ILLINOIS POLLUTION CONTROL BOARD
    December 20,
    1995
    IN THE MATTER OF:
    )
    15
    ROP PLAN:
    )
    CLEAN-UP PART II:
    )
    R96-l3
    AMENDMENTS TO 35
    ILL. ADM.
    )
    (Rulemaking-Air)
    CODE PARTS 218
    AND
    219
    ProDosed Rule.
    First Notice.
    OPINION
    AND
    ORDER OF THE BOARD
    (by J.
    Theodore Meyer):
    On December 13,
    1995 the Illinois Environmental Protection
    Agency (Agency)
    filed this proposal for rulemaking.
    In addition
    to the proposal, the Agency filed a motion to waive certain
    filing requirements.
    Section 182(b) (1) of the Clean Air Act
    (42
    U.s.c.
    7511(b) (1))
    required Illinois to submit a plan by November 15,
    1993,
    for achieving a 15
    reduction of volatile organic material
    (VOM)
    emissions in the Chicago and Metro—East ozone nonattainment
    areas
    (15
    Rate—of-Progress
    (ROP)
    Plan).
    Section 182(b)
    of the
    CAA
    also required Illinois to submit fully adopted measures to
    implement the ROP Plan.
    Illinois submitted its 15
    ROP plan
    November 13,
    1993, and thereafter proposed regulations to
    implement the ROP Plan.
    The Agency proposes seven
    (7)
    minor
    amendments to 35 Ill. Adm.
    Code Parts
    218 and 219:
    1)
    Add identical
    language found in Section 218.208(b)
    regarding “equivalent alternative control plans” to
    Section 219.108(b);
    2)
    Revise certain equations for vapor pressure
    in Subpart
    A;
    3)
    Clarify the applicable record keeping and reporting
    requirements for coating operations using touch-up and
    repair coatings in Subpart
    F;
    4)
    Correct a Federal Register citation regarding Synthetic
    Organic Chemical and Polymer Manufacturing Plants
    (SOCMI)
    and correct typographical errors in Subpart Q;
    5)
    Reflect the Illinois General Assembly’s repeal in
    Public Law 89-79
    of the bakery oven rules
    in Subpart
    FF;
    6)
    Amend the exemption for polyethylene manufacturing
    operations in Subpart TT; and,
    7)
    Correct a typographical error in Appendix G.
    As mentioned above,
    the Agency also filed a motion to waive
    certain filing requirements of 35
    Ill.
    Adm.
    Code
    102.
    Specifically, the Agency requests a waiver of the nine
    (9)
    copy
    filing requirement,
    stating that, due to the length of the
    2
    proposal, it would be more feasible to file five
    (5)
    full copies
    and four
    (4)
    partial copies with the Board.
    The Agency also
    requested relief from 35
    Ill.
    Adm.
    Code 120 which requires that
    the entire proposal be submitted to the Attorney General and the
    Department of Natural Resources.
    The Agency contacted
    representatives of both departments who agreed that it would be
    sufficient to be formally notified that a proposal has been made
    and where it can be reviewed.
    Finally, the Agency asked for
    relief from providing copies of incorporated material to meet the
    requirement of 35
    Iii. Adm. Code 102.121(f).
    The Board hereby
    grants the Agency’s motion to waive the above described filing
    requirements.
    Today the Board acts to send this proposal to first notice
    under the Illinois Administrative Procedure Act,
    but without
    commenting on the merits of the proposal.
    This proposal was filed pursuant to Sections 27 and 28.5 of
    the Environmental Protection Act
    (Act)
    as a fast—track rulemaking
    proceeding.
    (415 ILCS 5/27 and 28.5
    (1994.)
    Section 28.5
    requires the Board to proceed with rulemaking under set time—
    frames.
    The Board has no discretion to adjust these time frames
    under any circumstances.
    The following schedule indicates the
    deadlines by which the Board must act, as provided in Section
    28.5:
    first notice
    on or before December 20,
    1995
    first hearing
    on or before February 6,
    1996
    second hearing
    no later than 30 days after
    the start of the first hearing
    third hearing
    no later than
    14 days after
    the start of the second
    hearing
    second notice
    (if third hearing cancelled)
    on or before April
    4,
    1996
    (if third hearing held)
    on or before May 2,
    19956
    final adoption and filing
    21 days after receipt of JCAR
    certificate of no objection
    The Board notes that the above dates are the deadlines as
    established by Section 28.5 and do not represent actual hearing
    dates or filing dates.
    While the schedule includes second and
    third hearings,
    these hearings may be cancelled if unnecessary.
    The Board will proceed
    in this matter as prescribed
    in Section
    28.5 and discussed in the Board’s resolution.
    (~
    Clean Air Act
    Rulemaking Procedures Pursuant to Section 28.5 of the
    Environmental Protection Act,
    as Added By P.A.
    87-1213,
    (October
    29,
    1992 and December
    3,
    1992), RES 92—2.)
    In the interest of administrative economy, the Board directs
    the Hearing Officer to verify that the persons on the Clean Air
    Act Notice List wish to continue to receive mailing
    in this
    3
    proceeding.
    ORDER
    The Board directs the Clerk to cause publication of the
    following amendments
    in the Illinois Register for first notice:
    TITLE 35:
    ENVIRONMENTAL PROTECTION
    SUBTITLE B:
    AIR POLLUTION
    CHAPTER
    I:
    POLLUTION CONTROL BOARD
    SUBCHAPTER c:
    EMISSIONS STANDARDS AND
    LIMITATIONS FOR STATIONARY SOURCES
    PART 218
    ORGANIC MATERIAL EMISSION STANDARDS AND
    LIMITATIONS FOR THE CHICAGO AREA
    SUBPART A:
    GENERAL PROVISIONS
    Section
    218. 100
    218. 101
    218. 102
    218.103
    218.104
    218.105
    218.106
    218.107
    218.108
    218. 109
    218.110
    218
    .
    ill
    218.112
    218.113
    218. 114
    Introduction
    Savings Clause
    Abbreviations and Conversion Factors
    Applicability
    Definitions
    Test Methods and Procedures
    Compliance Dates
    Operation of Afterburners
    Exemptions, Variations, and Alternative Means of
    Control or Compliance Determinations
    Vapor Pressure of Volatile Organic Liquids
    Vapor Pressure of Organic Material or Solvent
    Vapor Pressure of Volatile Organic Material
    Incorporations by Reference
    Monitoring for Negligibly-Reactive Compounds
    Compliance with Permit Conditions
    SUBPART B:
    ORGANIC EMISSIONS FROM STORAGE
    AND LOADING OPERATIONS
    Applicability for VOL
    Control Requirements for Storage Containers of VOL
    Storage Containers of VPL
    Loading Operations
    Petroleum Liquid Storage Tanks
    External Floating Roofs
    Compliance Dates
    Compliance Plan (Repealed)
    Testing VOL Operations
    Monitoring VOL Operations
    Recordkeeping and Reporting for VOL Operations
    Section
    218. 119
    218.120
    218.121
    218. 122
    218.123
    218.124
    218.125
    218. 126
    218.127
    218.128
    218.129
    4
    SUBPART
    C:
    ORGANIC EMISSIONS FROM
    MISCELLANEOUS EQUIPMENT
    Section
    218.141
    218.142
    218.143
    218.144
    Separation Operations
    Pumps and Compressors
    Vapor Blowdown
    Safety Relief Valves
    SUBPART E:
    SOLVENT CLEANING
    SUBPART
    F:
    COATING OPERATIONS
    Emission Limitations
    Daily-Weighted Average Limitations
    Solids Basis Calculation
    Alternative Emission Limitations
    Exemptions from Emission Limitations
    Exemption from General Rule on Use of Organic Material
    Compliance Schedule
    Recordkeeping and Reporting
    Cross-Line Averaging to Establish Compliance for
    Coating Lines
    218.213
    Recordkeeping and Reporting for Cross—Line Averaging
    Participating Coating Lines
    218.214
    Changing Compliance Methods
    SUBPART
    0:
    USE OF ORGANIC MATERIAL
    Use of Organic Material
    Alternative Standard
    Fuel Combustion Emission Units
    Operations with Compliance Program
    SUBPART H:
    PRINTING AND PUBLISHING
    Section
    218.401
    218.402
    218.403
    218.404
    218.405
    Flexographic and Rotogravure Printing
    Applicability
    Compliance Schedule
    Recordkeeping and Reporting
    Lithographic Printing:
    Applicability
    Solvent Cleaning in General
    Cold Cleaning
    Open Top Vapor Degreasing
    Conveyorized Degreasing
    Compliance Schedule
    (Repealed)
    Test Methods
    Section
    218.181
    218.182
    218.183
    218.184
    218.185
    218.186
    Section
    218.204
    218.205
    218.206
    218.207
    218.208
    218.209
    218.210
    218.211
    218.212
    Section
    218.301
    218.302
    218.303
    218.304
    5
    218.406
    Provisions Applying to Heatset Web Offset Lithographic
    Printing Prior to March
    15,
    1996
    218.407
    Emission Limitations and Control Requirements for
    Lithographic Printing Lines On and After March 15, 1996
    218.408
    Compliance Schedule for Lithographic Printing on and
    After March 15,
    1996
    218.409
    Testing for Lithographic Printing On and After March
    15,
    1996
    218.410
    Monitoring Requirements for Lithographic Printing
    218.411
    Recordkeeping and Reporting for Lithographic Printing
    SUBPART
    Q:
    SYNTHETIC ORGANIC CHEMICAL
    AND
    POLYMER
    MANUFACTURING
    PLANT
    Section
    218.421
    218.422
    218.423
    218.424
    218.425
    218.426
    2 18.427
    218.428
    218.429
    218.430
    218.43.
    218.432
    218.433
    218.434
    218.435
    218.436
    Section
    218.441
    218.442
    218.443
    218.444
    218.445
    218.446
    218.447
    218.448
    218.449
    218.450
    218.451
    218.452
    218.453
    General Requirements
    Inspection Program Plan for Leaks
    Inspection Program for Leaks
    Repairing Leaks
    Recordkeeping for Leaks
    Report for Leaks
    Alternative Program for Leaks
    Open-Ended Valves
    Standards for Control Devices
    Compliance Date
    (Repealed)
    Applicability
    Control Requirements
    Performance and Testing Requirements
    Monitoring
    Requirements
    Recordkeeping and Reporting Requirements
    Compliance Date
    SUBPART R:
    PETROLEUM REFINING AND
    RELATED INDUSTRIES; ASPHALT MATERIALS
    Petroleum Refinery Waste Gas Disposal
    Vacuum Producing Systems
    Wastewater
    (Oil/Water)
    Separator
    Process Unit Turnarounds
    Leaks:
    General Requirements
    Monitoring Program Plan for Leaks
    Monitoring Program for Leaks
    Recordkeeping for Leaks
    Reporting for Leaks
    Alternative Program for Leaks
    Sealing Device Requirements
    Compliance Schedule for Leaks
    Compliance
    Dates
    (Repealed)
    6
    SUBPART
    5:
    RUBBER
    AND
    MISCELLANEOUS
    PLASTIC
    PRODUCTS
    Manufacture
    of
    Pneumatic Rubber Tires
    Green
    Tire
    Spraying
    Operations
    Alternative
    Emission
    Reduction Systems
    Emission Testing
    Compliance Dates
    (Repealed)
    Compliance Plan
    (Repealed)
    SUBPART
    T:
    PHARMACEUTICAL MANUFACTURING
    Section
    218.480
    Applicability
    218.481
    Control of Reactors,
    Distillation Units,
    Crystallizers,
    Centrifuges and Vacuum Dryers
    218.482
    Control of Air Dryers, Production Equipment Exhaust
    Systems and Filters
    Material Storage and Transfer
    In—Process Tanks
    Leaks
    Other Emission Units
    Testing
    Monitoring for Air Pollution Control Equipment
    Recordkeeping for Air Pollution Control Equipment
    SUBPART V:
    BATCH OPERATIONS AND AIR
    OXIDATION PROCESSES
    Applicability for Batch Operations
    Control Requirements for Batch Operations
    Determination of Uncontrolled Total Annual Mass
    Emissions and Average Flow Rate Values for Batch
    Operations
    218.503
    Performance and Testing Requirements for Batch
    Operations
    Monitoring
    Requirements
    for
    Batch
    Operations
    Reporting and Recordkeeping for Batch Operations
    Compliance Date
    Emission Limitations for Air Oxidation Processes
    Definitions (Repealed)
    Savings Clause
    Compilance
    Determination of Applicability
    Emission Limitations for Air Oxidation Processes
    (Renumbered)
    218.526
    Testing and Monitoring
    218.527
    Compliance Date
    (Repealed)
    Section
    218.461
    218.462
    218.463
    2 18.464
    218.465
    218.466
    218.483
    218.484
    218.485
    218.486
    218.487
    218.488
    218.489
    Section
    218.500
    218.501
    218.502
    218.504
    218.505
    2 18.506
    218.520
    218.521
    218.522
    218.523
    218.524
    218.525
    7
    Section
    218.54
    1
    SUBPART W:
    Pesticide Exception
    AGRICULTURE
    Architectural Coatings
    Paving Operations
    Cutback Asphalt
    Section
    218.581
    218.582
    218.583
    218.584
    218.585
    218.586
    Bulk Gasoline Plants
    Bulk Gasoline Terminals
    Gasoline Dispensing Operations
    -
    Storage Tank Filling
    Operations
    Gasoline Delivery Vessels
    Gasoline Volatility Standards
    Gasoline Dispensing Operations
    -
    Motor Vehicle Fueling
    Operations
    SUBPART
    Z:
    DRY CLEANERS
    Section
    218.601
    218.602
    218.603
    2 18.604
    218.605
    218 .606
    218.607
    218.608
    218.609
    218.610
    218.611
    218.612
    218.613
    Section
    218.620
    218.621
    218.623
    218.624
    218.
    625
    218.626
    Perchloroethylene Dry Cleaners
    Applicability
    Leaks
    Compliance Dates
    (Repealed)
    Compliance Plan
    (Repealed)
    Exception to Compliance Plan (Repealed)
    Standards for Petroleum Solvent Dry Cleaners
    Operating Practices for Petroleum Solvent Dry Cleaners
    Program for Inspection and Repair of Leaks
    Testing and Monitoring
    Applicablity for Petroleum Solvent Dry Cleaners
    Compliance Dates
    (Repealed)
    Compliance Plan
    (Repealed)
    SUBPART AA:
    PAINT AND INK MANUFACTURING
    Applicability
    Exemption for Waterbase Material and Heatset-Offset Ink
    Permit Conditions
    (Repealed)
    Open Top Mills,
    Tanks, Vats or Vessels
    Grinding Mills
    Storage Tanks
    Section
    218.561
    218.562
    218.563
    SUBPART X:
    CONSTRUCTION
    SUBPART Y:
    GASOLINE DISTRIBUTION
    8
    218.628
    Leaks
    218.630
    Clean Up
    218.636
    Compliance Schedule
    218.637
    Recordkeeping and Reporting
    SUBPART BB:
    POLYSTYRENE PLANTS
    Section
    218.640
    Applicability
    218.642
    Emissions Limitation
    at Polystyrene Plants
    218.644
    Emissions Testing
    SUBPART CC: POLYESTER RESIN PRODUCT
    MANUFACTURING
    PROCESS
    Section
    218.660
    Applicability
    218.666
    Control Requirements
    218.667
    Compliance Schedule
    218.668
    Testing
    218.670
    Recordkeeping and Reporting for Exempt Emission Units
    218.672
    Recordkeeping and Reporting for Subject Emission Units
    SUBPART DD: AEROSOL CAN FILLING
    Section
    218.680
    Applicability
    218.686
    Control Requirements
    218.688
    Testing
    218.690
    Recordkeeping and Reporting for Exempt Emission Units
    218.692
    Recordkeeping and Reporting for Subject Emission Units
    SUBPART FF:
    BAKERY OVENS
    (Repealed)
    Section
    218.720
    Applicability
    (Repealed)
    218.722
    Control Requirements
    (Repealed)
    218.726
    Testing
    (Repealed)
    218.727
    Monitoring
    (Repealed)
    218.728
    Recordkeeping and Reporting
    (Repealed)
    218.729
    Compliance Date
    (Repealed)
    218.730
    Certification
    (Repealed)
    SUBPART GG:
    MARINE TERMINALS
    Section
    218.760
    Applicability
    218.762
    Control Requirements
    218.764
    Compliance Certification
    218.766
    Leaks
    9
    218.768
    Testing and Monitoring
    218.770
    Recordkeeping and Reporting
    SUBPART HH:
    MOTOR VEHICLE REFINISHING
    Section
    218.780
    218.782
    2 18.784
    218.786
    218.787
    2 18.788
    218.789
    218.790
    218.791
    218.792
    218.875
    218.877
    218.879
    218.881
    218.883
    218.886
    Section
    218.940
    218.943
    218.946
    218.947
    218.948
    Section
    218.960
    218.963
    218.966
    Emission
    Limitations
    Alternative Control Requirements
    Equipment Specifications
    Surface Preparation Materials
    Work Practices
    Testing
    Monitoring and Recordkeeping for Control Devices
    General Recordkeeping and Reporting
    Compliance Date
    Registration
    Applicability of Subpart BB
    (Renumbered)
    Emissions Limitation at Polystyrene Plants
    (Renumbered)
    Compliance Date
    (Repealed)
    Compliance Plan
    (Repealed)
    Special Requirements for Compliance Plan (Repealed)
    Emissions Testing
    (Renumbered)
    SUBPART PP:
    MISCELLANEOUS FABRICATED
    PRODUCT MANUFACTURING PROCESSES
    SUBPART QQ:
    MISCELLANEOUS FORMULATION
    MANUFACTURING
    PROCESSES
    Applicability
    Permit Conditions
    (Repealed)
    Control Requirements
    Compliance Schedule
    Testing
    SUBPART RR:
    MISCELLANEOUS ORGANIC
    CHEMICAL MANUFACTURING PROCESSES
    Applicability
    Permit Conditions
    (Repealed)
    Control Requirements
    Section
    218.920
    218.923
    218.926
    218.927
    218.928
    Applicability
    Permit Conditions
    (Repealed)
    Control Requirements
    Compliance Schedule
    Testing
    10
    218.967
    Compliance Schedule
    218.968
    Testing
    Exempt Emission Units
    Subject Emission Units
    Section 218.Appendix A:
    Section 218.Appendix B:
    Section 218.Appendix C:
    Section 218.Appendix D:
    Section 2l8.Appendix E:
    Section 218.Appendix G:
    Section 218.Appendix H:
    List of Chemicals Defining Synthetic
    Organic Chemical and Polymer
    Manufacturing
    VOM Measurement Techniques for Capture
    Efficiency
    Reference Methods and Procedures
    Coefficients for the Total Resource
    Effectiveness Index
    (TRE)
    Equation
    List of Affected Marine Terminals
    TRE Index Measurements for SOCMI
    Reactors and Distillation Units
    Baseline VOM Content Limitations for
    Subpart F,
    Section 218.212 Cross-Line
    Averaging
    AUTHORITY:
    Implementing Section 10 and authorized by Section
    28.5 of the Environmental Protection Act 415
    ILCS 5/10 and
    28.5.
    SOURCE:
    Adopted at R91-7 at 15 Ill.
    Reg.
    12231, effective August
    16,
    1991; amended in R91—23 at 16 Ill.
    Reg.
    13564, effective
    August 24,
    1992; amended in R91—28 and R91-30 at 16 Ill.
    Reg.
    13864, effective August 24,
    1992; amended in R93-9
    at 17
    Ill.
    Reg.
