ILLINOIS POLLUTION CONTROL BOARD
November 18,
1994
IN THE MATTER OF:
)
15
ROP
PLAN
CONTROL MEASURES
)
FOR VOM EMISSIONS
-
PART VII:
)
R94—33
BATCH OPERATIONS:
)
(Rulemaking)
AMENDMENTS TO 35 ILL.
ADM.
)
CODE PARTS 211,
218
AND
219
)
Proposed Rule.
First Notice.
OPINION
AND
ORDER OF THE BOARD
(by R.C. Flemal):
On November 14,
1994,
the Illinois Environmental Protection
Agency
(Agency) filed this proposal for rulemaking.
The proposal
represents one part of Illinois’ submittal of a complete state
implementation plan
(SIP).
Section 182(b) (1)
of the Clean Air
Act
(42 U.S.C. 7511(b) (1))
requires all moderate and above ozone
nonattainment areas to achieve a 15
reduction of 1990 emissions
of volatile organic material
(VOM)
by 1996.
The Chicago and
Metro—East St. Louis areas are classified as “Severe” and
“Moderate” nonattainment for ozone, respectively, and are subject
to the 15
reduction requirement.
This proposal represents Part
VII of the rulemakings anticipated in the 15
Rate of Progress
Plan (“15
ROP Plan”).
The proposal seeks to amend 35 Ill. Adm.
Code 211, 218 and 219.
The proposed rulemaking would control VOM emissions from
chemical processes operating in a batch mode.
The proposed
amendments to Subpart V are intended to cover all batch
operations at sources identified by standard industrial
classification codes,
as defined in the 1987 edition of the
Standard Industrial Classification Manual, which manufacture as a
primary product or intermediate, any chemical identified by the
following:
plastic materials and resins
(SIC 2821),
pharmaceutical preparations
(2834), medicinal chemicals and
botanical production
(SIC 2833), gum and wood chemicals (SIC
2861),
cyclic crudes and intermediates
(SIC 2865), industrial
organic chemicals (SIC
2869)
and agricultural chemicals (SIC
2879).
The rulemaking is proposed for process vents associated
with batch or non—continuous chemical manufacturing operations.
Batch operations in the Chicago and Metro—East ozone
nonattainment areas,
as defined in 35 Iii. Adm. Code Parts 218
and 219, Sections 218.103 and 219.103, are subject to this
rulemaking.
All process vents associated with batch operations
at Stepan Company’s Milisdale manufacturing facility, Elwood,
Illinois,
a’re also subject to the proposal.
Today the Board acts to send this proposal to first notice
under the Illinois Administrative Procedure Act, but without
commenting on the merits of the proposal.
This proposal was filed pursuant to Section 28.5 of the
Environmental Protection Act
(Act)
as
a fast—track rulemaking
proceeding.
(415 ILCS 5/28.5
(1992).)
Section 28.5 requires the
Board to proceed with rulemaking under set time—frames.
The
Board has no discretion to adjust these time frames under any
circumstances.
The following schedule indicates the deadlines by
which the Board must act,
as provided in Section 28.5:
first notice
on or before November 29,
1994
first hearing
on or before January
8, 1995
second hearing
no later than 30 days after
the start of the first hearing
third hearing
no later than 14 days after
the start of the second
hearing
second notice
(if third hearing cancelled)
on or before March 24,
1995
(if third hearing held)
on or before April
13,
1995
final adoption and filing
21 days after receipt of JCAR
certificate of no objection
The Board notes that the above dates are the deadlines as
established by Section 28.5 and do not represent actual hearing
dates or filing dates.
While the schedule includes second and
third hearings, these hearings may be cancelled if unnecessary.
The Board will proceed in this matter as prescribed in Section
28.5 and discussed in the Board’s resolution.
(~
Clean Air Act
Rulemaking Procedures Pursuant to Section 28.5 of the
Environmental Protection Act, as Added By P.A. 87-1213,
(October
29,
1992 and December
3,
1992), RES 92—2.)
The Agency has filed a motion for waiver of requirements
with the proposal.
The Agency requests waiver of the following
requirements:
that the Agency submit the original and nine
copies of the entire regulatory proposal; that the Agency submit
an entire copy of the proposal to the Attorney General and the
Department of Energy and Natural Resources
(DENR); and that the
Agency submit copies of all documents upon which it relied.
The
Agency asks that it be permitted to file an original plus five
complete copies of the proposal and four partial copies.
A
partial copy includes the pleadings and the proposed rules, but
does not include the supporting exhibits.
The Attorney General
and DENR have agreed with the Agency that a copy of the proposal
need not be served upon them.
The Agency has provided the Board
with one copy of some of the documents on which it relied, and
notes that the other documents are readily accessible or already
in the Board’s possession.
The Board grants the Agency’s motion.
3
ORDER
The Board directs the Clerk to cause publication of the
following amendments in the Illinois Register for first notice:
TITLE 35:
ENVIRONMENTAL PROTECTION
SUBTITLE B:
AIR POLLUTION
CHAPTER
I:
POLLUTION CONTROL BOARD
SUBCHAPTER c:
EMISSION STANDARDS
AND
LIMITATIONS
FOR STATIONARY SOURCES
PART 211
DEFINITIONS
AND
GENERAL PROVISIONS
SUBPART A:
GENERAL PROVISIONS
Section
211.101
211.102
Section
211.121
211.122
211.130
211.150
211.170
211.210
211.230
211. 250
211.270
211.290
211.310
211.330
211.350
211.370
211.390
211.410
211.430
211. 450
211.470
211.490
211.510
211.530
211.550
211. 560
211. 570
211. 590
211.610
211.630
Incorporation by Reference
Abbreviations and Conversion Factors
SUBPART B:
DEFINITIONS
Other Definitions
Definitions
(Repealed)
Accelacota
Accumulator
Acid Gases
Actual Heat Input
Adhesive
Aeration
Aerosol Can Filling Line
Afterburner
Air Contaminant
Air Dried Coatings
Air Oxidation Process
Air Pollutant
Air Pollution
Air Pollution Control Equipment
Air Suspension Coater/Dryer
Airless Spray
Air Assisted Airless Spray
Annual Grain Through-Put
Application Area
Architectural Coating
As Applied
As-Applied Fountain Solution
Asphalt
Asphalt Prime Coat
Automobile
Automobile or Light-Duty Truck Assembly Source or
Automobile or Light-Duty Truck Manufacturing Plant
4
211. 650
211.670
211.690
211. 695
211.696
211. 710
211.730
211.750
211.770
211.790
211.810
211.830
211.850
211.870
211.890
211.910
211.930
211.950
211.970
211.990
211. 1010
211. 1050
211. 1070
211. 1090
211. 1110
211. 1130
211. 1150
211. 1170
211. 1190
211. 1210
211. 1230
211. 1250
211. 1270
211. 1290
211. 1310
211. 1330
211. 1350
211. 1370
211.1390
211. 1410
211. 1430
211. 1470
211. 1490
211. 1510
211. 1530
211.1550
211.1570
211. 1590
211. 1610
211. 1630
211. 1650
211. 1670
Automobile or Light-Duty Truck Refinishing
Baked Coatings
Batch Loading
Batch Operation
Batch Process Train
Bead-Dipping
Binders
British Thermal Unit
Brush or Wipe Coating
Bulk Gasoline Plant
Bulk Gasoline Terminal
Can
Can Coating
Can Coating Line
Capture
Capture Device
Capture Efficiency
Capture System
Certified Investigation
Choke Loading
Clean Air Act
Cleaning and Separating Operation
Cleaning Materials
Clear Coating
Clear Topcoat
Closed Purge System
Closed Vent System
Coal Refuse
Coating
Coating Applicator
Coating Line
Coating Plant
Coil Coating
Coil Coating Line
Cold Cleaning
Complete Combustion
Component
Concrete Curing Compounds
Concentrated Nitric Acid Manufacturing Process
Condensate
Condensible PM-b
Continuous Process
Control Device
Control Device Efficiency
Conventional Soybean Crushing Source
Conveyorized Degreasing
Crude Oil
Crude Oil Gathering
Crushing
Custody Transfer
Cutback Asphalt
Daily-Weighted Average VON Content
5
Day
Degreaser
Delivery Vessel
Dip Coating
Distillate
Fuel Oil
Drum
Dry Cleaning Operation or Dry Cleaning Facility
Dump-Pit Area
Effective Grate Area
Effluent Water Separator
Electrostatic Bell or Disc Spray
Electrostatic Spray
Emergency or Standby Unit
Emission Rate
Emission Unit
Enamel
Enclose
End Sealing Compound Coat
Enhanced Under-the-Cup Fill
Ethanol Blend Gasoline
Excess Air
Excessive Release
Existing Grain-Drying Operation
Existing Grain-Handling Operation
Exterior Base Coat
Exterior End Coat
External Floating Roof
Extreme Performance Coating
Fabric Coating
Fabric Coating Line
Federally Enforceable Limitations and Conditions
Final Repair Coat
Firebox
Fixed—Roof Tank
Flexographic Printing
Flexographic Printing Line
Floating Roof
Fountain Solution
Freeboard Height
Fuel Combustion Emission Unit or Fuel Combustion
Emission Source
Fugitive Particulate Matter
Full Operating Flowrate
Gas Service
Gas/Gas Method
Gasoline
Gasoline Dispensing Operation or Gasoline Dispensing
Facility
Gel Coat
Grain
Grain—Drying Operation
Grain—Handling and Conditioning Operation
211. 1690
211.1710
211.1730
211. 1750
211.1770
211.1790
211. 1810
211. 1830
211. 1850
211. 1870
211. 1890
211. 1910
211. 1920
211. 1930
211. 1950
211.1970
211.1990
211. 2010
211.2030
211.2050
211.2070
211.2090
211. 2110
211.2130
211.2150
211.2170
211. 2190
211. 2210
211.2230
211.2250
211.2270
211. 2310
211.2330
211.2350
211.2370
211.2390
211.2410
211.2430
211.2450
211.2470
211.2490
211.2510
211.2530
211.2550
211.2570
211.2590
211.2610
211.2650
211.2670
211.2690
6
211.2710
211.2730
211.2750
211.2770
211.2790
211.2810
211.2830
211.2850
211.2870
211.2890
211.2910
211.2930
211.2950
211.2970
211.2990
211.3010
211.3030
211.3050
211.3070
211.3090
211.3110
211.3130
211.3150
211. 3170
211. 3190
211.3210
211.3230
211.3250
211. 3270
211.3290
211. 3310
211.3330
211. 3350
211.3370
211.3390
211. 3410
211.3430
211.3450
211.3470
211.3480
211.3490
211.3500
211.3510
211.3530
211.3550
211. 3570
211.3590
211.3610
211.3620
211. 3630
211.3650
211.3660
Grain-Handling
Operation
Green-Tire
Spraying
Green
Tires
Gross
Heating
Value
Gross Vehicle Weight Rating
Heated Airless Spray
Heatset
Heatset Web Offset Lithographic Printing Line
Heavy
Liquid
Heavy
Metals
Heavy
Off-Highway
Vehicle
Products
Heavy
Off-Highway
Vehicle
Products
Coating
Heavy
Off-Highway
Vehicle Products Coating Line
High
Temperature
Aluminum
Coating
High
Volume
Low
Pressure
(HVLP)
Spray
Hood
Hot
Well
Housekeeping
Practices
Incinerator
Indirect
Heat
Transfer
Ink
In—Process
Tank
In-Situ Sampling Systems
Interior Body Spray Coat
Internal—Floating Roof
Internal Transferring Area
Lacquers
Large Appliance
Large Appliance Coating
Large Appliance Coating Line
Light Liquid
Light-Duty Truck
Light Oil
Liquid/Gas Method
Liquid-Mounted Seal
Liquid Service
Liquids Dripping
Lithographic Printing Line
Load-Out Area
Loading Event
Low Solvent Coating
Lubricating Oil
Magnet Wire
Magnet Wire Coating
Magnet Wire Coating Line
Major Dump Pit
Major Metropolitan Area
(MMA)
1’~ajorPopulation Area
(MPA)
Manually Operated Equipment
Manufacturing Process
Marine Terminal
Marine Vessel
7
211.3670
211.3690
211.3710
211.3730
211.3750
211.3770
211.3790
211
.
