2.2.2 Needle Valves. To control gas flow.
hood.
6. QUALITY ASSURANCE
6.1 The success of this protocol lies in designing the TTE to
119—676
where standard temperature for mole/scm is 20°C.
Where:
temperature of 20°C.
f) The total vent stream concentration (by volume) of compounds
containing halogens (ppmv, by compound) shall be summed from
the individual concentrations of compounds containing halogens
EFFECTIVENESS INDEX (TRE) EQUATION
OR EQUAL TO 3.5 MJ/scm
OR EQUAL TO 0.48 NJ/scm
b c d e f
a b c d e f
0. 0.0. 0.0. 0.0. 0.
0. 00900.00900.00900.0090
industry groups.
plant unless:
system that meets the requirements of subsection(d) (4);
water, as measured as close as possible tothe vapor hose connection; and
C) Avoidable leaks of liquid during loading orunloading operations.
1) That have an annual. gasoline throughput greater
than or equal to ~l,000,000gallons, as averaged
over the preceding three calendar years; and

ILLINOIS POLLUTION CONTROL BOARD

February 28, 1991

IN THE MATTER OF:

)

PACT DEFICIENCIES IN THE

)

METRO-EAST AREA:

 AMENDMENTS

)

 P91-8

TO 35

 ILL.ADM.CODE PART 215

)

 (Rulemaking)

AND THE ADDITION OF PART 219

Proposed Rule.

 First Notice.

ORDER OF THE BOARD

(by

3.

 Theodore Meyer):

On January

17,

 1991,

the

 Illinois Environmental Protection

Agency

 (Agency)

 filed this proposal for rulemaking.

 The proposal

seeks

to

 correct

 deficiencies

 identified

by

the

 United

 States

Environmental

 Protection

 Agency

 (USEPA)

in

 Illinois’

 state

implementation plan

 (SIP)

 for ozone

 in the Metro—East

 area,

and

contains regulations requiring the

 implementation

of

 reasonably

available control technology (PACT) for certain sources of volatile

organic

 material

 (VOM).

The

 Board

 accepted

the

 proposal

for

hearing on February 7,

 1991.

 The Board also accepted the Agency’s

certification that this rulemaking

 is federally required pursuant

to

 Section

 28.2

of

the

 Environmental

 Protection

Act

 (Act)

(Ill.Rev.Stat.

 1989,

 ch. 111 1/2,

 par.

 1028.2), as amended by P.A.

86—1409.

Today

the

 Board

 sends

 this

 proposal

to

 first

 notice,

as

required by Section 5.01 of the Illinois Administrative Procedure

Act.

 (Ill.Rev.Stat.

 1989,

ch.

 127,

 par.

 1005.01.)

 The proposal

is

 submitted

as

 filed by the Agency,

 with no alterations.

The

Board emphasizes that in sending this proposal to first notice,

it

adopts jiQ substantive position on the merits of the proposal.

The

Board

 believes

 that

 publishing

the

 proposal

at

 this

 time

 will

maximize

the

 opportunity

for

 public

 comment

on

the

 proposal.

Additionally,

 the Board has already stated that

 it places

 a very

high

 priority

on

the

 quick

 resolution

of

 this

 rulemaking.

Beginning the statutorily-required first notice period at this time

will allow for the most expeditious resolution of the proceeding.

The Board notes that

 two hearings have been scheduled in this

proceeding.

 These hearings are consolidated hearings with docket

P91-7

 PACT Deficiencies

 in the

 Chicago

 Area:

 Amendments

to

35

Ill.Adm.Code 215 and the Addition of Part 218.

 A hearing will be

held in Chicago on Wednesday, April

10,

 1991, and a second hearing

will

be

 conducted

in

 Granite

 City

on

 Monday,

 April

15,

 1991.

Please note that the Chicago hearing will be limited to discussion

of proposed amendments to Part 215 and to the proposed addition of

Part 218.

 The Granite City hearing will be limited to discussion

119—463

2

of the proposed amendments to Part 215 and to the proposed addition

of

 Part

 219.

 Please

 contact

the

 hearing

 officer

for

 further

information

 about

 required

 pre-filing

of

 testimony

and

 other

hearing matters.

The Board directs the Clerk to cause first notice publication

in the Illinois Register of the following amendments:

TITLE 35:

 ENVIRONMENTAL PROTECTION

SUBTITLE B:

 AIR POLLUTION

CHAPTER

I:

 POLLUTION CONTROL BOARD

SUBCHAPTER

c:

 EMISSIONS STANDARDS AND LIMITATIONS FOR STATIONARY SOURCES

Section

PART 219

ORGANIC MATERIAL EMISSION STANDARDS AND LIMITATIONS

FOR THE METRO EAST AREA

SUBPART A:

 GENERAL PROVISIONS

219.100

219.101

219.102

219.103

219.104

219.105

219.106

219.107

219.108

219.109

219.110

219.111

219.112

SUBPART

B:

Section

219.121

219.122

219.123

219.124

219.125

219.126

219.127

219.128

Introduction

Clean—up and Disposal Operations

Abbreviations and Conversion Factors

Applicability

Definitions

Test Methods and Procedures

Compliance Dates

Afterburners

Exemptions, Variations,

 and Alternative Means

of

Control

 or Compliance Determinations

Vapor Pressure of Volatile Organic Liquids

Vapor Pressure of Organic Material or Solvents

Vapor Pressure of Volatile Organic Material

Incorporations by Reference

ORGANIC EMISSIONS FROM STORAGE AND LOADING OPERATIONS

Storage Containers

Loading Operations

Petroleum Liquid Storage Tanks

External Floating Roofs

Compliance Dates

Compliance Plan

Emissions Testing

Measurement of Seal Gaps

SUBPART

C:

 ORGANIC EMISSIONS FROM MISCELLANEOUS EQUIPMENT

Section

119—464

3

219.141

219.142

219. 143

219. 144

Section

219.181

219. 182

219.183

219.184

219.185

219. 186

Section

219.204

219.205

219.206

219.207

219.208

219.209

219. 210

219.211

Section

219.401

219.402

219.403

219.404

219.405

Separation Operations

Pumps and Compressors

Vapor Blowdown

Safety Relief Valves

SUBPART

E:

 SOLVENT CLEANING

Solvent Cleaning

 in General

Cold Cleaning

Open Top Vapor Degreasing

Conveyorized Degreasing

Compliance Schedule

Test Methods

SUBPART

F:

 COATING OPERATIONS

Emission Limitations for Manufacturing Plants

Daily-Weighted Average Limitations

Solids Basis Calculation

Alternative Emission Limitations

Exemptions from Emission Limitations

Exemption from General Rule on Use of Organic Material

Compliance Schedule

Recordkeeping and Reporting

SUBPART

G:

 USE OF ORGANIC MATERIAL

Use of Organic Material

Alternative Standard

Fuel Combustion Emission Sources

Operations with Compliance Program

Flexographic and Rotogravure Printing

Applicability

Compliance Schedule

Recordkeeping and Reporting

Heatset Web Offset Lithographic Printing

SUBPART

 LEAKS FROM SYNTHETIC ORGANIC CHEMICAL AND POLYMER

MANUFACTURING EQUIPMENT

General Requirements

Inspection Program Plan for Leaks

Inspection Program for Leaks

Repairing Leaks

Section

219. 301

219.302

219.303

219.304

SUBPART H:

 PRINTING AND PUBLISHING

Section

219. 421

219. 422

219.423

219.424

119—465

4

219.425

219.426

219.427

219.428

219.429

219.430

Recordkeeping for Leaks

Report for Leaks

Alternative Program for Leaks

Open-ended Valves

Standards for Control Devices

Compliance Date

SUBPART R:

 PETROLEUN REFINING AND RELATED INDUSTRIES;

ASPHALT MATERIALS

Section

219.441

219.442

219.443

219.444

219.445

219.446

219.447

219.448

219.449

219.450

219.451

219.452

219.453

Petroleum Refinery Waste Gas Disposal

Vacuum Producing Systems

Wastewater

 (Oil/Water) Separator

Process Unit Turnarounds

Leaks:

 General Requirements

Monitoring Program Plan for Leaks

Monitoring Program for Leaks

Recordkeeping for Leaks

Reporting for Leaks

Alternative Program for Leaks

Sealing Device Requirements

Compliance Schedule for Leaks

Compliance Dates

Section

219.480

219.481

SUBPART

S:

 RUBBER

AND

 MISCELLANEOUS

 PLASTIC PRODUCTS

Manufacture of Pneumatic Rubber Tires

Green Tire Spraying Operations

Alternative Emission Reduction Systems

Emission Testing

Compliance Dates

Compliance Plan

SUBPART

T:

 PHARMACEUTICAL MANUFACTURING

Applicability of Subpart T

Control of Reactors,

 Distillation Units,

 Crystallizers,

Centrifuges and Vacuum Dryers

219.482

 Control of Air Dryers, Production Equipment Exhaust

Systems and Filters

Material Storage and Transfer

In—Process Tanks

Leaks

Other Emission Sources

Testing

Monitoring and Recordkeeping for Air Pollution Control

Equipment

219.489

 Recordkeeping for Air Pollution Control Equipment

SUBPART V:

 AIR OXIDATION PROCESSES

Section

219.461

219.462

219.463

219.464

219.465

219.466

219.483

219.484

219.485

219.486

219.487

 219.488

119—466

5

Section

219.521

219.525

219.526

219.527

Definitions

Emission Limitations for Air Oxidation Processes

Testing and Monitoring

Compliance Date

SUBPART W:

 AGRICULTURE

Section

219. 541

 Pesticide Exception

SUBPART X:

 CONSTRUCTION

Section

219.561

219.562

219.563

Section

219.581

219.582

219.583

219.584

219.585

Section

219.601

219. 602

219.603

219.604

219.605

219.606

219.607

219. 608

219.609

219.610

219. 611

219.612

219.613

Architectural Coatings

Paving Operations

Cutback Asphalt

SUBPART

Y:

 GASOLINE DISTRIBUTION

Bulk Gasoline Plants

Bulk Gasoline Terminals

Gasoline Dispensing Facilities

Gasoline Delivery Vessels

Gasoline Volatility Standards

SUBPART

Z:

 DRY CLEANERS

Perchloroethylene Dry Cleaners

Exemptions

Leaks

Compliance Dates

Compliance Plan

Exception to Compliance Plan

Standards for Petroleum Solvent Dry Cleaners

Operating Practices for Petroleum Solvent Dry Cleaners

 Program for Inspection and Repair of Leaks

Testing and Monitoring

Exemption for Petroleum Solvent Dry Cleaners

Compliance Dates

Compliance Plan

SUBPART AA:

 PAINT AND INK MANUFACTURING

Applicability

Exemption for Waterbase Material and Heatset Offset Ink

Permit Conditions

Open—top Mills, Tanks,

 Vats or Vessels

Section

219.620

219.621

219.623

219.624

119—467

6

219.625

 Grinding Mills

219.626

 Storage Tanks

219.628

 Leaks

219.630

 Clean Up

219.636

 Compliance Schedule

219.637

 Recordkeeping and Reporting

SUBPART BB:

 POLYSTYRENE PLANTS

Section

219.875

 Applicability of Subpart BB

219.877

 Emissions Limitation at Polystyrene Plants

219.879

 Compliance Date

219.881

 Compliance Plan

219.883

 Special Requirements

 for Compliance Plan

219.886

 Emissions Testing

SUBPART PP:

 MISCELLANEOUS FABRICATED PRODUCT MANUFACTURING PROCESSES

Section

219.920

 Applicability

219.923

 Permit Conditions

219.926

 Control Requirements

219.927

 Compliance Schedule

219.928

 Testing

SUBPART

QQ:

 MISCELLANEOUS FORMULATION MANUFACTURING PROCESSES

Section

219.940

 Applicability

219.943

 Permit Conditions

219.946

 Control Requirements

219.947

 Compliance Schedule

219.948

 Testing

SUBPART RR:

 MISCELLANEOUS ORGANIC CHEMICAL MANUFACTURING PROCESSES

Section

219.960

 Applicability

219.963

 Permit Conditions

219.966

 Control Requirements

219.967

 Compliance Schedule

219.968

 Testing

SUBPART TT:

 OTHER EMISSION SOURCES

Section

219.980

 Applicability

219.983

 Permit Conditions

219.986

 Control Requirements

219.987

 Compliance Schedule

219.988

 Testing

119—468

7

SUBPART

 UU:.

 RECORDKEEPING AND REPORTING FOR NON-CTG SOURCES

Section

219.990

 Exempt Emission Sources

219.991

 Subject Emission Sources

Appendix A:

 List of Chemicals Defining Synthetic Organic

Chemical and Polymer Manufacturing

Appendix B:

 VON Measurement Techniques

 £or Capture Efficiency

Appendix C:

 Reference Methods and Procedures

Appendix D:

 Coefficients for the Total Resource Effectiveness

Index

 (TRE)

 Equation

AUTHORITY:

 Implementing Section 10 and authorized by Section

28.2 of the Environmental Protection Act

 (Ill.

 Rev.

 Stat.

 1989,

ch.

 111 1/2,

 pars.

 1010 and 1028.2)

SOURCE:

 Adopted at

____

 Ill. Peg.

_____,

 effective

____________

SUBPART A:

 GENERAL PROVISIONS

Section 219.100

 Introduction

a)

 This Part contains standards and limitations for

emissions of organic material from stationary sources

located in the Metro East area,

 which

 is comprised of

Madison,

 Monroe,

 and St. Clair Counties.

b)

 Sources subject to this Part may be subject to the

following:

1)

 Permits required under

35

 Ill. Adm.

 Code 201;

2)

 Air quality standards under

35

 Ill.

 Adm.

 Code 243;

c)

 This Part

 is divided into Subparts which are grouped as

follows:

1)

 Subpart

A:

 General Provisions

2)

 Subparts

 B-F:

 Emissions from equipment and

operations in common to more than one industry;

3)

 Subpart G:

 Emissions from use of organic

material;

4)

 Subparts H-end:

 Special rules for various

industry groups.

Section 219.101

 Cleanup and Disposal Operation

119—469

8

Emission of organic material released during clean—up operations

and disposal shall be included

with other

emissions of organic

material from the related emission source or air pollution

control equipment in determining total emissions.

Section 219.102

 Abbreviations and Conversion Factors

a)

 The following abbreviations are used

 in this Part:

ASTM American Society for Testing and Materials

bbl

 barrels

 (42 gallons)

 degrees Celsius or centigrade

cm

 centimeters

cu in.

 cubic inches

 degrees Fahrenheit

FIP

 Federal Implementation Plan

ft

 feet

ft2

 square feet

g

 grams

gpm

 gallons per minute

g/mole

 grams per mole

gal

 gallons

hr

 hours

in

 inches

 degrees Kelvin

kcal kilocalories

kg

 kilograms

kg/hr

 kilograms per hour

kPa

 kilopascals; one thousand newtons per square

meter

1

 liters

1/sec

 liters per second

lbs

 pounds

lbs/hr

 pounds per hour

lbs/gal

 pounds per gallon

LEL

 lower explosive limit

m

 meters

m2

 square meters

m3

 cubic meters

mg

 milligrams

Mg

 Negagrams,

 metric tons or tonnes

ml

 milliliters

mm

 minutes

NJ

 megajoules

mm Hg

 millimeters of mercury

ppm

 parts per million

ppmv parts per million by volume

psi

 pounds per square inch

psia pounds per square inch absolute

psig pounds per square inch gauge

119—470

9

scf

 standard cubic feet

scm

 standard cubic meters

sec

 seconds

SIP

 State Implementation Plan

TTE

 temporary total enclosure

sq cm

 square centimeters

sq

in

 square inches

T

 English ton

ton

 English ton

USEPA

 United States Environmental Protection

Agency

VOC

 volatile organic compounds

VOL

 volatile organic liquids

VON

 volatile organic materials

b)

 The following conversion factors are used in this Part.

English

 Metric

1 gal

 3.785

1

1,000 gal 3,785

1

or 3.785

in3

1 psia

 6.897 kPa

 (51.71 mm Hg)

2.205 lbs

 1 kg

1 bbl

 159.0

1

1 cu

in

 16.39 ml

1 lb/gal

 119,800 mg/i

1 ton

 0.907 Mg

1 T

 0.907 Mg

Section 219.103

 Applicability

The provisions of this Part shall apply to all sources located

in

Madison,

 Monroe,

and

St. Clair County.

a)

 The provisions of this Part shall become effective

sixty days after a final decision by the federal

appellate court of the general appeal

 (Illinois

Environmental Regulatory Group

v.

 USEPA,

 No. 90-2778

(and consolidated cases)

 (7th Cir.))

 of the federal

implementation plan

 (FIP)

 for the Chicago area

promulgated by the U.S. Environmental Protection Agency

(55 Fed. Reg.

 26184, June 29,

 1990;

 55 Fed.

 Peg.

 31981,

August

6,

 1990;

 55 Fed. Reg.

 39774,

 September 28,

1990), provided, however, that if a provision of the

FIP is voided or made ineffective by a federal court,

the corresponding provision in this proceeding shall

not become effective.

b)

 The provisions of

this Part specifically applicable to

each appellant who appealed the FIP for the Chicago

area shall become effective sixty days after a final

119—47 1

10

decision of that appellant’s appeal by

the federal

appellate court; provided, however,

 that

 if the

provisions ofthe

 FIP applicable to that party are

voided or made ineffective by

 a federal court, the

corresponding provisions

 in this proceeding shall not

become effective.

Section 219.104

 Definitions

The following terms are defined for the purpose of this Part.

“Accelacota” means a pharmaceutical coating operation

which consists of a horizontally rotating perforated

drum in which tablets are placed,

 a coating is applied

by spraying,

 and the coating is dried by the flow of

air across the drum through the perforations.

“Accumulator” means the reservoir of a condensing unit

receiving the condensate from a surface condenser.

“Acid Gases” means for the purposes of Section 9.4 of

the Environmental Protection Act

 (the Act)

 (Ill. Rev.

Stat.

 1987,

ch.

 ill 1/2,

 par.

 1009.4)

 hydrogen

chloride, hydrogen fluoride and hydrogen bromide, which

exist as gases,

 liquid mist,

 or any combination

thereof.

“Actual emissions” means the actual quantity of VOM

emissions from an emission source during a particular

time period.

“Actual Heat Input” means the quantity of heat produced

by the combustion of fuel using the gross heating value

of the fuel.

“Adhesive” means any substance or mixture of substances

intended to serve as

a

 joining compound.

“Afterburner” means

 a control device in which materials

in gaseous effluent are combusted.

“Air contaminant” means any solid,

 liquid, or gaseous

matter, any odor,

 or any form of energy, that is

capable of being released into the atmosphere from an

emission source.

“Air dried coatings” means any coatings that dry by use

of air or forced air at temperatures up to 363.15 K

(194°F)

“Air pollution” means the presence in the atmosphere of

one or more air

contaminants

 in sufficient quantities

119—472

11

and of such characteristics and duration as to be

injurious to human,

 plant,

 or animal life,

 to health,

or to property,

 or to unreasonably interfere with the

enjoyment of life or property.

“Air pollution control equipment” means any equipient

or facility of

 a type intended to eliminate,

 prevent,

reduce or control the emission of specified air

contaminants to the atmosphere.

“Air suspension

coater/dryer” means a pharmaceutical

coating operation which consists of vertical chambers

 in which tablets or particles are placed,

 and a coating

is applied and then dried while the tablets or

particles are kept in

 a fluidized state by the passage

of air upward through the chambers.

“Airless spray” means a spray coating method

 in which

the coating

 is atomized by forcing

 it through a small

opening at high pressure.

 The coating liquid

 is not

mixed with air before exiting. from the nozzle.

“Air—assisted airless spray” means

 a spray coating

method which combines compressed air with hydraulic

pressure to atomize

the coating material into finer

droplets than is achieved with pure airless spray.

Lower hydraulic pressure is used than with airless

spray.

“Allowable emissions” means the quantity of VON

emissions during

 a particular time period from a

stationary source calculated using the maximum rated

capacity of the source

 (unless restricted by federally

enforceable limitations on operating rate,

 hours of

operation,

 or both)

 and the most stringent of:

the

applicable standards

 in 40 CFR Parts

 60 and 61;

the

applicable implementation plan;

 or a federally

enforceable permit.

“Ambient air quality standards” means those standards

designed to protect the public health and welfare

codified in 40 CFR Part 50

 and promulgated from time

 to time by the USEPA pursuant to authority contained in

Section 108 of the Clean Air Act,

 42 U.S.C.

 7401 et

seq.,

 as amended from time to time.

“Applicator” means

 a device used in .a coating line to

apply coating.

“As applied” means the exact formulation of

 a coating

during application on or impregnation into a substrate.

119—473

12

“Architectural Coating” means any coating used for

residential or commercial buildings or their

appurtenances,

 or for industrial buildings,

 which

is

site applied.

“Asphalt” means the dark—brown to black cementitious

material

 (solid,

 semisolid,

 or liquid

 in consistency)

of which the main constituents are bitumens which occur

naturally or as a residue of petroleum refining.

“Asphalt Prime Coat” means

 a low—viscosity liquid

asphalt applied to an absorbent surface as the first of

more than one asphalt coat.

“Automobile” means

 a motor vehicle capable of carrying

no more than

 12 passengers.

“Automobile or light—duty truck assembly plant” means

a

facility where parts are assembled or finished for

eventual inclusion into a finished automobile or

light—duty truck ready for sale to vehicle dealers,

but

not including customizers, body shops,

 and other

repainters.

“Automobile or light-duty truck refinishing” means the

repainting of used automobiles and light-duty trucks.

“Baked coatings” means any coating which

is cured or

dried in an oven where the oven air temperature exceeds

90°C(194°F)

“Batch Loading” means the process

 of loading a number

of individual parts at the same time for degreasing.

“Bead-Dipping” means the dipping of an assembled tire

bead into a solvent-based cement.

“Binders” means organic materials and resins which do

not contain VOM.

“Bituminous coatings” means black or brownish coating

materials which are soluble in carbon disulfide,

 which

consist mainly of hydrocarbons, and which are obtained

from natural deposits or as residues from the

distillation of crude oils or of low grades of coal.

“British Thermal Unit” means the quantity of heat

required to raise one pound of water from 60°Fto 61°F

(abbreviated btu).

“Brush or wipe coating” means a manual method of

applying

 a coating using a brush,

 cloth,

 or similar

119—474

13

object.

“Bulk gasoline plant” means

 a gasoline storage and

distribution facility

with an

average throughput of

76,000

 1 (20,000 gal)

 or less on a 30—day roiling

 average that distributes gasoline to gasoline

dispensing facilities.

“Bulk Gasoline Terminal” means any gasoline storage and

distribution facility that receives gasoline by

pipeline, ship or barge,

 and distributes gasoline to

bulk gasoline plants or gasoline dispensing facilities.

“Can” means any metal container, with or without

 a top,

cover,

 spout or handles,

 into which solid or liquid

materials are packaged.

“Can coating” means any coating applied on

 a single

walled container that is manufactured from metal sheets

thinner than 29 gauge (0.0141

 in.).

“Can coating facility” means

a

 facility that includes

one or more can coating line(s)

“Can coating line” means

 a coating line

 in which any

protective, decorative,

 or functional coating is

applied onto the surface of cans or can components.

“Capture” means the containment or recovery of

emissions from

 a process for direction into a duct

which may be exhausted through a stack or vent to a

control device.

 The overall abatement of emission-s

from a process with an add—on control device

is

a

function both of the capture efficiency and of the

control device.

“Capture device” means

 a hood,

 enclosed room floor

sweep or other means of collecting solvent or other

pollutants into a duct.

 The pollutant can then be

directed to a pollution control device such as an

afterburner or carbon adsorber.

 Sometimes the term

is

used loosely to include the control device.

“Capture efficiency” means the fraction of all VON

generated by a process that are directed to an

abatement or recovery device.

“Capture system” means all equipment (including, but

not limited to, hoods,

 ducts,

 fans, ovens,

 dryers,

etc.)

 used to contain, collect and transport an air

pollutant to a control device.

119—475

14

“Clean Air Act” means the Clean Air Act of

 1963,

as

amended,

 including the Clean Air Act Amendments of

1977,

 (42 U.S.C.

 7401 et seq.),

 and the Clean Air Act

Amendments

of

 1990,

 (P.A.

 101549).

“Clear coating” means coatings that lack color and

opacity or are transparent using the undercoat as a

reflectant base or undertone color.

“Clear topcoat” means the final coating which contains

binders, but not opaque pigments,

and

 is specifically

formulated to form a transparent or translucent solid

protective film.

“Closed Purge System” means

 a system that is not open

to the atmosphere and that

 is composed of piping,

connections,

 and,

 if necessary,

 flow inducing devices

that transport liquid or vapor from a piece or pieces

of equipment to a control device, or return the liquid

or vapor to the process line.

“Closed vent system” means a system that is not open to

the atmosphere and is composed of piping,

 connections,

and,

 if necessary,

 flow inducing devices that transport

gas or vapor from an emission source to a control

device.

“Coating” means

 a material applied onto or impregnated

into a substrate for protective,

 decorative,

or

functional purposes.

 Such materials include, but are

not limited to,

 paints,

 varnishes,

 sealers, adhesives,

thinners, diluents, and inks.

“Coating applicator” means equipment used to apply

a

coating.

“Coating line” means an operation consisting of a

series of one or more coating applicators and any

associated flash-off areas,

 drying areas,

 and ovens

wherein a surface coating

 is applied, dried,

 or cured.

(It is not necessary for an operation to have an oven,

or flash—off area,

 or drying area to be included

in

this definition.)

“Coating plant” means any plant that contains one or

more coating line(s).

“Coil” means any flat metal sheet or strip that is

rolled or wound

 in concentric rings.

“Coil coating” means any coating applied

on any flat

metal sheet or strip that comes in rolls or coils.

119—476

15

“Coil coating facility” means a facility that includes

one or more coil coating line(s).

“Coil coating line” means a coating line

in which any

protective,

 decorative or functional coating

 is applied

onto the surface of flat metal sheets,

 strips,

 rolls,

or coils for industrial or commercial use.

“Cold cleaning” means the process of cleaning and

removing soils from surfaces by spraying, brushing,

flushing,

 or immersion while maintaining the organic

solvent below its boiling point.

 Wipe cleaning

 is not

included in this definition.

“Complete Combustion” means

 a process in which all

carbon contained in a fuel or gas stream is converted

to carbon dioxide.

“Component” means, with respect to synthetic organic

chemical and polymer manufacturing equipment,

and

petroleum refining and related industries,

 any piece of

equipment which has the potential to leak

VON

including,

 but not limited to, pump seals,

 compressor

seals,

 seal oil degassing vents,

 pipeline valves,

pressure relief devices, process drains,

 and open. ended

pipes.

 This definition excludes valves which are not

externally regulated,

 flanges,

 and equipment in heavy

liquid service.

 For purposes of Subpart Q of this

Part,

 this definition also excludes bleed ports of gear

pumps

 in polymer service.

“Concrete curing compounds” means any coating applied

to freshly poured concrete to retard the evaporation of

water.

“Condensate” means volatile organic liquid separated

from its associated gases, which condenses due to

changes

 in the temperature or pressure and remains

liquid at standard conditions.

“Continuous process” means, with respect to polystyrene

resin,

 a method of manufacture

 in which the styrene raw

material

 is delivered on a continuous basis to the

reactor

 in which the styrene is polymerized to

polystyrene.

“Control device” means equipment (such as an

afterburner or adsorber) used to remove or prevent the

emission of air pollutants from a contaminated exhaust

stream.

119—477

16

“Control device efficiency” means the ratio of the

pollution prevented by a control device and the

pollution introduced to the control device,

 expressed

as a percentage.

“Conveyorized degreasing” means the continuous process

of cleaning and removing soils from surfaces utilizing

 either cold or vaporized solvents.

“Crude oil” means a naturally occurring mixture which

consists of hydrocarbons and sulfur,

 nitrogen,

or

oxygen derivatives of hydrocarbons and which is

a

liquid at standard conditions.

“Crude oil gathering” means the transportation of crude

oil or condensate after custody transfer between a

production facility and a reception point.

“Custody transfer” means the transfer of produced

petroleum and/or condensate after processing and/or

treating in the producing operations,

 from storage

tanks or automatic transfer facilities to pipelines or

any other forms

 of transportation.

“Cutback Asphalt” means any asphalt which has been

liquified by blending with petroleum solvents other

than residual fuel oil and has not been emulsified with

water.

“Daily—weighted average VON content” means the average

VON content of two or more coatings

 as applied on a

coating line during any day, taking into account the

fraction of total coating volume that each coating

represents,

 as calculated with the following equation:

VON

—

V.C.J/V

1=1

where:

VON~

 The average VON content of two or more

coatings as applied each day on a

coating line

 in units

 of kg VOM/l

 (lbs

VON/gal)

 of coating

 (minus water and any

compounds which are specifically

exempted from the definition of VON),

n

 The number of different coatings as

applied each day on a coating line,

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17

 The volume of each coating

 (minus water

and any compounds which are specifically

exempted from the definition of VOM)

as

applied each day on

 a coating line

in

units of

1

 (gal)

C1

 The VON content of each coating as

applied each day on

 a coating line

in

units of kg VON/l

 (lbs VOM/gal)

of

coating

 (minus water and any compounds

which are specifically exempted from the

definition of VON),

and

VT

 The total

volume of all coatings

 (minus

water and any compounds which are

specifically exempted from the

definition of

VOM)

 as applied each day

on a coating line in units of

1

 (gal).

“Day” means the consecutive 24 hours beginning at 12:00

AN

 (midnight)

 local time.

“Degreaser” means any equipment or system used

in

solvent cleaning.

“Delivery vessel” means any tank truck

 or trailer

equipped with a storage tank that

 is used for the

transport of gasoline to

a

 stationary storage tank at

a

gasoline dispensing

 facility,

 bulk gasoline plant,

or

bulk gasoline terminal.

“Dip coating” means

 a method of applying coatings

in

which the part is submerged in

 a tank filled with the

coating.

“Distillate Fuel Oil” means fuel oils of grade

No.

1

or

2 as specified in detailed requirements for fuel oil

ASTN D—369—69

 (1971)

“Dry Cleaning Facility” means a facility engaged in the

cleaning of fabrics using an essentially nonaqueous

solvent by means of one or more solvent washes,

extraction of excess solvent by spinning and drying by

tumbling

 in an airstream.

 The facility includes,

but

is not limited to, washers,

 dryers,

 filter and

purification systems, waste disposal systems, holding

tanks,

 pumps and attendant piping and valves.

“Effluent Water Separator” means any tank,

 box,

 sump or

other apparatus in which any

organic material floating

on or entrained or contained in water entering such

119—479

18

tank,

 box,

 sump or other apparatus is physically

separated and removed from such water prior to

outfall,

drainage or recovery of such water.

“Electrostatic bell or disc spray” means

an

electrostatic spray coating method

in which a

rapidly—spinning bell- or disc-shaped applicator is

used to create

 a fine mist and apply the coating with

high transfer efficiency.

“Electrostatic spray” means a spray coating method in

which opposite electrical charges are applied to the

substrate and the coating.

 The coating

 is attracted to

the object due to the electrostatic potential between

them.

“Emission Rate” means total quantity of any air

contaminant discharge into the atmosphere

 in any

one—hour period.

“Emission source” and “source” mean

any facility from

which VON is emitted or capable of being emitted into

the atmosphere.

“Enamel” means a coating that cures by chemical

cross—linking of its base resin.

 Enamels can be

distinguished from lacquers because enamels are not

readily resoluble

in their original solvent.

“Enclose” means to cover any VOL surface that is

exposed to the atmosphere.

“End sealing compound coat” means

 a compound applied to

can ends which functions as a gasket when the end is

 assembled onto the can.

“Excess Air” means air supplied in addition to the

theoretical quantity necessary for complete combustion

of all fuel and/or combustible waste material.

“Excessive release” means a discharge of more than 295

g (0.65 lbs)

 of mercaptans and/or hydrogen sulfide into

the atmosphere in any 5-minute period.

“Exterior base coat” means a coating applied to the

exterior of

 a can body,

 or flat sheet to provide

protection to the metal

 or to provide background for

any lithographic or printing operation.

“Exterior end coat” means

 a coating applied to the

exterior end of a can to provide protection to the

metal.

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19

“External—floating roof” means a cover over an open top

storage tank consisting

 of a double deck or pontoon

single deck which rests upon and is supported by the

volatile organic liquid being contained and

 is equipped

with

 a closure seal or seals to close the space between

the roof edge and tank shell.

“Extreme environmental conditions” means exposure to

any or all of the following:

 ambient weather

conditions; temperatures consistently above

95oC

(203°F);detergents;

 abrasive and scouring agents;

solvents;

 or corrosive atmospheres.

“Extreme performance coating” means any coating which

 during intended use is exposed to extreme environmental

conditions.

“Fabric coating” means any coating applied on textile

fabric.

 Fabric coating includesthe application of

coatings by impregnation.

“Fabric coating facility” means

 a facility that

includes one or more fabric coating

 lines.

“Fabric coating line” means a coating line

 in which any

protective, decorative,

 or functional coating or

reinforcing material is applied on or impregnated into

a textile

 fabric.

“Federally enforceable” means all limitations and

conditions which are enforceable by the Administrator

including those requirements developed pursuant to 40

CFR Parts

 60 and 61;

requirements within any applicable

implementation plan;

 and any permit requirements

established pursuant to 40 CFR 52.21

 or under

regulations approved pursuant to 40 CFR Part 51 Subpart

I and 40 CFR 51.166.

“Final repair coat” means the repainting of any topcoat

which is damaged during vehicle assembly.

“Firebox” means the chamber or compartment of a boiler

or furnace in which materials are burned, but not the

combustion chamber or afterburner of an incinerator.

“Fixed—roof tank” means a cylindrical shell with a

permanently affixed roof.

“Flexographic printing” means the application of words,

designs,

 and pictures to a substrate by means of

 a roll

printing technique in which the pattern to be applied

119—481

20

is raised above the printing roll and the image carrier

is made of elastomeric materials.

“Flexographic printing line” means a printing line

in

which each roll printer uses a roll with raised areas

for applying an image such as words,

 designs,

or

pictures to a substrate.

 The image carrier on the roll

is made of rubber or other elastomeric material.

“Floating roof” means

 a roof on a stationary tank,

reservoir, or other container which moves vertically

upon change in volume of the stored material.

“Fountain solution” means the solution which is applied

to the image plate to maintain hydrophilic properties

of the non—image areas.

“Freeboard Height” means for open top vapor degreasers,

the distance from the top of the vapor zone to the top

of the degreaser tank.

 For cold cleaning degreasers,

the distance from the solvent to the top of the

degreaser tank.

“Fuel combustion emission source” means any furnace,

boiler,

 or similar equipment used for the primary

purpose of producing heat or power

 by indirect heat

transfer.

“Fuel gas system” means

 a system for collection of

refinery fuel gas including,

 but not limited to, piping

for collecting tail gas from various process units,

 mixing drums and controls, and distribution piping.

“Gas service” means that the component contains process

fluid that is in the gaseous state at operating

conditions.

“Gas/gas method” means either of two methods for

determining capture which rely only on gas phase

measurements.

 The first method requires construction

of a temporary total enclosure

 (TTE) to ensure that all

would—be fugitive emissions are measured.

 The second

method uses the building or room which houses the

facility as an enclosure.

 The second method requires

that all other VON sources within the room be shut down

while the test is performed,

 but all fans and blowers

within the room must be operated according to normal

procedures.

“Gasoline” means any petroleum distillate or petroleum

distillate/alcohol blend having a Reid vapor pressure

of 27.6 kPa or greater which is used as

 a fuel for

119—482

21

internal combustion engines.

“Gasoline dispensing facility” means any site where

gasoline is transferred from a stationary storage tank

to a motor vehicle gasoline tank used to provide fuel

to the engine of that motor vehicle.

“Green Tire Spraying” means the spraying of green

tires,

 both inside and outside, with release compounds

which help remove air from the tire during molding and

prevent the tire from sticking to the mold after

 curing.

“Green Tires” means assembled tires before molding and

curing have occurred.

“Gross vehicle weight” means the manufacturer’s gross

weight rating for the

 individual vehicle.

“Gross vehicle weight rating” means the value specified

by the manufacturer as the maximum design loaded weight

of

 a single vehicle.

“Heated airless spray” means an airless spray coating

method in which the coating is heated just prior to

application.

“Heatset” means

 a class of web—offset

 lithography which

requires a heated dryer to solidify the printing inks.

“Heatset-web-off

set lithographic printing line” means

a

lithographic printing line in which a blanket cylinder

is used to transfer ink from a plate cylinder to a

substrate continuously fed from a roll or an extension

process and an oven is used to solidify the printing

inks.

“Heavy liquid” means liquid with a true vapor pressure

of less than 0.3 kPa

 (0.04 psi)

 at 294.3oK (70~F)

established in a standard reference text or as

determined by ASTN method D2879-86

 (incorporated by

reference in Section 219.112);

 or which has 0.1 Reid

Vapor Pressure as determined by ASTN method D323-82

(incorporated by reference in Section 219.112); or

which when distilled requires a temperature of 421.95°K

(300°F) or greater to recover

10

percent of the liquid

as determined by ASTM method D86-82

 (incorporated by

reference in Section 219.112).

“Heavy off—highway vehicle products” means,

 for the

purpose of Subpart F of this Part,

 heavy construction,

mining,

 farming,

 or material handling equipment; heavy

119—483

22

industrial engines; diesel—electric

 locomotives and

associated power generation equipment;

 and the

components of such equipment or engines.

“Heavy off-highway vehicle products coating facility”

means a facility that includes one or more heavy

off-highway vehicle products coating line(s).

“Heavy off—highway vehicle products coating line” means

a coating line

 in which any protective,

 decorative,

or

functional coating is applied onto the surface of heavy

off-highway vehicle products.

“High temperature aluminum coating” means

 a coating

that is certified to withstand a temperature of 537.8oC

(1000°F) for 24 hours.

“Hood” means

 a partial enclosure or canopy for

capturing and exhausting,

 by means of

 a draft,

the

organic vapors or other

 fumes rising from

 a coating

process or other source.

“Hood capture efficiency” means the emissions from a

process which are captured by the hood and directed

into a control device, expressed as a percentage of all

emissions.

“Hot well” means the reservoir of a condensing unit

receiving the condensate from a barometric condenser.

“Hour” means a block period of

 60 minutes

 (e.g.,

 1:00am

to 2:00am).

“In—process tank” means a container used for mixing,

blending,

 heating,

 reacting, holding,

 crystallizing,

evaporating or cleaning operations in the manufacture

of pharmaceuticals.

“In—situ Sampling Systems” means nonextractive samplers

or in—line samplers.

“In vacuum service” means,

 for the purpose of Subpart Q

of this Part, equipment which is operating at an

internal pressure that

is at least

 5 kPa

 (0.73

 psia)

below ambient pressure.

“Incinerator” means a combustion apparatus

 in which

refuse

 is burned.

“Indirect heat transfer” means transfer of heat in such

a way that the source of heat does not come into direct

contact with process materials.

119—484

23

“Ink” means

 a coating used in printing,

 impressing,

or

transferring an image onto

 a substrate.

“Interior body spray coat” means a coating applied by

spray to the interior of a can body.

“Internal—floating roof” means a cover or roof

 in a

fixed-roof tank which rests upon and

 is supported by

the volatile organic liquid being contained and is

 equipped with

 a closure seal or seals to close the

space between the roof edge and tank shell.

“Lacquers” means any clear wood finishes formulated

with nitrocellulose

 or synthetic resins to dry by

evaporation without chemical reaction, including clear

lacquer sanding sealers.

“Large appliance” means any residential and commercial

washers,

 dryers,

 ranges, refrigerators,

 freezers, water

heaters, dishwashers,

 trash compactors,

air

conditioners, and other similar products.

“Large appliance coating” means any coating applied to

the component metal parts

 (including,

 but not limited

to, doors, cases,

 lids, panels, and interior support

parts)

 of residential and commercial washers,

 dryers,

ranges,

 refrigerators,

 freezers, water heaters, dish

washers,

 trash compactors,

 air conditioners, and other

similar products.

“Large appliance coating facility” means

 a facility

that includes one or more large appliance coating

line(s)

“Large appliance coating line” means

 a coating line in

which any protective,

 decorative,

 or functional coating

is applied onto the surface of large appliances.

“Light liquid” means VON in the liquid state which

is

not defined as heavy liquid.

“Light—duty truck” means any motor vehicle rated at

 3,850 kg gross vehicle weight or

 less,

 designed mainly

to transport property.

“Liquid/gas method” means either of two methods for

determining capture which require both gas phase and

liquid phase measurements and analysis.

 The first

method requires construction of a TTE.

 The second

method uses the building or room which houses the

facility as an enclosure.

 The second method requires

119—485

24

that all other VON sources within the room be shut down

while the test is performed,

 but all fans and blowers

within the room must be operated according to normal

procedures.

“Liquid—Mounted Seal” means a primary seal mounted in

continuous contact with the liquid between the tank

wall and the floating roof edge around the

circumference of the roof.

“Liquid service” means that the equipment or component

contains process fluid that is

 in a liquid state at

operating conditions.

“Liquids Dripping” means any visible leaking from a

seal including spraying, misting, clouding and ice

formation.

“Lithographic printing line” means a printing line,

except that the substrate

 is not necessarily fed from

an unwinding roll,

 in which each roll printer uses

a

roll where both the image and non—image areas are

essentially in the same plane

 (planographic).

“Low Solvent Coating” means a coating which contains

less organic solvent than the conventional coatings

used by the industry.

 Low solvent coatings include

water-borne, higher solids, electro—deposition and

powder coatings.

“Magnet wire” means aluminum or copper wire formed into

an electromagnetic

 coil.

“Magnet wire coating” means any coating or electrically

insulating varnish or enamel applied to magnet wire.

“Magnet wire coating facility” means a facility that

includes one or more magnet wire coating line(s).

“Magnet wire coating line” means a coating line

in

which any protective,

 decorative,

 or functional coating

is applied onto the surface of a magnet wire.

“Malfunction” means any sudden and unavoidable failure

of air pollution control equipment,

 process equipment,

or a process to operate in a normal or usual manner.

Failures that are caused entirely or

 in part by poor

maintenance,

 careless operation,

 or any other

preventable upset condition or preventable equipment

breakdown shall not be considered malfunctions.

“Manufacturing process” means a method whereby

a

119—486

25

process emission source or series of process emission

sources

 is used to convert raw materials,

 feed stocks,

subassemblies,

 or other components

 into a product,

either for sale or for use as a component

 in a

subsequent manufacturing process.

“Material Recovery Section” means any equipment

designed to transport and recover styrene monomer

and

other impurities from other products and by-products

in

a polystyrene plant, including but not limited to the

styrene devolatilizer unit and styrene recovery unit.

“Maximum theoretical emissions” means the quantity of

volatile organic material emissions that theoretically

could be emitted

 by a stationary source before add—on

controls based on the design capacity or maximum

production capacity of the source and 8760 hours per

year.

 The design capacity or maximum production

capacity includes use of coating(s)

 or ink(s) with the

highest volatile organic material content actually used

in practice by the source.

“Metal

furniture”

means

furniture

piece

including,

but not limited to,

 tables,

 chairs, waste baskets,

beds,

desks,

lockers,

benches,

shelving,

file

cabinets,

lamps,

and

room

dividers.

“Metal furniture coating” means any non—adhesive

coating applied to any furniture piece made of metal or

any metal part which is or will be assembled with other

metal,

wood,

fabric,

plastic

glass

parts

form

furniture piece including,

 but not limited to,

 tables,

chairs, waste baskets, beds,

 desks,

 lockers,

 benches,

shelving,

 file cabinets,

 lamps, and room dividers.

This definition shall not apply to any coating line

coating miscellaneous metal parts or products.

“Metal furniture coating facility” means a facility

that includes one or more metal furniture coating

line(s)

“Metal furniture coating line” means

 a coating line in

which any protective,

 decorative,

 or functional coating

is applied onto the surface of metal furniture.

“Metallic shoe—type seal” means a primary or secondary

seal constructed of metal sheets

 (shoes)

 which are

joined together to form a ring,

 springs,

 or levers

which attach the shoes to the floating roof and hold

the

shoes

against

the

tank

wall,

and

coated

fabric

which

 is suspended from the shoes to the floating roof.

119—487

26

“Miscellaneous fabricated product manufacturing

process” means:

A manufacturing process involving one or more of

the following applications,

 including any drying

and curing of formulations, and capable of

emitting VON:

Adhesives to fabricate or assemble components

or products

Asphalt solutions to paper or fiberboard

Asphalt to paper or felt

Coatings or dye to leather

Coatings to plastic

Coatings to rubber or glass

Disinfectant material to manufactured items

Plastic foam scrap or “fluff” from the

manufacture of foam containers and packaging

material to form resin pallets

Resin solutions to fiber substances

Viscose solutions for food casings

The storage and handling of formulations

associated with the process described above,

and

the use and handling of

 organic liquids and other

substances for clean—up operations associated with

the process described

in this definition.

“Miscellaneous formulation manufacturing process”

means:

A manufacturing process which compounds one or

more of the following and

 is capable of emitting

VOM:

Adhesives

Asphalt solutions

Caulks, sealants,

 or waterproofing agents

Coatings,

 other than paint and ink

119—488

27

Concrete curing compounds

Dyes

Friction materials and compounds

Resin solutions

Rubber solutions

Viscose solutions

The storage and handling of formulations

associated with the process described above,

and

the use and handling of organic liquids and other

substances for clean—up operations associated with

the process described in this definition.

“Miscellaneous metal parts or products” means any metal

part or metal product, even

 if attached to or combined

with a nonmetal part or product, except cans,

 coils,

metal furniture,

 large appliances,

 magnet wire,

automobiles,

 ships, and airplane bodies.

“Miscellaneous metal parts and products coating” means

any coating applied to any metal part or metal product,

even if attached to

or combined with

 a nonmetal part or

product, except

 cans,

 coils, metal furniture,

 large

appliances,

 and magnet wire.

 Prime coat,

 prime

surfacer coat,

 topcoat,

 and final repair coat for

automobiles and light-duty trucks are not miscellaneous

metal parts and products coatings.

 However, underbody

anti—chip

 (e.g., underbody plastisol)

 automobile,

and

light-duty truck coatings are miscellaneous metal parts

and products coatings.

 Also,

 automobile or light-duty

truck refinishing coatings, coatings applied to the

exterior of marine vessels, coatings applied to the

exterior of airplanes,

 and the customized topcoating

of

automobiles and trucks if production

 is less than 35

vehicles per day are not miscellaneous metal parts and

products coatings.

“Miscellaneous metal parts or products coating

facility” means

 a facility that includes one or more

miscellaneous metal parts or products coating

 lines.

“Miscellaneous metal parts or products coating line”

means a coating line in which any protective,

decorative,

 or functional coating

 is applied onto the

surface of miscellaneous metal parts or products.

“Miscellaneous organic chemical manufacturing process”

119—489

28

means:

A manufacturing process which produces by chemical

reaction,

 one or more of the following organic

compounds or mixtures of organic compounds and

which is capable of emitting VON:

Chemicals listed in Appendix A of this

section

Chlorinated and sulfonated compounds

Cosmetic, detergent,

 soap,

 or surfactant

intermediaries

 or specialties and products

Disinfectants

Food additives

Oil and petroleum product additives

Plasticizers

Resins or polymers

Rubber additives

Sweeteners

Varnishes

The storage and handling of formulations

associated with the process described above and

the use and handling of organic liquids and other

 substances for clean—up operations associated with

the process described in this definition.

“Monitor” means to measure and record.

“Multiple package coating” means a

coating made from

more than one different ingredient which must be mixed

prior to using and has

 a limited pot life due to the

chemical reaction which occurs upon mixing.

“No Detectable Volatile Organic Material Emissions”

means a discharge of volatile organic material into the

atmosphere as indicated by an instrument reading of

less than

500 ppm above background as determined in

accordance with 40 CFR 60.485(c).

“Offset” means, with respect to printing and publishing

operations,

 use of a blanket cylinder to transfer ink

119—490

29

from the plate cylinder to the surface to be printed.

“Opaque stains” means all stains that are not

semi—transparent stains.

“Open top vapor degreasing” means the batch process of

cleaning and removing soils from surfaces by condensing

hot solvent vapor on the colder metal parts.

“Open—ended valve” means any valve,

 except pressure

relief devices, having one side of the valve in contact

with process fluid and one side open to the atmosphere,

either directly or through open piping.