    16636, effective September 27,
    1993; amended in R93—l4 at 18
    Ill. Reg. at
    1945, effective January 24, 1994;
    amended in R94-12
    at 18 Ill. Reg.
    at 14973, effective September 21,
    1994;
    amended
    in R94—15 at
    18 Ill. Reg.
    16392, effective October 25,
    1994;
    amended in R94-16 at 18
    Ill. Reg.
    16950, effective November 15,
    1994; amended in R94—2l,
    R94—31 and R94—32 at 19
    Ill.
    Reg.
    6848,
    effective May 9,
    1995; amended in R94—33 at 19 Ill. Reg.
    7359,
    effective May 22,
    1995; amended at
    _____
    Ill. Reg.
    effective
    _____________________
    Section
    218.980
    218.983
    218.986
    218.987
    218.988
    Section
    218.990
    218.991
    SUBPART TT:
    OTHER EMISSION UNITS
    Applicability
    Permit Conditions
    (Repealed)
    Control Requirements
    Compliance Schedule
    Testing
    SUBPART UU:
    RECORDKEEPING
    AND
    REPORTING
    11
    BOARD NOTE:
    This Part implements the Environmental Protection
    Act as of July
    1,
    1994.
    SUBPART A:
    GENERAL PROVISIONS
    Section 218.110
    Vapor Pressure of Organic Material or Solvent
    a)
    If the organic material or solvent consists of only a
    single compound, the vapor pressure shall be determined
    by ASTN Method D2879-86 (incorporated by reference in
    Section 218.112 of this Part)
    or the vapor pressure may
    be obtained from a publication such as:
    Boublik,
    T.,
    V. Fried and E. Hala,
    “The Vapor Pressure of Pure
    Substances,” Elsevier Scientific Publishing Co., New
    York
    (1973); Perry’s Chemical Engineer’s Handbook,
    McGraw-Hill Book Company
    (1984);
    CRC Handbook of
    Chemistry and Physics, Chemical Rubber Publishing
    Company
    (1986-87); and Lange’s Handbook of Chemistry,
    John A.
    Dean,
    editor, McGraw-Hill Book Company
    (1985).
    b)
    If the organic material or solvent is in a mixture made
    up of both organic material compounds and compounds
    which are not organic material,
    the vapor pressure
    shall be determined by the following equation:
    n
    E
    P,
    X,
    Pvom ~om
    =
    i=1
    n
    B
    i=l
    where:
    Porn
    =
    Total vapor pressure of the portion of
    the mixture which is composed of organic
    material;
    n
    =
    Number of organic material components
    in
    the mixture;
    i
    =
    Subscript denoting an individual
    component;
    P1
    =
    Vapor pressure of an organic material
    component determined
    in accordance with
    subsection
    (a)
    of this Section;
    Xl
    =
    Mole fraction of the organic material
    component of the total organic mixture.
    12
    c)
    If the organic material or solvent is
    in a mixture made
    up of only organic material compounds, the vapor
    pressure shall be determined by ASTM Method D2879-86
    (incorporated by reference
    in Section 218.112
    of this
    Part)
    or by the above equation.
    (Source:
    Amended at
    _____
    Ill. Req.
    __________,
    effective
    —
    _______________________________________________________
    )
    Section 218.111
    Vapor Pressure of Volatile Organic Material
    a)
    If the VON consists of only a single compound,
    the
    vapor pressure shall be determined by ASTM Method
    D2879—86
    (incorporated by reference
    in Section 218.112
    of this Part)
    or the vapor pressure may be obtained
    from a publication such as:
    Boublik, T.,
    V.
    Fried and
    E. Hala,
    “The Vapor Pressure of Pure Substances,”
    Elsevier Scientific Publishing Co., New York
    (1973);
    Perry’s Chemical Engineer’s Handbook, McGraw-Hill Book
    Company
    (1984); CRC Handbook of Chemistry and Physics,
    Chemical Rubber Publishing Company
    (1986-87); and
    Lange’s Handbook of Chemistry,
    John A.
    Dean, editor,
    McGraw-Hill Book Company
    (1985).
    b)
    If the VOM is in
    a mixture made up of both VOM
    compounds and compounds which are not VOM, the vapor
    pressure shall be determined by the following equation:
    n
    B
    P,
    X,
    ~vom
    =
    i=1
    n
    B
    x,
    1=1
    where:
    Pvom
    =
    Total vapor pressure of the portion of
    the mixture which
    is composed of VOM;
    n
    =
    Number of VOM components
    in the mixture;
    i
    =
    Subscript denoting an individual
    component;
    P1
    =
    Vapor pressure of a VOM component
    determined
    in accordance with subsection
    (a)
    of this Section;
    Xi
    =
    Mole fraction of the VOM component of
    13
    the total organic mixture.
    c)
    If the VOM is in a mixture made up of only VOM
    compounds, the vapor pressure shall be determined by
    ASTM Method D2879-86
    (incorporated by reference in
    Section 218.112
    of this Part)
    or by the above equation.
    (Source:
    Amended at
    _____
    Ill.
    Reg.
    _________,
    effective
    —
    ____________________________________________________________
    )
    SUBPART
    F:
    COATING OPERATIONS
    Section 218.208
    Exemptions From Emission Limitations
    a)
    Exemptions for all coating categories except wood
    furniture coating.
    The limitations of this Subpart
    shall not apply to coating lines within a source,
    that
    otherwise would be subject to the same subsection of
    Section 218.204
    (because they belong to the same
    coating category,
    e.g.
    can coating), provided that
    combined actual emissions of VOM from all lines at the
    source subject to that subsection never exceed 6.8
    kg/day
    15
    lbs/day
    before the application of capture
    systems and control devices.
    (For example, can coating
    lines within a source would not be subject to the
    limitations of Section 218.204(b)
    of this Subpart if
    the combined actual emissions of VON from the can
    coating lines never exceed 6.8 kg/day
    15
    lbs/day
    before the application of capture systems and control
    devices.)
    Volatile organic material emissions from
    heavy off-highway vehicle products coating lines must
    be combined with VOM emissions from miscellaneous metal
    parts and products coating lines to determine
    applicability.
    Any owner or operator of a coating
    source shall comply with the applicable coating
    analysis test methods and procedures specified in
    Section 218.105(a)
    of this Part and the recordkeeping
    and reporting requirements specified in Section
    218.211(a)
    of this Subpart if total VOM emissions from
    the subject coating lines are always less than or equal
    to 6.8 kg/day
    15
    lbs/day
    before the application of
    capture systems and control devices and,
    therefore, are
    not subject to the limitations of Section 218.204 of
    this Subpart.
    Once a category of coating lines at a
    source is subject to the limitations
    in Section 218.204
    of this Subpart the coating lines are always subject to
    the limitations in Section 218.204
    of this Subpart.
    b)
    Applicability for wood furniture coating
    14
    1)
    The limitations of this Subpart shall apply to a
    source’s wood furniture coating lines if the
    source contains process emission units,
    not
    regulated by Subparts B,
    E, F (excluding Section
    218.204(1)
    of this Subpart), H (excluding Section
    218.405 of this Part),
    Q,
    R,
    5, T
    (excluding
    Section 218.486 of this Part),
    V,
    X,
    Y, or BB of
    this Part, which as a group both:
    A)
    Have a maximum theoretical emissions of 91 Mg
    (100 tons)
    or more per calendar year of VOM
    if no air pollution control equipment were
    used,
    and
    B)
    Are not limited to less than
    91 Mg
    (100 tons)
    of VON per calendar year
    if no air pollution
    control equipment were used, through
    production or capacity limitations contained
    in a federally enforceable permit or SIP
    revision.
    2)
    The limitations of this Subpart shall apply to a
    source’s wood furniture coating
    lines,
    on and
    after March 15,
    1996,
    if the source contains
    process emission units, which as
    a group,
    have a
    potential to emit 22.7 Mg
    (25 tons)
    or more of VOM
    per calendar year and have not limited emissions
    to less than 22.7 Mg
    (25 tons)
    of VOM per calendar
    year through production or capacity limitations
    contained in a federally enforceable operating
    permit or SIP revision,
    and which:
    A)
    Are not regulated by Subparts B,
    E,
    F
    (excluding Section 218.204(1)
    of this
    Subpart),
    H,
    Q,
    R,
    S, T
    (excluding Section
    218.486 of this Part),
    V,
    X,
    Y,
    Z
    or BB of
    this Part; and
    B)
    Are not included
    in any of the following
    categories:
    synthetic organic chemical
    manufacturing industry
    (SOCMI)
    distillation,
    SOCMI reactors,
    plastic parts coating
    (business machines), plastic parts coating
    (other), offset lithography,
    industrial
    wastewater, autobody refinishing, SOCMI batch
    processing, volatile organic liquid storage
    tanks and clean-up solvents operations.
    3)
    If a source ceases to fulfill the criteria of
    subsection
    (b) (1)
    or
    (b) (2)
    of this Section, the
    15
    limitations of Section 218.204(1)
    of this Subpart
    shall continue to apply to any wood furniture
    coating line which was ever subject to the
    limitations of Section 218.204(1)
    of this Subpart.
    4)
    For the purposes of subsection
    (b)
    of this
    Section, an emission unit shall be considered to
    be regulated by a Subpart if it is subject to the
    limitations of that Subpart.
    An emission unit is
    not considered regulated by a Subpart
    if it
    is not
    subject to the limits of that Subpart,
    e.g.,
    the
    emission unit is covered by an exemption in the
    Subpart or the applicability criteria of the
    Subpart are not met.
    5)
    Any owner or operator of a wood furniture coating
    line to which the limitations of this Subpart are
    not applicable due to the criteria
    in subsection
    (b) of this Section shall, upon request by the
    Agency or the USEPA,
    submit records to the Agency
    and the USEPA within 30 calendar days from the
    date of the request that document that the coating
    line is exempt from the limitations of this
    Subpart.
    C)
    On and after March 15,
    1996,
    the limitations of this
    Subpart shall not apply to touch—up and repair coatings
    used by a coating source described by subsections
    218.204(b),
    (d),
    (f),
    (g),
    (i),
    (j),
    (n) and
    (0)
    of
    this Subpart; provided that the source-wide volume of
    such coatings used does not exceed 0.95
    1
    (1 quart) per
    eight—hour period or exceed 209 1/yr
    55
    gal/yr
    for
    any rolling twelve month period.
    Recordkeeping and
    reporting for touch—up and repair coatings shall be
    consistent with Section 218.211(b) (4)
    of this Subpart
    subsection
    (d)
    of this Section.
    d)
    On and after March 15,
    1996,
    the owner or operator of a
    coating line or a group of coating lines using touch—up
    and repair coatings that are exempted from the
    limitations of Section 218.204(b),
    (d),
    (f),
    (g),
    (i),
    (j),
    (n) and
    (o)
    of this Subpart because of the
    provisions of Section 218.208(c)
    of this Subpart shall:
    1)
    Collect and record the name,
    identification
    number, and volume used of each touch—up and
    repair coating,
    as applied on each coating line,
    per eight-hour period and per month;
    2)
    Perform calculations on a daily basis,
    and
    16
    maintain at the source records of such
    calculations, of the combined volume of touch—up
    and repair coatings used source—wide for each
    eight-hour period;
    3)
    Perform calculations on
    a monthly basis,
    and
    maintain at the source records of such
    calculations, of the combined volume of touch-up
    and repair coatings used source—wide for the month
    and the rolling twelve month period;
    4)
    Prepare and maintain at the source an annual
    summary of the information required to be compiled
    pursuant to subsections
    (c) (4) (A)
    and
    (c) (4) (B)
    (d) (1)
    and
    (d) (2)
    of this Section on or before
    January 31 of the following year;
    5)
    Maintain at the source for a minimum period of
    three years all records required to be kept under
    this subsection and make such records available to
    the Agency upon request;
    6)
    Notify the Agency in writing
    if the use of touch-
    up and repair coatings at the source ever exceeds
    a volume of 0.95
    1
    (1 quart)
    per eight-hour period
    or exceeds 209 1/yr
    -f-j55
    gal/yr-J-j for any rolling
    twelve month period within 30 days after any such
    exceedance.
    Such notification shall include a
    copy of any records of such exceedance; and
    7)
    “Touch—up and repair coatings” means,
    for purposes
    of 35 Ill. Adm. Code 218.208, any coating used to
    cover minor scratches and nicks that occur during
    manufacturing and assembly processes.
    (Source:
    Amended at
    _____
    Ill.
    Reg.
    __________,
    effective
    SUBPART Q:
    SYNTHETIC ORGANIC CHEMICAL
    AND POLYMER MANUFACTURING PLANT
    Section 218.431
    Applicability
    a)
    The provisions of Sections 218.431 through 218.436 of
    this Subpart shall apply to:
    1)
    Every owner or operator of any chemical
    manufacturing process unit that manufactures, as a
    primary product, one or more of the chemicals
    17
    listed in Appendix A of this Part and that
    chemical manufacturing process unit causes or
    allows any reactor or distillation unit,
    either
    individually or
    in tandem,
    to discharge one or
    more process vent streams either directly to the
    atmosphere or to a recovery system.
    2)
    All continuous distillation and reactor process
    emission units not subject to Section 218.520
    through 218.527 of this Part, and located within
    Stepan Company’s Millsdale manufacturing facility,
    Elwood, Illinois.
    b)
    Notwithstanding subsection
    (a)
    of this Section, the
    control requirements set forth within Section 218.432
    of this Subpart shall not apply to the following:
    1)
    Any process vent stream with
    a total resource
    effectiveness
    (TRE)
    index value greater than 10.
    However,
    such process vent stream remains subject
    to the performance testing requirements contained
    in Section 218.433 of this Subpart and the
    reporting and recordkeeping requirements contained
    in Section 218.435
    of this Subpart;
    2)
    Any reactor or distillation unit that
    is designed
    and operated as a batch operation;
    3)
    Any reactor or distillation unit that
    is part of a
    polymer manufacturing operation;
    4)
    Any reactor or distillation unit that
    is part of
    the chemical manufacturing process unit with a
    total design capacity of less than
    1 gigagram
    (1,100 tons) per year for all chemicals produced,
    as a primary product, within that process unit.
    However,
    such operations remain subject to the
    reporting and recordkeeping requirements contained
    in Section 218.435(d)
    of this Subpart;
    5)
    Any vent stream with a flow rate less than 0.0085
    scm/mm
    or a total VOM concentration of less than
    500 ppniv,
    less methane and ethane,
    as measured by
    Method 18, or a concentration of VOM of less than
    250 ppmv as measured by Method 25A.
    However, such
    operations remain subject to the performance
    testing requirement listed in Section 218.433 of
    this Subpart,
    as well as the reporting and
    recordkeeping requirements contained in Section
    218.435
    of this Subpart; or
    18
    6)
    Any reactor or distillation unit included within
    an Early Reduction Program,
    as specified in 40 CFR
    63, and published
    in
    57
    Fed.
    Reg.
    61970
    (October
    22,
    1993) jDecember 29,
    1992), evidenced by a
    timely enforceable commitment approved by USEPA.
    (Source:
    Amended at
    _____
    Ill.
    Reg.
    _________,
    effective
    —
    Section 218.434
    Monitoring Requirements
    a)
    The owner or operator of a source subject to the control
    requirements
    in Section 218.432 of this Subpart that uses an
    incinerator to comply with the VOM emission limitation
    specified
    in Section 218.432 (a) (1)
    shall install, calibrate,
    maintain,
    and operate, according to manufacturer’s
    specifications,
    a temperature monitoring device equipped
    with a continuous recorder and having an accuracy of ±1
    percent of the temperature measured expressed
    in degress
    Celsius,
    or ±0.5°C,whichever is greater.
    1)
    Where an incinerator other than a catalytic incinerator
    is used,
    a temperature monitoring device shall be
    installed
    in the firebox.
    2)
    Where a catalytic incinerator is used, temperature
    monitoring devices shall be installed in the gas stream
    immediately before and after the catalyst bed.
    b)
    The owner or operator of a source that uses
    a flare to
    comply with Section 218.432(a) (2)
    of this Subpart shall
    install, calibrate, maintain and operate, according to
    manufacturer’s specifications,
    a heat—sensing device,
    such
    as an ultraviolet beam sensor or thermocouple,
    at the pilot
    light to indicate continuous presence of a flame.
    c)
    The owner or operator of a source that uses a boiler or
    process heater with a design heat input capacity less than
    44 megawatts to comply with Section 218.432(a) (1)
    of this
    Subpart shall install, calibrate, maintain and operate,
    according to the manufacturer’s specifications,
    a
    temperature monitoring device in the firebox.
    The
    monitoring device shall be equipped with a continuous
    recorder with an accuracy of ±1percent of the temperature
    being measured expressed in degrees Celsius or ±0.5°C,
    whichever is greater.
    Any boiler or process heater in which
    all vent streams are introduced with primary fuel
    is exempt
    from this requirement.
    d)
    The owner or operator of
    a process vent with
    a TRE index
    19
    value of 4.0 or less that uses one or more product recovery
    devices shall install either an organic monitoring device
    equipped with a continuous recorder or the monitoring
    equipment specified in subsections
    (d) (1),
    (d) (2),
    (d) (3)
    or
    (d) (4)
    of this Section, depending on the type of recovery
    device used.
    All monitoring equipment shall be installed,
    calibrated and maintained according to the manufacturer’s
    specifications.
    1)
    Where an absorber is the final recovery device in the
    recovery system,
    a scrubbing liquid temperature
    monitoring device and a specific gravity monitoring
    device,
    each equipped with a continuous recorder,
    shall
    be used.
    2)
    Where a condenser is the final recovery device in the
    recovery system,
    a condenser exit
    (product side)
    temperature monitoring device equipped with
    a
    continuous recorder and having an accuracy of ±1
    percent of the temperature being monitored expressed in
    degrees Celsius or ±0.5°C,whichever
    is greater.
    3)
    Where a carbon adsorber is the final recovery device in
    the recovery system, an integrating regeneration Qtream
    steam flow monitoring device having an accuracy of ±10
    percent, capable of recording the total regeneration
    strcam steam mass flow for each regeneration cycle;
    and
    a carbon bed temperature monitoring device having an
    accuracy of ±1percent of the temperature being
    monitored expressed in degrees Celsius of ±0.5°C,
    capable of recording the carbon bed temperature after
    each regeneration and within
    15 minutes of completing
    any cooling cycle.
    4)
    Where a scrubber is used with an incinerator,
    boiler,
    or,
    in the case of halogenated vent streams,
    a process
    heater, the following monitoring equipment
    is required
    for
    the
    scrubber:
    A)
    A
    pH
    monitoring
    device
    equipped
    with
    a
    continuous
    recorder to monitor the pH
    of
    the
    scrubber
    effluent;
    and
    B)
    Flow meters equipped with a continuous recorder at
    the scrubber influent for liquid flow and the
    scrubber inlet for gas stream flow.
    e)
    The owner or operator of a process vent using a vent system
    that contains bypass lines capable of diverting a vent
    stream away from the control device associated with a
    20
    process vent shall comply with either
    (e) (1)
    or
    (e) (2)
    of
    this Section.
    Equipment needed for safety purposes,
    including, but not limited to, pressure relief devices, are
    not subject to this subsection.
    1)
    The owner or operator shall install, calibrate,
    maintain and operate a flow indicator that provides a
    record of vent stream flow at least once every 15
    minutes.
    The flow indicator shall be installed at the
    entrance to any bypass line that could divert the vent
    stream away from the control device to the atmosphere.
    2)
    The owner or operator shall secure the bypass line
    valve in the closed position with a car-seal or a
    lock-and-key type configuration.
