ILLINOIS POLLUTION CONTROL BOARD
    July 18, 1996
    IN THE MATTER OF:
    )
    )
    TRIENNIAL WATER QUALITY REVIEW: ) R94-1 (B)
    AMENDMENTS TO 35 ILL. ADM. CODE ) (Rulemaking - Water)
    302.202, 302.212, 302.213, 304.122 and )
    304.301 (Ammonia Nitrogen) )
    Proposed Rule. First Notice.
    OPINION AND ORDER OF THE BOARD (by E. Dunham, C.A. Manning and R.C.
    Flemal):
    This matter comes before the Board on a regulatory proposal filed on February 24,
    1994 by the Illinois Environmental Protection Agency (Agency). The Agency filed the
    proposal as part of its mandatory review of the applicable water quality standards of the State
    of Illinois pursuant to 33 U.S.C. §§ 1251-1387 (1987).
    1
    On January 4, 1996, the Board severed the docket into subdockets A & B. Subdocket
    (A) contains the amendments proposed by the Agency for lead and mercury (Sections 302.208
    and 302.407).
    2
    Subdocket (B) contains the amendments proposed by the Agency for ammonia
    nitrogen (Sections 302.202, 302.212, 302.213, 304.122 and 304.301). The Board today
    proposes the amendments to the ammonia nitrogen standards for first notice.
    The Board's responsibility in this matter arises from the Environmental Protection Act
    (Act) (415 ILCS 5/1 et. seq. (1994)). The Board is charged therein to "determine, define, and
    implement the environmental control standards applicable in the state of Illinois." (415 ILCS
    5/5(b) (1994).) More generally, the Board's rulemaking charge is based on the system of
    checks and balances integral to the Illinois environmental governance: the Board bears
    responsibility for the rulemaking and principal adjudicatory functions; the Agency has primary
    responsibility for administration of the Act and the Board's regulations. The latter includes
    administering today's proposed amendments.
    PROCEDURAL HISTORY
    1
    The Federal Water Pollution Control Act, commonly known as the Clean Water Act (CWA), §§
    101-607 requires the Agency to periodically, but at least every three years, review the water quality
    standards applicable in the State. This review is commonly referred to as the "triennial review".
    2
    The amendments in Subdocket (A) were adopted by the Board on May 16, 1996 and
    published at 20 Ill. Reg. 7682.

    2
    The major portion of today's proposed
    amendments were filed by the Agency
    pursuant to Section 27 of the Environmental Protection Act and the Board's procedural rules at
    35 Ill. Adm. Code §§ 102.120 and 102.121.
    Pursuant to Section 28.2 of the Act and the Board's procedural rules at 35 Ill. Adm.
    Code § 102.121(e), the Agency initially contended that today's rulemaking is needed to fulfill
    the requirements of the Federal Clean Water Act (CWA), and therefore is required pursuant to
    federal law. Nevertheless, the Agency's certification regarding the required nature of the
    amendments cited to only part of the proposal and, moreover, did not include a written
    confirmation letter from the United States Environmental Protection Agency (USEPA). Based
    on these deficiencies in the Agency's original certification, the Board by order of March 17,
    1994, found that it had not been shown that the amendments as proposed were federally-
    required.
    On April 11, 1994, the Agency filed a motion requesting that the Board reconsider its
    March 17, 1994 order. The Agency certified that the entire rulemaking is federally required.
    Additionally, the Agency attached a confirmation letter from USEPA Region V stating that the
    proposed changes for the lead, mercury, and ammonia standards would address inconsistencies
    between current State law and the CWA. The confirmation letter also observed that the
    proposal would be consistent with the CWA and federal regulations. By order of May 5, 1994
    the Board granted the Agency's motion for reconsideration and accepted the Agency proposal
    as a federally-required rule pursuant to Section 28.2 of the Act.
    By order of September 15, 1994, the Board adopted the Agency's proposal for
    purposes of first notice, pursuant to Section 5.01 of the Illinois Administrative Procedure Act.
    (415 ILCS 100/1005-40). The Board adopted the proposal without making substantive
    comment on the merits of the proposal. First notice publication occurred in the Illinois
    Register on September 30, 1994 at 18 Ill. Reg. 14555 (Part 302) and 18 Ill. Reg. 14549 (Part
    304). The Illinois Administrative Procedure Act requires that adoption of the rule occur
    within one year of the first notice publication. (5 ILCS 5/40(e) (1994).) As the one-year time
    period has already elapsed, the Board sends the amendments proposed in this docket back to
    first notice.
    Three public hearings were held before hearing officer Diane O'Neill on Docket R94-
    1: on November 10, 1994 (Tr1.) in Chicago, Illinois; on November 22, 1994 (Tr2.) in
    Springfield, Illinois; and on January 26, 1995 (Tr3.) in Chicago, Illinois. Additional hearings
    were held in Docket R4-1(B) on February 22 and 23, 1996 (Tr4. and Tr5.) in Chicago,
    Illinois. At these hearings the Board received testimony in support of the proposal from the
    Agency, as well as testimony on various aspects of the proposal from interested persons.
    At the completion of each set of hearings the Board opened a short comment period. In
    response to a public comment from the Chemical Industry Council, the Board extended the
    comment period to allow participants to comment on the possible effect that an anticipated
    paper from USEPA Region VIII concerning ammonia nitrogen could have on this proceeding.

    3
    After reviewing those comments the Board
    finds no reason to delay the adoption of the
    proposed amendments until after the paper on ammonia nitrogen is issued by USEPA Region
    VIII.
    On June 1, 1995, the Agency filed a "Motion to Correct a Typographical Error". The
    Agency requested that the Board correct a typographical error in Section 302.213 of the
    proposed regulations and allow a short comment period to allow the regulated community to
    respond to this correction. The Board granted the motion and allowed participants to file
    comments on the correction until July 7, 1995. The Board allowed the Agency until July 14,
    1995 to file a response to any comments. The Board did not receive any comments on the
    correction. However, this motion is moot because the Agency has submitted a revised
    proposal which further modifies the language of Section 302.213.
    OVERVIEW OF THE PROPOSAL
    The Board today proposes adoption of amendments to the ammonia nitrogen general
    use water quality standards as proposed by the Agency. The Board proposes the amendments
    as submitted by the Agency in its public comment. (PC #8(B) Exhibit BB). While some of the
    language and numbers have been changed from the original proposal the general concepts have
    not changed. The following is a summary of the proposed amendments filed by the Agency.
    Ammonia: General Use Water Quality Standard
    The Board currently has General Use Water Quality Standards for (total) ammonia
    nitrogen and un-ionized ammonia nitrogen found at 35 Ill. Adm. Code 302.212.
    By today's action the Board proposes, in agreement with the Agency's
    recommendations, to reconstitute much of Section 302.212 for the purposes of adding clarity
    to the section and of incorporating up-dated information on the effects of pH and temperature
    on ammonia toxicity.
    Effluent Modified Waters (Ammonia)
    Today's newly proposed Section 302.213 defines and gives the Agency authority to
    identify Effluent Modified Waters (EMW). An EMW consists of waters downstream from an
    effluent outfall that have the potential to exceed the chronic standard (CS) for ammonia.
    Ammonia Effluent Standard Exemption Process
    Today's proposal reorganizes that portion of the Board's effluent regulations that
    provide for exception from the prohibition against causing or contributing to a violation of the
    ammonia water quality standards. The existing exception procedure at 35 Ill. Adm. Code
    304.301 is proposed for repeal, and new subsections 304.122(c) and (d) are proposed for
    addition.

    4
    Conforming and Housekeeping Amendments
    There are several places in the sections which are today opened for other purposes
    where housekeeping corrections are in order. Among these are updating citations to the
    Illinois Compiled Statues to the current (1994) edition and changing the abbreviation of the
    word "liter" from "l" to "L".
    PROPOSAL OF "THE CITIES"
    On December 8, 1994, the Cities of Batavia, Geneva, Moline, St. Charles, Sterling and
    Rock Falls (the Cities or Ammonia Group) filed proposed amendments and a statement of
    reason. The proposal raises concerns by the Cities on the implementation of the standards and
    the arbitrary, calendar cut-off dates for the summer and winter standards. The Cities propose
    amendments to the proposal to ensure that the standards are implemented in a manner which
    takes actual instream conditions into consideration to the maximum extent practicable. The
    proposed amendments require the gathering of monitoring data to determine whether there is a
    water quality problem. If a problem is detected, the discharger would be required to remedy
    the problem.
    The proposal by the Cities recommends that dischargers be allowed a year to upgrade
    facilities to ensure that best degree treatment is being provided. The discharger would than
    conduct a one year monitoring program to detect possible water violations. If any violations
    are detected, the discharger would develop an appropriate compliance schedule to bring the
    facility into compliance. Under the Cities’ proposal, existing permit limits would remain in
    effect while data is being collected.
    The Cities also suggest that the proposal allow for the use of actual data to demonstrate
    that an exceedence of the winter water quality standard would not be in violation if the
    instream temperature is greater than 12°C at the time of the exceedence. The Cities agree that
    it is impractical to base the winter standard solely on temperature since the temperature of
    many waterways is not monitored. However, the Cities believe that when temperature data is
    available, the temperature should be used to determine the allowable ammonia level.
    A response to this proposal was filed on behalf of the Sierra Club, Trout Unlimited,
    Citizens for a Better Environment, Lake Michigan Federation and Friends of the Chicago
    River on January 13, 1995. The response maintains that the proposal of the Cities should be
    rejected because it attempts to carve out special rules for determining effluent limits for
    ammonia without any showing that the rules for determining effluent limits for ammonia
    should be any weaker. In fact, the response argues, that the current procedures for
    determining effluent limits probably is not strict enough to prevent acute and chronic toxicity
    under critical conditions. The response also states that the Cities proposal fails to spell out the
    details of the monitoring program.

    5
    HEARING RECORD
    In addition to extensive documentation in support of the proposed amendments, the
    Agency has presented the testimony, both in prefiled testimony and at hearing,
    3
    of Joel Cross,
    Manager of the Planning Section of the Agency's Division of Water Pollution Control; Robert
    G. Mosher, Supervisor of the Standards and Monitoring Support Unit, Planning Section of the
    Agency's Division of Water Pollution Control; and Dean J. Studer, Environmental Protection
    Engineer at the Division of Water Pollution Control.
    Agency Witnesses - Cross at November 10, 1994 Hearing
    Mr. Cross testified to the general need for the State of Illinois to regularly review its
    water quality standards as part of the triennial review process. (Tr1. at 16-17.)
    Mr. Cross also testified to the particular need to update the Board's ammonia water
    quality standards. He noted that the last update of these standards was undertaken in 1982,
    and there have been significant advancements in the derivation of ammonia water quality
    standards since that time. (Cross at 1-2.) Among these has been the development of a National
    Criteria Document (NCD) for ammonia.
    4
    (Cross at 6.) Mr. Cross observed that the Agency
    has reviewed this document and later studies in an attempt to determine what levels of
    ammonia would be protective of native and aquatic life under stream conditions found in
    Illinois. (Id. at 2.) On the basis of this review the Agency has recommended to the Board,
    ammonia standards that are less restrictive than the ammonia NCD values, but which the
    Agency finds are protective of the native and resident species in Illinois General Use Waters.
    (Id. at 3.)
    Mr. Cross further testified to the rationale behind the proposed ammonia exemption
    process and the EMW concept. Mr. Cross observed:
    An additional goal of the standards review process was to identify the
    compliance abilities of wastewater plants designed to remove ammonia from
    effluent using a nitrification stage of treatment. These treatment plants could
    not consistently produce effluents that met existing ammonia water quality
    standards during the winter months and were formerly given winter effluent
    limitations based on the facility's ability to treat ammonia. Resurrecting an
    exemption approach for facilities demonstrating the best degree of treatment
    currently recognized as economically reasonable, is necessary to rectify the
    disparity between protective water quality standards and technical feasibility.
    3
    For the purposes of citation herein, the prefiled testimonies are cited according to author and page
    (e.g., Mosher at ___) or to Exhibit number (Exh.) and hearing transcripts are cited according to
    hearing number and page (e.g., Tr1. at __).
    4
    This document is Exhibit E to the Agency's proposal of February 24, 1994.

