ILLINOIS POLLUTION CONTROL BOARD
    September
    15,
    1994
    IN THE MATTER OF:
    )
    )
    Amendments to 35
    Iii.
    Adin.
    )
    Code 302.302,
    302.208, 302.212
    )
    R94—1
    302.213,
    302.407, 304.122 and
    )
    (Rulemaking)
    304.301
    (Ammonia Nitrogen, Lead
    )
    and Mercury)
    )
    Proposed Rule
    First Notice
    OPINION
    AND
    ORDER OF THE BOARD
    (by E.
    Dunham,
    C.
    A. Manning and
    R.
    C.
    Flemal)
    On February 24,
    1994, the Illinois Environmental Protection
    Agency
    (Agency)
    filed a regulatory proposal as part of its
    mandatory review of the applicable water quality standards of the
    State of Illinois pursuant to 33 U.S.C.
    §~
    1251—1387
    (1987).’
    The Agency filed the proposal pursuant to Section 27 of the
    Environmental Protection Act
    (Act)
    and the Board’s procedural
    rules at 35
    Ill.
    Adm. Code
    §~
    102.120 and 102.121.2
    (415 ILCS
    5/27
    (1992).)
    Pursuant to Section 28.2 of the Act and the
    Board’s procedural rules at
    35 Ill. Adm. Code
    §
    102.121(e) the
    Agency certified that the proposed rulemaking is needed to
    fulfill the requirements of the Federal Clean Water Act and
    therefore was federally required.
    (415 ILCS 5/28.2
    (1992).)
    However, the Agency only certified to part of the proposed
    rulemaking and did not include a written confirmation letter from
    the United States Environmental Protection Agency
    (U.S.
    EPA).
    Based on the Agency’s proposal and certification, the Board on
    March 17,
    1994, rejected that the rulemaking was federally
    required.
    The Agency filed a motion to reconsider that
    determination on April
    11,
    1994.
    In its motion for
    reconsideration,
    the Agency stated that the entire rulemaking is
    federally required.
    Additionally, the Agency attached the
    confirmation letter from U.S. EPA Region V stating that the
    proposed changes for the ammonia, mercury and lead standards
    ‘The Federal Water Pollution Control Act commonly know as
    the Clean Water Act
    (CWA)
    §~
    101-607 requires the Agency to
    periodically, but at least every three years,
    review the water
    quality standards applicable in that State.
    The Agency refers to
    this as the “Triennial Review.”
    2The Agency is proposing to amend 35 Ill. Adm. Code
    §~
    302.302,
    302.208,
    302.212, 302.407,
    304.122 and 304.301 to update
    the ammonia nitrogen, mercury and lead general water quality
    standards,
    secondary contact and indigenous aquatic life
    standards and other applicable regulations.
    In addition, the
    Agency is proposing to add a new section 35 Ill. Adm. Code
    302.213 entitled “Effluent Modified Waters.”

    2
    would address the inconsistencies of the current State law to the
    Federal Water Pollution Control Act (FWPCA)
    .~
    (33 U.S.C.
    §1313(c) (2) (A)
    and §1313(c) (2) (b).)
    The confirmation letter also
    states that the proposal would be consistent with the FWPCA and
    federal regulations.
    On May 5,
    1994,
    the Board granted the
    Agency motion for reconsideration and accepted the Agency
    proposal as
    a federally required rule pursuant to Section 28.2 of
    the Act.
    Today the Board sends this proposal to first notice,
    as
    required by Section 5.01 of the Illinois Administrative Procedure
    Act.
    (415 ILCS 100/1005-40).
    The Board takes this action without
    ruling on the merit of the proposal and takes no position
    regarding the substance of the proposal.
    The proposal is
    submitted for publication as filed by the Agency.
    The Board has
    made only minor nonsubstantive changes to the rules in order to
    conform to Illinois Administrative Procedure Act and
    Administrative Code Unit requirements and correct errors.
    The
    Board emphasizes that in sending this proposal to first notice at
    this time will maximize the opportunity for public comment on the
    proposal.
    Additionally, the Board has already stated that it
    places a very high priority on the quick resolution of this
    rulemaking.
    Beginning the statutorily-required first notice
    period at this time will allow for the most expeditious
    resolution of the proceeding.
    The Board’s responsibility in this matter arises from the
    Environmental Protection Act.
    The Board is charged therein to
    “determine, define, and implement the environmental control
    standards applicable in the state of Illinois.”
    (415 ILCS 5/5(b)
    (1992).)
    More generally,
    the Board’s rulemaking charge is based
    on the system of checks and balances integral to the Illinois
    environmental governance:
    the Board bears responsibility for the
    rulemaking and principal adjudicatory functions; while the Agency
    has primary responsibility for administration of the Act and the
    Board’s regulations.
    The latter includes administering today’s
    new regulation.
    BACKGROUND
    This rulemaking is proposing to modify the standards for
    total ammonia nitrogen,
    lead and mercury standards.
    The proposed
    revised ammonia nitrogen,
    lead and mercury standards are a
    follow-up to the establishment of toxics control water quality
    standard proposed in ProPosed Amendments to Title 35 Subtitle C
    (Toxics Control), R88-2l.
    The Agency also considered the
    treatment abilities of wastewater treatment plants during the
    winter months in determining the modified nitrogen standard.
    (See
    3The FWPCA is also know as the Clean Water Act(CWA).
    (40
    C.F.R.
    §131.11(a) (1) and
    (2).)

