ILLINOIS POLLUTION CONTROL BOARD
    June 7, 2001
     
    IN THE MATTER OF:
     
    PROPOSED AMENDMENTS TO TIERED
    APPROACH TO CORRECTIVE ACTION
    OBJECTIVES (TACO): 35 ILL. ADM.
    CODE 742
     
      
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    )
    )
    )
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    R00-19(B)
    (Rulemaking – Land)
          
    Proposed Rule. Second Notice.
     
    OPINION AND ORDER OF THE BOARD (by E.Z. Kezelis, M. McFawn, N.J. Melas):
     
     
    On May 15, 2000, the Illinois Environmental Protection Agency (Agency) filed a
    proposal to amend 35 Ill. Adm. Code 742 of the Board’s land regulations, which are commonly
    referred to as the Tiered Approach to Corrective Action Objectives (TACO) rules. The TACO
    rules were originally adopted by the Board on June 5, 1997, in Tiered Approach to Corrective
    Action Objectives (TACO): 35 Ill. Adm. Code 742, R97-12(A). Part 742 contains procedures
    for developing remediation objectives based on risks to human health and the environment posed
    by environmental conditions at sites undergoing remediation in the Site Remediation Program,
    the Leaking Underground Storage Tank Program, and pursuant to Resource Conservation and
    Recovery Act (RCRA) Part B permits and closures.
     
    The Board accepted this matter for hearing on May 18, 2000. On July 27, 2000, the
    Board sent this matter to first notice without commenting on the merits of the proposal. By
    today’s action, the Board sends this proposal to second notice, pursuant to the Administrative
    Procedure Act (5 ILCS 100/1-1
    et seq
    . (1998)), for consideration by the Joint Committee on
    Administrative Rules.
     
    PROCEDURAL HISTORY
     
    Background
     
    On May 15, 2000, the Agency submitted proposed amendments to the TACO regulations.
    The Board’s adoption of these amendments is authorized by Sections 27 and 28 of the
    Environmental Protection Act (Act) (415 ILCS 5/27, 28 (1998)).
     
    The Board moved the Agency’s proposal to first notice on July 27, 2000. In doing so, the
    Board divided the proposal into two subdockets based upon subject matter. Subdocket A
    contained those amendments that the Board was required to adopt pursuant to Public Act 91-909,
    which was signed and became effective July 7, 2000. Among other things, the amendments in
    Subdocket A created a new institutional control, known as the Environmental Land Use Control
    or “ELUC.” Since Public Act 91-909 required the adoption of regulations implementing the
    ELUC by no later than January 6, 2001, the Board decided to create a separate subdocket that
    could be expedited if necessary. Those amendments contained in Subdocket A were adopted by

     
    2
    the Board on December 21, 2000. See Proposed Amendments to Tiered Approach to Corrective
    Action Objectives (TACO): 35 Ill. Adm. Code 742 (December 21, 2000), R00-19(A).
     
    In addition to adopting regulations pertaining to the ELUC, the Board also adopted
    amendments to 35 Ill. Adm. Code 742, Appendix A, Table G, in Subdocket A. Appendix A,
    Table G was originally part of Subdocket A, but in response to public comments seeking
    expedition of the new arsenic background standards contained therein, the Board incorporated
    the table into Subdocket A. The remainder of proposed amendments are all contained in
    Subdocket B, which is the subject of this second notice opinion.
      
    Subdocket (B)
     
    The Agency submitted these proposed amendments to address several aspects of TACO
    that, with the benefit of time and practical experience, it believed were in need of clarification
    and correction. Statement of Reasons at 2. The adoption by the Board of these amendments is
    authorized pursuant to Sections 27 and 28 of the Act (415 ILCS 5/27, 28 (1998)).
     
     
    When the Board sent this proposal to first notice, it created two subdockets based upon
    subject matter: Subdockets A and B. The amendments proposed in this Subdocket B include
    changes and updates to various provisions that the Agency and regulated community agree were
    in need of revision. In today’s action, the Board proceeds to second notice with the entire
    Subdocket B, but for two notable exceptions. The first exception involves Appendix A, Table G,
    which was incorporated into Subdocket A, and was adopted by the Board on December 21, 2000.
     
    The second exception deals with the proposed cleanup standards for methyl tertiary-butyl
    ether (MTBE), which are found in Appendix A, Table A; Appendix B, Table A; Appendix B,
    Table B; Appendix B, Table E; Appendix B, Table F; and Appendix C, Table E. In order to
    allow a concurrent examination of the MTBE issues raised in this and other currently pending
    rulemaking proposals, the Board will not be moving forward at this time with the proposed
    MTBE cleanup standards. Rather, the MTBE cleanup standards proposed herein will be
    addressed by the Board in a separate rulemaking subdocket which is opened today and identified
    as, Proposed Amendments to Tiered Approach to Corrective Action Objectives (TACO): 35 Ill.
    Adm. Code 742, R00-19(C).
     
    Development of the Proposal
     
     
    Three hearings were held in this matter during the first-notice period. The first hearing
    was held on August 25, 2000, in Chicago. The second hearing was held on September 11, 2000,
    in Springfield. The final hearing, held on September 21, 2000, in Chicago, was reserved for the
    purpose of receiving comments or questions regarding the Board’s request of the Department of
    Commerce and Community Affairs (DCCA) to conduct an economic impact study, and DCCA’s
    declining to perform one.
     
     
    At the first hearing in Chicago, the Agency presented testimony from a number of
    witnesses, including: (1) John Sherrill, with the Remedial Project Management Section of the
    Agency’s Bureau of Land, Division of Remediation Management; (2) Gary King, manager of the

     
    3
    Division of Remediation Management within the Agency’s Bureau of Land; (3) James Patrick
    O’Brien, Senior Public Service Administrator and Manager of the Office of Chemical Safety; (4)
    Lawrence W. Eastep, Manager of the Remedial Project Management Section, Bureau of Land;
    (5) Christopher Nickell, Project Manager with the Leaking Underground Storage Tank Section,
    Bureau of Land; (6) Connie Sullinger, Environmental Protection Specialist IV, Office of
    Chemical Safety; (7) Douglas Clay, Manager of the Leaking Underground Storage Tank Section,
    Bureau of Land; (8) Tracey Hurley, Environmental Toxicologist, Toxicity Assessment Unit,
    Office of Chemical Safety; and (9) Thomas Hornshaw, Senior Public Service Administrator and
    Manager of Toxicity Assessment Unit, Office of Chemical Safety. The content of these
    witnesses’ testimony will be examined in greater detail as the specific proposals are discussed.
     
     
    At the second hearing, the following persons presented testimony regarding the
    Subdocket B proposal: King, O’Brien, Eastep, Clay, and Richard Cobb, Manager of the
    Groundwater Section, Bureau of Water, of the Agency; Randle Schick, Assistant Chief Counsel
    for the Illinois Department of Transportation; and David Sykuta, Executive Director of the
    Illinois Petroleum Council.
     
     
    No one appeared at the third hearing in Chicago and no testimony was given.
     
     
    The following exhibits were submitted into the record at hearing.
    1
     
     
     
    Exhibit No.
      
      
    Exhibit Name
     
     
    Agency Ex. 1
      
      
    Group exhibit consisting of prefiled
     
      
      
      
      
    testimony of Agency witnesses
    2
     
     
     
    Agency Ex. 2
      
      
    “Basis for Proposing a Preventive
    Notice and Response Level for
    MTBE in 35 Ill. Adm. Code 620”
     
      
      
       
      
      
      
     
    In addition to the testimony and exhibits presented at hearing, the Board has also received
    public comments in this matter. The public comment period expired on October 23, 2000. The
    following public comments were received regarding Subdocket B:
     
     
    Public Comment No.
      
    Date
      
    Public Comment Name
     
     
    PC 1
      
      
      
    10/23/00
    Illinois Environmental Regulatory Group
    (IERG)
     
    1
    Only those witnesses, exhibits, and public comments relating to Subdocket B are identified
    here. All other witnesses, exhibits, and public comments were already addressed in the second
    notice opinion in Subdocket A. See Proposed Amendments to Tiered Approach to Corrective
    Action Objectives (TACO): 35 Ill. Adm. Code 742 (November 16, 2000), R00-19(A).
    2
    For purposes of this opinion and order, references to “Agency Ex. 1” will be to the prefiled
    testimony. For clarification, the references will specify the witness’ name, such as, “Agency Ex.
    1 (King)” or “Agency Ex. 1 (Sullinger).”

     
    4
     
    PC 2
      
      
      
    10/23/00
    Illinois Steel Group (ISG)
     
     
    PC 3
      
      
      
    10/24/00
    Mitroff Companies
     
     
    PC 4
      
      
      
    10/25/00
    Illinois Petroleum Council
     
     
    PC 5
      
      
      
    10/25/00
    Home Builders Association of Illinois
     
     
    PC 6
      
      
      
    10/25/00
    The Green Environmental Group, Ltd.
     
    PC 7
      
    10/25/00
    Home Builders Association of Greater
    Chicago
     
    PC 8
      
      
      
    10/27/00
    Village of Palatine
     
    PC 9
      
      
      
    10/23/00
    Illinois Environmental Protection Agency
    (Agency)
     
    DISCUSSION OF SUBDOCKET B SECOND NOTICE PROPOSAL
     
    There have been only a few minor changes to the rule from that proposed by the Board in
    its first-notice opinion and order. There have been no changes to the first notice language in
    following sections: 742.210, 742.220, 742.300, 742.305, 742.310, 742.315, 742.605, 742.700,
    742.715, 742.900, 742.925, 742.1005, 742.1015, 742.1020, and 742.1105. On August 11, 2000,
    the Agency filed an errata sheet in which changes to the first notice language were proposed.
    The changes proposed by the Agency in its errata sheet have all been incorporated into this
    second-notice order and will be discussed, where necessary, below. Some of the amendments
    proposed by the Agency merely clarify the meaning or impact of a certain section. Unless a
    specific point of clarification raised concerns, questions, or comments during the first notice
    period, the Board will not necessarily comment on it specifically in this opinion. Rather, the
    Board will rely on statements made by both Agency and industry representatives that suggest full
    support for and agreement with the clarifications proposed.
     
    The Board does note, however, that although no mention was made of it at hearing, an
    interesting change is being proposed to Section 742.710. Specifically, the proposed amendment
    would add mercury, a metal, to those substances that must be evaluated in determining a Tier 2
    soil remediation objective for the inhalation exposure route. This is noteworthy because
    although mercury is a metal, it can be inhaled.
     
    However, since the Board did not comment at all on the merits of this rulemaking
    proposal in its first notice opinion and order, we will now focus on the justification for
    noteworthy portions of the proposed amendments and any significant changes that have been
    made subsequent to first notice.
     
    Section 742.220 Determination of Soil Saturation Limit
     

     
    5
     
    The Agency proposed a change to the soil saturation limits as they relate to a Tier 3
    cleanup.
    3
    Currently, the TACO rules prohibit a person from taking full advantage of a Tier 3
    evaluation if the soil saturation limit is exceeded. Agency Ex. 1 (Sherrill) at 2. The proposed
    amendments strike all references to “Tier 3” in Section 742.220(a) and (b), so that an exceedence
    of a soil saturation limit does not preclude a person from developing a Tier 3 cleanup proposal.
    Id
    . Referring to previous testimony given, Sherrill concluded that a person should be able to,
    “propose a Tier 3 demonstration to show that a site does not pose a risk to human health and the
    environment.”
    Id
    .
     
     
    Sherrill explained that when a soil saturation limit is exceeded, that indicates the presence
    of free product. Agency Ex. 1 (Sherrill) at 3. The TACO equations used to determine
    remediation objectives under Tier 1 and Tier 2 are not meant to apply to free product.
    Id
    .
    However, since a Tier 3 evaluation is one that allows a person to develop remediation objectives
    using parameters other than those found in Tier 1 or Tier 2, an exceedence of the soil saturation
    limit should not necessarily preclude the development of a Tier 3 proposal.
    Id
    .
     
     
    No public comments were received on this proposed change. The Board finds merit in
    the reasoning offered by the Agency in support of the proposed change. The Board therefore
    adopts this proposal, and expects that it will provide some relief for those persons in the
    regulated community wishing to develop a Tier 3 proposal.
     