    6
    Such an exemption must be based on
    design standards for nitrification, the
    use attainment of receiving waters and the actual performance of individual
    facilities. To accommodate the disparity between technical feasibility and the
    devised water quality standards, a new regulatory concept for some receiving
    streams is proposed. Effluent modified waters would be designated where the
    best reasonable treatment has been provided but chronic ammonia standards in
    the low dilution receiving stream may not be met. (Cross at 3-4.)
    Finally, Mr. Cross observed that prior to approaching the Board with the instant
    proposal the Agency had consulted various interested persons regarding the content of the
    proposal. Among these was the USEPA, with whom "many hours of negotiation" were spent.
    (Cross at 4.) Mr. Cross contends that, although this process "added many months to the time
    needed to bring [the Agency's] petition to the Board", it was necessary to insure the eventual
    viability of the proposal. (Id. at 4.)
    Agency Witnesses - Mosher at November 10, 1994 Hearing
    The testimony of Mr. Mosher focused on the technical justification for the proposed
    new water quality standards and on the anticipated economic impact of the new water quality
    standards. The largest portion of Mr. Mosher's testimony focused on the technical
    justification for the proposed ammonia water quality standards. Mr. Mosher characterizes the
    central theme of the ammonia standard as a "not to be exceeded" value of 0.04 mg/L un-
    ionized ammonia, applicable outside of a designated mixing zone. (Mosher at 1.)
    Un-ionized ammonia (NH
    3
    ) is regulated because it is the toxic component of ammonia
    in aqueous solutions where it forms an equilibrium with the relatively non-toxic ammonium
    (NH
    4
    +
    ) ion. (Mosher at 2.) Together un-ionized and ionized ammonia are referred to as total
    ammonia. (Mosher at 2.) The Agency recognizes the well documented relationship between
    pH, temperature and ammonia. (Mosher at 2.) As pH and temperature increase, the
    proportion of un-ionized ammonia also increases. (Mosher at 2.)
    The Agency contends that the current standard (no single sample may exceed 0.04
    mg/L un-ionized ammonia) results in an over-protective chronic standard because this
    concentration of un-ionized ammonia would only be toxic to Illinois organisms over a long
    period of exposure. (Mosher at 2.) In addition, the Agency believes that there is a problem
    with the current standard of allowing ammonia levels of 1.5 mg/L regardless of the un-ionized
    concentration present. (Mosher at 2.) The Agency contends that studies have shown that this
    level is not always protective of aquatic life. (Mosher at 2.)
    The ammonia NCD provided important toxicology data and concepts used by the
    Agency in developing the proposed ammonia water quality standards. (Mosher at 8.) These
    contributions include: 1) a two number standard allowing implementation based on exposure
    period, 2) a wholly toxicity based approach allowing for protection of aquatic life, and 3) a

    7
    comprehensive compilation of ammonia
    toxicity literature. (Mosher at 8.) Other
    concepts contained in the NCD were determined to be unjustified for use in Illinois. (Mosher
    at 8.)
    The Agency recognizes that a large number of wastewater treatment plants will be
    unable to meet the proposed water quality standards for ammonia even after providing the best
    degree of treatment. (Mosher at 15.) These facilities discharge to receiving streams with little
    or no permanent upstream flow to provide dilution for ammonia bearing effluents and cannot
    be expected to meet the proposed water quality standards. (Mosher at 15.) Proposed Section
    302.213 creates a category of waters (effluent modified waters) that would not have an
    applicable ammonia standard other than the 15 mg/L total ammonia limit of Section
    302.212(a) and the acute standard of subsection (b). (Mosher at 15.) This provision affords
    relief to dischargers meeting the Agency's concept of best degree of treatment. (Mosher at 15.)
    The Agency sees no alternative but to recognize the limitations of available technologies to
    remove ammonia by proposing the subcategory of effluent modified waters. (Mosher at 17.)
    The Agency believes that recognition of the ammonia situation will serve to fully inform the
    public concerning use attainment; however, it will not cause standards to be exceeded or
    degradation to occur from increased loading or new discharges to highly valued waters.
    (Mosher at 18.)
    Mr. Mosher's final area of testimony was directed to the Agency's analysis of the
    probable economic impact of adoption of the proposed new standards. (Mosher at 28-38.) Mr.
    Mosher observed that it is the Agency's belief that adoption of the proposed ammonia water
    quality standards would carry economic consequences for a number of individual dischargers.
    In particular, Mr. Mosher identified a list of major municipal wastewater dischargers that the
    Agency believed would need to upgrade existing ammonia treatment so as not to cause or
    contribute to a violation of the ammonia standards as proposed. (Exh. 4, Agency Exh. S.)
    The Agency maintains that any evaluation of the impact of the proposed ammonia
    standards must be done on a facility specific basis. (Mosher at 29.) There are 181 municipal
    dischargers with a design average flow of 1 mgd or greater in Illinois. (Mosher at 30.) The
    Agency's research found that 115 of the 181 major municipal dischargers have permit limits of
    1.5 and 4.0 and would not be impacted by the proposed amendments. (Mosher at 30.)
    Dischargers to the Mississippi, Ohio and Wabash Rivers have adequate dilution available to
    comply with the new standards and therefore will not be impacted by the proposed
    amendments. (Mosher at 31.) The Illinois River has unique ammonia standards that are not
    impacted by this rulemaking. (Mosher at 31.) Some smaller major dischargers to the
    Kaskaskia, Kankakee and Rock Rivers have not had ammonia limits in their NPDES permits
    because of the available dilution and will not be impacted by the proposed standards. (Mosher
    at 31.) Five of the 181 facilities discharge to secondary contact waters which are not affected
    by the proposed standards. (Mosher at 31.) Nine dischargers were identified that discharge to
    low dilution receiving waters but do not have nitrification facilities. (Mosher at 31.) Several
    of these facilities are working toward compliance while one has a site-specific exemption from
    the Board. (Mosher at 31.) The Agency contends that compliance with the new standard for

    8
    these facilities will be no more expensive than
    compliance with the existing standards and
    therefore did not include these costs in its economic analysis. (Mosher at 31.)
    The Agency identified 19 facilities
    5
    that were at risk of noncompliance under the
    proposed standards. (Mosher at 32.) Nine of the identified facilities cannot meet the 30 day
    average ammonia concentrations to allow compliance with the chronic standard. (Mosher at
    32.) The Agency contends that an investigation of some of the facilities would find that minor
    changes in operation could bring about some degree of nitrification and allow compliance with
    the new standards. (Mosher at 32.) However, the Agency is fairly certain that most of the
    identified facilities will have to be partially redesigned to meet the proposed standards.
    (Mosher at 32.)
    The Agency estimated the costs for complete nitrification at the nine facilities identified
    as not being able to meet the 30 day ammonia concentrations at $32,420,000.
    6
    (Mosher at
    34.) The Agency maintains that this represents the worst-case estimate of costs. (Mosher at
    34.) The Agency maintains that actual costs could be substantially less because many of the
    facilities will not have to institute changes of the magnitude figured into the estimate. (Mosher
    at 34.)
    The remaining ten facilities can meet thirty day averages, but can not meet daily
    maximum limits as required by the acute standards. (Mosher at 36.) Compliance at these
    facilities may be possible through advanced modeling of the zone of dilution, the construction
    of a high rate diffuser, or changes in management of the process. (Mosher at 36.)
     
    The Agency has not studied the impact of the proposed amendments on minor
    municipal dischargers which number approximately 600. (Mosher at 35.) The Agency
    believes that a smaller proportion of these facilities will require modifications due to higher
    dilution ratios for the smaller facilities. (Mosher at 35.) The Agency also recognizes the
    possible impact on industrial dischargers but believes that the incidence of discharges
    containing significant ammonia are much less common among industrial dischargers. (Mosher
    at 35.)
    The Agency maintains that the conclusions of its economic impact study will be
    impacted by changing conditions such as population growth and decline, physical and chemical
    5
    The Agency originally identified 20 facilities but later removed the Libertyville facility from the
    list because the facility had completed construction of an expanded facility which provided more
    efficient ammonia removal. (Tr2. at 12.)
    6
    The original figure provided by the Agency of $35,720,000 was reduced by 3.3 million to reflect
    the removal of the Libertyville facility from the list of impacted facilities. (Tr2. at 12.) This cost
    estimate was further reduced by the Agency at subsequent hearings due to additional information
    that was obtained about some of the facilities. (Exh. 41 at 38.) The Agency estimates the cost for
    compliance for these facilities at $20,000,000.00. (Exh. 41 at 38; See page 14 of this opinion.)

    9
    features of the waterbodies, and improvements
    in technology. (Mosher at 37.) The Agency
    asserts that the need for compliance action by municipal dischargers will be made during the
    application process for individual NPDES permits. (Mosher at 37.)
    Agency Witnesses - Studer at November 10, 1994 Hearing
    The Agency's final witness, Mr. Studer, focused his testimony on the technologies
    available for removing ammonia from wastewater. He testified that there are two categories of
    treatment technologies for nitrogen; nitrification which is the oxidation of ammonia to form
    nitrates and denitrification which is the removal of nitrogen containing components by
    conversion to nitrogen gas. (Studer at 1-2.) The technologies reviewed by Mr. Studer include
    breakpoint chlorination, ammonia stripping, ion exchange, reverse osmosis, and biological
    removal technologies (lagoons, recirculating sand filters, algal harvesting, wetland utilization
    and land application). (Studer at 2 -7) He testified that conventional biological treatment, the
    treatment of sewage to establish a population of nitrifying bacteria, is capable of achieving
    monthly average ammonia concentrations in the effluent for domestic wastewater of 1.5 mg/L
    from April through October, and 4.0 mg/L from November through March. (Tr1. at 25.)
    Mr. Studer also explained the establishment of effluent modified waters (EMW).
    EMWs are waters downstream from a wastewater treatment facility that, at a minimum, can
    comply with a summer monthly average of 1.5 mg/L (total ammonia as N) during all months
    from April through October and a winter monthly average of 4.0 mg/L (total ammonia as N)
    during all months from November through March, yet cannot consistently comply with the
    chronic ammonia water quality standard. (Studer at 13.) EMWs will continue downstream of
    the facility, the distance that it takes for the chronic ammonia water quality standard to be met
    on a consistent basis. (Studer at 13.) Waters showing aquatic life impairment from ammonia
    will not be listed as EMWs. (Studer at 14.) Facilities which cannot consistently meet the
    monthly averages of 1.5 mg/L or 4.0 mg/L will not be considered for EMW status, but will
    generally be required to modify the facility. (Studer at 14.)
    Additional Testimony from Hearings on November 10 and 22, 1994
    James Daugherty from the Illinois Association of Wastewater Agencies (IAWA)
    testified on behalf of the members of that association. IAWA supports the numbers proposed
    by the Agency but believes that additional data is needed. (Daugherty at 1.) IAWA urges that
    additional studies be performed before the next proposal on ammonia standards. (Daugherty at
    1.) In its testimony IAWA stated that it endorsed the need for a study to define the effects of
    ammonia, supports the adoption of a factor of three in the averaging rule, and endorses the
    setting of higher effluent limits for individual facilities. (Daugherty at 8.) IAWA recommends
    the adoption of the proposed regulations with comments on the application of ammonia action
    levels for the implementation of effluent modified waters. (Daugherty at 8.) IAWA also
    believes that the implementation policy should allow individual dischargers to use models other
    than the mass balance calculation. (Tr3. at 262.)

