ILLINOIS POLLUTION CONTROL BOARD
June
11,
1991
IN THE
MATTER
OF:
)
)
RACT DEFICIENCIES IN THE
)
METRO-EAST AREA:
AMENDMENTS
)
R91-8
TO 35 ILL.ADN.CODE PART 215
)
(Rulemaking)
AND
THE ADDITION OF PART 219
)
PROPOSED RULE.
SECOND NOTICE.
OPINION
AND
ORDER OF THE BOARD
(by J. Theodore Meyer):
This matter is before the Board on a regulatory proposal filed
by
the
Illinois
Environmental
Protection
Agency
(Agency).
Additionally, on June 3,
1991, the Agency filed a motion to amend
the proposal.
The Board
today
takes
action on that motion
to
amend,
and proposes these
rules for second notice.
This opinion
and
order
will
contain
only
the
procedural
history
of
this
proceeding and the text of the rules themselves.
The Board will
issue a supplemental opinion shortly.
Procedural History
On January
17,
1991,
the
Agency
filed
this
proposal
for
rulemaking.
The proposal seeks to correct deficiencies identified
by the United States Environmental Protection Agency
(USEPA)
in
Illinois’ state implementation plan
(SIP)
for ozone in the Metor-
East area,
and contains regulations requiring the implementation
of
reasonably
available
control
technology
(RACT)
for
certain
sources
of
volatile
organic
material
(VOM).
The
proposed
regulations
are
intended to
identical
in effect to the
federal
implementation
plan
(FIP)
promulgated
by
the
United
States
Environmental Protection Agency (USEPA)
for the Chicago area.
(55
Fed. Reg.
26814, June 29,
1990.)
The Board accepted the proposal
for hearing
on February
7,
1991.
The Board
also accepted the
Agency’s certification that this rulemaking is federally required
pursuant to Section 282 of the Environmental Protection Act
(Act)
(Ill.Rev.Stat.
1989,
ch. 111 1/2, par. 1028.2), as amended by PA.
86—1409.
The Board sent the rules,
as proposed by the Agency, to
first notice on February 28, 1991.
The rules were published in the
Illinois Register on March 15, 1991, at 15 Ill.Reg. 3892.
On March
28,
1991,
the
Board
found
that
no
economic
impact
study
was
necessary in this proceeding.
Hearings were held on April
10 and
15,
1991.
The
first notice
comment period
in this
rulemaking
expired on April 29,
1991.
On Nay 2,
1991, the Agency filed a motion to suspend emergency
rulemaking.
The Board had previously expressed its intention to
2
proceed
with
these
proposed
rules
on
an
emergency
basis,
as
provided by Section 5.02 of the Administrative Procedure Act (APA)
(Ill.Rev.Stat.
1989,
ch.
127,
par.
1005.02) and Section 27(c)
of
the Act.
The Board intended to adopt the rules on an emergency
basis in order to meet the May 15,
1991 deadline set forth in the
federal Clean Air Act Amendments of 1990,
and also proceed with
“regular”
rulemaking.
The Agency moved that the Board suspend
consideration of the proposal as an emergency rulemaking, alleging
that the proposal was not appropriate
for emergency rulemaking.
Among
other things,
the Agency noted that a representative from
USEPA
had
stated
at
hearing
that
USEPA
believed
that
only
“permanent” rules were sufficient to meet the May 15 deadline, and
that USEPA did not view emergency rules to be “permanent”.
On May
3,
1991, the Illinois Environmental Regulatory Group
(IERG)
filed
a motion in support of the Agency’s motion to suspend emergency
rulemaking.
IERG stated that emergency rules would be a “futile”
attempt to meet the May
15
date.
IERG also stated that
it was
involved
in
serious
negotiations with USEPA
and
the Agency
on
points of disagreement in these proposed rules.
At a May 6,
1991
Board meeting,
the Board deferred action on the motion for one
week,
in
order
to
allow
the
participants
additional
time
to
continue discussions with USEPA.
On May
13,
1991,
the Agency
filed
a
status
report
and
a
“motion to extend first notice”.
The Agency updated that Board on
the continuing discussions between USEPA,
IERG,
and the Agency.
The Agency
stated that the negotiations involved discussions
on
maximum theoretical emissions
(MTE),
compliance and applicability
dates for the proposed rules, and the rules proposed as Subpart TT.
The status report included a letter from Stephen Rothblatt,
Chief
of the Regulation Development Branch for Region V of USEPA.
That
letter
confirmed
that
USEPA
was
involved
with
“serious”
negotiations with IERG and the Agency.
The Agency moved that the
Board delay moving
into second notice
until May
30,
1991.
The
Agency
contended
that
it
looked
very
favorable
that
all
participants would reach an agreement, and noted that if the Board
moved to second notice before the completion of the negotiations,
it would
be unable
to make changes
in the proposed rule
(as a
result of any agreement)
without returning to first notice.
The
Agency noted that Illinois
is working within a very tight time
frame for this rulemaking,
so that there would be no time to return
to first notice.
The Agency summarized:
Therefore,
despite the Agency’s earlier,
fervent pleas
that the Board
go to second
notice May
9,
1991,
the
Agency requests that the Board delay second notice until
May 30,
1991.
Once the Board goes to second notice, no
changes,
other than
in response to comment
from
the
Joint Committee on Administrative Rules)
JCAR,
can be
made to the rules.
The Agency,
then, would submit the
rules
at
second
notice
to
USEPA
as
our
state
implementation plan
SIP.
We would supplement the SIP
3
submittal with the final rules once they are promulgated.
These
activities
should
have
the
effect
of
having
Illinois
removed
from
the
deficiency
list
prior
to
publication
while
at
the
same
time
allowing
the
negotiating
parties
the
opportunity
to
complete
negotiations.
(Agency motion to extend first notice,
p. 6)
On May 14,
1991,
in reliance on the statements and requests made
by the Agency,
IERG,
and USEPA,
the Board granted the Agency’s
motions to suspend emergency rulemaking and to delay second notice
until after May 30,
1991.
Motion to Amend Proposal
On
June
3,
1991,
the Agency
filed
a
motion
to amend
its
proposal.
The proposed amendments are a result of the negotiations
between
the
Agency,
USEPA,
and
IERG.
The Agency
states
that
although no formal agreement has yet been reached between the three
participants, the Agency believes that the proposed amendments are
approvable
by
USEPA.
The
Agency
suggests
amendments
to
the
definition of MTE (Section 219.104), the addition of a definition
of “rolling limit” (Section 219.104), changes to the applicability
and
compliance
date provisions
(Sections 219.103
and
219.106),
amendments to the applicability provisions of Subpart TT (Section
219.980),
and
revisions
to
the
testing
provisions
in
non-CTG
categories
in
Subparts
PP,
QQ,
RR,
and
TT
(Sections
219.105,
219.928,
219.948,
219.968,
219.988,
and
219.991).
The Agency
maintains that these proposed amendments are in the best interests
of
the
State
and
will
result
in
no
negative
impact
on
the
environment.
The Agency states that the amendments are the product
of great effort to produce an acceptable and effective SIP revision
for the State.
Although USEPA has not yet indicated that it can
approve all of the suggested revisions,
the Agency believes that
ultimate approval by USEPA can be obtained.
IERG filed a motion in support of the Agency’s motion to amend
the proposal on June
4,
1991.
IERG states that it supports the
suggested amendments,
and agrees with the reasons given
by the
Agency.
IERG maintains that although it and USEPA have been unable
to reach a settlement,
IERG believes that the amendments proposed
by the Agency are federally approvable.
Thus,
IERG asks that the
Board adopt
second notice of the proposed
rules,
including the
Agency’s suggested amendments.
After a review of the pleadings, the Board grants the Agency’s
motion to amend its proposal.
Based on the statements made by the
Agency and IERG,
the Board believes that the proposed amendments
are federally approvable,
and will protect the viability of the
various federal court appeals of the FIP, on which these proposed
rules
are
based.
Language added
to the rules
is indicated by
4
underlining, while deletions are shown by strike-throughs.
Many of the motions and other
filings received during the
course of this proceeding have urged the Board to act as quickly
as possible.
The Board shares the participants’ concern for timely
action,
and
has
expedited
this
proceeding.
Because
of
its
sensitivity to quick action, the Board today proposes these rules,
as amended,
for second notice.
The Board does so only eight days
after the Agency filed its motion to amend.
This short time period
has not allowed preparation of a full opinion to accompany the
proposed rules.
Although the Board usually delays adoption of
rules
until
a
complete
opinion
is
prepared,
the
unusual
circumstances of this proceeding merit a change
in this policy.
As stated above, today the Board proceeds to second notice of these
proposed rules.
The Board will
issue
a
supplemental opinion
as
soon as possible.
Additionally. the Board notes that it has made
no
attempt
to
address
any
possible
drafting
problems
in
the
A~ency’si~roposalwhich may be of concern to JCAR.
ORDER
The Board hereby proposes the following amendments for second
notice,
to be
filed
with the Joint
Committee on Administrative
Rules:
TITLE 35:
ENVIRONMENTAL PROTECTION
SUBTITLE
B:
AIR POLLUTION
CHAPTER
I:
POLLUTION CONTROL BOARD
SUBCHAPTER c:
EMISSIONS STANDARDS
AND
LIMITATIONS FOR STATIONARY SOURCES
PART 215
ORGANIC MATERIAL EMISSION STANDARDS AND LIMITATIONS
SUBPART A:
GENERAL
PROVISIONS
Section
215.100
Introduction
215.101
Clean-up and Disposal Operations
215.102
Testing Methods
215.103
Abbreviations and Conversion Factors
215. 104
Definitions
215.105
Incorporations by Reference
215.106
Afterburners
215.107
Determination of Applicability
SUBPART
B:
ORGANIC EMISSIONS FROM STORAGE
AND
LOADING
OPERATIONS
Section
215.121
Storage Containers
215.122
Loading Operations
215.123
Petroleum Liquid Storage Tanks
5
External Floating Roofs
Compliance Dates and Geographical Areas
Compliance Plan
Emissions Testing
Measurement of Seal Gaps
SUBPART
C:
ORGANIC
EMISSIONS FROM
MISCELLANEOUS EQUIPMENT
Separation Operations
Pumps
and Compressors
Vapor Blowdown
Safety Relief Valves
SUBPART
E:
SOLVENT CLEANING
Section
215.181
215. 182
215.183
215.184
215.185
Section
215.202
215.204
215.205
215.206
215.207
215.208
215.209
215.210
215.211
215.212
215.213
215.214
Solvent Cleaning in General
Cold Cleaning
Open Top Vapor Degreasing
Conveyorized Degreasing
Compliance Plan
SUBPART F:
COATING OPERATIONS
Compliance Schedules
Emission Limitations for Manufacturing Plants
Alternative Emission Limitations
Exemptions from Emission Limitations
Compliance by Aggregation of Emission Sources
Testing Methods for Volatile Organic Material Content
Exemption from General Rule on Use of Organic Material
Alternative Compliance Schedule
Compliance Dates and Geographical Areas
Compliance Plan
Special Requirements for Compliance Plan
Roadmaster Emissions Limitations
SUBPART
Section
215.240
215.241
215.245
215.249
Section
215.260
H:
SPECIAL LIMITATIONS FOR SOURCES IN
MAJOI~URBANIZED
AREAS WHICH
ARE NONATTAINMENT FOR OZONE
Applicability
External Floating Roofs
Flexographic and Rotogravure Printing
Compliance Dates
SUBPART I:
ADJUSTED RACT EMISSIONS LIMITATIONS
215.124
215.125
215.126
215.127
215.128
Section
215.141
215.142
215.143
215.144
Applicability
6
Petition
Public Hearing
Board Action
Agency Petition
Section
215.301
215.302
215.303
215.304
215.305
Section
215.340
215.342
215.344
215.345
215.346
215.347
Use of Organic Material
Alternative Standard
Fuel Combustion Emission Sources
Operations with Compliance Program
Viscose Exemption (Repealed)
SUBPART N:
VEGETABLE OIL PROCESSING
Hexane Extraction Soybean Crushing
Hexane Extraction Corn Oil Processing
Recordkeeping For Vegetable Oil Processes
Compliance Determination
Compliance Dates and Geographical Areas
Compliance Plan
SUBPART P:
PRINTING
AND
PUBLISHING
Section
215.401
215.402
215.403
215.404
215.405
215.406
215.407
215.408
215.409
215.410
SUBPART
Section
215.420
215.421
215.422
215.423
215.424
215.425
215.426
215.427
215.428
215.429
Flexographic and Rotogravure Printing
Exemptions
Applicability of Subpart K
Testing and Monitoring
(Repealed)
Compliance Dates and Geographical Areas
Alternative Compliance Plan
Compliance Plan
Heatset Web Offset Lithographic Printing
Testing Methods for Volatile Organic Material Content
Emissions Testing
Q:
LEAKS
FROM
SYNTHETIC
ORGANIC
CHEMICAL
AND
POLYMER
MANUFACTURING EQUIPMENT
Applicability
General Requirements
Inspection Program Plan for Leaks
Inspection
Program
for
Leaks
Repairing
Leaks
Recordkeeping
for
Leaks
Report
for
Leaks
Alternative
Program
for
Leaks
Compliance Dates
Compliance Plan
215.261
215.263
215. 264
215.267
SUBPART
K:
USE
OF
ORGANIC
MATERIAL
7
215.430
215.431
215.
432
215. 433
215.434
215.435
215.436
215.437
215.438
215.439
SUBPART R:
Section
215.441
215.442
215.443
2 15.444
2 15.445
2 15.446
215.447
2 15.448
215.449
215.450
215.451
215.452
215.453
General Requirements
Inspection Program Plan for Leaks
Inspection Program for Leaks
Repairing Leaks
Recordkeeping for Leaks
Report for Leaks
Alternative Program for Leaks
Open-Ended Valves
Standards for Control Devices
Compliance Date
PETROLEUM REFINING AND RELATED
INDUSTRIES;
ASPHALT MATERIALS
Petroleum Refinery Waste Gas Disposal
Vacuum Producing Systems
Wastewater
(Oil/Water)
Separator
Process
Unit
Turnarounds
Leaks:
General Requirements
Monitoring Program Plan for Leaks
Monitoring Program for Leaks
Recordkeeping for Leaks
Reporting for Leaks
Alternative Program for Leaks
Sealing
Device
Requirements
Compliance Schedule for Leaks
Compliance Dates and Geographical Areas
Section
215.480
215.481
SUBPART S:
RUBBER AND MISCELLANEOUS PLASTIC PRODUCTS
Manufacture of Pneumatic Rubber Tires
Green Tire Spraying Operations
Alternative Emission Reduction Systems
Emission Testing
Compliance Dates and Geographical Areas
Compliance Plan
Testing Methods for Volatile Organic Material Content
SUBPART T:
PHARMACEUTICAL MANUFACTURING
Applicability of Subpart T
Control of Reactors, Distillation Units, Crystallizers,
Centrifuges and Vacuum Dryers
215.482
Control
of
Air
Dryers,
Production
Equipment
Exhaust
Systems and Filters
Material Storage and Transfer
In—Process Tanks
Leaks
Other Emission Sources
Testing
Section
215.461
215.462
215. 463
215.464
215.465
215.466
215.467
215.483
215.484
215.485
215.486
215.487
8
215.488
2 15.489
Monitors for Air Pollution Control Equipment
Compliance
Schedule
SUBPART U:
COKE MANUFACTURING
AND
BY-PRODUCT
RECOVERY
Section
215. 500
215. 510
215.512
215.513
215.514
215.515
215.516
215.517
Section
215.520
215.521
2 15.525
215.526
215.527
Section
215.541
Section
215.
561
215. 562
215. 563
Section
215.581
215. 582
215.583
215. 584
215.585
215. 586
Except ions
Coke By-Product Recovery Plants
Coke
By-Product
Recovery
Plant
Leaks
Inspection Program
Recordkeeping Requirements
Reporting Requirements
Compliance Dates
Compliance Plan
SUBPART V:
AIR OXIDATION PROCESSES
Applicability
Definitions
Emission Limitations for Air Oxidation Processes
Testing and Monitoring
Compliance Date
SUBPART W:
AGRICULTURE
Pesticide Exception
SUBPART X:
CONSTRUCTION
Architectural Coatings
Paving Operations
Cutback Asphalt
SUBPART Y:
GASOLINE DISTRIBUTION
Bulk Gasoline Plants
Bulk
Gasoline
Terminals
Gasoline
Dispensing
Facilities
Gasoline
Delivery
Vessels
Gasoline
Volatility
Standards
Emissions Testing
SUBPART Z:
DRY CLEANERS
Perchioroethylene Dry Cleaners
Exemptions
Leaks
Section
215.601
215.602
215. 603
9
215.604
Compliance Dates and Geographical Areas
215.605
Compliance Plan
215.606
Exception to Compliance Plan
215.607
Standards for Petroleum Solvent Dry Cleaners
215.608
Operating Practices for Petroleum Solvent Dry Cleaners
215.609
Program for Inspection and Repair of Leaks
215.610
Testing and Monitoring
215.611
Exemption for Petroleum Solvent Dry Cleaners
215.612
Compliance
Dates
and
Geographical
Areas
215.613
Compliance Plan
215.614
Testing
Method
for
Volatile
Organic
Material
Content
of
Wastes
215.615
Emissions
Testing
SUBPART
AA:
PAINT
AND INK MANUFACTURING
Section
215.620
Applicability
215.621
Exemption for Waterbase Material and Heatset Offset Ink
215.623
Permit Conditions
215.624
Open-top Mills, Tanks, Vats or Vessels
215.625
Grinding Mills
215.628
Leaks
215.630
Clean Up
215.636
Compliance Dates
SUBPART BB:
POLYSTYRENE PLANTS
Section
215.875
Applicability of Subpart BB
215.877
Emissions
Limitation
at
Polystyrene
Plants
215.879
Compliance Date
215.881
Compliance Plan
215.883
Special Requirements for Compliance Plan
215.886
Emissions Testing
SUBPART PP:
MISCELLANEOUS FABRICATED PRODUCT MANUFACTURING PROCESSES
Section
215.920
Applicability
215.923
Permit Conditions
215.926
Control Requirements
SUBPART
QQ:
MISCELLANEOUS FORMULATION MANUFACTURING PROCESSES
Section
215.940
Applicability
215.943
Permit Conditions
215.946
Control Requirements
10
UBPART RR:
MISCELLANEOUS ORGANIC CHEMICAL MANUFACTURING PROCESSES
Section
215.960
Applicability
215.963
Permit Conditions
215.966
Control Requirements
Appendix A
Rule Into Section Table
Appendix B
Section Into Rule Table
Appendix C
Past Compliance Dates
Appendix D
List
of
Chemicals
Defining
Synthetic
Organic
Chemical and Polymer Manufacturing
Appendix E
Reference Methods and Procedures
Appendix F
Coefficients for the Total Resource Effectiveness
Index
(TRE)
Equation
AUTHORITY:
Implementing Section
10 and authorized by Section 27
of the Environmental Protection Act
(Ill.
Rev. Stat.
1989,
ch.
ill
1/2,
pars.
1010 and 1027).
SOURCE:
Adopted as Chapter 2:
Air Pollution, Rule 205:
Organic
Material Emission Standards and Limitations,
R71-23,
4
PCB
191,
filed and effective April
14,
1972; amended in R77—3,
33 PCB 357,
at
3 Ill.
Reg.
18,
p.
41, effective Nay 3,
1979;
amended in R78-3
and R78—4,
35 PCB 75,
at 3 Ill. Reg.
30, p.
124, effective July 28,
1979; amended in R80-5 at
7
Ill. Reg.
1244, effective January 21,
1983;
codified at
7 Ill.
Reg.
13601;
Notice of Corrections at
7
Ill. Reg. 14575; amended in R82—l4 at 8 Ill. Reg.
13254, effective
July 12, 1984; amended in R83—36 at 9 Ill. Reg. 9114, effective May
30,
1985; amended in R82—l4 at 9 Ill. Reg. 13960, effective August
28,
1985;
amended
in
R85—28
at
11
Ill.
Reg.
3127,
effective
February 3, 1987; amended in R82—l4 at 11 Ill. Reg.
7296, effective
April
3,
1987;
amended
in
R85—21(A)
at
11
Ill.
Reg.
11770,
effective June
29,
1987;
recodified
in
R86—39
at
11
Ill.
Reg.
13541;
amended
in
R82—14
and
R86—12
at
11
Ill.
Reg.
16706,
effective September 30, 1987; amended in R85—2l(B) at 11 Ill. Reg.
19117,
effective
November
9,
1987;
amended
in
R86—36,
R86—39,
R86—40 at 11 Ill. Reg. 20829, effective December 14, 1987; amended
in R82—l4 and R86—37 at 12 Ill. Reg.
815, effective December 24,
1987;
amended
in R86—18 at
12
Ill.
Reg.
7311, effective April
8,
1988; amended in R86—1O at 12 Ill.
Reg. 7650,
effective April 11,
1988; amended in R88—23 at 13 Ill. Reg.
10893, effective June 27,
1989; amended in R88—30(A) at 14 Ill. Reg. 3555, effective February
27, 1990; emergency amendments adopted in R88—30(A) at 14 Ill. Reg.
6421, effective April 11, 1990, for a maximum of 150 days; amended
in R88—19 at 14 Ill.
Reg.
7596, effective Nay 8,
1990; amended in
R89—l6(A) at 14 Ill. Reg. 9173, effective May 23,
1990; amended in
R88—30(B)
at
15
Ill.
Reg.
3309,
effective
February
13,
1991;
amended
in
R91-7
at
15
Ill.
Reg.
_________,
effective
11
SUBPART A:
GENERAL PROVISIONS
Section 215.100
Introduction
a)
This
Part
contains
standards
and
limitations
for
emissions
of
organic
material
from
stationary
sources
located
in areas other than the Chicago area counties of
Cook. DuPage, Kane. Lake. McHenry. and Will and the Metro
East area counties
of Madison.
Monroe.
and
St.
Clair.
Standards
and
limitations
a~~lyin~in
the
Chicago
area
are
set
forth
in
Part
218.
Standards
and
limitations
applvin~
in
the
Metro
East
area
are
set
forth
in Part
219.
~j
Notwithstanding
any
other
provision
of
this
Part,
the
provisions
of
this
Part
shall
not
a~ly
to
sources
located
in
the
Chicago
area
counties
of
Cook.
DuPage.
Kane.
Lake,
Mcaenry
and
Will
unless
the
provisions
of
35
Ill.
Adm.
Code
Part
218
applicable
to
such
sources
are
voided
or
otherwise
made
ineffective
pursuant
to
Section
218.100
of
35
Ill.
Adin.
Code
Part
218.
21
Notwithstanding
any
other provision of this Part,
the
provisions
of
this
Part
shall
not
apply
to
sources
in
the
Metro
East
area
counties
of
Madison.
Monroe
and
St.
Clair unless the provisions
of
35
Ill.
Adm.
Code
Part
219
applicable
to
such
sources
are
voided
or
otherwise
made
ineffective
pursuant
to
Section
219.100
of
35
Ill.
Adm.
Code
Part
219.
b)
Sources
subject
to
this
Part
may
be
subject
to
the
following:
1)
Permits required under
35
Ill.
Adm.
Code
201;
2)
Air
quality
standards
under
35
Ill.
Adxu.
Code
243.
C)
This
Part
is
divided
into
Subparts
which
are
grouped
as
follows:
1)
Subpart
A:
General
provisions;
2)
Subparts
B
-
J:
Emissions
from
equipment
and
operations
in
common
to
more
than
one
industry;
3)
Subparts
K
—
N:
Emissions
from
use
of
organic
material;
4)
Subparts
N
—
end:
Special
rules
for
various
industry groups.
12
(Source:
Amended at 15 Ill. Reg.
___________,
effective
SUBPART Y:
GASOLINE DISTRIBUTION
Section
215.581
Bulk
Gasoline
Plants
a)
Subject
to
subsection
(e),
no
person
may
cause
or
allow
the
transfer
of
gasoline
from
a
delivery
vessel
into
a
stationary
storage
tank
located
at
a
bulk
gasoline
plant
unless:
1)
The
delivery
vessel
and
the
stationary
storage
tank
are
each
equipped
with
a
vapor
collection
system
that
meets
the
requirements
of
subsection
(d)
(4);
2)
Each
vapor
collection system is operating;
3)
The delivery
vessel
displays
the
appropriate
sticker
pursuant
to
the
requirements
of
Section
215.584(b)
or
(d);
4)
The
pressure
relief
valve(s)
on
the
stationary
storage
tank
and
the
delivery
vessel
are
set
to
release
at
no
less
than
0.7
psi
or
the
highest
pressure
allowed
by
state
or
local fire codes or the
guidelines
of
the
National
Fire
Prevention
Association; and
5)
The stationary
storage tank
is
equipped with
a
submerged
loading
pipe.
b)
Subject
to
subsection
(f),
no
person
may
cause
or
allow
the
transfer
of
gasoline
from
a
stationary
storage
tank
located
at
a
bulk
gasoline
plant
into
a
delivery
vessel
unless:
1)
The
requirements
set
forth
in
subsections
(a)
(1)
through
(a)
(4)
are
met;
and
2)
Equipment
is
available
at
the
bulk
gasoline
plant
to
provide
for
the
submerged
filling
of
the
delivery
vessel
or
the
delivery
vessel
is
equipped
for
bottom
loading.
c)
Subject
to
subsection
(e),
each
owner
of
a
stationary
storage
tank
located
at
a
bulk
gasoline
plant
shall:
1)
Equip
each
stationary
storage
tank
with
a
vapor
control
system
that
meets
the
requirements
of
subsection
(a) or
(b), whichever is applicable;
13
2)
Provide
instructions
to
the
operator
of
the
bulk
gasoline
plant
describing
necessary
maintenance
operations
and
procedures
for
prompt
notification
of
the
owner in case of any malfunction of a vapor
control
system;
and
3)
Repair,
replace
or
modify
any
worn
out
or
malfunctioning
component
or
element
of
design.
d)
Subject
to
subsection
(e),
each
operator
of
a
bulk
gasoline plant shall:
1)
Maintain
and
operate
each
vapor
control
system
in
accordance
with
the
owner’s
instructions;
2)
Promptly
notify
the
owner
of
any
scheduled
maintenance
or
malfunction
requiring
replacement
or
repair
of
a
major
component
of
a
vapor
control
system; and
3)
Maintain gauges, meters or other specified testing
devices in proper working order;
4)
Operate the bulk plant vapor collection system and
gasoline
loading
equipment
in
a
manner
that
prevents:
A)
Gauge
pressure
from
exceeding
18
inches
of
water and vacuum
from exceeding
6
inches
of
water, as measured as close as possible to the
vapor hose connection; and
B)
A reading equal to or greater than 100 percent
of
the
lower
explosive
limit
(LEL
measured
as
propane)
when tested
in accordance with the
procedure
described
in
EPA
450/2-78-051
Appendix
B;
and
C)
Avoidable
leaks
of
liquid
during
loading
or
unloading
operations.
5)
Provide
a pressure tap or equivalent on the bulk
plant vapor collection system in order to allow the
determination of compliance with 215.581(d) (4) (A);
and
6)
Within
15
business
days
after
discovery
of
the
leak
by the owner,
operator, or the Agency, repair and
retest a vapor collection system which exceeds the
limits of subsection
(d) (4) (A) or
(B).
e)
The requirements of subsections
(a),
(c)
and
(d)
shall
14
not
apply
to:
1)
Any stationary storage tank with a capacity of less
than 575 gallons; or
2)
Any
bulk
gasoline
plant
whose
annual
gasoline
throughput is less than 350,000 gallons as averaged
over the preceding three calendar years.
f)
The requirements of subsection
(b)
shall
only apply to
bulk
gasoline
plants:
1)
That have an annual gasoline throughput greater than
or
equal
to
1,000,000
gallons,
as
averaged
over
the
preceding three calendar years; and
2)
That
either
distribute
gasoline
to
gasoline
dispensing
facilities subject to the requirements
of
Section
215583(a)(2).
35
Ill.
Adin.
Code
218.583(b) (2) or 35 Ill. Adm. Code 219.583(a) (2) or
that
are
located
in
the
following
counties:
Boone,
Cook,
Durage,
Kane,
Lake,
Madison,
Mclienry,
Peoria,
Rock
Island,
Ct.
Clair,
Tazcwell,
Will
or
Winnebago.
g)
Bulk
gasoline
plants
were
required
to
take
certain
actions
to
achieve
compliance
which
are
summarized
in
Appendix
C.
(Source:
Amended
at
15
Ill.
Reg.
_______________,
effective
TITLE
35:
ENVIRONMENTAL
PROTECTION
SUBTITLE
B:
AIR
POLLUTION
CHAPTER
I:
POLLUTION
CONTROL
BOARD
SUBCHAPTER
C:
EMISSIONS
STANDARDS
AND
LIMITATIONS
FOR
STATIONARY
SOURCES
PART
219
ORGANIC
MATERIAL
EMISSION
STANDARDS
AND
LIMITATIONS
FOR
THE
METRO
EAST
AREA
SUBPART A:
GENERAL PROVISIONS
Section
219.100
Introduction
219.101
Clean-up and Disposal Operations
219.102
Abbreviations
and
Conversion
Factors
219. 103
Applicability
219. 104
Definitions
15
219.105
219.106
219.107
219.108
219.109
219.110
219.111
219.112
Test
Methods
and
Procedures
Compliance Dates
Afterburners
Exemptions,
Variations,
and
Alternative
Means
of
Control or Compliance Determinations
Vapor
Pressure
of
Volatile
Organic
Liquids
Vapor Pressure of Organic Material or Solvents
Vapor
Pressure
of
Volatile
Organic
Material
Incorporations by Reference
SUBPART
B:
ORGANIC EMISSIONS FROM STORAGE AND LOADING OPERATIONS
Section
219.
121
219.
122
219.
123
219.124
219.125
219. 126
Storage Containers
Loading Operations
Petroleum Liquid Storage Tanks
External Floating Roofs
Compliance Dates
Compliance Plan
SUBPART
C:
ORGANIC EMISSIONS FROM MISCELLANEOUS EQUIPMENT
Section
SUBPART E:
SOLVENT CLEANING
Section
219.181
219. 182
219.183
219. 184
219.185
219.186
Section
219.
2 04
219.205
219. 206
219.207
2 19.208
219.209
219.210
219.211
Solvent Cleaning in General
Cold Cleaning
Open
Top
Vapor
Degreasing
Conveyorized Degreasing
Compliance Schedule
Test Methods
SUBPART
F:
COATING
OPERATIONS
Emission
Limitations
for
Manufacturing
Plants
Daily-Weighted
Average
Limitations
Solids Basis Calculation
Alternative Emission Limitations
Exemptions from Emission Limitations
Exemption
from
General
Rule
on
Use
of
Organic
Material
Compliance
Schedule
Recordkeeping
and
Reporting
219.141
219.142
219.143
219.144
Separation Operations
Pumps and Compressors
Vapor Blowdown
Safety
Relief.
Valves
16
SUBPART
G:
USE
OF
ORGANIC
MATERIAL
Section
219.301
219.302
219.303
219.304
Section
219. 401
219. 402
2 19.403
219.404
219. 405
SUBPART
Section
219.421
219.422
219.423
219.424
219.425
2 19.426
2 19.427
2 19.428
2 19.429
219.430
Use
of
Organic
Material
Alternative
Standard
Fuel
Combustion
Emission
Sources
Operations
with
Compliance
Program
SUBPART
H:
PRINTING
AND
PUBLISHING
Flexographic
and
Rotogravure
Printing
Applicability
Compliance Schedule
Recordkeeping
and
Reporting
Heatset
Web
Offset
Lithographic
Printing
Q:
LEAKS
FROM
SYNTHETIC
ORGANIC
CHEMICAL
AND
POLYMER
MANUFACTURING
EQUIPMENT
General Requirements
Inspection
Program
Plan
for
Leaks
Inspection
Program
for
Leaks
Repairing Leaks
Recordkeeping
for
Leaks
Report
for
Leaks
Alternative Program for Leaks
Open-ended
Valves
Standards
for
Control
Devices
Compliance
Date
SUBPART
R:
PETROLEUM
REFINING
AND
RELATED
INDUSTRIES;
ASPHALT
MATERIALS
Section
219.441
219.442
2 19.443
2 19.444
2 19.445
2 19.446
219.447
219.448
219.449
2 19.450
219.451
219.452
2 19.453
Petroleum Refinery Waste Gas Disposal
Vacuum
Producing
Systems
Wastewater
(Oil/Water)
Separator
Process
Unit
Turnarounds
Leaks:
General
Requirements
Monitoring
Program
Plan
for
Leaks
Monitoring Program for Leaks
Recordkeeping
for
Leaks
Reporting
for
Leaks
Alternative
Program
for
Leaks
Sealing
Device
Requirements
Compliance
Schedule
for
Leaks
Compliance
Dates
17
SUBPART S:
RUBBER AND MISCELLANEOUS PLASTIC PRODUCTS
Manufacture of Pneumatic Rubber Tires
Green
Tire
Spraying
Operations
Alternative
Emission
Reduction
Systems
Emission
Testing
Compliance Dates
Compliance Plan
SUBPART T:
PHARMACEUTICAL
MANUFACTURING
Section
219.480
219.481
219.482
219. 483
219.484
219.485
219.486
219.487
219.488
219.
489
Section
219
•
521
219.525
219.526
219.527
Section
219.541
Applicability of Subpart T
Control of Reactors, Distillation Units,
Crystallizers,
Centrifuges and Vacuum Dryers
Control
of
Air
Dryers,
Production
Equipment
Exhaust
Systems
and
Filters
Material
Storage
and
Transfer
In—Process
Tanks
Leaks
Other
Emission
Sources
Testing
Monitoring
and
Recordkeeping
for
Air
Pollution
Control
Equipment
Recordkeeping
for
Air
Pollution
Control
Equipment
SUBPART
V:
AIR
OXIDATION
PROCESSES
Definitions
Emission
Limitations
for
Air
Oxidation
Processes
Testing
and
Monitoring
Compliance
Date
SUBPART
W:
AGRICULTURE
Pesticide
Exception
SUBPART X:
CONSTRUCTION
Section
219.561
219.562
219.563
Section
219.581
Architectural Coatings
Paving Operations
Cutback Asphalt
SUBPART Y:
GASOLINE DISTRIBUTION
Section
219.
461
2 19.462
219.463
2 19.464
2 19.465
2 19.466
Bulk
Gasoline
Plants
18
SUBPART
Z:
DRY
CLEANERS
Section
219.601
219.
602
219.603
219.604
219.
605
219.
606
219.
607
219.608
219.
609
219.
610
219.
611
219.612
219.
613
Section
219.620
219.621
219.623
219.624
219.625
219.626
219.628
219.630
219.
636
219. 637
Perchloroethylene
Dry
Cleaners
Exemptions
Leaks
Compliance
Dates
Compliance
Plan
Exception
to
Compliance
Plan
Standards
for
Petroleum
Solvent
Dry
Cleaners
Operating
Practices
for
Petroleum
Solvent
Dry
Cleaners
Program
for
Inspection
and
Repair
of
Leaks
Testing
and
Monitoring
Exemption
for
Petroleum
Solvent
Dry
Cleaners
Compliance
Dates
Compliance Plan
SUBPART
AA:
PAINT
AND
INK
MANUFACTURING
Applicability
Exemption for Waterbase Material and Heatset Offset Ink
Permit Conditions
Open-top
Mills,
Tanks,
Vats
or
Vessels
Grinding
Mills
Storage
Tanks
Leaks
Clean
Up
Compliance
Schedule
Recordkeeping
and
Reporting
SUBPART
BB:
POLYSTYRENE
PLANTS
Applicability
of
Subpart
BB
Emissions Limitation at Polystyrene Plants
Compliance
Date
Compliance
Plan
Special
Requirements
for
Compliance
Plan
Emissions
Testing
SUBPART PP:
MISCELLANEOUS FABRICATED PRODUCT MANUFACTURING PROCESSES
219.582
219.583
219.584
219.585
Bulk
Gasoline
Terminals
Gasoline Dispensing Facilities
Gasoline
Delivery
Vessels
Gasoline
Volatility
Standards
Section
2 19.875
2 19.877
219. 879
219. 881
219. 883
219. 886
Section
219.920
219.923
219.926
Applicability
Permit
Conditions
Control Requirements
19
219.927
Compliance
Schedule
219.928
Testing
SUBPART
QQ:
MISCELLANEOUS
FORMULATION
MANUFACTURING
PROCESSES
Section
219.940
Applicability
219.943
Permit
Conditions
219.946
Control
Requirements
219.947
Compliance
Schedule
219.948
Testing
SUBPART
PR:
MISCELLANEOUS ORGANIC CHEMICAL MANUFACTURING PROCESSES
Section
219.960
Applicability
219.963
Permit
Conditions
219.966
Control
Requirements
219.967
Compliance
Schedule
219.968
Testing
SUBPART
TT:
OTHER
EMISSION
SOURCES
Section
219.980
Applicability
219.983
Permit
Conditions
219.986
Control Requirements
219.987
Compliance
Schedule
219.988
Testing
SUBPART
UU:
RECORDKEEPING
AND
REPORTING
FOR
NON-CTG
SOURCES
Section
219.990
Exempt
Emission
Sources
219.991
Subject Emission Sources
Appendix A:
List of Chemicals Defining Synthetic Organic
Chemical
and
Polymer
Manufacturing
Appendix
B:
VON
Measurement
Techniques
for
Capture
Efficiency
Appendix
C:
Reference
Methods
and
Procedures
Appendix
D:
Coefficients
for
the
Total Resource Effectiveness
Index
(TRE)
Equation
AUTHORITY:
Implementing
Section
10
and
authorized
by
Section
28.2
of
the
Environmental
Protection
Act
(Ill.
Rev.
Stat.
1989,
ch.
111
1/2,
pars.
1010
and
1028.2).
SOURCE:
Adopted
at
15
Ill.
Reg.
_______,
effective
___________
20
SUBPART A:
GENERAL PROVISIONS
Section
219.100
Introduction
a)
This
Part
contains
standards
and
limitations
for
emissions
of
organic
material
from
stationary
sources
located
in
the
Metro
East
area,
which
is
comprised
of
Madison,
Monroe,
and
St.
Clair
Counties.
b)
Sources
subject
to
this
Part
may
be
subject
to
the
following:
1)
Permits required under 35 Ill.
Adin.
Code
201;
2)
Air quality standards under 35 Ill. Adm. Code 243;
C)
This Part is divided into Subparts which are grouped as
follows:
1)
Subpart A:
General Provisions
2)
Subparts
B-F:
Emissions
from
equipment
and
operations
in
common
to
more
than
one
industry;
3)
Subpart
G:
Emissions
from
use
of
organic
material;
4)
Subparts H-end:
Special rules for various
industry groups.
Section
219.101
Cleanup
and
Disposal
Operation
Emission
of
organic
material
released
during
clean—up
operations
and
disposal
shall
be
included
with
other
emissions
of
organic
material
from
the
related
emission
source
or
air
pollution
control
equipment
in
determining
total
emissions.
Section
219.102
Abbreviations
and
Conversion
Factors
a)
The
following
abbreviations
are
used
in
this Part:
ASTM
American
Society
for
Testing
and
Materials
bbl
barrels
(42
gallons)
•C
degrees
Celsius
or
centigrade
cm
centimeters
Cu
in.
cubic
inches
°F
degrees Fahrenheit
FIP
Federal Implementation Plan
ft
feet
ft2
square
feet
g
grams
21
gpm
gallons per minute
g/inole
grams per mole
gal
gallons
hr
hours
in
inches
oK
degrees
Kelvin
kcal kilocalories
kg
kilograms
kg/hr
kilograms
per
hour
kPa
kilopascals;
one
thousand
newtons
per
square
meter
1
liters
1/sec
liters
per
second
lbs
pounds
lbs/hr
pounds per hour
lbs/gal
pounds per gallon
LEL
lower explosive limit
meters
square meters
m3
cubic meters
ing
milligrams
Mg
Megagrams, metric tons or tonnes
ml
milliliters
mm
minutes
NJ
megajoules
mm
Hg
millimeters
of
mercury
ppm
parts
per
million
ppmv parts per million by volume
psi
pounds per square inch
psia pounds per square inch absolute
psig pounds per square inch gauge
scf
standard cubic feet
scm
standard cubic meters
sec
seconds
SIP
State Implementation Plan
TTE
temporary total enclosure
sq cm
square centimeters
sq in
square inches
T
English ton
ton
English ton
USEPA
United States Environmental Protection
Agency
VOC
volatile organic compounds
VOL
volatile organic liquids
VON
volatile organic materials
22
b)
The following conversion factors are used in this Part.
English
Metric
1 gal
3.785 1
1,000 gal 3,785 1 or 3.785 m3
1 psia
6.897 kPa (51.71 mm Hg)
2.205 lbs
1 kg
1 bbl
159.0 1
1
Cu
in
16.39 ml
I lb/gal
119,800 mg/i
1 ton
0.907 Mg
1 T
0.907 Mg
Section 219.103
Applicability
The provisions of this Part shall
apply
to
all
sources
located
in
Madison, Monroe, and St. Clair
Counties.
a)
The
provisions
of
this
Part shall become effective
sixty
days
after
a
final
decision
by
the
federal
appellate court of the general appeal
(Illinois
Environmental Regulatory Group v. UCEFA,
No.
90 2778
(and consolidated
cases)
(7th
Cir.))
-of
the federal
implementation plan
(FIP)
for
the
Chicago
area
promulgated by the U.C.
Environmental
Protection
Agency
(55 Fed. Reg.
26134,
June
29,
1990;
5~Fed.
fleg.
31931,
August
6,
1090;
55 Fed.
fleg.
39774,
Ceptcmber
20,
1000), provided, however, that if a provision of
the
FIP is voided or made ineffective by a federal court,
the corresponding provision in
this
proceeding
shall
not
become
effective-~
b)
The
provisions
of
this
Part
specifically
applicable
to
each
appellant
who
appealed
the
FIP
for
the
Chicago
ni~n
~hn11
become~cff~~,’fiiw
~iii+u
s1n~r~nft-i~i-
ri
‘finni
decision
of
that
appellant’s
appeal
by
t he
federal
appellate
court;
provided,
however,
that
if
the
provisions
of
the
PIP
applicable
to
that
party
are
~rnr1~r1
r~
made
ineffac1~1!~
~“-~
~
fari~valcourt, th~
~2
corresponaing
~
in
th~
procecaing
shall
not
become effective.
Section
219.104
Definitions
The
following
terms
are
defined
for
the
purpose
of
this
Part.
“Accelacota” means
a pharmaceutical coating operation
which
consists
of
a
horizontally
rotating
perforated
drum
in
which
tablets
are
placed,
a
coating
is
applied
by
spraying,
and
the
coating
is
dried
by
the
flow
of
23
air
across
the
drum
through
the
perforations.
“Accumulator”
means
the
reservoir
of
a
condensing
unit
receiving the condensate from a surface condenser.
“Acid
gases”
means
for
the
purposes
of
Section
9.4
of
the
Environmental
Protection
Act
(the
Act)
(Ill.
Rev.
Stat.
1987,
ch.
111
1/2,
par.
1009.4),
hydrogen
chloride,
hydrogen
fluoride
and
hydrogen
bromide,
which
exist
as
gases,
liquid
mist,
or
any
combination
thereof.
“Actual emissions” means the actual quantity of VOM
emissions
from
an
emission
source
during
a
particular
time period.
“Actual heat input” means the quantity of heat produced
by the combustion of fuel using the gross heating value
of
the
fuel.
“Adhesive” means any substance or mixture of substances
intended
to
serve
as
a
joining
compound.
“Afterburner”
means
a
control
device
in
which
materials
in
gaseous
effluent
are
combusted.
“Air contaminant” means any solid, liquid,
•or gaseous
matter,
any
odor,
or
any
form
of
energy,
that
is
capable
of
being
released
into
the
atmosphere
from
an
emission source.
“Air dried coatings” means any coatings that dry by use
of air or forced air at temperatures up to 363.15 K
(194°F)
“Air pollution” means the presence in the atmosphere of
one
or
more
air
contaminants
in
sufficient
quantities
and
of
such
characteristics
and
duration
as
to
be
injurious
to
human,
plant,
or
animal
life,
to
health,
or
to
property,
or
to
unreasonably
interfere
with
the
enjoyment of life or property.
“Air
pollution
control
equipment”
means
any
equipment
or facility of a type intended to eliminate,
prevent,
reduce or control the emission of specified air
contaminants
to
the
atmosphere.
“Air
suspension
coater/dryer”
means
a
pharmaceutical
coating
operation
which
consists
of
vertical
chambers
in which tablets or particles are placed, and a coating
is applied and then dried while the tablets or
particles are kept in a fluidized state by the passage
24
of
air
upward
through
the
chambers.
“Airless
spray”
means
a
spray
coating
method
in
which
the
coating
is
atomized
by
forcing
it
through
a
small
opening
at
high
pressure.
The
coating
liquid
is
not
mixed
with
air
before
exiting
from
the
nozzle.
“Air—assisted airless spray” means a spray coating
method
which
combines
compressed
air
with
hydraulic
pressure
to
atomize
the
coating
material
into
finer
droplets
than
is
achieved
with
pure
airless
spray.
Lower
hydraulic
pressure
is
used
than
with
airless
spray.
“Allowable
emissions”
means
the
quantity
of
VON
emissions during a particular time period from a
stationary
source
calculated
using
the
maximum
rated
capacity
of
the
source
(unless
restricted
by
federally
enforceable limitations on operating rate,
hours of
operation,
or
both)
and
the
most
stringent
of:
the
applicable
standards
in
40
CFR
Parts
60
and
61;
the
applicable implementation plan;
or a federally
enforceable permit.
“Ambient
air quality standards” means those standards
designed
to
protect
the
public
health
and
welfare
codified
in
40
CFR
Part
50
and
promulgated
from
time
to
time
by
the
USEPA
pursuant
to
authority
contained
in
Section
108
of
the
Clean
Air
Act,
42
U.S.C.
7401
et
seq.,
as
amended
from
time
to
time.
“Applicator” means a device used in
a coating line to
apply
coating.
“As applied” means the exact formulation of a coating
during application,on or impregnation into a substrate.
“Architectural
coating”
means
any
coating
used
for
residential
or
commercial
buildings
or
their
appurtenances,
or
for
industrial
buildings,
which
is
site applied.
“Asphalt” means the dark—brown to black cementitious
material
(solid,
semisolid,
or
liquid
in
consistency)
of
which
the
main
constituents
are
bitumens
which
occur
naturally or as a residue of petroleum refining.
“Asphalt prime coat” means a low-viscosity liquid
asphalt
applied
to
an
absorbent
surface
as
the
first
of
more
than
one
asphalt
coat.
“Automobile” means a motor vehicle capable of carrying
25
no
more
than
12
passengers.
“Automobile
or
light-duty
truck
assembly
plant”
means
a
facility
where
parts
are
assembled
or
finished
for
eventual inclusion into a finished automobile or
light-duty truck ready for sale to vehicle dealers, but
not
including
customizers,
body
shops,
and
other
repainters.
“Automobile
or
light-duty
truck
refinishing”
means
the
repainting of used automobiles and light-duty trucks.
“Baked coatings” means any coating which is cured or
dried
in
an
oven
where the oven air temperature exceeds
90°C
(194°F).
“Batch loading” means the process of loading
a number
of individual parts at the same time for degreasing.
“Bead-dipping” means the dipping of an assembled tire
bead into a solvent—based cement.
“Binders” means organic materials and resins which do
not contain VON.
“Bituminous coatings” means black or brownish coating
materials which are soluble in carbon disulfide, which
consist mainly of hydrocarbons, and which are obtained
from natural deposits or as residues from the
distillation of crude oils or of low grades of coal.
“British thermal unit” means the quantity of heat
required to raise one pound of water from 60°Fto 61°F
(abbreviated btu).
“Brush
or
wipe
coating”
means
a manual method of
applying
a
coating
using
a
brush,
cloth,
or
similar
object.
“Bulk
gasoline
plant”
means
a
gasoline
storage
and
distribution
facility
with
an
average
throughput
of
76,000
1
(20,000 gal) or less on a 30-day rolling
average
that
distributes
gasoline
to
gasoline
dispensing facilities.
“Bulk
gasoline
terminal”
means
any
gasoline
storage
and
distribution
facility
that
receives
gasoline
by
pipeline, ship or barge, and distributes gasoline to
bulk gasoline plants or gasoline dispensing facilities.
“Can” means any metal container,
with or without a top,
cover,
spout or handles, into which solid or liquid
26
materials are packaged.
“Can coating” means any coating applied on a single
walled container that is manufactured from metal sheets
thinner than 29 gauge
(0.0141 in.).
“Can coating facility” means
a facility that includes
one or more can coating line(s).
“Can coating line” means a coating line in which any
protective,
decorative,
or functional coating is
applied onto the surface of cans or can components.
“Capture” means the containment or recovery of
emissions from a process for direction into a duct
which may be exhausted through a stack or vent to a
control device.
The overall abatement of emissions
from
a
process
with
an
add—on
control
device
is
a
function both of the capture efficiency and of the
control device.
“Capture device” means
a hood, enclosed room floor
sweep or other means of collecting solvent or other
pollutants into a duct.
The pollutant can then be
directed to a pollution control device such as an
afterburner or carbon adsorber.
Sometimes the term is
used loosely to include the control device.
“Capture efficiency” means the fraction of all VON
generated by a process that are directed to an
abatement or recovery device.
“Capture system” means all equipment (including, but
not limited to, hoods,
ducts,
fans,
ovens, dryers,
etc.) used to contain, collect and transport an air
pollutant to a control device.
“Clean
Air
Act”
means the Clean Air Act of 1963,
as
amended, including the Clean Air Act Amendments of
1977,
(42 U.S.C.
7401 et seq.), and the Clean Air Act
Amendments
of
1990,
(P.A.
101549).
“Clear
coating”
means
coatings
that
lack
color
and
opacity or are transparent using the undercoat as a
reflectant base or undertone color.
“Clear topcoat” means the final coating which contains
binders,
but
not
opaque
pigments,
and
is
specifically
formulated to form a transparent or translucent solid
protective film.
“Closed purge system” means a system that is not open
27
to
the
atmosphere
and
that
is
composed
of
piping,
connections,
and,
if necessary,
flow inducing devices
that
transport
liquid
or
vapor
from
a
piece
or
pieces
of
equipment
to
a
control
device,
or return the liquid
or
vapor
to
the
process
line.
“Closed vent system” means a system that is not open to
the
atmosphere
and
is
composed
of
piping,
connections,
and,
if necessary,
flow
inducing
devices
that
transport
gas or vapor from an emission source to a control
device.
“Coating” means a material applied onto or impregnated
into a substrate for protective, decorative,
or
functional purposes.
Such materials include, but are
not limited to, paints, varnishes,
sealers, adhesives,
thinners, diluents, and inks.
“Coating applicator” means equipment used to apply a
coating.
“Coating line” means an operation consisting of a
series of one or more coating applicators and any
associated flash—off areas, drying areas, and ovens
wherein a surface coating is applied, dried,
or cured.
(It is not necessary for an operation to have an oven,
or flash-off area, or drying area to be included in
this definition.)
