ILLINOIS POLLUTION CONTROL BOARD
    November 18,
    1994
    IN THE MATTER OF:
    )
    15
    ROP
    PLAN
    CONTROL MEASURES
    )
    FOR VOM EMISSIONS
    -
    PART VII:
    )
    R94—33
    BATCH OPERATIONS:
    )
    (Rulemaking)
    AMENDMENTS TO 35 ILL.
    ADM.
    )
    CODE PARTS 211,
    218
    AND
    219
    )
    Proposed Rule.
    First Notice.
    OPINION
    AND
    ORDER OF THE BOARD
    (by R.C. Flemal):
    On November 14,
    1994,
    the Illinois Environmental Protection
    Agency
    (Agency) filed this proposal for rulemaking.
    The proposal
    represents one part of Illinois’ submittal of a complete state
    implementation plan
    (SIP).
    Section 182(b) (1)
    of the Clean Air
    Act
    (42 U.S.C. 7511(b) (1))
    requires all moderate and above ozone
    nonattainment areas to achieve a 15
    reduction of 1990 emissions
    of volatile organic material
    (VOM)
    by 1996.
    The Chicago and
    Metro—East St. Louis areas are classified as “Severe” and
    “Moderate” nonattainment for ozone, respectively, and are subject
    to the 15
    reduction requirement.
    This proposal represents Part
    VII of the rulemakings anticipated in the 15
    Rate of Progress
    Plan (“15
    ROP Plan”).
    The proposal seeks to amend 35 Ill. Adm.
    Code 211, 218 and 219.
    The proposed rulemaking would control VOM emissions from
    chemical processes operating in a batch mode.
    The proposed
    amendments to Subpart V are intended to cover all batch
    operations at sources identified by standard industrial
    classification codes,
    as defined in the 1987 edition of the
    Standard Industrial Classification Manual, which manufacture as a
    primary product or intermediate, any chemical identified by the
    following:
    plastic materials and resins
    (SIC 2821),
    pharmaceutical preparations
    (2834), medicinal chemicals and
    botanical production
    (SIC 2833), gum and wood chemicals (SIC
    2861),
    cyclic crudes and intermediates
    (SIC 2865), industrial
    organic chemicals (SIC
    2869)
    and agricultural chemicals (SIC
    2879).
    The rulemaking is proposed for process vents associated
    with batch or non—continuous chemical manufacturing operations.
    Batch operations in the Chicago and Metro—East ozone
    nonattainment areas,
    as defined in 35 Iii. Adm. Code Parts 218
    and 219, Sections 218.103 and 219.103, are subject to this
    rulemaking.
    All process vents associated with batch operations
    at Stepan Company’s Milisdale manufacturing facility, Elwood,
    Illinois,
    a’re also subject to the proposal.

    Today the Board acts to send this proposal to first notice
    under the Illinois Administrative Procedure Act, but without
    commenting on the merits of the proposal.
    This proposal was filed pursuant to Section 28.5 of the
    Environmental Protection Act
    (Act)
    as
    a fast—track rulemaking
    proceeding.
    (415 ILCS 5/28.5
    (1992).)
    Section 28.5 requires the
    Board to proceed with rulemaking under set time—frames.
    The
    Board has no discretion to adjust these time frames under any
    circumstances.
    The following schedule indicates the deadlines by
    which the Board must act,
    as provided in Section 28.5:
    first notice
    on or before November 29,
    1994
    first hearing
    on or before January
    8, 1995
    second hearing
    no later than 30 days after
    the start of the first hearing
    third hearing
    no later than 14 days after
    the start of the second
    hearing
    second notice
    (if third hearing cancelled)
    on or before March 24,
    1995
    (if third hearing held)
    on or before April
    13,
    1995
    final adoption and filing
    21 days after receipt of JCAR
    certificate of no objection
    The Board notes that the above dates are the deadlines as
    established by Section 28.5 and do not represent actual hearing
    dates or filing dates.
    While the schedule includes second and
    third hearings, these hearings may be cancelled if unnecessary.
    The Board will proceed in this matter as prescribed in Section
    28.5 and discussed in the Board’s resolution.
    (~
    Clean Air Act
    Rulemaking Procedures Pursuant to Section 28.5 of the
    Environmental Protection Act, as Added By P.A. 87-1213,
    (October
    29,
    1992 and December
    3,
    1992), RES 92—2.)
    The Agency has filed a motion for waiver of requirements
    with the proposal.
    The Agency requests waiver of the following
    requirements:
    that the Agency submit the original and nine
    copies of the entire regulatory proposal; that the Agency submit
    an entire copy of the proposal to the Attorney General and the
    Department of Energy and Natural Resources
    (DENR); and that the
    Agency submit copies of all documents upon which it relied.
    The
    Agency asks that it be permitted to file an original plus five
    complete copies of the proposal and four partial copies.
    A
    partial copy includes the pleadings and the proposed rules, but
    does not include the supporting exhibits.
    The Attorney General
    and DENR have agreed with the Agency that a copy of the proposal
    need not be served upon them.
    The Agency has provided the Board
    with one copy of some of the documents on which it relied, and
    notes that the other documents are readily accessible or already
    in the Board’s possession.
    The Board grants the Agency’s motion.

    3
    ORDER
    The Board directs the Clerk to cause publication of the
    following amendments in the Illinois Register for first notice:
    TITLE 35:
    ENVIRONMENTAL PROTECTION
    SUBTITLE B:
    AIR POLLUTION
    CHAPTER
    I:
    POLLUTION CONTROL BOARD
    SUBCHAPTER c:
    EMISSION STANDARDS
    AND
    LIMITATIONS
    FOR STATIONARY SOURCES
    PART 211
    DEFINITIONS
    AND
    GENERAL PROVISIONS
    SUBPART A:
    GENERAL PROVISIONS
    Section
    211.101
    211.102
    Section
    211.121
    211.122
    211.130
    211.150
    211.170
    211.210
    211.230
    211. 250
    211.270
    211.290
    211.310
    211.330
    211.350
    211.370
    211.390
    211.410
    211.430
    211. 450
    211.470
    211.490
    211.510
    211.530
    211.550
    211. 560
    211. 570
    211. 590
    211.610
    211.630
    Incorporation by Reference
    Abbreviations and Conversion Factors
    SUBPART B:
    DEFINITIONS
    Other Definitions
    Definitions
    (Repealed)
    Accelacota
    Accumulator
    Acid Gases
    Actual Heat Input
    Adhesive
    Aeration
    Aerosol Can Filling Line
    Afterburner
    Air Contaminant
    Air Dried Coatings
    Air Oxidation Process
    Air Pollutant
    Air Pollution
    Air Pollution Control Equipment
    Air Suspension Coater/Dryer
    Airless Spray
    Air Assisted Airless Spray
    Annual Grain Through-Put
    Application Area
    Architectural Coating
    As Applied
    As-Applied Fountain Solution
    Asphalt
    Asphalt Prime Coat
    Automobile
    Automobile or Light-Duty Truck Assembly Source or
    Automobile or Light-Duty Truck Manufacturing Plant

    4
    211. 650
    211.670
    211.690
    211. 695
    211.696
    211. 710
    211.730
    211.750
    211.770
    211.790
    211.810
    211.830
    211.850
    211.870
    211.890
    211.910
    211.930
    211.950
    211.970
    211.990
    211. 1010
    211. 1050
    211. 1070
    211. 1090
    211. 1110
    211. 1130
    211. 1150
    211. 1170
    211. 1190
    211. 1210
    211. 1230
    211. 1250
    211. 1270
    211. 1290
    211. 1310
    211. 1330
    211. 1350
    211. 1370
    211.1390
    211. 1410
    211. 1430
    211. 1470
    211. 1490
    211. 1510
    211. 1530
    211.1550
    211.1570
    211. 1590
    211. 1610
    211. 1630
    211. 1650
    211. 1670
    Automobile or Light-Duty Truck Refinishing
    Baked Coatings
    Batch Loading
    Batch Operation
    Batch Process Train
    Bead-Dipping
    Binders
    British Thermal Unit
    Brush or Wipe Coating
    Bulk Gasoline Plant
    Bulk Gasoline Terminal
    Can
    Can Coating
    Can Coating Line
    Capture
    Capture Device
    Capture Efficiency
    Capture System
    Certified Investigation
    Choke Loading
    Clean Air Act
    Cleaning and Separating Operation
    Cleaning Materials
    Clear Coating
    Clear Topcoat
    Closed Purge System
    Closed Vent System
    Coal Refuse
    Coating
    Coating Applicator
    Coating Line
    Coating Plant
    Coil Coating
    Coil Coating Line
    Cold Cleaning
    Complete Combustion
    Component
    Concrete Curing Compounds
    Concentrated Nitric Acid Manufacturing Process
    Condensate
    Condensible PM-b
    Continuous Process
    Control Device
    Control Device Efficiency
    Conventional Soybean Crushing Source
    Conveyorized Degreasing
    Crude Oil
    Crude Oil Gathering
    Crushing
    Custody Transfer
    Cutback Asphalt
    Daily-Weighted Average VON Content

    5
    Day
    Degreaser
    Delivery Vessel
    Dip Coating
    Distillate
    Fuel Oil
    Drum
    Dry Cleaning Operation or Dry Cleaning Facility
    Dump-Pit Area
    Effective Grate Area
    Effluent Water Separator
    Electrostatic Bell or Disc Spray
    Electrostatic Spray
    Emergency or Standby Unit
    Emission Rate
    Emission Unit
    Enamel
    Enclose
    End Sealing Compound Coat
    Enhanced Under-the-Cup Fill
    Ethanol Blend Gasoline
    Excess Air
    Excessive Release
    Existing Grain-Drying Operation
    Existing Grain-Handling Operation
    Exterior Base Coat
    Exterior End Coat
    External Floating Roof
    Extreme Performance Coating
    Fabric Coating
    Fabric Coating Line
    Federally Enforceable Limitations and Conditions
    Final Repair Coat
    Firebox
    Fixed—Roof Tank
    Flexographic Printing
    Flexographic Printing Line
    Floating Roof
    Fountain Solution
    Freeboard Height
    Fuel Combustion Emission Unit or Fuel Combustion
    Emission Source
    Fugitive Particulate Matter
    Full Operating Flowrate
    Gas Service
    Gas/Gas Method
    Gasoline
    Gasoline Dispensing Operation or Gasoline Dispensing
    Facility
    Gel Coat
    Grain
    Grain—Drying Operation
    Grain—Handling and Conditioning Operation
    211. 1690
    211.1710
    211.1730
    211. 1750
    211.1770
    211.1790
    211. 1810
    211. 1830
    211. 1850
    211. 1870
    211. 1890
    211. 1910
    211. 1920
    211. 1930
    211. 1950
    211.1970
    211.1990
    211. 2010
    211.2030
    211.2050
    211.2070
    211.2090
    211. 2110
    211.2130
    211.2150
    211.2170
    211. 2190
    211. 2210
    211.2230
    211.2250
    211.2270
    211. 2310
    211.2330
    211.2350
    211.2370
    211.2390
    211.2410
    211.2430
    211.2450
    211.2470
    211.2490
    211.2510
    211.2530
    211.2550
    211.2570
    211.2590
    211.2610
    211.2650
    211.2670
    211.2690

    6
    211.2710
    211.2730
    211.2750
    211.2770
    211.2790
    211.2810
    211.2830
    211.2850
    211.2870
    211.2890
    211.2910
    211.2930
    211.2950
    211.2970
    211.2990
    211.3010
    211.3030
    211.3050
    211.3070
    211.3090
    211.3110
    211.3130
    211.3150
    211. 3170
    211. 3190
    211.3210
    211.3230
    211.3250
    211. 3270
    211.3290
    211. 3310
    211.3330
    211. 3350
    211.3370
    211.3390
    211. 3410
    211.3430
    211.3450
    211.3470
    211.3480
    211.3490
    211.3500
    211.3510
    211.3530
    211.3550
    211. 3570
    211.3590
    211.3610
    211.3620
    211. 3630
    211.3650
    211.3660
    Grain-Handling
    Operation
    Green-Tire
    Spraying
    Green
    Tires
    Gross
    Heating
    Value
    Gross Vehicle Weight Rating
    Heated Airless Spray
    Heatset
    Heatset Web Offset Lithographic Printing Line
    Heavy
    Liquid
    Heavy
    Metals
    Heavy
    Off-Highway
    Vehicle
    Products
    Heavy
    Off-Highway
    Vehicle
    Products
    Coating
    Heavy
    Off-Highway
    Vehicle Products Coating Line
    High
    Temperature
    Aluminum
    Coating
    High
    Volume
    Low
    Pressure
    (HVLP)
    Spray
    Hood
    Hot
    Well
    Housekeeping
    Practices
    Incinerator
    Indirect
    Heat
    Transfer
    Ink
    In—Process
    Tank
    In-Situ Sampling Systems
    Interior Body Spray Coat
    Internal—Floating Roof
    Internal Transferring Area
    Lacquers
    Large Appliance
    Large Appliance Coating
    Large Appliance Coating Line
    Light Liquid
    Light-Duty Truck
    Light Oil
    Liquid/Gas Method
    Liquid-Mounted Seal
    Liquid Service
    Liquids Dripping
    Lithographic Printing Line
    Load-Out Area
    Loading Event
    Low Solvent Coating
    Lubricating Oil
    Magnet Wire
    Magnet Wire Coating
    Magnet Wire Coating Line
    Major Dump Pit
    Major Metropolitan Area
    (MMA)
    1’~ajorPopulation Area
    (MPA)
    Manually Operated Equipment
    Manufacturing Process
    Marine Terminal
    Marine Vessel