    10
    Jim Mick from the Illinois Department
    of Conservation (IDOC)
    7
    testified that Illinois
    anglers spend more than 11,600,000 days annually fishing in Illinois and impact Illinois'
    economy by over $870 million. (Mick at 1.) IDOC maintains that protection of Illinois
    streams, which provide the last available habitat for some 78 endangered and threatened
    aquatic species, is important to preserve the biodiversity of Illinois' natural resources. (Mick at
    1.) IDOC believes that removal of the 1.5 mg/L total ammonia floor is an improvement in the
    water quality standards for Illinois streams but using the actual un-ionized ammonia levels as
    the standard would provide better protection. (Mick at 1.)
    IDOC notes that no guidelines or criteria are proposed to protect the highly valued
    streams from potential degradation. (Mick at 1.) IDOC contends that the ammonia toxicity
    may effect early life stages of fish. (Mick at 1.) IDOC claims that ammonia related toxicity
    effects are not always apparent and could be deleterious to native fish populations. (Mick at 1.)
    IDOC recommends that stream basins designated as "A" or "B"
    8
    be protected from
    lower water quality than currently exists. (Mick at 2.) IDOC observes that there is a lack of
    warm water stream species toxicity data. (Mick at 2.) IDOC recommends that the Board be
    cautious and err in favor of the aquatic natural resources, until more definitive data from
    research is collected. (Mick at 2.) IDOC recommends that streams which are annually stocked
    with trout be protected from lowered water quality standards. (Mick at 2.)
    Bob Evans, the Executive Director of the Water and Sewer Commission in Freeport,
    Illinois, testified on the previous expenditures incurred by the City of Freeport due to changes
    in chlorination in its permit and changes in sludge regulations. (Tr2. at 118.) He also states
    that the lowest ammonia level measured in the Pecatonica River, to which Freeport discharges,
    is 0.4 mg/L. (Tr2. at 119.) He contends that the level of ammonia in the River is due to
    agricultural runoff. (Tr2. at 120.) He concludes that the proposed regulations would require
    Freeport to expend additional money to treat its water for ammonia with no beneficial effect
    on the receiving stream. (Tr2. at 120.)
    Testimony from Hearing on January 26, 1995
    At the third hearing on January 26, 1995, testimony was presented by Mary Ross on
    behalf of the Sierra Club. Ms. Ross stated that the Sierra Club believes that the proposed
    ammonia standard is not strong enough because it does not consider cold water species. (Ross
    7
    The IDOC has been reorganized and is now part of the Department of Natural Resources.
    8
    The designation of the stream basins is provided in "Biological Stream Characterization: A
    Biological Assessment of Illinois Stream Quality" which was submitted as public comment #5 by
    the IDOC.

    11
    at 1.) The Sierra Club also supports the
    adoption of standards for zinc, selenium,
    nickel and phosphorous. (Ross at 3.)
    Edward Michael testified on behalf of Trout Unlimited that the underlying assumptions
    that prompted the Agency's action are basically invalid. (Michael at 1.) Trout Unlimited
    supports adoption of water quality standards consistent with USEPA's national criteria
    document. (Michael at 2.) Trout Unlimited contends that an acceptable proposal should
    protect the most sensitive species and provide an exemption for waters which cannot contain
    those species. (Michael at 2.) Trout Unlimited believes that the proposed rule fails to provide
    for the preservation of the integrity of aquatic habitat in Illinois which is known to be or to
    have been utilized by salmonids. (Michael at 2.)
    Mayors from the cities of St. Charles, Geneva, Batavia, Sterling, Rock Falls, Dixon
    and Moline (Mayors) presented statements at the third hearing. The Mayors testified that they
    support the use of ammonia standards as a means to protect the quality of the waterways but
    object to the limited amount of information used by the Agency in deriving the standards.
    (Tr3. at 28.) The Mayors support the alternate proposal submitted by the Cities as a means to
    allow dischargers to optimize their ammonia treatment capabilities and determine where the
    standards are being achieved. (Tr3. at 26.) The Mayors observe that the Agency has
    acknowledged that it does not have any actual water quality data or biological surveys to
    demonstrate that current discharges are causing instream exceedences of the proposed
    standards or that the receiving streams are suffering any biological damage. (Tr3. at 25.) The
    Mayors support the collection of additional data to determine whether a problem actually exists
    and to determine the benefits of the proposal. (Tr3. at 26.)
    The Mayors also explained the economic impact that the proposed regulations will have
    on their communities. The Mayors noted that previously wastewater treatment plants could
    receive at least 75% grant funding for improvements to the facilities. (Tr3. at 29.) However,
    these grants are no longer available and most of the costs would need to be passed on to the
    citizens. (Tr3. at 29.)
    Kirby Holland of New Water Development testified on a land treatment system to
    manage wastewater. (Tr3. at 84 - 93.)
    James Huff of the engineering consulting firm of Huff & Huff testified in support of
    the amendments proposed by the Cities. Mr. Huff recognizes that the Agency's proposed
    chronic ammonia water quality standards are 50% to 68% more restrictive than the existing
    regulations. (Huff at. 4.) He further contends that benefits from the proposed change have not
    been identified and the change will result in a large economic burden for some communities.
    (Huff at 4.) In support of the recommendation that the parties be allowed to submit
    temperature data to prove that there was no actual violation, Mr. Huff testified to the
    temperature of two Illinois streams, one in the northern part of the state and one in the
    southern part of the state. (Huff at 7.) He found that there were periods in November and
    March where the temperature exceeded 12°C. (Huff at 7.) Mr. Huff maintains that the use of

    12
    temperatures to determine ammonia levels as
    described in the Cities proposal is protective
    of the environment. (Huff at 8.) Concerning the number of significant digits of the standard,
    he testified that three significant digits is impractical due to confidence levels and accuracy.
    (Huff at 10.) Mr. Huff maintains that the approach for deriving effluent limits proposed by
    the Cities is consistent with federal regulations and assures that water quality standards will be
    achieved. (Huff at 11.) He estimated the cost of once-a-week monitoring to obtain additional
    data on ammonia levels in streams at $4,000 per year. (Tr3. at 116.)
    Chad Tuttle, Environmental Manager for Indian Refining Limited Partnership
    9
    (IRLP),
    testified on the impact of the proposed regulation on IRLP. He estimates the cost of adding
    the preferred treatment of activated sludge with nitrification at between $10 to $15 million and
    would not guarantee consistent compliance with permit limits. (Tr3. at 201.) At the Agency's
    recommendation IRLP considered the use of breakpoint chlorination but found that it did not
    present a feasible form of treatment.
    10
    (Tr3. at 202.)
    Testimony from Hearings on February 22 and 23, 1996
    On November 8, 1995, the Board held a pre-hearing conference to further define the
    issues related to hearing in this rulemaking and as such, presented the Agency and the
    participants with various issues which were to be addressed at hearings held on February 22
    and 23, 1996.
    Agency Comments. The Agency maintains that the proposed standards are consistent
    with the Federal Water Pollution Control Act, 33 U.S.C §§1251-1387 (1987), commonly
    referred to as the Clean Water Act and the federal regulations. (Exh. 41 at 2.) The Agency asserts
    that the USEPA will approve the amendments in the present form but even a slight change may
    result in disapproval by the USEPA. (Exh. 41 at 2.) The Agency also indicates that USEPA has
    stated that it could not accept the amendments proposed by the Ammonia Group. (Exh. 41 at 2.)
    The Agency provided a summary of the positions neighboring states (Indiana, Ohio,
    Michigan, Missouri, Kentucky, Wisconsin, Iowa and Minnesota) have taken with respect to
    ammonia nitrogen standards and effluent limits. (Exh. 41 at 3.) Illinois is the first state in
    Region V to develop and propose new ammonia nitrogen limits different than those proposed
    9
    In November 1995 Indian Refining ceased operation of the refinery. The refinery was
    purchased by American Western Refining Limited Partnership which intends to reinitiate
    operation of the facility once financing has been obtained. (Tr4. at 175.) On April 4, 1996,
    American Western Refining, L.P. filed a motion to incorporate past comments and testimony
    of Indian Refining Limited Partnership. The Board granted the motion on May 2, 1996.
    10
    See also In the Matter of: Proposal of Mobil Oil Corporation to Amend the Water Pollution
    Regulations (January 7, 1988), R84-16 at 3, where the Board acknowledged that the use of
    breakpoint chlorination is inappropriate since it would result in the formation of chlorinated
    hydrocarbons.

    13
    by the NCD. (Exh. 41 at 3.) Other states in
    Region 5 are looking to Illinois to the lead
    the way with respect to ammonia nitrogen . (Exh. 41 at 3.)
    The Agency has not formulated a position on specific facilities being granted adjusted
    standards, variances or site specific relief from the proposed ammonia standards. (Exh. 41 at
    10.) However, the Agency notes that relief from ammonia nitrogen water quality standards
    requires federal approval and the Agency believes that the relief allowed by the proposed
    EMW provision is the extent to which the USEPA will grant relief. (Exh. 41 at 10.) With the
    exception of waterways that support viable populations of trout, the Agency does not view any
    rivers or streams as having unique characteristics such that site specific relief may be
    warranted. (Exh. 41 at 10.)
    The Agency believes that loan funding will be available for projects necessary to meet
    the proposed ammonia nitrogen water quality standards. (Exh. 41 at 12.)
    The Agency has specified three reasons why many of the facilities identified as
    potentially not meeting the provisions of the proposed amendments are substantially direct
    dischargers to the Rock and Fox Rivers:
    1. The Rock and Fox River are medium in size and do not provide the
    dilution that a larger river would provide.
    2. The population density in Northern Illinois is much greater than in
    other parts of the state.
    3. The pH level, which is the most influential water quality factor in
    determining permit limits for ammonia nitrogen, is relatively high in
    the Rock and Fox Rivers.
    (Exh. 41 at 13-15.)
    Despite these characteristics, the aquatic life communities in the Rock and Fox Rivers are not
    substantially different from other rivers in the state of Illinois. (Exh. 41 at 15.) With the
    exception of salmonid fishes, the Agency finds no valid basis to suggest that any particular
    region should have ammonia nitrogen standards different from those proposed. (Exh. 41 at
    16.)
    The Agency conducted an update of its literature search and found four additional
    papers related to ammonia nitrogen. (Exh. 41 at 18-21.) The Agency also provided an update
    of the nine facilities that were identified in previous testimony as not meeting existing
    ammonia nitrogen standards. (Exh. 41 at 21-26.)
    In its prefiled testimony from the November 10, 1994 hearing, the Agency submitted a
    list of major municipal treatment plants listed as potentially unable to comply with the
    proposed ammonia nitrogen standards and provided a cost estimate for compliance at these
    facilities. (See Exh. 2-S.) Based on additional information on several of these facilities, the
    Agency updated its cost estimates for compliance. (Exh. 41 at 26.) The Agency calculates that

    14
    under the worst case scenario the estimated
    cost for compliance with the proposed
    ammonia nitrogen standards for major municipal dischargers is $20,034,000. (Exh. 41 at 39.)
    The Agency observes that this is more than a 50% reduction from the initial estimated cost.
    (Exh. 41 at 26.) In addition, the Agency notes that at least seven facilities have been
    identified as being unable to comply with the existing water quality standards that are able to
    comply with the proposed standards. (Exh. 41 at 26.)
    Under existing standards, the ammonia nitrogen concentration a facility discharges to
    its receiving stream must not cause the receiving stream to exceed 0.04 mg/L un-ionized
    ammonia nitrogen unless the total ammonia nitrogen concentration is less than 1.5 mg/L.
    (Exh. 41 at 40.) As a result, a substantial number of major municipal dischargers will have to
    comply with winter monthly average ammonia nitrogen permit limits more stringent than 4.0
    mg/L. (Exh. 41 at 40.) Since 1993, the Agency has drafted NPDES permits with winter
    ammonia nitrogen effluent limits set at appropriate levels to comply with current ammonia
    nitrogen standards. (Exh. 41 at 40.) At least four permits were issued with a three year
    compliance plan, which when completed will require compliance with the water quality based
    ammonia nitrogen limits. (Exh. 41 at 40.) In addition, four other facilities have such
    compliance plans in their draft NPDES permits. (Exh. 41 at 41.) The Agency expects the
    number of facilities unable to meet the winter water quality based effluent ammonia nitrogen
    limit to double. (Exh. 41 at 41.) The Agency estimates a capital cost of $66 million for these
    facilities to comply with the existing ammonia standards. (Tr4. at 13.) If the trend continues,
    it is reasonable to assume that these numbers would double when the current five year NPDES
    cycle is complete and the cost could exceed $132 million. (Tr4. at 13.) However, these costs
    could be avoided if the proposal as amended is adopted within a reasonable time period prior
    to the affected facilities having constructed hardware. (Tr.4. at 168.)
    The Agency has committed to promulgating a rulemaking implementing EMW
    procedures. (Tr4. at 156.)
    Borden Chemical. Sailesh Jantrania, technical manager for Borden Chemicals &
    Plastics Operating Limited Partnership (BCP) in Illiopolis, Illinois testified that the proposed
    ammonia nitrogen standard is too stringent and that the EMW provision will not provide relief
    to dischargers to low flow streams. (Exh. 49 at 1.) BCP contends that: 1)exceedences of the
    standards by dischargers to low flow streams will not be rare and infrequent; 2)the proposed
    standards are not necessary to protect Illinois waters; 3)the EMW provision needs to be
    modified to provide the relief intended by the Agency; 4)Section 304.122 should be modified
    to make clear that daily variability around monthly average limitations is not precluded by the
    regulation; and 5)additional monitoring costs may result from the proposed standards. (Exh.
    49 at 1.)
    Fox Metro Water Reclamation District. Greg Buchner, special projects coordinator for
    the Fox Metro Water Reclamation District (FMWRD)
    11
    testified on the impact of the proposed
    11
    The Fox Metro Water Reclamation District was formerly know as the Aurora Sanitary
    District.

