ILLINOIS POLLUTION CONTROL BOARD

June 3,

1993

IN THE

MATTER OF:

)

R93—2

PRETREATMENT UPDATE, USEPA

)

 (Identical in Substance Rules)

REGULATIONS

 (July

1,

1992

through December 31,

 1992)

)

Proposal for Public Comment.

PROPOSED OPINION

AND

ORDER OF THE BOARD

 (by J. Anderson):

Pursuant to Sections 13.3 of the Environmental Protection

Act

 (Act)

 (Ill.

 Rev.

 Stat.

 1991,

ch.

 111½, par.

 1013.3

415

 ILCS

5/13.3)), the Board proposes amendments to the wastewater

pretreatment regulations.

Section 13.3 of the Act requires the Board to adopt

regulations which are “identical in substance” with USEPA

pretreatment regulations adopted pursuant Sections 307 and 402 of

the Clean Water Act.

 Section 13.3 of the Act provides that

Section

 5 of the Administrative Procedure Act

 (Ill.

 Rev.

 Stat. ch

127,

 par. 1001—1 et sep.

5

 ILCS 100/1—1 et secT.)

 shall not

apply.

 Because this rulemaking is not subject to Section 5 of

the APA,

 it is not subject to first notice or to second notice

review by JCAR.

 However, Section 13.3 of the Act does require

 the Board to provide for notice and public comment before rules

are filed with the Secretary of State.

Section 7.2 of the Act includes a definition of “identical

in substance”.

 This codifies the Board’s past interpretations of

its mandate under Section 13.3 of the Act.

The pretreatment regulations govern discharges by industrial

users to publicly owned treatment works (POTWs).

 The rules are

intended to prevent industrial discharges from passing through

POTW5 without adequate treatment to waters of the State, and to

prevent industrial discharges from interfering with the operation

of the treatment plant.

 Effluent discharges are regulated

pursuant to

 35 Ill.

 Adin.

 Code 304 and 309.

The Illinois pretreatment rules are contained in 35 Ill.

Adm. Code 307 and 310, and more recently,

 as part of the R91-5

rulemaking, Part 309.

 Part 307 includes the categorical

pretreatment standards, which are incorporated by reference from

the USEPA rules.

 Part 310 specifies how a POTW sets up a

pretreatment program, and how industrial users get pretreatment

permits or authorizations to discharge.

 Part 309 sets forth the

NPDES permit requirements.

 Although Part 309 does not pertain

directly to sewer users and industrial wastewater pretreatment,

it includes requirements at Section 309.103 that pertain to NPDES

permittees required to have an approved pretreatment program.

b~3-D

107

2

The federal wastewater pretreatment regulations are found at

40 CFR 400 through 499.

 This rulemaking updates the Illinois

pretreatment rules to correspond with federal amendments made in

the period from July

 1 through December 31,

 1992.

 The sole USEPA

action during this period is as follows:

Federal Action

 Summary

57 Fed. Reg. 41836

 (Sept.

 Standards for non—amenable

11,

 1992)

 cyanides, background levels

of metals, correct listing

errors in the appendices,

and amend the applicability

of OCPSF subcategories

PUBLIC COMMENTS

The Board will receive public comment on this proposal for a

period of 45 days following its publication in the Illinois

Register.

 The Board will delay filing any adopted rules with the

Secretary of State for

 30 days after adoption, particularly to

allow USEPA review.

 The complete text of the proposed amendments

follows the discussions of this opinion.

HISTORY OF

RCRA,

 UST and UIC ADOPTION

AGENCY OR BOARD ACTION?

EDITORIAL CONVENTIONS

The Board appended three routine discussions at the end of

this opinion.

 The first is

 a summary history of the Illinois

wastewater pretreatment program.

 It lists all actions taken to

adopt and maintain this program since its inception.

 The second

is a discussion of how the Board codifies requirements that call

for state determinations,

 such as for exemptions, exceptions,

etc.

 The third discussion relates to our use of language in the

codification of identical—in—substance rules.

 We intend these as

reference aids for interested persons

 in the regulated community.

DISCUSSION

The amendments involved in this proceeding are based on

USEPA amendments to rules affecting the Organic Chemicals,

Plastics, and Synthetic Fibers

 (OCPSF) Category

 (40 CFR 414,

corresponding to 35 Ill.

 Adm. Code 307.Subpart 0).

 These

amendments establish alternative cyanide limitations for non—

amenable cyanide resulting from unavoidable complexing

 in process

wastestreams.

 They also establish alternative limitations for

metals to accommodate low background levels of metals in non—

“metal-bearing wastestreams” from incidental sources, such as

source water, raw materials contamination, and materials of

construction.

 The federal amendments further correct listing

errors

 in the federal appendices

 (40 CFR 414 Appendices A

 & B,

b~3-O

108

3

corresponding to Sections 307.2490 and 307.2491), and amend the

applicability provisions for the Other Fibers, Thermoplastic

Resins, and Thermosetting Resins subcategories

 (40 CFR 414,

Subparts C, D

&

 E, corresponding to Sections 307.2402,

 307.2403

&

307.2404).

 The federal amendments finally purport to move two

chemicals from the Bulk Organic Chemicals Subcategory

 (40 CFR

414, Subpart G, corresponding to Section 307.2406)

 to the

Specialty Organic Chemicals Subcategory

 (40 CFR 414,

 Subpart H,

corresponding to Section 307.2407).

The following discussions consider each of the sets of

amendments in turn.

 However, prior to discussion of the

amendments actually made to the Illinois wastewater pretreatment

program, the Board discusses a number of federal amendments that

do not result in amendments to the state program.

Federal Amendments to Direct Discharge Requirements

In past update dockets, the Board has raised the issue of

federal amendments to the direct discharge requirements.

As

previously discussed in R89—12

 (Apr.

12,

 1990)

 and R86—44

 (Dec.

3,

 1987),

 40 CFR Chapter I, Subchapter N

 (Parts 400 through 499)

includes the federal categorical wastewater pretreatment

standards.

 It also includes USEPA’s categorical NPDES effluent

limitations.

Although the Board has fulfilled its identical-in—substance

mandate and periodically adopted and amended Illinois’

pretreatment standards in response to federal actions, we have

not done so for the categorical NPDES effluent limitations.

We

have no authority to adopt such rules using the identical-in-

substance procedures.

 Therefore,

 any adoption or amendment of

categorical NPDES effluent limitations must be done as either a

Section 27 general rulemaking or as a Section 28.2 federally—

required rulemaking

 (if the Agency certifies the rules as

required to meet the requirements of the federal Clean Water

Act).

 In the case of a Section 27 rulemaking, the Board

generally relies on the Agency for proposal of the rules to

initiate the proceeding.

 In the case of a Section 28.2

rulemaking,

 the Board must rely on the filing of an Agency

proposal.

 Throughout the history of the federal categorical

NPDES regulations,

 since 1974

 39 Fed. Reg. 4532), the Agency

has not filed such a proposal.

 Further, the Board received no

public comments despite a specific request for comments in docket

R91-5.

 As a result, the Board has not acted on those federal

rules.

As a result, Illinois does not have a set of categorical

effluent limitations in its regulations that corresponds with the

industry-specific limitations included in the federal rules.

The

Board cannot now determine the ultimate effects of such a

deficiency,

 but on its face it is obvious that the Agency must

L;3-O

109

4

 rely on something other than Illinois regulations if it were to

impose these limitations in any NPDES permit.

 These limitations

are mandatory at the federal level, so USEPA would likely require

the Agency to impose them.

 The Board cannot say whether this is

a desireable situation, but

 we invite public comment on whether

the Agency or the Board should initiate a rulemaking proceeding

to adopt Illinois categorical, industry-specific NPDES effluent

limitations based on the corresponding federal regulatory

limitations.

Specific

 to this docket,

 there are elements of the federal

categorical effluent limitations that the Board is not adopting.

First,

 the Board is not adopting those portions of the

alternative non—amenable cyanide and metals allowances rules as

they relate to direct discharges.

 (40 CFR 414.11

(g)

&

 (h),

as

added at 57

 Fed. Reg.

 41843.)

 Second, the Board is not adopting

the BOD5,

 TSS, and pH limitation provisions for plants that

produce in multiple subcategories of the OCPSF category.

 (40 CFR

414.11(i), as added at 57 Fed. Reg.

41843

 & 40 CFR 414.21,

414.31,

 414.41,

 414.51,

 414.61,

 414.71

 & 414.81, as amended at 57

Fed. Reg. 41843.)

 Third,

 the amendments to the subcategorical

applicability statements, affected in this rulemaking as to

 pretreatment,

 do not affect any direct discharges.

 (40 CFR

414.30,

 414.40,

 414.50

 & 414.70, as amended at 57 Fed. Reg.

41843.)

 Finally, the amendments that identify the various waste—

streams, affected in this rulemaking as to pretreatment, do not

similarly identify any direct discharges.

 (40 CFR 414, App. A

&

App.

B,

 as amended at 57 Fed. Req. 41843.)

Routine Amendments——All Sections

As a routine matter, the Board made certain routine

amendments wherever the need was apparent.

 These included

updating the edition of the Code of Federal Regulations to the

1992 edition.

 This also meant using or adding,

 as appropriate,

“above”,

 “below”,

 “of this Section”, or “of this Part” whenever

we encountered Section— or Part—internal cross references in the

Sections under amendment.

