this definition, the following organic

enmnound~ 

hr~ve

been 

dr~tevm~ined

to have neal iaible

materials:

~CFC—114)-

Dichiorotrifluoroethanc (HCFC-123)

1, l-Difluoroethane (HFC-152a)

Ethane

Methane

~~uoroethanc (HFC—125)

Tetrafluoroethanc (HFC-134a)-

1, 1,2, 2—Tctr-afluorocthanc (J-IFC-l34)

Trichlorecthanc (Methyl chloroform)

Chiorodifluoroethanc (HCFC-142b)

Chloro-difluoromcthane (CFC-22~

Chloropcntafluoroethane (CFC-1 15)

2-Chloro-l,l,1,2—tetrafluoroethane (HCFC-124)

Dichiorodifluoromethane (CFC-12)

Dichlorofluoroethane (HCFC-141b)

Dichloromcthane (Methyleno chloride)

nhlri~ptctr”.~”-~

41

1,1, l-Trichloroethane (Methyl chloroform)

Triohlorofluoromethanc (CFC 11)

Trichlorotrifluorocthane (CFC-113)

Trifluoromethane (FC-23)

and the following classes of compounds:

Cyclic, branched, or linear, completely fluorinated

alkanes.

Cyclic, branched, or linear, completely fluorinated

ethers with no unsaturations.

Cyclic, branched, or linear, completely fluorinated

tertiary aminco with no unsaturations.

Sulphur-containing perfluorocarbons with no unsaturations

and with sulfur bonds only to carbon and fluorine.

BOAflD NOTE: UCEPA or the Agency may require

monitoring to 

demonstrate the amount of an exempted

compound in a sourcc’-s emissions on a case-by—case basis

as a pre-condition to exemption of that compound under

certain circumstances, such as where VONs and excm~tcd

com~ouncis are mixed together    

arc

large

~~z~unds, 

-chemical com~..~itionof th....

exempted compounds is not known. Sec 35 Ill. Mm. Codc

number of

pO~fl~s,-1

~i IA ~if~_’~if~

“Volatile Organic Material

Content” or “VOMC”: the

emissions of

volatile organic material which would result

from the exposure of

a coating, printing ink, fountain

solution, tire spray, dry cleaning waste or other similar

material to the air, including any drying or curing, in the

absence of any control equipment. VONC is typically

expressed as kilogram (kg) VON/liter (lb VON/gallon) o-f

coating or coating solids, or kg VON/kg (lb VOH/lb) of

coating solids, of coating material or material.

“Volatile Petroleum Liquid”: Any petroleum liquid with a

true vapor pressure that is greater than 1.5 path (78

millimeters of mercury) at standard conditions.

“Wastewatcr (Oil/Water) Separator”: Any device or piece of

equipment which utilices the -difference in density between

oil and water to remove oil and associated chemicals of

device, ~n~h    

fl~t’~nlntinn

tank 

ni~ a

clarifier,

which removes petroleum derived compounso tram

waste water.

“Weak Nitric Acid Manufacturing Process”: Any acid

producing facility manufacturing nitric acid with a

concentration of less than 70 percent by weight.

“Woodworking”:

polishing and

The

making

shaping, sawing,

into products of

grinding,

any form

smoothing,

or shape of

wood.

(Source: Repealed at 

—

Ill. Reg. 

_____,

effective

Section 211.130 Accelacota

“Accelacota” means a pharmaceutical coating operation which

consists of a horizontally rotating perforated drum in which

tablets are placed, a coating is applied by spraying, and the

coating is dried by the flow of air across the drum through the

perforations.

(Source:

Added at

Ill. Reg.

_____,

effective

_____________

Section

211.150 Accumulator

“Accumulator” means the reservoir

of a condensing unit receiving

the condensate from a surface condenser.

(Source:

Added at

Ill.

Reg.

_____,

effective

______________

Section 211.170 Acid Gases

“Acid gases” means~ for the purposes of Section 9.4 of the

Environmental Protection Act (the Act) (Ill. Rev. Stat. 1991, ch.

l11~, par. 1009.4) f415 ILCS 5/9.4), hydrogen chloride, hydrogen

fluoride and hydrogen bromide, which exist as gases, liquid mist,

or any combination thereof.

(Source: Added at 

—

Ill. Reg.

_____,

effective 

____________

Section 211.210

Actual Heat Input

“Actual heat input” means the quantity of heat produced by the

combustion of fuel using the gross heating value of the fuel.

(Source: Added at

Ill. Reg.

_____,

effective

43

Section 211.230

Adhesive

“Adhesive” means any substance or mixture of substances intended

to serve as a joining compound.

(Source:

Added at

Ill. Reg.

_____,

effective 

_______________

Section 211.250 Aeration

“Aeration” means the practice

of forcing air through bulk stored

grain to maintain the condition of the grain.

(Source: Added at

Ill. Reg.

effective_________

Section 211.290

Afterburner

“Afterburner” means a control

device in which materials in

gaseous effluent are combusted.

(Source: Added at  

Ill. Reg. 

_____,

effective 

_______________

Section 211.310 Air Contaminant

“Air contaminant” means any solid, liquid, or gaseous matter, any

odor, or any form of energy, that is capable

of being released

into the atmosphere.

(Source:

Added at

—

Ill. Reg.

_____,

effective 

_______________

Section 211.330 Air Dried Coatings

“Air dried coatings” means any coatings that dry by use of air or

forced air at temperatures up to 363.15°K (194°F).

(Source: Added at 

—

Ill. Reg. 

_____,

effective 

_______________

Section 211.350

Air Oxidation Process

“Air oxidation process” means any unit process including

ainxnoxidation and oxychlorination which uses air or a

combination

of air and oxygen as an oxidant in combination with one or more

organic reactants to produce one or more organic compounds.

(Source: Added at

—

Ill. 

Reg.

_____,

effective 

_______________

44

Section 211.370 Air Pollutant

“Air pollutant” means an air pollution agent or combination of

such agents. including any physical, chemical, biological,

radioactive (including source material, special nuclear materiala

and byproduct materiaU substance or matter which is emitted into

or otherwise enters the atmosphere. Such term includes any

precursors to the formation of any air pollutant, to the extent

that the

relevant statute or rule has identified such precursor

or precursors for particular purpose for which the term “air

pollutant” is used.

(Source: Added at  

Ill. Reg. 

_____,

effective 

_______________

Section

211.390 Air Pollution

“Air pollution” means the presence in the atmosphere of one or

more air contaminants in

sufficient quantities and of such

characteristics

and duration as to be injurious to human, plant,

or animal life, to health, or to property, 

or to unreasonably

interfere with the enjoyment of life or property.

(Source: Added at 

—

Ill. Reg. 

_____,

effective 

________________

Section 211.410 Air Pollution Control Equipment

“Air pollution control equipment” means any equipment or

apparatus of a type intended to eliminate, prevent, reduce or

control the emission of air contaminants to the atmosphere.

(Board Note: The requirements to obtain permits for air

pollution control equipment, in 35 Ill. Adrn. Code 201.Subpart C,

~pplv to such equipment intended 

to eliminate, prevent, reduce or

control the emissions of specified air contaminants from

stationary emission units.

(Source: Added at 

—

Ill. Reg. 

_____,

effective 

________________

Section

211.430 Air Suspension Coater/Dryer

“Air suspension coater/dryer” means

a pharmaceutical coating

operation which consists of vertical chambers in which tablets or

particles are placed, and a coating is applied and then dried

while the tablets or particles are kept in a fluidized state by

the passage of air upward through the chambers.

(Source: Added at  

Ill. Peg. 

_____,

effective 

________________

Section 211.450 Airless Spray

“Airless sDrav” means a spray coating method in which the coating

is atomized by forcing it through a small opening at high

pressure. The coating liquid is not mixed with air before

exiting from the nozzle.

(Source: Added at 

—

Ill. Reg. 

_____,

effective 

_______________

Section 211.470 Air Assisted Airless Spray

“Air assisted airless spray” means a spray coating method which

combines compressed air with hydraulic pressure to atomize the

coating material into finer droplets than is achieved with pure

airless spray. Lower hydraulic pressure is used than with

airless spray.

(Source: Added at 

—

Ill. Reg.   

effective 

_______________

______________________________ )

Section 211.490 Annual Grain Through-Put

“Annual grain through-put” unless otherwise shown by the owner or

operator, annual grain through-put for grain—handling operations,

which have been in operation for three consecutive years prior to

June 30, 1975, shall be determined by adding grain receipts and

shipments for the three previous fiscal years and dividing the

total by 6. The annual grain through-put for grain-handling

operations in operation for less than three consecutive years

prior to June 30, 1975, shall be determined by a reasonable

three-year estimate; the owner or operator shall document the

reasonableness of his three—year estimate.

(Source: Added at 

—

Ill. Reg. 

_____,

effective 

_______________

Section 211.510 Application Area

“Application area” means an area where a coating is applied by

dipping, spraying or other techniques.

(Source: Added at  

Ill. Reg. 

_____,

effective 

_______________

Section 211.530 Architectural Coating

“Architectural coating” means any coating used for residential or

commercial buildings or their appurtenances, or for industrial

buildings, which is site applied.

46

(Source: Added at 

—

Ill. Reg.

_____,

effective 

_______________

Section 211.550 As Applied

“As applied” means the formulation of a coating during

application on or impregnation into a substrate, including any

dilution solvents or thinners added at the source before

application of the coating.

(Source: Added at 

—

Ill. Reg. 

_____,

effective 

_______________

Section 211.570 Asphalt

“Asphalt” means the dark-brown to black cementitious material

(solid, semisolid, or liquid in consistency) of which the main

constituents are bitumens which

occur naturally or as a residue

of petroleum refining.

(Source: Added at 

—

Ill. Reg. 

_____,

effective 

_______________

Section 211.590 Asphalt Prime Coat

“Asphalt prime coat” means

a low—viscosity liquid asphalt applied

to an absorbent surface as the first of more than one asphalt

coat.

(Source: Added at   

Ill. Reg. 

_____,

effective 

_______________

Section 211.610 Automobile

“Automobile” means a motor vehicle which normally has four

wheels, is used predominately for carrying 12 or fewer

passengers, and is not a light—duty truck.

(Source: Added at  

Ill. Reg. 

_____,

effective 

______________

Section 211.630

Automobile or Light-Duty

Truck Assembly Source

or Automobile or Light-Duty Truck Manufacturing

Plant

“Automobile or light—duty truck assembly source” or “Automobile

or light-duty truck manufacturing plant” means a source where

parts are assembled

or finished for inclusion into a finished

automobile or light-duty truck ready for sale to vehicle dealer

but not including customizers, body shops, and other

repainters.

47

(Source: Added at 

—

Ill. Reg. 

_____,

effective

Section 211.650 Automobile or Light-Duty Truck Refinishing

“Automobile or light-duty truck refinishing” means the repainting

of used automobiles and light-duty trucks.

(Source: Added at 

—

Ill. Reg.

effective

Section 211.670 Baked Coatings

“Baked coatings” means any coating which is cured or dried in an

oven where the oven air temperature exceeds 90°C (194°F).

(Source: Added at

—

Ill. 

Reg.

effective

Section 211.690 Batch Loading

“Batch loading” means, with resPect to solvent cleaning, the

process of loading

p number of individual parts 

at the same time

for degreasing.

(Source: Added at  

Ill. Reg.    

effective

Section 211.710 Bead-Dipping

“Bead-diPping” means the dipping of an assembled tire bead into a

solvent-based cement.

(Source: Added at 

—

Ill. Reg.

Section 211.730 Binders

“Binders” means organic materials and

effective

resins which do not contain

VON.

(Source: Added at  

Ill. Reg.    

effective

)

Section

211.750 British Thermal Unit

“British Thermal Unit”

means the quantity of heat required to

raise one pound of water from 60°F to 61°F (abbreviated btu).

(Source: Added at 

—

Ill. Peg. 

_____,

effective 

_______________

_________________________________ )

48

Section 211.770

Brush or Wipe Coating

“Brush or wipe coating” means

a manual method of applying a

coating using a brush, cloth, or similar object.

(Source: Added at 

—

Ill. Reg.

_____,

effective 

______________

_________________________________)

Section 211.790

Bulk Gasoline Plant

~  “Bulk gasoline plant” means, for purposes of 35 Ill.

Adin. Code 215, any gasoline storage and distribution

source 

that receives gasoline from bulk gasoline

terminals by delivery vessels and distributes gasoline

to gasoline dispensing operations.

“Bulk gasoline plant” means, for purposes of 35 Ill.

Adm. Code 218 and

219, a gasoline storage and

distribution source with an average throughput of

76,000 1 (20,000 gal) or less on a 30—day rolling

average that distributes gasoline to gasoline

dispensing operations.

(Source: Added at 

—

Ill. Reg.

_____,

effective 

______________

Section 211.810 Bulk Gasoline Terminal

“Bulk gasoline terminal” means any gasoline storage and

distribution source that receives gasoline by pipeline, ship or

barge, and distributes gasoline to bulk gasoline plants or

gasoline dispensing operations.

(Source: Added at  

Ill. 

Reg.

_____,

effective 

______________

Section 211.830 Can

“Can” means any cylindrical single walled metal container, with

or without a top, cover, spout or handles, with walls thinner

than 29 gauge (0.0141 inch) into which solid or liquid materials

may be packaged.

(Source: Added at  

Ill. Peg. 

_____,

effective 

______________

Section 211.850

Can Coating

“Can coating” means any protective,

decorative or functional

coating applied onto 

the surface

of a can or a metal sheet or

metal part which is made into a can.

49

(Source: Added at 

—

Ill. Reg. 

_____,

effective

Section 211.870 Can Coating Line

“Can coating line” means a coating 1 me in which any protective,

decorative, or functional coating is applied onto the surface of

a can or a metal sheet or metal part which is made into a can.

(Source: Added at 

—

Ill. Peg.

)

Section 211.890 Capture

effective

“Capture” means the ~      

or recovery of 

fi-r~

an

emission unit for direction into a duct which may be exhausted

through a stack or vent to a control device. The overall

abatement of emissions from an emission unit with an add-on

control device is a function both of the

capture efficiency and

of the control device

efficiency.

(Source: Added at

—

Ill. Peg. 

_____,

effective 

_______________

Section 211.910 Capture Device

“Capture device” means a hood, enclosed room, floor sweep or

other means of collecting volatile organic material or other air

contaminants into a duct. The pollutant can then be directed to

a pollution control device such as an afterburner, carbon

adsorber, fabric filter or scrubber. Sometimes the term is used

loosely to include the control device.

(Source: Added at

—

Ill. Reg. 

_____,

effective 

________________

Section 211.930 Capture Efficiency

“Capture efficiency” means, for purposes of 

35 Ill. Adm. Code 218

and 219, the weight

of VOM entering a capture system and

delivered to a control device divided by the weight of VOM

generated by an emission unit, during a particular time period.

expressed as a percentage.

(Source:

Added at

—

Ill. 

Reg.

_____,

effective 

________________

Section 211.950 Capture System

“Capture

system” means all equipment (including, but not limited

to, hoods, ducts, fans, ovens, dryers, etc.) used to contain,

collect and transport an air contaminant to a control device.

50

(Source: Added at 

—

Ill. Peg. 

_____,

effective 

________________

Section 211.970 Certified Investigation

“Certified investigation” means a report signed by Illinois

Environmental Protection Agency (Aaency) personnel certifying

whether a grain-handling operation (or portion thereof) or

grain—drying operation is causing or tending to cause air

pollution. Such report must describe the signatory’s

investigation, including a summary of those facts on which the

signatory relies to certify whether the grain-handling or

grain-dryin~ operation is causing or threatening or allowing the

discharge or emission of any contaminant into the environment so

as to cause or tend to cause air pollution in Illinois, either

alone or in combination with contaminants from other sources, or

so as to violate regulations or standards adopted by the

Pollution Control Board (Board) under the Environmental

Protection Act

(Act). The certified investigation shall be open

to a reasonable public inspection and may

be copied upon payment

of the actual cost of reproducing the original.

(Source: Added at 

—

Ill. Peg. 

____,

effective 

______________

Section 211.990 Choke Loading

“Choke loading” means that method of transferring grain from the

grain-handling operation to any vehicle for shipment or delivery

which precludes a free fall velocity of grain from a discharge

spout into the receiving container.

(Source: Added at 

—

Ill. Peg. 

_____,

effective 

________________

Section 211.1010

Clean Air Act

“Clean Air Act” means the Clean Air

Act Amendments of 1970 (42

U.S.C. ~7401 et

seq.), as amended in 1977 and 1990.

(Source: Added at 

—

Ill. Reg. 

_____,

effective 

________________

Section 211.1050 Cleaning and Separating Operation

“Cleaning and separating operation” means that operation where

foreign and undesired substances are removed from the grain.

(Source: Added at 

—

Ill. Peg. 

_____,

effective 

_______________

51

Section 211.1090 Clear Coating

“Clear coating” means coatings that lack color and opacity or are

transparent using the undercoat as a

ref lectant base or undertone

color.

(Source: Added at

—

Ill. Peg.

effective

)

Section 211.1110 Clear Topcoat

“Clear topcoat” means the final coating which contains binders.

but not opaque picn~ents. and is specifically

formulated to form a

transparent or translucent solid protective film.

(Source: Added at 

—

Ill. Reg.    

effective

Section 211.1130 Closed Purge System

“Closed purge system” means a system that is not open to the

atmosphere and that is composed of Piping, connections, and, if

necessary, flow inducing devices that transport liquid or vapor

from a piece or pieces of equipment to a control device, or

return the liquid or vapor to the

process line.

(Source: Added at 

—

Ill. Peg.    

effective

Section 211.1150 Closed Vent System

“Closed vent system” means a system that is 

not open to the

atmosphere and is composed of piping, connections, and, if

necessary, flow inducing devices that transport gas or vapor from

p piece or pieces of equipment to a control device.

(Source: Added at

—

Ill. Peg.    

effective

Section 211.1170

Coal Refuse

“Coal refuse” means waste products of coal 

r’l

~r~rc

and

coal preparation operations containing coal, matrix material,

clay and other organic and inorganic material.

(Source: Added at 

—

Ill. Peg.   

effective 

_____________

Section 211.1190 Coating

~j. “Coating” means, for purposes of 35 Ill. Mm. Code 215,

a material applied to a substrate for decorative,,

52

protective or other functional purposes. Such material

shall include, but are not limited to paints,

varnishes, sealers, adhesives, diluents and thinners.

~j. “Coating” means, for purposes of 

35 Ill. Adm. Code 218

and 219, a material applied onto or impregnated into a

substrate for protective, decorative, or functional

purposes. Such materials include, but are not limited

to,diluents,paints,andvarnishes,inks.  

sealers, adhesives, thinners1

(Source: Added at 

—

Ill. Reg. 

_____,

effective 

_______________

Section 211.1210 Coating Applicator

“Coating applicator” means equipment used

to aptly a coating.

(Source: Added at 

—

Ill. Reg. 

_____,

effective 

_______________

Section 211.1230 Coating Line

~

“Coating line” means, for purposes of 

35 Ill. Mm. Code

215, an operation where a surface coating is applied to

a material and subsequently the coating is dried and/or

cured.

~j “Coating line” means, for Purposes of 35 Ill. Mm. Code

218 and 219, an operation consisting of a series of one

or more coating applicators and any associated

flash-off areas, drying areas, and ovens wherein a

coating is applied, dried, and/or cured. A coating

line ends at the point where the coating is dried or

cured, or prior to any subsequent application of a

different coating.

It is not necessary for an

operation to have an oven or a flash-off area in order

to be included in this definition.

(Source: Added at  

Ill. Reg. 

_____,

effective 

_______________

_________________________________ )

Section 211.1250 Coating Plant

“Coating plant” means any building, structure or installation

that contains a coating line and which is located on one or more

contiguous or adjacent properties and which is owned or operated

by the same person (or

by persons under common control).

(Source:

Added at

—

Ill. Peg.

_____,

effective 

_______________

53

Section 211.1270 Coil Coating

“Coil coating” means

any protective, decorative or functional

coating which is applied onto any flat metal sheet or strip which

is delivered to the coating line as a roll or coil, unwound and

coated as a continuous substrate.

(Source: Added at 

—

Ill. Reg.

effective

Section 211.1290 Coil Coating Line

“Coil coating line” means a coating line in which any protectiy~

decorative or functional coating is applied onto any flat metal

sheet or strip which is delivered to the coating line as a roll

or coil, unwound and coated as a continuous substrate.

(Source: Added at  

Ill. Peg. 

_____,

effective

Section 211.1310 Cold Cleaning

“Cold cleaning” means the process of cleaning and removing soils

from surfaces bY spraying, brushing, 

flushing, or immersion while

maintaining the organic solvent below its boiling Point. Wipe

cleaning is not included in this definition.

(Source: Added at

Ill. Peg. 

_____

effective

Section 211.1330 Complete Combustion

“Complete combustion” means a process in which all carbon

~ontairt~d in a fuel or aas stream is conv~rt~dto carbon ~

(Source: Added at 

—

Ill. Peg.    

effective

Section 

211.1350 Component

“Component” means any

piece of equipment which has the pot~nti~1

to leak 

volatile organic material (VOM) including, but not

limited to. pump seals, compressor seals, seal oil degassjng

vents, pipeline valves, pressure relief devices, process drains.

and open ended valves and lines, and flanges.

For purposes of

Subparts Q and P in 35 Ill. Adrn. Code 215, 218 and 219, this

definition excludes valves which are not externallY regulated,

flanges, and equipment in heavy liquid service. For purposes of

Subpart Q of 35 Ill. Adm. Code 215, 218 and 219, this definition

also excludes bleed ports of gear ~um~s in polymer service.

54

(Source:

Added at

—

Ill. Peg.

_____,

effective 

_______________

Section 211.1370 Concrete Curing Compounds

“Concrete curing compounds” means any coating applied to freshly

poured concrete to retard the evaporation of water.

(Source: Added at  

Ill. Peg. 

_____,

effective 

_______________

_________________________________ )

Section 211.1390 Concentrated Nitric Acid Manufacturing Process

“Concentrated nitric acid manufacturing process” means any acid

producing facility manufacturing nitric acid with a concentration

equal to or greater than 70 percent by weight.

(Source: Added at 

—

Ill. Peg. 

_____,

effective 

_______________

Section 211.1410 Condensate

“Condensate” means volatile organic liquid separated from its

associated gases, which condenses due to changes in the

temperature or pressure and remains liquid at standard

conditions.

(Source:

Added at

—

Ill.

Peg.

_____,

effective

_______________

Section 211.1430 Condensible PM-b

“Condensible PM-b” means PM-b formed immediately or shortly

after discharge to the atmosphere, as measured by the applicable

test method specified in 35 Ill. Adm. Code 212.110. Condensible

particulate

matter exists in gaseous and/or vapor form prior to

release_to_the atmosphere, e.g., in the 

stack, and forms

particulate matter upon condensation when subject to conditions

of cooling and dilution in the atmosphere.

(Source: Added at 

—

Ill. 

Reg.

_____,

effective 

_______________

Section 211.1470 Continuous Process

“Continuous process” means, with respect to manufacture of

polystyrene resin, a method of manufacture in which the styrene

raw material is delivered on a continuous basis to the

reactor in

which the styrene is polyinerized to polystyrene.

(Source:

Added at

—

Ill. Peg. 

_____,

effective

_______________

55

Section 211.1490 Control Device

“Control device” means equipment (such as an afterburner,

adsorber, fabric filter or scrubber) used to remove or prevent

the emission of an air contaminant from a contaminated exhaust

stream.

(Source: Added at — Ill. Reg. 

_____,

effective 

_______________

Section 211.1510 Control Device Efficiency

“Control device efficiency” means, for purposes of 35 Ill. Adm.

Code 218 and 219, the weight of VOM generated by an emission unit

which is destroyed or removed by a control device, divided by the

weight of

VOM generated by such unit entering the control device.

during a particular time period, expressed as a

percentage.

(Source:

Added at

—

Ill. Peg.

_____,

effective 

_______________

Section 211.1530 Conventional Soybean Crushing

Source

“Conventional soybean crushing source” means any hexane

extraction soybean crushing equipment that uses direct contact

steam for desolventizinq and producing toasted soy meals.

(Source: Added at 

—

Ill. Peg.

_____,

effective 

_______________

Section 211.1550 Conveyorized Degreasing

“Conveyorized degreasing” means the continuous process of

cleaning and removing soils from surfaces utilizing either cold

or vaporized solvents.

(Source: Added at — Ill. Reg. 

_____,

effective

_______________

Section 211.1570 Crude Oil

“Crude oil” means a naturally occurring mixture which consists of

hydrocarbons and sulfur, nitrogen, or oxygen derivatives of

hydrocarbons and which is a liquid at standard conditions.

(Source: Added at — Ill. 

Reg.

_____,

effective 

______________

56

Section 211.1590 Crude Oil Gathering

“Crude oil gathering” means the transportation of crude oil or

condensate after custody transfer between a production site and a

reception point.

(Source: Added at 

—

Ill. Reg. 

_____,

effective 

_______________

_________________________________ )

Section 211.1610 Crushing

“Crushing” means the fragmentation of non—metallic minerals by a

machine such as a -jaw, gyratory, cone, roll, rod, mill,

hammermill, and impactor.

(Source: Added at — Ill. Peg. 

_____,

effective 

_______________

Section 211.1630 Custody Transfer

“Custody transfer” means the transfer of produced petroleum

and/or condensate after processing and/or treating in the

producing operations, from storage tanks or automatic transfer

systems to pipelines or any other forms of

transportation.

(Source:

Added at

Ill. Peg.

_____,

effective

________________

Section 211.1650 Cutback Asphalt

“Cutback asphalt” means any asphalt which has been liguified by

blending with petroleum solvents other than residual fuel oil and

has not been emulsified with water.

(Source: Added at — Ill. Reg. 

_____,

effective 

_______________

Section 211.1670 Daily-Weighted

Average VOM Content

“Daily-weighted average VOM content” means the average VON

content of two or more coatings as

applied on a coating line

during any day,

taking into 

account the fraction

of total coating

volume that

each coating represents, as calculated with 

the

following equation:

n

MQ~W

I E

v,~__ç,

1/VT

i=l

where:

57

VOMW 

=

The average VON content of two or more

coatings as applied each day on a coating

line in units of kg VOM/l (lbs VON/gal) of

coating (minus water and any compounds which

are specifically exempted from the definition

of VOM),

n

=

The number of different coatings as applied

each day on a coating line,

The volume of each coating (minus water and

any compounds which are specifically exempted

from the definition of VOM) as applied each

day on a coating line in units of 1 (gal).

The VOM content of each coating as applied

each day on

a coating line in units of kg

VOM/l (lbs VON/gal) of coating (minus water

and any compounds which are specifically

exempted from the definition of VON), and

The total volume of all coatings (minus water

and any compounds which are specifically

exempted from the definition of

VON) as

applied each day on a coating line in units

of 1 (gal)

(Source: Added at — 

Ill. Peg.

_____,

effective 

______________

Section 211.1690

“Day” means, for purposes of Part 2b8 or Part 219, the

consecutive 24 hours beginning at 12:00 AN (midnight) local time

or beginning at affixed time consistent with the source’s

operatin~schedule, as provided below. A source may use a day

beginning at a time other than midnight which is consistent with

its operating schedule provided that the owner or operator of the

source first notifies that Agency in writing of such alternative,

describing why it would be more reasonable to maintain records on

this basis. The owner or operator shall notify the Agency in

writing prior to any change in the time at which a day begins.

(Source: Added at

Ill. Peg.

_____,

effective 

_______

Section 211.1710  Degreaser

“Degreaser” means any equipment or system used in solvent

cleaning.

58

(Source: Added at 

—

Ill. Reg. 

_____,

effective 

_______________

Section 211.1730

Delivery Vessel

“Delivery vessel” means any tank truck or trailer equipped with a

storage tank that is used for the transport of gasoline to a

stationary storage tank at a gasoline dispensing operation, bulk

gasoline plant, or bulk gasoline terminal.

(Source:

Added at

—

Ill. Reg.

_____,

effective 

_______________

Section 211.1750

Dip Coating

“Dip coating” means a method

of applying coatings in which the

part is submerged in a tank filled with the coating.

(Source:

Added at

—

Ill. Peg.

_____,

effective 

_______________

Section 211.1770  Distillate Fuel Oil

“Distillate fuel oil” means fuel oils of grade No. 1 or 2 as

specified in detailed requirements for fuel oil ASTM D—369—69

(1971) incorporated by reference in 35 Ill. Adm. Code 218.112 and

219.112.

(Source: Added at  

Ill. Peg. 

_____,

effective 

_______________

Section 211.1790  Drum

“Drum” means any cylindrical shipping container of 13 to

110-gallon capacity.

(Source:

Added at

—

Ill. Reg.

_____,

effective 

_______________

_________________________________ )

Section 211.1810  Dry Cleaning Operation or Dry Cleaning

Facility

“Dry cleaning operation” or

“Dry cleaning facility” means the

cleaning of fabrics using an essentially nonaqueous solvent by

means of one or more solvent washes, extraction of excess solvent

by spinning and

drying by tumbling in an airstream. The dry

cleaning operation or facility includes, but is not

limited to,

washers, dryers, filter and purification systems, waste disposal

systems, holding tanks, pumps and

attendant piping and valves.

(Source: Added at — Ill. Peg. 

_____,

effective 

_______________

59

Section 211.1830

Dump-Pit Area

“Dump—Pit area” means any area where grain is received at a

grain-handling or grain-drying operation.

(Source: Added at 

—

Ill. Reg.

_____,

effective 

______________

Section 211.1850

Effective Grate Area

“Effective prate area” means that area of a dump—pit grate

throuah which air passes, or would pass. when aspirated.

(Source: Added at — Ill. Peg. 

_____,

effective 

______________

Section 211.1870  Effluent Water SeParator

“Effluent water separator” means any tank, box, sump or other

apparatus in which any organic material floating on or

entrained

or contained in water entering such tank, box, sump or other

aPParatus is physically separated and removed from such water

prior to outfall, drainage or recovery of such water.

(Source: Added at  

Ill. Reg. 

_____,

effective 

_____________

Section 211.1890  Electrostatic Bell or Disc SPraY

“Electrostatic bell or disc spray” means an electrostatic spray

coating method in which a rapidly-spinning bell— or disc-shared

applicator is used to create a fine mist and a~p1y the coating

with high transfer efficiency.

(Source:

Added at

—

Ill. Reg.

_____,

effective

_____________

Section 211.1910  Electrostatic Spray

“Electrostatic spray” means a spray coating method in which

opposite electrical charges are applied to the substrate and the

coating. The coating is attracted to the object due to the

electrostatic potential between them.

(Source: Added at — 

Ill. Peg.

_____,

effective 

______________

Section 211.1930  Emission Rate

“Emission rate” means, if not otherwise stated in a specific

provision, the total quantity of a particular specified air

contaminant discharged into the atmosphere in any one-hour

60

period. For example, if not otherwise specified in 

35 Ill. Mm.

Code 218 or 219, emission rate means the

total auantity of

volatile organic material discharged into the atmosphere in any

one—hour period.

(Source: Added at 

—

Ill. Peg. 

_____,

effective 

_______________

Section 211.1950  Emission Unit

“Emission unit” means any part or activity at a stationary source

that emits or has the potential to emit any air pollutant.

(Source: Added at — Ill. Peg. 

_____,

effective 

________________

Section 211.1970

Enamel

“Enamel” means a coating that cures by chemical

cross—linking of

its base resin. Enamels can be distinguished from lacquers

because enamels are

not readily resoluble in their original

solvent.

(Source: Added at 

—

Ill. Peg. 

_____,

effective

_______________

Section 211.1990  Enclose

“Enclose” means, for purpose of 35 Ill. Adm. Code 215.481(c),

215.482(b), 218.481(c), 218.482(b), 219.481(c) and 219.482(b), to

cover any volatile organic liquid surface that is exposed to the

atmosphere.

(Source: Added at  

Ill. Reg. 

_____,

effective 

_______________

Section 211.2010  End Sealing Compound Coat

“End sealing compound coat”

means a can coating applied to can

ends which functions as a gasket when the end

is assembled onto

the can.

(Source: Added at  

Ill. Peg. 

_____,

effective 

_______________

Section 211.2050  Ethanol Blend Gasoline

“Ethanol blend gasoline” means a mixture of gasoline and at least

9 ethanol by volume.

(Source: Added at  

Ill. Peg. 

_____,

effective 

_______________

61

Section 211.2070  Excess Air

“Excess air” means air supplied in addition to the theoretical

guantity necessary for complete combustion of all fuel and/or

combustible waste material.

(Source: Added at  

Ill. Peg.

_____,

effective 

_______________

Section 211.2090  Excessive Release

“Excessive release” means, for PurPoses of 35 Iii. Adm. Code

215.144, 218.144 and 219.144, a discharge of more than 295 g

(0.65 ibs) of mercaptans and/or hydrogen sulfide into the

atmosphere in any 5-minute period.

(Source: Added at 

—

Ill. Reg. 

_____,

effective 

_______________

Section 211.2110  Existing Grain-Drying Operation

“Existing grain-drying operation” means any ~rain—drving

operation the construction or modification of which was commenced

prior to June 30, 1975.

(Source: Added at 

—

Ill. Reg. 

_____,

effective 

________________

Section 211.2130

Existing Grain-Handling Operation

“Existing grain-handling operation” means any grain-handling

operation the construction or modification of which was commenced

prior to June 30, 1975.

(Source: Added at — Ill. Peg. 

_____,

effective 

________________

Section 211.2150  Exterior Base Coat

“Exterior base coat” means a can coating applied to the exterior

of a two-piece can body to provide protection to the metal or to

provide background for any lithographic or printing operation.

(Source: Added at — Ill. Reg. 

_____,

effective 

_______________

Section 211.2170  Exterior End Coat

“Exterior end coat” means a can coating applied to the exterior

end of a can to provide protection to the metal.

62

(Source: Added at 

—

Ill. Reg. 

_____,

effective

Section 211.2190  External Floating Roof

“External floating roof” means a cover over an open to~storage

tank consisting of a double deck or pontoon single deck which

rests upon and is supported by the volatile organic liquid being

contained and is equipped with a closure seal or seals to close

the space between the roof edge and tank shell.

__________________    

Extreme Performance Coating

“Extreme performance coating” means any coating which during

intended use is exposed to any or all of the following: ambient

weather conditions, temperatures consistently above 95°C (203°F).

detergents. abrasive and scouring agents, solvents, or corrosive

atmospheres.

(Source: Added at

—

Ill. Peg. 

_____,

effective 

______________

Section 211.2230  Fabric Coating

“Fabric coating” means any protective, decorative or functional

coating which is applied onto or impregnated into a textile

fabric which is delivered to the coatina line as a roll, unwound

and coated as a continuous substrate.

(Source: Added at 

—

Ill. Reg.    

effective

Section 

211.2250  Fabric Coating Line

“Fabric coating line” means a coating line in which any

protective, decorative, or functional coating is applied onto or

impregnated into a textile fabric which

is delivered to the

coating line

as a roll, unwound and coated as a continuous

substrate.

(Source: Added at — Ill. Reg. 

_____,

effective 

__________

Section 211.2270  Federally Enforceable Limitations and

Conditions

“Federally enforceable limitations and conditions” means all

limitations and conditions which are enforceable by the

Administrator of the USEPA, including those requirements

(Source:

Section 211.2210

Added at 

—

Ill. Reg. 

_____,

effective

63

developed pursuant to 40 CFR Parts 60 and 61; requirements within

any applicable implementation plan; and any permit requirements

established pursuant to 40 CFR 52.21 or 40 CFR 52.737 or under

regulations approved pursuant to 40 CFR Part 51 Subpart I, 40 CFR

51.166 and 40 CFR Part 70.

(Source: Added at  

Ill. Peg. 

_____,

effective 

________________

Section 211.2310  Final Repair Coat

“Final repair coat” means, with respect to automobile or

light—duty truck assembly or manufacturing, a coating which is

used to repaint topcoat which is damaged during vehicle assembly.

(Source: Added at — Ill. Peg. 

_____,

effective 

_______________

Section 211.2330  Firebox

“Firebox” means the chamber or compartment of

a boiler or furnace

in which 

materials are burned, but not

the combustion chamber or

afterburner of an incinerator.

(Source: Added at 

—

Ill. Reg. 

_____,

effective 

_______________

Section 211.2350

Fixed—Roof Tank

“Fixed-roof tank” means a cylindrical shell with a permanently

affixed roof.

(Source: Added at 

—

Ill. Req. 

_____,

effective 

_______________

Section 211.2370  Flexographic Printing

“Flexographic printing” means a roll printing technique in which

the pattern to be applied

is raised above the printing roll and

the

image carrier is made of rubber or other elastomeric

materials.

(Source: Added at — Ill. Peg. 

_____,

effective 

_______________

Section 211.2390  Flexographic Printing Line

“Flexographic printing line” means a printing line performing

flexographic printing.

(Source:

Added at

—

Ill.

Peg.

_____,

effective

________________

64

Section 211.2410

Floating Roof

“Floating roof” means a roof on a stationary tank, reservoir, or

other container which moves vertically upon change in volume of

the stored material.

(Source:

Added at

—

Ill. Peg.

_____,

effective 

______________

Section 211.2430  Fountain Solution

“Fountain solution” means the solution used in certain methods of

printinq which is applied to the image ~1ate to maintain

hydrophilic properties of the non-image areas.

(Source: Added at — Ill. Peg. 

_____,

effective 

_______________

Section 211.2450  Freeboard Height

“Freeboard height” means, for open top

vapor degreasers, the

distance from the top of the vapor zone to the top of the

degreaser tank, and for cold

cleaning degreasers, the distance

from the solvent to the top of the degreaser tank.

(Source: Added at — 

Ill. Reg.

_____,

effective 

______________

Section 211.2470  Fuel Combustion Emission Unit or Fuel

Combustion Emission Source

“Fuel combustion emission unit” or “Fuel combustion emission

source” means any furnace, boiler,

or similar equipment used for

the primary ouroose of oroducirici heat or oower by ~1-~r~recth~l-

transfer.

(Source: Added at

—

Ill.

211.2490  Fugitive

Peg.

Particulate

effective

Section                 

Matter

“Fugitive particulate matter” means

any particulate matter

emitted into the atmosphere other than throuah a stack, prov1dcA

that nothing in this definition or in 35 

Ill. Mm. Code 212,

Subpart

K shall exempt any emission unit from compliance with

other provisions of 35 Ill. Adm. Code 212 otherwise a~p1icable

merely because of the absence of a stack.

(Source:

Added at

Ill. Reg.

_____,

effective

65

Section

211.2510  Full Operating Fbowrate

“Full operating flowrate” means maximum operating capacity of the

source. emission unit or process unit, as applicable.

(Source: Added at —— Ill. Reg. 

_____,

effective 

_______________

Section 211.2530  Gas Service

“Gas service” means that the equipment or component contains

process fluid that is in the gaseous state at operating

conditions.

(Source:

Added at

Ill. Peg.

_____,

effective 

_______________

Section 211.2550

Gas/Gas Method

“Gas/gas method” means either of

two methods for determining VON

caPture efficiency which rely only on gas phase measurements.

The first method

requires construction of a temPorarY total

enclosure (TTE) to ensure that all would-be fugitive emissions

are measured. The second method uses the building or room which

houses the coating line, printing line or other emission unit as

an enclosure. The second method requires that all other VON

lines or emission units within the room be shut down while the

test is performed, but all fans and blowers within the room must

be ooerated according to normal procedures.

(Source: Added at 

—

Ill. Peg. 

_____,

effective 

_______________

Section 211.2570  Gasoline

“Gasoline” means any petroleum distillate or petroleum

distillate/alcohol

blend having a Reid vapor pressure of 27.6 kPa

or greater which is used as a fuel for internal combustion

engines.

(Source: Added at —  

Ill. Peg. 

_____,

effective 

_______________

Section 211.2590

Gasoline Dispensing Operation or Gasoline

Dispensing Facility

“Gasoline dispensing operation” or “Gasoline dispensing facility”

means any site where gasoline js transferred from a stationary

storage tank to a motor vehicle

gasoline tank used to provide

fuel to the engine of that motor vehicle.

66

(Source: Added at

—

Ill. Peg.

effective

_________________________________

)

Section 211.2650  Grain

“Grain” means the whole kernel or seed of corn, wheat, oats.

soybeans and any other cereal or oil seed plant and the normal

fines, dust and foreign matter which results from harvesting,

handling or conditioning. The grain shall be unaltered by

grinding or processing.

(Source:

Added at

—

Ill. Reg.

_____,

effective 

____________

Section 211.2670

Grain—Drying Operation

“Grain—drying operation” means any operation, excluding aeration,

by which moisture is removed from grain and which typically uses

forced ventilation with the addition of heat.

(Source: Added at —  

Ill. Peg. 

_____,

effective 

________________

Section 211.2690  Grain—Handling and Conditioning Operation

“Grain-handling and conditioning operation” means a grain storage

facility and its associate grain transfer, cleaning, drying,

grinding and mixing operations.

(Source: Added at —  

Ill. Peg. 

_____,

effective 

________________

Section 211.2710  Grain-Handling Operation

“Grain—handling operation” means any operation where one or more

of the following grain-related processes (other than grain—drying

operation, portable grain-handling equipment, one-turn storage

space, and excluding flour mills and feed mills) are performed:

receiving, shipping, transferring, storing, mixing

or treating of

grain or other processes pursuant to normal grain operations.

(Source: Added at

Ill. Peg.

effective

)

Section 211.2730  Green—Tire Spraying

“Green tire sprayirici”    

the spraying of green tires, both

inside and outside, with release compounds which help remove air

from the tire during molding and prevent the tire from sticking

to the mold after curing.

67

(Source: Added at  

Ill. Peg. 

_____,

effective 

_______________

Section 211.2750  Green Tires

“Green tires” means assembled tires before molding and curing

have occurred.

(Source: Added at   

Ill. Peg. 

_____,

effective 

_______________

Section 211.2770  Gross Heating Value

“Gross heating value” means amount of heat produced when a unit

quantity of fuel is burned to

carbon dioxide and water vapor, and

the water vapor condensed as described in ASTM D2015-66, D900—55.

D1826—64 and D240—64 incorporated by reference in Section 211.101

of this Part.

(Source: Added at —  

Ill. Peg. 

_____,

effective 

_______________

Section 211.2790  Gross Vehicle Weight Rating

“Gross vehicle weight rating” means the value specified by the

manufacturer as the maximum design loaded weight of a single

vehicle.

(Source:

Added at

—

Ill. Reg. 

_____,

effective 

_______________

Section 211.2810  Heated Airless Spray

“Heated airless spray” means an airless spray coating method in

which the coating is heated just prior to application.

(Source: Added at

—

Ill. Peg. 

_____,

effective 

_______________

Section 211.2830

Heatset

“Heatset” means a class of lithography which requires a heated

dryer to solidify 

the printing inks.

(Source: Added at  

Ill. Peg. 

_____,

effective 

_______________

Section 211.2850  Heatset-Web-Off set Lithographic Printing Line

“Heatset-web—offset lithographic printing line” means a

lithographic printing line in which a blanket cylinder is used to

transfer ink from a plate cylinder to a substrate continuously

68

fed from a roll or an extension process and an oven is used to

solidify the printing inks.

(Source: Added at 

—

Ill. Peg. 

_____,

effective 

____________

_________________________________

)

Section 211.2870  Heavy Liquid

“Heavy liquid” means liquid with a true vapor pressure of less

than_0.3_kPa (0.04 psi) at 294.3°K (70°F) established in a

standard reference text or as determined by ASTM method D2879—86

(incorporated by reference in 35 Ill. Adm. Code 218.112 and

219.b12~or which has 0.1 Reid Vapor Pressure as determined by

ASTM method D323-82 (incorporated by reference in 35 Ill. Adm.

Code 215.105, 218.112 and 219.112); or which when distilled

requires a temperature of 421.95°1 (300°F) or greater to recover

10 percent of the liquid as determined by ASTM method D86-82

(incorporated by reference in 35 Ill. Mm.

216.1~~. 21.5.112

and 219.112)

~..I¼*C

- -

- - - -

- - - - - ——

(Source: Added at 

—

Ill. Peg.    

effective

Section 211.2890

Heavy Metals

“Heavy 

metals” means, for the

purposes of Section 9.4 of the Act,

elemental, ionic, or combined forms of arsenic, cadmium, mercury,

chromium, nickel and lead.

(Source: Added at —  Ill. Peg.    

effective

Section 211.2910  Heavy Off-Highway Vehicle Products

“Heavy off—highway vehicle products” means heavy construction,

mining, farming, or material handling equipment; heavy industrial

engines; diesel—electric locomotives and associated power

generation equipment; and the constituent parts of such equipment

or engines.

(Source: Added at  

Ill. Peg. 

_____,

effective 

_____________

Section 211.2930  Heavy Off-Highway Vehicle Products Coating

“Heavy off—highway vehicle products coating” means any

protective, decorative or functional coating applied onto the

surface of heavy off-highway vehicle products. However, a high

temperature aluminum coating to a diesel—electric locomotive in

Cook County is not a heavy off-highway vehicle products coating.

69

(Source: Added at —  Ill. Peg. 

_____,

effective 

_______________

Section 211.2950  Heavy Off-Highway Vehicle Products Coating

Line

“Heavy off-highway vehicle products coating line” means a coating

line in which any protective, decorative, or functional coating

is_applied onto the surface of heavy off-highway vehicle

products. However, a~~licationof a high temperature aluminum

coating to a diesel-electric locomotive in Cook County is not a

heavy off-highway vehicle Products coating line or tart of a

heavy off-highway vehicle Products coating line.

(Source: Added at —  Ill. Reg. 

_____,

effective 

_______________

Section 211.2970  High Temperature Aluminum Coating

“High temperature aluminum coating” means a coating that is

certified to withstand a temperature of 537.8°C (1000°F) for 24

hours.

(Source: Added at —  

Ill. Peg. 

_____,

effective

_______________

Section 211.2990  High Volume Low Pressure (HVLP) Spray

“High volume low pressure

(HVLP) 

spray” means equipment used to

apply coatings by means of a spray gun which operates between 0.1

and

10 psig air pressure.

(Source:

Added at

—

Ill. Peg.

_____,

effective 

_______________

Section 211.3010  Hood

“Hood” means a partial enclosure or canopy for capturing and

exhausting, bY means of 

a draft, the organic vapors or

other

fumes produced from a coating line, printing line or other

emission unit.

(Source: Added at 

—

Ill. Reg. 

_____,

effective 

______________

Section 211.3030  Hot Well

“Hot well” means the reservoir of a condensing unit receiving the

condensate from a barometric condenser.

(Source:

Added at

—

Ill. Reg. 

_____,

effective

_______________

70

Section 211.3050  Housekeeping Practices

“Housekeeping practices” means those activities specifically

defined in the list of housekeeping practices developed by the

Joint EPA

Industry Task

Force and included herein under 35 

Iii.

Adm. Code 

212.461.

(Source: Added at 

—

Ill. Req. 

_____,

effective 

_______________

Section 211.3070  Incinerator

“Incinerator” means a combustion apparatus in which refuse is

burned.

(Source:

Added at

—

Ill. Peg.

_____,

effective 

_______________

Section 211.3090

Indirect Heat

Transfer

“Indirect heat transfer” means transfer of heat in such a way

that the source of heat does not come into direct contact with

process materials.

(Source:

Added at

—

Ill. Reg.

_____,

effective

_______________

Section 211.3110  Ink

“Ink” means a coating used in printing, impressing, or

transferring words, pictures, designs or other images onto a

substrate.

(Source: Added at —  Ill. Peg. 

_____,

effective 

_______________

Section 211.3130

In—Process Tank

“In—process tank”

means, with respect to manufacture of

pharmaceuticals. a container used for mixing, blending, heating,

reacting, holding, crystallizing,

evaporating or

cleaning

operations.

(Source: Added at —  

Ill. Peg. 

_____,

effective 

_______________

Section 211.3150  In-Situ Sampling Systems

“In-situ sampling systems” means nonexractive samplers or in-line

samplers.

71

(Source: Added at —  

Ill. Peg. 

_____,

effective 

_______________

Section 211.3170  Interior Body Spray Coat

“Interior body spray coat” means a can coating applied by spray

to the interior of a can body.

(Source: Added at  

Ill. Peg.

effective 

_______________

Section 211.3190  Internal-Floating Roof

“Internal—floating roof” means a cover or roof in a fixed—roof

tank which rests upon and is supported by the volatile organic

liquid being contained and is equipped with a closure seal or

seals to close the space between the roof edge and tank shell.

(Source: Added at

—

Ill. Peg. 

_____,

effective 

______________

Section 211.3210  Internal Transferring Area

“Internal transferring area” means areas and associated equipment

used for conveying grain among the various grain operations.

(Source: Added at  

Ill. Reg. 

_____,

effective 

_______________

Section 211.3230  Lacquers

“Lacquers” means, with respect to coating of wood furniture, any

clear wood finishes formulated with nitrocellulose or synthetic

resins to dry by evaporation without chemical reaction, including

clear lacquer sanding

sealers.

(Source:

Added at

Ill. Reg.

_____,

effective 

_______________

Section 211.3250  Large Appliance

“Large appliance” means any residential and commercial washers,

dryers, ranges, refrigerators, freezers, water heaters,

dishwashers, trash compactors, air conditioners, and other

similar products.

(Source: Added at —  

Ill. Peg.

_____,

effective 

______________

Section 211.3270  Large Appliance Coating

72

“Large appliance coating” means any protective, decorative or

functional coating applied onto the surface of large appliances

or to the constituent metal parts (including, but not limited to,

doors, cases, lids, panels, and interior support parts) of large

appliances.

(Source: Added at 

—

Ill. Reg.

effective 

_______________

_________________________________ 

)

Section 211.3290  Large Appliance Coating Line

“Large appliance coating line” means a coating line in which any

protective, decorative, or functional coating is applied onto the

surface of large appliances or to the constituent metal parts

(including but not limited to doors, cases, lids, panels and

interior parts) of large appliances.

(Source: Added at  

Ill. Req. 

_____,

effective 

________________

_________________________________

)

Section 211.3310  Light Liquid

“Light liguid” means VON in the liquid state which is not defined

as heavy liquid.

(Source: Added at  

Ill. Peg. 

_____,

effective 

_______________

Section 211.3330  Light-Duty Truck

“Light-duty truck” means any motor vehicle with a gross vehicle

weight rating of 3,850 kg or less, designed mainly to transport

Property.

(Source: Added at 

—

Ill. Peg. 

_____,

effective 

________________

Section 211.3350

Light Oil

“Light oil” means a

liquid condensed or absorbed from coke oven

gas composed of

benzene, toluene. and xylene.

(Source:

Added at

Ill. Peg.

_____,

effective 

_______________

Section 211.3370  Liquid/Gas Method

“Liquid/gas method” means either of two methods for determining

VOM capture efficiency which require both gas phase and liquid

phase measurements and analysis. The first method requires

construction of a temporary total enclosure (TTE) to ensure that

all would-be fugitive emissions are measured. The second method

73

uses the building or room which houses the coating line, printing

line or other emission unit as an enclosure. The second method

requires that all other VON lines or emission units within the

room be shut down while the test is performed, but all fans and

blowers within the room must

be ooerated according to normal

procedures.

(Source: Added at —  Ill. Peg. 

_____,

effective 

________

Section 211.3390  Liquid-Mounted Seal

“Liquid—mounted seal” means a primary seal mounted in continuous

contact with the liquid between the tank wall and the floating

roof edge around the circumference of the roof.

(Source: Added at —  Ill. Peg. 

_____,

effective 

________)

Section 211.3410  Liquid Service

“Liquid service” means that the equipment or component contains

process fluid that is in a liquid state at operating conditions.

(Source: Added at —  

Ill. Peg. 

_____,

effective

________)

Section 211.3430  Liquids Dripping

“Liquids dripping” means any visible leaking from a seal

including spraying, misting, clouding and ice formation.

(Source:

Added at

Ill. Reg.

_____,

effective 

_______________

Section 211.3450  Lithographic Printing Line

“Lithoara~hicprinting line” means a web or. sheetfed printing

line in which each roll printer uses a roll where both the image

and non—image areas are essentially in the same Plane

(planographic).

(Source: Added at  

Ill. Peg. 

_____,

effective 

______________

Section 211.3470  Load-Out Area

“Load—out area” means any area where grain is transferred from

the grain-handling operation to any vehicle for shipment or

delivery.

(Source: Added at 

—

Ill. 

Peg.

_____,

effective 

_______________

74

Section 211.3490

Low Solvent Coating

“Low solvent coating” means a coating which contains less organic

solvent than the conventional coatings used by the industry. Low

solvent coatings include water—borne, higher solids,

electro-deposition and powder coatings.

(Source: Added at 

—

Ill. Peg. 

_____,

effective 

_____________

Section 211.3510  Magnet Wire

“Magnet wire” means aluminum or copper wire which may

subsequently be used in an electromagnetic device.

(Source: Added at 

—

Ill. Peg. 

_____,

effective 

_____________

_________________________________

)

Section 211.3530  Magnet Wire Coating

“Magnet wire coating” means any electrically insulating varnish

or enamel or other protective, decorative or functional coating

applied onto the surface of magnet wire.

(Source: Added at

—

Ill. Peg. 

_____,

effective 

_____________

Section 211.3550  Magnet Wire Coating Line

“Magnet wire coating line” means a coating line in which any

electrically insulating varnish or enamel or other protective,

decorative, or functional coating is applied onto the surface of

macmet wire

(Source: Added at —  Ill

211.3570

Malor

Re

Dump

g.

effective

Section

Pit

“Malor 

dump

oit”

— — ,I,.__,_,,_J

~nv dump pit with an annual grain

through-put of more than 300.000 bushels, or which receives morn

than 40 of the annual grain through—put of the grain-handling

operation.

(Source: Added at —  

Ill.

Peg. 

_____,

effective 

__________

Section 211.3590  Mal or Metropolitan Area (MMA)

“Malor Metropolitan Area (MMA)” means any county or group of

counties which is defined by the following Table:

75

MAJOR METROPOLITAN 

AREAS

IN ILLINOIS (MMA’s)

COUNTIES INCLUDED IN NNA

Champaign-Urbana    

ChamPaign

Chicago         

Cook, Lake, Will, DuPage,

McHenrv, Kane, Grundy.

Kendall, Kankakee

Decatur         

Macon

Peoria

Peoria, Tazewell

Rockford        

Winnebago

Rock Island 

Moline  

Rock Island

Springfield

San~ainon

St.

Louis (Illinois)

St. Clair, Madison

Bloomington 

—

Normal  

McLean

(Source: Added at 

—

Ill. Reg. 

_____,

effective 

___________

Section 211.3610  Major Population Area (MPA)

“Malor Population Area (NPA)” means areas of major population

concentration in Illinois, as described below:

The area within the counties of Cook~ Lake; DuPage;

Will; the townships of Burton, Richmond, McHenry,

Greenwood, Nunda, Door, Algonquin, Grafton and the

municipality of Woodstock. plus a zone extending two

miles beyond the boundary of said municipality located

in McHenry County; the townships of Dundee, Rutland,

Elgin, Plato, St. Charles, Campton, Geneva,

Blackberry,

Batavia, Sugar Creek and Aurora located in Kane County;

and the municipalities of Kankakee, Bradley and

Bourbonnais, ~1us a zone extending two miles beyond the

boundaries of said municipalities in Kankakee County.

The area within the municipalities of Rockford and

Loves Park, ~1us a zone extending two miles beyond the

boundaries of said municipalities.

The area within the municipalities of Rock Island,

Moline, East Moline, Carbon Cliff, Milan, Oak Grove,

Silvis. Hampton, Greenwood

and Coal Valley. plus a zone

extending two miles beyond the boundaries of said

municipalities.

The area within the municipalities of Galesbur~and

East Galesburg, plus a zone extending two miles beyond

the boundaries of said municipalities.

76

The

area within the municipalities of Bartonville.

Peoria and Peoria Heights, ~1us a zone extending two

miles beyond the boundaries of said municipalities.

The area within the municipalities of Pekin, North

Pekin, Marquette Heights. Creve Coeur and East Peoria,

plus a zone extending two miles beyond the boundaries

of said municipalities.

The

area within the municipalities of Bloomington and

Normal. plus a zone

extending two miles beyond the

boundaries of said municipalities.

The area within the municipalities of Champaign. Urbana

and Savoy, plus a zone extending two miles beyond the

boundaries of said municipalities.

The area within the municipalities of Decatur. Mt.

Zion, Harristown and Forsyth, plus a zone extending two

miles beyond the boundaries of said municipalities.

The area within the municipalities of

Springfield.

Leland Grove. Jerome. Southern View. Grandview, Sherman

and Chatham, plus a zone extending two miles beyond the

boundaries of said municipalities.

The area within the townships of Godfrey, Foster, Wood

River, Fort Russell, Chouteau, Edwardsville, Venice.

Nameoki, Alton, Granite City and Collinsville located

in Madison County; and the townships of Stites,

Canteen,

Centreville, Caseyville, St. Clair. Sugar Loaf

and Stookey located in St. Clair County.

(Source: Added at 

—

Ill. Peg. 

_____,

effective 

_______________

Section 211.3630  Manufacturing Process

“Manufacturing process” means a method whereby a process emission

unit or series of process emission units is used to convert raw

materials, feed stocks, subassemblies, or other constituent parts

into a product. either for sale or for use in a subsequent

manufacturing process.

(Source: Added at 

—

Ill.

Reg.   

effective 

_______________

Section 211.3650  Marine Terminal

“Marine terminal” means a facility

primarily engaged in loading

and unloading watercraft.

77

(Source: Added at 

—

Ill. Reg. 

_____,

effective 

________________

Section 211.3670  Material Recovery Section

“Material recovery section” means, with resPect to manufacture Qf

polystyrene resin, any eguipment designed to transPort and

recover stvrene monomer and other impurities from other products

and by-products in a polystyrene plant, including but not limited

to the

stvrene devolatizer unit and stvrene recovery unit.

(Source: Added at —  

Ill. Peg.

_____,

effective 

_______________

Section 211.3690  Maximum Theoretical Emissions

“Maximum theoretical emissions” means the quantity of volatile

organic material emissions that theoretically could be emitted bY

a stationary source before

add—on controls based on the design

capacity or maximum production capacity of the

source and 8760

hours per year. The design capacity or maximum production

capacity includes use of coating(s) or ink(s) with the highest

volatile organic material content actually used in practice by

the

source, provided, however, the Agency shall, when

appropriate, and upon request by the permit applicant, limit the

“maximum theoretical emissions” of a source by the imposition of

conditions in a federally enforceable operating permit for such

source. Such conditions shall not be inconsistent with

requirements of the Clean Air Act, as amended, or any applicable

~guirements established by the Board. Such conditions shall be

established in Place of design capacity or maximum production

capacity in calculating the “maximum theoretical emissions” for

such source and may include, among

other things, the

establishment of production limitations, caPacity limitations, or

limitations on the volatile organic material content of coatings

or inks, or the hours of operation of any emission unit, or a

combination of any such limitat~ions. Production or capacity

limitations shall be established on a basis of no longer than one

month excePt in those cases where a limit spanning a longer

period of time is appropriate. In such cases, a limit or

limitation must not exceed an annual limit rolled on a basis of

at most a month; that is, for example, a monthly production or p

capacity level must be determined for each parameter subject to a

production or capacity limitation and added to the eleven Prior

monthlY levels for monthly comparison with the annual limit. Any

production or capacity limitations shall be verified through

appro~rjate recordkeeping.

(Board Note: The USEPA may deem

operating permits which do

not conform to 

the operating permit program requirements and the

requirements of USEPA’s underlying regulations, including the

78

requirement that limitations be quantifiable and enforceable as a

practical matter, not “federally enforceable.”)

(Source: Added at 

—

Ill. Peg. 

_____,

effective 

______________

Section 211.3710  Metal Furniture

“Metal furniture” means a furniture piece including, but not

limited to, tables, chairs, waste baskets, beds, desks, lockers..

benches, shelving, file cabinets, lamps, and room dividers made

in whole or in part of metal.

(Source: Added at 

—

Ill. Peg. 

_____,

effective 

______________

Section 211.3730  Metal Furniture Coating

“Metal furniture coating” means any protective~, decorative or

functional coating applied onto the surface of any metal

furniture or any metal part which will be assembled with other

metal, wood, fabric, plastic or glass parts to form metal

furniture. However, an adhesive is not a metal furniture

coating.

(Source: Added at —  Ill. Reg. 

_____,

effective 

______________

Section 211.3750  Metal Furniture Coating Line

“Metal furniture coating line” means a coating line in which any

protective, decorative, or

functional coating is applied onto the

surface of any metal furniture or any metal part which will be

assembled with other metal, wood, fabric or glass parts to form

metal furniture. However, application of an adhesive is not a

metal furniture coating line or part of a metal furniture coating

line.

(Source: Added at 

—

Ill. Peg.    

effective

Section’ 211.3770  Metallic Shoe—Type Seal

“Metallic shoe-type seal” means a primary or secondary seal

constructed of metal sheets (shoes) which are joined together to

form a ring, springs or levers which attach the shoes to the

floating roof and hold the shoes against the tank wall, and a

coated membrane which is suspended from the shoes to the floating

roof.

(Source: Added at

—

Ill. 

Reg.

_____,

effective

79

Section 211.3790  Miscellaneous Fabricated Product

Manufacturing Process

“Miscellaneous fabricated product manufacturing process” means:

A manufacturing process involving one or more of the

following applications, including any drying and curing

of formulations, and capable of emitting VON:

Adhesives to fabricate or assemble tarts or

products;

Asphalt solutions to gaper or fiberboard;

Asphalt to paper or felt;

Coatings 

or dye

to leather;

Coatings to plastic;

Coatings to rubber or glass;

Disinfectant material to manufactured items;

Plastic foam scrap or “fluff” from the manufacture

of foam containers and packaging material to form

resin pellets;

Resin solutions to fiber substances;

Rubber solutions to molds; or

Viscose solutions for food casings.

The storage and handling of formulations associated

with the process described above and the use and

handling of organic liquids and other substances for

clean-up operations associated with the process

described in this definition would be included.

(Source: Added at —  Ill. Reg. 

_____,

effective 

_______________

Section 211.3810  Miscellaneous Formulation Manufacturing

Process

“Miscellaneous formulation manufacturing process” means:

A manufacturing process which compounds one or more of

the following and is capable of emitting VON:

Adhesives

80

Asphalt solutions;

Caulks, sealants, or waterproofing agents;

Coatings, other than paint and ink;

Concrete curing compounds;

Dyes;

Friction materials and compounds;

Resin solutions;

Rubber solutions; or

Viscose solutions.

The storage and handling of formulations associated

with the process described above, and the use and

handling of organic liquids and other substances for

clean—up operations associated with the process

described in this definition would be included.

(Source: Added at —  

Ill. Peg.

_____,

effective 

____________

Section 211.3830  Miscellaneous Metal Parts and Products

“Miscellaneous metal parts and products” for the purpose of 35

Ill. Adin. Code 215. Subpart F, shall include farm machinery,

garden machinery, small appliances, commercial machinery.

industrial machinery, fabricated metal products and any other

industrial category in which metal parts or products under the

Standard Industrial Classification Code for Major Groups 33, 34,

35, 36. 37, 38 or 39 are coated, with the exception of the

following: coating lines subject to 35 Ill. Adm. Code 215.204(a)

through (i) and (k). architectural coatings, automobile or

light-duty truck refinishing, the exterior of marine vessels and

the customized top coating of automobiles and trucks if

production is less than thirty-five vehicles per day.

(Source: Added at 

—

Ill.

Peg. 

_____,

effective 

______________

Section 211.3850  Miscellaneous Metal Parts and Products

Coating

“Miscellaneous metal parts and products coating” means, for

purposes of 35 Ill. Adm. Code 218 and 219. any protective,

decorative or functional coating applied onto the surface of any

81

metal part or metal product, even if attached to or combined with

a nonmetal tart or product

Including but not limited

to underbody anti-chip (e.g.~,

underbody ~lastisol) automobile and light-duty truck

coatings

But not including

the following coatings which are

subject to seParate regulations: can coatings, coil

coatings, metal furniture coatings, large appliance

coatings. magnet wire coatings, and prime coat, primer

surfacer coat, topcoat and final repair coat for

automobile and light-duty trucks; and

g~ Not including the following coatings: architectural

coatings, automobile or light-duty truck refinishing

coatings, coatings applied to the exterior of marine

vessels, coatings applied to the exterior of airplanes,

customized topcoat for automobiles and trucks if

production is less than 35 vehicles per day, and high

temPerature aluminum coating applied to diesel-electric

locomotives in Cook County.

(Source: Added at —  Ill. Peg. 

_____,

effective 

_______________

_________________________________

)

Section 211.3870  Miscellaneous Metal Parts or Products Coating

Line

“Miscellaneous metal parts or products coating line” means, for

purposes of 35 Ill. Adm. Code 218 and 219, a coating line in

which any protective, decorative, or functional coating is

applied onto the surface of any meta. Part or metal product, even

if attached to or combined with a nonmetal part or product

~  Including but not limited to underbody anti-chip (e.g.,

underbody ~lastisol) automobile and light-duty truck

coatings

~j But not including the following coatings which are

subiect to separate regulations: can coatings, coil

coatings, metal furniture coatings. 1ar~eappliance

coatings, magnet wire coatings, and prime coat, primer

surfacer coat, topcoat and final repair coat for

automobile and light-duty trucks;

and

çj. Not including the

following coatings: architectural

coatings, automobile or light-duty truck refinishing

coatings, coatings applied to the exterior of marine

vessels, coatings applied to the exterior of airplan~

customized topcoat for automobiles and trucks if

production is less than 35 vehicles per days and hjg~

82

temperature aluminum coating applied to diesel—electric

locomotives in Cook County.

(Source:

Added at

—

Ill. Reg.

_____,

effective 

_______________

Section 211.3890  Miscellaneous Organic Chemical Manufacturing

Process

“Miscellaneous organic chemical manufacturing process” means:

A manufacturing process which produces, by chemical

reaction, one or more of the following organic

compounds or mixtures of organic compounds and which is

capable of emitting volatile organic material (VOM):

Chemicals listed in Appendix A of 35 Ill. Mm.

Code 215, 218 or 219, as applicable;

Chlorinated and sulfonated compounds;

Cosmetic, detergent, soap, or surfactant

intermediaries or specialties and products;

Disinfectants;

Food additives;

Oil and petroleum product additives;

Plasticizers;

Resins or polymers;

Rubber additives;

Sweeteners; or

Varnishes.

The storage and handling of formulations associated

with_the process described above and the use and

handling of organic liquids and other substances for

clean-up operations associated with the process

described in this definition would be included.

(Source: Added at —  

Ill. Peg. 

_____,

effective 

________________

83

Section 211.3910  Mixing Operation

“Mixing operation” means the operation of combining two or more

ingredients. of which at least one is a grain.

(Source: Added at —— Ill. Reg. 

_____,

effective 

________________

Section 211.3930  Monitor

“Monitor” means to measure and record.

(Source: Added at —  

Ill. Reg.

_____,

effective 

_______________

Section 211.3970  Multiple Package Coating

“Multiple package coating” means a coating made from more than

one different ingredient which must be mixed prior to using and

has a limited Pot life due to the chemical reaction which occurs

upon mixing.

(Source: Added at 

—

Ill. Peg. 

_____,

effective 

________________

Section 211.3990  New Grain—Drying Operation

“New grain—drying operation” means any grain-drying operation the

construction or modification of which commenced on or after June

30, 1975.

(Source: Added at —  

Ill. Peg. 

_____,

effective 

________________

Section 211.4010  New Grain—Handling Operation

“New grain-handling operation” means any grain—handling operation

the construction or modification of which commenced on or after

June 30, 1975.

(Source: Added at

—

Ill. Reg.   

effective 

________________

Section 211.4030  No Detectable Volatile Organic Material

Emissions

“No detectable volatile organic material emissions” means a

discharge of volatile organic material into the atmosphere as

indicated by an instrument reading of less than 500 ~ above

background as determined in accordance with 40 CFR 60.485(c)

(incorporated by reference in 35 Ill. Adm. Code 215.105, 218.112,

and 219.112).

84

(Source: Added at 

—

Ill. Peg.

_____,

effective 

_________

Section 211.4050  Non-contact Process Water Cooling Tower

“Non—contact process water cooling tower” means a towerlike

device in which water is cooled by contact with atmospheric air

and evaporation, where such water has been or will be used for

cooling of a process stream where VON is present without

intentional direct contact of the cooling water and process

stream.

(Source: Added at 

—

Ill. Peg. 

_____,

effective 

_____________

Section 211.4070  Offset

“Offset” means,

with respect toprinting, use of a blanket

cylinder to transfer ink from the olate cv~~r~r~-to the surface

to be orinted.

(Source: Added at —

211.4090  One

Ill. Peg.

Hundred Percent

effective

Section                

Acid

“One hundred percent acid” means, with respect to sulfuric and

nitric acids, acid with a specific gravity of 1.8205 at 30°C in

the case of

sulfuric acid and 1.4952 at 30°C in the case of

nitric acid.

(Source: Added at 

—

Ill. Peg.

_____,

effective 

______________

Section 211.4110  One—Turn Storage Space

“One-turn storage space” means that space used to store grain

with a total annual through-put not in excess of the total bushel

storage of that space.

(Source: Added at 

—

Ill. Peg. 

_____,

effective 

_____________

Section 211.4130  OPacity

“Opacity” means a condition which renders material partially or

wholly impervious to transmittance of light and causes

obstruction of an observer’s view. For the

purposes of these

regulations,

the following equivalence between opacity and

Ringelmann shall be employed:

85

Opacity Percent  

Rinaelmann

0.5

100

5.

(Source:

Added at

—

Ill. Peg.

_____,

effective 

____________

Section 211.4150  OPaaue Stains

“OPaque stains” means all stains that are not semi-transparent

stains.

(Source: Added at 

—

Ill. Peg. 

_____,

effective 

____________

Section 211.4170  OPen ToP VaPor Degreasing

“Open to~vapor degreasing” means the batch process of cleaning

and removing soils from surfaces bY condensing hot solvent vapor

on the colder metal parts.

(Source: Added at —  

Ill. Peg. 

_____,

effective 

_______________

Section 211.4190  Open-Ended Valve

“Open-ended valve” means any valve, except pressure relief

devices, having one side of the valve in contact with process

fluid and one side open to the atmosphere. either directly or

through open piping.

(Source:

Added at

Ill. Reg.

_____,

effective 

_______________

Section 211.4210  OPerator of a Gasoline Dispensing Operation

or Operator of a Gasoline Dispensing Facility

“Operator of gasoline dispensing operation” or “Operator of a

gasoline dispensing facility” means any person who is the lessee

of or operates, controls or supervises a gasoline dispensing

operation or a gasoline dispensing facility.

(Source: Added at —  Ill. Peg. 

_____,

effective 

______________

Section 211.4230  Organic Compound

86

“Organic compound” means any compound of carbon, excluding carbon

monoxide. carbon dioxide, carbonic acid, metallic carbides or

carbonates. and ainmonium carbonate.

(Source:

Added at

—

Ill. Reg.

_____,

effective 

______________

Section 211.4250  Organic Material and Organic Materials

~j “Organic materials” means, for the ~ur~oses of Section

9.4 of the Act, any chemical compound of carbon,

including diluents and thinners which are liquids at

standard conditions and which are used as dissolvers,

viscosity reducers or cleaning agents, including

~olychlorinated dibenzo—p-dioxins, polychlorinated

dibenzofurans and polynuclear aromatic hydrocarbons but

excluding methane, carbon monoxide, carbon dioxide,

carbonic acid, metallic carbonic acid, metallic

carbide, metallic carbonates and ammoniun carbonate are

not organic materials.

~  “Organic material” means, for the purpose of 35 Ill.

Adm. Code 215, 218 and 219, any chemical compound of

carbon

including diluents and thinners which are

liquids at standard conditions and which are used as

dissolvers, viscosity reducers, or cleaning agents, but

excluding methane, carbon monoxide, carbon dioxide,

carbonic acid, metallic carbonic acid, metallic

carbide, metallic carbonates, and ammonium carbonate.

(Source:

Added at

—

Ill. Peg. 

_____,

effective

_______________

Section 211.4270  Organic Vapor

“Organic vapor” means the gaseous phase of an organic material or

a mixture of organic materials present in the atmosphere.

(Source: Added at —  

Ill. Peg. 

_____,

effective 

_______________

Section 211.4290  Oven

“Oven” means, with respect to a coating line or printing line, a

chamber within which heat is used for one or more of the

following purposes: dry, bake, cure, or polymerize a coating or

ink.

(Source: Added at —  Ill. Reg. 

_____,

effective 

_______________

Section 211.4310

87

Overall Control

“Overall control” means the product of the caPture efficiency and

the control device efficiency.

(Source: Added at —  

Ill. Peg. 

_____,

effective 

_______________

Section 211.4330  Overvarn i sh

“Overvarnish” means a transparent coating applied directly over

ink or coating.

(Source: Added at  

Ill. Peg. 

_____,

effective

Section 211.4350  Owner of a Gasoline Dispensing Operation or

Owner of a Gasoline Dispensing Facility

“Owner of a gasoline dispensing operation” or “Owner of a

dispensin~facility” 

any Person who has

leaal or

equitable title to a s’~~v storaae tank at a ~

ciign~nsina oo~r~tion

(Source: Added at

—

Ill. Peg.    

effective

Section 211.4370  Owner or Operator

“Owner or operator” means any person who owns, operates, 

controls, or supervises a source, an emission unit or air

pollution control equipment.

(Source: Added at

Section 211.4390

Ill. Peg. 

_____,

effective

Packaging Rotogravure Printing

“Packaging rotogravure Printing” means rotogravure printing upon

paper. paper board, metal foil, plastic uilm. and other

substrates, which are, in subseauent operations, formed into

packaging Products or labels for articles to be sold.

(Source: Added at —  

Ill. Peg.

_____,

effective 

______________

)

Section 211.4410  

Packaging Rotogravure Printing Line

“Packaging rotogravure printing line” means a rotogravure

printing line performing packaging rotogravure printing.

88

(Source: Added at —  Ill. Peg. 

_____,

effective 

_______________

Section 211.4430  Pail

“Pail” means any cylindrical ship~inacontainer of 1 to 12-gallon

capacity and constructed of 29—gauge and heavier material.

(Source: Added at 

—

Ill. Peg. 

_____,

effective 

_______________

_________________________________

)

Section 211.4450  Paint Manufacturing Source or Paint

Manufacturing Plant

“Paint manufacturing source” or “Paint manufacturing plant” means

a source that mixes, blends, or compounds enamels, lacquers..

sealers, shellacs, stains, varnishes, or pigmented surface

coatings.

(Source: Added at —  

Ill. Req. 

_____,

effective 

________________

Section 211.4470  Paper Coating

“Paper coating” means any protective, decorative or functional

coating applied on paper, plastic film, or metallic foil to make

certain products, including but not limited to adhesive tapes and

labels,

book covers, post cards, office copier paper, drafting

paper, or pressure sensitive tapes. For purposes of 35 Ill. 

Adm.

Code 

218 and

219, paper coating includes coatings applied by

impregnation or saturation.

(Source: Added at —  

Ill. Peg. 

_____

effective 

________________

_________________________________

)

Section 211.4490  Paper Coating Line

“Paper coating line” means a coating line in which any

protective, decorative, or functional coating is applied on,

saturated into, or impregnated into paper, plastic film, or

metallic foil to make certain products, including but not limited

to adhesive tapes and labels, book covers, post cards, office

copier paper, drafting paper and pressure sensitive tapes. For

pi~irposesof 35 Ill. Adm. Code 218 and 219, a paper coating line

includes saturation or impregnation.

(Source: Added at  

Ill. Reg. 

_____,

effective 

_______________

89

Section 211.4510  Particulate Matter

“Particulate matter” means any solid or liquid material, other

than water, which exists in finely divided form.

(Source: Added at —  

Ill. Reg. 

_____,

effective 

_______________

Section 211.4530  Parts Per Million (Volume) or PPM (Vol)

“Parts ~er million (volume)” or “PPM (vol)” means a volume/volume

ratio whidh expresses the volumetric concentration of gaseous air

contaminant in a million unit volume of gas.

(Source: Added at —  Ill. Peg. 

_____,

effective 

_______________

Section 211.4550  Person

“Person” means any individual; corporation; Partnership; firm;

association; trust; estate; public or private institution; group;

state; municipality; political subdivision of a state; any

agency, department,

or instrumentality of the United States: and

~ officer, agent, or employee of any of the above.

(Source: Added at —  

Ill. Reg. 

_____,

effective 

________________

Section 211.4590  Petroleum

“Petroleum” means the crude oil removed from the earth and the

oils derived from tar sands, shale, and coal.

(Source: Added at —  Ill. Reg. 

_____,

effective 

_______________

Section 211.4610  Petroleum Liquid

“Petroleum liquid” means crude oil, condensate or any finished or

intermediate Product manufactured at

a petroleum refinery, but

not including Number 2 through Number 6 fuel oils as specified in

ASTM D-396-69 (incorporated bY reference in 35 Ill. Adm. Code

218.112 and 219.112), gas turbine fuel oils Numbers 2—GT through

4-GT as specified jn ASTM D-2880-71 (incorporated bY reference in

218.112 and 219.112) or diesel fuel oils Numbers 2—D and 4—D. as

specified in ASTN D-975-68 (incorporated by reference in 35 Ill.

Adm. Code 218.112 and 219.112).

(Source: Added at —  Ill. Peg. 

_____,

effective 

_______________

90

Section 211.4630  Petroleum Refinery

“Petroleum refinery” means any source engaged in producing

gasoline, kerosene, distillate fuel oils, residual fuel oils~,

lubricants, or other products through distillation of petroleum,

or through redistillation, cracking, or reforming of unfinished

petroleum derivatives.

(Source: Added at 

—

Ill. Reg. 

_____,

effective 

_______________

Section 211.4650  Pharmaceutical

“Pharmaceutical” means any compound or mixture, other than food,

used in the prevention, diagnosis, alleviation, treatment, or

cure of disease in human and animal.

(Source: Added at —  Ill. Peg. 

_____,

effective 

_______________

Section 211.4670  Pharmaceutical Coating Operation

“Pharmaceutical coating operation” means a device in which a

coating is applied to a pharmaceutical, including air drying or

curing of the coating.

(Source: Added at —  

Ill. Peg. 

_____,

effective

______________

Section 211.4690  Photochemically Peactive Material

“Photochemically reactive material” means any organic material

with an aggregate of more than 20 percent of its total volume

composed of the chemical compounds classified below or the

composition of which exceeds any of the following individual

percentage composition limitations. Whenever any photochemically

reactive material or any constituent of any organic material may

be_classified from its chemical structure into more than one of

the above groups of organic materials, it shall be considered as

a member of the most reactive group, that is, the group having

the least allowable percent of the total organic materials.

A combination of hydrocarbons, alcohols, aldehydes,

esters, ethers or ketones having an olefinic or

cyclo-olefinic types of unsaturation: 5 percent. 

This

definition

does not apply to perchioroethylene or

trichloroethylene.

A combination of aromatic compounds with eight or more

carbon atoms to the molecule except ethylbenzene: 8

Percent.

91

A combination of ethylbenzene, ketones having branched

hydrocarbon structures or toluene: 20 percent.

(Source: Added at  

Ill. Peg. 

_____,

effective 

_______________

_________________________________

)

Section 211.4710  Pigmented Coatings

“Pigmented coatings” means oPaaue coatings containing binders and

colored pigments which are formulated to conceal the wood surface

either as an undercoat or topcoat.

(Source: Added at 

—

Ill. Reg.   

effective 

_______________

Section 211.4730  Plant

“Plant” means, for purposes other than 35 Ill. Adm. Code 215. 218

and 219, all of the pollutant—emitting activities which belon~ to

the same industrial grouping, are located on one or more

contiguous or adjacent properties. and are under the control of

the same person (or persons under common control), except the

activities of any marine vessel. Pollutant—emitting activities

shall be considered as part of the same industrial grouping if

they be1on~to the same major group (i.e., which have the same

two-digit code) as described in the “Standard Industrial

Classification Manual,” 1987 (incorporated bY reference in 35

Ill. Adm. Code 218.112 and 219.112).

(Source: Added at —  

Ill. Peg. 

_____,

effective

_______________

Section 211.4750  Plasticizers

“Plasticizers” means substances added to a polymer composition to

soften and add flexibility to the product.

(Source: Added at

—

Ill. Req. 

_____,

effective 

_______________

Section 211.4770  PM—b

“PM-b” means particulate matter with an aerodynamic diameter

less than or egual to a nominal 10 micrometers, as measured by

the applicable test methods specified bY rule. Ambient air

concentrations 

for PM-la

are usuallY expressed in micrograms Per

cubic meter (ug/m3).

‘(Source: Added at —  

Ill. Req. 

_____,

effective 

_______________

92

Section 211.4790  Pneumatic Rubber Tire Manufacture

“Pneumatic rubber tire manufacture” means the production of

pneumatic rubber tires with a bead diameter up to but not

including 20.0 inches and cross section dimension up to 12.8

inches, but not including specialty tires for antique or other

vehicles when produced on equipment separate from normal

production lines for passenger or truck type tires.

(Source: Added at 

—

Ill. Peg. 

_____,

effective 

_______________

Section 211.4810  Polybasic Organic Acid Partial Oxidation

Manufacturing Process

“Polybasic organic acid partial oxidation manufacturing process”

means any process involving partial oxidation of hydrocarbons

with air to manufacture polybasic acids or their anhydrides, such

as maleic anhydride, phthalic anhydride, terephthalic acid,

isophthalic acid. trimelletic anhydride.

(Source: Added at  

Ill. Peg. 

_____,

effective 

_______________

Section 211.4870  Polystyrene Plant

“Polystyrene plant” means any collection

of process units and

associated storage facilities at a source engaged in using

stvrene to manufacture polystyrene resin.

(Source: Added at

—

Ill. Req. 

_____,

effective 

______________

Section 211.4890

Polystyrene Resin

“Polystyrene resin” means a substance consisting of

styrene

polymer and additives which

is manufactured at a polystyrene

plant.

(Source: Added at —  Ill. Peg. 

_____,

effective 

______________

Section 211.4910  Portable Grain—Handling Equipment

“Portable grain-handling equipment” means any equipment

(excluding portable grain dryers) that is designed and maintained

to be movable primarily for use in a non-continuous operation for

loading and unloading one-turn storage space and is not

physically connected to the grain elevator, provided that the

manufacturer’s rated capacity of the equipment does not exceed

10,000 bushels per hour.

93

(Source: Added at  

Ill. Peg. 

_____,

effective 

_______________

Section 211.4930  Portland Cement Manufacturing Process

Emission Source

“Portland cement manufacturing process emission source” means anY

items of Process equipment or manufacturing processes used in or

associated with the Production of portland cement, including, but

not limited to. a kiln, clinker cooler, raw mill system, finish

mill system, raw material dryer, material storaae bin or systenu

material conveyor belt or other transfer system. material

conveyor belt transfer point, ba~gin~operation, bulk unloading

station. or bulk loading station.

(Source: Added at —  Ill. Peg. 

_____,

effective 

_______________

Section 211.4950  Portland Cement Process or Portland Cement

Manufacturing Plant

“Portland cement process” or “Portland cement manufacturing

plant” means anY facility or Plant manufacturing Portland cement

bY either the wet or dry process.

(Source: Added at —  Ill. Peg. 

_____,

effective 

_______________

_________________________________

)

Section 211.4990  Power Driven Fastener Coating

“Power driven fastener coating” means the coating of nail,

staple, brad and finish nail fasteners where such fasteners are

fabricated from wire or rod of

0.0254 inch diameter or greater,

where such fasteners are bonded

into coils or strips, such coils

and strips containing a number of

such fasteners, which fasteners

are manufactured for use in power tools, and which fasteners must

conform with formal standards for specific uses established by

various federal and national organizations including Federal

Specification FF-N-105b of the General Services Administration

dated Au~ust23. 1977 (does not include any later amendments or

editions; U.S. Army Armament Research and DeveloPment Command.

Attn: DRDAR-TST, Rock Island. IL 61201), Bulletin UN-25d of the

U.S. DePartment of Housing and Urban Development 

—

Federal

Housing Administration dated SePtember 5. 1973 (does not include

any later amendments or editions; Department of HUD. 547 W.

Jackson Blvd.. Room 1005, Chicago, IL 60606). and the Model

Building Code of the Council of American Building Officials, and

similar standards. For the purposes of this definition, the

terms “brad” and “finish nail” refer to single le~fasteners

fabricated in the same manner as staples. The application of

coatings to staple, brad, and finish nail fasteners may be

associated with the incremental forming of such fasteners in a

94

cyclic or repetitious manner (incremental fabrication) or with

the forming of strips of such fasteners as a unit from a band of

wires (unit fabrication).

(Source: Added at —  

Ill. Reg. 

_____,

effective 

________________

Section 211.5030  Pressure Release

“Pressure release” means the emission of materials resulting from

system pressure being greater than set pressure of the pressure

relief device.

(Source: Added at 

—

Ill. Reg. 

_____,

effective 

_______________

Section 211.5050  Pressure Tank

“Pressure tank” means a tank in which fluids are stored at a

pressure greater than atmospheric pressure.

(Source: Added at

—

Ill. Reg. 

_____,

effective 

________________

Section 211.5070  Prime Coat

“Prime coat” means the first of two or more coatings applied to a

substrate in a multiple coat operation.

(Source: Added at 

—

Ill. 

Req.

_____,

effective 

_______________

Section 211.5090  Primer Surfacer Coat

“Primer surfacer coat” means a coating used to touch up areas on

the_surface_of automobile or light-duty truck bodies not

adequately covered 

by the prime

coat before application of the

to~coat. The primer surfacer coat is applied between the prime

coat and topcoat. An anti-chip coating applied to main body

parts (e.g., rocker panels, bottom of doors and fenders, and

leading edge of roof) is a primer surfacer coat. The primer

surfacer coat is also referred to as a “guide coat.”

(Source: Added at —  

Ill. Peg. 

_____,

effective 

________________

Section 211.5110  Primer Surfacer Operation

“Primer surfacer operation” means the application area(s).

flashoff area(s) and oven(s) that are used to apply and dry or

cure primer surfacer coat on a single assembly line.

95

(Source: Added at —  

Ill. Reg. 

_____,

effective. 

______________

Section 211.5130  Primers

“Primers” means any coatings formulated and applied to substrates

to provide p firm bond between the substrate and subseauent

coats.

(Source: Added at —  

Ill. Reg. 

_____,

effective 

_______________

Section 211.5150  Printing

“Printing” means the application of words, designs, pictures, or

other images to a substrate using ink.

(Source: Added at 

—

Ill. Peg. 

_____,

effective 

_______________

Section 211.5170  Printing Line

“Printing line” means an operation consisting of a series of one

or more roll printers and any associated roll coaters, drying

areas, and ovens wherein one or more coatings are applied. dried,

and/or cured.

(Source: Added at 

—

Ill. Reg. 

_____ ,

effective

_______________

Section 211.5185  Process Emission Source

“Process emission source” means any stationary emission source

other than a fuel combustion emission unit or an incinerator.

(Source: Added at —  

Ill. Req. 

_____,

effective 

_______________

Section 211.5190  Process Emission Unit

“Process emission unit” means any stationary emission unit other

than a fuel combustion emission unit or an incinerator.

(Source:

Added at

—

Ill. 

Peg.

_____,

effective 

_______________

Section 211.5210  Process Unit

“Process unit” means equipment and components assembled to

produce, as intermediate or final products, one or more

chemicals. A process unit can operate independently if supplied

with sufficient feed or raw materials and sufficient storage

96

facilities for the product.

For purposes of Subpart 0 of Parts

215. 218 and 

219,

a process unit must produce one or more of the

chemicals listed in ~    

A of 35 Ill. Adrn. Code 215. 218 or

219. as aotlicable

(Source: Added at —  Ill.

211.5230  Process

Peg.

Unit

effective

Section             

Shutdown

“Process unit ~hiitei~iw~”means a work practice or operational

procedure that stops production from a process unit or part

procedureprocessunitthatAnstoosunscheduledproductionworkfrompracticeaprocessorunitoper~’~orpart1

process unit for less than 24 hours is not a process unit

shutdown. The use of spare equipment and

components and

technically feasible bypassing of equipment and components

without stopping production is not a process unit shutdown.

of a

of a

(Source: Added at 

—

Ill. Peg. 

_____,

effective 

_______________

Section 211.5250  Process Weight Rate

“Process weight rate” means the actual weight or engineering

approximation thereof of all materials except liquid and gaseous

fuels and combustion air introduced into any process per hour.

For a cyclical or batch operation, the process weight rate shall

be determined by dividing such actual weight or engineering

approximation thereof

by

the number

of hours of operation

excluding any time during which the equipment is idle. For

continuous processes, the process weight rate shall be determined

by dividing such actual weight or engineering approximation

thereof by the number of hours in one complete operation,

excluding any time during which the equipment is idle.

(Source: Added at —  

Ill. Peg. 

_____,

effective 

_______________

Section 211.5270  Production Equipment Exhaust System

“Production equipment exhaust system” means a system for

collecting and directing into the atmosphere emissions of

volatile organic material from reactors, centrifuges, and other

process emission units.

(Source: Added at 

—

Ill. Peg.

_____,

effective

97

Section 211.5310  Publication Potoaravure Printing Line

“Publication rotogravure printing line” means a rotoaravure

printing line printing upon paper which is subsequently formed

into books..~ magazines, catalogues, brochures. directories.

newspaper su~~lementsor other tyPes of non—packaging printed

materials 

(Source: Added at  

Ill. Peg. 

_____,

effective 

_______________

Section 211.5330  Purged Process Fluid

“Purged process fluid” means liquid or vapor from a process unit

that contains volatile organic material and that results from

flushing or cleaning the sample line(s) of a process unit so that

an uncontaminated sample may then be taken for testing or

analysis.

(Source: Added at  

Ill. 

Peg.

_____,

effective 

_______________

Section 211.5350  Reactor

“Reactor” means a vat, vessel, or other device in which chemical

reactions take place.

(Source: Added at —  

Ill. Req. 

_____,

effective 

_______________

Section 211.5370  Reasonably Available Control Technology

(PACT)

“Reasonably available control technology (RACT)” means the lowest

emission limitation that an emission unit is capable of meeting

by the application of control technology that is reasonably

available considering technological and economic feasibility.

(Source: Added at —  

Ill. Req. 

_____ ,

effective 

_______________

Section 211.5410

Refiner

“Refiner” means any person who owns, leases, operates, controls,

or supervises a refinery.

(Source: Added at —  

Ill. Peg. 

_____,

effective 

______________

98

Section 211.5430  

Refinery Fuel Gas

“Refinery fuel gas” means any gas which is generated by a

petroleum refinery Process unit and which is combusted at the

refinery, including any gaseous mixture of natural gas and fuel

gas.

(Source: Added at

Section 211.5450

—  Ill. Reg. 

_____,

effective

Refinery Fuel Gas System

“Refinery fuel gas system” means a system for collection of

refinery fuel gas including, but not limited to. piping for

collecting tail gas from various orocess units  

‘~‘

drums arid

c~ôntrr1s. and 

distr~i,~~44ônnininri

—

-—

—

,t,.ana_..,

‘“‘~‘-----

(Source:

Added at

—

Ill. Peg.

Section 211.5470  Refinery Unit or Re

effective

finery Process Unit

“Refinery unit” or “Refinery process unit” means a set of

ii~rim~ntwhich are a part of a basic process operation such as

distillation. hydrotreating. cracking, or reforming of

hydrocarbons.

(Source: Added at

Section 211.5490

Ill. Reg. 

_____,

effective

Refrigerated Condenser

“Refrigerated condenser” means a surface condenser in which the

coolant supplied to the condenser has been cooled by a mechanical

device, other than by a cooling tower or evaporative spray

cooling, such as refrigeration unit or steam chiller unit.

(Source: 

Added at

Ill. Peg. 

_____,

effective

Section 211.5510

Reid Vapor Pressure

“Reid vapor Pressure” means the absolute vapor pressure of

volatile crude oil

and volatile nonviscous petroleum liquids

except liguified petroleum gases as determined by the method

referenced in the Section where the term is used or by ASTN

0323—89 (if not referenced in the Section where the term is

used), incorporated by reference in 35 Ill. Adm. Code 218.112 and

219.112.

(Source: Added at  

Ill. Reg. 

_____,

effective

99

Section 211.5550  Repair Coat

“Repair coat” means, with respect to coating wood furniture,

coatings used to correct imperfections or damage to furniture

surface.

(Source: Added at 

—

Ill. Reg. 

_____,

effective 

_______________

_________________________________

)

Section 211.5570  ~paired

“Repaired” means. for the purpose of Subpart 0 of 35 Ill. Adm.

Code 21-5. 218 and 219. that equipment or a component has been

adiusted, or otherwise altered, to eliminate a leak.

(Source: Added at —  

Ill. Req. 

_____,

effective 

_______________

Section 211.5590  Residual Fuel Oil

“Residual fuel oil” means fuel oils of arade No. 4, 5 and 6 as

specified in detailed requirements for fuel oils ASTM D—396—69

(1971) incorporated by reference in 35 Ill. Adm. Code 218.112 and

219.112.

(Source: Added at —  

Ill. Peg. 

_____,

effective 

________________

Section 211.5610  Restricted Area

“Restricted area” means the area within the boundaries of any

“-municipality” as defined in the Illinois 

Municipal Code, plus a

zone extending one mile beyond the boundaries of any such

municipality having a population of 1000 or 

more according to the

latest federal census.

(Source:

Added at

Ill. Reg.

_____,

effective 

________________

Section 211.5630

Retail Outlet

“Retail outlet” means

any gasoline dispensing operation at which

aasoline is sold or offered for sale for use in motor vehicles.

(Source: Added at —  

Ill. Peg. 

_____,

effective 

_______________

Section 211.5650  Ringelmann Chart

“Pingelmann chart” means the chart published and described in the

Bureau of Mines, U.S. Department of Interior, Information

100

Circular 8333 (Revision of 1C7718) May 1, 1967, or any adaptation

thereof which has been approved by the Agency.

(Source: Added at  

Ill. Peg. 

_____,

effective 

_______________

Section 211.5670  Roadway

“Roadway” means any street, highway. road, alley, sidewalk,

parking lot, airport, rail bed or terminal, bikeway, pedestrian

mall or other structure used for transportation purposes.

(Source: Added at 

—

Ill. Peg. 

_____,

effective 

_______________

_________________________________

)

Section 211.5690  Roll Coater

“Roll coater” means an apparatus used for roll coating.

(Source: Added at 

—

Ill. Peg. 

_____,

effective 

_______________

_________________________________ 

)

Section 211.5710  Roll Coating

“Roll coating” means a method of applying a coating to a moving

substrate by means of rotating hard rubber, elastomeric or metal

rolls.

(Source:

Added at

—

Ill. Peg. 

_____,

effective 

_______________

Section 211.5730  Roll Printer

“Roll printer” means an apparatus used for roll printing.

(Source: Added at —  

Ill. Peg. 

_____,

effective 

_______________

Section 211.5750  Roll Printing

“Roll printing” means the method of printing by means of a series

of rolls, usually of hard rubber or metal, each with only partial

coverage.

(Source: Added at 

—

Ill. Peg. 

_____,

effective 

_______________

Section 211.5770  Rotogravure Printing

“Rotogravure printing” means roll printing in which the pattern

to be applied is recessed in the roll relative to the non-image

area.

101

(Source:

Added at

—

Ill. Peg. 

_____,

effective 

________________

Section 211.5790  Roto~ravurePrinting Line

“Rotogravure printing line” means a printing line performing

rotogravure printing.

(Source: Added at 

—

Ill. Peg. 

_____,

effective 

_______________

Section 211.5810  Safety Relief Valve

“Safety relief valve” means a valve which is normally closed and

which is designed to open in order to relieve excessive pressures

within a vessel or pipe.

(Source: Added at  

Ill. Req. 

_____,

effective 

_______________

Section 211.5830  Sandblasting

“SandblastincT” means the use of a mixture of sand and air at high

pressures for cleaning and/or polishing any tv~e of surface.

(Source:

Added at

—

Ill. Reg.

_____,

effective

_______________

Section 211.5850  Sanding Sealers

“Sanding sealers” means any coatings formulated for and a~p1ied

to bare wood for sanding and to seal the wood for subsequent

application of varnish. To be considered a sanding sealer a

coating must be clearly labelled as such.

(Source: Added at  

Ill. Req. 

_____,

effective 

_______________

Section 211.5870  Screening

“Screening” means separating material according to size bY

pressing undersized material through one or more mesh surfaces

(screens) in series, and retaining oversized material on the mesh

surfaces (screens).

(Source: Added at

—

Ill. Req. 

_____,

effective 

_______________

Section 211.5890  Sealer

“Sealer” means a coating containing binders which seals wood

prior to the application of the subsequent coatings.

102

(Source: Added at —  

Ill. Peg. 

_____,

effective 

_______________

Section 211.5910  Semi-Transparent Stains

“Semi—transparent stains” means stains containing dyes or semi-

transparent pigments which are formulated to enhance wood grain

and change the color of the surface but not to conceal the

surface, including, but not limited to, sap stain, toner,

non-grain raising stains, pad stain, or spatter stain.

(Source: Added at  

Ill. Peg.

_____,

effective 

_______________

Section 211.5930  Sensor

“Sensor” means a device that measures a physical quantity or the

change in a physical quantity such as temperature, pressure, flow

rate. pH. or liquid level.

(Source: Added at —  

Ill. Req. 

_____,

effective 

_______________

Section 211.5950  Set of Safety Relief Valves

“Set of safety relief valves” means one or more safety relief

valves designed to open in order to relieve excessive pressures

in the same vessel or pipe.

(Source: Added at —  

Ill. Req. 

_____,

effective 

_______________

Section 211.5970  Sheet Basecoat

“Sheet basecoat” means a coating applied to metal when the metal

is in sheet form to serve as either the exterior or interior of a

can for either two-piece or three-piece cans.

(Source: Added at 

—

Ill. Peg.

_____,

effective 

_______________

_________________________________ 

)

Section 211.5990  Shotblasting

“Shotblasting” means the use of a mixture of any metallic or

non-metallic substance and air at high pressures for cleaning

and/or polishing any type of surface.

(Source: Added at 

—

Ill. Peg. 

_____,

effective 

_______________

103

Section 211.6010  Side—Seam Spray Coat

“Side—seam spray coat” means a can coating applied to the seam of

a three—piece can.

(Source: Added at —  

Ill. Reg. 

_____,

effective 

_______________

Section 211.6030  Smoke

“Smoke” means small gas-borne particles resulting from incomplete

combustion. consisting predominatelv but not exclusively of

carbon, ash and other combustible material, that form a visible

plume in the air.

(Source: Added at —  

Ill. Req.

_____,

effective 

_______________

Section 211.6050  Smokeless Flare

“Smokeless flare” means a combustion unit and the stack to which

it is affixed in which organic material achieves combustion by

burning in the atmosphere such that the smoke or other

particulate matter emitted to the atmosphere from such combustion

does not have an appearance density or shade darker that No. 1 of

the Ringlemann Chart.

(Source:

Added at

—

Ill. Reg. 

_____,

effective

________________

Section 211.6070  Solvent

“Solvent” means a liquid substance that is used to dissolve or

dilute another

substance. This term includes, but is not limited

to organic materials used as dissolvers, viscosity reducers,

degreasing agents, or cleaning agents.

(Source: Added at  

Ill. Req. 

_____,

effective 

_______________

Section 211.6090  Solvent Cleaning

“Solvent cleaning” means the process of cleaning soils from

surfaces by cold cleaning, open to~vapor degreasing.or

conveyorized 

degreasing.

(Source: Added at —  

Ill. Peg. 

_____,

effective 

_______________

)

104

Section 211.6130  Source

“Source” means any stationary source (or any group of stationary

sources that are located on one or more contiguous or adiacent

properties, and are under common control of the same person or

persons under common control) belonging to a single malor

industrial arouping. For the purposes of defining “source,” a

stationary source or group of stationary sources shall be

considered part of a sinale industrial grouping if all of the

pollutant emitting activities at such source or group of sources

on contiguous or adlacent Pro~ertvbelong to the same Major GrouP

(i.e., all have the same two-digit code) as described in the

Standard Industrial Classification Manual. 3.987 (incorporated by

reference in 35 Ill. Adin. Code 218.112 and 219.112)

(Source: Added at —  

Ill. Req. 

_____,

effective 

_______________

Section 211.6150  Specialty High Gloss Catalyzed Coating

“Specialty high gloss catalyzed coating” means commercial

contract finishing of material prepared for printers and

lithographers where the finishing process uses a solvent—borne

coating. formulated with a catalyst, in a quantity of no more

than

12.000 gallons/year as supplied, where the coating machines

are sheet fed and the coated sheets are brought to a minimum

surface temperature of 190°F, and where the coated sheets are to

achieve the minimum specular reflectance index of 65 measured at

a 60 degree angle with a gloss meter.

(Source: Added at —  

Ill. Reg. 

_____,

effective 

______________

Section 211.6190 Specialty Soybean Crushing Source

“Specialty soybean crushing source” means any hexane extraction

soybean crushing equipment using indirect steam heat in flash or

vapor desolventizers as the Primary method of desolventizing and

~

soecialtv solvent extracted soy 

ants or flour

(Source: Added at 

—

Ill. Req.    

effective

Section 211.6210  Splash Loading

“Splash loading” means a method of loading a tank, railroad tank

car, tank truck, or trailer by use of other than a submerged

loading pipe.

(Source: Added at

Ill. Req.

_____,

effective

105

Section 211.6230

Stack

“Stack” means a flue or conduit. free—standing or with exhaust

port above the roof

of the building on which it is mounted, by

which_air contaminants are emitted into the atmosphere.

(Source: Added at —  

Ill. Reg. 

_____,

effective 

_______________

Section 211.6270  Standard Conditions

“Standard.conditions” means a temperature 

of 70°F and a pressure

of 14.7 psia.

(Source: Added at —  

Ill. Peg.

_____,

effective 

________________

Section 211.6290  Standard Cubic Foot (scf)

“Standard cubic foot (scf)” means the volume of one cubic foot of

gas at standard -conditions.

(Source: Added at 

—

Ill. Peg. 

_____,

effective 

_______________

Section 211.6310  Start—Up

“Start—up” means the setting in operation of an emission unit for

any purpose.

(Source: Added at 

—

Ill. Req. 

_____,

effective 

________________

Section 211.6330  Stationary Emission Source

“Stationary emission source” means an emission source which is

not self-propelled.

(Source: Added at —  

Ill. Peg.

_____,

effective 

_______________

Section 211.6350  Stationary Emission Unit

“Stationary emission unit” means an emission unit which is not

self—propelled.

(Source: Added at —  

Ill. Peg.

_____,

effective 

________________

106

Section 211.6370  Stationary Source

“Stationary source” means any building, structure, faci1itv,~r

installation that emits or may emit any air pollutant.

(Source: Added at 

—

Ill. Peg. 

_____,

effective 

______________

Section 211.6390  Stationary Storaae Tank

“Stationary storage tank” means any container of liquid or gas

which is designed and constructed to remain at one site.

(Source: Added at 

—

Ill. Peg. 

_____,

effective 

_______________

Section 211.6410  Storage Tank or Storage Vessel

“Storage tank or storage vessel” means any tank, reservoir or

container used for the storage of liquid or gaseous material.

(Source: Added at  

Ill. Peg. 

_____,

effective 

______________

Section 211.6430  Styrene Devolatilizer Unit

“Styrene devolatilizer unit” means equipment performing the

function of separating unreacted styrene monomer and other

volatile components from polystyrene

in a vacuum devolatilizer.

(Source: Added at —  

Ill. Peg.

_____,

effective 

_______________

Section 211.6450  Styrene Recovery Unit

“Styrene recovery unit” means equipment performing the function

of separating stvrene monomer from other less volatile components

of the styrene devolatilizer unit’s output. The separated

styrene monomer may be reused as a raw material in the

polystyrene plant.

(Source: Added at  

Ill. Peg. 

_____,

effective 

______________

Section 211.6470  Submerged Loading Pipe

~j “Submerged loading pipe” means, for purposes of 35 Iii.

Adm. Code 215, any loading pipe the discharge opening

of which is entirely submerged when the liguid level is

6 inches above the bottom of the tank. When applied to

a tank which is loaded from the side, any loading pipe

the discharge of which is entirely submerged when the

107

liquid level is 18 inches or two times the loading pipe

diameter, whichever is greater, above the bottom of the

tank. The definition shall also aP~lvto any loading

pipe which is continuously submerged during loadina

operations.

~j “Submerged loading pine” means, for Purposes of 35 Ill.

Adm, Code 218 and 219, anY discharge Pipe or nozzle

which meets either of the following conditions:

Where the tank is filled from the top, the end of

the discharge piPe or nozzle must be totally

submer~edwhen the liauid level is 15 cm (6 in.)

above the bottom of the tank.

Where the tank is filled from the side, the

discharge pipe or nozzle must be totally submerged

when the liquid level is 46 cm (18 in.) above the

bottom of the tank.

(Source: Added at —  

Ill. Peg. 

_____,

effective

_______________

Section 211.6490  Substrate

“Substrate” means the surface onto which a coating is applied or

into which a coating is impregnated.

(Source: Added at 

—

Ill. Peg. 

_____,

effective 

_______________

Section 211.6510  Sulfuric Acid Mist

“Sulfuric acid mist” means sulfuric acid mist as measured

according to the

method specified in 

35 Ill. Adm. Code

214.101(b)

(Source:

Added at

—

Ill. 

Req.

_____,

effective 

_______________

Section 211.6530  Surface Condenser

“Surface condenser” means a device which removes a substance from

a gas stream by reducing the temperature of the stream, without

direct contact between the coolant and the stream.

(Source: Added at  

Ill. Req. 

_____,

effective 

_______________

108

Section 211.6550  Synthetic Organic Chemical or Polymer

Manufacturing Plant

“Synthetic organic chemical or polymer manufacturing plant” mear~

a source that produces, as intermediates or final products,

chemicals or polymers.

(Source: Added at 

—

Ill. Peg. 

_____,

effective 

______________

Section 211.6570  Tablet Coating Operation

“Tablet coating operation” means a pharmaceutical coating

operation in which tablets are coated.

(Source: Added at 

—

Ill. Peg. 

_____,

effective 

_______________

Section 211.6590  Thirty Day Rolling Average

“Thirty day

rolling average” means any value arithmetically

averaged over any consecutive thirty days.

(Source: Added at

—

Ill. Peg. 

_____,

effective 

______________

Section 211.6610  Three-Piece Can

“Three—piece can” means a can which is made from a rectangular

sheet and two circular ends.

(Source: Added at 

—

Ill. Peg. 

_____,

effective 

______________

Section 211.6670  Topcoat

“Topcoat” means a coating applied to a substrate in a multiple

coat operation other than prime coat, primer surfacer coat or

final repair coat.

(Source: Added at —  

Ill. Reg. 

_____,

effective 

______________

Section 211.6690  Topcoat Operation

“Topcoat operation” means the application area(s), flash—off

area(s). and oven(s) used to apply and dry or cure the topcoat

(except final off-line repair) on automobile or light-duty truck

bodies or body parts on a single assembly line.

(Source: Added at —  

Ill. Req. 

_____,

effective 

_______________

109

Section 211.6730  

Transfer Efficiency

“Transfer efficiency” means the ratio of the amount of coating

solids deposited onto a part or product to the total amount of

coating solids used, during a particular time period.

(Source: Added at 

—

Ill. Peg.   

effective

Section 211.6750  

Tread End Cementing

“Tread end cementing” means the application of a solvent—based

cement to the tire tread ends.

(Source: Added at

Section 211.6770

Ill. Reg.

_____,

effective

True VaPor Pressure

“True vapor pressure” means the equilibrium partial pressure

exerted by a volatile organic liquid as determined in accordance

with methods described in American Petroleum Institute Bulletin

2517. “Evaporation Loss From Floating Poof Tanks,” second

edition. February 1980 (incoroOr~-’~by ref~r~nr~in 35 III

(~i-~,ri~21~112 ~nd 21q112

—

Adm.

(Source: Added at

Tur

Ill.

naro

Peg.

und

effective

Section 211.6790

“Turnaround” means, with respect to a refinery process unit, the

procedure of shutting down an

operating refinery unit, emptying

gaseous and liquid contents to do inspection, maintenance and

repair work, and putting the unit back into production.

(Source: Added at —  

Ill. Reg.

_____,

effective 

_____________

Section 211.6810  

Two-Piece Can

“Two—piece can” means a can that consists of a body manufactured

i.e., drawn, from a single piece of metal and one toP or end.

(Source: Added at  

Ill. Peg.

effective

Section 211.6850

Undertread Cementing

“Undertread cementing” means the application of a solvent—based

cement to the underside of a tire

tread.

110

(Source: Added at —  

Ill. Peg.

_____,

effective 

_____________

Section 211.6870  Unregulated Safety Relief Valve

“Unregulated safety relief valve” means a safety relief valve

which cannot be actuated by a means other than high pressure in

the pipe or vessel which it protects.

(Source: Added at 

—

Ill. Peg. 

_____,

effective 

_______________

Section 211.6890  Vacuum Producing System

“Vacuum producing system” means any reciprocating, rotary. or

centrifugal blower or compressor or any let elector or device

that creates suction from a pressure below atmospheric and

discharges against a greater pressure.

(Source: Added at —  

Ill. Peg. 

_____,

effective 

______________

Section 211.6910  Vacuum Service

“Vacuum service” means, for the purpose of Subpart p of this 35

Ill. Adm. Code 215, 218 and 219, equipment or a component which

is operating at an internal pressure that is at least 

5 kPa (0.73

psia) below ambient pressure.

(Source: Added at —  

Ill. Peg. 

_____,

effective 

_______________

Section 211.6930  Valves Not Externally Regulated

“Valves not

externally regulated” means valves that have no

provision for external adlustment or governance during their

operation, such as in—line check valves.

(Source: Added at 

—

Ill. Peg. 

_____,

effective 

_______________

Section 211.6950  Vapor Balance System

“Vapor balance system” means any combination of pipes or hoses

which creates a closed system between the vapor spaces of an

unloading tank and a receiving tank such that vapors displaced

from the receiving tank are transferred to the tank being

unloaded.

(Source: Added at —  

Ill. Peg. 

_____,

effective 

_______________

111

Section 211.6970  VaPor Collection System

“Vapor collection system” means all piping, seals, hoses,

connections, pressure—vacuum vents, and other comPonents between

the gasoline delivery vessel and the vaPor processing unit and/or

the storage tanks and vapor holder.

(Source: Added at  

Ill. Reg. 

_____,

effective 

_______________

Section 211.6990  VaPor Control System

“Vapor control system” means any sYstem that limits or prevents

release to the atmosphere of organic material in the vapors

displaced from a tank during the transfer of gasoline or other

volatile organic liquid.

(Source: Added at   

Ill. Reg. 

_____,

effective 

_______________

Section 211.7010  Vapor-Mounted Primary Seal

“Vapor-mounted primary seal” means a primary seal mounted with an

air space bounded 

by the bottom of the primary seal. the tank

wall, the liquid surface and the floating roof.

(Source: Added at —  

Ill. Peg. 

_____,

effective 

_______________

Section 211.7030  VaPor Recovery SYstem

“Vapor recovery system” means, with respect to a storage tank,

storing a volatile organic liquid, a vapor gathering system

capable of collecting all volatile organic material (VOM) vapors

and gases discharged from the storage tank and a vapor disposal

sYstem capable of processing such VOM vapors and gases so as to

prevent their emission to the atmosphere.

(Source: Added at —  

Ill. Peg. 

_____,

effective 

_______________

Section 211.7070  Vinyl Coating

“Vinyl coating” means any protective, decorative or functional

coating or ink applied to vinyl or urethane or vinyl or urethane

coated fabric which is delivered to a coating line or printing

Line as a roll, unwound and coated as a continuous substrate.

However, a plastisol is not

a vinyl coating.

(Source:

Added at

Ill.

Req.

_____,

effective

_______________

112

Section 211.7090  Vinyl Coating Line

“Vinyl coating line” means a coating line in which any

protective, decorative or functional coating or ink is applied

onto vinyl or urethane or vinyl or urethane coated fabric which

is delivered to a coating line or printin~line as a roll,

unwound and coated as a continuous substrate. However,

application of a plastisol to vinyl or urethane or vinyl or

urethane coated fabric is not a vinyl  

~ri line or tart of

vinyl r~r~tina1in~

~,,~

a

——--—

(Source:

Added at

)

Section 211.7110

“Volatile organic

—

Ill. Req.

effective

Volatile Organic Liquid (VOL)

liquid (VOL)” means any substance which is

liquid at storage conditions and which contains volatile organic

material.

(Source: Added at 

—

Ill. Peg. 

_____,

effective 

_______________

Section 211.7130  Volatile Organic Material Content (VOMC)

“Volatile organic material content (VOMC)” means, for the purpose

of 35 Ill. Adm. Code

215, the emissions of volatile organic

material which would result from the exposure of a coating,

printing 

ink,

fountain solution, tire spray, dry cleaning waste

or other similar material to the air, including any drying or

curing, in the absence of any control equipment. VOMC is

typically expressed as kilogram (kg) VOM/liter (lb VON/gallon) of

coating or coating solids, or kg VON/kg (lb VOM/lb) of coating

solids, coating or material.

(Source: Added at —  

Ill. Req. 

_____,

effective 

_______________

_________________________________

)

Section 211.7150  Volatile Organic Material (VON) or Volatile

Organic Compound (VOCI

“Volatile organic material (VON)” or “Volatile organic compound

(VOC)” means any compound of carbon, excluding carbon monoxide,

carbon dioxide, carbonic acid, metallic carbides or carbonates,

and aminonium carbonate, which participates in atmospheric

photochemical reactions.

~j.. This includes any such organic compound other than the

following, which have been determined to have

negligible photochemical reactivity: Methane; ethane;

methylene chloride (dichlormethane),

1,1,1-trichlorethane (methyl chloroform)

113

1,1,l-trichloro—2,2,2-trifluoroethane (CFC—113);

trichiorofluoroinethane (CFC-ll);

dichlorodifluoromethane (CFC-121; chiorodifluoromethane

(CFC-22); trifluoroinethane (FC—23); 1,2—dichloro

1,1,2,2-tetrafluoroethane (CFC-114);

cloro~entafluoroethane (CFC—115); 1.1. 1—trifluoro

2, 2-dichloroethane (HCFC-123); 1.3., 12—tetrafluoroethane

LHFC-134a); 1, 1-dichloro 1—f luoroethane (HCFC—141b);

1—chloro 1,1-difluoroethane (HCFC—142b);

2—chloro-1, 1,1 ,2-tetrafluoroethane (HCFC-124)

~entafluoroethane (HFC-125); 1,1.2 ,2-tetrafluoroethane

(HFC-134); 1. 1,1—trifluoroethane (HFC—143a);

1. 1-djfluroethane (HFC-152a); and ~erfluorocarbon

compounds which fall into these classes:

~j.. Cyclic, branched, or linear, completely

fluorinated alkanes:

Cyclic, 

branched, or linear, completely

fluorinated ethers with no unsaturations

Cyclic, branched, or linear, completely

fluorinated tertiary amines with no unsaturations

and

~j.. Sulfur containing perfluorocarbons with no

unsaturations and with sulfur bonds only to carbon

and fluorine.

For purposes of determining VON emissions and

compliance with emissions limits, VON w.ill be measured

by the test methods in the approved implementation Plan

or 40 CFR Part 60, Appendix A, incorporated by

reference at 35 Ill. Adm. Code 215.105,

218.112, and

219.112, as applicable or by source—specific test

methods which have been established pursuant to a

permit issued pursuant to a program a~~rovedor

promulgated under Title V of the Clean Air Act or under

40 CFR Part 51, Subpart I or Appendix 5, incorporated

by reference at 35 Ill. Adm. Code

218.112 and 219.112

or under 40 CFR Part 52.21. incorporated by reference

at_35_Ill. Mm. Code 218.112 and 219.112. as

applicable. Where such a method also measures

compounds with negligible photochemical reactivity,

these negligibly—reactive compounds may be excluded as

VON if the amount of such compounds is accurately

quantified, and such exclusions is approved by the

Agency.

~j. As a precondition to excluding these

negligibly-reactive

compounds as VON or at any time

thereafter, the Agency may require an owner or operator

114

to provide monitoring or testing methods and results

demonstrating, to the satisfaction of the Agency. the

amount of negligibly-reactive compounds in the source’~

emissions.

The USEPA shall not be bound by any State determination

as to appropriate methods for testing or monitoring

negligibly-reactive compounds if such determination is

not reflected in any of the test methods in subsection

(b~ above.

(Source: Added at 

—

Ill. Peg. 

_____,

effective 

_______________

Section 211.7170  Volatile Petroleum Liquid

“Volatile petroleum liquid” means any petroleum liquid with a

true vapor pressure that is greater than 1.5 psia (78 millimeters

of mercury) at standard conditions.

(Source: Added at —  

Ill. Peg.

_____,

effective 

_______________

Section 211.7190  Wash Coat

“Wash coat” means a coating containing binders which seals wood

surfaces, prevents undesired staining, and controls penetration.

(Source: Added at  

Ill. Peg. 

_____,

effective 

________________

Section 211.7210  Wastewater (Oil/Water) Separator

“Wastewater (oil/water) separator” means any device or piece of

equipment which utilizes the difference in density between oil

and water to remove oil and associated chemicals from water, or

any

device, such as a flocculation tank or a clarifier, which

removes petroleum derived compounds from waste water.