    Section 742.225 Demonstration of Compliance with Remediation Objectives
     
     
    The proposed change to Section 742.225 involved the addition of a new subsection (f),
    which clarifies that “soil sample concentrations determined by laboratory tests for the purposes
    of comparison to corrective action objectives should be normalized for moisture content by
    calculating and reporting the soil concentration of contaminants on a dry soil weight basis.”
    Agency Ex. 1 (O’Brien) at 2. The Agency supports this amendment because it will result in
    greater consistency and accuracy in sampling results.
    Id
    .
     
     
    Under the current scheme, results of soil samples taken from the same location may vary
    from day to day depending on the moisture content of the soil at the particular time the sample is
    collected. Agency Ex. 1 (O’Brien) at 2. At hearing, O’Brien testified that the variability
    between a dry weight sample and a saturated weight sample could be at least 30%. Tr. (8/25/00)
    at 95. Furthermore, in some instances, that variability factor may be enough to “tip the scales”
    between meeting a remediation objective or not. Tr. (8/25/00) at 96.
     
    3
    The TACO regulations provide for a three-tiered approach to cleanup objectives. Under a Tier
    1 analysis, an applicant compares levels of contaminants of concern at the remediation site to
    pre-determined remediation objectives. See Tiered Approach to Corrective Action Objectives
    (TACO): 35 Ill. Adm. Code 742 (June 5, 1997), R97-12(A). For a Tier 2 analysis, an applicant
    uses site-specific information and equations set forth in the rules to develop alternative
    remediation objectives for contaminants of concern.
    Id
    . Finally, a Tier 3 analysis provides
    greater flexibility by allowing an applicant to develop site-specific remediation objectives using
    alternative parameters not found in Tier 1 or Tier 2.
    Id
    .

     
    6
    According to O’Brien, the proposed dry weight measurement is consistent with the
    analytical methods directed by the United States Environmental Protection Agency (USEPA).
    Agency Ex. 1 (O’Brien) at 3. USEPA provided analytical methods in USEPA SW-846, which is
    incorporated in the TACO rules at Section 742.210.
    Id
    . O’Brien stated that, “it is, therefore,
    entirely consistent with the SW-846 procedures for the TACO rules to define circumstances for
    reporting analytical results on a dry weight basis.”
    Id
    . The Agency does not propose a specific
    manner in which the dry weight is to be achieved, but rather just that the dry weight of a sample
    be analyzed. Tr. (8/25/00) at 95.
     
     
    During the first hearing in Chicago, O’Brien was questioned in some detail regarding this
    proposed amendment. Additionally, the Illinois Steel Group (ISG), in public comment, urged
    the Board to reconsider adoption of this proposed amendment. The Board appreciates the
    questions and views expressed and recognizes their value in helping to develop a clear and
    complete record on this issue.
     
    Specifically, O’Brien was questioned about, among other things, the need for the
    proposed amendment; whether the American Society for Testing of Materials (ASTM) requires
    dry weight sampling; and the effective date of the amendment. In response, O’Brien testified
    that while he is not aware of any specific sites where the potential variations in sampling results
    have been a problem, he is aware of instances when the Agency has split a sample with a party
    and the Agency lab gets one result and the party’s lab gets another because one used dry weight
    and one used wet. Tr. (8/25/00) at 98. O’Brien also testified that he was not able to find any
    ASTM methodology that addresses the wet weight/dry weight issue in any detail.
    Id.
    at 101.
    Finally, O’Brien concluded that the dry weight sampling requirement would become effective
    upon the adoption of these proposed amendments.
    Id
    . For sites currently undergoing
    remediation, all samples collected after the effective date of these amendments would need to be
    collected and analyzed on a dry weight basis.
    Id
    . at 101-03.
     
    According to O’Brien, the additional resources necessary to report results on a dry weight
    basis are minimal. Agency Ex. 1 (O’Brien) at 4. Similarly, Eastep added that the Agency
    “informally surveyed a number of the consultants that [they] deal with, and most of them are
    reporting on a dry weight basis now.” Tr. (8/25/00) at 106.
     
    Based on the information in the record, the Board concludes that the clarification
    proposed by the Agency is necessary in order to ensure consistency in sampling procedures and
    in sampling results. Furthermore, since many of those involved in TACO-related remediations
    are already using the dry weight standard, the Board finds that this added requirement will not
    unduly prejudice the regulated community.
     
    Section 742.305 Contaminant Source and Free Product Determination
     
     
    The provisions of Section 742.305 involve requirements that must be met in order to
    exclude exposure routes from consideration as a source of contamination. A significant change
    to this Section is the addition of polychlorinated biphenyls (PCBs) as a contaminant of concern
    that must not be present in levels exceeding 50 parts per million (ppm) for an exposure route to
    be excluded. Agency Ex. 1 (Eastep) at 3. The Agency chose the 50 ppm threshold because it is

     
    7
    the threshold used under federal regulations (40 C.F.R. 761.3) to define PCB remediation waste.
    Agency Ex. 1 (Eastep) at 3.
     
     
    The Agency also proposed similar PCB-related changes to three other areas of the TACO
    rules: Section 742.900(f); Part 742, Appendix B, Table A; and Part 742, Appendix B, Table B.
    These proposed amendments make it clear that under a Tier 1 evaluation, a one ppm PCB limit
    has been set and that persons preparing a Tier 3 cleanup objective must comply with the federal
    PCB requirements found at 40 C.F.R. 761. Agency Ex. 1 (Eastep) at 4. In proposing these
    additional PCB-related changes, the Agency indicated that it is attempting to set remediation
    objectives for PCBs that satisfy the federal requirements.
    Id
    .
     
     
    The PCB parameters established by these proposed amendments appear to be consistent
    with federal regulations. The Board therefore includes these parameters in the TACO
    regulations.
     
    Section 742.1020 Highway Authority Agreements
     
     
    The changes proposed to this section are the result of discussions between the Agency
    and the Illinois Department of Transportation (IDOT). Highway Authority Agreements are used
    under the TACO rules as institutional controls. Agency Ex. 1 (King) at 5. The proposed
    changes include revisions to the required elements of a Highway Authority Agreement and the
    addition of a requirement that the Highway Authority Agreement be referenced in the chain of
    title for the remediation property.
     
     
    Randle Schick, Assistant Chief Counsel for IDOT, testified at the Springfield hearing.
    Schick testified that IDOT currently has 300 Highway Authority Agreements that are either
    approved or in the process of being approved. Tr. (9/11/00) at 82. Furthermore, Schick testified
    that IDOT supports the changes proposed in this rulemaking.
    Id
    .
     
     
    No public comments were received regarding these proposals. Since both the Agency
    and IDOT agree that these changes are necessary to ensure efficient operation of the Highway
    Authority Agreements, the Board accepts these proposed amendments.
     
    Part 742 Appendices
     
     
    There are a number of proposed changes to various segments of the tables contained in
    the appendices to Part 742. Rather than go through them item-by-item, we will attempt to
    summarize the various changes being proposed and the reasons for the changes.
     
    Arsenic Remediation Objectives
      
     
    Previously, in R00-19(A), the Board adopted a revised background level for arsenic in
    Appendix A, Table G. See Proposed Amendments to Tiered Approach to Corrective Action
    Objectives (TACO): 35 Ill. Adm. Code 742 (December 21, 2000), R00-19(A). The increase in
    the acceptable background level for arsenic was adopted by the Board based on new scientific

     
    8
    knowledge about the existence of naturally occurring arsenic in Illinois and in response to public
    comment.
    Id
    .
     
    Still pending are related amendments proposed to Appendix B, Tables A and B. The
    Agency also proposed amendments to the arsenic remediation objectives for the ingestion
    exposure routes listed in each of the Appendix B tables. Agency Ex. 1 (Sullinger) at 2. Table A
    addresses the residential remediation exposure route, while Table B addresses the
    industrial/commercial remediation exposure route.
    Id
    . at 3. The Agency proposed a replacement
    of the current remediation objectives with a reference to the limits set forth in Appendix A, Table
    G.
    Id
    .
     
    Updates to Acceptable Detection Limits
     
     
    Agency witness Hurley testified regarding proposed changes to various parts of the
    appendices to Part 742. The amendments are proposed “to reflect updates to ‘Test Methods for
    Evaluating Solid Waste, Physical/Chemical Methods,’ USEPA Publication number SW-846.”
    Agency Ex. 1 (Hurley) at 2.
     
     
    In Appendix A, Table H consists of chemicals which, under a Tier 1, Class 1
    groundwater remediation objective, exceed a 1 in 1,000,000 cancer risk concentration. Agency
    Ex. 1 (Hurley) at 2. The Agency proposed adding six chemicals to this list because their updated
    acceptable detection limits (ADLs) now exceed the 1 in 1,000,000 cancer risk concentrations.
    The newly proposed chemicals are: bis (2-ethylhexyl)phthalate, DDD, DDE, DDT, 2,6-
    dinitroluene, and 2,4,6-trichlorophenol. Changes to the ADLs for 12 other listed chemicals are
    also proposed. For four of the 18 chemicals added or changed, the Tier I Groundwater
    Remediation Objectives for the groundwater component of the Groundwater Ingestion Route (35
    Ill. Adm. Code 742.Appendix B, Table E) are likewise changed to match the corresponding ADL
    according to the procedures specified in 35 Ill. Adm. Code 620.
     
     
    Proposed changes to Appendix B, Tables A, B, E, and F are designed to update and
    clarify the tables by updating references to the most recent Practical Quantitation Limits, and by
    clarifying the process used to derive certain specified groundwater remediation objectives.
    Agency Ex. 1 (Hurley) at 3.
     
    Updates to Tier 1 Objectives
     
     
    Agency witness Hornshaw testified on behalf of the Agency regarding proposed updates
    to the tables found in Appendix A, Tables A, E and F; Appendix B, Tables A, B, C, D, E, and F;
    and Appendix C, Tables B, D, E, I, and J. See generally Agency Ex. 1 (Hornshaw). In addition
    to the updated tables, there are also some corresponding changes proposed for the rules
    themselves. These proposed changes merely serve to clarify and correct confusing or incorrect
    information currently in the rules.
    Id
    .
     
    PUBLIC COMMENTS
     

     
    9
    Throughout this proceeding, the regulated community has repeatedly expressed support
    for the vast majority of changes proposed in this rulemaking. However, several issues were
    raised in public comment for which further discussion is appropriate.
     
    Potential Conflict with Other Proposed Amendments
     
      
    First, in PC 1, IERG expressed a concern regarding the fact that many of the proposed
    amendments in this rulemaking are related to other portions of Title 35, for which amendments
    will also be needed, and that the TACO amendments should not proceed until the other related
    amendments are also before the Board. PC 1 at 4-5. Specifically, at the time of IERG’s
    comment, the Board was awaiting proposed amendments from the Agency for Part 732
    (Petroleum Underground Storage Tank Program) and Part 740 (Site Remediation Program) of
    Title 35. IERG’s concern was that “the proposed revisions to Part 742 currently before the
    Board in Subdocket B cannot be fully considered by the Board, by IERG, or by other parties
    with an interest in the revision, until the Agency’s proposed revisions to Parts 732 and 740 are
    also before the Board for consideration.” PC 1 at 4. For that reason, IERG requested that the
    Board not move forward with Subdocket B until such time as the Agency’s proposals for
    amendment to Parts 732 and 740 were also before the Board. PC 1 at 5. The Board recognizes
    the interrelation between the provisions of Part 732 and Part 740 and those provisions being
    amended in this TACO proceeding.
     
    Both of those rulemaking proposals have now been submitted to the Board and hearings
    have been held. Except for concerns regarding the proposed regulation of MTBE, we are
    confident that these TACO amendments can proceed forward without creating a conflict with the
    Part 732 and Part 740 regulations.
     
    Applicability of Adopted Amendments to Ongoing Remedial Activities
     
      
    An important concern was also raised by ISG in its public comments. That concern
    involves the implementation of these proposed amendments for sites in the midst of ongoing
    remediation projects. PC 2 at 3. ISG suggested that it would be:
     
    unfair, arbitrary and capricious for the Board and then the [Agency] to simply
    impose these new requirements on ongoing activities, where the new
    requirements would substantially change the cost or direction of the activities. It
    is also unfair for these changes to be adopted without some determination as to
    when the new standards will apply. PC 2 at 3-4.
     