“Operator of Gasoline Dispensing Facility” means any

person who is the lessee of or operates, controls or

 supervises a gasoline dispensing facility.

“Organic compound” means any compound of carbon,

excluding carbon monoxide,

 carbon dioxide, carbonic

acid, metallic carbides or carbonates,

 and ammonium

carbonate.

“Organic material” means any chemical compound of

carbon including diluents and thinners which are

liquids at standard conditions and which are used as

dissolvers, viscosity reducers,

 or cleaning agents, but

excluding methane, carbon monoxide, carbon dioxide,

carbonic acid, metallic carbonic acid, metallic

carbide, metallic carbonates,

 and ammonium carbonate.

“Organic vapor” means the gaseous phase of an organic

material or a mixture of organic materials present

in

the atmosphere.

“Oven” means a chamber within which heat is used for

one or more of the following purposes:

 dry,

 bake,

cure,

 or polymerize a coating or ink.

“Overall control” means the product of the capture

efficiency and the control device efficiency.

“Overvarnish” means a transparent coating applied

directly over ink or coating.

“Owner of Gasoline Dispensing Facility” means any

person who has legal or equitable title to a stationary

storage tank at a gasoline dispensing facility.

“Owner or operator” means any person who owns,

operates,

 leases,

 controls,

 or supervises an emission

source or air pollution control equipment.

119—491

30

“Packaging rotogravure printing” means rotogravure

printing upon paper, paper board, metal foil,

 plastic

film,

 and other substrates, which are,

 in subsequent

operations,

 formed into packaging products or labels

for articles to be sold.

“Packaging rotogravure printing line” means a

rotogravure printing line in which surface coatings are

applied to paper, paperboard,

 foil,

 film,

 or other

substrates which are to be used to produce containers,

packaging products,

 or labels for articles.

“Paint manufacturing plant” means

 a plant that mixes,

blends,

 or compounds enamels,

 lacquers,

 sealers,

shellacs,

 stains,

 varnishes,

 or pigmented surface

coatings.

“Paper coating” means any coatingapplied on paper,

plastic film,

 or metallic foil to make certain

products,

 including

 (but not limited to) adhesive tapes

and labels, book covers,

 post cards,

 office copier

paper, drafting paper,

 or pressure sensitive tapes.

Paper coating includes the application of coatings by

impregnation and/or saturation.

“Paper coating facility” means

 a facility that includes

one or more paper coating lines.

“Paper coating line” means a coating line

 in which any

protective,

 decorative,

 or functional coating is

applied on, saturated

 into,

 or impregnated into paper,

plastic film,

 or metallic foil to make certain

products,

 including (but not limited to)

 adhesive tapes

and labels, book covers, post cards,

 office copier

paper, drafting paper,

 and pressure sensitive tapes.

“Parts per million

 (volume)” means

 a volume/volume

ratio which expresses the volumetric concentration of

gaseous air contaminant in a million unit volume of

gas.

“Person” means any individual,

 corporation,

partnership,

 association, State, municipality,

political subdivision of

 a State; any agency,

department,

 or instrumentality of the United States;

and any officer,

 agent,

 or employee thereof.

“Petroleum” means the crude oil removed from the earth

and the oils derived from tar sands,

 shale,

 and coal.

“Petroleum Liquid” means crude oil, condensate or any

119—4 92

31

finished or intermediate product manufactured

 at a

petroleum refinery,

 but not including

Number

 2 through

Number

 6 fuel oils as specified

 in ASTM D—396-69, gas

turbine fuel oils Numbers 2-GT through 4-GT as

 specified in ASTN D—2880-71 or diesel fuel oils Numbers

2—D and 4-D,

 as specified in ASTM D—975—68.

“Petroleum refinery” means any facility engaged

in

producing gasoline,

 kerosene,

 distillate fuel oils,

residual fuel oils,

 lubricants, or other products

through distillation of petroleum,

 or through

redistillation,

 cracking,

 or reforming of unfinished

petroleum derivatives.

“Pharmaceutical” means any compound or mixture,

 other

than food, used

 in the prevention,

 diagnosis,

alleviation,

 treatment,

 or cure of disease in human and

animal.

“Pharmaceutical coating operation” means

 a device in

which

 a coating is applied to

 a pharmaceutical,

including air drying or curing of the coating.

“Photochemically Reactive Material” means any organic

material with an aggregate of more than 20 percent of

its total volume composed of the chemical compounds

classified below or the composition of which exceeds

any of the following individual percentage composition

limitations.

 Whenever any photochemically reactive

material or any constituent of any organic material may

be classified

 from its chemical structure into more

than one of the above groups of organic materials

it

shall be considered as a member of the most reactive

group,

 that

 is, the group having the least allowable

percent of the total organic materials.

A combination of hydrocarbons, alcohols,

aldehydes,

 esters, ethers or ketones having an

olefinic or cyclo—olefinic

 types of unsaturation:

5 percent.

 This definition does not apply to

perchloroethylene or trichloroethylene.

A combination of aromatic compounds with eight

or

more carbon atoms to the molecule except

ethylbenzene:

 8 percent.

A combination of ethylbenzene, ketones having

branched hydrocarbon structures or toluene:

20

percent.

“Pigmented coatings” means opaque coatings containing

binders and colored pigments which are formulated to

119—493

32

conceal the wood surface either as an undercoat or

topcoat.

“Plant” means all of the pollutant-emitting activities

which belong to the same industrial grouping,

are

located on one or more contiguous or adjacent

properties,

 and are under the control of the same

person

 (or persons under common control),

 except the

activities of any marine vessel.

 Pollutant—emitting

activities shall be considered as part of the same

industrial grouping if they belong to the same “Major

Group”

 (i.e., which have the same two—digit code)

as

described in the “Standard Industrial Classification

 Manual,

 1987”

 (incorporated by reference in Section

219.112).

“Plasticizers” means a substance added to a polymer

composition to soften and add flexibility to the

product.

“Pneumatic Rubber Tire Manufacture” means the

production of pneumatic rubber tires with a bead

diameter up to but not including 20.0 inches and cross

section dimension up to 12.8 inches, but not including

specialty tires for antique or other vehicles when

produced on equipment separate from normal production

lines for passenger or truck type tires.

“Polystyrene Plant” means any plant using styrene to

manufacture polystyrene resin.

“Polystyrene Resin” means substance consisting of

styrene polymer and additives which

 is manufactured at

a polystyrene plant.

“Pressure Release” means the emission of materials

resulting from system pressure being greater than set

pressure of the pressure relief device.

“Pressure Tank” means

 a tank in which fluids are stored

at a pressure greater than atmospheric pressure.

“Prime coat” means the first of two or more coatings

applied to a surface.

“Prime surfacer coat” means a coating used to touch up

areas on the surface of automobile or light—duty truck

bodies not adequately covered by the prime coat before

application of the top coat.

 The prime surfacer coat

is applied between the prime coat and topcoat.

An

anti-chip coating applied to main body parts

 (e.g.,

rocker panels,

 bottom of doors and fenders,

 and leading

119—494

33

edge of roof)

 is a prime surfacer coat.

“Primers” means any coatings formulated and applied to

substrates to provide a firm bond between the substrate

and subsequent coats.

“Printing” means the application of words,

 designs, and

pictures to a substrate using ink.

“Printing

 line” means

 an operation consisting of

a

series of one or more roll printers and any associated

roll coaters, drying areas, and ovens wherein one or

more coatings are applied,

 dried,

 and/or cured.

“Process” means any stationary emission source other

than a fuel combustion emission source or an

incinerator.

“Process Unit” means components assembled to produce,

as intermediate or final products, one or more of the

chemicals listed in

35

 Ill.

 Adin.

 Code

219 Appendix A.

A process unit can operate independently

 if supplied

with sufficient feed or raw materials and sufficient

storage facilities for the product.

“Process Unit Shutdown” means a work practice or

operational procedure that stops production from a

process unit or part of a process unit.

 An unscheduled

work practice or operational procedure that stops

production from

 a process unit or part of a process

unit for less than 24 hours

 is not a process unit

shutdown.

 The use of spare components and technically

feasible bypassing of components without stopping

production

 is not a process unit shutdown.

“Production equipment exhaust system” means a system

for collecting and directing into the atmosphere

emissions of volatile organic material from reactors,

centrifuges,

 and other process emission sources.

“Publication rotogravure printing line” means a

rotogravure printing line

 in which coatings are applied

to paper which

 is subsequently formed into books,

magazines,

 catalogues,

 brochures,

 directories,

newspaper supplements,

 or other types of printed

material.

“Purged Process Fluid” means liquid or vapor from a

process unit that contains volatile organic material

and that results from flushing or cleaning the sample

line(s)

of

 a process unit so that an uncontaminated

sample may then be taken for testing or analysis.

119—495

34

“Reactor” means a vat,

 vessel,

 or other device in which

chemical reactions take place.

“Reasonably Available Control Technology

 (PACT)” means

the lowest emission limitation that an emission source

is capable of meeting by the application of control

 technology that

 is reasonably available considering

technological and economic feasibility.

“Refiner” means any person who owns,

 leases,

 operates,

controls,

 or supervises

 a refinery.

“Refinery Fuel Gas” means any gas which

 is generated by

a petroleum refinery process unit and which

is

combusted at the refinery, including any gaseous

mixture of natural gas and fuel gas.

“Refinery unit,

 process unit or unit” means a set of

components which are a part of a basic process

operation such as distillation, hydrotreating,

cracking,

 or reforming of hydrocarbons.

“Refrigerated condenser” means a surface condenser

in

which the coolant supplied to the condenser has been

cooled by a mechanical device, other than by a cooling

tower or evaporative spray cooling,

 such as

refrigeration unit or steam chiller unit.

“Reid vapor pressure” means the standardized measure

of

the vapor pressure of a liquid in pounds per square

inch absolute

 (Psia)

 at 100°F (37.8°C)

“Repair coatings” means coatings used to correct

imperfections or damage to furniture surface.

“Repaired” means,

 for the purpose of Subpart Q of this

Part,

 that equipment component has been adjusted,

or

otherwise altered,

 to eliminate a leak.

“Residual Fuel Oil” means

 fuel oils of grade No.

4,

5

and 6 as specified in detailed requirements

 for fuel

oils ASTM D—396—69

 (1971)

“Retail Outlet” means any gasoline dispensing facility

at which gasoline

 is sold or offered for sale for use

in motor vehicles.

“Roll coater” means an apparatus in which

 a uniform

layer of coating is applied by means of one or more

rolls across the entire width of a moving substrate

119—496

35

“Roll printer” means an apparatus used

 in the

application of words,

 designs,

 or pictures to a

substrate,

 usually by means of one or more rolls each

with only partial coverage.

“Roll printing” means the application of words,

designs, and pictures to a substrate usually by means

of a series of hard rubber or metal rolls each with

only partial coverage.

“Roller coating” means a method of applying a coating

to a sheet or strip in which the coating is transferred

by a roller or series of rollers.

“Rotogravure printing” means the application of words,

designs, and pictures to a substrate by means of a roll

printing technique in which the pattern to be applied

is recessed relative to the non-image area.

“Rotogravure printing line” means

 a printing line in

which each roll printer uses a roll with recessed areas

for applying an image to a substrate.

“Safety relief valve” means a valve which

 is normally

closed and which

 is designed to open in order to

relieve excessive pressures within a vessel or pipe.

“Sanding sealers” means any coatings formulated for and

applied to bare wood for sanding and to seal the wood

for subsequent application of varnish.

 To be

considered a sanding sealer

 a coating must be clearly

labelled as such.

“Sealer” means

 a coating containing binders which seals

wood prior to the application of the subsequent

coatings.

“Sensor” means

 a device that measures

 a physical

quantity or

the change in

 a physical quantity such

as

temperature,

 pressure,

 flow rate,

pH,

 or liquid level.

“Semi—transparent stains” means stains containing dyes

or semi—transparent pigments which are formulated to

enhance wood grain and change the color of the surface

but not to conceal the surface,

 including,

 but not

limited to, sap stain,

 toner, non—grain raising stains,

pad stain,

 or spatter stain.

“Set of safety relief valves” means one or more safety

relief valves designed to open

 in order to relieve

excessive pressures

 in the same vessel or pipe.

119—497

36

“Sheet basecoat” means a coating applied to metal when

the metal

 is in sheet form to serve as either the

exterior or interior of a can for either two—piece or

three—piece cans.

“Side—seam spray coat” means a

coating applied to the

seam of

 a three—piece can.

“Single coat” means one coating application applied to

a metal surface.

“Solvent” means a liquid substance that is used to

dissolve or dilute another substance.

“Solvent cleaning” means the process of cleaning soils

from surfaces by cold cleaning,

 open top vapor

degreasing,

 or conveyorized degreasing.

“Specified air contaminant” means any air contaminant

as to which this Part contains emission standards or

other specific

 limitations.

“Splash loading” means

 a method of loading

 a tank,

railroad tank car, tank truck, or trailer by use of

other than a submerged loading pipe.

“Stack” means

 a flue or conduit, free-standing or with

exhaust port above the roof of the building on which it

is mounted, by which

air contaminants are emitted into

the atmosphere.

“Standard conditions” means a temperature of 70°Fand

a

pressure of

 14.7 psia.

“Standard cubic foot

 (scf)” means the volume of one

cubic foot of gas at standard conditions.

“Standard Industrial

Classification Manual” means the

Standard Industrial Classification Manual

 (1987),

Superintendent of Documents,

 U.S. Government Printing

Office, Washington,

 DC 20402

 (incorporated by reference

in Section 219.112).

“Start—up” means the setting in operation of an

emission source for any purpose.

“Stationary emission source” and “Stationary source”

mean an emission source which

 is not self—propelled.

“Storage tank or storage vessel” means any stationary

tank,

 reservoir or container used for the storage of

VOL.

119—498

37

“Styrene Devolatilizer Unit” means equipment performing

the function of separating unreacted styrene monomer

and other volatile components from polystyrene in

a

vacuum devolatilizer.

“Styrene Recovery Unit” means equipment performing the

function of separating styrene monomer from other

 less

volatile components

 of the styrene devolatilizer unit’s

output.

 The separated styrene monomer may be reused as

a raw material

 in the polystyrene plant.

“Submerged loading pipe” means any discharge pipe or

nozzle which meets either of the following conditions:

Where the tank is filled from the top, the end of

the discharge pipe or nozzle must be totally

submerged when the liquid level

is

 15 cm

(6

 in.)

above the bottom of the tank.

Where the tank is filled from the side, the

discharge pipe or nozzle must be totally submerged

 when the liquid level

 is 46 cm

 (18 in.)

 above the

bottom of the tank.

“Substrate” means the surface onto which

 a coating

is

applied or into which a coating is impregnated.

“Surface condenser” means

 a device which removes a

substance from

 a gas stream by reducing the temperature

of the stream,

 without direct contact between the

coolant and the stream.

“Synthetic Organic Chemical or Polymer Manufacturing

Plant” means

 a plant that produces,

 as intermediates or

final products,

 one or more of the chemicals or

polymers listed in 35

 Ill.

 Adm. Code 219 Appendix A.

“Tablet coating operation” means

 a pharmaceutical

coating operation in which tablets are coated.

“Thirty—day rolling average” means any value

arithmetically averaged over any consecutive

thirty-days.

“Three—piece can” means a can which is made from a

rectangular sheet and two circular ends.

“Topcoat” means

 a coating applied in a multiple coat

operation other than prime coat,

 final repair coat,

or

prime surfacer coat.

119—499

38

“Topcoat operation” means all topcoat spray booths,

flash—off areas,

 and bake ovens

at

 a facility which are

used to apply, dry,

 or cure the final coatings

 (except

final off—line repair)

 on components of automobile or

light-duty truck bodies.

“Transfer efficiency” means the ratio of the amount of

coating solids deposited onto a part or product to the

total amount

 of coating solids used.

“Tread End Cementing” means the application of a

solvent—based cement to the tire tread ends.

“True vapor pressure” means the equilibrium partial

pressure exerted by a volatile organic liquid as

determined in accordance with methods described

in

American Petroleum Institute Bulletin 2517,

“Evaporation Loss From Floating Roof Tanks,” second

edition, February 1980 (incorporated by reference in

Section 219.112).

“Turnaround” means the procedure of shutting down an

operating refinery unit,

 emptying gaseous and liquid

contents to do inspection, maintenance and repair work,

and putting the unit back into production.

“Two—piece can” means a can which

 is drawn from a

shallow cup and requires only one end to be attached.

“Undercoaters” means any coatings formulated for and

applied to substrates to provide

 a smooth surface for

subsequent coats.

“Undertread Cementing” means the application of

a

solvent—based cement to the underside of

 a tire tread.

“Unregulated safety relief valve” means a safety relief

valve which cannot be actuated by a means other than

high pressure

 in the pipe or vessel which

 it protects.

“Vacuum producing system” means any reciprocating,

rotary,

 or centrifugal blower or compressor or any jet

ejector or device that creates suction from a pressure

below atmospheric and discharges against a greater

pressure.

“Valves not externally regulated” means valves that

have no external controls,

 such as in—line check

valves.

“Vapor balance system” means any combination of pipes

or hoses which creates a closed system between the

119—500

39

vapor spaces of an unloading tank and a receiving tank

such that vapors displaced from the receiving tank are

transferred to the tank being unloaded.

“Vapor collection system” means all piping,

 seals,

hoses, connections, pressure—vacuum vents,

 and other

possible sources between the gasoline delivery vessel

and the vapor processing unit and/or the storage tanks

and vapor holder.

“Vapor control system” means any system that limits or

prevents release to the atmosphere of organic material

in the vapors displaced from a tank during the transfer

of gasoline.

“Vapor—Mounted Primary Seal” means

 a primary seal

mounted with an air space bounded by the bottom of the

primary seal, the tank wall,

 the liquid surface and the

floating roof.

“Vapor recovery system” means

 a vapor gathering system

 capable of collecting all VON vapors and gases

discharged from the storage tank and a vapor disposal

system capable of processing such VOM

vapors and gases

so as to prevent their emission to the atmosphere.

“Vehicle” means a device by which any person or

property may be propelled,

 moved,

 or drawn upon

a

highway, excepting a device moved exclusively by human

power or used exclusively upon stationary rails or

tracks.

“Vinyl coating” means any topcoat or printing ink

applied to vinyl coated fabric or vinyl sheets.

 Vinyl

coating does not include plastisols.

“Vinyl coating facility” means

 a facility that includes

one or more vinyl coating line(s).

“Vinyl coating line” means a coating line

 in which any

protective, decorative or functional coating

 is applied

onto vinyl coated fabric or vinyl sheets.

“Volatile organic liquid” means any substance which is

liquid at storage conditions and which contains

volatile organic compounds.

“Volatile organic material

 (VOM)

 or volatile organic

compound (VOC)” means any organic compound which

participates

 in atmospheric photochemical reactions.

This includes any organic compound other than the

following compounds:

 methane,

 ethane, methyl

119—501

40

chloroform

 (1,1,1—trichloroethane),

 CFC—1l3

(trichlorotrifluoroethane),

 methylene chloride

(dichloromethane), CFC-ll (trichlorofluoromethane),

CFC—l2

 (dichlorodifluoromethane), CFC—22

(chlorodifluoromethane),

 FC—23

 (trifluoromethane),

CFC-1l4

 (dichlorotetrafluoroethane), CFC—l15

(chloropentafluoroethane), HCFC—l23

(dichlorotrifluoroethane), HFC-134a

(tetrafluoroethane),

 HCFC-l4lb (dichlorofluoroethane)

and HCFC-l42b (chlorodifluoroethane).

 These compounds

have been determined to have negligible photochemical

reactivity.

For purposes of determining compliance with emission

limits, VOC will be measured by the approved test

methods.

 Where such a method also inadvertently

measures compounds with negligible photochemical

reactivity,

 an owner or operator may exclude these

negligibly reactive compounds when determining

compliance with an emissions standard.

“Volatile Petroleum Liquid” means any petroleum liquid

with a true vapor pressure that

 is greater than 1.5

psia

 (78 millimeters of mercury)

 at standard

conditions.

“Wash coat” means

 a coating containing binders which

seals wood surfaces,

 prevents undesired staining,

and

controls penetration.

“Wastewater

 (Oil/Water) Separator” means any device or

piece

 of equipment which utilizes the difference

in

density between oil and water to remove oil and

associated chemicals of water,

 or any device, such as

a

flocculation tank or

 a clarifier,

 which removes

petroleum derived compounds from waste water.

“Web” means a substrate which is printed in continuous

roll—fed presses.

“Wood furniture” means room furnishings including

cabinets

 (kitchen,

 bath, and vanity),

 tables,

 chairs,

beds,

 sofas,

 shutters,

 art objects, wood paneling,

 wood

flooring, and any other coated furnishings made of

wood, wood composition,

 or fabricated wood materials.

“Wood furniture coating facility” means

 a facility that

includes one or more wood furniture coating line(s).

“Wood furniture coating line” means a coating line

in

which any protective,

 decorative,

 or functional coating

is applied onto wood furniture.

119—502

41

“Woodworking” means the shaping,

 sawing,

 grinding,

smoothing, polishing,

 and making into products of any

form or shape of wood.

Section 219.105

 Testing Methods and Procedures

a)

 Coatings,

 Inks and Fountain Solutions

The following test methods and procedures

 shall be used

to determine compliance of applied coatings,

 inks,

and

fountain solutions with the limitations set forth in

this Part.

1)

 Sampling:

 Samples collected for analyses shall be

one—liter taken into a one-liter container at

a

location and time such that the sample will

be

representative

 of the coating as applied

 (i.e.,

the sample shall include any dilution solvent or

other VON added during the manufacturing process).

The container must be tightly sealed immediately

after the sample is taken.

 Any solvent or other

VOM added after the sample

 is taken must be

measured and accounted for in the calculations

in

subsection

 (a) (3).

 For multiple package coatings,

separate samples of each component shall be

obtained.

 A mixed sample shall not be obtained as

it will cure in the container.

 Sampling

procedures shall follow the guidelines presented

in:

A)

 ASTN D3925-8l(1985)

 standard practice for

sampling liquid paints and related pigment

coating. This practice is incorporated by

reference in Section 219.112.

B)

 ASTM E300-86 standard practice for sampling

industrial chemicals. This practice is

incorporated

 by reference

 in Section 219.112.

2)

 Analyses:

 The applicable analytical methods

specified below shall be used to determine the

composition of coatings,

 inks,

 or fountain

solutions as applied.

A)

 Method 24

 of 40 CFR 60, Appendix

A,

incorporated by reference in Section 219.112,

shall be used to determine the VON content

and density of coatings.

 If it

is

demonstrated to the satisfaction of the

Agency and the USEPA that plant coating

formulation data are equivalent to Method 24

119—503

42

results,

 formulation data may be used.

In

the event of any inconsistency between

a

Method 24 test and a facility’s formulation

data, the Method 24 test will govern.

B)

 Method 24A of 40 CFR Part 60, Appendix A,

incorporated by reference

 in Section 219.112,

shall be used to determine the VON content

and density of rotogravure printing inks and

related coatings.

 If it

 is demonstrated to

the satisfaction of the Agency and USEPA that

the plant coating formulation data are

equivalent to Method 24A results, formulation

data may be used.

 In the event of any

inconsistency between a Method 24A test and

a

facility’s formulation data,

 the Method 24A

test will govern.

C)

 The following ASTM methods are the analytical

procedures for determining VON:

 ASTM Dl475-85: Standard test method for

 density of paint, varnish,

 lacquer and

related products.

 This test method

is

incorporated by reference

 in Section

219.112.

ii)

 ASTM D2369-87: Standard test method for

volatile content of a coating. This test

method is incorporated by reference

in

Section 219.112.

iii) ASTM D3792—86: Standard test method for

water content of water—reducible paints

by direct injection into a gas

chromatograph.

 This test method

is

incorporated by reference in Section

219.112.

iv)

 ASTN D40l7—81(1987):

 Standard test

method for water content in paints and

paint materials by the Karl Fischer

method. This test method

 is incorporated

by reference in Section 219.112.

v)

 ASTM D4457-85: Standard test method for

determination of dichloromethane and

1,1,1, trichloroetharie

 in paints and

coatings by direct injection into

 a gas

chromatograph.

 (The procedure

delineated above can be used to develop

protocols for any compounds specifically

119—504

43

exempted from the definition of VON.)

This test method is incorporated by

reference

 in Section 219.112.

vi)

 ASTM D2697—86: Standard test method for

volume non—volatile matter in clear or

pigmented coatings.

 This test method is

incorporated by reference in Section

219.112.

vii) ASTM D3980-87:

 Standard practice for

interlaboratory testing of paint and

related materials. This practice

is

incorporated by reference in Section

219.112.

viii)

 ASTM E180—85: Standard practice for

determining the precision data of

ASTM methods for analysis of and

testing of industrial chemicals.

This practice is incorporated by

reference

 in Section 219.112.

ix)

 ASTM D2372-85:

 Standard method of

separation of vehicle from

solvent-reducible paints. This method is

incorporated by reference in Section

219.112.

D)

 Use of an adaptation to any of the analytical

methods specified in subsections

 (a) (2) (A),

(B), and

 (C) may not be used unless approved

by the Agency and USEPA.

 An owner or

operator must submit sufficient documentation

for the Agency and USEPA to find that the

analytical methods specified in subsections

(a) (2) (A),

 (B),

and

(C)

 will yield inaccurate

results and that the proposed adaptation

is

appropriate.

3)

 Calculations:

 Calculations

 for determining the

VON content, water content and the content of any

compounds which are specifically exempted from the

definition of VON of coatings,

 inks and fountain

solutions as applied shall follow the guidance

provided

 in the following documents.

A)

 “A Guide for Surface Coating Calculation”,

EPA—340/1-86-0l6,

 incorporated by reference

in Section 219.112.

B)

 “Procedures for Certifying Quantity of

119—505

44

Volatile Organic Compounds Emitted by Paint,

Ink and Other Coatings”

 (revised June 1986),

EPA—450/3—84-019,

 incorporated by reference

in Section 219.112.

C)

 “A Guide for Graphic Arts Calculations”,

August

 1988,

 EPA—340/1-88—003,

 incorporated

by reference in Section 219.112

b)

 Automobile or Light-Duty Truck Test Protocol

The protocol for testing,

 including determining the

transfer efficiency,

 of coating applicators at topcoat

coating operations at an automobile assembly facility

shall follow the procedure

in:

 “Protocol for

Determining the Daily Volatile Organic Compound

Emission Rate of Automobile and Light-Duty Truck

Topcoat Operations”,

 December 1988,

 EPA—450/3-88-0l8,

incorporated by reference in Section 219.112.

c)

 Capture System Efficiency Test Protocols

1)

 Applicability

The requirements

 of subsection

 (c) (2) shall apply

to all VOM emitting processes employing capture

 equipment (e.g.,hoods,

 ducts),

 except those cases

noted below.

A)

If

 a source installs a permanent total

enclosure

 (PTE) that meets Agency and USEPA

specifications, and which directs all VON to

a control device,

 then the source

 is exempted

from the requirements described in subsection

(c) (2).

 The Agency and USEPA specifications

to determine whether a structure

is

considered

 a PTE are given

 in Procedure T of

Appendix B of this Part.

 In this instance,

the capture efficiency

 is assumed to be

100

percent and the source is still required to

measure control efficiency using appropriate

test methods as specified in subsection

 (d).

B)

If

 a source uses

 a control device designed to

collect and recover VON (e.g., carbon

adsorber),

 an explicit measurement

 of capture

efficiency

 is not necessary provided that the

conditions given below are met.

 The overall

control of the system can be determined by

directly comparing the input liquid VON to

the recovered liquid VON.

 The general

procedure for use in this situation

 is given

119—506

45

in 40 CFR 60.433,

 incorporated by reference

 in Section 219.112, with the following

additional restrictions:

i)

 The source must be able to equate

solvent usage with solvent recovery on a

24-hour

 (daily)

 basis, rather than a

30-day weighted average, within 72 hours

following the 24—hour period.

In

addition,

 one of the following two

criteria must be met:

ii)

 The solvent recovery system

 (i.e.,

capture and control system)

 must be

dedicated to a single process

 line

(e.g., one process line venting to a

carbon adsorber system),

or

iii)

 If the solvent recovery system controls

multiple process

 lines, then the source

must be able to demonstrate that the

overall control

 (i.e., the total

recovered solvent VON divided by the sum

of liquid VON input to all process lines

venting to the control system) meets

or

exceeds the most stringent standard

applicable for any process line venting

to the control system.

2)

 Specific Requirements

The capture efficiency of a process line shall

be

measured using one of the four protocols given

below.

 Any error margin associated with

 a test

protocol may not be incorporated

 into the results

of a capture efficiency test.

 If these techniques

are not suitable for a particular process, then

 the source may use an alternative capture

efficiency protocol, provided that the alternative

protocol is approved by the Agency and approved by

the USEPA as a SIP revision.

A)

 Gas/gas method using temporary total

enclosure

 (TTE).

 The Agency and USEPA

specifications to determine whether a

temporary enclosure is considered a TTE are

given

 in Procedure T of Appendix B of this

Part.

 The capture efficiency equation to be

used for this protocol is:

CE

 Gw/(Gw

Fw)

119—50

7

46

where:

CE

 capture efficiency,

 decimal

fraction

Gw

 mass of VON captured and delivered

to control device using

 a TTE

Fw

 mass of fugitive VON that escapes

from a TTE

Procedure G.2 contained in Appendix B of this

Part is used to obtain Gw.

 Procedure F.1

in

Appendix B of this Part is used to obtain

Fw.

B)

 Liquid/gas method using TTE.

 The Agency and

USEPA specifications to determine whether

a

temporary enclosure

 is considered a TTE are

given

 in Procedure T of Appendix B of this

 Part.

 The capture efficiency equation to be

used for this protocol

is:

CE

(L

 F)/L

where:

CE

 capture efficiency,

 decimal

fraction

L

 mass of liquid VOM input to

process

Fw

 mass of fugitive VOM that escapes

from a TTE

Procedure L contained in Appendix B of this

Part is used to obtain

L.

 Procedure F.l

in

Appendix B of this Part is used to obtain

Fw.

C)

 Gas/gas method using the building or room

(building or room enclosure)

 in which the

affected source is located as the enclosure

and in which “F” and “G” are measured while

operating only the affected facility.

All

fans and blowers in the building or room must

be operated as they would under normal

production.

 The capture efficiency equation

to be used for this protocol

is:

CE

 G/(G

FB)

where: CE

 capture efficiency,

 decimal

fraction

G

 mass of VON captured and

119—508

47

delivered to control device

=mass of fugitive VON that escapes

from building enclosure

Procedure G.2 contained

 in Appendix B of this

Part is used to obtain G.

 Procedure F.2 in

Appendix B of this Part is used to obtain

FB.

D)

 Liquid/gas method using the building or room

(building or room enclosure)

 in which the

affected source

 is located as the enclosure

and in which

 “F” and “L” are measured while

operating only the affected facility.

All

fans and blowers

 in the building or room must

be operated as they would under normal

production.

 The capture efficiency equation

to be used for this protocol

is:

CE

=

(L

 FB)/L

where:

CE

 capture efficiency,

 decimal

fraction

L

 mass of liquid VON input to

process

FB =mass of fugitive VON that escapes

from building enclosure

Procedure L contained

 in Appendix B of this

section is used to obtain

L.

 Procedure F.2

in Appendix B of this section

 is used to

obtain FB.

3)

 Recordkeeping and Reporting

A)

 All affected facilities must maintain a

copy

of the capture efficiency protocol submitted

to the Agency and the USEPA on file.

All

results of the appropriate test methods and

capture efficiency protocols must be reported

to the Agency within sixty

 (60)

 days of the

test date.

 A copy of the results must be

kept on file with the source for a period of

three

 (3) years.

B)

 If any changes are made to capture or control

equipment,

 then the source is required to

notify the Agency and the USEPA of these

changes and a new test may be required by the

119—509

48

Agency or the USEPA.

C)

 The source must notify the Agency 30 days

prior to performing any capture efficiency or

control test.

 At that time,

 the source must

notify the Agency which capture efficiency

protocol and control device test methods will

be used.

D)

 Sources utilizing a PTE must demonstrate that

this enclosure meets the requirement given

in

Procedure T

 (in Appendix B of this Part)

for

a PTE during any testing of their control

device.

E)

 Sources utilizing a TTE must demonstrate that

their TTE meets the requirements given

in

Procedure T

 (in Appendix B of this Part)

for

a TTE during testing of their control device.

The source must also provide documentation

that the quality assurance criteria for a TTE

 have been achieved.

d)

 Control Device Efficiency Testing and Monitoring

1)

 The control

device efficiency shall be determined

by simultaneously measuring the inlet and outlet

gas phase VOM concentrations and gas volumetric

flow rates

 in accordance with the gas phase test

methods specified

 in subsection

 (f).

2)

 Any owner or operator that uses an afterburner or

carbon adsorber to comply with any Section of this

Part shall use USEPA approved continuous

monitoring equipment which

 is installed,

calibrated, maintained,

 and operated according to

vendor specifications

 at all times the afterburner

or carbon adsorber

is

 in use.

 The continuous

monitoring equipment must monitor the following

parameters:

A)

 Combustion chamber temperature of each

afterburner.

B)

 Temperature rise across each catalytic

afterburner bed or VON concentration of

exhaust.

C)

 The VON concentration of each carbon

adsorption bed exhaust.

e)

 Overall Efficiency

119—5 10

49

1)

 The overall efficiency of the emission control

system shall be determined as the product of the

capture system efficiency and the control device

efficiency or by the liquid/liquid test protocol

 as specified in 40 CFR 60.433,

 incorporated by

reference in Section 219.112,

 (and revised by

subsection

 (c) (1) (B) for each solvent recovery

system.

 In those cases in which the overall

efficiency

 is being determined for an entire

 line,

the capture efficiency used to calculate the

product of the capture and control efficiency

is

the total capture efficiency over the entire

 line.

2)

 For coating lines which are both chosen by the

owner or operator to comply with Section

219.207(a),

 (d),

 (e),

 (f),

or

(g)

 by the

alternative in Section 219.207(b) (2)

 and meet the

criteria allowing them to comply with Section

219.207 instead

 of Section 219.204, the overall

efficiency of the capture system and control

device,

 as determined by the test methods and

procedures specified in subsections

 (c),

 (d) and

(e) (1),

 shall be no less than the equivalent

overall efficiency which shall be calculated by

the following equation:

E

 (VON

 VON1

 /VOMa)

 x 100

where:

E

 Equivalent overall efficiency of the

capture system and control device as a

percentage,

VOMa

 Actual VON content of

 a coating,

 or the

daily-weighted average VOM content of

two or more coatings

 (if more than one

coating is used), as applied to the

subject coating line as determined by

the applicable test methods and

procedures specified

 in subsection

(a) (4) (i)

 of this Part in units of kg

VOM/l

 (lb VON/gal)

 of coating solids

as

applied,

VON1

 The VOM emission limit specified in

Section 219.207(a)

or

(b)

 in units of kg

VON/i

 (lb VON/gal)

 of coating solids

as

applied.

119—511

50

f)

 Volatile Organic Material Gas Phase Source Test Methods

The methods in

 40 CFR Part 60, Appendix A,

 incorporated

by reference in Section 219.112 delineated below shall

be used to determine control device efficiencies.

1)

 40 CFR Part

 60, Appendix A, Method

18,

 25 or

 25A,

incorporated by reference in Section 219.112

as

appropriate to the conditions at the site,

 shall

be used to determine VON concentration.

 Method

selection shall be based on consideration of the

diversity of organic species present and their

total concentration and on consideration of the

potential presence of interfering gases.

 Except

as indicated in subsections

 (f) (1) (A) and

(B)

below,

 the test shall consist of three separate

runs, each lasting a minimum of 60 mm,

 unless the

Agency and the USEPA determine that process

variables dictate shorter sampling times.

A)

 When the method

 is to be used to determine

the efficiency of a carbon adsorption system

with a common exhaust stack for all the

individual adsorber vessels, the test shall

consist

 of three separate runs,

 each

coinciding with one or more complete

sequences through the adsorption cycles of

all the individual adsorber vessels.

B)

 When the method is to be used to determine

the efficiency of a carbon adsorption

 system

with individual exhaust stacks for each

adsorber vessel,

 each adsorber vessel shall

be tested individually.

 The test for each

adsorber vessel shall consist of three

separate runs.

 Each run shall coincide with

one or more complete adsorption cycles.

2)

 40 CFR Part

 60, Appendix A, Method

 1 or 1A,

incorporated by reference in Section 219.112,

shall be used for sample and velocity traverses.

3)

 40 CFR Part 60, Appendix

 A, Method

2,

2A,

 2C or

2D, incorporated by reference

 in Section 219.112,

shall be used for velocity and volumetric

 flow

rates.

4)

 40 CFR Part 60, Appendix A, Method

3,

 incorporated

by reference in Section 219.112, shall be used for

gas analysis.

5)

 40 CFR Part 60, Appendix

 A, Method

4,

 incorporated

119—512

51

by reference in Section 219.112, shall be used for

stack gas moisture.

6)

 40 CFP Part 60, Appendix A, Methods

2,

2A,

2C,

2D,

3 and 4,

 incorporated by reference in Section

219.112, shall be performed,

 as applicable,

at

least twice during each test run.

7)

 Use of an adaptation to any of the test methods

specified in subsections

 (f) (1),

 (2),

 (3),

 (4),

(5) and

 (6) may not be used unless approved by the

Agency and the USEPA.

 An owner or operator must

submit sufficient documentation for the Agency and

the USEPA to find that the test methods specified

in subsections

 (f)(1),

 (2),

 (3),

 (4),

 (5) and

(6)

will yield inaccurate results and that the

proposed adaptation

 is appropriate.

g)

 Leak Detection Methods for Volatile Organic Material

Owners or operators required by this Part to carry out

a

 leak detection monitoring program shall comply with

 the following requirements:

1)

 Leak Detection Monitoring

A)

 Monitoring shall comply with 40 CFR 60,

Appendix A, Method 21, incorporated by

reference

 in Section 219.112.

B)

 The detection instrument shall meet the

performance criteria of Method 21.

C)

 The instrument shall be calibrated before use

on each day of its use by the methods

specified in Method 21.

D)

 Calibration gases shall be:

i)

 Zero air

 (less than

loppm of hydrocarbon

in air);

and

ii)

 A mixture of methane or n—hexane and air

at a concentration of approximately,

but

no less than,

 10,000 ppm methane or

n—hexane.

E)

 The instrument probe shall be traversed

around all potential leak interfaces as close

possible as described

 in Method 21.

2)

 When equipment

 is tested for compliance with no

119—5 13

52

detectable emissions as required, the test shall

comply with the following requirements:

A)

 The requirements of subsections

 (g) (1) (A)

through

 (g) (1) (E) above shall apply.

B)

 The background level shall be determined as

set forth in Method 21.

3)

 Leak detection tests shall be performed consistent

with:

A)

 “APTI Course SI 417 controlling Volatile

Organic Compound Emissions from Leaking

Process Equipment”,

 EPA-450/2—82—0l5,

incorporated by reference

 in Section 219.112.

B)

 “Portable Instrument User’s Manual for

Monitoring VOC Sources”,

 EPA-340/l—86-015,

incorporated by reference in Section 219.112.

C)

 “Protocols

 for Generating Unit-Specific

Emission Estimates for Equipment Leaks of VOC

and VHAP”, EPA-450/3-88-OlO,

 incorporated by

reference in Section 219.112.

D)

 “Petroleum Refinery Enforcement Manual”,

EPA—340/l—80—008,

 incorporated by reference

in Section 219.122.

h)

 Bulk Gasoline Delivery System Test Protocol

1)

 The method for determining the emissions of

gasoline from

 a vapor recovery system are

delineated

 in 40 CFR 60, Subpart XX,

 Section

60.503,

 incorporated by reference in Section

219.112.

2)

 Other tests shall be performed consistent with:

A)

 “Inspection Manual for Control of Volatile

Organic Emissions from Gasoline Marketing

Operations:

 Appendix D”, EPA-340/l-80-012,

incorporated by reference in Section 219.112.

B)

 “Control of Hydrocarbons from Tank Truck

Gasoline Loading Terminals: Appendix A”,

EPA-450/2-77-026,

 incorporated by reference

in Section 219.112.

Section 219.106

 Compliance Dates

119—514

53

a)

 Compliance with the requirements

 of all rules

is

required by May

1,

 1992,

 or sixty days after a final

decision by a federal court of the general appeal of

the FIP (Illinois Environmental Regulatory Group

v.

USEPA, No. 90—2778

 (and Consolidated Cases)

 (7th

Cir.)), whichever

 is later, consistent with the

provisions of Section 219.103.

b)

 Compliance with the requirements

 of provisions of this

part specifically applicable to a category of sources

which

 is the same as any of the individual appeals of

the FIP shall be required by May

1,

 1992,

 or sixty days

following a final decision by a federal court

 of the

appeal of the FIP impacting the specific category of

sources, whichever

 is later, consistent with the

provisions of Section 219.103.

Section 219.107

 Afterburners

The operation of any natural gas fired afterburner and capture

system used to comply with this Part

 is. not required during the

period of November

 1 of any year to April

 1 of the following year

provided that the operation of such devices is not required for

purposes of occupational safety or health,

 or for the control

of

 toxic substances,

 odor nuisances,

 or other regulated pollutants.

Section 219.108

 Exemptions, Variations,

 and Alternative Means

of Control

 or Compliance Determinations

Notwithstanding the provisions of any other Sections of this

Part,

 any exemptions, variations or alternatives to the control

requirements, emission limitations,

 or test methods set forth in

this Part shall be effective only when approved by the Agency and

approved by the USEPA as a SIP revision.

Section 219.109

 Vapor Pressure of Volatile Organic Liquids

a)

 If the VOL consists of only a single compound,

the

vapor pressure shall be determined by ASTM Method

D2879-86 (incorporated by reference in Section 219.112)

or the vapor pressure may be obtained from a published

source such as:

 Boublik,

 T..,

V.

 Fried and E.

 Hala,

“The Vapor Pressure of Pure Substances,” Elsevier

Scientific Publishing Co., New York (1973);

 Perry’s

Chemical Engineer’s Handbook, McGraw-Hill Book Company

(1984); CRC Handbook of Chemistry and Physics, Chemical

Rubber Publishing Company

 (1986-87); and Lange’s

Handbook of Chemistry,

 John A.

 Dean,

 editor,

McGraw-Hill Book Company

 (1985).

b)

 If the VOL is a mixture, the vapor pressure shall be

determined by ASTM Method D2879—86

 (incorporated by

119—5 15

reference in Section 219.112)

 or by the following

equation:

Pvo1

jJPi Xi

where:

 Total vapor pressure of the

mixture,

n

 Number of components in the

mixture,

i

 Subscript denoting an individual

component,

P1

 Vapor pressure of a component

determined in accordance with

Subpart A of this Part

 Mole fraction of the component

in

the total mixture.

Section 219.110

 Vapor Pressure of Organic Material or Solvent

a)

 If the organic material or solvent consists of only a

single compound, the vapor pressure shall be determined

by

ASTM

 Method D2879-86

 (incorporated by reference

in

Section 219.112)

 or the vapor pressure may be obtained

from a published source such as:

 Boublik,

T.,

V.

 Fried

and E.

 Hala,

 “The Vapor Pressure of Pure Substances,”

Elsevier Scientific Publishing Co., New York

 (1973);

Perry’s Chemical Engineer’s Handbook, McGraw-Hill Book

Company

 (1984); CRC Handbook of Chemistry and Physics,

Chemical Rubber Publishing Company

 (1986-87);

and

Lange’s Handbook of Chemistry,

 John

 A. Dean,

 editor,

McGraw-Hill Book Company

 (1985).

b)

 If the organic material or solvent is

in

 a mixture made

up of both organic material compounds and compounds

which are not organic material,

 the vapor pressure

shall be determined by the following equation:

SP.X.

P

SX~

119—5 16

55

i=1

where:

~om

Total vapor pressure of the portion of

the

mixture which is composed of organic

material,

n

 Number of organic material components

the mixture,

i

 Subscript denoting

an individual

component,

P1

 =Vapor

pressure

of an organic material

component determined

 in accordance with

Subpart A of this Part,

=Mole fraction of the organic material

component of the

total mixture.

 If the organic material or solvent is

 in a mixture made

up of only organic material compounds,

 the vapor

pressure shall be determined by ASTM Method D2879-86

(incorporated by reference

 in Section 219.112)

 or by

the above equation.

Section 219.111

 Vapor Pressure of Volatile Organic Material

a)

 If the VON consists of

only

 a single compound,

the

vapor pressure shall be determined by ASTN Method

D2879-86

 (incorporated by reference in Section 219.112)

or the vapor pressure may be obtained from a published

source such as:

 Boublik,

 T..,

V.

 Fried and E.

 Hala,

“The Vapor Pressure of Pure Substances,” Elsevier

Scientific Publishing

 Co., New York

 (1973); Perry’s

Chemical Engineer’s Handbook, NcGraw-Hill Book Company

(1984); CRC Handbook

of

Chemistry and Physics,

 Chemical

Rubber Publishing Company

 (1986-87);

 and Lange’s

Handbook of Chemistry,

 John A. Dean,

 editor,

McGraw-Hill Book Company

 (1985).

b)

 If the VON is in

a mixture made

up of both VOM

compounds and compounds which are not VOM,

 the vapor

pressure

shall be determined by the following equation:

~PiXi

~vOn1

i=1

n

119—517

56

SXi

1=1

where:

~vom

 Total vapor pressure of the portion of

the mixture which is composed of VON,

n

 Number of VOM components

 in the mixture,

i

 Subscript denoting an individual

component,

P~

 Vapor pressure of a VON component

determined

 in accordance with Subpart A

of this Part,

X1

 Mole fraction of the VON component of

the total mixture.

c)

 If the VON is in

 a mixture made up of only VOM

compounds,

 the vapor pressure shall

 be determined

ASTM Method D2879-86

 (incorporated by reference

in

Section 219.112)

 or by the above equation.

Section 219.112

 Incorporations by Reference

The foLlowing materials are incorporated by reference:

a)

 American Society for Testing and Materials,

 1916 Race

Street, Philadelphia,

 PA 19103:

1)

 ASTM D2879—86

2)

 ASTM D323—82

3)

 ASTN D86—82

 ASTM D—369—69

 (1971)

5)

 ASTM D—396—69

6)

 ASTM D2880—7l

7)

 ASTM D—975—68

8)

 ASTM D3925—8l (1985)

9)

 ASTM E300—86

10)

 ASTM D1475—85

11)

 ASTM D2369—87

12)

 ASTM D3792—86

13)

 ASTM D4017—8l

 (1987)

14)

 ASTM D4457—85

15)

 ASTM D2697—86

16)

 ASTM D3980—87

17)

 ASTM E18O—85

18)

 ASTN D2372—85

19)

 ASTM D97—66

119—518

57

20)

 ASTM E—168

21)

 ASTN E—169

22)

 ASTN E—260

23)

 ASTM D2504—83

24)

 ASTM D2382—83

b)

 Standard Industrial Classification Manual, published by

Executive Office of the President,

 Office of Management

and Budget,

 Washington,

 D.C.,

 1987.

c)

 American Petroleum Institute Bulletin 2517,

“Evaporation Loss From Floating Roof Tanks”,

 Second

ed., February,

 1980.

d)

 40 CFR 60

 (July

1,

 1990)

e)

 40 CFR 61

 (July

1,

 1990)

f)

 40 CFR 50

 (July

1,

 1989).

g)

 40 CFR 51

 (July

1,

 1989)

h)

 40 CFR 52

 (July

1,

 1989)

i)

 United States Environmental Protection Agency,

Washington,

 D.C.,

 EPA—340/l-86-0l6.

j)

 United States Environmental Protection Agency,

Washington D.C.,

 EPA—450/3—84—0l9.

k)

 United States Environmental Protection Agency,

Washington D.C.,

 EPA—340/1—88-003.

1)

 United States Environmental Protection Agency,

Washington D.C.,

 EPA—450/3-88-OlB.

in)

 United States Environmental Protection Agency,

Washington,

 D.C.,

 EPA—450/2—78—029.

n)

 United States Environmental Protection Agency,

Washington,

 D.C.,

 EPA—450/2-78—OSl.

o)

 United States Environmental Protection Agency,

Washington,

 D.C.,

 EPA—450/3—82—009.