(Source: Added at 

—

Ill. Peg. 

_____,

effective 

_______________

Section 211.7230  Weak Nitric Acid Manufacturing Process

“Weak nitric acid manufacturing process” means any acid producing

facility manufacturing nitric acid with a concentration of less

than 70 percent by weight.

(Source: Added at —  

Ill. Reg.

_____,

effective 

________________

115

Section 211.7250  Web

“Web” means a substrate which is coated or Printed as a

continuous substrate after being unrolled from the roll in which

the substrate

is delivered to a line.

(Source: Added at —  

Ill. Reg. 

_____,

effective 

______________

Section 211.7270  Wholesale Purchase 

—

Consumer

“Wholesale purchase 

—

consumer” means any person or organization

that purchases or obtains gasoline from a supplier for ultimate

consumption or use in motor vehicles and receives delivery of

gasoline into a storage tank with a capacity of at least 2082

liters (550 gallons) owned and controlled by that person.

(Source: Added at —  Ill. Reg.   

effective 

______________

Section 211.7290  Wood Furniture

“Wood furniture” means room furnishings including cabinets

(kitchen. bath, and vanity), tables. chairs, beds, sofas,

shutters, art oblects, wood paneling, wood flooring, and any

other coated furnishings made of wood, wood composition, or

fabricated wood materials.

(Source: Added at 

—

Ill. Req. 

_____,

effective 

______________

Section 211.7310  Wood Furniture Coating

“Wood furniture coating” means any protective, decorative or

functional coating applied to wood furniture or wood furniture

parts.

(Source: Added at

—

Ill. Reg. 

_____,

effective 

______________

Section 211.7330  Wood Furniture Coating Line

“Wood furniture coating line” means a coating line in which any

protective, decorative, or functional coating is a~~liedto wood

furniture or wood furniture parts.

(Source: Amended at  

Ill. Peg. 

______,

effective 

___________

116

Section 211.7350  Woodworking

“Woodworking” means the shaping. sawing, ~rinding, smoothing.

polishing and making into products of any form or shape of wood.

(Source: Added at 

—

Ill. Reg. 

_____,

effective 

_____________

117

TITLE 35: ENVIRONMENTAL PROTECTION

SUBTITLE B: AIR POLLUTION

CHAPTER I: POLLUTION CONTROL BOARD

SUBCHAPTER C: EMISSIONS STANDARDS AND LIMITATIONS

FOR STATIONARY SOURCES

PART 218

ORGANIC MATERIAL EMISSION STANDARDS AND LIMITATIONS FOR THE

CHICAGO AREA

SUBPART A: GENERAL

PROVISIONS

Introduction

Abbreviations and Conversion Factors

Applicability

Definitions

Test Methods and Procedures

Compliance Dates

Operation of Afterburners

Exemptions, Variations, and Alternative Means of Control

or Compliance Determinations

Vapor Pressure of Volatile Organic Liquids

Vapor Pressure of Organic Material or Solvent

Vapor Pressure of Volatile Organic Material

Incorporations by Reference

SUBPART B: ORGANIC EMISSIONS FROM STORAGE AND LOADING OPERATIONS

Section

218

121

218.122

218

123

218.124

218.125

218. 126

Storage Containers

Loading Operations

Petroleum Liquid Storage Tanks

External Floating Roofs

Compliance Dates (Repealed)

Compliance Plan (Repealed)

SUBPART C: ORGANIC EMISSIONS FROM MISCELLANEOUS EQUIPMENT

Section

218

141

218.142

218.143

218.144

Section

218.181

218. 182

218.183

Separation Operations

Pumps and Compressors

Vapor Blowdown

Safety Relief Valves

SUBPART E: SOLVENT CLEANING

Solvent Cleaning in General

Cold Cleaning

Open Top Vapor Degreasing

Section

218

•

100

218.101

218

102

218.103

218

104

218.105

218

•

106

218.107

218 .108

218.109

218. 110

218.111

218.112

incTs Clause

118

Emission Limitations for Manufacturing rianta

Daily-Weighted Average Limitations

Solids Basis Calculation

Alternative Emission Limitations

Exemptions from Emission Limitations

Exemption from General Rule on Use of Organic Material

Compliance Schedule

Recordkeeping and Reporting

SUBPART G:

USE OF ORGANIC MATERIAL

Section

218.301

218.302

218. 3 03

218. 304

Section

218.401

2 18.402

218.403

218. 404

218. 405

SUBPART

Section

218.421

218.422

218. 423

218.424

218.425

218.426

218. 427

218. 428

218

•

429

218

•

430

Use of Organic Material

Alternative Standard

Fuel Combustion Emission Courcea Units

Operations with Compliance Program

SUBPART H: PRINTING AND PUBLISHING

Flexographic and Rotogravure Printing

Applicability

Compliance Schedule

Recordkeeping and Reporting

Heatset-Web-Off set Lithographic Printing

LEAKS FROM SYNTHETIC ORGANIC CHEMICAL AND POLYMER

MANUFACTURING £QUIPMEN—T PLANT

General Requirements

Inspection Program Plan for Leaks

Inspection Program for Leaks

Repairing Leaks

Recordkeeping for Leaks

Report for Leaks

Alternative Program for Leaks

Open-Ended Valves

Standards for Control Devices

Compliance Date (Repealedi

Conveyorized Degreas ing

Compliance Schedule (Repealed)

Test Methods

SUBPART F: COATING OPERATIONS

218.184

218.185

218. 186

Section

218. 204

218.205

2 18.206

218.207

2 18.208

218.209

218.210

218.211

119

SUBPART P: PETROLEUM REFINING AND

RELATED INDUSTRIES;

ASPHALT MATERIALS

Petroleum Refinery Waste Gas Disposal

Vacuum Producing Systems

Wastewater (Oil/Water) Separator

Process Unit Turnarounds

Leaks: General Requirements

Monitoring Program Plan for Leaks

Monitoring Program for Leaks

Recordkeeping for Leaks

Reporting for Leaks

Alternative Program for Leaks

Sealing Device Requirements

Compliance Schedule for Leaks

Compliance Dates (Repealed)

SUBPART 5: RUBBER

AND MISCELLANEOUS PLASTIC PRODUCTS

Manufacture of Pneumatic Rubber Tires

Green Tire Spraying Operations

Alternative Emission Reduction Systems

Teoting and MonitoringEmission Testing

Compliance Dates (Repealed)

Compliance Plan (Repealed)

SUBPART T: PHARMACEUTICAL MANUFACTURING

Centrifuges and Vacuum Dryers

218.482 Control of Air Dryers, Production Equipment Exhaust

Systems and Filters

Material Storage and Transfer

In—Process Tanks

Leaks

Other Emission Courcca Units

Testing

Monitoring for Air Pollution Control Equipment

Recordkeeping for Air Pollution Control Equipment

SUBPART V: AIR OXIDATION PROCESSES

Definitions (Repealed)

Emission Limitations for Air Oxidation Processes

Testing and Monitoring

Compliance Date (Repealed)

Section

218. 441

218. 442

218.443

218.444

2 18.445

218.446

218. 447

218.448

218. 449

2 18.450

218. 451

218.452

218.453

Section

218

461

218.462

218

463

218.464

218. 465

218. 466

Section

218.480

218.481

Applicability

Control of Reactors, Distillation Units, Crystallizers,

218.483

218.484

218. 485

218. 486

218.487

218.488

218. 489

Section

218.521

218 .525

218.526

218.527

120

SUBPART W: AGRICULTURE

Section

218.541 Pesticide Exception

SUBPART X: CONSTRUCTION

Bulk Gasoline Plants

Bulk Gasoline Terminals

Gasoline Dispensing Facilities 

—

Storage Tank Filling

Operations

Gasoline Delivery Vessels

Gasoline Volatility Standards

Gasoline Dispensing Facilitic3 Operations 

Motor Vehicle

Fueling Operations

SUBPART Z:

DRY CLEANERS

Section

218. 601

218.602

218.603

218.604

2 18.605

218 .606

218.607

218.608

218.609

218. 610

218. 611

218.612

218.613

Perchioroethylene Dry Cleaners

Exemptions

Leaks

Compliance Dates (Repealed)

Compliance Plan (Repealed)

Exception to Compliance Plan (Repealed)

Standards for Petroleum Solvent Dry Cleaners

Operating Practices for Petroleum Solvent Dry

Program for Inspection and Repair of Leaks

Testing and Monitoring

Exemption for Petroleum Solvent Dry Cleaners

Compliance Dates (Repealed)

Compliance Plan (Re~ea1ed)

Cleaners

SUBPART AA:

PAINT AND INK MANUFACTURING

Section

218. 620

218.621

218. 623

218. 624

218.625

218. 626

218. 628

218

•

630

Applicability

Exemption for Waterbase Material and Heatset-Offset Ink

Permit Conditions

Open-4Top Mills, Tanks, Vats or Vessels

Grinding Mills

Storage Tanks

Leaks

Clean Up

Architectural Coatings

Paving Operations

Cutback Asphalt

SUBPART Y: GASOLINE DISTRIBUTION

Section

218. 561

218. 562

218. 563

Section

218.581

218.582

218.583

218

•

584

218

•

585

2 18.586

121

218.636

218.637

Compliance Schedule

Recordkeeping and Reporting

SUBPART BB: POLYSTYRENE PLANTS

Sect ion

218.875218.640

210.877218.642

218.086218.644   

Emissions Testing

218.875 Applicability of Subpart BB (Renumbered)

218.877 Emissions Limitation at Polystyrene Plants (Renumberedi

218.879 Compliance Date (Repealed)

218.881 Compliance Plan (Repealed)

218.883 Special Requirements for Compliance Plan (Repealed)

218.886 Emissions Testing (Renumbered)

SUBPART PP: MISCELLANEOUS FABRICATED PRODUCT MANUFACTURING

PROCESSES

Section

218. 920

218.923

218.926

218.927

218.928

Applicability

Permit Conditions

Control Requirements

Compliance Schedule

Testing

SUBPART 

QQ:

MISCELLANEOUS FORMULATION MANUFACTURING PROCESSES

Section

218.940

218.943

218.946

218.947

218. 948

Applicability

Permit Conditions

Control Requirements

Compliance Schedule

Testing

SUBPART PR: MISCELLANEOUS ORGANIC CHEMICAL MANUFACTURING

PROCESSES

Section

218.980

218. 983

218.986

218.987

Applicability

Permit Conditions

Control Requirements

Compliance Schedule

Applicability of Cubpart BB

Emissions Limitation at Polystyrene Plants

Section

218.960

218. 963

218.966

218.967

2 18.968

Applicability

Permit Conditions

Control Requirements

Compliance Schedule

Testing

SUBPART TT: OTHER EMISSION COURCEC UNITS

122

218.988 Testing

SUBPART UU: RECORDKEEPING AND REPORTING FOR NON-CTC

SOURCES

Section

218.990 Exempt Emission Courcca Units

218.991 Subject Emission Courcca Units

Section 2l8.Appendix A: List of Chemicals Defining Synthetic

Organic Chemical and Polymer

Manufacturing

Section 218.Appendix B: VOM Measurement Techniques for Capture

Efficiency

Section 218 .Appendix C: Reference Methods and Procedures

Section 218.Appendix D: Coefficients for the Total Resource

Effectiveness Index (TRE) Equation

AUTHORITY: Implementing Section 10 and authorized by Section

28.5 of the Environmental Protection Act (Ill. Rev. Stat. 1991,

ch. iii3~, par. 1010), (PA. 87—1213, effective September 26,

1992) (415 ILCS 5/10 and 28.5.

SOURCE: Adopted at R9l-7 at 15 Iii. Reg. 12231, effective August

16, 1991; amended in P91—23 at 16 Ill. Reg. 13564, effective

August 24, 1992; amended 

in R91-28 and R91—30 at 16 Ill. Reg.

13864, effective August 24, 1992; amended in R93—_ at 17 Ill.

Reg. 

—,

effective _______________________

SUBPART A: GENERAL 

PROVISIONS

Section 218.100

Introduction

a)  This Part contains standards and limitations for

emissions of organic material and volatile organic

material from stationary sources located in the Chicago

area, which is comprised of Cook, DuPage, Kane, Lake,

McHenry and Will Counties and Aux Sable Township and

Goose Lake Township in Grundv County and Oswego

Township in Kendall County.

b)  Sources subject to this Part may be subject to the

following:

1)  Permits required under 35 Ill. Adin. Code 2Olt ~

2)  Air quality standards under 35 Ill. Adin. Code

123

c)  This Part is divided into Subparts which are grouped as

follows:

1)  Subpart A: General Provisions~

2)  Subparts B-F: Emissions from equipment and

operations in common to more than one industry;

3)  Subpart G: Emissions from use of organic

material;

4)  Subparts H-end ~: Special rRules for various

industry groups.

~  Subpart TT: Rules for emission units not

otherwise addressed.

Subpart UU: Recordkeeping and reporting for

equipment00.

PR. andandTT.operations

addressed by Subparts PP1

(Source: Amended at —  Ill. Reg. 

______,

effective 

___________

_________________________ )

Section 218.101  

Cleanup and Dis~osa1flnt-rption5avings Clause

Emission of organic material released during clean—up operations

and disposal shall be included with other cini~ionsof orrmnhi~

material from the related emission source or air poi~ution

control cquipmcnt in determining total emissions.

~j Every owner or operator of an emission unit formerly

sub-lect to 35 Ill. Adm. Code Part 215 shall have

complied with its standards and limitations by the

dates and schedules applicable to the emission unit in

accordance with 35 Ill. Adm. Code 215 or upon initial

start-up. All compliance dates or schedules found in

35 Ill. Adm. Code 215 are not superseded by this Part

and remain in full

force and effect.

~j Nothing in this Part shall affect the responsibility of

any owner or operator that is now or has been subiect

to_the_FIP_to comply with its requirements thereunder

by the dates specified in the FIP.

(Source: Section repealed, new Section adopted at 

_____

Ill.

Peg. 

_______,

effective 

_______________________________)

Section 218.102  

Abbreviations and Conversion Factors

The following abbrov.LUL.Lons are used in this Partt

-square meters

-cubic mctcrs

-milligrams

j~ams, metric

millilitei.

ncaac

NDO

ppm

ppm’~

psi

ps4~

sof

ounu~

ounas

sauarc

‘-per 

per

inch

poundo per

square inch

-standard cubic feet

LIP

Ctatc Implementation Plan

TTE

temporary total enclosure

‘a’-’  

-tin

square centimeters

-square inches

-English ton

English ton

124

American Society for

barrels (42 gallons)

degrecs Celsius or a

cm

ccnt~~~

cu in   

cubic inches

m~h

-degrees ~

Fcdcral Impi

feet

c--A-

Fl?-

ion Plan

ft

2

ga~

kca 1

gallons per minute

grams per mole

gal 1nn~

hflh1r’~

inohcs

degrees Kclvi~..

kilocalorics

kilograms

ni-

kilograms per

hour

kilopasoals; one thousand newtons per square

meter

.L.

1/sec

lbs

lbs/hr

lbQ/gal

-pounds per hour

•1~

ITI I nil ~

4r~ n~ tonncs

n.i

mcgajoules

millimeters of mercury

natural draft opening

parts per million

r~i’rtri per mi 1 1 i rrn by 

‘ut~1iimr~

absolut....

sq in

.1..

UCEPA

ni_n

United Stat

A-

ion Agency

?,~1__

c~,~ 

Winy               

—

L.a.. 

—

English Metric

1 gal  

3.785 1

1 psia

2.205 lbs 1 kg

1 bbl  

159.0 1

1 cu in 16.39 ml

1 lb/gal

1l9~1~flfl

1 ton  

0.907 MrT

1 T

0.907 Mg

The abbreviations and conversion factors of 35 Ill. 

Adin.

Code 211

a~~lvto this Part.

(Source:

Amended at

—

Ill. Peg.

______,

effective 

___________

_________________________ )

Section 218.103  

Applicability

The provisions of this Part shall apply to all sources located in

the Chicago area, which is composed of Cook, DuPage, Kane, Lake,

McHenry e~and Will Counties, e~and AUX Sable Township e~’~

Goose Lake Township in Grundy County 

e~

~jj~ Oswego Township in

Kendall County.

a)  The provisions of this Part shall become effective

on July 1, 1991 with the following exceptions:

1) The

provisions of this Part shall become effective

on September 1, 1991 for each appellant, including

the constituents represented by appellants who are

associations, who has appealed the federal

implementation plan (FIP) for the Chicago area

(Illinois Environmental Regulatory Group v. USEPA,

No. 90-2778 (and consolidated cases) (7th CiT.)).

of any provision of this Part

125

organ..... oompouncts

VOL

volatile organic liquids

VOM

volatile organic 

materials

Environmental 

6.C~kPa (51.71 mm Hg)

2)

—

~~1

~iypiiu~wi~

~o

sources which

any

has

inaivi.uuai source

a~oea1edthe Fl?

category of

shall be stayed

to the ~     

-such individua...

tr~r,nr~’

nf ~nflri~r’-~

rrr!t-~ivr~r1

r~ ritnv

—

—J

nf th~

of the Fl? from UCEP.~

court. 

When

the court has taken final

i-riz4nr~

potion 

or

nffiri~i

when UCEPA

has published in the

the

Ft~ti,~i~i

provisions

-i~~

rn~r’~r

of

finril

the Fl?

intinn

specifically

t~n

applicable

to such individual source or category of aouroeo

or such 

stay is terminated, the 

Board shall take

corresponding action, if 

nooesoary, 

by the

adoption of a peremptory rule pursuant to 35 I~llu

Adju. 

Code

102.347 and Section 5.03 of the

Administrative Procedure Act (Ill. Rev.

Stat. 1989, oh. 127, oh. 1005.03).I~

effectiveness of any provision of this Part

applicable to any individual source or category of

sources which has appealed the FIP shall be stayed

to the extent that such individual source or

category of sources received a stay of the

effectiveness of the FIP, pending reconsideratiortA

from the USEPA or from the court in the FIP appeal

cited in subsection 218.103(p) (1) above. When

USEPA has published in the Federal Register final

action to revise or affirm the provisions of the

FIP specifically applicable to such individual

source or category of sources or such stay is

otherwise terminated, the Board shall take

corresponding action and the Agency shall submit

such action to USEPA for approval. Until such

time as USEPA approves the corresponding amendment

to this Part, the FIP rule shall remain the

applicable implementation plan for that source or

category of sources

under the Clean Air Act.

The provisions of this Part shall become effective

on November 15, 1992 for all sources located in

Aux Sable Township or Goose Lake Township in

Grundy County or in Oswego Township in Kendall

County.

b)  The provisions of the Part shall not apply to Viskase

Corporation; Allsteel, Incorporated; Stepan Company; or

Ford Motor Company to the extent such source has

obtained an adjusted standard from the Board or an

exclusion from the General Assembly for any Subpart of

this Part or of 35 Iii. Adm. Code 215.

(Board Note: Subsection 218.103(b) 

of this Section shall be

effective at the federal level only upon approval by 

USEPA.)

(Source: Amended at 

—

Ill. Reg.

______,

effective 

___________

126

Section 218.104

Definitions

~1_

—

~t_

127

A-

“Accolacota” means a pharmaceutical coating operation

whioh consists of a hori~onta1lyrotating perforated

drum in which tablets are placed, a coating is applied

by spraying, and the coating is dried by the flow of

air across the drum through the perforations.

“Accumulator” means the reservoir of a condensing unit

receiving the condensate from a surface condenser.

“Acid Gases” moans for the purposes of Section 

9.4

of

the Environmental Protection Act (the 

Act) (Ill. Rev.

F~tnt. 1’)R7 nh. 111 1/~

ririr..

1flfl’~i.~. h~~pgp~

chloride, hydrogen fluoride and hydrogen bromide, which

exist as gasos, liquid mist, or any combination

thereof.

“Actual emissions” moans the actual quantity of VON

omissions from an emission 

source during 

a particular

time period.

“Actual Heat Input” moans the quantity of heat produced

by the combustion of fuel using the gross heating value

of the fuel.

“Adhesive” moans any substance or mixture of substances

intended to serve as a joining compound.

tiAfterburnerit 

moans a control device in which materials

in gaseous effluent arc combustcd.

“Air contaminant” moans any solid, liquid, or gaseous

matter, any odor, or any 

form of energy, that is

capable of being released into the atmosphere from an

emission source.

“Air dried coatings” means any coatings that dry by use

of air or forced air at temperatures up to 363.15~jZ

(194°F)

“Air pollution” means the presence in the atmosphere of

one or more air contaminants in sufficient quantities

and of such characteristics and duration as to be

injurious to human, plant, or animal life, to health,

or to property, or to unreasonably interfere with the

enjoyment of life or property.

“Air pollution control oauiDmont” means any eciuipment

nrfacility

r’f 

.............~.naco. ‘-~i-evpni-,

—

...ntcndcd tc 

•

reauco or controi the emjssjuii ui. uj..,..,...jflCd 

air

contaminants to the atmos~hcro.

“Air suspension cocitor/dryor” means

~er&-4-~- which consists of

—,

a pharmaceutical

r,r’ 

vertical chambers

n which

—

——-—-I I

—~

__-~

u.~-

particluu 

.aL...

~.&.u.jup,anu a 

ooatifl~

ayp.i.i~u

~nu then dried while the tablets or

particles are kept in a fluidiccd 

state by the passage

of air upward through the chambers.

“Airless spray” means a spray coating method in whioh

the coating is atomisod by forcing it 

through a small

opening at high pressure. The coating liquid is not

mixed with air before exiting from the no~1c.

“Air assisted airless spray” moans a spray coating

method which combines oomprcsscd air with hydraulic

pressure to atomico the coating material into finer

droplets than is achieved with pure airless spray.

Lower hydraulic pressure is used than with airless

spray.

“Allowable omissions” means the quantity of VON

omissions during a particular time period from a

stationary source calculated using the maximum rated

capacity of the source (unless restricted by federally

enforceable limitations on operating rate, hours of

or k,~.., and the most

~‘~—~

nacnt 

~-:

the

applicable standards in 40 CFI1 

Parts 60 and 61~the

applicable implementation plan; or a federally

enforceable 

~~-~m~i- 

-“Ambient air quality standards” means those standards

designed to protect the public health and welfare

codified in 40 CFR Part 50 

and

promulgated from time -to

time by the UBEPA pursuant to authority contained in

Section 108 of the Clean Air Act, 42 U.S.C. 7401 ~t

seq., as amended from time to time.

“Applicator” moans a device used in a coating line to

apply coating.

“As applied” moans the exact formulation of a coating

during application on or impregnation into a 

substrate.

“Architectural Coating” means any coating used 

for

residential or commercial buildings or their

appurtenances, or for industrial buildings, which is

cite applied.

“Asphalt” moans the dark—brown to black cementitious

material (solid, semisolid, or liquid in 

consistency)

of which the main constituents are 

bitumens which occur

naturally or as a residue of petroleum refining.

r1r~ lii-

128

129

“Asphalt Prime Coat” mcci:

asphalt applied to an absorbent surface as the first of

more than one asphalt goat.

“Automobile” means a motor vehicle capable of oarryinq

no more than 12 passengers.

“Automobile or light-duty truck assembly plant” means--a

facility where parts are assembled or finished for

eventual inclusion into a finished automobile or light—

duty truck ready for sale to vehicle dealers, but net

including customizers, body shops, and other

rcpaintoro.

“Automobile or light-duty truck refinishing” moans 

the

repainting of used automobiles and light-duty trucks.

“Baked 

coatings” means any coating which is cured or

dried 

in an oven where the oven air temperature exceeds

90°C (194°F).

“Batch Loading” moans 

the process of loading a number

of individual parts at the same time for degreasing.

“Bead—Dipping” means the dipping 

of an assembled tire

head 

into

a solvent—based cement.

“Binders” means organic materials and resins which do

not contain VON.

“Bituminous coatings” means black or brownish coating

materials which arc soluble in 

carbon dioulfidc, which

consist mainly of hydrocarbons,

and which arc obtained

from natural deposits or as residues from the

distillation of crude oils or of low grades of goal.

“British Thermal Unit” means the quantity of heat

required to raise one pound of water 

from -60°Fto 61°F

(abbreviated btu).

“Brush or wipe coating” moans 

a manual method of

applying a coating using a brush, cloth, or similar

object.

“Bulk gasoline plant” means -a gasoline storage and

distribution facility with an average throughput of

76,000 1 (20,000 gal) or less on a 30—day rolling

average that distributes gasoline to gasoline

dispensing facilities.

.

on facility

“Can coating 

“

means a facility that includes one 

or

more can coating line(s).

“Can coating line” moans a coating line in which any

protective, decorative, or functional coating is

applied onto the surface of cans or can components.

“Capture” means the containment or rccovcry of

emissions from a process for direction into a duct

which may be exhausted through a stack or vent to a

control device. 

-The 

overall abatement of emissions

from a process with 

an

add—on control device is a

function both of the capture efficiency and of the

control device.

“Capture device” moans a hood, enclosed room floor

sweep or other means of collecting solvent or other

pollutants into a duct. The pollutant can then be

directed to a pollution control device such as an

afterburner or carbon cidsorber. Sometimes the term

is

used loosely to include the control device.

“Capture cffici,...~..2     

the fractL.. of all VON

generated by a process that are directed to an

“Capture system” moans all equipment (including, but

not limited to, hoods, duets, fans, ovens, dryers,

etc.) used to contain, collect and transport an air

pellutant to a control device.

“Clean Air Apt” means the Clean Air Act of 1963, as

amended, including the Clean Air Act 

Amendments 

of

1q77, (42 U.S.C. 7401 Ct seq.), and the Clean Air Act

Amendments of 1900, (P.L. 10l—~49).

distri

!i~li

130

~u.ut

~~uiine plant3 or’ ga3oliflO diI3penaingfaci1itii~u.

“Can” moans any metal container, with or without a top,

cover, spout or handles, into which solid or 

liquid

materials arc packaged.

“Can coating” means any coating applied on a single

walled container that is manufactured from metal obeotS

t~hinnr~r

thr~n 

‘~)

n~iirir

(fl.flhll in.

“Clear coating” moans coatings that lack color and

opacity or are transparent using the undercoat as a

ref lectant base or undertone color.

131

“Clear topcoat” moans the final coating which contains

binders, but not opaque pigments, and is specifically

formulated to form 

a transparent or translucent 

solid

protective film.

“Closed Purge Cystoin” means a system that 

is not open

to the atmosphere and that is composed of piping,

oonnoctions, and, if necessary, flow inducing devioca

that transport liquid or vapor from a piece 

pieces

of equipment to a control device, or return the liqiri4-d

or vapor to the process line.

“Closed vent system” means a system that is not open—to

the atmosphere and is composed of piping, connections,

and, if necessary, flow inducing devices that transport

gas or vapor from an emission source to a control

device.

“Coating” moans a material applied onto or impregnated

into a substrate for protective, decorative, or

functional purposes. Such materials include, but arc

not limited to, paints, varnicihos,soalcrs, adhesives,

thinners, diluents, and inks.

“Coating applicator” 

means equipment used to apply a

coating.

“Coating line” means an operation consisting of a

series of one or more coating applicators and any

associated flash—off areas, drying areas, and ovens

wherein a surface coating 

is applied, dried, or cured.

(It is not 

necessary for an operation to have an oven,

or flash—off 

area, or drying area to 

be included in

this definition-.--)

“Coating plant” means any plant that contains one or

more coating line(s).

“Coil” moans any flat metal shoot or strip that is

rolled or wound in concentric rings.

“Coil coating” means any coating applied on any flat

metal sheet or strip that comes in rolls or coils.

“-Coil coating facility” moans 

a facility that includes

one or more coil coating line(s).

“Coil coating line” means 

a coating line in which any

protective, decorative 

or functional coating is applied

onto the surface of flat metal shoots, strips, rolls,

or coils for industrial or commercial use.

132

“Cold cleaning” 

meano 

the procces of cleaning and

removing soils from surfaces by spraying, brushing,

*lushinp

r~~-

immersion while maintaining

t~hr~~‘ini-~

solvent below 

its

boiling point. Wipe cleaning ionot

included in this definition-.

“Complete Combustion” means a process in which all

earbon contained in a fuel or gas stream is converted

to carbon dioxide.

‘1Componcnt” means, with respect to synthetic organic

chemical and polymer manufacturing equipment, and

petroleum refining and related industries, any piece of

equipment which has -the potential to leak VON

including, but not limited to, pump scale, oomprccioor

scale, seal oil dogassing vents, pipeline valves,

pressure relief devices, process drains, and open 

ended

pipes. This definition excludes valves which arc not

externally regulated, flanges, and equipment in 

heavy

liquid service. For purposes of Cubpart Q of this

t~art, this definition also excludes bleed ports of gear

pumps in polymer 

service.

“Concrete curir~a

to fresh~ 

~.

water.

“Condensate” means volatile organic liquid separated

from its associated gases, which condenses due to

changes 

in the temperature or pressure and remains

liquid at standard conditions.

“continuous process” means, with respect to polystyrene

resin, a method of manufacture in which the styrcne raw

material is delivered on a continuous basis to the

reactor in which the styrene is polyinoriiiod to

polystyrene.

“Control device” means equipment (such as an

afterburner or adsorber) used to remove or prevent the

emission of air pollutants from a contaminated exhaust

otream.

“Control device efficiency” means the ratio of the

pollution prevented by a control device and the

pollution introduced to the control device, 

expressed

as a percentage.

“Conveyori~eddegreasing” moans the continuous process

of cleaning 

and removing soils from surfaces utilizing

e-ither cold or vaporized solvents.

‘J

1~VUPOL1T11)fl

g applied

“Crude oil” means a naturally occurring mixture which

consists of hydrocarbons and sulfur, nitrogen, or

oxygen derivatives 

of hydrocarbons and which is a

liquid at standard conditions.

“Crude oil gathering” moans the transportation of crude

oil or condensate after custody transfer between a

production facility and a reception point.

“Custody transfer” means the transfer of produced

petroleum 

and/or condensate after processing and/or

treating in the producing operations, from storage

tanks 

or automatic transfer facilities to pipelines or

any

other 

forms of transportation.

“Cutback Asphalt” means any asphalt which has been

liquificd by blending with petroleum solvents other

than residual fuel oil and has not boon emulsified with

water.

“Daily-weighted average VON content” means the average

VON content of two or more coatings as applied on a

coating line during any day, taking into account the

fr~r~i, r~f 1rii~1 

r~oatinp

“cluing that 

-~--‘~ --.-‘-“-—

represents, as calculated 

with the following equationi

where:

VON~

—

The average VON content of two or more

coatings as applied rri~h 

~irw

r~nr~1irtrrline in 

iiriitn r,i-

:--::::i:

~bs

and any

——

•-———

.a_

—

A_t.

—

I — 2

2 —

—

e,a.r~

133

VONW 

E V-j---~1 /VT

——

~——,  

,

number 

of different coatings as

applied each day on a coating line,

—

The volume of each coating (minus water

and any compounds which are specifically

exempted from the definition of VON) as

applied each day on a 

~

line in

units of 1 (gal).

flit.

—

yea..

— — —

A..

— —

—

— —

applied each day on a  

ting

134

units of kg VON/I (lbs VON/gal) of

~uui..jny~   

water 

and any oompounes

which arc specifically exempted from

of VON), and

the

definition

The total 

voiUmO 

of

r~i

nnritina~ 

(mi

water and any comp

f

—

ical

...Ufl

lyexcmp

U....

. ~

rin

coating 

1 ini~ 

LInll14 ~.i

from the

applied  

-day

I A..

—

— .~

‘1

~acn

“Day”

means the consecutive 

24 heuro beginning at 12r9G

AM (midnight) local time.

“Degreascr” means any equipment or system used—in

solvent cleaning.

-“Delivery vessel” means any tank truck or trailer

equipped with a storage tank that is used for the

transport of gasoline to a stationary utorage tank at a

gasoline dispensing facility, bulk gasoline plant, or

bulk gasoline terminal.

“-Dip 

coating” 

means a method of applying coatings in

which the part is submerged in a tank filled with the

eoating.

“Distillate Fuel 

quIt 

means fuel oils of grade No. 1 or

2 as specified in detailed requirements for fuel oil

ACTh D—3?O—69 

(1971).

“Dry Cleaning Facility” moans a facility engaged in the

cleaning of fabrics using an essentially nonaqueous

solvent by 

moans of one or more solvent washes,

extraction of excess solvent by spinning and drying ~y

tumbling in an airotrcam. The facility includes, but

is not limited to, washers, dryers, filter and

purification 

systems, waste disposal systems, holding

tanks, pumps 

and attendant piping and valves.

“Effluent Water Separator” means any 

tank, 

box, 

suinp 

or

other apparatus in which any organic material floating

on or entrained 

-or

contained in water entering such

tank, box, 

sump 

or other apparatus is physically

separated and removed from such water prior to outfall,

drainage or recovery of such water.

~atic bell or 

tii ~

~ spray coating mc

apidly-op inning bell— or disc

135

used to create 

a fine mist and apply the coating with

high transfer 

efficiency.

“F1~fjt~

~nr”

moans

r~

tu

r,nriI-iv~i maPhrui

I-n

which opposite clootricul ohargce arc applied to the

substrate and the ooating. The coating is attracted to

the object duo to the electrostatic potential between

them.

“Emission 

Rate” means total quantity of any air

contaminant discharge into the atmosphere in any

one-hour period.

“Emission source” and “source” mean any facility from

which VON is emitted or capable of being emitted inte

the atmosphere.

“Enamel” means a coating that cures 

by chemical

cross-linking of its base 

resin. Enamels can be

distinguished from 

lacquers because enamels arc not

readily resoluble in their 

ni-irrinr~1 solvent.

“Enclose” means to cover any VOL surface that is

exposed to the atmosphere.

“End scaling compound coat” means 

a compound applied to

can ends which functions as a gasket when the end is

assembled onto the can.

“Excess Air” means air supplied in addition to the

theoretical quantity necessary for complete combustion

of all fuel and/or combustible waste material.

“Excessive release” means a 

discharge of more than 295

g (0.65 ibs) of mcrcaptans and/or hydrogen -sulfide into

th-e atmosphere in any 

5 minute period.

“Exterior base coat” moans a coating applied to the

exterior of a can body, or flat shoot to provide

protection to the metal or to provido background for

any lithographic or printing operation.

“Exterior end coat” means a coating applied to the

exterior end of a can to provide protection to the

metal.

“External floating roof” means a cover over an open top

storage tank consisting of a double dock or pontoon

single deck which rests upon and is supported by the

volatile organic liquid being-contained and is equipped

with 

a closure seal or seals to close the space 

betwoe~

the roof edge and tank ahcll.

onmontal conditions”

the followingi 

ambii

mperatures 

oonsiote

gonto, abrasive and

orroslye atmosphcrc~

“Extreme perforinanoo

during intended use

coating” means any

coating which

is exposed to extreme environment-a-I

conditions.

“Fabric coating” 

means 

any coati

applied 

~..

tcx

fabric.

Fabric ooating includes the application of

coatings by impregnation.

~e

ating facility” m

nc

or more 

fabric

a faoility that

ing lines.

“Fabric 

coating line” means a coating line in which any

protective, decorative, or 

functional

coating or

reinforcing material is applied on or impregnated into

a textile fabric.

“Federally enforceable” moans all limitations and

conditions which are enforceable by the Adminintrator

including those requirements developed pursuant to 40

CFR Parts 60 

and

61; requirements within any applicable

~.mplcmentationplan; and any permit requirements

established pursuant to 40 CFR 52.21 or under

regulations approved pursuant to 40 

CFR

Part 51 Subpart

I and 40 CFII 51.166.

“Final repair coat” means the repainting of any topcoat

which is damaged during vehicle assembly.

“Firebox” means the- chamber or compartment of a boiler

or furnace in which materials are burned, but not the

eonibustion chamber or afterburner of an incinerator.

“Fixed roof 

tank” means a cylindrical shell with a

permanently affixed 

roof.

-“Flexographic printing” means the application of words,

designs, and pictures te a substrate by means of a roll

printing technique in which the pattern to be applied

~s raised above the printing rel. and the image -carrier

is made of elastomeric materials.

“Floxographic printing line” means a printing line in

which each roll printer uses a roll Mith raised areas

for applying an image such as words, designs, or

pictures to a substrate.

The image carrier on the roll

is made of rubber or other elastomoric material.

136

“Extreme cnvi~

any or all of

conditions; t~

(203SF); dctcj

nt weather

~tly above 950C

acouring agenti,

137

is:

—

I _i_

cc

114

“Fountain solution” means

the

solution which is applied

to the image plate

to maintain hydrophilio properties

the non-image areas.

“Freeboard Height” means for open top vapor degreasere,

the distance from the top of the vapor sene to the top

of the degreaser tank. For cold cleaning dogreasors,

the distance from the solvent to the top of the

dcgrcascr 

tank.

“Fuel combustion emission source” means any furnace,

boiler, or similar equipment used for the primary

purpose of producing heat or power by indirect heat

transfer.

“Fuel gas system” moans a system for collection of

refinery fuel gas including, but not limited to, piping

for collecting tail gas from various process units,

mixing

drums and controls, and distribution piping.

“Cas service” moans that 

the component oontaino process

fluid that is in the gaseous state at operating

conditions.

“CaD/gas 

method”

means either of two methods for

determining capture which rely only on gas phase

measurements. The first method requires construction

of a temporary total enclosure (TTE) to ensure that all

would-be fugitive emissions arc measured. The o000nd

method uses the building or room which houses the

facility as an enclosure. The second method requires

that all other VON sources within the room be shut down

while the test

is performed, but 

all fans and blowers

within the

room

must be operated according to normal

procedures.

“Casoline” moans any petroleum distillate or petroleum

distillate/alcohol blond having a Reid vapor pressure

27.6 kPci or greater which 

is used as a fuol for

internal combustion engines.

“Casolino dispensing facility” moans any 

site where

gasoline is transferred from 

a stationary storage tank

to a motor vehicle gasoline tank used to provide fuel

to the engine of that motor vehicle.

“Croon Tire Spraying” means the spraying of green

tires, both inside and outside, with release compounds

138

which help remove air from the tire during molding and

prevent the tire from sticking to the mold after

curing.

“Croon Tires” moans assembled tires before molding and

curing have occurred.

“Cross vehicle weight” moans

the

manufaoturor’e grose

weight rating for the individual vehicle.

“Gross vehicle weight rating” moans

the

value specified

by the manufacturer as the maximum design loaded weight

of a single vehicle.

“Heated airless spray” means

an airless spray coating

method in which the coating is heated just prior to

application.

“Hoatset” moans a

class 

of web—offset lithography which

requires a heated dryer to solidify the printing inks.

“Hoatset-wob-off act lithographic printing line” moans a

lithographic printing line in which a blanket cylinder

is used to transfer 

ink

from a plate cylinder to a

substrate continuously fed from a roll 

or an extension

process and an oven is used to colidify the printing

inks.

“Heavy 

liquid” means liquid with a true vapor pressure

of less than 0.3 kPa (0.04 psi) 

at 294.3°K (70°F)

established in a standard reference text or as

determined 

by

ACTh

method D2879—86 (incorporated by

reference in Section 210.112); or which has 0.1 Reid

Vapor Pressure 

as determined by 

ACTH method D32382

(incorporated by reference in Section 218.112); or

which when distilled requires a temperature of 421.959c

-(300°F) or greater to recover 10 percent of the liquid

as determined by

ACTN 

method D86—Bg (incorporated by

reference in Coction 218.112).

“Heavy 

off—highway vehicle products” means, for the

purpose of Subpart F of this Part, heavy construction,

mining, farming, or material handling equipment; heavy

industrial engines; diesel-electric locomotives and

associated

power -equipment; and 

the compononts of such

equipment or engines.

-j-,c~1rJ

,

.ehici... 

,~..

means a facility -that includes

off-highway vehicle ~

~oduot~ coating facility”

.._._

139

“-Heavy 

otr-n~ignwayvehicle 

produws coating line” means

a coating line in which any protective, dooorative, or

f-unotional coating is applied onto the surface of 

heavy

off-highway vehicle products.

“High temperature aluminum coating” means a coating

that is certified to withstand a temperature of 537.6°C

(1000°F) for 24 hours.

“Hood” means a partial enclosure or canopy for

capturing and exhausting, by means of a draft, the

organic vapors or other fumes rising from a ooating

process or other source.

“Hood capture efficiency” moans the omissions from a

process which arc captured by the hood and directed

into a control device, expressed as a percentage of all

emissions.

“Hot well” 

means the reservoir of a condensing unit

receiving the condensate from a barometric condenser.

‘tflour” means a block period of 60 minutes (e.g., 1100am

to 21005m).

“In—process

tank” means a container used for mixing,

blending, hosting, reacting, holding, oryctallicing,

evaporating or cleaning operations in the manufacture

of pharmaceuticals.

“In-situ Sampling Systems” means nonoxtractive samplers

or in—line samplers.

“-In vacuum service” means, for the purpose of Subpart 

Q

of this Part, -equipment which is operating at an

internal pressure that is at least 5 kra (0.73 psia)

below ambient pressure.

“-Incinerator” means a combustion apparatus in which

refuse is burned.

“-Indirect heat transfer” means transfer of heat in ouch

a—way that the source of heat does not 

come 

into direct

eontact with process materials.

“Ink” means a coating 

used in printing, impressing, or

transferring an image onto a cubstrato.

“-Interior body spray coat” means a coating applied by

spray to the interior of a can body.

140

“internal-floating

roof” moans a paver or roof

in a

fixed-roof tank which rests

the volatile organic liquid

upon and is supported

being contained and is

equipped with a closure seal or 

seals to close the

space

between 

the roof edge

and tank shell.

..oquors” 

moans any clear wood finishes formulated

with

evaporation without chornioal reaction, including clear

lacquer sanding scalers.

“Large appliance” means any residential and commercial

washers, dryers, ranges, refrigerators,

froe~ers, water

heaters, dishwashers, trash compactors, air

conditioners, and other

similar products.

“Large appliance coating” means any coating applied to

the component 

metal parts (including, but not limited

to, doors, oases,

li-do, 

panels, and interior support

parts) of residential and commercial washers,

dryers,

ranges, refrigerators, freezers, water heaters,

dishwashers, trash compactors, air

conditioners, and

other similar products.

“Large appliance coating facility” moans a facility

that includes one or more large appliance coating

line(s).

“Large appliance coating line” means a coating line in

which any protective, decorative, or functional coating

is applied onto the surface of large appliances.

“Light liquid” moans VON in the liquid state which is

not defined as heavy liquid.

“Light—duty truck” means any motor vehicle rated at

~,&50 kg 

gross vehicle weight or less, designed mainly

to transport property.

u~ccrm

liquid

~ning capture which require

both

phase measurements and analysis.

gas phase and

The first

method requires construction of 

a TTE. The second

method 

uses the building or room which

houses the

facility as an onc...osure. The scoona

...~....noa

requi......~

that -all other VON sources within

the room be shut down

while the toot

within the room

is performed, but

must be operated

all fans

according

and

blowers

normal

141

“Liquid Mounted Coal” means a primary 

seal mounted in

continuous contact with the liquid between the

tank

wall and the floating roof edge around the

or component

circumference of the roof.

“Liquid service” means that the equipment

contains process fluid that is in a liquid

state at

operating conditions.

ri~.

~JujppJ.j1g~

means 

r1n’~r ~t.r 1141 III I

,~

I U~

ri ri r~—~-rri~r

ru-i 

i I

TifT

‘Liqui~:

~akjn,

1 includi

clouding

formation.

ri from 

rITtfl

1 tT1I~

“Lithographio printing line” means a printing line,

except

~nu~ ~ su~atraiu

not. 

nooeasar.~.J.y

wu

tram

an unwinding roll, in which each roll printer uses a

roll whore both 

the

image and non-image

areas 

are

essentially in the same plane (planographio).

“Low Colvent Coating” means a coating which contains

less organic solvent than the conventional coatings

used by the industry. Low solvent coatings include

water-borne, higher solids, clcctro—dcpooition and

powder coatings.

“Magnet wire” means aluminum or copper wire formed into

an electromagnetic coil.

“Magnet wire costing” means any 

coating 

or electrically

insulating varnish or enamel applied to magnet wire.

“Magnet wire coating facility” means a facility that

includes one or more magnet wire coating line(s).

“Magnet wire

coating line” means a coating line in

which any protective, decorative, or functional ooating

is applied onto the surface of a magnet wire.

“Malfunction” means any sudden and unavoidable failure

of air pollution control equipment, process equipment,

or a process to operate in a normal or usual manner.

Failures that are caused entirely or in part by poor

maintenance, careless operation,

or

any other

preventable upset condition or preventable equipment

breakdown shall not be considered malfunotions.

“Manufacturing process” moans a method whereby a

process emission source or series of process 

omission

souroes 

used to raw materials, feed stocks,

oubaaaomblies, or other components into a product,

either for sale or for use as a component in a

subsequent manufacturing process.

“l4atcrial

142

—

ia...

designed to transport and recover otyreno monomer and

other impurities from other products and by-products in

a polystyrene plant, including but not limited to the

styrene devolcitilicor unit and styrene recovery unit.

“Maximum theoretical emissions” moans the quantity of

volatile 

organic material emissions that theoretically

could be emitted by a stationary

source 

before add—on

controls based on the design -capacity or maximum

production -capacity of the source and 8760 hours per

year. The design capacity or

maximum 

production

capacity includes use of coating(s) or

ink(s) 

with

the

highest volatile organic material content actually uoed

in practice by the source.

Provided, however, the

Agency shall, when appropriate, and upon request by the

permit ~zipplicant,limit the “maximum theoretical

emissions” of 

a source by the imposition of conditions

in a federally enforceable operating permit for such

source. Such conditions -shall not be inconsistent with

requirement of the Clean Air

Act, as 

amended, or any

applicable requirements established by the Board. Such

conditions shall be established in plaoe of design

capacity or maximum

production capacity in calculating

the “maximum

theoretical emissions” for such source and

may include, among other things, the establishment of

production limitations, capacity limitations, emission

limitations, or limitations on 

the volatile organic

material content of coatings or inks, 

or the hours of

operation 

-of

any emission source, or a combination of

any such limitations.

Production or capacity limitations shall be established

on basis of no longer than one month except in those

cases where a limit spanning a longer 

period

of time is

appropriate. In such cases, a rolling limit” shall be

employed. 

Any

production or capacity limitations shall

be verified through appropriate rooordkoeping. (Board

Notei

The UCEPA may deem operating permits which do

not conform to the operating permit program

requirements and the requirements—of

tJSEPA’o underlying

regulations, including the requirement that limitations

be quantifiable and enforceable as a practical matter,

not “federally enforceable.”)

“Metal furniture” means a furniture piece 

including,

but

not limited to, tables, chairs,

waste 

baskets,

beds, desks, lookers, benches, shelving, file cabinets~

lamps, and room dividers.

“Metal furniture coating”

means any non-adhesive

seating applied to any furniture piece made of metal or

143

any metal part which

is or will be 

assembled with other

metal, wood, fabric, plastic or 

glass parts to form a

furniture piece including, but not limited to, tables,

chairs, waste baskets, beds, desks,

lookers, bcnohco-,-

shelving flit’ 

cabinets,

lamps

r~r~i~

room 

dividers—

This definition shall not 

apply to any coating line

pentino misocllaneouo metal parts or products.

“Metal furniture coating facility” moans a facility

that includes one or more metal furniture coating

line(s).

“Metal furniture coating line” means a coating line in

which any protective, decorative, or functional coating

is

applied onto 

the

surface of 

metal furniture.

“ic~aJ.J~.oones—typo

scsi” moans 

a

primary or soconuary

.~n1 ~‘tr~r~    

-~f

metal shoots

t,hlr~h ~

ring, springa, or 1...

wnich attach the shoes

to the floating roof and hold

the chaos against the tank 

wall1 and a coated fabric

which is suspended from the shoes to the floating roof.

“Miscellaneous fabricated product

process” means~

manufacturing

A manufacturing

process involving one or more of the

following applications,

including any drying and

itting VON~

curing

of formulations, and capable of 

joined together 

4-—

‘~1Jr’

products

Asphalt

•1 - a-

Asphalt t -paper or felt

Coatings or dye to loather

Coatings to plastic

Coatings to rubber

or glass

Plastic foam scrap or “fluff” from the manufacture

of foam containers 

and

packaging 

material to

form

resin pallets

Rosin solutions to fiber substances

Viscose solutions for food casings

144

The storage and handling of formulations associated

with the process described above, and the use and

handling of organic liquids and other substances

for

clean-up operations associated with the proocas

described in this definition.

“Miscellaneous formulation manufacturing process”

means 

*

A manufacturing process which

compounds 

one

or more

of

the following and is capable of emitting VOH~

Adhesivea

Asphalt solutions

Caulks, cealants, or waterproofing ag

Coatings, other than paint and ink

Concrete curing compounds

Dyes

Friction materials and compounds

Resin solutions

Rubber solutions

The storage and handling of formulations associated

with the process described above, and the usc and

handling of organic liquids and other substances for

clean—up operations associated with the ‘~occss

des-oribed in this

definition.

“Miscellaneous metal parts or products” means any metal

part 

or metal product, even if attached to or oombin6d

with 

a nonmetal part or product, except

pans, coils,

metal furniture, large appliances, magnet wire,

automobiles, ships, and airplane 

bodies.

“-Miscellaneous metal 

parts and products coating” moans

any coating applied to any

metal part or metal 

product,

even if attached to or combined with a nonmetal part or

product, except cans,

coils, metal furniture, large

appliances, and magnet wire.

Prime goat, prime

surfacer coat, topcoat, and final repair coat for

automobiles and light-duty trucks are not miscellaneous

metal parts and products coatings.

However, underbody

145

anti-chip (e.g., underbody plastisol) automobile and

light-duty truck coatings are miscellaneous metal 

parts

and products coatings.

Also, automobile or light duty

truck 

refinishing coatings, coatings applied to the

exterior of marine vessels, coatings applied to the

exterior of airplanes, and the oustomiced topooating—ef

automobiles and trucks if production is loss than 35

vehicles per day are not miscellaneous metal parts

and

products coatings.

“Micccllanoous motal parts or products coating

facility” means a faoility that includes one or more

miscellaneous metal parts or produots coating lines.

“Miscellaneous metal parts or products coating line”

means a coating line in which any protcotive,

decorative, or functional coating is applied 

onto 

the

surface of miscellaneous metal parts or products.

“Miscellaneous organic chemiosi manufacturing process”

means:

A manufacturing process which produces, by chemical

reaction, one or more of the following organic

oomi~oundsor mixtures of organic compounds and which is

capable of emitting VOMz

Chemicals listed in Appendix A of this Part

Chlorinated and sulfonated compounds

Cosmetic, detergent, soap, 

or curfactant

intermediaries or specialt ics and products

i-i — — a

— a ~

-I--

Gi-l and petroleum pr

r~1 ~

additives

Resins or

polymers

Rubber additives

~wcctcncrs

Varnishes

The storage and handling of for

with the process described abov

1-ations associated

and

the usc and

146

handling of organic liquids and other substances for

clean-up operations associated with the process

described in this definition.

means to measure and record.

package coating” -moans a ooating 

made

from

“Monitor”

“Multiple

more 

than

prior to

one

different ingredient which must be

using and has a limited pot life due to

mixed

the

chemical

reaction 

which occurs upon mixing.

materi...

ia~

—

iiosiona”

,..:ganio

means 

p disohar——               

1-nt

~rif~

r’-tcptablc Volatile 

-Orsani

ntmospncre

uu

---

~.~nstrumerit

roaai.., of

less than 500 ppm above

bacitground as determined ~n

accordance with 40 

CFR 60. 485(o).

“Offset” moans, with respect -to -printing and publishing

operations, use of a 

blanket cylinder to transfer

ink

from the plate cylinder to the surface to be printed.

“Opaque stains” means all stains that 

arc

not semi-

transparent stains.

“Open top vapor degreasing” means the batch process of

cleaning and removing soils from surfaces by condensing

hot solvent vapor on the colder metal parts.

“Open—ended valve” means any valve, except pressure

relief devices, having

one

-side of the valve in

contaot

with process fluid and one side open to the atmosphere,

either directly or through open -piping.

“Operator of

Casoline Di~spensing Facility” moans any

person who icr 

the lessee of or

operates, controls or

supervises a gasoline dispensing facility.

“Organic compound” means any compound of carbon,

excluding carbon monoxide, carbon dioxide, carbonic

acid, metallic carbjdpg

-or

-carbonates, and

ammonium

carbonate.

“Organic 

material”

means any 

chemical compound of

oarbon including 

diluents and

thinners 

whioh are

liquids at standard conditions and which are used as

dissolvers, viscosity reducers, or cleaning agents, but

excluding methane, carbon monoxide, carbon dioxide,

carbonic acid, metallic—carbonic acid, metallic

carbide, metallic carbonates, and

ammonium 

earbonate-~-

one or more of the following purposes.

thj,

or polymeri~c a coating

-or ink.

“Overall control” means the product. of the capture

efficiency and the control device efficiency.

“Overvarnish” moans a transparent coating applied

directly over

ink -or 

coating.

“Owner of 

Casolino Dispensing Facility” moans any

person who has legal or equitable title to a stationary

storage

tank 

at a gasoline dispensing facility.

“Owner or operator” moans any person who owns,

operates, leases, -controls, or supervises an

emission

source

o~air pollution control equipment.

“Packaging rotogravure printing”

means rotogravure

printing upon paper, paper board, metal foil, plastic

film, and other substrates, which are, in subsequent

operations, formed into packaging products or labels

fr~r ~ 

ir~1r”-i ‘f-n hrr

i~r~1~1

“Packaging rotogravure printing line” means a

rotogravure printing line in which sui~face coatings are

applied to paper, paperboard, foil, film, or 

other

substrates which arc to be 

used to produce containers,

packaging products, or labels for articles.

“Paint manufacturing plant” means a plant that mixes,

blends, or compounds enamels, laoqucrs, scalers,

ehcllacs, stains, varnishes, or pigmented surface

coatings.

“Paper coating” means any coating applied on paper,

plastic film, or mctalli-o foil to make -certain

products, including (but

not limited to) adhesive 

tapes

and labels, book covers, post cards, office copier

paper, drafting paper, or pressure sonsitivc

tapes.

Paper coating 

includes the application of coatings by

impregnation and/or saturation.

“Paper coating facility” moans a facility that includes

one or more paper ooating lines.

“Paper coating

line”

moans a coating lino in 

which

any

protective, decorative, or functional coating is

147

“Organic vapor” means the gaseous phase of an organie

material or a mixture of organio materials present in

the

atmosphere.

“Oven” means a

chamber within which heat is used for

~—,-————z——-_

plastio film, or metallic foil to make certain

p~eT..

~.,

includi~ -(but

not

limited to)

.-“~---~

~1I1.—

-~

labcl3,-

~ieT 

oar&.,

ducts

no-olt covers, 

r s~-

148

.~...

tapee

Ott1t~

u~Jyior

paper, ur~tit.ingp~ipei, .~.uiu 

p~uuuL-c

ucnsltivc tapcu.

“Parts per million

(volume)” moans a volume/volume

ratio which expresses the volumetric conoontration of

gaseous air contaminant in a 

million unit volume of

gas.

“Person” means any individual,

corporation,

partnership, association, Ctatc, municipality,

political subdivision of a Ctatc; any agency,

department, or instrumentality of the United Ctatcs-f

and any officer, agent, or employee thereof.

“Petroleum” means the crude

oil

removed from 

the earth

and the oils derived from tar sands, shale, and coal.

“Petroleum Liquid” means orude oil, condensate or any

finished or intermediate product manufactured at a

petroleum refinery, but not including

Number 2 through

Number 

6 fuel oils as specified in ACTM D-396-69, gas

turbine fuel oils Numbers 2—CT through 4-CT as

specified in ACTh D-2880—71 or diesel fuel oils Numbers

2—D and 4-D, as specified in ACTH D 975-6g.

“Petroleum refinery” means any facility engaged in

producing gasoline, kerosene, distillate fuel oils,

residual fuel oils, lubricants, or other products

through distillation

of petroleum, or through

r-edistillation, cracking, or reforming of unfinished

petroleum derivatives.

“-Pharmaceutical” means any compound or mixture, other

than food, used in the prevention, diagnosis,

alleviation, treatment, or cure of 

disease in human and

animal.

“-Pharmaceutical coating operation” moans a device in

which a coating is applied to a pharmaceutical,

including air drying 

-or

curing of the coating.

“-Photochomically Reactive Material” means any organic

material with 

an aggregate of more 

than 30 percent of

its total volume composed of 

the chemical compounds

classified below or the composition of which exceeds

any

-of

the following individual percentage composition

limitations. Whenever any photoohcmically reactive

material or any 

constituent of any organic material may

be classified from its chemical 

structure into more

of organic materials it

shall be considered as a 

member

of the

most reactive

group, that is, the group having

the least allowable

percent 

of the total organic materials.

A combination of hydrocarbons, alcohols,

aldehydos, 

caters, others or kotonos having an

clef iniL.

cycle-olaf inL...

..jpcs -es-

tur~t-~

5pcrccnt.

~ly

unsa

Lo-fl’

149

~_1__

_1~~_~~_

~ieL-uiLLoroetnyicneUL~ iULU~i.Cfl~.

A combination of aromatic compounds with eight oz

more carbon atoms to the molecule 

except

cthylbcnzencz

8 percent.

A combination of ethylbcnscnc, kctoncs having

branched hydrocarbon structures or tolucnc~ 20

percent.

“Pigmented coatings” moans

opaque coatings containing

binders and colored pigments 

which arc formulated to

conceal the wood surface either as an 

undcrooat 

or

topcoat.

“Plant” means all of the pollutant-emitting activities

which belong to the 

came industrial grouping, are

located on one or more contiguous or adjacent

properties, and are under the control of the same

person (or persons under common control), except the

activities of any marine vcssol. Pollutant—emitting

activities shall 

be considered as part of the same

industrial grouping if they belong to the same 

“Major

Croup” (i.e., which have the 

same two-digit code) as

described in the “Ctandard Industrial Classification

Manual, 1987” (incorporated by reference in Cection

218.112).

“-Plasticicers” moans a substance added -to a polymer

composition to soften and add flexibility

to the

product.

“Pneumatic flubber Tire Manufacture” means the

production of pneumatic rubber tires with a bead

dAamotcr up to but not including 20.0 inches and cross

section dimension up to 12.8 inches, but not inoludi-ng

specialty tires for antique or other vehicles when

pr-oduced

on equipment separate from normal produotiofi

lines for passenger or truck

type 

tires.

“Polystyrono Plant” moans any plant

using 

styrefle to

manufacture polystyrene resin.

“Pressure Release” moans 

the emission of 

materials

resulting from system pressure being greater than sot

pressure 

of the pressure relict device.

“Pressure ‘rank” 

means 

a tank 

in

which fluids are

etered

at a pressure greater 

than atmospheric pressure.

“Prime goat” moans the first of two or more coatings

applied to a surface.

“Prime surfacer goat” moans a coating 

used to touch up

areas on the surface 

of automobile or light—duty truck

bodies 

not adequately covered by the prime coat before

application of the top goat. 

The

prime surfacer coat

is

applied between

the prime -coat and topcoat. An

anti—chip coating applied to main body parts (e.g.,

rocker panels, bottom of doors and fenders, and leading

edge of roof) is a prime surfacer coat.

“Primers” moans any coatings formulated and applied to

substrates to provide a firm bond between the substrate

and oubsccment goats.

“Printing”   

the applicati~-ef~ 

..~.,

designs, and

pictures to a substrate using 

ink.

“Printing line” means an operation consisting -of a

sprigs 

pf

one or more roll printers and any associated

roll coatcrs, drying areas, and ovens wherein one or

more coatings arc applied, dried, and/or cured.

“Process” means any stationary emission source 

other

than a fuel combustion emission 

source

or an

incinerator.

“Process Unit” means components assembled to produce,

as intermediate or final products, one or more of

the

ehemjcplp listed in 

35

Ill. Adin. Code 218 Appcndi~ A.

A process unit can operate independently if supplied

with sufficient food or

raw materials and sufficient

storage facilities for the product.

“Process Unit 

Chutdown” means 

a work practice 

-or

eperationalproccdure that stops production from a

process unit or part of a process 

unit.

An unscheduled

work practice or operational procedure that stops

production from a proos

t*nit 

for

less than 24 h

150

“rolyotyrencr(osin”

D1C~flG

styrene po~.ymLx-

~.inu

~

a polystyrene 

plant.

consisting of

which- 

manuracturoa at

unit or part of a pr

net

~..

~~1

151

shutdown. The usc of 

spare-eemponcnts and technically

feasible bypassing of -components without stopping

production is not 

a process unit shutdown.

“Production equipment exhaust system” means a system

f or collecting and directing into the atmosphere

emissions of -volatile organic material from roaotoro-j-

centrifuges, and other process emission sources.

“Publication rotogravure printing line” means a

retogravure printing line in which coatings are 

applied

to paper which is subsequently formed into 

books,

magazines, catalogues, brochures, directories,

newspaper

supplements, or other

typos

of printed

material.

“Purged Process Fluid” means liquid or vapor from a

process unit 

that contains volatile organic material

and that results from flushing or gleaning the 

sample

line(s) of a process unit so that an uncontaminated

sample may then be taken for testing or analysis.

“Reactor” means a vat, vessel, or other device in which

chemical reactions take place.

“Reasonably Available Control Technology (ItACT)” means

the lowest emission limitation that an-emission source

is capable of meeting

by the application of control

technology that is reasonably 

available considering

technological and economic feasibility.

“Refiner” means any person who 

owns,

leases, operates,

controls, or supervises a refinery.

“‘tefinery Fuel Caz”

~ petroleum rcfi.iiw~y 

p~ue~uuuiiii.~ ..uiu wuiu~i 

.i.u

conthustod at the refinory, including any gaseous

mixture of natural -gas and 

fuel gas.

“Refinery unit, 

process unit or unit” moans a oct of

compononts which are a part of 

a basic process

operation such as distillation, hydrotroating,

eraoking, or reforming of hydrocarbons.

“Refrigerated condenser” means a surface condenser in

which the

coolant 

supplied

to the condenser has 

boon

cooled by a mechanical device, other than by a 

cooling

means any gac which 

iøgcncrated by

tower or evaporative spray cooling, suen as

refrigeration unit or steam chiller 

unit.

152

“Reid vapor pressure” means the standardized 

measure

the vapor pressure of

a liquid in pounds per 

square

inch 

absolute (Psia)

~at 100OF (37.3CC).

“Repair coatings” means coatings used to correot

-imperfections or damage to furniture surface.

“Repaired” moans, for the purpose of Cubpart Q of

thiS

Part, that equipment component has

been adjusted, or

otherwise altered, to eliminate a leak.

“Residual Fuel Oil” means fuel oils of grade flo. 4, 5

and £ as specified in 

detailed

requirements for fuel

oils A.C.T.HS D—396—69 (1971).

“Retail Outlet” moans any 

gasoline dispensing facility

at which gasoline

is sold or offered for sale for use

in motor vehicles.

“Roll coatcr” means an apparatus

in

which a 

uniform

layer of coating 

is

applied

by

moans of one or more

rolls across the entire width of 

a moving substrate.

“Roll printer” means an apparatus used in the

application of words, designs, and pictures to a

substrate, usually

by

means of one or more rolls each

with only partial coverage.

“Roll printing” moans the application of words,

designs, and pictures to

a substrate usually by moans

of a series of hard rubber or metal rolls each with

only partial coverage.

“poller coating” means a method of 

applying

a coating

to a sheet or strip in which the coating is transferred

by a roller or series of rollers.

“Rolling limit” means that a limit

or limitation must

not exceed an annual 

limit rolled on a

basis 

of at moot

a month monthly 

basis; that is, for example, 

a monthly

production or capacity level must be 

determined for

each

parameter subject to a production or capacity

1t~itationand 

added to the eleven prior monthly levels

for monthly

comparison with the annual limit.

“Rotogravure printing” means 

the application of words-,

designs,

and pictures to a 

substrate

by means of a roll

printing technique in which the pattern to be applied

is recessed

r~1ntivr~

tn

thr~ non—imr~rit~srnn.

153

“Rotogravuro printing

line” means a printing line in

which each roll printer uses 

a roll with recessed areas

for

applying an imago to a 

substrate.

“Cafcty relief valve” means a valve which is normally

closed and which is designed to open in order to

relieve excessive pressures within a vessel or pipe.

“Banding scalers” means any coatings formulated for and

applied to bare wood for sanding and to seal the wood

for subsequent application of varnish. To be

considered a sanding sealer a coating must be clearly

labelled as ouch.   

“-Sealer” means a coating containing 

binders which seals

wood prior to the application of the subsequent

coatings.

“Censor” moans 

a device that measures a

physical

quantity or the change in a physical quantity ouch as

temperature, pressure, flow rate, 

pH, or liquid level.

“Cemi—transparont stains” means stains containing dyes

or semi-transparent pigments which are formulated to

enhance wood grain 

and change the color 

-of the 

surface

but not to conceal the surface, including, but not

limited to, sap stain, toner, non—grain raising stains,

pad stain, or spatter stain.

“Cot of safety relief valves” means 

one or more safety

relief 

valves designed to open in order to relieve

excessive pressures in the same vessel or 

pipe.

“Chect basocoat” means 

a coating applied to metal when

the metal is in sheet form to serve as either the

exterior or interior of a can for either two-piece or

three—piece cans.

“Cide-secim spray coat” means a coating applied to the

seam of a three-piece can.

“Cinglo coat” moans one coating application applied—to

a metal surface.

“Solvent” means a liquid substance that is used to

dissolve or dilute another substance.

“Colvent cleaning” 

means the process of cleaning soils

from surfacos by cold cleaning, open top vapor

dogreasing, or oonveyori~eddogreasing.

154

“Specified

air contaminant” means any air contaminant

as to which this- Part contains emission standards or

other specific limitations.

“Splash loading” means 

a method of loading a 

tank,

railroad 

tank

car, 

tank 

truck, or trailer by usc of

other than a submerged loading

pipe.

“Stack” moans a flue or conduit, free—standing or with

exhaust port above the roof of the -building on which it

is mounted, by 

which

air contaminants 

arc emitted into

the atmosphere.

‘~-Standard conditions” means a temperature of 70~Fand a

pressure of 14.7 psia.

“Standard cubic

foot -(oaf)” means the volume of one

cubic foot of gas at standard conditions.

“Standard Industrial Classification Manual” means the

Standard Industrial Classification Manual (1987),

Superintendent of Documents, U.C. Covcrnincnt Printing

Off icc, Washington, 

DC 20402 (incorporated by reference

in Section 218.112).

“Start-up” means the setting in operation of an

emission source 

for any purpose.

“Stationary emission source” mean an emission source

which is not self-propelled.

“Storage tank or storage vessel” means any stationary

tank, 

reservoir or container used for the storage of

VOL.

“Styronc Dovolatiliser Unit” means equipment performing

the function of separating unreacted atyrene monomer

and other volatile components

from polystyrene in a

vacuum devoiatili~er.

“Etyreno Recovery Unit” means equipment performing the

function of

separating otyreno monomer from 

other less

volatile

components of the -styreno devolatilizcr 

unit’s

output.

The separated otyrene monomer may be reused as

a raw material 

in the polystyrene plant.

“Submerged loading pipe” means any 

discharge pipe or

no~lc which meets either of 

the following oonditions*

Whore 

the tank 

is filled from tne top, the 

end of

the discharge pipe

or noz~lomust be totally

155

submerges wncn the liquid level -i

above the bottom of the tank.

Where 

the tank is filled from the side, the

discharge pipe 

or nozzle must be totally submerged

when the liquid level is 4?~cm 

(18 in.) above the

bottom of the tank.

“Substrate” moans the surface onto 

which a coating is

applied 

or into which a coating is impregnated.

“Surface condenser” means a device which removes a

substance from 

a gas stream by reducing the temperature

of the stream, without direct contact between the

coolant and the stream.

“Synthetic Organic Chemical or Polymer Manufacturing

Plant” means a plant that produces, as intermediates or

final products, one or more of the chemicals or

polymers listed in 35 Iii. Adm. Code 218 Appendix A.

“Tablet coating operation” means a pharmaceutical

coating operation

in which tablets 

are coated.

“Thirty-day rolling average” moans any value

arithmetically averaged over any consecutive

thirty days.

“Three piece can” means a can which is 

made from a

rectangular sheet and two circular ends.

“Topcoat” moans a coating applied in a multiple coat

operation other than prime coat, final repair coat, or

prime

surfacer coat.

“TPopcoat operation” means all topcoat spray booths,

flash-off areas, and bake ovens at a 

facility which are

UDrOd 

to apply, dry, or cure the final coatings -(except

final off-line repair) on components of automobile or

light-duty truck bodies.

“-Transfer efficiency” moans the ratio of the amount of

eeating 

solids deposited onto a part or product to 

the

total amount of coating solids used.

“-Tread End Cementing” means the application of a

ee-lvent-basod cement to the tire tread ends.

“True vapor pressure” moans the equilibrium partial

t~rcssur~   

a volatile organic liquid as

ut uuuo~aunCe

with methods described in

156

“Zvaporation Loss 

From Floating Roof 

Tanks,” 

second

edition, February 

1980 (incorporated by reference in

Section 218.112)-.

‘t~~~naround”means

the procedure of shutting 

down 

an

operating ref 

i.ncry unit, emptying go acous and liquid

uun~n~ ~.u uu ~i.n~pcu.an,    

cnunu~ 

una

r~p~ir wori~-r

and putting

the unit back into production.

“Two—piece

pan” moans a can which is 

drawn 

from a

shallow cup and requires

only one 

end to be attaohed-~-

“Underoocitero” means any coatings formulated for and

applied to substrates to provide a smooth surface

for

subsequent 

coats.

“jjndcrtrepd Cementing” moans the application of a

solvent-based cement to the underside of 

a tire tread.

Unregulated safety relief valve” means 

a safety relief

valve which -cannot b-c actuated by a means other than

high pressure in the pipe or vessel which it protects.

“Vacuum producing system” moans any reciprocating,

rotary, or -eontrifugal blower or compressor or any jot

ejeotor 

or device that creates suction from a 

pressure

below atmospheric -and discharges against a

greater

pressure-.-

“Valves not externally regulated” moans valves that

have no external controls, such as in—line check

valves-.-

“Vapor balance system” -moans any combination of pipes

or hoses which creates a closed system between the

vapor spaces of an unloading tank and 

a

receiving tank

such that vapors displaced from the receiving tank are

transferred to the

tank 

being unloaded.

“Vapor collection system” means all piping, seals,

hoses, connections,

pressure vacuum vents, and other

possible 

sources between the gasoline delivery vessel

and

the

vapor processing unit and/or the storage 

tanks

and vapor holder.

“Vapor control system” means any system that limits or

prevents 

release to the atmosphere

of organic 

material

in the vapors displaced from a

tank 

during

the

transfer

of gasoline.-

“Vapor—Mounted Primary Coal” means a primary seal

meunted with an air space bounded by the bottom of the

157

primary seal, the tank wall, the liquid surface and the

floating roof.

“Vapor recovery system” 

means a vapor gathering

system

capable of

collecting all VOM vapors and -gases

discharged from the storage tank and a vapor dispose-I

system capable of processing such VOM

vapors and

gases

so as to prevent their emission to the 

-atmosphere.

“Vehicle” means 

a dcvioe by which any person or

property may be propelled, moved, or drawn upon a

highway, excepting a device moved exclusively by 

human

power or used exclusively upon stationary rails or

tracks.

“Vinyl coating” means any topcoat or printing ink

applied to vinyl coated fabric or vinyl shects. Vinyl

coating does not include placitisols.

“Vinyl coating facility” means a facility that includes

one or more vinyl coating line(s).

“Vinyl coating line” means a coating line in which -any

protective, decorative

-or

functional coating is applied

onto vinyl coated fabric or vinyl sheets.

“Volatile organic liquid (VOL)” moans any substance

which is liquid at storage conditions and which

contains volatile organic compounds.

“Volatile organic material (VOM) or volatile organic

compound (VOC)” means “volatile organic material (VOM)

or volatile organic compound (VOC)”, as that term is

defined in 

35

Ill. Adm. Code Part 211.

“Volatile Petroleum Liquid” moans any petroleum liquid

with a true vapor pressure that is greater than 1.5

psia (78 millimeters of mercury) at standard

conditions.

“Wash coat” moans a-coating containing binders which

seals wood surfaces, prevents undesired staining, 

and

controls penetration.

“Wastowator (Oil/Water) Separator” 

moans any 

-device 

or

piece of equipment which utilit~esthe difference in

density between oil and water to remove 

oil

and

associated chemicals from water, or any device, such as

a flocculation tank or a olarifier

which removes

___

__i~_

158

“Web” means a substrate which is printed in continuous

roll—f cd presses.

“Wood

furniture” moans room 

furnishings including

oabinets (kitchen, bath, and vanity), tables, chairs-i

beds, 

pof

as, shutters, art ebjeets,

weed 

paneling,

weed

flooring, and

any

other coated furnishings made of

wood, wood

compositicn, or 

fabricated

wood 

materials-a

“Weed furniture eeating facility” means a fasility that

includes one or more wood furniture coating lino(o)—~-

“Wood furniture coating

line” moans a coating line in

which any protective, decorative, or functional coating

is applied onto 

wood furniture.

“Woodworking” moans 

the shaping, sawing, grinding,

smoothing, polishing, and making into products of any

f-cnn or shape of wood.

The definitions of 35 Ill. Adin. Code 211

apply to this Part.

(Source: Amended at 

—

Ill. Reg.    

effective 

___________

_________________________ )

Section 218.105  

Test Methods and Procedures

a)  Coatings, Inks and Fountain Solutions

The following test methods and procedures shall be used

to determine compliance of 

~ applied coatings, inks,

and fountain solutions with the limitations set forth

in this Part.

1)  Sampling: Samples collected for analyses shall be

one-liter taken into a one—liter container at a

location and time such that the sample will be

representative of the coating as applied (i.e.,

the sample shall include any dilution solvent or

other VON added during the manufacturing process).

The container must be tightly sealed immediately

after the sample is taken.

Any solvent or other

VOM added after the sample is taken must be

measured and accounted for in the calculations in

subsection (a) (3) of this Section. For multiple

package coatings, separate samples of each

component shall be obtained. A mixed sample shall

not be obtained as it will cure in the container.

Sampling procedures shall follow the guidelines

presented in:

159

ASTN 

D3925-81(1985) standard practice for

sampling liquid paints

and related pigment

coating. This practice is incorporated by

reference 

in Section 218.112 of this Part.

B)

ASTM 

E300-86 standard practice for sampling

industrial chemicals. This practice is

incorporated by reference in Section 218.112

of this Part.

Analyses:

The applicable analytical methods

specified below shall be used to determine the

composition of coatings, inks, or fountain

solutions as applied.

A)  Method 24 of 40 CFR 60, Appendix A,

incorporated by reference in Section 218.112

of this Part, shall be used to determine the

VON content and density of coatings. If it

is demonstrated to the satisfaction of the

Agency and the USEPA that plant coating

formulation data are equivalent to Method 24

results, formulation data may be used. In

the event of any inconsistency between a

Method 24 test and a facility’s

formulation

data, the Method 24 test will govern.

B)  Method 24A of 40 CFR Part 60, Appendix A,

incorporated by reference in Section 218.112

of this Part, shall be used to determine the

VON content and density of rotogravure

printing inks and related coatings. If it is

demonstrated to the satisfaction of the

Agency and USEPA that the plant coating

formulation data are equivalent to Method 24A

results, formulation data may be used. In

th& event of any inconsistency between a

Method 24A test and a facility’s formulation

data, the Method 24A test will govern.

C) The following

ASTN 

methods

are the analytical

procedures for determining VON:

i)  ASTM D1475-85: Standard test method for

density of paint, varnish, lacquer and

related products. This test method is

incorporated by reference in Section

218.112 of this Part.

ii)

ASTN 

D2369-87: Standard test method for

volatile content of a coating. This test

160

method is incorporated by reference in

Section 218.112 of this Part.

iii) ASTM D3792-86: Standard test method for

water content of water—reducible paints

by direct injection into a gas

chromatograph. This test method is

incorporated by reference in Section

218.112 of this Part.

iv) ASTN 

D4017—81(1987): Standard test

method for water content in paints and

paint materials by the Karl Fischer

method. This test method is incorporated

by reference in Section 218.112 of this

Part.

v)  ASTN D4457-85: Standard test method for

determination of dichioromethane and

1,1,1, trichioroethane in paints and

coatings by direct injection into a gas

chromatograph. (The procedure

delineated above can be used to develop

protocols for any compounds specifically

exempted from the definition of VON.)

This test method is incorporated by

reference in Section 218.112 of this

Part.

vi) ASTM D2697-86: Standard test method for

volume non—volatile matter in clear or

pigmented coatings. This test method is

incorporated by reference in Section

218.112 of this Part.

vii) ASTN D3980-87: Standard practice for

interlaboratory testing of paint and

related materials. This practice is

incorporated by reference in Section

218.112 of this Part.

viii)ASTN E180-85: Standard practice for

determining the precision data of ASTM

methods for 

analysis of and testing of

industrial chemicals. This practice is

incorporated by reference in Section

218.112

of this Part.

ix) ASTN D2372—85: Standard method of

separation of vehicle from solvent—

reducible paints. This method is

161

incorporated by reference in Section

218.112 of this Part.

D)  Use of an adaptation to any of the analytical

methods specified in subsections (a) (2) (A),

(B), and (C) of this Section may not be used

unless approved by the Agency

and USEPA. An

owner or operator must submit sufficient

documentation for the Agency and USEPA to

find that the analytical methods 

specified in

subsections (a) (2) (A), (B), and (C) of this

Section will yield inaccurate results and

that the proposed adaptation is appropriate.

3)  Calculations: Calculations for determining 

the

VON content, water content and the content of any

compounds which are specifically exempted from the

definition of VON of coatings, inks and fountain

solutions as applied shall follow the guidance

provided in the following documents-a-i

“A Guide for Surface Coating Calculation”,

EPA-340/1-86-016, incorporated by reference

in Section 218.112 of this Part.

B)  “Procedures for Certifying Quantity of

Volatile Organic Compounds Emitted by Paint,

Ink and Other Coatings” (revised June 1986),

EPA-450/3-84-019, incorporated by reference

in Section 218.112 of this Part.

“A Guide for Graphic

Arts 

Calculations”,

August 1988, EPA-340/l—88-003, incorporated

by reference in Section 218.112

of this Part.

b) Automobile

or Light-Duty Truck Test Protocol

The protocol

for testing, including determining

the transfer efficiency,- of coating applicators~

at primer surfacer operations and topcoat coating

operations at an automobile or lictht-duty truck

assembly facility source shall follow the

procedures in:”Protocol for Determining the Daily

Volatile Organic Compound Emission Rate of

Automobile and Light-Duty Truck Topcoat

Operations” (“topcoat protocol”), December 1988,

EPA-450/3-88-018, incorporated by reference in

Section 218.112 of this Part.

~j Prior to testing pursuant to the topcoat protocol.

the owner or operator of

a coating operation

sub-lect to the topcoat or primer surfacer limit in

162

Sections 218.204(a) (2) or 218.204(a) (3) shall

submit a detailed testing mro~osa1 specifying the

method by which testing will be conducted and how

compliance will be demonstrated consistent with

the topcoat protocol.

The proposal shall include.

at a minimum, p 

comprehensive plan (including a

rationale) for determining

the

transfer efficiencY

at each booth through the use of in—~1antor pilot

testing, the selection of coatings to be tested

(for the purpose 

of determining transfer

efficiency) including the rationale for coating

groupings. the method for determining the analytic

VON content of as a~~liedcoatings and 

the

formulation solvent content of as applied

coatings, and a description of the records of

coating 

VON content as applied and coatino’s usaae

which will be kent to demonstrate compliance.

UPon a~~rovalof the ~ro~osal by the Agency and

LJSEPA. the compliance demonstration for a coating

line may proceed.

c)  Capture System Efficiency Test Protocols

1)  Applicability

The requirements of subsection (c) (2) of this

Section shall apply to all VON emitting processes

emission units employing capture equipment (e.g.,

hoods, ducts), except those cases noted below.

A)  If an oourcc instaliseinission unit is

equipped with (or uses) a permanent total

enclosure (PTE) that meets Agency and USEPA

specifications, and which directs all VON to

a control device, then the sourocemission

unit is exempted from the requirements

described in subsection (c) (2) of this

Section. The Agency and USEPA specifications

to determine whether a structure is

considered a

PTE

are given in Procedure T of

Appendix B of this Part. In this 

instance,

the capture efficiency is assumed to be 100

percent and the sourceemission unit is still

required to measure control efficiency using

appropriate test methods as specified in

subsection (d) of this Section.

B)  If a~oourcc upesemission unit is equipped

with (or uses) uses a control device designed

to collect and recover VON (e.g., carbon

adsorber), an explicit measurement of capture

efficiency is not necessary provided that the

163

conditions given below are met. The overall

control of the system can be determined by

directly comparing the input liquid VON to

the recovered liquid VON. The general

procedure for use in this situation is given

in 40 CFR 60.433, incorporated by reference

in Section 218.112 of this Part, with the

following additional restrictions:

The source must be able to

cquacc

solvent usage with solvent reoovery on -a

24-hour (daily)—basirs, rather than a

30-day weighted average, within

72

hours

following the 24 hour 

period. 

In

addition, one of the following two

criteria must be mets Unless otherwise

specified in subsection (c) (1) (B) 

(ii)

below, the owner or operator shall

obtain data each operating daY for the

solvent usage and solvent recovery to

permit the determination of the solvent

recovery efficiency of the system each

operating day using a 7—day rolling

period. The recovery efficiency for

each operating day is computed as the

ratio of the total recovered solvent for

that day and the most recent prior 6

operating days to the total solvent

usage for the same 7-day period used for

the recovered solvent, rather than 

p

30-

day weighted average as given in 40 CFR

60.433 incorporated by reference at

Section 218.112 of this Part. This

ratio shall be expressed as a

percentage. The ratio shall be computed

within 72 hours following each 7-day

period. A source that believes that the

7-day rolling period is not appropriate

may use an alternative multi—day rolling

period not to exceed 

30 days. with the

aPproval of the Agency and USEPA. In

addition. the criteria in subsection

(c)_(1) (B) (iii) or subsection

(C) (1) (B) (iv) below must be met.

£jI The owner or operator of the source

en~a~edj~printing located at 350 E.

22nd Street. Chicago. Illinois. shall

obtain data each operatin~day for the

solvent usage and solvent recovery to

permit the determination of the solvent

recovery efficiency of the system each

164

operating day using a 14—day rolling

period. The recovery efficiency for

each operating day is computed as the

ratio of the total recovered solvent for

that day and the most recent prior 13

operating days to the total solvent

usage for the same 14-day period used

for the recovered solvent, rather than a

30-day weighted average

as given in 40

CER 60.433. incorporated by reference

in

Section 218.112 of this Part. This

ratio shall be expressed as a

percentage. The ratio shall be computed

within 17 dave following each 

14-day

period. In addition, the criteria in

subsection (c) 

(1) (B) (iii) or subsection

(C) (1) (B) (iv) below must be 

met.

44~3-iii) The solvent recovery system (i.e.,

capture and control system) must be

dedicated to a single coating

line.

printin~ line, or other discrete

activity that by itself is subiect to an

applicable VON emission standard,

process line (e.g., one process line

vcnting to

a carbon adsorbcr system), or

iii)jyj.. If the solvent recovery system controls

more than one coating line. printing

line or other discrete activity that by

itself is subiect to an applicable VON

emission standard, the overall control

Xie. the total recovered VOM divided by

the sum of liquid VON input from all

lines and other activities venting to

the control system) must meet or exceed

the most stringent standard applicable

to any line or other discrete activity

venting to the control system.multiplc

rrppcsp 

lines, then the source must be

a~c ~o ~icmonstratc tnat tnc ov’~’’

control (i.e 

•

,thc total recovered

solvent VOM divided by the sum of liquid

VON input to all proecs~lines venting

to the control system) meets or e~ooods

the most stringent standard applicable

for any process line venting to the

control system.

165

2) Specific

Requirements

The capture efficiency of a~p~eeese—~M~eemjs~s.iQn

unit shall be measured using one of the four

protocols given below. 

Any

error margin

associated with a test protocol may not be

incorporated into the results of a capture

efficiency test. If these techniques are not

suitable for a particular process, then 

the ciourso

may use an alternative capture efficiency protocol

may be used, provided that the alternative

protocol is approved by the Agency and approved by

the USEPA as a SIP revision.

A)  Gas/gas method using temporary total

enclosure (TTE). The Agency and USEPA

specifications to determine whether a

temporary enclosure is considered a TTE are

given in Procedure T of Appendix B of this

Part. The capture efficiency equation to be

used for this protocol is:

CE

=

Gw/(Gw + Fw)

where:

Qeapture efficiency, decimal

fraction~

=

i~mass of VON 

captured and delivered

to control device using a TTE~

=

amass of fugitive

VOM that escapes

from a TTE.

Procedure G.2 contained in Appendix B of this

Part is used to obtain Gw. Procedure F.1 in

Appendix B of this Part is used to obtain Fw.

B)  Liquid/gas method using TTE. The Agency and

USEPA specifications to determine whether a

temporary enclosure is considered a TTE 

are

given in Procedure T of Appendix B of this

Part. The capture 

efficiency equation to be

used for this protocol is:

CE

=

(L

Fw)/L

where:

CE

=

çeapture efficiency, decimal

fracti on~

166

L

=

~sass of liquid VOM input to

process emission unit

Fw

=

~mass of fugitive VON that escapes

from a TTE.~..

Procedure L contained in Appendix 

of this

Part is used to obtain L. Procedure F.3. in

Appendix B of this Part is used to obtain Fw.

C)  Gas/gas method using the building or room

(building or room enclosure)~.in which the

affected coating line. printing line or other

acuroceinission unit is located,,, as the

enclosure and in which 

“F” 

and “G”

are

measured while operating only the affected

line or facilitycmission unit. All fans and

blowers in the building or room must be

operated as they would under normal

production. The capture efficiency equation

to be used for this protocol is:

CE

=

G/(G + FB)

where:

CE

Qeapture efficiency, decimal

tract ionj..

G

=

~mass of VON captured and delivered

to control devicej.

FB

=  ~mass of 

fugitive VOM that escapes

from building enc1osure~

Procedure G.2 contained in Appendix B of this

Part is used to obtain G. Procedure F.2 in

Appendix B of this Part is used to obtain FB.

D)  Liquid/gas method using the building or room

(building or room enclosure)~in which the

affected coating line, printing line or other

oourcceinission unit is located,~as the

enclosure and in which “F” and “L” are

measured while operating only the affected

line or facilitycmission unit. All fans and

blowers in the building or room must be

operated as they would under normal

production. The capture efficiency equation

to be used for this protocol is:

167

CE

=

(L

—

FB)/L

where:

CE

=

~eapture efficiency, decimal

fractionj

L =  amass of liquid VON input to

process emission unit

FB

=

I.~mass of fugitive VON that escapes

from building enclosure~

Procedure L contained in Appendix B of this

Part is used to obtain L. Procedure F.2 in

Appendix B of this Part is used to obtain FB.

3)  Recordkeeping and Reporting

All affected facilitiesowners

or operators

affected bY this subsection must maintain a

copy of the capture efficiency protocol

submitted to the Agency and the USEPA on

file. All results of the appropriate test

methods and capture efficiency protocols must

be reported to the Agency within sixty (60)

days of the test date. A copy of the results

must be kept on tile with the source for a

period of three (3) years.

B)  If any changes are made to capture or control

equipment, then the source is required to

notify the Agency and the USEPA of these

changes and a new test may be required by the

Agency or the USEPA.

C)  The source must notify the Agency 30 days

prior to performing any capture efficiency or

control test. At that time, the source must

notify the Agency which capture efficiency

protocol and control device test methods will

be used.

D)  Sources utilizing a PTE must demonstrate that

this enclosure meets the requirement given in

Procedure T (in Appendix B of this Part) for

a PTE during any testing of their

control

device

168

E)  Sources utilizing a TTE must demonstrate that

their TTE meets the

requirements given in

Procedure T (in Appendix B of

this Part) for

a TTE during testing of their control device.

The source must also provide documentation

that the

quality assurance criteria for a 

TTE

have been achieved.

d)  Control Device Efficiency Testing and Monitoring

The control device efficiency shall be determined

by simultaneously measuring the inlet and outlet

gas phase VON concentrations and gas volumetric

flow rates in accordance with 

the

gas

phase

test

methods specified in subsection

(f) of this

Section.

2)  Any owner or operator~

~j 4~hatuses an afterburner or carbon adsorber

to comply with any Section of this Part 

Zl~.

shall use Agency and USEPA approved

continuous monitoring equipment which is

installed, calibrated, maintained,- and

operated according to vendor specifications

at all times the afterburner or carbon

adsorber is in use except as provided in

subsection (d) (3) of this Section. The

continuous monitoring equipment must monitor

the following parameters:

?~-)-

j) For each afterburner which does not have

a catalyst bed, the G~ombustionchamber

temperature 

of each afterburner.

£~J

For each afterburner which has a

catalyst bed. commonly known as a

catalytic afterburner, the ~P~emperature

rise across each catalytic afterburner

bed or VON concentration of exhaust.

~-      iii) For each carbon adsorber. c~heVON

concentration of each carbon adsorption

bed exhaust or the exhaust of the bed

next in sequence to be desorbed.

Of an automobile or light-duty 

truck primer

surfacer operation or topcoat operation

subiect to subsection (d) (2) (A) above, shall

keep a separate record of the following data

for the control devices, unless alternative

169

provisions are set forth in a Permit pursuant

to Title V of the Clean Air Act:

j)~. For 

thermal afterburners for which

combustion chamber temperature is

monitorech all 3—hour periods of

operation in which the average

combustion temperature was more 

than

28°C (50°F) below the averaae combustion

temperature measured durina the most

recent performance test that

demonstrated that the operation was in

compliance

iii

For catalytic afterburners for which

temperature rise is monitored. all

3-hour periods of operation in which the

average gas

temperature before the

catalyst bed is more than 28°C (50°F)

below the average 

gp~

temperature

immediately before the catalyst bed

measured during the most recent

performance test that demonstrated that

the operation was in compliance.

iii) For catalytic afterburners and carbon

adsorbers for which VON concentration is

monitored. all 3-hour periods of

operation during which the averaae VOM

concentration or the reading of organics

in the exhaust aases is more than 20

percent greater than the average exhaust

gas concentration or reading measured by

the organic monitoring device during the

most

recent determination of the

recovery efficiency of a carbon adsorber

or performance test for a catalytic

afterburner, which determination or test

demonstrated that the operation was in

compliance.

An owner or operator that uses a carbon adsorber

to com~1vwith Section 218.401 of this Part may

oPerate the adsorber during periods of monitoring

eaui~mentmalfunction, provided that:

~j The owner or oPerator notifies in writing the

Agency and USEPA within, 10 days after the

conclusion of any 72 hour period during which

the adsorber is operated and the associated

monitoring equipment is not operational, of

such monitoring equipment failure and

170

provides the duration of the malfunction, a

description of the repairs made to the

equipment, and the total to date of all hours

in the calendar year during which the

adsorber was operated and the associated

monitoring equipment was not operational

~j During such period of malfunction the

adsorber is operated using timed geguences as

the basis for periodic reaeneration of the

adsorber

~j The period of such adsorber operation does

not exceed 360 hours 

in any calendar year

without the approval of the Agency and USEPA

and

~  The total of all hours in the calendar year

during which the adsorber was operated and

the associated monitoring equipment was not

operational shall be reported, in writing, to

the Agency and USEPA by January 31st of the

following calendar year.

e)  Overall Efficiency

1)

The overall efficiency of the emission control

system shall be determined as the product of the

capture system efficiency and the control device

efficiency or by the liquid/liquid test protocol

as specified in 40 CFR 60.433, incorporated by

reference in Section 218.112 of this Part, (and

revised by subsection (C) (1) (B) of this Section)

for each solvent recovery system.

In those cases

in which the overall efficiency is being

determined for an entire line, the capture

efficiency used to calculate the product of the

capture and control efficiency is the total

capture efficiency over the entire line.

For coating lines which are both chosen by the

owner or operator 

to comply with Section

218.207~a-)-j~j,(d), (e), (f), or (g) of this Part

by the alternative in Section 218.207(b) (2) ~

this Part and meet the criteria allowing them to

comply with Section 218.207 of this Part instead

of Section 

218.204 of this Part, the 

overall

efficiency of the capture system and control

device, as determined by the test methods arid

procedures specified in subsections (C), (d) and

(e) (1) of this Section, shall be 

no less than the

171

equivalent overall efficiency which shall be

calculated by the following equation:

E  =  (VONa 

VON1) /VOMa)X 100

where:

=

Equivalent overall efficiency of

the

capture system and control device as a

percentage-1-,j.

VONa 

=

Actual VON 

content of a coating, or the

daily-weighted average VON content of

two or more coatings (if more than one

coating is used), as applied to the

subject coating line as determined by

the applicable test methods and

procedures specified in subsection (a)

of this Section in units of kg VON/i

(lb VON/gal) of coating solids as

appl ied~j..

VOH~1= The VON emission limit specified in

Section.~216.207(a) or (b) 218.204 or

218.205 of this Part in units of kg

VON/i (lb VON/gal) of coating solids as

applied

f)  Volatile Organic Material Gas Phase Source Test Methods

The methods in 40 CFR Part 60, Appendix A, incorporated

by reference in Section 218.112 of this Part delineated

below shall be used to determine control device

efficiencies

1)  40 CFR Part 60, Appendix A, Method 18, 25 or 25A,

incorporated by reference in Section 218.112 ~

this Part as appropriate to the conditions at the

site, shall be used to determine VON

concentration. Method selection shall be based on

consideration of the diversity of organic species

present and their total concentration and on

consideration of the potential presence of

interfering gases. Except as indicated in

subsections (f) (1) (A) and (B) below, the test

shall consist of three 

separate runs, each lasting

a minimum of 60 mm, unless the Agency and the

USEPA determine that process variables dictate

shorter sampling times.

172

When the method is 

to be used to determine

the efficiency of a carbon adsorption system

with a common exhaust stack for all the

individual adsorber vessels,

the test shall

consist of three separate 

runs, 

each

coinciding with one or more complete

sequences 

through the adsorption cycles of

all the individual adsorber vessels.

B)  When the method is to be used to determine

the efficiency 

of a carbon adsorption system

with individual exhaust stacks for each

adsorber vessel, each adsorber vessel shall

be tested individually. The test for each

adsorber vessel shall consist of three

separate runs. Each run shall coincide with

one or more complete adsorption cycles.

2)  40 CFR Part 60, Appendix A, Method 1 or 1A,

incorporated by reference in Section 218.112 Q~.

this Part, shall be used for sample and velocity

traverses.

3)  40 CFR Part 60, Appendix A, Method 2, 2A, 2C or

2D, incorporated by reference in Section 218.112

of this Part, shall be used for velocity and

volumetric flow rates.

4)

40 CFR Part 60, Appendix A, Method 3, incorporated

by reference in Section 218.112 of this Part,

shall be used for gas analysis.

5)  40 CFR Part 60, Appendix A, Method 4, incorporated

by reference in Section 218.112 of this Part,

shall be used for stack gas moisture.

6)  40 CFR Part 60, Appendix A, Methods 2, 2A, 2C, 2D,

3 and 4, incorporated by reference in Section

218.112 of this Part, shall be performed, as

applicable, at least twice during each test run.

7)  Use of an adaptation to any of the test methods

specified in subsections (f) (1), (2), (3), (4),

(5) and (6) of this Section may not be used unless

approved by the Agency and the USEPA on 

a case by

case basis. An owner or operator must submit

sufficient documentation for the Agency and the

USEPA to find that the test methods specified in

subsections (f)(1), (2), (3), (4), (5) and (6) ~

this Section will yield inaccurate results and

that the proposed adaptation is appropriate.

173

g)  Leak Detection Methods for Volatile Organic Material

Owners or operators required 

by this Part to carry out

a leak detection monitoring program shall comply with

the following requirements:

1)  Leak Detection Monitoring

A)  Monitoring shall comply with 40 CFR 60,

Appendix A, Method 21, incorporated by

reference in Section 218.112 of this Part.

B)  The detection instrument shall meet the

performance criteria of Method 21.

C)  The instrument shall be calibrated before use

on each day of its use by the methods

specified in Method 21.

D)  Calibration gases shall be:

i)  Zero air (less than lOppm of hydrocarbon

in air); and

ii) A mixture of methane or n—hexane and air

at a concentration of approximately, but

no less than, 10,000 ppm methane or

n-hexane.

E) The instrument

probe shall be traversed

around all potential leak interfaces as close

to the interface as possible as described in

Method 21.

2)  When equipment is tested for compliance with no

detectable emissions as required, the test shall

comply with the following requirements:

A)  The requirements of subsections (g) (1) (A)

through (g) (1) (E) of 

this Section above shall

apply.

The background level shall be determined as

set forth in Method 21.

3)  Leak detection tests shall be performed consistent

with:

A)

“APTI Course SI

417 controlling Volatile

Organic Compound Emissions from Leaking

Process Equipment”, EPA—450/2—82—015,

174

incorporated by reference in Section 218.112

of this Part.

B)  “Portable Instrument User’s Manual for

Monitoring VOC Sources”, EPA—340/1—86-015,

incorporated by reference in Section 218.112

of this Part.

“Protocols for Generating Unit-Specific

Emission Estimates for Equipment

Leaks 

of VOC

and VHAP”, EPA-450/3—88-010, incorporated by

reference in Section 218.112 of this Part.

D)

“Petroleum Refinery Enforcement Manual”,

EPA-340/l-80-008, incorporated by reference

in Section 213.122218.112 of this Part.

h)  Bulk Gasoline Delivery System Test Protocol

1)  The method for determining the emissions of

gasoline from a vapor recovery system are

delineated in 40 CFR 60, Subpart XX, Section

60.503, incorporated by reference in Section

218.112 of this Part.

2)  Other tests shall be performed consistent with:

A)  “Inspection Manual for Control of Volatile

Organic Emissions from Gasoline Marketing

Operations: Appendix D”, EPA—340/1—80-0l2,

incorporated by reference in Section 218.112

of this Part.

B)  “Control of Hydrocarbons from Tank Truck

Gasoline Loading Terminals: Appendix A”,

EPA-450/2-77-026, incorporated by reference

in Section 218.112 of this Part.

1)  Notwithstanding other requirements of this Part, upon

request of the Agency where it 

is necessary to

demonstrate compliance, an owner or operator of an

emission oourcc unit which is subject to this Part

shall, 

at his own expense, conduct tests in accordance

with the applicable test methods and procedures

specific in this Part. Nothing in this Section shall

limit the authority of the LISEPA pursuant to the Clean

Air Act, as amended, to require testing.

jj.  Stage II Gasoline Vapor Recovery Test Methods

The methods for determining the acce~tab1eperformance

of Staae II Gasoline Vapor Recovery System are

175

delineated in “Technical Guidance—Stage II Vapor

RecoverY Systems for Control of Vehicle Refueling

Emissions at Gasoline Dispensing Facilities.” found at

EPA 450/3-91-022b and incorporated by reference in

Section 218.112 of this Part. S~ecifica1ly. the test

methods are as follows:

Dynamic Back~ressureTest is a test procedure used

to determine the pressure drop (flow resistance)

throuah balance vapor collection and control

systems (including nozzles. vapor hoses. swivels.

dispenser ~ipina. and underground ~ipina) 

prescribed flow rates.

Pressure Decay/Leak Test is a test procedure used

to quantify the vapor tightness of a vapor

collection and control system installed at

gasoline dispensing facilities.

Liquid Blockaae Test is a test procedure used to

detect low points in any vapor collection and

control system where condensate maY accumulate.

(Source:

Amended at

—

Ill. Reg.

______,

effective 

____________

Section 218.106  

Compliance Dates

a)  Compliance with the requirements of all rules is

required by July, 1991, or September 1, 1991, for all

sources located in Cook, DuPage, Kane, Lake, McHenry or

Will Counties, consistent with the appropriate

provisions of Section 218.103 of this Part.

b)  Compliance with the requirements of this Part is

required by November 15, 1993, for all sources located

in Aux Sable Township or Goose Lake Township in Grundy

County or in Oswego Township in Kendall County.

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

____________

______________________)

Section 218.107  

Operation of Afterburners

The operation of any natural gas fired afterburner and capture

system used to comply with this Part is not required during the

period of November 1 of any year to April 1 of 

the following year

provided that the operation of such devices is not required for

purposes of occupational safety or health, or for the control of

toxic substances, odor nuisances, or other regulated pollutants.

176

(Source: A.mended at 

—

Ill. Reg.    

effective 

_________

_____________________ )

Section

218.109  

Vapor Pressure of Volatile Organic Liquids

a)  If the VOL 

consists of only a single compound, the

vapor pressure shall be determined by ASTM Method

D2879-86 (incorporated by reference in Section 218.112

of this Part) or the vapor pressure may be obtained

from a publiohcd oourccpublicatipri such as: Boublik,

T., V. Fried and E. Hala, “The Vapor Pressure of

Pure

Substances,” Elsevier Scientific Publishing Co., New

York (1973); Perry’s Chemical Engineer’s 

Handbook,

McGraw-Hill Book Company (1984); CRC Handbook of

Chemistry and Physics, Chemical Rubber Publishing

Company (1986-87); and Lange’s Handbook of Chemistry,

John A. Dean, editor, McGraw-Hill Book Company (1985).

b)  If the VOL is a mixture, the vapor pressure shall be

determined by ASTM Method D2879-86 (incorporated by

reference in Section 218.112) or by the following

equation:

n

~vor

E Pj Xj

1=1

where:

~vol 

=

Total vapor pressure of the mixture,-~.

n

=

Number of components in the mixture,-~

i

=

Subscript denoting an individual

component-,-~

~1

=

Vapor pressure of a component determined

in accordance with Cubpart A of thit~

t’~artsubsection (a) of this Section

Xl

=

Mole fraction of 

the

component in the

total mixture.

(Source: Amended at 

—

Ill. Reg. 

_____,

effective 

_____________

Section 218.110  

Vapor Pressure of Organic Material or Solvent

a)  If the organic material or solvent consists 

of only a

single compound, the vapor pressure shall be determined

by ASTN Method D2879-86 (incorporated by reference in

177

Section 218.112 of this Part) or the vapor pressure may

be obtained from a publiohcd couroc publication such

as: Boublik, T., V. Fried and E. Hala, “The Vapor

Pressure of Pure Substances,” Elsevier Scientific

Publishing Co., New York (1973); Perry’s Chemical

Engineer’s Handbook, McGraw-Hill Book Company (1984);

CRC Handbook of Chemistry and Physics, Chemical 

Rubber

Publishing Company (1986—87); and Lange’s Handbook of

Chemistry, John A. Dean, editor, McGraw-Hill Book

Company (1985).

b)  If the organic material or solvent is in a mixture made

up of both organic material compounds and compounds

which are not organic material, the vapor pressure

shall be determined by the following equation:

Ti

PiXi

Pvoin    

=

1=1

n

Xi

i=1

where:

~om

Total vapor pressure of the portion of

the mixture which is composed of organic

n

Numbermateria1of7~organic material components in

the mixture-a.

I

Subscript denoting an individual

componentrj...

Pj

Vapor pressure of an organic material

component determined in accordance with

Gubpart A of thi3 rart subsection (a) of

this Section7j

Mole fraction of the organic material

component of

the

total mixture.

c)  If the organic material or solvent is in a mixture 

made

up of only organic material compounds, the vapor

pressure shall be determined by ASTM Method D2879-86

(incorporated by reference in Section 218.112 of this

Part) or by the above equation.

(Source: Amended at —  

Ill. Reg.

______,

effective 

__________

______________________)

178

Section 218.111  

Vapor Pressure of Volatile Organic Material

a)  If the VON consists of only a single compound, the

vapor pressure shall be determined by ASTM Method

D2879-86 (incorporated by reference in Section 218.112

of this Part) or the vapor pressure may be obtained

from a publichcd oourocpublication such as: Boub.ik,

T., V. Fried and E. Hala, “The Vapor Pressure of 

Pure

Substances,” Elsevier Scientific Publishing Co., New

York (1973); Perry’s Chemical Engineer’s Handbook,

McGraw-Hill Book Company (1984); CRC Handbook of

Chemistry and Physics, Chemical Rubber Publishing

Company (1986-87); and

Lange’s Handbook of Chemistry,

John 

A. Dean, editor, McGraw-Hill 

Book Company (1985).

b)  If the VON is in a mixture made up of both VON

compounds and compounds which are not VON, the vapor

pressure shall be determined by the following equation:

Ti

E

PiXj

~vonf  

i=1

n

E

i=1

where:

~voin

Total vapor pressure of the portion of

the mixture which is composed of

VOM~1.

n

Number of VON components in the

mixture,-2.

I

Subscript denoting an individual

componentT~

Vapor pressure of a VON component

determined in accordance with Cubp~rt A

of this Part subsection (a) of this

Section,-~

Mole fraction of the VON component of

the total mixture.

c)  If the VON is in a mixture made up of only VON

compounds, the vapor pressure shall be determined by

ASTM Method D2879-86 (incorporated by reference in

Section 218.112 of this Part) or by the above

equation.

179

(Source: Amended at  

Ill. Reg. 

______,

effective 

__________

______________________ )

Section 218.112  

Incorporations by Reference

The following materials are incorporated by reference and do not

contain any subsequent additions or amendments:

a)  American Society for Testing and Materials, 1916 Race

Street, Philadelphia, PA 19103:

1)  ASTM D2879—86

2)  ASTM D323—82

3)  ASTM D86—82

4)  ASTM D—369—69 (1971)

5)  ASTN D—396—69

6)  ASTM D2880—71

7)  ASTM D—975—68

8)  ASTN D3925—8l (1985)

9)  ASTM E300—86

10) ASTM D1475—85

11) ASTM D2369—87

12) ASTN D3792—86

13) ASTN 

D4017—81 (1987)

14) ASTN 

D4457—85

15) ASTM D2697—86

16) ASTN D3980—87

17) ASTN 

E180—85

18) ASTN D2372—85

19) ASTM D97—66

20) ASTN E—168—67 (1977)

21) ASTN E—169~2.

22) ASTM E—260~j,

23) ASTM D2504—83

24) ASTN D2382—83

2~1

ASTM D323-82 (approved 1982)

b)  Standard Industrial Classification Manual, published by

Executive Office of the President, Office of

Management

and Budget, Washington, D.C., 1987.

c)  American Petroleum Institute Bulletin 2517,

“Evaporation Loss From Floating Roof Tanks”, Second

ed., February, 1980.

d) 40 CFR Part 60 (July

1, 19901991) and 40 

CFR

60.

Appendix A. Method 24 (57 FR 30654. July 10, 

1992).

40 CFR Part 61 (July 1,

1-9-9-01991).

f)  40 CFR Part 50 (July 1, 19891991).

180

g)  40 CFR Part 51 (July 1, 19891991).

h)  40 

CFR

Part 52 (July 1, 19391991).

40

CFR

Part 80 (July 1. 1991).

#)-j~“A Guide for Surface Coating Calculation”, United

States Environmental Protection Agency, Washington,

D.C., EPA—340/l—86—016.

*lcI

“Procedures for Certifying Quantity of Volatile Organic

Compounds Emitted by Paint, Ink and Other Coating”.

(revised June 1986). United States Environmental

Protection Agency, Washington D.C., EPA—450/3—84—019.

k-)-fl

“A Guide for Graphic Arts Calculations”. Au~st 1988~.

United States Environmental Protection Agency,

Washington D.C., EPA—340/l—88—003.

.1-)-~j “Protocol for Determining the Daily Volatile Organic

Compound Emission Rate of Automobile and Light-Duty

Truck Topcoat Operations”. December 1988. United States

Environmental Protection Agency, Washington D.C.,

EPA—450/3—88—018.

~3-flj“Control of Volatile Organic Emissions from

Manufacturing of Synthesized Pharmaceutical Products”.

United States Environmental Protection Agency,

Washington, D.C., EPA—450/2—78—029.

*~3-~j“Control of Volatile Organic Compound Leaks from

Gasoline Tank Trucks and Vapor Collection Systems”.

Appendix B. United States Environmental Protection

Agency, Washington, D.C., EPA-450/2—78-051.

e3-pj “Control of Volatile Organic Compound Emissions from

Large Petroleum Dry Cleaners”. United States

Environmental Protection Agency, Washington, D.C.,

EPA—450/3—82—009.

~ “APTI

Course S1417 Controlling Volatile Organic

Compound Emissions from Leaking Process Equipment”.

United States Environmental Protection Agency.

Washington. D.C.. EPA—450/2—82—015.

~j “Portable Instrument User’s Manual for Monitoring VOC

Sources”. United States Environmental Protection

Aaencv. Washington. D.C.. EPA—340/1—86—015.

~j. “Protocols for Generating Unit—Specific Emission

Estimates for Equipment Leaks of VOC and VHAP”. United

181

States Environmental Protection Agency. Washington~

D.C.. EPA—450/3—88—010.

~j “Petroleum Refinery Enforcement Manual”. United States

Environmental Protection Agency, Washington. D.C..

EPA—340/1—80—008.

j~ “Inspection Manual for Control of Volatile oraanic

Emissions from Gasoline Marketing Operations: A~~endix

D”. United States Environmental Protection Agency.

Washington. D.C.. EPA—340/1—80—012.

“Control of Hydrocarbons from Tank 

Truck Gasoline

Loading Terminals: Appendix A”. United States

Environmental Protection Agency. Washington. D.C..

EPA—450/2—77—026.

~  “Technical Guidance-Stage II Vapor Recovery Systems for

Control of Vehicle Refueling Emissions at Gasoline

Dispensing Facilities”. United States Environmental

Protection Agency. Washington. D.C.. EPA—450/3—91-022b.

~j California Air Resources Board. Compliance Division.

Compliance Assistance Program: Gasoline Marketing and

Distribution: Gasoline Facilities Phase I & II

(October 1988, rev. March 1991) (CARB Manual).

(Source: Amended at 

—

Ill. Reg.    

effective 

____________

_________________________ )

SUBPART

B: ORGANIC EMISSIONS FROM STORAGE AND LOADING OPERATIONS

Section 218.121  

Storage Containers

No person shall cause or allow the storage of any VOL with a

vapor pressure of 17.24 kPa (2.5 psia) or greater at 294.3~K

(70°F) or any gaseous organic material in any stationary tank,

reservoir or other container of more than 151 cubic meters

(40,000 gal) capacity unless such tank, reservoir or other

container:

a)  Is a pressure 

tank capable of withstanding 

the

vapor

pressure of such liquid or the pressure of the gas, so

as to prevent vapor or gas loss to the atmosphere at

all times; or,

b)  Is designed and equipped with one of the following

vapor loss control devices:

1)  A floating roof which rests on the surface of the

VOL and

is equipped with a closure seal or seals

between the roof edge and the tank wall. Such

182

floating roof shall not be permitted if the 

VOL

has a vapor pressure of 86.19 

kPa

(12.5 psia) or

greater at 294.3 °K (70°F).

No person shall cause

or allow the emission of air contaminants into the

atmosphere from any gauging or sampling devices

attached to such tanks, except during sampling or

maintenance operations.

A vapor recovery system consisting of:

A vapor gathering system capable of

collecting 85 or more of the uncontrolled

VON that would be otherwise

emitted to the

atmosphere; and,

B)  A vapor disposal system capable of processing

such VON so as to 

prevent its emission to the

atmosphere. No person shall cause or allow

the emission of air contaminants into the

atmosphere from any gauging or sampling

devices attached to such tank, reservoir or

other container except during sampling.

3)  Other equipment or means of equal efficiency

approved by the Agency according to the provisions

of 35 Ill. Ad.m. Code 201, and further processed

consistent with Section 218.108.

(Source: Amended at 

—

Ill. Reg.

______,

effective 

____________

______________________ )

Section 218.122  

Loading Operations

a) No

person shall cause or allow the discharge of more

than 3.6 kg/hr (8 lbs/hr) of organic material into the

atmosphere during the loading of any organic material

from the aggregate loading pipes of any loading

facility area having through-put of greater than 151

cubic meters per day (40,000 gal/day) 

into any railroad

tank car, tank truck or trailer

unless 

such loading

facilityarea is equipped with 

submerged loading pipes-,-

eubmorgod fill or a device that is equally effective in

controlling emissions and

is approved by the Agency

according to the provisions of 35 Ill.

Adm. 

Code 201,

and further

processed consistent with Section 218.108.

b)  No person shall cause or allow the loading of any

organic material into any stationary tank having a

storage capacity of greater than 946 1 (250 gal),

unless such tank is equipped with a permanent submerged

loading pipe, oubmcrgcd fill or an equivalent device

approved by the Agency according to the provisions of

183

35 Ill. Adm. Code

201, and further processed

consistent

with Section 218.108 of this Part, or unless such tank

is a pressure tank as described

in Section 218.121(a)

of this Part or is fitted with a 

recovery system as

described in Section 218.121(b) (2) of this Part.

c)  Exception: If no odor nuisance exists the 

limitations

of this Section shall only apply to 

the loading of VOL

with a vapor pressure of 17.24 kPa (2.5 psia) or

greater at 294.3°K (70°F).

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

____________

____________________)

Section 218.123  

Petroleum Liquid Storage Tanks

a)  The requirements of subsection 

(b) of this Section

shall not apply to any stationary storage tank:

1)  Equipped before January 1, 1979 with one of the

vapor loss control devices specified in Section

218.121(b) of this Part, except Section

218.121(b) (1) of this Part

2)  With a capacity of less than 151.42 cubic meters

(40,000 gal);

3)  With a capacity of less than 1,600 cubic meters

(422,400 gal) and used to store produced crude oil

and condensate prior to custody transfer;

With a capacity of less than 1,430 cubic meters

(378,000 gal) and used to store produced oil or

condensate in crude oil gathering;

5)  Subject to new source performance standards for

storage vessels of petroleum liquid, ~5 Ill. Adm.

Codc 230 40 CFR 60. as regulations ~romulaated by

the US. Environmental Protection Aaency under

Section lii. of the Clean Air Act (42 USC 7411). as

amended. THE PROVISIONS OF SECTION 111 OF ThE

CLEAN

AIR ACT 

...

ARE APPLICABLE 

IN ThIS STATE

AND

ARE ENFORCEABLE UNDER ITHE ENVIRONMENTAL

PROTECTION ACT1 (Ill. Rev. Stat. 

1991. ch. 111~.

Par. 1009.1(b)) 1415 ILCS 5/9.1(b)1

6)  In which volatile petroleum liquid 

is not stored;

or

7)  Which is a pressure tank as described in Section

218.121(a) of this Part.

184

b)  Subject to subsection (a) of this Section no owner or

operator of a stationary storage tank shall cause or

allow the storage of any volatile petroleum liquid in

the tank unless:

1)

The tank 

is equipped with one of the vapor loss

control devices specified in Section 218.121(b) ~

this Part

2)

There are no visible holes, tears or other defects

in the seal or any seal fabric or material of any

floating roof;

3) All openings of any

floating roof deck, except

stub drains, are equipped with covers, lids or

seals such that:

The cover, lid or seal is in the closed

position at all times except when petroleum

liquid is transferred to or from the tank;

B)  Automatic bleeder vents are closed at all

times except when the roof is floated off or

landed on the roof leg supports; and

C)  Rim vents, if provided, are set to open when

the roof is being floated off the roof leg

supports or at the manufacturer’s

recommended

setting;

4)  Routine inspections of floating roof seals are

conducted through roof hatches once every six

months;

5)  A complete inspection of the cover and seal of any

floating roof tank is made whenever the tank is

emptied for reasons other than the transfer of

petroleum liquid during the normal operation of

the tank, or whenever repairs are made as a result

of any semi—annual inspection

or incidence of roof

damage or defect; and

6)  A record of the results of each inspection

conducted under subsection (b) (4) or (b) (5) ~

this Section is maintained.

a)

Ounoro and oporatoro

01 pocroi.oum liquid storage 

tanks

were rcquired to havo compliance achedul

suinmari~edin Appendix C to 35 Ill 

Adm.

Coda 215.

(Source: Amended at 

—

Ill. Reg.    

effective 

____________

185

Section 218.124  

External Floating Roofs

a)  In addition to meeting the requirements of Section

218.123(b) of this Part, no owner or operator of a

stationary storage tank equipped with an external

floating roof shall cause or allow the storage of any

volatile petroleum liquid in the tank unless:

1)  The tank has been fitted~

With a continuous secondary seal extending

from the floating roof to the tank wall (rim

mounted secondary seal)~or

With 

aAny

other dcvioc which controla VON

emissiona with an 

effeotivenooc3 omia~ 

grcatcr than a 

riiu mounted acconuary

ocal;equipment or means of e~al efficiency

a~~rovedby the A~encv according to the

provisions of 35 Iii. Adm. Code 201. and

further processed consistent with Section

218.108 of this Part

2)  Each seal closure device meets the following

requirements:

A)  The seal is intact and uniformly in place

around the circumference of the floating roof

between the floating roof and tank wall; and

B)  The accumulated area of gaps exceeding 0.32

centimeter (1/8 inch) in width between the

secondary seal and the tank wall shall not

exceed 21.2 square centimeters per meter of

tank diameter (1.0 square inches per foot of

tank diameter). Compliance with this

reauirenient shall be determined by:

Physically measuring the length and

width of all gaps around the entire

circumference of the secondary seal in

each mlace where a 0.32 cm (0.125 in.)

uniform diameter probe passes freely

(without forcing or binding against the

seal) between the seal and the tank

wall: and

Summing 

the area

of the individual gaps.