     
    During the first hearing in this matter, Agency witness Eastep offered his suggestion as to
    how the Agency would handle implementation of the new standards with regard to ongoing
    remedial activities:
     
    I think it would depend on where they [persons undergoing remediation projects]
    were at in the program. There have been some people that have entered the
    program four years ago and for whatever reason haven’t proceeded in the

     
    10
    program, they have just entered it in effect. Maybe they haven’t even done any
    sampling. Those people would follow the new rules.
     
    I would think, though, if you had a site that had developed remediation objectives
    and we had approved the plan, that they wouldn’t have to go back and do
    anything.
     
    Or I guess conceivably somebody could have even submitted their report,
    documenting their completion report, they would not have to go back if it were in
    that transitional period. So it would probably depend on where they were at in the
    program.
     
    If they had done an investigation three-and-a-half years ago and not done
    anything since and then they continued the investigation next year after the rules
    were passed, then they would be subject to the new rules too. Tr. (8/25/00) at
    143-44 (emphasis added).
     
    The Board appreciates the concerns raised by ISG and agrees that further
    clarification about the applicability of these amendments to ongoing remedial projects is
    beneficial.
     
    As illustrated by Agency witness Eastep’s testimony, the Agency has considered several
    different scenarios about how it will apply the TACO standards, new and old, to ongoing
    remediation projects in the various programs which rely upon them. For example, Eastep
    testified that, “if you had a site that had developed remediation objectives and [the Agency] had
    approved the plan, [then] they wouldn’t have to go back and do anything.” Tr. (8/25/00) at 143-
    44. The Board recognizes that the TACO standards are not self-implementing, and are instead
    implemented through a variety of cleanup programs, including Site Remediation Program (SRP),
    Leaking Underground Storage Tank (LUST), and Resource Conservation and Recovery Act
    (RCRA) closure permits. Within these programs, there are a variety of plans for which Agency
    approval is required, including, but not limited to, a remedial action plan (SRP), a corrective
    action plan (LUST), and a RCRA Part B permit. Other Agency approvals are also necessary at
    various stages of a cleanup under each of these programs. Because the TACO standards are not
    self-implementing, those standards, old and new, can only be applied to ongoing remediation
    sites in accordance with the relevant cleanup program. Likewise, any challenges to their
    applicability must proceed under the procedures established for the particular program.
     
    Accordingly, the Board concludes that the applicability of the TACO amendments, once
    adopted, must be governed by the relevant program’s rules. Should a program participant
    challenge their applicability to a particular cleanup in the future, the Board will consider the
    challenge in the context of that particular case and that program’s particular rules.
     
    MTBE
     
     
    In its first notice opinion and order, the Board included Agency proposed amendments,
    which would establish new cleanup standards for MTBE. Proposed Amendments to Tiered

     
    11
    Approach to Corrective Action Objectives (TACO): 35 Ill. Adm. Code 742 (July 27, 2000),
    R00-19(B). MTBE is not currently regulated under TACO. See 35 Ill. Adm. Code 742. Since
    first notice, the Agency also filed with the Board a rulemaking in which it proposes a new
    groundwater quality standard for MTBE. See Proposed MTBE Groundwater Quality Standards
    Amendments: 35 Ill. Adm. Code 620, R01-14. In the course of the Board’s proceedings in the
    groundwater proposal, the Agency has submitted documentation in support of the proposed
    MTBE regulations. On June 1, 2001, the Agency also submitted additional comments in the
    groundwater proceeding which further address MTBE-related issues.
     
     
    Also subsequent to our first notice opinion and order, there has been action in the State
    legislature to ban the use of MTBE in Illinois. Specifically, the House and Senate
    have both passed bills (House Bill 171/Senate Bill 1102) which prohibit the use, sale,
    distribution, blending, or manufacturing of MTBE as a fuel additive in Illinois. If signed by the
    Governor, the ban would be effective in three years.
     
     
    In light of the recent and significant concerns expressed regarding the use and regulation
    of MTBE, the Board is, by separate order today, opening a new subdocket, R00-19(C), which
    will be dedicated to addressing the addition of MTBE to the TACO standards as a contaminant
    for which testing and remediation must be performed. By opening a Subdocket C, the Board
    intends to provide a focused and well-reasoned examination of the MTBE issues. Because the
    MTBE TACO standards are so closely related to the proposed groundwater standards, the Board
    finds it prudent to address these two rulemaking proposals concurrently. The Board will proceed
    expeditiously in its efforts to adopt a scientifically supportable and environmentally protective
    MTBE standard.
     
    ECONOMIC AND TECHNICAL CONSIDERATION
     
     
    Section 27(a) of the Environmental Protection Act, requires that in promulgating
    regulations, the Board “shall take into account . . . the technical feasibility and economic
    reasonableness of measuring or reducing the particular type of pollution.” 415 ILCS 5/27(a)
    (1998).
     
     
    Pursuant to a letter dated August 1, 2000, the Board requested that DCCA conduct an
    economic impact study related to these proposed amendments. As is the Board’s practice, the
    August 1, 2000 letter contained a provision providing that in the event DCCA failed to respond
    to the letter within ten days, the Board would rely on a previous letter from DCCA, dated March
    10, 2000, in which DCCA expressed its inability to perform the requested economic impact
    study. DCCA did not respond to the Board’s August 1, 2000 letter. A hearing was scheduled to
    examine the Board’s request and DCCA’s lack of response, but no one appeared to give
    testimony.
     
     
    Considering that the majority of the proposed amendments in this second notice proposal
    will have little if any actual economic impact on either State agencies or the regulated
    community, the Board concludes that the proposed amendments are economically reasonable.
     

     
    12
     
    The Board also finds that the proposed amendments are technically feasible and are
    strongly supported by the regulated community.
     
    ORDER
     
     
    The Board directs the Clerk to cause the filing of the following with the Joint Committee
    on Administrative Rules.
     
     
    TITLE 35: ENVIRONMENTAL PROTECTION
    SUBTITLE G: WASTE DISPOSAL
    CHAPTER I: POLLUTION CONTROL BOARD
    SUBCHAPTER f: RISK BASED CLEANUP OBJECTIVES
    PART 742
    TIERED APPROACH TO CORRECTIVE ACTION OBJECTIVES
    SUBPART A: INTRODUCTION
     
    Section
    742.100
    Intent and Purpose
    742.105
    Applicability
    742.110
    Overview of Tiered Approach
    742.115
    Key Elements
    742.120
    Site Characterization
     
    SUBPART B: GENERAL
     
    Section
    742.200
    Definitions
    742.205
    Severability
    742.210
    Incorporations by Reference
    742.215
    Determination of Soil Attenuation Capacity
    742.220
    Determination of Soil Saturation Limit
    742.225
    Demonstration of Compliance with Remediation Objectives
    742.230
    Agency Review and Approval
     
    SUBPART C: EXPOSURE ROUTE EVALUATIONS
     
    Section
    742.300
    Exclusion of Exposure Route
    742.305
    Contaminant Source and Free Product Determination
    742.310
    Inhalation Exposure Route
    742.315
    Soil Ingestion Exposure Route
    742.320
    Groundwater Ingestion Exposure Route
     
    SUBPART D: DETERMINING AREA BACKGROUND
     

     
    13
    Section
    742.400
    Area Background
    742.405
    Determination of Area Background for Soil
    742.410
    Determination of Area Background for Groundwater
    742.415
    Use of Area Background Concentrations
     
    SUBPART E: TIER 1 EVALUATION
     
    Section
    742.500
    Tier 1 Evaluation Overview
    742.505
    Tier 1 Soil and Groundwater Remediation Objectives
    742.510
    Tier 1 Remediation Objectives Tables
     
    SUBPART F: TIER 2 GENERAL EVALUATION
     
    Section
    742.600
    Tier 2 Evaluation Overview
    742.605
    Land Use
    742.610
    Chemical and Site Properties
     
    SUBPART G: TIER 2 SOIL EVALUATION
     
    Section
    742.700
    Tier 2 Soil Evaluation Overview
    742.705
    Parameters for Soil Remediation Objective Equations
    742.710
    SSL Soil Equations
    742.715
    RBCA Soil Equations
    742.720
    Chemicals with Cumulative Noncarcinogenic Effects
     
    SUBPART H: TIER 2 GROUNDWATER EVALUATION
     
    Section
    742.800
    Tier 2 Groundwater Evaluation Overview
    742.805
    Tier 2 Groundwater Remediation Objectives
    742.810
    Calculations to Predict Impacts from Remaining Groundwater Contamination
     
    SUBPART I: TIER 3 EVALULATIONEVALUATION
     
    Section
    742.900
    Tier 3 Evaluation Overview
    742.905
    Modifications of Parameters
    742.910
    Alternative Models
    742.915
    Formal Risk Assessments
    742.920
    Impractical Remediation
    742.925
    Exposure Routes

     
    14
    742.930
    Derivation of Toxicological Data
     
    SUBPART J: INSTITUTIONAL CONTROLS
     
    Section
    742.1000
    Institutional Controls
    742.1005
    No Further Remediation Letters
    742.1010
    Environmental Land Use Controls
    742.1012
    Federally Owned Property: Land Use Control Memorandums of Agreement
    742.1015
    Ordinances
    742.1020
    Highway Authority Agreements
     
    SUBPART K: ENGINEERED BARRIERS
     
    Section
    742.1100
    Engineered Barriers
    742.1105
    Engineered Barrier Requirements
     
    APPENDIX A
    General
    ILLUSTRATION A
    Developing Soil Remediation Objectives Under the Tiered Approach
    ILLUSTRATION B
    Developing Groundwater Remediation Objectives Under the Tiered
    Approach
    TABLE A
    Soil Saturation Limits (C
    sat
    ) for Chemicals Whose Melting Point is Less than
    30
    ?
    C
    TABLE B
    Tolerance Factor (K)
    TABLE C
    Coefficients {A
    N-I+1
    } for W Test of Normality, for N=2(1)50
    TABLE D
    Percentage Points of the W Test for Nn=3(1)50
    TABLE E
    Similar-Acting Noncarcinogenic Chemicals
    TABLE F
    Similar-Acting Carcinogenic Chemicals
    TABLE G
    Concentrations of Inorganic Chemicals in Background Soils
    TABLE H
    Chemicals Whose Tier 1 Class I Groundwater Remediation Objective Exceeds
    the 1 in 1,000,000 Cancer Risk Concentration
     
    APPENDIX B
    Tier 1 Tables and Illustrations
    ILLUSTRATION A
    Tier 1 Evaluation
    TABLE A
    Tier 1 Soil Remediation Objectives for Residential Properties
    TABLE B
    Tier 1 Soil Remediation Objectives for Industrial/Commercial Properties
    TABLE C
    pH Specific Soil Remediation Objectives for Inorganics and Ionizing Organics
    for the Soil Component of the Groundwater Ingestion Route (Class I
    Groundwater)
    TABLE D
    pH Specific Soil Remediation Objectives for Inorganics and Ionizing Organics
    for the Soil Component of the Groundwater Ingestion Route (Class II
    Groundwater)
    TABLE E
    Tier 1 Groundwater Remediation Objectives for the Groundwater Component of
    the Groundwater Ingestion Route

     
    15
    TABLE F
    Values Used to Calculate the Tier 1 Soil Remediation Objectives for the Soil
    Component of the Groundwater Ingestion Route
     
    APPENDIX C
    Tier 2 Tables and Illustrations
    ILLUSTRATION A
    Tier 2 Evaluation for Soil
    ILLUSTRATION B
    Tier 2 Evaluation for Groundwater
    ILLUSTRATION C
    US Department of Agriculture Soil Texture Classification
    TABLE A
    SSL Equations
    TABLE B
    SSL Parameters
    TABLE C
    RBCA Equations
    TABLE D
    RBCA Parameters
    TABLE E
    Default Physical and Chemical Parameters
    TABLE F
    Methods for Determining Physical Soil Parameters
    TABLE G
    Error Function (erf)
    TABLE H
    Q/C Values By Source Area
    TABLE I
    K
    oc
    Values for Ionizing Organics as a Function of pH (cm
    3
    /g or L/kg or
    cm3water/g
    soil
    ) cm
    3
    water
    /g
    soil
    )
    TABLE J
    Values to be Substituted for K
    d
    or K
    s
    ks k
    d
    or k
    s
    when Evaluating Inorganics as a
    Function of pH (cm3/g cm
    3
    /g or L/kg or cm
    3
    water/g
    soil
    cm
    3
    water
    /g
    soil
    )
    TABLE K Parameter Estimates for Calculating Water-Filled Soil Porosity (
    ?
    w
    )
     
    AUTHORITY: Implementing Sections 22.4, 22.12, Title XVI, and Title XVII and authorized by
    Sections 27, 57.14, and 58.5 of the Environmental Protection Act [415 ILCS 5/22.4, 22.12, 27,
    57.14 and 58.5 and Title XVI and Title XVII].
    SOURCE: Adopted in R97-12(A) at 21 Ill. Reg. 7942, effective July 1, 1997; amended in R97-
    12(B) at 21 Ill. Reg. 16391, effective December 8, 1997; amended in R97-12(C) at 22 Ill. Reg.
    10847, effective June 8, 1998; amended in R00-19(B) at 24 25 Ill. Reg. _______, effective
    ____________________.
    NOTE:
    Capitalization indicates statutory language.
    SUBPART B: GENERAL
    Section 742.210
    Incorporations by Reference
    a)
    The Board incorporates the following material by reference:
    ASTM. American Society for Testing and Materials, 1916 Race Street,
    Philadelphia, PA 19103 (215) 299-5400.
    ASTM D 2974-87, Standard Test Methods for Moisture, Ash and Organic
    Matter of Peat and Other Organic Soils, approved May 29, 1987
    (reapproved 1995).
    ASTM D 2488-93, Standard Practice for Description and Identification of
    Soils (Visual-Manual Procedure), approved September 15, 1993.