    15
    standards on the FMWRD. The FMWRD
    submitted a report containing data gathered
    on the Fox River. (Exh. 50.) Samples taken over a one year period were analyzed for
    dissolved oxygen (DO), temperature, pH and ammonia nitrogen. (Exh. 50 at 5.) The report
    supports the Agency’s earlier observation that the Fox River has a naturally occurring high
    pH. (Exh 50 at 6.) Using the data, FMWRD calculated water quality based ammonia nitrogen
    effluent standards for its facility under different scenarios. (Exh. 50 at 7.) The calculations
    show that due to the high pH of the Fox River, FMWRD would be subject to un-ionized
    ammonia nitrogen levels far below the proposed water quality standards. (Exh. 50 at 9.)
    FMWRD’s main concern is that the proposal will result in effluent limits for its facility
    that are more stringent than 1.5 mg/L summer and 4.0 mg/L winter. (Exh. 50 at 10.) While
    the facility may currently be able to meet these standards it is doubtful that these levels could
    be maintained as community growth increases. (Exh. 50 at 10.) FMWRD is also concerned
    that the USEPA could strike down the agreement between the Agency and FMWRD to use
    data from the downstream sampling and result in the recalculation of effluent limits. (Exh. 50
    at 10.) FMWRD also objects to the use of “Existing Effluent Quality” in determining future
    effluent limits because its does not take into account future community growth and it penalizes
    well run treatment facilities. (Exh. 50 at 10.)
    FMWRD suggests that the proposal be modified to create an exception to the general
    rule where there is high naturally occurring pH.
    Illinois Association of Wastewater Agencies. James Daugherty testified on behalf of
    IAWA. IAWA expressed its concern over the limited amount of toxicity data available to
    derive the standards. (Tr5. at 65.) IAWA believes that standards of 1.5/4.0 mg/L are the
    lowest effluent levels that should be written because these are levels that are achieved through
    present technology. (Tr5. at 266.) IAWA stresses the importance of adopting the proposal
    given the expiration of Section 304.301. (Tr5. at 267.) IAWA notes that it did not pursue an
    extension of Section 304.301 since this rulemaking was pending. (Tr5. at 267.)
    Ammonia Group. James Huff testified on behalf of the Ammonia Group (Cities of
    Batavia, Geneva, Rock Falls, St. Charles, Sterling and Galesburg). Mr. Huff provided an
    update on what the communities have done since the previous hearing. (Exh. 52 at 1 - 12.)
    Mr. Huff notes the excellent fishing conditions on the Fox River and the abundance of fish
    near outfalls and in mixing zones and questions the effects of ammonia at existing levels on
    aquatic life. (Exh 52 at 13.)
    A one year sampling program consisting of weekly samples from nineteen stations on
    the Fox River and eight tributaries was developed by a group of dischargers along the Fox
    River. (Exh. 52 at 13.) Mr. Huff acted as project manager of the study and submitted a report
    of the study “Ammonia Water Quality Study of the Fox River” to the Board. (Exh. 53.)
    Based on the data obtained from this study, Mr. Huff concludes that a further tightening of the
    effluent limits is not justified. (Exh. 52 at 15.)
          

    16
    The Ammonia Group suggests the following changes to the proposal:
    1)
    Allow stream temperatures to be measured at discharger’s option to determine
    appropriate water quality standard (0.020 or 0.050 mg/L).
    2)
    Incorporate the extension of time as originally proposed by the six communities
    for implementation of the revised effluent limits.
    3)
    Drop the extra zero in the un-ionized ammonia limits.
    4)
    Allow scientifically defensible alternatives to the Agency’s mass balance
    procedure for deriving effluent ammonia limits.
    5)
    Adopt the four-sample average concept, as proposed by the Agency.
    6)
    Adopt a winter un-ionized ammonia limit of 0.03 mg/L and/or consider keeping
    the 1.5 mg/L total ammonia “floor” limit.
    7)
    Effluent modified waters should be tied strictly to NPDES permit limits of 1.5
    mg/L summer and/or 4.0 mg/L winter.
    8)
    Allow seasonal EMW designations.
    9)
    Ammonia effluent limits should not be set below 1.5/4.0 mg/L.
    (Exh. 52 at 20-21.)
    PUBLIC COMMENTS
    Comments filed in R94-1 relating to ammonia
    The Board received 26 public comments on the proposal as originally filed in R94-1.
    One comment (PC #12) concerned the portion of the proposal concerning lead and mercury
    (Subdocket) and the remaining 25 public comments concerned the proposed amendments to the
    ammonia standard, the origin and content of which are summarized in this section.
    PC #1:
    By Linda Brand, Manager of Regulatory Flexibility Unit, Illinois Department
    of Commerce and Community Affairs: a review of the proposed amendments
    found no impact on small businesses. Filed 10/5/94.
    PC #2:
    The City of Sterling, Illinois, by Stephen Berly, City Manager; the community
    became aware of the proposed rule on November 10, 1994 and requests more
    time to understand the effects of the proposed rulemaking. Filed 11/29/94.
    PC #3:
    The City of Rock Falls, Illinois, by Glen R. Kuhlmeier, Mayor; requests
    additional time to evaluate the proposed rules. Filed 11/29/94.
    PC #4:
    The City of St. Charles, Illinois; requests a 12-month delay for evaluation of
    its wastewater treatment facility. Filed 11/29/94.
    PC #5:
    The Illinois Department of Conservation (IDOC) by Jim Mick, Streams
    Program Manager, Division of Fisheries; copy of a 1989 study "Biological

    17
    Stream Characterization: A
    Biological Assessment of Illinois Stream
    Quality." Filed 12/27/94.
    PC #6:
    By Arthur R. Allan who opposes the proposed rulemaking. Mr. Allen
    expresses concern over the present decline of fish species in the Fox River and
    the potential for future degradation. He characterizes the Cities' proposal as a
    request to skate up close to the illegal parameters. Filed 1/17/95.
    PC #7:
    The City of Dixon by Donald E. Sheets, Mayor; a resolution of the City
    Council of Dixon passed on January 17, 1995. The resolution requests that
    the Board approve the amendments proposed by the Cities. Filed 1/23/95.
    PC #8:
    By James Warchall on behalf of Borden Chemicals and Plastics Operating
    Limited Partnership.
    12
    Mr. Warchall suggests that the concept of effluent
    modified waters (EMW) be modified. Mr. Warchall suggests that an NPDES
    permittee should be able to request that the Agency make a determination as to
    whether a stream is an EMW. The modifications suggested by Borden also
    include deleting the requirement that EMWs meet the water quality standard
    and that the language of Section 302.213(a)(2) be rewritten to avoid
    ambiguity. Filed 1/13/95.
    PC #9:
    Agency Comments and Questions in response to the comments of James
    Warchall. The Agency foresees problems in implementing the suggestion
    concerning determinations on EMWs. The Agency believes that the
    determination of an EMW should be part of the permitting process but that
    informal and tentative determinations will be made in some situations. The
    Agency maintains that requiring EMWs to meet the water quality standard is
    necessary to protect aquatic life and for USEPA approval. The Agency
    objects to any change in the language of Section 302.213(a)(2) since this
    section was the subject of some rather long and intense discussions with the
    USEPA. Filed 1/24/95.
    PC #10:
    By J. Dennis Hastert, Member of Congress, in support of the Cities' request
    for additional time. Mr. Hastert believes that before requiring the expenditure
    of millions of dollars every assurance should be made that there is a real
    problem. Filed 3/9/95.
    PC #11:
    The Sierra Club, Illinois Chapter of Trout Unlimited, Citizens for a Better
    Environment, Lake Michigan Federation, and Friends of the Chicago River,
    by Albert F. Ettinger; This comment recommends adoption of USEPA
    12
    This document was originally filed as pre-filed testimony; however, since no-one appeared at
    hearing to present the testimony, the hearing officer entered the testimony as well as the questions
    of the Agency on the testimony (PC # 9) as public comments.

    18
    standards for ammonia. The
    commenters assert that the proposed
    amendments are requests for site-specific relief and the objection of the Cities
    is to the implementation of the standards. The comment also suggests that
    standards for zinc, selenium, nickel and phosphorous should be adopted. Filed
    3/10/95.
    PC #13:
    By Cynthia L. Skrukud, McHenry County Defenders; supports adoption of
    standards but believes that more stringent USEPA standard for ammonia
    should be adopted. In addition, the comment states that effluent modified
    waters only serve to protect polluted waters from the possibility of becoming
    cleaner. Filed 3/10/95.
    PC #14:
    By Billita Jacobsen, Fox Path Association; asserts that lower ammonia
    standards are needed to protect recreational uses of the Fox River. Filed
    3/10/95.
    PC #15:
    By Barbara Marquardt, President Fox Valley Land Foundation; cites the
    effects of sewage discharge on rivers and encourages the investigation of land
    application of sewage. Filed 3/10/95.
    PC #16:
    Fuji Photo Film, Inc. by Nancy Neely; Fuji notes that ammonia compounds
    are used extensively in photo imaging processes. Fuji believes that the
    proposed limits will place an undue burden on photoprocessors and the cost of
    compliance will filter down to small business owners. Filed 3/13/95.
    PC #17:
    Indian Refining Limited Partnership (IRLP) by Christina Riewer; IRLP asserts
    that it will not be able to meet the proposed ammonia standards. IRLP
    supports the proposal of the Cities for deriving effluent limits based on actual
    stream data. Filed 3/13/95.
    PC #18:
    The Chemical Industry Council of Illinois (CICI), by Mark Homer. This
    comment asserts that sufficient evidence has not been provided by the Agency
    to show that the proposed ammonia nitrogen limits are necessary to protect
    Illinois waterways. CICI claims that chemical manufacturers will be effected
    since their effluent contains ammonia. CICI maintains that any standard above
    two significant digits is unjustified. Filed 3/13/95.
    PC #19:
    The National Photographic Manufacturers, Inc., by Thomas Duffy; expresses
    agreement with PC #20 from Eastman Kodak and suggests that USEPA
    standards be adopted. Filed 3/13/95.
    PC #20:
    The Eastman Kodak Company by Linda J. Liszewski; Eastman Kodak
    believes that the standards should be consistent with USEPA guidance. Filed
    3/15/95.