Alternative Standards for Certain Discharges——Sections 307.1103

&

307.2400

(b)

USEPA amended 40 CFR 414.11 at

 57 Fed. Reg.

 41843.

 This

corresponds to 35 Ill.

 Adm. Code 307.2400(b).

 It is the

applicability statement of the pretreatment regulations.

 USEPA

added new subsection

(g)

 (corresponding to Section

307.2400(b) (7)), which provides for an alternative cyanide

limitation for wastestreams that contain non—amenable cyanides.

(The federal rule parenthetically defines non—amenable cyanide as

 cyanide that is not oxidized by chlorine.)

 USEPA further added

new subsection

(h)

 (corresponding to Section 307.2400(b) (8)),

(~t

5

which provides for alternative metals limitations for certain

non-metal—bearing wastestreams.

As to the new non—amenable cyanide provisions, the

amendments render the pretreatment regulations inapplicable to

discharges of non—amenable cyanides under certain circumstances.

For the exemption to apply, the control authority must determine

that the regulatory cyanide limitations “are not achievable due

to elevated levels of non-amenable cyanide

 that result from

unavoidable complexing of cyanide at the process source

.“.

The control authority must also establish an alternative total or

amenable cyanide standard “that reflects the best available

technology economically achievable”.

 Review of certain broadly—

specified information

 is required for such a determination.

The

determination must be made

 in writing.

As to the alternative metals standards provisions, the rules

allow the control authority to establish standards for lead and

zinc for wastestreams that are not listed in 40 CFR 414, Appendix

A and not otherwise determined a “metal—bearing waste streams”.

The control authority must determine that “the wastewater metals

contamination is due to background levels that are not reasonably

avoidable from sources such as intake water, corrosion of

construction materials or contamination of raw materials”.

As

for the alternative cyanide standards, review of certain broadly—

specified information is required for such a determination, and

the determination must be made in writing.

 The standards must be

set between “the lowest level which the control authority

determines based on best professional judgment can be reliably

measured and the concentration of such metals present in the

wastestreams, but not to exceed (the standards for existing

sources”.

In adapting these provisions,

 the Board has attempted to do

with a minimum of deviation from the federal text.

 First, as

previously discussed,

 the Board removed all references and

provisions applicable to direct discharges.

 Thus, we dropped

“permit writer” from both subsections and major segments of

federal subsection

(h)

 (corresponding to subsection

 (b)(8)).

Further, USEPA uses “discharge limitations” to refer to direct

discharges and “standards” to refer to discharges to a POTW.

The

Board used “limitations” to refer to discharges subject to the

pretreatment regulations.

 The word “standards” carries certain

implications

 in Illinois administrative law that we wish to

avoid:

 it requires the Agency to act standards established by

the Board, but it allows the Agency to employ those standards to

derive limitations.

 See Granite City Division of National Steel

Co.

 v. PCB (Apr.

15,

 1993),

No.

72850

 (slip op.).

For similar reasons,

as

 is briefly explained in the segments

of this opinion entitled “Agency or Board Action?” and “Editorial

Conventions”, we used “the control authority shall” grant the

U

I

‘)

—

6

alternative limitation when it makes a determination.

 Allowing

further discretion to deny the alternative limitation after the

control authority has made the appropriate determination would

run afoul of Illinois administrative law.

 The control authority

has all the discretion allowed under the federal rules

 in its

prerogative of making the determination or not making the

determination;

it

 is just that further use of “may” could

endanger that discretion.

The Board further clarified the federal language.

 We used

“control authority” in several places and the active voice in

place of the passive.

 We added references to the primary

determination subsection in each of the ancillary determinations

subsections.

 Further, the Board added language that requires the

control authority to base its determination on “the information

at its disposal”.

 This would impose a burden on the discharger

to supply the information to the authority.

 It would also allow

the authority to use whatever information it has on file about

the discharger and other relevant information in its possession.

Finally, we changed “analysis information” to “analytical

information” and “construction materials” to “materials of

construction”

 (a phrase of art)

 and we subdivided the two federal

provisions into subsections and effected minor rewording for

additional clarity.

The Illinois regulations already include Section 307.1103,

which imposes a limitation on allowable total cyanide discharges

to a POTW.

 This is a state-only provision, adopted in R71—14,

4

PCB

3

 (Mar.

7,

 1972); amended in R74—15,

 31 PCB 405

 (Sept.

7,

1978); and renumbered in R86—44,

 84 PCB 89

 (Dec.

3,

 1987), that

survives in the present pretreatment rules.

 This rule allows

adjustment of cyanide discharges up to a maximum of 10 mg/i as

total cyanide.

 On its face,

 this state—only provision is more

stringent that the corresponding federal provision.

 Further, any

inconsistency with the federal provision is not facially

apparent.

 If this pre-existing state—only rule were either less

stringent than or inconsistent with the new federal alternative

complexed cyanide limitation provision,

 the Board would be

compelled to repeal it.

 Otherwise, the only way to repeal this

provision is through a full Section 27 rulemaking proceeding, not

by use of our Section 13.3 identical-in-substance authority.

Because Section 307.1103 could prove problematic, we have

proposed a minor amendment to open it for this rulemaking.

We

have proposed new subsection

 (d), which states that any action

under Section 307.1103

 is subject to the limitations of Section

307.2400(b) (7).

 Similarly, we proposed at Section

307.2400(b) (7) (D)

 language to the effect that any action under

this Section is subject to the limitations of Section 307.1103.

A broad range of alternative actions are possible, ranging from

repeal of Section 307.1103

 (within the limitations noted above)

to not adopting the new federal alternative limitation provision

0H43-OI

7

(so long as not doing so does not render the Illinois rules

either less stringent than or inconsistent with the federal

rules).

 The Board chose one middle—of—the—road option in

proposing cross—references.

 An equally viable middle—ground

option is to amend Section 307.1103 to include its present

limitations together with the new federal limitations.

 The Board

requests comments on our approaches to the alternative

limitations provisions.

 We specifically requests comments on the

above issues regarding the relationship between Section 307.1103

 and the new federal alternative cyanide discharge provision.

A~p1icabilitv

of OCPSF Subcategories-—Sections

 307.2402 through

307.2406

Section 307.2402 derives from 40 CFR 414,

 Subpart C; Section

307.2403 from 40 CFR 414, Subpart D; Section 307.2404 from 40 CFR

414, Subpart E; Section 307.2405 from 40 CFR 414, Subpart F; and

Section 307.2406 from 40 CFR 414,

 Subpart G.

 USEPA amended the

applicability statements of 40 CFR 414.30

 (for Subpart C), 414.40

(for subpart D), 414.50

 (for Subpart E), and 414.70

 (for Subpart

G)

 at 57 Fed. Reg.

41844

 (Sept.

11,

 1992).

The amendments to sections 414.30 (corresponding to 35 Ill.

Adm. Code 307.2402(a))

 414.40 (corresponding to 35 Ill. Adm. Code

307.2403(a)), and 414.50 (corresponding to 35 Ill.

Adm.

 Code

307.2404(a)) include rewording the preamble statements for

greater clarity.

 Thus,

 “manufacture of the following SIC

•

.“

 became “manufacture of products classified under SIC

listed below”.

 USEPA did not similarly amend nearly

identical language in the preambles of sections 414.60 and

414.70.

 This aspect of the federal amendments appears purely

stylistic and non—substantive.

USEPA further amended the applicability statements of

sections 414.40 and 414.70 to remove product listings from the

table of products and product groups included in each respective

subcategory.

 Thus,

 USEPA removed cellulose sponge from the

Thermoplastic Resins Subcategory (section 414.40) and citric

acid,

 fatty acids,

 aspirin, sodium dithiophosphates, and wax

dispersion emulsions (section 414.70(a),

 (c), and

 (e))

 from the

Bulk Organic Chemicals Subcategory.

 However, USEPA did not

include the fatty acids, citric acid,

 and aspirin in the

Specialty Organic Chemicals Subcategory,

 as discussed at 57 Fed.

Reg.

 41836 and 41842.

 Rather, USEPA merely deleted these

products and product groups.

The Board made the federal amendments with a minimum degree

of deviation.

 We added commas to the federal language for

greater clarity.

 The stylistic amendments in the preamble

language of sections 414.30 through 414.50 (corresponding to 35

Ill.

 Adm. Code 307.2402(a)

 through 307.2404(a))

 is so appealing

0k3-U1

that we unilaterally made similar revisions to Sections

307.2405(a)

 and 307.2406(a), despite the fact that USEPA did not

similarly amend sections 414.60 and 414.70.

 In Section

307.2406(a) (2), the Board has corrected “fatty acids” to “fatty

amines”, which

 is the correct listing from 40 CFR 414.70(b).

The Board requests comments on our approach to the OCPSP

subcategory applicability provisions.

Com~lexedMetal-Bearing Wastestreams and Cyanide—Bearing

Wastestreams——Sections 307.2490 and 307.2491

Section 307.2490 derives from 40 CFR 414, Appendix A, and

Section 307.2491 derives from 40 CFR 414, Appendix B.

 USEPA

amended these provisions at 57 Fed.

 Req.

41844

 (Sept.

11,

 1992).

The amendments to Appendix A delete the entries for methylene

diphenylisocyanate, hexamethylene diamine/hexamethylene diiso—

cyanate

 phosgene, polyurethane resins/diisocyanate

 polyoxy—

alkalene glycol, polyurethane fibers/polyoxyalkylene glycol

tolylene diisocyanate

 dialkylamine, and tolylene diisocyanate/

tolylene diamines

 phosgene from the cyanide—bearing wastestream

listings.