SUBPART B:

 ORGANIC EMISSIONS FROM STORAGE AND LOADING OPERATIONS

Section 219.121

 Storage Containers

No person shall cause or allow the storage of any VOL with a

vapor pressure of 17.24 kPa

 (2.5 psia)

 or greater at 294.3oK

(7OoF)

 or any gaseous organic material in any stationary tank,

119—5 19

58

reservoir or other container

 of more than 151 cubic meters

(40,000

 gal) capacity unless such tank,

 reservoir or other

container:

a)

Is

 a pressure tank capable

 of withstanding the vapor

pressure of such

 liquid or the pressure of the gas,

so

as to prevent vapor or gas loss to the atmosphere at

 all times;

or,

b)

 Is designed and equipped with one of the following

vapor loss control devices:

1)

 A floating roof which rests on the surface of the

VOL and is equipped with

 a closure seal or seals

between the roof edge and the tank wall.

 Such

floating roof shall not be permitted if the VOL

has a vapor pressure of 86.19 kPa

 (12.5 psia)

or

greater at 294.3°K (70°F).

 No person shall cause

or allow the emission of air contaminants

 into the

atmosphere from any gauging or sampling devices

attached to such tanks, except during sampling or

maintenance operations.

2)

 A vapor recovery system consisting of:

A)

 A vapor gathering system capable of

collecting 85

 or more of the uncontrolled

VON that would be otherwise emitted to the

atmosphere;

 and,

B)

 A vapor disposal system capable of processing

such VON so as to prevent its emission to the

atmosphere.

 No person shall cause

 or allow

the emission of air contaminants

 into the

atmosphere from any gauging or sampling

devices attached to such tank,

 reservoir or

other container except during sampling.

3)

 Other equipment or means

 of equal efficiency

approved by the Agency according to the provisions

of 35

 Ill.

 Adm.

 Code 201,

 and further processed

consistent with Section 219.108.

Section 219.122

 Loading Operations

a)

 No person shall cause or allow the discharge of more

than 3.6 kg/hr

 (8 lbs/hr)

 of organic material into the

atmosphere during the loading of any organic material

from the aggregate loading pipes

 of any loading

facility having through-put of greater than 151 cubic

meters per day

 (40,000 gal/day)

 into any railroad tank

car, tank truck or trailer unless such loading facility

119—520

59

is equipped with submerged loading pipes, submerged

fill or a device that is equally effective in

controlling emissions and is approved by the Agency

according to the provisions of 35

 Ill.

 Adm.

 Code 201,

and further processed consistent with Section 219.108.

b)

 No person shall cause or allow the loading of any

organic material into any stationary tank having

a

storage capacity of greater than 946 1

 (250 gal),

unless such tank is equipped with a permanent submerged

loading pipe, submerged fill or an equivalent device

approved by the Agency according to the provisions

of

35

 Ill. Adm.

 Code 201, and further processed consistent

with Section 219.108,

 or unless such tank

 is a pressure

tank as described

 in Section 219.121(a)

 or is fitted

with a recovery system as described

 in Section

219.121(b) (2).

c)

 Exception:

 If no odor nuisance exists the limitations

of this Section shall only apply to the loading

 of VOL

with a vapor pressure of 17.24 kPa

 (2.5 psia)

or

greater at 294.3°K

(7OoF).

Section 219.123

 Petroleum Liquid Storage Tanks

a)

 The requirements

 of subsection

(b)

 shall not apply to

any stationary storage tank:

1)

 Equipped before January

1,

 1979 with one of the

vapor loss control devices specified

 in Section

219.121(b), except Section 219.121(b) (1);

2)

 With

 a capacity of less than 151.42 cubic meters

(40,000 gal);

3)

 With

 a capacity of less than 1,600 cubic meters

(422,400 gal)

 and used to store produced crude oil

and condensate prior to custody transfer;

4)

 With a capacity of less than 1,430 cubic meters

(378,000 gal)

 and used to store produced oil or

condensate

 in crude oil gathering;

5)

 Subject to new source performance standards for

storage vessels of petroleum

 liquid,

35

 Ill.

 Adm.

Code 230;

6)

 In which volatile petroleum liquid

 is not stored;

or

7)

 Which

 is a pressure tank as described

 in Section

219.121(a)

119—521

60

b)

 Subject to subsection

(a)

 no owner

 or operator of

a

stationary storage tank shall cause

 or allow the

storage of any VOL in the tank unless:

1)

 The tank is equipped with one of the vapor

 loss

control devices specified

 in Section 219.121(b);

2)

 There are no visible holes, tears or other defects

in the seal or any seal fabric or material of any

floating roof;

3)

 All openings of any floating roof deck,

 except

stub drains, are equipped with covers,

 lids or

seals such that:

A)

 The cover,

 lid or seal

is

 in the closed

position at all times except when petroleum

liquid is transferred to or from the tank;

B)

 Automatic bleeder vents are closed at all

times except when the roof

 is floated off or

landed on the roof leg supports; and

C)

 Rim vents,

 if provided,

 are set to open

when

the roof

 is being floated off the roof leg

supports or at the manufacturer’s recommended

setting;

4)

 Routine inspections of floating roof seals are

conducted through roof hatches once every six

months;

5)

 A complete inspection of the cover and seal

 of any

floating roof tank is made whenever the tank

is

emptied for reasons other than the transfer of

petroleum liquid during the normal operation of

the tank,

 or whenever repairs are made as a result

of any semi—annual inspection or incidence

 of roof

damage or defect;

and

6)

 A record of the results of each inspection

conducted under subsection

 (b) (4)

or

 (b) (5)

is

maintained.

c)

 Owners and operators of petroleum liquid storage tanks

were required to have compliance schedules as

summarized

 in Appendix C, to 35 Ill Adm. Code 215.

Section 219.124

 External Floating Roofs

a)

 In addition to meeting the requirements of Section

119—522

61

219.123(b),

 no owner or operator of a stationary

storage tank equipped with an external floating roof

shall cause or allow the storage of any volatile

petroleum liquid in the tank unless:

1)

 The tank has been fitted with a continuous

secondary seal extending from the floating roof to

the tank wall

 (rim mounted secondary seal)

 or any

other device which controls VON emissions with an

effectiveness equal to or greater than a rim

mounted secondary

 seal;

2)

 Each seal closure device meets the following

requirements:

A)

 The seal

 is intact and uniformly in place

around the circumference of the floating roof

between the floating roof and tank wall;

and

B)

 The accumulated area of gaps exceeding 0.32

centimeter

 (1/8

 inch)

 in width between the

secondary seal and the tank wall shall not

exceed 21.2 square centimeters per meter

of

tank diameter

 (1.0 square inches per foot of

tank diameter).

3)

 Emergency roof drains are provided with slotted

membrane fabric covers or equivalent covers across

at least 90 percent of the area of the opening;

4)

 Openings are equipped with projections into the

tank which remain below the liquid surface

 at- all

times;

5)

 Inspections are conducted prior to May

 1 of each

year to insure compliance with subsection

 (a);

6)

 The secondary seal gap is measured prior to Nay

1

of each year;

7)

 Records of the types of volatile petroleum liquid

stored,

 the maximum true vapor pressure of the

liquid as stored, the results

 of the inspections

and the results of the secondary seal gap

measurements are maintained and available to the

Agency, upon verbal or written request,

 at any

reasonable time for a minimum of two years after

 the date on which the record was made.

b)

 Subsection

(a)

 does not apply to any stationary storage

tank equipped with an external floating roof:

119—5 23

62

1)

 Exempted under Section 219.123(a) (2) through

219.123 (a) (6);

2)

 Of welded construction equipped with a metallic

type shoe seal having

 a secondary seal from the

top of the shoe seal to the tank wall

(shoe—mounted secondary seal);

3)

 Of welded construction equipped with a metallic

type shoe seal,

 a liquid—mounted foam seal,

a

liquid-mounted liquid-filled-type seal,

 or other

closure device of equivalent control efficiency

approved by the Agency in which a petroleum liquid

with a true vapor pressure less than 27.6 kPa

 (4.0

psia)

at

294.3oK

(70°F) is stored; or

4)

 Used to store crude oil with

 a pour point of 5OoF

or higher as determined by ASTM Standard D97-66

incorporated by reference

 in Section 219.112.

Section 218.125

 Compliance Dates

Every owner or operator of an emission source subject to 35

 Ill.

Adm.

 Code 215,

 Subpart B as of December

31,

1987

 shall have

complied with its standards and limitations by December

31,

 1987.

Section 219.126

 Compliance Plan

a)

 The owner or operator of an emission source previously

subject to Section 215.125 shall

have submitted to the

Agency a compliance plan as required by 35

 Ill.

 Adm.

Code 201.241,

 including a project completion schedule

where applicable,

 no later than April 21,

 1983.

b)

 Unless the submitted compliance plan or schedule was

disapproved by the Agency, the owner or operator of

a

facility or emission source subject to the rules

specified in subsection

 (a) may operate the emission

source according to the plan and schedule as submitted.

c)

 The plan and schedule shall meet the requirements of

35

Ill. Adm.

 Code 201.241 including specific interim dates

as required in 35 Ill. Adm.

 Code 201.242.

SUBPART

C:

 ORGANIC EMISSIONS FROM MISCELLANEOUS EQUIPMENT

Section 219.141

 Separation Operations

a)

 No person shall use any single or multiple compartment

effluent water separator which receives effluent water

containing 757 1/day

 (200 gal/day)

 or more of organic

material from any equipment processing,

 refining,

119—524

63

treating,

 storing or handling organic material unless

 such effluent water separator is equipped with air

pollution control equipment capable of reducing by 85

percent or more the uncontrolled organic material

emitted to the atmosphere.

 Exception:

 If no odor

nuisance exists the limitations of this subsection

shall not apply

 if the vapor pressure of the organic

material is below 17.24 kPa

 (2.5

psia)

 at 294.3°K

(70°F)

b)

 Subsection

(a)

 shall not

apply to water and crude oil

separation

 in the

production of Illinois crude oil,

if

the vapor

pressure of such crude oil

 is less than 34.5

kPa

 (5 psia).

Section 219.142

 Pumps and Compressors

No person shall cause or allow the discharge of more than 32.8 ml

(2 cu

in)

 of VOL with vapor pressure of

 17.24 kPa

 (2.5 psia)

or

greater at

294.3oK

 (70°F)

into the atmosphere from any pump or

compressor in any 15 minute period at standard conditions.

Section 219.143

 Vapor Blowdown

No person shall cause or allow the emission of organic material

into the atmosphere from any vapor blowdown system or any safety

relief valve, except such safety relief valves not capable of

causing

 an excessive release,

 unless such emission is controlled:

a)

To

 10 ppm equivalent methane

 (molecular weight

 16.0)

or

less;

or,

b)

 By combustion in a smokeless flare;

or,

c)

 By other air pollution control equipment approved by

the Agency according to the provisions of

 35 Ill.

 Adin.

Code 201, and further processed consistent with Section

219.108.

Section 219.144

 Safety Relief Valves

Section 219.143

 shall not apply to any set of unregulated safety

relief valves capable of causing excessive releases,

 provided the

owner or operator thereof,

 by October

1,

 1972,

 supplied the

Agency with the following:

a)

 A historical record of each such set

 (or,

 if such

records were unavailable,

 of similar sets which,

by

virtue of operation under similar circumstances, may

reasonably have been presumed to have the same or

greater frequency of excessive releases)

 for a

three-year period immediately preceding October

1,

119—525

64

1972,

 indicating:

1)

 Dates on which excessive releases occurred from

each such set;

 and,

2)

 Duration in minutes of each such excessive

release;

 and,

3)

 Quantities

 (in pounds)

 of mercaptans and/or

hydrogen sulfide emitted into the atmosphere

during each such excessive release.

b)

 Proof, using such three—year historical records, that

no excessive release is likely to occur from any such

set either alone or in combination with such excessive

releases from other sets owned or operated by the same

person and located within a ten—mile radius from the

center point of any such set, more frequently than

3

times

 in any 12 month period;

c)

 Accurate maintenance records pursuant to the

requirements of subsection

 (a);

 and,

d)

 Proof,

 at three—year

 intervals, using such three-year

historical records, that such set conforms to the

requirements of subsection

 (c).

SUBPART

E:

 SOLVENT CLEANING

Section 219.181

 Solvent Cleaning in General

The requirements of this Subpart shall apply to all cold

cleaning,

 open top vapor degreasing,

 and conveyorized degreasing

operations.

Section 219.182

 Cold Cleaning

a)

 Operating Procedures:

 No person shall operate a cold

cleaning degreaser unless:

1)

 Waste solvent is stored

 in covered containers only

and not disposed of in such a manner that more

than 20

 of the waste solvent

 (by weight)

is

allowed to evaporate into the atmosphere;

2)

 The cover of the degreaser

 is closed when parts

are not being handled; and

3)

 Parts are drained until dripping ceases.

b)

 Equipment Requirements:

 No person shall operate

 a cold

cleaning degreaser unless:

119—5 26

65

1)

 The degreaser is equipped with a cover which

is

closed whenever parts are not being handled in the

cleaner.

 The cover shall be designed to be easily

operated with one hand or with the mechanical

assistance of springs, counter—weights or a

powered system if:

A)

 The solvent vapor pressure is greater than

2

kPa

 (15 mmHg or 0.3 psi) measured at 38°C

(100°F);

B)

 The solvent

 is agitated;

or

C)

 The solvent

 is heated above ambient room

temperature.

2)

 The degreaser

 is equipped

with a facility for

draining cleaned parts.

 The drainage facility

shall be constructed so that parts are enclosed

under the cover while draining unless:

A)

 The solvent vapor pressure

 is less than 4.3

kPa

 (32 mmHg or 0.6 psi) measured at

38°C

(lO0cF)

;

or

B)

 An internal drainage facility cannot be

 fitted into the cleaning system,

 in which

case the drainage facility may be external.

3)

 The degreaser is equipped with one of the

following control devices

 if the vapor pressure of

the solvent

 is greater than 4.3 kPa

 (32 mmHg or

0.6 psi) measured at 38°C(100°F) or

 if the

solvent is heated above 50°C(120°F) or its

boiling point:

A)

 A freeboard height of 7/10 of the inside

width of the tank or 91 cm

 (36 in), whichever

is less; or

B)

 Any other equipment or system of equivalent

emission control as approved by the Agency

and further processed consistent with Section

219.108.

 Such a system may include

 a water

cover, refrigerated chiller or carbon

adsorber.

4)

A

permanentpeDnt~igupnec~dbE~±Rm~fix~dgtth~he

degreaser; and

5)

If

a solvent spray

 is used,

 the degreaser

is

119—527

66

equipped with a solid fluid stream spray,

 rather

than a fine,

 atomized or shower spray.

Section 219.183

 Open Top Vapor Degreasing

a)

 Operating Requirements:

 No person shall operate an

open top vapor degreaser unless:

1)

 The cover of the degreaser is closed when

workloads are not being processed through the

degreaser;

2)

 Solvent carryout emissions are minimized by:

A)

 Racking parts to allow complete drainage;

B)

 Moving parts

 in and out of the degreaser at

less than 3.3 m/min

 (11 ft/mm);

C)

 Holding the parts

 in the vapor zone until

condensation ceases;

D)

 Tipping out any pools of solvent on the

cleaned parts before removal from the vapor

zone;

 and,

E)

 Allowing parts to dry within the degreaser

until visually dry.

3)

 Porous or absorbent materials,

 such as cloth,

leather, wood or rope are not degreased;

4)

 Less than half of the degreaser’s open top area

is

occupied with a workload;

5)

 The degreaser

 is not loaded to the point where the

vapor level would drop more than 10 cm

(4

in)

 when

the workload is removed from the vapor zone;

6)

 Spraying is done below the vapor level only;

7)

 Solvent leaks are repaired immediately;

8)

 Waste solvent is stored in covered containers only

and not disposed of in such a manner that more

than 20

 of the waste solvent

 (by weight)

is

allowed to evaporate into the atmosphere;

9)

 Water

 is not visually detectable in solvent

 exiting from the water separator;

and

10)

 Exhaust ventilation exceeding 20 cubic meters per

119—528

67

minute per square meter

 (65 cubic feet per minute

per square foot)

 of degreaser open area is not

used,

 unless necessary to meet the requirements

of

the Occupational Safety and Health Act

(29

 U.S.C.

Section 651 et seq.).

b)

 Equipment Requirements:

 No person shall operate an

open top vapor degreaser unless:

1)

 The degreaser is equipped with a cover designed to

open and close easily without disturbing the vapor

zone;

2)

 The degreaser

 is equipped with the following

switches:

A)

A

device which shuts off the sump heat source

if the amount of condenser coolant

 is not

sufficient to maintain the designed vapor

level; and

B)

 A device which shuts off the spray pump

if

the vapor level drops more than

 10 cm

(4

in)

below the bottom condenser coil;

and

C)

 A device which shuts off the sump heat source

when the vapor level exceeds the design

level.

3)

 A permanent conspicuous label summarizing the

operating procedure

 is affixed to the degreaser;

4)

 The degreaser

 is equipped with one

 of the

following devices:

A)

 A freeboard height of 3/4 of the inside width

of the degreaser tank or 91 cm

 (36 in),

whichever

 is less; and if the degreaser

opening is greater than

 1 square meter

 (10.8

ft2),

 a powered or mechanically assisted

cover; or

B)

 Any other equipment or system of equivalent

emission control as approved by the Agency

and further processed consistent with Section

219.108.

 Such equipment or system

may

include a refrigerated chiller,

 an enclosed

design or a carbon adsorption system.

Section 219.184

 Conveyorized Degreasing

119—529

68

a)

 Operating Requirements:

 No person shall operate

a

conveyorized degreaser unless:

1)

 Exhaust ventilation exceeding

 20 cubic meters per

minute per square meter

 (65 cubic feet per minute

per square foot)

 of area of loading and unloading

opening is not used,

 unless necessary to meet the

requirements of the Occupational Safety and Health

Act

 (29 U.S.C. Section 651 et seq.).

2)

 Solvent carryout emissions are minimized by:

A)

 Packing parts for best drainage;

and

B)

 Maintaining the vertical conveyor speed at

less than 3.3 m/min

 (11 ft/mm);

3)

 Waste solvent

 is stored in covered containers

 only

and not disposed of in such a manner that more

than 20

 of the waste solvent

 (by weight)

is

allowed to evaporate into the atmosphere;

4)

 Solvent leaks are repaired immediately;

5)

 Water is not visually detectable

 in solvent

exiting from the water separator; and

6)

 Downtime covers are placed over entrances and

exits of conveyorized degreasers

 immediately after

the conveyors and exhausts are shut down and not

removed until just before start-up.

b)

 Equipment Requirements:

 No person shall operate a

conveyorized degreaser unless:

1)

 The degreaser is equipped with a drying tunnel,

rotating

 (tumbling)

 basket or other equipment

sufficient to prevent cleaned parts from carrying

out solvent liquid or vapor;

2)

 The degreaser

 is equipped with the following

switches:

A)

A

device which shuts off the suinp heat source

if the amount of condenser coolant is not

sufficient to maintain the designed vapor

level;

B)

 A device which shuts off the spray pump or

the conveyor

 if the vapor level drops more

than 10 cm

(4

in)

 below the bottom condenser

coil; and

119—530

69

C)

A

device which shuts off the sump heat source

when the vapor level exceeds the design

level;

3)

 The degreaser

 is equipped with openings for

entrances and exits that silhouette workloads so

that the average clearance between the parts and

the edge of the degreaser opening is less than

10

cm

(4

in)

 or less than 10 percent of the width of

the opening;

4)

 The degreaser is equipped with downtime covers for

closing off entrances and exits when the degreaser

is shut down;

and

5)

 The degreaser is equipped with one of the

following control devices,

 if the air/vapor

in~erface

 is larger than 2.0 square meters

 (21.6

ft

):

A)

A

carbon adsorption system with ventilation

greater than or equal to 15 cubic meters per

minute per square meter

 (50 cubic feet per

minute per square

 foot)

 of air/vapor area

when downtime covers are open,

 and exhausting

less than 25 ppm of solvent by volume

averaged over a complete adsorption cycle;

or

B)

 Any other equipment or system of equivalent

 emission control

 as approved by the Agency,

and further processed consistent with Section

219.108.

 Such equipment or system may

include a refrigerated chiller.

Section 219.185

 Compliance Schedule

Every owner or operator of an emission source which was

previously exempt from the requirements

 of Subpart E of

35

 Ill.

Adm.

 Code 215

 (Sections 215.182—215.184)

 because

 it satisfied the

criteria

 in either 35

 Ill. Adm.

 Code 215.181(a)

or

35

 Ill.

 Adm.

Code 215.181(b),

 shall comply with the requirements

 of this

Subpart on and after a date consistent with Section 219.106.

A

source which did not satisfy the criteria in either 35

 Ill.

 Adm.

Code 215.181(a)

 or 35

 Ill. Adm.

 Code 215.181(b)

 shall comply with

the requirements of this Subpart upon adoption.

Section 219.186

 Test Methods

The following test methods shall be used to demonstrate

compliance with this Subpart:

119—531

70

a)

 Vapor pressures shall be determined by using the

procedure specified in Section 219.110.

b)

 Exhaust ventilation rates shall be determined by using

the procedures specified in Section 219.105(f) (3).

c)

 The performance of control devices shall be determined

by using the procedures specified in Section

219.105(f).

SUBPART F:

 COATING OPERATIONS

Section 219.204

 Emission Limitations for Manufacturing Plants

Except as provided in Section 219.208,

 no owner or operator of

a

coating line shall apply at any time any coating in which the VOM

content exceeds the following emission limitations for the

specified coating.

 The following emission limitations are

expressed

 in units of VON per volume of coating

 (minus water and

any compounds which are specifically exempted from the definition

of VOM)

 as applied at each coating applicator, except where

noted.

 Compounds which are specifically exempted from the

definition of VON should be treated as water for the purpose of

calculating the “less water” part of the coating composition.

Compliance with this Subpart must be demonstrated through the

applicable coating analysis test methods and procedures

 specified

in Section 219.105(a)

 and the recordkeeping and reporting

requirements specified

 in Section 219.211(c).

 (Note:

The

equation presented in Section 219.206 shall be used to calculate

emission limitations for determining compliance by add-on

controls,

 credits for transfer efficiency,

 emissions trades and

cross-line averaging.)

 The emission limitations are as follows:

a)

 Automobile or Light-Duty

 kg/i

 lb/gal

Truck Coating

1)

 Prime coat

 0.14

 (1.2)

2)

 Prime surfacer coat

 0.34

 (2.8)

(Note:

 The prime surfacer coat limitation

 is based

upon a transfer efficiency of

 30 percent.

 The use of

transfer efficiency credits can be allowed only

if

approved by the Agency and approved by the USEPA as a

SIP

revision.

3)

 Topcoat

 1.81

 (15.1)

(Note:

 The topcoat limitation

 is in units of kg

 (lbs)

of VON per

1

 (gal)

 of coating solids deposited.

119—532

71

Compliance with the limitation shall be based on the

daily-weighted average VON content from the entire

topcoat operation (all topcoat spray booths,

 flash-off

areas and bake ovens).

 Compliance shall be

demonstrated

 in accordance with the topcoat protocol

for automobiles and light-duty trucks referenced

in

Section 219.105(b).

 Section 219.205 does not apply to

the topcoat limitation.)

 At least 180 days prior to

the initial compliance date,

 the owner or operator of

a

coating line subject to the topcoat limitation shall

have submitted to the USEPA a detailed proposal

 specifying the method of demonstrating compliance with

the protocol.

 The proposal shall have included,

at

a

minimum, a comprehensive plan (including a rationale)

for determining the transfer efficiency at each booth

through the use of in—plant,

 or pilot testing;

the

selection of coatings to be tested

 (for the purpose of

determining transfer efficiency)

 including the

rationale for coating groupings;

 and the method for

determining the analytic VON content of as

appliedcoatings and the formulation solvent content of

as applied coatings.

 Upon approval of the protocol by

the USEPA,

 the source may proceed with the compliance

demonstration.

kg/l

 lb/gal

4)

 Final repair coat

 0.58

 (4.8)

b)

 Can Coating

 kg/i

 lb/gal

1)

 Sheet basecoat and

 0.34

 (2.8)

overvarriish

2)

 Exterior basecoat and

 0.34

 (2.8)

overvarnish

3)

 Interior body spray coat 0.51

 (4.2)

4)

 Exterior end coat

 0.51

 (4.2)

5)

 Side

seam spray coat

 0.66

 (5.5)

6)

 End sealing compound coato.44

 (3.7)

kg/l

 lb/gal

c)

 Paper Coating

 0.35

 (2.9)

(Note:

 The paper coating limitation shall not apply to

any owner or operator of any paper coating line on

which printing is performed if the paper coating line

119—533

72

complies with the emissions limitations in Subpart

H:

Printing and Publishing, Sections 219.401 through

219.404.)

kg/i

 lb/gal

d)

 Coil Coating

 0.31

 (2.6)

e)

 Fabric Coating

 0.35

 (2.9)

f)

 Vinyl Coating

 0.45

 (3.8)

g)

 Metal Furniture Coating

 0.36

 (3.0)

h)

 Large Appliance Coating

 0.34

 (2.8)

(Note:

 The limitation shall not apply to the use of

quick—drying lacquers for repair of scratches and nicks

that occur during assembly, provided that the volume

of

coating does not exceed. 0.95

1

 (1 quart)

 in any one

rolling eight-hour period.)

kg/l

 lb/gal

i)

 Magnet Wire Coating

 0.20

 (1.7)

 Miscellaneous Metal Parts and

Products Coating

1)

 Clear coating

 0.52

 (4.3)

2)

 Air—dried coating

 0.42

 (3.5)

3)

 Extreme performance

 0.42

 (3.5)

coating

4)

 All other coatings

 0.36

 (3.0)

kg/i

 lb/gal

k)

 Heavy Off-Highway Vehicle

Products Coating

1)

 Extreme performance

 0.42

 (3.5)

prime coat

2)

 Extreme performance top-

 0.42

 (3.5)

coat

 (air dried)

3)

 Final repair coat

 0.42

 (3.5)

(air dried)

119—534

73

4)

 All other coatings are subject to the emission

limitations for miscellaneous metal parts and

products coatings in subsection

(j)

 above.

kg/i

 lb/gal

1)

 Wood Furniture Coating

1)

 Clear topcoat

 0.67

 (5.6)

2)

 Opaque stain

 0.56

 (4.7)

3)

 Pigmented coat

 0.60

 (5.0)

4)

 Repair coat

 0.67

 (5.6)

5)

 Sealer

 0.67

 (5.6)

6)

 Semi-transparent stain

 0.79

 (6.6)

7)

 Wash coat

 0.73

 (6.1)

(Note:

 An owner or operator of a wood furniture

coating operation subject to this Section shall apply

all coatings, with the exception of no more than 37.8

1

(10 gal)

 of coating per day used for touch-up and

repair operations, using one or more of the following

 application systems:

 airless spray application system,

air—assisted airless spray application system,

electrostatic spray application system, electrostatic

bell or disc spray application system, heated airless

spray application system,

 roller coating,

 brush or

wipe

coating application system,

 or dip coating application

system.)

ni)

 Existing Diesel-Electric Locomotive Coating Lines

in

Cook County

kg/i

 lb/gal

1)

 Extreme performance prime

 0.42

 (3.5)

coat

2)

 Extreme performance top-

 0.42

 (3.5)

coat

 (air dried)

3)

 Final repair coat

 0.42

 (3.5)

(air dried)

4)

 High-temperature aluminum

 0.72

 (6.0)

coating

119—535

74

5)

All

other coatings

 0.36

 (3.0)

Section 219.205

 Daily-Weighted Average Limitations

No owner or operator of a coating line subject to the limitations

of Section 219.204 and complying by means of this Section shall

operate the subject coating line unless the owner or operator has

demonstrated compliance with subsection

 (a),

 (b),

 (c),

 (d),

(e)

or

(f)

 (depending upon the source category)

 through the

applicable coating analysis test methods and procedures

 specified

in Section 219.105(a)

 and the recordkeeping and reporting

requirements specified in Section 219.211(d):

a)

 No owner or operator of a coating line subject to only

~

 of the limitations from among Section

219.204 (a) (1),

 (a) (2),

 (a) (4),

(c)

(d)

(e)

(f)

(g)

(h), or

(i)

 shall apply coatings on any such coating

line,

 during any day, whose daily-weighted average VOM

content exceeds the emission limitation to which the

coatings are subject.

b)

 No owner or operator of a miscellaneous metal parts and

products coating line subject to the limitations of

Section 219.204(j)

 shall apply coatings to

miscellaneous metal parts or products on the subject

coating line unless the requirements

 in subsection

(b) (1)

or

 (b) (2) below are met.

1)

 For each coating line which applies multiple

coatings,

 all of which are subject to the same

numerical emission limitation within Section

219.204(j)

 above, during the same day

 (e.g.,

all

coatings used on the

 line are subject to 0.42 kg/I

3.5

 lbs/gal),

 the daily-weighted average VOM

content shall not exceed the coating VON content

limit corresponding to the category of coating

used,

or

2)

 For each coating line which applies coatings from

more than one of the four coating categories

in

Section 219.204(j)

 above, during the same day,

the

owner or operator shall have a site-specific

proposal approved -by the Agency and approved by

the USEPA as a SIP revision.

 To receive approval,

the requirements of USEPA’s Emissions Trading

Policy Statement

 (and related policy) must be

satisfied.

c)

 No owner or operator of a can coating facility subject

to the limitations of Section 215.204(b)

 shall operate

the subject coating facility using a coating with a VON

content

 in excess of the limitations specified in

119—5 36

75

Section 215.204(b)

 unless all of the

following

requirements are met:

1)

 An alternative daily emission limitation shall be

determined according to subsection

 Cc) (2) below.

Actual daily emissions shall never exceed the

alternative daily emission limitation and shall

be

calculated by use of the following equation.

E

S

 V.C.

~

1=1

~

where:

Ed

 Actual VON emissions for the day in

units of kg/day

 (lbs/day),

i

 Subscript denoting a specific coating

applied,

n

 Total number of coatings applied in the

can coating operation,

 Volume of each coating applied for the

day in units of 1/day

 (gal/day)

of

coating (minus water and any compounds

which are specifically exempted from the

definition of VON),

and

 The VON content of each coating as

applied in units of kg VOM/l

 (lbs

VON/gal)

 of coating

 (minus water and any

compounds which are specifically

exempted from the definition of VON).

2)

 The alternative daily emission limitation

 (Ad)

shall be determined on a daily basis as follows:

Ad=

S

___

(D~

—

L1)

where:

Ad

 The VON emissions allowed for the day in

units of kg/day

 (lbs/day),

i

 Subscript denoting a specific coating

applied,

119—537

76

n

 Total number of surface coatings applied

in the can coating operation,

C1

 The VON content of each surface coating

as applied

 in units

 of kg VON/i

 (lbs

VON/gal)

 of coating

 (minus water and any

compounds which are specifically

exempted from the definition of VON),

 The density of VON in each coating

applied.

 For the purposes of

calculating Ad, the density is

0.882 kg VON/i VON (7.36 lbs VON/gal

VON),

 Volume

 of each surface coating applied

for the day in units of

1

 (gal)

of

coating (minus water and any compounds

which are specifically exempted from the

definition of VON),

 The VOM emission limitation for each

surface coating applied as specified

in

Section 219.204(b)

 in units

 of kg VON/i

(lbs VON/gal)

 of coating

 (minus water

and any compounds which are specifically

exempted from the definition of VOM).

d)

 No owner or operator of a heavy off-highway vehicle

products coating line subject to the limitations of

Section 219.204(k)

 shall apply coatings to heavy

off-highway vehicle products on the subject coating

line unless the requirements of subsection

 (d) (1)

or

(d) (2)

 below are met.

1)

 For each coating line which applies multiple

 coatings, all of which are subject to the same

numerical emission limitation within Section

219.204(k)

 above,

 during the same day (e.g.,

all

coatings used on the line are subject to 0.42 kg/l

3.5

 lbs/gal),

 the daily-weighted average

VOM

content shall not exceed the coating VOM content

limit corresponding to the category of coating

used,

or

2)

 For each coating line which applies coatings

subject to more than one numerical emission

limitation in Section 219.204(k)

 above,

 during the

same day, the owner or operator shall have

 a site

specific proposal approved by the Agency and

approved by the USEPA as a SIP revision.

To

119— 538

77

receive approval, the requirements of USEPA’s

Emissions Trading Policy Statement

 (and related

policy) must be satisfied.

e)

 No owner or operator of a wood furniture coating line

subject to the limitations of Section 219.204(1)

 shall

apply coatings to wood furniture on the subject coating

line unless the requirements of subsection

 (e) (1)

or

(e) (2),

 in addition to the requirements specified in

the note to Section 219.204(1),

 are met.

1)

 For each coating line which applies multiple

coatings, all of which are subject to the same

numerical emission limitation within Section

219.204(1)

 above,

 during the same day

 (e.g.,

all

coatings used on the line are subject to 0.67 kg/i

5.6

 lbs/gal),

 the daily—weighted average

VON

content shall not exceed the coating VON content

limit corresponding to the category of coating

used,

or

2)

 For each coating line which applies coatings

subject to more than one numerical emission

limitation

 in Section 219.204(1)

 above,

 during the

same day,

 the owner or operator shall have a site

specific proposal approved by the Agency and

approved by the USEPA as a SIP revision.

To

receive approval, the requirenients of USEPA’s

Emissions Trading Policy Statement

 (and related

policy)

 must be satisfied.

f)

 No owner or operator of an existing diesel—electric

locomotive coating line subject to the limitations of

Section 219.204(m)

 shall apply coatings to

diesel—electric locomoti~reson the subject coating line

unless the requirements of subsection

 (b) (1)

or

 (b) (2)

are met.

1)

 For each coating line which applies multiple

coatings, all of which are subject to the same

numerical emission limitation within Section

219.204(m)

 above, during the same day

 (e.g.,

all

coatings used on the line are subject to 0.42 kg/i

3.5

 lbs/gal),

 the daily—weighted average VON

content shall not exceed the coating VON content

limit corresponding to the category of coating

used,

or

2)

 For each coating line which applies coatings

subject to more than one numerical emission

limitation in Section 219.204(m)

 above,

 during the

same day,

 the owner or operator shall have

 a site

119—5 39

78

specific proposal approved by the Agency and

approved by the USEPA as a SIP revision.

To

receive approval, the requirements of USEPA’s

Emissions Trading Policy Statement

 (and related

policy) must be satisfied.

Section 219.206

 Solids Basis Calculation

Limitations

 in terms of kg

 (lbs)

 of VON emissions per

1

 (gal)

of

solids as applied at each coating applicator shall be determined

by

the following equation:

S=

C

1

—

 (C/D)

where:

S

 The limitation on VON emissions in terms

of kg VON/i

 (lbs VON/gal)

 of solids,

C

 The limitation on VON emissions

 in terms

of kg/i

 (lbs/gal)

 of coating

 (minus

water and any compounds which are

specifically excluded from the

definition of VON)

 specified in Section

219.204,

D

 The density of VON in the coating.

For

the purposes of calculating

 5, the

density

 is 0.882 kg

VOM/1

VON

 (7.36

lbs

VON/gal VON).

Section 219.207

 Alternative Emission Limitations

a)

 Any owner or operator of a coating line subject to

Section 219.204 may comply with this Section, rather

than with Section 219.204,

 if a capture system and

control device are operated at all times and the owner

or operator demonstrates compliance with subsections

(c),

 (d),

 (e),

 (f),

(g)

or

(h)

 (depending upon the

source category) through the applicable coating

analysis and capture system and control device

efficiency test methods and procedures specified in

Section 219.105 and the recordkeeping and reporting

requirements specified in Section 219.211(e);

 and the

control device

 is equipped with the applicable

monitoring equipment specified in Section 219.105(d)

and the monitoring equipment is installed,

 calibrated,

operated and maintained according to vendor

specifications at all times the control device is

in

use.

 A capture system and control device,

 which does

not demonstrate compliance with subsection

(c)

 (d),

119—540

79

(e),

 (f),

(g)

or

 (h) may be used as an alternative to

compliance with Section 219.204 only if the alternative

is approved by the Agency and approved by the USEPA as

a SIP revision.

b)

 Alternative Add-On Control Methodologies

1)

The

coating line is equipped with a capture system

and control device that provides 81 percent

reduction in the overall emissions of VON from the

coating line and the control device has

a

90

percent efficiency,

or

2)

 The system used to control VON from the coating

line

 is demonstrated to have an overall efficiency

sufficient to limit VON emissions to no more than

what is allowed under Section 219.204.

 Use of any

control system other than an afterburner, carbon

adsorption,

 condensation,

 or absorption scrubber

system can be allowed only if approved by the

Agency and approved by the USEPA as a SIP

revision.

 The use of transfer efficiency credits

can be allowed only

 if approved by the Agency and

approved by the USEPA as a SIP revision.

 Baseline

transfer efficiencies and transfer efficiency test

methods must be approved by the Agency and the

USEPA.

Such overall efficiency is to be determined as

follows:

A)

 obtain the emission limitation from the

appropriate subsection in Section 219.204,

B)

 calculate “S” according to the equation

in

Section 219.206,

3)

 calculate the overall efficiency required

according to Section 219.105(e).

 For the

purposes of calculating this value,

 according

to the equation in Section 219.105(e) (2),

VON1 is equal to the value of “5” as

determined above in subsection

 (b) (2) (B).

c)

 No owner or operator of

 a coating line subject to only

one of the emission limitations from among Section

219.204(a) (1),

 (a) (2)

 (a) (4),

(c)

(d)

(e)

(f)

(g)

(h)

or

 (i) and equipped with a capture system and

control device shall operate the subject coating line

unless the requirements

 in subsection

 (b) (1)

or

 (b) (2)

above are met.

 No owner or operator of

 a coating line

119—54 1

80

subject to Section 219.204(a) (3)

and

equipped with a

capture system and control device shall operate the

coating line unless the owner or operator demonstrates

compliance with the topcoat limitation in accordance

with the topcoat protocol for automobile or light-duty

trucks referenced

 in Section 219.105(b).

d)

 No owner or operator of a miscellaneous metal parts and

products coating line which applies one or more

coatings during the same day,

 all of which are subject

to the same numerical emission limitation within

Section 219.204(j)

 (e.g.,

 all coatings used on the line

are subject to 0.42 kg/l

3.5

 lbs/gal),

 and which

is

equipped with a capture system and control device shall

operate the subject coating line unless the

requirements

 in subsection

 (b) (1)

or

 (b) (2) above are

met.

e)

 No owner or operator of a heavy off-highway vehicle

products coating line which applies one or more

coatings during the same day, all of which are subject

to the same numerical emission limitation within

Section 219.204(k)

 (e.g.,

 all coatings used on the line

are subject to 0.42 kg/l

3.5

 lbs/gal),

 and which is

equipped with a capture system and control device shall

operate the subject coating line unless the

requirements in subsection

 (b) (1)

or

 (b) (2)

 above are

met.

f)

 No owner or operator of an existing diesel—electric

locomotive coating line which applies one or more

coatings during the same day, all of which are subject

to the same numerical emission limitation within

Section 219.204(m)

 (e.g.,

 all coatings used on the line

are subject to 0.42 kg/l

3.5

 lbs/gal),

 and which

is

equipped with a capture system and control device shall

operate the subject coating line unless the

requirements in subsection

 (b) (1)

or

 (b) (2)

 are met.

g)

 No owner or operator of a wood furniture coating line

which applies one or more coatings during the same day,

all of which are subject to the same numerical emission

limitation within Section 219.204(1)

 (e.g.,

all

coatings used on the line are subject to 0.67 kg/l

5.6

lbs/gal),

 and which

 is equipped with a capture system

and control device shall operate the subject coating

line unless the requirements in subsection

 (b) (1)

or

(b) (2)

 are met.

 If compliance is achieved by meeting

the requirements in subsection

 (b) (2), then the

provisions

 in the note to Section

219.204(1)

 must also

be met.

119—542

81

h)

 No owner or operator of

 a can coating facility and

equipped with a capture system and control device shall

operate the subject coating facility unless the

requirements in subsection

 (h) (1)

or

 (h) (2) below are

met.

1)

 An alternative daily emission limitation shall be

determined according to Section 219.205(c) (2).

Actual daily emissions shall never exceed the

alternative daily emission limitation and shall be

calculated by use of the following equation:

Ed

~V1

C1

 (1—F1)

where:

Ed

 Actual VON emissions for the day in

units of kg/day (lbs/day),

i

 Subscript denoting the specific coating

applied,

n

 Total number of surface coatings as

applied in the can coating operation,

V1

 Volume of each coating as applied for

the day in units of 1/day

 (gal/day)

of

coating

 (minus water and any compounds

which are specifically exempted from the

definition of VON),

C1

 The VON content of each coating as

applied in units

 of kg VOM/l

 (lbs

VON/gal)

 of coating

 (minus water and any

compounds which are specifically

exempted from the definition of VON),

and

F1

 Fraction, by weight,

 of VON emissions

from the surface coating, reduced or

prevented from being emitted to the

ambient air. This is the overall

efficiency of the capture system and

control device.

2)

 The coating line

 is equipped with a capture system

and control device that provide 75 percent

reduction in the overall emissions of VON from the

coating line and the control device has a

90

119—543

82

percent efficiency.

Section 219.208

 Exemptions From Emission Limitations

a)

 Exemptions for all source categories except wood

furniture coating.

 The limitations of this Subpart

shall not apply to coating lines within a facility,

that otherwise would be subject to the same subsection

of Section 219.204

 (because they belong to the same

source category,

 e.g.

 can coating), provided that

combined actual emissions of VON from all lines

 at the

facility subject to that subsection never exceed

6.8 kg/day

 (15 lbs/day) before the application of

capture systems and control devices.

 (For example,

can

coating lines within a plant would not be subject to

the limitations of Section 219.204(b)

 if the combined

 actual emissions of

VON

from the can coating lines

never exceed 6.8 kg/day

 (15 lbs/day) before the

application of capture systems and control devices.)

Volatile organic material emissions from heavy

off-highway vehicle products coating lines must be

combined with VON emissions from miscellaneous metal

parts and products coating lines to determine

applicability.

 Any owner or operator of a coating

facility shall comply with the applicable coating

analysis test methods and procedures specified in

Section 219.105(a)

 and the recordkeeping and reporting

requirements specified in Section 219.211(a)

 if total

VON emissions from the subject coating lines are always

less than or equal to 6.8 kg/day

 (15 lbs/day) before

the application of capture systems and control devices

and,

 therefore,

 are not subject to the limitations- of

Section 219.204.

 Once a category of coating lines at

a

facility is subject to the limitations in Section

219.204, the coating lines are always subject to the

limitations in Section 219.204.

b)

 Applicability for wood furniture coating

1)

 The limitations of this Subpart shall apply to a

plant’s wood furniture coating lines if the plant

contains process emission sources, not regulated

by Subparts

B,

E,

 F (excluding Section

219.204(1)), H (excluding Section 219.405),

Q,

R,

5,

V,

X,

Y,

or

 Z of this Part,

 which as a group

both:

A)

 have maximum theoretical emissions of

91

Mg

(100 tons)

 or more per calendar year of VON

if no air pollution control equipment were

used,

and

119—544

83

B)

 are not limited to less than 91 Mg

 (100 tons)

of VON per calendar year if no

 air pollution

control equipment were used, through

production or capacity limitations contained

in a federally enforceable construction

permit or SIP revision.

2)

 If a plant ceases to fulfill the criteria of

subsection

 (b) (1), the limitations of Section

219.204(1)

 shall continue to apply to any wood

furniture coating line which was ever subject to

the limitations of Section 219.204(1).

3)

 For the purposes of subsection

 (b), an emission

source shall be considered regulated by a Subpart

if

 it is subject to the limitations of that

Subpart.

 An emission source is not considered

regulated by a Subpart

 if its emissions are below

the applicability cutoff level

 or if the source

is

covered by an exemption.

4)

 Any owner or operator of

 a wood furniture coating

 line to which the limitations of this Subpart are

not applicable due to the criteria in subsection

(b)

 shall, upon request by the Agency or the

USEPA, submit records to the Agency and the USEPA

within 30 calendar days from the date of the

request that document that the coating line

is

exempt from the limitations of this Subpart.

Section 219.209

 Exemption From General Rule on Use of Organic

Material

No

owner or operator of

 a coating line subject to the limitations

of Section 219.204

 is required to meet the limitations of

Subpart G

 (Section 219.301 or 219.302)

 of this Part,

 after the

date by

which the coating line is

required to meet Section

219.204.

Section 219.210

 Compliance Schedule

Every owner or operator of a coating line

 (of a type included

within Section 219.204)

 shall comply with the requirements of

Section 219.204,

 219.207 or 219.208 and Section 219.211

in

accordance with the appropriate compliance schedule as specified

in subsection

 (a),

 (b),

(c)

or

 (d) below:

a)

 No owner or operator of

 a coating line which is exempt

from the limitations of Section 219.204 because of the

criteria in Section 219.208(a)

 shall operate said

 coating line on or after a date consistent with Section

219.106, unless the owner

 or operator has complied

119—54

5

84

with,

 and continues to comply with,

 Section 219.211(b).

Wood furniture coating lines are not subject to Section

219.211(b)

b)

 No owner or operator of a coating line complying by

means

 of Section 219.204

 shall operate said coating

line on or after a date consistent with Section

219.106, unless the owner or operator has complied

with,

 and continues to comply with,

 Sections 219.204

and 219.211(c).

c)

 No owner or operator of a coating line complying by

means of Section 219.205 shall operate said coating

line on or after

 a date consistent with Section

219.106, unless the owner or operator has complied

with,

 and continues to comply with,

 Sections 219.205

and 219.211(d).

d)

 No owner or operator of

 a coating line complying

by

means of Section 219.207 shall operate said coating

line on or after a date consistent with Section

219.106, unless the owner or operator has complied

with,

 and continues to comply with,

 Sections 219.207

and 219.211(e).

Section 219.211

 Recordkeeping and Reporting

a)

 The VOM content of each coating and the efficiency of

each capture system and control device shall be

determined by the applicable test methods and

procedures specified in Section 219.105 to establish

the records required under this Section.

b)

 Any owner or operator of a coating line which is

exempted from the limitations of Section 219.204

because of Section 219.208(a)

 shall comply with the

following:

1)

 By a date consistent with Section 219.106, the

owner or operator of a facility referenced in this

subsection shall certify to the Agency that the

facility is exempt under the provisions of Section

219.208(a).

 Such certification shall include:

A)

 A declaration that the facility is exempt

from the limitations of Section 219.204

because of Section 219.208(a); and

B)

 Calculations which demonstrate that the

combined VON emissions from all coating lines

at the facility never exceed 6.8 kg

(15

 lbs)

per day before the application of capture

119—546

85

systems and control devices.

The

following

equation shall be used to calculate total

VON

emissions:

Ifl

T

S

S

(A.

 B.).

e

j.

1=1

where:

Te

 =Total VON emissions from coating lines

at a facility each day before the

application of capture systems and

control devices in units of kg/day

(lbs/day),

m

 Number of coating lines at the

facility,

j

 Subscript denoting an individual

coating line,

n

 Number of different coatings as

applied each day on each coating

line at the facility,

i

 Subscript denoting an individual

coating,

A1

 Weight

of VON per volume of each coating

(minus water and any compounds which are

specifically exempted from the

definition of VON)

 as applied each day

on each coating line at the facility in

units of kg VON/i

 (lbs VON/gal),

and

B1

 Volume of each coating

 (minus water and

any compounds which are specifically

exempted from the definition of VON)

as

applied each day on each coating line at

the facility

 in units of 1/day

(gal/day).

 The instrument or method by

which the owner or operator accurately

measured or calculated the volume of

each coating as applied on each coating

line each day shall be described in the

certification to the Agency.

2)

 On and after

 a date consistent with Section

219.106, the owner or operator of a facility

referenced in this subsection shall collect and

119—547

86

record all of the following information each day

for each coating line and maintain the information

at the facility for a period of three years:

A)

 The name and identification number of each

coating as applied on each coating line.

B)

 The weight of VOM per volume and the volume

of each coating (minus water and any

compounds which are specifically exempted

from the definition of VON)

 as applied each

day on each coating line.