“Coating plant” means any plant that contains one or
more coating line(s).
“Coil” means any flat metal sheet or strip that is
rolled or wound in concentric rings.
“Coil coating” means any coating applied on any flat
metal sheet or strip that comes in rolls or coils.
“Coil coating facility” means a facility that includes
one
or
more
coil
coating
line(s).
“Coil coating line” means a coating line in which any
protective,
decorative or functional coating is applied
onto the surface of flat metal sheets,
strips, rolls,
or coils for industrial or commercial use.
“Cold
cleaning”
means
the
process
of
cleaning
and
removing
soils
from
surfaces
by
spraying,
brushing,
flushing,
or
immersion
while
maintaining
the organic
solvent below its boiling point.
Wipe cleaning is not
included in this definition.
28
“Complete combustion” means a process in which all
carbon contained in a fuel or gas stream is converted
to
carbon
dioxide.
“Component” means, with respect to synthetic organic
chemical
and
polymer
manufacturing
equipment,
and
petroleum
refining
and
related
industries,
any
piece
of
equipment
which
has
the
potential
to
leak
VON
including,
but
not
limited
to,
pump
seals,
compressor
seals,
seal
oil
degassing
vents,
pipeline
valves,
pressure
relief
devices,
process
drains,
and
open
ended
pipes.
This
definition
excludes
valves
which are not
externally regulated, flanges, and equipment in heavy
liquid
service.
For
purposes
of
Subpart
Q
of this
Part, this definition also excludes bleed ports of gear
pumps in polymer service.
“Concrete curing compounds” means any coating applied
to freshly poured concrete to retard the evaporation of
water.
“Condensate” means volatile organic liquid separated
from its associated gases, which condenses due to
changes in the temperature or pressure and remains
liquid at standard conditions.
“Continuous process” means, with respect to polystyrene
resin,
a method of manufacture in which the styrene raw
material is delivered on
a
continuous
basis
to
the
reactor in which the styrene is polymerized to
polystyrene.
“Control device” means equipment (such as an
afterburner or adsorber) used to remove or prevent the
emission of air pollutants from
a contaminated exhaust
stream.
“Control device efficiency” means the ratio of the
pollution prevented by
a
control
device
and
the
pollution introduced to the control device, expressed
as
a
percentage.
“Conveyorized
degreasing”
means
the
continuous
process
of cleaning and removing
soils
from
surfaces
utilizing
either cold or vaporized solvents.
“Crude
oil”
means
a
naturally
occurring
mixture which
consists of hydrocarbons and sulfur, nitrogen,
or
oxygen derivatives of hydrocarbons and which is
a
liquid at standard conditions.
“Crude oil gathering” means the transportation of crude
29
oil or condensate after custody transfer between
a
production
facility and a reception point.
“Custody
transfer”
means
the
transfer
of
produced
petroleum and/or condensate after processing and/or
treating in the producing operations,
from storage
tanks
or
automatic transfer facilities to pipelines or
any other forms of transportation.
“Cutback asphalt” means any asphalt which has been
liquified
by
blending
with
petroleum
solvents
other
than residual fuel oil and has not been emulsified with
water.
“Daily—weighted average VON content” means the average
VON
content
of
two
or
more
coatings
as
applied
on
a
coating line during any day, taking into account the
fraction of total coating volume that each coating
represents,
as calculated with the following equation:
VOMW
=
~
VICI/VT
where:
VOMW
=
The average VON content of two or more
coatings as applied each day on a
coating line in units of kg VON/l
(lbs
VON/gal) of coating
(minus water and any
compounds which are specifically
exempted from the definition of VON),
n
=
The number of different coatings as
applied each day on a coating line,
V1
The volume of each coating
(minus water
and any compounds which are specifically
exempted from the definition of VON)
as
applied
each
day
on
a
coating
line
in
units
of
1
(gal)
C~
=
The VON content of each coating as
applied each day on
a coating line in
units of kg VOM/l
(lbs VOM/gal)
of
coating (minus water and any compounds
which are specifically exempted from the
definition of VOM), and
VT
=
The total volume of all coatings
(minus
water and any compounds which are
specifically exempted from the
30
definition of VON)
as applied each day
on
a coating line
in
units
of
1
(gal).
“Day” means the consecutive 24 hours beginning at 12:00
AM (midnight)
local time.
“Degreaser” means any equipment or system used in
solvent cleaning.
“Delivery vessel” means any tank truck or trailer
equipped with a storage tank that is used for the
transport of gasoline to a stationary storage tank at a
gasoline dispensing facility, bulk gasoline plant, or
bulk
gasoline
terminal.
“Dip coating” means a method of applying coatings in
which the part is submerged in a tank filled with the
coating.
“Distillate fuel oil” means fuel oils of grade No.
1 or
2 as specified in detailed requirements for fuel oil
ASTM D—369—69 (1971).
“Dry cleaning facility” means a facility engaged in the
cleaning of fabrics using an essentially nonaqueous
solvent by means of one or more solvent washes,
extraction of excess solvent by spinning and drying by
tumbling in an airstreain.
The facility includes, but
is
not
limited
to,
washers,
dryers,
filter
and
purification systems, waste disposal systems, holding
tanks, pumps and attendant piping and valves.
“Effluent water separator” means any tank,
box, sump or
other apparatus in which any organic material floating
on or entrained or contained in water entering such
tank, box, sump or- other apparatus is physically
separated and removed from such water prior to outfall,
drainage or recovery of such water.
“Electrostatic bell or disc spray” means an
electrostatic
spray
coating method in which a
rapidly-spinning
bell-
or
disc—shaped
applicator
is
used
to
create
a
fine
mist
and
apply
the
coating
with
high transfer efficiency.
“Electrostatic
spray”
means
a
spray
coating method in
which opposite electrical charges are applied to the
substrate and the coating.
The
coating
is
attracted
to
the object due to the electrostatic potential between
them.
“Emission rate” means total quantity of any air
31
contaminant discharge into the atmosphere in any
one—hour period.
“Emission source” and “source” mean any facility from
which VON is emitted or capable of being emitted into
the
atmosphere.
“Enamel”
means
a
coating
that
cures
by
chemical
cross-linking of its base resin.
Enamels can be
distinguished from lacquers because enamels are not
readily
resoluble
in
their
original
solvent.
“Enclose” means to
cover
any VOL surface that is
exposed to the atmosphere.
“End sealing compound coat” means a compound applied to
can ends which functions as a gasket when the end is
assembled onto the can.
“Excess air” means air supplied in addition to the
theoretical quantity necessary for complete combustion
of all
fuel
and/or
combustible waste material.
“Excessive release” means a discharge of more than 295
g
(0.65
lbs)
of
mercaptans
and/or
hydrogen
sulfide
into
the atmosphere in any 5-minute period.
“Exterior base coat” means a coating applied to the
exterior of a can body,
or flat sheet to provide
protection
to
the
metal
or
to provide background for
any lithographic or printing operation.
“Exterior end coat” means a coating applied to the
exterior
end
of
a can to provide protection to the
metal.
“External—floating
roof”
means
a
cover
over
an
open
top
storage tank consisting of a double deck or pontoon
single deck which rests upon and is supported by the
volatile organic liquid being contained and is equipped
with a closure seal or seals to close the space between
the roof edge and tank shell.
“Extreme
environmental
conditions”
means
exposure
to
any or all of the following: ambient weather
conditions;
temperatures consistently above 95°C
(203°F);detergents; abrasive and scouring agents;
solvents; or corrosive atmospheres.
“Extreme performance coating” means any coating which
during intended use is exposed to extreme environmental
conditions.
32
“Fabric coating” means any coating applied on textile
fabric.
Fabric coating includes the application of
coatings by impregnation.
“Fabric coating facility” means a facility that
includes one or more fabric coating lines.
“Fabric coating line” means a coating line in which any
protective, decorative,
or functional coating or
reinforcing material is applied on or impregnated into
a textile fabric.
“Federally
enforceable”
means
all
limitations
and
conditions which are enforceable by the Administrator
including those requirements developed pursuant to 40
CFR Parts 60 and 61; requirements within any applicable
implementation plan; and any permit requirements
established pursuant to 40 CFR 52.21 or under
regulations approved pursuant to 40 CFR Part 51 Subpart
I and 40 CFR 51.166.
“Final repair coat” means the repainting of any topcoat
which
is
damaged
during
vehicle
assembly.
“Firebox” means the chamber or compartment of a boiler
or furnace in which materials are burned, but not the
combustion
chamber
or afterburner of an incinerator.
“Fixed-roof tank” means a cylindrical shell with a
permanently affixed roof.
“Flexographic printing” means the application of words,
designs, and pictures to a substrate by means of a roll
printing
technique
in
which
the
pattern
to
be
applied
is raised above the printing roll and the image carrier
is made of elastomeric materials.
“Flexographic printing line” means
a printing line in
which each roll printer uses a roll with raised areas
for applying an image such as words, designs, or
pictures to a substrate.
The.image carrier on the roll
is made of rubber or other elastomeric material.
“Floating roof” means a roof on a stationary tank,
reservoir,
or
other
container
which
moves
vertically
upon
change
in
volume
of
the
stored
material.
“Fountain
solution”
means
the
solution
which
is
applied
to the image plate to maintain hydrophilic properties
of the non—image areas.
33
“Freeboard height” means for open top vapor degreasers,
the distance from the top of the vapor zone to the top
of
the
degreaser
tank.
For
cold
cleaning
degreasers,
the distance from the solvent to the top of the
degreaser tank.
“Fuel
combustion
emission
source”
means
any
furnace,
boiler, or similar equipment used for the primary
purpose
of
producing
heat
or
power
by
indirect
heat
transfer.
“Fuel gas system” means a system for collection of
refinery fuel gas including, but not limited to, piping
for collecting tail gas from various process units,
mixing drums and controls,
and distribution piping.
“Gas service” means that the component contains process
fluid that is in the gaseous state at operating
conditions.
“Gas/gas method” means either of two methods for
determining capture which rely only on gas phase
measurements.
The first method requires construction
of a temporary total enclosure (TTE)
to ensure that all
would—be fugitive emissions are measured.
The second
method uses the building or room which houses the
facility as an enclosure.
The second method requires
that all other VON sources within the room be shut down
while the test is performed, but all fans and blowers
within the room must be operated according to normal
procedures.
“Gasoline” means any petroleum distillate or petroleum
distillate/alcohol blend having a Reid vapor pressure
of 27.6 kPa or greater which is used as a fuel for
internal combustion engines.
“Gasoline dispensing facility’t means any site where
gasoline is transferred from a stationary storage tank
to
a
motor
vehicle
gasoline
tank
used
to
provide
fuel
to the engine of that motor vehicle.
“Green tire spraying” means the spraying of green
tires, both inside and outside, with release compounds
which
help
remove
air
from
the
tire
during
molding
and
prevent
the
tire
from
sticking
to
the
mold
after
curing.
“Green tires” means assembled tires before molding and
curing have occurred.
“Gross vehicle weight” means the manufacturer’s gross
34
weight rating for the individual vehicle.
“Gross vehicle weight rating” means the value specified
by the manufacturer as the maximum design loaded weight
of a single vehicle.
“Heated airless spray” means an airless spray coating
method in which the coating is heated just prior to
application.
“Heatset”
means
a
class
of
web—offset
lithography
which
requires
a
heated
dryer
to
solidify
the
printing
inks.
“Heatset-web-offset
lithographic
printing
line”
means
a
lithographic printing line in which a blanket cylinder
is used to transfer ink from
a plate cylinder to a
substrate continuously fed from a roll or an extension
process and an oven is used to solidify the printing
inks.
“Heavy liquid” means liquid with a true vapor pressure
of
less
than
0.3
kPa
(0.04
psi)
at
294.3’K
(70°F)
established in a standard reference text or as
determined by ASTM method D2879-86 (incorporated by
reference
in
Section
219.112);
or
which
has
0.1
Reid
Vapor
Pressure
as
determined
by
ASTM
method D323-82
(incorporated by reference in Section 219.112); or
which when distilled requires a temperature of 42l.95°K
(300°F)or greater to recover 10 percent of the liquid
as determined by
ASTN
method D86-82
(incorporated by
reference in Section 219.112).
“Heavy off-highway vehicle products” means,
for the
purpose of Subpart F of this Part, heavy construction,
mining,
farming, or material handling equipment; heavy
industrial engines; diesel-electric locomotives and
associated power generation equipment;
and the
components of such equipment or engines.
“Heavy
off-highway
vehicle products coating facility”
means
a
facility
that
includes
one
or
more
heavy
off-highway
vehicle
products
coating
line(s).
“Heavy
off-highway
vehicle
products
coating
line”
means
a
coating
line
in
which
any
protective,
decorative,
or
functional
coating
is
applied
onto
the
surface
of
heavy
off-highway vehicle products.
“High
temperature
aluminum
coating” means a coating
that
is
certified
to
withstand
a
temperature
of
537.8°C
(1000°F)
for
24
hours.
35
“Hood” means a partial enclosure or canopy for
capturing and exhausting, by means of a draft, the
organic vapors or other fumes rising from a coating
process or other source.
“Hood capture efficiency” means the emissions from a
process which are captured by the hood and directed
into a control device, expressed as a percentage of all
emissions.
“Hot well” means the reservoir of a condensing unit
receiving the condensate from a barometric condenser.
“Hour” means a block period of 60 minutes (e.g.,
1:00am
to 2:00am).
“In—process tank” means a container used for mixing,
blending, heating, reacting, holding,
crystallizing,
evaporating or cleaning operations
•in the manufacture
of pharmaceuticals.
“In—situ sampling systems” means nonextractive samplers
or in—line samplers.
“In vacuum service” means,
for the purpose of Subpart Q
of this Part,
equipment which is operating at an
internal pressure that is at least 5 kPa
(0.73 psia)
below ambient pressure.
“Incinerator” means a combustion apparatus in which
refuse is burned.
“Indirect heat transfer” means transfer of heat in such
a way that the source of heat does not come into direct
contact with process materials.
“Ink” means a coating used in printing,
impressing,
or
transferring an image onto a substrate.
“Interior body spray coat” means a coating applied by
spray to the interior of a can body.
“Internal—floating roof” means a cover or roof in a
fixed-roof tank which rests upon and is supported by
the volatile organic liquid being contained and is
equipped with a closure seal or seals to close the
space between the roof edge and tank shell.
“Lacquers” means any clear wood finishes formulated
with nitrocellulose or synthetic resins to dry by
evaporation without chemical reaction,
including clear
lacquer sanding sealers.
36
“Large appliance” means any residential and commercial
washers,
dryers,
ranges,
refrigerators,
freezers,
water
heaters,
dishwashers,
trash
compactors,
air
conditioners,
and
other
similar
products.
“Large
appliance
coating”
means
any
coating
applied
to
the
component
metal
parts
(including,
but
not
limited
to,
doors,
cases,
lids,
panels,
and
interior
support
parts)
of
residential
and
commercial
washers,
dryers,
ranges,
refrigerators,
freezers,
water
heaters,
dish
washers,
trash
compactors,
air
conditioners,
and
other
similar products.
“Large appliance coating facility” means a facility
that includes one or more large appliance coating
line(s).
“Large
appliance coating line” means a coating line in
which any protective,
decorative,
or functional coating
is
applied
onto
the
surface
of
large
appliances.
~‘Light
liquid”
means
VON
in
the
liquid
state
which
is
not
defined
as
heavy
liquid.
“Light—duty
truck”
means
any
motor
vehicle
rated
at
3,850
kg
gross
vehicle
weight
or
less,
designed
mainly
to
transport
property.
“Liquid/gas method” means either of two methods for
determining capture which require both gas phase and
liquid phase measurements and analysis.
The first
method requires construction of a TTE.
The second
method
uses
the
building
or
room
which
houses
the
facility
as
an
enclosure.
The
second
method
requires
that
all
other
VOM. sources
within
the
room
be
shut
down
while the test is performed,
but all fans and blowers
within the room must be operated according to normal
procedures.
“Liquid—mounted seal” means a primary seal mounted in
continuous
contact
with
the
liquid
between
the
tank
wall and the floating roof edge around the
circumference
of
the
roof.
“Liquid service” means that the equipment or component
contains
process
fluid
that
is
in
a
liquid
state
at
operating
conditions.
“Liquids
dripping”
means
any
visible
leaking
from
a
seal
including
spraying,
misting,
clouding
and
ice
formation.
37
“Lithographic
printing
line”
means
a
printing
line,
except
that
the
substrate
is
not
necessarily
fed
from
an
unwinding
roll,
in
which
each
roll
printer
uses
a
roll where both the image and non—image areas are
essentially
in
the
same
plane
(planographic).
“Low
solvent coating” means a coating which contains
less
organic
solvent
than
the
conventional
coatings
used
by
the
industry.
Low
solvent
coatings
include
water-borne, higher solids, electro-deposition and
powder coatings.
“Magnet wire” means aluminum or copper wire formed into
an electromagnetic coil.
“Magnet wire coating” means any coating or electrically
insulating varnish or enamel applied to magnet wire.
“Magnet wire coating facility” means a facility that
includes one or more magnet wire coating line(s).
“Magnet
wire
coating
line”
means
a
coating
line
in
which any protective, decorative, or functional coating
is applied onto the surface of a magnet wire.
“Malfunction” means any sudden and unavoidable failure
of
air
pollution
control
equipment,
process
equipment,
or
a
process
to
operate
in
a
normal
or
usual
manner.
Failures that are caused entirely or in part by poor
maintenance, careless operation,
or any other
preventable upset condition or preventable equipment
breakdown shall not be considered malfunctions.
“Manufacturing process” means a method whereby a
process emission source or series of process emission
sources is used to convert raw materials,
feed stocks,
subassenthlies,
or
other
components
into
a
product,
either for sale or for use as a component in a
subsequent
manufacturing
process.
“Material
recovery
section”
means
any
equipment
designed
to
transport
and
recover
styrene
monomer
and
other impurities from other products and by-products in
a
polystyrene
plant,
including
but
not
limited
to
the
styrene devolatilizer unit and styrene recovery unit.
“Maximum theoretical emissions” means the quantity of
volatile organic material emissions that theoretically
could be emitted by a
stationary
source
before
add—on
controls
based
on
the
design
capacity
or
maximum
production
capacity
of
the
source
and
8760
hours
per
38
year.
The design capacity or maximum production
capacity includes use of coating(s)
or ink(s) with the
highest
volatile
organic
material
content
actually
used
in
practice
by
the
source.
Provided,
however,
the
Agency shall, when ain,ropriate. and upon reauest by the
permit
applicant,
limit
the
“maximum
theoretical
emissions”
of a source by the imposition of conditions
in
a federally enforceable operating permit for such
source.
Such
conditions
shall
not
be
inconsistent
with
requirement of the Clean Air Act, as amended, or any
applicable requirements established by the Board.
Such
conditions shall
be
established
in
place
of
design
capacity of maximum production capacity in calculating
the “maximum theoretical emissions” for such source and
may include, among other things, the establishment of
production limitations, capacity limitations, emission
limitations, or limitations on the volatile organic
material content of coatings or inks, or the hours of
operation of any emission source, or a combination of
any
such
limitations.
Production
or
capacity
limitations shall
be established on basis of no longer
than one month except in those cases where a limit
spanning a longer period of time is appropriate.
In
such cases,
a “rolling limit” shall be employed.
Any
production or capacity limitations shall be verified
through appropriate recordkeeping.
(Board Note:
The USEPA may deem operating permits
which do not conform to the operatin~permit program
requirements and the requirements of USEPA’s underlying
regulations,
including the requirement that limitations
be quantifiable and enforceable as a practical matter,
not “federally enforceable.”)
“Metal furniture” means a furniture piece including,
but not limited to, tables,
chairs, waste baskets,
beds,
desks,
lockers,
benches,
shelving,
file
cabinets,
lamps, and room dividers.
“Metal furniture coating” means any non—adhesive
coating
applied
to
any
furniture
piece
made
of
metal
or
any
metal
part
which
is
or
will
be
assembled
with
other
metal,
wood,
fabric,
plastic
or
glass
parts
to form a
furniture piece including, but not limited to, tables,
chairs, waste baskets, beds,
desks, lockers,
benches,
shelving,
file cabinets,
lamps,
and room dividers.
This definition shall not apply to any coating line
coating miscellaneous metal parts or products.
“Metal furniture coating facility” means a facility
that includes one or more metal furniture coating
line(s).
39
“Metal furniture coating line” means a coating line in
which any protective, decorative,
or functional coating
is applied onto the surface of metal furniture.
“Metallic shoe-type seal” means a primary or secondary
seal constructed of metal sheets (shoes) which are
joined together to form a ring,
springs, or levers
which attach the shoes to the floating roof and hold
the shoes against the tank wall,
and a coated fabric
which is suspended from the shoes to the floating roof.
“Miscellaneous fabricated product manufacturing
process”
means:
A manufacturing process involving one or more of
the following applications,
including any drying
and curing of formulations, and capable of
emitting VON:
Adhesives to fabricate or assemble components
or
products
Asphalt solutions to paper or fiberboard
Asphalt to paper or felt
Coatings or dye to leather
Coatings to plastic
Coatings to rubber or glass
Disinfectant material to manufactured items
Plastic foam scrap or “fluff” from the
manufacture of foam containers and packaging
material to form resin pallets
Resin solutions to fiber substances
Viscose
solutions
for
food
casings
The storage and handling of formulations
associated
with
the
process
described
above,
and
the use and handling of organic liquids and other
substances for clean—up operations associated with
the
process
described
in
this
definition.
“Miscellaneous formulation manufacturing process”
means:
40
A manufacturing process which compounds one or
more of the following and is capable of emitting
VON:
Adhesives
Asphalt
solutions
Caulks, sealants, or waterproofing agents
Coatings, other than paint and ink
Concrete curing compounds
Dyes
Friction materials and compounds
Resin solutions
Rubber solutions
Viscose solutions
The storage and handling of formulations
associated
with
the
process
described above,
and
the use and handling of organic liquids and other
substances for clean—up operations associated with
the process described in this definition.
“Miscellaneous
metal
parts
or
products”
means
any
metal
part
or
metal
product,
even
if
attached
to
or
combined
with
a
nonmetal
part
or
product,
except
cans,
coils,
metal
furniture,
large
appliances,
magnet
wire,
automobiles,
ships, and airplane bodies.
“Miscellaneous metal parts and products coating” means
any coating applied to any metal part or metal product,
even if attached to or combined with a nonmetal part or
product,
except cans, coils, metal furniture,
large
appliances,
and magnet wire.
Prime coat, prime
surfacer
coat,
topcoat,
and
final
repair
coat
for
automobiles
and
light—duty
trucks
are
not
miscellaneous
metal parts and products coatings.
However, underbody
anti-chip
(e.g., underbody plastisol)
automobile,
and
light—duty
truck
coatings are miscellaneous metal parts
and products coatings.
Also,
automobile or light-duty
truck refinishing coatings, coatings applied to the
exterior of marine vessels, coatings applied to the
exterior of airplanes,
and the customized topcoating of
automobiles and trucks if production is less than 35
vehicles per day are not miscellaneous metal parts and
41
products coatings
“Miscellaneous metal parts or products coating
facility” means a facility that includes one or more
miscellaneous metal parts or products coating lines.
“Miscellaneous
metal
parts
or
products coating line”
means a coating line in which any protective,
decorative, or functional coating is applied onto the
surface of miscellaneous metal parts or products.
“Miscellaneous organic chemical manufacturing process”
means:
A manufacturing process which produces by chemical
reaction, one or more of the following organic
compounds or mixtures of organic compounds and
which is capable of emitting VON:
Chemicals
listed
in
Appendix
A
of
this
Part
Chlorinated and sulfonated compounds
Cosmetic, detergent,
soap,
or surfactant
intermediaries or specialties and products
Disinfectants
Food additives
Oil
and petroleum product additives
Plasticizers
Resins or polymers
Rubber additives
Sweeteners
Varnishes
The
storage
and
handling
of
formulations
associated with the process described above and
the use and handling of organic liquids and
other
substances for clean—up operations associated with
the process described in this definition.
“Monitor” means to measure and record.
“Multiple package coating” means
a coating made from
more than one different ingredient which must be mixed
42
prior to using and has a limited pot life due to the
chemical
reaction
which
occurs
upon
mixing.
“No
detectable
volatile
organic
material
emissions”
means
a discharge of volatile organic material into the
atmosphere
as
indicated
by
an
instrument
reading
of
less
than
500
ppm
above
background
as
determined
in
accordance
with
40
CFR
60.485(c).
“Offset”
means,
with
respect
to
printing
and
publishing
operations,
use of a blanket cylinder to transfer ink
from
the
plate
cylinder
to the surface to be printed.
“Opaque
stains”
means
all
stains
that
are
not
semi—transparent stains.
“Open
top
vapor
degreasing”
means
the
batch
process
of
cleaning and removing soils from surfaces by condensing
hot solvent vapor on the colder metal parts.
“Open—ended valve” means any valve,
except pressure
relief devices, having one side of the valve in contact
with process fluid and one side open to the atmosphere,
either
directly
or
through
open
piping.
“Operator
of
gasoline
dispensing
facility”
means
any
person who is the lessee of or operates, controls or
supervises a gasoline dispensing facility.
“Organic compound” means any compound of carbon,
excluding
carbon
monoxide,
carbon
dioxide,
carbonic
acid,
metallic
carbides
or
carbonates,
and
ammoniuin
carbonate.
“Organic
material”
means
any
chemical
compound
of
carbon including diluents and thinners which are
liquids at standard conditions and which are used as
dissolvers, viscosity reducers, or cleaning agents, but
excluding
methane,
carbon
monoxide,
carbon
dioxide,
carbonic acid, metallic carbonic acid, metallic
carbide, metallic carbonates, and ammonium carbonate.
“Organic vapor” means the gaseous phase of an organic
material or a mixture of organic materials present in
the
atmosphere.
“Oven” means a chamber within which heat is used for
one
or
more
of
the
following
purposes:
dry,
bake,
cure, or polymerize a coating or ink.
“Overall control” means the product of the capture
efficiency and the control device efficiency.
43
“Overvarnish” means a transparent coating applied
directly over ink or coating.
“Owner of gasoline dispensing facility” means any
person who has legal or equitable title to a stationary
storage
tank
at
a
gasoline
dispensing
facility.
“Owner
or
operator”
means
any
person
who
owns,
operates, leases,
controls, or supervises an emission
source
or
air
pollution
control
equipment.
“Packaging
rotogravure
printing”
means
rotogravure
printing upon paper, paper board, metal
foil, plastic
film, and other substrates, which are,
in subsequent
operations,
formed into packaging products or labels
for articles to be sold.
“Packaging rotogravure printing line” means a
rotogravure printing line in which surface coatings are
applied to paper, paperboard,
foil,
film,
or other
substrates
which
are
to
be
used
to
produce
containers,
packaging products, or labels for articles.
“Paint manufacturing plant” means a plant that mixes,
blends, or compounds enamels,
lacquers,
sealers,
shellacs, stains, varnishes,
or pigmented surface
coatings.
“Paper coating” means any coating applied on paper,
plastic film,
or metallic foil to make certain
products,
including (but not limited to)
adhesive tapes
and labels, book covers, post cards,
office copier
paper,
drafting paper, or pressure sensitive tapes.
Paper
coating
includes
the
application
of
coatings
by
impregnation
and/or
saturation.
“Paper
coating
facility”
means
a
facility
that
includes
one
or
more
paper
coating
lines.
“Paper
coating
line”
means
a
coating
line
in which any
protective, decorative, or functional coating is
applied
on, saturated into, or impregnated into paper,
plastic
film,
or
metallic
foil
to
make
certain
products,
including (but not limited to) adhesive tapes
and labels, book covers, post cards, office copier
paper, drafting paper, and pressure sensitive tapes.
“Parts per million (volume)” means a volume/volume
ratio which expresses the volumetric concentration of
gaseous air contaminant in
a million unit volume of
gas.
44
“Person” means any individual,
corporation,
partnership, association, State, municipality,
political subdivision of a State; any agency,
department, or instrumentality of the United States;
and any officer, agent,
or employee thereof.
“Petroleum”
means
the
crude
oil
removed
from
the
earth
and
the
oils
derived
from
tar
sands,
shale,
and
coal.
“Petroleum
liquid”
means
crude
oil,
condensate
or
any
finished
or
intermediate
product
manufactured
at
a
petroleum
refinery,
but not including Number
2 through
Number
6
fuel oils as specified in
ASTN
D—396—69,
gas
turbine fuel oils Numbers 2-GT through 4-GT as
specified in ASTM D-2880—71 or diesel fuel oils Numbers
2—D and 4-D,
as specified in ASTM D—975—68.
“Petroleum refinery” means any facility engaged in
producing gasoline, kerosene, distillate fuel oils,
residual
fuel
oils,
lubricants,
or
other
products
through distillation of petroleum, or through
redistillation,
cracking,
or reforming of unfinished
petroleum derivatives.
“Pharmaceutical” means any compound or mixture, other
than food,
used in the prevention, diagnosis,
alleviation, treatment,
or cure of disease in human and
animal.
“Pharmaceutical coating operation” means a device in
which a coating is applied to a pharmaceutical,
including air drying or curing of the coating.
“Photochemically reactive material” means any organic
material with an aggregate of more than 20
percent
of
its total volume composed of the chemical compounds
classified below or the composition of which exceeds
any of the following individual percentage composition
limitations.
Whenever
any
photochemically
reactive
material or any constituent of any organic material may
be
classified
from
its
chemical
structure
into
more
than one of the above groups of organic materials it
shall
be
considered
as
a
member
of
the
most
reactive
group, that is, the group having the least allowable
percent of the total organic materials.
A combination of hydrocarbons, alcohols,
aldehydes,
esters,
ethers or ketones having an
olefinic or cyclo—olefinic types of unsaturation:
5 percent.
This definition does not apply to
perchloroethylene or trichloroethylene.
45
A
combination
of
aromatic
compounds
with
eight
or
more carbon atoms to the molecule except
ethylbenzene:
8 percent.
A combination of ethylbenzene, ketones having
branched hydrocarbon structures or toluene:
20
percent.
“Pigmented
coatings”
means
opaque
coatings
containing
binders and colored pigments which are formulated to
conceal the wood surface either as an undercoat or
topcoat.
“Plant” means all of the pollutant-emitting activities
which belong to the same industrial grouping, are
located on one or more contiguous or adjacent
properties, and are under the control of the same
person
(or persons under common control), except the
activities of any marine vessel.
Pollutant—emitting
activities shall be considered as part of the same
industrial grouping if they belong to the same “Major
Group”
(i.e., which have the same two—digit code)
as
described in the “Standard Industrial Classification
Manual,
1987”
(incorporated by reference in Section
219.112).
“Plasticizers” means a substance added to a polymer
composition to soften and add flexibility to the
product.
“Pneumatic rubber tire manufacture” means the
production
of
pneumatic
rubber
tires
with
a
bead
diameter up to but not including 20.0 inches and cross
section dimension up to 12.8 inches, but not including
specialty tires for antique or other vehicles when
produced on equipment separate from normal production
lines for passenger or truck type tires.
“Polystyrene plant” means any plant using styrene to
manufacture polystyrene resin.
“Polystyrene resin” means substance consisting of
styrene polymer and additives which is manufactured at
a
polystyrene
plant.
“Pressure
release”
means
the
emission
of
materials
resulting from system pressure being greater than set
pressure
of the pressure relief device.
“Pressure tank” means a tank in which fluids are stored
at a pressure greater than atmospheric pressure.
46
“Prime coat” means the first of two or more coatings
applied
to
a
surface.
“Prime surfacer coat” means a coating used to touch up
areas
on
the
surface
of
automobile
or
light—duty
truck
bodies
not adequately covered by the prime coat before
application of the top coat.
The prime surfacer coat
is
applied
between the prime coat and topcoat.
An
anti-chip
coating
applied
to
main
body
parts
(e.g.,
rocker panels, bottom of doors and fenders, and leading
edge of roof)
is a prime surfacer coat.
“Primers” means any coatings formulated and applied to
substrates to provide a
firm
bond between the substrate
and subsequent coats.
“Printing” means the application of words, designs,
and
pictures
to
a
substrate
using
ink.
“Printing line” means an operation consisting of a
series of one or more roll printers and any associated
roll coaters,
drying areas, and ovens wherein one or
more coatings are applied, dried, and/or cured.
“Process”
means
any
stationary
emission
source
other
than
a
fuel
combustion
emission
source
or
an
incinerator.
“Process
unit”
means
components
assembled
to
produce,
as intermediate or final products, one or more of the
chemicals listed in 35
Ill. Adm. Code 219 Appendix A.
A process unit can operate independently if supplied
with sufficient feed or raw materials and sufficient
storage
facilities
for
the
product.
“Process
unit
shutdown”
means
a
work
practice
or
operational procedure that stops production from a
process
unit
or
part
of
a
process
unit.
An
unscheduled
work practice or operational procedure that stops
production
from
a
process
unit
or
part
of
a
process
unit for less than 24 hours
is not a process unit
shutdown.
The use of spare components and technically
feasible bypassing of components without stopping
production is not a process unit shutdown.
“Production equipment
exhaust
system”
means
a
system
for collecting and directing into the atmosphere
emissions of volatile organic material from reactors,
centrifuges, and other process emission sources.
“Publication rotogravure printing line” means a
47
rotogravure
printing
line
in which coatings are applied
to
paper
which
is
subsequently
formed
into
books,
magazines,
catalogues, brochures, directories,
newspaper supplements, or other types of printed
material.
“Purged process fluid” means liquid or vapor from a
process unit that contains volatile organic material
and that results from flushing or cleaning the sample
line(s)
of
a
process
unit
so
that
an
uncontaminated
sample
may
then
be
taken
for
testing
or
analysis.
“Reactor” means a vat, vessel, or other device in which
chemical reactions take place.
“Reasonably Available Control Technology
(RACT)”
means
the lowest emission limitation that an emission source
is capable of meeting by the application of control
technology that is reasonably available considering
technological and economic feasibility.
“Refiner” means any person who owns,
leases,
operates,
controls, or supervises a refinery.
“Refinery fuel gas” means any gas which is generated by
a petroleum refinery process unit and which is
combusted
at
the
refinery,
including
any
gaseous
mixture
of
natural
gas
and
fuel
gas.
“Refinery unit,
process unit or unit” means a set of
components which are a part of a basic process
operation such as distillation, hydrotreating,
cracking, or reforming of hydrocarbons.
“Refrigerated condenser” means a surface condenser in
which the coolant supplied to the condenser has been
cooled by a mechanical device, other than by a cooling
tower or evaporative spray cooling, such as
refrigeration unit or steam chiller unit.
“Reid vapor pressure” means the standardized measure of
the
vapor
pressure
of
a
liquid
in
pounds
per
square
inch absolute
(psia)
at 100°F(37.8°C).
“Repair coatings” means coatings used to correct
imperfections
or
damage
to furniture surface.
“Repaired” means,
for the purpose of Subpart Q of this
Part,
that equipment component has been adjusted, or
otherwise altered, to eliminate a leak.
“Residual fuel oil” means fuel oils of grade No.
4,
5
48
and
6 as specified in detailed requirements for fuel
oils ASTM D—396—69
(1971).
“Retail outlet” means any gasoline dispensing facility
at which gasoline is sold or offered for sale for use
in
motor
vehicles.
“Roll
coater”
means
an
apparatus
in
which
a
uniform
layer
of
coating
is
applied
by
means
of one or more
rolls
across
the
entire
width
of
a
moving
substrate
“Roll printer” means an apparatus used in the
application
of
words,
designs,
or
pictures
to
a
substrate,
usually by means of one or more rolls each
with only partial coverage.
“Roll printing” means the application of words,
designs, and pictures to a substrate usually by means
of a series of hard rubber or metal rolls each with
only
partial
coverage.
“Roller coating” means a method of applying a coating
to a sheet or strip in which the coating is transferred
by a roller or series of rollers.
“Rolling limit” means that a limit or limitation must
not exceed an annual limit rolled on a monthly basis;
that is,
a monthly production or capacity level must be
determined for each Parameter subiect to a production
or
capacity
limitations
and
added
to
the eleven prior
monthly levels for monthly comparison with the annual
limit.
“Rotogravure printing” means the application of words,
designs, and pictures to a substrate by means of a roll
printing technique- in which the pattern to be applied
is recessed relative to the non—image area.
“Rotogravure printing line” means a printing line in
which
each
roll
printer
uses
a
roll
with
recessed
areas
for
applying
an
image
to
a
substrate.
“Safety relief valve” means a valve which is normally
closed and which is designed to open in order to
relieve excessive pressures within a vessel or pipe.
“Sanding sealers” means any coatings formulated for and
applied to bare wood for sanding and to seal the wood
for
subsequent
application
of
varnish.
To
be
considered
a
sanding sealer a coating must be clearly
labelled as such.
49
“Sealer” means a coating containing binders which seals
wood prior to the application of the subsequent
coatings.
“Sensor”
means
a
device
that
measures
a
physical
quantity or the change in a physical quantity such as
temperature, pressure, flow rate,
pH, or liquid level.
“Semi—transparent stains” means stains containing dyes
or semi—transparent pigments which are formulated to
enhance
wood
grain
and
change the color of the surface
but not to conceal the surface, including, but not
limited to,
sap stain, toner,
non-grain raising stains,
pad stain, or spatter stain.
“Set of safety relief valves” means one or more safety
relief valves designed to open in order to relieve
excessive pressures in the same vessel or pipe.
“Sheet basecoat” means a coating applied to metal when
the metal is in sheet form to serve as either the
exterior or interior of a can for either two—piece or
three—piece cans.
“Side-seam spray coat” means a coating applied to the
seam of a three—piece can.
“Single coat” means one coating application applied to
a metal surface.
“Solvent” means a liquid substance that is used to
dissolve or dilute another substance.
“Solvent cleaning” means the process of cleaning soils
from surfaces by cold cleaning, open top vapor
degreasing,
or conveyorized degreasing.
“Specified air contaminant” means any air contaminant
as to which this Part contains emission standards or
other
specific
limitations.
“Splash loading” means a method of loading a tank,
railroad tank car, tank truck,
or trailer by use of
other than a submerged loading pipe.
“Stack” means a flue or conduit, free—standing or with
exhaust
port above the roof of the building on which it
is mounted, by which air contaminants are emitted into
the atmosphere.
“Standard conditions” means a temperature of 70°Fand a
pressure of 14.7 psia.
50
“Standard
cubic
foot
(scf)”
means
the volume of one
cubic
foot of
gas
at
standard
conditions.
“Standard Industrial Classification Manual” means the
Standard
Industrial
Classification
Manual
(1987),
Superintendent
of
Documents,
U.S.
Government
Printing
Office,
Washington,
DC
20402
(incorporated
by
reference
in
Section
219.112).
“Start—up”
means
the
setting
in
operation
of
an
emission source for any purpose.
“Stationary emission source” and “Stationary source”
mean an emission source which is not self—propelled.
“Storage tank or storage vessel” means any stationary
tank, reservoir or container used for the storage of
VOL.
“Styrene devolatilizer unit” means equipment performing
the function of separating unreacted styrene monomer
and
other
volatile
components
from
polystyrene
in
a
vacuum
devolatilizer.
“Styrene
recovery
unit”
means
equipment
performing
the
function
of
separating
styrene
monomer
from
other
less
volatile
components
of the styrene devolatilizer unit’s
output.
The separated styrene monomer may be reused as
a raw material in the polystyrene plant.
“Submerged loading pipe” means any discharge pipe or
nozzle which meets either of the following conditions:
Where the tank is filled from the top, the end of
the discharge pipe or nozzle must be totally
submerged when the liquid level is 15 cm
(6 in.)
above the bottom of the tank.
Where the tank is filled from the side,
the
discharge pipe or nozzle must be totally submerged
when the liquid level is 46 cm
(18 in.) above the
bottom of the tank.
“Substrate” means the surface onto which a coating is
applied
or
into
which
a
coating
is
impregnated.
“Surface condenser” means a device which removes a
substance from a gas stream by reducing the temperature
of the stream, without direct contact between the
coolant and the stream.
51
“Synthetic organic chemical or polymer manufacturing
plant” means a plant that produces,
as intermediates or
final products, one or more of the chemicals or
polymers listed in 35 Ill.
Adm. Code 219 Appendix A.
“Tablet coating operation” means a pharmaceutical
coating operation in which tablets are coated.
“Thirty—day rolling average” means any value
arithmetically averaged over any consecutive
thirty-days.
“Three—piece can” means a can which is made from a
rectangular sheet and two circular ends.
“Topcoat” means a coating applied in a multiple coat
operation other than prime coat, final repair coat, or
prime surfacer coat.
“Topcoat operation” means all topcoat spray booths,
flash-off areas,
and bake ovens at a facility which are
used to apply,
dry,
or cure the final coatings
(except
final off—line repair) on components of automobile or
light-duty truck bodies.
“Transfer efficiency” means the ratio of the amount of
coating solids deposited onto a part or product to the
total amount of coating solids used.
“Tread end cementing” means the application of a
solvent-based cement to the tire tread ends.
“True Vapor pressure” means the equilibrium partial
pressure
exerted
by
a
volatile
organic
liquid
as
determined in accordance with methods described in
American Petroleum Institute Bulletin 2517,
“Evaporation Loss From Floating Roof Tanks,” second
edition, February 1980 (incorporated by reference in
Section 219.112)
“Turnaround” means the procedure of shutting down an
operating refinery unit, emptying gaseous and liquid
contents to do inspection, maintenance and repair work,
and putting the unit back into production.
“Two-piece can” means a can which
is drawn from a
shallow cup and requires only one end to be attached.
“TJndercoaters” means any coatings formulated for and
applied to substrates to provide
a smooth surface for
subsequent coats.
52
“Undertread cementing” means the application of a
solvent—based cement to the underside of a tire tread.
“Unregulated safety relief valve” means a safety relief
valve
which
cannot
be
actuated
by
a
means
other
than
high
pressure
in
the
pipe
or
vessel
which
it
protects.
“Vacuum producing system” means any reciprocating,
rotary, or centrifugal blower or compressor or any jet
ejector
or
device
that
creates
suction
from
a
pressure
below atmospheric and discharges against a greater
pressure.
“Valves
not
externally
regulated”
means
valves
that
have no external controls, such as in—line check
valves
“Vapor balance system” means any combination of pipes
or hoses which creates a closed system between the
vapor spaces of an unloading tank and a receiving tank
such that vapors displaced from the receiving tank are
transferred to the tank being unloaded.
“Vapor collection system” means all piping,
seals,
hoses,
connections, pressure—vacuum vents, and other
possible sources between the gasoline delivery vessel
and the vapor processing unit and/or the storage tanks
and vapor holder.
“Vapor control system” means any system that limits or
prevents release to the atmosphere of organic material
in the vapors displaced from a tank during the transfer
of gasoline.
“Vapor-mounted primary seal” means a primary seal
mounted with an air space bounded by the bottom of the
primary seal,
the tank wall,
the liquid surface and the
floating roof.
“Vapor recovery system” means a vapor gathering system
capable
of
collecting all VON vapors and gases
discharged from the storage tank and a vapor disposal
system capable of processing such VON vapors and gases
so as to prevent their emission to the atmosphere.
“Vehicle” means a device by which any person or
property may be propelled, moved, or drawn upon a
highway, excepting a device moved exclusively by human
power or used exclusively upon stationary rails or
tracks.
“Vinyl coating” means any topcoat or printing ink
53
applied to vinyl coated fabric or vinyl sheets.
Vinyl
coating does not include plastisols.
“Vinyl coating facility” means a facility that includes
one or more vinyl coating line(s).
“Vinyl coating line” means
a coating line in which any
protective,
decorative
or
functional
coating
is
applied
onto vinyl coated fabric or vinyl sheets.
“Volatile
organic
liquid”
means any substance which is
liquid
at
storage
conditions
and
which
contains
volatile
organic
compounds.
“Volatile organic material
(VON) or volatile organic
compound
(VOC)” means any
organic
compound which
participates in atmospheric photochemical reactions.
This includes any organic compound other than the
following compounds:
methane, ethane, methyl
chloroform
(1,1, l-trichloroethane), CFC-113
(trichlorotrifluoroethane), inethylene chloride
(dichloromethane), CFC-l1
(trichiorofluoromethane)
CFC-l2
(dichlorodifluoromethane), CFC-22
(chlorodifluoromethane),
FC-23
(trifluoromethane),
CFC-114
(dichlorotetrafluoroethane), CFC-ll5
(chloropentafluoroethane), HCFC—l23
(dichlorotrifluoroethane),
HFC-134a
(tetrafluoroethane),
HCFC-141b
(dichlorofluoroethane)
and HCFC-142b (chlorodifluoroethane).
These compounds
have been determined to have negligible photochemical
reactivity.
For
purposes
of
determining
compliance
with
emission
limits,
VOC
will
be
measured
by
the
approved
test
methods.
Where such a method also inadvertently
measures compounds with negligible photochemical
reactivity,
an owner or operator may exclude these
negligibly reactive compounds when determining
compliance with an emissions standard.
“Volatile petroleum liquid” means any petroleum liquid
with a true vapor pressure that is greater than 1.5
psia
(78 millimeters of mercury)
at standard
conditions.
“Wash coat” means a coating containing binders which
seals
wood surfaces, prevents undesired staining, and
controls
penetration.
“Wastewater
(oil/water)
separator”
means
any
device
or
piece of equipment which utilizes the difference in
density
between
oil
and
water
to remove oil and
54
associated chemicals of water,
or any device, such as a
flocculation tank or a clarifier, which removes
petroleum derived compounds from waste water.
“Web” means a substrate which is printed in continuous
roll-fed presses.
“Wood
furniture”
means
room
furnishings
including
cabinets
(kitchen,
bath,
and vanity), tables, chairs,
beds,
sofas,
shutters, art objects, wood paneling, wood
flooring,
and
any
other
coated
furnishings
made
of
wood, wood composition, or fabricated wood materials.
“Wood furniture coating facility” means a facility that
includes
one
or
more
wood
furniture
coating
line(s).
“Wood furniture coating line” means a coating line in
which any protective,
decorative, or functional coating
is applied onto wood furniture.
“Woodworking” means the shaping, sawing, grinding,
smoothing, polishing, and making into products of any
form or shape of wood.
Section 219.105
Testing Methods and Procedures
a)
Coatings, Inks and Fountain Solutions
The
following
test
methods
and
procedures
shall
be
used
to determine compliance of applied coatings,
inks, and
fountain solutions with the limitations set forth in
this Part.
1)
sampling:
Samples collected for analyses shall be
one—liter taken into a one—liter container at a
location and time such that the sample will be
representative of the coating as applied (i.e.,
the
sample
shall
include
any
dilution
solvent
or
other VOM added during the manufacturing process).
The container must be tightly sealed immediately
after the sample is taken.
Any solvent or other
VON added after the sample is taken must be
measured and accounted for in the calculations in
subsection
(a) (3).
For multiple package coatings,
separate samples of each component shall be
obtained.
A mixed sample shall not be obtained as
it will cure in the container.
Sampling
procedures shall follow the guidelines presented
in:
A)
ASTM
D3925-Bl(1985)
standard
practice
for
sampling liquid paints and related pigment
55
coating.
This
practice
is
incorporated
by
reference
in
Section
219.112.
B)
ASTM E300-86 standard practice for sampling
industrial chemicals. This practice is
incorporated by reference in Section 219.112.
2)
Analyses:
The
applicable
analytical
methods
specified below shall be used to determine the
composition of coatings,
inks, or fountain
solutions
as
applied.
A)
Method 24 of 40 CFR 60, Appendix A,
incorporated
by
reference
in
Section
219.112,
shall be used to determine the
VON
content
and density of coatings.
If it is
demonstrated to the satisfaction of the
Agency and the USEPA that plant coating
formulation data are equivalent to Method 24
results, formulation~data may be used.
In
the event of
any
inconsistency
between
a
Method 24 test and a facility’s formulation
data, the Method 24 test will govern.
B)
Method 24A of 40 CFR Part 60, Appendix A,
incorporated by reference in Section 219.112,
shall be used to determine the VOM content
and density of rotogravure printing inks and
related coatings.
If it is demonstrated to
the satisfaction of the Agency and USEPA that
the plant coating formulation data are
equivalent to Method 24A results,
formulation
data may be used.
In the event of any
inconsistency
between
a
Method
24A test and a
facility’s formulation data,
the Method 24A
test will govern.
C)
The following ASTM methods are the analytical
procedures for determining VON:
i)
ASTM Dl475-85: Standard test method for
density
of
paint,
varnish,
lacquer
and
related
products.
This
test
method
is
incorporated
by
reference
in
Section
219.112.
ii)
ASTM
D2369—87:
Standard
test
method
for
volatile content of a coating. This test
method is incorporated by reference in
Section 219.112.
iii) ASTM D3792-86: Standard test method for
56
water
content
of
water-reducible
paints
by direct injection into a gas
chromatograph. This test method is
incorporated by reference in Section
219.112.
iv)
ASTM D4017-8l(1987): Standard test
method
for
water
content
in
paints
and
paint
materials
by
the
Karl
Fischer
method.
This
test
method
is
incorporated
by
reference
in
Section
219.112.
v)
ASTN
D4457—85:
Standard
test
method
for
determination
of
dichloromethane
and
1,1,1, trichloroethane in paints and
coatings by direct injection into a gas
chromatograph.
(The procedure
delineated
above can be used to develop
protocols for any compounds specifically
exempted from the definition of VON.)
This test method is incorporated by
reference in Section 219.112.
vi)
ASTM D2697-86: Standard test method for
volume non—volatile matter in clear or
pigmented
coatings.
This test method is
incorporated
by
reference
in
Section
219.112.
vii)
ASTM
D3980-87: Standard practice for
interlaboratory testing of paint and
related materials. This practice is
incorporated by reference in Section
219.112.
viii)
ASTM E180-85: Standard practice for
determining the precision data of
ASTM methods for analysis of and
testing
of
industrial
chemicals.
This practice is incorporated by
reference
in
Section
219.112.
ix)
ASTM
D2372—85: Standard method of
separation
of
vehicle
from
solvent-reducible paints. This method is
incorporated
by
reference
in
Section
219.112.
D)
Use of an adaptation to any of the analytical
methods specified in subsections
(a) (2) (A),
(B), and
(C) may not be used unless approved
by the Agency and USEPA.
An owner or
57
operator must submit sufficient documentation
for
the
Agency
and
USEPA
to
find
that
the
analytical
methods
specified
in
subsections
(a)(2)(A),
(B),
and
(C)
will
yield
inaccurate
results
and
that
the
proposed
adaptation
is
appropriate.
3)
Calculations:
Calculations
for
determining
the
VON content, water content and the content of any
compounds which are specifically exempted from the
definition of VON of coatings, inks and fountain
solutions
as
applied
shall
follow
the
guidance
provided
in
the
following
documents.
A)
“A Guide for Surface Coating Calculation”,
EPA-340/1-86-0l6,
incorporated by reference
in Section 219.112.
B)
“Procedures for Certifying Quantity of
Volatile Organic Compounds Emitted by Paint,
Ink and Other Coatings”
(revised June 1986),
EPA-450/3-84-0l9,
incorporated by reference
in Section 219.112.