    3
    Amendment to 35
    Ill.
    Adm. Code Section 304.301, Exception for
    Ammonia Nitrogen Water quality Violations, R88—22.)
    In this proposal, the Agency also corrects the STORET number
    in 35 Ill.
    Adm. Code 302.407.
    The correct STORET number for un-
    ionized ammonia
    (as N)
    is 00612.
    The Agency also amends the
    effluent standard in 35 Ill. Adm. Code 304.122.
    The Agency
    recognizes an inherent relationship between water quality
    standard and effluent limitations.
    ORDER
    The Board directs the Clerk to cause publication of the
    following amendments in the Illinois Register for first notice:
    TITLE 35:
    ENVIRONMENTAL PROTECTION
    SUBTITLE C:
    WATER POLLUTION
    CHAPTER
    I:
    POLLUTION CONTROL BOARD
    PART 302
    WATER QUALITY STANDARDS
    SUBPART A:
    GENERAL WATER QUALITY PROVISIONS
    Section
    302.100
    302.101
    302.102
    302.103
    302
    .
    104
    302.105
    Section
    302.201
    302.202
    302 .203
    302.204
    302 .205
    302 .206
    302.207
    302.208
    302.210
    302.211
    302 .212
    302.213
    Definitions
    Scope and Applicability
    Allowed Mixing, Mixing Zones and ZIDs
    Stream Flows
    Main River Temperatures
    Nondegradation
    SUBPART
    B:
    GENERAL USE WATER
    QUALITY STANDARDS
    Scope and Applicability
    Purpose
    Offensive Conditions
    pH
    Phosphorus
    Dissolved Oxygen
    Radioactivity
    Numeric Standards for Chemical Constituents
    Other Toxic Substances
    Temperature
    Ammonia Nitrogen and Un-ionized Ammonia
    Effluent Modified Waters
    (Ammonia)

    4
    SUBPART
    C:
    PUBLIC AND FOOD
    PROCESSING WATER SUPPLY STANDARDS
    Section
    302.301
    302.302
    302.303
    302.304
    302.305
    302.306
    Section
    302.401
    302 .402
    302.403
    302.404
    302.405
    302.406
    302.407
    302.408
    302.409
    302.410
    Scope and Applicability
    Algicide Permits
    Finished Water Standards
    Chemical Constituents
    Other Contaminants
    Fecal Coliform
    SUBPART
    D:
    SECONDARY CONTACT
    AND
    INDIGENOUS AQUATIC LIFE STANDARDS
    Scope and Applicability
    Purpose
    Unnatural Sludge
    pH
    Dissolved Oxygen
    Fecal Coliform (Repealed)
    Chemical Constituents
    Temperature
    Cyanide
    Substances Toxic to Aquatic Life
    SUBPART E:
    LAKE MICHIGAN WATER
    QUALITY STANDARDS
    Scope and Applicability
    Dissolved Oxygen
    pH
    Chemical Constituents
    Fecal Coliform
    Temperature
    Existing Sources on January
    1,
    1971
    Sources
    under
    Construction
    But
    Not
    in
    Operation
    on
    January
    1,
    1971
    302.509
    Other Sources
    SUBPART F:
    PROCEDURES FOR
    DETERMINING WATER QUALITY CRITERIA
    Scope and Applicability
    Definitions
    Mathematical Abbreviations
    Data Requirements
    Determining the Acute Aquatic Toxicity Criterion for an
    Individual Substance
    General Procedures
    302.615
    Determining
    the
    Acute
    Aquatic
    Toxicity
    Criterion
    -
    Section
    302.501
    302
    .
    502
    302.503
    302.504
    302.505
    302.506
    302.507
    302.508
    Section
    302.601
    302.603
    302.604
    302.606
    302.612