3)  Emergency roof drains are provided with slotted

membrane fabric covers or equivalent covers across

at least 90 percent of the area of the opening;

186

4)  Openings are equipped with projections into the

tank 

which remain

below the liquid surface at all

times;

Inspections are conducted prior to May 1 of each

year to insure compliance with subsection (a) Q~

this Section

6)  The secondary seal gap is measured prior to May 1

of each year-t and within 30 days of a written

re~est to demonstrate compliance with subsection

(2) (B) of this Section

7)  Records of the types of 

volatile petroleum liquid

stored, the maximum true vapor pressure of the

liquid as stored, the results of the inspections

and the results

of the secondary seal gap

measurements are maintained and available to the

Agency, upon verbal or written request, at any

reasonable time for a minimum of two years after

the date on which the record was made.

b)  Subsection (a) above does not apply to any stationary

storage tank equipped with an external floating roof:

1)  Exempted under Section 218 

•

123 (a) (2) through

218.123(a) (6) of this Part

2)  Of welded construction equipped with a metallic

type shoe seal having a secondary seal from the

top of the shoe seal to the tank wall

(shoe—mounted secondary seal);

3)  Of welded construction equipped with a metallic

type shoe seal, a 

liquid—mounted foam seal, a

liquid-mounted liquid-filled-type seal, or other

closure device of equivalent control efficiency

approved by the Agency in which a petroleum liquid

with a true vapor pressure less than 

27.6 kPa (4.0

psia) at 294.3°K (70°F) 

is stored; or

4)  Used to store crude oil with a pour point of 50°F

or higher as determined by ASTM 

Standard D97-66

incorporated by reference in Section 218.112 ~

this Part.

(Source: Amended at 

—

Ill. Reg.    

effective 

___________

______________________)

Section 218.125  

Compliance Dates (Repealed)

187

Every owner or operator of an emission source

subject 

to 35 Ill.

Adin.

Code 

215, Subpart B, as of

December 

31, 1~)87 shall have

cemoliod with 

its standards and limitations by December 31, 1!~87.

(Source:

Repealed at

—

Ill. Reg.    

effective

___________

_____________________)

Section 218.126  

Compliance Plan (Repealed)

a)  The owner er operator -ef an 

emission

source 

previeuely

subject 

to Section 215.125 shall have submitted to 

the

Agency a compliance plan as required by 35 Ill.

Adm.

Code 201.241, including a project completion sohodule

uhorc applicable, no latcr than April 21, 1~3.

b)  Unless the submitted ~omplianoe plan or schedule was

disapproved by the Agency, the owner or operator of a

facility or emission 

-source 

subject to the rules

specified in subsection (a) may operate the omission

source according to the plan and schedule as submitted.

‘.-)

Separation Operations

The p1~ and schedule shall 

......~.

the

‘-eauircmcntc3 ~

Ill.

Adin. 

Coda 201.241 including specific interim dates

as required in 35 Ill. 

Adin. 

Code 201.242.

(Source: Repealed at —  

Ill. Reg. 

______,

effective

___________

______________________ )

SUBPART C: ORGANIC EMISSIONS FROM MISCELLANEOUS EQUIPMENT

Section 218.141

a)  No person shall use any single or multiple compartment

effluent water separator which receives effluent water

containing 757 1/day (200 gal/day) or more of organic

material from any equipment processing, refining,

treating, storing or handling organic material unless

such effluent water separator is equipped with air

pollution control equipment capable of reducing by 85

percent or more the uncontrolled organic material

emitted to the atmosphere. Exception: 

If no odor

nuisance exists the limitations of this subsection

shall not apply if the vapor pressure of the organic

material is below 17.24 

kPa

(2.5 psia) at 294.3°K

(70°F).

b)  Subsection (a) of this Section shall not apply to water

and crude oil separation in the production of Illinois

crude oil, if the vapor pressure of such crude oil is

less than 34.5 kPa (5 psia).

188

(Source: Amended at  

Ill. Reg.   

—,

effective 

____________

______________________)

Section 218.143  

Vapor Blowdown

No person shall cause or allow the emission of organic material

into the atmosphere from any vapor blowdown system or any safety

relief valve,

except such safety relief valves not capable of

causing an excessive release, unless such.emission is controlled:

a)  To 10 ppm equivalent methane (molecular weight 

16.0) or

less; or,

b)  By combustion in a smokeless flare; or,

c) By other

air pollution control equipment approved by

the Agency according to the provisions of 35 Ill.

Ad.m.

Code 201,

and further processed consistent with Section

218.108 of this Part.

(Source: Amended at 

—

Ill. Reg. 

_____,

effective 

___________

____________________ )

Section 218.144  

Safety Relief Valves

Section 218.143 of this Part shall not apply to any set of

unregulated safety relief valves capable of causing excessive

releases, provided the owner or operator thereof, by October 1,

1972, supplied the Agency with the following:

a)  A historical record of each such set (or, if such

records were unavailable, of similar sets which, by

virtue of operation under similar circumstances, may

reasonably have been presumed to have the same or

greater frequency of excessive releases) for a three—

year period immediately preceding October 1, 1972,

indicating:

1)

Dates on 

which excessive releases occurred from

each such set; and,-

2)  Duration in minutes of each such excessive

3)

release;Quantitiesand(in7

pounds) of mercaptans and/or

hydrogen sulfide emitted into the atmosphere

during each such excessive release.

b)  Proof, using such three—year historical records, that

no excessive release is likely to occur from any such

set either alone or in combination with such excessive

releases from other sets owned or operated by the same

189

person and located within a ten-mile radius from the

center point of any such set, more frequently

than 3

times in any 12 month period;

c)  Accurate maintenance records pursuant to the

requirements of subsection (a) of this Section and,

Proof, at three—year intervals, using such three—year

historical records, that such set conforms 

to the

requirements of subsection (c) of this 

Section.

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

____________

____________________ )

SUBPART E:

SOLVENT CLEANING

Section 218.181  

Solvent Cleaning in General

The requirements of this Subpart shall apply to all cold

cleaning, open top vapor degreasing, and conveyorized 

degreasing

operations which use volatile organic materials.

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

____________

Section 218.182  

Cold Cleaning

a)  Operating Procedures: No person shall operate a cold

cleaning degreaser unless:

1)  Waste solvent is stored in covered containers only

and not disposed of in such a manner that more

than 20 of the waste solvent (by weight) is

allowed to evaporate into the atmosphere;

2)  The cover of the degreaser is closed when parts

are not being handled; and

3)  Parts are drained until dripping ceases.

b)  Equipment Requirements: No person shall operate a cold

cleaning degreaser unless:

1)  The degreaser is equipped with a cover which is

closed whenever parts are

not being handled in 

the

cleaner.

The cover shall be designed to be easily

operated with one hand or with the mechanical

assistance of springs, counter—weights or a

powered system if:

190

A)  The solvent vapor pressure is greater than 2

kPa (15 mmHg or 0.3 psi) measured at 38°C

(100°F);

B)  The solvent is agitated; or

C)  The solvent is heated above ambient room

temperature.

2)  The degreaser is equipped with a ~ae4~4.ty~yj~e

for draining cleaned parts. The drainage iaaility

device shall be constructed so that parts are

enclosed under the cover while draining unless:

A)  The solvent vapor pressure is less than 4.3

kPa (32 

inmHg

or 0.6 psi) measured at 38°C

(100°F); or

B)  An internal drainage facilitydevice cannot be

fitted into the cleaning system, in which

case the drainage facilitydevice may be

external.

3)  The degreaser is equipped with one of the

following control devices if the vapor pressure of

the solvent is greater than 4.3 kPa (32 inniIg or

0.6 psi) measured at 38°C(100°F) or if the

solvent is heated above 50°C (120°F) or its

boiling point:

A) A freeboard height of 7/10 of the inside

width of the tank or 91 cm (36 in), whichever

is less; or

B)

Any

other equipment or system of equivalent

emission control as approved by the Agency

and further processed consistent with Section

218.108 of this Part. Such a system may

include a water cover, refrigerated chiller

or carbon adsorber.

4)  A permanent conspicuous label summarizing the

operating procedure is affixed to the degreaser;

and

5)  If a solvent spray is used, 

the

degreaser is

equipped with a solid fluid stream spray, rather

than a fine, atomized or shower spray.

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

__________

______________________)

191

Section 218.183  

Open Top Vapor Degreasing

a)  Operating Requirements: No person shall operate an open

top vapor degreaser unless:

The cover of the degreaser is closed when

workloads are not being processed through the

degreaser;

2)  Solvent carryout emissions are minimized by:

A)  Racking parts to allow complete drainage;

B)  Moving parts in and out of the degreaser at

less than 3.3 rn/mm (11 ft/mm);

C)  Holding the parts in the 

vapor zone 

until

condensation ceases;

D)  Tipping out any pools of solvent on the

cleaned parts before removal from the vapor

zone; ~

E)  Allowing parts to dry within the degreaser

until visually dry.

3)  Porous or absorbent materials, such as cloth,

leather, wood or rope are not degreased;

4)  Less than half of the degreaser’s open top area is

occupied with a workload;

5)  The degreaser is not loaded to the point where the

vapor level would drop more than 10 cm (4 in) when

the workload is removed from the vapor zone;

6)  Spraying is done below the vapor level only;

7)  Solvent leaks are repaired immediately;

8)  Waste solvent is stored in covered containers only

and not disposed of in such a manner that more

than 20 of the waste solvent (by weight) is

allowed to evaporate into the atmosphere;

9)  Water is not visually detectable in solvent

exiting from the water separator; and

10) Exhaust ventilation exceeding 20 cubic meters per

minute per square meter (65 cubic feet per minute

per square foot) of degreaser open area is not

192

used, unless necessary to meet the requirements of

the Occupational Safety 

and Health Act (29 U.S.C.

Section 651 et seq.).

b)  Equipment Requirements: No person shall operate an open

top vapor degreaser unless:

1)  The degreaser is equipped with a cover designed to

open and close easily without disturbing the vapor

zone;

2)  The degreaser is equipped with the following

switches:

A) A dcviocQjj~which shuts off the sump heat

source if the amount 

of condenser coolant is

not sufficient to maintain the designed vapor

level; and

B)  A dcviccQ~which shuts off the spray pump if

the vapor level drops more than 10 cm (4 in)

below the bottom condenser coil; and

C)  A dcviccQ~~which shuts off the sump heat

source when the vapor level exceeds the

design level.

3)  A permanent conspicuous label summarizing the

operating procedure is affixed to the degreaser;

4)  The degreaser is equipped with one of the

following devices:

A) A freeboard height of 3/4 of the inside width

of the degreaser tank or 91 cm (36 in),

whichever is less; and if the degreaser

opening is greater than 1 square meter (10.8

square feet), a powered or mechanically

assisted cover; or

B)

Any

other equipment or system of equivalent

emission control as approved by the Agency

and further processed consistent with Section

218.108 of this Part. Such equipment or

system may include a refrigerated chiller, an

enclosed design or a carbon adsorption

system.

(Source: Amended at 

—

Ill. Reg.

______,

effective 

____________

______________________)

193

Section 218.184  

Conveyorized Degreasing

a)  Operating Requirements: No person shall operate a

conveyorized degreaser unless:

1)  Exhaust ventilation exceeding 20 cubic meters per

minute per square meter (65 cubic feet per minute

per square foot) of area of loading and unloading

opening is not used, unless necessary to meet the

requirements of the Occupational Safety and Health

Act (29 U.S.C. Section 

651 et seq.);

2)  Solvent carryout emissions are minimized by:

A)  Racking parts for best drainage; and

B)  Maintaining the vertical conveyor speed at

less than 3.3 rn/mm (11 ft/mm);

3)  Waste solvent is stored in covered containers only

and not disposed of in such a manner that more

than 20 of the waste solvent (by weight) is

allowed to evaporate into the atmosphere;

4)  Solvent leaks are repaired immediately;

5)  Water is not visually detectable in solvent

exiting from the water separator; and

6)  Downtime covers are placed over entrances and

exits of conveyorized degreasers immediately after

the conveyors and exhausts are shut down and not

removed until just before start—up.

b)  Equipment Requirements: No person shall operate a

conveyorized degreaser unless:

1)  The degreaser is equipped with a drying tunnel,

rotating (tumbling) basket or other equipment

sufficient to prevent cleaned parts from carrying

out solvent liquid or vapor;

2)  The degreaser is equipped with 

the

following

switches:

A)  A dcvicoOne which shuts off the sump heat

source if the amount of condenser coolant is

not sufficient to maintain the designed vapor

level;

B)  A devicoOne which shuts off the spray pump or

the conveyor if the vapor level drops more

194

than 10 cm (4 in) below the bottom condenser

coil; and

C)  A—4e~4eeO~which shuts of 

f the sump heat

source when the vapor level exceeds the

design 1evel~~

3)  The degreaser is equipped with openings for

entrances and exits that silhouette work.oads SO

that the average clearance between the parts and

the

edge of the degreaser opening is less than 10

cm (4 in) or less than 

10 percent of 

the

width of

the opening;

4)  The degreaser is equipped with downtime covers for

closing off entrances and exits when the degreaser

is shut down; and

5)  The degreaser is equipped with one of the

following control devices, if the air/vapor

interface is larger than 2.0 square meters (21.6

square feet):

A)  A carbon adsorption system with ventilation

greater than or equal to 15 cubic meters per

minute per square meter (50 cubic feet per

minute per square foot) of air/vapor area

when downtime covers are open, and exhausting

less than 25 ppm of solvent by volume

averaged over a complete adsorption cycle; or

B)  Any other equipment or system of equivalent

emission control as approved by the Agency,

and further processed consistent with Section

218.108 of this Part. Such equipment or

system may include a refrigerated chiller.

(Source: Amended at  

Ill. Reg. 

______,

effective 

____________

______________________)

Section 218.185  

Compliance Schedule (Repealed)

Every ewner or epera~er

e~

an emission seuree 

wnien was

previously eKempt from the requirements of -Subpart E of 35 Ill.

Adm. Cede 215 (Sections 215.182-215.184) beeause it satisfied 

the

criteria in either 35 Ill. Mm. Code- 215.181(a) or 35 

Ill. Mm.

Code 215.181(b), shall comply with the requirements of this

Subpart en and after a date eensistent with Seotien 218.10?. A

source which did not satisfy 

the criteria in either 35 Ill. 

Mm.

Code 215.181(a) or 35 Ill. A~. Code 215.18l(b~shall cemply vith

the requirements of this Subpart upon -adoDtion.

195

(Source: Repealed at 

—

Ill. Reg.    

effective 

___________

____________________ )

Section 218.186  

Test Methods

The following test methods shall be used to demonstrate

compliance with this Subpart:

a)  Vapor pressures shall be determined by using the

procedure specified in Section 218.110 of this Part.

b)  Exhaust ventilation rates shall be determined by using

the procedures specified in Section 218.105(f) (3) QL

this Part.

c)  The performance of control devices shall be determined

by using the procedures specified in Section 218.105(f)

of this Part.

(Source: Amended at  

Ill. Reg.    

effective 

____________

SUBPART F: COATING OPERATIONS

Section 218.204  

Emission Limitations for Manufaoturmntr Plants

Except as provided in Sections 218.205. 218.207 and 

218.208 ~

this Part, no owner or operator of a coating line shall apply at

any time any coating in which the VON content exceeds the

following emission limitations for the specified coating. The

following emission limitations are expressed in units of VON per

volume of coating (minus water and any compounds which are

specifically exempted from the definition of VON) as applied at

each coating applicator, except where noted. Compounds which are

specifically exempted from the definition of VON should be

treated as water for the purpose of calculating the “less water”

part of the coating composition. Compliance with this Subpart

must be demonstrated through the applicable coating analysis test

methods and procedures specified in Section 218.105(a) of this

Part and the recordkeeping and reporting requirements specified

in Section 218.211(c) of this Part except where noted. (Note:

The equation presented in Section 218.206 of this Part shall be

used to calculate emission limitations for determining compliance

by add—on controls, credits for transfer efficiency, emissions

trades and cross-line averaging.) The emission limitations are

as follows:

a)  Automobile or Light-Duty   

kg/l    

lb/gal

Truck Coating

1)  Prime coat       

0.14    

(1.2)

196

2)  Primer surfacer coat  

p.341.81  

(~-r-&15.1)

(Note: The primer surfacer coat limitation is

based upon 

a transfer offioicnoy of 30 percent.

The use of transfer cffioionoy credits can ho

allowed only if approved by the Agency and

approved by

thc

UCEPA as a CIP revision in units

of kg (ibs) of VON ~er 1 (aal) 

of coating solids

deposited. Compliance with the limitation shall

be based on the daily-weighted average from an

entire primer surfacer operation. Compliance

shall be demonstrated in accordance with the

topcoat ~rotoco1 referenced in Section 218.105(bI

and the recordkeeping and reporting reauirements

specified in Section 218.211(f). Testing to

demonstrate compliance shall be performed in

accordance with the topcoat protocol and a

detailed testing ~roposa1 approved by the A~encv

and USEPA specifying the method of demonstrating

compliance with the protocol. Section 218.205 does

not apply to the primer surfacer limitation.)

kg/l    

lb/gal

3)  Topcoat        

1.81    

(15.1)

(Note: The topcoat limitation is in units of kg

(lbs) of VON per 1 (gal) of coating solids

deposited. Compliance with the limitation shall

be based on the daily-weighted average VON oontcnt

from 

#he~j~entire 

topcoat operation (all topcoat

spray booths, flash-off arcas and bakc ovcno).

Compliance shall be demonstrated in accordance

with the topcoat protocol for automobiles and

light-duty trucks referenced in Section 218.105(b)

of this Part and the recordkeeping and reporting

requirements specified in Section 218.211(f).

Testing to demonstrate compliance shall be

performed in accordance with the topcoat protocol

~ Coction 218.205 does not apply to the topooat

limitation.) 

At least 180 days prior to the

initial complianoc date, the owner or operator of

a coating line 

subject to the topcoat limitation

shall have submitted to 

the UCEPA a detailed

testing proposal approved by the Agency and USEPA

specifying the method of demonstrating compliance

with the protocol. The proposal shall havo

included, at a minimum, a comprehensive plan

(including a rationale) for determining the

transfer eLJ~~.uJ.pnpyat each booth through

~

use

of in-plant, or pilot testing; tnc ociea~ion of

coatings to be tested (for the purpose of

determining transfer efficiency) including the

rationale for coating groupings;

for determining the analytic VON

irInr~ £1rtf~ 

fnrmiilnt

and the method

content of ac

applied a.~.

inr~ nn1trs,nt~

content of as applied coatings. Upon approval of

the protocol by the UCEPA, 

the

source may

proceed

with the compliance demonstration. Section

218.205 of this Part does not a~~1vto the ~pcoat

limitation.)

kg/l    

lb/gal

4)  Final repair coat   

0.58     

(4.8)

Can Coating

kg/l

lb/gal

1)  Sheet basecoat and

overvarnish

0.34

(2.8)

2)  Exterior basecoat and

overvarnish       

0.34    

(2.8)

3)  Interior body spray coat 0.51    

(4.2)

4)  Exterior end coat    

0.51    

(4.2)

5)  Side seam spray coat  

0.66    

(5.5)

6)  End sealing compound coato.44    

(3.7)

kg/l    

lb/gal

c)  Paper Coating        

0.35    

(2.9)

(Note: The paper coating limitation shall not apply to

any

owner or operator of any paper coating line on

which printing is performed if the paper coating line

complies with the emissions limitations in Subpart H:

Printing and Publishing, Sections 218.401 of this Part

through 218.404.)

kg/i

lb/gal

d)  Coil Coating         

0.33.      

(2.6)

Fabric Coating

0.35

(2.9)

f)  Vinyl Coating        

0.45    

(3.8)

g)  Metal Furniture Coating   

0.36    

(3.0)

Ii)   Large Appliance Coating   

0.34

(2.8)

(Note: The limitation shall not apply to the use of

quick-drying lacquers for repair of scratches and nicks

that occur during assembly, provided that the volume of

—~

197

198

coating does not exceed 0.95 1 (1 quart) in any one

rolling eight-hour period.)

kg/i    

lb/gal

1)  Magnet Wire Coating     

0.20    

(1.7)

j)  Miscellaneous Metal Parts and

Products Coating

1)  Clear coating     

0.52    

(4.3)

2)  Air-dried coating    

0.42    

(3.5)

3)  Extreme performance  

0.42    

(3.5)

coating

~i1 Steel pail and drum  

(0.52)    

(4.3)

interior coating

4~) All other coatings   

0.36    

(3.0)

kg/l

lb/gal

k)  Heavy Off-Highway Vehicle

Products Coating

1) Extreme performance  

0.42    

(3.5)

prime coat

2) Extreme performance top- 0.42    

(3.5)

coat (air dried)

3) Final repair coat    

0.42    

(3.5)

(air dried)

4) All other coatings are subject to the emission

limitations for miscellaneous metal parts and

products coatings in subsection 

(j)

above.

1)  Wood Furniture Coating   

kg/i    

lb/gal

1)  Clear topcoat      

0.67    

(5.6)

2)  Opaque stain      

0.56    

(4.7)

3)  Pigmented coat     

0.60    

(5.0)

4)  Repair coat       

0.67    

(5.6)

5)  Sealer         

0.67    

(5.6)

6)  Semi-transparent stain 0.79    

(6.6)

199

7)  Wash coat       

0.73    

(6.1)

(Note: An owner or operator of a wood furniture

coating operation subject to this Section shall

apply all coatings, with the exception of no more

than 37.8 

1 (10 gal) of coating per day used for

touch-up and repair operations, using one or more

of the following application systems: airless

spray application system, air—assisted airless

spray application system, electrostatic spray

application system, electrostatic bell or disc

spray application system, heated airless spray

application system, roller coating, brush or wipe

coating application system, e~dip coating

application system or high volume low pressure

IHVLP)

application system.)

m) Existing Diesel-Electric Locomotive Coating Lines in

Cook County

kg/i    

lb/gal

1)  Extreme performance prime

coat           

0.42    

(3.5)

2)  Extreme performance top-

coat (air dried)     

0.42    

(3.5)

3)  Final repair coat

(air dried)

0.42

(3.5)

4)  High-temperature aluminum

coating         

0.72    

(6.0)

5)  All other coatings    

0.36    

(3.0)

(Source: Amended at  

Ill. Reg.    

effective 

___________

_________________________ )

Section 218.205  

Daily-Weighted Average Limitations

No owner or operator of a coating line subject to the limitations

of Section 218.204 of this Part and complying by means of this

Section shall operate the subject coating line unless the owner

or operator has demonstrated compliance with subsection (a), (b),

(C),  (d), (e) or (f) of this Section (depending upon the source

category of coating) through the applicable coating analysis test

methods and procedures specified in Section 218.105(a) of this

Part and the recordkeeping and reporting requirements specified

in Section 218.211(d) of this Part:

200

a)  No owner or operator of a coating line subject to only

one of the limitations from among Section

218.204(a) 

(1), ~a)(2), (a) (4), (C),  (d) 

(e)

(f)

(g)

(h), or (i) of this Part shall apply coatings on any

such coating line, during any day, whose daily-weighted

average VON content exceeds

the emission limitation to

which the coatings are subject.

b)  No owner or operator 

of a miscellaneous metal parts and

products coating line subject to the limitations of

Section 218.204(j) of this Part shall apply coatings to

miscellaneous metal parts or products on the subject

coating line unless the requirements in subsection

(b) (1) or (b) (2) below are met.

3.)   For each coating line which 

applies multiple

coatings, all of which are subject to the same

numerical emission limitation within Section

218.204(j) during the same day (e.g., all coatings

used on the line are subject to 0.42 kg/i (3.5

lbs/gal)), the daily-weighted average VON content

shall not exceed the coating VON content limit

corresponding to the category of coating used, or

2)  For each coating line which applies coatings

sublect to more than one numerical emission

limitation from more than one of

the

four 

coating

categories in Section 218.204(j) above, during the

same day, the owner or operator shall have a

site-specific proposal approved by the Agency and

approved by the USEPA as a SIP revision. To

receive approval, the requirements of USEPA’s

Emissions Trading Policy Statement (and related

policy) 51 Fed. Reg. 43814 (December 4, 1986),

must be satisfied.

C)

No owner or

operator of a can coating facilityline

subject to the limitations of Section ~~204(b)  ~

this Part shall operate the subject coating facility

line using a coating with a VON content in excess of

the limitations specified in Section ~&~j1.204(b) 

QZ.

this Part unless all of the following requirements are

met:

1)  An alternative daily emission limitation shall be

determined for the can coating operation. i.e. for

all of the can coating lines at the source,

according to subsection (c) (2) below. Actual

daily emissions shall never exceed the alternative

daily emission limitation and shall be calculated

by use of the following equation.

201

n

Ed= E Vj Cj

i=1

where:

Ed

Actual VON emissions for the day in

units of kg/day (lbs/day)~.~

I

Subscript denoting a specific

coating applied,-j.

n

Total number of coatings applied in

the can coating operation, i.e. all

can coating lines at the source:

V~

Volume of each coating applied for

the day in units of 1/day (gal/day)

of coating (minus water and any

compounds which are specifically

exempted from the definition of

VON)~

Cj

The VOM content of each coating as

applied in units of kg VON/i (lbs

VON/gal) of coating (minus water

and any compounds which are

specifically exempted from the

definition of VON).

2)  The alternative daily emission limitation (Ad)

shall be determined for the can coating operation.

i.e. for all of the can coating lines at the

source, on a daily basis as follows:

n

Ad=

E Vj~LiIQI 

—

Cji~

i=l

(Di— L~

where:

Ad

The

VON emissions allowed

for the

day in units of kg/day (lbs/day)~j.

I  =  Subscript denoting a specific

coating appliedrj..

=

Total number

of surface coatings

applied in the can coating

operation7j~

202

Ci =  The VON content of each surface

coating as applied in units of kg

VON/i (lbs VON/gal) of coating

(minus water and any compounds

which are specifically exempted

from the definition of VOM)Tj.

D~ =  The density of VON in each coating

applied. For the purposes 

calculating ~-A?j,the density is

0.882 kg VON/i VON (7.36 lbs

VOM/gal VOM)~j~

Vj~

Volume of each surface coating

applied for the day in units of 1

(gal) of coating (minus water and

any compounds which are

specifically exempted from the

definition of VON)7~.

The VON emission limitation for

each surface coating applied as

specified in Section 218.204(b) 

91.

this Part in units of kg VON/i (lbs

VON/gal) of coating (minus water

and any compounds which are

specifically exempted from the

definition of VON).

d)  No owner or operator of a heavy off-highway vehicle

products coating line subject to the limitations of

Section 218.204(k) of this Part shall apply coatings to

heavy off-highway vehicle products on the subject

coating line unless the requirements of subsection

(d) (1) or (d) (2) below are met.

1)  For each coating line which applies multiple

coatings, all of which are subject to the same

numerical emission limitation within Section

218.204(k) above, during 

the same 

day (e.g., all

coatings used on the line are subject to 0.42 kg/i

(3.5 lbs/gal)), the daily-weighted average VON

content shall not exceed the coating VOM content

limit corresponding to the category of coating

used, or

2)  For each coating line which applies coatings

subject to more than one numerical emission

limitation in Section 218.204(k) above, during the

same day, the owner or operator shall have a site

specific proposal approved by the Agency and

203

approved by the USEPA as a SIP revision. To

receive approval, the requirements of USEPA’s

Emissions Trading Policy Statement (and related

policy) 51 Fed. Reg. 43814 (December 4. 1986)~

must be satisfied.

e)  No owner or operator of a wood furniture coating line

subject to the limitations of Section 218.204(1) 

91

this Part shall apply coatings to wood furniture on the

subject coating line unless the requirements of

subsection (e) (1) or subsection (e) (2) below, in

addition to the requirements specified in 

the

note to

Section 218.204(1) of this Part, are met.

1)  For each coating line which applies multiple

coatings, all of which are subject to the same

numerical emission limitation within Section

218.204(1) above, during the same 

day (e.g., all

coatings used on the line are subject to 0.67 kg/i

(5.6 lbs/gal), the daily-weighted average VON

content shall not exceed 

the coating VON content

limit corresponding to the category of coating

used, or

2)  For each coating line which applies coatings

subject to more than one numerical emission

limitation in Section 218.204(1) above, during the

same day, the owner or operator shall have a site

specific proposal approved by the Agency and

approved by the USEPA as a SIP revision. To

receive approval, the requirements of USEPA’s

Emissions

Trading Policy Statement (and related

policy) 51 Fed. Reg. 43814 (December 4.. 1986).

must be satisfied.

f)  No owner or operator of an existing diesel—electric

locomotive coating line in Cook County, subject to the

limitations of Section 218.204(m) of this Part shall

apply coatings to diesel—electric locomotives on the

subject coating line unless the requirements of

subsection (b)(1)(f)(1) or -(b)(2)-(f)(2) 

of this Section

are met.

1)  For each coating line which applies multiple

coatings, all of which are subject to the same

numerical emission limitation within Section

218.204(m) above, during 

the same day (e.g., all

coatings used on the line 

are subject to 0.42 kg/I

(3.5 lbs/gal), the daily-weighted average VOM

content shall not exceed the coating VON content

limit corresponding to the category of coating

used, or

204

2)  For each coating line which applies coatings

subject to more than one numerical emission

limitation in Section 218.204(m) above, during the

same day, the owner or operator shall have a site

specific proposal approved by the Agency and

approved by the USEPA as a SIP revision. To

receive approval, the requirements of USEPA’s

Emissions Trading Policy Statement (and related

policy) must be satisfied.

(Source: Amended at 

—

Ill. Reg.    

effective 

____________

______________________)

Section 218.206  

Solids Basis Calculation

Limitations in terms of kg (ibs) of VON emissions per 

1 (gal) of

solids as applied at each coating applicator shall be determined

by the following equation:

S  =     

C

1

—

(C/D)

where:

S  =  The limitation on VON emissions in terms of

kg VON/i (lbs VON/gal) of

solids,-i.

C  =  The limitation on VON emissions in terms of

kg/i (lbs/gal) of coating (minus water and

any compounds which are specifically

excluded

from the definition of VON) specified in

Section 218.204,- of this Part

D

The density of

VON in the coating. For the

purposes of calculating S, the density is

0.882 kg VON/i VOM (7.36 lbs VON/gal VON).

(Source: Amended at 

—

Ill. Reg.   

effective 

____________

______________________)

Section 218.207  

Alternative Emission Limitations

Any

owner or operator of a coating line subject to

Section 218.204 of this Part may comply with this

Section, 

rather than with Section 218.204 of this Part,

if a capture system and control device are operated at

all times the coating line is in operation and the

owner or operator demonstrates compliance with

subsections (c), (d), (e), (f),

(g) or (h) of this

Section (depending upon the source category) through

the applicable coating analysis and capture system and

control device efficiency test methods and procedures

205

specified in Section 

218.105 of this Part and the

recordkeeping and reporting requirements specified in

Section 218.211(e) of this Part and the control device

is equipped with the applicable monitoring equipment

specified in Section 218.105(d) of this 

Part 

and the

monitoring equipment is installed, calibrated, operated

and maintained according to vendor specifications at

all times the control device is in use. A capture

system and control device, which does not demonstrate

compliance with subsection (c), (d), (e), 

(f), (g) or

(h) of this Section may be used as an alternative to

compliance with Section 218.204 of this Part only if

the

alternative is approved 

by the Agency and approved

by the USEPA as a SIP revision.

b)  Alternative Add-On Control Methodologies

1)  The coating line is equipped with a capture system

and control device that provides 81 percent

reduction in the overall emissions of VON from the

coating line and the control device has a 90

percent efficiency, or

2)  The system used to control VON from 

the

coating

line is demonstrated to have an overall efficiency

sufficient to limit VON emissions to no more than

what is allowed under Section 218.204 of this

Part. Use of any control system other than an

afterburner, carbon adsorption, condensation, or

absorption scrubber system can 

be allowed only if

approved by the Agency and approved by the USEPA

as a SIP revision. The use of transfer efficiency

credits can be allowed only 

if approved by the

Agency and approved by the USEPA as a SIP

revision. Baseline transfer efficiencies and

transfer efficiency test methods must be approved

by the Agency and the USEPA.

Such overall efficiency is to be determined as

follows:

A)  eQbtain the emission limitation from the

appropriate subsection in Section 218.204 of

this Part,-j.

B)  e~alculate“S” according to the equation in

Section 

218.206 of this Part,-~

C)  e~alculatethe overall efficiency required

according to Section 218.105(e) of this Part.

For the purposes of calculating this value,

according to the equation in Section

206

218.105(e) (2) of this Part, VOM1is equal to

the value of 1~Sttas determined above in

subsection (b) (2) (B) of this Section.

c)  No owner or operator of a coating line subject to only

one of the emission limitations from among Section

218.204(a) (1),

(a)(2), (a) (4), (c), (d), (e), (f), (g),

(h) or (i) of this Part and equipped with a capture

system and control device shall operate the subject

coating line unless the requirements in subsection

(b) (1) or (b) (2) above are met. No owner or operator

of a coating line subject to Section 218.204 (a) (2) or

218.204 (a)

(3) and equipped with a capture system and

control device shall operate the coating line unless

the owner or operator demonstrates compliance with tI~e

topcoat such limitation in accordance with the topcoat

protocol for automobile or light-duty trucks referenced

in Section 218.105(b).

d) No owner or operator of

a miscellaneous metal parts and

products coating line which applies one or more

coatings during the same day, all of which are subject

to the same numerical emission limitation within

Section 218.204(j) of this Part (e.g., all coatings

used on the line are subject to 0.42 kg/i (3.5

lbs/gal), and which is equipped with a capture system

and control device shall operate the subject coating

line

unless the requirements in subsection (b) (1) or

(b) (2) above are met.

e)  No owner or operator of a heavy off-highway vehicle

products coating line which applies one or more

coatings during the same day, all of which are subject

to the same numerical emission limitation within

Section 218.204(k) of this Part

(e.g., all coatings

used

on the line are subject to 0.42 kg/i (3.5

lbs/gal), and which is equipped with a capture system

and control device shall operate the subject coating

line unless the requirements in subsection (b) (1) or

(b) (2) above are met.

f)  No owner or operator of an existing diesel—electric

locomotive coating line in Cook County which applies

one or more coatings during the same day, all of which

are subject to the same numerical emission limitation

within Section 218.204(m) of 

this Part (e.g., all

coatings used on the line

are subject to 0.42 kg/i (3.5

lbs/gal)), and which is equipped with a capture system

and control device shall operate the subject coating

line unless the requirements in subsection (b) (1) or

(b) (2) above are met.

207

No owner or operator of a wood furniture coating line

which applies one or more coatings during the same day,

all of which are subject to the same numerical emission

limitation within Section 218.204(1) of this Part

(e.g., all coatings used on the line are subject to

0.67 kg/l (5.6 lbs/gal),

and which is equipped with a

capture system and control device shall operate the

subject coating line unless the requirements in

subsection (b) (1) or (b) (2) of this Section

are

met.

If compliance is achieved by meeting

the

requirements

in subsection (b) (2) of this Part, then the provisions

in the note to Section 218.204(1)

of this Part must

also be met.

h)  No owner or operator of a can coating faailityline ef~4

which is equipped with a capture system and control

device shall operate the subject coating faoility~jne

unless the requirements in subsection (Ii) (1) or (h) (2)

below are met.

1)  An alternative daily emission limitation shall be

determined for the can coating operation. i.e. for

all of the can coating lines at the source.

according to Section 218.205(c) (2) of this Part.

Actual daily emissions shall never exceed the

alternative daily emission limitation and shall be

calculated by use of the following equation:

n

E Vj Ci (1-Ft)

1=1

where:

Ed

Actual VOM emissions for the day in

units of kg/day (lbs/day),-.~

i

Subscript denoting the specific

coating applied,-j.

=

Total number of surface coatings as

applied in the can coating

operation,-~

Volume

of each coating as

applied

for the day in units of 1/day

(gal/day) of coating (minus water

and any compounds which are

specifically exempted from 

the

definition of VOM),-~

208

Cj

The VON content of each coating as

applied in units of kg VON/i (lbs

VON/gal) of coating (minus water

and any compounds which are

specifically exempted from the

definition of VON) and

Fraction, by weight, of VON

emissions from the surface coating,

reduced or prevented from being

emitted to the ambient air. This is

the overall efficiency of the

capture system and control devices.

2)

The coating line is equipped with a capture system

and control device that provide 75 

percent

reduction in the overall emissions of VON from the

coating line and the control device has a 90

percent efficiency.

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

____________

______________________ )

Section 218.208  

Exemptions From Emission Limitations

a)  Exemptions for all Gourcecoating categories except wood

furniture coating. The limitations of this Subpart

shall not apply to coating lines within a facility

source, that otherwise would be subject to the same

subsection of Section 218.204 (because they belong to

the same sourcecoating category, e.g. can coating)

provided that combined actual emissions of VON from all

lines at the faciiitysource subject to that subsection

never exceed 6.8 kg/day (15 lbs/day) before the

application of capture systems and control devices.

(For example, can coating lines within a plantsource

would not be subject to the limitations of Section

218.204(b) of this Part if the combined actual

emissions of VON from the can coating lines never

exceed 6.8 kg/day (15 lbs/day) before the application

of capture systems and control devices.) Volatile

organic material emissions from heavy off—highway

vehicle products coating lines must be combined with

VON emissions from miscellaneous metal parts and

products coating lines to determine applicability. 

Any

owner or operator of a coating taciiitysource shall

comply with the applicable coating analysis test

methods and procedures specified in Section 218.105(a)

of this Part and the recordkeeping and reporting

requirements specified in Section 218.211(a) of this

Part if total VON emissions from the subject coating

209

lines are always less than or equal to 6.8 kg/day

(15 lbs/day) before the application of capture systems

and control devices and, therefore, are not subject to

the limitations of Section 218.204 of this Part. Once

a category of coating lines at a facilitysource is

subject to the limitations in Section 218.204, of this

Part the coating lines are always subject to the

limitations in Section 218.204 of this Part.

b)  Applicability for wood furniture coating

1)  The limitations of this Subpart shall apply to a

plant’osource’s wood furniture coating lines if

the plantsource contains process emission souroos

units, not regulated by Subparts B, E, F

(excluding Section 218.204(1) of this Part), H

(excluding Section 218.405), Q, R, S, T (exciudina

Section 218.486 of this Part),V, X, Y, e~Z or BB

of this Part, which as a group both:

A)  Hhave maximum theoretical emissions of 91 Mg

(100 tons) or more per calendar year of VON

if no air pollution control equipment were

used, and

B)  Aare not limited to less than 91 Mg

(100 tons) of VON per calendar year if no

air pollution control equipment were used,

through production or capacity limitations

contained in a federally enforceable

construction permit or SIP revision.

2)  If a plantsource ceases to fulfill the criteria of

subsection (b) (1) of this Section, the limitations

of Section 218.204(1) of this Part shall continue

to apply to any wood furniture coating line which

was ever subject to the limitations of Section

218.204(1) of this Part.

3)  For the purposes of subsection (b) of this

Section, an emission oourocunit shall be

considered regulated

by a Subpart if it is subject

to the limitations of that Subpart. An emission

eourccunit is not considered regulated by a

Subpart if it is not subiect to the limits of that

Subpart, e.g., the emission unit is covered by an

exemption in the Subpart or the a~~p1icabilitv

criteria of the Subpart are not met. its omissions

arc below the applicability cutoff level or if the

dby

210

4)

Any owner 

or operator of a wood furniture coating

line to which the limitations of this Subpart are

not applicable due to the criteria in subsection

(b) of this Section shall, upon request by the

Agency or the USEPA, submit records to the Agency

and the USEPA within 30 calendar days from the

date of the request that document that the coating

line is exempt from the limitations of this

Subpart.

(Source: Amended at  

Ill. Reg.    

effective 

____________

_______________________)

Section 218.209  

Exemption From General Rule on Use of Organic

Material

No owner or operator of a coating line subject to the limitations

of Section 218.204 of this Part is required to meet the

limitations of Subpart G (Section 218.301 or 218.302) of this

Part, after the date by which the coating line is required to

meet Section 218.204 of this Part.

(Source: Amended at  

Ill. Reg. 

______,

effective 

____________

______________________)

Section 218.210  

Compliance Schedule

Every owner or operator of a coating line (of a type included

within Section 218.204) of this Part shall comply with the

requirements of Section 218.204, 218.205. 218.207 or 218.208 and

Section 218.211 of this Part in accordance with the appropriate

compliance schedule as specified in subsection (a), (b), (C)  or

(d) below:

a)  No owner or operator of a coating line which is exempt

from the limitations of Section 218.204 of this Part

because of the criteria in Section 218.208(a) of this

Part shall operate said coating line on or after a date

consistent with Section 218.106 of this Part, unless

the owner or operator has complied with, and continues

to comply with, Section 218.211(b) of this Part. Wood

furniture coating lines are not 

subject to Section

218.211(b) of this Part..

b)  No owner or operator of a coating line complying by

means of Section 218.204 of this Part shall operate

said coating line on or after a date consistent with

Section 218.106 of this Part, unless the owner or

operator has complied with, and continues to comply

with, Sections 218.204

and 218.211(c) of this Part.

211

c)  No owner or operator of a coating line complying by

means of Section 218.205 of this Part shall operate

said coating line on or after a date consistent with

Section 218.106 of this Part, unless the owner or

operator has complied with, and continues to comply

with, Sections 218.205 and 218.211(d) of this Part.

d)  No owner or operator of a coating line complying by

means of Section 218.207 of this Part shall operate

said coating line on or after a date consistent with

Section 218.106 of this Part, unless the owner or

operator has complied with, and continues to comply

with, Sections 218.207 and 218.211(e) of this Part.

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

_________

_____)

Section 218.211  

Recordkeeping and Reporting

a)  The VOM content of each coating and the efficiency of

each capture system and control device shall be

determined by the applicable test methods and

procedures specified in Section 218.105 of this Part to

establish the records required under this Section.

b)  Any owner or operator of a coating line which is

exempted from the limitations of Section 218.204 

91

this Part because of Section 218.208(a) of this Part

shall comply with the following:

1)  By a date consistent with Section 218.106 of this

Part, the owner or operator of a ~

line or a group of coatinc~lines referenced in

this subsection(b) of this Section shall certify

to the Agency that the ~acilitycoating line or

group of coating lines is exempt under the

provisions of Section 218.108(a) of this Part.

Such certification shall include:

A)  A declaration that the 1-aci1itycoatin~ line

or group of coating lines is exempt from the

limitations of Section 218.204 of this Part

because of Section 218.208(a) of this Part

and

B)  Calculations which demonstrate that the

combined VON emissions from &I-~JI~coating

lines at the facility~grouP of coating

lines never exceed 6.8 kg (15 lbs) per day

before the application of capture systems and

control devices. The following equation

212

shall be used to calculate total VON

emissions:

mn

Tte =    

S

(AjBi)j

j=1 i=1

where:

Tte

Total VON emissions from coating

lines at a facility each day before

the application of capture systems

and control devices in units of

kg/day (1bs/day),-~

m

Number of coating lines at the

facility source that otherwise

would be subiect to the same

subsection of Section 218.104 of

this Part (because they belong to

the same catec~ory. e.g.. can

coating) 

,-~

Subscript denoting an individual

coating line,-j.

n

Number of different coatings as

applied each day on each coating

line at the faci1ity,j~

i

Subscript denoting an individual

coating,-j

A~

Weight of VON per volume of each

coating (minus water and any

compounds which are specifically

exempted from the definition of

VOM) as applied each day on each

coating line at the facility in

units of kg VON/i (lbs VOM/gal)j.~

and

Bi

Volume of each coating (minus water

and any compounds which are

specifically exempted from the

definition of VON) as applied each

day on each coating line at the

facility in units of 1/day

(gal/day). The instrument or

method by which the owner or

operator accurately measured or

213

calculated the volume of each

coating as applied on each coating

line each day shall be described in

the certification to the Agency.

2)  On and after a date consistent with Section

218.106 of this Part, the owner or operator of a

facility coating line or arou~of coating lines

referenced in this subsection shall collect and

record all of the following information each day

for each coating line and maintain the information

at the facilitysource for a period of three years:

A)  The name and identification number of each

coating as applied on each coating line.

B)  The weight of VON per volume and the volume

of each coating (minus water and any

compounds which are specifically exempted

from the definition of VON) as applied each

day on each coating line.

3)  On and after a date consistent with Section

218.106 of this Part, the owner or operator of a

facility coating line or group of coating lines

exempted from the limitations of Section 218.204

of this Part because of Section 218.208(a) of this

Part shall notify the Agency of any record showing

that total VON emissions from the coating

facilityline or group of coating lines exceed 6.8

kg (15 ibs) in any day before the application of

capture systems and control devices by sending a

copy of such record to the Agency within 30 days

after the exceedance occurs.

C)   Any owner or operator of a coating line subject to 

the

limitations of Section 218.204 of this Part other than

Section 218.204(a) (2) or (a)(3) and complying by means

of Section 218.204 of this Part shall comply with the

following:

1)  By a date consistent with Section 218.106 of this

Part, or upon initial start-up of a new coating

line, or upon changing the method of compliance

from an existing subject coating line from Section

218.205 or Section 218.207 of this Part to Section

218.204 of this Part the owner or operator of a

subject coating line shall certify to the Agency

that the coating line will be in compliance with

Section 218.204 of this Part on and after a date

consistent with Section 218.106 of this Part, or

214

on and after the initial start-up date. Such

certification shall include:

A) The name and identification number of each

coating as applied on each coating line.

B)  The weight of VON per volume of each coating

(minus water and any compounds which are

specifically exempted from the definition of

VON) as applied each day on each coating

line.

e~ For coating lincssubjoot to Cootion

s—, ~—

,

_1__1,

4+

The

name

and identification

number 

each coating 218.204 (a) (3) 

WW~ ~

—

218

204 (a) (3)

coating

2)  On and after a date consistent with Section

218.106 of this Part, or on and after the initial

start—up date, the owner or operator of a subiect

coating line oubjoct to tho limitations of Cootien

~18.204 and semplying by means of Section 218.204

shall collect and record all of the following

information each day for each coating line and

maintain the information at the facility source

for a period of three years:

44+

~

- -

n~imc

-and ~

each coating

line,

..~..entifioation

number 

iii)

uu~ingThe

—

£.

wcigh~

.•

au ~pp1icd on caoh coating linc.,

The instrument or method by which the

owner or operator will accurately

measure or calculate the volume of each

coating as applied each day on each

coating line,

The

method by which the

owner 

operator will create and maintain

records each day as required in

subsection (a) (2) below for coating

lines subject to Ceation 218.204(a) (3),

An cramplc format in which the records

required in subsection (o) (2) below for

nub4~at 

to Coction

215

A) The name and identification number of each

coating as applied on each coating line.

B)  The weight of VON per volume of each coating

(minus water and any compounds which are

specifically exempted from the definition of

VON) as applied each day on each coating

line.

~ coating i~ncs-subject to Ccotion

218 204(a)(3) tl~

record o n00009ary

-to

palo ulate

the

daily weighted

the coating line in

proposal submitted,

average VON

accordanoc

and proved

content from

with the

by the UCEPA,

rnirimnnt tn

f~r~r~tinn

~1~~O4

i—,

s—,

3)  On and after a date consistent with Section

218.106 of this Part, the owner or operator of a

subject coating line shall notify the Agency in

the following instances:

A) Any record showing violation of Section

218.204 of this Part shall be reported by

sending a copy of such record to the Agency

within 30 days following the occurrence of

the violation, except that any -record showing

a violation of Ceotion 218.204(a) (3) -shall be

rcportod by sending a copy of ouch record to

the Agency within 15 -days from the end -of the

month in which the violation occurred.

B)  At least 30 calendar days before changing the

method of compliance with Ccction 218.204

from Section 218.204 of this Part to Section

218.205 or Section 218.207 of this Part, the

owner or operator shall comply with all

requirements of subsection (d) (1) or (e) (1)

of this Section below, respectively. Upon

changing the method of compliance

w-ith

Ccction 218.204 from Section 218.204 of this

Part to Section 218.205 of this Part or

Section 218.207 of this Part, the owner or

operator shall comply with all requirements

of subsection (d) or (e) of this Section,

respectively.

s.)-   For coating lingo subject to Ccction

2l8.204~(a)(3) the owner or operator shall

notify the Agency of any change to the

topooating operation at least 30 days bofore

the change is effected. The Agency shall

216

tification

tooting is require

determines that ro

d. If the Agency

certification tosting—4e

required, then the owner 

or operator oha3~

eubmit a proposal to the Agency to test

within 30 days and 

retest within 30 days of

the Agency’s approva.L

of the propoca.~..

d) Any owner or operator of a coating line subject to the

limitations of Section 218.204 of this Part and

complying by means of Section 218.205 of this Part

shall comply with the following:

1)  By a date consistent with Section 218.106 of this

Part, or upon initial start—up of a new coating

line, or upon changing the method of compliance

for an existing subject coating line from Section

218.204 or Section 218.207 of this Part to Section

218.205 of this Part the owner or operator of the

subject coating line shall certify to the Agency

that the coating line will be in compliance with

Section 218.205 of this Part on and after a date

consistent with Section 218.106 of this Part, or

on and after the initial start—up date. Such

certification shall include:

A) The name and identification number of each

coating line which will comply by means of

Section 218.205 of this Part.

B)  The name and identification number of each

coating as applied on each coating line.

C)  The weight of VON per volume and the volume

of each coating (minus water and any

compounds which are specifically exempted

from the definition of VON) as applied each

day on each coating line.

D) The instrument or method by which the owner

or operator will accurately measure or

calculate the volume of each coating as

applied each day on each coating line.

E)  The method by which the owner or operator

will create and maintain records each day as

required in subsection (d) (2) of this

~ection.

F)  An example of the format in which the records

required in subsection (d) (2) of this Section

will be kept.

217

2)  On and after a date consistent with Section

218.106 of this Part, or on and after the initial

start-up date, the owner or operator of a

subiect

coating line 

eubj

eat to the

limitations -of 

Section

218.204 and complying by means of Cootion 218.305

shall collect and record all of the following

information each day for each coating line and

maintain the information at 

the facility source

for

a period of three years:

A) The name and identification number of each

coating as applied on each coating line.

B)  The weight of VON per volume and the volume

of each coating (minus water and any

compounds which are specifically exempted

from the definition of VON) as applied each

day on each coating line.

C)  The daily-weighted average VON content of all

coatings as applied on 

each coating line as

defined in Section 218.104 of this Part.

3)  On and after a date consistent with Section

218.106 of this Part, the owner or operator of a

subject coating line shall notify the Agency in

the following instances:

A)  Any record showing violation of Section

218.205 of this Part shall be reported by

sending a copy of such record to the Agency

within 30 days following the occurrence of

the violation.

B)  At least 30 calendar days before changing the

method of compliance with this subpart from

Section 218.205 of this Part to Section

218.204 or Section 218.207 of this Part, the

owner or operator shall comply with all

requirements of subsection (c) (1) or (e) (1)

of this Section, respectively. Upon changing

the method of compliance with this subpart

from Section 218.205 to Section 218.204 or

Section 218.207 af this Part, the owner or

operator shall comply with all requirements

of subsection (c) or (e) of this Section,

respectively.

e)  Any owner or operator of a coating line subject to the

limitations of Section 218.207 of this Part and

complying by means of Section 218.207(c), (d), (e),

218

(f), (g) or (h) of this Part shall comply with the

following:

1)  By a date consistent with Section 218.106 of this

Part, or upon initial start-up of a new coating

line, or upon changing the method of compliance

for an existing coating line from Section 218.204

or Section 

218.205 

of this Part to Section 218.207

of this Part, the owner or operator of the subject

coating line shall perform all tests and submit to

the Agency the results of all tests and

calculations

necessary to demonstrate that the

subject coating line will be in compliance with

Section 218.207 of this Part on and after a date

consistent with Section 218.106 of this Part, or

on and after the initial start—up date.

2)  On and after a date consistent with Section

218.106 of this Part, or on and after the initial

start-up date, the owner or operator of a subiect

coating line subject to the limitations of Ccotion

.218.207 

and complying by moans of Cootion

218.207(c), (d), (c), (f), (g), or (h) shall

collect and record all of the following

information each day for each coating line and

maintain the information at the facilitysource for

a period of three years:

A) The weight of VOM per volume of coating

solids as applied each day on each coating

line, if complying pursuant to Section

218.207(b) (2) of this Part.

B)  Control device monitoring data.

C)  A log of operating time for the capture

system, control device, monitoring equipment

and the associated coating line.

D)  A maintenance log for the capture system,

control device and monitoring equipment

detailing all routine and non—routine

maintenance performed including dates and

duration of any outages.

3)  On and after a date consistent with Section

218.106 of this Part, the owner or operator of a

subject coating line shall notify the Agency in

the following instances:

A)

Any record

showing violation of Section

218.207 of this Part shall be reported by

219

sending a copy of such record to the Agency

within 30 days following the occurrence of

the violation.

B)  At least 30 calendar days before changing the

method of compliance with this Subpart from

Section 218.207 of this Part to Section

218.204 or Section 218.205 of this Part, the

owner or operator shall comply with all

requirements 

of subsection (c) (1) or (d) (1)

of this Section, respectively. Upon changing

the method of compliance with this subpart

from Section 218.207 of this Part to Section

218.204 or Section 218.205 of this Part, 

the

owner or operator shall comply with all

requirements of subsection (c) or (d) of this

Section, respectively.

fi

Any

owner or operator of a primer surfacer operation or

topcoat operation subiect to the limitations of Section

218.204(a) (2) or (a)(3) of this Part shall com~1vwith

the following:

~J.

By a date consistent with Section 218.106 of 

this

Part, or upon initial start—up pf a new coating

operation, the owner or operator of a subiect

coating operation shall certify to the Agency that

the operation will be in compliance with Section

218.204 of this Part on and after a date

consistent with Section 218.106 of this Part. or

on and after the initial start-up date. Such

certification shall include:

~j The name and identification number of each

coating operation which will comply by means

of Section 218.204(a) (2) and (a)(3) of this

Part and the name and identification number

of each coating line in each coating

operation.

~j.. The name and identification number of each

coating as applied on each coating line in

the coating operation.

~j The weight of VON ~er volume of each 

coating

(minus water and any compounds which are

specifically exempted from the definition of

VOM) as a~~1iedeach day on each coating

line.

Qj The transfer efficiency and control

efficiency measured for each coating line.

220

~j Test reports, including raw data and

calculations documenting the testing

performed to measure transfer efficiency and

control efficiency.

fi

The instrument or method 

by which the owner

~ operator will accurately measure or

calculate the volume 

of each coating as

applied each day

on each coating line.

Q~

The method by which the owner or operator

will create

and maintain records each day as

required in subsection (f) (2) below.

lii

An example format for presenting the records

required in subsection (f1 (2) below.

21

On and after a date consistent with Section

218.106 of this Part, or on and after the initial

start—up date, the owner or operator of a 

subiect

coating operation shall collect and record all of

the following information

each day for each

operation and maintain the information at the

source for a period of three years:

~1

All information necessary to calculate the

daily-weighted average VON emissions from the

coating operations in kg (lbs) ~er 1 (gal) 

pf

coating solids deposited in accordance with

the proposal submitted, and approved pursuant

to Section 218.204(a) (2) or (a)’(3) of this

Part including:

ii.  The name and identification number of

each

coating as applied on each coating

operation.

jjj The weight of VON per volume of each

coating (minus water and any compounds

which are specifically exempted from the

definition of VON) as a~p1iedeach day

on each coating operation.

~j ~f a control device(s) is used to control VON

emissions, control device monitoring data; a

log of operating time for the capture system.

control device, monitoring equiPment and the

associated coating operation; and a

maintenance log for the capture system~

control device and monitoring equipment.

detailing all routine and non-routine

221

maintenance performed includina dates and

duration of any outages.

~  On and after a date consistent with Section

218.106 of 

this

Part or on and after the initial

start-up 

date. the owner or operator of a

subiect

coatina operation shall determine and record the

daily VOM emissions in kg (ibs) Per 1 (gal) of

coating solids deposited 

in accordance with

the

pro~osa1submitted and a~~rovedpursuant to

Section 218.204(a) (2) or (p1(3) 

of this Part

within 10 days from the end of the month and

maintain this information at the source for a

period of three years.

~J.

On and after 

a date consistent with

Section

218.106 of this Part, the owner or operator of a

subiect coating operation shall notify the Agency

in the followina instances:

~  Any record showing a violation of Section

218.204(a) (2) or (a)(3) of this Part shall be

reported by sending a 

~ppy 

of such record to

the Aaency within 15 dave from the end of the

month in which the violation occurred.

~j The owner or operator shall notify the Agency

of any chanae to the operation at least 30

days before the

chanae is effected. The

Aaencv shall determine whether or not

compliance testing is required. If the

Aaencv determines that compliance testina is

reaujred, then the owner or

operator shall

submit a testing proposal to the Agency

within 30 days and test within 30 days of the

aP~rova1of the ~ro~osal by the Aaencv and

USEPA.

(Source: Amended at —  

Ill. Reg.

effective 

____________

_______________________)

SUBPART G:

USE OF ORGANIC MATERIAL

Section 218.301  

Use of Organic Material

No person shall cause or allow the discharge of more than 3.6

kg/hr (8 lbs/hr) of organic material into the atmosphere from any

emission courocunit, except as provided in Sections 218.302,

218.303, 218.304 of this Part and the following exception: If no

odor nuisance exists the limitation

of this Subpart shall apply

only to photocheinically reactive material.

222

(Source: Amended at  

Ill. Reg. 

______,

effective 

____________

_______________________)

Section 218.302

Alternative Standard

Emissions of organic material in excess of those permitted by

Section 218.301 

of this Part are allowable

if such emissions are

controlled by

one of the following methods:

a)  Flame, thermal or catalytic incineration so as either

to reduce such emissions to 10 ppm equivalent methane

(molecular weight 16) or less, or to convert 85 percent

of the hydrocarbons to carbon dioxide and water; or,

b)  A vapor recovery system which adsorbs and/or condenses

at least 85 

percent of the total uncontrolled organic

material that would otherwise be emitted to the

atmosphere; or,

C)   Any other air pollution control equipment approved by

the Agency and approved by the USEPA as a SIP revision

capable of reducing by 85 percent or more the

uncontrolled organic material that would be otherwise

emitted to the atmosphere.

(Source: Amended at  

Ill. Reg. 

______,

effective 

____________

_________________________ )

Section 218.303  

Fuel Combustion Emission CourccsUnits

The provisions of Sections 218.301 and 218.302 of this Part shall

not apply to fuel combustion emission souroceunits.

(Source: Amended at  

Ill. Reg.    

effective 

____________

_________________________ )

Section 218.304  

Operations with Compliance Program

The provisions of Sections 218.301 and 218.302 of this Part shall

not apply to any owner, operator, user or manufacturer of paint,

varnish, lacquer, coatings or printing ink whose compliance

program and project completion schedule, as required by 35 Ill.

Athn. Code 201, provided for the reduction of organic material

used in such

process to 20 percent or less of total volume by May

30, 1977.

(Source:

Amended at

Ill. Reg.

______,

effective

____________

____________________)

223

SUBPART H:

PRINTING AND PUBLISHING

Section 218.401  

Flexographic and Rotogravure Printing

a)  No owner or operator of a subject flexographic,

packaging rotogravure or publication rotogravure

printing line shall apply at any time any coating or

ink

unless the VON content does not exceed the

limitation specified in either subsection (a) (1) or

(a) (2) 

below. Compliance with this Section must be

demonstrated through the applicable coating or 

ink

analysis test methods and procedures specified in

Section 218.105(a) of this Part and 

the

recordkeeping

and reporting requirements specified in Section

218.404(c) 

of this Part. As an alternative to

compliance with this subsection, a subject printing

line may meet the requirements of subsection (b) or (c)

below.

1)  Forty percent VON by volume of the coating and ink

(minus water and any compounds which are

specifically exempted from the definition of VOM),

or

2)  Twenty-five percent VON by volume of the volatile

content in the coating and 

ink.

b)  No owner or operator of a subject flexographic,

packaging rotogravure or publication rotogravure

printing line shall apply coatings or inks on the

subject printing line unless the weighted average, by

volume, VON content of all coatings and inks as applied

each day on the subject printing line does not exceed

the limitation specified in either subsection (a) (1)

(as determined by subsection (b) (l)j or subsection

(a)

(4~2,)) 

(as determined by subsection (b) (2)1.

Compliance with this subsection must be demonstrated

through the applicable coating or ink analysis test

methods and procedures specified in Section 218.105(a)

of this Part and the recordkeeping and reporting

requirements specified in 

Section 218.404(d) of this

Part.

1)  The following equation shall be used to determine

if the weighted average VON content of all

coatings and inks as applied each day on the

subject 

printing line exceeds

the limitation

specified in subsection (a) (1) of this Section.

n

224

Z Cj Lj~ (V51+ VVONJ)

VOM(j)(A)

n

E

L~ (V5j+ VVOMj)

i=4~i_

Where:

VOM(i) (A) 

The weighted average VON content in

units of percent VOM by volume of

all coatings and inks (minus water

and any compounds which are

specifically exempted from the

definition of VON) used each day,-z.

i

Subscript denoting a specific

coating or ink as applied~j.

n

The number of different coatings

and/or inks as applied each day on

a printing line7-i.

Cj

The VON content in units of percent

VON by volume of each coating or

ink

as applied (minus water and any

compounds which are specifically

exempted from the definition of

VOM)-~

The liquid volume of each coating

or ink as applied in units of 1

(gal),-j~.

Vsj

The volume fraction

of solids in

each coating or ink

as applied and

VVOMi

The volume fraction of VOM in each

coating or ink as applied.

2)  The following equation shall be used to determine

if the weighted average VON content of all

coatings and inks as applied each day on the

subject printing line exceeds the limitation

specified in subsection (a) 

(2) of this Section.

n

225

E C~Li V~j

VOM(j)(B)

i=i

n

E Li V~iy~

i=1

where:

VON(i) (B) 

The weighted average VON content in

units of percent VON by volume of

the volatile content of all

coatings and inks used each day~i.

i

Subscript denoting a specific

coating or ink as applied,-j..

n

The number of different coatings

and/or inks as applied each day on

each printing 1ine~-j.

Ci

The VON content in units of percent

VON by volume of the volatile

matter in each coating or ink as

app 1 ied,-~

Li

The liquid volume of each coating

or

ink

as applied in units of 1

(gal) and

The volume fraction of volatile

matter in each coating or ink as

applied.

C)   No owner or operator of a subject flexographic,

packaging rotogravure or publication rotogravure

printing line equipped with a capture system and

control device shall operate the subject printing line

unless the owner or operator meets the requirements in

subsection (c) (1), (c) (2), or (C) (3) and subsections

(C)

(4),

(C) (5) and (C) (6) below.

1)  A carbon adsorption system is used which, reduces

the captured VON emissions by at least 90 percent

by weight, or

2)  An incineration system is used which reduces the

captured VON emissions by at least 90 percent by

weight, or

3)  An alternative VON emission reduction system is

used which is demonstrated to have at least a

226

90 percent control device efficiency, approved by

the Agency and approved by USEPA as a SIP

revision, and

4) The, printing

line is equipped with a capture

system and control device that provides an overall

reduction in VON emissions of at least:

A)  75 percent where a publication rotogravure

printing line is employed, or

B)  65 percent where a packaging rotogravure

printing line is employed, or

C)  60 percent where a flexographic printing line

is employed, and

5)  The control device is equipped with the applicable

monitoring equipment specified in Section

218.105 (d) (2) of this Part and7 except as provided

in Section 218.105(d) (3) of this Part, the

monitoring equipment is installed, calibrated,

operated and maintained according to vendor

specifications at all times the control device is

in use, and

6)  The capture system and control device are operated

at all times when the subject printing line is in

operation. The owner or operator shall

demonstrate compliance with this subsection by

using the applicable capture system and control

device test methods and procedures specified in

Section 218.105(c) through Section 218.105(f) ~

this Part and by complying with the recordkeeping

and reporting requirements specified in Section

218.404(e) of this Part.

(Source: Amended at 

—

Ill. Reg.    

effective 

____________

Section 218.402  

Applicability

a)  The limitations of Section 218.401 of this Part apply

to all flexographic and rotogravure printing lines at a

subject facilitysource. All faciliticosources with

flexographic and/or rotogravure printing lines are

subject facilitiposources unless:

Total maximum theoretical emissions of VON

from

all flexographic and rotogravure printing line(s)

(including solvents used for cleanup operations

associated with flexographic and rotogravure

227

printing line(s)) at the facilitysource never

exceed 90.7 Mg (100 tons) per calendar year before

the application of capture systems and control

devices, or

A federally enforceable construction permit or SIP

revision for all flexographic and rotogravure

printing line(s) at a facilitysource requires the

owner or operator to limit production or capacity

of these printing line(s) to reduce total VOM

emissions from all flexographic and rotogravure

printing line(s) to 90.7 Mg (100 tons) or less per

calendar year before the application of capture

systems and control devices.

b)  Upon achieving compliance with this Subpart, the

omipoign ocuroc 

flexoaraphic and rotogravure

printing lines are not required to meet Subpart G

(Sections 218.301 or ~-3~2l8.~02 of this Part).

Emiooion aourcco Flexoaraphic and rotoaravure printing

lines exempt from this Subpart are subject to Subpart G

(Sections 218.301 or &Z~.~8-02Q~this Part).

Rotogravure or flexographic equipment used for both

roll printing and paper coating is subject to this

Subpart.

c)  Once subject to the limitations of Section 218.40l~, a

flexographic or rotogravure printing line is always

subject to the limitations of Section 218.401 of this

Part.

Any

owner or 

operator of any flexographic

or

rotogravure 

printing line that is exempt

from the

limitations of Section 218,401 of this Part because of

the criteria ‘in this Section is subject to the

recordkeeping and reporting requirements specified in

Section 218.404(b) of this Part.

(Source: Amended at 

—

Ill. Reg.    

effective 

____________

_________________________ )

Section 218.403  

Compliance 

Schedule

Every owner or operator of a flexographic and/or rotogravure

printing

line shall comply with the applicable requirements of

Section 218.401 and Section 218.404 

of this Part in accordance

with the applicable compliance schedule specified in subsection

(a), (b), (c) or (d) below:

a) No owner or

operator of a flexographic or rotogravure

printing line which is exempt from

the limitations of

Section 218.401 of this Part because of the criteria in

228

Section 218.402 of this Part shall operate said

printing line on or after a date consistent with

Section 218.106 of this Part, unless the owner or

operator has complied with, and continues to comply

with, Section 218.404(b) of this Part.

b)  No owner or operator of a flexographic or rotogravure

printing line complying by means of Section 218.401(a)

of this Part shall operate said printing line on or

after a date consistent with Section 218.106 of this

Part, unless the owner or operator has complied with,

and continues to comply with, Section 218.401(a) and

Section 218.404(c) of this Part.

c)  No owner or operator of a flexographic or rotogravure

printing line complying by means of Section 218.401(b)

of this Part shall

operate said printing line on or

after

a date consistent with Section 218.106 of 

this

Part, unless the owner or operator has complied with,

and continues to

comply with, Section 218.401(b) and

Section 218.404(d) of this Part.

d)  No owner or operator of a flexographic or rotogravure

printing line complying by means of Section 218.401(c)

of this Part shall operate said printing line on or

after a date consistent with Section 218.106 of this

Part, unless the owner or operator has complied with,

and continues to comply with, Section 218.401(c) and

Section 218.404(e) of this Part.

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

____________

_________________________ )

Section 218.404  

Recordkeeping and Reporting

a)  The VON content of each coating and ink and the

efficiency of each capture system and control device

shall be determined by the applicable test methods and

procedures specified in Section 218.105 of this Part to

establish the records required under this Section.

b) Any owner

or operator of a printing line which is

exempted from the limitations of Section 218.401 Q~.

this Part because of the criteria in Section 218.402 

~f

this Part shall comply with the following:

1)  By a date consistent with Section 218.106 of this

Part, the owner or operator of a facility

flexoaraphic and rotogravure trintina line to

which this subsection is applicable shall certify

to the Agency that the facility flexoaraphic and

rotogravure ~rintjng line is exempt under the

229

provisions of Section 218.402 of this Part.

Such

certification shall include:

A)  A declaration that the facilityflexoaraphic

and rotoaravure printing line is exempt from

the limitations of the criteria in Section

218.401 of this Part because of Section

218.402 of this Part, and

B)  Calculations which demonstrate that total

maximum theoretical emissions of VON from all

flexographic and rotogravure printing lines

at the faoilitysource never exceed 90.7 Mg

(100 tons) per calendar year before the

application of capture systems and control

devices. Total maximum theoretical emissions

of VON for a flexographic or rotogravure

printing facilitysource is the 

sum

of maximum

theoretical emissions of VON from each

flexographic and rotogravure printing line at

the facilitysource. The following equation

shall be used to calculate total maximum

theoretical emissions of VON per calendar

year before the application of capture

systems and control devices for each

flexographic and rotogravure printing line at

the facilitysource:

EpAXB+ 1095 (CxDxFI

where:

Ep

Total maximum theoretical emissions

of VON from one flexographic or

rotogravure printing line in units

of kg/year (lbs/year)Tj~.

A

Weight of VON per volume of solids

of the coating or 

ink

with the

highest VON content as applied each

year on the printing line in units

of kg VOM/l (lbs VON/gal) of

coating or ink solids7~a*,4

B

Total volume of solids for all

coatings and inks that can

potentially be applied each year on

the printing line in units of

1/year (gal/year). The instrument

and/or method by which the owner or

operator accurately measured or

230

calculated the volume of each

coating and ink as applied and the

amount that can potentially be

applied each year on the printing

line shall be described in the

certification to the Agency-j.

Weight of VOM per volume of

material for the c1eanu~material

or solvent with the highest VON

content as used each year on the

printina line in units of Ka/1 (lbs

VON/gall

of such material;

The areatest volume of cleanup

material or solvent used in any

8—hour period and

The highest fraction of cleanup

material or solvent which is not

recycled or recovered for offsite

disposal during any 8-hour period.

2)  On and after a date consistent with Section

218.106 

of this Part, the owner

or operator of a

facility flexographic and rotogravure printing

line referenced in this subsection shall collect

and record all of the following information each

year for each printing line and maintain the

information at the facilitysource for a period of

three years:

The name and identification

number 

each

coating and ink as applied on each printing

line.

B)  The VON content and the volume of each

coating and ink as applied each year on each

printing line.

3)  On and after a date consistent with Section

218.106 of this Part, the owner or

operator of a

faaility flexographic and rotoaravure ~rintina

line exempted from the limitations of Section

218.401 of this Part because of the criteria in

Section 218.402 of this Part shall notify the

Agency

of any record showing that total maximum

theoretical emissions of VON from all printing

lines exceed 90.7 Mg (100 tons) in any 

calendar

year before the application of capture systems and

control devices by sending a copy of such record

231

to the Agency within 30 days after the exceedance

occurs.

Any owner

or operator of a printing line subject to the

limitations of Section 218.401 of this Part and

complying by means of Section 218.401(a) of this Part

shall comply with the following:

1)  By a date consistent with Section 218.106 of this

Part, or upon initial start-up of 

a new printing

line,

or upon changing the method of compliance

from an existing subject printing line from

Section 218.401(b) or Section 218.401(c) of this

Part to Section 218.401(a) of 

this Part,

the owner

or operator of a subject printing line shall

certify to the Agency that the printing line will

be in compliance with Section 218.401(a), of this

Part on and after a date consistent with Section

218.106 of this Part, or on and

after the initial

start-up date.

Such certification shall include:

A)  The name and identification number of each

coating and 

ink

as applied on each printing

line.

The VON content of each coating

and

ink

applied each day

on each printing line.

2)  On and after a date consistent with Section

218.106 of this Part, or on and after the initial

start—up date, the owner or operator of a printing

line

subject to the limitations of Section 218.401

of this Part and

complying by means of Section

218.401(a) of this Part

shall collect and record

all of the following information each day for each

coating line and maintain the

information at the

facilitysource for a period of three years:

A)  The name and identification number 

of each

coating and 

ink

as applied on each printing

line.

B)  The VON content of each coating and ink as

applied each day on each printing line.

3)  On and after a date consistent with Section

218.106 of this Part, the owner or operator of a

subject printing line shall notify the Agency in

the following instances:

A)

Any

record showing violation of Section

218.401(a) of this Part shall be reported by

232

sending a copy of such record to the Agency

within 30 days following the occurrence of

the violation.

B)  At least 30 calendar days before changing the

method of compliance with Section 218.401 Q~

this Part from Section 218.401(a) of this

Part to Section 218.401(b) or (c) of this

Part, the 

owner or operator shall comply with

all requirements of subsection (b) (1) or

(a) (1) (d) (1) or (e)(1l of this Section,

respectively. Upon changing the method of

compliance with Section 218.401 of this Part

from Section 218.401(a) of this Part to

Section 218.401(b) or (c) of this Part, the

owner or operator shall

comply with all

requirements of subsection -~~-~jor 4e)-.j~j

of this Section, respectively.

Any owner or operator of a printing line subject to the

limitations of Section 218.401 of this Part 

and

complying by means of Section 218.401(b) shall comply

with the following:

1)  By a date consistent with Section 218.106 of this

Part,

or upon initial start-up of a new printing

line, or upon changing the method of compliance

for an existing subject printing line from Section

218.401(a) or (C)  of this Part to Section

218.401(b) of this Part, the owner or operator of

the subject printing line shall certify to the

Agency that the printing line will be in

compliance with Section 218.401(b) of this Part on

and after a date consistent with Section 218.106

of this Part, or on and after the initial start—up

date. Such certification shall include:

A) The name and identification number of each

printing line which will comply by means of

Section 218.401(b) of this Part.

B)  The name and identification number of each

coating and

ink

available for use on each

printing line.

C)  The VON content of each coating and ink as

applied each day on each printing line.

D)  The instrument or method by which the owner

or operator will accurately measure or

calculate the volume of each coating and ink

as applied each day on each printing line.

233

E)  The method by which the owner or operator

will

create and maintain records each day as

required in subsection 4~)-jQ,j(2) of this

Section.

F)  An example of the format in which the records

required in subsection 4~J~j.(2)of this

Section will be kept.

2)  On and after a date consistent with Section

218.106 of this Part, or on and after the initial

start-up date, the owner or operator of a printing

line subject to the limitations of Section 218.401

of this Part and complying by means of Section

218.401(b) of this Part shall collect and record

all of the following information each day for each

printing line and maintain the information at the

facilitysource for a period of three years:

A)  The name and identification number of each

coating and ink as applied on each printing

line.

B)  The VON content and the volume of each

coating and ink as applied each day on each

printing line.

C)  The daily-weighted average VON content of all

coatings and inks as applied on each printing

line.

3)  On and after a date consistent with Section

218.106 of this Part, the owner

or operator of a

subject printing line shall notify the Agency in

the following instances:

A) Any record showing violation of Section

218.401(b) of this Part shall be reported by

sending a copy of such

record to the Agency

within 30 days following the occurrence of

the violation.

B)  At least 30 calendar days before changing the

method of compliance with Section 218.401 ~

this Part from Section

218.401(b) of this

Part to Section 218.401(a) or 218.401(c) ~

this Part, the owner or operator shall comply

with all requirements of subsection (c) (1) or

(e) (1) of this Section, respectively. Upon

changing the method of compliance with

Section 218.401 of this Part from Section

218.401(b) of this Part to Section 218.401(a)

234

or (c) of this Part, the owner or operator

shall comply with all requirements of

subsection

(C) or (e) of this Section,

respectively.

e)  Any owner or operator of a printing line subject to the

limitations of Section 218.401 of this Part and

complying by means of Section 218.401(c) of this Part

shall comply with the following:

1)  By a date consistent with Section 218.106 of this

Part, or upon initial start-up of a new printing

line, or upon changing the method of compliance

for an existing printing line from Section

218.401(a) or (b) of this Part to Section

218.401(c) 

of this Part, the owner or operator of

the subject printing line shall perform all tests

and

submit to the Agency the results of all tests

and calculations necessary to demonstrate that the

subject printing line will be in compliance with

Section 218.401(c) of this Part on and after a

date consistent with Section 218.106

of this Part,

or on and after the initial start—up date.

2)  On and after a date consistent with Section

218.106 of this Part, or on and after the initial

start—up date, the owner or operator of a printing

line subject to the limitations of Section 218.401

of this Part and

complying by means of Section

218.401(c) of 

this Part shall collect and

record

all of the following information each day for each

printing line and maintain the information at the

facility for a period of three years:

Control device monitoring data.

B)  A log of operating time for the capture

system, control device, monitoring equipment

and the associated printing line.

C)  A maintenance log for the capture system,

control device and monitoring equipment

detailing all routine and non—routine

maintenance performed including dates and

duration of any

outages.

3)  On and after a date consistent with Section

218.106 of this Part, the owner

or operator of a

subject printing line shall notify the Agency in

the following instances:

235

A)

Any

record showing violation of Section

218.401(c) of this Part, shall be reported by

sending a copy of such record to the Agency

within 30 days following the occurrence of

the violation.

B)  At least 30 calendar days before changing the

method of compliance with Section 218.401 2Z.

this Part from Section 218.401(c) of this

Part to Section 218.401(a) or (b) of this

Part, the owner or operator shall comply with

all requirements of subsection (c) (1) or

(d) (1) of this Section, respectively. Upon

changing the method of compliance with

Section 218.401 of this Part from Section

218.401(c) of this Part to Section 218.401(a)

or (b) of this Part, the owner or operator

shall comply with all requirements of

subsection (c) or (d) of this Section,

respectively.

(Source: Amended at  

Ill. Reg.    

effective 

____________

_________________________ )

Section 218.405  

Heatset-Web-Offset Lithographic Printing

a)  Applicability

1)  The limitations of subsection (b) below apply to

all heatset-web-offset lithographic printing lines

(including solvents used for cleanup operations

associated with the heatset—web-off set

lithographic printing line(s)) at a subject

facilitysource. All facilitico sources with

heatset-web-off set lithographic printing lines are

subject faciliticosources unless:

Total maximum theoretical emissions of VON

from all heatset-web-offset lithographic

printing lines (including solvents used for

cleanup operations associated with the

heatset-web-offset 1ithoara~hicprinting

line(s)) at the facilitysource never exceed

90.7 Mg 

(100 tons) per calendar year in the

absence of air pollution control equipment,

or

B)  A federally enforceable conotruotion permit

or SIP revision for

all heatset-web-off set

lithographic printing linesjg~at a facility

source requires the owner or operator to

limit production or capacity of these

236

printing line(s) to reduce total VON

emissions from all heatset—web—of feet

lithographic printing line(s) to 90.7 Mg

(100 tons) per calendar year or less in the

absence of air pollution control equipment,

and

Any owner or operator of any heatset—web—of feet

lithographic printing line that is exempt from the

limitations in subsection (b) of this Section

because of the criteria in subsection (a) (1) ~

this Section shall be subject to 

the recordkeeping

and reporting requirements in subsection (C) (1) QL

this Section.

Specific Provisions.

No owner or operator of a subject

heatset-web-off set printing line may cause or allow the

operation of the subject beatset-web-offset printing

line unless the owner

or operator meets the

requirements in subsection (b) (1) or (b) 

(2)

and the

requirements in subsections (b) (3) and (b) (4) below.

1)  An afterburner system is installed and operated

that reduces 90 percent of the VON emissions from

the dryer exhaust, or

2)  The fountain solution contains no more than

8 percent, by weight, 

of VON and a condensation

recovery system is installed and operated that

removes at least 75 percent of the non-isopropyl

alcohol organic materials from the dryer exhaust,

and

3)  The control device is equipped with the applicable

monitoring equipment specified in Section

218.105(d) (2) of this Part and the monitoring

equipment is installed, calibrated, operated and

maintained according to vendor specifications at

all times the control device is in use, and

The control device is operated at all times when

the subject printing line is in operation.

The

owner or operator shall demonstrate compliance

with this Section by using the applicable test

methods and procedures specified in Section

218.105(a), (d), and (f) ‘of this Part and by

complying with the recordkeeping and reporting

requirements specified in subsection (C)  below.

c)  Recordkeeping and Reporting. The VON content of each

fountain solution and ink and 

the efficiency of each

control device shall be determined by the applicable

237

test methods and procedures specified in Section

218.105 of this Part to establish the records required

under this subsection.

Any owner or operator of a printing line which is

exempted from the limitations of subsection (b) ~

this Section because of the criteria in subsection

(a) of this Section shall comply with

the

following:

By a date consistent with Section 218.106

~L

this Part,

the owner or operator of a

facility

heatset— web-offset 1ithoara~hic

printing line to which subsection

(C) (1)Q.~

this Section is applicable shall certify to

the Agency that the facility heatset-web-

off set lithographic printing ‘line is exempt

under the provisions of subsection (a) ~

this Section.

Such certification

shall

include:

A declaration that the facility heatset-

web-off set lithographic printing line is

exempt from the limitations of

subsection (b) of this Section because

of the criteria in subsection (a) ~

this Section, and

ii) Calculations which demonstrate that

total maximum theoretical emissions of

VON from all

heatset-web—offset

lithographic printing lines at the

facilitysource

never exceed 90.7 Mg

(100 tons) per calendar year before the

application of air pollution control

equipment. Total maximum theoretical

emissions of VON for a heatset—web-

off set lithographic printing facility

source is the sum

of maximum theoretical

emissions of VON from each beatset—web-

of fset lithographic printing line at the

facilit-ysource. The following equation

shall be used to calculate total maximum

theoretical emissions of VON per

calendar year in the absence of air

pollution control equipment for each

heatset-web-off set lithographic printing

line at the f-acilitysource.

Ep (A X B) + (C 

D)+1095 (F X G X H)

100

238

where:

Total maximum 

theoretical

emissions of VON from one

heatset-web-off set printing

line in units of kg/year

(1bs/year),-~.

Weight of VON per volume of

solids of ink with the highest

VON content as applied each

year on the printing line in

units of kg VON/i (lbs

VON/gal) of solids, andj.

Total 

volume of solids for all

inks that can potentially be

applied each year on the

printing line in units of

1/year (gal/year). The

instrument or method by which

the owner or operator

accurately measured or

calculated the volume of each

ink

as applied and the amount

that can potentially be

applied each year on the

printing line shall be

described in the certification

to the Agency-a

C

The weight percent VON of the

fountain solution with the

highest VON content--j

D

The total volume of fountain

solution that can potentially

be used each year on the

printing line in units of

1/year (gal/year). The

instrument and/or method by

which the owner or operator

accurately measured or

calculated the volume of each

fountain solution used and the

amount that can potentially be

used each year on the printing

line shall be described in the

certification

to the Agency~-j~.

239

£

Weight of VON ~er volume of

material for the cleanup

material or solvent with the

highest VOM content as used

each year on the printina 1in~

in units of Ka/l (lbs VOM/aalI

of such material:

The greatest volume of cleanup

material or solvent used in

any 8-hour period and

The highest fraction of

cleanup material or solvent

which is not recycled or

recovered for offsite disposal

during any 8-hour ~erjod.

B)  On and after a date consistent with Section

218.106 of this Part, the owner or operator

of a facilityheatset—web-offset 1ithogra~hic

printing line to which subsection (c) (1) ~

this Section is applicable shall collect and

record all of the following information each

year for each printing line and maintain the

information at the facilitysource for a

period of three years:

i)  The name and identification of each

fountain solution and ink as applied on

each printing line.

ii) The VON content and the volume of each

fountain solution and ink as applied

each year on each printing line.

C)  On and after a date consistent with Section

218.106 of this Part, the owner or operator

of a facilitysource exempted from the

limitations of subsection (b) of this Section

because of the criteria in subsection (a) ~

this Section shall notify the Agency of any

record showing that total maximum theoretical

emissions of VOM from all printing lines

exceed 90.7 Mg (100 tons) in any calendar

year in the 

absence of air pollution control

equipment by sending a copy of such record to

the Agency within 30 days after 

the

exceedance occurs.

2)

Any

owner or operator of a printing line subject

to the limitations of subsection (b) of this

240

Section and complying by means of subsection

(b) (1) of this Section shall comply with the

following:

By a date consistent with Section 218.106 Q.~

this Part, or upon initial start-up of a new

printing line, or upon changing the method of

compliance for an existing printing line from

subsection (b)(2) to subsection 

(b)(1) QZ.

this Section the owner or operator of the

subject printing line shall perform all tests

and submit to

the Agency the 

results of all

tests and calculations necessary to

demonstrate that the subject printing line

will be in compliance with subsection (b) (1)

of this Section on and after a date

consistent with Section 218.106 of this Part,

or on and after the initial start-up date.

B)  On and after a date consistent with Section

218.106 of this Part, or on and after the

initial start-up date, the owner or operator

of a printing line subject to the limitations

of subsection (b) of this Section and

complying by means of subsection (b) (1) 

Qf.

this Section shall collect and record the

following information each day for each

printing line and maintain the information at

the facilitysource for a period of three

years:

i)  Control device monitoring data.

ii) A log of operating time for the control

device, monitoring equipment and the

associated printing line.

iii) A maintenance log for the control device

and monitoring equipment detailing all

routine and nonroutine maintenance

performed including dates and duration

of any outages.

C)  On and after a date consistent with Section

218.106 of this Part, the owner or operator

of a subject printing line shall notify the

Agency in the following instances:

i)  Any record showing violation of

subsection (b) (1) of this Section shall

be reported by sending a copy of such

record to the Agency within 30 days

24.

following the occurrence of the

violation.

ii) At least 30 calendar days before

changing the method of compliance with

subsection (b) of this Section from

subsection (b)(1)to (b)(2) of this

Section, the owner or operator shall

comply with all requirements of

subsection (c) (3) (A) of this Section.

Upon changing the method of compliance

with subsection (b) of this Section from

subsection (b) (1) to (b) (2) of this

Section, the owner or operator shall

comply with all requirements of

subsection (C) (3) of this Section.

3)

Any

owner or operator of a printing line subject

to the limitations of subsection (b) of this

Section and complying by means of subsection

(b) (2) of this Section shall comply with the

following:

A)  By a date consistent with Section 218.106 

Qf~

this Part, or upon initial start-up of a new

printing line, or upon changing the method of

compliance for an existing printing line from

subsection (b) (1) to (b) (2) of this Section

the owner or operator of the subject printing

line shall perform all tests and submit to

the Agency and the USEPA the results of all

tests and calculations necessary to

demonstrate that the subject printing line

will be in compliance with subsection (b) (2)

of this Section on and after a date

consistent with Section 218.106 of this Part,

or on and after the initial start-up date.

B)  On and after a date consistent with Section

218.106 of this Part, or on and after the

initial start-up date, the owner or operator

of a printing line subject to the limitations

of subsection (b) of this Section and

complying by means of subsection (b) (2) ~

this Section shall collect and record the

following information each day for each

printing line and maintain the information at

the facilitysource

for a period of

three years:

i)  The VON content of the fountain solution

used each day on each printing line.

242

ii)

A log of operating time for the control

device and the associated printing line.

iii) A maintenance log for the control device

detailing all routine and non—routine

maintenance performed including dates

and duration of any outages.

On and after a date consistent with Section

218.106 of this Part, the owner or operator

of a subject printing line shall notify 

the

Agency in the following instances:

i)

Any

record showing violation of

subsection (b) (2) shall be reported by

sending a copy 

of such record to the

Agency within 30 days following the

occurrence of the violation.

ii) At least 30 calendar days before

changing the method of compliance with

subsection (b) of this Section from

subsection (b) (2) to (b) (1) of this

Section, the owner or operator shall

comply with all requirements of

subsection (c) (2) (A) of this Section.

Upon changing the method of compliance

with subsection (b) of this Section from

subsection (b) (2) to (b) (1) of this

Section, the owner or operator shall

comply with all requirements of

subsection (C) (2) of this Section.

d)  Compliance Schedule. Every owner or operator of a

heatset-web-off set lithographic printing line shall

comply with the applicable requirements of subsections

(b) and (c) of this Section in accordance with the

applicable compliance schedule specified in subsection

(d) (1) 

(d) (2) 

or (d) (3) below:

1)  No owner or operator of a heatset—web—offeet

lithographic printing line which is exempt from

the limitations of subsection (b) of this Section

because of the criteria in subsection (a) of this

Section shall operate said printing line on or

after a date consistent with Section 218.106 ~

this Part, unless the owner or operator has

complied with, and continues to comply with,

subsection

-f~-~J(1)and 

(c)

(1) of this Part.

2)  No owner or operator of a heatset-web—offset

lithographic printing line complying by means of

243

subsection (b) (1) of this Section shall operate

said printing line on or after a date consistent

with Section 218.106 of this Part, unless the

owner or operator has complied with, and continues

to comply with, subsection (b) (2) (b) (1). (b) (3L

(b) (4) and

(C) (2) of this Section.

No owner or operator of a heatset—web—off set

lithographic printing line complying by means of

subsection (b) (2) of this Section shall operate

said printing line on or after a date consistent

with Section 218.106 of this Part, unless the

owner or operator has complied with, and continues

to comply with, subsection (b) (2). (b) (3). (b) (4)

~  (c) (3) of this Section.

(Source: Amended at 

—

Ill. Reg.

effective 

____________

_________________________)

SUBPART Q: LEAKS FROM SYNTHETIC ORGANIC CHEMICAL AND POLYMER

MANUFACTURING EQUIPMENT 

PLANT

Section 218.421  

General Requirements

The owner or operator of a plant which processes more than 3660

mg/yr (4033 tons/year) gaseous and light liquid VON, and whose

components are used to manufacture the synthetic organic

chemicals or polymers listed in Appendix A, shall comply with

this Subpart. The provisions of this Subpart are applicable to

components containing 10 percent or more by weight VOM as

determined by

ASTN method 

E-168, E-169 and E-260, incorporated by

reference in Section 218.112 of this Part. Those components that

are not process unit components are exempt from this Subpart. A

component shall be considered to be leaking if the VON is equal

to, or is greater than 10,000 ppmv as methane or hexane as

determined by USEPA Reference Method 21, as specified at 40 

CFR

60, Appendix A, incorporated by reference in Section 218.112 ~

this Part, indication of liquids dripping, or indication by a

sensor that a seal or barrier fluid system has failed. The

provisions of this Subpart are not applicable if the equipment

components are

used to produce heavy liquid chemicals only from

heavy liquid feed or raw materials.

(Source: Amended at  

Ill. Reg.    

effective 

____________

_______________________ )

Section 218.422  

Inspection Program Plan for Leaks

The owner or operator of a synthetic organic chemical or polymer

manufacturing plant subject to Section 218.421 of this Part 

shall

prepare an inspection program plan which contains, at a minimum:

244

a)  An identification of all components and 

the period in

which each will be monitored pursuant to Section

218.423 of this Part.

The format for the monitoring log required by Section

218.425 of this Part.

A description of the monitoring equipment to be used

when complying with Section 218.423 of this Part, and

d)  A description of the methods to be used to identify all

pipeline valves, pressure relief valves in gaseous

service, all leaking components, and components

exempted under Section 218.423+4-jj~ of this Part such

that they are obvious and can be located by both plant

personnel performing monitoring and Agency personnel

performing inspections.

(Source: Amended at  

Ill. Reg.    

effective     

)

Section 218.423  

Inspection Program for Leaks

The owner or operator of a synthetic organic chemical or polymer

manufacturing plant subject to this e.~ubpartshall, for the

purposes of detecting leaks, conduct a component inspection

program using the test methods specified in Method 21, 40 CFR 60,

Appendix A (1986), incorporated by reference in Section 218.112

of this Part, consistent with the following provisions:

a)  Test annually those components operated near extreme

temperature or pressure such that they would be unsafe

to routinely monitor and those components which would

require the elevation of monitoring personnel higher

than two meters above permanent worker access

structures or surfaces.

b)  Test quarterly all other pressure relief valves in gas

service, pumps in light liquid service, valves in light

liquid service and in gas service, and compressors.

c)  If less than or equal to 2 percent of the valves in

light liquid service and in gas service tested pursuant

to subsection (b) of this Section are found ~ 

leak

for five consecutive quarters, no leak tests shall be

required for three

consecutive quarters. Thereafter,

leak tests shall resume for the next quarter. If that

test shows less than or equal to 2 percent of the

valves in light liquid service and in gas service are

leaking, then no tests are required for the next

three quarters. 

If more than

2 percent are leaking,

then tests are required for the next five quarters.

245

d)  Observe visually all pump seals weekly.

e)  Test immediately any pump seal from which liquids are

observed dripping.

f)  Test any relief valve within 

24 hours after it has

vented to the atmosphere.

Routine instrument monitoring of valves which are not

externally regulated, flanges, and equipment in heavy

liquid service, is not required.

However, any valve

which is not externally regulated, flange or piece of

equipment in heavy liquid service that is found to be

leaking on the basis

of sight, smell or sound shall be

repaired as soon as practicable but no later than

30 days after the leak is found.

h) Test immediately after repair any component that was

found leaking.

i)  Within one hour of its detection, a weatherproof,

readily visible tag, in bright colors such as red or

yellow, bearing an identification number and the date

on which the leak was detected must be affixed on the

leaking component and remain in place until the leaking

component is repaired.

j)  The following components are exempt from the monitoring

requirements in this Section:

1)  Any 

component that

is in vacuum service, and

2)  Any pressure relief valve that is connected to an

operating flare header or vapor recovery device.

(Source: Amended at  

Ill. Reg. 

______,

effective 

____________

_________________________ )

Section 218.424  

Repairing Leaks

All leaking components must be repaired and retested as soon as

practicable but no later than 15 days after the leak is found

unless the

leaking component cannot be repaired until the process

unit is shut down. Records of repairing and retesting must be

maintained in accordance with Section 218.425 and 218.426 of this

Part.

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

____________

_____

)

Section 218.425  

Recordkeeping for Leaks

246

The owner or operator of a synthetic organic chemical

or polymer manufacturing plant shall maintain a leaking

components monitoring log which shall contain, at a

minimum, the following information:

1)  The name of the process unit where the component

is located;

2)  The type of component (e.g., valve, seal);

3)  The identification number of 

the component;

4)  The date on which a leaking component is

discovered;

5)  The date on which a leaking component is repaired;

6)

The date and 

instrument reading of ‘the recheck

procedure after a leaking component is repaired;

7)  A record of the calibration of the monitoring

instrument;

8)  The identification number of leaking components

which cannot be repaired until process unit

shutdown; and

9)  The total number of valves in light liquid service

and in gas

service inspected; the total number and

the percentage of these valves found leaking

during the monitoring period.

b)  Copies of the monitoring log shall be retained by the

owner or operator for a minimum

of two years after the

date on which the record was made or the report was

prepared.

C)   Copies of the monitoring log shall be made available to

the Agency~

upon verbal or written request~.prior to or

at the time of inspection pursuant to Section 4(d) of

the Environmental Protection Act (Act) (Ill. Rev. Stat.

1989~j,, ch. ill 1/2, pars. 1001 et seq.) 1415 ILCS 5/1

et sea.J at any reasonable time.

(Source:

Amended at

—

Ill. 

Reg.

______,

effective

____________

Section 218.426  

Report for Leaks

The owner or operator of a synthetic organic chemical or polymer

manufacturing plant subject to Section 218.421 through 218.430 91

this Part shall:

247

Submit quarterly reports to the Agency on or before

March 31, June 30, September 30, and December 31 of

each year, listing all leaking components identified

pursuant

to Section 218.423 of this 

Part but not

repaired within 15 

days, all leaking components

awaiting process unit shutdown, 

the total number of

components inspected, the type of components inspected,

and the total number of components found leaking, the

total

number of valves in light liquid service and in

gas service inspected and the number and percentage of

valves in light liquid service and in gas service found

leaking.

Submit a signed statement with the report attesting

that all monitoring and repairs were performed as

required under Section 218.421 through 218.427 of this

Part.

(Source: Amended at —  Ill. Reg. 

______,

effective 

____________

Section 218.427  

Alternative Program for Leaks

The Agency shall approve an alternative program of monitoring,

recordkeeping, or reporting to that prescribed in this Subpart

upon a demonstration by the owner or operator of such plant that

the alternative program will provide plantsource personnel and

Agency personnel with an equivalent ability to identify and

repair leaking components. Any alternative program can be

allowed if approved by the Agency and approved by the USEPA as a

SIP revision.

(Source: Amended at —  Ill. Reg.    

effective 

____________

_________________________ )

Section 218.428  

Open-Ended Valves

a)  Each open-ended valve shall be equipped with a cap,

blind flange, plug, or a second valve, except during

operations requiring fluid flow through the open-ended

valve.

b)  Each open-ended valve equipped with a second valve

shall be operated in a manner such 

that the valve on

the process fluid end is closed before the second valve

is closed.

C)   Components which are open—ended valves and which serve

as asainpling connection shall be controlled such that

they comply with subsection(c)(1). (c)(2) or (c)(3)

below. This requirement does not a~~lyto in-situ

sampling systems 

+

248

1)  A closed purge system or closed vent system shall

return purged process fluid to the process line

with no detectable VON emissions to the

atmosphere, or

2)  A closed purge system or closed vent system shall

collect and recycle purged process fluid to the

process line with no detectable VON emissions to

the atmosphere, or

3)  Purged process fluid shall be transported to a

control device that complies with the

requirements

of Section 218.429 of this Part. If a container is

used to transport purged process fluid to the

control device, the container shall be a closed

container designed and used to reduce the VON

emissions vented from purged process fluid after

transfer to no detectable VOM emissions as

determined by USEPA Reference Method 21. as

specified in 40 CFR 60. Appendix A (1990 or 1991)

incorporated by reference in Section 218.112 of

this Part. For purposes of this Section. the

phrase “after transfer” shall refer to the time at

which the entire amount of purged process fluid

resulting from a flushing or cleaning of the

sample line enters the container, provided.

however, that purged process fluid may be

transferred from the initial container to another

closed container prior to disposal. e.g., to a

bulk waste storage container.

43-

In oitu aampling systcms arc oxompt from ouboooti~..

(c).

(Source: Amended at 

—

Ill. Reg.    

effective 

____________

_________________________)

Section 218.429  

Standards for Control Devices

Control devices used to comply with Section 218.428(c) of this

Part shall comply with the following:

a)  If the control device is a vapor recovery system (for

example, condensers and adsorbers), it shall be

designed and operated to recover the VON emissions

vented to it with an efficiency of 95 percent or

greater.

1~) If the control device is an enclosed combustion 

device,

it shall be designed and operated to reduce the VON

emissions vented to it with an efficiency of 95 percent

249

or greater, or to provide a minimum residence time of

0.75 seconds at a minimum temperature of 816°C.

c)  If the control device is a flare, it shall:

Be designed for and operated with no visible

emissions as determined by USEPA Reference Method

22, 40 CFR 60, Appendix A (1986), incorporated by

reference in Section 218.112, except for periods

not to exceed a total of 

5 minutes during any 2

consecutive hours.

2)  Be operated with a pilot flame present at all

times and shall be monitored with a thermocouple

or any other equivalent device to detect the

presence of the pilot flame.

3)  Be steam-assisted, air assisted, or nonassisted.

Be used only with the net heating value of

the

gas

being combusted being 11.2 NJ/scm (300 Btu/scf) or

greater if the flare is steam—assisted or

air-assisted; or with the net heating value of the

gas being coinbusted being 7.45 NJ/scm or greater

if the flare is nonassisted. The net heating

value of the gas being combusted shall be

calculated using the following equation:

n

Hr

K E CiHj

i=1

Where:

Hr

Net heating value of the sample in

NJ/scm; where the net enthalpy per

mole of offgas is based on

combustion at 25°C and 760 mm Hg,

but the standard temperature for

determining the volume

corresponding to one mole is 20°C--j

Constant,

1.740 x

(1/ppm) (g-mole/scm) (MJ/Kcal)

where

standard temperature for (g—mole/scm) is

20°Crj

250

Cj

Concentration of sample component

i, in ppm, as measured by USEPA

Reference Method 18, 40 

CFR 60,

Appendix A (1986), and

ASTM D

2504-83, both incorporated by

reference in Section 218.112-ri

Hi

Net heat of combustion of sample

component 

kcal/g mole. The

heats of combustion may be

determined using ASTM D 

2382-83,

incorporated by reference in

Section 218.112 of this Part, if

published values are not available

or cannot be calculated.

5)  Steam-assisted and nonassisted flares shall be

designed and operated with an exit velocity, as

determined by dividing the volumetric flowrate (in

units of standard temperature and pressure), as

determined by USEPA Reference Method 2 or 2A, 40

CFR 60, Appendix A (1986) incorporated by

reference in Section 218.112 of this Part, as

appropriate; by the unobstructed (free) cross

sectional area of

the flare tip, less than 18

rn/sec (60 ft/sec).

Air-assisted flares shall be designed and operated

with an exit velocity less than the maximum

permitted velocity, Vmax,as determined by the

following equation:

Vmax  

8.706 + O.7OB4(Hr~.~

Vmax  

Maximum permitted velocity, m/see.j.

8.706

Constant-a

0.7084  

Constant,-~

Hr

The net heating value as determined

in subsection (C) (4) of this

section.

If the control device is a closed container, it shall

be designed and operated to reduce the VOM emicoionr3,

vented from

purged process fluid 

after transfer, to ne

detectable

von

omissions

pp

determined by USEPA

Reference Method 21 as -specified at 40

CF~4?0, Appendix

A(198?),incorporatodbyroferenoeinScotion~1S.112.

—

L~’

transfer” shall refer to the time at which the

entire

amount 

purged process fluid resulting from a

fluohing or cleaning of the

sample line enters 

the

closed container or containers including the final

251

container(s) prior to disposal-.

The following

information pertaining to closed vent systems and

control devices subiect to Section 218.429 shall be

maintained by the owner or operator. These records

shall be undated as necessary to describe current

operation arid eaui~ment. The records shall be retained

at p readily accessible location at the source for a

minimum of two years after the control device is

~ermanentlv shutdown.

j~ Detailed schematics, design specifications, and

pi~in~and instrumentation diagrams

2i~ The dates and description of any chanaes in desian

specifications;

A description of the parameter or parameters

monitored and recorded as reczuired in subsection

(f) (1) to ensure that the control devices are

operated and maintained in conformance with their

design and an explanation why that parameter (or

parameters) was selected for monitoring.

~nc

-owner

or operator or a oontrai. ucv1.cC 

BIla.L.L 

monitor

the control device to cnsurc that it is operated and

maintained in conformance with the manufacturer’s

speoificationa,

modified to thc partioular process

dcsign.

~)

The control device shall be operated at all times when

emissions may be vented to it.

~j. Owners and operators of control devices used to comply

with this Subpart shall monitor each control device to

ensure that the control device is operated and

maintained in conformance with its designs at all times

that emissions may be vented to it. This monitoring

shall be conducted in accordance with Section

218.429(d) (3). The records prepared as cart of this

monitoring activity shall include the dates of startup

and shutdown of control devices and identify periods

when_the_devices are not operated as designed,

including periods when a flare pilot light does not

have a flame.

gj The reauirements of subsections (d). (e) and (f) shall

not apply to a combustion device used for disposal of

puraed Process fluid which is subiect to the Burning of

Hazardous Waste in Boilers and Industrials Furnaces

(BIF) rules, 40 CFR Parts 260, 261. 264, 265. 266. and

270. or which is subiect to the Resource Conservation

and Recovery Act (RCRA) rules. 35 Iii. Adin. Code Parts

252

703. 720. 721, 724, 725. and 726. The owner or

operator of such combustion device located at the

source shall satisfy a~p1icableprovisions of the RCEA

or BIF rules.

(Source: Amended at  

Ill. Reg.    

effective 

____________

_______________________)

Section 218.430  

Compliance Date (Repealed)

The owner or operator of a synthetic organic chemical or polyae~

manufacturing plant subjoot to 35 Ill. Adm. Code 315.430 

throu~

215.438 as 

December 31, 1~)87shall have complied with the

standards and limitations of those Cootions no later than

IJCUCIaDCr .J~’-

.LJ~J.

(Source: Repealed at 

—

Ill. Reg.    

effective 

___________

SUBPART R: PETROLEUM REFINING 

AND RELATED

INDUSTRIES;

ASPHALT 

MATERIALS

Section 218.441

Petroleum Refinery Waste Gas Disposal

a)  Except as provided in subsection (b) or (c) of this

Section, no person shall cause or allow the discharge

of organic materials in excess of 100 ppm equivalent

methane (molecular weight 16.0) into the atmosphere

from:

1)

Any

catalyst regenerator of a petroleum cracking

system; or

2)

Any

petroleum fluid coker; or

3)

Any

other waste gas stream from any petroleum or

petrochemical manufacturing process.

b)  Exception. Existing sources subject to subsection

(a) (3) of this Section may, alternatively, at their

election, comply with the organic material emission

limitations imposed by 35 Ill.

Adm. 

Code 21~.301 or

21~4.302;provided, however, that there shall be no

increase in emissions from such sources above the level

of emissions in existence on May 3, 1979.

c)  New Sources. Sources subject to subsection (a) (3) Q~

this Section, construction of which commenced on or

after January 1, 1977, may, at their election, comply

with the following emission limitations:

253

1)  A maximum of eight pounds per hour of organic

material; or

2)  Emission of organic material in excess of the

limitation of subsection (c) (1) of this Section is

allowable if such emissions are controlled by air

pollution control methods or equipment approved by

the Agency capable of reducing by 85 percent or

more the uncontrolled organic material that would

otherwise be emitted to the atmosphere. Such

methods or equipment must be approved by the

Agency and approved by the USEPA as a SIP

revision.

(Source: Amended at 

—

Ill. Reg. 

______,

effective

____________

_______________________ )

Section 218 

•

443

Wastewater (Oi’/Water) Separator

No owner or operator of a petroleum refinery shall operate any

wastewater (oil/water) separator at a petroleum refinery unless

the separator is equipped with air pollution control equipment

capable of reducing by 85 percent or more the uncontrolled

organic material emitted to the atmosphere. If no odor nuisance

exists, the limitation of this Section shall not apply if the

vapor pressure of the organic material is below 10.34 

kPa (1.5

psia) at 2~G4.3°K(70°F) at all times.

(Source: Amended at —  Ill. Reg. 

______,

effective 

____________

Section 218.445  

Leaks: General Requirements

a-)-The owner or operator of a petroleum refinery shall:

4~) Develop a monitoring program plan consistent with the

provisions of Section 218.446;

~)

Conduct a monitoring program consistent with the

provisions of Section 218.447;

3~) Record all leaking components which have a volatile

organic material concentration exceeding 10,000 ppm

consistent with the provisions of Section 218.448;

4~) Identify each component consistent with the monitoring

program plan submitted pursuant to Section 218.446;

~)

Repair and retest the leaking components as soon as

possible within 22 days after the leak is found, but no

later than June 1 for the purposes of Section

218.447 (a) (1), unless the leaking components cannot be

254

repaired until the unit is shut down for turnaround;

and

?~) Report to the Agency consistent with the provisions of

Section 218.449.

(Source: Amended at  

Ill. Reg. 

______,

effective

____________

_______________________)

Section 218.446  

Monitoring Program Plan for Leaks

The owner or operator of a petroleum refinery shall prepare a

monitoring program plan which contains, at a minimum:

a)  An identification of all refinery components and the

period in which each will be monitored pursuant to

Section 218.447 of this part

b)  The format for the monitoring log required by Section

218.448 of this part

C)   A description of the monitoring equipment to be used

pursuant to Section 218.447 of this part and

d)  A description of the methods to be used to identify all

pipeline valves, pressure relief valves in gaseous

service and all leaking components such that they are

obvious to both refinery personnel performing

monitoring and Agency personnel performing inspections.

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

___________

______________________ )

Section 218.447

Monitoring Program for Leaks

a)  The owner or operator of a petroleum refinery subject

to Section 218.445 of this Part shall, for the purpose

of detecting leaks, conduct a component monitoring

program consistent with the following provisions:

1)  Test once between March 1 and June 1 of each year,

by methods referenced in Section 218.105(g) QZ~

this Part, all pump seals, pipeline valves in

liquid service and process drains-~.

2)  Test once each quarter of each calendar year, by

methods referenced in Section 218.105(g) of this

Part, all pressure relief valves in gaseous

service, pipeline valves in gaseous service and

compressor seals-a

255

3)  Inaccessible valves may be tested once each

calendar year instead of once each quarter of 

each

calendar year~-j.

Observe visually all pump seals weekly~-i~

5)  Test immediately any pump seal from which liquids

are

observed dripping,-.~

Test any relief valve within 24 hours after it has

vented to the atmosphere,-~ and

7)  Test immediately after repair any component that

was found leaking.

b)  Storage tank valves and pressure relief devices

connected to an operating flare header or vapor

recovery device are exempt from the monitoring

requirements in subsection (a) of this Section.

C)   The Agency or the USEPA may require more frequent

monitoring than would otherwise be required by

subsection (a) for components which are demonstrated to

have a history of leaking.

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

____________

_________________________ )

Section 218.449  

Reporting for Leaks

The owner or operator of a petroleum refinery shall:

a)  Submit a report to the Agency prior to the 1st day of

both July

and September listing all leaking components

identified pursuant to Section 218.447 of this Part but

not repaired within 22 days, all leaking components

awaiting unit turnaround, the total number of

components inspected and the total number of components

found leaking;

b)  Submit a signed statement with the report attesting

that all monitoring and repairs were performed as

required under Sections 

218.445 through 218.448 of this

Part.

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

____________

_________________________ )

Section 218.450  

Alternative Program for Leaks

The Agency may approve an alternative program of monitoring,

recordkeeping or reporting to that prescribed in Sections 218.446

256

through 218.449 of this Part upon a demonstration by the owner or

operator of a petroleum refinery that the alternative program

will provide refinery, Agency and USEPA personnel with an

equivalent ability to identify and repair leaking components.

Any alternative program can

be allowed only if approved by the

USEPA as a SIP revision.

(Source: Amended at 

—

Ill. Reg. 

______,

effective

____________

_____________________)

Section 218.452  

Compliance Schedule for 

Leaks

The owner or operator of a petroleum refinery shall adhere to the

increments of progress contained in the following schedule:

a)  Have submitted to the ~SEP~.A~eflgya monitoring program

consistent with Section 218.446 of this Part prior to

September 1, 1990.

b)  Have submitted to the ~     

the first monitoring

report pursuant to Section 218.449 of this Part prior

to October 1, 1990.

(Source: Amended at

—

Ill. Reg.    

effective 

________

_______________________)

Section 218.453

Compliance Dates (Repealed)

—

— — —- —

—- -

—

_L.

L..—

Ifl. Adm.. Code

complied with

215

its

Cubpart

standar-ds

Ras

and

-of Dcoembcr

limitations

31

,l987ahallhavc

December 31, 1937.

(Source: Repealed at 

—

Ill. Reg. 

______,

effective

___________

_________________________)

SUBPART S: RUBBER AND MISCELLANEOUS PLASTIC PRODUCTS

Section 218.461  

Manufacture of Pneumatic Rubber Tires

The owner or operator of an undertread cementing, treadend

cementing or bead dipping operation at a pneumatic rubber tire

manufacturing facilitysource shall install and operate:

a) A capture system, with

minimum capture efficiency of 65

percent by weight of VON for treadend cementing or bead

dipping operations and a capture system with a minimum

capture efficiency of 55.5 percent by weight of VOM for

undertread cementing; and

b)  A control device that meets the requirements of one of

the following:

257

1) A carbon

adsorption system designed and operated

in a manner such that there is at least a 90

percent removal of VON by weight from the gases

ducted to the control device;

An afterburning system that oxidizes at least 90

percent of the captured nonmethane VOl’Is (VON

measured as total combustible carbon) to carbon

dioxide and water; and

3) An alternative

VON emission reduction system

demonstrated to have at least a 90 percent overall

reduction efficiency and approved by the Agency

and approved by the USEPA as a SIP revision.

(Source:

Amended at

—

Ill. Reg.   

effective

____________

_________________________ )

Section 218.462  

Green Tire Spraying Operations

The owner or operator of a green tire spraying operation at a

pneumatic rubber tire manufacturing facilitysource shall:

a)  Install and operate:

1)  A capture system with a minimum capture efficiency

of 90 percent by weight of VON; and

2)  A control device that meets the requirements of

one of the following:

A)  A carbon adsorption system designed and

operated in a manner such that there is at

least 90 percent removal of VON by weight

from the ~aees~as~e~ducted to the control

device;

B)  An afterburning system that oxidizes at least

90 percent of the captured nonméthane VON

(measured as total combustible carbon) to

carbon dioxide and water; or

C)  An alternative VON emission reduction system

demonstrated to have at least a 90 percent

overall reduction efficiency and approved by

the Agency and approved by the USEPA as a SIP

revision.

b)  Substitute for the normal solvent—based mold release

compound water-based sprays containing:

258

1)  No more than five percent by volume of VOM as

applied for the inside of tires;

2)

No more than 

ten percent by volume of VON as

applied for the outside of tires.

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

____________

_______________________)

Section 218.463

Alternative Emission Reduction Systems

In lieu of complying with Section 218.461 or 218.462 of this

Part, the owner or operator of an emission source may utilize an

alternative volatile organic emission reduction system, including

an alternative production process, which is demonstrated to be

equivalent to Section 218.461 or 218.462 of this Part on

the basis of emissions of volatile organic mat~e*~materj.~1.A

treadend cementing

operation shall be considered equivalent to

Section 218.461 or 218.462 of this Part for the purposes of this

Section if the total volatile organic emission from such

operation is 10 grams or less per tire.

(Source: Amended at 

—

Ill. Reg.    

effective

____________

_________________________ )

Section 218.464  

~~na and MonitoringEmission Testing

a)  Upon a reasonable request by the Agency, the owner or

operator of a VON emission source required to comply

with a limit of Sections 218.461 through 218.464 Qf

this Part shall conduct emissions testing, at such

person’s own expense, to demonstrate compliance.

b)  A person planning to conduct a VOId emission test to

demonstrate compliance shall notify the Agency of that

intent not less than 30 days before the planned

initiation of the tests so the Agency may observe the

test.

(Source:

Amended at

—

Ill. Reg. 

______,

effective

____________

_________________________ )

Section 218.465  

Compliance Dates (Repealed)

Every 

euner 

or

operator of an emission 

source 

su~jeetto 

Ill.

Adm. Code

complied

21~,

with

Subpart 

B, as of

its standards and

December 31, 1987 shall

limitations by December

have

31, 1987.

(Source: Repealed at 

—

Ill. Reg. 

______,

effective

________________________ )

Section 218.466  

Compliance Plan (Repealedl

259

The owner or operator of an emission source shall have

oubmittcd to the Agency a compliance plan, pursuant to

35 Ill. Adin. Code 201, Cubpart H, including a projoet

oomplction schedule whore applioablc, no later 

than

April 21, 

193-3--

Unless 

the

submitted compliancc plan or schedule was

disapproved by the Agency, the owner or operator of a

facility or omission source may operate 

the

emission

source 

according to 

the

plan and schedule as submitted.

The

plan and schedule shall moot the requirements of 35

Ill. Adin.

Code 

201, Cubpart

Ii, including specific

interim dates as required in 35 Ill. 

Adm. 

Code 301.242.

(Source: Repealed at 

—

Ill. Reg. 

______,

effective

___________

_________________________ )

SUBPART T: PHARMACEUTICAL MANUFACTURING

Section 218.480  

Applicability

a)  The rules of this Subpart, except for Sections 218.483

through 218.485 of this Part, apply to all emission

oourccsunits of VON, including but not limited to

reactors, distillation units, dryers, storage tanks for

VOL, equipment for the transfer of VOL, filters,

crystallizers, washers, laboratory hoods,

pharmaceutical coating operations, mixing operations

and centrifuges used in manufacturing, including

packaging, of pharmaceuticals, and emitting more than

6.8 kg/day

(15 lbs/day) and more than 2,268 kg/year

(2.5 tons/year) of VON. If such an emission sourocunit

emits less than 2,268 kg/year (2.5 tons/year) of VON,

the requirements of this Subpart still apply to the

emission oourccunit if VON emissions from the emission

sourocunit exceed 45.4 kg/day (100 lbs/day).

b)  Notwithstanding subsection (a) of this Section, the 

air

suspension coater/dryer, fluid bed dryers, tunnel

dryers, 

and Accelacotas located in Libertyville

Township,

Lake County, Illinois shall be exempt from

the rules of this Subpart, except for Sections 218.483

through 

218.485,

if emissions of VON not vented to air

pollution control equipment do not exceed the following

levels:

1)  ~or the air suspension coater/dryer: 2,268

kg/year (2.5 tons/year);

2)  ~or each fluid bed dryer: 4,535 kg/year

(5.0 tons/year);

260

3)  ft~oreach tunnel dryer: 6,803 kg/year (7.5

tons/year)~- and

4)  ~or each Accelacota: 6,803 kg/year

(7.5 tons/year).

c)  Sections 218.483 through 218.485 of this Part apply to

a plantsource having one or more emission sourocaunits

that:

1)

Are

used to manufacture pharmaceuticals, and

2)  Emit more than 6.8 kg/day (15 lbs/day) of VON and

more than 2,268 kg/year (2.5 tons/year) of VON,

or, if less than 2,268 kg/year (2.5 tons/year),

these Sections still apply if emissions from one

or more sources exceed 45 

•

4 kg/day (100 lbs/day).

d)  No owner or operator shall violate any condition in a

permit when the condition results in exclusion of an

emission courocunit from this Subpart.

e)

Any

pharmaceutical manufacturing source that becomes

subject to the provisions of this Subpart at any time

shall remain subject to the provisions of this Subpart

at all times.

f)  Emissions subject to this Subpart shall be controlled

at all times consistent with the requirements set forth

in this Subpart.

g)

Any

control device required pursuant to this Subpart

shall

be operated at all times when the source it is

controlling is

operated.

h)  Determinations of daily and annual emissions for

purposes of this Section shall be made using both data

on the hourly emission rate (or the emissions per unit

of throughput) and appropriate daily and annual data

from records 

of emission sourocunit operation (or

material throughput or material consumption data). In

the absence of representative test data pursuant to

Section 218.487 of this Part for the hourly emission

rate (or the emissions per unit of throughput), such

items shall be calculated using engineering

calculations, including the methods described in

Appendix B of ~SControl of Volatile Organic

Emissions

from Manufacturing of Synthesized Pharmaceutical

Products” (EPA-450/ 2-78-029), incorporated by

reference in Section 218.112 of this Part. (This

subsection shall not affect the Agency’s or the USEPA’s

261

authority to require emission tests to be performed

pursuant to Section 218.487 of this Part.)