 The amendments to Appendix B delete the entries for

tetraethyl lead/alkyl halide

 sodium-lead alloy and tetramethyl

lead/alkyl halide

 sodium-lead alloy from the listings for lead-

bearing complexed metal—bearing wastestreams.

 USEPA explains

that the entries in Appendix A are subjected to the part 414

cyanide limitations.

 It further explains that the wastestreams

listed in Appendix B are not subject to the part 414 metals

limitations; rather, these wastestreams are subject to regulation

 on the basis of “best professional judgment” pursuant to 40 CFR

414.11(f)

 (corresponding to 35

 Ill. Adm. Code 307.2400(b) (6)).

The Board adopted the federal amendments without revision.

Since we incorporated both federal appendices by reference, we

needed only update the references in the Illinois rules.

We

invite comment on how we accommodated the federal. amendments to

40 CFR

414,

 Appendices A and B.

HISTORICAL OUTLINE OF BOARD PRETREATMENT REGULATION

The Illinois pretreatment rules were adopted in R86-44,

84

PCB 89, Opinion and Order of the Board of December 3,

 1987.

The

rules appeared at

12

 Ill.

 Req. 2502

 (Jan.

29,

 1988), effective

January 13,

 1988.

The Board has updated the pretreatment rules in the

following update rulemakings:

R88—l1

 90 PCB 411, June 14,

 1988;

12

 Ill.

 Reg.

 13094,

effective July 29,

1988

 (USEPA amendments through

December 31,

 1987).

01t~.3-O1lL~

9

R88—18

 94 PCB 237, December

17,

 1988;

 13 Ill. Reg. 1794

&

2463

 (Parts 307

 & 310),

 effective January 31,

1989

(USEPA amendments January

 1 through June 30,

 1988)

R89—3

 103 PCB 609, September 28,

 1989;

 13 Ill. Reg.

19243

 & 19288

 (Parts 310

 & 307), effective

November 17,

1989

 (Part 307) and November 27,

1989

(Part 310)

 (USEPA amendments July

 1 through

December 31,

 1988).

R89—12

 110 PCB 119, April 12,

 1990;

 14 Ill. Req. 7608

&

7620

 (Parts 310

 & 307), effective May 8,

1990

(USEPA amendments January 1 through June 30,

1989)

R90-6

 Dismissed at 109 PCB 629, March 22, 1990

 (No USEPA

amendments July 1,

 1989 through December 31,

1989)

R90—15

 Dismissed at 123 PCB 875, June 20, 1991

 (No USEPA

amendments January

 1 through June 28,

 1990).

R91—5

 129 PCB 375, January 23,

 1992;

 16 Ill. Req.

 7337,

7346

 & 7377

 (Parts 310,

309

 & 307), effective

April 27,

1992

 (USEPA amendments June 29,

1990

through December 31,

 1990).

R91—l7

 Dismissed at 128 PCB 231, December 6,

1991

(No

USEPA amendments January 1 through June 30,

 1991).

R92—5

 Dismissed at 133 PCB 109, April

9,

1992

 (No USEPA

amendments July

 1 through December 31,

 1991).

 R92—14

 Dismissed at 135 PCB 467, August 13,

1992

(No

USEPA amendments January

 1 through June 30,

 1992).

R93-2

 This docket.

AGENCY OR BOARD ACTION?

Section 7.2(a)(5)

 of the Act requires the Board to specify

which decisions USEPA will retain.

 In addition, the Board is to

specify which State agency is to make decisions, based on the

general division of functions within the Act and other Illinois

statutes.

In situations in which the Board has determined that USEPA

will retain decision-making authority, the Board has replaced

“Regional Administrator” with USEPA,

 so as to avoid specifying

which office within USEPA is to make a decision.

UIL+3-OI

10

In a few instances in identical in substance rules,

decisions are not appropriate for Agency action pursuant to a

permit application.

 Among the considerations in determining the

general division of authority between the Agency and the Board

are:

1.

 Is the person making the decision applying a Board

regulation,

 or taking action contrary to

 (“waiving”) a Board

regulation?

 It generally takes some form of Board action to

“waive”

 a Board regulation.

2.

 Is there a clear standard for action such that the

Board can give meaningful review to an Agency decision?

3.

 Does the action result in exemption from the permit

requirement itself?

 If so, Board action is generally

required.

4.

 Does the decision amount to “determining, defining or

implementing environmental control standards” within the

meaning of Section 5(b) of the Act.

 If so,

 it must be made

by the Board.

There are four common classes of Board decision:

 variance,

adjusted standard, site specific rulemaking,

 and enforcement.

The first three are methods by which a regulation can be

temporarily postponed

 (variance) or adjusted to meet specific

situations (adjusted standard or site specific rulemaking).

 Note

that there often are differences in the nomenclature for these

decisions between the USEPA and Board regulations.

EDITORIAL CONVENTIONS

As a final note, the federal rules have been edited to

establish a uniform usage throughout the Board’s regulations.

For example, with respect to “shall”,

 “will”, and “may”

—

 “shall”

is used when the subject of a sentence has to do something.

“Must” is used when someone has to do something, but that someone

is not the subject of the sentence.

 “Will” is used when the

Board obliges itself to do something.

 “May”

 is used when choice

of a provision is optional.

 “Or” is used rather than “and/or”,

and denotes “one or both”.

 “Either”.

“or” denotes “one but not

both”.

“And”

denotes

“both”.

ORDER

The

Board

hereby

proposes

 the following amendments to the

Illinois

wastewater

pretreatment

regulations

 Sections

307.2400,

307.2402,

307.2403,

307.2404,

307.2405,

307.2406,

307.2490,

and

307.2491.

TITLE

35:

ENVIRONMENTAL

PROTECTION

U~3-OI16

11

SUBTITLE C:

 WATER POLLUTION

CHAPTER

I:

 POLLUTION CONTROL BOARD

PART

307

SEWER DISCHARGE CRITERIA

Section

307.101

307.102

307. 103

307.

104

307.105

307.1001

307.1002

307. 1003

307.1005

SUBPART A:

 GENERAL PROVISIONS

Preamble

(Renumbered)

General

Requirements

(Renumbered)

Mercury

(Renumbered)

Cyanide (STORET number 00720)

 (Renumbered)

Pretreatment

Requirements

(Repealed)

Preamble

Definitions

Test

Procedures

for

Measurement

 Toxic Pollutants

SUBPART

GENERAL

AND

 SPECIFIC PRETREATMENT REQUIREMENTS

General

and

Specific

 Requirements

Mercury

Cyanide

SUBPART

DAIRY

PRODUCTS

PROCESSING

Receiving Stations

Fluid Products

Cultured Products

Butter

Cottage Cheese and Cultured Cream Cheese

Natural

and

Processed

Cheese

Fluid

Mix

for

Ice

Cream

and

other

Frozen

Desserts

Ice Cream,

 Frozen Desserts, Novelties and Other Dairy

Desserts

Condensed Milk

Dry Milk

Condensed Whey

Dry Whey

SUBPART

GRAIN

MILLS

Corn

Wet

Milling

Corn

Dry

Milling

Normal

Wheat

Flour

Bulgur Wheat Flour

Normal

Rice

Milling

Parboiled

Rice

Milling

Animal Feed

Hot Cereal

Ready-to-eat

Cereal

Wheat

Starch

and

Gluten

Section

307.1101

307.1102

307.1103

Section

307. 1501

307. 1502

 307.1503

307.1504

307.1505

307.1506

307.1507

307.1508

307.1509

307.1510

307.1511

307.1512

Section

307.1601

307.1602

307.1603

307.1604

307.1605

307.1606

307.1607

307.1608

307.1609

307.1610

Milling

ot~-.o1

12

General Provisions

Apple Juice

Apple Products

Citrus Products

Frozen Potato Products

Dehydrated

Potato

Products

Canned and Preserved Fruits

Canned and Preserved Vegetables

Canned

and

Miscellaneous

Specialties

SUBPART

I:

 CANNED AND PRESERVED SEAFOOD

Farm-raised Catfish

Fish Meal Processing Subcategory

SUBPART J:

 SUGAR PROCESSING

Beet Sugar Processing

Crystalline Cane Sugar Refining

Liquid Cane Sugar Refining

SUBPART K:

 TEXTILE MILLS

General Provisions

Wool Scouring

Wool Finishing

Low Water Use Processing

Woven Fabric Finishing

Knit Fabric Finishing

Carpet Finishing

Stock and Yarn Finishing

Nonwoven Manufacturing

Felted Fabric Processing

SUBPART L:

 CEMENT MANUFACTURING

Nonleaching

Leaching

Materials

Storage

Piles

Runoff

SUBPART M:

 FEEDLOTS

Section

307.2201

General

307.2202

 Ducks

SUBPART N:

 ELECTROPLATING

Section

307.2300

General

Provisions

307.2301

Electroplating

Common

Metals

307.2302

Electroplating

Precious

Metals

OtL~3-D118

SUBPART

CANNED

AND

PRESERVED

FRUITS

AND

VEGETABLES

Section

307. 1700

307.1701

307. 1702

307.1703

307.1704

307.1705

307.1706

307.1707

307.1708

Section

307. 1801

307. 1815

Section

307. 1901

307.1902

307. 1903

Section

307.2000

307.2001

307.2002

307. 2003

307.2004

307

2005

307. 2006

307.2007

307.2008

307.2009

Section

307.2101

307. 2102

307. 2103

13

307.2304

Anodizing

307.2305

Coatings

307.2306

Chemical

Etching

and

Milling

307.2307

 Electroless Plating

307.2308

Printed

Circuit

Boards

SUBPART

ORGANIC

CHEMICALS,

PLASTICS

 AND SYNTHETIC FIBERS

General

Provisions

Rayon Fibers

Other

Fibers

Thermoplastic

Resins

Thermosetting Resins

Commodity Organic Chemicals

Bulk Organic Chemicals

Specialty

Organic

Chemicals

Non-complexed Metal-bearing and Cyanide-bearing

Wastestreams

307.2491

 Complexed Metal-bearing

Wastestreams

SUBPART

INORGANIC

CHEMICALS

MANUFACTURING

General

Provisions

Aluminum

Chloride

Production

Aluminum

Sulfate

Production

Calcium

Carbide

 Production

Calcium Chloride Production

Calcium Oxide Production

Chlor-alkali Process

 (Chlorine and Sodium or Potassium

Hydroxide

Production)

Hydrofluoric Acid Production

Hydrogen Peroxide Production

Potassium

Metal

Production

Potassium

Dichromate

Production

Potassium Sulfate Production

 Sodium Bicarbonate Production

Sodium Chloride Production

Sodium Dichromate and Sodium Sulfate Production

Sodium

Sulfite

Production

Titanium Dioxide Production

Aluminum Fluoride Production

Ammonium

Chloride

Production

Borax

Production

Boric Acid Production

Bromine

Production

Calcium Carbonate Production

Calcium Hydroxide Production

Carbon Monoxide and Byproduct Hydrogen Production

Chrome

Pigments

Production

Chromic Acid Production

Copper

Salts

Production

Ferric Chloride Production

Section

307.2400

307.2401

307.

2402

307.2403

307.2404

307.2405

307.2406

307.2407

307.2490

Section

307.2500

307.2501

307.2502

307.2503

307.2504

307.2505

307.2506

307.2508

307.2509

307.2511

307.2512

307.2513

307.2514

307.2516

307.2517

307.2520

307.2522

307.2523

307.2524

307.2527

307.2528

307.2529

307

2530

307 .2531

307.2533

307.2534

307.2535

307.2536

307.2538

01Li~3-U119

14

307.2540

307.2541

307.2542

307.2543

307.2544

307.2545

307.2547

307.2549

307.2550

307.2551

307.2553

307.2554

307.2555

307.2560

307.2563

307.2564

307.2565

307. 2566

307. 2567

Section

307.2701

307.2702

307

2703

307.2704

307.2705

307.2706

307.2707

307.2708

307.2709

307.2710

307.2711

307.2712

307.2713

307.2714

307. 2715

307.2716

307.2717

307.2718

307.2719

Section

307.2801

307.2802

307.2803

307.2804

307.2805

307.2806

307.2807

Fluorine Production

Hydrogen Production

Hydrogen Cyanide Production

Iodine

Production

Lead Monoxide Production

Lithium

Carbonate

Production

Nickel

Salts

Production

Oxygen and Nitrogen Production

Potassium

Chloride

Production

Potassium

Iodide

Production

Silver

Nitrate

Production

Sodium

Bisulfite

Production

Sodium Fluoride Production

Stannic

Oxide

Production

Zinc Sulfate Production

Cadmium

Pigments

and

Salts

Production

Cobalt

Salts

Production

Sodium Chlorate Production

Zinc Chloride Production

SUBPART

 SOAP

AND

 DETERGENTS

Soap

Manufacturing

Batch

Kettle

Fatty Acid Manufacturing by Fat Splitting

Soap

Manufacturing

Fatty

Acid

Neutralization

Glycerine Concentration

Glycerine Distillation

Manufacture of Soap Flakes and Powders

Manufacture

Bar

Soaps

Manufacture of Liquid Soaps

Oleum

Sulfonation

and

Sulfation

Air-Sulfur Trioxide Sulfation and Sulfonation

Sulfur Trioxide Solvent and Vacuum Sulfonation

Sulfamic

Acid

Sulfation

Chlorosulfonic Acid Sulfation

Neutralization of Sulfuric Acid Esters and Sulfonic

Acids

Manufacture of Spray Dried Detergents

Manufacture

Liquid

Detergents

Manufacturing

Detergents

 Dry Blending

Manufacture of Drum Dried Detergents

Manufacture of Detergent Bars and Cakes

SUBPART S:

 FERTILIZER MA.NUFACTURING

Phosphate

Ainmon

ia

Urea

Ammonium Nitrate

Nitric

Acid

Ammonium

Sulfate

Production

Mixed

and

Blend

Fertilizer

Production

01143-0120

SUBPART

PETROLEUM

REFINING

Section

307.2901

307.2902

307.2903

307.2904

307.2905

Section

307.3000

307. 3001

307.3002

307. 3003

307. 3004

307.3005

307.3006

307.3007

307.3008

307.3009

307. 3010

307.3011

307.3012

Section

307.3100

307.3101

307.3102

307.3103

307.3104

307.3105

307. 3106

307.3107

307.3108

307.

3109

307. 3110

307.3111

 307.3112

307.3113

307. 3114

307. 3115

307. 3116

307.3117

307.3118

307.3119

307.3120

307.3121

307.3122

307.3123

307.3124

307.3125

Topping

Cracking

Petrochemical

Lube

Integrated

SUBPART U:

 IRON

AND

STEEL

MANUFACTURING

General

Provisions

Cokemaking

Sintering

I roninak

ing

Stee

lmaking

Vacuum Degassing

Continuous

Casting

Hot

Forming

Salt Bath Descaling

Acid Pickling

Cold Forming

Alkaline

Cleaning

Hot

Coating

SUBPART V:

 NONFERROUS METALS MANUFACTURING

General

Provisions

Bauxite Refining

Primary Aluminum Smelting

Secondary Aluminum Smelting

Primary

Copper

Smelting

Primary

Electrolytic

Copper

Refining

Secondary Copper

Primary

Lead

Primary

Zinc

Metallurgical

Acid

Plants

Primary

Tungsten

Primary Columbium—Tantalum

Secondary Silver

Secondary Lead

Primary

Antimony

Primary

Beryllium

Primary

and

Secondary

Germanium

and

Gallium

Secondary

Indium

Secondary Mercury

Primary

Molybdenum

and

Rhenium

Secondary Molybdenum and Vanadium

Primary

Nickel

and

Cobalt

Secondary

Nickel

Primary Precious Metals and Mercury

Secondary Precious Metals

Primary Rare Earth Metals

01143-0121

16

307.3126

307.3127

307.3128

307.3129

307.3130

307.3131

Section

307.3301

Section

307.3401

307.3402

307.3403

307.3404

307.3405

307.3406

307.3407

Section

307.3500

307.3501

307.3502

307.3503

307.3504

307.3505

307.3506

307.3507

307.3508

307.3509

307.3590

Section

307.3601

307.3602

307.3603

307.3604

307.3605

307.3606

307.3607

307.3608

307.3610

307.3611

307.3612

307.3613

Secondary

Tantalum

Secondary Tin

Primary and Secondary Titanium

Secondary Tungsten and Cobalt

Secondary Uranium

Primary Zirconium and Hafnium

SUBPART X:

STEAM

 ELECTRIC POWER GENERATING

Steam

Electric

Power

Generating

SUBPART Y:

 FERROALLOY MANUFACTURING

Open Electric Furnaces With Wet Air Pollution Control

Devices

Covered

Electric

Furnaces

and

Other

Smelting

Operations

with Wet Air Pollution Control Devices

Slag Processing

Covered

Calcium

Carbide

 Furnaces With Wet Air Pollution

Control Devices

Other Calcium Carbide Furnaces

Electrolytic

Manganese

Products

Electrolytic

Chromium

SUBPART

LEATHER

TANNING

AND

FINISHING

General

Provisions

Hair Pulp,

 Chrome Tan, Retan-Wet Finish

Hair Save,

 Chrome Tan, Retan-Wet Finish

Hair Save or Pulp, Non—Chrome Tan, Retan—Wet Finish

Retan-Wet

Finish—Sides

No Beamhouse

Through-the-Blue

Shearling

Pigskin

Retan-Wet Finish-Splits

Potassium Ferricyanide Titration Method

SUBPART BA:

 GLASS

MANUFACTURING

Insulation Fiberglass

Sheet

Glass

Manufacturing

Rolled Glass Manufacturing

Plate Glass Manufacturing

Float Glass Manufacturing

Automotive Glass Tempering

Automotive Glass Laminating

Glass Container Manufacturing

Glass Tubing

 (Danner) Manufacturing

Television

Picture

Tube

Envelope

Manufacturing

Incandescent Lamp Envelope Manufacturing

Hand Pressed and Blown Glass Manufacturing

~3-U

122

17

SUBPART BB:

 ASBESTOS MANUFACTURING

Section

307.3701

307.3702

307.3703

307.3704

307.3705

307.3706

307.3707

307.3708

307.3709

307.3710

307.3711

Section

307.3801

307.3802

307.3803

307. 3804

307.3805

307.3806

307.3807

307.3808

307.3809

307.3810

307.3811

Section

307. 3900

307.3901

307.3902

307.3903

307.3904

307.3905

307.3906

307.3907

307. 3908

307.3909

307.3910

307 .3911

307.3912

 307.3913

307.3914

307.3915

307.3916

Asbestos-Cement Pipe

Asbestos-Cement

Sheet

Asbestos Paper

 (Starch Binder)

