ILLINOIS POLLUTION CONTROL BOARD
    August 1, 1996
    IN MATTER OF:
    LISTING OF FEDERAL HAZARDOUS AIR
    POLLUTANTS, GREAT LAKES
    COMMISSIONS TOXIC COMPOUNDS
    AND GREAT WATERS PROGRAM TOXIC
    COMPOUNDS, AND SOURCE
    REPORTING FOR ILLINOIS TOXIC AIR
    CONTAMINANTS: AMENDMENTS TO 35
    ILL. ADM. CODE 232
    )
    )
    )
    )
    )
    )
    )
    )
    )
    )
    R96-4
    (Rulemaking - Air)
    Proposed Rule. First Notice.
    OPINION AND ORDER OF THE BOARD (by J. Yi):
    Pursuant to Sections 9.5, 27 and 28 of the Environmental Protection Act (Act) (415
    ILCS 5/9.5, 27 and 28), the Illinois Environmental Protection Agency (Agency) filed this
    rulemaking proposal on October 13, 1995. In addition to the proposal the Agency filed a
    motion to waive certain filing requirements, to expedite the hearing process and to consolidate
    R90-1(C), In the Matter of: Toxic Air Contaminant List (35 Ill. Adm. Code 232); Reporting
    Requirements for Emission Sources and R90-1(D), In the Matter of: Toxic Air Contaminant
    List, Styrene (35 Ill. Adm. Code 232.Appendix A), into this proceeding.
    In our order of November 2, 1995 we granted the Agency's motions and found that the
    filing met the requirements of Sections 27 and 28 of the Act. The Board also accepted this
    matter for hearing and directed the hearing officer to set this matter for hearing. Additionally,
    the Board, in separate orders closed the dockets in both R90-1(C) and (D).
    The Board held two hearings in this matter. The first hearing was held on February
    23, 1996 in Springfield, Illinois. The second hearing was held on April 9, 1996 in Chicago,
    Illinois. The post-hearing comment period ended May 17, 1996.
    Today the Board acts to send this rulemaking proposal for first notice. Pursuant to
    Section 5.01 of the Illinois Administrative Procedure Act (IAPA) and Section 102.342 of the
    Board's procedural rules, the IAPA 45-day public comment period will commence upon
    publication of today's proposal in the Illinois Register, during which the Board will accept
    written comments from any person. Persons interested in providing additional comment on
    this proposal should submit such comments in writing to the Clerk of the Board prior to the
    expiration of this 45-day period.
    The Board will not hold any hearings beyond those that have
    already been held unless a written request for hearing is received by the Clerk of the Board.

    2
    PURPOSE OF PROPOSAL
    The proposal has two (2) main purposes both of which are connected to the Illinois's
    Toxic Air Contaminants (ITAC) list. First, the proposal intends to update the ITAC by adding
    chemicals or substances either listed as federal Hazardous Air Pollutants (HAPs) under Section
    112(b) of the Clean Air Act (CAA) as amended in 1990, or targeted as chemicals or
    compounds of concern under the United States Environmental Protection Agency's (USEPA)
    "Great Waters" program under Section 112(m) of the CAA to 35 Ill. Adm. Code
    232.Appendix A. In addition to updating ITAC, the proposal will require all sources that meet
    the applicability criteria to submit an ITAC Source Report for the calendar year 1996. Finally
    the proposal will correct typographical errors in the current ITAC list.
    PROPOSED AMENDMENTS
    This portion of the opinion will discuss the proposed amendments to 35 Ill. Adm. Code
    232 section by section.
    Section 232.120 Definitions
    The proposed amendments to Section 232.120 are to delete definitions no longer
    applicable to this Part as a result of revisions to 35 Ill. Adm. Code 211 and to add definitions
    of “commercial fuel”, “Illinois Toxic Air Contaminant” (ITAC), “ITAC Source Report”,
    “manufacture”, “otherwise use”, “prices”, and “Toxic Air Contaminant” (TAC). The
    definition of “commercial fuel” is necessary because Section 9.5(e)(3) of the Act exempts
    emissions of ITACs from combustion processes using commercial fuel from the source
    reporting requirements. The definitions of “manufacture”, “otherwise use” and “process”
    have also been added to address applicability thresholds, and these definitions are identical in
    substance to those in Section 313 of the Emergency Planning and Community Right-to Know
    Act, Title III of Superfund Amendments and Reauthorization Act of 1986 (SARA 313) (42
    U.S.C. 11001
    et seq
    .) The definitions of ITAC and TAC have been added to delineate only
    those chemicals listed in Appendix A that are subject to this proposal. “ITAC Source Report”
    has been added as a definition to address what information is required to be reported under this
    proposal.
    Section 232.120 has also been revised to delete the definitions of “New emission
    source” and “Process unit” since these definitions are inconsistent with, or are no longer
    necessary because of, earlier revisions to Part 211.
    The Agency’s proposal to the Board suggested that the definition of “‘Emits’ or
    ‘Emissions’ or ‘Emitted’”, be deleted because of earlier revisions to Part 211. However
    contained in the definition of “‘Emits’ or ‘Emissions’ or ‘Emitted’”, is the definition of
    “Fugitive emission” which is not defined in either Part 201 or 211. The definition of
    “Fugitive emission” is at Section 203.124. Since Parts 201 and 211 do not contain a