(Source: Amended at  

Ill. Reg. 

______,

effective 

____________

_______________________)

Section 218.481  

Control of Reactors, Distillation Units,

Crystallizers, Centrifuges and Vacuum Dryers

a)  The owner or operator shall equip all reactors,

distillation units, crystallizers, centrifuges and

vacuum dryers that are used to manufacture

pharmaceuticals with surface condensers or other air

pollution control equipment listed in subsection (b) 2~

this Section.

If a surface condenser is used, it shall

be operated such that the 

condenser outlet gas

temperature does not exceed:

1)  248 .2°K(-13°F) when condensing VON of vapor

pressure greater than 40.0 kPa (5.8 psi) at

294.3°K (70°F), or

2)  258.2 °K (5°F) when condensing VOM of vapor

pressure greater than 20.0 

kPa

(2.9 psi) at

294.3°K (70°F), or

3)  273.2°K (32°F) when condensing VON of vapor

pressure greater than 10.0 kPa (1.5 psi) at

294.3°K (70°F), or

4)  283.2°K (50°F) when condensing VON of vapor

pressure greater than 7.0 kPa (1.0 psi) at 294.3°K

(70°F), or

5)  298.2°K (77°F) when condensing VON of vapor

pressure greater than 3.45 kPa (0.5 psi) at

294.3°K (70°F).

b)  If a scrubber, carbon adsorber, thermal afterburner,

catalytic afterburner, or other air pollution control

equipment other than a surface condenser is used, such

equipment shall provide a reduction in the emissions of

VON of 90 percent or more.

c)  The owner or operator 

shall

enclose all centrifuges

used 

to manufacture pharmaceuticals and that have

an

exposed VOL surface, where the VON in the VOL has a

vapor pressure of 3.45 kPa (0.5 psi) or more at 294.3°K

(70°F), except as production, sampling, maintenance, or

inspection procedures require operator access.

262

(Source: Amended at  

Ill. Reg.    

effective 

____________

Section 218.482  

Control of Air Dryers, Production Equipment

Exhaust Systems and Filters

a)  The owner or operator of an air dryer or production

equipment exhaust system used to manufacture

pharmaceuticals shall control the emissions of VON from

such emission oourocsunit by air pollution control

equipment which reduces by 90 percent or more 

the

VON

that would otherwise be emitted into the atmosphere.

b)  The owner or operator shall enclose all rotary vacuum

filters and other filters used to manufacture

pharmaceuticals and that have an exposed VOL surface,

where the VON in the VOL has a vapor pressure of 3.45

kPa

(0.5 psi) or more at 294~°K(70°F),except as

production,, sampling, maintenance, or inspection

procedures require operator access.

(Source: Amended at —  Ill. Reg. 

______,

effective 

____________

_________________________ )

Section 218.483  

Material Storage and Transfer

The owner or operator of a pharmaceutical manufacturing

plantsource shall:

a)  Provide a vapor balance system that is at least

90 percent effective in reducing VON emissions from

truck or railcar deliveries to storage tanks with

capacities equal to or

greater than 7.57 m3 (2,000 gal)

that store VOL with vapor pressures greater than

28.0 

kPa

(4.1 psi) at 294.3°K(70°F), and

b) Install, operate,

and maintain pressure/vacuum

conservation vents set at 0.2 

kPa

(0.03 psi) or greater

on all storage tanks that store VOL with vapor

pressures greater than 10

kPa (1.5 psi) at 294.3°K

(70°F).

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

____________

_________________________ )

Section 218.485  

Leaks

The owner or operator of a pharmaceutical manufacturing

plantsource shall repair any component

from which a leak of VOL

can be observed. The repair shall be completed as soon as

practicable but no later than 15 days after the leak is found.

263

If the leaking component cannot be repaired until the process

unit

is shut down, the leaking component must then be repaired

before the unit is restarted.

(Source: Amended at  

Ill. Reg.    

effective 

____________

_______________________)

Section 218.486

Other Emission £ourccc Units

The owner or operator of a washer, laboratory hood, tablet

coating operation, mixing operation or any other process emission

sourocunit not subject to Sections 218.481 through 218.485 Q~.

this Part, and used to manufacture pharmaceuticals shall control

the emissions of VON from such emission oourocaunits by:

Air pollution control equipment which reduces by

81 percent or more the VON that would otherwise be

emitted to the atmosphere, or

A surface condenser which captures all the VON which

would otherwise be emitted to the atmosphere and which

meets the requirements of Section 218.481(a) of this

Part and (b).

(Source: Amended at

—

Ill. Reg. 

______,

effective 

____________

_________________________ )

Section 218.487  

Testing

a)  Upon request by the Agency or the USEPA, the owner or

operator of any VON emission source subject to this

Subpart or exempt from this Subpart by virtue of the

provisions of Section 218.480 of this Part shall, at

his own expense, demonstrate compliance to the Agency

and the USEPA by the methods or procedures listed in

Section 218.105(f) (1) of this Part.

b)  A person planning to conduct a VON emissions test to

demonstrate compliance with this Subpart shall notify

the Agency and the USEPA of that intent not less than

30 calendar days before the planned initiation of the

test.

(Source:

Amended at

—

Ill. Reg. 

______,

effective

____________

_________________________ )

Section 218.489  

Recordkeeplng for Air Pollution Control

Equipment

a)  The owner or operator of a pharmaceutical manufacturing

facility source shall maintain the following records:

264

Parameters listed in Section 2l8.488(a)-(4)- of this

Part shall be recorded.

2)  For souroceemission units subject to Section

218.481, of this Part, the vapor pressure of VON

being controlled shall be recorded for every

process.

b)  For any leak subject to Section 218.485 of this Part

which cannot be readily repaired within one hour after

detection, the following records shall be kept:

1)  The name of the leaking equipment,

2)  The date and time the leak is detected,

3)  The action taken to repair the leak, and

4)  The dat~aand time the leak is repaired.

c)  The following records shall be kept for emission

aourocsunits subject to Section 218.484 of this Part

which contain VOL:

1)  For maintenance and inspection:

The date and time each cover is opened,

B)  The length of time the cover remains open,

and

C)  The reason why the cover is opened.

2)  For production and sampling, detailed written

procedures or manufacturing directions specifying

the circumstances 

under which covers may be opened

and the procedures for opening covers.

d)  For each emission oourccunit used in the manufacture of

pharmaceuticals for which the owner or operator of a

pharmaceutical manufacturing plantsource claims

emission standards are not applicable, because the

emissions are below the applicability cutoffs in

Section 218.480(a) or 218.480(b) of this Part, the

owner or operator shall:

1)  Maintain a demonstration including detailed

engineering calculations of the maximum daily and

annual emissions for each such emission sourocunit

showing that the emissions are below the

applicability cutoffs in Section 218.480(a) or

265

218.480(b) of this Part, as appropriate, for the

current and prior calendar years;

2)  Maintain appropriate operating records for each

such emission source to identify whether the

applicability cutoffs in Section 218.480(a) or

218.480(b) of this Part, as appropriate, are ever

exceeded; and

Provide written notification to the Agency and the

USEPA within 30 days of a determination that such

an emission oourccunit has exceeded 

the

applicability cutoffs in Section 218.480(a) or

218.480(b) of this Part, as appropriate.

e)  Records required under subsection ‘(a) of this Section

shall be maintained by the owner or operator for a

minimum of two years after the date on which they are

made.

f)  Copies of the records shall be made available to the

Agency or the USEPA upon verbal or written request.

(Source:

)

Amended at

—

Ill. Req. 

______

effective

SUBPART V: AIR OXIDATION PROCESSES

Section 218.521

Definitions (Repealed)

—

fl—

—IS

—.t

a—

, ~

a—fl

218.lO4thc foilowingdcfinition3 apply to this Cubparti

“Air Oxidation

Propose”t any unit proooso

aminoxidation and oxyohiorination which 

ur~ri

inoluding

nir nr n

oouwin~ion oi air ana 

oxygen ac an oxidant in combination

vith one or more organic reactants to produce one or more

organic compounds.

“Coot Effootivoneso”,

the annual expense for cost of

control of a given process stream divided by the reduction

in omissions of organic -material of that stream.

“Flow (F)”i Vent otroam flowrato (scm/mm) at a standard

temperature of 20°C.

“Full Operating Flowrato”i Haximuin operating capacity 

the facility.

“Hourly Emissions (E)”e Hourly omissions reported in kg/hr

measured at full operating flowrate.

266

.“,_ ,___

l.,

-

———

4’_ — •&_~

..r’w~a’~~~’ç.rf

~.&

(HJ/som), whore the net enthalyy 

1e~. ...~u 

orrgas is based

on combustion at 25°Cand 760 

mm Hg, but the 

standard

temperature 

for determining the volume -corresponding to 

One

mole is 

200C, 

pa in the definition of “Flow.”

“Preeess Vent Stream”, An emission 

stream 

resulting frea an

air oxidation proooso.

“Total Dcaouroc Effectiveness -Index (TRE)”s Cost

effectiveness in dollars per megagram of controlling any

gaseous stream vented to the atmosphere from an air

oxidation process divided by ~1600/flg,using the oritoria

and methods sot forth in 

this Cubpart 

and Appendices C and

D.

(Source: Repealed at 

—

Ill. Reg.    

effective 

___________

_______________________ )

Section 218.525  

Emission Limitations for Air Oxidation

Processes

a)  No person shall cause or allow the emission of VON from

any process vent stream unless the process vent stream

is vented to a combustion device which is designed and

operated either:

1)  To reduce the volatile organic emissions vented to

it with an efficiency of at least ninety eight

percent (98) by weight; or

2)  To emit VON at a concentration less than twenty

parts per million by volume, dry basis.

b)  &i.3~~iroxidation faciliticaprocess vent stream for

which an existing combustion device is employed to

control process VON emissions e~ej~not required to

meet the 98 percent emissions limit until the

combustion device is replaced for other reasons, which

shall be considered to include, but not be limited to,

normal maintenance, malfunction, accident, and

obsolescence. The combustion device is considered to be

replaced when:

1)  All of the device is replaced; or

2)  When the cost of the repair of the device or the

cost of replacement of part of

the device exceeds

50 of the cost of replacing the entire device

with a device which complies.

267

C)   The limitations of subsection (a) above do not apply to

any process vent stream or combination of process vent

streams which has a Total Resource Effectiveness Index

(TRE) greater than 1.0, as determined by the following

methods:

1)  If an air oxidation process has more than one

process vent stream, 

TRE

shall be based upon a

combination of the process vent streams.

2)  TRE of a process vent stream shall be determined

according to the following equation:

TRE

E1(a + bF~+ CF + dFH + e(FH)~ +

fF0’5)

where:

n

0.881.

TRE

Total resource effectiveness

indexr~~

F

Vent stream flowrate (scm/mm), at

a standard temperature of 2O°C-ri.

E

Hourly measured emissions in

kg/hr--i.

H

Net heating value of vent stream

(NJ/scm), where the net enthalpy

per mole of offgas is based on

combustion at 25°Cand 760 mm Hg,

but the standard temperature for

determining the volume

corresponding to one mole is 20°C,

as in the definition of “Flow”-r.L

a, b, c,

d, e

and f=  Coefficients obtained by use of

Appendix 

~

3)  For nonchlorinated process vent streams, if 

the

net heating value, H, is greater than 3.6 

NJ/scm,

F shall be replaced by ~ ~ for purposes of

calculating

TRE. ~F-~

~.   is computed as follows:

FH

/

3.6

where F and H are as defined in subsection (c) (2)

of this Section.

268

4)  The actual numerical values used in the equation

described in

subsection (C) 

(2) above shall be

determined as follows:

A) All reference methods and procedures for

determining the flow, (F), hourly emissions,

(E), and net heating, (H), value shall be in

accordance with Appendix C.

B)  All coefficients described in subsection

(c) (2) of this Section shall be in accordance

with Appendix D.

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

____________

_______________________)

Section 218.527  

Compliance Date (Repealed)

Each owner or operator of an -emission oourcc—subjcot to 35 Ill.

Adm. Code 215, Cubpart V, as 

-of

December 31, 1987 shall havc

complied with the standards and limitations of 35 Ill. Adm. Code

215, Cubpart V, by December 31, 1987.

(Source: Repealed at 

—

Ill. Reg. 

______,

effective 

___________

_________________________ )

SUBPART W: AGRICULTURE

Section 218.541  

Pesticide Exception

The provisions of Sections 218.301 and 218.302 of this Part shall

not apply to the spraying or use of insecticides, herbicides or

other pesticides.

(Source: Amended at 

—

Ill. Reg.    

effective 

____________

______________________ )

SUBPART X:

CONSTRUCTION

Section

218.562  

Paving Operations

The provisions of Sections 218.301 and 218.302 of this Part shall

not apply to the application of paving asphalt and pavement

marking paint from sunrise to sunset.

(Source: Amended at 

—

Ill. Reg.    

effective 

____________

____________________)

SUBPART Y: GASOLINE DISTRIBUTION

Section 218.581  

Bulk Gasoline Plants

269

a)  Subject to 6~ubsection (e) of this Section, no person

may cause or allow the transfer of gasoline from a

delivery vessel into a stationary storage tank located

at a bulk gasoline plant unless:

1)  The delivery vessel and the stationary storage

tank are each equipped with a vapor collection

system that meets the requirements of subsection

(d) (4) of this Section7i.

2)  Each vapor collection system is operating~j.

3)  The delivery vessel displays the appropriate

sticker pursuant to the requirements of Sections

218.584 (b) or (d) of this Part,-~

4)  The pressure relief valve(s) on 

the

stationary

storage tank and the delivery vessel are set to

release

at no less than 0.7 psi or the highest

pressure allowed by state or local fire codes or

the guidelines of the National Fire Prevention

Association7~and

5)  The stationary storage tank is equipped with a

submerged loading pipe.

b)  Subject to subsection (f) of this Section, no person

may cause or allow the transfer of gasoline from a

stationary storage tank located at a bulk gasoline

plant into a delivery vessel unless:

1)  The requirements set forth in subsections (a) (1)

through (a) (4) of this Section are metr.1. and

2)  Equipment is available at the bulk gasoline plant

to provide for the submerged filling of the

delivery vessel or the delivery vessel is equipped

for bottom loading.

C)

Subject

to subsection (e) of this Section, each owner

of a stationary storage tank located at a bulk gasoline

plant shall:

1)  Equip each stationary storage tank with a vapor

control system that meets the requirements of

subsection (a) or (b) of this Section, whichever

is applicab1e-~

2)  Provide instructions to the operator of the bulk

gasoline plant describing necessary maintenance

operations and procedures for prompt notification

of the owner in case of any malfunction of a

270

vapor control system,-~and

3)  Repair, replace or modify any worn out or

malfunctioning component or element of design.

d)  Subject to subsection (e) of this Section, each

operator of a bulk gasoline plant shall:

1)  Maintain and operate each vapor control system in

accordance with the owner’s instructions7j~

2)  Promptly notify the owner of any scheduled

maintenance or malfunction requiring replacement

or repair of a major component of a vapor control

system,-~and

3)  Maintain gauges, meters or other specified testing

devices in proper working order7j

4)  Operate the bulk plant vapor collection system and

gasoline loading equipment in a manner that

prevents:

A) Gauge pressure from exceeding 45.7 cm (18

in.) of water and vacuum from exceeding 15.2

cm (6 in.) of water, as 

measured

as close as

possible to the vapor hose connection7~and

B)  A reading equal to or greater than 100

percent of the lower explosive limit (LEL

measured as propane) when tested in

accordance with the procedure described in

“Control of Volatile Organic Compound Leaks

from Gasoline Tank Trucks and Vapor

Collection Systems”, Appendix B,

EPA 450/2-78-051, (incorporated by reference

in Section 218.112) of this PartT.j. and

C)  Avoidable leaks of liquid during loading or

unloading operations.

5)  Provide a pressure tap or equivalent on the bulk

plant vapor collection system in order to allow

the determination of compliance with subsection

(d) (4) (A) of this Sectjon~jand

6)  Within 15 business days after discovery of any

leak by the owner, the operator, 

the

Agency or 

the

USEPA, repair and retest a vapor collection system

which exceeds the limits of subsection (d) (4) (A)

or (B) of this Section.

271

e)  The requirements of subsections (a), (c) and (d) ~

this Section shall not apply to:

1)

Any

stationary storage tank with a capacity of

less than 2,177 1 (575 gal)7~.or

Any bulk gasoline plant whose daily gasoline

throughput

is less than 15,140 1 (4,000 gal/day)

on a thirty—day rolling average.

f)  The requirements of subsection (b) of this Section

shall apply only to bulk gasoline plants whose daily

gasoline throughput is greater than or equal to 15,140

1 (4,000 gal/day) on a thirty—day rolling average.

g)

Any

bulk gasoline plant which is ever subject to

subsections (a), (b), (c), or

(d) shall always be

subject to these paragraphs.

(Source: Amended at 

—

Ill. Reg.    

effective 

____________

_________________________)

Section 218.582  

Bulk Gasoline Terminals

a)  No person shall cause or allow the transfer of gasoline

into any delivery vessel from any bulk gasoline

terminal unless:

1)  The bulk gasoline terminal is equipped with a

vapor control system that limits emission of VON

to 80 mg/i (0.00067 lbs/gal) of gasoline loaded;

2)  The vapor control system is operating and all

vapors displaced in the loading of gasoline to the

delivery vessel are vented only to the vapor

control system;

3)  There is no liquid drainage from the loading

device when it

is not in use;

4)  All loading and vapor return lines are equipped

with fittings which are vapor tight; and

5)  The delivery vessel displays the appropriate

sticker pursuant to the requirements of Section

218.584(b) or (d) of this Part or, if the

terminal

is driver-loaded, the terminal owner or

operator shall be deemed to be in compliance with

this Section when terminal access authorization is

limited to those owners and/or operators of

delivery vessels who have provided a current

272

certification as required by Section 218.584(c) (3)

of this Part.

~

gaooiinc

terminais wore roquirca to taxo

certain actions to achieve oomplianoc which are

ouinmari&~cdin 35 Ill. 

Adm. Coda

215, Appendix C.

e~) The operator of a bulk gasoline terminal shall:

1)  Operate the terminal vapor collection system and

gasoline loading equipment in a manner that

prevents:

A) Gauge pressure from exceeding 18 inches of

water and vacuum from exceeding 6 inches of

water as measured as close as possible to the

vapor hose connection; and

B) A reading equal to or greater than 100

percent of the lower explosive limit (LEL

measured as propane) when tested in

accordance with the procedure described in

EPA 450/2-78-051 Appendix B~incorporated by

reference in Section 218.112 of this Part

and

C)  Avoidable leaks of liquid during loading or

unloading operations.

2)  Provide a pressure tap or equivalent on the

terminal vapor collection system in order to allow

the determination of compliance with Section

218.582(d) (1) (A) of this Part and

3)

Within 15 business

days after discovery of the

leak by the owner, operator, or the Agency repair

and retest a vapor collection system which exceeds

the

limits of subsection (c) (1) (A) or (B) of this

Section.

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

___________

_________________________ )

Section 218.583  

Gasoline Dispensing Facilities 

—

Storage Tank

Filling Operations

a)  Subject to subsection (b) below, no person shall cause

or allow the transfer of gasoline from any delivery

vessel into any stationary storage tank at a gasoline

dispensing facilityo~erationunless:

273

1)  The tank is equipped with a submerged loading

pipe; and

2)  The vapors displaced from the storage tank during

filling are processed by a vapor control system

that includes one or more of the following:

A)  A vapor collection system that meets the

requirements of subsection (d) (4) below; or

B)  A refrigeration—condensation system or any

other system approved by the Agency and

approved by the USEPA as a SIP revision, that

recovers at least 90 percent by weight of all

vaporized organic material from 

the

equipment

being controlled; and

C)  The delivery vessel displays the appropriate

sticker pursuant to the requirements of

Section 218.584(b) or (d) of this Part.

b)  The requirements of subsection (a) (2) above shall not

apply to transfers of gasoline to a stationary storage

tank at a gasoline dispensing faoilityo~erationif:

1)  The tank is equipped with a floating roof, or

other system of equal or 

better emission control

approved by the Agency and approved by the USEPA

as a SIP revision;

2)  The tank has a capacity of less than 2000 gallons

and was in place and operating before January 1,

1979; or

3)  The tank has a capacity of less than 575 gallons.

c)  Subject to subsection (b) above, each owner of a

gasoline dispensing facilityoperation shall:

1)  Install all 

control systems and

make all process

modifications required by subsection (a) above;

2)  Provide instructions to the operator of 

the

gasoline dispensing facilityo~erationdescribing

necessary maintenance operations and procedures

for prompt notification of the owner in case of

any malfunction of a vapor control system; and

3)  Repair, replace or modify any worn out or

malfunctioning component or element of design.

274

d)  Subject to subsection (b) above, each operator of a

gasoline dispensing faci1ityo~erationshall:

1)  Maintain and operate each vapor control system in

accordance with the owner’s instructions;

2)  Promptly notify the owner of any scheduled

maintenance or malfunction requiring replacement

or repair of a major component of a vapor control

system;

3)  Maintain gauges, meters or other specified testing

devices in proper working order;

4)  Operate the vapor collection system and delivery

vessel unloading points in a manner that prevents:

A) A reading equal to or greater than 100

percent of the lower explosive limit (LEL

measured as propane) when tested in

accordance with the procedure described in

EPA 450/2-78-051 Appendix B, and

B)  Avoidable leaks of liquid during the filling

of storage tanks; and

5)  Within 15 business days after discovery of the

leak by the owner, operator, or the Agency, repair

and retest a vapor collection system which exceeds

the limits of subsection (d) (4) (A) above.

e~- Casoline dispensing facilities were required to take

pertain actions to achieve -compliance ~‘hioharc

auininari~cd in 35 Iii.

Adm. 

Code 215, Appendix C.

(Source: Amended at  

Ill. Reg. 

______,

effective 

____________

_________________________ )

Section 218.584

Gasoline Delivery Vessels

a)  Any delivery vessel equipped for vapor control by use

of vapor collection equipment:

1)  Shall have a vapor space connection that is

equipped with fittings which are vapor tight;

2)  Shall have its hatches closed at all times during

loading or unloading operations, unless a top

loading vapor recovery system is used;

3)  Shall not internally exceed a gauge pressure of 18

inches of water or a vacuum of 6 inches of water;

275

4)  Shall be designed and maintained to be vapor tight

at all times during normal operations;

5)  Shall not be refilled in Illinois at other than:

A)  A bulk gasoline terminal that complies with

the requirements of Section 218.582 of this

Part or

B)  A bulk gasoline plant that complies with the

requirements of Section 218.581(b) of this

Part.

6)  Shall be tested annually in accordance with Method

27, 40 CFR 60, Appendix A, incorporated by

reference in Section 218.105. Each vessel must be

repaired and retested within 15 business days

after discovery

of the leak by the owner,

operator, or the Agency, when it fails to sustain:

A)  A pressure drop of no more than three inches

of water in five minutes; and

B)  A vacuum drop of no more than three inches of

water in five minutes.

b)

Any

delivery vessel meeting the requirements of

subsection (a) of this Section shall have a sticker

affixed to the tank adjacent to the tank manufacturer’s

data plate which contains the tester’s name, the tank

identification number and the date of the test. The

sticker shall be in a

form prescribed by the Agency,

and, for those delivery vessels subject to 35 Ill. Ada.

Code 215 as of December 31, 1987 shall have been

displayed no later than December 31, 1987.

c)  The owner or operator of a delivery vessel shall:

1)  Maintain copies of any test required under

subsection (a) (6) of

this Section for a period of

3 years;

2)  Provide copies of these tests to the Agency upon

request; and

3)  Provide annual test result certification to bulk

gasoline

plants and terminals where the delivery

vessel is loaded.

d)  Any delivery vessel which has undergone and passed a

test in another state which has a USEPA-approved leak

testing and certification program will satisfy the

276

requirements of subsection (a) of this Section.

Delivery vessels must display a sticker, decal or

stencil approved by the state where tested or comply

with the requirements of subsection (b) of this

Section. All such stickers, decals or stencils shall

have been displayed no later than December 31, 1987,

for delivery vessels subject to 35 Ill. Ada. Code 215

as of December 31, 1987.

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

____________

_________________________ )

Section 218.585  

Gasoline Volatility Standards

a)  No person shall sell, offer for sale, dispense, supply,

offer for supply, or transport for use in Illinois

gasoline whose Reid vapor pressure exceeds the

applicable limitations set forth in subsections (b) and

(c) of this Section during the regulatory control

periods, which shall be July j~y 1 to August 31

September 15 for retail outlets, wholesale

purchaser—consumer, facilities operations, and all

other facilities operations.

b)  The Reid vapor pressure of gasoline, a measure of its

volatility, shall not exceed 9.5Q psi (65.5 62.07 

kPa)

during the regulatory control period in 1990 and each

year thereafter.

C)   The Reid vapor pressure of ethanol blend gasolines

shall not exceed the limitations for gasoline set forth

in subsection (b) of this Section by more than 1.0 psi

(6.9 kPa). Notwithstanding this limitation, blenders

of ethanol blend gasolines whose Reid vapor pressure is

less than 1.0 psi above the base stock gasoline

immediately after blending with ethanol are prohibited

from adding butane or any product that will increase

the Reid vapor pressure of the blended gasoline.

All sampling of gasoline required pursuant to the

provisions of this Section shall be conducted by one or

more of the following approved methods or procedures

which are incorporated by reference in Section 215.105.

1)  For manual sampling, ASTN D4057;

2)  For automatic sampling, ASTN D4l77;

3)  Sampling procedures for Fuel Volatility, 40 CFR 80

Appendix D.

277

e)  The Reid vapor pressure of gasoline shall be measured

in accordance with either test method ASTM D323 or a

modification of ASTN D323 

known as the “dry method” as

set forth in 40 CFR 80, Appendix E, incorporated by

reference in 35 Ill. Ada. Code ~     

of this

Part. For gasoline 

—

oxygenate blends which contain

water—extractable oxygenates, the Reid vapor pressure

shall be measured using 

the dry

method test.

f)  The ethanol content of ethanol blend gasolines shall be

determined by use of one of the approved testing

methodologies specified in 40 

CFR

80, Appendix F,

incorporated by reference in 35 Ill. Ada. Code

&~~5U~ of this Part.

g)

Any

alternate to the sampling or testing methods or

procedures contained in subsections (d), (e), and (f)

of this Section must be approved by the Agency, which

shall consider data comparing the performance of the

proposed alternative

to the performance of one or more

approved test methods or procedures. Such data shall

accompany any request for Agency approval of any

alternate test procedure.

If the Agency determines

that such data demonstrates that the proposed

alternative will achieve results equivalent to the

approved test methods or procedures, the Agency shall

approve the proposed alternative.

h)  Each refiner or supplier that distributes gasoline or

ethanol blends shall:

1)  During the regulatory control period, state that

the Reid vapor pressure of all gasoline or ethanol

blends leaving the refinery or distribution

facility operation for use in Illinois complies

with the Reid vapor pressure limitations set forth

in 35 Ill. Ada. Code 24&2~.585(b) and (c). 

Any

facilityoperation receiving this gasoline shall be

provided with a copy of an invoice, bill of

lading, or other documentation used in normal

business practice stating

that the Reid vapor

pressure of the gasoline complies with the State

Reid vapor pressure standard.

2)  Maintain records for a period of one year on the

Reid vapor pressure, quantity shipped and date of

delivery

of any gasoline or ethanol blends leaving

the refinery or distribution facility operation

for use in Illinois. The Agency shall be provided

with copies of such records if 

requested.

278

(Source: Amended at 

—

Ill. Reg.    

effective

__________

_______________________)

Section 218.586  

Gasoline Dispensing Facilities Operations 

—

Motor Vehicle Fueling Operations

a)  For 

the

purposes of this Section, the following

definitions apply.

1)  Average M~onth1y~yolumei- means tThe amount 

motor vehicle fuel dispensed per month from a

gasoline dispensing facility operation based

upon

a monthly average for the 2—year period of

November, 1990 through 

October, 1992 or, if not

available, the monthly average for 

the

most recent

twelve calendar months. Monthly averages are to

include only those months when the facility

operation was operating.

2)

Certified+ means 

aAny vapor collection and control

system which has been tested and approved by CA.RB

as having a vapor recovery and removal efficiency

of at least 95 (by weight) shall constitute a

certified vapor collection and control system.

CARE testing and approval is pursuant to the CARE

manual, hereby incorporated by reference 

~.t

218.112 of this Part (California Air Resources

Board, Compliance Division, Compliance Assistance

Programs Facilities Phase I ~ II (Ootobcr 1988,

rev. Harch 1991 CAi1B Manual)). This incorporation

includes no later additions or amendments.

3)  Completion of installation-.- means tThe successful

passing of one or more of the following tests

applicable to the installed vapor collection and

control system: Dynamic Backpressure Test,

Pressure Decay/Leak

Test, and Liquid Blockage

Test~ (United Ctatcs Environmental Protection

Agency, Washington D.C., EPA—450-3-9l-002b).

These tests are hereby incorporated by reference

at 218.112 of this Part. This incorporation

includes no later additions or amendments.

Constructed÷means f~abricated, erected or

installed; refers to any facility, emission source

or air pollution control equipment.

5)  CARB÷means California Air Resources Board, P.O.

Box 2815, Sacramento, CA 95812.

6)  Employee-.- means aAny person who performs work for

an employer.

279

7)  FacilityO~eration-.-means aAny building, structure,

installation, operation or combination thereof

located on contiguous properties and under common

ownership that

provides for the dispensing of

motor vehicle fuel.

8)  Gasoline ~ispensing Facility operation: means

MAny ~        

where motor vehicle fuel is

dispensed into motor vehicle fuel tanks or

portable containers from a storage tank with a

capacity of 2176 liters (575 gallons) or more.

Modification÷ means

aAny 

change, removal or

addition, other than an identical replacement, of

any component contained within the vapor

collection and control system.

10) Motor J~ehicle÷means aAny self-propelled vehicle

powered by an internal combustion engine

including, but not limited to, automobiles and

trucks. Specifically excluded from this

definition are watercraft and aircraft.

11) Motor ~yehicle ~uel÷ means aAny petroleum

distillate having a Reid vapor pressure of more

than 27.6 kilopascals (kPa) (four pounds per

square inch) and which is used to power motor

vehicles.

12) Owner or O~perator÷means aAny person who owns,

leases, operates, manages, supervises or controls

(directly or indirectly) a gasoline dispensing

facilityoperation.

13) Reid Vyapor Ppressure÷£~orgasoline, 4~shall be

measured in accordance with either the method ASTM

D323 or a modification of ASTM D323 known as 

the

“dry method” as set forth in 40 CFR 80, Appendix

E, incorporated by references in 35 Ill. Ada. Code

215.105218.112 of this Part.

14)

Vapor G~ollection and ~ontrol

6~ystem÷means aAny

system certified by CARB which limits the

discharge to the atmosphere of motor vehicle fuel

vapors displaced during the dispensing of motor

vehicle fuel into motor vehicle fuel tanks.

b)  The provisions of subsection (c) below shall apply to

any gasoline dispensing facility operation which

dispenses an average monthly volume of more than 10,000

gallons of motor vehicle fuel per month. Compliance

280

shall be demonstrated in accordance with the schedule

provided in subsection (d) below.

c)  No owner or operator of a gasoline dispensing facility

oDeration subject to the requirements of subsection (b)

above shall cause or allow the dispensing of motor

vehicle fuel at any time from a motor fuel dispenser

unless the dispenser is equipped with and utilizes a

vapor collection and control system which is properly

installed and operated as provided below:

1) Any vapor collection and control system installed,

used or maintained has been CARE certified.

2)  Any vapor collection and control system utilized

is maintained in accordance with the

manufacturer’s specifications and the

certification.

3)  No elements or components of a vapor collection

and control system are modified, removed, replaced

or otherwise rendered inoperative in a manner

which prevents the system from performing in

accordance with its certification and design

specifications.

4)  A vapor collection and control system has no

defective, malfunctioning or missing components.

5)  Operators and employees of the gasoline dispensing

facility operation are trained and instructed in

the proper operation and maintenance of a vapor

collection and control system.

6)  Instructions are posted in a conspicuous and

visible place within the motor fuel dispensing

area and describe the proper method of dispensing

motor vehicle fuel with the use of the vapor

collection and control system.

d)  In conjunction with the compliance provisions of

Section 218.105 of this Part, faoiliticsoperations

subject to the requirements of subsection (c) above

shall demonstrate compliance according to the

following:

1)  Faciliticcpperations that commenced construction

after November 1,

1990, must comply by May 1,

1993.

2)  Faoilitjespperatjons that commenced construction

before November 1,

1990, and dispense an average

281

monthly volume of more than 100,000 gallons of

motor fuel per month must comply by November 1,

1993.

3)

that commenced construction

before November 1, 1990, and dispense an average

monthly volume of less than 100,000 gallons of

motor fuel per month must comply by November 1,

1994.

New faoilitiesoperations constructed after 

the

adoption of this Section shall comply with the

requirements

of subsection (c) above upon startup

of the facilityoperation.

5)  Existing faciliticooperations previously exempted

from but which become subject to the requirements

of subsection (C) above after May 1, 1993 shall

comply with the requirements of subsection (c)

above within six calendar months of the date from

which the facilityoperation becomes subject.

e)  Any gasoline dispensing facility operation that becomes

subject to the provisions of subsection (c) above at

any time shall remain subject to the provisions of

subsection (c) above at all times.

f)  Upon request by the Agency, the owner or operator of a

gasoline dispensing facilityoperation which claims to

be exempt from the requirements of

this Section shall

submit records to the Agency within 30 calendar days

from the date of the request which demonstrate that the

gasoline dispensing facilityo~erationis in fact

exempt.

Recordkeeping and reporting:

1)  Any gasoline dispensing facilityoperation subject

to subsection (C) above shall retain at the

facility operation copies of the registration

information required at subsection (ii) below.

2)  Records and reports required pursuant to this

subsection shall be made available to the Agency

upon request. Records and reports which shall be

maintained by

the owner or operator of the

gasoline dispensing faoilityo~erationshall

clearly demonstrate:

A)  That a certified vapor collection and control

system has been installed and tested to

282

verify its performance according to its

specifications.

B)  That proper maintenance has been conducted in

accordance with the manufacturer’s

specifications and requirements.

C)  The time period and duration of all

malfunctions of the vapor collection and

control system.

D)  The motor vehicle fuel throughput of 

the

fncilityo~erationfor each calendar month of

the previous year.

E)  That operators and employees are trained and

instructed in the proper operation and

maintenance of the vapor collection and

control system and informed as to the

potential penalties associated with the

violation of any provision of this Section.

h)

Any

gasoline dispensing ~ae-~4tyo~erat.iox~tionsubject to

subsection

(c) above shall be exempt from the permit

requirements specified under 35 Ill. Ada. Code 201.142,

201.143 and 201.144 for its vapor collection and

control systems, provided that:

1)  Upon the installation of a vapor collection and

control system, the owner or operator of the

gasoline dispensing facilityo~erationsubmits to

the Agency a registration which provides at

minimum the ~         

name and address,

signature of the owner or operator, the CARE

Executive Order Number for the vapor collection

and control system to be utilized, the number of

nozzles

(excluding diesel or kerosene) used for

motor vehicle refueling, the monthly average

volume of motor vehicle fuel dispensed, the

location (including contact person’s name,

address, and telephone number) of records and

reports required by this Section, and 

the date of

completion of installation of the vapor collection

and control system.

2)  The registration is submitted to 

the Agency within

30 days of completion of such installation.

3)  A copy of the registration information is

maintained at the gasoline dispensing facility

oDerat ion.

283

4)  Upon the modification of an existing vapor

collection and control system, the owner or

operator of the gasoline dispensing facility

operation submits to the Agency a registration

that details the changes to the information

provided in the previous registration of the vapor

collection and control system and which includes

the signature of the owner or operator. The

registration must be submitted to the Agency

within 30 days of completion of such modification.

(Source: Amended at    

Ill. Reg. 

________,

effective_________

SUBPART Z: DRY CLEANERS

Section 218.601  

Perchioroethylene Dry Cleaners

The owner or operator of a dry cleaning facilityoperation which

uses perchioroethylene shall:

a)  Vent the entire dryer exhaust through a properly

designed and functioning carbon adsorption system or

equally effective control device; and

b)  Emit no more than 100 ppmv of VON from the dryer

control device before dilution, or achieve a 90 percent

average reduction before dilution; and

C)   Immediately repair all components found to be leaking

liquid VOM; and

d)  Cook or treat all diatomaceous earth filters so that

the residue contains 25 kg (55 lb) or less of VOM per

100 kg (220 ib) of wet waste material; and

e)  Reduce the VOM from all solvent stills to 60 kg (132

ib) or less per 100 kg (220 lb) of wet waste material;

and

f)  Drain all filtration cartridges in the filter housing

or other sealed container for at least 24 hours before

discarding the cartridges; and

g)  Dry all drained filtration cartridges in equipment

connected to an emission reduction system or in a

manner that will eliminate emission of VOM to the

atmosphere.

284

(Source: Amended at 

—

Ill. Reg.    

effective

_______________________ )

Section 218.602  

Exemptions

The provisions of Section 218.601 of this Part are not applicable

to perchloroethylene 

dry

cleaning operations which are

coin—operated or to dry cleaning faciliticcioperations

consuming

less than 30 gal per month (360 gal per year) of

perchloroethylene.

(Source:

Amended at

_____________________)

Ill. Reg.    

effective

Section 218.603

Leaks

The presence of leaks shall be determined for purposes of Section

218.601(c) of this Part by a visual inspection of the following:

hose connections, unions, couplings and valves; machine door

gaskets and seatings; filter head gasket and seating; pumps; base

tanks and storage containers; water separators; filter sludge

recovery; distillation unit; diverter valves; saturated lint from

lint baskets; and cartridge filters.

(Source: Amended at 

—

Ill. Reg.    

, effective 

____________

Section 218.604  

Compliance Dates (Repealed)

set forth in 35 Ill. Ada. Code 215.60-..

(Source: Repealed at  

Ill. Reg.    

,

effective

______________________)

Section 218.605  

Compliance Plan (Repealed)

The owner or operator of an emission source 

subj

cot to

this Cubpart shall have submitted to the Agency a

oomplianee plan, pursuant to 3S Ill. Ada. Code 201,

Cubpart H, including a project completion schedule

where applicable, no later than, for Section 218.601(a)

and (b), April 21, 1983.

Unless the submitted compliance plan or schedule was

disapproved by the Agency, the owner or operator of a

facility or omission source may operate the omission

source according to the plan and schedule as submitted.

Every owner or operator of an omission source previously 

subj

cot

to 35 Ill. Ada. Code 215, Cubpart Z, shall have oompliod with its

standards and limitations 

in accordance with the applicable dates

The

plan and schedule shall moot the requirements of-3-~

Ill. Ada. Code 201, £ubpart H, including specific

interim datca as required in 35 Ill. 

Ada. Code 201.242~-

(Source: Repealed at 

—

Ill. Reg.    

effective

Section 218.606  

Exception to Compliance Plan (Repealed)

Coin 

operated

dry cleaning operations and dry

cleaning facilities

consuming ices than 30 gal—per month (360 gal per year) of

perohloroothylone are not required to submit or obtain an 

Agency

approvcd compliance plan or project completion schedule.

(Source: Repealed at 

—

Ill. Reg. 

______,

effective 

___________

Section 218.608  

Operating Practices for Petroleum Solvent Dry

Cleaners

In order to minimize fugitive solvent emissions, the owner or

operator of a petroleum solvent dry cleaning faOilitysource shall

employ good housekeeping practices including the following:

a)  General Housekeeping Requirements

1)  Equipment containing solvent 

(washers,

dryers,

extractors and filters) shall remain closed at all

times except during load transfer and maintenance.

Lint filter and button trap covers shall remain

closed except when solvent—laden material is being

removed.

2)  Cans, buckets, barrels and other containers of

solvent or of solvent-laden material shall be

covered except

when in use.

3)  Solvent-laden material shall be exposed to the

atmosphere only for the minimum time necessary for

load transfer.

b)  Installation and operation of equipment:

1)  All cartridge filters shall be enclosed and

operated in accordance with the procedures and

specifications recommended by the manufacturer for

the cartridge filter. After installation, the

cartridges shall be inspected, monitored and

maintained in accordance with the manufacturer’s

recommendations; and

~*

285

)

)

286

2)  Vents on containers for new solvent and for

solvent-containing waste shall be constructed and

maintained so as to minimize solvent vapor

emissions. Criteria for the minimization of

solvent vapor emissions include the elimination of

solvent buckets and barrels standing open to the

atmosphere, and the repair of gaskets and seals

that expose solvent-rich environments to the

atmosphere, to be determined through visual

inspection.

(Source: Amended at 

—

Ill. Reg. 

______,

effective

____________

_________________________ )

Section 218.609  

Program for Inspection and Repair of 

Leaks

a)  The owner or operator of a petroleum solvent 

dry

cleaning facilitysource shall conduct the following

visual inspections on a weekly basis:

1)  Washers, dryers, solvent filters, settling tanks,

vacuum stills and containers and conveyors of

petroleum solvent shall be

inspected for visible

leaks of solvent liquid.

2)  Pipes, hoses and fittings shall be inspected for

active dripping or dampness.

3)  Pumps and filters shall be inspected for leaks

around seals and access covers.

4)  Gaskets and seals shall be inspected for wear and

defects.

b)  Leaks of petroleum solvent liquid and vapors shall be

repaired within three working days of detection, unless

necessary replacement parts are not on site.

1)  If necessary, repair parts shall be ordered within

three working days of detection of the leak.

2)  The leak shall be repaired within three days of

delivery of necessary parts.

(Source:

Amended at  

Ill. Reg. 

______,

effective

____________

_______________________)

Section 218.610

Testing and Monitoring

a) Compliance

with Sections 218.607(b) (2), 218.608 and

218.609 of this Part shall be determined by visual

inspection; and

287

b)  Compliance with Sections 218.607(a) (2) and (b) (1) ~

this Part shall be determined by methods described in

EPA—450/3-82—009 (1982) incorporated by reference in

Section 218.112 of this Part.

c) If a control device is

used to comply with Section

218.607(a) (1) of this Part, then compliance shall be

determined using 40 CFR 60 

Appendix A, Method 25 (1984)

incorporated by reference in Section 218.112 of this

Part.

(Source: Amended at 

—

Ill. Reg.    

effective

____________

_______________________ )

Section 218.611  

Exemption for Petroleum Solvent Dry Cleaners

The provisions of Sections 218.607 through 218.610 of this Part

shall not apply to petroleum solvent 

dry

cleaning facilities

sources whose emissions of VOM do not exceed 91 megagrams (100

tons) per year in the absence of pollution control equipment or

whose emissions of VON, as limited by the operating permit, will

not exceed 91 megagrams (100 tons) per year in the absence of

pollution control equipment.

(Source: Amended

at

Ill. Reg.    

effective 

____________

_________________________ )

Section 218.612  

Compliance Dates (Repealed)

Oowncro and operators of cmission sources subject to 35 Ill. Ada.

Code 315.607 through 215.609 as of December 31, 1907 shall have

complied with the requirements set forth therein no later than

December 31, 1987.

(Source: Repealed at

—

Ill. Reg. 

______,

effective 

___________

______________________)

Section 218.613  

Compliance Plan (Re~ea1ed)

e-)-  The owner or operator of an emission souroo subject-to

35 Ill. Ada. Code 215.610(a) as of May 31, 1987 shall

have submitted to the Agency a compliance plan,

including a project completion schedule whore

applicable, no later than Nay 31, 1987.

b)-  The plan and schedule shall moot the requirements of 35

Ill. Adm. Code 201.

(Source: Repealed at  

Ill. Reg. 

______,

effective 

___________

_________________________ )

SUBPART AA:

PAINT AND INK MANUFACTURING

288

Section 218.620  Applicability

a)  This ~eubpart shall apply to all paint and ink

manufacturing plantasources which:

1)  Include process emission aourocsunits not subject

to Subparts B, E, F (excluding Section 218.204(1)

of this Part), H j.excluding Section 218.405 ~

this Part), 

Q, R, S, T (excluding Section 218.4M

of this Part). V, X, Y, Z or BB of this Part; and

which as a group both:

A) fibave 

maximum theoretical emissions of 91 

Mg

(100 tons) or more per calendar year of VON

if no air pollution control equipment were

used, and

B)  Aere not limited to less than 91 Mg (100

tons) of VON emissions per calendar year in

the absence of air pollution control

equipment, through production or capacity

limitations contained in a federally

enforceable construction permit or a SIP

revision, or

2)  Produce more than 7,570,820 1 (2,000,000 gal) per

calendar year of paint or ink formulations, which

contain less than 10 percent (by weight) water,

and ink formulations not containing as the primary

solvents water, Magie oil or glycol.

b)  For the purposes of this Subpart, uncontrolled VON

emissions are the emissions of VON which would result

if no air pollution control equipment were used.

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

____________

_________________________ )

Section 218.621  

Exemption for Waterbase Material and

Heatset—Offset Ink

The requirements of Sections 218.624.~.and 218.625 and Section

218.628(a) of this Part shall not apply to equipment while it is

being used to produce either:

a)  p~aintor ink formulations which contain 10 percent or

more (by weight) water, or

b)

4~nks

containing Magie oil and glycol as the primary

solvent.

289

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

____________

_________________________)

Section 2 18.623  

Permit Conditions

No person shall violate any condition in a permit when 

the

condition results in exclusion of the plantsource or an emission

sourocurtit from this Subpart.

(Source: Amended at  

Ill. Reg. 

______,

effective

____________

_________________________)

Section 218.624  

Open-tIop Mills, Tanks, Vats or Vessels

No person shall operate an open-top mill, tank, vat or vessel

with a volume of more than 45 1 (12 gal) for the production of

paint or ink unless:

a)  The mill, tank, vat or vessel is equipped with a cover

which completely covers the mill, tank, vat or vessel

opening except for an opening no larger than necessary

to allow for safe clearance for a mixer shaft. Such

cover shall extend at least 1.27 cm (0.5 in) beyond the

outer rim of the opening or be attached to 

the

rim.

b)  The cover remains closed except when production,

sampling, maintenance

or inspection procedures require

access.

C)   The cover is maintained in good condition such that,

when in place, it maintains contact with the rim of the

opening for at least 90 percent of the circumference of

the rim.

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

____________

_________________________ )

Section 

218.628

Leaks

The owner or operator of a paint or ink manufacturing plantsource

shall, for the purpose of detecting leaks, conduct an equipment

monitoring program as set forth below:

a)  Each pump shall be checked by visual inspection each

calendar week for indications

of leaks, that is,

liquids dripping

from the pump seal. If there are

indications of liquids dripping from the pump seal, the

pump shall be 

repaired

as soon as practicable, but no

later than 15 calendar days after the leak is detected.

b)

Any

pump, valve, pressure relief valve, sampling

connection, open-ended valve and flange or connector

290

containing a fluid which is at least 10 percent VON by

weight which appears to be leaking on the basis of

sight, smell or sound shall be repaired as soon as

practicable, but no later than 15 calendar days after

the leak is detected.

c)  A weather proof, readily visible tag, in bright colors

such as red or yellow, bearing an identification 

number

and the date 

on which the leak was detected shall be

attached to 

leaking equipment. The tag may be 

removed

upon repair, that is, when the equipment is adjusted or

otherwise altered to allow operation without leaking.

d) When a leak is detected, the owner or operator shall

record the date of detection and repair and the record

shall be retained at the plantsource for at least two

years from the date of each detection or each repair

attempt. The record shall be made available to any

person upon verbal or written request during business

hours.

(Source: Amended at 

—

Ill. Reg.    

effective 

____________

_______________________)

Section 218.636  

Compliance Schedule

Every owner or operator of 

an emission source subject to the

control requirements of this Subpart shall comply with the

requirements thereof on and after a date consistent with Section

218.106 of this Part.

(Source: Amended at 

—

Ill. Reg.    

effective 

____________

_________________________ )

Section 218.637

Recordkeeping and Reporting

a)  Upon request by the Agency, the owner or operator of an

emission source which claims to be exempt from the

requirements of this Subpart shall submit records to

the Agency within 30 calendar days from the date of the

request which document that the emission source is in

fact exempt from this Subpart. These records shall

include (but are not limited to) the percent water (by

weight) in the paint or 

ink

being produced and the

quantity of Magie oil, glycol and other solvents in the

ink

being produced.

b)  Every owner or 

operator of

a~iemission source which is

subject to the requirements of this Subpart shall

maintain all records necessary to demonstrate

compliance with those requirements at the facility

source for three years.

291

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

____________

_________________________ )

SUBPART BB: POLYSTYRENE PLANTS

Section ~-1C.875218.640 Applicability of Cubpart BB

The provisions of this Subpart shall apply to polystyrene plants:

a)  Which use continuous processes to manufacture

polystyrene

polybutadiene co-polymer; and

b)  Which fall within Standard Industrial Classification

Group No. 282, Industry No.

2821, except that the

manufacture of polystyrene resins need not be the

primary manufacturing process at the plant.

(Source: Renumbered from Section 218.875 and amended at 

____

Ill. Reg. 

_____,

effective 

______________________)

Section 218.877218.642 Emissions Limitation at Polystyrene

Plants

No person shall cause or allow the emissions of VON from the

material recovery section to exceed 0.12 kg of Volatile Organic

Material per 1000 kg of polystyrene resin produced.

(Source: Renumbered from Section 218.877 at 

—

Ill. Reg.

effective 

_____________________________)

Section 2-1~&.886218.644 Emissions Testing

a)  Upon a reasonable request by the Agency, the owner or

operator of a polystyrene plant subject to this Subpart

shall at his 

own

expense demonstrate compliance 

by use

of the following method: 40 CFR 60, Appendix A, Method

25

Determination of Total Gaseous Non—Methane Organic

Emissions as Carbon (1984), incorporated by reference

in Section 218.112 of this Part.

b) A person planning to conduct

a VON emissions test to

demonstrate compliance with this Subpart shall notify

the Agency of that intent not less than 30 days before

the planned initiation of the tests so the Agency may

observe the test.

(Source: Renumbered from Section 218.886 and amended at 

____

Ill.

Reg.

_____,

effective

_______________________)

Section 218.875

Applicability

of Subpart BB (Renumbered)

292

(Source: Renumbered to Section 218.640 at 

____

Ill. Reg.

effective

______________)

Section 218.877  

Emissions Limitation at Polystyrene Plants

(Renumbered)

(Source: Renumbered to 

Section

218.642 at 

____

Ill. Reg.

effective

______________)

Section 218.879  

Compliance Date (Repealed)

Every

owner 

and operator of an emission source 

subject 

to 35 III.

Ada. Code 215, Cubpart EB, as of December 31, 1987, shall have

oompliod with its standards and limitations by Docombor 31, 1987.

(Source: Repealed at 

—

Ill. Reg. 

______,

effective 

___________

______________________)

Section 218.881  

Compliance Plan (Repealed)

a-)-   The owner or operator of an omission source formerly

subjoot to the requirements of 35 Ill. Ada. Cede 315

Cubpart

BB shall have submitted to the Agency a

compliance plan in accordance with 35 Ill. Adm. Code

201, Cubpart H, including

a project completion schedule

en or bcfore 

December 1, 1987.

-b3-  Unless the submitted ooiapliancc plan or schedule was

disapproved by the Agency, the owner or operator of n

facility or emission sourcc subject to this Cubpart may

operate the emission source according to the plan and

schedule as submitted.

c-I-  The plan and schedule shall moot the requirements of 35

Ill. 

Ada. 

Code 201, Cubpart H and Cootion 218.803.

(Source: Repealed at 

—

Ill. Reg.    

effective 

____________

Section 218.883  

Special Requirements for Compliance Plan

(Repealed)

For

sources 

subject 

to -this Subpart,

an approvable complianee

plan shall inolude~

c-I-

description

emiot3ions

of each process

limitation;

which is 

subject to an

Quantification of the emissions 

from each process;

A description 

of the procedures and methods used to

determine the emissions 

-of

VON;

293

4)-  A description of the methods which will be used to

demonstrate oomplianoe 

with 

the allowable plantwide

emission limitation (Section 215.877), including a

method of inventory, rocordkceping and omission

th1.IhUUJ.~ILXOfl or measurement.

(Source: Repealed at  

Ill. Reg. 

______,

effective 

___________

_____________________)

Section 218.886  

Emissions Testing 

(Renumbered)

(Source: Renumbered to Section 218.644 at 

____

Ill. Reg.

effective 

____________________________)

SUBPART PP: MISCELLANEOUS FABRICATED PRODUCT MANUFACTURING

PROCESSES

Section 218.920  

Applicability

a)  The requirements of this Subpart shall apply to a

plant’ssource’s miscellaneous fabricated product

manufacturing process emission

courccaunits which are

not included within any of the source 

categories

specified in Subparts B, E, F, H, 

Q, R, S,

L..

V1

X, Y.1..

Z or or BB of this Part, if 

the

plantsource is subject

to this Subpart. A plantsource is subject to this

Subpart if it contains process emission souroosunits,

not regulated by Subparts B, E, F (excluding Section

218.204(1) of this Part), H (excluding Section 218.405

of this Part), Q, R, S, T (excluding Section 218.486 of

this Part). V, X, Y~e~Z or BB of this Part; which as

a group both:

1)  fihave maximum theoretical 

emissions

of 91 Mg (100

tons) or more per calendar year of VON if no air

pollution control equipment were used, and

2)  Aare not limited to less than 91 Mg (100 tons) of

VON emissions per calendar year in the absence of

air pollution control equipment, through

production or capacity limitations contained in a

federally enforceable con3truction permit or a SIP

revision.

b)  If a 

plantsource ceases to

fulfill the criteria of

Subsection (a) of this Section, the requirements of

this Subpart shall continue to apply to a miscellaneous

organic chemical manufacturing process emission

ocurocunit which was ever subject to the control

requirements of Section 218.966 of this Part.

C)   No limits under this Subpart shall apply to emission

scurocounits with emissions of VON to 

the

atmosphere

less than or equal to 0.91 Mg (1.0 ton) per calendar

year if the total emissions from such emission units

sources

not complying with Section 218.966 of this Part

does not exceed 4.5 Mg (5.0 tons) per calendar year.

d)  For the purposes of this Subpart, an emission source

unit

shall be considered regulated by a Subpart if it

is subject to the limits of that Subpart. An emission

sourocunit is not considered regulated by a Subpart if

it is not sublect to the limits of that Subpart. e.g..

the emission unit is covered by an exemption in the

Subpart or the ap~licabilitvcriteria of the Subpart

are not met. its emissions    

o~the applicability

300

~riiircpic covered by an

c~cmpt ion.

e)  For the purposes of this Subpart, uncontrolled VON

emissions are the emissions of VON which would result

if no air pollution control equipment were used.

Zj The control requirements in Subpart PR shall not a~o1v

to sewage treatment plants; vegetable oil extraction

and processing: coke ovens (including by-product

recovery ~1ants): fuel combustion units: bakeries:

barae loading facilities: let engine test cells:

production of polystyrene foam insulation board

including storage

and extrusion of scrap where blowina

agent is added to the polystyrene resin at the source..

but not including blending and preliminary exoansion of

resin prior to molding where blowing aaent is

incoriorated into the polystyrene resin by the producer

of the resin: production of polystyrene foam packaaina

not including blendng and preliminary expansion of

resin prior to molding where blowing agent is

incorporated into the polystyrene resin by the producer

of the resin and not including storage and extrusion of

scrap where blowing agent is added to the polystyrene

resin at the source: and iron

and steel production.

(Source: Amended at  

Ill. Reg. 

______,

effective 

____________

_______________________ )

Section 218.963  

Permit Conditions

No person shall violate any condition in a permit when the

condition results in exclusion of the plantsource or an emission

sourocunit from this Subpart.

(Source: Amended at  

Ill. Reg. 

______,

effective 

___________

_______________________ )

Section 218.966  

Control Requirements

Every owner or operator of an cmicision souroca miscellaneous

organic chemical manufacturing process emission unit subject to

this Subpart shall comply with the requirements of subsection

(a)~e~(b)or (C) below.

a)  Emission capture and control techniques which achieve

an overall reduction in uncontrolled VON emissions of

at least 81 percent from each emission unit, or

(Board Note: For the purpose of this provision~. an

emission unit is any part or activity at 

a

source of a

type that by itself is subject to control reauirements

301

in other Subparts of this Part or 40 

CFR

60.

incorporated by reference in Section 218.112. e.g.. a

coatina line, a printing line, a process unit. a

wastewater system. or other equi~ment or is otherwise

any part or activity at a source.)

b)  An alternative control plan which has been approved by

the Agency and approved by the USEPA in a federally

enforceable permit or as a SIP revision.

ci

AnY

leaks from components sublect to the control

requirements of this Subpart shall be sublect to the

following control measures by March 15. 1995:

j,i  Repair any component from which a leak of VOL can

be observed. The repair shall be completed as soon

as practicable but no later than 15 days after the

leak is found, unless the leaking component cannot

be repaired until the next process unit shutdown.

in which case the leaking component must be

repaired before the unit is restarted.

~  For any leak which cannot be readily repaired

within one hour after detection, the following

records, as set forth in this subsection, shall be

kent. These records shall be maintained by the

owner or operator for a minimum of two years after

the date on which they are made. Copies of the

records shall be made available to the Aaency or

USEPA upon verbal or written reauest.

~j The name and identification of the leaking

component

~j The date and time the leak is detected

~  The action taken to repair the leak: and

pj The date and time the leak is repaired.

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

___________

_______________________

)

Section 218.967  

Compliance Schedule

Every owner or operator of an emission sourocunit subject to the

control requirements of this Subpart shall comply with the

requirements of this Subpart on and after a date consistent with

Section 218.106 of this Part.

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

____________

_________________________ )

302

Section 218.968  

Testing

a)  When in the opinion of the Agency it is necessary to

conduct testing to demonstrate compliance with Section

218.966 of this Part, the owner or operator of a VON

emission ciourceunit subject to the requirements of this

Subpart shall, at his own expense, conduct such tests

in accordance with the

applicable test methods and

procedures specified in Section 218.105 of this Part.

Nothing in this Section shall limit the authority of

the USEPA pursuant to the Clean Air Act, as amended, to

require testing.

(Source: Amended at 

—

Ill. Reg.    

, effective 

____________

_______________________

)

SUBPART TT: OTHER EMISSION COURCEC UNITS

Section 218.980  

Applicability

a)  The requirements of this Subpart shall apply to a

p-lzint’-ssource’s VON emission souroesunits, which are

not included within any of the souroc categories

specified in Subparts B, E, F, H, Q, R, S, ~ V, X, Y,

2, AA, ~ PP, QQ, or PR of this Part, or are not

exempted from permitting requirements pursuant to 35

Ill. 

Adm.

Code 201.146, if the plantsource is subject

to this Subpart.

A plantsource is subject to this

Subpart if it contains process emission courceounits,

not regulated by Subparts B, E, F (excluding Section

218.204(1) of this Part), H (excluding Section 218.405

of this Part), Q, R, 

5,

T (excluding Section 218.486 of

this Part), V, X, Y e~ 2 or BB of this Part, which as

a group both:

1)  ~have maximum 

theoretical emissions of 91 Mg (100

tons) or more per calendar year of VON if no air

pollution control equipment were used, and

2)  Aare not limited to less than 91 Mg (100 tons) of

VON emissions per calendar year in the absence of

air pollution control

equipment, through

production or capacity limitations contained in a

federally enforceable construction or operating

permit or a SIP revision.

If a plantsource ceases to fulfill the criteria of

subsection (a), of this Section the requirements of

this Subpart shall continue to apply to an emission

ciourceunit which

was ever subject to the control

requirements of Section 218.986 of this Part.

303

No limits under this Subpart shall apply to emission

oourocounits with emissions of VOM to the atmosphere

less than or equal to 2.3 Mg (2.5 tons) per calendar

year if the total emissions from such emission units

sources not complying with Section 218.986 of this

Part

does not exceed 4.5 Mg (5.0 tons) per calendar year.

d)  For the purposes of this Subpart, an emission 

source

unit 

shall be considered regulated by a Subpart if it

is subject to the limits of that Subpart. An emission

courocunit is not considered regulated by a Subpart if

it is not sublect to the limits of that Subpart. e.g..

the emission unit is covered by an exemption in the

Subpart or the ap~licabi1itycriteria of the 

Subpart

are not met. its omissions arc below the applicability

cutoff level or if the

source is covered by an

exemption.

The control requirements in Subparts,

~

PR, CC 

and TT

shall not apply to sewage treatment plants7j. vegetable

oil extraction and processingj plants, coke ovens

(including by-product recovery plants),-j. fuel

combustion units oourocs,j bakeriesrj. barge loading

facilitiesTj.

jet engine test cellsT~pharmaceutical

manufacturing production of polystyrene

foam 

insulation

board -(-including storage and extrusion of scrap where

blowing agent is added to the polystyrene resin at the

plant source*. but not including blending and

preliminary expansion of resin prior to molding where

blowing aaent is incorporated into the ~olvstvrene

resin by the producer of the resin7.L production of

polystyrene foam packaging .fnot including blending and

preliminary expansion of resin prior to molding where

blowing agent is incorporated into the polystyrene

resin by the Producer of the resin+, and not including

storage and extrusion of scrap where blowing agent is

added to the polystyrene resin at the plantsource3-,-j

and iron and steel production.

(Source: Amended at  

Ill. Reg. 

______,

effective 

___________

_________________________ )

Section 218.983  

Permit Conditions

No person shall violate any condition in a permit when the

condition results in exclusion of the plantsource or an emission

sourocunit from this Subpart.

(Source:

Amended at

—

Ill. Reg.

______,

effective

____________

_________________________ )

Section 218.986  

Control Requirements

304

Every owner or operator of an emission courceunit subject to this

Subpart shall comply with the requirements of subsection (a), (b)

e~ (c).(d),. or (e) below.

a)  Emission capture and control equipment which achieve an

overall reduction in uncontrolled VON emissions of at

least 81 percent from each emission unit, or

(Board Note: For the purpose of this provision. an

emission unit is

any part or activity at a source of a

tv~ethat 

by itself is subject

to control r-eauirements

in other Subparts of this Part or 40 CFR 60.

incorporated by reference in Section 218.112, e.g.. a

coating line. a printing line, a process unit. a

wastewater system, or other equipment. or is otherwise

any mart or activity at a source.)

b) For coating lines, the daily—weighted average VON

content shall not exceed 0.42 kg VOM/l (3.5 lbs

VOM/gal) of coating (minus water and any compounds

which are specifically

exempted from the definition of

VON) as applied during any day.

Owners and operators

complying with this Section are not required to comply

with Section 218.301 of this Part, or

c)  An alternative control plan which has been approved by

the Agency and approved

by the USEPA in a federally

enforceable permit or as a SIP revision.

Non—contact process water cooling towers which are

subject to the control requirements of this Subpart

shall comply with the following control measures no

later than March 15, 1995 or upon initial startup:

~J The owner or operator of a non-contact process

water cooling tower shall perform the following

actions to control emissions of volatile organic

material (VOM) from such a tower:

Al Inspect and monitor such tower to identify

leaks of VON into the water, as further

specified in subsection (d) (3) below:

~i When a leak is identified, initiate and carry

out steps to identify the specific leaking

component or components as soon as

practicable,

as further specified in

subsection (d) (4) below.

~j

When a

leaking component is identified which:

305

j) Can be removed from service without

disrumting production, remove the

component from service

jj)~. Cannot be removed from service without

disrupting

production. undertake repair

of the comPonent at the next reasonable

opmortunity to do so Includina any

period when the commonent is out of

service for scheduled maintenance. as

further specified in subsection (d) (4~

below

QJ

Maintain records of inspection and monitorina

activities, identification of leaks and

leaking components. elimination and remair of

leaks, and operation of eauipment as related

to these activities, as further specified in

subsection (d) (5) below.

A VON leak shall be considered to exist in a non-

contact Process water cooling water system if the

VON emissions or VON content exceed background

levels as determined by monitoring conducted in

accordance with subsection (d) (3) (A) below.

~j.. The owner or operator of an non—contact mrocess

water cooling tower shall carry out an inspection

and monitoring program to identify VON leaks in

the cooling water system.

Al The owner or operator of a non—contact

process water cooling tower shall submit to

the Agency a proposed monitoring program,

accompanied by technical justification for

the program, including justification for the

sampling location(s), parameter(s) selected

for_measurement, monitoring and inspection

freauencv, and the criteria used relative to

the monitored marameters to determine whether

a leak exists as specified in subsection

(d) (2) above.

~J..This inspection and monitoring mroaram for

non—contact mrocess 

water cooling towers

shall include, but shall not be limited to:

LL Monitoring of each such tower with a

water flow rate of 25,000 ~allons per

minute or more at a 

metroleum ref

inerv

at least weekly and monitoring of other

towers at least monthly

306

.jjj Inspection of each such tower at least

weekly if monitoring is not merformed at

least weekly.

Q.l

21i.is inspection and monitoring proaram shall

~ carried out in accordance with written

mrocedures which the Agency shall smecjfv as

a condition in a federally enforceable

operating permit. These procedures shall

include the VOM background levels for the

cooling tower as established by the owner or

operator through monitoring: describe the

locations at which samples will be taken:

identify the parameter(s) to be measured. the

frequency of measurements. and the procedures

for monitoring each such tower, that is,

taking of samples and other subse~ent

handling and analyzing of samples; provide

the criteria used to determine that a leak

exists as specified in subsection (d) (2)

above: and describe the records which will be

maintained.

A non-contact process water cooling tower is

exempt from the requirements of subsections

(d) (3) (B) and (d) (3) (C) above if all

equipment where leaks of VOM into cooling

water may occur is operated at a minimum

pressure in the cooling water of at least 35

kPa greater than the maximum pressure in the

process fluid.

il The repair of a leak in a non—contact process

water cooling tower shall be considered to be

commleted in an acceptable manner as follows:

Al Efforts to identify and locate the leaking

components are initiated as soon as

practicable, but in no event later than three

days after detection of the leak in the

cooling water tower

~  Leaking components shall be remaired or

removed from service as soon as mossible but

no later than 30 days after the leak in the

cooling water tower is detected, unless the

leaking components cannot be repaired until

the next scheduled shutdown for maintenance.

~1

The

owner or operator of a non—contact process

water cooling tower shall keep records as set

forth below in this subsection. These records

307

shall be retained at 

a readily accessible location

at the source and shall be available for

inspection and co~yin~by the Aaency for at least

3 years:

Al Records of inspection and monitoring

activity:

~j Records of each leak identified in such

tower. with date. time and nature of

observation or measured level of parameter~

Qj Records of activity to identify leakina

components, with date initiated.

summary

of

components inspected with dates. and method

of inspection and observations

~j Records of activity to remove a leakina

commonent from service or repair a leaking

component, with date initiated and completed.

descrimtion of actions taken and the basis

for determining the leak in such tower has

been eliminated. If the leaking commonent is

not identified, repaired or eliminated within

30 days of initial identification of a leak

in such tower, this report shall include

specific reasons why the leak could not be

eliminated sooner including all other

intervening periods when the process unit was

out of service, actions taken to minimize VON

losses prior to elimination of the leak and

any actions taken to Prevent the recurrence

of a leak of this type.

~j The owner or omerator of a non—contact mrocess

water cooling tower shall submit an annual report

to the Agency which provides:

Al The number of leaks identified in each

cooling tower

DI

A general description of activity to repair

or eliminate leaks which were identified

~j Identification of each leak which was not

repaired in 30 days from the date of

identification of a leak in such a tower,

with description of the leaks. explanation

why the leak was not 

repaired in 30 days:

308

~j Identification of any periods when reauired

inspection and monitoring activities were not

carried out.

Any

leaks 

from components subject to the control

requirements of this Subpart shall be subiect to

the

following control measures by March 15, 1995:

.3J.  Remair any commonent from which a leak of VOL can

be observed. The repair shall be commieted as Boon

as practicable but no later than 15 days after 

the

leak is found. unless the leakina commonent cannot

be repaired until the next process unit shutdown.

in which case the leaking component must be

repaired before

the unit is restarted.

21

For any leak which cannot 

be readily remaired

within one hour after detection, the following

records, as set forth below in this subsection,

shall be kept. These records shall be maintained

by the owner or operator for a minimum of two

years after the date on which they are made.

Copies of the records shall be made available to

the Agency or USEPA upon verbal or written

request.

Al The name and identification of the leaking

component:

~j The date and time the leak is detected

Q).,   

The action taken to repair the leak; and

Qj The date and time the leak is remaired.

(Source: Amended at 

—

Ill. Reg. 

______,

effective

____________

_______________________ )

Section 218.987

Compliance Schedule

Every owner or operator of an emissions ciourcounit which is

subject to this Subpart shall comply with the requirements of

this Subpart 

on and

after a date consistent with Section 218.106

of this Part.

(Source: Amended at 

—

Ill. Reg. 

______,

effective

___________

_____________________ )

Section 218.988  

Testing

a)  When in the opinion of the Agency it is necessary to

conduct testing to demonstrate compliance with Section

309

218.986 of this Part, the owner or operator of a VON

emission sourocunit subject to the requirements of this

Subpart shall, at his 

own

expense, conduct such tests

in accordance with the applicable test methods and

procedures specified in Section 218.105 of this Part.

b)  Nothing in this Section shall limit the authority of

the USEPA pursuant to the Clean Air Act, as amended, to

require testing.

(Source: Amended at 

—

Ill. Reg.    

,

effective

___________

_______________________)

SUBPART UI): RECORDKEEPING 

AND

REPORTING FOR NON—CTC COURCEB

Section 218.990  

Exempt Emission LourocoUnits

Upon request by 

the Agency, the owner or operator of an emission

unit source which is exempt from the requirements of Subparts PP,

QQ, PR, TT or Section 218.208(b) of this Part shall submit

records to the Agency within 30 calendar days from the date of

the request that document that the emission unit couroc is exempt

from those requirements.

(Source: Amended at —  Ill. Reg. 

______,

effective 

____________

_______________________ )

Section 218.991  

Subject Emission SourocoUnits

a)

Any

owner or operator of a VON emission sourocunit

which is subject to the requirements of Subpart PP, 

QQ,

PR or TT and complying by the use of emission capture

and control equipment shall comply with the following:

1)  By a date consistent with Section 218.106 of this

Part, or upon initial start—up of a new emission

oourccunit, the owner or operator of the subject

VON emission courceunit shall demonstrate to the

Agency that the subject emission courceunit will

be in compliance on and after a date consistent

with Section 218.106

of this Part, or on and after

the initial start-up date by submitting to 

the

Agency all calculations and other supporting data,

including descriptions and results of any tests

the owner or operator may have performed.

2)  On and after a date consistent with Section

218.106 of this Part, or on and after the initial

start-up date, the owner or operator of a subject

VON emission source shall collect and record all

of the following information each day and maintain

310

the

information at 

the facilitysource for a period

three years:

A)  Control device monitoring data.

B)  A log of operating time for the capture

system, control device, monitoring equipment

and the associated emission source.

A maintenance log for the capture system,

control device and monitoring equipment

detailing all routine and non—routine

maintenance performed including dates and

duration of any outages.

3) On and

after a date consistent with Section

218.106 of this Part, the owner or operator of a

subject VON emission source shall notify the

Agency in 

the

following instances:

Any record showing a violation of the

requirements of Subpart PP,

QQ, RR or TT

shall 

reported by sending a copy of such

record to the

Agency within 30 days following

the occurrence of the violation.

B)  At least 30 calendar days before changing 

the

method of compliance with Subpart PP or TT

from the use of capture systems and control

devices to the use of complying coatings, the

owner or operator shall comply with all

requirements of subsection (b) (1) of this

Section. Upon changing the method of

compliance with Subpart PP or PT from the use

of capture systems and control devices to the

use of complying coatings, the owner or

operator shall comply with all requirements

of subsection (b) of this Section.

Testing

When in the opinion of the Agency it is

necessary to conduct testing to demonstrate

compliance with this Subpart, the owner or

operator of a VON emission source subject to

the requirements of this Subpart shall, at

his own expense, conduct such tests in

accordance with the applicable test methods

and procedures specified in Section 218.105

of this Part.

311

B)  Nothing in this Section shall limit the

authority of the USEPA pursuant to the 

Clean

Air Act, as amended, to require

testing.

b) Any owner or operator of a coating line which is

subject to the requirements of Subpart PP or TT and

complying by means of the daily-weighted average VON

content limitation shall comply with the following:

1)  By a date consistent with Section 218.106 of this

Part, or upon initial

start-up of a coating line

subject to Subpart PP or TT, the owner or operator

of the subject coating line shall certify to the

Agency that the coating line will be in compliance

on and after a date consistent with Section

218.106 of this Part, or on and after the initial

start-up date.

Such certification

shall include:

The name and identification

number of each

coating line which will comply by means of

the daily-weighted average VON content

limitation.

B)  The name and identification number 

of each

coating as applied on each coating line.

C)  The weight of VOM per volume and the volume

of each coating (minus water and any

compounds which are specifically exempted

from the definition of VON) as applied each

day on each coating line.

D)  The instrument or method by which the owner

or operator will accurately measure or

calculate the volume of each coating as

applied each day on each coating line.

E)  The method by which the owner or operator

will create and maintain records each day as

required in subsection (b) (2) of this

Section.

F)  An example of the format in which the records

required in subsection (b) (2) of this Section

will be kept.

2)  On and after a date consistent with Section

218.106 of this Part, or on and after the initial

start—up date, the owner or operator of a subject

coating line

shall collect and record all of the

following information each day for each coating

312

line and maintain the information at the

faoilitysource for a

period of three years:

The name and identification

number of each

coating as applied on each coating line.

B)  The weight of VON per volume and 

the volume

of each coating (minus water and any

compounds which are specifically

exempted

from the definition of VON) as applied each

day on each coating line.

The daily—weighted average VON content of all

coatings as applied on each coating line as

defined in Section 218.104 of this Part.

3)  On and after a date consistent with Section

218.106 of this Part, the owner or operator of a

subject coating line shall notify the Agency in

the following instances:

Any record showing violation of the

requirements of Subpart PP or TT shall be

reported by sending a copy of such record to

the Agency

and the USEPA within 30 days

following the occurrence of the violation.

B)  At least 30 calendar days before changing the

method of compliance with Subpart PP or TT

from the use of complying coatings to the use

capture systems and control devices, the

owner or operator shall comply with all

requirements of subsection (a) (1) of this

Section.

Upon changing the method of

compliance with Subpart PP or TT from the use

of complying coatings to the use capture

systems and control devices, the owner or

operator shall comply with all requirements

of subsection

(a) of this Section.

Any owner or operator of a VON emission source which is

subject to the requirements of Subpart PP, 

QQ, PR or TT

and complying by means of an alternative control plan

which has been approved by the Agency and approved by

the

USEPA 

as a SIP revision shall comply with

the

recordkeeping and reporting requirements specified in

the alternative control plan.

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

____________

_________________________ )

313

Section 218.Appendix A

List of Chemicals Defining Synthetic Organic Chemical and Polymer

Manufacturing

CAS No. a       

Chemical.

105—57—7

Acetal

75—07—0       

Acetaldehyde

107—89—1

Acetaldol

60-35—5

Acetamide

103—84—4

Acetanilide

64-19-7        

Acetic acid

108-24-7

Acetic

anhydride

67—64—1       

Acetone

75-86-5

Acetone cyanohydrin

75-05—8       

Acetonitrile

98—86—2

Acetophenone

75-36-5

Acetyl chloride

74—86-2

Acetylene

107—02—8       

Acrolein

79-06-1

Acrylamide

79-10—7

Acrylic acid & esters

107—13—1       

Acrylonitrile

124—04-9

Adipic acid

3,~—69—3

Adiporiitrile

Alkyl naphthalenes

107—18—6       

Allyl alcohol

107-05—1       

Allyl chloride

1321-11—5

Aminobenzoic acid

111—41—1

Aminoethylethanolamine

123—30-8       

p-aininophenol

628-63-7,       

Amyl acetates

123—92—2

Amyl 

alcohols

110—58—7       

Amyl amine

543—59-9       

Amyl 

chloride

Amyl mercaptans

1322—06-1

Ainyl phenol

62—53—3

Aniline

142—04-1

Aniline hydrochloride

29191—52—4

Anisidine

100—66—3

Anisole

118—92-3

Anthranilic acid

84-65-1

Anthraquinone

100—52—7

Benzaldehyde

55-21—0

Benzamide

71—43—2

Benzene

98—48—6

Benzenedisulfonic acid

CAS No. a

Chemical

98-11-3       

Benzenesulfonic acid

134—81—6

Benzil

76-93-7       

Benzilic acid

314

65-85—0

Benzoic acid

119—53—9       

Benzoin

100—47—0

Benzonitrile

119-61-9

Benzophenone

98-07—7

Benzotrichloride

98-88—4

Benzoyl chloride

100—51-6       

Benzyl alcohol

100—46—9

Benzylaiuine

120—51—4

Benzyl benzoate

100—44—7

Benzyl chloride

98-87—3

Benzyl dichloride

92—52—4

Biphenyl

80-05-7

Bisphenol A

10-86-1

Broniobenzene

27497—51-4

Bromonaphthalene

106-99-0

Butadiene

106—98—9       

1—butene

123—86—4       

n—butyl acetate

141-32-2

n-butyl acrylate

71—36—3

n—butyl alcohol

78—92-2        

s-butyl alcohol

75—65-0

t-butyl alcohol

109-73-9

n-butylamine

13952—84—6      

s—butylamine

75-64-9

t-butylamine

98-73-7        

p-tert-butyl benzoic acid

107—88—0

1,3—butylene glycol

123-72-8

n-butyraldehyde

107-92-6

Butyric acid

106-31-0       

Butyric anhydride

109-74—0       

Butyronitrile

105—60-2       

Caprolactam

75—1—50

Carbon disulfide

558-13—4

Carbon tetrabromide

55-23-5        

Carbon tetrachloride

9004—35—7

Cellulose acetate

79-11—8        

Chloroacetic acid

108—42-9       

m-chloroaniline

95—51-2

o—chloroaniline

106-47—8

p—chloroaniline

35913—09—8

Chlorobenzaldehyde

108—90—7       

Chlorobenzene

118—91-2,

Chlorobenzoic acid

S35~8O~8L

CAS No. ~

Chemical

2136—81—4,

Chlorobenzotrichloride

2136—89—2

5216—25—1

1321—03—5       

Chlorobenzoyl chloride

75-45—6

Chiorodifluoroethane

315

25497-29—4

Chiorodifluoromethane

67—66-3

Chloroform

25586—43—0

Chloronaphthalene

88—73-3

o-chloronitrobenzene

100-00-5

p-chloronitrobenzene

25167—80—0      

Chlorophenols

126-99-8

Chloroprene

7790—94—5

Chlorosulfonic acid

108—41—8

m-chlorotoluene

95-49-8       

o-chlorotoluene

106—43-4       

p-chlorotoluene

75-72—9       

Chiorotrifluoromethane

108—39—4

m—cresol

95—48—7

o—cresol

106—44—5

p—cresol

1319-77-3

Mixed cresols

1319-77-3      

Cresylic acid

4170-30—0      

Crotonaldehyde

3724-65—0

Crontonic acid

98—82—8

Cumene

8 0-15-9

Cuinene 

hydroperoxide

372—09—8

Cyanoacetic acid

506—77-4       

Cyanogen chloride

108—80-5       

Cyanuric acid

108-77-0       

Cyanuric chloride

110—82-7

Cyclohexane

108—93—0       

Cyclohexanol

108—94-1       

Cyclohexanone

110—83-8       

Cyclohexene

108—91-8       

Cyclohexylamine

111—78-4

Cyclooctadiene

112—30—1       

Decanol

123-42-2       

Diacetone alcohol

27576-04-1      

Diaminobenzoic acid

95-76—1,

Dichloroaniline

95—82—9,

554—00—7,

608—27—5,

608—31—1,

626—43—7,

CAS No. a

Chemical

27134—27—6

573 11—92—9k

541-73-1       

m-dichlorobenzene

95-50-1

o-dichlorobenzene

106—46—7

p—dichlorobenzene

75—71—8        

Dichlorodifluoromethane

111-44-4       

Dichloroethyl ether

107-06-2       

1,2-dichioroethane (EDC)

96—23—1        

Dichlorohydrin

26952—23—8      

Dichioropropene

316

101—83—7       

Dicyclohexylamine

109-89-7

Diethylamine

111—46—6

Diethylene glycol

112-36-7

Diethylene glycol diethyl ether

111-96—6

Diethylene glycol dimethyl

ether

112-34-5

Diethylene glycol monobutyl

ether

124-17-7

Diethylene glycol mononbutyl

ether

acetate

111-90-0

Diethyi.ene glycol monoethyl

ether

112-15-2       

Diethylene glycol monoethyl

ether acetate

111-77-3

Diethylene glycol monomethyl

ether

64-67-5

Diethyl sulfate

75—37—6       

Difluoroethane

25167-70-8      

Diisobutylene

26761—40—0

Diisodecyl phthalate

27554—26-3      

Diisooctyl phthalate

674—82—8       

Diketene

124-40-3       

Dimethylamine

121—69-7

N,N-dimethylaniline

115—10-6       

N,N-dimethyl ether

68-12—2

N, N-dimethylformainide

57-14-7       

Dimethyihydrazine

77—78-1

Dimethyl sulfate

75-18-3        

Dimethyl sulfide

67—68—5       

Dimethyl sulfoxide

120-61-6       

Dimethyl terephthalate

99—34-3        

3,5—dinitrobenzoic acid

51-28—5       

Dinitrophenol

Dinitrotoluene

123-91—1

Dioxane

646—06—0

Dioxilane

CAS

No. a

Chemical

122—39—4

Diphenylainine

101-84-4

Diphenyl oxide

102—08—9

Diphenyl thiourea

25265-71-8

Dipropylene glycol

25378—22-7

Dodecene

28675—17—4      

Dodecylaniline

27193—86-8

Dodecylphenol

106-89-8

Epichlorohydrin

64—17—5

Ethanol

Ethanolamines

141—78—6       

Ethyl acetate

141-97-9       

Ethyl acetoacetate

140-88—5       

Ethyl acrylate

317

75—04—7       

Ethylainine

100—41-4

Ethylbenzene

74-96-4        

Ethyl bromide

9004—57—3

Ethylcellulose

75-00-3        

Ethyl chloride

105—39-5

Ethyl chloroacetate

105—56-6

Ethylcyanoacetate

74—85—1

Ethylene

96—49—1

Ethylene carbonate

107-07-3       

Ethylene chlorohydrin

107—15—3       

Ethylenediamine

106-93-4

Ethylene dibromide

107—21—1       

Ethylene glycol

111-55-7

Ethylene glycol diacetate

110-71-4

Ethylene glycol dimethyl ether

111-76-2       

Ethylene glycol monobutyl ether

112-07-2       

Ethylene glycol monobutyl ether

acetate

110-80-5

Ethylene glycol monoethyl ether

111-15-9

Ethylene glycol monoethyl ether

acetate

109-86-4

Ethylene glycol monoethyl ether

110—49—6       

Ethylene glycol monomethyl

ether acetate

122—99-6

Ethylene glycol monophenyl

ether

2807-30-9      

Ethylene glycol monopropyl

ether

75—21-8       

Ethylene oxide

60-29-7        

Ethyl ether

104—76-7       

2-ethylhexanol

122—51-0

Ethyl orthoformate

95-92-1        

Ethyl oxalate

41892—71—1      

Ethyl sodium oxaloacetate

CAS

No. a       

Chemical

50—00-0       

Formaldehyde

75—12—7

Formamide

64—18-6       

Formic acid

110—17—8       

Fuinaric acid

98—01-1        

Furfural

56—81—5        

Glycerol (Synthetic)

26545—73-7

Glycerol dichlorohydrin

25791—96—2

Glycerol triether

56—40—6

Glycine

107—22—2

Glyoxal

118-74-1       

Hexachlorobenzene

67-72-1

Hexachloroethane

36653—82—4

Hexadecyl alcohol

124-09-4

Hexainethylenediamine

629-11-8

Hexamethylene glycol

100-97-0

Hexamethylenetetramine

318

74—90-8

Hydrogen cyanide

123-31-9

Hydroquinone

99-96-7

p-hydroxybenzoic acid

26760—64—5

Isoamylene

78—83—1

Isobutanol

110—19-0

Isobutyl acetate

115-11-7

Isobutylene

78—84-2

Isobutyraldehyde

79-31-2

Isobutyric acid

25339-17—7

Isodecanol

26952—21—6

Isooctyl alcohol

78—78-4

Isopentane

78—59-1

Isophorone

121—91—5

Isophthalic acid

78—79-5

Isoprene

67—63-0

Isopropanol

108—21-4       

Isopropyl acetate

75—31—0        

Isopropylamine

75—29-6        

Isopropyl chloride

25168—06—3      

Isopropylphenol

Ketene

~

Linear alkyl sulfonate*

123—01-3       

Linear alkylbenzene

110—16—7       

Maleic acid

108—31-6

Maleic anhydride

6915—15—7      

Nalic acid

141—79—7

Mesityl oxide

121—47—1       

Netanilic acid

79—41-4       

Nethacrylic acid

563—47—3

Methallyl chloride

67—56-1       

Methanol

CAS No. a

Chemical

79-20-9

Methyl acetate

105—45—3       

Methyl acetoacetate

74—89-5       

Nethylamine

100—61—8

n-methylaniline

74-83-9        

Methyl bromide

37365-71-2      

Methyl butynol

74-87-3

Methyl chloride

108-87-2

Methyl cyclohexane

1331—22-2      

Methyl cyclohexanone

75-09-2

Nethylene chloride

101—77-9

Nethylene dianiline

101-68-8

Methylene diphenyl diisocyanate

78—93-3        

Methyl ethyl ketone

107-31-3       

Methyl formate

108-11-2       

Methyl isobutyl carbinol

108-10-1       

Methyl isobutyl ketone

80-62-6        

Methyl methacrylate

77-75-8

Methylpentynol

98-83-9

B-methylstyrene

319

110—91-8

Morpholine

85-47-2

a-naphthalene sulfonic acid

120-18-3

B-naphthalene sulfonic acid

90—15-3

a-naphthol

135-19-3       

B-naphthol

75-98-9

Neopentanoic acid

88—74-4        

o-nitroaniline

100—01—6

p-nitroaniline

91—23—6

o-nitroanisole

100—17 —4

p—nitroanisole

98-95-3

Nitrobenzene

27178_83_2c

Nitrobenzoic acid (o, m & p)

79-24-3

Nitroethane

75—52-5

Nitromethane

88—75—5

Nitrophenol

25322-01-4      

Nitropropane

1321—12—6

Nitrotoluene

27215—95—8      

Nonene

25154-52—3      

Nonylphenol

27193—28—8      

Octylphenol

123—63-7       

Paraldehyde

115-77-5       

Pentaerythritol

109—66—0       

n-pentane

109—67—1       

1—pentene

127—18—4        

Perchioroethylene

594-42-3       

Perchloromethyl mercaptan

94-70-2        

o-phenetidine

156-43-4

p-phenetidine

CAS No. a       

Chemical

108—95—2

Phenol

98—67—9,       

Phenolsulfonic acids

585—38—6,

609—46—1

133_39_76

9~-4O-7      

Phenyl anthranilic acid

Phenylenediamine

75—44—5       

Phosgene

85-44—9        

Phthalic anhydride

85-41—6

Phthalimide

108—99-6

b-picoline

110—85—0

Piperazine

9003—29-6,

Polybutenes

25036—29—7°

25322—68—3

Polyethylene glycol

25322-69-4

Polypropylene glycol

123-38-6

Propionaldehyde

79—09—4

Propionic acid

71-23—8        

n—propyl alcohol

107-10-8       

Propylamine

540-54-5       

Propyl chloride

115-07-1       

Propylene

320

127-00-4

Propylene chlorohydrin

78—87-5

Propylene dichloride

57—55—6

Propylene glycol

75-56-9

Propylene oxide

110—86—1

Pyridine

106—51—4

Quinone

108—46—3

Resorcinol

27138—57—4

Resorcylic acid

69—72—7

Salicylic acid

127-09-3

Sodium acetate

532-32-1

Sodium benzoate

9004-32-4      

Sodium carboxymethyl cellulose

3926-62-3

Sodium chloroacetate

141—53-7

Sodium formate

139—02—6

Sodium phenate

110—44—1       

Sorbic acid

100-42—5       

Styrene

110—15—6

Succinic acid

110—61—2

Succinitrile

121—57—3       

Sulfanilic acid

126—33—0

Sulfolane

1401-55—4      

Tannic acid

100-21-0       

Terephthalic acid

79.345c      

Tetrachloroethanes

CAS No. a

Chemical

117-08-8       

Tetrachlorophthalic anhydride

78-00-2

Tetraethyllead

119—64-2

Tetrahydronaphthalene

85-43-8        

Tetrahydrophthalic anhydride

75—74—1       

Tetramethyllead

110—60-1       

Tetramethylenediamine

110-18-9

Tetramethylethylenediamine

108883

Toluene

95—80-7        

Toluene—2 , 4—diamine

584—84-9       

Toluene—2 , 4-diisocyanate

26471-62-5      

Toluene diisocyanates (mixture)

1333-07—9       

Toluene sulfonamide

Toluenesulfonic acids

98-59—9

Toluene sulfonyl chloride

26915—12—8      

Toluidines

87-61-6,       

Trichlorobenzenes

108—70—3

120—82—1

71—55—6        

1,1, l—trichloroethan~

79—00—5

1, l,2—trichloroethane

79—01-6

Trichloroethylene

75-69-4

Trichiorofluoromethane

96—18—4

1,2, 3—trichloropropane

76—13—1

1,1, 2—trichloro—l, 2, 2—trifluoro

ethane

121-44-8       

Triethylamine

321

112-27—6

Triethylene glycol

112-49-2

Triethylene glycoldimethyl

ether

7756-94-7       

Triisobutylene

75-50-3       

Trimethylainine

57—13—6

Urea

108—05-4

Vinyl acetate

75—01-4

Vinyl chloride

75-35-4

Vinylidene chloride

25013—15-4      

Vinyl toluene

1330—20—7      

Xylenes (mixed)

95—47-6        

o-xylene

106—42—3       

p—xylene

1300—71—6      

Xylenol

~90—73-8       

Xylidine

‘ ~         

methyl tert-butyl ether

9~2—88-4     

Polyethylene

(~)

Polypropylene

9009—53-6       

Polystyrene

a) CAS

numbers refer to the Chemical Abstracts Registery

numbers assigned 

to specific chemicals, isomers or

mixtures

of chemicals. Some isomers or mixtures that are covered by

the standards do not have CAS numbers assigned to them. The

standards apply to all of the chemicals listed, whether CAS

numbers have been assigned or not.

b)

No

CAS number(s) have been assigned to this chemical, to its

isomers, or mixtures containing these chemicals.

C)

CAS numbers

for some of the isomers are listed: the

standards apply to all of the isomers and mixtures, even if

CAS

numbers have not been assigned.

(Source: Amended at 

—

Ill. Reg.

,  effective 

___________

_________________________)

322

Section 218.Appendix B

VON

Measurement Techniques for Capture 

Efficiency

Procedure G.1

Captured

VOG1~Emissions

1.  INTRODUCTION

1.1 Applicability. This procedure is applicable for determining

the volatile organic materialsoompounda (VOG~j) content of

captured gas streams.

It is intended to be used as a segment in

the development of liquid/gas or gas/gas protocols for

determining

VOq~

capture efficiency (CE) for surface coating and

printing operations. The procedure may not be acceptable in

certain site—specific situations, e.g., when: (1) direct fired

heaters or other circumstances affect the quantity of

VOGM 

at the

control device inlet; and (2) particulate organic aerosols are

formed in the process and are present in the captured emissions.

1.2 Principle. The amount of VOG~,J 

captured (G) is calculated as

the

sum

of the products of 

the

VO~Jcontent (CGj),the flow rate

(QGj),and the sample time (TC) from each captured emissions

point.

1.3 Estimated Measurement 

Uncertainty. The measurement

uncertainties are estimated for each captured or fugitive

emissions point as follows:

QGj= 5.5 percent and

CGj= ±5.0 percent.

Based on these

numbers, 

the probable

uncertainty for G is estimated at about ±7.4 percent.

1.4 Sampling Requirements.

A capture efficiency test shall

consist of at least three sampling runs.

The sampling time for

each run should be at least 8 hours, unless otherwise approved.

1.5 Notes.

Because this procedure is often applied in highly

explosive areas, caution and care should be exercised in choosing

appropriate equipment and installing and using the equipment.

Mention of trade names or

company products does not constitute

endorsement.

All gas concentrations (percent, ppm) are by

volume, unless otherwise noted.

APPARATUS AND REAGENTS

2.1 Gas VOGN Concentration. A schematic of the measurement

system is shown in Figure 1. 

The main components are described

below:

2.1.1 Sample Probe.

Stainless steel, or equivalent.

The probe

shall be heated to prevent VOGIj 

condensation.

2.1.2

Calibration Valve Assembly.

Three-way valve assembly at

the outlet of sample probe to direct the zero and calibration

323

gases to the analyzer.

Other methods, such as quick—connect

lines, to route calibration gases to the outlet of the sample

probe are acceptable.

2.1.3

Sample Line. Stainless steel or Teflon tubing to

transport the sample gas to the analyzer. The sample line must

be heated to prevent condensation.

2.1.4 Sample Pump. 

leak—free pump, to pull the sample gas

through 

the system at a flow rate sufficient to minimize

the

response time of the measurement system. The components of 

the

pump that contact the gas stream shall be constructed of

stainless steel or Teflon. The sample pump must be heated to

prevent condensation.

2.1.5

Sample Flow Rate Control.

A sample flow rate control

valve and rotameter, or equivalent, to maintain a constant

sampling rate within 10 percent.

The flow rate control valve and

rotameter must be heated to prevent condensation.

A control

valve may also be located on the sample pump bypass loop to

assist in controlling the

sample 

pressure and flow rate.

2.1.6

Sample Gas Manifold.

Capable of diverting a portion of

the sample gas stream to the flame ionization analyzer (FIA), and

the remainder to the bypass discharge vent.

The manifold

components shall be constructed of stainless steel or Teflon. If

captured or 

fugitive emissions are to be measured at multiple

locations, the measurement system shall be designed to use

separate sampling probes, lines, and pumps for each measurement

location and a common sample gas manifold and FIA. The sample

gas manifold and connecting lines to the FIA must be heated to

prevent condensation.

2.1.7

organic Concentration Analyzer.

An FIA with a span value

of 1.5 times the expected concentration as propane; however,

other span values may be used if it can be demonstrated that they

would provide more accurate measurements.

The system shall be

capable of meeting or exceeding the following specifications:

2.1.7.1 Zero Drift. Less than ±3.0percent of 

the span value.

2.1.7.2

Calibration Drift.

Less than ±3.0 percent of the span

value.

2.1.7.3

Calibration Error.

Less than ±5.0 percent of the

calibration gas value.

2.1.7.4 Response Time. Less than 30 seconds.

2.1.8 Integratorf Data Acquisition System. An analog or digital

device or computerized data acquisition system used to integrate

the FIA response or compute the average response and record

324

measurement data. The minimum data sampling frequency for

computing average or integrated values is one measurement value

every 5 seconds. The device shall be capable of recording

average values at least once per minute.

2.1.9 Calibration and Other Gases. Gases used for calibration,

fuel, and combustion air (if required) are contained in

compressed gas cylinders. All calibration gases shall be

traceable to NIST standards and shall be certified by the

manufacturer to ±1percent of the tag value. Additionally, the

manufacturer of the cylinder should provide a recommended shelf

life for each calibration gas cylinder over which the

concentration does not change more than ±2percent from the

certified value. For calibration gas values not generally

available, alternative methods for preparing calibration gas

mixtures, such as dilution systems, may be used with prior

approval.

2.1.9.1 Fuel. A 40 percent 112/60 percent He or 40 percent 112/60

percent

N2 gas mixture is recommended to avoid an oxygen

synergism effect 

that reportedly occurs when oxygen concentration

varies significantly from a mean value.

2.1.9.2 Carrier Gas. High purity air with less than 1 ppm of

organic material (as propane or carbon equivalent) or less than

0.1 percent of the span value, whichever is greater.

2.1.9.3 FIA Linearity Calibration Gases. Low-, mid-, and

high—range gas mixture standards with nominal propane

concentrations of 20-30, 45-55, and 70-80 percent of the span

value in air, respectively. Other calibration values and other

span values may be used if it can be shown that more accurate

measurements would be achieved.

2.1.10 Particulate Filter. An in-stack or an out-of-stack glass

fiber filter is recommended if exhaust gas particulate loading is

significant. An out-of—stack filter must be heated to prevent

any condensation unless it can be demonstrated that no

condensation occurs.

2.2 Captured Emissions Volumetric Flow Rate.

2.2.1 Method 2 or 2A Apparatus. For determining volumetric flow

rate.

2.2.2 Method 3 Apparatus and Reagents. For determining

molecular weight of the gas stream. An estimate of the molecular

weight of the gas stream may be used if it can be justified.

2.2.3 Method 4 Apparatus and Reagents. For determining moisture

content, if necessary.

325

3.  DETERMINATION OF VOLUMETRIC FLOW RATE OF CAPTURED EMISSIONS

3.1 Locate all points where emissions are captured from the

affected faoilitycmission unit. Using Method 1, determine the

sampling points. Be sure to check each site for cyclonic or

swirling flow.

3.2 Measure the velocity at each sampling site at least once

every hour during each sampling run using Method 2 or 

2A.

4.  DETERMINATION OF VOC!j CONTENT OF CAPTURED 

EMISSIONS

4.1 Analysis Duration.

Measure the

VO~I,j 

responses at each

captured emissions point during the entire test run or, if

applicable, while the process is operating.

If there are

multiple captured emission locations, design a sampling system to

allow a single FIA to be used to determine the VOC!j 

responses at

all sampling locations.

4.2 Gas

VOG~Concentration.

4.2.1 Assemble the sample train as shown in Figure 1. Calibrate

the FIA according to the procedure in Section 5.1.

4.2.2

Conduct a system check according to the procedure in

Section 5.3.

4.2.3 Install the sample probe so that the probe is centrally

located in the stack, pipe, or duct, and is sealed tightly at the

stack port connection.

4.2.4

Inject zero gas at the calibration valve assembly.

Allow

the measurement system response to reach zero.

Measure the

system response time as the time required for the system to reach

the effluent concentration after the calibration valve has been

returned to the effluent sampling position.

4.2.5 Conduct a system check before and a system drift 

check

after each sampling

run

according to the procedures in Sections

5.2 and 5.3. If the drift check following a run indicates

unacceptable performance, the run

is not valid. The tester may

elect to perform system drift checks during the 

run not to exceed

one

drift 

check per hour.

4.2.6 Verify that the sample lines, filter, and pump

temperatures are 120 ±5°C.

4.2.7 Begin sampling at the start of the test period and

continue to sample during the entire run. Record the starting

and ending times and any required process information as

appropriate. If multiple captured emission locations are sampled

326

using a single FIA, sample at each location for the same amount

of time (e.g., 2 minutes) and continue to switch from one

location to another for the entire test run. Be sure that total

sampling time at each location is the same at 

the end of the test

run. Collect at least 4 separate measurements from each sample

point during each

hour of testing. Disregard the measurements 

each sampling location until two times the response time of the

measurement system has elapsed.

Continue sampling for at least 1

minute and record the concentration measurements.

4.3 Background Concentration.

4.3.1 Locate all NDO’s of the TTE. A sampling point shall be

centrally located outside of the TTE at 4 equivalent diameters

from each NDO, if possible. If there are more than 6 NDO’s,

choose

6 sampling points evenly spaced among 

the NDO’s.

4.3.2 Assemble the sample train as shown in Figure 2. Calibrate

the FIA and conduct a system check according to 

the

procedures in

Sections 5.1 and 5.3. NOTE: This sample train shall be a

separate sampling train from the one to measure the captured

emissions.

4.3.3 Position the probe at the sampling location.

4.3.4 Determine the response time, conduct the system check and

sample according to the procedures described in Sections 4.2.4 to

4.2.7.

4.4 Alternative Procedure. The direct interface sampling and

analysis procedure described in Section 7.2 of Method 18 may be

used to determine the gas VOC concentration. The system must be

designed to collect and analyze at least one sample every 10

minutes.

5.  CALIBRATION AND QUALITY ASSURANCE

5.1 FIA Calibration and Linearity Check. Make 

necessary

adjustments to the air and fuel supplies for the FIA and ignite

the burner. Allow the FIA to warm up for the period recommended

by the manufacturer. Inject a calibration gas into 

the

measurement system and adjust the back—pressure regulator to 

the

value required to achieve the flow rates specified by the

manufacturer. Inject the zero— and the high—range calibration

gases and adjust

the

analyzer calibration to provide the proper

responses.

Inject the low- and mid—range gases and record the

responses of the measurement system.

The calibration and

linearity of the system are acceptable if the responses for all

four 

gases are within 5 percent of the respective gas values.

the performance of the system is not acceptable, repair or adjust

the system and repeat the linearity check. Conduct a calibration

327

and linearity check after assembling the analysis system and

after a major change is made to the system.

5.2 Systems Drift Checks. Select the calibration gas that most

closely approximates the concentration of the captured emissions

for conducting the

drift 

checks. Introduce the zero and

calibration gas at the calibration valve

assembly 

and verify that

the appropriate gas flow rate and pressure are present at the

FIA. Record the measurement system responses to the zero

and

calibration gases.

The performance of the system is acceptable

if the difference between the drift check measurement and the

value obtained in Section 5.1 is less than 3 percent of

the

span

value. Conduct the system

drift 

checks at the end of each run.

5.3 System Check. Inject the high range calibration gas at the

inlet of the sampling probe and record the response. The

performance of the system is acceptable if the measurement system

response is within 5 percent of the value obtained in Section 5.1

for the high range calibration gas. Conduct a system check

before and after each test run.

5.4 Analysis Audit. Immediately before each test analyze an

audit cylinder as described in Section 5.2. The analysis audit

must agree with the audit cylinder concentration within 10

percent.

6. NOMENCLATURE

A~

area of NDO i, ft~-~

AN

total area of all NDO’s in the enclosure, ftZ~~1.

CBI

corrected average VO~jconcentration of background

emissions at point i, ppm propane--j~.

CB

average background concentration,

ppm propane,-~.

CGj

corrected average

VOG!.j concentration of captured

emissions at point j, ppm propane-~-j

CDH

average measured concentration for the drift check

calibration gas, ppm propane-~j.

CDO

average system drift check concentration for zero

concentration gas, ppm propane-~-j

C11

actual concentration of the drift 

check

calibration gas, ppm propane~

Ci

uncorrected average background VOC~concentration

measured at point i, ppm propane-T-j.

328

uncorrected average

VOG)J concentration measured at

point

j, ppm propane-a

total VOQIj 

content of captured emissions,

kgi-j.

1.830 x 10~kg/(m3-ppm)--j

n

number of measurement points-a

QGj

average effluent volumetric flow rate corrected to

s~andard conditions at captured emissions point

j,

m /min~j

total duration 

of captured emissions sampling run,

mm.

7. CALCULATIONS

7.1 Total

VOGZj 

Captured Emissions.

n

G

E

(CGj~CB) QGjTC K1   

Eq. 1

j=1

7.2

VOG~jConcentration 

of the Captured Emissions at Point

j.

CGj

(Cj- CDO)   

CH

Eq. 2

CDH- CDO

7.3 Background VOG1~Concentration at Point i.

CBi

(Ci- CDO)   

C~j

Eq. 3

CDH— CDO

7.4 Average Background Concentration.

n

E CBIAi

CB

i-1

Eq.4

NOTE: If the concentration at each point is within 20 percent of

the average concentration of all points, the terms “A~”and “AN”

may be deleted from Equation 4.

Procedure G.2 

Captured

VOG~Emissions (Dilution Technique)

INTRODUCTION

1.1 Applicability.

This procedure is applicable for determining

the volatile organic eompoundomaterials (VO~~)content 

329

captured gas streams. It is intended to

be used as a segment in

the development of a gas/gas protocol in which fugitive emissions

are measured for determining

VOG?j 

capture efficiency (CE) for

surface coating and printing operations.

A dilution system is

used to reduce the voe~

concentration of the captured emission to

about 

the same concentration as the fugitive emissions.

The

procedure may not be acceptable in certain site-specific

situations,

e.g., when: (1) direct fired heaters or other

circumstances affect 

the quantity of

VO~J 

the

control device

inlet; and (2) particulate organic aerosols are formed in the

process and are present in the captured emissions.

1.2 Principle. The 

amount

of VOG)j captured (G) is calculated as

the

sum

of the products of the

VOG~jcontent (CGj) ,the flow rate

(QGj) ,and the sampling time (Ta) from each captured emissions

point.

1.3 Estimated Measurement Uncertainty.

The measurement

uncertainties

are estimated for each captured or fugitive

emissions point as follows:

QGj= ±5.5 percent and CGj= ±5

percent.

Based on these numbers, the probable uncertainty for G

is estimated at about ±7.4percent.

1.4 Sampling Requirements.

A capture efficiency test shall

consist of at least three sampling runs.

The sampling time for

each run should be at least 8 hours, unless otherwise approved.

1.5 Notes. Because this procedure is often applied in highly

explosive areas, caution and care should be exercised in choosing

appropriate equipment and installing and using the equipment.

Mention of trade names or company products does not constitute

endorsement. All gas concentrations (percent, ppm) are by

volume, unless otherwise noted.

2.

APPARATUS

AND REAGENTS

2.1 Gas VOG~jConcentration. A schematic of the measurement

system is shown in 

Figure

1. The main components are described

below:

2.1.1 Dilution System. A Kipp in-stack dilution probe and

controller or similar device may be used. The dilution rate 

may

be changed by substituting different critical orifices or

adjustments of the aspirator supply pressure. The dilution

system shall be heated to prevent

VOC~jcondensation. 

Note: An

out—of-stack dilution device may be used.

2.1.2

Calibration Valve Assembly. Three-way valve assembly at

the outlet of sample probe to direct the zero and calibration

gases to the analyzer. Other methods, such as quick—connect

330

lines, to route calibration gases to the outlet of the sample

probe 

are acceptable.

2.1.3

Sample Line. Stainless steel or Teflon tubing to

transport the sample gas to the analyzer. The sample line must

be heated to prevent condensation.

2.1.4 Sample Pump. A leak-free pump, to pull

the sample gas

through

the system at a 

flow rate sufficient to minimize the

response

time 

of the measurement system. The components of the

pump

that 

contact the gas stream shall be constructed of

stainless steel or Teflon. The sample pump must be heated to

prevent condensation.

2.1.5

Sample Flow Rate Control.

A sample flow rate control

valve and rotameter, or equivalent, to maintain a constant

sampling rate within 10 percent.

The flow control valve and

rotameter must be heated to prevent condensation. A control

valve may also be located on the sample pump bypass loop to

assist in controlling the sample pressure and flow rate.

2.1.6

Sample Gas Manifold.

Capable of diverting a portion of

the sample gas stream to the flame ionization analyzer (FIA), and

the remainder to the bypass discharge vent. The manifold

components shall be constructed of stainless steel or Teflon.

captured or fugitive emissions are to be measured at multiple

locations, the measurement system shall be designed to use

separate sampling probes, lines, and pumps for each measurement

location and a common sample gas manifold and FIA. The sample

gas manifold and connecting lines to the FIA must be heated to

prevent condensation.

2.1.7

Organic Concentration Analyzer.

An FIA with a span value

of 1.5 times the expected concentration as propane; however,

other span values may be used if it can be demonstrated that they

would provide more accurate measurements. The system shall be

capable of meeting or

exceeding the following specifications:

2.1.7.1

Zero Drift.

Less than ±3.0 percent of the span value.

2.1.7.2 Calibration Drift. Less than ±3.0percent of 

the span

value.

2.1.7.3

Calibration Error.

Less than ±5.0 percent of the

calibration gas value.

2.1.7.4 Response Time. Less than 30 seconds.

2.1.8

Integrator/Data Acquisition System. An analog or digital

device or computerized data acquisition system used to integrate

the FIA response or compute the average response and record

measurement data. The minimum data sampling frequency for

331

computing average or integrated values is one measurement value

every 5 seconds. The device 

shall be capable of recording

average values at least once per minute.

2.1.9 Calibration and Other Gases.

Gases used for calibration,

fuel, and combustion air (if required) are contained in

compressed gas cylinders.

All calibration gases shall be

traceable to NIST standards and shall be certified by the

manufacturer to ±1 percent of the tag value. Additionally, the

manufacturer of the cylinder should provide a recommended shelf

life for each calibration gas cylinder over which the

concentration does not change more than ±2percent from the

certified value.

For calibration gas values not generally

available, alternative methods for preparing calibration gas

mixtures, 

such as dilution systems, may be used with prior

approval.

2.1.9.1 Fuel. A 40 percent H2/60 percent He or 40 percent 112/60

percent N2 gas mixture is recommended to avoid an oxygen

synergism effect that reportedly occurs when oxygen concentration

varies significantly

from a mean value.

2.1.9.2 Carrier Gas and Dilution Air Supply. High purity air

with less than 1 ppm of organic material (as propane or carbon

equivalent) or less than 0.1 percent of the span value, whichever

is greater.

2.1.9.3

FIA Linearity Calibration Gases.

Low—, mid-, and

high—range gas mixture standards with nominal propane

concentrations of 20-30, 45-55, and 70-80 percent of the span

value in air, respectively.

Other calibration values and other

span values may be used if it can be shown that more accurate

measurements would be achieved.

2.1.9.4 Dilution Check Gas. Gas mixture standard containing

propane in air, approximately half the span value after dilution.

2.1.10 Particulate Filter. An in-stack or an out—of-stack glass

fiber filter is recommended if exhaust gas particulate

loading is

significant. An out-of-stack filter must be heated to prevent

any condensation unless it can be demonstrated that no

condensation occurs.

2.2 Captured Emissions Volumetric Flow Rate.

2.2.1 Method 2 or 2A Apparatus.

For determining volumetric flow

rate.

2.2.2 Method 3 Apparatus and Reagents.

For determining

molecular weight of the gas stream. An estimate of the molecular

weight of the gas stream may be used if it can be 

justified.

332

2.2.3

Method

Apparatus and Reagents.

For determining moisture

content, if necessary.

3.  DETERMINATION OF VOLUMETRIC FLOW RATE OF 

CAPTURED

EMISSIONS

3.1 Locate all points where emissions are captured from the

affected facility. Using Method 1, determine the sampling points.

Be sure to check each site for cyclonic or swirling flow.

3.2 Measure the velocity at each sampling site at least once

every hour during each sampling run using Method 

2 or 2A.

4.  DETERMINATION OF VOGi~CONTENT OF CAPTURED EMISSIONS

4.1 Analysis Duration.

Measure the

VOG?j 

responses at each

captured emissions point during the entire test run or, if

applicable, while the process is operating. If there are a

multiple captured emissions locations, design a sampling system

to allow a single FIA to be used to determine the VO~ 

responses

at all sampling locations.

4.2 Gas VOG1j Concentration.

4.2.1 Assemble the sample train as shown in Figure 1. Calibrate

the FIA according to the procedure in Section 5.1.

4.2.2 Set the dilution ratio and determine the dilution factor

according to the procedure in Section 5.3.

4.2.3 Conduct a system check according to the procedure in

Section 5.4.

4.2.4

Install the sample probe so that the probe is centrally

located in the stack, pipe, or duct, and is sealed tightly at the

stack port connection.

4.2.5 Inject zero gas at the calibration valve assembly.

Measure the system response time as the time required for 

the

system to reach the effluent concentration after the calibration

valve has been returned to the effluent sampling position.

4.2.6 Conduct a system check before and a system

drift 

check

after each sampling rim according to the procedures in Sections

5.2 and 5.4. If the

drift 

check following a run indicates

unacceptable performance, the run is not valid.

The tester may

elect to

perform system drift 

checks during the run not to exceed

one

drift 

check per hour.

4.2.7 Verify that the sample lines, filter,

and pump

temperatures are 120 ±5°C.

333

4.2.8 Begin sampling at the start of the test period and

continue to sample during the entire run. Record the starting

and ending times and any required process information as

appropriate.

If multiple captured emission locations are sampled

using a single FIA, sample at each location for the same

amount

of time (e.g., 2 minutes) and continue to switch from one

location to another for the entire test run. Be sure that total

sampling time at each location is the same at the end of the test

run. Collect at least 4 separate measurements from each sample

point during each hour of testing.

Disregard the measurements at

each sampling location until two times the response time of

the

measurement system has elapsed.

Continue sampling for at least 1

minute and record the concentration measurements.

4.3 Background Concentration.

4.3.1 Locate all NDO’s of the TTE. A sampling point shall be

centrally located outside of the TTE at 4 equivalent diameters

from each

NDO, 

if possible.

If there are more than 6 NDO’s,

choose 6 sampling points evenly spaced among the NDO’s.

4.3.2

Assemble the sample train as shown in Figure 2. 

Calibrate

the FIA and conduct a system check according to the procedures in

Sections 5.1 and

5.4.

4.3.3 Position the probe at the sampling location.

4.3.4 Determine the response time, conduct the system check and

sample according to the procedures described in Sections 4.2.4 to

4.2.8.

4.4 Alternative Procedure. The direct interface sampling and

analysis

procedure described in Section 7.2 of Method 18 may be

used to determine the gas VO~jconcentration. The system must be

designed to collect and analyze at least one sample every 10

minutes.

5.  CALIBRATION AND QUALITY ASSURANCE

5.1 FIA Calibration and Linearity Check. Make necessary

adjustments to the air and fuel supplies for the FIA and ignite

the burner.

Allow the FIA to warm up for the period recommended

by the manufacturer.

Inject a calibration gas into the

measurement system after the dilution system and adjust the back—

pressure regulator to the value required to achieve the

flow

rates specified by the manufacturer. Inject the zero— and 

the

high-range calibration gases and adjust the analyzer calibration

to provide the proper responses. Inject the low— and mid—range

gases and record the responses of the measurement system. The

calibration and linearity of the system are acceptable if the

responses for all four gases are within 5 percent of the

334

respective gas values. If the performance of the system is not

acceptable, repair or adjust the system and repeat the linearity

check. Conduct a calibration and linearity check after

assembling the analysis system and after a major change is made

to the system.

5.2 Systems Drift Checks. Select the calibration 

gas that most

closely approximates the concentration of the diluted captured

emissions for conducting the drift checks. Introduce the 

zero

and calibration gas at the calibration valve

assembly 

and verify

that

the

appropriate gas flow rate and pressure are present at

the FIA. Record the measurement system responses to the zero and

calibration gases.

The performance of the system is acceptable

if the difference between the drift check measurement and the

value obtained in Section 5.1 is less than 3 percent of the span

value. Conduct the system

drift 

check at the end of each run.

5.3 Determination of Dilution Factor. Inject the dilution check

gas into the measurement system 

before the dilution system and

record the response. Calculate the dilution factor using

Equation 3.

5.4

System Check. Inject the high range calibration gas at the

inlet to the sampling probe while the dilution air is turned off.

Record the response.

The performance of the system is acceptable

if the measurement system response is within 5 percent of the

value obtained in Section 5.1 for the high range calibration gas.

Conduct a system check before and after each test run.

5.5 Analysis Audit. Immediately before each test analyze an

audit cylinder as described in Section 5.2. The analysis audit

must agree with the audit cylinder concentration within 10

percent.

6.

NOMENCLATURE

Ai

area of NDO i, ft~-..L

total area of all NDO’s in the enclosure, ft2-~

actual concentration of the dilution check gas,

ppm propane-a

CBI

corrected average

VOQ!,J 

concentration of background

emissions at point i, ppm propane-~j

average background concentration,

ppm propane~-j

CDH

average measured concentration for the drift check

calibration gas, ppm propane--j.

335

CDO

average system drift check concentration for zero

concentration

gas, ppm propane~-j

C11

actual concentration of the drift check

calibration gas, ppm propane-~j.

Cj~

uncorrected average background VO~Jconcentration

measured at point i, ppm propane-a

Cj

uncorrected average V0q1 concentration measured at

point j, ppm propane-~-j

CM

measured concentration of the dilution check gas,

ppm propane-u

DF

dilution factor-~-j

G

total VOC!~

content of captured emissions, kg-ri.

K1

1.830 x 10~kg/(m3-ppm)—.~

n

number of measurement points-ri

QGj

average effluent volumetric flow rate corrected to

s~andardconditions at captured emissions point j,

m /min-.i.

TC

total duration of capture efficiency sampling run,

mm.

CALCULATIONS

7.1 Total VO~ Captured Emissions.

n

G

E CGjQGjTCK1       

Eq. 1

j=l

7.2 VO~1Concentration of the Captured Emissions at Point j.

DF (Cj~CDO)         

Eq. 2

CDH- CDO

7.3 Dilution Factor.

DFSA.       

Eq. 3

CM

7.4 Background

VOG1~J 

Concentration at Point i.

