ILLINOIS POLLUTION CONTROL BOARD
    March 16,
    1995
    IN THE MATTER OF:
    )
    15
    ROP
    PLAN
    CONTROL MEASURES
    )
    FOR VOM EMISSIONS
    -
    PART VII:
    )
    P.94—33
    BATCH
    OPERATIONS:
    )
    (Rulemaking
    -
    Air)
    AMENDMENTS TO 35
    ILL.
    ADM.
    )
    CODE PARTS
    211,
    218 AND
    219
    )
    Proposed Rule.
    Second Notice.
    OPINION AND ORDER OF THE
    BOARD
    (by R.C. Flemal):
    This matter comes before the Board on the November
    14,
    1994
    filing by the Illinois Environmental Protection Agency
    (Agency)
    of a proposal for rulemaking.
    The proposal
    in intended to
    implement portions of the federal Clean Air Act.
    Section 182(b)
    (1)
    of the Clean Air Act
    (42 U.S.C.
    7511(b) (1)) requires all moderate and above ozone nonattainment
    areas to achieve a 15
    reduction of 1990 emissions of volatile
    organic material
    (VOM)
    by 1996.
    The Chicago and Metro-East St.
    Louis areas are classified as “severe” and “moderate”
    nonattainment for ozone, respectively, and are subject to the 15
    reduction requirement.
    Today’s proposal represents Part VII of
    the rulemakings anticipated
    in Illinois’
    15
    Rate of Progress
    Plan and one part of Illinois’ submittal of a complete state
    implementation plan
    (SIP)
    for the control of ozone.
    Today’s
    proposal seeks to amend
    35 Iii. Adm. Code 211, 218 and 219.
    The Board’s responsibility in this matter arises from the
    Environmental Protection Act
    (Act)
    (415 ILCS 5/1 et seq.
    (1992)).
    The Board
    is charged therein to “determine, define and implement
    the environmental control standards applicable
    in the State of
    Illinois”
    (415 ILCS 5/5(b)).
    This proposal was filed pursuant to
    Section 28.5 of the Act as a fast-track rulemaking proceeding.
    (415 ILCS 5/28.5 (1992).)
    Section 28.5 of the Act requires the
    Board to proceed with rulemaking under set time—frames.
    The
    Board has no discretion to adjust these time—frames under any
    circumstances.
    Today the Board acts to send this proposal to second notice.
    The Clerk shall cause the filing of the attached order with the
    Joint Committee on Administrative Rules pursuant to Section
    5 of
    the Administrative Procedures Act
    (APA).
    (5 ILCS 100/1005-40
    (1992).)
    2
    PROCEDURAL
    HISTORY
    Pursuant to Section 28.5 of the Act, the Board on November
    18,
    1994 sent this proposal to first notice under the APA without
    commenting on the merits of the proposal.
    The proposal was
    published in the Illinois Register on December
    16,
    1994 as
    follows:
    Section
    211 was published at 18
    Ill.
    Reg. 17808;
    Section 218 was published at 18
    Ill.
    Reg.
    17823; and Section 219
    was published at 18
    Ill. Reg.
    17844.
    Hearing was held in this matter on January
    4,
    1995,
    in
    Chicago,
    Illinois, before hearing officer Audrey Lozuk-Lawless.
    The Board has also received six public comments, which are
    discussed in detail below.
    PROPOSAL
    The proposed rules are intended to provide for control of
    VON emissions from chemical processes operating in a batch or
    non—continuous mode.
    The rules would be implemented by
    amendments to 35 Ill.
    Adm. Code Part 211,
    218 and 219,
    Subpart V.
    Sources that are intended to be covered are all batch
    operations at sources identified by specific standard industrial
    classifications
    (SIC)
    codes.
    The codes, as defined in the
    1987
    edition of the Standard Industrial Classification Manual, are
    codes that cover manufacture as a primary product or
    intermediate,
    any chemical identified by the following:
    plastic
    materials and resins (SIC 2821), pharmaceutical preparations
    (2834), medicinal chemicals and botanical production
    (SIC 2833),
    gum and wood chemicals
    (SIC 2861),
    cyclic crudes and
    intermediates
    (SIC 2865),
    industrial organic chemicals
    (SIC
    2869),
    and agricultural chemicals
    (SIC 2879)~.
    The geographic areas subject to this proposal are the
    Chicago and Metro—East St. Louis ozone nonattainment areas as
    defined in 35
    Ill.
    Adm. Code 218.103 and 219.103.
    The Agency has identified eighteen affected facilities
    located within these areas, with the majority of affected
    The rule also explicitly applies to all batch operations
    at Stepan Company’s Millsdale manufacturing facility located in
    Elwood,
    Illinois, regardless of SIC codes.
    (See proposed Section
    218.500(a) (2).)
    As Stepan Company observes
    (PC #6 at
    2), the
    Milisdale facility has certain batch operations that do riot fit
    into the specified codes, but which nevertheless are chemically
    and operationally similar to those that do.
    3
    facilities located in the Chicago ozone nonattainment area.
    The
    Agency has undertaken various outreach activities with these
    affected industries and industrial associations, including
    meeting with interested persons and distributing drafts of the
    proposal among them.
    (Statement of Reasons at 6-7.)
    The Agency contends that the control programs as proposed
    are designed to allow compliance at a cost of less than $2,500
    per ton of VON reduced.
    (Statement of Reasons at
    6.)
    The United
    States Environmental Protection Agency
    (USEPA)
    estimates that the
    cost effectiveness of controlling VOM emissions from batch
    processes is
    $2,500 per ton.
    (~.
    at 5.)
    TESTIMONY AND COMMENTS
    The Board received the following six public comments in this
    rulemaking:
    PC #1
    Comments of the Illinois Department of
    Commence and Community Affairs;
    PC #2
    Comments of the Administrative Code Division
    of the Illinois Secretary of State;
    PC #3
    Comments of the City of Chicago Department of
    Environment;
    PC
    //4
    Comments of the Illinois Environmental
    Protection Agency;
    PC #5
    Comments of the Illinois Environmental
    Regulatory Group;
    and
    PC #6
    Comments of Stepan Company.
    The Board has considered all public comments,
    as well as all
    testimony and exhibits,
    in making its decisions in this matter.
    The following is a summary of the major issues raised in comments
    and during the hearing process.
    A.
    Comments of the Illinois Department of Commerce and
    Community Affairs
    The comment from the Illinois Department of Commerce and
    Community Affairs
    (DCCA)
    states that DCCA has reviewed the
    proposal and determined that it will not significantly impact
    small businesses.
    DCCA defers to the findings from hearings
    conducted by the Board and written public comment to the Board.
    4
    B.
    Comments of the Administrative Code Division of the Illinois
    Secretary of State
    The comment of the Administrative Code Division recommends
    various nonsubstantive form and typographical corrections.
    The
    Board accepts these recommendations and incorporates them into
    today’s second notice proposal.
    C.
    Comments of the City
    of Chicago Department of Environment
    The Chicago Department of Environment
    (CDOE)
    recognizes that
    the proposed rulemaking will impact Chicago area industry;
    CDOE
    nevertheless supports the proposed rulemaking.
    CDOE states that
    the targeted VOM reduction level of
    12 tons per day
    is a
    necessary and significant step toward reducing VOM emissions in
    this region as required by the Clean Air Act.
    CDOE also believes
    this proposal will not only help the region reach ozone
    attainment, but result in positive environmental and health
    benefits.
    D.
    Comments of the Illinois Environmental Protection Agency,
    Illinois Environmental Regulatory Group, and Stepan Company
    Substantive issues have been addressed in public comment
    by
    the Agency
    (PC #4), the Illinois Environmental Regulatory Group
    (IERG
    -—
    PC #5), and the Stepan Company
    (Stepan
    —-
    PC #6).
    Most
    of these issues originally arose during discussions at the
    January
    4,
    1995 hearing, and the public comments represent the
    response of the three parties to these discussions.
    Included are
    a number of changes recommended by the Agency
    in response to
    concerns of IERG and Stepan.
    1)
    Sections
    218.505 and 219.505, Reporting/Recordkeeping
    Requirements for Owners and Operators
    IERG proposes that the recordkeepirig/reporting requirement
    for flares,
    found at Sections 218.505 and
    219.505, be limited to
    the maintenance of records of the flare pilot flame monitoring,
    and record of all periods of operations during which the pilot
    flame
    is absent.
    (PC #5
    at
    2.)
    In response to this proposal,
    the Agency recommends that the Board delete a portion of the
    first notice Sections 218.505(c)
    (2)
    and 219.505(c) (2)
    .
    (PC #4
    at
    8.)
    The Board accepts the Agency’s proposed deletion for the
    purposes of second notice.
    (See Sections 218.505(c) (2) and
    219.505(c) (2).)
    2)
    Sections 218.502(b) (2)
    and 219.502(b) (2)
    and Sections
    218.503(f) (3) (A) (iii)
    and 219.503(f) (3) (A) (iii),
    Definition of Emission Event
    5
    IERG and Stepan claim that the proposal needs to address the
    zero flow rate situation, wherein a batch cycle sits for a period
    of time prior to the process continuing; failure to consider zero
    flow rates could result in a flawed determination of
    applicability and/or control efficiency.
    (PC #5 at
    3; PC #6 at
    18.)
    IERG proposes language to clarify that an “emission event”
    is
    a “discrete period of venting that is associated with a single
    unit operation”,
    and “the zero flow rate period would not be an
    emission event for purposes of the Batch Processes Rule”.
    (PC #5
    at 3.)
    The Agency responds that if flow rates are measured in
    accordance with Section 218.502(f) (2)
    and the resulting flow rate
    measurement is equivalent to zero, then “such an event is not
    considered an emission event for purposes of this proposal”.
    (PC
    #4 at 8.)
    In addition, the Agency proposes additional language
    to Sections 218.502(b) (2) and 219.502(b) (2) and Sections
    218.503(f) (3) (iii)
    and 219.503(f) (3) (iii)
    that defines the term
    “emission event” and considers the situation where the flow rate
    for any emission event
    is zero.
    The Board accepts this expanded definitional language as
    proposed by the Agency and incorporates
    it into the second notice
    proposal.
    (See Sections 218.502(f) (2), 219.502(f) (2),
    218.503(f) (3) (A) (iii),
    and 219.503(f) (3) (A) (iii)
    .)
    3)
    Sections 218.503(f) (3) (A) and 219.503(f) (3) (A), Method
    25A and Method 18 Testing Procedure for Batch
    Processes
    IERG and Stepan propose that additional flexibility should
    be allowed when sampling batch cycles of eight hours or greater
    duration.
    (PC #5 at
    3; PC #6 at 13-17.)
    IERG claims that during
    review of the draft CTG and discussions with the USEPA’s Research
    Triangle Park staff and the Agency,
    it was agreed that
    alternative sampling strategy could be used for batch cycles of
    eight hours or greater duration that contain emission events
    greater than four hours.
    (PC #5 at
    4.)
    Stepan believes that
    emissions from these long events can be accurately quantified
    based on three one—hour samples taken during the emission event.
    (PC #6 at 16
    —
    17.)
    The Agency agrees with Stepan’s recommendation that an
    alternative sampling strategy be allowed.
    Specifically, the
    Agency now proposes the option of allowing either continuous
    testing or discrete testing in the form of a minimum of three
    one—hour samples for each emission event of greater than four
    hours at each single unit operation.
    (PC #4 at 5.)
    However, the
    Agency specifically proposes that
    if the facilities elect the
    discrete sampling option, an emission profile (developed using
    material balances and process stoichiometry) must be developed
    for the entire duration of the emission event and the facility
    6
    must demonstrate that the portion of the emissions event being
    tested defines the emissions profile for such emission event.
    (PC #4 at 5.)
    The Board accepts the Agency’s revised language and
    incorporates it into the second notice proposal.
    (See Sections
    218.503(f) (3) (i)
    and
    (ii), and Sections 219.503(f)(3)(i)
    and
    (ii).)
    4)
    Section 218.503(f)(3)(A)(i)
    and 219.503(f)(3)(A)(i),
    Time Period for Changing Out an Impinger Train under
    Method 18
    IERG and Stepan propose that the Board increase the maximum
    amount of time to change out an impinger train when testing under
    Method 18.
    Their proposal is to increase the time from a 15-
    minute interval to
    a maximum 30-minute interval.
    (PC #5 at
    4; PC
    #6 at 17—18.)
    The Agency agrees with IERG and Stepan that a 30-minute
    interval between measurements
    is acceptable, but only in the
    event that a change in the impinger train is necessary.
    Otherwise,
    the Agency proposes the 15—minute interval must not be
    exceeded2.
    (PC #4 at
    6.)
    The Board accepts the Agency’s addition and incorporates
    it
    into the second notice proposal.
    (See Section
    218.503(f) (3) (A) (i) and Section 219.503(f) (3) (A) (1).)
    5)
    Sections 218.502(a)
    and 219.502(a),
    Alternative
    Approach to Determine Uncontrolled Total Annual Mass
    Emissions of VON
    IERG proposes that an alternative method be included to
    allow an owner or operator, where total production
    is reflected
    in the data upon which a valid Agency permit is based, to
    determine applicability on the basis of annual production versus
    the actual number of cycles that occur during a given year.
    (PC
    #5 at 5;
    Tr. at 32.)
    Stepan also questions whether the Agency
    would agree to an alternative approach based on total production
    rather than the potential or permitted number of batch cycles.
    The Agency comments that “(i)f the permitted levels as
    reflected in Stepan’s operating permit correspond to total
    production,
    then the Agency would agree with Stepan’s proposal to
    allow the use of total production as an alternative to the use of
    potential or permitted number of batch cycles in calculating
    2
    The Agency’s comment cites Sections 218/219.503(f) (3) (i).
    The correct citation is 218/219.503 (if) (3) (A) (1)
    7
    uncontrolled mass emissions”.
    (PC #4 at 5.)
    In addition, the
    Agency proposes a definition for the term “emission event” within
    Sections 218.502 and 219.502.
    (PC #4 at 5.)
    The Board accepts the Agency’s additional language and
    incorporates it into the second notice proposal.
    (See Sections
    218.502(a) (2), 219.502(a),
    218.502(b),
    219.502(b),
    218.503(f) (3) (A) (iii),
    and 219.503(f) (3) (A) (iii).)
    6)
    Sections 218.503(i)
    and 219.503(i), Absence of Request
    by Agency to Conduct Performance Testing
    IERG suggests that the Agency clarify that when utilizing
    control devices other than flares or process boilers,
    in the
    absence of an Agency request to conduct performance testing,
    an
    owner or operator may demonstrate compliance by the use of
    engineering estimates or process stoichiometry.
    (PC #5 at 5.)
    The Agency agrees with IERG’s suggestion and has proposed
    additional
    language to specifically provide for the use of
    engineering estimates.
    (PC #4 at 8.)
    The Board accepts this additional language and incorporates
    it into the second notice proposal.
    (See Sections 218.503(i)
    and
    219.503(i).)
    7)
    Continuous Process Units
    Stepan proposes that the Board include clarification that
    in
    aggregating emissions from a process train,
    owners and operators
    (and Agency permit writers) should consider the following:
    “i)
    Is the unit used in more than one train?
    ii)
    Are the units
    interdependent?
    iii)
    Are the materials used chemically
    compatible?
    iv)
    Are the units geographically close and
    accessible?
    v)
    Are the units operated as
    a process train
    throughout the year?
    vi)
    Are any continuous units involved?
    and vii)
    Can emissions be vented to a common control device?”
    (PC #6 at 11—12.)
    The Agency does not propose specific language to address
    Stepan’s concerns.