3810
211.3830
211.3850
211.3870
211.3890
211.3910
211.3930
211.3950
211.3970
211.3990
211.4010
211.4030
211.4050
211.4070
211.4090
211.4110
211.4130
211.4150
211.4170
211.4190
211.
4210
211.4230
211.4250
211.4260
211.4270
211.4290
211.4310
211.4330
211.4350
211.4370
211.4390
211.4410
211.4430
211.4450
211.4470
211.4490
211.4510
211.4530
211.4550
211.4590
211.4610
211.4630
211.4650
Material Recovery Section
Maximum Theoretical Emissions
Metal Furniture
Metal Furniture Coating
Metal Furniture Coating Line
Metallic Shoe-Type Seal
Miscellaneous Fabricated Product Manufacturing Process
Miscellaneous Formulation Manufacturing Process
Miscellaneous Metal Parts and Products
Miscellaneous Metal Parts and Products Coating
Miscellaneous Metal Parts or Products Coating Line
Miscellaneous Organic Chemical Manufacturing Process
Mixing Operation
Monitor
Monomer
Multiple Package Coating
New Grain-Drying Operation
New Grain-Handling Operation
No Detectable Volatile Organic Material’ Emissions
Non—contact Process Water Cooling Tower
Offset
One Hundred Percent Acid
One—Turn Storage Space
Opacity
Opaque Stains
Open Top Vapor Degreasing
Open-Ended Valve
Operator of a Gasoline Dispensing Operation or Operator
of a Gasoline Dispensing Facility
Organic Compound
Organic Material and Organic Materials
Organic Solvent
Organic Vapor
Oven
Overall Control
Overvarnish
Owner of a Gasoline Dispensing Operation or Owner of a
Gasoline Dispensing Facility
Owner or Operator
Packaging
Rotogravure
Printing
Packaging
Rotogravure
Printing
Line
Pail
Paint
Manufacturing
Source
or
Paint
Manufacturing
Plant
Paper
Coating
Paper
Coating
Line
Particulate Matter
Parts Per Million
(Volume)
or PPM
(Vol)
Person
Petroleum
Petroleum Liquid
Petroleum Refinery
Pharmaceutical
8
211.4670
211.4690
211.4710
211.4730
211.4750
211.4770
211.4790
211.4810
211.4830
211.4850
211.4870
211.4890
211.4910
211.4930
211.4950
211.4970
211.4990
211.
5030
211.5050
211.5060
211.5070
211.5090
211.5110
211.5130
211.5150
211.5170
211.5185
211.5190
211.5210
211.5230
211.5245
211.5250
211.5270
211.5310
211.5330
211.5340
211.5350
211.5370
211.5390
211.5410
211.5430
211.5450
211.5470
211.5490
211.5500
211.5510
211.5530
211.5550
211.5570
211.5590
Pharmaceutical
Coating
Operation
Photochemically
Reactive
Material
Pigmented
Coatings
Plant
Plasticizers
PM—b
Pneumatic
Rubber
Tire
Manufacture
Polybasic Organic Acid Partial Oxidation Manufacturing
Process
Polyester Resin Material(s)
Polyester Resin Products Manufacturing Process
Polystyrene Plant
Polystyrene Resin
Portable Grain-Handling Equipment
Portland Cement Manufacturing Process Emission Source
Portland Cement Process or Portland Cement
Manufacturing Plant
Potential
to
Emit
Power
Driven
Fastener
Coating
Pressure
Release
Pressure
Tank
Pressure/Vacuum
Relief
Valve
Prime
Coat
Primer
Surfacer
Coat
Primer Surfacer Operation
Primers
Printing
Printing Line
Process Emission Source
Process Emission Unit
Process Unit
Process Unit Shutdown
Process Vent
Process
Weight
Rate
Production Equipment Exhaust System
Publication
Rotogravure
Printing
Line
Purged Process Fluid
Rated Heat Input Capacity
Reactor
Reasonably Available Control Technology
(RACT)
Reclamation System
Refiner
Refinery Fuel Gas
Refinery Fuel Gas System
Refinery Unit or Refinery Process Unit
Refrigerated Condenser
Regulated Air Pollutant
Reid Vapor Pressure
Repair
Repair Coat
Repaired
Residual Fuel Oil
9
211.5610
211.5630
211.
5650
211.
5670
211.
5690
211.
5710
211.5730
211.
5750
211.
5770
211.5790
211.5810
211.5830
211.5850
211.5870
211.5890
211.5910
211.5930
211.5950
211.5970
211.5990
211.
6010
211.
6025
211.
6030
211.6050
211.6070
211.6090
211.6110
211.6130
211.6150
211.6170
211.6190
211.6210
211.6230
211.6250
211.6270
211.6290
211.6310
211.6330
211.6350
211.6355
211.6360
211.6370
211.6390
211.6410
211.6430
211.6450
211.6470
211.6490
211.6510
211.6530
211.6550
Restricted
Area
Retail
Outlet
Ringelinann
Chart
Roadway
Roll
Coater
Roll
Coating
Roll
Printer
Roll
Printing
Rotogravure Printing
Rotogravure
Printing
Line
Safety
Relief
Valve
Sandblasting
Sanding
Sealers
Screening
Sealer
Semi-Transparent
Stains
Sensor
Set
of
Safety
Relief
Valves
Sheet
Basecoat
Shotblasting
Side-Seam
Spray
Coat
Single Unit Operation
Smoke
Smokeless Flare
Solvent
Solvent Cleaning
Solvent Recovery System
Source
Specialty High Gloss Catalyzed Coating
Specialty Leather
Specialty Soybean Crushing Source
Splash Loading
Stack
Stain Coating
Standard Conditions
Standard
Cubic
Foot
(scf)
Start-Up
Stationary
Emission
Source
Stationary Emission Unit
Stationary Gas Turbine
Stationary Reciprocating Internal Combustion Engine
Stationary Source
Stationary Storage Tank
Storage Tank or Storage Vessel
Styrene Devolatilizer Unit
Styrene Recovery Unit
Submerged Loading Pipe
Substrate
Sulfuric Acid Mist
Surface Condenser
Synthetic Organic Chemical or Polymer Manufacturing
Plant
10
211.6570
211.6590
211. 6610
211.6630
211. 6650
211.6670
211.6690
211. 6710
211.6730
211.
6750
211. 6770
211.6790
211.6810
211.6830
211.6850
211. 6870
211.6890
211. 6910
211. 6930
211.6950
211. 6970
211.6990
211.7010
211.7030
211.7050
211.7070
211.7090
211.7110
211.7130
211.7150
211.7170
211.
7190
211.7210
211. 7230
211.7250
211.
7270
211.7290
211.
7310
211.7330
211.7350
Tablet Coating Operation
Thirty-Day Rolling Average
Three—Piece Can
Through-the-Valve Fill
Tooling Resin
Topcoat
Topcoat Operation
Touch-Up
Transfer Efficiency
Tread End Cementing
True Vapor Pressure
Turnaround
Two—Piece Can
Under-the-Cup
Fill
Undertread Cementing
Unregulated Safety Relief Valve
Vacuum Producing System
Vacuum Service
Valves Not Externally Regulated
Vapor Balance System
Vapor Collection System
Vapor Control System
Vapor-Mounted Primary Seal
Vapor Recovery System
Vapor—Suppressed Polyester Resin
Vinyl Coating
Vinyl Coating Line
Volatile Organic Liquid
(VOL)
Volatile Organic Material Content
(VOMC)
Volatile Organic Material
(VOM)
or Volatile Organic
Compound
(VOC)
Volatile Petroleum Liquid
Wash Coat
Wastewater
(Oil/Water)
Separator
Weak Nitric Acid Manufacturing Process
Web
Wholesale Purchase
—
Consumer
Wood Furniture
Wood Furniture Coating
Wood Furniture Coating Line
Woodworking
APPENDIX A
Rule into Section Table
APPENDIX B
Section into Rule Table
AUTHORITY:
Implementing Sections 9,
9.1 and 10 and authorized by
Section 27 and 28.5 of the Environmental Protection Act
(Ill.
Rev.
Ctat.
1901,
oh.
111~,
pars.
1009,
1009.1,
1010
and
1027),
(P.A.
87—1213, effective &eptc~tbor26,
1992-~
415
ILCS 5/9,
9.1,
10,
27 and 28.5
(1992).
SOURCE:
Adopted as Chapter 2:
Air Pollution, Rule 201:
11
Definitions,
R7b-23,
4 PCB 191,
filed and effective April
14,
1972; amended
in P.74—2 and P.75—5,
32 PCB 295,
at
3 Ill.
Reg.
5,
p.
777,
effective February
3,
1979;
amended
in R78-3 and 4,
35
PCB 75 and 243,
at
3 Ill.
Reg.
30,
p.
124, effective July 28,
1979; amended in P.80-5,
at
7
Iii.
Reg.
1244, effective January
21,
1983;
codified at 7 Ill.
Reg.
13590; amended in P.82—i (Docket
A)
at
10 Ill. Reg.
12624,
effective July 7,
1986; amended in
R85—21(A)
at 11 Ill. Reg.
11747, effective June 29, 1987; amended
in R86—34 at
11 Ill.
Reg.
12267, effective July
10,
1987;
amended
in R86—39 at 11 Ill.
Reg.
20804, effective December
14,
1987;
amended in P.82-14 and R86-37
at
12 Ill. Reg.
787, effective
December 24,
1987;
amended in R86—18 at 12 Ill.
Reg.
7284,
effective April
8,
1988;
amended
in R86—10 at
12 Ill.
Reg.
7621,
effective April 11,
1988; amended in R88—23 at
13 Ill. Reg.
10862, effective June
27, 1989; amended in P.89—S at
13 Ill.
Reg.
17457,
effective January
1,
1990; amended in P.89-16(A)
at 14 Ill.
Reg.
9141,
effective May 23,
1990;
amended in R88—30(B)
at 15
Ill.
Reg.
5223,
effective March 28,
1991; amended in R88—14 at 15
Ill. Reg.
7901, effective May
14,
1991; amended in P.91-10 at 15
Ill.
Reg.
15564, effective October 11,
1991;
amended
in P.91-6 at
15 Ill.
Reg.
15673, effective October
14,
1991; amended in P.91—22
at
16
Ill.
Reg.
7656,
effective May
1,
1992; amended in P.91-24 at
16
Ill.
Reg.
13526, effective August 24,
1992;
amended in P.93—9
at 17 Ill. Reg.
16504, effective September 27,
1993; amended in
R93—1l at
17
Ill.
Reg. 21471,
effective December 7,
1993; amended
in R93—14 at 18
Iii. Reg.
1253,
effective January 18,
1994;
amended in P.94—12 at 18 Ill. Reg.
14962, effective September 21,
1994; amended in R94-14 at 18 Ill. Reg.
15744,
effective October
17,
1994;
amended in R94—15 at
18 Iii. Reg.
16379, effective
November
4,
1994; amended in R94-~at ~
Ill. Reg.
effective
__________________;
amended in R94—~ at ~
Ill.
Reg.
_________,
effective
________________
SUBPART
B:
DEFINITIONS
Section 211.695
Batch Operation
“Batch operation” means, for purposes of
35
Ill.
Adm.
Code
Parts
218
and
219,
Sections
218.500
through 218.506 and 219.500 throu~h
219.506,
a noncontinuous operation in which a discrete auantitv
or batch of feed is charged into a chemical manufacturina process
unit and distilled or reacted, or otherwise used at one time, and
may include, but is not limited to. reactors, filters. dryers.
distillation columns, extractors. crystallizers, blend tanks.
neutralizer
tanks.
digesters.
surge tanks and product separators.
After each batch operation. the eaui~mentis ~enerallv emptied
before a fresh batch is started.
(Source:
Added
at
_____
Ill.
Reg.
,
effective
______________________________________________________
)
Section 211.696
Batch Process Train
12
“Batch
ørocess
train”
means,
for
purposes
of
35
Iii.
Adm.
