ILLINOIS POLLUTION CONTROL BOARD
August 1, 1996
IN MATTER OF:
LISTING OF FEDERAL HAZARDOUS AIR
POLLUTANTS, GREAT LAKES
COMMISSIONS TOXIC COMPOUNDS
AND GREAT WATERS PROGRAM TOXIC
COMPOUNDS, AND SOURCE REPORTING
FOR ILLINOIS TOXIC AIR
CONTAMINANTS: AMENDMENTS TO 35
ILL. ADM. CODE 232
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R96-4
(Rulemaking - Air)
Proposed Rule. First Notice.
OPINION AND ORDER OF THE BOARD (by J. Yi):
Pursuant to Sections 9.5, 27 and 28 of the Environmental Protection Act (Act) (415 ILCS
5/9.5, 27 and 28), the Illinois Environmental Protection Agency (Agency) filed this rulemaking proposal
on October 13, 1995. In addition to the proposal the Agency filed a motion to waive certain filing
requirements, to expedite the hearing process and to consolidate R90-1(C), In the Matter of: Toxic Air
Contaminant List (35 Ill. Adm. Code 232); Reporting Requirements for Emission Sources and R90-
1(D), In the Matter of: Toxic Air Contaminant List, Styrene (35 Ill. Adm. Code 232.Appendix A),
into this proceeding.
In our order of November 2, 1995 we granted the Agency's motions and found that the filing
met the requirements of Sections 27 and 28 of the Act. The Board also accepted this matter for hearing
and directed the hearing officer to set this matter for hearing. Additionally, the Board, in separate
orders closed the dockets in both R90-1(C) and (D).
The Board held two hearings in this matter. The first hearing was held on February 23, 1996 in
Springfield, Illinois. The second hearing was held on April 9, 1996 in Chicago, Illinois. The post-
hearing comment period ended May 17, 1996.
Today the Board acts to send this rulemaking proposal for first notice. Pursuant to Section
5.01 of the Illinois Administrative Procedure Act (IAPA) and Section 102.342 of the Board's
procedural rules, the IAPA 45-day public comment period will commence upon publication of today's
proposal in the Illinois Register, during which the Board will accept written comments from any person.
Persons interested in providing additional comment on this proposal should submit such comments in
writing to the Clerk of the Board prior to the expiration of this 45-day period.
The Board will not hold
2
any hearings beyond those that have already been held unless a written request for hearing is
received by the Clerk of the Board.
PURPOSE OF PROPOSAL
The proposal has two (2) main purposes both of which are connected to the Illinois's Toxic Air
Contaminants (ITAC) list. First, the proposal intends to update the ITAC by adding chemicals or
substances either listed as federal Hazardous Air Pollutants (HAPs) under Section 112(b) of the Clean
Air Act (CAA) as amended in 1990, or targeted as chemicals or compounds of concern under the
United States Environmental Protection Agency's (USEPA) "Great Waters" program under Section
112(m) of the CAA to 35 Ill. Adm. Code 232.Appendix A. In addition to updating ITAC, the
proposal will require all sources that meet the applicability criteria to submit an ITAC Source Report for
the calendar year 1996. Finally the proposal will correct typographical errors in the current ITAC list.
PROPOSED AMENDMENTS
This portion of the opinion will discuss the proposed amendments to 35 Ill. Adm. Code 232
section by section.
Section 232.120 Definitions
The proposed amendments to Section 232.120 are to delete definitions no longer applicable to
this Part as a result of revisions to 35 Ill. Adm. Code 211 and to add definitions of “commercial fuel”,
“Illinois Toxic Air Contaminant” (ITAC), “ITAC Source Report”, “manufacture”, “otherwise use”,
“prices”, and “Toxic Air Contaminant” (TAC). The definition of “commercial fuel” is necessary
because Section 9.5(e)(3) of the Act exempts emissions of ITACs from combustion processes using
commercial fuel from the source reporting requirements. The definitions of “manufacture”, “otherwise
use” and “process” have also been added to address applicability thresholds, and these definitions are
identical in substance to those in Section 313 of the Emergency Planning and Community Right-to
Know Act, Title III of Superfund Amendments and Reauthorization Act of 1986 (SARA 313) (42
U.S.C. 11001
et seq
.) The definitions of ITAC and TAC have been added to delineate only those
chemicals listed in Appendix A that are subject to this proposal. “ITAC Source Report” has been
added as a definition to address what information is required to be reported under this proposal.
Section 232.120 has also been revised to delete the definitions of “New emission source” and
“Process unit” since these definitions are inconsistent with, or are no longer necessary because of, earlier
revisions to Part 211.
The Agency’s proposal to the Board suggested that the definition of “‘Emits’ or ‘Emissions’ or
‘Emitted’”, be deleted because of earlier revisions to Part 211. However contained in the definition of
“‘Emits’ or ‘Emissions’ or ‘Emitted’”, is the definition of “Fugitive emission” which is not defined in
either Part 201 or 211. The definition of “Fugitive emission” is at Section 203.124. Since Parts 201
3
and 211 do not contain a definition of “Fugitive emission” we will delete the definition of “‘Emits’ or
‘Emissions’ or ‘Emitted’” but retain the definition for “Fugitive emission”.
Subpart D: Source Identification Requirements
Sections 232.400 through 232.460, contain the requirements relating to source reporting.
Section 232.400 states the purpose of Subpart D.
