ILLINOIS POLLUTION CONTROL BOARD
    August 11,
    1994
    IN THE MATTER OF:
    )
    MARATHON
    OIL COMPANY’S PETITION
    )
    R91-23
    FOR SITE-SPECIFIC RULE CHANGE TO
    )
    (Rulemaking)
    35 ILL.
    ADM.
    CODE 303.323
    )
    Adopted Rule.
    Final Order.
    OPINION
    AND
    ORDER OF THE BOARD
    (by R.C. Flemal):
    On August 19,
    1991 Marathon Oil Company (Marathon)
    filed
    this proposal for site—specific rulemaking.
    Marathon seeks to
    amend the limits contained in the current site—specific rule at
    35
    Ill.
    Adm. Code 303.323 pertaining to chloride.
    The Board’s responsibility in this matter arises from the
    Environmental Protection Act
    (Act)
    (415 ILCS 5/1 et seq.
    (1992)).
    The Board is charged therein to “determine, define and implement
    the environmental control standards applicable in the State of
    Illinois”
    (415 ILCS 5/5(b)).
    More generally,
    the Board’s
    rulemaking charge is based on the system of checks and balances
    integral to Illinois environmental governance:
    the Board
    is
    responsible for rulemaking and adjudication; the Illinois
    Environmental Protection Agency
    (Agency)
    is responsible for
    carrying out the principal administrative duties.
    The latter’s
    duties include administering today’s regulation.
    Today the Board adopts Marathon’s proposal.
    The new
    regulation will become effective upon filing with the Secretary
    of State.
    REGULATORY AND PROCEDURAL HISTORY
    The Board’s general effluent regulations do not include a
    specific liitiitation for chloride.
    However, they do prohibit any
    discharge that would cause or contribute to a violation of a
    water quality standard
    (35 Ill. Adm. Code 304.105), and there are
    water quality standards for chloride.
    In the instant matter, the
    pertinent water quality standard for chloride is the 500 mg/L
    General Use Water Quality Standard found at 35 Iii.
    Adxn.
    Code
    302.304.
    Marathon initially petitioned this Board for temporary
    exemption of its receiving waters from the 500 mg/L water quality
    standard in PCB 80-102.
    On October
    2,
    1980 the Board granted

    —2—
    this petition for variance, under condition that chloride
    effluent concentrations not exceed 700 mg/L, effective through
    October
    2,
    1985.
    In PCB 85-83 Marathon petitioned for extension of the PCB
    80—102 variance with respect to chloride.
    On January 23,
    1986
    this petition was granted effective for the period October 2,
    1985 through October
    2,
    1990.
    On January 28,
    1987 Marathon filed a site—specific
    rulemaking petition seeking,
    among other matters, to make
    permanent its exemption from causing or contributing to
    violations of the 500 ing/L water quality standard under the
    continuing provision that its effluent discharge not exceed 700
    mg/L.
    On September 13,
    19891 the Board responded to Marathon’s
    petition by promulgating a new rule at 35 Ill.
    Adm. Code 303.323.
    The new rule generally tracked Marathon’s proposal, except that
    the Board added
    a
    550 mg/L limit on in-stream chloride
    concentrations as recommended by the Agency.
    Accordingly, prior
    to today’s action the applicable rule has been:
    Section 303.323
    Sugar Creek and Its Unnamed
    Tributary
    a)
    This Section applies only to Sugar Creek and
    its unnamed tributary from the point at which
    Marathon Petroleum2 Company’s outfall 001
    discharges into the unnamed tributary to the
    confluence of Sugar Creek and the Wabash
    River.
    b)
    35 Ill.
    Adm. Code 304.105 shall not apply to
    total dissolved solids and chlorides
    discharged by Marathon Petroleum Company’s
    Outfall 001,
    so long as both of the following
    conditions are true:
    1)
    Effluent from Marathon Petroleum
    Company’s Outfall 001 does not exceed
    3,000 mg/i total dissolved solids or 700
    mg/i chlorides,
    2)
    The water in the unnamed tributary does
    not exceed 2,000 mg/i total dissolved
    solids or 550 mg/i chlorides.
    1
    In the Matter of: Marathon Petroleum Company Site-Specific,
    R87—2,
    103 PCB 133.
    2
    Marathon Oil Company is the successor in interest to Marathon
    Petroleum Company
    (VResp. brief at 1).