    The Board finds that no additional
    modifications in response to Stepan’s suggestions are necessary.
    8)
    Calendar Year
    At hearing Stepan questioned the Agency whether
    determinations of uncontrolled total annual mass emissions were
    to be based on a calendar year or a rolling 12—month period.
    (Tr. at 38-39.)
    The Agency responded that the intent was that a
    calendar year be used for all calculations of uncontrolled total
    annual mass emissions.
    (Tr.
    at 39.)
    8
    Stepan now asks that the Board memorialize this portion of
    the record within today’s opinion and order.
    (PC #6 at
    18.)
    The
    Board accordingly observes that the record in this matter
    indicates that a calendar year is intended to be used for
    purposes of calculating uncontrolled total annual mass emissions.
    9)
    Effective Date
    Stepan recommends that the Board make these regulations
    effective as of the date when the final rule is published in the
    Illinois Register.
    (PC #6 at 19.)
    The Board notes that pursuant
    to the APA all adopted regulations becomes effective in this
    manner,
    and that accordingly no special action by the Board is
    warranted.
    CONCLUSION
    The Board finds that the proposed rules are technically
    feasible and economically reasonable,
    and that the rules are
    necessary to meet the requirements of the Clean Air Act.
    The
    Board finds that the record supports proceeding to second notice
    with the proposed rules as amended.
    ORDER
    The Board hereby proposes the following amendments to
    35
    Ill. Adm. Code 211,
    218 and 219.
    The Board directs the Clerk to
    submit the following amendments to the Joint Committee on
    Administrative Rules for second notice.
    9
    TITLE 35:
    ENVIRONMENTAL PROTECTION
    SUBTITLE B:
    AIR POLLUTION
    CHAPTER I:
    POLLUTION CONTROL BOARD
    SUBCHAPTER c:
    EMISSION STANDARDS AND LIMITATIONS
    FOR STATIONARY SOURCES
    PART 211
    DEFINITIONS
    AND
    GENERAL PROVISIONS
    SUBPART A:
    GENERAL PROVISIONS
    Section
    211. 101
    211. 102
    Section
    211. 121
    211. 122
    211. 130
    211. 150
    211. 170
    211.210
    211.230
    211.250
    211.270
    211.290
    211.310
    211.330
    211.350
    211.370
    211.390
    211.410
    211. 430
    211. 450
    211.470
    211.490
    211.510
    211. 530
    211.550
    211.560
    211. 570
    211.590
    211.610
    211.630
    211.650
    211.670
    211.690
    211.695
    211.696
    Incorporations by Reference
    Abbreviations and Conversion Factors
    SUBPART B:
    DEFINITIONS
    Other Definitions
    Definitions
    (Repealed)
    Accelacota
    Accumulator
    Acid Gases
    Actual Heat Input
    Adhesive
    Aeration
    Aerosol Can Filling Line
    Afterburner
    Air Contaminant
    Air Dried Coatings
    Air Oxidation Process
    Air Pollutant
    Air Pollution
    Air Pollution Control Equipment
    Air Suspension Coater/Dryer
    Airless Spray
    Air AssistedAirless Spray
    Annual Grain Through-Put
    Application Area
    Architectural Coating
    As Applied
    As—Applied Fountain Solution
    Asphalt
    Asphalt Prime Coat
    Automobile
    Automobile or Light-Duty Truck Assembly Source or
    Automobile or Light-Duty Truck Manufacturing Plant
    Automobile or Light-Duty Truck Refinishing
    Baked Coatings
    Batch Loading
    Batch Operation
    Batch Process Train
    10
    211.710
    211.730
    211.750
    211.770
    211.790
    211. 810
    211.830
    211.850
    211.870
    211.890
    211.910
    211.930
    211.950
    211.970
    211.990
    211.1010
    211. 1050
    211. 1070
    211. 1090
    211.1110
    211. 1130
    211. 1150
    211.1170
    211.1190
    211. 1210
    211. 1230
    211.1250
    211.1270
    211. 1290
    211. 1310
    211. 1330
    211. 1350
    211. 1370
    211. 1390
    211.1410
    211.1430
    211. 1470
    211. 1490
    211.1510
    211.1530
    211.1550
    211. 1570
    211.1590
    211.1610
    211.1630
    211.1650
    211. 1670
    211.1690
    211. 1710
    211.1730
    211. 1750
    211. 1770
    Bead-Dipping
    Binders
    British Thermal Unit
    Brush or Wipe Coating
    Bulk Gasoline Plant
    Bulk Gasoline Terminal
    Can
    Can Coating
    Can Coating Line
    Capture
    Capture Device
    Capture Efficiency
    Capture System
    Certified Investigation
    Choke Loading
    Clean Air Act
    Cleaning and Separating Operation
    Cleaning Materials
    Clear Coating
    Clear Topcoat
    Closed Purge System
    Closed Vent System
    Coal Refuse
    Coating
    Coating Applicator
    Coating Line
    Coating Plant
    Coil Coating
    Coil Coating Line
    Cold Cleaning
    Complete Combustion
    Component
    Concrete Curing Compounds
    Concentrated Nitric Acid Manufacturing Process
    Condensate
    Condensible PM—b
    Continuous Process
    Control Device
    Control Device Efficiency
    Conventional Soybean Crushing Source
    Conveyorized Degreasing
    Crude Oil
    Crude Oil Gathering
    Crushing
    Custody Transfer
    Cutback Asphalt
    Daily-Weighted Average VON Content
    Day
    Degreaser
    Delivery Vessel
    Dip Coating
    Distillate Fuel Oil
    11
    Drum
    Dry Cleaning Operation or Dry Cleaning Facility
    Dump-Pit Area
    Effective Grate Area
    Effluent Water Separator
    Electrostatic Bell or Disc Spray
    Electrostatic Spray
    Emergency or Standby Unit
    Emission Rate
    Emission Unit
    Enamel
    Enclose
    End Sealing Compound Coat
    Enhanced Under-the-Cup Fill
    Ethanol Blend Gasoline
    Excess Air
    Excessive Release
    Existing Grain-Drying Operation
    Existing Grain-Handling Operation
    Exterior Base Coat
    Exterior End Coat
    External Floating Roof
    Extreme Performance Coating
    Fabric Coating
    Fabric Coating Line
    Federally Enforceable Limitations and Conditions
    Fill
    Final Repair Coat
    Firebox
    Fixed-Roof Tank
    Flexographic Printing
    Flexographic Printing Line
    Floating Roof
    Fountain Solution
    Freeboard Height
    Fuel Combustion Emission Unit or Fuel Combustion
    Emission Source
    Fugitive Particulate Matter
    Full Operating Flowrate
    Gas Service
    Gas/Gas Method
    Gasoline
    Gasoline Dispensing Operation or Gasoline Dispensing
    Facility
    Gel Coat
    Grain
    Grain-Drying Operation
    Grain-Handling and Conditioning Operation
    Grain-Handling Operation
    Green-Tire Spraying
    Green Tires
    Gross Heating Value
    Gross Vehicle Weight Rating
    211. 1790
    211. 1810
    211. 1830
    211. 1850
    211. 1870
    211. 1890
    211. 1910
    211. 1920
    211. 1930
    211. 1950
    211.1970
    211.1990
    211.2010
    211.2030
    211.2050
    211.2070
    211.2090
    211.2110
    211.2130
    211.2150
    211.2170
    211.2190
    211.2210
    211.2230
    211.2250
    211.2270
    211.2300
    211.2310
    211.2330
    211.2350
    211.2370
    211.2390
    211.2410
    211.2430
    211.2450
    211.2470
    211.2490
    211.2510
    211.2530
    211.2550
    211.2570
    211.2590
    211.2610
    211.2650
    211.2670
    211.2690
    211.2710
    211.2730
    211.2750
    211.2770
    211.2790
    12
    211.2810
    211.2830
    211.2850
    211.2870
    211.2890
    211.2910
    211.2930
    211.2950
    211.2970
    211.2990
    211.3010
    211.3030
    211.3050
    211.3070
    211.3090
    211.3110
    211.3130
    211.3150
    211. 3170
    211.3190
    211.3210
    211.3230
    211.3250
    211.3270
    211.3290
    211.3310
    211.3330
    211.3350
    211.3370
    211.3390
    211.3410
    211.3430
    211.3450
    211.3470
    211.3480
    211.3490
    211.3500
    211.3510
    211.3530
    211.3550
    211.3570
    211.3590
    211.3610
    211.3620
    211.3630
    211.3650
    211.3660
    211.3670
    211.3690
    211.3695
    211.3710
    211.3730
    Heated Airless Spray
    Heatset
    Heatset Web Offset Lithographic Printing Line
    Heavy Liquid
    Heavy Metals
    Heavy Off-Highway Vehicle Products
    Heavy Off-Highway
    Vehicle Products Coating
    Heavy Off-Highway Vehicle Products Coating Line
    High Temperature Aluminum Coating
    High Volume Low Pressure
    (HVLP)
    Spray
    Hood
    Hot Well
    Housekeeping Practices
    Incinerator
    Indirect Heat Transfer
    Ink
    In—Process Tank
    In-Situ Sampling Systems
    Interior Body Spray Coat
    Internal-Floating Roof
    Internal Transferring Area
    Lacquers
    Large Appliance
    Large Appliance Coating
    Large Appliance Coating Line
    Light Liquid
    Light-Duty Truck
    Light Oil
    Liquid/Gas Method
    Liquid-Mounted Seal
    Liquid Service
    Liquids Dripping
    Lithographic Printing Line
    Load-Out Area
    Loading Event
    Low Solvent Coating
    Lubricating Oil
    Magnet Wire
    Magnet Wire Coating
    Magnet Wire Coating
    Line
    Major Dump Pit
    Major Metropolitan Area
    (MMA)
    Major Population Area
    (MPA)
    Manually Operated Equipment
    Manufacturing Process
    Marine Terminal
    Marine Vessel
    Material Recovery Section
    Maximum Theoretical Emissions
    Maximum True Vapor Pressure
    Metal Furniture
    Metal Furniture Coating
    13
    211.3750
    211.3770
    211.3790
    211.3810
    211.3830
    211.3850
    211.3870
    211.3890
    211.3910
    211.3930
    211.3950
    211.3970
    211.3990
    211.4010
    211.4030
    211.4050
    211.4070
    211.4090
    211. 4110
    211.4130
    211.4150
    211.4170
    211.4190
    211.4210
    211.4230
    211.4250
    211.4260
    211.4270
    211.4290
    211.4310
    211.4330
    211.4350
    211.4370
    211.4390
    211.4410
    211.4430
    211.4450
    211.4470
    211.4490
    211.4510
    211.4530
    211.4550
    211.4590
    211.4610
    211.4630
    211.4650
    211.4670
    211.4690
    211.4710
    211.4730
    Metal Furniture Coating Line
    Metallic Shoe—Type Seal
    Miscellaneous Fabricated Product Manufacturing Process
    Miscellaneous Formulation Manufacturing Process
    Miscellaneous Metal Parts and Products
    Miscellaneous Metal Parts and Products Coating
    Miscellaneous Metal Parts or Products Coating Line
    Miscellaneous Organic Chemical Manufacturing Process
    Mixing Operation
    Monitor
    Monomer
    Multiple Package Coating
    New Grain-Drying Operation
    New Grain-Handling Operation
    No Detectable Volatile Organic Material Emissions
    Non—contact Process Water Cooling Tower
    Offset
    One Hundred Percent Acid
    One-Turn Storage Space
    Opacity
    Opaque Stains
    Open Top Vapor Degreasing
    Open-Ended Valve
    Operator of a Gasoline Dispensing Operation or Operator
    of a Gasoline Dispensing Facility
    Organic Compound
    Organic Material and
    Organic Materials
    Organic Solvent
    Organic Vapor
    Oven
    Overall Control
    Overvarnish
    Owner of a Gasoline Dispensing Operation or Owner of a
    Gasoline Dispensing Facility
    Owner or Operator
    Packaging Rotogravure Printing
    Packaging Rotogravure Printing Line
    Pail
    Paint Manufacturing Source or Paint Manufacturing Plant
    Paper Coating
    Paper Coating Line
    Particulate Matter
    Parts Per Million
    (Volume)
    or PPM
    (Vol)
    Person
    Petroleum
    Petroleum Liquid
    Petroleum Refinery
    Pharmaceutical
    Pharmaceutical Coating Operation
    Photochemically Reactive Material
    Pigmented Coatings
    Plant
    14
    211.4750
    211.4770
    211.4790
    211.4810
    211.4830
    211.4850
    211.4870
    211.4890
    211.4910
    211.4930
    211.4950
    211.4970
    211.4990
    211.5030
    211.5050
    211.5060
    211.5070
    211.5090
    211.5110
    211.5130
    211.5150
    211.5170
    211.5185
    211.5190
    211.5210
    211.5230
    211.5245
    211.5250
    211.5270
    211.5310
    211.5330
    211.5340
    211.5350
    211.5370
    211.5390
    211.5410
    211.5430
    211.5450
    211.5470
    211.5490
    211.5500
    211.5510
    211.5530
    211.5550
    211.5570
    211.5590
    211.5610
    211.5630
    211.5650
    211.5670
    Plasticizers
    PM-b
    Pneumatic Rubber Tire Manufacture
    Polybasic Organic Acid Partial Oxidation Manufacturing
    Process
    Polyester Resin Material(s)
    Polyester Resin Products Manufacturing Process
    Polystyrene Plant
    Polystyrene Resin
    Portable Grain-Handling Equipment
    Portland Cement Manufacturing Process Emission Source
    Portland Cement Process or Portland Cement
    Manufacturing Plant
    Potential to Emit
    Power Driven Fastener Coating
    Pressure Release
    Pressure Tank
    Pressure/Vacuum Relief Valve
    Prime Coat
    Primer Surfacer Coat
    Primer Surfacer Operation
    Primers
    Printing
    Printing Line
    Process Emission Source
    Process Emission Unit
    Process Unit
    Process Unit Shutdown
    Process Vent
    Process Weight Rate
    Production Equipment Exhaust System
    Publication Rotogravure Printing Line
    Purged Process Fluid
    Rated Heat Input Capacity
    Reactor
    Reasonably Available Control Technology
    (RACT)
    Reclamation System
    Refiner
    Refinery Fuel Gas
    Refinery Fuel Gas System
    Refinery Unit or Refinery Process Unit
    Refrigerated Condenser
    Regulated Air Pollutant
    Reid Vapor Pressure
    Repair
    Repair Coat
    Repaired
    Residual Fuel Oil
    Restricted Area
    Retail Outlet
    Ringelmann Chart
    Roadway
    15
    211.5690
    211.5710
    211.5730
    211.5750
    211. 5770
    211.5790
    211.5810
    211.5830
    211.5850
    211.5870
    211.5890
    211. 5910
    211.5930
    211.5950
    211. 5970
    211.5990
    211.6010
    211. 6025
    211.6030
    211.6050
    211.6070
    211. 6090
    211.6110
    211.6130
    211.6150
    211. 6170
    211. 6190
    211.6210
    211.6230
    211.6250
    211.6270
    211.6290
    211. 6310
    211.6330
    211.6350
    211.6355
    211.6360
    211.6370
    211. 6390
    211. 6410
    211.6430
    211.6450
    211.6470
    211.6490
    211. 6510
    211.6530
    211.6550
    211.6570
    211.6590
    211.6610
    211.6630
    Roll Coater
    Roll Coating
    Roll Printer
    Roll Printing
    Rotogravure Printing
    Rotogravure Printing Line
    Safety Relief Valve
    Sandblasting
    Sanding Sealers
    Screening
    Sealer
    Semi—Transparent Stains
    Sensor
    Set of Safety Relief Valves
    Sheet Basecoat
    Shotblasting
    Side-Seam Spray Coat
    Single Unit Operation
    Smoke
    Smokeless Flare
    Solvent
    Solvent Cleaning
    Solvent Recovery System
    Source
    Specialty High Gloss Catalyzed Coating
    Specialty Leather
    Specialty Soybean Crushing Source
    Splash Loading
    Stack
    Stain Coating
    Standard Conditions
    Standard Cubic Foot
    (scf)
    Start-Up
    Stationary Emission Source
    Stationary Emission Unit
    Stationary Gas Turbine
    Stationary Reciprocating Internal Combustion Engine
    Stationary Source
    Stationary Storage Tank
    Storage Tank or Storage Vessel
    Styrene Devolatilizer Unit
    Styrene Recovery Unit
    Submerged Loading Pipe
    Substrate
    Sulfuric Acid Mist
    Surface Condenser
    Synthetic Organic Chemical or Polymer Manufacturing
    Plant
    Tablet Coating Operation
    Thirty—Day Rolling Average
    Three—Piece Can
    Through-the-Valve Fill
    16
    Tooling Resin
    Topcoat
    Topcoat Operation
    Touch—Up
    Transfer Efficiency
    Tread End Cementing
    True Vapor Pressure
    Turnaround
    Two—Piece Can
    Under—the-Cup Fill
    Undertread Cementing
    Unregulated Safety Relief Valve
    Vacuum Producing System
    Vacuum Service
    Valves Not Externally Regulated
    Vapor Balance System
    Vapor Collection System
    Vapor Control System
    Vapor-Mounted Primary Seal
    Vapor Recovery System
    Vapor—Suppressed Polyester Resin
    Vinyl Coating
    Vinyl Coating Line
    Volatile Organic Liquid
    (VOL)
    Volatile Organic Material Content
    (VOMC)
    Volatile Organic Material
    (VOM)
    or Volatile Organic
    Compound (VOC)
    Volatile Petroleum Liquid
    Wash Coat
    Wastewater
    (Oil/Water) Separator
    Weak Nitric Acid Manufacturing Process
    Web
    Wholesale Purchase
    —
    Consumer
    Wood Furniture
    Wood Furniture Coating
    Wood Furniture Coating Line
    Woodworking
    AUTHORITY:
    Implementing Sections
    9,
    9.1 and 10 and
    Section
    27 and 28.5 of the Environmental Protection
    5/9,
    9.1,
    10,
    27 and 28.53.