Section 232.410(a) provides the applicability threshold: any source that manufactures,
processes, or imports 25,000 lbs. or more of any individual ITAC in any calendar year; or otherwise
uses 10,000 lbs. of any individual ITAC in any calendar year. Section 232.410(b) lists those processes
or operations that are not subject to Subpart D, and incorporates the exemptions in Section 9.5(e) of
the Act. Section 232.410(c) provides for an additional applicability threshold, beyond the threshold in
232.410(a).
Section 232.420 provides that the Agency will supply to all sources expected to be affected by
this proposal an ITAC Source Report that contains all the data fields required by Subpart D. This
report is designed to assist affected sources in complying with the requirements of Subpart D, although
the information need not be submitted on this form. The ITAC Source Report form is similar to the
form being utilized through SARA 313.
Section 232.421 requires that all emission reports submitted pursuant to Subpart D be certified,
and specifies the criteria for a certifying individual, as well as the required certification.
Section 232.423 provides that the failure of an affected source to receive an ITAC Source
Report from the Agency does not relieve a source from the obligation to file an emissions report.
Section 232.430(a) specifies the date by which a source must file an emissions report and lists
the information required to be submitted. Section 232.430(b) lists which emissions of ITACs are
considered to be
de minimis
and therefore not subject to reporting. Section 232.430(c) specifies the
date for reporting for sources that become subject to this proposal after January 1, 1996. Section
232.430(d), (e), and (f) list when a source must submit a revised emissions report to the Agency.
Section 232.440 allows a source to use engineering estimates to determine emissions if the type
of estimate is reasonable, is specified, is the best information available, and notes that this Subpart does
not require monitoring or testing in connection with these emissions reports.
Section 232.450(a) provides that the Agency may request additional information, beyond that
initially submitted or specified in Section 232.430. Section 232.450(b) specifies that a source must
retain records upon which the data included in the emissions report is based for a minimum period of
three years, and must make these records available to the Agency upon request.
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Section 232.460 requires a source to correct any errors in the data previously submitted within
60 days of discovering such error.
Subpart E: Listing and Delisting
Section 232.501 contains an explanation for the inclusion of the chemicals and compound listed
as HAPs under Section 112(b) of the CAA and for the inclusion of the “Great Waters” program
targeted compounds under Section 112(m) of the CAA, and exempts these new compounds from the
listing requirements of Section 232.500.
Section 232.Appendix A List of Toxic Air Contaminants
Appendix A has been amended to add the HAPS and Great Waters TACs not previously listed, and to
denote the compounds as either HAPs, Great Water TACs, or both. Furthermore, Appendix A has
also been revised to correct typographical errors and errors in the Chemical Abstract Service (CAS)
numbers for previously listed chemicals.
ORDER
The Board hereby proposes the following regulations for First Notice pursuant to the IAPA.
The Board directs the Clerk to cause publication of these regulations in the Illinois Register for first
notice. (The text starts on the following page.)
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TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE B: AIR POLLUTION
CHAPTER I: POLLUTION CONTROL BOARD
SUBCHAPTER f: TOXIC AIR CONTAMINANTS
PART 232
TOXIC AIR CONTAMINANTS
SUBPART A: GENERAL PROVISIONS
Section
232.100
Introduction
232.110
Incorporations by Reference
232.120
Definitions (Repealed)
232.130
Applicability
SUBPART B: DETERMINATION OF A TOXIC AIR
CONTAMINANT
Section
232.200
Characteristics for Determining a Toxic Air Contaminant
SUBPART C: PROCEDURES FOR EVALUATING
CHARACTERISTICS OF A TOXIC AIR CONTAMINANT
Section
232.300
Purpose
232.310
Procedures for Determining the Toxicity Score
232.320
Carcinogen Classification
SUBPART D: SOURCE IDENTIFICATION REQUIREMENTS
Section
232.400
Purpose
232.410
Applicability
232.420
ITAC Source Report
232.421
Emissions Report Certification
232.423
Failure to Receive an ITAC Source Report
232.430
Emissions Report
232.440
Use of Available Data
232.450
Retention of Records
232.460
Reporting of Errors
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SUBPART E: LISTING AND DELISTING
Section
232.500
Procedures for Listing and Delisting Toxic Air Contaminants
232.501
Listing of Federal Hazardous Air Pollutants, Great Lakes Commission Toxic
Compounds and Great Waters Program Toxic Compounds
APPENDIX A:
List of Toxic Air Contaminants
APPENDIX B:Additional Procedures for Calculating the Chronic Toxicity Score
APPENDIX C:
Carcinogens (Categories A, B1, and B2) listed on the Integrated Risk
Information System (IRIS) as of December 31, 1989 (United States
Environmental Protection Agency, Office of Health and Environmental
Assessment)
AUTHORITY: Implementing Section 9.5 and authorized by Section 27 of the Environmental
Protection Act [415 ILCS 5/9.5 and 27].
SOURCE: Adopted in R90-1 at 16 Ill. Reg. 16592, effective October 18, 1992; amended in R__-__
at _____ Ill. Reg. __________, effective ______________199_.
SUBPART A: GENERAL PROVISIONS
Section 232.120
Definitions (Repealed)
The definitions of 35 Ill. Adm. Code 201.102, 211.122 and 215.104, 201 and 211 apply to this Part,
as well as the definitions contained in this Section. Where a definition contained in this Section is more
specific than those found in 35 Ill. Adm. Code 201.102, 211.122 and 215.104 201 and 211, it must
take precedence in application of this Part.
"ACGIH" means the American Conference of Governmental Industrial Hygienists.
"Adverse health effect" means a health injury or disease that may be produced by exposure to a
contaminant. This includes any decrement in the function of an organ or organ system or any
subclinical organ lesion that is likely to lead to a decrement in an organ or organ system function.
