ILLINOIS POLLUTION CONTROL BOARD
September 5, 1996
IN THE MATTER OF:
)
)
R95-17
SAFE DRINKING WATER ACT
)
(Identical-in-Substance Rules)
UPDATE, USEPA Amendments
)
(Public Water Supplies)
(January 1 through June, 30,
)
1995)
)
Adopted Rule. Final Order.
OPINION AND ORDER OF THE BOARD (by R.C. Flemal):
SUMMARY OF TODAY'S ACTION
Pursuant to Section 17.5 of the Environmental Protection Act (Act), the Board today adopts an
update to its regulations that are identical in substance to USEPA regulations implementing the Safe
Drinking Water Act (SDWA). The Board rules are contained in 35 Ill. Adm. Code 611. The text of
the adopted rules appears in the order segment of this document, following the discussions.
Section 17.5 of the Act provides for quick adoption of regulations that are "identical in
substance" to federal regulations. Section 17.5 provides that Title VII of the Act and Section 5 of the
Illinois Administrative Procedure Act (APA) shall not apply. Because this rulemaking is not subject to
Section 5 of the APA (5 ILCS 100/5-35 and 5-45), it is not subject to first notice requirements or
second notice review by the Joint Committee on Administrative Rules (JCAR).
As discussed more fully below, this rulemaking involves revisions of the Illinois public water
supply regulations. It includes the federal amendments to the SDWA analytical procedures corrections
and the deletion of obsolete, redundant, and outdated rules adopted by USEPA on June 29, 1995.
Further involved are several corrections to the base text of the regulations, as requested by the Illinois
EPA (Agency).
PUBLIC COMMENTS
The Board requested public comments on the proposal of April 18, 1996. The Board
accepted comments for more than 45 days after Notices of Proposed Amendments appeared in the
Illinois Register on May 3, 1996, at 20 Ill. Reg. 6121 (Part 607) and 611 (Part 6133). The Board
received the following three comments on the proposal:
PC 1
Illinois EPA (Agency), docketed June 17, 1996, by Connie L. Tonsor, Assistant
Counsel, Division of Legal Counsel.
2
PC 2
Illinois EPA (Agency), docketed June 26, 1996, by Lou Allyn Byus, Assistant
Manager, Field Operations, Division of Public Water Supplies (with attached letter to
Charlene Denys, Chief, Safe Drinking Water Branch, USEPA Region V, including
handwritten reply notes).
PC 3
U.S. Environmental Protection Agency (USEPA), docketed July 9, 1996, by Ronald
W. Murawski, Minnesota/Illinois State Project Officer, Safe Drinking Water Branch.
By PC 1, the Agency expressed general agreement with the approach taken by the Board on
the amendments. It included a small number of suggested revisions, and it requested that the Board
open a general rulemaking docket to consider the Agency-suggested amendments not included in the
April 18, 1996 proposal for public comment. (See discussion on pages 5 through 13 of this opinion
and order.) The Board opened docket R96-18 in response to that request.
PC 2 highlighted an apparent error in the text of certain federal amendments of June 29, 1995
relating to analytical methods. The Agency requested in PC 2 that the Board correct the error in
adopting these amendments. USEPA responded in PC 3 that there was no error. The Board considers
the Agency-suggested correction below, beginning on page 14 of this opinion and order.
REASONS FOR DELAY
Section 7.2(b) of the Environmental Protection Act (415 ILCS 5/7.2(b) requires the Board to
complete the present amendments within one year of the federal action upon which they are based.
Since the date of the earliest federal amendments was June 29, 1995, the nominal due date for
completion of this proceeding was June 29, 1996. The Board has been unable to complete this matter
before that date due to the magnitude of the review of the Public Water Supplies rules prompted by a
request filed by the Illinois EPA, the press of other matters before the Board, and the fact that the
Board will seek additional comment before filing the amendments with the Secretary of State. Section
7.2(b) allows the Board to extend the deadline by publishing a notice of the reasons for delay in the
Illinois Register. The Board presently anticipates filing these amendments within 35 days after the date
of this order--i.e., by October 10, 1996.
The Board will cause a copy of the above segment of this opinion to be published in the Illinois
Register, as required by Section 7.2(b) of the Act.
ROUTINE DISCUSSIONS
3
At the end of the opinion segment of this document are two routine discussions generally made
as part of identical-in-substance opinions. The first is a summary of the history of the Illinois SDWA
identical-in-substance proceedings. The second is a summary of some of the conventions the Board
uses in deriving identical-in-substance rules. We present those discussions for general informational
purposes.
FEDERAL ACTIONS COVERED BY THIS RULEMAKING
AND GENERAL DISCUSSION OF THE PRESENT ISSUES
The SDWA program was drawn from 40 CFR 141 (national primary drinking water regulations
or NPDWRs), 40 CFR 142 (NPDWRs implementation), and 40 CFR 143 (national secondary
drinking water regulations or NSDWRs). The nominal update period of the R95-17 docket is from
January 1, 1995 through June 30, 1995. USEPA amended its SDWA regulations three times during
the update period; two sets of amendments require Board action, and the third does not. The federal
actions during the time-frame of this docket were as follows:
60 Fed. Reg. 33658 (June 28, 1995)
(Revisions to State Primacy Provisions)
60 Fed. Reg. 33926 (June 29, 1995)
(Deletion of Obsolete, Redundant, and Out-Dated
Rules)
60 Fed. Reg. 34084 (June 29, 1995)
(Analytical Methods Technical Corrections)
The amendments to the state primacy provisions, adopted by USEPA on June 28, 1995,
amended the provisions for withdrawal of federal authorization of a state's SDWA program. None of
the USEPA amendments affected the actual state program requirements, so no Board action is
necessary beyond noting the federal action. The deletion of obsolete, redundant, and out-dated rules on
June 29, 1995 included revisions to elements of the federal rules that have counterparts in the Illinois
regulations. Amendments resulted to the Illinois rules from those federal amendments. The analytical
methods amendments of June 29, 1995 corrected minor errors in the analytical methods amendments of
December 5, 1994 (59 Fed. Reg. 1994), adopted by the Board in consolidated docket R94-24/R95-3
on June 15, 1995, and in the July 17, 1992 (57 Fed. Reg. 31776) federal Phase V rules, adopted by
the Board in docket R93-1 on July 13, 1993. The June 29, 1993 analytical methods corrections also
require Board action.
Board action is further required by a comment filed March 1, 1996 by the Agency. That
comment highlights various errors and inconsistencies in the text of all of the Subtitle F regulations
(including the groundwater protection and groundwater quality rules). The Agency requested numerous
corrections to the text of the rules. Further discussion of this request and a detailed outline of the
corrections appear below on pages 5 through 13 of this discussion.
4
DETAILED SECTION-BY-SECTION-ANALYSIS
The Board adopts amendments in response to these federal actions. The following detailed
section-by-section discussion focuses on the details of the actions taken.
Routine, General and Housekeeping Amendments--All Sections
The Board has performed a number of standard revisions to the text of the federal rules. The
single most common revision is a change in usage to "USEPA", reversing the changes begun in an earlier
update docket. The Joint Committee on Administrative Rules requested that the Board standardize the
usage, choosing either "USEPA" or "U.S. EPA" throughout the text of all regulations in all media (air,
water, land, drinking water, etc.). The Agency Bureau of Air requested that the Board use "USEPA".
After consideration of the Bureau of Air's request, the Board elected to begin the conversion to
"USEPA", which commences in this docket as to the drinking water regulations and which will continue
into the future. Other standard revisions are so minor as to warrant no explanation. The standard
changes are as follows:
1.
Where the federal rules require an action "by" a certain date, the Board renders that as "on or
before" that date.
2.
We have changed various subsections to the active voice, rather than following the federal use
of the passive voice.
3.
We have updated all Board Notes to reflect the 1995 version of the Code of Federal
Regulations, where appropriate.
Agency-Requested Corrections to the Rules--Many Sections
The Board received a letter on March 4, 1996 from the Agency. The Agency has reviewed all
of the Subtitle F regulations. The letter highlights a number of errors and format anomalies in the texts of
Parts 601, 602, 603, 606, 607, 611, 615, 616, 617, and 620. The Agency uses the letter to suggest a
number of corrective and conforming amendments that it wants the Board to ultimately make to the texts
in Subtitle F. The Board is making a great number of the revisions suggested by the Agency, but we
cannot make all the requested changes in the context of this proceeding. For a variety of reasons,
1
most
1
Most notably, many of the requested corrections relate to rules adopted by the Section 27 general
rulemaking procedure, they do not affect identical-in-substance subject matter, and/or the amendments
may require substantive review of the affected rule.
5
of the amendments the Board is not making in this proceeding are the proper subject of a Section 27
general rulemaking proceeding; those amendments are not the proper subject of a Section 17.5
identical-in-substance proceeding.
Parts 601 through 611 constitute the current Illinois drinking water rules. The primary emphasis
of Parts 601, 602, 603, 606, and 607 is on regulations unique to Illinois; these Parts predate the advent
of the current federal primary drinking water rules, and segments of those older rules survive in Parts
601, 602, 603, and 607. The Board ultimately repealed Parts 604 and 605 in the course of implement
the federal primary drinking water regulations of 40 CFR 141 through 143, from which Part 611 is
derived. The Board cannot "amend" the repealed Parts 604 and 605 so as to update the format of the
Source Notes, as requested by the Agency. Further, most of the Agency-requested corrective and
conforming amendments to Parts 601, 602, 603, 606, and 607 are not necessary to implementing the
federal primary drinking water regulations, and some would require substantive review of the rules.
Neither of these types of action is appropriate in the context of an identical-in-substance proceeding.
Parts 615 through 617 are the Illinois water well setback regulations, adopted using the general
rulemaking procedure of Sections 14.4 and 27 of the Act in R89-5, effective January 10, 1992. The
Board adopted Part 620 pursuant to Section 27 of the Act and Section 8 of the Illinois Groundwater
Protection Act [415 ILCS 55/8] in R89-14, effective November 25, 1991. The subject matters of the
setback and groundwater protection rules do not relate to the federal primary drinking water
regulations. Amendment of these Parts is also inappropriate in the context of an identical-in-substance
proceeding.
The Board has reviewed the entire list of over 100 suggested revisions submitted by the
Agency. Numerous amendments have resulted to the texts of Parts 607 and 611. The Board made the
recommended corrections and revisions within these Parts that were related to the Board's identical-in-
substance mandate under Section 17.5 of the Act. The table indicates a summary response to each
Agency suggestion, and notes at the end of the table give further explanation where necessary. The
following summarizes the Agency's suggestions and indicates the Board's response to each:
Agency-Recommended Corrections and Revisions
Section
Agency Request
Board Response/Action
1. 601 Source Note
Update to ILCS citation
§ 27 subject matter
2. 601.101
Update to ILCS citation
§ 27 subject matter
3. 601.103
Section missing from SOS file
Call SOS and provide copy of
filed rule
4. 601.105 "Act"
Update to ILCS citation
§ 27 subject matter
5. 601.105 "boil order"
Change "bacteriologically" to
"microbiologically"
§ 27 subject matter
6
6. 601.105 "certified
laboratory"
Add reference to Illinois Department of
Nuclear Safety; Update to ILCS
citation
§ 27 subject matters
7. 601.105 "persistent
contamination"
Change "check samples" to "repeat
samples"
See note 1 below
8. 601.105 "recurring
contamination"
Change "calendar year" to "twelve
consecutive month period"
See note 2 below
9. 601.105 "re-sell
water"
Change to "sell water"
See note 3 below
10. 602 Source Note
Update to ILCS citation
§ 27 subject matter
11. 602.105
Update names of statutes cited; update
to ILCS citations
§ 27 subject matters
12. 602.108
Repunctuate Section; correct cross-
reference to Section 602.105(c)
§ 27 subject matters
13. 602.109(a)
Correct to "registered person"
§ 27 subject matter
14. 602.110(c)
Add definite article before "permittee"
§ 27 subject matter
15. 602.114
Add comma after "Part"
§ 27 subject matter
16. 602.115(b)
Update to ILCS citation
§ 27 subject matter
17. 602.120
Change to "this Part"
§ 27 subject matter
18. 603 Source Note
Update to ILCS citation
§ 27 subject matter
19. 603.102
Update statutory citations; update to
ILCS citation
§ 27 subject matters
20. 603.103
Update statutory citations; update to
ILCS citation
§ 27 subject matters
21. 603.103(a)
Change "for" to "of"
§ 27 subject matter
22. 603.104
Update statutory citations; update to
ILCS citation
§ 27 subject matters
23. 603.104(c)
Change "for" to "of"
§ 27 subject matter
24. 604.401
Provision not shown as repealed in
SOS filed copy
Call SOS to assure Section does
not appear
25. 607 Source Note
Update to ILCS citation
See Note 4 below
26. 607.103(a)
Add requirement for boiling minimum
specified time; add requirement for
continuing notice until occurrence of
specified event
§ 27 subject matter
27. 607.103(b)
Repunctuate subsection for enhanced
clarity
§ 27 subject matter
28. 607.104(c)
Change reference to Part 611, to reflect
repeal of Parts 605 and 606
Done in this docket; see note 4
below
7
29. 607.104(e)
Correct "35 Ill. Adm. Code 603.103 or
604.102" to "35 Ill. Adm. Code 104 or
Section 17(b) of the Act
§ 27 subject matter
30. 611.100(a)
Correct ILCS citation to Section 17.5
Done in this docket
31. 611.100(b)
Add "to"
Done in this docket
32. 611.102(b)
"Technical Bulletin 601"
Change "Test" to "Testing"
Done in this docket
33. 611.102(b)
"ASTM Method
D1688-90 A or C"
Change "Graphit" to "Graphite"
Done in this docket
34. 611.130(b)(2)(A)
Change "TTHM" to "Fluoride"
Done in this docket
35. 611.130(c)(1)
Board Note
Change "PAT" to "PTA"
See note 5 below
36. 611.212(b)(3)(A)
Add "or"
Done in this docket
37. 611.212(d)(3)
Change "organism" to "organisms"
Done in this docket
38. 611.212(e)(1)
Correct "turbidity"
Done in this docket
39. 611.212(f)(2)
Add "surface"
Done in this docket
40. 611.212(g)
Correct "occurrence"
Done in this docket
41. 611.220 Board
Note
Correct citation to Public Health Code
See note 6 below
42. 611.357(c)(1)
Correct cross-reference to
"611.356(d)(2)(A)"
Done in this docket
43. 611.357(c)(2)
Correct cross-reference to
"611.356(d)(2)(B)"
Done in this docket
44. 611.359(a)(2)(C)
Add reference to the Agency's future
35 Ill. Adm. Code 184 regulations
See note 7 below
45. 611.510(b)(11)
Correct dieldrin method to "525.2"
Done in this docket, see note 8
below
46. 611.531(a)(2)
Change "to" to "of"
See note 9 below
47. 611.591
Correct "result of analysis . . . indicates"
Done in this docket
48. 611.606(b)
Insert "a"
Done in this docket
49. 611.611(a)(22)(E)
Correct "discrete"
Done in this docket
50. 611.611(c)(1)
Add reference to the Agency's future
35 Ill. Adm. Code 184 regulations
See note 7 below
51. 611.611(c)(2)(G)
Correct "mg/L"
Done in this docket
52. 611.630(b)
Add comma
Done in this docket
53. 611.641(d)
Correct cross-reference to Section
611.648(k)
See note 10 below
54. 611.645 Board
Note
Correct "alachlor"
Done in this docket
8
55. 611.646(k)(5)(C)
Add "the"
Done in this docket
56. 611.646(q)(1)(A),
(q)(2)(A) & (s)(2)(A)
Add reference to the Agency's future
35 Ill. Adm. Code 184 regulations
See note 7 below
57. 611.648
A page (subsections (l) through (r)) is
missing from the SOS filed copy of the
text
Call SOS and provide copy of
filed rule
58. 611.648(s)(2)(B)
Correct to "below"
Done in this docket
59. 611.683(a), (a)(4)
& (b)(1)
Correct cross-references to Section
611.680(b)
Done in this docket
60. 611.684
Correct cross-reference to Section
611.680(b)
Done in this docket
61. 611.685
Delete references to methods deleted in
R94-23/R95-3; the SOS filed copy has
two versions of the text
References deleted in this
docket; call SOS to assure only
correct version appears
62. 611.720(b)
Correct to "are"
Done in this docket
63. 611.731(a)(1) &
(c)(4)
Repunctuate proviso
Done in this docket
64. 611.731(c)(2)
Change to "processes"
Done in this docket
65. 611.732(a)(2)
Repunctuate proviso; correct to "dose"
Done in this docket
66. 611.831
Delete unnecessary comma
Done in this docket
67. 611.840(b)
Repunctuate for clarity
See note 11 below
68. 611.851(c)(3)
Delete cross-reference to Section
611.647
Done in this docket
69. 611.852(c)(1)
Correct to "within"
Done in this docket
70. 611.855
Missing from the SOS filed text
Call SOS and provide a copy if
needed
71. 611.858
Correct cross-references to Sections
611.301(b) and 611.603
Done in this docket
72. 611.864
Provision not adopted by the Board
appears in SOS text
Call JCAR
73. 611.870
Delete cross-references to repealed
Section 611.650 or repeal whole
Section
Section repealed in this docket
74. 611.App. A(16),
(24), (53), (57), (58) &
(70)
Correct usage to "groundwater"
See note 12 below
75. 611.App. A(20)
Correct punctuation
Done in this docket
76. 611.App. A(28)
Correct to "hearts"
Done in this docket
77. 611.App. A(36),
(40) & (41)
Correct to "an"
Done in this docket
9
78. 611.App. B
Add Table headings used by USEPA;
use "
≤
" and "
≥
"; delete ">"
Done in this docket, see note 13
below
79. 611.App. B, Table
1.1
Correct values to "376" and "298"
Done in this docket
80. 611.App. B, Table
1.3
Correct values to "218" and "226"
Done in this docket
81. 611.App. B, Table
1.4
Correct value to "98"
Done in this docket
82. 611.App. B,
Tables 2.1 & 3.1
Remove decimal points from values;
add missing footnotes from federal text
Done in this docket
83. 611.Table E
The SOS filed text includes two
versions of this provision
Call SOS for deletion of
improper version
84. 611.Table F
Correct alignment of text
Done in this docket
85. 615 Authority Note
Update to ILCS citation
§ 27 subject matter
86. 615.102 preamble,
"groundwater stan-
dards" & "licensed
water well contractor"
Update to ILCS citation
§ 27 subject matter
87. 615.102 "registered
land surveyor" &
"registered professional
engineer"
Update to new statutory citation
§ 27 subject matter
88. 615.203(b)(1) &
(b)(2)
Update to ILCS citation
§ 27 subject matter
89. 615.462
Correct cross-reference to "Subpart E"
§ 27 subject matter
90. 616 Authority Note
Update to ILCS citation
§ 27 subject matter
91. 616.101
Update to ILCS citation
§ 27 subject matter
92. 616.102
Update to ILCS citation
§ 27 subject matter
93. 616.104(g)
Correct statutory source reference to
"Section 14.2(c) of the Act"
§ 27 subject matter
94. 616.447
Correct heading to "Section 616.447"
§ 27 subject matter
95. 617 Authority Note
Update to ILCS citation
§ 27 subject matter
96. 617.101
Update to ILCS citation
§ 27 subject matter
97. 617.102
Update to ILCS citation
§ 27 subject matter
98. 620 Authority Note
Update to ILCS citation
§ 27 subject matter
99. 620.110 preamble,
"IGPA", "Private
Sewage Disposal Act"
& "previously mined
area" Board Note
Update to ILCS citation
§ 27 subject matter
10
100. 620.110 "cumula-
tive impact area"
Correct citation to "Surface Coal
Mining Land Conservation and
Reclamation Act" and update to ILCS
citation
§ 27 subject matter
101. 620.110 "unit"
Correct format of statutory source
reference
§ 27 subject matter
102. 620.260(k)(2)
Correct ILCS citation to "520 ILCS
10"
§ 27 subject matter
103. 620.301(c)
Use "Illinois Oil and Gas Act" in
statutory citation and update to ILCS
citation
§ 27 subject matter
104. 620.420(b)(2)
Update to ILCS citation
§ 27 subject matter
105. 620.450(b)(1)
Update to ILCS citation
§ 27 subject matter
106. 620.505(a)(5)(A)
& (a)(5)(C)
Update to ILCS citations
§ 27 subject matter
Note 1: The term "check" sample is used in Sections 611.680(b)(3) and 611.683(b)(1) of the Board's
rules (as it is in corresponding 40 CFR 141.30(b)(3) and (c)(2)), which relate to trihalomethanes, and in
Section 611.860(a)(2) of the Board's rules (as it is in corresponding 40 CFR 141.33(a)(2)), which
relates to bacteriological sampling. It also appears in Sections 654.301(c); 654.303(b); and
654.304(a), (b), and (e) of the Agency's rules, which relate to bacteriological sampling. The phrase
"repeat" sample is used in Sections 611.325(b), 611.522, 611.523(a)(2) and (a)(3), and 611.525 of
the Board's rules (as it is in corresponding 40 CFR 141.63(b) and 141.21(b), (c)(1)(ii), (c)(1)(iii), and
(e)) in the context of microbiological monitoring. In Section 611.560(b) (and corresponding 40 CFR
141.22(b)), the term relates to turbidity monitoring. Although a federal transition in terminology could
prompt identical-in-substance amendment of Illinois regulations not directly derived from federal
regulations in order to maintain consistency in the rules, the Board will not amend this usage at this time.
The term "check" is used as part of the definition of "persistent contamination" and is not defined here.
That means that this is part of the mixed, interchangeable usage of "check" and "repeat" sampling, rather
than the core source of possible confusion, and the suggested amendment would not add further clarity.
Since alteration of the usage should consider the merits of the regulatory text on some basis other than
consistency with the federal program, this is more appropriately a subject of a Section 27 proceeding.
Note 2: The phrase "recurrent contamination" appears only in Section 653.607(b)(3) of the Agency's
regulations and nowhere else in Parts 601 through 603, 607, or 611 of the Board's rules. Therefore the
requested amendment would not serve to conform the Board's rules to the federal SDWA program.
Amendment or repeal of rules on any other basis is more appropriate in the context of a Section 27
proceeding.
Note 3: The phrase "re-sell water" appears only in this definition. The phrase "sell water" appears only
in Section 611.100(d)(3) (as it is in corresponding 40 CFR 141.3(c)). Therefore the requested
11
amendment would not serve to conform the Board's rules to the federal SDWA program. Amendment
or repeal of rules on any other basis is more appropriate in the context of a Section 27 proceeding.
Note 4: The repeal of Part 605 occurred in docket R93-1, and the repeal of Part 606 occurred in
docket R88-26. Since both dockets were identical-in-substance proceedings, and the Board did not
correct the references at that those times, the amendment is the proper subject of this proceeding.
Since this Part is open for this amendment, the Board will comply with the Agency's request and update
the statutory citation in the authority note to the ILCS citation.
Note 5: The use of "PAT" indicated errors and discrepancies in the text of the federal rules. USEPA
corrected these on July 1, 1994, at 59 Fed. Reg. 34324. The Board did not delete the discussion of
the errors and discrepancies at that time, but is doing so in this docket.
Note 6: The Board cited 77 Ill. Adm. Code 900.40(e), which was the only provision relating to
operator certification that our research revealed. This citation further appears by way of example,
"e.g.". We cannot see that revision is necessary unless the Agency can indicate a more appropriate
citation.
Note 7: The Board cannot cross-reference regulations that do not yet exist. In fact, our research
reveals that the Agency had not proposed these rules as of the March 22, 1996 issue of the Illinois
Register. Since it will take the Agency more time to complete its Part 184 rulemaking under Article V
of the Administrative Procedure Act (5 ILCS 100/5) than for the Board to adopt these amendments
using the identical-in-substance procedure, the Board will wait until at least after the Agency has acted
with regard to Part 184 before we update the cross-references to Part 183 to reflect Part 184. That
will likely occur in some future docket.
Note 8: In making the Agency-suggested correction, the Board notes that method 508.1 was also
omitted for this contaminant. We add that correction to this docket as well.
Note 9: The Board prefers to substitute "for" and has done so.
Note 10: The Board makes the correction in the cross-reference, but since former Section 611.648(k)
is now codified as Section 611.645, the Board used the new location.
Note 11: The Board uses "any" in place of "the" and "of" in place of "in".
Note 12: The term "groundwater" is already used in subsections (16) and (24), and subsection (56) is
amended to delete its substantive language in this proceeding, so the Board made no change in those
subsections. The Board converted all remaining occurrences to "groundwater" in subsections (53),
(57), and (70), a search further revealed that this change was also necessary for subsection (54).
12
Note 13: USEPA uses "
≤
" for pH 9.0 and greater in Tables 1.1 through 1.6. The Board has corrected
this to "
≥
", which is the correct scientific symbol.
The Board has three basic options in dealing with the Agency-requested amendments that we
have determined are more appropriate in the context of a Section 27 general rulemaking proceeding:
1. The Board could wait until the Agency files a separate petition for amendments pursuant to Section
27, doing nothing more until that time, then initiate the requested proceeding; or
2. The Board could interpret the Agency's letter as a petition for amendments pursuant to Section 27,
and immediately assign a separate docket number and initiate the rulemaking with the Agency as
proponent.
The Board invited comment on our responses to the Agency-recommended corrections to the
texts of Subtitle F Public Water Supplies regulations and on the approach we should take to
consideration of the Agency-requested amendments to Subtitle F. The Agency responded in PC 3,
asking that the Board consider its letters as the basis for opening a general rulemaking docket for
consideration of the amendments. In PC 3, the Agency committed to filing a more complete petition for
rulemaking to include these suggested amendments and possible others to the rules. The Board opened
docket R96-18 on June 20, 1196 for consideration of the Agency's suggested amendments.
Corrections to Analytical Methods--Sections 611.102(c), 611.526, 611.531, 611.600, 611.648,
611.683, 611.685 & 611.687
USEPA corrected typographical errors and technical errors and omissions in the SDWA
analytical methods on June 29, 1995, at 60 Fed. Reg. 34084. The Board has incorporated the federal
corrections with minimal deviation in language as necessary to conform with the text and format of the
existing Illinois regulations.
A correction to 40 CFR 141.21(f)(3) added a line about sample storage temperatures at
footnote 1 to the table (corresponding with 35 Ill. Adm. Code 611.526(c)). The Board added this
language as an independent clause, rather than as a separate sentence, and conformed with our existing
"supplier" usage, rather than use "supply". Another correction to footnote 2 (corresponding with 35 Ill.
Adm. Code 611.526(c)(1)(A)) added the omitted language "and false-negative rate".
USEPA corrected the Standard Method 2550B to 2550 for temperature at 40 CFR
141.23(k)(1) (corresponding with 35 Ill. Adm. Code 611.611(a)(24)), in order to reference the entire
method. It further removed footnote 1 to the table at 40 CFR 141.23(k)(4) (corresponding with 35 Ill.
Adm. Code 611.611(b)(1)(A), (b)(3)(A), (b)(4)(A), (b)(5)(A), (b)(6)(A), (b)(9)(A), (b)(10)(A),
(b)(14)(A), and (b)(15)(A)) to remove language already included in the referenced analytical method.
Another correction in the text of the table is in the proper format for "NaOH". It was not necessary for
13
the Board to act on this latter correction, since we did not repeat it in the original adoption of this
provision.
USEPA also corrected aspects of the synthetic and volatile organic chemical contaminant (SOC
and VOC) and trihalomethanes (THM) analytical methods. A correction to the chemical name "1,2-
dibromo-3-chloropropane" appeared in 40 CFR 141.24(h)(18) (corresponding with 35 Ill. Adm. Code
611.648(r)(2)). USEPA restored inadvertently-removed language from Part III of removed Appendix
C to 40 CFR 141.30 at 40 CFR 141.30 (e) and (g) (corresponding with 35 Ill. Adm. Code 611.685
and new 611.687) relating to THM and total THM potential sampling. In incorporating the 40 CFR
141.30(e) language, the Board used this opportunity to correct two oversights from the prior R94-
23/R95-3 docket: we deleted the incorporation of previously-removed 40 CFR 141, Subpart C,
Appendix C from Section 611.102(c), and we restored language pertaining to total THM sampling
erroneously deleted from Section 611.685 in that docket. In incorporating the newly-restored language
of 40 CFR 141.30(g), the Board has divided new Section 611.687 language into subsections for
enhanced clarity, altered the federal text to use "must" in subsection (a), and imposed the provisions of
the subsections (b) and (c) as requirements on the "supplier". USEPA also removed references to
USEPA methods 501.1 and 501.2 from 40 CFR 141.30(e) (corresponding with 35 Ill. Adm. Code
611.685), which USEPA had earlier removed as viable for use. No Board action is required to remove
those references at this time because the Board earlier removed them in R94-24/R95-3, when we made
the amendments necessary to centralize the methods in response to the December 5, 1994 (59 Fed.
Reg. 62469) consolidation of analytical methods. Finally, USEPA added a reference at 40 CFR
141.30(c)(1) (corresponding with 35 Ill. Adm. Code 611.683(a)(1)) to the total THM potential
sampling procedure of 40 CFR 141.30(g). The Board incorporated that amendment without revision.
USEPA also corrected 40 CFR 141.74(a)(1) (corresponding with 35 Ill. Adm. Code
611.531(a)(2)). USEPA deleted the reference to analysis for temperature, corrected the method name
"fecal coliform procedure", added omitted language to footnote 2 to the table pertaining to sample
storage temperatures, and corrected the omission from footnote 3 language referring to the "false-
negative rate" for total coliforms. The Board has incorporated these federal corrections with only minor
deviations from the federal text: we have retained our use of Board Notes to present the federal
footnote material, and we used "the supplier" in place of "systems". Other federal corrections to 40
CFR 141.74(a)(1) were not necessary in the Illinois rules due to differences in the structures of the two
sets of regulations. These include the use of superscript for marking the footnotes.
The Board invited comment on our responses to the federal corrections to the Phase V and
analytical methods regulations. The Agency responded with PC 1, expressing general agreement with
the amendments made. The corrections recommended by the Agency in PC 1 and accepted by the
Board are tabulated as follows:
14
Agency-Prompted Revisions to the Text of the Proposed Rules
Section
Correction
611.100(a), (b) & (e)
Use "USEPA"
611.130(e)(6)
Add "BOARD NOTE:"
611.510(a)(2)
Correct spelling of "application"
611.526(c)
Correct spelling of "hold"
611.526(f)(2)
Use lower case for "agar"
611.526(h)
Correct spelling of "incorporations"
611.646(n), (p) & (q)
Use "USEPA"
611.687(c)(1)
Change "it" to "if"
The Board made no changes in response to a number of Agency recommendations asserting that there
were too many spaces between sentences in a handful of provisions: Sections 611.357(a)(1)(A);
611.526(f)(1), (f)(2), and (f)(3); 611.851(a)(1); and 611.Appendix A(15), (21), (57), (59), (60), and
(68). The Board could find no such errors in the text. However, the re-examination of the text
prompted by the Agency suggestions did disclose a handful of additional necessary corrections that the
Board has made. These are tabulated as follows:
Other Revisions to the Text of the Proposed Rules
Section
Correction
611.102(a) "Guidance Manual . . ."
Capitalize "Using" in title
611.102(a) "Guidance Manual . . .", "USEPA
Asbestos Methods-100.1", "USEPA Asbestos
Methods-100.2", "USEPA Environmental
Inorganics Methods", "USEPA Environmental
Metals Methods", "USEPA Organic Methods"
& "USEPA Technical Notes"
Use "USEPA"
15
611.102(b) "NTIS" & "United States
Environmental Protection Agency, EMSL"
methods listings, "USEPA, Science and
Technology Branch" heading
Use "USEPA"
611.641(d) Board note
Use "USEPA"
611.645 preamble
Use "USEPA"
In submitting PC 2, the Agency suggested further that USEPA made an error at 60 Fed. Reg.
34086 in adding footnote 2 to the entries for total coliforms and fecal coliforms in the table at 40 CFR
141.74(a)(1). The Agency requested that the Board correct the error in the text of the adopted
amendments. Attached to PC 2 is a June 20, 1996 letter from the Agency to USEPA discussing the
apparent error and requesting resolution. At the bottom of that letter is an hand-written note from
USEPA acknowledging the problem and promising resolution.
The addition of footnote 2 to the two entries for total coliforms and fecal coliforms had the
effect of significantly shortening the transit time formerly allowed for samples from 30 hours to eight
hours. The Agency contended in its letter to USEPA that this eight-hour transit time will create hardship
for public water supplies and laboratories in that many would be forced into prearranged direct transit of
samples and immediate analysis, rather than on overnight shipment and analysis. The Agency correctly
highlights that the preamble discussion at 60 Fed. Reg. 34084 considers adding a maximum sample
transit temperature limitation, but does not discuss transit time. The preamble discussion states that the
addition of the temperature limitation--i.e., the only correction relating to footnote 2--rectifies an error
made on December 5, 1994, at 59 Fed. Reg. 62456. The Agency correctly highlights that the
December 5, 1994 discussion at 59 Fed. Reg. 62460 declined to shorten the sample transit time to 24
hours because of the issues of hardship raised in public comments on such a reduction. USEPA stated
that it would work with states to minimize any such hardships if it should decide to reduce the transit
time from 30 hours to 24 hours.
PC 3, from USEPA Region V, relates a response to PC 2 from the Office of Ground Water
and Drinking Water. The Office stated that there is an intended difference between 40 CFR
141.21(f)(3) (corresponding with 35 Ill. Adm. Code 611.526(c)), which allows a 30-hour transit time
for finished water samples, and 40 CFR 141.74(a)(1) (corresponding with 35 Ill. Adm. Code
611.531(a)(1)), which was amended to eight hours for raw water samples from unfiltered supplies. The
Office explained that coliform die-off is more rapid for raw water samples than for finished water
samples, so the differences in the respective transit times "is no discrepancy". The Office proceeded to
explain that there are no unfiltered supplies in Illinois, so the 8-hour transit time would not apply here.
In considering the Agency's request to remove the reference to an eight-hour transit time for
total coliform and fecal coliform samples, we are inclined to agree with the Agency that an error has
16
occurred at the federal level. Further, we find that the comments from USEPA Office of Ground Water
and Drinking Water are not directly relevant to the issue whether USEPA erred in shortening the transit
time requirements. First, USEPA chose not to shorten the transit time to 24 hours on December 5,
1994, instead committing itself to addressing the issues and problems raised by such an action at a
future time. Nothing in the federal action of June 29, 1995 actually addresses the transit time. Rather,
the June 29 action was a series of technical amendments intended to correct the December 5 actions.
The only discussion relating to the corrections to footnote 2 relate to the maximum sample transit
temperature. This does not indicate that USEPA intended to address the transit time issues. Second,
section 4 of the federal Administrative Procedure Act (5 U.S.C. § 553) requires public notice for
comment on amendments to regulations. USEPA did not subject the eight-hour transit time to such
comment. Rather, USEPA made the express determination at 60 Fed. Reg. 34084 that public
comment on its technical corrections was "not necessary or within the public interest". This is a finding
allowed under APA section 4, but usually reserved to instances where the instant amendments do not
raise new issues on which comment has not previously been sought.
Despite this, the Board feels constrained to retain the eight-hour sample transit time
incorporated into the proposal for public comment. Our mandate under Sections 7.2 and 17.5 is to
adopt regulations that are "identical-in-substance" to the federal SDWA regulations. The federal rules
now provide an eight-hour transit time for fecal coliform and total coliform samples between the time of
sampling and the time of analysis. Nothing in the record before the Board clearly and unequivocally
indicates that USEPA did not intend this change. If the Board were to retain the 30-hour transit time
requirement, we would risk a situation in which the Illinois regulations would become less stringent than
the federal rules. This is a risk to federal authorization of the federal program that we are not willing to
take without a very clear indication from USEPA that the change to eight hours was an error and
correction of the error will not jeopardize state primacy.
For these reasons, the Board is retaining the eight-hour maximum sample retention time in this
final opinion and order. Nevertheless, we do believe that USEPA erred in applying this time to total
coliforms and fecal coliforms, so we will withhold filing these amendments for 30 days after the date of
this order. This 30 days will allow the Agency additional time to elicit the comments of USEPA directly
on this issue before the amendments would become effective. If the Board receives an indication from
USEPA that an error has occurred, the Board will have an additional opportunity to amend the rules by
a supplemental opinion and order.
The Board requests supplemental comment from USEPA on the issue of whether
USEPA erred in changing the 30-hour sample retention time for total coliforms and fecal
coliforms to eight hours. Specifically, the Board desires comment on whether we can retain
the 30-hour requirement without rendering the Illinois regulations fatally less stringent than
the federal rules on this point.
17
Deletion of Obsolete, Redundant, and Out-Dated Rules--Sections 611.300, 611.301, 611.600 &
611.Appendix A(56)
USEPA adopted the removal of obsolete, redundant, and out-dated rules on June 29, 1995 (60
Fed. Reg. 33926) in response to a March 4, 1995 Presidential order. The removal rulemakings on that
date embraced several federal environmental programs, including those under the Safe Drinking Water
Act. As to the SDWA primary drinking water regulations, USEPA removed seven segments of the
rules.