     
    16
    ASTM D 1556-90, Standard Test Method for Density and Unit Weight of
    Soil in Place by the Sand-Cone Method, approved June 29, 1990.
    ASTM D 2167-94, Standard Test Method for Density and Unit Weight of
    Soil in Place by the Rubber Balloon Method, approved March 15, 1994.
    ASTM D 2922-91, Standard Test Methods for Density of Soil and Soil-
    Aggregate in Place by Nuclear Methods (Shallow Depth), approved
    December 23, 1991.
    ASTM D 2937-94, Standard Test Method for Density of Soil in Place by
    the Drive-Cylinder Method, approved June 15, 1994.
    ASTM D 854-92, Standard Test Method for Specific Gravity of Soils,
    approved November 15, 1992.
    ASTM D 2216-92, Standard Method for Laboratory Determination of
    Water (Moisture) Content of Soil and Rock, approved June 15, 1992.
    ASTM D 4959-89, Standard Test Method for Determination of Water
    (Moisture) Content of Soil by Direct Heating Method, approved June 30,
    1989 (reapproved 1994).
    ASTM D 4643-93, Standard Test Method for Determination of Water
    (Moisture) Content of Soil by the Microwave Oven Method, approved
    July 15, 1993.
    ASTM D 5084-90, Standard Test Method for Measurement of Hydraulic
    Conductivity of Saturated Porous Materials Using a Flexible Wall
    Permeameter, approved June 29, 1990.
    ASTM D 422-63, Standard Test Method for Particle-Size Analysis of
    Soils, approved November 21, 1963 (reapproved 1990).
    ASTM D 1140-92, Standard Test Method for Amount of Material in Soils
    Finer than the No. 200 (75
    ?
    m) Sieve, approved November 15, 1992.
    ASTM D 3017-88, Standard Test Method for Water Content of Soil and
    Rock in Place by Nuclear Methods (Shallow Depth), approved May 27,
    1988.
    ASTM D 4525-90, Standard Test Method for Permeability of Rocks by
    Flowing Air, approved May 25, 1990.
    ASTM D 2487-93, Standard Test Method for Classification of Soils for
    Engineering Purposes, approved September 15, 1993.

     
    17
    ASTM E 1527-93, Standard Practice for Environmental Site Assessments:
    Phase I Environmental Site Assessment Process, approved March 15,
    1993. Vol. 11.04.
    ASTM E 1739-95, Standard Guide for Risk-Based Corrective Action
    Applied at Petroleum Release Sites, approved September 10, 1995.
    Barnes, Donald G. and Dourson, Michael. (1988). Reference Dose (RfD):
    Description and Use in Health Risk Assessments. Regulatory Toxicology and
    Pharmacology. 8, 471-486.
    GPO. Superintendent of Documents, U.S. Government Printing Office,
    Washington, DC 20401, (202) 783-3238.
    USEPA Guidelines for Carcinogenic Risk Assessment, 51 Fed. Reg.
    33992-34003 (September 24, 1986).
    "Test Methods for Evaluating Solid Waste, Physical/Chemical Methods",
    USEPA Publication number SW-846 (Third Edition, Final Update III,
    December 1996Final Update IIIA, April 1998), as amended by Updates I,
    IIA, and III, and IIIA (Document No. 955-001-00000-1)(contact USEPA,
    Office of Solid Waste, for Update III).
    "Methods for the Determination of Organic Compounds in Drinking
    Water", EPA Publication No. EPA/600/4-88/039 (December 1988
    (Revised July 1991)).
    "Methods for the Determination of Organic Compounds in Drinking
    Water, Supplement II", EPA Publication No. EPA/600/R-92/129 (August
    1992).
    "Methods for the Determination of Organic Compounds in Drinking
    Water, Supplement III", EPA Publication No. EPA/600/R-95/131 (August
    1995).
    IRIS. Integrated Risk Information System, National Center for Environmental
    Assessment, U.S. Environmental Protection Agency, 26 West Martin Luther King
    Drive, MS-190, Cincinnati, OH 45268, (513) 569-7254.
    "Reference Dose (RfD): Description and Use in Health Risk
    Assessments", Background Document 1A (March 15, 1993).
    "EPA Approach for Assessing the Risks Associated with Chronic
    Exposures to Carcinogens", Background Document 2 (January 17, 1992).
    Nelson, D.W., and L.E. Sommers. (1982). Total carbon, organic carbon, and
    organic matter. In: A.L. Page (ed.), Methods of Soil Analysis. Part 2. Chemical

     
    18
    and Microbiological Properties. 2nd Edition, pp. 539-579, American Society of
    Agronomy. Madison, WI.
    NTIS. National Technical Information Service, 5285 Port Royal Road,
    Springfield, VA 22161, (703) 487-4600.
    "Dermal Exposure Assessment: Principles and Applications", EPA
    Publication No. EPA/600/8-91/011B (January 1992).
    "Exposure Factors Handbook", EPA Publication No. EPA/600/8-89/043
    (July 1989).
    "Risk Assessment Guidance for Superfund, Vol. I; Human Health
    Evaluation Manual, Supplemental Guidance: Standard Default Exposure
    Factors", OSWER Directive 9285.6-03 (March 1991).
    "Rapid Assessment of Exposure to Particulate Emissions from Surface
    Contamination Sites," EPA Publication No. EPA/600/8-85/002 (February
    1985), PB 85-192219.
    "Risk Assessment Guidance for Superfund, Volume I; Human Health
    Evaluation Manual (Part A)", Interim Final, EPA Publication No.
    EPA/540/1-89/002 (December 1989).
    "Risk Assessment Guidance for Superfund, Volume I; Human Health
    Evaluation Manual, Supplemental Guidance, Dermal Risk Assessment
    Interim Guidance", Draft (August 18, 1992).
    "Soil Screening Guidance: Technical Background Document", EPA
    Publication No. EPA/540/R-95/128, PB 96-963502 (May 1996).
    "Soil Screening Guidance: User's Guide", EPA Publication No.
    EPA/540/R-96/018, PB 96-963505 (April 1996).
    "
    Superfund Exposure Assessment Manual", EPA Publication No.
    EPA/540/1-88/001 (April 1988).
    RCRA Facility Investigation Guidance, Interim Final, developed by USEPA
    (EPA 530/SW-89-031), 4 volumes May 1989.
    b)
    CFR (Code of Federal Regulations). Available from the Superintendent of
    Documents, U.S. Government Printing Office, Washington, D.C. 20402
    (202)783-3238:
    40 CFR 761.120 (19931998).
    c)
    This Section incorporates no later editions or amendments.

     
    19
    (Source: Amended in R00-19(B) at 24 25 Ill. Reg. _______ , effective _____________)
    Section 742.220
    Determination of Soil Saturation Limit
    a)
    For any organic contaminant that has a melting point below 30
    o
    C, the remediation
    objective for the inhalation exposure route developed under Tier 2 or Tier 3 shall
    not exceed the soil saturation limit, as determined under subsection (c) of this
    Section.
    b)
    For any organic contaminant, the remediation objective under Tier 2 or Tier 3 for
    the soil component of the groundwater ingestion exposure route shall not exceed
    the soil saturation limit, as determined under subsection (c) of this Section.
    c)
    The soil saturation limit shall be:
    1)
    The value listed in Appendix A, Table A for that specific contaminant;
    2)
    A value derived from Equation S29 in Appendix C, Table A; or
    3)
    A value derived from another method approved by the Agency.
    (Source: Amended in R00-19(B) at 24 25 Ill. Reg. _______, effective ______________)
    Section 742.225
    Demonstration of Compliance with Remediation Objectives
    Compliance is achieved if each sample result does not exceed that respective remediation
    objective unless a person elects to proceed under subsections (c), (d) and (e) of this Section.
    a)
    Compliance with groundwater remediation objectives developed under Subparts
    D through F and H through I shall be demonstrated by comparing the contaminant
    concentrations of discrete samples at each sample point to the applicable
    groundwater remediation objective. Sample points shall be determined by the
    program under which remediation is performed.
    b)
    Unless the person elects to composite samples or average sampling results as
    provided in subsections (c) and (d) of this Section, compliance with soil
    remediation objectives developed under Subparts D through G and I shall be
    demonstrated by comparing the contaminant concentrations of discrete samples to
    the applicable soil remediation objective.
    1)
    Except as provided in subsections (c) and (d) of this Section, compositing
    of samples is not allowed.
    2)
    Except as provided in subsections (c) and (d) of this Section, averaging of
    sample results is not allowed.

     
    20
    3)
    Notwithstanding subsections (c) and (d) of this Section, compositing of
    samples and averaging of sample results is not allowed for the
    construction worker population.
    4)
    The number of sampling points required to demonstrate compliance is
    determined by the requirements applicable to the program under which
    remediation is performed.
    c)
    If a person chooses to composite soil samples or average soil sample results to
    demonstrate compliance relative to the soil component of the groundwater
    ingestion exposure route, the following requirements apply:
    1)
    A minimum of two sampling locations for every 0.5 acre of contaminated
    area is required, with discrete samples at each sample location obtained at
    every two feet of depth, beginning at six inches below the ground surface
    and continuing through the zone of contamination. Alternatively, a
    sampling method may be approved by the Agency based on an
    appropriately designed site-specific evaluation. Samples obtained at or
    below the water table shall not be used in compositing or averaging.
    2)
    For contaminants of concern other than volatile organic contaminants:
    A)
    Discrete samples from the same boring may be composited.
    B)
    Discrete sample results from the same boring may be averaged.
    3)
    For volatile organic contaminants:
    A)
    Compositing of samples is not allowed.
    B)
    Discrete sample results from the same boring may be averaged.
    d)
    If a person chooses to composite soil samples or average soil sample results to
    demonstrate compliance relative to the inhalation exposure route or ingestion
    exposure route, the following requirements apply:
    1)
    A person shall submit a sampling plan for Agency approval, based upon a
    site-specific evaluation;
    2)
    For volatile organic compounds, compositing of samples is not allowed;
    and
    3)
    All samples shall be collected within the contaminated area.
    e)
    When averaging under this Section, if no more than 50% of sample results are
    reported as "non-detect", "no contamination", "below detection limits", or similar
    terms, such results shall be included in the averaging calculation as one-half of the
    reported analytical detection limit for the contaminant. However, when