3)

 On and after a date consistent with Section

219.106,

 the owner or operator of a facility

exempted from the limitations of Section 219.204

because of Section 219.208(a)

 shall notify the

Agency of any record showing that total VON

emissions from the coating facility exceed 6.8 kg

(15

 lbs)

 in any day before the application of

capture systems and control devices by sending

a

copy of such record to the Agency within 30 days

after the exceedance occurs.

c)

 Any owner or operator of a coating line subject to the

limitations of Section 219.204 and complying by means

of Section 219.204

 shall comply with the following:

1)

By

 a date consistent with Section 219.106,

 or upon

initial start-up of a new coating line,

 or upon

changing the method of compliance from an existing

subject coating line from Section 219.205 or

Section 219.207 to Section 219.204; the owner or

operator of a subject coating line shall certify

to the Agency that the coating line will be in

compliance with Section 219.204 on and after a

date consistent with Section 219.106,

 or on and

after the initial start—up date.

 Such

certification shall include:

A)

 The name and identification number of each

coating as applied on each coating line.

B)

 The weight of VON per volume of each coating

(minus water and any compounds which are

specifically exempted from the definition of

VON)

 as applied each day on each coating

line.

C)

 For coating lines subject to Section

219.204(a) (3)

 certification shall include:

119—548

87

i)

 The name and identification number

of

each coating line which will comply by

means of Section 219.204(a) (3),

ii)

 The name and identification number of

each coating as applied on-each coating

line,

iii) The weight of VON per volume of each

coating as applied on each coating line,

iv)

 The instrument or method by which the

owner -or operator will accurately

measure or calculate the volume of each

coating as applied each day on each

coating line,

v)

 The method by which the owner or

operator will create and maintain

records each day as required in

subsection

 (c) (2)

 below for coating

lines subject to Section 219.204(a) (3),

vi)

 An example format in which the records

required in subsection

 (c) (2)

 below for

coating lines subject to Section

219.204 (a) (3).

2)

 On and after a date consistent with Section

219.106,

 -or on and after the initial start-up

date,

 the owner or operator of a coating line

subject to the limitations of Section 219.204 and

complying by means of Section 219.204 shall

collect and record all of the following

information each day for each coating line and

maintain the information at the facility for

a

period of three years:

A)

 The name and identification number of each

coating as applied on each coating line.

B)

 The weight of VON per volume of each coating

(minus water and any compounds which are

specifically exempted from the definition of

VON)

 as applied each day on each coating

line.

C)

 For coating lines subject to Section

219.204(a) (3), the owner or operator shall

maintain all records necessary to calculate

the daily-weighted average VON content from

the coating line in accordance with the

119—54 9

88

proposal submitted,

 and approved by the

USEPA, pursuant to Section 219.204 (a) (3).

3)

 On and after a date consistent with Section

219.106, the owner or operator of a subject

coating line shall notify the Agency

 in the

following instances:

A)

 Any record showing violation of Section

219.204 shall be reported by sending a copy

of such record to the Agency within 30 days

following the occurrence of the violation,

except that any record showing

 a violation of

Section 219.204 (a) (3)

 shall be reported by

sending a copy of such record to the Agency

within 15 days from the end of the month in

which the violation occurred.

B)

 At least

 30 calendar days before changing the

method of compliance with Section 219.204

from Section 219.204 to Section 219.205 or

Section 219.207, the owner or operator shall

comply with all requirements

 of subsection

(ci) (1)

or

 (e) (1)

 below,

 respectively.

 Upon

changing the method of compliance with

Section 219.204 from Section 219.204 to

Section 219.205 or Section 219.207, the owner

or operator shall comply with all

requirements of subsection

(d)

or

 (e),

respectively.

C)

 For coating lines subject to Section

219.204(a) (3), the owner or operator shall

notify the Agency of any change to the

topcoating operation at least 30 days before

the change is effected.

 The Agency shall

determine whether or not recertification

testing is required.

 If the Agency

determines that recertification testing is

required, then the owner or operator shall

submit a proposal to the Agency to test

within 30 days and retest within 30 days of

the Agency’s approval of the proposal.

d)

 Any owner or operator of a coating line subject to the

limitations of Section 219.204 and complying by means

of Section 219.205 shall comply with the following:

1)

 By a date consistent with Section 219.106,

 or upon

initial start—up of a new coating line,

 or upon

changing the method of compliance for an existing

subject coating line from Section 219.204 or

119—550

89

Section 219.207 to Section 219.205; the owner or

operator of the subject coating line shall certify

to the Agency that the coating line will be

in

compliance with Section 219.205 on and after

a

date consistent with Section 219.106, or on and

after the initial start-up date.

 Such

certification shall include:

A)

 The name and identification number of each

coating line which will comply by means of

Section 219.205.

B)

 The name and identification number of each

coating as applied on each coating line.

C)

 The weight of VON per volume and the volume

of each coating

 (minus water and any

compounds which are specifically exempted

from the definition of VON)

 as applied each

day on each coating line.

D)

 The instrument or method by which the owner

or operator will accurately measure or

calculate the volume of each coating as

applied each day on each coating line.

E)

 The method by which the owner or-operator

will create and maintain records each day as

required in subsection

 (ci) (2).

F)

 An example of the format in which the records

required in subsection

 (ci) (2) will be kept.

2)

 On and after

 a date consistent with Section

219.106,

 or on and after the initial start-up

date, the owner or operator of a coating line

subject to the limitations of Section 219.204 and

complying by means of Section 219.205,

 shall

collect and record all of the following

information each day for each coating line and

maintain the information at the facility for

a

period of three years:

A)

 The name and identification number of each

coating as applied on each coating line.

B)

 The weight of VON per volume and the volume

of each coating

 (minus water and any

compounds which are specifically exempted

from the definition of VON)

 as applied each

day on each coating line.

119—55 1

90

C)

 The daily—weighted average VOM content of

all

coatings as applied on each coating line as

defined in Section 219.104.

3)

 On and after a date consistent with Section

219.106, the owner or operator of

 a subject

coating line shall notify the Agency in the

following instances:

A)

 Any record showing violation of Section

219.205 shall be reported by sending a copy

of such record to the Agency within 30 days

following the occurrence of the violation.

B)

 At least 30 calendar days before changing the

method of compliance with this subpart from

Section 219.205 to Section 219.204 or Section

219.207,

 the owner or operator shall comply

with all requirements of subsection

 (c) (1)

or

(e) (1), respectively.

 Upon changing the

method of compliance with this subpart from

Section 219.205 to Section 219.204 or Section

219.207, the ow~ththo~ldprEqüthremhnt~

 o~mply

subsection

(c)

or

 (e),

respectively.

e)

 Any owner or operator of a coating line subject to the

limitations of SectiOn 219.207 and complying by means

of Section 219.207(c),

 (d),

 (e),

 (f),

(g)

or

(h)

 shall

comply with the following:

1)

 By a date consistent with Section 219.106, or upon

initial start—up of

 a new coating line,

 or upon

changing the method of compliance for an existing

coating line from Section 219.204 or Section

219.205 to Section 219.207, the owner or operator

of the subject coating line shall perform all

tests and submit to the Agency the results of all

tests and calculations necessary to demonstrate

that the subject coating line will be in

compliance with Section 219.207 on and after

a

date consistent with Section 219.106,

 or on and

after the initial start-up date.

2)

 On and after a date consistent with Section

219.106,

 or on and after the initial start-up

date,

 the owner or operator of a coating line

subject to the limitations of Section 219.207 and

complying by means of Section 219.207(c),

 (ci),

(e),

 (f),

(g)

or

(h)

 shall collect and record all

of the following information each day for each

coating line and maintain the information at the

119—552

91

facility for

 a period of three years:

A)

 The weight of VOM per volume of coating

solids as applied each day on each coating

line,

 if complying pursuant to Section

219.207(b) (2)

B)

 Control device monitoring data.

C)

 A log of operating time for the capture

system, control device, monitoring equipment

and the associated coating line.

D)

 A maintenance log for the capture system,

control device and monitoring equipment

detailing all routine and non—routine

maintenance performed including dates and

duration of any outages.

3)

 On and after a date consistent with Section

219.106,

 the owner or operator of a subject

coating line shall notify the Agency in the

following instances:

A)

 Any record showing violation of Section

219.207 shall be reported by sending a copy

of such record to the Agency within 30 days

following the occurrence of the violation.

B)

 At least 30 calendar days before changing the

method of compliance with this Subpart from

Section 219.207 to Section 219.204 or Section

219.205,

 the owner or operator shall comply

with all requirements of subsection

 (c) (1)

or

(ci) (1)

 of this Section,

 respectively.

 Upon

changing the method of compliance with this

subpart from Section 219.207 to Section

219.204 or Section 219.205, the owner or

operator shall comply with all requirements

of subsection

(C)

or

 (ci)

 of this Section,

 respectively.

SUBPART G:

 USE OF ORGANIC MATERIAL

Section 219.301

 Use of Organic Material

No person shall cause or allow the discharge of more than 3.6

kg/hr

(8

 ibs/hr)

 of organic material into the atmosphere from

any

emission source, except as provided

 in Sections 219.302,

 219.303,

219.304 and the following exception:

 If no odor nuisance exists

the limitation of this Subpart shall apply only to

photochemically reactive material.

119—553

92

Section 219.302

 Alternative Standard

Emissions of organic material in excess of those permitted by

Section 219.301 are allowable if such emissions are controlled

by

one of the following methods:

a)

 Flame, thermal or catalytic incineration so as either

to reduce such emissions to 10 ppm equivalent methane

(molecular weight

 16) or less,

 or to convert 85 percent

of the hydrocarbons to carbon dioxide and water;

or,

b)

 A vapor recovery system which adsorbs and/or condenses

at least 85 percent of the total uncontrolled organic

material that would otherwise be emitted to the

atmosphere;

or,

c)

 Any other air pollution control equipment approved by

the Agency and approved by the USEPA as a SIP revision

capable of reducing by 85 percent or more the

 uncontrolled organic material, that would be otherwise

emitted to the atmosphere.

Section 219.303

 Fuel Combustion Emission Sources

The provisions of Sections 219.301 and 219.302 shall not apply to

fuel combustion emission sources.

Section 219.304

 Operations with Compliance Program

The provisions of Sections 219.301 and 219.302 shall not apply to

any

owner,

 operator, user or manufacturer of paint,

 varnish,

lacquer, coatings or printing ink whose compliance program and

project completion schedule,

 as required by 35 Ill. Acm. Code

201, provided for the reduction of organic material used in such

process to 20 percent or less of total volume by May 30,

 1977.

SUBPART H:

 PRINTING AND PUBLISHING

Section 219.401

 Fiexographic and Rotogravure Printing

a)

 No owner or operator of

 a subject flexographic,

packaging rotogravure or publication rotogravure

printing line shall apply at any time any coating or

ink unless the VOM content does not exceed the

limitation specified in either subsection

 (a) (1)

or

(a) (2)

 below.

 Compliance with this Section must be

demonstrated through the applicable coating or ink

analysis test methods and procedures specified in

Section 219.105(a)

 and the recordkeeping and reporting

requirements specified in Section 219.404(c).

 As an

alternative to compliance with this subsection,

a

119—554

93

subject printing line may meet the requirements of

subsection

(b)

or

(c)

 below.

1)

 Forty percent VON by volume of the coating and ink

(minus water and any compounds which are

specifically exempted from the definition of VON),

or

2)

 Twenty-five percent VON by volume of the volatile

content in the coating and ink.

b)

 No owner or operator of a subject flexographic,

packaging rotogravure or publication rotogravure

printing line shall apply coatings or inks on the

subject printing line unless the weighted average,

by

volume, VOM content of all coatings and inks as applied

each day on the subject printing line does not exceed

the limitation specified in either subsection

 (a) (1)

(as determined by subsection

 (b) (I) or subsection

(a) (1))

 (as determined by subsection

 (b) (2).

Compliance with this subsection must be demonstrated

through the applicable coating or ink analysis test

methods and procedures specified in Section 219.105(a)

and the recordkeeping and reporting requirements

specified in Section 219.404(d).

1)

 The following equation shall be used to determine

if the weighted average VON content of all

coatings and inks as applied each day on the

subject pr±p~h~i~n~nesubedsttbB

 ~á*4t~tion

C1Li

 (V51

 VVOMI)

VOM(.)

(A)

L1(V~1

 VVoMI)

Where:

VON(i)(A)

 The weighted average VON content

in

units

 of percent VON by volume of

all coatings and inks

 (minus water

and any compounds which are

specifically exempted from the

definition of VON) used each day,

i

 Subscript denoting a specific

coating or ink as applied,

119—555

94

n

 The number of different coatings

and/or inks as applied each day on

a printing line,

C1

 The VON content in units of percent

VON by volume of each coating or

ink as applied

 (minus water and

any

compounds which are specifically

exempted from the definition of

VON),

L1

 The liquid volume of each coating

or ink as applied in units

of

1

(gal)

V51

 The volume fraction of solids

in

each coating or ink as applied,

and

VvoM.

 The volume fraction of

VOM

in each

 coating or ink as applied.

2)

 The following equation shall be used to determine

if the weighted average VON content of all

coatings and inks as applied each day on the

subject printing line exceeds the limitation

specified in subsection

 (a) (2).

S

CLV

1=1

iiVl4i

VOM(i)(B)

S

L.V

1=1

VMi

where:

VOM(i)(B)

 The weighted average VON content in

units of percent VOM by volume of

the volatile content of all

coatings and inks used each day,

i

 Subscript denoting a specific

coating or ink as applied,

n

 The number of different coatings

and/or inks as applied each day on

each printing

 line,

C1

 The VON content in units of percent

VON by volume of the volatile

matter in each coating or ink as

119—5 56

95

applied,

L1

 The liquid volume of each coating

or ink as applied in units of

1

(gal),

and

V~1

 The volume fraction of volatile

matter in each coating or ink as

applied.

c)

 No owner or operator of a subject fiexographic,

packaging rotogravure or publication rotogravure

printing line equipped with a capture system and

control device shall operate the subject printing line

unless the owner or operator meets the requirements in

subsection

 (c) (1),

 (c) (2),

or

 (c) (3)

 and subsections

(c)

(4),

 (c) (5) and

 (c) (6)

 below.

1)

 A carbon adsorption system is used which reduces

the captured VON emissions by at least 90 percent

by weight, or

2)

 An incineration system is used which reduces the

captured VOM emissions by at least 90 percent by

weight,

or

3)

 An alternative VON emission reduction system

is

used which is demonstrated to have at least

a

90 percent control device efficiency,

 approved by

the Agency and approved by USEPA as a SIP

revision, and

4)

 The printing line is equipped with a capture

system and control device that provides an overall

reduction in VON emissions of at least:

A)

 75 percent where a publication rotogravure

printing line is employed,

or

B)

 65 percent where a packaging rotogravure

printing line

 is employed,

or

C)

 60 percent where a flexographic printing line

is employed, and

4)

 The control device is equipped with the applicable

 monitoring equipment specified in Section

219.105(d) (2)

 and the monitoring equipment is

installed,

 calibrated,

 operated and maintained

according to vendor specifications at all times

the control device is in use, and

119—55 7

96

5)

 The capture system and control device are operated

at all times when the subject printing line is in

operation.

 The owner or operator shall

demonstrate compliance with this subsection by

using the applicable capture system and control

device test methods and procedures specified in

Section 219.105(c)

 through Section 219.105(f)

and

by complying with the recordkeeping and reporting

requirements specified in Section 219.404(e).

Section 219.402

 Applicability

a)

 The limitations of Section 219.401 apply to all

flexographic and rotogravure printing lines at

a

subject facility.

 All facilities with flexographic

and/or rotogravure printing lines are subject

facilities unless:

1)

 Total maximum theoretical emissions of VON from

all fiexographic and rotogravure printing line(s)

at the facility never exceed 90.7 Mg

 (100 tons)

per calendar year before the application of

capture systems and control devices,

or

2)

 A federally enforceable construction permit or SIP

 revision for all fiexographic and rotogravure

printing line(s)

 at a facility requires the owner

or operator to limit production or capacity of

these printing line(s) to reduce total VON

emissions from all flexographic and rotogravure

printing line(s)

 to 90.7 Mg

 (100 tons)

 or less per

calendar year before the application of capture

systems and control devices.

b)

 Upon achieving compliance with this

 Subpart,

the

emission source

 is not required to meet Subpart G

(Sections 219.301 or 219.302)

 Emission sources exempt

from this Subpart are subject to Subpart G

 (Sections

219.301 or 215.802).

 Rotogravure or flexographic

equipment used for both roll printing and paper coating

is subject to this Subpart.

c)

 Once subject to the limitations of Section 219.401,

a

flexographic or rotogravure printing line

 is always

subject to the limitations of Section 219.401.

d)

 Any owner or operator of any fiexographic or

rotogravure printing line that is exempt from the

limitations of Section 219.401 because of the criteria

in this Section is subject to the recordkeeping and

reporting requirements specified

 in Section 219.404(b).

119—558

97

Section 219.403

 Compliance Schedule

Every owner or operator of a fiexographic and/or rotogravure

printing line shall comply with the applicable requirements of

Section 219.401 and Section 219.404

 in accordance with the

applicable compliance schedule specified in subsection

 (a),

 (b),

(c)

or

(d)

 below:

a)

 No owner or operator of a flexographic or rotogravure

printing line which

 is exempt from the limitations of

Section 219.401 because of the criteria

 in Section

219.402 shall operate said printing line on or after

a

date consistent with Section 219.106, unless the owner

or operator has complied with,

 and continues to comply

with, Section 219.404(b).

b)

 No owner or operator of a flexographic or rotogravure

printing line complying by means of Section 219.401(a)

shall

operate said printing line on or after a date

consistent with Section 219.106,

 unless the owner or

operator has complied with,

 and continues to comply

with,

 Section 219.401(a)

 and Section 219.404(c).

c)

 No owner or operator of a flexographic or rotogravure

printing line complying by means of Section 219.401(b)

shall operate said printing line on or after a date

consistent with Section 219.106, unless the owner or

operator has complied with,

 and continues to comply

with,

 Section 219.401(b)

 and Section 219.404(d).

d)

 No owner or operator of

 a flexographic or rotogravure

printing line complying by means of Section 219.401(c)

shall operate said printing line on or after a date

consistent with Section 219.106, unless the owner or

operator has complied with,

 and continues to comply

with,

 Section 219.401(c)

 and Section 219.404(e).

Section 219.404

 Recordkeeping and Reporting

a)

 The VOM content of each coating and ink and the

efficiency of each capture system and control device

shall be determined by the applicable test methods and

procedures specified

 in Section 219.105 to establish

the records required under this Section.

b)

 Any owner or operator of a printing line which is

exempted from the limitations of

Section 219.401

because of the criteria in Section 219.402 shall comply

with the following:

1)

 By a date consistent with Section 219.106, the

119—5 59

98

owner or operator of

 a facility to which this

subsection is applicable shall certify to the

Agency that the facility

 is exempt under the

provisions of Section 219.402.

 Such certification

shall include:

A)

 A declaration that the facility is exempt

from the limitations of the criteria in

Section 219.401 because of Section 219.402,

and

B)

 Calculations which demonstrate that total

maximum theoretical emissions of VOM from all

flexographic and rotogravure printing lines

at the facility never exceed 90.7 Mg

(100 tons) per calendar year before the

application of capture systems and control

devices.

 Total maximum theoretical emissions

of VON for a flexographic or rotogravure

printing facility is the sum of maximum

theoretical emissions

 of VON from each

flexographic and rotogravure printing line at

the facility.

 The following equation shall

be used to calculate total maximum

theoretical emissions of VON per calendar

year before the application of capture

systems and control devices for each

flexographic and rotogravure printing line at

the facility:

E~

 A x B

where:

 Total maximum theoretical emissions of

VON from one flexographic or rotogravure

printing line in units of kg/year

(lbs/year),

A

 Weight of VON per volume of solids

of

the coating or ink with the highest VON

content as applied each year on the

printing line

 in units of kg

VON/i

 (lbs

VON/gal)

 of coating or ink solids, and

B

 Total volume of solids for all coatings

and inks that can potentially be applied

each year on the printing line in units

of 1/year

 (gal/year).

 The instrument

and/or method by which the owner or

119—560

99

operator accurately measured or

calculated the volume of each coating

and ink as applied and the amount that

can potentially be applied each year on

the printing line shall be described in

the certification to the Agency.

2)

 On and after a date consistent with Section

219.106, the owner or operator of a facility

referenced in this subsection shall collect and

record all of the following information each year

for each printing line and maintain the

information at the facility for a period of three

years:

A)

 The name and identification number of each

coating and ink as applied on each printing

line.

B)

 The VON content and the volume of each

coating and ink as applied each year on each

printing line.

3)

 On and after a date consistent with Section

219.106,

 the owner or operator of a facility

exempted from the limitations of Section 219.401

because of the criteria in Section 219.402 shall

notify the Agency of any record showing that total

maximum theoretical emissions of VON from all

printing lines exceed 90.7 Mg

 (100 tons)

 in any

calendar year before the application of capture

systems and control devices by sending

 a copy of

such record to the Agency within 30 days after the

exceedance occurs.

c)

 Any owner or operator of a printing line subject to the

limitations of Section 219.401 and complying by means

of Section 219.401(a)

 shall comply with the following:

1)

By

a date consistent with Section 219.106,

 or upon

initial start-up of a new printing line,

 or upon

changing the method of compliance from an existing

subject printing line from Section 219.401(b)

or

Section 219.401(c)

 to Section 219.401(a),

the

owner or operator of a subject printing line shall

certify to the Agency that the printing line will

be in compliance with Section 219.401(a)

 on and

after a date consistent with Section 219.106,

or

on and after the initial start-up date.

 Such

certification shall include:

A)

 The name and identification number of each

119—56 1

100

coating and ink as applied on each printing

line.

B)

 The VON content of each coating and

 ‘ink as

applied each day on each printing line.

2)

 On and after a date consistent with Section

219.106,

 or on and after the initial start-up

date,

 the owner or operator of a printing line

subject to the limitations of Section 219.401 and

 complying by means of Section 219.401(a)

 shall

collect and record all of the following

information each day for each coating line and

maintain the information at the facility for

a

period of three years:

A)

 The name and identification number of each

coating and ink as applied on each printing

line.

B)

 The VON content of each coating and ink as

applied each day on each printing line.

3)

 On and after a date consistent with Section

219.106,

 the owner or operator of a subject

printing line shall notify the Agency

 in the

following instances:

A)

 Any record showing violation of Section

219.401(a)

 shall be reported by sending

a

copy of such record to the Agency within

30

days following the occurrence of the

violation.

B)

 At least 30 calendar days before changing the

method of compliance with Section 219.401

from Section 219.401(a)

 to Section 219.401(b)

or

 (c), the owner or operator shall comply

with all requirements

 of subsection

 (b) (1)

or

(c) (1), respectively.

 Upon changing the

method of compliance with Section 219.401

from Section 219.401(a)

 to Section 219.401(b)

or

 (c), the owner or operator shall

comply

with all requirements of subsection

(b)

or

 (c), respectively.

ci)

 Any owner or operator of a printing line subject to the

limitations of Section 219.401 and complying by means

of Section 219.401(b)

 shall comply with the following:

1)

 By a date consistent with Section 219.106,

 or upon

initial start-up of a new printing line,

 or upon

119—562

101

changing the method of compliance for an existing

subject printing line from Section 219.401(a)

or

(C)

 to Section 219.401(b),

 the owner or operator

of the subject printing line shall certify to the

Agency that the printing line will be in

compliance with Section 219.401(b)

 on and after

a

date consistent with Section 219.106,

 or on and

after the initial start-up date.

 Such

certification shall include:

A)

 The name and identification number of each

printing line which will comply by means

of

Section 219.401(b)

B)

 The name and identification number of each

coating and ink available for use on each

printing line.

C)

 The VON content of each coating and ink as

applied each day on each printing line.

D)

 The instrument or method by which the owner

or operator will accurately measure or

calculate the volume of each coating and ink

as applied each day on each printing line.

E)

 The method by which the owner or operator

will create and maintain records each day as

required in subsection

 (b) (2).

F)

 An example of the format in which the records

required in subsection

 (b) (2) will be kept.

2)

 On and after a date consistent with Section

219.106, or on and after the initial start—up

date,

 the owner or operator of a printing line

subject to the limitations of Section 219.401 and

complying by means of Section 219.401(b)

 shall

collect and record all of the following

information each day for each printing line and

maintain the information at the facility for

a

period of three years:

A)

 The name and ‘identification number of each

coating and ink as applied on each printing

line.

B)

 The VOM content and the volume of each

coating and ink as applied each day on each

printing line.

C)

 The daily-weighted average VON content of all

119—563

102

coatings and inks as applied on each printing

line.

3)

 On and after

 a date consistent with Section

219.106, the owner or operator of a subject

printing line shall notify the Agency in the

following instances:

A)

 Any record showing violation of Section

219.401(b)

 shall be reported by sending a

copy of such record to the Agency within 30

days following the occurrence of the

violation.

B)

 At least 30 calendar days before changing thE

method of compliance with Section 219.401

from Section 219.401(b)

 to Section 219.401(a)

or 219.401(c),

 the owner or operator shall

comply with all requirements of subsection

(c) (1)

or

 (e) (1), respectively.

 Upon

changing the method of compliance with

Section 219.401 from Section 219.401(b)

to

Section 219.401(a)

or

(C),

 the owner or

operator shall comply with all requirements

of subsection

(c)

or

 (e)., respectively.

e)

 Any owner or operator of a printing line subject to th

limitations of Section 219.401 and complying by means

of Section 219.401(c)

 shall comply with the following:

1)

 By a date consistent with Section 219.106, or upon

initial start-up of a new printing line,

 or upon

changing the method of compliance for an existing

printing line from Section 219.401(a)

or

(b)

to

Section 219.401(c),

 the owner or operator of the

subject printing line shall perform all tests and

submit to the Agency the results of all tests and

calculations necessary to demonstrate that the

subject printing line will be in compliance with

Section 219.401(c)

 on and after

 a date consistent

with Section 219.106, or on and after the initial

start-up date.

2)

 On and after a date consistent with Section

219.106, or on and after the initial start-up

date,

 the owner or operator of a printing line

subject to the limitations of Section 219.401 and

complying by means of Section 219.401(c)

 shall

collect and record all of the following

information each day for each printing line and

maintain the information at the facility for a

period of three years:

119—564

103

A)

 Control device monitoring data.

B)

 A log of operating time for the capture

system,

 control device, monitoring equipment

and the associated printing line.

C)

 A maintenance log for the capture system,

control device and monitoring equipment

detailing all routine and non—routine

maintenance performed including dates and

duration of any outages.

3)

 On and after

 a date consistent with Section

219.106, the owner or operator of a subject

printing line shall notify the Agency in the

following instances:

A)

 Any record showing violation of Section

219.401(c),

 shall be reported by sending a

copy of such record to the Agency within 30

days following the occurrence of the

violation.

B)

 At least

 30 calendar days before changing the

method of compliance with Section 219.401

from Section 219.401(c)

 to Section 219.401(a)

or

 (b), the owner or operator shall comply

with all requirements of subsection

 (c) (1)

or

(d) (1), respectively.

 Upon changing the

method of compliance with Section 219.401

from Section 219.401(c)

 to Section 219.401(a)

or

 (b), the owner or operator shall comply

with all requirements of subsection

(c)

or

(ci), respectively.

Section 219.405

 Heatset—Web-Offset Lithographic Printing

a)

 Applicability

1)

 The limitations of subsection

 (b) below apply to

all heatset—web-offset lithographic printing lines

at a subject facility.

 All facilities with

heatset—web-offset lithographic printing lines are

subject facilities unless:

A)

 Total maximum theoretical emissions of VON

from all heatset-web-offset lithographic

printing lines at the facility never exceed

90.7 Mg (100 tons)

 per calendar year in the

absence of air pollution control equipment,

or

119—565

104

B)

 A federally enforceable construction permit

or SIP revision for all heatset-web-offset

lithographic printing lines(s)

 at a facility

 requires the owner or operator to limit

production or capacity of these printing

line(s) to reduce total VON emissions from

all heatset-web—offset lithographic printing

line(s) to 90.7 Mg (100 tons)

 per calendar

year or less in the absence of air pollution

control equipment,

and

2)

 Any owner or operator of any heatset—web-offset

lithographic printing line that is exempt from the

limitations in subsection

 (b) because of the

criteria in subsection

 (a) (1)

 shall be subject

to

the recordkeeping and reporting requirements

in

subsection

 (c) (1).

b)

 Specific Provisions.

 No owner or operator of a subject

heatset—web— offset printing line may cause or allow

the operation of the subject heatset-web-offset

printing line unless the owner or operator meets the

requirements in subsection

 (b) (1)

or

 (b) (2)

 and the

requirements in subsections

 (b) (3)

and

 (b) (4)

 below.

1)

 An afterburner system is installed and operated

that reduces 90 percent of the VOM emissions from

the dryer exhaust,

or

2)

 The fountain solution contains no more than

8 percent, by weight,

 of VON and a condensation

recovery system is installed and operated that

removes at least 75 percent of the non—isopropyl

alcohol organic materials from the dryer exhaust,

and

3)

 The control device is equipped with the applicable

monitoring equipment specified in Section

219.105 (ci) (2)

 and the monitoring equipment is

installed,

 calibrated, operated and maintained

according to vendor specifications at all times

the control device is in use,

and

4)

 The control device is operated at all times when

the subject printing line is

 in operation.

The

owner or operator shall demonstrate compliance

with this Section by using the applicable test

methods and procedures specified in Section

219.105(a),

 (d), and

 (f) and by complying with the

recordkeeping and reporting requirements specified

in subsection

(c)

 below.

119—566

105

c)

 Recordkeeping and Reporting.

 The VON content of each

fountain solution and ink and the efficiency of each

control device shall be determined by the applicable

test methods and procedures specified in Section

219.105 to establish the records required-under this

subsection.

1)

 Any owner or operator of a printing line which is

exempted from the limitations of subsection

(b)

because of the criteria in subsection

(a)

 shall

comply with the following:

A)

 By a date consistent with Section 219.106,

 the owner or operator of a facility to which

subsection

 (c) (1)

 is applicable shall certify

to the Agency that the facility is exempt

under the provisions of subsection

 (a).

 Such

certification shall include:

i)

 A declaration that the facility is

exempt from the limitations of

subsection

 (b) because of the criteria

in subsection

 (a), and

ii)

 Calculations which demonstrate that

total maximum theoretical emissions of

VON from all heatset-web-offset

lithographic printing lines at the

facility never exceed 90.7 Mg

 (100 tons)

per calendar year before the application

of air pollution control equipment.

Total maximum theoretical emissions of

VON for a heatset-web-offset

lithographic printing facility is the

sum of maximum theoretical emissions of

VON from each heatset-web-offset

lithographic printing line at the

facility.

 The following equation shall

be used to calculate total maximum

theoretical emissions of VON per

calendar year in the absence of air

pollution control equipment for each

heatset-web-offset lithographic printing

line at the facility.

E

 (A x

B)

~x

D)

p

100

where:

119—567

106

E~

 Total maximum theoretical emissions

of VON from one heatset—web-offset

printing line in units of kg/year

(lbs/year),

A

 Weight of VON per volume of solids

of ink with the highest VON content

as applied each year on the

printing line in units of kg

VON/i

(lbs VON/gal)

 of solids,

and

B

 Total volume of solids for all inks

that can potentially be applied

each year on the printing line

in

units of 1/year

 (gal/year).

The

instrument or method by which the

owner or operator accurately

measured or calculated the volume

of each ink as applied and the

amount that can potentially be

applied each year on the printing

line shall be described in the

certification to the Agency.

C

 The weight percent VON of the

fountain solution with the highest

VON content.

D

 The total volume of -fountain

solution that can potentially be

used each year on the printing line

in units of 1/year

 (gal/year)

The

instrument and/or method by which

the owner or operator accurately

measured or calculated the volume

of each fountain solution used and

the amount that can potentially be

used each year on the printing line

shall be described in the

certification to the Agency.

B)

 On and after a date consistent with Section

219.106, the owner or operator of a facility

to which subsection

 (c) (1)

 is applicable

shall collect and record all of the following

information each year for each printing line

and maintain the information at the facility

for

 a period of three years:

i)

 The name and identification of each

fountain solution and ink as applied on

119—568

107

each printing line.

ii)

 The VON content and the volume of each

fountain solution and ink as applied

each year on each printing line.

C)

 On and after a date consistent with Section

219.106, the owner or operator of

 a facility

exempted from the limitations of subsection

(b) because of the criteria in subsection

(a)

shall notify the Agency of any record showing

that total maximum theoretical emissions of

VON from all printing lines exceed 90.7 Mg

(100 tons)

 in any calendar year in the

absence of air pollution control equipment by

sending a copy of such record to the Agency

within 30 days after the exceedance occurs.

2)

 Any owner or operator of a printing line subject

to the limitations of subsection

 (b) and complying

by means of subsection

 (b) (1)

 shall comply with

the following:

A)

 By a date consistent with Section 219.106,

or

upon initial start-up of a new printing line,

or upon changing the method of compliance for

an existing printing line from subsection

(b) (2) to subsection

 (b) (1); the owner or

operator of the subject printing line shall

perform all tests and submit to the Agency

the results of all tests and calculations

necessary to demonstrate that the subject

printing line will be

 in compliance with

subsection

 (b) (1)

 on and after a date

consistent with Section 219.106,

 or on and

after the initial start-up date.

B)

 On and after a date consistent with Section

219.106, or on and after the initial start-up

date,

 the owner or operator of a printing

line subject to the limitations of subsection

(b)

 and complying by means of subsection

(b) (1)

 shall collect and record the following

information each day for each printing line

and maintain the information at the facility

for a period of three years:

i)

 Control device monitoring data.

ii)

 A log of operating time for the control

device, monitoring equipment and the

associated printing line.

119—569

108

iii) A maintenance log for the control device

 and monitoring equipment detailing all

routine and nonroutine maintenance

performed including dates and duration

of any outages.

C)

 On and after a date consistent with Section

219.106, the owner or operator of

 a subject

printing line shall notify the Agency in the

following instances:

1)

 Any record showing violation of

subsection

 (b) (1)

 shall be reported

by

sending a copy of such record to the

Agency within 30 days following the

occurrence of the violation.

ii)

 At least

 30 calendar days before

changing the method of compliance with

subsection

 (b) from subsection

 (b) (1)

to

(b) (2), the owner or operator shall

comply with all requirements of

subsection

(C)

(3) (A).

 Upon changing

the

method of compliance with subsection

(b)

from subsection

 (b) (1)

to

 (b) (2)

the

owner or operator shall comply with

all

requirements of subsection

 (c) (3).

3)

 Any owner or operator of a printing line subject

to the limitations of subsection

 (b) and complying

by means of subsection

 (b) (2)

 shall comply with

the following:

A)

 By a date consistent with Section 219.106,

or

upon initial start-up of a new printing line,

or upon changing the method of compliance

for

an existing printing line from subsection

(b)(1)

 to (b)(2); the owner or operator of

the subject printing line shall perform all

tests and submit to the Agency and the USEPA

the results of all tests and calculations

necessary to demonstrate that the subject

printing line will be in compliance with

subsection

 (b) (2) on and after a date

consistent with Section 219.106,

 or on and

after the initial start-up date.

B)

 On and after a date consistent with Section

219.106,

 or on and after the initial start-up

date,

 the owner or operator of

 a printing

line subject to the limitations of subsection

119—570

109

(b)

 and complying by means of subsection

(b) (2)

 shall collect and record the following

information each day for each printing line

and maintain the information at the facility

for a period of three years:

i)

 The VOM content of the fountain solution

used each day on each printing line.

ii)

 A log of operating time for the control

device and the associated printing line.

iii) A maintenance log for the control device

detailing all routine and non—routine

maintenance performed including dates

 and duration of any outages.

C)

 On and after a date consistent with Section

219.106, the owner or operator of a subject

printing line shall notify the Agency in the

following instances:

I)

 Any record showing violation of

subsection

 (b) (2)

 shall be reported by

 sending

 a copy of such record to the

Agency within

 30 days following the

occurrence of the violation.

ii)

 At least

 30 calendar days before

changing the method of compliance with

subsection

(b)

 from subsection

 (b) (2)

to

(b) (1), the owner

 or operator shall

comply with all requirements of

subsection

 (c) (2) (A).

 Upon changing the

method of compliance with subsection

(b)

from subsection

 (b)(2)

to

 (b)(1), the

owner or operator shall comply with all

requirements of subsection

 (c) (2).

ci)

 Compliance Schedule.

 Every owner

 or operator of a

heatset-web-offset lithographic printing line shall

comply with the applicable requirements of subsections

(b) and

(c)

 in accordance with the applicable

compliance schedule specified in subsection

 (ci) (1),

(ci)

(2),

or

 (d) (3)

 below:

1)

 No owner or operator of a heatset—web—offset

 lithographic printing line which is exempt from

the limitations of subsection

 (b) because of the

criteria in subsection

(a)

 shall operate said

printing line on or after

 a date consistent with

Section 219.106, unless the owner or operator has

119—57 1

110

complied with, and continues to comply with,

subsection

 (b) (1) and

 (c) (1).

2)

 No owner or operator of a heatset—web—offset

lithographic printing line complying by means of

subsection

 (b) (1)

 shall operate said printing line

on or after a date consistent with Section

219.106, unless the owner or operator has complied

with,

 and continues to comply with,

 subsection

(b) (2)

and

 (c) (2)

3)

 No owner or operator of a heatset—web—offset

lithographic printing line complying by means of

subsection

 (b) (2)

 shall operate said printing line

on or after a date consistent with Section

219.106,

 unless the owner or operator has complied

 with,

 and continues to comply with,

 subsection

(c) (3)

SUBPART Q:

 LEAKS FROM SYNTHETIC ORGANIC CHEMICAL

AND POLYMER MANUFACTURING EQUIPMENT

Section 219.421

 General Requirements

The owner or operator of a plant which processes more than 3660

mg/yr

 (4033 tons/year)

 gaseous and light liquid VOM,

 and whose

components are used to manufacture the synthetic organic

chemicals or polymers listed in Appendix A,

 shall comply with

this Subpart.

 The provisions of this Subpart are applicable to

components containing 10 percent or more by weight VON as

determined by ASTM method E-168,

 E—l69 and E-260,

 incorporated by

reference in Section 219.112.

 Those components that are not

process unit components are exempt from this Subpart.

A

component shall be considered to be leaking if the VON is equal

to,

 or is greater than 10,000 ppmv as methane or hexane as

determined by USEPA Reference Method

 21, as specified at 40 CFR

60, Appendix A,

 incorporated by reference in Section 219.112,

indication of liquids dripping, or indication by a sensor that a

seal or barrier fluid system has failed.

 The provisions of this

Subpart are not applicable

 if the equipment components are used

to produce heavy liquid chemicals only from heavy liquid feed or

raw materials.

Section 219.422

 Inspection

Prøgram Plan for Leaks

The owner or operator of

 a synthetic organic chemical or polymer

manufacturing plant subject to Section 219.421 shall prepare an

inspection program plan which contains,

 at a minimum:

a)

 An identification of all components and the period in

 which each will be monitored pursuant to Section

219.423.

119—572

111

b)

 The format for the monitoring log required by Section

219.425.

c)

 A description of the monitoring equipment to be used

when complying with Section 219.423,

and

ci)

 A description of the methods to be used to identify all

pipeline valves, pressure relief valves in gaseous

service,

 all leaking components,

 and components

exempted under Section 219.423(i)

 such that they are

obvious and can be located by both plant personnel

performing monitoring and Agency personnel performing

inspections.

Section 219.423

 Inspection Program for Leaks

The owner or operator of a synthetic organic chemical or polymer

manufacturing plant subject to this subpart’ shall,

 for the

purposes of detecting leaks, conduct a component inspection

program using the test methods specified in Method

21,

 40 CFR 60,

Appendix A

 (1986),

 incorporated by reference in Section 219.112,

consistent with the following provisions:

a)

 Test annually those components operated near extreme

temperature or pressure such that they would be unsafe

to routinely monitor and those components which would

require the elevation of monitoring personnel higher

than two meters above permanent worker access

 structures or surfaces.

b)

 Test quarterly all other pressure relief valves in gas

service, pumps

 in light liquid service, valves in light

liquid service and in gas service,

 and compressors.

c)

If

 less than or equal to 2 percent of the valves in

light liquid service and in gas service tested pursuant

to subsection

 (b) are found not to leak for

five consecutive quarters, no leak tests shall be

required for three consecutive quarters.

 Thereafter,

leak tests shall resume for the next quarter.

 If that

test shows less than or equal to

 2 percent of the

valves in light liquid service -and in gas service are

leaking, then no tests are required for the next

three quarters.

 If more than

 2 percent are leaking,

then tests are required for the next five quarters.

d)

 Observe visually all pump seals weekly.

e)

 Test immediately any pump seal from which liquids are

observed dripping.

119—573

112

f)

 Test any relief valve within 24 hours after it has

vented to the atmosphere.

g)

 Routine instrument monitoring of valves which ‘are not

externally regulated, flanges,

 and equipment in heavy

liquid service,

 is not required.

 However, any valve

which is not externally regulated,

 flange or piece of

 equipment in heavy liquid service that is found to be

leaking on the basis of sight,

 smell or sound shall be

repaired as soon as practicable but no later than

30 days after the leak is found.

h)

 Test immediately after repair any component that

was

found leaking.

i)

 Within one hour of its detection,

 a weatherproof,

readily visible tag,

 in bright colors such as red or

yellow, bearing an identification number and the date

on which the leak was detected must be affixed on the

leaking component and remain

 in place until the leaking

component is repaired.

j)

 The following

components are exempt from the monitoring

requirements in this Section:

1)

 Any component that is in vacuum service,

and

2)

 Any pressure relief valve that is connected to an

operating flare header or vapor recovery device.

Section 219.424

 Repairing Leaks

All leaking components must be repaired and retested as soon as

practicable but no later than 15 days after the leak is found

unless the leaking component cannot be repaired until the process

unit is shut down.

 Records of repairing and retesting must be

maintained in accordance with Section 219.425 and 219.426.

Section 219.425

 Recordkeeping for Leaks

a)

 The owner or operator of a synthetic organic chemical

or polymer manufacturing plant shall maintain a leaking

components monitoring log which shall contain, at a

minimum,

 the following information:

1)

 The name of the process unit where the component

is located;

2)

 The type of component

 (e.g., valve,

 seal);

3)

 The identification number of the component;

119—574

113

4)

 The date on which a leaking component is

discovered;

5)

 The date on which

 a leaking component is repaired;

6)

 The date and instrument reading of the recheck

procedure after a leaking component is repaired;

7)

 A record of the calibration of the monitoring

instrument;

8)

 The identification number of leaking components

which cannot be repaired until process unit

shutdown; and

9)

 The total number of valves

 in light liquid service

and in gas service inspected; the total number and

the percentage of these valves found leaking

during the monitoring period.

b)

 Copies of the monitoring log shall be retained by the

owner or operator for a minimum of two years after the

date on which the record was made or the report was

prepared.

c)

 Copies of the monitoring log shall

 be, made available to

the Agency upon verbal or written request prior to or

at the time of inspection pursuant to Section 4(d)

of

the Environmental Protection Act

 (Act)

 (Ill. Rev.

 Stat.

1989,

ch.

 111 1/2,

 pars.

 1001 et seq.)

 at any

reasonable time.

Section 219.426

 Report for Leaks

The owner or operator of a synthetic organic chemical or polymer

manufacturing plant subject to Section 219.421 through 219.430

shall:

a)

 Submit quarterly reports to the Agency on or before

March 31, June 30, September 30,

 and December 31 of

each year,

 listing all leaking components identified

pursuant to Section 219.423 but not repaired within

15

days,

 all leaking components awaiting process unit

shutdown, the total number of components inspected,

thE

type of components inspected,

 and the total number of

components found leaking, the total number of valves

ir

light liquid service and in gas service inspected and

the number and percentage of valves in light liquid

service and in gas service found leaking.

b)

 Submit

 a signed statement with the report attesting

that all monitoring and repairs were performed as

119—575

114

required under Section 219.421 through 219.427.

Section 219.427

 Alternative Program for Leaks

The Agency shall approve an alternative program of monitoring,

recordkeeping,

 or reporting to that prescribed in this Subpart

upon a demonstration by the owner or operator of such plant that

the alternative program will provide plant personnel and Agency

personnel with an equivalent ability to identify and repair

leaking components.

 Any alternative program can be allowed when

approved by the Agency and approved by the USEPA as a SIP

revision.

Section 219.428

 Open-Ended Valves

a)

 Each open-ended valve shall be equipped with a cap,

blind flange, plug,

or

 a second valve,

 except during

operations requiring fluid flow through the open-ended

valve.

b)

 Each open-ended valve equipped with a second valve

shall be operated in

 a manner such that the valve on

the process fluid end is closed before the second valve

is closed.

c)

 Components which are open—ended valves and which serve

as

 a sampling connection shall be controlled such that:

1)

 A closed purge system or closed vent system shall

return purged process fluid to the process line

with no detectable volatile organic material

emissions to the atmosphere,

or

2)

 A closed purge system or closed vent system shall

collect and recycle purged process fluid to the

process line with no detectable volatile organic

material emissions to the atmosphere,

or

3)

 Purged process fluid shall be transported to a

control device that complies with the requirements

of Section 219.429.

ci)

 In—situ sampling systems are exempt from subsection

(c).

Section 219.429

 Standards for Control Devices

Control devices used to comply with Section 219.428(c)

 shall

comply with the following:

a)

 If the control device is

 a vapor recovery system

 (for

example, condensers and adsorbers),

 it shall be

119—576

115

designed and operated to recover the volatile organic

material emissions vented to it with an efficiency

of

95 percent or greater.

b)

 If the control device is an enclosed combustion device,

it shall be designed and operated to reduce the

volatile organic material emissions vented to it with

an efficiency of 95 percent or greater,

 or to provide a

minimum residence time of

0.75 seconds at a minimum

temperature of 816oC.

c)

 If the control device is a flare,

 it shall:

1)

 Be designed for and operated with no visible

emissions as determined by USEPA Reference Method

22,

 40 CFR 60, Appendix A (1986),

 incorporated by

reference in Section 219.112, except for

periods

not to exceed a total of

 5 minutes during any

2

consecutive hours.

2)

 Be operated with a pilot flame present at all

 times and shall be monitored with a thermocouple

or any other equivalent device to detect the

presence of the pilot flame.

3)

 Be steam—assisted,

 air—assisted,

 or nonassisted.

4)

 Be used only with the net heating value of the gas

being combusted being 11.2 MJ/scm

 (300 Btu/scf)

or

greater if the flare

 is steam—assisted or

air-assisted; or with the net heating value of the

gas being combusted being 7.45 NJ/scm or greater

if the flare is nonassisted.

 The net heating

value

 of the gas being combusted shall be

calculated using the following equation:

H

K

S

 C.H.

r

1=1

~

Where:

Hr

 Net heating value of

the sample in NJ/scm;

where the net enthalpy per mole of offgas is based

on combustion at 25°Cand 760 mm Hg, but the

standard temperature for determining the volume

corresponding to one mole is 2OoC.

K

 Constant,

1.740 x 10~ (1/ppm) (g—mole/scm) (MJ/Kcal)

119—57 7

116

where

standard temperature for (g—mole/scm)

 is 20°C.

C1

 Concentration of sample component i,

 in ppm,

as measured by USEPA Reference Method

18,

40

CFR 60, Appendix A

 (1986), and ASTM D

2504-83, both incorporated by reference

in

Section 219.112.

H1

 Net heat of combustion of

sample component

i,

kcal/g mole.

 The heats of combustion may be

determined using ASTM D 2382-83, incorporated

by reference in Section 219.112,

 if published

values are not available or cannot be

calculated.

5)

 Steam—assisted and nonassisted flares shall be

designed and operated with an exit velocity,

as

determined by dividing the volumetric flowrate

(in

units of standard temperature and pressure),

as

determined by USEPA Reference Method

 2 or

2A,

40

CFR 60, Appendix A

 (1986)

 incorporated by

reference in Section 219.112,

 as appropriate; by

the unobstructed

 (free)

 cross sectional area of

the flare tip, less than 18

m/sec

 (60 ft/sec).

6)

 Air—assisted flares shall be designed and operated

with an exit velocity less than the maximum

permitted velocity,

 Vmaxi

 as determined by the

following equation:

V

 8.706

+

0.7084(H).

Vmax

 Maximum permitted velocity, m/sec.

8.706

 Constant.

0.7084

 Constant.