An amendment to 40 CFR 141.11 (corresponding with 35 Ill. Adm. Code 611.300) removed
all the old maximum contaminant levels (MCLs) except that for arsenic. Those MCLs appeared in the
newer listing at 40 CFR 141.62 (corresponding with 35 Ill. Adm. Code 611.301). It was not
necessary for the Board to make corresponding deletions, since the Board had already removed the
duplicative MCLs from Section 611.300; however, review of subsections (b) through (d) revealed
other outdated language that we deleted in this proceeding. This included an incorporation by reference
in subsection (d) rendered superfluous by the incorporation of the actual language from the incorporated
federal provision in prior docket R93-1.
Amendments to 40 CFR 141.23(a)(4)(i), 141.62(b)(14), and 141.32(e)(56) (corresponding
with 35 Ill. Adm. Code 611.600(d), 611.301(b), and 611.Appendix A(56), respectively) removed the
MCL and health effects warning for nickel from the table of MCLs, the methods table, and the health
effects provision. It left the nickel entries pertaining to analytical methods, BAT, and detection limits
intact. USEPA undertook this action in response to an agreed judicial remand in the consolidated
litigation in Nickel Development Institute v. EPA, No. 92-1407, and Specialty Steel Industry of the
U.S. v. Browner, No. 92-1410 (D.C. Cir.). The Board adopted the federal deletions without
significant deviation. We added an explanatory Board Note at Sections 611.301(b) and 611.600(d)
relating to the deletion of the nickel MCL. We further used the opportunity to remove obsolete
language from Section 611.301(b) and its Board Note. We also added our customary language at
Section 611.Appendix A(56) to maintain structural parity with the federal rules.
An amendment to 40 CFR 141.23(k)(3)(ii) (corresponding with 35 Ill. Adm. Code
611.611(c)) corrected a typographical error. Since the Board corrected the error when adopting the
original rule in R93-1, the Board need not directly respond to this federal action. Although no
amendment of the corresponding Illinois rule is necessary based on this federal action, the Board
deleted language in the Board Note at Section 611.611(c)(2)(A) that explained our correction of the
federal error.
The Board does not need to respond to three other federal rules deletions. Illinois never
adopted the MCL goals (MCLGs) for drinking water contaminants because these are not mandatory
federal primary drinking water standards. This means that no amendment is necessary to remove the
nickel MCLG entries as in 40 CFR 141.51(b). Similarly, it is not necessary for the Board to respond
18
to the deletion of the one-time health effects notice for lead of 40 CFR 141.34. That requirement
expired prior to the initial implementation of the federal primary drinking water standards when the
Board adopted R88-26. The Board never incorporated that expired provision into the Illinois rules.
The Board invited comment on our responses to the federal deletion of obsolete, redundant,
and out-dated regulations. The Agency responded generally that it agreed with the Board's approach to
these actions.
SDWA REGULATORY HISTORICAL SUMMARY
The Board adopted the initial round of USEPA drinking water regulations, including the "Phase
I" rules, adopted by USEPA prior to June 30, 1989, as follows:
R88-26
114 PCB 149, August 9, 1990 (14 Ill. Reg. 16517, effective September 20,
1990).
Subsequent dockets updated the regulations to include federal amendments since that time:
R90-4
112 PCB 317, dismissed June 21, 1990 (no USEPA amendments July 1
through December 31, 1989).
R90-13
117 PCB 687, December 20, 1990 (15 Ill. Reg. 1562, effective January 22,
1991) (January 1, 1990 through June 30, 1990).
R90-21
116 PCB 365, November 29, 1990 (14 Ill. Reg. 20448, effective December
11, 1990) (Corrections to R88-26).
R91-3
137 PCB 253, November 19, 1992 (16 Ill. Reg. 19010, effective December 1,
1992) (USEPA Phase II and Coliforms--consolidated with R92-9; July 1,
1990 through January 31, 1991).
R91-15
137 PCB 627, dismissed December 3, 1992 (no USEPA amendments
February 1, 1991 through May 31, 1991).
R92-3
-- PCB --, May 6, 1993 (17 Ill. Reg. 7796, effective May 18, 1993) (USEPA
Phase IIB and Lead and Copper rules; June 1, 1991 through December 31,
1991).
R92-9
137 PCB 253, November 19, 1992 (16 Ill. Reg. 19010, effective December 1,
1992) (Corrections to Phase I rules, R88-26--consolidated with R91-3).
19
R92-12
137 PCB 725, dismissed December 3, 1992 (no USEPA amendments June 1,
1992 through June 30, 1991).
R93-1
-- PCB --, July 14, 1993 (17 Ill. Reg. 12648, effective July 23, 1993)
(USEPA Phase V rules; July 1, 1992 through December 31, 1992).
R93-19
-- PCB --, dismissed September 23, 1993 (no USEPA amendments January 1
through June 30, 1993).
R94-4
-- PCB --, July 21, 1994 (18 Ill. Reg. 12291, effective July 28, 1995) (TTHM
analytical methods; July 1, 1993 through December 31, 1993).
R94-23
-- PCB --, June 15, 1995 (19 Ill. Reg. 8613, effective June 20, 1995) (Lead
and Copper Corrections; January 1 through June 30, 1994) (Consolidated
with R95-3).
R95-3
-- PCB --, June 15, 1995 (19 Ill. Reg. 8613, effective June 20, 1995) (Phase
II, IIB & V Corrections & Analytical Methods Amendments; July 1 through
December 31, 1994) (Consolidated with R94-23).
R95-17
This Docket, -- PCB --, September 5, 1996 (-- Ill. Reg. --, effective October
--, 1996) (Corrections to analytical methods and deletion of obsolete,
redundant, and outdated provisions; January 1 through June, 30, 1995).
R96-7
-- PCB --, dismissed March 7, 1996 (no USEPA amendments July 1 through
December 31, 1995).
R97-2
Reserved docket. (January 1 through June 30, 1996).
AGENCY OR BOARD ACTION?
Section 7.2(a)(5) of the Act requires the Board to specify which decisions USEPA will retain.
In addition, the Board is to specify which State agency is to make decisions based on the general
division of functions within the Act and other Illinois statutes.
In situations where the Board has determined that USEPA will retain decision-making authority,
the Board has replaced "Regional Administrator" with USEPA, so as to avoid specifying which office
within USEPA is to make a decision.
20
In a few instances, decisions are not appropriate for Agency action pursuant to a permit
application. Among the considerations in determining the general division of authority between the
Agency and the Board are the following:
1. Is the person making the decision applying a Board regulation, or taking action contrary to
("waiving") a Board regulation? It generally takes some form of Board action to "waive" a
Board regulation.
2. Is there a clear standard for action such that the Board can give meaningful review to an
Agency decision?
3. Does the action result in exemption from the permit requirement itself? If so, Board action
is generally required.
4. Does the decision amount to "determining, defining or implementing environmental control
standards" within the meaning of Section 5(b) of the Act? If so, it must be made by the Board.
There are four common classes of Board decision: variance, adjusted standard, site specific
rulemaking, and enforcement. The first three are methods by which a regulation can be temporarily
postponed (variance) or adjusted to meet specific situations (adjusted standard or site specific
rulemaking). Note that there often are differences in the nomenclature for these decisions between the
USEPA and Board regulations.
EDITORIAL CONVENTIONS
As a final note, the federal rules have been edited to establish a uniform usage throughout the
Board's regulations. For example, with respect to "shall", "will", and "may", "shall" is used when the
subject of a sentence has to do something; "must" is used when someone has to do something, but that
someone is not the subject of the sentence; "will" is used when the Board obliges itself to do something,
and "may" is used when choice of a provision is optional. As to the conjunctions, "or" is used rather
than "and/or", and denotes "one or both"; "either . . . or" denotes "one but not both"; and "and" denotes
"both".
ORDER
The Board will delay 30 days submitting these amendments to the Secretary of State for filing
and publication in the Illinois Register.
21
TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE F: PUBLIC WATER SUPPLIES
CHAPTER I: POLLUTION CONTROL BOARD
PART 607
OPERATION AND RECORD KEEPING
Section
607.101
Protection During Repair Work (Repealed)
607.102
Disinfection Following Repair or Reconstruction (Repealed)
607.103
Emergency Operation
607.104
Cross Connections
607.105
Laboratory Testing Equipment (Repealed)
607.106
Record Maintenance (Repealed)
607.APPENDIXppendix A
References to Former Rules (Repealed)
AUTHORITY: Implementing Section 17 and authorized by Section 27 of the
Environmental Protection Act (Ill. Rev. Stat. 1985, ch. 111 1/2, pars. 1017
and 1027)[415 ILCS 5/17 & 27].
SOURCE: Filed with Secretary of State January 1, 1978; amended and codified
at 6 Ill. Reg. 11497 effective September 14, 1982; amended in R88-26 at 14
Ill. Reg. 16512, effective September 20, 1990; amended in R95-17 at 20 Ill.
Reg. ________, effective ______________________.
Section 607.104
Cross Connections
a)
No physical connection shall be permitted between the potable
portion of a supply and any other water supply not of equal or
better bacteriological and chemical quality as determined by
inspection and analysis by the Agency, except as provided for in
subsection (d).
b)
There shall be no arrangement or connection by which an unsafe
substance may enter a supply.
c)
Control of all cross-connections to a supply is the responsibility
of the owner or official custodian of the supply. If a privately
owned water supply source meets the applicable criteria, it may be
connected to a water supply upon approval by the owner or official
custodian and by the Agency. Where such connections are
permitted, it is the responsibility of the public water supply
officials to assure submission from such privately owned water
supply source or sources samples and operating reports, as
required by 35 Ill. Adm. Code 605 and 606611 as applicable to the
cross-connected source.
d)
The Agency may adopt specific conditions for control of unsafe
cross-connections, which shall be complied with by the supplies of
this State, as applicable. These conditions shall be adopted
22
and/or changed by the Agency as prescribed in 35 Ill. Adm. Code
602.115.
e)
Each community water supply exempted pursuant to 35 Ill. Adm. Code
603.103 or 604.402 shall provide an active program approved by the
Agency to continually educate and inform water supply consumers
regarding prevention of the entry or contaminants into the
distribution system. Conditions under which the Agency will
approve this active program shall be adopted or changed by the
Agency as prescribed in 35 Ill. Adm. Code 602.115.
(Source: Amended at 20 Ill. Reg. ________, effective ______________________)
TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE F: PUBLIC WATER SUPPLIES
CHAPTER I: POLLUTION CONTROL BOARD
PART 611
PRIMARY DRINKING WATER STANDARDS
SUBPART A: GENERAL
Section
611.100
Purpose, Scope and Applicability
611.101
Definitions
611.102
Incorporations by Reference
611.103
Severability
611.107
Agency Inspection of PWS Facilities
611.108
Delegation to Local Government
611.109
Enforcement
611.110
Special Exception Permits
611.111
Section 1415 Variances
611.112
Section 1416 Variances
611.113
Alternative Treatment Techniques
611.114
Siting requirements
611.115
Source Water Quantity
611.120
Effective dates
611.121
Maximum Contaminant Levels and Finished Water Quality
611.125
Fluoridation Requirement
611.126
Prohibition on Use of Lead
611.130
Special Requirements for Certain Variances and Adjusted Standards
SUBPART B: FILTRATION AND DISINFECTION
Section
611.201
Requiring a Demonstration
611.202
Procedures for Agency Determinations
611.211
Filtration Required
611.212
Groundwater under Direct Influence of Surface Water
611.213
No Method of HPC Analysis
611.220
General Requirements
611.230
Filtration Effective Dates
23
611.231
Source Water Quality Conditions
611.232
Site-specific Conditions
611.233
Treatment Technique Violations
611.240
Disinfection
611.241
Unfiltered PWSs
611.242
Filtered PWSs
611.250
Filtration
611.261
Unfiltered PWSs: Reporting and Recordkeeping
611.262
Filtered PWSs: Reporting and Recordkeeping
611.271
Protection during Repair Work
611.272
Disinfection following Repair
SUBPART C: USE OF NON-CENTRALIZED TREATMENT DEVICES
Section
611.280
Point-of-Entry Devices
611.290
Use of Point-of-Use Devices or Bottled Water
SUBPART D: TREATMENT TECHNIQUES
Section
611.295
General Requirements
611.296
Acrylamide and Epichlorohydrin
611.297
Corrosion Control
SUBPART F: MAXIMUM CONTAMINANT LEVELS (MCL's)
Section
611.300
Old MCLs for Inorganic Chemicals
611.301
Revised MCLs for Inorganic Chemicals
611.310
Old MCLs for Organic Chemicals
611.311
Revised MCLs for Organic Contaminants
611.320
Turbidity
611.325
Microbiological Contaminants
611.330
Radium and Gross Alpha Particle Activity
611.331
Beta Particle and Photon Radioactivity
SUBPART G: LEAD AND COPPER
Section
611.350
General Requirements
611.351
Applicability of Corrosion Control
611.352
Corrosion Control Treatment
611.353
Source Water Treatment
611.354
Lead Service Line Replacement
611.355
Public Education and Supplemental Monitoring
611.356
Tap Water Monitoring for Lead and Copper
611.357
Monitoring for Water Quality Parameters
611.358
Monitoring for Lead and Copper in Source Water
611.359
Analytical Methods
611.360
Reporting
611.361
Recordkeeping
SUBPART K: GENERAL MONITORING AND ANALYTICAL REQUIREMENTS
Section
24
611.480
Alternative Analytical Techniques
611.490
Certified Laboratories
611.491
Laboratory Testing Equipment
611.500
Consecutive PWSs
611.510
Special Monitoring for Unregulated Contaminants
SUBPART L: MICROBIOLOGICAL
MONITORING AND ANALYTICAL REQUIREMENTS
Section
611.521
Routine Coliform Monitoring
611.522
Repeat Coliform Monitoring
611.523
Invalidation of Total Coliform Samples
611.524
Sanitary Surveys
611.525
Fecal Coliform and E. Coli Testing
611.526
Analytical Methodology
611.527
Response to Violation
611.531
Analytical Requirements
611.532
Unfiltered PWSs
611.533
Filtered PWSs
SUBPART M: TURBIDITY MONITORING AND ANALYTICAL REQUIREMENTS
Section
611.560
Turbidity
SUBPART N: INORGANIC MONITORING AND ANALYTICAL REQUIREMENTS
Section
611.591
Violation of State MCL
611.592
Frequency of State Monitoring
611.600
Applicability
611.601
Monitoring Frequency
611.602
Asbestos Monitoring Frequency
611.603
Inorganic Monitoring Frequency
611.604
Nitrate Monitoring
611.605
Nitrite Monitoring
611.606
Confirmation Samples
611.607
More Frequent Monitoring and Confirmation Sampling
611.608
Additional Optional Monitoring
611.609
Determining Compliance
611.610
Inorganic Monitoring Times
611.611
Inorganic Analysis
611.612
Monitoring Requirements for Old Inorganic MCLs
611.630
Special Monitoring for Sodium
611.631
Special Monitoring for Inorganic Chemicals
SUBPART O: ORGANIC MONITORING AND ANALYTICAL REQUIREMENTS
Section
611.640
Definitions
611.641
Old MCLs
611.645
Analytical Methods for Organic Chemical Contaminants
611.646
Phase I, Phase II, and Phase V Volatile Organic Contaminants
611.647
Sampling for Phase I Volatile Organic Contaminants (Repealed)
25
611.648
Phase II, Phase IIB, and Phase V Synthetic Organic Contaminants
611.650
Monitoring for 36 Contaminants (Repealed)
611.657
Analytical Methods for 36 Contaminants (Repealed)
611.658
Special Monitoring for Organic Chemicals
SUBPART P: THM MONITORING AND ANALYTICAL REQUIREMENTS
Section
611.680
Sampling, Analytical and other Requirements
611.683
Reduced Monitoring Frequency
611.684
Averaging
611.685
Analytical Methods
611.686
Modification to System
611.687
Sampling for THM Potential
SUBPART Q: RADIOLOGICAL MONITORING AND ANALYTICAL REQUIREMENTS
Section
611.720
Analytical Methods
611.731
Gross Alpha
611.732
Manmade Radioactivity
SUBPART T: REPORTING, PUBLIC NOTIFICATION AND RECORDKEEPING
Section
611.830
Applicability
611.831
Monthly Operating Report
611.832
Notice by Agency
611.833
Cross Connection Reporting
611.840
Reporting
611.851
Reporting MCL and other Violations
611.852
Reporting other Violations
611.853
Notice to New Billing Units
611.854
General Content of Public Notice
611.855
Mandatory Health Effects Language
611.856
Fluoride Notice
611.858
Fluoride Secondary Standard
611.860
Record Maintenance
611.870
List of 36 Contaminants
611.Appendix A
Mandatory Health Effects Information
611.Appendix B
Percent Inactivation of G. Lamblia Cysts
611.Appendix C
Common Names of Organic Chemicals
611.Appendix D
Defined Substrate Method for the Simultaneous Detection of
Total Coliforms and Eschericia Coli from Drinking Water
611.Appendix E
Mandatory Lead Public Education Information
611.Table A
Total Coliform Monitoring Frequency
611.Table B
Fecal or Total Coliform Density Measurements
611.Table C
Frequency of RDC Measurement
611.Table D
Number of Lead and Copper Monitoring Sites
611.Table E
Lead and Copper Monitoring Start Dates
611.Table F
Number of Water Quality Parameter Sampling Sites
611.Table G
Summary of Monitoring Requirements for Water Quality
Parameters
1
26
611.Table Z
Federal Effective Dates
AUTHORITY: Implementing Sections 17 and 17.5 and authorized by Section 27 of
the Environmental Protection Act [415 ILCS 5/17, 17.5 and 27].
SOURCE: Adopted in R88-26 at 14 Ill. Reg. 16517, effective September 20,
1990; amended in R90-21 at 14 Ill. Reg. 20448, effective December 11, 1990;
amended in R90-13 at 15 Ill. Reg. 1562, effective January 22, 1991; amended in
R91-3 at 16 Ill. Reg. 19010, December 1, 1992; amended in R92-3 at 17 Ill.
Reg. 7796, effective May 18, 1993; amended in R93-1 at 17 Ill. Reg. 12650,
effective July 23, 1993; amended in R94-4 at 18 Ill. Reg. 12291, effective
July 28, 1994; amended in R94-23 at 19 Ill. Reg. 8613, effective June 20,
1995; amended in R95-17 at 20 Ill. Reg. ________, effective
______________________.
Note: Capitalization denotes statutory language.
SUBPART A: GENERAL
Section 611.100
Purpose, Scope and Applicability
a)
This Part satisfies the requirement of Section 17.5 of the
Environmental Protection Act (Act) [415 ILCS 5/17.5] that the
Board adopt regulations which are identical in substance with
federal regulations promulgated by the United States Environmental
Protection Agency (U.S. EPA) pursuant to Sections 1412(b),
1414(c), 1417(a) and 1445(a) of the Safe Drinking Water Act (SDWA)
(42 U.S.C. 300f et seq.)
b)
This Part establishes primary drinking water regulations (NPDWRs)
pursuant to the SDWA, and also includes additional, related State
requirements which are consistent with and more stringent than the
U.S. EPA regulations (Section 7.2(a)(6) of the Act). The latter
provisions are specifically marked as "additional State
requirements". They apply only to community water systems (CWSs).
c)
This Part applies to "suppliers", owners and operators of "public
water systems" ("PWSs"). PWSs include CWSs, "non-community water
systems ("non-CWSs") and "non-transient non-community water
systems ("NTNCWSs"), as these terms are defined in Section
611.101.
1)
CWS suppliers are required to obtain permits from the
Illinois Environmental Protection Agency (Agency) pursuant
to 35 Ill. Adm. Code 602.
2)
Non-CWS suppliers are subject to additional regulations
promulgated by the Illinois Department of Public Health
(Public Health) pursuant to Section 9 of the Illinois
27
Groundwater Protection Act [415 ILCS 55/9], including 77
Ill. Adm. Code 900.
3)
Non-CWS suppliers are not required to obtain permits or
other approvals from the Agency, or to file reports or other
documents with the Agency. Any provision in this Part so
providing is to be understood as requiring the non-CWS
supplier to obtain the comparable form of approval from, or
to file the comparable report or other document with Public
Health.
BOARD NOTE: Derived from 40 CFR 141.1 (1994).
d)
This Part applies to each PWS, unless the PWS meets all of the
following conditions:
1)
Consists only of distribution and storage facilities (and
does not have any collection and treatment facilities);
2)
Obtains all of its water from, but is not owned or operated
by, a supplier to which such regulations apply;
3)
Does not sell water to any person; and
4)
Is not a carrier which conveys passengers in interstate
commerce.
BOARD NOTE: Derived from 40 CFR 141.3 (1994).
e)
Some subsection labels have been omitted in order to maintain
local consistency between U.S. EPA subsection labels and the
subsection labels in this Part.
(Source: Amended at 20 Ill. Reg. ________, effective ______________________)
Section 611.102
Incorporations by Reference
a)
Abbreviations and short-name listing of references. The following
names and abbreviated names, presented in alphabetical order, are
used in this Part to refer to materials incorporated by reference:
"Amco-AEPA-1 Polymer" is available from Advanced Polymer
Systems.
"ASTM Method" means a method published by and available from
the American Society for Testing and Materials (ASTM).
"Colisure Test" means "Colisure Presence/Absence Test for
Detection and Identification of Coliform Bacteria and
Escherichia Coli in Drinking Water", available from
Millipore Corporation, Technical Services Department.
28
"Dioxin and Furan Method 1613" means "Tetra- through Octa-
Chlorinated Dioxins and Furans by Isotope-Dilution
HRGC/HRMS", available from NTIS.
"GLI Method 2" means GLI Method 2, "Turbidity", Nov. 2,
1992, available from Great Lakes Instruments, Inc.
"Guidance Manual for Compliance with the Filtration and
Disinfection Requirements for Public Water Systems uUsing
Surface Water Sources", available from U.S. EPA Science and
Technology Branch.
"HASL Procedure Manual" means HASL Procedure Manual, HASL
300, available from ERDA Health and Safety Laboratory.
"Maximum Permissible Body Burdens and Maximum Permissible
Concentrations of Radionuclides in Air and in Water for
Occupational Exposure", NCRP Report Number 22, available
from NCRP.
"NCRP" means "National Council on Radiation Protection".
"NTIS" means "National Technical Information Service".
"ONGP-MUG Test" (meaning "minimal medium ortho-nitrophenyl-
beta-d-galactopyranoside-4-methyl-umbelliferyl-beta-d-
glucuronide test"), also called the "Autoanalysis Colilert
System", is Method 9223, available in "Standard Methods for
the Examination of Water and Wastewater", 18th ed., from
American Public Health Association.
"Procedures for Radiochemical Analysis of Nuclear Reactor
Aqueous Solutions", available from NTIS.
"Radiochemical Methods" means "Interim Radiochemical
Methodology for Drinking Water", available from NTIS.
"Standard Methods", means "Standard Methods for the
Examination of Water and Wastewater", available from the
American Public Health Association or the American
Waterworks Association.
"Technical Bulletin 601" means "Technical Bulletin 601,
"Standard Method of Testing for Nitrate in Drinking Water",
July, 1994, available from Analytical Technology, Inc.
"Technicon Methods" means "Fluoride in Water and
Wastewater", available from Technicon.
29
"U.S. EPA Asbestos Methods-100.1" means Method 100.1,
"Analytical Method for Determination of Asbestos Fibers in
Water", available from NTIS.
"U.S. EPA Asbestos Methods-100.2" means Method 100.2,
"Determination of Asbestos Structures over 10-
μ
m in Length
in Drinking Water", available from NTIS.
"U.S. EPA Environmental Inorganics Methods" means "Methods
for the Determination of Inorganic Substances in
Environmental Samples", available from NTIS.
"U.S. EPA Environmental Metals Methods" means "Methods for
the Determination of Metals in Environmental Samples",
available from NTIS.
"U.S. EPA Inorganic Methods" means "Methods for Chemical
Analysis of Water and Wastes", available from NTIS.
(Methods 150.1, 150.2, and 245.2, which formerly appeared in
this reference, are available from U.S. EPA EMSL.)
"U.S. EPA Organic Methods" means "Methods for the
Determination of Organic Compounds in Drinking Water", July,
1991, for Methods 502.2, 505, 507, 508, 508A, 515.1, and
531.1; "Methods for the Determination of Organic Compounds
in Drinking Water--Supplement I", July, 1990, for Methods
506, 547, 550, 550.1, and 551; and "Methods for the
Determination of Organic Compounds in Drinking Water--
Supplement II", August, 1992, for Methods 515.2, 524.2,
548.1, 549.1, 552.1, and 555, available from NTIS. Methods
504.1, 508.1, and 525.2 are available from EPA EMSL.
"USGS Methods" means "Methods of Analysis by the U.S.
Geological Survey National Water Quality Laboratory--
Determination of Inorganic and Organic Constituents in Water
and Fluvial Sediments", available from NTIS and USGS.
"U.S. EPA Technical Notes" means "Technical Notes on
Drinking Water Methods", available from NTIS.
"Waters Method B-1011" means "Waters Test Method for the
Determination of Nitrite/Nitrate in Water Using Single
Column Ion Chromatography", available from Millipore
Corporation, Waters Chromatography Division.
b)
The Board incorporates the following publications by reference:
Access Analytical Systems, Inc., See Environetics, Inc.
Advanced Polymer Systems, 3696 Haven Avenue, Redwood City,
CA 94063 415-366-2626:
30
Amco-AEPA-1 Polymer. See 40 CFR 141.22(a) (1995).
Also, as referenced in ASTM D1889.
American Public Health Association, 1015 Fifteenth Street
NW, Washington, DC 20005 800-645-5476:
"Standard Methods for the Examination of Water and
Wastewater", 18th Edition, 1992, including "Supplement
to the 18th Edition of Standard Methods for the
Examination of Water and Wastewater", 1994
(collectively referred to as "Standard Methods, 18th
ed."). See the methods listed separately for the same
references under American Water Works Association.
Analytical Technology, Inc. ATI Orion, 529 Main Street,
Boston, MA 02129:
Technical Bulletin 601, "Standard Method of Test for
Nitrate in Drinking Water", July, 1994, PN 221890-001
(referred to as "Technical Bulletin 601").
ASTM. American Society for Testing and Materials, 1976 Race
Street, Philadelphia, PA 19103 215-299-5585:
ASTM Method D511-93 A and B, "Standard Test Methods
for Calcium and Magnesium in Water", "Test Method A--
complexometric Titration" & "Test Method B--Atomic
Absorption Spectrophotometric", approved 1993.
ASTM Method D515-88 A, "Standard Test Methods for
Phosphorus in Water", "Test Method A--Colorimetric
Ascorbic Acid Reduction", approved August 19, 1988.
ASTM Method D859-88, "Standard Test Method for Silica
in Water", approved August 19, 1988.
ASTM Method D1067-92 B, "Standard Test Methods for
Acidity or Alkalinity in Water", "Test Method B--
Electrometric or Color-Change Titration", approved May
15, 1992.
ASTM Method D1125-91 A, "Standard Test Methods for
Electrical Conductivity and Resistivity of Water",
"Test Method A--Field and Routine Laboratory
Measurement of Static (Non-Flowing) Samples", approved
June 15, 1991.
ASTM Method D1179-93 B "Standard Test Methods for
Fluoride in Water", "Test Method B--Ion Selective
Electrode", approved 1993.
31
ASTM Method D1293-84 "Standard Test Methods for pH of
Water", "Test Method A--Precise Laboratory
Measurement" & "Test Method B--Routine or Continuous
Measurement", approved October 26, 1984.
ASTM Method D1688-90 A or C, "Standard Test Methods
for Copper in Water", "Test Method A--Atomic
Absorption, Direct" & "Test Method C--Atomic
Absorbtion, Graphit Furnace", approved March 15, 1990.
ASTM Method D2036-91 A or B, "Standard Test Methods
for Cyanide in Water", "Test Method A--Total Cyanides
after Distillation" & "Test Method B--Cyanides
Amenable to Chlorination by Difference", approved
September 15, 1991.
ASTM Method D2459-72, "Standard Test Method for Gamma
Spectrometry in Water," approved July 28, 1972,
discontinued 1988.
ASTM Method D2907-91, "Standard Test Methods for
Microquantities of Uranium in Water by Fluorometry",
"Test Method A--Direct Fluorometric" & "Test Method
B--Extraction", approved June 15, 1991.
ASTM Method D2972-93 B or C, "Standard Test Methods
for Arsenic in Water", "Test Method B--Atomic
Absorption, Hydride Generation" & "Test Method C--
Atomic Absorption, Graphite Furnace", approved 1993.
ASTM Method D3223-91, "Standard Test Method for Total
Mercury in Water", approved September 23, 1991.
ASTM Method D3559-90 D, "Standard Test Methods for
Lead in Water", "Test Method D--Atomic Absorption,
Graphite Furnace", approved August 6, 1990.
ASTM Method D3645-93 B, "Standard Test Methods for
Beryllium in Water", "Method B--Atomic Absorption,
Graphite Furnace", approved 1993.
ASTM Method D3697-92, "Standard Test Method for
Antimony in Water", approved June 15, 1992.
ASTM Method D3859-93 A, "Standard Test Methods for
Selenium in Water", "Method A--Atomic Absorption,
Hydride Method", approved 1993.
ASTM Method D3867-90 A and B, "Standard Test Methods
for Nitrite-Nitrate in Water", "Test Method A--
32
Automated Cadmium Reduction" & "Test Method B--Manual
Cadmium Reduction", approved January 10, 1990.
ASTM Method D4327-91, "Standard Test Method for Anions
in Water by Ion Chromatography", approved October 15,
1991.
American Waterworks Association et al., 6666 West Quincy
Ave., Denver, CO 80235 303-794-7711:
Standard Methods for the Examination of Water and
Wastewater, 13th Edition, 1971 (referred to as
"Standard Methods, 13th ed.").
Method 302, Gross Alpha and Gross Beta
Radioactivity in Water (Total, Suspended and
Dissolved).
Method 303, Total Radioactive Strontium and
Strontium 90 in Water.
Method 304, Radium in Water by Precipitation.
Method 305, Radium 226 by Radon in Water
(Soluble, Suspended and Total).
Method 306, Tritium in Water.
Standard Methods for the Examination of Water and
Wastewater, 18th Edition, 1992 (referred to as
"Standard Methods, 18th ed."):
Method 2130 B, Turbidity, Nephelometric Method.
Method 2320 B, Alkalinity, Titration Method.
Method 2510 B, Conductivity, Laboratory Method.
Method 2550 B, Temperature, Laboratory and Field
Methods.
Method 3111 B, Metals by Flame Atomic Absorption
Spectrometry, Direct Air-Acetylene Flame Method.
Method 3111 D, Metals by Flame Atomic Absorption
Spectrometry, Direct Nitrous Oxide-Acetylene
Flame Method.
Method 3112 B, Metals by Cold-Vapor Atomic
Absorption Spectrometry, Cold-Vapor Atomic
Absorption Spectrometric Method.
33
Method 3113 B, Metals by Electrothermal Atomic
Absorption Spectrometry, Electrothermal Atomic
Absorption Spectrometric Method.
Method 3114 B, Metals by Hydride
Generation/Atomic Absorption Spectrometry,
Manual Hydride Generation/Atomic Absorption
Spectrometric Method.
Method 3120 B, Metals by Plasma Emission
Spectroscopy, Inductively Coupled Plasma (ICP)
Method.
Method 3500-Ca D, Calcium, EDTA Titrimetric
Method.
Method 4110 B, Determination of Anions by Ion
Chromatography, Ion Chromatography with Chemical
Suppression of Eluent Conductivity.
Method 4500-CN
-
C, Cyanide, Total Cyanide after
Distillation.
Method 4500-CN
-
E, Cyanide, Colorimetric Method.
Method 4500-CN
-
F, Cyanide, Cyanide-Selective
Electrode Method.
Method 4500-CN
-
G, Cyanide, Cyanides Amenable to
Chlorination after Distillation.
Method 4500-Cl D, Chlorine (Residual),
Amperometric Titration Method.
Method 4500-Cl E, Chlorine (Residual), Low-Level
Amperometric Titration Method.
Method 4500-Cl F, Chlorine (Residual), DPD
Ferrous Titrimetric Method.
Method 4500-Cl G, Chlorine (Residual), DPD
Colorimetric Method.
Method 4500-Cl H, Chlorine (Residual),
Syringaldazine (FACTS) Method.
Method 4500-Cl I, Chlorine (Residual),
Iodometric Electrode Technique.
34
Method 4500-ClO
2
C, Chlorine Dioxide,
Amperometric Method I.
Method 4500-ClO
2
D, Chlorine Dioxide, DPD
Method.
Method 4500-ClO
2
E, Chlorine Dioxide,
Amperometric Method II (Proposed).
Method 4500-F
-
B, Fluoride, Preliminary
Distillation Step.
Method 4500-F
-
C, Fluoride, Ion-Selective
Electrode Method.
Method 4500-F
-
D, Fluoride, SPADNS Method.
Method 4500-F
-
E, Fluoride, Complexone Method.
Method 4500-H
+
B, pH Value, Electrometric
Method.
Method 4500-NO
2
-
B, Nitrogen (Nitrite),
Colorimetric Method.
Method 4500-NO
3
-
D, Nitrogen (Nitrate), Nitrate
Electrode Method.
Method 4500-NO
3
-
E, Nitrogen (Nitrate), Cadmium
Reduction Method.
Method 4500-NO
3
-
F, Nitrogen (Nitrate),
Automated Cadmium Reduction Method.
Method 4500-O
3
B, Ozone (Residual) (Proposed),
Indigo Colorimetric Method.
Method 4500-P E, Phosphorus, Ascorbic Acid
Method.
Method 4500-P F, Phosphorus, Automated Ascorbic
Acid Reduction Method.
Method 4500-Si D, Silica, Molybdosilicate
Method.
Method 4500-Si E, Silica, Heteropoly Blue
Method.
Method 4500-Si F, Silica, Automated Method for
Molybdate-Reactive Silica.
35
Method 4500-SO
4
2-
C, Sulfate, Gravimetric Method
with Ignition of Residue.
Method 4500-SO
4
2-
D, Sulfate, Gravimetric Method
with Drying of Residue.
Method 4500-SO
4
2-
F, Sulfate, Automated
Methylthymol Blue Method.
Method 6651, Glyphosate Herbicide (Proposed).
Method 9215 B, Heterotrophic Plate Count, Pour
Plate Method.
Method 9221 A, Multiple-Tube Fermentation
Technique for Members of the Coliform Group,
Introduction.
Method 9221 B, Multiple-Tube Fermentation
Technique for Members of the Coliform Group,
Standard Total Coliform Fermentation Technique.
Method 9221 C, Multiple-Tube Fermentation
Technique for Members of the Coliform Group,
Estimation of Bacterial Density.
Method 9221 D, Multiple-Tube Fermentation
Technique for Members of the Coliform Group,
Presence-Absence (P-A) Coliform Test.
Method 9222 A, Membrane Filter Technique for
Members of the Coliform Group, Introduction.
Method 9222 B, Membrane Filter Technique for
Members of the Coliform Group, Standard Total
Coliform Membrane Filter Procedure.
Method 9222 C, Membrane Filter Technique for
Members of the Coliform Group, Delayed-
Incubation Total Coliform Procedure.
Method 9223, Chromogenic Substrate Coliform Test
(Proposed).
Standard Methods for the Examination of Water and
Wastewater, 18th Edition Supplement, 1994 (Referred to
as "Standard Methods, 18th ed."):
Analytical Technology, Inc. ATI Orion, 529 Main Street,
Boston, MA 02129:
36
Technical Bulletin 601, "Standard Method of Testing
for Nitrate in Drinking Water", July, 1994, PN 221890-
001 (referred to as "Technical Bulletin 601").
ASTM. American Society for Testing and Materials, 1976 Race
Street, Philadelphia, PA 19103 215-299-5585:
ASTM Method D511-93 A and B, "Standard Test Methods
for Calcium and Magnesium in Water", "Test Method A--
complexometric Titration" & "Test Method B--Atomic
Absorption Spectrophotometric", approved 1993.
ASTM Method D515-88 A, "Standard Test Methods for
Phosphorus in Water", "Test Method A--Colorimetric
Ascorbic Acid Reduction", approved August 19, 1988.
ASTM Method D859-88, "Standard Test Method for Silica
in Water", approved August 19, 1988.
ASTM Method D1067-92 B, "Standard Test Methods for
Acidity or Alkalinity in Water", "Test Method B--
Electrometric or Color-Change Titration", approved May
15, 1992.
ASTM Method D1125-91 A, "Standard Test Methods for
Electrical Conductivity and Resistivity of Water",
"Test Method A--Field and Routine Laboratory
Measurement of Static (Non-Flowing) Samples", approved
June 15, 1991.
ASTM Method D1179-93 B "Standard Test Methods for
Fluoride in Water", "Test Method B--Ion Selective
Electrode", approved 1993.
ASTM Method D1293-84 "Standard Test Methods for pH of
Water", "Test Method A--Precise Laboratory
Measurement" & "Test Method B--Routine or Continuous
Measurement", approved October 26, 1984.