     
    21
    performing a test for normal or lognormal distribution for the purpose of
    calculating a 95% Upper Confidence Limit of the mean for a contaminant, a
    person may substitute for each non-detect value a randomly generated value
    between, but not including, zero and the reported analytical detection limit. If
    more than 50% of sample results are "non-detect", another statistically valid
    procedure approved by the Agency may be used to determine an average.
    f)
    All soil samples collected after the effective date of this subsection (f) shall be
    reported on a dry weight basis for the purpose of demonstrating compliance, with
    the exception of the TCLP and SPLP and the property pH.
    (Source: Amended in R00-19(B) at 24 25 Ill. Reg. _______, effective ____________)
    SUBPART C: EXPOSURE ROUTE EVALUATIONS
    Section 742.300
    Exclusion of Exposure Route
    a)
    This Subpart sets forth requirements to demonstrate that an actual or potential
    impact to a receptor or potential receptor from a contaminant of concern can be
    excluded from consideration from one or more exposure routes. If an evaluation
    under this Part Subpart demonstrates the applicable requirements for excluding an
    exposure route are met, then the exposure route is excluded from consideration
    and no remediation objective(s) need be developed for that exposure route.
    b)
    No exposure route may be excluded from consideration until characterization of
    the extent and concentrations of contaminants of concern at a site has been
    performed. The actual steps and methods taken to characterize a site shall be
    determined by the specific program requirements under which the site
    remediation is being addressed.
    c)
    As an alternative to the use of the requirements in this Part Subpart, a person may
    use the procedures for evaluation of exposure routes under Tier 3 as set forth in
    Section 742.925.
    (Source: Amended in R00-19(B) at 24 25 Ill. Reg. _______, effective ______________)
    Section 742.305
    Contaminant Source and Free Product Determination
    No exposure route shall be excluded from consideration relative to a contaminant of concern
    unless the following requirements are met:
    a)
    The sum of the concentrations of all organic contaminants of concern shall not
    exceed the attenuation capacity of the soil as determined under Section 742.215;
    b)
    The concentrations of any organic contaminants of concern remaining in the soil
    shall not exceed the soil saturation limit as determined under Section 742.220;

     
    22
    c)
    Any soil which contains contaminants of concern shall not exhibit any of the
    characteristics of reactivity for hazardous waste as determined under 35 Ill. Adm.
    Code 721.123;
    d)
    Any soil which contains contaminants of concern shall not exhibit a pH less than
    or equal to 2.0 or greater than or equal to 12.5, as determined by SW-846 Method
    9040B: pH Electrometric for soils with 20% or greater aqueous (moisture) content
    or by SW-846 Method 9045C: Soil pH for soils with less than 20% aqueous
    (moisture) content as incorporated by reference in Section 742.210; and
    e)
    Any soil which contains contaminants of concern in the following list of inorganic
    chemicals or their salts shall not exhibit any of the characteristics of toxicity for
    hazardous waste as determined by 35 Ill. Adm. Code 721.124, or an alternative
    method approved by the Agency: arsenic, barium, cadmium, chromium, lead,
    mercury, selenium or silver; and.
    f)
    If contaminants of concern include polychlorinated biphenyls (PCBs), the
    concentration of any PCBs in the soil shall not exceed 50 parts per million as
    determined by SW-846 Methods.
    (Source: Amended in R00-19(B) at 24 25 Ill. Reg. _______, effective ______________)
    Section 742.310
    Inhalation Exposure Route
    The inhalation exposure route may be excluded from consideration if:
    a)
    The requirements of Sections 742.300 and 742.305 are met; and
    b)
    An institutional control, in accordance with Subpart J, is in place that meets the
    following requirements:
    1)
    Either:
    A)
    The concentration of any contaminant of concern within ten feet of
    the land surface or within ten feet of any man-made pathway shall
    not exceed the Tier 1 remediation objective under Subpart E for
    the inhalation exposure route; or
    B)
    An engineered barrier, as set forth in Subpart K and approved by
    the Agency, is in place; and
    2)
    Requires safety precautions for the construction worker if the Tier 1
    construction worker remediation objectives are exceeded.
    b)
    An approved engineered barrier is in place that meets the requirements of Subpart
    K;

     
    23
    c)
    Safety precautions for the construction worker are taken if the Tier 1 construction
    worker remediation objectives are exceeded; and
     
     
    d)
    An institutional control, in accordance with Subpart J, will be placed on the
    property.
    (Source: Amended in R00-19(B) at 24 25 Ill. Reg. _______, effective ______________)
    Section 742.315
    Soil Ingestion Exposure Route
    The soil ingestion exposure route may be excluded from consideration if:
    a)
    The requirements of Sections 742.300 and 742.305 are met; and
    b)
    An institutional control, in accordance with Subpart J, is in place that meets the
    following requirements:
    1)
    Either:
    A)
    The concentration of any contaminant of concern within three feet
    of the land surface shall not exceed the Tier 1 remediation
    objective under Subpart E for the ingestion of soil exposure route;
    or
    B)
    An engineered barrier, as set forth in Subpart K and approved by
    the Agency, is in place; and
    2)
    Requires safety precautions for the construction worker if the Tier 1
    construction worker remediation objectives are exceeded.
    b)
    An approved engineered barrier is in place that meets the requirements of Subpart
    K;
    c)
    Safety precautions for the construction worker are taken if the Tier 1 construction
    worker remediation objectives are exceeded; and
     
     
    d)
    An institutional control, in accordance with Subpart J, will be placed on the
    property.
    (Source: Amended in R00-19(B) at 24 25 Ill. Reg. _______, effective _______________)
    SUBPART F: TIER 2 GENERAL EVALUATION
    Section 742.605
    Land Use
    a)
    Present and post-remediation land use is evaluated in a Tier 2 evaluation.
    Acceptable exposure factors for the Tier 2 evaluation for residential,
    industrial/commercial, and construction worker populations are provided in the
    far right column of both Appendix C, both Tables B and D. Use of exposure

     
    24
    factors different from those in Appendix C, Tables B and D must be approved by
    the Agency as part of a Tier 3 evaluation.
    b)
    If a Tier 2 evaluation is based on an industrial/commercial property use, then:
    1)
    Construction worker populations shall also be evaluated; and
    2)
    Institutional controls are required in accordance with Subpart J.
    (Source: Amended in R00-19(B) at 24 25 Ill. Reg. _______, effective _______________)
    SUBPART G: TIER 2 SOIL EVALUATION
    Section 742.700
    Tier 2 Soil Evaluation Overview
    a)
    Tier 2 remediation objectives are developed through the use of models which
    allow site-specific data to be considered. Appendix C, Tables A and C list
    equations that shall be used under a Tier 2 evaluation to calculate soil remediation
    objectives prescribed by SSL and RBCA models, respectively. (See also
    Appendix C, Illustration A.)
    b)
    Appendix C, Table A lists equations that are used under the SSL model. (See also
    Appendix C, Illustration A.) The SSL model has equations to evaluate the
    following human exposure routes:
    1)
    Soil ingestion exposure route;
    2)
    Inhalation exposure route for:
    A)
    Volatiles Organic contaminants;
    B)
    Fugitive dust; and
    3)
    Soil component of the groundwater ingestion exposure route.
    c)
    Evaluation of the dermal exposure route is not required under the SSL model.
    d)
    Appendix C, Table C lists equations that are used under the RBCA model. (See
    also Appendix C, Illustration A.) The RBCA model has equations to evaluate
    human exposure based on the following:
    1)
    The combined exposure routes of inhalation of vapors and particulates,
    soil ingestion and dermal contact with soil;
    2)
    The ambient vapor inhalation (outdoor) route from subsurface soils;
    3)
    Soil component of the groundwater ingestion route; and
    4)
    Groundwater ingestion exposure route.

     
    25
    e)
    The equations in either Appendix C, Table A or C may be used to calculate
    remediation objectives for each contaminant of concern under Tier 2, if the
    following requirements are met:
    1)
    The Tier 2 soil remediation objectives for the ingestion and inhalation
    exposure routes shall use the applicable equations from the same approach
    (i.e., SSL equations in Appendix C, Table C).
    2)
    The equations used to calculate soil remediation objectives for the soil
    component of the groundwater ingestion exposure route are not dependent
    on the approach utilized to calculate soil remediation objectives for the
    other exposure routes. For example, it is acceptable to use the SSL
    equations for calculating Tier 2 soil remediation objectives for the
    ingestion and inhalation exposure routes, and the RBCA equations for
    calculating Tier 2 soil remediation objectives for the soil component of the
    groundwater ingestion exposure route.
    3)
    Combining equations from Appendix C, Tables A and C to form a new
    model is not allowed. In addition, Appendix C, Tables A and C must use
    their own applicable parameters identified in Appendix C, Tables B and
    D, respectively.
    f)
    In calculating soil remediation objectives for industrial/commercial property use,
    applicable calculations shall be performed twice: once using
    industrial/commercial population default values and once using construction
    worker population default values. The more stringent soil remediation objectives
    derived from these calculations must be used for further Tier 2 evaluations.
    g)
    Tier 2 data sheets provided by the Agency shall be used to present calculated Tier
    2 remediation objectives, if required by the particular program for which
    remediation is being performed.
    h)
    The RBCA equations which rely on the parameter Soil Water Sorption
    Coefficient (k
    s
    ) can only be used for ionizing organics and inorganics by
    substituting values for k
    s
    from Appendix C, Tables I and J, respectively. This will
    also require the determination of a site-specific value for soil pH.
    (Source: Amended in R00-19(B) at 24 25 Ill. Reg. _______, effective ______________)
    Section 742.710
    SSL Soil Equations
    a)
    This Section sets forth the equations and parameters used to develop Tier 2 soil
    remediation objectives for the three exposure routes using the SSL approach.
    b)
    Soil Ingestion Exposure Route
    1)
    Equations S1 through S3 form the basis for calculating Tier 2 remediation
    objectives for the soil ingestion exposure route using the SSL approach.

     
    26
    Equation S1 is used to calculate soil remediation objectives for
    noncarcinogenic contaminants. Equations S2 and S3 are used to calculate
    soil remediation objectives for carcinogenic contaminants for residential
    populations and industrial/commercial and construction worker
    populations, respectively.
    2)
    For Equations S1 through S3, the SSL default values cannot be modified
    with site-specific information.
    c)
    Inhalation Exposure Route
    1)
    Equations S4 through S16, S26 and S27 are used to calculate Tier 2 soil
    remediation objectives for the inhalation exposure route using the SSL
    approach. To address this exposure route, volatiles organic contaminants
    and mercury must be evaluated separately from fugitive dust using their
    own equations set forth in subsections (c)(2) and (c)(3) of this Section,
    respectively.
     