Hr

 The net heating value as determined

in

subsection

 (c) (4)

 of this section.

d)

 If the control device is a closed container,

 it shall

be designed and operated to reduce the volatile organic

material emissions, vented from purged process fluid

after transfer, to no detectable volatile organic

material emissions as determined by USEPA Reference

Method

 21 as specified at 40 CFR 60, Appendix A

 (1986),

incorporated by reference in Section 219.112.

For

purposes of this Section, the phrase

“after transfer”

shall refer to the time at which the entire amount of

purged process fluid resulting from a flushing or

cleaning of the sample line enters the closed container

119—578

117

or containers including the final container(s) prior to

disposal.

e)

 The owner or

operator of a control device shall monitor

the control device to ensure that it is operated and

maintained in conformance with the manufacturer’s

specifications, modified to the particular process

design.

f)

 The control device shall be operated at all times when

emissions may be vented to

it.

Section 219.430

 Compliance-Date

The owner or operator of a synthetic organic chemical or

polymer

manufacturing plant subject to

35

 Ill. Adm. Code 215.430 through

215.438

as

 of December 31,

 1987 shall have complied with the

standards and limitations

of those Sections no later than

December

31,

 1987.

SUBPART R:

 PETROLEUM REFINING AND RELATED INDUSTRIES; ASPHALT MATERIALS

Section 219.441

 Petroleum Refinery Waste Gas Disposal

a)

 Except as provided in subsection

 (b) or

 (c),

 no person

shall cause or allow the discharge of organic materials

in excess of

100 ppm equivalent methane

 (molecular

weight 16.0)

 into the atmosphere from:

1)

 Any catalyst regenerator of a petroleum cracking

system; or

2)

 Any petroleum fluid coker; or

3)

 Any other waste gas stream from any petroleum or

petrochemical manufacturing process.

b)

 Exception.

 Existing sources subject to subsection

(a)

(3) may,

 alternatively,

 at their election, comply

with

the organic material emission limitations imposed

by

 35 Iii.

 Adm.

 Code 215.301 or 215.302; provided,

however, that there shall be no -increase in emissions

 from such sources above the level of emissions in

existence on Nay 3,

 1979.

c)

 New Sources.

 Sources ~ubject to subsection

 (a) (3),

construction of which commenced on or after January

1,

1977, may,

 at their election, comply with the following

emission limitations:

1)

 A maximum of eight pounds per hour of organic

119—579

118

material; or

2)

 Emission of organic material

 in excess of the

limitation of subsection

 (c) (1)

 is allowable if

such emissions are controlled by air pollution

control methods or equipment approved by the

Agency capable of reducing by 85 percent or more

the uncontrolled organic material that would

otherwise be emitted to the atmosphere.

 Such

methods or equipment must be approved by the

Agency and approved by the USEPA as a SIP

revision.

Section 219.442

 Vacuum Producing Systems

No owner or operator of a petroleum refinery shall cause or allow

the operation of any vacuum producing system unless the

condensers,

 hot wells and accumulators of any such system are

equipped with vapor loss control equipment including, but not

limited to, piping, valves,

 flame arrestors and hot well covers,

to vent any volatile organic material with a vapor pressure of

10.34 kPa

 (1.5 psia)

 or greater at 294.3oK

 (70°F) to a heater,

fire box,

 flare, refinery fuel gas system,

 or other equipment or

system of equal emission control as approved by the Agency and

approved by the USEPA as a SIP revision.

 This Section shall not

apply to vacuum producing systems on lube units.

Section 219.443

 Wastewater

 (Oil/Water)

 Separator

No owner

or operator of a petroleum refinery shall operate any

wastewater

 (oil/water) separator at a petroleum refinery unless

the separator is equipped with air pollution control equipment

capable of reducing by 85 percent or more the uncontrolled

organic material emitted to the atmosphere.

 If no odor nuisance

exists,

 the limitation of this Section shall not apply if the

vapor pressure of the organic material is below 10.34 kPa

 (1.5

psia)

 at 204.3oK (70°F) at all times.

Section 219.444

 Process Unit Turnarounds

a)

 No owner or operator of a-petroleum refinery shall

cause or allow a refinery process unit turnaround

except

 in compliance with an operating procedure as

approved by the Agency.

b)

 Unless

 a procedure was already on file with the Agency

as part of an approved operating permit no later than

November

1,

 1979,

 the owner or operator of

 a petroleum

refinery shall submit to the Agency for approval

a

detailed procedure for reducing emissions of volatile

organic material during refinery process unit

turnarounds from organic material with a vapor pressure

119—580

119

of 10.34 kPa (1.5 psia) or greater at

294.3oK

(7OoF).

The Agency shall not approve the procedure unless it

provides for:

1)

 Depressurization of the refinery process unit or

vessel to a flare, refinery fuel gas system,

or

other equipment or system of equal emission

control,

 as approved by the Agency and approved

by

the USEPA as a SIP revision, until the internal

pressure from the vessel or unit is less than 5.0

psig before allowing the vessel to be vented to

the atmosphere;

2)

 Recordkeeping of the following items:

A)

 Each date that a refinery unit or vessel is

shut down;

and

B)

 The total estimated quantity of volatile

organic material emitted to the atmosphere

and the duration of the emission

 in hours.

Section 219.445

 Leaks:

 General Requirements

a)

 The owner or operator of a petroleum refinery shall:

1)

 Develop a monitoring program plan consistent with

the provisions of Section 219.446;

 Conduct a monitoring program consistent with the

 provisions of Section 219.447;

3)

 Record all leaking components which have a

volatile organic material concentration exceeding

10,000 ppm consistent with the provisions of

Section 219.448;

4)

 Identify each component consistent with the

monitoring program plan submitted pursuant to

Section 219.446;

5)

 Repair and retest the leaking components as soon

as possible within 22 days after the leak

is

found, but no later than June

 1 for the purposes

of Section 219.447(a) (1), unless the leaking

components cannot be repaired until the unit is

shut down for turnaround; and

6)

 Report to the Agency consistent with the

provisions of Section 219.449.

Section 219.446

 Monitoring Program Plan for Leaks

119—58 1

120

The owner or operator of a petroleum refinery shall prepare

a

monitoring program plan which contains, at a minimum:

a)

 An identification of all refinery components and the

period in which each will be monitored pursuant to

Section 219.447;

b)

 The format for the monitoring log required by Section

219

448;

c)

 A description of the monitoring equipment to be used

pursuant to Section 219.447; and

d)

 A description of the methods to be used to identify all

 pipeline valves, pressure relief valves in gaseous

service and all leaking components such that they are

obvious to both refinery personnel performing

monitoring and Agency personnel performing inspections.

Section 219.447

 Monitoring Program for Leaks

a)

 The owner or operator of a petroleum refinery subject

to Section 219.445 shall,

 for the purpose of detecting

leaks,

 conduct a component monitoring program

consistent with the following provisions:

1)

 Test once between March

 1 and June

 1 of each year,

by methods referenced in Section 219.105(g),

all

pump seals,

 pipeline valves in liquid service and

process drains.

2)

 Test once each quarter of each calendar year, by

methods referenced in Section 219.105(g),

all

pressure relief valves in gaseous service,

pipeline valves in gaseous service and compressor

seals.

3)

 Inaccessible valves may be tested once each

calendar year instead of once each quarter of each

calendar year.

4)

 Observe visually all pump seals weekly.

5)

 Test immediately any pump seal from which liquids

are observed dripping,

6)

 Test any relief valve within 24 hours after

 it has

vented to the atmosphere,

and

7)

 Test immediately after repair any component that

was found leaking.

119—582

121

 Storage tank valves and pressure relief devices

connected to an operating flare header or vapor

recovery device are exempt from the monitoring

requirements in subsection

 (a).

c)

 The Agency may require more frequent monitoring than

would otherwise be required by subsection

(a)

for

components which are demonstrated to have a history of

leaking.

Section 219.448

 Recordkeeping for Leaks

a)

 The owner or operator of a petroleum refinery shall

maintain a leaking components monitoring log which

shall contain,

 at a minimum, the following information:

1)

 The name of the process unit where the component

is located;

2)

 The type of component

 (e.g., valve,

 seal);

3)

 The identification number of the component;

4)

 The date on which a leaking component is

discovered;

5)

 The date on which a leaking component is repaired;

6)

 The date and instrument reading of the recheck

procedure after a leaking component is repaired;

7)

 A record of the calibration of the monitoring

instrument;

8)

 The identification number of leaking components

which cannot be repaired until turnaround; and

 The total number of components inspeOted and the

total number of components found leaking during

that monitoring period.

 Copies of the monitoring log shall be retained by the

owner or operator for a minimum of two years after the

date on which the record was made or the report

prepared.

c)

 Copies of the monitoring log shall be made available to,

the Agency, upon verbal or written request,

 at any

reasonable time.

Section 219.449

 Reporting for Leaks

119—

5

83

122

The owner or operator of a petroleum refinery shall:

a)

 Submit a report to the Agency prior to the 1st day of

both July and September listing all leaking components

identified pursuant to Section 219.447 but not repaired

within 22 days,

 all leaking components awaiting unit

turnaround, the total number of components inspected

and the total number of components found leaking;

b)

 Submit a signed statement

with the report attesting

that all monitoring and repairs were performed as

required under Sections 219.445 through 219.448.

Section 219.450

 Alternative Program

 for Leaks.

The Agency may approve an alternative program of monitoring,

recordkeeping or reporting to that prescribed in Sections 219.446

through 219.449 upon

 a demonstration by the owner or operator of

a petroleum refinery that the alternative program will provide

refinery, Agency and USEPA personnel with an equivalent ability

to identify and repair leaking components.

 Any alternative

program can be allowed only if approved by the USEPA as a SIP

revision.

Section 219.451

 Sealing Device Requirements

Except for safety pressure relief valves,

 no’ owner or operator

of

a petroleum refinery shall install or operate a valve

 at the end

of a pipe or line containing volatile organic materials unless

the pipe or line is sealed with a second valve, blind flange,

plug,

 cap or other sealing device.

 The sealing device may be

removed only when a sample

 is being taken or during maintenance

operations.

Section 219.452

 Compliance Schedule for Leaks

The owner or operator of a petroleum refinery shall adhere to the

increments of progress contained in the following schedule:

a)

 Submit to the Agency a monitoring program consistent

with Section 219.446 prior to July

1,

 1991 or

 a date

consistent with Section 219.106.

b)

 Submit to the Agency the first monitoring report

pursuant to Section 219.449 prior to August

1,

 1991 or

a date consistent with Section 219.106.

Section 218.453

 Compliance Dates

Every owner or operator of a petroleum refinery subject to 35

Ill. Adm. Code 215, Subpart R as of December 31,

 1987 shall have

119—

5

84

123

complied with

its standards and limitations by December

31,

 1987.

SUBPART

5:

 RUBBER AND MISCELLANEOUS PLASTIC PRODUCTS

Section 219.461

 Manufacture of Pneumatic Rubber Tires

The owner or operator of an undertread cementing,

 treadend

cementing or bead dipping operation at a pneumatic rubber tire

manufacturing facility shall install and operate:

a)

 A capture system, with minimum capture efficiency of

65

percent by weight of VON for treadend cementing or bead

dipping operations and a capture system with a minimum

capture efficiency of 55.5 percent by weight of VON for

undertread cementing; and

b)

 A control device that meets the requirements of one of

the following:

1)

 A carbon adsorption system designed and operated

in a manner such that there

 is at least a 90

percent removal of VON by weight from the gases

ducted to the control device;

2)

 An afterburning system,that oxidizes at least 90

percent of the captured nonmethane VON

 (VOM

measured as total combustible carbon)

 to carbon

dioxide and water; and

3)

 An alternative VON emission reduction system

demonstrated to have at least a 90 percent-overall

reduction efficiency and approved by the Agency

and approved by the USEPA.

Section 219.462

 Green Tire Spraying Operations

The owner or operator of

 a green tire spraying operation at a

pneumatic rubber tire manufacturing facility shall:

a)

 Install and operate:

1)

 A capture system with a minimum capture efficiency

of 90 percent by weight of -VOM;

and

2)

 A control device that meets the requirements of

one of the following:

A)

 A carbon adsorption system designed and

operated in a manner such that there is at

least 90 percent removal of VON by weight

from the bases ducted to the control device;

‘119—585

124

B)

 An afterburning system that oxidizes at least

90 percent of the captured nonmethane

VON

(measured as total combustible carbon)

to

carbon dioxide and water; or

C)

 An alternative VON emission reduction system

demonstrated to have at least a 90 percent

overall reduction efficiency approved by

the

Agency and approved by the USEPA as a SIP

revision.

b)

 Substitute for the normal solvent—based mold release

compound water—based sprays containing:

1)

 No more than five percent by volume of VON as

applied for the inside of tires;

2)

 No more than ten percent by volume of VON as

applied for the outside of tires.

Section 219.463

 Alternative Emission Reduction Systems

In lieu of complying with Section 219.461 or 219.462, the owner

or operator of an emission source may utilize an alternative

volatile organic emission reduction system,

 including an

alternative production process, which

 is demonstrated to be

equivalent to Section 219.461 or 219.462 on the basis of

emissions of volatile organic matter.

 A treadend cementing

operation shall be considered equivalent to Section 219.461 or

219.462

 for the purposes of this Section if the total volatile

organic emission from such operation is 10 grams

 or less per

tire.

Section 219.464

 Testing and Monitoring

a)

 Upon

 a reasonable request by the Agency,

 the owner

or

operator of

 a VON emission source required to comply

with a limit of Sections 219.461 through 219.464 shall

conduct emissions testing,

 at such person’s own

expense, to demonstrate compliance.

b)

 A person planning to conduct a VOM emission test to

demonstrate compliance shall notify the Agency of that

intent not less than 30 days before the planned

initiation of the tests so the Agency may observe the

test.

Section 218.465

 Compliance Dates

Every owner or operator of an emission source subject to 35

 Ill.

Adm.

 Code 215,

 Subpart

 S, as of December

31,

 1987 shall have

complied with its standards and limitations by December 31,

 1987.

119—586

125

Section 219.466

 Compliance Plan

a)

 The owner or operator

 of an emission source shall have

submitted to the Agency

 a compliance plan,

 pursuant to

35

 Iii. Adm. Code 201, Subpart

H,

 including a project

completion schedule where applicable,

 no later than

April 21,

 1983.

b)

 Unless the submitted compliance plan or schedule was

disapproved by the Agency, the owner or operator of

a

facility or emission source may operate the emission

source according to the plan and schedule as submitted.

c)

 The plan and schedule shall meet the requirements of

35

Ill. Adm. Code 201, Subpart H,

 including specific

interim dates as required in

35

 Ill. Adm.

 Code 201.242.

SUBPART T:

 PHARMACEUTICAL MANUFACTURING

Section 219.480

 Applicability

a)

 The rules of this Subpart, except for Sections 219.483

through 219.485, apply to all emission sources of

VOM,

including but not limited to reactors, distillation

 units,

 dryers,

 storage tanks for VOL, equipment for the

transfer of VOL,

 filters, crystallizers, washers,

laboratory hoods, pharmaceutical coating operations,

mixing operations and centrifuges used in

manufacturing, including packaging,

 of pharmaceuticals,

and emitting more than 6.8 kg/day

 (15 lbs/day)

 and more

than 2,268 kg/year

 (2.5 tons/year)

 of VON.

 If an

emission source emits less than 2,268 kg/year (2.5

tons/year)

 of VON, the requirements of this Subpart

still apply to the emission source if VON emissions

from the emission source exceed 45.4 kg/day

(100 lbs/day)

b)

 Notwithstanding subsection

 (a), the air suspension

coater/dryer, fluid bed dryers, tunnel dryers,

and

Accelacotas located

 in Libertyvilie Township,

 Lake

County,

 Illinois shall be exempt from the rules of this

Subpart,

 except for Sections 219.483 through 219.485,

if emissions of VON not vented to air pollution control

equipment do not exceed the following levels:

1)

 for the air suspension coater/dryer:

 2,268 kg/year

(2.5 tons/year);

2)

 for each fluid bed dryer:

 4,535 kg/year

(5.0 tons/year);

119—587

126

3)

 for each tunnel dryer:

 6,803 kg/year

 (7.5

tons/year); and

4)

 for each Accelacota:

 6,803 kg/year

(7.5 tons/year).

c)

 Sections 219.483 through 219.485 apply to a plant

having one or more emission sources that:

1)

 Are used to manufacture pharmaceuticals,

and

2)

 Emit more than 6.8 kg/day

 (15 lbs/day)

 of VON and

more than 2,268 kg/year

 (2.5 tons/year)

 of VON,

or,

 if less than 2,268 kg/year (2.5 tons/year),

these Sections still apply if emissions from one

or more sources exceed 45.4 kg/day

 (100 lbs/day).

ci)

 No owner or operator shall violate any condition in

a

permit when the condition results in exclusion of an

emission source from this Subpart.

e)

 Any pharmaceutical manufacturing source that becomes

subject to the provisions of this Subpart at any time

shall remain subject to the provisions of this Subpart

at all times.

f)

 Emissions subject to this Subpart shall be controlled

at all times consistent with the requirements set forth

in this Subpart.

g)

 Any control device required pursuant to this Subpart

shall be operated at all times when the source

 it is

controlling is operated.

h)

 Determinations of daily and annual emissions for

purposes of this Section shall be made using both data

on the hourly emission rate

 (or the emissions per unit

 of throughput)

 and appropriate daily and annual data

from records of emission source operation

 (or material

throughput or material consumption data).

 In the

absence of representative test data pursuant to Section

219.487 for the hourly emission rate

 (or the emissions

per unit of throughput), such items shall be calculated

using engineering calculations,

 including the methods

described in Appendix B of “Control of Volatile Organic

Emissions from Manufacturing of Synthesized

Pharmaceutical Products”

 (EPA—450/2—78—029),

incorporated by reference in Section 219.112.

 (This

subsection shall not affect the Agency’s or the USEPA’s

authority to require emission tests to be performed

pursuant to Section 219.487.)

119—588

127

Section 219.481

 Control of Reactors,

 Distillation Units,

Crystallizers, Centrifuges and Vacuum Dryers

a)

 The owner or operator shall equip all reactors,

distillation units,

 crystallizers, centrifuges and

vacuum dryers that are used to manufacture

pharmaceuticals with surface condensers or other air

pollution control equipment listed in subsection

 (b).

If a surface condenser is used,

 it shall be operated

such that the condenser outlet gas temperature does not

exceed:

1)

 248..2oK (-13°F)when condensing VON of vapor

 pressure greater than 40.0 kPa (5.8 psi)

at

294.3oK (70°F),

or

2)

 258.2°K(5°F)when condensing VON of vapor

pressure greater than 20.0 kPa (2.9 psi)

at

 294.3°K(70°F),or

3)

 273.2°K (32 oF) when condensing VON of vapor

pressure greater than 10.0 kPa (1.5 psi)

at

294.3oK

 (70°F),

or

4)

 283.2oK

 (50°F)

when condensing VON of vapor

pressure greater than 7.0 kPa

 (1.0 psi)

at

294.3oK

(70°F)

or

5)

 298.2oK

 (77°F)

when condensing VON of vapor

pressure greater than 3.45 kPa (0.5 psi)

at

294.3oK

 (70°F).

b)

If

 a scrubber, carbon adsorber,

 thermal afterburner,

catalytic afterburner,

 or other air pollution control

equipment other than a surface condenser is used,

 such

equipment shall provide a reduction in the emissions of

VON of 90 percent or more.

c)

 The owner or operator shall enclose all centrifuges

used to manufacture pharmaceuticals and that have an

exposed VOL surface, where the VON in the VOL has a

vapor pressure of 3.45 kPa (0.5 psi)

 or more at

294.3oK

(70°F),

except as production,

 sampling, maintenance, or

inspection procedures require operator access.

Section 219.482

 Control of Air Dryers, Production Equipment

Exhaust Systems and Filters

a)

 The owner or operator of an air dryer or production

equipment exhaust system used to manufacture

pharmaceuticals shall control the emissions of VON from

such emission sources by air pollution control

119—589

128

equipment which reduces by 90 percent or more the VON

that would otherwise be emitted into the atmosphere.

b)

 The owner or operator shall enclose all rotary vacuum

filters and other filters used to manufacture

pharmaceuticals and that have an exposed

VOL

surface,

where the VOM in the VOL has a vapor pressure of 3.45

kPa

(0.5

psi)

 or more at

294oK

 (70°F),

except as

production,

 sampling, maintenance,

 or inspection

procedures require operator access.

Section 219.483

 Material Storage and Transfer

The owner or operator of a pharmaceutical manufacturing plant

shall:

a)

 Provide a vapor balance system that is at least

90 percent effective in reducing VON emissions from

truck or railcar deliveries to storage tanks with

capacities equal to or greater than 7.57 m3

 (2,000

 gal)

that store

VOL

with vapor pressures greater than

28.0

kPa

 (4.1 psi)

at

294.3oK

 (70°F),

and

b)

 Install, operate, and maintain pressure/vacuum

conservation vents set at 0.2 kPa

 (0.03 psi)

 or greater

on all storage tanks that store VOL with vapor

pressures greater than 10 kPa

 (1.5 psi)

at

294.3oK

(70°F)

Section 219.484

 In—Process Tanks

The owner or operator shall install covers on all in—process

tanks used to manufacture pharmaceuticals and containing a VOL at

any time.

 These covers must remain closed, except as production,

sampling, maintenance or inspection procedures require operator

access.

Section

219.485

 Leaks

The owner or operator of a pharmaceutical manufacturing plant

shall repair any component from which a leak of VOL can be

observed.

 The repair shall be completed as soon as practicable

but no later

than

15

days after the leak is found.

If

the

leaking component cannot be repaired until the process unit is

shut down,

 the leaking component must then be repaired before the

unit

 is restarted.

Section 219.486

 Other Emission Sources

The owner or operator of a washer, laboratory hood,

 tablet

coating operation, mixing operation or any other process emission

119—590

129

source not subject to Sections 219.481 through 219.485,

 and used

to manufacture pharmaceuticals shall control the emissions of VON

from such emission sources by:

a)

 Air pollution control equipment which reduces by

81 percent or more the VOM that would otherwise be

emitted to the atmosphere,

or

b)

 A surface condenser which captures all the VON which

would otherwise be emitted to the atmosphere and which

meets the requirements of Section 219.481(a)

and

 (b).

Section 219.487

 Testing

a)

 Upon request by the Agency or the USEPA, the owner or

operator of any VON emission source subject to this

Subpart or exempt from this Subpart by virtue of the

provisions of Section 219.480 shall,

 at his own

expense, demonstrate compliance to the Agency and the

USEPA by the methods or procedures listed in Section

219.105(f) (1).

b)

 A person planning to conduct a VON emissions test

to

demonstrate compliance with this Subpart shall notify

the Agency and the USEPA of that intent not less than

30 calendar days before the planned initiation of

the

test.

Section 219.488

 Monitoring for Air Pollution Control

Equipment

a)

 At a minimum,

 continuous monitors for the following

parameters shall be installed on air pollution control

equipment used to control sources subject to this

Subpart:

1)

 Destruction device combustion temperature.

2)

 Temperature rise across a catalytic afterburner

bed.

3)

 VON concentration on a carbon adsorption unit to

determine breakthrough.

4)

 Outlet gas temperature of a refrigerated

condenser.

5)

 Temperature of a non—refrigerated condenser

coolant supply system.

b)

 Each monitor shall be equipped with a recording device.

119—591

130

c)

 Each monitor shall be calibrated quarterly.

d)

 Each monitor shall operate at all times while the

associated control equipment is operating.

Section 219.489

 Recordkeeping for Air Pollution Control

Equipment

a)

 The owner or operator of

 a pharmaceutical manufacturing

facility shall maintain the following records:

1)

 Parameters listed in Section 219.488(a) (1)

 shall

be recorded.

2)

 For sources subject to Section 219.481,

 the vapor

pressure of VON being controlled shall be recorded

for every process.

b)

 For any leak subject to Section 219.485 which cannot be

readily repaired within one hour after detection,

the

following records shall be kept:

1)

 The name of the leaking equipment,

2)

 The date and time the leak is detected,

3)

 The action taken to repair the leak,

and

4)

 The data and time the leak is repaired.

c)

 The following records shall be kept for emission

sources subject to Section 219.484 which contain VOL:

1)

 For maintenance and inspection:

A)

 The date and time each cover

 is opened,

B)

 The length of time the cover remains open,

and

C)

 The reason why the cover is opened.

2)

 For production and sampling, detailed written

procedures or manufacturing directions specifying

the circumstances under which covers may be opened

and the procedures for opening covers.

ci)

 For each emission source used in the manufacture of

pharmaceuticals for which the owner or operator of a

pharmaceutical manufacturing plant claims emission

standards are not applicable,

 because the emissions are

below the applicability cutoffs in Section 219.480(a)

119—592

131

or 219.480(b),

 the owner or operator shall:

1)

 Maintain a demonstration including detailed

 engineering calculations of the maximum daily and

annual emissions for each such emission source

showing that the emissions are below the

applicability cutoffs in Section 219.480(a)

or

219.480(b),

 as appropriate,

 for the current and

prior calendar years;

2)

 Maintain appropriate operating records for each

such emission source to identify whether the

applicability cutoffs in Section 219.480(a)

or

219.480(b),

 as appropriate, are ever exceeded; and

3)

 Provide written notification to the Agency and the

USEPA

within 30 days of a determination that such

an emission source has exceeded the applicability

cutoffs in Section 219.480(a)

 or 219.480(b),

as

appropriate.

e)

 Records required under subsection

(a)

 shall be

maintained by the owner or operator for a minimum of

two years after the date on which they are made.

f)

 Copies of the records shall be made available to the

Agency or the USEPA upon verbal or written-request.

SUBPART V:

 AIR OXIDATION PROCESSES

Section 219.521

 Definitions

In addition to the definitions of 35 Ill. Adm.

 Code 211, the

following definitions apply to this Subpart:

“Air Oxidation Process”:

 any unit process including

ammoxidation and oxychlorination which uses air or a

combination of air and oxygen as an oxidant in

 combination with one or more organic reactants to

produce one or more organic compounds.

“Cost Effectiveness”:

 the annual expense for cost of

control of

 a given process stream divided by the

reduction in emissions of organic material of that

stream.

“Flow

 (F)”:

 Vent stream flowrate (scm/mm)

 at a

standard temperature of 2OoC.

“Full Operating Flowrate”:

 Maximum operating capacity

of the facility.

119—593

132

“Hourly Emissions

 (E)”:

 Hourly emissions reported in

kg/hr measured at full operating flowrate.

“Net Heating Value

 (H)”:

 Vent stream net heating value

(MJ/scm), where the net enthalpy per mole of offgas

is

based on combustion at 25°Cand 760 mm Hg, but the

standard temperature for determining the volume

corresponding to one mole is 20°C,as in the definition

of “Flow.”

“Process Vent Stream”:

 An emission stream resulting

from an air oxidation process.

“Total Resource Effectiveness Index

 (TRE)”:

 Cost

effectiveness in dollars per megagram of controlling

any gaseous stream vented to the atmosphere from an air

oxidation process divided by $1600/Mg, using the

criteria and methods set forth in this Subpart and

Appendices C and D.

Section 219.525

 Emission Limitations for Air Oxidation

 Processes

a)

 No person shall cause or allow the emission of volatile

organic material

 (VOM)

 from any process vent stream

unless the process vent stream is vented to a

combustion device which is designed and operated

either:

1)

 To reduce the volatile organic emissions vented

to

it with an efficiency of at least ninety eight

percent

 (98)

 by weight; or

2)

 To emit VOM at a concentration less than twenty

parts per million by volume, dry basis.

b)

 Air oxidation facilities for which an existing

combustion device

 is employed to control process VON

emissions are not required to meet the 98 percent

emissions limit until the combustion device is replaced

for other reasons, which shall be considered to

include, but not be limited to, normal maintenance,

malfunction, accident, and obsolescence.

The

combustion device is considered to be replaced when:

1)

 All of the device is replaced; or

2)

 When the cost of the repair of the device or the

cost of replacement of part of the device exceeds

50

 of the cost of replacing the entire device

with a device which complies.

L19—594

133

c)

 The limitations of subsection

 (a) do not apply to any

 process vent stream or combination of process vent

streams which has

 a Total Resource Effectiveness Index

(TRE)

 greater than 1.0,

 as determined by the following

methods:

1)

 If an air oxidation process has more than one

process vent stream, TRE shall be based upon a

combination of the process vent streams.

2)

 TRE of a process vent stream shall be determined

according to the following equation:

TRE

E~ a

+

bF” + cF

+

dFH

+

 e(FH)’1

+

fF0~5

where:

n

 0.88

TRE

 Total resource effectiveness index.

F

 Vent stream flowrate (scm/mm),

 at a

standard temperature of 20°C.

E

 Hourly measured emissions in kg/hr.

H

 Net heating value of vent stream

(NJ/scm), where the net enthaipy per

mole of offgas

 is based on combustion at

25°Cand 760 mm Hg, but the standard

temperature for determining the volume

corresponding to one mole is 20°C,as in

the definition of “Flow”.

a,b,c,d,

e and £

 Coefficients obtained by use of Appendix

F.

3)

 For nonchlorinated process vent streams,

 if the

net heating value,

H,

 is greater than 3.6 NJ/scm,

F shall be replaced by F1 for purposes of

calculating TRE.

 F1 is computed as follows:

F1

FH

/

3.6

where F and H are as defined in subsection

 (c) (2).

4)

 The actual numerical values used in the equation

described in subsection

 (c) (2)

 shall

 be determined

as follows:

119—595

134

A)

 All reference methods and procedures for

determining the flow,

 (F), hourly emissions,

(E), and net heating,

 (H), value shall be

in

accordance with Appendix C.

B)

 All coefficients described in subsection

(c) (2)

 shall be in accordance with Appendix

D.

Section 219.526

 Testing and Monitoring

a)

 Upon reasonable request by the Agency, the owner or

operator of an air oxidation process shall demonstrate

compliance with this Subpart by use of the methods

specified in Appendix C.

 This Section does not limit

the USEPA’s authority, under the Clean Air Act,

to

require demonstrations of compliance.

b)

 A person planning to conduct a VOM emissions test to

demonstrate compliance with this Subpart shall notify

the Agency of that intent not less than 30 days before

the planned initiation of the tests so that the Agency

may observe the test.

Section 219.527

 Compliance Date

Each owner or operator of an emission source subject to

 35 Ill.

Adm. Code 215, Subpart V,

 as of December

 31,’ 1987 shall have

complied with the standards and limitations of 35 Ill. Adm. Code

215,

 Subpart V, by December 31,

 1987.

SUBPART W:

 AGRICULTURE

Section 219.541

 Pesticide Exception

The provisions of Sections 219.301 and 219.302 shall not apply

to

the spraying or use of insecticides, herbicides or other

pesticides.

SUBPART

X:

 CONSTRUCTION

Section 219.561

 Architectural Coatings

No person shall cause or allow the sale or use of any

architectural coating containing more than 20

percent by volume

of photo-chemically reactive material in containers having

a

capacity of more than one gallon.

Section 219.562

 Paving Operations

The provisions of Sections 219.301 and 219.302 shall not apply to

the application of paving asphalt and pavement marking paint from

119—596

135

sunrise to sunset.

Section 219.563

 Cutback Asphalt

a)

 No person shall cause or allow the use or application

of cutback asphalt for paving, resurfacing,

reconditioning,

 repairing or otherwise maintaining a

roadway unless:

1)

 The use or application of the cutback asphalt

commences on or after October

 1 of any year and

such use or application is completed by April

30

of the following year;

or

2)

 The cutback asphalt is

 a long-life stockpile

material which remains in stock after April 30 of

each year and as such

 it may be used until

depleted for patching potholes and for other

similar repair work;

or

3)

 The cutback asphalt is to be used solely as an

asphalt prime coat.

b)

 Sources subject to this Section are not required to

submit or obtain an Agency approved compliance plan or

project completion schedule under

35

 Ill. Adm. Code

201, Subpart H.

SUBPART

Y:

 GASOLINE DISTRIBUTION

Section 219.581

 Bulk Gasoline Plants

a)

 Subject to Subsection

 (e), no person may cause or allow

the transfer of gasoline from a delivery vessel into a

stationary storage tank located at a bulk gasoline

plant unless:

1)

 The delivery vessel and the stationary storage

tank are each equipped with a vapor collection

system that meets the requirements of subsection

(ci) (4)

2)

 Each vapor collection system is operating,

3)

 The delivery vessel displays the appropriate

sticker pursuant to the requirements of Sections

219.584

(b)

or

 (d),

4)

 The pressure relief valve(s) on the stationary

storage tank and the delivery vessel are set to

release at no less than 0.7 psi or the highest

pressure allowed by state or local fire codes or

119—597

136

the guidelines of the National Fire Prevention

Association,

and

5)

 The stationary storage tank is equipped with a

submerged loading pipe.

b)

 Subject to subsection

 (f),

 no person may cause or allow

the transfer of gasoline from a stationary storage tank

located at a bulk gasoline plant into a delivery vessel

unless:

1)

 The requirements set forth in subsections

(a)

(1)

through

 (a) (4) are met, and

2)

 Equipment is available at the bulk gasoline plant

to provide for the submerged filling of the

delivery vessel or the delivery vessel

 is equipped

for bottom loading.

c)

 Subject to subsection

 (e), each owner of a stationary

storage tank located at a bulk gasoline plant shall:

1)

 Equip each stationary storage tank with a vapor

control system that meets the requirements of

subsection

(a)

or

 (b), whichever is applicable,

2)

 Provide instructions to the operator of the bulk

gasoline plant describing necessary maintenance

operations and procedures for prompt notification

of the owner in case of any malfunction of a vapor

control system, and

3)

 Repair, replace or modify any worn out or

malfunctioning component or element of design.

d)

 Subject to subsection

 (e),

 each operator of a bulk

gasoline plant shall:

1)

 Maintain and operate each vapor control system in

accordance with the owner’s instructions,

2)

 Promptly notify the owner of any scheduled

maintenance or malfunction requiring replacement

or repair of a major component of a vapor control

system, and

3)

 Maintain gauges, meters or other specified testing

 devices in proper working order,

4)

 Operate the bulk plant vapor collection system and

gasoline loading equipment in a manner that

prevents:

119=598

137

A)

 Gauge pressure from exceeding 45.7 cm

(18

in.)

 of water and vacuum from exceeding 15.2

cm

 (6 in.)

 of water,

 as measured as close as

possible to the vapor hose connection,

and

B)

 A reading equal to or greater than 100

 percent of the lower explosive limit

 (LEL

measured as propane) when tested in

accordance with the procedure described in

“Control of Volatile Organic Compound Leaks

from Gasoline Tank Trucks and Vapor

Collection Systems”, Appendix B,

EPA 450/2-78-051,

 (incorporated by reference

in Section 219.112), and

C)

 Avoidable leaks of liquid during loading or

unloading operations.

5)

 Provide a pressure tap or equivalent on the bulk

plant vapor collection system in order to allow

the determination of compliance with subsection

(ci) (4) (A)

and

6)

 Within

 15 business days after discovery of any

leak by the owner,

 the operator, the Agency or the

USEPA, repair and retest a vapor collection system

which exceeds the limits of subsection

(d)

(4) (A)

or

 (B).

e)

 The requirements of subsections

 (a),

 (c) and

(d)

 shall

not apply to:

1)

 Any stationary storage tank with

 a capacity of

less than 2,177

1

 (575 gal),

or

2)

 Any bulk gasoline plant whose daily gasoline

throughput is less than 15,140

1

 (4,000 gal/day)

on a thirty-day rolling average.

f)

 The requirements of subsection

(b)

 shall apply only to

 bulk gasoline plants whose daily gasoline throughput

is

greater than or equal

 t,o 15,140

1

 (4,000 gal/day)

on

a

thirty-day rolling average.

g)

 Any bulk gasoline plant which

 is ever subject to

subsections

 (a),

 (b),

 (c),

or

 (ci)

 shall always be

subject to these paragraphs.

Section 219.582

 Bulk Gasoline Terminals

a)

 No person shall cause or allow the transfer of gasoline

119—599

138

into any delivery vessel from any bulk gasoline

terminal unless:

1)

 The bulk gasoline terminal is equipped with a

vapor control system that limits emission of

VOM

to 80 mg/1 (0.00067 lbs/gal)

 of gasoline loaded;

2)

 The vapor control system

 is operating and all

vapors displaced in the loading of gasoline to the

delivery vessel are vented only to the vapor

control system;

3)

 There

 is no liquid drainage from the loading

device when it is not in use;

4)

 All loading and vapor return lines are equipped

with fittings which are vapor tight; and

5)

 The delivery vessel displays the appropriate

sticker pursuant to the requirements of Section

219.584(b)

or

 (d); or,

 if the terminal

is

driver—loaded, the terminal owner or operator

shall be deemed to be in compliance with this

Section when terminal access authorization is

limited to those owners and/or operators of

delivery vessels who have provided a current-

certification as required by Section

219.584(c) (3).

b)

 Bulk gasoline terminals were required to take certain

actions to achieve compliance which are summarized

in

35

 Ill.

 Adm.

 Code 215, Appendix

C.

c)

 The operator of a bulk gasoline terminal shall:

1)

 Operate the terminal vapor collection system and

gasoline loading equipment in a manner that

prevents:

A)

 Gauge pressure from exceeding 18

 inches of

water and vacuum from exceeding

 6 inches of

water as measured as close as possible to the

vapor hose connection; and

B)

 A reading equal to or greater than 100

percent of the lower explosive limit

 (LEL

measured as propane) when tested in

accordance with the procedure described in

EPA 450/2-78-051

Appendix B incorporated by

reference in Section 219.112; and

C)

 Avoidable leaks of liquid during loading or

119—600

139

unloading operations.

2)

 Provide a pressure tap or equivalent on the

 terminal vapor collection system in order to allow

the determination of compliance with Section

219.582(d) (1) (A); and

3)

 Within

 15 business days after discovery of the

leak by the owner,

 operator,

 or the Agency repair

and retest a vapor collection system which exceeds

the limits of subsection

 (c) (1) (A)

or

 (B).

Section 219.583

 Gasoline Dispensing Facilities

a)

 Subject to subsection

 (b),

 no person shall cause or

allow the transfer of gasoline from any delivery vessel

into any stationary storage tank at

 a gasoline

dispensing facility unless:

1)

 The tank is equipped with a submerged loading

pipe;

and

2)

 The vapors displaced from the storage tank during

filling are processed by a vapor control system

that includes one or more of the following:

A)

 A vapor collection system that meets the

requirements of subsection

 (ci) (4);

or

5)

 A refrigeration—condensation system or any

other system approved by the Agency and

approved by the USEPA as a SIP revision,

 that

recovers at least

 90 percent by weight of all

vaporized organic material from the equipment

being controlled; and

C)

 The delivery vessel displays the appropriate

sticker pursuant to the requirements of

Section 219.584(b)

or

 (d).

b)

 The requirements of subsection

 (a) (2)

 shall not apply

to transfers of gasoline to a stationary storage tank

at a gasoline dispensing facility if:

1)

 The tank is equipped with a floating roof,

or

other system of equal or better emission control

as approved by the Agency and approved by the

USEPA as a SIP revision;

2)

 The tank has a capacity of less than 2000 gallons

and was in place and operating before January

1,

1979; or

119—601

140

3)

 The tank has a capacity of less than 575 gallons.

c)

 Subject to subsection

 (b), each owner of a gasoline

dispensing facility shall:

1)

 Install all control systems and make all process

modifications required by subsection

 (a);

2)

 Provide instructions to the operator of the

gasoline dispensing facility describing necessary

maintenance operations and procedures for prompt

notification of the owner in case of any

malfunction of a vapor control system; and

3)

 Repair,

 replace or modify any worn out or

malfunctioning component or element of design.

ci)

 Subject to subsection

 (b), each operator of a gasoline

dispensing facility shall:

1)

 Maintain and operate each vapor control system in

 accordance with the owner-’s instructions;

2)

 Promptly notify the owner of any scheduled

maintenance or malfunction requiring replacement

or repair of a major component of a vapor control

system;

3)

 Maintain gauges, meters or other specified testing

devices

 in proper working order;

4)

 Operate the vapor collection system and delivery

vessel unloading points in a manner that prevents:

A)

 A reading equal to or greater than 100

percent of the lower explosive limit

 (LEL

measured as propane) when tested in

accordance with the procedure described in

EPA 450/2-78-051 Appendix B, and

B)

 Avoidable leaks of liquid during the filling

of storage tanks; and

5)

 Within 15 business days after discovery of the

leak by the owner,

 operator,

 or the Agency,

 repair

and retest a vapor collection system which exceeds

the limits of subsection

 (d) (4) (A).

e)

 Gasoline dispensing facilities were required to take

certain actions to achieve compliance which are

summarized in 35

 Iii.

 Adm. Code 215, Appendix

C.

119—602

141

Section 219.584

 Gasoline Delivery Vessels

a)

 Any delivery vessel equipped for vapor control by use

of vapor collection equipment:

1)

 Shall have a vapor space connection that is

equipped with fittings which are vapor tight;

2)

 Shall have its hatches closed at all times during

loading or unloading operations, unless a top

loading vapor recovery system is used;

3)

 Shall not internally exceed a gauge pressure of

18

inches of water or a vacuum of

 6 inches of water;

4)

 Shall be designed and maintained to be vapor tight

at all times during normal operations;

5)

 Shall not be refilled in Illinois at other than:

A)

 A bulk gasoline terminal that complies with

the requirements of Section 219.582

or

B)

 A bulk gasoline plant that complies with the

requirements of Section 219.581(b).

6)

 Shall be tested annually in accordance with Method

27,

 40 CFR 60, Appendix A,

 incorporated by

reference in Section 219.105.

 Each vessel must be

repaired and retested within 15 business days

after discovery of the leak by the owner,

operator,

 or the Agency, when it fails to sustain:

A)

 A pressure drop of no more than three inches

of water in five minutes; and

B)

 A vacuum drop of no more than three inches of

water in five minutes.

b)

 Any delivery vessel meeting the requirements of

subsection

(a)

 shall have a sticker affixed to the tank

adjacent to the tank manufacturer’s data plate which

contains the tester’s name,

 the tank identification

number and the date of the test.

 The sticker shall be

in a form prescribed by the Agency,

 and,

 for those

delivery vessels subject to 35

 Ill. Adm. Code 215 as

of

December 31,

 1987 shall have been displayed no later

than December 31,

 1987.

c)

 The owner or operator of a delivery vessel shall:

119—603

142

1)

 Maintain copies of any test required under

 subsection

 (a) (6)

 for a period of

 3 years;

2)

 Provide copies of these tests to the Agency upon

request; and

3)

 Provide annual test result certification to bulk

gasoline plants and terminals where the delivery

vessel

 is loaded.

d)

 Any delivery vessel which has undergone and passed a

test in another state which has a USEPA-approved leak

testing and certification program will satisfy the

requirements of subsection

 (a).

 Delivery vessels must

display a sticker, decal or stencil approved by the

state where tested or comply with the requirements

of

subsection

 (b).

 All such stickers, decals or stencils

shall have been displayed no later than December

31,

1987,

 for delivery vessels subject to 35

 Ill.

 Adm. Code

215 as of December 31,

 1987.

Section 219.585

 Gasoline Volatility Standards

a)

 No person shall sell, offer for sale,

 dispense, supply,

offer for supply, or transport for use in Illinois

gasoline whose Reid vapor pressure exceeds the

applicable limitations set forth

 in subsections

(b)

and

(c) during the regulatory control periods,

 which shall

be July

 1 to August 31 for retail outlets, wholesale

purchaser-consumer facilities,

 and all other

facilities.

b)

 The Reid vapor pressure of gasoline,

 a measure

 of its

volatility,

 shall not exceed 9.5 psi

 (65.5 kPa) during

the regulatory control period in 1990 and each year

thereafter.

c)

 The Reid vapor pressure of ethanol blend gasolines

shall not exceed the limitations for gasoline set forth

in subsection

 (b) by more than 1.0 psi

 (6.9 kPa).

Notwithstanding this limitation, blenders of ethanol

blend gasolines whose Reid vapor pressure is less than

1.0 psi above the base stock gasoline immediately after

blending with ethanol are prohibited from adding butane

or any product that will increase the Reid vapor

pressure of the blended gasoline.

ci)

 All sampling of gasoline required pursuant to the

provisions of this Section shall be conducted by one or

more of the following approved methods or procedures

which are incorporated by reference in Section 215.105.

119—604

143

1)

 For manual sampling, ASTN D4057;

2)

 For automatic sampling, ASTM D4l77;

3)

 Sampling procedures for Fuel Volatility,

 40 CFR 80

Appendix D.

e)

 The Reid vapor pressure of gasoline shall be measured

in accordance with either test method ASTN D323 or a

modification of ASTN D323 known as the “dry method” as

set forth

 in 40 CFR 80, Appendix E, incorporated by

reference in 35 Ill. Adm. Code 215.105.

 For gasoline

oxygenate blends which contain water-extractable

oxygenates,

 the Reid vapor pressure shall be measured

using the dry method test.

f)

 The ethanol content of ethanol blend gasolines shall

be

determined by use of one of the approved testing

methodologies specified in 40 CFR 80, Appendix F,

incorporated by reference in 35 Ill.

 Adm.

 Code 215.105.

g)

 Any alternate to the sampling or testing methods or

procedures contained

 in subsections

 (ci),

 (e), and

(f)

must be approved by the Agency, which shall consider

data comparing the performance of the proposed

alternative to the performance of one or more approved

test methods or procedures.

 Such data shall accompany

any request for Agency approval of any alternate test

procedure.

 If the Agency determines that such data

demonstrates that the proposed a~~ernative

 will achieve

results equivalent to the approved test methods or will

achieve results equivalent to the approved test methods

or procedures,

 the Agency shall approve the proposed

alternative.

h)

 Each refiner or supplier that distributes gasoline or

ethanol blends shall:

1)

 During the regulatory control period,

 state that

the Reid vapor pressure of all gasoline or ethanol

blends leaving the refinery or distribution

facility for use in Illinois complies with the

Reid vapor pressure limitations set forth in 35

Ill.

 Adm. Code 215.585(b)

and

 (c).

 Any facility

receiving this gasoline shall be provided with a

copy of an invoice, bill of lading, or other

documentation used in normal business practice

stating that the Reid vapor pressure of the

gasoline complies with the State Reid vapor

pressure standard.

2)

 Maintain records for a period of one year on the

119—605

144

Reid vapor pressure, quantity shipped and date of

delivery of any gasoline or ethanol blends leaving

the refinery or distribution facility for use

in

 Illinois.

 The Agency shall be provided with

copies of such records

 if requested.

SUBPART

Z:

 DRY CLEANERS

Section 219.601

 Perchioroethylene Dry Cleaners

The owner or operator of a dry cleaning facility which uses

perchloroethylene shall:

a)

 Vent the entire dryer exhaust through a properly

designed and functioning carbon adsorption system or

equally effective control device; and

b)

 Emit no more than 100 ppmv of VON from the dryer

control device before dilution,

 or achieve a 90 percent

average reduction before dilution; and

c)

 Immediately repair all components found to be leaking

liquid VON; and

ci)

 Cook or treat all diatomaceous earth filters so that

the residue contains 25 kg

(55

ib)

 or’ less of volatile

organic material per 100 kg

 (220

lb)

 of wet waste

material; and

e)

 Reduce the vVOM from all solvent stills to

 60 kg

 (132

lb)

 or less per 100 kg

 (220 ib)

 of wet waste material;

and

f)

 Drain all filtration cartridges

 in the filter housing

or other sealed container for at least 24 hours before

discarding the cartridges;

and

g)

 Dry all drained filtration cartridges

 in equipment

connected to an emission reduction system or in a

manner that will eliminate emission of volatile organic

material to the atmosphere.

Section 219.602

 Exemptions

The provisions of Section 219.601

are not applicable to

perchloroethylene dry cleaning operations which are coin—operated

or to dry cleaning facilities consuming less than 30 gal per

month

 (360 gal per year)

 of perchloroethylene.

Section 219.603

 Leaks

The presence of leaks shall be determined

 for purposes of Section

119—606

145

219.601(c)

 by a visual inspection of the following: hose

connections, unions, couplings and valves; machine door gaskets

and seatings; filter head gasket and seating;

 pumps; base tanks

and storage containers; water separators; filter sludge recovery;

distillation unit; diverter valves; saturated lint from lint

baskets; and cartridge filters.

Section 219.604

 Compliance Dates

Every owner or operator of an emission source previously subject

to 35

 Ill.

 Adm. Code 215, Subpart

 Z shall have complied with its

standards and limitations in accordance with the applicable dates

set forth in 35 Ill.