"Commercial fuel" means:
a)
Any fuel offered for final sale for use in combustion processes;
7
b)
Any gaseous fuel generated as a by-product at a source for which the source has been
issued an operating permit to use such fuel internally in combustion processes, including
internal combustion engines; or
c)
Any waste derived fuel for which an operating permit has been issued and which
represents no more than five percent (.05) by weight on a daily basis of total fuel used in
combustion processes by a source.
"Critical gestation days" means the days during which the formation and differentiation of organs
and organ systems occurs during embryonic development.
"Emits" or "Emission" or "Emitted" means any non-accidental release into the atmosphere from
an emission source or air pollution control equipment, or fugitive emissions defined according to
35 Ill. Adm. Code 203.124.
“Fugitive emissions” is defined according to 35 Ill. Adm. Code 203.124.
"IARC" means the World Health Organization's International Agency for Research on Cancer.
"IRIS" means the USEPA's Integrated Risk Information System.
"Illinois Toxic Air Contaminant" (ITAC) means any toxic air contaminant listed pursuant to 35
Ill. Adm. Code 232, excluding, specifically: coke oven gas; any hazardous air pollutant (HAP)
now or hereafter listed under Section 112(b) of the Clean Air Act (CAA), as amended; and any
pollutant or contaminant listed as a compound of concern under the Great Waters Program
under Section 112(m) of the CAA.
"ITAC Source Report" means the report that the Agency provides to the source that lists data
fields for the information required in the emissions report for Subpart D of this Part, and
contains the information, if any, that previously has been reported to the Agency for those data
fields.
"LC50" means the concentration in the air of a contaminant that kills, or is estimated to kill, fifty
percent (.50) of a population of laboratory animals where the exposure is brief (8 hours or less)
and where the route of exposure is inhalation.
"LD50" means the dose of a contaminant that kills, or is estimated to kill, 50 percent of a
population of laboratory animals where the route of exposure is ingestion.
"Lowest observed adverse effect level" means the lowest experimentally determined dose at
which a statistically or biologically significant indication of the toxic effect of concern is
observed.
8
"Manufacture" means, for the purposes of 35 Ill. Adm. Code Sections 232.400 through
232.460 of this Part, to produce, prepare, or compound a listed ITAC, and includes
coincidental production of an ITAC (e.g., as a by-product or impurity) as a result of the
manufacture, processing or otherwise use or treatment of one or more chemical substances not
an ITAC. An ITAC intentionally incorporated into a product is considered to be manufactured.
"NTP" means the United States' Department of Health and Human Services, Public Health
Services' National Toxicological Program.
"New emission source" means an emission source or air pollution control equipment for which a
construction permit is required by 35 Ill. Adm. Code 201 after (the effective date of these
rules); or an emission source or air pollution control equipment for which an operating permit is
required by 35 Ill. Adm. Code 201, where the owner or operator failed to apply for a
construction permit and applies for the first operating permit.
"No observed effect" means the condition where no adverse health effect has been detected.
"Otherwise use" means, for the purposes of 35 Ill. Adm. Code Sections 232.400 through
232.460 of this Part, any activity involving a listed ITAC at a source that does not fall within the
definitions of "manufacture" or "process."
"Process" means, for the purposes of 35 Ill. Adm. Code Sections 232.400 through 232.460 of
this Part, the preparation of an ITAC after its manufacture for distribution in commerce in the
same physical state as, or in a different form or physical state from, that in which it was received
by the source, or preparation that produces a change in physical state or chemical form.
"Process unit" shall have the meaning set forth in 35 Ill. Adm. Code Section 211.5210.
"Toxic air contaminant" (TAC) means a contaminant identified pursuant to Section 232.200 or
Section 232.501 of this Part and listed in Appendix A of this Part.
(Source: Amended at _____ Ill. Reg. __________, effective ______________199_.)
SUBPART D: SOURCE IDENTIFICATION REQUIREMENTS
Section 232.400
Purpose
This Subpart establishes identification and reporting requirements for new and existing sources that emit
Illinois Toxic Air Contaminants.
(Source: Added at _____ Ill. Reg. _______, effective ______________199_.)
9
Section 232.410
Applicability
a)
This Subpart shall apply to any owner or operator of a source that manufactures,
processes or imports 25,000 lbs or more of any individual ITAC in any calendar year
or otherwise uses 10,000 lbs of any individual ITAC in any calendar year.
b)
This Subpart shall not apply to the following:
1)
Retail dry cleaning operations;
2)
Retail and noncommercial storage and handling of motor fuels;
3)
Combustion processes, including internal combustion engines, using only
commercial fuel; and
4)
Equipment and operations which are exempt from permitting requirements
pursuant to 35 Ill. Adm. Code 201.146;
c)
If an ITAC is present in a mixture of chemicals at a source at a concentration below one
percent (0.01) by weight, or one-tenth of one percent (.001) by weight in the case of an
ITAC which is a carcinogen listed in Appendix C of this Part, an owner or operator
subject to this Subpart is not required to consider the quantity of the ITAC in such
mixture when determining whether an applicable threshold has been met under
subsection (a) of this Section or in determining the amount of emissions to be reported
under Section 232.430 of this Part.
(Source: Added at _____ Ill. Reg. ______, effective ______________199_.)
Section 232.420
ITAC Source Report
a)
On or before April 1, 1997, the Agency shall provide to the owner or operator of a
source subject to this Subpart the ITAC Source Report. The ITAC Source Report
shall contain all data fields for the information required under this Subpart.
b)
The information on emissions provided by the owner or operator of a source in the
emissions report shall be based on the best information available to the owner or
operator and that is reflective of the operations of the source and its ITAC emissions.