C)
“A Guide for Graphic Arts Calculations”,
August
1988,
EPA-340/1-88-003,
incorporated
by
reference
in
Section
219.112
b)
Automobile or Light-Duty Truck Test Protocol
The protocol for testing, including determining the
transfer efficiency,
of coating applicators at topcoat
coating operations at an automobile assembly facility
shall follow the procedure in:
“Protocol for
Determining
the
Daily
Volatile
Organic
Compound
Emission
Rate
of
Automobile
and
Light-Duty
Truck
Topcoat Operations”, December 1988, EPA—450/3—88—018,
incorporated by reference in Section 219.112.
c)
Capture System Efficiency Test Protocols
1)
Applicability
The requirements of subsection
(c) (2)
shall apply
to
all
VON
emitting
processes
employing
capture
equipment (e.g., hoods, ducts),
except those cases
noted below.
A)
If a source installs a permanent total
enclosure
(PTE)
that meets Agency and USEPA
specifications, and which directs all VOM to
a
control
device,
then
the
source
is
exempted
58
from the requirements described in subsection
(c) (2).
The Agency and USEPA specifications
to
determine
whether
a
structure
is
considered
a
PTE
are
given
in
Procedure
T
of
Appendix
B
of
this
Part.
In
this
instance,
the
capture
efficiency
is
assumed
to
be
100
percent
and
the
source
is
still
required
to
measure
control efficiency using appropriate
test methods as specified in subsection
(d).
B)
If
a
source
uses
a
control
device
designed
to
collect
and
recover
VON
(e.g.,
carbon
adsorber), an explicit measurement of capture
efficiency
is
not
necessary
provided
that
the
conditions
given
below
are
met.
The
overall
control
of
the
system
can
be
determined
by
directly comparing the input liquid VON to
the recovered liquid VOM.
The general
procedure for use in this situation is given
in
40
CFR
60.433,
incorporated
by
reference
in Section 219.112, with the following
additional restrictions:
i)
The source must be able to equate
solvent usage with solvent recovery on a
24-hour
(daily)
basis,
rather than a
30-day weighted average, within 72 hours
following the 24-hour period.
In
addition, one of the following two
criteria must be met:
ii)
The solvent recovery system (i.e
•,
capture
and
control
system)
must
be
dedicated
to
a
single
process
line
(e.g.,
one
process
line
venting
to
a
carbon
adsorber
system),
or
iii)
If the solvent recovery system controls
multiple process lines, then the source
must be able to demonstrate that the
overall
control
(i.e.,
the
total
recovered
solvent
VOM
divided
by
the
sum
of liquid VON input to all process lines
venting to the control system) meets or
exceeds
the
most
stringent
standard
applicable
for
any
process
line
venting
to
the
control
system.
2)
Specific Requirements
The
capture
efficiency
of
a
process
line
shall
be
measured using one of the four protocols given
59
below.
Any error margin associated with a test
protocol may not be incorporated into the results
of
a
capture
efficiency
test.
If
these
techniques
are
not
suitable
for
a
particular
process,
then
the source may use an alternative capture
efficiency protocol, provided that the alternative
protocol is approved by the Agency and approved by
the USEPA as a SIP revision.
A)
Gas/gas method using temporary total
enclosure
(TTE).
The Agency and USEPA
specifications to determine whether a
temporary enclosure is considered a TTE are
given in Procedure T of Appendix B of this
Part.
The capture efficiency equation to be
used for this protocol
is:
CE
=
Gw/(Gw
+
Fw)
where:
CE
=
capture
efficiency,
decimal
fraction
Gw
=
mass of VON captured and delivered
to control device using a TTE
Fw
=
mass of fugitive
VON
that
escapes
from a TTE
Procedure
G.2
contained
in
Appendix
B
of
this
Part is used to obtain Gw.
Procedure F.l
in
Appendix B of this Part is used to obtain Fw.
B)
Liquid/gas method using TTE.
The Agency and
USEPA specifications to determine whether a
temporary enclosure is considered a TTE are
given
in
Procedure
T
of
Appendix
B
of
this
Part.
The
capture
efficiency
equation
to
be
used for this protocol
is:
CE
=
(L
—
F~)/L
where:
CE
=
capture
efficiency,
decimal
fraction
L
=
mass of liquid VON input to
process
Fw
=
mass
of
fugitive
VON
that
escapes
from a TTE
Procedure L contained in Appendix B of this
Part is used to obtain L.
Procedure F.1 in
60
Appendix
B
of
this
Part
is
used
to
obtain
Fw.
C)
Gas/gas method using the building or room
(building or room enclosure)
in which the
affected source is located as the enclosure
and in which “F” and “G” are measured while
operating only the affected facility.
All
fans and blowers in the building or room must
be operated as they would under normal
production.
The capture efficiency equation
to
be
used
for
this
protocol
is:
CE
=
G/(G
+
F8)
where: CE
=
capture efficiency, decimal
fraction
G
=
mass
of VON captured and
delivered to control device
=
mass of fugitive VON that escapes
from building enclosure
Procedure
G.2
contained
in
Appendix
B
of
this
Part is used to obtain G.
Procedure F.2 in
Appendix
B
of
this
Part
is
used
to
obtain
F8.
D)
Liquid/gas method using the building or room
(building or room enclosure)
in which the
affected source is located as the enclosure
and in which “F” and “L” are measured while
operating only the affected facility.
All
fans
and
blowers
in
the
building
or
room
must
be
operated
as
they
would
under
normal
production.
The capture efficiency equation
to be used for this protocol
is:
CE
=
(L
—
F8)/L
where: CE
=
capture efficiency, decimal
fraction
L
=
mass of liquid VON input to
process
F8
=
mass of fugitive VOM that escapes
from building enclosure
Procedure L contained in Appendix B of this
section is used to obtain L.
Procedure F.2
in Appendix B of this section is used to
obtain F8.
61
3)
Recordkeeping
and
Reporting
A)
All affected facilities must maintain a copy
of
the
capture
efficiency
protocol
submitted
to the Agency and the USEPA on file.
All
results
of
the
appropriate
test
methods
and
capture
efficiency
protocols
must
be
reported
to
the
Agency
within
sixty
(60)
days
of
the
test date.
A copy of the results must be
kept on file with the source for a period of
three
(3) years.
B)
If any changes are made to capture or control
equipment,
then the source
is required to
notify the Agency and the USEPA of these
changes and
a new test may be required by the
Agency
or
the
USEPA.
C)
The source must notify the Agency 30 days
prior to performing any capture efficiency or
control test.
At that time, the source must
notify the Agency which capture efficiency
protocol and control device test methods will
be used.
D)
Sources utilizing a
PTE
must demonstrate that
this enclosure meets the requirement given in
Procedure T
(in Appendix B of this Part)
for
a
PTE
during any testing of their control
device.
E)
Sources utilizing a TTE must demonstrate that
their TTE meets the requirements given in
Procedure T
(in Appendix B of this Part)
for
a TTE during testing of their control device.
The source must also provide documentation
that the quality assurance criteria for a TTE
have
been
achieved.
d)
Control
Device
Efficiency
Testing
and
Monitoring
1)
The control device efficiency shall be determined
by simultaneously measuring the inlet and outlet
gas
phase
VON
concentrations
and
gas
volumetric
flow rates
in accordance with the gas phase test
methods
specified
in
subsection
(f).
2)
Any owner or operator that uses an afterburner or
carbon adsorber to comply with any Section of this
Part shall use USEPA approved continuous
monitoring equipment which is installed,
62
calibrated, maintained, and operated according to
vendor
specifications
at
all
times
the
afterburner
or carbon adsorber is in use.
The continuous
monitoring equipment must monitor the following
parameters:
A)
Combustion
chamber
temperature
of
each
afterburner.
B)
Temperature rise across each catalytic
afterburner
bed
or
VON
concentration
of
exhaust.
C)
The VON concentration of each carbon
adsorption bed exhaust.
e)
Overall
Efficiency
1)
The overall efficiency of the emission control
system shall be determined as the product of the
capture system efficiency and the control device
efficiency or by the liquid/liquid test protocol
as specified in 40 CFR 60.433, incorporated by
reference in Section 219.112,
(and
revised
by
subsection
(c) (1) (B)
for each solvent recovery
system.
In those cases in which the overall
efficiency
is
being
determined
for
an
entire
line,
the
capture
efficiency
used
to
calculate
the
product
of
the
capture
and
control
efficiency
is
the
total
capture
efficiency
over
the
entire
line.
2)
For coating lines which are both chosen by the
owner or operator to comply with Section
219.207(a),
(d),
(e),
(f), or
(g) by the
alternative
in
Section
219.207(b)
(2)
and meet the
criteria
allowing
them
to
comply
with
Section
219.207
instead
of
Section
219.204, the overall
efficiency of the capture system and control
device,
as determined by the test methods and
procedures specified in subsections
(c),
(d) and
(e) (1),
shall be no less than the equivalent
overall efficiency which shall be calculated by
the following equation:
E
=
(VOM8
-
VONti/VOMa)
x
100
where:
E
=
Equivalent overall efficiency of the
capture system and control device as a
percentage,
63
VOMa
=
Actual VON content of a coating,
or the
daily-weighted average VON content of
two or more coatings
(if more than one
coating is used), as applied to the
subject coating line as determined by
the applicable test methods and
procedures specified in subsection
(a) (4) (i) of this Part in units of kg
VOM/1
(lb
VON/gal)
of coating solids as
applied,
VOM~
=
The VON emission limit specified in
Section 219.207(a) or
(b)
in units of kg
VON/i
(lb VOM/gal)
of coating solids as
applied.
f)
Volatile Organic Material Gas Phase Source Test Methods
The methods in 40 CFR Part
60,
Appendix
A,
incorporated
by reference in Section 219.112 delineated below shall
be used to determine control device efficiencies.
1)
40 CFR Part 60, Appendix A, Method 18,
25 or 25A,
incorporated by reference in Section 219.112 as
appropriate to the conditions at the site,
shall
be used to determine VOM concentration.
Method
selection shall be based on consideration of the
diversity
of
organic species present and their
total concentration and on consideration of the
potential presence of interfering gases.
Except
as
indicated
in
subsections
(f) (1) (A) and
(B)
below,
the test shall consist of three separate
runs, each lasting a minimum of 60 mm, unless the
Agency and the USEPA determine that process
variables dictate shorter sampling times.
A)
When the method is to be used to determine
the efficiency of a carbon adsorption system
with a common exhaust stack for all the
individual
adsorber
vessels,
the test shall
consist of three separate runs, each
coinciding with one or more complete
sequences through the adsorption cycles of
all the individual adsorber vessels.
B)
When the method is to be used to determine
the
efficiency
of
a
carbon
adsorption
system
with individual exhaust stacks for each
adsorber vessel, each adsorber vessel shall
be tested individually.
The test for each
adsorber vessel shall consist of three
separate runs.
Each
run
shall coincide with
64
one or more complete adsorption cycles.
2)
40 CFR Part 60, Appendix A, Method
1 or 1A,
incorporated by reference in Section 219.112,
shall
be
used
for
sample
and velocity traverses.
3)
40
CFR
Part
60,
Appendix
A,
Method
2,
2A,
2C
or
2D, incorporated by reference in Section 219.112,
shall be used for velocity and volumetric flow
rates.
4)
40 CFR Part 60, Appendix A, Method
3,
incorporated
by reference in Section
219.112,
shall be used for
gas
analysis.
5)
40 CFR Part 60, Appendix A, Method 4,
incorporated
by reference in Section 219.112, shall be used for
stack gas moisture.
6)
40 CFR Part 60, Appendix A, Methods
2,
2A,
2C,
2D,
3 and 4, incorporated by reference in Section
219.112,
shall
be
performed,
as applicable,
at
least twice during each test run.
7)
Use of an adaptation to any of the test methods
specified in subsections
(f) (1),
(2),
(3),
(4),
(5)
and
(6) may not be used unless approved by the
Agency and the USEPA.
An owner or operator must
submit sufficient documentation for the Agency and
the USEPA to find that the test methods specified
in subsections
(f)(1),
(2),
(3),
(4),
(5)
and
(6)
will
yield
inaccurate
results
and that the
proposed
adaptation
is
appropriate.
g)
Leak Detection Methods for Volatile Organic Material
Owners or operators required by this Part to carry out
a leak detection monitoring program shall comply with
the following requirements:
1)
Leak Detection Monitoring
A)
Monitoring
shall
comply
with
40
CFR
60,
Appendix A, Method 21,
incorporated by
reference in Section 219.112.
B)
The detection instrument shall meet the
performance criteria of Method 21.
C)
The
instrument
shall
be
calibrated
before
use
on
each
day
of
its
use
by
the
methods
specified in Method 21.
65
D)
Calibration gases shall be:
i)
Zero air (less than lOppm of hydrocarbon
in air);
and
ii)
A mixture
of
methane
or
n—hexane
and
air
at
a
concentration
of
approximately,
but
no
less
than,
10,000
ppm
methane
or
n-hexane.
E)
The
instrument
probe
shall
be
traversed
around
all
potential
leak
interfaces
as
close
possible as described in Method 21.
2)
When equipment is tested for compliance with no
detectable emissions as required, the test shall
comply with the following requirements:
A)
The requirements of subsections
(g) (1) (A)
through
(g) (1) (E)
above shall apply.
B)
The
background
level
shall
be
determined
as
set
forth
in
Method
21.
3)
Leak detection tests shall be performed consistent
with:
A)
“APTI Course SI 417 controlling Volatile
Organic
Compound
Emissions
from
Leaking
Process Equipment”, EPA—450/2—82—015,
incorporated by reference in Section 219.112.
B)
“Portable Instrument User’s Manual for
Monitoring VOC Sources”, EPA—340/l—86—015,
incorporated by reference in Section 219.112.
C)
“Protocols for Generating Unit-Specific
Emission Estimates for Equipment Leaks of VOC
and
VHAP”,
EPA-450/3-88-OlO,
incorporated
by
reference
in
Section
219.112.
D)
“Petroleum Refinery Enforcement Manual”,
EPA-340/1-80-008,
incorporated by reference
in
Section
219.122.
h)
Bulk
Gasoline
Delivery
System
Test
Protocol
1)
The
method
for
determining
the
emissions
of
gasoline from a vapor recovery system are
delineated in 40 CFR 60, Subpart XX, Section
60.503, incorporated by reference in Section
66
219.112.
2)
Other
tests
shall
be
performed
consistent
with:
A)
“Inspection Manual for Control of Volatile
Organic Emissions from Gasoline Marketing
Operations:
Appendix
D”,
EPA-340/l—80-012,
incorporated by reference in Section 219.112.
B)
“Control
of
Hydrocarbons
from
Tank
Truck
Gasoline
Loading
Terminals:
Appendix
A”,
EPA-450/2-77-026,
incorporated
by
reference
in Section 219.112.
fl
Notwithstanding
other
requirements
of
this
Part,
upon
request
of
the
A~encv
where
it
is
necessary
to
demonstrate
compliance,
an
owner
or
operator
of
an emission source which is subiect to this Part
shall,
at
his
own
expense,
conduct tests in
accordance
.with
the
applicable
test
methods
and
procedures specified in this Part.
~
Nothing in the Section shall limit the authority
of
the
USEPA
pursuant
to
the
Clean
Air
Act,
as
amended, to require testing.
Section
219.106
Compliance
Dates
a)
Compliance with the requirements of all rules
is
required
by
Nay
1,
1992,
or
sixty
days
after
a
final
decision
by
a
federal
court
of the general a~~ealof
$-h~i
,-~•i i.
i
i_-~
—
_________________________________________________________________________
—
UCEPA,
No.
90-2770
(and
Consolidated
Cases)
(7th
Cir.)), whichever is latcr,
consistent with the
nvi~ir~rit
r~f
rtir~ri
~
‘ T”
~---vironincntal
~
-if~r~p~r
‘i~r~i~rt~r
-
b)
-Compliance
with
t he
requiremcnts
of
provisions
of
this
part
specifically
applicable
to
a
category
of
sources
which
is
the
same
-
h~
as
any
of
~
h’.~
the
)‘p”.
individual
~
appeals
~
of
~
th-...
~
following
a
final
decision
by
a
federal
court
of
the
appeal of the FIP impacting the specific category of
sourccs,
whichever
is
later,
consistent
with
the
provisions
of
Cection
219.103.
F’
11L’
Compliance
with
the
requirements
of
all
rules
is
required
by
May
15,
1992,
consistent with the provisions of Section 219.103.
Section
219.107
Afterburners
The operation of any natural gas fired afterburner and capture
system used to comply with this Part is not required during the
67
period of November
1 of any year to April
1 of the following year
provided that the operation of such devices is not required for
purposes of occupational safety or health, or for the control of
toxic substances,
odor nuisances,
or other regulated pollutants.
Section 219.108
Exemptions, Variations, and Alternative Means
of Control or Compliance Determinations
Notwithstanding the provisions of any other Sections of this
Part, any exemptions, variations or alternatives to the control
requirements, emission limitations, or test methods set forth in
this Part shall be effective only when approved by the Agency and
approved by the tJSEPA as a SIP revision.
Section 219.109
Vapor Pressure of Volatile Organic Liquids
a)
If
the
VOL~-consists
of
only
a
single
compound,
the
vapor
pressure
shall
be
determined
by
ASTM
Method
D2879—86
(incorporated
by
reference
in
Section
219.112)
or
the
vapor
pressure
may
be
obtained
from
a
published
source
such
as:
Boublik, T.,
V. Fried and E.
Hala,
“The Vapor Pressure of Pure Substances,” Elsevier
Scientific Publishing Co., New York
(1973); Perry’s
Chemical Engineer’s Handbook, McGraw-Hill Book Company
(1984);
CRC Handbook of Chemistry and Physics, Chemical
Rubber Publishing Company (1986—87); and Lange’s
Handbook of Chemistry, John A.
Dean, editor,
McGraw-Hill Book Company (1985).
b)
If the VOL is a mixture,
the
vapor
pressure
shall
be
determined by ASTM Method D2879—86 (incorporated by
reference in Section 219.112)
or by the following
equation:
~voL
=
EP1 X~
where:
~vo(
=Total vapor pressure of the mixture,
n
=
Number
of
components
in
the
mixture,
i
=
Subscript
denoting
an
individual
component,
=
Vapor pressure of a component
determined in accordance with
Subpart
A
of
this
Part
68
X1
=
Mole
fraction
of
the
component
in
the
total
mixture.
Section
219.110
Vapor
Pressure
of
Organic
Material
or
Solvent
a)
If
the
organic
material
or
solvent
consists
of
only
a
single
compound,
the
vapor
pressure
shall
be
determined
by
ASTM
Method
D2879—86
(incorporated
by
reference
in
Section
219.112)
or
the
vapor
pressure
may
be
obtained
from
a
published
source
such
as:
Boublik,
T.,
V.
Fried
and
E.
Hala,
“The
Vapor
Pressure
of
Pure
Substances,”
Elsevier
Scientific
Publishing
Co.,
New
York
(1973);
Perry’s
Chemical
Engineer’s
Handbook,
McGraw-Hill
Book
Company
(1984);
CRC
Handbook
of
Chemistry
and
Physics,
Chemical
Rubber
Publishing
Company
(1986-87);
and
Lange’s
Handbook
of
Chemistry,
John
A.
Dean,
editor,
McGraw-Hill Book Company (1985).
b)
If the organic material or solvent is in
a
mixture
made
up of both organic material compounds and compounds
which are not organic material, the vapor pressure
shall be determined by the following equation:
~om
=
n
SX.
i=1
1
where:
=
Total vapor pressure of the portion of the
mixture
which
is
composed
of
organic
material,
n
=
Number
of
organic
material
components
in
the
mixture,
i
=
Subscript denoting an individual
component,
P~
=
Vapor
pressure
of
an
organic
material
component determined in accordance with
Subpart
A
of
this
Part,
X1
=
Mole
fraction
of
the
organic
material
component
of
the
total
mixture.
c)
If the organic material or solvent is in a mixture made
up of only organic material compounds, the vapor
69
pressure shall be determined by ASTM Method D2879-86
(incorporated
by
reference
in
Section
219.112)
or
by
the above equation.
Section
219.111
Vapor
Pressure
of
Volatile
Organic
Material
a)
If
the
VON
consists
of
only
a
single
compound,
the
vapor
pressure
shall
be
determined
by
ASTN
Method
D2879-86 (incorporated by reference in Section 219.112)
or
the
vapor
pressure
may
be
obtained
from
a
published
source
such
as:
Boublik,
T.,
V.
Fried
and
E.
Hala,
“The Vapor Pressure of Pure Substances,” Elsevier
Scientific Publishing Co., New York
(1973); Perry’s
Chemical Engineer’s Handbook, McGraw-Hill Book Company
(1984);
CRC Handbook of Chemistry and Physics,
Chemical
Rubber Publishing Company (1986-87); and Lange’s
Handbook of Chemistry, John A. Dean,
editor,
McGraw-Hill Book Company (1985).
~b)
If the VON is in a mixture made up of both VON
compounds and compounds which are not VOM, the vapor
pressure shall be determined by the following equation:
=
i=1
n
EX~
i =1
where:
=
Total vapor pressure of the portion of the
mixture which is composed of VON,
n
=
Number
of
VON
components
in
the
mixture,
i
=
Subscript denoting an individual
component,
P~
=
Vapor pressure of a VON component
determined in accordance with Subpart A
of
this
Part,
X~
=
Mole fraction of the VON component of
the
total
mixture.
c)
If
the
VON
is
in
a
mixture
made
up
of
only
VOM
compounds,
the vapor pressure shall be determined by
ASTM Method D2879-86 (incorporated by reference in
Section
219.112)
or
by
the
above
equation.
70
Section
219.112
Incorporations
by
Reference
The following materials are incorporated by reference:
a)
American
Society
for
Testing
and
Materials,
1916
Race
Street,
Philadelphia,
PA
19103:
1)
ASTM
D2879—86
2)
ASTN
D323—82
3)
ASTM
D86—82
4)
ASTM
D—369—69
(1971)
5)
ASTM D—396—69
6)
ASTN
D2880—71
7)
ASTM
D—975—68
8)
ASTM
D3925—8l
(1985)
9)
ASTM
E300—86
10)
ASTM
D1475—85
11)
ASTM
D2369—87
12)
ASTN
D3792—86
13)
ASTN
D40l7—8l
(1987)
14)
ASTM D4457—85
15)
ASTM D2697—86
16)
ASTM
D3980—87
17)
ASTM E180—85
18)
ASTM
D2372—85
19)
ASTN
D97—66
20)
ASTN
E—l68
21)
ASTM
E—l69
22)
ASTM
E—260
23)
ASTM
D2504—83
24)
ASTM
D2382—83
b)
Standard Industrial Classification Manual, published by
Executive Office of the President, Office of Management
and Budget, Washington,
D.C.,
1987.
c)
American Petroleum Institute Bulletin 2517,
“Evaporation Loss From Floating Roof Tanks”, Second
ed.,
February,
1980.
d)
40
CFR
60
(July
1,
1990).
e)
40
CFR
61
(July
1,
1990)
f)
40 CFR 50 (July
1,
1989)
g)
40
CFR
51
(July
1,
1989).
h)
40 CFR 52
(July
1,
1989).
i)
United States Environmental Protection Agency,
71
Washington,
D.C.,
EPA—340/l—86—016.
j)
United States Environmental Protection Agency,
Washington
D.C.,
EPA-450/3-84-019.
k)
United
States
Environmental
Protection
Agency,
Washington D.C.,
EPA—340/1—88—003.
1)
United States Environmental Protection Agency,
Washington D.C., EPA—450/3—88-018.
m)
United States Environmental Protection Agency,
Washington,
D.C., EPA-450/2-78—029.
n)
United States Environmental Protection Agency,
Washington,
D.C., EPA—450/2—78—05l.
o)
United States Environmental Protection Agency,
Washington,
D.C., EPA-450/3—82—009.
SUBPART B:
ORGANIC EMISSIONS FROM STORAGE
AND
LOADING
OPERATIONS
Section
219.121
Storage Containers
No
person
shall
cause
or
allow
the
storage
of
any
VOL
with
a
vapor pressure of 17.24 kPa
(2.5 psia)
or greater at 294.3°K
(70°F)
or
any
gaseous
organic
material
in any stationary tank,
reservoir or other container of more than 151 cubic meters
(40,000 gal) capacity unless such tank,
reservoir or other
container:
a)
Is a pressure tank capable of withstanding the vapor
pressure of such liquid or the pressure of the gas,
so
as to prevent vapor or gas loss to the atmosphere at
all times;
or,
b)
Is
designed
and
equipped
with
one
of
the
following
vapor
loss
control
devices:
1)
A floating roof which rests on the surface of the
VOL
and
is
equipped
with
a
closure
seal
or
seals
between
the
roof
edge
and
the
tank
wall.
Such
floating
roof
shall
not
be
permitted
if
the
VOL
has
a
vapor
pressure
of
86.19
kPa
(12.5
psia)
or
greater
at
294.3~K (70°F).
No
person
shall
cause
or
allow
the
emission
of
air
contaminants
into
the
atmosphere
from
any
gauging
or
sampling
devices
attached to such tanks, except during sampling or
maintenance operations.
2)
A
vapor
recovery
system
consisting
of:
72
A)
A vapor gathering system capable of
collecting 85
or more of the uncontrolled
VOM
that
would
be
otherwise
emitted
to
the
atmosphere;
and,
B)
A vapor disposal system capable of processing
such VON so as to prevent its emission to the
atmosphere.
No
person
shall
cause
or
allow
the
emission
of
air
contaminants
into
the
atmosphere from any gauging or sampling
devices
attached
to
such
tank,
reservoir
or
other container except during sampling.
3)
Other
equipment
or
means
of
equal
efficiency
approved
by
the
Agency
according
to
the
provisions
of
35
Ill.
Adm.
Code
201,
and
further
processed
consistent with Section 219.108.
Section 219.122
Loading Operations
a)
No person shall cause or allow the discharge of more
than 3.6 kg/hr
(8 lbs/hr) of organic material into the
atmosphere during the loading of any organic material
~rom
the
aggregate
loading
pipes
of
any
loading
facility having through-put of greater than 151 cubic
meters per day (40,000 gal/day) into any railroad tank
car,
tank
truck
or
trailer
unless
such
loading
facility
is
equipped
with
submerged
loading
pipes,
submerged
fill or a device that is equally effective in
controlling emissions and is approved by the Agency
according to the provisions of 35 Ill. Adm. Code 201,
and
further
processed
consistent
with
Section
219.108.
b)
No
person
shall
cause
or
allow
the
loading
of
any
organic
material
into
any
stationary
tank
having
a
storage
capacity
of
greater
than
946
1
(250
gal),
unless such tank i~equipped with a permanent submerged
loading pipe, submerged fill or an equivalent device
approved by the Agency according to the provisions of
35 Ill.
Adm.
Code
201,
and
further
processed
consistent
with
Section
219.108,
or
unless
such
tank
is
a
pressure
tank
as
described
in
Section
219.121(a)
or
is
fitted
with
a
recovery
system
as
described
in
Section
219.121(b)
(2).
c)
Exception:
If
no
odor
nuisance
exists
the
limitations
of this Section shall only apply to the loading of VOL
with
a
vapor
pressure
of
17.24
kPa
(2.5
psia)
or
greater at 294.3’K (70°F).
Section 219.123
Petroleum Liquid Storage Tanks
73
a)
The requirements of subsection
(b)
shall not apply to
any
stationary
storage
tank:
1)
Equipped before January 1,
1979 with one of the
vapor loss control devices specified in Section
219.121(b), except Section 219.121(b) (1);
2)
With a capacity of less than 151.42 cubic meters
(40,000 gal);
3)
With
a
capacity
of
less
than
1,600
cubic
meters
(422,400 gal) and used to store produced crude oil
and condensate prior to custody transfer;
4)
With a capacity of less than 1,430 cubic meters
(378,000 gal)
and used to store produced oil or
condensate in crude oil gathering;
5)
Subject to new source performance standards for
storage vessels of petroleum liquid,
35 Ill. Adm.
Code 230;
6)
In which volatile petroleum liquid is not stored;
or
7)
Which is a pressure tank as described in Section
219.121(a).
b)
Subject to subsection
(a) no owner or operator of a
stationary storage tank shall cause or allow the
storage of any VOL in the tank unless:
1)
The tank is equipped with one of the vapor loss
control devices specified in Section 219.121(b);
2)
There are no visible holes, tears or other defects
in the seal or any seal fabric or material of any
floating roof;
3)
All openings of any floating roof deck, except
stub drains, are equipped with covers, lids or
seals
such
that:
A)
The cover, lid or seal is in the closed
position at all times except when petroleum
liquid is transferred to or from the tank;
B)
Automatic bleeder vents are closed at all
times except when the roof is floated off or
landed on the roof leg supports; and
C)
Rim vents,
if provided, are set to open when
74
the roof is being floated off the roof leg
supports or at the manufacturer’s recommended
setting;
4)
Routine inspections of floating roof seals are
conducted through roof hatches once every six
months;
5)
A complete inspection of the cover and seal of any
floating roof tank is made whenever the tank is
emptied for reasons other than the transfer of
petroleum liquid during the normal operation of
the tank,
or whenever repairs are made as a result
of any semi-annual inspection or incidence of roof
damage or defect; and
6)
A record of the results of each inspection
conducted under subsection
(b) (4) or
(b) (5)
is
maintained.
C)
Owners
and operators of petroleum liquid storage tanks
were
required
to
have
compliance
schedules
as
summarized in Appendix C,
to 35 Ill Adm. Code 215.
Section
219.124
External Floating Roofs
a)
In addition to meeting the requirements of Section
219.123(b), no owner or operator of a stationary
storage tank equipped with an external floating roof
shall cause or allow the storage of any volatile
petroleum liquid in the tank unless:
1)
The tank has been fitted with a continuous
secondary seal extending from the floating roof to
the tank wall
(rim mounted secondary seal)
or any
other device which controls VON emissions with an
effectiveness equal to or greater than a rim
mounted
secondary
seal;
2)
Each
seal
closure
device
meets
the
following
requirements:
A)
The seal
is intact and uniformly in place
around the circumference of the floating roof
between
the
floating
roof
and
tank
wall;
and
B)
The accumulated area of gaps exceeding 0.32
centimeter
(1/8 inch)
in width between the
secondary seal and the tank wall shall not
exceed 21.2 square centimeters per meter of
tank diameter (1.0 square inches per foot of
tank diameter).
75
3)
Emergency roof drains are provided with slotted
membrane fabric covers or equivalent covers across
at least 90 percent of the area of the opening;
4)
Openings are equipped with projections into the
tank which remain below the liquid surface at all
times;
5)
Inspections are conducted prior to May 1 of each
year to insure compliance with subsection
(a);
6)
The
secondary seal gap is measured prior to May 1
of each year;
7)
Records of the types of volatile petroleum liquid
stored,
the maximum true vapor pressure of the
liquid as stored, the results of the inspections
and the results of the secondary seal gap
measurements are maintained and available to the
Agency, upon verbal or written request, at any
reasonable time for a minimum of two years after
the date on which the record was made.
b)
Subsection
(a) does not apply to any stationary storage
tank equipped with an external floating roof:
1)
Exempted under Section 219.123(a) (2) through
219.123 (a) (6);
2)
Of welded construction equipped with a metallic
type shoe seal having a secondary seal from the
top of the shoe seal to the tank wall
(shoe-mounted secondary seal);
3)
Of welded construction equipped with a metallic
type shoe seal,
a liquid—mounted foam seal,
a
liquid-mounted liquid-filled-type seal,
or other
closure device of equivalent control efficiency
approved by the Agency in which a petroleum liquid
with a true vapor pressure less than 27.6 kPa
(4.0
psia)
at 294.3°K(70°F) is stored; or
4)
Used to store crude oil with a pour point of 50°F
or
higher
as
determined
by
ASTN
Standard
D97-66
incorporated by reference in Section 219.112.
Section 218.125
Compliance Dates
Every owner or operator of an emission source subject to 35 Ill.
Adm. Code 215, Subpart B as of December 31,
1987 shall have
complied with its standards and limitations by December 31,
1987.
76
Section
219.126
Compliance
Plan
a)
The owner or operator of an emission source previously
subject to Section 215.125 shall have submitted to the
Agency a compliance plan as required by 35 Ill. Adm.
Code 201.241,
including a project completion schedule
where applicable,
no later than April 21,
1983.
b)
Unless the submitted compliance plan or schedule was
disapproved by the Agency, the owner or operator of a
facility or emission source subject to the rules
specified in subsection
(a) may operate the emission
source according to the plan and schedule as submitted.
c)
The plan and schedule shall meet the requirements of 35
Ill. Adm. Code 201.241 including specific interim dates
as required in 35 Ill. Adm. Code 201.242.
SUBPART C:
ORGANIC EMISSIONS FROM MISCELLANEOUS EQUIPMENT
Section 219.141
Separation Operations
a)
No person shall use any single or multiple compartment
effluent water separator which receives effluent water
containing 757 1/day (200 gal/day) or more of organic
material from any equipment processing,
refining,
treating, storing or handling organic material unless
such effluent water separator is equipped with air
pollution control equipment capable of reducing by 85
percent or more the uncontrolled organic material
emitted to the atmosphere.
Exception:
If no odor
nuisance exists the limitations of this subsection
shall not apply if the vapor pressure of the organic
material is below 17.24 kPa (2.5 psia)
at 294.3°K
(70°F).
b)
Subsection
(a)
shall
not
apply
to
water
and
crude
oil
separation in the production of Illinois crude oil,
if
the
vapor
pressure
of
such
crude
oil
is
less
than
34.5
kPa
(5
psia).
Section 219.142
Pumps and Compressors
No
person
shall
cause
or
allow
the
discharge
of
more
than
32.8
ml
(2
cu
in)
of
VOL
with vapor pressure of 17.24 kPa
(2.5 psia)
or
greater at 294.3°K(70°F) into the atmosphere from any pump or
compressor in any 15 minute period at standard conditions.
Section 219.143
Vapor Blowdown
No person shall cause or allow the emission of organic material
77
into the atmosphere from any vapor blowdown system or any safety
relief valve,
except such safety relief valves not capable of
causing an excessive release, unless such emission is controlled:
a)
To 10 ppm equivalent methane
(molecular weight 16.0)
or
less;
or,
b)
By combustion in a smokeless flare;
or,
c)
By other air pollution control equipment approved by
the Agency according to the provisions of 35 Ill. Adm.
Code 201, and further processed consistent with Section
219.108.
Section 219.144
Safety Relief Valves
Section 219.143 shall not apply to any set of unregulated safety
relief valves capable of causing excessive releases, provided the
owner or operator thereof, by October
1,
1972, supplied the
Agency with the following:
a)
A historical record of each such set
(or,
if such
records were unavailable,
of similar sets which,
by
virtue of operation under similar circumstances, may
reasonably have been presumed to have the same or
greater frequency of excessive releases)
for a
three-year period immediately preceding October
1,
1972,
indicating:
1)
Dates on which excessive releases occurred from
each such set; and,
2)
Duration in minutes of each such excessive
-
release; and,
3)
Quantities
(in pounds) of mercaptans and/or
hydrogen sulfide emitted into the atmosphere
during each such excessive release.
b)
Proof, using such three-year historical records, that
no excessive release is likely to occur from any such
set either alone or in combination with such excessive
releases from other sets owned or operated by the same
person and located within a ten—mile radius from the
center point of any such set, more frequently than 3
times in any 12 month period;
c)
Accurate maintenance records pursuant to the
requirements of subsection
(a); and,
d)
Proof, at three-year intervals, using such three-year
historical records, that such set conforms to the
78
requirements of subsection
(c).
SUBPART E:
SOLVENT CLEANING
Section 219.181
Solvent Cleaning in General
The
requirements
of
this
Subpart
shall
apply
to
all
cold
cleaning, open top vapor degreasing, and conveyorized degreasing
operations.
Section 219.182
Cold Cleaning
a)
Operating Procedures:
No person shall operate a cold
cleaning degreaser unless:
1)
Waste solvent is stored in covered containers only
and not disposed of in such a manner that more
than
20
of
the
waste
solvent
(by
weight)
is
allowed
to
evaporate
into
the
atmosphere;
2)
The cover of the degreaser is closed when parts
are not being handled; and
3)
Parts are drained until dripping ceases.
b)
Equipment Requirements:
No person
shall
operate
a
cold
cleaning degreaser unless:
1)
The degreaser is equipped with a cover which is
closed whenever parts are not being handled in the
cleaner.
The cover shall be designed to be easily
operated with one hand or with the mechanical
assistance of springs, counter—weights or a
powered system if:
A)
The solvent vapor pressure is greater than 2
kPa
(15
ñunHg
or 0.3 psi) measured at 38°C
(100°F);
B)
The solvent is agitated; or
C)
The solvent is heated above ambient room
temperature.
2)
The degreaser is equipped with a facility for
draining cleaned parts.
The drainage facility
shall be constructed so that parts are enclosed
under the cover while draining unless:
A)
The solvent vapor pressure is less than 4.3
kPa
(32
mmHg
or 0.6 psi) measured at 38°C
(100°F);or
79
B)
An internal drainage facility cannot be
fitted into the cleaning system,
in which
case the drainage facility may be external.
3)
The degreaser is equipped with one of the
following control devices if the vapor pressure of
the solvent is greater than 4.3 kPa
(32
minflg
or
0.6 psi) measured at 38°C(100°F)or if the
solvent is heated above 50°C(120°F) or its
boiling point:
A)
A freeboard height of 7/10 of the inside
width of the tank or 91 cm
(36 in), whichever
is less; or
B)
Any other equipment or system of equivalent
emission control as approved by the Agency
and further processed consistent with Section
219.108.
Such a system may include a water
cover, refrigerated chiller or carbon
adsorber.
4)
A permanentpecat~ihgupnec~dhee~ama&fix~dgtththe
degreaser; and
5)
If a solvent spray is used,
the degreaser is
equipped with a solid fluid stream spray,
rather
than a fine,
atomized or shower spray.
Section 219.183
Open Top Vapor Degreasing
a)
Operating Requirements:
No person shall operate an
open top vapor degreaser unless:
1)
The cover of the degreaser is closed when
workloads are not being processed through the
degreaser;
2)
Solvent carryout emissions are minimized by:
A)
Racking parts to allow complete drainage;
B)
Moving parts in and out of the degreaser at
less than 3.3 m/min
(11 ft/mm);
C)
Holding the parts in the vapor zone until
condensation ceases;
D)
Tipping out any pools of solvent on the
cleaned parts before removal from the vapor
zone;
and,
80
E)
Allowing parts to dry within the degreaser
until
visually
dry.
3)
Porous or absorbent materials, such as cloth,
leather, wood or rope are not degreased;
4)
Less than half of the degreaser’s open top area is
occupied with a workload;
5)
The degreaser is not loaded to
the
point
where
the
vapor
level
would
drop
more
than
10
cm
(4
in)
when
the
workload
is
removed
from
the
vapor
zone;
6)
Spraying is done below the vapor level only;
7)
Solvent leaks are repaired immediately;
8)
Waste solvent is stored in covered containers only
and not disposed of in such a manner that more
than 20
of the waste solvent (by weight)
is
allowed to evaporate into the atmosphere;
9)
Water is not visually detectable in solvent
exiting from the water separator; and
10)
Exhaust ventilation exceeding 20 cubic meters per
minute per square meter
(65 cubic feet per minute
per square foot)
of degreaser open area is not
used, unless necessary to meet the requirements of
the Occupational Safety and Health Act
(29 U.S.C.
Section 651 et seq.).
b)
Equipment Requirements:
No person shall operate an
open top vapor degreaser unless:
1)
The degreaser is equipped with a cover designed to
open and close easily without disturbing the vapor
zone;
2)
The degreaser is equipped with the following
switches:
A)
A device which shuts off the sump heat source
if the amount of condenser coolant is not
sufficient to maintain the designed vapor
level; and
B)
A device which shuts of
f
the spray pump if
the vapor level drops more than 10 cm
(4
in)
below the bottom condenser coil; and
81
C)
A device which shuts off the sump heat source
when the vapor level exceeds the design
level.
3)
A permanent conspicuous label summarizing the
operating procedure is affixed to the degreaser;
4)
The
degreaser is equipped with one of the
following devices:
A)
A freeboard height of 3/4 of the inside width
of the degreaser tank or 91 cm
(36 in),
whichever is less; and if the degreaser
opening is greater than
1 square meter
(10.8
ft2),
a powered or mechanically assisted
cover; or
B)
Any other equipment or system of equivalent
emission control as approved by the Agency
and further processed consistent with Section
219.108.
Such equipment or system may
include a refrigerated chiller, an enclosed
design or a carbon adsorption system.
Section 219.184
Conveyorized Degreasing
a)
Operating Requirements:
No person shall operate a
conveyorized degreaser unless:
1)
Exhaust ventilation exceeding 20 cubic meters per
minute per square meter
(65 cubic feet per minute
per square foot)
of area of loading and unloading
opening is not used, unless necessary to meet the
requirements of the Occupational Safety and Health
Act
(29 U.S.C.
Section 651 et seq.).
2)
Solvent carryout emissions are minimized by:
A)
Racking parts for best drainage; and
B)
Maintaining the vertical conveyor speed at
less
than
3.3
m/min
(11
ft/mm);
3)
Waste
solvent
is stored in covered containers only
and not disposed of in such a manner that more
than 20
of the waste solvent
(by weight)
is
allowed to evaporate into the atmosphere;
4)
Solvent leaks are repaired immediately;
5)
Water is not visually detectable in solvent
exiting from the water separator; and
82
6)
Downtime covers are placed over entrances and
exits of conveyorized degreasers immediately after
the conveyors and exhausts are shut down and not
removed until just before start—up.
b)
Equipment Requirements:
No person shall operate a
conveyorized degreaser unless:
1)
The degreaser is equipped with a drying tunnel,
rotating (tumbling) basket or other equipment
sufficient to prevent cleaned parts from carrying
out solvent liquid or vapor;
2)
The degreaser is equipped with the following
switches:
A)
A device which shuts off the sump heat source
if the amount of condenser coolant is not
sufficient to maintain the designed vapor
level;
B)
A device which shuts off the spray pump or
the conveyor if the vapor level drops more
than 10 cm
(4
in)
below the bottom condenser
coil; and
C)
A device which shuts off the sump heat source
when the vapor level exceeds the design
level;
3)
The degreaser is equipped with openings for
entrances and exits that silhouette workloads so
that the average clearance between the parts and
the edge of the degreaser opening is less than 10
cm
(4
in) or less than 10 percent of the width of
the
opening;
4)
The degreaser is equipped with downtime covers for
closing off entrances and exits when the degreaser
is shut down; and
5)
The degreaser is equipped with one of the
following control devices,
if the air/vapor
interface is larger than 2.0 square meters
(21.6
ft2):
A)
A carbon adsorption system with ventilation
greater than or equal to 15 cubic meters per
minute per square meter
(50 cubic feet per
minute per square foot)
of air/vapor area
when downtime covers are open, and exhausting
83
less than 25 ppm of solvent by volume
averaged over a complete adsorption cycle; or
B)
Any other equipment or system of equivalent
emission control as approved by the Agency,
and further processed consistent with Section
219.108.
Such equipment or system may
include
a
refrigerated
chiller.
Section 219.185
Compliance Schedule
Every owner or operator of an emission source which was
previously exempt from the requirements of Subpart E of 35 Ill.
Adm. Code 215
(Sections 215.182—215.184) because it satisfied the
criteria
in
either
35
Ill.
Adm.
Code
215.181(a)
or
35
Ill.
Adm.
Code 215.181(b),
shall comply with the requirements of this
Subpart on and after a date consistent with Section 219.106.
A
source which did not satisfy the cri.~.’riain either 35 Ill.
Adm.
Code 215.181(a) or 35 Ill. Adm. Code 215.181(b)
shall comply with
the requirements of this Subpart upon adoption.
Section 219.186
Test Methods
The following test methods shall be used to demonstrate
compliance
with
this
Subpart:
a)
Vapor pressures shall be determined by using the
procedure specified in Section 219.110.
b)
Exhaust ventilation rates shall be determined by using
the procedures specified in Section 219.105(f) (3).
c)
The performance of control devices shall be determined
by using the procedures specified in Section
219.105(f).
SUBPART F:
COATING OPERATIONS
Section 219.204
Emission Limitations for Manufacturing Plants
Except as provided in Section 219.208, no owner or operator of a
coating line shall apply at any time any coating in which the VON
content exceeds the following emission limitations for the
specified coating.
The following emission limitations are
expressed in units of VON per volume of coating
(minus water and
any compounds which are specifically exempted from the definition
of VON)
as applied at each coating applicator, except where
noted.
Compounds which are specifically exempted from the
definition of VON should be treated as water for the purpose of
calculating the “less water” part of the coating composition.
Compliance with this Subpart must be demonstrated through the
84
applicable
coating
analysis
test
methods
and
procedures
specified
in
Section
219.105(a)
and
the
recordkeeping
and
reporting
requirements
specified
in
Section
219.211(c).
(Note:
The
equation presented in Section 219.206 shall be used to calculate
emission limitations for determining compliance by add-on
controls, credits for transfer efficiency, emissions trades and
cross—line averaging.)
The emission limitations are as follows:
a)
Automobile or Light-Duty
k~/l
lb/gal
Truck
Coating
1)
Prime
coat
0.14
(1.2)
2)
Prime surfacer coat
0.34
(2.8)
(Note:
The prime surfacer coat limitation is based
upon a transfer efficiency of 30 percent.
The use of
transfer
efficiency
credits
can
be
allowed
only
if
approved by the Agency and approved by the USEPA as a
SIP revision.
3)
Topcoat
1.81
(15.1)
~(Note: The topcoat limitation is in units of kg
(ibs)
of VON per 1
(gal)
of
coating
solids
deposited.
Compliance with the limitation shall be based on the
daily-weighted average VON content from the entire
topcoat operation
(all topcoat spray booths, flash-off
areas and bake ovens).
Compliance shall be
demonstrated in accordance with the topcoat protocol
for automobiles and light—duty trucks referenced in
Section 219.105(b).
Section 219.205 does not apply to
the topcoat limitation.)
At least 180 days prior to
the initial compliance date, the owner or operator of a
coating line subject to the topcoat limitation shall
have submitted to the USEPA a detailed proposal
specifying the method of demonstrating compliance with
the protocol.
The proposal shall have included,
at a
minimum,
a comprehensive plan (including a rationale)
for determining the transfer efficiency at each booth
through
the
use
of
in-plant,
or
pilot
testing;
the
selection of coatings to be tested (for the purpose of
determining transfer efficiency)
including the
rationale for coating groupings; and the method for
determining
the
analytic
VON
content
of
as
appliedcoatings
and
the
formulation
solvent
content
of
as applied coatings.
Upon approval of the protocol by
the USEPA,
the source may proceed with the
compliance
demonstration.
k~/1
lb/c~a1
85
4)
Final repair coat
b)
Can Coating
1)
Sheet basecoat and
overvarnish
2)
Exterior basecoat and
overvarnish
3)
Interior body spray coat
4)
Exterior end coat
5)
Side seam spray coat
6)
End sealing compound
c)
Paper Coating
0.35
(Note:
The paper coating limitation shall not apply to
any owner or operator of any paper coating line on
which printing is performed if the paper coating line
complies with the emissions limitations in Subpart
H:
Printing and Publishing, Sections 219.401 through
219.404.)
kg/l
lb/gal
d)
Coil Coating
0.31
(2.6)
e)
Fabric Coating
0.35
(2.9)
f)
Vinyl Coating
0.45
(3.8)
g)
Metal
Furniture
Coating
0.36
(3.0)
h)
Large Appliance Coating
0.34
(2.8)
(Note:
The limitation shall not apply to the use of
quick-drying lacquers for repair of scratches and nicks
that occur during assembly, provided that the volume of
coating does not exceed 0.95 1
(1 quart)
in any one
rolling eight—hour period.)
kg/i
lb/~al
1)
Magnet Wire Coating
0.20
(1.7)
j)
Miscellaneous Metal Parts and
0.58
kg!1
0.34
0.34
0.51
0.51
0.66
coato.44
(4.8)
lb/gal
(2.8)
(2.8)
(4.2)
(4.2)
(5.5)
(3.7)
lb/gal
(2.9)
k~/l
86
Products
Coating
1)
Clear coating
0.52
(4.3)
2)
Air-dried coating
0.42
(3.5)
3)
Extreme
performance
0.42
(3.5)
coating
4)
All other coatings
0.36
(3.0)
ka/l
lb/gal
k)
Heavy Off-Highway Vehicle
Products Coating
1)
Extreme performance
0.42
(3.5)
prime coat
2)
Extreme performance top-
0.42
(3.5)
coat
(air
dried)
3)
Final repair coat
0.42
(3.5)
(air dried)
4)
All other coatings are subject to the emission
limitations for miscellaneous metal parts and
products coatings in subsection
(j)
above.
k~/l
lb/gal
1)
Wood
Furniture
Coating
1)
Clear topcoat
0.67
(5.6)
2)
Opaque stain
0.56
(4.7)
3)
Pigmented coat
0.60
(5.0)
4)
Repair coat
0.67
(5.6)
5)
Sealer
0.67
(5.6)
6)
Semi-transparent stain
0.79
(6.6)
7)
Wash coat
0.73
(6.1)
(Note:
An owner or operator of a wood furniture
coating
operation
subject
to
this
Section
shall
apply
all
coatings,
with
the
exception
of
no
more
than
37.8
1
(10
gal)
of
coating
per
day
used
for touch-up and
repair operations,
using one or more of the following
87
application systems:
airless spray application system,
air—assisted airless spray application system,
electrostatic spray application system, electrostatic
bell or disc spray application system, heated airless
spray application system, roller coating, brush or wipe
coating application system, or dip coating application
system.)
Section
219.205
Daily-Weighted
Average
Limitations
No
owner
or operator of a coating line
subject
to
the
limitations
of
Section
219.204
and
complying
by
means
of
this
Section
shall
operate
the
subject coating line unless the owner or operator has
demonstrated compliance with subsection
(a),
(b),
(c),
(d),
(e)
or
(f)
(depending upon the source category) through the
applicable coating analysis test methods and procedures specified
in Section 219.105(a)
and the recordkeeping and reporting
requirements
specified
in
Section
219.211(d):
a)
No owner or operator of a coating line subject to only
one of the limitations from among Section
219.204(a) (1),
(a) (2),
(a) (4),
(c)
,
(d)
,
(e)
,
(f)
,
(g)
,
(h),
or
(1)
shall
apply
coatings
on
any
such
coating
line,
during
any
day, whose daily-weighted average VON
content
exceeds
the
emission limitation to which the
coatings are subject.
b)
No owner or operator of a miscellaneous metal parts and
products
coating
line
subject
to
the
limitations
of
Section
219.204(j)
shall apply coatings to
miscellaneous metal parts or products on the subject
coating line unless the requirements in subsection
(b) (1) or
(b) (2) below are met.
1)
For each coating line which applies multiple
coatings, all of which are subject to the same
numerical emission limitation within Section
219.204(j)
above, during the same day (e.g., all
coatings used on the line are subject to 0.42 kg/l
3.5
lbs/gal)), the daily—weighted average VON
content shall not exceed the coating VON content
limit corresponding to the category of coating
used,
or
2)
For each coating line which applies coatings from
more than one of the four coating categories in
Section 219.204(j)
above,
during the same day, the
owner or operator shall have a site—specific
proposal approved by the Agency and approved by
the USEPA as a SIP revision.