    SOURCE:
    Adopted as Chapter
    2:
    Air Pollution,
    Rule 201:
    Definitions,
    P.71—23,
    4 PCB 191,
    filed and effective April
    14,
    1972; amended in P.74—2 and P.75—5,
    32 PCB 295, at
    3 Ill.
    Reg.
    5,
    p.
    777, effective February
    3,
    1979; amended
    in R78-3 and 4,
    35
    PCB 75 and 243,
    at
    3 Ill. Reg.
    30,
    p.
    124,
    effective July 28,
    1979; amended in R80-5,
    at
    7 Ill. Req.
    1244,
    effective January
    21,
    1983; codified at
    7 Ill.
    Reg.
    13590; amended
    in R82—l
    (Docket
    211. 6650
    211.6670
    211.6690
    211.6710
    211.6730
    211.6750
    211.6770
    211.6790
    211.6810
    211.6830
    211.6850
    211.6870
    211.6890
    211.6910
    211.6930
    211.6950
    211.6970
    211.6990
    211.7010
    211.7030
    211.7050
    211.7070
    211.7090
    211.7110
    211.7130
    211.7150
    211.7170
    211.7190
    211.7210
    211.7230
    211.7250
    211.7270
    211.7290
    211.7310
    211.7330
    211.7350
    APPENDIX A
    APPENDIX B
    Rule into Section Table
    Section into Rule Table
    authorized by
    Act 415
    ILCS
    17
    A)
    at 10 Ill.
    Beg.
    12624, effective July
    7,
    1986; amended in
    P.85—21(A)
    at
    11
    Ill.
    Beg.
    11747, effective June 29,
    1987; amended
    in P.86—34 at
    11
    Ill. Reg.
    12267, effective July 10,
    1987; amended
    in R86—39 at
    11
    Ill. Req.
    20804,
    effective December 14,
    1987;
    amended in P.82—14 and R86-37 at 12
    Ill.
    Req.
    787, effective
    December 24,
    1987; amended in P.86-18 at
    12
    Ill.
    Reg.
    7284,
    effective April 8,
    1988; amended in P.86—10 at
    12
    Ill. Req.
    7621,
    effective April 11,
    1988; amended
    in R88-23 at
    13 Ill.
    Req.
    10862, effective June 27,
    1989;
    amended in P.89—8 at
    13
    Ill. Reg.
    17457, effective January
    1,
    1990; amended in R89—16(A) at 14
    Ill.
    Beg.
    9141, effective May 23,
    1990;
    amended in P.88-30(B)
    at 15
    Ill. Req.
    5223,
    effective March
    28,
    1991; amended
    in P.88—14 at 15
    Ill. Reg.
    7901,
    effective May
    14,
    1991; amended in P.91—10
    at
    15
    Ill.
    Beg.
    15564, effective October 11,
    1991; amended
    in R91—6 at
    15
    Ill.
    Req.
    15673,
    effective October 14,
    1991;
    amended in P.91—22
    at 16 Ill. Req.
    7656,
    effective May
    1,
    1992; amended
    in P.91—24 at
    16 Iii.
    Reg.
    13526,
    effective August 24,
    1992;
    amended
    in R93—9
    at
    17
    Ill.
    Reg.
    16504, effective September 27,
    1993; amended
    in
    P.93—li at
    17 Ill. Beg.
    21471, effective December
    7,
    1993; amended
    in R93—l4 at 18
    Ill. Req.
    1253,
    effective January 18,
    1994;
    amended in P.94-12 at 18
    Ill. Beg.
    14962, effective September 21,
    1994; amended in R94—l4 at
    18
    Ill.
    Beg.
    15744,
    effective October
    17,
    1994; amended in P.94—15 at 18 Ill. Req.
    16379, effective
    October
    25,
    1994;
    amended in P.94—16 at
    18 Ill. Beg.
    16929,
    effective November
    15,
    1994;
    amended
    in R94—33 at
    19 Ill. Beg.
    —
    ______,
    effective _______________________
    BOARD NOTE:
    This Part implements the Illinois Environmental
    Protection Act as of July
    1,
    1994.
    SUBPART B:
    DEFINITIONS
    Section 211.695
    Batch Operation
    “Batch operation” means,
    for purposes of 35 Ill. Adm. Code Parts
    218 and 219, Sections 218.500 throu~h218.506 and 219.500 through
    219.506,
    a noncontinuous operation in which
    a discrete quantity
    or batch of feed
    is charged into
    a chemical manufacturing process
    unit and distilled or reacted,
    or otherwise used at one time, and
    maY include, but is not limited to, reactors, filters, dryers,
    distillation columns, extractors,
    crystallizers, blend tanks,
    neutralizer tanks, digesters,
    surge tanks and Product separators.
    After each batch operation, the equipment is generally emptied
    before a fresh batch is started.
    (Source:
    Added at 19 Ill.
    Req.
    ,
    effective
    ____________
    Section 211.696
    Batch Process Train
    “Batch process train” means,
    for purposes of 35 Ill.
    Adm. Code
    Parts 218 and 219, Sections 218.500 through 218.506 and 219.500
    18
    through
    219.506, the collection of equipment
    (e.g.,
    reactors,
    filters,
    dryers, distillation columns, extractors,
    crystallizers,
    blend tanks, neutralizer tanks,
    digesters,
    surge tanks and
    product separators)
    configured to produce a specific product or
    intermediate by a batch operation.
    A batch process train
    terminates at the point of storage or product handling of the
    product or intermediate being produced in the batch process
    train.
    Irrespective
    of the product being produced,
    a batch
    process train which
    is independent of other processes shall be
    considered
    a single batch process train for purposes of 35 Ill.
    Adm. Code Parts 218 and 219.
    (Source:
    Added at
    19 Ill. Req.
    __________,
    effective
    ___________
    Section 211.5245
    Process Vent
    “Process vent” means,
    for purposes of
    35
    Ill. Adm.
    Code Parts 218
    and 219.
    Sections 218.500 through 218.506
    and 219.500
    through
    219.506, any non-fugitive source of VON emissions to the
    atmosphere resulting from non—combustion emission units.
    A
    process vent begins at the inlet to the control device,
    or in the
    absence of a control device, at the point of discharge to the
    atmosphere.
    This includes all emission units vents and stacks.
    Not included
    in this definition are exhaust streams from exhaust
    hoods and building ventilation fans which are used to provide
    ventilation for workers and not to collect and discharge
    emissions from specific emission units.
    (Source:
    Added at 19 Ill. Req.
    effective
    Section 211.6025
    Single Unit Operation
    “Single unit operation” means,
    for purposes of
    35 Ill. Adm. Code
    Parts 218 and 219, Sections 218.500
    through
    218.506 and 219.500
    through 219.506,
    a distinct piece of equipment in a batch
    operation within which one or more discrete processing steps
    occur.
    Such discrete processing steps include, but are not
    limited to, the preparation of reactants,
    facilitation of
    reactions, separation and purification of products or
    intermediates, and recycling of materials.
    (Source:
    Added at
    19 Ill.
    Reg.
    _________,
    effective
    19
    TITLE 35:
    ENVIRONMENTAL PROTECTION
    SUBTITLE B:
    AIR POLLUTION
    CHAPTER
    I:
    POLLUTION CONTROL BOARD
    SUBCHAPTER
    C:
    EMISSIONS STANDARDS AND LIMITATIONS
    FOR STATIONARY SOURCES
    PART 218
    ORGANIC MATERIAL EMISSION STANDARDS
    AND
    LIMITATIONS FOR THE
    CHICAGO AREA
    SUBPART A:
    GENERAL PROVISIONS
    Section
    218.100
    218.101
    218.102
    218.103
    218.104
    218.105
    218.106
    218.107
    218.108
    218. 109
    218. 110
    218.111
    218. 112
    218.113
    218. 114
    Introduction
    Savings Clause
    Abbreviations and Conversion Factors
    Applicability
    Definitions
    Test Methods and Procedures
    Compliance Dates
    Operation of Afterburners
    Exemptions, Variations, and Alternative Means of
    Control or Compliance Determinations
    Vapor Pressure of Volatile Organic Liquids
    Vapor Pressure of
    Organic Material or Solvents
    Vapor Pressure of Volatile Organic
    Material
    Incorporations by Reference
    Monitoring for Negligibly-Reactive Compounds
    Compliance with Permit Conditions
    SUBPART
    B:
    ORGANIC EMISSIONS FROM STORAGE AND LOADING
    OPERATIONS
    Applicability for VOL
    Control Requirements for Storage Containers of VOL
    Storage Containers of VPL
    Loading Operations
    Petroleum Liquid Storage
    Tanks
    External Floating Roofs
    Compliance Dates
    Compliance Plan
    (Repealed)
    Testing VOL Operations
    Monitoring VOL Operations
    Recordkeeping and Reporting for VOL Operations
    SUBPART C:
    ORGANIC EMISSIONS FROM MISCELLANEOUS
    EQUIPMENT
    Section
    218.141
    Separation Operations
    218.142
    Pumps and Compressors
    Section
    218. 119
    218.120
    218.121
    218.122
    218.123
    218. 124
    218.125
    218.126
    218.127
    218. 128
    218. 129
    20
    218.143
    218. 144
    Section
    218. 181
    218.182
    218. 183
    218. 184
    218. 185
    218.186
    Section
    218. 204
    218.205
    218.206
    218.207
    218.208
    218.209
    218.210
    218.211
    Section
    218.301
    218.302
    218.303
    218
    .
    304
    Section
    218.401
    218.402
    218.403
    218.404
    218.405
    Section
    218.421
    218. 422
    218
    .
    423
    218 .424
    218.425
    Vapor Blowdown
    Safety Relief Valves
    SUBPART E:
    SOLVENT CLEANING
    Solvent Cleaning in General
    Cold Cleaning
    Open Top Vapor Degreasing
    Conveyorized Degreasing
    Compliance Schedule
    (Repealed)
    Test Methods
    SUBPART F:
    COATING OPERATIONS
    Emission Limitations
    Daily—Weighted Average Limitations
    Solids Basis Calculation
    Alternative Emission Limitations
    Exemptions from Emission Limitations
    Exemption from General Rule on Use of Organic Material
    Compliance Schedule
    Recordkeeping and Reporting
    SUBPART G:
    USE OF ORGANIC MATERIAL
    Use of Organic
    Material
    Alternative Standard
    Fuel Combustion Emission Units
    Operations with Compliance Program
    SUBPART H:
    PRINTING AND PUBLISHING
    Flexographic and Rotogravure Printing
    Applicability
    Compliance Schedule
    Recordkeeping and Reporting
    Heatset Web Offset Lithographic Printing
    SUBPART
    Q:
    LEAKS FROM SYNTHETIC
    ORGANIC CHEMICAL AND POLYMER
    MANUFACTURING PLANT
    General Requirements
    Inspection Program Plan for Leaks
    Inspection Program for Leaks
    Repairing Leaks
    Recordkeeping for Leaks
    21
    218.426
    218.427
    218.428
    218.429
    218.430
    Section
    218.441
    218.442
    218.443
    218.444
    218.445
    218.446
    218.447
    218.448
    218.449
    218.450
    218.451
    218.452
    218.453
    Report for Leaks
    Alternative Program for Leaks
    Open-Ended Valves
    Standards for Control Devices
    Compliance Date
    (Repealed)
    SUBPART R:
    PETROLEUM REFINING AND
    RELATED INDUSTRIES; ASPHALT MATERIALS
    Petroleum Refinery Waste Gas Disposal
    Vacuum Producing Systems
    Wastewater
    (Oil/Water) Separator
    Process Unit Turnarounds
    Leaks:
    General Requirements
    Monitoring Program Plan for Leaks
    Monitoring Program for Leaks
    Recordkeeping for Leaks
    Reporting for Leaks
    Alternative Program for Leaks
    Sealing Device Requirements
    Compliance Schedule for Leaks
    Compliance Dates
    (Repealed)
    SUBPART S:
    RUBBER AND MISCELLANEOUS PLASTIC PRODUCTS
    Section
    218.461
    218.462
    218.463
    218.464
    218.465
    218.466
    Section
    218.480
    218.481
    218.482
    218.483
    218.484
    218.485
    218.486
    218.487
    218.488
    218.489
    Manufacture of Pneumatic Rubber Tires
    Green Tire Spraying Operations
    Alternative Emission Reduction Systems
    Emission Testing
    Compliance Dates
    (Repealed)
    Compliance Plan
    (Repealed)
    SUBPART T:
    PHARMACEUTICAL MANUFACTURING
    Applicability
    Control of Reactors,
    Distillation Units,
    Crystallizers,
    Centrifuges and Vacuum Dryers
    Control of Air Dryers,
    Production Equipment Exhaust
    Systems and Filters
    Material Storage and Transfer
    In-Process Tanks
    Leaks
    Other Emission Units
    Testing
    Monitoring for Air Pollution Control Equipment
    Recordkeeping for Air Pollution Control Equipment
    SUBPART V:
    BATCH OPERATIONS AND AIR OXIDATION PROCESSES
    22
    Section
    218. 500
    218.501
    218.502
    218.503
    218. 504
    218.505
    218.506
    218.520
    218.521
    218.522
    218. 523
    218.524
    218.525
    218.526
    218.527
    Section
    218. 541
    Section
    218.561
    218.562
    218.563
    Section
    218.581
    218.582
    218.583
    2 18.584
    218.585
    218.586
    Section
    218. 601
    218.602
    218.603
    218. 604
    218.605
    Applicability for Batch Operations
    Control Requirements for Batch Operations
    Determination of Uncontrolled Total Annual Mass
    Emissions and Average Flow Rate Values for Batch
    Operations
    Performance and Testing Requirements
    for Batch
    OPerations
    Monitoring Requirements
    for Batch Operations
    Re~ortinaand Recordkeeping for Batch Operations
    Compliance Date
    Emission Limitations for Air Oxidation Processes
    Definitions
    (Repealed)
    Savings Clause
    Compliance
    Determination of Applicability
    Emission Limitations for Air Oxidation Processes
    Testing and Monitoring
    Compliance Date
    (Repealed)
    SUBPART W:
    AGRICULTURE
    Pesticide Exception
    SUBPART
    X:
    CONSTRUCTION
    Architectural Coatings
    Paving Operations
    Cutback Asphalt
    SUBPART Y:
    GASOLINE DISTRIBUTION
    Bulk Gasoline Plants
    Bulk Gasoline Terminals
    Gasoline Dispensing Operations
    -
    Storage Tank Filling
    Operations
    Gasoline Delivery Vessels
    Gasoline Volatility Standards
    Gasoline Dispensing Operations
    -
    Motor Vehicle Fueling
    Operations
    SUBPART
    Z:
    DRY CLEANERS
    Perchloroethylene Dry Cleaners
    Applicability
    Leaks
    Compliance Dates
    (Repealed)
    Compliance Plan (Repealed)
    23
    218.606
    218.607
    218.608
    218.609
    218.610
    218.611
    218.612
    218.613
    Section
    218. 620
    218.621
    218.623
    218.624
    218.625
    218.626
    218.628
    218.630
    218.636
    218.637
    Section
    218.640
    218.642
    218.644
    Exception to Compliance Plan
    (Repealed)
    Standards for Petroleum Solvent Dry Cleaners
    Operating Practices for Petroleum Solvent Dry Cleaners
    Program for Inspection and Repair of Leaks
    Testing and Monitoring
    Applicability for Petroleum Solvent Dry Cleaners
    Compliance Dates
    (Repealed)
    Compliance Plan (Repealed)
    SUBPART
    AA:
    PAINT AND INK MANUFACTURING
    Applicability
    Exemption for Waterbase Material and Heatset—Offset Ink
    Permit Conditions
    (Repealed)
    Open Top Mills, Tanks, Vats or Vessels
    Grinding Mills
    Storage Tanks
    Leaks
    Clean Up
    Compliance Schedule
    Recordkeeping and Reporting
    SUBPART SB:
    POLYSTYRENE PLANTS
    Applicability
    Emissions Limitation at Polystyrene Plants
    Emissions Testing
    Applicability
    Control Requirements
    Compliance Schedule
    Testing
    Recordkeeping and Reporting for Exempt Emission Units
    Recordkeeping and Reporting for Subject Emission Units
    SUBPART DD: AEROSOL CAN FILLING
    Applicability
    Control Requirements
    Testing
    Recordkeeping and Reporting for Exempt Emission Units
    Recordkeeping and Reporting for Subject Emission Units
    Section
    218.760
    SUBPART GG:
    MARINE TERMINALS
    SUBPART CC:
    POLYESTER RESIN PRODUCT MANUFACTURING PROCESS
    Section
    218. 660
    218. 666
    218.667
    218.668
    218.670
    218
    .