    5
    Toxicity Independent of Water Chemistry
    302.618
    Determining
    the
    Acute
    Aquatic
    Toxicity
    Criterion
    Toxicity Dependent on Water Chemistry
    302.621
    Determining
    the
    Acute
    Aquatic
    Toxicity
    Criterion
    -
    Procedures for Combinations of Substances
    302.627
    Determining the Chronic Aquatic Toxicity Criterion for an
    Individual Substance
    General Procedures
    302.630
    Determining
    the
    Chronic
    Aquatic
    Toxicity Criterion
    Procedure for Combination of Substances
    The Wild and Domestic Animal Protection Criterion
    The Human Threshold Criterion
    Determining the Acceptable Daily Intake
    Determining the Human Threshold Criterion
    The Human Nonthreshold Criterion
    Determining the Risk Associated Intake
    Determining the Human Nonthreshold Criterion
    Stream
    Flow
    for
    Application
    of
    Human
    Nonthreshold
    Criterion
    Bioconcentration Factor
    Determination of Bioconcentration Factor
    Utilizing the Bioconcentration Factor
    Listing of Derived Criteria
    AUTHORITY:
    Implementing Section 13 and authorized by Section 27 of
    the Environmental Protection Act
    (Ill.
    11ev.
    Stat.
    1991,
    oh.
    111½,
    pars.
    1013 and 1027)
    (415 ILCS 5/13 and 27
    (1992))..
    SOURCE:
    Filed with the Secretary of State January 1, 1978; amended
    at
    2
    Ill.
    Reg.
    44,
    p.
    151,
    effective November 2,
    1978; amended at
    3 Ill. Reg.
    20,
    p.
    95,
    effective May 17,
    1979:
    amended at
    3
    Ill.
    Reg.
    25,
    p.
    190, effective June 21,
    1979; codified at
    6
    Ill.
    Reg.
    7818,
    effective Junc
    22,
    1982
    amended
    at
    6
    Ill.
    Reg.
    11161,
    effective
    September
    7,
    1982;
    amended
    at
    6
    Ill.
    Reg.
    13750,
    effective October 26,
    1982; peremptory amendments at 10 Ill.
    Reg.
    461, effective December 23,
    1985; amended in R87-27 at 12 Ill. Reg.
    9911,
    effective May
    27,
    1988;
    amended in R85—29
    at
    12
    Ill.
    Reg.
    12082,
    effective July
    11,
    1988;
    amended in R88-1 at
    13 Ill.
    Reg.
    5998,
    effective April
    18,
    1989;
    amended
    in R88—21(A)
    at
    14
    Ill.
    Reg.
    2899,
    effective February
    13,
    1990;
    added
    at
    14
    Ill.
    Reg.
    11979,
    effective July
    9,
    1990;
    amended in R94—l
    at
    ________
    Ill.
    Reg.
    _________
    ,
    effective
    302.633
    302
    .
    642
    302.645
    302.648
    302.651
    302.654
    302.657
    302.658
    302.660
    302.663
    302.666
    302.669
    Appendix A
    Appendix B
    References to Previous Rules
    Sources of Codified Sections

    6
    Section 302.202 Purpose
    The general use standards will protect the State’s water for
    aquatic
    life
    (except
    as
    provided
    in
    Section
    302.213),
    wildlife,
    agricultural use,
    secondary contact use and most
    industrial
    uses
    and
    ensure
    the
    aesthetic
    quality
    of
    the
    State’s
    aquatic
    environment.
    Primary
    contact
    uses
    are
    protected
    for
    all
    general
    use
    waters
    whose
    physical
    configuration permits such use.
    (Source: Amended at 18 Ill.
    Reg.
    _____________,
    effective
    ______
    Section 302.208 Numeric Standards for Chemical Constituents
    a)
    The acute
    standard
    (AS)
    for the
    chemical constituents
    listed
    in subsection (8)~shall not be exceeded at any
    time except as provided in subsection (e)~.
    b)
    The chronic standard
    (CS)
    for the chemical constituents
    listed
    in subsection (4)~shall not be exceeded by the
    arithmetic average of at least four consecutive samples
    collected over any period of at least four days,
    except
    as provided
    in subsection
    (e)~.
    The samples used to
    demonstrate compliance or lack of compliance with a CS
    must be collected in a manner which assures an average
    representative of the sampling period.
    c)
    The
    human
    health
    standard
    (HHS)
    for
    the
    chemical
    constituents
    listed
    in
    subsection
    (f)
    shall
    not
    be
    exceeded when the stream flow is at or above the harmonic
    mean pursuant
    to Section
    302.658
    nor
    shall
    an
    annual
    average based on at least eight samples collected in
    a
    manner representative of the sample period exceed the HHS
    except as provided in subsection
    (d).
    ~e)
    In waters where mixing
    is
    allowed pursuant to Section
    302.102, the following apply:
    1.
    The AS shall not be exceeded
    in any waters except
    for those waters for which the Agency has approved
    a ZID pursuant to Section 302.102.
    2.
    The CS shall not be exceeded outside of waters in
    which
    mixing
    is
    allowed
    pursuant
    to
    Section
    302.102.
    3.
    The HHS shall not be exceeded outside of waters in
    which
    mixing
    is
    allowed
    pursuant
    to
    Section
    302.102.

    7
    Arsenic
    (total)
    Cadmium
    (total)
    Chromium
    (total
    hexavalent)
    Chromium
    (total
    trivalent)
    Copper
    (total)
    Cyanide
    Lead
    (total)
    Mercury
    TRC
    71900
    500600
    360
    exp(A+Bln(H)
    3,
    but not to
    exceed 50
    ug/L, where
    A=-2.9l8 and
    B=l.128
    16
    expA+Bln(h)
    where A=3.688
    and 3=0.8190
    exp~A+Bln(H)
    where A=-1.464
    and B=0.9422
    22
    expA+Bln(H)
    but not to
    exceed
    100
    ug
    /
    L
    where A=-l.460
    -1.301 and
    B=1.273
    9--s 2.6
    19
    expA+Bln(H)
    where A=l.561
    and B=0.8190
    expA+Bln(H)
    where A=-1.465
    and B=0.8545
    5.2
    Not Applied
    expA+Bln(H)
    1,
    where A=-2.863
    and B=1.273
    Not
    Applied
    1.3
    11
    where:
    ug/L
    =
    microgram per liter,
    expx
    3
    =
    base neutral logarithms raised
    to the x- power,
    and
    ~4)
    Storet
    AS
    CS
    Constituent
    Number
    (ug/L)
    ug/L
    190
    exp A+Bln(H)3
    where A=-3.490
    and 3=0.7852
    11
    01002
    01027
    01032
    01033
    01042
    00718
    01051
    ln(H)
    =
    natural
    logarithm of Hardness
    (~T~P1~T
    Ofl9flO~

