ILLINOIS POLLUTION CONTROL BOARD
    March 14
    ,
    1972
    IN MATTER OF PROPOSED REGULATION
    BANNING PHOSPHATES
    IN DETERGENTS
    )
    #R71-lO
    I~NDOTHER CLEANING PRODUCTS
    OPINION OF THE BOARD
    (BY MR. LAWTON):
    Pursuant to Section
    28 of the Environmental Protection Act, Earthforce,
    Inc.
    and Northwestern Students
    for
    a Better Environment submitted
    a pro-
    posed regulation for consideration,
    providing
    as
    follows:
    “No detergent or other cleaning product containing
    phosphorus compounds may be sold in Illinois after
    June
    1,
    1972.”
    The Board found that the petition satisfied the procedural requirements
    of Section 28, was not plainly devoid of merit and did not deal with
    a
    subject on which
    a hearing had been previously held.
    Hearings were held
    in Chicago and Peoria.
    The presentation of the proponents consisted primarily of
    a statement
    attributed to Dr. Wesley 0.
    Pipes, which was read into the record at the
    first hearing,
    Dr. Pipes appearing for cross-examination at a later hear-
    ing.
    Speaking
    in support of
    the proposal were H.
    W. Poston,
    Commissioner
    of Environmental Control
    for the City of Chicago;
    Lee Botts,
    Executive
    Secretary of the Lake Michigan Federation;
    and three witnesses on behalf
    of Armour—Dial,
    Inc.
    Principal opponent of
    the proposed regulation was
    The Soap and Detergent Association which presented industry witnesses
    and
    a substantial amount of written material.
    Mr. Ralph Evans appeared
    as
    a Board witness.
    Section
    27 of the Environmental Protection Act requires that in pro-
    mulgating regulations,
    the Board shall
    take into account the technical
    feasibility and economic reasonableness of reducing the particular pollu-
    tion involved.
    Title III,
    Section
    11,
    dealing with the Board’s powers
    with respect to prohibition of water pollution states as one of the
    purposes of the title
    the assurance that no contaminants
    are discharged
    into
    the waters of the State without being given the degree of treatment
    or control necessary
    to prevent pollution.
    Phosphorus
    and phosphate discharges
    into the waters of Illinois have
    been
    the subject of considerable concern and action by the Board since
    its inception.
    Regulation #70-6 established water quality and effluent
    standards for phosphorus discharges into Lake Michigan.
    In adopting
    state-wide effluent standards,
    #R70-8, we limited emission of phosphorus
    4
    71

    Regulation #71-14, Water Quality Standards,
    adopted March
    7,
    1972,
    provides
    as
    follows:
    “203(c)
    Phosphorus
    (STORET number
    -
    00665)
    :
    Phosphorus
    as
    P
    shall not exceed 0.05 mg/i in any reservoir
    or lake,
    or in any stream at the point where
    it
    enters
    any reservoir or
    lake.’
    Section
    206
    limits phosphorus
    in Lake Michigan to
    .007 milligrams
    per liter.
    The opinion
    in support
    of the regulations
    states
    as follows:
    “203(c)
    provides
    a phosphorus limit for reservoirs
    and lakes
    and
    for streams tributary
    to them.
    The evidence
    is strong
    that phosphorus
    above this
    level in relatively still water
    can give
    rise to obnoxious algae blooms.
    The evidence does
    not
    support the
    need for
    a phosphorus standard in other situations,
    and
    the proposal
    for such
    a standard
    is here omitted.
    So is the
    earlier
    proposal
    for
    an
    algae
    limit,
    which
    was
    too
    stringent
    to
    indicate
    the
    presence
    of
    a
    nuisance.
    The
    evidence
    does
    not
    support
    any
    numerical
    standard
    for
    algae,
    and
    we
    rely
    upon
    the
    nuisance standard of 203(a)
    .
    We have not defined “reservoir”
    or worked out on a case-by—case basis in light of
    the policy
    here expressed.
    Not every navigation dam will be held to create
    a lake for
    this purpose.
    Despite the uncertainty,
    it does not
    seem appropriate
    to
    postpone necessary regulation for lack of
    a
    perfect
    definition.”
    The
    regulations
    promulgated
    by
    the
    Board
    manifest
    an
    intention
    to
    minimize
    the
    discharge
    of
    phosphorus
    and
    phosphates
    into
    the
    waters
    of
    the
    state
    where
    such
    limitation
    is
    necessary
    in
    furtherance
    of
    our
    statutory objectives.