Code
Parts
218
and
219,
Sections 218.500 through 218.506 and 219.500
through 219.506. the collection of equipment
(e.g., reactors,
filters. dryers. distillation columns,
extractors, crystallizers,
blend tanks,
neutralizer tanks, digesters,
surge tanks and
product separators)
confic~uredto produce a specific product or
intermediate by a batch operation.
A batch process train
terminates at the point of storage or product handling of the
product or intermediate being produced in the batch process
train.
Irrespective of the product being produced.
a batch
process train which is independent of other processes shall be
considered a single batch process train for purposes of 35 Ill.
Adm. Code Parts 218 and 219.
(Source:
Added at
_____
Ill. Reg.
,
effective
____
____________________________________________________________
)
Section 211.5245
Process Vent
“Process
vent”
means~
for
purposes
of
35
Ill.
Adm.
Code
Parts
218
and 219. Sections 218.500 throu~h218.506 and 219.500 throu~h
219.506,
any non-fugitive source of VON emissions to the
atmosphere resulting from non—combustion emission units.
A
process vent begins at the inlet to the control device. or in the
absence of a control device. at the point of discharge to the
atmosphere.
This includes all emission units vents and stacks.
Not included in this definition are exhaust streams from exhaust
hoods and building ventilation fans which are sued to provide
ventilation for workers and not to collect and discharge
emissions from specific emission units.
(Source:
Added
at
_____
Ill.
Reg.
,
effective
____
_______________________________________________________
)
Section
211.6025
Single Unit Operation
“Single
unit
operation”
means,
for
purposes
of 35 Ill. Adm. Code
Parts 218 and 219. Sections 218.500 through 218.506 and 219.500
through
219.506.
a distinct piece of equipment in a batch
operation within which one or more discrete processing steps
occur.
Such discrete processing steps include, but are not
limited to, the preparation of reactants.
facilitation of
reactions, separation and purification of products or
intermediates,
and
recycling
of
materials.
(Source~ Added at
Ill. Reg.
,
effective
____
13
TITLE
35:
ENVIRONMENTAL
PROTECTION
SUBTITLE
B:
AIR
POLLUTION
CHAPTER
I:
POLLUTION
CONTROL
BOARD
SUBCHAPTER
c:
EMISSIONS
STANDARDS
AND
LIMITATIONS
FOR
STATIONARY
SOURCES
PART
218
ORGANIC
MATERIAL
EMISSION
STANDARDS
AND
LIMITATIONS
FOR
THE
CHICAGO
AREA
SUBPART
A:
GENERAL
PROVISIONS
Section
218.
100
218.101
218.102
218.103
218.104
218.105
218. 106
218.
107
218.
108
218.109
218.
110
218.111
218. 112
218.113
218.
114
Introduction
Savings Clause
Abbreviations and Conversion Factors
Applicability
Definitions
Test Methods and Procedures
Compliance
Dates
Operation of Afterburners
Exemptions,
Variations,
and Alternative Means of
Control or Compliance Determinations
Vapor Pressure of Volatile Organic Liquids
Vapor Pressure of Organic Material or Solvents
Vapor Pressure of Volatile Organic Material
Incorporations by Reference
Monitoring for Negligibly-Reactive Compounds
Compliance
with
Permit
Conditions
SUBPART B:
ORGANIC EMISSIONS FROM STORAGE AND LOADING OPERATIONS
Section
218.119
218.121
218.122
218.
123
218.124
218.125
218.126
Applicability
for
VOL
Storage Containers
Loading Operations
Petroleum Liquid Storage Tanks
External Floating Roofs
Compliance Dates
(Repealed)
Compliance Plan (Repealed)
Separation Operations
Pumps and Compressors
Vapor Blowdown
Safety Relief Valves
Section
218.141
218.142
218.143
218. 144
SUBPART
C:
ORGANIC
EMISSIONS
FROM
MISCELLANEOUS
EQUIPMENT
14
Emission Limitations
Daily-Weighted
Average
Limitations
Solids Basis Calculation
Alternative Emission Limitations
Exemptions from Emission Limitations
Exemption from General Rule on Use of Organic Material
Compliance Schedule
Recordkeeping and Reporting
SUBPART
G:
USE
OF
ORGANIC
MATERIAL
Use
of
Organic
Material
Alternative Standard
Fuel Combustion Emission Units
Operations with Compliance Program
SUBPART H:
PRINTING
AND
PUBLISHING
Sect ion
218.401
218.402
218.403
218. 404
218.
405
Section
218.421
218.422
218.
423
218.424
218.425
218.426
218.427
218.428
Flexographic and Rotogravure Printing
Applicability
Compliance Schedule
Recordkeeping and Reporting
Heatset-Web-Offset Lithographic Printing
SUBPART
Q:
LEAKS
FROM
SYNTHETIC
ORGANIC CHEMICAL AND
POLYMER
MANUFACTURING
PLANT
General Requirements
Inspection Program Plan for Leaks
Inspection Program for Leaks
Repairing Leaks
Recordkeeping for Leaks
Report for Leaks
Alternative Program for Leaks
open—Ended Valves
SUBPART
E:
SOLVENT
CLEANING
Solvent Cleaning in General
Cold
Cleaning
Open
Top
Vapor
Degreasing
Conveyorized Degreasing
Compliance Schedule (Repealed)
Test Methods
SUBPART
F:
COATING
OPERATIONS
Section
218.181
218.182
218.183
218.184
218.185
218.186
Section
218
.
204
218.205
218.206
218.207
218.208
218.209
218.210
218.211
Section
218.301
218.302
218. 303
218.304
15
218.429
Standards for Control Devices
218.430
Compliance Date
(Repealed)
SUBPART
P.:
PETROLEUM
REFINING
AND
RELATED
INDUSTRIES;
ASPHALT MATERIALS
Section
218.441
218.442
218.443
218.444
218.445
218.446
218.447
218.448
218.449
218.
450
218.451
218.452
218.453
Petroleum
Refinery
Waste
Gas
Disposal
Vacuum Producing Systems
Wastewater (Oil/Water)
Separator
Process
Unit
Turnarounds
Leaks:
General Requirements
Monitoring Program Plan for Leaks
Monitoring Program for Leaks
Recordkeeping for Leaks
Reporting for Leaks
Alternative Program for Leaks
Sealing Device Requirements
Compliance Schedule for Leaks
Compliance Dates
(Repealed)
SUBPART
S:
RUBBER
AND
MISCELLANEOUS PLASTIC PRODUCTS
Manufacture of Pneumatic Rubber Tires
Green Tire Spraying Operations
Alternative Emission Reduction Systems
Emission Testing
Compliance Dates
(Repealed)
Compliance Plan (Repealed)
SUBPART
T:
PHARMACEUTICAL
MANUFACTURING
Section
218.480
218.481
218.482
218. 483
218. 484
218.485
218.486
218.487
218.488
218.489
Applicability
Control of Reactors, Distillation Units,
Crystallizers,
Centrifuges and Vacuum Dryers
Control of Air Dryers, Production Equipment Exhaust
Systems and Filters
Material Storage and Transfer
In—Process Tanks
Leaks
Other Emission Units
Testing
Monitoring for Air Pollution Control Equipment
Recordkeeping for Air Pollution Control Equipment
SUBPART
V:
BATCH
OPERATIONS
AND
AIR OXIDATION PROCESSES
Section
218. 500
218.501
ApPlicability for Batch operations
Section
218.461
218.462
218.463
218. 464
218.465
218. 466
Control Requirements for Batch Operatons
16
218.502
218.503
218.504
218.505
218.506
218.521
218.525
218.526
218. 527
Section
218.541
Section
218.561
218.562
218.563
Section
218.581
218.582
218.583
218.584
218.585
218.586
Determination of Uncontrolled Total Annual Mass
Emissions and Average Flow Rate Values for Batch
ODerations
Performance
and Testing Requirements for Batch
Operations
Monitoring
Requiremsnts
for
Batch
Operations
RePorting and Recordkeeping for Batch Operations
Compliance Date
Definitions
(Repealed)
Emission
Limitations
for
Air
Oxidation
Processes
Testing
and
Monitoring
Compliance Date (Repealed)
SUBPART W:
AGRICULTURE
Pesticide Exception
SUBPART X:
CONSTRUCTION
Architectural Coatings
Paving Operations
Cutback Asphalt
SUBPART Y:
GASOLINE DISTRIBUTION
Bulk Gasoline Plants
Bulk Gasoline Terminals
Gasoline Dispensing Operations
-
Storage Tank Filling
Operations
Gasoline Delivery Vessels
Gasoline Volatility Standards
Gasoline Dispensing Operations
-
Motor Vehicle Fueling
Operations
SUBPART
Z:
DRY CLEANERS
Section
218.601
218.602
218.603
218.604
218.605
218.606
218.607
218.608
218.609
218.610
218.611
218.612
Perchloroethylene Dry Cleaners
Applicability
Leaks
Compliance Dates
(Repealed)
Compliance Plan (Repealed)
Exception to Compliance Plan
(Repealed)
Standards for Petroleum Solvent Dry Cleaners
Operating Practices for Petroleum Solvent Dry Cleaners
Program for Inspection and Repair of Leaks
Testing and Monitoring
Applicablity for Petroleum Solvent Dry Cleaners
Compliance Dates (Repealed)
17
218.613
Section
218.620
218.621
218.623
218.624
218.
625
218.626
218.628
218.630
218.636
218.637
Section
218.640
218.642
218.644
Compliance
Plan
(Repealed)
SUBPART
AA:
PAINT
AND
INK
MANUFACTURING
Applicability
Exemption for Waterbase Material and Heatset-Offset Ink
Permit Conditions
(Repealed)
Open Top Mills, Tanks, Vats or Vessels
Grinding Mills
Storage Tanks
Leaks
Clean Up
Compliance Schedule
Recordkeeping and Reporting
SUBPART
BB:
POLYSTYRENE
PLANTS
Applicability
Emissions Limitation at Polystyrene Plants
Emissions Testing
SUBPART
CC:
POLYESTER
RESIN
PRODUCT MANUFACTURING PROCESS
Section
218.660
218.666
218.667
218
•
668
218.670
218.672
Section
218.680
218.686
218.688
218.690
218.692
Section
218.760
218.762
218 .764
218.766
218.768
218.770
218.875
218.877
Applicability
Control Requirements
Compliance Schedule
Testing
Recordkeeping and Reporting for Exempt Emission Units
Recordkeeping
and
Reporting
for
Subject
Emission
Units
SUBPART
DD:
AEROSOL CAN
FILLING
Applicability
Control Requirements
Testing
Recordkeeping and Reporting for Exempt Emission Units
Recordkeeping and Reporting for Subject Emission Units
SUBPART GG:
MARINE TERMINALS
Applicability
Control Requirements
Compliance Certification
Leaks
Testing and Monitoring
Recordkeeping and Reporting
Applicability of Subpart BB (Renumbered)
Emissions Limitation at Polystyrene Plants
(Renumbered)
18
218.879
218.881
218.883
218.886
Compliance Date (Repealed)
Compliance Plan (Repealed)
Special Requirements for Compliance Plan
(Repealed)
Emissions
Testing
(Renumbered)
SUBPART PP:
MISCELLANEOUS FABRICATED PRODUCT MANUFACTURING
PROCESSES
Section
218.920
218.