    3
    definition of “Fugitive emission” we will delete the definition of “‘Emits’ or ‘Emissions’ or
    ‘Emitted’” but retain the definition for “Fugitive emission”.
    Subpart D: Source Identification Requirements
    Sections 232.400 through 232.460, contain the requirements relating to source
    reporting. Section 232.400 states the purpose of Subpart D.
    Section 232.410(a) provides the applicability threshold: any source that manufactures,
    processes, or imports 25,000 lbs. or more of any individual ITAC in any calendar year; or
    otherwise uses 10,000 lbs. of any individual ITAC in any calendar year. Section 232.410(b)
    lists those processes or operations that are not subject to Subpart D, and incorporates the
    exemptions in Section 9.5(e) of the Act. Section 232.410(c) provides for an additional
    applicability threshold, beyond the threshold in 232.410(a).
    Section 232.420 provides that the Agency will supply to all sources expected to be
    affected by this proposal an ITAC Source Report that contains all the data fields required by
    Subpart D. This report is designed to assist affected sources in complying with the
    requirements of Subpart D, although the information need not be submitted on this form. The
    ITAC Source Report form is similar to the form being utilized through SARA 313.
    Section 232.421 requires that all emission reports submitted pursuant to Subpart D be
    certified, and specifies the criteria for a certifying individual, as well as the required
    certification.
    Section 232.423 provides that the failure of an affected source to receive an ITAC
    Source Report from the Agency does not relieve a source from the obligation to file an
    emissions report.
    Section 232.430(a) specifies the date by which a source must file an emissions report
    and lists the information required to be submitted. Section 232.430(b) lists which emissions of
    ITACs are considered to be
    de minimis
    and therefore not subject to reporting. Section
    232.430(c) specifies the date for reporting for sources that become subject to this proposal
    after January 1, 1996. Section 232.430(d), (e), and (f) list when a source must submit a
    revised emissions report to the Agency.
    Section 232.440 allows a source to use engineering estimates to determine emissions if
    the type of estimate is reasonable, is specified, is the best information available, and notes that
    this Subpart does not require monitoring or testing in connection with these emissions reports.
    Section 232.450(a) provides that the Agency may request additional information,
    beyond that initially submitted or specified in Section 232.430. Section 232.450(b) specifies
    that a source must retain records upon which the data included in the emissions report is based

    4
    for a minimum period of three years, and must make these records available to the Agency
    upon request.
    Section 232.460 requires a source to correct any errors in the data previously submitted
    within 60 days of discovering such error.
    Subpart E: Listing and Delisting
    Section 232.501 contains an explanation for the inclusion of the chemicals and
    compound listed as HAPs under Section 112(b) of the CAA and for the inclusion of the “Great
    Waters” program targeted compounds under Section 112(m) of the CAA, and exempts these
    new compounds from the listing requirements of Section 232.500.
    Section 232.Appendix A List of Toxic Air Contaminants
    Appendix A has been amended to add the HAPS and Great Waters TACs not previously listed,
    and to denote the compounds as either HAPs, Great Water TACs, or both. Furthermore,
    Appendix A has also been revised to correct typographical errors and errors in the Chemical
    Abstract Service (CAS) numbers for previously listed chemicals.
    ORDER
    The Board hereby proposes the following regulations for First Notice pursuant to the
    IAPA. The Board directs the Clerk to cause publication of these regulations in the Illinois
    Register for first notice. (The text starts on the following page.)

    5
    TITLE 35: ENVIRONMENTAL PROTECTION
    SUBTITLE B: AIR POLLUTION
    CHAPTER I: POLLUTION CONTROL BOARD
    SUBCHAPTER f: TOXIC AIR CONTAMINANTS
    PART 232
    TOXIC AIR CONTAMINANTS
    SUBPART A: GENERAL PROVISIONS
    Section
    232.100
    Introduction
    232.110
    Incorporations by Reference
    232.120
    Definitions (Repealed)
    232.130
    Applicability
    SUBPART B: DETERMINATION OF A TOXIC AIR
    CONTAMINANT
    Section
    232.200
    Characteristics for Determining a Toxic Air Contaminant
    SUBPART C: PROCEDURES FOR EVALUATING
    CHARACTERISTICS OF A TOXIC AIR CONTAMINANT
    Section
    232.300
    Purpose
    232.310
    Procedures for Determining the Toxicity Score
    232.320
    Carcinogen Classification
    SUBPART D: SOURCE IDENTIFICATION REQUIREMENTS
    Section
    232.400
    Purpose
    232.410
    Applicability
    232.420
    ITAC Source Report
    232.421
    Emissions Report Certification
    232.423
    Failure to Receive an ITAC Source Report
    232.430
    Emissions Report
    232.440
    Use of Available Data
    232.450
    Retention of Records
    232.460
    Reporting of Errors
    SUBPART E: LISTING AND DELISTING

    6
    Section
    232.500
    Procedures for Listing and Delisting Toxic Air Contaminants
    232.501
    Listing of Federal Hazardous Air Pollutants, Great Lakes Commission Toxic
    Compounds and Great Waters Program Toxic Compounds
    APPENDIX A:
    List of Toxic Air Contaminants
    APPENDIX B:
    Additional Procedures for Calculating the Chronic Toxicity Score
    APPENDIX C:
    Carcinogens (Categories A, B1, and B2) listed on the Integrated Risk
    Information System (IRIS) as of December 31, 1989 (United States
    Environmental Protection Agency, Office of Health and Environmental
    Assessment)
    AUTHORITY: Implementing Section 9.5 and authorized by Section 27 of the Environmental
    Protection Act [415 ILCS 5/9.5 and 27].
    SOURCE: Adopted in R90-1 at 16 Ill. Reg. 16592, effective October 18, 1992; amended in
    R__-__ at _____ Ill. Reg. __________, effective ______________199_.
    SUBPART A: GENERAL PROVISIONS
    Section 232.120
    Definitions (Repealed)
    The definitions of 35 Ill. Adm. Code 201.102, 211.122 and 215.104, 201 and 211 apply to
    this Part, as well as the definitions contained in this Section. Where a definition contained in
    this Section is more specific than those found in 35 Ill. Adm. Code 201.102, 211.122 and
    215.104 201 and 211, it must take precedence in application of this Part.
    "ACGIH" means the American Conference of Governmental Industrial Hygienists.
    "Adverse health effect" means a health injury or disease that may be produced by
    exposure to a contaminant. This includes any decrement in the function of an organ or
    organ system or any subclinical organ lesion that is likely to lead to a decrement in an
    organ or organ system function.
    "Commercial fuel" means:
    a)
    Any fuel offered for final sale for use in combustion processes;
    b)
    Any gaseous fuel generated as a by-product at a source for which the source has
    been issued an operating permit to use such fuel internally in combustion
    processes, including internal combustion engines; or