336

CBi (Cj CDO)   

Cp~

Eq. 4

CDH- CDO

7

•

5 Average Background Concentration.

n

E CBJAj

CB= i=1                 

Eq. 5

nAN

NOTE: If 

the

concentration at each point is within 20 percent of

the average concentration of all points, the terms “A1”and “AN”

may be deleted from Equation 4.

Procedure F.2 

Fugitive VOG?j Emissions from Building Enclosures

1. INTRODUCTION

1.1 Applicability. This procedure is applicable for determining

the fugitive volatile organic compoundomaterials (VO6~j) emissions

from a building enclosure (BE). It is intended to be used as a

segment in the development of liquid/gas or gas/gas protocols for

determining VO~jcapture efficiency (CE) for surface coating and

printing operations.

1.2 Principle. The total amount of fugitive VO~jemissions (FB)

from the BE is calculated as the sum of the products of the VO~J

content (CFj)Of each fugitive emissions point, its flow rate

(QFj) ,and time (T).

1.3 Measurement Uncertainty. The measurement uncertainties are

estimated for each fugitive emissions point as follows: QFj=

±5.0percent and CFj= ±5.0percent. Based on these numbers, the

probable uncertainty for

FB is estimated at about ±11.2percent.

1.4 Sampling Requirements. A capture efficiency test shall

consist of at least three sampling runs. The sampling time for

each run should be at least 8 hours, unless otherwise approved.

1.5 Notes. Because this procedure is often applied in highly

explosive areas, caution and care should be exercised in choosing

appropriate equipment and installing and using the equipment.

Mention of trade names or company products does not constitute

endorsement. All gas concentrations (percent, ppm) are by

volume, unless otherwise noted.

2.  APPARATUS AND REAGENTS

2.1 Gas VOG~Concentration. A schematic of the measurement

system is shown in Figure 1. The main components are described

below:

337

2.1.1 Sample Probe. Stainless steel, or equivalent. The probe

shall be heated to prevent VO~jcondensation.

2.1.2 Calibration Valve Assembly. Three-way valve assembly at

the outlet of sample probe to direct the zero and calibration

gases to the analyzer. Other methods, such as quick—connect

lines, to route calibration gases to the outlet of the sample

probe are acceptable.

2.1.3 Sample Line. Stainless steel or Teflon tubing to

transport the sample gas to the analyzer.

The sample line must

be heated to prevent condensation.

2.1.4 Sample

Pump. A leak-free pump, to pull the sample gas

through 

the system at a flow rate sufficient to minimize the

response time of the measurement system. The components of the

pump that contact the gas stream shall be constructed of

stainless steel or Teflon. The sample pump must be heated to

prevent condensation.

2.1.5 Sample Flow Rate Control. A sample flow rate control

valve and rotameter, or equivalent, to maintain a constant

sampling rate within 10 percent. The flow rate control valve and

rotameter must be heated to prevent condensation.

A control

valve may also be located on the sample pump bypass loop to

assist in controlling the sample pressure and flow rate.

2.1.6 Sample Gas Manifold. Capable of diverting a portion of

the sample gas stream to the flame ionization analyzer (FIA), and

the remainder to the bypass discharge vent. The manifold

components shall

be constructed of stainless steel or Teflon. If

emissions are to be measured at multiple locations, the

measurement system shall be designed to use separate sampling

probes, lines, and pumps for each measurement location and a

common sample gas manifold and FIA. The sample gas manifold must

be heated to prevent condensation.

2.1.7

Organic Concentration Analyzer.

An FIA with a span value

of 1.5 times the expected concentration as propane; however,

other span values may be used if it can be demonstrated that they

would provide more accurate measurements. The system shall be

capable of meeting or exceeding the following specifications:

2.1.7.1 Zero Drift. Less than ±3.0percent of the span value.

2.1.7.2

Calibration Drift.

Less than ±3.0 percent of the span

value.

2.1.7.3 Calibration Error. Less than ±5.0percent of the

calibration gas value.

2.1.7.4 Response Time. Less than 30 seconds.

338

2.1.8 Integrator/Data Acquisition System. An analog or digital

device or computerized data acquisition system used to integrate

the FIA response or compute the average response and record

measurement data. The minimum data sampling frequency for

computing average or integrated values is one measurement value

every 5 seconds. The device shall be capable of recording

average values at least once per minute.

2.1.9

Calibration and Other Gases. Gases used for calibration,

fuel, and combustion air (if required) are contained in

compressed gas cylinders.

All calibration gases shall be

traceable to NIST standards and shall be certified by the

manufacturer to ±1 percent of the tag value. Additionally, the

manufacturer of the cylinder should provide a recommended shelf

life for each calibration gas cylinder over which the

concentration does not change more than ±2 percent from the

certified value. For calibration gas values not generally

available, alternative methods for preparing calibration gas

mixtures, such as dilution systems, may be used with prior

approval.

2.1.9.1

Fuel.

A 40 percent 112/60 percent He or 40 percent 112/60

percent N2 gas mixture is recommended to avoid an oxygen

synergism effect that reportedly occurs when oxygen concentration

varies significantly from a mean value.

2.1.9.2

Carrier Gas. High purity air with less than 1 ppm of

organic material (propane or carbon equivalent) or less than 0.1

percent of the span value, whichever is greater.

2.1.9.3 FIA Linearity Calibration Gases. Low-, mid—, and

high—range gas mixture standards with nominal propane

concentrations of 20-30, 45—55, and 70-80 percent of the span

value in air, respectively.

Other calibration values and other

span values may be used if it can be shown that more accurate

measurements would be achieved.

2.1.10 Particulate Filter. An in-stack or an out-of—stack glass

fiber filter is recommended if exhaust gas particulate loading is

significant.

An out-of-stack filter must be heated to prevent

any condensation unless it can be demonstrated that no

condensation occurs.

2.2 Fugitive Emissions Volumetric Flow Rate.

2.2.1 Flow Direction Indicators. Any

means of indicating inward

or outward flow, such as light plastic film or paper streamers,

smoke

tubes, filaments, and sensory 

perception.

2.2.2

Method 2 or 2A Apparatus.

For determining volumetric flow

rate.

Anemometers or similar devices calibrated according to the

339

manufacturer’s instructions may be used when low velocities are

present. Vane anemometers (Young-maximum response propeller),

specialized pitots with electronic manometers (e.g., Shortridge

Instruments Inc., Airdata Multimeter 860) are commercially

available with measurement thresholds of 15 and 8 mpm (50 and

25 fpm), respectively.

2.2.3 Method 3 Apparatus and Reagents. For determining

molecular weight of the gas stream. An estimate of the molecular

weight of the gas stream may be used if it can be justified.

2.2.4 Method 4 Apparatus and Reagents. For determining moisture

content, if necessary.

3.  DETERMINATION OF VOLUMETRIC FLOW RATE OF FUGITIVE EMISSIONS

3.1 Preliminary Determinations. The purpose of this exercise is

to determine

which exhaust points should be measured for volumetric flow rates

and VOG~concentrations.

3.1.1 Forced Draft Openings. Identify all forced draft

openings. Determine the volumetric flow rate according to Method

2.

3.1.2 NDO’s Exhaust Points. The NDO’s in the roof of a facility

the building or room in which the emission unit is located are

considered to be exhaust points. Determine volumetric flow rate

from these NDO’s. Divide the cross—sectional area according to

Method 1 using 12 equal areas.

Use the appropriate velocity

measurement devices, e.g., propeller anemometers.

3.1.3 Other NDO’s.

3.1.3.1

This step is optional.

Determine the exhaust flow rate,

including that of the control device, from the enclosure and 

the

intake air flow rate. If the exhaust flow rate divided by the

intake air flow rate is greater than 1.1, then all other NDO’s

are not considered to be significant exhaust points.

3.1.3.2 If the option above is not taken, identify all other

NDO’s and other potential points through which fugitive emissions

may escape the enclosure. Then use the following criteria to

determine whether flow rates and VO~Mconcentrations need to be

measured:

3.1.3.2.1 Using the appropriate flow direction indicator,

determine the flow direction. An NDO with zero or inward flow is

not an exhaust point.

3.1.3.2.2 Measure the outward volumetric flow rate from the

remainder of the NDO’s. If the collective flow rate is 2

340

percent, or less, of the flow rate from Sections 3.1.1 and 3.1.2,

then these NDO’s, except those within two equivalent diameters

(based

on NDO opening) from 

VO~joouroc~emittinciDoint, may be

considered to be non—exhaust points.

3.1.3.2.3 If the percentage calculated in Section 3.1.3.2.2 is

greater 

than 2 percent, those NDO’S

(except those within two

equivalent diameters from a VOG!,j 

oourccoemittina point) whose

volumetric flow rate total 2 percent of the flow rate from

Sections 3.1.1 and 3.1.2 may be considered as non—exhaust points.

All remaining

NDO’s shall 

be measured for volumetric flow rate

and

VOQ~fconcentrations during the CE test.

3.1.3.2.4

The tester may choose to measure

VOG)J 

concentrations

at the forced exhaust points and the NDO’s. If the total

VO~j

emissions from the NDO’s are less than 2 percent of 

the emissions

from the forced draft and roof NDO’s, then these NDO’s may be

eliminated from further consideration.

3.2 Determination of Flow Rates.

3.2.1 Measure the volumetric flow rate at all locations

identified as exhaust points in Section 3.1. Divide each exhaust

opening into 9 equal areas for rectangular openings and 8 for

circular openings.

3.2.2 Measure the velocity at each site at least once every hour

during each sampling run using Method 2 or 2A, if applicable, or

using the low velocity instruments in Section 2.2.2.

4.  DETERMINATION OF VOGIj CONTENT OF FUGITIVE EMISSIONS

4.1 Analysis Duration. Measure the voq~responses 

at each

fugitive emission point during the entire test run or, if

applicable, while the process is operating. If there are

multiple emissions locations, design a sampling system to allow a

single FIA to be used to determine the VO~Mresponses 

at all

sampling locations.

4.2 Gas

VOG~jConcentration.

4.2.1

Assemble the sample train as shown in Figure 1. 

Calibrate

the FIA and conduct a system check according to the procedures in

Sections 5.1 and 5.3, respectively.

4.2.2 Install the sample probe so that the probe is centrally

located in the stack, pipe, or duct, and is sealed tightly at the

stack port connection.

4.2.3 Inject zero gas at the calibration valve assembly. Allow

the measurement system response to reach zero. Measure the

341

system response time as the time required for the system to reach

the effluent concentration after the calibration valve has been

returned to the effluent sampling position.

4.2.4 Conduct a system check before and a system

drift 

check

after each sampling run according to the procedures in Sections

5.2 and 5.3.

If the drift check following a run indicates

unacceptable performance, the run is not valid.

The tester may

elect to perform drift checks during the run not to exceed one

drift 

check per hour.

4.2.5 Verify that the sample lines, filter,

and pump

temperatures are 120 ±5°C.

4.2.6 Begin sampling at the start of the test period and

continue to sample during the entire run. Record the starting

and ending times and any required process information as

appropriate. If multiple emission locations are sampled using a

single FIA, sample at each location for the same amount of time

(e.g., 2 minutes) and continue to switch from one location to

another for the entire test run. Be sure that total sampling

time 

at each location is the same at the end of the test run.

Collect at least 4 separate measurements from each sample point

during each hour of testing. Disregard the response measurements

at each sampling location until two times the response time of

the measurement system has elapsed.

Continue sampling for at

least 1 minute and record the concentration measurements.

4.3 Alternative Procedure The direct interface sampling and

analysis procedure described in Section 7.2 of Method 18 may be

used to determine the gas 

VO~j

concentration. The system must be

designed to collect and analyze at least one sample every 10

minutes.

CALIBRATION AND QUALITY ASSURANCE

5.1 FIA Calibration and Linearity Check. Make necessary

adjustments to the air and fuel supplies for the FIA and ignite

the burner.

Allow the FIA to warm up for the period recommended

by the manufacturer. Inject a calibration gas into the

measurement system and adjust the back—pressure regulator to the

value required to achieve the flow rates specified by the

manufacturer. Inject the zero— and the high—range calibration

gases and adjust the analyzer calibration to provide the proper

responses. Inject the low— and mid—range gases and record 

the

responses of the measurement system.

The calibration and

linearity of the system are acceptable if the responses for all

tour gases are within 5 percent of the respective gas values. If

the performance of the

system is 

not acceptable, repair or adjust

the system and repeat the linearity check. Conduct a calibration

and linearity check after assembling the analysis system and

after a major change is made to the system.

342

5.2 Systems Drift Checks. Select the calibration gas that most

closely approximates the concentration of the captured emissions

for conducting the drift checks. Introduce the zero and

calibration gas at the calibration valve

assembly 

and verify that

the

appropriate gas flow rate and pressure are present at the

FIA. Record the measurement system responses to the zero and

calibration gases.

The performance of the system is acceptable

if the difference between the drift check measurement and the

value obtained in Section 5.1 is less than 3 percent of the span

value.

Conduct a system drift check at the end of each run.

5.3 System Check. Inject the high range calibration gas at the

inlet of the sampling probe and record the response.

The

performance of the system, is acceptable if the measurement system

response is within 5 percent of the value obtained in Section 5.1

for the high range calibration gas. Conduct a system check

before each test run.

5.4 Analysis Audit.

Immediately before each test analyze an

audit cylinder as described in Section 5.2. The analysis audit

must agree with the audit cylinder concentration within 10

percent.

NOMENCLATURE

CDH

average measured concentration for the drift check

calibration gas, ppm propane--j.

CDO

average system drift check concentration for zero

concentration gas, ppm

propane--i.

CFj

corrected average VOGN 

concentration of fugitive

emissions at point 

ppm propane-ri.

C11

actual concentration of the drift 

check

calibration gas, ppm propane-ri.

uncorrected average vo~rjconcentration measured at

point j,

ppm propane-ri.

FB

total VOG~Jcontent of fugitive emissions from the

building, kg-ri

K1

1.830 x 10°kg/(m3-ppm)--.~

number 

of measurement points-rj

QFj

average effluent volumetric flow rate corrected to

s~andardconditions at fugitive emissions point 

m /min-.~

343

TF

total duration of capture efficiency sampling run,

mm.

7.

CALCULATIONS

7.1 Total VOGZf Fugitive Emissions From the Building.

&

CFjQFjTF K1        

Eq. 1

j=1

7.2

VOGIf 

Concentration of the Fugitive Emissions at Point j.

CFj

(Cj~CDO)

Eq. 2

CDH

CDO

Procedure F.1 

—

Fugitive VO~j 

Emissions from Temporary Enclosures

1.  INTRODUCTION

1.1 Applicability. This procedure is applicable for determining

the fugitive volatile organic compoundomaterials (VOG~) 

emissions

from a temporary total enclosure (TTE). It is intended to be

used as a segment in the development of liquid/gas or gas/gas

protocols for determining

VO~j capture efficiency (CE) for

surface coating and printing operations.

1.2 Principle. The 

amount

of fugitive VOG~jemissions (F) from

the TTE is calculated as the sum of the products of the VOGZ*j

content (CF~),theflow rate (QFj),and the sampling time (Tp~ from

each fugitive emissions point.

1.3 Estimated Measurement

Uncertainty. The measurement

uncertainties are estimated for each fugitive emission point

as follows: QFj= ±5.5percent and CFj= ±5.0percent. Based 

these numbers, the probable uncertainty for F is estimated at

about ±7.4percent.

1.4 Sampling Requirements. A capture efficiency test shall

consist of at least three sampling runs. The sampling time for

each run should be at least B hours, unless otherwise approved.

1.5 Notes. Because this procedure is often applied in highly

explosive areas, caution and care should be exercised in choosing

appropriate equipment and installing and using the equipment.

Mention of trade names or company products does not constitute

endorsement. All gas concentrations (percent, ppm) are by

volume, unless otherwise noted.

2.

APPARATUS AND

REAGENTS

344

2.1 Gas VOGZj Concentration. A schematic of the 

measurement

system is shown in Figure 1. The main components are described

below:

2.1.1 Sample Probe. Stainless steel, or equivalent. The probe

shall be heated to prevent VO~ijcondensation.

2.1.2

Calibration Valve Assembly.

Three—way valve assembly at

the outlet of sample probe to direct the zero and calibration

gases to 

the

analyzer. Other methods, such as quick—connect

lines, to route calibration gases to the outlet of the sample

probe 

are acceptable.

2.1.3 Sample Line. Stainless

steel or Teflon tubing to

transport the sample gas to the analyzer. The sample line must

be heated to prevent condensation.

2.1.4 Sample Pump. A leak-free pump, to pull the sample gas

through 

the system at a flow rate sufficient to minimize the

response time of the measurement system. The components of the

pump that contact the gas stream shall be constructed of

stainless steel or Teflon. The sample pump must be heated to

prevent condensation.

2.1.5 Sample Flow Rate Control. A sample flow rate control

valve and rotameter, or equivalent, to maintain a constant

sampling rate within 10 percent. The flow control valve and

rotameter must be heated to prevent condensation. A control

valve may also be located on the sample pump bypass loop to

assist in controlling the sample pressure and flow rate.

2.1.6 Sample Gas Manifold. Capable of diverting a portion of

the sample gas stream to the flame ionization analyzer (FIA), and

the remainder to the bypass discharge vent. The manifold

components shall be constructed of stainless steel or Teflon. If

emissions are to be measured at multiple locations, the

measurement system shall

be designed to use separate sampling

probes, lines, and pumps for each measurement location and a

common sample gas manifold and FIA. The sample gas manifold and

connecting lines to the FIA must be heated to prevent

condensation.

2.1.7 organic Concentration Analyzer.

An FIA with a

span 

value

of 1.5 times the expected concentration as propane; however,

other span values may be used if it can be demonstrated that they

would provide more accurate measurements. The system shall be

capable of meeting or exceeding the following specifications:

2.1.7.1 Zero Drift. Less than ±3.0percent of the span value.

2.1.7.2 Calibration Drift. Less than ±3.0percent of the span

value.

345

2.1.7.3 Calibration Error. Less than ±5.0percent of the

calibration gas value.

2.1.7.4 Response Time. Less than 30 seconds.

2.1.8

Integrator/Data Acquisition System. An analog or digital

device or computerized data acquisition system used to integrate

the FIA response or compute the average response and record

measurement data.

The minimum data sampling frequency for

computing average or integrated values is one measurement value

every 5 seconds. The device shall be capable of recording

average values at least once per minute.

2.1.9

Calibration and Other Gases. Gases used for calibration,

fuel, and combustion air (if required) are contained in

compressed gas cylinders.

All calibration gases shall be

traceable to NIST standards and shall be certified by the

manufacturer to ±1percent of the tag value. Additionally, the

manufacturer of the cylinder should provide a recommended shelf

life for each calibration gas cylinder over which the

concentration does not change more than ±2percent from 

the

certified value. For calibration gas values not generally

available, alternative methods for preparing calibration gas

mixtures, such as dilution systems, may be used with prior

approval.

2.1.9.1 Fuel. A 40 percent 112/60 percent He or 40 percent 112/60

percent N2 gas mixture is recommended to avoid an oxygen

synergism effect that reportedly occurs when oxygen concentration

varies significantly

from a mean value.

2.1.9.2 Carrier Gas. High purity air with less than 1 ppm of

organic material (as propane or carbon equivalent) or less than

0.1 percent of the span value, whichever is greater.

2.1.9.3 FIA Linearity Calibration Gases. Low-, mid—, and

high—range gas mixture standards with nominal propane

concentrations of 20-30, 45-55, and 70-80 percent of the span

value in air, respectively.

Other calibration values and other

span values may be used if it can be shown that more accurate

measurements would be achieved.

2.1.10 Particulate Filter. An in-stack or an out—of—stack glass

fiber filter is recommended if exhaust gas particulate

loading is

significant. An out-of-stack filter must be heated to prevent

any condensation unless it can be demonstrated that no

condensation occurs.

2.2 Fugitive Emissions Volumetric Flow Rate.

346

2.2.1 Method 2 or 2A Apparatus.

For determining volumetric flow

rate.

2.2.2 Method 

Apparatus and Reagents. For determining

molecular weight of the gas stream. An estimate of the molecular

weight of the gas stream may be used if it can be justified.

2.2.3

Method 4 Apparatus and Reagents.

For determining moisture

content, if necessary.

2.3 Temporary Total Enclosure.

The criteria for designing a

TTE

are discussed in Procedure T.

3.  DETERMINATION OF VOLUMETRIC FLOW RATE OF FUGITIVE EMISSIONS

3.1 Locate all points where emissions are exhausted from the

TTE. 

Using Method 1,

determine the sampling points. Be sure to

check each site for cyclonic or swirling flow.

3.2 Measure the velocity at each sampling site at least once

every hour during each sampling run using Method 2 or 2A.

4.  DETERMINATION OF VO~IjCONTENT OF FUGITIVE EMISSIONS

4.1 Analysis Duration. Measure 

the

VOG!,j 

responses at each

fugitive emission point during the entire test run or, if

applicable, while the process is operating. If there are

multiple emission locations, design a sampling system to allow a

single FIA to be used to determine the VOG~responses 

at all

sampling locations.

4.2 Gas

VOG~JConcentration.

4.2.1 Assemble the sample train as shown in Figure 1. Calibrate

the FIA and conduct a system check according to the procedures in

Sections 5.1 and 5.3, respectively.

4.2.2 Install the sample probe so that the probe is centrally

located in the stack, pipe, or duct, and is sealed tightly at 

the

stack port connection.

4.2.3

Inject zero gas at the calibration valve assembly.

Allow

the measurement system response to reach zero.

Measure the

system response time as the time required for the system to reach

the effluent concentration after the calibration valve has been

returned to the effluent sampling position.

4.2.4 Conduct a system check before and a system

drift 

check

after each sampling run according to the procedures in Sections

5.2 and 5.3. If the drift check following a run indicates

unacceptable performance, the run is not valid. The tester may

347

elect to perform system drift checks during the 

run not to exceed

one drift check per hour.

4.2.5 Verify that the sample lines, filter, and pump

temperatures are 120 ±5°C.

4.2.6 Begin sampling at the start of the test period and

continue to sample during the entire run. Record the starting

and ending times and any required process information as

appropriate. If multiple emission locations are sampled using a

single FIA, sample at each location for the same amount of time

(e.g., 2 minutes) and continue to switch from one location to

another for the entire test run. Be sure that total sampling

time at each location is the same at the end of the test run.

Collect at least 4 separate measurements from each sample point

during each hour of testing. Disregard the response measurements

at each sampling location until two times the response time of

the measurement system has elapsed. Continue sampling for at

least 1 minute and record the concentration measurements.

4. 3 Background Concentration.

4.3.1 Determination of VO~ Background Concentration.

4.3.1.1 Locate all NDO’s of the TTE. A sampling point shall be

centrally located outside of the TTE at 4 equivalent diameters

from each NDO, if possible. If there are more than 6 NDO’s,

choose 6 sampling points evenly spaced among the NDO’s.

4.3.1.2 Assemble the sample train as shown in Figure 2.

Calibrate the FIA and conduct a system check according to the

procedures in Sections 5.1 and 5.3.

4.3.1.3 Position the probe at the sampling location.

4.3.1.4 Determine the response time, conduct the system check

and sample according to the procedures described in Sections

4.2.3 to 4.2.6.

4.4 Alternative Procedure.

The direct interface sampling and

analysis procedure described in Section 7.2 of Method 18 may be

used to determine the gas 

voq~

concentration. The system must be

designed to collect and analyze at least one sample every 10

minutes.

5.  CALIBRATION 

AND

QUALITY ASSURANCE

5.1 FIA Calibration and Linearity Check. Make necessary

adjustments to the air and fuel supplies for the FIA and ignite

the burner. Allow the FIA to warm up for the period recommended

by the manufacturer.

Inject a calibration gas into the

measurement system and adjust the back-pressure regulator to the

348

value required to achieve the flow rates specified by the

manufacturer.

Inject the zero- and the high—range calibration

gases and adjust the analyzer calibration to provide the proper

responses.

Inject the low— and mid—range gases and record the

responses of 

the

measurement system. The calibration and

linearity of the system are acceptable if the responses for all

four gases are within 5 percent of the respective gas values. If

the performance of the system is not acceptable, repair or adjust

the

system 

and repeat the linearity check. Conduct a calibration

and linearity check after assembling the analysis system and

after a major change is made to the system.

5.2

Systems Drift Checks. Select the calibration gas

concentration that most closely approximates that of the fugitive

gas emissions to conduct the drift checks.

Introduce the zero

and calibration gas at the calibration valve assembly and verify

that the appropriate gas flow rate and pressure are present at

the FIA. Record the measurement system responses to the zero and

calibration gases. The performance of the system is acceptable

if the difference between the drift check measurement and the

value obtained in Section 5.1 is less than 3 percent of the span

value. Conduct a system drift check at the end of each run.

5.3 System Check. Inject the high range calibration gas at the

inlet of the sampling probe and record the response. The

performance of the system is acceptable if the measurement system

response is within 5 percent of the value obtained in Section 5.1

for the high range calibration gas. Conduct a system check

before each test run.

5.4 Analysis Audit. Immediately before each test analyze an

audit cylinder as described in Section 5.2. 

The analysis audit

must agree with the audit cylinder concentration within 10

percent.

6.

NOMENCLATURE

area of NDO i, ft~-.i.

AN

total area

of all NDO’s in the enclosure, ft~-~i.

CBj

corrected average VOqf concentration of background

emissions at point i, ppm propane.i.

average background concentration, ppm propane,-i.

CDH

average measured concentration for the drift check

calibration

gas, ppm propane-ri.

349

CDO

average system drift check concentration for zero

concentration gas, ppm

propane-rj

CFj

corrected average VO~ 

concentration of fugitive

emissions at point j, ppm propane--i.

C11

actual concentration of the drift check

calibration gas, ppm propane-ri.

uncorrected average background

VOG~Jconcentration

measured at point i, ppm propane-ri.

Cj

uncorrected average VO~Jconcentration measured at

point j, ppm propane--j

G

total

VOG?’j content of captured emissions, kgr~

K1

1.830 x

10~kg/(m3-ppm~~

n

number of measurement points-~j.

QFj

average effluent volumetric flow rate corrected to

standard

conditions at fugitive emissions point j, m3/mini.i.

total duration of fugitive emissions sampling run,

mm.

7. CALCULATIONS

7.1 Total VOG~1Fugitive Emissions.

n

E

(CFj- CB) QFjTF K1

Eq. 1

7.2

VO~!jConcentration 

of the Fugitive Emissions at Point

j.

CFj= (Cj- CDO)            

Eq. 2

CDH- CDO

7.3 Background VO~jConcentration 

at Point i.

CBi= (Ci- CDO)

Eq. 3

CDH— CDO

7.4 Average Background Concentration.

n

E CBIAi

CB= 1=1                 

Eq. 5

350

NOTE: If the concentration at each point is within 20 percent of

the average concentration of all points, the terms “A~”and “AN”

may be deleted from Equation 4.

Procedure L

VOGN 

Input

1. INTRODUCTION

1.1 Applicability. This procedure is applicable for determining

the input of volatile organic oompourld3materials

(VOQIj). 

It is

intended to be used as a segment in the development of liquid/gas

protocols for determining VOGIj capture efficiency (CE) for

surface coating and printing operations.

1.2 Principle. The 

amount

of VOG?’J 

introduced to the process

(L) is the sum of the products of the weight (W) of each VOGZ,~

containing liquid (ink, paint, solvent, etc.) used and its

VO?I~J

content (V). A sample of each

VOGJ 

containing liquid is analyzed

with a flame ionization analyzer (FIA) to determine V.

1.3 Estimated Measurement Uncertainty. The measurement

uncertainties are estimated for each VO~

containing liquid as

follows: W 

2.0 percent and V

±12.0percent. Based on these

numbers, 

the probable uncertainty for L is estimated at about

±12.2percent for each 

voq~

containing liquid.

1.4 Sampling Requirements. A capture efficiency test shall

consist of at least three sampling runs. The sampling time for

each run should be at least 8 hours, unless otherwise approved.

1.5 Notes. Because this procedure is often applied in highly

explosive areas, caution and care should be exercised in choosing

appropriate equipment and installing and using the equipment.

Mention of trade names or company products does not constitute

endorsement. All gas concentrations (percent, ppm) are by

volume, unless otherwise noted.

APPARATUS AND REAGENTS

2.1 Liquid Weight.

2.1.1 Balances/Digital Scales.

To weigh drums of

VOGZf

containing liquids to within 0.2 lb.

•

2 Volume Measurement Apparatus (Alternative).

Volume

meters, flow

meters, density measurement equipment, etc., as

needed to achieve same accuracy as direct weight measurements.

351

2.2 VOG)J Content (Flame Ionization Analyzer Technique). The

liquid sample analysis system is shown in

Figures 1 and 2. The

following equipment is required:

2.2.1 Sample Collection Can. An appropriately sized metal can

to be used to collect

VO~ containing materials. 

The can must be

constructed in such a way that it can be grounded to the coating

container.

2.2.2

Needle Valves.

To control gas flow.

2.2.3 Regulators.

For carrier gas and calibration gas

cylinders.

2.2.4

Tubing. 

Teflon or stainless steel tubing with diameters

and lengths determined by connection requirements of equipment.

The tubing between the sample oven outlet and the 

PIA shall be

heated to maintain a temperature of 120 ±5°C.

2.2.5 Atmospheric Vent. A tee and 0— to 0.5—liter/mm rotameter

placed in the sampling line between the carrier gas cylinder and

the VOGZ~sample vessel to release the excess carrier gas. A

toggle valve placed between the tee and

the rotaineter facilitates

leak tests of the analysis system.

2.2.6

Thermometer.

Capable of measuring the temperature of the

hot water bath

to within 

lee.

2.2.7 Sample Oven. Heated enclosure, containing calibration gas

coil heaters, critical orifice, aspirator, and other liquid

sample analysis components, capable of maintaining a temperature

of 120 ±5°C.

2.2.8 Gas Coil Heaters.

Sufficient lengths of stainless steel

or Teflon tubing to allow zero and calibration gases to be heated

to the sample oven temperature before entering the critical

orifice or aspirator.

2.2.9 Water Bath.

Capable of heating and maintaining a sample

vessel temperature of 100 ±5°C.

2.2.10 Analytical Balance.

To measure ±0.001 g.

2.2.11

Disposable Syringes.

2—cc or 5—cc.

2.2.12 Sample Vessel. Glass, 40—mi septum vial. A separate

vessel is needed for each sample.

2.2.13 Rubber Stopper. Two-hole stopper to accommodate 3.2—mm

(1/8—in.) Teflon tubing, appropriately sized to fit the opening

of the sample vessel. The rubber stopper should be wrapped in

Teflon tape to provide a tighter seal and to prevent any reaction

352

of the sample with the rubber stopper.

Alternatively,

any

leak—free closure fabricated of non—reactive materials and

accommodating the necessary tubing fittings may be used.

2.2.14 Critical Orifices.

Calibrated critical orifices capable

of providing constant flow rates from 50 to 250 ml/min at

known

pressure drops.

Sapphire orifice assemblies (available from

O’Keefe Controls Company) and glass capillary tubing have been

found to be adequate for this application.

2.2.15

Vacuum Gauge.

0- to 760—mm (0— to 30—in.) Hg U—Tube

manometer or vacuum gauge.

2.2.16

Pressure Gauge. Bourdon gauge capable of measuring the

maximum air pressure at the aspirator inlet (e.g., 100 psig).

2.2.17 Aspirator.

A device capable of generating sufficient

vacuum at the sample vessel to create critical flow through the

calibrated orifice when sufficient air pressure is present at the

aspirator inlet. The aspirator must also provide sufficient

sample pressure to operate the FIA. The sample is also mixed

with the dilution gas within the aspirator.

2.2.18 Soap Bubble Meter. Of an appropriate size to calibrate

the critical orifices in the system.

2.2.19

Organic Concentration Analyzer.

An FIA with a span value

of 1.5 times the expected concentration as propane; however other

span values may be used if it can be demonstrated that they would

provide more accurate measurements. The system shall be capable

of meeting or exceeding the following specifications:

2.2.19.1 Zero Drift. Less than ±3.0percent of 

the span

value.

2.2.19.2 Calibration Drift. Less than ±3.0percent of span

value.

2.2.19.3 Calibration Error. Less than ±5.0percent of 

the

calibration gas value.

2.2.20 Integrator/Data Acquisition System.

An analog or digital

device or computerized data acquisition system used to integrate

the FIA response or compute the average response and record

measurement data. The minimum

data sampling frequency for

computing average or integrated values is one measurement value

every 5 seconds. The device shall be capable of recording

average values at least once per minute.

2.2

•

21 Chart Recorder (Optional). A chart recorder or similar

device is recommended to provide a continuous analog display of

the measurement results during the liquid sample analysis.

353

2.2.22 Calibration and Other Gases. For calibration, fuel, and

combustion air (if required) contained in compressed gas

cylinders. All calibration gases shall be traceable to NIST

standards and shall be certified by the manufacturer to ±1

percent of the tag value. Additionally, the manufacturer of the

cylinder should provide a recommended shelf life for each

calibration gas cylinder over which the concentration does not

change more than ±2 percent from the certified value.

For

calibration gas values not generally available, alternative

methods for preparing calibration gas mixtures, such 

as dilution

systems, may be used with prior approval.

2.2.22.1

Fuel.

A 40 percent 112/60 percent He or 40 percent 112/60

percent N2 gas

mixture is recommended to avoid an oxygen

synergism effect that reportedly occurs when oxygen concentration

varies significantly

from a mean value.

2.2.222

Carrier Gas. High purity air with less than 3. ppm of

organic material (as propane) or less than 0.1 percent of the

span value, whichever is greater.

2.2.22.3 FIA Linearity Calibration Gases. Low-, mid-, and

high—range gas mixture standards with nominal propane

concentrations of 20-30, 45-55, and 70-80 percent of the span

value in air, respectively. Other calibration values and other

span values may be used if it can be shown that more accurate

measurements would be achieved.

2.2.22.4 System Calibration Gas. Gas mixture standard

containing propane in air, approximating the undiluted VO~j

concentration expected for the liquid samples.

3.  DETERMINATION OF LIQUID INPUT WEIGHT

3.1 weight Difference. Determine the amount of material

introduced to the process as the weight difference of the feed

material before and after each sampling run. In determining the

total

VOGI’I containing liquid usage, account for: (a) the initial

(beginning) VO~Jcontaining liquid mixture; (b) any solvent added

during the test run; (c) any coating added during the test run;

and (d) any residual

VO~)Jcontaining liquid mixture remaining at

the end of the sample run.

3.1.1 Identify all points where VO~jcontaining liquids are

introduced to the process. To obtain an accurate measurement of

VOG)J containing liquids, start with an empty fountain (if

applicable).

After completing the run, drain the liquid in the

fountain back into the liquid drum (if possible), and weigh the

drum again. Weigh the VO~jcontaining liquids to ±0.5percent of

the total weight (full) or ±0.1percent of the total weight of

VO~?jcontaining liquid used during the sample run, whichever is

354

less. If the residual liquid cannot be returned to the drum,

drain the fountain into a preweighed empty drum to determine the

final weight of the liquid.

3.1.2

If it is not possible to measure a single representative

mixture, 

then weigh the various components separately (e.g., if

solvent is added during the

sampling run, weigh the solvent

before it is added to the mixture).

If a fresh drum of

VO~f

containing liquid is needed during the run, then weigh both the

empty drum and fresh drum.

•

2 Volume Measurement (Alternative).

If direct weight

measurements are not feasible, the tester may use volume meters

and flow rate meters (and density measurements) to determine the

weight of liquids used if it can be demonstrated that the

technique produces results equivalent to the direct weight

measurements.

If a single representative mixture cannot be

measured, measure the components separately.

4.  DETERMINATION OF VO~JCONTENT IN INPUT LIQUIDS

4.1 Collection of Liquid Samples.

4.1.1 Collect a 100-ml or larger sample of the

VO6~f

containing

liquid mixture

at each application location at the beginning and

end of each test run. A separate sample should be taken of each

VOGIj 

containing liquid

added to the application mixture during

the test run. If a fresh drum is needed during the sampling run

then obtain a sample from the fresh drum.

4.1.2 When collecting the sample, ground the sample container to

the coating drum. Fill the sample container as close to the rim

as possible to minimize the amount of headspace.

4.1.3 After the sample is collected, seal the container so the

sample cannot leak out or evaporate.

4.1.4

Label the container to identify clearly the contents.

4.2 Liquid Sample

VOG!j 

Content.

4.2.1

Assemble the liquid VO~)Jcontent analysis system as shown

in Figure 1.

4.2.2 Permanently identify all of the critical orifices that may

be used. Calibrate each critical orifice under the expected

operating conditions (i.e., sample vacuum and temperature)

against a volume meter as described in Section 5.3.

4.2.3 Label and tare the sample vessels (including the stoppers

and caps) and the syringes.

355

4.2.4 Install an empty sample vessel and perform a leak test of

the system. Close the carrier gas valve and atmospheric vent and

evacuate the sample vessel to 250 mm (10 in.) Hg absolute or less

using the aspirator. Close the toggle valve at the inlet to the

aspirator 

and

observe the vacuum for at least one minute. If

there is 

any

change in the sample pressure, release 

the vacuum,

adjust or repair the apparatus as necessary and repeat the leak

test.

4.2.5 Perform the analyzer calibration and linearity checks

according to the procedure in Section 5.1. Record the responses

to each of the calibration gases and the back—pressure setting of

the FIA.

4.2.6 Establish the appropriate dilution ratio by adjusting

the

aspirator air supply or substituting critical orifices.

Operate

the aspirator at a vacuum of at least 25 mm (1 in.) Hg greater

than the vacuum necessary

to achieve critical flow. Select the

dilution ratio so that

the maximum response of the FIA to the

sample does not exceed the high-range calibration gas.

4.2.7 Perform system calibration checks at two levels by

introducing compressed

gases at the inlet to the sample vessel

while the aspirator and dilution devices are operating. Perform

these checks using the carrier gas (zero concentration) and the

system calibration gas. If the response to the carrier gas

exceeds ±0.5 percent of span, clean or repair the apparatus and

repeat the check. Adjust the dilution ratio as necessary to

achieve the correct response to the upscale check, but do not

adjust the analyzer calibration. Record the identification of

the orifice, aspirator air supply pressure, FIA back—pressure,

and the responses of the FIA to the carrier and system

calibration gases.

4.2.8 After completing the above checks, inject the system

calibration gas for approximately 10 minutes.

Time the exact

duration of the gas injection using a stopwatch. Determine the

area under the FIA response curve and calculate the system

response factor based on the sample gas flow rate, gas

concentration,

and the duration of the injection as compared to

the integrated response using Equations 2 and 3.

4.2.9 Verify that the sample oven

and sample line temperatures

are 120 ±5°Cand that the water bath temperature is 100 ±5°C.

4.2.10 Fill a tared syringe with approximately 1 g of the VOG~

containing liquid and weigh it. Transfer the liquid to a tared

sample vessel. Plug the sample vessel to 

minimize sample loss.

Weigh the sample vessel containing the liquid to determine the

amount of sample actually received. Also, as a quality control

check, weigh the empty syringe to determine the amount of

material delivered. The two coating sample weights should agree

356

within ±0.02

g. If not, repeat the procedure until an acceptable

sample is obtained.

4.2.11 Connect the vessel to the analysis system. Adjust the

aspirator supply pressure to the correct value. Open the valve

on the carrier gas supply to the sample vessel and adjust it to

provide a slight excess flow to the atmospheric vent. As soon as

the initial response of the FIA begins to decrease, immerse the

sample vessel in the water bath. (Applying heat to the sample

vessel too soon may cause the FID response to exceed the

calibrated range of the instrument, and thus invalidate the

analysis.)

4.2.12

Continuously measure and record the response of the FIA

until all of the

volatile material has been evaporated from the

sample and the instrument response has returned to the baseline

(i.e., response less than 0.5 percent of the span value).

Observe the aspirator supply pressure, FIA back—pressure,

atmospheric vent, and other

system operating parameters during

the run; repeat the analysis procedure if any of these parameters

deviate from the values established during the system calibration

checks in Section

4.2.7. After each sample perform the drift

check described in Section 5.2.

If the drift check results are

acceptable, calculate the VOG~content of the sample using the

equations in Section 7. Integrate the area under the FIA

response 

curve,

or determine the average concentration response

and the duration of sample analysis.

5. CALIBRATION AND QUALITY ASSURANCE

5.1 FIA Calibration and Linearity Check. Make necessary

adjustments to the air and fuel supplies for the FIA and ignite

the burner. Allow the FIA to warm up for the period recommended

by the manufacturer.

Inject a calibration gas into the

measurement system and adjust the back-pressure regulator to the

value required to achieve the flow rates specified by the

manufacturer. Inject the zero- and the high-range calibration

gases and adjust the analyzer calibration to provide the proper

responses.

Inject the low— and mid-range gases and record the

responses of the

measurement system. The calibration and

linearity of the system are acceptable if the responses for all

four 

gases are within 5 percent of the respective gas values.

the performance of the system is not acceptable, repair or adjust

the system and repeat the linearity check. Conduct a calibration

and linearity check after assembling the analysis system and

after a major change is made to the system.

5.2 Systems Drift Checks. After each sample, repeat the system

calibration checks in Section 4.2.7 before any adjustments to the

FIA or measurement system are made. If the zero or calibration

drift exceeds ±3percent of the span value, discard the result

and repeat the analysis.

357

5.3 Critical Orifice Calibration.

5.3.1 Each critical orifice must be calibrated at the specific

operating conditions that it will be used. Therefore, assemble

all, components of the liquid sample analysis system as shown in

Figure 

3. A

stopwatch is also required.

5.3.2

Turn 

on the sample oven, sample line, and water bath

heaters and allow the system

to reach the proper operating

temperature. Adjust the aspirator to a vacuum of 380 

(15 in.)

Hg vacuum. Measure the time required for one soap bubble to move

a known distance and record barometric pressure.

5.3.3

Repeat the calibration procedure at a vacuum of 406 mm (16

in.) Hg and at 25-mm (3.-in.) Hg intervals until three consecutive

determinations provide the same flow rate.

Calculate the

critical flow rate for the orifice in ml/min at standard

conditions. Record the vacuum necessary to achieve critical

flow.

6.

NOMENCLATURE

AL

area under the response curve of the liquid

sample, area count-~

area under the response curve of the calibration

gas, area count--.,

actual concentration of 

system calibration gas,

ppm propane-a

1.830 x 10’9g/(ml-ppm)-~j..

total VOGl.j content of liquid input, kg-ri.

mass of liquid sample delivered to the sample

vessel, g-rj,

q

flow rate

through critical orifice, m1/min”r~

liquid analysis system response factor, g/area

count-~-j

total gas injection time for system calibration

gas

during integrator calibration, min~~-j

VFj

final 

voq,~

fraction of VOG!~j containing 

liquid

jr.L

V1j

initial VO~jfraction of VO~jcontaining liquid

358

VAj

VOGIj 

fraction of

VOQ?~containing 

liquid

j

added

during the 

run-~

V

VO~j fraction of liquid sample-~-,~

WFj

weight of VOG?~

containing liquid

j

remaining at

end of the run, kg~-,L

Wij

weight of voq~containing liquid

j

at beginning of

the run, kg--j

WAj

weight of VOG~containing liquid j 

added during

the run, kg.

7.  CALCULATIONS

7.1 Total

VOG1j Content of the 

Input

VO~!jContaining Liquid.

n

nn

L

~ V1~1j=VFjWFj+ E VAjWAj R   

Eq. 2.

j1

j=l

7.2 Liquid Sample Analysis System Response Factor for Systems

Using Integrators, Grams/Area Counts.

Eq. 2

7.3 VOG~ContentA5 of the Liquid Sample.

Eq. 3

Procedure T

—

Criteria 

for and Verification of a Permanent or

Temporary Total Enclosure

1.  INTRODUCTION

1.1 Applicability.

This procedure is used to determine whether

a permanent or temporary enclosure meets the criteria of a total

enclosure.

1.2 Principle.

An enclosure is evaluated against a set of

criteria.

If the criteria are met and if all the exhaust gases

are ducted to a control device, then the volatile organic

compoundomaterials (VO~?j) capture efficiency (CE) is assumed to

be 100 percent and CE need not be measured.

However, if part of

the exhaust gas stream is not ducted to

a control device, CE must

be determined.

2.  DEFINITIONS

359

2.1 Natural Draft Opening (NDO) 

Any permanent opening in the

enclosure that remains open during operation of the facility

emission unit and is not connected to a duct in which a fan is

installed.

2.2 Permanent Total Enclosure (PTE) 

-—

A permanently installed

enclosure that completely surrounds a~oouroc -of emnissioneunit

such that all VOG~Jemissions are captured and contained for

discharge

through 

a control device.

2.3 Temporary Total Enclosure (TTE) 

A temporarily installed

enclosure that completely surrounds a~ souroc of

emissioneunit

such that all VOeIj emissions are captured and contained for

discharge through ducts that allow for the accurate measurement

of VOGZj 

rates.

3.  CRITERIA OF A TEMPORARY TOTAL 

ENCLOSURE

3.1

Any

NDO shall be at least 4 equivalent opening diameters

from each

VOG~Jemitting point.

3.2 Any exhaust point from the enclosure shall be at least 4

equivalent duct or hood diameters from each NDO.

3.3 The total area of all NDO’s shall not exceed 5 percent of

the surface area of the enclosure’s four walls, floor, and

ceiling.

3.4 The average facial velocity (FV) of air through all NDO’s

shall be at least 3,600 rn/hr (200 fpm). The direction of air

through all NDO’s shall be into the enclosure.

3.5 All access doors and windows whose

areas are not included in

Section 3.3 and are not included in the calculation in Section

3.4 shall be closed during routine operation of the

prooco3omission unit.

4.  CRITERIA OF A PERMANENT 

TOTAL ENCLOSURE

4.1 Same as Sections 3.1 and 3.3 

—

3.5.

4.2 All VO~Memissions 

must be captured and contained for

discharge through a control device.

5.  PROCEDURE

5.1 Determine the equivalent diameters of the 

NDO’s and

determine the distances from each VO~jemitting point to all

NDO’s. Determine the equivalent diameter of each exhaust duct or

hood and its distance to all NDO’s. Calculate the distances in

terms of equivalent diameters. The number of equivalent

diameters shall be at least 4.

360

5.2 Measure the total area (At) of the enclosure and the total

area (AN) of all NDO’s of the enclosure. Calculate the NDO to

enclosure area ratio (NEAR) as follows:

NEAR 

AN/At

The NEAR

must be 0.05.

5.3 Measure the volumetric flow rate, corrected to standard

conditions, of each gas stream exiting the enclosure through an

exhaust duct or hood using EPA Method 2. In some cases (e.g.,

when the building is the enclosure), it may be necessary to

measure 

the

volumetric flow rate, corrected to standard

conditions, of each gas stream entering the enclosure through a

forced makeup air duct using Method 2. Calculate FV using the

following equation:

(Qo

QI)/AN

where:

Qo

the sum of the volumetric flow from all gas

streams exiting the enclosure through an exhaust

duct or hood.

Qi

the sum of the volumetric flow from all gas

streams into the enclosure through a forced makeup

air duct; zero, if there is no forced makeup air

into the enclosure.

AN

total area of all NDO’s in enclosure.

The Fl? shall be at least 3,600 rn/hr (200 fpm).

5.4 Verify that the direction of air flow through all NDO’s is

inward. Use streamers, smoke tubes,

tracer gases, etc. Strips

of plastic wrapping film have been found to be effective.

Monitor the direction of air flow at intervals of at least 10

minutes for at least 1 hour.

6.  QUALITY ASSURANCE

6.1 The success of this protocol lies in designing the TTE 

simulate the conditions that exist without the TTE, i.e., 

the

effect of the TTE on the normal flow patterns around the affected

~ae4ty~~s~ion  ~ini~or the amount of fugitive VOGII emissions

should be minimal. The TTE must enclose the application

stations,

coating reservoirs, and all areas from the application

station to the oven. The oven does not have to be enclosed if it

is under negative pressure. The NDO’S of the temporary enclosure

and a fugitive exhaust fan must be properly sized and placed.

361

6.2. Estimate the ventilation rate

of the TTE that best

simulates 

the

conditions that exist without the TTE, i.e., the

effect of the

TTE

on the normal flow patterns around the affected

~

or the amount of fugitive VOGZj emissions

should be minimal. Figure 1 may be used as an aid. Measure the

concentration (CG) and flow rate (QG) of the captured gas stream,

specify a safe concentration (CF) for the fugitive gas stream,

estimate the CE, and then use the plot in Figure 1 to determine

the volumetric flowrate of the fugitive gas stream (QF). A

fugitive VOGIj emission exhaust fan that has a variable flow

control is desirable.

6.2.1 Monitor the concentration of VOG~jinto the capture device

without the TTE. To minimize the effect of temporal variation on

the captured emissions, the baseline measurement should be made

over as long a time period as practical. However, the process

conditions must be the same for the measurement in Section 6.2.3

as they are for this baseline measurement. This may require

short measuring times for this quality control check before and

after the construction of the TTE.

6.2.2 After the TTE is constructed, monitor the VO~)j

concentration inside the TTE. This concentration shall not

continue to increase and must not exceed the safe level according

to OSHA requirements for permissible exposure limits. An

increase in VOGN concentration indicates poor TTE design or poor

capture efficiency.

6.2.3 Monitor the concentration of 

VOQ?j

into the capture device

with the

TTE. 

To limit the effect of the TTE

on the process, the

VOGIj concentration with and without the TTE must be within ±10

percent. If the measurements do not agree, adjust the

ventilation rate from the TTE until they agree within 10 percent.

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

____________

362

Section 2l8.Appendix C

Reference Test Methods and Procedurcefor Air Oxidation Processes

Introduction

This Appendix presents the reference methods and procedures

required for implementing Reasonably Available Control

Technology

(RACT). Methods and procedures are

identified for two types of

~ACT

implementation:

a) Determination of

VOC~Jdestruction efficiency for evaluating

compliance with the 98 weight percent VOG~reduction 

or 20

ppmv emission limit specified in Sections 215.520 through

215.527; and

Determination of offgas flowrate, hourly emissions and

stream net heating value for calculating TRE.

All reference methods identified in this Appendix refer to the

reference methods specified at 40 CFR 

60, Appendix A,

incorporated by reference in Section 215.105.

VOGIj DESTRUCTION EFFICIENCY DETERMINATION

The following reference methods and procedures are required for

determining compliance with the percent destruction efficiency

specified in Sections 215.520 through 215.527.

a)  Reference Method 1 or 1A for selection of the sampling site.

The control device inlet sampling site for determination of

vent stream molar composition or total organic compound

destruction efficiency shall be prior to

the inlet of any

control device and after all recovery devices.

b)  Reference Methods 2, 2A, 2C or 2D for determination of the

volumetric flowrate.

c)  Reference Method 3 to measure oxygen concentration of the

air dilution correction.

The emission sample shall be

corrected to

3 percent oxygen.

d)  Reference Method 18 to determine the concentration of total

organic compounds (minus methane and

ethane) in the control

device outlet and total organic compound reduction

efficiency of the control device.

TRE DETERMINATION

The following reference methods and procedures are required for

determining the of fgas flowrate, hourly emissions, and the net

heating value of the gas combusted to calculate the vent stream

TRE.

363

a)  Reference Method 1 or 1A for selection of the sampling site.

The sampling site for the vent stream flowrate and molar

composition determination prescribed in (b) and (c) shall be

prior to the inlet of any combustion device, prior to any

post—reactor dilution of the stream with air and prior to

any post—reactor introduction of halogenated compounds into

the vent stream. Subject to the preceding restrictions on

the sampling site, it shall be after the final recovery

device. If any gas stream other than the air oxidation vent

stream is normally conducted through the recovery system of

the affected facility, such stream shall be rerouted or

turned off while the vent stream is sampled, but shall be

routed normally prior to the measuring of the initial 

value

of the monitored parameters for determining compliance with

the recommended RACT. If the air oxidation vent stream is

normally routed through any equipment which is not a part of

the air oxidation process as defined in 35 Ill. Adm. Code

211.122, such equipment shall be bypassed by the vent stream

while the vent stream is sampled, but shall not be bypassed

during the measurement of the initial value of 

the

monitored

parameters for determining compliance with Subpart V.

b)  The molar composition of the vent stream shall be determined

using the following methods:

1)  Reference Method 18 to measure the concentration of all

organics, including those containing halogens, unless a

significant portion of the compounds of interest are

polymeric (high molecular weight), can polymerize

before analysis or have low vapor pressures, in which

case Reference Method 25(a) shall be used.

2)  ASTM 

D1946-67

(reapproved 1977), incorporated by

reference in Section 215.105, to measure the

concentration of carbon monoxide and hydrogen.

3) Reference Method

4 to measure the content of water

vapor, if necessary.

C)   The volumetric flowrate shall be determined using Reference

Method 2, 2A, 2C or 2D, as appropriate.

d)  The net heating value of the vent stream shall be calculated

using the following equation:

n

H=K

E CiHi

i1

Where:

364

H

Net heating value of the sample, MJ/scm, where 

the

net enthalpy per mole of offgas

is based on

combustion at 25°C and 760 mm Hg, but the

standard

temperature for determining the volume

corresponding to one mole is 20°C,as in the

definition of F (vent stream flowrate) below.

Constant, 1.740 x 10”7(1/ppm) (mole/scm) (MJ/kcal)

where standard temperature for mole/scm is 20W.

Ci

Concentration 

of sample component i, reported on a

wet basis, in ppm, as measured by Reference Method

18 or ASTM D1946-67 (reapproved 1977),

incorporated by reference in Section 215.105.

Hi

Net heat of combustion of sample component i,

kcal/mole based on combustion at 25!,C and 760 mm

Hg. If published values are not available or

cannot be calculated, the heats of combustion of

vent stream components are required to be

determined using

ASTM D2382-76, incorporated by

reference in Section 215.1O5~

e)  The emission rate of total organic compounds in the process

vent stream shall be calculated using the following

equation:

n

E=K F E CiMi

i=1

where:

E  = Emission rate of total organic compounds (minus

methane and ethane) in the sample in kg/hr-i-;

K

Constant 2.494 x 10”6(1/ppni) (mole/scm) (kg/g)

(min/hr), where standard temperature for

(mole/scm) is 20°C,-;

Mi

Molecular weight of sample 

component i (g/mo1e)~

Vent stream flowrate (scm/mm), at a standard

temperature of 20°C.

f)  The total vent stream concentration (by volume) of compounds

containing halogens (ppmv, by compound) shall be

summed froir

the individual concentrations of compounds containing

halogens which were measured by Reference Method 18.!,,

365

Amended at

—

Ill. Reg. 

_____

effective

____________

366

Section 218.Appendix D

Coefficients for the Total Resource Effectiveness Index (ThE)

Equation

This Appendix contains values for the total resource

effectiveness index (TRE)

equation in Subpart V.

If a flow rate falls exactly on the boundary between the

indicated ranges, the operator shall use the row in which the

flow rate is maximum.

COEFFICIENTS FOR TRE EQUATION FOR CHLORINATED PROCESS

VENT STREAMS WITH

NET HEATING VALUE LESS THAN OR EQUAL TO 3.5 NJ/scm

FLOW RATE

(scm/nun)

Mm. Max.  a    

b

c

d

e

f

0.0 13.5 48.73 0.   

0.404 —0.1632 0.   

0.

13.5 700.  42.35 0.624 0.404 —0.1632 0.   

0.0245

700. 1400.  84.38 0.678 0.404 —0.1632 0.   

0.0346

1400. 2100. 126.41 0.712 0.404 —0.1632 0.   

0.0424

2100. 2800. 168.44 0.747 0.404 —0.1632 0.   

0.0490

2800. 3500. 210.47 0.758 0.404 —0.1632 0.   

0.0548

CO.EFFICIENTS FOR TRE EQUATION FOR CHLORINATED PROCESS

VENT STREAMS

WITH

NET HEATING VALUE GREATER 

THAN

3.5 MJ/scm

FLOW RATE

(scm/mm)

Mm. Max.  a    

b

c

d

e

f

13.5

47.76

—0.292

13.5 700.  41.58 0.605 —0.292 0.    

0.

0.0245

700. 1400.  82.84 0.658 —0.292 0.    

0.

0.0346

1400. 2100. 123.10 0.691 —0.292 0.    

0.

0.0424

2100. 2800. 165.36 0.715 —0.292 0.    

0.

0.0490

2800. 3500. 206.62 0.734 —0.292 0.    

0.

0.0548

COEFFICIENTS FOR

TRE

EQUATION FOR NONCHLORINATED PROCESS

VENT STREAMS WITH

NET HEATING VALUE LESS THAN OR EQUAL TO 0.48 NJ/scm

FLOW RATE

(scm/mm)

Mm. Max.  

a

b

c

d

e

f

0.  13.5 19.05 0.   

0.113 —0.214  0.   

0.

13.5 1350.  16.61 0.239 0.113 —0.214  0.   

0.0245

1350. 2700.  32.91 0.260 0.113 —0.214  0.   

0.0346

2700. 4050.  49.21 0.273 0.113 —0.214  0.   

0.0424

COEFFICIENTS FOR TRE EQUATION FOR NONCHLORINATED PROCESS

367

VENT STREAMS

WITH NET HEATING VALUE GREATER THAN 

•

48 AND LESS THAN OR

EQUAL 

1.9 NJ/scm

FLOW RATE

(scm/mm)

Mm.

Max.  

a

0.

13.5 19.74 0.   

0.400 —0.202  0.   

0.

13.5 1350.  18.30 0.138 0.400 —0.202  0.   

0.0245

1350. 2700.  36.28 0.150 0.400 —0.202  0.   

0.0346

2700. 4050.  54.26 0.158 0.400 —0.202  0.   

0.0424

COEFFICIENTS FOR TRE EQUATION FOR NONCHLORINATED PROCESS

VENT STREAMS

WITH NET HEATING VALUE GREATER THAN 1.9 

AND

LESS THAN OR

EQUAL TO 

3.6 NJ/scm

FLOW RATE

(scm/mm)

Mm. Max.  a    

b

c

d

e

f

13.5

15.24

0.033

13.5 1190.  13.63 0.157 0.033 0.    

0.

0.0245

1190. 2380.  26.95 0.171 0.033 0.    

0.

0.0346

2380.

3570.

40.27

0.179 0.033

0.0424

COEFFICIENTS FOR TRE EQUATION FOR NONCHLORINATED PROCESS

VENT STREAMS WITH

NET HEATING VALUE GREATER THAN 

3.6 MG/scm

FLOW RATE

(scm/mm)

Mm. Max.  a   

b  c     

d

e

f

13.5

15.24

0.0090

13.5 1190. 13.63  0.  0.   

0.0090  0.0503  0.0245

1190. 2380. 26.95  0.  0.   

0.0090  0.0546  0.0346

2380. 3570. 40.27  0.  0.   

0.0090  0.0573  0.0424

(Source:

Amended 

—

Ill. Reg. 

______,

effective 

__________

_______________________ )

368

TITLE 35: ENVIRONMENTAL PROTECTION

SUBTITLE B: AIR POLLUTION

CHAPTER I: POLLUTION 

CONTROL BOARD

SUBCHAPTER C:  

EMISSIONS

STANDARDS AND LIMITATIONS

FOR STATIONARY

SOURCES

PART 219

ORGANIC MATERIAL EMISSION STANDARDS AND 

LIMITATIONS

FOR STATIONARY SOURCES

SUBPART A:

GENERAL PROVISIONS

Section

219. 100

219.101

219. 102

219

103

219.104

219.105

219. 106

219. 107

219. 108

219. 109

219.110

219.111

219. 112

219.113

SUBPART B:

Introduction

Clczin-up 3nd Di~po~a

Abbreviations and Conversion Factors

Applicability

Definitions

Test Methods and Procedures

Compliance Dates

1 OperationSavings Clause

Operation of Afterburners

Exemptions, Variations, and Alternative Means of

Control or Compliance Determinations

Vapor Pressure of Volatile Organic Liquids

Vapor Pressure of Organic Material or Solvent

Vapor Pressure

of Volatile Organic Material

Incorporations by Reference

Monitoring for Negligibly-Reactive Compounds

ORGANIC EMISSIONS FROM STORAGE AND LOADING OPERATIONS

Separation Operations

Pumps and Compressors

Vapor Blowdown

Safety Relief Valves

Solvent Cleaning in General

Cold Cleaning

Section

219.121 Storage Containers

219.122 Loading Operations

219.123 Petroleum Liquid Storage Tanks

219.124 External Floating Roofs

219.125 Compliance Dates (Repealed)

219.126 Compliance Plan (Repealed)

SUBPART C: ORGANIC EMISSIONS FROM MISCELLANEOUS EQUIPMENT

Section

219.141

219.142

219. 143

219.144

Section

219.181

219. 182

SUBPART E:

SOLVENT CLEANING

369

219. 183

219.184

219.185

219. 186

Open Top Vapor Degreasing

Conveyorized Degreasing

Compliance Schedule (Re~ea1ed)

Test Methods

SUBPART F: COATING OPERATIONS

Section

219. 204

219.205

219

206

2 19.207

219.208

219

209

219.210

219.211

Emission Limitations for Hanuf~ictur

a a-

.‘~

____

~.

Daily-Weighted Average Limitations

Solids Basis Calculation

Alternative Emission Limitations

Exemptions From Emission Limitations

Exemption From General Rule on Use of Organic Material

Compliance Schedule

Recordkeeping and Reporting

SUBPART G: USE OF 

ORGANIC MATERIAL

Section

219. 301

219.302

219.303

219.304

Section

219.401

219.402

219.403

219.404

219.405

SUBPART

Section

219.421

219.422

219.423

219.424

219.425

219.426

219.427

219.428

219.429

219 .430

Use of Organic Material

Alternative Standard

Fuel Combustion Emission Courcc~Units

Operations with Compliance Program

SUBPART H: PRINTING AND PUBLISHING

Flexographic and Rotogravure Printing

Applicability

Compliance Schedule

Recordkeeping and Reporting

Heatset-Web-Off set Lithographic Printing

Q: LEAKS FROM SYNTHETIC ORGANIC CHEMICAL AND POLYMER

MANUFACTURING EQUIPMENT PLANT

General Requirements

Inspection Program Plan for Leaks

Inspection Program for Leaks

Repairing Leaks

Recordkeeping for Leaks

Report for Leaks

Alternative Program for Leaks

Open-Ended Valves

Standards for Control Devices

Compliance Date (Repealed~

370

SUBPART R:

PETROLEUM REFINING AND RELATED INDUSTRIES;

ASPHALT MATERIALS

Section

219 .480

219.481

Petroleum Refinery Waste Gas Disposal

Vacuum Producing Systems

Wastewater (Oil/Water) Separator

Process Unit Turnarounds

Leaks: General Requirements

Monitoring Program Plan for Leaks

Monitoring Program for Leaks

Recordkeeping for Leaks

Reporting for Leaks

Alternative Program for Leaks

Sealing Device Requirements

Compliance Schedule for Leaks

Compliance Dates (Repealed)

SUBPART S: RUBBER AND MISCELLANEOUS PLASTIC PRODUCTS

Manufacture of Pneumatic Rubber Tires

Green Tire Spraying Operations

Alternative Emission Reduction Systems

Tc3ting and HonitoringEmission Testing

Compliance Dates (Repealed)

Compliance Plan (Repealed)

SUBPART T: PHARMACEUTICAL MANUFACTURING

Systems and Filters

Material Storage and Transfer

In—Process Tanks

Leaks

Other Emission

S-o-urceo Units

Testing

Monitoring and Rccordhc~ina

Equipment

219.489 Recordkeeping for Air Pollution Control Equipment

SUBPART V: AIR 

OXIDATION PROCESSES

Definitions (Repealed)

Emission Limitations for Air Oxidation Processes

Testing and Monitoring

Compliance Date (Repealed)

Section

219. 441

219.442

219. 443

219.444

219.445

219.446

219. 447

219.448

219.449

219. 450

219.451

219.452

219.453

Section

219.461

219.462

219.463

219.464

219.465

219.466

Applicability

Control of Reactors, Distillation Units, Crystallizers,

Centrifuges and Vacuum Dryers

219.482 Control of Air Dryers, Production Equipment Exhaust

219.483

219.484

219.485

219.486

219 .487

219.488                

for Air Pollution Control

Section

219.521

219.525

219.526

219.527

371

SUBPART W: AGRICULTURE

Section

219.541 Pesticide Exception

Perchioroethylene Dry Cleaners

Exemptions

Leaks

Compliance Dates (Repealed)

Compliance Plan (Repealed)

Exception to Compliance Plan (Repealed)

Standards for Petroleum Solvent Dry Cleaners

Operating Practices for Petroleum Solvent Dry Cleaners

Program for Inspection and Repair of Leaks

Testing and Monitoring

Exemption for Petroleum Solvent Dry Cleaners

Compliance Dates (Repealed)

Compliance Plan (Repealed)

SUBPART AA: PAINT AND INK MANUFACTURING

Section

219. 620

219.621

219.623

219.624

219.625

219.626

219.628

219.630

Applicability

Exemption for Waterbase Material and Heatset-Offset Ink

Permit Conditions

Open-~Top Mills, Tanks, Vats or Vessels

Grinding Mills

Storage Tanks

Leaks

Clean Up

SUBPART X: CONSTRUCTION

Architectural Coatings

Paving Operations

Cutback Asphalt

SUBPART Y:

GASOLINE DISTRIBUTION

Bulk Gasoline Plants

Bulk Gasoline Terminals

Gasoline Dispensing Facilities 

—

Storage Tank Filling

Operations

Gasoline Delivery Vessels

Gasoline Volatility Standards

Gasoline Dispensing Facilitic~Operations 

—

Motor

Vehicle Fueling Operations

SUBPART Z: 

DRY CLEANERS

Section

219.561

219.562

219.563

Section

219.581

219.582

219.583

219.584

219.585

219.586

Section

219. 601

219.602

219.603

219.604

219.605

219.606

219.607

219.608

219.609

219.610

219.611

219.612

219.613

372

219.636

219.637

Compliance Schedule

Recordkeeping and Reporting

SUBPART BB: POLYSTYRENE 

PLANTS

Section

219.875219.640

Applicability of Cubpart BE

219.877219.642

Emissions Limitation at Polystyrene Plants

219.886219.644

Emissions Testing

Applicability of Subpart BB (Renumbered)

Emissions Limitation at Polystyrene Plants (Renuinbereth

Compliance Date (Repealed)

Compliance Plan (Repealed)

Special Requirements for Compliance Plan (Repealed)

Emissions Testing (Renumbered)

SUBPART PP: MISCELLANEOUS FABRICATED PRODUCT

MANUFACTURING PROCESSES

Section

219.920

219.923

219.926

219.927

219.928

Applicability

Permit Conditions

Control Requirements

Compliance Schedule

Testing

SUBPART 

QQ:

MISCELLANEOUS FORMULATION MANUFACTURING PROCESSES

Section

219.940

219.943

219.946

219.947

219.948

Section

219.960

219.963

219.966

219.967

219.968

Applicability

Permit Conditions

Control Requirements

Compliance Schedule

Testing

SUBPART RR: MISCELLANEOUS ORGANIC CHEMICAL

MANUFACTURING PROCESSES

Applicability

Permit Conditions

Control Requirements

Compliance Schedule

Testing

SUBPART TT:

OTHER EMISSION COURCES UNITS

Section

219.980

219.983

219.986

219.987

Applicability

Permit Conditions

Control Requirements

Compliance Schedule

219.875

219.877

219.879

219 .881

219.883

219.886

373

219.988 Testing

SUBPART UIJ: RECORDKEEPING AND REPORTINC F-OR NON-CTC COUI1CEC

Section

219.990 Exempt Emission CourocoUnits

219.991

Subject Emission CourocoUnits

Section 219.Appéndix A: List of Chemicals Defining Synthetic

Organic Chemical and Polymer

Manufacturing

Section 219.Appendix B: VON Measurement Techniques for Capture

Efficiency

Section 219.Appendix C: Reference Test Methods and Proccdurco

for Air Oxidation

Section 219.Appendix D: Coefficients for the Total Resource

Effectiveness Index (TRE) Equation

AUTHORITY: Implementing Section 10 and authorized by Section

28.5 of the Environmental Protection Act (Ill. Rev. Stat. 1991,

ch. 111½, par. 1010) ((P.A. 87-1213, effective September 26,

1992) 415 ILCS 5/10 and 28.5.

SOURCE: Adopted at R9l-8 at 15 Ill. 

Reg. 12491, effective August

16, 1991; amended in R9l—24 at 16 Ill. Reg. 13597, 

effective

August 24, 1992; amended in R91—30 at 16 Ill. Reg. 13883,

effective August 24, l992~ amended in 

___________

at —  Ill.

Reg. 

______,

effective __________________________

374

SUBPART A:

GENERAL PROVISIONS

Section 219.100

Introduction

a)

This Part contains standards and limitations for

emissions of organic material and volatile organic

material from stationary sources located in the Metro~

East area, which is comprised of

Madison, Monroe, and

St. Clair Counties.

Sources subject to this Part may be subject to the

following:

1)  Permits required under 35 Ill. Adm. Code 2Ol-~~

Air quality standards under 35 Ill. Adm. Code

C)

This

2Part43~~is

divided 

into Subparts which are grouped as

follows:

Subpart A: General Provisions~

2)  Subparts B-F: Emissions from equipment and

operations in common to more than one industry;

3)  Subpart G: Emissions from use of organic

material;

4)  Subparts 

H—e*~4~:

Cpccial rEules for various

industry groups.

Subpart TT: Rules for emission units not

otherwise addressed.

~J

Subpart UU: Recordkeeping and reporting for

equipment and operation addressed by Subparts PP.

00. RR, and TT.

(Source:

Amended at

_____,

Ill.

Reg.

_____,

effective

__________

Section 219.101

Clo~

ono~al OpcrationSavings Clause

Emiooion of organic material released during clean up opera e~e

a-nd diopocal &~ia1l be included with other omissions of organic

~atoria1 from the reiaceu emission source or air

control equipment 

a.,

~

total effiicrniono.

Every owner or operator of an emission unit formerly subiect to

35 Ill. Adm. Code 215 shall have complied with its standards and

limitations by the dates and schedules applicable to the emission

375

unit in accordance with Part 215 or upon initial start-up.

All

compliance dates or schedules found in Part 215 are not

superseded bY this Part and remain in full Iorce and 

effect.

(Source: Section repealed,

new Section added at 

______,

Ill.

Reg.

,     effective __________________________________)

Section 219.102  

Abbreviations and Conversion Factors

a-)-

Thc following abbrcviations arc

ed in this Part:

ACTH

bbl

em

cu in

g /

mo1

C

~4c

kca I

kg

kg/hr

kPa

-1

1/sec

lbs/hr

lbs/gal

LEL

mm Hg

ppm

ppmv

pal a

cubic inches

degrees Fahrenheit

ywn.~. 

pei~

minute

grams pcr mole

gallons

houre

inchcs

Kclvin

kilocalori-es

3d lograms

kilograms per hour

kilopascals; one Ui

mctcr

liters

liters per second

pounds

1~~

w~ta ,sa.a     

- - .,‘.JSAJ.

pounds per gallon

r~ut-~r,—~vrl1 

i

vr~

mn i t

meters

s_,

Li L~4 ~

jtfl~ —.

S~.~ Li

metric

milliliters

minutes

mcgajoule a

—~

1•1~

~

p. —— 2 —

——

——S.