    A visual inspection
    of the seal or closure mechanism shall be performed at
    least once every month to ensure that the valve is
    maintained in the closed position and the vent stream
    is not diverted through the bypass line.
    f)
    The owner or operator of a process vent may monitor by an
    equivalent alternative means or parameters other than those
    listed in subsections
    (a) through
    (d)
    of this Section.
    Any
    equivalent alternative shall be approved by the Agency and
    USEPA, and contained in the source’s operating permit as
    federally enforceable permit conditions.
    (Source:
    Amended at
    Ill. Reg.
    _________,
    effective
    Section 218.435
    Recordkeeping and Reporting Requirements
    a)
    Every owner or operator of a reactor or distillation unit
    with a TRE index value of 4.0 or less shall keep records,
    for a minimum of
    3 years,
    of the following parameters
    measured during a performance test or TRE determination
    required under Section 218.433 of this Subpart, and required
    to be monitored under Section 218.434 of this Subpart.
    1)
    Every owner or operator of a source that seeks to
    demonstrate compliance with Section 218.432 (a) (1)
    of
    this Subpart through the use of either a thermal or
    catalytic incinerator shall maintain records of the
    following:
    A)
    The average firebox temperature of the incinerator
    (or the average temperature upstream and
    downstream of the catalyst bed for a catalytic
    incinerator), measured at least every 15 minutes
    and averaged over the same time period of the
    21
    performance testing; and
    B)
    The percent reduction of VOM determined as
    specified in Section 218.433(c)
    of this Subpart
    achieved by the incinerator,
    or the concentration
    of VOM (ppmv,
    by compound)
    determined as specified
    in Section 218.433(c)
    of this Subpart at the
    outlet of the control device,
    on a dry basis,
    corrected to
    3 percent oxygen.
    2)
    Every owner or operator of a source that seeks to
    demonstrate compliance with Section 218.432 (a) (1)
    of
    this Subpart through the use of a boiler or process
    heater shall maintain the records described below.
    Any
    boiler or process heater in which all vent streams are
    introduced with primary fuel are exempt from these
    requirements.
    A)
    A description of the location at which the vent
    stream is introduced into the boiler or process
    heater; and
    B)
    The average combustion temperature of the boiler
    or process heater with a design heat input
    capacity of less than 44 megawatt measured at
    least every 15 minutes and averaged over the same
    time period of the performance testing.
    3)
    Every owner or operator of a source that seeks to
    demonstrate compliance with Section 218.432 (a) (2)
    of
    this Subpart through use of a smokeless
    flare,
    or flare
    design
    (i.e., steam—assisted,
    air—assisted,
    or
    nonassisted), shall maintain records of all visible
    emission readings, heat content determinations,
    flow
    rate measurements, and exit velocity determinations
    made during the performance test,
    continuous records of
    the flare pilot flame monitoring, and records of all
    periods of operations during which the pilot flame is
    absent.
    4)
    Every owner or operator of a source that seeks to
    demonstrate compliance with Section 218.432(b)
    of this
    Subpart shall maintain records of the following:
    A)
    Where an absorber is the final recovery device
    in
    the recovery system,
    the exit specific gravity
    (or
    alternative parameter which is a measure of the
    degree of absorbing liquid saturation,
    if approved
    by the Agency and USEPA, and average exit
    temperature of the absorbing liquid measured at
    22
    least every 15 minutes and averaged over the same
    time period as the performance testing
    (both
    measured while the vent stream is normally routed
    and constituted);
    B)
    Where a condenser is the final recovery device in
    the recovery system, the average exit
    (product
    side)
    temperature measured at least every 15
    minutes and averaged over the same time period as
    the performance testing while the vent stream is
    normally routed and constituted;
    C)
    Where
    a carbon absorber is the final recovery
    device in the recovery system,
    the total strcam
    steam mass or volumetric flow measured at least
    every 15 minutes and averaged over the same time
    period as the performance testing
    (full carbon bed
    cycle),
    the temperature of the carbon bed after
    regeneration
    (and within 15 minutes
    of completion
    of any cooling cycle(s)),
    and duration of the
    carbon bed steaming cycle
    (all measured while the
    vent stream is normally routed and constituted);
    D)
    As an alternative to subsection
    (a) (4) (A),
    (a) (4) (B)
    or
    (a) (4) (C)
    of this Section, the
    concentration level or reading indicated by the
    organic monitoring device at the outlet of the
    absorber,
    condenser,
    or carbon absorber,
    measured
    at least every 15 minutes and averaged over the
    same time period as the performance testing
    (measured while the vent stream
    is normally routed
    and constituted);
    or
    E)
    All measurements and calculations performed to
    determine the flow rate,
    VOM concentration,
    heating value,
    and TRE index value of the vent
    stream.
    b)
    Every owner or operator of a reactor or distillation unit
    with a TRE index value of less than 4.0 shall be subject to
    the exceedance reporting requirements of the draft Enhanced
    Monitoring Guidelines as published at 58 Fed.
    Reg.
    54648
    (October 22,
    1993).
    c)
    Every owner or operator of a source seeking to comply with
    Section 218.432(b)
    of this Subpart shall maintain records of
    the following:
    1)
    Any changes in production capacity,
    feedstock type,
    catalyst type,
    or of any replacement,
    removal,
    or
    23
    addition of recovery equipment or reactors and
    distillation units; and
    2)
    Any recalculation of the flow rate, VON concentration,
    or TRE index value calculated according to Section
    (c)
    of Appendix G of this Part.
    d)
    Every owner or operator of a source claiming a design
    capacity of less than
    1 gigagram (1,100 tons)
    per year,
    as
    contained in Section 218.431(b)
    of this Subpart, shall
    maintain records of the design capacity or any changes
    in
    equipment or operations that may affect the design capacity.
    e)
    Every owner or operator of
    a source claiming a vent stream
    flow rate or vent stream concentration exemption level,
    as
    contained in Section 218.431(b) (5)
    of this Subpart, shall
    maintain records to indicate that the stream flow rate is
    less than 0.0085 scm/mm
    or the vent stream concentration
    is
    less than 500 ppmv.
    (Source:
    Amended at
    _____
    Ill.
    Reg.
    __________
    ,
    effective
    —
    SUBPART FF:
    BAKERY OVENS
    (Repealed)
    Section 218.720
    Applicability (Repealed)
    a)
    The provisions of this Subpart shall apply to every
    owner or operator of a source which operates a bakery
    oven,
    as defined at 35
    Ill. Admin.
    Code 2l1.C80, unless
    tihc~
    source bakes products only for on—site human
    n-mntion or on—site retail sale.
    ~thatanding
    ~_~~on
    (a) of this Section,
    source
    w
    LLgulrcd to comply with the control
    ~
    ~
    “dart
    orL;
    ~
    i
    i
    v
    i
    i
    i. ii
    c
    ci
    u r-
    ci ci
    h
    z
    ~
    th
    ci
    rcguiremefltci
    cli-
    iriii~
    r.tirir
    potential
    to cmii~
    ~
    i
    my
    (.z
    LUflL~)
    or
    more of VON per
    year,
    in the aggregate,
    from all emission units at the
    source,
    cxc lud.~....,.
    1)
    Emission units regulated by Subparts B,
    E,
    F,
    H,
    Q,
    R,
    C,
    T
    (excluding Section 218.486
    of this
    Part),
    V,
    X,
    Y,
    Z or BB of this Part;
    and
    2)
    Emissi,.,., units that
    ...~
    inc1~~.-L. ~
    of the
    following categories:
    synthetic organic chemical
    manufacturing industry
    (COCHI)
    distillation,
    COCMI~
    reactors, wood furniture coating, plastic parts
    coating (business machines),
    plastic parts coating
    24
    (other), offset lithography,
    industrial
    wastcwater,
    autobody refinishing,
    COCHI batch
    processing,
    volatile organic liquid storage tanks
    ~
    ~n—’~
    oolvent~
    operations.
    Every owner or operator of a source which has limited
    its i~ntcntialto emit below 22.7 Mg
    (25 tons)
    of VON
    per year,
    as specified in subsection
    (b)
    of this
    Section, through federally enforceable permit
    conditions
    is not required to comply with this Subpart.
    d)
    Every
    owner
    or
    CXCIU~L
    irum
    t~.nc
    control
    rcquircmcn-w
    01
    LfllB
    ~UD~UEt
    because of the criteria in subsection
    (b)
    of this
    Section remains ~ubjcct
    to the rccordkccping and
    reporting requirements of Section 218.728(b)
    Subpart and the certification rcquircmcnto
    in
    of this
    Scotion
    .~it~.ii0(d)
    of
    this
    Subpart.
    (Source: Repealed at
    _____
    Ill. Reg.
    __________,
    effective
    —
    Section 218.722
    Control Requirements
    (Repealed)
    ~vcry
    owner
    nr
    nn~r.~torof
    a source subject to the
    control requirements of this Subpart shall comply wi’cn
    the requirements of subsection
    (a) (1)
    or
    (a) (2)
    of this
    Section for each bakery oven with a rated heat input
    capacity of at least
    2 mmbtu/hr or at least 586
    kW:
    1)
    Operate emissions capture and control equipment
    which achieves an overall reduction
    in
    uncontrolled VON emissions of at least
    n,-’rs-’r~ni
    ~‘-‘-
    such
    bakcry
    ~
    2)
    Provide
    an
    equivalent
    alternative
    c
    suon
    ~akcry
    ovens
    at
    tnc
    source
    wnion
    nas
    ucen
    approves
    oy
    tnc
    Agency
    ana
    UCEPA
    tnrrillTn Icacrally
    enforceable
    permit
    conai~.....
    revision.
    b)
    An owner or operator of a source subject to the control
    requirements of this Subpart may elect to exempt from
    the control requirements
    in subsections
    (a) (1)
    or
    (a) (2) and
    (c) (1)
    or
    (c) (2)
    of this Section any bakery
    oven with actual VON emissions
    less than or equal to
    15
    TPY; provided that the total actual VON emissions from
    all such exempt bakery ovens never exceed 25 TPY.
    25
    ‘a~s
    t~
    .-Th#-n.-
    —‘..—..~.
    ~——~..—.——‘.
    ~.a
    ‘as
    ~
    ovens at the source which has been
    approved
    by
    the Agency and UCEPA through federally
    enforceable permit conditions or as a SIP
    revision.
    d)
    Any bakery oven that becomes subject to the
    requirements of this Subpart
    at any time shall remain
    subject to the requirements of this Subpart at all
    times thereafter.
    (Source: Repealed at
    Ill.
    Reg.
    __________
    ,
    effective
    —
    Section 218.726
    Testing
    (Repealed)
    I
    ~--.4--’-.
    4-----~~
    (a)
    of
    ..~.
    this Section, until March
    15,
    1998,
    only,
    a
    source
    may
    elect to comply with the control requirements
    in
    subsection
    (c) (1)
    or
    (0)
    (2)
    of this Section, rather
    than the control requirements
    in subsection
    (a) (1)
    or
    (a) (2)
    of this Section,
    if all emission units at the
    source,
    in the aggregate, excluding emission units
    regulated by Subparts B,
    E,
    F, H (excluding Section
    218.405 of this Subpart),
    Q,
    R,
    5,
    T (excluding Section
    218.486 of this Subpart),
    V,
    X,
    Y,
    Z
    or BB of this
    Part, have maximum theoretical emissions of
    less than
    90.7 Mg
    (100 tons)
    of VON p~r
    v~ar or
    are limited to
    1a”~i
    th.,ri
    r)fl7
    Mg
    (iflO
    fcinr~i
    rn-
    vat
    ~mi’~ic1n’~
    pm
    in the
    ak...~.......-e of ai
    ~l1uti...
    -ee&’~’
    ~
    through production or capacity limitati~.~
    _c__,
    ._1,__
    c______t1
    __~!s..
    _~__11s..1
    in
    ~11I1CU
    in
    icacrui~ycniorocuuic
    p~riu1Leoriuii~ion~
    or
    a SIP revision:
    1)
    Operate emissions capture and control equipment
    which
    achieves
    an
    overall
    reduction
    in
    uncontrolled
    VON emissions of at least
    CO
    percent
    from each bakery oven with
    a
    rated heat input
    capacity of at least
    2 mmbtu/hr
    or
    at least 586
    KW; or
    2)
    Provide
    an equivalent alternative control plan for
    suun
    tests in accordance with the applicable test methods
    and procedures specified
    in Section 218.105(f)
    of this
    Part to demonstrate compliance with the control
    requirements of this Subpart and shall:
    1)
    Notify the Agency 30 days prior to conducting such
    26
    tcsts~ and
    2)
    Submit all test
    days of ccnduc1~
    b)
    Nothing in this Section shall limit the authority of
    UCEPA pursuant to the Clean Air Act
    (CAA)
    to require
    testing, or shall affect the authority of USEPA unde
    Section
    114 of the
    CAA
    (42
    U.S.C.
    7414
    (1990)—)--
    (Source: Repealed at
    _____
    Ill. Reg.
    _________,
    effective
    —
    Section 218.727
    Monitoring
    (Repealed)
    a)
    Every owner or operator of
    a bakery oven subject to the
    control requirements of this Subpart shall install and
    operate at all times a device to continuously monitor
    the following parameters for each type of control
    device as
    follow-si-
    1)
    For catalytic oxidizers,
    the inlet and outlet
    temperatures
    of the oxidizer;
    2)
    For regenerative oxidizers,
    the temperature in the
    combustion chamber;
    or
    3)
    For thermal incinerators,
    the temperature in the
    combustion chamber.
    ‘‘~‘
    ‘~“~ ‘~
    ~
    may monitor with an alternative
    “-~ametcrs if approved by the
    enforceable permit
    (Source: Repealed at
    _____
    Ill.
    Reg.
    __________,
    effective
    —
    Section 218.728
    Recordkeeping and Reporting
    (Repealed)
    a)
    Every
    owner
    or
    operator
    of
    a
    bakery
    oven
    shall
    maintain
    the following records for the moot recent consecutive
    3
    year period for all bakery ovens subject
    to the control
    requirements of this Subpart.
    Such records shall be
    made available to the Agency immediately upon request.
    .1
    —F
    methodo; ;;ni~~~
    Agency
    and
    UCEPA
    through
    federally
    conditions or as a SIP revision.
    1)
    Parameters for control devices as monitored
    pursuant to Section 218.727 of this Subpart
    27
    2)
    Hrs/day of operation of
    each
    bakery
    ovcn-j-ET?1 w?144 736 m?473 736 l?S?BT?
    3)
    Factors necessary to calculate VON omissions for
    all bakery ovens including, but not limited to,
    type of dough used for each yeast-leavened baked
    product,
    initial yeast percentage for
    ea-e1~i
    product, total fermentation time for each product,
    any additional percentage of yeast added,
    and the
    fermentation time of any additional yeas-ti
    C~tlculateddaily VON cmiooi~~
    -ef
    ~ch
    bakery
    expressed
    as
    lbs/day;
    5)
    Total
    amount
    of
    each
    type
    of
    yeast-l
    product
    produced
    by
    each
    bakery
    oven
    lbs/day.
    b)
    Every owner or operator of a bakery oven which
    is
    exempt from the control requirements of this Subpart
    because of the criteria
    in Section 218.720(b)
    of this
    Subpart shall maintain records necessary to demonstrate
    that its potential to emit is less than 22.7 Mg
    (25
    tons)
    of VON per year,
    as
    218.720(b).
    Such ret-!r~~d~
    mos’-
    -cacnt
    ~cified
    in Ccct~-~
    “~‘‘
    l-~-~
    maintained for ~-‘-e
    -3-
    period and shall
    be
    -~
    available to the Agency immediately upon request.
    1tt’-..’-—’—.
    a)
    Every owner
    exempt from
    or
    the
    operator
    control
    of a bakery
    requirements
    oven whic
    of this
    h is
    Subpart
    because of the criteria specified in Section 218.722(b)-
    of this Subpart shall:
    1)
    ctua’
    ¶1f~1R
    .1
    ~.-.-~_-
    ~
    necessary
    1r~
    m~n~.i1r
    th~i-
    Fhi
    ~
    from
    exempt
    bakery
    or
    equal
    to
    15
    TPY
    for
    each
    bakery
    oven
    and
    less than or equal to 25 TPY from all
    exempt
    b~kcryovens combined.
    Such records shall
    be
    maintained for the most recent consecutive
    3 year
    period and shall be made available to the Agency
    immr~rii~fi—1~i
    nnr~n
    ir-~-~1-
    2)
    Notify
    the
    Agency
    in
    writing
    if the actual VOM
    xempt bak_~
    -
    ~---.,.,
    .~
    .-.
    ~
    ~
    ~
    a~mI .~3 ~
    I ci
    fl!~ r
    r
    iim
    i fl
    a.
    1 S
    TPV
    r~r
    ncir-li..
    -
    vciri
    r’m
    .~.
    -.
    .~
    -
    TPY,
    within 30 ~e—a2~
    the ~
    Such notice shall include a copy of all records of
    the
    cxcccdance.
    y
    ~-
    i--a~-v nvcin
    ~-~Jr~ u
    cixcir~r~i1
    —
    ~
    cxcmnt
    baker”
    “~
    25
    —
    occurs
    ~&)
    -~
    l-~-_~
    -‘
    -~
    1
    28
    controlling
    emissions
    as
    provided
    in
    Section
    218.722(c)
    of this Subpart until March 15,
    1998,
    shall maintain
    records necessary to demonstrate that its maximum
    theoretical emissions as specified in Section
    218.722(c)
    arc less than 90.7 Hg
    (100 tons)
    of VON per
    year.
    Such records shall be maintancd for the most
    recent consecutive
    3 year period and shall be made
    available to the Agency immediatley upon request.
    (Source:
    Repealed
    at
    _____
    Ill.
    Reg.
    __________,
    effective
    —
    Section 218.729
    Compliance Date
    (Repealed)
    On and after March
    15,
    1996,
    upon initial startup
    or upon
    modification,
    every
    owner or operator of a source
    subject
    to
    this
    Subpart shall comply with the requirements
    of this Subpart.
    (Source: Repealed at
    Ill.
    Reg.
    __________,
    effective
    Certification (Repealed)
    tor
    of
    a source subject to the
    of
    this
    Subpart
    shall
    certify
    r.~parton or before a
    date
    218.729 of this Subpart.
    —
    1
    control requirements of this Subpart
    of
    compliance,
    the
    owner
    or
    pnrritnr
    compliance with the reguirem
    the alternative method upnn
    compliance.
    --
    c)
    All certifications
    of compliance with this Subpart
    shall
    include
    the
    results
    of
    all tests and the
    calculations
    performed
    ~
    ~
    that
    each
    ::~p1ianccwith,
    or is exempt from,
    its of this Cubpa:~
    i..