    7
    c)
    Any waste derived fuel for which an operating permit has been issued and
    which represents no more than five percent (.05) by weight on a daily basis of
    total fuel used in combustion processes by a source.
    "Critical gestation days" means the days during which the formation and differentiation
    of organs and organ systems occurs during embryonic development.
    "Emits" or "Emission" or "Emitted" means any non-accidental release into the
    atmosphere from an emission source or air pollution control equipment, or fugitive
    emissions defined according to 35 Ill. Adm. Code 203.124.
    “Fugitive emissions” is defined according to 35 Ill. Adm. Code 203.124.
    "IARC" means the World Health Organization's International Agency for Research on
    Cancer.
    "IRIS" means the USEPA's Integrated Risk Information System.
    "Illinois Toxic Air Contaminant" (ITAC) means any toxic air contaminant listed
    pursuant to 35 Ill. Adm. Code 232, excluding, specifically: coke oven gas; any
    hazardous air pollutant (HAP) now or hereafter listed under Section 112(b) of the
    Clean Air Act (CAA), as amended; and any pollutant or contaminant listed as a
    compound of concern under the Great Waters Program under Section 112(m) of the
    CAA.
    "ITAC Source Report" means the report that the Agency provides to the source that
    lists data fields for the information required in the emissions report for Subpart D of
    this Part, and contains the information, if any, that previously has been reported to the
    Agency for those data fields.
    "LC50" means the concentration in the air of a contaminant that kills, or is estimated to
    kill, fifty percent (.50) of a population of laboratory animals where the exposure is
    brief (8 hours or less) and where the route of exposure is inhalation.
    "LD50" means the dose of a contaminant that kills, or is estimated to kill, 50 percent
    of a population of laboratory animals where the route of exposure is ingestion.
    "Lowest observed adverse effect level" means the lowest experimentally determined
    dose at which a statistically or biologically significant indication of the toxic effect of
    concern is observed.
    "Manufacture" means, for the purposes of 35 Ill. Adm. Code Sections 232.400 through
    232.460 of this Part, to produce, prepare, or compound a listed ITAC, and includes
    coincidental production of an ITAC (e.g., as a by-product or impurity) as a result of

    8
    the manufacture, processing or otherwise use or treatment of one or more chemical
    substances not an ITAC. An ITAC intentionally incorporated into a product is
    considered to be manufactured.
    "NTP" means the United States' Department of Health and Human Services, Public
    Health Services' National Toxicological Program.
    "New emission source" means an emission source or air pollution control equipment
    for which a construction permit is required by 35 Ill. Adm. Code 201 after (the
    effective date of these rules); or an emission source or air pollution control equipment
    for which an operating permit is required by 35 Ill. Adm. Code 201, where the owner
    or operator failed to apply for a construction permit and applies for the first operating
    permit.
    "No observed effect" means the condition where no adverse health effect has been
    detected.
    "Otherwise use" means, for the purposes of 35 Ill. Adm. Code Sections 232.400
    through 232.460 of this Part, any activity involving a listed ITAC at a source that does
    not fall within the definitions of "manufacture" or "process."
    "Process" means, for the purposes of 35 Ill. Adm. Code Sections 232.400 through
    232.460 of this Part, the preparation of an ITAC after its manufacture for distribution
    in commerce in the same physical state as, or in a different form or physical state from,
    that in which it was received by the source, or preparation that produces a change in
    physical state or chemical form.
    "Process unit" shall have the meaning set forth in 35 Ill. Adm. Code Section 211.5210.
    "Toxic air contaminant" (TAC) means a contaminant identified pursuant to Section
    232.200 or Section 232.501 of this Part and listed in Appendix A of this Part.
    (Source: Amended at _____ Ill. Reg. __________, effective ______________199_.)
    SUBPART D: SOURCE IDENTIFICATION REQUIREMENTS
    Section 232.400
    Purpose
    This Subpart establishes identification and reporting requirements for new and existing sources
    that emit Illinois Toxic Air Contaminants.
    (Source: Added at _____ Ill. Reg. _______, effective ______________199_.)
    Section 232.410
    Applicability

    9
    a)
    This Subpart shall apply to any owner or operator of a source that
    manufactures, processes or imports 25,000 lbs or more of any individual ITAC
    in any calendar year or otherwise uses 10,000 lbs of any individual ITAC in any
    calendar year.
    b)
    This Subpart shall not apply to the following:
    1)
    Retail dry cleaning operations;
    2)
    Retail and noncommercial storage and handling of motor fuels;
    3)
    Combustion processes, including internal combustion engines, using only
    commercial fuel; and
    4)
    Equipment and operations which are exempt from permitting
    requirements pursuant to 35 Ill. Adm. Code 201.146;
    c)
    If an ITAC is present in a mixture of chemicals at a source at a concentration
    below one percent (0.01) by weight, or one-tenth of one percent (.001) by
    weight in the case of an ITAC which is a carcinogen listed in Appendix C of
    this Part, an owner or operator subject to this Subpart is not required to consider
    the quantity of the ITAC in such mixture when determining whether an
    applicable threshold has been met under subsection (a) of this Section or in
    determining the amount of emissions to be reported under Section 232.430 of
    this Part.
    (Source: Added at _____ Ill. Reg. ______, effective ______________199_.)
    Section 232.420
    ITAC Source Report
    a)
    On or before April 1, 1997, the Agency shall provide to the owner or operator
    of a source subject to this Subpart the ITAC Source Report. The ITAC Source
    Report shall contain all data fields for the information required under this
    Subpart.
    b)
    The information on emissions provided by the owner or operator of a source in
    the emissions report shall be based on the best information available to the
    owner or operator and that is reflective of the operations of the source and its
    ITAC emissions.
    (Source: Added at _____ Ill. Reg. _____, effective ______________199_.)
    Section 232.421
    Emissions Report Certification