    7
    211.3670
    211.3690
    211.3710
    211.3730
    211.3750
    211.3770
    211.3790
    211
    .
    3810
    211.3830
    211.3850
    211.3870
    211.3890
    211.3910
    211.3930
    211.3950
    211.3970
    211.3990
    211.4010
    211.4030
    211.4050
    211.4070
    211.4090
    211.4110
    211.4130
    211.4150
    211.4170
    211.4190
    211.
    4210
    211.4230
    211.4250
    211.4260
    211.4270
    211.4290
    211.4310
    211.4330
    211.4350
    211.4370
    211.4390
    211.4410
    211.4430
    211.4450
    211.4470
    211.4490
    211.4510
    211.4530
    211.4550
    211.4590
    211.4610
    211.4630
    211.4650
    Material Recovery Section
    Maximum Theoretical Emissions
    Metal Furniture
    Metal Furniture Coating
    Metal Furniture Coating Line
    Metallic Shoe-Type Seal
    Miscellaneous Fabricated Product Manufacturing Process
    Miscellaneous Formulation Manufacturing Process
    Miscellaneous Metal Parts and Products
    Miscellaneous Metal Parts and Products Coating
    Miscellaneous Metal Parts or Products Coating Line
    Miscellaneous Organic Chemical Manufacturing Process
    Mixing Operation
    Monitor
    Monomer
    Multiple Package Coating
    New Grain-Drying Operation
    New Grain-Handling Operation
    No Detectable Volatile Organic Material’ Emissions
    Non—contact Process Water Cooling Tower
    Offset
    One Hundred Percent Acid
    One—Turn Storage Space
    Opacity
    Opaque Stains
    Open Top Vapor Degreasing
    Open-Ended Valve
    Operator of a Gasoline Dispensing Operation or Operator
    of a Gasoline Dispensing Facility
    Organic Compound
    Organic Material and Organic Materials
    Organic Solvent
    Organic Vapor
    Oven
    Overall Control
    Overvarnish
    Owner of a Gasoline Dispensing Operation or Owner of a
    Gasoline Dispensing Facility
    Owner or Operator
    Packaging
    Rotogravure
    Printing
    Packaging
    Rotogravure
    Printing
    Line
    Pail
    Paint
    Manufacturing
    Source
    or
    Paint
    Manufacturing
    Plant
    Paper
    Coating
    Paper
    Coating
    Line
    Particulate Matter
    Parts Per Million
    (Volume)
    or PPM
    (Vol)
    Person
    Petroleum
    Petroleum Liquid
    Petroleum Refinery
    Pharmaceutical

    8
    211.4670
    211.4690
    211.4710
    211.4730
    211.4750
    211.4770
    211.4790
    211.4810
    211.4830
    211.4850
    211.4870
    211.4890
    211.4910
    211.4930
    211.4950
    211.4970
    211.4990
    211.
    5030
    211.5050
    211.5060
    211.5070
    211.5090
    211.5110
    211.5130
    211.5150
    211.5170
    211.5185
    211.5190
    211.5210
    211.5230
    211.5245
    211.5250
    211.5270
    211.5310
    211.5330
    211.5340
    211.5350
    211.5370
    211.5390
    211.5410
    211.5430
    211.5450
    211.5470
    211.5490
    211.5500
    211.5510
    211.5530
    211.5550
    211.5570
    211.5590
    Pharmaceutical
    Coating
    Operation
    Photochemically
    Reactive
    Material
    Pigmented
    Coatings
    Plant
    Plasticizers
    PM—b
    Pneumatic
    Rubber
    Tire
    Manufacture
    Polybasic Organic Acid Partial Oxidation Manufacturing
    Process
    Polyester Resin Material(s)
    Polyester Resin Products Manufacturing Process
    Polystyrene Plant
    Polystyrene Resin
    Portable Grain-Handling Equipment
    Portland Cement Manufacturing Process Emission Source
    Portland Cement Process or Portland Cement
    Manufacturing Plant
    Potential
    to
    Emit
    Power
    Driven
    Fastener
    Coating
    Pressure
    Release
    Pressure
    Tank
    Pressure/Vacuum
    Relief
    Valve
    Prime
    Coat
    Primer
    Surfacer
    Coat
    Primer Surfacer Operation
    Primers
    Printing
    Printing Line
    Process Emission Source
    Process Emission Unit
    Process Unit
    Process Unit Shutdown
    Process Vent
    Process
    Weight
    Rate
    Production Equipment Exhaust System
    Publication
    Rotogravure
    Printing
    Line
    Purged Process Fluid
    Rated Heat Input Capacity
    Reactor
    Reasonably Available Control Technology
    (RACT)
    Reclamation System
    Refiner
    Refinery Fuel Gas
    Refinery Fuel Gas System
    Refinery Unit or Refinery Process Unit
    Refrigerated Condenser
    Regulated Air Pollutant
    Reid Vapor Pressure
    Repair
    Repair Coat
    Repaired
    Residual Fuel Oil

    9
    211.5610
    211.5630
    211.
    5650
    211.
    5670
    211.
    5690
    211.
    5710
    211.5730
    211.
    5750
    211.
    5770
    211.5790
    211.5810
    211.5830
    211.5850
    211.5870
    211.5890
    211.5910
    211.5930
    211.5950
    211.5970
    211.5990
    211.
    6010
    211.
    6025
    211.
    6030
    211.6050
    211.6070
    211.6090
    211.6110
    211.6130
    211.6150
    211.6170
    211.6190
    211.6210
    211.6230
    211.6250
    211.6270
    211.6290
    211.6310
    211.6330
    211.6350
    211.6355
    211.6360
    211.6370
    211.6390
    211.6410
    211.6430
    211.6450
    211.6470
    211.6490
    211.6510
    211.6530
    211.6550
    Restricted
    Area
    Retail
    Outlet
    Ringelinann
    Chart
    Roadway
    Roll
    Coater
    Roll
    Coating
    Roll
    Printer
    Roll
    Printing
    Rotogravure Printing
    Rotogravure
    Printing
    Line
    Safety
    Relief
    Valve
    Sandblasting
    Sanding
    Sealers
    Screening
    Sealer
    Semi-Transparent
    Stains
    Sensor
    Set
    of
    Safety
    Relief
    Valves
    Sheet
    Basecoat
    Shotblasting
    Side-Seam
    Spray
    Coat
    Single Unit Operation
    Smoke
    Smokeless Flare
    Solvent
    Solvent Cleaning
    Solvent Recovery System
    Source
    Specialty High Gloss Catalyzed Coating
    Specialty Leather
    Specialty Soybean Crushing Source
    Splash Loading
    Stack
    Stain Coating
    Standard Conditions
    Standard
    Cubic
    Foot
    (scf)
    Start-Up
    Stationary
    Emission
    Source
    Stationary Emission Unit
    Stationary Gas Turbine
    Stationary Reciprocating Internal Combustion Engine
    Stationary Source
    Stationary Storage Tank
    Storage Tank or Storage Vessel
    Styrene Devolatilizer Unit
    Styrene Recovery Unit
    Submerged Loading Pipe
    Substrate
    Sulfuric Acid Mist
    Surface Condenser
    Synthetic Organic Chemical or Polymer Manufacturing
    Plant

    10
    211.6570
    211.6590
    211. 6610
    211.6630
    211. 6650
    211.6670
    211.6690
    211. 6710
    211.6730
    211.
    6750
    211. 6770
    211.6790
    211.6810
    211.6830
    211.6850
    211. 6870
    211.6890
    211. 6910
    211. 6930
    211.6950
    211. 6970
    211.6990
    211.7010
    211.7030
    211.7050
    211.7070
    211.7090
    211.7110
    211.7130
    211.7150
    211.7170
    211.
    7190
    211.7210
    211. 7230
    211.7250
    211.
    7270
    211.7290
    211.
    7310
    211.7330
    211.7350
    Tablet Coating Operation
    Thirty-Day Rolling Average
    Three—Piece Can
    Through-the-Valve Fill
    Tooling Resin
    Topcoat
    Topcoat Operation
    Touch-Up
    Transfer Efficiency
    Tread End Cementing
    True Vapor Pressure
    Turnaround
    Two—Piece Can
    Under-the-Cup
    Fill
    Undertread Cementing
    Unregulated Safety Relief Valve
    Vacuum Producing System
    Vacuum Service
    Valves Not Externally Regulated
    Vapor Balance System
    Vapor Collection System
    Vapor Control System
    Vapor-Mounted Primary Seal
    Vapor Recovery System
    Vapor—Suppressed Polyester Resin
    Vinyl Coating
    Vinyl Coating Line
    Volatile Organic Liquid
    (VOL)
    Volatile Organic Material Content
    (VOMC)
    Volatile Organic Material
    (VOM)
    or Volatile Organic
    Compound
    (VOC)
    Volatile Petroleum Liquid
    Wash Coat
    Wastewater
    (Oil/Water)
    Separator
    Weak Nitric Acid Manufacturing Process
    Web
    Wholesale Purchase
    Consumer
    Wood Furniture
    Wood Furniture Coating
    Wood Furniture Coating Line
    Woodworking
    APPENDIX A
    Rule into Section Table
    APPENDIX B
    Section into Rule Table
    AUTHORITY:
    Implementing Sections 9,
    9.1 and 10 and authorized by
    Section 27 and 28.5 of the Environmental Protection Act
    (Ill.
    Rev.
    Ctat.
    1901,
    oh.
    111~,
    pars.
    1009,
    1009.1,
    1010
    and
    1027),
    (P.A.
    87—1213, effective &eptc~tbor26,
    1992-~
    415
    ILCS 5/9,
    9.1,
    10,
    27 and 28.5
    (1992).
    SOURCE:
    Adopted as Chapter 2:
    Air Pollution, Rule 201:

    11
    Definitions,
    R7b-23,
    4 PCB 191,
    filed and effective April
    14,
    1972; amended
    in P.74—2 and P.75—5,
    32 PCB 295,
    at
    3 Ill.
    Reg.
    5,
    p.
    777,
    effective February
    3,
    1979;
    amended
    in R78-3 and 4,
    35
    PCB 75 and 243,
    at
    3 Ill.
    Reg.
    30,
    p.
    124, effective July 28,
    1979; amended in P.80-5,
    at
    7
    Iii.
    Reg.
    1244, effective January
    21,
    1983;
    codified at 7 Ill.
    Reg.
    13590; amended in P.82—i (Docket
    A)
    at
    10 Ill. Reg.
    12624,
    effective July 7,
    1986; amended in
    R85—21(A)
    at 11 Ill. Reg.
    11747, effective June 29, 1987; amended
    in R86—34 at
    11 Ill.
    Reg.
    12267, effective July
    10,
    1987;
    amended
    in R86—39 at 11 Ill.
    Reg.
    20804, effective December
    14,
    1987;
    amended in P.82-14 and R86-37
    at
    12 Ill. Reg.
    787, effective
    December 24,
    1987;
    amended in R86—18 at 12 Ill.
    Reg.
    7284,
    effective April
    8,
    1988;
    amended
    in R86—10 at
    12 Ill.
    Reg.
    7621,
    effective April 11,
    1988; amended in R88—23 at
    13 Ill. Reg.
    10862, effective June
    27, 1989; amended in P.89—S at
    13 Ill.
    Reg.
    17457,
    effective January
    1,
    1990; amended in P.89-16(A)
    at 14 Ill.
    Reg.
    9141,
    effective May 23,
    1990;
    amended in R88—30(B)
    at 15
    Ill.
    Reg.
    5223,
    effective March 28,
    1991; amended in R88—14 at 15
    Ill. Reg.
    7901, effective May
    14,
    1991; amended in P.91-10 at 15
    Ill.
    Reg.
    15564, effective October 11,
    1991;
    amended
    in P.91-6 at
    15 Ill.
    Reg.
    15673, effective October
    14,
    1991; amended in P.91—22
    at
    16
    Ill.
    Reg.
    7656,
    effective May
    1,
    1992; amended in P.91-24 at
    16
    Ill.
    Reg.
    13526, effective August 24,
    1992;
    amended in P.93—9
    at 17 Ill. Reg.
    16504, effective September 27,
    1993; amended in
    R93—1l at
    17
    Ill.
    Reg. 21471,
    effective December 7,
    1993; amended
    in R93—14 at 18
    Iii. Reg.
    1253,
    effective January 18,
    1994;
    amended in P.94—12 at 18 Ill. Reg.
    14962, effective September 21,
    1994; amended in R94-14 at 18 Ill. Reg.
    15744,
    effective October
    17,
    1994;
    amended in R94—15 at
    18 Iii. Reg.
    16379, effective
    November
    4,
    1994; amended in R94-~at ~
    Ill. Reg.
    effective
    __________________;
    amended in R94—~ at ~
    Ill.
    Reg.
    _________,
    effective
    ________________
    SUBPART
    B:
    DEFINITIONS
    Section 211.695
    Batch Operation
    “Batch operation” means, for purposes of
    35
    Ill.
    Adm.
    Code
    Parts
    218
    and
    219,
    Sections
    218.500
    through 218.506 and 219.500 throu~h
    219.506,
    a noncontinuous operation in which a discrete auantitv
    or batch of feed is charged into a chemical manufacturina process
    unit and distilled or reacted, or otherwise used at one time, and
    may include, but is not limited to. reactors, filters. dryers.
    distillation columns, extractors. crystallizers, blend tanks.
    neutralizer
    tanks.
    digesters.
    surge tanks and product separators.
    After each batch operation. the eaui~mentis ~enerallv emptied
    before a fresh batch is started.
    (Source:
    Added
    at
    _____
    Ill.
    Reg.
    ,
    effective
    ______________________________________________________
    )
    Section 211.696
    Batch Process Train