    2)
    Volatiles Organic Contaminants
    A)
    Equations S4 through S10 are used to calculate Tier 2 soil
    remediation objectives for volatile organic contaminants and
    mercury based on the inhalation exposure route. Equation S4 is
    used to calculate soil remediation objectives for noncarcinogenic
    volatile organic contaminants in soil for residential and
    industrial/commercial populations. Equation S5 is used to
    calculate soil remediation objectives for noncarcinogenic volatile
    organic contaminants and mercury in soil for construction worker
    populations. Equation S6 is used to calculate soil remediation
    objectives for carcinogenic volatile organic contaminants in soil
    for residential and industrial/commercial populations. Equation S7
    is used to calculate soil remediation objectives for carcinogenic
    volatile organic contaminants in soil for construction worker
    populations. Equations S8 through S10, S27 and S28 are used for
    calculating numerical values for some of the parameters in
    Equations S4 through S7.
    B)
    For Equation S4, a numerical value for the Volatilization Factor
    (VF) can be calculated in accordance with subsection (c)(2)(F) of
    this Section. The remaining parameters in Equation S4 have either
    SSL default values listed in Appendix C, Table B or toxicological-
    specific information (i.e., RfC), which can be obtained from IRIS
    or requested from the program under which the remediation is
    being performed.
    C)
    For Equation S5, a numerical value for the Volatilization Factor
    adjusted for Agitation (VF') can be calculated in accordance with

     
    27
    subsection (c)(2)(G) of this Section. The remaining parameters in
    Equation S5 have either SSL default values listed in Appendix C,
    Table B or toxicological-specific information (i.e., RfC), which
    can be obtained from IRIS or requested from the program under
    which the remediation is being performed.
    D)
    For Equation S6, a numerical value for VF can be calculated in
    accordance with subsection (c)(2)(F) of this Section. The
    remaining parameters in Equation S6 have either default values
    listed in Appendix C, Table B or toxicological-specific information
    (i.e., URF), which can be obtained from IRIS or requested from the
    program under which the remediation is being performed.
    E)
    For Equation S7, a numerical value for VF' can be calculated in
    accordance with subsection (c)(2)(G) of this Section. The
    remaining parameters in Equation S7 have either default values
    listed in Appendix C, Table B or toxicological-specific information
    (i.e., URF), which can be obtained from IRIS or requested from the
    program under which the remediation is being performed.
    F)
    The VF can be calculated for residential and industrial/commercial
    populations using one of the following equations based on the
    information known about the contaminant source and receptor
    population:
    i)
    Equation S8, in conjunction with Equation S10, is used to
    calculate VF assuming an infinite source of contamination;
    or
    ii)
    If the area and depth of the contaminant source are known
    or can be estimated reliably, mass limit considerations may
    be used to calculate VF using Equation S26.
    G)
    The VF' can be calculated for the construction worker populations
    using one of the following equations based on the information
    known about the contaminant source:
    i)
    Equation S9 is used to calculate VF' assuming an infinite
    source of contamination; or
    ii)
    If the area and depth of the contaminant source are known
    or can be estimated reliably, mass limit considerations may
    be used to calculate VF' using Equation S27.
    3)
    Fugitive Dust
    A)
    Equations S11 through S16 are used to calculate Tier 2 soil
    remediation objectives using the SSL fugitive dust model for the

     
    28
    inhalation exposure route. Equation S11 is used to calculate soil
    remediation objectives for noncarcinogenic contaminants in
    fugitive dust for residential and industrial/commercial populations.
    Equation S12 is used to calculate soil remediation objectives for
    noncarcinogenic contaminants in fugitive dust for construction
    worker populations. Equation S13 is used to calculate soil
    remediation objectives for carcinogenic contaminants in fugitive
    dust for residential and industrial/commercial populations.
    Equation S14 is used to calculate soil remediation objectives for
    carcinogenic contaminants in fugitive dust for construction worker
    populations. Equations S15 and S16 are used for calculating
    numerical quantities for some of the parameters in Equations S11
    through S14.
    B)
    For Equation S11, a numerical value can be calculated for the
    Particulate Emission Factor (PEF) using Equation S15. This
    equation relies on various input parameters from a variety of
    sources. The remaining parameters in Equation S11 have either
    SSL default values listed in Appendix C, Table B or toxicological-
    specific information (i.e., RfC), which can be obtained from IRIS
    or requested from the program under which the remediation is
    being performed.
    C)
    For Equation S12, a numerical value for the Particulate Emission
    Factor for Construction Worker (PEF') can be calculated using
    Equation S16. The remaining parameters in Equation S12 have
    either SSL default values listed in Appendix C, Table B or
    toxicological-specific information (i.e., RfC), which can be
    obtained from IRIS or requested from the program under which the
    remediation is being performed.
    D)
    For Equation S13, a numerical value for PEF can be calculated
    using Equation S15. The remaining parameters in Equation S13
    have either default values listed in Appendix C, Table B or
    toxicological-specific information (i.e., URF), which can be
    obtained from IRIS or requested from the program under which the
    remediation is being performed.
    E)
    For Equation S14, a numerical value for PEF' can be calculated
    using Equation S16. The remaining parameters in Equation S14
    have either default values listed in Appendix C, Table B or
    toxicological-specific information (i.e., URF), which can be
    obtained from IRIS or requested from the program under which the
    remediation is being performed.
    d)
    Soil Component of the Groundwater Ingestion Exposure Route

     
    29
    The Tier 2 remediation objective for the soil component of the groundwater
    ingestion exposure route can be calculated using one of the following equations
    based on the information known about the contaminant source and receptor
    population:
    1)
    Equation S17 is used to calculate the remediation objective assuming an
    infinite source of contamination.
    A)
    The numerical quantities for four parameters in Equation S17, the
    Target Soil Leachate Concentration (C
    w
    ), Soil-Water Partition
    Coefficient (K
    d
    ) for non-ionizing organics, Water-Filled Soil
    Porosity (
    ?
    w
    ) Theta
    w
    (
    ?
    w
    ) and Air-Filled Soil Porosity (
    ?
    a
    ) Theta
    a
    (
    ?
    a
    ), are calculated using Equations S18, S19, S20 and S21,
    respectively. Equations S22, S23, S24 and S25 are also needed to
    calculate numerical values for Equations S18 and S21. The pH-
    dependent K
    d
    values for ionizing organics can be calculated using
    Equation S19 and the pH-dependent K
    oc
    values in Appendix C,
    Table I.
    B)
    The remaining parameters in Equation S17 are Henry's Law
    Constant (H'), a chemical specific value listed in Appendix C,
    Table E and Dry Soil Bulk Density (
    ?
    b
    ), a site-specific based value
    listed in Appendix C, Table B.
    C)
    The default value for GW
    obj
    is the Tier 1 groundwater objective.
    For chemicals for which there is no Tier 1 groundwater
    remediation objective, the value for GW
    obj
    shall be the Health
    Advisory concentration determined according to the procedures
    specified in 35 Ill. Adm. Code 620, Subpart F. As an alternative to
    using Tier 1 groundwater remediation objectives or Health
    Advisory concentrations determined according to the procedures
    specified in 35 Ill. Adm. Code 620, Subpart F., GW
    obj
    may be
    developed using Equations R25 and R26, if approved institutional
    controls are in place as required in Subpart J.
    2)
    If the area and depth of the contaminant source are known or can be
    estimated reliably, mass limit considerations may be used to calculate the
    remediation objective for this exposure route using Equation S28. The
    parameters in Equation S28 have default values listed in Appendix C,
    Table B.
    (Source: Amended in R00-19(B) at 24 25 Ill. Reg. _______, effective ________________)
    Section 742.715
    RBCA Soil Equations
    a)
    This Section presents the RBCA model and describes the equations and
    parameters used to develop Tier 2 soil remediation objectives.

     
    30
    b)
    Ingestion, Inhalation, and Dermal Contact
    1)
    The two sets of equations in subsections (b)(2) and (b)(3) of this Section
    shall be used to generate Tier 2 soil remediation objectives for the
    combined ingestion, inhalation, and dermal contact with soil exposure
    routes.
    2)
    Combined Exposure Routes of Soil Ingestion, Inhalation of Vapors and
    Particulates, and Dermal Contact with Soil
    A)
    Equations R1 and R2 form the basis for deriving Tier 2
    remediation objectives for the set of equations that evaluates the
    combined exposure routes of soil ingestion, inhalation of vapors
    and particulates, and dermal contact with soil using the RBCA
    approach. Equation R1 is used to calculate soil remediation
    objectives for carcinogenic contaminants. Equation R2 is used to
    calculate soil remediation objectives for noncarcinogenic
    contaminants. Soil remediation objectives for the ambient vapor
    inhalation (outdoor) route from subsurface soils must also be
    calculated in accordance with the procedures outlined in subsection
    (b)(3) of this Section and compared to the values generated from
    Equations R1 or R2. The smaller value (i.e., R1 and R2 compared
    to R7 and R8, respectively) from these calculations is the Tier 2
    soil remediation objective for the combined exposure routes of soil
    ingestion, inhalation, and dermal contact with soil.
    B)
    In Equation R1, numerical values are calculated for two
    parameters:
    i)
    The volatilization factor for surficial soils (VF
    ss
    ) using
    Equations R3 and R4; and
    ii)
    The volatilization factor for subsurface soils regarding
    particulates (VF
    p
    ) using Equation R5.
    C)
    VF
    ss
    uses Equations R3 and R4 to derive a numerical value.
    Equation R3 requires the use of Equation R6. Both equations must
    be used to calculate the VF
    ss
    . The lowest calculated value from
    these equations must be substituted into Equation R1.
    D)
    The remaining parameters in Equation R1 have either default
    values listed in Appendix C, Table D or toxicological-specific
    information (i.e., SF
    o
    , SF
    i
    ), which can be obtained from IRIS or
    requested from the program under which the remediation is being
    performed.
    E)
    For Equation R2, the parameters VF
    ss
    and VF
    p
    are calculated. The
    remaining parameters in Equation R2 have either default values

     
    31
    listed in Appendix C, Table D or toxicological-specific
    information (i.e., RfD
    o
    , RfD
    i
    ), which can be obtained from IRIS or
    requested from the program under which the remediation is being
    performed.
    F)
    For chemicals other than inorganics which do not have default
    values for the dermal absorption factor (RAF
    d
    ) in Appendix C,
    Table D, a dermal absorption factor of 0.5 shall be used for
    Equations R1 and R2. For inorganics, dermal absorption may be
    disregarded (i.e., RAF
    d
    = 0).
    3)
    Ambient Vapor Inhalation (outdoor) route from Subsurface Soils (soil
    below one meter)
    A)
    Equations R7 and R8 form the basis for deriving Tier 2
    remediation objectives for the ambient vapor inhalation (outdoor)
    route from subsurface soils using the RBCA approach. Equation
    R7 is used to calculate soil remediation objectives for carcinogenic
    contaminants. Equation R8 is used to calculate soil remediation
    objectives for noncarcinogenic contaminants.
    B)
    For Equation R7, the carcinogenic risk-based screening level for
    air (RBSL
    air
    ) and the volatilization factor for soils below one meter
    to ambient air (VF
    samb
    ) have numerical values that are calculated
    using Equations R9 and R11, respectively. Both equations rely on
    input parameters from a variety of sources.
    C)
    The noncarcinogenic risk-based screening level for air (RBSL
    air
    )
    and the volatilization factor for soils below one meter to ambient
    air (VF
    samb
    ) in Equation R8 have numerical values that can be
    calculated using Equations R10 and R11, respectively.
    c)
    Soil Component of the Groundwater Ingestion Exposure Route
    1)
    Equation R12 forms the basis for deriving Tier 2 remediation objectives
    for the soil component of the groundwater ingestion exposure route using
    the RBCA approach. The parameters, groundwater at the source
    (GW
    source
    ) and Leaching Factor (LF
    sw
    ), have numerical values that are
    calculated using Equations R13 and R14, respectively.
    2)
    Equation R13 requires numerical values that are calculated using Equation
    R15.
    3)
    Equation R14 requires numerical values that are calculated using
    Equations R21, R22, and R24. For non-ionizing organics, the Soil Water
    Sorption Coefficient k
    s
    shall be calculated using Equation R20. For
    ionizing organics and inorganics, the values for (k
    s
    ) are listed in Appendix
    C, Tables I and J, respectively. The pH-dependent k
    s
    values for ionizing

     
    32
    organics can be calculated using Equation R20 and the pH-dependent K
    oc
     
    values in Appendix C, Table I. The remaining parameters in Equation
    R14 are field measurements or default values listed in Appendix C, Table
    D.
    d)
    The default value for GW
    comp
    is the Tier 1 groundwater remediation objective.
    For chemicals for which there is no Tier 1 groundwater remediation objective, the
    value for GW
    comp
    shall be the Health Advisory concentration determined
    according to the procedures specified in 35 Ill. Adm. Code 620, Subpart F. As an
    alternative to using the Tier 1 groundwater remediation objectives or Health
    Advisory above concentrations, GW
    comp
    may be developed using Equations R25
    and R26, if approved institutional controls are in place as may be required in
    Subpart J.
    (Source: Amended in R00-19(B) at 24 25 Ill. Reg. _______, effective _______________)
    SUBPART H: TIER 2 GROUNDWATER EVALUATION
    Section 742.805
    Tier 2 Groundwater Remediation Objectives
    a)
    To develop a groundwater remediation objective under this Section that exceeds
    the applicable Tier 1 groundwater remediation objective, or for which there is no
    Tier I groundwater remediation objective, a person may request approval from the
    Agency if the person has performed the following:
    1)
    Identified the horizontal and vertical extent of groundwater for which the
    Tier 2 groundwater remediation objective is sought;
    2)
    Taken corrective action, to the maximum extent practicable to remove
    any free product;
    3)
    Using Equation R26 in accordance with Section 742.810, demonstrated
    that the concentration of any contaminant of concern in groundwater will
    meet:
    A)
    The applicable Tier 1 groundwater remediation objective at the
    point of human exposure; or
    B)
    For any contaminant of concern for which there is no Tier 1
    groundwater remediation objective, the Health Advisory
    concentration determined according to the procedures specified in
    35 Ill. Adm. Code 620, Subpart F at the point of human exposure.
    A person may request the Agency to provide these concentrations
    or may propose these concentrations under Subpart I;
    4)
    Using Equation R26 in accordance with Section 742.810, demonstrated
    that the concentration of any contaminant of concern in groundwater
    within the minimum or designated maximum setback zone of an existing