ASTM Method D1688-90 A or C, "Standard Test Methods
for Copper in Water", "Test Method A--Atomic
Absorption, Direct" & "Test Method C--Atomic
Absorbtion, Graphite Furnace", approved March 15,
1990.
ASTM Method D2036-91 A or B, "Standard Test Methods
for Cyanide in Water", "Test Method A--Total Cyanides
after Distillation" & "Test Method B--Cyanides
Amenable to Chlorination by Difference", approved
September 15, 1991.
37
ASTM Method D2459-72, "Standard Test Method for Gamma
Spectrometry in Water," approved July 28, 1972,
discontinued 1988.
ASTM Method D2907-91, "Standard Test Methods for
Microquantities of Uranium in Water by Fluorometry",
"Test Method A--Direct Fluorometric" & "Test Method
B--Extraction", approved June 15, 1991.
ASTM Method D2972-93 B or C, "Standard Test Methods
for Arsenic in Water", "Test Method B--Atomic
Absorption, Hydride Generation" & "Test Method C--
Atomic Absorption, Graphite Furnace", approved 1993.
ASTM Method D3223-91, "Standard Test Method for Total
Mercury in Water", approved September 23, 1991.
ASTM Method D3559-90 D, "Standard Test Methods for
Lead in Water", "Test Method D--Atomic Absorption,
Graphite Furnace", approved August 6, 1990.
ASTM Method D3645-93 B, "Standard Test Methods for
Beryllium in Water", "Method B--Atomic Absorption,
Graphite Furnace", approved 1993.
ASTM Method D3697-92, "Standard Test Method for
Antimony in Water", approved June 15, 1992.
ASTM Method D3859-93 A, "Standard Test Methods for
Selenium in Water", "Method A--Atomic Absorption,
Hydride Method", approved 1993.
ASTM Method D3867-90 A and B, "Standard Test Methods
for Nitrite-Nitrate in Water", "Test Method A--
Automated Cadmium Reduction" & "Test Method B--Manual
Cadmium Reduction", approved January 10, 1990.
ASTM Method D4327-91, "Standard Test Method for Anions
in Water by Ion Chromatography", approved October 15,
1991.
Method 6610, Carbamate Pesticides.
ERDA Health and Safety Laboratory, New York, NY:
HASL Procedure Manual, HASL 300, 1973. See 40 CFR
141.25(b)(2) (1995).
Great Lakes Instruments, Inc., 8855 North 55th Street,
Milwaukee, WI 53223:
38
GLI Method 2, "Turbidity", Nov. 2, 1992.
Millipore Corporation, Technical Services Department, 80
Ashby Road, Milford, MA 01730 800-654-5476:
Colisure Presence/Absence Test for Detection and
Identification of Coliform Bacteria and Escherichia
Coli in Drinking Water, February 28, 1994 (referred to
as "Colisure Test").
Millipore Corporation, Waters Chromatography Division, 34
Maple St., Milford, MA 01757 800-252-4752:
Waters Test Method for the Determination of
Nitrite/Nitrate in Water Using Single Column Ion
Chromatography, Method B-1011 (referred to as "Waters
Method B-1011").
NCRP. National Council on Radiation Protection, 7910
Woodmont Ave., Bethesda, MD 301-657-2652:
"Maximum Permissible Body Burdens and Maximum
Permissible Concentrations of Radionuclides in Air and
in Water for Occupational Exposure", NCRP Report
Number 22, June 5, 1959.
NTIS. National Technical Information Service, U.S.
Department of Commerce, 5285 Port Royal Road, Springfield,
VA 22161 (703) 487-4600 or 800-553-6847:
Method 100.1, "Analytical Method for Determination of
Asbestos Fibers in Water", EPA-600/4-83-043,
September, 1983, Doc. No. PB83-260471 (referred to as
"U.S. EPA Asbestos Methods-100.1").
Method 100.2, "Determination of Asbestos Structures
over 10-
μ
m in Length in Drinking Water", EPA-600/4-83-
043, June, 1994, Doc. No. PB94-201902 (Referred to as
"U.S. EPA Asbestos Methods-100.2".
"Methods for Chemical Analysis of Water and Wastes",
March, 1983, Doc. No. PB84-128677 (referred to as
"U.S. EPA Inorganic Methods"). (Methods 150.1, 150.2,
and 245.2, which formerly appeared in this reference,
are available from U.S. EPA EMSL.)
"Methods for the Determination of Metals in
Environmental Samples", June, 1991, Doc. No. PB91-
231498 (referred to as "U.S. EPA Environmental Metals
Methods").
39
"Methods for the Determination of Organic Compounds in
Drinking Water", December, 1988, revised July, 1991,
EPA-600/4-88/039 (referred to as "U.S. EPA Organic
Methods"). (For methods 502.2, 505, 507, 508, 508A,
515.1 and 531.1.)
"Methods for the Determination of Organic Compounds in
Drinking Water--Supplement I", July, 1990, EPA-600-4-
90-020 (referred to as "U.S. EPA Organic Methods").
(For methods 506, 547, 550, 550.1, and 551.)
"Methods for the Determination of Organic Compounds in
Drinking Water--Supplement II", August, 1992, EPA-
600/R-92-129 (referred to as "U.S. EPA Organic
Methods"). (For methods 515.2, 524.2, 548.1, 549.1,
552.1 and 555.)
"Procedures for Radiochemical Analysis of Nuclear
Reactor Aqueous Solutions", H.L. Krieger and S. Gold,
EPA-R4-73-014, May, 1973, Doc. No. PB222-154/7BA.
"Technical Notes on Drinking Water Methods", EPA-
600/R-94-173, October, 1994, Doc. No. PB-104766
(referred to as "U.S. EPA Technical Notes").
BOARD NOTE: U.S. EPA made the following assertion
with regard to this reference at 40 CFR 141.23(k)(1)
and 141.24(e) and (n)(11) (19945): This document
contains other analytical test procedures and approved
analytical methods that remain available for
compliance monitoring until July 1, 1996.
"Tetra- through Octa- Chlorinated Dioxins and Furans
by Isotope Dilution HRGC/HRMS", October, 1994, EPA-
821-B-94-005 (referred to as "Dioxin and Furan Method
1613").
Technicon Industrial Systems, Tarrytown, NY 10591:
"Fluoride in Water and Wastewater", Industrial Method
#129-71W, December, 1972 (referred to as "Technicon
Methods: Method #129-71W"). See 40 CFR
141.23(f)(10), footnotes 6 and 7 (1995).
"Fluoride in Water and Wastewater", #380-75WE,
February, 1976 (referred to as "Technicon Methods:
Method #380-75WE"). See 40 CFR 141.23(f)(10),
footnotes 6 and 7 (1995).
United States Environmental Protection Agency, EMSL,
Cincinnati, OH 45268 513-569-7586:
40
"Interim Radiochemical Methodology for Drinking
Water", EPA-600/4-75-008 (referred to as
"Radiochemical Methods"). (Revised) March, 1976.
"Methods for the Determination of Organic Compounds in
Finished Drinking Water and Raw Source Water"
(referred to as "U.S. EPA Organic Methods"). (For
methods 504.1, 508.1, and 525.2 only). See NTIS.
"Methods for Chemical Analysis of Water and Wastes"
(referred to as "U.S. EPA Inorganic Methods"). See
NTIS. (Methods 150.1, 150.2, and 245.2 only)
"Procedures for Radiochemical Analysis of Nuclear
Reactor Aqueous Solutions". See NTIS.
U. S. EPA, Science and Technology Branch, Criteria and
Standards Division, Office of Drinking Water, Washington
D.C. 20460:
"Guidance Manual for Compliance with the Filtration
and Disinfection Requirements for Public Water Systems
using Surface Water Sources", October, 1989.
USGS. Books and Open-File Reports Section, United States
Geological Survey, Federal Center, Box 25425, Denver, CO
80225-0425:
Methods available upon request by method number from
"Methods of Analysis by the U.S. Geological Survey
National Water Quality Laboratory--Determination of
Inorganic and Organic Constituents in Water and
Fluvial Sediments", Open File Report 93-125 or Book 5,
Chapter A-1, "Methods for Determination of Inorganic
Substances in Water and Fluvial Sediments", 3d ed.,
Open-File Report 85-495, 1989, as appropriate
(referred to as "USGS Methods").
I-1030-85
I-1062-85
I-1601-85
I-1700-85
I-2598-85
I-2601-90
41
I-2700-85
I-3300-85
c)
The Board incorporates the following federal regulations by
reference:
40 CFR 136, Appendix B and C (19945).
40 CFR 141, Subpart C, Appendix C (1994).
d)
This Part incorporates no later amendments or editions.
(Source: Amended at 19 Ill. Reg. 8613, effective June 20, 1995)
Section 611.130
Special Requirements for Certain Variances and Adjusted
Standards
a)
Relief from the TTHM MCL.
1)
In granting any variance or adjusted standard to a supplier
that is a CWS that adds a disinfectant at any part of
treatment and which provides water to 10,000 or more persons
on a regular basis from the maximum contaminant level for
TTHM listed in Section 611.310(c), the Board will require
application of the best available technology (BAT)
identified at subsection (a)(4) below for that constituent
as a condition to the relief, unless the supplier has
demonstrated through comprehensive engineering assessments
that application of BAT is not technically appropriate and
technically feasible for that system, or it would only
result in a marginal reduction in TTHM for that supplier.
2)
The Board will require the following as a condition for
relief from the TTHM MCL where it does not require the
application of BAT:
A)
That the supplier continue to investigate the
following methods as an alternative means of
significantly reducing the level of TTHM, according to
a definite schedule:
i)
introduction of off-line water storage for THM
precursor reduction;
ii)
aeration for TTHM reduction, where geography and
climate allow;
iii)
introduction of clarification, where not
presently practiced;
42
iv)
use of alternative sources of raw water; and
v)
use of ozone as an alternative or supplemental
disinfectant or oxidant, and
B)
That the supplier report results of that investigation
to the Agency.
3)
The Agency shall petition the Board to reconsider or modify
a variance or adjusted standard, pursuant to 35 Ill. Adm.
Code 101.Subpart K, if it determines that an alternative
method identified by the supplier pursuant to subsection
(a)(2) above is technically feasible and would result in a
significant reduction in TTHM.
4)
Best available technology for TTHM reduction:
A)
use of chloramines as an alternative or supplemental
disinfectant,
B)
use of chlorine dioxide as an alternative or
supplemental disinfectant, or
C)
improved existing clarification for THM precursor
reduction.
BOARD NOTE: Derived from 40 CFR 142.60 (1994). The
restrictions of this subsection do not apply to
suppliers regulated for TTHM as an additional state
requirement. See the Board Note to Section
611.301(c).
b)
Relief from the fluoride MCL.
1)
In granting any variance or adjusted standard to a supplier
that is a CWS from the maximum contaminant level for
fluoride listed in Section 611.301(b), the Board will
require application of the best available technology (BAT)
identified at subsection (b)(4) below for that constituent
as a condition to the relief, unless the supplier has
demonstrated through comprehensive engineering assessments
that application of BAT is not technically appropriate and
technically feasible for that supplier.
2)
The Board will require the following as a condition for
relief from the fluoride MCL where it does not require the
application of BAT:
A)
That the supplier continue to investigate the
following methods as an alternative means of
43
significantly reducing the level of TTHM fluoride,
according to a definite schedule:
i)
modification of lime softening;
ii)
alum coagulation;
iii)
electrodialysis;
iv)
anion exchange resins;
v)
well field management;
vi)
use of alternative sources of raw water; and
vii)
regionalization, and
B)
That the supplier report results of that investigation
to the Agency.
3)
The Agency shall petition the Board to reconsider or modify
a variance or adjusted standard, pursuant to 35 Ill. Adm.
Code 101.Subpart K, if it determines that an alternative
method identified by the supplier pursuant to subsection
(b)(2) above is technically feasible and would result in a
significant reduction in fluoride.
4)
Best available technology for fluoride reduction:
A)
activated alumina absorption centrally applied, and
B)
reverse osmosis centrally applied.
BOARD NOTE: Derived from 40 CFR 142.61 (1994).
c)
Relief from an inorganic chemical contaminant, VOC, or SOC MCL.
1)
In granting to a supplier that is a CWS or NTNCWS any
variance or adjusted standard from the maximum contaminant
levels for any VOC or SOC, listed in Section 611.311(a) or
(c), or for any inorganic chemical contaminant, listed in
Section 611.301, the supplier must have first applied the
best available technology (BAT) identified at Section
611.311(b) (VOCs and SOCs) or Section 611.301(c) (inorganic
chemical contaminants) for that constituent, unless the
supplier has demonstrated through comprehensive engineering
assessments that application of BAT would achieve only a
minimal and insignificant reduction in the level of
contaminant.
44
BOARD NOTE: U.S. EPA lists BAT for each SOC and VOC at 40
CFR 142.62(a) (19945), for the purposes of variances and
exemptions (adjusted standards). That list is identical to
the list at 40 CFR 141.61(b) (1995)., with three exceptions:
the section 142.62 listing adds PTA ("PAT") for alachlor;
lists OX for hexachlorobenzene, instead of GAC; and omits
PTA for toxaphene. The Board has chosen to use the section
141.61(a) (Section 611.311) BAT listing because we believe
that this leads to greater consistency.
2)
The Board may require any of the following as a condition
for relief from a MCL listed in Section 611.301 or 611.311:
A)
That the supplier continue to investigate alternative
means of compliance according to a definite schedule,
and
B)
That the supplier report results of that investigation
to the Agency.
3)
The Agency shall petition the Board to reconsider or modify
a variance or adjusted standard, pursuant to 35 Ill. Adm.
Code 101.Subpart K, if it determines that an alternative
method identified by the supplier pursuant to subsection
(c)(2) above is technically feasible.
BOARD NOTE: Derived from 40 CFR 142.62(a) through (e)
(1994).
d)
Conditions requiring use of bottled water or point-of-use or
point-of-entry devices. In granting any variance or adjusted
standard from the maximum contaminant levels for organic and
inorganic chemicals or an adjusted standard from the treatment
technique for lead and copper, the Board may impose certain
conditions requiring the use of bottled water, point-of-entry
devices, or point-of-use devices to avoid an unreasonable risk to
health, limited as provided in subsections (e) and (f) below.
1)
Relief from an MCL. The Board may, when granting any
variance or adjusted standard from the MCL requirements of
Sections 611.301 and 611.311, impose a condition that
requires a supplier to use bottled water, point-of-use
devices, point-of-entry devices or other means to avoid an
unreasonable risk to health.
2)
Relief from corrosion control treatment. The Board may,
when granting an adjusted standard from the corrosion
control treatment requirements for lead and copper of
Sections 611.351 and 611.352, impose a condition that
requires a supplier to use bottled water and point-of-use
45
devices or other means, but not point-of-entry devices, to
avoid an unreasonable risk to health.
3)
Relief from source water treatment or service line
replacement. The Board may, when granting an exemption from
the source water treatment and lead service line replacement
requirements for lead and copper under Sections 611.353 or
611.354, impose a condition that requires a supplier to use
point-of-entry devices to avoid an unreasonable risk to
health.
BOARD NOTE: Derived from 40 CFR 142.62(f) (1994).
e)
Use of bottled water. Suppliers that propose to use or use
bottled water as a condition for receiving a variance or an
adjusted standard from the requirements of Section 611.301 or
Section 611.311, or an adjusted standard from the requirements of
Sections 611.351 through 611.354 must meet the requirements of
either subsections (e)(1), (e)(2), (e)(3), and (e)(6) or (e)(4),
(e)(5) and (e)(6) below:
1)
The supplier must develop a monitoring program for Board
approval that provides reasonable assurances that the
bottled water meets all MCLs of Sections 611.301 and 611.311
and submit a description of this program as part of its
petition. The proposed program must describe how the
supplier will comply with each requirement of this
subsection.
2)
The supplier must monitor representative samples of the
bottled water for all contaminants regulated under Sections
611.301 and 611.311 during the first three-month period that
it supplies the bottled water to the public, and annually
thereafter.
3)
The supplier shall annually provide the results of the
monitoring program to the Agency.
4)
The supplier must receive a certification from the bottled
water company as to each of the following:
A)
that the bottled water supplied has been taken from an
approved source of bottled water, as such is defined
in Section 611.101;
B)
that the approved source of bottled water has
conducted monitoring in accordance with 21 CFR
129.80(g)(1) through (3);
46
C)
and that the bottled water does not exceed any MCLs or
quality limits as set out in 21 CFR 103.35, 110, and
129.
5)
The supplier shall provide the certification required by
subsection (e)(4) above to the Agency during the first
quarter after it begins supplying bottled water and annually
thereafter.
6)
The supplier shall assure the provision of sufficient
quantities of bottled water to every affected person
supplied by the supplier via door-to-door bottled water
delivery.
BOARD NOTE: Derived from 40 CFR 142.62(g) (1994).
f)
Use of point-of-entry devices. Before the Board grants any PWS a
variance or adjusted standard from any NPDWR that includes a
condition requiring the use of a point-of-entry device, the
supplier must demonstrate to the Board each of the following:
1)
that the supplier will operate and maintain the device;
2)
that the device provides health protection equivalent to
that provided by central treatment;
3)
that the supplier will maintain the microbiological safety
of the water at all times;
4)
that the supplier has established standards for performance,
conducted a rigorous engineering design review, and field
tested the device;
5)
that the operation and maintenance of the device will
account for any potential for increased concentrations of
heterotrophic bacteria resulting through the use of
activated carbon, by backwashing, post-contactor
disinfection, and heterotrophic plate count monitoring;
6)
that buildings connected to the supplier's distribution
system have sufficient devices properly installed,
maintained, and monitored to assure that all consumers are
protected; and
7)
that the use of the device will not cause increased
corrosion of lead and copper bearing materials located
between the device and the tap that could increase
contaminant levels at the tap.
BOARD NOTE: Derived from 40 CFR 142.62(h) (1994).
47
(Source: Amended at 20 Ill. Reg. ________, effective ______________________)
SUBPART B: FILTRATION AND DISINFECTION
Section 611.212
Groundwater under Direct Influence of Surface Water
The Agency shall, pursuant to Section 611.201, require all CWSs to demonstrate
whether they are using "groundwater under the direct influence of surface
water" by June 29, 1994. The Agency shall determine with information provided
by the supplier whether a PWS uses "groundwater under the direct influence of
surface water" on an individual basis. The Agency shall determine that a
groundwater source is under the direct influence of surface water based upon:
a)
Physical characteristics of the source: whether the source is
obviously a surface water source, such as a lake or stream. Other
sources which may be subject to influence from surface waters
include: springs, infiltration galleries, wells or other
collectors in subsurface aquifers.
b)
Well construction characteristics and geology with field
evaluation.
1)
The Agency may use the wellhead protection program's
requirements, which include delineation of wellhead
protection areas, assessment of sources of contamination and
implementation of management control systems, to determine
if the wellhead is under the influence of surface water.
2)
Wells less than or equal to 50 feet in depth are likely to
be under the influence of surface water.
3)
Wells greater than 50 feet in depth are likely to be under
the influence of surface water, unless they include:
A)
A surface sanitary seal using bentonite clay, concrete
or similar material,
B)
A well casing that penetrates consolidated (slowly
permeable) material, and
C)
A well casing that is only perforated or screened
below consolidated (slowly permeable) material.
4)
A source which is less than 200 feet from any surface water
is likely to be under the influence of surface water.
c)
Any structural modifications to prevent the direct influence of
surface water and eliminate the potential for Giardia lamblia cyst
contamination.
48
d)
Source water quality records. The following are indicative that a
source is under the influence of surface water:
1)
A record of total coliform or fecal coliform contamination
in untreated samples collected over the past three years,
2)
A history of turbidity problems associated with the source,
or
3)
A history of known or suspected outbreaks of Giardia lamblia
or other pathogenic organisms associated with surface water
(e.g. cryptosporidium), whichthat has been attributed to
that source.
e)
Significant and relatively rapid shifts in water characteristics
such as turbidity, temperature, conductivity or pH.
1)
A variation in turbidity of 0.5 NTU or more over one year is
indicative of surface influence.
2)
A variation in temperature of 9 Fahrenheit degrees or more
over one year is indicative of surface influence.
f)
Significant and relatively rapid shifts in water characteristics
such as turbidity, temperature, conductivity or pH which closely
correlate to climatological or surface water conditions are
indicative of surface water influence.
1)
Evidence of particulate matter associated with the surface
water. or,
2)
Turbidity or temperature data which correlates to that of a
nearby surface water source.
g)
Particulate analysis: Significant occurreance of insects or other
macroorganisms, algae or large diameter pathogens such as Giardia
lamblia is indicative of surface influence.
1)
"Large diameter" particulates are those over 7 micrometers.
2)
Particulates must be measured as specified in the "Guidance
Manual for Compliance with the Filtration and Disinfection
Requirements for Public Water Systems using Surface Water
Sources", incorporated by reference in Section 611.102.
h)
The potential for contamination by small-diameter pathogens, such
as bacteria or viruses, does not alone render the source "under
the direct influence of surface water".
BOARD NOTE: Derived from the definition of "groundwater under the
direct influence of surface water" in 40 CFR 141.2 (19945); from
49
the Preamble at 54 Fed. Reg. 27489 (June 29, 1989); and from the
U.S. EPA "Guidance Manual for Compliance with the Filtration and
Disinfection Requirements for Public Water Systems using Surface
Water Sources", incorporated by reference in Section 611.102.
(Source: Amended at 20 Ill. Reg. ________, effective ______________________)
Section 611.220
General Requirements
a)
The requirements of this Subpart constitute NPDWRs. This Subpart
establishes criteria under which filtration is required as a
treatment technique for PWSs supplied by a surface water source
and PWSs supplied by a groundwater source under the direct
influence of surface water. In addition, these regulations
establish treatment technique requirements in lieu of MCLs for the
following contaminants: Giardia lamblia, viruses, HPC bacteria,
Legionella and turbidity. Each supplier with a surface water
source or a groundwater source under the direct influence of
surface water shall provide treatment of that source water that
complies with these treatment technique requirements. The
treatment technique requirements consist of installing and
properly operating water treatment processes which reliably
achieve:
1)
At least 99.9 percent (3-log) removal or inactivation of
Giardia lamblia cysts between a point where the raw water is
not subject to recontamination by surface water runoff and a
point downstream before or at the first customer; and
2)
At least 99.99 percent (4-log) removal or inactivation of
viruses between a point where the raw water is not subject
to recontamination by surface water runoff and a point
downstream before or at the first customer.
b)
A supplier using a surface water source or a groundwater source
under the direct influence of surface water is considered to be in
compliance with the requirements of subsection (a) if:
1)
It meets the requirements for avoiding filtration in
Sections 611.230 through 611.232 and the disinfection
requirements in Section 611.241; or
2)
It meets the filtration requirements in Section 611.250 and
the disinfection requirements in Section 611.242.
c)
Each supplier using a surface water source or a groundwater source
under the direct influence of surface water shall have a certified
operator pursuant to 35 Ill. Adm. Code 603.103 and the Public
Water Supply Operations Act [415 ILCS 45].
50
BOARD NOTE: Derived from 40 CFR 141.70 (19945). The Public Water
Supply Operations Act applies only to CWSs, which are regulated by
the Agency. It does not apply to non-CWSs, which are regulated by
Public Health. Public Health has its own requirements for
personnel operating water supplies that it regulates, e.g., 77
Ill. Adm. Code 900.40(e).
(Source: Amended at 20 Ill. Reg. ________, effective ______________________)
SUBPART F: MAXIMUM CONTAMINANT LEVELS (MCL'S)
Section 611.300
Old MCLs for Inorganic Chemicals
a)
The old MCLs listed in subsection (b) below for inorganic
chemicals apply only to CWS suppliers. Compliance with old MCLs
for inorganic chemicals is calculated pursuant to Section 611.612,
except that analyses for arsenic are to be performed pursuant to
Section 611.611.
BOARD NOTE: Derived from 40 CFR 141.11(a) (19945).
b)
The following are the old MCL's for inorganic chemicals, with the
old MCL for cyanide effective only until the revised MCL for
cyanide at Section 611.301(a) becomes effective:
Contaminant
Level, mg/L
Additional
State
Requirement (*)
Arsenic
0.05
Iron
1.0
*
Manganese
0.15
*
Zinc
5.
*
BOARD NOTE: Derived from 40 CFR 141.11(b) & (c) (19945).
This provision, which corresponds with 40 CFR 141.11, was
formerly the only listing of MCLs for inorganic parameters.
However, U.S. EPA added another listing of inorganic MCLs
at 40 CFR 141.62 at 56 Fed. Reg. 3594 (Jan. 30, 1991), which
corresponds with Section 611.301. Following the changing
U.S. EPA codification scheme creates two listings of MCLs:
one at this Section and one at Section 611.301. This causes
fluoride to appear in both the 40 CFR 141.11(b) and
141.62(b) listings with the same MCL. The Board has deleted
the corresponding fluoride MCL from this Section in favor of
that which appears at Section 611.301(b).
c)
This subsection corresponds with 40 CFR 141.11(c) (1995), the
substance of which the Board has codified in subsection (b)
51
abovemarked as reserved by USEPA. This statement maintains
structural parity with the federal rules.
d)
Nitrate.
1) The Board incorporates by reference 40 CFR 141.11(d) (1994).
This incorporation includes no later editions or
amendments.
2)
Non-CWSs may exceed the MCL for nitrate under the following
circumstances:
A)
The nitrate level must not exceed 20 mg/L,
B)
The water must not be available to children under six
months of age,
C)
There will be continuous posting of the fact that the
nitrate level exceeds 10 mg/L together with the public
health effects information set forth in paragraph (2)
of Section 611.Appendix A,
D)
The supplier will annually notify local public health
authorities and Public Health of the nitrate levels
that exceed 10 mg/L, and
E)
No adverse public health effects result.
BOARD NOTE: Derived from 40 CFR 141.11(d) (19945).
Public Health regulations may impose a nitrate
limitation requirement. Those regulations are at 77
Ill. Adm. Code 900.50.
e)
The following supplementary condition applies to the MCLs listed
in subsection (b) above for iron and manganese:
1)
CWS suppliers that serve a population of 1000 or less, or
300 service connections or less, are exempt from the
standards for iron and manganese.
2)
The Agency may, by special exception permit, allow iron and
manganese in excess of the MCL if sequestration tried on an
experimental basis proves to be effective. If sequestration
is not effective, positive iron or manganese reduction
treatment as applicable must be provided. Experimental use
of a sequestering agent may be tried only if approved by
special exception permit.
BOARD NOTE: This is an additional State requirement.
(Source: Amended at 20 Ill. Reg. ________, effective ______________________)
52
Section 611.301
Revised MCLs for Inorganic Chemicals
a)
This subsection corresponds with 40 CFR 141.62(a), reserved by
U.S. EPA. This statement maintains structural consistency with
U.S. EPA rules.
b)
The MCLs in the following table apply to CWSs. Except for
fluoride, the MCLs also apply to NTNCWSs. The MCLs for nitrate,
nitrite, and total nitrate and nitrite also apply to transient
non-CWSs. The MCLs for antimony, beryllium, cyanide, nickel, and
thallium are effective January 17, 1994.
Contaminant
MCL
Units
Antimony
0.006
mg/L
Asbestos
7
MFL
Barium
2
mg/L
Beryllium
0.004
mg/L
Cadmium
0.005
mg/L
Chromium
0.1
mg/L
Cyanide (as free CN
-
)
0.2
mg/L
Fluoride
4.0
mg/L
Mercury
0.002
mg/L
Nickel 0.1 mg/L
Nitrate (as N)
10.
mg/L
Nitrite (as N)
1.
mg/L
Total Nitrate and Nitrite
10.
mg/L
(as N)
Selenium
0.05
mg/L
Thallium
0.002
mg/L
BOARD NOTE: See the definition of "initial compliance
period" at Section 611.101. The federal secondary MCL for
fluoride is 2.0 mg/L. The federal regulations require
public notice when water exceeds this level. See 40 CFR
143.3 and 143.5 (1994). The Illinois notice requirement for
fluoride above 2.0 mg/L appears at Section 611.858.See
Section 611.300(d) for an elevated nitrate level for non-
CWSs. USEPA removed and reserved the MCL for nickel on June
29, 1995, at 60 Fed. Reg. 33932, as a result of a judicial
order in Nickel Development Institute v. EPA, No. 92-1407,
and Specialty Steel Industry of the U.S. v. Browner, No. 92-
1410 (D.C. Cir. Feb. 23 & Mar. 6, 1995), while retaining the
contaminant, analytical methodology, and detection limit
listings for this contaminant.
c)
U.S. EPA has identified the following as BAT for achieving
compliance with the MCL for the inorganic contaminants identified
in subsection (b) above, except for fluoride:
53
Contaminant
BAT(s)
Antimony
C/F
RO
Asbestos
C/F
DDF
CC
Barium
IX
LIME
RO
ED
Beryllium
AA
C/F
IX
LIME
RO
Cadmium
C/F
IX
LIME
RO
Chromium
C/F
IX
LIME, BAT for Cr(III) only
RO
Cyanide
IX
RO
Cl
2
Mercury
C/F, BAT only if influent Hg
concentrations less than or equal to (
≤
)
10
μ
g/L
GAC
LIME, BAT only if influent Hg
concentrations
≤
10
μ
g/L
RO, BAT only if influent Hg concentrations
≤
10
μ
g/L
Nickel
IX
LIME
RO
Nitrate
IX
RO
ED
54
Nitrite
IX
RO
Selenium
AAL
C/F, BAT for Se(IV) only
LIME
RO
ED
Thallium
AAL
IX
Abbreviations
AAL
Activated alumina
C/F
Coagulation/filtration
DDF
Direct and diatomite filtration
GAC
Granular activated carbon
IX
Ion exchange
LIME
Lime softening
RO
Reverse osmosis
CC
Corrosion control
ED
Electrodialysis
Cl
2
Oxidation (chlorine)
UV
Ultraviolet irradiation
BOARD NOTE: Derived from 40 CFR 141.62 (19945).
(Source: Amended at 20 Ill. Reg. ________, effective ______________________)
SUBPART G: LEAD AND COPPER
Section 611.357
Monitoring for Water Quality Parameters
All large system suppliers, and all small and medium-sized system suppliers
that exceed the lead action level or the copper action level, shall monitor
water quality parameters in addition to lead and copper in accordance with
this Section. The requirements of this Section are summarized in Section
611.Table G.
a)
General Requirements
1)
Sample collection methods
A)
Use of tap samples. The totality of all tap samples
collected by a supplier shall be representative of
water quality throughout the distribution system
taking into account the number of persons served, the
different sources of water, the different treatment
methods employed by the supplier, and seasonal
55
variability. Although a supplier may conveniently
conduct tap sampling for water quality parameters at
sites used for coliform sampling performed pursuant to
Subpart L of this Part, it is not required to do so,
and a supplier is not required to perform tap sampling
pursuant to this Section at taps targeted for lead and
copper sampling under Section 611.356(a).
B)
Use of entry point samples. Each supplier shall
collect samples at entry point(s) to the distribution
system from locations representative of each source
after treatment. If a supplier draws water from more
than one source and the sources are combined before
distribution, the supplier must sample at an entry
point to the distribution system during periods of
normal operating conditions (i.e., when water is
representative of all sources being used).
2)
Number of samples
A)
Tap samples. Each supplier shall collect two tap
samples for applicable water quality parameters during
each six-month monitoring period specified under
subsections (b) through (e) below from the number of
sites indicated in the first column of Section
611.Table E.
B)
Entry point samples.
i)
Initial monitoring. Each supplier shall collect
two samples for each applicable water quality
parameter at each entry point to the
distribution system during each six-month
monitoring period specified in subsection (b)
below.
ii)
Subsequent monitoring. Each supplier shall
collect one sample for each applicable water
quality parameter at each entry point to the
distribution system during each six-month
monitoring period specified in subsections (c)
through (e) below.
b)
Initial Sampling.
1)
Large systems. Each large system supplier shall measure the
applicable water quality parameters specified in subsection
(b)(3) below at taps and at each entry point to the
distribution system during each six-month monitoring period
specified in Section 611.356(d)(1).
56
2)
Small and medium-sized systems. Each small and medium-sized
system supplier shall measure the applicable water quality
parameters specified in subsection (b)(3) below at the
locations specified in this subsection during each six-month
monitoring period specified in Section 611.356(d)(1) during
which the supplier exceeds the lead action level or the
copper action level.
3)
Water quality parameters:
A)
pH;
B)
alkalinity;
C)
orthophosphate, when an inhibitor containing a
phosphate compound is used;
D)
silica, when an inhibitor containing a silicate
compound is used;
E)
calcium;
F)
conductivity; and
G)
water temperature.
c)
Monitoring after installation of corrosion control.
1)
Large systems. Each large system supplier that installs
optimal corrosion control treatment pursuant to Section
611.351(d)(4) shall measure the water quality parameters at
the locations and frequencies specified in subsections
(c)(3) and (c)(4) below during each six-month monitoring
period specified in Section 611.356(d)(2)(iA).
2)
Small and medium-sized systems. Each small or medium-sized
system that installs optimal corrosion control treatment
pursuant to Section 611.351(e)(5) shall measure the water
quality parameters at the locations and frequencies
specified in subsections (c)(3) and (c)(4) below during each
six-month monitoring period specified in Section
611.356(d)(2)(iiB) in which the supplier exceeds the lead
action level or the copper action level.
3)
Tap water samples, two samples at each tap for each of the
following water quality parameters:
A)
pH;
B)
alkalinity;
57
C)
orthophosphate, when an inhibitor containing a
phosphate compound is used;
D)
silica, when an inhibitor containing a silicate
compound is used; and
E)
calcium, when calcium carbonate stabilization is used
as part of corrosion control.
4)
Entry point samples, one sample at each entry point to the
distribution system every two weeks (bi-weekly) for each of
the following water quality parameters:
A)
pH;
B)
when alkalinity is adjusted as part of optimal
corrosion control, a reading of the dosage rate of the
chemical used to adjust alkalinity, and the alkalinity
concentration; and
C)
when a corrosion inhibitor is used as part of optimal
corrosion control, a reading of the dosage rate of the
inhibitor used, and the concentration of
orthophosphate or silica (whichever is applicable).
d)
Monitoring after the Agency specifies water quality parameter
values for optimal corrosion control.
1)
Large systems. After the Agency has specified the values
for applicable water quality control parameters reflecting
optimal corrosion control treatment pursuant to Section
611.352(f), each large system supplier shall measure the
applicable water quality parameters in accordance with
subsection (c) above during each six-month monitoring period
specified in Section 611.356(d)(3).
2)
Small and medium-sized systems. Each small or medium-sized
system supplier shall conduct such monitoring during each
six-month monitoring period specified in Section
611.356(d)(3) in which the supplier exceeds the lead action
level or the copper action level.
3)
Confirmation sampling.
A)
A supplier may take a confirmation sample for any
water quality parameter value no later than 3 days
after it took the original sample it seeks to confirm.
B)
If a supplier takes a confirmation sample, it must
average the result obtained from the confirmation
sample with the result obtained from the original
58
sample it seeks to confirm, and the supplier shall use
the average of these two results for any compliance
determinations under Section 611.352(g).
C)
The Agency shall delete the results that it determines
are due to obvious sampling errors from this
calculation.
e)
Reduced monitoring.
1)
Reduction in tap monitoring. A supplier that has maintained
the range of values for the water quality parameters
reflecting optimal corrosion control treatment during each
of two consecutive six-month monitoring periods under
subsection (d) above shall continue monitoring at the entry
point(s) to the distribution system as specified in
subsection (c)(4) above. Such a supplier may collect two
samples from each tap for applicable water quality
parameters from the reduced number of sites indicated in the
second column of Section 611.Table E during each subsequent
six-month monitoring period.
2)
Reduction in monitoring frequency.
A)
Stages of reductions.
i)
Annual monitoring. A supplier that maintains
the range of values for the water quality
parameters reflecting optimal corrosion control
treatment specified pursuant to Section
611.352(f) during three consecutive years of
monitoring may reduce the frequency with which
it collects the number of tap samples for
applicable water quality parameters specified in
subsection (e)(1) above from every six months to
annually.
ii)
Triennial monitoring. A supplier that maintains
the range of values for the water quality
parameters reflecting optimal corrosion control
treatment specified pursuant to Section
611.352(f) during three consecutive years of
annual monitoring under subsection (e)(2)(A)(i)
above may reduce the frequency with which it
collects the number of tap samples for
applicable water quality parameters specified in
subsection (e)(1) above from annually to once
every three years.
B)
A supplier that conducts sampling annually or every
three years shall collect these samples evenly
59
throughout the calendar year so as to reflect seasonal
variability.
C)
Any supplier subject to a reduced monitoring frequency
pursuant to this subsection that fails to operate
within the range of values for the water quality
parameters specified pursuant to Section 611.352(f)
shall resume tap water sampling in accordance with the
number and frequency requirements of subsection (d)
above.
f)
Additional monitoring by systems. The results of any monitoring
conducted in addition to the minimum requirements of this section
shall be considered by the supplier and the Agency in making any
determinations (i.e., determining concentrations of water quality
parameters) under this Section or Section 611.352.