    12
    “Batch
    ørocess
    train”
    means,
    for
    purposes
    of
    35
    Iii.
    Adm.
    Code
    Parts
    218
    and
    219,
    Sections 218.500 through 218.506 and 219.500
    through 219.506. the collection of equipment
    (e.g., reactors,
    filters. dryers. distillation columns,
    extractors, crystallizers,
    blend tanks,
    neutralizer tanks, digesters,
    surge tanks and
    product separators)
    confic~uredto produce a specific product or
    intermediate by a batch operation.
    A batch process train
    terminates at the point of storage or product handling of the
    product or intermediate being produced in the batch process
    train.
    Irrespective of the product being produced.
    a batch
    process train which is independent of other processes shall be
    considered a single batch process train for purposes of 35 Ill.
    Adm. Code Parts 218 and 219.
    (Source:
    Added at
    _____
    Ill. Reg.
    ,
    effective
    ____
    ____________________________________________________________
    )
    Section 211.5245
    Process Vent
    “Process
    vent”
    means~
    for
    purposes
    of
    35
    Ill.
    Adm.
    Code
    Parts
    218
    and 219. Sections 218.500 throu~h218.506 and 219.500 throu~h
    219.506,
    any non-fugitive source of VON emissions to the
    atmosphere resulting from non—combustion emission units.
    A
    process vent begins at the inlet to the control device. or in the
    absence of a control device. at the point of discharge to the
    atmosphere.
    This includes all emission units vents and stacks.
    Not included in this definition are exhaust streams from exhaust
    hoods and building ventilation fans which are sued to provide
    ventilation for workers and not to collect and discharge
    emissions from specific emission units.
    (Source:
    Added
    at
    _____
    Ill.
    Reg.
    ,
    effective
    ____
    _______________________________________________________
    )
    Section
    211.6025
    Single Unit Operation
    “Single
    unit
    operation”
    means,
    for
    purposes
    of 35 Ill. Adm. Code
    Parts 218 and 219. Sections 218.500 through 218.506 and 219.500
    through
    219.506.
    a distinct piece of equipment in a batch
    operation within which one or more discrete processing steps
    occur.
    Such discrete processing steps include, but are not
    limited to, the preparation of reactants.
    facilitation of
    reactions, separation and purification of products or
    intermediates,
    and
    recycling
    of
    materials.
    (Source~ Added at
    Ill. Reg.
    ,
    effective
    ____

    13
    TITLE
    35:
    ENVIRONMENTAL
    PROTECTION
    SUBTITLE
    B:
    AIR
    POLLUTION
    CHAPTER
    I:
    POLLUTION
    CONTROL
    BOARD
    SUBCHAPTER
    c:
    EMISSIONS
    STANDARDS
    AND
    LIMITATIONS
    FOR
    STATIONARY
    SOURCES
    PART
    218
    ORGANIC
    MATERIAL
    EMISSION
    STANDARDS
    AND
    LIMITATIONS
    FOR
    THE
    CHICAGO
    AREA
    SUBPART
    A:
    GENERAL
    PROVISIONS
    Section
    218.
    100
    218.101
    218.102
    218.103
    218.104
    218.105
    218. 106
    218.
    107
    218.
    108
    218.109
    218.
    110
    218.111
    218. 112
    218.113
    218.
    114
    Introduction
    Savings Clause
    Abbreviations and Conversion Factors
    Applicability
    Definitions
    Test Methods and Procedures
    Compliance
    Dates
    Operation of Afterburners
    Exemptions,
    Variations,
    and Alternative Means of
    Control or Compliance Determinations
    Vapor Pressure of Volatile Organic Liquids
    Vapor Pressure of Organic Material or Solvents
    Vapor Pressure of Volatile Organic Material
    Incorporations by Reference
    Monitoring for Negligibly-Reactive Compounds
    Compliance
    with
    Permit
    Conditions
    SUBPART B:
    ORGANIC EMISSIONS FROM STORAGE AND LOADING OPERATIONS
    Section
    218.119
    218.121
    218.122
    218.
    123
    218.124
    218.125
    218.126
    Applicability
    for
    VOL
    Storage Containers
    Loading Operations
    Petroleum Liquid Storage Tanks
    External Floating Roofs
    Compliance Dates
    (Repealed)
    Compliance Plan (Repealed)
    Separation Operations
    Pumps and Compressors
    Vapor Blowdown
    Safety Relief Valves
    Section
    218.141
    218.142
    218.143
    218. 144
    SUBPART
    C:
    ORGANIC
    EMISSIONS
    FROM
    MISCELLANEOUS
    EQUIPMENT

    14
    Emission Limitations
    Daily-Weighted
    Average
    Limitations
    Solids Basis Calculation
    Alternative Emission Limitations
    Exemptions from Emission Limitations
    Exemption from General Rule on Use of Organic Material
    Compliance Schedule
    Recordkeeping and Reporting
    SUBPART
    G:
    USE
    OF
    ORGANIC
    MATERIAL
    Use
    of
    Organic
    Material
    Alternative Standard
    Fuel Combustion Emission Units
    Operations with Compliance Program
    SUBPART H:
    PRINTING
    AND
    PUBLISHING
    Sect ion
    218.401
    218.402
    218.403
    218. 404
    218.
    405
    Section
    218.421
    218.422
    218.
    423
    218.424
    218.425
    218.426
    218.427
    218.428
    Flexographic and Rotogravure Printing
    Applicability
    Compliance Schedule
    Recordkeeping and Reporting
    Heatset-Web-Offset Lithographic Printing
    SUBPART
    Q:
    LEAKS
    FROM
    SYNTHETIC
    ORGANIC CHEMICAL AND
    POLYMER
    MANUFACTURING
    PLANT
    General Requirements
    Inspection Program Plan for Leaks
    Inspection Program for Leaks
    Repairing Leaks
    Recordkeeping for Leaks
    Report for Leaks
    Alternative Program for Leaks
    open—Ended Valves
    SUBPART
    E:
    SOLVENT
    CLEANING
    Solvent Cleaning in General
    Cold
    Cleaning
    Open
    Top
    Vapor
    Degreasing
    Conveyorized Degreasing
    Compliance Schedule (Repealed)
    Test Methods
    SUBPART
    F:
    COATING
    OPERATIONS
    Section
    218.181
    218.182
    218.183
    218.184
    218.185
    218.186
    Section
    218
    .
    204
    218.205
    218.206
    218.207
    218.208
    218.209
    218.210
    218.211
    Section
    218.301
    218.302
    218. 303
    218.304

    15
    218.429
    Standards for Control Devices
    218.430
    Compliance Date
    (Repealed)
    SUBPART
    P.:
    PETROLEUM
    REFINING
    AND
    RELATED
    INDUSTRIES;
    ASPHALT MATERIALS
    Section
    218.441
    218.442
    218.443
    218.444
    218.445
    218.446
    218.447
    218.448
    218.449
    218.
    450
    218.451
    218.452
    218.453
    Petroleum
    Refinery
    Waste
    Gas
    Disposal
    Vacuum Producing Systems
    Wastewater (Oil/Water)
    Separator
    Process
    Unit
    Turnarounds
    Leaks:
    General Requirements
    Monitoring Program Plan for Leaks
    Monitoring Program for Leaks
    Recordkeeping for Leaks
    Reporting for Leaks
    Alternative Program for Leaks
    Sealing Device Requirements
    Compliance Schedule for Leaks
    Compliance Dates
    (Repealed)
    SUBPART
    S:
    RUBBER
    AND
    MISCELLANEOUS PLASTIC PRODUCTS
    Manufacture of Pneumatic Rubber Tires
    Green Tire Spraying Operations
    Alternative Emission Reduction Systems
    Emission Testing
    Compliance Dates
    (Repealed)
    Compliance Plan (Repealed)
    SUBPART
    T:
    PHARMACEUTICAL
    MANUFACTURING
    Section
    218.480
    218.481
    218.482
    218. 483
    218. 484
    218.485
    218.486
    218.487
    218.488
    218.489
    Applicability
    Control of Reactors, Distillation Units,
    Crystallizers,
    Centrifuges and Vacuum Dryers
    Control of Air Dryers, Production Equipment Exhaust
    Systems and Filters
    Material Storage and Transfer
    In—Process Tanks
    Leaks
    Other Emission Units
    Testing
    Monitoring for Air Pollution Control Equipment
    Recordkeeping for Air Pollution Control Equipment
    SUBPART
    V:
    BATCH
    OPERATIONS
    AND
    AIR OXIDATION PROCESSES
    Section
    218. 500
    218.501
    ApPlicability for Batch operations
    Section
    218.461
    218.462
    218.463
    218. 464
    218.465
    218. 466
    Control Requirements for Batch Operatons

    16
    218.502
    218.503
    218.504
    218.505
    218.506
    218.521
    218.525
    218.526
    218. 527
    Section
    218.541
    Section
    218.561
    218.562
    218.563
    Section
    218.581
    218.582
    218.583
    218.584
    218.585
    218.586
    Determination of Uncontrolled Total Annual Mass
    Emissions and Average Flow Rate Values for Batch
    ODerations
    Performance
    and Testing Requirements for Batch
    Operations
    Monitoring
    Requiremsnts
    for
    Batch
    Operations
    RePorting and Recordkeeping for Batch Operations
    Compliance Date
    Definitions
    (Repealed)
    Emission
    Limitations
    for
    Air
    Oxidation
    Processes
    Testing
    and
    Monitoring
    Compliance Date (Repealed)
    SUBPART W:
    AGRICULTURE
    Pesticide Exception
    SUBPART X:
    CONSTRUCTION
    Architectural Coatings
    Paving Operations
    Cutback Asphalt
    SUBPART Y:
    GASOLINE DISTRIBUTION
    Bulk Gasoline Plants
    Bulk Gasoline Terminals
    Gasoline Dispensing Operations
    -
    Storage Tank Filling
    Operations
    Gasoline Delivery Vessels
    Gasoline Volatility Standards
    Gasoline Dispensing Operations
    -
    Motor Vehicle Fueling
    Operations
    SUBPART
    Z:
    DRY CLEANERS
    Section
    218.601
    218.602
    218.603
    218.604
    218.605
    218.606
    218.607
    218.608
    218.609
    218.610
    218.611
    218.612
    Perchloroethylene Dry Cleaners
    Applicability
    Leaks
    Compliance Dates
    (Repealed)
    Compliance Plan (Repealed)
    Exception to Compliance Plan
    (Repealed)
    Standards for Petroleum Solvent Dry Cleaners
    Operating Practices for Petroleum Solvent Dry Cleaners
    Program for Inspection and Repair of Leaks
    Testing and Monitoring
    Applicablity for Petroleum Solvent Dry Cleaners
    Compliance Dates (Repealed)

    17
    218.613
    Section
    218.620
    218.621
    218.623
    218.624
    218.
    625
    218.626
    218.628
    218.630
    218.636
    218.637
    Section
    218.640
    218.642
    218.644
    Compliance
    Plan
    (Repealed)
    SUBPART
    AA:
    PAINT
    AND
    INK
    MANUFACTURING
    Applicability
    Exemption for Waterbase Material and Heatset-Offset Ink
    Permit Conditions
    (Repealed)
    Open Top Mills, Tanks, Vats or Vessels
    Grinding Mills
    Storage Tanks
    Leaks
    Clean Up
    Compliance Schedule
    Recordkeeping and Reporting
    SUBPART
    BB:
    POLYSTYRENE
    PLANTS
    Applicability
    Emissions Limitation at Polystyrene Plants
    Emissions Testing
    SUBPART
    CC:
    POLYESTER
    RESIN
    PRODUCT MANUFACTURING PROCESS
    Section
    218.660
    218.666
    218.667
    218
    668
    218.670
    218.672
    Section
    218.680
    218.686
    218.688
    218.690
    218.692
    Section
    218.760
    218.762
    218 .764
    218.766
    218.768
    218.770
    218.875
    218.877
    Applicability
    Control Requirements
    Compliance Schedule
    Testing
    Recordkeeping and Reporting for Exempt Emission Units
    Recordkeeping
    and
    Reporting
    for
    Subject
    Emission
    Units
    SUBPART
    DD:
    AEROSOL CAN
    FILLING
    Applicability
    Control Requirements
    Testing
    Recordkeeping and Reporting for Exempt Emission Units
    Recordkeeping and Reporting for Subject Emission Units
    SUBPART GG:
    MARINE TERMINALS
    Applicability
    Control Requirements
    Compliance Certification
    Leaks
    Testing and Monitoring
    Recordkeeping and Reporting
    Applicability of Subpart BB (Renumbered)
    Emissions Limitation at Polystyrene Plants
    (Renumbered)

    18
    218.879
    218.881
    218.883
    218.886
    Compliance Date (Repealed)
    Compliance Plan (Repealed)
    Special Requirements for Compliance Plan
    (Repealed)
    Emissions
    Testing
    (Renumbered)
    SUBPART PP:
    MISCELLANEOUS FABRICATED PRODUCT MANUFACTURING
    PROCESSES
    Section
    218.920
    218.
    923
    218.926
    218.927
    218.928
    Applicability
    Permit Conditions
    (Repealed)
    Control Requirements
    Compliance Schedule
    Testing
    SUBPART
    QQ:
    MISCELLANEOUS FORMULATION MANUFACTURING PROCESSES
    Section
    218.940
    218.943
    218.946
    218.947
    218.948
    Applicability
    Permit Conditions
    (Repealed)
    Control
    Requirements
    Compliance Schedule
    Testing
    SUBPART
    RR:
    MISCELLANEOUS
    ORGANIC
    CHEMICAL
    MANUFACTURING
    PROCESSES
    Section
    218.960
    218.963
    218.966
    218.967
    218.968
    Section
    218.980
    2 18.983
    218.986
    218.987
    218.988
    Section
    218.990
    218.991
    Section
    Applicability
    Permit Conditions
    (Repealed)
    Control Requirements
    Compliance Schedule
    Testing
    SUBPART
    TT:
    OTHER
    EMISSION
    UNITS
    Applicability
    Permit
    Conditions
    (Repealed)
    Control Requirements
    Compliance Schedule
    Testing
    SUBPART UU:
    RECORDKEEPING AND
    REPORTING
    Exempt Emission Units
    Subject Emission Units
    218.Appendix A:
    List of Chemicals Defining Synthetic
    Organic Chemical and Polymer
    Manufacturing