    672
    Section
    218.680
    218.686
    218 .688
    218.690
    218.692
    Applicability
    24
    218.762
    218.764
    218.766
    218.768
    218.770
    218.875
    218.877
    218.879
    218.881
    218.883
    218.886
    Control Requirements
    Compliance Certification
    Leaks
    Testing and Monitoring
    Recordkeeping and Reporting
    Applicability of Subpart SB
    (Renumbered)
    Emissions Limitation at Polystyrene Plants
    (Renumbered)
    Compliance Date
    (Repealed)
    Compliance Plan (Repealed)
    Special Requirements for Compliance Plan (Repealed)
    Emissions Testing (Renumbered)
    SUBPART PP:
    MISCELLANEOUS FABRICATED PRODUCT MANUFACTURING
    PROCESSES
    Section
    218.920
    218.923
    218.926
    218.927
    218.928
    Applicability
    Permit Conditions
    (Repealed)
    Control Requirements
    Compliance Schedule
    Testing
    SUBPART
    QQ:
    MISCELLANEOUS
    FORMULATION
    MANUFACTURING
    PROCESSES
    Section
    218.940
    218.943
    218.946
    218.947
    218.948
    Applicability
    Permit Conditions
    (Repealed)
    Control Requirements
    Compliance Schedule
    Testing
    SUBPART RB:
    MISCELLANEOUS ORGANIC CHEMICAL MANUFACTURING
    PROCESSES
    Applicability
    Permit Conditions
    (Repealed)
    Control Requirements
    Compliance Schedule
    Testing
    Section
    218.980
    218.983
    218.986
    218.987
    218.988
    Applicability
    Permit Conditions
    (Repealed)
    Control Requirements
    Compliance Schedule
    Testing
    Section
    218.960
    218.963
    218.966
    218.967
    218.968
    SUBPART TT:
    OTHER EMISSION UNITS
    SUBPART UU:
    RECORDKEEPING AND REPORTING
    25
    Section
    218.990
    Exempt Emission Units
    218.991
    Subject Emission Units
    Section 218.Appendix A:
    List of Chemicals Defining Synthetic
    Organic Chemical and Polymer
    Manufacturing
    Section 218.Appendix
    B:
    VON Measurement Techniques for Capture
    Efficiency
    Section 218 .Appendix C:
    Reference Methods and Procedures
    Section 218.Appendix
    D:
    Coefficients for the Total Resource
    Effectiveness Index
    (TRE)
    Equation
    Section 218.Appendix
    E:
    List of Affected Marine Terminals
    AUTHORITY:
    Implementing Section
    10 and authorized by Section
    28.5 of the Environmental Protection Act
    415
    ILCS 5/10 and
    28.5.
    SOURCE:
    Adopted at R91-7 at
    15 Ill. Req.
    12231, effective August
    16,
    1991;
    amended in R91—24 at 16
    Ill.
    Beg.
    13564, effective
    August
    24,
    1992;
    amended in R9l—28 and P.91—30 at
    16
    Ill. Reg.
    13864, effective August 24,
    1992; amended in P.93—9 at 17
    Ill.
    Req.
    16636, effective September
    27,
    1993; amended
    in P.93-14
    at 18
    Ill. Beg.
    1945,
    effective January
    24,
    1994;
    amended
    in P.94—12 at
    18
    Ill.
    Req.
    14973, effective September 21,
    1994;
    amended
    in R94-
    15 at 18 Ill.
    Req.
    16392, effective October 25,
    1994;
    amended in
    R94—l6 at
    18 Ill.
    Beg.
    16950,
    effective November
    15,
    1994;
    amended
    in R94—33 at 19
    Ill. Beg.
    ________,
    effective
    ____________
    BOARD NOTE:
    This Part implements the Illinois Environmental
    Protection Act as of July
    1,
    1994.
    SUBPART V:
    BATCH OPERATIONS AND AIR OXIDATION PROCESSES
    Section 218.500
    ~pplicability
    for Batch Operations
    ~
    The control requirements
    set forth
    in Section 218.501
    of this Subpart shall apply to:
    .~j.
    Process vents associated with batch operations at
    sources identified by any of the following four—
    digit standard industrial classification
    (“SIC”)
    codes, as defined in the 1987 edition of the
    Federal Standard Industrial Classification Manual:
    SIC 2821,
    2833,
    2834,
    2861,
    2865,
    2869,
    and 2879
    and
    ZL
    All batch operations at StePan Company’s Millsdale
    manufacturing facility.
    Elwood,
    Illinois.
    26
    ~j
    The requirements of Sections 218.500 through 218.506
    shall not apply to:
    ~
    Any emission unit included within the category
    specified in
    35
    Ill.
    Adm.
    Code Part 218, Subpart B
    or T
    ~j
    AnY emission unit included within the cate~orv
    specified in Sections 218.520 through 218.527
    of
    this Subpart; and
    ~J
    Any emission unit included within an Early
    Reduction Program, as specified
    in
    40 CFR Part
    63,
    and_published in 57
    Fed. Reg.
    61970
    (December 29,
    1992), evidenced by
    a timely enforceable
    commitment approved by USEPA.
    gj
    The following single unit operations and batch process
    trains are subject to this
    Subpart but are considered
    to be de minimis and are,
    therefore,
    exempt from the
    control requirements
    of Section 218.501 of this
    Subpart.
    However, the recordkeeping and reporting
    requirements
    in Section 218.505 of this Subpart shall
    aPPlY to such de minimis single unit operations and
    batch process trains:
    fl
    Within a batch operation, any single unit
    operation with uncontrolled total annual mass
    emissions of less than or equal to
    500 lb/yr of
    VON.
    Such single unit operations are also
    excluded from the calculation of the total annual
    mass emissions for a batch process train.
    If the
    uncontrolled total annual mass emissions from such
    exempt single unit operation exceed 500 lb/Yr of
    VON in any subseauent year,
    the source shall
    calculate applicabilitvin accordance with
    subsection
    (d)
    of this Section for both the
    individual single unit operation and the batch
    process train containing the single unit
    operation; and
    2i
    Any batch
    process train containing process vents
    that_have,
    in the aggregate,
    uncontrolled total
    annual mass emissions,
    as determined in accordance
    with Section 218.502(a)
    of this Subpart,
    of less
    than 30,000 lb/yr of VOM for all products
    manufactured in such batch process train.
    ~j
    The applicability equations
    in subsection
    (e)
    of this
    Section, which require the calculation of uncontrolled
    total annual mass emissions and flow rate value, shall
    be used to determine whether a single unit operation or
    27
    a batch process train is
    sub-lect to the control
    requirements set forth in Section
    218.501 of this
    Subpart. The applicability equation shall
    be applied to
    the following:
    fl..
    Any single unit operation with uncontrolled total
    annual mass emissions that exceed 500 lb/yr and
    with a VOM concentration greater than 500 ppmv.
    In this individual determination,
    no applicability
    analysis shall be performed for any single unit
    operation with a VOM concentration of less than or
    egual to 500 ~pniv; and
    .~j
    Any batch process train containing process vents
    which,
    in the aggregate, have uncontrolled total
    annual mass emissions of 30,000 lb/yr or more of
    VOM from all products manufactured
    in the batch
    process train.
    Any single unit operation with
    uncontrolled total annual mass emissions exceeding
    500
    lb/yr. regardless of VOM concentration, shall
    be included in the aggregate applicability
    analysis.
    ~j
    Applicability equations
    fl
    The applicability equations
    in this subsection are
    specific to volatility.
    ~j
    For purposes of this subsection,
    the following
    abbreviations apply:
    =
    Vent stream flow rate, scfm
    ~j
    UTANE
    =
    Uncontrolled total annual mass
    emissions of VOM,
    expressed as
    lb/yr
    =
    Weighted average volatility
    ~j
    NVOM1
    =
    Mass of VOM component i
    ~j.
    MWVOM1=
    Molecular
    weight of VOM component
    i; and
    fi
    VP~
    =
    Vapor pressure of VOM component
    i.
    ~J
    Weighted average volatility shall
    be calculated as
    follows:
    n
    (MVOM1)
    ~
    (VP)x
    28
    i=1
    (MWVOM1)
    3
    WAV
    =
    __________________
    n
    (MVOM1)
    i=1
    (MWVOM1)
    il
    For purposes of determining applicability, flow
    rate values shall be calculated as follows:
    Al
    Low WAV has
    a vapor pressure less than or
    equal to 75 ntmHg at 20°C(68°F),and shall
    use the following equation:
    FR
    =
    0.07
    (UTANE)1
    —
    1,821
    ~j
    Moderate WAV has
    a vapor pressure greater
    than 75 mmHq but less than or equal to 150
    mmHg at 20°C (68°F), and shall use the
    following equation:
    FR
    =
    0.031
    (UTAME)1
    —
    494
    ~j
    High WAV has a vapor pressure greater than
    150 mmHg at 20°C (68°F), and shall use the
    following equation:
    FR
    =
    0.013
    (UTANE)1
    —
    301
    ~j
    To determine the vapor pressure of VOM, the
    applicable methods and procedures
    in Section
    218.111 of this Part shall apply.
    (Source:
    Added at 19 Ill.
    Beg.
    _______,
    effective
    __________
    Section
    218.501
    Control Requirements
    for Batch Operations
    ~j
    Every owner or operator of a single unit operation with
    an average flow rate,
    as determined
    in accordance with
    Section 218.502(b)
    of this Subpart, below the flow rate
    value calculated by the applicability equations
    contained in Section 218.500(e)
    of this Subpart,
    shall
    reduce uncontrolled VON emissions from such single unit
    operation by an overall efficiency,
    on average,
    of at
    least 90 percent,
    or
    20 ppmv,
    per batch cycle.
    ~j
    Every owner or operator of
    a batch process train with
    an average flow rate,
    as determined
    in accordance with
    Section 218.502(b) (2)
    of this Subpart, below the flow
    rate value calculated by the applicability equations
    contained
    in Section 218.500(e)
    of this Subpart,
    shall
    29
    reduce uncontrolled VOM emissions from such batch
    process train
    by an overall efficiency,
    on average,
    of
    at least 90 percent.
    or 20
    ppmv,
    per batch cycle.
    For
    purposes of demonstrating compliance with the emission
    limitations set forth in this Section, any control
    device meeting the criteria
    in subsection
    (c)
    of this
    Section shall be deemed to achieve a control efficiency
    of 90 percent.
    or 20 ppmv,
    per batch cycle,
    as
    applicable.
    ~gj
    Notwithstanding subsections
    (a)
    or
    (b)
    of this Section.
    any source that has installed on or before March 15,
    1995, any control device which is demonstrated to the
    Agency’s satisfaction to be unable to meet the
    applicable control requirements of this Section,
    scrubber, or shell and tube condenser using
    a non—
    refrigerated cooling media,
    and such device achieves at
    least 81 percent control efficiency of VOM emissions,
    is required to meet the 90 percent emission limitation
    or 20 ppmv VON concentration set forth
    in subsections
    (a)
    or
    (b)
    of this Section,
    as applicable, upon the
    earlier to occur of the date the device
    is replaced for
    any reason,
    including,
    but not limited to, normal
    maintenance, malfunction,
    accident, and obsolescence,
    or December 31,
    1999.
    A scrubber, shell and tube
    condenser using a non—refrigerated cooling media,
    or
    other control device meeting the criteria of this
    subsection,
    is considered replaced when:
    jj.
    All of the device
    is replaced; or
    21
    When
    either the cost to repair the device or the
    cost to replace
    part of the device exceeds
    50
    percent of the cost of replacing the entire device
    with a control device that complies with the 90
    percent emission limitation
    or 20 ppmv VON
    concentration level in subsection
    (a)
    of this
    Section. as applicable.
    ~j
    If a boiler or process heater is used to comply with
    this Section,
    the vent stream shall be introduced into
    the flame zone of the boiler or process heater.
    ~j
    If a flare is used to comply with this Section,
    it
    shall comply with the requirements of 40 CFR 60.18.
    incorporated by reference at Section
    218.112
    of this
    Part.
    The
    flare operation requirements
    of 40 CFR 60.18
    do not apply
    if a process, not subject to this Subpart,
    vents an emergency relief discharge into a common flare
    header and causes the flare servicing the process
    sub-ject to this Subpart to not comply with one or more
    of the provisions of 40 CFR 60.18.