BOARD NOTE: Derived from 40 CFR 141.87 (19945).
(Source: Amended at 20 Ill. Reg. ________, effective ______________________)
SUBPART K: GENERAL MONITORING AND ANALYTICAL REQUIREMENTS
Section 611.510
Special Monitoring for Unregulated Contaminants
a)
Monitoring for Phase I unregulated contaminants.
1)
All CWS and NTNCWS suppliers shall begin monitoring for the
contaminants listed in subsection (a)(5) no later than the
the following dates:
A)
Less than 3300 persons served: January 1, 1991.
B)
3300 to 10,000 persons served: January 1, 1989.
C)
More than 10,000 persons served: January 1, 1988.
2)
SWS and mixed system suppliers shall sample at points in the
distribution system representative of each water source or
at entry points to the distribution system after any
applicaition of treatment. The minimum number of samples is
one year of quarterly samples per water source.
3)
GWS suppliers shall sample at points of entry to the
distribution system representative of each well after any
application of treatment. The minimum number of samples is
one sample per entry point to the distribution system.
4)
The Agency may issue a SEP pursuant to Section 610.110 to
require a supplier to use a confirmation sample for results
60
that it finds dubious for whatever reason. The Agency must
state its reasons for issuing the SEP if the SEP is Agency-
initiated.
5)
List of Phase I unregulated chemical contaminants:
Bromobenzene
Bromodichloromethane
Bromoform
Bromomethane
Chlorobenzene
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
o-Chlorotoluene
p-Chlorotoluene
Dibromomethane
m-Dichlorobenzene
1,1-Dichloroethane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
1,3-Dichloropropene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
1,2,3-Trichloropropane
6)
This subsection corresponds with 40 CFR 141.40(f), reserved
by U.S. EPA. This statement maintains structural
consistency with U.S. EPA rules.
7)
Analyses performed pursuant to subsection (a) shall be
conducted using the following U.S. EPA Organic Methods:
Methods 502.2 or 524.2 or their equivalent as approved by
the Agency, except that analyses for bromodichloromethane,
bromoform, chlorodibromomethane, and chloroform may also be
performed using U.S. EPA Organic Methods: Method 551, and
analyses for 1,2,3-trichloropropane may also be performed
using U.S. EPA Organic Methods: Method 504.1, all of which
are incorporated by reference in Section 611.102.
BOARD NOTE: Subsection (b) derived from 40 CFR 141.40(a)
through (m) (19945), as amended at 59 Fed. Reg. 62469 (Dec.
5, 1994). The Board has adopted no counterpart to 40 CFR
141.40(h), which the Board has codified at subsection (c)
below; 141.40(i), which pertains to the ability of suppliers
to grandfather data up until a date long since expired;
141.41(j), an optional U.S. EPA provision relating to
monitoring 15 additional contaminants that U.S. EPA does not
require for state programs; 141.40(k), which pertains to
61
notice to the Agency by smaller suppliers up until a date
long since expired in lieu of sampling; 141.40(l), which the
Board has adopted at subsection (d) below; and 141.40(m), an
optional provision that pertains to composite sampling.
Otherwise, the structure of this Section directly
corresponds with 40 CFR 141.40(a) through (m) (19945).
b)
Monitoring for Phase V unregulated contaminants. Monitoring of
the unregulated organic contaminants listed in subsection (b)(11)
below and the unregulated inorganic contaminants listed in
subsection (b)(12) below shall be conducted as follows:
1)
Each CWS and NTNCWS supplier shall take four consecutive
quarterly samples at each sampling point for each
contaminant listed in subsection (b)(11) below and report
the results to the Agency. Monitoring must be completed by
December 31, 1995.
2)
Each CWS and NTNCWS supplier shall take one sample at each
sampling point for each contaminant listed in subsection
(b)(12) below and report the results to the Agency.
Monitoring must be completed by December 31, 1995.
3)
Each CWS and NTNCWS supplier may apply to the Agency for a
SEP pursuant to Section 611.110 that releases it from any of
the requirements of subsections (b)(1) and (b)(2) above.
4)
The Agency shall grant a SEP pursuant to Section 611.110 as
follows:
A)
From any requirement of subsection (b)(1) above based
on consideration of the factors set forth at Section
611.110(e), and
B)
From any requirement of subsection (b)(2) above if
previous analytical results indicate contamination
would not occur, provided this data was collected
after January 1, 1990.
5)
A GWS supplier shall take a minimum of one sample at every
entry point to the distribution system that is
representative of each well after treatment ("sampling
point").
6)
A SWS or mixed system supplier shall take a minimum of one
sample at points in the distribution system that are
representative of each source or at each entry point to the
system after treatment ("sampling point").
7)
If the system draws water from more than one source and
sources are combined before distribution, the supplier shall
62
sample at an entry point during periods of normal operating
conditions (when water representative of all sources is
being used).
8)
The Agency may issue a SEP pursuant to Section 610.110 to
require a supplier to use a confirmation sample for results
that it finds dubious for whatever reason. The Agency must
state its reasons for issuing the SEP if the SEP is Agency-
initiated.
9)
Suppliers shall take samples at the same sampling point
unless the Agency has granted a SEP allowing another
sampling point because conditions make another sampling
point more representative of the water from each source or
treatment plant.
BOARD NOTE: Subsection (b)(9) above corresponds with
duplicate segments of 40 CFR 141.40(n)(5) and (n)(6)
(19945), which correspond with subsections (b)(5) and (b)(6)
above. The Board has adopted no counterpart to 40 CFR
141.40(n)(9), an optional provision that pertains to
composite sampling. Otherwise, the structure of this
Section directly corresponds with 40 CFR 141.40(n) (19945).
10)
Instead of performing the monitoring required by this
subsection, a CWS and NTNCWS supplier serving fewer than 150
service connections may send a letter to the Agency stating
that the PWS is available for sampling. This letter must be
sent to the Agency by January 1, 1994. The supplier shall
not send such samples to the Agency, unless requested to do
so by the Agency.
11)
List of Phase V unregulated organic contaminants with
methods required for analysis (all methods are from U.S. EPA
Organic Methods unless otherwise noted; all are incorporated
by reference in Section 611.102):
Contaminant
U.S. EPA Organic Methods
63
Aldicarb
531.1, Standard Methods,
18th ed.: Method 6610
Aldicarb sulfone
531.1, Standard Methods,
18th ed.: Method 6610
Aldicarb sulfoxide
531.1, Standard Methods,
18th ed.: Method 6610
Aldrin
505, 508, 508.1, 525.2
Butachlor
507, 525.2
Carbaryl
531.1, Standard Methods,
18th ed.: Method 6610
Dicamba
515.1, 515.2, 555
Dieldrin
505, 508, 508.1, 525.2
3-Hydroxycarbofuran
531.1, Standard Methods,
18th ed.: Method 6610
Methomyl
531.1, Standard Methods,
18th ed.: Method 6610
Metolachlor
507, 508.1, 525.2
Metribuzin
507, 508.1, 525.2
Propachlor
508, 508.1, 525.2
12)
List of unregulated inorganic contaminants (all methods
indicated are incorporated by reference in Section 611.102):
Contaminant
Methods
Sulfate
U.S. EPA Environmental Inorganic
Methods: Methods 300.0, 375.2; ASTM
Method D 4327-91; Standard Methods,
18th ed.: Methods 4110, 4500-SO
4
2-
F, 4500-SO
4
2-
C & 4500-SO
4
2-
D
BOARD NOTE: Subsection (b) derived from 40 CFR
141.40(n) (19945), as amended at 59 Fed. Reg. 62471
(Dec. 5, 1994).
c)
Analyses performed pursuant to this Section must be conducted by a
laboratory certified pursuant to Section 611.646(q).
BOARD NOTE: Subsection (c) derived from 40 CFR 141.40 (h)
(19945).
d)
All CWS and NTNCWS suppliers shall repeat the monitoring required
by this Section no less frequently than every five years, starting
from the dates specified in subsections (a)(1) and (b)(2) above.
BOARD NOTE: Subsection (d) derived from 40 CFR 141.40 (l)
(19945).
(Source: Amended at 20 Ill. Reg. ________, effective ______________________)
64
SUBPART L: MICROBIOLOGICAL MONITORING
AND ANALYTICAL REQUIREMENTS
Section 611.526
Analytical Methodology
a)
The standard sample volume required for total coliform analysis,
regardless of analytical method used, is 100 mL.
b)
Suppliers need only determine the presence or absence of total
coliforms, a determination of total coliform density is not
required.
c)
Suppliers shall conduct total coliform analyses in accordance with
one of the following analytical methods, incorporated by reference
in Section 611.102 (the time from sample collection to initiation
of analysis may not exceed 30 hours, and the supplier is
encouraged but not required to hold samples below 10
°
C during
transit):
1)
Multiple-Tube Fermentation (MTF) Technique, as set forth in
Standard Methods, 18th ed.: Methods 9221 A and B:
A)
Lactose broth, as commercially available, may be used
in lieu of lauryl tryptose broth if the supplier
conducts at least 25 parallel tests between this
medium and lauryl tryptose broth using the water
normally tested and this comparison demonstrates that
the false-positive rate and false negative rate for
total coliforms, using lactose broth, is less than 10
percent;
B)
If inverted tubes are used to detect gas production,
the media should cover these tubes at least one-half
to two-thirds after the sample is added; and
C)
No requirement exists to run the completed phase on 10
percent of all total coliform-positive confirmed
tubes.
2)
Membrane Filter (MF) Technique, as set forth in Standard
Methods, 18th ed.: Methods 9222 A, B, and C.
3)
P-A Coliform Test, as set forth in: Standard Methods, 18th
ed.: Method 9221 D:
A)
No requirement exists to run the completed phase on 10
percent of all total coliform-positive confirmed
tubes; and
65
B)
Six-times formulation strength may be used if the
medium is filter-sterilized rather than autoclaved.
4)
ONPG-MUG test: Standard Methods, 18th ed.: Method 9223.
(The ONPG-MUG test is also known as the autoanalysis
colilert system.)
5)
Colisure Test from Millipore Corporation, incorporated by
reference in Section 611.102. (The Colisure Test must be
incubated for 28 hours before examining results. If an
examination of the results at 28 hours is not convenient,
then results may be examined at any time between 28 hours
and 48 hours.)
BOARD NOTE: U.S. EPA included the P-A Coliform and Colisure
Tests for testing finished water under the coliform rule,
but did not include them for the purposes of the surface
water treatment rule, under Section 611.531, for which
quantitation of total coliforms is necessary. For these
reasons, U.S. EPA included Standard Methods: Method 9221 C
for the surface water treatment rule, but did not include it
for the purposes of the total coliform rule, under this
Section.
d)
This subsection corresponds with 40 CFR 141.21(f)(4), which U.S.
EPA has marked "reserved". This statement maintains structural
consistency with the federal regulations.
e)
Suppliers shall conduct fecal coliform analysis in accordance with
the following procedure:
1)
When the MTF Technique or P-A Coliform Test is used to test
for total coliforms, shake the lactose-positive presumptive
tube or P-A vigorously and transfer the growth with a
sterile 3-mm loop or sterile applicator stick into brilliant
green lactose bile broth and EC medium, defined below, to
determine the presence of total and fecal coliforms,
respectively.
2)
For approved methods that use a membrane filter, transfer
the total coliform-positive culture by one of the following
methods: remove the membrane containing the total coliform
colonies from the substrate with a sterile forceps and
carefully curl and insert the membrane into a tube of EC
medium. (The laboratory may first remove a small portion of
selected colonies for verification); swab the entire
membrane filter surface with a sterile cotton swab and
transfer the inoculum to EC medium (do not leave the cotton
swab in the EC medium); or inoculate individual total
coliform-positive colonies into EC medium. Gently shake the
inoculated tubes of EC medium to insure adequate mixing and
66
incubate in a waterbath at 44.5±0.2
°
C for 24±2 hours. Gas
production of any amount in the inner fermentation tube of
the EC medium indicates a positive fecal coliform test.
3)
EC medium is described in Standard Methods, 18th ed.:
Method 9221 E.
4)
Suppliers need only determine the presence or absence of
fecal coliforms, a determination of fecal coliform density
is not required.
f)
Suppliers shall conduct analysis of E. coli in accordance with one
of the following analytical methods:
1)
EC medium supplemented with 50
μ
g/L of MUG (final
concentration). EC medium is as described in subsection
(e). MUG may be added to EC medium before autoclaving. EC
medium supplemented with 50
μ
g/L MUG is commercially
available. At least 10 mL of EC medium supplemented with
MUG must be used. The inner inverted fermentation tube may
be omitted. The procedure for transferring a total
coliform-positive culture to EC medium supplemented with MUG
is as in subsection (e) for transferring a total coliform-
positive culture to EC medium. Observe fluorescence with an
ultraviolet light (366 nm) in the dark after incubating tube
at 44.5±2
°
C for 24±2 hours; or
2)
Nutrient agar supplemented with 100
μ
g/L MUG (final
concentration). Nutrient Aagar is described in Standard
Methods, 18th ed.: Method 9221 B, at pages 9-47 to 9-48.
This test is used to determine if a total coliform-positive
sample, as determined by the MF technique or any other
method in which a membrane filter is used, contains E. coli.
Transfer the membrane filter containing a total coliform
colony or colonies to nutrient agar supplemented with 100
μ
g/L MUG (final concentration). After incubating the agar
plate at 35
°
Celsius for 4 hours, observe the colony or
colonies under ultraviolet light (366 nm) in the dark for
fluorescence. If fluorescence is visible, E. coli are
present.
3)
Minimal Medium ONPG-MUG (MMO-MUG) Test, as set forth in
Section 611.Appendix D. (The Autoanalysis Coliert System is
a MMO-MUG test.) If the MMO-MUG test is total coliform
positive after a 24-hour incubation, test the medium for
fluorescence with a 366-nm ultraviolet light (preferably
with a 6-watt lamp) in the dark. If fluorescence is
observed, the sample is E. coli-positive. If fluorescence
is questionable (cannot be definitively read) after 24 hours
incubation, incubate the culture for an additional four
hours (but not to exceed 28 hours total), and again test the
67
medium for fluorescence. The MMO-MUG test with hepes buffer
is the only approved formulation for the detection of E.
coli.
4)
The Colisure Test, from Millipore Corporation, incorporated
by reference in Section 611.102.
g)
As an option to the method set forth in subsection (f)(3), a
supplier with a total coliform-positive, MUG-negative, MMO-MUG
test may further analyze the culture for the presence of E. coli
by transferring a 0.1 mL, 28-hour MMO-MUG culture to EC medium +
MUG with a pipet. The formulation and incubation conditions of
the EC medium + MUG, and observation of the results are described
in subsection (f)(1).
h)
This subsection corresponds with 40 CFR 141.21(f)(8), a central
listing of all documents incorporated by reference into the
federal microbiological analytical methods. The corresponding
Illinois incorporatations by reference are located at Section
611.102. This statement maintains structural parity with U.S. EPA
regulations.
BOARD NOTE: Derived from 40 CFR 141.21(f) (19945), as amended at
59 Fed. Reg. 62466 (Dec. 5, 1994).
(Source: Amended at 20 Ill. Reg. ________, effective ______________________)
Section 611.531
Analytical Requirements
Only the analytical method(s) specified in this Section may be used to
demonstrate compliance with the requirements of Subpart B. Measurements for
pH, temperature, turbidity and RDCs must be conducted under the supervision of
a certified operator. Measurements for total coliforms, fecal coliforms and
HPC must be conducted by a laboratory certified by the Agency to do such
analysis. The following procedures must be performed by the following
methods, incorporated by reference in Section 611.102:
a)
A supplier shall:
1)
Conduct analysis of pH in accordance with one of the methods
listed at Section 611.611; and
2)
Conduct analyses toof total coliforms, fecal coliforms,
heterotrophic bacteria, and turbidity, and temperature in
accordance with one of the following methods, and by using
analytical test procedures contained in U.S. EPA Technical
Notes, incorporated by reference in Section 611.102:
A)
Total Coliforms:
68
BOARD NOTE: The time from sample collection to
initiation of analysis must not exceed 8 hours. The
supplier is encouraged but not required to hold
samples below 10
°
C during transit.
i)
Total coliform fermentation technique: Standard
Methods, 18th ed.: Method 9221 A, B, and C.
BOARD NOTE: Lactose broth, as commercially
available, may be used in lieu of lauryl
tryptose broth if the supplier conducts at least
25 parallel tests between this medium and lauryl
tryptose broth using the water normally tested
and this comparison demonstrates that the false-
positive rate and false-negative rate for total
coliforms, using lactose broth, is less than 10
percent. If inverted tubes are used to detect
gas production, the media should cover these
tubes at least one-half to two-thirds after the
sample is added. No requirement exists to run
the completed phase on 10 percent of all total
coliform-positive confirmed tubes.
ii)
Total coliform membrane filter technique:
Standard Methods, 18th ed.: Method 9222 A, B,
and C.
iii)
ONPG-MUG test (also known as the autoanalysis
colilert system): Standard Methods, 18th ed.:
Method 9223.
BOARD NOTE: U.S. EPA included the P-A Coliform
and Colisure Tests for testing finished water
under the coliform rule, under Section 611.526,
but did not include them for the purposes of the
surface water treatment rule, under this
Section, for which quantitation of total
coliforms is necessary. For these reasons, U.S.
EPA included Standard Methods: Method 9221 C
for the surface water treatment rule, but did
not include it for the purposes of the total
coliform rule, under Section 611.526.
B)
Fecal Coliforms:
BOARD NOTE: The time from sample collection to
initiation of analysis must not exceed 8 hours. The
supplier is encouraged but not required to hold
samples below 10
°
C during transit.
69
i)
Fecal coliform MPN procedure: Standard Methods,
18th ed.: Method 9221 E.
BOARD NOTE: A-1 broth may be held up to three
months in a tightly closed screwcap tube at 4
°
C
(39
°
F).
ii)
Fecal Coliforms Membrane Filter Procedure:
Standard Methods, 18th ed.: Method 9222 D.
C)
Heterotrophic bacteria: Pour plate method: Standard
Methods, 18th ed.: Method 9215 B.
BOARD NOTE: The time from sample collection to
initiation of analysis must not exceed 8 hours. The
supplier is encouraged but not required to hold
samples below 10
°
C during transit.
D)
Turbidity:
i)
Nephelometric method: Standard Methods, 18th
ed.: Method 2130 B.
ii)
Nephelometric method: U.S. EPA Environmental
Inorganic Methods: Method 180.1
ii)
GLI Method 2.
E)
Temperature: Standard Methods, 18th ed.: Method
2550.
b)
A supplier shall measure residual disinfectant concentrations with
one of the following analytical methods from Standard Methods,
18th ed., and by using analytical test procedures contained in
U.S. EPA Technical Notes, incorporated by reference in Section
611.102:
1)
Free chlorine:
A)
Amperometric Titration: Method 4500-Cl D.
B)
DPD Ferrous Titrimetric: Method 4500-Cl F.
C)
DPD Colimetric: Method 4500-Cl G.
D)
Syringaldazine (FACTS): Method 4500-Cl H.
2)
Total chlorine:
A)
Amperometric Titration: Method 4500-Cl D.
70
B)
Amperometric Titration (low level measurement):
Method 4500-Cl E.
C)
DPD Ferrous Titrimetric: Method 4500-Cl F.
D)
DPD Colimetric: Method 4500-Cl G.
E)
Iodometric Electrode: Method 4500-Cl I.
3)
Chlorine dioxide:
A)
Amperometric Titration: Method 4500-ClO
2
C or E.
B)
DPD Method: Method 4500-ClO
2
D.
4)
Ozone: Indigo Method: Method 4500-O
3
B.
5)
Alternative test methods: The Agency may grant a SEP
pursuant to Section 611.110 that allows a supplier to use
alternative chlorine test methods as follows:
A)
DPD colorimetric test kits: Residual disinfectant
concentrations for free chlorine and combined chlorine
may also be measured by using DPD colorimetric test
kits.
B)
Continuous monitoring for free and total chlorine:
Free and total chlorine residuals may be measured
continuously by adapting a specified chlorine residual
method for use with a continuous monitoring
instrument, provided the chemistry, accuracy, and
precision remain the same. Instruments used for
continuous monitoring must be calibrated with a grab
sample measurement at least every five days or as
otherwise provided by the Agency.
BOARD NOTE: Suppliers may use a five-tube test or a
ten-tube test.
BOARD NOTE: Derived from 40 CFR 141.74(a) (19945), as amended at
59 Fed. Reg. 62470 (Dec. 5, 1994).
(Source: Amended at 20 Ill. Reg. ________, effective ______________________)
SUBPART N: INORGANIC MONITORING AND ANALYTICAL REQUIREMENTS
Section 611.591
Violation of State MCL
This Section applies to old MCLs that are marked as "additional State
requirements" at Section 611.300, and for which no specific monitoring,
71
reporting or public notice requirements are specified below. If the results
of analysis pursuant to this Part indicates that the level of any contaminant
exceeds the old MCL, the CWS supplier shall:
a)
Report to the Agency within seven days, and initiate three
additional analyses at the same sampling point within one month;
b)
Notify the Agency and give public notice as specified in Subpart
T, when the average of four analyses, rounded to the same number
of significant figures as the old MCL for the contaminant in
question, exceeds the old MCL; and,
c)
Monitor, after public notification, at a frequency designated by
the Agency, and continue monitoring until the old MCL has not been
exceeded in two consecutive samples, or until a monitoring
schedule as a condition of a variance or enforcement action
becomes effective.
BOARD NOTE: This is an additional State requirement.
(Source: Amended at 20 Ill. Reg. ________, effective ______________________)
Section 611.600
Applicability
The following types of suppliers shall conduct monitoring to determine
compliance with the old MCLs in Section 611.300 and the revised MCLs in
611.301, as appropriate, in accordance with this Subpart:
a)
CWS suppliers.
b)
NTNCWS suppliers.
c)
Transient non-CWS suppliers to determine compliance with the
nitrate and nitrite MCLs.
BOARD NOTE: Derived from 40 CFR 141.23 (preamble) (19945).
d)
Detection limits. The following are detection limits for purposes
of this Subpart (MCLs from Section 611.301 are set forth for
information purposes only):
Contaminant
MCL (mg/L,
except as-
bestos)
Method
Detec-
tion
Limit
(mg/L)
Antimony
0.006
Atomic absorption-furnace
technique
0.003
Atomic absorption-furnace
technique (stabilized
0.0008
72
temperature)
Inductively-coupled plasma-
mass spectrometry
0.0004
Atomic absorption-gaseous
hydride technique
0.001
Asbestos
7 MFL
Transmission electron
microscopy
0.01 MFL
Barium
2
Atomic absorption- furnace
technique
0.002
Atomic absorption- direct
aspiration technique
0.1
Inductively-coupled plasma
arc furnace
0.002
Inductively-coupled plasma
0.001
Beryllium
0.004
Atomic absorption-furnace
technique
0.0002
Atomic absorption-furnace
technique (stabilized
temperature)
0.00002
Inductively-coupled plasma
(using a 2x preconcen-
tration step; a lower MDL
is possible using 4x
preconcentration)
0.0003
Inductively-coupled plasma-
mass spectrometry
0.0003
Cadmium
0.005
Atomic absorption- furnace
technique
0.0001
Inductively-coupled plasma
0.001
Chromium
0.1
Atomic absorption- furnace
technique
0.001
Inductively-coupled plasma
0.007
Inductively-coupled plasma
0.001
Cyanide
0.2
Distillation,
0.02
73
spectrophotometric
(screening method for total
cyanides)
Automated distillation,
spectrophotometric
(screening method for total
cyanides)
0.005
Distillation, selective
electrode (screening method
for total cyanides)
0.05
Distillation, amenable,
spectrophotometric (for
free cyanides)
0.02
Mercury
0.002
Manual cold vapor technique
0.0002
Automated cold vapor
technique
0.0002
Nickel
0.1No MCL
Atomic absorption-furnace
technique
0.001
Atomic absorption-furnace
technique (stabilized
temperature)
0.0006
Inductively-coupled plasma
(using a 2x preconcen-
tration step; a lower MDL
is possible using 4x
preconcentration)
0.005
Inductively-coupled plasma-
mass spectrometry
0.0005
Nitrate (as N)
10
Manual cadmium reduction
0.01
Automated hydrazine
reduction
0.01
Automated cadmium reduction
0.05
Ion-selective electrode
1
Ion chromatography
0.01
Nitrite (as N)
1
Spectrophotometric
0.01
74
Automated cadmium reduction
0.05
Manual cadmium reduction
0.01
Ion chromatography
0.004
Selenium
0.05
Atomic absorption- furnace
technique
0.002
Atomic absorption- gaseous
hydride technique
0.002
Thallium
0.002
Atomic absorption-furnace
technique
0.001
Atomic absorption-furnace
technique (stabilized
temperature)
0.0007
Inductively-coupled plasma-
mass spectrometry
0.0003
BOARD NOTE: Derived from 40 CFR 141.23 preamble and paragraph
(a)(4)(i) (19945). See the Board Note at Section 611.301(b)
relating to the MCL for nickel.
(Source: Amended at 20 Ill. Reg. ________, effective ______________________)
Section 611.601
Monitoring Frequency
Monitoring shall be conducted as follows:
a)
Required sampling.
1)
Each supplier shall take a minimum of one sample at each
sampling point at the times required by Section 611.610
beginning in the initial compliance period.
2)
Each sampling point must produce samples that are
representative of the water from each source after treatment
or from each treatment plant, as required by subsection (b)
below. The total number of sampling points must be
representative of the water delivered to users throughout
the PWS.
3)
The supplier shall take each sample at the same sampling
point unless conditions make another sampling point more
representative of each source or treatment plant and the
Agency has granted a SEP pursuant to subsection (b)(5)
below.
75
b)
Sampling points.
1)
Sampling points for GWSs. Unless otherwise provided by SEP,
a GWS supplier shall take at least one sample from each of
the following points: each entry point that is
representative of each well after treatment.
2)
Sampling points for SWSs and mixed systems. Unless
otherwise provided by SEP, a SWS or mixed system supplier
shall take at least one sample from each of the following
points:
A)
Each entry point after the application of treatment;
or
B)
A point in the distribution system that is
representative of each source after treatment.
3)
If a system draws water from more than one source, and the
sources are combined before distribution, the supplier shall
sample at an entry point during periods of normal operating
conditions when water is representative of all sources being
used.
4)
Additional sampling points. The Agency shall, by SEP,
designate additional sampling points in the distribution
system or at the consumer's tap if it determines that such
samples are necessary to more accurately determine consumer
exposure.
5)
Alternative sampling points. The Agency shall, by SEP,
approve alternate sampling points if the supplier
demonstrates that the points are more representative than
the generally required point.
c)
This subsection corresponds with 40 CFR 141.23(a)(4), an optional
U.S. EPA provision relating to compositing of samples that U.S.
EPA does not require for state programs. This statement maintains
structural consistency with U.S. EPA rules.
d)
The frequency of monitoring for the following contaminants must be
in accordance with the following Sections:
1)
Asbestos: Section 611.602;
2)
Antimony, barium, beryllium, cadmium, chromium, cyanide,
fluoride, mercury, nickel, selenium, and thallium: Section
611.603;
3)
Nitrate: Section 611.604; and
76
4)
Nitrite: Section 611.605.
BOARD NOTE: Derived from 40 CFR 141.23(a) and (c) (19945).
(Source: Amended at 20 Ill. Reg. ________, effective ______________________)
Section 611.606
Confirmation Samples
a)
Where the results of sampling for antimony, asbestos, barium,
beryllium, cadmium, chromium, cyanide, fluoride, mercury, nickel,
selenium, or thallium indicate a level in excess of the MCL, the
supplier shall collect one additional sample as soon as possible
after the supplier receives notification of the analytical result
(but no later than two weeks after the initial sample was taken)
at the same sampling point.
b)
Where nitrate or nitrite sampling results indicate a level in
excess of the MCL, the supplier shall take a confirmation sample
within 24 hours after the supplier's receipt of notification of
the analytical results of the first sample.
1)
Suppliers unable to comply with the 24-hour sampling
requirement must, based on the initial sample, notify the
persons served in accordance with Section 611.851.
2)
Suppliers exercising this option must take and analyze a
confirmation sample within two weeks of notification of the
analytical results of the first sample.
c)
Averaging rules are specified in Section 611.609. The Agency
shall delete the original or confirmation sample if it determines
that a sampling error occurred, in which case the confirmation
sample will replace the original sample.
BOARD NOTE: Derived from 40 CFR 141.23(f) (19945).
(Source: Amended at 20 Ill. Reg. ________, effective ______________________)
Section 611.611
Inorganic Analysis
Analytical methods are from documents incorporated by reference in Section
611.102. These are mostly referenced by a short name defined by Section
611.102(a). Other abbreviations are defined in Section 611.101.
a)
Analysis for the following contaminants must be conducted using
the following methods or an alternative approved pursuant to
Section 611.480. Criteria for analyzing arsenic, chromium,
copper, lead, nickel, selenium, sodium, and thallium with
digestion or directly without digestion, and other analytical
procedures, are contained in U.S. EPA Technical Notes,
incorporated by reference in Section 611.102. (This document also
77
contains approved analytical test methods that remain available
for compliance monitoring until July 1, 1996. These methods will
not be available for use after July 1, 1996.)
1)
Antimony:
A)
Inductively-coupled plasma-mass spectrometry: U.S.
EPA Environmental Metals Methods: Method 200.8.
B)
Atomic absorption, hydride technique: ASTM Method
D3697-92.
C)
Atomic absorption, platform furnace technique: U.S.
EPA Environmental Metals Methods: Method 200.9.
D)
Atomic absorption, furnace technique: Standard
Methods, 18th ed.: Method 3113 B.
2)
Arsenic:
A)
Inductively-coupled Plasma:
i)
U.S. EPA Environmental Metals Methods: Method
200.7, or
ii)
Standard Methods, 18th ed.: Method 3120 B.
B)
Inductively-coupled plasma-mass spectrometry: U.S.
EPA Environmental Metals Methods: Method 200.8.
C)
Atomic absorption, platform furnace technique: U.S.
EPA Environmental Metals Methods: Method 200.9.
D)
Atomic Absorption, furnace technique:
i)
ASTM Method D2972-93 C, or
ii)
Standard Methods, 18th ed.: Method 3113 B.
E)
Atomic absorption, hydride technique:
i)
ASTM Method D2972-93 B, or
ii)
Standard Methods, 18th ed.: Method 3114 B.
3)
Asbestos: Transmission electron microscopy: U.S. EPA
Asbestos Methods-100.1 and U.S. EPA Asbestos Methods-100.2.
4)
Barium:
A)
Inductively-coupled plasma:
78
i)
U.S. EPA Environmental Metals Methods: Method
200.7, or
ii)
Standard Methods, 18th ed.: Method 3120 B.
B)
Inductively-coupled plasma-mass spectrometry: U.S.
EPA Environmental Metals Methods: Method 200.8.
C)
Atomic absorption, direct aspiration technique:
Standard Methods, 18th ed.: Method 3111 D.
D)
Atomic absorption, furnace technique: Standard
Methods, 18th ed.: Method 3113 B.
5)
Beryllium:
A)
Inductively-coupled plasma:
i)
U.S. EPA Environmental Metals Methods: Method
200.7, or
ii)
Standard Methods, 18th ed.: Method 3120 B.
B)
Inductively-coupled plasma-mass spectrometry: U.S.
EPA Environmental Metals Methods: Method 200.8.
C)
Atomic absorption, platform furnace technique: U.S.
EPA Environmental Metals Methods: Method 200.9.
D)
Atomic absorption, furnace technique:
i)
ASTM Method D3645-93 B, or
ii)
Standard Methods, 18th ed.: Method 3113 B.
6)
Cadmium:
A)
Inductively-coupled plasma arc furnace: U.S. EPA
Environmental Metals Methods: Method 200.7.
B)
Inductively-coupled plasma-mass spectrometry: U.S.
EPA Environmental Metals Methods: Method 200.8.
C)
Atomic absorption, platform furnace technique: U.S.
EPA Environmental Metals Methods: Method 200.9.
D)
Atomic absorption, furnace technique: Standard
Methods, 18th ed.: Method 3113 B.
7)
Chromium:
79
A)
Inductively-coupled plasma arc furnace:
i)
U.S. EPA Environmental Metals Methods: Method
200.7, or
ii)
Standard Methods, 18th ed.: Method 3120 B.
B)
Inductively-coupled plasma-mass spectrometry: U.S.
EPA Environmental Metals Methods: Method 200.8.
C)
Atomic absorption, platform furnace technique: U.S.
EPA Environmental Metals Methods: Method 200.9.
D)
Atomic absorption, furnace technique: Standard
Methods, 18th ed.: Method 3113 B.
8)
Cyanide:
A)
Manual distillation (Standard Methods, 18th ed.:
Method 4500-CN
-
C), followed by spectrophotometric,
amenable:
i)
ASTM Method D2036-91 B,
ii)
Standard Methods, 18th ed.: Method 4500-CN
-
G.
B)
Manual distillation (Standard Methods, 18th ed.:
Method 4500-CN
-
C), followed by spectrophotometric,
manual:
i)
ASTM Method D2036-91 A,
ii)
Standard Methods, 18th ed.: Method 4500-CN
-
E,
or
iii)
USGS Methods: Method I-3300-85.
C)
Manual distillation (Standard Methods, 18th ed.:
Method 4500-CN
-
C), followed by semiautomated
spectrophotometric: U.S. EPA Environmental Inorganic
Methods: Method 335.4.
D)
Selective electrode: Standard Methods, 18th ed.:
Method 4500-CN
-
F.
9)
Fluoride:
A)
Ion Chromatography:
80
i)
U.S. EPA Environmental Inorganic Methods:
Method 300.0,
ii)
ASTM Method D4327-91, or
iii)
Standard Methods, 18th ed.: Method 4110 B.
B)
Manual distillation, colorimetric SPADNS: Standard
Methods, 18th ed.: Method 4500-F
-
B and D.
C)
Manual electrode:
i)
ASTM Method D1179-93B, or
ii)
Standard Methods, 18th ed.: Method 4500-F
-
C.
D)
Automated electrode: Technicon Methods: Method 380-
75WE.
E)
Automated alizarin:
i)
Standard Methods, 18th ed.: Method 4500-F
-
E,
or
ii)
Technicon Methods: Method 129-71W.
10)
Mercury:
A)
Manual cold vapor technique:
i)
U.S. EPA Environmental Metals Methods: Method
245.1,
ii)
ASTM Method D3223-91, or
iii)
Standard Methods, 18th ed.: Method 3112 B.
B)
Automated cold vapor technique: U.S. EPA Inorganic
Methods: Method 245.2.
C)
Inductively-coupled plasma-mass spectrometry: U.S.
EPA Environmental Metals Methods: Method 200.8.
11)
Nickel:
A)
Inductively-coupled plasma:
i)
U.S. EPA Environmental Metals Methods: Method
200.7, or
ii)
Standard Methods, 18th ed.: Method 3120 B.
81
B)
Inductively-coupled plasma-mass spectrometry: U.S.
EPA Environmental Metals Methods: Method 200.8.
C)
Atomic absorption, platform furnace technique: U.S.
EPA Environmental Metals Methods: Method 200.9;
D)
Atomic absorption, direct aspiration technique:
Standard Methods, 18th ed.: Method 3111 B;
E)
Atomic absorption, furnace technique: Standard
Methods, 18th ed.: Method 3113 B;
12)
Nitrate:
A)
Ion chromatography:
i)
U.S. EPA Environmental Inorganic Methods:
Method 300.0,
ii)
ASTM Method D4327-91,
iii)
Standard Methods, 18th ed.: Method 4110 B, or
iv)
Waters Test Method B-1011, available from
Millipore Corporation.
B)
Automated cadmium reduction:
i)
U.S. EPA Environmental Inorganic Methods:
Method 353.2,
ii)
ASTM Method D3867-90 A, or
iii)
Standard Methods, 18th ed.: Method 4500-NO
3
-
F.
C)
Ion selective electrode:
i)
Standard Methods, 18th ed.: Method 4500-NO
3
-
D,
or
ii)
Technical Bulletin 601.
D)
Manual cadmium reduction:
i)
ASTM Method D3867-90 B, or
ii)
Standard Methods, 18th ed.: Method 4500-NO
3
-
E.
13)
Nitrite:
82
A)
Ion chromatography:
i)
U.S. EPA Environmental Inorganic Methods:
Method 300.0,
ii)
ASTM Method D4327-91,
iii)
Standard Methods, 18th ed.: Method 4110 B, or
iv)
Waters Test Method Method B-1011, available from
Millipore Corporation.
B)
Automated cadmium reduction:
i)
U.S. EPA Environmental Inorganic Methods:
Method 353.2,
ii)
ASTM Method D3867-90 A, or
iii)
Standard Methods, 18th ed.: Method 4500-NO
3
-
F.
C)
Manual cadmium reduction:
i)
ASTM Method D3867-90 B, or
ii)
Standard Methods, 18th ed.: Method 4500-NO
3
-
E.