To receive approval,
the requirements of USEPA’s Emissions Trading
88
Policy Statement
(and related policy) must be
satisfied.
c)
No owner or operator of a can coating facility subject
to the limitations of Section 215.204(b)
shall operate
the subject coating facility using a coating with a VON
content
in
excess
of
the limitations specified in
Section 215.204(b)
unless all of the following
requirements
are
met:
1)
An alternative daily emission limitation shall be
determined according to subsection
(C)
(2) below.
Actual daily emissions shall never exceed the
alternative
daily
emission
limitation and shall be
calculated by use of the following equation.
n
E
=
E
V.C.
d
1=1
where:
=
Actual VON emissions for the day in
units of kg/day (lbs/day),
i
=
Subscript denoting a specific coating
applied,
n
=
Total number
of
coatings
applied
in
the
can
coating
operation,
V1
=
Volume of each
coating
applied
for
the
day in units of 1/day
(gal/day) of
coating (minus water and any compounds
which are specifically exempted from the
definition of VON),
and
C~
=
The VON content of each coating as
applied in units of kg VON/i
(lbs
VON/gal) of coating
(minus water and any
compounds which are specifically
exempted from the definition of VON).
2)
The alternative daily emission limitation
(Ad)
shall be determined on a daily basis as follows:
Ad=
.~
V~L~j.Q1-C~1
1—1
(D1
—
L.)
where:
89
Ad
=
The VON emissions allowed for the day in
units of kg/day (lbs/day),
i
=
Subscript denoting a specific coating
applied,
n
=
Total number of surface coatings applied
in the can coating operation,
C.
=
The VON content of each surface coating
as applied in units of kg VOM/1
(lbs
VON/gal)
of coating (minus water and any
compounds which are specifically
exempted from the definition of VON),
D1
=
The density of VON in each coating
applied.
For the purposes of
calculating Ad, the density
is
0.882 kg VOM/l VOM (7.36 lbs VON/gal
VOM),
V1
=
Volume of each surface coating applied
for the day in units of 1
(gal)
of
coating
(minus water and any compounds
which are specifically exempted from the
definition of VON),
L~
=
The VON emission limitation for each
surface coating applied as specified in
Section 219.204(b)
in units of kg VON/l
(lbs VON/gal)
of coating (minus water
and any compounds which are specifically
exempted from the definition of VON).
d)
No owner or operator of a heavy off—highway vehicle
products coating line subject to the limitations of
Section 219.204(k)
shall apply coatings to heavy
off-highway vehicle products on the subject coating
line unless the requirements of subsection
(d) (1) or
(d) (2) below are met.
1)
For each coating line which applies multiple
coatings, all of which are subject to the same
numerical emission limitation within Section
219.204(k)
above,
during the same day (e.g.,
all
coatings used on the line are subject to 0.42 kg/l
3.5
lbs/gal),
the daily-weighted average VON
content shall not exceed the coating VOM content
limit corresponding to the category of coating
used, or
2)
For each coating line which applies coatings
90
subject to more than one numerical emission
limitation
in
Section 219.204(k) above, during the
same day, the owner or operator shall have a site
specific proposal approved by the Agency and
approved by the USEPA as a SIP revision.
To
receive approval, the requirements of USEPA’s
Emissions Trading Policy Statement (and related
policy) must be satisfied.
e)
No owner or operator of a wood furniture coating line
subject to the limitations of Section 219.204(1) shall
apply coatings to wood furniture on the subject coating
line unless the requirements of subsection
(e) (1)
or
(e) (2),
in addition to the requirements specified in
the note to Section 219.204(1), are met.
1)
For each coating line which applies multiple
coatings, all of which are subject to the same
numerical emission limitation within Section
219.204(1)
above, during the same day (e.g.,
all
coatings used on the line are subject to 0.67 kg/i
5.6
lbs/gal)), the daily-weighted average VON
content shall not exceed the coating VON content
limit corresponding to the category of coating
used,
or
2)
For each coating line which applies coatings
subject to more than one numerical emission
limitation in Section 219.204(1)
above, during the
same day, the owner or operator shall have a site
specific proposal approved by the Agency and
approved by the USEPA as a SIP revision.
To
receive approval, the requirements of USEPA’s
Emissions Trading Policy Statement (and related
policy) must be satisfied.
Section 219.206
Solids Basis Calculation
Limitations in terms of kg
(Ibs)
of VON emissions per 1
(gal)
of
solids as applied at each coating applicator shall be determined
by the following equation:
S=
C
1
—
(C/D)
where:
S
=
The limitation on VON emissions in terms
of kg VOM/l
(lbs VON/gal) of solids,
C
=
The limitation on VON emissions in terms
of kg/l
(lbs/gal) of coating (minus
91
water and any compounds which are
specifically excluded from the
definition of VON) specified in Section
219.204,
D
=
The density of VON in the coating.
For
the purposes of calculating 5, the
density is 0.882 kg VON/i VON (7.36 lbs
VON/gal VON).
Section 219.207
Alternative Emission Limitations
a)
Any owner or operator of a coating line subject to
Section 219.204 may comply with this Section, rather
than with Section 219.204,
if a capture system and
control device are operated at all times and the owner
or operator demonstrates compliance with subsections
(c),
(d),
(e),
(f),
(g) or
(h)
(depending upon the
source category) through the applicable coating
analysis and capture system and control device
efficiency test methods and procedures specified in
Section 219.105 and the recordkeeping and reporting
requirements specified in Section 219.211(e); and the
control device
is equipped with the applicable
monitoring equipment specified in Section 219.105(d)
and the monitoring equipment is installed, calibrated,
operated and maintained according to vendor
specifications at all times the control device
is in
use.
A capture system and control device, which does
not demonstrate compliance with subsection
(c),
(d),
(e),
(f),
(g) or
(h) may be used as an alternative to
compliance with Section 219.204 only if the alternative
is approved by the Agency and approved by the USEPA as
a SIP revision.
b)
Alternative Add-On Control Methodologies
1)
The coating line is equipped with a capture system
and control device that provides 81 percent
reduction in the overall emissions of VON from the
coating line and the control device has a 90
percent efficiency,
or
2)
The system used to control VON from the coating
line is demonstrated to have an overall efficiency
sufficient to limit VON emissions to no more than
what is allowed under Section 219.204.
Use of any
control system other than an afterburner, carbon
adsorption,
condensation, or absorption scrubber
system can be allowed only if approved by the
Agency and approved by the USEPA as a SIP
revision.
The use of transfer efficiency credits
92
can be allowed only if approved by the Agency and
approved by the USEPA as a SIP revision.
Baseline
transfer efficiencies and transfer efficiency test
methods must be approved by the Agency and the
USEPA.
Such overall efficiency is to be determined as
follows:
A)
obtain the emission limitation from the
appropriate subsection in Section 219.204,
B)
calculate
“S’1 according to the equation in
Section 219.206,
3)
calculate the overall efficiency required
according to Section 219.105(e).
For the
purposes of calculating this value, according
to the equation in Section 219.105(e) (2),
VON1
is equal to the value of
“S”
as
determined above in subsection
(b) (2) (B).
c)
No owner or operator of a coating line subject to only
one of the emission limitations from among Section
219.204(a)(l),
(a)(2),
(a) (4),
(c),
(d),
(e)
,
(f),
(g),
(h) or
(i) and equipped with a capture system and
control device shall operate the subject coating line
unless the requirements in subsection
(b) (1)
or
(b) (2)
above are met.
No owner or operator of a coating line
subject to Section 219.204(a) (3) and equipped with a
capture system and control device shall operate the
coating line unless the owner or operator demonstrates
compliance with the topcoat limitation in accordance
with the topcoat protocol for automobile or light-duty
trucks referenced
in Section 219.105(b).
d)
No owner or operator of a miscellaneous metal parts and
products coating line which applies one or more
coatings during the same day, all of which are subject
to the same numerical emission limitation within
Section 219.204(j)
(e.g.,
all coatings used on the line
are subject to 0.42 kg/l
3.5
lbs/gal),
and which is
equipped with a capture system and control device shall
operate the subject coating line unless the
requirements in subsection
(b) (1) or
(b) (2)
above are
met.
e)
No owner or operator of a heavy off-highway vehicle
products coating line which applies one or more
coatings during the same day,
all of which are subject
to the same numerical emission limitation within
Section 219.204(k)
(e.g.,
all coatings used on the line
93
are subject to 0.42 kg/i (3.5 lbs/gal)),
and which is
equipped with a capture system and control device shall
operate the subject coating line unless the
requirements
in subsection
(b) (1) or
(b) (2)
above are
met.
f)
No owner or operator of a wood furniture coating line
which applies one or more coatings during the same day,
all of which are subject to the same numerical emission
limitation within Section 219.204(1)
(e.g., all
coatings used on the line are subject to 0.67 kg/l
5.6
lbs/gal)),
and which is equipped with a capture system
and control device shall operate the subject coating
line unless the requirements
in subsection
(b) (1) or
(b) (2)
are met.
If compliance is achieved by meeting
the requirements in subsection
(b) (2), then the
provisions in the note to Section 219.204(1) must also
be met.
g)
No owner or operator of
a can coating facility and
equipped with a capture system and control device shall
operate the subject coating facility unless the
requirements in subsection
(h) (1) or
(h) (2) below are
met.
1)
An alternative daily emission limitation shall be
determined according to Section 219.205(c) (2).
Actual daily emissions shall never exceed the
alternative daily emission limitation and shall be
calculated by use of the following equation:
Ed
=
E V1
C,
(1—F1)
where:
Ed
=
Actual VON emissions for the day in
units of kg/day
(lbs/day),
i
=
Subscript denoting the specific coating
applied,
n
=
Total number of surface coatings as
applied in the can coating operation,
V~
=
Volume of each coating as applied for
the day in units of 1/day
(gal/day) of
coating
(minus water and any compounds
which are specifically exempted from the
definition of VOM),
94
C~
=
The VON content of each coating as
applied in units of kg VON/l
(lbs
VON/gal) of coating (minus water and any
compounds which are specifically
exempted from the definition of VON),
and
F1
=
Fraction, by weight, of VON emissions
from the surface coating, reduced or
prevented from being emitted to the
ambient air. This is the overall
efficiency of the capture system and
control device.
2)
The coating line is equipped with a capture system
and control device that provide 75 percent
reduction in the overall emissions of VON from the
coating line and the control device has a 90
percent efficiency.
Section 219.208
Exemptions From Emission Limitations
a)
Exemptions for all source categories except wood
furniture coating.
The limitations of this Subpart
shall not apply to coating lines within a facility,
that otherwise would be subject to the same subsection
of Section 219.204
(because they belong to the same
source category, e.g. can coating), provided that
combined
actual emissions of VON from all lines at the
facility subject to that subsection never exceed
6.8
kg/day
(15 lbs/day) before the application of
capture systems and control devices.
(For example, can
coating lines within a plant would not be subject to
the limitations of Section 219.204(b)
if the combined
actual emissions of VON from the can coating lines
never exceed 6.8 kg/day
(15 lbs/day) before the
application of capture systems and control devices.)
Volatile organic material emissions from heavy
off-highway vehicle products coating lines must be
combined with VOM emissions from miscellaneous metal
parts and products coating lines to determine
applicability.
Any
owner or operator of
a coating
facility shall comply with the applicable coating
analysis test methods and procedures specified in
Section 219.105(a) and the recordkeeping and reporting
requirements specified in Section 219.211(a)
if total
VON emissions from the subject coating lines are always
less than or equal to 6.8 kg/day
(15 lbs/day) before
the application of capture systems and control devices
and, therefore, are not subject to the limitations of
Section 219.204.
Once a category of coating lines at a
facility is subject to the limitations in Section
95
219.204, the coating lines are always subject to the
limitations in Section 219.204.
b)
Applicability for wood furniture coating
1)
The limitations of this Subpart shall apply to a
plant’s wood furniture coating lines if the plant
contains process emission sources, not regulated
by Subparts
B,
E, F (excluding Section
219.204(1)), H (excluding Section 219.405),
Q,
R,
5,
V,
X,
Y,
or Z of this Part, which as a group
both:
A)
have maximum theoretical emissions of 91 Mg
(100 tons)
or more per calendar year of VOM
if no air pollution control equipment were
used, and
B)
are not limited to less than 91 Mg
(100 tons)
of VON per calendar year if no
air pollution
control equipment were used, through
production or capacity limitations contained
in a federally enforceable construction
permit or SIP revision.
2)
If a plant ceases to fulfill the criteria of
subsection (b)(1), the limitations of Section
219.204(1)
shall continue to apply to any wood
furniture coating line which was ever subject to
the limitations of Section 219.204(1).
3)
For the purposes of subsection
(b), an emission
source shall be considered regulated by a Subpart
if it is subject to the limitations of that
-
Subpart.
An emission source is not considered
regulated by
a Subpart if its emissions are below
the applicability cutoff level or if the source is
covered by an exemption.
4)
Any owner or operator of a wood furniture coating
line to which the limitations of this Subpart are
not applicable due to the criteria in subsection
(b)
shall, upon request by the Agency or the
USEPA,
submit records to the Agency and the USEPA
within 30 calendar days from the date of the
request that document that the coating line is
exempt from the limitations of this Subpart.
Section 219.209
Exemption From General Rule on Use of Organic
Material
No owner or operator of a coating line subject to the limitations
96
of Section 219.204
is required to meet the limitations of
Subpart G
(Section 219.301 or 219.302) of this Part,
after the
date by which the coating line is required to meet Section
219.204.
Section 219.210
Compliance Schedule
Every owner or operator of a coating line
(of a type included
within Section 219.204)
shall comply with the requirements of
Section 219.204, 219.207 or 219.208 and Section 219.211 in
accordance with the appropriate compliance schedule as specified
in subsection
(a),
(b),
(c) or
(d) below:
a)
No owner or operator of a coating line which is exempt
from the limitations of Section 219.204 because of the
criteria in Section 219.208(a)
shall operate said
coating line on or after a date consistent with Section
219.106, unless the owner or operator has complied
with,
and continues to comply with,
Section 219.211(b).
Wood furniture coating lines are not subject to Section
219.211(b).
b)
No owner or operator of a coating line complying by
means of Section 219.204 shall operate said coating
line on or after a date consistent with Section
219.106, unless the owner or operator has complied
with, and continues to comply with, Sections 219.204
and 219.211(c).
c)
No owner or operator of a coating line complying by
means of Section 219.205 shall operate said coating
line on or after
a date consistent with Section
219.106, unless the owner or operator has complied
with, and continues to comply with, Sections 219.205
and 219.211(d).
d)
No owner or operatpr of a coating line complying by
means of Section 219.207 shall operate said coating
line on or after a date consistent with Section
219.106, unless the owner or operator has complied
with, and continues to comply with, Sections 219.207
and 219.211(e).
Section 219.211
Recordkeeping and Reporting
a)
The VOM content of each coating and the efficiency of
each capture system and control device shall be
determined by the applicable test methods and
procedures specified in Section 219.105 to establish
the records required under this Section.
b)
Any owner or operator of a coating line which is
97
exempted from the limitations of Section 219.204
because of Section 219.208(a) shall comply with the
following:
1)
By a date consistent with Section 219.106, the
owner or operator of a facility referenced in this
subsection shall certify to the Agency that the
facility is exempt under the provisions of Section
219.208(a).
Such certification shall include:
A)
A declaration that the facility is exempt
from the limitations of Section 219.204
because of Section 219.208(a);
and
B)
Calculations which demonstrate that the
combined VON emissions from all coating lines
at the facility never exceed 6.8 kg
(15 lbs)
per day before the application of capture
systems and control devices.
The following
equation shall be used to calculate total VON
emissions:
In
n
T
=
E
(A.
B.).
e
isi
1=1
t
1
J
where:
Te
=
Total VON emissions from coating lines
at a facility each day before the
application of capture systems and
control devices in units of kg/day
(lbs/day),
m
=
Number of coating lines at the
facility,
j
=
Subscript denoting an individual
coating line,
n
=
Number of different coatings as
applied each day on each coating
line at the facility,
=
Subscript denoting an individual
coating,
A1
=
Weight of VON per volume of each coating
(minus water and any compounds which are
specifically exempted from the
definition of VON) as applied each day
on each coating line at the facility in
98
units of kg VON/i
(lbs VON/gal), and
B1
=
Volume
of each coating (minus water and
any compounds which are specifically
exempted from the definition of VON)
as
applied each day on each coating line at
the facility in units of 1/day
(gal/day).
The instrument or method by
which the owner or operator accurately
measured or calculated the volume of
each coating as applied on each coating
line each day shall be described in the
certification to the Agency.
2)
On and after a date consistent with Section
219.106, the owner or operator of a facility
referenced in this subsection shall collect and
record all of the following information each day
for each coating line and maintain the information
at the facility for a period of three years:
A)
The name and identification number of each
coating as applied on each coating line.
B)
The weight of VON per volume and the volume
of each coating (minus water and any
compounds which are specifically exempted
from the definition of VON)
as applied each
day on each coating line.
3)
On and after a date consistent with Section
219.106, the owner or operator of a facility
exempted from the limitations of Section 219.204
because of Section 219.208(a)
shall notify the
Agency of any record showing that total VON
emissions from the coating facility exceed 6.8 kg
(15 ibs)
in any day before the application of
capture systems and control devices by sending a
copy of such record to the Agency within 30 days
after the exceedance occurs.
c)
Any owner or operator of a coating line subject to the
limitations of Section 219.204 and complying by means
of Section 219.204 shall comply with the following:
1)
By a date consistent with Section 219.106, or upon
initial start—up of a new coating line, or upon
changing the method of compliance from an existing
subject coating line from Section 219.205 or
Section 219.207 to Section 219.204; the owner or
operator of a subject coating line shall certify
to the Agency that the coating line will be in
99
compliance with Section 219.204 on and after a
date consistent with Section 219.106, or on and
after the initial start-up date.
Such
certification shall include:
A)
The name and identification number of each
coating as applied on each coating line.
B)
The weight of VON per volume of each coating
(minus water and any compounds which are
specifically exempted from the definition of
VON)
as applied each day on each coating
line.
C)
For coating lines subject to Section
219.204(a) (3), certification shall include:
i)
The name and identification number of
each coating line which will comply by
means of Section 219.204(a) (3),
ii)
The name and identification number of
each coating as applied on each coating
line,
iii) The weight of VON per volume of each
coating as applied on each coating line,
iv)
The instrument or method by which the
owner or operator will accurately
measure or calculate the volume of each
coating as applied each day on each
coating line,
v)
The method by which the owner or
operator will create and maintain
records each day as required in
subsection
(c) (2) below for coating
lines subject to Section 219.204(a) (3),
vi)
An example format in which the records
required in subsection
(c) (2) below for
coating lines subject to Section
219.204 (a) (3).
2)
On and after a date consistent with Section
219.106, or on and after the initial start—up
date,
the owner or operator of a coating line
subject to the limitations of Section 219.204 and
complying by means of Section 219.204 shall
collect and record all of the following
information each day for each coating line and
100
maintain the information at the facility for a
period of three years:
A)
The name and identification number of each
coating as applied on each coating line.
B)
The weight of VON per volume of each coating
(minus water and any compounds which are
specifically exempted from the definition of
VON)
as applied each day on each coating
line.
C)
For coating lines subject to Section
219.204(a) (3), the owner or operator shall
maintain all records necessary to calculate
the daily-weighted average VON content from
the coating line in accordance with the
proposal submitted, and approved by the
USEPA, pursuant to Section 219.204(a) (3).
3)
On and after a date consistent with Section
219.106, the owner or operator of a subject
coating line shall notify the Agency in the
following instances:
A)
Any record showing violation of Section
219.204 shall be reported by sending a copy
of such record to the Agency within 30 days
following the occurrence of the violation,
except that any record showing a violation of
Section 219.204(a) (3)
shall be reported by
sending a copy of such record to the Agency
within 15 days from the end of the month in
which the violation occurred.
B)
At least 30 calendar days before changing the
method of compliance with Section 219.204
from Section 219.204 to Section 219.205 or
Section 219.207, the owner or operator shall
comply with all requirements of subsection
(d) (1) or
(e) (1) below,
respectively.
Upon
changing the method of compliance with
Section 219.204 from Section 219.204 to
Section 219.205 or Section 219.207, the owner
or operator shall comply with all
requirements of subsection
(d) or
(e),
respectively.
C)
For coating lines subject to Section
219.204(a) (3), the owner or operator shall
notify the Agency of any change to the
topcoating operation at least 30 days before
101
the change is effected.
The Agency shall
determine whether or not recertification
testing is required.
If the Agency
determines that recertification testing is
required, then the owner or operator shall
submit
a
proposal to the Agency to test
within 30 days and retest within 30 days of
the Agency’s approval of the proposal.
d)
Any owner or operator of a coating line subject to the
limitations of Section 219.204 and complying by means
of Section 219.205 shall comply with the following:
1)
By a date consistent with Section 219.106, or upon
initial start—up of a new coating line, or upon
changing the method of compliance for an existing
subject coating line from Section 219.204 or
Section 219.207 to Section 219.205; the owner or
operator of the subject coating line shall certify
to the Agency that the coating line will be in
compliance with Section 219.205 on and after a
date consistent with Section 219.106,
or on and
after the initial start-up date.
Such
certification shall
include:
A)
The name and identification number of each
coating line which will comply by means of
Section 219.205.
B)
The name and identification number of each
coating as applied on each coating line.
C)
The weight of VOM per volume and the volume
of each coating (minus water and any
compounds which are specifically exempted
from the definition of VON)
as applied each
day on each coating line.
D)
The instrument or method by which the owner
or operator will accurately measure or
calculate the volume of each coating as
applied each day on each coating line.
E)
The method by which the owner or operator
will create and maintain records each day as
required in subsection
(d) (2).
F)
An example of the format in which the records
required in subsection
(d) (2) will be kept.
2)
On and after a date consistent with Section
219.106, or on and after the initial start-up
102
date, the owner or operator of a coating line
subject to the limitations of Section 219.204 and
complying by means of Section 219.205,
shall
collect and record all of the following
information each day for each coating line and
maintain the information at the facility for a
period of three years:
A)
The name and identification number of each
coating as applied on each coating line.
B)
The weight of VON per volume and the volume
of each coating (minus water and any
compounds which are specifically exempted
from the definition of VON) as applied each
day on each coating line.
C)
The daily-weighted average VON content of all
coatings as applied on each coating line as
defined in Section 219.104.
3)
On and after a date consistent with Section
219.106, the owner or operator of a subject
coating line shall notify the Agency in the
following instances:
A)
Any record showing violation of Section
219.205 shall be reported by sending a copy
of such record to the Agency within 30 days
following the occurrence of the violation.
B)
At least 30 calendar days before changing the
method of compliance with this subpart from
Section 219.205 to Section 219.204 or Section
219.207, the owner or operator shall comply
with all requirements of subsection
(c) (1) or
(e)(l), respectively.
Upon changing the
method of compliance with this subpart from
Section 219.205 to Section 219.204 or Section
219.207, the ~
o~mply
subsection
(c) or
(e),
respectively.
e)
Any owner or operator of a coating line subject to the
limitations of Section 219.207 and complying by means
of Section 219.207(c),
(d),
(e),
(f),
(g) or
(h)
shall
comply with the following:
1)
By a date consistent with Section 219.106, or upon
initial start—up of a new coating line, or upon
changing the method of compliance for an existing
coating line from Section 219.204 or Section
103
219.205 to Section 219.207, the owner or operator
of the subject coating line shall perform all
tests and submit to the Agency the results of all
tests and calculations necessary to demonstrate
that the subject coating line will be in
compliance with Section 219.207 on and after
a
date consistent with Section 219.106, or on and
after the initial start-up date.
2)
On and after a date consistent with Section
219.106, or on and after the initial start-up
date, the owner or operator of a coating line
subject to the limitations of Section 219.207 and
complying by means of Section 219.207(c),
(d),
(e),
(f),
(g), or
(h) shall collect and record all
of the following information each day for each
coating line and maintain the information at the
facility for a period of three years:
A)
The weight of VON per volume of coating
solids as applied each day on each coating
line,
if complying pursuant to Section
219.207(b) (2).
B)
Control device monitoring data.
C)
A log of operating time for the capture
system, control device, monitoring equipment
and the associated coating line.
D)
A maintenance log for the capture system,
control device and monitoring equipment
detailing all routine and non—routine
maintenance performed including dates and
duration of any outages.
3)
On and after
a date consistent with Section
219.106, the owner or operator of a subject
coating line shall notify the Agency in the
following instances:
A)
Any record showing violation of Section
219.207 shall be reported by sending a copy
of such record to the Agency within 30 days
following the occurrence of the violation.
B)
At least 30 calendar days before changing the
method of compliance with this Subpart from
Section 219.207 to Section 219.204 or Section
219.205, the owner or operator shall comply
with all requirements of subsection
(c) (1) or
(d) (1)
of this Section,
respectively.
Upon
104
changing the method of compliance with this
subpart from Section 219.207 to Section
219.204 or Section 219.205, the owner or
operator shall comply with all requirements
of subsection
(c) or
(d)
of this Section,
respectively.
SUBPART G:
USE OF ORGANIC MATERIAL
Section 219.301
Use of Organic Material
No person shall cause or allow the discharge of more than 3.6
kg/hr
(8 lbs/hr)
of organic material into the atmosphere from any
emission source, except as provided in Sections 219.302,
219.303,
219.304 and the following exception:
If no odor nuisance exists
the limitation of this Subpart shall apply only to
photochemically reactive material.
Section 219.302
Alternative Standard
Emissions of organic material in excess of those permitted by
Section 219.301 are allowable if such emissions are controlled by
one of the following methods:
a)
Flame, thermal or catalytic incineration
so
as either
to reduce such emissions to 10 ppm equivalent methane
(molecular weight 16) or less, or to convert 85 percent
of the hydrocarbons to carbon dioxide and water;
or,
b)
A vapor recovery system which adsorbs and/or condenses
at least 85 percent of the total uncontrolled organic
material that would otherwise be emitted to the
atmosphere;
or,
c)
Any other air pollution control equipment approved by
the Agency and approved by the USEPA as a -SIP revision
capable of reducing by 85 percent or more the
uncontrolled organic material that would be otherwise
emitted to the atmosphere.
Section 219.303
Fuel Combustion Emission Sources
The provisions of Sections 219.301 and 219.302 shall not apply to
fuel combustion emission sources.
Section 219.304
Operations with Compliance Program
The provisions of Sections 219.301 and 219.302 shall not apply to
any owner,
operator, user or manufacturer of paint, varnish,
lacquer, coatings or printing ink whose compliance program and
project completion schedule, as required by 35 Ill.
Adm.
Code
201, provided for the reduction of organic material used in such
105
process to 20 percent or less of total volume by May 30,
1977.
SUBPART H:
PRINTING
AND
PUBLISHING
Section 219.401
Flexographic and Rotogravure Printing
a)
No owner or operator of a subject flexographic,
packaging rotogravure or publication rotogravure
printing line shall apply at any time any coating or
ink unless the VON content does not exceed the
limitation specified in either subsection
(a) (1) or
(a) (2)
below.
Compliance with this Section must be
demonstrated through the applicable coating or ink
analysis test methods and procedures specified in
Section 219.105(a)
and the recordkeeping and reporting
requirements specified in Section 219.404(c).
As an
alternative to compliance with this subsection,
a
subject printing line may meet the requirements of
subsection
(b) or
(c) below.
1)
Forty percent VON by volume of the coating and ink
(minus water and any compounds which are
specifically exempted from the definition of VON),
or
2)
Twenty-five percent VON by volume of the volatile
content in the coating and ink.
b)
No owner or operator of a subject flexographic,
packaging rotogravure or publication rotogravure
printing line shall apply coatings or inks on the
subject printing line unless the weighted average, by
volume, VON content of all coatings and inks as applied
each day on the subject printing line does not exceed
the limitation specified in either subsection
(a) (1)
(as determined by subsection
(b) (1)) or subsection
(a) (2)
(as determined by subsection
(b) (2)).
Compliance with this subsection must be demonstrated
through the applicable coating or ink analysis test
methods and procedures specified in Section 219.105 (a)
and the recordkeeping and reporting requirements
specified in Section 219.404(d).
1)
The following equation shall be used to determine
if the weighted average VOM content of all
coatings and inks as applied each day on the
subject pr~p~dà~iHnine~ubedstths
~i~4t~tion
C1L1 (V~~
+
VOM(i)(A)
=
_____________________________
106
L~(V~1
+
V~~)
Where:
VOM(i)CA)
=
The weighted average VON content in
units of percent VON by volume of all
coatings and inks
(minus water and any
compounds which are specifically
exempted from the definition of VON)
used each day,
i
=
Subscript denoting a specific
coating or ink as applied,
n
=
The number of different coatings
and/or inks as applied each day on
a printing line,
=
The VON content in units of percent
VON by volume of each coating or
ink as applied
(minus water and any
compounds which are specifically
exempted from the definition of
VON),
=
The liquid volume of each coating
or ink as applied in units of 1
(gal),
~
=
The volume fraction of solids in
each coating or ink as applied,
and
Vv~1
=
The volume fraction of VON in each
coating or ink as applied.
2)
The following equation shall be used to determine
if the weighted average VON content of all
coatings and inks as applied each day on the
subject printing line exceeds the limitation
specified in subsection
(a) (2).
i=1
~
C~L1V~1
VOM(1)(8)
=
•9~
LIVVffl
where:
107
VOM(I)(B)
=
The weighted average VON content in
units of percent VOM by volume of the
volatile content of all coatings and
inks used each day,
i
=
Subscript denoting a specific
coating or ink as applied,
The number of different coatings
and/or inks as applied each day on
each printing line,
C1
=
The VON content in units of percent
VON by volume of the volatile
matter in each coating or ink as
applied,
L1
=
The liquid volume of each coating
or ink as applied in units of
1
(gal),
and
~
=The volume fraction of volatile matter
in each coating or ink as applied.
c)
No owner or operator of a subject flexographic,
packaging rotogravure or publication rotogravure
printing line equipped with a capture system and
control device shall operate the subject printing line
unless the owner or operator meets the requirements in
subsection
(c) (1),
(c) (2), or
(c) (3) and subsections
(c) (4),
(c) (5) and
(c) (6)
below.
1)
A carbon adsorption system is used which reduces
the captured VON emissions by at least 90 percent
by weight, or
2)
An incineration system is used which reduces the
captured VON emissions by at least 90 percent by
weight, or
3)
An alternative VON emission reduction system is
used which is demonstrated to have at least a
90 percent control device efficiency,
approved by
the Agency and approved by USEPA as a SIP
revision, and
4)
The printing line is equipped with a capture
system and control device that provides an overall
reduction in VON emissions of at least:
A)
75 percent where a publication rotogravure
printing line is employed, or
108
B)
65 percent where a packaging rotogravure
printing line is employed,
or
C)
60 percent where a flexographic printing line
is employed, and
5)
The control device is equipped with the applicable
monitoring equipment specified in Section
219.105(d) (2) and the monitoring equipment is
installed,
calibrated, operated and maintained
according to vendor specifications at all times
the control device is in use, and
6)
The capture system and control device are operated
at all times when the subject printing line is in
operation.
The owner or operator shall
demonstrate compliance with this subsection by
using the applicable capture system and control
device test methods and procedures specified in
Section 219.105(c) through Section 219.105(f) and
by complying with the recordkeeping and reporting
requirements specified in Section 219.404(e).
Section 219.402
Applicability
a)
The limitations of Section 219.401 apply to all
flexographic and rotogravure printing lines at a
subject facility.
All facilities with flexographic
and/or rotogravure printing lines are subject
facilities unless:
1)
Total maximum theoretical emissions of VON from
all flexographic and rotogravure printing line(s)
at the facility never exceed 90.7 Mg (100 tons)
per calendar year before the application of
capture systems and control devices, or
2)
A federally enforceable construction permit or SIP
revision for all flexographic and rotogravure
printing line(s) at a facility requires the owner
or operator to limit production or capacity of
these printing line(s)
to reduce total VON
emissions from all flexographic and rotogravure
printing line(s) to 90.7 Mg (100 tons)
or less per
calendar year before the application of capture
systems and control devices.
b)
Upon achieving compliance with this Subpart, the
emission source is not required to meet Subpart G
(Sections 219.301 or 219.302).
Emission sources exempt
from this Subpart are subject to Subpart G (Sections
109
219.301 or 215.802).
Rotogravure or flexographic
equipment used for both roll printing and paper coating
is subject to this Subpart.
c)
Once subject to the limitations of Section 219.401,
a
flexographic or rotogravure printing line is always
subject to the limitations of Section 219.401.
d)
Any
owner or operator of any flexographic or
rotogravure printing line that is exempt from the
limitations of Section 219.401 because of the criteria
in this Section is subject to the recordkeeping and
reporting requirements specified in Section 219.404(b).
Section 219.403
Compliance Schedule
Every owner or operator of a flexographic and/or rotogravure
printing line shall comply with the applicable requirements of
Section 219.401 and Section 219.404 in accordance with the
applicable compliance schedule specified in subsection
(a),
(b),
(c) or
(d)
below:
a)
No owner or operator of a flexographic or rotogravure
printing line which is exempt from the limitations of
Section 219.401 because of the criteria in Section
219.402 shall operate said printing line on or after
a
date consistent with Section 219.106, unless the owner
or operator has complied with, and continues to comply
with, Section 219.404(b).
b)
No owner or operator of a flexographic or rotogravure
printing line complying by means of Section 219.401(a)
shall operate said printing line on or after a date
consistent with Section 219.106, unless the owner or
operator has complied with,
and continues to comply
with,
Section 219.401(a)
and Section 219.404(c).
c)
No owner or operator of a flexographic or rotogravure
printing line complying by means of Section 219.401(b)
shall operate said printing line on or after a date
consistent with Section 219.106, unless the owner or
operator has complied with, and continues to comply
with, Section 219.401(b)
and Section 219.404(d).
d)
No owner or operator of a flexographic or rotogravure
printing line complying by means of Section 219.401(c)
shall operate said printing line on or after a date
consistent with Section 219.106, unless the owner or
operator has complied with,
and continues to comply
with, Section 219.401(c) and Section 219.404(e).
Section 219.404
Recordkeeping and Reporting
110
a)
The VON content of each coating and ink and the
efficiency of each capture system and control device
shall be determined by the applicable test methods and
procedures specified in Section 219.105 to establish
the records required under this Section.
b)
Any owner or operator of a printing line which is
exempted from the limitations of Section 219.401
because of the criteria in Section 219.402 shall comply
with the following:
1)
By a date consistent with Section 219.106, the
owner or operator of a facility to which this
subsection is applicable shall certify to the
Agency that the facility is exempt under the
provisions of Section 219.402.
Such certification
shall include:
A)
A declaration that the facility is exempt
from the limitations of the criteria in
Section 219.401 because of Section 219.402,
and
B)
Calculations which demonstrate that total
maximum theoretical emissions of VON from all
flexographic and rotogravure printing lines
at the facility never exceed 90.7 Mg
(100 tons)
per calendar year before the
application of capture systems and control
devices.
Total maximum theoretical emissions
of VOM for a flexographic or rotogravure
printing facility is the sum of maximum
theoretical emissions of VON from each
flexographic and rotogravure printing line at
the facility.
The following equation shall
be used to calculate total maximum
theoretical emissions of VON per calendar
year before the application of capture
systems and control devices for each
flexographic and rotogravure printing line at
the facility:
E~
=
A
x B
where:
E~
=
Total maximum theoretical emissions of
VON from one flexographic or rotogravure
printing line in units of kg/year
(lbs/year),
111
A
=
Weight of VON per volume of solids of
the coating or ink with the highest VON
content as applied each year on the
printing line in units of kg VON/i
(lbs
VOM/gal) of coating or ink solids,
and
B
=
Total volume of solids for all coatings
and inks that can potentially be applied
each year on the printing line in units
of 1/year (gal/year).
The instrument
and/or method by which the owner or
operator accurately measured or
calculated the volume of each coating
and ink as applied and the amount that
can potentially be applied each year on
the printing line shall be described in
the certification to the Agency.
2)
On and after a date consistent with Section
219.106,
the owner or operator of a facility
referenced in this subsection shall collect and
record all of the following information each year
for each printing line and maintain the
information at the facility for a period of three
years:
A)
The name and identification number of each
coating and ink as applied on each printing
line.
B)
The VON content and the volume of each
coating and ink as applied each year on each
printing line.
3)
On and after a date consistent with Section
219.106, the owner or operator of a facility
exempted from the limitations of Section 219.401
because of the criteria in Section 219.402
shall
notify the Agency of any record showing that total
maximum theoretical emissions of VOM from all
printing lines exceed 90.7 Mg (100 tons)
in any
calendar year before the application of capture
systems and control devices by sending a copy of
such record to the Agency within 30 days after the
exceedance occurs.
c)
Any owner or operator of a printing line subject to the
limitations of Section 219.401 and complying by means
of Section 219.401(a)
shall comply with the following:
1)
By a date consistent with Section 219.106,
or upon
112
initial start-up of a new printing line, or upon
changing the method of compliance from an existing
subject printing line from Section 219.401(b) or
Section 219.401(c)
to Section 219.401(a), the
owner or operator of a subject printing line shall
certify to the Agency that the printing line will
be in compliance with Section 219.401(a)
on and
after a date consistent with Section 219.106, or
on and after the initial start-up date.
Such
certification shall include:
A)
The name and identification number of each
coating and
ink
as applied on each printing
line.
B)
The VOM content of each coating and ink as
applied each day on each printing line.
2)
On and after a date consistent with Section
219.106, or on and after the initial start-up
date, the owner or operator of a printing line
subject to the limitations of Section 219.401 and
complying by means of Section 219.401(a)
shall
collect and record all of the following
information each day for each coating line and
maintain the information at the facility for a
period of three years:
A)
The name and identification number of each
coating and ink as applied on each printing
line.
B)
The VON content of each coating and ink as
applied each day on each printing line.
3)
On
and after a date consistent with Section
219.106, the owner or operator of a subject
printing line shall notify the Agency in the
following instances:
A)
Any record showing violation of Section
219.401(a)
shall be reported by sending a
copy of such record to the Agency within 30
days following the occurrence of the
violation.
B)
At least 30 calendar days before changing the
method of compliance with Section 219.401
from Section 219.401(a)
to Section 219.401(b)
or
(c), the owner or operator shall comply
with all requirements of subsection
(b) (1) or
(c) (1), respectively.
Upon changing the
113
method of compliance with Section 219.401
from Section 219.401(a) to Section 219.401(b)
or
(c), the owner or operator shall comply
with all requirements of subsection
(b) or
(c), respectively.
d)
Any
owner or operator of a printing line subject to the
limitations of Section 219.401 and complying by means
of Section 219.401(b) shall comply with the following:
1)
By a date consistent with Section 219.106,
or upon
initial start-up of a new printing line,
or upon
changing the method of compliance for an existing
subject printing line from Section 219.401(a)
or
(c) to Section 219.401(b), the owner or operator
of the subject printing line shall certify to the
Agency that the printing line will be in
compliance with Section 219.401(b)
on and after
a
date consistent with Section 219.106, or on and
after the initial start-up date.
Such
certification shall include:
A)
The name and identification number of each
printing line which will comply by means of
Section 219.401(b).
B)
The name and identification number of each
coating and ink available for use on each
printing line.
C)
The VON content of each coating and ink as
applied each day on each printing line.
D)
The instrument or method by which the owner
or operator will accurately measure or
calculate the volume of each coating and ink
as applied each day on each printing line.
E)
The method by which the owner or operator
will create and maintain records each day as
required in subsection
(b) (2).
F)
An example of the format in which the records
required in subsection
(b) (2) will be kept.
2)
On and after
a date consistent with Section
219.106, or on and after the initial start—up
date, the owner or operator of a printing line
subject to the limitations of Section 219.401 and
complying by means of Section 219.401(b)
shall
collect and record all of the following
information each day for each printing line and
114
maintain the information at the facility for a
period of three years:
A)
The name and identification
number
of each
coating and ink as applied on each printing
line.
B)
The VON content and the volume of each
coating and ink as applied each day on each
printing line.
C)
The daily-weighted average VON content of all
coatings and inks as applied on each printing
line.
3)
On and after a date consistent with Section
219.106, the owner or operator of a subject
printing line shall notify the Agency in the
following instances:
A)
Any record showing violation of Section
219.401(b)
shall be reported by sending a
copy of such record to the Agency within 30
days following the occurrence of the
violation.
B)
At least 30 calendar days before changing the
method of compliance with Section 219.401
from Section 219.401(b) to Section 219.401(a)
or 219.401(c),
the owner or operator shall
comply with all requirements of subsection
(c) (1) or
(e) (1), respectively.
Upon
changing the method of compliance with
Section 219.401 from Section 219.401(b)
to
Section 219.401(a)
or
(c), the owner or
operator shall comply with all requirements
of subsection
(c)
or
(e), respectively.
e)
Any owner or operator of a printing line subject to the
limitations of Section 219.401 and complying by means
of Section 219.401(c)
shall comply with the following:
1)
By a date consistent with Section 219.106, or upon
initial start-up of a new printing line, or upon
changing the method of compliance for an existing
printing line from Section 219.401(a)
or
(b) to
Section 219.401(c),
the owner or operator of the
subject printing line shall perform all tests and
submit to the Agency the results of all tests and
calculations necessary to demonstrate that the
subject printing line will be in compliance with
Section 219.401(c)
on and after a date consistent
115
with Section 219.106, or on and after the initial
start-up date.
2)
On and after a date consistent with Section
219.106, or on and after the initial start-up
date, the owner or operator of a printing line
subject to the limitations of Section 219.401 and
complying by means of Section 219.401(c)
shall
collect and record all of the following
information each day for each printing line and
maintain the information at the facility for a
period of three years:
A)
Control device monitoring data.
B)
A log of operating time for the capture
system,
control device, monitoring equipment
and the associated printing line.
C)
A maintenance log for the capture system,
control device and monitoring equipment
detailing all routine and non-routine
maintenance performed including dates and
duration of any outages.
3)
On and after a date consistent with Section
219.106, the owner or operator of a subject
printing line shall notify the Agency in the
following instances:
A)
Any record showing violation of Section
219.401(c),
shall be reported by sending a
copy of such record to the Agency within 30
days following the occurrence of the
violation.
B)
At least 30 calendar days before changing the
method of compliance with Section 219.401
from Section 219.401(c)
to Section 219.401(a)
or
(b), the owner or operator shall comply
with all requirements of subsection
(c) (1)
or
(d) (1), respectively.
Upon changing the
method of compliance with Section 219.401
from Section 219.401(c)
to Section 219.401(a)
or
(b), the owner or operator shall comply
with all requirements of subsection
(C)
or
(d), respectively.
Section 219.405
Heatset-Web-Offset Lithographic Printing
a)
Applicability
116
1)
The limitations of subsection
(b) below apply to
all heatset-web-offset lithographic printing lines
at a subject facility.
All facilities with
heatset-web-offset lithographic printing lines are
subject facilities unless:
A)
Total maximum theoretical emissions of VON
from all heatset-web-offset lithographic
printing lines at the facility never exceed
90.7 Mg (100 tons) per calendar year in the
absence of air pollution control equipment,
or
B)
A federally enforceable construction permit
or SIP revision for all heatset-web-offset
lithographic printing lines(s)
at a facility
requires the owner or operator to limit
production or capacity of these printing
line(s) to reduce total VON emissions from
all heatset—web-offset lithographic printing
line(s) to 90.7 Mg
(100 tons) per calendar
year or less in the absence of air pollution
control equipment,
and
2)
Any owner or operator of any heatset—web-offset
lithographic printing line that is exempt from the
limitations in subsection
(b) because of the
criteria in subsection
(a) (1)
shall be subject to
the recordkeeping and reporting requirements in
subsection
(c) (1).
b)
Specific Provisions.
No owner or operator of a subject
heatset-web— offset printing line may cause or allow
the operation of the subject heatset-web-offset
printing line unless the owner or operator meets the
requirements in subsection
(b) (1)
or
(b) (2) and the
requirements in subsections
(b) (3) and
(b) (4)
below.
1)
An afterburner system is installed and operated
that reduces 90 percent of the VON emissions from
the dryer exhaust, or
2)
The fountain solution contains no more than
8 percent, by weight, of VON and a condensation
recovery system is installed and operated that
removes at least 75 percent of the non—isopropyl
alcohol organic materials from the dryer exhaust,
and
3)
The control device is equipped with the applicable
monitoring equipment specified in Section
219.105(d) (2) and the monitoring equipment is
117
installed,
calibrated, operated and maintained
according to vendor specifications at all times
the control device is in use, and
4)
The control device is operated at all times when
the subject printing line is in operation.
The
owner or operator shall demonstrate compliance
with this Section by using the applicable test
methods and procedures specified in Section
219.105(a),
(d), and
(f) and by complying with the
recordkeeping and reporting requirements specified
in subsection
(c) below.
c)
Recordkeeping and Reporting.
The VON content of each
fountain solution and ink and the efficiency of each
control device shall be determined by the applicable
test methods and procedures specified in Section
219.105 to establish the records required under this
subsection.
1)
Any owner or operator of a printing line which is
exempted from the limitations of subsection
(b)
because of the criteria in subsection
(a)
shall
comply with the following:
A)
By a date consistent with Section 219.106,
the owner or operator of a facility to which
subsection
(c) (1)
is applicable shall certify
to the Agency that the facility is exempt
under the provisions of subsection
(a).
Such
certification shall include:
i)
A declaration that the facility is
exempt from the limitations of
subsection
(b) because of the criteria
in subsection. (a), and
ii)
Calculations which demonstrate that
total maximum theoretical emissions of
VON from all heatset-web—offset
lithographic printing lines at the
facility never exceed 90.7 Mg (100 tons)
per calendar year before the application
of air pollution control equipment.
Total maximum theoretical emissions of
VON for a heatset—web-offset
lithographic printing facility is the
sum of maximum theoretical emissions of
VON from each heatset-web-offset
lithographic printing line at the
facility.
The following equation shall
be used to calculate total maximum
118
theoretical emissions of VON per
calendar year in the absence of air
pollution control equipment for each
heatset-web-offset lithographic printing
line at the facility.
E~
=
(A x B)
+
(C x D)
100
where:
E~
=
Total maximum theoretical emissions
of VON from one heatset—web-offset
printing line in units of kg/year
(lbs/year),
A
=
Weight of VOM per volume of solids
of ink with the highest VON content
as applied each year on the
printing line in units of kg VON/i-
(lbs VON/gal) of solids, and
B
=
Total volume of solids for all inks
that ~an potentially be applied
each year on the printing line in
units of 1/year (gal/year).
The
instrument or method by which the
owner or operator accurately
measured or calculated the volume
of each ink as applied and the
amount that can potentially be
applied each year on the printing
line shall be described in the
certification to the Agency.
C
=
The weight percent VON of the
fountain solution with the highest
VON content.
D
=
The total volume of fountain
solution that can potentially be
used each year on the printing line
in units of 1/year
(gal/year).
The
instrument and/or method by which
the owner or operator accurately
measured or calculated the volume
of each fountain solution used and
the amount that can potentially be
used each year on the printing line
shall be described in the
certification to the Agency.
119
B)
On and after a date consistent with Section
219.106, the owner or operator of a facility
to which subsection
(C) (1) is applicable
shall collect and record all of the following
information each year for each printing line
and maintain the information at the facility
for a period of three years:
i)
The name and identification of each
fountain solution and ink as applied on
each printing line.
ii)
The VON content and the volume of each
fountain solution and ink as applied
each year on each printing line.
C)
On and after a date consistent with Section
219.106, the owner or operator of a facility
exempted from the limitations of subsection
(b) because of the criteria in subsection
(a)
shall notify the Agency of any record showing
that total maximum theoretical emissions of
VON from all printing lines exceed 90.7 Mg
(100 tons)
in any calendar year in the
absence of air pollution control equipment by
sending a copy of such record to the Agency
within 30 days after the exceedance occurs.
2)
Any owner or operator of a printing line subject
to the limitations of subsection
(b) and complying
by means of subsection
(b) (1)
shall comply with
the following:
A)
By a date consistent with Section 219.106, or
upon initial start-up of a new printing line,
or upon changing the method of compliance for
an existing printing line from subsection
(b) (2) to subsection
(b) (1); the owner or
operator of the subject printing line shall
perform all tests and submit to the Agency
the results of all tests and calculations
necessary to demonstrate that the subject
printing line will be in compliance with
subsection
(b) (1) on and after a date
consistent with Section 219.106, or on and
after the initial start-up date.
B)
On and after a date consistent with Section
219.106, or on and after the initial start-up
date,
the owner or operator of a printing
line subject to the limitations of subsection
(b)
and complying by means of subsection
120
(b)
(1)
shall collect and record the following
information each day for each printing line
and maintain the information at the facility
for a period of three years:
i)
Control device monitoring data.
ii)
A log of operating time for the control
device, monitoring equipment and the
associated printing line.
iii) A maintenance log for the control device
and monitoring equipment detailing all
routine and nonroutine maintenance
performed including dates and duration
of any outages.
C)
On and after a date consistent with Section
219.106, the owner or operator of a subject
printing line shall notify the Agency
in the
following instances:
i)
Any record showing violation of
subsection
(b) (1)
shall be reported by
sending
a copy of such record to the
Agency within 30 days following the
occurrence of the violation.
ii)
At least 30 calendar days before
changing the method of compliance with
subsection
(b)
from subsection
(b) (1) to
(b) (2), the owner or operator shall
comply with all requirements of
subsection
(c) (3) (A).
Upon changing the
method of compliance with subsection
(b)
from subsection
(b)(1)
to (b)(2), the
owner or operator shall comply with all
requirements of subsection
(c) (3).
3)
Any owner or operator of a printing line subject
to the limitations of subsection
(b) and complying
by means of subsection
(b) (2)
shall comply with
the following:
A)
By a date consistent with Section 219.106, or
upon initial start-up of a new printing line,
or upon changing the method of compliance for
an existing printing line from subsection
(b) (1) to
(b) (2); the owner or operator of
the subject printing line shall perform all
tests and submit to the Agency and the USEPA
the results of all tests and calculations
121
necessary to demonstrate that the subject
printing line will be in compliance with
subsection
(b) (2) on and after
a date
consistent with Section 219.106, or on and
after the initial start-up date.
B)
On and after a date consistent with Section
219.106, or on and after the initial start—up
date, the owner or operator of a printing
line subject to the limitations of subsection
(b) and complying by means of subsection
(b) (2)
shall collect and record the following
information each day for each printing line
and maintain the information at the facility
for a period of three years:
i)
The VON content of the fountain solution
used each day on each printing line.
ii)
A log of operating time for the control
device and the associated printing line.
iii) A maintenance log for the control device
detailing all routine and non—routine
maintenance performed including dates
and duration of any outages.