    —
    1 1
    —
    1 ..~
    -~
    4- K
    ~
    1
    1
    ~‘~‘ing
    -
    thr
    ~niirc~
    i
    :-~
    i n
    cimnr
    the control
    i—i--r~’i
    rt
    -
    t~
    1)
    The name and identification number of each oven
    and any associated capture and control dcvice;
    2)
    The maximum rated heat input of each oven;
    3)
    A eicissification of each oven as either a
    “bakery
    Section 218.730
    .,
    the method
    shall _~rtify
    ents o~~hio Subpart
    f-.-.~
    changi~ the method of
    29
    4)
    The capture and control efficiency of each bakery
    oven
    control
    device;
    5)
    Test reports, calculations, and other data
    necessary to demonstrate that the capture and
    control efficiency of each bakery
    oven
    control
    device achieves an overall reduction
    in
    uncontrolled VON cmiss~-~n~i
    of at least 81 per
    -6)
    The
    date
    each
    bak
    4-
    ~L1
    .-.~
    4
    d)
    On or before March
    15,
    1996,
    or upon initial startup,
    every owner or operator of a
    bakery oven which
    is
    exempt from the control requirements of this Subpart
    because of the criteria
    in Section 218.720(b)
    of this
    Subpart shall certify that its potential to emit
    is
    lcs~than 22.7 Hg
    (25 tons)
    of VON per year,
    as
    specified
    in
    Section
    218.720(b).
    c)
    —
    1~
    I
    ~
    upon ~-~4-ialsta~tup,
    .._.~
    owner or
    opcra...or
    of
    a
    bakery
    oven
    which
    is
    exempt from the control requirements of this Subpart
    because of the criteria specified
    in Section 218.722(b)
    of this Subpart shall certify that actual VON emissions
    from any individual exempt bakery oven never exceed 15
    TPY and that VON emissions from all exempt bakery
    ovens,
    in
    the
    aggregate,
    never exceed 25 TPY.
    f)
    On
    or
    before
    March
    15,
    1996,
    or upon initial startup if
    prior
    to
    March
    15,
    1998,
    every
    owner
    or
    operator
    of
    a
    bakery oven which is controlling emissions
    as provided
    by Section 218.722(c)
    of this Subpart shall certify
    that its maximum theoretical emissions as specified
    in
    Section 218.722(c)
    arc less than 90.7 Mg
    (100 tons)
    of
    VOM
    r~nrv~r.
    --
    -L
    (Source: Repealed at
    _____
    Ill.
    Reg.
    __________,
    effective
    SUBPART TT:
    OTHER EMISSION UNITS
    Section 218.980
    Applicability
    d exclusively to bake non—y
    .1
    —
    30
    a)
    Maximum theoretical emissions:
    1)
    A source is
    subject
    to
    this Subpart if
    it contains
    process emission units not regulated by Subparts
    B,
    E, F (excluding Section 218.204(1)
    of this
    Part), H (excluding Section 218.405 of this Part),
    Q,
    R,
    S, T
    (excluding Section 218.486
    of this
    Part),
    V,
    X,
    Y,
    Z or BB of this Part,
    which as a
    group both:
    A)
    Have maximum theoretical emissions
    of 90.7
    Mg
    (100 tons)
    or more per calendar year of VOM,
    and
    B)
    Are not limited to less than 90.7 Mg
    (100
    tons)
    of VON emissions per calendar year in
    the absence of air pollution control
    equipment through production or capacity
    limitations contained
    in a federally
    enforceable permit or a SIP revision.
    2)
    If a source
    is subject to this Subpart as provided
    in this Subpart, the requirements of this Subpart
    shall apply to a source’s VOM emission units which
    are not included within any of the categories
    specified
    in Subparts
    B,
    E,
    F,
    H,
    Q,
    R,
    5,
    T,
    V,
    X,
    Y,
    Z,
    AA,
    BB, PP, QQ, or RR of this Part or
    which are not exempted from permitting
    requirements pursuant to 35 Ill. Adm.
    Code
    201.146.
    b)
    Potential to emit:
    1)
    A source is subject to this Subpart
    if it has the
    potential to emit 22.7 Mg
    (25 tons)
    or more of VON
    per year,
    in aggregate,
    from emission units,
    other
    than furnaces at glass container manufacturing
    sources and VON leaks from components, that are:
    A)
    Not regulated by Subparts B,
    E,
    F,
    H,
    Q,
    R,
    5,
    T,
    (excluding Section 218.486
    of this
    Part),
    V,
    X,
    Y,
    Z,
    or BB of this Part,
    or
    B)
    Not included
    in any of the following
    categories:
    synthetic organic chemical
    manufacturing industry
    (SOCMI)
    distillation,
    SOCMI reactors, wood furniture, plastic parts
    coating (business machines),
    plastic parts
    coating
    (other), offset lithography,
    industrial wastewater,
    autobody refinishing,
    31
    SOCMI batch processing,
    volatile organic
    liquid
    storage
    tanks
    and
    clean—up
    solvents
    operations.
    2)
    If a source is subject to this Subpart as provided
    above,
    the requirements
    of this Subpart shall
    apply to a source’s VOM emission units, which are:
    A)
    Not included within any of the categories
    specified in Subparts B,
    E,
    F,
    H,
    Q,
    R,
    S,
    T,
    V,
    X,
    1,
    Z,
    AA,
    BB,
    CC, DD,
    PP,
    QQ
    or RR of
    this Part,
    or which are not exempted from
    permitting requirements pursuant to 35
    Ill.
    Adm. Code
    201.146
    (excluding Section
    201.146(0)
    and
    (p)),
    or
    B)
    Not included in any of the following
    categories:
    synthetic organic chemical
    manufacturing industry
    (SOCMI)
    distillation,
    SOCMI reactors, wood furniture, plastic parts
    coating (business machines),
    plastic parts
    coating
    (other), offset lithography,
    industrial wastewater,
    autobody refinishing,
    SOCMI batch processing, volatile organic
    liquid storage tanks and clean—up solvents
    operations.
    c)
    If a source ceases to fulfill the criteria of
    subsections
    (a)
    and/or
    (b)
    of this Section, the
    requirements of this Subpart shall continue to apply to
    an emission unit which was ever subject to the control
    requirements of Section 219.986 of this Part.
    d)
    No limits under this Subpart shall apply to emission
    units with emissions of VON to the atmosphere less than
    or equal to 2.3 Mg
    (2.5 tons)
    per calendar year
    if the
    total emissions from such emission units not complying
    with Section 219.986 of this Part does not exceed 4.5
    Mg
    (5.0 tons) per calendar year.
    e)
    For the purposes of this Subpart, an emission unit
    shall be considered regulated by
    a Subpart,
    if it
    is
    subject to the limits of that Subpart.
    An emission
    unit is considered not regulated by
    a Subpart
    if
    it is
    not subject to the limits of that Subpart,
    e.g., the
    emission unit
    is covered by an exemption in the Subpart
    or the applicability criteria of the Subpart are not
    met.
    f)
    The control requirements
    in Subpart TT shall not apply
    32
    to
    sewage treatment plants; vegetable oil extraction
    and processing; coke ovens
    (including by-product
    recovery
    plants);
    fuel
    combustion
    units;
    bakeries;
    barge
    loading
    facilities;
    jet
    engine
    test
    cells;
    production
    of
    polystyrene
    foam insulation board
    including
    storage
    and
    extrusion
    of
    scrap
    where
    blowing
    agent
    is
    added
    to
    the
    polystyrene resin at the source,
    but not including blending and preliminary expansion of
    resin prior to molding where blowing agent
    is
    incorporated into the polystyrene resin by the producer
    of the resin; production of polystyrene or polyethylene
    foam
    packaging
    not including blending and preliminary
    expansion of resin prior to molding where blowing agent
    is
    incorporated
    into the polystyrene or polyethylene
    resin by the producer of the resin,
    and not including
    storage and extrusion of scrap where blowing agent is
    added to the polystyrene or polyethylene resin at the
    source;
    and iron and steel production; and furnaces at
    glass
    container
    manufacturing
    sources.
    (Source:
    Amended at
    Ill.
    Reg.
    __________,
    effective
    Section 218.Appendix G
    TRE Index Measurements for SOCMI
    Reactors and Distillation Units
    For purposes of Subpart
    Q,
    Sections 218.431 through 218.435, the
    following apply:
    a)
    The following test methods shall be used to determine
    compliance with the total resource effectiveness
    (“TRE”)
    index value:
    1)
    Method
    1 or
    1A, incorporated by reference at Section
    218.112 of this Part, as appropriate,
    for selection of
    the sampling site.
    A)
    The sampling site for the vent stream molar
    composition determination and flow rate prescribed
    in subsections
    (a) (2)
    and
    (a)
    (3)
    of this Appendix
    shall be, except for the situations outlined
    in
    subsection
    (a) (1) (B),
    after the final recovery
    device,
    if a recovery system is present, prior to
    the inlet of any control device,
    and prior to any
    post-reactor or post-distillation unit
    introduction of halogenated compounds into the
    vent stream.
    No traverse site selection method is
    needed for vents smaller than
    10 cm in
    diameter.
    33
    B)
    If any gas stream other than the reactor or
    distillation unit vent stream is normally
    conducted through the final recovery device:
    i)
    The sampling site for vent stream flow rate
    and molar composition shall be prior to the
    final recovery device and prior to the point
    at which any nonreactor or nondistillation
    unit vent stream or stream from
    a nonaffected
    reactor or distillation unit is introduced.
    Method 18 incorporated by reference at
    Section
    218.112
    of this Part,
    shall be used
    to measure organic compound concentrations at
    this site.
    ii)
    The efficiency of the final recovery device
    is determined by measuring the organic
    compound concentrations using Method
    18,
    incorporated by reference at Section 218.112
    of this Part,
    at the inlet to the final
    recovery device after the introduction of all
    vent streams and at the outlet of the final
    recovery device.
    iii)
    The efficiency of the final recovery device
    determined according to subsection
    (a) (1) (B) (ii) of this Appendix shall be
    applied to the organic compound
    concentrations measured according to
    subsection
    (a) (1) (B) (i)
    of this Appendix to
    determine the concentrations of organic
    compounds from the final recovery device
    attributable to the reactor or distillation
    unit vent stream.
    The resulting organic
    compound concentrations are then used to
    perform the calculations outlined
    in
    subsection
    (a) (4) of this Appendix.
    2)
    The molar composition of the vent stream shall be
    determined as follows:
    A)
    Method 18,
    incorporated by reference at Section
    218.112 of this Part, to measure the concentration
    of organic compounds including those containing
    halogens;
    B)
    ASTM Dl946-77,
    incorporated by reference
    at
    Section 218.112
    of this Part,
    to measure the
    concentration of carbon monoxide and hydrogen;
    and
    34
    C)
    Method
    4,
    incorporated
    by
    reference
    at
    Section
    218.112 of this Part,
    to measure the content of
    water
    vapor.
    3)
    The volumetric flow rate shall be determined using
    Method 2,
    2A,
    2C,
    or 2D, incorporated by reference at
    Section
    218.112 of this Part,
    as appropriate.
    4)
    The emission rate of VOM (minus methane and ethane)
    (EVOM)
    in the vent stream shall be calculated using the
    following formula:
    n
    EVOM
    =
    K2
    ~
    C1M1
    Q5
    j=l
    where:
    EVOM
    =
    Emission rate of VOM
    (minus methane and
    ethane)
    in the sample, kg/hr.
    K2
    =
    Constant,
    2.494
    x 10~ (l/ppmv) (g-
    mole/scm) (kg/g) (min/hr), where standard
    temperature for
    (g—molefscm)
    is 20°C.
    C1
    =
    Concentration of compound
    j,
    on a dry
    basis,
    in ppmv as measured by Method 18,
    incorporated by reference at Section
    218.112 of this Part,
    as indicated in
    Section 218.433(c) (3) of this Part.
    =
    Molecular weight of sample
    j,
    g/g-mole.
    Q~
    =
    Vent stream flow rate
    (scm)
    at a
    temperature of
    20°C.
    5)
    The total vent stream concentration (by volume)
    of
    compounds containing halogens
    (ppmv,
    by compound)
    shall
    be summed from the individual concentrations of
    compounds containing halogens which were measured by
    Method
    18,
    incorporated
    by
    reference
    at
    Section
    218.112
    of this Part.
    6)
    The net heating value of the vent stream shall be
    calculated using the following:
    n
    HT
    =
    K1 ~
    C1H1
    (l-B~~)
    j=l
    where:
    35
    HT
    =
    Net heating value of the sample
    (MJ/scm),
    where
    the
    net
    enthaply
    per
    mole of vent stream is based on
    combustion of 25°Cand 760 mmHG, but the
    standard
    temperature
    for
    determining
    the
    volume
    corresponding
    to
    one
    mole
    is
    2-~~
    2OQC,
    as in the definition of Q,
    (vent
    stream flow rate).
    K1
    =
    Constant,
    1.740 x 10~ (ppmv)1
    (g-mole/scm),
    (MJ/KCal),
    where standard
    temperature for
    (g-mole/scm)
    is 20°C.
    B~5
    =
    Water vapor content of the vent stream,
    proportion by volume; except that
    if the vent
    stream passes through a final stream jet and
    is not condensed,
    it shall be assumed that
    B~5
    =
    0.023
    in order to correct to 2.3
    percent moisture.
    C1
    =
    Concentration on a dry basis of compound
    j
    in ppmv,
    as measured for all organic
    compounds by Method
    18,
    incorporated by
    reference at Section 218.112 of this
    Part, and measured for hydrogen and
    carbon monoxide by using ASTM Dl946-77,
    incorporated by reference at Section
    218.112 of this Part.
    H1
    =
    Net heat of combustion of compound
    j,
    kCal/g—mole, based on combustion at 25°C
    and 760 mmHG.
    The heats of combustion
    of vent stream components shall be
    determined using ASTM D2382-83,
    incorporated by reference at Section
    218.112 of this Part,
    if published
    values are not available or cannot be
    calculated.
    b)
    1)
    The TRE index value of the vent shall be calculated
    using the following:
    TRE
    =
    1~a
    +
    b
    (Q3)
    +
    c
    (HT)
    +
    d
    (Ev(M)J
    where:
    EVOM
    36
    TRE
    =
    TRE index value.
    EVOM
    Qs
    HT
    EVOM
    a,b,
    =
    c,d
    Hourly emission rate of VON
    (kg/hr)
    as
    calculated in subsection
    (a)
    (4)
    of this
    Appendix.
    =
    Vent stream flow rate scm/mm
    at a
    standard temperature of
    20°C.
    =
    Vent
    stream
    net
    heating
    value
    (NJ/scm),
    as calculated in subsection
    (a) (6)
    of
    this Appendix.
    Hourly emission rate of VON (minus methane
    and ethane),
    (kg/hr)
    as calculated
    in
    subsection
    (a) (4)
    of this Appendix.
    Value of coefficients presented below
    are:
    V?~
    1
    lip
    flf (~pFf~,‘j
    c~r~4-
    Type of
    Stream
    Nonhalogenated
    Basis
    ‘are
    2.129
    0.183 —0.005
    0.359
    Thermal incinerator
    zero
    (0)
    Percent heat
    Recovery
    Thermal incinerator
    70 Percent heat
    Recovery
    3.075
    0.021 —0.037
    0.018
    803
    0.032 —0.042
    0.007
    Halogenated
    Thermal
    5.470
    incinerator
    and scrubber
    0.
    ~-040
    0.004
    2)
    Every owner or operator of a vent stream shall use tn~..
    applicable coefficients identified for values a,
    b,
    c
    and d in subsection
    (b) (1)
    of this Appendix to
    calculate the TRE index value based on a flare,
    a
    thermal incinerator with zero percent heat recovery,
    and a thermal incinerator with 70 percent heat
    recovery,
    and shall select the lowest TRE index value.
    3)
    Every owner or operator of a reactor or distillation
    unit with a halogenated vent stream,
    determined as any
    stream with a total concentration of halogen atoms
    contained in organic compounds of
    200 ppmv or greater,
    37
    shall use the applicable coefficients identified for
    values a,
    b,
    c and d in subsection
    (b)
    (1)
    of this
    Appendix
    to
    calculate
    the
    TRE
    index
    value
    based
    on
    a
    thermal
    incinerator
    and
    scrubber.
    C)
    Every
    owner
    or
    operator
    of
    a
    source
    seeking to comply with
    Section
    218.432(b)
    of this Part shall recalculate the flow
    rate and VOM concentration for each affected vent stream
    whenever process changes are made.
    Examples of process
    changes include, but are not limited to, changes in
    production capacity, feedstock type, or catalyst type,
    or
    whenever there is replacement,
    removal,
    or addition of
    recovery equipment.
    The flow rate and VOM concentration
    shall be recalculated based on test data, or on
    best
    engineering estimates of the effects of the change to the
    recovery system.
    d)
    Whenever a process change,
    as defined in Section 218.435(c)
    of this Subpart, yields a TRE index value of 1.0 or less,
    the owner or operator shall notify and submit a report to
    the Agency according to the requirements specified in
    Section 218.435(c)
    of this Subpart, within 180 calendar days
    after the process change and shall conduct a performance
    test according to the methods and procedures required by
    Section
    218.433 of this Part.
    e)
    For the purpose of demonstrating that a process vent stream
    has
    a
    VON
    concentration
    below
    500
    ppmv,
    the
    following
    shall
    be used:
    1)
    The sampling site shall be selected as specified
    in
    Section 218.433(c) (1)
    of this Part.
    2)
    Method
    18 or Method 25A of 40 CFR Part 60, Appendix A,
    incorporated by reference at Section 218.112
    of this
    Part,
    shall be used to measure concentration;
    alternatively,
    any other method or data that has been
    validated according to the protocol in Method 301 of 40
    CFR Part 63, Appendix A,
    incorporated by reference at
    Section
    218.112
    of this Part,
    may be used.
    3)
    Where
    Method
    18
    is used,
    the following procedures shall
    be used to calculate ppmv concentration:
    i)
    The minimum sampling time for each run shall be
    1
    hour
    in which either an integrated sample or four
    grab samples shall be taken.
    If grab sampling is
    used, then the samples shall be taken at
    approximately equal intervals
    in time, such as
    15
    minute intervals during the run.
    38
    ii)
    The concentration of VOM shall be calculated using
    Method
    18 according to Section 218.433(c) (4)
    of
    this
    Part.
    4)
    Where Method 25A
    is used,
    the following procedures
    shall
    I~eused to calculate ppmv VOM concentration:
    A)
    Method 25A shall be used only if a single VON is
    greater than 50 percent of total VOM, by volume,
    in the process vent stream.
    B)
    The vent stream composition may be determined by
    either~process
    knowledge,
    test
    data
    collected
    using an
    appropriate
    Reference
    Method
    or
    a
    method
    of data collection validated according to the
    protocol
    in Method 301 of
    40 CFR Part
    63, Appendix
    A,
    incorporated by reference at Section 218.112
    of this Part.
    Examples of information that
    constitute process knowledge include calculations
    based
    on material balances, process stoichiometry,
    or previous test results provided the results are
    still relevant to the current process vent stream
    conditions.
    C)
    The VON used as the calibration gas for Method 25A
    shall be the single VOM present at greater than
    50
    percent of the total VOM by volume.
    D)
    The span value for Method 25A shall be 50 ppmv.
    E)
    Use
    of Method 25A is acceptable if the response
    from the high-level calibration gas
    is at least 20
    times the standard deviation of the response from
    the zero calibration gas when the instrument
    is
    zeroed on the most sensitive scale.
    F)
    The concentration of VOM shall be corrected to
    3
    percent oxygen using the procedures and equation
    in Section 218.433(c) (3)
    of this Part.
    5)
    The owner or operator shall demonstrate that the
    concentration of VOM,
    including methane and ethane,
    measured by Method 25A is below 250
    ppnmv to qualify for
    the low concentration exclusion
    in Section 218.431
    of
    this Part.
    (Source:
    Amended
    at
    Ill.
    Reg.