—4-4—-—.’-

—

feet

Implcmcntati

feet

milligrams

tons

~~~2

volume

~uarc inch absolute

paig

ccf

scm

Sec

TTE

sq am

sq in

UCEPA

~9M

standard pubic feet

standard cubic 

‘-----

3000flUt3

-temporary total end

square centimeters

square 

j.iiuimCQ

English ton

English ton

United States Environmental

volatile organic compounds

volatile organic liquids

volatile organic materials

~--

The following   

s~ionfactors are   

in this

English

Metric

I gal

1,000 gal

1 psia

2.205 lbs

1 bbl

1 cu in

1 lb/gal

1 ton

iT

3.785 1

1

?~.897kPa (51.71 

mitt

Hg)

159.0 1

16.39 ml

119,800 mg/l

0.907 Hg

0.907 Hg

The abbreviations and conversion factors of 35 Ill. Adm. Code 211

apply to this Part.

(Source:

Amended at

____,

Ill. Reg. 

____

effective 

____________

Section 219.104  

Definitions

The following

—-

—

S.t

2 —

“Acoclacota” means

a pharmaceutical coating operation

which eansists of a horicontally rotating perforated

drum in which tablets are placed, a coating is applied

by spraying, and the coating is dried by the flow of

air across the drum through the perforations.

“Accumulator” means the reservoir of a condensing unit

receiving the condonsato from a surface condenser.

i,-..j

r~-~~r-—~”

means frir 

thr’ ~

~f

r~t~i

r~ii

-

rif

the Envis.,.,...ent~a 

~SLi~.~a.)fl

Act (the Act)

(T~~

Stat. 1987, oh. lii 1/2, par. 1009.4), hydrogen

376

iII~I~ .‘a. Li

2—

377

chloride, hydrogen fluorid~..

exist as gases, liquid mist, or any combination

thereof.

“Actual emissions” means the actual quantity of VOM

omissions from an omission sourco during a partioul-ar

time period.

“Actual Heat Input” moans the quantity of heat

produced

by the combustion of fuel using the -gross heating va1~e

of the fuel.

“Adhesive” moans any substance or mixture of substances

intended to serve as a joining compound.

“~Aftorburner”moans a control device in which materials

in gaseous effluent are combusted.

“Air contaminant” means any solid, liquid, or gaseous

matter, any odor, or any form of energy, that is

capable of being released into the atmosphere from an

emission source.

“Air dried coatings” means any coatings that dry by 

use

of air or forced air at temperatures up to 363.15~Y~

(194°F)

_~....d through the chambers.

HAirless 

spray” means a spray coating 

method in which

thc~ 

c~c~ntinri i~

m~r~d hv 

fc~,rt-~inrt

it

throuah 

—

“Air pllution” means

—--esence in the atmosDhcre of

LiuiL~

iS’S~

contaminants 4r. s~fficicnt~antiti..Li

and of such characteristics 

~and duration as to b-c

injurious to human, plant, or animal life, to health,

or to property, or to unreasonably interfere with the

enjoyment of life or property.

“Air pollution control equipment” means any equipment

or facility of a type intended to eliminate, prevent,

reduce or control the emission of specified air

contaminants to the atmosphere.

“Air suspension coater/drycr” means a pharmaceutical

coating operation which consists

of vertical chambers

in which tablets or particles are placed, and a coating

is applied and then dried while the tablets or

particles arc kept in a fluidicod state by the passage

a i

nr~ur,1-

opening at high pressure. The coating liquid iB not

mixed with air before exiting from the noccic.

378

“Air-assisted airless spray” moans a spray coating

method which combines compressed air with hydraulic

pressure to atomiec the coating material into finer

droplets than is achieved with pure airloos spray.

Lower hydraulic pressure is used than with airless

spray.

“Allowable omissions” means the quantity of VOM

emissions during a 

particular

time period from a

stationary source calculated using the maximum rated

capacity of the source (unless restricted

—J

federally

entoraaa~io iiml...Li..iona on operating rate, hours of

operation, or both) and the most stringent of i   

the

applicable st    

in 40 CFfl Parts 60 and 61; th~

~

impi~~     

.C_~3

anciares

r~mr~rtt.1LLLJr1 

‘- -.

.JL .~.t

pi.~L_Ju.L1..

“Ambient air quality standards” means those standards

designed to protect the public health and welfare

codified in 40 CFR Part 50 and promulgated from time to

time by the UCEPA pursuant to authority contained in

Section 108 

of

the Clean Air Act, 42 U.S.C. 7401 

et

seq., as amended from time to time.

“Applicator” moans a device used in a coating line to

apply coating.

“As applied” moans the exact formulation of a coating

during application on or impregnation into a substrate.

“Architectural Coating” means any coating used for

residential or commercial buildings or their

appurtenances, or for industrial buildings, which is

site applied.

“Asphalt” means the dark-brown to black coniontitious

material (solid, semisolid, or liquid in consistency)

of which the main constituents arc bituinens which occur

naturally or as a residue of petroleum refining.

“Asphalt Prime Coat” means a low-viscosity liquid

asphalt applied to an absorbent surface as the first of

more than one asphalt coat.

“Automobile” moans a motor vehicle capable of carrying

no more than 12 passengers.

“~‘~tomobi1  

light   

truck

facility whcrc parts arc assembled

LiLiSCnit 

ly plant”

_1____t.1

finished

—

light-duty truck ready for sale to vehicle dealers, b~i~

not including customi

rcpaintcrs.

379

~‘~~~2

~s, and other

“Automobile or light duty truck refinishing” means the

repainting of uscd automobiles and light-duty trucks—.

“Baked coatings” means any coating which is cured or

dried in an oven where the oven air temperature cxoeed~

90°C (194cF).

“Batch LLi......~

—————.

4—1_.

~

af loading 

number

of individual parts at the same time for degreaaing-~-

“Bead-Dipping” mcano the dipping of an assembled tire

bead into a solvent—based cement.

“Binders” moans organic materials and rc~inswhich do

not contain VOM.

“Bituminous coatings” means black or brownish coating

materials which are soluble in carbon disulfide, which

consist mainly of hydrocarbons, and which are obtained

dcposit3 gras residues from the

line to gasoline

“Bulk Casolino Terminal” moans any gasoline storage and

distribution facility that receives gasoline by

pipeline, ship or barge, and distributes gasoline to

bulk gasoline plants or gasoline dispensing facilities.

“Can” means any metal container, with or without a top-i-

cover, spout or handles, into which solid or liquid

materials are packaged.

“Can coating” means any coating applied on a single

walled container that is manufactured from metal ~hcets

thinner than 29 gauge (0.0141 in.).

II.-.44-4~

yi....4e-It

__r

.4-

___-.

—

-,.‘——

—“~—

.--

required to raise one pound of water from 60°Fto ~1°F

(abbreviated btu) 

——

—

applying a coating u3ingabruch,

cloth, or similar

object.

“Bulk 

gasoline plant” means

a gasoline storage and

distribution facility with an av--”~ th~-rn~r~hr~ut

of

36,000 

1 (20,000 gal) or l~Li

average that distributes g~

di~oc~nr~inafaci1itic~.

380

“Can coating 

“

means a facility that includes one or

more can coating line(s).

“Can coating line” moans a coating line in which any

protective, decorative, or functional coating is

applied -onto the surface of cans or can components.

“Capture” means -the containment or recovery of

emissions from a process for direction into a duct

which may be exhausted through a stack or vent to a

control device. The overall abatement of omissions

from a process with an add on control device is a

function both of the capture efficiency and of the

control device.

“Capture device” means a hood, enclosed room floor

swoop or other moans of collecting solvent or other

pollutants i.nto a duct. The pollutant can then be

directed to a pollution control device ouch as an

afterburner or carbon adsorbcr. Comctimcs the term is

used loosely to include the control device.

“Capture efficicncy- means

by

a process tnat

or recovery device

“Capture system” means all equipment (including, but

not limited to, hoods, ducts, fans, ovens, dryers,

etc.) used to contain, collect and transport an air

pollutant to a control device.

“Clean Air Act” means the Clean Air Act of .1963, as

amended, including the Clean Air Act Amendments of

1977, (42 U.S.C. 7401 et seq.), and the Clean Air Act

Amendments of 1990, 

(P.L. 

101-540)

“Clear coating” means coatings that lack oolor and

opacity or arc transparent using the undercoat as a

ref loctant base or undertone color.

“Clear topcoat” moans the final coating which contains

binders, but not opaque pigments, and is specifically

formulated to form a transparent or translucent solid

protective film.

“Closed Purge System” means a system that is not 

ope~

to the atmosphere and that is composed of piping,

eonnections, and, if ncoeosary, flow inducing devices

that transport liquid or vapor from a piece or pieces

of equipment to a control device, or return the liqui-d

or vapor to the process line.

~

app-lied, dried,

-f~ is not

for

~...

~pcration to have

e

flash-off

Li~Lif

or drying area to be

this 

dcfin

a33ociatcd flash-aff

uhs—)—r’ ~i

r~iii—f.~r~

flCCCQ5Li~.

L L.1(Jf1.

, 1,rI

~

fJr’n~

rtr

c~11rc

...

.~iucicci

“Coating plant” means -any plant that contains one or

more coating un c(s).

“Coil” means any flat metal shcct or strip that is

rolled or wound in conoentric rings.

“Coil coating”   

any coating applied  any flat

metal chect or strip that comes in rolls or coils.

“Coil coating facility” means a facility that includes

one or more coil coating line(s).

“Coil coating line” means a coating line in which any

protective, decorative or functional coating is applied

onto the surface of fl-at metal sheets, strips, rolls,

or coils for industrial or commercial use.

“Cold cleaning” means the process of cleaning and

removing soils from surfaces by spraying, brushing,

flushing, or immersion while maintaining the organic

solvent below its boiling point. Wipe cleaning is not

included in this definition.

“Complete Combustion” means a process in which all

carbon contained in a fuel or gas stream is converted

to carbon dioxide.

“Component” means, with respect to synthetic organ-i-e

chemical and polymer manufacturing equipment, and

381

“Closed vent system” means a system that is not open—to

the atmosphere and is 

composed of piping, connections,

and, if necessary, flow inducing devices that transport

gas or vapor from an emission source to a control

device.

“Coating” means a material applied onto or impregnated

into a substrate for protective, decorative, or

functional purposes. Cuch materials include, but arc

not limited to, paints, varnishes,sociloro, adhesives,

thinners, dilucnts, and inks.

“Coating applicator” moans equipment used to apply a

coating.

“Coating line” mcar~

art

nrtc~rati~n

conc~istingof a

nf

mn~~

~

and any

~r

382

petroleum refining and related industries, any piece of

equipment which has the potential to leak VOM

including, but not limited to, pump seals, compressor

seals, seal oil degassing vents, pipeline valves,

pressure relief devises, propose drains, and open ended

pipes. This definition excludes valves which arc not

externally regulated, flanges, and equipment in heavy

li-quid service. For purposes of Cubpzirt Q of this

Part, this definition also excludes bleed ports of gear

pumps in polymer service.

“Concrete curing compounds” moans any coating applied

to freshly poured oonorete to retard the evaporation 

Of

water.

“Condensate” moans volatile organic liquid separated

from its associated gases, which condenses due to

changes in the temperature or pressure and remains

liquid at standard conditions.

“Continuous process” means, with respect to polystyrene

resin, a mctho-d of manufacture in which the styrenc raw

maecrictl is delivered on a continuous basis to the

reactor in which the styrene is polyinerizcd to

polystyrene.

“Control device” means equipment (such as an

afterburner or adsorber) used to remove or prevent the

emission of air pollutants from a contaminated exhaust

stream.

“Control device efficiency” means the ratio of the

pollution prevented by a control device and the

pollution introduced to the control device, expressed

as a percentage.

“Conveyoriz-ed degreacing” means the continuous process

of cleaning and removing soils from surfaces utilizing

cither cold or vaporized solvents.

“Crude oil” means a naturally occurring mixture which

consists of hydrocarbons and sulfur, nitrogen, or

oxygen derivatives of hydrocarbons and which 

is a

liquid at standard conditions.

“~udc oil ~~~5ing” 

the 4

~1f~VT

~il or condensate after custody transfer betwe~..., 

production facility and a reception point.

“-Custody transfer” moans the transfer of produced

petroleum and/or condensate -aftcr processing and/or

treating in the producing operations, from storage

T-1r~r, ~f  crucl-e

tanks or automatic transfer facilities to pipelines or

any other forms of transportation.

“Cutback Asphalt” moans any asphalt which has boon

liquif led by blending with petroleum solvents other

than residual fuel oil and has not boon emulsified with

water.

“Daily—weighted average von content” moans the avcra~e

von content of two or more coatings a~applied on -a

coating 1mb during any day, taking into account the

fraction of total coating volume that each coating

represents, as -calculated with the following equation:-

~_n

~

where:

The average Von content of two or more

coatings as -applied each day on a

coatina line in units of kg yOH/. (lbs

-‘

~

(minus water and

compounds which arc specifically

exempted from the definition of VOl-I),

—

~nc number

Oi

~

ui~i~~iflU~

arnhleg cacn 

n~~’

on a coacir~rT

—

The volume of each coating (minus water

and any compounds which arc specifically

exempted from the definition of VOH) as

applied each day on a coating line in

units of 1 (gal).

nfl

ri~’.

tilT

ICtil

~.rt

fically

definition of VOH), and

-The total

—s.—

lume of all coatings (minus

specifically exempted from the

t,,~, I

ii I

LLnLI

.,I~

~-VON)~.

applied

383

~7ON/gal)

_s.~

—-~

——-—.—.,

The VON content of each co~tingao

--~:: 

‘~?.‘JH/l (lbs

VOH/gal)

) ~

~ L11

(~.JLH1

111V

(1111

OO~t

1 riu

fll~

coating

~ininus 

wuccr und ~tny

—

—----—-~

-,--—..—---.-‘

compounds

-p.--

-~

-each duy

on a coating line in uni~t~ui. 

(gal).

384

“Day” means the consecutive 24 hours beginning at

AH (midnight) local time.

l2,-9-9~

“Degroaser” means any equipment or system used in

solvent cleaning.

“Delivery vessel” means any tank truck or trailer

equipped with a storage tank that is used for the

transport of gasoline to a stationary storage tank ata

gasoline dispensing facility, bulk gasoline plant, or

bulk gasoline terminal.

“Dip coating” means a method of applying coatings in

which the part is submerged in a tank filled with

coating.

the

means

“~~-‘--~

~‘uclOil”   

fuel 

--..~

---

4

rJrl

4

ficd in detailed ~equ............or fuel oil

AETH D—~69—6~l(1~71~

~-.

“Dry Cleaning Facility” means a facility engaged in the

cleaning of fabrics using an essentially nonaqueous

solvent by means of one or more solvent washes,

extraction of excess solvent by spinning and drying by

tumbling in an airstrccun. The facility includes, but

is not limited to, washers, dryers, filter and

purification systems, waste disposal systems, holding

tanks, pumps and attendant piping and valves.

“Effluent Water Ecpztrator” moans any tank, box, oump or

r~t-hr~r anna

tn~ in

uhit-~h 

ant’

nrgr~nir~ matr~ria1

f~r~ating

Onor 

ontrained or oontaincd in water entering such

tank, box, sump 

or other apparatus is physically

separated and removed from ouch water prior to 

outfall,

drainage or recovery of ouch water.

“Electrostatic bell or disc spray” means an

electrostatic spray coating method in which a

rapidly-spinning bell- or disc-shaped applicator is

used to 

create 

a fine mist and apply the coating with

high transfer efficiency.

“Electrostatic spray” means a spray coating method in

which opposite electrical charges arc applied to the

substrate and the coating. The coating is attracted to

the object duo to the electrostatic potential between

them.

—I

“Emission nate” moans total quantity of any air

contaminant discharge into the atmosphere in any

one-hour period.

385

“Emission source” and “source” mean any facility from

which von is cmitted or capable of being emitted mt-c

the atmosphere.

“Enamel” means a coating that cures by chemical

cross-linking of ito base resin. Enamels can be

distinguished from lacquers bcoausc enamels are not

readily resoluble in their original solvent.

“Enclose” means to cover any VOL surface that is

exposed to the atmosnh~rc.

•“End sealing compound goat” means a compound applied to

ean ends which functions as a gasket when the end is

• assembled onto the can.

“Excess Air” means air supplied in addition to the

theoretical quantity necessary for complete combustion

of all fuel and/or oombustiblc waste material.

“Excessive release” means a discharge of more t-han 295

g (0.65 lbs) of mercaptans and/or hydrogen sulfide into

the atmosphere in any 5-minute period.

“Exterior base

coat” means a coating applied to the

exterior of a can body, or flat sheet to provide

protection to the metal or to provide background for

any lithographic or printing operation.

“Exterior end coat” means a coating applied to the

exterior end of a can to provide protection to the

metal.

r

storage tank consisting of a double deck or pontoon

single deck which rests upon and is supported by the

volatile organic liquid being contained and is equipped

with a closure seal or seals to close the space between

the roof edge and tank ohcll.

11-Extromc environmental conditions” means exposure to

any or all of the following! ambient weather

conditions; temperatures consistently above 

95°C

(203°F); detergents; abrasive and scouring agents;

solvents; or corrosive atmospheres.

“Ext

conditions.

~+#~

immç

performance 

coating” means any coating which

‘-“

intended use is exposed

to extreme onvironmenta-l

386

“Fabric coating” means any coating applied on textile

fabric. Fzibrio coating includes the application -e~

coatings by impregnation.

“Fabric coating facility” means a faoility that

includes one or more fabric coating lines.

“Fabric coating line” means a coating line in which -any

protective, decorative, or functional coating or

reinforcing material is applied on or impregnated into

a-textile fabric.

“Federally enforceable” means all limitations and

conditions which arc enforceable by the Administrator

including those requirements developed pursuant to 40

CFR Parts 60 and 617 requirements within any applicable

implementation plan; and any permit requirements

established pursuant to 40 CFR 52.21 or under

regulations approved pursuant to 40 CFR Part 51 Cubpart

I and 40 CFF( 51.166.

“Final repair coat”

moans the repainting of any topcoat

which is damaged during vehicle assembly.

“Firebox” means the chamber

or compartment of a boiler

or furnace in which materials are burned, but not the

combustion chamber or afterburner of an incinerator.

“Fixed-roof tank” means a cylindrical shell with a

permanently affixed roof.

“Flexographic printing” means the application of words,

designs, and pictures to a substrate by means of a roll

printing technique in which the pattern to be applied

is raised above the printing roll end the image carrier

is made of clastomeric materials.

“Flexogrophic printing line” means a printing line -in

which each roll printer uses a roll with raised areas

for applying an image such as words, designs, or

pictures to a substrate. The image carrier on the roll

is made of rubber or other clastomoric material.

“Floating roof” means a roof on a stationary tank,

reservoir, or other container which moves vertically

upon change in volume of the stored material.

‘

imaac

tO

“Four~t-h

plate to 

•~~Li1fltUI~~

of the non-image areas.

solution” moans the solution which 

i.c

applied

-warophilic proDerti~.

“Frecboar~Heigh~”

387

-nr~~a

a-~a.

P—S

tnc ui~i~.anee~rom the top of the vapor ~ono to the top

of the degrcascr tank. For cold cleaning dcgrcaocrs,

the distance from the solvent to the top of the

dcgrcaccr tank.

“Fuel combustion emission source” moans any furnace,

boiler, or similar equipment used for the primary

purpose of producing heat or power by indiroct heat

transfer.

“Fuel gas system” moans a system for collection of

refinery fuel gas including, but not limited to, piping

for collecting tail gas from various process units,

mixing drums and controls, and distribution piping.

“Cas service” moans that the component contains process

fluid that is in the gaseous state at operating

conditions.

“Cas/gas method” means -either of two methods for

determining capture which rely only on gas phase

mcasur-ements. The first method requires construction

of a temporary total enclosure (TTE) to ensure that all

would-bc fugitive emissions are measured. The second

method uses the building or room which houses the

facility as an enclosure. The second method requires

that all other VOl~sources within the room be shut down

while the

test 

performed, but all fans and blowers

within the room must be operated according to normal

procedures.

“-Casolinc” means any petroleum distillate

or petroleum

distillatejalc-ohol blend having a Reid vapor pressure

of 27.6 kfla or greater which is used as a fuel for

internal combustion engines.

“Gasoline dispensing facility” means any site where

gasoline is transferred

from a stationary storage tank

to a motor vehicle gasoline 

tank

used to provide fuel

to the engine 

-of

that motor vehicle.

ucrccn Tire Cpraying” means the spraying of green

tires, both inside and outside, with release compounds

which help remove air from the tire during molding and

prevent the tire from sticking to the mold after

curing.

“Creen Tires” moans assembled tires before molding and

curing have occurred.

“Cross vehicle weight” means the manufacturer’s gross

weight rating for the individual vehicle.

“Cross vehicle weight rating” means the value specified

by the manufacturer as the maximum design loaded wci~ht

of a single vehicle.

“Heated airless spray” moans an airless spray coating

method in which the coating is heated just prior to

application.

uHeatset~Imeans a class of web-offset lithography which

requires a heated dryer to solidify the printing inks.

“Heatset-web-offeet lithographic printing line” means a

lithographic printing line in which a blanket cylinder

is -used to transfer ink from a plate cylinder to a

substrate continuously fed from a roll or an extension

process and an oven is used to solidify the printing

inks.

“Hccw~-’ 1~r~n~r~”means 

14-niir~ ~J1-h r~ i~-nr

vanrir

nrcssur~

nf 1e--~~

3~Pa (0.04 psi) at 294.3°K(~°~+

established in a stanciard rcrorcncc text or as

determined by ACT!-! method D2879-86 (incorporated by

reference in Ccction 219.112); or which has 0.1 Reid

~‘~nor Prc~~urt~

a~ dc~termincd 

kETM 

mr~thod 

D323—B2

(incorpor’~~

wni.cn wncn distillcd rcquirco atcinperaturcof

421.95°K

(300°F) or greater to

as determined b’s-’ 

1~.ETM

recover

method

10 percent of the liquid

DE6-~2 (inoornorr~ted

by

“Heavy 

off-highway vehicle !~t5~

means, for the

~~L~U~3C

UI.

I..uDpurL r 

Ui.

LjIjJ

irL,

I1tUV~

OUfl~1..LUUI..iOfl,

mining, farming, 

-or

material handling equipment; heavy

industrial engines; diesel-electric locomotives and

associated power equipment; and the components of such

equipment or engines.

“Heavy off-highway vehicle products coating facility”

moans a facility that includes one or more heavy

off-highway vehicle products coating line(s).

-“Heavy off-highway vehicle products coating line” means

a coating line in which any protective, decorative, or

functional coating is applied onto the surface of heavy

off-highway vehicle products.

“HigL t.~

that is cc~ified to withstand

-(1000°F~for 24 hours.

388

-c

A-

—J

a 1

mim

~r~ating”means a

temDoratn~’

coati,i~

of

7..F~Qc

389

“Hood” means a partial enclosure or canopy for

capturing and exhausting, by means of a draft, the

organic vapors or other fumes rising from a coating

—~-ocess or other source-

“Hood capture efficiency” means the emissions from

process which are captured by the hood and directed

into a controi sevice, expresses as a percentage of all

emissions.

“Hot 

well” 

moans 

the reservoir of a oondencing unit

receiving the condensate from a barometric condonaer~.

“Hour” means a block period of 60 minutes (e.g., l~OOam

to 2~00am).

“In process tank” means a container used for mixing,

blending, heating, reacting, holding, crystallizing,

evaporating or cleaning operations in the manufacture

of pharmaceuticals.

“In situ Campling £yoteins” moans nonextractive samplers

or in-line samplers.

“In vacuum s-~-~ice”means

, for 

‘~

of

this Part, ~    

which i~ crat*~,at-

internal pr

C-S

IlL

c that is at least S kfla (0.73 

p~A-a-)-

- --

~‘~DODC 

Cubpart Q

10W

UIILL)ICII

“Incinerator” means a combustion apparatus in which

refuse 

is burned.

“Indirect heat transfer” means transfer of h-cat in such

a way that the source of heat does not come into direct

contact with process materials.

“Ink” means a coating used in printing, impressing, or

transferring an image onto a substrate.

“Inter~..,~

coat” 

---

..~,

-applied by

spray to the interior of

a can body.

-“-I-ntcrnal-floating roof” moans a cover or roof 

in

a

fixed-roof tank which

roots upon and is 

supported

by

the volatile organic liquid being contained and is

equipped with a closure seal or seals to close the

space between the roof edge and tank shell.

“Lacquers” means any clear unorl 

f

i~hr’, fwmii1atr~ii

with

390

nitrocellulose or synthetic resins to dry by

evaporation without chemical reaction, including clear

lacquer sanding scalers.

“Large appliance” means any residential and commorcial

washers, dryers, ranges, refrigerators, frec~oro, water

heaters, dishwashers, trash oompaotoro, air

conditioners, and other similar products.

“Large appliance coating” moans any coating appliod to

the component metal parts (including, but not limited

to, doors, oases, lids, panels, and interior support

parts) of residential and commercial washers, dryoro,

ranges, refrigerators, frecDcrs, water heaters,

dishwashers, trash compactors, air conditioners, and

other similar products.

“Large appliance coating facility” means a facility

that includes one or more large appliance coating

-line(s).

“Large appliance coating line” moans a coating line in

which any protective, decorative, or functional coating

is applied onto the-surface of large appliances.

“Light liquid” moans VON in the liquid state which is

not

defined as heavy liquid.

“Light—duty truck” means any motor vehicle rated at

3,850 kg gross vehicle weight or less, designed mainly

to transport property.

“Liquid/gas method” means either of two methods for

determining capture -which require both gas phase and

liquid phase measurements and analysis. The first

method requires construction of a TTE. The second

ffiethod uses the building or room which houses the

facility as an enclosure. The second method requires

that all other VON sources within the room be shut down

while the test is performed, but all fans and blowers

within the room must b-s operated according to normal

procedures.

“Liquid-Mounted Seal”

means a 

primary seal mounted in

continuous contact with the liquid between 

the tank

wall and the floating roof edge around the

circumference of the roof.

“Liquid service” means that the equipment or component

nt~ain~

nir~rr~~

fliii,i

ihat i~ 

in n ‘iquid state r~t

operating conditions.

391

“Liquids Dripping” means

seal including -spraying,

any

visible leaking from a

misting, clouding and

iso

formation.

line,

-ceosarily fed fr.....

l-~-printer 

uses—a

~-

“Magnet wire” means aluminum or copper wire formed into

an electromagnetic coil.

“Magnet wire coating” moans any coating or 

electrically

insulating varnish or enamel applied to magnet wire.

“Magnet wire coating facility” means a facility that

includes one or more magnet wire coating line(s).

“Magnet wire coating line” means a coating line in

which any protective, decorative, or functional coating

is applied onto the surface of a magnet wire.

“Malfunction” means any sudden and unavoidable failure

of air pollution control equipment, process equipment,

or a process to operate in a normal or usual manner.

Failures that arc caused entirely or in part by poor

maintenance, careless operation, or any other

preventable upset condition or preventable equipment

breakdown shall not be considered malfunctions.

“Manufacturing process” means a method whereby a

process emission source or series of process emission

sources is used to raw materials, feed stocks,

oubaoscinblics, or other components into a product,

either for sale or for usc as a component in a

subsequent manufacturing process.

-“Material Recovery Cection” means any equipment

designed to transport and recover otyrenc monomer and

other impurities from other products and by-products in

a polystyrene plant, including but not limited to the

styrcn? dcvolatiliccr unit and styrenc recovery unit.

“Maximum theoretical omissions” means the quantity -of

volatile organic material emissions that theoretically

—

orinti....

roil

esscn

except that the substrate is not

unwindL~ roll, irt—~i4~

“

both 

t’” 

4~,_

tiall”--

u~r

rti

,1u_’fI~

rInd 

non

iia~igcar~~

“r’~

,

in cne caine plane (planographic)

“Low Solvent Coating” moans a coating which containo

less organic solvent than the conventional coating-s

used by the industry. Low solvent coatings include

water-borne, higher solids, eleotro-dep-osition and

oowdcr coatings.

could be omitted by a stationary source before add-on

controls based on the design capacity or maximum

production capacity of the oouroe and 8760 hours per

year.

The design capacity or maximum production

capacity includes use of coating(s) or ink(s) with the

highest volatile organic material content actually used

in practice by the source. Provided, however, the

Agency shall, when appropriate, and upon request by the

permit applicant, limit the “maximum theoretical

emissions” of a source by the imposition of conditions

in a federally enforceable operating permit for eueh

source. Such conditions shall not be inconsistent with

requirement of the Clean Air Act, as amended, or 

any

applicable requirements established by the Board. Such

conditions shall be established in place of design

capacity or maximum production capacity in calculating

the “maximum theoretical emissions” for such source and

~p’-r

inr~1~~r~t-

cnnona 

M-hr~r things, 1-hr~

establishment~of

mater

elucti..,.. limitat 

limitat...

limitations, or limitations on the volatile organi-c

ial

..in..

operat~.on of 

any

u.. ~ou

nyu or ....~.u

-

.~..i

oiir~

emission source, or u 

UufflI~.IUL..I.U1i

of

nnv ciueh I imit~iti

on~.

e~

Production or capacity limitations shall be established

on basis of no longer than one month except in those

cases whore a limit spanning a longer period of time is

appropriate. In such cases, a rolling limit” shall be

employed. Any production or capacity limitations shall

be verified through appropriate recordkecping. (Board

Note: The UCEPA may deem operating permits which do

not conform to the operating permit program

requirements and the requirements of UCEPA’s underlying

regulations, including the requirement that limitations

be quantifiable and enforceable as a practical matter,

not “federally enforceable.”)

“Metal furniture” moans a furniture piece including,

but not limited to, tables, chairs, waste baskets,

beds, desks, lockers, benches, shelving, file cabinets-,-

lamps, and room dividers.

—-

r,ir-nitiirr

~

mr~r~nr~

nnv nnn—adhositr~

r~r

ma

as some

~_I I~1~

-~S

—I

~urni

.“1~e4:•~:1

~

a~.., •~licdto .a~y

any m-~’-~part which i...    will

metal, ,~ood, fabric, plas~

furniture piece including,

~

LJE~

t3r

-ti-ti_n

f~-W

n1m

—~

e1~elving, file aabincts, lamps, and room dividers.

This definition shall not apply to any coating line

coating miscellaneous metal parts or products.

392

—--4

-be-

led with

~

parts to f

but not limited to, tables-i

393

“Metal furniture coating facility”

that includes one or more metal fu:

line(s).

a facility

“Metal fur

niture coating line” means a coating line in

which any protective, decorative, or functional coating

is applied onto the surface of metal

furniture.

ItMetalijo

nho~-~~~,~r~1”

moans

r~

r~i- 

secondary

constructed of metal sheets (~hoco) which arc

joined together to form a ring, springs, or lever-s

which attach the -shoes to the floating roof and hold

thcehocsagain3tthctankwzlii, and a coated fabric

.‘

“-Miscellaneous fabricated

process” means:

or pr

involving one or more of

ons, including any drying

ons, and 

capable of

Asphalt solutions to paper or fiberboard

p ~mer or rc~t

Coatings 

—or dye to leather

cou~n”~

to n1.,~tjc

Coatings to rubber or glass

Disinfectant 

material to manufactured items

Plastic foam scrap or “fluff” from the

manufacture of foam containers and packaging

material to form resin palicts

—

Viscose solutions for food casings

The storage and handling of formulations

associated with the process described above, 

and

the use and handling of organic liquids and othe~

substances for clean—up operations acoosiatod with

fh~’ ~ocess described in this definition.

A manufacturing process

the following applicati

and curing of formulati

emitting VON:

394

~ation manui:aeturing proocco”

mcans

manuriwtiirinri

nrno~pswhich comDounas on

more p        

and is -cao~

VON:

Adhcs ivos

Asohalt solutions

...uu~..,,

sc~ants, 

or waterproofing ag

Coatings, other than paint and ink

Concrc.~

....~

-~‘

compoui

Dyes

rrloLlOn materials and

Resin -solutions

Rubber solutions

Viscose 

solutions

The storage and handling of formulations

associated with the process described above, and

the use and handling of organic liquids and other

substances for clean-up operations associated with

th~

rn~pcessdescribed in this   

“Miscellaneous metal parts or products” means any metal

part or metal product, even if attached to or combined

with a nonmetal part or product, except cans, coils,

metal furniture, large appliances, magnet wire,

automobiles, ships, and airplane bodies.

“Miscellaneous metal parts and products coating” means

any coating applied to any metal part or metal product,

oven if attached to or combined with a nonmetal part or

product, except cans, coils, metal furniture, large

appliances, and magnet wire. Primp coat, prime

surfacer coat, topcoat, and final repair c-oat for

automobiles and light-duty trucks are not miscellaneous

metal parts and products coatings. However, underbody

anti-chip (e.g., underbody plastisol) automobile and

light-duty truck coatings arc miscellaneous metal parts

and products coatings. Also, automobile or light-duty

truck refinishing coatings, coatings applied to the

exterior of marine vessels, coatings applied to the

~395

exterior of airplanes, and the eustoini~ed topooating—e~

automobiles and trucks if production is less than 3&

vehicles per day are not miscellaneous metal parts and

products coatings.

“Miscellaneous metal parts or products coating

facility” means a facility that includes one or more

miscellaneous metal parts or products coating lines.

“Misoellaneous metal parts or products coating line-”

means a coating line in which any protective,

decorative, or functional coating is applied onto the

surface of miscellaneous metal parts or products.

“Miscellaneous organic chemical manufacturing process”

means:

A manufacturing process which

chemical reaction, one or more of the following

organic compounds or mixtures of organic compounds

and which

is capable of emitting VOM:

Chemicals listed in Appendix A of this Part

Chlorinated and sulfonated compounds

Cosmetic, detergent, soap, or surf actant

intermediaries or specialties and products

Food additives

Oil and petroleum

Plasticizers

Resins or polymers

nuIJueL

~uuiLives

Cwec-ccncrs

Varnishes

The storage and handling of formulations

associated with the process described above and

the use and handling of organic liquids and

other

substances for clean-up operations associated 

with

the process described in this definition.

“Monitor” means to

396

“Multiple package coating” moons a coating made from

more than one different ingredient which must be

mixed

prior to using and has a limited pot life due to the

chemical reaction which

ooours 

upon mixing.

means“No

Detectablea

dischargeVolatileof volatileOrganicorganicMaterialmaterialEmissionsintott the

atmosphere as indicated by an instrument reading of

less than 500 ppm above background as determined in

accordance with 40 CFR 60.485(c).

means.

te-

and

•

Dueji-

e4~-i

sf a ~

cylinder to transfer ink

from the plate cylinder to the surface to be printed.

“Opaque stains” means all stains that are not

semi-transparent stains.

“Open top vapor dogroasing” means the batch process of

cleaning and removing soils from surfaces by condensing

hot solvent vapor on the colder metal parts.

“Open-ended valve” means any valve, except pressure

relief devices, having one side of the valve in contact

with process fluid and one side open to the atmosphere,

either directly or through open piping.

“Operator of-Casolinc Dispensing Facility” moans any

person who is the lessee of or operates, controls or

supervises a gasoline dispensing facility.

“Organic compoundt’ means any compound of carbon,

excluding carbon monoxide, carbon dioxide, carbonic

acid, metallic carbidga or carbonates, and ammonium

carbonate.

“Organic material” means any chemical compound of

carbon including diluonts and thinners which arc

liquids at standard conditions and which arc used as

dissolvers, viscosity reducers, or cleaning agents, but

excluding methane, carbon monoxide, carbon dioxide,

carbonic acid, metallic carbonic acid, metallie

carbide, metallic carbonates, and ammonium carbonate.

“organio vapor” moans the gaseous phase of an organ4e

material or a mixture of organic materials present ifi

the atmosphere.

“Oven” moans a cha~bcrwithin which heat is used for

one or more of the following purposes: dry, bake, cure,

or polymerize a coating or ink.

‘-.~

397

“Overall control” means the product of the 

capture

efficiency and the control device efficiency.

“Ovcrvarnish” means a transparent 

coating applied

directly over 

ink or coating.

~-

—~.7

crnc~ns

ULLL L

of Casoli

Facilit;-”

-    menn~

i’ho has l..~il or egi4

~&.1p

-~“~

~~lity

‘toi~ner

pcruan                    

L... ~Ofl3~7

storage

~init 

~ii~ ~ g.a~uL.Lnc

ui.upcnuJng

“Owner or operator” means any person who owns,

operates, leases, controls, or supervises an emission

source or air pollution control equipment.

“Packaging rotogravure printing” means rotogravure

printing upon paper, paper board, metal foil, plastic

film, and other substrates, which are, in subsequent

operations,

formed into packaging products or labels

for articles to be sold.

“Packaging rotogravure printing line” means a

rotogravure printing line in which surface coatings arc

applied to paper, paperboard, foil, film, or other

substrates which arc to be used to produce containers,

packaging products, or labels for articles.

“Paint manufacturing plant” means a plant that mixes,

blends, or compounds enamels, lacquers, scalers,

shellacs, stains, varnishes, or pigmented surface

coatings.

“Paper coating” means any coating applied on paper,

plastic film, or motallic foil to make certain

products, including (but not limited to) adhesive tapes

and labels, book covers, post cards, office copier

paper, drafting paper, or pressure sensitive tapes.

Paper coating includes the application of coatings by

impregnation and/or saturation.

“Paper coating facility” moans a facility that includes

one or more paper coating lines.

“Paper coating line” means a coating line in which any

protective, decorative, or functional coating is

applied on, saturated into, or impregnated into paper,

plastic film, or metallic foil to make certain

products, including (but not limited to) adhesive tapes

and labels, book covers, post cards, office copier

paper, drafting paper, and pressure sensitive tapes.

“Parts per million (volume)” moans a volume/volume

ratio which expresses the volumetric concentration of

398

gaseous air contaminant in a million unit volume of

gas.

“person” means any individual, corporation,

partnership, association, Ctatc, municipality,

political subdivision of a Ctatc; any agency,

department, -or instrumentality of the United Ctatco-j-

and

any officer, agent, or employee thereof.

“Petroleum” moons the crude oil removed from the earth

and the oils derived from tar sands, shale, and coal.

“Petroleum Liquid” moans orude oil, condensate or any

finished or intermediate product manufactured cit a

petroleum refinery, but not including Number 2 through

Number 6 fuel oils as specified in ACTM D 396-69, gas

turbine fuel oils ~1umbcrs2-CT through 

4 CT as

specified in 

A&PH

D-2880 7. or diesel fuel oils Numbers

2-D

and 4—D,

as specified in ACTM D—975 68.

“Petroleum refinery” means any facility engaged in

producing gasoline, kerosene, distillate fuel oils,

residual fuel oils, lubricants, or other products

through distillation of petroleum, or through

redistillation, cracking, or reforming of unfinished

petroleum —derivatives.

ru-il 

“~

m-~n~~

nrit~ r~r,mrtr,nr,,i r~r 

vi-iirr 

nthr~r

than food, used in the prcvention,diagnoc3is,

alleviation, treatment, or cure of disease in human and

animal.

“Pharmaceutical coating operation” means a device in

which a coating is applied to a pharmaceutical,

including air drying or curing of the coating.

-.~i--npt

mater

e~

TI+~

rn~ rn-

1~..

-i’-1rm~

wnenever

~-~-titucnt

---

-,~ ~

—.

percent of the total organic materials.

Reac~~

“-‘--“--‘-~‘‘~

ms~ri-~

any organi~

t~crccnt of

eeh 4e&

~y

~.

._ .

ial with 

.in

..~~egatcof more ~an 20

its total volume omp~ 

of the cl.......ical co~

~lasoified bel   

-~

ee~~

my

-of

t’” following ~Tdivi’~’

-l-imit~

matcral or 

~.., ~

any ,...~,...Ae

be classified from its chemical structure into more

than one of the above groups of organic materials it

shall 

be considered as a member of the most reactive

Rr,-,nri.. 

t-hr,+ 4—

i-’—

~‘-—i

tht~ 

l,-it

lntrp~j,~

.LLiOI

u.. wiii.ei.

nrnoun~

r’l’il’

pcrcefltage

composition

—-“-toohomicnuly 

vrrtr~i-ive

~‘terial 

may

——

—

aldehydes, esters, ethers or ketoncs navi-ng an

olefinic or cyclo-olefinic typos of unc3aturatiori~

399

5 percent. This definition does

not apply t

perohloroethylcnc or trichlorocthylcne.

A combination of aromatic compounds with eight

-or

more carbon atoms -to the molecule except

ethylbcnzenc: 8 percent.

A combination of cthylbcnzcnc, ketonco having

branched hydrocarbon structures or toluene: —2-G

percent.

“Pigmented coatings” moans opaque coatings containing

binders and colored pigments which arc formulcited—te

conceal the wood surface either as an undercoat or

topcoat.

~1 U ~

all of the pollutant ~

~ctivitics

;~Duping,

~jacent

-1~

~-1~ t

mr’~yi~t

.,

substzin

r~r ~

dded t

rr~

1 r~ri

I~.T11lfr

composition to soften and add flexibility

to the

product.

“Pneumatic Rubber Tire Manufacture” moans the

production of pneumatic rubber tires with a bead

diameter -up to but not including 20.0 inches and cross

section dimension up to 12.8 inches, but not including

specialty tires for -antique or other vehicles when

produced on equipment separate from normal production

lines for passenger or truck type tires.

“Polystyrene Plant” means any plant using styreno to

manufacture polystyrene resin.

“Polystyrene Resin” means substance consisting of

otyrono polymer and additives which is manufactured at

a polystyrene plant.

“-Pressure Release” means the emission of materials

resulting from system pressure being greater than oct

nrr~~mrr~

r~f thr

nr~~iir~

ri~1ir~f

it~t~.

“Plant”

which

—

__A_

—

it~i .i I

•

ILL

LQfl~ LU

LI1~

L~UUC

£1LUU.31~~L

1.11

1-rHL;Irr~r,

-lr, r~n~-~r~- 

~-~-•  

contic~uou~

nr-

nr~

~r~~jp5,

and arc under the contro~.

pcrDon ~or persons uneer common contro...,, except th~.

activities of any marine vessel. Pollutant-emitting

activities shall be considered as part of the same

industrial grouping if they belong to the same “Major

Croup” (i.e., which have the caine two-digit code) as

described in the “Standard Industrial Classification

Manual, 1987” (incorporated by reference in Cection

219.112).

400

“Pressure Tank” 

means a

tank in which fluids are stored

at a pressure greater than atmospheric pressure.

“Prime coat” means the first of two or more coatings

applied to a ourface.

“Prime surfacer goat” moans a coating used to touch up

areas on the surface of automobile or .i-ght-duty truek

bodies not adequately covered by the prime coat before

application of the top coat. The prime surfacer pocit

is applied between the prime coat and topcoat. An

anti-chip coating applied to main body parts (e.g.,

rocker panels, bottom of doors and fenders, and loading

edge of roof) is a prime surfacer goat.

“Primers” moans any coatings formulated and applied to

substrates to provide a firm bond between the substrate

and subsequent coats.

“Printing” means the application of words, designs, and

pictures to a substrate using ink.

“-Printing line” means an operation consisting of a

series of one or more roll printers and any associated

roll coaters, drying areas, and ovens wherein one or

more coatings are applied, dried, and/-or cured.

“Process” means any stationary emission source other

than a fuel combustion emission source or an

incinerator.

“Process Unit” means components assembled to produce,

go intermediate or final products, one or more of the

chemicals listed in 35 Ill. Adm. Code 219 Appendix A.

A process unit can operate indcpcncicnt.iy

it

suppiica

with sufficient feed or raw materials and sufficient

storage facilities for the product.

“Process Unit Shutdown” means a work practice or

operational procedure that stops production from a

process

....~.....

~ part of a process unit.

An unscheduled

work practice or operational procedure that stops

production from a process unit or part of a process

tmit for less than 24 hours is not a process unit

shutdown. The use of spare components and technically

-f-ecisible bypassing of components without stopping

production is not a process unit shutdown.

“Production equipment exhaust system” means a system

for collecting and directing into the atmosphere

omissions of volatile organic material from reactors-,

centrifuges, and other process emission sources.

401

~

“Purged Process Fluid” means liquid or vapor from a

process unit that contains volatile organic material

and that results from

line(s) of a process

flush.~.~

unit so that an

the sanipL..

uncontaminated

sample may 

then be taken for testing or analysis.

“Reactor” means a vat, vessel, or other device in which

chemical reactions take place.

“Reasonably Available Control Technology (~CT)” means

the lowest emission limitation that 

an emission source

is capable of meeting by the application of control

technology that is reasonably available considering

technological and economic feasibility.

“Refiner” means any person who owns, leases, operates,

controls, or supervises a refinery.

“Refinery Fuel Cas” means any gas which is generated by

a petroleum refinery process unit and which is

combusted at the refinery, including any gaseous

mixture of natural gas and fuel gas.

“Refinery unit, process unit or unit” means a

set of

components which arc a part of a basic process

operation such

as distillation, hydrotreating,

cracking, or reforming of hydrocarbons.

“Refrigerated condenser” means

ci

surface condenser in

which the coolant supplied to the condenser has been

cooled by a mechanical device, other than by a cooling

tower or evaporative spray cooling, ouch as

refrigeration unit or steam chiller unit.

“Reid vapor pressure” means the standardi~cdmeasure of

the vapor pressure of a liquid in pounds per square

inch absolute (Psia) at 100°F (37.0°C).

“Repair coatings” means coatings used to correct

imperfections or damage to furniture surface.

“Repaired 

“

,  ~or th....

..S.c

Q pf

Part, that 

equipment componont has been adjusted, or

..ij-c

material.

roLogravuro prJ.ntLng .~ino 

WIiJ.UII

ucJa~1ngs are app~.icu

to paper which is subsequently formed into books,

magacines, catalogues, brochures, directories,

newsoaner supplements, or other types of printed

402

“Residual Fuel Oil” moans fuel oils of grade No. 4, &

and 6 as specified in detailed requirements for

fu~e-~

oils A.C.T.H. D 396—69 (1971).

“Retail Outlet” means any gasoline dispensing facility

at which gasoline is sold or offered for sale for use

in motor vehicles.

“Roll coatcr” means an apparatus in which a uniform

layer of coating is applied by means of one or more

rolls across the entire width of a moving substrate-i-

“Roll printer” means an apparatus used in the

application of words, designs, and pictures to a

substrate, usually by means of one or more rolls each

with only -partial coverage.

“Roll printing” means the application of words,

designs, and pictures to a substrate usually by means

o~ a series of hard rubber or metal rolls each with

only partial coverage.

“Roller coating” means a method of applying a coating

to ~ ~hr~t~t rr ~trir~ 

in tyhic~h

th~c~p~tint~ii~ trr~nr~fcrred

—J

—

——--~

~)(C~O-t~,j

~111 ~1fi

Flu .1 J

I I rn I t I (3 ~I I 1L. (311 .1

LJ.1 L~.

-Il

most

a month monthly basis; that is, for example, a monthly

production or capacity level must be determined for

each parameter subject to a production or -capacity

limitation and added to the eleven prior monthly levels

for monthly comparison with the annual limit.

“Rotogravure printing” means the application of words,

designs, and pictures to a oubstrate 

by means of a roll

~——.

~~—~-~-•.•“—

.~_____________________________________________________

...n which

th~_

to be applied

is recessed relative to the non-image area.

“Rotogra

wh~ich

for

cacn

“Safety relief valve” means a valve which is normally

closed and which is designed to open in order to

relieve 

excessive pressures within a vessel or pipe.

“Sanding scalers” moans any

bare wood for san

coatings

ding

,rui

formulated for and

.~,..lied

1r~ ~ir’n1

thr~ unnr~

for sub..~uentapplicati~. of varnish ~e ~

considered a sanding scaler a coating must be clearly

-r-~

“Rolling limit” means that a limit or limitation must

fiet-          

—-

—

—

—,

—

—— — ~

printing line” means a printing

roll ,,~inter   

roll 

~msgc   

to a suI3trat~.

-I—

—

I S

—

403

“Sealer” moans a coating containing binders which seals

wood prior to the application of the subsequent

coatings.

“~cnsor”means a device that measures a physical

quantity or-the change in a physical quantity ouch as

temperature, pressure,

flow 

rate, pH, or liquid level--

“Semi—transparent stains” means stains containing dyes

or semi—transparent pigments which arc formulated to

enhance wood grain and change the color of the surface

but not to conceal the surface, including, but not 

limited to, sap stain, toner, non grain raising stains-,

pad stain, or spatter stain.

“sot of safety

relief valves” means one or more safety

rc~iii~f

v~1vc~s~ic~sianc~d

to

open in order 

relieve

-—

-

“Sheet bcisecocitt~ means a cacti

the metal is in sheet form to

ng applied to metal

serve as either the

when

exterior or interior of a can

three-piece cans.

for

either two-piece or

“Side-scam spray coat” means a coating applied to

seam of a three-piece can.

the

“-Cingle coat” means one coating application applied to

a -metal surface.

“Solvent” means a liquid substance that is used to

dissolve 

or dilute another substance.

“Solvent cleaning” means the process of cleaning soils

from surfaces by cold cleaning, open top vapor

degreasing, or convcyoriccd dcgreasing.

“Specified air contaminant” means any air contaminant

as to which this 

Part contains

emission standards or

other specific limitations.

“Splash loading” means a method of loading a tank,

r-ailroad tank -car, tank truck, -or trailer by usc of

other 

than 

ci submerged loading pipe.

“Stack” means a flue or conduit, free-standing or with

exhaust port above the roof of the building on which—i-~

is mounted, by which air contaminants arc emitted into

the atmosphere.

“Standard conditions” means a temperature 

-of

70°Fand a

pressure of

14.7 psia.

404

“Standard cubic foot (scf)” moans the volume of one

cubic foot of gas at standard conditions.

“Standard Industrial Classification Manual” moans the

Standard Industrial Classification Manual (1987),

Superintendent of Documents, U.S. Covcrnment Printing

Office, Washington, DC 20402 (incorporated by refereries

in Section 219.112).

the setting

~  nurpi

“Stationary emission source” mean an emission source

which is not self—propelled.

“Storage tank or storage vessel” means any stationary

tank, reservoir or container used for the storage of

VOL.

“Ctyrcne Dcvolatilizcr Unit” means equipment performing

the function of separating unreacted styrene monomer

and other volatile components from polystyrene in a

vacuum devolatilizer.

“Ctyrcnc Recovery Unit” means equipment performing the

function of separating styrcnc monomer from other less

volatile components of -the styrenc dcvolatilizcr unit’s

output. The separated styrenc monomer 

reused as

a raw material in the polystyrene plant.

“Submerged loading pipe” means any discharge pipe or

nozzle which meets either of the following conditions:

Where the tank is filled from the top, the end of

the discharge pipe or noccle must be totally

submerged when the liquid level is 15 cm (6 in.)

above the bottom of the tank.

Where the tank is filled from the side, the

discharge pipe or nozzle must be totally submerged

when the liquid level is 46 cm (18 in.) above the

bottom of the tank.

“Substrate” means the surface onto which a coating is

applied or into which a coating is impregnated.

“Surface condenser” means a device which removes a

substance from a gas stream by reducing the temperature

of the stream, without direct contact between the

coolant and the stream.

--—--

—

—--—

—

——s---——

--—--—--~

final

~

..c

ê-~-~

polymers listed 

1~3

lilA. Code 219 Appendix A.

“Tablet coating operation” means a pharmaceutical

coating operation in which tablets arc coated.

“Thirty day rolling average” means any value

arithmetically averaged over any conscoutive

thirty-days.

“Three—piece can” means a can which is made from a

rectangular sheet and two circular ends.

“Topcoat” ~cans a coating applied

in a multiple coat

opL...uLion u~.ii~r

...i~Iii

UU~L,

i..a.flU~.

rcpui.L- COat,

prime surfacer coat.

“Topcoat operation” means

all topcoat spray booths,

flash-off areas, and bake ovens at a facility which are

used to apply, dry, or cure the final coatings (except

final off—line repair) on components of automobile or

light-duty truck bodies.

“Transfer efficiency” means the ratio of

the amount of

coating solids

deposited onto a part or product to the

total amount of coating solids used.

“Tread End Cementing” means the application of a

solvent-based cement to the tire tread ends.

“True vapor pressure” means the equilibrium partial

pressure exerted by ci volatile organic liquid as

determined in accordance with methods described in

American Petroleum Institute Bulletin 2517,

“Evaporation Loss From Floating Roof Tanks,” second

edition, February 1980 (incorporated by reference -&-n

Section 219.112).

“Turnaround” moans the procedure of shutting down an

operating refinery unit, emptying gaseous and liquid

contents to do insooction. maintenance and repair work,

g the unit back into pr

_l_.

cat.

~iiui.iow oup 

and

q........g7Tca

requires

~caa.

was

acaaa

only one

a. ca

~a.I.

~.a

n a. a. a. ..,ai. ~a

end to be

attached.

“Undcrcoatcrs” means any coatings formulated for and

i~no1iod to rnth~tr~itosto 

nrovido

~ rnnooth surface for

405

s1_

a____1_

,..t_!...~...I

——

I-

- —.

-

a--—-

—

406

4---

A_ 1~

..~

application of a

dersido of a tire

tread-

nron  

r~ cm r

cxcco’-

F_~crt~  

~_~lled

highway,   

...ing a device       

--~

—J

power or used exclusively upon stationary rails or

tracks.

Unregulated safety relief valve” means a safety rcli-ef

valve which cannot be actuated by a means other than

high pressure in the pipe or vessel which it protects-i-

“Vacuum producing system” means any reciprocating,

rotary, or centrifugal blower or compressor or any jet

ejector or device that creates suction from a prosoure

below 

atmospheric and discharges against a greater

pressure.

“Valves not externally regulated” means valves that

have no external controls, such as in—line check

valves.

“Vapor balance system” means any combination of pipes

er hoses which creates a closed system between the

vapor spaces of an unloading tank and a receiving tank

such that vapors displaced from the receiving tank arc

transferred to the tank being unloaded.

“Vapor collection system” means all piping, seals,

hoses, connections, pressure-vacuum vents, and other

possible sources between the gasoline delivery vessel

and the vapor processing unit and/or the storage tanks

and vapor holder.

“Vapor control system” means any system that limits or

prevents release to the atmosphere of organic material

in the vapors displaced from a tank during the transfer

of gasoline.

“Vapor-Mounted Primary Seal” means a -primary seal

mounted with an air space bounded by the bottom of the

primary seal, the tank wall, the liquid surface and the

floating roof.

“Vapor recovery system” means a vapor gathering system

capable of collecting all VON vapors and -gases

discharged from the storage tank and a vapor disposal

system capable of processing such VON vapors and gases

so as to prevent their emission to the atmosphere.

~Vchicle” means ci device by which any person or

moved, or drawn upon

~yr~1n~-’!Jr~1tr~ human

~iatcd 

~...

wat~a., any ~

4-locculation tank or 

a clarifi..~, which

petroleum derived compounds from waste water.

“Web” moans a substrate which

is printed in continuous

roll—fed presses.

“Wood furniture” means room furnishings including

cabinets (kitchen, bath, and vanity), tables, ohairs,

beds, sofas, shutters, art objects, wood paneling, wood

flooring, and any other coated furnishings made of

wood, wood composition, or fabricated wood material-s--

“Wood furniture àoating facility” means a facility that

includes one or more wood furniture coating line(s)-.-

“Wood furniture coating line” means a coating line-&R

which any protective, decorative, or functional coating

is applied onto wood furniture.

407

“Vinyl coating”

~2i

appiica to viny.., coated fabric or vinylshoo.s.Viny1~

coating dccc not include plastisols.

“Vinyl coating facility” moans a facility that includes

one or more vinyl coating line(s).

“Vinyl coating line” means a coating line in which any

protective, decorative or functional coating is applied

onto vinyl coated fabric or vinyl sheets.

“Volatile organic liquid (VOL)” means any substance

which is liquid at storage conditions and which

oontains volatile organic compounds.

“Volatile organic material (VON) or volatile organic

compound (VOC)” means “volatile organic material (VON)

or volatile

organic compound (VOC)”, as that term is

defined in 35 Ill. Adrn. Code Part 211.

“Volatile Petroleum Liquid” means

any petroleum liquid

with a true vapor pressure that is greater than 1.5

psia (78 millimeters of mercury) at standard

conditions.

“Wash coat” means a coating containing binders which

seals wood surfaces, prevents undesired staining, and

controls penetration.

“Wastcwatcr (Oil/Water) Separator” means any device or

piece of equipment which utilizes the difference in

rir.n’~ify

hr’t’ur’r’n oil 

~-inii unti-”r to

rr~movr oil nr~t’i

~. ~-,  

sucn

ca —

408

“Woodworking” means tne shaping, sawing, grinding,

smooi-~ninn~noiisning, and ~mrikin~~into oroducts of -any

form or shape of wood.

The definitions of 35 Ill. Adrn. Code 211 apply to this Part.

(Source: Amended at  

Ill. Reg.    

,

effective

__________

Section 219.105  

Test Methods and Procedures

a)  Coatings, Inks and Fountain Solutions

The following test methods and procedures shall be used

to determine compliance of ~ applied coatings, inks,

and fountain solutions with the limitations set forth

in this Part.

1)  Sampling: Samples collected for analyses shall be

one—liter taken into a one—liter container at a

location and time such that the sample will be

representative of the coating as applied (i.e.,

the sample shall include any dilution solvent or

other VON added during the manufacturing process).

The container must 

be tightly sealed inunediately

after the sample is taken. Any solvent or other

VON added after the sample is taken must be

measured and accounted for in the calculations in

subsection (a) (3) of this Section. 

For multiple

package coatings, separate samples of each

component shall be obtained. A mixed sample shall

not be obtained as it will cure in the container.

Sampling procedures shall follow the guidelines

presented in:

A)  ASTM D3925—8l(1985) standard practice for

sampling liquid paints and related pigment

coating. This practice is incorporated by

reference in Section 219.112 of this Part.

B)  ASTM E300-86 standard practice for sampling

industrial chemicals. This practice is

incorporated by reference in Section 219.112

of this Part.

2)  Analyses: The applicable analytical methods

specified below shall be used to determine the

composition of coatings, inks, or fountain

solutions as applied.

Method 24 of 40 CFR 60, Appendix A,

incorporated by reference in Section 219.112

409

of this Part, shall be used to determine the

VON content and density of coatings.

If it

is demonstrated to the satisfaction of the

Agency and the

TJSEPA 

that plant coating

formulation data are equivalent to Method 24

results, formulation data may be used. In

the event of any inconsistency between a

Method 24 test and a facility’s formulation

data, the Method 24 test will govern.

B)  Method 24A of 40 CFR Part 60, Appendix A,

incorporated by reference in Section 219.112,

shall be used to determine the VON content

and density of rotogravure printing inks and

related coatings. If it is demonstrated to

the satisfaction of the Agency and USEPA that

the plant coating formulation data are

equivalent to Method 24A results, formulation

data may be used. In the event of any

inconsistency between a Method 24A test and a

facility’s formulation data, the •Method 24A

test will govern.

C)  The following ASTM methods are the analytical

procedures for determining VON:

I)  ASTM D1475-85: Standard test method for

density of paint, varnish, lacquer and

related products. This test method is

incorporated by reference in Section

219.112 of this Part.

ii) ASTM D2369-87: Standard test method for

volatile content of a coating. This test

method is incorporated by reference in

Section 219.112 of this Part.

iii) ASTM D3792-86: Standard test method for

water content of water—reducible paints

by direct injection into a gas

chromatograph. This test method is

incorporated by reference in Section

219.112 of this Part.

iv) ASTM D4017—8l(1987): Standard test

method for water content in paints and

paint materials by the Karl Fischer

method. This test method is incorporated

by reference in Section 219.112 of this

Part.

410

v)  ASTM D4457-85: Standard test method for

determination of dichloromethane and

1,1,1, trichloroethane in paints and

coatings by direct injection into a gas

chroxnatograph. (The procedure

delineated above can be used to develop

protocols for any compounds specifically

exempted from the definition of VON.)

This test method is incorporated by

reference in Section 219.112 of this

Part.

vi) ASTM D2697—86: Standard test method for

volume non-volatile matter in clear or

pigmented coatings. This test method is

incorporated by reference in Section

219.112 of this Part.  

vii) ASTM D3980—87: Standard practice for

interlaboratory testing of paint and

related materials. This practice is

incorporated

by reference in Section

219.112 of this Part.

viii)  

ASTM E180-85: Standard practice for

determining the precision data of ASTM

methods for analysis of and testing of

industrial chemicals. This practice is

incorporated by reference in Section 219.112

of this Part.

ix)

ASTN D2372-85: Standard method of

separation

of vehicle from

solvent-reducible paints. This method is

incorporated by reference in Section

219.112 of this Part.

-D)  Use of an adaptation to any of the analytical

methods specified in subsections (a) (2) (A),

(B), and (C) of this Section may not be used

unless approved by the Agency and USEPA. An

owner or operator must submit sufficient

documentation for the Agency and USEPA 

find that the analytical methods specified in

subsections (a) (2) (A), (B), and (C) of this

Section will yield inaccurate results and

that the proposed adaptation is appropriate.

Calculations:

Calculations for determining the

VOM content, water content and the content of any

compounds which are specifically exempted from the

411

definition of VOM of coatings, inks and

fountain

solutions as applied shall follow the guidance

provided in the following documents-~-~

A)  “A Guide for Surface Coating Calculation”,

EPA-340/1-86-016, incorporated by reference

in Section 219.112 of this Part.

B)  “Procedures for Certifying Quantity of

Volatile Organic Compounds Emitted by Paint,

Ink and Other Coatings” (revised June 1986),

EPA-450/3-84-019, incorporated by reference

in Section 219.112 of this Part.

C)  “A Guide for Graphic Arts Calculations”,

August 1988, EPA-340/1—88-003, incorporated

by reference

in Section 219.112 of this Part.

b)  Automobile or Light-Duty Truck Test Protocol

The protocol for testing, including determining

the transfer efficiencyT of coating applicators~

at primer surfacer operations and topcoat coating

operations at an automobile or light-duty truck

assembly facility source shall follow the

procedure in: “Protocol for Determining the Daily

Volatile Organic Compound Emission Rate of

Automobile and Light-Duty Truck Topcoat

Operations” (“topcoat protocol”), December 1988,

EPA-450/3—88-018, incorporated by reference in

Section 219.112 of this Part.

21

Prior to testing pursuant to the topcoat protocol.

the owner or operator of a coating operation

subleet to the topcoat or primer surfacer limit in

Sections 219.204(a~ (2) or 219.204 (a) (3) shall

submit a detailed testing proposal specifying the.

method by which testing will be conducted and how-

compliance will be demonstrated consistent with

the topcoat protocol. The proposal shall include,,

at a minimum, a comprehensive plan (including a

rationale) for determining the transfer efficiency

at each booth throu~h the use of in-plant or pilot

testing, the selection of coatings to be tested

(for the purpose of determining transfer

efficiency) including the rationale for coating

groupings, the method for determining the analytic

VOM content of as applied coatings and the

formulation solvent content of as applied

coatings, and a description of the records of

412

coating VON content as applied and coating’s usal,

which will be kept to demonstrate compliance.

UPon approval of the proposal by the Agency and

USEPA. the compliance demonstration for a coating

line may proceed.

C)

Capture 

System Efficiency Test Protocols

1)  Applicability

The requirements of subsection (c) (2) of this

Section shall apply to all VON emitting processes

emission units employing capture equipment (e.g.,

hoods, ducts), except those cases noted below.

A)  If a source installean emission unit is

eguipped with (or uses) a permanent total

enclosure (PTE) that meets Agency and USEPA

specifications, and which directs all VON to

a control device, then the sourceeinission

unit is exempted from the requirements

described in subsection

(C)

(2) of this

Section. The Agency

and USEPA specifications

to determine whether a structure is

considered a PTE are given in Procedure T of

Appendix B of this Part. In this instance,

the capture efficiency is assumed to be ioc~

percent and the sourceemission unit is sti1~.

required to measure control

efficiency using

appropriate test methods as specified in

subsection (d) of this Section.

B)  If a source usesan emission unit is equipped

with (or uses) a control device designed to

collect and recover VON (e.g., carbon

adsorber), an explicit measurement of capture

efficiency is not necessary provided that the

conditions given below are met. The overall

control of the system can be determined by

directly comparing the input liquid VON to

the recovered liquid VON. The general

procedure for use in this situation is given

in 40 CFR 60.433, incorporated by reference

in Section 219.112 of this Part, with the

following additional restrictions:

i)  ‘inc source mus-c ~c aiic co 

r’rn1~te

usage witn soivent recovery on a

24—hour (daily) ba3is, rather than—a

30-day weighted average, within 72 hours

following the 24-hour period. In

addition, one of the following 

two

413

criteria must be met: The source owner

or operator shall obtain data each

operating day for the solvent usage and

solvent recovery to permit the

determination of the solvent recovery

efficiency of the system each operating

day using a 7-day rolling period. The

recovery efficiency for each operating

day is-computed as the ratio of the

total recovered solvent for that day and

the most recent prior 6 operating days

to the total solvent usage for the same

7-day_period used for the recovered

solvent, rather than a 30-day weighted

average as given in 40 CFR 60.433

incorporated by reference in Section

219.112 of this Part. This ratio shall

be expressed as a percentage. The ratio

shall be computed within 72 hours

following each 7—day period. A source

that believes that the 7—day rolling

period is not appropriate may use an

alternative multi-day rolling period not

to exceed 30 days, with the approval of

the Agency and USEPA. In addition, the

criteria in subsection (c) (1) (B) (ii) or

subsection (c) (1) (B) (iii) below must be

met.

ii) The solvent recovery system (i.e.,

capture and control system) must be

dedicated to a single coating line,

printing line, or other discrete

activity that by itself is subiect to an

applicable VON emission standard,

process line (e.g., one process line

venting to a carbon adsorbcr system), or

iii) If the solvent recovery system controls

more than one coating line, printing

line or other discrete activity that by

itself is subiect to an applicable VON

emission standard, the overall control

(i.e. the total recovered VON divided by

the sum of liquid VON input from all

lines and other activities venting to

the control system). must meet or exceed

the most stringent standard applicable

to any line or other discrete activity

venting to the control systern.multiple

process lines, then the source must be

able to demonstrate that the overall

414

~ntrol (i.o.,the total r

solvent VON divided by the sum of ~4qu4~

VON

input to all process lines venting

to the con..~...... system) meets or o~cce4-~

the most stringent standard applicable

for any process line venting to #4~e

control system.

Specific Requirements

The capture efficiency of a process 1inc~~

emission unit shall be measured using one of the

four protocols given below. Any error margin

associated with a test protocol may not be

incorporated into the results of a capture

efficiency test. If these techniques are not

suitable for a particular process, then the source

may use an alternative capture efficiency protocol

may be used, provided that the alternative

protocol is approved by the Agency and approved by

the USEPA as a SIP revision.

A)  Gas/gas method using temporary total

enclosure (TTE).

The Agency and USEPA

specifications to determine whether a

temporary enclosure is considered a TTE are

given in Procedure T of Appendix B of this

Part. The capture efficiency equation to be

used for this protocol is:

CE

—

Gw/(Gw + Fw)

where:

CE

=

capture efficiency, decimal

fraction,j

Gw

mass of VON captured and delivered

to control device using a TTE~

Fw

=

mass of fugitive VON that escapes

from a TTE~

Procedure G.2 contained in Appendix B of this

Part is used to obtain Gw. Procedure F.l in

Appendix B of this Part is used to obtain Fw.

B)  Liquid/gas method using TTE. The Agency and

USEPA specifications to determine whether a

temporary enclosure is considered a TTE are

given in Procedure T

of Appendix B of this

415

Part. The capture efficiency equation to be

used for this protocol is:

CE

=

(L

Fw)/L

where:

CE

=

capture efficiency, decimal

fract ion~

L

mass of liquid VON input to process

emission unit

Fw

=

mass of fugitive VON that escapes

from a TTE~

Procedure L contained in Appendix B of this

Part is used to obtain L. Procedure F.1 in

Appendix B of this Part is used to obtain Fw.

C)  Gas/gas method using the building or room

(building or room enclosure),. in which the

affected coating line, printing line or other

sourceelnission unit is located~as the

enclosure and in which “F” and “G” are

measured while operating only the affected

line or facilityemission unit. All fans and

blowers in the building or room must be

operated as they would under normal

production. The capture efficiency equation

to be used for this protocol is:

CE

= G/(G

+ FB)

where:

CE

capture efficiency, decimal

fra ct i onj,

G

mass of VON captured and delivered

to control device~

FB  =  mass 

of fugitive

VON that escapes

from building enc1osure~

Procedure G.2

contained in Appendix B of this

Part is used to obtain G. Procedure F.2 in

Appendix B of this Part is used to obtain FB.

D)  Liquid/gas method using the building or room

(building or room enc1osure)~ in which the

416

affected coating line, printing line or oth?1

courceeinission unit is located,~as the

enclosure and in which “F” and “L” are

measured while operating only the affected

line facility emission unit. All fans and

blowers in the building or room must be

operated as they would under normal

production. The capture efficiency equation

to be used for this protocol is:

=

(L

FB)/L

where:

=

capture efficiency, decimal

fract ionj.,

L

=

mass of liquid VON input to process

emission unit

=

mass of fugitive VOM that escapes

from building enc1osure~

Procedure L contained in Appendix B of this

Part is used to obtain L. Procedure F.2 in

Appendix

B of this Part is used to obtain FB.

3)  Recordkeeping and Reporting

All affected faciliticoowners or

operator

affected by this subsection must maintain a

copy of the capture efficiency protocol

submitted to the Agency and the USEPA on

file. All results of the appropriate test

methods and capture efficiency protocols must

be reported to the Agency within sixty (60)

days of the test date. A copy of the results

must be kept on file with the source for a

period of three (3) years.

B)  If any changes are made to capture or control

equipment, then the source is required to

notify the Agency and the USEPA of these

changes and a new test may be required by the

Agency or the USEPA.

C)  The source must notify the Agency 30 days

prior to performing any capture efficiency or

control test. At that time, the source must

notify the Agency which capture efficiency

417

protocol and control device test methods will

be used.

D)  Sources utilizing a PTE must demonstrate that

this enclosure meets the requirement given in

Procedure T (in Appendix B of this Part) for

a PTE during any testing of their control

device.

E)  Sources utilizing a TTE must demonstrate that

their TTE meets the requirements given in

Procedure T (in Appendix B of this Part) for

a TTE during testing of their control device.

The source must also provide documentation

that the quality assurance criteria for a TTE

have been achieved.

d)  Control Device Efficiency Testing and Monitoring

1)  The control device efficiency shall be determined

by simultaneously measuring the inlet and outlet

gas phase VON concentrations and gas volumetric

flow rates in accordance

with the gas phase test

methods specified in subsection (f) of this

Section.

Any owner or operator~

~j. ~That uses an afterburner or carbon adsorber

to comply with any Section of this Part ZU

shall use Agency and USEPA approved

continuous monitoring equipment which is

installed, calibrated, maintained, and

operated according to vendor specifications

at all times the afterburner or carbon

adsorber is in use except as provided in

subsection (d) (3) of this Section. The

continuous monitoring equipment must monitor

the following parameters:

h-)-   

For each afterburner which does not have

a catalyst bed, the ~coinbustion chamber

temperature of each afterburner.

jJJ. For each 

afterburner

which has a

catalyst bed, commonly known as a

catalytic afterburner,

the ~emperature

rise across each catalytic afterburner

bed or VON concentration of exhaust.

418

G)-  iii) For each carbon adsorber, ~he VON

concentration of each carbon adsorption

bed exhaust or the exhaust of the bed

next in sequence to be desorbed.

~j, Of an automobile or light-duty truck Drimer

surfacer operation or topcoat operation

subject to subsection (d) (2) (A~ above, shall

keep a separate record of the followina data

for the control devices, unless alternative

provisions are set forth in a permit pursuant

to Title V of the Clean Air Act:

,jj  For thermal afterburners for which

combustion chamber temPerature is

monitored, all 3—hour periods of

operation in which the average

combustion temperature was more than

28°C (50°F) below the average combustion

temPerature measured during the

most

recent performance test that

demonstrated that the operation was in

compliance.

jjj, For catalytic afterburners for which

temPerature rise is monitored, all

3-hour periods of operation in which th~

average aps temperature before the

catalyst bed is more than 28°C (50°F)

below the average gpg temperature

immediately before the catalYst bed

measured during the most recent

Performance test that demonstrated that

the operation was in compliance.

iii) For catalytic afterburners and carbon

adsorbers for which VOM concentration is

monitored, all 3—hour periods of

operation during which the average VON

concentration or the reading of organics

in_the exhaust gases j~more than 20

Percent areater than the average exhaust

aas concentration or reading measured bi

the organic monitoring device during the

most recent determination of the

recovery efficiency of a carbon adsorbe~

or performance test for a catalytic

afterburner, which determination or 

that demonstrated that the operation w~

in compliance.

419

An owner or operator that uses a carbon adsorber

to comply with 

Section

219.401 of this Part maY

oPerate the adsorber during periods of monitorinQ~

equipment malfunction. provided that:

~  The owner or operator notifies in writina the

A~encvand USEPA, within 10 days after the

conclusion of any 72 hour period durina which

the adsorber is operated and the associated

monitoring equipment is not operational, of

such monitoring equipment failure and

provides the duration of the malfunction. a

description of the repairs made to the

equipment, and the total to date of all hours

in the calendar Year during which the

adsorber was operated and the associated

monitoring equipment was not operational

~j. During such period of malfunction the

adsorber is operated using timed sequences as

the basis for periodic regeneration pf 

the

adsorber

~j The period of such adsorber operation does

not exceed 360 hours in anY calendar year

without the a~~rovalof the Aaencv and USEPA

and

The total of all hours in the calendar year

during which the adsorber was oPerated and

the associated monitoring equipment was not

operational shall be reported, in writing, to

the Agency and USEPA by JanuarY 31st of the

following calendar year.

e)  Overall Efficiency

The overall efficiency of the emission control

system shall be determined as the product of the

capture system efficiency and the control device

efficiency or by the liquid/liquid test protocol

as specified in 40 CFR 60.433, incorporated by

reference in Section 219.112 of this Part, (and

revised by subsection (c) (1) (B) of this Section)

for each solvent recovery system. In those cases

in which the overall efficiency is being

determined for an entire line, the capture

efficiency used to calculate the product of the

capture and control efficiency is the total

capture efficiency over the entire line.

420

2)  For coating lines which are both chosen by the

owner or operator to comply with Section

219.207(a), (d), (e), (f), or (g) of this Part by

the alternative in Section 219.207(b) (2) of this

Part and meet the criteria allowing them to comply

with Section 219.207 instead of Section 219.204 Q~.

this Part, the overall efficiency of the capture

system and control device, as determined by the

test methods and procedures specified in

subsections (c), (d) and (e) (1) of this Section,

shall be no less than the equivalent overall

efficiency which shall be calculated by the

following equation:

E

(VOMa 

VON1 /VOMa) x 100

where:

E

=

Equivalent overall efficiency of the

capture system and control device as a

percentage-,-j

VON, 

=

Actual VON content of a coating, or the

daily-weighted average VON content of

two or more coatings (if more than one

coating is used), as applied to the

subject coating line as determined by

the applicable test methods and

procedures specified in subsection

(a) (4) (i) of this Part in units of kg

VOM/l

(lb VON/gal) of coating solids as

applied-,-j~

VOM1 

The VON emission limit specified in

Ccction 21~.207(a) or (b) Sections

219.204 or 219.205 of this Part in units

of kg VON/l (lb VON/gal) of 

coating

solids as applied.

f)  Volatile Organic Material Gas Phase Source Test Methods

The methods in 40 CFR Part 60, Appendix A, incorporated

by reference in Section 219.112 of this Part delineated

below shall be used to determine control device

efficiencies.

1)  40 CFR Part 60, Appendix A, Method 18, 25 or 25A,

incorporated by reference in Section 219.112 g~

this Part as appropriate to the conditions at the

site, shall be used to determine VOM

421

concentration. Method selection shall be based on

consideration of the diversity of organic species

present and their total concentration and on

consideration of the potential presence of

interfering gases. Except as indicated in

subsections (f) (1) (A) and (B) below, the test

shall consist of three separate runs, each lasting

a minimum of 60 mm, unless the Agency and the

USEPA determine that process variables dictate

shorter sampling times.

A)  When the method is to be used to determine

the efficiency of a carbon adsorption system

with a common exhaust stack for all the

individual adsorber vessels, the test shall

consist of three separate runs, each

coinciding with one or more complete

sequences through the adsorption cycles of

all the individual adsorber vessels.

B)

When 

the method is to be used to determine

the efficiency of a carbon adsorption system

with individual exhaust stacks for each

adsorber vessel, each adsorber vessel shall

be tested individually. The test for each

adsorber vessel

shall consist of three

separate runs. Each run shall coincide with

one or more complete adsorption cycles.

2)  40 CFR Part 60, Appendix A, Method 1 or 1A,

incorporated by reference in Section 219.112 çj

this Part, shall be used for sample and velocity

traverses.

3)  40 CFR Part 60, Appendix A, Method 2, 2A, 2C or

2D, incorporated by reference in Section 219.112

of this Part, shall 

be used for velocity and

volumetric flow rates.

4)

40 CFR 

Part 60, Appendix A, Method 3, incorporated

by reference in Section 219.112 of this Part,

shall be used for gas analysis.

5)  40 CFR Part 60, Appendix A, Method 4, incorporated

by reference in Section 219.112 of this Part,

shall be used for stack gas moisture.

6)  40 CFR Part 60, Appendix A, Methods 2, 2A, 2C, 2D,

3 and 4, incorporated by reference in Section

219.112 of this Part, shall be performed, as

applicable, at least twice during each test run.

422

7)  Use of an adaptation to any of the test methods

specified in subsections (f) (1), (2), (3)

,

(4),

(5) and (6) of this Section may not be used unless

approved by the Agency and the USEPA on a case bY

case basis. An owner or operator must submit

sufficient documentation for the Agency and the

USEPA to find that the test methods specified in

subsections (f)(l), (2), (3), (4), (5) and (6) Q~

this Section will yield inaccurate results and

that the proposed adaptation is appropriate.

g)  Leak Detection Methods for Volatile Organic Material

Owners or operators required by this Part to carry out

a leak detection monitoring program shall comply with

the following requirements:

1)  Leak Detection Monitoring

A)  Monitoring shall comply with 40 CFR 60,

Appendix A, Method 21, incorporated by

reference in Section 219.112 of this Part.

The detection instrument shall meet the

performance criteria of Method 21.

C)  The instrument shall be calibrated before use

on each day of its use by the methods

specified in Method 21.

D)  Calibration gases shall be:

i)  Zero air (less than lopprn of hydrocarbon

in air); and

ii) A mixture of methane

or n—hexane and air

at a concentration

of approximately, but

no less than, 10,000 ppm methane or

n—hexane.

E)  The instrument probe shall be traversed

around all potential leak interfaces as close

to the interface as possible as described in

Method 21.

2)  When equipment is tested for compliance with no

detectable emissions as

required, the test shall

comply with the following requirements:

A)  The requirements of subsections (g) (1) (A)

through (g) (1) (E) of this

Section above shall

apply.

423

B)  The background level shall be determined as

set forth in Method 21.

3)  Leak detection tests shall be performed consistent

with:             

A) “APTI Course SI 417 controlling Volatile

Organic Compound Emissions from Leaking

Process Equipment”, EPA-450/2—82—015,

incorporated by reference in Section 219.112

of this Part.

B)  “Portable Instrument User’s Manual for

Monitoring VOG?j Sources”, EPA-340/ 1-86-015,

incorporated by reference in Section 219.112

of this Part.

C)  “Protocols for Generating Unit-Specific

Emission Estimates for Equipment Leaks of

VO~GMand VHAP”, 

EPA—450/3—88—010,

incorporated by reference in Section 219.112

of this Part.          

D)  “Petroleum Refinery Enforcement Manual”,

EPA-340/1—80-008, incorporated by reference

in Section 219.122219.112 of this Part.

h)  Bulk Gasoline Delivery System Test Protocol

1)  The method for determining the emissions of

gasoline from a vapor recovery system are

delineated in 40 CFR 60, Subpart XX, Section

60.503, incorporated by reference in Section

219.112 of this Part.

2)  Other tests shall be performed consistent with:

A)  “Inspection Manual for Control of Volatile

Organic Emissions from Gasoline Marketing

Operations: Appendix D”, EPA-340/ 1—80—012,

incorporated by reference in Section 219.112

of this Part.

B)  “Control of Hydrocarbons from Tank Truck

Gasoline Loading Terminals: Appendix A”,

EPA-450/2-77-026, incorporated by reference

in Section 219.112 of this Part.

1)  Notwithstanding other requirements of this Part, upon

request of the Agency where it is necessary to

demonstrate compliance, an owner or operator of an

emission source unit which is subject to this Part

424

shall, at his own expense, conduct tests in accordance

with the applicable test methods and procedures

specific in this Part. Nothing in this Section shall

limit the authority of the USEPA pursuant to the Clean

Air Act, as amended, to require testing.

jj  Stage II Gasoline VaPor RecoverY Test Methods

The

methods for determining the acceptable performance

of_Staae II Gasoline VaPor Recovery SYstem are

delineated in “Technical Guidance—Stage II Vapor

RecoverY Systems for Control of Vehicle Refuelina

Emissions at Gasoline Dispensing Facilities,” found at

EPA 450/3-91-022b and incorporated by reference in

Section 219.112 of this Part. Specifically. the test

methods are as follows:

jj Dynamic BackPressure Test is a test procedure used

to determine the pressure drop (flow resistance)

through balance vaPor 

collection and control

sYstems (including nozzles, vapor hoses. swivels,

dispenser piping, and underaround piping) at

prescribed flow rates.

~  Pressure Decay/Leak Test is a test Procedure used

to auantify the vapor tightness of a vapor

collection and control system installed at

gasoline dispensing facilities.

~j. Liquid Blockage Test is a test procedure used to

detect low points in any vapor collection and

control system where condensate may accumulate.

(Source: Amended at —  Ill. Reg. 

______,

effective 

____________

Section 219.106  

Compliance Dates

Compliance with the requirements of all rules is required by May

15, 1992, consistent with the provisions of Section 219.103 g~

this Part.

(Source: Amended at —  Ill. Reg. 

______,

effective

Section 219.107  

Operation of Afterburners

The operation of any natural gas fired afterburner and capture

system used to comply with this Part is not required during the

period of November 1 of any year to April 1 of the following year

provided that the operation of such devices is not required for

425

purposes of occupational safety or health, or for the control of

toxic substances, odor nuisances, or

other regulated pollutants.

(Source: Amended at —  Ill. Reg. 

______,

effective 

____________

Section 219.109  

Vapor Pressure of Volatile Organic Liquids

a)  If the VOL consists of only a single compound, the

vapor pressure shall be determined by ASTM Method

02879-86 (incorporated by reference in Section 219.112

of this Part) or the vapor pressure may be obtained

from a published sourcepublication such as: Boublik,

T., V. Fried and E. Hala, “The Vapor Pressure of Pure

Substances,” Elsevier Scientific Publishing Co., New

York (1973); Perry’s Chemical Engineer’s Handbook,

McGraw-Hill Book Company (1984); CRC Handbook of

Chemistry and Physics, Chemical Rubber Publishing

Company (1986-87); and Lange’s Handbook of Chemistry,

John A. Dean, editor, McGraw-Hill Book Company (1985).

b)  If the VOL is a mixture, the vapor pressure shall be

determined by ASTM Method D2879—86 (incorporated by

reference in Section 219.112 of this Part) or by the

following equation:

n

PvoI  = 

1=1

p1 x1

where:

P~01 

Total vapor pressure of the mixtureT~

=

Number of components in the mixture~~

Subscript denoting an individual

component~~

P.

=

Vapor pressure of a component determined

in accordance with Cubpart A of this

Partsubsection (a) of this Section

Mole fraction of the component in the

total mixture.

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

____________

Section 219.110  

Vapor Pressure of Organic Material or Solvent

426

a)  If the organic material or solvent consists of only a

single compound, the vapor pressure shall be determined

by ASTM Method 02879-86 (incorporated by reference in

Section 219.112 of this Part) or the vapor pressure may

be obtained from a published oourocpublication such as:

Boublik, T., V. Fried and E. Hala, “The Vapor Pressure

of Pure Substances,” Elsevier Scientific Publishing

Co., New York (1973); Perry’s Chemical Engineer’s

Handbook, McGraw-Hill Book Company (1984); CRC Handbook

of Chemistry and Physics, Chemical Rubber Publishing

Company (1986-87); and Lange’s Handbook of Chemistry,

John A. Dean, editor, McGraw-Hill Book Company (1985).

b)  If the organic material or solvent is in a mixture made

up of both organic material compounds and compounds

which are not organic material, the vapor pressure

shall be determined by the following equation:

n

~c~n

Eil P1X1

n

R

1=1

X1

where:

Total vapor pressure of the portion of

the mixture which is composed of organic

materia l-~j

n

=

Number of organic material components in

the mixture-,-~

=

Subscript denoting an individual

component7-~

P1

=

Vapor pressure of an organic material

component determined in accordance with

Subpart A of this Partsubsection (a) of

this SectionT.~

Xl

=

Mole fraction of the organic material

component of the total mixture.

C)   If the organic material or solvent is in a mixture made

up of only organic material compounds, the vapor

pressure shall be determined by ASTM Method D2879-86

(incorporated by reference in Section 219.112 of this

Part) or by the above equation.

427

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

____________

Section 219.111  

Vapor Pressure of Volatile Organic Material

a)  If the VON consists of only a single compound, the

vapor pressure shall be determined by ASTM Method

D2879-86 (incorporated by reference in Section 219.112

of this Part) or the vapor pressure may be obtained

from a published sourcepublication such as: Boubuik,

T., V. Fried and E. Hala, “The Vapor Pressure of Pure

Substances,” Elsevier Scientific Publishing Co., New

York (1973); Perry’s Chemical Engineer’s Handbook,

McGraw-Hill Book Company (1984); CRC Handbook of

Chemistry and Physics, Chemical Rubber Publishing

Company

(1986—87); and Lange’s Handbook of Chemistry,

John A. Dean, editor, McGraw-Hill Book Company (1985).

b)  If the VON is in a mixture made up of both VON

compounds and compounds which are not VON, the vapor

pressure shall be determined by the following equation:

n

~om

E

1=1

P~X1

n

E

i=1

X1

where:

Total vapor pressure of the portion

of the mixture which is composed of

VONNumber7~

of VON components in the

mixtureT~

I

=

Subscript denoting an individual

component7j

P1

=

Vapor pressure of a VON component

determined in accordance with

6ubpart A of this Partsubsection

(a) of this Section-~

X~

=

Mole fraction of the VON component

of the total mixture.

C)   If the VON is in a mixture made up of only VON

compounds, the vapor pressure shall be determined by

428

ASTM Method D2879-86 (incorporated by reference in

Section 219.112 of this Part) or by the above equation.

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

_____________

_________________________)

Section 219.112  

Incorporations by Reference

The following materials are incorporated by reference and do not

contain any subsequent additions or amendments:

a)  American Society for Testing and Materials, 1916 Race

Street, Philadelphia, PA 19103:

1)  ASTM D2879—86

2)  ASTM 0323—82

3)  ASTM D86—82

4)  ASTM D—369—69 (1971)

5)  ASTN 0—396—69

ASTM D2880—71

7)  ASTM 0—975—68

ASTM D3925—81 (1985)

9)  ASTM E300—86

10) ASTN Dl475—85

11) ASTN D2369—87

12) ASTM D3792—86

13) ASTM D4017—81 (1987)

14) ASTN 04457—85

15)

ASTM D2697—86

16) ASTM D3980—87

17) ASTM E180—85

18) ASTM D2372—85

19) ASTM D97—66

20) ASTM E—168—87 (1977)

21) ASTM E—169~i

22) ASTM E—260~j,

23) ASTM D2504—83

24)

ASTM D2382—83

~j ASTM D323-82 

(approved 1982)

Standard Industrial Classification

Manual, published by

Executive Office of the President, Office of Management

and Budget, Washington, D.C., 1987.

C)   American Petroleum Institute 

Bulletin

2517,

“Evaporation Loss From Floating Roof Tanks”, Second

ed., February, 1980.

d)  40 CFR Part 60 (July 1, 19901991) and 40 CFR 60,

Appendix A. Method 24 (57 FR 30654, July 10, 1992).

e)  40 CFR Part 61 (July 1, 19901991).

429

f)  40 CFR Part 50 (July 1, 19891991).

g)  40 CFR Part 51 (July 1, -1-9891991)

h)  40 CFR Part 52 (July 1, 19891991).

j).  40 CFR Part 80 (July 1, 1991).

4-)-jI “A Guide for Surface Coating Calculation”, United

States Environmental Protection Agency, Washington,

D.C., EPA—340/l—86—016.

&3-~ci.. “Procedures for Certifyina Ouantity of Volatile Organic

Compounds Emitted by Paint, Ink and Other Coating”,

(revised June 1986), United States Environmental

Protection Agency, Washington D.C., EPA-450/3—84-019.

k-)-jj”A Guide for Graphic Arts Calculations”, August 1988~

United States Environmental Protection Agency,

Washington D.C., EPA-340/l-88-003.

~)-~j“Protocol for Determining the Daily Volatile Organic

Compound Emission Rate of Automobile and Light-Duty

Truck Topcoat Operations”. December 1988, United States

Environmental Protection Agency, Washington D.C.,

EPA—450/3—88—018.

~)-~j “Control of Volatile Organic Emissions from

Manufacturing of Synthesized Pharmaceutical Products”,

United States Environmental Protection Agency,

Washington, D.C., EPA—450/2—78—029.

~)-gj~.“Control of Volatile Organic Compound Leaks from

Gasoline Tank Trucks and Vapor Collection Systems”,

Appendix B, United States Environmental Protection

Agency, Washington, D.C., EPA-450/2-78-051.

e-)-pj. “Control of Volatile Organic 

Compound

emissions from

Large Petroleum Dry Cleaners”, United States

Environmental Protection Agency, Washington, D.C.,

EPA—450/3—82—009.

gj “APTI Course S1417 Controlling Volatile Organic

Compound Emissions from Leaking Process Eauipment”,

United States Environmental Protection Agency,

Washington, D.C., EPA—450/2—82—015.

“Portable Instrument User’s Manual for Monitoring VOM

Sources”, United States Environmental Protection

Agency, Washington, D.C., EPA-340/1-86-015.

430

~j “Protocols for Generating Unit-Specific Emission

Estimates for Equipment Leaks of VON and VHAP”, Unit~

States Environmental Protection Agency. Washington~

D.C., EPA—450/3—88—010.

~  “Petroleum Refinery Enforcement Manual”, United States

Environmental Protection Agency. Washington~ D.C..

EPA—340 /1—80—008.

~j “Inspection Manual for Control of Volatile Organic

Emissions from Gasoline Marketing Operations: Appendix

D”. United States Environmental Protection Agency,

Washington, D.C., EPA—340/1—80—012.

“Control of Hydrocarbons from Tank Truck Gasoline

Loading Terminals: Appendix A”. United States

Environmental Protection Agency. Washington, D.C.,

EPA—450 /2—77—026.

~j “Technical Guidance-Stage II VaPor Recovery Systems for

Control of Vehicle

Refueling Emissions at Gasoline

Dispensing Facilities”, United States Environmental

Protection Agency, Washington, D.C., EPA-450/3—91-022b.

California Air Resources Board. Compliance Division.

Compliance Assistance Program: Gasoline Marketing and

Distribution: Gasoline Facilities Phase I & II

(October 1988, rev. March 1991) (CARB Manual).

(Source: Amended at —  Ill. Reg. 

______,

effective 

____________

SUBPART B: ORGANIC EMISSIONS FROM STORAGE AND LOADING OPERATIONS

Section 219.121  

Storage Containers

No person shall cause or allow the storage of any VOL with a

vapor pressure of 17.24 kPa (2.5 psia) or greater at

294.3°K

(70°F) or any gaseous organic material in any stationary tank,

reservoir or other container of more than 151 cubic meters

(40,000 gal) capacity unless such tank, reservoir or other

container:

a)  Is a pressure tank capable of withstanding the vapor

pressure of such liquid or the pressure of the gas, so

as to prevent vapor or gas loss to the atmosphere at

all times; or,

b)  Is designed and equipped with one of the following

vapor loss control devices:

431

1) A floating roof which rests on

the surface of the

VOL and 

is equipped with a closure seal

or seals

between the roof edge and the tank wall. Such

floating roof shall not be permitted if the VOL

has a vapor pressure of 86.19 kPa (12.5 psia) or

greater at 294.3°K(70°F). No person shall cause

or allow the emission of air contaminants into the

atmosphere from any gauging or sampling devices

attached to such tanks, except during sampling or

maintenance operations.

2)  A vapor recovery system consisting of:

A)  A vapor gathering system capable of

collecting 85 or more of the uncontrolled

VON that would be otherwise emitted to the

atmosphere; and,

B)  A vapor disposal system capable of processing

such VON so as to prevent its emission to the

atmosphere. No person shall cause or allow

the emission of air contaminants into the

atmosphere from any gauging or sampling

devices attached to such tank, reservoir or

other container except during sampling.

3)  Other equipment or means of equal efficiency

approved by the Agency according to the provisions

of 35 Ill. Adm. Code 201, and further processed

consistent with Section 219.108 of this Part.

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

____________

Section 219.122  

Loading Operations

a)  No person shall cause or allow the discharge of more

than 3.6 kg/hr (8 lbs/hr) of organic material into the

atmosphere during the loading of any organic material

from the aggregate loading pipes of any loading

facilityarea having through-put of greater than 151

cubic meters per day (40,000 gal/day) into any railroad

tank car, tank truck or trailer unless such loading

facilityarea is equipped with submerged loading pipes~

submerged fill or a device that is equally effective in

controlling emissions and is approved by the Agency

according to the provisions of 35 Ill. Adin. Code 201,

and further processed consistent with Section 219.108

of this Part.

b)  No person shall cause or allow the loading of any

organic material into any stationary tank having a

432

storage capacity of greater than 946 1. (250 gal),

unless such tank is equipped with a permanent submerged

loading pipe, submerged fill or an equivalent device

approved by the Agency according to the provisions of

35 Ill. Adm. Code 201, and further processed consistent

with Section 219.108 of this Part, or unless such tank

is a pressure tank as described in Section 219.121(a)

of this Part or is fitted with a recovery system as

described in Section 219.121(b) (2) of this Part.

c)  Exception: If no odor nuisance exists the limitations

of this Section shall only apply to the loading of VOL

with a vapor pressure of 17.24 kPa (2.5 psia) or

greater at 294.3°K (70°F).

(Source: Amended at —  Ill. Reg. 

______,

effective 

____________

Section 219.123  

Petroleum Liquid Storage Tanks

a)  The requirements of subsection (b) of this Section

shall not apply to any stationary storage tank:

1)

Equipped 

before January 1, 1979 with one of the

vapor loss control devices specified in Section

219.121(b) of this Part, except Section

219.121(b) (1) of this Part

2)  With a capacity of less than 151.42 cubic meters

(40,000 gal);

3)  With a capacity of less than 1,600 cubic meters

(422,400 gal) and used to store produced crude oil

and condensate prior to custody transfer;

4)  With a capacity of less than 1,430 cubic meters

(378,000 gal) and used to store produced oil or

condensate in crude oil gathering;

Subject to new source performance standards for

storage vessels of petroleum liquid, 35 Ill. Adm.

Code 230 40 CFR 60, as regulations promulgated by

the U.S. Environmental Protection Agency under

Section 11. of the Clean Air Act (42 USC 7411), as

amended.

THE PROVISIONS OF SECTION 111 OF THE

CLEAN AIR ACT 

...

ARE APPLICABLE IN THIS STATE AND

ARE ENFORCEABLE UNDER THE ENVIRONMENTAL

PROTECTION ACT (Ill. Rev. Stat. 1991, ch. l1l~,

Par. 1009.1(b)) 415 ILCS 5/9.1(b)1

6)  In which volatile petroleum liquid is not stored;

or

433

7)  Which is a pressure tank as described in Section

219.121(a) of this Part.

Subject to subsection (a) of this Section

no owner or

operator of a 

stationary

storage tank shall cause or

allow the storage of any VOL in the tank unless:

1)  The tank is equipped with one of the vapor loss

control devices specified in Section 219.121(b)

Q~

this Part

2)  There are no visible holes, tears or other defects

in the seal or any seal fabric or material of any

floating roof;

3)  All openings of any floating roof deck, except

stub drains, are equipped with covers, lids or

seals such that:

A)  The cover, lid or seal is in the closed

position at all times except when petroleum

liquid is transferred to or from the tank;

B)  Automatic bleeder vents are closed at all

times except when the roof is floated off or

landed on the roof leg supports; and

C)  Rim vents, if provided, are set to open when

the roof is being floated off the roof leg

supports or at the manufacturer’s recommended

setting;

4)  Routine inspections of floating roof seals are

conducted through roof hatches once every six

months;

5)  A complete inspection of the cover and seal of any

floating roof tank is made whenever the tank is

emptied for reasons other than the transfer of

petroleum liquid during the normal operation of

the tank, or whenever repairs are made as a result

of any semi—annual inspection or incidence of roof

damage or defect; and

6)  A record of the results of each inspection

conducted under subsection (b) (4) or (b) (5) ~

this Section is maintained.

e)  Owners and operators of petroleum liquid storage tanks

were required to have compliance schedules as

ThTh~-i?r~r~in ~nr~-c~r~iivC’ 

tn ~ Til

Aim C~c~d~21~..

434

(Source: Amended at 

______,

Ill. Reg. 

_____,

effective 

________

—

Section 219.124

External Floating Roofs

a)  In addition to meeting the requirements of Section

219.123(b) of this Part, no owner or operator of a

stationary storage tank equipped with an external

floating roof shall cause or allow the storage of any

volatile petroleum liquid in the tank unless:

1)  The tank has been fitted:

~  fitted w~itha continuous secondary seal

extending from the floating roof to the tank

wall (rim mounted secondary seal)~or

~  With any other device which controls VON

emissions 

wi’Ln

~n effectiveness equal to or

~-‘-~-

than a rim mounted secondary sea-I;

equipment or means of equal efficiency

approved by the Agency according to the

provisions of 35 Ill. Adm. Code 201, and

further processed consistent with Section

219.108 of this Part.

2)  Each seal closure device meets the following

requirements:

A)  The seal is intact and uniformly in place

around the circumference of 

the floating roof

between the floating roof and tank wall; and

B)  The accumulated area of gaps exceeding 0.32

centimeter (1/8 inch) in width between the

secondary seal and the tank wall shall not

exceed 21.2 square centimeters per meter of

tank diameter (1.0 square inchee per foot of

tank diameter). Compliance with this

requirement shall be determined by:

Physically measuring the length and

width of all gaps around the entire

circumference of the secondary seal in

each place where a 0.32 cm (0.125 i~j

uniform diameter probe passes freely

(without forcing or binding against the

seal) between the seal and the tank

wall; and

JJJ

Summing the area of the individual gaps.

435

3)  Emergency 

roof drains are provided

with slotted

membrane fabric covers or equivalent covers across

at least 90 percent of the area of the opening;

4)  Openings are equipped with projections into the

tank which remain below the liquid surface at all

times;

5)  Inspections are conducted prior to May 1 of each

year to insure compliance with subsection (a) 

this Section

6)  The secondary seal gap is measured prior to May 1

of each year~and within 30 days of a written

request to demonstrate compliance with subsection

(2) (B) of this Section

7) Records of the

types of volatile petroleum liquid

stored, the maximum true vapor pressure of the

liquid as stored, the results of the inspections

and the results of the secondary seal gap

measurements are maintained and available to the

Agency, upon verbal or written request, at any

reasonable time for a minimum of two years after

the date on which the record was made.

b)  Subsection (a) above does not apply to any stationary

storage tank equipped with an external floating roof:

1)  Exempted under Section 219.123(a) (2) through

219.123(a) (6) of this Part

2)  Of welded construction equipped with a metallic

type shoe seal having a secondary seal from the

top of the shoe seal to the tank wall

(shoe-mounted secondary seal);

3)  Of welded construction equipped with a metallic

type shoe seal, a liquid—mounted foam seal, a

liquid-mounted liquid-filled—type seal, or other

closure device of equivalent control efficiency

approved by the Agency in which a petroleum liquid

with a true vapor pressure less than 27.6 kPa (4.0

psia) at 294.3°K (70°F) is stored; or

4)  Used to store crude oil with a pour point of 50°F

or

higher as determined by ASTM Standard

D97-66

incorporated by reference in Section 219.112 p~

this Part.

(Source: Amended at —  Ill. Reg. 

______,

effective 

___________

436

Section 21~.125 Compliance Dates (Re~ea1ed)

Every owner or operator of -an -emission 

source oub~eot to 35

Ill-u

Adm. 

Code 215, Cubpart B, as of December 31, 1937 shall have

complied with its standards and limitations by December 31, 1987-.

(Source: Repealed at 

—

Ill. Reg.    

,  effective 

__________

_________________________)

Section 219.126  

Compliance Plan (Repealed)

The owner or operator -of 

i.... ~

source prcviousi.y

subject to Ccotion 215.125 shall have submitted to the

Agency a compliance plan as required by 35 Ill. Adm.

Code 

201.241, including

a project completion schedule

where applicable, no later than April 21, 1983.

Unless the submitted compliance plan or schedule ~as

~sapprovca by the Agency, the owner or operator

facility or emission source subject to the rules

specified in subsection (a) may operate the emission

source according to the r~lanand schedule as submitted.

The plan and schedule shall meet the ~rcquircmcnts of 35

Ill. Adm. Code 201.241 including specific interim dates

as required in 35 Ill. Adm. Code 2-01.242.

(Source: Repealed at —  Ill. Reg. 

______,

effective 

___________

SUBPART C: ORGANIC EMISSIONS FROM MISCELLANEOUS EQUIPMENT

Section 219.141  

Separation Operations

a) No person shall use any single

or multiple compartment

effluent water separator which receives effluent water

containing 757 1/day (200 gal/day) or more of organic

material from any equipment processing, refining,

treating, storing or handling organic material unless

such effluent water separator is equipped with air

pollution control equipment capable of reducing by 85

percent or more the uncontrolled organic material

emitted to the atmosphere. Exception: If no odor

nuisance exists the limitations of this subsection

shall not apply if the vapor pressure of the organic

material is below 17.24 kPa (2.5 psia) at 294.3°K

(70°F)

b)  Subsection (a) of this Section shall not apply to water

and crude oil separation in the production of Illinois

crude oil, if the vapor pressure of such crude oil is

less than 34.5 kPa (5 psia).

437

(Source: Amended at 

______,

Ill. Reg.   

,  effective 

__________

______________________ )

Section 219.143  

Vapor Blowdown

No person shall cause or allow the emission of organic material

into the atmosphere from any vapor blowdown system or any safety

relief valve, except such safety relief valves not capable of

causing an excessive release, unless such emission is controlled:

a)  To 10 ppm equivalent methane (molecular weight 16.0) or

less; or,

b)  By combustion in a smokeless flare; or,

C)   By other air pollution control equipment approved by

the Agency according to

the provisions of 35 Ill. Adm.

Code 201, and further processed consistent with Section

219.108 of this Part.

(Source: Amended at  

Ill. Reg. 

______,

effective 

_____________

Section 219.144  

Safety Relief Valves

Section 219.143 of this Part shall not apply to any set of

unregulated safety relief valves capable of causing excessive

releases, provided the owner or operator thereof, by October 1,

1972, supplied the Agency with the following:

a)  A historical record of each such set (or, if such

records were unavailable, of similar sets which, by

virtue of operation under similar circumstances, may

reasonably have been presumed to have the same or

greater frequency of excessive releases) for a

three-year period immediately preceding October 1,

1972, indicating:

Dates on which excessive releases occurred from

each such set; andT

2) Duration in minutes

of each such excessive

release; andT

3)  Quantities (in pounds) of mercaptans and/or

hydrogen sulfide emitted into the atmosphere

during each such excessive release.

b)  Proof, using such three-year historical records, that

no excessive release is likely to occur from any such

set either alone or in combination with such excessive

releases from other sets owned or operated by the same

438

person and located within a ten—mile radius from the

center point of any such set, more frequently than 3

times in any 12 month period;

C)   Accurate maintenance records pursuant to the

requirements of subsection (a) of this Section and,

d)  Proof, at three-year intervals, using such three—year

historical records, that such set conforms to the

requirements of subsection (c) of this Section.

(Source: Amended at  

Ill. Reg.    

,  effective 

____________

______________________ )

SUBPART E: SOLVENT CLEANING

Section

219.181  

Solvent Cleaning in General

The

requirements of this Subpart

shall apply to all cold

cleaning, open

top vapor degreasing, and conveyorized degreasing

operations which use volatile organic materials.

(Source:

Amended at

Ill. Reg.

______,

effective 

____________

Section 219.182  

Cold Cleaning

a)  Operating Procedures: No person shall operate a cold

cleaning degreaser unless:

1)  Waste solvent is stored in covered containers only

and not disposed of in such a manner that more

than 20 of the waste solvent (by weight) is

allowed to evaporate into the atmosphere;

2)  The cover of the degreaser is closed when parts

are not being handled; and

Parts are drained until dripping ceases.

b) Equipment Requirements:

No person shall operate a cold

cleaning degreaser unless:

1)  The degreaser is equipped with a cover which is

closed whenever parts are not being handled in the

cleaner. The cover shall be designed to be easily

operated with one hand or with the mechanical

assistance of springs, counter—weights or a

powered system if:

439

A)  The solvent vapor pressure is greater than 2

kPa (15 mmNg or 0.3 psi) measured at 38°C

(100°F);

B)  The solvent is agitated; or

C)  The solvent is heated above ambient room

temperature.

2)  The degreaser is equipped with a facilitydevice

for draining cleaned parts. The drainage

facilitydevice shall be constructed so that parts

are enclosed under the cover while draining

unless:

The solvent vapor pressure

is less than 4.3

kPa (32 ininHg or 0.6 psi) measured at 38°C

(100°F); or   

B)  An internal drainage facilitydevice cannot be

fitted into the cleaning system, in which

case the drainage facilitydevice may be

external.

3)  The degreaser is equipped with one of the

following control devices if the vapor pressure of

the solvent is greater than 4.3 kPa (32 inmHg or

0.6 psi) measured at 38°C(100°F) or if the

solvent is heated above 50°C (120°F) or its

boiling point:              

A freeboard height of 7/10 of the inside

width of the tank or 91 cm (36 in), whichever

is less; or

Any other equipment or system of equivalent

emission control as approved by the Agency

and further processed consistent with Section

219.108 of this Part. Such a system may

include a water

cover, refrigerated chiller

or carbon adsorber.

4)  A permanent conspicuous label summarizing the

operating procedure is affixed to the degreaser;

and

5)  If a solvent spray is used, the degreaser is

equipped with a solid fluid stream spray, rather

than a fine, atomized or shower spray.

(Source: Amended at 

______,

Ill. Reg. 

_______,

effective

440

Section

219.183  

Open Top Vapor Degreasing

a)  Operating Requirements: No person shall operate an

open top vapor degreaser unless:

1)  The cover of the degreaser is closed when

workloads are not being processed through the

degreaser;

2)  Solvent carryout emissions are minimized by:

A)  Racking parts to allow complete drainage;

B)  Moving parts in and out of the degreaser at

less than 3.3 m/min (11 ft/mm) ;

C)  Holding the parts in the vapor zone until

condensation ceases;

D)  Tipping out any pools of solvent on the

cleaned parts before removal from the vapor

zone; 

E)  Allowing parts to dry within the degreaser

until visually dry.

3)  Porous or absorbent materials, such as cloth,

leather, wood or rope are not degreased;

4)  Less than half of the degreaser’s open top area is

occupied with a workload;

5)

The degreaser is not loaded to the point where the

vapor level would drop more than 10 cm (4 in) when

the workload is removed from the vapor zone;

6)  Spraying is done below the vapor level only;

7)  Solvent leaks are repaired immediately;

8)  Waste solvent is stored in covered containers only

and not disposed of in such a manner that more

than 20 of the waste solvent (by weight) is

allowed to evaporate into the atmosphere;

9)  Water is not visually detectable in solvent

exiting from the water separator; and

10) Exhaust ventilation exceeding 20 cubic meters per

minute per square meter (65 cubic feet per minute

per square foot) of degreaser open area is not

used, unless necessary to meet the requirements of

441

the Occupational Safety and Health Act (29 U.S.C.

Section 651 et seq.).

b) Equipment Requirements:

No person shall operate an

open top vapor degreaser unless:

1)  The degreaser is equipped with a cover designed to

open and close easily without disturbing the vapor

zone;

2)  The degreaser is equipped with the following

switches:

A)  A dcviccQj~which shuts off the sump heat

source if the amount of condenser coolant is

not sufficient to maintain the designed vapor

level; and

B)  A dcviccQ~which shuts off the spray pump if

the vapor level drops more than 10 cm (4 in)

below the bottom condenser coil; and

C)  A dcviccQ~which shuts off the sump heat

source when the vapor level exceeds the

design 1evel~

3)  A permanent conspicuous label summarizing the

operating procedure is affixed to the degreaser;

4)  The degreaser is equipped with one of the

following devices:

A) A freeboard height of

3/4 of the inside width

of the degreaser tank or 91 cm (36 in),

whichever is less; and if the degreaser

opening is greater than

1 square meter (10.8

a powered or mechanically assisted

cover; or

Any other equipment or system of equivalent

emission control as approved by the Agency

and further processed consistent with

Section

219.108 of this Part.

Such equipment or

system may include a refrigerated chiller, an

enclosed design or a carbon adsorption

system.

(Source: Amended at 

_____,

Ill. Reg.    

,  effective 

__________

Section 219.184  

Conveyorized Degreasing

442

a)  Operating Requirements: No person shall operate a

conveyorized degreaser unless:

1)  Exhaust ventilation exceeding 20 cubic meters per

minute per square meter (65 cubic feet per minute

per square foot) of area of loading and unloading

opening is not used, unless necessary to meet the

requirements of the Occupational Safety and Health

Act (29 U.S.C. Section 651 et seq.);

2)  Solvent carryout emissions are minimized by:

A)  Racking parts for best drainage; and

B)  Maintaining the vertical conveyor speed at

less than 3.3 m/min (11 ft/mm);

3)  Waste solvent is stored in covered containers only

and not disposed of in such a manner that more

than 20 of the waste solvent (by weight) is

allowed to evaporate into the atmosphere;

4)  Solvent leaks are repaired immediately;

5)  Water is not visually detectable in solvent

exiting from the water separator; and

6)  Downtime covers are placed over entrances and

exits of conveyorized degreasers immediately after

the conveyors and exhausts are shut down and not

removed until just before start-up.

b)  Equipment Requirements: No person shall operate a

conveyorized degreaser unless:

1)  The degreaser is equipped with a drying tunnel,

rotating (tumbling) basket or other equipment

sufficient to prevent cleaned parts from carrying

out solvent liquid or vapor;

The degreaser is equipped with the following

switches:

A)  A dcviccQ~which shuts off the suinp heat

source if the amount of condenser coolant is

not sufficient to maintain the designed vapor

level;

B)  A deviccQ~~which shuts off the spray pump or

the conveyor if the vapor level drops more

than 10 cm (4 in) below the bottom condenser

coil; and

443

C)  A dcviccQ~which shuts off the sump heat

source when the vapor level exceeds the

design level;

3)  The degreaser is equipped with openings for

entrances and exits that silhouette workloads so

that the average clearance between the parts and

the edge of the degreaser opening is less than 10

cm (4 in) or less than 10 percent of the width of

the opening;

4)  The degreaser is equipped with downtime covers for

closing off entrances and exits when the degreaser

is shut down; and

5)  The degreaser is equipped with one of the

following control devices, if the air/vapor

interface is larger than

2.0 square meters (21.6

ft2)

A)  A carbon adsorption system with ventilation

greater than or equal to 15 cubic meters per

minute per square meter (50 cubic feet per

minute per square foot) of air/vapor area

when downtime covers are open, and exhausting

less than 25 ppm of solvent by volume

averaged over a complete adsorption cycle; or

B)  Any other equipment or system of equivalent

emission control as approved by the Agency,

and further processed consistent with Section

219.108 of this Part.

Such equipment or

system may include a refrigerated chiller.

(Source: Amended at 

_____,

Ill. Reg. 

______,

effective

Section 219.185  

Compliance Schedule (Re~ea1ed)

Every owner or operator of sri emission source which was

previously c~cmptfrom the requirements of Subpart E of 35 Iii.

Adin. Code 215 (Cections 215.182-215.184) because it satisfied the

criteria in either 35 Ill. Adm. 

Code 215.181(a) or 35 Ill. Adm.

Code 215.181(b), shall comply with the requirements of this

Subpart

on and after a date consistent with Section 219.106. A

source which did not satisfy the criteria in either 35 Ill. Adm.

Code 215.IB.(a) or 35 Ill. Adm. Code 215.181(b) shall comply with

the requirements of this Snhr~rt ur~onadoption.

(Source: Repealed at

—

Ill. Reg. 

______,

effective 

___________

444

Section 219.186  

Test Methods

The following test methods shall

be used to demonstrate

compliance with this

Subpart:

a) Vapor pressures

shall be determined by using the

procedure specified in Section 219.110 of this Part.

b)  Exhaust ventilation rates shall be determined by using

the procedures specified in Section 219.105(f) (3) ~

this Part.

C)   The performance of control devices shall be determined

by using the procedures specified in Section 219.105(f)

of this Part.

(Source: Amended at 

_____,

Ill. Reg.    

,  effective 

__________

SUBPART F: COATING OPERATIONS

Section 219.204  

Emission Limitations for flanufactur~rir~~pn~

Except as provided in Section~219.205. 219.207 and 219.208 g~

this Part, no owner or operator of a coating line shall apply at

any time any coating in which the VON content exceeds the

following emission limitations for the specified coating. The

following emission limitations are expressed in units of VON per

volume of coating (minus water and any compounds which are

specifically exempted from the definition of VON) as applied at

each coating applicator, except where noted. Compounds which are

specifically exempted from the definition of VON should be

treated as water for the purpose of calculating the “less water”

part of the coating composition. Compliance with this Subpart

must be demonstrated through the applicable coating analysis test

methods and procedures specified in Section 219.105(a) of this

Part and the recordkeeping and reporting requirements specified

in Section 219.211(c) of this Part. (Note: The equation

presented in Section 219.206 of this Part shall be used to

calculate emission limitations for determining compliance by

add-on controls, credits for transfer efficiency, emissions

trades and cross—line averaging.)

The emission limitations are

as follows:

a)  Automobile or Light-Duty Truck Coating

kg/i     

lb/gal

1)  Prime coat       

0.14      

(1.2)

2)  Primer surfacer coat  

p.341.81   

(~2--&15.1)

(Note: The primer surfacer coat limitation is

based upon a transfer efficiency of 30 percent.

The -use of transfer efficiency credits can ~e

allowed only if approved by the Agency and

approved by the UCEPA as a SIP rcvisionin units~f

kg (ibs) of VON per 1 (aal) of coating solids

deposited. Compliance with the limitation shall

be based on the daily-weighted average from afl

entire primer surfacer operation. Compliance

shall be demonstrated in accordance with the

topcoat protocol referenced in Section 2l9.105(b1

and the recordkee~ingand reporting requirements

specified in Section 219.211(f). Testing to

demonstrate compliance shall be performed in

accordance with the topcoat protocol and a

detailed testing proposal aDDroved by the Agency

and USEPA specifying the method of demonstrating

compliance with the protocol. Section 219.205

does not a~~lvto the primer surfacer limitation.)

3)  Topcoat

(Note: The topcoat limitation is in units of kg

(lbs) of VON per 1 (gal) of coating solids

deposited.

Compliance with the limitation shall

be based on the daily-weighted average VOH content

from 

entire topcoat operation (all topcoat

spray booths, flash—off

areas and bake ovens).

Compliance shall be demonstrated in accordance

with the topcoat protocol for automobiles and

light—duty trucks referenced in Section 219.105(b)

of this Part and the recordkeeping and reporting

reguirements specified in Section 219.211(f).

Testing to demonstrate compliance shall be

performed in accordance with the topcoat protocol

and Section 219.205 deco not apply to the topcoat

limitation.) At least 180 days prior to the

initial compliance date, the owner or operator of

a co-ating line subject to the topcoat limitation

shall have submitted to the UCEPA a detailed

testing proposal approved by the Agency and USEPA

specifying the method of demonstrating compliance

with the protocol. The proposal shall have

included, at a minimum, a comprehensive plan

(including a rationale) for determining the

tr~fr’r c~ff4r4cncr~

r~t~

each booth through the use

of 1r plant,  

pilot

Pn~v4

4 r”~i 

thr’ 

rr~t4 

‘~~‘

-of

coatings to be tested (for the purpose

determining transfer efficiency) including the

rrtinnr~1t-~for coating groupings; ~md th~mctht-~ii

11i~L

445

kg! 1

1.81

lb/gal

(15.1)

applied coatings and the formulation solvent

content of as applied coatings. Upon approval s-f

446

1 by the UCEP7~.. the source may proceed

~mplianccacmonstration. Section

219.205 of this Part does not apply to the topcoat

limitation.)

kg/l  

lb/gal

4)  Final repair coat       

0.58   

(4.8)

b)  Can Coating            

kg/l  

lb/gal

1)  Sheet basecoat and overvarnish 0.34   

(2.8)

2)  Exterior basecoat and

overvarnish          

0.34   

(2.8)

3)  Interior body spray coat   

0.51   

(4.2)

4)  Exterior end coat       

0.51   

(4.2)

5)  Side seam spray coat     

0.66   

(5.5)

6)

End sealing compound coat

0.44

(3.7)

kg/i  

lb/gal

c)  Paper Coating           

0.35   

(2.9)

(Note: The paper coating limitation shall not apply to

any owner or operator of any paper coating line on

which printing is performed if 

the paper coating line

complies with the emissions limitations in Subpart H:

Printing and Publishing, 

Sections 219.401 through

219.404.)of this Part.)

kg/l  

lb/gal

d)  Coil Coating            

0.31   

(2.6)

e)  Fabric Coating           

0.35   

(2.9)

f)  Vinyl Coating           

0.45   

(3.8)

Metal Fu-rniture Coating

0.36

(3.0)

h)  Large Appliance Coating      

0.34   

(2.8)

(Note: The limitation shall not apply to the use of

quick-drying lacquers for repair of

scratches and nicks

that occur during assembly, provided that the volume of

coating does not exceed 0.95 1 (1 quart) in any one

rolling eight-hour period.)

kg/l  

lb/gal

i)  Magnet Wire Coating        

0.20   

(1.7)

447

Miscellaneous Metal 

Parts and Products Coating

kg/i  

lb/gal

1)  Clear coating         

0.52   

(4.3)

Air—dried coating

0.42

(3.5)

3)  Extreme performance coating  0.42   

(3.5)

il

Steel pail and drum interior

coating            

0.52   

(4.3)

4~) All other coatings      

0.36   

(3.0)

k)  Heavy Off-Highway Vehicle Products Coating

kg/i  

lb/gal

1)  Extreme performance prime coat 0.42   

(3.5)

Extreme performance top—coat

(air dried)           

0.42   

(3.5)

3)  Final repair coat (air dried) 0.42   

(3.5)

All other coatings are subject to the emission

limitations for miscellaneous metal parts and

products coatings in subsection (j)

above.

1)  Wood Furniture Coating

kg/l  

lb/gal

1)  Clear topcoat         

0.67   

(5.6)

2)  Opaque stain          

0.56   

(4.7)

3)  Pigmented coat         

0.60   

(5.0)

4)  Repair coat          

0.67   

(5.6)

5)  Sealer            

0.67   

(5.6)

Semi-transparent stain

0.79

(6.6)

7)  Wash coat           

0.73   

(6.1)

(Note: An owner or operator of a wood furniture

coating operation subject to this Section shall

apply all coatings, with the exception of no more

than 37.8 1 (10 gal) of coating per day used for

touch—up and repair operations, using one or more

of the following application systems: airless

spray application system, air-assisted airless

spray application system, electrostatic spray

application system, electrostatic bell or

448

disc—spray application system, heated airless

spray application system, roller coating, brush oh

wipe coating application system, e~dip coating

application system or high volume low pressure

(HVLP)

application system.)

(Source: Amended at 

—

Ill. Reg. 

_____,

effective 

_____________

Section 219.205  

Daily—Weighted Average Limitations

No owner or operator of a coating line subject to the limitations

of Section 219.204 of this Part and complying by means of this

Section shall operate the subject coating line unless the owner

or operator has demonstrated compliance with subsection~ (a),

(b), (c), (d), (e) or (f) of this Section (depending upon the

e-ource category of coating) through the applicable coating

analysis test methods and

procedures specified in Section

219.105(a) of this Part and the recordkeeping and reporting

requirements specified in Section 219.211(d) of this Part:

a)  No owner or operator of a coating line subject to only

one of the

limitations from among Section 219.204(a) (1), (cx)(2),

(a)(4), (C),  (d), (e), (f), (g), (h), or (i) of this

Part shall apply coatings on any such coating line,

during any day, whose daily-weighted average VON

content exceeds the emission limitation to which the

coatings are subject.

b)  No owner or operator of a miscellaneous metal parts and

products coating line subject to the limitations of

Section 219.204(j) of this Part shall apply coatings to

miscellaneous metal parts or products on the subject

coating line unless the requirements in subsection

(b) (1) or (b) (2) of this Section below are met.

1)  For each coating line which applies multiple

coatings, all of which are subject to the same

numerical emission limitation within Section

219.204(j) above, during the same day (e.g., all

coatings used on the line are subject to 0.42 kg/l

(3.5 lbs/gal), the daily-weighted average VON

content shall not exceed the coating VON content

limit corresponding to the category of coating

used, or

2)  For each coating line which applies coatings

sub~iect to more than one numerical emission

limitation from more than one of the four coating

categories in Section 219.204(j) above, during the

same day, the owner or operator shall have a

449

site-specific proposal approved by the Agency and

approved by the USEPA as a 

SIP revision. To

receive approval, the requirements of USEPA’s

Emissions Trading Policy Statement (and related

policy) 51 Fed. Reg. 43814 (December 4, 1986),

must be satisfied.

c)  No owner or operator of a can coating facilityline

subject to the limitations of Section ~43~J~.204(b) Q.~

this Part shall operate the subject coating

facilityline using a coating with a VOM content in

excess of the limitations specified in Section

~24~&219.204(b)of this Part unless all of the following

requirements are met:

1)  An alternative daily emission limitation for the

can coating operation. i.e. for all the can

coating lines at the source, shall be determined

according to subsection (C)

(2) below. Actual

daily emissions shall never exceed the alternative

daily emission limitation and shall be calculated

by use of the following equation.

n

Ed

~ V~C~

i=1

where:

Ed

Actual VON emissions for the day in

i

units

Subscript

of kg/daydenoting(ibs/day)a

specific7~

n

Total

coating

number

app1iedof7~coatings

applied in

the can coating operation i.e. all

can coating lines at the source

V~

=

Volume of each coating applied for

the day in units of 1/day (gal/day)

of coating (minus water and any

compounds which are specifically

exempted from the definition of

VOM)~

C1   = The VOM content of each coating as

applied in units of kg VON/i (lbs

VOM/gal) of coating (minus water

and any compounds which are

450

specifically exempted from the

definition of VON).

2)  The alternative daily emission limitation (Ad)

shall be determined for the can coating pperation~

i.e. for all the can coating lines at the source~

on a daily basis as follows:

n

Ad

=

E V1L1j~, 

-C11

i=1

(D,

—

L.)

where:

Ad

=

The VON emissions allowed for the

day in units of kg/day (lbs/day),-.j.

Subscript 

denoting a specific

=

Totalcoatingnumberapp1iedof7~surface coatings

applied in

the can coating

operat ion-~

C1

=

The VON content of each surface

coating as applied in units of kg

VON/i (lbs VOM/gal) of coating

(minus water and any 

compounds

which are specifically exempted

from the definition of VOM)~j

D1

=

The density of VOM in each coating

applied. For the purposes of

calculating 

4~,

the density is

0. 882 kg VOM/1 VON (7.36 lbs

VON/gal VOM)T~

VI

Volume of each surface coating

applied for the day in units of 1

(gal) of coating (minus water and

any compounds which are

specifically exempted from the

definition of VOM)T~

L.

=

The VON emission limitation for

each surface coating applied as

specified in Section 219.204(b) of

this Part in units of kg VOM/l (lbs

VON/gal) of coating (minus water

and any compounds which are

451

specifically exempted from the

definition of VON).

d)  No owner or operator of a heavy off—highway vehicle

products coating line subject to the limitations of

Section 219.204(k) of this Part shall apply coatings to

heavy off-highway vehicle products on the subject

coating line unless the requirements of subsection

(d) (1) or (d) (2) below are met.

1)  For each coating line which applies multiple

coatings, all of which are subject to the same

numerical emission limitation within Section

219.204(k) above, during the same day (e.g., all

coatings

used on the line are subject to 0.42 kg/i

3.5 lbs/gal)), the daily-weighted average VON

content shall not exceed the coating VON content

limit corresponding to the category of

coating

used, or

2)  For each coating line which applies coatings

subject to more than- one numerical emission

limitation in Section 219.204(k) above, during the

same day, the owner or operator shall have a site

specific proposal approved by the Agency and

approved by the USEPA as a 

SIP revision. To

receive approval, the requirements of USEPA’s

Emissions Trading Policy Statement (and related

policy) 51 Fed. Reg. 43814 (December 4, 1986) must

be satisfied.

e)  No owner or operator of a wood furniture coating line

subject to the limitations of Section 219.204(1) g~.

this Part shall apply coatings to wood furniture on the

subject coating line unless the requirements of

subsection (e) (1) or subsection (e) (2) below, in

addition to the requirements specified in the note to

Section 219.204(1) of this Part, are met.

For each coating line which applies multiple

coatings, all of which are subject to the same

numerical emission limitation within Section

219.204(1) above, during the same day (e.g., all

coatings

used on the line are subject to 0.67 kg/l

(5.6 lbs/gal)), the daily—weighted average VON

content shall not exceed the coating VON content

limit corresponding to the category of coating

used, or

2)  For each coating line which applies coatings

subject to more than one numerical emission

limitation in Section 219.204(1) above, during the

452

same day, the owner or operator shall have a site

specific proposal approved by the Agency and

approved by the USEPA as a SIP revision. To

receive approval, the requirements of USEPA’s

Emissions Trading Policy Statement (and related

policy) 51 Fed. Req. 43814 (December 4. 1986).

must be satisfied.

(Source: Amended at  

Ill. Reg.    

,  effective 

___________

______________________ )

Section 219.206  

Solids Basis Calculation

Limitations in terms of kg (lbs) of VON emissions per 1 (gal) of

solids as applied at each coating applicator shall be determined

by the following equation:

S=

C

1

—

(C/D)

where:

S

The limitation on VON emissions in terms of

kg VON/i (lbs VON/gal) of so1idsT~

C

=

The limitation on VOM emissions in terms of

kg/l (lbs/gal) of

coating (minus water and

any compounds which are specifically excluded

from the definition of VOM) specified in

Section 2l9.2O4~~j

D

The density of VON in the coating. For the

purposes of calculating 5, the density is

0.882 kg VON/i VON (7.36 lbs VOM/gal VON).

(Source: Amended at

_____,

Ill. Reg. 

______,

effective

Section 219.207  

Alternative Emission Limitations

a)  Any owner or operator of a coating line subject to

Section 219.204 of this Part may comply with this

Section, rather than with Section 219.204 of this Part,

if a capture system and control device are operated at

all times the coating line is in operation and the

owner or operator demonstrates compliance with

subsections (c), (d), (e), (f), (g) or (h) ~o-fthis

Section (depending upon the source category) through

the applicable coating analysis and capture system and

control device efficiency test methods and procedures

specified in Section 219.105 of this Part and the

recordkeeping and reporting requirements specified in

453

Section 219.211(e) of this Part and the control device

is equipped with the applicable monitoring equipment

specified in Section 219.105(d) of this Part and the

monitoring equipment is installed, calibrated, operated

and maintained according to vendor specifications at

all times the control device is in use. A capture

system and control device, which does not demonstrate

compliance with subsection (c), (d), (e), (f), (g) or

(h) of this Section may be used as an alternative to

compliance with Section 219.204 of this Part only if

the alternative is approved by the Agency and approved

by the USEPA as a SIP revision.

b)  Alternative Add-On Control Methodologies

1)  The coating line is equipped with a capture system

and control device that provides 81 percent

reduction in the overall emissions of VOM from the

coating line and the control device has a 90

percent efficiency, or

2)  The system used to control VOM from the coating

line is demonstrated to

have an overall efficiency

sufficient to limit VON emissions to no more than

what is allowed under Section 219.204 of this

Part. Use of any control system other than an

afterburner, carbon adsorption, condensation, or

absorption scrubber system can be allowed only if

approved by the Agency and approved by the USEPA

as a SIP revision. The use of transfer efficiency

credits can be allowed only if approved by the

Agency and approved by the USEPA as a SIP

revision. Baseline transfer efficiencies and

transfer efficiency test methods must be approved

by the Agency and the USEPA.

Such overall efficiency is to be determined as

follows:

A)  eQbtain the emission limitation from the

appropriate subsection in Section 219.204 of

this Part,

B) eçalculate “5” according

to the equation in

Section 219.206 of this Part,

C) e~alculate

the overall efficiency required

according to Section 219.105(e) of this Part.

For the 

purposes of calculating this value,

according to the equation in Section

219.105(e) (2) of this Part, VON1 is equal to

454

the value of “5” as determined above in

subsection (b) (2) (B) of this Section.

C)   No owner or operator of a coating line subject to only

one of the emission limitations from among Section.

219.204(a)(1y, (a)(2), (a)(4), (c), (d), (e), (f), (g),

(h) or (i) of this Part and equipped with a capture

system and control device shall operate the subject

coating line unless the requirements in subsection

(b) (1) or (b) (2) above are met. No owner or operator

of a coating line subject to Section 219.204 (a) (2) or

(a) (3) of this Part and equipped with a capture system

and control device shall operate the coating line

unless the owner or operator demonstrates compliance

with the topcoat such limitation in accordance with the

topcoat protocol for automobile or light-duty trucks

referenced 

in Section 219.105(b) ~ this Part.

d)  No owner or operator of a miscellaneous metal parts and

products coating line which applies one or more

coatings during the same day, all of which are subject

to

the same numerical emission limitation within

Section 219.204(j) of this Part (e.g., all coatings

•used on the line are subject to 0.42 kg/i 3.5

lbs/gal)), and which is equipped with a capture system

and control device shall operate the subject coating

line unless the requirements in subsection (b) (1) or

(b) (2) above are met.

e) No owner or operator of

a heavy off—highway vehicle

products coating line which applies one or more

coatings during the same day, all of which are subject

to the same numerical emission limitation within

Section 219.204(k) (e.g., all coatings used on the line

are subject to 0.42 kg/l (3.5 lbs/gal)), and which is

equipped with a capture system and control device shall

operate the subject coating line unless the

requirements in subsection (b) (1) or (b) (2) above are

met.

4-

No owner or operator of anexiGtingdi000l-electric

coatingo during the o~rncday, 

all of which are subject

to the same numerical omission 

limitation within

Section 219.204(m) (e.g., all 

coatings used on the line

arc subject to 0.42 kg/i 3.5 

lbs/gal)), and which is

~tn~ir~rir’~i uith r~ caoturc sy~i-r.m rrna~ ~n rri~t 

~ir~ij4r~r~ ~ih~11

epcr3tc the ~

-,.—...~-..

~-i~ unl.~~thc

requirements in subsection (b)(1) or (b)(2) are met.

g-)-fl No owner or operator of a wood furniture coating line

which applies one or more coatings during the same day,

455

all of which are subject to the same numerical emission

limitation within Section 219.204(1) of this Part

(e.g., all coatings used on the line are subject to

0.67 kg/i 5.6 lbs/gal), and which is equipped with a

capture system and control device shall operate the

subject coating line unless the requirements in

subsection (b) (1) or (b) (2)

of this Section are met.

If compliance is achieved by meeting the requirements

in subsection (b) (2) of this Section, then the

provisions in the note to Section 219.204(1) of this

Part must also be met.

~+g1 No owner or operator of a can coating facilityline and

equipped with a capture system and control device shall

operate the subject coating facilityline unless the

requirements in subsection (h) (1) or (h) (2) below are

met.

1)  An alternative daily emission limitation for the

can coating operation, i.e. for all the can

coating lines at the source, shall be determined

according to Section 219.205(c) (2) of this Part.

Actual daily emissions shall never exceed the

alternative daily emission limitation and shall be

calculated by use of the following equation:

n

Ed

E

i=i

V1 C1 (1—F1

where:

Ed

Actual VON emissions for the day in

units of kg/day (lbs/day)-~-j.

i

=

Subscript denoting the specific

n

Total

coating

number

applied

of

7~

surface coatings as

applied in the can coating

operation-7-j.

V1

=

Volume of each coating as applied

for the day in units of 1/day

(gal/day) of coating (minus water

and any compounds which are

specifically exempted from the

definition of VON),-~

C1

The VON content of each coating as

applied in units of kg VON/i (lbs

456

VON/gal) of coating (minus water

and any compounds which are

specifically exempted from the

definition of VOM)j.

F1

=

Fraction, by weight, of VON

emissions from the surface coating,

reduced or prevented from being

emitted to the ambient air. This is

the overall efficiency of the

capture system and control device~

The coating line is equipped with a capture system

and control device that provide 75 percent

reduction

in the overall emissions of VON from the

coating line and the control device has a 90

percent efficiency.

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

____________

_________________________ )

Section 219.208  

Exemptions From Emission Limitations

a)  Exemptions for all sourcecoating categories except wood

furniture coating. The limitations of this Subpart

shall not apply to coating lines within a

facilit-ysource, 

that otherwise would

be subject to the

same subsection of Section 219.204 (because they belong

to the same co-urcccoating category, e.g. can coating),

provided that combined actual emissions of VON from all

lines at the facilitysource subject to that subsection

never exceed 6.8 kg/day (15 lbs/day) before the

application of capture systems and control devices.

(For example, can coating lines within a piantsource

would not be subject to the limitations of Section

219.204(b) of this Part if the combined actual

emissions of VON from the can coating lines never

exceed 6.8 kg/day (15 lbs/day) before the application

of capture systems and control devices.) Volatile

organic material emissions from heavy 

off-highway

vehicle products coating lines must be combined with

VON emissions from miscellaneous metal parts and

products coating lines to determine applicability. Any

owner or operator of a coating f~acilitysourceshall

comply with the applicable coating analysis test

methods and procedures specified in Section 219.105(a)

of this Part and the recordkeeping and reporting

requirements specified in Section 219.211(a) of this

Part if total VON emissions from the subject coating

lines are always less than or equal to 6.8 kg/day

(15 lbs/day) before the application of capture systems

457

and control devices and, therefore, are not subject to

the limitations of Section 219.204 of this Part. Once

a category of coating lines at a facilitysource

subject to the limitations in Section 219.204 of this

Part, the coating lines are always subject to the

limitations in Section 219.204 of this Part.

b)  Applicability for wood furniture coating

1)  The limitations of this Subpart shall apply to a

plant’ssource’s wood furniture coating lines if

the plantsource contains process emission

oourccsunits, not regulated by Subparts B, E, F

(excluding Section 219.204(1) of this Part), H

(excluding Section 219.405 of this Part), Q, R, S,

T (excluding Section 219.486 of this Part). V, X,

1, e~Z or BB of this Part, which as a group both:

hfjave maximum theoretical

emissions of 91 Mg

(100 tons) or more per calendar year of VON

if no air pollution control equipment were

used, and

B)  eAre not limited to less than 91 Mg

(100 tons) of VON per calendar year if no air

pollution control equipment were used,

through production or capacity limitations

contained in a federally enforceable

construction permit or SIP revision.

2)  If a plantsource ceases to fulfill the criteria of

subsection (b) (1) of this Section, the limitations

of Section 219.204(1) of this Part shall continue

to apply to any wood furniture coating line which

was ever subject to the limitations of Section

219.204(1) of this Part.

3)  For the purposes of subsection (b) of this

Section, 

an emission