    —3—
    On August 19,
    1991 Marathon filed this site-specific
    rulemaking proposal, seeking to amend the chloride provisions of
    Section 303.323.
    Therein Marathon proposed to increase the site-
    specific effluent chloride limitation from 700 mg/L to 1000 ing/L
    and the chloride water quality standard from 550 mg/L to 700
    mg/L.
    Hearing was held before hearing officer Karen Rosenwinkel on
    this site—specific petition on September 10,
    1992 in Robinson,
    Illinois.
    No members of the public attended.
    Briefs were filed
    by Marathon on April
    12,
    1993 and by the Agency on May 17,
    1993.
    On October
    7,
    1993 the Board adopted this matter for first
    notice.
    Publication occurred at 17 Iii.
    Reg.
    18759, October 29,
    1993.
    Two public comments were filed during the first—notice
    comment period, each dealing with ministerial matters3.
    On June 21,
    1994 the Board adopted Marathon’s proposal for
    second notice.
    The proposal was adopted without change from
    first notice.
    The second notice proposal was reviewed by the
    Joint Committee on Administrative Rules, which issued a notice of
    no objection on July 19,
    1994.
    During the early pendency of the instant regulatory
    proposal, Marathon also had before the Board a related variance
    petition.
    In that petition Marathon requested as variance
    conditions the same 1000 mg/L and 700 mg/L effluent and water
    quality limitations that are here adopted as amendments to
    Section 303.323.
    The variance proposal was filed on September 17,
    1991 and
    docketed as PCB 91-173.
    On December 19,
    1991 the Board granted
    Marathon’s motion to incorporate the record of the variance
    proceeding into this site—specific rulemaking proceeding4.
    The Board initially denied the variance.
    However, upon
    appeal the Board’s denial was reversed5 and on October 7,
    1993
    the Board issued the variance6.
    That variance is scheduled to
    ~ PC
    #4
    filed
    by
    the
    Illinois
    Department
    of
    Commerce
    and
    Community
    Affairs
    and
    PC
    #5
    filed
    by
    the
    Administrative
    Code
    Division of the Office of the Secretary of State.
    ‘~
    In the Matter of:
    Marathon Oil Company Site Specific, R91-
    23,
    128 PCB 899.
    ~ Marathon Oil Company v.
    IEPA and PCB
    (5th Dist.
    1993),
    242
    Ill.App.3d 200,
    610 N.E.2d 789,
    182 Iii.
    Dec.
    920.
    6
    Marathon Oil Company
    v.
    Illinois Environmental Protection
    A~encv,PCB 91-173,
    PCB
    —.

