ILLINOIS POLLUTION CONTROL BOARD
    July 10,
    1980
    MOBIL OIL CORPORATION,
    Petitioner,
    v.
    )
    PCB 80—53
    ILLINOIS ENVIRONMENTAL
    )
    PROTECTION AGENCY,
    )
    Respondent.
    OPINION AND ORDER OF THE BOARD
    (by
    I.
    Goodman):
    On April
    15,
    1980 the Petitioner,
    Mobil Oil Corporation,
    filed
    a Revised Petition for Variance Extension.
    Petitioner
    seeks an extension of the variance from Rule 408(a) of Chapter
    3:
    Water Pollution (hereinafter, Chapter
    3) granted to it in PCB
    78—277.
    The Petitioner has waived a hearing in this matter.
    The
    Illinois Environmental Protection Agency (Agency) recommends that
    Petitioner be granted a variance from Rule 408(a) of Chapter
    3,
    as
    it pertains to cyanide,
    until December
    31,
    1981 subject to
    specified conditions.
    Pursuant to the Board*s Procedural Rule
    402(a), the Petitioner has requested that the record from the
    prior variance proceeding
    (PCB 78—277) be incorporated into the
    record.
    The request is granted.
    Petitioner owns and operates
    a conventional petroleum fuel
    refinery in Channahon
    Township, Will County, Illinois.
    The
    facility utilizes water from the Des Plaines River for boiler
    feed, cooling tower makeup,
    and as once—through, non—contact
    cooling water.
    Process water from the refinery is subjected to
    pre—treatment and final
    treatment before being discharged into
    the Des Plaines River.
    The Board has granted Petitioner a variance from cyanide
    limitations on six previous occasions.
    The most recent variance,
    was granted on February 1,
    1979 and extended until July 1,
    1980.
    Petitioner in its February 25,
    1980 progress report stated that
    additional control measures had been installed and that monitors
    were in operation.
    The
    report also indicated that
    a test of
    ammonium polysulfide injection into the fluidic catalytic cracker
    (FCC) unit to evaluate the conversion of cyanides to biodegradable
    thiocyanates would be conducted.
    Petitioner is currently studying bio-nitrification to
    determine whether it contributes to cyanide excursions.
    The
    nitrification treatment facility appears to reduce the cyanide
    levels and then release cyanide in a slug load when nitrification

    —2—
    rates are high; therefore, Petitioner has concluded that
    fluctuations in the bio—system pH during nitrification may
    be
    one of the primary eontributing factors in the release of cyanide
    from the biomass.
    Furthermore,
    studies
    indicate that nitrate
    ions cause a positive interference with the total cyanide test.
    Petitioner is currently determining whether this phenomenon is
    causing its reported cyanide excursions.
    Despite effluent level excursions, cyanide concentrations in
    the
    river mixing zone have remained very low.
    Upstream and
    downstream
    monitoring reports indicate that the
    refinery is not
    adding significantly to cyanide levels
    in the Des
    Plaines River.
    The Board
    finds that an arbitrary
    and unreasonable hardship
    would be imposed upon the Petitioner
    if the variance extension
    were denied.
    The lack of available control technology for
    cyanide, the good faith efforts of the petitioner,
    and the
    absence of noticeable harm to the environment convince the Board
    that the petitioner should he granted a variance
    from Rule 408(a)
    of Chapter
    3 until December 31,
    1981 subject to conditions
    included in the Order herein.
    The Will County Health Department responded to the variance
    petition with a letter pointing out the existence of recreational
    uses of the Illinois River downstream from Mobil and requesting
    that the Board consider the hazards of cyanide with respect to
    other uses of the stream,
    The Board commends the interest taken
    by the Health Department on behalf of the citizens but,
    nevertheless,
    finds that the total discharge levels
    in this case
    are
    so small that any potential harm downstream is de minimus.
    This Opinion constitutes the findings of fact and
    conclusions of law in this matter.
    ORD
    ER
    It is the Order
    of
    the Illinois Pollution Control Board
    that:
    I.
    Petitioner,
    Mobil Oil Corporation, be granted a variance
    from Rule 408(a) of Chapter
    3 until December 31,
    1981,
    subject
    to the following conditions:
    a.
    The cyanide effluent discharge level shall
    not exceed
    a monthly average of 0.2 mg/i and a daily maximum of
    0.37
    mg/l,
    with the exception that Petitioner shall be allowed
    one excursion per month above the daily maximum which
    shall not exceed an absolute level of 1,5 mg/i.
    b.
    Petitioner shall continue to submit progress reports
    to the Agency in the same manner as required by previous
    variances for this facility.

    —3--
    2.
    This variance shall
    terminate if Petitioner demonstrates
    to the Board that,
    under the same facts as herein, positive
    interference during the testing procedure is the sole cause
    for cyanide readings to exceed the limitations
    in Rule 408(a)
    of Chapter 3.
    3.
    The Illinois Environmental Protection Agency is
    authorized to modify Petitioner’s NPDES permit to be
    consistent with the terms of this variance, including
    granting permission for the use of sulfamic acid in testing
    for cyanide
    levels.
    4.
    In the event that Petitioner discovers the cause or
    causes of its cyanide excursions,
    it shall immediately
    notify the Agency thereof, and within a reasonable time
    thereafter,
    submit to the Agency a program to achieve
    compliance with Rule 408(a) of Chapter
    3 as
    it pertains to
    cyanide.
    5.
    Within 45 days after the date of this Order, Petitioner
    shall execute and forward to the Illinois Environmental
    Protection Agency, Division of Water Pollution Control,
    Compliance Assurance Unit,
    2200 Churchill Road,
    Springfield,
    illinois 62706 a Certification of acceptance and agreement to
    be hound to all terms and conditions of the variance.
    This
    45—day period shall
    be held in abeyance for any period during
    which this matter
    is appealed.
    The certification shall be
    as
    follows:
    CERTIFICATION
    Mobil Oil Corporation hereby accepts and agrees to be bound by
    all terms and conditions of the order of the Pollution Control
    Board in PCB 80—53 dated
    ____________________
    Petitioner
    By
    ,
    Authorized Agent
    Title
    Date
    I, Christan L,
    Moffett,
    Clerk of the Illinois Pollution
    Control Board, hereby certify that th~above Opinion and Order
    wer~adopted on the
    Jb~”
    day of
    1980 by
    a vote
    of
    ..~-
    D

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