(Source: Added at _____ Ill. Reg. _____, effective ______________199_.)
Section 232.421
Emissions Report Certification
10
All emission reports filed pursuant to this Subpart shall contain the following certification statement: "All
emissions data verified, modified or provided on behalf of the source named above represents the best
available information and is true and accurate to the best of my knowledge." The certification statement
shall be signed by an individual responsible for the accuracy of the emissions report and who will take
legal responsibility for the information verified or reported therein. The certification statement shall be
accompanied by the full name, title, actual signature, date of signature, and a telephone number of the
individual signing the emissions report.
(Source: Added at _____ Ill. Reg. _____, effective ______________199_.)
Section 232.423
Failure to Receive an ITAC Source Report
Failure to receive the ITAC Source Report from the Agency shall not relieve an owner or operator from
the obligation to file a complete emissions report. Any owner or operator who does not receive the
ITAC Source Report on or before April 1, 1997, may contact the Agency to request the ITAC Source
Report.
(Source: Added at _____ Ill. Reg. _____, effective ______________199_.)
Section 232.430
Emissions Report
a)
On or before July 1, 1997, the owner or operator of a source subject to this Subpart
shall file an emissions report for the calendar year 1996 which shall include the following
information:
1)
Source identification information; and
2)
Identify by generic name and Chemical Abstract Service (CAS) number, the
source’s actual annual emissions of each ITAC expressed in tons per year
(TPY), and the source's annual fugitive emissions of each ITAC, expressed in
TPY, for each ITAC that exceeds the threshold for applicability as set forth in
Section 232.410 of this Part. In determining the actual annual emissions of each
ITAC, the source may exclude emissions of such ITAC from all emission units
with de minimis emissions of ITACs.
b)
The following emissions of ITACs shall be considered to be de minimis and shall not be
subject to reporting requirements under this Subpart:
1)
Emissions of ITACs from an emission unit which, in the aggregate, are less than
one-half (0.5) TPY;
11
2)
Emissions from a process unit resulting from a process vent stream with ITAC
concentrations that are always less than one-tenth of one percent (0.001) by
weight on a daily basis, if such concentrations include any carcinogen listed in
Appendix C of this Part;
3)
Emissions from a process unit resulting from a process vent stream with ITAC
concentrations that are always less than one percent (0.01) by weight on a daily
basis, if such concentrations do not include any carcinogen listed in Appendix C
of this Part; or
4)
Fugitive emissions of ITACs from a process unit which, in the aggregate, are
less than one-half (0.5) TPY.
c)
If a source becomes subject to this Subpart on or after January 1, 1996, the owner or
operator of the source shall submit an emissions report to the Agency on or before July
1 of the year following the date the source becomes subject to this Subpart for the
period from the date the source first becomes subject to this Subpart through the end of
the calendar year before the year the first report from such source is due under this
Subpart. Such emissions report shall contain all of the information listed in subsections
(a)(1), (a)(2), and (a)(3) of this Section and any additional information requested by the
Agency pursuant to Section 232.450 of this Part. Any such emissions report shall
satisfy the requirements of Sections 232.410, 232.420, 232.421, 232.423, 232.430,
232.440, 232.450, and 232.460 of this Part.
d)
An owner or operator of a source subject to this Subpart shall submit to the Agency a
revised, correct emissions report on or before July 1 of the year following the
occurrence of any of the following:
1)
If the source's actual annual emissions of any individual ITAC or any
combination of ITACs required to be reported under this Subpart increases by
more than one-half (0.50) TPY or one (1) TPY, respectively, from the sources'
emissions of ITACs initially reported under this Subpart; or
2)
If the source emits an ITAC that exceeds the threshold for applicability as set
forth in Section 232.410 of this Part which was not previously reported in the
source's initial report of its emissions of ITACs or in any subsequent revised
report of its emissions of ITACs required to be submitted pursuant to this
subsection.
e)
Any revised emissions report required to be submitted under subsection (d) of this
Section shall contain all of the information listed in subsection (a) of this Section and any
additional information requested by the Agency pursuant to Section 232.450 of this
12
Part. Any revised emissions report shall satisfy the requirements of Sections 232.410,
232.420, 232.421, 232.423, 232.430 232.440, 232.250, and 232.450 of this Part.
f)
By July 1 of the calendar year following any modification or change to an emission unit
requiring a revision to an existing permit or a new permit and which may result in an
increase in emissions of a previously reported ITAC by ten percent (.10) or more, an
owner or operator of a source subject to this Subpart shall submit to the Agency a
revised emissions report which includes the information required under Section 232.430
of this Part.
(Source: Added at _____ Ill. Reg. _____, effective _______________199_.)
Section 232.440
Use of Available Data
a)
In order to provide the information required under this Subpart, the owner or operator
of a source may:
1)
Use reasonable engineering estimates of total emissions of individual ITACs
pursuant to an emissions determination method, if, in each case, the owner or
operator of a source specifies the emissions determination method used to
estimate total emissions and certifies that such data represents the best available
information and is true and accurate to the best of his/her knowledge; or
2)
If available, monitoring or measuring data collected pursuant to other provisions
of law or regulation.
b)
Nothing in this Subpart requires the monitoring or measurement of the quantities,
concentrations, or frequency of emissions of any ITAC beyond any monitoring or
measurement required under other provisions of law or regulation.