     
    33
    potable water supply well will meet the applicable Tier 1 groundwater
    remediation objective or, if there is no Tier 1 groundwater remediation
    objective, the Health Advisory concentration determined according to the
    procedures specified in 35 Ill. Adm. Code 620. A person may request the
    Agency to provide these concentrations or may propose these
    concentrations under Subpart I;
    5)
    Using Equation R26 in accordance with Section 742.810, demonstrated
    that the concentration of any contaminant of concern in groundwater
    discharging into a surface water will meet the applicable water quality
    standard under 35 Ill. Adm. Code 302;
    6)
    Demonstrated that the source of the release is not located within the
    minimum or designated maximum setback zone or within a regulated
    recharge area of an existing potable water supply well; and
    7)
    If the selected corrective action includes an engineered barrier as set forth
    in Subpart K to minimize migration of contaminant of concern from the
    soil to the groundwater, demonstrated that the engineered barrier will
    remain in place for post-remediation land use through an institutional
    control as set forth in Subpart J.
    b)
    A groundwater remediation objective that exceeds the water solubility of that
    chemical (refer to Appendix C, Table E for solubility values) is not allowed.
    c)
    The contaminants of concern for which a Tier 1 remediation objective has been
    developed shall be included in any mixture of similar-acting chemicals under
    consideration in Tier 2. The evaluation of 35 Ill. Adm. Code 620.615 regarding
    mixtures of similar-acting chemicals shall be considered satisfied for Class I
    groundwater at the point of human exposure if either of the following
    requirements are achieved:
    1)
    Calculate the weighted average using the following equations:
    a
    CUOx
    a
    CUOx
    CUOx
    CUOx
    ave
    x
    x
    x
    x
    W
    ?
    ?
    ?
    ?
    ?
    ...
    3
    2
    2
    1
    1
    3
      
    where:
    W
    ave
    = Weighted Average
    x
    1
    through x
    a
    =
    Concentration of each individual contaminant at the
    location of concern. Note that, depending on the target organ, the actual
    number of contaminants will range from 2 to 14.
    CUOx
    a
    =
    A Tier 1 or Tier 2 remediation objective must be developed
    for each x
    a
    .

     
    34
    iA)
    If the value of the weighted average calculated in accordance with
    the equations above is less than or equal to 1.0, then the
    remediation objectives are met for those chemicals.
    iiB)
    If the value of the weighted average calculated in accordance with
    the equations above is greater than 1.0, then additional remediation
    must be carried out until the level of contaminants remaining in the
    remediated area have a weighted average calculated in accordance
    with the equation above less than or equal to one; or
    2)
    Divide each individual chemical's remediation objective by the number of
    chemicals in that specific target organ group that were detected at the site.
    Each of the contaminant concentrations at the site is then compared to the
    remediation objectives that have been adjusted to account for this potential
    additivity.
    d)
    The evaluation of 35 Ill. Adm. Code 620.615 regarding mixtures of similar-acting
    chemicals are considered satisfied if the cumulative risk from any contaminant(s)
    of concern listed in Appendix A, Table H, plus any other contaminant(s) of
    concern detected in groundwater and listed in Appendix A, Table F as affecting
    the same target organ/organ system as the contaminant(s) of concern detected
    from Appendix A, Table H, does not exceed 1 in 10,000.
    (Source: Amended in R00-19(B) at 24 25 Ill. Reg. _______, effective _______________)
    Section 742.810
    Calculations to Predict Impacts from Remaining Groundwater
    Contamination
    a)
    Equation R26 predicts the contaminant concentration along the centerline of a
    groundwater plume emanating from a vertical planar source in the aquifer
    (dimensions S
    w
    wide and S
    d
    deep). This model accounts for both three-
    dimensional dispersion (x is the direction of groundwater flow, y is the other
    horizontal direction, and z is the vertical direction) and biodegradation.
    1)
    The parameters in this equation are:
    X =
    distance from the planar source to the location of concern,
    along the centerline of the groundwater plume (i.e., y=0,
    z=0)
    C
    x
    =
    the concentration of the contaminant at a distance X from
    the source, along the centerline of the plume
    C
    source
    =
    the greatest potential concentration of the contaminant of
    concern in the groundwater at the source of the
    contamination, based on the concentrations of contaminants
    in groundwater due to the release and the projected
    concentration of the contaminant migrating from the soil to

     
    35
    the groundwater. As indicated above, the model assumes a
    planar source discharging groundwater at a concentration
    equal to C
    source
    .
    ?
    x
    =
      
    dispersivity in the x direction (i.e., Equation R16)
    ?
    y
    =
      
    dispersivity in the y direction (i.e., Equation R17)
    ?
    z
    =
      
    dispersivity in the z direction (i.e., Equation R18)
    U =
    specific discharge (i.e., actual groundwater flow velocity
    through a porous medium; takes into account the fact that
    the groundwater actually flows only through the pores of
    the subsurface materials) where the aquifer hydraulic
    conductivity (K), the hydraulic gradient (I) and the total
    soil porosity
    ?
    T
    must be known (i.e., Equation R19)
    ?
    =
    first order degradation constant obtained from Appendix C,
    Table E or from measured groundwater data
    S
    w
    =
      
    width of planar groundwater source in the y direction
    S
    d
    =
      
    depth of planar groundwater source in the z direction
    2)
    The following parameters are determined through field measurements: U,
    K, I,
    ?
    T
    , S
    w
    , S
    d
    .
    A)
    The determination of values for U, K, I and
    ?
    T
    can be obtained
    through the appropriate laboratory and field techniques;
    B)
    From the immediate down-gradient edge of the source of the
    groundwater contamination values for S
    w
    and S
    d
    shall be
    determined. S
    w
    is defined as the width of groundwater at the
    source which exceeds the Tier 1 groundwater remediation
    objective. S
    d
    is defined as the depth of groundwater at the source
    which exceeds the Tier 1 groundwater remediation objective; and
    C)
    Total soil porosity can also be calculated using Equation R23.
    b)
    Once values are obtained for all the input parameters identified in subsection (a)
    of this Section, the contaminant concentration C
    x
    along the centerline of the
    plume at a distance X from the source shall be calculated such so that X is the
    distance from the down-gradient edge of the source of the contamination at the
    site to the point where the contaminant concentration is equal to the Tier 1
    groundwater remediation objective or Health Advisory concentration determined
    according to the procedures specified in 35 Ill. Adm. Code 620, Subpart F.

     
    36
    1)
    If there are any potable water supply wells located within the calculated
    distance X, then the Tier 1 groundwater remediation objective or
    concentration shall be met at the edge of the minimum or designated
    maximum setback zone of the nearest potable water supply down-gradient
    of the source. If there are any potable water supply wells located within
    the calculated distance X, then the Tier 1 groundwater remediation
    objective or Health Advisory concentration shall be met at the edge of the
    minimum or designated maximum setback zone of the nearest potable
    water supply down-gradient of the source. If no potable water supply
    wells exist within the calculated distance X, then it can be determined that
    no existing potable water supply wells are adversely impacted. To
    demonstrate that a minimum or maximum setback zone of a potable water
    supply well will not be impacted above the applicable Tier 1 groundwater
    remediation objective or concentration determined according to the
    procedures specified in 35 Ill. Adm. Code 620, Subpart F, X shall be the
    distance from the C
    source
    location to the edge of the setback zone.
    2)
    To demonstrate that no surface water is adversely impacted, X shall be the
    distance from the down-gradient edge of the source of the contamination
    at the site to the nearest surface water body. This calculation must show
    that the contaminant in the groundwater at this location (C
    x
    ) does not
    exceed the applicable water quality standard.
    (Source: Amended in R00-19(B) at 24 25 Ill. Reg. _______, effective ______________)
    SUBPART I: TIER 3 EVALUATION
    Section 742.900
    Tier 3 Evaluation Overview
    a)
    Tier 3 sets forth a flexible framework to develop remediation objectives outside of
    the requirements of Tiers 1 and 2. Although Tier 1 and Tier 2 evaluations are not
    prerequisites to conduct Tier 3 evaluations, data from Tier 1 and Tier 2 can assist
    in developing remediation objectives under a Tier 3 evaluation.
    b)
    The level of detail required to adequately characterize a site depends on the
    particular use of Tier 3. Tier 3 can require additional investigative efforts beyond
    those described in Tier 2 to characterize the physical setting of the site. However,
    in situations where remedial efforts have simply reached a physical obstruction
    additional investigation may not be necessary for a Tier 3 submittal.
    c)
    Situations that can be considered for a Tier 3 evaluation include, but are not
    limited to:
    1)
    Modification of parameters not allowed under Tier 2;
    2)
    Use of models different from those used in Tier 2;

     
    37
    3)
    Use of additional site data to improve or confirm predictions of exposed
    receptors to contaminants of concern;
    4)
    Analysis of site-specific risks using formal risk assessment, probabilistic
    data analysis, and sophisticated fate and transport models (e.g., requesting
    a target hazard quotient greater than 1 or a target cancer risk greater than 1
    in 1,000,000);
    5)
    Requests for site-specific remediation objectives because an assessment
    indicates further remediation is not practical;
    6)
    Incomplete human exposure pathway(s) not excluded under Subpart C;
    7)
    Use of toxicological-specific information not available from the sources
    listed in Tier 2;
    8)
    Land uses which are substantially different from the assumed residential
    or industrial/commercial property uses of a site (e.g., a site will be used for
    recreation in the future and cannot be evaluated in Tiers 1 or 2); and
    9)
    Requests for site-specific remediation objectives which exceed Tier 1
    groundwater remediation objectives so long as the following is
    demonstrated:
    A)
    To the extent practical, the exceedance of the groundwater quality
    standard has been minimized and beneficial use appropriate to the
    groundwater that was impacted has been returned; and
     
    B)
    Any threat to human health or the environment has been
    minimized
    . [415 ILCS 5/58.5(D)(4)(A)]
    d)
    For requests of a target cancer risk ranging between 1 in 1,000,000 and 1 in
    10,000 at the point of human exposure or a target hazard quotient greater than 1 at
    the point of human exposure, the requirements of Section 742.915 shall be
    followed. Requests for a target cancer risk exceeding 1 in 10,000 at the point of
    human exposure are not allowed.
    e)
    Requests for approval of a Tier 3 evaluation must be submitted to the Agency for
    review under the specific program under which remediation is performed. When
    reviewing a submittal under Tier 3, the Agency shall consider
    whether the
    interpretations and conclusions reached are supported by the information
    gathered
    . [415 ILCS 58.7(e)(1)]. The Agency shall approve a Tier 3 evaluation if
    the person submits the information required under this Part and establishes
    through such information that public health is protected and that specified risks to
    human health and the environment have been minimized.

     
    38
    f)
    If contaminants of concern include polychlorinated biphenyls (PCBs), requests for
    approval of a Tier 3 evaluation must additionally address the applicability of 40
    CFR 761.
    (Source: Amended in R00-19(B) at 24 25 Ill. Reg. _______, effective ______________)
    Section 742.925
    Exposure Routes
    Technical information may demonstrate that there is no actual or potential impact of
    contaminants of concern to receptors from a particular exposure route. In these instances, a
    demonstration excluding an exposure route shall be submitted to the Agency for review and
    approval. A submittal under this Section shall include the following information:
    a)
    A description of the route evaluated;
    b)
    Technical support including a discussion of the natural or man-made barriers to
    exposure through that route, and calculations, and modeling results A description
    of the site and physical site characteristics;
    c)
    Physical and chemical properties of contaminants of concern A discussion of the
    result and possibility of the route becoming active in the future; and
    d)
    Contaminant migration properties; Technical support that may include, but is not
    limited to, the following:
    1)
    a discussion of the natural or man-made barriers to that exposure route;
    2)
    calculations and modeling;
    3)
    physical and chemical properties of contaminants of concern; and
    4)
    contaminant migration properties.
    e)
    Description of the site and physical site characteristics; and
    f)
    Discussion of the result and possibility of the route becoming active in the future;
    (Source: Amended in R00-19(B) at 24 25 Ill. Reg. _______, effective ________________)
    SUBPART J: INSTITUTIONAL CONTROLS
    Section 742.1005
    No Further Remediation Letters
    a)
    A No Further Remediation Letter issued by the Agency under 35 Ill. Adm. Code
    732 or 742 740 may be used as an institutional control under this Part if the
    requirements of subsection (b) of this Section are met.