    However,
    the record in the present proceeding
    does not support adoption of
    the
    regulation
    as
    proposed.
    Accordingly,
    the petition for adoption of
    the regulation must be denied at this time.
    In arriving at this decision, we
    do not foreclose further consideration
    of this regulation or one of similar import.
    Our holding today
    is
    merely
    a determination that on the record
    of the present proceeding,
    a
    state-wide phosphate ban for detergents
    is not justified.
    The principal issues emerging from the hearings
    are first, whether
    phosphorus
    removal
    at the source
    is necessary
    in lieu of or in addition
    to phosphate
    removal at the sewage treatment plant,
    secondly, whether
    satisfactory substitutes exist
    for phosphate in consideration of requisJt~
    detergent capabilities,
    and lastly, whether such substitute materials
    are reasonably safe to those who use them as well
    as those in their
    proximity.
    Phosphate
    is
    used
    in
    detergents
    to
    increase
    efficiency
    of
    the
    surfa
    active
    agent,
    to keep dirt particles suspended
    in wash water,
    to furnisl
    necessary alkalinity
    for proper cleaning,
    to provide resistance against
    4
    73

    criteria
    for phosphorus without phosphate removal processes at
    treatment plants.
    The technical feasibility and economic reasonable-
    ness ci phosphate
    removal at waste water treatment plants is conceded.
    However,
    if
    detergent phosphate
    is banned,
    it is contended that
    sub-~
    stantial savings will be effected
    in
    the
    treatment plant operation
    resulting from the decreased
    use of
    chemicals and decreased costs
    of
    sludge disposal.
    Also,
    with
    a detergent ban, petitioners contend that
    in some instances, phosphate removal processes would
    not
    be necessary
    at
    all in order to meet water
    quality effluent standards,
    The decrease
    in chemicals needed for treatment would save much—needed resources
    (R,39,)and at
    the same time lessen the dissolved solids entering the
    receiving waters.
    Petitioner concludes as follows:
    I. That installation of phosphate
    removal processes at municipal waste water plants is technically feasi-
    ble and economically reasonable;
    2.
    That phosphate removal would
    still be required in many instances, even if phosphates are banned
    from
    detergents;
    3,
    That in flowing streams which provide adequate
    dilution, water quality protection will be assured even without the
    e:nployment of phosphate removal processes
    if
    a phosphate detergent
    ban
    is
    invoked;
    4. The banning of phosphates from detergents
    is an attrac-
    tive alternative to
    the
    installation of phosphate removal processes
    at all municipal waste water treatment plants because the money saved
    by not installing phosphate removal equipment can be used to solve other
    water pollution problems, because phosphate removal processes will
    con-’
    sume
    resources and energy,
    because some phosphate removal processes
    add to the chloride and sulphide content of the effluent and because
    all phosphate removal processes increase the problem of sludge disposal.
    (R,41)
    Dr. Pipes next considers the sources
    of phosphorus in surface waters
    considering the relative contribution of storm water and land
    run-off and observing that efforts to control agricultural run—off as
    well as urban storm drainage and effluent control are necessary to
    resolve the phosphorus problem.
    As stated in the testimony,
    “The
    banning of phosphorus detergents will not solve the entire problem of
    phosphorus in the surface waters.
    We realize the control
    oE dispersed
    sources of pollutants
    is more difficult than the control of identifiable
    discharges.
    We believe that the limitation of phosphorus content in
    effluents
    is an essential step in arriving at the solution to the phos-
    phorus problem.
    We also support the Board in their attempts to take the
    necessary steps
    to solve the other parts of the problem,”
    (R.44)
    Dr. Pipes next discusses phosphorus
    as
    a pollutant,
    observing that
    phosphates discharged into municipal and industrial effluent serve as
    nutrients for algae and other aquatic vegetation.
    While the effect of
    excessive algal growth in lakes has not been disputed, the point of
    controversy has been whether the phosphates
    or other nutrients such
    as
    carbon or nitrogen are the controlling factors which limits excessive
    algal growth.