sourceunit shall be

considered regulated by a Subpart if it is subject

to the limitations of that Subpart. An emission

courceunit is not considered regulated by a

Subpart if it is not subiect to the limits of that

Subpart. e.g.. the emission unit is covered by an

exemption in the Subpart or the applicability

criteria of the Subpart are not met. its cmissioi~-s

arc below the applicability cutoff level or if 

the

source is covered by an exemption.

4)  Any owner or operator of a wood furniture coating

line to which the limitations of this Subpart are

not applicable due to the criteria in subsection

458

(b) of this Section shall, upon request by the

Agency or the USEPA, submit records to the Agency

and the USEPA within 30 calendar days from the

date of the request that document that the coating

line is exempt from the limitations of this

Subpart.

(Source: Amended at  

Iii. Reg. 

______,

effective 

____________

Section 219.209  

Exemption From General Rule on Use of Organic

Material

No owner or operator of a coating line subject to the limitations

of Section 219.204 of this Part is required to meet the

limitations of Subpart G (Section 219.301 or 219.302) of this

Part, after the date by which the coating line is required to

meet Section 219.204 of this Part.

(Source: Amended at 

—

Ill. Peg. 

______,

effective 

____________

Section 219.210  

Compliance Schedule

Every owner or operator of a coating line (of a type included

within Section 219.204 of this Part) shall comply with the

requirements of Section 219.204, 219.205. 219.207 or 219.208 and

Section 219.211 of this Part in accordance with the appropriate

compliance schedule as specified in subsection (a), (b), (c) or

(d) below:

a)  No owner or operator of a coating line which is exempt

from the limitations of Section 219.204 of this Part

because of the criteria in Section 219.208(a) of this

Part shall operate said coating line on or after a date

consistent with Section 219.106 of this Part, unless

the owner or operator has complied with, and continues

to comply with, Section 219.211(b) of this Part. Wood

furniture coating lines are not

subject to Section

219.211(b) of this Part.

b)  No owner or operator of a coating line complying by

means of Section 219204 of this Part shall operate

said coating line on or after a date consistent with

Section 219.106 of this Part, unless the owner or

operator has complied with, and continues to comply

with, Sections 219.204 and 219.211(c) of this Part.

c)  No owner or operator of a coating line complying by

means of Section 219.205 of this Part shall operate

said coating line on or after a date consistent with

Section 219.106 of this Part, unless the owner or

459

operator has complied with, and continues to comply

with, Sections 219.205 and 219.211(d) of this Part.

d)  No owner or operator of a coating line complying by

means of Section 219.207 of this Part shall operate

said coating line on or after a date consistent with

Section 219.106 of this Part, unless the owner or

operator has complied with, and continues to comply

with, Sections 219.207 and 219.211(e) of this Part.

(Source: Amended at  

Ill. Reg. 

______,

effective 

_________

Section 219.211  

Recordkeeping and Reporting

a)  The VOM content of each coating and the efficiency of

each capture system and control device shall be

determined by the applicable test methods and

procedures specified in Section 219.105 of this Part to

establish the records required under this Section.

b)  Any owner or operator of a coating line which is

exempted from the limitations of Section 219.204 p~

this Part because of Section 219.208(a) of this Part

shall comply with the following:

1)  By a date consistent with Section 219.106 of this

Part, the owner or operator of a facilitycoating

line or group of coating lines referenced in this

subsection 

1kJ.~. 

of this Section shall certify to

the Agency that the facilitycoating line or group

of coating lines is exempt under the provisions of

Section 219.208(a) of this Part. Such 

certification shall include:

A)  A declaration that the facilitycoating line

is exempt from the limitations of Section

219.204 of this Part because of Section

219.208(a) of this Part and

B)  Calculations which demonstrate that the

combined VON emissions from a-~the coating

line and all other coating lines in the same

category at the facility never exceed 6.8 kg

(15 lbs) per day before the application of

capture systems and control devices. The

following equation shall be used to calculate

total VON emissions:

460

mn

Te

=

E (A1 B1)~

j=1 i=1

where:

Te~=Total VON emissions from coating lines

at a facility each day before the

application of capture systems and

control devices in units of kg/day

(lbs/day)~~

in

=

Number of coating lines at the

f-a-oilitysource that otherwise would

be subiect to the same subsection

of Section 219.104 of this Part

(because they belong to the same

category, e.g.. can coating)~-j

j

Subscript denoting an individual

coating 1ine-~-:

n

Number of different coatings as

applied each day on each coating

line at the fncility,~

=

Subscript denoting an individual

coat i ng-~-~

A

Weight of VON per volume of each

coating (minus water and any

compounds which are specifically

exempted from the definition of

VON) as applied each day on each

coating line at the facility in

units of kg VOM/l (lbs VON/gal)~

B1

Volume of each coating (minus water

and any compounds which are

specifically exempted from the

definition of VON) as applied each

day on each coating line at the

facility in units of 1/day

(gal/day). The instrument or

method by which the owner or

operator accurately measured or

calculated the volume of each

coating as applied on each coating

line each day shall be described in

the certification to the Agency.

461

2)  On and after a date consistent with Section

219.106 of this Part, the owner or operator of a

facilitycoating

line or group of lines referenced

in this subsection shall collect and record all of

the following information each day for each

coating line and maintain the information at the

facilitysource for a period of three years:

A)  The name and identification number of each

coating as applied on each coating line.

B)  The weight of VON per volume and the volume

of each coating (minus water and any

compounds which are specifically exempted

from the definition of VON) as applied each

day on each coating line.

3)  On and after a date consistent with Section

219.106 of this Part, the owner or operator of a

facilitycoating line or group of coating lines

exempted from the limitations of Section 219.204

of this Part because of Section 219.208(a) of this

Part shall notify the Agency of any record showing

that total VOM emissions from the coating

facilityline or group of coating lines exceed

6.8 kg (15 lbs) in any day before the application

of capture systems and control devices by sending

a copy of such record to the Agency within 30 days

after the exceedance occurs.

c)  Any owner or operator of a coating line subject to the

limitations of Section 219.204 of this Part other than

Section 219.204(a) (2) and (a)(3) and complying by means

of Section 219.204 of this Part shall comply with the

following:

1)  By a date consistent with Section 219.106 of this

Part, or upon initial start—up of a new coating

line, or upon changing the method of compliance

from an existing subject coating line from Section

219.205 or Section 219.207 to Section 219.204 ~

this Part the owner or operator of a subject

coating line shall certify to the Agency that the

coating line will be in compliance with Section

219.204 of this Part on and after a date

consistent with Section 219.106 of this Part, or

on and after the initial start-up date. Such

certification shall include:

A)  The name and identification number of each

coating as applied on each coating line.

462

B)  The weight of VON per volume of each coating

(minus water and any compounds which are

specifically exempted from the definition of

VOM) as applied each day on each coating

line.

?-)-  

For coating

lines 

subject to Section

219.204 (a) (3) certification shall inoludc~

4-)-   The name and identification number of

each ~

line

m~.Jr1LJ w

E~CCt~iri

—--~

. ~.~LJ-_ I

~ I

comply by

The name and identification number of

each coating as applied on erich coating

line,

iii) The weight of VON per volume of each

coating as applied on each coating line,

...nstrument or method by which the

owner or operator will 3ccurate~y

measure or calculate the volume of each

co~tina

~r1i~d each 

d~iv

on each

coating i~inc,

~)-

The method by which the owner or

onrn-atpr

will create rind maintain

rrt~nri1’~

r~ic~hti:iv

~ r~r1uir-cp

in

QUDSCCt1Ofl (C) 

(~)

OCIOW 

ror

Cpp1in~

rr~t to Section 219.204(a) (3),

~4-- An example format in which the records

required in subsection (c) (2) below for

coating lines subject to Cection

219.204(a) (3)

2)  On and after a date consistent with Section

219.106 of this Part, or on and after the initial

start-up date, the owner or operator of a sublect

coating line subject to the limitations of Section

2~9.204 and complying by means of Section 219.204

shall collect and record all of the following

information each day for each coating line and

maintain the information at the facility source

for a period of three years:

A)  The name and identification number of each

coating as applied on each coating line.

B)  The weight of VON per volume of each coating

(minus water and any compounds which are

463

specifically exempted from the definition of

VON) as applied each day on each coating

line.

___I___~__a_

ã_~_ ~

—

‘I

maintain 

~

dail2 ~

~nrr—n 

n~.rerrige vufl content

fmm

the coating line in aooordanoc with the

proposal submitted, and approved by the

UCEPA, pursuant to Section 218 

•

204 (a) (3).

3)  On and after a date consistent with Section

219.106 of this Part, the owner or operator of a

subject coating line shall notify the Agency in

the following instances:

A)

B)  At least 30 calendar days before changing the

method of compliance with Section 219.204

from Section 219.204 to Section 219.205 or

Section 219.207 of this Part, the owner or

operator shall comply with all requirements

of subsection (d) (1) or (e) (1) below,

respectively. Upon changing the method of

compliance with Section 219.204 from Section

219.204 to Section 219.205 or Section 219.207

of this Part, the owner or operator shall

comply with all requirements of subsection

(d) or (e) of this Section, respectively.

£--   

For coating lines subject to Section

219.204(a) (3), the owner or ~n~r~tor ~naii

notjfv the Agency or any onange

topcoating operation at least 30 days before

the change is effected. The Agency shall

d~t~rminc~

~jhc±heror not determines that

n testing is required, then

4.~.

~

--~~~~‘‘

1 to

.J-.

Any record showing violation of Section

219.204 of this Part shall be reported by

sending a copy of such record to the Agency

within 30 days following the occurrence of

the violation, except that any record showing

a violation of Section 219.204 (a) (3) shall be

reported by sending a copy of such record to

the Agency within 15 days from the end of the

month in which the violation occurred.

the Agency to tc3t within 30 dayc

~..

~#a~

464

d)  Any owner or operator of a coating line subject to the

limitations of Section 219.204 of this Part and

complying by means of Section 219.205 of this Part

shall comply with the following:

1)  By a date consistent with Section 219.106 of this

Part, or upon initial start—up of a new coating

line, or upon changing the method of compliance

for an existing subject coating line from Section

219.204 or Section 219.207 to Section 219.205 Q~.

tkis Part the owner or operator of the subject

coating line shall certify to the Agency that the

coating line will be in compliance with Section

219.205 on and after a date consistent with

Section 219.106 of this Part, or on and after the

initial start—up date. Such certification shall

include:

A)  The name and identification number of each

coating line which will comply by means of

Section 219.205 of this Part.

B)  The name and identification number of each

coating as applied on each coating line.

C)  The weight of VON per volume and the volume

of each coating (minus water and any

compounds which are specifically exempted

from the definition of VON) as applied each

day on each coating line.

D)  The instrument or method by which the owner

or operator will accurately measure or

calculate the volume of each coating as

applied each day on each coating line.

E)  The method by which the owner or operator

will create and maintain records each day as

required in subsection (d) (2) of this

Section.

F)  An example of the format in which the records

required in subsection (d) (2) of this Section

will be kept.

2)  On and after a date consistent with Section

219.106 of this Part, or on and after the initial

start-up date, the owner or operator of a subiect

coating line oubject to the limitations of &ecti-e~

ma compuying by means of Section 219.205

shall collect and record all of the following

information each day for each coating line and

465

maintain the information at the facilitysource for

a period of three years:

A)  The name and identification number of each

coating as applied on each coating line.

B)  The weight of VON per volume and the volume

of each coating (minus water and any

compounds which are specifically exempted

from the definition of VON) as applied each

day on each coating line.

C)  The daily-weighted average VON content of all

coatings as applied on each coating line as

defined in Section 219.104 of this Part.

3)  On and after a date consistent with Section

219.106 of this Part, the owner or operator of a

subject coating line shall notify the Agency in

the following instances:

A)  Any record showing violation of Section

219.205 of this Part shall be reported by

sending a copy of such record to the Agency

within 30 days following the occurrence of

the violation.

B)  At least 30 calendar days before changing the

method of compliance with this subpart from

Section 219.205 to Section 219.204 or Section

219.207 of this Part, the owner or operator

shall comply with all requirements of

subsection (c) (1) or (e) (1) of this Section,

respectively. Upon changing the method of

compliance with this subpart from Section

219.205 to Section 219.204 or Section 219.207

of this Part, the owner or operator shall

comply with all requirements of subsection

(c) or (e) of this Section, respectively.

e)  Any owner or operator of a coating line subject to the

limitations of Section 219.207 and complying by means

of Section 219.207(c), (d), (e), (f), (g) or (h) ~

this Part shall comply with the following:

1)  By a date consistent with Section 219.106 of this

Part, or upon initial start—up of a new coating

line, or upon changing the method of compliance

for an existing coating line from Section 219.204

or Section 219.205 to Section 219.207 of this

Part, the owner or operator of the subject coating

line shall perform all tests and submit to the

466

Agency the results of all tests and calculations

necessary to demonstrate that the subject coating

line will be in compliance with Section 219.207 

QZ.

this Part on and after a date consistent with

Section 219.106 of this Part, or on and after the

initial start-up date.

2)  On and after a date consistent with Section

219.106 of this Part, or on and after the initial

start-up date, the owner or operator of a coating

line subject to the limitations of Section 219.207

subiect and complying by means of Section

219.207(c), (d), (C),  (f), (g), or (h) shall

collect and record all of the following

information each day for each coating line and

maintain the information at the facilitysource for

a period of- three years:

A)  The weight of VON per volume of coating

solids as applied each day on each coating

line, if complying pursuant to Section

219.207(b) (2) of this Part.

B)  Control device monitoring data.

C)  A log of operating time for the capture

system, control device, monitoring equipment

and the associated coating line.

D)  A maintenance log for the capture system,

control device and monitoring equipment

detailing all routine and non-routine

maintenance performed including dates and

duration of any outages.

3)  On and after a date consistent with Section

219.106 of this Part, the owner or operator of a

subject coating line shall notify the Agency in

the following instances:

A)  Any record showing violation of Section

219.207 of this Part shall be reported by

sending a copy of such record to 

the Agency

within 30 days following the occurrence of

the violation.

B)  At least 30 calendar days before changing the

method of compliance with this Subpart from

Section 219.207 to Section 219.204 or Section

219.205 of this Part, the owner or operator

shall comply with all requirements of

subsection (c) (1) or (d) (1) of this Section,

467

respectively. Upon changing the method of

compliance with this subpart from Section

219.207 to Section 219.204 or Section 219.205

of this Part, the owner or operator shall

comply with all requirements of subsection

(c) or (d) of this Section, respectively.

fl

AnY owner or operator of a primer surfacer operation or

topcoat operation subject to the limitations of Section

219.204(a) (2) or (a)(3)of this Part shall com~lvwith

the following:

fl

By a date consistent with Section 219.106 of this

Part, or upon initial start—up of a new coating

operation. the owner or operator of a subject

coating operation shall certify to the A~encv that

the operation will be in compliance with Section

219.204 of this Part on and after a date

consistent with Section 219.106 of this Part, or

on and after the initial start—up date. Such

certification shall include:

~  The name and identification number of each

coating operation which will comply bY means

of Section 219.204(a) (2) and (a) (3) of this

Part and the name and identification number

of each coating line in each coating

operation.

~j The name and identification number of each

coating as applied on each coating line in

the coating operation.

çj  The weight of VON ~er volume of each coating

(minus water and any compounds which are

specifically exemPted from the definition of

VOM) as applied each day on each coating

line.

~j The transfer efficiency and control

efficiency measured for each coating line.

~j. Test reports. including raw data and

calculations documenting the testing

performed to measure transfer efficiency and

control efficiency.

fi

The instrument or method by which the owner

or operator will accurately measure or

calculate the volume of each coating as

applied each day on each coating line.

468

QI

The method by which the owner or operator

will create and maintain records each day as

reauired in subsection (f) (2) below.

~j An example format for presenting the records

required in subsection (f) (2) below.

j).  On and after a date consistent with Section

219.106 of this Part, or on and after the initial

start—up date, the owner or operator of a subiect

coating operation shall collect and record all of

the following information each day for each

topcoat or primer surfacer coating operation and

maintain the information at the source for a

period of three years:

~j.. All information necessary to calculate the

daily-weighted average VON emissions from the

coating operations in kg (ibs) per 1 (gal) of

coating solids deposited in accordance with

the ~ro~osa1 submitted, and approved pursuant

to Section 219.204(a) (2) or (a)(3) of this

Part including:

The name and identification number of

each coating as applied on each coating

operation.

j   The weight of VON per volume of each

coating (minus water and any compounds

which are specifically exempted from the

definition of VON) as applied each day

on each coating operation.

~j If a control device(s) is used to control VON

emissions, control device monitoring data; a

log of operating time for the capture system,

control device, monitoring equipment and the

associated coating operation; and a

maintenance 1o~for the capture system,

control device and monitoring equipment,

detailing all routine and non-routine

maintenance performed including dates and

duration of any outages.

~  On and after a date consistent with Section

219.106 of this Part or on and after the initial

start—up date, the owner or operator of a subiect

coating operation shall determine and record the

daily VON emissions in kg(lbs) per 1 (gal) of

coating solids deposited in accordance with the

proposal submitted and approved pursuant to

469

Section 219.204(a) (2) or (a)(3) of this Part

within 10 days from the end of the month and

maintain this information at the source for a

period of three years.

4j~. 

On and after a date consistent with Section

219.106 of this Part, the owner or operator of a

subiect coating operation shall notify the Agency

in the following instances:

~j Any record showing a violation of Section

219.204(a) (2) or (a)(3) of this Part shall be

reported by sending a co~vof such record to

the A~encvwithin 15 days from the end of the

month in which the violation occurred.

.~J

The owner or operator shall notify the Agency

of any change to the operation at least 30

days before the change is effected. The

Agency shall determine whether or not

compliance testing is required. If the

Agency determines that compliance testing is

required, then the owner or operator shall

submit a testing proposal to the Agency

within 30 days and test within 30 days of the

approval of the proposal by the Agency and

US EPA.

(Source: Amended at  

Ill. Reg. 

______,

effective 

____________

SUBPART G: USE OF ORGANIC MATERIAL

Section 219.301  

Use of Organic Material

No person shall cause or allow the discharge of more than 3.6

kg/hr (8 lbs/hr) of organic material into the atmosphere from any

emission sourceunit, except as provided in Sections 219.302,

219.303, 219.304 of this Part and the following exception: If no

odor nuisance exists the limitation of this Subpart shall apply

only to photochemically reactive material.

(Source: Amended at —  Ill. Reg. 

______,

effective 

____________

Section 219.302  

Alternative Standard

Emissions of organic material in excess of those permitted by

Section 219.301 of this Part are allowable if such emissions are

controlled by one of the following methods:

470

a)  Flame, thermal or catalytic incineration so as either

to reduce such emissions to 10 ppm equivalent methane

(molecular weight 16) or less, or to convert 85 percent

of the hydrocarbons to carbon dioxide and water; or,

b)  A vapor recovery system which adsorbs and/or condenses

at least 85 percent of the total uncontrolled organic

material that would otherwise be emitted to the

atmosphere; or,

c)  Any other air pollution control equipment approved by

the Agency and approved by the USEPA as a SIP revision

capable of reducing by 85 percent or more the

uncontrolled organic material that would be otherwise

emitted to the atmosphere.

(Source: Amended at  

Ill. Reg. 

______,

effective 

____________

Section 219.303  

Fuel Combustion Emission CourccsUnits

The provisions of Sections 219.301 and 219.302 of this Part shall

not apply to fuel combustion emission sourcesunits.

(Source: Amended at —  Ill. Reg. 

______,

effective 

____________

Section 219.304  

Operations with Compliance Program

The provisions of Sections 219.301 and 219.302 of this Part shall

not apply to any owner, operator, user or manufacturer of paint,

varnish, lacquer, coatings or printing ink whose compliance

program and project completion schedule, as required by 35 Ill.

Adm. Code 201, provided for the reduction of organic material

used in such process to 20 percent or less of total volume by May

30, 1977.

(Source: Amended at —  Ill. Reg. 

______,

effective 

____________

SUBPART H: PRINTING AND PUBLISHING

Section 219.401  

Flexographic and Rotogravure Printing

a)  No owner or operator of a subject flexographic,

packaging rotogravure or publication rotogravure

printing line shall apply at any time any coating or

ink unless the VON content does not exceed the

limitation specified in either subsection (a) (1) or

(a) (2) below. Compliance with this Section must be

demonstrated through the applicable coating or ink

analysis test methods and procedures specified in

471

Section 219.105(a) and the recordkeeping and reporting

requirements specified in Section 219.404(c) of this

Part. As an alternative to compliance with this

subsection, a subject printing line may meet the

requirements of subsection (b) or (c) below.

1)  Forty percent VON by volume of the coating and ink

(minus water and any compounds which are

specifically exempted from the definition of VON),

or

2)  Twenty-five percent VON by volume of the volatile

content in the coating and ink.

b)  No owner or operator of a subject flexographic,

packaging rotogravure or publication rotogravure

printing line shall apply coatings or inks on the

subject printing line unless the weighted average, by

volume, VON content of all coatings and inks as applied

each day on the subject printing line does not exceed

the limitation specified in either subsection (a) (1)

(as determined by subsection (b) (1)1 or subsection

(a) (li)) (as determined by subsection (b) (2) of this

Section). Compliance with this subsection must be

demonstrated through the applicable coating or ink

analysis test methods and procedures specified in

Section 219.105(a) of this Part and the recordkeeping

and reporting requirements specified in Section

219.404(d) of this Part.

1)  The following equation shall be used to determine

if the weighted average VON content of all

coatings and inks as applied each day on the

subject printing line exceeds the limitation

specified in subsection (a) (1) of this Section.

n

E  C~L1 (V~~+

i=4 1

VOM(~A) 

n

E  L (V81 + V~0~)

i=4-l

Where:

VOM(I)(A)   

The weighted average VON content in

units of percent VON by volume of

all coatings and inks (minus water

472

and any compounds which are

specifically exempted from the

definition of VON) used each day-ri

I

=

Subscript denoting a specific

coating or ink as applied,-j

n

=

The number of different coatings

and/or inks as applied each day on

a printing 1ine,-~

CI

=

The VON content in units of percent

VON by volume of each coating or

ink as applied (minus water and any

compounds which are specifically

exempted from the definition of

VON)-~-j~

L,

The liquid volume of each coating

or ink as applied in units of 1

(gal)-~-~

V11

=

The volume fraction of solids in each

coating or ink as applied, and~

VVOMI 

The volume fraction of VON in each

coating or ink as applied.

2)  The following equation shall be used to determine

if the weighted average VON content of all

coatings and inks as applied each day on the

subject printing line exceeds the limitation

specified in subsection (a) (2) of this Section.

n

E  C1 L1 V~

VOM(j)m   

i=1

n

E  L1V~~

i=1

where:

VOM(I)~)  

=

The weighted average VOM content in

units of percent VON by volume of

the volatile content of all

coatings and inks used each day~

i

=

Subscript denoting a specific coating or

ink as applie~,j..

473

n

=

The number of different coatings and/or

inks as applied each day on each

printing linei.

Cl

=

The VON content in units of percent VON

by volume of the volatile matter in each

coating or ink as

applied,-.j

L,   =  The liquid volume of each coating or ink

as applied in units of 1 (gal), and~

The volume fraction of volatile matter

in each coating or ink as applied.

c)  No owner or operator of a subject flexographic,

packaging rotogravure or publication rotogravure

printing line equipped with a capture system and

control device shall operate the subject printing line

unless the owner or operator meets the requirements in

subsection (c) (1), (c) (2) or (c) (3) and subsections

(C) (4) ,  (c) (5) and (C) (6) below.

1)  A carbon adsorption system is used which reduces

the captured VON emissions by at least 90 percent

by weight, or

2)  An incineration system is used which reduces the

captured VON emissions by at least 90 percent by

weight, or

3)  An alternative VOM emission reduction system is

used which is demonstrated to have at least a

90 percent control device efficiency, approved by

the Agency and approved by USEPA as a SIP

revision, and

4)  The printing line is equipped with a capture

system and control device that provides an overall

reduction in VON emissions of at least:

A)  75 percent where a publication rotogravure

printing line is employed, or

B)  65 percent where a packaging rotogravure

printing line is employed, or

C)  60 percent where a flexographic printing line

is employed, and

474

5)  The control device is equipped with the applicable

monitoring equipment specified in Section

219.105(d) (2) of this Part and., except as provided

in Section 219.105(d) (3) of this Part, the

monitoring equipment is installed, calibrated,

operated and maintained according to vendor

specifications at all times the control device is

in use, and

The capture system and control device are operated

at all times when the subject printing line is in

operation. The owner or operator shall

demonstrate compliance with this subsection by

using the applicable capture system and control

device test methods and procedures specified in

Section 219.105(c) of this Part through Section

219.105(f) of this Part and by complying with the

recordkeeping and reporting requirements specified

in Section 219.404(e) of this Part.

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

____________

_________________________ )

Section 219.402  

Applicability

a)  The limitations of Section 219.401 of this Part apply

to all flexographic and rotogravure printing lines at a

subject facilitysource. All faciliticssources with

flexographic and/or rotogravure printing lines are

subject facilitiessources unless:

1)  Total maximum theoretical emissions of VOM from

all flexographic and rotogravure printing line(s)

(including solvents used for cleanup operations

associated with flexographic and rotogravure

printing line(s)), at the facilitysource never

exceed 90.7 Mg 100 tons) per calendar year before

the application of capture systems and control

devices, or

2)  A federally enforceable construction permit or SIP

revision for all flexographic and rotogravure

printing line(s) at a facilitysource requires the

owner or operator to limit production or capacity

of these printing line(s) to reduce total VON

emissions from all flexographic and rotogravure

printing line(s) to 90.7 Mg (100 tons) or less per

calendar year before the application of capture

systems and control devices.

b)  Upon achieving compliance with this Subpart, the

emission source isflexographic and rotogravure printing

475

lines are not required to meet Subpart G (Sections

219.301 or 219.302 of

this Part). Emission sources

Flexographic and rotogravure printing lines exempt from

this Subpart are subject to Subpart G (Sections 219.301

or ~2j~.~02

of this Part).

Rotogravure or

flexographic equipment used for both roll printing and

paper coating is subject to this Subpart.

c)  Once subject to the limitations of Section 219.401 QZ.

this Part, a flexographic or rotogravure printing line

is always subject to the limitations of Section 219.401

of this Part.

d)  Any owner or operator of any flexographic or

rotogravure printing line that is exempt from the

limitations of Section 219.401 of this Part because of

the criteria in this Section is subject to the

recordkeeping and reporting requirements specified in

Section 219.404(b) of this Part.

(Source: Amended at —  Ill. Reg. 

______,

effective 

____________

Section 219.403  

Compliance Schedule

Every owner or operator of a flexographic and/or rotogravure

printing line shall comply with the applicable requirements of

Section 219.401 and Section 219.404 of this Part in accordance

with the applicable compliance schedule specified in subsection

(a) ,   (b) ,   (c) or (d) below:

a)  No owner or operator of a flexographic or rotogravure

printing line which is exempt from the limitations of

Section 219.401 of this Part because of the criteria in

Section 219.402 of this Part shall operate said

printing line on or after a date consistent with

Section 219.106 of this Part, unless the owner or

operator has complied with, and continues to comply

with, Section 219.404(b) of this Part.

b)  No owner or operator of a flexographic or rotogravure

printing line complying by means of Section 219.401(a)

of this Part shall operate said printing line on or

after a date consistent with Section 219.106 of this

Part, unless the owner or operator has complied with,

and continues to comply with, Section 219.401(a) 

Q~.

this Part and Section 219.404(c) of this Part.

c)  No owner or operator of a flexographic or rotogravure

printing line complying by means of Section 219.401(b)

of this Part shall operate said printing line on or

after a date consistent with Section 219.106 of this

476

Part,

unless the owner or operator has complied with,

and continues to comply with, Section 219.401(b) and

Section 219.404(d) of this Part.

d)  No owner or operator of a flexographic or rotogravure

printing line complying by means of Section 219.401(c)

of this Part shall operate said printing line on or

after a date consistent with Section 219.106 of this

Part, unless the owner or operator has complied with,

and continues to comply with, Section 219.401(c) and

Section 219.404(e) of this Part.

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

___________

Section 219.404  

Recordkeeping and Reporting

a)  The VON content of each coating and ink and the

efficiency of each capture system and control device

shall be determined by the applicable test methods and

procedures specified in Section 219.105 of this Part to

establish the records required under this Section.

b)  Any owner or operator of a printing line which is

exempted from the limitations of Section 219.401 Q~

this Part because of the criteria in Section 219.402 ~

this Part shall comply with the following:

1)  By a date consistent with Section 219.106 of this

Part, the owner or operator of a

-focilityflexographic and rotogravure printing line

to which this subsection is applicable shall

certify to the Agency that the -facility

flexographic and rotogravure printing line is

exempt under the provisions of Section 219.402 Q~

this Part. Such certification shall include:

A)  A declaration that the facilityflexographic

and rotogravure printing line is exempt from

the limitations of the criteria in Section

219.401 because of Section 219.402 of this

Part, and

B)  Calculations which demonstrate that total

maximum theoretical emissions of VON from all

flexographic and rotogravure printing lines

at the ~ci1itysource never exceed 90.7 Mg

(100 tons) per calendar year before the

application of

capture systems and control

devices. Total maximum theoretical emissions

of VON for a flexographic or rotogravure

printing facilitysource is the sum of maximum

477

theoretical emissions of VON from each

flexographic and rotogravure printing line at

the facilitysource. The following equatior.

shall be used to calculate total maximum

theoretical emissions of VON per calendar

year before the application of capture

systems and control devices for each

flexographic and rotogravure printing line at

the facilitysource:

E~=AxB+ 1095 (CxDxF)

where:

E~

=

Total maximum theoretical emissions

of VOM from one flexographic or

rotogravure printing line in units

of kg/year (lbs/year)~

A

Weight of VON per volume of solids

of the coating or ink with the

highest VON content as applied each

year on the printing line in units

of kg VOM/l (lbs VON/gal) of

coating or ink solids

and~

B  =  Total volume of solids for all

coatings and inks that can

potentially be applied each year on

the printing line in units of

1/year (gal/year). The instrument

and/or method by which the owner or

operator accurately measured or

calculated the volume of each

coating and ink as applied and the

amount that can potentially be

applied each year on the printing

line shall be described in the

certification to the Agency-~

C

Weight of VOM ~er volume of

material for the cleanup material

or solvent with the highest VON

content as used each year on the

printing line in units of 

K~l1 

(lbs

VOM/~al) of such material;

The greatest volume of cleanup

material or solvent used in any

8-hour period

478

The highest fraction of cleanup

material or solvent which is ii~t

recycled or recovered for offsit~

disposal during any 8—hour perioth

2)  On and after a date consistent with Section

219.106 of this Part, the owner or operator of a

facility referenced in this subsection shall

collect and record all of the following

information each year for each printing line and

maintain the information at the facilitysource for

a period of three years:

A)  The name and identification number of each

coating and ink as applied on each printing

line.

B)  The VON content and the volume of each

coating and ink as applied each year on each

printing line.

3)  On and after a date consistent with Section

219.106 of this Part, the owner or operator of a

facility exempted from the limitations of Section

219.401 of this Part because of the criteria in

Section 219.402 of this Part shall notify the

Agency of any record showing that total maximum

theoretical emissions of VON from all printing

lines exceed 90.7 Mg (100 tons) in any calendar

year before the application of capture systems and

control devices by sending a copy of such record

to the Agency within 30 days after the exceedance

occurs.

c)  Any owner or operator of a printing line subject to the

limitations of Section 219.401 of this Part and

complying by means of Section 219.401(a) of this Part

shall comply with the following:

1)  By a date consistent with Section 219.106 of this

Part, or upon initial start-up of a new printing

line, or upon changing the method of compliance

from an existing subject printing line from

Section 219.401(b) or Section 219.401(c) to

Section 219.401(a) of this Part, the owner or

operator of a subject printing line shall certify

to the Agency that the printing line will be in

compliance with Section 219.401(a) of this Part on

and after a date consistent with Section 219.106

of this Part, or on and after the initial start-up

date. Such certification shall include:

479

A)  The name and identification number of each

coating and ink as applied on each printing

line.

B)  The VON content of each coating and ink as

applied each day on each printing line.

2)  On and after a date consistent with Section

219.106 of this Part, or on and after the initial

start—up date, the owner or operator of a printing

line subject to the limitations of Section 219.401

of this Part and complying by means of Section

219.401(a) of this Part shall collect and record

all of the following information each day for each

coating line and maintain the information at the

facility source for a period of three years:

A)  The name and identification number of each

coating and ink as applied on each printing

line.

B)  The VOM content of each coating and ink as

applied each day on each printing line.

3)  On and after a date consistent with Section

219.106 of this Part, the owner or operator of a

subject printing line shall notify the Agency in

the following instances:

A)  Any record showing violation of Section

219.401(a) of this Part shall be reported by

sending a copy of such record to the Agency

within 30 days following the occurrence of

the violation.

B)  At least 30 calendar days before changing the

method of compliance with Section 219.401 ~

this Part from Section 219.401(a) to Section

219.401(b) or (c) of this Part, the owner or

operator shall comply with all requirements

of subsection (b) (1) or (c) (1) (ci) (1) or

(e) (1) of this Section, respectively. Upon

changing the method of compliance with

Section 219.401 of this Part fromSection

219.401(a) to Section 219.401(b) or (C) ~

this Part, the owner or operator shall comply

with all requirements of subsection -(-~3-j.~j.or

-fe3-(e) of this Section, respectively.

d)  Any owner or operator of a printing line subject to the

limitations of Section 219.401 of this Part and

480

complying by means of Section 219.401(b) of this Part

shall comply with the following:

1)  By a date consistent with Section 219.106 of this

Part, or upon initial start-up of a new printing

line, or upon changing the method of compliance

for an existing subject printing line from Section

219.401(a) or (c) to Section 219.401(b) of this

Part, the owner or operator of the subject

printing line shall certify to the Agency that the

printing line will be in compliance with Section

219.401(b) of this Part on and after a date

consistent with Section 219.106 of this Part, or

on and after the initial start-up date. Such

certification shall include:

A)  The name and identification number of each

printing line which will comply by means of

Section 219.401(b) of this Part.

B)  The name and identification number of each

coating and ink available for use on each

printing line.

C)  The VON content of each coating and ink as

applied each day on each printing line.

D)  The instrument or method by which the owner

or operator will accurately measure or

calculate the volume of each coating and ink

as applied each day on each printing line.

E)  The method by which the owner or operator

will create and maintain records each day as

required in subsection -~-j~j...(2)of this

Section.

F)  An example of the format in which the records

required in subsection --j~j~j2)of this

Section will be kept.

2)  On and after a date consistent with Section

219.106 of this Part, or on and after the initial

start-up date, the owner or operator of a printing

line subject to the limitations of Section 219.401

and complying by means of Section 219.401(b) ~

this Part shall collect and record all of the

following information each day for each printing

line and maintain the information at the

facilitysource for a period of three years:

481

A)  The name and identification number of each

coating and ink as applied on each printing

line.

B)  The VOM content and the volume of each

coating and ink as applied each day on each

printing line.

C)  The daily-weighted average VOM content of all

coatings and inks as applied on each printing

line.

3)  On and after a date consistent with Section

219.106 of this Part, the owner or operator of a

subject printing line shall notify the Agency in

the following instances:

A)  Any record showing violation of Section

219.401(b) of this Part shall be reported by

sending a copy of

such record to the Agency

within 30 days following the occurrence of

the violation.

B)  At least 30 calendar days before changing the

method of compliance with Section 219.401 ~

this Part from Section 219.401(b) to Section

219.401(a) or 219.401(c) of this Part, the

owner or operator shall comply with all

requirements of subsection (c) (1) or (e) (1)

of this Section, respectively. Upon changing

the method of compliance with Section 219.401

of this Part from Section 219.401(b) to

Section 219.401(a) or (c) of this Part, the

owner or operator shall comply with all

requirements of subsection (c) or (e) of this

Section, respectively.

e)  Any owner or operator of a printing line subject to the

limitations of Section 219.401 of this Part and

complying by means of Section 219.401(c) of this Part

shall comply with the following:

1)  By a date consistent with Section 219.106 of this

Part, or upon initial start—up of a new printing

line, or upon changing the method of compliance

for an existing printing line from Section

219.401(a) or (b) to Section 219.401(c) of this

Part, the owner or operator of the subject

printing line shall perform all tests and submit

to the Agency the results of all tests and

calculations necessary to demonstrate that the

subject printing line will be in compliance with

482

Section 219.401(c) of this Part on and after a

date consistent with Section 219.106 of this Part,

or on 

arid

after the initial start-up date.

2)  On and after a date consistent with Section

219.106 of this Part, or on and after the initial

start-up date, the owner or operator of a printing

line subject to the limitations of Section 219.401

of this Part and complying by means of Section

219.401(c) of this Part shall collect and record

all of the following information each day for each

printing line and maintain the information at the

facility for a period of three years:

A)  Control device monitoring data.

B)  A log of operating time for the capture

system, control device, monitoring equipment

and the associated printing line.

C)  A maintenance log for the capture system,

control device and monitoring equipment

detailing all routine and non-routine

maintenance performed including dates and

duration of any outages.

3)  On and after a date consistent with Section

219.106 of this Part, the owner or operator of a

subject printing line shall notify the Agency in

the following instances:

Any record showing violation of Section

219.401(c) of this Part, shall be reported by

sending

a copy of such record to the Agency

within 30 days following the occurrence of

the violation.

B)  At least 30 calendar days before changing the

method of compliance with Section 219.401 ~

this Part from Section 219.401(c) to Section

219.401(a) or (b) of this Part, the owner or

operator shall comply with all requirements

of subsection (c) (1) or (d) (1) of this

Section, respectively. Upon changing the

method of compliance with Section 219.401 ~

this Part from Section 219.401(c) to Section

219.401(a) or (b) of this Part, the owner or

operator shall comply with all requirements

of subsection (c) or (d) of this Section,

respectively.

483

(Source:

Amended at

—

Ill. Reg. 

______,

effective 

____________

Section 219.405  

Heatset-Web-Offset Lithographic Printing

a)  Applicability

1)  The limitations of subsection (b) below apply to

all heatset-web-off set lithographic printing lines

at a subject facilitysource. All facilitics

sources with heatset-web-off set lithographic

printing lines are subject facilities sources

unless:

A)  Total maximum theoretical emissions of VON

from all heatset-web-offset lithographic

printing lines (including solvents used for

cleanup operations associated with the

heatset-web-offset lithographic printing

line(s)) at the facilitysource never exceed

90.7 Mg (100 tons) per calendar year in the

absence of air pollution control equipment,

or

B)  A federally enforceable construction permit

or SIP revision for all heatset-web-offset

lithographic printing lines(s) at a

facilitysource requires the owner or operator

to limit production or capacity of these

printing line(s) to reduce total VON

emissions from all heatset—web—offset

lithographic printing line(s) to 90.7 Mg

(100 tons) per calendar year or less in the

absence of air pollution control equipment,

and

2)  Any owner or operator of any heatset-web—off set

lithographic printing line that is exempt from the

limitations in subsection (b) of this Section

because of the criteria in subsection (a) (1) ~

this Section shall be subject to the. recordkeeping

and reporting requirements in subsection (c) (1) ~

this Section.

b)  Specific Provisions. No owner or operator of a subject

heatset—web-offset printing line may cause or allow the

operation of the subject heatset-web-offset printing

line unless the owner or operator meets the

requirements in subsection (b) (1) or (b) (2) and the

requirements in subsections (b) (3) and (b) (4) below.

484

1)  An afterburner system is installed and operated

that reduces 90 percent of the VON emissions from

the dryer exhaust, or

2)  The fountain solution contains no more than

8 percent, by weight, of VOM and a condensation

recovery system is installed and operated that

removes at least 75 percent of the non-isopropyl

alcohol organic materials from the dryer exhaust,

and

3)  The control device is equipped with the applicable

monitoring equipment specified in Section

219.105(d) (2) of this Part and the monitoring

equipment is installed, calibrated, operated and

maintained according to vendor specifications at

all times the control device is in use, arid

4)  The control device is operated at all times when

the subject printing line is in operation. The

owner or operator shall demonstrate compliance

with this Section by using the applicable test

methods and procedures specified in Section

219.105(a), (d), and (f) of this Part and by

complying with the recordkeeping and reporting

requirements specified in subsection (c) below.

c)  Recordkeeping and Reporting. The VON content of each

fountain solution and ink and the efficiency of each

control device shall

be determined by the applicable

test methods and procedures specified in Section

219.105 of this Part to establish the records required

under this subsection.

1)  Any owner or operator of a printing line which is

exempted from the limitations of subsection (b) ~

this Section because of the criteria in subsection

(a) of this Section shall comply with the

following:

A)  By a date consistent with Section 219.106 ~

this Part, the owner or operator of a

f-~cility---heatset-web-offset 

lithographic

printing line to which subsection (c) (1) of

this Section is applicable shall certify to

the Agency that the facility is heatset-

web-of fset lithographic printing line exempt

under the provisions of subsection (a) ~

this Section. Such certification shall

include:

485

i)  A declaration that the facility heatset-

web-off set lithographic printing line is

exempt from the limitations of

subsection (b) of this Section because

of the criteria in subsection (a) Q~.

this Section, and

ii) Calculations which demonstrate that

total maximum theoretical emissions ot

VON from all heatset-web-off set

lithographic printing lines at the

facilitysource never exceed 90.7 Mg

(100 tons) per calendar year before the

application of air pollution control

equipment. Total maximum theoretical

emissions of VOM for a heatset—

web-of f set lithographic printing

facility source is the sum of maximum

theoretical emissions of VOM from each

heatset-web-offset lithographic printing

line at the facility. The following

equation shall be used to calculate

total maximum theoretical emissions of

VON per calendar year in the absence of

air pollution control equipment for each

heatset-web-offset lithographic printing

line at the facilitysource.

(A

x B)

+ (C 

D)+1095 (F x G x H)

100

where:

Total maximum theoretical

emissions of VON from one

heatset-web-off set printing

line in units of kg/year

(lbs/year)-,-~

A

=

Weight of VOM per volume of

solids of

ink with the highest

VON content as applied each

year on the printing line in

units of kg VOM/l (lbs

VON/gal)

of solids and~

B

Total volume of solids for all

inks that can potentially be

applied each year on the

printing line in units of

1/year (gal/year). The

486

instrument or method by which

the owner or operator

accurately measured or

calculated the volume of each

ink as applied and the amount

that can potentially be

applied each year on the

printing line shall be

described in the certification

to the Agency-rj~.

C

=

The weight percent VON of the

fountain solution with the

highest VON content-a

D

=

The total volume of fountain

solution that can potentially

be used each year on the

printing line in units of

1/year (gal/year). The

instrument and/or method by

which the owner or operator

accurately measured or

calculated the volume of each

fountain solution used and the

amount that can potentially be

used each year on the printing

line shall be described in the

certification to the Agency-~j

Weight of VON per volume of

material for the cleanup

material or solvent with the

highest VON content as used

each year on the printing line

in units of Kg/l (lbs VOM/gal)

of such material;

The greatest volume of cleanup

material or solvent used in

any 8—hour period;

The highest fraction of

cleanup material or solvent

which is not recycled or

recovered for offsite disposal

during any 8-hour period.

B)  On and after a date consistent with Section

219.106 of this Part, the owner or operator

of a facility heatset—web-offset lithographic

printing line to which subsection (c) (1) ~

487

this Section is applicable shall collect and

record all of the following information each

year for each printing line and maintain the

information at the facilitysource for a

period of three years:

i)  The name and identification of each

fountain solution and ink as applied on

each printing line.

ii) The VON content and the volume of each

fountain solution and ink as applied

each year on each printing line.

C)  On and after a date consistent with Section

219.106 of this Part, the owner or operator

of a facilityheatset-web-off set lithographic

printing line exempted from the limitations

of subsection (b) of this Section because of

the criteria in subsection (a) of this

Section shall notify the Agency of any record

showing that total maximum theoretical

emissions of VON from all printing lines

exceed 90.7 Mg (100 tons) in any calendar

year in the absence of air pollution control

equipment by sending a copy of such record to

the Agency within 30 days after the

exceedance occurs.

2)  Any owner or operator of a printing line subject

to the limitations of subsection (b) of this

Section and complying by means of subsection

(b) (1) of this Section shall comply with the

following:

A)  By a date consistent with Section 219.106 ~

this Part, or upon initial start-up of a new

printing line, or upon changing the method of

compliance for an existing printing line from

subsection (b) (2) to subsection (b) (1) of

this Section the owner or operator of the

subject printing line shall perform all tests

and submit to the Agency the results of all

tests and calculations necessary to

demonstrate that the subject printing line

will be in compliance with subsection (b) (1)

of this Section on and after a date

consistent with Section 219.106 of this Part,

or on and after the initial start-up date.

B)  On and after a date consistent with Section

219.106 of this Part, or on and after the

488

initial start-up date, the owner or operator

of a printing line subject to the limitations

of subsection (b) of this Section and

complying by means of subsection (b) (1) g~

this Section shall collect and record the

following information each day for each

printing line and maintain the information at

the facilitysource

for a period of three

years:

i)  Control device monitoring data.

ii) A log of operating time for the control

device, monitoring equipment and the

associated printing line.

iii) A maintenance log for the control device

and monitoring equipment detailing all

routine and nonroutine maintenance

performed including dates and duration

of any outages.

C)  On and after a date consistent with Section

219.106 of this Part, the owner or operator

of a subject printing line shall notify the

Agency in the following instances:

i)  Any record showing violation of

subsection (b) (1) of this Section shall

be reported by sending a copy of such

record to the Agency within 30 days

following the occurrence of the

violation.

ii) At least 30 calendar days before

changing the method of compliance with

subsection (b) of this Section from

subsection (b) (1) to (b) (2) of this

Section, the owner or operator shall

comply with all requirements of

subsection (c) (3) (A) of this Section.

Upon changing the method of compliance

with subsection (b) from subsection

(b) (1) to (b) (2) of this Section, the

owner or operator shall comply with all

requirements of subsection (c) (3) 

~f

this Section.

3)  Any owner or operator of a printing line subject

to the limitations of subsection (b) of this

Section and complying by means of subsection

489

(b) (2) of this Section shall comply with th~

following:

A)  By a date consistent with Section 219.106 

Q~

this Part, or upon initial start-up of a new

printing line, or upon changing the method of

compliance for an existing printing line from

subsection (b) (1) to (b) (2) of this Section

the owner or operator of the subject printing

line shall perform all tests and submit to

the Agency and the USEPA the results of all

tests and calculations necessary to

demonstrate that the subject printing line

will be in compliance with subsection (b) (2)

of this Section on and after a date

consistent with Section 219.106 of this Part,

or on and after the initial start-up date.

B)  On and after a date consistent with Section

219.106 of this Part, or on and after the

initial start—up date, the owner or operator

of a printing line subject to the limitations

of subsection (b) of this Section and

complying by means of subsection (b) (2) ~

this Section shall collect and record the

following information each day for each

printing line and maintain the information at

the facilitysource for a period of three

years:

i)  The VOM content of the fountain solution

used each day on each printing line.

ii) A log of operating time for the control

device and the associated printing line.

iii) A maintenance log for the control device

detailing all routine and non—routine

maintenance performed including dates

and duration of any outages.

C)  On and after a date consistent with Section

219.106 of this Part, the owner or operator

of a subject printing line shall notify the

Agency in the following instances:

i)  Any record showing violation of

subsection (b) (2) of this Section shall

be reported by sending a copy of such

record to the Agency within 30 days

following the occurrence of the

violation.

490

ii) At least 30 calendar days before

changing the method of compliance with

subsection (b) of this Section from

subsection (b) (2) to (b) (1) of this

Section, the owner or operator shall

comply with all requirements of

subsection (C) (2) (A) of this Section.

Upon changing the method of compliance

with subsection (b) from subsection

(b) (2) to (b) (1) of this Section, the

owner or operator shall comply with all

requirements of subsection (C) 

(2)

~f

this Section.

d) Compliance Schedule. Every owner or operator of-a

heatset—web-off set lithographic printing line shall

comply with the applicable requirements of subsections

(b) and (C) of this Section in accordance with the

applicable compliance schedule specified in subsection

(ci) (1) ,   (d) (2) ,  or (ci) (3) below:

1)  No owner or operator of a heatset—web-offset

lithographic printing line which is exempt from

the limitations of subsection (b) of this Section

because of the criteria in subsection (a) of this

Section shall operate said printing line on or

after a date consistent with Section 219.106 ~

this Part, unless the owner or operator has

complied with, and continues to comply with,

subsection -f-b.~-~j(l)and (c) (1) of this Section.

2)  No owner or operator of a heatset—web-offset

lithographic printing line complying by means of

subsection (b) (1) of this Section shall operate

said printing line on or after a date consistent

with Section 219.106 of this Part, unless the

owner or operator has complied with, and continues

to comply with, subsection (b) (2) (b) (1), (b) (3).

(b) (4) and (C) (2) of this Section.

3)  No owner or operator of a heatset—web—offset

lithographic printing line complying by means of

subsection (b) (2) of this Section shall operate

said printing line on or after a date consistent

with Section 219.106 of this Part, unless the

owner or operator has complied with, and continues

to comply with, subsection (b) (2) (b) (3). (b) (4)

and (c) (3) of this Section.

(Source: Amended at  

Ill. Reg. 

______

,  effective 

____________

491

SUBPART Q: LEANS FROM SYNTHETIC ORGANIC CHEMICAL AND POLYMER

MANUFACTURING EQUIPMENT PLANT

Section 219.421  

General Requirements

The owner or operator of a plant which processes more than 3660

mg/yr (4033 tons/year) gaseous and light liquid VON, and whose

components are used to manufacture the synthetic organic

chemicals or polymers listed in Appendix A, shall comply with

this Subpart. The provisions of this Subpart are applicable to

components containing 10 percent or more by weight VON as

determined by ASTM method E-168, E-169 and E-260, incorporated by

reference in Section 219.112 of this Part. Those components that

are not process unit components are exempt from this Subpart. A

component shall be considered to be leaking if the VON is equal

to, or is greater than 10,000 ppxnv as methane or hexane as

determined by USEPA Reference Method 21, as specified at 40 CFR

60, Appendix A, incorporated by reference in Section 219.112 

Q~

this Part, indication of liquids dripping, or indication by a

sensor that a seal or barrier fluid system has failed. The

provisions of this Subpart are not applicable if the equipment

components are used to produce heavy liquid chemicals only from

heavy liquid feed or raw materials.

(Source: Amended at —  Ill. Reg. 

______,

effective 

___________

Section 219.422  

Inspection Program Plan for Leaks

The owner or operator of a synthetic organic chemical or polymer

manufacturing plant subject to Section 219.421 of this Part shall

prepare an inspection program plan which contains, at a minimum:

a)  An identification of all components and the period in

which each will be monitored pursuant to Section

219.423 of this Part.

b)  The format for the monitoring log required by Section

219.425 of this Part.

c)  A description of the monitoring equipment to be used

when complying with Section 219.423 of this Part, and

d)  A description of the methods to be used to identify all

pipeline valves, pressure relief valves in gaseous

service, all leaking components, and components

exempted under Section 219.423-(4+jjj. g~ this Part such

that they are obvious and can be located by both plant

personnel performing monitoring and Agency personnel

performing inspections.

492

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

____________

Section 219.423  

Inspection Program for Leaks

The owner or operator of a synthetic organic chemical or polymer

manufacturing plant subject to this ~eubpart shall, for the

purposes of detecting leaks, conduct a component inspection

program using the test methods specified in Method 21, 40 CFR 60,

Appendix A (1986), incorporated by reference in Section 219.112

of this Part, consistent with the following provisions:

Test annually those components operated near extreme

temperature or pressure such that they would be unsafe

to routinely monitor and those components which would

require the elevation of monitoring personnel higher

than two meters above permanent worker access

structures or surfaces.

b)  Test quarterly all other pressure relief valves in gas

service, pumps in light liquid service, valves in light

liquid service and in gas service, and compressors.

c)  If less than or equal to 2 percent of the valves in

light liquid service and in gas service tested pursuant

to subsection (b) of this Section are found ~e# to leak

for five consecutive quarters, no leak tests shall be

required for three consecutive quarters. Thereafter,

leak tests shall resume for the next quarter. If that

test shows less than or equal to 2 percent of the

valves in light liquid service and in gas service are

leaking, then no tests are required for the next

three quarters. If more than 2 percent are leaking,

then tests are required for the next five quarters.

ci)   Observe visually all pump seals weekly.

e)  Test immediately any pump seal from which liquids are

observed dripping.

f)  Test any relief valve within 24 hours after it has

vented to the atmosphere.

g)  Routine instrument monitoring of valves which are not

externally regulated, flanges, and equipment in heavy

liquid service, is not required. However, any valve

which is not externally regulated, flange or piece of

equipment in heavy liquid service that is found to be

leaking on the basis of sight, smell or sound shall be

repaired as soon as practicable but no later than

30 days after the leak is found.

493

h)  Test immediately after repair any component that was

found leaking.

i)  Within one hour of its detection, a weatherproof,

readily visible tag, in bright colors such as red or

yellow, bearing an identification number and the date

on which the leak was detected must be affixed on the

leaking component and remain in place until the leaking

component is repaired.

j)  The following components are exempt from the monitoring

requirements in this Section:

1)  Any component that is in vacuum service, and

2)  Any pressure relief valve that is connected to an

operating flare header or vapor recovery device.

(Source: Amended at  

Ill. Reg. 

______,

effective 

____________

Section 219.424  

Repairing Leaks

All leaking components must be repaired and retested as soon as

practicable but no later than 15 days after the leak is found

unless the leaking component cannot be repaired until the process

unit is shut down. Records of repairing and retesting must be

maintained in accordance with Section 219.425 and 219.426 of this

Part.

(Source: Amended at 

_____,

Ill. Reg. 

______,

effective

Section 219.425  

Recordkeeping for Leaks

a)  The owner or operator of a synthetic organic chemical

or polymer manufacturing plant shall maintain a leaking

components monitoring log which shall contain, at a

minimum, the following information:

1)  The name of the process unit where the component

is located;

2)  The type of component (e.g., valve, seal);

3)  The identification number of the component;

4)  The date on which a leaking component is

discovered;

5)  The date on which a leaking component is repaired;

494

6)  The date and instrument reading of the recheck

procedure after a leaking component is repaired;

7)  A record of the calibration of the monitoring

instrument;

8)  The identification number of leaking components

which cannot be repaired until process unit

shutdown; and             

9)  The total number of valves in light liquid service

and in gas service inspected; the total number and

the percentage of these valves found leaking

during the monitoring period.

b)  Copies of the monitoring log shall be retained by the

owner or operator for a minimum of two years after the

date on which the record was made or the report was

prepared.

c)  Copies of the monitoring log shall be made available to

the Agency~upon verbal or written request~prior to or

at the time of inspection pursuant to Section 4(d) of

the Environmental Protection Act (Act) (Ill. Rev. Stat.

19?-~j~,ch. 111½, pars. 1001 et seq.) 1415 ILCS 5/1 et

seq.~at any reasonable time.

(Source: Amended at  

Ill. Reg. 

______,

effective 

____________

_________________________ )

Section 219.426  

Report for Leaks

The owner or operator of a synthetic organic chemical or polymer

manufacturing plant subject to Section 219.421 through 219.430 ~

this Part shall:

a)  Submit quarterly reports to the Agency on or before

March 31, June 30, September 30, and December 31 of

each year, listing all leaking components identified

pursuant to Section 219.423 of this Part but not

repaired within 15 days, all leaking components

awaiting process unit shutdown, the total number of

components inspected, the type of components inspected,

and the total number of components found leaking, the

total number of valves in light liquid service and in

gas service inspected and the number and percentage of

valves in light liquid service and in gas service found

leaking.

b)  Submit a signed statement with the report attesting

that all monitoring and repairs were performed as

495

required under Section 219.421 through 219.427 of 

thi~

Part.

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

____________

Section 219.427  

Alternative Program for Leaks

The Agency shall approve an alternative program of monitoring,

recordkeeping, or reporting to that prescribed in this Subpart

upon a demonstration by the owner or operator of such plant that

the alternative program will provide plantsource personnel and

Agency personnel with an equivalent ability to identify and

repair leaking components. Any alternative program can be

allowed when approved by the Agency and approved by the tJSEPA as

a SIP revision.

(Source: Amended at —  Ill. Reg. 

______,

effective 

____________

Section 219.428  

Open—Ended Valves

a)  Each open-ended valve shall be equipped with a cap,

blind flange, plug, or a second valve, except during

operations requiring fluid flow through the open-ended

valve.

b)  Each open-ended valve equipped with a second valve

shall be operated in a manner such that the valve on

the process fluid end is closed before the second valve

is closed.

c)  Components which are open—ended valves and which serve

as a sampling connection shall be controlled such that

they com~lvwith subsection (c) (1). (c) (2) or (c) (3)

below. This requirement does not a~nlvto in-situ

sampl jrig systems. +

1)  A closed purge system or closed vent system shall

return purged process fluid to the process line

with no detectable volatile organic material

emissions to the atmosphere, or

2)  A closed purge system or closed vent system shall

collect and recycle purged process fluid to the

process line with no detectable volatile organic

material emissions to the atmosphere, or

3)  Purged process fluid shall be transported to a

control device that complies with the requirements

of Section 219.429 of this Part. If a container

is used to transport ~ur~ed process fluid to the

496

control device, the container shall be a c1o~

container designed and used to reduce the VON

emissions vented from purged process fluid after

transfer to no detectable VON emissions as

determined by USEPA Reference Method 21. as

specified in 40 CFR 60. A~~endixA (1990 or 199lI

incorporated by reference in Section 219.112 of

this Part. For purposes of this Section. the

phrase “after transfer” shall refer to the time at

which the entire amount of purged process fluid

resulting from a flushing or cleaning of the

sample line enters the container, provided.

however, that ~ur~ed process fluid may be

transferred from the initial container to another

closed container prior to disposal, e.g.. to a

bulk waste storage container.

d)  In—situ sampling systems arc cxcii       

bsect.~4.

(c).

(Source: Amended at 

_____,

Ill. Reg. 

______,

effective 

__________

Section 219.429  

Standards for Control Devices

Control devices used to comply with Section 219.428(c) of this

Part shall comply with the following:

a)  If the control device is a vapor recovery system (for

example, condensers and adsorbers), it shall be

designed and operated to recover the volatile organic

material emissions vented to it with an efficiency of

95 percent or greater.

b)  If the control device is an enclosed combustion device,

it shall be designed and operated to reduce the

volatile organic material emissions vented to it with

an efficiency of 95 percent or greater, or to provide a

minimum residence time of 0.75 seconds at a minimum

temperature of 816°C.

c)  If the control device is a flare, it shall:

1)  Be designed for and operated with rio visible

emissions as determined by USEPA Reference Method

22, 40 CFR 60, Appendix A (1986), incorporated by

reference in Section 219.112 of this Part, except

for periods riot to exceed a total of 5 minutes

during any 2 consecutive hours.

2)  Be operated with a pilot flame present at all

times and shall be monitored with a thermocouple

497

or any other equivalent device to detect the

presence of the pilot flame.

3)  Be steam—assisted, air—assisted, or nonassisted.

4)  Be used only with the net heating value of the gas

being combusted being 11.2 MJ/scm (300 Btu/scf) or

greater if the flare is steam—assisted or air—

assisted; or with the net heating value of the gas

being combusted being 7.45 MJ/scm or greater if

the flare is nonassisted. The net heating value

of the gas being combusted shall be calculated

using the following equation:

n

Hr  =  K

i=1

E  C1H1

Where:

Hr

Net heating value of the sample in

MJ/scm; where the net enthalpy per

mole of offgas is based on

combustion at 25°Cand 760 mm Hg,

but the standard temperature for

determining the volume

corresponding to one mole is 20°C--~

K

Constant,

1.740 x 10~ (1/ppm) (g—mole/scm) (MJ/Kcal)

where

standard temperature for (g—mole/scm) is

200

C--i

C1

Concentration of sample component

i, in ppm, as measured by USEPA

Reference Method 18, 40 CFR 60,

Appendix A (1986), and ASTM D

2504-83, both incorporated by

reference in Section 219. 112 of

this Part-a

H1

Net heat of combustion of sample

component i, kcal/g mole. The

heats of combustion may be

determined using ASTM D 2382—83,

incorporated by reference in

498

Section 219.112 of this Part, if

published values are not available

or cannot be calculated.

5)  Steam—assisted and nonassisted flares shall be

designed and operated with an exit velocity, as

determined by dividing the volumetric flowrate (in

units of standard temperature and pressure), as

determined by USEPA Reference Method 2 or 2A, 40

CFR 60, Appendix A (1986) incorporated by

reference in Section 219.112 of this Part, as

appropriate; by the unobstructed (free) cross

sectional area of the flare tip, less than 18

m/sec (60 ft/sec).

6)  Air-assisted flares shall be designed and operated

with an exit velocity less than the maximum

permitted velocity, V~, as determined by the

following equation:

V~

8.706 + 0.7084(H~)~-;

V~

Maximum permitted

velocity, m/sec-~j

8.706        

Constant-a

0.7084       

Constant-~

Hr

The net heating value as

determined in subsection

(c) (4) of this section.

ci)   If the control device is a closed container, it shall

be designed and operated to reduce the volatile organic

material emissions, vcnted from purged process fl-uid

after tranof Cr, to no detectable vo-latile organic

i~aterial emissions as determined by UCEPA Reference

Method 21 -as specified at 40 CFR 60, Appendix A (1986),

incorporated by reference in Cection 219.112. For

purposco of this Cection, the phrase “after transfer”

shall refer to the time at which the entire amount of

purged process fluid resulting from a flushing or

cleaning of the sample line enters the closed container

or containers including the final container(s) prior te

disposal. The following information pertaining to

closed vent systems and control devices subiect to

Section 219.429 shall be maintained by the owner or

operator. These records shall be updated as necessari

to describe current operation and equipment. The

records shall be retained as a readily accessible

location at the source for a minimum of two years after

the control device is permanently shutdown.

499

~j. Detailed schematics. design specifications. and

piPing and instrumentation diagrams

21

The dates and description of any chanaes in design

specifications

fl

description of the Parameter or parameters

monitored and recorded as reauired in subsection

(f) (1~to ensure that the control devices are

ooerated and maintained in conformance with their

design and an explanation why that parameter (or

parameters) was selected for monitoring.

Thp owner or opcrutor of a control device shall monitor

tnc

concroi. acvico to ensure tnuc ~c 

n’irrato~and

~

..n conrormance witn ‘cnc manuracturcrs

specifications, modified to the ~~ticular ~occss

design.

#~)

The control device shall be operated at all times when

emissions may be vented to it.

fj.

Owners and oPerators of control devices used to comply

with this Subpart shall monitor each control device to

ensure that the control device is operated and

maintained in conformance with its designs at all times

that emissions may be vented to it. This monitoring

shall be conducted in accordance with Section

219.429(d)(3). The records ~re~ared as Part of this

monitoring activity shall include the dates of startup

and shutdown of control devices and identify periods

when the devices are not operated as designed.

including periods when a flare pilot light does not

have a flame.

g~ The requirements of subsections (d). (e) and (f) shall

not ap~lvto a combustion device used for disposal of

purged process fluid which is subiect to the Burning of

Hazardous Waste in Boilers and Industrials Furnaces

(BIF) rules, 40 CFR Parts 260. 261. 264. 265, 266, and

270, located at the source or which is sub’iect to the

Resource Conservation and RecoverY Act (RCRA) rules, 35

Ill. Adm. Code Parts 703. 720. 721. 724. 725. and 726.

The owner or operator of such combustion device shall

satisfy applicable provisions of the RCRA or BIF rules.

(Source: Amended at —  Ill. Reg. 

______,

effective 

____________

500

Section 219.430  

Compliance Date (Repealed)

The owner or operator of a synthetic organic chemical -or polymer

~anufaoturing plant subject to 35 Ill. Mm. Code 215.430 through

215.438 as of December 31, 1987 shall have complied with the

stanuaras ar~.i.imnita’cions or tnooc ~eotions no iatcr tnan

December 31, 1987.

(Source: Repealed at 

—

Ill. Reg. 

______,

effective 

___________

SUBPART R: PETROLEUM REFINING AND RELATED INDUSTRIES;

ASPHALT MATERIALS

Section 219.441  

Petroleum Refinery Waste Gas Disposal

a)  Except as provided in subsection (b) or (c) of this

Section, 

rio

person shall cause or allow the discharge

of organic materials in excess of 100 ppm equivalent

methane (molecular weight 16.0) into the atmosphere

from:

1)  Any catalyst regenerator of a petroleum cracking

system; or

2)  Any petroleum fluid coker; or

3)  Any other waste gas stream from any petroleum or

petrochemical manufacturing process.

b)  Exception. Existing sources subject to subsection

(a) (3) of this Section may, alternatively, at their

election, comply with the organic material emission

limitations imposed by 35 Ill. Mm. Code 21~.30l or

21?-2.302; provided, however, that there.shall be no

increase in emissions from such sources above the level

of emissions in existence on May 3, 1979.

c)  New Sources. Sources subject to subsection (a) (3) 

~f

this Section, construction of which commenced on or

after January 1, 1977, may, at their election, comply

with the following emission limitations:

1)  A maximum of eight pounds per hour of organic

material; or

2)

Emission of organic material in excess of the

limitation of subsection (c) (1) of this Section is

allowable if such emissions are controlled by air

pollution control methods or equipment approved by

the Agency capable of reducing by 85 percent or

more the uncontrolled organic material that would

501

otherwise be emitted to the atmosphere. Such

methods or equipment must be approved by the

Agency and approved

by the USEPA as a SIP

revision.

(Source: Amended at

—

Ill. Reg.    

,  effective 

____________

Section 219.443  

Wastewater (Oil/Water) Separator

No owner or operator of a petroleum refinery shall operate any

wastewater (oil/water) separator at a petroleum refinery unless

the separator is equipped with air pollution control equipment

capable of reducing by 85 percent or more the uncontrolled

organic material emitted to the atmosphere. If no odor nuisance

exists, the limitation of this

Section shall not apply if the

vapor pressure of the organic material is below 10.34 kPa (1.5

psia) at 2G~4.3°K(70°F) at all times.

(Source: Amended at  

Ill. Reg. 

______,

effective 

____________

Section 219.445  

Leaks: General Requirements

a-).-The owner or operator of a petroleum refinery shall:

~a) Develop a monitoring program plan consistent with the

provisions of Section 219.446 of this Part

2b) Conduct a monitoring program consistent with the

provisions of Section 219.447 of this Part

~)

Record all leaking components which have a volatile

organic material concentration exceeding 10,000 ppm

consistent with the provisions of Section 219.448 Q.f

this Part

4d) Identify each component consistent with the monitoring

program plan submitted pursuant to Section 219.446 g~

this Part

~)

Repair and retest the leaking components as soon as

possible within 22 days after the leak is found, but no

later than June 1 for the purposes of Section

219.447(a) (1) of this Part, unless the leaking

components cannot be repaired until the unit is shut

down for turnaround; and

~)

Report to the Agency consistent with the provisions of

Section 219.449 of this Part.

502

(Source: Amended at  

Ill. Reg. 

______,

effective 

____________

______

)

Section 219.446  

Monitoring Program Plan for Leaks

The owner or operator of a petroleum refinery shall prepare a

monitoring program plan which contains, at a minimum:

a)  An identification of all refinery components and the

period in which each will be monitored pursuant to

Section 219.447 of this Part

The format for the monitoring log required by Section

219.448 of this Part

c)  A description of the monitoring equipment to be used

pursuant to Section 219.447 of this Part and

d)  A description of the methods to be used to identify all

pipeline valves, pressure relief valves in gaseous

service and all leaking components such that they are

obvious to both refinery personnel performing

monitoring and Agency personnel performing inspections.

(Source: Amended at 

_____,

Ill. Reg. 

______,

effective 

__________

Section 219.447  

Monitoring Program for Leaks

a)  The owner or operator of a petroleum refinery subject

to Section 219.445 of this Part shall, for the purpose

of detecting leaks, conduct a component monitoring

program consistent with the following provisions:

1)  Test once between March 1 and June 1 of each year,

by methods referenced in Section 219.105(g) g~

this Part, all pump seals, pipeline valves in

liquid service and process drains-~

2)  Test once each quarter of each calendar year, by

methods referenced in Section 219.105(g) of this

Pa~rt, all pressure relief valves in gaseous

service, pipeline valves in gaseous service and

compressor seals-ri

3)  Inaccessible valves may be tested once each

calendar year instead of once each quarter of each

calendar year--;

4)  Observe visually all pump seals weekly--j

503

5)  Test immediately any pump seal from which liquids

are observed dripping~~

6)  Test any relief valve within 24 hours after it has

vented to the atmosphere,-~and

7)  Test immediately after repair any component that

was found leaking.

b)  Storage tank.valves and pressure relief devices

connected to an operating flare header or vapor

•recovery device are exempt from the monitoring

requirements in subsection (a) of this Section.

c)  The Agency may require more frequent monitoring than

would otherwise be required by subsection (a) of this

Section for components which are demonstrated to have a

history of leaking.

(Source: Amended at  

Ill. Reg. 

______,

effective 

____________

Section 219.449  

Reporting for Leaks

The owner or operator of a petroleum refinery shall:

a)  Submit a report to the Agency prior to the 1st day of

both July and September listing all leaking components

identified pursuant to Section 219.447 of this Part but

not repaired within 22 days, all leaking components

awaiting unit turnaround, the total number of

components inspected and the total number of components

found leaking;

b)  Submit a signed statement with the report attesting

that all monitoring and repairs were performed as

required under Sections 219.445 through 219.448 of this

Part.

(Source: Amended at —  Ill. Reg. 

______,

effective 

____________

Section 219.450  

Alternative Program for Leaks

The Agency may approve an alternative program of monitoring,

recordkeeping or reporting to that prescribed in Sections 219.446

through 219.449 of this Part upon a demonstration by the owner or

operator of a petroleum refinery that the alternative program

will provide refinery, Agency and USEPA personnel with an

equivalent ability to identify and repair leaking components.

Any alternative program can be allowed only if approved by the

USEPA as a SIP revision.

504

(Source: Amended at  

Ill. Reg.    

,  effective 

____________

Section 219.452  

Compliance Schedule for Leaks

The owner or operator of a petroleum refinery shall adhere to the

increments of progress contained in the following schedule:

a)  Submit to the Agency a monitoring program consistent

with Section 219.446 of this Part prior to July 1, 1991

or a date consistent with Section 219.106 of this Part.

b)  Submit to the Agency the first monitoring report

pursuant to Section 219.449 of this Part prior to

August 1, 1991 or a date consistent with Section

219.106 of this Part.

(Source: Amended at  

Ill. Reg.    

, effective 

____________

Section 218.453  

Compliance Dates (Repealed)

Every owner or operator of a petroleum refinery s~ubjcctto 35

Ill. Adm. 

Code

215, Cubpart fl as of December 31, 19C7 shall have

complied with its standards and limitations by December 31, 1987.

(Source: Repealed at 

—

Ill. Reg. 

_____,

effective 

__________

SUBPART S: RUBBER AND MISCELLANEOUS PLASTIC PRODUCTS

Section 219.461  

Manufacture of Pneumatic Rubber Tires

The owner or operator of an undertread cementing, treadend

cementing or bead dipping operation at a pneumatic rubber tire

manufacturing -f~aoilitysourceshall install and operate:

a)  A capture system, with minimum capture efficiency of 65

percent by weight of VOM for treadend cementing or bead

dipping operations and a capture system with a minimum

capture efficiency of 55.5 percent by weight of VOM for

undertread cementing; and

b)  A control device that meets the requirements of one of

the following:

1)  A carbon adsorption system designed and operated

in a manner such that there is at least a 90

percent removal of VOM by weight from the gases

ducted to the control device;

505

2)

An afterburning system that oxidizes at least 90

percent of the captured noninethane VON (VOM

measured as total combustible carbon) to carbon

dioxide and water; and

3)  An alternative VON emission reduction system

demonstrated to have at least a 90 percent overall

reduction efficiency and approved by the Agency

and approved by the USEPA.

(Source: Amended at —  Ill. Reg. 

_____,

effective 

____________

Section 219.462  

Green Tire Spraying Operations

The owner or operator of a green tire spraying operation at a

pneumatic rubber tire manufacturing facilitysource shall:

a)  Install and operate:

1)  A capture system with a minimum capture efficiency

of 90 percent by weight of VOM; and

2)  A control device that meets the requirements of

one of the following:

A)  A carbon adsorption system designed and

operated in a manner such that there is at

least 90 percent removal of VON by weight

from the basesgases ducted to the control

device;

B)  An afterburning system that oxidizes at least

90 percent of the captured nonmethane VON

(measured as total combustible carbon) to

carbon dioxide and water; or

C)  An alternative VON emission reduction system

demonstrated to have at least a 90 percent

overall reduction efficiency approved by the

Agency and approved by the USEPA as a SIP

revision.

b)  Substitute for the normal solvent-based mold release

compound water-based sprays containing:

1)  No more than five percent by volume of VOM as

applied for the inside of tires;

2)  No more than ten percent by volume of VON as

applied for the outside of tires.

506

(Source: Amended at  

Ill. Reg.    

,  effective 

_____

_________________________ )

Section 219.463  

Alternative Emission Reduction Systems

In lieu of complying with Section 219.461 or 219.462 of this

Part, the owner or operator of an cmission source may utilize an

alternative volatile organic emission reduction system, including

an alternative production process, which is demonstrated to be

equivalent to Section 219.461 or 219.462 of this Part on the

basis of emissions of volatile organic matter material. A

treadend cementing operation shall be considered equivalent to

Section 219.461 or 219.462 of this Part for the purposes of this

Section if the total volatile organic emission from such

operation is 10 grams or less per tire.

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

____________

Section 219.464  

Testing and NonitoringEmission Testing

a)  Upon a reasonable request by the Agency, the owner or

operator of a VOM emission source required to comply

with a limit of Sections 219.461 through 219.464 Q~

this Part shall conduct emissions testing, at such

person’s own expense, to demonstrate compliance.

b)  A person planning to conduct a VON emission test to

demonstrate compliance shall notify the Agency of that

intent not less than 30 days before the planned

initiation of the tests so the Agency may observe the

test.

(Source: Amended at —  Ill. Reg. 

______,

effective 

____________

Section 218.465  

Compliance Dates (Repealed)

Every owner or operator of an cmission source subject to 35 Ill.

Mm. Code 215, Cubpart C, as c-f December 31, 1987 shall have

complied with its standards and limitations by December 31, 1937.

(Source: Repealed at —  Ill. Reg.    

, effective 

__________

_________________________)

Section 219.466  

Compliance Plan (Repealed)

The owner  op-erator  

~~on source snaii nave

submitted to the Agency a compliance plan, pursuant te

35 Ill. Acm. Code 201, Cubpart H, including a project

c-omplotion schedule where  

1iruTh1~.

no later than

April 21, 1983.

Section 219.480  

Applicability

507

(Source: Repealed at —  Ill. Reg. 

______,

effective

SUBPART T: PHARMACEUTICAL MANUFACTURING

a)  The rules of this Subpart, except for Sections 219.483

through 219.485, apply to all emission sourcesunits of

VOM, including but not limited to reactors,

distillationequipment

forunits,the transferdryers, ofstorageVOL, filters,tanks

for VOL1

crystallizers, washers, laboratory hoods,

pharmaceutical coating operations, mixing operations

and centrifuges used in manufacturing, including

packaging, of pharmaceuticals, and emitting more than

6.8 kg/day (15 lbs/day) and more than 2,268 kg/year

(2.5 tons/year) of VON. If suche~ emission aourccunit

emits less than 2,268 kg/year (2.5 tons/year) of VOM,

the requirements of this Subpart still apply to the

emission sourceunit if VOM emissions from the emission

sourccunit exceed 45.4 kg/day (100 lbs/day).

Notwithstanding subsection (a), the air suspension

coatcr/dryer, fluid bed dryers, tunnel dryers, and

1~t~ 

lncatcd

in Libcrtyvillc Township 

T.~ki-

County, Illinois shall be exempt from the rules of this

Cubpart, except for Cections 219.483 through 219.435,

if emissions of VON not vented to air pollution control

equipment do not exceed the following levels:

4+ for the air suspension ooatcr/drycr: 2,268 kg/year

(2.5 tons/year);

ror each fluid bed dryer: 4,535 kg/year

(5.0 tons

dr~cr: 6,803 kg/year (f.~

4-)-   for each Accelcicota: 6,803 kg/year

(7.5 tons/year).

Unless the submitted compliance plan or schedule wee

disapproved by the Agency, the owner or operator of a

facility or emission source may operate the emission

source acooraing to the sian        

sunmitced.

The plan and schedule shall meet the requirements of 35

Ill. Adrn. Code 201, Cubpc&rt H, including specific

interim dates as required in 35 Ill. Mm. Code 201.242.

4+

for each tunnel

tnn~J~’r~r’~

—-—--—

I ~

508

e-)-~jSections 219.483 through 219.485 of this Part apply to

a p-lan-tsource having one or more emission -sourcesunits

that:

1)  Are used to manufacture pharmaceuticals, and

2)  Emit more than 6.8 kg/day (15 lbs/day) of VOM and

more than 2,268 kg/year (2.5 tons/year) of VON,

or, if less than 2,268 kg/year (2.5 tons/year),

these Sections still apply if emissions from one

or more sources exceed 45.4 kg/day (100 lbs/day).

~3-~gjNo owner or operator shall violate any condition in a

permit when the condition results in exclusion of an

emission courceunit from this Subpart.

e3-~jAny pharmaceutical manufacturing source that becomes

subject to the provisions of this Subpart at any time

shall remain subject to the provisions of this Subpart

at all times.

~-)-~J.

Emissions subject to this Subpart shall be controlled

at all times consistent with the requirements set forth

in this Subpart.

~f~j

Any control device required pursuant to this Subpart

shall be operated at all times when the source it is

controlling is operated.

h3-gj Determinations of daily and annual emissions for

purposes of this Section shall be made using both data

on the hourly emission rate (or the emissions per unit

of throughput) and appropriate daily and annual data

from records of emission 3ourc-eunit operation (or

material throughput or material consumption data). In

the absence of representative test data pursuant to

Section 219.487 of this Part for the hourly emission

rate (or the emissions per unit of throughput), such

items shall be calculated using engineering

calculations, including the methods described in

Appendix B of “Control of Volatile Organic Emissions

from Manufacturing of Synthesized Pharmaceutical

Products” (EPA-450/2-78—029), incorporated by reference

in Section 219.112 of this Part. (This subsection

shall not affect the Agency’s or the USEPA’s authority

to require emission tests to be performed pursuant to

Section 219.487 of this Part.)

(Source: Amended at —  Ill. Reg. 

______,

effective 

____________

509

Section 219.481  

Control of Reactors, Distillation Units,

Crystallizers, Centrifuges and Vacuum Dryers

a)  The owner or operator shall equip all reactors,

distillation units, crystallizers, centrifuges and

vacuum dryers that are used to manufacture

pharmaceuticals with surface condensers or other air

pollution control equipment listed in subsection (b) ~

•this Section. If a surface condenser is used, it shall

be operated such that the condenser outlet gas

temperature does not exceed:

1)  248.2°K (-13°F) when condensing VON of vapor

pressure greater than 40.0 kPa (5.8 psi) at

294.3°K (70°F), or

2)  258.2°K (5°F) when condensing VOM of vapor

pressure greater than 20.0 kPa (2.9 psi) at

294.3°K (70°F), or

3)  273.2°1 (32°F) when condensing VON of vapor

pressure greater than 10.0 kPa (1.5 psi) at

294.3°K (70°F), or

4)  283.2°K (50°F) when condensing VON of vapor

pressure greater than 7.0 kPa (1.0 psi) at 294.3°K

(70°F), or

5)  298.2°1 (77°F) when condensing VON of vapor

pressure greater than 3.45 kPa (0.5 psi) at

294.3°1 (70°F).

b)  If a scrubber, carbon adsorber, thermal afterburner,

catalytic afterburner, or other air pollution control

equipment other than a surface condenser is used, such

equipment shall provide a reduction in the emissions of

VOM of 90 percent or more.

c)  The owner or operator shall enclose all centrifuges

used to manufacture pharmaceuticals and that have an

exposed VOL surface, where the VOM in the VOL has a

vapor pressure of 3.45 kPa (0.5 psi) or more at 294.3°K

(70°F), except as production, sampling, maintenance, or

inspection procedures require operator access.

(Source: Amended at 

_____,

Ill. Reg. 

______,

effective

Section 219.482  

Control of Air Dryers, Production Equipment

Exhaust Systems and Filters

510

a)  The owner or operator of an air dryer or production

equipment exhaust system used to manufacture

pharmaceuticals shall control the emissions of VON from

such emission souroceunits by air pollution control

equipment which reduces by 90 percent or more the VON

that would otherwise be emitted into the atmosphere.

b)  The owner or operator shall enclose all rotary vacuum

filters and other filters used to manufacture

pharmaceuticals and that have an exposed VOL surface,

where the VON in the VOL has a vapor pressure of 3.45

kPa (0.5 psi) or more at 294~°K(70°F), except as

production, sampling, maintenance, or inspection

procedures require operator access.

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

____________

Section 219.483  

Material Storage and Transfer

The owner or operator of a pharmaceutical manufacturing

plantsource shall:

a)  Provide a vapor balance system that is at least

90 percent effective in reducing VON emissions from

truck or railcar deliveries to storage tanks with

capacities equal to or greater than 7.57 m3 (2,000 gal)

that store VOL with vapor pressures greater than

28.0 kPa (4.1 psi) at 294.3°K(70°F), and

b)  Install, operate, and maintain pressure/vacuum

conservation vents set at 0.2 kPa (0.03 psi) or greater

on all storage tanks that store VOL with vapor

pressures greater than 10 kPa (1.5 psi) at 294.3°K

(70°F)

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

____________

_________________________ )

Section 219.485  

Leaks

The owner or operator of a pharmaceutical manufacturing

plantsource shall repair any component from which a leak of VOL

can be observed. The repair shall be completed as soon as

practicable but no later than 15 days after the leak is found.

If the leaking component cannot be repaired until the process

unit is shut down, the leaking component must then be repaired

before the unit is restarted.

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

____________

511

Section 219.486  

Other Emission Courocs Units

The owner or operator of a washer, laboratory hood, tablet

coating operation, mixing operation or any other process emission

sourccunit not subject to Sections 219.481 through 219.485 Q~

this Part, and used to manufacture pharmaceuticals shall control

the emissions of VON from such emission oourccsunits by:

a)  Air pollution control equipment which reduces by

81 percent or more the VON that would otherwise be

emitted to the atmosphere, or

b)  A surface condenser which captures all the VON which

would otherwise be emitted to the atmosphere and which

meets the requirements of Section 219.481(a) of this

Part and (b).

(Source: Amended at —  Ill. Reg. 

______,

effective 

_____________

_________________________ )

Section 219.487  

Testing

a)  Upon request by the Agency or the USEPA, the owner or

operator of any VOM emission source subject to this

Subpart or exempt from this Subpart by virtue of the

provisions of Section 219.480 of this Part shall, at

his own expense, demonstrate compliance to the Agency

and the USEPA by the methods or procedures listed in

Section 219.105(f) (1) of this Part.

b)  A person planning to conduct a VON emissions test tO

demonstrate compliance with this Subpart shall notify

the Agency and the USEPA of that intent not less than

30 calendar days before the planned initiation of the

test.

(Source: Amended at 

_____,

Ill. Reg. 

______,

effective 

__________

Section 219.489  

Recordkeeping for Air Pollution Control

Equipment

a)  The owner or operator of a pharmaceutical manufacturing

facilitysource shall maintain the following records:

1)  Parameters listed in Section 219.488(a) of this

Part -(4-)- shall be recorded.

2)  For sourcesemnission units subject to Section

219.481 of this Part, the vapor pressure of VON

512

being controlled shall be recorded for every

process.

b)  For any leak subject to Section 219.485 of this Part

which cannot be readily repaired within one hour after

detection, the following records shall be kept:

1)  The name of the leaking equipment,

2)  The date and time the leak is detected,

3)  The action taken to repair the leak, and

4)  The data& and time the leak is repaired.

C)   The following records shall be kept for emission

sourcesunits subject to Section 219.484 of this Part

which contain VOL:

1)  For maintenance and inspection:

A) The date and time each cover is opened,

B)  The length of time the cover remains open,

and

C)  The reason why the cover is opened.

2)  For production and sampling, detailed written

procedures or manufacturing directions specifying

the circumstances under which covers may be opened

and the procedures for opening covers.

d)  For each emission sourccunit used in the manufacture of

pharmaceuticals for which the owner or operator of a

pharmaceutical manufacturing plantsource claims

emission standards are not applicable, because the

emissions are below the applicability cutoffs in

Section 219.480(a) or 219.480(b) of this Part, the

owner or operator shall:

1)  Maintain a demonstration including detailed

engineering calculations of the maximum daily and

annual emissions for each such emission source

unit showing that the emissions are below the

applicability cutoffs in Section 219.480(a) or

219.480(b) of this Part, as appropriate, for the

current and prior calendar years;

2)  Maintain appropriate operating records for each

such emission source to identify whether the

applicability cutoffs in Section 219.480(a) or

513

219.480(b) of this Part, as appropriate, are ever

exceeded; and

3)  Provide written notification to the Agency and the

USEPA within 30 days of a determination that such

an emission sourceunit has exceeded the

applicability cutoffs in Section 219.480(a) or

219.480(b) of this Part, as appropriate.

e)  Records required under subsection (a) of this Section

shall be maintained by the owner or operator for a

minimum of two years after the date on which they are

made.

f)  Copies of the records shall be made available to the

Agency or the USEPA upon verbal or written request.

(Source: Amended at —  Ill. Reg. 

______,

effective 

_________

SUBPART V: AIR OXIDATION PROCESSES

Section 219.521  

Definitions (Repealed)

to the definitions of 35 Ill. Adin. Code 211, the

apply

“Air Oxidation Process”: any unit process including

aminoxidation and oxychlorincition which uses air or a

combination of air and oxygen as an oxidant in

combination with one or more organic reactants to

produce one or more organic compounds.

“Cost Effectiveness”: the annual expense for cost of

control given process stream divided by the rcductin

in emis-sions 

-of

organic material of that stream.

~Flow (F)”! Vent stream flowrate (scm/mm) at a

standard temperature of 20°C.

“Full Operating Flowrate”: Maximum operating capacity

t~f t~ht- fi1H-~

—J

“Hourly Emissions (E)”: Hourly emissions reported in

kg/hr measured at full operating flowrate.

“Net Heating Value (H)”t Vent stream net heating value

(NJ/scm), where the net enthalpy per mole of offgcis 

based on combustion at 25°Cend 760 mm Hg, but the

standard temperature for determining the volume

corresponding to one moic is 20°C,as in the definition

of “Flow.”

514

“Process Vent Stream”: An emission stream resulting

from an air oxidation process.

“Total Resource Effectiveness Index (ThE)”: Cost

cffcotivencsGin dollars per rncgagram of controlling

...ny

y..tr.iuuuu

t~ir~im 

vonto~

~o atmoopnere rrom an air

oxidation process divided by $1600/Hg, using the

criteria and methods set forth in this Subpart and

C ama D.

(Source: Repealed at 

—

Ill. Reg. 

______,

effective 

___________

Section 219.525  

Emission Limitations for Air Oxidation

Processes

a)  No person shall cause or allow the emission of volatile

organic material (VOM) from any process vent stream

unless the process vent stream is vented to a

combustion device which is designed and operated

either:

1)  To reduce the volatile organic emissions vented to

it with an efficiency of at least ninety eight

percent (98) by weight; or

2)  To emit VON at a concentration less than twenty

parts per million by volume, dry basis.

b)

AnAair

oxidation facilitiesprocess vent stream for

which an existing combustion device is employed to

control process VOM emissions e-~ej~not required to

meet the 98 percent emissions limit until the

combustion device is replaced for other reasons, which

shall be considered to include, but not be limited to,

normal maintenance, malfunction, accident, and

obsolescence. The combustion device is considered to

be replaced when:

1)  All of the device is replaced; or

2)  When the cost of the repair of the device or the

cost of replacement of part of the device exceeds

50 of the cost of replacing the entire device

with a device which complies.

c)  The limitations of subsection (a) above do not apply to

any process vent stream or combination of process vent

streams which has a Total Resource Effectiveness Index

(TRE) greater than 1.0, as determined by the following

methods:

515

1)  If an air oxidation process has more than one

process vent stream, TRE shall be based upon a

combination of the process vent streams.

2)  TRE of a process vent stream shall be determined

according to the following equation:

where:TRE

E’ a + bF°+ cF + dFH + e(FM) + fF°5

n

=

0.88k

TRE =  Total resource effectiveness

index-ri

F

Vent stream flowrate (scm/mm), at

a standard temperature of 20°C,-~

E

=

Hourly measured emissions in

kg/hr-ri.

H

Net heating value of vent stream

(MJfscm), where the net enthalpy

per mole of offgas is based on

combustion at 25°Cand 760 mm Hg,

but the standard temperature for

determining the volume

corresponding to one mole is 20°C,

as in the definition of “F1ow”~-;

a, b, c,

d,e

and f   

=

Coefficients obtained by use

of Appendix FQ.

3)  For nonchlorinated process vent streams, if the

net heating value, H, is greater than 3.6 NJ/scm,

F shall be replaced by ~~for purposes of

calculating TRE. ~  is computed as follows:

FH

/

3.6

where F and H are as defined in subsection (C) (2).

4-)   The actual numerical values used in the equation

described in subsection (C) (2) above shall be

determined as follows:

A)  All reference methods and procedures for

determining the flow, (F), hourly emissions,

516

(E), and net heating, (H), value shall be in

accordance with Appendix C.

B)  All coefficients described in subsection

(c) (2) of this Section shall be in accordance

with Appendix D.

(Source: Amended at —  Ill. Reg. 

______,

effective 

____________

Section 219.527  

Compliance Date (Repealed)

31, 1987

SUBPART W: AGRICULTURE

Section 219.541  

Pesticide Exception

The provisions of Sections 219.301 and 219.302 of this Part shall

not apply to the spraying or use of insecticides, herbicides or

other pesticides.

(Source: Amended at —  Ill. Reg. 

______,

effective

)

Section 219.562

SUBPART X: CONSTRUCTION

Paving Operations

The provisions of Sections 219.301 and 219.302 of this Part shall

not apply to the application of paving asphalt and pavement

marking paint from sunrise to sunset.

(Source: Amended at

Section 219.581

Ill. Reg. 

______,

effective

Bulk Gasoline Plants

a)  Subject to Ssubsection (e) of this Section, no person

may cause or allow the transfer of gasoline from a

delivery vessel into a stationary storage tank located

at a bulk gasoline plant unless-e-j

215,     

V, by Dc

Each owner or operator of en emission source subject to 35 Il-I.

Ad~i. Code 215, subpart V, as of December 31, 1987 shall have

$h-~ 

~tandards and limitations

nf ~ 

T11 ~-1~ C~niir’

(Source: Repealed at —  Ill. Reg. 

______,

effective

SUBPART 1: GASOLINE DISTRIBUTION

1)  The delivery vessel and the stationary

517

storage tank are each equipped with a vapor

collection system that meets the requirements of

2)

subsectionEach

vapor collection(d)

(4) of thissystemSectionis

operating,-~7~

3)  The delivery vessel displays the appropriate

sticker pursuant to the requirements of Sections

219.584 (b) or (d) of this Part~j~

4)  The pressure relief valve(s) on the stationary

storage tank and the delivery vessel are set to

release at no less than 0.7 psi or the highest

pressure allowed by state or local fire codes or

the guidelines of the National Fire Prevention

Association7~and

5)  The stationary storage tank is equipped with a

submerged loading pipe.

b)  Subject to subsection (f) of this Section, no person

may cause or allow the transfer of gasoline from a

stationary storage tank located at a bulk gasoline

plant into a delivery vessel unless:

1)  The requirements set forth in subsections (a) (1)

through (a) (4) of this Section are met7j~and

2)  Equipment is available at the bulk gasoline plant

to provide for the submerged filling of the

delivery vessel or the delivery vessel is equipped

for bottom loading.

c)  Subject to subsection (e) of this Section, each owner

of a stationary storage tank located at a bulk gasoline

plant shall:

1)  Equip each stationary storage tank with a vapor

control system that meets the requirements of

subsection (a) or (b) of this Section, whichever

is applicable,-~

2)  Provide instructions to the operator of the bulk

gasoline plant describing necessary maintenance

operations and procedures for prompt notification

of the owner in case of any malfunction of a vapor

control system,~and

3)  Repair, replace or modify any worn out or

malfunctioning component or element of design.

518

d)  Subject to subsection (e) of this Section, each

operator of a bulk gasoline plant shall:

1)  Maintain and operate each vapor control system in

accordance with the owner’s instructionsT~

2)  Promptly notify the owner of any scheduled

maintenance or malfunction requiring replacement

or repair of a major component of a vapor control

system7-.~and

3)  Maintain gauges, meters or other specified testing

devices in proper working orderT~

4)  Operate the bulk plant vapor collection system and

gasoline loading equipment in a manner that

prevents:

A)  Gauge pressure from exceeding 45.7 cm (18

in.) of water and vacuum from exceeding 15.2

cm (6 in.) of water, as measured as close as

possible to the vapor hose connection7j. and

B)  A reading equal to or greater than 100

percent of the lower explosive limit (LEL

measured as propane) when tested in

accordance with the procedure described in

“Control of Volatile Organic Compound Leaks

from Gasoline Tank Trucks and Vapor

Collection Systems”, Appendix B, EPA 450/

2—78-051, (incorporated by reference in

Section 219.112 of this Part)T~and

C)  Avoidable leaks of liquid during loading or

unloading operations.

5)  Provide a pressure tap or equivalent on the bulk

plant vapor collection system in order to allow

the determination of compliance with subsection

(d) (4) (A) of this Section,-~and

6)  Within 15 business days after discovery of any

leak by the owner, the operator, the Agency or the

USEPA, repair and retest a vapor collection system

which exceeds the limits of subsection (d) (4) (A)

or (B) of this Section.

e)  The requirements of subsections (a), (c) and (d) ~

this Section shall not apply to:

1)  Any stationary storage tank with a capacity of

less than 2,177 1 (575 gal)-~-~or

519

2)  Any bulk gasoline plant whose daily gasoline

throughput is less than 15,140 1 (4,000 gal/day)

on a thirty-day rolling average.

f)  The requirements of subsection (b) shall apply only to

bulk gasoline plants whose daily gasoline throughput is

greater than or equal to 15,140 1 (4,000 gal/day) on a

thirty-day rolling average.

g)  Any bulk gasoline plant which is ever subject to

subsections (a), (b), (c), or (d) of this Section shall

always be subject to these paragraphs.

(Source: Amended at —  Ill. Reg. 

______,

effective 

____________

Section 219.582  

Bulk Gasoline Terminals

a)  No person shall cause or allow the transfer of gasoline

into any delivery vessel from any bulk gasoline

terminal unless:

1)  The bulk gasoline terminal is equipped with a

vapor control system that limits emission of VON

to 80 mg/i (0.00067 lbs/gal) of gasoline loaded;

2)  The vapor control system is operating and all

vapors displaced in the loading of gasoline to the

delivery vessel are vented only to the vapor

control system;

3)  There is no liquid drainage from the loading

device when it is not in use;

4)  All loading and vapor return lines are equipped

with fittings which are vapor tight; and

5)  The delivery vessel displays the appropriate

sticker pursuant to the requirements of Section

219.584(b) or (d) of this Part or, if the

terminal is driver—loaded, the terminal owner or

operator shall be deemed to be in compliance with

this Section when terminal access authorization is

limited to those owners and/or operators of

delivery vessels who have provided a current

certification as required by Section 219.584(c) (3)

of this Part.

Bulk gasoline terminals wore

actions to achieve compliance

required to

which are

take ocrtai~

summcirised in

35 Ill. Adm. Code 215, ~ppcna1x 

520

e~) The operator of a bulk gasoline terminal shall:

I)  Operate the terminal vapor collection system and

gasoline loading equipment in a manner that

prevents:

A)  Gauge pressure from exceeding 18 inches of

water and vacuum from exceeding 6 inches of

water as measured as close as possible to the

vapor hose connection; and

B)  A reading equal to or greater than 100

percent of the lower explosive limit (LEL

measured as propane) when tested in

accordance with the procedure described in

EPA 450/2-78-051 Appendix B~ incorporated by

reference in Section 219.112 of this Part

and

C)  Avoidable leaks of liquid during loading or

unloading operations.

2)  Provide a pressure tap or equivalent on the

terminal vapor collection system in order to allow

the determination of compliance with Section

219.582(d) (1) (A) of this Part and

3)  Within 15 business days after discovery of the

leak by the owner, operator, or the Agency repair

and retest a vapor collection system which exceeds

the limits of subsection (c) (1) (A) or (B) of this

Section.

(Source: Amended at  

Ill. Reg. 

______,

effective 

____________

Section 219.583  

Gasoline Dispensing Facilities 

—

Storage Tank

Filling Operations

a)  Subject to subsection (b) below, no person shall cause

or allow the transfer of gasoline from any delivery

vessel into any stationary storage tank at a gasoline

dispensing faci1ityo~erationunless:

1)  The tank is equipped with a submerged loading

pipe; and

2)  The vapors displaced from the storage tank during

filling are processed by a vapor control system

that includes one or more of the following:

521

A)  A vapor collection system that meets the

requirements of subsection (d) (4) below; or

B)  A refrigeration—condensation system or any

other system approved by the Agency and

approved by the USEPA as a SIP revision, that

recovers at least 90 percent by weight of all

vaporized organic material from the equipment

being controlled; and

C)  The delivery vessel displays the appropriate

sticker pursuant to the requirements of

Section 219.584(b) or (d) of this Part.

b)  The requirements of subsection (a) (2) above shall not

apply to transfers of gasoline to a stationary storage

tank at a gasoline dispensing facilityoperation if:

1)  The tank is equipped with a floating roof, or

other system of equal or better emission control

as approved by the Agency and approved by the

USEPA as a SIP revision;

2)  The tank has a capacity of less than 2000 gallons

and was in place and operating before January 1,

1979; or

3)  The tank has a capacity of less than 575 gallons.

c)  Subject to subsection (b) above, each owner of a

gasoline dispensing facilityoperation shall:

1)  Install all control systems and make all process

modifications required by subsection (a) above;

2)  Provide instructions to the operator of the

gasoline dispensing facilityoperation describing

necessary maintenance operations and procedures

for prompt notification of the owner in case of

any malfunction of a vapor control system; and

3)  Repair, replace or modify any worn out or

malfunctioning component or element of design.

d)  Subject to subsection (b) above, each operator of a

gasoline dispensing facility operation shall:

1)  Maintain and operate each vapor control system in

accordance with the owner’s instructions;

2)  Promptly notify the owner of any scheduled

maintenance or malfunction requiring replacement

522

or repair of a major component of a vapor control

system;

3)  Maintain gauges, meters or other specified testing

devices in proper working order;

4)  Operate the vapor collection system and delivery

vessel unloading points in a manner that prevents:

A)  A reading equal to or greater than 100

percent of the lower explosive limit (LEL

measured as propane) when tested in

accordance with the procedure described in

EPA 450/2-78-051 Appendix B, and

B)  Avoidable leaks of liquid during the filling

of storage tanks; and

5)  Within 15 business days after discovery of the

leak by the owner, operator, or the Agency, repair

and retest a vapor collection system which exceeds

the limits of subsection (d) (4) (A) above.

Cesolino dispensing facilities wore required to take

certain actions to achieve compliance which are

summariccd in 35 Ill. Adm. Code 215.Appondix C.

(Source: Amended at —  Ill. Reg. 

______,

effective 

____________

Section 219.584  

Gasoline Delivery Vessels

a)  Any delivery vessel equipped for vapor control by use

of vapor collection equipment:

1)  Shall have a vapor space connection that is

equipped with fittings which are vapor tight;

2)  Shall have its hatches closed at all times during

loading or unloading operations, unless a top

loading vapor recovery system is used;

3)  Shall not internally exceed a gauge pressure of 18

inches of water or a vacuum of 6 inches of water;

4)  Shall be designed and maintained to be vapor tight

at all times during normal operations;

5)  Shall not be refilled in Illinois at other than:

523

A)  A bulk gasoline terminal that complies with

the- requirements of Section 219.582 of this

Part or

B)  A bulk gasoline plant that complies with the

requirements of Section 219.581(b) of this

Part.

6)  Shall be tested annually in accordance with Method

27, 40 CFR 60, Appendix A, incorporated by

reference in Section 219.105 of this Part. Each

vessel must be repaired and retested within 15

business days after discovery of the leak by the

owner, operator, or the Agency, when it fails to

sustain:

A)  A pressure drop of no more than •three inches

of water in five minutes; and

B)  A vacuum drop of no more than three inches of

water in five minutes.

b)  Any delivery vessel meeting the requirements of

subsection (a) of this Section shall have a sticker

affixed to the tank adjacent to the tank manufacturer’s

data plate which contains the tester’s name, the tank

identification number and the date of the test. The

sticker shall be in a form prescribed by the Agency,

and, for those delivery vessels subject to 35 Ill. Adm.

Code 215 as of December 31, 1987 shall have been

displayed no later than December 31, 1987.

c)  The owner or operator of a delivery vessel shall:

1)  Maintain copies of any test required under

subsection (a) (6) of this Section for a period of

3 years;

2)  Provide copies of these tests to the Agency upon

request; and

3)  Provide annual test result certification to bulk

gasoline plants and terminals where the delivery

vessel is loaded.

d)  Any delivery vessel which has undergone and passed a

test in another state which has a USEPA-approved leak

testing and certification program will satisfy the

requirements of subsection (a) of this Section.

Delivery vessels must display a sticker, decal or

stencil approved by the state where tested or comply

with the requirements of subsection (b) of this

524

S~tion. All such stickers, decals or stencils shall

have been displayed no later than December 31, 1987,

for delivery vessels subject to 35 Ill. Adm. Code 215

as of December 31, 1987.

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

____________

Section 219.585  

Gasoline Volatility Standards

a)  No person shall sell, offer for sale, dispense, supply,

offer for supply, or transport for use in Illinois

gasoline whose Reid vapor pressure exceeds the

applicable limitations set forth in subsections (b) and

(c) of this Section during the regulatory control

periods, which shall be July ~j~y1 to August 31

September 15 for retail outlets, wholesale

purchaser—consumer facilities, and all other

facilities.

b)  The Reid vapor pressure of gasoline, a measure of its

volatility, shall not exceed 9.~Qpsi (~5.562.07kPa)

during the regulatory control period in 1990 and each

year thereafter.

c)  The Reid vapor pressure of ethanol blend gasolines

shall not exceed the limitations for gasoline set forth

in subsection (b) of this Section by more than 1.0 psi

(6.9 kPa). Notwithstanding this limitation, blenders

of ethanol blend gasolines whose Reid vapor pressure is

less than 1.0 psi above the base stock gasoline

immediately after blending with ethanol are prohibited

from adding butane or any product that will increase

the Reid vapor pressure of the blended gasoline.

d)  All sampling of gasoline required pursuant to the

provisions of this Section shall be conducted by one or

more of the following approved methods or procedures

which are incorporated by reference in Section 215.105.

1)  For manual sampling, ASTM D4057;

2)  For automatic sampling, ASTM D4177;

3)  Sampling procedures for Fuel Volatility, 40 CFR 80

Appendix D.

e)  The Reid vapor pressure of gasoline shall be measured

in accordance with either test method ASTM D323 or a

modification of ASTM D323 known as the “dry method” as

set forth in 40 CFR 80, Appendix E, incorporated by

reference in 35 Ill. Adm. Code 2-~2~  

of this

525

Part. For gasoline 

—

oxygenate blends which contain

water—extractable oxygenates, the Reid vapor pressure

shall be measured using the dry method test.

f)  The ethanol content of ethanol blend gasolines shall be

determined by use of one of the approved testing

methodologies specified in 40 CFR 80, Appendix F,

incorporated by reference in 35 Ill. Adm. Code

2+~219.~UZ of this part.

g)  Any alternate to the sampling or testing methods or

procedures contained in subsections (d), (e), and (f)

of this Section must be approved by the Agency, which

shall consider data comparing the performance of the

proposed alternative to the performance of one or more

approved test methods or procedures. Such data shall

accompany any request for Agency approval of any

alternate test procedure. If the Agency determines

that such data demonstrates that the proposed

alternative will achieve results equivalent to the

approved test methods or will achieve results.

equivalent to the approved test methods or procedures,

the Agency shall approve the proposed alternative.

h)  Each refiner or supplier that distributes gasoline or

ethanol blends shall:

1)  During the regulatory control period, state that

the Reid vapor pressure of all gasoline or ethanol

blends leaving the refinery or distribution

facility for use in Illinois complies with the

Reid vapor pressure limitations set forth in 35

Ill. Adm. Code ~4-S~J~.585(b)and (c) of this Part.

Any facilitysource receiving this gasoline shall

be provided with a copy of an invoice, bill of

lading, or other documentation used in normal

business practice stating that the Reid vapor

pressure of the gasoline complies with the State

Reid vapor pressure standard.

2)  Maintain records for a period of one year on the

Reid vapor pressure, quantity shipped and date of

delivery of any gasoline or ethanol blends leaving

the refinery or distribution facility for use in

Illinois. The Agency shall be provided with

copies of such records if requested.

(Source: Amended at —  Ill. Reg. 

______,

effective 

____________

526

Section 219.586  

Gasoline Dispensing Fecilitiespperations 

—

Motor Vehicle Fueling Operations

a)  For the purposes of this e~ection, the following

definitions apply.

1)  Average Mnjonthly ~o1ume÷ means tche amount of

motor vehicle fuel dispensed per month from a

gasoline dispensing facility operation based upon

a monthly average for the 2—year period of

November, 1990 through October, 1992 or, if not

available, the monthly average for the most recent

twelve calendar months. Monthly averages are to

include only those months when the facility

operation was operating.

2)

________

~~uaes no later additions or amenainents.

3)  Completion of installation÷means tThe successful

passing of one or more of the following tests

applicable to the installed vapor collection and

control system: Dynamic Backpressure Test,

Pressure Decay/Leak Test, and Liquid Blockage

Test~ (United States Environmental Protection

Agency, Washington D.C., EPA-450/3 91- 002b).

These tests arc hereby incorporated by reference

at 219.112 of this Part. This incorporation

includes no later additions or amendments.)

4)  Constructed+ means f~abricated, erected or

installed; refers to any facility, emission source

or air pollution control equipment.

5)  CARB÷means California Air Resources Board, P.O.

Box 2815, Sacramento, CA 95812.

6)  Employee÷means aAny person who performs work for

an employer.

7)  ~         

means aAny building, structure,

installation, operation or combination thereof

Certified+ means aAny vapor collection and control

system which has been tested and approved by CARS

as having a vapor recovery and removal efficiency

of at least 95 (by weight) shall constitute a

certified vapor collection and control system.

CARB testing and approval is pursuant to the CARB

manual, hereby incorporated by reference ~

219.112 of this Part (California Air Resources

Board, Compliance Division, Compliance Assistance

Program: Facilities Phase I & II (October 1988,

r-~~v.

Mm~h

1’)fll C~T?R M~r~i1~l). 

This incorporat~n

527

located on contiguous properties and under common

ownership that provides for the dispensing of

motor vehicle fuel.

8)  Gasoline ~ispensing Facilityoperation÷means aAny

facility operation where motor vehicle fuel is

dispensed into motor vehicle fuel tanks or

portable containers from a storage tank with a

capacity of 2176 liters (575 gallons) or more.

9)  Modification÷means aAny change, removal or

addition, other than an identical replacement, of

any component contained within the vapor

collection and control system.

10) Motor ~yehicle÷ means aAny self-propelled vehicle

powered by an internal combustion engine

including, but not limited to, automobiles and

trucks. Specifically excluded from this

definition are watercraft and aircraft.

11) Motor ‘~ehicle~uel÷ means aAny petroleum

distillate having a Reid vapor pressure of more

than 27.6 kilopascals (kPa) (four pounds per

square inch) and which is used to power motor

vehicles.

12) Owner or GQperator÷means aAny person who owns,

leases, operates, manages, supervises or controls

(directly or indirectly) a gasoline dispensing

facilityoperation.

13) Reid Vyapor Ppressure÷~3~orgasoline, ~ shall be

measured in accordance with either the method ASTM

D323 or a modification of ASTM D323 known as the

“dry method” as set forth in 40 CFR 80, Appendix

E, incorporated by references in 35 Ill. Adm. Code

215.105219.112 of this Part.

14) Vapor G~ollection and G~ontrol &~ystem÷means aAny

system certified by CARB which limits the

discharge to the atmosphere of motor vehicle fuel

vapors displaced during the dispensing of motor

vehicle fuel into motor vehicle fuel tanks.

b)  The provisions of subsection (c) below shall apply to

any gasoline dispensing facilityoperation which

dispenses an average monthly volume of more than 10,000

gallons of motor vehicle fuel per month. Compliance

shall be demonstrated in accordance with the schedule

provided in subsection (d) below.

528

C)   No owner or operator of a gasoline dispensing facility

o~erationsubject to the requirements of subsection (b)

above shall cause or allow the dispensing of motor

vehicle fuel at any time from a motor fuel dispenser

unless the dispenser is equipped with and utilizes a

vapor collection and control system which is properly

installed and operated as provided below:

1)  Any vapor collection and control system installed,

used or maintained has been CARB certified.

2)  Any vapor collection and control system utilized

is maintained in accordance with the

manufacturer’s specifications and the

certification.

3)  No elements or components of a vapor collection

and control system are modified, removed, replaced

or otherwise rendered inoperative in a manner

which prevents the system from performing in

accordance with its certification and design

specifications.

4)  A vapor collection and control system has no

defective, malfunctioning or missing components.

5)  Operators and employees of the gasoline dispensing

facilityoperation are trained and instructed in

the proper operation and maintenance of a vapor

collection and control system.

6)  Instructions are posted in a conspicuous and

visible place within the motor fuel dispensing

area and describe the proper method of dispensing

motor vehicle fuel with the use of the vapor

collection and control system.

d)  In conjunction with the compliance provisions of

Section 219.105 of this Part, faciliticsoperations

subject to the requirements of subsection (c) above

shall demonstrate compliance according to the

following:

1)  FacilitiesOperations that commenced construction

after November 1, 1990, must comply by May 1,

1993.

2)  FaciliticoOperations that commenced construction

before November 1, 1990, and dispense an average

monthly volume of more than 100,000 gallons of

motor fuel per month must comply by November 1,

1993.

529

3)  FacilitiesOperations that commenced construction

before November 1, 1990, and dispense an average

monthly volume of less than 100,000 gallons of

motor fuel per month must comply by November 1,

1994.

4)  New facilitiesoperations constructed after the

adoption of this Section shall comply with the

requirements of subsection (c) above upon startup

of the faoilityo~eration.

5)  Existing faciliticooperations previously exempted

from but which become subject to the requirements

of subsection (c) above after May 1, 1993 shall

comply with the requirements of subsection (c)

above within six calendar months of the date from

which the faci1ityo~erationbecomes subject.

e)  Any gasoline dispensing f-acilityo~erationthat becomes

subject to the provisions of subsection (c) above at

any time shall remain subject to the provisions of

subsection (c) above at all times.

f)  Upon request by the Agency, the owner or operator of a

gasoline dispensing faoilityoPeration which claims to

be exempt from the requirements of this Section shall

submit records to the Agency within 30 calendar days

from the date of the request which demonstrate that the

gasoline dispensing -f-acilit-yoperation is in fact

exempt.

g)  Recordkeeping and reporting:

1)  Any gasoline dispensing -f-a-eilityoPeration subject

to subsection (c) above shall retain at the

facilityoperation copies of the registration

information required at subsection (h) below.

2)  Records and reports required pursuant to this

subsection shall be made available to the Agency

upon request. Records and reports which shall be

maintained by the owner or operator of the

gasoline dispensing facility operation shall

clearly demonstrate:

A)  That a certified vapor collection and control

system has been installed and tested to

verify its performance according to its

specifications.

530

B)  That proper maintenance has been conducted in

accordance with the manufacturer’s

specifications and requirements.

C)  The time period and duration of all

malfunctions of the vapor collection and

control system.

D)  The motor vehicle fuel throughput of the

facilityo~eration for each calendar month of

the previous year.

E)  That operators and employees are trained and

instructed in the proper operation and

maintenance of the vapor collection and

control system and informed as to the

potential penalties associated with the

violation of any provision of this Section.

h)  Any gasoline dispensing faci1ityo~erationsubject to

subsection (c) above shall be exempt from the permit

requirements specified under 35 Ill. Adm. Code 201.142,

201.143 and 201.144 of this Part for its vapor

collection and control systems, provided that:

1)  Upon the installation of a vapor collection and

control system, the owner or operator of the

gasoline dispensing facilityo~erationsubmits to

the Agency a registration which provides at

minimum the facilityoperation name and address,

signature of the owner or operator, the CARB

Executive Order Number for the vapor collection

and control system to be utilized, the number of

nozzles (excluding diesel or kerosene) used for

motor vehicle refueling, the monthly average

volume of motor vehicle fuel dispensed, the

location (including contact person’s name,

address, and telephone number) of records and

reports required by this Section, and the date of

completion of installation of the vapor collection

and control system.

2)  The registration is submitted to the Agency within

30 days of completion of such installation.

3)  A copy of the registration information is

maintained at the gasoline dispensing

facilityoperation.

4)  Upon the modification of an existing vapor

collection and control system, the owner or

operator of the gasoline dispensing facility

531

operation submits to the Agency a registration

that details the changes to the information

provided in the previous registration of the vapor

collection and control system and which includes

the signature of the owner or operator. The

registration must be submitted to the Agency

within 30 days of completion of such modification.

(Source: Amended at 

_____

Ill. Reg. 

________,

effective 

_________

______________________ )

SUBPART Z: DRY CLEANERS

Section 219.601  

Perchioroethylene Dry Cleaners

The owner or operator of a dry cleaning facility operation which

uses perchloroethylene shall:

a)  Vent the entire dryer exhaust through a properly

designed and functioning carbon adsorption system or

equally effective control device; and

b)  Emit no more than 100 ppmv of VON from the dryer

control device before dilution, or achieve a 90 percent

average reduction before dilution; and

c)  Immediately repair all components found to be leaking

liquid VOM; and

d)  Cook or treat all diatomaceous earth filters so that

the residue contains 25 kg (55 ib) or less of volatile

organic material per 100 kg (220 lb) of wet waste

material; and

e)  Reduce the vVOM from all solvent stills to 60 kg (132

lb) or less per 100 kg (220 lb) of wet waste material;

and

f)  Drain all filtration cartridges in the filter housing

or other sealed container for at least 24 hours before

discarding the cartridges; and

g)  Dry all drained filtration cartridges in equipment

connected to an emission reduction system or in a

manner that will eliminate emission of volatile organic

material to the atmosphere.

(Source: Amended at —  Ill. Reg. 

______,

effective 

_____________

Section 219.602  

Exemptions

532

The provisions of Section 219.601 are not applicable to

perchloroethylene dry cleaning operations which are coin—operated

or to dry cleaning faciliticooperations consuming less than 30

gal per month (360 gal per year) of perchioroethylene.

(Source: Amended at 

—

Ill. Reg. 

______,

effective

)

Section 219.603  

Leaks

The presence of leaks shall be determined for purposes of Section

219.601(c) of this Part by a visual inspection of the following:

hose connections, unions, couplings and valves; machine door

gaskets and seatings; filter head gasket and seating; pumps; base

tanks and storage containers; water separators; filter sludge

recovery; distillation unit; diverter valves; saturated lint from

lint baskets; and cartridge filters.

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

____________

Section 219.604  

Compliance Dates (Repealed)

Every owner -or operator of an emission s-ourcc previously subject

to 35 Ill. Adm. Code 215, Subpart Z, shall have complied with its

ot-andardo and limitations in accordance with the applicable dates

(Source: Repealed at —  Ill. Reg. 

______

effective

~..~uding 

_________

applicable, no later thai., for

and (b), April 21, 198~

Unless the submitted compliance plan or schedule was

dicapprovod by the Agency, the owner or operator of a

facility or emission source may operate the emission

source according to the plan and schedule as 

submitted.

The plan and schedule shall meet the requirements of 

3-5

Ill. Adm. Code 201, Subpart H, including specific

interim d~to~as required in 35 Ill. Adm. Code 201.242.

Section 219.605  

Compliance Plan (Repealed)

The owner or operator of an emission source subject to

this Subpart shall have submitted to the Agency a

oomplianr~r 

r~1~-~n 

-~iimnt 

trt

~.S

T1’I.

C’r~1c~2C~1,

Subpart 

~rn-’-+

... ~--‘~

completion schedule

219.601(a)

533

(Source: Repealed at —  Ill. Reg. 

______,

effective

Section 219.606  

Exception to Compliance Plan (Re~ealedI

Coin-operated dry cleaning operations and dry cleaning facilities

consuming ices than 30 gal per month (360 gal per year) of

pcrchloroothylcno

arc not required to submit or obtain an Agency

approved compliance plan or project oom~1otion schedule.

(Source: Repealed at —  Ill. Reg. 

______,

effective 

___________

_________________________ )

Section 219.608  

Operating Practices for Petroleum Solvent Dry

Cleaners

In order to minimize fugitive solvent emissions, the owner or

operator of a petroleum solvent dry cleaning facilitysource shall

employ good housekeeping practices including the following:

a)  General Housekeeping Requirements

1)  Equipment containing solvent (washers, dryers,

extractors and filters) shall remain closed at all

times except during load transfer and maintenance.

Lint filter and button trap covers shall remain

closed except when solvent—laden material is being

removed.

2)  Cans, buckets, barrels and other containers of

solvent or of solvent—laden material shall be

covered except when in use.

3)  Solvent-laden material shall be exposed to the

atmosphere only for the minimum time necessary for

load transfer.

b)  Installation and operation of equipment:

1)  All cartridge filters shall be enclosed and

operated in accordance with the procedures and

specifications recommended by the manufacturer for

the cartridge filter. After installation, the

cartridges shall be inspected, monitored and

maintained in accordance with the manufacturer’s

recommendations; and

2)  Vents on containers for new solvent and for

solvent-containing waste shall be constructed and

maintained so as to minimize solvent vapor

emissions. Criteria for the minimization of

solvent vapor emissions include the elimination of

534

solvent buckets and barrels standing open to the

atmosphere, and the repair of gaskets and seals

that expose solvent-rich environments to the

atmosphere, to be determined through visual

inspection.

(Source: Amended at 

—

Ill. Reg.    

, effective 

____________

_________________________)

Section 219.609  

Program for Inspection and Repair of Leaks

a)  The owner or operator of a petroleum solvent dry

cleaning facilitysource shall conduct the following

visual inspections on a weekly basis:

1)  Washers, dryers, solvent filters, settling tanks,

vacuum stills and containers and conveyors of

petroleum solvent shall be inspected for visible

leaks of solvent liquid.

2)  Pipes, hoses and fittings shall be inspected for

active dripping or dampness.

3)  Pumps and filters shall be inspected for leaks

around seals and access covers.

4)  Gaskets and seals shall be inspected for wear and

defects.

b)  Leaks of petroleum solvent liquid and vapors shall be

repaired within three working days of detection, unless

necessary replacement parts are not on site.

1)  If necessary, repair parts shall be ordered within

three working days of detection of the leak.

2)  The leak shall be repaired within three days of

delivery of necessary parts.

(Source: Amended at  

Ill. Reg. 

______,

effective 

____________

Section 219.610  

Testing and Monitoring

a)  Compliance with Sections 219.607(b) (2), 219.608 and

219.609 of this Part shall be determined by visual

inspection; and

b)  Compliance with Sections 219.607 (a) (2) and (b) (1) Q~

this Part shall be determined by methods described in

EPA4SO/3-82-009 (1982) incorporated by reference in

Section 219.112 of this Part.

535

c)  If a control device is used to comply with Section

219.607(a) (1) of this Part, then compliance shall be

determined using 40 CFR 60 Appendix A, Method 25 (3.984)

incorporated by reference in Section 219.112 of this

Part.

(Source: Amended at  

Ill. Reg.    

,  effective 

____________

_________________________ )

Section 219.611  

Exemption for Petroleum Solvent Dry Cleaners

The provisions of Sections 219.607 through 219.610 of this Part

shall not apply to petroleum solvent dry cleaning facilities

sources whose emissions of volatile organic material do not

exceed 91 Mg (100 tons) per year in the absence of pollution

control equipment or whose emissions of VOM, as limited by the

operating permit, will not exceed 91 Mg (100 tons) per year in

the absence of pollution control equipment.

(Source: Amended at  

Ill. Reg. 

______,

effective 

____________

Section 219.612  

Compliance Dates (Repealed)

Owners and operators of emission sources subject to 35 Ill. Adm.

‘rir~r’ 21 

c~cn~th~r~ugh

21

~flfl  

r~f fl~rr’mhr’~r ~1

1’)~7  

11 h~’r’

complied with thc x    

ements set forth therein no 1

December 31, 1987.

(Source: Repealed at 

—

Ill. Reg. 

______,

effective

Section 219.613  

Compliance Plan (Repealed)

a-)-   The owner or operator of an emission source formerly

subject to 35 Ill. Adin. Code 215.610(a) as of Hay 31,

1937 shall have submitted to the Agency a compliance

plan, including a project completion schedule where

applicable, no later than Hay 31, 1987.

s-)-

The plan and schedule shall meet the requirements of 35

Ill. Adm. Code 201.

(Source: Repealed at —  Ill. Reg. 

______,

effective —

SUBPART AA: PAINT AND INK MANUFACTURING

Section 219.620  Applicability

a)  This s~ubpartshall apply to all paint and ink

manufacturing plantssources which:

536

1)  Include process emission oouroeeunits not subject

to Subparts B, E, F (excluding Section 219.204(1)

of this Part), H jexcluding Section 219.405 Q~

this Part), Q, R, S, T (excludinc~ Section 219.486

of this Part). V, X, Y~.e~Z or BB of this Part;

and which as a group both:

A) ~Uave maximum theoretical emissions of 91 Mg

(100 tons) or more per calendar year of VON

if no air pollution control equipment were

used, and

B)  eAre not limited to less than 91 Mg (100

tons) of VOM emissions per 

calendar

year in

the absence of air pollution control

equipment, through production or capacity

limitations contained in a federally

enforceable construction permit or a SIP

revision, or

2)  Produce more than 7,570,820 1 (2,000,000 gal) per

calendar year of paint or ink formulations, which

contain less than 10 percent (by weight) water,

and.ink formulations not containing as the primary

solvents water, Magie oil or glycol.

b)  For the purposes of this Subpart, uncontrolled VON

emissions are the emissions of VOM which would result

if no air pollution control equipment were used.

(Source: Amended at  

Ill. Reg. 

______,

effective 

___________

Section 219.621  

Exemption for Waterbase Material and

Heatset—Off set Ink

The requirements of Sections 219.624 and 219.625 and Section

219.628(a) of this Part shall not apply to equipment while it is

being used to produce either:

~aint

or ink formulations which contain 10 percent or

more (by weight) water, or

b)  4~nkscontaining Magie oil and glycol as the primary

solvent.

(Source: Amended at  

Ill. Reg.    

,  effective 

___________

_________________________ )

537

Section 219.623  

Permit Conditions

No person shall violate any condition in a permit when the

condition results in exclusion of the plan-tsource or an emission

sourocunit from this Subpart.

(Source: Amended at 

—

Ill. Reg.    

, effective 

____________

_________________________)

Section 219.624  

Open-4~~opMills, Tanks, Vats or Vessels

No person shall operate an open—top mill, tank, vat or vessel

with a volume of more than 45 1 (12 gal) for the production of

paint or ink unless:

The mill, tank, vat or vessel is equipped with a cover

which completely covers the mill, tank, vat or vessel

opening except for an opening no larger than necessary

to allow for safe clearance for a mixer shaft. Such

cover shall extend at least 1.27 cm (0.5 in.) beyond

the outer rim of the opening or be attached to the rim.

b)  The cover remains closed except when production,

sampling, maintenance or inspection procedures require

access.

c)  The cover is maintained in good condition such that,

when in place, it maintains contact with the rim of the

opening for at least 90 percent of the circumference of

the rim.

(Source: Amended at  

Ill. Reg. 

______,

effective 

____________

Section 219.628  

Leaks

The owner or operator of a paint or ink manufacturing plantsource

shall, for the purpose of detecting leaks, conduct an equipment

monitoring program as set forth below:

a)  Each pump shall be checked by visual inspection each

calendar week for indications of leaks, that is,

liquids dripping from the pump seal. If there are

indications of liquids dripping from the pump seal, the

pump shall be repaired as soon as practicable, but no

later than 15 calendar days after the leak is detected.

b)  Any pump, valve, pressure relief valve, sampling

connection, open—ended valve and flange or connector

containing a fluid which is at least 10 percent VON by

weight which appears to be leaking on the basis of

sight, smell or sound shall be repaired as soon as

538

practicable, but no later than 15 calendar days after

the leak is detected.

c)  A weather proof, readily visible tag, in bright colors

such as red or yellow, bearing

an identification number

and the date on which the leak was detected shall be

attached 

to leaking equipment. The tag may be removed

upon repair, that is, when the equipment is adjusted or

otherwise altered to allow operation without leaking.

d)  When a leak is detected, the owner or operator shall

record the date 

of detection and repair and

the record

shall be retained at the plantsource for at least two

years from the date of each detection or each repair

attempt. The record shall be made available to any

person upon verbal or written request during business

hours.

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

____________

Section 219.636  

Compliance Schedule

Every owner or operator of an emission source subject to the

control requirements of this Subpart shall comply with the

requirements thereof on and after a date consistent with Section

219.106 of this Part.

(Source: Amended at —  Ill. Reg. 

______,

effective 

____________

Section 219.637  

Recordkeeping and Reporting

a)  Upon request by the Agency, the owner or operator of a~

emission source which claims to be exempt from the

requirements of this Subpart shall submit records to

the Agency within 30 calendar days from the date of the

request which document that the emission source

is in fact exempt from this Subpart. These records

shall include (but are not limited to) the percent

water (by weight) in the paint or ink being produced

and the quantity of Magie oil, glycol and other

solvents in the ink being produced.

b)  Every owner or operator of an emission source which is

subject to the requirements of this Subpart shall

maintain all records necessary to demonstrate

compliance with those requirements at the

facilitysource for three years.

(Source: Amended at  

Ill. Reg. 

______,

effective 

____________

539

SUBPART BB: POLYSTYRENE PLANTS

Section 219.875219.640  ApplicabilitY of Cubpart BB

The provisions of this Subpart shall apply to polystyrene plants:

a)  Which use continuous processes to manufacture

polystyrene 

polybutadiene co-polymer; and

b)  Which fall within Standard Industrial Classification

Group No. 282, Industry No. 2821, except that the

manufacture of polystyrene resins need not be the

primary manufacturing process at the

plant.

(Source: Renumbered from Section 219.875 and amended at

Ill. Reg. 