(Source: Added at _____ Ill. Reg. _____, effective ______________199_.)
Section 232.450
Retention of Records/ Additional Information
a)
For purposes of modeling and conducting assessments of information submitted under
this Subpart, the Agency may request supporting documentation or additional
information for any emissions report submitted by a source, including:
1)
An identification by generic name and Chemical Abstract Service (CAS)
number the source’s emissions of each ITAC by emission unit, with maximum
hourly emission rates in lbs/hr and actual annual emissions in TPY and the
source's fugitive emissions of each ITAC in TPY;
13
2)
Operating data, exhaust point information and, if applicable, control device
information for each emission unit; and
3)
Copies of engineering estimate calculations, mass balance calculations, and any
other information or documentation used by the owner or operator of a source
in preparing an emissions report.
b)
All records and calculations upon which the data submitted in the emissions report are
based must be retained by the source for a minimum of three (3) years following the
filing of a complete report. The owner or operator of a source shall provide the
requested information in a format acceptable to the Agency within 60 days after the
receipt of the request.
c)
Nothing in this Section shall be interpreted to impose upon any source subject to this
Subpart any additional monitoring which is not otherwise required by applicable rules or
a permit condition.
(Source: Added at _____ Ill. Reg. _____, effective ______________199_.)
Section 232.460
Reporting of Errors
If, after submitting any emissions report required by this Subpart, the owner or operator of a source
discovers any error in the data reported, the owner or operator shall notify the Agency of the error in
writing and shall provide the Agency with the correct data. The notification and correction shall be
conveyed to the Agency within sixty (60) days after the owner's or operator's discovery of the error.
The corrected data shall be certified in accordance with Section 232.421 of this Part.
(Source:
Added at _____ Ill. Reg. ______, effective ______________199_.)
SUBPART E: LISTING AND DELISTING
Section 232.501
Listing of Federal Hazardous Air Pollutants, Great Lakes Commission Toxic
Compounds and Great Waters Program Toxic Compounds
Notwithstanding the provisions of Section 232.500 of this Part, all chemicals listed as "hazardous air
pollutants" under Section 112(b) of the CAA, as amended in 1990 (42 U.S.C. 7412(b)), and all
chemicals targeted as toxic compounds or chemicals by the Great Lakes Commission or under the
United States Environmental Protection Agency's "Great Waters" Program which are not currently listed
as toxic air contaminants under this Part, are hereby listed as toxic air contaminants under Appendix A
of this Part. The listing of hazardous air pollutants and other toxic compounds or chemicals as toxic air
14
contaminants under this Section is without reference to the listing procedures of Section 232.500 of this
Part.
(Source:
Added at Ill. Reg. , effective , 199 .)
Section 232.APPENDIX A List of Toxic Air Contaminants
Chemical Name
CAS Number
Acetaldehyde
75-07-0*
Acetamide
60-35-5*
Acetonitrile
75-05-8*
Acetophenone
98-86-2*
2-Acetylaminofluorene
53-96-3*
Acrolein
107-02-8*
Acrylamide
79-06-1*
Acrylic acid
79-10-7*
Acrylonitrile
107-13-1*
Aldrin
309-00-2**
Allyl chloride
107-05-1*
2-Aminoanthraquinone
117-79-3
4-Aminoazobenzene
60-09-3
o-Aminoazotoluene
93-56-3
4-Aminobiphenyl
92-67-1*
1-Amino-2-methylanthraquinone
82-28-0
Amitrole
61-82-5
Aniline
62-53-3*
o-Anisidine
90-04-0*
o-Anisidine hydrochloride
134-29-2
Antimony
7440-36-0
Arsenic
7440-38-2
Asbestos (friable)
1332-21-4*
Azobenzene
103-33-3
Benzo(a)anthracene
56-55-3
Benzene
71-43-2*
Benzidine
92-87-5*
Benzo(a)pyrene
50-32-8**
Benzo(b)fluoranthene [3,4-Benzofluoronthene]
205-99-2**
Benzo(j)fluoranthene
205-82-3
Benzo(k)fluoranthene [11,12-Benzofluoranthene]
207-08-9**
1,12-Benzoperylene
191-24-2**
Benzotrichloride
98-07-7*
15
Benzyl chloride
100-44-7*
Benzyl violet
1694-09-3
Beryllium