    Publication entitled “The Effect of Carbon on Algal
    Growth
    -
    its Relationship
    to Eutrophication”
    is referred to, in which
    4
    75

    and
    by
    using
    pickling
    liquor,
    a
    steel
    waste
    product,
    “one
    pollutant
    can be used
    to get rid of two”,
    (Exhibit
    l2A and
    B)
    Three witnesses
    from Armour-Dial,
    Inc.
    testified in support of
    the
    proposed
    regulation,
    addressing
    themselves
    principally
    to
    a
    non—
    phosphate detergent called
    ‘Triumph’
    in which
    the phosphate builder is
    replaced by sodium carbonate.
    The product
    is manufactured by DeSoto,
    Inc. and is identical
    to products distributed by Sears,
    Roebuck
    &
    Company and Whirlpool Corporation under other brand names.
    The sub-
    stance of their testimony was
    that the sodium carbonate-based detergent
    they have been working with is ecologically preferable to
    a phosphate-
    based detergent,
    that it does
    not possess attributes
    of toxicity or
    corrosiveness exceeding most phosphate—based detergents,
    that phosphate—
    based detergents
    are
    as hazardous
    and that the dangers resulting from
    non-phosphate detergents have been over—dramatized.
    Lastly,
    the
    Armour-Dial,
    Inc. witnesses contend that its product
    is
    as good
    a
    detergent as
    the best-selling phosphate product and superior to
    a consi-
    derable number of others in terms
    of soil removal,
    performance on fabrics1
    water softening,
    absence of film
    and other considerations by which the
    effectiveness
    of detergents are judged.
    (R.60
    to
    84)
    With respect
    to the possible reduction of flame-retarding finishes,
    the witness observed that such
    fabrics presently in use have been de-
    signed for use with phosphate-based detergents
    and that other resins
    used
    for flame retardation could be employed that would not be affected
    by sodium carbonate based detergents
    (R.83)
    A witness
    for DeSoto,
    Inc.
    supporting the testimony of the Armour—
    Dial,
    Inc. witnesses discussed the subject of precautionary labeling,
    observing that no detergent, phosphate or non-phosphate,
    is safe
    to
    eat,
    put in the eye, or leave on
    the skin for long periods of time and
    that
    all detergents should have precautionary labels with first-aid
    instructions.
    (R.85).
    He concluded that it is not fair to say that
    there is no safe and effective substitute
    for phosphate detergents and
    that
    the DeSoto product cleans
    as well
    and is
    as
    safe as phosphate-
    based detergents in use for many years
    (R.95)
    The foregoing constituted
    the principal testimony in support of the
    proposed regulation.
    ~r. Ralph Evans
    (R.l26),
    Head of the Water Quality Section of
    the
    Illinois State Water Survey,
    appeared as
    a Board witness.
    He testified
    that there is
    no question
    that phosphorus
    is
    a major algal nutrient and
    the most controllable of many nutrients required for algal productivity,
    which alone makes it attractive for control purposes.
    Phosphorus,
    on
    the other hand,
    is
    not toxic,
    does not directly degrade water quality and
    serves usefully in detergent formulations for cleaning purposes.
    He
    observed that the current controversy regarding phosphorus has developed
    from its association with the term “eutrophication”, which,
    in essence,
    is the process
    by which
    a body of water becomes over—nourished from
    4
    77

    James
    N.
    Carlisle,
    Manager
    of
    the
    Great
    Peoria
    Sanitary District,
    testified
    that
    even
    with
    removal
    of
    phosphates
    from
    detergents,
    the
    final
    effluent
    from
    the
    treatment
    facility
    would
    contain
    3
    or
    4
    milligrams
    per
    liter
    of
    phosphorus,
    which
    would
    require
    phosphorus
    removal
    at
    the
    plant
    in
    order
    to
    meet
    the
    1
    milligram
    per
    liter
    pro-
    posed
    for
    certain
    streams,
    If
    pickle
    liquor
    is
    employed,
    the
    two
    major
    costs
    ~ouid~be
    for
    chemical
    and
    sludge
    removal.
    In
    his
    judgment,
    the eva
    ability
    of
    chemicals
    locally
    would
    reduce
    chemical
    costs
    and
    sludge
    remc
    costs
    would
    remain
    essentially
    the
    same.
    He
    believes
    that
    the
    benefit
    of
    a
    phosphate
    ban
    would
    no.t
    be
    considerable
    because
    treatment
    at the
    plant
    would
    still
    be
    necessary.