    30
    (Source:
    Added at 19
    Ill.
    Beg.
    ______,
    effective
    _____________
    Section 218.502
    Determination of Uncontrolled Total Annual
    Mass Emissions and Average Flow Rate Values
    for Batch Operations
    ~
    Uncontrolled total annual mass emissions shall be
    determined by the following methods:
    fl
    Direct process vent emissions measurements taken
    prior to any release to the atmosphere,
    following
    any recovery device and prior to any control
    device, provided such measurements conform with
    the requirements of measuring the mass flow rate
    of VON incoming to the control device as set forth
    in Section 218.503(f) (2).
    (f)
    (3) (A) and
    (f) (3) (B)
    of this Subpart; or
    21
    Engineering estimates of the uncontrolled VOM
    emissions from
    a process vent or process vents,
    in
    the aggregate, within a batch process train, using
    either the potential or permitted number of batch
    cycles per year or total production as represented
    in the source’s operating permit as follows:
    Al
    Engineering estimates of the uncontrolled VON
    emissions shall be based upon accepted
    chemical engineering principles, measurable
    process parameters, or physical or chemical
    laws and their properties.
    Examples of
    methods include, but are not limited to, the
    following:
    Jj
    Use of material balances based on
    process stoichiometry to estimate
    maximum VOM concentrations
    JJJ
    Estimation of maximum flow rate based on
    physical equipment design such as pump
    or blower capacities; and
    iii)
    Estimation of VON concentrations based
    on saturation conditions.
    ~j
    All data, assumptions and procedures used in
    any engineering estimate shall be documented.
    •
    ~l
    Average flow rate shall be determined by any of the
    following methods:
    31
    fl
    Direct process vent flow rate measurements taken
    prior to any release to the atmosphere,
    following
    any recovery device and prior to any control
    device, ~rovjded such measurements conform with
    the requirements of measuring incoming volumetric
    flow rate set forth in Section 218.503(e) (2)
    of
    this Subpart
    21
    Average flow rate for a single unit operation
    having multiple emission events or batch process
    trains shall be the weighted average flow rate,
    calculated as follows:
    n
    ~
    AFR1
    x ADE1JJ
    i=l
    WAF
    =
    ___________________
    n
    ~
    (ADEJ.
    1=1
    where:
    WAF
    =
    Actual weighted average flow
    rate for a single unit
    operation or batch process
    train
    =
    Average flow rate per emission
    event
    =
    Annual duration of emission
    event; and
    =
    Number of emission events.
    For purposes of this formula, the term “emission
    event” shall be defined as a discrete period of
    venting that is associated with a single unit
    operation.
    For example,
    a displacement of vapor
    resulting from the charging of a single unit
    operation with VON will result in a discrete
    emission event that w 11 last through the duration
    of_the_charge and will have an average flow rate
    equal to the rate of the charge.
    The expulsion of
    expanded vapor space when the single unit
    operation is heated
    is also an emission event.
    Both of these examples of emission events and
    others may occur
    in the same single unit operation
    during the course of the batch cycle.
    If the flow
    rate measurement for any emission event is zero,
    according to Section 218.503(f) (2)
    of this
    Subpart, then such event
    is not an emission event
    for purposes of this Section.
    32
    fl
    Engineering estimates calculated in accordance
    with the requirements in subsection
    (a)
    (2)
    of this
    Section.
    çj
    For purposes of determining the average flow rate for
    steam vacuuming systems,
    the steam flow shall
    be
    included
    in the average flow rate calculation.
    (Source:
    Added at 19 Ill. Req
    effective
    ______________
    Section 218.503
    Performance and Testing Requirements for
    •
    Batch Operations
    ~j
    Upon the Agency’s request, the owner or operator of a
    batch operation shall conduct testing to demonstrate
    compliance with Section 218.501 of this Subpart.
    The
    owner or operator shall, at its own expense, conduct
    such tests
    in accordance with the applicable test
    methods and procedures specified in Section 218.503(d).
    (e), and
    (f)
    of this Subpart.
    ~j
    Notwithstanding subsection
    (a)
    of this Section, flares
    and process boilers used to comply with control
    requirements of Section 218.501 of this Subpart shall
    be exemDt from performance testing requirements.
    ~j
    When a flare is used to comply with the control
    requirements of Section 218.501 of this Subpart, the
    flare shall comply with the requirements of 40 CFR
    60.18,
    incorporated by reference at Section 218.112 of
    this Part.
    ~j
    The owner or operator of a batch operation that is
    exempt from the control requirements of Section 218.501
    of this Subpart shall demonstrate,
    upon
    the Agency’s
    request, the absence of oversized gas moving equipment
    in any manifold.
    Gas moving equipment shall be
    considered oversized if
    it exceeds the maximum
    requirements of the exhaust flow rate by more than 30
    percent.
    ~j
    For the purpose of demonstrating compliance with the
    control requirements in Section 218.501 of this
    Subpart~the batch operation shall be run at
    representative operating conditions and flow rates
    during any performance test.
    ~j
    The following methods in 40 CFR 60,
    Appendix A,
    incorporated by reference at Section 218.112 of this
    Part,
    shall be used to demonstrate compliance with the
    reduction efficiency requirement set forth in Section
    218.501 of this Subpart:
    33
    j~
    Method
    1 or 1A,
    as appropriate,
    for selection of
    the sampling sites if
    the flow measuring device is
    not a rotameter.
    The control device inlet
    sampling site for determination of vent stream VON
    composition reduction efficiency shall be prior to
    the control device and after the control device
    21
    Method
    2.
    2A.
    2C,
    or 2D,
    as appropriate,
    for
    determination of gas stream volumetric flow rate
    flow measurements, which shall be taken
    continuously.
    No traverse is necessary when the
    flow measuring device is an ultrasonic probe
    ~j
    Method 25A or Method 18,
    if applicable, to
    determine the concentration of VOM in the control
    device inlet and outlet;
    Al
    The sampling time for each run shall be as
    follows:
    jj
    For batch cycles less than eight hours
    in length, readings shall be taken
    continuously over the entire length of
    the batch cycle with a maximum of 15-
    minute intervals between measurements if
    using Method 25A.
    If using Method
    18,
    readings shall be taken continuously
    with a maximum of 15-minute intervals
    between measurements throughout the
    batch cycle unless it becomes necessary
    to_change the impinger train,
    in which
    case a 30-minute interval shall not be
    exceeded.
    JJJ.
    For batch cycles of eight hours and
    greater in length,
    the owner or
    operator may either test in
    accordance with the test procedures
    defined in subsection
    (f) (3) (A) (i)
    of this Section or the owner or
    operator may elect to perform
    tests, pursuant to either Method
    25A or Method 18, only during those
    portions of each emission event
    which define the emission profile
    of each emission event occurring
    within the batch cycle.
    For each
    emission event of less than four
    hours
    in duration, the owner or
    operator shall test continuously
    over the entire emission event as
    set forth
    in Subsection
    34
    (f) (3) (A) (i)
    of this Section.
    For
    each emission event of greater than
    four hours in
    duration,
    the owner
    or operator shall elect either to
    perform a minimum of three one hour
    test runs during the emission event
    or shall test continuously over the
    entire emission event within each
    single unit operation in the batch
    process train.
    To demonstrate that
    the portion of the emission event
    to be tested define the emission
    profile for the emission event, the
    owner or operator electing to rely
    on this option shall develop an
    emission profile for the entire
    emission event.
    Such emission
    profile shall be based upon either
    process knowledge or test data
    collected.
    Examples of information
    that could constitute process
    knowledge include,
    but are not
    limited to,
    calculations based
    on
    material balances and process
    stoichiometry.
    Previous test
    results may be used provided such
    results are still relevant to the
    current process vent stream
    conditions.
    iii)
    For purposes of subsection
    (f) (3)
    of
    this Section, the term “emission event”
    shall be defined as
    a discrete period of
    venting that
    is associated with a single
    unit operation.
    For example,
    a
    displacement of vapor resulting from the
    charging of a single unit operation with
    VON will result in a discrete emission
    event that will last through the
    duration
    of the charge and will have an
    average flow rate equal to the rate of
    the charge.
    The expulsion
    of expanded
    single unit operation vapor space, when
    the vessel is heated is also an emission
    event.
    Both of these examples of
    emission events and others may occur in
    the same single unit operation during
    the course of the batch cycle.
    If the
    flow rate measurement for any emission
    event_is zero,
    in accordance with
    Section 218.503(f) (2)
    of the Subpart,
    35
    then such event
    is not an emission event
    for purposes of this Section.
    ~j
    The mass emission rate from the process vent
    or inlet to the control device shall be
    determined by combining concentration and
    flow rate measurements taken simultaneously
    at sampling sites selected in accordance with
    subsection
    (f) (1)
    of this Section throughout
    the batch cycle
    çj
    The mass emission rate from the control
    device outlet shall be obtained by combining
    concentration and flow rate measurements
    taken simultaneously at sampling sites
    selected in accordance with subsection
    (f) (1)
    of this Section throughout the batch cycle
    and
    P1
    The efficiency
    of the control device shall
    be
    determined by integrating the mass emission
    rates obtained in subsections
    (f) (3) (B) and
    (f)(3) (C)
    of this Section, over the time of
    the batch cycle and dividing the difference
    in inlet and outlet mass flow totals by the
    inlet mass flow total.
    gj
    Upon request by the Agency to conduct testing,
    an owner
    or operator of a batch operation which has installed
    a
    scrubber,
    a shell and tube condenser using a non—
    refrigerated cooling media,
    or any other control device
    which meets the criteria of Section
    218.501(c)
    of this
    Subpart, shall demonstrate that such device achieves
    the control efficiency applicable within Section
    218.501 of this Subpart upon the earlier to occur of
    the date the device is replaced or December
    31,
    1999.
    jjj
    The owner or operator of a batch operation may propose
    an alternative test method or procedures to demonstrate
    compliance with the control requirements set forth
    in
    Section 218.501 of this Subpart.
    Such method or
    procedures shall be approved by the Agency and USEPA as
    evidenced by federally enforceable permit conditions.
    LL
    In the absence of
    a request by the Agency to conduct
    performance testing
    in accordance with the provisions
    of this Section, a source may demonstrate compliance by
    the use of engineering estimates or process
    stoichiometry.
    (Source:
    Added at 19
    Ill. Req
    effective
    ______________
    36
    Section 218.504
    Monitoring Requirements for Batch Operations
    ~j
    Every owner or operator using
    an afterburner to comply
    with Section 218.501 of this Subpart shall install,
    calibrate, maintain and operate,
    according to
    manufacturer’s specifications,
    temperature monitoring
    devices with an accuracy of ±1 percent of the
    temperature being measured expressed in degrees
    Celsius, equipped with continuous recorders.
    fl
    Where a catalytic afterburner
    is used,
    temperature
    monitoring devices shall be installed in the gas
    stream_immediately before and after the catalyst
    bed.
    21
    Where an afterburner other than a catalytic
    afterburner
    is used,
    a temperature monitoring
    device shall be installed in the combustion
    chamber.
    ~J..
    Every owner or operator using
    a flare to comply with
    Section 218.501 of this Subpart shall install~
    calibrate,
    maintain and operate, according to
    manufacturer’s specifications,
    a heat sensing device,
    such as an ultra—violet beam sensor or thermocouple,
    at
    the pilot light to indicate continuous presence of
    a
    flame.
    ~j
    Every owner
    or operator using
    a scrubber to comply with
    this Section 218.501 of this Subpart shall install,
    calibrate, maintain,
    and operate, according to
    manufacturer’s specifications,
    the following:
    fl
    A temperature monitoring device for scrubbant
    liquid having an accuracy of ±1 percent of the
    temperature being monitored expressed in degrees
    Celsius and a specific gravity device for
    scrubbant liquid, each equipped with a continuous
    recorder;
    or
    21
    A VON monitoring device used to indicate the
    concentration of VON exiting the control device
    based on a detection principle such as infra—red
    photoionization, or thermal conductivity, each
    equipped with a continuous recorder.
    ~j
    Every owner or operator using a condenser to comply
    with Section 218.501 of this Subpart shall install,
    calibrate, maintain,
    and operate,
    according to
    manufacturer’s specifications,
    the following:
    37
    fl
    A condenser exit temperature monitoring device
    equipped with a continuous recorder and having an
    accuracy of ±1 percent of the temperature being
    monitored expressed in degrees Celsius;
    or
    21
    A VON monitoring device used to indicate the
    concentration of VON such as infra—red,
    photoionization,
    or thermal conductivity, each
    equipped with
    a continuous recorder.
    ~j
    Every owner or operator using a carbon adsorber to
    comply with this Subpart shall install,
    calibrate,
    maintain, and operate, according to the manufacturer’s
    specifications,
    the following equipment:
    j)
    An integrating regeneration steam flow monitoring
    device having an accuracy of ±10 percent, and
    a
    carbon bed temperature monitoring device having an
    accuracy of ±1 percent of the temperature being
    monitored expressed in degrees Celsius, both
    equipped with a continuous recorder;
    or
    21
    A VON monitoring device used to indicate the
    concentration level of VON exiting such device
    based on a detection principle such as infra—red,
    photoionization,
    or thermal conductivity,
    each
    equipped with
    a continuous recorder.
    XI
    Every owner or operator using a boiler or process
    heater with a design heat input capacity less than 44
    Nw to comply with Section 218.501 of
    this Subpart shall
    install,
    calibrate, maintain,
    and operate,
    according to
    the manufacturer’s specifications,
    a temperature
    monitoring device in the firebox with an accuracy of ±
    1 percent of the temperature being measured expressed
    in degrees Celsius, equipped with a continuous
    recorder.
    Any boiler or process heater
    in which all
    process vent streams are introduced with primary fuel
    is exempt from this reguireinent.
    gj
    The owner or operator of
    a process vent shall be
    permitted to monitor by an alternative method or may
    monitor parameters other that those listed in
    subsections
    (a)
    through
    (f)
    of this Section,
    if
    approved by the Agency and USEPA.
    Such alternative
    method or parameters shall
    be contained in the source’s
    operating permit as federally enforceable permit
    conditions.
    ~j
    Notwithstanding subsections
    (a) through
    (g)
    of this
    Section, sources using a scrubber,
    shell and tube
    condenser using a non—refrigerated cooling media,
    or
    38
    other control device meeting the criteria of Section
    218.501Cc)
    of this Subpart,
    are required to monitor
    compliance with the requirements of this Subpart on and
    after the earlier to occur of the date such device
    is
    replaced for any reason or December 31,
    1999.
    (Source:
    Added at 19
    Ill.
    Beg.
    _______,
    effective
    _____________
    Section 218.505
    Reporting and Recordkeeping for Batch
    Operations
    ~j
    Every owner or operator of a de minimis single unit
    ~peration or batch process train exempt under Section
    218.500(c) (1)
    or
    (c) (2)
    of this Subpart shall keep
    records of the uncontrolled total annual mass emissions
    for any de minimis single unit operation or batch
    process train,
    as applicable,
    and documentation
    verifying these values or measurements.
    The
    documentation shall include the engineering
    calculations, any measurements made in accordance with
    Section 218.503
    of this Subpart,
    and the potential or
    permitted number of batch cycles per year or,
    in the
    alternative, total production as represented
    in the
    source’s operating permit.
    ~j
    Every owner or operator of a single unit operation
    exempt under Section 218.500(b) (3)
    or
    (d)
    of this
    Subpart shall keep the following records:
    fl
    The uncontrolled total annual mass emissions and
    documentation verifying these values or
    measurements.