    _________
    effective
    39
    TITLE 35:
    ENVIRONMENTAL PROTECTION
    SUBTITLE B:
    AIR POLLUTION
    CHAPTER
    I:
    POLLUTION
    CONTROL BOARD
    SUBCHAPTER c:
    EMISSIONS STANDARDS
    AND
    LIMITATIONS
    FOR
    STATIONARY
    SOURCES
    PART 219
    ORGANIC MATERIAL EMISSION STANDARDS AND
    LIMITATIONS
    FOR
    THE METRO EAST AREA
    SUBPART A:
    GENERAL PROVISIONS
    Section
    219. 100
    219. 101
    219. 102
    219.103
    219.104
    219.105
    219.106
    219.107
    219.108
    219.109
    219.110
    219.111
    219.112
    219. 113
    Section
    Introduction
    Savings
    Clause
    Abbreviations
    and
    Conversion
    Factors
    Applicability
    Definitions
    Test Methods and Procedures
    Compliance
    Dates
    Operation of Afterburners
    Exemptions, Variations,
    and Alternative Means of
    Control
    or Compliance Determinations
    Vapor Pressure of Volatile Organic Liquids
    Vapor Pressure of Organic Material or Solvent
    Vapor
    Pressure of Volatile Organic Material
    Incorporations by Reference
    Monitoring for Negligibly-Reactive Compounds
    SUBPART B:
    ORGANIC EMISSIONS FROM STORAGE
    AND LOADING OPERATIONS
    219.119
    219.120
    219.121
    219.122
    219.123
    219.124
    219.125
    219.126
    219.
    127
    219. 128
    219.129
    Section
    219.141
    Applicability for VOL
    Control Requirements for Storage Containers of VOL
    Storage Containers of VPL
    Loading Operations
    Petroleum Liquid Storage Tanks
    External
    Floating
    Roofs
    Compliance
    Dates
    Compliance Plan
    (Repealed)
    Testing VOL Operations
    Monitoring VOL Operations
    Recordkeeping and Reporting for VOL Operations
    SUBPART C:
    ORGANIC EMISSIONS FROM
    MISCELLANEOUS EQUIPMENT
    Separation Operations
    40
    219.142
    Pumps and Compressors
    219.143
    Vapor Blowdown
    219.144
    Safety Relief Valves
    SUBPART
    E:
    SOLVENT
    CLEANING
    Section
    219.181
    Solvent Cleaning in General
    219.182
    Cold
    Cleaning
    219.183
    Open Top Vapor Degreasing
    219.184
    Conveyorized Degreasing
    219.185
    Compliance
    Schedule
    (Repealed)
    219.186
    Test Methods
    SUBPART
    F:
    COATING OPERATIONS
    Section
    219.204
    Emission Limitations
    219.205
    Daily—Weighted
    Average
    Limitations
    219.206
    Solids
    Basis
    Calculation
    219.207
    Alternative Emission Limitations
    219.208
    Exemptions
    From Emission Limitations
    219.209
    Exemption
    From
    General
    Rule
    on
    Use
    of
    Organic
    Material
    219.210
    Compliance Schedule
    219.211
    Recordkeeping
    and
    Reporting
    219.212
    Cross-Line Averaging to Establish Compliance for
    Coating
    Lines
    219.213
    Recordkeeping
    and
    Reporting
    for
    Cross-Line
    Averaging
    Participating
    Coating
    Lines
    219.214
    Changing Compliance Methods
    SUBPART G:
    USE OF ORGANIC MATERIAL
    Section
    219.301
    Use of Organic Material
    219.302
    Alternative
    Standard
    219.303
    Fuel Combustion Emission Units
    219.304
    Operations with Compliance Program
    SUBPART H:
    PRINTING AND PUBLISHING
    Section
    219.401
    Flexographic and
    Rotogravure
    Printing
    219.402
    Applicability
    219.403
    Compliance Schedule
    219.404
    Recordkeeping
    and
    Reporting
    219.405
    Lithographic Printing:
    Applicability
    219.406
    Provisions Applying to Heatset Web Offset Lithographic
    Printing Prior to March
    15,
    1996
    219.407
    Emission Limitations and Control Requirements for
    41
    Lithographic Printing Lines On and After March
    15,
    1996
    219.408
    Compliance Schedule for Lithographic Printing on and
    After
    March
    15,
    1996
    219.409
    Testing for Lithographic Printing On and After March
    15,
    1996
    219.410
    Monitoring Requirements for Lithographic Printing
    219.411
    Recordkeeping and Reporting for Lithographic Printing
    SUBPART
    Q:
    SYNTHETIC
    ORGANIC
    CHEMICAL
    AND
    POLYMER
    MANUFACTURING
    PLANT
    Section
    219.421
    219.422
    219.423
    219.424
    219.425
    219.426
    219.427
    219.428
    219.429
    219.430
    219.431
    219.432
    219.433
    219.434
    219.435
    219.436
    Section
    219.441
    219.442
    219.443
    219.444
    219.445
    219.446
    219.447
    219.448
    219.449
    219.450
    219.451
    219.452
    219.453
    General Requirements
    Inspection Program Plan for Leaks
    Inspection Program for Leaks
    Repairing
    Leaks
    Recordkeeping for Leaks
    Report
    for
    Leaks
    Alternative Program for Leaks
    Open-Ended Valves
    Standards for Control Devices
    Compliance Date
    (Repealed)
    Applicability
    Control Requirements
    Performance and Testing Requirements
    Monitoring Requirements
    Recordkeeping
    and
    Reporting
    Requirements
    Compliance Date
    SUBPART
    R:
    PETROLEUM
    REFINING
    AND
    RELATED INDUSTRIES; ASPHALT MATERIALS
    Petroleum Refinery Waste Gas Disposal
    Vacuum Producing Systems
    Wastewater
    (Oil/Water)
    Separator
    Process Unit Turnarounds
    Leaks:
    General Requirements
    Monitoring Program Plan for Leaks
    Monitoring Program for Leaks
    Recordkeeping for Leaks
    Reporting for Leaks
    Alternative Program for Leaks
    Sealing Device Requirements
    Compliance Schedule for Leaks
    Compliance
    Dates
    (Repealed)
    SUBPART
    S:
    RUBBER AND MISCELLANEOUS
    PLASTIC PRODUCTS
    42
    Section
    219.461
    Manufacture
    of
    Pneumatic
    Rubber
    Tires
    219.462
    Green Tire Spraying Operations
    219.463
    Alternative Emission Reduction Systems
    219.464
    Emission
    Testing
    219.465
    Compliance
    Dates
    (Repealed)
    219.466
    Compliance
    Plan
    (Repealed)
    SUBPART T:
    PHARMACEUTICAL MANUFACTURING
    Section
    219.480
    Applicability
    219.481
    Control of Reactors,
    Distillation Units,
    Crystallizers,
    Centrifuges
    and
    Vacuum
    Dryers
    219.482
    Control of Air Dryers,
    Production Equipment Exhaust
    Systems and Filters
    219.483
    Material Storage and Transfer
    219.484
    In—Process
    Tanks
    219.485
    Leaks
    219.486
    Other Emission Units
    219.487
    Testing
    219.488
    Monitoring for Air Pollution Control Equipment
    219.489
    Recordkeeping for Air Pollution Control Equipment
    SUBPART V:
    BATCH OPERATIONS AND AIR OXIDATION PROCESSES
    Section
    219.500
    Applicability for Batch Operations
    219.501
    Control Requirements for Batch Operations
    219.502
    Determination of Uncontrolled Total Annual Mass
    Emissions
    and
    Actual
    Weighted Average Flow Rate Values
    for
    Batch
    Operations
    219.503
    Performance and Testing Requirements for Batch
    Operations
    219.504
    Monitoring Requirements for Batch Operations
    219.505
    Reporting
    and
    Recordkeeping
    for
    Batch
    Operations
    219.506
    Compliance Date
    219.520
    Emission Limitations for Air Oxidation Processes
    219.521
    Definitions (Repealed)
    219.522
    Savings
    Clause
    219.523
    Compliance
    219.524
    Determination of Applicability
    219.525
    Emission Limitations for Air Oxidation Processes
    (Renumbered)
    219.526
    Testing
    and
    Monitoring
    219.527
    Compliance Date
    (Repealed)
    SUBPART W:
    AGRICULTURE
    Section
    43
    Architectural Coatings
    Paving
    Operations
    Cutback Asphalt
    Section
    219.581
    219.582
    219.583
    219.584
    219.585
    219.586
    Section
    219.601
    219.602
    219.603
    219.604
    219.605
    219.606
    219.607
    219.608
    219.609
    219.610
    219.611
    219.612
    219.613
    Bulk Gasoline Plants
    Bulk Gasoline Terminals
    Gasoline Dispensing Operations
    —
    Storage Tank Filling
    Operations
    Gasoline Delivery Vessels
    Gasoline Volatility Standards
    Gasoline Dispensing Operations
    -
    Motor Vehicle Fueling
    Operations
    (Repealed)
    SUBPART Z:
    DRY CLEANERS
    Perchloroethylene Dry Cleaners
    Exemptions
    Leaks
    Compliance Dates
    (Repealed)
    Compliance Plan
    (Repealed)
    Exception to Compliance Plan
    (Repealed)
    Standards for Petroleum Solvent Dry Cleaners
    Operating Practices for Petroleum Solvent Dry Cleaners
    Program
    for
    Inspection
    and
    Repair
    of
    Leaks
    Testing
    and
    Monitoring
    Exemption
    for
    Petroleum
    Solvent
    Dry
    Cleaners
    Compliance
    Dates
    (Repealed)
    Compliance Plan
    (Repealed)
    SUBPART AA:
    PAINT AND INK MANUFACTURING
    Section
    219.620
    219.621
    219.623
    219.624
    219.625
    219.626
    219.628
    219.630
    219.636
    Applicability
    Exemption for Waterbase Material and Heatset-Offset Ink
    Permit Conditions
    Open—Top
    Mills,
    Tanks,
    Vats
    or
    Vessels
    Grinding Mills
    Storage
    Tanks
    Leaks
    Clean Up
    Compliance Schedule
    219.541
    Pesticide
    Exception
    SUBPART
    X:
    CONSTRUCTION
    Section
    219.561
    219.562
    219.563
    SUBPART
    Y:
    GASOLINE DISTRIBUTION
    44
    219.637
    Recordkeeping
    and
    Reporting
    SUBPART BB:
    POLYSTYRENE PLANTS
    Section
    219.640
    219.642
    219.644
    Section
    219.720
    219.722
    219.726
    219.727
    219.728
    219.729
    219.730
    Section
    219.760
    219.762
    219.764
    219.766
    219.768
    219.770
    Section
    219.780
    219.782
    219.784
    219.786
    219.787
    219.788
    219.789
    219.790
    219.791
    219.792
    219.875
    219.877
    219.879
    219.881
    219.883
    219.886
    Applicability
    Emissions
    Limitation
    at
    Polystyrene
    Plants
    Emissions Testing
    SUBPART
    FF:
    BAKERY
    OVENS
    (Repealed)
    Applicability
    (Repealed)
    Control
    Requirements
    (Repealed)
    Testing
    (Repealed)
    Monitoring
    (Repealed)
    Recordkeeping and Reporting
    (Repealed)
    Compliance Date
    (Repealed)
    Certification (Repealed)
    SUBPART GG:
    MARINE TERMINALS
    Applicability
    Control
    Requirements
    Compliance Certification
    Leaks
    Testing and Monitoring
    Recordkeeping
    and
    Reporting
    SUBPART
    HI-i:
    MOTOR VEHICLE REFINISHING
    Emission Limitations
    Alternative Control Requirements
    Equipment Specifications
    Surface Preparation Materials
    Work
    Practices
    Testing
    Monitoring and Recordkeeping for Control Devices
    General
    Recordkeeping
    and
    Reporting
    Compliance
    Date
    Registration
    Applicability
    of
    Subpart
    BB
    (Renumbered)
    Emissions
    Limitation
    at
    Polystyrene
    Plants
    (Renumbered)
    Compliance
    Date
    (Repealed)
    Compliance
    Plan
    (Repealed)
    Special Requirements for Compliance Plan (Repealed)
    Emissions Testing
    (Renumbered)
    45
    SUBPART
    PP:
    MISCELLANEOUS FABRICATED
    PRODUCT
    MANUFACTURING
    PROCESSES
    Section
    219.920
    Applicability
    219.923
    Permit
    Conditions
    219.926
    Control
    Requirements
    219.927
    Compliance
    Schedule
    219.928
    Testing
    SUBPART
    QQ:
    MISCELLANEOUS
    FORMULATION
    MANUFACTURING
    PROCESSES
    Section
    219.940
    Applicability
    219.943
    Permit Conditions
    219.946
    Control Requirements
    219.947
    Compliance Schedule
    219.948
    Testing
    SUBPART RR:
    MISCELLANEOUS ORGANIC
    CHEMICAL MANUFACTURING PROCESSES
    Section
    219.960
    Applicability
    219.963
    Permit
    Conditions
    219.966
    Control
    Requirements
    219.967
    Compliance Schedule
    219.968
    Testing
    SUBPART
    TT:
    OTHER EMISSION UNITS
    Section
    219.980
    Applicability
    219.983
    Permit
    Conditions
    219.986
    Control Requirements
    219.987
    Compliance
    Schedule
    219.988
    Testing
    SUBPART UU:
    RECORDKEEPING AND REPORTING
    Section
    219.990
    Exempt Emission Units
    219.991
    Subject Emission Units
    Section
    219.Appendix
    A:
    List
    of
    Chemicals
    Defining Synthetic
    Organic Chemical and Polymer
    Manufacturing
    Section
    219.Appendix
    B:
    VON
    Measurement
    Techniques
    for
    Capture
    Efficiency
    46
    Section
    219.Appendix
    C:
    Reference
    Methods
    And
    Procedures
    Section
    219.Appendix
    D:
    Coefficients
    for
    the Total Resource
    Effectiveness Index
    (TRE)
    Equation
    Section
    219.Appendix
    E:
    List
    of
    Affected
    Marine
    Terminals
    Section
    2l9.Appendix
    G:
    TRE
    Index
    Measurements
    for
    SOCMI
    Reactors and Distillation Units
    Section 2l9.Appendix H:
    Baseline VOM Content Limitations for
    Subpart
    F,
    Section
    219.212
    Cross-Line
    Averaging
    AUTHORITY:
    Implementing Section 10 and authorized by Section
    28.5 of the Environmental Protection Act 415
    ILCS 5/10 and
    28.5.
    SOURCE:
    Adopted at R91-8 at 15 Ill. Reg.
    12491, effective August
    16,
    1991; amended in R91—24 at 16
    Ill. Reg.
    13597, effective
    August
    24,
    1992;
    amended
    in
    R91—30
    at 16
    Ill. Reg.
    13883,
    effective August 24,
    1992; emergency amendment in R93-12 at 17
    Ill. Reg.
    8295,
    effective May 24,
    1993,
    for a maximum of 150
    days,
    amended in R93-9 at 17 Ill.
    Reg.
    16918, effective September
    27,
    1993
    and
    October
    21,
    1993; amended in R93-28 at 18 Ill.
    Reg.
    4242,
    effective March
    3,
    1994;
    amended in R94-12 at 18
    Ill. Reg.
    14987, effective September 21,
    1994;
    amended in R94-15 at
    18 Ill.
    Reg.
    16415, effective October 25,
    1994; amended in R94-16 at 18
    Ill. Reg.
    16980, effective November 15,
    1994; emergency amendment
    in R95-lO at 19
    Ill.
    Reg.
    3059,
    effective February 28,
    1995,
    for
    a
    maximum
    of
    150
    days;
    amended
    in
    R94-21,
    R94-31
    and
    R94-32
    at
    19
    Ill. Reg.
    6958,
    effective May 9,
    1995;
    amended in R94—33 at 19
    Ill.
    Reg.
    7385,
    effective May 22,
    1995;
    amended in R96-2 at
    _____
    Ill. Reg.
    __________,
    effective
    ________________________;
    amended
    in
    R96
    at
    _____
    Ill.
    Reg.
    _________,
    effective
    _______
    BOARD NOTE:
    This Part implements the Illinois Environmental
    Protection Act as of July
    1,
    1994.
    SUBPART A:
    GENERAL PROVISIONS
    Section
    219.108
    Exemptions,
    Variations,
    and
    Alternative
    Means
    of Control or Compliance Determinations
    Notwithstanding the provisions of any other Sections of this
    PartT
    ~j.
    a~ny
    exemptions, variations or alternatives to the
    control requirements, emission limitations,
    or test
    methods
    set
    forth
    in
    this
    Part shall be effective only
    when
    approved
    by
    the
    Agency
    and
    approved
    by
    the
    USEPA
    as a SIP revision.
    47
    Any equivalent alternative control plans, equivalent
    device,
    or
    other
    equivalent
    practice
    authorized
    by
    the
    Agency
    where
    this
    Part
    provides
    for
    such
    alternative
    or
    equivalent
    practice
    or
    egutvalent
    variations
    or
    alterations
    to
    test
    methods
    a~~roved by
    the
    Agency
    shall
    be
    effective
    only
    when
    included
    in
    a
    federally
    enforceable
    permit
    or
    approved
    as
    a
    SIP
    revision.
    (Source:
    Amended
    at
    _____
    Ill.
    Reg.
    _________,
    effective
    —
    Section
    219.110
    Vapor
    Pressure
    of
    Organic
    Material
    or
    Solvent
    a)
    If
    the
    organic
    material
    or
    solvent
    consists
    of
    only
    a
    single compound, the vapor pressure shall be determined
    by
    ASTM
    Method
    D2879-86
    (incorporated
    by
    reference
    in
    Section 219.112 of this Part)
    or the vapor pressure may
    be obtained from
    a publication such as:
    Boublik,
    T.,
    V. Fried and E. Hala,
    “The Vapor Pressure of Pure
    Substances,”
    Elsevier
    Scientific
    Publishing
    Co.,
    New
    York
    (1973); Perry’s Chemical Engineer’s Handbook,
    McGraw-Hill
    Book
    Company
    (1984);
    CRC
    Handbook
    of
    Chemistry and Physics, Chemical Rubber Publishing
    Company
    (1986-87);
    and
    Lange’s
    Handbook
    of
    Chemistry,
    John
    A.
    Dean,
    editor,
    McGraw-Hill
    Book
    Company
    (1985).
    b)
    If
    the
    organic
    material
    or
    solvent
    is
    in
    a
    mixture
    made
    up
    of
    both
    organic
    material
    compounds
    and
    compounds
    which are not organic material, the vapor pressure
    shall be determined by the following equation:
    n
    B
    P1x,
    Porn
    i=1
    n
    i=1
    where:
    Porn
    =
    Total vapor pressure of the portion of
    the
    mixture
    which
    is
    composed
    of
    organic
    material;
    n
    =
    Number of organic material components
    in
    the
    mixture;
    i
    =
    Subscript
    denoting
    an
    individual
    component;
    48
    P1
    =
    Vapor
    pressure
    of
    an
    organic material
    component determined in accordance with
    subsection
    (a)
    of
    this
    Section;
    Xl
    =
    Mole
    fraction
    of
    the organic material
    component
    of
    the
    total
    organic
    mixture.
    c)
    If
    the
    organic
    material
    or
    solvent
    is
    in
    a
    mixture
    made
    up
    of
    only
    organic
    material
    compounds,
    the
    vapor
    pressure
    shall
    be
    determined
    by
    ASTM
    Method
    D2879-86
    (incorporated
    by
    reference
    in
    Section
    219.112
    of
    this
    Part)
    or by the above equation.
    (Source:
    Amended at
    ____
    Ill.
    Reg.
    _________,
    effective
    —
    Section 219.111
    Vapor Pressure of Volatile Organic Material
    a)
    If
    the
    VON
    consists
    of
    only
    a
    single
    compound,
    the
    vapor pressure shall be determined by ASTM Method
    D2879-86
    (incorporated by reference in Section 219.112
    of this Part)
    or the vapor pressure may be obtained
    from
    a publication such as:
    Boublik, T.,
    V.
    Fried and
    E.