    —4—
    expire on October 7,
    1994,
    or upon final disposition of the
    instant rulemaking, whichever occurs first.
    FACILITY DESCRIPTION
    Marathon operates a petroleum refinery located on the
    outskirts of the City of Robinson, Crawford County,
    Illinois.
    The refinery processes approximately 200,000~barrels of oil per
    day and employs approximately 650 persons
    (SSPet. 1-2.)~
    Part of the refining process consists of removing chloride
    mixed with water from the crude oil.
    The quantity of chloride in
    the crude oil varies depending upon the nature of the pore fluids
    in the source rocks of the crude oil and the history of recovery,
    transportation, and storage of the crude oil.
    Because the
    Marathon facility receives crude oil from different sources, the
    chloride content of the crude processed at the facility likewise
    differs.
    Since 1988 the chloride content has varied on a
    monthly-average basis from a low of 29.2 pounds per million
    barrels to 104.5 pounds per million barrels;
    in the first ten
    months of 1991 chloride contents ranged from an average of 48.5
    to 88.7 pounds per million barrels
    (VPet.
    Exh. 8.)
    Marathon treats its wastewaters prior to discharging them.
    However, the treatment is not capable of producing significant
    reduction in chlorides.
    Marathon is in the process of designing
    an upgraded treatment facility that would allow it to increase
    treatment capacity, but this too would have only marginal effect
    on chloride discharge concentrations and does not contain any
    specific technology to remove chlorides
    (VTr. at 25-27.)
    The
    effluent chloride that the plant discharges is basically
    dependent on the salt content in the crude oil and the amount of
    water discharged to the creek.
    (SSTr. at 8.)
    ~The record contains different figures for the amount of crude
    processed per day at this facility.
    The figures range from 170,000
    to 205,000 barrels per day.
    (SSPet. 1—2; VTr. 11; SSTr.
    6,
    23,
    36;
    SSPet.
    Exh. A-l)
    g
    Citations to the record will indicate transcript references
    as “Tr.”,
    petition as “Pet.”,
    exhibits as
    “Pet.
    Exh.”
    or
    “Resp.
    Exh.”,
    and briefs as “Pet.
    Br.” or “Resp. Br.”.
    Citations to the
    site—specific and variances records will
    be distinguished where
    necessary
    by prefacing
    the
    citations
    with
    “SS”
    for
    the site-
    specific record and “V” for the variance record; e.g.,
    “SSPet. at
    xx.,,

    —5—
    Discharge of the wastewaters is to an unnamed9 tributary of
    Sugar Creek at approximately mile 5.0 of the unnamed tributary;
    Sugar Creek thence flows approximately five miles more to its
    mouth on the Wabash River
    (SSPet.
    2, Attachment A; VPet.
    Exh.
    1
    at 8.)
    The unnamed tributary at the Marathon discharge has a
    drainage area of approximately eight square miles
    (VTr.
    at 15)
    and a natural 7—day 10-year low flow of zero
    (VTr. at 22).
    However, actual low flow in the unnamed tributary is controlled
    by wastewater and other manmade discharges.
    These include
    discharges located upstream from Marathon’s discharge that
    aggregate an average of approximately 1.4 million gallons per day
    (MGD’°) (SSPet.
    Exh.
    1 at A3, VTr. at 15-6),
    of which the
    discharge of the City of Robinson’s sewage treatment plant at 1.2
    MGD is the largest.
    Marathon itself discharges an average of
    another 1.4 MGD, such that the low flow is approximately doubled
    due to Marathon’s discharge.
    TECHNICAL FEASIBILITY AND ECONOMIC REASONABLENESS
    Compliance Efforts
    Over the years Marathon has examined different treatment
    alternatives for chloride, including concentrating the chloride,
    removing it, and disposing of it underground by injection or in a
    dried form in landfills.
    Marathon has also examined transporting
    the effluent to a larger water body via pipeline and discharging
    it there.
    Marathon argues that none of these alternatives is
    technically feasible or economically reasonable.
    (SSTr. at 8—9.)
    Marathon currently uses storing techniques employing storm
    water impoundments.
    The storage process is described as total
    diversion of the effluent from the wastewater plant to storm
    water basins with later treatment of both collected stormwater
    and already once—treated, diverted effluent.
    Discharges from the
    plant are resumed again during periods of higher flow.
    (SSTr. at
    10—11.)
    Marathon maintains that the storage option, while
    technically feasible, does not work during periods when high
    chloride content in crude and storm events coincide.
    Marathon
    offers that preventing discharges that exceed the limits is
    increasingly harder to achieve during such storm events.
    ~ Although
    not
    officially
    named,
    the
    creek
    is
    sometimes
    referred to as Robinson Creek
    (e.g., VPet.
    Exh.,
    p.
    6).
    10
    One MGD equals 0.04381 cubic meters per second or 1.55 cubic
    feet per second
    (cfs).