    10
    All emission reports filed pursuant to this Subpart shall contain the following certification
    statement: "All emissions data verified, modified or provided on behalf of the source named
    above represents the best available information and is true and accurate to the best of my
    knowledge." The certification statement shall be signed by an individual responsible for the
    accuracy of the emissions report and who will take legal responsibility for the information
    verified or reported therein. The certification statement shall be accompanied by the full
    name, title, actual signature, date of signature, and a telephone number of the individual
    signing the emissions report.
    (Source: Added at _____ Ill. Reg. _____, effective ______________199_.)
    Section 232.423
    Failure to Receive an ITAC Source Report
    Failure to receive the ITAC Source Report from the Agency shall not relieve an owner or
    operator from the obligation to file a complete emissions report. Any owner or operator who
    does not receive the ITAC Source Report on or before April 1, 1997, may contact the Agency
    to request the ITAC Source Report.
    (Source: Added at _____ Ill. Reg. _____, effective ______________199_.)
    Section 232.430
    Emissions Report
    a)
    On or before July 1, 1997, the owner or operator of a source subject to this
    Subpart shall file an emissions report for the calendar year 1996 which shall
    include the following information:
    1)
    Source identification information; and
    2)
    Identify by generic name and Chemical Abstract Service (CAS) number,
    the source’s actual annual emissions of each ITAC expressed in tons per
    year (TPY), and the source's annual fugitive emissions of each ITAC,
    expressed in TPY, for each ITAC that exceeds the threshold for
    applicability as set forth in Section 232.410 of this Part. In determining
    the actual annual emissions of each ITAC, the source may exclude
    emissions of such ITAC from all emission units with de minimis
    emissions of ITACs.
    b)
    The following emissions of ITACs shall be considered to be de minimis and
    shall not be subject to reporting requirements under this Subpart:
    1)
    Emissions of ITACs from an emission unit which, in the aggregate, are
    less than one-half (0.5) TPY;

    11
    2)
    Emissions from a process unit resulting from a process vent stream with
    ITAC concentrations that are always less than one-tenth of one percent
    (0.001) by weight on a daily basis, if such concentrations include any
    carcinogen listed in Appendix C of this Part;
    3)
    Emissions from a process unit resulting from a process vent stream with
    ITAC concentrations that are always less than one percent (0.01) by
    weight on a daily basis, if such concentrations do not include any
    carcinogen listed in Appendix C of this Part; or
    4)
    Fugitive emissions of ITACs from a process unit which, in the
    aggregate, are less than one-half (0.5) TPY.
    c)
    If a source becomes subject to this Subpart on or after January 1, 1996, the
    owner or operator of the source shall submit an emissions report to the Agency
    on or before July 1 of the year following the date the source becomes subject to
    this Subpart for the period from the date the source first becomes subject to this
    Subpart through the end of the calendar year before the year the first report
    from such source is due under this Subpart. Such emissions report shall contain
    all of the information listed in subsections (a)(1), (a)(2), and (a)(3) of this
    Section and any additional information requested by the Agency pursuant to
    Section 232.450 of this Part. Any such emissions report shall satisfy the
    requirements of Sections 232.410, 232.420, 232.421, 232.423, 232.430,
    232.440, 232.450, and 232.460 of this Part.
    d)
    An owner or operator of a source subject to this Subpart shall submit to the
    Agency a revised, correct emissions report on or before July 1 of the year
    following the occurrence of any of the following:
    1)
    If the source's actual annual emissions of any individual ITAC or any
    combination of ITACs required to be reported under this Subpart
    increases by more than one-half (0.50) TPY or one (1) TPY,
    respectively, from the sources' emissions of ITACs initially reported
    under this Subpart; or
    2)
    If the source emits an ITAC that exceeds the threshold for applicability
    as set forth in Section 232.410 of this Part which was not previously
    reported in the source's initial report of its emissions of ITACs or in any
    subsequent revised report of its emissions of ITACs required to be
    submitted pursuant to this subsection.
    e)
    Any revised emissions report required to be submitted under subsection (d) of
    this Section shall contain all of the information listed in subsection (a) of this
    Section and any additional information requested by the Agency pursuant to

    12
    Section 232.450 of this Part. Any revised emissions report shall satisfy the
    requirements of Sections 232.410, 232.420, 232.421, 232.423, 232.430
    232.440, 232.250, and 232.450 of this Part.
    f)
    By July 1 of the calendar year following any modification or change to an
    emission unit requiring a revision to an existing permit or a new permit and
    which may result in an increase in emissions of a previously reported ITAC by
    ten percent (.10) or more, an owner or operator of a source subject to this
    Subpart shall submit to the Agency a revised emissions report which includes
    the information required under Section 232.430 of this Part.
    (Source: Added at _____ Ill. Reg. _____, effective _______________199_.)
    Section 232.440
    Use of Available Data
    a)
    In order to provide the information required under this Subpart, the owner or
    operator of a source may:
    1)
    Use reasonable engineering estimates of total emissions of individual
    ITACs pursuant to an emissions determination method, if, in each case,
    the owner or operator of a source specifies the emissions determination
    method used to estimate total emissions and certifies that such data
    represents the best available information and is true and accurate to the
    best of his/her knowledge; or
    2)
    If available, monitoring or measuring data collected pursuant to other
    provisions of law or regulation.
    b)
    Nothing in this Subpart requires the monitoring or measurement of the
    quantities, concentrations, or frequency of emissions of any ITAC beyond any
    monitoring or measurement required under other provisions of law or
    regulation.
    (Source: Added at _____ Ill. Reg. _____, effective ______________199_.)
    Section 232.450
    Retention of Records/ Additional Information
    a)
    For purposes of modeling and conducting assessments of information submitted
    under this Subpart, the Agency may request supporting documentation or
    additional information for any emissions report submitted by a source,
    including:
    1)
    An identification by generic name and Chemical Abstract Service (CAS)
    number the source’s emissions of each ITAC by emission unit, with