    19
    PC #21:
    The Graphic Arts Technical Foundations by Gary A. Jones; suggests the
    possible effect on small businesses of the proposal. Filed 3/15/95.
    PC #22:
    The Cities of Batavia, Geneva, Rock Falls, St. Charles, and Sterling
    (Ammonia Group) by Lee Cunningham. The Ammonia Group believes that it
    is wrong to require expenditure without any known environmental benefit.
    The Ammonia Group maintains that the Agency has no biological survey
    reports that show that the discharge of ammonia from any of the affected
    facilities has caused instream degradation. The key elements of the Ammonia
    Group's proposal include providing an opportunity for dischargers to
    determine whether ammonia degradation will occur, dischargers would
    maximize the ammonia treatment in light of existing operational conditions,
    where temperature data exists it can be used to determine if a violation
    occurred and there is no support for adding a zero to the standards. Filed
    3/15/95.
    13
    PC #23:
    Illinois Association of Wastewater Agencies (IAWA) by James L. Daugherty;
    supports adoption of the standards as proposed with amendments presented in
    their testimony. IAWA believes that the addition of a third decimal place is
    inappropriate. Filed 3/22/95.
    PC #24:
    Agency's Final Comment by Margaret Howard; (This comment addresses
    many issues of contention; in view of its length and content, the comment is
    summarized in a separate following section.) Filed 4/11/95.
    PC #25:
    Index Department of the Administrative Code Division of the Office of the
    Secretary of State; notes corrections that must be made to the text of the rule
    before the rule can be adopted. The Board today makes the suggested
    corrections to the text. Filed 11/7/94.
    PC #26:
    Illinois Environmental Regulatory Group submitted by Katherine Hodge. This
    comment expresses concerns on the Board’s scheduling a pre-hearing
    conference at this point in the proceeding. Filed 10/31/95.
    Summary of Agency's Comment (PC #24). The Agency believes that the limited
    criticism of the actual numbers proposed for the water quality standards indicates that the
    regulated community concurs with the basic precepts of the rulemaking. The Agency argues
    that the addition of the third digit is necessary to ensure that rounding practices would not
    compromise the integrity of the standards. The standards are to be considered as "not to
    exceed" values. The Agency is agreeable to adopting the standards with three significant digits
    13
    Public Comments #22 and #23 were accompanied by motions to file instanter. Those motions
    are hereby granted.

    20
    or including a narrative on rounding practices
    or adopting the three digits from the original
    calculations.
    The Agency does not support the amendments proposed by the Cities (Ammonia
    Group) and notes that the USEPA has also indicated that it does not support the amendments.
    The Agency contends that some facilities will need to add nitrification to meet the
    proposed standards. For facilities that employ the highest level of ammonia nitrogen removal
    but are unable to meet the proposed standards, the regulations include the concept of effluent
    modified water. The Agency maintains that the proposed regulations are technically feasible.
    The Agency maintains that the proposed regulations are economically reasonable. The
    Agency recognizes that the ammonia standards will have a potential effect on approximately 20
    major municipal dischargers and one industrial discharger. The Agency has provided worst
    case costs for the upgrading of these facilities. The Agency maintains that the proposed
    regulations are economically reasonable and from a statewide perspective, the economic impact
    for a handful of municipal dischargers will be minimal.
    The Agency maintains that implementation is not an issue in the proposed regulation.
    However, in recognition of criticisms from potentially affected dischargers, the Agency notes
    the proposed regulations will be implemented according to the Agency's existing
    implementation procedures. The Agency also recognizes that portions of the implementation
    procedures will need to be updated to match portions of the proposed regulations. The Agency
    also states that new implementation procedures will be proposed in an Agency rulemaking after
    the Board enters its final order in this rulemaking.
    The Agency believes that a temperature based water quality standard is inappropriate.
    The Agency maintains that the use of 12° is not supported on the record and that the Agency
    used 12° as the break between summer and winter based an the lack of toxicity information in
    the range between 10° and 14°. The Agency also believes that the use of a temperature based
    water quality standard is inappropriate when the standard is implemented as an average. The
    Agency contends that the temperature standard will be difficult to implement. Thermal
    variations in the stream would result in different standards for different parts of the stream.
    The Agency is opposed to allowing time to study compliance with the proposed
    ammonia standards. The Agency contends that the "wait and see" monitoring approach is
    inconsistent with the intent of the protection principles of the CWA. The Agency maintains
    that treatment plants should already be taking measures to minimize ammonia effluent
    concentrations. The Agency maintains that data collection should occur simultaneously with
    other items in a compliance schedule. The Agency contends that optimization of ammonia
    removal at a treatment plant and monitoring programs can be incorporated into the three year
    compliance schedule in a NPDES permit.

    21
    The Agency agrees that a viable
    population of trout exists in one five mile
    long reach of a stream in Illinois. The Agency also acknowledges that trout toxicity data was
    removed from consideration in deriving the proposed standards. The Agency states that a
    special ammonia standard could be derived for this stream segment but there are no point
    sources to this segment so no consequences of the special standard would be immediately felt.
    The Agency contends that the warm water conditions of Illinois waterbodies rather than
    ammonia nitrogen prevent trout from permanently establishing in Illinois waterways.
    The Agency believes that the comments from the photographic industry reflect a
    misunderstanding of the proposed regulations. The Agency states that the comments of the
    photographic industry imply that the proposed limitations apply to effluent dischargers instead
    of water quality in the waters of the State. The Agency maintains that the proposed standards
    are consistent with current USEPA policies and guidelines. The Agency also maintains that
    the proposed standards are not more stringent than USEPA requirements. The Agency
    believes that imposing limits on ammonia contributors to pretreatment is not a viable option.
    The Agency describes the comments from the Chemical Industry Council of Illinois as
    suffering from major misconceptions of the details of the rulemaking. The Agency notes that
    only one industrial facility was identified as being potentially impacted. The Agency maintains
    that streams will be designated as EMW when NPDES permits are issued and that there is no
    reason to pre-designate these streams. The Agency believes that the regulations are clear in
    specifying the criteria necessary to designate a water as effluent modified. The Agency
    believes that in impacted communities, industrial users will pay only a proportionate share of
    costs based on their relative contribution to the system.
    The Agency disputes IAWA's contention that the factors used to obtain un-ionized
    ammonia values were inaccurate. The Agency supports IAWA's suggestion that the Agency
    should be open to other models in its rules of implementation but the Agency maintains that
    the proper time for the presentation of these models is in the updating process of the
    implementation procedures.
    While the Agency does not completely agree with the comments submitted by IRLP,
    the Agency and IRLP have continued to discuss the issues regarding IRLP's facility. The
    Agency makes the following statement concerning IRLP:
    IRLP and the Agency have reached conceptual agreement resolving the chronic water
    quality issues. That agreement involves using an effluent design average discharge rate
    ("Q
    E
    ") for IRLP of 2.3 million gallons per day ("MGD"). The Agency would also use
    monthly ("7Q
    10
    ") values based upon a June 1993 Illinois State Survey Report for the
    Embarras River. The acute water quality issues remain to be solved.
    Comments filed in R94-1(B)

    22
    PC #1(B)
    14
    Granite City Division,
    National Steel Corporation (GCD). GCD
    contends that the Agency has not shown that the proposed standard is
    economically or technically feasible for industrial dischargers. Filed
    3/29/96.
    PC #2(B)
    McHenry County Defenders and the Friends of the Fox River submitted by
    Gerald Paulson. The comment objects to the provision that establishes effluent
    modified waters and the lack of an ammonia standard that is protective of cold
    water fish species. The comment notes that parties who cannot meet the
    proposed standards may request an adjusted standard from the Board and a
    special procedure is not necessary. The comment notes that streams that flow
    into the Kishawaukee River are able to support cold water species not found in
    other parts of the state. The comment urges adoption of USEPA standards for
    these streams instead of the proposed standards which are not protective of
    cold water species. Filed 3/29/96
    PC #3(B)
    Sierra Club, Illinois Chapter of Trout Unlimited, Citizens for a Better
    Environment, Lake Michigan Federation, and Friends of the Chicago River
    submitted by Albert Ettinger. This comment contends that the Board must: 1)
    eliminate or at least clarify the provision regarding EMW; 2) adopt ammonia
    water quality standards consistent with the USEPA national criteria for
    ammonia or adopt those criteria for Illinois waters known to have harbored or
    to harbor cold water species and 3) reject the arguments which ask the Board
    to adopt standards that are wholly inadequate to protect aquatic life. Filed
    3/29/96.
    PC #4(B)
    The Ammonia Group submitted by Lee Cunningham. This comment provides
    an overview of the Ammonia Group’s position as presented in testimony and
    other filings. The comment explains the differences between the Ammonia
    Group’s proposal and the Agency’s proposal. The Ammonia Group supports
    the amendments submitted by IAWA clarifying the EMW requirements. The
    Ammonia Group withdraws the concept of using actual stream temperature to
    determine ammonia standards from its proposal. Filed on 3/29/96.
    PC #5(B)
    William Leja, member of the Sierra Club. Mr. Leja refers the Board to
    several scientific studies and their findings. In addition, he questions whether
    the findings of these studies have been considered in the proposed rules. Filed
    on 4/1/96.
    14
    The public comments filed in Subdocket (B) were entered into the Docket beginning with
    number 1, a (B) is added after the public comment number to indicate that the comment was
    filed in Subdocket (B).

    23
    PC #6(B)
    American Western Refining
    submitted by Bill Forcade. American
    Western Refining suggests that the Board mandate a rational implementation of
    the proposed ammonia water quality standard as part of the rulemaking. Such
    implementation shall include a provision for an affirmative defense when the
    permittee can show that actual stream data shows no violation of the water
    quality standard, provide American Western with dry weather discharge levels
    and stream low flow levels and provide American Western with a Zone of
    Initial Dilution equal to 2% of the Embarras River’s flow. Filed 4/4/96.
    PC #7(B)
    Chemical Industry Council of Illinois (CICI) by Mark Homer. CICI contends
    that further technical support of any adverse impact on Illinois waterways is
    necessary before changing the ammonia nitrogen standard especially
    considering the cost of compliance. CICI submits that no additional action
    should be taken in this matter due to the confusion and controversy
    surrounding the federal ammonia nitrogen water quality standards. CICI
    reports that USEPA Region VIII is drafting a white paper on ammonia
    standards. CICI observes that other states in Region V have not taken any
    action but are looking to Illinois to lead the way. CICI also observes that the
    EMW provision creates an uncertainty as to which facilities will be effected by
    the proposal. Filed 4/5/96.
    PC #8(B)
    Illinois Environmental Protection Agency submitted by Margaret Howard.
    This comment presents a summary of the Agency’s position and responses to
    issues and comments. This comment contains a revised proposal consisting of
    language agreed to between USEPA and the Agency. (Attachment BB.) The
    Agency anticipates that loans will be available to fund some of the
    modifications to facilities that will be required by the proposed amendments.
    Filed on 4/8/96.
    PC#9(B)
    15
    Supplemental Comments of the Ammonia Group submitted by Lee
    Cunningham. The Ammonia Group provided a copy of the Hall report
    providing additional information on the regulatory history of the development
    of national ammonia water quality criteria, a summary of post-1984 research
    on ammonia toxicity impacts, some additional information on actions by other
    states and recommendations for revisions. (Attachment C to PC #9(B).) The
    comment also provides a summary of a teleconference with two USEPA
    employees concerning this proceeding. Filed on 6/3/96.
    PC#10(B)
    City of Belleville. Belleville reports that it has received a draft permit
    containing more stringent ammonia limits than previous permits and a
    15
    The Agency filed a motion to strike this comment. The motion and the response to the
    motion are addressed in a section following the discussion of the comments.