    19
    Section 218.Appendix
    B:
    VOM
    Measurement
    Techniques
    for
    Capture
    Efficiency
    Section 218.Appendix
    C:
    Reference Test Methods for Air Oxidation
    Processes
    Section
    218.Appendix
    D:
    Coefficients
    for
    the Total Resource
    Effectiveness
    Index
    (TRE)
    Equation
    Section
    218.Appendix
    E:
    List
    of Affected Marine Terminals
    AUTHORITY:
    Implementing Section 10 and authorized by Section
    28.5 of the Environmental Protection Act
    (Ill. Rev.
    Stat.
    1991,
    ch.
    111½,
    par.
    1010)
    (P.A.
    87—1213,
    effective
    September
    26,
    1992)
    415
    ILCS
    5/10
    and
    28.5.
    SOURCE:
    Adopted
    at
    R91-7
    at
    15
    Ill.
    Reg.
    12231,
    effective August
    16,
    1991;
    amended in P.91—23 at 16 Ill. Reg.
    13564,
    effective
    August 24,
    1992;
    amended in
    P.91—28 and P.91-30 at
    16 Ill. Reg.
    13864, effective August 24,
    1992;
    amended in P.93—9 at 17 Ill.
    Reg.
    16636, effective September 27,
    1993;
    amended
    in
    R93—14
    at
    18
    Ill.
    Reg.
    at
    1945,
    effective
    January
    24,
    1994;
    amended
    in
    P.94—12
    at 18
    Ill. Reg.
    14973, effective September 21,
    1994; amended in
    R94-15 at
    18
    Ill. Reg.16379,
    effective November 4,
    1994; amended
    in R94—~
    at
    ~li
    Ill. Reg.
    ,
    effective
    __________________
    amended
    in
    R94-~
    at
    ~
    Ill.
    Reg.
    ,
    effective
    ____________
    SUBPART V:
    BATCH OPERATIONS AND AIR OXIDATION PROCESSES
    Section 218.500
    Applicability for Batch Operations
    ~
    The control requirements set forth in Section 218.501
    of
    this
    Subpart
    shall
    apply
    to:
    3j
    Process vents associated with batch operations at
    sources identified by any of the following
    four—
    digit standard industrial classification I”SIC”)
    codes,
    as defined in the
    1987
    edition
    of
    the
    Federal Standard Industrial Classification Manual:
    SIC 2821.
    2833,
    2834,
    2861.
    2865,
    2869.
    and 2879
    and
    •All batch operations at Stepan ComPany’s Milisdale
    manufacturing facility. Elwood, Illinois.
    ~
    The requirements of Sections 218.500 through 218.506
    shall not a~~lvto:
    jj
    Any emission unit included within the category
    specified in 35 Iii.
    Adin.
    Code Part 218.
    Subparts
    BorT
    21
    Any
    emission unit included within the category
    specified in Sections 218.520 through 218.527 of

    20
    this
    Subpart;
    and
    ~j.
    Any emission unit included within an Early
    Reduction Program, as specified in 40 CFR Part 63,
    and published in 57 Fed.
    Req.
    61970
    (December 29,
    1992). evidenced by a timely enforceable
    commitment approved bY USEPA.
    ci
    The following single unit operations and batch process
    trains are subject to this Subpart but are considered
    to be de minimis and are, therefore,
    exempt from the
    control requirements of Section 218.501 of this
    Subpart.
    However, the recordkeeping and reporting
    requirements
    in
    Section
    218.505
    of
    this
    Subpart
    shall
    apply to such de minimis single unit operations and
    batch
    process
    trains:
    fl
    Within a batch operation,
    any single unit
    operation
    with
    uncontrolled
    total
    annual mass
    emissions of less than or equal to
    500
    lb/yr
    of
    VON.
    Such single unit operations are also
    excluded from the calculation of the total annual
    mass emissions for a batch process train.
    If the
    uncontrolled total annual mass emissions from such
    exempt
    single
    unit
    o~erption
    exceed
    500 lb/yr of
    VON in any subsequent year. the source shall
    calculate applicability in accordance with
    subsection
    Cd)
    of this Section for both the
    individual single unit operation and the batch
    process train containing the single unit
    operation; and
    ~J...
    Any
    batch process train containing process vents
    that have,
    in the aggregate, uncontrolled total
    annual mass emissions,
    as determined in accordance
    with Section 218.502(a)
    of this Subpart. of less
    than 30.000 lb/yr of VON for all products
    manufactured in such batch process train.
    ~j
    The a~p1icabi1itvequations in subsection
    (e) of this
    Section, which require the calculation of uncontrolled
    total annual mass emissions and flow rate value,
    shall
    be used to determine whether a single unit operation or
    a batch process train is subiect to the control
    requirements set forth in Section 218.501 of this
    Subpart. The applicability equation shall be applied to
    the following:
    fl
    Any single unit operation with uncontrolled total
    annual mass emissions that exceed 500 lb/yr and
    with a VON concentration greater than 500 ~mv.
    In this individual determination, no a~plicabilitv

    21
    analysis shall be performed for any sir~g1eunit
    operation with a VON concentration
    of less than or
    equal
    to
    500
    ~pmv;
    and
    21
    Any
    batch
    Process
    train
    containing
    process
    vents
    which,
    in the aggregate. have uncontrolled total
    annual mass emissions of 30,000
    lb/yr or more of
    VOM from all products manufactured in the batch
    process train.
    Any single unit operation with
    uncontrolled
    total
    annual
    mass
    emissions
    exceeding
    500
    lb/yr.
    re~ard1ess
    of VON concentration, shall
    be
    included
    in
    the
    a~~re~ate
    applicability
    analysis.
    ci
    A~~licabi1itvequations
    ~j.
    The
    applicability
    equations
    in
    this
    subsection
    are
    specific
    to
    volatility.
    21
    For
    Purposes
    of
    this subsection, the following
    abbreviations
    a~~ly:
    =
    Vent
    stream
    flow
    rate.
    scfm
    ~j
    UTANE
    =
    Uncontrolled total annual mass
    emissions of VON. expressed as
    lb/yr
    Q1
    WAV
    =
    Weiahted avera~evolatility
    Q1
    MVOM~
    =
    Mass of VON component
    i; and
    ~j
    MWVOM~=
    Molecular weight of VON component
    i;
    and
    11
    3~
    =
    Vapor pressure of VON component
    j.
    ~j
    Weighted average volatility shall be calculated as
    follows:
    n
    (MVOM~1)
    E
    (VP1)x
    )
    i=1
    (NWVOM1)
    WAV
    =
    n
    (
    (MVOM~)
    3
    3
    i=1
    (
    (MWVON~)
    ~
    Yor purposes of determining applicability, flow
    rate values shall be calculated as follows:

    22
    ~
    Low
    WAV
    has
    a
    vapor
    pressure
    less
    than
    or
    equal to 75
    mmHg
    at 20°C (68°F).and shall
    use the following equation:
    FR
    =
    10.07
    (UTANE)
    1,821
    ~
    Moderate WAV has a vapor pressure greater
    than
    75
    inxnHg
    but
    less
    than
    or
    equal
    to
    150
    minHg
    at
    20°C
    (68°F).
    and shall use the
    following equation:
    FR
    =
    10.031
    (UTANE)
    494
    gj
    High WAV has a vapor pressure areater than
    150
    ininHg at 20°C (68°F). and shall use the
    following equation:
    FR
    =
    0.013
    (UTAME)
    301
    ~J
    To determine the vapor pressure of VON, the
    applicable methods and procedures
    in Section
    218.111 of this Part shall apply.
    (Source:
    Added at
    Ill.
    Reg.
    _______,
    effective
    Section 218.501
    Control Requirements
    for Batch Operations
    ~j.. Every owner or operator of a single unit operation with
    an average flow rate,
    as determined in accordance with
    Section 218.502(b) of this Subpart. below the flow rate
    value calculated by the applicability equations
    contained in Section 218.500(e)
    of this Subpart, shall
    reduce uncontrolled VON emissions from such single unit
    operation by an overall efficiency, on average,
    of at
    least 90 percent. or 20 ppmv, per batch cycle.
    ~j
    Every owner or operator of a batch process train with
    an
    average
    flow
    rate,
    as
    determined
    in
    accordance
    with
    Section 218.502(b) (2) of this Subpart, below the flow
    rate value calculated bY the applicability equations
    contained in Section 218.500(e) of this Subpart, shall
    reduce uncontrolled VON emissions from such batch
    process train by an overall efficiency, on average, of
    at least 90 percent. or 20 p~mv.~er batch cycle.
    For
    purposes of demonstrating compliance with the emission
    limitations set forth in this Section. any control
    device meeting the criteria in subsection
    (c) of this
    Section shall be deemed to achieve a control efficiency
    of 90 percent. or 20 p~mv.per batch cycle,
    as
    applicable.

    23
    ci
    Notwithstanding subsections
    (a)
    or
    (b)
    of
    this
    Section~
    any
    source
    that
    has
    installed
    on
    or
    before
    March
    15,
    1995,
    any
    control
    device
    which
    is demonstrated to the
    Agency’s satisfaction to be unable to meet the
    applicable control requirements of this Section,
    scrubber,
    or
    shell
    and
    tube
    condenser using a non-
    refrigerated cooling media, and such device achieves at
    least 81 Percent control efficiency of VON emissions.
    is
    required
    to
    meet
    the
    90
    percent
    emission
    limitation
    or
    20
    p~inv
    VON
    concentration
    set
    forth
    in
    subsections
    (a)
    or
    (b)
    of
    this
    Section,
    as applicable, upon the
    earlier to occur of the date the device is replaced for
    any reason, including, but not limited to, normal
    maintenance, malfunction,
    accident, and obsolescence,
    or
    December
    31,
    1999.
    A
    scrubber.
    shell
    and
    tube
    condenser using a non—refrigerated cooling media,
    or
    other control device meeting the criteria of this
    subsection
    is considered replaced when:,
    31
    All
    of
    the
    device
    is replaced; or
    21
    When
    either
    the
    cost
    to
    repair
    the
    device
    or
    the
    cost to replace cart of the device exceeds 50
    percent of the cost of replacing the entire device
    with a control device that complies with the 90
    Percent emission limitation or 20 ~pmv VON
    concentration level in subsection
    (a) of this
    Section.
    as applicable.
    ~.
    If
    a boiler or process heater is used to comply with
    this Section. the vent stream shall be introduced into
    the flame zone of the boiler or Process heater.
    ~
    If a flare is used to com~lvwith this Section.
    it
    shall comply with the reauirements of 40 CFR 6O.18.~
    incorporated by reference at Section 218.112 of this
    Part.
    The flare operation requirements of 40 CFR 60.18
    do not apply
    if a process. not subiect to this Subpart,
    vents an emergency relief discharge into a common flare
    header and causes the flare servicing the process
    subject to this Subpart to not comply with one or more
    of ths provisions of 40 CFR 60.18.
    (Source:
    Added at
    _____
    111. Reg.
    ,
    effective
    ______
    ______________________________________________
    )
    Section 218.502
    Determination of Uncontrolled Total Annual
    Mass Emissions and Average Flow Rate Values
    for Batch Operations
    ,~j
    Uncontrolled total annual mass emissions shall be
    determined by the following methods:

    24
    ~,j
    Direct process vent emissions measurements taken
    prior to any release to the atmosphere.
    following
    any recovery device and prior to anY control
    device, provided such measurements conform with
    the requirements of measuring the mass flow rate
    of VON incoming to the single unit operation as
    set forth in Section 218.503(f) (2),
    (f) (3)(A)
    and
    (f) (3) (B)
    of this Subpart; or
    21
    Engineering estimates of the uncontrolled VON
    emissions from
    a process vent or process vents,
    in
    the aggregate1 within a batch process train.
    multiplied by the potential or permitted number of
    batch cycles Per Year as follows:
    ~
    Engineering estimates of the uncontrolled VON
    emissions shall be based upon accented
    chemical engineering principles, measurable
    process parameters.
    or physical or chemical
    laws and their properties.
    Examples of
    methods include, but are not limited to, the
    following:
    LL
    Use of material balances based on
    process stoichiometry to estimate
    maximum VOM concentrations
    jJJ,
    Estimation of maximum flow rate based on
    physical eaui~mentdesign such as
    pump
    or blower capacities; and
    iii) Estimation of VOM concentrations based
    on saturation conditions.
    ~j
    All data, assumptions and Procedures used in
    any engineering estimate shall be documented.
    ~
    Average flow rate shall be determined by any of the
    following methods:
    31
    Direct process vent flow rate measurements taken
    prior to any release to the atmosphere, following
    anY recovery device and prior to any control
    device, provided such measurements conform with
    the requirements of measuring incoming volumetric
    flow rate set forth in Section 218.503(e) (2) of
    this SubDart
    21.
    Averaae flow rate for a single unit operation
    havina multiple emission events or batch process
    trains shall be the weighted average flow rate,
    calculated as follows:

    25
    n
    E
    AFR~
    x
    ADE1)1
    i=1
    WAF
    =
    _____________
    n
    E
    (ADE~1
    i=1
    where:
    =
    Actual weighted average flow
    rate for a single unit
    operation or batch process
    train;
    AFR~
    =
    Average flow rate per emission
    event:
    =
    Annual duration of emission
    event;
    and
    n
    =
    Number of emission events.
    31
    Engineering estimates calculated in accordance
    with the requirements in subsection
    (a) (2) of this
    Section.
    ~j
    For purposes of determining the average flow rate for
    steam vacuuming systems~ the steam flow shall be
    included in the average flow rate calculation.
    (Source:
    Added at
    ____
    Ill. Reg.
    ______,
    effective
    ______
    I
    Section 218.503
    Performance and Testing Requirements for
    Batch Operations
    ~
    UPon the Agency’s request, the owner or operator of a
    batch operation shall conduct testing to demonstrate
    compliance with Section 218.501 of this Subpart.
    The
    owner or operator shall, at its own expense, conduct
    such tests in accordance with the applicable test
    methods and procedures specified in Section 218.503(d),
    (e). and
    (f) of this Subpart.
    ~
    Notwithstanding subsection
    (a) of this Section.
    flares
    and_Process boilers used to comply with control
    requirements of Section 218.501 of this Subpart shall
    be exempt from performance testing requirements.
    ci
    When a flare is used to com~lvwith the control
    i~equirementsof Section 218.501 of this Subpart. the
    flare
    shall
    comply
    with the requirements of 40 CFR
    60.18.
    incorporated by reference at Section 218112
    of
    this Part.