    In
    his
    view,
    “at
    the
    present
    time,
    there
    are
    too
    many
    conflicting
    opinions,
    unsupported
    by
    proven
    data
    which
    make
    the
    benefits
    derived
    (from
    a
    phosphate
    ban)
    questionable.’
    (R. 136.)
    Keith
    A.
    Booman,
    Technical
    Director
    of
    the
    Soap
    and Detergent Asso-
    ciation,
    testified in opposition
    to the proposed regulation
    (R.l44)
    He summarized the uses
    of phosphate
    in
    detergents,
    including
    water
    softening,
    dirt
    suspension,
    alkalinity
    and
    emulsification
    of
    oil
    and
    grease,
    stressing
    the
    safety
    of
    the
    phosphates
    to
    humans,
    aquatic
    life,
    fabrics
    and
    machinery.
    Also
    emphasized
    was
    the
    use
    of
    specialty
    deter-
    gents used in hospitals,
    restaurants,
    dairies,
    food processing plants
    and meat and poultry plants.
    The statement
    of
    Dr.
    Steinfeld,
    Surgeon
    General
    of
    the
    United
    States
    was
    read into the record in part:
    “...I am concerned.. .with another danger which
    deserves our attention, danger that the national outcry
    over the levels
    of phosphates
    in detergents will become
    so great
    as
    to obscure the health or environmental im-
    pact of alternatives to phosphates..
    Lew Theoharous, Associate Director of Research for Proctor
    & Gamble
    Company reviewed the relation between phosphates
    in detergents
    and
    eutrophication.
    His review of statements made by scientists to the
    Federal Trade Commission during April and June of 1971
    lead to the
    following conclusions:
    that accelerated eutrophication is limited to
    a small portion of the country and does not create
    a public health
    problem,
    that where eutrophication is
    a problem, removal of phosphates
    from detergents will have little or no effect on
    the growth of algae
    and that the consensus of opinion was that replacement
    for phosphates
    should be authorized only when
    such replacements have been adequately
    tested for environmental
    safety.
    Simulated experiments conducted in
    apartment house complexes where phosphate detergents were
    not used,
    suggested that the waste water without phosphate detergent would have
    the same algal-producing characteristics
    as waste water in which phos-
    phate detergent was present and that treatment by precipitation of
    sewage containing phosphate detergent would eliminate algal growth
    (R.165)
    The use of soap in place of phosphate detergents was considered.
    In the judgment of this witness, soap is
    a suitable cleaning material
    4
    79

    Analysis of several dozen non-phosphate laundry detergents re-
    presented a distinct hazard in the home because of the high alkalinity
    of these
    products.
    Toxic
    household
    products
    can
    express
    their
    toxicity
    when they
    are
    used. without
    adequate
    precautions
    for
    their
    intended
    use
    or when
    grossly
    misused.
    The
    usual victim of
    episodes
    of
    misuse
    is
    the
    young
    child
    between
    one
    and
    four
    whose
    natural
    curiosity
    often
    leads
    him to put into
    his
    mouth
    materials
    that
    no
    adult
    would
    consider palatable.
    Accidental poisoning
    is conceded to he the leading cause of death of
    young children
    in this age group and, of course, non—fatal injuries
    are
    far more common
    than
    fatal
    ones.
    Both
    liquid
    and
    granular
    house-
    hold
    detergents
    are
    involved
    frequently
    in
    such
    accidental
    ingestions.
    According
    to 1969 statistics, approximately
    15
    of all inquiries
    at
    poison centers
    in the United States concerned the accidental ingestion
    of household cleaning and polishing agents of children under five years
    of
    age.
    In
    1969,
    this
    amount
    consisted
    of
    10,978
    reports
    of
    which
    about
    one-third
    involved
    detergents
    ~nd
    chemicals.
    Often,
    the
    results
    are
    nothing
    more
    than
    mild
    sore
    throat
    without
    permanent
    injury
    and
    rarely
    lead to clinically significant illnesses, which only require mild measures
    of first-aid.
    Such reassurances cannot be extended
    to
    cases involving
    high alkalinity detergents which are presently appearing on the American
    market and alerting to the dangerous consequences of these materials
    cannot be expected to prevent injury.