C)
On and after a date consistent with Section
219.106, the owner or operator of a subject
printing line shall notify the Agency in the
following instances:
i)
Any record showing violation of
subsection
(b) (2)
shall be reported by
sending a copy of such record to the
Agency within 30 days following the
occurrence of the violation.
ii)
At least 30 calendar days before
changing the method of compliance with
subsection
(b) from subsection
(b) (2) to
(b) (1), the owner or operator shall
comply with all requirements of
subsection
(C)
(2) (A).
Upon changing the
method of compliance with subsection
(b)
from subsection
(b) (2) to
(b) (1), the
owner or operator shall comply with all
requirements of subsection
(c) (2).
d)
Compliance Schedule.
Every owner or operator of
a
heatset-web-offset lithographic printing line shall
comply with the applicable requirements of subsections
122
(b) and
(c)
in accordance with the applicable
compliance schedule specified in subsection
(d)(1),
(d) (2), or
(d) (3)
below:
1)
No owner or operator of a heatset—web—offeet
lithographic printing line which is exempt from
the limitations of subsection
(b) because of the
criteria in subsection
(a) shall operate said
printing line on or after a date consistent with
Section 219.106, unless the owner or operator has
complied with, and continues to comply with,
subsection
(b) (1) and
(c) (1).
2)
No owner or operator of a heatset—web—offset
lithographic printing line complying by means of
subsection
(b) (1)
shall operate said printing line
on or after a date consistent with Section
219.106, unless the owner or operator has complied
with, and continues to comply with,
subsection
(b)(2)
and (c)(2).
3)
No owner or operator of a heatset—web—offset
lithographic printing line complying by means of
subsection
(b) (2)
shall operate said printing line
on or after a date consistent with Section
219.106, unless the owner or operator has complied
with, and continues to comply with,
subsection
(C)
(3)
SUBPART
Q:
LEAKS FROM SYNTHETIC ORGANIC CHEMICAL
AND
POLYMER
MANUFACTURING
EQUIPMENT
Section 219.421
General Requirements
The owner or operator of a plant which processes more than 3660
mg/yr
(4033 tons/year)
gaseous and light liquid VON, and whose
components are used to manufacture the synthetic organic
chemicals or polymers listed in Appendix A, shall comply with
this Subpart.
The provisions of this Subpart are applicable to
components containing 10 percent or more by weight VON as
determined
by
ASTN
method E-l68, E-169 and E-260,
incorporated by
reference in Section 219.112.
Those components that are not
process unit components are exempt from this
Subpart.
A
component shall be considered to be leaking if the VON is equal
to, or is greater than 10,000 ppmv as methane or hexane as
determined
by USEP.A Reference Method 21,
as specified at 40 CFR
60, Appendix A, incorporated by reference in Section 219.112,
indication of liquids dripping, or indication by a sensor that a
seal or barrier fluid system has failed.
The provisions of this
Subpart are not applicable if the equipment components are used
to produce heavy liquid chemicals only from heavy liquid feed or
raw materials.
123
Section 219.422
Inspection Program Plan for Leaks
The owner or operator of a synthetic organic chemical or polymer
manufacturing plant subject to Section 219.421 shall prepare an
inspection program plan which contains, at a minimum:
a)
An identification of all components and the period in
which each will be monitored pursuant to Section
219. 423.
b)
The format for the monitoring log required by Section
219.425.
c)
A description of the monitoring equipment to be used
when complying with Section 219.423, and
d)
A description of the methods to be used to identify all
pipeline valves, pressure relief valves in gaseous
service,
all leaking components, and components
exempted under Section 219.423(i)
such that they are
obvious and can be located by both plant personnel
-performing monitoring and Agency personnel performing
inspections.
Section 219.423
Inspection Program for Leaks
The owner or operator of a synthetic organic chemical or polymer
manufacturing plant subject to this subpart shall, for the
purposes of detecting leaks, conduct a component inspection
program using the test methods specified in Method 21,
40 CFR 60,
Appendix A (1986), incorporated by reference in Section 219.112,
consistent with the following provisions:
a)
Test annually those components operated near extreme
temperature or pressure such- that they would be unsafe
to routinely monitor and those components which would
require the elevation of monitoring personnel higher
than two meters above permanent worker access
structures or surfaces.
b)
Test quarterly all other pressure relief valves in gas
service, pumps in light liquid service, valves in light
liquid service and in gas service, and compressors.
c)
If less than or equal to 2 percent of the valves in
light liquid service and in gas service tested pursuant
to subsection
(b) are found not to leak for
five consecutive quarters, no leak tests shall be
required for three consecutive quarters.
Thereafter,
leak tests shall resume for the next quarter.
If that
test shows less than or equal to 2 percent of the
124
valves in light liquid service and in gas service are
leaking, then no tests are required for the next
three quarters.
If more than
2 percent are leaking,
then tests are required for the next five quarters.
d)
Observe visually all pump seals weekly.
e)
Test immediately any pump seal from which liquids are
observed dripping.
f)
Test any relief valve within 24 hours after it has
vented to the atmosphere.
g)
Routine instrument monitoring of valves which are not
externally regulated,
flanges,
and equipment in heavy
liquid service,
is not required.
However, any valve
which is not externally regulated,
flange or piece of
equipment
in heavy liquid service that is found to be
leaking on the basis of sight,
smell or sound shall be
repaired as soon as practicable but no later than
30 days after the leak is found.
h)
Test immediately after repair any component that was
found leaking.
i)
Within one hour of its detection,
a weatherproof,
readily visible tag, in bright colors such as red or
yellow, bearing an identification number and the date
on which the leak was detected must be affixed on the
leaking component and remain in place until the leaking
component is repaired.
j)
The following components are exempt from the monitoring
requirements in this Section:
1)
Any component that is in vacuum service, and
2)
Any pressure relief valve that is connected to an
operating flare header or vapor recovery device.
Section 219.424
Repairing Leaks
All leaking components must be repaired and retested as soon as
practicable but no later than 15 days after the leak is found
unless the leaking component cannot be repaired until the process
unit is shut down.
Records of repairing and retesting must be
maintained in accordance with Section 219.425 and 219.426.
Section 219.425
Recordkeeping for Leaks
a)
The owner or operator of a synthetic organic chemical
or polymer manufacturing plant shall maintain a leaking
125
components monitoring log which shall contain, at a
minimum, the following information:
1)
The name of the process unit where the component
is located;
2)
The type of component
(e.g., valve,
seal);
3)
The identification number of the component;
4)
The date on which a leaking component is
discovered;
5)
The date on which a leaking component is repaired;
6)
The date and instrument reading of the recheck
procedure after a leaking component is repaired;
7)
A record of the calibration of the monitoring
instrument;
8)
The identification number of leaking components
which cannot be repaired until process unit
shutdown; and
9)
The total number of valves in light liquid service
and in gas service inspected;
the total number and
the percentage of these valves found leaking
during the monitoring period.
b)
Copies of the monitoring log shall be retained by the
owner or operator for a minimum of two years after the
date on which the record was made or the report was
prepared.
c)
Copies of the monitoring log shall be made available to
the Agency upon verbal or written request prior to or
at the time of inspection pursuant to Section 4(d) of
the Environmental Protection Act
(Act)
(Ill.
Rev.
Stat.
1989,
ch.
111 1/2, pars.
1001 et seq.)
at any
reasonable time.
Section 219.426
Report for Leaks
The owner or operator of a synthetic organic chemical or polymer
manufacturing plant subject to Section 219.421 through 219.430
shall:
a)
Submit quarterly reports to the Agency on or before
March 31, June 30, September 30, and December 31 of
each year,
listing all leaking components identified
pursuant to Section 219.423 but not repaired within 15
126
days, all leaking components awaiting process unit
shutdown, the total
number
of components inspected,
the
type of components inspected,
and the total number of
components found leaking, the total number of valves in
light liquid service and in gas service inspected and
the number and percentage of valves in light liquid
service and in gas service found leaking.
b)
Submit a signed statement with the report attesting
that all monitoring and repairs were performed as
required under Section 219.421 through 219.427.
Section 219.427
Alternative Program for Leaks
The Agency shall approve an alternative program of monitoring,
recordkeeping, or reporting to that prescribed in this Subpart
upon a demonstration by the owner or operator of such plant that
the alternative program will provide plant personnel and Agency
personnel with an equivalent ability to identify and repair
leaking components.
Any alternative program, can be allowed when
approved by the Agency and approved by the USEPA as a SIP
revision.
Section 219.428
Open—Ended Valves
a)
Each open-ended valve shall be equipped with a cap,
blind flange,
plug, or a second valve,
except during
operations requiring fluid flow through the open-ended
valve.
b)
Each open—ended valve equipped with a second valve
shall be operated in a manner such that the valve on
the process fluid end is closed before the second valve
is closed.
c)
Components which are open-ended valves and which serve
as a sampling connection shall be controlled such that:
1)
A closed purge system or closed vent system shall
return purged process fluid to the process line
with no detectable volatile organic material
emissions to the atmosphere,
or
2)
A closed purge system or closed vent system shall
collect and recycle purged process fluid to the
process line with no detectable volatile organic
material emissions to the atmosphere,
or
3)
Purged process fluid shall be transported to
a
control device that complies with the requirements
of Section 219.429.
127
d)
In-situ sampling systems are exempt from subsection
(C).
Section 219.429
Standards for Control Devices
Control devices used to comply with Section 219.428(c)
shall
comply with the following:
a)
If the control device is a vapor recovery system
(for
example, condensers and adsorbers),
it shall be
designed and operated to recover the volatile organic
material emissions vented to it with an efficiency of
95 percent or greater.
b)
If the control device is an enclosed combustion device,
it shall be designed and operated to reduce the
volatile organic material emissions vented to it with
an efficiency of 95 percent or greater, or to provide a
minimum residence time of 0.75 seconds at a minimum
temperature of 816°C.
-
c)
If the control device is a flare,
it shall:
1)
Be designed for and operated with no visible
emissions as determined by USEPA Reference Method
22,
40 CFR 60, Appendix A
(1986), incorporated by
reference in Section 219.112, except for periods
not to exceed a total of 5 minutes during any 2
consecutive hours.
2)
Be operated with a pilot flame present at all
times and shall be monitored with a thermocouple
or any other equivalent device to detect the
presence of the pilot flame.
3)
Be steam—assisted,
air—assisted, or nonassisted.
4)
Be used only with the net heating value of the gas
being
combusted
being 11.2
NJ/scm
(300 Btu/scf) or
greater if the flare is steam-assisted or
air-assisted; or with the net heating value of the
gas being combusted being 7.45 NJ/scm or greater
if the flare is nonassisted.
The net heating
value of the gas being combusted shall be
calculated using the following equation:
n
H
=
K
E
C.H.
r
i—i
1
Where:
128
Hr
=
Net heating value of the sample in NJ/scm;
where the net enthalpy per mole of offgas is based
on combustion at 25°Cand 760 mm Hg, but the
standard temperature for determining the volume
corresponding to one mole is 20°C.
K
=
Constant,
1.740 x 10~’(1/ppm) (g-mole/scm) (MJ/Kcal)
where
standard temperature for
(g—mole/scm)
is 20°C.
=
Concentration of sample component
i,
in ppm,
as measured by USEPA Reference Method 18,
40
CFR 60, Appendix A (1986),
and
ASTN
D
2504-83, both incorporated by reference in
Section 219.112.
=
Net heat of combustion of sample component i,
kcal/g mole.
The heats of combustion may be
determined using
ASTN
D
2382-83, incorporated
by reference in Section 219.112,
if published
values are not available or cannot be
calculated.
5)
Steam—assisted and nonassisted flares shall be
designed and operated with an exit velocity, as
determined by dividing the volumetric flowrate (in
units of standard temperature and pressure),
as
determined by USEPA Reference Method
2 or 2A, 40
CFR 60, Appendix A
(1986)
incorporated by
reference in Section 219.112, as appropriate; by
the unobstructed
(free)
cross sectional area of
the flare tip, less than 18 rn/sec
(60 ft/sec).
6)
Air-assisted flares shall be designed and operated
with an exit velocity less than the maximum
permitted velocity, V~, as determined by the
following equation:
=
8.706
+
O~7O84(Hr)•
V~
=
Maximum permitted velocity, m/sec.
8.706
=
Constant.
0.7084
=
Constant.
Hr
=
The net heating value as determined in
subsection
(c) (4) of this section.
d)
If the control device
is a closed container,
it shall
be designed and operated to reduce the volatile organic
material emissions, vented from purged process fluid
129
after transfer,
to no detectable volatile organic
material emissions as determined by USEPA Reference
Method 21 as specified at 40 CFR 60, Appendix A
(1986),
incorporated by reference in Section 219.112.
For
purposes of this Section,
the phrase “after transfer”
shall refer to the time at which the entire amount of
purged process fluid resulting from a flushing or
cleaning of the sample line enters the closed container
or containers including the final container(s) prior to
disposal.
e)
The owner or operator of a control device shall monitor
the control device to ensure that it is operated and
maintained in conformance with the manufacturer’s
specifications, modified to the particular process
design.
f)
The control device shall be operated at all times when
emissions may be vented to it.
Section 219.430
Compliance Date
The owner tr operator of a synthetic organic chemical or polymer
manufacturing plant subject to 35 111.
Mm.
Code 215.430 through
215.438 as of December 31,
1987 shall have complied with the
standards and limitations of those Sections no later than
December 31,
1987.
SUBPART R:
PETROLEUM REFINING AND RELATED INDUSTRIES; ASPHALT MATERIALS
Section 219.441
Petroleum Refinery Waste Gas Disposal
a)
Except as provided in subsection
(b) or
(c), no person
shall cause or allow the discharge of organic materials
in excess of 100 ppm equivalent methane (molecular
weight 16.0)
into the atmosphere from:
1)
Any catalyst regenerator of a petroleum cracking
system; or
2)
Any petroleum fluid coker; or
3)
Any other waste gas stream from any petroleum or
petrochemical manufacturing process.
b)
Exception.
Existing sources subject to subsection
(a) (3)
may, alternatively, at their election, comply
with the organic material emission limitations imposed
by 35 Ill.
Adm.
Code 215.301 or 215.302; provided,
however, that there shall be no increase in emissions
from such sources above the level of emissions in
130
existence on May 3,
1979.
c)
New Sources.
Sources subject to subsection
(a) (3),
construction of which commenced on or after January
1,
1977, may, at their election, comply with the following
emission limitations:
1)
A maximum of eight pounds per hour of organic
material; or
2)
Emission of organic material in excess of the
limitation of subsection
(C)
(1)
is allowable if
such emissions are controlled by air pollution
control methods or equipment approved by the
Agency capable of reducing by 85 percent or more
the uncontrolled organic material that would
otherwise be emitted to the atmosphere.
Such
methods or equipment must be approved by the
Agency and approved by the USEPA as a SIP
revision.
Section 219.442
Vacuum Producing Systems
No owner or operator of a petroleum- refinery shall cause or allow
the operation of any vacuum producing system unless the
condensers,
hot wells and accumulators of any such system are
equipped with vapor loss control equipment including, but not
limited to,
piping, valves,
flame arrestors and hot well covers,
to vent any volatile organic material with a vapor pressure of
10.34 kPa
(1.5 psia)
or greater at 294.3°K(70°F)to a heater,
fire box,
flare,
refinery fuel gas system, or other equipment or
system of equal emission control as approved by the Agency and
approved by the USEPA as a SIP revision.
This Section shall not
apply to vacuum producing systems on lube units.
Section 219.443
Wastewater
(Oil/Water)
Separator
No owner or operator of
a petroleum refinery shall operate any
wastewater (oil/water) separator at a petroleum refinery unless
the separator is equipped with air pollution control equipment
capable of reducing by 85 percent or more the uncontrolled
organic material emitted to the atmosphere.
If no odor nuisance
exists, the limitation of this Section shall not apply if the
vapor pressure of the organic material is below 10.34 kPa (1.5
psia) at 204.3°K(70°F) at all times.
Section 219.444
Process Unit Turnarounds
a)
No owner or operator of a petroleum refinery shall
cause or allow a refinery process unit turnaround
except in compliance with an operating procedure as
approved by the Agency.
131
b)
Unless a procedure was already on file with the Agency
as part of an approved operating permit no later than
November
1,
1979,
the owner or operator of a petroleum
refinery shall submit to the Agency for approval a
detailed procedure for reducing emissions of volatile
organic material during refinery process unit
turnarounds from organic material with a vapor pressure
of 10.34 kPa (1.5 psia) or greater at 294.3°K(70°?).
The Agency shall not approve the procedure unless it
provides for:
1)
Depressurization of the refinery process unit or
vessel to a flare, refinery fuel gas system, or
other equipment or system of equal emission
control,
as approved by the Agency and approved by
the USEPA as a SIP revision, until the internal
pressure from the vessel or unit is less than 5.0
psig before allowing the vessel to be vented to
the atmosphere;
2)
Recordkeeping of the following items:
A)
Each date that a refinery unit or vessel is
shut down; and
B)
The total estimated quantity of volatile
organic material emitted to the atmosphere
and the duration of the emission in hours.
Section 219.445
Leaks:
General Requirements
a)
The owner or operator of a petroleum refinery shall:
1)
Develop a monitoring program plan consistent with
the provisions of Section 219.446;
2)
Conduct a monitoring program consistent with the
provisions of Section 219.447;
3)
Record all leaking components which have a
volatile organic material concentration exceeding
10,000 ppm consistent with the provisions of
Section 219.448;
4)
Identify each component consistent with the
monitoring program plan submitted pursuant to
Section 219.446;
5)
Repair and retest the leaking components as soon
as possible within 22 days after the leak is
found, but no later than June 1 for the purposes
132
of Section 219.447(a) (1), unless the leaking
components cannot be repaired until the unit is
shut down for turnaround; and
6)
Report to the Agency consistent with the
provisions of Section 219.449.
Section 219.446
Monitoring Program Plan for Leaks
The owner or operator of a petroleum refinery shall prepare
a
monitoring program plan which contains, at a minimum:
a)
An identification of all refinery components and the
period in which each will be monitored pursuant to
Section 219.447;
b)
The format for the monitoring log required by Section
219.448;
-c)
A description of the monitoring equipment to be used
pursuant to Section 219.447; and
d)
A description of the methods to be used to identify all
pipeline valves, pressure relief valves in gaseous
service and all leaking components such that they are
obvious to both refinery personnel performing
monitoring and Agency personnel performing inspections.
Section 219.447
Monitoring Program for Leaks
a)
The owner or operator of a petroleum refinery subject
to Section 219.445 shall,
for the purpose of detecting
leaks, conduct a component monitoring program
consistent with the following provisions:
1)
Test once between March 1 and June 1 of each year,
by methods referenced in Section 219.105(g), all
pump seals, pipeline valves in liquid service and
process drains.
2)
Test once each quarter of each calendar year, by
methods referenced in Section 219.105(g), all
pressure relief valves in gaseous service,
pipeline valves in gaseous service and compressor
seals.
3)
Inaccessible valves may be tested once each
calendar year instead of once each quarter of each
calendar year.
4)
Observe visually all pump seals weekly.
133
5)
Test immediately any pump seal from which liquids
are observed dripping,
6)
Test any relief valve within 24 hours after it has
vented to the atmosphere,
and
7)
Test immediately after repair any component that
was found leaking.
b)
Storage tank valves and pressure relief devices
connected to an operating flare header or vapor
recovery device are exempt from the monitoring
requirements in subsection
(a).
c)
The Agency may require more frequent monitoring than
would otherwise be required by subsection
(a)
for
components which are demonstrated to have a history of
leaking.
Section 219.448
Recordkeeping for Leaks
a)
The owner or operator of a petroleum refinery shall
maintain a leaking components monitoring log which
shall contain,
at a minimum, the following information:
1)
The name of the process unit where the component
is located;
2)
The type of component
(e.g., valve,
seal);
3)
The identification number of the component;
4)
The date on which
a leaking component is
discovered;
5)
The
date on which
a leaking component is repaired;
6)
The date and instrument reading of the recheck
procedure after a leaking component is repaired;
7)
A record of the calibration of the monitoring
instrument;
8)
The identification number of leaking components
which cannot be repaired until turnaround; and
9)
The total number of components inspected and the
total
number
of components found leaking during
that monitoring period.
b)
Copies of the monitoring log shall be retained by the
owner or operator for a minimum of two years after the
134
date on which the record was made or the report
prepared.
C)
Copies of the monitoring log shall be made available to
the Agency, upon verbal or written request, at any
reasonable time.
Section 219.449
Reporting for Leaks
The owner or operator of a petroleum refinery shall:
a)
Submit a report to the Agency prior to the 1st day of
both July and September listing all leaking components
identified pursuant to Section 219.447 but not repaired
within 22 days,
all leaking components awaiting unit
turnaround, the total number of components inspected
and the total number of components found leaking;
b)
Submit a signed statement with the report attesting
that all monitoring and repairs were performed as
required under Sections 219.445 through 219.448.
Section 219.450
Alternative Program for
Leaks.
The Agency may approve an alternative program of monitoring,
recordkeeping or reporting to that prescribed in Sections 219.446
through 219.449 upon a demonstration by the owner or operator of
a petroleum refinery that the alternative program will provide
refinery, Agency and USEPA personnel with an equivalent ability
to identify and repair leaking components.
Any
alternative
program can be allowed only if approved by the USEPA as a SIP
revision.
Section 219.451
Sealing Device Requirements
Except for safety pressure relief valves, no owner or operator of
a petroleum refinery shall install or operate a valve at the end
of a pipe or line containing volatile organic materials unless
the pipe or line is sealed with a second valve, blind flange,
plug, cap or other sealing device.
The sealing device may be
removed only when a sample is being taken or during maintenance
operations.
Section 219.452
Compliance Schedule for Leaks
The owner or operator of a petroleum refinery shall adhere to the
increments of progress contained in the following schedule:
a)
Submit to the Agency a monitoring program consistent
with Section 219.446 prior to July 1,
1991 or a date
consistent with Section 219.106.
135
b)
Submit to the Agency the first monitoring report
pursuant to Section 219.449 prior to August
1,
1991 or
a date consistent with Section 219.106.
Section 218.453
Compliance Dates
Every
owner or operator of a petroleum refinery subject to 35
Ill.
Adju.
Code 215, Subpart R as of December 31,
1987 shall have
complied with its standards and limitations by December 31,
1987.
SUBPART
5:
RUBBER
AND
MISCELLANEOUS
PLASTIC
PRODUCTS
Section 219.461
Manufacture of Pneumatic Rubber Tires
The owner or operator of an undertread cementing, treadend
cementing
or
bead
dipping
operation
at
a
pneumatic
rubber
tire
manufacturing facility shall install and operate:
a)
A capture system, with minimum capture efficiency of 65
percent by weight of VON for treadend cementing or bead
dipping operations and a capture system with a minimum
capture efficiency of 55.5 percent by weight of VON for
undertread cementing;
and
b)
A control device that meets the requirements of one of
the following:
1)
A carbon adsorption system designed and operated
in a manner such that there is at least a 90
percent removal of VON by weight from the gases
ducted to the control device;
2)
An afterburning system that oxidizes at least 90
percent of the captured nonmethane VON (VOM
measured as total combustible carbon) to carbon
dioxide and water; and
3)
An alternative VON emission reduction system
demonstrated to have at least a 90 percent overall
reduction efficiency and approved by the Agency
and approved by the USEPA.
Section 219.462
Green Tire Spraying Operations
The owner or operator of a green tire spraying operation at a
pneumatic rubber tire manufacturing facility shall:
a)
Install and operate:
1)
A capture system- with a minimum capture efficiency
of 90 percent by weight of VON; and
136
2)
A control device that meets the requirements of
one of the following:
A)
A carbon adsorption system designed and
operated in a manner such that there
is at
least 90 percent removal of VON by weight
from the bases ducted to the control device;
B)
An afterburning system that oxidizes at least
90 percent of the captured rioninethane VON
(measured as total combustible carbon) to
carbon dioxide and water; or
C)
An alternative VON emission reduction system
demonstrated to have at least a 90 percent
overall reduction efficiency approved by the
Agency and approved by the USEPA as a SIP
revision.
b)
Substitute for the normal solvent—based mold release
compound water-based sprays containing:
1)
No more than five percent by volume of VON as
applied for the inside of tires;
2)
No more than ten percent by vOlume of VON as
applied for the outside of tires.
Section 219.463
Alternative Emission Reduction Systems
In lieu of complying with Section 219.461 or 219.462, the owner
or operator of an emission source may utilize an alternative
volatile organic emission reduction system, including an
alternative production process, which is demonstrated to be
equivalent to Section 219.461 or 219.462 on the basis of
emissions of volatile organic matter.
A treadend cementing
operation shall be considered equivalent to Section 219.461 or
219.462 for the purposes of this Section if the total volatile
organic emission from such operation is 10 grams or less per
tire.
Section 219.464
Testing and Monitoring
a)
Upon a reasonable request by the Agency, the owner or
operator of a VON emission source required to comply
with a limit of Sections 219.461 through 219.464 shall
conduct emissions testing, at such person’s own
expense, to demonstrate compliance.
b)
A person planning to conduct a VON emission test to
demonstrate compliance shall notify the Agency of that
intent not less than 30 days before the planned
137
initiation of the tests so the Agency may observe the
test.
Section 218.465
Compliance Dates
Every owner or operator of an emission source subject to 35 Ill.
Adm.
Code 215, Subpart 5,
as of December 31,
1987 shall have
complied with its standards and limitations by December 31,
1987.
Section 219.466
Compliance Plan
a)
The owner or operator of an emission source shall have
submitted
to
the
Agency a compliance plan, pursuant to
35 Ill. Adm. Code 201, Subpart H, including a project
completion schedule where applicable, no later than
April 21,
1983.
b)
Unless the submitted compliance plan or schedule was
disapproved by the Agency, the owner or operator of a
facility or emission source may operate the emission
source according to the plan and schedule as submitted.
C)
The plan and schedule shall meet the requirements of 35
Ill. Adm. Code 201, Subpart
H, including specific
interim dates as required in 35 Ill.
Adm. Code 201.242.
SUBPART
T:
PHARMACEUTICAL
MANUFACTURING
Section 219.480
Applicability
a)
The rules of this Subpart, except for Sections 219.483
through 219.485, apply to all emission sources of VON,
including but not limited to reactors, distillation
units, dryers, storage tanks for VOL, equipment for the
transfer of VOL,
filters, crystallizers, washers,
laboratory hoods, pharmaceutical coating operations,
mixing operations and centrifuges used in
manufacturing, including packaging, of pharmaceuticals,
and emitting more than 6.8 kg/day
(15 lbs/day) and more
than 2,268 kg/year (2.5 tons/year)
of VON.
If an
emission source emits less than 2,268 kg/year
(2.5
tons/year)
of VON, the requirements of this Subpart
still apply to the emission source if VON emissions
from the emission source exceed 45.4 kg/day
(100 lbs/day).
b)
Notwithstanding subsection
(a), the air suspension
coater/dryer,
fluid
bed
dryers,
tunnel
dryers,
and
Accelacotas located in Libertyville Township,
Lake
County, Illinois shall be exempt from the rules of this
Subpart, except for Sections 219.483 through 219.485,
if emissions of VON not vented to air pollution control
138
equipment
do
not
exceed
the
following
levels:
1)
for the air suspension coater/dryer:
2,268 kg/year
(2.5 tons/year);
2)
for each fluid bed dryer: 4,535 kg/year
(5.0 tons/year);
3)
for each tunnel dryer: 6,803 kg/year (7.5
tons/year);
and
4)
for each Accelacota:
6,803 kg/year
(7.5 tons/year).
c)
Sections 219.483 through 219.485 apply to a plant
having one or more emission sources that:
1)
Are used to manufacture pharmaceuticals, and
2)
Emit more than 6.8 kg/day
(15, lbs/day)
of VOM and
more than 2,268 kg/year (2.5 tOns/year) of VON,
or,
if less than 2,268 kg/year (2.5 tons/year),
these Sections still apply
if emissions from one
or more sources exceed 45.4 kg/day
(100 lbs/day).
d)
No owner or operator shall violate any condition in a
permit when the condition results in exclusion of an
emission source from this Subpart.
e)
Any pharmaceutical manufacturing source that becomes
subject to the provisions of this Subpart at any time
shall remain subject to the provisions of this Subpart
at all times.
f)
Emissions subject to this Subpart shall be controlled
at all times consistent with the requirements set forth
in this Subpart.
g)
Any control device required pursuant to this Subpart
shall be operated at all times when the source it is
controlling is operated.
h)
Determinations of daily and annual emissions for
purposes
of
this
Section
shall
be
made
using
both
data
on the hourly emission rate (or the emissions per unit
of throughput)
and appropriate daily and annual data
from records of emission source operation (or material
throughput or material consumption data).
In the
absence of representative test data pursuant to Section
219.487 for the hourly emission rate
(or the emissions
per unit of throughput), such items shall be calculated
using engineering calculations, including the methods
139
described in Appendix B of “Control of Volatile Organic
Emissions from Manufacturing of Synthesized
Pharmaceutical Products” (EPA-450/2—78-029),
incorporated by reference in Section 219.112.
(This
subsection shall not affect the Agency’s or the USEPA’s
authority to require emission tests to be performed
pursuant to Section 219.487.)
Section 219.481
Control of Reactors, Distillation Units,
Crystallizers, Centrifuges and Vacuum Dryers
a)
The owner or operator shall equip all reactors,
distillation units, crystallizers, centrifuges and
vacuum dryers that are used to manufacture
pharmaceuticals with surface condensers or other air
pollution control equipment listed in subsection
(b).
If a surface condenser is used,
it shall be operated
such that the condenser outlet gas temperature does not
exceed:
1)
248.2eK (-13°F)when condensing VON of vapor
pressure greater than 40.0 kPa (5.8 psi)
at
294.3°K(70°?), or
2)
258.2°K(5°?)when condensing VON of vapor
pressure greater than 20.0 kPa (2.9 psi)
at
294.3°K(70°F),or
3)
273.2°K(32°F)when condensing VON of vapor
pressure greater than 10.0 kPa (1.5 psi)
at
294.3°K(70oF),
or
4)
283.2.K (50°F)when condensing VON of vapor
pressure greater than 7.0 kPa
(1.0 psi)
at 294.3°K
(70°F),or
5)
298.2°K(77°F)when condensing VON of vapor
pressure greater than 3.45 kPa (0.5 psi)
at
294.3°K(70°F).
b)
If a scrubber, carbon adsorber, thermal afterburner,
catalytic afterburner, or other air pollution control
equipment other than a surface condenser is used,
such
equipment shall provide a reduction in the emissions of
VON of 90 percent or more.
C)
The owner or operator shall enclose all centrifuges
used to manufacture pharmaceuticals and that have an
exposed VOL surface, where the VON in the VOL has
a
vapor pressure of 3.45 kPa (0.5 psi) or more at 294.3°K
(70°F),except as production,
sampling, maintenance, or
inspection procedures require operator access.
140
Section 219.482
Control of Air Dryers, Production Equipment
Exhaust Systems and Filters
a)
The owner or operator of an air dryer or production
equipment exhaust system used to manufacture
pharmaceuticals shall control the emissions of VON from
such emission sources by air pollution control
equipment
which
reduces
by
90
percent
or
more
the
VON
that would otherwise be emitted into the atmosphere.
b)
The owner or operator shall enclose all rotary vacuum
filters and other filters used to manufacture
pharmaceuticals and that have an exposed VOL surface,
where the VON in the VOL has a vapor pressure of 3.45
kPa
(0.5 psi)
or more at 294°K(70°F),except as
production,
sampling, maintenance, or inspection
procedures require operator access.
Section 219.483
Material Storage and Transfer
The owner or operator of a pharmaceutical manufacturing plant
shall:
a)
Provide a vapor balance system that is at least
90 percent effective in reducing VON emissions from
truck or railcar deliveries to storage tanks with
capacities equal to or greater than 7.57 m3
(2,000 gal)
that store VOL with vapor pressures greater than
28.0 kPa (4.1 psi) at 294.3°K(70°F),and
b)
Install,
operate, and maintain pressure/vacuum
conservation
vents
set
at
0.2
kPa
(0.03
psi)
or
greater
on all storage tanks that store VOL with vapor
pressures greater than 10 kPa (15 psi) at 294.3°K
(70°?).
Section 219.484
In-Process Tanks
The owner or operator shall install covers on all in-process
tanks used to manufacture pharmaceuticals and containing a VOL at
any time.
These covers must remain closed, except as production,
sampling, maintenance or inspection procedures require operator
access.
Section 219.485
Leaks
The owner or operator of a pharmaceutical manufacturing plant
shall repair any component from which a leak of VOL can be
observed.
The repair shall be completed as soon as practicable
but no later than 15 days after the leak is found.
If the
leaking component cannot be repaired until the process unit is
141
shut down,
the leaking component must then be repaired before the
unit is restarted.
Section 219.486
Other Emission Sources
The owner or operator of a washer, laboratory hood, tablet
coating operation,
mixing operation or any other process emission
source not subject to Sections 219.481 through 219.485, and used
to manufacture pharmaceuticals shall control the emissions of VON
from such emission sources by:
a)
Air pollution control equipment which reduces by
81 percent or more the VON that would otherwise be
emitted to the atmosphere,
or
b)
A surface condenser which captures all the VON which
would otherwise be emitted to the atmosphere and which
meets the requirements of Section 219.481(a)
and
(b).
Section 219.487
Testing
a)
Upon request by the Agency or the USEPA, the owner or
operator of any VON emission source subject to this
Subpart or exempt from this Subpart by virtue of the
provisions of Section 219.480 shall, at his own
expense, demonstrate compliance to the Agency and the
USEPA by the methods or procedures listed in Section
219.105(f) (1).
b)
A person planning to conduct a VON emissions test to
demonstrate compliance with this Subpart shall notify
the Agency and the USEPA of that intent not less than
30 calendar days before the planned initiation of the
test.
Section 219.488
Monitoring for Air Pollution Control
Equipment
a)
At a minimum,
continuous monitors for the following
parameters shall be installed on air pollution control
equipment used to control sources subject to this
Subpart:
1)
Destruction device combustion temperature.
2)
Temperature rise across a catalytic afterburner
bed.
3)
VON concentration on a carbon adsorption unit to
determine breakthrough.
4)
Outlet gas temperature of a refrigerated
142
condenser.
5)
Temperature of a non-refrigerated condenser
coolant supply system.
b)
Each monitor shall be equipped with a recording device.
c)
Each monitor shall be calibrated
quarterly.
d)
Each monitor shall operate at all times while the
associated control equipment is operating.
Section 219.489
Recordkeeping for Air Pollution Control
Equipment
a)
The owner or operator of a pharmaceutical manufacturing
facility shall maintain the following records:
1)
Parameters listed in Section 219.488(a) (1)
shall
be recorded.
2)
For sources subject to Section 219.481, the vapor
pressure of VON being controlled shall be recorded
for every process.
b)
For any leak subject to Section 219.485 which cannot be
readily repaired within one hour after detection, the
following records shall be kept:
1)
The name of the leaking equipment,
2)
The date and time the leak is detected,
3)
The action taken to repair the leak,
and
4)
The data and time the leak is repaired.
c)
The following records shall be kept for emission
sources subject to Section 219.484 which contain VOL:
1)
For maintenance and inspection:
A)
The date and time each cover is opened,
B)
The length of time the cover remains open,
and
C)
The reason why the cover is opened.
2)
For production and sampling, detailed written
procedures or manufacturing directions specifying
the circumstances under which covers may be opened
143
and the procedures for opening covers.
d)
For each emission source used in the manufacture of
pharmaceuticals for which the owner or operator of a
pharmaceutical manufacturing plant claims emission
standards are not applicable, because the emissions are
below the applicability cutoffs in Section 219.480(a)
or 219.480(b), the owner or operator shall:
1)
Maintain a demonstration including detailed
engineering calculations of the maximum daily and
annual emissions for each such emission source
showing that the emissions are below the
applicability cutoffs in Section 219.480(a)
or
219.480(b), as appropriate, for the current and
prior calendar years;
2)
Maintain appropriate operating records for each
such emission source to identify whether the
applicability cutoffs in Section 219.480(a)
or
219.480(b), as appropriate, are ever exceeded; and
3)
Provide written notification to the Agency and the
USEPA within 30 days of a determination that such
an emission source has exceeded the applicability
cutoffs in Section 219.480(a)
or 219.480(b),
as
appropriate.
e)
Records required under subsection
(a)
shall be
maintained by the owner or operator for a minimum of
two years after the date on which they are made.
f)
Copies
of
the
records
shall
be
made
available
to
the
Agency or the USEPA upon verbal or written request.
SUBPART
V:
AIR
OXIDATION
PROCESSES
Section 219.521
Definitions
In addition to the definitions of 35 Ill.
Athu. Code 211,
the
following definitions apply to this Subpart:
“Air Oxidation Process”:
any unit process including
ammoxidation
and
oxychlorination
which
uses
air
or
a
combination
of
air
and
oxygen
as
an
oxidant
in
combination
with
one
or
more
organic
reactants
to
produce one or more organic compounds.
“Cost Effectiveness”:
the annual expense for cost of
control of a given process stream divided by the
reduction in emissions of organic material of that
stream.
144
“Flow
(F)”:
Vent stream flowrate (scm/mm)
at a
standard temperature of 20°C.
“Full
Operating
Flowrate”:
Maximum
operating
capacity
of the facility.
“Hourly Emissions
(E)”:
Hourly emissions reported in
kg/hr measured at full operating flowrate.
“Net Heating Value
(H)”:
Vent stream net heating value
(NJ/scm),
where the net enthalpy per mole of offgas is
based on combustion at 25°Cand 760 mm Hg, but the
standard temperature for determining the volume
corresponding to one mole is 20°C,as
in the definition
of “Flow.”
“Process Vent Stream”:
An emission stream resulting
from
an
air
oxidation
process.
“Total
Resource
Effectiveness
Index
(TRE)”:
Cost
effectiveness in dollars per megagrain of controlling
any gaseous stream vented to the atmosphere from an air
oxidation process divided by $1600/Mg, using the
criteria and methods set forth in this Subpart and
Appendices C and D.
Section 219.525
Emission Limitations for Air Oxidation
Processes
a)
No person shall cause or allow the emission of volatile
organic material
(VON)
from any process vent stream
unless the process vent stream is vented to a
combustion
device
which
is
designed
and
operated
either:
1)
To reduce the volatile organic emissions vented to
it with an efficiency of at least ninety eight
percent
(98)
by weight; or
2)
To emit VON at a concentration less than twenty
parts per million by volume,
dry
basis.
b)
Air oxidation facilities for which an existing
combustion
device
is
employed
to
control
process
VON
emissions are not required to meet the 98 percent
emissions limit until the combustion device is replaced
for other reasons, which shall be considered to
include, but not be limited to, normal maintenance,
malfunction, accident, and obsolescence.
The
combustion
device
is
considered
to
be
replaced
when:
145
1)
All of the device is replaced; or
2)
When the cost of the repair of the device or the
cost of replacement of part of the device exceeds
50
of the cost of replacing the entire device
with a device which complies.
c)
The limitations of subsection
(a) do not apply to any
process vent stream or combination of process vent
streams which has a Total Resource Effectiveness Index
(TRE)
greater. than 1.0,
as determined by the following
methods:
1)
If an air oxidation process has more than one
process
vent
stream,
TRE
shall
be
based
upon
a
combination
of
the
process
vent
streams.
2)
TRE of a process vent stream shall be determined
according to the following equation:
TRE
=
E1
a
+
bF~
+
cF
+
dFH
+
e(FH)’1
+
fF05
where:
n
=
0.88
TRE
=
Total resource effectiveness index.
F
=
Vent stream flowrate (scm/mm), at a
standard temperature of 20°C.
E
=
Hourly measured emissions in kg/hr.
H
=
Net heating value of vent stream
(NJ/scm),
where the net enthalpy per
mole
of
offgas
is
based
on
combustion
at
25°Cand 760
inn Hg, but the standard
temperature for determining the volume
corresponding to one mole is 20°C,as in
the definition of “Flow”.
a,b,c,d,
e and f
=
Coefficients obtained by use of Appendix
F.
3)
For nonchiorinated process vent streams,
if the
net heating value,
H,
is greater than 3.6 NJ/scm,
F shall be replaced by F1 for purposes of
calculating TRE.
F1 is computed as follows:
F1
=
FH
/
3.6
146
where F and H are as defined in subsection
(c) (2).
4)
The actual numerical values used in the equation
described in subsection
(c) (2) shall be determined
as follows:
A)
All reference methods and procedures for
determining the flow,
(F), hourly emissions,
(E), and net heating,
(H), value shall be in
accordance with Appendix C.
B)
All coefficients described in subsection
(C)
(2)
shall be in accordance with Appendix
D.
Section 219.526
Testing and Monitoring
a)
Upon
reasonable
request
by
the
Agency,
the
owner
or
operator of an air oxidation process shall demonstrate
compliance with this Subpart by use of the methods
specified in Appendix C.
This Section does not limit
the USEPA’s authority, under the Clean Air Act,
to
require demonstrations of compliance.
b)
A person planning to conduct a VON emissions test to
demonstrate compliance with this Subpart shall notify
the Agency of that intent not less than 30 days before
the planned initiation of the tests so that the Agency
may observe the test.
Section 219.527
Compliance Date
Each owner or operator of an emission source subject to 35 Ill.
Adm. Code 215, Subpart V, as of December 31,
1987 shall have
complied with the standards and limitations of 35 Ill.
Adin. Code
215, Subpart V, by December 31,
1987.
SUBPART W:
AGRICULTURE
Section 219.541
Pesticide Exception
The provisions of Sections 219.301 and 219.302 shall not apply to
the spraying or use of insecticides, herbicides or other
pesticides.
SUBPART X:
CONSTRUCTION
Section 219.561
Architectural Coatings
No person shall cause or allow the sale or use of any
architectural coating containing more than 20 percent by volume
of photo-chemically reactive material
in containers having
a
147
capacity of more than one gallon.
Section 219.562
Paving Operations
The provisions of Sections 219.301 and 219.302 shall not apply to
the application of paving asphalt and pavement marking paint from
sunrise to sunset.
Section 219.563
Cutback Asphalt
a)
No person shall cause or allow the use or application
of cutback asphalt for paving,
resurfacing,
reconditioning,
repairing or otherwise maintaining a
roadway unless:
1)
The use or application of the cutback asphalt
commences
on
or
after
October
1
of
any
year
and
such use or application is completed by April
30
of the following year; or
2)
The cutback asphalt is a long-life stockpile
material which remains in stock after April
30 of
each year and as such it may be used until
depleted for patching potholes and for other
similar
repair
work;
or
3)
The cutback asphalt is to be used solely as an
asphalt prime coat.
b)
Sources subject to this Section are not required to
submit or obtain an Agency approved compliance plan or
project completion schedule under 35 Ill. Adm. Code
201, Subpart H.
SUBPART Y:
GASOLINE DISTRIBUTION
Section 219.581
Bulk Gasoline Plants
a)
Subject to Subsection
(e), no person may cause or allow
the transfer of gasoline from a delivery vessel into a
stationary storage tank located at a bulk gasoline
plant unless:
1)
The delivery vessel and the stationary storage
tank are each equipped with a vapor collection
system that meets the requirements of subsection
(d) (4),
2)
Each vapor collection system
is operating,
3)
The delivery vessel displays the appropriate
sticker pursuant to the requirements of Sections
148
219.584
(b) or
(d),
4)
The pressure relief valve(s)
on the stationary
storage tank and the delivery vessel are set to
release at no less than 0.7 psi or the highest
pressure allowed by state or local fire codes or
the
guidelines
of
the
National
Fire
Prevention
Association,
and
5)
The stationary storage tank is equipped with a
submerged loading pipe.
b)
Subject to subsection
(f), no person may cause or allow
the
transfer
of
gasoline
from
a
stationary
storage
tank
located
at
a
bulk
gasoline
plant
into
a
delivery
vessel
unless:
1)
The requirements set forth in subsections
(a) (1)
through
(a) (4) are met, and
2)
Equipment is available at the bulk gasoline plant
to provide for the submerged filling of the
delivery vessel or the delivery vessel is equipped
for bottom loading.
c)
Subject to subsection
(e), each owner of a stationary
storage
tank
located
at
a
bulk
gasoline
plant
shall:
1)
Equip each stationary storage tank with a vapor
control system that meets the requirements of
subsection
(a) or
(b), whichever is applicable,
2)
Provide instructions to the operator of the bulk
gasoline plant describing necessary maintenance
operations and procedures for prompt notification
of the owner in case of any malfunction of a vapor
control system, and
3)
Repair, replace or modify any worn out or
malfunctioning component or element of design.
d)
Subject to subsection
(e), each operator of a bulk
gasoline plant shall:
1)
Maintain and operate each vapor control system in
accordance with the owner’s instructions,
2)
Promptly notify the owner of any scheduled
maintenance or malfunction requiring replacement
or repair of a major component of a vapor control
system, and
149
3)
Maintain gauges, meters or other specified testing
devices in proper working order,
4)
Operate the bulk plant vapor collection system and
gasoline loading equipment in a manner that
prevents:
A)
Gauge pressure from exceeding 45.7 cm
(18
in.) of water and vacuum from exceeding 15.2
c-rn
(6
in.) of water, as measured as close as
possible to the vapor hose connection, and
B)
A
reading
equal
to
or
greater
than
100
percent of the lower explosive limit
(LEL
measured as propane) when tested in
accordance
with
the
procedure
described
in
“Control of Volatile Organic Compound Leaks
from Gasoline Tank Trucks and Vapor
Collection Systems”, Appendix B,
EPA 450/2-78-051,
(incorporated by reference
in Section 219.112), and
C)
Avoidable leaks of liquid during loading or
unloading operations.
5)
Provide
a
pressure
tap
or
equivalent
on
the
bulk
plant vapor collection system in order to allow
the
determination
of
compliance
with
subsection
(d) (4) (A), and
6)
Within 15 business days after discovery of any
leak
by
the
owner,
the
operator,
the
Agency
or
the
USEPA, repair and retest a vapor collection system
which exceeds the limits of subsection
(d) (4) (A)
or
(B).
e)
The requirements of subsections
(a),
(c) and
(d)
shall
not apply to:
1)
Any
stationary
storage
tank
with
a
capacity
of
less than 2,177
1
(575 gal),
or
2)
Any bulk gasoline plant whose daily gasoline
throughput is less than 15,140
1
(4,000 gal/day)
on a thirty-day rolling average.
f)
The requirements of subsection
(b)
shall apply only to
bulk gasoline plants whose daily gasoline throughput is
greater than or equal to 15,140
1
(4,000 gal/day)
on a
thirty-day rolling average.
g)
Any
bulk
gasoline
plant
which
is
ever
subject
to
150
subsections
(a),
(b),
(c),
or
(d)
shall
always
be
subject to these paragraphs.
Section 219.582
Bulk Gasoline Terminals
a)
No person shall cause or allow the transfer of gasoline
into
any
delivery
vessel
from
any
bulk
gasoline
terminal
unless:
1)
The bulk gasoline terminal is equipped with a
vapor control system that limits emission of VON
to
80
mg/l
(0.00067
lbs/gal)
of
gasoline
loaded;
2)
The vapor control system is operating and all
vapors displaced in the loading of gasoline to the
delivery vessel are vented only to the vapor
control system;
3)
There is no liquid drainage from the loading
device when it is not
in use;
4)
All
loading
and
vapor
return
lines
are
equipped
with
fittings
which
are
vapor
tight;
and
5)
The
delivery
vessel
displays
the
appropriate
sticker pursuant to the requirements of Section
219.584(b) or
(d); or,
if the terminal
is
driver—loaded, the terminal owner or operator
shall
be
deemed
to
be
in
compliance
with
this
Section
when
terminal
access
authorization
is
limited
to
those
owners
and/or
operators
of
delivery vessels who have provided a current
certification as required by Section
219.584(c) (3).
b)
Bulk
gasoline
terminals
were
required
to
take
certain
actions
to
achieve
compliance
which
are
summarized
in
35 Ill. Adm. Code 215, Appendix C.
c)
The
operator
of
a
bulk
gasoline
terminal
shall:
1)
Operate the terminal vapor collection system and
gasoline loading equipment in a manner that
prevents:
A)
Gauge pressure from exceeding 18 inches of
water
and
vacuum
from
exceeding
6
inches
of
water as measured as close as possible to the
vapor hose connection; and
B)
A
reading
equal
to
or
greater
than
100
percent
of
the
lower
explosive
limit
(LEL
151
measured
as
propane)
when
tested
in
accordance with the procedure described in
EPA 450/2-78-051 Appendix B incorporated by
reference in Section 219.112; and
C)
Avoidable leaks of liquid during loading or
unloading operations.
2)
Provide a pressure tap or equivalent on the
terminal
vapor
collection
system
in
order
to
allow
the determination of compliance with Section
219.582(d) (1) (A); and
3)
Within 15 business days after discovery of the
leak
by
the
owner,
operator,
or
the
Agency
repair
and
retest
a
vapor
collection
system
which
exceeds
the limits of subsection
(c)(1)(A) or
(B).
Section 219.583
Gasoline Dispensing Facilities
a)
Subject to subsection
(b), no person shall cause or
allow the transfer of gasoline from any delivery vessel
into
any
stationary
storage
tank
at
a
gasoline
dispensing
facility
unless:
1)
The
tank
is
equipped
with
a
submerged
loading
pipe; and
2)
The vapors displaced from the storage tank during
filling are processed by a vapor control system
that includes one or more of the following:
A)
A vapor collection system that meets the
requirements
of
subsection
(d) (4);
or
B)
A
refrigeration—condensation
system
or
any
other system approved by the Agency and
approved by the USEPA as a SIP revision, that
recovers at least 90 percent by weight of all
vaporized organic material from the equipment
being controlled; and
C)
The delivery vessel displays the appropriate
sticker pursuant to the requirements of
Section 219.584(b)
or
(d).
b)
The requirements of subsection
(a) (2)
shall not apply
to transfers of gasoline to a stationary storage tank
at a gasoline dispensing facility if:
1)
The
tank
is
equipped
with
a
floating
roof,
or
other system of equal or better emission control
152
as approved by the Agency and approved by the
USEPA as a SIP revision;
2)
The tank has a capacity of less than 2000 gallons
and was in place and operating before January
1,
1979;
or
3)
The tank has a capacity of less than 575 gallons.
c)
Subject to subsection
(b), each owner of a gasoline
dispensing facility shall:
1)
Install all control systems and make all process
modifications required by subsection
(a);
2)
Provide instructions to the operator of the
gasoline
dispensing
facility
describing
necessary
maintenance
operations
and
procedures
for
prompt
notification of the owner in case of any
malfunction
of
a
vapor
control
system;
and
3)
Repair, replace or modify any worn out or
malfunctioning component or element of design.
d)
Subject to subsection
(b), each operator of a gasoline
dispensing facility shall:
1)
Maintain
and
operate
each
vapor
control
system
in
accordance with the owner’s instructions;
2)
Promptly notify the owner of any scheduled
maintenance or malfunction requiring replacement
or repair of a major component of a vapor control
system;
3)
Maintain
gauges,
meters
or
other
specified
testing
devices in proper working order;
4)
Operate the vapor collection system and delivery
vessel unloading points in
a manner that prevents:
A)
A reading equal to or greater than 100
percent of the lower explosive limit
(LEL
measured as propane) when tested in
accordance with the procedure described in
EPA 450/2-78-051 Appendix B, and
B)
Avoidable
leaks
of
liquid
during
the
filling
of storage tanks; and
5)
Within
15
business
days
after
discovery
of
the
leak by the
owner,
operator, or the Agency, repair
153
and
retest
a
vapor
collection
system
which
exceeds
the
limits
of
subsection
(d) (4) (A).
e)
Gasoline dispensing facilities were required to take
certain actions to achieve compliance which are
summarized
in
35
Ill.