    26
    ~
    The owner
    or operator of a batch operation that
    is
    exempt from the control requirements
    of Section 218.501
    of this Subpart shall demonstrate,
    upon the Agency’s
    request, the absence of oversized gas moving equipment
    in any manifold.
    Gas moving eauipment shall be
    considered oversized if
    it exceeds the maximum
    requirements
    of the exhaust
    flow rate by more than
    30
    percent.
    ci
    For the purpose of demonstrating compliance with the
    control requirements in Section 218.501 of this
    Subpart. the batch operation shall be run at
    representative operating conditions and flow rates
    during any performance test.
    fl
    The following methods
    in 40 CFR 60. Appendix A.
    incorporated by reference at Section 218.112 of this
    Part,
    shall be used to demonstrate com~1iancewith the
    reduction efficiency requirement set forth in Section
    218.501 of this Subpart:
    31
    Method
    1 or 1A, as ap~roprjate, for selection of
    the sam~1ingsites if the flow measuring device is
    not a rotameter.
    The control device inlet
    sampling site for determination of vent stream VOM
    composition reduction efficiency shall be prior to
    the control device and after the control device
    21.
    Method
    2.
    2A.
    2C. or 2D. as appropriate, for
    determination of gas stream volumetric flow rate
    flow measurements, which shall be taken
    continuously.
    No traverse is necessary when the
    flow measuring device is an ultrasonic probe
    .
    31
    Method 25A or Method 18
    if applicable, to
    determine the concentration of VOM in the control
    device inlet and outlet
    ~
    The sampling time for each run will be the
    entire length of the batch cycle in which
    readings shall be taken continuously,
    if
    Method 25A is used,
    or as often as
    is
    possible using Method 18, with a maximum of
    15—minute intervals between measurements
    throughout the batch cycle
    ~j
    The mass emission rate from the process vent
    or inlet to the control device shall be
    determined by combining concentration and
    flow rate measurements taken simultaneously
    at sampling sites selected in accordance with
    subsection
    (f) (1) of this Section throughout

    27
    the batch cycle
    ~1
    The mass emission rate from the control
    device outlet shall be obtained by combining
    concentration and flow rate measurements
    taken simultaneously at sampling sites
    selected in accordance with subsection
    (f) (1)
    of this Section throughout the batch cycle
    and
    Q),.
    The efficiency of the control device shall be
    determined by integrating the mass emission
    rates obtained in subsections
    Cc) (3) (A)
    and
    (c)_(3)_(3) of this Section, over the time of
    the batch cycle and dividing the difference
    in inlet and outlet mass flow totals by the
    inlet mass flow total.
    ci
    Upon request bY the Agency to conduct t~esting,an owner
    or operator of a batch operation which has installed
    a
    scrubber,
    a shell and tube condenser using a non—
    refrigerated cooling media, or anY other control device
    which meets the criteria of Section 218.501(c)
    of this
    Subpart, shall demonstrate that such device achieves
    the control efficiency applicable within Section
    218.501 of this Subpart upon the earlier to occur of
    the date the device is replace or December 31,
    1999.
    ~
    The owner or operator of a batch operation may propose
    an alternative test method or procedures to demonstrate
    compliance with the control requirements set forth in
    Section 218.501 of this Subpart.
    Such method or
    procedures shall be approved by the A~encvand USEPA as
    evidenced by federally enforceable permit conditions.
    (Source:
    Added at
    _____
    Ill. Reg.
    ______,
    effective
    ______
    Section 218.504
    Monitoring Requirements for Batch Operations
    ~j.. Every owner or operator usina an afterburner to comely
    with Section 218.501 of this Subpart, shall install.
    calibrate, maintain and operate, according to
    manufacturer’s specifications, temperature monitoring
    devices with an accuracY of ±1 Percent of the
    temperature being measured expressed in dearees
    Celsius, equipped with continuous recorders.
    j~j
    Where
    a catalytic afterburner is used. temperature
    monitoring devices shall be installed in
    the
    gas
    stream immediately before and after the catalyst
    bed.

    28
    al
    Where an afterburner other than a catalytic
    afterburner
    is used,
    a temperature monitoring
    device shall be
    installed in the combustion
    chamber.
    ~
    Every owner or operator using a flare to comely with
    Section 218.501 of
    this Subpart, shall install,
    calibrate, maintain and operate,
    according to
    manufacturer’s specifications,
    a heat sensing device,
    such as an ultra—violet beam sensor or thermocouple,
    at
    the pilot light to indicate continuous presence of a
    flame.
    ci
    Every owner or operator using a scrubber to comply with
    this Section 218.501 of this Subpart, shall install,
    calibrate, maintain, and operate. according to
    manufacturer’s specifications, the following:
    31
    A temperature monitoring device for scrubbant
    liquid having an accuracy of ±1 percent of the
    temperature being monitored expressed in degrees
    Celsius and a specific gravity device for
    scrubbant liquid, each equipped with
    a continuous
    recorder; or
    21
    A VON monitoring device used to indicate the
    concentration of VOM exiting the control device
    based on a detection principle such as infra—red
    photoionization.
    or thermal conductivity, each
    equipped with a continuous recorder.
    ~j
    Every owner or operator using a condenser to comply
    with Section 218.501 of this Subpart. shall install.
    calibrate, maintain, and operate. according to
    manufacturer’s specifications, the following:
    31
    A condenser exit temperature monitoring device
    equipped with a continuous recorder and having an
    accuracy of ±1 percent of the temperature being
    monitored expressed in degrees Celsius; or
    21
    A VOM monitoring device used to indicate the
    concentration of VON such as infra—red.
    ~hotoionization,
    or thermal conductivity, each
    equipped with a continuous recorder.
    ~
    Every owner or operator using a carbon adsorber to
    com~lvwith this Subpart shall install, calibrate,
    maintain.
    and operate, according to the manufacturer’s
    specifications the following equipment:
    31
    An integrating regeneration stream flow monitoring

    29
    device having an accuracy of ±10 percent. and a
    carbon bed temperature monitoring device having an
    accuracy of ±1 percent of the temperature being
    monitored exPressed in degrees Celsius. both
    equi~~ed with
    a
    continuous
    recorder;
    or
    21
    A VOM monitoring device used to indicate the
    concentration level or VOM exiting such device
    based on a detection principle such as infra—red,
    photoionization,
    or thermal conductivity, each
    eguipped with a continuous recorder.
    ,fj
    Every owner or oPerator using a boiler or process
    heater with a design heat input capacity less than 44
    MW_to_com~lvwith Section 218.501 of this Subpart.
    shall install, calibrate, maintain, and operate,
    according to the manufacturer’s specifications.
    a
    temperature monitoring device in the firebox with an
    accuracy of ±1 percent of the temperature being
    measured expressed in degrees Celsius. equipped with a
    continuous recorder.
    Any boiler or process heater
    in
    which all process vent streams are introduced with
    primary fuel is exempt from this reauirement.
    ci
    The owner or operator of a process vent shall be
    permitted to monitor by an alternative method or may
    monitor Parameters other that those listed in
    subsections
    (a) through
    (f) of this Section.
    if
    a~~rovedby the Aaencv and USEPA.
    Such alternative
    method or parameters shall be contained in the source’s
    operating permit as federally enforceable permit
    conditions.
    ~
    Notwithstanding subsections
    (a) through
    (g)
    of this
    Section, sources using a scrubber, shell and tube
    condenser using a non—refrigerated cooling media,
    or
    other control device meeting the criteria of Section
    218.501(c)
    of this Subpart, are required to monitor
    compliance with the requirements of this SubPart on and
    after the earlier to occur of the date such device is
    replaced for any reason or December 31.
    1999.
    (Source:
    Added at
    Ill. Reg.
    ,
    effective
    _______
    Section 218.505
    Reporting and Recordkeepin~for Batch
    Operations
    ~j
    Every owner or operator of a de ininimis single unit
    operation or batch process train exemPt under Section
    218.500(c) (1) or
    (c) (2) of this Subpart, shall keep
    records of the uncontrolled total annual mass emissions

    30
    for any de minimis single unit operation or batch
    process train,
    as applicable,
    and documentation
    verifying these values or measurements.
    The
    documentation shall include the enqineering
    calculations or measurements coupled with the potential
    or permitted number of batch cycles Per year if the
    uncontrolled total annual mass emissions is obtained
    from measurements made in accordance with Section
    218.503 of this Subpart.
    ~
    Every owner or operator of a single unit operation
    exemPt under Sections 218.500(b) (3) or
    (d) of this
    Subpart shall keen the following records:
    31
    The uncontrolled total annual mass emissions and
    documentation verifying these values or
    measurements.
    The documentation shall include the
    calculations or measurements coupled with the
    permitted or permitted number of emission events
    per year if the uncontrolled total annual mass
    emissions is obtained from measurements made in
    accordance with Section 218.~503of this Subpart;
    and
    21
    The average flow rate
    in scfm and documentation
    verifying this value.
    ci
    Every owner or operator of a batch operation subiect to
    the control requirements of Section 218.501 of this
    Subpart shall keep records of the following parameters
    required to be monitored under Section 218.504 of this
    Subpart:
    31
    If using a thermal or catalytic afterburner to
    comply with Section 218.501 of this Subpart.
    records indicating the average combustion chamber
    temPerature of the afterburner
    (or the average
    temPerature upstream and downstream of the
    catalyst bed for a catalytic afterburner)
    measured continuously and averaaed over the same
    time period as the performance test
    2.1
    If using a flare
    (i.e.. stream—assisted, air—
    assisted or nonassisted) to comply with Section
    218.501 of this Subpart. continuous records of the
    flare pilot flame monitoring and records of all
    periods of operations during which the pilot flame
    is absent.
    For purposes of determining compliance
    with 40 CFR 60.18.
    incorporated by reference at
    218.112 of this Part.
    records shall also be kent
    indicating heat content determinations,
    flow rate
    measurements and the exit velocity determinations.

    31
    31
    If using any of the following as a control device,
    the following records:
    ~
    Where a scrubber is used, the exit specific
    gravity
    (or alternative parameter which is a
    measure of the degree of absorbing liauid
    saturation,
    if a~Provedby the Aaencv) and
    the average exit temperature of the absorbing
    liquid, measured continuously and averaaed
    over the same time period as the performance
    test
    (both measured while the vent stream
    is
    routed normally)
    ~j.
    Where a condenser is used, the average exit
    (product side)
    temperature measured
    continuously and averaaed over the same time
    period as the performance test while the vent
    stream is routed normally
    ci
    Where a carbon adsorber is used, the total
    stream mass flow measured continuously and
    averaged over the same time period as the
    performance test
    (full carbon bed cycle).
    temperature of the carbon bed after
    regeneration
    (and within 15 minutes of
    completion of any cooling cycle(s)), and
    duration of the carbon bed steaming cycle
    (all measured while the vent stream
    is routed
    normally); or
    j~j
    As an alternative to subsections
    (c) (3) (A).
    (c) (3) (B). or
    (c) (3) (C)
    of this Section, at a
    minimum, records indicating the concentration
    level or reading indicated by the VON
    monitoring device at the outlet of the
    scrubber,
    condenser, or carbon adsorber,
    measured continuously and averaged over the
    same time period as the performance test
    (while the vent stream is routed normally).
    ~
    Every owner or operator of an single unit operation
    claiming a vent stream concentration exemption level,
    as set forth in Section 218.500(d) (1) of this Subpart,
    shall maintain records to indicate the vent stream
    concentration is less than or e~al to 500 ppmv. and
    shall notify the Agency in writing if the vent stream
    concentration at any time e~a1sor exceeds 500 pPmv.
    within 30 days of such event.
    Such notification shall
    include a copy of all records of such event.
    ~
    owner or operator of a batch operation subiect to
    the control requirements of Section 218.501 of this