7440-41-7
Beryllium oxide
1304-56-9
Biphenyl
92-52-4*
Bis(chloromethyl)ether
542-88-1*
Boron trifluoride
7637-07-2
Bromoform
75-25-2*
4-Bromophenyl phenyl ether
101-55-3**
1,3-Butadiene
106-99-0*
Butyl benzyl phthalate
85-68-7
beta-Butyrolacetone
3068-88-0
C.I. Basic Red 9 monohydrochloride
569-61-9
Cadmium
7440-43-9
Cadmium oxide
1306-19-0
Calcium cyanamide
156-62-7*
Caprolactam
105-60-2*
Captan
133-06-2*
Carbaryl
63-25-2*
Carbofuran
1563-66-2
Carbon black
1333-86-4
Carbon disulfide
75-15-0*
Carbon tetrachloride
56-23-5*
Carbonyl sulfide
463-58-1*
Carbosulfan
55285-14-8
Catechol
120-80-9*
Chloramben
133-90-4*
Chlordane
57-74-9††
Chlorinated dibenzodioxins
--
Chlorinated dibenzofurans
--
Chlorendic acid
115-28-6
Alpha-Chlorinated toluenes
--
Chlorinated paraffins ([C12, 60% chlorine)]
108171-26-2
Chlorine
7782-50-5*
Chloroacetic acid
79-11-18*
2-Chloroacetophenone
532-27-4*
Chlorobenzene
108-90-7*
Chlorobenzilate
510-15-6*
Chloroform
67-66-3*
Chloromethyl methyl ether
107-30-2*
34-Chloro-2-methylpropene
563-47-3
4-Chloro-o-phenylenediamine
95-83-0
16
p-Chloro-o-toluidine
95-69-2
4-Chlorophenyl phenyl ether
7005-72-3**
Chloroprene
126-99-8*
Chromium
7440-47-3
Chromium (VI)
18540-29-9
Chrysene
218-01-9
Coal tar (pitch) volatiles
65996-93-2
Cobalt
7440-48-4
Coke Oven Emissions
--
Copper
7440-50-8
p-Cresidine
120-71-8
Creosote (Coal)
8001-58-9
Cresol (mixed isomers) [Cresols/Cresylic acid
(isomers and mixture)]
1319-77-3*
o-Cresol
95-48-7*
m-Cresol
108-39-4*
p-Cresol
106-44-5*
Cumene
98-82-8*
Cyanazine
21725-46-2
Cyclohexanone
108-94-1
DDD
72-54-8
DDE
3547-04-4*
4,4'-DDE
72-55-9**
DDT
50-29-3**
Di-n-octyl phthalate
117-84-0**
2,4-Diaminoanisole
615-05-4
2,4-Diaminoanisole sulfate
39156-41-7
4,4'-Diaminodiphenyl ether
101-80-4
2,4-Diaminotoluene
95-80-7*
Diazomethane
334-88-3*
Dibenzo(a,h)acridine
226-36-8
Dibenzo(a,j)acridine
224-42-0
Dibenzo(a,h)anthracene [1,2:5.6-Dibenzanthracene]
53-70-3**
Dibenzo(a,e)pyrene
192-65-4
Dibenzo(a,h)pyrene
189-64-0
Dibenzo(a,i)pyrene
189-55-9
Dibenzo(a,l)pyrene
191-30-0
Dibenzofurans
132-64-9*
Dibutyl phthalate
84-74-2††
1,2-Dibromo-3-chloropropane
96-12-8*
1,2-Dibromoethane [Ethylene dibromide]
106-93-4*
1,4-Dichlorobenzene(p-)
106-46-7*
17
3,3'-Dichlorobenzidine
91-94-1*
3,3'-Dichlorobenzidine dihydrochloride
612-83-9
Dichloroethyl ether
[Bis(2-chloroethyl)ether]
111-44-4*
2,4-Dichlorophenoxyacetic acid
[2,4-D,salts and esters]
94-75-7*
1,2-Dichloropropane
[Propylene dichloride]
78-87-5*
1,3-Dichloropropylene [1,3-Dichloropropene]
542-75-6*
Dichlorvos
62-73-7*
Dieldrin
60-57-1**
Diepoxybutane
1464-53-5
Diethanolamine
111-42-2*
N,N-Diethyl aniline [N,N-Dimethylaniline]
121-69-7*
1,2-Diethylhydrazine
1615-80-1
Di(2-ethylhexyl) pPhthalate [Bis(2-ethylhexyl)
phthalate (DEHP)]
117-81-7*
Diethyl sulfate
64-67-5*
Diglycidyl resorcinol ether
101-90-6
3,3'-Dimethoxybenzidine [Dianisidine]
119-90-4*
Dimethyl acetamide
127-19-5
Dimethyl phthalate
131-11-3*
4-Dimethyl aminoazobenzene [Dimethyl aminoazo-
benzene]
60-11-7*
3,3'-Dimethyl benzidene [o-Tolidine]
119-93-7*
Dimethyl carbamoyl chloride
79-44-7*
N,N-Dimethyl formamide
68-12-2*
1,1-Dimethyl hydrazine
57-14-7*
1,2-Dimethyl hydrazine
540-73-8
Dimethyl sulfate
77-78-1*
Dinitrocresol [4,6-Dinitro-o-cresol, and salts]
534-52-1*
2,4-Dinitrophenol
51-28-5*
2,4-Dinitrotoluene
121-14-2*
1,4-Dioxane [1,4-Diethyleneoxide]
123-91-1*
1,2-Diphenylhydrazine
122-66-7*
Disulfoton
298-04-4
Endothall
145-73-3
Endrin
72-20-8††
Epichlorohydrin
106-89-8*
1,2-Epoxybutane
106-88-7*
2-Ethoxyethanol
110-80-5
Ethyl acrylate
140-88-5*
Ethyl benzene
100-41-4*
Ethyl chloride [Chloroethane]
75-00-3*
18
Ethylene dichloride [1,2-Dichloroethane]
107-06-2*
Ethylene glycol
107-21-1*
Ethylene imine [Aziridine]
151-56-4*
Ethylene oxide
75-21-8*
Ethylene thiourea
96-45-7*
Ethylidene dichloride [1,1-Dichloroethanel]
75-34-3*
Etridiazole
2593-15-9
FMC-67825
95465-99-9
Fluorine
7782-41-4
Folpet
133-07-3
Formaldehyde
50-00-0*
Furmecyclox
60568-05-0
Heptachlor
76-44-8††
Heptachlor epoxide
1024-57-3**
Hexachlorobenzene
118-74-1††
Hexachloro-1,3-butadiene [Hexachlorobutadiene]
87-68-3††
Hexachlorocyclopentadiene
77-47-4*