    Hala,
    “The Vapor Pressure of Pure Substances,”
    Elsevier Scientific Publishing Co., New York (1973);
    Perry’s Chemical Engineer’s Handbook,
    McGraw-Hill Book
    Company
    (1984);
    CRC
    Handbook
    of Chemistry and Physics,
    Chemical Rubber Publishing Company
    (1986-87); and
    Lange’s Handbook of Chemistry, John A. Dean,
    editor,
    McGraw-Hill Book Company
    (1985).
    b)
    If the VOM is in a mixture made up of both VOM
    compounds and compounds which are not VON,
    the vapor
    pressure shall be determined by the following equation:
    n
    B
    P1X,
    Pvorn
    i=1
    n
    B
    X,
    i=1
    where:
    ~vom
    =
    Total
    vapor
    pressure
    of
    the portion of the
    mixture which is composed of VON;
    n
    =
    Number of VON components in the mixture;
    1
    =
    Subscript
    denoting
    an
    individual component;
    49
    P1
    =
    Vapor
    pressure
    of
    a
    VON
    component
    determined
    in
    accordance
    with
    subsection
    (a)
    of
    this
    Section;
    Xl
    =
    Mole fraction of the VOM component of the
    total organic mixture.
    c)
    If
    the
    VOM
    is
    in
    a
    mixture
    made
    up
    of
    only
    VOM
    compounds,
    the
    vapor
    pressure
    shall
    be
    determined
    by
    ASTM
    Method
    D2879-86
    (incorporated
    by
    reference
    in
    Section 219.112 of this Part)
    or by the above equation.
    (Source:
    Amended at
    Ill. Reg.
    _________,
    effective
    SUBPART F:
    COATING OPERATIONS
    Section 219.208
    Exemptions From Emission Limitations
    a)
    Exemptions for all coating categories except wood
    furniture coating.
    The limitations of this Subpart
    shall not apply to coating lines within a source, that
    otherwise would be subject to the same subsection of
    Section
    219.204
    (because
    they
    belong
    to
    the
    same
    coating
    category,
    e.g.
    can
    coating),
    provided that
    combined actual emissions of VOM from all lines at the
    source subject to that subsection never exceed 6.8
    kg/day
    (15 lbs/day) before the application
    of
    capture
    systems and control devices.
    (For example, can coating
    lines within a source would not be subject to the
    limitations of Section 219.204(b)
    of this Subpart if
    the combined actual emissions of VOM from the can
    coating lines never exceed 6.8 kg/day
    (15 lbs/day)
    before the application of capture systems and control
    devices.)
    Volatile
    organic
    material emissions from
    heavy off-highway vehicle products coating lines must
    be combined with VON emissions from miscellaneous metal
    parts and products coating lines to determine
    applicability.
    Any owner or operator of a coating
    source shall comply with the applicable coating
    analysis
    test
    methods
    and
    procedures specified in
    Section 219.105(a)
    of this Part and the recordkeeping
    and reporting requirements specified
    in Section
    219.211(a)
    of
    this
    Subpart
    if
    total VON emissions from
    the subject coating lines are always less than or equal
    to 6.8 kg/day
    (15 lbs/day) before the
    application
    of
    capture systems and control devices and,
    therefore,
    are
    not subject to the limitations of Section 219.204 of
    this
    Subpart.
    Once
    a
    category
    of
    coating lines at a
    50
    source
    is
    subject
    to
    the
    limitations
    in Section 219.204
    of
    this
    Subpart
    the
    coating
    lines
    are
    always
    subject
    to
    the
    limitations
    in
    Section
    219.204
    of
    this
    Subpart.
    b)
    Applicability
    for
    wood
    furniture
    coating
    1)
    The limitations of this Subpart shall apply to a
    source’s wood furniture coating lines if the
    source
    contains
    process
    emission
    units,
    not
    regulated
    by
    Subparts
    B,
    E,
    F
    (excluding
    Section
    219.204(1)
    of
    this
    Subpart),
    H
    (excluding
    Section
    219.405
    of
    this
    Part),
    Q,
    R,
    S, T (excluding
    Section 219.486 of this Part),
    V,
    X,
    Y,
    Z or BB of
    this
    Part,
    which
    as
    a
    group
    both:
    A)
    Have
    a
    maximum
    theoretical
    emissions of 91 Mg
    (100
    tons)
    or
    more
    per calendar year of VOM
    if no air pollution control equipment were
    used,
    and
    B)
    Are not limited to less than
    91
    Mg
    (100
    tons)
    of
    VOM
    per calendar year if no air pollution
    control equipment were used,
    through
    production or capacity limitations contained
    in a federally enforceable permit or SIP
    revision.
    2)
    The limitations of this Subpart shall apply to a
    source’s
    wood
    furniture coating lines,
    on and
    after
    March
    15,
    1996,
    if
    the
    source
    contains
    process
    emission
    units,
    which
    as
    a
    group
    have
    a
    potential
    to
    emit
    22.7
    Mg
    (25
    tons)
    or
    more
    of
    VOM
    per
    calendar
    year
    and
    have
    not
    limited
    emissions
    to
    less
    than
    22.7
    Mg
    (25
    tons)
    of
    VOM per calendar
    year through production or capacity limitations
    contained in a federally enforceable operating
    permit
    or
    SIP revision, and which:
    A)
    Are not regulated by Subparts B,
    E, F
    (excluding Section
    219.204(1)
    of
    this
    Subpart),
    H,
    Q,
    R,
    5,
    T
    (excluding
    Section
    219.486
    of
    this
    Part),
    V,
    X,
    1,
    Z
    or
    BB
    of
    this Part; and
    B)
    Are
    not
    included
    in
    any
    of
    the
    following
    categories:
    synthetic organic chemical
    manufacturing industry
    (SOCMI)
    distillation,
    SOCMI reactors, plastic parts coating
    (business machines), plastic parts coating
    (other), offset lithography,
    industrial
    51
    wastewater, autobody refinishing,
    SOCMI batch
    processing,
    volatile
    organic
    liquid
    storage
    tanks and clean-up solvents operations.
    3)
    If a source ceases to fulfill the criteria of
    subsection
    (b)
    (1)
    or
    (b)
    (2)
    of
    this
    Section,
    the
    limitations
    of
    Section
    219.204(1)
    of
    this
    Subpart
    shall continue to apply to any wood furniture
    coating
    line
    which
    was
    ever
    subject
    to
    the
    limitations
    of
    Section
    219.204(1)
    of
    this
    Subpart.
    4)
    For
    the
    purposes
    of
    subsection
    (b)
    of
    this
    Section,
    an
    emission
    unit shall be considered to
    be regulated by a Subpart if
    it
    is
    subject
    to
    the
    limitations of that Subpart.
    An emission unit is
    not
    considered
    regulated
    by
    a
    Subpart
    if
    it
    is
    not
    subject
    to
    the limits of that Subpart,
    e.g., the
    emission unit
    is covered by an exemption in the
    Subpart or the applicability criteria of the
    Subpart are not met.
    5)
    Any
    owner
    or
    operator
    of
    a
    wood furniture coating
    line to which the limitations of this Subpart are
    not applicable due to the criteria in subsection
    (b)
    of
    this
    Section
    shall,
    upon
    request
    by
    the
    Agency
    or
    the
    USEPA,
    submit records to the Agency
    and the USEPA within 30 calendar days from the
    date
    of
    the request that document that the coating
    line
    is
    exempt
    from
    the
    limitations
    of
    this
    Subpart.
    c)
    On
    and
    after
    March
    15,
    1996,
    the limitations of this
    Subpart
    shall
    not apply to touch-up and repair coatings
    used by a coating source described by subsections
    219.204(b),
    (d),
    (f),
    (g),
    (i),
    (j),
    (m)
    and
    (n)
    of
    this Subpart; provided that the source-wide volume of
    such
    coatings
    used
    does
    not
    exceed
    0.95
    1
    (1
    quart)
    per
    eight-hour
    period
    or
    exceed
    209
    1/yr
    (55
    gal/yr)
    for
    any rolling twelve month period.
    Recordkeeping and
    reporting for touch-up and repair coatings shall be
    consistent
    with
    Section
    219.211(b)
    (4)
    of
    this
    Subpart
    subsection
    (d)
    of
    this
    Section.
    d)
    On and after March
    15,
    1996,
    the owner
    or
    operator
    of
    a
    coating
    line
    or
    a
    group
    of coating lines using touch—up
    and repair coatings that are exempted from the
    limitations of Section 219.204(b),
    (d),
    (f),
    (g),
    (i),
    (j),
    (m) and
    (n)
    of
    this Subpart because of the
    provisions of Section 219.208(c)
    of this Subpart
    shall:
    52
    1)
    Collect and record the name,
    identification
    number,
    and
    volume
    used
    of
    each
    touch—up
    and
    repair coating,
    as applied on each coating me,
    per
    eight-hour
    period
    and
    per
    month;
    2)
    Perform
    calculations
    on
    a
    daily
    basis,
    and
    maintain
    at
    the
    source
    records
    of
    such
    calculations of the combined volume of touch—up
    and
    repair
    coatings
    used
    source—wide
    for
    each
    eight-hour
    period;
    3)
    Perform
    calculations
    on
    a
    monthly
    basis, and
    maintain at the source records of such
    calculations of the combined volume of touch—up
    and repair coatings used source—wide for the month
    and
    the
    rolling
    twelve
    month
    period;
    4)
    Prepare and maintain at the source an annual
    summary of the information required to be compiled
    pursuant
    to
    subsections
    (a)
    (4)
    (A)
    and
    (a)
    (4)
    (B)
    (d) (1) and
    (d) (2)
    of this Section on or before
    January 31 of the following year;
    5)
    Maintain at the source for a minimum period of
    three years all records reuqired to be kept under
    this subsection and make such records available to
    the Agency upon request;
    6)
    Notify the Agency
    in writing if
    the
    use
    of
    touch-
    up
    and repair coatings at the source ever exceeds
    a
    volume
    of
    0.95
    1
    (1 quart) per eight-hour period
    or exceeds 209 1/yr
    (55 gal/yr)
    for any rolling
    twelve month period within 30 days after any such
    exceedance.
    Such
    notification
    shall
    include
    a
    copy
    of
    any
    records
    of
    such
    exceedance;
    and
    7)
    “Touch—up
    and
    repair
    coatings”
    means,
    for
    purposes
    of 35
    Ill.
    Adm.
    Code 219.208, any coating used to
    cover minor scratches and nicks that occur during
    manufacturing and assembly processes.
    (Source:
    Amended
    at
    _____
    Ill.
    Reg.
    _________,
    effective
    —
    SUBPART
    Q:
    SYNTHETIC ORGANIC CHEMICAL
    AND
    POLYMER MANUFACTURING PLANT
    Section 219.431
    Applicability
    53
    a)
    The
    provisions
    of
    Sections
    219.431
    through
    219.436
    of
    this
    Subpart
    shall
    apply
    to
    every
    owner
    or
    operator
    of
    any chemical manufacturing process unit that
    manufactures,
    as
    a
    primary
    product,
    one
    or
    more
    of
    the
    chemicals
    listed
    in
    Appendix
    A
    of
    this
    Part
    and
    that
    chemical
    manufacturing
    process
    unit
    causes
    or
    allows
    any
    reactor
    or
    distillation
    unit,
    either
    individually
    or
    in
    tandem,
    to
    discharge
    one
    or
    more
    process
    vent
    streams
    either
    directly
    to
    the
    atmosphere
    or
    to
    a
    recovery
    system.
    b)
    Notwithstanding subsection
    (a)
    of this Section, the
    control
    requirements
    set
    forth
    within
    Section
    219.432
    of
    this
    Subpart
    shall
    not
    apply
    to
    the
    following:
    1)
    Any
    process
    vent
    stream
    with
    a
    total
    resource
    effectiveness
    (TRE)
    index value greater than 1.0.
    However, such process vent stream remains subject
    to the performance testing requirements contained
    in Section 219.433 of this Subpart and the
    reporting
    and
    recordkeeping
    requirements
    contained
    in
    Section
    219.435
    of
    this
    Subpart;
    2)
    Any
    reactor
    or
    distillation
    unit
    that
    is
    designed
    and
    operated
    as
    a batch operation;
    3)
    Any reactor or distillation unit that is part of a
    polymer manufacturing operation;
    4)
    Any reactor or distillation unit that is part of
    the chemical manufacturing process unit with a
    total design capacity of less than
    1 gigagram
    (1,100 tons)
    per year for all chemicals produced,
    as
    a
    primary
    product,
    within
    that
    process
    unit.
    However,
    such
    operations remain subject to the
    reporting
    and
    recordkeeping
    requirements
    contained
    in Section 219.435(d)
    of this Subpart;
    5)
    Any vent stream with
    a flow rate less than 0.0085
    scm/mm
    or
    a
    total
    VON
    concentration
    of
    less
    than
    500
    ppnmv,
    less
    methane
    and
    ethane,
    as
    measured
    by
    Method
    18,
    or a concentration of VON of less than
    250
    ppmv
    as
    measured
    by
    Method
    25A.
    However,
    such
    operations remain subject to the performance
    testing requirement listed in Section 219.433
    of
    this
    Subpart,
    as
    well
    as
    the
    reporting
    and
    recordkeeping requirements contained
    in Section
    219.435
    of
    this
    Subpart;
    or
    6)
    Any reactor or distillation unit included within
    54
    an
    Early
    Reduction
    Program,
    as
    specified
    in
    40
    CFR
    63,
    and
    published
    in
    57
    Fed.
    Reg.
    61970
    (October
    22,
    1993)
    (December
    29.
    1992), evidenced by a
    timely
    enforceable commitment approved by USEPA.
    (Source:
    Amended
    at
    Ill.
    Reg.
    _________,
    effective
    Section
    219.434
    Monitoring
    Requirements
    a)
    The owner or operator of a source subject to the control
    requirements
    in
    Section
    219.432
    of this Subpart that uses an
    incinerator
    to
    comply
    with
    the
    VON
    emission
    limitation
    specified
    in
    Section
    219.432(a)
    (1)
    shall
    install,
    calibrate,
    maintain,
    and
    operate, according to manufacturer’s
    specifications,
    a
    temperature
    monitoring
    device
    equipped
    with a continuous recorder and having an accuracy of ±1
    percent of the temperature measured expressed
    in degress
    Celsius,
    or ±0.5°C,whichever is greater.
    1)
    Where
    an
    incinerator
    other
    than
    a
    catalytic
    incinerator
    is
    used,
    a
    temperature
    monitoring
    device
    shall
    be
    installed
    in
    the
    firebox.
    2)
    Where
    a
    catalytic incinerator is used,
    temperature
    monitoring devices shall be installed in the gas stream
    immediately before and after the catalyst bed.
    b)
    The owner or operator of a source that uses a flare to
    comply with Section 219.432(a) (2)
    of this Subpart shall
    install, calibrate, maintain and operate, according to
    manufacturer’s specifications,
    a heat—sensing device,
    such
    as an ultraviolet beam sensor or thermocouple,
    at the pilot
    light
    to
    indicate
    continuous presence of a flame.
    c)
    The
    owner
    or
    operator
    of
    a
    source
    that
    uses
    a
    boiler
    or
    process
    heater
    with
    a
    design
    heat
    input
    capacity
    less
    than
    44 megawatts to comply with Section 219.432 (a) (1)
    of this
    Subpart shall install, calibrate, maintain and operate,
    according to the manufacturer’s specifications,
    a
    temperature
    monitoring
    device
    in
    the
    firebox.
    The
    monitoring
    device
    shall
    be equipped with a continuous
    recorder with an accuracy of ±1percent of the temperature
    being
    measured
    expressed
    in
    degrees Celsius or ±0.5°C,
    whichever
    is
    greater.
    Any
    boiler
    or process heater in which
    all
    vent
    streams
    are
    introduced
    with
    primary
    fuel
    is
    exempt
    from
    this
    requirement.
    d)
    The owner or operator of a process vent with a TRE index
    value of 4.0 or less that uses one or more product recovery
    55
    devices
    shall
    install
    either
    an
    organic
    monitoring
    device
    equipped
    with
    a
    continuous
    recorder
    or
    the
    monitoring
    equipment
    specified
    in
    subsections
    (d)
    (1),
    (d) (2),
    (d)
    (3)
    or
    (d) (4) of this Section, depending on the type of recovery
    device used.
    All monitoring equipment shall be installed,
    calibrated
    and
    maintained
    according
    to
    the
    manufacturer’s
    specifications.
    1)
    Where
    an
    absorber
    is
    the
    final
    recovery
    device
    in
    the
    recovery
    system,
    a
    scrubbing
    liquid
    temperature
    monitoring
    device
    and
    a
    specific
    gravity
    monitoring
    device,
    each
    equipped
    with
    a
    continuous
    recorder,
    shall
    be
    used.
    2)
    Where
    a
    condenser
    is
    the final recovery device
    in the
    recovery system,
    a condenser exit
    (product side)
    temperature
    monitoring
    device
    equipped
    with
    a
    continuous
    recorder
    and having an accuracy of ±1
    percent
    of
    the
    temperature
    being
    monitored
    expressed
    in
    degrees Celsius or ±0.5°C,whichever is greater.
    3)
    Where
    a
    carbon
    adsorber is the final recovery device in
    the
    recovery
    system,
    an
    integrating regeneration stream
    steam flow monitoring device having an accuracy of ±10
    percent, capable of recording the total regeneration
    stream
    steam
    mass
    flow
    for
    each
    regeneration
    cycle; and
    a
    carbon
    bed
    temperature
    monitoring
    device
    having
    an
    accuracy
    of
    ±1percent of the temperature being
    monitored expressed in degrees Celsius of ±0.5°C,
    capable of recording the carbon bed temperature after
    each regeneration and within 15 minutes of completing
    any cooling cycle.
    4)
    Where
    a
    scrubber
    is
    used
    with
    an
    incinerator,
    boiler,
    or,
    in
    the
    case
    of
    halogenated
    vent
    streams,
    a
    process
    heater,
    the following monitoring equipment
    is required
    for
    the
    scrubber:
    A)
    A pH monitoring device equipped with a continuous
    recorder
    to monitor the pH
    of
    the scrubber
    effluent;
    and
    B)
    Flow meters equipped with a continuous recorder at
    the
    scrubber
    influent
    for
    liquid
    flow
    and
    the
    scrubber inlet for gas stream flow.
    e)
    The
    owner
    or
    operator
    of
    a
    process
    vent
    using
    a
    vent
    system
    that
    contains
    bypass
    lines
    capable of diverting a vent
    stream
    away
    from
    the
    control
    device
    associated
    with
    a
    process
    vent
    shall
    comply
    with
    either
    (e)
    (1)
    or
    (e)
    (2)
    of
    56
    this
    Section.
    Equipment
    needed
    for
    safety
    purposes,
    including,
    but
    not
    limited
    to,
    pressure
    relief
    devices,
    are
    not
    subject
    to
    this
    subsection.
    1)
    The
    owner
    or
    operator
    shall
    install,
    calibrate,
    maintain
    and
    operate
    a
    flow
    indicator
    that
    provides
    a
    record
    of
    vent
    stream
    flow
    at
    least
    once
    every
    15
    minutes.
    The
    flow
    indicator
    shall
    be
    installed
    at
    the
    entrance to any bypass line that could divert the vent
    stream
    away
    from
    the
    control
    device
    to
    the
    atmosphere.
    2)
    The
    owner
    or
    operator
    shall
    secure
    the
    bypass
    line
    valve
    in
    the
    closed
    position
    with
    a
    car—seal
    or
    a
    lock-and-key type configuration.