    The documentation shall include any
    engineering calculations, any measurements made in
    accordance with Section 218.503 of this Subpart,
    and the potential or permitted number of batch
    cycles per year,
    or,
    in the alternative,
    total
    production as represented in the source’s
    operating permit.
    21
    The. average flow rate in scfm and documentation
    verifying this value.
    ~j
    Every owner or operator of
    a batch operation sub-lect to
    the control requirements of Section 218.501 of this
    Subpart shall keep records of the following parameters
    required to be monitored under Section 218.504 of this
    Subpart:
    fl
    If using a thermal or catalytic afterburner to
    comply with Section 218.501 of this Subpart,
    records indicating the average combustion chamber
    39
    temperature of the afterburner
    (or the average
    temperature upstream and downstream of the
    catalyst bed for a catalytic afterburner),
    measured continuously and averaged over the same
    time period as the performance test
    21
    If using a flare
    (i.e., steam—assisted,
    air-
    assisted or nonassisted)
    to comply with Section
    218.501 of this Subpart, continuous records of the
    flare pilot flame monitoring and records of all
    periods of operations during which the pilot flame
    is absent.
    ~j
    If using any of the following as a control device,
    the following records:
    Al
    Where a scrubber is used,
    the exit specific
    gravity
    (or alternative parameter which is
    a
    measure of the degree of absorbing liquid
    saturation,
    if approved by the Agency)
    and
    the average exit temperature of the absorbing
    liquid, measured continuously and averaged
    over the same time period as the performance
    test
    (both measured while the vent stream is
    routed normally)
    ~j
    Where a condenser is used, the average exit
    (product side)
    temperature measured
    continuously and averaged over the same time
    period as the performance test while the vent
    stream is routed normally
    ~Q)
    Where a carbon adsorber
    is used,
    the total
    steam mass flow measured continuously and
    averaged over the same time period as the
    performance test
    (full carbon bed cycle),
    temperature of the carbon bed after
    regeneration
    (and within 15 minutes after
    completion of any cooling cycle(s)), and
    duration of the carbon bed steaming cycle
    (all measured while the vent stream is routed
    normally); or
    Q1
    As an alternative to subsection
    (c)(3)(A),
    (c) (3) (B), or
    (c) (3) (C)
    of this Section,
    at
    a
    minimum, records indicating the concentration
    level
    or reading indicated by the VOM
    monitoring device at the outlet of the
    scrubber, condenser,
    or carbon adsorber,
    measured continuously and averaged over the
    same time period as the performance test
    (while the vent stream
    is routed normally).
    40
    ~j
    Every owner
    or operator of
    a single unit operation
    claiming a vent stream concentration exemption level,
    as set forth
    in Section 218.500(d) (1)
    of this Subpart,
    shall maintain records to indicate the vent stream
    concentration is less than or equal to 500 ppmv,
    and
    shall notify the Agency in writing if the vent stream
    concentration at any time equals or exceeds
    500 ppmv,
    within 60 days after such event.
    Such notification
    shall include a copy of all records of such event.
    ~j
    An owner or operator of a batch operation
    subject to
    the control requirements of Section 218.501 of this
    Subpart may maintain alternative records other than
    those listed in subsection
    (c)
    of this Section.
    Any
    alternative recordkeeping shall be approved by the
    Agency and USEPA and shall be contained in the source’s
    operating permit as federally enforceable permit
    conditions.
    XI
    Notwithstanding subsections
    (a) through
    (e)
    of this
    Section, any owner
    or operator of a batch operation
    which uses either a scrubber, shell and tube condenser
    using non—refrigerated cooling media,
    or other control
    device meeting the criteria of Section 218.501(c)
    of
    this Subpart,
    is required to monitor compliance with
    the requirements of this Subpart on and after the
    earlier to occur of the date such device
    is replaced
    for any reason or December 31.
    1999.
    gj
    The owner or operator of a de minimis single unit
    operation or batch process train exempt from the
    control requirements of Section 218.500(c)
    of this
    Subpart shall notify the Agency in writing
    if the
    uncontrolled total annual mass emissions from such de
    minimis single unit operation or batch process train
    exceed the threshold in Section 218.500(c) (1)
    or
    (c) (2)
    of this Subpart, respectively, within
    60 days after the
    event occurs.
    Such notification shall
    include a copy
    of all records of such event.
    j~j.
    Every owner or operator of
    a batch operation required
    to keep records under this Section shall maintain such
    records at the source for a minimum period of three
    years and shall make all such records available to the
    Agency upon request.
    (Source:
    Added at
    19 Ill. Req.
    _______,
    effective
    ______________
    Section 218.506
    Compliance Date
    41
    Every owner or operator of a batch operation subject to Sections
    218.500 through 218.506 of this Subpart shall comply with its
    standards, limitations and mandates by March 15,
    1996, or upon
    initial start up, whichever is later.
    (Source:
    Added at
    19 Ill.
    Req.
    ______,
    effective
    ____________
    _________________________)
    42
    TITLE 35:
    ENVIRONMENTAL PROTECTION
    SUBTITLE B:
    AIR POLLUTION
    CHAPTER I:
    POLLUTION CONTROL BOARD
    SUBCHAPTER
    c:
    EMISSIONS STANDARDS
    AND
    LIMITATIONS
    FOB STATIONARY SOURCES
    PART
    219
    ORGANIC MATERIAL EMISSION STANDARDS AND LIMITATIONS FOB THE
    METRO EAST AREA
    SUBPART A:
    GENERAL PROVISIONS
    Section
    219.100
    219. 101
    219.102
    219.103
    219.104
    219. 105
    219.106
    219.107
    219. 108
    219.109
    219.110
    219.111
    219.112
    219.113
    219.114
    Introduction
    Savings Clause
    Abbreviations and Conversion Factors
    Applicability
    Definitions
    Test Methods and Procedures
    Compliance Dates
    Operation of Afterburners
    Exemptions, Variations,
    and Alternative Means of
    Control or Compliance Determinations
    Vapor Pressure of Volatile Organic Liquids
    Vapor Pressure of Organic Material or Solvents
    Vapor Pressure of Volatile Organic Material
    Incorporations by Reference
    Monitoring for Negligibly-Reactive Compounds
    Compliance with Permit Conditions
    SUBPART B:
    ORGANIC EMISSIONS PROM STORAGE AND LOADING OPERATIONS
    Section
    219.119
    219.120
    219.121
    219.122
    219.123
    219.124
    219.125
    219.126
    219.127
    219.128
    219.129
    Applicability for VOL
    Control Requirements for Storage Containers of VOL
    Storage Containers of VPL
    Loading Operations
    Petroleum Liquid Storage Tanks
    External Floating Roofs
    Compliance Dates
    Compliance Plan
    (Repealed)
    Testing VOL Operations
    Monitoring VOL Operations
    Recordkeeping and Reporting for VOL Operations
    SUBPART C:
    ORGANIC EMISSIONS FROM MISCELLANEOUS EQUIPMENT
    Section
    219.141
    219.142
    219.143
    Separation Operations
    Pumps and Compressors
    Vapor Blowdown
    43
    219. 144
    Section
    219.181
    219.182
    219.183
    219. 184
    219.185
    219.186
    Section
    219.204
    219.205
    219.206
    219.207
    219.208
    219.209
    219.210
    219.211
    Section
    219.301
    219.302
    219.303
    219.304
    Section
    219.401
    219 .402
    219.403
    219.404
    219.405
    Section
    219.421
    219.422
    219.423
    219.424
    219.425
    219.426
    Safety Relief Valves
    SUBPART
    E:
    SOLVENT CLEANING
    Solvent Cleaning in General
    Cold Cleaning
    Open Top Vapor Degreasing
    Conveyorized Deqreasing
    Compliance Schedule
    (Repealed)
    Test Methods
    SUBPART F:
    COATING OPERATIONS
    Emission Limitations
    Daily-Weighted Average Limitations
    Solids Basis Calculation
    Alternative Emission Limitations
    Exemptions from Emission Limitations
    Exemption from General Rule on Use of Organic Material
    Compliance Schedule
    Recordkeeping and Reporting
    SUBPART G:
    USE OF ORGANIC MATERIAL
    Use of Organic Material
    Alternative Standard
    Fuel Combustion Emission Units
    Operations with Compliance Program
    SUBPART H:
    PRINTING AND PUBLISHING
    Flexographic and Rotogravure Printing
    Applicability
    Compliance Schedule
    Recordkeeping and Reporting
    Heatset Web Offset Lithographic Printing
    SUBPART
    Q:
    LEAKS FROM SYNTHETIC
    ORGANIC CHEMICAL AND POLYMER
    MANUFACTURING PLANT
    General Requirements
    Inspection Program Plan for Leaks
    Inspection Program for Leaks
    Repairing Leaks
    Recordkeeping for Leaks
    Report for Leaks
    44
    219.427
    219.428
    219.429
    219.430
    Section
    219.441
    219.442
    219.443
    219.444
    219.445
    219.446
    219.447
    219.448
    219.449
    219.450
    219.451
    219.452
    219.453
    Alternative Program for Leaks
    Open-Ended Valves
    Standards for Control Devices
    Compliance Date
    (Repealed)
    SUBPART R:
    PETROLEUM REFINING AND
    RELATED INDUSTRIES; ASPHALT MATERIALS
    Petroleum Refinery Waste Gas Disposal
    Vacuum Producing Systems
    Wastewater
    (Oil/Water) Separator
    Process Unit Turnarounds
    Leaks:
    General Requirements
    Monitoring Program Plan for Leaks
    Monitoring Program for Leaks
    Recordkeepinq for Leaks
    Reporting for Leaks
    Alternative Program for Leaks
    Sealing Device Requirements
    Compliance Schedule for Leaks
    Compliance Dates
    (Repealed)
    SUBPART
    S:
    RUBBER AND MISCELLANEOUS PLASTIC PRODUCTS
    Section
    219.461
    219.462
    219.463
    219.464
    219.465
    219.466
    Section
    219.480
    219.481
    219.482
    219.483
    219.484
    219.485
    219.486
    219.487
    219.488
    219.489
    Manufacture of Pneumatic Rubber Tires
    Green Tire Spraying Operations
    Alternative Emission Reduction Systems
    Emission Testing
    Compliance Dates
    (Repealed)
    Compliance Plan
    (Repealed)
    SUBPART T:
    PHARMACEUTICAL MANUFACTURING
    Applicability
    Control of Reactors, Distillation Units,
    Crystallizers,
    Centrifuges and Vacuum Dryers
    Control of Air Dryers, Production Equipment Exhaust
    Systems and Filters
    Material Storage and Transfer
    In—Process Tanks
    Leaks
    Other Emission Units
    Testing
    Monitoring for Air Pollution Control Equipment
    Becordkeeping for Air Pollution Control Equipment
    SUBPART V:
    BATCH OPERATIONS AND AIR OXIDATION PROCESSES
    Section
    45
    Applicability for Batch Operations
    _______
    Control Requirements for Batch Operations
    _______
    Determination of Uncontrolled Total Annual Mass
    Emissions and Actual Weighted Average Flow Rate Values
    for Batch Operations
    219.503
    Performance and Testing Requirements for Batch
    Operations
    _______
    Monitoring Requirements for Batch Operations
    Reporting and Recordkeeping for Batch Operations
    ________
    Compliance Date
    Emission Limitations for Air Oxidation
    Definitions (Repealed)
    Savings Clause
    Compliance
    Determination of Applicability
    Emission Limitations for Air Oxidation
    (Renumbered)
    219.526
    Testing and Monitorinq
    219.527
    Compliance Date (Repealed)
    Architectural Coatings
    Paving Operations
    Cutback Asphalt
    Section
    219. 581
    219.582
    219.583
    219.584
    219.585
    EMERGENCY
    219.586
    Section
    219.601
    219 .602
    219. 603
    219. 604
    Bulk Gasoline Plants
    Bulk Gasoline Terminals
    Gasoline Dispensing Operations
    -
    Storage Tank Filling
    Operations
    Gasoline Delivery Vessels
    Gasoline Volatility Standards
    Gasoline Dispensing Operations
    -
    Motor Vehicle Fueling
    Operations
    (Repealed)
    SUBPART
    Z:
    DRY CLEANERS
    Perchloroethylene Dry Cleaners
    Exemptions
    Leaks
    Compliance Dates
    (Repealed)
    219.500
    219.501
    219.502
    219.504
    219.505
    219.506
    219.520
    219.521
    219.522
    219.523
    219.524
    219.525
    Processes
    Processes
    SUBPART W:
    AGRICULTURE
    Section
    219.541
    Pesticide Exception
    SUBPART
    X:
    CONSTRUCTION
    Section
    219.561
    219.562
    219.563
    SUBPART
    Y:
    GASOLINE DISTRIBUTION
    46
    219. 605
    219.606
    219.607
    219.608
    219.609
    219.610
    219.611
    219.612
    219.613
    Section
    219.620
    219. 621
    219.623
    219.624
    219. 625
    219.626
    219.628
    219.630
    219.636
    219.637
    Section
    219.640
    219.642
    219.644
    Section
    219.760
    219.762
    219.764
    219.766
    219.768
    219.770
    219.875
    219.877
    219.879
    219.881
    219.883
    219.886
    Compliance Plan (Repealed)
    Exception to Compliance Plan
    (Repealed)
    Standards for Petroleum Solvent Dry Cleaners
    Operating Practices for Petroleum Solvent Dry Cleaners
    Program for Inspection and Repair of Leaks
    Testing and Monitoring
    Exemption for Petroleum Solvent Dry Cleaners
    Compliance Dates
    (Repealed)
    Compliance Plan (Repealed)
    SUBPART AA:
    PAINT AND INK MANUFACTURING
    Applicability
    Exemption for Waterbase Material and Heatset-Offset Ink
    Permit Conditions
    Open-Top Mills, Tanks,
    Vats
    or Vessels
    Grinding Mills
    Storage Tanks
    Leaks
    Clean Up
    Compliance Schedule
    Recordkeeping and Reporting
    SUBPART BB:
    POLYSTYRENE PLANTS
    Applicability
    Emissions Limitation at Polystyrene Plants
    Emissions Testing
    SUBPART GG:
    MARINE TERMINALS
    Applicability
    Control Requirements
    Compliance Certification
    Leaks
    Testing and Monitoring
    Recordkeeping and Reporting
    Applicability of Subpart BB (Renumbered)
    Emissions Limitation at Polystyrene Plants
    (Renumbered)
    Compliance Date
    (Repealed)
    Compliance Plan
    (Repealed)
    Special Requirements for Compliance Plan (Repealed)
    Emissions Testing (Renumbered)
    SUBPART PP:
    MISCELLANEOUS FABRICATED PRODUCT MANUFACTURING
    PROCESSES
    47
    Section
    219.920
    Applicability
    219.923
    Permit Conditions
    219.926
    Control Requirements
    219.927
    Compliance Schedule
    219.928
    Testing
    SUBPART
    QQ:
    MISCELLANEOUS FORMULATION MANUFACTURING PROCESSES
    Section
    219 .940
    Applicability
    219.943
    Permit Conditions
    219.946
    Control Requirements
    219.947
    Compliance Schedule
    219.948
    Testing
    SUBPART BR:
    MISCELLANEOUS ORGANIC CHEMICAL MANUFACTURING
    PROCESSES
    Section
    219.960
    Applicability
    219.963
    Permit Conditions
    219.966
    Control Requirements
    219.967
    Compliance Schedule
    219.968
    Testing
    SUBPART TT:
    OTHER EMISSION UNITS
    Section
    219.980
    Applicability
    219.983
    Permit Conditions
    219.986
    Control Requirements
    219.987
    Compliance Schedule
    219.988
    Testing
    SUBPART UU:
    RECORDKEEPING AND REPORTING
    Section
    219.990
    Exempt Emission Units
    219.991
    Subject Emission Units
    Appendix A
    List of Chemicals Defining Synthetic Organic
    Chemical and Polymer Manufacturing
    Appendix B
    VOM Measurement Techniques
    for Capture Efficiency
    Appendix C
    Reference Methods and Procedures
    Appendix D
    Coefficients for the Total Resource Effectiveness
    Index
    (TRE)
    Equation
    Appendix E
    List of Affected Marine Terminals
    AUTHORITY:
    Implementing
    Section
    10 and authorized by Section
    28.5 of the Environmental Protection Act
    415
    ILCS 5/10 and
    28.5.