D)
Spectrophotometric: Standard Methods, 18th ed.:
Method 4500-NO
2
-
B.
14)
Selenium:
A)
Atomic absorption, hydride:
i)
ASTM Method D3859-93 A, or
ii)
Standard Methods, 18th ed.: Method 3114 B.
B)
Inductively-coupled plasma-mass spectrometry: U.S.
EPA Environmental Metals Methods: Method 200.8.
C)
Atomic absorption, platform furnace technique: U.S.
EPA Environmental Metals Methods: Method 200.9.
D)
Atomic absorption, furnace technique:
i)
ASTM Method D3859-93 B, or
ii)
Standard Methods, 18th ed.: Method 3113 B.
15)
Thallium:
83
A)
Inductively-coupled plasma-mass spectrometry: U.S.
EPA Environmental Metals Methods: Method 200.8.
B)
Atomic absorption, platform furnace technique: U.S.
EPA Environmental Metals Methods: Method 200.9.
16)
Lead:
A)
Atomic absorption, furnace technique:
i)
ASTM Method D3559-90 D, or
ii)
Standard Methods, 18th ed.: Method 3113 B.
B)
Inductively-coupled plasma-mass spectrometry: U.S.
EPA Environmental Metals Methods: Method 200.8.
C)
Atomic absorption, platform furnace technique: U.S.
EPA Environmental Metals Methods: Method 200.9.
17)
Copper:
A)
Atomic absorption, furnace technique:
i)
ASTM Method D1688-90 C, or
ii)
Standard Methods, 18th ed.: Method 3113 B.
B)
Atomic absorption, direct aspiration:
i)
ASTM Method D1688-90 A, or
ii)
Standard Methods, 18th ed.: Method 3111 B.
C)
Inductively-coupled plasma:
i)
U.S. EPA Environmental Metals Methods: Method
200.7, or
ii)
Standard Methods, 18th ed.: Method 3120 B.
D)
Inductively-coupled plasma-mass spectrometry: U.S.
EPA Environmental Metals Methods: Method 200.8.
E)
Atomic absorption, platform furnace technique: U.S.
EPA Environmental Metals Methods: Method 200.9.
18)
pH:
A)
Electrometric:
84
i)
U.S. EPA Inorganic Methods: Method 150.1,
ii)
ASTM Method D1293-84, or
iii)
Standard Methods, 18th ed.: Method 4500-H
+
B.
B)
U.S. EPA Inorganic Methods: Method 150.2.
19)
Conductivity: Conductance:
A)
ASTM Method D1125-91 A, or
B)
Standard Methods, 18th ed.: Method 2510 B.
20)
Calcium:
A)
EDTA titrimetric:
i)
ASTM Method D511-93 A, or
ii)
Standard Methods, 18th ed.: Method 3500-Ca D.
B)
Atomic absorption, direct aspiration:
i)
ASTM Method D511-93 B, or
ii)
Standard Methods, 18th ed.: Method 3111 B.
C)
Inductively-coupled plasma:
i)
U.S. EPA Environmental Metals Methods: Method
200.7, or
ii)
Standard Methods, 18th ed.: Method 3120 B.
21)
Alkalinity:
A)
Titrimetric:
i)
ASTM Method D1067-92 B, or
ii)
Standard Methods, 18th ed.: Method 2320 B.
B)
Electrometric titration: USGS Methods: Method I-
1030-85.
22)
Orthophosphate (unfiltered, without digestion or
hydrolysis):
A)
Automated colorimetric, ascorbic acid:
85
i)
U.S. EPA Environmental Inorganic Methods:
Method 365.1, or
ii)
Standard Methods, 18th ed.: Method 4500-P F.
B)
Single reagent colorimetric, ascorbic acid:
i)
ASTM Method D515-88 A, or
ii)
Standard Methods, 18th ed.: Method 4500-P E.
C)
Colorimetric, phosphomolybdate: USGS Methods: Method
I-1601-85.
D)
Colorimetric, phosphomolybdate, automated-segmented
flow: USGS Methods: Method I-2601-90.
E)
Colorimetric, phosphomolybdate, automated discrete:
USGS Methods: Method I-2598-85.
F)
Ion Chromatography:
i)
U.S. EPA Environmental Inorganic Methods:
Method 300.0,
ii)
ASTM Method D4327-91, or
iii)
Standard Methods, 18th ed.: Method 4110.
23)
Silica:
A)
Colorimetric, molybdate blue: USGS Methods: Method
I-1700-85.
B)
Colorimetric, molybdate blue, automated-segmented
flow: USGS Methods: Method I-2700-85.
C)
Colorimetric: ASTM Method D859-88.
D)
Molybdosilicate: Standard Methods, 18th ed.: Method
4500-Si D.
E)
Heteropoly blue: Standard Methods, 18th ed.: Method
4500-Si E.
F)
Automated method for molybdate-reactive silica:
Standard Methods, 18th ed.: Method 4500-Si F.
G)
Inductively-coupled plasma:
86
i)
U.S. EPA Environmental Metals Methods: Method
200.7, or
ii)
Standard Methods, 18th ed.: Method 3120 B.
24)
Temperature: thermometric: Standard Methods, 18th ed.:
Method 2550 B.
25)
Sodium:
A)
Inductively-coupled plasma: U.S. EPA Environmental
Metals Methods: Method 200.7.
B)
Atomic absorption, direct aspiration: Standard
Methods, 18th ed.: Method 3111 B.
b)
Sample collection for antimony, asbestos, barium, beryllium,
cadmium, chromium, cyanide, fluoride, mercury, nickel, nitrate,
nitrite, selenium, and thallium pursuant to Sections 611.600
through 611.604 must be conducted using the following sample
preservation, container and maximum holding time procedures:
1)
Antimony:
A)
Preservative: Concentrated nitric acid to pH less
than 2. If nitric acid cannot be used because of
shipping restrictions, the sample may initially be
preserved by icing and immediately shipping it to the
laboratory. Upon receipt in the laboratory, the
sample must be acidified with concentrated nitric acid
to pH less than 2. At the time of sample analysis,
the sample container must be thoroughly rinsed with
1:1 nitric acid; washings must be added to the sample.
B)
Plastic or glass (hard or soft).
C)
Holding time: Samples must be analyzed as soon after
collection as possible, but in any event within 6
months.
2)
Asbestos:
A)
Preservative: Cool to 4
°
C.
B)
Plastic or glass (hard or soft).
3)
Barium:
A)
Preservative: Concentrated nitric acid to pH less
than 2. If nitric acid cannot be used because of
shipping restrictions, the sample may initially be
87
preserved by icing and immediately shipping it to the
laboratory. Upon receipt in the laboratory, the
sample must be acidified with concentrated nitric acid
to pH less than 2. At the time of sample analysis,
the sample container must be thoroughly rinsed with
1:1 nitric acid; washings must be added to the sample.
B)
Plastic or glass (hard or soft).
C)
Holding time: Samples must be analyzed as soon after
collection as possible, but in any event within 6
months.
4)
Beryllium:
A)
Preservative: Concentrated nitric acid to pH less
than 2. If nitric acid cannot be used because of
shipping restrictions, the sample may initially be
preserved by icing and immediately shipping it to the
laboratory. Upon receipt in the laboratory, the
sample must be acidified with concentrated nitric acid
to pH less than 2. At the time of sample analysis,
the sample container must be thoroughly rinsed with
1:1 nitric acid; washings must be added to the sample.
B)
Plastic or glass (hard or soft).
C)
Holding time: Samples must be analyzed as soon after
collection as possible, but in any event within 6
months.
5)
Cadmium:
A)
Preservative: Concentrated nitric acid to pH less
than 2. If nitric acid cannot be used because of
shipping restrictions, the sample may initially be
preserved by icing and immediately shipping it to the
laboratory. Upon receipt in the laboratory, the
sample must be acidified with concentrated nitric acid
to pH less than 2. At the time of sample analysis,
the sample container must be thoroughly rinsed with
1:1 nitric acid; washings must be added to the sample.
B)
Plastic or glass (hard or soft).
C)
Holding time: Samples must be analyzed as soon after
collection as possible, but in any event within 6
months.
6)
Chromium:
88
A)
Preservative: Concentrated nitric acid to pH less
than 2. If nitric acid cannot be used because of
shipping restrictions, the sample may initially be
preserved by icing and immediately shipping it to the
laboratory. Upon receipt in the laboratory, the
sample must be acidified with concentrated nitric acid
to pH less than 2. At the time of sample analysis,
the sample container must be thoroughly rinsed with
1:1 nitric acid; washings must be added to the sample.
B)
Plastic or glass (hard or soft).
C)
Holding time: Samples must be analyzed as soon after
collection as possible, but in any event within 6
months.
7)
Cyanide:
A)
Preservative: Cool to 4
°
C. Add sodium hydroxide to
pH > 12. See the analytical methods for information
on sample preservation.
B)
Plastic or glass (hard or soft).
C)
Holding time: Samples must be analyzed as soon after
collection as possible, but in any event within 14
days.
8)
Fluoride:
A)
Preservative: None.
B)
Plastic or glass (hard or soft).
C)
Holding time: Samples must be analyzed as soon after
collection as possible, but in any event within 1
month.
9)
Mercury:
A)
Preservative: Concentrated nitric acid to pH less
than 2. If nitric acid cannot be used because of
shipping restrictions, the sample may initially be
preserved by icing and immediately shipping it to the
laboratory. Upon receipt in the laboratory, the
sample must be acidified with concentrated nitric acid
to pH less than 2. At the time of sample analysis,
the sample container must be thoroughly rinsed with
1:1 nitric acid; washings must be added to the sample.
B)
Plastic or glass (hard or soft).
89
C)
Holding time: Samples must be analyzed as soon after
collection as possible, but in any event within 28
days.
10)
Nickel:
A)
Preservative: Concentrated nitric acid to pH less
than 2. If nitric acid cannot be used because of
shipping restrictions, the sample may initially be
preserved by icing and immediately shipping it to the
laboratory. Upon receipt in the laboratory, the
sample must be acidified with concentrated nitric acid
to pH less than 2. At the time of sample analysis,
the sample container must be thoroughly rinsed with
1:1 nitric acid; washings must be added to the sample.
B)
Plastic or glass (hard or soft).
C)
Holding time: Samples must be analyzed as soon after
collection as possible, but in any event within 6
months.
11)
Nitrate, chlorinated:
A)
Preservative: Cool to 4
°
C.
B)
Plastic or glass (hard or soft).
C)
Holding time: Samples must be analyzed as soon after
collection as possible, but in any event within 28
days.
12)
Nitrate, non-chlorinated:
A)
Preservative: Concentrated sulfuric acid to pH less
than 2.
B)
Plastic or glass (hard or soft).
C)
Holding time: Samples must be analyzed as soon after
collection as possible, but in any event within 14
days.
13)
Nitrite:
A)
Preservative: Cool to 4
°
C.
B)
Plastic or glass (hard or soft).
90
C)
Holding time: Samples must be analyzed as soon after
collection as possible, but in any event within 48
hours.
14)
Selenium:
A)
Preservative: Concentrated nitric acid to pH less
than 2. If nitric acid cannot be used because of
shipping restrictions, the sample may initially be
preserved by icing and immediately shipping it to the
laboratory. Upon receipt in the laboratory, the
sample must be acidified with concentrated nitric acid
to pH less than 2. At the time of sample analysis,
the sample container must be thoroughly rinsed with
1:1 nitric acid; washings must be added to the sample.
B)
Plastic or glass (hard or soft).
C)
Holding time: Samples must be analyzed as soon after
collection as possible, but in any event within 6
months.
15)
Thallium:
A)
Preservative: Concentrated nitric acid to pH less
than 2. If nitric acid cannot be used because of
shipping restrictions, the sample may initially be
preserved by icing and immediately shipping it to the
laboratory. Upon receipt in the laboratory, the
sample must be acidified with concentrated nitric acid
to pH less than 2. At the time of sample analysis,
the sample container must be thoroughly rinsed with
1:1 nitric acid; washings must be added to the sample.
B)
Plastic or glass (hard or soft).
C)
Holding time: Samples must be analyzed as soon after
collection as possible, but in any event within 6
months.
c)
Analyses under this Subpart must be conducted by laboratories that
received approval from U.S. EPA or the Agency. Laboratories may
conduct sample analyses for antimony, beryllium, cyanide, nickel,
and thallium under provisional certification granted by the Agency
until January 1, 1996. The Agency shall certify laboratories to
conduct analyses for antimony, asbestos, barium, beryllium,
cadmium, chromium, cyanide, fluoride, mercury, nickel, nitrate,
nitrite, selenium, and thallium if the laboratory:
1)
Analyzes performance evaluation samples, provided by the
Agency pursuant to 35 Ill. Adm. Code 183.125(c), that
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include those substances at levels not in excess of levels
expected in drinking water; and
2)
Achieves quantitative results on the analyses within the
following acceptance limits:
A)
Antimony: ± 30% at greater than or equal to 0.006
mg/L.
BOARD NOTE: 40 CFR 141.23(k)(3) (1994), as renumbered
, actually lists "6#30" as the acceptance limit for
antimony. The Board corrected this to "± 30%" based
on the discussion at 57 Fed. Reg. 31801 (July 17,
1992).
B)
Asbestos: 2 standard deviations based on study
statistics.
C)
Barium: ± 15% at greater than or equal to 0.15 mg/L.
D)
Beryllium: ± 15% at greater than or equal to 0.001
mg/L.
E)
Cadmium: ± 20% at greater than or equal to 0.002
mg/L.
F)
Chromium: ± 15% at greater than or equal to 0.01
mg/L.
G)
Cyanide: ± 25% at greater than or equal to 0.1 mg/lL.
H)
Fluoride: ± 10% at 1 to 10 mg/L.
I)
Mercury: ± 30% at greater than or equal to 0.0005
mg/L.
J)
Nickel: ± 15 % at greater than or equal to 0.01 mg/L.
K)
Nitrate: ± 10% at greater than or equal to 0.4 mg/L.
L)
Nitrite: ± 15% at greater than or equal to 0.4 mg/L.
M)
Selenium: ± 20% at greater than or equal to 0.01
mg/L.
N)
Thallium: ± 30% at greater than or equal to 0.002
mg/L.
BOARD NOTE: Subsection (e) is derived from the table
to 40 CFR 141.23(k)(2) (19945), as renumbered at 59
Fed. Reg. 62466 (Dec. 5, 1994), and the discussion at
92
57 Fed. Reg. 31809 (July 17, 1992). Section 611.609
is derived from 40 CFR 141.23(k) (19945), as amended
at 59 Fed. Reg. 62466 (Dec. 5, 1994).
(Source: Amended at 20 Ill. Reg. ________, effective ______________________)
Section 611.630
Special Monitoring for Sodium
a)
CWS suppliers shall collect and analyze one sample per plant at
the entry point of the distribution system for the determination
of sodium concentration levels; samples must be collected and
analyzed annually for CWSs utilizing surface water sources in
whole or in part, and at least every three years for CWSs
utilizing solely groundwater sources. The minimum number of
samples required to be taken by the supplier is based on the
number of treatment plants used by the supplier, except that
multiple wells drawing raw water from a single aquifer may, with
the Agency approval, be considered one treatment plant for
determining the minimum number of samples. The Agency shall
require the supplier to collect and analyze water samples for
sodium more frequently in locations where the sodium content is
variable.
b)
The CWS supplier shall report to the Agency the results of the
analyses for sodium within the first 10 days of the month
following the month in which the sample results were received or
within the first 10 days following the end of the required
monitoring period as specified by SEP, whichever of these is
first. If more than annual sampling is required, the supplier
shall report the average sodium concentration within 10 days of
the month following the month in which the analytical results of
the last sample used for the annual average was received.
c)
The CWS supplier shall notify the Agency and appropriate local
public health officials of the sodium levels by written notice by
direct mail within three months. A copy of each notice required to
be provided by this subsection must be sent to the Agency within
10 days of its issuance.
d)
Analyses for sodium must be conducted as directed in Section
611.611(a).
BOARD NOTE: Derived from 40 CFR 141.41 (1994), as amended
at 59 Fed. Reg. 62470 (Dec. 5, 1994).
(Source: Amended at 20 Ill. Reg. ________, effective ______________________)
SUBPART O: ORGANIC MONITORING AND ANALYTICAL REQUIREMENTS
Section 611.641
Old MCLs
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a)
An analysis of substances for the purpose of determining
compliance with the old MCLs of Section 611.310 must be made as
follows:
1)
The Agency shall, by SEP, require CWS suppliers utilizing
surface water sources to collect samples during the period
of the year when contamination by pesticides is most likely
to occur. The Agency shall require the supplier to repeat
these analyses at least annually.
2)
The Agency shall, by SEP, require CWS suppliers utilizing
only groundwater sources to collect samples at least once
every three years.
b)
If the result of an analysis made pursuant to subsection (a)
indicates that the level of any contaminant exceeds its old MCL,
the CWS supplier shall report to the Agency within 7 days and
initiate three additional analyses within one month.
c)
When the average of four analyses made pursuant to subsection (a),
rounded to the same number of significant figures as the MCL for
the substance in question, exceeds the old MCL, the CWS supplier
shall report to the Agency and give notice to the public pursuant
to Subpart T. Monitoring after public notification must be at a
frequency designated by the Agency and must continue until the MCL
has not been exceeded in two successive samples or until a
monitoring schedule as a condition to a variance, adjusted
standard or enforcement action becomes effective.
d)
Analysis made to determine compliance with the old MCLs of Section
611.310 must be made in accordance with the appropriate methods
specified in Section 611.648(l)5.
BOARD NOTE: This provision now applies only to state-only MCLs.
It was formerly derived from 40 CFR 141.24(a) through (e), which
U.S. EPA removed and reserved at 59 Fed. Reg. 34323 (July 1,
1994).
(Source: Amended at 20 Ill. Reg. ________, effective ______________________)
Section 611.645
Analytical Methods for Organic Chemical Contaminants
Analysis for the Section 611.311(a) VOCs under Section 611.646,; the Section
611.311(c) SOCs under Section 611.648,; and the Section 611.310 old organic
MCLs under Section 611.641; and for THMs, TTHMs, and TTHM potential shall be
conducted using the methods listed in this Section or by equivalent methods as
approved by the Agency pursuant to Section 611.480. All methods are from U.S.
EPA Organic Methods unless otherwise indicated.
Volatile Organic Chemical Contaminants (VOCs):
94
Contaminant
Analytical Methods
Benzene
502.2, 524.2
Carbon tetrachloride
502.2, 524.2, 551
Chlorobenzene
502.2, 524.2
1,2-Dichlorobenzene
502.2, 524.2
1,4-Dichlorobenzene
502.2, 524.2
1,2-Dichloroethane
502.2, 524.2
cis-Dichloroethylene
502.2, 524.2
trans-Dichloroethylene
502.2, 524.2
Dichloromethane
502.2, 524.2
1,2-Dichloropropane
502.2, 524.2
Ethylbenzene
502.2, 524.2
Styrene
502.2, 524.2
Tetrachloroethylene
502.2, 524.2, 551
1,1,1-Trichloroethane
502.2, 524.2, 551
Trichloroethylene
502.2, 524.2, 551
Toluene
502.2, 524.2
1,2,4-Trichlorobenzene
502.2, 524.2
1,1-Dichloroethylene
502.2, 524.2
1,1,2-Trichloroethane
502.2, 524.2
Vinyl chloride
502.2, 524.2
Xylenes (total)
502.2, 524.2
Synthetic Organic Chemical Contaminants (SOCs):
Contaminant
Analytical Methods
2,3,7,8-Tetrachlorodibenzodioxin (2,3,7,8-TCDD
or dioxin)
Dioxin and Furan
Method 1613
95
2,4-D
515.1, 515.2, 555
2,4,5-TP (Silvex)
515.1, 515.2, 555
Alachlor
505*, 507, 508.1,
525.2
Atrazine
505*, 507, 508.1,
525.2
Benzo(a)pyrene
525.2, 550, 550.1
Carbofuran
531.1, Standard
Methods, 18th ed.:
Method 6610
Chlordane
505, 508, 508.1,
525.2
Dalapon
515.1, 552.1
Di(2-ethylhexyl)adipate
506, 525.2
Di(2-ethylhexyl)phthalate
506, 525.2
Dibromochloropropane (DBCP)
504.1, 551
Dinoseb
515.1, 515.2, 555
Diquat
549.1
Endothall
548.1
Endrin
505, 508, 508.1,
525.2
Ethylene Dibromide (EDB)
504.1, 551
Glyphosate
547, Standard
Methods, 18th ed.:
Method 6651
Heptachlor
505, 508, 508.1,
525.2
Heptachlor Epoxide
505, 508, 508.1,
525.2
Hexachlorobenzene
505, 508, 508.1,
525.2
96
Hexachlorocyclopentadiene
505, 508, 508.1,
525.2
Lindane
505, 508, 508.1,
525.2
Methoxychlor
505, 508, 508.1,
525.2
Oxamyl
531.1, Standard
Methods, 18th ed.:
Method 6610
PCBs (measured for compliance purposes as
decchlorobiphenyl)
508A
PCBs (qualitatively identified as Araclors)
505, 508
Pentachlorophenol
515.1, 515.2, 525.2,
555
Picloram
515.1, 515.2, 555
Simazine
505*, 507, 508.1,
525.2
Toxaphene
505, 508, 525.2
Total Trihalomethanes (TTHMs):
Contaminant
Analytical Methods
Total Trihalomethanes (TTHMs), Trihalomethanes
(THMs), and Maximum Total Trihalomethane
Potential
502.2, 524.2, 551
State-Only MCLs (for which a method is not listed above):
Contaminant
Analytical Methods
Aldrin
505, 508, 508.1,
525.2
DDT
505, 508
Dieldrin
505, 508, 508.1,
525.2
* denotes that for the particular contaminant, a nitrogen-phosphorus detector
should be substituted for the electron capture detector in method 505 (or
97
another approved method should be used) to determine alachlor, atrazine, and
simazine if lower detection limits are required.
BOARD NOTE: Derived from 40 CFR 141.24(e) (19945), as added at 59 Fed. Reg.
62469 (Dec. 5, 1994).
(Source: Amended at 20 Ill. Reg. ________, effective ______________________)
Section 611.646
Phase I, Phase II, and Phase V Volatile Organic Contaminants
Monitoring of the Phase I, Phase II, and Phase V VOCs for the purpose of
determining compliance with the MCL must be conducted as follows:
a)
Definitions. As used in this Section:
"Detect" and "detection" means that the contaminant of
interest is present at a level greater than or equal to the
"detection limit".
"Detection limit" means 0.0005 mg/L.
BOARD NOTE: Derived from 40 CFR 141.24(f)(7), (f)(11),
(f)(14)(i), and (f)(20) (1994). This is a "trigger level"
for Phase I, Phase II, and Phase V VOCs inasmuch as it
prompts further action. The use of the term "detect" in
this section is not intended to include any analytical
capability of quantifying lower levels of any contaminant,
or the "method detection limit". Note, however that certain
language at the end of federal paragraph (f)(20) is capable
of meaning that the "method detection limit" is used to
derive the "detection limit". The Board has chosen to
disregard that language at the end of paragraph (f)(20) in
favor of the more direct language of paragraphs (f)(7) and
(f)(11).
"Method detection limit", as used in subsections (q) and (t)
below means the minimum concentration of a substance that
can be measured and reported with 99 percent confidence that
the analyte concentration is greater than zero and is
determined from analysis of a sample in a given matrix
containing the analyte.
BOARD NOTE: Derived from 40 CFR 136, Appendix B (1994).
The method detection limit is determined by the procedure
set forth in 40 CFR 136, Appendix B. See subsection (t)
below.
b)
Required sampling. Each supplier shall take a minimum of one
sample at each sampling point at the times required in subsection
(u) below.
98
c)
Sampling points.
1)
Sampling points for GWSs. Unless otherwise provided by SEP,
a GWS supplier shall take at least one sample from each of
the following points: each entry point that is
representative of each well after treatment.
2)
Sampling points for SWSs and mixed systems. Unless
otherwise provided by SEP, a SWS or mixed system supplier
shall sample from each of the following points:
A)
Each entry point after treatment; or
B)
Points in the distribution system that are
representative of each source.
3)
The supplier shall take each sample at the same sampling
point unless the Agency has granted a SEP that designates
another location as more representative of each source,
treatment plant, or within the distribution system.
4)
If a system draws water from more than one source, and the
sources are combined before distribution, the supplier shall
sample at an entry point during periods of normal operating
conditions when water is representative of all sources being
used.
BOARD NOTE: Subsections (b) and (c) above derived from 40
CFR 141.24(f)(1) through (f)(3) (1994).
d)
Each CWS and NTNCWS supplier shall take four consecutive quarterly
samples for each of the Phase I VOCs, excluding vinyl chloride,
and Phase II VOCs during each compliance period, beginning in the
compliance period starting in the initial compliance period.
e)
Reduction to annual monitoring frequency. If the initial
monitoring for the Phase I, Phase II, and Phase V VOCs as allowed
in subsection (r)(1) below has been completed by December 31,
1992, and the supplier did not detect any of the Phase I VOCs,
including vinyl chloride, Phase II, or Phase V VOCs, then the
supplier shall take one sample annually beginning in the initial
compliance period.
f)
GWS reduction to triennial monitoring frequency. After a minimum
of three years of annual sampling, GWS suppliers that have not
previously detected any of the Phase I VOCs, including vinyl
chloride, Phase II, or Phase V VOCs shall take one sample during
each three-year compliance period.
g)
A CWS or NTNCWS supplier that has completed the initial round of
monitoring required by subsection (d) above and which did not
99
detect any of the Phase I VOCs, including vinyl chloride, Phase
II, and Phase V VOCs may apply to the Agency for a SEP pursuant to
Section 611.110 that releases it from the requirements of
subsection (e) or (f) above. A supplier that serves fewer than
3300 service connections may apply to the Agency for a SEP
pursuant to Section 611.110 that releases it from the requirements
of subsection (d) above as to 1,2,4-trichlorobenzene.
BOARD NOTE: Derived from 40 CFR 141.24(f)(7) and (f)(10) (1994),
and the discussion at 57 Fed. Reg. 31825 (July 17, 1992).
Provisions concerning the term of the waiver appear below in
subsections (i) and (j) below. The definition of "detect",
parenthetically added to the federal counterpart paragraph is in
subsection (a) above.
h)
Vulnerability Assessment. The Agency shall consider the factors
of Section 611.110(e) in granting a SEP from the requirements of
subsections (d), (e), or (f) above sought pursuant to subsection
(g) above.
i)
A SEP issued to a GWS pursuant to subsection (g) above is for a
maximum of six years, except that a SEP as to the subsection (d)
above monitoring for 1,2,4-trichlorobenzene shall apply only to
the initial round of monitoring. As a condition of a SEP, except
as to a SEP from the initial round of subsection (d) above
monitoring for 1,2,4-trichlorobenzene, the supplier shall, within
30 months after the beginning of the period for which the waiver
was issued, reconfirm its vulnerability assessment required by
subsection (h) above and submitted pursuant to subsection (g)
above, by taking one sample at each sampling point and reapplying
for a SEP pursuant to subsection (g) above. Based on this
application, the Agency shall either:
1)
If it determines that the PWS meets the standard of Section
611.610(e), issue a SEP that reconfirms the prior SEP for
the remaining three-year compliance period of the six-year
maximum term; or,
2)
Issue a new SEP requiring the supplier to sample annually.
BOARD NOTE: This provision does not apply to SWSs and mixed
systems.
j)
Special considerations for SEPs for SWS and mixed systems.
1)
The Agency must determine that a SWS is not vulnerable
before issuing a SEP pursuant to a SWS supplier. A SEP
issued to a SWS or mixed system supplier pursuant to
subsection (g) above is for a maximum of one compliance
period; and
100
2)
The Agency may require, as a condition to a SEP issued to a
SWS or mixed supplier, that the supplier take such samples
for Phase I, Phase II, and Phase V VOCs at such a frequency
as the Agency determines are necessary, based on the
vulnerability assessment.
BOARD NOTE: There is a great degree of similarity between
40 CFR 141.24(f)(7), the provision applicable to GWSs, and
40 CFR 141.24(f)(10), the provision for SWSs. The Board has
consolidated the common requirements of both paragraphs into
subsection (g) above. Subsection (j) above represents the
elements unique to SWSs and mixed systems, and subsection
(i) above relates to GWSs. Although 40 CFR 141.24(f)(7) and
(f)(10) are silent as to mixed systems, the Board has
included mixed systems with SWSs because this best follows
the federal scheme for all other contaminants.
k)
If one of the Phase I VOCs, excluding vinyl chloride, Phase II, or
Phase V VOCs is detected in any sample, then:
1)
The supplier shall monitor quarterly for that contaminant at
each sampling point that resulted in a detection.
2)
Annual monitoring.
A)
The Agency shall grant a SEP pursuant to Section
611.110 that allows a supplier to reduce the
monitoring frequency to annual at a sampling point if
it determines that the sampling point is reliably and
consistently below the MCL.
B)
A request for a SEP must include the following minimal
information:
i)
For a GWS, two quarterly samples.
ii)
For a SWS or mixed system, four quarterly
samples.
C)
In issuing a SEP, the Agency shall specify the level
of the contaminant upon which the "reliably and
consistently" determination was based. All SEPs that
allow less frequent monitoring based on an Agency
"reliably and consistently" determination shall
include a condition requiring the supplier to resume
quarterly monitoring pursuant to subsection (k)(1)
above if it violates the MCL specified by Section
611.311.
101
3)
Suppliers that monitor annually shall monitor during the
quarter(s) that previously yielded the highest analytical
result.
4)
Suppliers that do not detect a contaminant at a sampling
point in three consecutive annual samples may apply to the
Agency for a SEP pursuant to Section 611.110 that allows it
to discontinue monitoring for that contaminant at that
point, as specified in subsection (g) above.
5)
A GWS supplier that has detected one or more of the two-
carbon contaminants listed in subsection (k)(5)(A) below
shall monitor quarterly for vinyl chloride as described in
subsection (k)(5)(B) below, subject to the limitation of
subsection (k)(5)(C) below.
A)
Two-carbon contaminants (Phase I or II VOC):
1,2-Dichloroethane (Phase I)
1,1-Dichloroethylene (Phase I)
cis-1,2-Dichloroethylene (Phase II)
trans-1,2-Dichloroethylene (Phase II)
Tetrachloroethylene (Phase II)
1,1,1-Trichloroethylene (Phase I)
Trichloroethylene (Phase I)
B)
The supplier shall sample quarterly for vinyl chloride
at each sampling point at which it detected one or
more of the two-carbon contaminants listed in
subsection (k)(5)(A) above.
C)
The Agency shall grant a SEP pursuant to Section
611.110 that allows the supplier to reduce the
monitoring frequency for vinyl chloride at any
sampling point to once in each three-year compliance
period if it determines that the supplier has not
detected vinyl chloride in the first sample required
by subsection (k)(5)(B) above.
l)
Quarterly monitoring following MCL violations.
1)
Suppliers that violate an MCL for one of the Phase I VOCs,
including vinyl chloride, Phase II, or Phase V VOCs, as
determined by subsection (o) below, shall monitor quarterly
for that contaminant, at the sampling point where the
violation occurred, beginning the next quarter after the
violation.
2)
Annual monitoring.
102
A)
The Agency shall grant a SEP pursuant to Section
611.110 that allows a supplier to reduce the
monitoring frequency to annually if it determines that
the sampling point is reliably and consistently below
the MCL.
B)
A request for a SEP must include the following minimal
information: four quarterly samples.
C)
In issuing a SEP, the Agency shall specify the level
of the contaminant upon which the "reliably and
consistently" determination was based. All SEPs that
allow less frequent monitoring based on an Agency
"reliably and consistently" determination shall
include a condition requiring the supplier to resume
quarterly monitoring pursuant to subsection (l)(1)
above if it violates the MCL specified by Section
611.311.
D)
The supplier shall monitor during the quarter(s) that
previously yielded the highest analytical result.
m)
Confirmation samples. The Agency may issue a SEP pursuant to
Section 610.110 to require a supplier to use a confirmation sample
for results that it finds dubious for whatever reason. The Agency
must state its reasons for issuing the SEP if the SEP is Agency-
initiated.
1)
If a supplier detects any of the Phase I, Phase II, or Phase
V VOCs in a sample, the supplier shall take a confirmation
sample as soon as possible, but no later than 14 days after
the supplier receives notice of the detection.
2)
Averaging is as specified in subsection (o) below.
3)
The Agency shall delete the original or confirmation sample
if it determines that a sampling error occurred, in which
case the confirmation sample will replace the original or
confirmation sample.
n)
This subsection corresponds with 40 CFR 141.24(f)(14), an optional
U.S. EPA provision relating to compositing of samples that U.S.
EPA does not require for state programs. This statement maintains
structural consistency with U.S. EPA rules.
o)
Compliance with the MCLs for the Phase I, Phase II, and Phase V
VOCs must be determined based on the analytical results obtained
at each sampling point.
103
1)
For suppliers that conduct monitoring at a frequency greater
than annual, compliance is determined by a running annual
average of all samples taken at each sampling point.
A)
If the annual average of any sampling point is greater
than the MCL, then the supplier is out of compliance.
B)
If the initial sample or a subsequent sample would
cause the annual average to exceed the MCL, then the
supplier is out of compliance immediately.
C)
Any samples below the detection limit shall be deemed
as zero for purposes of determining the annual
average.
2)
If monitoring is conducted annually, or less frequently, the
supplier is out of compliance if the level of a contaminant
at any sampling point is greater than the MCL. If a
confirmation sample is taken, the determination of
compliance is based on the average of two samples.
3)
When the portion of the distribution system that is out of
compliance is separable from other parts of the distribution
system and has no interconnections, the supplier may issue
the public notice required by Subpart T of this Part only to
persons served by that portion of the distribution system
that is not in compliance.
p)
This provision corresponds with 40 CFR 141.24(f)(16) (1994), which
U.S. EPA removed and reserved at 59 Fed. Reg. 62468 (Dec. 5,
1994). This statement maintains structural consistency with the
federal regulations.
q)
Analysis under this Section must only be conducted by laboratories
that have received certification by U.S. EPA or the Agency
according to the following conditions:
1)
To receive certification to conduct analyses for the Phase I
VOCs, excluding vinyl chloride, Phase II VOCs, and Phase V
VOCs, the laboratory must:
A)
Analyze performance evaluation samples that include
these substances provided by the Agency pursuant to 35
Ill. Adm. Code 183.125(c);
B)
Achieve the quantitative acceptance limits under
subsections (q)(1)(C) and (q)(1)(D) below for at least
80 percent of the Phase I VOCs, excluding vinyl
chloride, Phase II VOCs, except vinyl chloride, or
Phase V VOCs;
104
C)
Achieve quantitative results on the analyses performed
under subsection (q)(1)(A) above that are within ± 20
percent of the actual amount of the substances in the
performance evaluation sample when the actual amount
is greater than or equal to 0.010 mg/L;
D)
Achieve quantitative results on the analyses performed
under subsection (q)(1)(A) above that are within ± 40
percent of the actual amount of the substances in the
performance evaluation sample when the actual amount
is less than 0.010 mg/L; and
E)
Achieve a method detection limit of 0.0005 mg/L,
according to the procedures in 40 CFR 136, appendix B,
incorporated by reference in Section 611.102.
2)
To receive certification to conduct analyses for vinyl
chloride the laboratory must:
A)
Analyze performance evaluation samples provided by the
Agency pursuant to 35 Ill. Adm. Code 183.125(c);
B)
Achieve quantitative results on the analyses performed
under subsection (q)(2)(A) above that are within ± 40
percent of the actual amount of vinyl chloride in the
performance evaluation sample;
C)
Achieve a method detection limit of 0.0005 mg/L,
according to the procedures in 40 CFR 136, appendix B,
incorporated by reference in Section 611.102; and
D)
Obtain certification pursuant to subsection (q)(1)
above for Phase I VOCs, excluding vinyl chloride,
Phase II VOCs, and Phase V VOCs.
r)
Use of existing data.
1)
The Agency shall allow the use of data collected after
January 1, 1988 but prior to the effective date of this
Section, pursuant to Agency sample request letters, if it
determines that the data are generally consistent with the
requirements of this Section.
2)
The Agency shall grant a SEP pursuant to Section 611.110
that allows a supplier to monitor annually beginning in the
initial compliance period if it determines that the supplier
did not detect any Phase I, Phase II, or Phase V VOC using
existing data allowed pursuant to subsection (r)(1) above.
105
s)
The Agency shall, by SEP, increase the number of sampling points
or the frequency of monitoring if it determines that it is
necessary to detect variations within the PWS.
t)
Each laboratory certified for the analysis of Phase I, Phase II,
or Phase V VOCs pursuant to subsection (q)(1) or (q)(2) above
shall:
1)
Determine the method detection limit (MDL), as defined in 40
CFR 136, Appendix B, incorporated by reference in Section
611.102, at which it is capable of detecting the Phase I,
Phase II, and Phase V VOCs; and,
2)
Achieve an MDL for each Phase I, Phase II, and Phase V VOC
that is less than or equal to 0.0005 mg/L.
u)
Each supplier shall monitor, within each compliance period, at the
time designated by the Agency by SEP pursuant to Section 611.110.