923
218.926
218.927
218.928
Applicability
Permit Conditions
(Repealed)
Control Requirements
Compliance Schedule
Testing
SUBPART
QQ:
MISCELLANEOUS FORMULATION MANUFACTURING PROCESSES
Section
218.940
218.943
218.946
218.947
218.948
Applicability
Permit Conditions
(Repealed)
Control
Requirements
Compliance Schedule
Testing
SUBPART
RR:
MISCELLANEOUS
ORGANIC
CHEMICAL
MANUFACTURING
PROCESSES
Section
218.960
218.963
218.966
218.967
218.968
Section
218.980
2 18.983
218.986
218.987
218.988
Section
218.990
218.991
Section
Applicability
Permit Conditions
(Repealed)
Control Requirements
Compliance Schedule
Testing
SUBPART
TT:
OTHER
EMISSION
UNITS
Applicability
Permit
Conditions
(Repealed)
Control Requirements
Compliance Schedule
Testing
SUBPART UU:
RECORDKEEPING AND
REPORTING
Exempt Emission Units
Subject Emission Units
218.Appendix A:
List of Chemicals Defining Synthetic
Organic Chemical and Polymer
Manufacturing
19
Section 218.Appendix
B:
VOM
Measurement
Techniques
for
Capture
Efficiency
Section 218.Appendix
C:
Reference Test Methods for Air Oxidation
Processes
Section
218.Appendix
D:
Coefficients
for
the Total Resource
Effectiveness
Index
(TRE)
Equation
Section
218.Appendix
E:
List
of Affected Marine Terminals
AUTHORITY:
Implementing Section 10 and authorized by Section
28.5 of the Environmental Protection Act
(Ill. Rev.
Stat.
1991,
ch.
111½,
par.
1010)
(P.A.
87—1213,
effective
September
26,
1992)
415
ILCS
5/10
and
28.5.
SOURCE:
Adopted
at
R91-7
at
15
Ill.
Reg.
12231,
effective August
16,
1991;
amended in P.91—23 at 16 Ill. Reg.
13564,
effective
August 24,
1992;
amended in
P.91—28 and P.91-30 at
16 Ill. Reg.
13864, effective August 24,
1992;
amended in P.93—9 at 17 Ill.
Reg.
16636, effective September 27,
1993;
amended
in
R93—14
at
18
Ill.
Reg.
at
1945,
effective
January
24,
1994;
amended
in
P.94—12
at 18
Ill. Reg.
14973, effective September 21,
1994; amended in
R94-15 at
18
Ill. Reg.16379,
effective November 4,
1994; amended
in R94—~
at
~li
Ill. Reg.
,
effective
__________________
amended
in
R94-~
at
~
Ill.
Reg.
,
effective
____________
SUBPART V:
BATCH OPERATIONS AND AIR OXIDATION PROCESSES
Section 218.500
Applicability for Batch Operations
~
The control requirements set forth in Section 218.501
of
this
Subpart
shall
apply
to:
3j
Process vents associated with batch operations at
sources identified by any of the following
four—
digit standard industrial classification I”SIC”)
codes,
as defined in the
1987
edition
of
the
Federal Standard Industrial Classification Manual:
SIC 2821.
2833,
2834,
2861.
2865,
2869.
and 2879
and
•All batch operations at Stepan ComPany’s Milisdale
manufacturing facility. Elwood, Illinois.
~
The requirements of Sections 218.500 through 218.506
shall not a~~lvto:
jj
Any emission unit included within the category
specified in 35 Iii.
Adin.
Code Part 218.
Subparts
BorT
21
Any
emission unit included within the category
specified in Sections 218.520 through 218.527 of
20
this
Subpart;
and
~j.
Any emission unit included within an Early
Reduction Program, as specified in 40 CFR Part 63,
and published in 57 Fed.
Req.
61970
(December 29,
1992). evidenced by a timely enforceable
commitment approved bY USEPA.
ci
The following single unit operations and batch process
trains are subject to this Subpart but are considered
to be de minimis and are, therefore,
exempt from the
control requirements of Section 218.501 of this
Subpart.
However, the recordkeeping and reporting
requirements
in
Section
218.505
of
this
Subpart
shall
apply to such de minimis single unit operations and
batch
process
trains:
fl
Within a batch operation,
any single unit
operation
with
uncontrolled
total
annual mass
emissions of less than or equal to
500
lb/yr
of
VON.
Such single unit operations are also
excluded from the calculation of the total annual
mass emissions for a batch process train.
If the
uncontrolled total annual mass emissions from such
exempt
single
unit
o~erption
exceed
500 lb/yr of
VON in any subsequent year. the source shall
calculate applicability in accordance with
subsection
Cd)
of this Section for both the
individual single unit operation and the batch
process train containing the single unit
operation; and
~J...
Any
batch process train containing process vents
that have,
in the aggregate, uncontrolled total
annual mass emissions,
as determined in accordance
with Section 218.502(a)
of this Subpart. of less
than 30.000 lb/yr of VON for all products
manufactured in such batch process train.
~j
The a~p1icabi1itvequations in subsection
(e) of this
Section, which require the calculation of uncontrolled
total annual mass emissions and flow rate value,
shall
be used to determine whether a single unit operation or
a batch process train is subiect to the control
requirements set forth in Section 218.501 of this
Subpart. The applicability equation shall be applied to
the following:
fl
Any single unit operation with uncontrolled total
annual mass emissions that exceed 500 lb/yr and
with a VON concentration greater than 500 ~mv.
In this individual determination, no a~plicabilitv
21
analysis shall be performed for any sir~g1eunit
operation with a VON concentration
of less than or
equal
to
500
~pmv;
and
21
Any
batch
Process
train
containing
process
vents
which,
in the aggregate. have uncontrolled total
annual mass emissions of 30,000
lb/yr or more of
VOM from all products manufactured in the batch
process train.
Any single unit operation with
uncontrolled
total
annual
mass
emissions
exceeding
500
lb/yr.
re~ard1ess
of VON concentration, shall
be
included
in
the
a~~re~ate
applicability
analysis.
ci
A~~licabi1itvequations
~j.
The
applicability
equations
in
this
subsection
are
specific
to
volatility.
21
For
Purposes
of
this subsection, the following
abbreviations
a~~ly:
=
Vent
stream
flow
rate.
scfm
~j
UTANE
=
Uncontrolled total annual mass
emissions of VON. expressed as
lb/yr
Q1
WAV
=
Weiahted avera~evolatility
Q1
MVOM~
=
Mass of VON component
i; and
~j
MWVOM~=
Molecular weight of VON component
i;
and
11
3~
=
Vapor pressure of VON component
j.
~j
Weighted average volatility shall be calculated as
follows:
n
(MVOM~1)
E
(VP1)x
)
i=1
(NWVOM1)
WAV
=
n
(
(MVOM~)
3
3
i=1
(
(MWVON~)
~
Yor purposes of determining applicability, flow
rate values shall be calculated as follows:
22
~
Low
WAV
has
a
vapor
pressure
less
than
or
equal to 75
mmHg
at 20°C (68°F).and shall
use the following equation:
FR
=
10.07
(UTANE)
—
1,821
~
Moderate WAV has a vapor pressure greater
than
75
inxnHg
but
less
than
or
equal
to
150
minHg
at
20°C
(68°F).
and shall use the
following equation:
FR
=
10.031
(UTANE)
—
494
gj
High WAV has a vapor pressure areater than
150
ininHg at 20°C (68°F). and shall use the
following equation:
FR
=
0.013
(UTAME)
—
301
~J
To determine the vapor pressure of VON, the
applicable methods and procedures
in Section
218.111 of this Part shall apply.
(Source:
Added at
Ill.
Reg.
_______,
effective
Section 218.501
Control Requirements
for Batch Operations
~j.. Every owner or operator of a single unit operation with
an average flow rate,
as determined in accordance with
Section 218.502(b) of this Subpart. below the flow rate
value calculated by the applicability equations
contained in Section 218.500(e)
of this Subpart, shall
reduce uncontrolled VON emissions from such single unit
operation by an overall efficiency, on average,
of at
least 90 percent. or 20 ppmv, per batch cycle.
~j
Every owner or operator of a batch process train with
an
average
flow
rate,
as
determined
in
accordance
with
Section 218.502(b) (2) of this Subpart, below the flow
rate value calculated bY the applicability equations
contained in Section 218.500(e) of this Subpart, shall
reduce uncontrolled VON emissions from such batch
process train by an overall efficiency, on average, of
at least 90 percent. or 20 p~mv.~er batch cycle.
For
purposes of demonstrating compliance with the emission
limitations set forth in this Section. any control
device meeting the criteria in subsection
(c) of this
Section shall be deemed to achieve a control efficiency
of 90 percent. or 20 p~mv.per batch cycle,
as
applicable.
23
ci
Notwithstanding subsections
(a)
or
(b)
of
this
Section~
any
source
that
has
installed
on
or
before
March
15,
1995,
any
control
device
which
is demonstrated to the
Agency’s satisfaction to be unable to meet the
applicable control requirements of this Section,
scrubber,
or
shell
and
tube
condenser using a non-
refrigerated cooling media, and such device achieves at
least 81 Percent control efficiency of VON emissions.
is
required
to
meet
the
90
percent
emission
limitation
or
20
p~inv
VON
concentration
set
forth
in
subsections
(a)
or
(b)
of
this
Section,
as applicable, upon the
earlier to occur of the date the device is replaced for
any reason, including, but not limited to, normal
maintenance, malfunction,
accident, and obsolescence,
or
December
31,
1999.
A
scrubber.
shell
and
tube
condenser using a non—refrigerated cooling media,
or
other control device meeting the criteria of this
subsection
is considered replaced when:,
31
All
of
the
device
is replaced; or
21
When
either
the
cost
to
repair
the
device
or
the
cost to replace cart of the device exceeds 50
percent of the cost of replacing the entire device
with a control device that complies with the 90
Percent emission limitation or 20 ~pmv VON
concentration level in subsection
(a) of this
Section.
as applicable.
~.
If
a boiler or process heater is used to comply with
this Section. the vent stream shall be introduced into
the flame zone of the boiler or Process heater.
~
If a flare is used to com~lvwith this Section.
it
shall comply with the reauirements of 40 CFR 6O.18.~
incorporated by reference at Section 218.112 of this
Part.
The flare operation requirements of 40 CFR 60.18
do not apply
if a process. not subiect to this Subpart,
vents an emergency relief discharge into a common flare
header and causes the flare servicing the process
subject to this Subpart to not comply with one or more
of ths provisions of 40 CFR 60.18.
(Source:
Added at
_____
111. Reg.
,
effective
______
______________________________________________
)
Section 218.502
Determination of Uncontrolled Total Annual
Mass Emissions and Average Flow Rate Values
for Batch Operations
,~j
Uncontrolled total annual mass emissions shall be
determined by the following methods:
24
~,j
Direct process vent emissions measurements taken
prior to any release to the atmosphere.
following
any recovery device and prior to anY control
device, provided such measurements conform with
the requirements of measuring the mass flow rate
of VON incoming to the single unit operation as
set forth in Section 218.503(f) (2),
(f) (3)(A)
and
(f) (3) (B)
of this Subpart; or
21
Engineering estimates of the uncontrolled VON
emissions from
a process vent or process vents,
in
the aggregate1 within a batch process train.
multiplied by the potential or permitted number of
batch cycles Per Year as follows:
~
Engineering estimates of the uncontrolled VON
emissions shall be based upon accented
chemical engineering principles, measurable
process parameters.
or physical or chemical
laws and their properties.
Examples of
methods include, but are not limited to, the
following:
LL
Use of material balances based on
process stoichiometry to estimate
maximum VOM concentrations
jJJ,
Estimation of maximum flow rate based on
physical eaui~mentdesign such as
pump
or blower capacities; and
iii) Estimation of VOM concentrations based
on saturation conditions.
~j
All data, assumptions and Procedures used in
any engineering estimate shall be documented.
~
Average flow rate shall be determined by any of the
following methods:
31
Direct process vent flow rate measurements taken
prior to any release to the atmosphere, following
anY recovery device and prior to any control
device, provided such measurements conform with
the requirements of measuring incoming volumetric
flow rate set forth in Section 218.503(e) (2) of
this SubDart
21.
Averaae flow rate for a single unit operation
havina multiple emission events or batch process
trains shall be the weighted average flow rate,
calculated as follows:
25
n
E
AFR~
x
ADE1)1
i=1
WAF
=
_____________
n
E
(ADE~1
i=1
where:
=
Actual weighted average flow
rate for a single unit
operation or batch process
train;
AFR~
=
Average flow rate per emission
event:
=
Annual duration of emission
event;
and
n
=
Number of emission events.
31
Engineering estimates calculated in accordance
with the requirements in subsection
(a) (2) of this
Section.
~j
For purposes of determining the average flow rate for
steam vacuuming systems~ the steam flow shall be
included in the average flow rate calculation.