    24
    compliance schedule.
    Belleville moves for the expeditious adoption
    of revisions to the ammonia regulations. Filed on 6/3/96
    PC#11(B)
    Illinois Environmental Protection Agency’s Comments on “Final Report of
    Ammonia Group Prepared by the Wisconsin Department of Natural
    Resources”.
    16
    The Agency distinguishes the findings of the Wisconsin Report
    and Illinois regulations and the water quality standards contained in the
    proposal. The Agency notes that the Wisconsin Report is a summary of
    recommendations with no indication whether the suggestions are workable.
    Filed on 6/5/96.
    PC#12(B)
    Illinois Environmental Protection Agency’s Additional Supplemental Final
    Comments. The Agency maintains that the planned drafting of an issue paper
    by USEPA Region VIII on ammonia nitrogen is irrelevant to this proceeding
    and therefore, this proceeding should not be delayed in anticipation of that
    paper. The Agency urges the Board to review the record in this matter and
    adopt the regulation as proposed. Filed on 6/5/96.
    PC#13(B)
    Supplemental Comments of the Illinois Association of Wastewater Agencies.
    IAWA urges the expeditious adoption of the amendments to the ammonia
    water quality standards including the language proposed on EMW. IAWA
    notes the serious shortage of data on chronic ammonia toxicity and requests
    that the Board give full consideration to all information before adopting more
    stringent chronic standards. IAWA also suggests that the Board defer all
    implementation details to the Agency. Filed on 6/17/96.
    Motions concerning PC#9(B)
    On June 27, 1996, the Agency filed a motion to strike the supplemental comments of
    the Ammonia Group. (PC #9(B)) The Agency contends that the comments contain information
    that is outside of the type of information requested by the Board’s order allowing the filing of
    additional comments and that the information submitted is irrelevant. The Agency maintains
    that the information in the Ammonia Group’s supplemental comment was available prior to the
    filing of the supplemental comment. The Agency also maintains that portions of the comments
    are hearsay testimony and therefore should be stricken.
    On June 3, 1996, the Ammonia Group filed a response to the Agency’s motion. The
    Ammonia Group notes that this proceeding is at the pre-First Notice stage and therefore the
    record is still open. While the Ammonia Group recognizes that the information regarding the
    teleconferences represents hearsay, it argues that the information is admissible in that it is
    relevant and non-repetitious. The Ammonia Group also observes that this type of information
    16
    This report was attached to the Ammonia Group’s Post-hearing Comments (PC#4(B)). On
    May 2, 1996, the Board denied the Agency’s motion to strike the Wisconsin Report.

    25
    does not differ in nature from information
    concerning USEPA policy submitted in this
    proceeding by the Agency.
    On July 8, 1996, the Illinois Steel Group (Steel Group) filed a response to the motion
    to strike. The Steel Group argues that the conversations between Mr. Cunningham and the
    USEPA do not constitute inadmissible hearsay. The Steel Group contends that this is not
    hearsay since Mr. Cunningham has personal knowledge of the conversations, and the question
    of whether the content of the conversation is fact is an area for further investigation in this
    rulemaking. The Steel Group also notes that striking this comment will result in material
    prejudice to the dischargers impacted by the rule in that substantial expenditures will be
    required to comply with the standard that may not be necessary.
    On July 17, 1996, the Agency filed a motion to file a reply along with a reply to the
    Ammonia Group’s response. The Board grants the Agency leave to file a reply and accepts
    the reply filed by the Agency. The Agency recognizes the fact that these proceedings are not
    closed but believes that the comments filed were to summarize the positions of the participants
    and not to present new information. The Agency maintains that the summary of the
    conversations represents hearsay and should not be allowed in a regulatory proceeding. In
    addition the Agency differentiate these conversations from other information on USEPA policy
    presented in this proceeding.
    The Board denies the Agency’s motion to strike the supplemental comments of the
    Ammonia Group. The Board will include the supplemental comments of the Ammonia Group
    as filed as part of the record to be considered by the Board in this rulemaking. Section
    102.282 allows for all information that is relevant and not repetitious to be entered into the
    record of a rulemaking. The Board also notes that the information was submitted in a public
    comment and not as sworn testimony. The Board will consider the comment as filed, giving it
    the appropriate weight in this matter.
    DISCUSSION
    The Board recognizes the concern among some of the participants in this matter that for
    some special uses, particularly the support of salmonid fish populations, the ammonia
    standards herein proposed may not be sufficient to support the special use. However, it must
    also be recognized that the General Use Water Quality Standards are intended to apply to
    general waters of the State, and are accordingly an inappropriate vehicle to address support of
    very special, and geographically-restricted needs. The Board observes that it has long utilized
    special standards for special needs,
    17
    and that it would always entertain proposals to utilize this
    concept to give necessary protection to any Illinois waters.
    17
    The Board's observes that it maintains a special section in its water quality rules titled "Water
    Use Designations and Site Specific Water Quality Standards" at 35 Ill. Adm. Code Part 303. The
    Board promulgates the standards that are necessary to support special uses.

    26
    Significant Figures
    The number of significant digits in the ammonia standards is no longer at issue in this
    matter since the new proposal submitted by the Agency did not contain levels to three
    significant digits. However, the Board offers the following comments on this issue.
    As regards the dispute over the number of significant figures to be used in specifying
    the ammonia standards, the Board is convinced that three significant figures is not in the
    instant circumstance justified, given the statistical errors of rounding and analysis.
    Standard Methods for the Examination of Water and Wastewater (18th ed.) discusses
    the relative error and relative standard deviation between laboratories and between method for
    NH
    3
    -N analysis. Depending on the analytical method and the ammonia nitrogen concentration
    present, relative errors to the test range from 0% to 20.0%. Relative standard deviations
    ranged from 5.3% to 69.8%. In some cases the low relative error between laboratories is
    easily explained by the high relative standard deviation found within laboratories. Given that
    standard deviations often exceed 10% of the result, reporting more than two significant figures
    cannot be technically justified.
    Determination of un-ionized ammonia requires: 1) the collection of a representative
    sample; 2) determination of sample temperature in the field; 3) measurement of pH; and 4)
    analysis of NH
    3
    - N. Errors of sampling and analysis occur at each point. Statistical support
    can only begin for the measurement yielding the least number of significant figures.
    Measurement of pH is usually carried only to two significant figures. Measurement of
    temperatures using field thermometers is seldom accurate to a third significant figure.
    Accordingly, the statistical necessity of compounding method errors indicates that a regulatory
    requirement for three significant digits is technically infeasible in this instance.
    As an alternative to the addition of a third significant digit the Agency requested that
    the Board include a narrative on rounding practices. However, the Agency did not specify the
    contents of that narrative or include any reference on the standard rounding practices to be
    employed by the Board. In addition, the Board recognizes that the rounding of analytical data
    is an issue in other areas before the Agency and the Board and therefore any discussion of
    rounding practices in this proceeding could have far reaching implications. Therefore, the
    Board declines to elaborate on rounding practices concerning the data of the proposed
    standards.
    Effluent Modified Waters
    The Board recognizes that the standard treatment methodology for ammonia N is
    nitrification in a biological treatment plant, usually activated sludge. This treatment method
    does not assure compliance with the chronic ammonia standards proposed at all times outside
    of a mixing zone, especially in small streams. The Board further recognizes that additional
    treatment would come at great cost, and with little or no benefit. The concept of effluent

    27
    modified waters is proposed to ensure that
    well run treatment plants are not found to be
    routinely in violation where no harm is done to the aquatic environment.
    To obtain the relief intended by this section, a discharger must demonstrate that limits
    of 1.5 mg/L in summer and 4.0 mg/L in winter of ammonia can be attained in the discharge,
    that the existing level of treatment will be maintained, and that new or increased ammonia
    loadings to the stream would meet nondegradation standards in the stream. Further, acute
    ammonia standards must be met, and there can be no known uses of the stream that would be
    adversely affected by the discharge. Once these demonstrations are made, the Agency may
    designate a portion of the stream to be effluent modified waters.
    Temperature Based Standards
    While the Ammonia Group did not agree with the Agency that a temperature standard
    would create an unnecessary burden, it withdrew the provision of its proposal for a
    temperature based standard due in part to the confusion as to how the standard would be
    implemented. (PC #4(B) at 14.) However, due to the amount of the record that pertains to this
    issue the Board will comment on the provision.
    The Board agrees that the addition of the temperature provision to the regulation will
    result in unnecessary confusion. The Board finds that the use of temperature would be
    applicable only in a limited number of incidents due to the limited monitoring of temperature
    and the limited number of times that the water temperature would require a different standard
    than that imposed by the date. The Board also believes that the use of temperature would
    unnecessarily complicate any determinations of compliance with the regulations. The Board is
    concerned with the variation in temperature that results from different measuring practices and
    the possible use of various methods to obtain a more favorable temperature reading.
    Additional Studies
    The Board recognizes the utility of additional toxicity studies on ammonia nitrogen,
    lead, mercury and other contaminants. The Board notes that these proposed standards are part
    of the Agency's triennial review and therefore, the water quality standards in this proposal
    may be subject to review in subsequent triennial reviews by the Agency. Information obtained
    from any studies would be instrumental in the next review period and other proposals relating
    to water quality standards.
    The proposal by the Cities and IAWA for additional studies failed to provide sufficient
    information on the types of studies to be performed, the parties responsible for the studies and
    the use of the studies. The Board believes that it could not allow additional time for studies
    without providing specific guidelines on the performance and use of the studies. The record
    before the Board was insufficient for the Board to determine an appropriate testing procedure.
    In addition, the Board believes that the specific facilities and waterways would require distinct

    28
    testing and sampling mechanisms that could
    not be adequately addressed in a rule of
    general applicability.
    In addition, the Board notes that the delays in this rulemaking have provided additional
    time for the participants to conduct studies and review compliance options. Several studies
    have been undertaken during the course of this rulemaking, in particular the Board notes the
    study of the Fox River presented by the Ammonia Group and additional data from dischargers
    provided by IAWA. and the study by the Fox Metro Water Reclamation District.
    Alternative Relief
    The Board recognizes that the proposed standards will adversely affect some facilities.
    However, relief for some facilities may be available in the provision of the proposal on
    effluent modified waters. Also as noted by the Agency, compliance schedules will be included
    in many NPDES permits to allow time for the facilities to implement the necessary
    modifications needed to achieve compliance. In addition, the Board notes that relief may also
    be available through variance, adjusted standard or site-specific rule from the Board.
    In reviewing the petitions of the affected facilities, the Board finds that it is not
    appropriate at this time to grant the types of relief requested. The proposal is a rule of general
    applicability to the general use waters of the State. Virtually all of the participants in this
    rulemaking agree that the rule is appropriate as a water quality standard. The affected
    facilities are comprised of municipalities and industrial facilities that the Agency has informed
    will be impacted by this rule. The Agency made that determination by calculating theoretical
    ammonia limits for a hypothetical permit for these facilities using a draft algorithm, and
    comparing the results to performance data from the plant effluents. The Board finds that the
    assertion by those facilities identified as being affected by the proposed amendments that
    additional relief will be needed is too tenuous a link for the Board to fashion relief for the
    affected facilities within this rule.
    Other Water Quality Standards
    The Sierra Club has urged the Board to adopt water quality standards for zinc,
    selenium, nickel and phosphorous. However, the record does not contain any proposed
    standards for these elements nor any studies or information concerning the effects of these
    elements. The consideration of water quality standards for constituents other than ammonia
    nitrogen is not appropriate in this rulemaking. A proposal for rulemaking containing the
    required information may be filed by any person pursuant to Section 102.120.
    Implementation
    While implementation of the proposed standards is not included in the proposal before
    the Board, one cannot consider the proposal without considering the effect the standards will
    have in determining permit limitations. Permit limits are derived by the Agency through the

