ILLINOIS POLLUTION CONTROL BOARD
    March 17,
    1977
    IN THE MATTER OF
    TOTAL DISSOLVED SOLIDS
    )
    R75-6
    EFFLUENT STANDARD
    OPINION OF THE BOARD
    (by Mr.
    Dumelle):
    A petition for regulatory change was filed by the Village of
    Sauget on March 27,
    1975, proposing amendment to Rule 408(b)
    of
    Chapter
    3, Water Pollution Regulations.
    This Rule sets forth the
    effluent standard for total dissolved solids.
    Accompanying the
    proposal was
    a petition with 200 signatures.
    The proposal was published
    in Environmental Register #101,
    and hearings were held on September 23,
    1975 in Sauget and
    October
    3, 1975 in Chicago to receive testimony and comments
    regarding the proposal.
    An Economic Impact Study
    (IIEQ Docu-
    ment No.
    76/17) was submitted to the Board by the Institute On
    August 24,
    1976 pursuant to Section
    6 of the Act.
    Hearings to
    receive comments on this study
    (Exhibit 19)
    were held on November
    3,
    1976 in Chicago and December 17, 1976 in Peoria.
    All testimony,
    exhibits, and public comments included in the record of this
    proceeding have been considered by the Board in rendering a
    Uecision on the proposed regulation.
    The effluent standard in
    Rule
    408(b)
    requires that total
    dissolved solids
    in an effluent shall not increase more than 750 mg/i
    above background concentration levels unless caused by recycling
    or other pollution abatement practices, and at no time may
    they exceed a concentration of 3500 mg/i.
    This standard is
    discussed in the Board Opinion of January
    6, 1972
    (R70-8, R71-14,
    R71—20)
    ,
    supporting the effluent regulations.
    The proposal presented by the Village of Sauget in this
    proceeding R75—6
    is to exempt from the total dissolved solids
    effluent standard those sources that meet water quality standards
    for total dissolved solids in receiving waters to which they
    discharge.
    The argument stated in the petition and discussed
    further in testimony is that, although the technology
    is available
    to meet the effluent standards, such treatment is economically
    unreasonable.
    The petitioner also stated that the present
    25
    163

    —2—
    effluent standard discourages the use of water recycling techni-
    ques, because recycling results
    in increased concentrations of
    total dissolved solids
    in a smaller volume of effluent, which
    may then violate the standard.
    At the first hearing the petitioner requested that the
    original proposal be
    limited to apply only to discharges to the
    Mississippi River.
    The testimony was limited to the Village
    of Sauget treatment plant operation, the costs required for Sauget to
    install and operate treatment facilities
    to meet the present
    effluent standard,
    and the impact of the Sauget treatment plant
    total dissolved solids discharges on the water quality in the
    Mississippi River.
    Sauget Wastewater Treatment Plant
    At the time of the hearings in 1975 the Sauget plant
    provided primary treatment to approximately 15 million gallons
    per day
    (MGD)
    of waste stream, average dry weather flow.
    The
    wastes treated are 99
    industrial wastes from companies in
    Sauget.
    The waste stream had been steadily reduced from a
    1961 volume of
    38 MGD, and the industrial dischargers were
    committed to reducing flow to
    8 MGD in 1976.
    The reason for the flow reduction was to concentrate
    the wastes in the stream to make
    it easier to treat as well
    as to reduce costs for construction and operation of a new treatment
    facility.
    Such a facility was under construction at the Sauget
    plant in 1975, designed to provide secondary treatment by
    means of chemical waste treatment.
    The process includes
    lime neutralization followed by precipitation of metals through
    addition of polyelectrolyte and removal by sedimentation and
    filtration.
    This plant will discharge to the Mississippi River
    until a Metro East area regional treatment facility is completed,
    at which time it will discharge to that larger facility.
    In 1975 the Sauget treatment plant effluent contained
    3500-5500 mg/i total dissolved solids
    (Exhibit 5).
    The
    effluent from the new secondary treatment facility
    is expected
    to have
    a concentration of
    8000 ppm, without any actual increase
    in dissolved solids loading from industrial wastes.
    The increased
    concentration will result from flow reduction plus a contribution
    of 700-1000 mg/i from lime added during neutralization.
    The pro-
    jected total dissolved solids concentration in the discharge from
    the Metro East regional facility will be 3800 mg/i.
    Therefore none
    of the effluents will meet the 3500 mg/i standard.
    25-164