(Source:
Added at
____
Ill. Reg.
______,
effective
______
I
Section 218.503
Performance and Testing Requirements for
Batch Operations
~
UPon the Agency’s request, the owner or operator of a
batch operation shall conduct testing to demonstrate
compliance with Section 218.501 of this Subpart.
The
owner or operator shall, at its own expense, conduct
such tests in accordance with the applicable test
methods and procedures specified in Section 218.503(d),
(e). and
(f) of this Subpart.
~
Notwithstanding subsection
(a) of this Section.
flares
and_Process boilers used to comply with control
requirements of Section 218.501 of this Subpart shall
be exempt from performance testing requirements.
ci
When a flare is used to com~lvwith the control
i~equirementsof Section 218.501 of this Subpart. the
flare
shall
comply
with the requirements of 40 CFR
60.18.
incorporated by reference at Section 218112
of
this Part.
26
~
The owner
or operator of a batch operation that
is
exempt from the control requirements
of Section 218.501
of this Subpart shall demonstrate,
upon the Agency’s
request, the absence of oversized gas moving equipment
in any manifold.
Gas moving eauipment shall be
considered oversized if
it exceeds the maximum
requirements
of the exhaust
flow rate by more than
30
percent.
ci
For the purpose of demonstrating compliance with the
control requirements in Section 218.501 of this
Subpart. the batch operation shall be run at
representative operating conditions and flow rates
during any performance test.
fl
The following methods
in 40 CFR 60. Appendix A.
incorporated by reference at Section 218.112 of this
Part,
shall be used to demonstrate com~1iancewith the
reduction efficiency requirement set forth in Section
218.501 of this Subpart:
31
Method
1 or 1A, as ap~roprjate, for selection of
the sam~1ingsites if the flow measuring device is
not a rotameter.
The control device inlet
sampling site for determination of vent stream VOM
composition reduction efficiency shall be prior to
the control device and after the control device
21.
Method
2.
2A.
2C. or 2D. as appropriate, for
determination of gas stream volumetric flow rate
flow measurements, which shall be taken
continuously.
No traverse is necessary when the
flow measuring device is an ultrasonic probe
.
31
Method 25A or Method 18
if applicable, to
determine the concentration of VOM in the control
device inlet and outlet
~
The sampling time for each run will be the
entire length of the batch cycle in which
readings shall be taken continuously,
if
Method 25A is used,
or as often as
is
possible using Method 18, with a maximum of
15—minute intervals between measurements
throughout the batch cycle
~j
The mass emission rate from the process vent
or inlet to the control device shall be
determined by combining concentration and
flow rate measurements taken simultaneously
at sampling sites selected in accordance with
subsection
(f) (1) of this Section throughout
27
the batch cycle
~1
The mass emission rate from the control
device outlet shall be obtained by combining
concentration and flow rate measurements
taken simultaneously at sampling sites
selected in accordance with subsection
(f) (1)
of this Section throughout the batch cycle
and
Q),.
The efficiency of the control device shall be
determined by integrating the mass emission
rates obtained in subsections
Cc) (3) (A)
and
(c)_(3)_(3) of this Section, over the time of
the batch cycle and dividing the difference
in inlet and outlet mass flow totals by the
inlet mass flow total.
ci
Upon request bY the Agency to conduct t~esting,an owner
or operator of a batch operation which has installed
a
scrubber,
a shell and tube condenser using a non—
refrigerated cooling media, or anY other control device
which meets the criteria of Section 218.501(c)
of this
Subpart, shall demonstrate that such device achieves
the control efficiency applicable within Section
218.501 of this Subpart upon the earlier to occur of
the date the device is replace or December 31,
1999.
~
The owner or operator of a batch operation may propose
an alternative test method or procedures to demonstrate
compliance with the control requirements set forth in
Section 218.501 of this Subpart.
Such method or
procedures shall be approved by the A~encvand USEPA as
evidenced by federally enforceable permit conditions.
(Source:
Added at
_____
Ill. Reg.
______,
effective
______
Section 218.504
Monitoring Requirements for Batch Operations
~j.. Every owner or operator usina an afterburner to comely
with Section 218.501 of this Subpart, shall install.
calibrate, maintain and operate, according to
manufacturer’s specifications, temperature monitoring
devices with an accuracY of ±1 Percent of the
temperature being measured expressed in dearees
Celsius, equipped with continuous recorders.
j~j
Where
a catalytic afterburner is used. temperature
monitoring devices shall be installed in
the
gas
stream immediately before and after the catalyst
bed.
28
al
Where an afterburner other than a catalytic
afterburner
is used,
a temperature monitoring
device shall be
installed in the combustion
chamber.
~
Every owner or operator using a flare to comely with
Section 218.501 of
this Subpart, shall install,
calibrate, maintain and operate,
according to
manufacturer’s specifications,
a heat sensing device,
such as an ultra—violet beam sensor or thermocouple,
at
the pilot light to indicate continuous presence of a
flame.
ci
Every owner or operator using a scrubber to comply with
this Section 218.501 of this Subpart, shall install,
calibrate, maintain, and operate. according to
manufacturer’s specifications, the following:
31
A temperature monitoring device for scrubbant
liquid having an accuracy of ±1 percent of the
temperature being monitored expressed in degrees
Celsius and a specific gravity device for
scrubbant liquid, each equipped with
a continuous
recorder; or
21
A VON monitoring device used to indicate the
concentration of VOM exiting the control device
based on a detection principle such as infra—red
photoionization.
or thermal conductivity, each
equipped with a continuous recorder.
~j
Every owner or operator using a condenser to comply
with Section 218.501 of this Subpart. shall install.
calibrate, maintain, and operate. according to
manufacturer’s specifications, the following:
31
A condenser exit temperature monitoring device
equipped with a continuous recorder and having an
accuracy of ±1 percent of the temperature being
monitored expressed in degrees Celsius; or
21
A VOM monitoring device used to indicate the
concentration of VON such as infra—red.
~hotoionization,
or thermal conductivity, each
equipped with a continuous recorder.
~
Every owner or operator using a carbon adsorber to
com~lvwith this Subpart shall install, calibrate,
maintain.
and operate, according to the manufacturer’s
specifications the following equipment:
31
An integrating regeneration stream flow monitoring
29
device having an accuracy of ±10 percent. and a
carbon bed temperature monitoring device having an
accuracy of ±1 percent of the temperature being
monitored exPressed in degrees Celsius. both
equi~~ed with
a
continuous
recorder;
or
21
A VOM monitoring device used to indicate the
concentration level or VOM exiting such device
based on a detection principle such as infra—red,
photoionization,
or thermal conductivity, each
eguipped with a continuous recorder.
,fj
Every owner or oPerator using a boiler or process
heater with a design heat input capacity less than 44
MW_to_com~lvwith Section 218.501 of this Subpart.
shall install, calibrate, maintain, and operate,
according to the manufacturer’s specifications.
a
temperature monitoring device in the firebox with an
accuracy of ±1 percent of the temperature being
measured expressed in degrees Celsius. equipped with a
continuous recorder.
Any boiler or process heater
in
which all process vent streams are introduced with
primary fuel is exempt from this reauirement.
ci
The owner or operator of a process vent shall be
permitted to monitor by an alternative method or may
monitor Parameters other that those listed in
subsections
(a) through
(f) of this Section.
if
a~~rovedby the Aaencv and USEPA.
Such alternative
method or parameters shall be contained in the source’s
operating permit as federally enforceable permit
conditions.
~
Notwithstanding subsections
(a) through
(g)
of this
Section, sources using a scrubber, shell and tube
condenser using a non—refrigerated cooling media,
or
other control device meeting the criteria of Section
218.501(c)
of this Subpart, are required to monitor
compliance with the requirements of this SubPart on and
after the earlier to occur of the date such device is
replaced for any reason or December 31.
1999.
(Source:
Added at
Ill. Reg.
,
effective
_______
Section 218.505
Reporting and Recordkeepin~for Batch
Operations
~j
Every owner or operator of a de ininimis single unit
operation or batch process train exemPt under Section
218.500(c) (1) or
(c) (2) of this Subpart, shall keep
records of the uncontrolled total annual mass emissions
30
for any de minimis single unit operation or batch
process train,
as applicable,
and documentation
verifying these values or measurements.
The
documentation shall include the enqineering
calculations or measurements coupled with the potential
or permitted number of batch cycles Per year if the
uncontrolled total annual mass emissions is obtained
from measurements made in accordance with Section
218.503 of this Subpart.
~
Every owner or operator of a single unit operation
exemPt under Sections 218.500(b) (3) or
(d) of this
Subpart shall keen the following records:
31
The uncontrolled total annual mass emissions and
documentation verifying these values or
measurements.
The documentation shall include the
calculations or measurements coupled with the
permitted or permitted number of emission events
per year if the uncontrolled total annual mass
emissions is obtained from measurements made in
accordance with Section 218.~503of this Subpart;
and
21
The average flow rate
in scfm and documentation
verifying this value.
ci
Every owner or operator of a batch operation subiect to
the control requirements of Section 218.501 of this
Subpart shall keep records of the following parameters
required to be monitored under Section 218.504 of this
Subpart:
31
If using a thermal or catalytic afterburner to
comply with Section 218.501 of this Subpart.
records indicating the average combustion chamber
temPerature of the afterburner
(or the average
temPerature upstream and downstream of the
catalyst bed for a catalytic afterburner)
measured continuously and averaaed over the same
time period as the performance test
2.1
If using a flare
(i.e.. stream—assisted, air—
assisted or nonassisted) to comply with Section
218.501 of this Subpart. continuous records of the
flare pilot flame monitoring and records of all
periods of operations during which the pilot flame
is absent.
For purposes of determining compliance
with 40 CFR 60.18.
incorporated by reference at
218.112 of this Part.
records shall also be kent
indicating heat content determinations,
flow rate
measurements and the exit velocity determinations.
31
31
If using any of the following as a control device,
the following records:
~
Where a scrubber is used, the exit specific
gravity
(or alternative parameter which is a
measure of the degree of absorbing liauid
saturation,
if a~Provedby the Aaencv) and
the average exit temperature of the absorbing
liquid, measured continuously and averaaed
over the same time period as the performance
test
(both measured while the vent stream
is
routed normally)
~j.
Where a condenser is used, the average exit
(product side)
temperature measured
continuously and averaaed over the same time
period as the performance test while the vent
stream is routed normally
ci
Where a carbon adsorber is used, the total
stream mass flow measured continuously and
averaged over the same time period as the
performance test
(full carbon bed cycle).
temperature of the carbon bed after
regeneration
(and within 15 minutes of
completion of any cooling cycle(s)), and
duration of the carbon bed steaming cycle
(all measured while the vent stream
is routed
normally); or
j~j
As an alternative to subsections
(c) (3) (A).
(c) (3) (B). or
(c) (3) (C)
of this Section, at a
minimum, records indicating the concentration
level or reading indicated by the VON
monitoring device at the outlet of the
scrubber,
condenser, or carbon adsorber,
measured continuously and averaged over the
same time period as the performance test
(while the vent stream is routed normally).
~
Every owner or operator of an single unit operation
claiming a vent stream concentration exemption level,
as set forth in Section 218.500(d) (1) of this Subpart,
shall maintain records to indicate the vent stream
concentration is less than or e~al to 500 ppmv. and
shall notify the Agency in writing if the vent stream
concentration at any time e~a1sor exceeds 500 pPmv.
within 30 days of such event.
Such notification shall
include a copy of all records of such event.
~
owner or operator of a batch operation subiect to
the control requirements of Section 218.501 of this
32
Subpart may maintain alternative records other than
those listed in subsection
(c)
of this Sectthn.
AnY
alternative recordkeepin~shall be approved
bv
the
Agency and USEPA and shall be contained in the source’s
operating permit as federally enforceable permit
conditions.
~j
Notwithstanding subsections
(a) throu~h (f I
of this
Section. anY owner or operator of
a batch operation
which uses either a scrubber,
shell and tube condenser
using non—refriqerated cooling media, or other control
device meeting the criteria of Section 218.501(c)
of
this Subpart, are required to monitor compliance with
the requirements of this Subpart on and after the
earlier to occur of the date such device is replaced
for any reason or December 31,
1999.