    32
    Subpart may maintain alternative records other than
    those listed in subsection
    (c)
    of this Sectthn.
    AnY
    alternative recordkeepin~shall be approved
    bv
    the
    Agency and USEPA and shall be contained in the source’s
    operating permit as federally enforceable permit
    conditions.
    ~j
    Notwithstanding subsections
    (a) throu~h (f I
    of this
    Section. anY owner or operator of
    a batch operation
    which uses either a scrubber,
    shell and tube condenser
    using non—refriqerated cooling media, or other control
    device meeting the criteria of Section 218.501(c)
    of
    this Subpart, are required to monitor compliance with
    the requirements of this Subpart on and after the
    earlier to occur of the date such device is replaced
    for any reason or December 31,
    1999.
    ~
    The owner or operator of a de minimis single unit
    qperation or batch process train exempt from the
    control requirements of Section 218.501(c) of this
    Subpart shall notify the A~encvin writing if the
    uncontrolled total annual mass emissions from such de
    minimis sing~leunit operation or batch process train
    exceed the threshold in Section 218.501(c) (1) or
    (c) (2)
    of this Subpart. respectively. within 60 days after the
    event occurs.
    Such notification shall include a copy
    of all records of such event.
    ~
    Every owner or operator of a batch operation required
    to keep records under this Section shall maintain such
    records at the source for a minimum Period of three
    y~rs and shall make all such records available to the
    Agency upon request.
    (Source:
    Added at
    _____
    Ill. Reg.
    _______,
    effective
    _______
    Section 218.506
    Compliance Date
    Every owner or operator of a batch operation subiect to Sections
    218.500 through 218.506 of this Subpart shall comply with its
    standards.
    limitations and mandates by March
    15,
    1996.
    or uPon
    initial start up. whichever is later.
    (Source:
    Added at
    _____
    Ill. Reg.
    _______,
    effective
    _______

    33
    TITLE
    35:
    ENVIRONMENTAL PROTECTION
    SUBTITLE B:
    AIR POLLUTION
    CHAPTER
    I:
    POLLUTION CONTROL BOARD
    SUBCHAPTER
    C:
    EMISSIONS STANDARDS AND LIMITATIONS
    FOR STATIONARY SOURCES
    PART
    219
    ORGANIC MATERIAL EMISSION STANDARDS
    AND LIMITATIONS FOR THE
    METRO
    EAST AREA
    SUBPART
    A:
    GENERAL PROVISIONS
    Section
    219.100
    219.101
    219. 102
    219.103
    219 .104
    219.105
    219.106
    219.107
    219. 108
    219.109
    219.110
    219.111
    219.112
    219.113
    219.114
    Introduction
    Savings Clause
    Abbreviations and Conversion Factors
    App?icabi1ity
    Definitions
    Test Methods and Procedures
    Compliance Dates
    Operation of Afterburners
    Exemptions, Variations, and Alternative Means of
    Control or Compliance Determinations
    Vapor Pressure of Volatile Organic Liquids
    Vapor Pressure of Organic Material or Solvents
    Vapor Pressure of Volatile Organic Material
    Incorporations by Reference
    Monitoring for Negligibly—Reactive Compounds
    Compliance with Permit Conditions
    SUBPART B:
    ORGANIC EMISSIONS FROM STORAGE
    AND
    LOADING OPERATIONS
    Section
    219.119
    219.121
    219.122
    219.123
    219.124
    219.125
    219.126
    Applicability for VOL
    Storage Containers
    Loading Operations
    Petroleum Liquid Storage Tanks
    External Floating Roofs
    Compliance Dates
    (Repealed)
    Compliance Plan (Repealed)
    SUBPART
    C:
    ORGANIC
    EMISSIONS
    FROM
    MISCELLANEOUS
    EQUIPMENT
    Section
    219.141
    219.142
    219.143
    219.144
    Separation Operations
    Pumps and Compressors
    Vapor Blowdown
    Safety Relief Valves
    SUBPART E:
    SOLVENT CLEANING
    Section

    34
    219. 181
    219. 182
    219. 183
    219. 184
    219. 185
    219. 186
    Section
    219.204
    219.205
    219.206
    219.207
    219.208
    219.209
    219.210
    219.211
    Section
    219.301
    219.302
    219.303
    219.304
    Section
    219.401
    219.402
    219.403
    219.404
    219.405
    Section
    219.421
    219.422
    219
    423
    219.424
    219.425
    219.426
    219
    427
    219.428
    219.429
    219.430
    Solvent Cleaning in General
    Cold Cleaning
    Open Top Vapor Degreasing
    Conveyorized Degreasing
    Compliance Schedule
    (Repealed)
    Test Methods
    SUBPART
    F:
    COATING OPERATIONS
    Emission Limitations
    Daily-Weighted
    Average Limitations
    Solids Basis Calculation
    Alternative Emission Limitations
    Exemptions from Emission Limitations
    Exemption from General Rule on Use of Organic Material
    Compliance Schedule
    Recordkeeping and Reporting
    SUBPART G:
    USE OF ORGANIC MATERIAL
    Use of Organic Material
    Alternative Standard
    Fuel Combustion Emission Units
    Operations with Compliance Program
    SUBPART H:
    PRINTING
    AND
    PUBLISHING
    Flexographic and Rotogravure Printing
    Applicability
    Compliance Schedule
    Recordkeeping and Reporting
    Heatset-Web-Offset Lithographic Printing
    SUBPART
    Q:
    LEAKS
    FROM SYNTHETIC
    ORGANIC CHEMICAL AND
    POLYMER
    MANUFACTURING
    PLANT
    General Requirements
    Inspection Program Plan for Leaks
    Inspection Program for Leaks
    Repairing Leaks
    Recordkeeping for Leaks
    Report for Leaks
    Alternative Program for Leaks
    Open-Ended Valves
    Standards
    for Control Devices
    Compliance Date (Repealed)

    35
    SUBPART
    R:
    PETROLEUM
    REFINING
    AND
    RELATED
    INDUSTRIES;
    ASPHALT
    MATERIALS
    Section
    219.441
    219. 442
    219.443
    219.444
    219.445
    219.446
    219.447
    219.448
    219.449
    219.450
    219.451
    219.452
    219.453
    Petroleum Refinery Waste Gas Disposal
    Vacuum Producing Systems
    Wastewater
    (Oil/Water) Separator
    Process Unit Turnarounds
    Leaks:
    General Requirements
    Monitoring Program Plan for Leaks
    Monitoring Program for Leaks
    Recordkeeping for Leaks
    Reporting for Leaks
    Alternative Program for Leaks
    Sealing Device Requirements
    Compliance Schedule for Leaks
    Compliance Dates
    (Repealed)
    SUBPART 5:
    RUBBER
    AND
    MISCELLANEOUS PLASTIC PRODUCTS
    Section
    219.461
    219.462
    219.463
    219.464
    219.465
    219.466
    Section
    219.480
    219.481
    219.482
    219.483
    219.484
    219.485
    219.486
    219.487
    219.488
    219.489
    Manufacture of Pneumatic Rubber Tires
    Green Tire Spraying Operations
    Alternative Emission Reduction Systems
    Emission Testing
    Compliance Dates
    (Repealed)
    Compliance Plan (Repealed)
    SUBPART T:
    PHARMACEUTICAL MANUFACTURING
    Applicability
    Control of Reactors, Distillation Units, Crystallizers,
    Centrifuges and Vacuum Dryers
    Control of Air Dryers, Production Equipment Exhaust
    Systems and Filters
    Material Storage and Transfer
    In—Process Tanks
    Leaks
    Other Emission Units
    Testing
    Monitoring for Air Pollution Control Equipment
    Recordkeeping for Air Pollution Control Equipment
    SUBPART V:
    BATCH OPERATIONS
    AND
    AIR OXIDATION PROCESSES
    Section
    219.500
    219.501
    219.502
    Ap~licabi1itvfor Batch Operations
    Control Requirements
    for Batch Operations
    Determination of Uncontrolled Total Annual Mass
    Emissions and Actual Weighted Average Flow Rate Values
    for Batch Operations

    36
    219.503
    Performance and Testing Requirements for Batch
    Operations
    Monitoring Requirements for Batch Operations
    Reporting and Recordkeeping for Batch Operations
    Compliance Date
    Definitions
    (Repealed)
    Emission Limitations for Air Oxidation Processes
    Testing and Monitoring
    Compliance Date (Repealed)
    SUBPART W:
    AGRICULTURE
    Section
    219.541
    Pesticide Exception
    SUBPART X:
    CONSTRUCTION
    Section
    219.581
    219.582
    219.583
    219.584
    219.585
    219.586
    Bulk Gasoline Plants
    Bulk Gasoline Terminals
    Gasoline Dispensing Operations
    Storage Tank
    Operations
    Gasoline Delivery Vessels
    Gasoline Volatility Standards
    Gasoline Dispensing Operations
    Motor Vehicle
    Operations
    Filling
    Fueling
    SUBPART Z:
    DRY CLEANERS
    Section
    219.601
    219.602
    219.603
    219.604
    219.605
    219.606
    219.607
    219.608
    219 .609
    219 .610
    219 .611
    219 .612
    219 .613
    Perchloroethylene Dry Cleaners
    Applicability
    Leaks
    Compliance Dates
    (Repealed)
    Compliance Plan (Repealed)
    Exception to Compliance Plan (Repealed)
    Standards for Petroleum Solvent Dry Cleaners
    Operating Practices for Petroleum Solvent Dry Cleaners
    Program for Inspection and Repair of Leaks
    Testing and Monitoring
    Applicablity for Petroleum Solvent Dry Cleaners
    Compliance Dates (Repealed)
    Compliance Plan (Repealed)
    219.504
    219.505
    219.506
    219.521
    219.525
    219.526
    219.527
    Section
    219.561
    219 .562
    219.563
    Architectural Coatings
    Paving Operations
    Cutback Asphalt
    SUBPART
    Y:
    GASOLINE
    DISTRIBUTION
    SUBPART
    AA:
    PAINT
    AND INK
    MANUFACTURING

    37
    Section
    219.620
    219.621
    219.623
    219.624
    219.625
    219.626
    219.628
    219.630
    219.636
    219.637
    Section
    219.640
    219.642
    219.644
    Applicability
    Exemption for Waterbase Material and Heatset-Offset Ink
    Permit Conditions
    (Repealed)
    Open Top Mills, Tanks, Vats or Vessels
    Grinding Mills
    Storage Tanks
    Leaks
    Clean Up
    Compliance Schedule
    Recordkeeping and Reporting
    SUBPART BB:
    POLYSTYRENE
    PLANTS
    Applicability
    Emissions Limitation at Polystyrene Plants
    Emissions Testing
    SUBPART CC: POLYESTER RESIN PRODUCT MANUFACTURING PROCESS
    Section
    219.660
    219.666
    219.667
    219.668
    219.670
    219.672
    Section
    219.680
    219.686
    219.688
    219.690
    219
    .
    692
    Section
    219.760
    219. 762
    219.764
    219.766
    219.768
    219.770
    219.875
    219.877
    219.879
    219.881
    219.883
    Applicability
    Control Requirements
    Compliance Schedule
    Testing
    Recordkeeping and Reporting for Exempt Emission Units
    Recorakeeping and Reporting for Subject Emission Units
    SUBPART DD: AEROSOL
    CAN
    FILLING
    Applicability
    Control Requirements
    Testing
    Recordkeeping and Reporting for Exempt Emission Units
    Recordkeeping and Reporting for Subject Emission Units
    SUBPART GG:
    MARINE TERMINALS
    Applicability
    Control Requirements
    Compliance Certification
    Leaks
    Testing and Monitoring
    Recordkeeping and Reporting
    Applicability of Subpart BB (Renumbered)
    Emissions Limitation at Polystyrene Plants
    (Renumbered)
    Compliance Date (Repealed)
    Compliance Plan (Repealed)
    Special Requirements for Compliance Plan (Repealed)

    38
    219.886
    Emissions Testing (Renumbered)
    SUBPART PP:
    MISCELLANEOUS FABRICATED PRODUCT
    MANUFACTURING
    PROCESSES
    Section
    219.920
    219.923
    219.926
    219
    .
    927
    219.928
    Applicability
    Permit Conditions
    (Repealed)
    Control Requirements
    Compliance Schedule
    Testing
    SUBPART
    QQ:
    MISCELLANEOUS
    FORMULATION
    MANUFACTURING PROCESSES
    Section
    219 .940
    219.943
    219 .946
    219.947
    219 .948
    App?icabi1ity
    Permit Conditions
    (Repealed)
    Control
    Requirements
    Compliance Schedule
    Testing
    SUBPART RR:
    MISCELLANEOUS ORGANIC CHEMICAL MANUFACTURING
    PROCESSES
    Section
    219
    960
    219.963
    219.966
    219.967
    219.968
    Section
    219.980
    219.983
    219.986
    219.987
    219.988
    Section
    219.990
    219.991
    Section
    Section
    Applicability
    Permit Conditions (Repealed)
    Control Requirements
    Compliance Schedule
    Testing
    SUBPART
    TT:
    OTHER EMISSION
    UNITS
    App?icabi1ity
    Permit Conditions (Repealed)
    Control Requirements
    Compliance Schedule
    Testing
    SUBPART UU:
    RECORDKEEPING
    AND
    REPORTING
    Exempt Emission Units
    Subject Emission Units
    219~.AppendixA:
    List of Chemicals Defining Synthetic
    Organic Chemical and Polymer
    Manufacturing
    219.Appendix B:
    VOM Measurement Techniques for Capture
    Efficiency