BOARD NOTE: Derived from 40 CFR 141.24(f) (1994).
(Source: Amended at 20 Ill. Reg. ________, effective ______________________)
Section 611.648
Phase II, Phase IIB, and Phase V Synthetic Organic
Contaminants
Analysis of the Phase II, Phase IIB, and Phase V SOCs for the purposes of
determining compliance with the MCL must be conducted as follows:
a)
Definitions. As used in this Section:
"Detect or detection" means that the contaminant of interest
is present at a level greater than or equal to the
"detection limit".
"Detection limit" means the level of the contaminant of
interest that is specified in subsection (r) below.
BOARD NOTE: This is a "trigger level" for Phase II, Phase
IIB, and Phase V SOCs inasmuch as it prompts further action.
The use of the term "detect" or "detection" in this section
is not intended to include any analytical capability of
quantifying lower levels of any contaminant, or the "method
detection limit".
b)
Required sampling. Each supplier shall take a minimum of one
sample at each sampling point at the times required in subsection
(q) below.
BOARD NOTE: U.S. EPA stayed the effective date of the MCLs for
aldicarb, aldicarb sulfone, and aldicarb sulfoxide at 57 Fed. Reg.
106
22178 (May 27, 1991). Section 611.311(c) includes this stay.
However, despite the stay of the effectiveness of the MCLs for
these three SOCs, suppliers must monitor for them.
c)
Sampling points.
1)
Sampling points for GWSs. Unless otherwise provided by SEP,
a GWS supplier shall take at least one sample from each of
the following points: each entry point that is
representative of each well after treatment.
2)
Sampling points for SWSs and mixed systems. Unless
otherwise provided by SEP, a SWS or mixed system supplier
shall sample from each of the following points:
A)
Each entry point after treatment; or
B)
Points in the distribution system that are
representative of each source.
3)
The supplier shall take each sample at the same sampling
point unless the Agency has granted a SEP that designates
another location as more representative of each source,
treatment plant, or within the distribution system.
4)
If a system draws water from more than one source, and the
sources are combined before distribution, the supplier shall
sample at an entry point during periods of normal operating
conditions when water is representative of all sources being
used.
BOARD NOTE: Subsections (b) and (c) above derived from 40
CFR 141.24(h)(1) through (h)(3) (19945).
d)
Monitoring frequency:
1)
Each CWS and NTNCWS supplier shall take four consecutive
quarterly samples for each of the Phase II, Phase IIB, and
Phase V SOCs during each compliance period, beginning in the
three-year compliance period starting in the initial
compliance period.
2)
Suppliers serving more than 3,300 persons that do not detect
a contaminant in the initial compliance period, shall take a
minimum of two quarterly samples in one year of each
subsequent three-year compliance period.
3)
Suppliers serving less than or equal to 3,300 persons that
do not detect a contaminant in the initial compliance
period, shall take a minimum of one sample during each
subsequent three-year compliance period.
107
e)
Reduction to annual monitoring frequency. A CWS or NTNCWS
supplier may apply to the Agency for a SEP that releases it from
the requirements of subsection (d) above. A SEP from the
requirement of subsection (d) above shall last for only a single
three-year compliance period.
f)
Vulnerability Assessment. The Agency shall grant a SEP from the
requirements of subsection (d) above based on consideration of the
factors set forth at Section 611.110(e).
g)
If one of the Phase II, Phase IIB, or Phase V SOCs is detected in
any sample, then:
1)
The supplier shall monitor quarterly for the contaminant at
each sampling point that resulted in a detection.
2)
Annual monitoring.
A)
A supplier may request that the Agency grant a SEP
pursuant to Section 610.110 that reduces the
monitoring frequency to annual.
B)
A request for a SEP must include the following minimal
information:
i)
For a GWS, two quarterly samples.
ii)
For a SWS or mixed system, four quarterly
samples.
C)
The Agency shall grant a SEP that allows annual
monitoring at a sampling point if it determines that
the sampling point is reliably and consistently below
the MCL.
D)
In issuing the SEP, the Agency shall specify the level
of the contaminant upon which the "reliably and
consistently" determination was based All SEPs that
allow less frequent monitoring based on an Agency
"reliably and consistently" determination shall
include a condition requiring the supplier to resume
quarterly monitoring pursuant to subsection (g)(1)
above if it detects any Phase II SOC.
3)
Suppliers that monitor annually shall monitor during the
quarter(s) that previously yielded the highest analytical
result.
4)
Suppliers that have three consecutive annual samples with no
detection of a contaminant at a sampling point may apply to
108
the Agency for a SEP with respect to that point, as
specified in subsections (e) and (f) above.
5)
Monitoring for related contaminants.
A)
If monitoring results in detection of one or more of
the related contaminants listed in subsection
(g)(5)(B) below, subsequent monitoring shall analyze
for all the related compounds in the respective group.
B)
Related contaminants:
i)
first group:
aldicarb
aldicarb sulfone
aldicarb sulfoxide
ii)
second group:
heptachlor
heptachlor epoxide.
h)
Quarterly monitoring following MCL violations.
1)
Suppliers that violate an MCL for one of the Phase II, Phase
IIB, or Phase V SOCs, as determined by subsection (k) below,
shall monitor quarterly for that contaminant at the sampling
point where the violation occurred, beginning the next
quarter after the violation.
2)
Annual monitoring.
A)
A supplier may request that the Agency grant a SEP
pursuant to Section 611.110 that reduces the
monitoring frequency to annual.
B)
A request for a SEP must include, at a minimum, the
results from four quarterly samples.
C)
The Agency shall grant a SEP that allows annual
monitoring at a sampling point if it determines that
the sampling point is reliably and consistently below
the MCL.
D)
In issuing the SEP, the Agency shall specify the level
of the contaminant upon which the "reliably and
consistently" determination was based. All SEPs that
allow less frequent monitoring based on an Agency
"reliably and consistently" determination shall
include a condition requiring the supplier to resume
109
quarterly monitoring pursuant to subsection (h)(1)
above if it detects any Phase II SOC.
E)
The supplier shall monitor during the quarter(s) that
previously yielded the highest analytical result.
i)
Confirmation samples.
1)
If any of the Phase II, Phase IIB, or Phase V SOCs are
detected in a sample, the supplier shall take a confirmation
sample as soon as possible, but no later than 14 days after
the supplier receives notice of the detection.
2)
Averaging is as specified in subsection (k) below.
3)
The Agency shall delete the original or confirmation sample
if it determines that a sampling error occurred, in which
case the confirmation sample will replace the original or
confirmation sample.
j)
This subsection corresponds with 40 CFR 141.24(h)(10), an optional
U.S. EPA provision relating to compositing of samples that U.S.
EPA does not require for state programs. This statement maintains
structural consistency with U.S. EPA rules.
k)
Compliance with the MCLs for the Phase II, Phase IIB, and Phase V
SOCs shall be determined based on the analytical results obtained
at each sampling point.
1)
For suppliers that are conducting monitoring at a frequency
greater than annual, compliance is determined by a running
annual average of all samples taken at each sampling point.
A)
If the annual average of any sampling point is greater
than the MCL, then the supplier is out of compliance.
B)
If the initial sample or a subsequent sample would
cause the annual average to be exceeded, then the
supplier is out of compliance immediately.
C)
Any samples below the detection limit must be
calculated as zero for purposes of determining the
annual average.
2)
If monitoring is conducted annually or less frequently, the
supplier is out of compliance if the level of a contaminant
at any sampling point is greater than the MCL. If a
confirmation sample is taken, the determination of
compliance is based on the average of two samples.
110
3)
When the portion of the distribution system that is out of
compliance is separable from other parts of the distribution
system and has no interconnections, the supplier may issue
the public notice required by Subpart T of this Part only to
persons served by that portion of the distribution system
that is not in compliance.
BOARD NOTE: Derived from 40 CFR 141.24(h)(11) (19945).
l)
This provision corresponds with 40 CFR 141.24(h)(12) (19945),
which U.S. EPA removed and reserved at 59 Fed. Reg. 62468 (Dec. 5,
1994). This statement maintains structural consistency with the
federal regulations.
m)
Analysis for PCBs must be conducted as follows using the methods
in Section 611.645:
1)
Each supplier that monitors for PCBs shall analyze each
sample using either U.S. EPA Organic Methods, Method 505 or
Method 508.
2)
If PCBs are detected in any sample analyzed using U.S. EPA
Organic Methods, Methods 505 or 508, the supplier shall
reanalyze the sample using Method 508A to quantitate the
individual Aroclors (as decachlorobiphenyl).
3)
Compliance with the PCB MCL must be determined based upon
the quantitative results of analyses using U.S. EPA Organic
Methods, Method 508A.
n)
Use of existing data.
1)
The Agency shall allow the use of data collected after
January 1, 1990 but prior to the effective date of this
Section, pursuant to Agency sample request letters, if it
determines that the data are generally consistent with the
requirements of this Section.
2)
The Agency shall grant a SEP pursuant to Section 611.110
that allows a supplier to monitor annually beginning in the
initial compliance period if it determines that the supplier
did not detect any Phase I VOC or Phase II VOC using
existing data allowed pursuant to subsection (n)(1) above.
o)
The Agency shall issue a SEP that increases the number of sampling
points or the frequency of monitoring if it determines that this
is necessary to detect variations within the PWS due to such
factors as fluctuations in contaminant concentration due to
seasonal use or changes in the water source.
111
BOARD NOTE: At 40 CFR 141.24(h)(15), U.S. EPA uses the stated
factors as non-limiting examples of circumstances that make
additional monitoring necessary.
p)
This subsection corresponds with 40 CFR 141.24(h)(16), a U.S. EPA
provision that the Board has not adopted because it reserves
enforcement authority to the state and would serve no useful
function as part of the state's rules. This statement maintains
structural consistency with U.S. EPA rules.
q)
Each supplier shall monitor, within each compliance period, at the
time designated by the Agency by SEP pursuant to Section 611.110.
r)
"Detection" means greater than or equal to the following
concentrations for each contaminant:
1)
for PCBs (Aroclors):
Aroclor
Detection Limit (mg/L)
1016
0.00008
1221
0.02
1232
0.0005
1242
0.0003
1248
0.0001
1254
0.0001
1260
0.0002
2)
for other Phase II, Phase IIB, and Phase V SOCs:
Contaminant
Detection Limit
(mg/L)
Alachlor
0.0002
Aldicarb
0.0005
Aldicarb sulfoxide
0.0005
Aldicarb sulfone
0.0008
Atrazine
0.0001
Benzo(a)pyrene
0.00002
Carbofuran
0.0009
Chlordane
0.0002
2,4-D
0.0001
Dalapon
0.001
1,2-Dibromo-3-chloropropane
(DBCP)
0.00002
Di(2-ethylhexyl)adipate
0.0006
Di(2-ethylhexyl)phthalate
0.0006
Dinoseb
0.0002
Diquat
0.0004
Endothall
0.009
Endrin
0.00001
112
Ethylene dibromide (EDB)
0.00001
Glyphosate
0.006
Heptachlor
0.00004
Heptachlor epoxide
0.00002
Hexachlorobenzene
0.0001
Hexachlorocyclopentadiene
0.0001
Lindane
0.00002
Methoxychlor
0.0001
Oxamyl
0.002
Picloram
0.0001
Polychlorinated biphenyls (PCBs)
(as decachlorobiphenyl)
0.0001
Pentachlorophenol
0.00004
Simazine
0.00007
Toxaphene
0.001
2,3,7,8-TCDD (dioxin)
0.000000005
2,4,5-TP (Silvex)
0.0002
s)
Laboratory Certification.
1)
Analyses under this Section must only be conducted by
laboratories that have received approval by U.S. EPA or the
Agency according to the following conditions.
2)
To receive certification to conduct analyses for the Phase
II, Phase IIB, and Phase V SOCs the laboratory must:
A)
Analyze performance evaluation samples provided by the
Agency pursuant to 35 Ill. Adm. Code 183.125(c) that
include these substances; and
B)
Achieve quantitative results on the analyses performed
under subsection (s)(2)(A) above that are within the
acceptance limits set forth in subsection (s)(2)(C)
abovebelow.
C)
Acceptance limits:
SOC
Acceptance Limits
Alachlor
± 45%
Aldicarb
2 standard deviations
Aldicarb sulfone
2 standard deviations
Aldicarb sulfoxide
2 standard deviations
Atrazine
± 45%
Benzo(a)pyrene
2 standard deviations
Carbofuran
± 45%
Chlordane
± 45%
Dalapon
2 standard deviations
Di(2-ethylhexyl)adipate
2 standard deviations
113
Di(2-ethylhexyl)phthalate
2 standard deviations
Dinoseb
2 standard deviations
Diquat
2 standard deviations
Endothall
2 standard deviations
Endrin
± 30%
Glyphosate
2 standard deviations
Dibromochloropropane (DBCP)
± 40%
Ethylene dibromide (EDB)
± 40%
Heptachlor
± 45%
Heptachlor epoxide
± 45%
Hexachlorobenzene
2 standard deviations
Hexachlorocyclopentadiene
2 standard deviations
Lindane
± 45%
Methoxychlor
± 45%
Oxamyl
2 standard deviations
PCBs (as Decachlorobiphenyl)
0-200%
Pentachlorophenol
± 50%
Picloram
2 standard deviations
Simazine
2 standard deviations
Toxaphene
± 45%
2,4-D
± 50%
2,3,7,8-TCDD (dioxin)
2 standard deviations
2,4,5-TP (Silvex)
± 50%
BOARD NOTE: Derived from 40 CFR 141.24(h)
(19945), as amended at 59 Fed. Reg. 62468 (Dec.
5, 1994).
(Source: Amended at 20 Ill. Reg. ________, effective ______________________)
SUBPART P: THM MONITORING AND ANALYTICAL REQUIREMENTS
Section 611.683
Reduced Monitoring Frequency
a)
A CWS supplier utilizing only groundwater sources may, by special
exception permit application, seek to have the monitoring
frequency required by Section 611.6810(b)(1) reduced to a minimum
of one sample for maximum TTHM potential per year for each
treatment plant used by the supplier, taken at a point in the
distribution system reflecting maximum residence time of the water
in the system.
1)
The CWS supplier shall submit to the Agency the results of
at least one sample analyzed for maximum TTHM potential
using the procedure specified in Section 611.687. A sample
must be analyzed forfrom each treatment plant used by the
supplier, taken at a point in the distribution system
114
reflecting the maximum residence time of the water in the
system.
2)
The Agency shall reduce the supplier's monitoring frequency
if it determines that, based upon the data submitted by the
supplier, the supplier has a maximum TTHM potential of less
than 0.10 mg/L and that, based upon an assessment of the
local conditions of the CWS, the CWS is not likely to
approach or exceed the MCL for TTHMs.
3)
The results of all analyses must be reported to the Agency
within 30 days of the supplier's receipt of such results.
4)
All samples collected must be used for determining whether
the supplier complies with the monitoring requirements of
Section 611.6810(b), unless the analytical results are
invalidated for technical reasons.
5)
Sampling and analyses must be conducted in accordance with
the methods listed in Section 611.685.
b)
Loss or modification of reduced monitoring frequency.
1)
If the results from any analysis taken by the supplier for
maximum TTHM potential are equal to or greater than 0.10
mg/L, and such results are confirmed by at least one check
sample taken promptly after such results are received, the
CWS supplier shall immediately begin monitoring in
accordance with the requirements of Section 611.6810(b), and
such monitoring must continue for at least one year before
the frequency may be reduced again.
2)
In the event of any significant change to the CWS's raw
water or treatment program, the supplier shall immediately
analyze an additional sample for maximum TTHM potential
taken at a point in the distribution system reflecting
maximum residence time of the water in the system.
3)
The Agency shall require increased monitoring frequencies
above the minimum where necessary to detect variation of
TTHM levels within the distribution system.
BOARD NOTE: Derived from 40 CFR 141.30 (c) (198994).
(Source: Amended at 20 Ill. Reg. ________, effective ______________________)
Section 611.684
Averaging
Compliance with Section 611.310(c) is determined based on a running annual
average of quarterly samples collected by the supplier as prescribed in
Section 611.6810(b)(1) or (2). If the average of samples covering any 12
115
month period exceeds the MCL, the CWS supplier shall report to the Agency and
notify the public pursuant to Subpart T. Monitoring after public notification
must be at a frequency designated by the Agency and must continue until a
monitoring schedule as a condition to a variance, adjusted standard or
enforcement action becomes effective.
BOARD NOTE: Derived from 40 CFR 141.30(d) (198994).
(Source: Amended at 20 Ill. Reg. ________, effective ______________________)
Section 611.685
Analytical Methods
Sampling and analyses made pursuant to this Subpart must be conducted by one
of the total trihalomethanes (TTHM) methods as directed in Section 611.645 and
in U.S. EPA Technical Notes, incorporated by reference in Section 611.102.
For the methods cited in subsections (a) and (b) above, see 40 CFR 141,
subpart C, appendix C, incorporated by reference in Section 611.102. Samples
for TTHM must be dechlorinated upon collection to prevent further production
of Trihalomethanes, according to the procedures described in the methods,
except acidification is not required if only THMs or TTHMs are to be
determined. Samples for maximum TTHM potential must not be dechlorinated or
acidified, and should be held for seven days at 25
°
C (or above) prior to
analysis.
BOARD NOTE: Derived from 40 CFR 141.30(e) (19945), as amended at 59 Fed. Reg.
62469 (Dec. 5, 1994).
(Source: Amended at 20 Ill. Reg. ________, effective ______________________)
Section 611.687
Sampling for Maximum THM Potential
a)
The water sample for determination of maximum total trihalomethane
potential must be taken from a point in the distribution system
that reflects maximum residence time. Procedures for sample
collection and handling are given in the methods.
b)
The supplier taking samples shall not add reducing agent to
"quench" the chemical reaction producing THMs at the time of
sample collection. The intent is to permit the level of THM
precursors to be depleted and the concentration of THMs to be
maximized for the supply being tested.
c)
Four experimental parameters affecting maximum THM production are
pH, temperature, reaction time, and the presence of a disinfectant
residual. The supplier taking the sample shall deal with these
parameters as follows:
1)
Measure the disinfectant residual at the selected sampling
point. Proceed only if a measurable disinfectant residual
is present.
116
2)
Collect triplicate 40 mL water samples at the pH prevailing
at the time of sampling, and prepare a method blank
according to the methods.
3)
Seal and store these samples together for seven days at 25
°
C or above.
4)
After this time period, open one of the sample containers
and check for disinfectant residual. Absence of a
disinfectant residual invalidates the sample for further
analysis.
5)
Once a disinfectant residual has been demonstrated, open
another of the sealed samples and determine total THM
concentration using an approved analytical method.
BOARD NOTE: Derived from 40 CFR 141.30(g) (1995).
(Source: Added at 20 Ill. Reg. ________, effective ______________________)
SUBPART Q: RADIOLOGICAL MONITORING AND ANALYTICAL REQUIREMENTS
Section 611.720
Analytical Methods
a)
The methods specified below, incorporated by reference in Section
611.102, are to be used to determine compliance with Sections
611.330 and 611.331, except in cases where alternative methods
have been approved in accordance with Section 611.480.
1)
Radiochemical Methods;
2)
Standard Methods, 13th Edition:
A)
Gross Alpha and Beta: Method 302;
B)
Total Radium: Method 304;
C)
Radium-226: Method 305;
D)
Strontium-89,90: Method 303;
E)
Tritium: Method 306.
3)
ASTM Methods:
A)
Cesium-134: ASTM D-2459;
B)
Uranium: ASTM D-2907.
117
b)
When the identification and measurement of radionuclides other
than those listed in subsection (a) isare required, the following
methods, incorporated by reference in Section 611.102, are to be
used, except in cases where alternative methods have been approved
in accordance with Section 611.480:
1)
"Procedures for Radiochemical Analysis of Nuclear Reactor
Aqueous Solutions", available from NTIS.
2)
HASL Procedure Manual, HASL 300.
c)
For the purpose of monitoring radioactivity concentrations in
drinking water, the required sensitivity of the radioanalysis is
defined in terms of a detection limit. The detection limit must
be that concentration which can be counted with a precision of
plus or minus 100 percent at the 95 percent confidence level (1.96
sigma where sigma is the standard deviation of the net counting
rate of the sample).
1)
To determine compliance with Section 611.330(a) the
detection limit must not exceed 1 pCi/L. To determine
compliance with Section 611.330(b) the detection limit must
not exceed 3 pCi/L.
2)
To determine compliance with Section 611.331 the detection
limits must not exceed the concentrations listed in that
Section.
d)
To judge compliance with the MCLs listed in Sections 611.330 and
611.331, averages of data must be used and must be rounded to the
same number of significant figures as the MCL for the substance in
question.
BOARD NOTE: Derived from 40 CFR 141.25 (198995).
(Source: Amended at 20 Ill. Reg. ________, effective ______________________)
Section 611.731
Gross Alpha
Monitoring requirements for gross alpha particle activity, radium-226 and
radium-228 are as follows:
a)
Compliance must be based on the analysis of an annual composite of
four consecutive quarterly samples or the average of the analyses
of four samples obtained at quarterly intervals.
1)
A gross alpha particle activity measurement may be
substituted for the required radium-226 and radium-228
analysis;, provided, that, the measured gross alpha particle
activity does not exceed 5 pCi/L at a confidence level of 95
percent (1.65 sigma where sigma is the standard deviation of
118
the net counting rate of the sample). In localities where
radium-228 may be present in drinking water, the Agency may,
by special exception permit, require radium-226 or radium-
228 analyses if it determines that the gross alpha particle
activity exceeds 2 pCi/L.
2)
When the gross alpha particle activity exceeds 5 pCi/L, the
same or an equivalent sample must be analyzed for radium-
226. If the concentration of radium-226 exceeds 3 pCi/L the
same or an equivalent sample must be analyzed for radium-
228.
b)
See Section 611.100(e).
c)
CWS suppliers shall monitor at least once every four years
following the procedure required by subsection (a). When an
annual record taken in conformance with subsection (a) has
established that the average annual concentration is less than
half the MCLs established by Section 611.330, the Agency shall, by
special exception permit, substitute analysis of a single sample
for the quarterly sampling procedure required by subsection (a).
1)
The Agency shall, by special exception permit, require more
frequent monitoring in the vicinity of mining or other
operations which may contribute alpha particle radioactivity
to either surface or groundwater sources of drinking water.
2)
A CWS supplier shall monitor in conformance with subsection
(a) for one year after the introduction of a new water
source. The Agency shall, by special exception permit,
require more frequent monitoring in the event of possible
contamination or when changes in the distribution system or
treatment processing occur which may increase the
concentration of radioactivity in finished water.
3)
The Agency shall, by special exception permit, require a CWS
supplier using two or more sources having different
concentrations of radioactivity to monitor source water, in
addition to water from a free-flowing tap.
4)
The Agency shall not require monitoring for radium-228 to
determine compliance with Section 611.330 after the initial
period;, provided, that the average annual concentration of
radium-228 has been assayed at least once using the
quarterly sampling procedure required by subsection (a).
5)
The Agency shall require the CWS supplier to conduct annual
monitoring if the radium-226 concentration exceeds 3 pCi/L.
d)
If the average annual MCL for gross alpha particle activity or
total radium as set forth in Section 611.330 is exceeded, the CWS
119
supplier shall give notice to the Agency and notify the public as
required by Subpart T. Monitoring at quarterly intervals must be
continued until the annual average concentration no longer exceeds
the MCL or until a monitoring schedule as a condition to a
variance, adjusted standard or enforcement action becomes
effective.
BOARD NOTE: Derived from 40 CFR 141.26(a) (198995).
(Source: Amended at 20 Ill. Reg. ________, effective ______________________)
Section 611.732
Manmade Radioactivity
Monitoring requirements for manmade radioactivity in CWSs are as follows:
a)
CWSs using surface water sources and serving more than 100,000
persons and such other CWSs as the Agency, by special exception
permit, requires must monitor for compliance with Section 611.331
by analysis of a composite of four consecutive quarterly samples
or analysis of four quarterly samples. Compliance with Section
611.331 is assumed without further analysis if the average annual
concentration of gross beta particle activity is less than 50
pCi/L and if the average annual concentrations of tritium and
strontium-90 are less than those listed in Section 611.331;,
provided, that if both radionuclides are present the sum of their
annual doses equivalents to bone marrow must not exceed 4
millirem/year.
1)
If the gross beta particle activity exceeds 50 pCi/L, an
analysis of the sample must be performed to identify the
major radioactive constituents present and the appropriate
organ and total body doses must be calculated to determine
compliance with Section 611.331.
2)
If the MCLs are exceeded, the Agency shall, by special
exception permit, require the supplier to conduct additional
monitoring to determine the concentration of man-made
radioactivity in principal watersheds.
3)
The Agency shall, pursuant to subsection (d), by special
exception permit, require suppliers of water utilizing only
groundwater to monitor for man-made radioactivity.
b)
See Section 611.100(e).
c)
CWS suppliers shall monitor at least every four years following
the procedure in subsection (a).
d)
The Agency shall, by special exception permit, require any CWS
supplier utilizing waters contaminated by effluents from nuclear
facilities to initiate quarterly monitoring for gross beta
120
particle and iodine-131 radioactivity and annual monitoring for
strontium-90 and tritium.
1)
Quarterly monitoring for gross beta particle activity must
be based on the analysis of monthly samples or the analysis
of a composite of three monthly samples. If the gross beta
particle activity in a sample exceeds 15 pCi/L, the same or
an equivalent sample must be analyzed for strontium-89 and
cesium-134. If the gross beta particle activity exceeds 50
pCi/L, an analysis of the sample must be performed to
identify the major radioactive constitutents present and the
appropriate organ and total body doses must be calculated to
determine compliance with Section 611.331.
2)
For iodine-131, a composite of five consecutive daily
samples must be analyzed once each quarter. The Agency
shall, by special exception permit, require more frequent
monitoring when iodine-131 is identified in the finished
water.
3)
The Agency shall, by special exception permit, require
annual monitoring for strontium-90 and tritium by means of
the analysis of a composite of four consecutive quarterly
samples or analysis of four quarterly samples.
4)
The Agency shall, by special exception permit, allow the
substitution of environmental surveillance data taken in
conjunction with a nuclear facility for direct monitoring of
manmade radioactivity by the supplier where the Agency
determines such data is applicable to the CWS.
e)
If the average annual MCL for man-made radioactivity set forth in
Section 611.331 is exceeded, the CWS supplier shall give notice to
the Agency and to the public as required by Subpart T. Monitoring
at monthly intervals must be continued until the concentration no
longer exceeds the MCL or until a monitoring schedule as a
condition to a variance, adjusted standard or enforcement action
becomes effective.
BOARD NOTE: Derived from 40 CFR 141.26(b) (198995).
(Source: Amended at 20 Ill. Reg. ________, effective ______________________)
SUBPART T: REPORTING, PUBLIC NOTIFICATION AND RECORDKEEPING
Section 611.831
Monthly Operating Report
Within 30 days following the last day of the month, each CWS supplier shall
submit a monthly operating report to the Agency, on forms provided or approved
by the Agency.
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BOARD NOTE: This is an additional State requirement.
(Source: Amended at 20 Ill. Reg. ________, effective ______________________)
Section 611.840
Reporting
a)
Except where a shorter period is specified in this Part, a
supplier shall report to the Agency the results of any test
measurement or analysis required by this Part within the following
times, whichever is shortest:
1)
The first ten days following the month in which the result
is received; or
2)
The first ten days following the end of the required
monitoring period, as specified by special exception permit.
b)
Except where a different reporting period is specified in this
Part, the supplier shall report to the Agency within 48 hours:
Theany failure to comply with any provision (including failure to
comply with monitoring requirements) inof this Part.
c)
The supplier is not required to report analytical results to the
Agency in cases where an Agency laboratory performs the analysis.
d)
The supplier, within ten days of completion of each public
notification required pursuant to Section 611.851 et seq., shall
submit to the Agency a representative copy of each type of notice
distributed, published, posted or made available to the persons
served by the supplier or to the media.
e)
The supplier shall submit to the Agency within the time stated in
the request copies of any records required to be maintained under
Section 611.860 or copies of any documents then in existence which
the Agency is entitled to inspect pursuant to the authority of
Section 4 of the Act.
BOARD NOTE: Derived from 40 CFR 141.31 (1989), as amended at 54
Fed. Reg. 27562, June 29, 1989.
(Source: Amended at 20 Ill. Reg. ________, effective ______________________)
Section 611.851
Reporting MCL and other Violations
A supplier that fails to comply with an applicable MCL or treatment technique
established by this Part or which fails to comply with the requirements of any
schedule prescribed pursuant to a variance or adjusted standard shall notify
persons served by the PWS as follows:
a)
Except as provided in subsection (c), the supplier shall give
notice:
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1)
By publication in a daily newspaper of general circulation
in the area served by the PWS as soon as possible, but in no
case later than 14 days after the violation or failure. If
the area served by a PWS is not served by a daily newspaper
of general circulation, notice must instead be given by
publication in a weekly newspaper of general circulation
serving the area; and
2)
By mail delivery (by direct mail or with the water bill), or
by hand delivery, not later than 45 days after the violation
or failure. This is not required if the Agency determines
by SEP that the supplier in violation has corrected the
violation or failure within the 45-day period; and
3)
For violations of the MCLs of contaminants that pose an
acute risk to human health, by furnishing a copy of the
notice to the radio and television stations serving the area
served by the PWS as soon as possible but in no case later
than 72 hours after the violation. The following violations
are acute violations:
A)
Any violations posing an acute risk to human health,
as specified in this Part or as determined by the
Agency on a case-by-case basis.
B)
Violation of the MCL for nitrate or nitrite in Section
611.301.
C)
Violation of the MCL for total coliforms, when fecal
coliforms or E. coli are present in the water
distribution system, as specified in Section
611.325(b).
D)
Occurrence of a waterborne disease outbreak.
b)
Except as provided in subsection (c), following the initial notice
given under subsection (a), the supplier shall give notice at
least once every three months by mail delivery (by direct mail or
with the water bill) or by hand delivery, for as long as the
violation or failure exists.
c)
Alternative methods of notice.
1)
In lieu of the requirements of subsections (a) and (b), a
CWS supplier in an area that is not served by a daily or
weekly newspaper of general circulation shall give notice by
hand delivery or by continuous posting in conspicuous places
within the area served by the CWS. Notice by hand delivery
or posting must begin as soon as possible, but no later than
72 hours after the violation or failure for acute violations
123
(as defined in subsection (a)(3)) or 14 days after the
violation or failure (for any other violation). Posting
must continue for as long as the violation or failure
exists. Notice by hand delivery must be repeated at least
every three months for as long as the violation or failure
exists.
2)
In lieu of the requirements of subsections (a) and (b), a
non-CWS supplier may give notice by hand delivery or by
continuous posting in conspicuous places within the area
served by the non-CWS. Notice by hand delivery or posting
must begin as soon as possible, but no later than 72 hours
after the violation or failure for acute violations (as
defined in subsection (a)(3)), or 14 days after the
violation or failure (for any other violation). Posting
must continue for as long as the violation or failure
exists. Notice by hand delivery must be repeated at least
every three months for as long as the violation or failure
exists.
3)
Where allowed, pursuant to Section 611.609(d),
611.646(o)(3), 611.647(i), or 611.648(k)(3) because it has a
separable system, a supplier may issue public notice only to
persons on that portion of its system that its out of
compliance.
BOARD NOTE: Generally derived from 40 CFR 141.32(a) (1993).
Subsection (c)(3) derived from 40 CFR 141.23(i)(4) &
141.24(f)(15)(iii), (g)(9) & (h)(11)(iii) (1993).
(Source: Amended at 20 Ill. Reg. ________, effective ______________________)
Section 611.852
Reporting other Violations
A supplier that fails to perform monitoring required by this Part, which fails
to comply with a testing procedure established by this Part, or which is
subject to a variance or adjusted standard under Section 611.111, 611.112 or
611.113 shall notify persons served by the PWS as follows:
a)
Except as provided in subsection (c) or (d), the supplier shall
give notice, within three months of the violation or granting of a
variance or adjusted standard, by publication in a daily newspaper
of general circulation in the area served by the PWS. If the area
served by a PWS is not served by a daily newspaper of general
circulation, notice must instead be given by publication in a
weekly newspaper of general circulation serving the area.
b)
Except as provided in subsection (c) or (d), following the initial
notice given under subsection (a), the supplier shall give notice
at least once every three months by mail delivery (by direct mail
or with the water bill) or by hand delivery, for as long as the
124
violation exists. Repeat notice of the existence of a variance or
adjusted standard (Section 611.111 through 611.113) must be given
every three months for as long as the variance or adjusted
standard remains in effect.
c)
Alternative methods of notice.
1)
In lieu of the requirements of subsections (a) and (b), a
CWS supplier in an area that is not served by a daily or
weekly newspaper of general circulation shall give notice,
within three months of the violation or granting of the
variance or adjusted standard, by hand delivery or by
continuous posting in conspicuous places within the area
served by the CWS. Posting must continue for as long as the
violation exists or a variance or adjusted standard remains
in effect. The CWS supplier shall repeat the notice by hand
delivery every three months for as long as the variance or
adjusted standard remains in effect.
2)
In lieu of the requirements of subsections (a) and (b), a
non-CWS supplier may give notice, within three months of the
violation or the granting of the variance or adjusted
standard, by hand delivery or by continuous posting in
conspicuous places within the area served by the non-CWS.
Posting must continue for as long as the violation exists,
or a variance or adjusted standard remains in effect.
Notice by hand delivery must be repeated at least every
three months for as long as the violation exists or a
variance or adjusted standard remains in effect.
BOARD NOTE: Derived from 40 CFR 141.32(b) (19915).
(Source: Amended at 20 Ill. Reg. ________, effective ______________________)
Section 611.858
Fluoride Secondary Standard
If a CWS exceeds the secondary standard for fluoride of 2.0 mg/L, as
determined by the last single sample taken in accordance with Section
611.6073, but does not exceed the MCL in Section 611.3001(b), the supplier
shall provide the fluoride notice in Section 611.Appendix A(9) to:
a)
All billing units annually;
b)
All billing units at the time service begins; and
c)
The local public health department.
BOARD NOTE: Derived from 40 CFR 143.3 and 143.5 (1994).
(Source: Amended at 20 Ill. Reg. ________, effective ______________________)
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Section 611.870
List of 36 Contaminants (Repealed)
a) This Section applies to only the contaminants listed in Section
611.650.
b) A CWS or NTNCWS supplier who is required to monitor under Section
611.650 shall send a copy of the results of such monitoring within
30 days of receipt and any public notice under subsection (d) to
the Agency or, for non-CWSs, Public Health.
c) See Section 611.100(e).
d) The supplier shall notify persons served by the PWS of the
availability of the results of sampling conducted under Section
611.650 by including a notice in the first set of water bills
issued by the supplier after the receipt of the results or written
notice within three months. The notice must identify a person and
supply the telephone number to contact for information on the
monitoring results. For surface water systems, public
notification is required only after the first quarter's monitoring
and must include a statement that additional monitoring will be
conducted for three more quarters with the results available upon
request.
BOARD NOTE: Derived from 40 CFR 141.35 (1989).
(Source: Repealed at 20 Ill. Reg. ________, effective ______________________)
Section 611.Appendix A Mandatory Health Effects Information
1)
Trichloroethylene. The United States Environmental Protection
Agency (U.S. EPA) sets drinking water standards and has determined
that trichloroethylene is a health concern at certain levels of
exposure. This chemical is a common metal cleaning and dry
cleaning fluid. It generally gets into drinking water by improper
waste disposal. This chemical has been shown to cause cancer in
laboratory animals such as rats and mice when the animals are
exposed at high levels over their lifetimes. Chemicals that cause
cancer in laboratory animals also may increase the risk of cancer
in humans who are exposed at lower levels over long periods of
time. U.S. EPA has set forth the enforceable drinking water
standard for trichloroethylene at 0.005 parts per million (ppm) to
reduce the risk of cancer or other adverse health effects which
have been observed in laboratory animals. Drinking water which
meets this standard is associated with little to none of this risk
and should be considered safe.
2)
Carbon tetrachloride. The United States Environmental Protection
Agency (U.S. EPA) sets drinking water standards and has determined
that carbon tetrachloride is a health concern at certain levels of
126
exposure. This chemical was once a popular household cleaning
fluid. It generally gets into drinking water by improper waste
disposal. This chemical has been shown to cause cancer in
laboratory animals such as rats and mice when the animals are
exposed at high levels over their lifetimes. Chemicals that cause
cancer in laboratory animals also may increase the risk of cancer
in humans who are exposed at lower levels over long periods of
time. U.S. EPA has set the enforceable drinking water standard
for carbon tetrachloride at 0.005 parts per million (ppm) to
reduce the risk of cancer or other adverse health effects which
have been observed in laboratory animals. Drinking water which
meets this standard is associated with little to none of this risk
and should be considered safe.