    In the words
    of Dr. Gosselin:
    “There is nothing about the appearance or packaging of
    the newer products
    that would in any way discourage the
    young child from mouthing them,
    in the same way that his
    older brothers
    and sisters may have sampled the phosphate
    detergents when they were toddlers.
    Accordingly,
    we must
    expect that ingestion episodes involving non-phosphate
    detergents will
    soon accumulate in substantial numbers.
    It
    is
    my expectation, based on considerations
    to be presented
    in a few moments,
    that many of these exposures will result
    in serious and even permanent injuries.
    These injuries are
    expected to take the form of chemical burns
    in the mouth,
    esophagus and eyes.
    “Certainly,
    no toddler will be dissuaded by
    a warning
    label
    on
    the
    package.
    In
    any
    case,
    many of
    these containers
    bear no warning.
    Among others one sometimes finds nothing
    more than the bland statement:
    ‘Keep out of reach of children’.
    Thus,
    even the intelligent and alert mother may have little
    basis today
    for recognizing
    that most of the new non—phosphate
    detergents have significantly higher toxicity potential than
    the phosphate preparations with which she has had long experience.
    In March,
    1971, the Food and Drug Administration seized two
    highly alkaline laundry detergent products, because of inade-
    quate cautionary labelling,
    and in June they acted to require
    such labelling on
    25 additional products.
    Since then,
    several
    manufacturers of similar products have added warning statements
    on the package,
    but the practice
    is still far from general.
    4—
    81

    predictions
    are
    based
    on
    experimental
    studies
    in
    dogs
    and
    rabbits
    and
    on
    at
    least
    one
    clinical
    episode
    in-
    volving an automatic dishwasher preparation no more alka-
    line than several phosphate—free products that are now being
    promoted
    as
    home
    laundry
    detergents.
    4.
    Thesepradictions
    are
    supported
    by
    recent
    scattered
    reports
    of
    personal
    injuries
    from
    the
    use
    and
    misuse
    of
    these
    phos-
    phate substitutes.
    The recent death of an infant in Conn-
    ecticut has been ascribed to Mouthing and then inhaling
    the powder of one such product.
    5
    In
    my
    opinion
    these
    products
    should
    carry
    a
    warning
    label
    of the type prescribed under the Federal Hazardous Sub-
    stances
    Act.
    However,
    I
    do
    not
    expect
    such
    cautionary
    labeling
    to
    prevent
    a
    considerable
    number of
    serious
    per-
    sonal
    injuries
    if these products gain general consumer
    acceptance.
    6.
    In my opinion the use of phosphate detergents should not
    be discouragedtntil there is available at least
    one
    alter-
    native product that is established to be safe as well as
    effective.
    The home is still an important part of our
    environment,
    and
    ecological
    principles
    should
    apply
    inside
    as
    well
    as
    outside
    the
    home.”
    John
    C.
    Livengood,
    Product
    Manager of
    Monsanto
    Industrial
    Chem-
    ical
    Company
    testified
    that
    the
    evaluation
    of
    forty-six
    non-phosphate
    detergents
    show
    a
    substantial
    amount
    of
    soditun
    carbonate
    and
    a
    higher
    alkalinity
    than
    phosphate-based
    products
    (R.205).
    Dr.
    Louis
    P.
    Scharpf,
    also
    of
    Monsanto,
    testified
    that
    on
    the
    basis
    of
    experiments
    conducted
    on
    the
    eyes
    of
    rabbits,
    using
    both
    phosphate
    and
    non-phosphate
    detergents
    (R.206)
    irritation
    was
    found
    to be far more severe, long-lasting and deteriorating when caused by
    high
    alkalinity
    non-phosphate
    detergents
    than
    by
    using
    phosphate
    deter-
    gents.
    Where
    high
    alkali
    detergent
    was
    used,
    not
    only
    was
    the
    initial
    injury
    more
    severe,
    but
    the
    period
    of
    healing
    far
    longer.
    Experiments
    conducted
    on
    the
    stomachs
    of
    dogs
    again
    showed
    a
    more
    severe
    and
    longer
    impact where carbonate-based detergents were utilized.
    Dr.
    Edwin
    R.
    Loder,
    from
    DuBois
    Chemicals
    Division,
    CHEZ4ED Cor-
    poration, testified on the subject of institutional and industrial
    detergent products (R.222).
    It is his view that the composition
    of detergents presently containing phosphate should not be altered until
    the use of substitutes for hospital, restaurant
    and
    food processing
    uses
    could
    be
    ascertained.