    39
    Section 219.Appendix C:
    Reference Test Methods for Air Oxidation
    Processes
    Section 219.Appendix
    D:
    Coefficients for the Total Resource
    Effectiveness
    Index
    (TRE)
    Equation
    Section 219.Appendix
    E:
    List of Affected Marine Terminals
    AUTHORITY:
    Implementing Section
    10 and authorized by Section
    28.5 of the Environmental Protection Act
    (Ill.
    Rev.
    Stat.
    1991,
    ch.
    111½, par.
    1010)
    (P.A.
    87—1213, effective September 26,
    1992)
    415
    ILCS 5/10 and 28.5.
    SOURCE:
    Adopted at R91-7 at 15
    Ill.
    Reg.
    12231,
    effective August
    16,
    1991;
    amended in R91—23 at 16 Ill. Reg.
    13564, effective
    August 24,
    1992; amended in R91—28 and R91—30 at
    16 Ill. Reg.
    13864,
    effective August 24,
    1992; amended in R93—9 at 17 Ill.
    Reg.
    16636,
    effective September 27,
    1993; amended in R93-14 at 18
    Ill. Reg. at 1945, effective January 24,
    1994; amended in R94-12
    at
    18 Ill. Reg.
    14973, effective September 21,
    1994; amended in
    R94-l5 at
    18
    Ill.
    Reg.
    16379, effective November
    ‘4,
    1994; amended
    in R94—j~at ~
    Ill. Reg.
    ,
    effective
    _________________;
    amended in R94-~at
    )~
    Ill.
    Reg.
    ,
    effective
    ____________
    SUBPART V:
    BATCH OPERATIONS
    AND
    AIR OXIDATION PROCESSES
    Section 219.500
    Applicability for Batch Operations
    ~j
    The control requirements set forth
    in Section 219.501
    of this Subpart shall apply to:
    1)..
    Process vents associated with batch operations at
    sources identified by any of the following four—
    digit standard industrial classification (“SIC”I
    codes, as defined in the 1987 edition of the
    Federal Standard Industrial Classification Manual:
    SIC 2821,
    2833,
    2834,
    2861.
    2865,
    2869,
    and 2879~
    and
    ~j
    All batch operations at Stepan Company’s Millsdale
    manufacturing facility, Elwood, Illinois.
    ~j
    The requirements of Sections 219.500 through 219.506
    shall not a~p1yto:
    jj.
    Any
    emission unit included within the category
    specified in 35
    Ill.
    Adm.
    Code Part 219, Subparts
    BorT
    ~j
    Any emission unit included within the category
    specified in Sections 219.520 through 219.527 of
    this Subpart; and

    40
    ~j.
    Any emission unit included
    within an Early
    Reduction Program,
    as specified
    in
    40 CFR Part
    63.
    and published in
    57 Fed. Req.
    61970
    (December 29,
    1992), evidenced by a timely enforceable
    commitment approved by USEPA.
    ~j
    The following single unit operations and batch process
    trains are subject to this Subpart but are considered
    to be de minimis and are,
    therefore, exempt from the
    control requirements of Section 219.501 of this
    Subpart.
    However, .the recordkeeping and reporting
    requirements in Section 219.505 of this Subpart shall
    apply to_such de minimis single unit operations and
    batch process trains:
    fl
    Within a batch operation, any single unit
    operation with uncontrolled total annual mass
    emissions of less than or equal to 500 lb/yr of
    VOM.
    Such single unit operations are also
    excluded from the calculation of the total annual
    mass emissions for a batch process train.
    If the
    uncontrolled total annual mass emissions from such
    exempt single unit operation exceed 500 lb/yr of
    VON in any subsequent year,
    the source shall
    calculate applicability in accordance with
    subsection
    (d) of this Section for both the
    individual single unit operation and the batch
    process train containing the single unit
    operation;
    and
    21
    Any batch process train containing process vents
    that have,
    in the aggregate, uncontrolled total
    annual mass emissions,
    as determined in accordance
    with Section 219.502(a) of this Subpart’, of less
    than 30,000 lb/yr of VOM for all products
    manufactured in such batch process train.
    ~J
    The
    applicability
    equations
    in
    subsection
    (e)
    of
    this
    Section. which require the calculation of uncontrolled
    total annual mass emissions and flow rate value, shall
    be used to determine whether a single unit operation or
    a_batch_process train is subject to the control
    requirements set forth in Section 219.501 of this
    Subpart. The applicability equation shall be applied to
    the following:
    il
    Any single unit operation with uncontrolled total
    annual mass emissions that exceed 500 lb/yr and
    with a VOM concentration greater than 500 ppmv.
    In this individual determination, no applicability
    analysis shall be performed for any single unit
    operation with a VOM concentration of less than or

    41
    equal to 500 ppmv; and
    21
    Any batch process train containing process vents
    which,
    in the aggregate, have uncontrolled total
    annual mass emissions of 30,000 lb/yr or more of
    VON from all products manufactured in the batch
    process train.
    Any
    single unit operation with
    uncontrolled total annual mass emissions exceeding
    500 lb/yr.
    regardless of VON concentration,
    shall
    be included in the aggregate applicability
    analysis.
    gj
    Applicability equations
    fl.
    The
    applicability equations in this subsection are
    specific to volatility.
    21
    For purposes of this subsection, the following
    abbreviations apply:
    =
    Vent stream flow rate, scfm
    ~j
    UTANE
    =
    Uncontrolled total annual mass
    emissions of VON, expressed as
    ib/yr
    =
    Weighted average volatility
    ~
    MV~Q~
    =
    Mass of VOM component 1; and
    ~j
    MWVOM~=
    Molecular weight of VOM component
    i; and
    fi
    3~
    =
    Vapor pressure of VOM component
    i.
    fl
    Weighted average volatility shall be calculated as
    follows:
    n
    (MVOM~)
    E
    ((VP1)x
    1=1
    (
    (MWVOM~)
    WAV
    =
    __________________
    n
    (MVON~)
    )
    i=1
    (MWVOM~)
    )
    For purposes of determining applicability, flow
    rate values shall be calculated as follows:
    ~j
    Low WAV has
    a vapor pressure less than or
    equal to 75
    minHq at 20°C
    (68°F), and shall

    42
    use the following equation:
    FR
    =
    fO.07
    (UTANE)1
    1,821
    ~
    Moderate WAV has a vapor pressure greater
    than 75 mmH~but less than or egual to 150
    mmH~
    at
    20°C(68°F),and shall use the
    following
    equation:
    FR
    =
    0.031
    (UTAME)1
    494
    Q1
    High WAV has a vapor pressure greater than
    150
    mixiNg
    at 20°C(68°F),and shall use the
    following equation:
    FR
    =
    0.013
    (UTANE)1
    301
    ~j
    To determine the vapor pressure of VON, the
    applicable methods and procedures in Section
    219.111 of this Part shall apply.
    (Source:
    Added at
    Ill.
    Reg.
    effective
    _______
    S~ctjon219.501
    Control Requirements for Batch Operations
    ~
    Every owner or operator of a single unit operation with
    an average flow rate, as determined in accordance with
    Section 219.502(b)
    of this Subpart. below the flow rate
    value calculated by the applicability equations
    contained in Section 219.500(e)
    of this Subpart,
    shall
    reduce uncontrolled VON emissions from such single unit
    operation by an overall efficiency. on average, of at
    least 90 percent, or 20 ppmv, per batch cycle.
    ~
    Every owner or operator of a batch process train with
    an average flow rate,
    as determined in accordance with
    Section 219.502(b) (2)
    of this Subpart, below the flow
    rate value calculated by the applicability equations
    contained in Section 219.500(e)
    of this Subpart, shall
    reduce uncontrolled VOM emissions from such batch
    process train by an overall efficiency,
    on average, of
    at least 90 percent. or 20 p~mv.per batch cycle.
    For
    purposes of demonstrating compliance with the emission
    limitations set forth in this Section, any control
    device meeting the criteria in subsection
    (c) of this
    Section shall be deemed to achieve a control efficiency
    of 90 percent. or 20 ~
    per batch cycle, as
    applicable.
    ~j
    Notwithstanding subsections
    (a) or
    (b) of this Section,
    any source that has installed on or before March 15.

    43
    1995,
    any
    control
    device
    which
    is
    demonstrated
    to
    the
    Agency’s satisfaction to be unable to meet the
    applicable control requirements
    of this Section,
    scrubber, or shell and tube condenser using a non—
    refrigerated cooling media,
    and such device achieves at
    least
    81 percent control efficiency of VON emissions~
    is required to meet the 90 percent emission limitation
    or 20 ppmv VOM concentration set forth in subsections
    (a)
    or
    (b)
    of this Section, as applicable, upon the
    earlier to occur of the date the device is replaced for
    any reason,
    including, but not limited to. normal
    maintenance, malfunction,
    accident, and obsolescence~
    or_December
    31,
    1999.
    A scrubber, shell and tube
    condenser using a non—refrigerated cooling media,
    or
    other control device meeting the criteria of this
    subsection
    is considered replaced when:
    fl.
    All of the device is replaced; or
    21
    When either the cost to repair the device or the
    cost to replace part of the device exceeds 50
    percent of the cost of replacing the entire device
    with a control device that complies with the 90
    percent emission limitation or 20 p~mvVON
    concentration level in subsection
    (a)
    of this
    Section, as applicable.
    ~j.
    If a boiler or process heater is used to comply with
    this Section, the vent stream shall be introduced into
    the flame zone of the boiler or process heater.
    ~j
    If a flare is used to comply with this Section.
    it
    shall comply with the requirements of 40 CFR 60.18,
    incorporated by reference at Section 219.112 of this
    Part.
    The flare operation requirements of 40 CFR 60.18
    do not apply if a process, not subject to this Subpart,
    vents an emergency relief discharge into a common flare
    header and causes the flare servicing the process
    subiect to this Subpart to not comply with one or more
    of the provisions of 40 CFR 60.18.
    (Source:
    Added at
    _____
    Ill. Reg.
    ,
    effective
    _______
    F
    Section 219.502
    Determination of Uncontrolled Total Annual
    Mass Emissions and Actual Weighted Average
    Flow Rate Values for Batch Operations
    ~j
    Uncontrolled total annual mass emissions shall be
    determined by the following methods:
    fl
    Direct process vent emissions measurements taken

    44
    prior to any release to the atmosphere,
    following
    any recovery device and prior to any control
    device, provided such measurements conform with
    the requirements of measuring the mass flow rate
    of VOM incoming to the single unit operation as
    set forth in Section 219.5031f)L2),
    (f)(3)(A) and
    (f)
    (3)
    (B)
    of
    this
    Subpart;
    or
    21
    Engineering estimates of the uncontrolled VOM
    emissions from a process vent or process vents,
    in
    the aggregate, within
    a batch process train,
    multiplied by the potential or permitted number of
    batch cycles per year as follows:
    ~j
    Engineering estimates of the uncontrolled VOM
    emissions shall be based upon accepted
    chemical engineering principles, measurable
    process parameters,
    or physical or chemical
    laws and their properties.
    Examples of
    methods include, but are not limited to, the
    following:
    j)
    Use of material balances based on
    process stoichiometry to estimate
    maximum VON concentrations
    ~jJJ.
    Estimation of maximum flow rate based on
    physical equipment design such as
    pump
    or blower capacities; and
    iii) Estimation of VON concentrations based
    on saturation conditions.
    ~
    All data,
    assumptions and procedures used in
    any engineering estimate shall be documented.
    ~j
    Average flow rate shall be determined by any of the
    following methods:
    ~j
    Direct process vent flow rate measurements taken
    prior to any release to the atmosphere.
    following
    any recovery device and prior to any control
    device, provided such measurements conform with
    the requirements of measuring incoming volumetric
    flow rate set forth in Section 219.503(e) (2)
    of
    this Subpart
    ~
    Average flow rate for a single unit operation
    having multiple emission events or batch process
    trains shall be the weighted average flow rate,,
    calculated as follows:

    45
    n
    ~ JAFR~
    x ADE~jJ
    i1
    WAF
    =
    _____________
    n
    E
    (ADE1j
    i=.
    where:
    =
    Actual weighted average flow
    rate for a single unit
    operation or batch process
    train
    =
    Average flow rate per emission
    event;
    ADE~
    =
    Annual duration of emission
    event; and
    =
    Number of emission events.
    fl
    Engineering estimates calculated in accordance
    with the requirements in subsection
    (a) (2)
    of this
    Section.
    ~j
    For purposes of determining the average flow rate for
    steam vacuuming systems, the steam flow shall be
    included in the average flow rate calculation.
    (Source:
    Added at
    _____
    Ill.
    Reg.
    ,
    effective
    _______
    Section 219.503
    Performance and Testing Requirements for
    Batch Operations
    ~j
    Upon the Agency’s request. the owner or operator of a
    batch operation shall conduct testing to demonstrate
    compliance with Section 219.501 of this Subpart.
    The
    owner_or operator shall,
    at its
    own
    expense,
    conduct
    such tests in accordance with the applicable test
    methods and procedures specified in Section 219.503(d),
    (e)
    and
    (f) of this Subpart.
    ~j
    Notwithstanding subsection
    (a)
    of this Section.
    flares
    and_process boilers used to comply with control
    requirements of Section 219.501 of this Subpart shall
    be exempt from performance testing requirements.
    ~j
    When a flare is used to com~1ywith the control
    requirements of Section 219.501 of this Subpart, the
    flare shall comply with the requirements of 40 CFR
    60.18. incorporated by reference at Section 219.112 of
    this Part.