    8
    STORET
    Constituent
    Number
    (ug/L)
    Mercury
    71900
    0.012
    where ug/L
    =
    micrograms per liter
    ge)
    Concentrations
    of the following
    chemical
    constituents
    shall not be exceeded except in waters for which mixing
    is allowed pursuant to Section 302.102.
    STORET
    Constituent
    Unit
    Number
    Standard
    Barium (total)
    mg/L
    01007
    5.0
    Boron
    (total)
    mg/L
    01022
    1.0
    Chloride
    mg/L
    00940
    500.
    (total)
    Fluoride
    mg/L
    00951
    1.4
    Iron
    mg/L
    01046
    1.0
    (dissolved)
    Manganese
    mg/L
    01055
    1.0
    (total)
    Nickel
    (total)
    mg/L
    01067
    1.0
    Phenols
    mg/L
    32730
    0.1
    Selenium
    mg/L
    01147
    1.0
    (total)
    Silver
    (total)
    ug/L
    01077
    5.0
    Sulfate
    mg/L
    00945
    500.
    Total
    mg/L
    70300
    1000.
    Dissolved
    Solids
    Zinc (total)
    mg/L
    01092
    1.0
    where:
    mg/L
    =
    milligram per liter and
    ug/L
    =
    microgram per liter
    (Source:
    Amended at 18
    Ill.
    Reg.
    _________,
    effective

    9
    Section 302.212 Total Ammonia Nitrogen and Un-ionized Ammonia
    a)
    Total
    ammonia
    nitrogen
    (as
    N:
    STORET
    Storet
    Number
    00610)
    shall in no case exceed
    15 mg/i.
    If ammonia nitrogen is less than 15 mg/i and greater than
    or
    equal
    to
    1.5
    mg/i,
    then un-ionized
    ammonia
    (as
    N)
    shall not exceed 0.04 mg/i.
    Un-ionized ammonia nitrogen (as N:
    STORET Number 00612)
    shall not exceed the acute and chronic standards given
    below sublect to the provisions of Section 302.208(a) and
    (b), and 302.213.
    jj
    From April through October the Acute Standard
    (AS1
    shall
    be
    0.3 mg/i
    and the Chronic
    Standard
    (CSI~
    shall
    be 0.05 mg/i.
    21
    From November through March
    the AS
    shall
    be
    0.11
    mg/l and the CS shall be 0.02 mg/i.
    Ammonia
    nitrogen concentrations of less than 1.5 mg/i arc
    lawful regardless of un-ionized ammonia concentration.
    ~4)
    For purposes of this
    section the concentration
    of un-
    ionized ammonia nitrogen as N and total ammonia nitrogen
    as
    N
    shall
    be
    computed
    according
    to
    the
    following
    equation~:
    U
    1.0013N
    (i-I-l0~)-
    N
    10.944l2(l+iOx)
    + 0.055913
    ~JI~1,
    ~j
    U 10.94412(l+10x)+O.05591
    where:
    X
    =
    0.9018
    +
    2729.92
    pH
    (T
    + 273.16)
    U=
    Concentration of un—ionized ammonia as N in mg/l
    N
    =
    Concentration of ammonia nitrogen as N in mg/l
    T
    =
    Temperature in degrees Celsius
    4e)
    The following table~,indicateG the maximum total ammonia
    nitrogen concentrations (mg/i as N) allowable pursuant to
    subsections
    (a)
    and
    (b)
    for certain combinations
    of pH
    and temperature.