Asbestos

Paper

(Elastomeric

Binder)

Asbestos Millboard

Asbestos Roofing

Asbestos Floor Tile

Coating or Finishing

Asbestos

Textiles

Solvent

Recovery

Vapor

Absorption

Wet Dust Collection

SUBPART

BC:

 RUBBER MANUFACTURING

Tire and Inner Tube Plants

Emulsion Crumb Rubber

Solution Crumb Rubber

Latex Rubber

Small-Sized General Molded,

 Extruded and Fabricated

Rubber Plants

Medium-Sized

General

Molded,

Extruded

and

Fabricated

Rubber

Plants

Large-Sized General Molded,

 Extruded and Fabricated

Rubber

Plants

Wet Digestion Reclaimed Rubber

Pan, Dry Digestion and Mechanical Reclaimed Rubber

Latex-Dipped, Latex-Extruded and Latex-Molded Rubber

Latex Foam

SUBPART ED:

 TIMBER PRODUCTS PROCESSING

General Provisions

Barking

Veneer

Plywood

Dry Process Hardboard

Wet Process Hardboard

Wood Preserving—Water Borne or Nonpressure

Wood Preserving—Steam

Wood Preserving—Boulton

Wet Storage

Log Washing

Sawmills

and

Planing

Mills

Finishing

Particleboard

Manufacturing

Insulation Board

Wood Furniture and Fixture Production Without Water

Wash

Spray

Booth(s)

Without

Laundry

Facilities

Wood Furniture and Fixture Production with Water Wash

Spray Booth(s)

 or With Laundry Facilities

01143-0123

18

Section

307.4000

307.4001

307.4002

307.4004

307.4005

307.4006

307.4007

307.4008

307.4009

307.4010

307.4011

307.4012

307.4013

307.4014

307.4015

307.4016

307.4017

307.4018

307.4019

307.4020

307.4021

307.4022

307.4023

307.4024

307.4025

307.4026

Section

307.4101

Section

307.4201

307.4202

307.4203

307.4204

307.4205

307.4206

307.4207

307.4208

307.4209

307.4210

Section

307.4300

307.4301

SUBPART BE:

 PULP,

 PAPER AND PAPERBOARD

General Provisions

Unbleached Kraft

Semi—Chemical

Unbleached Kraft-Neutral Sulfite Semi-Chemical

 (Cross

Recovery)

Paperboard

From

Wastepaper

Dissolving Kraft

Market Bleached Kraft

BCT Bleached Kraft

Fine Bleached Kraft

Papergrade Sulfite

 (Blow Pit Wash)

Dissolving Sulfite Pulp

Groundwood—Cheini —Mechanical

Groundwood—Thermo—Mechan ica1

Groundwood—CMN

Papers

Groundwood—Fine Papers

Soda

Deink

Nonintegrated-Fine Papers

Nonintegrated—Tissue Papers

Tissue From Wastepaper

Papergrade Sulfite (Drum Wash)

Unbleached Kraft and Semi—Chemical

Wastepaper-Molded

Products

Nonintegrated-Lightweight Papers

Nonintegrated—Filter and Nonwoven Papers

Nonintegrated-Paperboard

SUBPART BF:

 BUILDERS’ PAPER AND BOARD MILLS

Builder’s Paper and Roofing Felt

SUBPART

BG:

MEAT

PRODUCTS

Simple Slaughterhouse

Complex Slaughterhouse

Low—Processing Packinghouse

High-Processing Packinghouse

Small Processor

Meat Cutter

Sausage and Luncheon Meats Processor

Ham Processor

Canned Meats Processor

 Renderer

SUBPART BH:

 METAL FINISHING

General Provisions

Metal Finishing

01143-01 2~

19

SUBPART BN:

 PHARMACEUTICAL MANUFACTURING

Section

307.4900

 General Provisions

307.4901

 Fermentation Products

307.4902

 Extraction Products

307.4903

 Chemical Synthesis Products

307.4904

 Mixing/Compounding and Formulation

307.4905

Research

SUBPART BR:

 PAVING AND

ROOFING

MATERIALS

(TARS

 AND ASPHALT)

Asphalt Emulsion

Asphalt Concrete

Asphalt Roofing

Linoleum and Printed Asphalt Felt

SUBPART BU:

 PAINT FORMULATING

Section

307.5601

 Oil-Base Solvent Wash Paint

SUBPART BV:

 INK FORMULATING

Section

307.5701

 Oil-Base Solvent Wash Ink

SUBPART CD:

 PESTICIDE CHEMICALS

General Provisions

Organic

Pesticide

Chemicals

Manufacturing

Metallo-Organic

Pesticides

Chemicals

 Manufacturing

Pesticide Chemicals Formulating and Packaging

SUBPART CG:

 CARBON BLACK MANUFACTURING

Carbon Black Furnace Process

Carbon Black Thermal Process

Carbon Black Channel Process

 Carbon Black Lamp Process

SUBPART CJ:

 BATTERY MANUFACTURING

General

Provisions

Cadmium

Calcium

Lead

Leclanche

Lithium

Magnesium

Zinc

Section

307.7300

General

Provisions

131

143-0125

Section

307.5301

307.5302

307.5303

307.5304

Section

307.6500

307.6501

307.6502

307.6503

Section

307.6801

307.6802

307.6803

307.6804

Section

307.7100

307.7101

307.7102

307.7103

307.7104

307.7105

307.7106

307.7107

SUBPART

CL:

PLASTICS

MOLDING

 AND FORMING

20

307.7301

307.7302

307.7303

Section

307.7400

307.7401

307.7402

307.7403

307.7404

Section

307.7500

307.7501

307.7502

307.7503

307.7504

Section

307.7600

307.7601

307.7602

307.7603

307.7604

Section

307.7700

307.7701

307.7702

307.7703

307.7704

307.7705

307.7706

Section

307.7800

307.7801

307.7802

Contact Cooling and Heating Water

Cleaning Water

Finishing Water

SUBPART CM:

 METAL MOLDING AND CASTING

General Provisions

Aluminum Casting

Copper Casting

Ferrous

Casting

Zinc

Casting

SUBPART

CN:

COIL

COATING

General Provisions

Steel Basis Material

Galvanized Basis Material

Aluminum

Basis

Material

Canmaking

SUBPART CO:

 PORCELAIN ENAMELING

General Provisions

Steel Basis Material

Cast Iron Basis Material

Aluminum

Basis

Material

Copper

Basis

Material

SUBPART

CP:

ALUMINUM

FORMING

General

Provisions

Rolling With Neat Oils

Rolling

With

Emulsions

Extrusion

Forging

Drawing With Neat Oils

Drawing

With

 Emulsions or Soaps

SUBPART

CQ:

COPPER

FORMING

General

Provisions

Copper

Forming

 Beryllium Copper Forming

SUBPART

CR:

 ELECTRICAL AND

ELECTRONIC COMPONENTS

Section

307.7901

307.7902

307.7903

307.7904

Semiconductor

Electronic

Crystals

Cathode Ray Tube

Luminescent Materials

SUBPART CT:

 NONFERROUS METALS FORMING AND METAL POWDERS

01143-0126

21

Section

307.8100

General

Provisions

307.8101

 Lead-Tin-Bismuth Forming

307.8102

 Magnesium Forming

307.8103

 Nickel-Cobalt Forming

307.8104

 Precious Metals Forming

307.8105

 Refractory Metals Forming

307.8106

 Titanium Forming

307.8107

 Uranium Forming

307.8108

 Zinc Forming

307.8109

 Zirconium-Hafnium Forming

307.8110

 Metal Powders

307.Appendix A References to Previous Rules

 (Repealed)

AUTHORITY:

 Implementing Sections 13 and 13.3 and authorized by

Section

27

 of the Environmental Protection Act (Ill.

 Rev.

 Stat.

1991,

ch.

 111½,

 pars.

 1013,

 1013.3 and 1027).

SOURCE:

 Adopted in R70—5, at

 1 PCB 426, March 31,

 1971; amended

 in R7l-l4,

at

 4 PCB

3,

 March

7,

 1972;

amended in R74—3,

at

19 PCB

182, October 30,

 1975;

 amended in R74-15,

 16, at 31 PCB 405,

 at 2

Ill. Req.

44,

p.

 151, effective November 2,

 1978; amended in R76—

17, at 31 PCB 713,

at

 2 Ill. Reg.

45,

p.

 101, effective November

5,

 1978; amended in R76—2l,

 at 44 PCB 203,

at

 6 Ill.

 Reg. 563,

effective December 24,

 1981; codified at

 6 Ill.

 Req.

 7818;

amended in R82—5,

 10, at

54 PCB 411,

 at 8 Ill. Reg.

 1625,

effective

January

18,

1984;

amended

R86—44

Ill.

Req.

2592,

effective

January

13,

1988;

amended

R88-11

Ill.

Reg.

13094,

effective

July

29,

1988;

amended

R88—18

Ill.

Reg.

1794,

effective

January

31,

1989;

amended

R89—3

Ill.

Reg.

19288,

effective

November

17,

1989;

amended

R88—9

111.

Req.