    Detergents
    are
    needed
    for
    removal
    of
    food
    pathogens and spoilage microorganisms
    for
    restaurants,
    hospitals
    and
    institutional sanitation
    and
    forced modification of present industrial
    and
    institutional
    detergents
    could
    have
    a
    devastating
    effect
    on
    the
    public health aspects of cleaning and sanitizing.
    Approximately twenty
    4—83

    Dr.
    Paul
    F.
    Derr
    appeared
    on
    behalf
    of
    FMC~s Inorganic
    Chemicals Division,
    He
    testified
    to
    the principal causes of eutro~
    phication stating
    that
    in
    his
    judgement,
    detergent
    phosphates
    “are
    not
    and
    never
    have
    been
    a
    cause
    of
    eutrophication,”
    (R,256)
    ,
    It was
    his
    belief
    that
    excessive
    discharges
    of
    carbon-containing
    organic
    wastes have caused both
    the increase in
    alga?
    growth
    and
    simultaneously,
    an
    increase
    contained
    in
    phosphate
    found
    in
    solution.
    Thus,
    increased
    phosphat;e
    concentration.is
    a
    result
    of
    organic
    pollution and eutrophi-
    cation,
    not a cause.
    In his judgement,
    although phosphorus is one
    oi
    some
    i5
    to
    20 nutrients required for growth of all plants, in-
    cluding algae,
    any attempt to control eutrophication by limiting the
    input
    of
    phosphorus
    to
    a lake is doomed to failure;
    first, because
    of the relatively small amount of phosphorus
    needed for growth,
    secondly,
    that
    there
    are
    such
    large
    uncontrollable
    natural
    supplies
    of phosphorus
    that
    it
    will
    never
    be
    feasible
    to
    control
    phosphate
    input
    to
    a
    lake at extremely low levels which would be required to
    inhibit algae growth.
    All
    lakes contain excessive amounts
    of phos-
    phates, most of which is found in the bottom sediments.
    In contrast,
    other
    important
    inorganic
    nutrients
    such
    as
    carbon,
    nitrogen
    and
    potassium
    remain
    totally
    undissoived
    in
    the
    lake
    water,
    If
    phosphate
    input
    to
    a
    lake
    were
    completely
    stopped,
    phosphates
    in bottom sedi-
    ments would merely redissolve to maintain essentially
    a constant
    concentration of phosphate in the
    lake waters for many years.
    Thus,
    an increase or decrease of phosphate
    added to
    a
    lake has little or
    not effect on the growth of algae.
    The primary nutrient required
    by algae
    is
    carbon
    in the
    form of carbon
    dioxide.
    Algae
    is composed
    of between
    50
    to 75
    carbon,
    Bacterial decay of organic matter
    supplies the large amount of carbon dioxide essential to support
    algae growth.
    Bacterial
    decay of sewage leads
    to depletion of dis-
    solved oxygens creating
    the death of fish
    and aquatic animal life
    and
    also major chemical changes which greatly increase the release of
    nutrients,
    including phosphorus from the sedimentation.
    In his judge—
    ment,
    the answer to
    all these problems was adequate sewage treatment,
    including adequate chemical processes.
    Secondary sewage treatment
    permits natural biological processes to convert carbon in both the
    dissolved and suspended organic matter into carbon dioxide gas which
    is expelled into the atmosphere.
    In summary,
    this witness stated that
    “No one has ever shown that removal of phosphates
    from deter~ents
    will have any effect whatsoever on excessive growth of algae in
    lakes.
    Good sewage treatment is the only method for correcting
    the
    problem.”
    Incorporation of chemical precipitation processes removing
    carbon—containing organic wastes greatly increases the removal of
    all nutrients.
    Stacey
    L.
    Daniels appeared on behalf of Dow Chemical Company
    and discussed the technology available for removal of phosphorus
    from sewage and waste water
    (R.275)
    .
    He stated that 30
    to 70
    of
    the phosphorus present in sewage is contributed by detergents.
    The
    process of phosphorus removal must be practiced at waste water treat-
    ment plants even if there is
    no detergent phosphorus contribution
    to
    4
    85

    she
    has
    regarded
    as
    hazardous
    and
    which
    she
    has
    tried
    to
    keep
    out
    of
    reach
    of
    children.