 Adm. Code 215.604.

Section 219.605

 Compliance Plan

a)

 The owner or operator of an emission source subject to

this Subpart shall have submitted to the Agency a

compliance plan, pursuant to 35 Ill. Adm. Code 201,

Subpart H,

 including a project completion schedule

where applicable,

 no later than,

 for Section 219.601(a)

and

 (b), April 21,

 1983.

b)

 Unless the submitted compliance plan or schedule was

disapproved by the Agency, the owner or operator of

a

facility or emission source may operate the emission

source according to the plan and schedule as submitted.

c)

 The plan and schedule shall meet the requirements of 35

Ill.

 Adm. Code 201, Subpart

 H, including specific

interim dates as required in 35 Ill. Adm. Code 201.242.

Section 219.606

 Exception to Compliance Plan

Coin-operated dry cleaning operations and dry cleaning facilities

consuming less than 30 gal per month (360 gal per year)

of

perchloroethyiene are not required to submit or obtain an Agency

approved compliance plan or project completion schedule.

Section 219.607

 Standards for Petroleum Solvent Dry Cleaners

a)

 The owner or operator of a petroleum solvent dry

cleaning dryer shall either:

1)

 Limit emissions of volatile organic material to

the atmosphere to an average of 3.5 kilograms of

VON per 100 kilograms dry weight of articles dry

cleaned,

or

2)

 Install and operate a solvent recovery dryer in a

manner such that the dryer remains closed and the

recovery phase

 continues until a final solvent

119—607

146

flow rate of 50 ml per minute

 is attained.

b)

 The owner or

operator of a petroleum solvent filtration

system shall either:

1)

 Reduce the VON content in all filtration wastes to

1.0 kilogram or less per 100 kg dry weight of

articles dry cleaned,

 before disposal, and

exposure to the atmosphere,

or

2)

 Install and operate a cartridge filtration system,

and drain the filter cartridges in their sealed

housings for

 8 hours or more before their removal.

Section 219.608

 Operating Practices for Petroleum Solvent Dry

Cleaners

In order to minimize fugitive solvent emissions,

 the owner or

operator of

 a petroleum solvent dry cleaning facility shall

employ good housekeeping practices including the following:

a)

 General Housekeeping Requirements

1)

 Equipment containing solvent (washers, dryers,

extractors and filters)

 shall remain closed at

all

times except during load transfer and maintenance.

Lint filter and button trap covers shall remain

closed except when solvent—laden material

 is being

removed.

2)

 Cans, buckets, barrels and other containers of

solvent or of solvent—laden material shall be

covered except when in use.

3)

 Solvent-laden material shall be exposed to the

 atmosphere only for the minimum time necessary for

load transfer.

b)

 Installation and operation of equipment:

1)

 All cartridge filters shall be enclosed and

operated in accordance with the procedures and

specifications recommended by the manufacturer for

the cartridge filter.

 After installation, the

cartridges shall be inspected, monitored and

maintained in accordance with the manufacturer’s

recommendations; and

2)

 Vents on containers for new solvent and for

solvent—containing waste shall be constructed and

maintained so as to minimize solvent vapor

emissions.

 Criteria for the minimization of

119—608

147

solvent vapor emissions include the elimination

of

solvent buckets and barrels standing open to the

atmosphere,

 and the repair of gaskets and seals

that expose solvent—rich environments to the

atmosphere,

 to be determined through visual

inspection.

Section 219.609

 Program for Inspection and Repair of

Leaks

a)

 The owner or operator of a petroleum solvent dry

cleaning facility shall conduct the following visual

inspections on a weekly basis:

1)

 Washers,

 dryers,

 solvent filters,

 settling tanks,

vacuum stills and containers and conveyors of

petroleum solvent shall be inspected for visible

leaks of solvent liquid.

2)

 Pipes, hoses and fittings shall be inspected for

active dripping or dampness.

3)

 Pumps and filters shall be inspected for leaks

around seals and access covers.

4)

 Gaskets and seals shall be inspected for wea,r and

defects.

b)

 Leaks of petroleum solvent liquid and vapors shall be

repaired within three working days of detection,

 unless

necessary replacement parts are not on site.

1)

 If necessary,

 repair parts shall be ordered within

three working days of detection of the leak.

2)

 The leak shall be repaired within three days of

delivery of necessary parts.

Section 219.610

 Testing and Monitoring

a)

 Compliance with Sections 219.607(b) (2)

 215.608 and

215.609 shall be determined by visual inspection; and

b)

 Compliance with Sections 219.607(a) (2)

and

(b)

(1) shall

be determined by methods described in EPA-450/3-82-009

(1982)

 incorporated by reference in Section 219.112.

c)

 If a control device is used to comply with Section

219.607(a) (1), then compliance shall be determined

using 40 CFR 60 Appendix A, Method 25

 (1984)

incorporated by reference in Section 219.112.

119—609

148

Section 219.611

 Exemption for Petroleum Solvent Dry Cleaners

The provisions of Sections 219.607 through 219.610 shall not

apply to petroleum solvent dry cleaning facilities whose

emissions of volatile organic material do not exceed 91 Mg

 (100

tons)

 per year in the absence of pollution control equipment or

whose emissions of VON,

 as limited by the operating permit,

will

not exceed 91 Mg (100 tons)

 per year in the absence of pollution

control equipment.

Section 219.612

 Compliance Dates

Owners and operators of emission sources subject to 35 Ill. Adm.

Code 215.607 through 215.609 as of December 31,

 1987 shall have

complied with the requirements set forth therein no later than

December

31,

 1987.

Section 219.613

 Compliance Plan

a)

 The owner or operator of an emission source formerly

subject to 35

 Ill. Adm.

 Code 215.610(a)

 as of Nay 31,

1987 shall have submitted to the Agency a compliance

plan,

 including a project completion schedule where

applicable,

 no later than May 31,

 1987.

b)

 The plan and schedule shall meet the requirements of

35

Ill. Adm. Code 201.

SUBPART AA:

 PAINT

AND

INK MANUFACTURING

Section 219.620

 Applicability

a)

 This subpart shall apply to all paint and ink

manufacturing plants which:

1)

 Include process emission sources not subject to

Subparts B,

E,

 F (excluding Section 219.204(1)),

H

excluding Section 219.405),

Q,

R,

5,

V,

X,

 Y or

Z

of this Part; and which as a group both:

A)

 have maximum theoretical emissions of 91 Mg

(100 tons)

 or more per calendar year of

VOM

if no air pollution control equipment were

used, and

B)

 are not limited to less than 91 Mg (100 tons)

of VON emissions per calendar year in the

absence of air pollution control equipment,

through production or capacity limitations

contained in a federally enforceable

construction permit or a SIP revision,

or

119—6 10

149

2)

 Produce more than 7,570,820

1

 (2,000,000 gal)

per

calendar year of paint or ink formulations, which

contain less than 10 percent (by weight) water,

and ink formulations not containing as the primary

solvents water, Magie oil or glycol.

b)

 For the purposes of this Subpart, uncontrolled VON

emissions are the emissions of VON which would result

if no air pollution control equipment were used.

Section 219.621

 Exemption for Waterbase Material and

Heatset-Offset Ink

The requirements of Sections 219.624 and 219.625 and Section

219.628(a)

 shall not apply to equipment while it is being used to

produce either:

a)

 paint or ink formulations which contain 10 percent or

more

 (by weight)

 water,

or

b)

 inks containing Magie oil and glycol as the primary

solvent.

Section 219.623

 Permit Conditions

No person shall violate any condition in a permit when the

condition results in exclusion of the plant or an emission -source

from this Subpart.

Section 219.624

 Open-top Mills, Tanks, Vats or Vessels

No person shall operate an open-top mill,

 tank, vat or vessel

with a volume of more than 45

1

 (12 gal) for the production of

paint or ink unless:

a)

 The mill,

 tank, vat or vessel is equipped with a cover

which completely covers the mill,

 tank, vat or vessel

opening except for an opening no larger than necessary

to allow for safe clearance for a mixer shaft.

 Such

cover shall extend at least 1.27 cm

 (0.5 in.) beyond

the outer rim of the opening or be attached to the rim.

b)

 The cover remains closed except when production,

sampling, maintenance or inspection procedures require

access.

c)

 The cover is maintained in good condition such that,

when in place,

 it maintains contact with the rim of the

opening for at least 90 percent of the circumference of

the rim.

Section 219.625

 Grinding Mills

119=6 11

150

a)

 No person shall operate a grinding mill for the

production of paint or ink which is not maintained in

accordance with the manufacturer’s specifications.

b)

 No person shall operate a grinding mill fabricated or

modified after the effective date of this Subpart which

is not equipped with fully enclosed screens.

c)

 The manufacturer’s specifications shall be kept on file

at the plant by the owner or operator of the grinding

mill and be made available to any person upon verbal or

written request during business hours.

Section 219.626

 Storage Tanks

a)

 The owner or operator shall equip tanks storing VOL

with a vapor pressure greater than 10 kPa

 (1.5 psi)

at

2OoC

 (68oF) with pressure/vacuum conservation vents set

as a minimum at +/-0.2 kPa

 (0.029 psi).

 These controls

shall be operated at all times.

 An alternative air

pollution control system may be used if

it

results

 in a

greater emission reduction than these controls.

Any

alternative control system can be allowed only

if

approved by the Agency and approved by the USEPA as

a

SIP

revision.

‘

b)

 Stationary VOL storage containers with a capacity

greater than 946

1

 (250 gal)

 shall be equipped with a

submerged-fill pipe or bottom fill.

 These controls

shall be operated at all times.

 An alternative control

system can be allowed only if approved by the Agency

and approved by the USEPA as a SIP revision.

Section 219.628

 Leaks

The owner or operator of a paint or ink manufacturing plant

shall,

 for the purpose of detecting leaks,

 conduct an equipment

monitoring program as set forth below:

a)

 Each pump shall be checked by visual inspection each

calendar week for indications of leaks, that is,

liquids dripping from the pump seal.

 If there are

indications of liquids dripping from the pump seal,

the

pump shall be repaired as soon as practicable, but no

later than 15 calendar days after the leak

 is detected.

b)

 Any pump,

 valve, pressure relief valve, sampling

connection,

 open—ended valve and flange or connector

containing a fluid which is at least

 10 percent VON by

weight which appears to be leaking on the basis of

sight,

 smell or sound shaii be repaired as soon as

119—6 12

151

practicable,

 but no later than 15 calendar days after

the leak is detected.

c)

 A weather proof, readily visible tag,

 in bright colors

such as red or yellow, bearing an identification number

and the date on which the leak was detected shall

be

attached to leaking equipment.

 The tag may be removed

upon repair, that is, when the equipment is adjusted or

otherwise altered to allow operation without leaking.

d)

 When a leak is detected, the owner or operator shall

record the date of detection and repair and the record

shall be retained at the plant for at least two years

from the date of each detection or each repair attempt.

The record shall

 be made available to any person upon

verbal or written request during business hours.

Section 219.630

 Clean Up

a)

 No person shall clean paint or ink manufacturing

equipment with organic solvent unless the equipment

being cleaned is completely covered or enclosed except

for an opening no larger than necessary to allow safe

clearance for proper operation of the cleaning

equipment,

 considering the method and materials being

used.

b)

 No person shall

 store organic wash solvent in other

than closed containers, unless closed containers are

demonstrated to be a safety hazard, or dispose of

organic wash solvent in a manner such that more than 20

percent by weight is allowed to evaporate into the

 atmosphere.

Section 219.636

 Compliance Schedule

Every owner or operator of an emission source subject-to the

control requirements of this Subpart shall comply with the

requirements thereof on and after a date consistent with Section

219. 106.

Section 219.637

 Recordkeeping and Reporting

a)

 Upon request by the Agency, the owner or operator of an

emission source which claims to be exempt from the

requirements of this Subpart shall submit records to

the Agency within 30 calendar days from the date of the

request which document that the emission source

is

in

fact exempt from this Subpart.

 These records shall

include

 (but are not limited to)

 the percent water

(by

weight)

 in the paint or ink being produced and the

quantity of Magie oil, glycol and other solvents

 in the

119—6 13

152

ink being produced.

b)

 Every owner or operator of an emission source which is

subject to the requirements of this Subpart shall

maintain all records necessary to demonstrate

compliance with those requirements at the facility for

three years.

SUBPART BB:

 POLYSTYRENE

PLANTS

Section 219.875

 Applicability of Subpart BB

The provisions of this Subpart shall apply to polystyrene plants:

a)

 Which use continuous processes to manufacture

polystyrene

 polybutadiene co-polymer; and

b)

 Which fall within Standard Industrial Classification

Group No.

 282, Industry No.

 2821, except that the

manufacture of polystyrene resins need not be the

primary manufacturing process at the plant.

Section 219.877

 Emissions Limitation. at Polystyrene Plants

No person shall cause or allow the emissions of VON from the

material recovery section to exceed 0.12 kg of VON per 1000 kg of

polystyrene resin produced.

Section 219.879

 Compliance Date

Every owner and operator of an emission source subject to 35

 Ill.

Adm. Code 215, Subpart BB as of December

31,

 1987,

 shall have

complied with its standards and limitations by December 31,

 1987.

Section 219.881

 Compliance Plan

a)

 The owner or operator of an emission source formerly

subject to the requirements of

 35 Ill. Adm. Code 215

Subpart BB shall have submitted to the Agency

a

compliance plan in accordance with 35 Ill.

 Adm. Code

201, Subpart H,

 including a project completion schedule

on or before December 1,

 1987.

b)

 Unless the submitted compliance plan or schedule was

disapproved by the Agency, the owner or operator of a

facility or emission source subject to this Subpart may

operate the emission source according to the plan and

 schedule as submitted.

c)

 The plan and schedule shall meet the requirements of 35

Ill.

 Adm. Code 201, Subpart H and Section 219.883.

119—614

153

Section 219.883

 Special Requirements for Compliance Plan

For sources subject to this Subpart,

 an approvabie compliance

plan- shall include:

a)

 A description of each process which is subject to an

emissions limitation;

b)

 Quantification of the emissions from each process;

c)

 A description of the procedures and methods used to

determine the emissions of VON;

ci)

 A description of the methods which will be used to

demonstrate compliance with the allowable plantwide

emission limitation (Section 215.877),

 including a

method of inventory,

 recordkeeping and emission

calculation or measurement.

Section 219.886

 Testing and Monitoring

a)

 Upon a reasonable request by the Agency,

 the owner

or

operator of

 a polystyrene plant subject to this Subpart

shall at his own expense demonstrate compliance by use

of the following method:

 40 CFR 60, Appendix A, Method

25

—

 Determination of Total Gaseous Non-Methane Organic

Emissions as Carbon (1984),

 incorporated by reference

in Section 219.112.

b)

 A person planning to conduct a VON emissions test to

demonstrate compliance with this Subpart shall notify

the Agency of that intent not less than 30 days before

the planned initiation of the tests so the Agency may

observe the test.

SUBPART PP:

 MISCELLANEOUS FABRICATED PRODUCT MANUFACTURING PROCESSES

Section 219.920

 Applicability

a)

 The requirements of this Subpart shall apply to a

plant’s miscellaneous fabricated product manufacturing

process emission sources which are not included within

any of the source categories specified in Subparts

B,

E,

F,

H,

Q,

B,

5,

V,

X,

 Y or

Z

 if the plant

 is subject

to this Subpart.

 A plant is subject to this Subpart

if

it contains process emission sources, not regulated by

Subparts

B,

E,

F

 (excluding Section 219.204(a)),

H

(excluding Section 219.405),

Q,

R,

S,

V,

X,

 Y or

 Z of

this Part; which as a group both:

1)

 have maximum theoretical emissions of 91 Mg

 (100

119—615

154

tons)

 or more per calendar year of VON if no air

pollution control equipment were used,

and

2)

 are not limited to less than 91 Mg

 (100 tons)

of

VON emissions per calendar year in the absence of

air pollution control equipment,

 through

production or capacity limitations contained in

a

federally enforceable construction permit or

a

SIP

revision.

b)

 If a plant ceases to fulfill the criteria of subsection

(a), the requirements of this Subpart shall continue to

apply to a miscellaneous fabricated products

manufacturing process emission source which was ever

subject to the control requirements of Section 219.926.

c)

 No limits under this Subpart shall apply to emission

sources with emissions of VON to the atmosphere less

than or equal to 0.91 Mg (1.0 ton) per calendar year

if

the total emissions from such sources not complying

with Section 219.926 does not exceed 4.5 Mg

 (5.0 tons)

per calendar year.

ci)

 For the purposes of this Subpart,

 an emission source

shall

 be considered regulated by

 a Subpart if

it

is

subject to the limits of that Subpart.

 An emission

source is not considered regulated by a Subpart

 if its

emissions are below the applicability cutoff level or

if

the source is covered by an exemption.

e)

 For the purposes of this Subpart, uncontrolled VOM

emissions are the emissions of VON which would result

if no air pollution control equipment were used.

Section 219.923

 Permit Conditions

No

person shall violate any condition in a permit when the

condition results in exclusion of the plant or an emission source

from this Subpart.

Section 219.926

 Control Requirements

Every owner or operator of an emission source subject to this

Subpart shall comply with the requirements of subsection

 (a),

(b)

or

 (C):

a)

 Emission capture and control techniques which achieve

an overall reduction in uncontrolled VOM emissions of

at least 81 percent, or

b)

 For coating lines,

 the daily-weighted average VON

content shall not exceed 0.42 kg VON/i

 (3.5 lbs

119—616

155

VON/gal)

 of coating as applied (minus water and any

compounds which are specifically exempted from the

definition of VON) during any day.

 Owners and

operators complying with this Section are not required

to comply with Section 219.301,

or

c)

 An alternative control plan which has been approved by

the Agency and approved by the USEPA as a SIP revision.

Section 219.927

 Compliance Schedule

Every owner or operator of an emission source subject to the

control requirements of this Subpart shall comply with the

requirements thereof on and after a date consistent with Section

 219. 106.

Section 219.928

 Testing

Any owner or operator of a VON emission source which is subject

to this Subpart shall demonstrate compliance with Section 219.926

by using the applicable test methods and procedures specified in

Section 219.105.

SUBPART QQ:

 MISCELLANEOUS FORMULATION MANUFACTURING PROCESSES

Section 219.940

 Applicability

a)

 The requirements of this Subpart shall apply to a

plant’s miscellaneous formulation manufacturing process

emission sources, which are not included within any

of

the source categories specified in Subparts B,

E,

F,

H,

Q,

R,

5,

V,

X,

 Y or

 Z of this Part if the plant

is

subject to this Subpart.

 A plant is subject to this

Subpart if it contains process emission sources, not

regulated by Subparts

B,

E,

F

 (excluding Section

219.204(1)),

H

 (excluding Section 219.405),

Q,

R,

5,

V,

X,

 Y or

 Z of this Part; which as a group both:

1)

 have maximum theoretical emissions of

 91 Mg (100

tons)

 or more per calendar year of VON if no air

pollution control equipment were used, and

2)

 are not limited to, less than 91 Mg

 (100 tons)

of

VON emissions per calendar year in the absence of

air pollution control equipment,

 through

production or capacity limitations contained in a

federally enforceable construction permit or a SIP

revision.

b)

If

 a plant ceases to fulfill the criteria of subsection

(a), the requirements of this Subpart shall continue to

apply to a miscellaneous formulation manufacturing

119—617

156

process emission source which was ever subject to the

control requirements of Section 219.946.

c)

 No limits under this Subpart shall apply to emission

sources with emissions of VON to the atmosphere less

than or equal to 2.3 Mg (2.5 tons)

 per calendar year if

the total emissions from such sources not complying

with this Section does not exceed 4.5 Mg (5.0 tons)

per

calendar year.

d)

 For the purposes of this Subpart, an emission source

shall be considered regulated by a Subpart if

it

is

subject to the limits of that Subpart.

 An emission

source is not considered regulated by a Subpart if its

emissions are below the applicability cutoff level

or

if the source is covered by an exemption.

e)

 For the purposes of this Subpart, uncontrolled VON

emissions are the emissions of VON which would result

if no air pollution control equipment were used.

Section 219.943

 Permit Conditions

No person shall violate any condition in a permit when the

condition results in exclusion of the plant or an emission source

from this Subpart.

Section 219.946

 Control Requirements

Every owner or operator of an emission source subject to this

Subpart shall comply with the requirements of subsection

(a)

or

(b)

 below.

a)

 Emission capture and control techniques which achieve

an overall reduction in uncontrolled VON emissions of

at least 81 percent,

or

b)

 An alternative control plan which has been approved by

the Agency and approved by the USEPA as a SIP revision.

Section 219.947

 Compliance Schedule

Every owner or operator of an emission source subject to the

control requirements of this Subpart shall comply with the

requirements thereof on and after

 a date consistent with Section

219. 106.

Section 219.948

 Testing

Any owner or operator of a VON emission source which is subject

to this Subpart shall demonstrate compliance with Section 219.946

by using the applicable test methods and procedures specified in

119—618

157

Section 219.105.

SUBPART RR:

 MISCELLANEOUS ORGANIC CHEMICAL MANUFACTURING PROCESSES

Section 219.960

 Applicability

a)

 The requirements of this Subpart shall apply to

a

plant’s miscellaneous organic chemical manufacturing

process emission sources which are not included within

any of the source categories specified in Subparts B,

E,

F,

H,

Q,

R,

 5, V,

X,

 Y or

 Z of this Part,

 if the

plant

 is subject to this Subpart.

 A plant is subject

to this Subpart if

 it contains process emission

sources, not regulated by Subparts B,

E,

 F (excluding

Section 219.204(1)),

H

 (excluding Section 219.405),

Q,

R,

5,

V,

X,

 Y or

 Z of this Part; which as a group both:

1)

 have maximum theoretical emissions of 91 Mg

 (100

tons)

 or more per calendar year of VON if no air

pollution control equipment were used,

and

2)

 are not limited to less than 91 Mg (100 tons)

of

VOM emissions per calendar year in the absence of

air pollution control equipment,

 through

production or capacity limitations contained in

a

federally enforceable construction permit or

 a SIP

revision.

b)

If

 a plant ceases to fulfill the criteria of Subsection

(a), the requirements of this Subpart shall continue to

apply to a miscellaneous organic chemical manufacturing

process emission source which was ever subject to the

 control requirements of Section 219.966.

c)

 No limits under this Subpart shall apply to emission

sources with emissions of VON to the atmosphere less

than or equal to 0.91 Mg

 (1.0 ton) per calendar year if

the twt~

~

 ~o~pffi~i~.

0

tons) per calendar year.

ci)

 For the purposes of this Subpart, an emission source

shall be considered regulated by a Subpart if

it

is

subject to the limits of that Subpart.

 An emission

source is not considered regulated by a Subpart if its

emissions are below the applicability cutoff level or

if the source

 is covered by an exemption.

e)

 For the purposes of this Subpart, uncontrolled VON

emissions are the emissions of VON which would result

if no air pollution control equipment were used.

119—619

158

Section 219.963

 Permit Conditions

No

person shall violate any condition in a permit when the

condition results in exclusion of the plant or an emission source

from this Subpart.

Section 219.966

 Control Requirements

Every owner or operator of an emission source subject to this

Subpart shall comply with the requirements of subsection

(a)

or

(b) below.

a)

 Emission capture and control techniques which achieve

an overall reduction in uncontrolled VOM emissions of

at least 81 percent,

or

b)

 An alternative control plan which has been approved by

the Agency and approved by the USEPA as a SIP revision.

Section 219.967

 Compliance Schedule

Every owner or operator of an emission source subject to the

control requirements of this Subpart shall comply with the

requirements of this Subpart on and after

 a date consistent with

Section 219.106.

Section 219.968

 Testing

Any owner or operator of a VON emission source which is subject

to this Subpart shall demonstrate compliance with Section 219.966

by using the applicable test methods and procedures specified

in

Section 219.105.

SUBPART TT:

 OTHER EMISSION SOURCES

Section 219.980

 Applicability

a)

 The requirements of this Subpart shall apply to a

plant’s VOM emission sources, which are not included

within any of the source categories specified in

Subparts

B,

E,

F,

H,

Q,

R,

S,

V,

X,

Y,

Z,

AA,

PP,

QQ,

or RR of this Part,

 if the plant is subject to this

Subpart.

 A plant is subject to this Subpart if it

contains process emission sources, not regulated by

Subparts B,

E,

F

 (excluding Section 219.204(7)), H

(excluding Section 219.405),

Q,

R,

S,

V,

X,

 Y or

Z

of

this Part, which as a group both:

1)

 have maximum theoretical emissions of 91 Mg

 (100

tons)

 or more per calendar year of VON if no air

pollution control equipment were used,

and

119—620

159

2)

 are not limited to less than 91 Mg

 (100 tons)

of

VON emissions per calendar year in the absence of

air pollution control equipment, through

production or capacity limitations contained in

a

federally enforceable construction permit or

 a SIP

revision.

b)

If

a plant ceases to fulfill the criteria of subsection

(a), the requirements of this Subpart shall continue

to

apply to an emission source which was ever subject to

the control requirements of Section 219.986.

c)

 No limits under this Subpart shall apply to emission

sources with emissions of VON to the atmosphere less

than or equal to 2.3 Mg

 (2.5 tons)

 per calendar year

if

the total emissions from such sources not complying

with Section 219.986 does not exceed 4.5 Mg

 (5.0 tons)

per calendar year.

d)

 For the purposes of this Subpart,

 an emission source

shall be considered regulated by a Subpart if

 it is

subject to the limits of that Subpart.

 An emission

source is not considered regulated by a Subpart if its

emissions are below the applicability cutoff level or

if the source

 is covered by an exemption.

e)

 The control requirements in Subparts QQ, RR,

 SS and

TT

shall not apply to sewage treatment plants, vegetable

oil processing plants, coke ovens

 (including by-product

recovery plants),

 fuel combustion sources,

 bakeries,

barge loading facilities,

 jet engine test cells,

pharmaceutical manufacturing, production of polystyrene

foam insulation board

 (including storage and extrusion

of scrap where blowing agent is added to the

polystyrene resin at the plant), production of

polystyrene foam packaging (not including storage and

extrusion of scrap where blowing agent is added to the

polystyrene resin at the plant), and iron and steel

production.

Section 219.983

 Permit Conditions

No person shall violate any condition in a permit when the

condition results in exclusion of the plant or an emission source

from this Subpart.

Section 219.986

 Control Requirements

Every owner or operator of an emission source subject to this

Subpart shall comply with the requirements of subsection

 (a),

(b)

or

 (c) below.

119—62 1

160

a)

 Emission capture and control equipment which achieve an

overall reduction in uncontrolled VOM emissions of at

least 81 percent,

or

b)

 For coating lines, the daily-weighted average VON

content shall not exceed 0.42 kg VOM/l

 (3.5 lbs

VON/gal)

 of coating (minus water and any compounds

which are specifically exempted from the definition of

VON)

 as applied during any day.

 Owners and operators

complying with this Section are not required to comply

with Section 219.301,

or

c)

 An alternative control plan which has been approved by

the Agency and approved by the USEPA as a SIP revision.

Section 219.987

 Compliance Schedule

Every owner or operator of an emissions source which

 is subject

to this Subpart shall comply with the requirements of this

Subpart on and after a date consistent with Section 219.106.

Section 219.988

 Testing

Any owner or operator of a VON emission source which is subject

to this Subpart shall demonstrate compliance with Section 219.986

by using the applicable test methods and procedures specified

in

Section 219.105.

SUBPART UU:

 RECORDKEEPING

AND

REPORTING FOR NON-CTG SOURCES

Section 219.990

 Exempt Emission Sources

Upon request by the Agency, the owner or operator of an emission

source which

 is exempt from the requirements of Subparts PP,

QQ,

RR,

TT

or Section 219.208(b)

 shall submit records to the Agency

within

 30 calendar days from the date of the request that

document that the emission source

 is exempt from those

requirements.

Section 219.991

 Subject Emission Sources

a)

 Any owner or operator of a VON emission source which

is

subject to the requirements of Subpart PP, QQ, RR or

TT

and complying by the use of emission capture and

control equipment shall comply with the following:

1)

 By a date consistent with Section 219.106,

 or upon

initial start-up of a new emission source, the

owner or operator of the subject VON emission

source shall perform all tests and submit to the

Agency and the USEPA the results of all tests and

calculations necessary to demonstrate that the

119—6 22

161

subject emission source will be in compliance on

and after a date consistent with Section 219.106,

or on and after the initial start-up date.

2)

 On and after a date consistent with Section

219.106, or on and after the initial start-up

date,

 the owner or operator of a subject VON

emission source shall collect and record all of

the following information each day and maintain

the information at the facility for a period of

 three years:

A)

 Control device monitoring data.

B)

 A log of operating time for the capture

system, control device, monitoring equipment

and the associated emission source.

C)

 A maintenance log for the capture system,

control device and monitoring equipment

detailing all routine and non-routine

maintenance performed including dates and

duration of any outages.

3)

 On and after

 a date consistent with Section

219.106, the owner or operator

of

 a subject VON

emission source shall notify the Agency in the

following instances:

A)

 Any record showing a violation of the

requirements of Subpart PP, QQ,

RR

 or TT

shall be reported by sending a copy of such

record to the Agency within 30 days following

the occurrence of the violation.

B)

At

least 30 calendar days before changing the

method of compliance with Subpart

PP

or TT

from the use of capture systems and control

devices to the use of complying coatings,

the

owner or operator shall comply with all

requirements of subsection

 (b) (1).

 Upon

changing the method of compliance with

Subpart PP or TT from the use of capture

systems and control devices to the use of

complying coatings, the owner or operator

shall comply with all requirements of

 subsection

 (b).

b)

 Any owner or operator of a coating line which is

subject

to the requirements of Subpart

PP

 or TT and

complying by means of the daily-weighted average VON

content limitation shall comply with the following:

119—6 23

162

1)

By

 a date consistent with Section 219.106, or upon

initial start—up of a coating line subject to

Subpart PP or

TT,

 the owner or operator of the

subject coating line shall certify to the Agency

that the coating line will be in compliance on and

after a date consistent with Section 219.106, or

on and after the initial start-up date.

 Such

certification shall include:

A)

 The name and identification number of each

coating line which will comply

by

means

of

the daily-weighted average

VOM

content

limitation.

B)

 The name and identification number of each

coating as applied on each coating line.

C)

 The weight of VOM per volume and the volume

of each coating

 (minus water and any

compounds which are specifically exempted

from the definition of VON)

 as applied each

day on each coating line.

D)

 The instrument or method by which the owner

or operator will accurately measure or

calculate the volume of each coating as

applied each day on each’ coating line.

E)

 The method by which the owner or operator

will create and maintain records each day as

required in subsection

 (b) (2).

F)

 An example of the format in which the records

required in subsection

 (b) (2) will be kept.

2)

 On and after a date consistent with Section

219.106,

 or on and after the initial start-up

date,

 the owner or operator of a subject coating

line shall collect and record all of the following

information each day for each coating line and

maintain the information at the facility for a

period of three years:

A)

 The name and identification number of each

coating as applied on each coating line.

B)

 The weight of VON per volume and the volume

of each coating

 (minus water and any

compounds which are specifically exempted

from the definition of VON)

 as applied each

day on each coating line.

119—624

163

C)

 The daily-weighted average

VON

content of all

coatings as applied on each coating line as

defined in Section 219.104.

3)

 On and after a date consistent with -Section

 219.106, the owner or operator of a subject

coating line shall notify the Agency in the

following instances:

A)

 Any record showing violation of the

requirements of Subpart

PP

or

TT

shall be

reported by sending a copy of such record to

the Agency within 30 days following the

occurrence of the violation.

B)

 At least 30 calendar days before changing the

method of compliance with Subpart

PP

or TT

from the use of complying coatings to the use

capture systems and control devices, the

owner or operator shall comply with all

requirements of subsection

 (a) (1).

 Upon

changing the method of compliance with

Subpart PP or TT from the use of complying

coatings to the use capture systems and

control devices, the owner or operator shall

comply with all requirements of subsection

(a).

c)

 Any owner or operator of a VON emission source which is

subject to the requirements of Subpart PP,

QQ,

RR

or TT

and complying by means of an alternative control plan

which has been

approved

by

the Agency and approved by

the USEPA as a

SIP

 revision shall comply with the

recordkeeping and reporting requirements specified in

 the alternative control plan.

119—625

164

APPENDIX A

LIST OF CHEMICALS DEFINING SYNTHETIC

ORGANIC CHEMICAL AND POLYMER

MANUFACTURING

CAS No.

a

 Chemical

105—57—7

 Acetal

75-07-0

 Acetaldehyde

107-89-1

 Acetaldol

60-35-5

 Acetamide

103-84-4

 Acetanilide

64-19-7

 Acetic acid

108-24-7

 Acetic anhydride

67-64-1

 Acetone

75-86-5

 Acetone cyanohydrin

75-05-8

 Acetonitrile

98-86-2

 Acetophenone

75-36-5

 Acetyl chloride

74-86-2

 Acetylene

107—02—8

 Acrolein

79-06-1

 Acrylamide

79-10-7

 Acrylic acid & esters

107-13—1

 Acrylonitrile

124-04-9

 Adipic acid

111-69-3

 Adiponitrile

(b)

 Alkyl naphthalenes

107—18—6

 Allyl alcohol

107-05-1

 Ailyl chloride

1321-11—5

 Aminobenzoic acid

111-41-1

 Aminoethylethanolamine

123-30-8

 p-aminophenol

628-63-7,

 Amyl acetates

123—92—2

7l~4l~Oc

 Amyl alcohols

110-58-7

 Amyl amine

543-59-9

 Amyl chloride

llO~~68~7c

 Amyl mercaptans

1322-06-i

 Amyl phenol

62—53—3

 Aniline

142-04-1

 Aniline hydrochloride

29191—52—4

 Anisidine

100—66—3

 Anisole

118-92-3

 Anthranilic acid

84-65-1

 Anthraquinone

100-52-7

 Benzaldehyde

55—21—0

 Benzamide

71-43-2

 Benzene

98-48-6

 Benzenedisulfonic acid

98-11-3

 Benzenesuifonic acid

134—81—6

 Benzil

119—626

165

76-93-7

 Benzilic acid

65-85-0

 Benzoic acid

119—53—9

 Benzoin

100-47-0

 Benzonitrile

119-61-9

 Benzophenone

98-07-7

 Benzotrichioride

98-88-4

 Benzoyl chloride

100-51-6

 Benzyl alcohol

100-46-9

 Benzylamine

120-51-4

 Benzyi benzoate

100-44-7

 Benzyi chloride

98-87-3

 Benzyl dichloride

92-52-4

 Biphenyl

80-05-7

 Bisphenol A

10-86-1

 Bromobenzene

27497-51-4

 Bromonaphthalene

106-99-0

 Butadiene

106-98-9

 1-butene

123-86-4

 n-butyl acetate

141-32-2

 n-butyl acrylate

71-36-3

 n-butyl alcohol

78-92-2

 s-butyl alcohol

75-65-0

 t—butyl alcohol

109-73-9

 n-butyiamine

13952—84-6

 s—butylamine

75-64-9

 t-butylamine

98-73-7

 p-tert-butyl benzoic acid

107-88-0

 1,3-butylene glycol

123-72-8

 n-butyraldehyde

107-92-6

 Butyric acid

106-31-0

 Butyric anhydride

109-74-0

 Butyroriitrile

105-60-2’

 Caprolactam

75-1—50

 Carbon disulfide

558-13-4

 Carbon tetrabromide

55-23-5

 Carbon tetrachioride

9004-35-7

 Cellulose acetate

79-11-8

 Chioroacetic acid

108-42-9

 in-chioroaniline

95-51-2

 o-chloroaniline

106-47-8

 p-chloroaniline

35913-09-8

 Chlorobenzaidehyde

108-90-7

 Chlorobenzene

118-91-2,

 Chlorobenzoic acid

535—80—8,

74—1l—3c

2136-81-4,

 Chlorobenzotrichioride

2136—89—2,

1321-03-5

 Chlorobenzoyl chloride

75-45-6

 Chlorodifluoroethane

119—627

166

25497-29-4

 Chlorodifluoromethane

67-66-3

 Chloroform

25586-43-0

 Chloronaphthalene

88—73—3

 o—chloronitrobenzene

100-00-5

 p-chloronitrobenzene

25167-80-0

 Chiorophenols

126-99-8

 Chloroprene

7790-94-5

 Chlorosulfonic acid

108-41-8

 m-chlorotoluene

95-49-8

 o-chlorotoluene

106-43-4

 p—chlorotoluene

75-72-9

 Chlorotrifluoromethane

108-39-4

 in—cresol

95—48—7

 o—cresol

106-44—5

 p—cresol

1319-77-3

 Mixed cresols

1319—77-3

 Cresylic acid

4170-30-0

 Crotonaldehyde

3724-65-0

 Crontonic acid

98-82-8

 Cumene

80-15-9

 Cumene hydroperoxide

372-09-8

 Cyanoacetic acid

506-77-4

 Cyanogen chloride

108-80-5

 Cyanuric acid

108-77-0

 Cyanuric chloride

110-82-7

 Cyclohexane

108-93-0

 Cyclohexanol

108-94-1

 Cyclohexanone

110-83-8

 Cyclohexene

108-91-8

 Cyclohexylamine

111-78-4

 Cyclooctadiene

112—30—i

 Decanol

123-42-2

 Diacetone alcohol

27576-04-1

 Diaminobenzoic acid

95-76-i,

 Dichloroaniline

95—82—9,

554—00—7,

608—27—5,

608—31—1,

626—43—7,

27134—27—6

57311—92—9

541-73-1

 m-dichlorobenzene

95-50-i

 o-dichlorobenzene

106-46-7

 p-dichlorobenzene

75-71-8

 Dichlorodifiuoromethane

111-44-4

 Dichloroethyl ether

107-06-2

 1,2-dichioroethane

 (EDC)

96-23-1

 Dichlorohydrin

26952-23-8

 Dichloropropene

101-83-7

 Dicyclohexylamine

119—628

167

109-89—7

 Diethylamine

111-46—6

 Diethylene glycol

112-36-7

 Diethylene glycol diethyl ether

111-96-6

 Diethylene glycol dimethyl ether

112-34-5

 Diethylene glycol monobutyl ether

124-17-7

 Diethylene glycol mononbutyl ether

acetate

111-90-0

 Diethylene glycol monoethyl ether

112-15-2

 Diethylene glycol monoethyl ether acetate

111-77-3

 Diethylene glycol monomethyl ether

64-67-5

 Diethyl sulfate

75-37-6

 Difluoroethane

25167-70-8

 Diisobutylene

 26761-40-0

 Diisodecyi phthalate

27554-26—3

 Diisooctyl phthalate

674-82—8

 Diketene

124-40-3

 Dimethylamine

121-69-7

 N,N—dimethylaniline

115-10-6

 N,N-dimethyl ether

68-12-2

 N,N-dimethylformamide

57-14-7

 Dimethylhydrazine

77-78—1

 Dimethyl sulfate

75—18—3

 Dimethyl sulfide

67-68-5

 Dimethyl sulfoxide

120-61-6

 Dimethyl terephthalate

99-34-3

 3,5-dinitrobenzoic acid

51-28-5

 Dinitrophenol

Dinitrotoluene

123—91—1

 Dioxane

646-06—0

 Dioxilane

122-39-4

 Diphenylamine

101-84-4

 Diphenyl oxide

102-08-9

 Diphenyl thiourea

25265-71—8

 Dipropylene glycol

25378-22—7

 Dodecene

28675—17—4

 Dodecylaniline

27193-86—8

 Dodecylphenol

106-89-8

 Epichlorohydrin

64—17—5

 Ethanol

l4l~43~Sc

 Ethanolamines

141-78-6

 Ethyl

acetate

141-97-9

 Ethyl acetoacetate

140-88-5

 Ethyl

acrylate

75-04-7

 Ethylamine

100-41-4

 Ethylbenzene

74-96-4

 Ethyl bromide

 9004-57-3

 Ethylcellulose

75-00-3

 Ethyl

chloride

105-39—5

 Ethyl chioroacetate

105-56-6

 Ethylcyanoacetate

74—85—1

 Ethylene

119—629

168

96-49-1

 Ethylene carbonate

107-07-3

 Ethylene chlorohydrin

107-15-3

 Ethylenediamine

106-93-4

 Ethylene dibromide

107-21-1

 Ethylene giycol

111-55-7

 Ethylene glycol diacetate

110-71-4

 Ethylene giycol dimethyl ether

111-76-2

 Ethylene glycol monobutyl ether

112-07-2

 Ethylene glycol monobutyl ether acetate

110-80-5

 Ethylene glycol monoethyl ether

111-15-9

 Ethylene glycol monoethyl ether acetate

109-86-4

 Ethylene glycol monoethyl ether

110-49-6

 Ethylene glycol monomethyl ether acetate

122-99-6

 Ethylene glycol monophenyl ether

2807-30-9

 Ethylene glycol monopropyl ether

75-21-8

 Ethylene oxide

60-29-7

 Ethyl ether

104-76-7

 2-ethylhexanol

122-51-0

 Ethyl orthoformate

95-92-1

 Ethyl oxalate

41892-71-i

 Ethyl

sodium oxaloacetate

50-00-0

 Formaldehyde

75—12-7

 Formamide

64-18-6

 Formic acid

110-17-8

 Fumaric acid

98—01—1

 Furfural

56-81-5

 Glycerol

 (Synthetic)

26545-73-7

 Glycerol dichlorohydrin

25791-96-2

 Glycerol triether

56—40—6

 Glycine

107—22—2

 Glyoxal

118-74-1

 Hexachlorobenzene

67-72-1

 Hexachioroethane

36653-82-4

 Hexadecyl alcohol

124-09-4

 Hexamethylenediamine

629—11-8

 Hexamethylene glycol

100-97-0

 Hexamethylenetetramine

74-90-8

 Hydrogen cyanide

123-31-9

 Hydroquinone

99-96-7

 p-hydroxybenzoic acid

26760—64—5

 Isoamylene

78-83—1

 Isobutanol

110-19-0

 Isobutyl acetate

115-11-7

 Isobutylene

78-84-2

 Isobutyraldehyde

79-31-2

 Isobutyric acid

25339—17—7

 Isodecanol

26952-21-6

 Isooctyl alcohol

78-78-4

 Isopentane

78-59-1

 Isophorone

121-91—5

 Isophthalic acid

78—79—5

 Isoprene

119—630

169

67—63-0

 Isopropanol

108-21-4

 Isopropyl acetate

75-31-0

 Isopropylamine

75-29-6

 Isopropyl chloride

25168-06-3

 Isopropylphenol

463—51—4

 Ketene

(b)

 Linear alkyl suifonate*

123-01-3

 Linear alkylbenzene

110-16-7

 Maleic acid

108-31-6

 Maleic anhydride

6915—15—7

 Malic acid

141-79-7

 Mesityl oxide

121-47-i

 Metanilic acid

79-41-4

 Methacrylic acid

563-47—3

 Methallyl chloride

67-56-1

 Methanol

79-20-9

 Methyl acetate

105-45-3

 Methyl acetoacetate

74-89-5

 Nethylamine

100—61-8

 n—methylaniline

74-83-9

 Methyl bromide

37365-71-2

 Methyl butynol

74-87—3

 Methyl chloride

108-87-2

 Methyl

 cyclohexane

1331-22-2

 Methyl cyciohexanone

75-09-2

 Nethylene chloride

101-77-9

 Methylene dianiline

101-68-8

 Methylene diphenyl diisocyanate

78-93-3

 Methyl

 ethyl

ketone

107-31-3

 Methyl formate

108-11-2

 Methyl isobutyl carbinol

108-10-1

 Methyl

 isobutyl ketone

80-62-6

 Methyl

methacrylate

77-75-8

 Nethylpentynol

98-83-9

 B-methylstyrene

110-91-8

 Morpholine

85-47-2

 a-naphthalene sulfonic acid

120-18-3

 B-naphthaiene suifonic acid

90-15-3

 a—naphthol

135-19-3

 B-naphthol

75-98-9

 Neopentanoic acid

88-74-4

 o—nitroaniline

100-01-6

 p-nitroaniline

91-23-6

 o-nitroanisole

100-17—4

 p—nitroanisole

98-95-3

 Nitrobenzene

Nitrobenzoic acid

 (o, m

&

p)

79-24-3

 Nitroethane

75-52-5

 Nitromethane

88-75-5

 Nitrophenol

25322-01-4

 Nitropropane

119—631

170

1321-12-6

 Nitrotoluene

27215—95—8

 Nonene

25154-52-3

 Nonylphenol

27193-28-8

 Octyiphenol

123-63-7

 Paraldehyde

115-77-5

 Pentaerythritoi

109-66-0

 n-pentane

109-67-1

 1—pentene

127-18-4

 Perchloroethylene

594-42-3

 Perchloromethyl mercaptan

94-70-2

 o-phenetidine

156-43-4

 p-phenetidine

108—95—2

 Phenol

98—67—9,

 Phenolsulfonic acids

585—38—6,

609—46—1

133—39—7~

91-40-7

 Phenyl anthranilic acid

(b)

 Phenylenediaxnine

75-44-5

 Phosgene

85-44-9

 Phthalic anhydride

85-41-6

 Phthalimide

108—99—6

 b—picoline

110-85-0

 Piperazine

9003-29-6,

 Polybutenes

25322-68-3

 Polyethylene glycol

25322-69-4

 Polypropylene glycol

123-38-6

 Propionaldehyde

79-09-4

 Propionic acid

71-23-8

 n-propyl alcohol

107-10-8

 Propylamine

540-54-5

 Propyl chloride

115-07-1

 Propylene

127-00-4

 Propylene chiorohydrin

78-87-5

 Propylene dichloride

57-55-6

 Propylene glycol

75-56-9

 Propylene oxide

110—86—1

 Pyridine

106-51-4

 Quinone

108-46-3

 Resorcinol

27138-57-4

 Resorcylic acid

69—72—7

 Salicylic acid

127-09-3

 Sodium acetate

532-32-1

 Sodium benzoate

9004-32-4

 Sodium carboxymethyl cellulose

3926-62-3

 Sodium chioroacetate

141-53-7

 Sodium formate

 139-02-6

 Sodium phenate

110—44-I

 Sorbic acid

100-42—5

 Styrene

119—632

171

110—15—6

 Succinic acid

110—61—2

 Succinitrile

121—57—3

 Sulfanilic acid

126—33—0

 Sulfolane

1401-55—4

 Tannic acid

100-21-0

 Terephthalic acid

Tetrachioroethanes

117-08-8

 Tetrachlorophthalic anhydride

78-00-2

 Tetraethyllead

119-64-2

 Tetrahydronaphthalene

85-43-8

 Tetrahydrophthalic anhydricie

75-74-1

 Tetramethyllead

110-60-1

 Tetramethylenediamine

110-18-9

 Tetramethylethylenediamine

108—88—3

 Toluene

95-80-7

 Toluene—2,4—diamine

584-84—9

 Toluene—2, 4—diisocyanate

26471-62-5

 Toluene diisocyanates

 (mixture)

1333-07-9

 Toluene sulfonamide

lO4~lS~~4c

 Toluenesulfonic acids

98—59—9

 Toiuene sulfonyl chloride

26915—12—8

 Toluidines

87—61-6,

 Trichlorobenzenes

108—70—3,

l20—82—ic

71-55-6

 1,1, 1—trichioroethane

79-00-5

 l,l,2—trichloroethane

79-01-6

 Trichloroethylene

75-69-4

 Trichlorofluoromethane

 96-18-4

 1,2,3—trichloropropane

76-13-1

 1, l,2—trichloro—l,2,2—trifluoroethane

121-44-8

 Triethylamine

112-27-6

 Triethylene glycol

112-49-2

 Triethylene glycoldimethyl ether

7756-94-7

 Triisobutylene

75-50-3

 Trimethylamine

57—13-6

 Urea

108-05-4

 Vinyl acetate

75-01-4

 Vinyl chloride

75-35-4

 Vinylidene chloride

25013-15-4

 Vinyl toluene

1330-20-7

 Xylenes (mixed)

95—47—6

 o—xylene

106—42—3

 p—xylene

1300—71—6

 Xylenoi

1300—73—8

 Xylidine

(b)

 methyl tert-butyl

 ether

9002-88-4

 Polyethylene

(b)

 Polypropylene

9009-53-6

 Polystyrene

119—633

172

a) CAS numbers refer to the Chemical Abstracts Registery numbers

assigned to specific chemicals,

 isomers or mixtures of

chemicals.