Adxn.
Code 215, Appendix C.
Section
219.584
Gasoline
Delivery
Vessels
a)
Any delivery vessel equipped for vapor control by use
of vapor collection equipment:
1)
Shall
have
a
vapor
space
connection
that
is
equipped with fittings which are vapor tight;
2)
Shall
have
its
hatches
closed
at
all
times
during
loading
or
unloading
operations,
unless
a
top
loading
vapor
recovery
system
is
used;
3)
Shall
not
internally
exceed
a
gauge
pressure
of
18
inches
of
water
or
a
vacuum
of
6
inches
of
water;
4)
Shall
be
designed
and
maintained
to
be
vapor
tight
at
all
times
during
normal
operations;
5)
Shall
not
be
refilled
in
Illinois
at
other
than:
A)
A
bulk
gasoline
terminal
that
complies
with
the
requirements
of
Section
219.582
or
B)
A
bulk
gasoline
plant
that
complies
with
the
requirements
of
Section
219.581(b).
6)
Shall
be
tested
annually
in
accordance
with
Method
27,
40
CFR
60,
Appendix
A,
incorporated
by
reference
in
Section
219.105.
Each
vessel
must
be
repaired
and
retested
within
15
business
days
after
discovery
of
the
leak
by
the
owner,
operator, or the Agency, when it fails to sustain:
A)
A pressure drop of no more than three inches
of water in five minutes; and
B)
A
vacuum
drop
of
no
more
than
three
inches
of
water
in
five
minutes.
b)
Any
delivery
vessel
meeting
the
requirements
of
subsection
(a)
shall have
a sticker affixed to the tank
adjacent to the tank manufacturer’s data plate which
contains
the
tester’s
name,
the
tank
identification
number
and
the
date
of
the
test.
The
sticker
shall
be
in
a
form
prescribed
by
the
Agency,
and,
for
those
154
delivery
vessels
subject
to
35
Ill.
Adm.
Code
215
as
of
December
31,
1987
shall
have
been
displayed
no
later
than
December
31,
1987.
c)
The
owner
or
operator
of
a
delivery
vessel
shall:
1)
Maintain
copies
of
any
test
required
under
subsection
(a) (6)
for
a
period
of
3
years;
2)
Provide
copies
of
these
tests
to
the
Agency
upon
request;
and
3)
Provide annual test result certification to bulk
gasoline
plants
and
terminals
where
the
delivery
vessel
is
loaded.
d)
Any
delivery
vessel
which
has
undergone
and
passed
a
test
in
another
state
which
has
a
USEPA-approved
leak
testing
and
certification
program
will
satisfy
the
requirements
of
subsection
(a).
Delivery
vessels
must
display
a
sticker,
decal
or
stencil
approved
by
the
state
where
tested
or
comply
with
the
requirements
of
subsection
(b).
All
such. stickers,
decals
or
stencils
shall
have
been
displayed
no
later
than
December
31,
1987,
for
delivery
vessels
subject.
to
35
Ill.
Adm.
Code
215 as of December 31,
1987.
Section 219.585
Gasoline Volatility Standards
a)
No person shall sell, offer for sale, dispense,
supply,
offer for supply, or transport for use in Illinois
gasoline
whose
Reid
vapor
pressure
exceeds
the
applicable
limitations
set
forth
in
subsections
(b)
and
(C)
during
the
regulatory
control
periods,
which
shall
be July
1 to August 31 for retail outlets, wholesale
purchaser—consumer
facilities,
and
all
other
facilities.
b)
The
Reid
vapor
pressure
of
gasoline,
a
measure
of
its
volatility, shall not exceed 9.5 psi
(65.5 kPa) during
the regulatory control period in 1990 and each year
thereafter.
c)
The Reid vapor pressure of ethanol blend gasolines
shall not exceed the limitations for gasoline set forth
in subsection
(b) by more than 1.0 psi
(6.9 kPa).
Notwithstanding
this
limitation,
blenders
of
ethanol
blend gasolines whose Reid vapor pressure is less than
1.0 psi above the base stock gasoline immediately after
blending with ethanol are prohibited from adding butane
or
any
product
that
will
increase
the
Reid
vapor
pressure of the blended gasoline.
155
d)
All
sampling
of
gasoline
required
pursuant
to
the
provisions of this Section shall be conducted by one or
more of the following approved methods or procedures
which
are
incorporated
by
reference
in
Section
215.105.
1)
For
manual
sampling,
ASTN
D4057;
2)
For automatic sampling, ASTM D4177;
3)
Sampling procedures for Fuel Volatility,
40 CFR 80
Appendix D.
e)
The Reid vapor pressure of gasoline shall be measured
in accordance with either test method ASTN D323 or a
modification of ASTN D323 known
as
the
“dry
method”
as
set
forth
in
40
CFR
80,
Appendix
E,
incorporated
by
reference in 35 Ill. Adm. Code 215.105.
For gasoline
oxygenate blends which contain water—extractable
oxygenates, the Reid vapor pressure shall be measured
using the dry method test.
f)
The
ethanol
content
of
ethanol
blend
gasolines
shall
be
determined by use of one of the approved testing
methodologies specified in 40 CFR 80, Appendix F,
incorporated by reference in 35 Ill. Adm. Code 215.105.
g)
Any
alternate to
the
sampling
or
testing
methods
or
procedures
contained
in
subsections
(d),
(e),
and
(f)
must
be
approved
by
the
Agency,
which
shall
consider
data comparing the performance of the proposed
alternative
to
the
performance
of
one
or
more
approved
test
methods
or
procedures.
Such
data
shall
accompany
any
request
for
Agency
approval
of
any
alternate
test
procedure.
If
the
Agency
determines
that
such
data
demonstrates
that
the
proposed
alternative
will
achieve
results equivalent to the approved test methods or will
achieve results equivalent to the approved test methods
or procedures, the Agency shall approve the proposed
alternative.
h)
Each
refiner
or
supplier
that
distributes
gasoline
or
ethanol
blends
shall:
1)
During
the
regulatory
control
period,
state
that
the
Reid
vapor
pressure
of
all
gasoline
or
ethanol
blends
leaving
the
refinery
or
distribution
facility
for
use
in
Illinois
complies
with
the
Reid
vapor
pressure
limitations
set
forth
in
35
Ill.
Adm.
Code
215.585(b)
and
(C).
Any
facility
receiving this gasoline shall be provided with a
copy of an invoice, bill of lading, or other
156
documentation
used
in
normal
business
practice
stating that the Reid vapor pressure of the
gasoline complies with the State Reid vapor
pressure standard.
2)
Maintain records for a period of one year on the
Reid vapor pressure, quantity shipped and date of
delivery of any gasoline or ethanol blends leaving
the
refinery
or
distribution
facility
for
use
in
Illinois.
The Agency shall be provided with
copies of such records if requested.
SUBPART Z:
DRY
CLEANERS
Section
219.601
Perchloroethylene
Dry
Cleaners
The owner or operator of a dry cleaning facility which uses
perchloroethylene shall:
a)
Vent the entire dryer exhaust through a properly
designed and functioning carbon adsorption system or
equally effective control device; and
b)
Emit no more than 100 ppmv of VON from the dryer
control device before dilution,
or achieve a 90 percent
average
reduction
before
dilution;
and
c)
Immediately repair all components found to be leaking
liquid
VON;
and
d)
Cook
or
treat
all
diatomaceous
earth
filters
so
that
the
residue
contains
25
kg
(55
ib)
or
less
of
volatile
organic material per 100 kg (220
lb) of wet waste
material;
and
e)
Reduce the vVOM from all solvent stills to 60 kg
(132
lb)
or
less
per
100
kg
(220
1b)
of
wet
waste
material;
and
f)
Drain
all
filtration
cartridges
in
the
filter
housing
or other sealed container for at least 24 hours before
discarding the cartridges; and
g)
Dry all drained filtration cartridges in equipment
connected
to
an
emission
reduction
system
or
in
a
manner
that
will
eliminate
emission
of
volatile
organic
material to the atmosphere.
Section
219.602
Exemptions
The
provisions
of
Section
219.601
are
not
applicable
to
perchloroethylene dry cleaning operations which are coin-operated
157
or
to
dry
cleaning
facilities
consuming
less
than
30
gal
per
month
(360
gal
per
year)
of
perchioroethylene.
Section 219.603
Leaks
The presence of leaks shall be determined for purposes of Section
219.601(c) by
a visual inspection of the following: hose
connections, unions, couplings and valves; machine door gaskets
and seatings; filter head gasket and seating; pumps; base tanks
and storage containers; water separators; filter sludge recovery;
distillation unit; diverter valves; saturated lint from lint
baskets; and cartridge filters.
Section 219.604
Compliance Dates
Every
owner
or
operator
of
an
emission
source
previously
subject
to
35
Ill.
Adm.
Code
215,
Subpart
Z
shall
have
complied
with
its
standards and limitations in accordance with the applicable dates
set
forth
in
35
Ill.
Adm.
Code
215.604.
Section
219.605
Compliance
Plan
a)
The
owner
or
operator
of
an
emission
source
subject
to
this
Subpart
shall
have
submitted
to
the
Agency
a
compliance
plan,
pursuant
to
35
Iii.
Adm.
Code
201,
Subpart
H,
including
a
project
completion
schedule
where applicable,
no later than,
for Section 219.601(a)
and
(b), April
21, 1983.
b)
Unless
the
submitted
compliance
plan
or
schedule
was
disapproved
by
the
Agency,
the
owner
or
operator
of
a
facility or emission source may operate the emission
source according to the plan and schedule as submitted.
C)
The
plan
and
schedule
shall
meet
the
requirements
of
35
Ill.
Adm.
Code
201,
Subpart
H,
including
specific
interim
dates
as
required
in
35
Ill.
Adm.
Code
201.242.
Section 219.606
Exception to Compliance Plan
Coin—operated dry cleaning operations and dry cleaning facilities
consuming less than 30 gal per month (360 gal per year)
of
perchloroethylene are not required to submit or obtain an Agency
approved compliance plan or project completion schedule.
Section 219.607
Standards for Petroleum Solvent Dry Cleaners
a)
The owner or operator of a petroleum solvent
dry
cleaning dryer shall either:
1)
Limit
emissions
of
volatile
organic
material
to
the atmosphere to an average of 3.5 kilograms of
158
VON
per
100
kilograms
dry
weight
of
articles
dry
cleaned, or
2)
Install and operate a solvent recovery dryer in a
manner such that the dryer remains closed and the
recovery phase
continues until a final solvent
flow rate of 50 ml per minute is attained.
b)
The owner or operator of a petroleum solvent filtration
system shall either:
1)
Reduce the VON content in all filtration wastes to
1.0 kilogram or less per 100 kg dry weight of
articles dry cleaned, before disposal, and
exposure
to
the
atmosphere,
or
2)
Install
and
operate
a
cartridge
filtration
system,
and
drain
the
filter
cartridges
in
their
sealed
housings for
8 hours or more before their removal.
Section
219.608
Operating
Practices
for
Petroleum
Solvent
Dry
Cleaners
In
order
to
minimize
fugitive
solvent
emissions,
the
owner
or
operator
of
a
petroleum
solvent
dry
cleaning
facility
shall
employ
good
housekeeping
practices
including
the
following:
a)
General Housekeeping Requirements
1)
Equipment
containing
solvent
(washers,
dryers,
extractors and filters) shall remain closed at all
times except during load transfer and maintenance.
Lint filter and button trap covers shall remain
closed except when solvent—laden material
is being
removed.
2)
Cans,
buckets,
barrels
and
other
containers
of
solvent or of solvent—laden material shall be
covered except when in use.
3)
Solvent-laden material shall be exposed to the
atmosphere only for the minimum time necessary for
load transfer.
b)
Installation and operation of equipment:
1)
All
cartridge
filters
shall
be
enclosed
and
operated in accordance with the procedures and
specifications recommended by the manufacturer for
the cartridge filter.
After installation, the
cartridges shall be inspected, monitored and
maintained in accordance with the manufacturer’s
159
recommendations;
and
2)
Vents on containers for new solvent and for
solvent—containing waste shall be constructed and
maintained so as to minimize solvent vapor
emissions.
Criteria
for
the
minimization
of
solvent
vapor
emissions
include
the
elimination
of
solvent
buckets
and
barrels
standing
open
to
the
atmosphere, and the repair of gaskets and seals
that
expose
solvent—rich
environments
to
the
atmosphere, to be determined through visual
inspection.
Section
219.609
Program
for
Inspection
and
Repair
of
Leaks
a)
The
owner
or
operator
of
a
petroleum
solvent
dry
cleaning
facility
shall
conduct
the
following
visual
inspections on a weekly basis:
1)
Washers,
dryers,
solvent
filters,
settling
tanks,
vacuum
stills
and
containers
and
conveyors
of
petroleum
solvent
shall
be
inspected
for
visible
leaks
of
solvent
liquid.
2)
Pipes, hoses and fittings shall be inspected for
active
dripping
or
dampness.
3)
Pumps
and
filters
shall
be
inspected
for
leaks
around seals and access covers.
4)
Gaskets
and
seals
shall
be
inspected
for
wear
and
defects.
b)
Leaks
of
petroleum
solvent
liquid
and
vapors
shall
be
repaired
within
three
working
days
of
detection,
unless
necessary
replacement
parts
are
not
on
site.
1)
If
necessary,
repair
parts
shall
be
ordered
within
three
working
days
of
detection
of
the
leak.
2)
The leak shall be repaired within three days of
delivery of necessary parts.
Section
219.610
Testing
and
Monitoring
a)
Compliance
with
Sections
219.607(b)
(2),
215.608
and
215.609
shall
be
determined
by
visual
inspection;
and
b)
Compliance
with
Sections
219.607(a)
(2)
and
(b)(1)
shall
be
determined
by
methods
described
in
EPA-450/3-82-009
(1982)
incorporated
by
reference
in
Section
219.112.
160
C)
If a control device is used to comply with Section
219.607(a) (1), then compliance shall be determined
using 40
CFR
60 Appendix A, Method 25
(1984)
incorporated by reference in Section 219.112.
Section
219.611
Exemption
for
Petroleum
Solvent
Dry
Cleaners
The provisions of Sections 219.607 through 219.610 shall not
apply to petroleum solvent dry cleaning facilities whose
emissions of volatile organic material do not exceed 91 Mg (100
tons) per year in the absence of pollution control equipment or
whose emissions of VON, as limited by the operating permit, will
not exceed 91 Mg (100 tons) per year in the absence of pollution
control equipment.
Section
219.612
Compliance
Dates
Owners and operators of emission sources subject to 35 Ill.
Adm.
Code 215.607 through 215.609 as of December 31,
1987 shall have
complied
with
the
requirements
set
forth
therein
no
later
than
December
31,
1987.
Section 219.613
Compliance Plan-
a)
The owner or operator of an emission source formerly
subject
to
35
Ill.
Adm.
Code
215.610(a)
as
of
May
31,
1987 shall have submitted to the Agency a compliance
plan,
including a project completion schedule where
applicable,
no
later
than
Nay
31,
1987.
b)
The
plan
and
schedule
shall
meet
the
requirements
of
35
Ill.
Adm.
Code
201.
SUBPART
AA:
PAINT
AND
INK
MANUFACTURING
Section
219.620
Applicability
a)
This subpart shall apply to all paint and ink
manufacturing
plants
which:
1)
Include
process
emission
sources
not
subject
to
Subparts B,
E, F (excluding Section 219.204(1)), H
excluding Section 219.405),
Q,
R,
S,
V,
X,
Y
or
Z
of this Part;
and which as a group both:
A)
have maximum theoretical emissions of 91 Mg
(100 tons) or more per calendar year of VON
if
no
air
pollution
control
equipment
were
used, and
B)
are
not
limited
to
less
than
91
Mg
(100
tons)
161
of VON emissions per calendar year in the
absence of air pollution control equipment,
through production or capacity limitations
contained in a federally enforceable
construction
permit
or
a
SIP
revision,
or
2)
Produce more than 7,570,820 1
(2,000,000 gal) per
calendar year of paint or ink formulations, which
contain less than 10 percent (by weight) water,
and ink formulations not containing as the primary
solvents water, Magie oil or glycol.
b)
For the purposes of this Subpart, uncontrolled VOM
emissions are the emissions of VOM which would result
if
no
air
pollution
control
equipment
were
used.
Section 219.621
Exemption for Waterbase Material and
Heatset-Offset
Ink
The
requirements
of
Sections
219.624
and
219.625
and
Section
219.628(a)
shall
not
apply
to
equipment
while
it
is
being
used
to
produce either:
a)
paint or ink formulations which contain 10 percent or
more
(by
weight)
water,
or
b)
inks
containing
Magie
oil
and
glycol
as
the
primary
solvent.
Section
219.623
Permit
Conditions
No
person
shall
violate
any
condition
in
a
permit
when
the
condition results
in exclusion of the plant or an emission source
from
this
Subpart.
Section 219.624
Open-top Mills, Tanks, Vats or Vessels
No person shall operate an open—top mill,
tank, vat or vessel
with a volume of more than 45
1
(12 gal) for the production of
paint
or
ink
unless:
a)
The mill, tank, vat or vessel is equipped with a cover
which completely covers the mill,
tank, vat or vessel
opening
except
for
an
opening
no
larger
than
necessary
to allow for safe clearance for a mixer shaft.
Such
cover shall extend at least 1.27 cm (0.5 in.) beyond
the
outer
rim
of
the
opening
or
be
attached
to
the
rim.
b)
The
cover
remains
closed
except
when
production,
sampling,
maintenance
or
inspection
procedures
require
access.
162
C)
The
cover
is
maintained
in
good
condition
such
that,
when in place,
it maintains contact with the rim of the
opening for at least 90 percent of the circumference of
the rim.
Section 219.625
Grinding Mills
a)
No person shall operate a grinding mill for the
production of paint or ink which is not maintained in
accordance with the manufacturer’s specifications.
b)
No person shall operate a grinding mill fabricated or
modified
after
the
effective
date
of
this
Subpart
which
is not equipped with fully enclosed screens.
C)
The
manufacturer’s
specifications
shall
be
kept
on
file
at the plant by the owner or operator of the grinding
mill
and
be
made
available
to
any
person
upon
verbal
or
written
request
during
business
hours.
Section
219.626
Storage
Tanks
a)
The owner or operator shall equip tanks storing VOL
with
a
vapor
pressure
greater
than
10
kPa
(1.5
psi)
at
20°C(68.F) with pressure/vacuum conservation vents set
as
a
minimum
at
+/-0.2
kPa
(0.029
psi).
These
controls
shall be operated at all times.
An alternative air
pollution
control
system
may
be
used
if
it
results
in
a
greater
emission
reduction
than
these
controls.
Any
alternative
control
system
can
be
allowed
only
if
approved by the Agency and approved by the USEPA as a
SIP revision.
b)
Stationary
VOL
storage
containers
with
a
capacity
greater
than
946
1
(250
gal)
shall
be
equipped
with
a
submerged-fill
pipe
or
bottom
fill.
These
controls
shall
be
operated
at
all
times.
An
alternative
control
system
can
be
allowed
only
if
approved
by
the
Agency
and
approved
by
the
USEPA
as
a
SIP
revision.
Section 219.628
Leaks
The
owner
or
operator
of
a
paint
or
ink
manufacturing
plant
shall,
for
the
purpose
of
detecting
leaks,
conduct
an
equipment
monitoring program as set forth below:
a)
Each
pump
shall
be
checked
by
visual
inspection
each
calendar
week
for
indications
of
leaks,
that
is,
liquids dripping from the pump seal.
If there are
indications
of
liquids
dripping
from
the
pump
seal,
the
pump
shall
be
repaired
as
soon
as
practicable,
but
no
later
than
15
calendar
days
after
the
leak
is
detected.
163
b)
Any
pump,
valve, pressure relief valve,
sampling
connection, open—ended valve and flange or connector
containing
a
fluid
which
is
at
least
10
percent
VON
by
weight which appears to be leaking on the basis of
sight,
smell
or
sound
shall
be
repaired
as
soon
as
practicable, but no later than 15 calendar days after
the leak is detected.
c)
A weather proof, readily visible tag, in bright colors
such as red or yellow, bearing an identification number
and the date on which the leak was detected shall be
attached to leaking equipment.
The tag may be removed
upon repair, that is, when the equipment is adjusted or
otherwise
altered
to
allow
operation
without
leaking.
d)
When a leak is
detected,
the
owner
or
operator
shall
record
the
date
of
detection
and
repair
and
the
record
shall
be
retained
at
the
plant
for
at
least
two
years
from
the
date
of
each
detection
or
each
repair
attempt.
The
record
shall
be
made
available
to
any
person
upon
verbal
or
written
request
during
business
hours.
Section 219.630
Clean Up
a)
No
person
shall
clean
paint
or
ink
manufacturing
equipment
with
organic
solvent
unless
the
equipment
being
cleaned
is
completely
covered
or
enclosed
except
for
an
opening
no
larger
than
necessary
to
allow
safe
clearance for proper operation of the cleaning
equipment,
considering
the
method
and
materials
being
used.
b)
No
person
shall
store
organic
wash
solvent
in
other
than
closed
containers,
unless
closed
containers
are
demonstrated
to
be
a
safety
hazard,
or
dispose
of
organic
wash
solvent
in
a
manner
such
that
more
than
20
percent
by
weight
is
allowed
to
evaporate
into
the
atmosphere.
Section 219.636
Compliance Schedule
Every
owner
or
operator
of
an
emission
source
subject
to
the
control requirements of this Subpart shall comply with the
requirements thereof on and after a date consistent with Section
219.106.
Section 219.637
Recordkeeping and Reporting
a)
Upon request by the Agency, the owner or operator of an
emission
source
which
claims
to
be
exempt
from
the
requirements
of
this
Subpart
shall
submit
records
to
164
the Agency within 30 calendar days from the date of the
request which document that the emission source is in
fact exempt from this Subpart.
These records shall
include (but are not limited to) the percent water
(by
weight)
in the paint or ink being produced and the
quantity
of
Magie
oil,
glycol
and
other
solvents
in
the
ink being produced.
b)
Every owner or operator of an emission source which is
subject to the requirements of this Subpart shall
maintain all records necessary to demonstrate
compliance with those requirements at the facility for
three years.
SUBPART BB:
POLYSTYRENE
PLANTS
Section
219.875
Applicability
of
Subpart
BB
The
provisions
of
this
Subpart
shall
apply
to
polystyrene
plants:
a)
Which
use
continuous
processes
to
manufacture
polystyrene
-
polybutadiene co-polymer; and
b)
Which
fall
within
Standard
Industrial
Classification
Group
No.
282,
Industry
No.
2821,
except
that
the
manufacture of polystyrene resins need not be the
primary
manufacturing
process
at
the
plant.
Section
219.877
Emissions
Limitation
at
Polystyrene
Plants
No
person
shall
cause
or
allow
the
emissions
of
VON
from
the
material
recovery
section
to
exceed
0.12
kg
of
VOM
per
1000
kg
of
polystyrene
resin
produced.
Section
219.879
Compliance
Date
Every owner and operator of an emission source subject to 35 Ill.
Adm. Code 215, Subpart BB as of December 31,
1987, shall have
complied
with
its
standards
and
limitations
by
December
31,
1987.
Section 219.881
Compliance Plan
a)
The
owner
or
operator
of
an
emission
source
formerly
subject
to
the
requirements
of
35
Ill.
Adm.
Code
215
Subpart
BB
shall
have
submitted
to
the
Agency
a
compliance plan in accordance with 35 Ill. Adm. Code
201, Subpart H, including a project completion schedule
on or before December
1,
1987.
b)
Unless
the
submitted
compliance
plan
or
schedule
was
disapproved by the Agency, the owner or operator of a
facility
or
emission
source
subject
to
this
Subpart
may
165
operate the emission source according to the plan and
schedule as submitted.
c)
The plan and schedule shall meet the requirements of
35
Ill. Adm. Code 201, Subpart H and Section 219.883.
Section 219.883
Special Requirements for Compliance Plan
For sources subject to this Subpart, an approvable compliance
plan shall include:
a)
A
description
of
each
process
which
is
subject
to
an
emissions
limitation;
b)
Quantification
of
the
emissions
from
each
process;
C)
A description
of
the
procedures
and
methods
used
to
determine the emissions of VON;
d)
A description of the methods which will be used to
demonstrate
compliance
with
the
allowable
plantwide
emission
limitation
(Section
215.877),
including
a
~nethod
of
inventory,
recordkeeping
and
emission
calculation
or
measurement.
Section
219.886
Emissions
Testing
a)
Upon
a
reasonable
request
by
the
Agency,
the
owner
or
operator
of
a
polystyrene
plant
subject
to
this
Subpart
shall
at
his
own
expense
demonstrate
compliance
by
use
of
the
following
method:
40
CFR
60,
Appendix
A,
Method
25
-
Determination
of
Total
Gaseous
Non—Methane
Organic.
Emissions
as
Carbon
(1984),
incorporated
by
reference
in
Section
219.112.
b)
A
person
planning
jo
conduct
a
VON
emissions
test
to
demonstrate compliance with this Subpart shall notify
the Agency of that intent not less than 30 days before
the planned initiation of the tests so the Agency may
observe the test.
SUBPART
PP:
MISCELLANEOUS
FABRICATED
PRODUCT
MANUFACTURING
PROCESSES
Section 219.920
Applicability
a)
The
requirements
of
this
Subpart
shall
apply
to
a
plant’s
miscellaneous
fabricated
product
manufacturing
process
emission
sources
which
are
not
included
within
any
of
the
source
categories
specified
in
Subparts
B,
E,
F,
H,
Q,
R,
5,
V,
X, Y or Z if the plant
is subject
to
this
Subpart.
A
plant
is
subject
to
this
Subpart
if
166
it
contains
process
emission
sources,
not
regulated
by
Subparts
B,
E,
F
(excluding
Section
219.204(1)),
H
(excluding Section 219.405),
Q,
R,
S,
V,
X,
Y
or
Z
of
this Part; which as a group both:
1)
have maximum theoretical emissions of 91 Mg (100
tons) or more per calendar year of VON if no air
pollution
control
equipment
were
used,
and
2)
are
not
limited
to
less
than
91
Mg
(100
tons)
of
VON emissions per calendar year in the absence of
air
pollution
control
equipment,
through
production
or
capacity
limitations
contained
in
a
federally
enforceable
construction
permit
or
a
SIP
revision.
b)
If
a
plant-
ceases
to
fulfill
the
criteria
of
subsection
(a), the requirements of this Subpart shall continue to
apply to a miscellaneous fabricated products
manufacturing
process
emission-
source
which
was
ever
subject
to
the
control
requirements
of
Section
219.926.
c)
No
limits
under
this
Subpart
shall
apply
to
emission
sources with emissions of VON to the atmosphere less
than or equal to 0.91 Mg (10 ton) per calendar year if
the
total
emissions
from
such
sources
not
complying
with
Section
219.926
does
not
exceed
4.5
Mg
(5.0
tons)
per calendar year.
d)
For
the
purposes
of
this
Subpart,
an
emission
source
shall
be
considered
regulated
by
a
Subpart
if
it
is
subject
to
the
limits
of
that
Subpart.
An
emission
source
is
not
considered
regulated
by
a
Subpart
if
its
emissions
are
below
the
applicability
cutoff
level
or
if
the
source
is
covered
by
an
exemption.
e)
For
the
purposes
of
this
Subpart,
uncontrolled
VON
emissions
are
the
emissions
of
VON
which
would
result
if
no
air
pollution
control
equipment
were
used.
Section 219.923
Permit Conditions
No
person
shall
violate
any
condition
in
a
permit
when
the
condition
results
in
exclusion
of
the
plant
or
an
emission
source
from
this
Subpart.
Section
219.926
Control
Requirements
Every owner or operator of an
emission
source
subject
to
this
Subpart
shall
comply
with
the
requirements
of
subsection
(a),
(b)
or
(c):
167
a)
Emission capture and control techniques which achieve
an
overall
reduction
in
uncontrolled
VON
emissions
of
at
least
81
percent,
or
b)
For coating lines, the daily-weighted average VON
content shall not exceed 0.42 kg VOM/l
(3.5 lbs
VON/gal)
of coating as applied (minus water and any
compounds which are specifically exempted from the
definition
of
VON)
during
any
day.
Owners
and
operators complying with this Section are not required
to
comply
with
Section
219.301,
or
c)
An alternative control plan which has been approved by
the
Agency
and
approved
by
the
USEPA
as
a
SIP
revision.
Section
219.927
Compliance
Schedule
Every
owner
or
operator
of
an
emission
source
subject
to
the
control
requirements
of
this
Subpart
shall
comply
with
the
requirements
thereof
on
and
after
a
date
consistent
with
Section
219.106.
Section 219.928
Testing
Any owner or operator ofavuFi e~i~onoource which is subject
cu
Lfli~
L.uDpULL
~J1~1i1
aemunstrate compliance
.i.i~.n
~~u~i.on
by using the applicable test methods and procedure3 specified in
Cection 219. 105.
a.
When in the opinion of the Agency it is necessary to conduct
testinc~
to
demonstrate
compliance
with
Section
219.926,
the
owner
or
operator
of
a
VON
emission
source
subiect
to
the
requirements of this Subpart shall,
at his own expense,
conduct
such
tests
in
accordance
with
the
appliacable
test
methods
and
procedures
specified
in
Section
219.105.
~
Nothing
in
the
Section
shall
limit
the
authority
of
the
USEPA
pursuant
to
the
Clean
Air
Act,
as
amended,
to
rec~uire
testing.
SUBPART
QQ:
MISCELLANEOUS
FORMULATION
MANUFACTURING
PROCESSES
Section 219.940
Applicability
a)
The
requirements
of
this
Subpart
shall
apply
to
a
plant’s
miscellaneous
formulation
manufacturing
process
emission
sources,
which
are
not
included
within
any
of
the
source
categories
specified
in
Subparts
B,
E,
F,
H,
Q,
R,
5,
V,
X,
Y or
Z of this Part if
the
plant
is
subject
to
this
Subpart.
A
plant
is
subject
to
this
Subpart if it contains process emission sources, not
168
regulated by Subparts
B,
E,
F (excluding Section
219.204(1)),
H
(excluding
Section
219.405),
Q,
R,
5,
V,
X,
Y
or
Z
of
this
Part;
which
as
a
group
both:
1)
have maximum theoretical emissions of 91 Mg (100
tons)
or more per calendar year of VON if no air
pollution control equipment were used, and
2)
are not limited to less than 91 Mg (100 tons)
of
VON
emissions
per
calendar
year
in
the
absence
of
air pollution control equipment, through
production or capacity limitations contained in a
federally
enforceable
construction
permit
or
a
SIP
revision.
b)
If a plant ceases to fulfill the criteria of subsection
(a),
the
requirements
of
this
Subpart
shall
continue
to
apply to a miscellaneous formulation manufacturing
process
emission
source
which
was
ever
subject
to
the
control
requirements
of
Section
219.946.
c)
No limits under this Subpart shall apply to emission
sources with emissions of VON to the atmosphere less
than or equal to 2.3 Mg (2.5 tons)
per calendar year if
the
total
emissions
from
such
sources
not
complying
with this Section does not exceed 4.5 Mg (5.0 tons) per
calendar year-.
d)
For
the
purposes
of
this
Subpart,
an
emission
source
shall
be
considered
regulated
by
a
Subpart
if
it
is
subject
to
the
limits
of
that
Subpart.
An
emission
source
is
not
considered
regulated
by
a
Subpart
if
its
emissions
are
below
the
applicability
cutoff
level
or
if
the
source
is
covered
by
an
exemption.
e)
For the purposes of this Subpart, uncontrolled VON
emissions are the emissions of VON which would result
if
no
air
pollution
control
equipment
were
used.
Section 219.943
Permit Conditions
No person shall violate any condition in a permit when the
condition
results
in
exclusion
of
the
plant
or
an
emission
source
from this Subpart.
Section 219.946
Control Requirements
Every
owner
or
operator
of
an
emission
source
subject
to
this
Subpart shall comply with the requirements of subsection
(a)
or
(b)
below.
a)
Emission
capture
and
control
techniques
which
achieve
169
an
overall
reduction
in
uncontrolled
VON
emissions
of
at least 81 percent, or
b)
An alternative control plan which has been approved by
the Agency and approved by the USEPA as
a SIP revision.
Section 219.947
Compliance Schedule
Every owner or operator of an emission source subject to the
control
requirements
of
this
Subpart
shall
comply
with
the
requirements
thereof
on
and
after
a
date
consistent
with
Section
219.106.
Section
219.948
Testing
Any
owner
or
operator
of
a
VON
emission
source
which
is
subject
to
this
Subpart
shall
demonstrate
compliance
with
Section
219.946
by
using
the
applicable
test
methods
and
procedures
specified
in
~-1-irtn
219.105.
a.
When
in
the
opinion
of
the
Agency
it
is
necessarY
to
conduct
testinci
to
demonstrate
compliance
with
Section
219.946,
the
owner
or
operator
of
a
VON
emission
source
subiect
to
the
reauirements
of
this
Subpart
shall,
at
his
own
expense,
conduct
such
tests
in
accordance
with
the
appliacable
test
methods
and
Procedures
specified
in
Section
219.105.
b.
NothincT in the Section shall limit the authority of the
USEPA
pursuant
to
the
Clean
Air
Act,
as
amended.
to
reauire
testing.
SUBPART
PR:
MISCELLANEOUS
ORGANIC
CHEMICAL
MANUFACTURING
PROCESSES
Section
219.960
Applicability
a)
The
requirements
of
this
Subpart
shall
apply
to
a
plant’s miscellaneous organic chemical manufacturing
process
emission
sources
which
are
not
included
within
any
of
the
source
categories
specified
in
Subparts
B,
E,
F,
H,
Q,
R,
5,
V,
X,
Y
or
Z
of
this
Part,
if
the
plant
is subject to this Subpart.
A plant is subject
to
this
Subpart
if
it
contains
process
emission
sources, not regulated by Subparts B,
E,
F (excluding
Section
219.204(1)),
H
(excluding
Section
219.405),
Q,
R,
S,
V,
X,
Y
or
Z of this Part; which as a group both:
1)
have
maximum
theoretical
emissions
of
91
Mg
(100
tons)
or more per calendar year of VON if no air
pollution
control
equipment
were
used,
and
170
2)
are not limited to less than 91 Mg
(100 tons)
of
VON
emissions
per
calendar
year
in
the
absence
of
air pollution control equipment, through
production or capacity limitations contained in a
federally enforceable construction permit or a SIP
revision.
b)
If a plant ceases to fulfill the criteria of Subsection
(a), the requirements of this Subpart shall continue to
apply to a miscellaneous organic chemical manufacturing
process emission source which was ever subject to the
control requirements of Section 219.966.
c)
No limits under this Subpart shall apply to emission
sources with emissions of VON to the atmosphere less
than or equal to 0.91 Mg
(1.0 ton) per calendar year if
the twt~gadt~cbnng1crG~6sdo~ssuutce~caet1
~o~pflI~i~.
0
tons)
per calendar year.
d)
For the purposes of this Subpart, an emission source
shall be considered regulated by a Subpart if it is
subject to the limits of that
Subpart.
An
emission
source is not considered regulated by a Subpart if its
emissions are below the applicability cutoff level or
if the source
is covered by an exemption.
e)
For the purposes of this Subpart, uncontrolled VOM
emissions are the emissions of VOM which would result
if no air pollution control equipment were used.
Section 219.963
Permit Conditions
No person shall
violate
any
condition
in
a
permit
when
the
condition
results
in
exclusion
of
the
plant
or
an
emission
source
from
this
Subpart.
Section
219.966
Control
Requirements
Every owner or operator of an emission source subject to this
Subpart
shall
comply
with
the
requirements
of
subsection
(a)
or
(b) below.
a)
Emission capture and control techniques which achieve
an overall reduction in uncontrolled VON emissions of
at least 81 percent, or
b)
An
alternative
control
plan
which
has
been
approved
by
the
Agency
and
approved
by
the
USEPA
as
a
SIP
revision.
Section
219.967
Compliance
Schedule
Every owner or operator of an emission source subject to the
171
control
requirements
of
this
Subpart
shall
comply
with
the
requirements
of
this
Subpart
on
and
after
a
date
consistent
with
Section
219.106.
Section
219.968
Testing
~ny owner or operator of
ci
VON emission source which is subject
to this Subpart shall demonstrate compliance with Cection 219.966
by using the applicable test methods and procedures specified in
Section 219. 105.
a.
When
in the opinion of the Aciencv it is necessary to conduct
testing to demonstrate compliance with Section 219.966. the
owner
or
operator
of
a
VON
emission
source
subject
to
the
requirements
of
this
Subpart
shall,
at
his
own
expense,
conduct
such
tests
in
accordance
with
the
a~p1iacable
test
methods
and
procedures
specified
in
Section
219.105.
~
Nothing
in
the
Section
shall
limit
the
authority
of
the
USEPA
pursuant
to
the
Clean
Air
Act,
as
amended,
to
require
testing.
SUBPART
TT:
OTHER
EMISSION
SOURCES
Section
219.980
Applicability
a)
The
requirements
of
this
Subpart
shall
apply
to
a
plant’s
VON
emission
sources,
which
are
not
included
within
any
of
the
source
categories
specified
in
Subparts
B,
E,
F,
H,
Q,
R,
S,
V,
X,
Y,
Z, AA,
PP, QQ,
or RB of this Part, or are not exempted from permitting
requirements Pursuant to 35
Ill. Adm. Code 201.146, if
the plant is subject to this Subpart.
A plant
is
subject
to
this
Subpart
if
it
contains
process
emission
sources,
not
regulated
by
Subparts
B,
E,
F
(excluding
Section 219.204(7)-), H (excluding Section 219.405), Q,
R,
5,
V,
X,
Y
or
Z
of
this
Part,
which
as
a
group
both:
1)
have
maximum
theoretical
emissions
of
91
Mg
(100
tons)
or more per calendar year of VON if no air
pollution control equipment were used,
and
2)
are not limited to less than 91 Mg
(100 tons)
of
VON emissions per calendar year in the absence of
air pollution control equipment, through
production or capacity limitations contained in a
federally enforceable construction or operating
permit
or
a
SIP
revision.
b)
If
a
plant
ceases
to
fulfill
the
criteria
of
subsection
(a),
the
requirements
of
this
Subpart
shall
continue
to
apply
to
an
emission
source
which
was
ever
subject
to
172
the control requirements of Section 219.986.
C)
No limits under this Subpart shall apply to emission
sources with emissions of VON to the atmosphere less
than
or
equal
to
2.3
Mg
(2.5
tons)
per
calendar
year
if
the total emissions from such sources not complying
with Section 219.986 does not exceed 4.5 Mg (5.0 tons)
per calendar year.
d)
For the purposes of this Subpart, an emission source
shall
be
considered
regulated
by
a
Subpart
if
it
is
subject to the limits of that Subpart.
An emission
source
is not considered regulated by a Subpart if its
emissions are below the applicability cutoff level or
if
the
source
is
covered
by
an
exemption.
e)
The
control
requirements
in
Subparts
QQ,
RB,
SS
and
TT
shall
not
apply
to
sewage
treatment
plants,
vegetable
oil processing plants, coke ovens
(including by—product
recovery
plants),
fuel
combustion
sources,
bakeries,
barge
loading
facilities,
jet
engine
test
cells,
pharmaceutical
manufacturing,
production
of
polystyrene
foam
insulation
board
(including
storage
and
extrusion
of
scrap
where
blowing
agent
is
added
to
the
polystyrene resin at the plant), production of
polystyrene foam packaging (not including storage and
extrusion
of
scrap
where
blowing
agent
is
added
to
the
polystyrene
resin
at
the
plant),
and
iron
and
steel
production.
Section
219.983
Permit
Conditions
No
person
shall
violate
any
condition
in
a
permit
when
the
condition results in exclusion of the plant or an emission source
from this Subpart.
Section
219.986
Control
Requirements
Every
owner
or
operator
of
an
emission
source
subject
to
this
Subpart shall comply with the requirements of subsection
(a),
(b)
or
(c) below.
a)
Emission capture and control equipment which achieve an
overall reduction in uncontrolled VON emissions of at
least 81 percent, or
b)
For
coating
lines,
the
daily—weighted
average
VON
content shall not exceed 0.42 kg VOM/l
(3.5 lbs
VON/gal)
of
coating
(minus
water
and
any
compounds
which
are
specifically
exempted
from
the
definition
of
VON)
as
applied
during
any
day.
Owners
and
operators
complying
with
this
Section
are
not
required
to
comply
173
with
Section
219.301,
or
c)
An
alternative
control
plan
which
has
been
approved
by
the Agency and approved by the USEPA as a SIP revision.
Section 219.987
Compliance Schedule
Every
owner or operator of
an
emissions
source
which
is
subject
to
this
Subpart
shall
comply
with
the
requirements
of
this
Subpart
on
and
after
a
date
consistent
with
Section
219.106.
Section
219.988
Testing
Any
owner
or operator of a VON emission source which is subject
to
this
Subpart
shall
demon3trate
compliance
with
Section
219.936
by
using
the
applicable
teat
methods
and
procedures
specified
in
Section
~‘~105.
~
When
in
the
opinion
of
the
Agency
it
is
necessary
to
conduct
testing
to
demonstrate
compliance
with
Section
219.986.
the
owner
or
operator
of
a
VON
emission
source
subiect
to
the
requirements
of
this
Subpart
shall,
at
his
own
expense,
conduct such tests in accordance with the appliacable test
methods
and
procedures
specified
in
Section
219.105.
b.
Nothina
in
the
Section
shall
limit
the
authority
of
the
USEPA
pursuant
to
the
Clean
Air
Act,
as
amended,
to
require
testing.
SUBPART
UtJ:
RECORDKEEPING
AND
REPORTING
FOR
NON-CTG
SOURCES
Section 219.990
Exempt Emission Sources
Upon
request
by
the
Agency,
the
owner
or
operator
of
an
emission
source
which
is
exempt
from
the
requirements
of
Subparts
PP,
QQ,
RB,
TT or Section 219.208(b)
shall submit records to the Agency
within
30
calendar
days
from
the
date
of
the
request
that
document
that
the
emission
source
is
exempt
from
those
requirements.
Section 219.991
Subject Emission Sources
a)
Any owner or operator of a VON emission source which is
subject to the requirements of Subpart PP,
QQ,
PR
or TT
and complying by the use of emission capture and
control
equipment
shall
comply
with
the
following:
1)
By
a
date
consistent
with
Section
219.106,
or
upon
initial
start-up
of
a
new
emission
source,
the
owner or operator of the subject VON emission
source
shall
perform
all
tests
and
submit
to
the
Agency and the UCEPA demonstrate to the Agency
174
that
the
subject
emission
source
will
be
in
compliance on and after a date consistent with
Section 219.106, or on and after the initial
start-up date by submitting to the Agency all
calculations
and
other
supporting
data,
including
descriptions
and
results
of
any
tests
the
owner
or
operator may have
performed.
2)
On and after a date consistent with Section
219.106,
or
on
and
after
the
initial
start-up
date, the owner or operator of a subject VON
emission
source
shall
collect
and
record
all
of
the
following
information
each
day
and
maintain
the
information
at
the
facility
for
a
period
of
three
years:
A)
Control
device
monitoring
data.
B)
A
log
of
operating
time
for
the
capture
system,
control
device,
monitoring
equipment
and the associated emission source.
C)
A
maintenance
log
for
the
capture
system,
control device and monitoring equipment
detailing all routine and non—routine
maintenance performed including dates and
duration
of
any
outages.
3)
On
and
after
a
date
consistent
with
Section
219.106,
the
owner
or
operator
of
a
subject
VON
emission
source
shall
notify
the
Agency
in
the
following
instances:
A)
Any
record
showing
a
violation
of
the
requirements of Subpart PP,
QQ,
PR
or TT
shall be reported by sending a copy of such
record to the Agency within 30 days following
the occurrence of the violation.
B)
At
least
30
calendar
days
before
changing
the
method
of
compliance
with
Subpart
PP
or
TT
from
the
use
of
capture
systems
and
control
devices to the use of complying coatings, the
owner
or
operator
shall
comply
with
all
requirements of subsection (b)(1).
Upon
changing the method of compliance with
Subpart PP or TT from the use of capture
systems and control devices to the use of
complying
coatings,
the
owner
or
operator
shall
comply
with
all
requirements
of
subsection
(b).
175
jj
j)..
When
in
the
opinion
of
the
A~encv it
is
necessary to conduct testing to demonstrate
compliance with this Subpart, the owner or
operator of a VOM emission source subiect tot
the reauirements of this Subpart shall,
at
his
own
expense,
conduct
such
tests
in
accordance with the applicable test methods
and
procedures
specified
in
Section
219.105.
jjJ.
Nothing
in
this
section
shall
limit
the
suthority of the USEPA pursuant to the Clean
Air
Act,
as
amended,
to
require
testing.
b)
Any
owner or operator of a coating line which is
subject to the requirements of Subpart PP or TT and
complying by means of the daily-weighted average VON
content
limitation
shall
comply
with
the
following:
1)
By a date consistent with Section 219.106, or upon
initial
start-up
of
a
coating
line
subject
to
Subpart
PP
or
TT,
the
owner
or
operator
of
the
subject
coating
line
shall
certify
to
the
Agency
that the coating line will be in compliance on and
after a date consistent with Section 219.106, or
on
and
after
the
initial
start-up
date.
Such
certification shall include:
A)
The
name
and
identification
number
of
each
coating
line
which
will
comply
by
means
of
the
daily-weighted
average
VON
content
limitation.
B)
The
name
and
identification
number
of
each
coating
as
applied
on
each
coating
line.
C)
The
weight
of
VON
per
volume
and
the
volume
of each coating
(minus water and any
compounds which are specifically exempted
from the definition of VON)
as applied each
day on each coating line.
D)
The instrument or method by which the owner
or operator will accurately measure or
calculate the volume of each coating as
applied
each
day
on
each
coating
line.
E)
The
method
by
which
the
owner
or
operator
will
create
and
maintain
records
each
day
as
required in subsection
(b)(2).
F)
An example of the format in which the records
required in subsection
(b) (2) will be kept.
176
2)
On and after a date consistent with Section
219.106, or on and after the initial start-up
date, the owner or operator of a subject coating
line shall collect and record all of the following
information each day for each coating line and
maintain the information at the facility for a
period of three years:
A)
The name and identification number of each
coating as applied on each coating line.
B)
The weight of VON per volume and the volume
of
each
coating
(minus
water
and
any
compounds
which
are
specifically
exempted
from the definition of VON) as applied each
day
on
each
coating
line.
C)
The daily-weighted average VON content of all
coatings as applied on each coating line as
defined in Section 219.104.
3)
On
and
after
a
date
consistent
with
Section
219.106, the owner or operator of a subject
coating line shall notify the Agency in the
following instances:
A)
Any record showing violation of the
requirements
of
Subpart
PP
or
TT
shall
be
reported by sending a copy of such record to
the
Agency
within
30
days
following
the
occurrence of the violation.
B)
At
least
30
calendar
days
before
changing
the
method
of
compliance
with
Subpart
PP
or
TT
from
the
use
of
complying
coatings
to
the
use
capture
systems
and
control
devices,
the
owner or operator shall comply with all
requirements of subsection
(a) (1).
Upon
changing the method of compliance with
Subpart PP or TT from the use of complying
coatings to the use capture systems and
control devices, the owner or operator shall
comply with all requirements of subsection
(a).
c)
Any
owner or operator of a VON emission source which is
subject to the requirements of Subpart PP,
QQ,
RB
or TT
and complying by means of an alternative control plan
which
has
been
approved
by
the
Agency
and
approved
by
the IJSEPA as a SIP revision shall comply with the
recordkeeping
and
reporting
requirements
specified
in
177
the alternative control plan.
178
appendix A
List of Chemicals Defining Synthetic Organic
Chemical and Polymer Manufacturing
CAS No.