    A visual inspection
    of
    the
    seal
    or
    closure
    mechanism
    shall
    be performed at
    least once every month to ensure that the valve is
    maintained
    in
    the
    closed
    position
    and
    the
    vent
    stream
    is not diverted through the bypass line.
    f)
    The owner or operator of a process vent may monitor by an
    equivalent alternative means or parameters other than those
    listed in subsections
    (a) through
    (d) of this Section.
    Any
    equivalent alternative shall be approved by the Agency and
    USEPA,
    and contained in the source’s operating permit as
    federally enforceable permit conditions.
    (Source:
    Amended
    at
    Ill.
    Reg.
    __________,
    effective
    Section 219.435
    Recordkeeping and Reporting Requirements
    a)
    Every owner or operator of a reactor or distillation unit
    with a TRE index value of 4.0 or less shall keep
    records,
    for a minimum of
    3 years, of the following parameters
    measured
    during
    a
    performance
    test
    or TRE determination
    required
    under
    Section
    219.433
    of
    this Subpart, and required
    to
    be
    monitored under Section 219.434
    of this Subpart.
    1)
    Every
    owner
    or
    operator
    of
    a
    source
    that
    seeks
    to
    demonstrate
    compliance
    with
    Section
    219.432(a)
    (1)
    of
    this
    Subpart
    through
    the
    use
    of
    either
    a
    thermal
    or
    catalytic incinerator shall maintain records of the
    following:
    A)
    The
    average
    firebox
    temperature
    of
    the
    incinerator
    (or
    the
    average
    temperature
    upstream
    and
    downstream
    of
    the
    catalyst
    bed
    for
    a
    catalytic
    incinerator),
    measured
    at
    least
    every
    15
    minutes
    and
    averaged
    over
    the
    same
    time
    period
    of
    the
    performance testing; and
    57
    B)
    The
    percent
    reduction
    of
    VON
    determined
    as
    specified
    in
    Section
    219.433(c)
    of
    this
    Subpart
    achieved
    by
    the
    incinerator,
    or
    the
    concentration
    of VOM (ppmv,
    by compound)
    determined as specified
    in Section 219.433(c)
    of this Subpart at the
    outlet
    of
    the
    control
    device,
    on
    a
    dry
    basis,
    corrected
    to
    3
    percent
    oxygen.
    2)
    Every owner or operator of a source that seeks to
    demonstrate compliance with Section 219.432(a) (1)
    of
    this Subpart through the use of a boiler or process
    heater
    shall
    maintain
    the
    records described below.
    Any
    boiler
    or
    process
    heater
    in
    which
    all
    vent
    streams
    are
    introduced with primary fuel are exempt from these
    requirements.
    A)
    A
    description
    of
    the
    location
    at
    which
    the
    vent
    stream
    is
    introduced
    into the boiler or process
    heater;
    and
    B)
    The
    average
    combustion
    temperature
    of
    the
    boiler
    or process heater with a design heat input
    capacity
    of
    less
    than
    44
    megawatt
    measured
    at
    least
    every
    15
    minutes
    and
    averaged
    over
    the
    same
    time
    period
    of
    the
    performance
    testing.
    3)
    Every owner or operator of a source that seeks to
    demonstrate compliance with Section 219.432(a) (2)
    of
    this Subpart through use of a smokeless flare, or flare
    design
    (i.e.,
    steam—assisted,
    air—assisted,
    or
    nonassisted), shall maintain records of all visible
    emission
    readings,
    heat
    content
    determinations,
    flow
    rate
    measurements,
    and
    exit
    velocity
    determinations
    made
    during
    the
    performance
    test,
    continuous records of
    the flare pilot flame monitoring, and records of all
    periods of operations during which the pilot flame is
    absent.
    4)
    Every
    owner
    or
    operator
    of
    a
    source
    that
    seeks
    to
    demonstrate
    compliance with Section 219.432(b)
    of
    this
    Subpart shall maintain records of the following:
    A)
    Where
    an
    absorber is the final recovery device
    in
    the recovery
    system,
    the
    exit
    specific
    gravity
    (or
    alternative parameter which
    is a measure of the
    degree of absorbing liquid saturation,
    if approved
    by the Agency and USEPA, and average exit
    temperature
    of
    the
    absorbing
    liquid
    measured
    at
    least every 15 minutes and averaged over the same
    time
    period
    as
    the
    performance
    testing
    (both
    58
    measured
    while
    the
    vent
    stream
    is
    normally routed
    and
    constituted);
    B)
    Where
    a
    condenser
    is
    the
    final recovery device in
    the
    recovery
    system,
    the
    average
    exit
    (product
    side)
    temperature
    measured
    at
    least
    every
    15
    minutes
    and
    averaged
    over
    the
    same
    time
    period
    as
    the
    performance
    testing
    while
    the
    vent
    stream
    is
    normally
    routed
    and
    constituted;
    C)
    Where
    a
    carbon
    absorber
    is
    the
    final
    recovery
    device
    in
    the
    recovery
    system,
    the
    total
    stream
    steam
    mass
    or
    volumetric
    flow
    measured
    at
    least
    every
    15
    minutes
    and
    averaged
    over
    the
    same
    time
    period
    as
    the performance testing
    (full carbon bed
    cycle),
    the
    temperature
    of
    the
    carbon
    bed
    after
    regeneration
    (and within
    15 minutes of completion
    of
    any
    cooling
    cycle(s)),
    and
    duration
    of
    the
    carbon bed steaming cycle
    (all measured while the
    vent
    stream
    is
    normally
    routed
    and
    constituted);
    D)
    As
    an
    alternative
    to
    subsection
    (a)
    (4) (A),
    (a)(4)(B)
    or
    (a)(4)(C)
    of
    this
    Section, the
    concentration level
    or reading indicated by the
    organic
    monitoring
    device
    at
    the outlet of the
    absorber,
    condenser,
    or
    carbon
    absorber,
    measured
    at
    least
    every
    15
    minutes and averaged over the
    same time period as the performance testing
    (measured while the vent stream is normally routed
    and
    constituted);
    or
    E)
    All measurements and calculations performed to
    determine
    the
    flow rate, VOM concentration,
    heating
    value,
    and
    TRE index value of the vent
    stream.
    b)
    Every
    owner
    or
    operator
    of
    a reactor or distillation unit
    with a TRE index value of less than 4.0 shall be subject to
    the exceedance reporting requirements of the draft Enhanced
    Monitoring Guidelines as published at 58 Fed.
    Reg.
    54648
    (October
    22,
    1993).
    c)
    Every
    owner
    or
    operator
    of
    a
    source seeking to comply with
    Section 219.432(b)
    of this Subpart shall maintain records of
    the
    following:
    1)
    Any changes
    in production capacity,
    feedstock type,
    catalyst type,
    or of any replacement,
    removal,
    or
    addition
    of
    recovery
    equipment
    or
    reactors
    and
    distillation
    units;
    and
    59
    2)
    Any
    recalculation
    of
    the
    flow
    rate,
    VON
    concentration,
    or
    TRE
    index
    value
    calculated
    according
    to
    Section
    (c)
    of
    Appendix
    G
    of
    this
    Part.
    d)
    Every
    owner
    or
    operator
    of
    a
    source
    claiming
    a
    design
    capacity
    of
    less
    than
    1
    gigagram
    (1,100
    tons)
    per
    year,
    as
    contained
    in
    Section
    219.431(b)
    of
    this
    Subpart, shall
    maintain records of the design capacity or any changes in
    equipment or operations that may affect the design capacity.
    e)
    Every owner or
    operator
    of
    a
    source
    claiming
    a
    vent
    stream
    flow
    rate
    or
    vent
    stream
    concentration
    exemption
    level,
    as
    contained
    in
    Section
    219.431(b)
    (5)
    of
    this
    Subpart,
    shall
    maintain records to indicate that the stream flow rate is
    less than 0.0085 scm/mm
    or the vent stream concentration is
    less
    than
    500
    ppmv.
    (Source:
    Amended
    at
    _____
    Ill.
    Reg.
    _________,
    effective
    _______
    SUBPART
    FF:
    BAKERY OVENS
    (Repealed)
    Section
    219.720
    Applicability
    (Repealed)
    a)
    The
    provisions
    of
    this
    Subpart
    shall apply to every
    owner
    or
    operator
    of
    a
    source
    which
    operates
    a
    bakery
    oven,
    as
    defined
    at
    35
    Ill.
    Adm.
    Code
    211.680,
    unless
    the
    source
    bakes
    products
    only
    for
    on-site
    human
    ~
    ~
    1
    ~
    b)
    Notwithstanding
    source
    ‘-
    (a)of
    this
    Section,
    a
    requirements of this Subpart
    potential to emit 22.7 Hg
    (25
    only
    if
    tons)
    the source
    or more of
    has
    VON
    the
    per
    year,
    i
    n
    t~hr’
    ~rfvrr.-1+o
    ,
    frnm
    1
    1
    r~m
    i
    i
    ?~n
    ui t~
    t~hr~
    excluding:
    1)
    Emission units regulated by Subparts B,
    E,
    F,
    H,
    Q,
    B,
    6,
    T
    (excluding
    Section 219.486
    of this
    Part),
    V,
    X,
    Y,
    Z
    or
    BB
    of
    this
    Part;
    and
    Emission units that arc included in any of the
    2)
    following
    categories~
    synthetic
    organic
    chemical
    manufacturing
    industry
    (BOCHI)
    distillation, SOCHI
    reactors,
    wood furniture coating, plastic parts
    coating
    (business
    machines),
    plastic
    parts
    coating
    (other), offset lithography,
    industrial
    wastewatcr,
    autobody refinishing,
    SOCMI batch
    processing,
    volatile
    organic
    liquid
    storage
    tanks
    60
    a)
    Every
    owner
    or
    operator
    of
    a
    source which has limited
    its
    potential
    to
    omit
    below
    22.7
    Mg
    (25
    tons)
    of
    VON
    per
    year,
    as
    specified
    in
    subsection
    (b)
    of
    this
    through
    federally
    cnrorceauic
    ía
    is
    not
    required
    to
    comply
    with
    this
    Sul
    burrnarr z~ndthe
    .ificat..~.,..~
    219.730(d)
    of
    this
    Subpart.
    .-,‘—‘-—‘—-.--
    i_i.!
    (Source: Repealed at
    _____
    Ill.
    Reg.
    _________,
    effective
    Section 219.722
    Control Requirements
    (Repealed)
    a)
    Every
    owner
    or
    operator
    of
    a
    source
    ~
    control rcquiremcnto of this Subpart shall comply with
    the
    requirements
    of
    subsection
    (a)
    (1)
    or
    (a)
    (2)
    of
    this
    Section
    for
    each
    bakery
    oven
    with
    a
    rated
    heat
    input
    capacity
    of
    at
    least
    2
    mmbtu/hr
    or
    at
    least
    586
    kW:
    1)
    Operate
    emissions
    capture
    and
    control
    equipment
    which achieves an ovorall reduction in
    uncontrolled
    VON
    emissions
    of
    at
    least
    81
    percent
    from
    each
    such
    bakery
    oven;
    or
    2)
    Provide
    an
    equivalent
    alternative
    control
    plan
    for
    such
    bakery
    ovens
    at
    the
    source
    which
    has
    been
    approved
    by
    the
    Agency
    and
    USEPA
    through
    federally
    enforceable
    permit
    conditions
    or
    as
    a
    SIP
    revision.
    b)
    An
    owner
    or
    operator
    of
    a
    source
    subject
    to
    the
    control
    requirements
    of this Subpart may elect to exempt from
    the
    control
    requirements
    in
    subsections
    (a)
    (1)
    or
    (a)
    (2)
    and
    (a)
    (1)
    or
    (c)
    (2)
    of
    this
    Section
    any
    bakery
    oven
    with
    actual
    VON
    emissions
    less
    than
    or
    equal
    to
    15
    TPY; provided that the total actual VON emissions from
    all such exempt bakery ovens never exceed 25 TPY.
    Notwithstanding the requir
    this Section, until
    d)
    Every
    owner
    or
    operator
    of
    a
    bakery
    oven
    which
    is
    exempt
    from
    the
    control
    requirements
    of
    this
    Subpart
    because
    of
    the
    criteria
    in
    subsection
    (b)
    of
    this
    Section
    remains
    subject
    to
    the
    rccordkccping
    and
    r~cporting
    requirements
    of
    Section
    219.728(b’
    —-
    _a,
    only,
    a
    61
    cleat
    to
    comply
    with
    the
    control
    requirements
    in
    subsection
    (c)
    (1)
    or
    (a)
    (2)
    of
    this
    Section,
    rather
    than
    the
    control
    requirements
    in
    subsection
    (a)
    (1)
    or
    (a)
    (2)
    of
    this
    Section,
    if
    all
    emission
    units
    at
    the
    source,
    in the aggregate,
    excluding emission units
    regulated
    by
    Subparts
    B,
    E,
    F,
    H
    (excluding
    Section
    219.405
    of
    this
    Subpart),
    Q,
    B,
    C,
    T (excluding Section
    219.406
    of
    this
    Subpart),
    V,
    X,
    Y,
    Z
    or
    BB
    of
    this
    Subpart, have maximum theoretical emissions of less
    than
    90.7
    Hg
    (100
    tons)
    of
    VON
    per
    year
    or
    arc
    limited
    to less than 90.7 Mg
    (100 tons)
    of VON emissions per
    calendar
    year
    in
    the
    absence
    of
    air
    pollution
    control
    equipment
    through
    production
    or
    capacity
    limitations
    contained
    in
    federally
    enforceable
    permit
    conditions
    or
    in
    a
    SIP
    revisioni-
    1)
    Operate emissions capture and control equipment
    which
    achieves
    an
    overall
    reduction
    in
    uncontrolled
    VON
    emissions
    of
    at
    least
    60
    pcraen~
    from
    each
    bakery
    oven
    with
    a
    rated
    heat
    input
    capacity of at least
    2 minbtu/hr or at least 586
    KW; or
    2)
    Provide
    an
    equivalent
    alternatii~r~
    ~-
    -p~..
    such baiery ovens at the source which has been
    approved by the Agency and USEPA through federally
    ~nfnrc~s’~,h1
    t’
    n’rm’i
    i-
    r!cunti if--i r~n~i
    t~
    v-~
    ~t
    revision.
    d)
    Any
    bakery
    subject
    to
    the
    ~
    any time
    shal-1
    f
    this
    Subpart
    at
    all
    (Source:
    Repealed
    at
    _____
    Ill.
    Reg.
    __________,
    effective
    —
    Section 219.726
    Testing
    (Repealed)
    a)
    Upon request by the Agency, the owner or operator of a
    bakery oven shall,
    at its own expense, conduct such
    tests
    in
    accordance
    with
    the
    applicable
    test
    methods
    and procedures specified in Section 219.105(f)
    of this
    Part
    to
    demonstrate
    compliance
    with
    the
    contr-e-1
    requirements
    of
    this
    Subpart
    and
    shall:
    4-)-
    --Notify the
    tests;
    and
    .-~y~ziuy
    30 days prior to conducting such
    ii~
    that
    be
    -.--
    -~
    ~i1_
    Cubpa~
    -~~-
    62
    2)
    Submit
    all
    teot
    results
    to
    the
    Agency
    within
    30
    days
    of
    conducting
    such
    tests.
    Not..
    a..
    t-~
    tat
    ......
    S
    s~
    ~
    L. .I.SflI
    b~pa~aa
    a
    a afla
    ~..
    t1S.
    UCEPA
    pursuant
    to
    the
    Clean
    Air
    Act
    (CAA)
    to
    require
    testing,
    or
    shall
    affect
    the
    authority
    of
    UCEPA
    under
    gr~c+inn
    114
    nf
    t~hf~
    (~AA
    (42 TT~C~. 7414.
    ,
    i,jii
    (Source:
    Repealed
    at
    Ill.
    Reg.
    _________,
    effective
    Section 219.727
    Monitoring
    (Repealed)
    a)
    Every
    owner
    or
    operator
    of
    a
    bakery
    oven
    subject
    to
    the
    control
    requirements
    of
    this
    Subpart
    shall
    install
    and
    operate at all times a device to continuously monitor
    the
    following
    parameters
    for
    each
    type
    of
    control
    device
    as
    follows:
    1)
    For
    catalytic
    oxidizers,
    the inlet and outlet
    temperatures
    of the oxidizer;
    2)
    For
    regenerative
    oxidizers,
    the
    temperature
    in
    the
    combustion
    chamber;
    or
    3)
    For thermal incinerators, the temperature
    in the
    combustion
    chamber.
    The
    owner
    b....
    operator
    may
    ...~...
    .a.
    ~
    a.
    ~..
    an
    ...
    a.
    ~— ~_
    ~
    ~.5
    V
    method
    or
    monitor
    other
    parameters
    if
    approved
    by
    the
    Agency and USEPA through federally enforceable permit
    (Source:
    Repealed
    at
    )
    Ill.
    Reg.
    __________,
    effective
    Section
    219.728
    Recordkeeping
    and
    Reporting
    (Repealed)
    a)
    Every
    owner
    or
    operator
    of
    a
    bakery
    oven
    shall
    maintain
    the
    following
    rccords
    for
    the
    most
    recent
    consecutive
    3
    year period for all bakery ovens subject to the control
    requirements
    of
    this
    Subpart.
    Such
    records
    shall
    be
    made
    available
    to
    the
    Agency
    immediately
    upon
    request.
    1)
    Parameters for control devices as monitored
    pursuant to Section 219.727
    of this Subpart
    63
    2)
    Hrs/day
    of
    operation
    of
    each
    bakery
    oven
    3)
    Factors necessary to calculate VON emissions for
    all
    bakery
    ovens
    including,
    but
    not
    limited
    to,
    type
    of
    dough
    used
    for
    each
    yeast-leavened
    baked
    product,
    initial
    yeast
    percentage
    for
    each
    product,
    total
    fermentation
    time
    for
    each
    product,
    any
    additional
    percentage
    of
    yeast
    added,
    and
    the
    fermentation
    time
    of
    any
    additional
    yeast;
    4)
    Calculated
    daily
    VON
    emissions
    of
    each
    bakery
    oven
    expressed
    as
    lbs/day;
    es
    m_A_
    I
    —I
    product
    produced
    by
    lbs/day.
    ach bakery
    b)
    Every
    owner
    or
    operator of a bakery oven which
    is
    exempt from the control requirements of this Subpart
    because of
    the
    criteria
    in
    Section
    219.720(b)
    of
    this
    Subpart
    shall
    maintain
    records
    necessary
    to
    demonstrate
    that
    its
    potential
    to
    emit
    is
    less
    than
    22.7
    Mg
    (25
    tons)
    of VON per year,
    as
    specified
    in
    Section
    219.720(b).
    Such records shall be maintained for the
    mn’~it~
    rs~-?tnf-
    n~ir’r~wt-i’u’,-
    3
    year
    period
    -ch~!!
    -~-
    ~
    ~
    ~
    a)
    Every
    owner
    or
    operator
    of
    a
    bakery
    oven
    which
    is
    exempt from the control requirements
    of this Subpart
    because of the criteria specified in Section 219.722(b)
    of
    this
    Subpart
    shall:
    1)
    Maintain records necessary to demonstrate that the
    actual
    VOM
    emissions
    from
    exempt
    bakery
    ovens
    are
    less than or equal to 15 TPY for each bakery oven
    and
    less
    than
    or
    equal
    to
    25
    TPY
    from
    all
    exempt
    bakery ovens combined.
    Such records shall be
    maintained
    for
    the
    most
    recent
    consecutive
    3
    year
    made
    available
    to
    the
    Agency
    period
    and
    shall
    be
    immediately upon request; and
    ...t-~
    ~
    ~-~--
    15 TPY or the actual VON emissions from a
    combination of exempt bakery ovens ever exceed 25
    TPY,
    within 30 days after the exocedance occurs.