    13
    maximum hourly emission rates in lbs/hr and actual annual emissions in
    TPY and the source's fugitive emissions of each ITAC in TPY;
    2)
    Operating data, exhaust point information and, if applicable, control
    device information for each emission unit; and
    3)
    Copies of engineering estimate calculations, mass balance calculations,
    and any other information or documentation used by the owner or
    operator of a source in preparing an emissions report.
    b)
    All records and calculations upon which the data submitted in the emissions
    report are based must be retained by the source for a minimum of three (3)
    years following the filing of a complete report. The owner or operator of a
    source shall provide the requested information in a format acceptable to the
    Agency within 60 days after the receipt of the request.
    c)
    Nothing in this Section shall be interpreted to impose upon any source subject to
    this Subpart any additional monitoring which is not otherwise required by
    applicable rules or a permit condition.
    (Source: Added at _____ Ill. Reg. _____, effective ______________199_.)
    Section 232.460
    Reporting of Errors
    If, after submitting any emissions report required by this Subpart, the owner or operator of a
    source discovers any error in the data reported, the owner or operator shall notify the Agency
    of the error in writing and shall provide the Agency with the correct data. The notification
    and correction shall be conveyed to the Agency within sixty (60) days after the owner's or
    operator's discovery of the error. The corrected data shall be certified in accordance with
    Section 232.421 of this Part.
    (Source:
    Added at _____ Ill. Reg. ______, effective ______________199_.)
    SUBPART E: LISTING AND DELISTING
    Section 232.501
    Listing of Federal Hazardous Air Pollutants, Great Lakes Commission
    Toxic Compounds and Great Waters Program Toxic Compounds
    Notwithstanding the provisions of Section 232.500 of this Part, all chemicals listed as
    "hazardous air pollutants" under Section 112(b) of the CAA, as amended in 1990 (42 U.S.C.
    7412(b)), and all chemicals targeted as toxic compounds or chemicals by the Great Lakes
    Commission or under the United States Environmental Protection Agency's "Great Waters"
    Program which are not currently listed as toxic air contaminants under this Part, are hereby
    listed as toxic air contaminants under Appendix A of this Part. The listing of hazardous air

    14
    pollutants and other toxic compounds or chemicals as toxic air contaminants under this Section
    is without reference to the listing procedures of Section 232.500 of this Part.
    (Source:
    Added at Ill. Reg. , effective , 199 .)
    Section 232.APPENDIX A List of Toxic Air Contaminants
    Chemical Name
    CAS Number
    Acetaldehyde
    75-07-0*
    Acetamide
    60-35-5*
    Acetonitrile
    75-05-8*
    Acetophenone
    98-86-2*
    2-Acetylaminofluorene
    53-96-3*
    Acrolein
    107-02-8*
    Acrylamide
    79-06-1*
    Acrylic acid
    79-10-7*
    Acrylonitrile
    107-13-1*
    Aldrin
    309-00-2**
    Allyl chloride
    107-05-1*
    2-Aminoanthraquinone
    117-79-3
    4-Aminoazobenzene
    60-09-3
    o-Aminoazotoluene
    93-56-3
    4-Aminobiphenyl
    92-67-1*
    1-Amino-2-methylanthraquinone
    82-28-0
    Amitrole
    61-82-5
    Aniline
    62-53-3*
    o-Anisidine
    90-04-0*
    o-Anisidine hydrochloride
    134-29-2
    Antimony
    7440-36-0
    Arsenic
    7440-38-2
    Asbestos (friable)
    1332-21-4*
    Azobenzene
    103-33-3
    Benzo(a)anthracene
    56-55-3
    Benzene
    71-43-2*
    Benzidine
    92-87-5*
    Benzo(a)pyrene
    50-32-8**
    Benzo(b)fluoranthene [3,4-Benzofluoronthene]
    205-99-2**
    Benzo(j)fluoranthene
    205-82-3
    Benzo(k)fluoranthene [11,12-Benzofluoranthene]
    207-08-9**
    1,12-Benzoperylene
    191-24-2**
    Benzotrichloride
    98-07-7*
    Benzyl chloride
    100-44-7*
    Benzyl violet
    1694-09-3

    15
    Beryllium
    7440-41-7
    Beryllium oxide
    1304-56-9
    Biphenyl
    92-52-4*
    Bis(chloromethyl)ether
    542-88-1*
    Boron trifluoride
    7637-07-2
    Bromoform
    75-25-2*
    4-Bromophenyl phenyl ether
    101-55-3**
    1,3-Butadiene
    106-99-0*
    Butyl benzyl phthalate
    85-68-7
    beta-Butyrolacetone
    3068-88-0
    C.I. Basic Red 9 monohydrochloride
    569-61-9
    Cadmium
    7440-43-9
    Cadmium oxide
    1306-19-0
    Calcium cyanamide
    156-62-7*
    Caprolactam
    105-60-2*
    Captan
    133-06-2*
    Carbaryl
    63-25-2*
    Carbofuran
    1563-66-2
    Carbon black
    1333-86-4
    Carbon disulfide
    75-15-0*
    Carbon tetrachloride
    56-23-5*
    Carbonyl sulfide
    463-58-1*
    Carbosulfan
    55285-14-8
    Catechol
    120-80-9*
    Chloramben
    133-90-4*
    Chlordane
    57-74-9††
    Chlorinated dibenzodioxins
    --
    Chlorinated dibenzofurans
    --
    Chlorendic acid
    115-28-6
    Alpha-Chlorinated toluenes
    --
    Chlorinated paraffins ([C12, 60% chlorine)]
    108171-26-2
    Chlorine
    7782-50-5*
    Chloroacetic acid
    79-11-18*
    2-Chloroacetophenone
    532-27-4*
    Chlorobenzene
    108-90-7*
    Chlorobenzilate
    510-15-6*
    Chloroform
    67-66-3*
    Chloromethyl methyl ether
    107-30-2*
    34-Chloro-2-methylpropene
    563-47-3
    4-Chloro-o-phenylenediamine
    95-83-0
    p-Chloro-o-toluidine
    95-69-2
    4-Chlorophenyl phenyl ether
    7005-72-3**
    Chloroprene
    126-99-8*
    Chromium
    7440-47-3