°
Chemical
105—57—7
Acetal
75-07—0
Acetaldehyde
107—89—1
Acetaldol
60-35—5
Acetamide
103—84—4
Acetanilide
64-19-7
Acetic acid
108-24-7
Acetic anhydride
67—64—1
Acetone
75-86-5
Acetone cyanohydrin
75—05—8
Acetonitrile
98-86-2
Acetophenone
75—36-5
Acetyl
chloride
74-86-2
Acetylene
107—02—8
Acrolein
79-06-1
Acrylamide
79-10-7
Acrylic
acid
&
esters
107—13—1
Acrylonitrile
124—04—9
Adipic
acid
111—69—3
Adiponitrile
(b)
Alkyl
naphthalenes
107—18—6
Allyl alcohol
107—05—1
Allyl
chloride
1321—11—5
Aninobenzoic
acid
111—41-1
Aminoethylethanolamine
123—30—8
p—aminophenol
628—63-7
Amyl
acetates
123—92—2
~1l~4l~Oc
Amyl
alcohols
110—58—7
Amyl
amine
543—59-9
Amyl
chloride
llO~68~7c
Amyl
mercaptans
1322—06-1
Amyl
phenol
62—53—3
Aniline
142—04-1
Aniline hydrochloride
29191—52—4
Anisidine
100—66—3
Anisole
118—92—3
Anthranilic acid
84-65-1
Anthraquinone
100-52—7
Benzaldehyde
55-21—0
Benzamide
71-43-2
Benzene
98-48—6
Benzenedisulfonic acid
98-11-3
Benzenesulfonic
acid
134—81—6
Benzil
76-93—7
Benzilic acid
65-85—0
Benzoic
acid
119—53 —9
Benzoin
179
100-47—0
Benzonitrile
119-61—9
Benzophenone
98-07-7
Benzotrichloride
‘98-88-4
Benzoyl chloride
100—51—6
Benzyl
alcohol
100—46—9
Benzylamine
120—51—4
Benzyl benzoate
100—44—7
Benzyl chloride
98-87-3
Benzyl dichloride
92-52-4
Biphenyl
80—05-7
Bisphenol A
10-86-1
Bromobenzene
27497-51—4
Bromonaphthalene
106—99—0
Butadiene
106—98—9
l—butene
123—86—4
n—butyl
acetate
141-32-2
n-butyl
acrylate
71—36-3
n-butyl
alcohol
78—92—2
s—butyl
alcohol
75—65—0
t—butyl
alcohol
109-73-9
n-butylamine
13952-84—6
s—butylamine
75-64-9
t-butylamine
98-73-7
p-tert-butyl
benzoic
acid
107—88—0
1,3—butylene
glycol
123-72-8
n-butyraldehyde
107-92-6
Butyric acid
106-31-0
Butyric
anhydride
109-74-0
Butyronitrile
105—60—2
Caprolactam
75-1-50
Carbon
disulfide
558-13-4
Carbon
tetrabromide
55-23-5
Carbon tetrachioride
9004—35—7
Cellulose acetate
79—11-8
Chloroacetic acid
108—42—9
m-chloroaniline
95-51-2
o-chloroaniline
106—47-8
p—chloroaniline
35913—09—8
Chlorobenzaldehyde
108-90-7
Chlorobenzene
118-91-2,
Chlorobenzoic acid
535—80—8,
74—11—3c
2136—81—4,
Chlorobenzotrichloride
2136—89—2,
52l6~2S~l~
1321-03—5
Chlorobenzoyl
chloride
75-45-6
Chiorodifluoroethane
25497—29—4
Chlorodifluoromethane
67—66—3
Chloroform
25586-43-0
Chloronaphthalene
88—73—3
o-chloronitrobenzene
180
100-00—5
p-chloronitrobenzene
25167—80—0
Chlorophenols
126-99—8
Chloroprene
7790—94—5
Chlorosulfonic acid
108-41-8
m-chlorotoluene
95-49-8
o-chlorotoluene
106—43-4
p-chlorotoluene
75—72—9
Chlorotrifluoromethane
108—39-4
m—cresol
95—48—7
o—cresol
106—44-5
p-cresol
1319—77—3
Mixed cresols
1319-77—3
Cresylic acid
4170-30-0
Crotonaldehyde
3724—65—0
Crontonic acid
98—82—8
Cumene
80-15-9
Cumene hydroperoxide
372-09-8
Cyanoacetic acid
506—77-4
Cyanogen
chloride
108-80-5
Cyanuric
acid
108-77-0
Cyanuric
chloride
110-82-7
Cyclohexane
108—93—0
Cyclohexanol
108-94—1
Cyclohexanone
110-83—8
Cyclohexene
108-91—8
Cyclohexylamine
111—78—4
Cyclooctadiene
112—30—1
Decanol
123-42—2
Diacetone alcohol
27576—04-1
Diaminobenzoic
acid
95—76—1,
Dichioroaniline
95—82—9,
554—00—7,
608—27—5,
608—31—1,
626—43—7,
27134—27—6,
573l1_92_9c
541-73-1
m-dichlorobenzene
95-50-1
o-dichlorobenzene
106-46-7
p-dichlorobenzene
75-71-8
Dichlorodifluoromethane
111—44-4
Dichloroethyl
ether
107-06-2
1,2-dichloroethane
(EDC)
96-23-1
Dichlorohydrin
26952-23-8
Dichloropropene
101-83-7
Dicyclohexylamine
109-89-7
Diethylamine
111—46—6
Diethylene glycol
112-36-7
Diethylene
glycol
diethyl
ether
111-96-6
Diethylene
glycol
dimethyl
ether
112-34-5
Diethylene
glycol
monobutyl
ether
181
124-17-7
Diethylene glycol inononbutyl ether
acetate
111—90-0
Diethylene
glycol
monoethyl
ether
112—15—2
Diethylene
glycol
monoethyl
ether
acetate
111—77-3
Diethylene glycol monomethyl ether
64-67-5
Diethyl sulfate
75—37—6
Difluoroethane
25167—70—8
Diisobutylene
26761-40—0
Diisodecyl phthalate
27554—26—3
Diisooctyl phthalate
674—82-8
Diketene
124—40—3
Dimethylamine
12 1—69—7
N, N—dimethylaniline
115—10-6
N,N-dimethyl ether
68—12-2
N, N-dimethylformamide
57-14-7
Dimethyihydrazine
77—78-1
Dimethyl
sulfate
75—18-3
Dimethyl
sulfide
67—68-5
Dimethyl sulfoxide
120-61-6
Dimethyl terephthalate
99—34-3
3,5—dinitrobenzoic acid
51—28—5
Dinitrophenol
Dinitrotoluene
123—91—1
Dioxane
646—06—0
Dioxilane
122—39—4
Diphenylamine
101-84-4
Diphenyl
oxide
102-08-9
Diphenyl thiourea
25265-71-8
Dipropylene glycol
25378-22—7
Dodecene
28675-17—4
Dodecylaniline
27193-86-8
Dodecylphenol
106-89-8
Epichlorohydrin
64—17—5
Ethanol
Ethanolamines
141—78—6
Ethyl acetate
14 1—97—9
Ethyl
acetoacetate
140—88—5
Ethyl acrylate
75-04-7
Ethylamine
100—41-4
Ethylbenzene
74-96-4
Ethyl bromide
9004—57—3
Ethylcellulose
75—00-3
Ethyl
chloride
105-39-5
Ethyl chloroacetate
105—56-6
Ethylcyanoacetate
74—85-1
Ethylene
96-49-1
Ethylene carbonate
107-07—3
Ethylene
chlorohydrin
107—15—3
Ethylenediamine
106—93—4
Ethylene dibromide
107—21-1
Ethylene
glycol
111-55-7
Ethylene
glycol
diacetate
182
110-71-4
Ethylene
glycol
dimethyl
ether
111-76-2
Ethylene glycol monobutyl ether
112-07—2
Ethylene glycol monobutyl ether acetate
110-80—5
Ethylene glycol monoethyl ether
111-15—9
Ethylene
glycol
monoethyl
ether
acetate
109-86-4
Ethylene glycol monoethyl ether
110-49-6
Ethylene glycol monomethyl ether acetate
122-99-6
Ethylene
glycol
nionophenyl
ether
2807-30-9
Ethylene glycol monopropyl ether
75—21-8
Ethylene oxide
60-29-7
Ethyl ether
104-76-7
2—ethylhexanol
122—51—0
Ethyl orthoformate
95-92-1
Ethyl oxalate
41892—71-1
Ethyl
sodium
oxaloacetate
50—00-0
Formaldehyde
75—12-7
Formamide
64—18—6
Formic
acid
110—17—8
Fuinaric
acid
98—01—1
Furfural
56-81-5
Glycerol
(Synthetic)
26545-73—7
Glycerol dichlorohydrin
25791-96-2
Glycerol triether
56—40—6
Glycine
107—22—2
Glyoxal
118-74-1
Hexachlorobenzene
67—72—1
Hexachloroethane
36653—82—4
Hexadecyl alcohol
124-09—4
Hexamethylenediamine
629-11—8
Hexamethylene glycol
100-97-0
Hexamethylenetetramine
74-90-8
Hydrogen cyanide
123-31-9
Hydroquinone
99-96-7
p-hydroxybenzoic acid
26760—64—5
Isoamylene
78—83-1
Isobutanol
110-19—0
Isobutyl
acetate
115-11-7
Isobutylene
78-84-2
Isobutyraldehyde
79-31-2
Isobutyric acid
25339—17—7
Isodecanol
26952-21—6
Isooctyl alcohol
78-78-4
Isopentane
78-59-1
Isophorone
121-91-5
Isophthalic acid
78-79-5
Isoprene
67-63-0
Isopropanol
108-21-4
Isopropyl acetate
75-31—0
Isopropylamine
75-29—6
Isopropyl chloride
25168-06—3
Isopropyiphenol
463—51-4
Ketene
183
(b)
Linear alkyl sulfonate*
123—01-3
Linear alkylbenzene
110—16—7
Naleic acid
108-31—6
Maleic anhydride
6915—15—7
Nalic acid
141—79—7
Mesityl oxide
121—47-1
Netanilic acid
79—41—4
Nethacrylic acid
563—47-3
Methallyl chloride
67—56—1
Methanol
79—20-9
Methyl acetate
105—45—3
Methyl acetoacetate
74—89-5
Nethylamine
100—61—8
n-methylaniline
74-83-9
Methyl
bromide
37365-71—2
Methyl butynol
74-87-3
Methyl chloride
108-87-2
Methyl
cyclohexane
1331-22-2
Methyl cyclohexanone
75-09-2
Methylene chloride
101-77-9
Nethylene
dianiline
101-68-8
Nethylene diphenyl diisocyanate
78-93-3
Methyl ethyl ketone
107-31—3
Methyl
forinate
108-11—2
Methyl isobutyl carbinol
108-10-1
Methyl isobutyl ketone
80-62-6
Methyl methacrylate
77-75-8
Methylpentynol
98-83-9
B—methylstyrene
110—91—8
Norpholine
85-47—2
a—naphthalene sulfonic acid
120-18—3
B—naphthalene
sulfonic
acid
90—15—3
a—naphthol
135-19-3
B—naphthol
75-98-9
Neopentanoic acid
88—74-4
o-nitroaniline
100-01—6
p-nitroaniline
91—23—6
o—nitroanisole
100-17—4
p-nitroanisole
98—95-3
Nitrobenzene
Nitrobenzoic acid
(0,
ni
&
p)
79-24—3
Nitroethane
75-52-5
Nitromethane
88-75—5
Nitrophenol
25322—01-4
Nitropropane
1321-12—6
Nitrotoluene
27215—95—8
Nonene
25154-52—3
Nonylphenol
27193—28-8
Octylphenol
123-63-7
Paraldehyde
115-77—5
Pentaerythritol
109-66-0
n-pentane
184
109-67-1
l—pentene
127-18-4
Perchloroethylene
594-42-3
Perchloromethyl mercaptan
94-70-2
o-phenetidine
156-43—4
p-phenetidine
108—95—2
Phenol
98—67—9,
Phenolsulfonic acids
585—38—6,
609—46—1,
l33—39—.7c
91-40-7
Phenyl anthranilic acid
(b)
Phenylenediamine
75-44-5
Phosgene
85-44-9
Phthalic anhydride
85-41-6
Phthalimide
108—99—6
b—picoline
110—85—0
Piperazine
9003-29-6,
Polybutenes
25322-68-3
Polyethylene glycol
25322-69-4
Polypropylene glycol
123-38-6
Propionaldehyde
79—09-4
Propionic acid
71-23—8
n-propyl alcohol
107-10-8
Propylamine
540-54-5
Propyl
chloride
115-07-1
Propylene
127-00-4
Propylene chlorohydrin
78—87—5
Propylene dichloride
57—55—6
Propylene glycol
75-56-9
Propylene
oxide
110—86—1
Pyridine
106—51—4
Quinone
108—46—3
Resorcinol
27138—57—4
Resorcylic acid
69—72—7
Salicylic acid
127-09—3
Sodium acetate
532-32-1
Sodium benzoate
9004-32-4
Sodium carboxymethyl cellulose
3926-62-3
Sodium chloroacetate
141-53-7
Sodium formate
139-02-6
Sodium phenate
110-44-1
Sorbic acid
100-42-5
Styrene
110—15-6
Succinic acid
110—61—2
Succinitrile
121—57—3
Sulfanilic acid
126—33—0
Sulfolane
1401-55—4
Tannic acid
100—21-0
Terephthalic
acid
79345C
Tetrachloroethanes
117-08-8
Tetrachlorophthalic anhydride
185
78-00-2
Tetraethyllead
119—64—2
Tetrahydronaphthalene
85-43—8
Tetrahydrophthalic
anhydride
75-74—1
Tetramethyllead
110-60—1
Tetramethylenediamine
110—18—9
Tetramethylethylenediamine
108—88—3
Toluene
95—80—7
Toluene-2
,
4—diamine
584—84—9
Toluene-2, 4—diisocyanate
26471—62-5
Toluene diisocyanates (mixture)
1333—07—9
Toluene sulfonamide
1O4~l5~4c
Toluenesulfonic
acids
98—59—9
Toluene sulfonyl chloride
26915—12—8
Toluidines
87—61—6,
Trichlorobenzenes
108—70—3,
71—55—6
1,1,l—trichloroethane
79—00—5
1,1,2—trichloroethane
79-01-6
Trichloroethylene
75—69-4
Trichlorofluoromethane
9 6—18—4
1,2,
3—trichloropropane
76—13—1
l,l,2—trichloro—l,2,2—trifluoroethane
121-44—8
Triethylamine
112—27—6
Triethylene glycol
112—49-2
Triethylene glycoldimethyl
ether
7756-94—7
Triisobutylene
75-50—3
Trimethylamine
57—13—6
Urea
108—05-4
Vinyl acetate
75—01-4
Vinyl chloride
75-35-4
Vinylidene
chloride
25013—15—4
Vinyl toluene
1330—20—7
Xylenes
(mixed)
95—47—6
o—xylene
106—42—3
p—xylene
1300—71—6
Xylenol
1300—73—8
Xylidine
(b)
methyl
tert-butyl
ether
9002—88-4
Polyethylene
(b)
Polypropylene
9009-53-6
Polystyrene
a) CAS numbers refer to the Chemical Abstracts Registery numbers
assigned to specific chemicals,
isomers or mixtures of
chemicals.
Some isomers or mixtures that are covered by the
standards do not have CAS numbers assigned to them.
The
standards apply to all of the chemicals listed, whether CAS
numbers have been assigned or not.
b) No CAS number(s) have been assigned to this chemical, to its
isomers,
or mixtures containing these chemicals.
186
c)
CAS
numbers
for
some
of
the
isomers
are
listed:
the
standards
apply to all of the isomers and mixtures, even if CAS
numbers
have not been assigned.
187
Appendix B
VON Measurement Techniques for Capture Efficiency
Procedure G.l
-
Captured VOC Emissions
1.
INTRODUCTION
1.1
Applicability.
This procedure is applicable for determining
the volatile organic compounds
(VOC)
content of captured gas
streams.
It is intended to be used as a segment in the
development of liquid/gas or gas/gas protocols for determining
VOC capture efficiency
(CE)
for surface coating and printing
operations.
The procedure may not be acceptable in certain
site—specific
situations,
e.g.,
when:
(1)
direct fired heaters or
other circumstances affect the quantity of VOC at the control
device
inlet; and
(2) particulate organic aerosols are formed in
the process and are present in the captured emissions.
1.2
Principle.
The amount of VOC captured
(G)
is calculated as
the sum of the products of the VOC content
(Ce;),
the flow rate
and the sample time
(Ta)
from each captured emissions
point-
1.3
Estimated Measurement Uncertainty.
The measurement
uncertainties
are estimated for each captured or fugitive
emissions
point
as
follows:
=
5.5 percent and
C6~
=
~5~o
percent.
Based
on
these
numbers,
the
probable
uncertainty for G is estimated at about ±7•4percent.
1.4
Sampling
Requirements.
A
capture
efficiency
test
shall
consist
of
at
least
three sampling runs.
The sampling time for
each run should be at least
8 hours, unless otherwise approved.
1.5
Notes.
Because
this
procedure
is
often
applied
in
highly
explosive areas,
caution and care should be exercised in choosing
appropriate equipment and installing and using the equipment.
Mention of trade names or company products does not constitute
endorsement.
All
gas
concentrations
(percent, ppm) are by
volume, unless otherwise noted.
2.
APPARATUS
AND REAGENTS
2.1
Gas VOC Concentration.
A schematic of the measurement
system
is
shown
in Figure
1.
The main components are described
below:
2.1.1
Sample
Probe.
Stainless
steel,
or
equivalent.
The probe
shall
be
heated
to
prevent
VOC
condensation.
2.1.2
Calibration Valve Assembly.
Three-way valve
assembly
at
the outlet of sample probe to direct the zero and calibration
gases to the analyzer.
Other methods, such as quick—connect
lines, to route calibration gases to the outlet of the sample
188
probe
are
acceptable.
2.1.3
Sample Line.
Stainless steel or Teflon tubing to
transport
the
sample
gas to the analyzer.
The sample line must
be heated to prevent condensation.
2.1.4
Sample
Pump.
A leak-free pump, to pull the sample gas
through
the
system
at
a flow rate sufficient to minimize the
response time of the measurement system.
The components of the
pump that contact the gas stream shall be constructed of
stainless
steel
or
Teflon.
The sample pump must be heated to
prevent condensation.
2.1.5
Sample Flow Rate Control.
A sample flow rate control
valve and rotameter, or equivalent,
to maintain a constant
sampling rate within 10 percent.
The flow rate control valve and
rotameter must be heated to prevent condensation.
A control
valve may also be located on the sample pump bypass loop to
assist in controlling the sample pressure and flow rate.
2.1.6
Sample Gas Manifold.
Capable of diverting a portion of
the sample gas stream to the flame ionization analyzer (FIA), and
the remainder to the bypass discharge vent.
The manifold
components shall be constructed of stainless steel or Teflon.
If
captured or fugitive emissions are to be measured at multiple
locations, the measurement system shall be designed to use
separate sampling probes, lines,
and pumps for each measurement
location and a common sample gas manifold and FIA.
The sample
gas manifold and connecting lines to the FIA must be heated to
prevent condensation.
2.1.7
Organic Concentration Analyzer.
An FIA with a span value
of 1.5 times the expected concentration as propane; however,
other span values may be used if it can be demonstrated that they
would
provide
more
accurate
measurements.
The
system
shall
be
capable of meeting or exceeding the following specifications:
2.1.7.1
Zero Drift.
Less than ±3.0percent of the span value.
2.1.7.2
Calibration Drift.
Less than ±3.0percent of the span
value.
2.1.7.3
Calibration Error.
Less than ±5.0percent of the
calibration gas value.
2.1.7.4
Response Time.
Less than 30 seconds.
2.1.8
Integrator/Data Acquisition
System.
An
analog
or
digital
device or computerized data acquisition system used to integrate
the FIA response or compute the average response and record
measurement data.
The minimum data sampling frequency for
computing average or integrated values is one measurement value
189
every
5
seconds.
The
device
shall
be
capable
of
recording
average
values
at
least
once
per
minute.
2.1.9
Calibration
and
Other
Gases.
Gases
used
for
calibration,
fuel, and combustion air
(if required) are contained in
compressed gas cylinders.
All calibration gases shall be
traceable to NIST standards and shall be certified by the
manufacturer to ±1percent of the tag value.
Additionally, the
manufacturer of the cylinder should provide a recommended shelf
life for each calibration gas cylinder over which the
concentration does not change more than ±2percent from the
certified value.
For calibration gas values not generally
available,
alternative methods for preparing calibration gas
mixtures, such as dilution systems, may be used with prior
approval.
2.1.9.1
Fuel.
A 40 percent H2/60 percent He or 40 percent H2/60
percent N2 gas mixture is recommended to avoid an oxygen
synergism effect that reportedly occurs when oxygen concentration
varies significantly from a mean value.
2.1.9.2
Carrier Gas.
High purity air with less than 1 ppm of
organic ma~terial(as propane or carbon equivalent)
or less than
0.1 percent of the span value, whichever is greater.
2.1.9.3
FIA Linearity Calibration Gases.
Low-, mid-, and
high—range gas mixture standards with nominal propane
concentrations of 20-30,
45-55, and 70-80 percent of the span
value
in
air,
respectively.
Other
calibration
values
and
other
span
values
may
be
used
if it can be shown that more accurate
measurements would be achieved.
2.1.10
Particulate Filter.
An in-stack or an out—of-stack glass
fiber filter is recommended if exhaust gas particulate loading is
significant.
An out-of-stack filter must be heated to prevent
any condensation unless
it can be demonstrated that no
condensation occurs.
2.2
Captured Emissions Volumetric Flow Rate.
2.2.1
Method
2
or
2A Apparatus.
For
determining
volumetric
flow
rate.
2.2.2
Method
3
Apparatus
and
Reagents.
For
determining
molecular weight of the gas stream.
An estimate of the molecular
weight of the gas stream may be used if it can be justified.
2.2.3
Method
4 Apparatus and Reagents.
For determining moisture
content,
if necessary.
3.
DETERMINATION OF VOLUMETRIC FLOW RATE OF CAPTURED EMISSIONS
190
3.1
Locate all points where emissions are captured from the
affected facility.
Using Method 1, determine the sampling
points.
Be sure to check each site for cyclonic or swirling
flow.
3.2
Measure the velocity at each sampling site at least once
every
hour during each sampling run using Method
2 or 2A.
4.
DETERMINATION OF VOC CONTENT OF CAPTURED EMISSIONS
4.1
Analysis Duration.
Measure the VOC responses at each
captured emissions point during the entire test run or,
if
applicable,
while the process is operating.
If there are
multiple captured emission locations, design a sampling system to
allow
a
single
FIA
to
be
used
to
determine
the
VOC
responses
at
all sampling locations.
4.2
Gas VOC Concentration.
4.2.1
Assemble the sample train as shown in Figure
1.
~Calibrate
the FIA according to the procedure in Section 5.1.
191
4.2.2
Conduct
a
system
check
according
to
the
procedure
in
Section 5.3.
4.2.3
Install the sample probe so that the probe is centrally
located in the stack,
pipe, or duct, and is sealed tightly at the
stack port connection.
4.2.4
Inject zero gas at the calibration valve assembly.
Allow
the measurement system response to reach zero.
Measure the
system response time as the time required for the system to reach
the effluent concentration after the calibration valve has been
returned to the effluent sampling position.
4.2.5
Conduct a system check before and a system drift check
after each sampling run according to the procedures in Sections
5.2 and 5.3.
If the drift check following a run indicates
unacceptable performance, the run
is not valid.
The tester may
elect to
perform
system
drift
checks
during
the
run
not to exceed
one drift check per hour.
4.2.6
Verify that the sample lines,
filter, and pump
temperatures are 120±5°C.
4.2.7
Begin sampling at the start of the test period and
continue to sample during the entire run.
Record the starting
and ending times and any required process information as
appropriate.
If multiple captured emission locations are sampled
using
a
single
FIA,
sample
at each location for the same amount
of time (e.g.,
2 minutes) and continue to switch from one
location
to
another
for
the
entire
test run.
Be sure that total
sampling
time
at
each
location
is
the
same
at
the
end
of the test
run.
Collect at least
4 separate measurements from each sample
point during each hour of testing.
Disregard the measurements at
each sampling location until two times the response time of the
measurement system has elapsed.
Continue sampling for at least. 1
minute and record the concentration measurements.
4.3
Background Concentration.
4.3.1
Locate all
NDO’s
of the TTE.
A sampling point shall be
centrally located outside of the TTE at.4 equivalent diameters
from each
NDO,
ifpossible.
If
there
are
more
than
6
NDO’s,
choose 6 sampling points evenly spaced among the NDO’s.
4.3.2
Assemble the sample train as shown in Figure 2.
Calibrate
the FIA and conduct a system check according to the procedures in
Sections 5.1 and 5.3.
NOTE:
This sample
train
shall
be
a
separate sampling train from the one to measure the captured
emissions.
4.3.3
Position the probe at the sampling location.
192
4.3.4
Determine the response time, conduct the system check and
sample according to the procedures described in Sections 4.2.4 to
4.2.7.
4.4
Alternative Procedure.
The direct interface sampling and
analysis
procedure
described
in
Section
7.2
of
Method
18
may
be
used to determine the gas VOC concentration.
The system must be
designed to collect and analyze at least one sample every 10
minutes.
5.
CALIBRATION
AND
QUALITY
ASSURANCE
5.1
FIA Calibration and Linearity Check.
Make necessary
adjustments to the air and fuel supplies for the FIA and ignite
the burner.
Allow the FIA to warm up for the period recommended
by the manufacturer.
Inject a calibration gas into the
measurement system and adjust the back—pressure regulator to the
value required to achieve the flow rates specified by the
manufacturer.
Inject the zero- and the high—range calibration
gases and adjust the analyzer calibration to provide the proper
responses.
Inject
the
low-
and
mid-range
gases
and record the
responses of the
measurement
system.
The
calibration
and
linearity of the system are acceptable if the responses for all
four gases are within
5 percent of the respective gas values.
If
the performance of the system is not
acceptable,
repair
or
adjust
the system and repeat the linearity check.
Conduct a calibration
and linearity check after assembling the analysis system and
after a major change is made to the system.
5.2
Systems
Drift
Checks.
Select
the calibration gas that most
closely approximates the concentration of the captured emissions
for conducting the drift checks.
Introduce the zero and
calibration
gas
at the calibration valve assembly and verify that
the
appropriate
gas
flow
rate
and pressure are present at the
FTh.
Record
the
measurement
system
responses
to the zero and
calibration
gases.
The performance of the system is
acceptable
if
the
difference
between the drift check measurement and the
value obtained in Section 5.1 is less than
3 percent of the span
value.
Conduct
the
system
drift
checks
at
the
end
of
each
run.
5.3
System Check.
Inject the high range calibration gas at the
inlet
of
the
sampling
probe and record the response.
The
performance of the system is acceptable
if
the
measurement
system
response is
within
5 percent of the value obtained in Section 5.1
for the high range calibration gas.
Conduct a system check
before and after each test run.
5.4
Analysis Audit.
Immediately before each test analyze an
audit
cylinder
as
described
in
Section
5.2.
The
analysis
audit
must agree with the audit cylinder concentration within 10
percent.
193
6.
NOMENCLATURE
=
area of NDO i,
ft2.
=
total area of all
NDO’s
in the enclosure,
ft2.
=
corrected average VOC concentration of background
emissions at point i, ppm propane.
CB
=
average background concentration, ppm propane.
CGJ
=
corrected average VOC concentration of captured
emissions at point
j,
ppm propane.
=
average measured concentration for the drift check
calibration gas, ppm propane.
CDO
=
average system drift check concentration for zero
concentration gas, ppm propane.
CH
=
actual concentration of the drift check calibration
gas, ppm propane.
C1
=
uncorrected average background VOC concentration
measured at point
i, ppm propane.
C1
=
uncorrected
average VOC concentration measured at point
j,
ppm propane.
G
=
total VOC content of captured emissions,
kg.
K1
=
1.830 x 10~kg/ (m3—ppm).
n
=
number
of
measurement
points.
Q~
=
average
effluent
volumetric
flow
rate
corrected
to
standard conditions at captured emissions point
j,
m3/min.
=
total duration of captured emissions sampling run, mm.
7.
CALCULATIONS
7.1
Total VOC Captured Emissions.
G
=
•~
(CGJ
-
CB) ~GJTc K1
Eq.
1
7.2
VOC Concentration of the Captured Emissions at Point
j.
194
=
(C1
-
_________
Eq.
2
-
CDO
7.3
Background VOC Concentration at Point
i.
CBI
=
(C1
—
CD3)
C11
Eq.
3
—
CDO
7.4
Average Background Concentration.
n
E
C.A.
f-i
Bi
i
Eq.
4
nAN
NOTE:
If the concentration at each point is within 20 percent of
the average concentration of all points, the terms
“A1” and “A,~”
may be deleted from Equation 4.
195
Procedure G.2
-
Captured
VOC Emissions
(Dilution Technique)
1. INTRODUCTION
1.1
Applicability.
This procedure is applicable for determining
the volatile organic compounds
(VOC) content
of captured gas
streams.
It is intended to be used as a segment in the
development
of
a
gas/gas
protocol
in
which
fugitive
emissions
are
measured for determining VOC capture efficiency
(CE) for surface
coating
and
printing
operations.
A
dilution
system
is
used
to
reduce the VOC concentration of the captured emission to about
the same concentration as the fugitive emissions.
The procedure
may
not
be
acceptable
in
certain
site-specific
situations,
e.g.,
when:
(1)
direct
fired
heaters
or
other circumstances affect the
quantity
of
VOC
at
the
control device inlet; and
(2) particulate
organic aerosols are formed in the process and are present in the
captured emissions.
1.2
Principle.
The
amount
of
VOC
captured
(G)
is
calculated
as
the sum of the products of the VOC content
(CGJ), the flow rate
and the sampling time
(Tc) from each captured emissions
point.
1.3
Estimated Measurement Uncertainty.
The measurement
uncertainties are estimated for each captured or fugitive
emissions point as follows:
Q31
=
±5.5percent and
C31
=
percent.
Based on these numbers, the probable uncertainty for G
is estimated at about ±7~4
percent.
1.4
Sampling Requirements.
A capture efficiency
test
shall
consist of at least three sampling runs.
The sampling time for
each run should be at least
8 hours, unless otherwise approved.
1.5
Notes.
Because this procedure is often applied in highly
explosive
areas,
caution
ancL care should be exercised in choosing
appropriate equipment and installing and using the equipment.
Mention
of
trade
names
or company products does not constitute
endorsement.
All gas concentrations (percent, ppm) are by
volume,
unless
otherwise
noted.
2.
APPARATUS
AND
REAGENTS
2.1
Gas VOC Concentration.
A schematic of the measurement
system is shown in Figure
1.
The main components are described
below:
2.1.1
Dilution System.
A Kipp in—stack dilution probe and
controller or similar device may be used.
The dilution rate may
be changed by substituting different critical orifices or
adjustments of the aspirator supply pressure.
The dilution
196
system shall be heated to prevent
VOC
condensation.
Note:
An
out—of—stack dilution device may be used.
2.1.2
Calibration Valve Assembly.
Three-way valve assembly at
the outlet of sample probe to direct the zero and calibration
gases to the analyzer. Other methods, such as quick—connect
lines, to route calibration gases to the outlet of the sample
probe are acceptable.
2.1.3
Sample Line.
Stainless steel or Teflon tubing to
transport the sample gas to the analyzer.
The sample line must
be heated to prevent condensation.
2.1.4
Sample Pump.
A leak-free pump,
to pull the sample gas
through the system at a flow rate sufficient to minimize the
response time of the measurement system.
The components of the
pump that contact the gas stream shall be constructed of
stainless steel or Teflon.
The sample pump must be heated to
prevent
condensation.
2.1.5
Sample Flow Rate Control.
A sample flow rate control
valve and rotameter,
or equivalent, to maintain a constant
sampling rate within 10 percent.
The flow control valve and
rotameter must be heated to prevent condensation.
A control
valve may also be located on the sample pump. bypass loop to
assist in controlling the sample pressure and flow rate.
2.1.6
Sample Gas Manifold.
Capable of diverting a portion of
the sample gas stream to the flame ionization analyzer (FIA),
and
the remainder to the bypass discharge vent.
The manifold
components shall be constructed of stainless steel or Teflon.
If
captured or fugitive emissions are to be measured at multiple
locations,
the measurement system shall be designed to use
separate sampling probes,
lines, and pumps for each measurement
location and
a common sample gas manifold and FIA.
The sample
gas
manifold
and
connecting
lines
to the FIA must be heated to
prevent
condensation.
2.1.7
Organic Concentration Analyzer.
An FIA with a span value
of 1.5 times the expected concentration as propane; however,
other span values may be used if it can be demonstrated that they
would provide more accurate measurements.
The system shall be
capable of meeting or exceeding the following specifications:
2.1.7.1
Zero Drift.
Less than ±3.0percent of the span value.
2.1.7.2
Calibration Drift.
Less
than ±3•Qpercent of the span
value.
2.1.7.3
Calibration Error.
Less than ±5.0percent of the
calibration gas value.
197
2.1.7.4
Response Time.
Less than
30
seconds.
2.1.8
Integrator/Data
Acquisition
System.
An
analog
or
digital
device or computerized data acquisition system used to integrate
the FIA response or compute the average response and record
measurement data.
The minimum data sampling frequency for
computing average or integrated values is one measurement value
every 5 seconds.
The device shall be capable of recording
average
values
at
least
once
per
minute.
2.1.9
Calibration
and
Other
Gases.
Gases
used
for
calibration,
fuel,
and
combustion
air
(if
required)
are
contained
in
compressed gas cylinders.
All calibration gases shall be
traceable to NIST standards and shall be certified by the
manufacturer
to
±1percent
of the tag value.
Additionally, the
manufacturer of the cylinder should provide a recommended shelf
life for each calibration gas cylinder over which the
concentration does not change more than ±2percent from the
certified
value.
For
calibration
gas
values not generally
available,
alternative methods for preparing calibration gas
mixtures, such as dilution systems, may be used with prior
approval.
2.1.9.1
Fuel.
A 40 percent 112/60 percent Re or
40
percent
112/60
percent
N2 gas mixture is recommended to avoid an oxygen
synergism effect that reportedly occurs when oxygen concentration
varies significantly from a mean value.
2.1.9.2
Carrier Gas and Dilution Air Supply.
High purity air
with less than 1 ppm of organic material
(as propane or carbon
equivalent)
or less than 0.1 percent of the span value, whichever
is greater.
2.1.9.3
FIA
Linearity
Calibration
Gases.
Low-,
mid—,
and
high—range gas mixture standards with nominal propane
concentrations of 20-30,
45-55, and 70-80 percent of the span
value in air, respectively.
Other calibration values and other
span values may be used if it can be shown that more accurate
measurements would be achieved.
2.1.9.4
Dilution Check Gas.
Gas mixture standard containing
propane in air, approximately half the span value after dilution.
2.1.10
Particulate Filter.
An in-stack or an out—of—stack glass
fiber
filter
is recommended if exhaust gas particulate loading is
significant.
An
out-of—stack filter must be heated to prevent
any condensation
unless it can be demonstrated that no condensation occurs.
2.2
Captured Emissions Volumetric Flow Rate.
2.2.1
Method
2 or 2A Apparatus.
For determining volumetric flow
198
rate.
2.2.2
Method
3 Apparatus and Reagents.
For determining
molecular weight of the gas stream.
An estimate of the molecular
weight of the gas stream may be used if it can be justified.
2.2.3
Method
4 Apparatus and Reagents.
For determining moisture
content,
if necessary.
3.
DETERMINATION OF VOLUMETRIC FLOW RATE OF CAPTURED EMISSIONS
3.1
Locate all points where emissions are captured from the
affected facility. Using Method
1, determine the sampling points.
Be sure to check each site for cyclonic or swirling flow.
3.2
Measure the velocity at each sampling site at least once
every hour during each sampling run using Method
2 or 2A.
4.
DETERMINATION OF VOC CONTENT OF CAPTURED EMISSIONS
4.1
Analysis Duration.
Measure the VOC responses at each
captured emissions point during the entire test run or,
if
applicable, while the process is operating.
If there are a
multiple captured emissions locations,
design a sampling system
to allow a single FIA to be used to determine the VOC responses
at all sampling locations.
4.2
Gas VOC Concentration.
4.2.1
Assemble the sample train as shown in Figure
1.
Calibrate
the FIA according to the procedure in Section 5.1.
4.2.2
Set the dilution ratio and determine the dilution factor
according to the procedure in Section 5.3.
4.2.3
Conduct a system check according to the procedure in
Section 5.4.
4.2.4
Install the sample probe so that the probe is centrally
located in the stack, pipe, or duct, and is sealed tightly at the
stack port connection.
4.2.5
Inject zero gas at the calibration valve assembly.
Measure the system response time as the time required for the
system to reach the effluent concentration after the calibration
valve has been returned to the effluent sampling position.
4.2.6
Conduct a system check before and a system drift check
after each sampling
run
according to the procedures in Sections
5.2 and 5.4.
If the drift check following a run indicates
unacceptable performance, the run is not valid.
The tester may
elect to perform system drift checks during the run not to exceed
199
one drift check per hour.
4.2.7
Verify that the sample lines, filter, and pump
temperatures are 120±5°C.
4.2.8
Begin sampling at the start of the test period and
continue to sample during the entire run.
Record the starting
and ending times and any required process information as
appropriate.
If multiple captured emission locations are sampled
using a single FIA, sample at each location for the same amount
of time (e.g.,
2 minutes) and continue to switch from one
location to another for the entire test run.
Be sure that total
sampling time at each location is the same at the end of the test
run.
Collect at least
4 separate measurements from each sample
point during each hour of testing.
Disregard the measurements at
each sampling location until two times the response time of the
measurement system has elapsed.
Continue sampling for at least
1
minute and record the concentration measurements.
4.3
Background Concentration.
4.3.1
Locate all NDO’s of the TTE.
A sampling point shall be
centrally located outside of the TTE at 4 equivalent diameters
from each NDO,
if possible.
If there are more than 6 NDO’s,
choose
6 sampling points evenly spaced among the NDO’s.
4.3.2
Assemble the sample train as shown in Figure
2.
Calibrate
the FIA and conduct a system check according to the procedures in
Sections 5.1 and
5.4.
4.3.3
Position the probe at the sampling location.
4.3.4
Determine the response time, conduct the system check and
sample according to the procedures described in Sections 4.2.4 to
4.2.8.
4.4
Alternative Procedure.
The direct interface sampling and
analysis procedure described in Section 7.2 of Method 18 may be
used to determine the gas VOC concentration.
The system must be
designed to collect and analyze at least one sample every 10
minutes.
5.
CALIBRATION AND QUALITY ASSURANCE
5.1
FIA Calibration and Linearity Check.
Make necessary
adjustments to the air and fuel supplies for the FIA and ignite
the burner.
Allow the FIA to
warm
up for the period recommended
by the manufacturer.
Inject a calibration gas into the
measurement system after the dilution system and adjust the back-
pressure regulator to the value required to achieve the flow
rates specified by the manufacturer.
Inject the zero— and the
200
high—range calibration gases and adjust the analyzer calibration
to provide the proper responses.
Inject the low— and mid—range
gases and record the responses of the measurement system.
The
calibration and linearity of the system are acceptable if the
responses for all four gases are within
5 percent of the
respective gas values.
If the performance of the system is not
acceptable,
repair or adjust the system and repeat the linearity
check.
Conduct a calibration and linearity check after
assembling the analysis system and after a major change is made
to the system.
5.2
Systems Drift Checks.
Select the calibration gas that most
closely approximates the concentration of the diluted captured
emissions for conducting the drift checks.
Introduce the zero
and calibration gas at the calibration valve assembly and verify
that the appropriate gas flow rate and pressure are present at
the FIA.
Record the measurement system responses to the zero and
calibration gases.
The performance of the system is acceptable
if the difference between the drift check measurement and the
value obtained in Section 5.1 is less than
3 percent of the span
value.
Conduct the system drift check at the end of each run.
5.3
Determination of Dilution Factor.
Inject the dilution check
gas into the measurement system before the dilution system and
record the response.
Calculate the dilution factor using
Equation 3.
5.4
System Check.
Inject the high range calibration gas at the
inlet to the sampling probe while the dilution air is turned off.
Record the response.
The performance of the system is acceptable
if the measurement system response is within
5 percent of the
value obtained in Section 5.1 for the high range calibration gas.
Conduct a system check before and after each test run.
5.5
Analysis Audit.
Immediately before each test analyze an
audit cylinder as described in Section 5.2.
The analysis audit
must agree with the audit cylinder concentration within 10
percent.
6.
NOMENCLATURE
A1
=
area of
NDO
i,
ft2.
AN
=
total area of all
NDO’s
in the enclosure,
ft2.
CA
=
actual concentration of the dilution check gas, ppm
propane.
=
corrected average VOC concentration of background
emissions at point
i, ppm propane.
C8
=
average background concentration, ppm propane.
201
CDH
=
average measured concentration for the drift check
calibration gas, ppm propane.
CDD
=
average system drift check concentration for zero
concentration gas, ppm propane.
=
actual concentration of the drift check calibration
gas, ppm propane.
C1
=
uncorrected average background VOC concentration
measured at point i, ppm propane.
C1
=
uncorrected average VOC concentration measured at
point
j,
ppm propane.
CM
=
measured concentration of the dilution check gas, ppm
propane.
DF
=
dilution factor.
G
=
total VOC content of captured emissions,
kg.
K1
=
1.830 x 10~kg/(xn3-ppm).
n
=
number of measurement points.
QGJ
=
average effluent volumetric flow rate corrected to
standard conditions at captured emissions point
j,
m3/min.
Tc
=
total duration of capture efficiency sampling run,
mm.
7.
CALCULATIONS
7.1
Total VOC Captured Emissions.
G
=
.!~
C31
~GJ
T~K1
Eq.
1
7.2
VOC Concentration of the Captured Emissions at Point
j.
C31
=
DF
(C1
—
C30)
CH
Eq.
2
CDH
—
7.3
Dilution Factor.
Eq.
3
CM
202
7.4
Background VOC Concentration at Point
i.
C81
=
(C1
—
C30)
C11
Eq.
4
CDH
—
C33
7.5
Average Background Concentration.
n
E
C.A.
Si
1
C8=
Eq.5
nA~
NOTE:
If
the
concentration
at
each
point
is
within
20
percent
of
the
average
concentration
of
all
points,
the
terms
“A1”
and
“AN”
may be deleted from Equation 4.
Procedure F.2
-
Fugitive VOC Emissions from Building Enclosures
1.
INTRODUCTION
1.1
Applicability.
This procedure is applicable for determining
the fugitive volatile organic compounds
(VOC)
emissions from a
building enclosure
(BE).
It is intended to be used as
a segment
in the development of liquid/gas or gas/gas protocols for
determining VOC capture efficiency
(CE)
for surface coating and
printing operations.
1.2
Principle.
The total amount of fugitive VOC emissions
(FB)
from the BE is calculated as the sum of the products of the VOC
content
(CFJ)
of each fugitive emissions point,
its flow rate
(QF1)’
and time
(TF).
1.3
Measurement Uncertainty.
The measurement uncertainties are
estimated for each fugitive emissions point as follows:
QFJ
=
±5~Q
percent and
CF.
=
±5Qpercent.
Based on these numbers, the
probable uncertainty for
FB
is estimated at about ±11.2percent.
1.4
Sampling Requirements.
A capture efficiency test shall
consist of at least three sampling runs.
The sampling time for
each run should be at least
8 hours, unless otherwise approved.
1.5
Notes.
Because this procedure is often applied in highly
explosive areas, caution and care should be exercised in choosing
appropriate equipment and installing and using the equipment.
Mention of trade names or company products does not constitute
endorsement.
All gas concentrations
(percent, ppm) are by
volume, unless otherwise noted.
2.
APPARATUS
AND
REAGENTS
2.1
Gas VOC Concentration.
A schematic of the measurement
system is shown in Figure
1.
The main components are described
203
below:
2.1.1
Sample
Probe.
Stainless
steel,
or
equivalent.
The
probe
shall
be
heated
to
prevent
VOC
condensation.
2.1.2
Calibration
Valve
Assembly.
Three-way
valve
assembly
at
the outlet of sample probe to direct the zero and calibration
gases to the analyzer.
Other methods, such as quick-connect
lines,
to route calibration gases to the outlet of the sample
probe are acceptable.
2.1.3
Sample Line.
Stainless steel or Teflon tubing to
transport the sample gas to the analyzer.
The sample line must
be heated to prevent condensation.
2.1.4
Sample Pump.
A leak-free pump,
to pull the sample gas
through the system at a flow rate sufficient to minimize the
response time of the measurement system.
The components of the
pump that contact the gas streamshall be constructed of stainless
steel or Teflon.
The sample pump must be heated to prevent
condensation.
2.1.5
Sample Flow Rate Control.
A sample flow rate control
valve and rotameter,
or equivalent, to maintain a constant
sampling rate within 10 percent.
The flow rate control valve and
rotameter must be heated to prevent condensation.
A control
valve may also be located on the sample pump bypass loop to
assist in controlling the sample pressure and flow rate.
2.1.6
Sample Gas Manifold.
Capable of diverting a portion of
the sample gas stream to the flame ionization analyzer (FIA), and
the remainder to the bypass discharge vent.
The manifold
components shall be constructed of stainless steel or Teflon.
If
emissions are to be measured at multiple locations,
the
measurement system shall be designed to use separate sampling
probes, lines,
and pumps for each measurement location and a
common sample gas manifold and FIA.
The sample gas manifold must
be heated to prevent condensation.
2.1.7
Organic Concentration Analyzer.
An FIA with a span value
of 1.5 times the expected concentration as propane; however,
other span values may be used if it can be demonstrated that they
would provide more accurate measurements.
The system shall be
capable of meeting or exceeding the following specifications:
2.1.7.1
Zero Drift.
Less than ±30percent of the span value.
2.1.7.2
Calibration Drift.
Less than ±3.0percent of the span
value.
2.1.7.3
Calibration Error.
Less than ±5.0percent of the
calibration gas value.
204
2.1.7.4
Response Time.
Less than 30 seconds.
2.1.8
Integrator/Data Acquisition System.
An analog or digital
device or computerized data acquisition system used to integrate
the FIA response or compute the average response and record
measurement data.
The minimum data sampling frequency for
computing average or integrated values is one measurement value
every
5 seconds.
The device shall be capable of recording
average values at least once per minute.
2.1.9
Calibration and Other Gases.
Gases used for calibration,
fuel, and combustion air
(if required) are contained in
compressed gas cylinders.
All calibration gases shall be
traceable to NIST standards and shall be certified by the
manufacturer to ±1percent of the tag value.
Additionally, the
manufacturer of the cylinder should provide a recommended shelf
life for each calibration gas cylinder over which the
concentration does not change more than ±2percent from the
certified value.
For calibration gas values not generally
available,
alternative methods for preparing calibration gas
mixtures, such as dilution systems, may be used with prior
approval.
2.1.9.1
Fuel.
A 40 percent 112/60 percent He or 40 percent 112/60
percent N2 gas mixture is recommended to avoid an oxygen
synergism effect that reportedly occurs when oxygen concentration
varies significantly from a mean value.
2.1.9.2
Carrier Gas.
High purity air with less than 1 ppm of
organic material
(propane or carbon equivalent)
or less than 0.1
percent of the span value, whichever is. greater.
2.1.9.3
FIA Linearity Calibration Gases.
Low-, mid-,
and
high—range gas mixture standards with nominal propane
concentrations of 20-30,
45-55, and 70-80 percent of the span
value in air, respectively.
Other calibration values and other
span values may be used if it can be shown that more accurate
measurements would be achieved.
2.1.10
Particulate Filter.
An in-stack or an out-of—stack glass
fiber filter is recommended if exhaust gas particulate loading is
significant.
An out-of-stack filter must be heated to prevent
any condensation unless it can be demonstrated that no
condensation occurs.
2.2
Fugitive Emissions Volumetric Flow Rate.
2.2.1
Flow Direction Indicators.
Any means of indicating inward
or outward flow,
such as light plastic film or paper streamers,
smoke tubes,
filaments, and sensory perception.
205
2.2.2
Method
2 or 2A Apparatus.
For determining volumetric flow
rate.
Anemometers or similar devices calibrated according to the
manufacturer’s instructions may be used when low velocities are
4present.
Vane anemometers (Young—maximum response propeller),
specialized pitots with electronic manometers
(e.g.,
Shortridge
Instruments Inc., Airdata Multimeter 860)
are commercially
available with measurement thresholds of 15 and 8 mpm
(50 and
25 fpm),
respectively.
2.2.3
Method
3 Apparatus and Reagents.
For determining
molecular weight of the gas stream.
An estimate of the molecular
weight of the gas stream may be used if it can be justified.
2.2.4
Method
4 Apparatus and Reagents.
For determining moisture
content,
if necessary.
3.
DETERMINATION OF VOLUMETRIC FLOW RATE OF FUGITIVE EMISSIONS
3.1
Preliminary Determinations.
The purpose of this exercise is
to determine which exhaust points should be measured for
volumetric flow rates and VOC concentrations.
3.1.1
Forced Draft Openings.
Identify all forced draft
openings.
Determine the volumetric flow rate according to Method
2.
3.1.2
NDO’s Exhaust
Points.
The
NDO’s
in
the
roof
of
a
facility
are considered to be exhaust points.
Determine
volumetric
flow
rate from these NDO’s.
Divide the cross-sectional area according
to Method
1 using 12 equal areas.
Use the appropriate
velocity
measurement
devices,
e.g.,
propeller
anemometers.
3.1.3
Other
NDO’s.
3.1.3.1
This step is optional.
Determine the exhaust flow rate,
including that of the control device, from the enclosure and the
intake air flow rate.
If the exhaust flow rate divided by the
intake air flow rate is greater than 1.1, then all other NDO’s
are not considered to be significant exhaust points.
3.1.3.2
If the option above is not taken,
identify all other
NDO’s and other potential points through which fugitive emissions
may escape the enclosure.
Then use the following criteria to determine whether flow rates
and VOC concentrations need to be measured:
3.1.3.2.1
Using the appropriate flow direction indicator,
determine the flow direction.
An NDO with zero or inward flow is
not an exhaust point.
3.1.3.2.2
Measure the outward volumetric flow rate from the
remainder of the NDO’s.
If the collective flow rate is 2
206
percent, or less,
of the flow rate from Sections 3.1.1 and 3.1.2,
then these NDO’s,
except those within two equivalent diameters
(based on NDO opening) from VOC sources, may be considered to be
non—exhaust points.
3.1.3.2.3
If the percentage calculated in Section 3.1.3.2.2
is
greater than 2 percent, those NDO’s
(except those within two
equivalent diameters from VOC sources) whose volumetric flow rate
total
2 percent of the flow rate from Sections 3.1.1 and 3.1.2
may be considered as non—exhaust points.
All remaining NDO’s
shall be measured for volumetric flow rate and VOC concentrations
during the CE test.
3.1.3.2.4
The tester may choose to measure VOC concentrations at
the forced exhaust points and the NDO’s.
If the total VOC
emissions from the NDO’s are less than
2 percent of the emissions
from the forced draft and roof NDO’s, then these NDO’s may be
eliminated from further consideration.
3.2
Determination of Flow Rates.
3.2.1
Measure the volumetric flow rate at all locations
identified as exhaust points in Section 3.1.
Divide each exhaust
opening into
9 equal areas for rectangular openings and
8
for
circular openings.
3.2.2
Measure the velocity at each site at least once every hour
during each sampling
run
using Method
2 or 2A,
if applicable,
or
using the low velocity instruments in Section 2.2.2.
4.
DETERMINATION OF VOC CONTENT OF FUGITIVE EMISSIONS
4.1
Analysis Duration.
Measure the VOC responses at each
fugitive emission point during the entire test run or,
if
applicable, while the process is operating.
If there are
multiple emissions locations, design a sampling system to allow a
single FIA to be used to determine the VOC responses at all
sampling locations.
4.2
Gas VOC Concentration.
4.2.1
Assemble the sample train as shown in Figure
1.
Calibrate
the FIA and conduct a system check according to the procedures in
Sections 5.1 and 5.3, respectively.
4.2.2
Install the sample probe so that the probe is centrally
located in the stack, pipe,
or duct,
and is sealed tightly at the
stack port connection.
4.2.3
Inject zero gas at the calibration valve assembly.
Allow
the measurement system response to reach zero.
Measure the
system response time as the time required for the system to reach
207
the
effluent
concentration
after
the
calibration
valve has been
returned to the effluent sampling position.
4.2.4
Conduct a
system
check
before
and
a
system
drift
check
after
each
sampling
run according to the procedures in Sections
5.2 and 5.3.
If the drift check following a run indicates
unacceptable performance, the run is not valid.
The tester may
elect to perform drift checks during the run not to exceed one
drift check per hour.
4.2.5
Verify that the sample lines,
filter, and pump
temperatures are 120
±5oC.
4.2.6
Begin sampling at the start of the test period and
continue to sample during the entire run.
Record the starting
and ending times and any required process information as
appropriate.
If multiple emission locations are sampled using a
single FIA, sample at each location for the same amount of time
(e.g.,
2 minutes) and continue to switch from one location to
another for the entire test run.
Be sure that total sampling
time at each location is the same at the end of the test run.
Collect at least
4 separate measurements from each sample point
during each hour of testing.
Disregard the response measurements
at each sampling location until two times the response time of
the measurement system has elapsed.
Continue sampling for at
least 1 minute and record the concentration measurements.
4.3
Alternative Procedure
The direct interface sampling and
analysis procedure described in Section 7.2 of Method 18 may be
used to determine the gas VOC concentration.
The system must be
designed to collect and analyze at least one sample every 10
minutes.
5.
CALIBRATION
AND
QUALITY ASSURANCE
5.1
FIA Calibration and Linearity Check.
Make necessary
adjustments to the air and fuel supplies for the FIA and ignite
the burner.