    —6—
    Furthermore, Marathon presents that the potential for discharging
    effluent that exceeds the limits will increase due to additional
    planned changes in the operation of the storm water diversion
    system.
    Marathon intends to divert storm water out of the ponds,
    close the ponds,
    and replace them with tanks.
    This would result
    in a diminished amount of water to dilute the effluent from the
    treatment plant.
    The amount of dilution water is diminished
    because certain storm water runoff is not considered contaminated
    and no longer will be mixed with the contaminated storm water
    runoff.
    (SSTr.
    at 11-13.)
    The closure of the ponds may be
    necessary due to potential groundwater contamination and cleanup
    due to other contaminants present in the pond sediment
    (SSTr. at
    67.)
    ENVIRONMENTAL IMPACT
    The environmental impact issues are twofold.
    One issue
    involves Marathon’s position, acceded to by the Agency, that the
    continued use of the current management practices,
    especially in
    light of the planned changes to the treatment plant, may result
    in a negative impact on the receiving waters.
    The second
    consideration consists of an unknown toxicity problem present in
    Marathon’s effluent, and the Agency’s concerns that increased
    chloride may additionally burden an already stressed aquatic
    population.
    Storage Impacts
    Marathon presents that the storage option of controlling
    chloride levels in the plant effluent, discussed above, has a
    potential negative environmental impact on the stream due to the
    greater chance of overflow during certain storm events.
    Marathon
    further states that the use of all the storm water retained in
    the ponds to dilute the chloride has historically resulted in
    greater swings in the concentration of chloride discharged, which
    Marathon believes
    is not beneficial to the fish population.
    (SSTr.
    at 70.)
    The Agency basically concurs with Marathon’s assessment of
    the environmental impact of the currently—employed management
    techniques,
    as described in the testimony of Dean Studer:
    Although unable to determine at this time if
    discharging a “more continuous but higher level of
    chlorides in the stream”
    is any less stressful
    on
    the
    fish population,
    the Agency does believe that raising
    the water quality standard for chlorides in the
    receiving stream to allow Marathon to continually
    discharge effluent from outfall #001 is environmentally

    —7—
    prudent.
    Such
    a change in the chloride water quality
    standard would minimize the potential stress from the
    cyclic changes in flow and water quality resulting from
    the alternating cessation and commencing of discharge.
    *
    * *
    Given the nature of the receiving stream and the
    unknown toxicity problem,
    if an emergency bypass were
    to occur,
    it is possible that the discharge would
    contribute to the degradation of the receiving stream.
    (SSExh.
    4 at 7.)
    Unknown Toxicity Problem
    The unnamed tributary in question has been the subject of
    previous study.
    Marathon’s environmental consultant, Radian
    Corporation, performed
    a study of the receiving stream in 1986,
    finding that, while there were no fish for a distance below the
    Marathon outfall, the water quality and stream sediment quality
    had improved since a study done in 1976 by the Agency.
    (VTr. at
    47; VPet.
    Exhs.
    1,2.)
    A study was also undertaken by the Agency
    in 1986 and published in 1988.
    (VPet.
    Exh.
    1.)
    Marathon
    believes that the Agency’s study reaches the same basic
    conclusions as the Radian Corporation study.
    There are differences between the studies, mainly in scope,
    as the Agency study encompassed general stream quality while the
    Marathon study was limited to the Marathon discharge.
    (VTr. at
    45—46.)
    In 1991,
    the Agency performed a survey of the fishes of
    the Sugar Creek Basin in the proximity of the Marathon discharge
    and found some improvement in the fish population since the two
    1986 studies,
    as well as a lack of toxicity in the stream
    sediment.
    (Vresp.
    Exh.
    1.)
    The Agency reported fishless
    conditions for four
    (4) miles downstream of the Marathon outfall
    and concluded that “it seems very likely that the continued
    effluent toxicity from Marathon is the cause of impacts on the
    fish community”.
    (Id.)
    The 1991 study as well as the 1986 studies show that there
    continues to be an effect downstream of the Marathon discharge
    that is limiting or reducing the number of fish in the Sugar
    Creek Basin area.
    (VTr. at 49-50; VResp.
    Exh.
    1.)
    As Robert
    Wallace,
    of Radian Corporation testified:
    The
    Agency
    and, for that matter, Marathon, are at a
    loss to explain the stream degradation that is apparent
    from observation of the biological community in the
    stream, and there is some frustration on both sides
    because it can’t be clearly shown what’s causing it.
    Whether it’s something in the discharge or not, we
    don’t have identification of a chemical that’s causing
    the observed toxicity.
    (VTr. at 50.)