    10
    AIIMONIA NITROCEN
    QUALITY
    STANDARD
    (mg/i)
    (41)
    ~&
    (50)
    ~
    15
    (59)
    ~S
    13.9
    4-~-4
    (63)
    ~
    (77)
    4-~
    (36)
    4~&
    14.9
    4---~7-
    (95)
    4~
    10.7
    ~3—-4
    1)
    Summer
    (April through October) Acute
    6.50
    7.00
    7.50
    7.75
    8.00
    8.25
    8.50
    9.00
    °F
    °C
    32
    ,Q!Q
    15.00
    15.00
    15.00
    15.00 15.00
    15.00
    11.17
    3.74
    35
    1.7
    15.00
    15.00
    15.00
    15.00 15.00
    15.00
    9.75
    3.29
    jQ
    j~4~
    15.00
    15.00
    15.00
    15.00 15.00
    13.67
    7.82
    2.68
    45
    L2
    15.00
    15.00
    15.00
    15.00 15.00
    10.98
    6.31
    2.20
    50
    10.0
    15.00
    15.00
    15.00
    15.00 15.00
    8.88
    5.12
    1.82
    ~
    12.8
    15.00
    15.00
    15.00
    15.00 12.59
    7.21
    4.19
    1.53
    ~
    15.6
    15.00
    15.00
    15.00
    15.00 10.25
    5.89
    3.45
    1.29
    65
    18.3
    15.00
    15.00
    15.00
    14.68
    8.38
    4.85
    2.86
    1.11
    2Q
    21.1
    15.00
    15.00
    15.00
    12.03
    6.90
    4.01
    2.39
    0.96
    75
    23.9
    15.00
    15.00
    15.00
    9.90
    5.70
    3.34
    2.01
    0.84
    ~Q
    26.7
    15.00
    15.00
    14.34
    8.19
    4.74
    2.80
    1.70
    0.74
    ~
    29.4
    15.00
    15.00
    11.88
    6.81
    3.96
    2.36
    1.46
    0.67
    90
    32.2
    15.00
    15.00
    9.89
    5.69
    3.33
    2.00
    1.26
    0.60
    wii~i
    i,.’
    TEMP.
    ~---G
    pH
    ~-;4

    11
    2)
    Summer
    (April through October) Chror~kc
    3~
    Winter (Nov~mb~rthrourih Marc~h~Ac~ut~
    4)
    Winter (November throucih March)
    Chronic
    (Source:
    Amended at
    18
    Ill.
    Reg.
    effective
    __________
    6.50
    7.00
    7.50
    7.75
    32
    35
    40
    45
    50
    55
    60
    65
    70
    75
    80
    85
    90
    8.00
    8.25
    8.50
    9.00
    P11
    OC
    0.0
    1.7
    4.4
    7.2
    10.0
    12.8
    15.6
    18.3
    21.1
    23.9
    26.7
    29.4
    32.2
    15.00
    15.00
    15.00
    15.00
    15.00
    15.00
    15.00
    15.00
    12.58
    15.00
    15.00
    10.06
    15.00
    15.00
    8.09
    15.00
    15.00
    6.53
    15.00
    15.00
    5.29
    15.00
    13.52
    4.31
    15.00
    11.04
    3.53
    15.00
    9.05
    2.90
    15.00
    7.45
    2.39
    15.00
    6.15
    1.98
    15.00
    5.10
    1.65
    10.24
    8.91
    7.10
    5.68
    4.57
    3
    .
    69
    3
    .
    00
    2.45
    2.00
    1.65
    1.37
    1.14
    0.95
    5.78
    3.27
    1.86
    0.62
    5.03
    2.85
    1.63
    0.55
    4.01
    2.28
    1.30
    0.45
    3.22
    1.83
    1.05
    0.37
    2.59
    1.48
    0.85
    0.30
    2.10
    1.20
    0.70
    0.25
    1.71
    0.98
    0.57
    0.22
    1.40
    0.81
    0.48
    0.18
    1.15
    0.67
    0.40
    0.16
    0.95
    0.56
    0.33
    0.14
    0.79
    0.47
    0.28
    0.12
    0.66
    0.39
    0.24
    0.11
    0.56
    0.33
    0.21
    0.10
    8.25
    8.50
    9.00
    PU
    6.50
    7.00
    7.50
    7.75
    8.00
    °F
    °C
    32
    0.0
    15.00
    15.00
    15.00
    15.00
    12.71
    7.20
    4.10
    1.37
    35
    1.7
    15.00
    15.00
    15.00
    15.00
    11.07
    6.27
    3.58
    1.21
    40
    4.4
    15.00
    15.00
    15.00
    15.00
    8.83
    5.01
    2.87
    0.98
    j~.
    7.2
    15.00
    15.00
    15.00
    12.50
    7.08
    4.03
    2.31
    0.81
    10.0
    15.00
    15.00
    15.00
    10.05
    5.70
    3.25
    1.88
    0.67
    12.8
    15.00
    15.00
    14.36
    8.12
    4.62
    2.64
    1.54
    0.56
    ~Q
    15.6
    15.00
    15.00
    11.64
    6.60
    3.76
    2.16
    1.26
    0.47
    8.25
    8.50
    9.00
    °F
    ~Ji
    °C
    6.50
    7.00
    7.50
    7.75
    8.00
    32
    0.0
    15.00
    15.00
    7.27
    4.09
    2.31
    1.31
    0.74
    0.25
    1.7
    15.00
    15.00
    6.32
    3.56
    2.01
    1.14
    0.65
    0.22
    40
    4.4
    15.00
    15.00
    5.03
    2.84
    1.61
    0.91
    0.52
    0.18
    45
    7.2
    15.00
    12.69
    4.03
    2.27
    1.29
    0.73
    0.42
    0.15
    50
    10.0
    15.00
    10.19
    3.23
    1.83
    1.04
    0.59
    0.34
    0.12
    12.8
    15.00
    8.21
    2.61
    1.48
    0.84
    0.48
    0.28
    0.10
    .~Q
    15.6
    15.00
    6.65
    2.12
    1.20
    0.68
    0.39
    0.23
    0.09