3)
1,2-Dichloroethane. The United States Environmental Protection
Agency (U.S. EPA) sets drinking water standards and has determined
that 1,2-dichloroethane is a health concern at certain levels of
exposure. This chemical is used as a cleaning fluid for fats,
oils, waxes and resins. It generally gets into drinking water by
improper waste disposal. This chemical has been shown to cause
cancer in laboratory animals such as rats and mice when the
animals are exposed at high levels over their lifetimes.
Chemicals that cause cancer in laboratory animals also may
increase the risk of cancer in humans who are exposed at lower
levels over long periods of time. U.S. EPA has set the
enforceable drinking water standard for 1,2-dichloroethane at
0.005 parts per million (ppm) to reduce the risk of cancer or
other adverse health effects which have been observed in
laboratory animals. Drinking water which meets this standard is
associated with little to none of this risk and should be
considered safe.
4)
Vinyl chloride. The United States Environmental Protection Agency
(U.S. EPA) sets drinking water standards and has determined that
vinyl chloride is a health concern at certain levels of exposure.
This chemical is used in industry and is found in drinking water
as a result of the breakdown of related solvents. The solvents
are used as cleaners and degreasers of metals and generally get
into drinking water by improper waste disposal. This chemical has
been associated with significantly increased risks of cancer among
certain industrial workers who were exposed to relatively large
amounts of this chemical during their working careers. This
chemical has also been shown to cause cancer in laboratory animals
when the animals are exposed at high levels over their lifetimes.
Chemicals that cause increased risk of cancer among exposed
industrial workers and in laboratory animals also may increase the
risk of cancer in humans who are exposed at lower levels over long
periods of time. U.S. EPA has set the enforceable drinking water
standard for vinyl chloride at 0.002 parts per million (ppm) to
reduce the risk of cancer or other adverse health effects which
have been observed in laboratory animals. Drinking water which
127
meets this standard is associated with little to none of this risk
and should be considered safe.
5)
Benzene. The United States Environmental Protection Agency (U.S.
EPA) sets drinking water standards and has determined that benzene
is a health concern at certain levels of exposure. This chemical
is used as a solvent and degreaser of metals. It is also a major
component of gasoline. Drinking water contamination generally
results from leaking underground gasoline and petroleum tanks or
improper waste disposal. This chemical has been associated with
significantly increased risks of leukemia among certain industrial
workers who were exposed to relatively large amounts of this
chemical during their working careers. This chemical has been
shown to cause cancer in laboratory animals when the animals are
exposed at high levels over their lifetimes. Chemicals that cause
increased risk of cancer among exposed industrial workers and in
laboratory animals also may increase the risk of cancer in humans
who are exposed at lower levels over long periods of time. U.S.
EPA has set the enforceable drinking water standard for benzene at
0.005 parts per million (ppm) to reduce the risk of cancer or
other adverse health effects which have been observed in humans
and laboratory animals. Drinking water which meets this standard
is associated with little to none of this risk and should be
considered safe.
6)
1,1-Dichloroethylene. The United States Environmental Protection
Agency (U.S. EPA) sets drinking water standards and has determined
that 1,1-dichloroethylene is a health concern at certain levels of
exposure. This chemical is used in industry and is found in
drinking water as a result of the breakdown of related solvents.
The solvents are used as cleaners and degreasers of metals and
generally get into drinking water by improper waste disposal.
This chemical has been shown to cause liver and kidney damage in
laboratory animals such as rats and mice when the animals are
exposed at high levels over their lifetimes. Chemicals that cause
adverse effects in laboratory animals also may cause adverse
health effects in humans who are exposed at lower levels over long
periods of time. U.S. EPA has set the enforceable drinking water
standard for 1,1-dichloroethylene at 0.007 parts per million (ppm)
to reduce the risk of these adverse health effects which have been
observed in laboratory animals. Drinking water which meets this
standard is associated with little to none of this risk and should
be considered safe.
7)
Para-dichlorobenzene. The United States Environmental Protection
Agency (U.S. EPA) sets drinking water standards and has determined
that para-dichlorobenzene is a health concern at certain levels of
exposure. This chemical is a component of deodorizers, moth balls
and pesticides. It generally gets into drinking water by improper
waste disposal. This chemical has been shown to cause liver and
kidney damage in laboratory animals such as rats and mice when the
128
animals are exposed at high levels over their lifetimes.
Chemicals which cause adverse effects in laboratory animals also
may cause adverse health effects in humans who are exposed at
lower levels over long periods of time. U.S. EPA has set the
enforceable drinking water standard for para-dichlorobenzene at
0.075 parts per million (ppm) to reduce the risk of these adverse
health effects which have been observed in laboratory animals.
Drinking water which meets this standard is associated with little
to none of this risk and should be considered safe.
8)
1,1,1-Trichloroethane. The United States Environmental Protection
Agency (U.S. EPA) sets drinking water standards and has determined
that 1,1,1-trichloroethane is a health concern at certain levels
of exposure. This chemical is used as a cleaner and degreaser of
metals. It generally gets into drinking water by improper waste
disposal. This chemical has been shown to damage the liver,
nervous system and circulatory system of laboratory animals such
as rats and mice when the animals are exposed at high levels over
their lifetimes. Some industrial workers who were exposed to
relatively large amounts of this chemical during their working
careers also suffered damage to the liver, nervous system and
circulatory system. Chemicals which cause adverse effects among
exposed industrial workers and in laboratory animals also may
cause adverse health effects in humans who are exposed at lower
levels over long periods of time. U.S. EPA has set the
enforceable drinking water standard for 1,1,1-trichloroethane at
0.2 parts per million (ppm) to protect against the risk of these
adverse health effects which have been observed in laboratory
animals. Drinking water which meets this standard is associated
with little to none of this risk and should be considered safe.
9)
Fluoride. The U.S. Environmental Protection Agency requires that
we send you this notice on the level of fluoride in your drinking
water. The drinking water in your community has a fluoride
concentration of [concentration to be provided by supplier]
milligrams per liter (mg/L).
Federal regulations require that fluoride, which occurs naturally
in your water supply, not exceed a concentration of 4.0 mg/L in
drinking water. This is an enforceable standard called a Maximum
Contaminant Level (MCL), and it has been established to protect
the public health. Exposure to drinking water levels above 4.0
mg/L for many years may result in some cases of crippling skeletal
fluorosis, which is a serious bone disorder.
Federal law also requires that we notify you when monitoring
indicates that the fluoride in your drinking water exceeds 2.0
mg/L. This is intended to alert families about dental problems
that might affect children under nine years of age. The fluoride
concentration of your water exceeds this federal guideline.
129
Fluoride in children's drinking water at levels of approximately 1
mg/L reduces the number of dental cavities. However, some
children exposed to levels of fluoride greater than about 2.0 mg/L
may develop dental fluorosis. Dental fluorosis, in its moderate
and severe forms, is a brown staining and/or pitting of the
permanent teeth.
Because dental fluorosis occurs only when developing teeth (before
they erupt from the gums) are exposed to elevated fluoride levels,
households without children are not expected to be affected by
this level of fluoride. Families with children under the age of
nine are encouraged to seek other sources of drinking water for
their children to avoid the possibility of staining and pitting.
Your water supplier can lower the concentration of fluoride in
your water so that you will still receive the benefits of cavity
prevention while the possibility of stained and pitted teeth is
minimized. Removal of fluoride may increase your water costs.
Treatment systems are also commercially available for home use.
Information on such systems is available at the address given
below. Low fluoride bottled drinking water that would meet all
standards is also commercially available.
For further information, contact [name of contact person to be
provided by supplier] at your water system.
BOARD NOTE: Derived from 40 CFR 141.32(e)(9) and 143.5 (19945).
10)
Microbiological contaminants (for use when there is a violation of
the treatment technique requirements for filtration and
disinfection in Subpart B of this Part). The United States
Environmental Protection Agency (U.S. EPA) sets drinking water
standards and has determined that the presence of microbiological
contaminants are a health concern at certain levels of exposure.
If water is inadequately treated, microbiological contaminants in
that water may cause disease. Disease symptoms may include
diarrhea, cramps, nausea and possibly jaundice and any associated
headaches and fatigue. These symptoms, however, are not just
associated with disease-causing organisms in drinking water, but
also may be caused by a number of factors other than your drinking
water. U.S. EPA has set enforceable requirements for treating
drinking water to reduce the risk of these adverse health effects.
Treatment such as filtering and disinfecting the water removes or
destroys microbiological contaminants. Drinking water which is
treated to meet U.S. EPA requirements is associated with little to
none of this risk and should be considered safe.
11)
Total coliforms. (To be used when there is a violation of Section
611.325(a) and not a violation of Section 611.325(b)). The United
States Environmental Protection Agency (U.S. EPA) sets drinking
water standards and has determined that the presence of total
130
coliforms is a possible health concern. Total coliforms are
common in the environment and are generally not harmful
themselves. The presence of these bacteria in drinking water,
however, generally is a result of a problem with water treatment
or the pipes which distribute the water and indicates that the
water may be contaminated with organisms that can cause disease.
Disease symptoms may include diarrhea, cramps, nausea and possibly
jaundice, and any associated headaches and fatigue. These
symptoms, however, are not just associated with disease-causing
organisms in drinking water, but also may be caused by a number of
factors other than your drinking water. U.S. EPA has set an
enforceable drinking water standard for total coliforms to reduce
the risk of these adverse health effects. Under this standard, no
more than 5.0 percent of the samples collected during a month can
contain these bacteria, except that systems collecting fewer than
40 samples/month that have one total coliform-positive sample per
month are not violating the standard. Drinking water which meets
this standard is usually not associated with a health risk from
disease-causing bacteria and should be considered safe.
12)
Fecal Coliforms/E. coli. (To be used when there is a violation of
Section 611.325(b) or both Section 611.325(a) and (b).) The
United States Environmental Protection Agency (U.S. EPA) sets
drinking water standards and has determined that the presence of
fecal coliforms or E. coli is a serious health concern. Fecal
coliforms and E. coli are generally not harmful themselves, but
their presence in drinking water is serious because they usually
are associated with sewage or animal wastes. The presence of
these bacteria in drinking water is generally a result of a
problem with water treatment or the pipes which distribute the
water and indicates that the water may be contaminated with
organisms that can cause disease. Disease symptoms may include
diarrhea, cramps, nausea and possibly jaundice, and associated
headaches and fatigue. These symptoms, however, are not just
associated with disease-causing organisms in drinking water, but
also may be caused by a number of factors other than your drinking
water. U.S. EPA has set an enforceable drinking water standard
for fecal coliforms and E. coli to reduce the risk of these
adverse health effects. Under this standard all drinking water
samples must be free of these bacteria. Drinking water which
meets this standard is associated with little or none of this risk
and should be considered safe. State and local health authorities
recommend that consumers take the following precautions: [To be
inserted by the public water system, according to instruction from
State or local authorities].
13)
Lead. The United States Environmental Protection Agency (U.S.
EPA) sets drinking water standards and has determined that lead is
a health concern at certain exposure levels. Materials that
contain lead have frequently been used in the construction of
water supply distribution systems, and plumbing systems in private
131
homes and other buildings. The most commonly found materials
include service lines, pipes, brass and bronze fixtures, and
solders and fluxes. Lead in these materials can contaminate
drinking water as a result of the corrosion that takes place when
water comes into contact with those materials. Lead can cause a
variety of adverse health effects in humans. At relatively low
levels of exposure, these effects may include interference with
red blood cell chemistry, delays in normal physical and mental
development in babies and young children, slight deficits in the
attention span, hearing, and learning abilities of children, and
slight increases in the blood pressure of some adults. U.S. EPA's
national primary drinking water regulation requires all public
water systems to optimize corrosion control to minimize lead
contamination resulting from the corrosion of plumbing materials.
Public water systems serving 50,000 people or fewer that have
lead concentrations below 15 parts per billion (ppb) in more than
90% of tap water samples (the U.S. EPA "action level") have
optimized their corrosion control treatment. Any water system
that exceeds the action level must also monitor their source water
to determine whether treatment to remove lead in source water is
needed. Any water system that continues to exceed the action
level after installation of corrosion control and/or source water
treatment must eventually replace all lead service lines
contributing in excess of 15 ppb of lead to drinking water. Any
water system that exceeds the action level must also undertake a
public education program to inform consumers of ways they can
reduce their exposure to potentially high levels of lead in
drinking water.
14)
Copper. The United States Environmental Protection Agency (U.S.
EPA) sets drinking water standards and has determined that copper
is a health concern at certain exposure levels. Copper, a
reddish-brown metal, is often used to plumb residential and
commercial structures that are connected to water distribution
systems. Copper contaminating drinking water as a corrosion by-
product occurs as the result of the corrosion of copper pipes that
remain in contact with water for a prolonged period of time.
Copper is an essential nutrient, but at high doses it has been
shown to cause stomach and intestinal distress, liver and kidney
damage, and anemia. Persons with Wilson's disease may be at a
higher risk of health effects due to copper than the general
public. U.S. EPA's national primary drinking water regulation
requires all public water systems to install optimal corrosion
control to minimize copper contamination resulting from the
corrosion of plumbing materials. Public water systems serving
50,000 people or fewer that have copper concentrations below 1.3
parts per million (ppm) in more than 90% of tap water samples (the
U.S. EPA "action level") are not required to install or improve
their treatment. Any water system that exceeds the action level
must also monitor their source water to determine whether
treatment to remove copper in source water is needed.
132
15)
Asbestos. The United States Environmental Protection Agency (U.S.
EPA) sets drinking water standards and has determined that
asbestos fibers greater than 10 micrometers in length are a health
concern at certain levels of exposure. Asbestos is a naturally
occurring mineral. Most asbestos fibers in drinking water are
less than 10 micrometers in length and occur in drinking water
from natural sources and from corroded asbestos-cement pipes in
the distribution system. The major uses of asbestos were in the
production of cements, floor tiles, paper products, paint, and
caulking; in transportation-related applications; and in the
production of textiles and plastics. Asbestos was once a popular
insulating and fire retardant material. Inhalation studies have
shown that various forms of asbestos have produced lung tumors in
laboratory animals. The available information on the risk of
developing gastrointestinal tract cancer associated with the
ingestion of asbestos from drinking water is limited. Ingestion
of intermediate-range chrysolite asbestos fibers greater than 10
micrometers in length is associated with causing benign tumors in
male rats. Chemicals that cause cancer in laboratory animals also
may increase the risk of cancer in humans who are exposed over
long periods of time. U.S. EPA has set the drinking water
standard for asbestos at 7 million long fibers per liter to reduce
the potential risk of cancer or other adverse health effects which
have been observed in laboratory animals. Drinking water which
meets the U.S. EPA standard is associated with little to none of
this risk and should be considered safe with respect to asbestos.
16)
Barium. The United States Environmental Protection Agency (U.S.
EPA) sets drinking water standards and has determined that barium
is a health concern at certain levels of exposure. This inorganic
chemical occurs naturally in some aquifers that serve as sources
of groundwater. It is also used in oil and gas drilling muds,
automotive paints, bricks, tiles, and jet fuels. It generally
gets into drinking water after dissolving from naturally occurring
minerals in the ground. This chemical may damage the heart and
vascular system, and is associated with high blood pressure in
laboratory animals such as rats exposed to high levels during
their lifetimes. In humans, U.S. EPA believes that effects from
barium on blood pressure should not occur below 2 parts per
million (ppm) in drinking water. U.S. EPA has set the drinking
water standard for barium at 2 parts per million (ppm) to protect
against the risk of these adverse health effects. Drinking water
that meets the U.S. EPA standard is associated with little to none
of this risk and is considered safe with respect to barium.
17)
Cadmium. The United States Environmental Protection Agency (U.S.
EPA) sets drinking water standards and has determined that cadmium
is a health concern at certain levels of exposure. Food and the
smoking of tobacco are common sources of general exposure. This
inorganic metal is a contaminant in the metals used to galvanize
133
pipe. It generally gets into water by corrosion of galvanized
pipes or by improper waste disposal. This chemical has been shown
to damage the kidney in animals such as rats and mice when the
animals are exposed at high levels over their lifetimes. Some
industrial workers who were exposed to relatively large amounts of
this chemical during working careers also suffered damage to the
kidney. U.S. EPA has set the drinking water standard for cadmium
at 0.005 parts per million (ppm) to protect against the risk of
these adverse health effects. Drinking water that meets the U.S.
EPA standard is associated with little to none of this risk and is
considered safe with respect to cadmium.
18)
Chromium. The United States Environmental Protection Agency (U.S.
EPA) sets drinking water standards and has determined that
chromium is a health concern at certain levels of exposure. This
inorganic metal occurs naturally in the ground and is often used
in the electroplating of metals. It generally gets into water
from runoff from old mining operations and improper waste disposal
from plating operations. This chemical has been shown to damage
the kidney, nervous system, and the circulatory system of
laboratory animals such as rats and mice when the animals are
exposed at high levels. Some humans who were exposed to high
levels of this chemical suffered liver and kidney damage,
dermatitis and respiratory problems. U.S. EPA has set the
drinking water standard for chromium at 0.1 parts per million
(ppm) to protect against the risk of these adverse health effects.
Drinking water that meets the U.S. EPA standard is associated
with little to none of this risk and is considered safe with
respect to chromium.
19)
Mercury. The United States Environmental Protection Agency (U.S.
EPA) sets drinking water standards and has determined that mercury
is a health concern at certain levels of exposure. This inorganic
metal is used in electrical equipment and some water pumps. It
usually gets into water as a result of improper waste disposal.
This chemical has been shown to damage the kidney of laboratory
animals such as rats when the animals are exposed at high levels
over their lifetimes. U.S. EPA has set the drinking water
standard for mercury at 0.002 parts per million (ppm) to protect
against the risk of these adverse health effects. Drinking water
that meets the U.S. EPA standard is associated with little to none
of this risk and is considered safe with respect to mercury.
20)
Nitrate. The United States Environmental Protection Agency (U.S.
EPA) sets drinking water standards and has determined that nitrate
poses an acute health concern at certain levels of exposure.
Nitrate is used in fertilizer and is found in sewage and wastes
from human and/or farm animals and generally gets into drinking
water from those activities. Excessive levels of nitrate in
drinking water have caused serious illness and sometimes death in
infants under six months of age. The serious illness in infants
134
is caused because nitrate is converted to nitrite in the body.
Nitrite interferes with the oxygen carrying capacity of the
child's blood. This is an acute disease in that symptoms can
develop rapidly in infants. In most cases, health deteriorates
over a period of days. Symptoms include shortness of breath and
blueness of the skin. Clearly, expert medical advice should be
sought immediately if these symptoms occur. The purpose of this
notice is to encourage parents and other responsible parties to
provide infants with an alternate source of drinking water. Local
and State health authorities are the best source for information
concerning alternate sources of drinking water for infants. U.S.
EPA has set the drinking water standard at 10 parts per million
(ppm) for nitrate to protect against the risk of these adverse
effects. U.S. EPA has also set a drinking water standard for
nitrite at 1 ppm. To allow for the fact that the toxicity of
nitrate and nitrite are additive. , U.S. EPA has also established
a standard for the sum of nitrate and nitrite at 10 ppm. Drinking
water that meets the U.S. EPA standard is associated with little
to none of this risk and is considered safe with respect to
nitrate.
21)
Nitrite. The United States Environmental Protection Agency (U.S.
EPA) sets drinking water standards and has determined that nitrite
poses an acute health concern at certain levels of exposure. This
inorganic chemical is used in fertilizers and is found in sewage
and wastes from humans and/or farm animals and generally gets into
drinking water as a result of those activities. While excessive
levels of nitrite in drinking water have not been observed, other
sources of nitrite have caused serious illness and sometimes death
in infants under six months of age. The serious illness in
infants is caused because nitrite interferes with the oxygen
carrying capacity of the child's blood. This is an acute disease
in that symptoms can develop rapidly. However, in most cases,
health deteriorates over a period of days. Symptoms include
shortness of breath and blueness of the skin. Clearly, expert
medical advice should be sought immediately if these symptoms
occur. The purpose of this notice is to encourage parents and
other responsible parties to provide infants with an alternate
source of drinking water. Local and State health authorities are
the best source for information concerning alternate sources of
drinking water for infants. U.S. EPA has set the drinking water
standard at 1 part per million (ppm) for nitrite to protect
against the risk of these adverse effects. U.S. EPA has also set
a drinking water standard for nitrate (converted to nitrite in
humans) at 10 ppm and for the sum of nitrate and nitrite at 10
ppm. Drinking water that meets the U.S. EPA standard is
associated with little to none of this risk and is considered safe
with respect to nitrite.
22)
Selenium. The United States Environmental Protection Agency (U.S.
EPA) sets drinking water standards and has determined that
135
selenium is a health concern at certain high levels of exposure.
Selenium is also an essential nutrient at low levels of exposure.
This inorganic chemical is found naturally in food and soils and
is used in electronics, photocopy operations, the manufacture of
glass, chemicals, drugs, and as a fungicide and a feed additive.
In humans, exposure to high levels of selenium over a long period
of time has resulted in a number of adverse health effects,
including a loss of feeling and control in the arms and legs.
U.S. EPA has set the drinking water standard for selenium at 0.05
parts per million (ppm) to protect against the risk of these
adverse health effects. Drinking water that meets the U.S. EPA
standard is associated with little to none of this risk and is
considered safe with respect to selenium.
23)
Acrylamide. The United States Environmental Protection Agency
(U.S. EPA) sets drinking water standards and has determined that
acrylamide is a health concern at certain levels of exposure.
Polymers made from acrylamide are sometimes used to treat water
supplies to remove particulate contaminants. Acrylamide has been
shown to cause cancer in laboratory animals such as rats and mice
when the animals are exposed at high levels over their lifetimes.
Chemicals that cause cancer in laboratory animals also may
increase the risk of cancer in humans who are exposed over long
periods of time. Sufficiently large doses of acrylamide are known
to cause neurological injury. U.S. EPA has set the drinking water
standard for acrylamide using a treatment technique to reduce the
risk of cancer or other adverse health effects which have been
observed in laboratory animals. This treatment technique limits
the amount of acrylamide in the polymer and the amount of the
polymer which may be added to drinking water to remove
particulates. Drinking water systems which comply with this
treatment technique have little to no risk and are considered safe
with respect to acrylamide.
24)
Alachlor. The United States Environmental Protection Agency (U.S.
EPA) sets drinking water standards and has determined that
alachlor is a health concern at certain levels of exposure. This
organic chemical is a widely used pesticide. When soil and
climatic conditions are favorable, alachlor may get into drinking
water by runoff into surface water or by leaching into
groundwater. This chemical has been shown to cause cancer in
laboratory animals such as rats and mice when the animals are
exposed at high levels over their lifetimes. Chemicals that cause
cancer in laboratory animals also may increase the risk of cancer
in humans who are exposed over long periods of time. U.S. EPA has
set the drinking water standard for alachlor at 0.002 parts per
million (ppm) to reduce the risk of cancer or other adverse health
effects which have been observed in laboratory animals. Drinking
water that meets this standard is associated with little to none
of this risk and is considered safe with respect to alachlor.
136
25)
Aldicarb. The United States Environmental Protection Agency (U.S.
EPA) sets drinking water standards and has determined that
aldicarb is a health concern at certain levels of exposure.
Aldicarb is a widely used pesticide. Under certain soil and
climatic conditions (e.g., sandy soil and high rainfall), aldicarb
may leach into groundwater after normal agricultural applications
to crops such as potatoes or peanuts or may enter drinking water
supplies as a result of surface runoff. This chemical has been
shown to damage the nervous system in laboratory animals such as
rats and dogs exposed to high levels. U.S. EPA has set the
drinking water standard for aldicarb at 0.003 parts per million
(ppm) to reduce the risk of adverse health effects. Drinking
water that meets this standard is associated with little to none
of this risk and is considered safe with respect to aldicarb.
26)
Aldicarb sulfoxide. The United States Environmental Protection
Agency (U.S. EPA) sets drinking water standards and has determined
that aldicarb sulfoxide is a health concern at certain levels of
exposure. Aldicarb is a widely used pesticide. Aldicarb
sulfoxide in groundwater is primarily a breakdown product of
aldicarb. Under certain soil and climatic conditions (e.g., sandy
soil and high rainfall), aldicarb sulfoxide may leach into
groundwater after normal agricultural applications to crops such
as potatoes or peanuts or may enter drinking water supplies as a
result of surface runoff. This chemical has been shown to damage
the nervous system in laboratory animals such as rats and dogs
exposed to high levels. U.S. EPA has set the drinking water
standard for aldicarb sulfoxide at 0.004 parts per million (ppm)
to reduce the risk of adverse health effects. Drinking water that
meets this standard is associated with little to none of this risk
and is considered safe with respect to aldicarb sulfoxide.
27)
Aldicarb sulfone. The United States Environmental Protection
Agency (U.S. EPA) sets drinking water standards and has determined
that aldicarb sulfone is a health concern at certain levels of
exposure. Aldicarb is a widely used pesticide. Aldicarb sulfone
in groundwater is primarily a breakdown product of aldicarb.
Under certain soil and climatic conditions (e.g., sandy soil and
high rainfall), aldicarb sulfone may leach into groundwater after
normal agricultural applications to crops such as potatoes or
peanuts or may enter drinking water supplies as a result of
surface runoff. This chemical has been shown to damage the
nervous system in laboratory animals such as rats and dogs exposed
to high levels. U.S. EPA has set the drinking water standard for
aldicarb sulfone at 0.002 parts per million (ppm) to reduce the
risk of adverse health effects. Drinking water that meets this
standard is associated with little to none of this risk and is
considered safe with respect to aldicarb sulfone.
28)
Atrazine. The United States Environmental Protection Agency (U.S.
EPA) sets drinking water standards and has determined that
137
atrazine is a health concern at certain levels of exposure. This
organic chemical is a herbicide. When soil and climatic
conditions are favorable, atrazine may get into drinking water by
runoff into surface water or by leaching into groundwater. This
chemical has been shown to affect offspring of rats and the hearts
of dogs. U.S. EPA has set the drinking water standard for
atrazine at 0.003 parts per million (ppm) to protect against the
risk of these adverse health effects. Drinking water that meets
the U.S. EPA standard is associated with little to none of this
risk and is considered safe with respect to atrazine.
29)
Carbofuran. The United States Environmental Protection Agency
(U.S. EPA) sets drinking water standards and has determined that
carbofuran is a health concern at certain levels of exposure.
This organic chemical is a pesticide. When soil and climatic
conditions are favorable, carbofuran may get into drinking water
by runoff into surface water or by leaching into groundwater.
This chemical has been shown to damage the nervous and
reproductive systems of laboratory animals such as rats and mice
exposed at high levels over their lifetimes. Some humans who were
exposed to relatively large amounts of this chemical during their
working careers also suffered damage to the nervous system.
Effects on the nervous system are generally rapidly reversible.
U.S. EPA has set the drinking water standard for carbofuran at
0.04 parts per million (ppm) to protect against the risk of these
adverse health effects. Drinking water that meets the U.S. EPA
standard is associated with little to none of this risk and is
considered safe with respect to carbofuran.
30)
Chlordane. The United States Environmental Protection Agency
(U.S. EPA) sets drinking water standards and has determined that
chlordane is a health concern at certain levels of exposure. This
organic chemical is a pesticide used to control termites.
Chlordane is not very mobile in soils. It usually gets into
drinking water after application near water supply intakes or
wells. This chemical has been shown to cause cancer in laboratory
animals such as rats and mice when the animals are exposed at high
levels over their lifetimes. Chemicals that cause cancer in
laboratory animals also may increase the risk of cancer in humans
who are exposed over long periods of time. U.S. EPA has set the
drinking water standard for chlordane at 0.002 parts per million
(ppm) to reduce the risk of cancer or other adverse health effects
which have been observed in laboratory animals. Drinking water
that meets the U.S. EPA standard is associated with little to none
of this risk and is considered safe with respect to chlordane.
31)
Dibromochloropropane (DBCP). The United States Environmental
Protection Agency (U.S. EPA) sets drinking water standards and has
determined that DBCP is a health concern at certain levels of
exposure. This organic chemical was once a popular pesticide.
When soil and climatic conditions are favorable, DBCP may get into
138
drinking water by runoff into surface water or by leaching into
groundwater. This chemical has been shown to cause cancer in
laboratory animals such as rats and mice when the animals are
exposed at high levels over their lifetimes. Chemicals that cause
cancer in laboratory animals also may increase the risk of cancer
in humans who are exposed over long periods of time. U.S. EPA has
set the drinking water standard for DBCP at 0.0002 parts per
million (ppm) to reduce the risk of cancer or other adverse health
effects which have been observed in laboratory animals. Drinking
water that meets the U.S. EPA standard is associated with little
to none of this risk and is considered safe with respect to DBCP.
32)
o-Dichlorobenzene. The United States Environmental Protection
Agency (U.S. EPA) sets drinking water standards and has determined
that o-dichlorobenzene is a health concern at certain levels of
exposure. This organic chemical is used as a solvent in the
production of pesticides and dyes. It generally gets into water
by improper waste disposal. This chemical has been shown to
damage the liver, kidney and the blood cells of laboratory animals
such as rats and mice exposed to high levels during their
lifetimes. Some industrial workers who were exposed to relatively
large amounts of this chemical during working careers also
suffered damage to the liver, nervous system, and circulatory
system. U.S. EPA has set the drinking water standard for
o-dichlorobenzene at 0.6 parts per million (ppm) to protect
against the risk of these adverse health effects. Drinking water
that meets the U.S. EPA standard is associated with little to none
of this risk and is considered safe with respect to
o-dichlorobenzene.
33)
cis-1,2-Dichloroethylene. The United States Environmental
Protection Agency (U.S. EPA) establishes drinking water standards
and has determined that cis-1,2-dichloroethylene is a health
concern at certain levels of exposure. This organic chemical is
used as a solvent and intermediate in chemical production. It
generally gets into water by improper waste disposal. This
chemical has been shown to damage the liver, nervous system, and
circulatory system of laboratory animals such as rats and mice
when exposed at high levels over their lifetimes. Some humans who
were exposed to relatively large amounts of this chemical also
suffered damage to the nervous system. U.S. EPA has set the
drinking water standard for cis-1,2-dichloroethylene at 0.07 parts
per million (ppm) to protect against the risk of these adverse
health effects. Drinking water that meets the U.S. EPA standard
is associated with little to none of this risk and is considered
safe with respect to cis-1,2-dichloroethylene.
34)
trans-1,2-Dichloroethylene. The United States Environmental
Protection Agency (U.S. EPA) establishes drinking water standards
and has determined that trans-1,2-dichloroethylene is a health
concern at certain levels of exposure. This organic chemical is
139
used as a solvent and intermediate in chemical production. It
generally gets into water by improper waste disposal. This
chemical has been shown to damage the liver, nervous system, and
the circulatory system of laboratory animals such as rats and mice
when exposed at high levels over their lifetimes. Some humans who
were exposed to relatively large amounts of this chemical also
suffered damage to the nervous system. U.S. EPA has set the
drinking water standard for trans-1,2-dichloroethylene at 0.1
parts per million (ppm) to protect against the risk of these
adverse health effects. Drinking water that meets the U.S. EPA
standard is associated with little to none of this risk and is
considered safe with respect to trans-1,2-dichloroethylene.
35)
1,2-Dichloropropane. The United States Environmental Protection
Agency (U.S. EPA) sets drinking water standards and has determined
that 1,2-dichloropropane is a health concern at certain levels of
exposure. This organic chemical is used as a solvent and
pesticide. When soil and climatic conditions are favorable, 1,2-
dichloropropane may get into drinking water by runoff into surface
water or by leaching into groundwater. It may also get into
drinking water through improper waste disposal. This chemical has
been shown to cause cancer in laboratory animals such as rats and
mice when the animals are exposed at high levels over their
lifetimes. Chemicals that cause cancer in laboratory animals also
may increase the risk of cancer in humans who are exposed over
long periods of time. U.S. EPA has set the drinking water
standard for 1,2-dichloropropane at 0.005 parts per million (ppm)
to reduce the risk of cancer or other adverse health effects which
have been observed in laboratory animals. Drinking water that
meets the U.S. EPA standard is associated with little to none of
this risk and is considered safe with respect to
1,2-dichloropropane.
36)
2,4-D. This contaminant is subject to an "additional State
requirement". The supplier shall give the following notice if the
level exceeds the Section 611.311 MCL. If the level exceeds the
Section 611.310 MCL, but not that of Section 611.311, the supplier
shall give a general notice under Section 611.854.
The United States Environmental Protection Agency (U.S. EPA) sets
drinking water standards and has determined that 2,4-D is a health
concern at certain levels of exposure. This organic chemical is
used as a herbicide and to control algae in reservoirs. When soil
and climatic conditions are favorable, 2,4-D may get into drinking
water by runoff into surface water or by leaching into
groundwater. This chemical has been shown to damage the liver and
kidney of laboratory animals such as rats exposed at high levels
during their lifetimes. Some humans who were exposed to
relatively large amounts of this chemical also suffered damage to
the nervous system. U.S. EPA has set the drinking water standard
for 2,4-D at 0.07 parts per million (ppm) to protect against the
140
risk of these adverse health effects. Drinking water that meets
the U.S. EPA standard is associated with little to none of this
risk and is considered safe with respect to 2,4-D.
37)
Epichlorohydrin. The United States Environmental Protection
Agency (U.S. EPA) sets drinking water standards and has determined
that epichlorohydrin is a health concern at certain levels of
exposure. Polymers made from epichlorohydrin are sometimes used
in the treatment of water supplies as a flocculent to remove
particulates. Epichlorohydrin generally gets into drinking water
by improper use of these polymers. This chemical has been shown
to cause cancer in laboratory animals such as rats and mice when
the animals are exposed at high levels over their lifetimes.
Chemicals that cause cancer in laboratory animals also may
increase the risk of cancer in humans who are exposed over long
periods of time. U.S. EPA has set the drinking water standard for
epichlorohydrin using a treatment technique to reduce the risk of
cancer or other adverse health effects which have been observed in
laboratory animals. This treatment technique limits the amount of
epichlorohydrin in the polymer and the amount of the polymer which
may be added to drinking water as a flocculent to remove
particulates. Drinking water systems which comply with this
treatment technique have little to no risk and are considered safe
with respect to epichlorohydrin.
38)
Ethylbenzene. The United States Environmental Protection Agency
(U.S. EPA) sets drinking water standards and has determined
ethylbenzene is a health concern at certain levels of exposure.
This organic chemical is a major component of gasoline. It
generally gets into water by improper waste disposal or leaking
gasoline tanks. This chemical has been shown to damage the
kidney, liver, and nervous system of laboratory animals such as
rats exposed to high levels during their lifetimes. U.S. EPA has
set the drinking water standard for ethylbenzene at 0.7 parts per
million (ppm) to protect against the risk of these adverse health
effects. Drinking water that meets the U.S. EPA standard is
associated with little to none of this risk and is considered safe
with respect to ethylbenzene.
39)
Ethylene dibromide (EDB). The United States Environmental
Protection Agency (U.S. EPA) sets drinking water standards and has
determined that EDB is a health concern at certain levels of
exposure. This organic chemical was once a popular pesticide.
When soil and climatic conditions are favorable, EDB may get into
drinking water by runoff into surface water or by leaching into
groundwater. This chemical has been shown to cause cancer in
laboratory animals such as rats and mice when the animals are
exposed at high levels over their lifetimes. Chemicals that cause
cancer in laboratory animals also may increase the risk of cancer
in humans who are exposed over long periods of time. U.S. EPA has
set the drinking water standard for EDB at 0.00005 parts per
141
million (ppm) to reduce the risk of cancer or other adverse health
effects which have been observed in laboratory animals. Drinking
water that meets this standard is associated with little to none
of this risk and is considered safe with respect to EDB.
40)
Heptachlor. This contaminant is subject to an "additional State
requirement". The supplier shall give the following notice if the
level exceeds the Section 611.311 MCL. If the level exceeds the
Section 611.310 MCL, but not that of Section 611.311, the supplier
shall give a general notice under Section 611.854.
The United States Environmental Protection Agency (U.S. EPA) sets
drinking water standards and has determined that heptachlor is a
health concern at certain levels of exposure. This organic
chemical was once a popular pesticide. When soil and climatic
conditions are favorable, heptachlor may get into drinking water
by runoff into surface water or by leaching into groundwater.
This chemical has been shown to cause cancer in laboratory animals
such as rats and mice when the animals are exposed at high levels
over their lifetimes. Chemicals that cause cancer in laboratory
animals also may increase the risk of cancer in humans who are
exposed over long periods of time. U.S. EPA has set the drinking
water standards for heptachlor at 0.0004 parts per million (ppm)
to reduce the risk of cancer or other adverse health effects which
have been observed in laboratory animals. Drinking water that
meets this standard is associated with little to none of this risk
and is considered safe with respect to heptachlor.
41)
Heptachlor epoxide. This contaminant is subject to an "additional
State requirement". The supplier shall give the following notice
if the level exceeds the Section 611.311 MCL. If the level
exceeds the Section 611.310 MCL, but not that of Section 611.311,
the supplier shall give a general notice under Section 611.854.