~
The owner or operator of a de minimis single unit
qperation or batch process train exempt from the
control requirements of Section 218.501(c) of this
Subpart shall notify the A~encvin writing if the
uncontrolled total annual mass emissions from such de
minimis sing~leunit operation or batch process train
exceed the threshold in Section 218.501(c) (1) or
(c) (2)
of this Subpart. respectively. within 60 days after the
event occurs.
Such notification shall include a copy
of all records of such event.
~
Every owner or operator of a batch operation required
to keep records under this Section shall maintain such
records at the source for a minimum Period of three
y~rs and shall make all such records available to the
Agency upon request.
(Source:
Added at
_____
Ill. Reg.
_______,
effective
_______
Section 218.506
Compliance Date
Every owner or operator of a batch operation subiect to Sections
218.500 through 218.506 of this Subpart shall comply with its
standards.
limitations and mandates by March
15,
1996.
or uPon
initial start up. whichever is later.
(Source:
Added at
_____
Ill. Reg.
_______,
effective
_______
33
TITLE
35:
ENVIRONMENTAL PROTECTION
SUBTITLE B:
AIR POLLUTION
CHAPTER
I:
POLLUTION CONTROL BOARD
SUBCHAPTER
C:
EMISSIONS STANDARDS AND LIMITATIONS
FOR STATIONARY SOURCES
PART
219
ORGANIC MATERIAL EMISSION STANDARDS
AND LIMITATIONS FOR THE
METRO
EAST AREA
SUBPART
A:
GENERAL PROVISIONS
Section
219.100
219.101
219. 102
219.103
219 .104
219.105
219.106
219.107
219. 108
219.109
219.110
219.111
219.112
219.113
219.114
Introduction
Savings Clause
Abbreviations and Conversion Factors
App?icabi1ity
Definitions
Test Methods and Procedures
Compliance Dates
Operation of Afterburners
Exemptions, Variations, and Alternative Means of
Control or Compliance Determinations
Vapor Pressure of Volatile Organic Liquids
Vapor Pressure of Organic Material or Solvents
Vapor Pressure of Volatile Organic Material
Incorporations by Reference
Monitoring for Negligibly—Reactive Compounds
Compliance with Permit Conditions
SUBPART B:
ORGANIC EMISSIONS FROM STORAGE
AND
LOADING OPERATIONS
Section
219.119
219.121
219.122
219.123
219.124
219.125
219.126
Applicability for VOL
Storage Containers
Loading Operations
Petroleum Liquid Storage Tanks
External Floating Roofs
Compliance Dates
(Repealed)
Compliance Plan (Repealed)
SUBPART
C:
ORGANIC
EMISSIONS
FROM
MISCELLANEOUS
EQUIPMENT
Section
219.141
219.142
219.143
219.144
Separation Operations
Pumps and Compressors
Vapor Blowdown
Safety Relief Valves
SUBPART E:
SOLVENT CLEANING
Section
34
219. 181
219. 182
219. 183
219. 184
219. 185
219. 186
Section
219.204
219.205
219.206
219.207
219.208
219.209
219.210
219.211
Section
219.301
219.302
219.303
219.304
Section
219.401
219.402
219.403
219.404
219.405
Section
219.421
219.422
219
•
423
219.424
219.425
219.426
219
•
427
219.428
219.429
219.430
Solvent Cleaning in General
Cold Cleaning
Open Top Vapor Degreasing
Conveyorized Degreasing
Compliance Schedule
(Repealed)
Test Methods
SUBPART
F:
COATING OPERATIONS
Emission Limitations
Daily-Weighted
Average Limitations
Solids Basis Calculation
Alternative Emission Limitations
Exemptions from Emission Limitations
Exemption from General Rule on Use of Organic Material
Compliance Schedule
Recordkeeping and Reporting
SUBPART G:
USE OF ORGANIC MATERIAL
Use of Organic Material
Alternative Standard
Fuel Combustion Emission Units
Operations with Compliance Program
SUBPART H:
PRINTING
AND
PUBLISHING
Flexographic and Rotogravure Printing
Applicability
Compliance Schedule
Recordkeeping and Reporting
Heatset-Web-Offset Lithographic Printing
SUBPART
Q:
LEAKS
FROM SYNTHETIC
ORGANIC CHEMICAL AND
POLYMER
MANUFACTURING
PLANT
General Requirements
Inspection Program Plan for Leaks
Inspection Program for Leaks
Repairing Leaks
Recordkeeping for Leaks
Report for Leaks
Alternative Program for Leaks
Open-Ended Valves
Standards
for Control Devices
Compliance Date (Repealed)
35
SUBPART
R:
PETROLEUM
REFINING
AND
RELATED
INDUSTRIES;
ASPHALT
MATERIALS
Section
219.441
219. 442
219.443
219.444
219.445
219.446
219.447
219.448
219.449
219.450
219.451
219.452
219.453
Petroleum Refinery Waste Gas Disposal
Vacuum Producing Systems
Wastewater
(Oil/Water) Separator
Process Unit Turnarounds
Leaks:
General Requirements
Monitoring Program Plan for Leaks
Monitoring Program for Leaks
Recordkeeping for Leaks
Reporting for Leaks
Alternative Program for Leaks
Sealing Device Requirements
Compliance Schedule for Leaks
Compliance Dates
(Repealed)
SUBPART 5:
RUBBER
AND
MISCELLANEOUS PLASTIC PRODUCTS
Section
219.461
219.462
219.463
219.464
219.465
219.466
Section
219.480
219.481
219.482
219.483
219.484
219.485
219.486
219.487
219.488
219.489
Manufacture of Pneumatic Rubber Tires
Green Tire Spraying Operations
Alternative Emission Reduction Systems
Emission Testing
Compliance Dates
(Repealed)
Compliance Plan (Repealed)
SUBPART T:
PHARMACEUTICAL MANUFACTURING
Applicability
Control of Reactors, Distillation Units, Crystallizers,
Centrifuges and Vacuum Dryers
Control of Air Dryers, Production Equipment Exhaust
Systems and Filters
Material Storage and Transfer
In—Process Tanks
Leaks
Other Emission Units
Testing
Monitoring for Air Pollution Control Equipment
Recordkeeping for Air Pollution Control Equipment
SUBPART V:
BATCH OPERATIONS
AND
AIR OXIDATION PROCESSES
Section
219.500
219.501
219.502
Ap~licabi1itvfor Batch Operations
Control Requirements
for Batch Operations
Determination of Uncontrolled Total Annual Mass
Emissions and Actual Weighted Average Flow Rate Values
for Batch Operations
36
219.503
Performance and Testing Requirements for Batch
Operations
Monitoring Requirements for Batch Operations
Reporting and Recordkeeping for Batch Operations
Compliance Date
Definitions
(Repealed)
Emission Limitations for Air Oxidation Processes
Testing and Monitoring
Compliance Date (Repealed)
SUBPART W:
AGRICULTURE
Section
219.541
Pesticide Exception
SUBPART X:
CONSTRUCTION
Section
219.581
219.582
219.583
219.584
219.585
219.586
Bulk Gasoline Plants
Bulk Gasoline Terminals
Gasoline Dispensing Operations
—
Storage Tank
Operations
Gasoline Delivery Vessels
Gasoline Volatility Standards
Gasoline Dispensing Operations
—
Motor Vehicle
Operations
Filling
Fueling
SUBPART Z:
DRY CLEANERS
Section
219.601
219.602
219.603
219.604
219.605
219.606
219.607
219.608
219 .609
219 .610
219 .611
219 .612
219 .613
Perchloroethylene Dry Cleaners
Applicability
Leaks
Compliance Dates
(Repealed)
Compliance Plan (Repealed)
Exception to Compliance Plan (Repealed)
Standards for Petroleum Solvent Dry Cleaners
Operating Practices for Petroleum Solvent Dry Cleaners
Program for Inspection and Repair of Leaks
Testing and Monitoring
Applicablity for Petroleum Solvent Dry Cleaners
Compliance Dates (Repealed)
Compliance Plan (Repealed)
219.504
219.505
219.506
219.521
219.525
219.526
219.527
Section
219.561
219 .562
219.563
Architectural Coatings
Paving Operations
Cutback Asphalt
SUBPART
Y:
GASOLINE
DISTRIBUTION
SUBPART
AA:
PAINT
AND INK
MANUFACTURING
37
Section
219.620
219.621
219.623
219.624
219.625
219.626
219.628
219.630
219.636
219.637
Section
219.640
219.642
219.644
Applicability
Exemption for Waterbase Material and Heatset-Offset Ink
Permit Conditions
(Repealed)
Open Top Mills, Tanks, Vats or Vessels
Grinding Mills
Storage Tanks
Leaks
Clean Up
Compliance Schedule
Recordkeeping and Reporting
SUBPART BB:
POLYSTYRENE
PLANTS
Applicability
Emissions Limitation at Polystyrene Plants
Emissions Testing
SUBPART CC: POLYESTER RESIN PRODUCT MANUFACTURING PROCESS
Section
219.660
219.666
219.667
219.668
219.670
219.672
Section
219.680
219.686
219.688
219.690
219
.
692
Section
219.760
219. 762
219.764
219.766
219.768
219.770
219.875
219.877
219.879
219.881
219.883
Applicability
Control Requirements
Compliance Schedule
Testing
Recordkeeping and Reporting for Exempt Emission Units
Recorakeeping and Reporting for Subject Emission Units
SUBPART DD: AEROSOL
CAN
FILLING
Applicability
Control Requirements
Testing
Recordkeeping and Reporting for Exempt Emission Units
Recordkeeping and Reporting for Subject Emission Units
SUBPART GG:
MARINE TERMINALS
Applicability
Control Requirements
Compliance Certification
Leaks
Testing and Monitoring
Recordkeeping and Reporting
Applicability of Subpart BB (Renumbered)
Emissions Limitation at Polystyrene Plants
(Renumbered)
Compliance Date (Repealed)
Compliance Plan (Repealed)
Special Requirements for Compliance Plan (Repealed)
38
219.886
Emissions Testing (Renumbered)
SUBPART PP:
MISCELLANEOUS FABRICATED PRODUCT
MANUFACTURING
PROCESSES
Section
219.920
219.923
219.926
219
.
927
219.928
Applicability
Permit Conditions
(Repealed)
Control Requirements
Compliance Schedule
Testing
SUBPART
QQ:
MISCELLANEOUS
FORMULATION
MANUFACTURING PROCESSES
Section
219 .940
219.943
219 .946
219.947
219 .948
App?icabi1ity
Permit Conditions
(Repealed)
Control
Requirements
Compliance Schedule
Testing
SUBPART RR:
MISCELLANEOUS ORGANIC CHEMICAL MANUFACTURING
PROCESSES
Section
219
•
960
219.963
219.966
219.967
219.968
Section
219.980
219.983
219.986
219.987
219.988
Section
219.990
219.991
Section
Section
Applicability
Permit Conditions (Repealed)
Control Requirements
Compliance Schedule
Testing
SUBPART
TT:
OTHER EMISSION
UNITS
App?icabi1ity
Permit Conditions (Repealed)
Control Requirements
Compliance Schedule
Testing
SUBPART UU:
RECORDKEEPING
AND
REPORTING
Exempt Emission Units
Subject Emission Units
219~.AppendixA:
List of Chemicals Defining Synthetic
Organic Chemical and Polymer
Manufacturing
219.Appendix B:
VOM Measurement Techniques for Capture
Efficiency
39
Section 219.Appendix C:
Reference Test Methods for Air Oxidation
Processes
Section 219.Appendix
D:
Coefficients for the Total Resource
Effectiveness
Index
(TRE)
Equation
Section 219.Appendix
E:
List of Affected Marine Terminals
AUTHORITY:
Implementing Section
10 and authorized by Section
28.5 of the Environmental Protection Act
(Ill.
Rev.
Stat.
1991,
ch.
111½, par.
1010)
(P.A.
87—1213, effective September 26,
1992)
415
ILCS 5/10 and 28.5.