_____,

effective 

______________________)

Section 219.877219.642 Emissions Limitation at Polystyrene

Plants

No person shall cause or allow the emissions of VOM from the

material recovery section to exceed 0.12 kg of VON per 1000 kg of

polystyrene resin produced.

(Source: Renumbered from Section 219.877 at  

Ill. Reg. 

_____

effective ____________________________

Section 219.886219.644 Emissions Testing

a)  Upon a reasonable request by the Agency, the owner or

operator of a polystyrene plant subject to this Subpart

shall at his own expense demonstrate compliance by use

of the following method: 40 CFR 60, Appendix A, Method

25

—

Determination of Total Gaseous Non—Methane Organic

Emissions as Carbon (1984), incorporated by reference

in Section 219.112 of this Part.

b)  A person planning to conduct a VON emissions test to

demonstrate compliance with this Subpart shall notify

the Agency of that intent not less than 30 days before

the planned initiation of the tests so the Agency may

observe the test.

(Source: Renumbered from Section 219.886 and amended at 

____

Ill. Reg. 

_____

,  effective 

______________________)

Section 219.875  

Applicability of Subpart BB (Renumbered)

(Source: Renumbered to Section 219.640 at 

____

Ill. Reg. 

____

effective

Emissions Limitation at Polystyrene Plants

(Renumbered)

(Source: Renumbered to Section 219.642 at

effective 

______________)

____

Ill. Reg.

Section 219.879  

Compliance Date (Repealed)

Every owner and operator of an omission source subject to 3~Ill.

trim 

Code 215, Subpart

RR.

r~fUcoember ~1-   1~R7- 

nhall

h~iv~

(Source: Repealed at 

—

Ill. Reg.    

,  effective

_________________________)

Section 219.881  

Compliance Plan (Repealed)

with 35 Ill. Adm. Code

project completion schcdul

~)-

Unless the submitted compliance plan or schedule was

disapproved by the Agency, the owner or operator of a

facility or         

subject to-~

~(ILL

~ubpart 

m~y

i~..ue

~iui~iun ~ouroe ~.iooord1ngto the plan und

schedule as submitted.

•

~1I11~4~J(JL1

~(JULL~t~

e-)-   The pl~..

..-~-

le shall 

the

~f 35

Ill. Adm. Code 201, Subpart H and Section 219.883.

(Source: Repealed at —  Ill. Reg.    

,  effective

Section 219.883

For sources

plan shall include:

Special Requirements for Compliance Plan

jRepealed)

A description of each process which is subjeot to an

emissions limitation;

Quantification of the omissions from each process~

A description of the procedures and methods used to

determine the emissions of VON;

A description of the methods which will be used to

demonstrate compliance with the allowable plantwido

Section 219.877

540

—J

a-)-

ee~

i-ti-t

subje:t

Cubpar-

201,

...

..ance

The owner or operator of an emission source formerly

rr~

rnC requirements of

35-

Ill. Adm.

t’r~d~-21c

shall have 

plan i~

including

.Jccorciancc

~..~ttea to the Aaenc”

6+

subject to this Subpart, an approvable

541

(Election ?1~.o77), including

rooordkcrninri and emission

~icasurcment.

(Source: Repealed at —  Ill. Reg.    

,  effective 

____

Section 218.886  

Emissions Testing (Renumbered)

(Source: Renumbered to Section 218.644 at 

____

Ill. Reg.

effective 

______________________________)

SUBPART PP: MISCELLANEOUS FABRICATED PRODUCT

MANUFACTURING PROCESSES

Section 219.920  

Applicability

a)  The requirements of this Subpart shall apply to a

plant’ssource’ s miscellaneous fabricated product

manufacturing process emission couroesunits which are

not included within any of the source categories

specified in Subparts B, E, F, H, 

R, S, ~ V, X, Y~

e~Z or BB if the plantsource is subject to this

Subpart. A plantsource is subject to this Subpart if

it contains process emission sources units, not

regulated by Subparts B, E, F (excluding Section

219.204(1) of this Part), H (excluding Section 219.405

of this Part), Q, R, S, T. (excluding Section 219.486

of this Part), V, X, Y~e~Z or BB of this Part; which

as a group both:

1)  ~llavemaximum theoretical emissions of 91 Mg (100

tons) or more per calendar year of VOM if no air

pollution control equipment were used, and

2)  eAre not limited to less than 91 Mg (100 tons) of

VON emissions per calendar year in the absence of

air pollution control equipment, through

production or capacity limitations contained in a

federally enforceable construction permit or a SIP

revision.

b)  If a plantsource ceases to fulfill the criteria of

subsection (a) above, the requirements of this Subpart

shall continue to apply to a miscellaneous fabricated

products manufacturing process emission sourceunit

which was ever subject to the control requirements of

Section 219.926 of this Part.

c)  No limits under this Subpart shall apply to emission

sourcesunits with emissions of VON to the atmosphere

less than or equal to 0.91 Mg (1.0 ton) per calendar

542

year if the total emissions from such o-ources emission

units not complying with Section 219.926 of this Part

does not exceed 4.5/Mg (5.0 tons) per calendar year.

d)  For the purposes of this Subpart, an emission

oourceunit shall be considered regulated by a Subpart

if it is subject to the limits of that Subpart. An

emission sourceunit is not considered regulated by a

Subpart if it is not sublect to the limits of that

Subpart, e.g.. the emission unit is covered by an

exemption in the Subpart or the applicability criteria

of the Subpart are not met. its emissions are below

the applicability cutoff level or if the source is

covered by an cxrntrntion.

e)  For the purposes of this Subpart, uncontrolled VON

emissions are the emissions of VOM which would result

if no air pollution control equipment were used.

~j The control reguirments in Subpart PP shall not apply

to sewage treatment plants; vegetable oil extraction

and processing; coke ovens (including by—product

recovery plants~i; fuel combustion units: bakeries;

barge loading facilities; let engine test cells;

production of polystyrene foam insulation board

including storage and extrusion of scrap where blowin~

agent is added to the polystyrene resin at the source,

but not including blending and preliminary expansion of

resin prior to molding where blowing agent is

incorporated into the polystyrene resin by the producer

of the resin; production of polystyrene foam packaging

not including blending and preliminary expansion of

resin prior to molding where blowing agent is

incorporated into the polystyrene resin by the producer

of the resin and not including storage and extrusion of

scrap where blowing agent is added to the polystyrene

resin at the source; and iron and steel production.

(Source: Amended at 

—

Ill. Reg.    

,  effective 

____________

Section 219.923  

Permit Conditions

No person shall violate any condition in a permit when the

condition results in exclusion of the plantsource or an emission

oourccunit from this Subpart~

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

____________

_________________________)

Section 219.926  

Control Requirements

543

Every owner or operator of an omission sourcoiniscellaneous

fabricated product manufacturing process emission unit subject to

this Subpart shall comply with the requirements of subsection

(a), (b) or (c) of this Section:

a)  Emission capture and control techniques which achieve

an overall reduction in uncontrolled VON emissions of

at least 81 percent from each emission unit, or

(Board Note: For the ~ur~ose of this provision, an

emission unit is any part or activity at a source of a

type

that by itself 

is sublect to control requirements

in other Subparts of this Part or 40 CFR 60,

incorporated by reference in Section 219.112, e.g., a

coating line, a printing line, a process unit, a

wastewater system, or other equipment. or is otherwise

any cart or activity at a source.)

b)  For coating lines, the daily—weighted average VOM

content shall not exceed 0.42 kg VOMf1 (3.5 lbs

VOM/gal) of coating as applied (minus water and any

compounds which are specifically exempted from the

definition of VON) during any day. Owners and

operators complying with this Section are not required

to comply with Section 219.301 of this Part, or

c)  An alternative control plan which has been approved by

the Agency and approved by the USEPA in a federally

enforceable permit or as a SIP revision.

(Source: Amended at —  Ill. Reg. 

______,

effective 

____________

Section 219.927  

Compliance Schedule

Every owner or operator of an emission sourceunit subject to the

control requirements of this Subpart shall comply with the

requirements thereof on and after a date consistent with Section

219.106 of this Part.

(Source: Amended at  

Ill. Reg. 

______,

effective 

____________

Section 219.928  

Testing

a)  When in the opinion of the Agency it is necessary to

conduct testing to demonstrate compliance with Section

219.926 of this Part, the owner or operator of a VON

emission sourceunit subject to the requirements of this

Subpart shall, at his own expense, conduct such tests

in accordance with the applicable test methods and

procedures specified in Section 219.105 of this Part.

544

b)  Nothing in this Section shall limit the authority of

the USEPA pursuant to the Clean Air Act, as amended, to

require testing.

(Source: Amended at  

Ill. Reg.    

, effective 

____________

_________________________)

SUBPART QQ: MISCELLANEOUS FORMULATION MANUFACTURING PROCESSES

Section 219.940  Applicability

a)  The requirements of this Subpart shall apply to a

plant’ asource 

‘

s miscellaneous formulation manufacturing

process emission sourccsunits, which are not included

within any of the source categories specified in

Subparts B, E, F, H, Q, R, S, ~ V, X, Y.L e~ Z or BB of

this Part if the plantsource is subject to this

Subpart. A plantsource is subject to this Subpart if

it contains process emission sourccsunits, not

regulated by Subparts B, E, F (excluding Section

219.204(1) of this Part), H (excluding Section 219.405

of this Part), Q, ‘R, 5, T (excluding Section 219.486 of

this Part). V, X, Y~e~Z or BB of this Part; which as

a group both:

hflave maximum theoretical

emissions of 91 Mg (100

tons) or more per calendar year of VON if no air

pollution control equipment were used, and

2)  eAre not limited to less than 91 Mg (100 tons) of

VOM emissions per calendar year in the absence of

air pollution control equipment, through

production or capacity limitations contained in a

federally enforceable construction permit or a SIP

revision.

b)  If a plantsource ceases to fulfill the criteria of

subsection (a) of this Section, the requirements of

this Subpart shall continue to apply to a miscellaneous

formulation manufacturing process emission source unit

which was ever subject to the control requirements of

Section 219.946 of this Part.

C)   No limits under this Subpart shall apply to emission

sourceaunits with emissions of VON to the atmosphere

less than or equal to 2.3 Mg (2.5 tons) per calendar

year if the total emissions from such sources emission

units not complying with this Section does not exceed

4.5 Mg (5.0 tons) per calendar year.

d)  For the purposes of this Subpart, an emission

sourceunit shall be considered regulated by a Subpart

545

if it is subject to the limits of that Subpart. An

emission sourccunit is not considered regulated by a

Subpart if it is not sublect to the limits of that

Subpart, e.g., the emission unit is covered by an

exemption in the Subpart or the applicability criteria

of the Subpart are not met. its emissions arc below the

applicability

cutoff level or if the source is covered

by an exemption.

e)  For the purposes of this Subpart, uncontrolled VON

emissions are the emissions of

VON which would result

if no air pollution control equipment were used.

~j The control reauirements in Subpart 00 shall not a~~lv

to sewage treatment plants; vegetable oil extraction

and processing; coke ovens (including by—product

recovery plants); fuel combustion units; bakeries;

barge loading facilities; let engine test cells;

production of polystyrene foam insulation board

including storage and extrusion of scrap where blowing

agent is added to the polystyrene resin at the source,

but not including blending and preliminary expansion of

resin prior to molding where blowing agent is

incorporated into the polystyrene resin by the producer

of the resin; production of polystyrene foam packaging

not including blending and preliminary expansion of

resin prior to molding where blowing agent is

incorporated into the polystyrene resin by the producer

of the resin and not including storage and extrusion of

scrap where blowing agent is added to the polystyrene

resin at the source; and iron and steel production.

(Source: Amended at  

Ill. Reg. 

______

,  effective 

____________

Section 219.943  

Permit Conditions

No person shall violate any condition in a permit when the

condition results in exclusion of the plantsource or an emission

sourceunit from this Subpart.

(Source: Amended at —  Ill. Reg. 

______,

effective 

____________

Section 219.946  

Control Requirements

Every owner or operator of an emission souroca miscellaneous

formulation manufacturing process emission unit subject to this

Subpart shall comply with the requirements of subsection (a) or

(b) below.

546

a)  Emission capture and control techniques which achieve

an overall reduction in uncontrolled VON emissions of

at least 81 percent from each emission unit, or

(Board Note: For the purpose of this provision, an

emission unit is any part or activity at a source of a

type 

that by itself is sub-lect to control

requirements

in other Subparts of this Part or 40 CFR 60,.

incorporated by reference in Section 219.112. e.g.~, a

coating line, a printing line, a process unit, a

wastewater system, or other equipment, or is otherwise

any part or activity at a source.)

b)  An alternative control plan which has been approved by

the Agency and approved—by the USEPA in a federally

enforceable permit or as a SIP revision.

(Source: Amended at  

Ill. Reg. 

______,

effective 

____________

_________________________)

Section 219.947  

Compliance Schedule

Every owner or operator of an emission courc-eunit subject to the

control requirements of this Subpart shall comply with the

requirements thereof on and after a date consistent with Section

219.106 of this Part.

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

____________

Section 219.948  

Testing

a)  When in the opinion of the Agency it is necessary to

conduct testing to demonstrate compliance with Section

219.946 of this Part, the owner or operator of a VOM

emission oourceunit subject to the requirements of this

Subpart shall, at his own expense, conduct such tests

in accordance with the applicable test methods and

procedures specified in Section 219.105 of this Part.

b)  Nothing in this Section shall limit the authority of

the USEPA pursuant to the Clean Air Act, as amended, to

require testing.

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

____________

_________________________ )

547

SUBPART RR: MISCELLANEOUS ORGANIC CHEMICAL

MANUFACTURING PROCESSES

Section 219.960  

Applicability

a)  The requirements of this Subpart shall apply to a

plant’osource’s miscellaneous organic chemical

manufacturing process emission souroccunits which are

not included within any of the source categories

specified in Subparts B, E, F, H, 

Q, R, 5, ~ V, X, Y~

e~Z or BB of this Part, if the plantsource is subject

to this Subpart. A plantsource is subject to this

Subpart if it contains process emission oourccsunits,

not regulated by Subparts B, E, F (excluding Section

219.204(1) of this Part), H (excluding Section 219.405

of this Part), Q, R, S, ~ ~excludincrSection 219.486 of

this Part) V, X, Y~e~Z or BB of this Part; which as a

group both:

1)  1~jave maximum theoretical emissions of 91 Mg (100

tons) or more per calendar year of VON if no air

pollution control equipment were used, and

2)  eAre not limited to less than 91 Mg (100 tons) of

VOM emissions per calendar year in the absence of

air pollution control equipment, through

production or capacity limitations contained in a

federally enforceable construction permit or a SIP

revision.

b)  If a plantsource ceases to fulfill the criteria of

Subsection (a) of this Section, the requirements of

this Subpart shall continue to apply to a miscellaneous

organic chemical manufacturing process emission source

unit which was ever subject to the control requirements

of Section 219.966 of this Part.

c)  No limits under this Subpart shall apply to emission

oourccsunits with emissions of VON to the atmosphere

less than or equal to 0.91 Mg (1.0 ton) per calendar

year if the total emissions from such oourccs emission

units not complying with Section 219.966 of this Part

does not exceed 4.5 Mg (5.0 tons) per calendar year~.

d)  For the purposes of this Subpart, an emission source

unit shall be considered regulated by a Subpart if it

is subject to the limits of that Subpart.

An emission

oourccunit is not considered regulated by a Subpart if

it is not sublect to the limits of that Subpart. e.g.,

the emission unit is covered by an exemption in the

Subpart or the a~plicabilitvcriteria of the Subpart

are not met. its emissions are below the applicability

548

cutoff level or

...~c

exemption.

e)  For the purposes of this Subpart, uncontrolled VON

emissions are the emissions of VON which would result

if no air pollution control equipment were used.

The control requirements in Subpart RR shall not a~~iv

to sewage treatment plants; vegetable gil extraction

and_processing; coke ovens (including by—product

recovery plants): fuel combustion units; bakeries;

barge loading facilities; jet engine test cells;

production of polystyrene foam insulation board

including storage and extrusion of scrap where blowing

agent is added to the polystyrene resin at the source~

but not including blending and preliminary expansion of

resin prior to molding where blowing agent is

incorporated into the polystyrene resin by the producer

of the resin; production of polystyrene foam packaging

not including blending and preliminary expansion of

resin prior to molding where blowing agent is

incorporated into the polystyrene resin by the producer

of the resin and not including storage and extrusion of

scrap where blowing agent is added to the polystyrene

resin at the source; and iron and steel production.

(Source: Amended at 

—

Ill. Reg.    

,  effective 

____________

Section 219.963  

Permit Conditions

No person shall violate any condition in a permit when the

condition results in exclusion of the plantsource or an emission

eourceunit from this Subpart.

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

___________

Section 219.966  

Control Requirements

Every owner or operator of an emission sourcemiscellaneous

organic chemical manufacturing process emission unit, subject to

this Subpart shall comply with the requirements of subsection

(a)~

(b)~or (c) below.

a)  Emission capture and control techniques which achieve

an overall reduction in uncontrolled VON emissions of

at least 81 percent from each emission unit, or

(

Board Note: For the purpose of this provision, an

emission unit is any part or activity at a source of a

type that by itself is subiect to control requirements

549

in other Subparts of this Part or 40 CFR 60.

incorporated by reference in Section 219.112, e.g.~

coating line, a printing line, a process unit. a

wastewater system, or other eauipment. or is otherwise

any part or activity at 

source.)

b)  An alternative control plan which has been approved by

the Agency and approved by the USEPA in a federally

enforceable permit or as a SIP revision.

gj AnY leaks from components sublect to the control

requirements of this Subpart shall be subject to the

following control measures:

~j Repair any component from which a leak of VOL can

be observed. The repair shall be completed as soon

as practicable but no later than 15 days after the

leak is found, unless the leaking component cannot

be repaired until the next process unit shutdown,

in which case the leaking component must be

repaired before the unit is restarted.

21

For any leak which cannot be readily repaired

within one hour after detection, the following

records, as set forth in this subsection, shall be

kept. These records shall be maintained by the

owner or operator for a minimum of two years after

the date on which they are made. Copies of the

records shall be made available to the Agency or

USEPA upon verbal or written request.

~j The name and identification of the leaking

component

~  The date and time the leak is detected

~  The action taken to repair the leak; and

Qj The date and time the leak is repaired.

(Source: Amended at  

1.11. Reg. 

______,

effective 

____________

_________________________ )

Section 219.967  

Compliance Schedule

Every owner or operator of an emission oourccunit subject to the

control requirements of this Subpart shall comply with the

requirements of this Subpart on and after a date consistent with

Section 219.106 of this Part.

(Source: Amended at —  Ill. Reg.    

,  effective 

____________

550

Section 219.968  

Testing

When in the opinion of the Agency it is necessary to

conduct testing to demonstrate compliance with Section

219.966 of this Part, the owner or operator of a VON

emission courceunit subject to the requirements of this

Subpart shall, at his own expense, conduct such tests

in accordance with the applicable test methods and

procedures specified in Section 219.105 of this Part.

b)  Nothing in this Section shall limit the authority of

the USEPA pursuant to the Clean Air Act, as amended, to

require testing.

(Source: Amended at  

Ill. Reg. 

______,

effective 

____________

_________________________)

SUBPART TT: OTHER EMISSION COURCEC UNITS

Section 219.980  

Applicability

a)  The requirements of this Subpart shall apply to a

plant’ssource’s VON emission sourcesunits, which are

not included within any of the source categories

specified in Subparts B, E, F, H, Q, R, S, ~ V, X, Y,

Z, AA, ~ PP, QQ, or RR of this Part, or are not

exempted from permitting requirements pursuant to 35

Ill. Adm. Code 201.146, if the plantsource is subject

to this Subpart. A plantsource is subject to this

Subpart if it contains process emission souroesunits,

not regulated by Subparts B, E, F (excluding Section

219.204(1) of this Part), H (excluding Section 219.405

of this Part), Q, R, 5, T. (excluding Section 218.486

of this Part), V, X, Y e~ Z or BB of this Part, which

as a group both:

1)  ~jave maximum theoretical emissions of 91 Mg (100

tons) or more per calendar year of VON if no air

pollution control equipment were used, and

a~re not limited to less than 91 Mg (100 tons) of

VON emissions per calendar year in the absence of

air pollution control equipment, through

production or capacity limitations contained in a

federally enforceable ?onstruotian or operating

permit or a SIP revision.

b)  If a plantsource ceases to fulfill the criteria of

subsection (a) of this Section, the requirements of

this Subpart shall continue to apply to an emission

sourceunit which was ever subject to the control

requirements of Section 219.986 of this Part.

551

~c) No limits under this Subpart shall apply to emission

oourccsunits with emissions of VON to the atmosphere

less than or equal to 2.3 Mg (2.5 tons) per calendar

year if the total emissions from such sources emission

unit not complying with Section 219.986 of this Part

does not exceed 4.5 Mg (5.0 tons) per calendar year.

d)  For the purposes of this Subpart, an emission souree

unit shall be considered regulated by a Subpart if it

is subject to the limits of that Subpart. An emission

sourceunit is not considered regulated by a Subpart if

it is not sublect to the limits of that Subpart1 e.a.,

the emission unit is covered by an exemption in the

Subpart or the applicability criteria of the Subpart

are not met. its omissions are below the applicability

cutoff level or if the -source is covered by an

exemption.

The control requirements in Subparts QQ, RR, CC and TT

shall not apply to sewage treatment p1ants7~vegetable

oil extraction and processing planto,i. coke ovens

(including by-product recovery p1ants)-~-~fuel

combustion sourocs,units; bakeriesTj.. barge loading

facilitiesT~jet engine test cells~j.pharmaceutical

manufacturing production of polystyrene foam insulation

board -(-including storage and extrusion of scrapj where

blowing agent is added to the polystyrene resin at the

plantsource~~but not including blending and

preliminary expansion of resin prior to molding where a

blowing agent is incorporated into the polystyrene

resin by the producer of the resin~-~production of

polystyrene foam packaging -(-not including blending and

preliminary expansion of resin prior to molding where

blowing agent is incorporated into the polystyrene

resin by the producer of the resin; and not including

storage and extrusion of scrap where blowing agent is

added to the polystyrene resin at the plantsource)-~-~

and iron and steel production.

(Source: Amended at —  Ill. Reg. 

______,

effective 

____________

Section 219.983  

Permit Conditions

No person shall violate any condition in a permit when the

condition results in exclusion of the plantsource or an emission

sourceunit from this Subpart.

(Source: Amended at —  Ill. Reg. 

______,

effective 

____________

552

Section 219.986  

Control Requirements

Every owner or operator of an emission courceunit subject to this

Subpart shall comply with the requirements of subsection (a),

(b)~e~ (c),

(d) or (e) below.

a)  Emission capture and control equipment which achieve an

overall reduction in uncontrolled VON emissions of at

least 81 percent from each emission unit, or

f~oardNote: For the purpose of this provision, an

emission unit is any part or activity at a source of a

type that by itself is subiect to control requirements

in other Subparts of this Part or 40 CFR 60,

incorporated by reference in Section 219.112. e.g., a

coating line, a printing line, a process unit, a

wastewater system, or other equipment, or is otherwise

any part or activity at a source.)

b)  For coating lines, the daily-weighted average VON

content shall not exceed 0.42 kg VOM/l (3.5 lbs

VON/gal) of coating (minus water and any compounds

which are specifically exempted from the definition of

VON) as applied during any day. Owners and operators

complying with this Section are not required to comply

with Section 219.301 of this Part, or

c)  An alternative control plan which has been approved by

the Agency and approved by the USEPA in a federally

enforceable permit or as a SIP revision.

~j. Non-contact process water cooling towers which are

sub-ject to the control requirements of this Subpart

shall comply with the following control measures no

later than March 15, 1995 or upon initial startup:

~j The owner or operator of a non—contact process

water cooling tower shall perform the following

actions to control emissions of volatile organic

material (VON) from such a tower:

~j Inspect and monitor such tower to identify

leaks of VON into the water, as further

specified in subsection (d) (3) below

~j When a leak is identified, initiate and carry

out steps to identify the specific leaking

component or components as soon as

practicable, as further specified in

subsection (d) (4) below.

~j When a leaking component is identified which:

553

~jj Can be removed from service without

disrupting production, remove the

component from service:

jjj~. Cannot be removed from service without

disrupting production. undertake repair

of the component at the next reasonable

o~portunitvto do so including any

period when the component is out of

service for scheduled maintenance, as

further specified in subsection (d) (4)

below

Qj Maintain records of inspection and monitoring

activities, identification of leaks and

leaking components, elimination and repair of

leaks, and operation of equipment as related

to these activities, as further specified in

subsection (d) (5) below.

21

A VON leak shall be considered to exist in a non—

contact process water cooling water sYstem if the

VON emissions or VON content exceed background

levels as determined bY monitoring conducted in

accordance with subsection (d) (3) (A) below.

The owner or operator of an non—contact process

water cooling tower shall carry out an inspection

and monitoring program to identify VON leaks in

the cooling water system.

~  The owner or oPerator of a non-contact

process water cooling tower shall submit to

the A~encva ~ro~osed monitoring program,

accompanied by technical -justification for

the program. including justification for the

sampling location(s), parameter(s) selected

for measurement, monitoring and inspection

frepuency. and the criteria used relative to

the monitored parameters to determine whether

a leak exists as specified in subsection

(d)(2) above.

~j This inspection and monitoring Pro~ram for

non—contact process water cooling towers

shall include, but shall not be limited to:

Monitoring of each such tower with a

water flow rate of 25,000 ~al1ons per

minute or more at a petroleum refinery

at least weekly and monitoring of other

towers at least monthly

554

Inspection of each such tower at lea~~

weekly if monitoring is not performedat

least weekly.

Q)..   This inspection and monitoring proaram shall

be carried out in accordance with written

procedures which the Agency shall specify as

a condition in

a federally enforceable

operating permit. These procedures shall

include the VON background levels for the

cooling tower as established by the owner or

operator throuah monitoring: describe the

locations at which samples will be taken;

identify the parameter(s) to be measured, the

frequency of measurements, and the procedures

for monitoring each such tower, that is,

taking of samples and other subsequent

handling and analyzing of samples; provide

the criteria used to determine that a leak

exists as specified in subsection (d) (2)

above; and describe the records which will be

maintained.

Qj A non—contact process water cooling tower is

exempt from the requirements of subsections

(d) (3) (B) and (d) (3) (C) above, if all

equipment, where leaks of VON into cooling

water may occur, is operated at a minimum

pressure in the cooling water of at least 35

kPa greater than the maximum pressure in the

p~ocess fluid.

j).  The repair of a leak in a non—contact process

water cooling tower shall be considered to be

completed in an acceptable manner as follows:

~j Efforts to identify and locate the leaking

components are initiated as soon as

practicable, but in no event later than three

days after detection of the leak in the

cooling water tower

~  Leaking components shall be repaired or

removed from service as soon as possible but

no later than 30 days after the leak in the

cooling water tower is detected, unless the

leaking components cannot be repaired until

the next scheduled shutdown for maintenance.

~j The owner or operator of a non—contact process

water cooling tower shall keep records as set

forth below in this subsection. These records

555

shall be retained at a readily accessible location

at the source and shall be available for

inspection and copying by the A~encvfor at least

3 years:

~j. Records of inspection and monitoring

activity

.~j Records of each leak identified in such

tower. with date, time and nature of

observation or measured level of parameter:

~j Records of activity to identify leaking

components. with date initiated, summary of

components inspected with dates.. and method

of inspection and observations

Records of activity to remove a leaking

component from service or repair a leaking

component, with date initiated and completed.

description of actions taken and the basis

for determining the leak in such tower has

been eliminated. If the leaking component is

not identified, repaired or eliminated within

30 days of initial identification of a leak

in such tower, this report shall include

specific reasons why the leak could not be

eliminated sooner including all other

intervening periods when the process unit was

out of service, actions taken to minimize VON

losses prior to elimination of the leak and

any actions taken to prevent the recurrence

of a leak of this type.

.~j..  The owner or operator of a non-contact process

water cooling tower shall submit an annual report

to the Agency which provides:

~j The number of leaks identified in each

cooling tower

~j A general description of activity to repair

or eliminate leaks which were identified

Qj Identification of each leak which was not

repaired in 30 daYs from the date of

identification of a leak in such a tower,

with description of the leaks, explanation

why the leak was not repaired in 30 days

556

Qj

Identification of any periods when requirQ~

inspection and monitoring activities were not

carried out.

~j Any leaks from components subject to the control

requirements of this Subpart shall be subject to th~

following control measures by March 15, 1995:

Repair any component from which a leak of VOL can

be observed. The repair shall be completed as soon

as practicable but no later than 15 days after the

leak is found, unless the leaking component cannot

be repaired until the next process unit shutdown,

in which case the leaking component must be

repaired before the unit is restarted.

21

For any leak which cannot be readily repaired

within one hour after detection, the following

records, as set forth below in this subsection,

shall be kept. These records shall be maintained

by the owner or operator for a minimum of two

years after the date on which they are made.

Copies of the records shall be made available to

the Agency or USEPA upon verbal or written

request.

The name and identification of the leaking

component

~  The date and time the leak is detected

~j The action taken to repair the leak; and

Qj The date and time the leak is repaired.

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

____________

Section 219.987  

Compliance Schedule

Every owner or operator of an emissions sourceunit which is

subject to this Subpart shall comply with the requirements of

this Subpart on and after a date consistent with Section 219.106

of this Part.

(Source: Amended at  

Ill. Reg.    

, effective 

____________

Section 219.988  

Testing

a)  When in the opinion of the Agency it is necessary to

conduct testing to demonstrate compliance with Section

557

219.986 of this Part, the owner or operator of a VON

emission sourccunit subject to the requirements of this

Subpart shall, at his own expense, conduct such tests

in accordance with the applicable test methods and

procedures specified in Section 219.105.

b)  Nothing in this Section shall limit the authority of

the USEPA pursuant to the Clean Air Act, as amended, to

require testing.

(Source: Amended at 

—

Ill. Reg.    

,  effective 

____________

SUBPART UU: RECORDKEEPING AND REPORTING FOR NON--CTC COURCEC

Section 219.990  

Exempt Emission CourcesUnits

Upon request by the Agency, the owner or operator of an emission

unit source which is exempt from the requirements of Subparts PP,

QQ, RR, TT or Section 219.208(b) of this Part shall submit

records to the Agency within 30 calendar days from the date of

the request that document that the emission unit source is exempt

from those requirements.

(Source: Amended at —  Ill. Reg. 

______,

effective 

____________

Section 219.991  

Subject Emission SourcccUnits

a)  Any owner or operator of a VOM emission sourccunit

which is subject to the requirements of Subpart PP, QQ,

R.R or TT and complying by the use of emission capture

and control equipment shall comply with the following:

1)  By a date consistent with Section 219.106 of this

Part, or upon initial start—up of a new emission

sourceunit, the owner or operator of the subject

VON emission sourceunit shall demonstrate to the

Agency ~4iethat the subject emission souracunit

will be in compliance on and after a date

consistent with Section 219.106 of this Part, or

on and after the initial start-up date by

submitting to the Agency all calculations and

other supporting data, including descriptions and

results of any tests the owner or operator may

have performed.

2)  On and after a date consistent with Section

219.106 of this Part, or on and after the initial

start-up date, the owner or operator of a subject

VON emission source shall collect and record all

of the following information each day and maintain

558

the information at the -f-acili~ysource for a period

of three years:

A)  Control device monitoring data.

A log of operating time for the capture

system, control device, monitoring equipment

and the associated emission source.

C)  A maintenance log for the capture system,

control device and monitoring equipment

detailing all routine and non-routine

maintenance performed including dates and

duration of any outages.

3)  On and after a date consistent with Section

219.106 of this Part, the owner or operator of a

subject VON emission source shall notify the

Agency in the following instances:

A)  Any record showing a violation of the

requirements of Subpart PP, QQ, RR or TT

shall be reported by sending a copy of such

record to the Agency within 30 days following

the occurrence of the violation.

B)  At least 30 calendar days before changing the

method of compliance with Subpart PP or TT

from the use of capture systems and control

devices to the use of complying coatings, the

owner or operator shall comply with all

requirements of subsection (b) (1) of this

Section. Upon changing the method of

compliance with Subpart PP or TT from the use

of capture systems and control devices to the

use of complying coatings, the owner or

operator shall comply with all requirements

of subsection (b) of this Section.

4)  Testing

A)  When in the opinion of the Agency it is

necessary to conduct testing to demonstrate

compliance with this Subpart, the owner or

operator of a VON emission source subject to

the requirements of this Subpart shall, at

his own expense, conduct such tests in

accordance with the applicable test methods

and procedures specified in Section 219.105

of this Part.

559

B)  Nothing in this Section shall limit the

authority of the USEPA pursuant to the Clean

Air Act, as amended, to require testing.

b)  Any owner or operator of a coating line which is

subject to the requirements of Subpart PP or TT and

complying by means of the daily-weighted average VON

content limitation shall comply with the following:

1)  By a date consistent with Section 219.106 of this

Part, or upon initial start-up of a coating line

subject to Subpart PP or TT, the owner or operator

of the subject coating line shall certify to the

Agency that the coating line will be in compliance

on and after a date consistent with Section

219.106 of this Part, or on and after the initial

start-up date. Such certification shall include:

A)  The name and identification number of each

coating line which will comply by means of

the daily-weighted average VON content

limitation.

B)  The name and identification number of each

coating as applied on each coating line.

C)  The weight of VON per volume and the volume

of each coating (minus water and any

compounds which are specifically exempted

from the definition of VON) as applied each

day on each coating line.

D)  The instrument or method by which the owner

or operator will accurately measure or

calculate the volume of each coating as

applied each day on each coating line.

E)  The method by which the owner or operator

will create and maintain records each day as

required in subsection (b) (2).

F)  An example of the format in which the records

required in subsection (b) (2) of this Section

will be kept.

2)  On and after a date consistent with Section

219.106 of this Part, or on and after the initial

start—up date, the owner or operator of a subject

coating line shall collect and record all of the

following information each day for each coating

line and maintain the information at the

facilitysource for a period of three years:

560

The name and identification

number of each

coating as applied on each coating line.

B)  The weight of VON per volume and the volume

of each coating (minus water and any

compounds which are specifically exempted

from the definition of VOM) as applied each

day on each coating line.

C)  The daily-weighted average VON content of all

coatings as applied on each coating line as

defined

in Section 219.104 of this Part.

3)  On and after a date consistent with Section

219.106 of this Part, the owner or operator of a

subject coating line shall notify the Agency in

the following instances:

A)  Any record showing violation of the

requirements of Subpart PP or TT shall be

reported by sending a copy of such record to

the Agency within 30 days following the

occurrence of the violation.

B)  At least 30 calendar days before changing the

method of compliance with Subpart PP or TT

from the use of complying coatings to the use

capture systems and control devices, the

owner or operator shall comply with all

requirements of subsection (a) (1) of this

Section. Upon changing the method of

compliance with Subpart PP or TT from the use

of complying coatings to the use capture

systems and control devices, the owner or

operator shall comply with all requirements

of subsection (a) of this Section.

c)  Any owner or operator of a VON emission source which is

subject to the requirements of Subpart PP, QQ, RR or TT

and complying by means of an alternative control plan

which has been approved by the Agency and approved by

the USEPA as a SIP revision shall comply with the

recordkeeping and reporting requirements specified in

the alternative control plan.

(Source: Amended at  

Ill. Reg. 

______,

effective 

____________

561

Section 219.Appendix A

List of Chemicals Defining Synthetic Organic Chemical and

Polymer Manufacturing

CAS No.         

Chemical

105—57—7        

Acetal

75-07-0        

Acetaldehyde

107-89-1        

Acetaldol

60-35-5        

Acetamide

103—84-4        

Acetanilide

64-19-7        

Acetic acid

108-24-7

Acetic anhydride

67-64-1        

Acetone

75-86-5        

Acetone cyanohydrin

75-05-8        

Acetonitrile

98-86-2        

Acetophenone

75-36-5        

Acetyl chloride

74-86-2        

Acetylene

107—02—8        

Acrolein

79-06-1        

Acrylamide

79-10-7        

Acrylic acid & esters

107-13-1        

Acrylonitrile

124-04-9        

Adipic acid

111—69-3       

Adiponitrile

Alkyl naphthalenes

107—18—6        

Allyl alcohol

107—05-1       

Allyl chloride

1321—11—5       

Aminobenzoic acid

111-41-1       

Aminoethylethanolamine

123-30—8        

p—aminophenol

628-63-7,        

Amyl acetates

123—92—2

71-4l-0        

Amyl alcohols

110-58-7       

Amyl amine

543-59-9       

Amyl chloride

110_68_7c        

Amyl inercaptans

1322-06-1       

Amyl phenol

62—53—3        

Aniline

142-04-1        

Aniline hydrochloride

29191—52—4       

Anisidine

100—66—3        

Anisole

118-92-3        

Anthranilic acid

84-65-1        

Anthraquinone

100-52-7        

Benzaldehyde

55-21—0        

Benzamide

71—43—2        

Benzene

98-48-6        

Benzenedisulfonic acid

98-11-3         

Benzenesulfonic acid

134—81—6       

Benzil

76-93-7        

Benzilic acid

562

65—85—0        

Benzoic acid

119—53—9       

Benzoin

100-47-0       

Benzonitrile

119—61-9        

Benzophenone

98-07-7        

Benzotrichloride

98-88-4        

Benzoyl chloride

100-51-6       

Benzyl alcohol

100-46-9

Benzylamine

120-51-4        

Benzyl benzoate

100-44-7        

Benzyl chloride

98-87-3        

Benzyl dichloride

92—52—4        

Biphenyl

80—05-7        

Bisphenol A

10-86-1

Bromobenzene

27497-51-4       

Bromonaphthalene

106-99—0       

Butadiene

106—98—9        

1—butene

123-86-4        

n-butyl acetate

141-32-2        

n-butyl acrylate

71-36-3        

n-butyl alcohol

78-92-2        

s—butyl alcohol

75-65-0        

t—butyl alcohol

109-73-9       

n-butylamine

13952—84—6       

s—butylamine

75-64-9        

t—butylamine

98-73-7        

p—tert—butyl benzoic acid

107—88—0        

1,3—butylene glycol

123-72-8       

n-butyraldehyde

107-92-6        

Butyric acid

106-31-0       

Butyric anhydride

109-74-0        

Butyronitrile

105-60-2        

Caprolactam

75-1-50        

Carbon disulfide

558-13-4        

Carbon tetrabromide

55-23-5        

Carbon tetrachioride

9004-35-7       

Cellulose acetate

79-11-8         

Chloroacetic acid

108-42-9        

m-chloroaniline

95-51-2         

o-chloroaniline

106—47-8        

p-chloroaniline

35913-09—8       

Chlorobenzaldehyde

108—90-7        

Chlorobenzene

118-91-2,       

Chlorobenzoic acid

535—80—8,

74_11_3c

2136-81-4,       

Chlorobenzotrichloride

2136—89—2,

5216_25_1c

1321—03—5       

Chlorobenzoyl chloride

75-45-6        

Chlorodifluoroethane

25497-29-4       

Chlorodifluoromethane

563

67-66-3        

Chloroform

25586-43-0       

Chloronaphthalene

88-73-3        

o-chloronjtrobenzene

100-00-5        

p-chloronitrobenzene

25167-80-0       

Chlorophenols

126-99-8        

Chloroprene

7790-94-5       

Chiorosulfonic acid

108-41-8        

m-chlorotoluene

95-49-8        

o-chlorotoluene

106-43-4        

p—chlorotoluene

75-72-9        

Chiorotrifluoromethane

108—39—4        

m—cresol

95—48—7        

o—cresol

106—44—5       

p—cresol

1319-77-3       

Mixed cresols

1319—77-3       

Cresylic acid

4170-30-0       

Crotonaldehyde

3724—65—0       

Crontonic acid

98-82-8        

Cumene

80-15-9         

Cumene hydroperoxide

372-09-8        

Cyanoacetic acid

506-77—4        

Cyanogen chloride

108-80-5        

Cyanuric acid

108-77-0        

Cyanuric chloride

110-82-7        

Cyclohexane

108—93—0       

Cyclohexanol

108-94-1        

Cyclohexanone

110—83-8        

Cyclohexene

108—91-8        

Cyclohexylamine

111—78-4        

Cyclooctadiene

112—30-1       

Decanol

123-42-2        

Diacetone alcohol

27576-04-1      

Diaminobenzoic acid

95-76-1,        

Dichloroaniline

95—82—9,

554—00—7,

608—27—5,

608—31—1,

626—43—7,

27134—27—6,

5731l_92_9c

541-73-1       

m—dichlorobenzene

95-50-1         

o-dichlorobenzene

106-46-7

p—dichlorobenzene

75-71-8         

Dichlorodifluoromethane

111-44-4        

Dichloroethyl ether

107-06-2        

l,2-dichloroethane (EDC)

96-23-1        

Dichlorohydrin

26952-23-8       

Dichloropropene

101-83-7        

Dicyclohexylamine

109-89-7        

Diethylamine

564

111-46-6       

Diethylene glycol

112-36-7       

Diethylene glycol diethyl

ether

111-96-6       

Diethylene glycol dimethyl

ether

112-34-5       

Diethylene glycol monobutyl

ether

124-17-7       

Diethylene glycoi. mononbutyl

ether acetate

111-90-0       

Diethylene glycol monoethyl

ether

112-15-2        

Diethylene glycol monoethyl

ether acetate

111-77-3

Diethylene glycol

monomethyl

ether

64-67—5        

Diethyl sulfate

75-37-6        

Difluoroethane

25167—70—8       

Diisobutylene

26761-40-0      

Diisodecyl phthalate

27554—26—3       

Diisooctyl phthalate

674—82—8       

Diketene

124-40-3        

Dimethylamine

121—69—7       

N,N—dimethylaniline

115-10-6       

N,N-dimethyl ether

68-12-2        

N,N-dimethylformamide

57-14-7        

Dimethylhydrazine

77—78—1

Diinethyl sulfate

75—18—3

Dimethyl sulfide

67—68-5

Dimethyl sulfoxide

120-61-6       

Dimethyl terephthalate

99-34—3        

3,5—dinitrobenzoic acid

51-28-5        

Dinitrophenol

Dinitrotolyene

123-91—1       

Dioxane

646—06—0

Dioxilane

122-39-4        

Diphenylamine

101-84-4

Diphenyl oxide

102-08-9        

Diphenyl thiourea

25265-71-8

Dipropylene glycol

25378-22-7       

Dodecene

28675—17—4       

Dodecylaniline

27193-86-8       

Dodecyiphenol

106-89-8        

Epichlorohydrin

64—17—5        

Ethanol

141_43_5c        

Ethanolamines

141-78-6       

Ethyl acetate

141-97-9        

Ethyl acetoacetate

140-88—5       

Ethyl acrylate

75—04-7         

Ethylaxnine

100-41-4        

Ethylbenzene

74-96-4         

Ethyl bromide

565

9004—57—3       

Ethylcellulose

75-00-3        

Ethyl chloride

105-39-5       

Ethyl chloroacetate

105-56-6

Ethylcyanoacetate

74-85-1        

Ethylene

96-49-1        

Ethylene carbonate

107-07-3        

Ethylene chlorohydrin

107-15-3        

Ethylenediamine

106-93-4        

Ethylene dibromide

107-21-1        

Ethylene glycol

111-55-7        

Ethylene glycol diacetate

110-71-4

Ethylene glycol dimethyl ether

111-76-2

Ethylene glycol monobutyl

ether

112-07-2

Ethylene glycol monobutyl

ether acetate

110-80-5

Ethylene glycol monoethyl

ether

111-15-9        

Ethylene glycol monoethyl

ether acetate

109-86-4

Ethylene glycol monoethyl

ether

110-49-6        

Ethylene glycol monomethyl

ether acetate

122-99-6

Ethylene glycol inonophenyl

ether

2807-30-9

Ethylene glycol monopropyl

ether

75-21-8        

Ethylene oxide

60-29-7        

Ethyl ether

104-76-7        

2—ethylhexanol

122-51-0        

Ethyl orthoformate

95-92-1        

Ethyl oxalate

41892-71-1       

Ethyl sodium oxaloacetate

50-00-0        

Formaldehyde

75-12—7        

Formamide

64-18-6

Formic acid

110-17-8        

Fumaric acid

98—01—1        

Furfural

56-81-5        

Glycerol (Synthetic)

26545-73-7       

Glycerol dichlorohydrin

25791-96-2       

Glycerol triether 

56—40—6        

Glycine

107—22—2        

Glyoxal

118-74-1        

Hexachlorobenzene

67-72-1        

Hexachloroethane

36653-82-4       

Hexadecyl alcohol

124-09-4        

Hexamethylenediamine

629—11-8

Hexamethylene glycol

100-97-0       

Hexamethylenetetramine

74-90-8        

Hydrogen cyanide

123-31-9        

Hydroquinone

566

99-96-7        

p-hydroxybenzoic acid

26760—64—5      

Isoamylene

78—83—1        

Isobutanol

110-19-0       

Isobutyl acetate

115-11-7        

Isobutylene

78-84-2        

Isobutyraldehyde

79-31—2        

Isobutyric acid

25339—17—7       

Isodecanol

26952—21—6       

Isooctyl alcohol

78-78-4        

Isopentane

78-59-1        

Isophorone

121-91-5       

Isophthalic acid

78-79-5        

Isoprene

67-63-0        

Isopropanol

108-21-4        

Isopropyl acetate

75-31-0        

Isopropylamine

75-29—6        

Isopropyl chloride

25168-06-3       

Isopropylphenol

463—51—4

Ketene

Linear alkyl sulfonate*

123—01-3

Linear alkylbenzene

110—16—7        

Maleic acid

108-31-6        

Maleic anhydride

6915—15—7       

Malic acid

141—79-7       

Mesityl oxide

121-47—1       

Metanilic acid

79—41—4        

Methacrylic acid

563—47—3       

Nethallyl chloride

67—56-1        

Methanol

79-20-9        

Methyl acetate

105-45—3        

Methyl acetoacetate

74-89-5        

Nethylamine

100—61—8        

n—xnethylaniline

74-83-9        

Methyl bromide

37365-71-2       

Methyl butynol

74-87-3         

Methyl chloride

108-87-2

Nethyl cyclohexane

1331-22-2

Methyl cyclohexanone

75-09-2        

Methylene chloride

101—77—9        

Nethylene dianiline

101-68-8       

Methylene diphenyl

diisocyanate

78-93-3        

Methyl ethyl ketone

1073l-3       

Methyl forrnate

108-11-2

Methyl isobutyl carbinol

108-10-1       

Methyl isobutyl ketone

80—62—6        

Methyl methacrylate

77758

Methylpentynol

98-83-9        

B-methylstyrene

110-91-8        

Norpholine

85-47-2        

a—naphthalene sulfonic acid

567

120-18-3

B-naphthalene sulfonic acid

90-15-3         

a—naphthol

135-19-3        

B-naphthol

75-98-9        

Neopentanoic acid

88-74-4        

o—nitroaniline

100—01—6        

p—nitroaniline

91-23-6        

o—nitroanisole

100-17-4        

p-nitroanisole

98-95-3        

Nitrobenzene

27178_83_2c       

Nitrobenzoic acid (0, m & p)

79-24-3        

Nitroethane

75-52-5        

Nitromethane

88-75-5        

Nitrophenol

25322-01-4       

Nitropropane

1321-12-6       

Nitrotoluene

27215—95—8       

Nonene

25154-52-3       

Nonylphenol

27193-28-8       

Octylphenol

123—63-7

Paraldehyde

115-77-5        

Pentaerythritol

109—66-0        

n—pentane

109—67-1        

1—pentene

127-18-4        

Perchloroethylene

594-42-3        

Perchioromethyl mercaptan

94-70-2        

o-phenetidine

156-43-4        

p—phenetidine

108—95—2

Phenol

98—67—9,        

Phenolsulfonic acids

585—38—6,

609—46—1,

133_39_7c

91-40-7        

Phenyl anthranilic acid

Phenylenediamine

75-44-5        

Phosgene

85-44-9        

Phthalic anhydride

85-41—6        

Phthaliinide

108—99—6        

b—picoline

110-85—0        

Piperazine

9003-29-6,       

Polybutenes

25036_29_7c

25322-68-3       

Polyethylene glycol

25322-69-4       

Polypropylene glycol

123—38—6        

Propionaldehyde

79-09-4        

Propionic acid

71-23-8        

n-propyl alcohol

107—10—8        

Propylamine

540-54-5        

Propyl chloride

115-07-1        

Propylene

127-00-4        

Propylene chlorohydrin

78-87-5        

Propylene dichloride

57-55-6        

Propylene glycol

568

75-56-9        

Propylene oxide

110—86—1       

Pyridine

106—51—4        

Quinone

108-46-3        

Resorcinol

27138-57-4      

Resorcylic acid

69—72—7        

Salicylic acid

127-09—3        

Sodium acetate

532-32-1       

Sodium benzoate

9004-32-4       

Sodium carboxymethyl cellulose

3926-62-3       

Sodium chioroacetate

141-53—7        

Sodium formate

139-02-6       

Sodium phenate

110-44-1       

Sorbic acid

100—42—5       

Styrene

110—15—6        

Succinic acid

110—61—2        

Succinitrile

121-57—3        

Sulfanilic acid

126—33—0

Sulfolane

1401—55—4       

Tannic acid

100-21-0       

Terephthalic acid

7934_5C              

Tetrachloroethanes

117-08-8        

Tetrachlorophthalic anhydride

78-00-2        

Tetraethyllead

119-64-2        

Tetrahydronaphthalene

85-43-8         

Tetrahydrophthalic anhydride

75-74-1        

Tetramethyllead

110-60-1

Tetramethylenediamine

110-18-9        

Tetramethylethylenediamine

108-88-3        

Toluene

95—80—7         

Toluene—2 , 

4—diamine

584—84—9        

Toluene—2

, 4—diisocyanate

26471-62-5       

Toluene diisocyanates

(mixture)

1333-07—9       

Toluene sulfonamide

104_15_4c        

Toluenesulfonic acids

98-59-9        

Toluene sulfonyl chloride

26915—12—8       

Toluidines

87-61-6,        

Trichlorobenzenes

108—70—3,

l20_82_1c

7 1-55-6        

1,1, l-trichloroethane

79-00—5

1,1, 2-trichloroethane

79-01-6        

Trichloroethylene

75-69-4        

Trichiorofluoromethane

96-18-4        

l,2,3—trichloropropane

76-13—1        

1,1, 2—trichloro—l, 2, 2—trifluor

oethane

121-44-8        

Triethylamine

112-27-6        

Triethylene glycol

112-49-2    

Triethylene glycoldimethyl

ether

569

7756-94-.7        

Triisobutylene

75-50-3

Trimethylamine

57-13-6        

Urea

108—05-4        

Vinyl acetate

75-01-4        

Vinyl chloride

75-35-4        

Vinylidene chloride

25013-15-4       

Vinyl toluene

1330-20-7       

Xylenes (mixed)

95—47—6        

o—xylene

106—42—3

p—xylene

1300—71—6       

Xylenol

1300—73—8

Xylidine

methyl tert-butyl ether

9002-88-4

Polyethylene

Polypropylene

9009-53-6       

Polystyrene

a)  CAS numbers refer to the Chemical Abstracts Registery

numbers assigned to specific chemicals, isomers or

mixtures of chemicals. Some isomers or mixtures that

are covered by

the standards do not have CAS numbers

assigned to them. The standards apply to all of the

chemicals listed, whether CAS numbers have been

assigned or not.

b)  No CAS number(s) have been assigned to this chemical,

to its isomers, or mixtures containing these chemicals.

c)  CAS numbers for some of the isomers are listed: the

standards apply to all of the isomers and mixtures,

even if CAS numbers have not been assigned.

(Source: Amended at 

—

Ill. Reg. 

______,

effective 

_________

570

Section 219.Appendix B

VON Measurement Techniques for Capture Efficiency

Procedure G.1

Captured 

VO~jEmissions

1.  INTRODUCTION

1.1 Applicability. This procedure is applicable for determining

the volatile organic oompoundsmaterials (VO~M) content of

captured gas streams. it is intended to be used as a segment in

the development of liquid/gas or gas/gas protocols for

determining VOG!~capture efficiency (CE) for surface coating and

printing operations. The procedure may not be acceptable in

certain site-specific situations, e.g., when: (1) direct fired

heaters or other circumstances affect the quantity of VO~?.j at the

control device inlet; and (2) particulate organic aerosols are

formed in the process and are present in the captured emissions.

1.2 Principle. The amount of VO~!’J captured (G) is calculated as

the sum of the products of the VO~Jcontent (C03), the flow rate

(Q~),and the sample time (To) from each captured emissions

point.

1.3 Estimated Measurement Uncertainty. The measurement

uncertainties are estimated for each captured or fugitive

emissions point as follows: Q~

5.5 percent and

C03

~5.0 percent. Based on these numbers, the probable

uncertainty for G is estimated at about ~7.4 percent.

1.4 Sampling Requirements. A capture efficiency test shall

consist of at least three sampling runs. The sampling time for

each run should be at least 8 hours, unless otherwise approved.

1.5 Notes. Because this procedure is often applied in highly

explosive areas, caution and care should be exercised in choosing

appropriate

equipment and installing and using the equipment.

Mention of trade names or company products does not constitute

endorsement. All gas concentrations (percent, ppm) are by

volume,

unless otherwise noted.

APPARATUS AND REAGENTS

2.1 Gas 

Concentration. A schematic of the measurement

system is shown in Figure 1. The main components are described

below:

2.1.1 Sample Probe. Stainless steel, or equivalent. The probe

shall be heated to prevent VO~,jcondensation.

2.1.2 Calibration Valve Assembly. Three—way valve assembly at

the outlet of sample probe to direct the zero and calibration

571

gases to the analyzer. Other methods, such as quick—connect

lines, to route calibration gases to the outlet of the sample

probe are acceptable.

2.1.3 Sample Line. Stainless steel or Teflon tubing to

transport the sample gas to the analyzer. The sample line must

be heated to prevent condensation.

2.1.4 Sample Pump. A leak-free pump, to pull the sample gas

through the system at a flow rate sufficient to minimize the

response time of the measurement system. The components of the

pump that contact the gas stream shall be constructed of

stainless steel or Teflon. The sample pump must be heated to

prevent condensation.

2.1.5 Sample Flow Rate Control. A sample flow rate control

valve and rotameter, or equivalent, to maintain a constant

sampling rate within 10 percent. The flow -rate control valve and

rotameter must be heated to prevent condensation. A control

valve may also be located on the sample pump bypass loop to

assist in controlling the sample pressure and flow rate.

2.1.6 Sample Gas Manifold. Capable of diverting a portion of

the sample gas stream to the flame ionization analyzer (FIA), and

the remainder to the bypass discharge vent. The manifold

components

shall be constructed of stainless steel or Teflon. If

captured or fugitive emissions are to be measured at multiple

locations, the measurement system shall be designed to use

separate sampling probes, lines, and pumps for each measurement

location and a common sample gas manifold and FIA. The sample

gas manifold and connecting lines to the FIA must be heated to

prevent condensation.

2.1.7 Organic Concentration Analyzer. An FIA with a span value

of 1.5 times the expected concentration as propane; however,

other span values may be used if it can be demonstrated that they

would provide more accurate measurements. The system shall be

capable of meeting or exceeding the following specifications:

2.1.7.1 Zero Drift. Less than ±3.0percent of the span value.

2.1.7.2 Calibration Drift. Less than ±3.0 percent of the span

value.

2.1.7.3 Calibration Error. Less than ±5.0percent of the

calibration gas value.

2.1.7.4 Response Time. Less than 30 seconds.

2.1.8 Integrator/Data Acquisition System. An analog or digital

device or computerized data acquisition system used to integrate

the FIA response or compute the average response and record

572

measurement data. The minimum data sampling frequency for

computing average or integrated values is one measurement value

every 5 seconds. The device shall be capable of recording

average values at least once per minute.

2.1.9 Calibration and Other Gases. Gases used for calibration,

fuel, and combustion air (if required) are contained in

compressed gas cylinders. All calibration gases shall be

traceable to NIST standards and shall be certified by the

manufacturer to ±1percent of the tag value. Additionally, the

manufacturer of the cylinder should provide a recommended shelf

life for each calibration gas cylinder over which the

concentration does not change more than ±2percent from the

certified value. For calibration gas values not generally

available, alternative methods for preparing calibration gas

mixtures, such as dilution systems, may be used with prior

approval.         

2.1.9.1 Fuel. A 40 percent H2/60 percent He or 40 percent H2/60

percent N2 gas mixture is recommended to avoid an oxygen

synergism effect that reportedly occurs when oxygen concentration

varies significantly from a mean value.

2.1.9.2 Carrier Gas. High purity air with less than 1 ppm of

organic material (as propane or carbon equivalent) or less than

0.1 percent of the span value, whichever is greater.

2.1.9.3 FIA Linearity Calibration Gases. Low-, mid—, and

high—range gas mixture standards with nominal propane

concentrations of 20-30, 45-55, and 70-80 percent of the span

value in air, respectively. Other calibration values and other

span values may be used if it can be shown that more accurate

measurements would be achieved.

2.1.10 Particulate Filter. An in-stack or an out—of-stack glass

fiber filter is recommended if exhaust gas particulate

loading is

significant. An out-of-stack filter must be heated to prevent

any condensation unless it can be demonstrated that no

condensation occurs.

2.2 Captured Emissions Volumetric Flow Rate.

2.2.1 Method 2 or 2A Apparatus. For determining volumetric flow

rate.

2.2.2 Method 3 Apparatus and Reagents. For determining

molecular weight of the gas stream. An estimate of the molecular

weight of the gas stream may be used if it can be justified.

2.2.3 Method 4 Apparatus and Reagents. For determining moisture

content, if 

necessary.

573

3.  DETERMINATION OF VOLUMETRIC FLOW RATE OF CAPTURED EMISSIONS

3.1 Locate all points where emissions are captured from the

affected facilityemission unit. Using Method 1, determine the

sampling points. Be sure to check each site for cyclonic or

swirling flow.

3.2 Measure the velocity at each sampling site at least once

every hour during each sampling run using Method 2 or 2A.

4.  DETERMINATION OF 

VOG!j

CONTENT OF CAPTURED EMISSIONS

4.1 Analysis Duration. Measure the

VO~?jresponses at each

captured emissions point during the entire test run or, if

applicable, while the process is operating. If there are

multiple captured emission locations, design a sampling system to

allow a single FIA to be used to determine the 

VO~.jresponses

at

all sampling locations.

4.2 Gas 

VOGM Concentration.

4.2.1 Assemble the sample train as shown in Figure 1. Calibrate

the FIA according to the procedure in Section 5.1.

4.2.2 Conduct a system check according to the procedure in

Section 5.3.

4.2.3 Install the sample probe so that the probe is centrally

located in the stack, pipe, or duct, and is sealed tightly at the

stack port connection.

4.2.4 Inject zero gas at the calibration valve assembly. Allow

the measurement system response to reach zero. Measure the

system response time as the time required for the system to reach

the effluent concentration after the calibration valve has been

returned to the effluent sampling position.

4.2.5 Conduct a system check before and a system drift check

after each sampling run according to the procedures in Sections

5.2 and 5.3. If the drift check following a run indicates

unacceptable performance, the run is not valid. The tester may

elect to perform system drift checks during the

run not to exceed

one drift check per hour.

4.2.6 Verify that the sample lines, filter, and pump

temperatures are 120 ±5°C.

4.2.7 Begin sampling at the start of the test period and

continue to sample during the entire run. Record the starting

and ending times and any required process information as

appropriate. If multiple captured emission 

locations are

sampled

using a single FIA, sample at each location for the same amount

574

of time (e.g., 2 minutes) and continue to switch from one

location to another for the entire test run. Be sure that total

sampling time at each location is the same at the end of the test

run. Collect at least 4 separate measurements from each sample

point during each hour of testing. Disregard the measurements at

each sampling location until two times the response time of the

measurement system has elapsed. Continue sampling for at least 1

minute and record the concentration measurements.

4.3 Background Concentration.

4.3.1 Locate all NDO’S of the TTE. A sampling point shall be

centrally located outside of the TTE at 4 equivalent diameters

from each MDO, if possible. If there are more than 6 NDO’s,

choose 6 sampling points evenly spaced among the NDO’s.

4.3.2 Assemble the sample train as shown in Figure 2. Calibrate

the FIA and conduct a system check according to the procedures in

Sections 5.1 and 5.3. NOTE: This sample train shall be a

separate sampling train from the one to measure the captured

emissions.

4.3.3 Position the probe at the sampling location.

4.3.4 Determine the response time, conduct the system check and

sample according to the procedures described in Sections 4.2.4 to

4.2.7.

4.4 Alternative Procedure. The direct interface sampling and

analysis procedure described in Section 7.2 of Method 18 may be

used to determine the

gas

VO~

concentration. The system must be designed to collect

and analyze at least one sample every 10 minutes.

5.  CALIBRATION AND QUALITY ASSURANCE

5.1 FIA Calibration and Linearity Check. Make necessary

adjustments to the air and fuel

supplies for the FIA and ignite

the burner. Allow the FIA to warm up for the period recommended

by the manufacturer. Inject a calibration gas into the

measurement system and adjust the back—pressure regulator to the

value required to achieve the flow rates specified by the

manufacturer. Inject the zero— and the high—range calibration

gases and adjust the analyzer calibration to provide the proper

responses. Inject the low- and mid—range gases and record the

responses of the measurement system. The calibration and

linearity of the system are acceptable if the responses for all

four gases are within

5 percent of the respective gas values. If

the performance of the system is not acceptable, repair or adjust

the system and repeat the linearity check. Conduct a calibration

and linearity check after assembling the analysis system and

after a major change is made to the system.

575

5.2 Systems Drift Checks. Select the calibration gas that most

closely approximates the concentration of the captured emissions

for conducting the drift checks. Introduce the zero and

calibration gas at the calibration valve assembly and verify that

the appropriate gas flow rate and pressure are present at the

FIA. Record the measurement system responses to the zero and

calibration gases. The performance of the system is acceptable

if the difference between the drift check measurement and the

value obtained in Section 5.1 is less than 3 percent of the span

value. Conduct the system drift checks at the end of each run.

5.3 System Check. Inject the high range calibration gas at the

inlet of the sampling probe and record the response. The

performance of the system is

acceptable if the measurement system

response is within 5 percent of the value obtained in Section 5.1

for the high range calibration gas. Conduct a system check

before and after each test

run.

5.4 Analysis Audit. Immediately before each test analyze an

audit cylinder as described in Section 5.2. The analysis audit

must agree with the audit cylinder concentration within 10

percent.

6.  NOMENCLATURE

A1

area of NDO i, ft2~-.j

AN

total area of all NDO’s in the enclosure, ft2--j

C~

corrected average VOC~concentration of background

emissions at point i, ppm propane--j.

C~

average background concentration, ppm propane-~

=

corrected average VOC~concentration of captured

emissions at point j, ppm propane-s-.;

CDH

=

average measured concentration for the drift check

calibration gas, ppm propane~-;

C~

average system drift check concentration for zero

concentration gas, ppm propane-~j

actual concentration of the drift check

calibration gas, ppm

propane-a

uncorrected average background VOCN concentration

measured at point i, ppm propane--j.

C~

uncorrected average VOCM concentration measured at

point j, ppm propane-~-j

576

G

=

total VOC~content of captured emissions, kg-ri

=

1.830 x 10~kg/(1n3-ppm)-r.~

n

=

number of measurement points--j~

~

=

average effluent volumetric flow rate corrected to

standard conditions at captured emissions point j,

m3/min,-~i.

T~

=

total duration of captured emissions sampling run,

mm.

7.  CALCULATIONS

7.1 Total 

VO~MCaptured

Emissions.

G

(C0~ 

C8

)

Q~T~K1 Eq. 1

j=1

7.2

VO~J Concentration

of the Captured Emissions at Point j.

(c3

C~)

CR

Eq. 2

CDH -

7.3 Background VOGM Concentration at Point i.

(C1

C~)

CR

Eq. ~

C~

7.4 Average Background Concentration.

n

CB

=

i-i~

C131 A1

Eq. 4

NOTE: If the concentration at each point is within 20 percent of

the average concentration of all points, the terms “A-” and “AN”

may be deleted from Equation 4.

Procedure G.2 

Captured 

VO~,j

Emissions (Dilution Technique)

1.  INTRODUCTION

1.1 Applicability.

This procedure is applicable for determining

the volatile organic compoundsmaterials (VOGrj) content of

captured gas streams. It is intended to be used as a segment in

the development of a gas/gas protocol in which fugitive emissions

577

are measured for determining VO~1jcapture efficiency

(CE) for surface coating and printing operations. A dilution

system is used to reduce the VO~1concentration of the captured

emission to about the same concentration as the fugitive

emissions. The procedure may not be acceptable in certain

site—specific situations, e.g., when: (1) direct fired heaters or

other circumstances affect the quantity of VOG?j at the control

device inlet; and (2) particulate organic aerosols are formed in

the process and

are present in the captured emissions.

1.2 Principle. The amount of VO~ captured (G) is calculated as

the sum of the products of the VO~Icontent (C~),the flow rate

(Q~),and the sampling time (Ta) from each captured emissions

point.

1.3 Estimated Measurement Uncertainty. The measurement

uncertainties are estimated for each captured or fugitive

emissions point as follows: Q0~

=

±5.5percent and C03 

=

±5

percent. Based on these numbers, the probable uncertainty for G

is estimated at about ±7.4percent.

1.4 Sampling Requirements. A capture efficiency test shall

consist of at least three sampling runs. The sampling time for

each run should be at least 8 hours, unless otherwise approved.

1.5 Notes. Because this procedure is often applied in highly

explosive areas, caution and care should be exercised in choosing

appropriate equipment and installing and using the equipment.

Mention of trade names or company products does not constitute

endorsement. All gas concentrations (percent, ppm) are by

volume, unless otherwise

noted.

2.  APPARATUS AND REAGENTS

2.1 Gas VO~j Concentration. A schematic of the measurement

system is shown in Figure 1. The main components are described

below:

2.1.1 Dilution System. A Kipp in-stack dilution probe and

controller or similar device may be used. The dilution rate may

be changed by substituting different critical orifices or

adjustments of the aspirator supply pressure. The dilution

system shall be heated to prevent VOG~ condensation. Note: An

out-of-stack dilution device may be used.

2.1.2 Calibration Valve Assembly. Three—way valve assembly at

the outlet of sample probe to direct the zero and calibration

gases to the analyzer. Other methods, such as quick—connect

lines, to route calibration gases to the outlet of the sample

probe are acceptable.

578

2.1.3 Sample Line. Stainless steel or Teflon tubing to

transport the sample gas to the analyzer. The sample line must

be heated to prevent condensation.

2.1.4 Sample Pump. A leak-free pump, to pull the sample gas

through the

system at a flow rate sufficient to minimize the

response time of the measurement system. The components of the

pump that contact the gas stream shall be constructed of

stainless steel or Teflon. The sample pump must be heated to

prevent condensation.

2.1.5 Sample Flow Rate Control. A sample flow rate control

valve and rotameter, or equivalent, to maintain a constant

sampling rate within 10

percent. The flow control valve and

rotameter must be heated to prevent condensation. A control

valve may also be located on the sample pump bypass loop to

assist

in controlling the sample pressure and flow rate.

2.1.6 Sample Gas Manifold. Capable of diverting a portion of

the sample gas stream to the flame ionization analyzer (FIA), and

the remainder to 

the bypass discharge vent. The manifold

components shall be constructed of stainless steel or Teflon. If

captured or fugitive emissions are to be measured at multiple

locations, the measurement system shall be designed to use

separate sampling probes, lines, and pumps for each measurement

location and a common sample gas manifold and FIA. The sample

gas manifold and connecting lines to the FIA must be heated to

prevent condensation.

2.1.7 Organic Concentration Analyzer. An FIA with a span value

of 1.5 times the expected concentration as propane; however,

other span values may be used if it can be demonstrated that they

would provide more accurate measurements. The system shall be

capable of meeting or exceeding the following

specifications:

2.1.7.1 Zero Drift. Less than ±3.0percent of the span value.

2.1.7.2 Calibration Drift. Less than ±3.0percent of the span

value.

2.1.7.3 Calibration Error. Less than ±5.0percent of the

calibration gas value.

2.1.7.4 Response Time. Less than 30 seconds.

2.1.8 Integrator/Data Acquisition System. An analog or digital

device or computerized data acquisition system used to integrate

the FIA response or compute the average response and record

measurement data. The minimum data sampling frequency for

computing average or integrated values is one measurement value

every 5 seconds. The device shall be capable of recording

average values at least once per minute.

579

2.1.9 Calibration and Other Gases. Gases used for calibration,

fuel, and combustion air (if required) are contained in

compressed gas cylinders. All calibration gases shall be

traceable to NIST standards and shall be certified by the

manufacturer to ±1percent of the tag value. Additionally, the

manufacturer of the cylinder should provide a recommended shelf

life for each calibration gas cylinder over which the

concentration does not change more than ±2percent from the

certified value. For calibration gas values not generally

available, alternative methods for preparing calibration gas

mixtures, such as dilution systems, may be used with prior

approval.

2.1.9.1 Fuel. A 40 percent H2/60 percent He or 40 percent H2/60

percent N2 gas mixture is recommended to avoid an oxygen

synergism effect that reportedly occurs when oxygen concentration

varies significantly from a mean value.

2.1.9.2 Carrier Gas and Dilution Air Supply. High purity air

with less than 1 ppm of organic material (as propane or carbon

equivalent) or less than 0.1 percent of the span value, whichever

is greater.

2.1.9.3 FIA Linearity Calibration Gases. Low-, mid-, and

high-range gas mixture standards with nominal propane

concentrations of 20-30, 45-55, and 70-80 percent of the span

value in air, respectively. Other calibration values and other

span values may be used if it can be shown that more accurate

measurements would be achieved.

2.1.9.4 Dilution Check Gas. Gas mixture standard containing

propane in air, approximately half the span value after dilution.

2.1.10 Particulate Filter. An in-stack or an out-of-stack glass

fiber filter is recommended if exhaust gas particulate

loading is

significant. An 

out-of-stack filter

must be heated to prevent

any condensation unless it can be demonstrated that no

condensation occurs.

2.2 Captured Emissions Volumetric Flow Rate.

2.2.1 Method 2 or 2A Apparatus. For determining volumetric flow

rate.

2.2.2 Method 3 Apparatus and Reagents. For determining

molecular weight of the gas stream. An estimate of the molecular

weight of the gas stream may be used if it can be justified.

2.2.3 Method 4 Apparatus and Reagents. For determining moisture

content, if necessary.

580

DETERMINATION OF VOLUMETRIC FLOW RATE OF CAPTURED EMISSIONS

3.1 Locate all points where emissions are captured from the

affected facility. Using Method 1, determine the sampling points.

Be sure to check each site for cyclonic or swirling flow.

3.2 Measure the velocity at each sampling site at least once

every hour during each sampling run using Method 2 or 2A.

4.  DETERMINATION OF 

VO~

CONTENT OF CAPTURED EMISSIONS

4.1 Analysis Duration. Measure the VO~ responses at each

captured emissions point during the entire test run or, if

applicable, while the process is operating. If there are a

multiple captured emissions locations, design a sampling system

to allow a single FIA to be used to determine the 

VO~

responses

at all sampling locations.

4.2 Gas 

VOQ~Concentration.

4.2.1 Assemble the sample train as shown in Figure 1. Calibrate

the FIA according to the procedure in Section 5.1.

4.2.2 Set the dilution ratio and determine the dilution factor

according to the procedure in Section 5.3.

4.2.3 Conduct a system check according to the procedure in

Section 5.4.

4.2.4 Install the sample probe so that the probe is centrally

located in the stack, pipe, or duct, and is sealed tightly at the

stack port connection.

4.2.5 Inject zero gas at the calibration valve assembly.

Measure the system response time as the time required for the

system to reach the effluent concentration after the calibration

valve has been returned to the effluent sampling position.

4.2.6 Conduct a system check before and •a system drift check

after each sampling run according to the procedures in Sections

5.2 and 5.4. If the drift check following a run indicates

unacceptable performance, the run is not valid. The tester may

elect to perform system drift checks during the run not to exceed

one drift check per hour.

4.2.7 Verify that the sample lines, filter, and pump

temperatures are 120 ±5°C.

4.2.8 Begin sampling at the start of the test period and

continue to sample during the entire run. Record the starting

and ending times and any required process information as

581

appropriate.

If multiple captured emission locations are sampled

using a single FIA, sample at each location for the same amount

of time (e.g., 2 minutes) and continue to switch from one

location to another for the entire test run. Be sure that total

sampling time at each location is the same at the end of the test

run. Collect at least 4 separate measurements from each sample

point during each hour of testing. Disregard the measurements at

each sampling location until two times the response time of the

measurement system has elapsed. Continue sampling for at least 1

minute and record the concentration measurements.

4.3 Background Concentration.

4.3.1 Locate all NDO’s of the TTE. A sampling point shall be

centrally located outside of the TTE at 4 equivalent diameters

from each NDO, if possible. If there are more than 6 NDO’s,-

choose 6 sampling points evenly spaced among the NDO’s.

4.3.2 Assemble the sample train as shown in Figure 2. Calibrate

the FIA and conduct a system check according to the procedures in

Sections 5.1 and 5.4.

4.3.3 Position the probe at the sampling location.

4.3.4 Determine the response time, conduct the system check and

sample according to the procedures described in Sections 4.2.4 to

4.2.8.

4.4 Alternative Procedure. The

direct interface sampling and

analysis procedure described in Section 7.2 of Method 18 may be

used to determine the gas VO~jconcentration. The system must be

designed to collect and analyze at least one sample every 10

minutes.

5.  CALIBRATION AND QUALITY 

ASSURANCE

5.1 FIA Calibration and Linearity Check. Make necessary

adjustments to the air and fuel supplies for the FIA and ignite

the burner. Allow the FIA to warm up for the period recommended

by the manufacturer. Inject a calibration gas into the

measurement system after the dilution system and adjust the back—

pressure regulator to the value required to achieve the flow

rates specified by the manufacturer.

Inject the zero— and the

high-range calibration gases and adjust the analyzer calibration

to provide the proper responses. Inject the low— and mid-range

gases and record the responses of the measurement system. The

calibration and linearity of the system are acceptable if the

responses for all four gases are within 5 percent of the

respective gas values. If the performance of the system is not

acceptable, repair or adjust the system and repeat the linearity

check. Conduct a calibration and linearity check after

582

assembling the analysis system and after a major change is made

to the system.

5.2 Systems Drift Checks. Select the calibration gas that most

closely approximates the concentration of the diluted captured

emissions for conducting the drift checks.

Introduce the zero

and calibration gas at the calibration valve assembly and verify

that the appropriate gas flow rate and pressure are present at

the FIA. Record the measurement system responses to the zero and

calibration gases. The performance of the system is acceptable

if the difference between the drift check measurement and the

value obtained in Section 5.1 is less than 3 percent of the span

value. Conduct the system drift check at the end of each run.

5.3 Determination of Dilution Factor. Inject the dilution check

gas into the measurement system before the dilution system and

record the response. Calculate the dilution factor using

Equation 3.

5.4 System Check. Inject the high range calibration gas at the

inlet to the sampling probe while the dilution air is turned off.

Record the response. The performance of the system is acceptable

if the measurement system response is within 5 percent of the

value obtained in Section 5.1 for the high range calibration gas.

Conduct a system check before and after each test run.

5.5 Analysis Audit. Immediately before each test analyze an

audit cylinder as described in Section 5.2. The analysis audit

must agree with the audit cylinder concentration within 10

percent.

6.  NOMENCLATURE

A,

=

area of NDO i, ft2~-~

AN

=

total area of all NDO’s in the enclosure, ft2,-.L

CA

=

actual concentration of the dilution check gas,

ppm propane-a

C13,   

=

corrected average VOC~concentration of background

emissions at point i, ppm propane-~j

C8

=

average background concentration, ppm propane--;

CDH

=

average measured concentration for the drift check

calibration gas, ppm propane-rj

C~

=

average 

system

drift check concentration for zero

concentration gas, ppm propane-a

583

CR

=

actual concentration of the drift check

calibration gas, ppm propane--j

C,

=

uncorrected average background VOC!~concentration

measured at point i, ppm propane,-~

C3

=

uncorrected average VOC~concentration measured at

point j, ppm propane-a

CM

=

measured concentration of the dilution check gas,

ppm propane-u.

DF

=

dilution factor~-j~.

G

=

total VOCM content of captured emissions, kg-rj~.

=

1.830 

x 10~kg/(m3-ppm)-r~j

n

=

number of measurement points--j

Q03

=

average effluent volumetric flow rate corrected to

standard conditions at captured emissions point j,

m3/min-~

T~

=

total duration of capture efficiency sampling run,

mm.

7.  CALCULATIONS

7.1 Total VO~J Captured Emissions.

n

G = E C~ Q~ T~ K1  Eq. 1

jl

7.2

VO~jConcentration

of the Captured Emissions at Point j.

DF (C3 

C~)

CR

Eq. 2

CDH

7.3 Dilution Factor.

DF

=

CA_ Eq. 3

CM

7.4 Background 

VO~GM

Concentration at Point i.

C13, 

=

(C

C~)

CR_____  Eq. 4

CDH -

C~

584

7.5 Average Background Concentration.

n

~ C~ A,

C8=i=l     

Eq. 5

nAN

NOTE: If the concentration at each point is within 20 percent of

the average concentration of all points, the terms “As” and “AN”

may be deleted from Equation 4.    

Procedure F.2 

Fugitive VOG~,j Emissions from Building Enclosures

1. INTRODUCTION

1.1 Applicability. This procedure is applicable for determining

the fugitive volatile organic compoundomaterials 

(VO~j)

emissions

from a building enclosure (BE). It is intended to be used as a

segment in the development of liquid/gas or gas/gas protocols for

determining VO~j capture efficiency (CE) for surface coating and

printing operations.

1.2 Principle. The total amount of fugitive 

VO~!.Jemissions

(FB)

from the BE is calculated as the sum of the products of the VOG~j

content (CF3) of each fugitive emissions point, its flow rate

(QF3), and time (TF).

1.3 Measurement Uncertainty.

The measurement uncertainties

are

estimated for each fugitive emissions point as follows: QF3 

=

±5.0percent and CF3 

=

±5.0percent. Based on these numbers, the

-probable uncertainty for F13 is estimated at about ±11.2percent.

1.4 Sampling Requirements. A capture efficiency test shall

consist of at least three sampling runs. The sampling time for

each run should be at least 8 hours, unless otherwise approved.

1.5 Notes. Because this procedure is

often applied in highly

explosive areas, caution and care should be exercised in choosing

appropriate equipment and installing and using the equipment.

Mention of trade names or company products does not constitute

endorsement. All gas concentrations (percent, ppm) are by

volume, unless otherwise noted.

APPARATUS AND 

REAGENTS

2.1 Gas 

VO?!,J

Concentration. A schematic of the measurement

system is shown in Figure 1. The main components are described

below:

2.1.1 Sample Probe. Stainless steel, or equivalent. The probe

shall be heated to prevent voq~condensation.

585

2.1.2 Calibration Valve Assembly. Three-way valve assembly at

the outlet of sample probe to direct the zero and calibration

gases to the analyzer. Other methods, such as quick—connect

lines, to route calibration gases to the outlet of the sample

probe are acceptable.

2.1.3 Sample Line. Stainless steel or Teflon tubing to

transport the sample gas to the analyzer. The sample line must

be heated to prevent condensation.             

2.1.4 Sample Pump. A leak-free pump, to pull the sample gas

through the system at a flow rate sufficient to minimize the

response time of the measurement system. The components of the

pump that contact the gas stream shall be constructed of

stainless steel or Teflon. The sample pump must be heated to

prevent condensation.

2.1.5 Sample Flow

Rate Control. A sample flow rate control

valve and rotameter, or equivalent, to maintain a constant

sampling rate within 10 percent. The flow rate control valve and

rotameter must be heated to prevent condensation. A control

valve may also be located on the sample pump bypass loop to

assist in controlling the sample pressure and flow rate.

2.1.6 Sample Gas Manifold. Capable of diverting a portion of

the sample gas stream to the flame ionization analyzer (FIA), and

the remainder to the bypass discharge vent. The manifold

components shall be constructed of stainless steel or Teflon. If

emissions are to be measured at multiple locations, the

measurement system shall be designed to use separate sampling

probes, lines, and pumps for each measurement location and a

common sample gas manifold and FIA. The sample gas manifold must

be heated to prevent

condensation.

2.1.7 Organic Concentration Analyzer. An FIA with a span value

of 1.5 times the expected concentration as propane; however,

other span values may be used if it can be demonstrated that they

would provide more accurate measurements. The system shall be

capable of meeting or exceeding the following specifications:

2.1.7.1 Zero Drift. Less than ±3.0 percent of the span value.

2.1.7.2 Calibration Drift. Less than ±3.0percent of the span

value.

2.1.7.3 Calibration Error. Less than ±5.0percent of the

calibration gas value.

2.1.7.4 Response Time. Less than 30 seconds.

2.1.8 Integrator/Data Acquisition System. An analog or digital

device or computerized data acquisition system used to integrate

586

the FIA response or compute the average response and record

measurement data. The minimum data sampling frequency for

computing average or integrated values is one measurement value

every 5 seconds. The device shall be capable of recording

average values at least once per minute.

2.1.9 Calibration and Other Gases. Gases used for calibration,

fuel, and combustion air (if required) are contained in

compressed gas cylinders. All calibration gases shall be

traceable to NIST standards and shall be certified by the

manufacturer to ±1percent of the tag value. Additionally, the

manufacturer of the cylinder should provide a recommended shelf

life for each calibration gas cylinder

over which the

concentration does not change more than ±2percent from the

certified value. For calibration gas values not generally

available, alternative methods for preparing calibration gas

mixtures, such as dilution systems, may be used with prior

approval.

2.1.9.1 Fuel. A 40 percent H2/60 percent He or 40 percent H2/60

percent N2 gas mixture is recommended to avoid an oxygen

synergism effect that reportedly occurs when oxygen concentration

varies significantly from a mean value.

2.1.9.2

Carrier Gas. High purity air with less than 1 ppm of

organic material (propane or carbon equivalent) or less than 0.1

percent of the span value, whichever is greater.

2.1.9.3 FIA 

Linearity Calibration Gases. Low-, mid-, and

high-range gas mixture standards with nominal propane

concentrations of 20—30, 45—55, and 70—80 percent of the span

value in air, respectively. Other calibration values and other

span values may be used if it can be shown that more accurate

measurements would be achieved.

2.1.10 Particulate Filter. An in-stack or an out-of-stack glass

fiber filter is recommended if exhaust gas particulate loading is

significant.

An out-of-stack filter must be heated to prevent

any condensation unless it can be demonstrated that no

condensation occurs.

2.2 Fugitive Emissions Volumetric Flow Rate.

2.2.1 Flow Direction Indicators. Any means of indicating inward

or outward flow, such as light plastic film or paper streamers,

smoke tubes, filaments, and sensory perception.

2.2.2 Method 2 or 2A Apparatus. For determining volumetric flow

rate. Anemometers or similar devices calibrated according to the

manufacturer’s instructions may be used when low velocities are

present. Vane anemometers (Young-maximum response propeller),

587

specialized pitots with electronic manometers- (e.g., Shortridge

Instruments Inc., Airdata Multimeter 860) are commercially

available with measurement thresholds of 15 and 8 mpm (50 and

25 fpm), respectively.

2.2.3 Method 3 Apparatus and Reagents. For determining

molecular weight of the gas stream. An estimate of the molecular

weight of the gas stream may be used if it can be justified.

2.2.4 Method 4 Apparatus and Reagents. For determining moisture

content, if necessary.

DETERMINATION OF VOLUMETRIC FLOW RATE OF FUGITIVE

EMISSIONS

3.1 Preliminary Determinations. The purpose of this exercise is

to determine which exhaust points should be measured for

volumetric flow rates and VOGN concentrations.

3.1.1 Forced Draft Openings. Identify all forced draft

openings. Determine the volumetric flow rate according to Method

2.

3.1.2 NDO’s Exhaust Points. The NDO’s in the roof of ~

-f-acilitythe building or room in which the emission unit is

located are considered to be exhaust points. Determine

volumetric flow rate from these NDO’s. Divide the

cross—sectional area according to Method 1 using 12 equal areas.

Use the appropriate velocity measurement devices, e.g., propeller

anemometers.

3.1.3 Other NDO’s.

3.1.3.1 This step is optional. Determine the exhaust flow rate,

including that of the control device, from the enclosure and the

intake air flow rate. If the exhaust flow rate divided by the

intake air flow rate is greater than 1.1, then all other NDO’s

are not considered to be significant exhaust points.

3.1.3.2 If the option above is not taken, identify all other

NDO’s and other potential points through which fugitive emissions

may escape the enclosure.

Then use the following criteria to determine whether flow rates

and

VOG~1

concentrations need to be measured:

3.1.3.2.1 Using the appropriate flow direction indicator,

determine the flow direction. An NDO with zero or inward flow is

not an exhaust point.

3.1.3.2.2 Measure the outward volumetric flow rate from the

remainder of the NDO’s. If the collective flow rate is 2

percent, or less, of the flow rate from Sections 3.1.1 and 3.1.2,

588

then these NDO’s, except those within two equivalent diameters

(based on NDO opening) from 

~VOG)j

3ourocoemitting point, may be

considered to be non-exhaust points.

3.1.3.2.3 If the percentage calculated in Section 3.1.3.2.2 is

greater than 2 percent, those NDO’s (except those within two

equivalent diameters from aVO oouroc3emitting point) whose

volumetric flow rate total 2 percent of the flow rate from

Sections 3.1.1 and 3.1.2 may be considered as non—exhaust points.

All remaining NDO’s shall be measured for volumetric flow rate

and

VOG~concentrations

during the CE test.

3.1.3.2.4 The tester may choose to measure 

voq~concentrations

at the forced exhaust points and the NDO’s. If the total VOGI~

emissions from the NDO’s are less than 2 percent of the emissions

from the forced draft and roof NDO’s, then these NDO’s may be

eliminated from further consideration.

3.2 Determination of Flow Rates.

3.2.1 Measure the volumetric flow rate at all locations

identified as exhaust points in Section 3.1. Divide each exhaust

opening into 9 equal areas for rectangular openings and 8 for

circular openings.

3.2.2 Measure the velocity at each site at least once every hour

during each sampling run using Method 2 or-2A, if applicable, or

using the low velocity instruments in Section 2.2.2.

4.  DETERMINATION OF 

VOGN

CONTENT OF FUGITIVE EMISSIONS

4.1 Analysis Duration. Measure the VOG~jresponses at each

fugitive emission point during the entire test run or, if

applicable, while the process is operating. If there are

multiple emissions locations, design a sampling system to allow a

single FIA to be used to determine the VOG~ responses at all

sampling locations.

4.2 Gas VOGM Concentration.

4.2.1 Assemble the sample train as shown in Figure 1. Calibrate

the FIA and conduct a system check according to the procedures in

Sections 5.1 and 5.3, respectively.

4.2.2 Install the sample probe so that the probe is centrally

located in the stack, pipe, or duct, and is sealed tightly at the

stack port connection.

4.2.3 Inject zero gas at the calibration valve assembly. Allow

the measurement system response to reach zero. Measure the

system response time as the time required for the system to reach

589

the effluent concentration after the calibration valve has been

returned to the effluent sampling position.

4.2.4 Conduct a system check before and a system drift check

after each sampling run according to the procedures in Sections

5.2 and 5.3. If the drift check following a run indicates

unacceptable performance, the run is not valid. The tester may

elect to perform drift checks during the run not to exceed one

drift check per hour.

4.2.5 Verify that the sample lines, filter, and pump

temperatures are 120 ±5°C.

4.2.6 Begin sampling at the start of the test period and

continue to sample during the entire run. Record the starting

and ending times and any required process information as

appropriate. If multiple emission locations are sampled using a

single

FIA, sample at each location for the same amount of time

(e.g., 2 minutes) and continue to switch from one location to

another for the entire test run. Be sure that total sampling

time at each location is the same at the end of the test run.

Collect at least 4 

separate measurements from each sample point

during each hour of testing. Disregard the response measurements

at each sampling location until two times the response time of

the measurement system has elapsed. Continue sampling for at

least 1 minute and record the concentration measurements.

4.3 Alternative Procedure The direct interface sampling and

analysis procedure described in Section 7.2 of 

Method 18 may be

used to determine the gas VOG~1concentration. The system must be

designed to collect and analyze at least one sample every 10

minutes.

5.  CALIBRATION AND QUALITY ASSURANCE

5.1 FIA Calibration and Linearity Check. Make necessary

adjustments to the air and fuel supplies for the FIA and ignite

the burner. Allow the FIA to warm up for the period recommended

by the manufacturer. Inject a calibration gas into the

measurement 

system and adjust the back—pressure regulator to the

value required to achieve the flow rates specified by the

manufacturer. Inject the zero- and the high-range calibration

gases and adjust the analyzer calibration to provide the proper

responses. Inject the low- and mid-range gases and record the

responses of the measurement 

system.

The calibration and

linearity of the system are acceptable if the responses for all

four gases are within 5 percent of the respective gas values. If

the performance of the system is not acceptable, repair or adjust

the system and repeat the linearity check. Conduct a calibration

and linearity check after assembling the analysis system and

after a major change is made to the system.

590

5.2 Systems Drift Checks. Select the calibration gas that most

closely approximates the concentration of the captured emissions

for conducting the drift checks. Introduce the zero and

calibration gas at the calibration valve assembly and verify that

the appropriate gas flow rate and pressure are present at the

FIA. Record the measurement system responses to the zero and

calibration gases. The performance of the system is acceptable

if the difference between the drift check measurement and the

value obtained in Section 5.1 is less than 3 percent of the span

value. Conduct a system drift check at the end of each run.

5.3 System Check. Inject the high range calibration gas at the

inlet of the sampling probe and record the response. The

performance of the system is acceptable if the measurement system

response is within 5 percent of the value obtained in Section 5.1

for the high range calibration gas. Conduct a system check

before each test run.

5.4 Analysis Audit. Immediately before each test analyze an

audit cylinder as described in Section 5.2. The analysis audit

must agree with the audit cylinder concentration within 10

percent.

6.  NOMENCLATURE

=

average measured concentration for the drift check

calibration gas, ppm propane-~j

=

average system drift check concentration for zero

concentration gas, ppm propane-i-;

CFi

=

corrected average 

VOG~concentration

of fugitive

emissions at point j, ppm propane-~

CH

=

actual concentration of the drift check

calibration gas, ppm propane-~

C~

=

uncorrected average VOGN concentration measured at

point j, ppm propane.j

F8

=

total 

voq~j

content of fugitive emissions from the

building, kg-~

=

1.830 x 10~kg/(m3-ppm)-r~j

n

=

number of measurement points~-~

QF3

=

average effluent volumetric flow rate corrected to

standard conditions at fugitive emissions point j,

m3/min--j

591

TF  =  total duration of capture efficiency sampling run,

mm.

7.  CALCULATIONS

7.1 Total 

VOG~Fugitive

Emissions From the Building.

E C~ 

QF3

TF K1                          

Eq. 2

j=1

7.2

VOG?j

Concentration of the Fugitive Emissions at Point j.

CFj

=

(C~

C~)

CR_____               

Eq. 2

Procedure F.1 

—

Fugitive VOGN Emissions from Temporary Enclosures

1. INTRODUCTION

1.1 Applicability. This procedure is applicable for determining

the fugitive volatile organic compoundcmaterials (VOGN) emissions

from a temporary total enclosure (TTE). It is intended to be

used as a segment in the development of liquid/gas or gas/gas

protocols for determining VOG~Jcapture efficiency (CE) for

surface coating and printing operations.

1.2 Principle. The amount of fugitive VOGM emissions (F) from

the TTE is calculated as the sum of the products of the VOGN

content (CF))~ the flow rate (QF3), and the sampling time (TF) from

each fugitive emissions point.

1.3 Estimated Measurement Uncertainty. The measurement

uncertainties are estimated for each fugitive emission point as

follows: Q1~=±5.5percent and CF3 

=

±5.0percent. Based on

these numbers, the probable uncertainty for F is estimated at

about ±7.4 percent.

1.4 Sampling Requirements. A capture efficiency test shall

consist of at least three sampling runs. The sampling time for

each run should be at least 8 hours, unless otherwise approved.

1.5 Notes. Because this procedure is often applied in highly

explosive areas, caution and care should be exercised in choosing

appropriate equipment and installing and using the equipment.

Mention of trade names or company products does not constitute

endorsement. All gas concentrations (percent, ppm) are by

volume, unless otherwise noted.

2.  APPARATUS AND REAGENTS

592

2.1

Gas VOGM Concentration.

A schematic of the measurement

system is shown in Figure 1. The main components are described

below:

2.1.1 Sample Probe. Stainless steel, or equivalent. The probe

shall be heated to prevent VOG~condensation.

2.1.2 Calibration Valve Assembly. Three-way valve assembly at

the outlet of sample probe to direct the zero and calibration

gases to the analyzer. Other methods, such as quick-connect

lines, to route calibration gases to the outlet of the sample

probe are acceptable.

2.1.3 Sample Line. Stainless steel or Teflon tubing to

transport the sample gas to the analyzer. The sample line must

be heated to prevent condensation.

2.1.4 Sample Pump. A leak-free pump, to pull the sample gas

through the system at a flow rate sufficient to minimize the

response time of the measurement system. The components of the

pump that contact the gas stream shall be constructed of

stainless steel or Teflon. The sample pump must be heated to

prevent condensation.

2.1.5 Sample Flow Rate Control. A sample flow rate control

valve and rotameter, or equivalent, to maintain a constant

sampling rate within 10 percent. The flow control valve and

rotameter must be heated to prevent condensation. A control

valve may also be located on the sample pump bypass loop to

assist in controlling the sample pressure and flow rate.

2.1.6 Sample Gas Manifold. Capable of diverting a portion of

the sample gas stream to the flame ionization analyzer (FIA), and

the remainder to the bypass discharge vent. The manifold

components shall be constructed of stainless steel or Teflon. If

emissions are to be measured at multiple locations, the

measurement system shall be designed to use separate sampling

probes, lines, and pumps for each measurement location and a

common sample gas manifold and FIA. The sample gas manifold and

connecting lines to the FIA must be heated to prevent

condensation.

2.1.7 Organic Concentration Analyzer.

An FIA with a span

value

of 1.5 times the expected concentration as propane; however,

other span values may be used if it can be demonstrated that they

would provide more accurate measurements. The system shall be

capable of meeting or exceeding the following specifications:

2.1.7.1 Zero Drift. Less than ±3.0percent of the span value.

2.1.7.2 Calibration Drift. Less than ±3.0percent of the span

value.

593

2.1.7.3 Calibration Error. Less than ±5.0percent of the

calibration gas value.

2.1.7.4 Response Time. Less than 30 seconds.

2.1.8 Integrator/Data Acquisition System. An analog or digital

device or computerized data acquisition system used to integrate

the FIA response or compute the average response and record 

measurement data. The minimum data sampling frequency for

computing average or integrated values is one measurement value

every 5 seconds. The device shall be capable of recording

average values at least once per minute.    

2.1.9 Calibration and Other Gases. Gases used for calibration,

fuel, and combustion air (if required) are contained in

compressed gas cylinders. All calibration gases shall be

traceable to NIST standards and shall be certified by the

manufacturer to ±1 percent of the tag value. Additionally, the

manufacturer of the cylinder should provide a recommended shelf

life for each calibration gas cylinder over which the

concentration does not change more than ±2 percent from the

certified value. For calibration gas values not generally

available, alternative methods for preparing calibration gas

mixtures, such as dilution systems, may be used with prior

approval.

2.1.9.1 Fuel. A 40 percent H2/60 percent He or 40 percent H2/60

percent N2 gas mixture is recommended to avoid an oxygen

synergism effect that reportedly occurs when oxygen concentration

varies significantly from a mean value.

2.1.9.2 Carrier Gas. High purity air with less than 1 ppm of

organic material (as propane or carbon equivalent) or less than

0.1 percent of the span value, whichever is greater.

2.1.9.3 FIA Linearity Calibration Gases. Low-, mid-, and

high-range gas mixture standards with nominal propane

concentrations of 20-30, 45-55, and 70-80 percent of the span

value in air, respectively. Other calibration values and other

span values may be used if it can be shown that more accurate

measurements would be achieved.

2.1.10 Particulate Filter. An in-stack or an out—of-stack glass

fiber filter is recommended if exhaust gas particulate loading is

significant. An out-of-stack filter must be heated to prevent

any condensation unless it can be demonstrated that no

condensation occurs.

2.2 Fugitive Emissions Volumetric Flow Rate.

594

2.2.1 Method 2 or 2A Apparatus. For determining volumetric flow

rate.

2.2.2 Method 3 Apparatus and Reagents. For determining

molecular weight of the gas stream. An estimate of the molecular

weight of the gas stream may be used if it can be justified.

2.2.3

Method 4 Apparatus and Reagents.

For determining moisture

content, if necessary.

2.3 Temporary Total Enclosure. The criteria for designing a TTE

are discussed in Procedure T.

3.  DETERMINATION OF VOLUMETRIC FLOW RATE OF FUGITIVE EMISSIONS

3.1 Locate all points where emissions are exhausted from the

TTE. Using Method 1, determine the sampling points. Be sure to

check each site for cyclonic or swirling flow.

3.2 MeasUre the velocity at each sampling site at least once

every hour during each sampling run using Method 2 or 2A.

4.  DETERMINATION OF VOGN CONTENT OF FUGITIVE EMISSIONS

4.1 Analysis Duration. Measure the VOGM responses at each

fugitive emission point during the entire test run or, if

applicable, while the process is operating. If there are

multiple emission locations, design a sampling system to allow a

single FIA to be used to determine the VOCN responses at all

sampling locations.

4.2 Gas 

VOGM

Concentration.

4.2.1 Assemble the sample train as shown in Figure 1. Calibrate

the FIA and conduct a system check according to the procedures in

Sections 5.1 and 5.3, respectively.

4.2.2 Install the sample probe so that the probe is centrally

located in the stack, pipe, or duct, and is sealed tightly at the

stack port connection.

4.2.3 Inject zero gas at the calibration valve assembly. Allow

the measurement system response to reach zero. Measure the

system response time as the time required for the system to reach

the effluent concentration after the calibration valve has been

returned to the effluent sampling position.

.4.2.4 Conduct a system check before and a system drift check

after each sampling run according to the procedures in Sections

5.2 and 5.3. If the drift check following a run indicates

unacceptable performance, the run is not valid. The tester may

595

elect to perform system drift checks during the run not to exceed

one drift check per hour.           

4.2.5 Verify that the sample lines, filter, and pump

temperatures are 120 ±5°C.

4.2.6 Begin sampling at the start of the test period and

continue to sample during the entire run. Record the starting

and ending times and any required process information as

appropriate. If multiple emission locations are sampled using a

single FIA, sample at each location for the same amount of time

(-e.g., 2 minutes) and continue to switch from one location to

another for the entire test run. Be sure that total sampling

time at each location is the same at the end of the test run.

Collect at least 4 separate measurements from each sample point

during each hour of testing. Disregard the response measurements

at each sampling location until two times the response time of

the measurement system has elapsed. Continue sampling for at

least 1 minute and record the concentration measurements.

4.3 Background Concentration.

4.3.1 Determination of VOGN Background Concentration.

4.3.1.1 Locate all NDO’s of the TTE. A sampling point shall be

centrally located outside of the TTE at 4 equivalent diameters

from each NDO, if possible. If there are more than 6 NDO’s,

choose 6 sampling points evenly spaced among the NDO’s.

4.3.1.2 Assemble the sample train as shown in Figure 2.

Calibrate the FIA and conduct a system check according to the

procedures in Sections 5.1 and 5.3.

4.3.1.3 Position the probe at the sampling location.

4.3.1.4 Determine the response time, conduct the system check

and sample according to the procedures described in Sections

4.2.3 to 4.2.6.

4.4 Alternative Procedure. The direct interface sampling and

analysis procedure described in Section 7.2 of Method 18 may be

used to determine the gas 

VOQ~concentration.

The system must be

designed to collect and analyze at least one sample every 10

minutes.

5.  CALIBRATION AND QUALITY ASSURANCE

5..  FIA Calibration and Linearity Check. Make necessary

adjustments to the air and fuel supplies for the FIA and ignite

the burner. Allow the FIA to warm up for the period recommended

by the manufacturer. Inject a calibration gas into the

measurement system and adjust the back—pressure regulator to the

596

value required to achieve the flow rates specified by the

manufacturer. Inject the zero- and the high-range calibration

gases and adjust the analyzer calibration to provide the proper

responses. Inject the low- and mid—range gases and record the

responses of the measurement system. The calibration and

linearity of the system are acceptable if the responses for all

four gases are within 5 percent of the respective gas values. If

the performance of the system is not acceptable, repair or adjust

the system and repeat the linearity check. Conduct a calibration

and linearity check after assembling the analysis system and

after a major change is made to the system.

5.2 Systems Drift Checks. Select the calibration gas

concentration that most closely approximates that of the fugitive

gas emissions to conduct the drift checks. Introduce the zero

and calibration gas at the calibration valve assembly and verify

that the appropriate gas flow rate and pressure are present at

the FIA. Record the measurement system responses to the zero and

calibration gases. The performance of the system is acceptable

if the difference between the drift check measurement and the

value obtained in Section 5.1 is less than 3 percent of the span

value. Conduct a system drift check at the end of each run.

5.3 System Check. Inject the high range calibration gas at the

inlet of the sampling probe and record the response. The

performance of the system is acceptable if the measurement system

response is within 5 percent of the value obtained in Section 5.1

for the high range calibration gas. Conduct a system check

before each test run.

54 Analysis Audit. Immediately before each test analyze an

audit cylinder as described in Section 5.2. The analysis audit

must agree with the audit cylinder concentration within 10

percent.

NOMENCLATURE

=

area of NDO i, ft-rj

AN

=

total area of all NDO’s in the enclosure, ft2-~

corrected average VOGM concentration of background

emissions at point i, ppm propane~j

C8

=

average background concentration, ppm propane-~

=

average measured concentration for the drift check

calibration gas, ppm propane~

C~

=

average system drift check concentration for zero

concentration gas, ppm propane--;

597

C~3

=

corrected average VOGN concentration of fugitive

emissions at point j, ppm propane~-j

CR

=

actual concentration of the drift check

calibration gas, ppm propane-a

C~

=

uncorrected average background VOG?~j concentration

measured at point i, ppm propane-a

=

uncorrected average 

VOG~concentration

measured at

point j, ppm propane-a

G

=

total VOG~Jcontent of captured emissions, kg--.~

K1

=

1.830 

x 10~ kg/(m3-ppm)-r.;

n

=

number of measurement points~

QF3

=

average effluent volumetric flow rate corrected to

standard conditions at fugitive emissions point j,

m3/min-rj

total duration of fugitive emissions sampling run,

mm.

7. CALCULATIONS

7.1 Total VOGN Fugitive Emissions.

n

F= Z (CFJ 

—

C8

)

Q~TF K1                    

Eq. 1

j=1

7.2 VOGM Concentration of the Fugitive Emissions at Point j.

CF3

=

(C3

C~)

C~

Eq. 2

C~

7.3 Background VOG~ Concentration at Point i.

C8,

=

(C1

C~)

CH

Eq. 3

CDH

C~

7.4 Average Background Concentration.

n

E C81 A~

CB

=

i=l

Eq. 5

598

NOTE: If the concentration at each point is within 20 percent of

the average concentration of all points, the terms “Ai” and “AN”

may be deleted from Equation 4.

Procedure L

VOG~Input

1. INTRODUCTION

1.1 Applicability. This procedure is applicable for determining

the input of volatile organic eompoundsmaterials (VOq~). It is

intended to be used as a segment in the development of liquid/gas

protocols for determining VOG?~capture efficiency (CE) for

surface coating and printing operations.

1.2 Principle. The amount of 

VOG~jintroduced

to the process

(L) is the sum of the products of the weight (W) of each VOGI~I

containing liquid (ink, paint, solvent, etc.) used and its VOGN

content (V). A sample of each 

VOGN

containing liquid is analyzed

with a flame ionization analyzer (FIA) to determine V.

1.3 Estimated Measurement Uncertainty. The measurement

uncertainties are estimated for each VOGI~containing liquid as

follows: W 

=

±2.0percent and V 

=

±12.0percent. Based on these

numbers, the probable uncertainty for L is estimated at about

±12.2percent for each 

VOG~containing

liquid. 1.4 Sampling

Requirements. A capture efficiency test shall consist of at

least three sampling runs. The sampling time for each run should

be at least 8 hours, unless otherwise approved.

1.5 Notes. Because this procedure is often applied in highly

explosive areas, caution and care should be exercised in choosing

appropriate equipment and installing and using the equipment.

Mention of trade names or company products does not constitute

endorsement. All gas concentrations (percent, ppm) are by

volume, unless otherwise noted.

2.  APPARATUS AND REAGENTS

2.1 Liquid Weight.

2.1.1 Balances/Digital Scales. To weigh drums of VOGN

containing liquids to within 0.2 lb.

2.1.2 Volume Measurement Apparatus (Alternative). Volume

meters, flow meters, density measurement equipment, etc., as

needed to achieve same accuracy as direct weight measurements.

2.2 VOGM Content (Flame Ionization Analyzer Technique). The

liquid sample analysis system is shown in Figures 1 and 2. The

following equipment is required:

599

2.2.1 Sample Collection Can. An appropriately sized metal can

to be used to collect 

voq~

containing materials. The can must be

constructed in such a way that it can be grounded to the coating

container.

2.2.2 Needle Valves,. To control gas flow.

2.2.3 Regulators. For carrier gas and calibration gas

cylinders.

2.2.4 Tubing. Teflon or stainless steel tubing with diameters

and lengths determined by connection requirements of equipment.

The tubing between the sample oven outlet and the FIA shall be

heated to maintain a temperature of 120 ±5°C.

2.2.5 Atmospheric Vent. A tee and 0- to 0.5-liter/mm rotameter

placed in the sampling line between the carrier gas cylinder and

the

VOG~sample

vessel to release the excess carrier gas. A

toggle valve placed between the tee and the rotameter facilitates

leak tests of the analysis system.

2.2.6 Thermometer. Capable of measuring the temperature of the

hot water bath to within 1°C.

2.2.7 Sample Oven. Heated enclosure, containing calibration gas

coil heaters, critical orifice, aspirator, and other liquid

sample analysis components, capable of maintaining a temperature

of 120 ±5°C.

2.2.8 Gas Coil Heaters. Sufficient lengths of stainless steel

or Teflon tubing to allow zero and calibration gases to be heated

to the sample oven temperature before entering the critical

orifice or aspirator.

2.2.9 Water Bath. Capable of heating and maintaining a sample

vessel temperature of 100 ±5°C.

2.2.10 Analytical Balance. To measure ±0.001 g.

2.2.11 Disposable Syringes. 2-cc or 5-cc.

2.2.12 Sample Vessel. Glass, 40—ml septum vial. A separate

vessel is needed for each sample.

2.2.13 Rubber Stopper. Two-hole stopper to accommodate 3.2—mm

(1/8-in.) Teflon tubing, appropriately sized to fit the opening

of the sample vessel. The rubber stopper should be wrapped in

Teflon tape to provide a tighter seal and to prevent any reaction

of the sample with the rubber stopper. Alternatively, any

leak—free closure fabricated of non—reactive materials and

accommodating the necessary tubing fittings may be used.

600

2.2.14 Critical Orifices. Calibrated critical orifices capable

of providing constant flow rates from 50 to 250 mi/mm at known

pressure drops. Sapphire orifice assemblies (available from

O’Keefe Controls Company) and glass capillary tubing have been

found to be adequate for this application.

2.2.15 Vacuum Gauge. 0- to 760-mm (0— to 30—in.) Hg U-Tube

manometer or vacuum gauge.

2.2.16 Pressure Gauge. Bourdon gauge capable of measuring the

maximum air pressure at the aspirator inlet (e.g., 100 psig).

2.2.17 Aspirator. A device capable of generating sufficient

vacuum at the sample vessel to create critical flow through the

calibrated orifice when sufficient air pressure is present at the

aspirator inlet. The aspirator must also provide sufficient

sample pressure to operate the FIA. The sample is also mixed

with the dilution gas within the aspirator. 

2.2.18 Soap Bubble Meter. Of an appropriate size to calibrate

the critical orifices in the system.

2.2.19 Organic Concentration Analyzer. An FIA with a span value

of 1.5 times the expected concentration as propane; however other

span values may be used if it can be demonstrated that they would

provide more accurate measurements. The system shall be capable

-of meeting or exceeding the following specifications:

2.2.19.1 Zero Drift. Less than ±3.0percent of the span value.

2.2.19.2 Calibration Drift. Less than ±3.0percent of span

value.

2.2.19.3 Calibration Error. Less than ±5.0percent of the

calibration gas value.

2.2.20 Integrator/Data Acquisition System. An analog or digital

device or computerized data acquisition system used to integrate

the FIA response or compute the average response and record

measurement data. The minimum data sampling frequency for

computing average or integrated values is one measurement value

every 5 seconds. The device shall be capable of recording

average values at least once per minute.

2.2.21 Chart Recorder (optional). A chart recorder or similar

device is recommended to provide a continuous analog display of

the measurement results during the liquid sample analysis.

2.2.22 Calibration and Other Gases. For calibration, fuel, and

combustion air (if required) contained in compressed gas

cylinders. All calibration gases shall be traceable to NIST

standards and shall be certified by the manufacturer to ±1

601

percent of the tag value. Additionally, the manufacturer of the

cylinder should provide a recommended shelf-life for each

calibration gas cylinder over which the concentration does nor

change more than ±2percent from the certified value. For

calibration gas values not generally available, alternative

methods for preparing calibration gas mixtures, such as dilution

systems, may be used with prior approval.

2.2.22.1 Fuel. A 40 percent H2/60 percent He or 40 percent H2/60

percent N2 gas mixture is recommended to avoid an oxygen

synergism effect that reportedly occurs when oxygen concentration

varies significantly from a mean value.

2.2.22.2

Carrier Gas. High purity air with less than 1 ppm of

organic material (as propane) or less than 0.1 percent of the

span value, whichever is greater.

2.2.22.3 FIA Linearity Calibration Gases. Low-, mid-, and

high-range gas mixture standards with nominal propane

concentrations of 20-30, 45-55, and 70-80 percent of the span

value in air, respectively. Other calibration values and other

span values may be used if it can be shown that more accurate

measurements would be achieved.

2.2.22.4 System Calibration Gas. Gas mixture standard

containing propane in air, approximating the undiluted VOGN

concentration expected for the liquid samples.

3.  DETERMINATION OF LIQUID INPUT WEIGHT

3.1 Weight Difference. Determine the amount of material

introduced to the process as the weight difference of the feed

material before and after each sampling run. In determining the

total 

VOGL~

containing liquid usage, account for: (a) the initial

(beginning) VOG~containing liquid mixture; (b) any solvent added

during the test run; (c) any coating added during the test run;

and (d) any residual VOGN containing liquid mixture remaining at

the end of the sample run.

3.1.1 Identify all points where 

VOGN

containing liquids are

introduced to the process. To obtain an accurate measurement of

VOG?j

containing liquids, start with an empty fountain (if

applicable). After completing the run, drain the liquid in the

fountain back into the liquid drum (if possible), and weigh the

drum again. Weigh the VOG?,j containing liquids to ±0.5percent of

the total weight (full) or ±0.1percent of the total weight of

VOG~containing

liquid used during the sample run, whichever is

less. If the residual liquid cannot be returned to the drum,

drain the fountain into a preweighed empty drum to determine the

final weight of the liquid.

602

3.1.2 If it is not possible to measure a single representative

mixture, then weigh the various components separately (e.g.,

if

solvent is added during the sampling run, weigh the solvent

before it

is added to the mixture). If a fresh drum of VOGM

containing liquid is needed during the run, then weigh both the

empty drum and fresh drum.

3.2 Volume Measurement (Alternative).

If direct weight

measurements are not feasible, the tester may use volume meters

and flow rate meters (and density measurements) to determine the

weight of liquids used if it can be demonstrated that the

technique produces results equivalent to the direct weight

measurements.

If a single representative mixture cannot be

measured, measure the components separately.

4.  DETERMINATION OF 

VOG~1CONTENT

IN INPUT LIQUIDS

4.1 Collection of Liquid Samples.

4.1.1 Collect a 100-mi or larger sample of the 

VOG~containing

liquid mixture at each application location at the beginning and

end of each test run. A separate sample should be taken of each

VOq~containing

liquid added to the application mixture during

the test run. If a fresh drum is needed during the sampling run,

then obtain a sample from the fresh drum.

4.1.2 When collecting the sample, ground the sample container to

the coating drum. Fill the sample container as close to the rim

as possible to minimize the amount of headspace.

4.1.3 After the sample is collected, seal the container so the

sample cannot leak out or evaporate.

4.1.4 Label the container to identify clearly the contents.

4.2 Liquid Sample 

VO~~Content.

4.2.1 Assemble the liquid 

VOG~content

analysis system as shown

in Figure 1.

4.2.2 Permanently identify all of the critical orifices that may

be used. Calibrate each critical orifice under the expected

operating conditions (i.e., sample vacuum and temperature)

against a volume meter as described in Section 5.3.

4.2.3 Label and tare the sample vessels (including the stoppers

and caps) and the syringes.

4.2.4 Install an empty sample vessel and perform a leak test of

the system. Close the carrier gas valve and atmospheric vent and

evacuate the sample vessel to 250 mm (10 in.) Hg absolute or less

using the aspirator. Close the toggle valve at the inlet to the

603

aspirator and observe the vacuum for at least one minute. If

there is any change in the sample pressure, release the vacuum,

adjust or repair the apparatus as necessary and repeat the leak

test.

4.2.5 Perform the analyzer calibration and linearity checks

according to the procedure in Section 5.1. Record the responses

to each of the calibration gases and the back—pressure setting of

the FIA.

4.2.6 Establish the appropriate dilution ratio by adjusting the

aspirator air supply or substituting critical orifices.

Operate

the aspirator at a vacuum of at least 25 mm (1 in.) Hg greater

than the vacuum necessary to achieve critical flow. Select the

dilution ratio so that the maximum response of the FIA to the

sample does not exceed the high-range calibration gas.

4.2.7 Perform system calibration checks at two levels by

introducing compressed gases at the inlet to the sample vessel

while the aspirator and dilution devices are operating. Perform

these checks using the carrier gas (zero concentration) and the

system calibration gas. If the response to the carrier gas

exceeds ±0.5percent of span, clean or repair the apparatus and

repeat the check. Adjust the dilution ratio as necessary to

achieve the correct response to the upscale check, but do not

adjust the analyzer calibration. Record the identification of

the orifice, aspirator air supply pressure, FIA back-pressure,

and the responses of the FIA to the carrier and system

calibration gases.

4.2.8 After completing the above checks, inject the system

calibration gas for approximately 10 minutes. Time the exact

duration of the gas injection using a stopwatch. Determine the

area under the FIA response curve and calculate the system

response factor based on the sample gas flow rate, gas

concentration, and the duration of the injection as compared to

the integrated response using Equations 2 and 3.

4.2.9 Verify that the sample oven and sample line temperatures

are 120 ±5°Cand that the water bath temperature is 100 ±5°C.

4.2.10 Fill a tared syringe with approximately 1 g of the 

VOG~

containing liquid and weigh it. Transfer the liquid to a tared

sample vessel. Plug the sample vessel to minimize sample loss.

Weigh the sample vessel containing the liquid to determine the

amount of sample actually received. Also, as a quality control

check, weigh the empty syringe to determine the amount of

material delivered. The two coating sample weights should agree

within ±0.02g. If not, repeat the procedure until an acceptable

sample is obtained.

604

4.2.11 Connect the vessel to the analysis system. Adjust the

aspirator supply pressure to the correct value. Open the valve

on the carrier gas supply to the sample vessel and adjust it to

provide a slight excess flow to the atmospheric vent. As soon as

the initial response of the FIA begins to decrease, immerse the

sample vessel in the water bath.

(Applying heat to the sample

vessel too soon may cause the FID response to exceed the

calibrated range of the instrument, and thus invalidate the

analysis.)

4.2.12 Continuously measure and record the response of the FIA

until all of the volatile material has been evaporated from the

sample and the instrument response has returned

to the baseline

(i.e., response less than 0.5 percent of the span value).

Observe the aspirator supply pressure, FIA back—pressure,

atmospheric vent, and other system operating parameters during

the run; repeat the analysis procedure if any of these parameters

deviate from the values established during the system calibration

checks in Section 4.2.7. After each sample perform the drift

check described in Section 5.2. If the drift check results are

acceptable, calculate the 

VOG~jcontent

of the sample using the

equations in Section 7. Integrate the area under the FIA

response curve, or determine the average concentration response

and the duration of sample analysis.

5.  CALIBRATION AND QUALITY ASSURANCE

5.1 FIA Calibration and Linearity Check. Make necessary

adjustments to the air and fuel supplies for the FIA and ignite

the burner. Allow the FIA to warm up for the period recommended

by the manufacturer. Inject a calibration gas into the

measurement system and adjust the back-pressure regulator to the

value required to achieve the flow rates specified by the

manufacturer. Inject the zero- and the high—range calibration

gases and adjust the analyzer calibration to provide the proper

responses. Inject the low- and mid—range gases and record the

responses of the measurement system. The calibration and

linearity of the system are acceptable if the responses for all

four gases are within 5 percent of the respective gas values. If

the performance of the system is not acceptable, repair or adjust

the system and repeat the linearity check. Conduct a calibration

and linearity check after assembling the analysis system and

after a major change is made to the system.

5.2 Systems Drift Checks. After each sample, repeat the system

calibration checks in Section 4.2.7 before any adjustments to the

FIA or measurement system are made. If the zero or calibration

drift exceeds ±3percent of the span value, discard the result

and repeat the analysis.

5.3 Critical Orifice Calibration.

605

5.3.1 Each critical orifice must be calibrated at the specific

operating conditions that it will be used. Therefore, assemble

all components of the liquid sample analysis system as shown in

Figure 3. A stopwatch is also required.

5.3.2 Turn on the sample oven, sample line, and water bath

heaters and allow the system to reach the proper operating

temperature. Adjust the aspirator to a vacuum of 380 mm (15 in.)

Hg vacuum. Measure the time required for one soap bubble to move

a known distance and record barometric pressure.

5.3.3 Repeat the calibration procedure at a vacuum of 406 mm (16

in.) Hg and at 25-mm (1-in.) Hg intervals until three consecutive

determinations provide the same flow rate. Calculate the

critical flow rate for the orifice in mi/mm at standard

conditions. Record the vacuum necessary to achieve critical

flow.

6.  NOMENCLATURE

AL

=

area under the response curve of the liquid

sample, area count--i

area under the response curve of the calibration

gas, area count-~j

C~

=

actual concentration of system calibration gas,

ppm propane~-;~

K

=

1.830 

x 10~ g/(ml-ppm)-~

L

=

total VOGU content of liquid input, kg--~.

=

mass of liquid sample delivered to the sample

vessel, g-rj

q

=

flow rate through critical orifice, ml/min-~

RF

=

liquid analysis system response factor, g/area

count,-~

T~

=

total gas injection time for system calibration

gas during integrator calibration, min~-j

VFJ

=

final 

VOG~fraction

of VOGN containing liquid j--~

V1~  = initial VOGM fraction of 

VOGN

containing liquid

J~L

VAJ  =  VOGM fraction of 

VOGN

containing liquid j added

during the run~-~

606

V

=

VOG!j

fraction of liquid sample--;

W~ =  weight of 

VOG~containing

liquid j remaining at

end of the run, kg-rj..

W~ =  weight of VOG?~containing liquid j at beginning of

the run, kg-ri

=

weight of 

VOG!j

containing liquid j added during

the run, kg.

7.  CALCULATIONS

7.1 Total 

VOGN

Content of the Input 

VOG~Containing

Liquid.

n

nn

L

=

E Vb W13 

=

VFJ WFJ +  

E V~WAJ 

R

Eq. 1

j=l

j=1

j=1

7.2 Liquid Sample Analysis System Response Factor for Systems

Using Integrators, Grams/Area Counts.

Eq. 2

7.3

VOG~Content

of the Liquid Sample.

V =

Eq. 3

ML

Procedure T 

Criteria for and Verification of a Permanent or

Temporary Total Enclosure

1.  INTRODUCTION

1.1 Applicability. This procedure is used to determine whether

a permanent or temporary enclosure meets the criteria of a total

enclosure.

1.2 Principle. An enclosure is evaluated against a set of

criteria. If the criteria are met and if all the exhaust gases

are ducted to a control device, then the volatile organic

cornpoundsmaterials (VOGM) capture efficiency (CE) 

is assumed to

be 100 percent and CE need not be measured. However, if part of

the exhaust gas stream is not ducted to a control device, CE must

be determined.

2.  DEFINITIONS

2.1 Natural Draft Opening (NDO) 

Any permanent opening in the

enclosure that remains open during operation of the -f-acility

607

emission unit and is not connected to a duct in which a fan is

installed.

2.2 Permanent Total Enclosure (PTE) 

—-

A permanently installed

enclosure that completely surrounds a~ oouroc of emissionsunit

such that all 

VOG~Jemissions

are captured and contained for

discharge through a control device.

2.3 Temporary Total Enclosure (TTE)

A temporarily installed

enclosure that completely surrounds a~oourac of emissioneunit

such that all 

VOGN

emissions are captured and contained for

discharge through ducts that allow for the accurate measurement

of VOGM rates.

3.  CRITERIA OF A 

TEMPORARY

TOTAL ENCLOSURE

3.1 Any NDO shall be at least 4 equivalent opening diameters

from each 

VOG~emitting

point.

3.2 Any exhaust point from the enclosure shall be at least 4

equivalent duct or hood diameters from each NDO.

3.3 The total area of all NDO’s shall not exceed 5 percent of

the surface area of the enclosure’s four walls, floor, and

ceiling.

3.4 The average facial velocity (FV) of air through all NDO’s

shall be at least 3,600 m/hr (200 fpm). The direction of air

through all NDO’s shall be into the enclosure.

3.5 All access doors and windows whose areas are not included in

Section 3.3 and are not included in the calculation in Section

3.4 shall be closed during routine operation of the

proccD~etnissionunit.

4.  CRITERIA OF A PERMANENT TOTAL ENCLOSURE

4.1 Same as Sections 3.1 and 3.3 

3.5.

4.2 All VO?~.jemissions must be captured and contained for

discharge through a control device.

5.  PROCEDURE

5.1 Determine the equivalent diameters of the NDO’s and

determine the distances from each 

VOG~1emitting

point to all

NDO’s. Determine the equivalent diameter of each exhaust duct or

hood and its distance to all NDO’s. Calculate the distances in

terms of equivalent diameters. The number of equivalent

diameters shall be at least 4.

608

5.2 Measure the total area (A1) of the enclosure and the total

area (AN) of all NDO’s of the enclosure. Calculate the NDO to

enclosure area ratio (NEAR) as follows:

NEAR 

=

The NEAR must be 0.05.

5.3 Measure the volumetric flow rate, corrected to standard

conditions, of each gas stream exiting the enclosure through an

exhaust duct or hood using

EPA Method 2. In some cases (e.g.,

when the building is the enclosure), it may 

be necessary to

measure the volumetric flow rate, corrected to standard

conditions, of each gas stream entering the enclosure through a

forced makeup air duct using Method 2. Calculate FV using the

following equation:

FV

=

(Q,~ 

—

Q~)/AN

where:

Q0

=

the sum of the volumetric flow from all gas

streams exiting the enclosure through an exhaust

duct or hood.

Q1

=

the sum of the volumetric flow from all gas

streams into the enclosure through a forced makeup

air duct; zero, if there is no forced makeup air

into the enclosure.

AN =  total area of all NDO’s in enclosure.

The FV shall be at least 3,600 m/hr (200 fpm).

5.4 Verify that the direction of air flow through all NDO’s is

inward. Use streamers, smoke tubes, tracer gases, etc. Strips

of plastic wrapping film have been found to be effective.

Monitor the direction of air flow at intervals of at least 10

minutes for at least 1 hour.

6.

QUALITY 

ASSURANCE

6.1 The success of this protocol lies in designing the TTE to

simulate the conditions that exist without the TTE, i.e., the

effect of the TTE on the normal flow patterns around the affected

facilityemission unit or the amount of fugitive 

VOGM

emissions

should be minimal. The TTE must enclose the application

stations, coating reservoirs, and all areas from the application

station to the oven. The oven does not have to be enclosed if it

is under negative pressure. The NDO’s of the temporary enclosure

and a fugitive exhaust fan must be properly sized and placed.

609

6.2. Estimate the ventilation rate of the TTE that best

simulates the conditions that exist without the TTE, i.e., the

effect of the TTE on the normal flow patterns around the affected

f-acilityeinission unit or the amount of fugitive 

VOG~jemissions

should be minimal. Figure 1 may be used as an aid. Measure the

concentration (C0) and flow rate (Q0) of the captured gas stream,

specify a safe concentration (CF) for the fugitive gas stream,

estimate the CE, and then use the plot in Figure 1 to determine

the volumetric flowrate of the fugitive gas stream (QF)• A

fugitive 

VOG?j

emission exhaust fan that has a variable flow

control is desirable.

6.2.1 Monitor the concentration of VOG~into the capture device

without the TTE. To minimize the effect of temporal variation on

the captured emissions, the baseline measurement should be made

over as long a time period as practical. However, the process

conditions must be the same for the measurement in Section 6.2.3

as they are for this baseline measurement. This may require

short measuring times for this quality control check before and

after the construction of the TTE.

6.2.2 After the TTE is constructed, monitor the 

VOGN

concentration inside the TTE. This concentration shall not

continue to increase and must not exceed the safe level according

to OSHA requirements for permissible exposure limits. An

increase in VOGN concentration indicates poor TTE design or poor

capture efficiency.

6.2.3 Monitor the concentration of VOGN into the capture device

with the TTE. To limit the effect of the TTE on the process, the

VOGM

concentration with and without the TTE must be within ±10

percent. If the measurements do not agree, adjust the

ventilation rate from the TTE until they agree within 10 percent.

(Source: Amended at —  Ill. Reg. 

______,

effective 

____________

610

Section 219.Appendix C

Reference Test Methods on-cl Proccdurcafor Air Oxidation Processes

Introduction

This Appendix presents the reference

methods and procedures

required for implementing Reasonably Available

Control Technology

(RACT). Methods and procedures are

identified for two types of

RACT

implementation:

a)  Determination of VOGN destruction efficiency for evaluating

compliance with the 98 weight percent VOGi~reduction or 20

ppmv emission limit specified in Sections 215.520 through

215.527; and

b)  Determination of of fgas flowrate, hourly emissions and

stream net heating value for calculating TRE.

All reference methods identified in this Appendix refer to the

reference methods specified at 40 CFR 60, Appendix A,

incorporated by reference in Section 215.105.

VOGN DESTRUCTION EFFICIENCY DETERMINATION

The following reference methods and procedures are required for

determining compliance with the percent destruction efficiency

specified in Sections 215.520 through 215.527.

a)  Reference Method 1 or 1A for selection of the sampling site.

The control device inlet sampling site for determination of

vent stream molar composition or total organic compound

destruction efficiency shall be prior to the inlet of any

control device and after all recovery devices.

b)  Reference Methods 2, 2A, 2C or 2D for determination of the

volumetric flowrate.

c)  Reference Method 3 to measure oxygen concentration of the

air dilution correction. The emission sample shall be

corrected to 3 percent oxygen.

d)  Reference Method 18 to determine the concentration of total

organic compounds (minus methane and ethane) in the control

device outlet and total organic compound reduction

efficiency of the control device.

TRE DETERMINATION

The following reference methods and procedures are required for

determining the offgas flowrate, hourly emissions, and the net

heating value of the gas combusted to calculate the vent stream

TRE.

611

a)  Reference Method 1 or 1A for selection of the sampling site.

The sampling site for the vent stream flowrate and molar

composition determination prescribed in (b) and (c) shall be

prior to the inlet of any combustion device, prior to any

post-reactor dilution of the stream with air and prior to

any post-reactor introduction of halogenated compounds into

the vent stream. Subject to the preceding restrictions on

the sampling site, it shall be after the final recovery

device. If any gas stream other than the air oxidation vent

stream is normally conducted through the recovery system of

the affected facility, such stream shall be rerouted or

turned off while the vent stream is sampled, but shall be

routed normally prior

to the measuring of the initial value

of the monitored parameters for determining compliance with

the recommended 

RACT.

If the air oxidation vent stream is

normally routed through any equipment which is not a part of

the air oxidation process as defined in 35 Ill. Adm. Code

211.122, such equipment shall be bypassed by the vent stream

while the vent stream is sampled, but shall not be bypassed

during the measurement of the initial value of the monitored

parameters for determining compliance with Subpart V.

b)  The molar composition of the vent stream shall be determined

using the following methods:

1)  Reference Method 18 to measure the concentration of all

organics, including those containing halogens, unless a

significant portion of the compounds of interest are

polymeric (high molecular weight), can polymerize

before analysis or have low vapor pressures, in which

case Reference Method 25(a) shall be used.

2)  ASTM Dl946—67 (reapproved 1977), incorporated by

reference in Section 215.105, to measure the

concentration of carbon monoxide and hydrogen.

3)  Reference Method 4 to measure the content of water

vapor, if necessary.

c)  The volumetric flowrate shall be determined using Reference

Method 2, 2A, 2C or 2D, as appropriate.

d)  The net heating value of the vent stream shall be calculated

using the following equation:

n

H=K E CiHi

i=1

Where:

612

H

=

Net heating value of the sample, NJ/scm, where the

net enthalpy per mole of offgas is based on

combustion at 25°Cand 760 mm Hg, but the standard

temperature for determining the volume

corresponding to one mole is 20°C, as in the

definition of F (vent stream flowrate) below.

K  =  Constant, 1.740 x ~ (1/ppm) (mole/scm) (MJ/kcal)

where standard temperature for mole/scm is 20°C.

Ci

=

Concentration of sample component i, reported on a

wet basis, in ppm, as measured by Reference Method

18 or ASTM D1946-67 (reapproved 1977),

incorporated by reference in Section 215.105.

Hi

=

Net heat of combustion of sample component i,

kcal/xnole based on combustion at 25~Cand 760 mm

Hg. If published values are not available or

cannot be calculated, the heats of combustion of

vent stream components are required to be

determined using ASTM D2382-76, incorporated by

reference in Section 215.105.

e)  The emission rate of total organic compounds in the process

vent stream shall be calculated using the following

equation:

n

E=K F ~ CiMi

i1

Where:

E

=

Emission rate of total organic compounds (minus

methane and ethane) in the sample in kg/hr-i-;

K

=

Constant 2.494 x 10~(1/ppm) (mole/scm) (kg/g)

(mm/hr)1 where standard temperature for

(mole/scm) is 20°C~-;

Mi

=

Molecular weight of sample component i (g/mole),-;

F  =  Vent stream flowrate (scm/mm), at a standard

temperature of 20°C.

f)  The total vent stream concentration (by volume) of compounds

containing halogens (ppmv, by compound) shall be summed from

the individual concentrations of compounds containing

halogens which were measured by Reference Method l8~

613

(Source: Amended at 

—

Ill. Reg.    

,  effective

_________________________)

614

Section 219.Appendix D

Coefficients for the Total Resource Effectiveness Index (TRE)

Equation

This Appendix contains values for the total resource

effectiveness index (TRE) equation in Subpart V.

If a flow rate falls exactly on the boundary between the

indicated ranges, the operator shall use the row in which the

flow rate is maximum.

COEFFICIENTS FOR TRE EQUATION FOR CHLORINATED PROCESS

VENT STREAMS WITH

NET HEATING VALUE LESS ThAN OR EQUAL TO 3.5 NJ/scm

FLOW RATE

(scm/mm)

Mm. Max.  

a

b

c

d

e

f

0.0 13.5 48.73 0.   

0.404 —0.1632 0.   

0.

13.5 700.  42.35 0.624 0.404 —0.1632 0.    

0.0245

700. 1400.  84.38 0.678 0.404 —0.1632 0.   

0.0346

1400. 2100.  126.41 0.712 0.404 —0.1632 0.   

0.0424

2100. 2800.  168.44 0.747 0.404 —0.1632 0.   

0.0490

2800. 3500. 210.47 0.758 0.404 —0.1632 0.   

0.0548

COEFFICIENTS FOR TRE EQUATION FOR CHLORINATED PROCESS

VENT STREAMS WITH

NET HEATING VALUE GREATER THAN 3.5 NJ/scm

FLOW RATE

(scm/mm)

Mm. Max.  

a

b

c

d

e

f

0.

13.5 47.76 0.   

—0.292 0.     

0.

0.

13.5 700.  41.58 0.605 —0.292 0.     

0.

0.0245

700. 1400.  

82.84 0.658 —0.292 0.     

0.

0.0346

1400. 2100.  123.10 0.691 —0.292 0.     

0.

0.0424

2100. 2800.  165.36 0.715 —0.292 0.     

0.

0.0490

2800. 3500. 206.62 0.734 —0.292 0.     

0.

0.0548

COEFFICIENTS FOR TRE EQUATION FOR NONCHLORINATED PROCESS

VENT STREAMS WITH

NET HEATING VALUE LESS THAN OR EQUAL TO 0.48 NJ/scm

FLOW RATE

(scm

mi n)

Mm.Max.  

a

b

c

d

e

f

0.

13.5 19.05 0.   

0.113 —0.214  

0.-

0.

13.5 1350.  16.61 0.239 0.113 —0.214  0.   

0.0245

1350. 2700.  32.91 0.260 0.113 —0.214  0.    

0.0346

2700. 4050.  49.21 0.273 0.113 —0.214  0.    

0.0424

COEFFICIENTS FOR TRE EQUATION FOR NONCHLORINATED PROCESS

615

VENT STREAMS

WITH NET HEATING VALUE GREATER THAN 0.48 AND LESS THAN OR

EQUAL TO 1.9 NJ/scm

FLOW RATE

(scm/mm)

Mm. Max.  

a

b

c

d

e

f

0.

13.5 19.74 0.   

0.400 —0.202  0.   

0.

13.5 1350.  18.30 0.138 0.400 —0.202  0.   

0.0245

1350. 2700.  36.28 0.150 0.400 —0.202  0.   

0.0346

2700. 4050.  54.26 0.158 0.400 —0.202  0.   

0.0424

COEFFICIENTS FOR TRE EQUATION FOR NONCHLORINATED PROCESS

VENT STREAMS

WITH NET HEATING VALUE GREATER THAN 1.9 AND LESS THAN OR

EQUAL TO 3.6 NJ/scm

FLOW RATE

(scm/mm)

Mm.Max.   

a

b

c  d     

e

f

.0  13.5 15.24 0.   

0.033 0.     

0.

0.

13.5 1190.  

13.63 0.157 0.033 0.     

0.

0.0245

1190. 2380.  

26.95 0.171 0.033 0.    

0.

0.0346

2380. 3570.  

40.27 0.179 0.033 0.    

0.

0.0424

COEFFICIENTS FOR TRE EQUATION FOR NONCHLORINATED PROCESS

VENT STREAMS WITH

NET HEATING VALUE GREATER 

THAN

3.6 MG/scm

FLOW RATE

(scm/mm)

Mm. Max.   

a

b  c     

d

e

f

0.

13.5 15.24 0.  0.   

0.0090  0.     

0.

13.5 1190.  

13.63 0.  0.   

0.0090  0.0503  0.0245

1190. 2380.  

26.95 0.  0.   

0.0090  0.0546 0.0346

2380. 3570.  40.27 0.  0.   

0.0090  0.0573  0.0424

(Source: Amended at —  Ill. Reg. 

______,

effective

)