    —3—
    It
    is noted that the Village of Sauget’s total dissolved sglids
    measurements are obtained using an evaporation procedure at 103 C
    (R.
    30)
    ,
    whereas
    the Agency uses a procedure which evaporates
    at 180°C (R.
    236).
    The procedure used by Sauget will result
    in higher values,
    as much as
    50
    higher according to the
    Agency
    (F.
    222)
    ,
    because organics and water of hydration and
    occlusion will be retained in the residue which at the higher
    temperature would evaporate.
    A representative of Sauget testified that an Illinois
    EPA computer printout of source effluent data for 1972 through
    1974 showed that the Sauget plant was the only discharger
    to the
    Mississippi River in violation of the standard
    (R.
    47).
    The Agency
    could not verify which measurement procedure was used to obtain
    that data.
    There appears therefore to be some ambiguity
    in the
    effluent data presented in the record and in the present status
    of Sauqet regarding compliance with the effluent standard.
    However,
    when its secondary treatment plant is completed,
    its 8000 mg/i
    effluent will clearly be in violation of the standard, regardless
    of the measurement method used.
    Availability and Cost of Treatment Technolo~
    Four treatment processes are considered to be available to
    remove total dissolved solids from wastewater.
    These are reverse
    osmosis, electrodialysis, distillation, and ion exchange. The
    processes are described briefly on pages 4—6 of Exhibit
    1,
    and Dr. James Patterson also described them in his testimony
    (F.
    109-113).
    All four processes
    remove solids from the waste
    stream and concentrate them in a brine stream, which must be
    retreated or disposed of in an environmentally sound manner.
    The capital and operating costs involved with each of the
    four processes demonstrate that reverse osmosis
    is the most economical
    process, and
    it is also the smallest consumer of energy
    (F.
    115—
    118;
    Exhibit
    10, Table
    1).
    Dr. Patterson, consultant to Sauget,
    considered
    it to “represent a potential feasible process”
    (R.
    123).
    There are several interferences which can affect the reverse
    osmosis process, which thereby limit its applicability and
    increase
    its
    COStS.
    Reverse osmosis
    is susceptible
    to orqanic
    material
    in the wastewater which fouls the membranes,
    as well
    as to bacteria which degrade the membranes.
    Also, when the
    brine produced by the process becomes saturated with salts,
    they will precipitate on the membranes,
    causing irreparable damage.
    The first interferences require pretreatment of the wastewater
    with activated carbon, adding to the total costs.
    The second
    one limits the amount of concentration of salts and requires
    careful control of the system to prevent precipitation
    (F.
    123-
    125)
    25
    165

    —4—
    The flow diagram in Exhibit 11 is
    a conceptual design of
    the reverse osmosis process which would be needed to treat
    the Sauget secondary treatment plant effluent to meet the
    3500 mg/i standard.
    Only 5.6 MGD
    (69)
    of the 8.11 MGD flow
    is treated, resulting in 1.41 MGD brine stream as waste and
    4.19 MGD treated effluent which, when mixed with the remaining
    2.51 MGD
    (31)
    of secondary effluent will yield a 6.7
    MGD
    discharge which meets the required 3500 mg/i total dissolved
    solids.
    Pretreatment prior to reverse osmosis includes filtra-
    tion, pH adjustment,
    softening,
    and carbon adsorption.
    Total
    costs for the complete process, including waste
    brine disposal by deep well injection, were estimated to be
    $7.72 million capital and 5l.8~per 1000 gallon operating
    costs
    (Exhibit 10, Table
    9).
    These figures represent an
    87.9
    increase in total capital cost and 157
    increase in
    total operating costs for the new chemical treatment plant
    (F.
    144).
    The cost estimates in the Economic Impact Study
    (Exhibit 19)
    included the $7.72 million capital cost, but
    annual operating costs
    of $1.74 million
    (or 58.8’~per 1000
    gallon) were utilized instead of the Village of Sauget estimates.
    This higher estimate includes annualized capital cost as well
    as fuel consumption and labor.
    These costs for reverse osmosis
    with deep well injection for brine disposal were compared to
    costs anticipated using two other brine disposal methods.
    Treatment
    with deep well injection is shown to be by far the most economical
    method,
    though very expensive and possibly not an environmentally
    acceptable one.
    Impact of Sauget Effluent on Mississippi River Water Quality
    Water samples taken in 1974 from the Mississippi River
    just downstream from the Sauget outfall showed a maximum con-
    centration of
    368 mg/i total dissolved solids and a low reading
    of 324 mg/i
    (Exhibit 6)
    .
    Samples taken in 1975, also close
    to
    and. downstream from the outfall, yielded a high value of
    397 mg/i and a low of 262 mg/i.
    All of these values are well
    below the applicable water quality standard of 500 mg/i for
    water supply and
    food processing waters.
    Discharge from the new secondary treatment plant will
    have little or no effect on concentrations in the river, because
    the industrial waste loadings of dissolved solids will remain
    the same,
    though concentrated in a smaller waste stream.
    The
    only increase will be from the lime added during neutralization.
    If, on the other hand, these wastes were treated
    to meet the
    3500 mg/i effluent standard, the improvement in river water
    quality was estimated to be only
    1 mg/i total dissolved solids
    (Exhibit 19 p.
    121),
    reflecting the relatively small contribu-
    tion of this plant to total loadings in the Mississippi River.
    25
    166