SOURCE:
Adopted at R91-7 at 15
Ill.
Reg.
12231,
effective August
16,
1991;
amended in R91—23 at 16 Ill. Reg.
13564, effective
August 24,
1992; amended in R91—28 and R91—30 at
16 Ill. Reg.
13864,
effective August 24,
1992; amended in R93—9 at 17 Ill.
Reg.
16636,
effective September 27,
1993; amended in R93-14 at 18
Ill. Reg. at 1945, effective January 24,
1994; amended in R94-12
at
18 Ill. Reg.
14973, effective September 21,
1994; amended in
R94-l5 at
18
Ill.
Reg.
16379, effective November
‘4,
1994; amended
in R94—j~at ~
Ill. Reg.
,
effective
_________________;
amended in R94-~at
)~
Ill.
Reg.
,
effective
____________
SUBPART V:
BATCH OPERATIONS
AND
AIR OXIDATION PROCESSES
Section 219.500
Applicability for Batch Operations
~j
The control requirements set forth
in Section 219.501
of this Subpart shall apply to:
1)..
Process vents associated with batch operations at
sources identified by any of the following four—
digit standard industrial classification (“SIC”I
codes, as defined in the 1987 edition of the
Federal Standard Industrial Classification Manual:
SIC 2821,
2833,
2834,
2861.
2865,
2869,
and 2879~
and
~j
All batch operations at Stepan Company’s Millsdale
manufacturing facility, Elwood, Illinois.
~j
The requirements of Sections 219.500 through 219.506
shall not a~p1yto:
jj.
Any
emission unit included within the category
specified in 35
Ill.
Adm.
Code Part 219, Subparts
BorT
~j
Any emission unit included within the category
specified in Sections 219.520 through 219.527 of
this Subpart; and
40
~j.
Any emission unit included
within an Early
Reduction Program,
as specified
in
40 CFR Part
63.
and published in
57 Fed. Req.
61970
(December 29,
1992), evidenced by a timely enforceable
commitment approved by USEPA.
~j
The following single unit operations and batch process
trains are subject to this Subpart but are considered
to be de minimis and are,
therefore, exempt from the
control requirements of Section 219.501 of this
Subpart.
However, .the recordkeeping and reporting
requirements in Section 219.505 of this Subpart shall
apply to_such de minimis single unit operations and
batch process trains:
fl
Within a batch operation, any single unit
operation with uncontrolled total annual mass
emissions of less than or equal to 500 lb/yr of
VOM.
Such single unit operations are also
excluded from the calculation of the total annual
mass emissions for a batch process train.
If the
uncontrolled total annual mass emissions from such
exempt single unit operation exceed 500 lb/yr of
VON in any subsequent year,
the source shall
calculate applicability in accordance with
subsection
(d) of this Section for both the
individual single unit operation and the batch
process train containing the single unit
operation;
and
21
Any batch process train containing process vents
that have,
in the aggregate, uncontrolled total
annual mass emissions,
as determined in accordance
with Section 219.502(a) of this Subpart’, of less
than 30,000 lb/yr of VOM for all products
manufactured in such batch process train.
~J
The
applicability
equations
in
subsection
(e)
of
this
Section. which require the calculation of uncontrolled
total annual mass emissions and flow rate value, shall
be used to determine whether a single unit operation or
a_batch_process train is subject to the control
requirements set forth in Section 219.501 of this
Subpart. The applicability equation shall be applied to
the following:
il
Any single unit operation with uncontrolled total
annual mass emissions that exceed 500 lb/yr and
with a VOM concentration greater than 500 ppmv.
In this individual determination, no applicability
analysis shall be performed for any single unit
operation with a VOM concentration of less than or
41
equal to 500 ppmv; and
21
Any batch process train containing process vents
which,
in the aggregate, have uncontrolled total
annual mass emissions of 30,000 lb/yr or more of
VON from all products manufactured in the batch
process train.
Any
single unit operation with
uncontrolled total annual mass emissions exceeding
500 lb/yr.
regardless of VON concentration,
shall
be included in the aggregate applicability
analysis.
gj
Applicability equations
fl.
The
applicability equations in this subsection are
specific to volatility.
21
For purposes of this subsection, the following
abbreviations apply:
=
Vent stream flow rate, scfm
~j
UTANE
=
Uncontrolled total annual mass
emissions of VON, expressed as
ib/yr
=
Weighted average volatility
~
MV~Q~
=
Mass of VOM component 1; and
~j
MWVOM~=
Molecular weight of VOM component
i; and
fi
3~
=
Vapor pressure of VOM component
i.
fl
Weighted average volatility shall be calculated as
follows:
n
(MVOM~)
E
((VP1)x
1=1
(
(MWVOM~)
WAV
=
__________________
n
(MVON~)
)
i=1
(MWVOM~)
)
For purposes of determining applicability, flow
rate values shall be calculated as follows:
~j
Low WAV has
a vapor pressure less than or
equal to 75
minHq at 20°C
(68°F), and shall
42
use the following equation:
FR
=
fO.07
(UTANE)1
—
1,821
~
Moderate WAV has a vapor pressure greater
than 75 mmH~but less than or egual to 150
mmH~
at
20°C(68°F),and shall use the
following
equation:
FR
=
0.031
(UTAME)1
—
494
Q1
High WAV has a vapor pressure greater than
150
mixiNg
at 20°C(68°F),and shall use the
following equation:
FR
=
0.013
(UTANE)1
—
301
~j
To determine the vapor pressure of VON, the
applicable methods and procedures in Section
219.111 of this Part shall apply.
(Source:
Added at
Ill.
Reg.
effective
_______
S~ctjon219.501
Control Requirements for Batch Operations
~
Every owner or operator of a single unit operation with
an average flow rate, as determined in accordance with
Section 219.502(b)
of this Subpart. below the flow rate
value calculated by the applicability equations
contained in Section 219.500(e)
of this Subpart,
shall
reduce uncontrolled VON emissions from such single unit
operation by an overall efficiency. on average, of at
least 90 percent, or 20 ppmv, per batch cycle.
~
Every owner or operator of a batch process train with
an average flow rate,
as determined in accordance with
Section 219.502(b) (2)
of this Subpart, below the flow
rate value calculated by the applicability equations
contained in Section 219.500(e)
of this Subpart, shall
reduce uncontrolled VOM emissions from such batch
process train by an overall efficiency,
on average, of
at least 90 percent. or 20 p~mv.per batch cycle.
For
purposes of demonstrating compliance with the emission
limitations set forth in this Section, any control
device meeting the criteria in subsection
(c) of this
Section shall be deemed to achieve a control efficiency
of 90 percent. or 20 ~
per batch cycle, as
applicable.
~j
Notwithstanding subsections
(a) or
(b) of this Section,
any source that has installed on or before March 15.
43
1995,
any
control
device
which
is
demonstrated
to
the
Agency’s satisfaction to be unable to meet the
applicable control requirements
of this Section,
scrubber, or shell and tube condenser using a non—
refrigerated cooling media,
and such device achieves at
least
81 percent control efficiency of VON emissions~
is required to meet the 90 percent emission limitation
or 20 ppmv VOM concentration set forth in subsections
(a)
or
(b)
of this Section, as applicable, upon the
earlier to occur of the date the device is replaced for
any reason,
including, but not limited to. normal
maintenance, malfunction,
accident, and obsolescence~
or_December
31,
1999.
A scrubber, shell and tube
condenser using a non—refrigerated cooling media,
or
other control device meeting the criteria of this
subsection
is considered replaced when:
fl.
All of the device is replaced; or
21
When either the cost to repair the device or the
cost to replace part of the device exceeds 50
percent of the cost of replacing the entire device
with a control device that complies with the 90
percent emission limitation or 20 p~mvVON
concentration level in subsection
(a)
of this
Section, as applicable.
~j.
If a boiler or process heater is used to comply with
this Section, the vent stream shall be introduced into
the flame zone of the boiler or process heater.
~j
If a flare is used to comply with this Section.
it
shall comply with the requirements of 40 CFR 60.18,
incorporated by reference at Section 219.112 of this
Part.
The flare operation requirements of 40 CFR 60.18
do not apply if a process, not subject to this Subpart,
vents an emergency relief discharge into a common flare
header and causes the flare servicing the process
subiect to this Subpart to not comply with one or more
of the provisions of 40 CFR 60.18.
(Source:
Added at
_____
Ill. Reg.
,
effective
_______
F
Section 219.502
Determination of Uncontrolled Total Annual
Mass Emissions and Actual Weighted Average
Flow Rate Values for Batch Operations
~j
Uncontrolled total annual mass emissions shall be
determined by the following methods:
fl
Direct process vent emissions measurements taken
44
prior to any release to the atmosphere,
following
any recovery device and prior to any control
device, provided such measurements conform with
the requirements of measuring the mass flow rate
of VOM incoming to the single unit operation as
set forth in Section 219.5031f)L2),
(f)(3)(A) and
(f)
(3)
(B)
of
this
Subpart;
or
21
Engineering estimates of the uncontrolled VOM
emissions from a process vent or process vents,
in
the aggregate, within
a batch process train,
multiplied by the potential or permitted number of
batch cycles per year as follows:
~j
Engineering estimates of the uncontrolled VOM
emissions shall be based upon accepted
chemical engineering principles, measurable
process parameters,
or physical or chemical
laws and their properties.
Examples of
methods include, but are not limited to, the
following:
j)
Use of material balances based on
process stoichiometry to estimate
maximum VON concentrations
~jJJ.
Estimation of maximum flow rate based on
physical equipment design such as
pump
or blower capacities; and
iii) Estimation of VON concentrations based
on saturation conditions.
~
All data,
assumptions and procedures used in
any engineering estimate shall be documented.
~j
Average flow rate shall be determined by any of the
following methods:
~j
Direct process vent flow rate measurements taken
prior to any release to the atmosphere.
following
any recovery device and prior to any control
device, provided such measurements conform with
the requirements of measuring incoming volumetric
flow rate set forth in Section 219.503(e) (2)
of
this Subpart
~
Average flow rate for a single unit operation
having multiple emission events or batch process
trains shall be the weighted average flow rate,,
calculated as follows:
45
n
~ JAFR~
x ADE~jJ
i1
WAF
=
_____________
n
E
(ADE1j
i=.
where:
=
Actual weighted average flow
rate for a single unit
operation or batch process
train
=
Average flow rate per emission
event;
ADE~
=
Annual duration of emission
event; and
=
Number of emission events.
fl
Engineering estimates calculated in accordance
with the requirements in subsection
(a) (2)
of this
Section.
~j
For purposes of determining the average flow rate for
steam vacuuming systems, the steam flow shall be
included in the average flow rate calculation.
(Source:
Added at
_____
Ill.
Reg.
,
effective
_______
Section 219.503
Performance and Testing Requirements for
Batch Operations
~j
Upon the Agency’s request. the owner or operator of a
batch operation shall conduct testing to demonstrate
compliance with Section 219.501 of this Subpart.
The
owner_or operator shall,
at its
own
expense,
conduct
such tests in accordance with the applicable test
methods and procedures specified in Section 219.503(d),
(e)
•
and
(f) of this Subpart.
~j
Notwithstanding subsection
(a)
of this Section.
flares
and_process boilers used to comply with control
requirements of Section 219.501 of this Subpart shall
be exempt from performance testing requirements.
~j
When a flare is used to com~1ywith the control
requirements of Section 219.501 of this Subpart, the
flare shall comply with the requirements of 40 CFR
60.18. incorporated by reference at Section 219.112 of
this Part.
46
~
The
owner
or
operator
of
a batch operation that is
exempt from the control requirements of Section 219.501
of
this
Subpart
shall
demonstrate,
upon
the
Agency’s
request,
the absence of oversized gas moving equipment
in any manifold.
Gas moving equipment shall be
considered oversized
if
it exceeds the maximum
requirements of the exhaust flow rate by more than 30
percent.
~j
For the purpose of demonstrating compliance with the
control requirements in Section 219.501 of this
Subpart, the batch operation shall be run at
representative operating conditions and flow rates
during any performance test.
~J.