3100,

effective

February

20,

1990;

amended

R89-12

Ill.

Req.

7620,

effective

May

1990;

 amended in R91—5 at

16 Ill. Reg.

 7377,

 effective April 27,

1992;

amended

R93—2

17 Ill. Req.

_________,

 effective

_____________________

SUBPART B:

 GENERAL AND SPECIFIC PRETREATMENT REQUIREMENTS

Section 307.1103

 Cyanide

a)

 No waste to any public sewer system shall contain more

than

 10 mg/l total cyanide

 (STORET number 00720)

provided any sample tested shall not release

more than

2 mg/i of cyanide when tested at a pH of 4.5 and at a

temperature of 66 degrees C

(150 degrees

F)

 for a

period of 30 minutes, except as permitted by subsection

(b) below.

b)

 Upon application by a county, municipality, sanitary

district or public utility and approval by the Agency,

01143-0(27

22

based upon determination by the Agency that no

violation of the effluent standards of 35 Ill. Adm.

Code

304

will

result

and

that

hazard

 to workers in

such

sewage

works

will

result,

limited

additional

amounts

 cyanide exceeding the standards in

subsection

(a)

 above may be discharged to the sewage

works

such

county,

sanitary

district,

municipality

public

utility.

Nothing

this

Section

shall

construed

limiting

the

authority

any

county,

municipality,

sanitary

district

public

utility

impose

any

stringent

standards or limitations on cyanide discharges to its

sewage works.

Arty

~cti~r~

~rnd~rt&ken

~uant

 t~sub

oti~n ~

above

~hal1 be su~iegtto 1i~e1imit~t~on~

o~

,Set~o~

307 24OO(b~7L

(Source:

 Amended at

 17 Ill. Reg.

 effective

SUBPART

ORGANIC

CHEMICALS,

PLASTICS

AND

SYNTHETIC

FIBERS

Section

307.2400

General

Provisions

General

definitions.

The

Board

incorporates

reference

CFR

414.10

(199~Z).

This

incorporation

includes

later

amendments

 editions.

b)

 Applicability.

1)

 This Subpart applies to process wastewater

discharges from all establishments or portions of

establishments

which

manufacture

the

organic

chemicals,

plastics

and

synthetic

fibers

(OCPSF)

products

product

groups

which

are

covered

Sections

307.2402

through

307.2408

and

which

are

included

 in the following SIC major groups, as

defined in the Standard Industrial Classification

Manual,

incorporated

 by reference in

 35 Ill. Adm.

Code 310.107:

A)

 SIC 2821

 Plastic materials, synthetic

resins and nonvulcanizable elastomers.

B)

 SIC 2823

 Cellulosic man-made fibers.

SIC

2824

——

Synthetic

organic

fibers,

except

cellulosic.

01143-0128

23

D)

 SIC 2865

Cyclic

crudes

 and intermediates,

dyes and organic pigments.

E)

 SIC 2869

 Industrial organic chemicals, not

elsewhere classified.

This

Subpart

applies

wastewater

discharges

from

OCPSF

research

 and development,

 pilot plant,

technical

service

and

laboratory

bench

scale

operations

 if such operations are conducted in

conjunction with and related to existing OCPSF

manufacturing

activities

the

plant

site.

3)

 Notwithstanding subsection

(b)

(1)

 above, this

Subpart does not apply to discharges resulting

from the manufacture of OCPSF products if the

products

are

included

 in the following SIC

subgroups and if the products have in the past

been

reported

 the establishment under these

subgroups

and

not

under

the

SIC

groups

listed

subsection

(b) (1)

above:

SIC

2843085

Bulk

surface

active

agents.

B)

 SIC 28914

 Synthetic resin and rubber

adhesives;

C)

 Chemicals and chemical preparations not

elsewhere classified:

i)

 SIC 2899568

——

 Sizes,

 all types.

ii)

 SIC 2899597

 Other industrial chemical

specialties,

 including fluxes, plastic

wood preparations and embalming fluids.

D)

 SIC 2911058

 Aromatic hydrocarbons

manufactured

from

purchased

refinery

products.

E)

 SIC 2911632

——

 Aliphatic hydrocarbons

manufactured

from

purchased

refinery

products.

4)

 Notwithstanding subsection

 (b) (1) above, this

Subpart does not apply to any discharges for which

different

set

previously

promulgated

standards in 6ubpa~rt3F ct ccq.this Part apply,

unless the facility reports OCPSF products under

SIC codes

 2865,

 2869 or 2821,

 and the facility’s

OCPSF

wastewaters

are

discharged

separately

POTW.

13i

143-0(29

24

This

Subpart

does

not

apply

any

process

wastewater discharge from the manufacture of

organic

chemical

compounds

solely

extraction

from plant and animal raw materials or by

fermentation processes.

6)

 Discharges of chromium,

 copper,

 lead,

 nickel and

zinc in “complexed metal—bearing wastestreamsT”~

listed

Section

307.2491,

are

not

subject

this Subpart.

 Non—amenable cyanide.

Discharges

 of cyanide in “cyanide—bearing

waste

streams”,

listed

Section

307

2490

are not subiect to the cyanide

li~L~tjon~

of

this

Subpart

~

 the control authority determines that

the cyanide

lImitations

 are not

achievable due to éIéväted levels of

non—amenable cyanide

 (i.e., cyanide that

is not oxidized bY chlorine treatment)

that result from the unavoidable

complexin~ of

cyanide

the

process

source of the cyanide—bearing waste

streaiw~:and

~e

~

 ai~tho~ity

 establishes an

alternatIve

total

cyanide

amenable

cyanide limitation that reflects the

best available technology economically

achievable.

~Phe

determination made

pursuant

subs~tIon

(7~(A

 above an a review of t~ierelevant

engineering

production,

 and sampling and

analvtic~l information, at ~

 ~sposa~.,

including measurements

 both

?àtàl

and

amenable

cyanide

 the waste stream.

.

dét~

(b~

(7~(~ ~b9v~ ~

~a

vrltter

 analysis of the

extent

comp1exi’-~g

 in the waste stream and

its

impact

cyanide

treatabilitv

b~S~d

on

native

cyanide

01143-0130

25

sub~ection

are

 sublect to the l~mitat~onso~

...

...........

..........

.........................

~j-

Allowances

for

non—metal—bearing

waste

streams.

discharge 1~.mitat~ons

 for lead and zinc for

waste streams not listed

Section

307.2490

and

not

otherwise

determined

“metal—

bearing

waste

streams”

 ~i~tdetermines that

the wastewater metals contamination is due to

background

levels

that

are

not

 reasonably

avoidable~

from

su~chsou~e~ as

intake

water

corrosion of ~ateria1s

O~ c~onstruction~

or

containination’’cf

Iffá~e

~

 The çon~rola~tho~jty

 shall

bas~ ii~

determination ~

pursuant

subse~tio~

q~a review of relevant plant

operating

conditions

process

chemistry

engineering

 and sampling and analyticAl

information.

~

The

control

authority

shall

it~

~etçma~t~n

 ma~e~pui~ua~t

t

 ~ic~

sources and

 evel

s of the meta)s

 based on

the informat .~fl_

its

disposa

The

control

authority

may

establish

 for lead

and

zinc

for

non-”metal-

bearing

waste

streams”

for

ths

purposes

j~

 the lowest level that the control

authority determi

 es::~: based on best

professional

iudgemeñt~

 can be reliably

measured and

~

 the concentration of such metals Present

the

wastestreams,

but

not

exceed

the

a~~licable

I

 t~t~c,~is

 contained in

Sections

307.2401

gh

307.2407.

~ifl For zinc

 the applicable limitations

that the discharge must not exceed

those

appearing

the

tables

Sections

307.2401

through

307.2407,

not

the alternative 1i~mitationsfor rayon

 fiber manufacture by the viscose

process.t

set

forth

footnote

L~3-13131

26

the table in 40 CFR 414 25,

inccrpcq~t~d

by r~f~r~noe

 at Ss~tion

307

•

2401(~i~

~

acrylic fiber

manufádtüre

 the zinc

chloride/solvent

process..

 set forth

footnote

 2 to the

table

CFR

414 35. ~o~t~d

 J~y~e~er~nc~ ~t

Section ~07.24O2~o)(1~

~

 The 1i~titationsfor individual discharciers

shal1bé’~?O~ a mass basis~by multiplying

the concentration allowance established by

the control authority tim~sthe process

wastewater flow from the individual

wastestreams in which incidental metals ~

present.

c)

 Compliance date.

 All dischargers subject to a

pretreatment standard for existing sources in this

Subpart

must

comply

 with the standard by no later than

November

5,

 1990.

(Source:

 Amended at 17 Ill. Req.

 effective

)

Section 307.2402

 Other Fibers

a)

 Applicability.

 This Section applies to discharges of

process wastewater resulting from the manufacture of

the

~Q1loying

 products classified under SIC 2823~

cellulosic man—made fibers and fiber groups, except

rayon~and trnder SIC 2824~synthetic organic fibers and

fiber groups~flIsted belo~. Product groups are

indicated with an asterisk

(*).

*Acrylic fibers

(85

 Polyacrylonitrile)

*Cellulose acetate fibers

*Fluorocarbon

 (Teflon) fibers

*Modacrylic fibers

*Nylon

 6 fibers

Nylon

 6 monofilament

*Nylon 66 fibers

Nylon 66 monofilament

*Polyamide fibers

 (Quiana)

*Polyaramid

 (Keviar) resin fibers

*Polyaramid

 (Nomex) resin fibers

*Polyester fibers

*Polyethylene

fibers

*Polypropylene

fibers

*Polyurethane fibers

 (Spandex)

b)

 Specialized definitions.