    12
    Section 302.213
    Effluent Modified Waters
    (Ammonia)
    Effluent modified waters are those waters or portions
    of
    waters that the Agency has determined pursuant to 35
    Ill.
    Adm. Code 309. Subpart A, to have the potential to exceed,
    and
    are
    therefore
    not
    subiect
    to,
    the
    chronic
    ammonia
    standards of Section 302.212(b)
    downstream of an effluent
    outfall
    and outside
    of
    any
    allowable mixing
    zone.
    The
    Agency
    shall
    not
    identify
    a
    waterbody
    as
    an
    effluent
    modified water
    if
    it:
    receives effluent discharges
    that do not meet the
    requirements of
    35
    Ill.
    Adm.
    Code 304.122(d)
    prior
    to dilution with the receiving water
    21
    Has uses known to be adversely impacted by ammonia
    as
    designated
    under
    35
    Ill.
    Adm.
    Code
    303.201
    outside of any allowable mixing zone; and
    exceeds the acute standard of Section 302.212(b).
    (Source:
    Added
    at
    18
    Ill.
    Reg.
    __________________
    ,
    effective
    _____________________________________________________________________)
    Section 302.407
    Chemical Constituents
    Concentrations of other chemical constituents shall not exceed the
    following standards:
    STORET
    CONCENTRATION
    CONSTITUENTS
    NUMBER
    (mg/i)
    Ammonia Un—ionized
    (as
    N*)
    006192.
    0.1
    Arsenic
    (total
    01002
    1.0
    Barium
    (total)
    01007
    5.0
    Cadmium
    (total)
    01027
    0.15
    Chromium (total hexavalent)
    01032
    0.3
    Chromium (total trivalent)
    01033
    1.0
    Copper
    (total)
    01042
    1.0
    Cyanide
    (total)
    00720
    0.10
    Fluoride
    (total)
    00951
    15.0
    Iron
    (total)
    01045
    2.0
    Iron
    (dissolved)
    01046
    0.5
    Lead
    (total)
    01051
    0.1

    13
    Manganese
    (total)
    01055
    1.0
    Mercury
    (total)
    71900
    0.0005
    Nickel
    (total)
    01067
    1.0
    Oil,
    fats and grease
    00550,
    00556
    15.0**
    or 00560
    Phenols
    32730
    0.3
    Selenium
    (total)
    01147
    1.0
    Silver
    01077
    1.1
    Zinc (total)
    01092
    1.0
    Total Dissolved Solids
    70300
    1500
    *For
    purposes
    of
    this
    section
    the
    concentration
    of
    un—ionized
    ammonia shall be computed according to the following equation:
    N
    where:
    0.94412(1
    +
    lox)
    +
    0.0559
    X
    =
    0.09018
    +
    2729.92
    pH
    (T + 273.16)
    U
    =
    Concentration of un—ionized ammonia as N in mg/i
    N
    =
    Concentration of ammonia nitrogen as N in mg/i
    T
    =
    Temperature in degrees Celsius
    **Oil
    shall
    be
    analytically
    separated
    into
    polar
    and non-polar
    components if the total concentration exceeds 15 mg/i.
    In no case
    shall either of the components exceed iS mg/i
    (i.e.,
    15 mg/i polar
    materials and 15 mg/i non-polar materials).
    (Source:
    Amended at
    18 Ill.
    Reg.
    ______________,
    effective

    14
    TITLE 35:
    ENVIRONMENTAL PROTECTION
    SUBTITLE C:
    WATER POLLUTION
    CHAPTER
    I:
    POLLUTION CONTROL BOARD
    PART 304
    EFFLUENT STANDARDS
    SUBPART A:
    GENERAL EFFLUENT STANDARDS
    Section
    304.101
    304.102
    304.103
    304.104
    304.105
    304 .106
    304.120
    304.121
    304.122
    304 .123
    304.124
    304. 125
    304.126
    304.140
    304.141
    304.142
    Section
    Preamble
    Dilution
    Background Concentrations
    Averaging
    Violation of Water Quality Standards
    Offensive Discharges
    Deoxygenating Wastes
    Bacteria
    Total Ammonia Nitrogen
    (as N:STORET number 00610)
    Phosphorus
    (STORET number 00665)
    Additional Contaminants
    pH
    Mercury
    Delays in Upgrading
    (Repealed)
    NPDES Effluent Standards
    New Source Performance Standards
    (Repealed)
    SUBPART B:
    SITE SPECIFIC RULES AND
    EXCEPTIONS NOT OF GENERAL APPLICABILITY
    304.201
    304.202
    304.203
    304.204
    304.205
    304.206
    304 .207
    304.208
    304.209
    304.210
    304.211
    304
    .
    212
    304.213
    Wastewater
    Treatment
    Plant
    Discharges
    of
    the
    Metropolitan Sanitary District of Greater Chicago
    Chior-aikali Mercury Discharges in St. Clair County
    Copper Discharges by Olin Corporation
    Schoenberger Creek:
    Groundwater Discharges
    John Deere Foundry Discharges
    Alton Water Company Treatment Plant Discharges
    Gaiesburg
    Sanitary
    District
    Deoxygenating
    Wastes
    Discharges
    City of Lockport Treatment Plant Discharges
    Wood
    River
    Station
    Total
    Suspended
    Solids
    Discharges
    Alton Wastewater Treatment Plant Discharges
    Discharges
    From
    Borden
    Chemicals
    and
    Plastics
    Operating
    Limited
    Partnership
    Into
    an
    Unnamed
    Tributary of Long Point Slough
    Sanitary District of Decatur Discharges
    Union oil Refinery Ammonia Discharge