     
    39
    b)
    A request for approval of a No Further Remediation Letter as an institutional
    control shall meet the requirements applicable to the specific program under
    which the remediation is performed.
    (Source: Amended in R00-19(B) at 24 25 Ill. Reg. _______, effective ____________________)
    Section 742.1015
    Ordinances
    a)
    An ordinance adopted by a unit of local government that effectively prohibits the
    installation of potable water supply wells (and the use of such wells) may be used
    as an institutional control to meet the requirements of Section 742.320(d) or
    742.805(a)(3) if the requirements of this Section are met. Ordinances prohibiting
    the installation of potable water supply wells (and the use of such wells) that do
    not expressly prohibit the installation of potable water supply wells (and the use
    of such wells) by units of local government may be acceptable as institutional
    controls if the requirements of this Section are met and a Memorandum of
    Understanding (MOU) is entered into under subsection (i) of this Section.
    b)
    A request for approval of a local ordinance as an institutional control shall
    provide the following:
    1)
    A copy of the ordinance restricting groundwater use certified by an
    official of the unit of local government in which the site is located that it is
    the latest, most current a true and accurate copy of the ordinance, unless
    the Agency and the unit of local government have entered an agreement
    under subsection (i) of this Section, in which case the request may
    alternatively reference the MOU. The ordinance must demonstrate that
    potable use of groundwater from potable water supply wells is prohibited;
    2)
    A scaled map(s) delineating the areal area and extent of groundwater
    contamination (measured or modeled) above the applicable remediation
    objectives including any measured data showing concentrations of
    contaminants of concern in which the applicable remediation objectives
    are exceeded;
    3)
    Information showing the concentration of contaminants of concern in
    which the applicable remediation objectives are exceeded;
    34)
    A scaled map delineating the boundaries of all properties under which
    groundwater is located which exceeds the applicable groundwater
    remediation objectives;
    45)
    Information identifying the current owner(s) of each property identified in
    subsection (b)(4) (b)(3) of this Section; and
    56)
    A copy of the proposed submission of the information to the current
    owners identified in subsection (b)(5) (b)(4) of this Section of the
    information required in subsections (b)(1) through (b)(5) (b)(4) of this

     
    40
    Section and proof that the notification required in subsection (c) of this
    Section has been submitted. Within 45 days from the date the Agency's
    Nno Ffurther Rremediation determination is recorded, the person who
    requested to use the ordinance as an institutional control must submit
    proof to the Agency of the notice to the property owners identified in
    subsection (b)(4).
    c)
    Each of the property owners identified in subsection (b)(5) (b)(4) of this Section
    and the unit of local government must receive written notification from the party
    desiring to use the institutional control that groundwater remediation objectives
    have been approved by the Agency. Written proof of this notification shall be
    submitted to the Agency within 45 days from the date of the instrument
    memorializing the Agency’s no further remediation determination is recorded.
    The notification shall include:
    1)
    The name and address of the unit of local government;
    2)
    The citation to the ordinance;
    3)
    A description of the property being sent notice by adequate legal
    description or by reference to a plat showing the boundaries;
    4)
    A statement that the ordinance restricting groundwater use has been used
    by the Agency in reviewing a request for a groundwater remediation
    objective;
    5)
    A statement as to the nature of the release and response action with the site
    name, address, and Agency site number or Illinois inventory identification
    number; and
    6)
    A statement as to where more information may be obtained regarding the
    ordinance.
    d)
    Unless the Agency and the unit of local government have entered into a MOU
    under subsection (i) of this Section, the current owner or successors in interest of
    a site who have received approval of use of an ordinance as an institutional
    control under this Section shall:
    1)
    Monitor activities of the unit of local government relative to variance
    requests or changes in the ordinance relative to the use of potable
    groundwater at properties identified in subsection (b)(4) (b)(3) of this
    Section; and
    2)
    Notify the Agency of any approved variance requests or ordinance
    changes within 30 days after the date such action has been approved.
    e)
    The information required in subsections (b)(1) through (b)(6) (b)(5) of this
    Section and the Agency letter approving the groundwater remediation objective

     
    41
    shall be submitted to the unit of local government. Proof that the information has
    been filed with the unit of local government shall be provided to the Agency.
    f)
    Any ordinance or MOU used as an institutional control pursuant to this Section
    shall be recorded in the Office of the Recorder or Registrar of Titles of the county
    in which the site is located together with the instrument memorializing the
    Agency's no further remediation determination pursuant to the specific program
    within 45 days after receipt of the Agency's no further remediation determination.
     
    g)
    An institutional control approved under this Section shall not become effective
    until officially recorded in accordance with subsection (f) of this Section. The
    person receiving the approval shall obtain and submit to the Agency within 30
    days after recording a copy of the institutional control demonstrating that it has
    been recorded.
    h)
    The following shall be grounds for voidance of the ordinance as an institutional
    control and the instrument memorializing the Agency's no further remediation
    determination:
    1)
    Modification of the ordinance by the unit of local government to allow
    potable use of groundwater;
    2)
    Approval of a site-specific request, such as a variance, to allow potable
    use of groundwater at a site identified in subsection (b)(4) (b)(3) of this
    Section; or
    3)
    Violation of the terms of an institutional control recorded under Section
    742.1005 or Section 742.1010.
    i)
    The Agency and a unit of local government may enter into a MOU under this
    Section if the unit of local government has adopted an ordinance satisfying
    subsection (a) of this Section and if the requirements of this subsection are met.
    The MOU shall include the following:
    1)
    Identification of the authority of the unit of local government to enter the
    MOU;
    2)
    Identification of the legal boundaries, or equivalent, under which the
    ordinance is applicable;
    3)
    A certified copy of the ordinance;
    4)
    A commitment by the unit of local government to notify the Agency of
    any variance requests or proposed ordinance changes at least 30 days prior
    to the date the local government is scheduled to take action on the request
    or proposed change;

     
    42
    5)
    A commitment by the unit of local government to maintain a registry of all
    sites within the unit of local government that have received no further
    remediation determinations pursuant to specific programs; and
    6)
    If the ordinance does not expressly prohibit the installation of potable
    water supply wells (and the use of such wells) by units of local
    government, a commitment by the unit of local government:
    A)
    To review the registry of sites established under subsection (i)(5)
    of this Section prior to siting potable water supply wells within the
    area covered by the ordinance;
    B)
    To determine whether the potential source of potable water may be
    or has been affected by contamination left in place at those sites;
    and
    C)
    To take whatever steps are necessary to ensure that the potential
    source of potable water is protected from the contamination or
    treated before it is used as a potable water supply.
    (Source: Amended in R00-19(B) at 24 25 Ill. Reg. _______, effective ____________________)
    Section 742.1020
    Highway Authority Agreements
    a)
    An agreement with a highway authority may be used as an institutional control
    where the requirements of this Section are met and the Agency has determined
    that no further remediation is required as to the property(ies) to which the
    agreement is to apply.
    b)
    As part of the agreement the highway authority shall agree to:
    1)
    Prohibit the use of groundwater under the highway right of way that is
    contaminated above residential Tier 1 remediation objectives from the
    release as a potable supply of water; and
    2)
    Limit access to soil contamination under the highway right of way that is
    contaminated above residential Tier 1 remediation objectives from the
    release. Access to soil contamination may be allowed if, during and after
    any access, public health and the environment are protected.
    c)
    The agreement shall provide the following:
    1)
    Fully executed signature blocks by the highway authority and the owner of
    the property (or, in the case of a petroleum leaking underground storage
    tank, the owner or operator of the tank) from which the release occurred;
    2)
    A scaled map delineating the area and extent of soil and groundwater
    contamination above the applicable Tier 1 remediation objectives or a

     
    43
    statement that either soil or groundwater is not contaminated above the
    applicable Tier 1 residential remediation objectives;
    3)
    Information showing the concentration of contaminants of concern within
    the zone in which the applicable Tier 1 remediation objectives are
    exceeded;
    4)
    A stipulation of the information required by subsections (b) (c)(2) and (3)
    of this Section in the agreement if it is not practical to obtain the
    information by sampling the highway right-of-way; and
    5)
    Information identifying the current fee owner of the highway right-of-way
    and highway authority having jurisdiction.
    d)
    Highway Authority Agreements must be referenced in the instrument that is to be
    recorded on the chain of title for the remediation property.
    ed)
    Violation of the terms of an Agreement approved by the Agency as an
    institutional control under this Section shall be grounds for voidance of the
    Agreement as an institutional control and the instrument memorializing the
    Agency's no further remediation determination.
    f)
    Failure to provide all of the information required in subsections (b) and (c) of this
    Section will be grounds for denial of the hHighway aAuthority aAgreement as an
    institutional control.
    (Source: Amended in R00-19(B) at 24 25 Ill. Reg. _______, effective ____________________)
    SUBPART K: ENGINEERED BARRIERS
    Section 742.1105
    Engineered Barrier Requirements
    a)
    Natural attenuation, access controls, and point of use treatment shall not be
    considered engineered barriers. Engineered barriers may not be used to prevent
    direct human exposure to groundwater without the use of institutional controls.
    b)
    For purposes of determining remediation objectives under Tier 1, engineered
    barriers are not recognized.
    c)
    The following engineered barriers are recognized for purposes of calculating
    remediation objectives that exceed residential remediation objectives:
    1)
    For the soil component of the groundwater ingestion exposure route, the
    following engineered barriers are recognized if they prevent completion of
    the exposure pathway:

     
    44
    A)
    Caps, covering the contaminated media, or walls constructed of
    compacted clay, asphalt, concrete or other material approved by
    the Agency; and
    B)
    Permanent structures such as buildings and highways.
    2)
    For the soil ingestion exposure route, the following engineered barriers are
    recognized if they prevent completion of the exposure pathway:
    A)
    Caps, covering the contaminated media, or walls, constructed of
    compacted clay, asphalt, concrete, or other material approved by
    the Agency;
    B)
    Permanent structures such as buildings and highways; and
    C)
    Clean soil, covering the contaminated media, that is a minimum of
    three feet in depth.
    C)
    Soil, sand, gravel, or other geologic materials that:
    i)
    Cover the contaminated media;
    ii)
    Meet the soil remediation objectives under Subpart E for
    residential property for contaminants of concern; and
    iii)
    Are a minimum of three feet in depth.
    3)
    For the inhalation exposure route, the following engineered barriers are
    recognized if they prevent completion of the exposure pathway:
    A)
    Caps, covering the contaminated media, or walls constructed of
    compacted clay, asphalt, concrete, or other material approved by
    the Agency;
    B)
    Permanent structures such as buildings and highways; and
    C)
    Clean soil covering the contaminated media, that is a minimum of
    ten feet in depth and not within ten feet of any manmade pathway.
    C)
    Soil, sand, gravel, or other geologic materials that:
    i)
    Cover the contaminated media;
    ii)
    Meet the soil remediation objectives under Subpart E for
    residential property for contaminants of concern; and
    iii)
    Are a minimum of ten feet in depth and not within ten feet
    of any manmade pathway.

     
    45
    4)
    For the ingestion of groundwater exposure route, the following engineered
    barriers are recognized if they prevent completion of the exposure
    pathway:
    A)
    Slurry walls; and
    B)
    Hydraulic control of groundwater.
    d)
    Unless otherwise prohibited under Section 742.1100, any other type of engineered
    barrier may be proposed if it will be as effective as the options listed in subsection
    (c) of this Section.
    (Source: Amended in R00-19(B) at 24 25 Ill. Reg. _______, effective ____________________)

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