 None.

01143-0132

27

Existing

sources:

1)

 The Board incorporates by reference 40 CFR 414.35

(l99~).. This

incorporation includes no later

amendments or editions.

2)

No

person subject to

the pretreatment standards

 incorporated by reference in subsection jgI(1)

above shall cause, threaten or allow the discharge

of any contaminant to a POTW in violation of such

standards.

d)

 New sources:

1)

 The Board incorporates by reference 40 CFR 414.36

(l99~).

 This incorporation includes no later

amendments or editions.

2)

 No person subject to the pretreatment standards

incorporated by reference in subsection j~1(1)

above shall cause, threaten or allow the discharge

of any contaminant to a POTW in violation of such

standards.

3)

 “New source” means any building, structure,

facility or installation the construction of which

commenced after March 21,

 1983.

(Source:

 Amended at 17

 Ill.

 Reg.

 effective

Section 307.2403

 Thermoplastic Resins

a)

 Applicability.

 This Section applies to discharges of

process wastewater resulting from the manufacture of

the followingthe Products classified under

SIC 282134.

thermoplastic resins and thermoplastic resin groups~

listed below.

 Product groups are indicated with an’

asterisk

(*).

*Abietic acid

-—

 Derivatives

*ABS resins

*AB5—5AN resins

*Acrylate—methacrylate latexes

*Acrylic latex

*Acrylic resins

 *Cellulose acetate butyrates

Cellulose acetate resin

*Cellulose acetates

*Cellulose acetates priopionates

Cellulose nitrate

Ccllulozc ~pongc

01143-0133

28

*Ethylene-methacrylic acid copolymers

*Ethyiene—vinyl acetate copolymers

*Fatty acid resins

*Fluorocarbon polymers

Nylon

 11 resin

*Nylon 6—66 copolymers

*Nylon

6

 Nylon 11 blends

Nylon

 6 resin

Nylon 612 resin

Nylon 66 resin

*Nylons

*Petroleum hydrocarbon resins

*Polyvinyl pyrrolidone

 copolymers

*Poly (alpha) olefins

Polyacrylic acid

Palainides

*Polyarylamides

Polybutadiene

*Polybutenes

Polybutyl succinic anhydride

*Polycarbonates

*Polyester resins

*Polyester resins, Polybutylene terephthalate

*Polyester resins, Polyoxybenzoate

Polyethylene

*Polyethylene

 ethyl acrylate resins

*Polyethylene

 polyvinyiacetate copolymers

Polyethylene resin

 (HDPE)

Polyethylene resin

 (LDPE)

Polyethylene resin, scrap

Polyethylene resin, wax (low molecular weight)

Polyethylene resin,

 latex

Polyethylene resins

*Polyethylene resins, compounded

*Polyethylene, chlorinated

*Polyimides

*Polypropylene resins

Polystyrene

 (crystal)

Polystyrene

 (crystal) modified

*Polystyrene

— —

 copolymers

*Polystyrene

——

 acrylic latexes

Polystyrene impact resins

Polystyrene latex

Polystyrene, expandable

Polystyrene, expanded

*Polysulfone resins

Polyvinyl acetate

*Polyvinyl acetate

 PVC copolymers

*polyvinyl acetate copolymers

*Polyvinyl acetate resins

Polyvinyl alcohol resin

Polyvinyl chloride

IL..3-O

314

29

Polyvinyl chloride, chlorinated

*Polyvinyl ether

 maleic anhydride

*Polyvinyl formal resins

*Polyvinylacetate

-—

 methacrylic copolymers

*Polyvinylacetate acrylic copolymers

*Polyvinylacetate

 2-ethylhexylacrylate

copolymers

Polyvinylidine

chloride

*polyvinylidine chloride copolymers

*Polyvinylidine

 vinyl chloride resins

*PVC copolymers,

 acrylates

 (Latex)

*PVC copolymers, ethylene

 vinyl chloride

*Rosin derivative resins

*Rosin modified resins

*Rosjn resins

*SAN resins

*Silicones:

 Silicone resin

*Siljcones:

 Silicone rubbers

*Styrene

——

 maleic anhydride resins

Styrene polymeric residue

*Styrene

-—

 acrylic copolymer resins

*Styrene ——acrylonitrile ——acrylates copolymers

*Styrene

——

 butadiene resins

*Styrene

 butadiene resins (less than 50

butadiene)

*Styrene

——

 butadiene resins

 (Latex)

*Styrene

——

 divinyl benzene resins

 (ion exchange)

*Styrene

——

 methacrylate terpolymer resins

*Styrene

 methyl methacrylate copolymers

*Styrene, butadiene, vinyl toluene terpolymers

*Sulfonated styrene

——

 maleic anhydride resins

*Unsaturated polyester resins

*Vinyl toluene resins

*Vinyl toluene

-—

 acrylate resins

*Vinyl toluene

——

 butadiene resins

*Vinyl toluene

——

 methacrylate resins

*Vinylacetate

 n-butylacrylate copolymers

b)

 Specialized definitions.

 None.

c)

 Existing sources:

1)

 The Board incorporates by reference 40 CFR 414.45

(199&~). This incorporation includes no later

amendments or editions.

2)

 No person subject to the pretreatment standards

incorporated by reference in subsection j~j(1)

above shall cause, threaten or allow the discharge

of any contaminant to a POTW in violation of such

standards.

143-0135

30

d)

 New sources:

1)

 The Board incorporates by reference 40 CFR 414.46

(l99&~j.

 This incorporation includes no later

amendments or editions.

2)

 No person subject to the pretreatment standards

incorporated by reference in subsection j~~.(1)

above shall cause, threaten or allow the discharge

of any contaminant to a POTW in violation of such

standards.

3)

 “New source” means any building,

 structure,

facility or installation the construction of which

commenced after March 21,

 1983.

(Source:

 Amended at

 17 Ill.

 Req.

 effective

Section 307.2404

 Thermosetting Resins

a)

 Applicability.

 This Section applies to discharges of

process wastewater resulting from the manufacture of

the followingproducts classified under SIC 28214~

therinosetting resins and thermosettinq resin groups~

listed below.

 Product groups are indicated with an

asterisk

(*).

*Alkyd resins

Dicyanodiamide resin

*Epoxy resins

*Fumaric acid polyesters

*Furan resins

Glyoxal

 urea formaldehyde textile resin

*Ketone

——

 formaldehyde resins

*Nelamine resins

*phenolic resins

*Polyacetal resins

*Polyacrylamide

*Polyurethane prepolymers

*polyurethane resins

*Urea formaldehyde resins

*Urea resins

b)

 Specialized definitions.

 None.

c)

 Existing sources:

1)

 The Board incorporates by reference 40 CFR 414.55

(199~). This incorporation includes no later

amendments or editions.

01143—UI

31

2)

 No person subject to the pretreatment standards

incorporated by reference in subsection jgj(1)

above shall cause, threaten or allow the discharge

of any contaminant to a POTW in violation of such

standards.

d)

 New sources:

1)

 The Board incorporates by reference 40 CFR 414.56

(1994~). This incorporation includes no later

amendments or editions.

2)

 No person subject to the pretreatment standards

incorporated by reference in subsection j~j(1)

above shall cause, threaten or allow the discharge

 of any contaminant to a POTW in violation of such

standards.

3)

 “New source” means any building, structure,

facility or installation the construction of which

commenced after March 21,

 1983.

(Source:

 Amended at 17

 Ill. Req.

 effective

)

Section 307.2405

 Commodity Organic Chemicals

a)

 Applicability.

 This Section applies to discharges of

process wastewater resulting from the manufacture of

the

lcwingproduots

 classified inider SIC 2865 or

2869

 Comm

cdit’y ~

 I~~Tháñdcommodity organic

chemical groups~ listed belo~i

 Product groups are

indicated with an a~f~’r

1)

 Aliphatic organic chemicals

Acetaldehyde

Acetic acid

Acetic anhydride

Acetone

Acrylonitrile

Adipic acid

*Butylenes

 (Butenes)

Cyc1ohexane

Ethanol

Ethylene

Ethylene glycol

Ethylene oxide

Formaldehyde

Isopropanol

Methanol

Polyoxypropylene glycol

UI 143-0137

32

Propylene

Propylene oxide

Vinyl acetate

1,2-Dichloroethane

1,

3—Butadiene

2)

 Aromatic organic chemicals

Benzene

Cumene

Dimethyl terephthalate

Ethylbenzene

m-Xylene

 (impure)

p-Xylene

Phenol

*pitch tar residues

Pyrolysis gasolines

Styrene

Terephthalic acid

Toluene

*Xylenes, mixed

o-Xylene

3)

 Halogenated organic compounds

Vinyl chloride

b)

 Specialized definitions.

 None.

c)

 Existing sources:

1)

 The Board incorporates by reference 40 CFR 414.65

(199~).

 This incorporation includes no later

amendments or editions.

2)

 No person subject to the pretreatment standards

incorporated by reference in subsection ~gj(l)

above shall cause, threaten or allow the discharge

of any contaminant to a POTW in violation of such

standards.

d)

 New sources:

1)

 The Board incorporates by reference 40 CFR 414.66

(l99*~).