    15
    304.214
    304.215
    304.216
    304.218
    304.219
    304.220
    304.221
    304.222
    Section
    304.301
    304.302
    304.303
    Mobil Oil Refinery Ammonia Discharge
    City
    of
    Tuscoia
    Wastewater
    Treatment
    Facility
    Discharges
    Newton Station Suspended Solids Discharges
    City of Pana Phoshorus Discharge
    North Shore Sanitary District phosphorus Discharges
    East
    St.
    Louis
    Treatment
    Facility,
    Illinois—
    American Water Company
    Ringwood
    Drive Manufacturing
    Facility
    in McHenry
    County
    Intermittent Discharge of TRC
    SUBPART
    C:
    TEMPORARY EFFLUENT STANDARDS
    Exception
    for
    Ammonia
    Nitrogen
    Water
    Quality
    Violations
    (Repealed)
    City of Joliet East Side Wastewater Treatment Plant
    Amerock Corporation, Rockford Facility
    Appendix A
    References to Previous Rules
    AUTHORITY:
    Implementing Section 13 and authorized by Section 27 of
    the Environmental Protection Act
    (Ill.
    Rev.
    Stat.
    1991,
    ch.
    111½,
    pars.
    1013 and 1027)
    (415 ILCS 5/13 and 27
    (1992)).
    SOURCE:
    Filed with the Secretary of State January 1, 1978; amended
    at
    2
    Ill. Reg.
    30,
    p.
    343,
    effective July
    27,
    1978;
    amended at
    2
    Ill. Reg.
    44, p.
    151, effective November 2,
    1978; amended at 3 Ill.
    Reg.
    20,
    p.
    95, effective May 17,
    1979; amended at 3 Ill. Reg.
    25,
    p.
    190, effective June 21,
    1979; amended at 4 Ill. Reg.
    20,
    p.
    53
    effective
    May
    7,
    1980;
    amended
    at
    6
    Ill.
    Reg.
    563,
    effective
    December 24,
    1981; codified at 6
    Iii. Reg. 7818:
    amended at 6 Ill.
    Reg.
    11161,
    effective
    September
    7,
    1982;
    amended at
    6
    Ill.
    Reg.
    13750,
    effective October
    26,
    1982;
    amended at
    7
    Ill.
    Reg.
    3020,
    effective March
    4,
    1983;
    amended
    at
    7
    Ill.
    Reg.
    8111,
    effective
    June 23,
    1983; amended at
    7 Ill. Reg.
    14515, effective October 14,
    1983;
    amended at
    7
    Ill.
    Reg.
    14910,
    effective November
    14,
    1983;
    amended at
    7 Ill. Reg. 14910, effective November 14,
    1983; amended
    at 8 Ill. Reg.
    1600, effective January 18,
    1984; amended at 8 Ill.
    Reg.
    3687, effective March 14,
    1984; amended at 8 Ill.
    Reg.
    8237,
    effective June
    8,
    1984;
    amended
    at
    9
    Ill.
    Reg.
    1379,
    effective
    January 21,
    1985; amended at 9 Iii.
    Reg. 4510,
    effective March 22,
    1985; peremptory amendment at 10 Ill. Reg. 456, effective December
    23,
    1985; amended at 11 Ill. Reg. 3117, effective January 28,
    1987;
    amended
    in R84—l3
    at
    11
    Ill.
    Reg.
    7291
    effective April
    3,
    1987;
    amended
    in R86-17(A)
    at
    11
    Ill.
    Reg.
    14748,
    effective August
    24,
    1987; amended in R84-l6 at 12 lil.
    Reg. 2445, effective January 15,
    1988;
    amended
    in R83-23 at
    12
    Ill.
    Reg.
    8658,
    effective May
    10,
    1988;
    amended
    in R87—27
    at
    12
    Ill.
    Reg.
    9905,
    effective May
    27,
    1988;
    amended
    in R82—7
    at
    12
    Ill.
    Reg.
    10712,
    effective June
    9,
    1988; amended in R85—29 at
    12
    Ill.
    Reg.
    12064, effective July
    12,