Hexachlorodibenzo-p-dioxin
19408-74-3
Hexachloroethane
67-72-1*
Hexamethylene-1,6-diisocyanate
822-06-0*
Hexamethylphosphoramide
680-31-9*
Hexane
110-54-3*
Hydrazine
302-01-2*
Hydrazine sulfate
10034-93-2
Hydrochloric acid
7647-01-0*
Hydrogen cyanide
74-90-8
Hydrogen fluoride [Hydrofluoric acid]
7664-39-3*
Hydrogen sulfide
7783-06-4*
Hydroquinone
123-31-9*
Indeno(1,2,3-cd)pyrene
193-39-5**
Isophorone
78-59-1*
Isophorone diisocyanate
4098-71-9
Lead
7439-92-1
Lindane-[Hexachlorocyclohexane-alpha](alpha)
319-84-6**
Lindane-[Hexachlorocyclohexane-beta](beta)
319-85-7**
Lindane-[Hexachlorocyclohexane-gamma](gamma)
[Lindane all isomers]
58-89-9††
Lindane-[Hexachlorocyclohexane-mixed isomers]
(mixed isomers)
608-73-1
Linuron
330-55-2
Malathion
121-75-5
Maleic anhydride
108-31-6*
19
Manganese
7439-96-5
Mercury
7439-97-6**
Methanol
67-56-1*
Methoxychlor
72-43-5††
2-Methoxyethanol
109-86-4
2-Methoxyethanol acetate
110-49-6
Methyl bromide [Bromomethane]
74-83-9*
Methyl chloride [Chloromethane]
74-87-3*
Methyl chloroform [(1,1,1-Trichloroethane]
71-55-6*
Methyl ethyl ketone [2-Butanone]
78-93-3*
Methyl isobutyl ketone [Hexone]
108-10-1*
Methyl isocyanate
624-83-9*
Methyl methacrylate
80-62-6*
Methyl tert butyl ether
1634-04-4*
5-Methylchrysene
3697-24-3
4,4'-Methylene bis(2-chloroaniline)
101-14-4*
Methylenebis(phenylisocyanate) [Methylene
diphenyl diisocyanate (MDI)]
101-68-8
4,4'-Methylenebis(N,N'-dimethyl)benzenamine)
101-61-1
Methylene chloride [Dichloromethane]
75-09-2*
4,4'-Methylenedianiline
101-77-9*
4,4'-Methylenedianiline dihydrochloride
13552-44-8
Methyl hydrazine
60-34-4*
Methyl iodide [Iodomethane]
74-88-4*
Methyl mercaptan
74-93-1
N-Methyl-N'-nitro-N-nitrosoguanidine
70-25-7
Metolachlor
51218-45-2
Michler's Ketone
90-94-8
Mirex
2385-85-5**
Monoethanolamine
141-43-5
Naphthalene
91-20-3*
beta-Naphthylamide
91-59-8
Nickel
7440-02-0
Nitric acid
7697-37-2
Nitrilotriacetic acid
139-13-9
Nitrobenzene
98-95-3*
4-Nitrobiphenyl
92-93-3*
5-Nitro-o-anisidine
99-59-2
2-Nitropropane
79-46-9*
4-Nitrophenol
100-02-7*
N-Nitroso-n-butyl-N-(3-carboxypropyl) amine
38252-74-3
N-Nitroso-n-butyl-N-(4-hydroxybutyl) amine
3817-11-6
20
N-Nitrosodi-n-butylamine
924-16-3
N-Nitrosodiethanolamine
1116-54-7
N-Nitrosodiethylamine
55-18-5
N-Nitrosodimethylamine
62-75-9*
N-Nitrosodiphenylamine
86-30-6
N-Nitrosodi-n-propylamine
621-64-7
N-Nitroso-N-ethylurea
759-73-9
3-(N-Nitrosomethylamino) propionitrile
60153-49-3
N-Nitrosomethylethylamine
10595-95-6
N-Nitroso-N-methylurea
684-93-5*
N-Nitrosomethylvinylamine
4549-40-0
N-Nitrosomorpholine
59-89-2*
N-Nitrosonornicotine
16543-55-8
N-Nitrosopiperidine
100-75-4
N-Nitrosopyrrolidine
930-55-2
N-Nitrososarcosine
13256-22-9
Nitrofen
11836-75-5
Octachlorostyrene
2908-74-4**
PCDDs (Total polychlorinated dibenzodioxins)
--
PCDFs (Total polychlorinated dibenzofurans)
--
PAHs (Total polycyclic aromatic hydrocarbons)
--
Parathion
56-38-2*
Pentachlorobenzene
608-93-5††
Pentachloronitrobenzene [Quintobenzene]
82-68-8*
Pentachlorophenol
87-86-5*
Peracetic acid
79-21-0
Phenol
108-95-2††
p-Phenylenediamine
106-50-3*
Phenylhydrazine
100-63-0
Phorate
298-02-2
Phosgene
75-44-5*
Phosphine
7803-51-2*
Phosphorus
7723-14-0*
Phosphorus oxychloride
10025-87-3
Phosphorus pentachloride
10026-13-8
Photomirex
39801-14-4**
Phthalic anhydride
85-44-9*
Polybrominated biphenyls
--
Polychlorinated biphenyls [Aroclors]
1336-36-3††
Potassium bromate
7758-01-2
Propane sultone [1,3-Propane sultone]
1120-71-4*
beta-Propiolactone
57-57-8*
21
Propionaldehyde
123-38-6*
Propoxur [Baygon]
114-26-1*
Propyleneimine [1,2-Propylenimine(2-Methyl
aziridine)]
75-55-8*
Propylene oxide
75-56-9*
Pyrene
129-00-0
Quinoline
92-22-5*
Quinone
106-51-4*
Selenium
7782-49-2
Sodium borate
1303-96-4
Styrene 100-42-5
Styrene
100-42-5*
Styrene oxide
96-09-3*
Sulfallate
95-06-7
Sulfuric acid
7664-93-9
Terbufos
13071-79-9
1,2,3,4-Tetrachlorobenzene
634-66-2††
1,2,4,5-Tetrachlorobenzene
95-94-3††
1,1,2,2-Tetrachloroethane
79-34-35*
Tetrachloroethylene
[Perchloroethylene]
127-18-4*
2,3,7,8-Tetrachlorodibenzo-p-dioxin
[2,3,7,8-TCDD]
1746-01-6††
4,4'-Thiodianiline
139-65-1
Thiophenol
108-98-5
Thiourea
62-56-6