The following methods in 40 CFR 60, Appendix A,
incorporated by reference at Section 219.112 of this
Part,
shall be used to demonstrate compliance with the
reduction
efficiency
requirement
set
forth
in
Section
219.501 of this Subpart:
fl
Method
1 or 1A.
as apøropriate.
for selection of
the samplina sites
if the flow measuring device is
not a rotameter.
The control device inlet
sampling site for determination of vent stream VON
composition reduction efficiency shall be prior to
the control device and after the control device
21
Method 2,
2A.
2C. or 2D. as appropriate.
for
determination of gas stream volumetric flow rate
flow measurements, which shall be taken
continuously.
No traverse is necessary when the
flow measuring device is an ultrasonic probe
.
fl
Method 25A or Method 18,
if applicable,
to
determine the concentration of VOM in the control
device inlet and outlet:
~J.
The sampling time for each run will be the
entire length of the batch cycle in which
readings shall be taken continuously,
if
Method 25A is used,
or as often as is
possible using Method 18.
with a maximum of
15—minute intervals between measurements
throughout the batch cycle
~j
The mass emission rate from the process vent
or inlet to the control device shall be
determined by combining concentration and
flow rate measurements taken simultaneously
at samp1in~sites selected in accordance with
subsection
(f) (1)
of this Section throughout
47
the batch cycle~
~j
The mass emission rate from the control
device outlet shall be obtained by combining
concentration and flow rate measurements
taken simultaneously at sampling sites
selected in accordance with subsection
(f) (1)
of this Section throughout the batch cycle
and
DI
The efficiency of the control device shall be
determined by integrating the mass emission
rates_obtained in subsections
(c) (3) (A)
and
(c)
L3~
(B) of this Section.
over the time of
the batch cycle and dividing the difference
in inlet and outlet mass flow totals by the
inlet mass flow total.
gi
Upon request by the Agency to conduct testing, an owner
or operator of a batch operation which has installed a
scrubber,
a shell and tube condenser using a non—
refrigerated cooling media,
or any other control device
which meets the criteria of Section 219.501(c)
of this
Subpart, shall demonstrate that such device achieves
the control efficiency applicable within Section
219.501 of this Subpart upon the earlier to occur of
the date the device is replace or December 31,
1999.
~
The owner or operator of a batch operation may propose
an alternative test method or procedures to demonstrate
compliance with the control requirements set forth in
Section 219.501 of this Subpart.
Such method or
procedures shall be approved by the Agency and USEPA as
evidenced by federally enforceable permit conditions.
(Source:
Added at
_____
Ill. Reg.
,
effective
_______
Section 219.504
Monitoring Requirements for Batch Operations
~j
Every owner or operator using an afterburner to comply
with Section 219.501 of this Subpart. shall install,
calibrate, maintain and operate, according to
manufacturer’s specifications, temperature monitoring
devices with an accuracy of ±1 percent of the
temperature being measured expressed in degrees
Celsius. equipped with continuous recorders.
~j
Where
a catalytic afterburner is used, temperature
monitoring devices shall be installed in the gas
stream immediately before and after the catalyst
bed.
48
21
Where
an afterburner other than a catalytic
afterburner is used,
a temperature monitoring
device shall be installed in the combustion
chamber.
ki
Every
owner
or operator using a flare to comply with
Section 219.501 of this Subpart, shall install,
calibrate, maintain and operate,
according to
manufacturer’s specifications,
a heat sensing device,
such as an ultra—violet beam sensor or thermocouple, at
the pilot light to indicate continuous presence of a
flame.
~j
Every owner or operator using a scrubber to comply with
this Section 219.501 of this Subpart,
shall install,
calibrate, maintain, and operate. according to
manufacturer’s
specifications,
the
following:
fl.
A temperature monitoring device for scrubbant
liquid having an accuracy of ±1 percent of the
temperature being monitored expressed in degrees
Celsius and a specific gravity device for
scrubbant liquid, each equipped with a continuous
recorder; or
21
A VOM monitoring device used to indicate the
concentration of VOM exiting the control device
based on a detection ~rincip1e such as infra—red
photoionjzation, or thermal conductivity, each
equipped with a continuous recorder.
~j.
Every owner or operator using a condenser to comply
with Section 219.501 of this Subpart, shall install,
calibrate, maintain, and operate,
according to
manufacturer’s specifications, the following:
~j
A condenser exit temperature monitoring device
equipped with a continuous recorder. and having an
accuracy of ±1 percent of the temperature being
monitored expressed
in degrees Celsius; or
21
A VON monitoring device used to indicate the
concentration of VOM such as infra—red.
photoionization, or thermal conductivity, each
equipped with a continuous recorder.
~
Every owner or operator using a carbon adsorber to
comply with this Subpart shall instalL calibrate,
maintain, and operate, according to the manufacturer’s
specifications the following equi~ment:
An integrating regeneration stream flow monitoring
49
device having an accuracy of ±10 percent. and a
carbon bed temperature monitoring device having an
accuracy of ±1 percent of the temperature being
monitored expressed in degrees Celsius. both
e~jpped with a continuous recorder; or
21
A
VON
monitoring
device
used
to
indicate
the
concentration level or VOM exiting such device
based on
a detection principle such as infra—red,
photoionization. or thermal conductivity, each
equipped with a continuous recorder.
fl
Every owner or operator using a boiler or process
heater with a design heat input capacity less than 44
Mw_to_comply with Section 219.501 of this Subpart.
shall
install, calibrate, maintain, and operate,
according to the manufacturer’s specifications,
a
temperature monitoring device in the firebox with an
accuracy of ±1 percent of the temperature being
measured expressed in degrees Celsius.
equipped with
a
continuous recorder.
Any boiler or process heater in
which all process vent streams are introduced with
primary fuel is exempt from this requirement.
gi
The owner or operator of
a process vent shall be
permitted to monitor by an alternative method or may
monitor parameters other that those listed in
subsections
(a) through
(f) of this Section,
if
approved by the Agency and USEPA.
Such alternative
method or parameters shall be contained in the source’s
operating permit as federally enforceable permit
conditions.
~j
Notwithstanding subsections
(a) through
(g)
of this
Section. sources using a scrubber,
shell and tube
condenser using a non—refrigerated cooling media, or
other control device meeting the criteria of Section
219.501(c)
of this Subpart, are required to monitor
compliance with the requirements of this Subpart on and
after the earlier to occur of the date such device is
replaced for any reason or December 31,
1999.
(Source:
Added at
_____
Ill. Reg.
,
effective
_______
Section 219.505
Reporting and Recordkeepincz for Batch
Operations
~j
Every owner or operator of a de mirtimis single unit
operation or batch process train exempt under Section
219.500(c) (1) or
(c) (2) of this Subpart, shall keep
records of the uncontrolled total annual mass emissions
50
for any de ininiinis
single unit operation or batch
process train,
as
applicable, and documentation
verifying these values or measurements.
The
documentation shall include the engineering
calculations or measurements coupled with the potential
or permitted
number
of batch cycles per year if the
uncontrolled total annual mass emissions is obtained
from measurements made in accordance with Section
219.503 of this Subpart.
ki
Every owner or operator of
a single unit operation
exempt under Sections 219.500(b) (3)
or
(d)
of this
Subpart_shall keep the following records:
fl~.
The uncontrolled total annual mass emissions and
documentation verifying these values or
measurements.
The documentation shall include the
calculations or measurements coupled with the
permitted or permitted number of emission events
per year if the uncontrolled total annual mass
emissions is obtained from measurements made in
accordance with Section 219.503 of this Subpart
and
21
The average flow rate in scfm and documentation
verifying this value.
gj
Every owner or operator of a batch operation subject to
the control requirements of Section 219.501 of this
Subpart shall keep records of the following parameters
required to be monitored under Section 219.504 of this
Subpart:
fl.
If using a thermal or catalytic afterburner to
comply with Section 219.501 of this Subpart,
records indicating the average combustion chamber
temperature of the afterburner
(or the average
temperature upstream and downstream of the
catalyst bed for a catalytic afterburner).
measured continuously and averaged over the same
time period as the performance test
21
If using a flare
(i.e.. stream—assisted, air—
assisted or nonassisted)
to comply with Section
219.501 of this Subpart, continuous records of the
flare pilot flame monitoring and records of all
periods of operations during which the oilot flame
is absent.
For purposes of determining compliance
with 40 CFR 60.18, incorporated by reference at
219.112 of this Part, records shall also be kept
indicating heat content determinations, flow rate
measurements and the exit velocity determinations.
51
~J
If
using
any
of
the
following
as
a control device,
the following records:
~
Where a scrubber is used,
the exit specific
gr~avity(or alternative parameter which is a
measure of the degree of absorbing liquid
saturation,
if a~~rovedby the Agency)
and
the average exit temperature of the absorbing
liquid, measured continuously and averaged
over the same time period as the performance
test
(both measured while the vent stream is
routed normally)
~j
Where a
condenser is used, the average exit
(product side) temperature measured
continuously and averaged over the same time
period as the performance test while the vent
stream is routed normally:
~j
Where a carbon adsorber is used,
the total
stream mass flow measured continuously and
averaged over the same time period as the
performance test (full carbon bed cycle).
temoerature of the carbon bed after
regeneration (and within 15 minutes of
completion of any cooling cycle(s)), and
duration of the carbon bed steaming cycle
(all measured while the vent stream is routed
normally): or
DI
As an alternative to subsections
(c) (3) (A).
I
c)(3)(B). or (c)(3)(C) of this Section.
at a
minimum, records indicating the concentration
level or reading indicated by the VON
monitoring device at the outlet of the
scrubber, condenser,
or carbon adsorber.
measured continuously and avera~edover the
same time period as the performance test
(while the vent stream is routed normally).
~L
Every owner or operator of an single unit operation
claiming a vent stream concentration exemption level.
as set forth in Section 218.500(d) (11
of this Subpart,
shall maintain records to indicate the vent stream
concentration is less than or e~al to 500 ~pmv. and
shall notify the Agency in writing if the vent stream
concentration at any time equals or exceeds 500 ppmv.
within 30 days of such event.
Such notification shall
ii’iclude a copy of all records of such event.
An owner or operator of a batch operation subject to
the control requirements of Section 219.501 of this
52
Subpart may maintain
alternative
records other than
those listed in subsection
Cc)
of this Section.
Any
alternative recordkeeping shall be approved by the
Agency and USEPA and shall be contained in the source’s
operating permit as federally enforceable permit
conditions.
ZJ
Notwithstanding subsections
(a) through
(f)
of this
Section, any owner or operator of a batch operation
which uses either a scrubber, shell and tube condenser
using non—refrigerated cooling media,
or other control
device meeting the criteria of Section 219.501(c)
of
this Subpart.
are required to monitor compliance with
the requirements of this Subpart on and after the
earlier to occur of the date such device is replaced
for any reason or December 31.
1999.
gj
The owner or operator of a de minimis single unit
operation or batch process train exempt from the
control requirements of Section 219.501(c)
of this
Subpart shall notify the Agency in writing if the
uncontrolled total annual mass emissions from such de
minimis single unit operation or batch process train
exceed the threshold in Section 219.501(c) (1)
or (c)(2)
of this Subpart, respectively, within 60 days after the
event occurs.
Such notification shall include a copy
of all records of such event.
~
Every owner or operator of a batch operation required
to keep records under this Section shall maintain such
records at the source for a
minimum
period of three
years and shall make all such records available to the
Agency upon request.
(Source:
Added at
Ill. Reg.
_______,
effective
_______
Section 219.506
Compliance Date
Every owner or operator of a batch operation subject to Sections
219.500 through 219.506 of this Subpart shall com~lvwith its
standards,
limitations and mandates by March 15. 1996,
or upon
initial start up. whichever is later.
(Source:
Added at
_____
Ill. Reg.
_______,
effective
_______
IT IS SO ORDERED.
53
I, Dorothy M.
Gunn, Clerk of the Illinois Pollution Control
Board, hereby certify that the above opinion and order was
adopted on the
/~~-1 day of
~
,
1994,
by a vote
of
~-C.
~
~
/1t
~
Dorothy M./~Gunn, Clerk
Illinois P~llutionControl Board