    29
    use of water quality standards and are imposed
    to maintain the quality of the waterway and
    protect aquatic life.
    In support of the proposal the Agency included the implementation guidelines that the
    Agency follows. (Exh. 2L and 2M.) The Agency has asserted that it intends to adopt
    regulations concerning the implementation of the water standards.
    The Board recognizes that much of the opposition to the regulations by participants
    centered around the implementation of the standards and the ultimate effect the standards
    would have on ammonia nitrogen levels in permits. The Board believes that implementation
    standards should be promptly promulgated by the Agency, allowing for input from the
    regulated community. The Board also reminds the participants in this proceeding that any
    person may submit a regulatory proposal for adoption of a regulation to the Board pursuant to
    35 Ill. Adm. Code 102.120.
    ORDER
    The Board directs the Clerk to cause publication of the following amendments in the
    Illinois Register for first notice:
    TITLE 35: ENVIRONMENTAL PROTECTION
    SUBTITLE C: WATER POLLUTION
    CHAPTER I: POLLUTION CONTROL BOARD
    PART 302
    WATER QUALITY STANDARDS
    SUBPART A: GENERAL WATER QUALITY PROVISIONS
    Section
    302.100
    Definitions
    302.101
    Scope and Applicability
    302.102
    Allowed Mixing, Mixing Zones and ZIDs
    302.103
    Stream Flows
    302.104
    Main River Temperatures
    302.105
    Nondegradation
    SUBPART B: GENERAL USE WATER
    QUALITY STANDARDS
    Section
    302.201
    Scope and Applicability
    302.202
    Purpose
    302.203
    Offensive Conditions

    30
    302.204
    pH
    302.205
    Phosphorus
    302.206
    Dissolved Oxygen
    302.207
    Radioactivity
    302.208
    Numeric Standards for Chemical Constituents
    302.210
    Other Toxic Substances
    302.211
    Temperature
    302.212
    Ammonia Nitrogen and Un-ionized Ammonia
    302.213
    Effluent Modified Waters (Ammonia)
    SUBPART C: PUBLIC AND FOOD
    PROCESSING WATER SUPPLY STANDARDS
    Section
    302.301
    Scope and Applicability
    302.302
    Algicide Permits
    302.303
    Finished Water Standards
    302.304
    Chemical Constituents
    302.305
    Other Contaminants
    302.306
    Fecal Coliform
    SUBPART D: SECONDARY CONTACT AND
    INDIGENOUS AQUATIC LIFE STANDARDS
    Section
    302.401
    Scope and Applicability
    302.402
    Purpose
    302.403
    Unnatural Sludge
    302.404
    pH
    302.405
    Dissolved Oxygen
    302.406
    Fecal Coliform (Repealed)
    302.407
    Chemical Constituents
    302.408
    Temperature
    302.409
    Cyanide
    302.410
    Substances Toxic to Aquatic Life
    SUBPART E: LAKE MICHIGAN WATER
    QUALITY STANDARDS
    Section
    302.501
    Scope and Applicability
    302.502
    Dissolved Oxygen
    302.503
    pH
    302.504
    Chemical Constituents

    31
    302.505
    Fecal Coliform
    302.506
    Temperature
    302.507
    Existing Sources on January 1, 1971
    302.508
    Sources under Construction But Not in Operation on January 1, 1971
    302.509
    Other Sources
    SUBPART F: PROCEDURES FOR
    DETERMINING WATER QUALITY CRITERIA
    Section
    302.601
    Scope and Applicability
    302.603
    Definitions
    302.604
    Mathematical Abbreviations
    302.606
    Data Requirements
    302.612
    Determining the Acute Aquatic Toxicity Criterion for an Individual Substance -
    General Procedures
    302.615
    Determining the Acute Aquatic Toxicity Criterion - Toxicity Independent of Water
    Chemistry
    302.618
    Determining the Acute Aquatic Toxicity Criterion - Toxicity Dependent on Water
    Chemistry
    302.621
    Determining the Acute Aquatic Toxicity Criterion - Procedures for Combinations of
    Substances
    302.627
    Determining the Chronic Aquatic Toxicity Criterion for an Individual Substance -
    General Procedures
    302.630
    Determining the Chronic Aquatic Toxicity Criterion - Procedure for Combination of
    Substances
    302.633
    The Wild and Domestic Animal Protection Criterion
    302.642
    The Human Threshold Criterion
    302.645
    Determining the Acceptable Daily Intake
    302.648
    Determining the Human Threshold Criterion
    302.651
    The Human Nonthreshold Criterion
    302.654
    Determining the Risk Associated Intake
    302.657
    Determining the Human Nonthreshold Criterion
    302.658
    Stream Flow for Application of Human Nonthreshold Criterion
    302.660
    Bioconcentration Factor
    302.663
    Determination of Bioconcentration Factor
    302.666
    Utilizing the Bioconcentration Factor
    302.669
    Listing of Derived Criteria
    Appendix A
    References to Previous Rules
    Appendix B
    Sources of Codified Sections

    32
    AUTHORITY: Implementing Section 13 and
    authorized by Section 27 of the Environmental
    Protection Act (415 ILCS 5/13 and 27).
    SOURCE: Filed with the Secretary of State January 1, 1978; amended at 2 Ill. Reg. 44, p. 151,
    effective November 2, 1978; amended at 3 Ill. Reg. 20, p. 95, effective May 17, 1979: amended at
    3 Ill. Reg. 25, p. 190, effective June 21, 1979; codified at 6 Ill. Reg. 7818, amended at 6 Ill. Reg.
    11161, effective September 7, 1982; amended at 6 Ill. Reg. 13750, effective October 26, 1982;
    peremptory amendments at 10 Ill. Reg. 461, effective December 23, 1985; amended in R87-27 at
    12 Ill. Reg. 9911, effective May 27, 1988; amended in R85-29 at 12 Ill. Reg. 12082, effective July
    11, 1988; amended in R88-1 at 13 Ill. Reg. 5998, effective April 18, 1989; amended in R88-21(A)
    at 14 Ill. Reg. 2899, effective February 13, 1990; amended in R88-21(B) at 14 Ill. Reg. 11974,
    effective July 9, 1990; amended in R94-1(A) at 20 Ill. Reg. 7682, effective May 24, 1996;
    amended in R94-1(B) at ________ Ill. Reg. _____________, effective
    __________________________________
    BOARD NOTE: This Part implements the Illinois Environmental Protection Act as of July 1,
    1994.
    Section 302.202 Purpose
    The general use standards will protect the State's water for aquatic life (except as provided in
    Section 302.213), wildlife, agricultural use, secondary contact use and most industrial uses and
    ensure the aesthetic quality of the State's aquatic environment. Primary contact uses are
    protected for all general use waters whose physical configuration permits such use.
    (Source: Amended at 20 Ill. Reg. , effective )
       
    Section 302.212 Total Ammonia Nitrogen and Un-ionized Ammonia
    a)
    Total Aammonia nitrogen (as N: STORET Storet Number 3161600610) shall in
    no case exceed 15 mg/lL.
    b) If ammonia nitrogen is less than 15 mg/1 and greater than or equal to 1.5 mg/1,
    then un-ionized ammonia (as N) shall not exceed 0.04 mg/1.
    b)
    Un-ionized ammonia nitrogen (as N: STORET Number 00612) shall not exceed
    the acute and chronic standards given below subject to the provisions of Section
    302.208(a) and (b), and 302.213.
    1)
    From April through October the Acute Standard (AS) shall be 0.33
    mg/L and the Chronic Standard (CS) shall be 0.057 mg/L.

    33
    2)
    From November through March the AS shall be 0.14 mg/L and the CS
    shall be 0.025 mg/L.
    c) Ammonia nitrogen concentrations of less than 1.5 mg/1 are lawful regardless of
    un-ionized ammonia concentration.
    cd)
    For purposes of this Ssection the concentration of un-ionized ammonia nitrogen
    as N and total ammonia nitrogen as N shall be computed according to the
    following equations:
    U = 1.0013N
    (1+10
    x
    )
    U =
    N
    [0.94412(1+10
    x
    ) + 0.0559]
      
    and N = U [0.94412(1+10
    x
    )+0.0559]
    where: X = 0.09018 + 2729.92 - pH
    (T + 273.16)
    U =
    Concentration of un-ionized ammonia as N in mg/L
    N =
    Concentration of ammonia nitrogen as N in mg/lL
    T =
    Temperature in degrees Celsius
    de)
    The following tables indicates the maximum total ammonia nitrogen
    concentrations (mg/lL as N) allowable pursuant to subsections (a) and (b) for
    certain combinations of pH and temperature
    AMMONIA NITROGEN
    WATER QUALITY STANDARD (mg/l)
    TEMP.
    pH
    0
    C
    (
    0
    F)
    6.0
    6.5
    7.0
    7.5
    8.0
    8.5
    9.0
    5
    (41)
    15
    15
    15
    9.6
    3.1
    1.5
    1.5
    10
    (50)
    15
    15
    15
    6.5
    2.1
    1.5
    1.5
    15
    (59)
    15
    15
    13.9
    4.4
    1.5
    1.5
    1.5
    20
    (68)
    15
    15
    9.6
    3.1
    1.5
    1.5
    1.5
    25
    (77)
    15
    15
    6.7
    2.1
    1.5
    1.5
    1.5
    30
    (86)
    15
    14.9
    4.7
    1.5
    1.5
    1.5
    1.5

    34
    35
    (95)
    15
    10.7
    3.4
    1.5
    1.5
    1.5
    1.5
    1) Summer (April through October) Acute- un-ionized ammonia 0.33 mg/L
    pH
    6.5
    7.0
    7.5
    7.75
    8.0
    8.25
    8.5
    9.0
    0
    F
    0
    C
    55
    12.8
    15.0
    15.0
    15.0
    15.0
    13.8
    7.9
    4.6
    1.7
    60
    15.6
    15.0
    15.0
    15.0
    15.0
    11.2
    6.5
    3.8
    1.4
    65
    18.3
    15.0
    15.0
    15.0
    15.0
    9.8
    5.3
    3.1
    1.2
    70
    21.1
    15.0
    15.0
    15.0
    13.2
    7.6
    4.4
    2.6
    1.1
    75
    23.9
    15.0
    15.0
    15.0
    10.9
    6.3
    3.7
    2.2
    0.9
    80
    26.7
    15.0
    15.0
    15.0
    9.0
    5.2
    3.1
    1.9
    0.8
    85
    29.4
    15.0
    15.0
    13.1
    7.5
    4.4
    2.6
    1.6
    0.7
    90
    32.2
    15.0
    15.0
    10.9
    6.3
    3.7
    2.2
    1.4
    0.7
    2) Summer (April through October) Chronic-un-ionized ammonia 0.057 mg/L
    pH
    6.5
    7.0
    7.5
    7.75
    8.0
    8.25
    8.5
    9.0
    0
    F
    0
    C
    55
    12.8
    15.0
    15.0
    7.4
    4.2
    2.4
    1.4
    0.8
    0.3
    60
    15.6
    15.0
    15.0
    7.0
    3.4
    1.9
    1.1
    0.7
    0.2
    65
    18.3
    15.0
    15.0
    4.9
    2.8
    1.6
    0.9
    0.5
    0.2
    70
    21.1
    15.0
    12.6
    4.0
    2.3
    1.3
    0.8
    0.5
    0.2
    75
    23.9
    15.0
    10.3
    3.3
    1.9
    1.1
    0.6
    0.4
    0.2
    80
    26.7
    15.0
    8.6
    2.7
    1.6
    0.9
    0.5
    0.3
    0.1
    85
    29.4
    15.0
    7.8
    2.3
    1.3
    0.8
    0.4
    0.3
    0.1
    90
    32.2
    15.0
    5.8
    1.9
    1.1
    0.6
    0.4
    0.2
    0.1
    3) Winter (November through March) Acute un-ionized ammonia 0.14 mg/L
    pH
    6.5
    7.0
    7.5
    7.75
    8.0
    8.25
    8.5
    9.0
    0
    F
    0
    C
    32
    0.0
    15.0
    15.0
    15.0
    15.0
    15.0
    9.2
    5.2
    1.7
    35
    1.7
    15.0
    15.0
    15.0
    15.0
    14.1
    8.0
    4.5
    1.5
    40
    4.4
    15.0
    15.0
    15.0
    15.0
    11.3
    6.4
    3.7
    1.3
    45
    7.2
    15.0
    15.0
    15.0
    15.0
    9.0
    5.1
    2.9
    1.0
    50
    10.0
    15.0
    15.0
    15.0
    12.8
    7.3
    4.1
    2.4
    0.9
    55
    12.8
    15.0
    15.0
    15.0
    10.3
    5.9
    3.4
    2.0
    0.7
    60
    15.6
    15.0
    15.0
    14.8
    8.4
    4.8
    2.7
    1.6
    0.6
    4) Winter (November through March) Chronic un-ionized ammonia 0.025 mg/L
    pH
    6.5
    7.0
    7.5
    7.75
    8.0
    8.25
    8.5
    9.0