Thorium dioxide
1314-20-1
Titanium tetrachloride
7550-45-0*
Toluene
108-88-3††
Toluene-2,4-diisocyanate [2,4-Toluene
diisocyanate]
584-84-9*
Toluene-2,6-diisocyanate
91-08-7
o-Toluidine
95-53-4*
o-Toluidine hydrochloride
636-21-5
p-Toluidine
106-49-0
Toxaphene
8001-35-2††
1,2,4-Trichlorobenzene
120-82-1*
1,1,2-Trichloroethane
79-00-5*
Trichloroethylene
79-01-6*
2,4,5-Trichlorophenol
95-95-4*
2,4,6-Trichlorophenol
88-06-2*
Triethylamine
121-44-8*
Trifluralin
1582-09-8*
22
Trimethylbenzene
25551-13-7
1,2,4-Trimethyl benzene
95-63-6
2,4,6-Trinitrotoluene
118-96-7
2,2,4-Trimethylpentane
540-84-1*
Tris(2,3-dibromopropyl) phosphate
126-72-7
Trypan blue
72-57-1
Urethane [Ethyl carbamate]
51-79-6*
Vinyl acetate
108-05-4*
Vinyl bromide
593-60-2*
Vinyl chloride
75-01-4*
Vinylidene chloride [1,1-Dichloroethylene]
75-35-4*
Xylenes (isomers and mixture)
1330-20-7*
o-Xylenes
95-47-6*
m-Xylenes
108-38-3*
p-Xylenes
106-42-3*
Antimony compounds*
--
Includes any unique chemical substance
that contains antimony as part of that
chemical's infrastructure
Arsenic compounds*
--
Includes any unique chemical substance
that contains arsenic as part of that
chemical's infrastructure
Beryllium compounds*
--
Includes any unique chemical substance
that contains beryllium as part of that
chemical's infrastructure
Cadmium compounds*
--
Includes any unique chemical substance
that contains cadmium as part of that
chemical's infrastructure
Chromium compounds*
--
Includes any unique chemical substance
that contains chromium as part of that
chemical's infrastructure
Cobalt compounds*
--
23
Includes any unique chemical substance
that contains cobalt as part of that
chemical's infrastructure
Cyanide compounds*
--
x(pos) CN(neg) where X = H(pos) or any
other group where a formal dissociation
can be made. For example, KCN or Ca(CN)
2
Glycol ethers*
--
Includes any unique chemical substance
that contains glycol as part of that
chemical's infrastructure. Includes
mono- and di- ethers of ethylene glycol,
diethylene glycol, and triethylene glycol
R(OCH
2
CH
2
)
n
-OR' where
n = 1,2, or 3
R = alkyl or aryl groups
R' = R, H, or groups which, when
removed, yield glycol ethers with
the structure: R(OCH
2
CH
2
)
n
-OH.
Polymers are excluded from the glycol
category.
Fine mineral fibers*
--
Includes mineral fiber emissions from
facilities manufacturing or processing
glass, rock, or slag fibers (or other
mineral derived fibers) having the
average diameter of 1 micrometer or
less.
Lead compounds*
--
Includes any unique chemical substance
that contains lead as part of that
chemical's infrastructure
Manganese compounds*
--
Includes any unique chemical substance
that contains manganese as part of that
chemical's infrastructure
24
Mercury compounds*
--
Includes any unique chemical substance
that contains mercury as part of that
chemical's infrastructure
Nickel compounds*
--
Includes any unique chemical substance
that contains nickel as part of that
chemical's infrastructure
Polycyclic Organic Matter (POM)*
--
Includes organic compounds having more
than one benzene ring and a boiling
point equal to or greater than 100
degrees Celsius (212 degrees Farenheit).
Radionuclides (including radon)*
--
A type of atom which spontaneously
undergoes radioactive decay.
Selenium Compounds*
--
Includes any unique chemical substance
that contains selenium as part of that
chemical's infrastructure.
* Indicates presence on HAP List.
**Indicates presence on Great Waters List.
††Indicates presence on HAP and Great Waters Lists.
Section 41 of the Environmental Protection Act (415 ILCS 5/41 (1994)) provides for the
appeal of final Board orders within 35 days of the date of service of this order. The Rules of the
Supreme Court of Illinois establish filing requirements. (See also 35 Ill. Adm. Code 101.246 "Motions
for Reconsideration.")
IT IS SO ORDERED.
I, Dorothy M. Gunn, Clerk of the Illinois Pollution Control Board, hereby certify that the above
opinion and order was adopted on the _____ day of ___________, 1996, by a vote of
______________.
___________________________________
Dorothy M. Gunn, Clerk
Illinois Pollution Control Board