    —5—
    Economic Impact of the Regulation
    Costs
    to Sauget calculated in the benefit cost analysis,
    as
    cited above, were $1.74 million per year for reverse osmosis
    with
    deep well injection of brine wastes,
    to meet the standard.
    These
    costs were allocated to the industries discharging into
    the treatment plant,
    and their economic response to their increased
    cost burden was predicted.
    The response involved a potential
    loss
    of 0-652
    jobs and possible price increases for their products of
    0—1.3.
    Long term loss of industry to the area was also pro-
    jected as
    a possible outcome.
    The total benefits resulting from a
    1 mg/i improvement in
    dissolved solids water quality in the Mississippi River were
    estimated to be $460 per year, resulting from reduction in
    corrosion damage to power—generating cooling systems and to
    residential household plumbing fixtures and appliances.
    The
    dissolved solids properties considered in the analysis were
    corrosiveness, effects on osmotic pressure, and hardness.
    Toxicity of individual constituents was not included.
    This
    regulation will have a slight economic impact on the people
    in Illinois using Mississippi River water, but the impacts
    resulting from compliance by Sauget with the effluent standard
    are found
    to be greater.
    Because the Village of Sauget
    is at this time the only
    discharger to the Mississippi in violation of the effluent
    standard,
    exempting sources on that river from the standard
    will result in minimal water quality impacts, as discussed
    above.
    Sources expected to exceed the 3500 mg/i level would
    be
    industrial processes discharging directly or plants such
    as
    the one
    in Sauget which treat wastewaters primarily from
    industrial operations.
    The water recycling efforts of such
    sources, both for resource conservation and to allow more
    effective treatment of hazardous waste constituents, are relevant
    considerations
    in this matter.
    When evaluated along with the
    costs
    to Sauget and environmental problems involved with treating
    total dissolved solids,
    as well as the minimal expected impacts
    on users of the Mississippi River, an exemption from the effluent
    standard is merited as long as the water quality standard for
    total dissolved solids
    is
    met.
    We are not satisfied, however, that there is enough
    information
    in the record on the remaining waters of the State
    to apply the amendment statewide.
    Dilution ratios and background
    dissolved solids concentrations vary widely for different receiving
    waters, which may affect the relative water quality impacts
    of
    individual point sources discharging into them.
    Discharge character-
    istics and control capabilities of those sources may also be relevant.
    Data presented for a number of rivers
    in Illinois
    show that
    some
    violations of the water quality standard already exist and that
    concentrations of total dissolved solids are increasing slowly
    25
    167

    —6—
    over time
    in the Mississippi and Illinois Rivers.
    These facts
    must be considered thoroughly before a statewide exemption could
    be allowed.
    A proposal to delete the total dissolved solids effluent
    standard from the
    Water Pollution Regulations
    is pending before
    the Board
    in R76-2l Effluent Standards Revision.
    Further considera-
    tion of
    the standard and submission of additional information
    regarding
    its merits will be possible in R76-2l, and the record
    of this proceeding R75-6 can be incorporated into the R76-2l
    record.
    Therefore,
    at this time an exemption from the effluent
    standard is allowed only for sources on the Mississippi River,
    while leaving open the proposal in R76-21 for continued delibera-
    tion on the merits of the statewide effluent standard for total
    dissolved solids.
    This Opinion constitutes the Board’s findings of fact
    and conclusions of
    law.
    I,
    Christan L. Moffett, Clerk of the
    Illinois Pollution Control
    Board, hereby certify the above Opinion w~sadopted
    on
    t-he
    /7~day
    of March,
    I
    971
    by
    d
    voLe
    of
    ____________________________
    Christan L. Moffett,
    rk
    Illinois Pollution C
    rol Board
    25

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