    16
    Chromium (VI)
    18540-29-9
    Chrysene
    218-01-9
    Coal tar (pitch) volatiles
    65996-93-2
    Cobalt
    7440-48-4
    Coke Oven Emissions
    --
    Copper
    7440-50-8
    p-Cresidine
    120-71-8
    Creosote (Coal)
    8001-58-9
    Cresol (mixed isomers) [Cresols/Cresylic acid
    (isomers and mixture)]
    1319-77-3*
    o-Cresol
    95-48-7*
    m-Cresol
    108-39-4*
    p-Cresol
    106-44-5*
    Cumene
    98-82-8*
    Cyanazine
    21725-46-2
    Cyclohexanone
    108-94-1
    DDD
    72-54-8
    DDE
    3547-04-4*
    4,4'-DDE
    72-55-9**
    DDT
    50-29-3**
    Di-n-octyl phthalate
    117-84-0**
    2,4-Diaminoanisole
    615-05-4
    2,4-Diaminoanisole sulfate
    39156-41-7
    4,4'-Diaminodiphenyl ether
    101-80-4
    2,4-Diaminotoluene
    95-80-7*
    Diazomethane
    334-88-3*
    Dibenzo(a,h)acridine
    226-36-8
    Dibenzo(a,j)acridine
    224-42-0
    Dibenzo(a,h)anthracene [1,2:5.6-Dibenzanthracene]
    53-70-3**
    Dibenzo(a,e)pyrene
    192-65-4
    Dibenzo(a,h)pyrene
    189-64-0
    Dibenzo(a,i)pyrene
    189-55-9
    Dibenzo(a,l)pyrene
    191-30-0
    Dibenzofurans
    132-64-9*
    Dibutyl phthalate
    84-74-2††
    1,2-Dibromo-3-chloropropane
    96-12-8*
    1,2-Dibromoethane [Ethylene dibromide]
    106-93-4*
    1,4-Dichlorobenzene(p-)
    106-46-7*
    3,3'-Dichlorobenzidine
    91-94-1*
    3,3'-Dichlorobenzidine dihydrochloride
    612-83-9
    Dichloroethyl ether
    [Bis(2-chloroethyl)ether]
    111-44-4*
    2,4-Dichlorophenoxyacetic acid
    [2,4-D,salts and esters]
    94-75-7*
    1,2-Dichloropropane [Propylene dichloride]
    78-87-5*

    17
    1,3-Dichloropropylene [1,3-Dichloropropene]
    542-75-6*
    Dichlorvos
    62-73-7*
    Dieldrin
    60-57-1**
    Diepoxybutane
    1464-53-5
    Diethanolamine
    111-42-2*
    N,N-Diethyl aniline [N,N-Dimethylaniline]
    121-69-7*
    1,2-Diethylhydrazine
    1615-80-1
    Di(2-ethylhexyl) pPhthalate [Bis(2-ethylhexyl)
    phthalate (DEHP)]
      
    117-81-7*
    Diethyl sulfate
    64-67-5*
    Diglycidyl resorcinol ether
    101-90-6
    3,3'-Dimethoxybenzidine [Dianisidine]
    119-90-4*
    Dimethyl acetamide
    127-19-5
    Dimethyl phthalate
    131-11-3*
    4-Dimethyl aminoazobenzene [Dimethyl aminoazo-
    benzene]
    60-11-7*
    3,3'-Dimethyl benzidene [o-Tolidine]
    119-93-7*
    Dimethyl carbamoyl chloride
    79-44-7*
    N,N-Dimethyl formamide
    68-12-2*
    1,1-Dimethyl hydrazine
    57-14-7*
    1,2-Dimethyl hydrazine
    540-73-8
    Dimethyl sulfate
    77-78-1*
    Dinitrocresol [4,6-Dinitro-o-cresol, and salts]
    534-52-1*
    2,4-Dinitrophenol
    51-28-5*
    2,4-Dinitrotoluene
    121-14-2*
    1,4-Dioxane [1,4-Diethyleneoxide]
    123-91-1*
    1,2-Diphenylhydrazine
    122-66-7*
    Disulfoton
    298-04-4
    Endothall
    145-73-3
    Endrin
    72-20-8††
    Epichlorohydrin
    106-89-8*
    1,2-Epoxybutane
    106-88-7*
    2-Ethoxyethanol
    110-80-5
    Ethyl acrylate
    140-88-5*
    Ethyl benzene
    100-41-4*
    Ethyl chloride [Chloroethane]
    75-00-3*
    Ethylene dichloride [1,2-Dichloroethane]
    107-06-2*
    Ethylene glycol
    107-21-1*
    Ethylene imine [Aziridine]
    151-56-4*
    Ethylene oxide
    75-21-8*
    Ethylene thiourea
    96-45-7*
    Ethylidene dichloride [1,1-Dichloroethanel]
    75-34-3*
    Etridiazole
    2593-15-9
    FMC-67825
    95465-99-9