The United States Environmental Protection Agency (U.S. EPA) sets
drinking water standards and has determined that heptachlor
epoxide is a health concern at certain levels of exposure. This
organic chemical was once a popular pesticide. When soil and
climatic conditions are favorable, heptachlor epoxide may get into
drinking water by runoff into surface water or by leaching into
groundwater. This chemical has been shown to cause cancer in
laboratory animals such as rats and mice when the animals are
exposed at high levels over their lifetimes. Chemicals that cause
cancer in laboratory animals also may increase the risk of cancer
in humans who are exposed over long periods of time. U.S. EPA has
set the drinking water standards for heptachlor epoxide at 0.0002
parts per million (ppm) to reduce the risk of cancer or other
adverse health effects which have been observed in laboratory
animals. Drinking water that meets this standard is associated
with little to none of this risk and is considered safe with
respect to heptachlor epoxide.
142
42)
Lindane. The United States Environmental Protection Agency (U.S.
EPA) sets drinking water standards and has determined that lindane
is a health concern at certain levels of exposure. This organic
chemical is used as a pesticide. When soil and climatic
conditions are favorable, lindane may get into drinking water by
runoff into surface water or by leaching into groundwater. This
chemical has been shown to damage the liver, kidney, nervous
system, and immune system of laboratory animals such as rats, mice
and dogs exposed at high levels during their lifetimes. Some
humans who were exposed to relatively large amounts of this
chemical also suffered damage to the nervous system and
circulatory system. U.S. EPA has established the drinking water
standard for lindane at 0.0002 parts per million (ppm) to protect
against the risk of these adverse health effects. Drinking water
that meets the U.S. EPA standard is associated with little to none
of this risk and is considered safe with respect to lindane.
43)
Methoxychlor. The United States Environmental Protection Agency
(U.S. EPA) sets drinking water standards and has determined that
methoxychlor is a health concern at certain levels of exposure.
This organic chemical is used as a pesticide. When soil and
climatic conditions are favorable, methoxychlor may get into
drinking water by runoff into surface water or by leaching into
groundwater. This chemical has been shown to damage the liver,
kidney, nervous system, and reproductive system of laboratory
animals such as rats exposed at high levels during their
lifetimes. It has also been shown to produce growth retardation
in rats. U.S. EPA has set the drinking water standard for
methoxychlor at 0.04 parts per million (ppm) to protect against
the risk of these adverse health effects. Drinking water that
meets the U.S. EPA standard is associated with little to none of
this risk and is considered safe with respect to methoxychlor.
44)
Monochlorobenzene. The United States Environmental Protection
Agency (U.S. EPA) sets drinking water standards and has determined
that monochlorobenzene is a health concern at certain levels of
exposure. This organic chemical is used as a solvent. It
generally gets into water by improper waste disposal. This
chemical has been shown to damage the liver, kidney and nervous
system of laboratory animals such as rats and mice exposed to high
levels during their lifetimes. U.S. EPA has set the drinking
water standard for monochlorobenzene at 0.1 parts per million
(ppm) to protect against the risk of these adverse health effects.
Drinking water that meets the U.S. EPA standard is associated
with little to none of this risk and is considered safe with
respect to monochlorobenzene.
45)
Polychlorinated biphenyls (PCBs). The United States Environmental
Protection Agency (U.S. EPA) sets drinking water standards and has
determined that polychlorinated biphenyls (PCBs) are a health
143
concern at certain levels of exposure. These organic chemicals
were once widely used in electrical transformers and other
industrial equipment. They generally get into drinking water by
improper waste disposal or leaking electrical industrial
equipment. This chemical has been shown to cause cancer in
laboratory animals such as rats and mice when the animals are
exposed at high levels over their lifetimes. Chemicals that cause
cancer in laboratory animals also may increase the risk of cancer
in humans who are exposed over long periods of time. U.S. EPA has
set the drinking water standard for PCBs at 0.0005 parts per
million (ppm) to reduce the risk of cancer or other adverse health
effects which have been observed in laboratory animals. Drinking
water that meets this standard is associated with little to none
of this risk and is considered safe with respect to PCBs.
46)
Pentachlorophenol. The United States Environmental Protection
Agency (U.S. EPA) sets drinking water standards and has determined
that pentachlorophenol is a health concern at certain levels of
exposure. This organic chemical is widely used as a wood
preservative, herbicide, disinfectant, and defoliant. It
generally gets into drinking water by runoff into surface water or
leaching into groundwater. This chemical has been shown to
produce adverse reproductive effects and to damage the liver and
kidneys of laboratory animals such as rats and mice when the
animals are exposed at high levels over their lifetimes. Some
humans who were exposed to relatively large amounts of this
chemical also suffered damage to the liver and kidneys. This
chemical has been shown to cause cancer in laboratory animals such
as rats and mice when the animals are exposed at high levels over
their lifetimes. Chemicals that cause cancer in laboratory
animals also may increase the risk of cancer in humans who are
exposed over long periods of time. U.S. EPA has set the drinking
water standard for pentachlorophenol at 0.001 parts per million
(ppm) to reduce the risk of adverse health effects. Drinking
water that meets this standard is associated with little to none
of this risk and is considered safe with respect to pentachloro-
phenol.
47)
Styrene. The United States Environmental Protection Agency (U.S.
EPA) sets drinking water standards and has determined that styrene
is a health concern at certain levels of exposure. This organic
chemical is commonly used to make plastics and is sometimes a
component of resins used for drinking water treatment. Styrene
may get into drinking water from improper waste disposal. This
chemical has been shown to damage the liver and nervous system in
laboratory animals when exposed at high levels during their
lifetimes. U.S. EPA has set the drinking water standard for
styrene at 0.1 parts per million (ppm) to protect against the risk
of these adverse health effects. Drinking water that meets the
U.S. EPA standard is associated with little to none of this risk
and is considered safe with respect to styrene.
144
48)
Tetrachloroethylene. The United States Environmental Protection
Agency (U.S. EPA) sets drinking water standards and has determined
that tetrachloroethylene is a health concern at certain levels of
exposure. This organic chemical has been a popular solvent,
particularly for dry cleaning. It generally gets into drinking
water by improper waste disposal. This chemical has been shown to
cause cancer in laboratory animals such as rats and mice when the
animals are exposed at high levels over their lifetimes. Chemicals
that cause cancer in laboratory animals also may increase the risk
of cancer in humans who are exposed over long periods of time.
U.S. EPA has set the drinking water standard for
tetrachloroethylene at 0.005 parts per million (ppm) to reduce the
risk of cancer or other adverse health effects which have been
observed in laboratory animals. Drinking water that meets this
standard is associated with little to none of this risk and is
considered safe with respect to tetrachloroethylene.
49)
Toluene. The United States Environmental Protection Agency (U.S.
EPA) sets drinking water standards and has determined that toluene
is a health concern at certain levels of exposure. This organic
chemical is used as a solvent and in the manufacture of gasoline
for airplanes. It generally gets into water by improper waste
disposal or leaking underground storage tanks. This chemical has
been shown to damage the kidney, nervous system, and circulatory
system of laboratory animals such as rats and mice exposed to high
levels during their lifetimes. Some industrial workers who were
exposed to relatively large amounts of this chemical during
working careers also suffered damage to the liver, kidney and
nervous system. U.S. EPA has set the drinking water standard for
toluene at 1 part per million (ppm) to protect against the risk of
these adverse health effects. Drinking water that meets the U.S.
EPA standard is associated with little to none of this risk and is
considered safe with respect to toluene.
50)
Toxaphene. The United States Environmental Protection Agency
(U.S. EPA) sets drinking water standards and has determined that
toxaphene is a health concern at certain levels of exposure. This
organic chemical was once a pesticide widely used on cotton, corn,
soybeans, pineapples and other crops. When soil and climatic
conditions are favorable, toxaphene may get into drinking water by
runoff into surface water or by leaching into groundwater. This
chemical has been shown to cause cancer in laboratory animals such
as rats and mice when the animals are exposed at high levels over
their lifetimes. Chemicals that cause cancer in laboratory animals
also may increase the risk of cancer in humans who are exposed
over long periods of time. U.S. EPA has set the drinking water
standard for toxaphene at 0.003 parts per million (ppm) to reduce
the risk of cancer or other adverse health effects which have been
observed in laboratory animals. Drinking water that meets this
145
standard is associated with little to none of this risk and is
considered safe with respect to toxaphene.
51)
2,4,5-TP. The United States Environmental Protection Agency (U.S.
EPA) sets drinking water standards and has determined that
2,4,5-TP is a health concern at certain levels of exposure. This
organic chemical is used as a herbicide. When soil and climatic
conditions are favorable, 2,4,5-TP may get into drinking water by
runoff into surface water or by leaching into groundwater. This
chemical has been shown to damage the liver and kidney of
laboratory animals such as rats and dogs exposed to high levels
during their lifetimes. Some industrial workers who were exposed
to relatively large amounts of this chemical during working
careers also suffered damage to the nervous system. U.S. EPA has
set the drinking water standard for 2,4,5-TP at 0.05 parts per
million (ppm) to protect against the risk of these adverse health
effects. Drinking water that meets the U.S. EPA standard is
associated with little to none of this risk and is considered safe
with respect to 2,4,5-TP.
52)
Xylenes. The United States Environmental Protection Agency (U.S.
EPA) sets drinking water standards and has determined that xylene
is a health concern at certain levels of exposure. This organic
chemical is used in the manufacture of gasoline for airplanes and
as a solvent for pesticides, and as a cleaner and degreaser of
metals. It usually gets into water by improper waste disposal.
This chemical has been shown to damage the liver, kidney and
nervous system of laboratory animals such as rats and dogs exposed
to high levels during their lifetimes. Some humans who were
exposed to relatively large amounts of this chemical also suffered
damage to the nervous system. U.S. EPA has set the drinking water
standard for xylene at 10 parts per million (ppm) to protect
against the risk of these adverse health effects. Drinking water
that meets the U.S. EPA standard is associated with little to none
of this risk and is considered safe with respect to xylene.
53)
Antimony. The United States Environmental Protection Agency (U.S.
EPA) sets drinking water standards and has determined that
antimony is a health concern at certain levels of exposure. This
inorganic chemical occurs naturally in soils, ground water, and
surface water and is often used in the flame retardant industry.
It is also used in ceramics and glass, batteries, fireworks, and
explosives. It may get into drinking water through natural
weathering of rock, industrial production, municipal waste
disposal, or manufacturing processes. This chemical has been
shown to decrease longevity, and altered blood levels of
cholesterol and glucose in laboratory animals such as rats exposed
to high levels during their lifetimes. U.S. EPA has set the
drinking water standard for antimony at 0.006 parts per million
(ppm) to protect against the risk of these adverse health effects.
Drinking water that meets the U.S. EPA standard is associated
146
with little to none of this risk and is considered safe with
respect to antimony.
54)
Beryllium. The United States Environmental Protection Agency
(U.S. EPA) sets drinking water standards and has determined that
beryllium is a health concern at certain levels of exposure. This
inorganic chemical occurs naturally in soils, ground water, and
surface water and is often used in electrical equipment and
electrical components. It generally gets into water from runoff
from mining operations, discharge from processing plants, and
improper waste disposal. Beryllium compounds have been associated
with damage to the bones and lungs and induction of cancer in
laboratory animals such as rats and mice when the animals are
exposed to high levels during their lifetimes. There is limited
evidence to suggest that beryllium may pose a cancer risk via
drinking water exposure. Therefore, U.S. EPA based the health
assessment on noncancer effects with and extra uncertainty factor
to account for possible carcinogenicity. Chemicals that cause
cancer in laboratory animals also may increase the risk of cancer
in humans who are exposed over long periods of time. U.S. EPA has
set the drinking water standard for beryllium at 0.004 parts per
million (ppm) to protect against the risk of these adverse health
effects. Drinking water that meets the U.S. EPA standard is
associated with little to none of this risk and is considered safe
with respect to beryllium.
55)
Cyanide. The United States Environmental Protection Agency (U.S.
EPA) sets drinking water standards and has determined that cyanide
is a health concern at certain levels of exposure. This inorganic
chemical is used in electroplating, steel processing, plastics,
synthetic fabrics, and fertilizer products. It usually gets into
water as a result of improper waste disposal. This chemical has
been shown to damage the spleen, brain, and liver of humans
fatally poisoned with cyanide. U.S. EPA has set the drinking
water standard for cyanide at 0.2 parts per million (ppm) to
protect against the risk of these adverse health effects.
Drinking water that meets the U.S. EPA standard is associated with
little to none of this risk and is considered safe with respect to
cyanide.
56)
Nickel. The United States Environmental Protection Agency (U.S.
EPA) sets drinking water standards and has determined that nickel
is a health concern at certain levels of exposure. This inorganic
chemical occurs naturally in soils, ground water, and surface
water and is often used in electroplating, stainless steel, and
alloy products. It generally gets into water from mining and
refining operations. This chemical has been shown to damage the
heart and liver in laboratory animals when the animals are exposed
to high levels over their lifetimes. U.S. EPA has set the
drinking water standard at 0.1 parts per million (ppm) for nickel
to protect against the risk of these adverse health effects.
147
Drinking water that meets the U.S. EPA standard is associated with
little to none of this risk and is considered safe with respect to
nickel.This subsection corresponds with 40 CFR 141.32(e)(56)
marked "reserved" by USEPA. This statement maintains structural
consistency with USEPA rules.
57)
Thallium. The United States Environmental Protection Agency (U.S.
EPA) sets drinking water standards and has determined that
thallium is a health concern at certain high levels of exposure.
This inorganic chemical occurs naturally in soils, ground water,
and surface water and is used in electronics, pharmaceuticals, and
the manufacture of glass and alloys. This chemical has been shown
to damage the kidney, liver, brain, and intestines of laboratory
animals when the animals are exposed to high levels during their
lifetimes. U.S. EPA has set the drinking water standard for
thallium at 0.002 parts per million (ppm) to protect against the
risk of these adverse health effects. Drinking water that meets
the U.S. EPA standard is associated with little to none of this
risk and is considered safe with respect to thallium.
58)
Benzo(a)pyrene. The United States Environmental Protection Agency
(U.S. EPA) sets drinking water standards and has determined that
benzo(a)pyrene is a health concern at certain levels of exposure.
Cigarette smoke and charbroiled meats are common sources of
general exposure. The major source of benzo(a)pyrene in drinking
water is the leaching from coal tar lining and sealants in water
storage tanks. This chemical has been shown to cause cancer in
animals such as rats and mice when the animals are exposed to high
levels. U.S. EPA has set the drinking water standard for benzo-
(a)pyrene at 0.0002 parts per million (ppm) to protect against the
risk of cancer. Drinking water that meets the U.S. EPA standard
is associated with little to none of this risk and is considered
safe with respect to benzo(a)pyrene.
59)
Dalapon. The United States Environmental Protection Agency (U.S.
EPA) sets drinking water standards and has determined that dalapon
is a health concern at certain levels of exposure. This organic
chemical is a widely used herbicide. It may get into drinking
water after application to control grasses in crops, drainage
ditches, and along railroads. This chemical has been associated
with damage to the kidney and liver in laboratory animals when the
animals are exposed to high levels during their lifetimes. U.S.
EPA has set the drinking water standard for dalapon at 0.2 parts
per million (ppm) to protect against the risk of these adverse
health effects. Drinking water that meets the U.S. EPA standard
is associated with little to none of this risk and is considered
safe with respect to dalapon.
60)
Dichloromethane. The United States Environmental Protection
Agency (U.S. EPA) sets drinking water standards and has determined
that dichloromethane (methylene chloride) is a health concern at
148
certain levels of exposure. This organic chemical is a widely
used solvent. It is used in the manufacture of paint remover, as
a metal degreaser, and as an aerosol propellant. It generally
gets into water after improper discharge of waste disposal. This
chemical has been shown to cause cancer in laboratory animals such
as rats and mice when the animals are exposed to high levels
during their lifetimes. Chemicals that cause cancer in laboratory
animals also may increase the risk of cancer in humans who are
exposed over long periods of time. U.S. EPA has set the drinking
water standard for dichloromethane at 0.005 parts per million
(ppm) to protect against the risk of cancer or other adverse
health effects. Drinking water that meets the U.S. EPA standard
is associated with little to none of this risk and is considered
safe with respect to dichloromethane.
61)
Di(2-ethylhexyl)adipate. The United States Environmental
Protection Agency (U.S. EPA) sets drinking water standards and has
determined that di(2-ethylhexyl)adipate is a health concern at
certain levels of exposure. Di(2-ethylhexyl)adipate is a widely
used plasticizer in a variety of products, including synthetic
rubber, food packaging materials, and cosmetics. It may get into
drinking water after improper waste disposal. This chemical has
been shown to damage the liver and testes in laboratory animals
such as rats and mice when the animals are exposed to high levels.
U.S. EPA has set the drinking water standard for di(2-ethyl-
hexyl)adipate at 0.4 parts per million (ppm) to protect against
the risk of adverse health effects that have been observed in
laboratory animals. Drinking water that meets the U.S. EPA
standard is associated with little to none of this risk and is
considered safe with respect to di(2-ethylhexyl)adipate.
62)
Di(2-ethylhexyl)phthalate. The United States Environmental
Protection Agency (U.S. EPA) sets drinking water standards and has
determined that di(2-ethylhexyl)phthalate is a health concern at
certain levels of exposure. Di(2-ethylhexyl)phthalate is a widely
used plasticizer, which is primarily used in the production of
polyvinyl chloride (PVC) resins. It may get into drinking water
after improper waste disposal. This chemical has been shown to
cause cancer in laboratory animals such as rats and mice when the
animals are exposed to high levels during their lifetimes. U.S.
EPA has set the drinking water standard for di(2-ethylhexyl)-
phthalate at 0.006 parts per million (ppm) to protect against the
risk of cancer or other adverse health effects which have been
abserved in laboratory animals. Drinking water that meets the
U.S. EPA standard is associated with little to none of this risk
and is considered safe with respect to di(2-ethylhexyl)phthalate.
63)
Dinoseb. The United States Environmental Protection Agency (U.S.
EPA) sets drinking water standards and has determined that dinoseb
is a health concern at certain levels of exposure. Dinoseb is a
widely used pesticide and generally gets into water after
149
application on orchards, vineyards, and other crops. This
chemical has been shown to damage the thyroid and reproductive
organs in laboratory animals such as rats exposed to high levels.
U.S. EPA has set the drinking water standard for dinoseb at 0.007
parts per million (ppm) to protect against the risk of these
adverse health effects. Drinking water that meets the U.S. EPA
standard is associated with little to none of this risk and is
considered safe with respect to dinoseb.
64)
Diquat. The United States Environmental Protection Agency (U.S.
EPA) sets drinking water standards and has determined that diquat
is a health concern at certain levels of exposure. This organic
chemical is a herbicide used to control terrestrial and aquatic
weeds. It may get into drinking water by runoff into surface
water. This chemical has been shown to damage the liver, kidney,
and gastrointestinal tract and causes cataract formation in
laboratory animals such as dogs and rats exposed at high levels
over their lifetimes. U.S. EPA has set the drinking water
standard for diquat at 0.02 parts per million (ppm) to protect
against the risk of these adverse health effects. Drinking water
that meets the U.S. EPA standard is associated with little to none
of this risk and is considered safe with respect to diquat.
65)
Endothall. The United States Environmental Protection Agency
(U.S. EPA) sets drinking water standards and has determined that
endothall is a health concern at certain levels of exposure. This
organic chemical is a herbicide used to control terrestrial and
aquatic weeds. It may get into drinking water by runoff into
surface water. This chemical has been shown to damage the liver,
kidney, gastrointestinal tract, and reproductive system of
laboratory animals such as rats and mice exposed at high levels
over their lifetimes. U.S. EPA has set the drinking water
standard for endothall at 0.1 parts per million (ppm) to protect
against the risk of these adverse health effects. Drinking water
that meets the U.S. EPA standard is associated with little to none
of this risk and is considered safe with respect to endothall.
66)
Endrin. The United States Environmental Protection Agency (U.S.
EPA) sets drinking water standards and has determined that endrin
is a health concern at certain levels of exposure. This organic
chemical is a pesticide no longer registered for use in the United
States. However, this pesticide is persistent in treated soils
and accumulates in sediments and aquatic and terrestrial biota.
This chemical has been shown to cause damage to the liver, kidney,
and heart in laboratory animals such as rats and mice when the
animals are exposed to high levels during their lifetimes. U.S.
EPA has set the drinking water standard for endrin at 0.002 parts
per million (ppm) to protect against the risk of these adverse
health effects that have been observed in laboratory animals.
Drinking water that meets the U.S. EPA standard is associated with
150
little to none of this risk and is considered safe with respect to
endrin.
67)
Glyphosate. The United States Environmental Protection Agency
(U.S. EPA) sets drinking water standards and has determined that
glyphosate is a health concern at certain levels of exposure.
This organic chemical is a herbicide used to control grasses and
weeds. It may get into drinking water by runoff into surface
water. This chemical has been shown to cause damage to the liver
and kidneys in laboratory animals such as rats and mice when the
animals are exposed to high levels during their lifetimes. U.S.
EPA has set the drinking water standard for glyphosate at 0.7
parts per million (ppm) to protect against the risk of these
adverse health effects. Drinking water that meets the U.S. EPA
standard is associated with little to none of this risk and is
considered safe with respect to glyphosate.
68)
Hexachlorobenzene. The United States Environmental Protection
Agency (U.S. EPA) sets drinking water standards and has determined
that hexachlorobenzene is a health concern at certain levels of
exposure. This organic chemical is produced as an impurity in the
manufacture of certain solvents and pesticides. This chemical has
been shown to cause cancer in laboratory animals such as rats and
mice when the animals are exposed to high levels during their
lifetimes. Chemicals that cause cancer in laboratory animals also
may increase the risk of cancer in humans who are exposed over
long periods of time. U.S. EPA has set the drinking water
standard for hexachlorobenzene at 0.001 parts per million (ppm) to
protect against the risk of cancer and other adverse health
effects. Drinking water that meets the U.S. EPA standard is
associated with little to none of this risk and is considered safe
with respect to hexachlorobenzene.
69)
Hexachlorocyclopentadiene. The United States Environmental
Protection Agency (U.S. EPA) sets drinking water standards and has
determined that hexachlorocyclopentadiene is a health concern at
certain levels of exposure. This organic chemical is a used as an
intermediate in the manufacture of pesticides and flame
retardants. It may get into water by discharge from production
facilities. This chemical has been shown to damage the kidney and
the stomach of laboratory animals when exposed to high levels
during their lifetimes. U.S. EPA has set the drinking water
standard for hexachlorocyclopentadiene at 0.05 parts per million
(ppm) to protect against the risk of these adverse health effects.
Drinking water that meets the U.S. EPA standard is associated
with little to none of this risk and is considered safe with
respect to hexachlorocyclopentadiene.
70)
Oxamyl. The United States Environmental Protection Agency (U.S.
EPA) sets drinking water standards and has determined that oxamyl
is a health concern at certain levels of exposure. This organic
151
chemical is used as a pesticide for the control of insects and
other pests. It may get into drinking water by runoff into
surface water or leaching into ground water. This chemical has
been shown to damage the kidneys of laboratory animals such as
rats when exposed at high levels during their lifetimes. U.S. EPA
has set the drinking water standard for oxamyl at 0.2 parts per
million (ppm) to protect against the risk of these adverse health
effects. Drinking water that meets the U.S. EPA standard is
associated with little to none of this risk and is considered safe
with respect to oxamyl.
71)
Picloram. The United States Environmental Protection Agency (U.S.
EPA) sets drinking water standards and has determined that
picloram is a health concern at certain levels of exposure. This
organic chemical is used as a pesticide for broadleaf weed
control. It may get into drinking water by runoff into surface
water or leaching into groundwater as a result of pesticide
application and improper waste disposal. This chemical has been
shown to cause damage to the kidneys and liver in laboratory
animals such as rats when the animals are exposed to high levels
during their lifetimes. U.S. EPA has set the drinking water
standard for picloram at 0.5 parts per million (ppm) to protect
against the risk of these adverse health effects. Drinking water
that meets the U.S. EPA standard is associated with little to none
of this risk and is considered safe with respect to picloram.
72)
Simazine. The United States Environmental Protection Agency (U.S.
EPA) sets drinking water standards and has determined that
simazine is a health concern at certain levels of exposure. This
organic chemical is a herbicide used to control annual grasses and
broadleaf weeds. It may leach into groundwater or run off into
surface water after application. This chemical may cause cancer
in laboratory animals such as rats and mice when the animals are
exposed to high levels during their lifetimes. Chemicals that
cause cancer in laboratory animals also may increase the risk of
cancer in humans who are exposed over long periods of time. U.S.
EPA has set the drinking water standard for simazine at 0.004
parts per million (ppm) to reduce the risk of cancer or adverse
health effects. Drinking water that meets the U.S. EPA standard
is associated with little to none of this risk and is considered
safe with respect to simazine.
73)
1,2,4-Trichlorobenzene. The United States Environmental
Protection Agency (U.S. EPA) sets drinking water standards and has
determined that 1,2,4-trichlorobenzene is a health concern at
certain levels of exposure. This organic chemical is used as a
dye carrier and as a precursor in herbicide manufacture. It
generally gets into drinking water by discharges from industrial
activities. This chemical has been shown to cause damage to
several organs, including the adrenal glands. U.S. EPA has set
the drinking water standard for 1,2,4-trichlorobenzene at 0.07
152
parts per million (ppm) to protect against the risk of these
adverse health effects. Drinking water that meets the U.S. EPA
standard is associated with little to none of this risk and is
considered safe with respect to 1,2,4-trichlorobenzene.
74)
1,1,2-Trichloroethane. The United States Environmental Protection
Agency (U.S. EPA) sets drinking water standards and has determined
that 1,1,2-trichloroethane is a health concern at certain levels
of exposure. This organic chemical is an intermediate in the
production of 1,1-dichloroethylene. It generally gets into water
by industrial discharge of wastes. This chemical has been shown
to damage the kidney and liver of laboratory animals such as rats
exposed to high levels during their lifetimes. U.S. EPA has set
the drinking water standard for 1,1,2-trichloroethane at 0.005
parts per million (ppm) to protect against the risk of these
adverse health effects. Drinking water that meets the U.S. EPA
standard is associated with little to none of this risk and is
considered safe with respect to 1,1,2-trichloroethane.
75)
2,3,7,8-TCDD (dioxin). The United States Environmental Protection
Agency (U.S. EPA) sets drinking water standards and has determined
that dioxin is a health concern at certain levels of exposure.
This organic chemical is an impurity in the production of some
pesticides. It may get into drinking water by industrial
discharge of wastes. This chemical has been shown to cause cancer
in laboratory animals such as rats and mice when the animals are
exposed to high levels during their lifetimes. Chemicals that
cause cancer in laboratory animals also may increase the risk of
cancer in humans who are exposed over long periods of time. U.S.
EPA has set the drinking water standard for dioxin at 0.00000003
parts per million (ppm) to protect against the risk of cancer or
other adverse health effects. Drinking water that meets the U.S.
EPA standard is associated with little to none of this risk and is
considered safe with respect to dioxin.
BOARD NOTE: Derived from 40 CFR 141.32(e) (19945).
(Source: Amended at 20 Ill. Reg. ________, effective ______________________)
Section 611.Appendix B
Percent Inactivation of G. Lamblia Cysts
TABLE 1.1
CT-99.9 FOR 99.9 PERCENT INACTIVATION OF GIARDIA LAMBLIA CYSTS
BY FREE CHLORINE AT 0.5 DEGREES C OR LOWER
These CT values achieve greater than a 99.99 percent inactivation of viruses.
CT values between the indicated pH values may be determined by linear
interpolation. CT values between the indicated temperatures of different
tables may be determined by linear interpolation. If no interpolation is
used, use the CT 99.9 value at the lower temperature and at the higher pH.
153
Free Residual
pH
(mg/L) <=
≤
6.0
6.5
7.0
7.5
8.0
8.5 <=
≥
9.0
<=
≤
0.41
137
163
195
237
277
329
390
0.6
141
168
200
239
286
342
407
0.8
145
172
205
246
295
354
422
1.0
148
176
210
253
304
365
437
1.2
152
180
215
259
313 2376
451
1.4
155
184
221
266
321
387
464
1.6
157
189
226
273
329
397
477
1.8
162
193
231
279
338
407
489
2.0
165
197
236
286
346
417
500
2.2
169
201
242
297
353
426
511
2.4
172
205
247
2968
361
435
522
2.6
175
209
252
304
368
444
533
2.8
178
213
257
310
375
452
543
3.0
181
217
261
316
382
460
552
TABLE 1.2
CT-99.9 FOR 99.9 PERCENT INACTIVATION OF GIARDIA LAMBLIA CYSTS
BY FREE CHLORINE AT 5.0 DEGREES C
These CT values achieve greater than a 99.99 percent inctivation of viruses.
CT values between the indicated pH values may be determined by linear
interpolation. CT values between the indicated temperatures of different
tables may be determined by linear interpolation. If no interpolation is
used, use the CT 99.9 value at the lower temperature and at the higher pH.
Free Residual
pH
(mg/L) <=
≤
6.0
6.5
7.0
7.5
8.0
8.5 <=
≥
9.0
<=
≤
0.4
97
117
139
166
198
236
279
0.6
100
120
143
171
204
244
291
0.8
103
122
146
175
210
252
301
1.0
105
125
149
179
216
260
312
1.2
107
127
152
183
221
267
320
1.4
109
130
155
187
227
274
329
1.6
111
132
158
192
232
281
337
1.8
114
135
162
196
238
287
345
2.0
116
138
165
200
243
294
353
2.2
118
140
169
204
248
300
361
2.4
120
143
172
209
253
306
368
2.6
122
146
175
213
258
312
375
2.8
124
148
178
217
263
318
382
3.0
126
151
182
221
268
324
369
TABLE 1.3
CT-99.9 FOR 99.9 PERCENT INACTIVATION OF GIARDIA LAMBLIA CYSTS
BY FREE CHLORINE AT 10.0 DEGREES C
154
These CT values achieve greater than a 99.99 percent inactivation of viruses.
CT values between the indicated pH values may be determined by linear
interpolation. CT values between the indicated temperatures of different
tables may be determined by linear interpolation. If no interpolation is
used, use the CT 99.9 value at the lower temperature and at the higher pH.
Free Residual
pH
(mg/L) <=
≤
6.0
6.5
7.0
7.5
8.0
8.5 <=
≥
9.0
<=
≤
0.4
73
88
104
125
149
177
209
0.6
75
90
107
128
153
183
2108
0.8
78
92
110
131
158
189
2206
1.0
79
94
112
134
162
195
234
1.2
80
95
114
137
166
200
240
1.4
82
98
116
140
170
206
247
1.6
83
99
119
144
174
211
253
1.8
86
101
122
147
179
215
259
2.0
87
104
124
150
182
221
265
2.2
89
105
127
153
186
225
271
2.4
90
107
129
157
190
230
276
2.6
92
110
131
160
194
234
281
2.8
93
111
134
163
197
239
287
3.0
95
113
137
166
201
243
292
TABLE 1.4
CT-99.9 FOR 99.9 PERCENT INACTIVATION OF GIARDIA LAMBLIA CYSTS
BY FREE CHLORINE AT 15.0 DEGREES C
These CT values achieve greater than a 99.99 percent inactivation of viruses.
CT values between the indicated pH values may be determined by linear
interpolation. CT values between the indicated temperatures of different
tables may be determined by linear interpolation. If no interpolation is
used, use the CT 99.9 value at the lower temperature and at the higher pH.
Free Residual
pH
(mg/L) <=
≤
6.0
6.5
7.0
7.5
8.0
8.5 <=
≥
9.0
<=
≤
0.4
49
59
70
83
99
118
140
0.6
50
60
72
86
102
122
146
0.8
52
61
73
88
105
126
151
1.0
53
63
75
90
108
130
156
1.2
54
64
76
92
111
134
160
1.4
55
65
78
94
114
137
165
1.6
56
66
79
96
116
141
169
1.8
57
68
81
968
119
144
173
2.0
58
69
83
100
122
147
177
2.2
59
70
85
102
124
150
181
2.4
60
72
86
105
127
153
184
2.6
61
73
88
107
129
156
188
2.8
62
74
89
109
132
159
191
3.0
63
76
91
111
134
162
195
155
TABLE 1.5
CT-99.9 FOR 99.9 PERCENT INACTIVATION OF GIARDIA LAMBLIA CYSTS
BY FREE CHLORINE AT 20 DEGREES C
These CT values achieve greater than a 99.99 percent inactivation of viruses.
CT values between the indicated pH values may be determined by linear
interpolation. CT values between the indicated temperatures of different
tables may be determined by linear interpolation. If no interpolation is
used, use the CT 99.9 value at the lower temperature and at the higher pH.
Free Residual
pH
(mg/L) <=
≤
6.0
6.5
7.0
7.5
8.0
8.5 <=
≥
9.0
<=
≤
0.4
36
44
52
62
74
89
105
0.6
38
45
54
64
77
92
109
0.8
39
46
55
66
79
95
113
1.0
39
47
56
67
81
98
117
1.2
40
48
57
69
83
100
120
1.4
41
49
58
70
85
103
123
1.6
42
50
59
72
87
105
126
1.8
43
51
61
74
89
108
129
2.0
44
52
62
75
91
110
132
2.2
44
53
63
77
93
113
135
2.4
45
54
65
78
95
115
138
2.6
46
55
66
80
97
117
141
2.8
47
56
67
81
99
119
143
3.0
47
57
68
83
101
122
146
TABLE 1.6
CT-99.9 FOR 99.9 PERCENT INACTIVATION OF GIARDIA LAMBLIA CYSTS
BY FREE CHLORINE AT 25 DEGREES C AND HIGHER
These CT values achieve greater than a 99.99 percent inactivation of viruses.
CT values between the indicated pH values may be determined by linear
interpolation. CT values between the indicated temperatures of different
tables may be determined by linear interpolation. If no interpolation is
used, use the CT 99.9 value at the lower temperature and at the higher pH.
Free Residual
pH
(mg/L) <=
≤
6.0
6.5
7.0
7.5
8.0
8.5 <=
≥
9.0
<=
≤
0.4
24
29
35
42
50
59
70
0.6
25
30
36
43
51
61
73
0.8
26
31
37
44
53
63
75
1.0
26
31
37
45
54
65
78
1.2
27
32
38
46
55
67
80
1.4
27
33
39
47
57
69
82
1.6
28
33
40
48
58
70
84
1.8
29
34
41
49
60
72
86
2.0
29
35
41
50
61
74
88
156
2.2
30
35
42
51
62
75
90
2.4
30
36
43
52
63
77
92
2.6
31
37
44
53
65
78
94
2.8
31
37
45
54
66
80
96
3.0
32
38
46
55
67
81
97
TABLE 2.1
CT-99.9 FOR 99.9 PERCENT INACTIVATION OF GIARDIA LAMBLIA CYSTS
BY CHLORINE DIOXIDE AND OZONE
These CT values achieve greater than a 99.99 percent inactivation of viruses.
CT values between the indicated pH values may be determined by linear
interpolation. If no interpolation is used, use the CT
99.9
value at the lower
temperature for determining CT
99.9
values between indicated temperatures.
<=
≤
1
°
C
5
°
C
10
°
C
15
°
C
20
°
C >25
°
C
Chlorine dioxide
63.
26.
23.
19.
15.
11.
Ozone
2.9
1.9
1.4
0.95
0.72
0.48
TABLE 3.1
CT-99.9 FOR 99.9 PERCENT INACTIVATION OF GIARDIA LAMBLIA CYSTS
BY CHLORAMINES
These values are for pH values of 6 to 9. These CT values may be assumed to
achieve greater than a 99.99 percent inactivation of viruses only if chlorine
is added and mixed in the water prior to the addition of ammonia. If this
condition is not met, the system must demonstrate, based on on-site studies or
other information, as approved by the Agency, that the system is achieving at
least a 99.99 percent inactivation of viruses. CT values between the
indicated temperatures may be determined by linear interpolation. If no
interpolation is used, use the CT
99.9
value at the lower temperature for
determining CT
99.9
values between indicated temperatures.
<=
≤
1
°
C
5
°
C
10
°
C
15
°
C
20
°
C >
≥
25
°
C
Chloramines
3800.
2200.
1850.
1500.
1100.
750.
BOARD NOTE: Derived from 40 CFR 141.74(b) Tables, as adopted at 54 Fed. Reg.
27526, June 29, 1989 1.1 through 3.1 (1995).
(Source: Amended at 20 Ill. Reg. ________, effective ______________________)
Section 611.Table F
Number of Water Quality Parameter Sampling Sites
System Size
Number of Sites
(Persons Served)
(Standard Monitoring)
(Reduced Monitoring)
more than 100,000
25
10
10,001 to 100,000
10
7
3,301 to 10,000
3
3
157
501 to 3,300
2
2
101 to 500
1
1
100 or fewer
1
1
BOARD NOTE: Derived from 40 CFR 141.87(a)(2) and (e) (1992).
(Source: Amended at 20 Ill. Reg. ________, effective ______________________)
I, Dorothy M. Gunn, Clerk of the Illinois Pollution Control Board, hereby certify that the above
proposed opinion and order was adopted on the _____ day of ______________, 1996, by a vote of
.
__________________________________________
Dorothy M. Gunn, Clerk
Illinois Pollution Control Board