    16
    1988; amended in R87-22 at 12 Ill. Reg. 13966, effective August 23,
    1988;
    amended
    in R86—3
    at
    12
    Ill.
    Reg.
    20126, effective November
    16,
    1988; amended in R84—20 at 13 Ill. Reg.
    851, effective January
    9, 1989; amended in R85-1l at 13 Iii. Reg. 2060, effective February
    6,
    1989; amended in R88—1 at 13 Ill. Reg. 5976, effective April 18,
    1989;
    amended
    in R86—17B
    at
    13
    Ill.
    Reg.
    7754,
    effective May
    4,
    1989;
    amended
    in R88—22
    at
    13
    Ill.
    Reg.
    8880,
    effective May 26,
    1989;
    amended
    in R87—6
    at
    14
    Iii. Reg.
    6777,
    effective April
    24,
    1990;
    amended
    in R87—36
    at
    14
    Ill.
    Reg.
    9437,
    effective May
    31,
    1990; added at 14 Ill. Beg. 11979, effective July 9,
    1990; amended
    in
    R84—44
    at
    14
    Ill.
    Reg.
    20719,
    effective
    December
    11,
    1990;
    amended in R86—14 at 15 Ill. Reg.
    241, effective December 18, 1990;
    amended
    in R87—33 at 18
    Ill.
    Beg.
    11574,
    effective July
    7,
    1994;
    amended in R94-1
    at
    _____
    Ill.
    Reg.
    _______,
    effective
    _________
    Section 304.122
    Total Ammonia Nitrogen
    (as N: STORET number
    00610)
    a)
    No
    effluent
    from
    any
    source
    which
    discharges
    to
    the
    Illinois River,
    the Des
    Plaines
    River downstream
    of
    its
    confluence with
    the Chicago
    River
    System or the Calumet
    River System,
    and whose untreated waste load
    is 50,000 or
    more population
    equivalents
    shall
    contain
    more
    than
    2.5
    mg/l of total
    ammonia nitrogen as N during the months of
    April through October,
    or 4 mg/i at other times.
    b)
    Sources discharging to any of the above waters and whose
    untreated
    waste
    load cannot
    be commuted
    on
    a population
    equivalent
    basis
    comparable
    to
    that
    used
    for
    municipal
    waste treatment plants and whose total ammonia nitrogen as
    ~jdischarge exceeds 45.4 kg/day (100 pounds per day)
    shall
    not discharge an effluent of more than 3.0 mg/i of total
    ammonia nitrogen as
    N.
    ~
    In
    addition
    to
    the
    effluent
    standards
    set
    forth
    in
    subsections
    (a)
    and
    (b)
    above,
    all sources are subiect to
    Section 304.105 unless the Agency determines as part of the
    NPDES Permit Program under
    35 Ill.
    Adm.
    Code 309,
    Subpart
    A that alternate effluent standards are applicable pursuant
    to subsection
    (d)
    of this section.
    ~,j
    All discharges to effluent modified waters as defined at 35
    Ill.
    Adm.
    Code
    302.213,
    except
    for
    treatment
    works
    qualifvin~ under
    Section
    304.120(c),
    must demonstrate to
    the Agency
    that
    their
    effluent
    will not
    exceed monthly
    averages of 1.5 mg/i total ammonia as N during the months
    of April through October, or 4.0
    mg/i
    total ammonia as N at
    other
    times.
    The
    Agency
    shall
    apply
    the
    following
    restrictions
    in a NPDES Permit:
    Dischargers achieving lower ammonia concentrations

    17
    than given above, yet not meeting the chronic water
    quality standards of 35 Ill.
    Adm.
    Code 302.212(b),
    shall maintain their existing level
    of performance
    consistent with the facility’s expected organic and
    hydraulic loadings for the duration of their NPDES
    permit.
    21
    New or expanded
    discharges
    that
    increase ammonia
    loading
    to
    general
    use
    waters
    and/or
    create
    effluent modified waters or portions of waters must
    demonstrate
    compliance
    to
    the
    Agency
    with
    the
    nondegradation requirements
    at
    35
    Ill.
    Adm.
    Code
    302.105.
    (Source:
    Amended at 18
    Iii.
    Beg.
    ____________,
    effective
    Section
    304.301
    Exception
    for Ammonia
    Nitrogen Water
    Quality Violations
    (Repealed)
    a)
    Section
    304.105
    shall
    not
    apply
    to
    35
    Ill.
    Adm.
    Code
    -3-02.212
    for
    any
    source
    during
    the
    months
    of
    November
    through March;
    except that during the months of November
    through
    March
    no
    source
    shall
    discharge
    an
    effluent
    containing a concentration of ammonia nitrogen greater than
    4.0 mg/i
    if the discharge,
    alone
    or
    in combination with
    other discharges,
    causes or contributes to a violation of
    1~
    T11
    Adm.
    (~r~t1r
    ~O2..212..
    b)
    Compliance with the provisions
    of subsection
    (a)
    shall be
    achieved by March 31,
    1979,
    or such other date as required
    by NPDEC
    permit,
    or as
    ordered
    by the Board Under Title
    VIII or Title IX of the Environmental Protection Act.
    c)
    After July
    1,
    1991, the exemption provided in this Section
    ~-h~11
    ~
    (Source:
    Repealed at 18
    Ill.
    Reg.
    ______________,
    effective
    __________________________________________________________________________________________________ )
    IT IS SO ORDERED.
    I,
    Dorothy
    N.
    Gunn,
    Clerk
    of the Illinois Pollution
    Control
    Board, hereby certify that the abov~opij~ionorder was adopted on
    the_________________
    day of
    _____________________,
    1994,
    by a
    voteof
    ______.
    ~
    4.
    /~p~
    Dorothy M.
    G~inn, Clerk
    Illinois Pol’lution Control Board

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