Allow the FIA to warm up for the period recommended
by the manufacturer.
Inject a calibration gas into the
measurement system and adjust the back—pressure regulator to the
value required to achieve the flow rates specified by the
manufacturer.
Inject
the
zero—
and
the
high—range
calibration
gases
and
adjust
the
analyzer
calibration
to
provide
the
proper
responses.
Inject
the
low-
and
mid—range
gases
and
record
the
responses of the measurement system.
The calibration and
linearity
of
the
system
are
acceptable
if
the
responses
for
all
four gases are within
5 percent of the respective gas values.
If
the performance of the system is not acceptable,
repair or adjust
the system and repeat the linearity check.
Conduct a calibration
and linearity check after assembling the analysis system and
after a major change is made to the system.
208
5.2
Systems
Drift
Checks.
Select
the
calibration
gas
that
most
closely approximates the concentration of the captured emissions
for
conducting
the
drift
checks.
Introduce
the
zero
and
calibration
gas
at
the
calibration
valve
assembly
and
verify
that
the
appropriate
gas
flow
rate
and
pressure
are
present
at
the
FIA.
Record the measurement system responses to the zero and
calibration
gases.
The
performance
of
the
system
is
acceptable
if the difference between the drift check measurement and the
value
obtained
in
Section
5.1
is
less
than
3
percent
of
the
span
value.
Conduct a system drift check at the end of each run.
5.3
System
Check.
Inject
the
high range calibration gas at the
inlet
of
the
sampling
probe
and
record
the
response.
The
performance
of
the
system
is
acceptable
if
the
measurement
system
response
is
within
5
percent
of
the
value
obtained
in
Section
5.1
for the high range calibration gas.
Conduct a system check
before each test run.
5.4
Analysis Audit.
Immediately before each test analyze an
audit cylinder as described in Section 5.2.
The analysis audit
must agree with the audit cylinder concentration within 10
percent.
6.
NOMENCLATURE
CDH
=
average measured concentration for the
drift
check
calibration gas, ppm propane.
C30
=
average system drift check concentration for zero
concentration gas, ppm propane.
CFJ
=
corrected average VOC concentration of fugitive
emissions at point
j,
ppm propane.
C11
=
actual concentration of the
drift
check
calibration
gas, ppm propane.
C1
=
uncorrected average VOC concentration measured at point
j,
ppm propane.
F8
=
total VOC content of fugitive emissions from the
building,
kg.
K1
=
1.830
x
10~6kg/(m3-ppm).
n
=
number
of measurement
points.
QFJ
=
average effluent volumetric flow rate corrected to
standard conditions at fugitive emissions point
j,
m3/min.
=
total duration of capture efficiency sampling run, mm.
209
7.
CALCULATIONS
7.1
Total VOC Fugitive Emissions From the Building.
F8
=
.~
C~1
QFj
Tf
K1
Eq.
1
7.2
VOC Concentration of the Fugitive Emissions at Point
j.
CFJ
=
(C1
—
C30)
C11
Eq.
2
CDH
—
C30
Procedure F.l
—
Fugitive VOC Emissions from Temporary Enclosures
1.
INTRODUCTION
1.1
Applicability.
This procedure is applicable for determining
the fugitive volatile organic compounds
(VOC) emissions from a
temporary total enclosure (TTE).
It is intended to be used as
a
segment
in..
the development of liquid/gas or gas/gas protocols for
determining
VOC
capture
efficiency
(CE)
for
surface
coating
and
printing operations.
1.2
Principle.
The
amount
of
fugitive
VOC
emissions
(F)
from
the TTE
is calculated as the sum of the products of the VOC
content
(CFJ)1
the flow rate
(QF1)’ and the sampling time
(TF)
from
each fugitive emissions point.
1.3
Estimated Measurement Uncertainty.
The measurement
uncertainties are estimated for each fugitive emission point as
follows:
QfJ
=
±5~5
percent and CF3
=
~
percent.
Based on
these numbers, the probable uncertainty for F is estimated at
about
±7~4
percent.
1.4
Sampling Requirements.
A capture efficiency test shall
consist of at least three sampling runs.
The sampling time for
each run should be at least
8 hours, unless otherwise approved.
1.5
Notes.
Because this procedure is often applied in highly
explosive areas, caution and care should be exercised in choosing
appropriate equipment and installing and using the equipment.
Mention of trade names or company products does not
constitute
endorsement.
All gas concentrations (percent, ppm)
are by
volume, unless otherwise noted.
2.
APPARATUS
AND
REAGENTS
2.1
Gas VOC Concentration.
A schematic of the measurement
system is
shown
in
Figure
1.
The
main components are described
210
below:
2.1.1
Sample Probe.
Stainless steel, or equivalent.
The probe
shall be heated to prevent VOC condensation.
2.1.2
Calibration Valve Assembly.
Three-way valve assembly at
the
outlet
of
sample
probe
to direct the zero and calibration
gases to the analyzer.
Other methods, such as quick—connect
lines,
to
route
calibration
gases
to
the
outlet
of the sample
probe
are
acceptable.
2.1.3
Sample Line.
Stainless steel
or Teflon tubing to
transport the sample gas to the analyzer.
The sample line must
be heated to prevent condensation.
2.1.4
Sample Pump.
A leak-free pump,
to pull the sample gas
through the system at a flow rate sufficient to minimize the
response time of themeasurement system.
The components of the
pump that contact the gas stream shall be constructed
of-
stainless steel or Teflon.
The sample pump must be heated to
prevent condensation.
2.1.5
Sample Flow Rate Control.
A-sample flow rate control
valve and rotaineter, or equivalent,
to maintain a constant
sampling rate within 10 percent.
The flow control valve and
rotameter must be heated to prevent condensation.
A control
valve may also be located on the sample pump bypass loop to
assist in controlling the sample pressure and flow rate.
2.1.6
Sample
Gas
Manifold.
Capable
of
diverting
a
portion
of
the
sample
gas
stream
to
the
flame
ionization
analyzer
(FIA),
and
the
remainder
to
the
bypass
discharge
vent.
The
manifold
components
shall
be
constructed
of
stainless
steel
or
Teflon.
If
emissions
are to be measured at multiple locations,
the
measurement system shall be designed to use separate sampling
probes,
lines,
and
pumps
for
each
measurement
location
and
a
common
sample gas manifold and FIA.
The sample gas manifold and
211
connecting lines to the FIA must be heated to prevent
condensation.
2.1.7
Organic
Concentration
Analyzer.
An
FIA
with
a
span
value
of
1.5
times
the
expected
concentration
as
propane;
however,
other span values may be used if it can be demonstrated that they
would provide more accurate measurements.
The system shall be
capable of meeting or exceeding the following specifications:
2.1.7.1
Zero Drift.
Less
than ±3.0percent of the span value.
2.1.7.2
Calibration Drift.
Less than ±30percent of the span
value.
2.1.7.3
Calibration Error.
Less than ±5.0percent of the
calibration gas value.
2.1.7.4
Response Time.
Less than 30 seconds.
2.1.8
Integrator/Data
Acquisition
System.
An
analog
or
digital
device
or
computerized
data
acquisition
system
used
to
integrate
the FIA response or compute the average response and record
measurement data.
The minimum data sampling frequency for
computing average or integrated values is one measurement value
every
5
seconds.
The
device
shall
be
capable
of
recording
average
values
at
least
once
per
minute.
2.1.9
Calibration
and
Other
Gases.
Gases
used
for
calibration,
fuel,
and
combustion
air
(if
required)
are
contained
in
compressed
gas
cylinders.
All
calibration
gases
shall
be
traceable to NIST standards and shall be certified by the
manufacturer to ±1percent of the tag value.
Additionally, the
manufacturer
of
the
cylinder
should
provide
a
recommended
shelf
life
for
each
calibration
gas
cylinder
over
which
the
concentration
does
not
change
more
than
±2
percent
from
the
certified
value.
For
calibration
gas
values
notgenerally
available,
alternative
methods
for
preparing
calibration
gas
mixtures,
such
as
dilution
systems,
may
be
used
with
prior
approval.
2.1.9.1
Fuel.
A 40 percent 112/60 percent He or 40 percent
112/60
percent
N2 gas mixture is recommended to avoid an oxygen
synergism
effect
that
reportedly
occurs
when
oxygen
concentration
varies
significantly
from
a
mean
value.
2.1.9.2
Carrier
Gas.
High
purity
air
with
less
than
1
ppm
of
organic
material
(as
propane
or
carbon
equivalent)
or
less
than
0.1
percent
of
the
span
value,
whichever
is
greater.
2.1.9.3
FIA Linearity Calibration Gases.
Low-,
mid—,
and
high—range gas mixture standards with nominal propane
concentrations of 20—30, 45—55, and 70-80 percent of the span
212
value
in
air,
respectively.
Other
calibration
values
and
other
span
values
may
be
used
if
it
can
be
shown
that
more
accurate
measurements
would
be
achieved.
2.1.10
Particulate
Filter.
An
in-stack
or
an
out-of-stack
glass
fiber filter is recommended if exhaust gas particulate loading is
significant.
An out—of-stack filter must be heated to prevent
any condensation unless it can be demonstrated that no
condensation occurs.
2.2
Fugitive
Emissions
Volumetric
Flow
Rate.
2.2.1
Method
2
or
2A
Apparatus.
For
determining
volumetric
flow
rate.
2.2.2
Method
3 Apparatus and Reagents.
For determining
molecular weight of the gas stream.
An estimate of the molecular
weight
of
the
gas
stream
may
be
used
if
it
can
be
justified.
2.2.3
Method
4
Apparatus
and
Reagents.
For
determining
moisture
content,
if necessary.
2.3
Temporary Total Enclosure.
The criteria for designing a TTE
are discussed in Procedure
T.
3.
DETERMINATION
OF
VOLUMETRIC
FLOW
RATE
OF
FUGITIVE
EMISSIONS
3.1
Locate
all
points
where
emissions
are
exhausted
from
the
TTE.
Using
Method
1,
determine
the
sampling
points.
Be
sure
to
check
each
site
for
cyclonic
or
swirling
flow.
3.2
Measure
the
velocity
at
each
sampling
site
at
least
once
every
hour
during
each
sampling
run
using
Method
2
or
2A.
4.
DETERMINATION
OF VOC CONTENT OF FUGITIVE EMISSIONS
4.1
Analysis Duration.
Measure the VOC responses at each
fugitive
emission
point
during
the
entire
test
run
or, if
applicable,
while
the
process
is
operating.
If
there
are
multiple
emission
locations,
design
a
sampling
system
to
allow
a
single
FIA
to
be
used
to
determine
the
VOC
responses
at
all
sampling locations.
4.2
Gas VOC Concentration.
4.2.1
Assemble the sample train as shown in Figure
1.
Calibrate
the FIA and conduct a system check according to the procedures in
Sections
5.1
and
5.3,
respectively.
4.2.2
Install
the
sample
probe
so
that
the
probe
is
centrally
located in the stack, pipe,
or duct,
and is sealed tightly at the
stack
port
connection.
213
4.2.3
Inject zero gas at the calibration valve assembly.
Allow
the measurement system response to reach zero.
Measure the
system response time as the time required for the system to reach
the effluent concentration after the calibration valve has been
returned to the effluent sampling position.
4.2.4
Conduct a system check before and a system drift check
after each sampling run according to the procedures in Sections
5.2 and 5.3.
If the drift check following a
run
indicates
unacceptable performance, the run is not valid.
The tester may
elect
to
perform
system
drift
checks
during
the
run
not to exceed
one drift check per hour.
4.2.5
Verify
that
the
sample
lines,
filter,
and
pump
temperatures are 120±5°C.
4.2.6
Begin
sampling
at
the
start
of
the
test
period
and
continue
to
sample
during
the
entire
run.
Record
the
starting
and
ending
times
and
any
required
process
information
as
appropriate.
If
multiple
emission
locations
are
sampled
using
a
single
FIA,
sample
at
each
location
for
the
same
amount
of
time
(e.g.,
2 minutes)
and continue to switch from one location to
another
for
the
entire
test
run.
Be
sure
that
total
sampling
time
at
each
location
is
the
same
at
the
end
of
the
test
run.
Collect
at
least
4
separate
measurements
from
each
sample
point
during
each
hour
of
testing.
Disregard
the
response
measurements
at
each
sampling
location
until
two
times
the
response
time
of
the
measurement
system
has
elapsed.
Continue
sampling
for
at
least
1
minute
and
record
the
concentration
measurements.
4.3
Background Concentration.
4.3.1
Determination of VOC Background Concentration.
4.3.1.1
Locate all NDO’s of the TTE.
A sampling point shall be
centrally located outside of the TTE at
4 equivalent diameters
from
each
NDO,
if
possible.
If
there
are
more
than
6
NDO’s,
choose
6 sampling points evenly spaced among the NDO’s.
4.3.1.2
Assemble the sample train as shown in Figure
2.
Calibrate the FIA and conduct a system check according to the
procedures in Sections 5.1 and 5.3.
4.3.1.3
Position the probe at the sampling location.
4.3.1.4
Determine the response time, conduct the system check
and sample according to the procedures described in Sections
4.2.3 to 4.2.6.
4.4
Alternative Procedure.
The direct interface sampling and
analysis procedure described in Section 7.2 of Method 18 may be
used to determine the gas VOC concentration.
The system must be
214
designed
to
collect
and
analyze
at
least
one
sample
every
10
minutes.
5.
CALIBRATION
AND
QUALITY
ASSURANCE
5.1
FIA Calibration and
Linearity
Check.
Make
necessary
adjustments to the air and fuel supplies for the FIA and ignite
the burner.
Allow the FIA to warm up for the period recommended
by the manufacturer.
Inject a calibration gas into the
measurement
system
and
adjust
the
back-pressure
regulator
to
the
value required to achieve the flow rates specified by the
manufacturer.
Inject the zero— and the high—range calibration
gases and adjust the analyzer calibration to provide the proper
responses.
Inject the low— and mid—range gases and record the
responses of the measurement system.
The calibration and
linearity
of
the
system
are
acceptable
if
the
responses
for
all
four
gases
are
within
5
percent
of
the
respective
gas
values.
If
the performance of the system is not acceptable,
repair or adjust
the system and repeat the linearity check.
Conduct a calibration
and
linearity
check
after
assembling
the
analysis
system
and
after
a
major
change
is
made
to
the
system.
5.2
Systems Drift Checks.
Select the calibration gas
concentration
that
most
closely
approximates
that
of
the
fugitive
gas
emissions
to
conduct
the
drift
checks.
Introduce
the
zero
and
calibration
gas
at
the
calibration
valve
assembly
and
verify
that
the
appropriate
gas
flow
rate
and
pressure
are
present
at
the
FIA.
Record
the
measurement
system
responses
to
the
zero
and
calibration
gases.
The
performance
of
the
system
is
acceptable
if the difference between the drift check measurement and the
value obtained in Section 5.1 is less than
3 percent of the span
value.
Conduct
a
system
drift
check
at
the
end
of
each
run.
5.3
System Check.
Inject the high range calibration gas at the
inlet of the sampling probe and record the response.
The
performance of the system is acceptable if the measurement system
response is within
5 percent of the value obtained in Section 5.1
for
the
high
range
calibration
gas.
Conduct
a
system
check
before
each
test
run.
5.4
Analysis
Audit.
Immediately
before
each
test
analyze
an
audit cylinder as described in Section 5.2.
The analysis audit
must agree with the audit cylinder concentration within 10
percent.
6.
NOMENCLATURE
A1
=
area of NDO i,
ft2.
AN
=
total area of all NDO’s in the enclosure,
ft2.
C8~
=
corrected average VOC concentration of background
215
emissions at point
i, ppm propane.
C8
=
average
background
concentration,
ppm
propane.
S~H
=
average measured concentration for the drift check
calibration gas, ppm propane.
C30
=
average
system
drift
check
concentration
for
zero
concentration
gas,
ppm
propane.
CFJ
=
corrected average VOC concentration of fugitive
emissions at point
j,
ppm propane.
CH
=
actual
concentration
of
the
drift
check
calibration
gas, ppm propane.
C1
=
uncorrected average background VOC concentration at
point
i,
ppm
propane.
C~
=
uncorrected average VOC concentration
measured
at
point
j,
ppm propane.
F
=
total VOC content of fugitive emissions,
kg.
K1
=
1.830 x 10~kg/(m3-ppm).
n
=
number
of
measurement
points.
QFJ
=
average
effluent
volumetric
flow
rate
corrected
to
standard conditions at fugitive emissions point
j,
m3/min.
=
total duration of fugitive emissions sampling run, mm.
7.
CALCULATIONS
7.1
Total VOC Fugitive Emissions.
F
=
~
(CFJ
—
C8)
~FJ
TF
K1
Eq.
1
7.2
VOC
Concentration
of
the
Fugitive
Emissions
at
Point
j.
CFJ
=
(C1
—
C00)
C11
Eq.
2
CDH
—
C33
7.3
Background VOC Concentration at Point i.
C81
=
(C1
—
~
CH
Eq.
3
C311
—
C30
216
7.4
Average Background Concentration.
n
E
C.A.
C5=
Eq.5
nA~
NOTE:
If
the
concentration
at
each
point
is
within
20
percent
of
the
average
concentration
of
all
points,
the
terms
“A1”
and
“AN”
may
be
deleted
from
Equation
4.
217
Procedure L
-
VOC Input
1.
INTRODUCTION
1.1
Applicability.
This
procedure
is
applicable
for
determining
the
input
of
volatile
organic
compounds
(VOC).
It
is
intended
to
be
used
as
a
segment
in
the
development
of
liquid/gas
protocols
for
determining
VOC
capture
efficiency
(CE)
for
surface
coating
and
printing
operations.
1.2
Principle.
The
amount
of
VOC
introduced
to
the
process
(L)
is
the
sum
of
the
products
of
the
weight
(W)
of
each
VOC
containing
liquid
(ink,
paint,
solvent,
etc.)
used
and
its
VOC
content
(V).
A
sample
of
each
VOC
containing
liquid
is
analyzed
with
a
flame
ionization
analyzer
(FIA)
to
determine
V.
1.3
Estimated Measurement Uncertainty.
The measurement
uncertainties are estimated for each VOC containing liquid as
follows:
W
=
±2.0 percent
and
V
=
±12.0 percent.
Based
on
these
numbers,
the
probable
uncertainty
for
L
is
estimated
at
about
±12.2 percent
for
each
VOC
containing
liquid.
1.4
Sampling
Requirements.
A
capture
efficiency
test
shall
consist
of
at
least
three
sampling
runs.
The
sampling
time
for
each run should be at least
8 hours, unless otherwise approved.
1.5
Notes.
Because
this
procedure
is
often
applied
in
highly
explosive areas, caution and care should be exercised in choosing
appropriate
equipment
and
installing
and
using
the
equipment.
Mention
of
trade
names
or
company
products
does
not
constitute
endorsement.
All
gas
concentrations
(percent,
ppm)
are
by
volume,
unless
otherwise
noted.
2.
APPARATUS
AND
REAGENTS
2.1
Liquid Weight.
2.1.1
Balances/Digital
Scales.
To
weigh
drums
of
VOC
containing
liquids to within 0.2 lb.
2.1.2
Volume Measurement Apparatus (Alternative).
Volume
meters,
flow
meters,
density
measurement
equipment,
etc.,
as
needed
to
achieve
same
accuracy
as
direct
weight
measurements.
2.2
VOC
Content
(Flame
Ionization
Analyzer
Technique).
The
liquid
sample
analysis
system
is
shown
in
Figures
1
and
2.
The
following equipment is required:
2.2.1
Sample
Collection
Can.
An
appropriately
sized
metal
can
to be used to collect VOC containing materials.
The can must be
constructed
in
such
a
way
that
it
can
be
grounded
to
the
coating
container.
218
2.2.2
Needle
Valves.
To
control
gas
flow.
2.2.3
Regulators.
For carrier gas and calibration gas
cylinders.
2.2.4
Tubing.
Teflon
or
stainless
steel
tubing
with
diameters
and
lengths
determined
by
connection
requirements
of
equipment.
The
tubing
between
the
sample
oven
outlet
and
the
FIA
shall
be
heated to maintain a temperature of
120 ±5°C.
2.2.5
Atmospheric
Vent.
A
tee
and
0- to 0.5-liter/mm
rotameter
placed
in
the
sampling
line
between
the
carrier
gas
cylinder
and
the
VOC
sample
vessel
to
release
the
excess
carrier
gas.
A
toggle
valve
placed
between
the
tee
and
the
rotameter
facilitates
leak tests of the analysis system.
2.2.6
Thermometer.
Capable of measuring the temperature of the
hot water bath to within 1°C.
2.2.7
Sample Oven.
Heated enclosure, containing calibration gas
coil
heaters,
critical
orifice,
aspirator,
and
other
liquid
sample
analysis
components,
capable
of
maintaining
a
temperature
of
120
±5°C.
2.2.8
Gas
Coil
Heaters.
Sufficient
lengths
of
stainless
steel
or
Teflon
tubing
to
allow
zero
and
calibration
gases
to
be
heated
to
the
sample
oven
temperature
before
entering
the
critical
orifice or aspirator.
2.2.9
Water
Bath.
Capable
of
heating
and
maintaining
a
sample
vessel
temperature
of
100
±5°C.
2.2.10
Analytical
Balance.
To
measure
±0.001 g.
2.2.11
Disposable Syringes.
2-cc or 5-cc.
2.2.12
Sample Vessel.
Glass, 40-ml septum vial.
A separate
vessel
is
needed
for
each
sample.
2.2.13
Rubber
Stopper.
Two-hole
stopper
to
accommodate
3.2-mm
(1/8-in.)
Teflon
tubing,
appropriately
sized
to
£it
the
opening
of
the
sample
vessel.
The
rubber
stopper
should
be
wrapped
in
Teflon
tape
to
provide
a
tighter
seal
and
to
prevent
any
reaction
of
the
sample
with
the
rubber
stopper.
Alternatively,
any
leak—free closure fabricated of non—reactive materials and
accommodating
the
necessary
tubing
fittings
may
be
used.
2.2.14
Critical
Orifices.
Calibrated
critical
orifices
capable
of providing constant flow rates from 50 to 250 ml/min at known
pressure drops.
Sapphire orifice assemblies
(available from
O’Keefe Controls Company) and glass capillary tubing have been
219
found to be adequate for this application.
2.2.15
Vacuum
Gauge.
0-
to
760-mm
(0-
to
30-in.)
Hg
U-Tube
manometer
or
vacuum
gauge.
2.2.16
Pressure
Gauge.
Bourdon
gauge
capable
of
measuring
the
maximum air pressure at the aspirator inlet
(e.g.,
100 psig).
2.2.17
Aspirator.
A
device
capable
of
generating
sufficient
vacuum
at
the
sample
vessel
to
create
critical
flow
through
the
calibrated
orifice
when sufficient air pressure is present at the
aspirator
inlet.
The
aspirator
must
also
provide
sufficient
sample
pressure
to
operate
the
FIA.
The
sample
is
also
mixed
with
the
dilution
gas
within
the
aspirator.
2.2.18
Soap Bubble Meter.
Of an appropriate size to calibrate
the
critical
orifices
in
the
system.
2.2.19
Organic Concentration Analyzer.
An FIA with a span value
of
1.5
times
the
expected concentration as
propane;
however
other
span values may be used if it can be demonstrated that they would
provide more accurate measurements.
The system shall be capable
of
meeting
or
exceeding
the
following
specifications:
2.2.19.1
Zero
Drift.
Less
than
±3.0 percent
of
the
span
value.
2.2.19.2
Calibration
Drift.
Less
than
±3.0 percent
of
span
value.
2.2.19.3
Calibration
Error.
Less
than
±5.0 percent
of
the
calibration gas value.
2.2.20
Integrator/Data
Acquisition
System.
An
analog
or
digital
device or computerized data acquisition system used to integrate
the FIA response or
compute
the
average
response
and
record
measurement data.
The minimum data sampling frequency for
computing average or integrated values is one measurement value
every
5
seconds.
The
device
shall
be
capable
of
recording
average
values
at
least
once
per
minute.
2.2.21
Chart Recorder
(Optional).
A chart recorder or similar
device
is recommended to provide a continuous analog display of
the
measurement
results
during
the
liquid
sample
analysis.
2.2.22
Calibration
and
Other
Gases.
For
calibration,
fuel,
and
combustion
air
(if
required)
contained
in
compressed
gas
cylinders.
All
calibration
gases
shall
be
traceable
to
NIST
standards
and
shall
be
certified
by
the
manufacturer
to
±1
percent
of
the
tag
value.
Additionally,
the
manufacturer
of
the
cylinder
should
provide
a
recommended
shelf
life
for
each
calibration
gas
cylinder
over
which
the
concentration
does
not
change more than ±2percent from the certified value.
For
220
calibration
gas
values
not
generally
available,
alternative
methods
for
preparing
calibration
gas
mixtures,
such
as
dilution
systems,
may
be
used
with
prior
approval.
2.2.22.1
Fuel.
A 40 percent H2/60 percent He or 40 percent
H2/60
percent
N2
gas
mixture
is
recommended
to avoid an oxygen
synergism effect thatreportedly occurs when oxygen concentration
varies significantly from a mean value.
2.2.22.2
Carrier
Gas.
High
purity
air
with
less
than
1
ppm
of
organic material
(as propane) or less than 0.1 percent
of
the
span
value,
whichever
is greater.
2.2.22.3
FIA Linearity Calibration Gases.
Low-, mid—,
and
high—range
gas
mixture
standards
with
nominal
propane
concentrations of 20—30,
45-55,
and 70—80 percent of the span
value
in
air,
respectively.
Other
calibration
values
and
other
span values may be used if it
can
be
shown
that
more
accurate
measurements would be achieved.
2.2.22.4
System Calibration Gas.
Gas mixture standard
containing propane in air, approximating the undiluted VOC
concentration expected for the
liquid
samples.
3.
DETERMINATION OF LIQUID INPUT WEIGHT
3.1
Weight
Difference.
Determine
the
amount
of
material
introduced to the process as the weight difference
of
the
feed
material before and after each
sampling
run.
In
determining
the
total
VOC
containing
liquid
usage,
account
for:
(a)
the
initial
(beginning) VOC containing liquid mixture;
(b)
any
solvent
added
during
the
test
run;
(c)
any
coating
added
during
the test run;
and
(d)
any
residual
VOC
containing
liquid
mixture
remaining
at
the
end
of
the
sample
run.
3.1.1
Identify
all
points
where
VOC
containing
liquids
are
introduced
to
the
process.
To
obtain
an
accurate
measurement
of
VOC containing
liquids,
start
with
an
empty
fountain
(if
applicable).
After completing the run, drain the liquid
in
the
fountain back into the liquid drum (if possible), and
weigh
the
drum again.
Weigh
the
VOC
containing
liquids
to
~O.5 percent of
the
total
weight
(full)
or
±0.1 percent
of
the
total
weight
of
VOC
containing
liquid
used
during
the
sample
run,
whichever
is
less.
If the residual liquid cannot be returned to the drum,
drain the fountain into a preweighed empty drum to determine the
final
weight
of
the
liquid.
3.1.2
If it is not
possible
to
measure
a
single
representative
mixture, then weigh
the
various
components
separately
(e.g.,
if
solvent
is added during the sampling run, weigh the solvent
before it is added to the mixture).
If a fresh drum of VOC
containing liquid is needed during the run,
then
weigh
both
the
221
empty
drum
and fresh drum.
3.2
Volume Measurement (Alternative).
If direct weight
measurements are not feasible, the tester may use volume meters
and flow rate meters (and density measurements) to determine the
weight of liquids used if it can be demonstrated that the
technique produces results equivalent to the direct weight
measurements.
If a single representative mixture cannot be
measured, measure the components separately.
4.
DETERMINATION OF VOC CONTENT IN INPUT LIQUIDS
4.1
Collection of Liquid Samples.
4.1.1
Collect a 100-ml or larger sample of the VOC containing
liquid mixture at each application location at the beginning and
end of each test run.
A separate sample should be taken of each
VOC containing liquid added to the application mixture during the
test run.
If a fresh drum is needed during the sampling run,
then obtain a sample from the fresh drum.
4.1.2
When
collecting the sample, ground the sample container to
the coating drum.
Fill the sample container as close to the rim
as possible to minimize the amount of headspace.
4.1.3
After the sample is collected, seal the container so the
sample cannot leak out or evaporate.
4.1.4
Label the container to identify clearly the contents.
4.2
Liquid Sample VOC Content.
4.2.1
Assemble the liquid VOC content analysis system as shown
in Figure
1.
4.2.2
Permanently identify all of the critical orifices that may
be used.
Calibrate each critical orifice under the expected
operating conditions
(i.e.,
sample vacuum and temperature)
against a volume meter as described in Section 5.3.
4.2.3
Label and tare the sample vessels (including the stoppers
and caps) and the syringes.
4.2.4
Install an empty sample vessel and perform a leak test of
the system.
Close the carrier gas valve and atmospheric vent and
evacuate the sample vessel to 250 mm
(10 in.) Hg absolute or less
using the aspirator.
Close the toggle valve at the inlet to the
aspirator and observe the vacuum for at least one minute.
If
there is any change in the sample pressure, release the vacuum,
adjust or repair the apparatus as necessary and repeat the leak
test.
222
4.2.5
Perform the analyzer calibration and linearity checks
according to the procedure in Section 5.1.
Record the responses
to each of the calibration gases and the back—pressure setting of
the FIA.
4.2.6
Establish the appropriate dilution ratio by adjusting the
aspirator air supply or substituting critical orifices.
Operate
the aspirator at a vacuum of at least 25 mm
(1 in.) Hg greater
than the vacuum necessary to achieve critical flow.
Select the
dilution ratio so that the maximum response of the FIA to the
sample does not exceed the high-range calibration gas.
4.2.7
Perform system calibration checks at two levels by
introducing compressed gases at the inlet to the sample vessel
while the aspirator and dilution devices are operating.
Perform
these checks using the carrier gas
(zero concentration)
and the
system calibration gas.
If the response to the carrier gas
exceeds ±0.5percent of span, clean or repair the apparatus and
repeat the check.
Adjust the dilution ratio as necessary to
achieve the correct response to the upscale check, but do not
adjust the analyzer calibration.
Record the identification of
the orifice, aspirator air supply pressure, FIA back—pressure,
and the responses of the
FIA
to the carrier and system
calibration gases.
4.2.8
After completing the above checks,
inject the system
calibration gas for approximately 10 minutes.
Time the exact
duration of the gas injection using a stopwatch.
Determine the
area under the FIA response curve and calculate the system
response factor based on the sample gas flow rate, gas
concentration, and the duration of the injection as compared to
the integrated response using Equations
2 and
3.
4.2.9
Verify that the sample oven and sample line temperatures
are 120 ±5oCand that the water bath temperature is 100
±5oC.
4.2.10
Fill a tared syringe with approximately
1 g of the VOC
containing liquid and weigh it.
Transfer the liquid to a tared
sample vessel.
Plug the sample vessel to minimize sample loss.
Weigh the sample vessel containing the liquid to determine the
amount of sample actually received.
Also,
as a quality control
check, weigh the empty syringe to determine the amount of
material delivered.
The two coating sample weights should agree
within ±0.02g.
If not, repeat the procedure until an acceptable
sample is obtained.
4.2.11
Connect the vessel to the analysis system.
Adjust the
aspirator supply pressure to the correct value.
Open the valve
on the carrier gas supply to the sample vessel and adjust it to
provide a slight excess flow to the atmospheric vent.
As soon as
the initial response of the FIA begins to decrease,
immerse the
223
sample vessel in the water bath.
(Applying heat to the sample
vessel too soon may cause the FID response to exceed the
calibrated range of the instrument, and thus invalidate the
*analysis.)
4.2.12
Continuously measure and record the response of the FIA
until all of the volatile material has been evaporated from the
sample and the instrument response has returned to the baseline
(i.e.,
response less than 0.5 percent of the span value).
Observe the aspirator supply pressure, FIA back—pressure,
atmospheric vent,
and other system operating parameters during
the run; repeat the analysis procedure if any of these parameters
deviate from the values established during the system calibration
checks in Section 4.2.7.
After each sample perform the drift
check described in Section
5.2.
If
the drift check results are
acceptable, calculate the VOC content of the sample using the
equations in Section
7.
Integrate
the
area under the FIA
response curve, ordetermine the average concentration response
and the duration of sample analysis.
5.
CALIBRATION
AND QUALITY ASSURANCE
5.1
FIA Calibration and Linearity Check.
Make necessary
adjustments to the air and fuel supplies for the FIA and ignite
the burner.
Allow the FIA to warm up for the period recommended
by the manufacturer.
Inject a calibration gas into the
measurement system and adjust the back-pressure regulator to the
value required to achieve the flow rates specified by the
manufacturer.
Inject the zero— and the high—range calibration
gases and adjust the analyzer calibration to provide the proper
responses.
Inject the low- and mid-range gases and record the
responses of the measurement system.
The calibration and
linearity of the system are acceptable if the responses for all
four gases are within
5 percent of the respective gas values.
If
the performance of the system is not acceptable,
repair or adjust
the system and repeat the linearity check.
Conduct a calibration
and linearity check after assembling the analysis system and
after a major change is made to the system.
5.2
Systems Drift Checks.
After each sample, repeat the system
calibration checks in Section 4.2.7 before any adjustments to the
FIA or measurement system are made.
If the zero or calibration
drift exceeds ±3percent of the span value, discard the result
and repeat the analysis.
5.3
Critical Orifice Calibration.
5.3.1
Each critical orifice must be calibrated at the specific
operating conditions that it will be used.
Therefore,
assemble
all components of the liquid sample analysis system as shown in
Figure
3.
A stopwatch is also required.
224
5.3.2
Turn on the sample oven,
sample line, and water bath
heaters and allow the system to reach the proper operating
temperature.
Adjust the aspirator to a vacuum of 380 mm
(15 in.)
Hg vacuum.
Measure the time required for one soap bubble to move
a known distance and record barometric pressure.
5.3.3
Repeat the calibration procedure at a vacuum of 406 mm
(16
in.) Hg and at 25-mm
(1-in.) Hg intervals until three consecutive
determinations provide the same flow rate.
Calculate the
critical flow rate for the orifice in mi/mm
at standard
conditions.
Record the vacuum necessary to achieve critical
flow.
6.
NOMENCLATURE
AL
=
area under the response curve of the liquid sample,
area count.
=
area under the response curve of the calibration gas,
area count.
=
actual concentration of system calibration gas, ppm
propane.
K
= 1.830
x 10~g/(ml-ppm).
L =
total VOC content of
liquid
input,
kg.
=
mass of liquid sample delivered to the sample vessel,
g.
q
=
flow rate through critical orifice, mi/mm.
RF = liquid
analysis system response factor, g/area count.
=
total gas injection time
for system calibration gas
during integrator calibration, mm.
VFJ
=
final VOC fraction of VOC containing liquid
j.
V11
=
initial VOC fraction of VOC containing liquid
j.
VAJ
=
VOC fraction of VOC containing liquid
j
added during
the run.
V
=
VOC fraction of liquid sample.
WFJ
=
weight of VOC containing liquid
j
remaining at end of
the run, kg.
W11
=
weight of VOC containing liquid
j
at beginning of the
run, kg.
225
=
weight of VOC containing liquid
j
added during the run,
kg.
226
7.
CALCULATIONS
7.1
Total VOC Content of the Input VOC Containing Liquid.
L
=
V~1W~-
E
\~ WFJ +
E
V~1WAJ
Eq.
1
7.2
Liquid Sample Analysis System Response Factor for Systems
Using Integrators, Grams/Area Counts.
C~qT~K
Eq.
2
RF=
____________
A~
7.3
VOC Content of the Liquid Sample.
ALRF
Eq.
3
ML
Procedure T
-
Criteria for and Verification of a Permanent
or Temporary Total Enclosure
1.
INTRODUCTION
1.1
Applicability.
This procedure is used to determine whether
a permanent or temporary enclosure meets the criteria of a total
enclosure.
1.2
Principle.
An enclosure is evaluated against a set of
criteria.
If the criteria are met and if all the exhaust gases
are ducted to a control device, then the volatile organic
compounds
(VOC)
capture efficiency
(CE)
is assumed to be 100
percent and CE need not be measured.
However,
if part of the
exhaust gas stream is not ducted to a control device,
CE must be
determined.
2.
DEFINITIONS
2.1
Natural Draft Opening
(NDO)
--
Any permanent opening in the
enclosure that remains open during operation of the facility and
is not connected to a duct in which a fan is installed.
2.2
Permanent Total Enclosure
(PTE)
--
A permanently installed
enclosure that completely surrounds a source of emissions such
that all VOC emissions are captured and contained for discharge
through a control device.
2.3
Temporary Total Enclosure
(TTE)
--
A temporarily installed
enclosure that completely surrounds a source of emissions such
227
that all VOC emissions are captured and contained for discharge
through ducts that allow for the accurate measurement of VOC
rates.
3.
CRITERIA OF A TEMPORARY TOTAL ENCLOSURE
3.1
Any
NDO
shall be at least
4 equivalent opening diameters
from each VOC emitting point.
3.2
Any exhaust point from the enclosure shall be at least
4
equivalent duct or hood diameters from each NDO.
3.3
The total area of all NDO’s shall not exceed 5 percent of
the surface area of the enclosure’s four walls,
floor, and
ceiling.
3.4
The average facial velocity
(FV)
of air through all NDO’s
shall be at least 3,600 m/hr
(200 fpm).
The direction of air
through all NDO’s shall be into the enclosure.
3.5
All access doors and windows whose areas are not included in
Section 3.3 and are not included in the calculation in Section
3.4 shall be closed during routine operation of the process.
4.
CRITERIA OF A PERMANENT TOTAL ENCLOSURE
4.1
Same as Sections 3.1 and 3.3
—
3.5.
4.2
All VOC emissions must be captured and contained for
discharge through a control device.
5.
PROCEDURE
5.1
Determine the equivalent diameters of the NDO’s and
determine the distances from each VOC emitting point to all
NDO’s.
Determine the equivalent diameter of each exhaust duct or
hood and its distance to all NDO’s.
Calculate the distances in
terms of equivalent diameters.
The number of equivalent
diameters shall be at least 4.
5.2
Measure the total area
(Ar)
of the enclosure and the total
area
(AN)
of all NDO’s of the enclosure.
Calculate the
NDO
to
enclosure area ratio
(NEAR)
as follows:
NEAR
=
The NEAR must be
0.05.
5.3
Measure the volumetric flow rate, corrected to standard
conditions,
of each gas stream exiting the enclosure through an
exhaust duct or hood using EPA Method 2.
In some cases
(e.g.,
when the building is the enclosure),
it may be necessary to
228
measure the volumetric flow rate, corrected to standard
conditions,
of each gas stream entering the enclosure through a
forced makeup air duct using Method
2.
Calculate FV using the
following equation:
FV
=
Q0
—
Q1/
A11
where:
Q0
=
the sum of the volumetric flow from all gas streams
exiting the enclosure through an exhaust duct or
hood.
Q1
=
the sum of the volumetric flow from all gas streams
into the enclosure through a forced makeup air duct;
zero,
if there is no forced makeup air into the
enclosure.
AN
=
total area of all NDO’s in enclosure.
The FV shall be at least 3,600 m/hr (200 fpm).
5.4
verify that the direction of air flow through all NDO’s is
inward.
Use streamers,
smoke tubes, tracer gases, etc.
Strips
of plastic wrapping film have been found to be effective.
Monitor the direction of air flow at intervals of at least 10
minutes for at least 1 hour.
6.
QUALITY
ASSURANCE
6.1
The success of this protocol lies in designing the TTE to
simulate the conditions that exist without the TTE,
i.e., the
effect of the TTE on the normal flow patterns around the affected
facility or the amount of fugitive VOC emissions should be
minimal.
The
TTE
must enclose the application stations, coating
reservoirs,
and all areas from the application station to the
oven.
The oven does not have to be enclosed if it is under
negative pressure.
The NDO’s of the temporary enclosure and a
fugitive exhaust fan must be properly sized and placed.
6.2.
Estimate the ventilation rate of the TTE that best
simulates the conditions that exist without the TTE,
i.e., the
effect of the TTE on the normal flow patterns around the affected
facility or the amount of fugitive VOC emissions should be
minimal.
Figure
1 may be used as an aid.
Measure the
concentration
(C3) and flow rate
(Q3)
of the captured gas stream,
specify a safe concentration
(Cf)
for the fugitive gas stream,
estimate the CE, and then use the plot in Figure
1 to determine
the volumetric flowrate of the fugitive gas stream
(Qf).
A
fugitive VOC emission exhaust fan that has a variable flow
control is desirable.
229
6.2.1
Monitor the concentration of VOC into the capture device
without the TTE.
To minimize the effect of temporal variation on
the captured emissions, the baseline measurement should be made
over as long a time period as practical.
However, the process
conditions must be the same for the measurement in Section 6.2.3
as they are for this baseline measurement.
This may require
short measuring times for this quality control check before and
after the construction of the TTE.
6.2.2
After the TTE is constructed, monitor the VOC
concentration inside the TTE.
This concentration shall not
continue to increase and must not exceed the safe level according
to OSHA requirements for permissible exposure limits.
An
increase in VOC concentration indicates poor TTE design or poor
capture efficiency.
6.2.3
Monitor the concentration of VOC into the capture device
with the TTE.
To limit the effect of the TTE on the process, the
VOC concentration with and without the TTE must be within ±10
percent.
If the measurements do not agree, adjust the
ventilation rate from the TTE until they agree within 10 percent.
230
Appendix C
Reference Methods and Procedures
Introduction
This Appendix presents the reference methods and procedures
required for implementing Reasonably Available Control Technology
(RACT).
Methods and procedures are identified for two types of
ACT implementation:
a) Determination of VOC destruction efficiency for evaluating
compliance with the 98 weight percent VOC reduction or 20 ppmv
emission limit specified in Sections 215.520 through 215.527;
and
b) Determination of offgas flowrate, hourly emissions and stream
net heating value for calculating TRE.
All reference methods identified in this Appendix refer to the
reference methods specified at 40 CFR 60, Appendix A,
incorporated by reference in Section 215.105.
VOC DESTRUCTION EFFICIENCY DETERMINATION
The following reference methods and procedures are required for
determining compliance with the percent destruction efficiency
specified in Sections 215.520 through 215.527.
a) Reference Method
1 or lA for selection of the sampling site.
The control device inlet sampling site for determination of
vent stream molar composition or total organic compound
destruction efficiency shall be prior to the inlet of any
control device and after all recovery devices.
b) Reference Methods
2,
2A,
2C or 2D for determination of the
volumetric flowrate.
c) Reference Method
3 to measure oxygen concentration of the air
dilution correction.
The emission sample shall be corrected
to 3 percent oxygen.
d) Reference Method 18 to determine the concentration of total
organic compounds (minus methane and ethane)
in the control
device outlet and total organic compound reduction efficiency
of the control device.
TRE DETERMINATION
The following reference methods and procedures are required for
determining the offgas flowrate, hourly emissions,
and the net
heating value of the gas combusted to calculate the vent stream
TRE.
231
a) Reference Method
1 or lÀ for selection of the sampling site.
The sampling site for the vent stream flowrate and molar
composition determination prescribed in
(b) and
(c)
shall be
prior to the inlet of any combustion device, prior to any
post—reactor dilution of the stream with air and prior to any
post-reactor introduction of halogenated compounds into the
vent stream.
Subject to the preceding restrictions on the
sampling site,
it shall be after the final recovery device.
If any gas stream other than the air oxidation vent stream is
normally conducted through the recovery system of the affected
facility, such stream shall be rerouted or turned off while
the vent stream is sampled, but shall be routed normally prior
to the measuring of the initial value of the monitored
parameters
for determining compliance with the recommended
RACT.
If the air oxidation vent stream is normally routed
through any equipment which is not
a part of the air oxidation
process as defined in 35
Ill. Adm. Code 211.122, such
equipment shall be bypassed by the vent stream while the vent
stream is sampled, but shall not be bypassed during the
measurement of the initial value of the monitored parameters
for determining compliance with Subpart V.
b) The molar composition of the vent stream shall be determined
using the following methods:
1)
Reference Method 18 to measure the concentration of all
organics, including those containing halogens, unless a
significant portion of the compounds of interest are
polymeric (high molecular weight), can polymerize before
analysis or have low vapor pressures,
in which case
Reference Method 25(a)
shall be used.
2)
ASTN D1946-67
(reapproved 1977),
incorporated by reference
in Section 215.105, to measure the concentration of carbon
monoxide and hydrogen.
3)
Reference Method
4 to measure the content of water vapor,
if necessary.
C)
The volumetric flowrate shall be determined using Reference
Method
2,
2A,
2C or 2D, as appropriate.
ci) The net heating value of the vent stream shall be calculated
using the following equation:
n
H=K
E
CiHi
i=1
232
Where:
H
=
Net heating value of the sample, MJ/scm, where the net
enthalpy per mole of offgas
is based on combustion at
25°Cand 760 mm Hg, but the standard temperature for
determining the volume corresponding to one mole is
20°C,as in the definition of F (vent stream flowrate)
below.
K
=
Constant, 1.740 x l0~~
(1/ppm)
(mole/scm) (MJ/kcal)
where standard temperature for mole/scm is 20°C.
Ci
Concentration of sample component
i, reported on a wet
basis,
in ppm, as measured by Reference Method 18 or
ASTM D1946-67
(reapproved 1977), incorporated by
reference in Section 215.105.
Hi
=
Net heat of combustion of sample component i,
kcal/mole based on combustion at 25 C and 760 mm Hg.
If published values are not available or cannot be
calculated,
the heats of combustion of vent stream
components are required to be determined using ASTM
D2382-76, incorporated by reference in Section
215. 105.
e) The emission rate of total organic compounds in the process
vent stream shall be calculated using the following equation:
n
E=K
F
E
CiMi
i=1
Where:
E
=
Emission rate of total organic compounds (minus
methane and ethane)
in the sample in kg/hr.
K
=
Constant 2.494 x 106 (1/ppm)
(mole/scm)
(kg/g)
(min/hr), where standard temperature for
(mole/scm)
is 20°C.
Mi
=
Molecular weight of sample component
i
(g/mole).
F
=
Vent stream flowrate (scm/mm), at a standard
temperature of 20°C.
f) The total vent stream concentration
(by volume)
of compounds
containing halogens
(ppmv, by compound) shall be summed from
the individual concentrations of compounds containing halogens
233
which were measured by Reference Method 18.
234
Appendix D
Coefficients for the Total Resource Effectiveness
Index
(TRE)
Equation
This Appendix contains values for the total resource
effectiveness index
(TRE) equation in Subpart V.
If a flow rate falls exactly on the boundary between the
indicated ranges, the operator shall use the row in which the
flow rate is maximum.
COEFFICIENTS FOR TRE EQUATION
FOR CHLORINATED PROCESS VENT STREAMS WITH
NET HEATING VALUE LESS
THAN
OR EQUAL TO 3.5
MJ/scm
FLOW RATE
(scm/mm)
Mm.
Max.
a
b
c
d
e
f
FLOW RATE
(scm/mm)
Mm.
Max.
0.0
13.5
48.73
0.
0.404
—0.1632
0.
0.
13.5
700.
42.35
0.624
0.404
—0.1632
0.
0.0245
700.
1400.
84.38
0.678
0.404
—0.1632
0.
0.0346
1400.2100.
126.41
0.712
0.404
—0.1632
0.
0.0424
2100.2800.
168.44
0.747
0.404
—0.1632
0.
0.0490
2800.3500.
210.47
0.758
0.404
—0.1632
0.
0.0548
FOR
NET
COEFFICIENTS
FOR TRE EQUATION
CHLORINATED PROCESS VENT STREAMS WITH
HEATING VALUE GREATER
THAN
3.5 NJ/scm
0.
13.5
47.76
0.
—0.292
0.
0.
0.
13.5
700.
41.58
0.605 —0.292
0.
0.
0.0245
700.
1400.
82.84
0.658 —0.292
0.
0.
0.0346
1400. 2100.
123.10
0.691 —0.292
0.
0.
0.0424
2100. 2800.
165.36
0.715 —0.292
0.
0.
0.0490
2800. 3500.
206.62
0.734 —0.292
0.
0.
0.0548
a
b
c
d
e
f
235
0.
13.5
13.5 1350.
1350. 2700.
2700. 4050.
COEFFICIENTS FOR TRE EQUATION
FOR NONCHLORINATED PROCESS VENT STREAMS WITH
NET HEATING VALUE LESS
THAN
OR EQUAL TO 0.48 NJ/scm
19.05
16.61
32.91
49.21
0.
0.
0.
0.
0.
0.0245
0.0346
0. 0424
0.
13.5
13.5
1350.
1350. 2700.
2700. 4050.
COEFFICIENTS
FOR TRE EQUATION
FOR NONCHLORINATED
PROCESS VENT STREAMS WITH NET HEATING VALUE
GREATER
THAN
0.48 AND LESS THAN OR
EQUAL TO 1.9 NJ/scm
19.74
18.30
36.28
54.26
0.
0.
0.
0.
0.
0.0245
0.0346
0. 0424
FLOW RATE
(scm/mm)
Mm.
Max.
a
b
c
d
e
f
0.
0.113
—0.214
0.239
0.113
—0.214
0.260
0.113
—0.214
0.273
0.113
—0.214
FLOW RATE
(scm/mm)
Mm.
Max.
a
b
c
d
e
£
0.
0.400
—0.202
0.138
0.400
—0.202
0.150
0.400
—0.202
0.158
0.400
—0.202
236
COEFFICIENTS
FOR TRE EQUATION FOR NONCHLORINATED
PROCESS VENT STREAMS WITH NET HEATING VALUE
GREATER
THAN
1.9
AND
LESS
THAN
OR
EQUAL TO 3.6
NJ/scm
FLOW RATE
(scm/mm)
a
b
c
ci
e
f
COEFFICIENTS
FOR TRE EQUATION
FOR NONCHLORINATED PROCESS VENT STREAMS WITH
NET HEATING VALUE
GREATER
THAN
3.6
MG/scm
Mm.
Max.
a
IT IS SO ORDERED.
b
c
d
e
f
J. Marlin and J.D. Dumelle were not present.
I, Dorothy M. Gunn,
Clerk of the Illinois Pollution Control
Board, hereby Certify_that the abov
Opinion and Order was
adopted on the
//T.S
day of
________________,
1991,
by
a vote
of
~‘-O
.
t~~4i
~.
Dorothy N. G~nn,Cler1~
Illinois Polaution Control Board
FLOW RATE
(scm/mm)
Mm.
Max.
.0
13.5
15.24
0.
0.033
0.
0.
13.5
1190.
13.63
0.157
0.033
0.
0.
1190.2380.
26.95
0.171
0.033
0.
0.
2380.3570.
40.27
0.179
0.033
0.
0.
0.
13.5
13.5
1190.
1190. 2380.
2380. 3570.
0.
0. 0245
0. 0346
0.0424
0.
0. 0245
0. 0346
0. 0424
15.24
13
.
63
26.95
40.27
0.
0.
0.
0.
0.
0.
0.
0.
0. 0090
0.0090
0. 0090
0. 0090
0.
0. 0503
0.0546
0.0573