    18
    Fluorine
    7782-41-4
    Folpet
    133-07-3
    Formaldehyde
    50-00-0*
    Furmecyclox
    60568-05-0
    Heptachlor
    76-44-8††
    Heptachlor epoxide
    1024-57-3**
    Hexachlorobenzene
    118-74-1††
    Hexachloro-1,3-butadiene [Hexachlorobutadiene]
    87-68-3††
    Hexachlorocyclopentadiene
    77-47-4*
    Hexachlorodibenzo-p-dioxin
    19408-74-3
    Hexachloroethane
    67-72-1*
    Hexamethylene-1,6-diisocyanate
    822-06-0*
    Hexamethylphosphoramide
    680-31-9*
    Hexane
    110-54-3*
    Hydrazine
    302-01-2*
    Hydrazine sulfate
    10034-93-2
    Hydrochloric acid
    7647-01-0*
    Hydrogen cyanide
    74-90-8
    Hydrogen fluoride [Hydrofluoric acid]
    7664-39-3*
    Hydrogen sulfide
    7783-06-4*
    Hydroquinone
    123-31-9*
    Indeno(1,2,3-cd)pyrene
    193-39-5**
    Isophorone
    78-59-1*
    Isophorone diisocyanate
    4098-71-9
    Lead
    7439-92-1
    Lindane-[Hexachlorocyclohexane-alpha](alpha)
    319-84-6**
    Lindane-[Hexachlorocyclohexane-beta](beta)
    319-85-7**
    Lindane-[Hexachlorocyclohexane-gamma](gamma)
    [Lindane all isomers]
    58-89-9††
    Lindane-[Hexachlorocyclohexane-mixed isomers]
    (mixed isomers)
    608-73-1
    Linuron
    330-55-2
    Malathion
    121-75-5
    Maleic anhydride
    108-31-6*
    Manganese
    7439-96-5
    Mercury
    7439-97-6**
    Methanol
    67-56-1*
    Methoxychlor
    72-43-5††
    2-Methoxyethanol
    109-86-4
    2-Methoxyethanol acetate
    110-49-6
    Methyl bromide [Bromomethane]
    74-83-9*
    Methyl chloride [Chloromethane]
    74-87-3*
    Methyl chloroform [(1,1,1-Trichloroethane]
    71-55-6*
    Methyl ethyl ketone [2-Butanone]
    78-93-3*

    19
    Methyl isobutyl ketone [Hexone]
    108-10-1*
    Methyl isocyanate
    624-83-9*
    Methyl methacrylate
    80-62-6*
    Methyl tert butyl ether
    1634-04-4*
    5-Methylchrysene
    3697-24-3
    4,4'-Methylene bis(2-chloroaniline)
    101-14-4*
    Methylenebis(phenylisocyanate) [Methylene
    diphenyl diisocyanate (MDI)]
    101-68-8
    4,4'-Methylenebis(N,N'-dimethyl)benzenamine)
    101-61-1
    Methylene chloride [Dichloromethane]
    75-09-2*
    4,4'-Methylenedianiline
    101-77-9*
    4,4'-Methylenedianiline dihydrochloride
    13552-44-8
    Methyl hydrazine
    60-34-4*
    Methyl iodide [Iodomethane]
    74-88-4*
    Methyl mercaptan
    74-93-1
    N-Methyl-N'-nitro-N-nitrosoguanidine
    70-25-7
    Metolachlor
    51218-45-2
    Michler's Ketone
    90-94-8
    Mirex
    2385-85-5**
    Monoethanolamine
    141-43-5
    Naphthalene
    91-20-3*
    beta-Naphthylamide
    91-59-8
    Nickel
    7440-02-0
    Nitric acid
    7697-37-2
    Nitrilotriacetic acid
    139-13-9
    Nitrobenzene
    98-95-3*
    4-Nitrobiphenyl
    92-93-3*
    5-Nitro-o-anisidine
    99-59-2
    2-Nitropropane
    79-46-9*
    4-Nitrophenol
    100-02-7*
    N-Nitroso-n-butyl-N-(3-carboxypropyl) amine
    38252-74-3
    N-Nitroso-n-butyl-N-(4-hydroxybutyl) amine
    3817-11-6
    N-Nitrosodi-n-butylamine
    924-16-3
    N-Nitrosodiethanolamine
    1116-54-7
    N-Nitrosodiethylamine
    55-18-5
    N-Nitrosodimethylamine
    62-75-9*
    N-Nitrosodiphenylamine
    86-30-6
    N-Nitrosodi-n-propylamine
    621-64-7
    N-Nitroso-N-ethylurea
    759-73-9
    3-(N-Nitrosomethylamino) propionitrile
    60153-49-3
    N-Nitrosomethylethylamine
    10595-95-6
    N-Nitroso-N-methylurea
    684-93-5*
    N-Nitrosomethylvinylamine
    4549-40-0
    N-Nitrosomorpholine
    59-89-2*

    20
    N-Nitrosonornicotine
    16543-55-8
    N-Nitrosopiperidine
    100-75-4
    N-Nitrosopyrrolidine
    930-55-2
    N-Nitrososarcosine
    13256-22-9
    Nitrofen
    11836-75-5
    Octachlorostyrene
    2908-74-4**
    PCDDs (Total polychlorinated dibenzodioxins)
    --
    PCDFs (Total polychlorinated dibenzofurans)
    --
    PAHs (Total polycyclic aromatic hydrocarbons)
    --
    Parathion
    56-38-2*
    Pentachlorobenzene
    608-93-5††
    Pentachloronitrobenzene [Quintobenzene]
    82-68-8*
    Pentachlorophenol
    87-86-5*
    Peracetic acid
    79-21-0
    Phenol
    108-95-2††
    p-Phenylenediamine
    106-50-3*
    Phenylhydrazine
    100-63-0
    Phorate
    298-02-2
    Phosgene
    75-44-5*
    Phosphine
    7803-51-2*
    Phosphorus
    7723-14-0*
    Phosphorus oxychloride
    10025-87-3
    Phosphorus pentachloride
    10026-13-8
    Photomirex
    39801-14-4**
    Phthalic anhydride
    85-44-9*
    Polybrominated biphenyls
    --
    Polychlorinated biphenyls [Aroclors]
    1336-36-3††
    Potassium bromate
    7758-01-2
    Propane sultone [1,3-Propane sultone]
    1120-71-4*
    beta-Propiolactone
    57-57-8*
    Propionaldehyde
    123-38-6*
    Propoxur [Baygon]
    114-26-1*
    Propyleneimine [1,2-Propylenimine(2-Methyl
    aziridine)]
    75-55-8*
    Propylene oxide
    75-56-9*
    Pyrene
    129-00-0
    Quinoline
    92-22-5*
    Quinone
    106-51-4*
    Selenium
    7782-49-2
    Sodium borate
    1303-96-4
    Styrene 100-42-5
    Styrene
    100-42-5*
    Styrene oxide
    96-09-3*
    Sulfallate
    95-06-7