    48
    SOURCE:
    Adopted at R91—8 at 15
    Ill.
    Beg.
    12491, effective August
    16,
    1991;
    amended in R9l—24 at 16
    Ill. Beg.
    13597,
    effective
    August 24,
    1992;
    amended
    in R91—30 at
    16
    Ill.
    Beg.
    13883,
    effective August 24,
    1992; emergency amendment in R93-12 at
    17
    Ill.
    Req.
    8295,
    effective May 24,
    1993,
    for a maximum of 150
    days;
    amended in R93-9
    at
    17
    Ill.
    Beg.
    16918, effective September
    27,
    1993 and October 21,
    1993; amended in R93-28 at
    18
    Ill.
    Req.
    4242, effective March
    3,
    1994; amended in R94-12 at
    18
    Ill.
    Beg.
    14987, effective September 21,
    1994;
    amended in R94—l5 at
    18
    Ill.
    Req. 16415, effective October 25,
    1994;
    amended in R94-16 at 18
    Ill.
    Beg.
    16980,
    effective November 15,
    1994;
    amended in R94—33
    at 19 Ill.
    Req.
    ________,
    effective
    ______________________;
    emergency amendment in B95-10 at
    ___________
    Ill. Req.
    ________
    effective
    _______________
    for a maximum of 150 days.
    BOARD NOTE:
    This Part implements the Illinois Environmental
    Protection Act as of July
    1,
    1994.
    SUBPART V:
    BATCH OPERATIONS AND AIR OXIDATION PROCESSES
    Section 219.500
    Applicability for Batch Operations
    ~
    The control requirements set forth
    in Section 219.501
    of this Subpart shall apply to process vents associated
    with batch operations at sources identified by any of
    the following four-digit standard industrial
    classification
    (“SIC”)
    codes,
    as defined in the 1987
    edition of the Federal Standard Industrial
    Classification Manual: SIC 2821,
    2833,
    2834,
    2861,
    2865,
    2869,
    and 2879.
    ~j
    The requirements of Sections 219.500 through 219.506
    shall not apply to:
    fl
    Any emission unit included within the category
    specified in 35
    Ill.
    Adm. Code Part 219,
    Subpart
    B or T
    21
    Any emission unit included within the category
    specified in Sections 219.520 through 219.527 of
    this Subpart; and
    ~j
    Any emission unit included within an Early
    Reduction Program, as specified in 40 CFR Part 63,
    and published in
    57 Fed. Beg.
    61970
    (December
    29,
    1992), evidenced by a timely enforceable
    commitment approved by USEPA.
    ~j
    The following single unit operations and batch process
    trains are sub-ject to this Subpart but are considered
    to be de niinjmis and are, therefore,
    exempt from the
    49
    control requirements of Section 219.501 of this
    Subpart.
    However, the recordkeepinci and reporting
    requirements
    in Section 219.505 of this Subpart shall
    apply to such de minimis single unit operations and
    batch process trains:
    jj
    Within
    a batch operation,
    any single unit
    operation with uncontrolled total annual mass
    emissions of less than or equal to 500 lb/yr of
    VOM.
    Such single unit operations are also
    excluded from the calculation of the total annual
    mass emissions for a batch process train.
    If the
    uncontrolled total annual mass emissions from such
    exempt single unit operation exceed 500 lb/yr of
    VON in any subsequent year,
    the source shall
    calculate applicability in accordance with
    subsection
    (d) of this Section for both the
    individual single unit operation and the batch
    process train containing the single unit
    operation; and
    21
    Any batch process
    train containing process vents
    that have,
    in the aggregate,
    uncontrolled total
    annual mass emissions,
    as determined
    in accordance
    with Section 219.502(a)
    of this
    Subpart,
    of
    less
    than 30,000 lb/yr of VON for all products
    manufactured in such batch process train.
    ~jJ
    The applicability equations in subsection
    (e) of this
    Section, which require the calculation of uncontrolled
    total annual mass emissions and flow rate value,
    shall
    be used to determine whether a single unit operation or
    a batch process train
    is subject to the control
    requirements set forth in Section 219.501 of this
    Subpart. The applicability equation shall be applied to
    the following:
    fl.
    Any single unit operation with uncontrolled total
    annual mass emissions that exceed 500 lb/yr and
    with a VOM concentration greater than 500 ppmv.
    In this individual determination, no
    applicability
    analysis shall be performed for any single unit
    operation with a VOM concentration of less than or
    equal to 500 ppmv; and
    21
    Any batch process train containing process vents
    which,
    in the aggregate,
    have uncontrolled total
    annual mass emissions of 30,000 lb/yr or more of
    •
    VOM from all products manufactured
    in the batch
    process train.
    Any single unit operation with
    uncontrolled total annual mass emissions exceeding
    500 lb/yr. regardless of VOM concentration,
    shall
    50
    be included in the aggregate applicability
    analysis.
    ~j
    Applicability equations
    fl
    The applicability
    equations in this subsection are
    specific to volatility.
    21
    For purposes of this subsection, the following
    abbreviations apply:
    Al
    FR
    =
    Vent stream flow rate, scfm
    ~j
    TJTANE
    =
    Uncontrolled total annual mass
    emissions of VOM, expressed as
    lb/yr
    çj
    WAV
    =
    Weighted average volatility
    ~j
    MVOM
    =
    Mass of VON component I
    ~j
    MWVOM~=
    Molecular weight of VON component
    i; and
    fi
    ~
    =
    Vapor pressure of VOM component
    i.
    ~J
    Weighted average volatility shall be calculated as
    follows:
    n
    (MVOM1)
    ~
    (VP1)x
    i=l
    (MWVOM1)
    WAV
    =
    n
    (NVOM1)
    1=1
    (MWVOM1)
    4j.
    For purposes of determining applicability,
    flow
    rate values shall
    be calculated as follows:
    ~j
    Low WAV has a vapor pressure less than or
    equal
    to 75
    mmjg
    at 20°C (68°F), and shall
    use the following equation:
    FR
    =
    0.07
    (UTANE)1
    —
    1,821
    ~j
    Moderate WAV has a vapor pressure greater
    than 75 mmHg but less than or equal to 150
    mmHg at 20°C (68°F), and shall use the
    following equation:
    51
    FR
    =
    0.031
    (UTANE)1
    —
    494
    Qj
    High WAV has
    a vapor pressure greater than
    150 mmHg at 20°C(68°F),and shall use the
    following equation:
    FR
    =
    0.013
    (UTAME)
    1
    —
    301
    ~j.. To determine the vapor pressure of VOM, the
    applicable methods and procedures in Section
    219.111 of this Part shall
    apply.
    (Source:
    Added at
    19
    Ill. Beg.
    _______,
    effective
    ___________
    Section 219.501
    Control Requirements for Batch Operations
    ~j
    Every owner or operator of
    a single unit operation with
    an average flow rate, as determined
    in accordance with
    Section 219.502(b)
    of this Subpart, below the flow rate
    value calculated by the applicability equations
    contained in Section 219.500(e)
    of this Subpart,
    shall
    reduce uncontrolled VOM emissions from such single unit
    operation by an overall efficiency,
    on average,
    of at
    least 90 percent,
    or 20 ppmv,
    per batch cycle.
    ~j
    Every owner or operator of a batch process train with
    an average flow rate,
    as determined in accordance with
    Section 219.502(b) (2)
    of this Subpart,
    below the flow
    rate value calculated by the applicability equations
    contained in Section 219.500(e)
    of this Subpart,
    shall
    reduce uncontrolled VOM emissions from such batch
    process train by an overall efficiency,
    on average,
    of
    at least 90 percent, or 20 ppmv, per batch cycle.
    For
    purposes of demonstrating compliance with the emission
    limitations set forth
    in this Section, any control
    device meeting the criteria in subsection
    (c)
    of this
    Section shall
    be deemed to achieve
    a control efficiency
    of 90 percent, or
    20 ppmv, per batch cycle,
    as
    applicable.
    ~j
    Notwithstanding subsectIon
    (a)
    or
    (b)
    of this Section,
    apy source that has installed on or before March 15,
    1995,
    any control device which
    is demonstrated to the
    Agencv’s satisfaction to be unable to meet the
    applicable control requirements of this Section,
    scrubber, or shell and tube condenser using a non—
    refrigerated cooling media,
    and such device achieves at
    least
    81 percent control efficiency of VON emissions,
    is required to meet the 90 percent emission limitation
    or 20 ppmv VOM concentration set forth
    in subsection
    (a)
    or
    (b)
    of this Section, as applicable,
    upon the
    52
    earlier to occur of the date the device is replaced for
    any reason,
    including, but not limited to, normal
    maintenance, malfunction, accident, and obsolescence,
    or December 31,
    1999.
    A scrubber, shell and tube
    condenser using a non—refrigerated cooling media,
    or
    other control device meeting the criteria of this
    subsection,
    is considered replaced when:
    fl
    All of the device
    is replaced; or
    21
    When either the cost to repair the device or the
    cost to replace part of the device exceeds
    50
    percent of the cost of replacing the entire device
    with a control device that complies with the 90
    percent emission limitation or
    20 ppmv VOM
    concentration level in subsection
    (a)
    of this
    Section,
    as ap~licab1e.
    ~j
    If a boiler or process heater
    is used to comply with
    this Section. the vent stream shall be introduced into
    the flame zone of the boiler or process heater.
    ,~j
    If a flare is used to comply with this Section,
    it
    shall comply with the requirements of 40 CFR 60.18,
    incorporated by reference at Section 219.112 of this
    Part.
    The flare operation requirements of 40 CFR 60.18
    do not apply
    if a process, not subject to this Subpart,
    vents an emergency relief discharge into
    a common flare
    header and causes the flare servicing the process
    sub-lect to this Subpart to not comply with one or more
    of the provisions of 40 CFR 60.18.
    (Source:
    Added at 19 Ill. Beg.
    _______,
    effective
    ______________
    Section 219.502
    Determination of Uncontrolled Total Annual
    Mass Emissions and Actual Weighted Average
    Flow Rate Values for Batch Operations
    ~j
    Uncontrolled total annual mass emissions shall be
    determined by the following methods:
    fl
    Direct process vent emissions measurements taken
    prior to any release to the atmosphere,
    following
    any recovery device and prior to any control
    device, provided such measurements conform with
    the requirements of measuring the mass flow rate
    of VOM incoming to the control device as set forth
    in Section 219.503(f)(2),
    (f)(3)(A)
    and
    (f)(3’i(B)
    of this Subpart;
    or
    53
    21
    Engineering estimates of the uncontrolled VOM
    emissions from a process vent or process vents,
    in
    the aggregate, within a batch process train,
    using
    either the potential or permitted number of batch
    cycles per year or total production as represented
    in the source’s operating permit as follows:
    Al
    Engineering estimates of the uncontrolled VON
    emissions shall be based upon accepted
    chemical engineering principles, measurable
    process parameters,
    or physical or chemical
    laws and their properties.
    Examples of
    methods include, but are not limited to, the
    following:
    jj
    Use of material balances based on
    process stoichiometry to estimate
    maximum VON concentrations
    JJ~1
    Estimation of maximum flow rate based on
    physical equipment design such as pump
    or blower capacities;
    and
    iii) Estimation of VON concentrations based
    on saturation conditions.
    ~j
    All data,
    assumptions and procedures used in
    any engineering estimate shall be documented.
    ~
    Average flow rate shall be determined by any of the
    following methods:
    fl
    Direct process vent flow rate measurements taken
    prior to any release to the atmosphere,
    following
    any recovery device and prior to any control
    device, provided such measurements conform with
    the requirements of measuring incoming volumetric
    flow rate set forth in Section 219.503(e) (2)
    of
    this Subpart
    21
    Average flow rate for a single unit operation
    having multiple emission events or batch process
    trains shall be the weighted average flow rate,
    calculated as follows:
    n.
    ~ AFR~ x ADEJJ
    i=
    1
    WAF
    ______________
    n
    ~
    (ADE1I
    54
    11
    where:
    =
    Actual weighted average flow
    rate for
    a single unit
    operation or batch process
    train
    AERI
    =
    Average flow rate per emission
    event
    =
    Annual duration of emission
    event;
    and
    TI
    =
    Number of emission events.
    For purposes of this formula, the term “emission
    event” shall
    be defined as a discrete period of
    venting that is associated with a single unit
    operation.
    For example,
    a displacement of vapor
    resulting from the charging of a single unit
    operation with VON will result
    in
    a discrete
    emission event that will last through the duration
    of the charge and will have an average flow rate
    equal to the rate of the charge.
    The expulsion of
    expanded vapor space when the single unit
    operation is heated is also an emission event.
    Both of these examples of emission events and
    others may occur in the same single unit operation
    during the course of the batch cycle.
    If the flow
    rate measurement for any emission event
    is zero,
    according to Section 218.503(f) (2) of this
    Subpart, then such event
    is not an emission event
    for purposes of this Section.
    ~j.
    Engineering estimates calculated
    in accordance
    with the requirements in subsection
    (a) (2)
    of this
    Section.
    ~J
    For purposes of determining the average flow rate for
    steam vacuuming systems, the steam flow shall be
    included in the average flow rate calculation.
    (Source:
    Added at 19
    Ill. Beg.
    _______,
    effective
    ____________
    ______________________ )
    Section 219.503
    Performance and Testing Requirements for
    Batch Operations
    ~j
    Upon the Agency’s request, the owner or operator of
    a
    batch operation shall conduct testing to demonstrate
    compliance with Section 219.501 of this Subpart.
    The
    owner or operator shall,
    at its own expense, conduct
    55
    such tests in accordance with the applicable test
    methods and procedures specified in Section 219.503(d),
    (e),
    and
    (f) of this Subpart.
    ~j
    Notwithstanding
    subsection
    (a) of this Section, flares
    and process boilers used to comply with control
    requirements of Section 219.501 of this Subpart shall
    be exempt from performance testing requirements.
    gj
    When a flare is used to comply with the control
    requirements of Section 219.501 of this Subpart, the
    flare shall comply with the requirements of 40 CFR
    60.18,
    incorporated by reference at Section 219.112 of
    this Part.
    ~j
    The owner or operator of
    a batch operation that
    is
    exempt from the control requirements of Section 219.501
    of this Subpart shall demonstrate, upon the Agency’s
    request, the absence of oversized gas moving equipment
    in any manifold.
    Gas moving equipment shall be
    considered oversized if
    it exceeds the maximum
    requirements of the exhaust flow rate by more than 30
    percent.
    ~j
    For the purpose of demonstrating compliance with the
    control requirements in Section
    219.501
    of this
    Subpart, the batch operation shall be run at
    representative operating conditions and flow rates
    during any performance test.
    fl
    The following methods
    in 40 CFR 60, Appendix A,
    incorporated by reference at Section 219.112 of this
    Part,
    shall be used to demonstrate compliance with the
    reduction efficiency requirement set forth
    in Section
    219.501 of this Subpart:
    fl
    Method
    1 or
    lA. as appropriate,
    for selection of
    the sampling sites
    if the flow measuring device is
    not a rotameter.