 Some isomers or mixtures that are covered by the

standards do not have CAS numbers assigned to them.

The

standards apply to all of the chemicals listed, whether CAS

numbers have been assigned or not.

b)

No

CAS number(s) have been assigned to this chemical, to its

isomers,

 or mixtures containing these chemicals.

c) CAS numbers for some of the isomers are listed:

 the standards

apply to all of the isomers and mixtures,

 even if CAS numbers

have not been assigned.

119—634

173

APPENDIX B

VON MEASUREMENT TECHNIQUES FOR CAPTURE EFFICIENCY

Procedure G.1

 Captured VOC Emissions

I.

 INTRODUCTION

1.1

 Applicability.

 This procedure is applicable for determining

the volatile organic compounds

 (VOC)

 content of captured gas

streams.

 It is intended to be used as a segment in the

development of liquid/gas or gas/gas protocols for determining

VOC capture efficiency

 (CE)

 for surface coating and printing

operations.

 The procedure may not be acceptable in certain

site—specific situations,

 e.g., when:

 (1) direct fired heaters or

other circumstances affect the quantity of VOC at the control

device inlet; and

 (2) particulate organic aerosols are formed in

the process and are present in the captured emissions.

1.2

 Principle.

 The amount of VOC captured

(G)

 is calculated

as

the sum of the products of the VOC content

 (CGj).

 the flow rate

(Q~), and the sample time

 (Ta) from each captured emissions

point.

1.3

 Estimated Measurement Uncertainty.

 The measurement

uncertainties are estimated for each captured or fugitive

emissions point as follows:

 5.5 percent and

CG.

 ±5.0percent.

 Based on these numbers, the probable

un~certaintyfor G

 is estimated at about ±7,4percent.

1.4

 Sampling Requirements.

 A capture efficiency test shall

consist of at least three sampling runs.

 The sampling time for

each run should be at least

 8 hours, unless otherwise approved.

1.5

 Notes.

 Because this procedure is often applied in highly

explosive areas,

 caution and care should be exercised in choosing

appropriate equipment and installing and using the equipment.

Mention of trade names or company products does not constitute

endorsement.

 All gas concentrations

 (percent, ppm)

 are by

volume,

 unless otherwise noted.

2.

 APPARATUS AND REAGENTS

2.1

 Gas VOC Concentration.

 A schematic of the measurement

system is shown in Figure

1.

 The main components are described

below:

2.1.1

 Sample Probe.

 Stainless steel,

 or equivalent.

 The probe

shall be heated to prevent VOC condensation.

119—6 35

174

2.1.2

 Calibration Valve Assembly.

 Three-way valve assembly at

the outlet of sample probe to direct the zero and calibration

gases to the analyzer.

 Other methods, such as quick—connect

lines, to route calibration gases to the outlet of the sample

probe are acceptable.

2.1.3

 Sample Line.

 Stainless steel or Teflon tubing to

transport the sample gas to the analyzer.

 The sample line must

be heated to prevent condensation.

2.1.4

 Sample Pump.

 A leak—free pump, to pull the sample gas

through the system at a flow rate sufficient to minimize the

response time of the measurement system.

 The components of the

pump that contact the gas stream shall be constructed of

stainless steel or Teflon.

 The sample pump must be heated to

prevent condensation.

2.1.5

 Sample Flow Rate Control.

 A sample flow rate control

valve and rotameter,

 or equivalent,

 to maintain a constant

sampling rate within 10 percent.

 The flow rate control valve and

rotameter must be heated to prevent condensation.

 A control

valve may also be located on the

sample pump bypass loop to

assist

 in controlling the sample pressure and flow rate.

2.1.6

 Sample Gas Manifold.

 Capable of diverting

 a portion of

the sample gas stream to the flame ionization analyzer

 (FIA),

and

the remainder to the bypass discharge vent.

 The manifold

components shall be constructed of stainless steel

 or Teflon.

If

captured or fugitive emissions are to be measured at multiple

locations,

 the measurement system shall be designed to use

separate sampling probes,

 lines,

 and pumps for each measurement

location and a common sample gas manifold and FIA.

 The sample

gas manifold and connecting lines to the FIA must be heated to

prevent condensation.

2.1.7

 Organic Concentration Analyzer.

 An FIA with a span value

of 1.5 times the expected concentration as propane; however,

other span values may be used if

it

can be demonstrated that they

would provide more accurate measurements.

 The system shall be

capable of meeting or exceeding the following specifications:

2.1.7.1

 Zero Drift.

 Less than ±3.0percent of the span value.

2.1.7.2

 Calibration Drift.

 Less than ±3.0percent of the span

value.

2.1.7.3

 Calibration Error.

 Less than ±5.0percent of the

calibration gas value.

2.1.7.4

 Response Time.

 Less than 30 seconds.

119—636

175

2.1.8

 Integrator/Data Acquisition System.

 An analog or digital

device or computerized data acquisition system used to integrate

 the FIA response or compute the average response and record

measurement data.

 The minimum data sampling frequency for

computing average or integrated values is one measurement value

every

 5 seconds.

 The device shall be capable of recording

average values at least once per minute.

2.1.9

 Calibration and Other Gases.

 Gases used for calibration,

fuel, and combustion air

 (if required) are contained in

compressed gas cylinders.

 All calibration gases shall be

traceable to NIST standards and shall be certified by the

manufacturer to

±1percent of the tag value.

 Additionally, the

manufacturer of the cylinder should provide a recommended shelf

life for each calibration gas cylinder over which the

concentration does not change more than ±2percent from the

certified value.

 For calibration gas values not generally

available,

 alternative methods for preparing calibration gas

mixtures, such as dilution systems, may be used with prior

approval.

2.1.9.1

 Fuel.

 A 40 percent H2/60 percent He or 40 percent H2/60

percent N2 gas mixture

 is recommended to avoid an oxygen

synergism effect that reportedly occurs when oxygen concentration

varies significantly from

 a mean value.

2.1.9.2

 Carrier Gas.

 High purity air with less than

 1 ppm of

organic material

 (as propane or carbon equivalent)

 or less than

0.1 percent of the span value, whichever is greater.

2.1.9.3

FIA

Linearity Calibration Gases.

 Low-,

 mid-,

and

high—range gas mixture standards with nominal propane

concentrations of 20—30,

 45—55, and 70—80 percent of the span

value

 in air, respectively.

 Other calibration values and

other

span values may be used if it can be shown that more accurate

measurements would be achieved.

2.1.10

 Particulate Filter.

 An in-stack or an out-of-stack glass

fiber filter

 is recommended if exhaust gas particulate loading is

significant.

 An out-of-stack filter must be heated to prevent

any condensation unless it can be demonstrated that no

condensation occurs.

2.2

 Captured Emissions Volumetric Flow Rate.

2.2.1

 Method

 2 or 2A Apparatus.

 For determining volumetric flow

rate.

2.2.2

 Method

 3 Apparatus and Reagents.

 For determining

molecular weight of the gas stream.

 An estimate of the molecular

weight

 of the gas stream may be used if it can be justified.

119—6 37

176

2.2.3

 Method

 4 Apparatus and Reagents.

 For determining moisture

 content,

 if necessary.

3.

 DETERMINATION OF VOLUMETRIC FLOW

RATE OF CAPTURED EMISSIONS

3.1

 Locate all points where emissions are captured from the

affected facility.

 Using Method

 1, determine the sampling

points.

 Be sure to check each site for cyclonic or swirling

flow.

3.2

 Measure the velocity at each sampling site at least once

every hour during each sampling run using Method

 2 or 2A.

4.

 DETERMINATION OF VOC CONTENT OF CAPTURED EMISSIONS

4.1

 Analysis Duration.

 Measure the VOC responses at each

captured emissions point during the entire test run or,

if

applicable, while the process is operating.

 If there are

multiple captured emission locations, design-a sampling system to

allow a single FIA to be used to determine the VOC responses

at

all sampling locations.

4.2

 Gas VOC Concentration.

4.2.1

 Assemble the sample train as shown in Figure

1.

 Calibrate

the FIA according to the procedure in Section 5.1.

119—638

177

4.2.2

 Conduct a system check according to the procedure in

Section 5.3.

4.2.3

 Install the sample probe so that the probe is centrally

located in the stack, pipe,

 or duct, and is sealed tightly at the

 stack port connection.

4.2.4

 Inject zero gas at the calibration valve assembly.

 Allow

the measurement system response to reach zero.

 Measure the

system response time as the time required for the system to reach

the effluent concentration after the calibration valve has been

returned to the effluent sampling position.

4.2.5

 Conduct a system check before and a system drift check

after each sampling run according to the procedures

 in Sections

5.2 and 5.3.

 If the drift check following a run indicates

unacceptable performance,

 the run is not valid.

 The tester may

elect to perform system drift checks during the run not to exceed

one drift check per hour.

4.2.6

 Verify that the sample lines, filter,

 and pump

temperatures are 120 ±

SoC.

4.2.7

 Begin sampling at the start of the test period and

continue to sample during the entire run.

 Record the starting

and ending times and any required process information as

appropriate.

 If multiple captured emission locations are sampled

using a single FIA, sample at each location for the same amount

of time

 (e.g.,

 2 minutes) and continue to switch from one

location to another for the entire test run.

 Be sure that total

sampling time at each location is the same at the end of the test

run.

 Collect at least

 4 separate measurements from each sample

 point during each hour of testing.

 Disregard the measurements at

each sampling location until two times the response time of the

measurement system has elapsed.

 Continue sampling for at least

1

minute and record the concentration measurements.

4.3

 Background Concentration.

4.3.1

 Locate all NDO’s of the TTE.

 A sampling point shall be

centrally located outside of the TTE at

 4 equivalent diameters

from each NDO, ifpossible.

 If there are more than

 6 NDO’s,

choose

 6 sampling points evenly spaced among the NDO’s.

4.3.2

 Assemble the sample train as shown

 in Figure

2.

 Calibrate

the FIA and conduct a system check according to the procedures in

Sections 5.1 and 5.3.

 NOTE:

 This sample train shall be

a

separate sampling train from the one to measure the captured

emissions.

119—639

178

4.3.3

 Position the probe at the sampling location.

4.3.4

 Determine the response time,

 conduct the system check and

sample according to the procedures described in Sections 4.2.4

to

4.2.7.

4.4

 Alternative Procedure.

 The direct interface sampling and

analysis procedure described in Section 7.2 of Method 18 may be

used to determine the gas VOC concentration.

 The system must be

designed to collect and analyze at least one sample every 10

minutes.

5.

 CALIBRATION

AND

 QUALITY

ASSURANCE

5.1

 FIA Calibration and Linearity Check.

 Make necessary

adjustments to the air and fuel supplies for the FIA and ignite

the burner.

 Allow the FIA to warm up for the period recommended

by the manufacturer.

 Inject a calibration gas into the

measurement system and adjust the back—pressure regulator to

the

value required to achieve the flow rates specified by the

manufacturer.

 Inject the zero— and the high—range calibration

gases and adjust the analyzer calibration to provide the proper

responses.

 Inject the low— and mid—range gases and record the

responses of the measurement system.

 The calibration and

linearity of the system are acceptable

 if the responses for all

four gases are within

 5 percent of the respective gas values.

If

the performance of the system is not acceptable, repair or adjust

the system and repeat the linearity check.

 Conduct

 a calibration

and linearity check after assembling the analysis system and

after a major change

 is made to the system.

5.2

 Systems Drift Checks.

 Select the calibration gas that most

closely approximates the concentration of the captured emissions

for conducting the drift checks.

 Introduce the zero and

calibration gas at the calibration valve assembly and verify that

the appropriate gas flow rate and pressure are present at the

FIA.

 Record the measurement system responses to the zero and

calibration gases.

 The performance of the system is acceptable

if the difference between the drift check measurement and the

value obtained

 in Section 5.1

 is less than

 3 percent of the span

value.

 Conduct the system drift checks at the end of each run.

5.3

 System Check.

 Inject the high range calibration gas at the

inlet of the sampling probe and record the response.

The

performance of the system is acceptable if the measurement system

response is within

 5 percent of the value obtained in Section 5.1

for the high range calibration gas.

 Conduct a system check

before and after each test run.

5.4

 Analysis Audit.

 Immediately before each test analyze an

audit cylinder as described

in Section 5.2.

 The analysis audit

must agree with the audit cylinder concentration within 10

 119—640

179

percent.

NOMENCLATURE

=

area

NDO

ft2.

A.~

total

area

all

NDO’s

the

enclosure,

ft2.

CBI

corrected

average

VOC

concentration

background

emissions

point

ppm

propane.

average

background

concentration,

ppm

propane.

CGj

=

corrected

average

VOC

concentration

captured

emissions

point

j,

ppm

propane.

CDH

average

measured

concentration

for

the,- drift

check

calibration

gas,

ppm

propane.

CDO

average

system

drift

check

concentration

for

zero

concentration

gas,

ppm

propane.

actual

concentration

the

drift

 check calibration

gas,

ppm

 propane.

uncorrected

average

background

VOC

concentration

measured

point

i,

ppm

propane.

uncorrected

average

VOC

concentration

measured

point

j,

ppm

propane.

total

VOC

content

 captured emissions,

kg.

1.830

lo_6

kg/(m3—ppm).

number

measurement

points.

average

effluent

volumetric

flow

rate

corrected

standard conditions at captured emissions point

j,

m3/min.

Tc

 total duration of captured emissions sampling run, mm.

7.

 CALCULATIONS

7.1

 Total VOC Captured Emissions.

G

j=1

 (CGj

—

C3)

~

Eq.

119—641

180

7.2

 VOC Concentration of the Captured Emissions at Point

j.

C0~

(C~

CDO)

Eq.

CDH

—

CDO

7.3

 Background VOC Concentration at Point

i.

C31

(C1

—

 CDO)

C3~

Eq.

3

CDH

—

CDO

7.4

 Average Background Concentration.

n

C.A.

Eq.

~

nA~

NOTE:

 If the concentration at

each

point

within

percent

the

average

concentration

all

points,

the

terms

“A1t’

and

“AN”

may

deleted

from

Equation

119—642

181

Procedure G.2

 Captured VOC Emissions (Dilution Technique)

1. INTRODUCTION

1.1

 Applicability.

 This procedure is applicable for determining

the volatile organic compounds

 (VOC)

 content

 of captured gas

streams.

 It is intended to be used as a segment in the

development of a gas/gas protocol in which fugitive emissions are

measured for determining VOC capture efficiency

 (CE) for surface

coating and printing operations.

 A dilution system is used to

reduce the VOC concentration of the captured emission to about

the same concentration as the fugitive emissions.

 The procedure

may not be acceptable in certain site—specific situations,

 e.g.,

when:

(1)

 direct fired heaters or other circumstances affect the

quantity of VOC at the control device inlet; and

 (2) particulate

organic aerosols are formed in the process and are present in the

captured emissions.

1.2

Principle.

The

amount

 VOC captured

(G)

 is calculated as

the

sum

the

products

the

VOC

content

(C0~)~the

flow

rate

and

the

sampling

time

(Tc)

 from each captured emissions

point.

1.3

Estimated

Measurement

Uncertainty.

The

measurement

uncertainties

are

estimated

for

each

captured

fugitive

emissions point as follows:

±5~5percent

and

CGj

percent.

 Based on these numbers,

 the probable uncertainty for G

is estimated at about ±74 percent.

1.4

 Sampling Requirements.

 A capture efficiency test shall

consist of at least three sampling runs.

 The sampling time

for

 each run should be at least

 8 hours,

 unless otherwise approved.

1.5

 Notes.

 Because this procedure is often applied in highly

explosive areas,

 caution and care should be exercised in choosing

appropriate equipment and installing and using the equipment.

Mention of trade names or company products does not constitute

endorsement.

 All gas concentrations

 (percent, ppm) are by

volume, unless otherwise noted.

2.

 APPARATUS AND REAGENTS

2.1

 Gas VOC Concentration.

 A schematic of the measurement

system is shown in Figure

1.

 The main components are described

below:

2.1.1

 Dilution System.

 A Kipp in-stack dilution probe and

controller or similar device may be used.

 The dilution rate may

be changed by substituting different critical orifices or

119—643

182

adjustments of the aspirator supply pressure.

 The dilution

system shall be heated to prevent VOC condensation.

 Note:

An

out-of-stack dilution device may be used.

2.1.2

 Calibration Valve Assembly.

 Three-way valve assembly at

the

outlet

sample

probe

direct

the

zero

and

calibration

gases

the

analyzer.

Other

methods,

such

quick—connect

lines, to route calibration gases to the outlet of the sample

probe are acceptable.

2.1.3

 Sample Line.

 Stainless steel or Teflon tubing to

transport the sample gas to the analyzer.

 The sample line must

be heated to prevent condensation.

2.1.4

 Sample Pump.

 A leak-free pump,

 to pull the sample gas

through the system at a flow rate sufficient to minimize the

response time of the measurement system.

 The components of the

pump that contact the gas stream shall be constructed of

stainless steel or Teflon.

 The sample pump must be heated to

prevent condensation.

2.1.5

 Sample Flow Rate Control.

 A sample flow rate control

valve and rotameter,

 or equivalent, to maintain a constant

sampling rate within

 10 percent.

 The flow control valve and

rotameter must be heated to prevent condensation.

 A control

valve may also be located on the sample pump bypass loop to

assist in controlling the sample pressure and flow rate.

2.1.6

 Sample Gas Manifold.

 Capable of diverting a portion of

the sample gas stream to the flame ionization analyzer

 (FIA),

and

the remainder to the bypass discharge vent.

 The manifold

components shall be constructed of stainless steel or Teflon.

If

captured or fugitive emissions are to be measured at multiple

locations, the measurement system shall be designed to use

separate sampling probes,

 lines,

 and pumps for each measurement

location and a common sample gas manifold and FIA.

 The sample

gas manifold and connecting lines to the FIA must be heated to

prevent condensation.

2.1.7

 Organic Concentration Analyzer.

 An FIA with a span value

of 1.5 times the expected concentration

as propane; however,

other

span

values

may

used

can

demonstrated

that

they

would

provide

accurate

measurements.

The

system

shall

capable

meeting

exceeding

the

following

specifications:

2.1.7.1

Zero

Drift.

Less

than

 ±3.0percent of the span value.

2.1.7.2

Calibration

Drift.

Less

than

 ±3.0

percent of

the

span

value.

2.1.7.3

 Calibration Error.

 Less than ±5.0percent of the

119—644

183

calibration gas value.

2.1.7.4

Response

Time.

Less

than

seconds.

2.1.8

 Integrator/Data Acquisition System.

 An analog or digital

device or computerized data acquisition system used to integrate

the FIA response or compute the average response and record

measurement data.

 The minimum data sampling frequency for

computing average or integrated values is one measurement value

every

 5 seconds.

 The device shall be capable of recording

average values at least once per minute.

2.1.9

 Calibration and Other Gases.

 Gases used for calibration,

fuel, and combustion air

 (if required)

 are contained in

compressed gas cylinders.

 All calibration gases shall be

traceable to NIST standards and shall be certified by the

manufacturer to ±1percent of the tag value.

 Additionally,

the

manufacturer

the

cylinder

 should provide a recommended shelf

life

for

each

calibration

gas

cylinder

over

which

the

concentration

does

not

change

than

±2percent

from

the

certified

value.

 For calibration gas values not generally

available,

alternative

methods

for

preparing

calibration

gas

mixtures,

such

dilution

systems,

may

used

with

prior

approval.

2.1.9.1

 Fuel.

 A 40 percent H2/60 percent He or 40 percent H2/60

percent N2 gas mixture is recommended to avoid an oxygen

synergism effect that reportedly occurs when oxygen concentration

varies significantly from a mean value.

2.1.9.2

 Carrier Gas and Dilution Air Supply.

 High purity air

with less than

 1 ppm of organic material

 (as propane or carbon

equivalent)

 or less than

0.1

percent of the span value, whichever

is greater.

2.1.9.3

FIA

Linearity Calibration Gases.

 Low-,

 mid-,

and

high-range gas mixture standards with nominal propane

concentrations of 20-30, 45—55, and 70—80 percent of the span

value in air,

 respectively.

 Other calibration values and other

span values may be used if

 it can be shown that more accurate

measurements would be achieved.

2.1.9.4

 Dilution Check Gas.

 Gas mixture standard containing

propane in air,

 approximately half the span value after dilution.

2.1.10

 Particulate Filter.

 An in—stack or an out-of-stack glass

fiber filter

 is recommended if exhaust gas particulate loading is

 significant.

An

out-of—stack filter must be heated to prevent any condensation

unless

 it can be demonstrated that no condensation occurs.

119—645

184

2.2

 Captured Emissions Volumetric Flow Rate.

2.2.1

 Method

 2 or 2A Apparatus.

 For determining volumetric flow

rate.

2.2.2

 Method

 3 Apparatus and Reagents.

 For determining

molecular weight of the gas stream.

 An estimate of the molecular

weight of the gas stream may be used if it can be justified.

2.2.3

 Method

 4 Apparatus and Reagents.

 For determining moisture

content,

 if necessary.

3.

 DETERMINATION OF VOLUMETRIC FLOW RATE OF CAPTURED EMISSIONS

3.1

 Locate all points where emissions are captured from the

affected facility. Using Method

 1, determine the sampling points.

Be sure to check each site for cyclonic or swirling flow.

3.2

 Measure the velocity at each sampling site at least once

every hour during each sampling run using Method

 2 or 2A.

4.

 DETERMINATION OF VOC CONTENT OF CAPTURED EMISSIONS

4.1

 Analysis Duration.

 Measure the VOC responses at each

captured emissions point during the entire test run or,

if

applicable,

 while the process is operating.

 If there are a

 multiple captured emissions locations,

 design a sampling system

to allow a single FIA to be used to determine the VOC responses

at all sampling locations.

4.2

 Gas VOC Concentration.

4.2.1

 Assemble the sample train as shown

 in Figure

1.

 Calibrate

the FIA according to the procedure in Section 5.1.

4.2.2

 Set the dilution ratio and determine the dilution factor

according to the procedure in Section 5.3.

4.2.3

 Conduct a system check according to the procedure in

Section 5.4.

4.2.4

 Install the sample probe so that the probe is centrally

located in the stack, pipe,

 or duct,

 and is sealed tightly at the

stack port connection.

4.2.5

 Inject zero gas at the calibration valve assembly.

Measure the system response time as the time required for the

system to reach the effluent concentration after the calibration

valve has been returned to the effluent sampling position.

4.2.6

 Conduct a system check before and a system drift check

after each sampling run according to the procedures in Sections

119—646

185

5.2 and 5.4.

 If the drift check following a run indicates

unacceptable performance,

 the run is not valid.

 The tester

may

elect to perform system drift checks during the run not to exceed

one drift check per hour.

4.2.7

 Verify that the sample lines,

 filter, and pump

temperatures are 120 ±5°C.

4.2.8

 Begin sampling at the start of the test period and

continue to sample during the entire run.

 Record the starting

and ending times and any required process information as

appropriate.

 If multiple captured emission locations are sampled

using a single FIA,

 sample at each location for the same amount

of time

 (e.g.,

 2 minutes)

 and continue to switch from one

location to another for the entire test run.

 Be sure that total

sampling time at each location is the same at the end of the test

run.

 Collect at least

 4 separate measurements from each sample

point during each hour of testing.

 Disregard the measurements at

each sampling location until two times the response time of the

measurement system has elapsed.

 Continue sampling for at least

1

minute and record the concentration measurements.

4.3

 Background Concentration.

4.3.1

 Locate all NDO’s of the TTE.

 A sampling point shall be

centrally located outside of the TTE at

 4 equivalent diameters

from each NDO,

 if possible.

 If there are more than

 6 NDO’s,

choose

 6 sampling points evenly spaced among the NDO’s.

4.3.2

 Assemble the sample train as shown in Figure

2.

 Calibrate

the FIA and conduct a system check according to the procedures

in

Sections 5.1 and

5.4.

4.3.3

 Position the probe at the sampling location.

4.3.4

 Determine the response time, conduct the system check and

sample according to the procedures described in Sections 4.2.4

to

4.2.8.

4.4

 Alternative Procedure.

 The direct interface sampling and

analysis procedure described in Section 7.2 of Method

 18 may be

used to determine the gas VOC concentration.

 The system must be

designed to collect and analyze at least one sample every

10

minutes.

5.

 CALIBRATION AND QUALITY

ASSURANCE

5.1

 FIA Calibration and Linearity Check.

 Make necessary

adjustments to the air and fuel supplies for the FIA and ignite

the burner.

 Allow the FIA to warm up for the period recommended

119—64 7

186

by the manufacturer.

 Inject a calibration gas into the

measurement

system

after

the

dilution

system

and

adjust

the

back-

pressure regulator to the value required to achieve the

flow

rates specified by the manufacturer.

 Inject the zero— and the

high—range calibration gases and adjust the analyzer calibration

to provide the proper responses.

 Inject the low- and mid-range

gases and record the responses of the measurement system.

The

calibration and linearity of the system are acceptable if the

responses for all four gases are within

 5 percent of the

respective gas values.

 If the performance of the system is not

acceptable,

 repair or adjust the system and repeat the linearity

check.

 Conduct a calibration and linearity check after

assembling the analysis system and after a major change is made

to the system.

5.2

 Systems Drift Checks.

 Select the calibration gas that most

closely approximates the concentration of the diluted captured

emissions for conducting the drift checks.

 Introduce the zero

and calibration gas at the calibration valve assembly and verify

that the appropriate gas flow rate and pressure are present at

the FIA.

 Record the measurement system, responses to the zero and

calibration gases.

 The performance of the system

 is acceptable

if the difference between the drift check measurement and the

value obtained in Section 5.1 is less than

 3 percent of the span

value.

 Conduct the system drift check at the end of each run.

5.3

 Determination of Dilution Factor.

 Inject the dilution check

gas into the measurement system before the dilution system and

record the response.

 Calculate the dilution factor using

Equation

3.

5.4

 System Check.

 Inject the high range calibration gas at the

inlet to the sampling probe while the dilution air is turned off.

Record the response.

 The performance of the system is acceptable

if the measurement system response is within

 5 percent of the

value obtained in Section 5.1 for the high range calibration gas.

Conduct a system check before and after each test run.

5.5

 Analysis Audit.

 Immediately before each test analyze an

audit cylinder as described in Section 5.2.

 The analysis audit

must agree with the audit cylinder concentration within 10

percent.

6.

 NOMENCLATURE

area of NDO i,

 ft2.

AN

 total area of all

NDO’s

 in the enclosure,

 ft2.

CA

 actual concentration of the dilution check gas, ppm

propane.

119—648

187

C31

 corrected average Voc concentration of background

emissions at point

 i, ppm propane.

C3

 average background concentration, ppm propane.

CDH

 average measured concentration for the drift check

calibration

gas,

ppm

propane.

CDO

 average system drift check concentration for zero

concentration gas,

ppm

propane.

C3

actual

 concentration of the drift check calibration

gas, ppm propane.

C~

 uncorrected average background VOC concentration

measured at point

 i, ppm propane.

 uncorrected average VOC concentration measured at

point

j,

 ppm propane.

CM

 measured concentration of the dilution check gas,

ppm

propane.

DF

 dilution factor.

G

 total VOC content of captured emissions,

kg.

K1

 1.830 x 10_6 kg/(m3-ppm).

n

 number of measurement points.

 average effluent volumetric flow rate corrected to

standard conditions at captured emissions point

j,

m3/min.

T~

 total duration of capture efficiency sampling run,

mm.

7.

 CALCULATIONS

7.1

 Total VOC Captured Emissions.

G

~

C0~

~

 Tc K1

Eq.

1

7.2

 VOC Concentration of the Captured Emissions at Point

j.

CG.

DF

(C.

—

 CD0)

C3

Eq.

2

119—649

188

CD3

—

CDO

7.3

 Dilution Factor.

13?

 —CA—

Eq.

3

CM

7.4

 Background VOC Concentration at Point

i.

C31

(C1

—

 CDO)

C3

Eq.

4

CDH

—

CDO

7.5

 Average Background Concentration.

SC

A.

C3=’1

~

Eq.

5

nAN

NOTE:

 If the concentration at each point is within 20 percent

of

the average concentration of all points, the terms “At” and “AN”

may be deleted from Equation 4.

Procedure F.2

—

 Fugitive VOC Emissions from Building Enclosures

1.

 INTRODUCTION

1.1

 Applicability.

 This procedure is applicable for determining

the fugitive volatile organic compounds (VOC)

 emissions 1rom a

building enclosure (BE).

 It is intended to be used as a segment

in the development of liquid/gas or gas/gas protocols for

determining VOC capture efficiency

 (CE) for surface coating and

printing operations.

1.2

 Principle.

 The total amount of fugitive VOC emissions

 (FB)

from the BE is calculated as the sum of the products of the VOC

content

 (CF.)

 of each fugitive emissions point,

 its flow rate

and ~ime

 (TF).

1.3

 Measurement Uncertainty.

 The measurement uncertainties are

estimated for each fugitive emissions point as follows:

±5.0percent and CFj

 ±5.0percent.

 Based on these numbers,

the

probable uncertainty for FB is estimated at about ±11.2percent.

1.4

 Sampling Requirements.

 A capture efficiency test shall

consist of at

 least three sampling runs.

 The sampling time for

each run should be at least

 8 hours,

 unless otherwise approved.

1.5

 Notes.

 Because this procedure is often applied in highly

explosive areas,

 caution and care should be exercised in choosing

119—650

189

appropriate equipment and installing and using the equipment.

Mention of trade names or company products does not constitute

endorsement.

 All gas concentrations

 (percent,

 ppm) are by

volume, unless otherwise noted.

2.

 APPARATUS AND REAGENTS

2.1

 Gas VOC Concentration.

 A schematic of the measurement

system is shown in Figure

1.

The

main components are described

below:

2.1.1

 Sample Probe.

 Stainless steel,

 or equivalent.

 The probe

shall be heated to prevent VOC condensation.

2.1.2

 Calibration Valve Assembly.

 Three-way valve assembly at

the outlet of sample probe to direct the zero and calibration

gases to the analyzer.

 Other methods,

 such as quick—connect

lines,

 to route calibration gases to the outlet of the sample

probe are acceptable.

2.1.3

 Sample Line.

 Stainless steel or Teflon tubing to

transport the sample gas to the analyzer.

 The sample line must

be heated to prevent condensation.

2.1.4

 Sample Pump.

 A leak-free pump,

 to pull the sample gas

through the system at a flow rate sufficient to minimize the

response time of the measurement system.

 The components of the

pump that contact the gas streamshail be constructed of stainless

steel or Teflon.

 The sample pump must be heated to prevent

condensation.

2.1.5

 Sample Flow Rate Control.

 A sample flow rate control

valve and rotameter,

 or equivalent,

 to maintain a constant

 sampling rate within 10 percent.

 The flow rate control valve and

rotameter must be heated to prevent condensation.

 A control

valve may also be located on the sample pump bypass loop to

assist in controlling the sample pressure and flow rate.

2.1.6

 Sample Gas Manifold.

 Capable of diverting a portion of

the sample gas stream to the flame ionization analyzer (FIA),

and

the remainder to the bypass discharge vent.

 The manifold

components shall be constructed of stainless steel or Teflon.

If

emissions are to be measured at multiple locations,

the

measurement system shall be designed to use separate sampling

probes,

 lines, and pumps for each measurement location and a

common sample gas manifold and FIA.

 The sample gas manifold must

be heated to prevent condensation.

2.1.7

 Organic Concentration Analyzer.

 An FIA with a span value

of 1.5 times the expected concentration as propane; however,

other span values may be used if it can be demonstrated that they

would provide more accurate measurements.

 The system shall

be

119—651

190

capable of meeting or exceeding the following specifications:

2.1.7.1

Zero

Drift.

Less

than

±3.0 percent

the

span

value.

2.1.7.2

 Calibration Drift.

 Less than ±3.0percent of the span

value.

2.1.7.3

 Calibration Error.

 Less than ±5.0percent of the

calibration

gas

value.

2.1.7.4

 Response Time.

 Less than 30 seconds.

2.1.8

 Integrator/Data Acquisition System.

 An analog or digital

device or computerized data acquisition system used to integrate

the FIA response or compute the average response and record

measurement data.

 The minimum data sampling frequency for

computing average or integrated values

 is one measurement value

every 5 seconds.

 The device shall be capable of recording

average values at least once per minute.

2.1.9

 Calibration and Other Gases.

 Gases used

 for calibration,

fuel,

 and combustion air

 (if required) are contained in

compressed gas cylinders.

 All calibration gases shall

be

traceable to NIST standards and shall be certified by the

manufacturer to ±1percent of the tag value.

 Additionally,

the

manufacturer of the cylinder should provide a recommended shelf

life for each calibration gas cylinder over which the

concentration does not change more than ±2percent from the

certified value.

 For calibration gas values not generally

available, alternative methods

 for preparing calibration gas

mixtures, such as dilution systems, may be used with prior

approval.

2.1.9.1

 Fuel.

 A 40 percent H2/60 percent He or 40 percent H2/60

percent N2 gas mixture is recommended to avoid an oxygen

synergism effect that reportedly occurs when oxygen concentration

varies significantly from a mean value.

2.1.9.2

 Carrier Gas.

 High purity air with less than 1 ppm of

organic material

 (propane or carbon equivalent)

 or less than 0.1

percent of the span value, whichever is greater.

2.1.9.3

 FIA Linearity Calibration Gases.

 Low-, mid-,

and

high-range gas mixture standards with nominal propane

concentrations

20—30,

45—55,

and

70-80

percent

the

span

value

 in air, respectively.

 Other calibration values and other

span values may be used if it can be shown that more accurate

measurements would be achieved.

2.1.10

 Particulate Filter.

 An in-stack or an out-of—stack glass

fiber filter

 is recommended if exhaust gas particulate loading is

 119—652

191

significant.

 An out-of—stack filter must be heated to prevent

any condensation unless it can be demonstrated that no

condensation occurs.

2.2

 Fugitive Emissions Volumetric Flow Rate.

2.2.1

 Flow Direction Indicators.

 Any means of indicating inward

or outward flow,

 such as light plastic film or paper streamers,

smoke tubes,

 filaments, and sensory perception.

2.2.2

 Method

 2 or 2A Apparatus.

 For determining volumetric flow

rate.

 Anemometers or similar devices calibrated according to the

manufacturer’s instructions may be used when low velocities are

present.

 Vane anemometers

 (Young—maximum response propeller),

specialized pitots with electronic manometers

 (e.g.,

 Shortridge

Instruments Inc., Airdata Multimeter 860) are commercially

available with measurement thresholds of 15 and

 8 mpm

 (50 and

25 fpm),

 respectively.

2.2.3

 Method

 3 Apparatus and Reagents.

 For determining

molecular weight of the gas stream.

 An estimate of the molecular

weight of the gas stream may be used if it can be justified.

2.2.4

 Method

 4 Apparatus and Reagents.

 For determining moisture

content,

 if necessary.

3.

 DETERMINATION OF VOLUMETRIC FLOW RATE OF FUGITIVE EMISSIONS

3.1

 Preliminary Determinations.

 The purpose of this exercise is

to determine which exhaust points should be measured for

volumetric flow rates and VOC concentrations.

3.1.1

 Forced Draft Openings.

 Identify all forced draft

openings.

 Determine the volumetric flow rate according to

Method

2.

3.1.2

 NDO’s Exhaust Points.

 The NDO’s in the roof of

 a facility

are considered to be exhaust points.

 Determine volumetric flow

rate from these NDO’s.

 Divide the cross—sectional area according

to Method

 I using 12 equal areas.

 Use the appropriate velocity

measurement devices,

 e.g., propeller anemometers.

3.1.3

 Other NDO’s.

3.1.3.1

 This step is optional.

 Determine the exhaust flow rate,

including that of the control device,

 from the enclosure and the

intake air flow rate.

 If the exhaust flow rate divided by the

intake air flow rate is greater than 1.1,

 then all other NDO’s

are not considered to be significant exhaust points.

3.1.3.2

 If the option above

 is not taken,

 identify all other

NDO’s and other potential points through which fugitive emissions

119—653

192

may escape the enclosure.

Then use the following criteria to determine whether flow rates

and VOC concentrations need to be measured:

3.1.3.2.1

 Using the appropriate flow direction indicator,

determine the flow direction.

 An NDO with zero or inward flow is

not an exhaust point.

3.1.3.2.2

 Measure the outward volumetric flow rate from the

remainder of the NDO’s.

 If the collective flow rate is

2

percent, or less, of the flow rate from Sections 3.1.1 and 3.1.2,

then these NDO’s, except those within two equivalent diameters

(based on NDO opening) from VOC sources, may be considered to be

non—exhaust points.

3.1.3.2.3

 If the percentage calculated in Section 3.1.3.2.2 is

greater than

 2 percent, those NDO’s (except those within two

equivalent diameters from VOC sources) whose volumetric flow rate

total

 2 percent of the flow rate from Sections 3.1.1 and 3.1.2

may be considered as non—exhaust points.

 All remaining NDO’s

shall be measured for volumetric flow rate and VOC concentrations

during the CE test.

3.1.3.2.4

 The tester may choose to measure VOC concentrations at

the forced exhaust points and the NDO’s.

 If the total VOC

emissions from the NDO’s are less than

 2 percent of the emissions

from the forced draft and roof NDO’s, then these NDO’s may be

eliminated from further consideration.

3.2

 Determination of Flow Rates.

3.2.1

 Measure the volumetric flow rate at all locations

identified as exhaust points in Section 3.1.

 Divide each exhaust

opening into 9 equal areas for rectangular openings and

 8 for

circular openings.

3.2.2

 Measure the velocity at each site at least once every hour

during each sampling run using Method

 2 or 2A,

 if applicable,

or

using the low velocity instruments in Section 2.2.2.

4.

 DETERMINATION OF VOC CONTENT OF FUGITIVE EMISSIONS

4.1

 Analysis Duration.

 Measure the VOC responses at each

fugitive emission point during the entire test run or,

if

applicable,

 while the process is operating.

 If there are

multiple emissions locations,

 design a sampling system to allow a

single FIA to be used to determine the VOC responses at all

sampling locations.

4.2

 Gas VOC Concentration.

4.2.1

 Assemble the sample train as shown in Figure

1.

 Calibrate

119—654

193

the FIA and conduct a system check according to the procedures in

Sections 5.1 and 5.3, respectively.

4.2.2

 Install the sample probe so that the probe is centrally

located in the stack, pipe,

 or duct, and is sealed

tightly

 at the

stack port connection.

4.2.3

 Inject zero gas at the calibration valve assembly.

 Allow

the measurement system response to reach zero.

 Measure the

system response time as the time required for the system to reach

the effluent concentration after the calibration valve has been

returned to the effluent sampling position.

4.2.4

 Conduct a system check before and a system drift check

after each sampling run according to the procedures in Sections

 5.2 and 5.3.

 If the drift check following a run indicates

unacceptable performance, the run is not valid.

 The tester may

elect to perform drift checks during the run not to exceed one

drift check per hour.

4.2.5

 Verify that the sample lines,

 filter, and pump

temperatures are 120

±50C

4.2.6

 Begin sampling at the start of the test period and

continue to sample during the entire run.

 Record the starting

and ending times and any required process information as

appropriate.

 If multiple emission locations are sampled using a

single FIA, sample at each location for the same amount of time

(e.g.,

 2 minutes)

 and continue to switch from one location to

another for the entire test run.

 Be sure that total sampling

time at each location is the same at the end of the test run.

Collect at least

 4 separate measurements from each sample point

during each hour of testing.

 Disregard the response measurements

at each sampling location until two times the response time of

the measurement system has elapsed.

 Continue sampling for at

least

 1 minute and record the concentration measurements.

4.3

 Alternative Procedure

 The direct interface sampling and

analysis procedure described in Section 7.2 of Method

 18 may be

used to determine the gas VOC concentration.

 The system must be

 designed to collect and analyze at least one sample every 10

minutes.

5.

 CALIBRATION AND QUALITY ASSURANCE

5.1

 FIA Calibration and Linearity Check.

 Make necessary

adjustments to the air and fuel supplies for the FIA and ignite

the burner.

 Allow the FIA to warm up for the period recommended

by the manufacturer.

 Inject a calibration gas into the

measurement system and adjust the back-pressure regulator to the

value required to achieve the flow rates specified by the

119—655

194

manufacturer.

 Inject the zero— and the high—range calibration

gases and adjust the analyzer caLibration to provide the proper

responses.

 Inject the low— and mid—range gases and record the

responses of the measurement system.

 The calibration and

linearity of the system are acceptable if the responses for all

four gases are within

 5 percent of the respective gas values.

If

the performance of the system is not acceptable, repair or adjust

the system and repeat the linearity check.

 Conduct

 a calibration

and linearity check after assembling the analysis system and

after a major change is made to the system.

5.2

 Systems Drift Checks.

 Select the calibration gas that most

closely approximates the concentration of the captured emissions

for conducting the drift checks.

 Introduce the zero and

calibration gas at the calibration valve assembly and verify that

the appropriate gas flow rate and pressure are present at the

FIA.

 Record the measurement system responses to the zero and

calibration gases.

 The performance of the system is acceptable

if the difference between the drift check measurement and the

value obtained in Section 5.1 is less than 3 -percent of the span

value.

 Conduct a system drift check at the end of each run.

5.3

 System Check.

 Inject the high range calibration gas at the

inlet of the sampling probe and record the response.

The

performance of the system is acceptable if the measurement system

response is within

 5 percent of the value obtained in Section

5.1

for the high range calibration gas.

 Conduct a system check

before each test run.

5.4

 Analysis Audit.

 Immediately before each test analyze an

audit cylinder as described in Section 5.2.

 The analysis audit

must agree with the audit cylinder concentration within 10

percent.

NOMENCLATURE

CDH

average

measured

concentration

for

the

drift

check

calibration gas, ppm propane.

CDO

 average system drift check concentration for zero

concentration gas, ppm propane.

CFj

 corrected average VOC concentration of fugitive

emissions at point

j,

ppm propane.

C3

 actual concentration of the drift check calibration

gas,

ppm

propane.

 uncorrected average VOC concentration measured at point

j,

ppm propane.

119—656

195

FB

 total VOC content of fugitive emissions from the

building,

kg.

K1

 1.830 x io6 kg/(m3—ppm).

n

 number of measurement points.

 average effluent volumetric flow rate corrected to

standard conditions at fugitive emissions point

j,

m3/min.

TF

 total duration of capture efficiency sampling run, mm.

7.

 CALCULATIONS

7.1

 Total VOC Fugitive Emissions From the Building.

F3

~

~

 TF K1 Eq.

1

7.2

 VOC Concentration of the Fugitive Emissions at Point

j.

CFj

(C~

—

 CDO)

C3

Eq.

2

CDH

—

CDO

Procedure F.1

—

 Fugitive VOC Emissions from Temporary Enclosures

1.

 INTRODUCTION

1.1

 Applicability.

 This procedure is applicable for determining

the fugitive volatile organic compounds

 (VOC)

 emissions from a

temporary total enclosure (TTE).

 It is intended to be used as

a

segment in the development of liquid/gas or gas/gas protocols for

determining VOC capture efficiency

 (CE)

 for surface coating and

printing operations.

1.2

 Principle.

 The amount of fugitive VOC emissions

 (F) from

the TTE is calculated as the sum of the products of the VOC

content

 (CF.),

 the flow rate

(~F~)’

 and the sampling time

 (TF)

from each f~igitiveemissions point.

1.3

 Estimated Measurement Uncertainty.

 The measurement

uncertainties are estimated for each fugitive emission point as

follows:

~

±5~5

 percent and CF~

 ±5.0

percent.

 Based on

these numbers,

 the probable uncertainty for F is estimated at

about ±7•4percent.

1.4

 Sampling Requirements.

 A capture efficiency test shall

consist of at least three sampling runs.

 The sampling time for

119—657

196

each run should be at least

 8 hours, unless otherwise approved.

1.5

 Notes.

 Because this procedure is often applied in highly

explosive areas,

 caution and care should be exercised in choosing

appropriate equipment and installing and using the equipment.

Mention of trade names or company products does not constitute

endorsement.

 All gas concentrations

 (percent, ppm)

 are by

volume, unless otherwise noted.

2.

 APPARATUS

AND

REAGENTS

2.1

 Gas VOC Concentration.

 A schematic of the measurement

system is shown in Figure

1.

 The main components are described

below:

2.1.1

 Sample Probe.

 Stainless steel,

 or equivalent.

 The probe

shall be heated to prevent VOC condensation.

2.1.2

 Calibration Valve Assembly.

 Three-way valve assembly at

the outlet of sample probe to direct the zero and calibration

gases to the analyzer.

 Other methods,

 such as quick—connect

lines,

 to route calibration gases to the outlet of the sample

probe are acceptable.

2.1.3

 Sample Line.

 Stainless steel or Teflon tubing to

transport the sample gas to the analyzer.

 The sample line must

be heated to prevent condensation.

2.1.4

 Sample Pump.

 A leak-free pump,

 to pull the sample gas

through the system at a flow rate sufficient to minimize the

response time of themeasurement system.

 The components of the

pump that contact the gas stream shall be constructed of

stainless steel or Teflon.

 The sample pump must be heated to

prevent condensation.

2.1.5

 Sample Flow Rate Control.

 A sample flow rate control

valve and rotameter,

 or equivalent, to maintain a constant

sampling rate within 10 percent.

 The flow control valve and

rotameter must be heated to prevent condensation.

 A control

valve may also be located on the sample pump bypass loop to

assist in controlling the sample pressure and flow rate.

2.1.6

 Sample Gas Manifold.

 Capable of diverting a portion of

the sample gas stream to the flame ionization analyzer

 (FIA),

and

the remainder to the bypass discharge vent.

 The manifold

components shall be constructed of stainless steel or Teflon.

If

emissions are to be measured at multiple locations, the

measurement system shall be designed to use separate sampling

probes,

 lines,

 and pumps for each measurement location and a

common sample gas manifold and FIA.

 The sample gas manifold and

119—658

197

connecting lines to the FIA must be heated to prevent

 condensation.

2.1.7

 Organic Concentration Analyzer.

 An FIA with a span value

of 1.5 times the expected concentration as propane; however,

other span values may be used if it can be demonstrated that they

would provide more accurate measurements.

 The system shall be

capable of meeting or exceeding the following specifications:

2.1.7.1

 Zero Drift.

 Less than ±3.0percent of the span value.

2.1.7.2

 Calibration Drift.

 Less than ±3.0percent of the span

value.

2.1.7.3

 Calibration Error.

 Less than ±5.0percent of the

calibration gas value.

2.1.7.4

 Response Time.

 Less than 30 seconds.

2.1.8

 Integrator/Data Acquisition System.

 An analog or digital

device or computerized data acquisition system used to integrate

the FIA response or compute the average response and record

measurement data.

 The minimum data sampling frequency for

computing average or integrated values is one measurement value

every

 5 seconds.

 The device shall be capable of recording

average values at least once per minute.

2.1.9

 Calibration and Other Gases.

 Gases used for calibration,

fuel, and combustion air

 (if required) are contained in

compressed gas cylinders.

 All calibration gases shall be

traceable to NIST standards and shall be certified by the

manufacturer to ±1percent of the tag value.

 Additionally, the

 manufacturer of the cylinder should provide a recommended shelf

life for each calibration gas cylinder over which the

concentration does not change more than ±2percent from the

certified value.

 For calibration gas values notgenerally

available,

 alternative methods for preparing calibration gas

mixtures, such as dilution systems, may be used with prior

approval.

2.1.9.1

 Fuel.

 A 40 percent H2/60 percent He or 40 percent H2/60

percent N2 gas mixture is recommended to avoid an oxygen

synergism effect that reportedly occurs when oxygen concentration

varies significantly from a mean value.

2.1.9.2

 Carrier Gas.

 High purity air with less than

 1 ppm of

organic material

 (as propane or carbon equivalent)

 or less than

0.1 percent of the span value, whichever is greater.

2.1.9.3

 FIA Linearity Calibration Gases.

 Low—, mid-,

and

high—range gas mixture standards with nominal propane

119—659

198

concentrations of 20-30, 45-55, and 70-80 percent of the span

value

 in air, respectively.

 Other calibration values and other

span values may be used if

 it can be shown that more accurate

measurements would be achieved.

2.1.10

 Particulate Filter.

 An in—stack or an out-of-stack glass

fiber filter is recommended if exhaust gas particulate loading

is

significant.

 An out-of-stack filter must be heated to prevent

any condensation unless it can be demonstrated that no

condensation occurs.