    35
    0
    F
    0
    C
    32
    0.0
    15.0
    15.0
    9.1
    5.1
    2.9
    1.6
    0.9
    0.3
    35
    1.7
    15.0
    15.0
    7.9
    4.4
    2.5
    1.4
    0.8
    0.3
    40
    4.4
    15.0
    15.0
    6.3
    3.6
    2.0
    1.1
    0.7
    0.2
    45
    7.2
    15.0
    15.0
    5.0
    2.8
    1.6
    0.9
    0.5
    0.2
    50
    10.0
    15.0
    12.7
    4.0
    2.3
    1.3
    0.7
    0.4
    0.2
    55
    12.8
    15.0
    10.2
    3.3
    1.8
    1.0
    0.6
    0.3
    0.1
    60
    15.6
    15.0
    8.3
    2.6
    1.5
    0.9
    0.5
    0.3
    0.1
    (Source: Amended at 20 Ill. Reg. , effective )
    Section 302.213 Effluent Modified Waters (Ammonia)
    a) Effluent modified waters are those waters or portions of waters that the Agency
    has determined pursuant to 35 Ill. Adm. Code 309, Subpart A, to have the
    potential to exceed, and are therefore not subject to, the chronic ammonia
    standards of Section 302.212(b) downstream of an effluent outfall and outside of
    any allowable mixing zone. The Agency shall not identify a waterbody as an
    effluent modified water if it:
    1) has uses known to be adversely impacted by ammonia as designated
    under 35 Ill. Adm. Code 303.201 outside of any allowable mixing zone;
    or
    2)
    exceeds the acute standard of Section 302.212(b).
    b) All effluent discharges to an effluent modified water must meet the requirements
    of 35 Ill. Adm. Code 304.122(d) prior to dilution with the receiving water.
    (Source: Added at 20 Ill. Reg. ________________, effective _________________________)
    TITLE 35: ENVIRONMENTAL PROTECTION
    SUBTITLE C: WATER POLLUTION
    CHAPTER I: POLLUTION CONTROL BOARD
    PART 304
    EFFLUENT STANDARDS
    SUBPART A: GENERAL EFFLUENT STANDARDS
    Section
    304.101
    Preamble
    304.102
    Dilution

    36
    304.103
    Background Concentrations
    304.104
    Averaging
    304.105
    Violation of Water Quality Standards
    304.106
    Offensive Discharges
    304.120
    Deoxygenating Wastes
    304.121
    Bacteria
    304.122
    Total Ammonia Nitrogen (as N: STORET number 00610)
    304.123
    Phosphorus (STORET number 00665)
    304.124
    Additional Contaminants
    304.125
    pH
    304.126
    Mercury
    304.140
    Delays in Upgrading (Repealed)
    304.141
    NPDES Effluent Standards
    304.142
    New Source Performance Standards (Repealed)
    SUBPART B: SITE SPECIFIC RULES AND
    EXCEPTIONS NOT OF GENERAL APPLICABILITY
    Section
    304.201
    Wastewater Treatment Plant Discharges of the Metropolitan Sanitary District of
    Greater Chicago
    304.202
    Chlor-alkali Mercury Discharges in St. Clair County
    304.203
    Copper Discharges by Olin Corporation
    304.204
    Schoenberger Creek: Groundwater Discharges
    304.205
    John Deere Foundry Discharges
    304.206
    Alton Water Company Treatment Plant Discharges
    304.207
    Galesburg Sanitary District Deoxygenating Wastes Discharges
    304.208
    City of Lockport Treatment Plant Discharges
    304.209
    Wood River Station Total Suspended Solids Discharges
    304.210
    Alton Wastewater Treatment Plant Discharges
    304.211
    Discharges From Borden Chemicals and Plastics Operating Limited Partnership
    Into an Unnamed Tributary of Long Point Slough
    304.212
    Sanitary District of Decatur Discharges
    304.213
    UNO-VEN Refinery Ammonia Discharge
    304.214
    Mobil Oil Refinery Ammonia Discharge
    304.215
    City of Tuscola Wastewater Treatment Facility Discharges
    304.216
    Newton Station Suspended Solids Discharges
    304.218
    City of Pana Phoshorus Discharge
    304.219
    North Shore Sanitary District phosphorus Discharges
    304.220
    East St. Louis Treatment Facility, Illinois-American Water Company
    304.221
    Ringwood Drive Manufacturing Facility in McHenry County
    304.222
    Intermittent Discharge of TRC
    SUBPART C: TEMPORARY EFFLUENT STANDARDS

    37
    Section
    304.301
    Exception for Ammonia Nitrogen Water Quality Violations (Repealed)
    304.302
    City of Joliet East Side Wastewater Treatment Plant
    304.303
    Amerock Corporation, Rockford Facility
    Appendix A
    References to Previous Rules
    AUTHORITY: Implementing Section 13 and authorized by Section 27 of the Environmental
    Protection Act (415 ILCS 5/13 and 27).
    SOURCE: Filed with the Secretary of State January 1, 1978; amended at 2 Ill. Reg. 30, p.
    343, effective July 27, 1978; amended at 2 Ill. Reg. 44, p. 151, effective November 2, 1978;
    amended at 3 Ill. Reg. 20, p. 95, effective May 17, 1979; amended at 3 Ill. Reg. 25, p. 190,
    effective June 21, 1979; amended at 4 Ill. Reg. 20, p. 53 effective May 7, 1980; amended at 6
    Ill. Reg. 563, effective December 24, 1981; codified at 6 Ill. Reg. 7818: amended at 6 Ill.
    Reg. 11161, effective September 7, 1982; amended at 6 Ill. Reg. 13750, effective October 26,
    1982; amended at 7 Ill. Reg. 3020, effective March 4, 1983; amended at 7 Ill. Reg. 8111,
    effective June 23, 1983; amended at 7 Ill. Reg. 14515, effective October 14, 1983; amended
    at 7 Ill. Reg. 14910, effective November 14, 1983; amended at 7 Ill. Reg. 14910, effective
    November 14, 1983; amended at 8 Ill. Reg. 1600, effective January 18, 1984; amended at 8
    Ill. Reg. 3687, effective March 14, 1984; amended at 8 Ill. Reg. 8237, effective June 8, 1984;
    amended at 9 Ill. Reg. 1379, effective January 21, 1985; amended at 9 Ill. Reg. 4510,
    effective March 22, 1985; peremptory amendment at 10 Ill. Reg. 456, effective December 23,
    1985; amended at 11 Ill. Reg. 3117, effective January 28, 1987; amended in R84-13 at 11 Ill.
    Reg. 7291 effective April 3, 1987; amended in R86-17(A) at 11 Ill. Reg. 14748, effective
    August 24, 1987; amended in R84-16 at 12 Ill. Reg. 2445, effective January 15, 1988;
    amended in R83-23 at 12 Ill. Reg. 8658, effective May 10, 1988; amended in R87-27 at 12
    Ill. Reg. 9905, effective May 27, 1988; amended in R82-7 at 12 Ill. Reg. 10712, effective
    June 9, 1988; amended in R85-29 at 12 Ill. Reg. 12064, effective July 12, 1988; amended in
    R87-22 at 12 Ill. Reg. 13966, effective August 23, 1988; amended in R86-3 at 12 Ill. Reg.
    20126, effective November 16, 1988; amended in R84-20 at 13 Ill. Reg. 851, effective
    January 9, 1989; amended in R85-11 at 13 Ill. Reg. 2060, effective February 6, 1989;
    amended in R88-1 at 13 Ill. Reg. 5976, effective April 18, 1989; amended in R86-17B at 13
    Ill. Reg. 7754, effective May 4, 1989; amended in R88-22 at 13 Ill. Reg. 8880, effective May
    26, 1989; amended in R87-6 at 14 Ill. Reg. 6777, effective April 24, 1990; amended in R87-
    36 at 14 Ill. Reg. 9437, effective May 31, 1990; added at 14 Ill. Reg. 11979, effective July 9,
    1990; amended in R84-44 at 14 Ill. Reg. 20719, effective December 11, 1990; amended in
    R86-14 at 15 Ill. Reg. 241, effective December 18, 1990; amended in R87-33 at 18 Ill. Reg.
    11574, effective July 7, 1994; amended in R95-14 at 20 Ill. Reg. 3528, effective February 8,
    1996; amended in R94-1 (B) at 20 Ill. Reg. , effective
           

    38
    BOARD NOTE: This Part implements the
    Illinois Environmental Protection Act as of
    July 1, 1994.
    Section 304.122 Total Ammonia Nitrogen (as N: STORET number 00610)
    a)
    No effluent from any source which discharges to the Illinois River, the Des
    Plaines River downstream of its confluence with the Chicago River System or
    the Calumet River System, and whose untreated waste load is 50,000 or more
    population equivalents shall contain more than 2.5 mg/lL of total ammonia
    nitrogen as N during the months of April through October, or 4 mg/lL at other
    times.
    b)
    Sources discharging to any of the above waters and whose untreated waste load
    cannot be computed on a population equivalent basis comparable to that used for
    municipal waste treatment plants and whose total ammonia nitrogen as N
    discharge exceeds 45.4 kg/day (100 pounds per day) shall not discharge an
    effluent of more than 3.0 mg/lL of total ammonia nitrogen as N.
    c)
    In addition to the effluent standards set forth in subsections (a) and (b) above,
    all sources are subject to Section 304.105 unless the Agency determines as part
    of the NPDES Permit Program under 35 Ill. Adm. Code 309, Subpart A that
    alternate effluent standards are applicable pursuant to subsection (d) of this
    section.
    d)
    All dischargers to effluent modified waters as defined at 35 Ill. Adm. Code
    302.213, except for treatment works qualifying under Section 304.120(c) shall
    have an effective NPDES permit with monthly average effluent limits of 1.5
    mg/L total ammonia as N during the months of April through October, and 4.0
    mg/L total ammonia as N at other times, as well as the following restrictions:
    1)
    Dischargers achieving lower ammonia concentrations than given above,
    yet not meeting the chronic water quality standards of 35 Ill. Adm. Code
    302.212(b), shall maintain their existing level of performance consistent
    with the facility's expected organic and hydraulic loadings for the
    duration of their NPDES permit.
    2)
    New or expanded discharges that increase ammonia loading to general
    use waters and/or create effluent modified waters or portions of waters
    must demonstrate compliance to the Agency with the nondegradation
    requirements at 35 Ill. Adm. Code 302.105.
    (Source: Amended at 20 Ill. Reg. ____________, effective )
    SUBPART C: TEMPORARY EFFLUENT STANDARDS

    39
    Section 304.301 Exception for Ammonia Nitrogen Water Quality Violations (Repealed)
    a) Section 304.105 shall not apply to 35 Ill. Adm. Code 302.212 for any source
    during the months of November through March; except that during the months
    of November through March no source shall discharge an effluent containing a
    concentration of ammonia nitrogen greater than 4.0 mg/1 if the discharge, alone
    or in combination with other discharges, causes or contributes to a violation of
    35 Ill. Adm. Code 302.212.
    b) Compliance with the provisions of subsection (a) shall be achieved by March
    31, 1979, or such other date as required by NPDES permit, or as ordered by the
    Board Under Title VIII or Title IX of the Environmental Protection Act.
    c) After July 1, 1991, the exemption provided in this Section shall terminate.
    (Source: Repealed at 20 Ill. Reg. ______________, effective )
           
    IT IS SO ORDERED.
    I, Dorothy M. Gunn, Clerk of the Illinois Pollution Control Board, hereby certify that the
    above opinion and order was adopted on the day of , 1996, by
    a vote of .
    Dorothy M. Gunn, Clerk
    Illinois Pollution Control Board

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