    —8—
    Degradation was also attributed to the City of Robinson sewage
    treatment plant effluent, but there has been improvement
    downstream from that plant.
    (SSPetition at C 1-4,
    2-2.)
    Effects of Higher Chloride Concentration
    Marathon presented two recent studies prepared by its
    consultant, Radian Corporation, Marathon Oil Company Chloride
    Study of Robinson Creek, August 1992
    (SSExh.
    3), and Marathon Oil
    Company 7-Day Chronic Fathead Minnow-Larval Survival and Growth
    Test, July 1992
    (SSExh.
    2.)
    Based on these studies, Marathon’s
    witness, Robert C. Wallace concluded that “the
    results of these
    studies indicate that a chloride limitation of 1600 mg/L in the
    effluent would result in an instream chloride concentration at
    low flow of less than 1,000 mg/L,
    a level shown to be non-toxic
    to aquatic life”.
    (SS.Exh.
    1 at
    1.)
    The chronic toxicity test
    results are summarized as follows:
    A 7—day chronic fathead minnow test was conducted on
    synthetic effluent chloride levels of 700, 800,
    900,
    and 1,000 mg/L while holding total dissolved solids
    (TDS)
    constant at 2,000 mg/L.
    Results of the chronic toxicity test indicated that
    chloride concentrations up to 1,000 mg/L,
    the highest
    level tested, had no significant negative effect on
    fish survival.
    Larval survival in all chloride test
    solutions was greater than or equal to 93 percent.
    Bioxnass was higher in all chloride test solutions than
    in control groups.
    The no—observed effect
    concentration (NOEC)
    for the test was 1,000 mg/L
    chloride and the percent impairment concentration
    (1C25) was greater than 1,000 mg/L chloride.
    This
    would indicate that 1,000 mg/L chloride and 2,000 mg/L
    TDS do not produce toxicity to larval fathead minnows
    and should not be toxic to aquatic life in Robinson
    Creek.
    (SSExh.
    2 at 1-1.)
    The Agency did not dispute the results of these studies, per
    Se, but rather continued to assert its position that the
    chlorides may constitute a stress factor:
    The Agency is concerned that raising the chloride water
    quality standard too high will stress the aquatic biota
    and exacerbate the existing toxicity problems in the
    waters below Marathon’s outfall.
    Further, with the
    existing chronic toxicity problem in Marathon’s
    effluent, any toxicity tests for chloride will be
    biased.
    Therefore,
    the only way to measure the effects
    due strictly to chloride is to use a synthetic effluent
    in toxicity testing.
    This technique,
    being the sole
    option open to petitioner for chloride toxicity testing