2.2

 Fugitive Emissions Volumetric Flow Rate.

2.2.1

 Method

 2 or 2A Apparatus.

 For determining volumetric flow

rate.

2.2.2

 Method

 3 Apparatus and Reagents.

 For determining

molecular weight of the gas stream.

 An estimate of the molecular

weight of the gas stream may be used if it can be justified.

2.2.3

 Method

 4 Apparatus and Reagents.

 For determining moisture

content,

 if necessary.

2.3

 Temporary Total Enclosure.

 The criteria for designing a

TTE

are discussed in Procedure T.

3.

 DETERMINATION OF VOLUMETRIC FLOW RATE OF FUGITIVE EMISSIONS

3.1

 Locate all points where emissions are exhausted from the

TTE.

 Using Method

 1, determine the sampling points.

 Be sure to

check each site for cyclonic or swirling flow.

3.2

 Measure the velocity at each sampling site at least once

every hour during each sampling run using Method

 2 or 2A.

4.

 DETERMINATION OF VOC CONTENT OF FUGITIVE EMISSIONS

4.1

 Analysis Duration.

 Measure the VOC responses at each

fugitive emission point during the entire test run or,

if

applicable, while the process is operating.

 If there are

multiple emission locations,

 design a sampling system to allow

a

single FIA to be used to determine the VOC responses at all

sampling locations.

4.2

 Gas VOC Concentration.

4.2.1

 Assemble the sample train as shown in Figure

1.

 Calibrate

the FIA and conduct a system check according to the procedures in

Sections 5.1 and 5.3, respectively.

4.2.2

 Install the sample probe so that the probe is centrally

located in the stack,

 pipe, or duct,

 and is sealed tightly at the

119—660

199

stack port connection.

4.2.3

 Inject zero gas at the calibration valve assembly.

 Allow

the measurement system response to reach zero.

 Measure the

system response time as the time required for the system to

reach

the effluent concentration after the calibration valve has been

returned to the effluent sampling position.

4.2.4

 Conduct a system check before and a system drift check

after each sampling run according to the procedures in Sections

5.2 and 5.3.

If

the drift check following a run indicates

unacceptable performance, the run is not valid.

 The tester may

elect to perform system drift checks during the run not to exceed

one drift check per hour.

4.2.5

 Verify that the sample lines,

 filter, and pump

temperatures are 120 ±

SoC.

4.2.6

 Begin sampling at the start of the test period and

continue to sample during the entire run.

 Record the starting

and ending times and any required process information as

appropriate.

 If multiple emission locations are sampled using a

single FIA, sample at each location for the same amount of time

(e.g.,

 2 minutes) and continue to switch from one location to

another for the entire test run.

 Be sure that total sampling

time at each location is the same at the end of the test run.

Collect at least

4

separate measurements from each sample point

during each hour of testing.

 Disregard the response measurements

at each sampling location until two times the response time of

the measurement system has elapsed.

 Continue sampling for at

least

 1 minute and record the concentration measurements.

4.3

 Background Concentration.

4.3.1

 Determination of VOC Background Concentration.

4.3.1.1

 Locate all NDO’s of the TTE.

 A sampling point shall be

centrally located outside of the TTE at

 4 equivalent diameters

from each NDO,

 if possible.

 If there are more than

 6 NDO’s,

choose

 6 sampling points evenly spaced among the NDO’s.

4.3.1.2

 Assemble the sample train as shown in Figure 2.

Calibrate the FIA and conduct a system check according to the

 procedures in Sections

5..

 and 5.3.

4.3.1.3

 Position the probe at the sampling location.

4.3.1.4

 Determine the response time,

 conduct the system check

and sample according to the procedures described in Sections

4.2.3 to 4.2.6.

4.4

 Alternative Procedure.

 The direct interface sampling and

119—66 1

200

analysis procedure described in Section 7.2 of Method

18

may be

used to determine the gas VOC co~wentration. The system must be

designed to collect and analyze at least one sample every 10

minutes.

5.

 CALIBRATION AND QUALITY ASSURANCE

5.1

 FIA Calibration and Linearity Check.

 Make necessary

adjustments to the air and fuel supplies for the FIA and ignite

the burner.

 Allow the FIA to warm up for the period recommended

by the manufacturer.

 Inject a calibration gas into the

measurement system and adjust the back—pressure regulator to the

value required to achieve the flow rates specified by the

manufacturer.

 Inject the zero— and the high—range calibration

gases and adjust the analyzer calibration to provide the proper

responses.

 Inject the low— and mid—range gases and record the

responses of the measurement system.

 The calibration and

linearity of the system are acceptable if the responses for all

four gases are within

 5 percent of the respective gas values.

If

the performance of the system is not acceptable, repair or adjust

the system and repeat the linearity check.

 Conduct a calibration

and linearity check after assembling the analysis system and

after a major change is made to the system.

5.2

 Systems Drift Checks.

 Select the calibration gas

concentration that most closely approximates that of the fugitive

gas emissions to conduct the

 drift checks.

 Introduce the zero

and calibration gas at the calibration valve assembly and verify

that the appropriate gas flow rate and pressure are present at

the FIA.

 Record the measurement system responses to the zero and

calibration gases.

 The performance of the system is acceptable

if the difference between the drift check measurement and the

value obtained in Section 5.1

 is less than

 3 percent of the span

value.

 Conduct a system drift check at the end of each run.

5.3

 System Check.

 Inject the high range calibration gas at the

inlet of the sampling probe and record the response.

The

performance of the system is acceptable if the measurement system

response is within

 5 percent of the value obtained in Section 5.1

for the high range calibration gas.

 Conduct a system check

before each test run.

5.4

 Analysis Audit.

 Immediately before each test analyze an

audit cylinder as described in Section 5.2.

 The analysis audit

must agree with the audit cylinder concentration within 10

percent.

6.

 NOMENCLATURE

A1

 area of NDO

i,

 ft2.

119—662

201

AN

 total area of all NDO’s in the enclosure,

 ft2.

CBI

 corrected average VOC concentration of background

emissions at point

 i, ppm propane.

C3

 average background concentration, ppm propane.

CD3

 average measured concentration for the drift check

calibration gas, ppm propane.

CDQ

 average system drift check concentration for zero

concentration gas, ppm propane.

C?j

 corrected average VOC concentration of fugitive

emissions at point

j,

ppm propane.

C3

 actual concentration of the drift check calibration

gas, ppm propane.

C1

 uncorrected average background VOC concentration at

point

 i, ppm propane.

 uncorrected average VOC concentration measured at point

j,

ppm propane.

F

 total VOC content of fugitive emissions,

kg.

K1

 1.830 x lO_6 kg/(m3—ppm).

n

 number of measurement points.

 average effluent volumetric flow rate corrected to

standard conditions at fugitive emissions point

j,

m3/min.

TF

 total duration of fugitive emissions sampling run, mm.

7.

 CALCULATIONS

7.1

 Total VOC Fugitive Emissions.

F

 (CFj

C5)

~

TF

K1

Eq.

1

7.2

 VOC Concentration of the Fugitive Emissions at Point

j.

CFj

(C~

—

 CDO)

C3

Eq.

2

CDH

—

CD0

119—66

3

202

7.3

 Background VOC Concentration at Point

i.

C51

(C1

 CDO)

CH

Eq.

3

CDH

—

CD0

7.4

 Average Background Concentration.

n

S

 C.A.

i—i

CB

Eq.

5

nAN

NOTE:

If

the concentration at each point is within 20 percent of

the average concentration of all points, the terms “At” and

“AN”

may be deleted from Equation 4.

119—664

203

Procedure L

 VOC Input

1.

 INTRODUCTION

1.1

 Applicability.

 This procedure is applicable for determining

the input of volatile organic compounds

(VOC).

It

is intended

to

be used as a segment in the development of liquid/gas protocols

for determining VOC capture efficiency

 (CE)

 for surface coating

and printing operations.

1.2

 Principle.

 The amount of VOC introduced to the process

(L)

is the sum of the products of the weight

 (W) of each VOC

containing liquid

 (ink, paint,

 solvent, etc.) used and its VOC

content

 (V).

 A sample of each VOC containing liquid is analyzed

with a flame ionization analyzer

 (FIA) to determine V.

1.3

 Estimated Measurement Uncertainty.

 The measurement

uncertainties are estimated for each VOC containing liquid as

follows:

W

 ±2.0percent and V

 ±12.0percent.

 Based on these

numbers,

 the probable uncertainty for L is estimated at about

±12.2percent for each VOC containing liquid.

1.4

 Sampling Requirements.

 A capture efficiency test shall

consist of at least three sampling runs.

 The sampling time for

each run should be at least

 8 hours, unless otherwise approved.

1.5

 Notes.

 Because this procedure is often applied in highly

explosive areas,

 caution and care should be exercised in choosing

appropriate

equipment

and

installing

and

using

the

equipment.

Mention of trade names or company products does not constitute

endorsement.

 All gas concentrations (percent, ppm) are by

volume, unless otherwise noted.

2.

 APPARATUS

AND

REAGENTS

2.1

 Liquid Weight.

2.1.1

 Balances/Digital Scales.

 To weigh drums of VOC containing

liquids to within 0.2

lb.

2.1.2

 Volume Measurement Apparatus (Alternative).

 Volume

meters,

 flow meters, density measurement equipment,

 etc.,

as

needed to achieve same accuracy as direct weight measurements.

2.2

 VOC Content

 (Flame Ionization Analyzer Technique).

The

liquid sample analysis system is shown

 in Figures 1 and 2.

The

following equipment is required:

2.2.1

 Sample Collection Can.

 An appropriately sized metal can

to be used to collect VOC containing materials.

 The can must be

constructed in such a way that it can be grounded to the coating

container.

119—665

204

2.2.2

 Needle Valves.

 To control gas flow.

2.2.3

 Regulators.

 For carrier gas and calibration gas

cylinders.

2.2.4

 Tubing.

 Teflon or stainless steel tubing with diameters

and lengths determined by connection requirements of equipment.

The tubing between the sample oven outlet and the FIA shall be

heated to maintain a temperature of

 120 ±

5cC.

2.2.5

 Atmospheric Vent.

 A tee and 0- to 0.5—liter/mm

 rotameter

placed in the sampling line between the carrier gas cylinder and

the VOC sample vessel to release the excess carrier gas.

A

toggle valve placed between the tee and the rotameter facilitates

leak tests of the analysis system.

2.2.6

 Thermometer.

 Capable of measuring the temperature of the

hot water bath to within 1°C.

2.2.7

 Sample Oven.

 Heated enclosure, containing calibration gas

coil heaters, critical orifice,

 aspirator,

 and other liquid

 sample analysis components,

 capable of maintaining a temperature

of 120 ±5°C.

2.2.8

 Gas Coil Heaters.

 Sufficient lengths of stainless steel

or Teflon tubing to allow zero and calibration gases to be heated

to the sample oven temperature before entering the critical

orifice or aspirator.

2.2.9

 Water Bath.

 Capable of heating and maintaining a sample

vessel temperature of 100 ±5°C.

2.2.10

 Analytical Balance.

 To measure ±0.001g.

2.2.11

 Disposable Syringes.

 2—cc or 5—cc.

2.2.12

 Sample Vessel.

 Glass,

 40-ml septum vial.

 A separate

vessel

 is needed for each sample.

2.2.13

 Rubber Stopper.

 Two-hole stopper to acconuuodate 3.2-mm

(1/8-in.) Teflon tubing, appropriately sized to fit the opening

of the sample vessel.

 The rubber stopper should be wrapped in

Teflon tape to provide a tighter seal and to prevent any reaction

of the sample with the rubber stopper.

 Alternatively, any

leak-free closure fabricated of non—reactive materials and

accommodating the necessary tubing fittings may

be used.

2.2.14

 Critical Orifices.

 Calibrated critical orifices capable

of providing constant flow rates from 50 to 250 mi/mm

 at known

pressure drops.

 Sapphire orifice assemblies

 (available from

O’Keefe Controls Company) and glass capillary tubing have been

119—666

205

found

adequate

for

this

application.

2.2.15

 Vacuum Gauge.

 0- to

760-mm

 (0- to 30-in.) Hg U-Tube

manometer or vacuum gauge.

2.2.16

 Pressure Gauge.

 Bourdon gauge capable of measuring the

maximum air pressure at the aspirator inlet

 (e.g., 100 psig).

2.2.17

 Aspirator.

 A device capable of generating sufficient

vacuum at the sample vessel to create critical flow through the

calibrated orifice when sufficient air pressure is present at the

aspirator inlet.

 The aspirator must also provide sufficient

sample pressure to operate the FIA.

 The sample is also mixed

with the dilution gas within the aspirator.

2.2.18

 Soap Bubble Meter.

 Of an appropriate size to calibrate

the critical orifices in the system.

2.2.19

 Organic Concentration Analyzer.

 An-FIA with a span value

of 1.5 times the expected concentration as propane; however other

span values may be used if it can be demonstrated that they would

provide more accurate measurements.

 The system shall be capable

of meeting or exceeding the following specifications:

2.2.19.1

 Zero Drift.

 Less than ±3.0percent of the span value.

2.2.19.2

 Calibration Drift.

 Less than ±3.0

percent of span

value.

2.2.19.3

 Calibration Error.

 Less than ±5.0percent of the

calibration gas value.

2.2.20

 Integrator/Data Acquisition System.

 An analog or digital

device or computerized data acquisition system used to integrate

the FIA response or compute the average response and record

measurement

data.

The

minimum

data

sampling

frequency

for

computing

average

integrated

values

one

measurement

value

every 5 seconds.

 The device shall be capable of recording

average values at least once per minute.

2.2.21

 Chart Recorder (Optional).

 A chart recorder or similar

device

 is recommended to provide a continuous analog display of

the measurement results during the liquid sample analysis.

2.2.22

 Calibration and Other Gases.

 For calibration,

 fuel,

and

combustion air

 (if required) contained in compressed gas

cylinders.

 All calibration gases shall be traceable to NIST

standards and shall

 be certified by the manufacturer to ±1

percent of the tag value.

 Additionally, the manufacturer of the

cylinder should provide a recommended shelf life for each

calibration

gas

cylinder

over

which

the

concentration

does

not

change

than

±2 percent

from

the

certified

value.

For

119—66 7

206

calibration gas values not generally available, alternative

methods

for

preparing

calibration,

gas

mixtures,

such

dilution

systems, may be used with prior approval.

2.2.22.1

 Fuel.

 A 40 percent H2/60 percent He or 40 percent

H2/60 percent N2 gas mixture is recommended to avoid an oxygen

synergism

 effect thatreportedly occurs when oxygen

concentration

varies significantly from a mean value.

2.2.22.2

 Carrier Gas.

 High purity air with less than

 ppm of

organic material

 (as propane)

 or less than 0.1 percent of the

span

value,

whichever

greater.

2.2.22.3

 FIA Linearity Calibration Gases.

 Low—,

 mid—,

and

high—range gas mixture standards with nominal propane

concentrations of 20-30,

 45-55, and 70-80 percent of the span

value in air, respectively.

 Other calibration values and other

span values may be used if it can be shown that more accurate

 measurements would be achieved.

2.2.22.4

 System Calibration Gas.

 Gas mixture standard

containing propane in air, approximating the undiluted VOC

concentration expected for the liquid samples.

3.

 DETERMINATION OF LIQUID INPUT WEIGHT

3.1

 Weight Difference.

 Determine the amount of material

introduced to the process as the weight difference of the feed

material before and after each sampling run.

 In determining the

total VOC containing liquid usage, account for:

 (a) the initial

(beginning) VOC containing liquid mixture;

 (b) any solvent added

during

the

test

run;

(C)

 any coating added

during

the

test

run;

and

 (d) any residual VOC containing liquid mixture remaining at

the end of the sample run.

3.1.1

Identify

all

points

where

VOC

containing

liquids

are

introduced to the process.

 To obtain an accurate measurement of

VOC containing liquids,

 start with an empty fountain (if

applicable).

After

completing

the

run,

drain

the

liquid

the

fountain

back

into

the

liquid

drum

(if

possible),

and

weigh

the

drum

again.

Weigh

the

VOC

containing

liquids

±0.5 percent

the total weight

 (full)

 or ±0.1percent of the total weight of

VOC

containing

liquid

used

during

the

sample

run,

whichever

less.

 If the residual liquid cannot be returned to the drum,

drain the fountain into a preweighed empty drum to determine the

final

weight

the

liquid.

3.1.2

not

possible

measure

single

representative

mixture,

then

weigh

the

various

components

separately

(e.g.,

solvent is added during the sampling run, weigh the solvent

before

 it is added to the mixture).

 If a fresh drum of

VOC

119—668

207

containing liquid is needed during the run, then weigh both the

empty

drum

 and fresh drum.

3.2

 Volume Measurement

 (Alternative).

 If direct weight

measurements

are

not

feasible,

the

tester

may

use

volume

 meters

and flow rate meters

 (and density measurements) to determine the

weight

liquids

used

can

demonstrated

that

the

technique

produces

results

equivalent

the

direct

weight

measurements.

 If a single representative mixture cannot be

measured, measure the components separately.

4.

 DETERMINATION OF VOC CONTENT IN INPUT LIQUIDS

4.1

 Collection of Liquid Samples.

4.1.1

 Collect

100-ml

 larger sample of the VOC containing

liquid mixture at each application location at the beginning and

end of each test run.

 A separate sample should be taken of each

VOC containing liquid added to the application mixture during the

test run.

 If a fresh drum is needed during the sampling run,

then obtain a sample from the fresh drum.

4.1.2

 When collecting the sample, ground the sample container to

the coating drum.

 Fill the sample container as close to the rim

as possible to minimize the amount of headspace.

4.1.3

 After the sample is collected,

 seal the container so the

sample cannot leak out or evaporate.

4.1.4

Label

the

container

identify

clearly

the

contents.

4.2

 Liquid Sample VOC Content.

4.2.1

 Assemble the liquid VOC content analysis system as shown

in Figure

1.

4.2.2

Permanently

identify

all

the

critical

orifices

that

may

be used.

 Calibrate each critical orifice under the expected

operating conditions

 (i.e.,

 sample vacuum and temperature)

against a volume meter as described in Section 5.3.

4.2.3

Label

and

tare

the

sample

vessels

(including

the

 stoppers

and

caps)

and

the

syringes.

4.2.4

Install

empty

sample

vessel

and

perform

leak

test

the system.

 Close the carrier gas valve and atmospheric vent and

evacuate the sample vessel to 250 mm (10 in.) Hg absolute or less

using the aspirator.

 Close the toggle valve at the inlet to the

aspirator and observe the vacuum for at least one minute.

If

there is any change in the sample pressure, release the vacuum,

adjust or repair the apparatus as necessary and repeat the leak

119—669

208

test.

4.2.5

 Perform the analyzer calibration and linearity checks

according to the procedure in Section 5.1.

 Record the responses

each

the

calibration

gases

and

the

back—pressure

setting

the

FIA.

4.2.6

 Establish the appropriate dilution ratio by adjusting the

aspirator air supply or substituting critical orifices.

 Operate

the

aspirator

vacuum

least

(1

in.)

greater

than the vacuum necessary to achieve critical flow.

 Select the

dilution ratio so that the maximum response of the FIA to the

sample

does

not

exceed

the

high—range

calibration

gas.

4.2.7

 Perform system calibration checks at two levels by

introducing compressed gases at the inlet to the sample vessel

while the aspirator and dilution devices are operating.

 Perform

these checks using the carrier gas

 (zero concentration)

 and the

system calibration gas.

 If the response to the carrier gas

exceeds

±0.5 percent

span,

clean

 or repair the apparatus and

repeat the check.

 Adjust the dilution ratio as necessary to

 achieve the correct response to the upscale check,

 but do not

adjust the analyzer calibration.

 Record the identification of

the

orifice,

aspirator

air

supply

pressure,

FIA

back—pressure,

and the responses of the FIA to the carrier and system

calibration gases.

4.2.8

 After completing the abOve checks,

 inject the system

calibration gas for approximately 10 minutes.

 Time the exact

duration of the gas injection using a stopwatch.

 Determine the

area under the FIA response curve and calculate the system

response factor based on the sample gas flow rate,

gas

concentration, and the duration of the injection as compared to

the integrated response using Equations

 2 and 3.

4.2.9

 Verify that the sample oven and sample line temperatures

are 120

±50C

and that the water bath temperature is 100 ±5cC

4.2.10

Fill

tared

syringe

with

approximately

the

VOC

containing liquid and weigh it.

 Transfer the liquid to a tared

sample vessel.

 Plug the sample vessel to minimize sample loss.

Weigh the sample vessel containing the liquid to determine the

amount of sample actually received.

 Also,

 as a

quality

control

 check, weigh the empty syringe to determine the amount of

material

delivered.

The

two

coating

sample

weights

should

agree

within

±0.02 g.

not,

repeat

the

procedure

until

acceptable

sample is obtained.

4.2.11

 Connect the vessel to the analysis system.

 Adjust the

aspirator

supply

pressure

the

correct

value.

Open

the

valve

the

carrier

gas

supply

the

sample

vessel

and

adjust

119—6 70

209

provide

slight

excess

flow

the

atmospheric

vent.

soon

the

initial

response

the

FIA

begins

decrease,

immerse

the

sample

vessel

the

water

bath.

(Applying

heat

the

sample

vessel too soon may cause the FID response to exceed the

calibrated

range

the

instrument,

and

thus

invalidate

the

analysis.)

4.2.12

Continuously

measure

and

record

the

response

the

FIA

until

all

the

volatile

material

has

been

evaporated

from

the

sample

and

the

instrument

response

has

returned

the

baseline

(i.e.,

response

less

than

0.5

percent

the

span

value).

Observe

the

aspirator

supply

pressure,

FIA

back—pressure,

atmospheric

vent,

and

other

system

operating

parameters

during

the run; repeat the analysis procedure if any of these parameters

deviate from the values established during the system calibration

checks in Section 4.2.7.

 After each sample perform the drift

check

described

Section

5.2.

the

drift

check

results

are

acceptable,

 calculate the VOC content of the sample using the

equations in Section 7.

 Integrate the area under the FIA

response

curve,

ordetermine

the

average

concentration

response

and

the

duration

sample

 analysis.

5.

 CALIBRATION

AND

QUALITY

ASSURANCE

5.1

FIA

Calibration

and

Linearity

Check.

Make

necessary

adjustments to the air and fuel supplies for the FIA and ignite

the burner.

 Allow the FIA to warm up for the period recommended

the

manufacturer.

Inject

calibration

gas

into

the

measurement system and adjust the back—pressure regulator to the

value

required

achieve

the

flow

rates

specified

the

manufacturer.

 Inject the zero— and the high—range calibration

gases and adjust the analyzer calibration to provide the proper

responses.

Inject

the

low—

and

mid-range

gases

and

record

the

responses of the measurement system.

 The calibration and

linearity of the system are acceptable if the responses for all

four gases are within

 5 percent of the respective gas values.

If

the

performance

the

system

not

acceptable,

repair

adjust

the system and repeat the linearity check.

 Conduct

 a calibration

and linearity check after assembling the analysis system and

after a major change is made to the system.

5.2

Systems

Drift

Checks.

After

each

sample,

repeat

the

system

calibration

checks

Section

4.2.7

before

any

adjustments

the

FIA

measurement

system

are

made.

the

zero

calibration

drift

exceeds

±3percent

the

span

value,

discard

the

result

and

repeat

the

analysis.

5.3

Critical

Orifice

Calibration.

5.3.1

 Each critical orifice must be calibrated at the specific

operating

conditions

that

will

used.

Therefore,

assemble

119—67

210

all components of the liquid sample analysis system as shown

in

Figure

stopwatch

also

required.

5.3.2

 Turn on the sample oven,

 sample line, and water bath

heaters and allow the system to reach the proper operating

temperature.

Adjust

the

aspirator

vacuum

380

mum

(15

in.)

vacuum.

Measure

the

time

required

for

one

soap

bubble

move

a known distance and record barometric pressure.

5.3.3

 Repeat the calibration procedure at a vacuum of 406

mm

(16

in.) Hg and at 25-mm

 (1-in.) Hg intervals until three consecutive

determinations provide the same flow rate.

 Calculate the

critical

flow

rate

for

the

orifice

mul/min

standard

conditions.

Record

the

vacuum

necessary

achieve

critical

flow.

6.

 NOMENCLATURE

 area under the response curve

the

liquid

sample,

area

count.

A3

 area under the response curve of the calibration gas,

area

count.

C~

 actual concentration of system calibration gas, ppm

propane.

 1.830

10~ g/(ml—ppm).

L

 total VOC content of liquid input,

kg.

ML

 mass of liquid sample delivered to the sample vessel,

g.

flow

rate

through

critical

orifice,

ml/min.

RF

 liquid analysis system response factor, g/area count.

total

gas

injection

time

for

system

calibration

gas

during

integrator

calibration,

mm.

VFj

 final VOC fraction of VOC containing liquid

j.

V~

 initial VOC fraction of VOC containing liquid

j.

VAj

 VOC fraction of VOC containing liquid

j

added during

the run.

V

 VOC fraction of liquid sample.

WFj

 weight of VOC containing liquid

j

remaining at end of

119—672

211

the run, kg.

W1~

 weight of VOC containing liquid

j

at beginning of the

run, kg.

WAj

 weight of VOC containing liquid

j

 added during the run,

kg.

119—673

212

7.

 CALCULATIONS

7.1

Total

VOC

Content

the

Input

VOC

Containing

Liquid.

L

•~

 V1~W1~

z~5

~

~

S

 VA) W~

Eq.

1

7.2

 Liquid Sample Analysis System Response Factor for Systems

Using

Integrators,

Grams/Area

Counts.

Q~

g T~K

Eq.

A3

7.3

VOC

Content

 of the Liquid Sample.

V

Eq.

3

ML

Procedure

—

 Criteria for and Verification of a Permanent

Temporary

Total

Enclosure

1.

 INTRODUCTION

1.1

 Applicability.

 This procedure is used to determine whether

 a permanent or temporary enclosure meets the criteria of a total

enclosure.

1.2

Principle.

enclosure

evaluated

against

set

criteria.

 If the criteria are met and if all the exhaust gases

are ducted to a control device, then the volatile organic

compounds

 (VOC)

 capture efficiency

 (CE)

 is assumed to be 100

percent

and

need

not

measured.

However,

part

the

exhaust

gas

stream

not

ducted

control

device,

 CE must be

determined.

2.

 DEFINITIONS

2.1

Natural

Draft

Opening

(NDO)

Any

permanent opening in the

enclosure that remains open during operation of the facility and

is not connected to a duct in which a fan is installed.

2.2

 Permanent Total Enclosure (PTE)

—-

 A permanently installed

enclosure that completely surrounds a source of

emissions

such

that all VOC emissions are captured and contained for discharge

through a control device.

2.3

Temporary

Total

Enclosure

(TTE)

 A temporarily

installed

enclosure

that

completely

surrounds

source

emissions

such

that all VOC emissions are captured and contained for discharge

119—674

213

through ducts that allow for the accurate measurement of VOC

rates.

3.

 CRITERIA OF A

TEMPORARY

TOTAL

ENCLOSURE

3.1

 Any NDO shall be at least

 4 equivalent opening diameters

from each VOC emitting

point.

3.2

 Any exhaust point from the enclosure shall be at least

4

equivalent duct or hood diameters from each NDO.

3.3

 The total area of all NDO’s shall not exceed

 5 percent of

the surface area of the enclosure’s four walls,

 floor,

and

ceiling.

3.4

 The average facial velocity

 (FV)

 of air through all NDO’s

shall be at least 3,600

 mu/hr

 (200 fpm).

 The direction of air

through all NDO’s shall be into the enclosure.

3.5

 All access doors and windows whose areas are not included

in

Section 3.3 and are not included in the calculation in Section

3.4

shall

closed

during

routine

operation

the

process.

4.

 CRITERIA OF A PERMANENT TOTAL ENCLOSURE

4.1

 Same as Sections 3.1 and 3.3

—

3.5.

4.2

 All VOC emissions must be captured and contained for

discharge

through

control

device.

5.

 PROCEDURE

5.1

 Determine the equivalent diameters of the NDO’s and

determine the distances from each VOC emitting point to all

NDO’s.

 Determine the equivalent diameter of each exhaust duct or

hood and its distance to all NDO’s.

 Calculate the distances in

terms of equivalent diameters.

 The number of equivalent

diameters shall be at least

4.

5.2

 Measure the total area

 (At)

 of the enclosure and the total

area

 (AN)

 all. NDO’s of the enclosure.

 Calculate the NDO to

enclosure

area

ratio

(NEAR)

follows:

NEAR

 AN/At

The NEAR must be

0.05.

5.3

 Measure the volumetric flow rate, corrected to standard

conditions,

each gas stream exiting the enclosure through an exhaust duct

or hood using EPA Method

2.

 In some cases

 (e.g., when the

119—6 75

214

building is the enclosure),

 it may be necessary to measure the

volumetric flow rate,

 corrected to standard conditions,

0f

each

gas stream entering the enclosure through a forced makeup air

duct using Method

2.

 Calculate FV using the following equation:

FV

(Q0

Q1/

AN

where:

Q0

 the sum of the volumetric flow from all gas streams

exiting the enclosure through an exhaust duct or

hood.

Q1

 the sum of the volumetric flow from all gas streams

into

the

enclosure

through

forced

makeup

air

duct;

zero,

 if there is no forced makeup air into the

enclosure.

AN

 total area of all NDO’s in enclosure.

The FV shall be at least 3,600 m/hr (200 fpm).

5.4

 Verify that the direction of air flow through all NDO’s

is

inward.

 Use streamers,

 smoke tubes, tracer gases,

 etc.

 Strips

of plastic wrapping film have been found to be effective.

Monitor the direction of air flow at intervals of at least 10

minutes for at least

 1 hour.

6.

 QUALITY ASSURANCE

6.1

 The success of this protocol lies in designing the TTE to

simulate the conditions that exist without the TTE,

 i.e.,

the

effect of the TTE

 on the normal flow patterns around the affected

facility

the

amount

 fugitive VOC emissions should be

minimal.

 The TTE must enclose the application stations, coating

reservoirs,

 and all areas from the application station to the

oven.

 The oven does not have to be enclosed if it is under

negative

pressure.

The

NDO’S

 the temporary enclosure and a

fugitive

exhaust

fan

must

properly

sized

and

placed.

6.2.

 Estimate the ventilation rate of the TTE that best

simulates the conditions that exist without the TTE,

 i.e., the

effect of the TTE on the normal flow patterns around the affected

facility or the amount of fugitive VOC emissions should be

minimal.

 Figure

1

 may be used as an aid.

 Measure the

concentration

 (CG) and flow rate

 of the captured gas stream,

specify a safe concentration

 (Ce)

 for the fugitive gas stream,

estimate the CE, and then use the plot in Figure 1 to determine

 the volumetric flowrate of the fugitive gas stream

(Q~).

A

fugitive VOC emission exhaust fan that has a variable flow

control is desirable.

119—676

215

6.2.1

 Monitor the concentration of VOC into the capture device

without the TTE.

 To minimize the effect of temporal variation on

the captured emissions, the baseline measurement should be made

over as long a time period as practical.

 However, the process

conditions must be the same for the measurement in Section 6.2.3

as they are for this baseline measurement.

 This may require

short measuring times for this quality control check before and

after the construction of the TTE.

6.2.2

After

 the TTE is constructed, monitor the VOC

concentration inside the TTE.

 This concentration shall not

continue to increase and must not exceed the safe level according

to OSHA requirements for permissible exposure limits.

An

increase in VOC concentration indicates poor TTE design or poor

capture efficiency.

6.2.3

 Monitor the concentration of VOC into the capture device

with the TTE.

 To limit the effect of the TTE on the process, the

VOC concentration with and without the TTE must be within ±10

percent.

 If the measurements do not agree,

 adjust the

ventilation rate from the TTE until they agree within 10 percent.

119—677

216

APPENDIX C

REFERENCE

METHODS

AND

PROCEDURES

Introduction

This Appendix presents the reference methods and procedures

required

for

implementing

Reasonably

Available

Control

Technology

(RACT).

 Methods and procedures are identified for two types

of

ACT implementation:

a) Determination of VOC destruction efficiency for evaluating

compliance with the 98 weight percent VOC reduction or 20 ppmv

emission limit specified in Sections 215.520 through 215.527;

and

b) Determination of offgas flowrate, hourly emissions and stream

net heating value for calculating TRE.

All reference methods identified in this

 Appendix refer to the

reference

methods

specified

 40 CFR 60, Appendix A,

incorporated by reference in Section 215.105.

VOC

DESTRUCTION

EFFICIENCY

DETERMINATION

The following reference methods and procedures are required for

determining compliance with the percent destruction efficiency

specified in Sections 215.520 through 215.527.

a) Reference Method

 1 or 1A for selection of the sampling site.

The

control

device

inlet

sampling

site

for

determination

vent stream molar composition or total organic compound

destruction efficiency shall be prior to the inlet of any

control device and after all recovery devices.

b) Reference Methods

2,

2A,

 2C or 2D for determination of the

volumetric flowrate.

c) Reference Method

 3 to measure oxygen concentration of the air

dilution correction.

 The emission sample shall be corrected

to

 3 percent oxygen.

d) Reference Method

 18 to determine the concentration of total

organic compounds (minus methane and ethane)

 in the control

device outlet and total organic compound reduction efficiency

of the control device.

TRE

DETERMINATION

The following reference methods and procedures are required for

determining the offgas flowrate, hourly emissions,

 and the net

heating value of the gas combusted to calculate the vent stream

TRE.

119—678

217

Reference

Method

 or 1A for selection of the sampling site.

The

sampling

site

for

the

vent

stream

flowrate

and

molar

composition determination prescribed in

 (b) and

(c)

shall

 prior to the inlet of any combustion device, prior to any

post-reactor dilution of the stream with air and prior to

any

post-reactor introduction of halogenated compounds into the

vent stream.

 Subject to the preceding restrictions on the

sampling site,

 it shall be after the final recovery device.

If any gas stream other than the air oxidation vent stream

is

normally conducted through the recovery system of the affected

facility,

such

stream

shall

rerouted

turned

off

while

the vent stream is sampled, but shall be routed normally prior

the

measuring

the

initial

value

the

monitored

parameters for determining compliance with the recommended

PACT.

 If the air oxidation vent stream is normally routed

through any equipment which is not a part of the air oxidation

process as defined in 35 Ill.

 Admn.

 Code 211.122,

 such

equipment shall be bypassed by the vent stream while the vent

stream is sampled, but shall not be bypassed during the

measurement of the initial value of the monitored parameters

for determining compliance with Subpart V.

The

molar

composition

the

vent

 stream shall be determined

 using the following methods:

1)

 Reference Method

 18 to measure the concentration of all

organics,

 including those containing halogens, unless a

significant portion of the compounds of interest are

polymeric

 (high molecular

 weight),

can

polymerize

before

analysis or have low vapor pressures,

 in which case

Reference Method 25(a)

 shall be used.

2)

 ASTM D1946-67

 (reapproved 1977), incorporated by reference

in Section 215.105, to measure the concentration of carbon

monoxide and hydrogen.

3)

 Reference Method

 4 to measure the content of water vapor,

necessary.

The

volumetric

flowrate

shall

determined

using

 Reference

Method 2,

2A,

 2C or 2D,

 as appropriate.

d) The net heating value of the vent stream shall be calculated

using the following equation:

n

H=K

CiHi

i=l

119—67 9

218

Where:

H

 Net heating value of the sample,

 MJ/scm, where the

net

enthalpy per mole of offgas

 is based on combu-stion at

25°Cand 760 mm Hg, but the standard temperature for

determining the volume corresponding to one mole is

20°C,as in the definition of F

 (vent stream flowrate)

below.

K

 Constant,

 1.740 x l0”~ (1/ppm)

 (mole/scm) (MJ/kcal)

where standard temperature for mole/scm is 20°C.

Ci

 Concentration of sample component i, reported on a

wet

basis,

 in ppm, as measured by Reference Method 18 or

ASTM Dl946-67 (reapproved 1977), incorporated by

reference

 in Section 215.105.

Hi

 Net heat of combustion of sample component

i,

kcal/mole based on combustion at 25 C and 760

mm Hg.

If published values are not available or cannot be

calculated,

 the heats of combustion of vent stream

components are required to be determined using ASTM

D2382-76,

 incorporated by reference in Section

215.105.

e) The emission rate of total organic compounds in the process

vent stream shall be calculated using the following equation:

n

E=K

CiMi

i=1

Where:

E

 Emission rate of total organic compounds (minus

methane and ethane)

 in the sample in kg/hr.

K

 Constant 2.494 x lo_6

 (1/ppm)

 (mole/scm)

 (kg/g)

(min/hr), where standard temperature for

(mole/scm)

 is 20°C.

Ni

 Molecular weight of sample component i

 (g/mole).

F

 Vent stream flowrate (scm/mm), at a standard

temperature of 20°C.

f) The total vent stream concentration (by volume)

 of compounds

containing halogens (ppmv, by compound) shall

 be summed from

the individual concentrations of compounds containing halogens

119—680

219

which were measured by Reference Method 18.

119—68 1

220

APPENDIX D

COEFFICIENTS FOR THE TOTAL RESOURCE

EFFECTIVENESS INDEX

 (TRE)

 EQUATION

This Appendix contains values for the total resource

effectiveness index

 (TRE)

 equation in Subpart V.

If a flow rate falls exactly on the boundary between the

indicated ranges, the operator shall use the row in which the

flow rate is maximum.

COEFFICIENTS FOR TRE EQUATION

FOR CHLORINATED PROCESS VENT STREAMS WITH

NET HEATING VALUE LESS

THAN

OR EQUAL TO 3.5 MJ/scm

FLOW RATE

 (scm/mm)

Mm.

 Max.

a

b

c

d

e

f

0.0

 13.5

 48.73

0.

0.

13.5

 700.

 42.35

0.

 0.0245

700.

 1400.

 84.38

0.

 0.0346

1400.2100.

 126.41

0.

 0.0424

2100.2800.

 168.44

0.

 0.0490

2800.3500.

 210.47

0.

 0.0548

COEFFICIENTS FOR TRE EQUATION

FOR CHLORINATED PROCESS VENT STREAMS WITH

NET HEATING VALUE GREATER

THAN

3.5

MJ/scm

FLOW RATE

(scm/mm)

Mm.

 Max.

b

d

e

f

0.

 0.404

 —0.1632

0.624

 0.404

 —0.1632

0.678

 0.404

 —0.1632

0.712

 0.404

 —0.1632

0.747

 0.404

 —0.1632

0.758

 0.404

 —0.1632

a

c

0.

 13.5

 47.76

0.

 —0.292

0.

0.

0.

13.5

 700.

 41.58

 0.605 —0.292

0.

0.

 0.0245

700.

 1400.

 82.84

 0.658 —0.292

0.

0.

 0.0346

 1400.2100.

 123.10

 0.691 —0.292

0.

0.

 0.0424

2100.2800.

 165.36

 0.715 —0.292

0.

0.

 0.0490

2800. 3500.

 206.62

 0.734 —0.292

0.

0.

 0.0548

119—6 82

221

COEFFICIENTS FOR TRE EQUATION

FOR NONCHLORINATED PROCESS VENT STREAMS WITH

NET HEATING VALUE LESS

THAN

OR EQUAL TO 0.48 NJ/scm

FLOW RATE

(scm/mm)

Mm.

 Max.

a

b

c

d

e

f

0.

 13.5

 19.05

0.

 0.113

 —0.214

0.

0.

13.5

 1350.

 16.61

 0.239

 0.113

 —0.214

0.

 0.0245

1350.2700.

 32.91

 0.260

 0.113

 —0.214

0.

 0.0346

2700.4050.

 49.21

 0.273

 0.113

 —0.214

0.

 0.0424

COEFFICIENTS FOR TRE EQUATION FOR NONCHLORINATED

PROCESS VENT STREAMS WITH NET HEATING VALUE

GREATER

THAN

0.48 AND LESS

THAN

OR

EQUAL TO 1.9 NJ/scm

FLOW RATE

(scm/mm)

Mm.

 Max.

a

b

c

d

e

f

0.

 13.5

 19.74

0.

 0.400

 —0.202

0.

0.

13.5 1350.

 18.30

 0.138

 0.400

 —0.202

0.

 0.0245

1350.2700.

 36.28

 0.150

 0.400

 —0.202

0.

 0.0346

2700.4050.

 54.26

 0.158

 0.400

 —0.202

0.

 0.0424

119—683

222

COEFFICIENTS FOR TRE EQUATION FOR NONCHLORINATED

PROCESS VENT STREAMS WITH NET HEATING VALUE

GREATER THAN

1.9

AND

LESS

THAN

OR

EQUAL TO 3.6 NJ

/

scm

FLOW PATE

a

b

c

d

e

f

COEFFICIENTS

FOR

TRE

EQUATION

FOR NONCHLORINATED PROCESS VENT STREAMS WITH

NET HEATING VALUE GREATER

THAN

3.6

MG/scm

TITLE 35:

 ENVIRONMENTAL PROTECTION

SUBTITLE B:

 AIR POLLUTION

CHAPTER

POLLUTION

CONTROL

BOARD

SUBCHAPTER

EMISSIONS

STANDARDS

AND

LIMITATIONS FOR STATIONARY SOURCES

PART

215

ORGANIC MATERIAL EMISSION STANDARDS

AND

LIMITATIONS

SUBPART

A:

 GENERAL

PROVISIONS

Section

215.100

 Introduction

a)

 This Part contains standards and limitations for

emissions of organic material from stationary sources

located

areas

other

than

the

Chicago

area

counties

of Cook.

 DuPage.

 Kane,

 Lake.

 McHenry1 and Will and the

Metro East area counties of Madison. Monroe.

 and St.

Clair.

 Standards and limitations applying

 in the

FLOW

RATE

(scm/mm)

Mm.

 Max.

.0

 13.5

 15.24

0.

 0.033

0.

0.

13.5

 1190.

 13.63

 0.157

 0.033

0.

0.

1190.2380.

26.95

0.171

0.033

2380.3570.

 40.27

 0.179

 0.033

0.

0.

(scm/mm)

Mm.

 Max.

a

b

c

d

e

0.

 13.5

13.5

 1190.

1190. 2380.

2380. 3570.

0.

0.0245

0.0346

0.0424

0.

0.0245

0.0346

0.0424

15.24

13. 63

26. 95

40.27

0.

0.

0.

0.

0.

0.

0.

0.

f

0. 0090

0.0090

0.0090

0.0090

0.

0. 0503

0. 0546

0. 0573

Chicago area are set forth in Part 218.

 Standards and

119—684

223

limitations applying in the Metro East area are set

forth in Part 219.

fl.

 Notwithstanding any other provision of this Part,

the provisions of this Part shall not apply to

sources located in the Chicago area counties of

Cook, DuPage,

 Kane,

 Lake, McHenrv and Will unless

the provisions of 35

 Ill. Adm. Code Part 218

applicable to such sources are voided or otherwise

made ineffective pursuant to Section 218.100 of

35

Ill.

 Adm. Code Part 218.

~j

 Notwithstanding any other provision of this Part,

the provisions of this Part shall not apply to

sources in the Metro East area counties of

Madison. Monroe and

 St. Clair unless the

provisions of 35

 Ill. Adm. Code Part 219

applicable to such sources are voided or otherwise

made ineffective pursuant to Section 219.100 of

35

Ill.

 Admu.

 Code Part 219.

b)

 Sources subject to this Part may be subject to the

following:

1)

 Permits required under

 35 Ill. Adm. Code 201;

2)

 Air quality standards under

 35 Ill.

 Adm. Code 243.

c)

 This Part is divided into Subparts which are grouped as

follows:

1)

 Subpart A:

 General provisions;

2)

 Subparts B

J:

 Emissions from equipment and

operations

common

than

one

industry;

3)

 Subparts K

—

N:

 Emissions from use of organic

material;

4)

 Subparts N

 end:

 Special rules for various

industry groups.

(Source:

 Amended at 15 Ill.

 Reg.

 effective

SUBPART Y:

 GASOLINE DISTRIBUTION

Section

215.581

Bulk

Gasoline

Plants

a)

 Subject to subsection

 (e), no person may cause or allow

 the transfer of gasoline from a delivery vessel into a

stationary storage tank located at a bulk gasoline

119—685

224

plant unless:

1)

 The delivery vessel and the stationary storage

tank are each equipped with a vapor collection

system that meets the requirements of subsection

(d) (4);

2)

 Each vapor collection system

is

operating;

3)

 The delivery vessel displays the appropriate

sticker pursuant to the requirements of Section

215.584(b)

or

 (d);

4)

 The pressure relief valve(s)

 on the stationary

storage tank and the delivery vessel are set to

release at no less than 0.7 psi or the highest

pressure allowed by state or local fire codes or

the guidelines of the National Fire Prevention

Association; and

5)

 The stationary storage tank is equipped with a

submerged loading pipe.

b)

 Subject to subsection

 (f), no person may cause or

allow

the transfer of gasoline from a stationary storage tank

located at a bulk gasoline plant into a delivery vessel

unless:

1)

 The requirements set forth

 in subsections

 (a) (1)

through

 (a) (4) are met; and

2)

 Equipment is available at the bulk gasoline plant

to provide for the submerged filling of the

delivery vessel or the delivery vessel is equipped

for bottom loading.

c)

 Subject to subsection

 (e), each owner of a stationary

storage tank located at a bulk gasoline plant shall:

1)

 Equip each stationary storage tank with a vapor

control system that meets the requirements of

subsection

(a)

or

 (b), whichever is applicable;

2)

 Provide instructions to the operator of the bulk

gasoline plant describing necessary maintenance

operations and procedures for prompt notification

of the owner in case of any malfunction of a vapor

control system; and

3)

 Repair, replace or modify any worn out or

malfunctioning component or element of design.

119—686

225

d)

 Subject to subsection

 (e), each operator of

 a bulk

gasoline plant shall:

1)

 Maintain and operate each vapor control system in

accordance with the owner’s instructions;

2)

 Promptly notify the owner of any scheduled

maintenance or malfunction requiring replacement

or repair of a major component of a vapor control

system; and

3)

 Maintain gauges, meters or other specified testing

 devices in proper working order;

4)

 Operate the bulk plant vapor collection system and

gasoline loading equipment in a manner that

prevents:

A)

 Gauge pressure from exceeding 18 inches of

water and vacuum from exceeding

 6 inches of

water, as measured as close as possible to

the vapor hose connection; and

B)

 A reading equal to or greater than 100

percent of the lower explosive limit

 (LEL

measured as propane) when tested

in

accordance

with

the

procedure

described

EPA

450/2—78-051

Appendix

and

C)

 Avoidable leaks of liquid during loading or

unloading operations.

5)

 Provide a pressure tap or equivalent on the bulk

plant vapor collection system in order to allow

the

 determination of compliance with

215.581(d)

(4) (A);

and

6)

 Within

 15 business days after discovery of the

leak

the

owner,

operator,

the

Agency,

repair

and retest a vapor collection system which exceeds

the

limits

subsection

(d) (4)

(A)

(B).

e)

 The requirements of subsections

 (a),

(c)

and

(d)

 shall

not

apply

to:

Any

stationary

storage

 tank

with

capacity

less than 575 gallons; or

2)

 Any bulk gasoline plant whose annual gasoline

throughput

 is less than 350,000 gallons as

averaged over the

 preceding three calendar years.

119—687

226

f)

 The requirements of subsection

(b)

 shall. only apply to

bulk gasoline plants:

1)

 That have an annual. gasoline throughput greater

than or equal to ~l,000,000gallons,

 as averaged

over the preceding three calendar years; and

2)

 That either distribute gasoline to gasoline

dispensing facilities subject to the requirements

of Section 215.583(a) (2),

 35 Ill.

 Ad2n.

 Code

218.583(b)

(2)

111.

Adm.

Code

219.583(a)

(2)

or that-rare -located in the following—counties:-

Boone, Cook,

 DuPagc, Kane,

 Lake,

 Madioon,

 Ncllenry,

Peoria, Rock Island,

St.

 Clair, Tazewell, Will or

Winnebago.

g)

 Bulk gasoline plants were required to take certain

actions to achieve compliance which are summarized in

Appendix C.

(Source:

Amended

Ill.

Reg.

_______________,

 effective

ORDERED.

I, Dorothy M. Gunn, Clerk of the Illinois Pollution Control

hereby

certi

that

the

above

Order

was

adopted

the

~‘Y~i—’

 day of

 1991, by a vote of

~‘

Ill-

 Control Board

119—688