    The control device inlet
    sampling site for determination of
    vent stream VOM
    composition reduction efficiency shall be prior to
    the control device and after the control device
    21
    Method
    2,
    2A,
    2C.
    or
    2D.
    as appropriate,
    for
    determination of gas stream volumetric flow rate
    flow measurements, which shall be taken
    continuously.
    No traverse is necessary when the
    flow measuring device
    is an ultrasonic probe
    ,~j
    Method 25A or Method
    18,
    if applicable,
    to
    determine the concentration of VON in the control
    device inlet and outlet
    56
    Al
    The sampling time for each run shall
    be as
    follows:
    jj
    For batch cycles
    less than eight hours
    in length, readings shall be taken
    continuously over the entire length of
    the batch cycle with a maximum of 15—
    minute intervals between measurements
    if
    using Method 25A.
    If using Method 18,
    readings shall be taken continuously
    with a maximum of 15-minute intervals
    between measurements throughout the
    batch cycle unless it becomes necessary
    to change the ilnpinger train,
    in which
    case a 30-minute interval shall not be
    exceeded.
    Lii
    For batch cycles of eight hours and
    greater
    in length, the owner or operator
    may either test in accordance with the
    test procedures defined in
    subsection
    (f) (3) (A) (i)
    of this Section or the
    owner or operator may elect to perform
    tests, pursuant to either Method 25A or
    Method 18, only during those portions of
    each emission event which define the
    emission profile of each emission event
    occurring within the batch cycle.
    For
    each emission event of less than four
    hours
    in duration, the owner or operator
    shall test continuously over the entire
    emission event as set forth
    in
    subsection
    (f) (3) (A) (i)
    of this Section.
    For each emission event of greater than
    four hours in duration, the owner or
    operator shall elect either to perform
    a
    minimum of three one hour test runs
    during the emission event or shall test
    continuously over the entire emission
    event within each single unit operation
    in the batch process train.
    To
    demonstrate that the portion of the
    emission event to be tested define the
    emission profile for the emission event.
    the owner or operator electing to rely
    on this option shall develop an emission
    profile for the entire emission event.
    Such_emission profile shall be based
    upàn either process knowledge or test
    data collected.
    Examples of information
    that could constitute process knowledge
    include, but are not limited to,
    57
    calculations based on material balances
    and process stoichiometry.
    Previous
    test results may be used provided such
    results are still relevant to the
    current process vent stream conditions.
    iii)
    For purposes of subsection
    (f) (3)
    of
    this Section, the term “emission event”
    shall be defined as a discrete period of
    venting that is associated with a single
    unit operation.
    For example,
    a
    displacement of vapor resulting from the
    charging of a single unit operation with
    VOM will result in a discrete emission
    event that will last through the
    duration of the charge and will have an
    average flow rate equal to the rate of
    the charge.
    The expulsion of expanded
    single unit operation vapor space, when
    the vessel is heated is also an emission
    event.
    Both of these examples of
    emission events and others may occur in
    the same single unit operation during
    the course of the batch cycle.
    If the
    flow rate measurement for any emission
    event is zero,
    in accordance with
    Section 218.503(f) (2)
    of the Subpart,
    then such event
    is not an emission event
    for purposes of this Section.
    ~
    The mass emission rate from the process vent
    or inlet to the control device shall
    be
    determined by combining concentration and
    flow rate measurements taken simultaneously
    at sampling sites selected in accordance with
    subsection
    (f) (1)
    of this Section throughout
    the batch cycle
    ~j
    The mass emission rate from the control
    device outlet shall
    be obtained by combining
    concentration and flow rate measurements
    taken simultaneously at sampling sites
    selected
    in accordance with subsection
    (f) (1)
    of this Section throughout the batch cycle
    arid
    Qj
    The efficiency of the control device shall be
    determined by integrating the mass emission
    rates obtained in subsections
    (f) (3) (B)
    and
    (f) (3) (C)
    of this Section,
    over the time of
    the batch cycle and dividing the difference
    58
    in inlet and outlet mass flow totals by the
    inlet mass flow total.
    gj
    Upon request by the Agency to conduct testing, an owner
    or operator of a batch operation which has installed a
    scrubber,
    a shell and tube condenser using
    a non—
    refrigerated cooling media,
    or any other control device
    which meets the criteria of Section 219.501(c)
    of this
    Subpart, shall demonstrate that such device achieves
    the control efficiency applicable within Section
    219.501 of this Subpart upon the earlier to occur of
    the date the device
    is replaced or December 31,
    1999.
    ~j
    The owner or operator of a batch operation may propose
    an alternative test method or procedures to demonstrate
    compliance with the control requirements set forth in
    Section 219.501 of this Subpart.
    Such method or
    procedures shall be approved by the Agency and USEPA as
    evidenced by federally enforceable permit conditions.
    jj
    In the absence of a request by the Agency to conduct
    performance testing in accordance with the provisions
    of this Section,
    a source may demonstrate compliance by
    the use of engineering estimates or process
    stoichiometry.
    (Source:
    Added at 19 Ill. Beg.
    _______,
    effective
    ______________
    _______________________ )
    Section 219.504
    Monitoring Requirements for Batch Operations
    ~J
    Every owner
    or operator using an afterburner to comply
    with Section 219.501 of this Subpart shall install,
    calibrate, maintain and operate,
    according to
    manufacturer’s specifications,
    temperature monitoring
    devices with an accuracy of ±1 percent of the
    temperature being measured expressed in degrees
    Celsius, equipped with continuous recorders.
    fl
    Where a catalytic afterburner is used,
    temperature
    monitoring devices shall be installed in the gas
    stream immediately before and after the catalyst
    bed.
    21
    Where an afterburner other than a catalytic
    afterburner is used,
    a temperature monitoring
    device shall be installed in the combustion
    chamber.
    ~j
    Every owner or operator using a flare to comply with
    Section 219.501 of this Subpart, shall installr
    calibrate, maintain and operate,
    according to
    59
    manufacturer’s specifications,
    a heat sensing device,
    such as an ultra—violet beam sensor or thermocouple,
    at
    the pilot light to indicate continuous presence of
    a
    flame.
    ~.
    Every owner or operator using a scrubber to comply with
    this Section 219.501 of this Subpart shall
    install,
    calibrate,
    maintain, and operate, according to
    manufacturer’s specifications, the following:
    fl..
    A temperature monitoring device for scrubbant
    liguid having an accuracy of ±1 percent of the
    temperature being monitored expressed in degrees
    Celsius and a specific gravity device for
    scrubbant liquid,
    each equipped with
    a continuous
    recorder; or
    21
    A VOM monitoring device used to indicate the
    concentration of VOM exiting the control device
    based on a detection principle such as infra—red
    photoionization,
    or thermal conductivity, each
    eq~uippedwith a continuous recorder.
    ~J
    Every owner or operator using
    a condenser to comply
    with Section 219.501 of this Subpart shall install,
    calibrate,
    maintain,
    and operate, according to
    manufacturer’s specifications,
    the following:
    fl
    A condenser exit temperature monitoring device
    equipped with a continuous recorder and having an
    accuracy of ±1 percent of the temperature being
    monitored expressed in degrees Celsius; or
    21
    A VON monitoring device used to indicate the
    concentration of VON such as infra—red,
    photoionization,
    or thermal conductivity, each
    equipped with a continuous recorder.
    ~j
    Every owner or operator using a carbon adsorber to
    comply with this Subpart shall install,
    calibrate,
    maintain, and operate, according to the manufacturer’s
    specifications,
    the following equipment:
    fl
    An integrating regeneration steam flow monitoring
    device having an accuracy of ±10 percent, and a
    carbon bed temperature monitoring device having an
    accuracy of ±1 percent of the temperature being
    monitored expressed in degrees Celsius, both
    •
    equipped with a continuous recorder; or
    21
    A VON monitoring device used to indicate the
    concentration level
    of VOM exiting such device
    60
    based
    on a detection principle such as infra—red,
    photoionization,
    or thermal conductivity, each
    equipped with
    a continuOus recorder.
    Z~
    Every owner or operator using
    a boiler or process
    heater with
    a design heat input capacity less than 44
    Mw to comply with Section 219.501 of this Subpart shall
    install, calibrate,
    maintain, and operate, according to
    the manufacturer’s specifications,
    a temperature
    monitoring device in the firebox with an accuracy of ±
    1 Percent of the temperature being measured expressed
    in degrees Celsius, equipped with a continuous
    recorder.
    Any boiler or process heater
    in which all
    process vent streams are introduced with primary fuel
    is exempt from this requirement.
    g~
    The owner or operator of
    a process vent shall be
    p~rmittedto monitor by an alternative method or may
    monitor parameters other that those
    listed
    in
    subsections
    (a) through
    (f)
    of this Section,
    if
    approved by the Agency and USEPA.
    Such alternative
    method or parameters shall be contained in the source’s
    operating permit as federally enforceable permit
    conditions.
    iii
    Notwithstanding subsections
    (a) through
    (g)
    of this
    Section, sources using a scrubber,
    shell and tube
    condenser using a non—refrigerated cooling media,
    or
    other control device meeting the criteria of Section
    219.501(c)
    of this Subpart, are required to monitor
    compliance with the requirements
    of this Subpart on and
    after the earlier to occur of the date such device
    is
    replaced for any reason or December 31,
    1999.
    (Source:
    Added at 19
    Ill. Beg.
    _______,
    effective
    ______________
    ______________________ )
    Section 219.505
    Reporting and Recordkeeping for Batch
    Operations
    ~j
    Every owner
    or operator of a de minimis single unit
    operation or batch process train exempt under Section
    219.SOOtc) (1) or
    (c) (2)
    of this Subpart shall keep
    records of the uncontrolled total annual mass emissions
    for any de minimis single unit operation or batch
    process train,
    as applicable, and documentation
    verifying these values or measurements.
    The
    documentation shall include the engineering
    calculations, any measurements made in accordance with
    Section 218.503 of this Subpart, and the potential or
    permitted number of batch cycles per year or,
    in the
    61
    alternative, total production as represented
    in the
    source’s operating permit.
    ~
    Every owner or operator of
    a single unit operation
    exempt under Section 219.500(b) (3) or
    (d)
    of this
    Subpart shall keep the following records:
    fl.
    The uncontrolled total annual mass emissions and
    documentation verifying these values or
    measurements.
    The documentation shall include any
    engineering calculations, any measurements made in
    accordance with Section 218.503 of this Subpart,
    and the potential or permitted number of batch
    cycles per year
    or.,
    in the alternative,
    total
    production as represented in the source’s
    operating permit..
    21
    The average flow rate in
    scfni and documentation
    verifying this value.
    çj
    Every owner or operator of a batch operation subject to
    the control requirements of Section 219.501 of this
    Subpart shall keep records of the following parameters
    required to be monitored under Section 219.504 of this
    Subpart:
    fl
    If using a thermal or catalytic afterburner to
    comply with Section 219.501 of this Subpart,
    records indicating the average combustion chamber
    temperature of the afterburner
    (or the average
    temperature upstream and downstream of the
    catalyst bed for a catalytic afterburner),
    measured continuously and averaged over the same
    time period as the performance test
    21
    If using a flare
    (i.e.,
    steam—assisted,
    air—
    assisted or nonassisted)
    to comply with Section
    219.501 of this Subpart, continuous records of the
    flare pilot flame monitoring and records of all
    periods of operations during which the pilot flame
    is absent.
    ~
    If using any of the following as
    a control devic~
    the following records:
    Al
    Where a scrubber
    is used,
    the exit specific
    gravity
    (or alternative parameter which
    is
    a
    measure of the degree of absorbing liquid
    •
    saturation,
    if approved by the Agency)
    and
    the average exit temperature of the absorbing
    liquid, measured continuously and averaged
    over the same time period as the performance
    62
    test
    (both measured while the vent stream is
    routed normally)
    ~j
    Where a condenser is used,
    the average exit
    cproduct side)
    temperature measured
    continuously and averaged over the same time
    period as the performance test while the vent
    stream is routed normally
    ~j
    Where a carbon adsorber is used,
    the total
    steam mass flow measured continuously and
    averaged over the same time period as the
    performance test (full carbon bed cycle),
    temperature of the carbon bed after
    regeneration
    (and within
    15 minutes after
    completion of any cooling cycle(s)),
    and
    duration of the carbon bed steaming cycle
    (all measured while the vent stream is routed
    normally);
    or
    ~j
    As an alternative to subsections
    (c)(3)JA),
    (c)(3)(B),
    or
    (c)(3)(C)
    of this Section,
    at a
    minimum, records indicating the concentration
    level or reading indicated by the VOM
    monitoring device at the outlet of the
    scrubber,
    condenser,
    or carbon adsorber,
    measured continuously and averaged over the
    same time period as the performance test
    (while the vent stream is routed normally).
    ~
    Every owner or operator of a single unit operation
    claiming a vent stream concentration exemption level,
    as set forth in Section 218.500(d) (1)
    of this Subpart,
    shall maintain records to indicate the vent stream
    concentration is less than or equal to 500 ppinv,
    and
    shall notify the Agency
    in writing
    if the vent stream
    concentration at any time equals or exceeds 500 ppmv,
    within
    60 days after such event.
    Such notification
    shall include a copy of all records of such event.
    ~J.
    An owner or operator of
    a batch operation subject to
    the control requirements of Section 219.501 of this
    Subpart may maintain alternative records other than
    those listed in subsection
    (c)
    of this Section.
    Any
    alternative recordkeeping shall be approved by the
    Agency and USEPA and shall be contained in the source’s
    operating permit as federally enforceable permit
    conditions.
    fl
    Notwithstanding subsections
    (a)
    through
    (e)
    of this
    Section, any owner or operator of a batch operation
    which uses either
    a
    scrubber, shell and tube condenser
    •
    63
    using non—refrigerated cooling media,
    or other control
    device meeting the criteria of Section 219.501(c)
    of
    this Subpart,
    is required to monitor compliance with
    the requirements of this Subpart on and after the
    earlier to occur of the date such device
    is replaced
    for any reason or December 31,
    1999.
    gj
    The owner or operator of a de minimis single unit
    operation or batch process train exempt from the
    control requirements of Section 219.500(c)
    of this
    Subpart shall notify the Agency in writing
    if the
    uncontrolled total annual mass emissions from such de
    minimis single unit operation or batch process train
    exceed the threshold in Section 219.500(c) (1) or
    (c) (2)
    of this Subpart,
    respectively, within 60 days after the
    event occurs.
    Such notification shall include a copy
    of all records of such event.
    ~j
    Every owner or operator of
    a batch operation required
    to keep records under this Section shall maintain such
    records at the source for
    a minimum period of three
    years and shall make all such records available to the
    Agency upon request.
    (Source:
    Added at
    19
    Ill. Req.
    _______,
    effective
    _____________
    _________________________ )
    Section 219.506
    Compliance Date
    Every owner or operator of
    a batch operation subject to Sections
    219.500 through 219.506 of this Subpart shall comply with its
    standards,
    limitations and mandates by March
    15,
    1996,
    or upon
    initial start up, whichever is later.
    (Source:
    Added at
    19
    Ill. Reg.
    _______,
    effective
    ______________
    IT IS SO ORDERED.
    I, Dorothy M.
    Gunn,
    Clerk of the Illinois Pollution Control
    Board, hereby certify that the abov~opinionand order was
    adopted on ~e
    /
    ~-
    day of
    _______________,
    1995, by a
    vote of
    ___________
    •
    .
    Dorothy M. G)~n,Clerk
    Illinois Po~&itionControl Board

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