    46
    ~
    The
    owner
    or
    operator
    of
    a batch operation that is
    exempt from the control requirements of Section 219.501
    of
    this
    Subpart
    shall
    demonstrate,
    upon
    the
    Agency’s
    request,
    the absence of oversized gas moving equipment
    in any manifold.
    Gas moving equipment shall be
    considered oversized
    if
    it exceeds the maximum
    requirements of the exhaust flow rate by more than 30
    percent.
    ~j
    For the purpose of demonstrating compliance with the
    control requirements in Section 219.501 of this
    Subpart, the batch operation shall be run at
    representative operating conditions and flow rates
    during any performance test.
    ~J.
    The following methods in 40 CFR 60, Appendix A,
    incorporated by reference at Section 219.112 of this
    Part,
    shall be used to demonstrate compliance with the
    reduction
    efficiency
    requirement
    set
    forth
    in
    Section
    219.501 of this Subpart:
    fl
    Method
    1 or 1A.
    as apøropriate.
    for selection of
    the samplina sites
    if the flow measuring device is
    not a rotameter.
    The control device inlet
    sampling site for determination of vent stream VON
    composition reduction efficiency shall be prior to
    the control device and after the control device
    21
    Method 2,
    2A.
    2C. or 2D. as appropriate.
    for
    determination of gas stream volumetric flow rate
    flow measurements, which shall be taken
    continuously.
    No traverse is necessary when the
    flow measuring device is an ultrasonic probe
    .
    fl
    Method 25A or Method 18,
    if applicable,
    to
    determine the concentration of VOM in the control
    device inlet and outlet:
    ~J.
    The sampling time for each run will be the
    entire length of the batch cycle in which
    readings shall be taken continuously,
    if
    Method 25A is used,
    or as often as is
    possible using Method 18.
    with a maximum of
    15—minute intervals between measurements
    throughout the batch cycle
    ~j
    The mass emission rate from the process vent
    or inlet to the control device shall be
    determined by combining concentration and
    flow rate measurements taken simultaneously
    at samp1in~sites selected in accordance with
    subsection
    (f) (1)
    of this Section throughout

    47
    the batch cycle~
    ~j
    The mass emission rate from the control
    device outlet shall be obtained by combining
    concentration and flow rate measurements
    taken simultaneously at sampling sites
    selected in accordance with subsection
    (f) (1)
    of this Section throughout the batch cycle
    and
    DI
    The efficiency of the control device shall be
    determined by integrating the mass emission
    rates_obtained in subsections
    (c) (3) (A)
    and
    (c)
    L3~
    (B) of this Section.
    over the time of
    the batch cycle and dividing the difference
    in inlet and outlet mass flow totals by the
    inlet mass flow total.
    gi
    Upon request by the Agency to conduct testing, an owner
    or operator of a batch operation which has installed a
    scrubber,
    a shell and tube condenser using a non—
    refrigerated cooling media,
    or any other control device
    which meets the criteria of Section 219.501(c)
    of this
    Subpart, shall demonstrate that such device achieves
    the control efficiency applicable within Section
    219.501 of this Subpart upon the earlier to occur of
    the date the device is replace or December 31,
    1999.
    ~
    The owner or operator of a batch operation may propose
    an alternative test method or procedures to demonstrate
    compliance with the control requirements set forth in
    Section 219.501 of this Subpart.
    Such method or
    procedures shall be approved by the Agency and USEPA as
    evidenced by federally enforceable permit conditions.
    (Source:
    Added at
    _____
    Ill. Reg.
    ,
    effective
    _______
    Section 219.504
    Monitoring Requirements for Batch Operations
    ~j
    Every owner or operator using an afterburner to comply
    with Section 219.501 of this Subpart. shall install,
    calibrate, maintain and operate, according to
    manufacturer’s specifications, temperature monitoring
    devices with an accuracy of ±1 percent of the
    temperature being measured expressed in degrees
    Celsius. equipped with continuous recorders.
    ~j
    Where
    a catalytic afterburner is used, temperature
    monitoring devices shall be installed in the gas
    stream immediately before and after the catalyst
    bed.

    48
    21
    Where
    an afterburner other than a catalytic
    afterburner is used,
    a temperature monitoring
    device shall be installed in the combustion
    chamber.
    ki
    Every
    owner
    or operator using a flare to comply with
    Section 219.501 of this Subpart, shall install,
    calibrate, maintain and operate,
    according to
    manufacturer’s specifications,
    a heat sensing device,
    such as an ultra—violet beam sensor or thermocouple, at
    the pilot light to indicate continuous presence of a
    flame.
    ~j
    Every owner or operator using a scrubber to comply with
    this Section 219.501 of this Subpart,
    shall install,
    calibrate, maintain, and operate. according to
    manufacturer’s
    specifications,
    the
    following:
    fl.
    A temperature monitoring device for scrubbant
    liquid having an accuracy of ±1 percent of the
    temperature being monitored expressed in degrees
    Celsius and a specific gravity device for
    scrubbant liquid, each equipped with a continuous
    recorder; or
    21
    A VOM monitoring device used to indicate the
    concentration of VOM exiting the control device
    based on a detection ~rincip1e such as infra—red
    photoionjzation, or thermal conductivity, each
    equipped with a continuous recorder.
    ~j.
    Every owner or operator using a condenser to comply
    with Section 219.501 of this Subpart, shall install,
    calibrate, maintain, and operate,
    according to
    manufacturer’s specifications, the following:
    ~j
    A condenser exit temperature monitoring device
    equipped with a continuous recorder. and having an
    accuracy of ±1 percent of the temperature being
    monitored expressed
    in degrees Celsius; or
    21
    A VON monitoring device used to indicate the
    concentration of VOM such as infra—red.
    photoionization, or thermal conductivity, each
    equipped with a continuous recorder.
    ~
    Every owner or operator using a carbon adsorber to
    comply with this Subpart shall instalL calibrate,
    maintain, and operate, according to the manufacturer’s
    specifications the following equi~ment:
    An integrating regeneration stream flow monitoring

    49
    device having an accuracy of ±10 percent. and a
    carbon bed temperature monitoring device having an
    accuracy of ±1 percent of the temperature being
    monitored expressed in degrees Celsius. both
    e~jpped with a continuous recorder; or
    21
    A
    VON
    monitoring
    device
    used
    to
    indicate
    the
    concentration level or VOM exiting such device
    based on
    a detection principle such as infra—red,
    photoionization. or thermal conductivity, each
    equipped with a continuous recorder.
    fl
    Every owner or operator using a boiler or process
    heater with a design heat input capacity less than 44
    Mw_to_comply with Section 219.501 of this Subpart.
    shall
    install, calibrate, maintain, and operate,
    according to the manufacturer’s specifications,
    a
    temperature monitoring device in the firebox with an
    accuracy of ±1 percent of the temperature being
    measured expressed in degrees Celsius.
    equipped with
    a
    continuous recorder.
    Any boiler or process heater in
    which all process vent streams are introduced with
    primary fuel is exempt from this requirement.
    gi
    The owner or operator of
    a process vent shall be
    permitted to monitor by an alternative method or may
    monitor parameters other that those listed in
    subsections
    (a) through
    (f) of this Section,
    if
    approved by the Agency and USEPA.
    Such alternative
    method or parameters shall be contained in the source’s
    operating permit as federally enforceable permit
    conditions.
    ~j
    Notwithstanding subsections
    (a) through
    (g)
    of this
    Section. sources using a scrubber,
    shell and tube
    condenser using a non—refrigerated cooling media, or
    other control device meeting the criteria of Section
    219.501(c)
    of this Subpart, are required to monitor
    compliance with the requirements of this Subpart on and
    after the earlier to occur of the date such device is
    replaced for any reason or December 31,
    1999.
    (Source:
    Added at
    _____
    Ill. Reg.
    ,
    effective
    _______
    Section 219.505
    Reporting and Recordkeepincz for Batch
    Operations
    ~j
    Every owner or operator of a de mirtimis single unit
    operation or batch process train exempt under Section
    219.500(c) (1) or
    (c) (2) of this Subpart, shall keep
    records of the uncontrolled total annual mass emissions

    50
    for any de ininiinis
    single unit operation or batch
    process train,
    as
    applicable, and documentation
    verifying these values or measurements.
    The
    documentation shall include the engineering
    calculations or measurements coupled with the potential
    or permitted
    number
    of batch cycles per year if the
    uncontrolled total annual mass emissions is obtained
    from measurements made in accordance with Section
    219.503 of this Subpart.
    ki
    Every owner or operator of
    a single unit operation
    exempt under Sections 219.500(b) (3)
    or
    (d)
    of this
    Subpart_shall keep the following records:
    fl~.
    The uncontrolled total annual mass emissions and
    documentation verifying these values or
    measurements.
    The documentation shall include the
    calculations or measurements coupled with the
    permitted or permitted number of emission events
    per year if the uncontrolled total annual mass
    emissions is obtained from measurements made in
    accordance with Section 219.503 of this Subpart
    and
    21
    The average flow rate in scfm and documentation
    verifying this value.
    gj
    Every owner or operator of a batch operation subject to
    the control requirements of Section 219.501 of this
    Subpart shall keep records of the following parameters
    required to be monitored under Section 219.504 of this
    Subpart:
    fl.
    If using a thermal or catalytic afterburner to
    comply with Section 219.501 of this Subpart,
    records indicating the average combustion chamber
    temperature of the afterburner
    (or the average
    temperature upstream and downstream of the
    catalyst bed for a catalytic afterburner).
    measured continuously and averaged over the same
    time period as the performance test
    21
    If using a flare
    (i.e.. stream—assisted, air—
    assisted or nonassisted)
    to comply with Section
    219.501 of this Subpart, continuous records of the
    flare pilot flame monitoring and records of all
    periods of operations during which the oilot flame
    is absent.
    For purposes of determining compliance
    with 40 CFR 60.18, incorporated by reference at
    219.112 of this Part, records shall also be kept
    indicating heat content determinations, flow rate
    measurements and the exit velocity determinations.

    51
    ~J
    If
    using
    any
    of
    the
    following
    as
    a control device,
    the following records:
    ~
    Where a scrubber is used,
    the exit specific
    gr~avity(or alternative parameter which is a
    measure of the degree of absorbing liquid
    saturation,
    if a~~rovedby the Agency)
    and
    the average exit temperature of the absorbing
    liquid, measured continuously and averaged
    over the same time period as the performance
    test
    (both measured while the vent stream is
    routed normally)
    ~j
    Where a
    condenser is used, the average exit
    (product side) temperature measured
    continuously and averaged over the same time
    period as the performance test while the vent
    stream is routed normally:
    ~j
    Where a carbon adsorber is used,
    the total
    stream mass flow measured continuously and
    averaged over the same time period as the
    performance test (full carbon bed cycle).
    temoerature of the carbon bed after
    regeneration (and within 15 minutes of
    completion of any cooling cycle(s)), and
    duration of the carbon bed steaming cycle
    (all measured while the vent stream is routed
    normally): or
    DI
    As an alternative to subsections
    (c) (3) (A).
    I
    c)(3)(B). or (c)(3)(C) of this Section.
    at a
    minimum, records indicating the concentration
    level or reading indicated by the VON
    monitoring device at the outlet of the
    scrubber, condenser,
    or carbon adsorber.
    measured continuously and avera~edover the
    same time period as the performance test
    (while the vent stream is routed normally).
    ~L
    Every owner or operator of an single unit operation
    claiming a vent stream concentration exemption level.
    as set forth in Section 218.500(d) (11
    of this Subpart,
    shall maintain records to indicate the vent stream
    concentration is less than or e~al to 500 ~pmv. and
    shall notify the Agency in writing if the vent stream
    concentration at any time equals or exceeds 500 ppmv.
    within 30 days of such event.
    Such notification shall
    ii’iclude a copy of all records of such event.
    An owner or operator of a batch operation subject to
    the control requirements of Section 219.501 of this

    52
    Subpart may maintain
    alternative
    records other than
    those listed in subsection
    Cc)
    of this Section.
    Any
    alternative recordkeeping shall be approved by the
    Agency and USEPA and shall be contained in the source’s
    operating permit as federally enforceable permit
    conditions.
    ZJ
    Notwithstanding subsections
    (a) through
    (f)
    of this
    Section, any owner or operator of a batch operation
    which uses either a scrubber, shell and tube condenser
    using non—refrigerated cooling media,
    or other control
    device meeting the criteria of Section 219.501(c)
    of
    this Subpart.
    are required to monitor compliance with
    the requirements of this Subpart on and after the
    earlier to occur of the date such device is replaced
    for any reason or December 31.
    1999.
    gj
    The owner or operator of a de minimis single unit
    operation or batch process train exempt from the
    control requirements of Section 219.501(c)
    of this
    Subpart shall notify the Agency in writing if the
    uncontrolled total annual mass emissions from such de
    minimis single unit operation or batch process train
    exceed the threshold in Section 219.501(c) (1)
    or (c)(2)
    of this Subpart, respectively, within 60 days after the
    event occurs.
    Such notification shall include a copy
    of all records of such event.
    ~
    Every owner or operator of a batch operation required
    to keep records under this Section shall maintain such
    records at the source for a
    minimum
    period of three
    years and shall make all such records available to the
    Agency upon request.
    (Source:
    Added at
    Ill. Reg.
    _______,
    effective
    _______
    Section 219.506
    Compliance Date
    Every owner or operator of a batch operation subject to Sections
    219.500 through 219.506 of this Subpart shall com~lvwith its
    standards,
    limitations and mandates by March 15. 1996,
    or upon
    initial start up. whichever is later.
    (Source:
    Added at
    _____
    Ill. Reg.
    _______,
    effective
    _______
    IT IS SO ORDERED.

    53
    I, Dorothy M.
    Gunn, Clerk of the Illinois Pollution Control
    Board, hereby certify that the above opinion and order was
    adopted on the
    /~~-1 day of
    ~
    ,
    1994,
    by a vote
    of
    ~-C.
    ~
    ~
    /1t
    ~
    Dorothy M./~Gunn, Clerk
    Illinois P~llutionControl Board

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