    —9—
    at this time, was employed by petitioner in support of
    this proposal.
    This process, through its very nature,
    ignores the interaction of elevated chloride levels
    with the existing toxicity in Marathon’s effluent and
    introduces a decree
    sic)
    of bias
    in the results.
    (SSExh.
    4 at 4.)
    The Agency went on to state that it believes that in all
    probability, this bias in the testing will increase as the
    chloride levels go higher; therefore, the Agency is skeptical of
    the toxicity results.
    (SSExh.
    4 at 4-5.)
    Parties’ Positions
    The Agency agrees that site-specific relief for chloride is
    necessary.
    However due to the toxicity problem, the Agency
    expressed belief that the relief should be temporary,
    and that a
    toxicity reduction evaluation
    (TRE)
    should be required.
    Marathon
    is opposed to temporary relief in this site-specific rulemaking
    because of the time and effort that would be needed to complete
    another rulemaking in the future.
    Marathon also disagrees that a
    TRE should be required as a condition of the requested relief,
    pointing out that TRE’s are usually imposed by the Agency in the
    course of the grant of an NPDES permit.
    (VPet.
    status report. at
    3; see also,
    SSTr. at 50.)
    CONCLUSIONS
    In its first notice opinion, the Board concluded as follows:
    The Board is persuaded, based upon an analysis of
    the record in this proceeding, that there
    is no
    alternative treatment method for Marathon that is
    simultaneously technically feasible and economically
    reasonable.
    The Board is also persuaded that the
    increase in chloride in Marathon’s effluent as proposed
    here,
    is not
    a known limiting factor in the quality of
    the receiving waterway.
    Accordingly, the Board will
    today propose for first notice a rule which would
    provide the relief requested,
    as modified to comport
    with Administrative Code Division requirements.
    The Board emphasizes that it shares the Agency’s
    concern over the toxicity in the unnamed tributary.
    This toxicity needs to be characterized and eliminated.
    The toxicity issue would seem to be appropriately
    addressed in the NPDES permitting process.
    There the
    nature of the effluent in all its water quality aspects
    (including its possible toxicity)
    is a relevant concern
    (footnote: The Board notes that it is not prejudging
    the imposition of TRE’s
    in the pending permit appeal,

    —10—
    PCB 92-166, but only states that the issues are better
    raised in the permit context.).
    The Board also notes that its support of
    Marathon’s proposed amendment is predicated on the
    belief that chloride at the concentrations proposed is
    not a known notable contributor to degraded aquatic
    conditions in the unnamed tributary.
    Any evidence that
    would cause an opposite conclusion to be drawn at any
    time in the future would be grounds to reverse this
    support.
    The Board today affirms its first-notice conclusions.
    In
    the face of these conclusions and the absence of any substantive
    additions to the record since first notice, the Board finds that
    final action on this matter
    is warranted.
    ORDER
    The Board directs that the following amendments be submitted
    to the Secretary of State for final notice pursuant to Section
    6
    of the Illinois Administrative Procedure Act.
    PART 303
    WATER USE DESIGNATIONS
    AND
    SITE SPECIFIC
    WATER QUALITY STANDARDS
    Section 303.323
    Sugar Creek and Its Unnamed Tributary
    a)
    This Section applies only to Sugar Creek and its
    unnamed tributary from the point at which Marathon
    Petrolcum
    QjJ~
    Company’s outfall 001 discharges into the
    unnamed tributary to the confluence of Sugar Creek and
    the Wabash River.
    b)
    35 Ill.
    Adm. Code 304.105 shall not apply to total
    dissolved solids and chlorides discharged by Marathon
    Pctrolcum
    QJJ~
    Company’s outfall 001,
    so long as both of
    the following conditions are truc ~
    1)
    Effluent from Marathon Pctrolcum
    QjJ.
    Company’s
    outfall 001 does not exceed 3,000 mg/-l~total
    dissolved solids or ~-GG1,000 mg/n chlorides,
    and
    2)
    The water in the named tributary does not exceed
    2,000
    mg/-IL total dissolved solids or 454
    ~Q
    mg/~chlorides.
    IT IS SO ORDERED.

    —11—
    I, Dorothy M. Gunn, Clerk of the Illinois Pollution Control
    Board, hereby cert4~ythat the abov
    opinion and order was
    adopted on the
    //~—/--
    day of
    _______________,
    1994,
    by a vote
    of
    ~
    .
    (~?K24LI~LlA.
    ~
    —1~orothyM.
    q~ittn, Clerk
    Illinois Po~utionControl Board

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