 This

incorporation includes no later

amendments or editions.

2)

 No person subject to the pretreatment standards

incorporated by reference in subsection ~j(1)

above shall cause, threaten or allow the discharge

of any contaminant to a POTW in violation of such

standards.

11

1

1,

0

—

UIt~tU

33

3)

 For discharges of wastewater resulting from the

manufacture of butadiene by any process which

includes the oxidative dehydrogenation of butene,

“new source” means any building, structure,

facility or installation the construction of which

commenced after December 17,

 1973.

 For other

sources,

 “new source” means any building,

structure,

 facility or installation the

construction of which commenced after March 21,

1983.

(Source:

 Amended at 17

 Ill.

 Req.

 effective

)

Section 307.2406

 Bulk Organic Chemicals

a)

 Applicability.

 This Section applies to discharges of

process wastewater resulting from the manufacture of

the

fo11owing~roducts

classified

 ~rndo~SIC 2865 or

28694. bulk organic chemicals and bulk organic chemical

groups, listed belo~

 Product groups are indicated

with ~

1)

 Aliphatic organic chemicals

*Acetic acid esters

*Acetic acid salts

Acetone cyanohydrin

Acetylene

Acrylic acid

*Acrylic acid esters

*Alkoxy alkanols

*Alkylates

*alpha-olefins

Butane

 (all forms)

C—4 hydrocarbons

 (unsaturated)

 Calcium stearate

Caprolactam

Carboxymethyl cellulose

Cellulose acetate butyrates

*Cellulose ethers

Citric acid

Cumene hydroperoxide

Cyclohexanol

Cyclohexanol,

cyclohexanone

(mixed)

Cyclohexanone

Cyclohexene

*Cl2

 C18 primary alcohols

 (mixed)

*C5 concentrates

*C9 concentrates

Decanol

Diacetone alcohol

i

L.~

..)

34

*Dicarboxylic acids

—-

 salts

Diethyl ether

Diethylene glycol

Diethylene glycol diethyl ether

Diethylene qlycol dimethyl ether

Diethylene glycol monoethyl ether

Diethylene glycol monomethyl ether

*Dimer acids

Dioxane

Ethane

Ethylene glycol monophenyl ether

*Ethoxylates, miscellaneous

Ethylene qlycol dimethyl ether

Ethylene glycol monobutyl ether

Ethylene glycol monoethyl ether

Ethylene qlycol monomethyl ether

*Fatty acids

Glycerine (synthetic)

Glyoxal

Hexane

*Hexane and other C6 hydrocarbons

Isobutanol

Isobutylene

Isobutyraldehyde

Isophorone

Isophthalic acid

Isoprene

Isopropyl acetate

Ligninsulfonic acid, calcium salt

Maleic anhydride

Methacrylic acid

*Methacrylic acid esters

Methane

Methyl ethyl ketone

Methyl methacrylate

Methyl tert-butyl ether

Methyl isobutyl ketone

n—alkanes

n-butyl alcohol

n-butyl acetate

n-butyraldehyde

n-butyric acid

n-butyric anhydride

*n—parafins

n—propyl acetate

n-propyl alcohol

Nitrilotriacetic acid

Nylon salt

Oxalic acid

*Oxo aldehydes

-—

 alcohols

Pentaerythritol

Pentane

143-01140

35

*pentenes

*petroleum sulfonates

Pine oil

Polyoxybutylene glycol

Polyoxyethylene glycol

Propane

Priopionaldehyde

Propionic acid

Propylene glycol

sec-butyl alcohol

Sodium formate

Sorbitol

Stearic acid,

 calcium salt

 (wax)

tert-butyl alcohol

1-Butene

1—Pentene

1, 4-Butanediol

Isobutyl acetate

2—Butene

 (cis and trans)

2-Ethylhexanol

2-Ethylbutyraldehyde

2,2,4-Trimethyl-1,3—pentanediol

2)

 Amine and amide organic chemicals

2, 4-Diaminotoluene

*Alkyl amines

Aniline

Caprolactam, aqueous concentrate

Diethanolamine

Diphenylamine

*Ethanolamjnes

Ethylamine

Ethylenediamine

Ethylenediaminetetraacetic acid

*Fatty ~ip~nines

Hexamethylène’diä’inme

Isopropylamine

m-Tolujcline

Melamine

Melamine crystal

*Methylamines

Methylene dianiline

n-butylamine

N,N-diethylaniline

N,N-dimethylforinamide

*Njtroanilines

Polymeric methylene dianiline

sec—butylamine

tert-butylamine

Toluenediamine (mixture)

*Toluidines

143-0114!

36

o-Phenylenediamine

1, 4-Phenylenediamine dihydrochloride

2, 6—Dimethylaniline

4- (N-Hydroxyethylethylamino)—2—hydroxyethyl

aniline

4, 4’

-Methylenebis (N, N’—dimethyl) aniline

4,4’-Methylenedianiline

3)

 Aromatic organic chemicals

alpha-methylstyrene

*Alkyl benzenes

*Alkyl phenols

*Alkylbenzene sulfonic acids,

 salts

Aminobenzoic acid (meta and para)

A3pirin

beta-naphthalene sulfonic acid

Benzenedisulfonic acid

Benzoic acid

Bis(2-ethylhexyl)phthalate

Bisphenol A

BTX

——

 benzene, toluene, xylene

 (mixed)

 Butyl

octyl phthalate

Coal tar

*Coal tar products (miscellaneous)

Creosote

*Cresols, mixed

Cyanuric acid

*Cyclic aromatic sulfonates

Dibutyl phthalate

Diisobutyl phthalate

Diisodecyl phthalate

Diisooctyl phthalate

Dimethyl phthalate

Dinitrotoluene (mixed)

Ditridecyl phthalate

m—Cresol

Metanilic acid

Methylenediphenyldiisocyanate

Naphthalene

*Naphthas,

 solvent

Nitrobenzene

Nitrotoluene

Nonyiphenol

p-Cresol

Phthalic acid

Phthalic anhydride

*Tars

——

 pitches

tert-butylphenol

*Toluenediisocyanates

 (mixture)

Trimellitic acid

o—cresol

37

1-Tetralol,

 1-tetralone mix

2, 4-Dinitrotoluene

2, 6-Dinitrotoluene

4)

 Halogenated organic chemicals

Allyl chloride

Benzyl chloride

Carbon tetrachloride

*Chlorinated paraffins,

 35—44

 chlorine

Chlorobenzene

*Chlorobenzenes

 (mixed)

Chlorodifluoroethane

Chloroform

*Chloromethanes

2-Chloro-5-methylphenol

 (6-Chloro--m-cresol)

*Chlorophenols

Chioroprene

Cyanoqen chloride

Cyanuric chloride

Dichioropropane

 Epichlorohydrin

Ethyl chloride

*

Fluorocarbons

 (Freons)

Methyl chloride

Methylene chloride

Pentachlorophenol

Phosgene

Tetrachloroethylene

Trichloroethylene

Trichlorofluoromethane

Vinylidene chloride

1,1-Dichloroethane

1,1,1-Trichioroethane

2,4-Dichlorophenol

5)

 Other organic chemicals

Adiponitrile

Carbon disulfide

Dithiophosphatco,

 sodium salt

Fatty nitriles

*Organo—tin compounds

*Phosphate esters

Tetraethyl lead

Tetramethyl lead

*Urethane prepolymers

*Waxcs, cmulsions

——

_____

___

b)

 Specialized definitions.

 None.

c)

 Existing sources:

0U~3-0

1143

38

1)

 The Board incorporates by reference 40 CFR 414.75

(l994~Z). This incorporation includes no later

amendments or editions.

2)

 No person subject to the pretreatment standards

incorporated by reference in subsection ~gj(l)

above shall cause, threaten or allow the discharge

of any contaminant to a POTW in violation of such

standards.

d)

 New sources:

1)

 The Board incorporates by reference 40 CFR 414.76

(l99~~).This incorporation includes no later

 amendments or editions.

2)

 No person subject to the pretreatment standards

incorporated by reference in subsection j~jjl)

above shall cause, threaten or allow the discharge

of any contaminant to a POTW in violation of such

standards.

3)

 “New source” means any building, structure,

facility or installation the construction of which

commenced after March 21,

 1983.

(Source:

 Amended at

 17 Ill. Reg.

 effective

Section 307.2490

 Non-complexed Metal-bearing and Cyanide—

bearing Wastestreams

The Board incorporates by reference 40 CFR 414, Appendix A

(199-32).. as amended at 57 Fed. Req.

41844

 (Sept.

11,

 1992).

 This

incorporation includes no later amendments or editions.

(Source:

 Amended at 17

 Ill.

 Req.

 effective

Section 307.2491

 Coinplexed Metal-bearing Wastestreams

The Board incorporates by reference 40 CFR 414, Appendix B

(l9~92),as amended at

57

 Fed. Reg.

41844

 (Sept.

11.

 1992).

 This

incorporation includes no later amendments or editions.

(Source:

 Amended at 17 Ill.

 Req.

 effective

IT IS SO ORDERED.

01143-011414

39

 I, Dorothy M.

 Gunn, Clerk of the Illinois Pollution Control

Board, do hereby certify that the above opinion and o~derwas

adopted by the Board on the

 day of

.z~..

1993,

by

 a vote of

6~—

I

/

Dorothy N. .9tJ.nn, Clerk

Illinois P~llutionControl Board

01143-01145