    F~uc~h
    nnt~irn
    ~h.-~11
    ini-~1iuiic~~
    copy
    nf
    ~i11 rc~rnrd~inf
    1
    —
    -.‘~—--~-,
    4
    -.
    ~.4
    -
    d)
    Every
    owner
    or
    operator
    of
    a
    bakery
    oven
    which
    is
    64
    controlling
    emissions
    as
    provided
    in
    Section
    219.722(c-)-
    of
    this
    Cubpart
    until
    March
    15,
    1998,
    shall
    maintain
    records
    necessary
    to
    demonstrate
    that
    its
    maximum
    theoretical
    emissions
    as
    specified
    in
    Section
    219.722(c)
    are less than 90.7 Hg
    (100 tons)
    of VON
    r~r
    year.
    Cuch
    records
    shall
    be
    maintancd
    for
    the
    most
    recent
    consecutive
    3
    year
    period
    and
    shall
    be
    made
    available
    to
    the
    Agency
    immcdiatlcy
    upon
    request.
    (Source:
    Repealed
    at
    Ill.
    Reg.
    _________,
    effective
    Section 219.729
    Compliance Date
    (Repealed)
    On
    and
    after
    March
    15,
    1996,
    upon
    initial
    startup
    or
    upon
    modification,
    every
    owner
    or
    operator
    of
    a
    source
    subject
    to
    this
    Subpart
    shall
    comply
    with
    the
    requirements
    of
    this
    Subpart.
    (Source:
    Repealed
    at
    _____
    Ill.
    Reg.
    __________,
    effective
    Section
    219.730
    Certification (Repealed)
    a)
    Every
    owner
    or
    operator
    of
    a
    source
    subject
    to
    the
    control requirements of this Subpart shall certify
    compliance
    with
    this
    Subpart
    on
    or
    before
    a
    date
    consistent with Section 219.729 of this Subpart.
    b)
    If
    an
    owner
    or
    operator
    of
    a
    bakery
    oven
    subject
    to
    the
    control
    requirements
    of
    this
    Subpart
    changes
    the
    method
    of
    compliance,
    the
    owner
    or
    operator
    shall
    certify
    compliance
    with
    the
    requirements
    of
    this
    Subpart
    for
    the alternative method upon changing the method of
    compliance.
    c)
    All
    certifications
    of
    compliance
    with
    this
    Subpart
    shall include the results of all tests and
    the
    calculations
    performed
    to
    demonstrate
    that
    each
    oven
    at
    the source
    is in compliance with,
    or
    is exempt
    from,
    the
    control
    requirements
    of
    this
    Subpart.
    The
    ccrtification
    shall
    include
    the
    followingt
    1)
    The name and identification number of each oven
    and
    any
    associated
    capture
    and
    control
    device
    2)
    The maximum rated heat input of each ovcni-ET?1 w?144 155 m?480 155 l?S?BT?
    65
    3)
    A classification of each oven as either a “bakery
    oven” as defined in 35
    Ill. Admin. Code 211.680 or
    an
    oven
    used
    exclusively
    to
    bake
    non-yeast—
    leavened
    products,
    4)
    The
    capture
    and
    control
    efficiency
    of
    each
    bakery
    oven
    control
    device;
    Test
    reports,
    ~
    and
    other
    data
    necessary
    to
    demonstrate
    that
    the
    capture
    and
    control
    efficiency
    of
    each
    bakery
    oven
    control
    device
    achieves
    an
    overall
    reduction
    in
    uncontrolled
    VOM
    emissions
    of
    at
    least
    Cl
    PC
    en4
    6)
    The
    date
    each
    bakery
    oven
    control
    device
    was
    installed
    and
    operating.
    d)
    On
    or
    before
    March
    15,
    1996,
    or upon initial startup,
    evcry
    owner
    or
    operator
    of
    a
    bakery
    oven
    which
    is
    exempt
    from
    the
    control
    requirements
    of
    this
    Subpart
    because
    of
    the
    criteria
    in
    Section
    219.720(b)
    of
    this
    Subpart shall certify that its potential to emit
    is
    less
    than
    22.7
    Hg
    (25
    tons)
    of
    VON
    per
    year,
    a-s
    specified
    in
    Section
    219.720(b).
    e)
    On
    or
    before
    March
    15,
    1996,
    or
    upon
    initial
    startup,
    every
    owner
    or
    operator
    of
    a
    bakery
    oven
    which
    is
    exempt
    from
    the
    control
    requirements
    of
    this
    Subpart
    because of the criteria specified in Section 219.722(b)
    of
    this
    Subpart
    shall
    certify
    that
    actual
    VON
    emissions
    from
    any
    individual
    exempt
    bakery
    oven
    never
    exceed
    15
    TPY and that VON emissions from all exempt bakery
    ovens,
    in
    the
    aggregate,
    never
    exceed
    25
    TPY.
    On
    or
    before
    March
    15,
    1996,
    or
    upon
    initial
    startup
    if
    f)
    prior
    to
    March
    15,
    1998,
    every
    owner
    or
    operator
    of
    a
    bakery oven which is controlling emissions as provided
    by
    Section
    219.722(c)
    of
    this
    Subpart,
    shall
    certify
    that its maximum theoretical emissions as specified in
    Section
    219.722(c)
    arc
    less
    than
    90.7
    Hg
    (100
    tons)
    of
    VON per year.
    (Source: Repealed at
    _____
    Ill.
    Reg.
    _________,
    effective
    —
    Section
    219.Appendix
    G
    TRE
    Index
    Measurements
    for
    SOCMI
    Reactors and Distillation Units
    66
    For
    purposes
    of
    Subpart
    Q,
    Sections
    219.431
    through
    219.435,
    the
    following
    apply:
    a)
    The
    following
    test
    methods
    shall
    be
    used
    to
    determine
    compliance
    with
    the
    total
    resource
    effectiveness
    (“TRE”)
    index
    value:
    1)
    Method
    1
    or
    1A,
    incorporated
    by
    reference
    at
    Section
    219.112
    of
    this
    Part,
    as
    appropriate,
    for
    selection
    of
    the
    sampling
    site.
    A)
    The sampling site for the vent stream molar
    composition determination and flow rate prescribed
    in subsections
    (a) (2) and
    (a) (3) of this Appendix
    shall be, except for the situations outlined in
    subsection
    (a) (1) (B), after the final recovery
    device,
    if
    a
    recovery
    system
    is
    present,
    prior
    to
    the inlet of any control device, and prior to any
    post—reactor or post-distillation unit
    introduction of halogenated compounds into the
    vent stream.
    No traverse site selection method
    is
    needed for vents smaller than 10 cm in diameter.
    B)
    If any gas stream other than the reactor or
    distillation
    unit
    vent
    stream
    is normally
    conducted through the final recovery device:
    i)
    The sampling site for vent stream flow rate
    and molar composition shall be prior to the
    final recovery device and prior to the point
    at which any nonreactor or nondistillation
    unit
    vent
    stream
    or
    stream
    from
    a
    nonaffected
    reactor or distillation unit is introduced.
    Method 18 incorporated by reference at
    Section 219.112 of this Part,
    shall be used
    to measure organic compound concentrations at
    this
    site.
    ii)
    The efficiency of the final recovery device
    is
    determined
    by
    measuring
    the
    organic
    compound concentrations using Method
    18,
    incorporated by reference at Section 219.112
    of this Part,
    at the inlet to the final
    recovery device after the introduction of all
    vent streams and at the outlet of the final
    recovery device.
    iii)
    The efficiency of the final recovery device
    determined
    according
    to
    subsection
    (a)
    (1)
    (B) (ii)
    of
    this
    Appendix
    shall
    be
    67
    applied
    to
    the
    organic
    compound
    concentrations
    measured
    according
    to
    subsection
    (a)
    (1)
    (B) (i)
    of
    this
    Appendix
    to
    determine
    the
    concentrations
    of
    organic
    compounds from
    the
    final
    recovery
    device
    attributable to the reactor or distillation
    unit vent stream.
    The resulting organic
    compound
    concentrations
    are
    then
    used
    to
    perform the calculations outlined in
    subsection
    (a)
    (4)
    of
    this
    Appendix.
    2)
    The
    molar
    composition
    of
    the
    vent
    stream
    shall
    be
    determined as follows:
    A)
    Method 18, incorporated by reference at Section
    219.112 of this Part,
    to measure the concentration
    of
    organic
    compounds
    including
    those
    containing
    halogens;
    B)
    ASTN D1946-77,
    incorporated by reference at
    Section 219.112 of this Part,
    to measure the
    concentration of carbon monoxide and hydrogen; and
    C)
    Method
    4,
    incorporated by reference at Section
    219.112 of this Part, to measure the content of
    water
    vapor.
    3)
    The volumetric flow rate shall be determined using
    Method
    2,
    2A,
    2C, or 2D, incorporated by reference at
    Section
    219.112
    of
    this
    Part,
    as appropriate.
    4)
    The emission rate of VON (minus methane and ethane)
    (EVOM)
    in the vent stream shall be
    calculated using
    the
    following formula:
    n
    EVOM
    =
    K2
    ~ C~M~
    Q~
    j=l
    where:
    EVOM
    =
    Emission rate of VON (minus methane and
    ethane)
    in the sample, kg/hr.
    K2
    =
    Constant,
    2.494 x l0~ (l/ppmv)(g-
    mole/scm)
    (kg/g) (min/hr), where standard
    temperature for (g—mole/scm)
    is 20°C.
    =
    Concentration
    of
    compound
    j,
    on a dry
    basis,
    in ppmv as measured by Method
    18,
    incorporated by reference at Section
    68
    219.112 of this Part,
    as indicated in
    Section
    219.433(c)
    (3)
    of
    this
    Part.
    =
    Molecular
    weight
    of
    sample
    j,
    g/g-mole.
    Q~
    =
    Vent
    stream
    flow
    rate
    (scm)
    at
    a
    temperature
    of
    20°C.
    5)
    The
    total
    vent
    stream
    concentration
    (by
    volume)
    of
    compounds containing halogens (ppmv, by compound)
    shall
    be summed from the individual concentrations of
    compounds
    containing
    halogens which were measured by
    Method
    18,
    incorporated
    by
    reference
    at
    Section
    219.112
    of this Part.
    6)
    The net heating value of the vent stream shall be
    calculated using the following:
    n
    HT
    =
    K1 ~ C~H1 (l-B~0)
    J=1
    where:
    HT
    =
    Net heating value of the sample
    (MJ/scm),
    where
    the
    net enthaply per mole of vent
    stream
    is
    based
    on
    combustion
    of
    25°C and
    760
    mmHG, but the standard temperature for
    determining the volume corresponding to one
    mole is ~-S-~ 2OQC as in the definition of
    Q3
    (vent stream flow rate).
    K1
    =
    Constant,
    1.740
    x
    l0~
    (ppmv)’
    (g-mole/scm),
    (MJ/KCal),
    where
    standard
    temperature
    for
    (g—mole/scm)
    is 20°C.
    B~5
    =
    Water vapor content of the vent stream,
    proportion by volume; except that
    if the vent
    stream passes through a final stream jet and
    is
    not
    condensed,
    it
    shall
    be
    assumed
    that
    ~
    =
    0.023
    in
    order
    to correct to 2.3
    percent moisture.
    C1
    =
    Concentration on a dry basis of compound
    j
    in
    ppinv,
    as measured for all organic compounds
    by Method 18, incorporated by reference at
    Section 219.112 of this Part, and measured
    for hydrogen and carbon monoxide by using
    ASTM D1946-77,
    incorporated by reference at
    Section 219.112 of this Part.
    69
    H~
    =
    Net
    heat
    of
    combustion
    of
    compound
    j,
    kCal/g-
    mole, based on combustion at 25°Cand 760
    mmHG.
    The
    heats
    of
    combustion
    of
    vent
    stream
    components
    shall
    be
    determined
    using
    ASTN
    D2382-83,
    incorporated
    by
    reference
    at
    Section
    219.112
    of
    this
    Part,
    if
    published
    values
    are
    not
    available
    or
    cannot
    be
    calculated.
    b)
    1)
    The
    TRE
    index
    value
    of
    the
    vent
    shall
    be
    calculated
    using
    the
    following:
    TRE
    =
    1~a
    +
    b
    (Q5)
    +
    c
    (HT)
    +
    d
    (EVOM)
    EVOM
    where:
    TRE
    =
    TRE
    index
    value.
    EVOM
    Hourly emission rate of VOM (kg/hr)
    as
    calculated in subsection
    (a) (4)
    of this
    Appendix.
    Q3
    =
    Vent stream flow rate scm/mm
    at a
    standard temperature of 20°C.
    =
    Vent stream net heating value
    (MJ/scm),
    as calculated
    in subsection
    (a) (6)
    of
    this
    Appendix.
    EVOM
    Hourly emission rate of VOM
    (minus methane
    and
    ethane),
    (kg/hr)
    as
    calculated
    in
    subsection
    (a) (4)
    of this Appendix.
    a,b,
    =
    Value of coefficients presented below
    c,d
    are:
    Control Device
    Value of Coefficients
    Type of Stream
    Basis
    a
    b
    c
    d
    Nonhalogenated
    Flare
    2.129
    0.183
    —0.005
    0.359
    Thermal incinerator
    3.075
    0.021
    —0.037
    0.018
    zero
    (0) Percent heat
    Recovery
    Thermal
    incinerator
    3.803
    0.032
    -0.042
    0.007
    70 Percent heat
    Recovery
    70
    Halogenated
    Thermal incinerator
    5.470
    0.181
    -0.040
    0.004
    and
    scrubber
    2)
    Every
    owner
    or
    operator
    of
    a
    vent
    stream
    shall
    use
    the
    applicable
    coefficients
    identif
    led
    for
    values
    a,
    b,
    c
    and
    d
    in
    subsection
    (b) (1)
    of
    this
    Appendix
    to
    calculate
    the
    TRE
    index
    value
    based
    on a flare,
    a
    thermal
    incinerator
    with
    zero
    percent
    heat
    recovery,
    and a thermal incinerator with 70 percent heat
    recovery,
    and
    shall
    select
    the
    lowest
    TRE
    index
    value.
    3)
    Every
    owner
    or
    operator
    of
    a
    reactor
    or
    distillation
    unit
    with
    a
    halogenated
    vent
    stream,
    determined
    as
    any
    stream with a total concentration of halogen atoms
    contained in organic compounds of 200 ppmv or greater,
    shall
    use
    the
    applicable
    coefficients identified for
    values
    a,
    b,
    c
    and
    d
    in
    subsection
    (b)
    (1)
    of
    this
    Appendix
    to
    calculate
    the
    TRE index value based on a
    thermal incinerator and scrubber.
    c)
    Every owner or operator of a source seeking to comply with
    Section
    219.432(b)
    of
    this
    Part
    shall
    recalculate
    the
    flow
    rate and VON concentration for each affected vent stream
    whenever process changes are made.
    Examples of process
    changes include, but are not limited to, changes
    in
    production
    capacity,
    feedstock type,
    or catalyst type,
    or
    whenever
    there
    is
    replacement,
    removal,
    or
    addition
    of
    recovery
    equipment.
    The
    flow
    rate
    and
    VON
    concentration
    shall
    be
    recalculated
    based
    on
    test
    data,
    or
    on
    best
    engineering
    estimates
    of
    the
    effects
    of
    the
    change
    to
    the
    recovery system.
    d)
    Whenever
    a
    process
    change,
    as
    defined
    in Section 219.435(c)
    of this Subpart, yields a TRE index value of 1.0 or
    less,
    the owner or operator shall notify and submit a report to
    the Agency according to the requirements specified in
    Section 219.435(c)
    of this Subpart, within 180 calendar days
    after
    the
    process
    change
    and
    shall
    conduct
    a
    performance
    test according to the methods and procedures required by
    Section
    219.433
    of
    this
    Part.
    e)
    For the purpose of demonstrating that a process vent stream
    has a VOM concentration below 500 ppmv, the following shall
    be
    used:
    1)
    The
    sampling
    site shall be selected as specified in
    Section
    219.433(c)
    (1)
    of
    this
    Part.
    2)
    Method
    18
    or
    Method
    25A
    of
    40
    CFR
    Part
    60,
    Appendix
    A,
    incorporated
    by
    reference
    at
    Section 219.112
    of this
    71
    Part,
    shall
    be
    used
    to
    measure
    concentration;
    alternatively, any other method or data that has been
    validated
    according
    to
    the
    protocol
    in
    Method
    301
    of
    40
    CFR Part 63, Appendix A,
    incorporated by reference at
    Section
    219.112
    of
    this
    Part,
    may
    be
    used.
    3)
    Where Method 18
    is used, the following procedures shall
    be
    used
    to
    calculate
    ppmv
    concentration:
    1)
    The minimum sampling time for each run shall be
    1
    hour in which either an integrated sample or four
    grab samples shall be taken.
    If grab sampling is
    used, then the samples shall be taken at
    approximately
    equal
    intervals
    in
    time,
    such
    as
    15
    minute
    intervals
    during
    the
    run.
    ii)
    The concentration of VON shall be calculated using
    Method 18 according to Section 219.433(c) (4)
    of
    this
    Part.
    4)
    Where Method 25A is used, the following procedures
    shall be used to calculate ppinv VOM concentration:
    A)
    Method 25A shall be used only if a single VOM is
    greater than 50 percent of total VOM, by volume,
    in the process vent stream.
    B)
    The vent stream composition may be determined by
    either process knowledge,
    test data collected
    using an appropriate Reference Method or a method
    of
    data
    collection
    validated
    according
    to
    the
    protocol
    in
    Method
    301
    of
    40
    CFR
    Part
    63,
    Appendix
    A,
    incorporated by reference at Section 219.112
    of this Part.
    Examples of information that
    constitute
    process
    knowledge include calculations
    based
    on
    material balances, process stoichiometry,
    or previous test results provided the results are
    still relevant to the current process vent stream
    conditions.
    C)
    The
    VON
    used
    as
    the
    calibration
    gas
    for
    Method
    25A
    shall
    be
    the
    single
    VOM
    present
    at
    greater
    than
    50
    percent of the total VOM by volume.
    D)
    The span value for Method 25A shall
    be 50 ppmv.
    E)
    Use
    of
    Method
    25A
    is
    acceptable
    if
    the
    response
    from the high-level calibration gas
    is at least 20
    times the standard deviation of the response from
    the
    zero
    calibration
    gas
    when
    the
    instrument
    is
    72
    zeroed on the most sensitive scale.
    F)
    The concentration of VON shall be corrected to
    3
    percent
    oxygen
    using
    the
    procedures
    and
    equation
    in Section 219.433(c) (3) of this Part.
    5)
    The
    owner
    or
    operator
    shall
    demonstrate
    that
    the
    concentration
    of
    VOM,
    including
    methane
    and
    ethane,
    measured
    by
    Method
    25A
    is
    below
    250
    ppmv
    to
    qualify
    for
    the
    low
    concentration
    exclusion
    in
    Section
    219.431
    of
    this Part.
    (Source:
    Amended
    at
    _____
    Ill.
    Reg.
    _________,
    effective
    —
    IT
    IS
    SO
    ORDERED.
    I,
    Dorothy
    M.
    Gunn,
    Clerk
    of
    the
    Illinois
    Pollution
    Control
    Board,
    hereby certify that the above opinion and order was
    adopted on the
    ~9~-’
    day of
    ~
    ,
    1995,
    by
    a
    vote
    of
    7—b.
    I
    ~
    ~
    Dorothy M./”~unn,Clerk
    Illinois /~‘Ø”llutionControl Board

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