    21
    Sulfuric acid
    7664-93-9
    Terbufos
    13071-79-9
    1,2,3,4-Tetrachlorobenzene
    634-66-2††
    1,2,4,5-Tetrachlorobenzene
    95-94-3††
    1,1,2,2-Tetrachloroethane
    79-34-35*
    Tetrachloroethylene
    [Perchloroethylene]
    127-18-4*
    2,3,7,8-Tetrachlorodibenzo-p-dioxin
    [2,3,7,8-TCDD]
    1746-01-6††
    4,4'-Thiodianiline
    139-65-1
    Thiophenol
    108-98-5
    Thiourea
    62-56-6
    Thorium dioxide
    1314-20-1
    Titanium tetrachloride
    7550-45-0*
    Toluene
    108-88-3††
    Toluene-2,4-diisocyanate [2,4-Toluene
    diisocyanate]
    584-84-9*
    Toluene-2,6-diisocyanate
    91-08-7
    o-Toluidine
    95-53-4*
    o-Toluidine hydrochloride
    636-21-5
    p-Toluidine
    106-49-0
    Toxaphene
    8001-35-2††
    1,2,4-Trichlorobenzene
    120-82-1*
    1,1,2-Trichloroethane
    79-00-5*
    Trichloroethylene
    79-01-6*
    2,4,5-Trichlorophenol
    95-95-4*
    2,4,6-Trichlorophenol
    88-06-2*
    Triethylamine
    121-44-8*
    Trifluralin
    1582-09-8*
    Trimethylbenzene
    25551-13-7
    1,2,4-Trimethyl benzene
    95-63-6
    2,4,6-Trinitrotoluene
    118-96-7
    2,2,4-Trimethylpentane
    540-84-1*
    Tris(2,3-dibromopropyl) phosphate
    126-72-7
    Trypan blue
    72-57-1
    Urethane [Ethyl carbamate]
    51-79-6*
    Vinyl acetate
    108-05-4*
    Vinyl bromide
    593-60-2*
    Vinyl chloride
    75-01-4*
    Vinylidene chloride [1,1-Dichloroethylene]
    75-35-4*
    Xylenes (isomers and mixture)
    1330-20-7*
    o-Xylenes
    95-47-6*
    m-Xylenes
    108-38-3*
    p-Xylenes
    106-42-3*

    22
    Antimony compounds*
    --
    Includes any unique chemical substance
    that contains antimony as part of that
    chemical's infrastructure
    Arsenic compounds*
    --
    Includes any unique chemical substance
    that contains arsenic as part of that
    chemical's infrastructure
    Beryllium compounds*
    --
    Includes any unique chemical substance
    that contains beryllium as part of that
    chemical's infrastructure
    Cadmium compounds*
    --
    Includes any unique chemical substance
    that contains cadmium as part of that
    chemical's infrastructure
    Chromium compounds*
    --
    Includes any unique chemical substance
    that contains chromium as part of that
    chemical's infrastructure
    Cobalt compounds*
    --
    Includes any unique chemical substance
    that contains cobalt as part of that
    chemical's infrastructure
    Cyanide compounds*
    --
    x(pos) CN(neg) where X = H(pos) or any
    other group where a formal dissociation
    can be made. For example, KCN or Ca(CN)
    2
    Glycol ethers*
    --
    Includes any unique chemical substance
    that contains glycol as part of that
    chemical's infrastructure. Includes
    mono- and di- ethers of ethylene glycol,
    diethylene glycol, and triethylene glycol
    R(OCH
    2
    CH
    2
    )
    n
    -OR' where
    n = 1,2, or 3
    R = alkyl or aryl groups

    23
    R' = R, H, or groups which, when
    removed, yield glycol ethers with
    the structure: R(OCH
    2
    CH
    2
    )
    n
    -OH.
    Polymers are excluded from the glycol
    category.
    Fine mineral fibers*
    --
    Includes mineral fiber emissions from
    facilities manufacturing or processing
    glass, rock, or slag fibers (or other
    mineral derived fibers) having the
    average diameter of 1 micrometer or
    less.
    Lead compounds*
    --
    Includes any unique chemical substance
    that contains lead as part of that
    chemical's infrastructure
    Manganese compounds*
    --
    Includes any unique chemical substance
    that contains manganese as part of that
    chemical's infrastructure
    Mercury compounds*
    --
    Includes any unique chemical substance
    that contains mercury as part of that
    chemical's infrastructure
    Nickel compounds*
    --
    Includes any unique chemical substance
    that contains nickel as part of that
    chemical's infrastructure
    Polycyclic Organic Matter (POM)*
    --
    Includes organic compounds having more
    than one benzene ring and a boiling
    point equal to or greater than 100
    degrees Celsius (212 degrees Farenheit).
    Radionuclides (including radon)*
    --
    A type of atom which spontaneously
    undergoes radioactive decay.
    Selenium Compounds*
    --

    24
    Includes any unique chemical substance
    that contains selenium as part of that
    chemical's infrastructure.
    * Indicates presence on HAP List.
    **Indicates presence on Great Waters List.
    ††Indicates presence on HAP and Great Waters Lists.
    Section 41 of the Environmental Protection Act (415 ILCS 5/41 (1994)) provides for
    the appeal of final Board orders within 35 days of the date of service of this order. The Rules
    of the Supreme Court of Illinois establish filing requirements. (See also 35 Ill. Adm. Code
    101.246 "Motions for Reconsideration.")
    IT IS SO ORDERED.
    I, Dorothy M. Gunn, Clerk of the Illinois Pollution Control Board, hereby certify that
    the above opinion and order was adopted on the _____ day of ___________, 1996, by a vote
    of ______________.
    ___________________________________
    Dorothy M. Gunn, Clerk
    Illinois Pollution Control Board

    Back to top