    1ather
    suddenly,
    as
    one
    result
    of
    growing
    alarm
    over
    eutrophication
    problems
    (which
    alaim
    the
    Department
    of
    Health,
    Education
    and Welfare
    shares)
    and
    consequent
    moves
    to
    limit
    or
    ban
    phosphates
    in
    or
    from
    detergents,
    many
    producers
    turned
    to
    alternative
    builders
    and
    some
    marketed
    products
    which
    were
    highly
    alka-
    line
    and
    highly
    caustic.
    Some
    of
    these
    products
    were
    capable
    of
    inflicting
    harm
    on
    the
    unwary
    housewife
    and
    her
    children,
    but
    the
    hazard
    had
    not
    been
    adequately
    drawn
    to
    her
    attention
    before
    the
    press
    conference
    of
    September
    15,
    1971.
    Admittedly,
    some
    manufacturers
    of
    detergents
    had
    complied with
    the
    law.
    But
    some
    had
    not.
    And,
    although
    the
    Food and Drug Administration will continue to test detergent
    products, the
    frequent
    changes
    of
    product
    composition
    for
    the 200 or so detergents
    now
    marketed will
    tax
    the testing
    capacity
    of
    this
    Agency.
    Dr.
    Mitchell
    then
    considers
    the
    consequence
    of
    ingestion
    of
    phosphate-containing
    detergents
    as
    contrasted
    with
    those
    of
    highly
    caustic
    content
    and
    concludes
    that
    change
    in
    labelling
    alone would
    not
    be
    a
    sufficient
    protection,
    particularly
    among
    children
    who
    are in-
    capable
    of
    understanding
    them.
    “The
    causticity
    of a product
    varies
    directly
    as
    the
    pH
    differs from neutrality, which is to say, the
    more
    alkaline
    (or the more acid)
    the material, the stronger will be
    its
    corrosive
    properties.
    An
    important
    factor
    in
    determining
    the
    ultimate
    effect
    is
    the
    reserve
    alkalinity
    which
    is
    an
    indication of the ability of the offending material to
    pre-
    serve its highly alkaline state while reacting with tissue.
    “The physical state of the product may be either liquid
    or solid.
    Liquids,while more readily swallowed and more
    capable of~achingthe stomach, may be somewhat more readily
    diluted, neutralized and flushed away from a surface, such
    as the mouth
    and
    eye, than is a particulate matter.”
    He discusses the detrimental consequences of contact of highly
    caustic alkaline
    material
    on
    the
    skin, eye ,mouth
    ,larynx,
    esophagus,
    stomach
    and
    tracia,
    noting
    that
    a
    child
    would
    not
    have
    the
    ability
    to
    neutralize
    the
    effect
    of
    such
    contact.
    He
    notes
    that
    it
    is
    too
    soot
    to
    enumerate
    the
    accidents
    which
    have
    occurred
    since
    the
    first
    of
    the
    many
    alkali
    products
    in
    detergents
    began
    but
    there
    have
    been
    acci-
    dents
    from
    some
    of
    these
    products.
    Citing
    the
    death
    of
    a
    fif teen—
    month-old
    chili
    who
    aspirated
    one
    of
    these
    products
    and
    a
    St.
    Louis
    child
    who
    suffered
    mouth
    burns,
    he
    discounts
    the
    effects
    of
    cautionary
    labeling
    in
    furnishing
    suitable
    protection
    to
    those
    using
    or
    caning
    in
    contact with
    the
    product.
    He
    states:
    “To
    my
    knowledge,
    there
    has
    been
    very little
    public
    out-
    cry
    against
    the
    hazardous
    nature
    of
    some
    of
    the
    highly
    alka-
    line
    laundry
    products.
    Attention
    has
    been
    focused
    on
    the
    hazard
    posed
    by
    phosphates
    in
    respect
    to
    waters.
    There
    has
    been
    4—57

    a matter of interest
    and concern,
    it cannot be the controlling
    element in imposing
    a state~wideban on a household product.
    It
    appears undisputed that approximately 50
    of the phosphate content
    in municipal sewage is contributed by phosphate detergents and
    proponents suggest that the banning of phosphate detergents may
    enable some small and middle-sized
    communities to meet Board
    effluent standards without undertaking the additional cost of
    phosphate
    removal.
    This conclusion,
    at least with regard to
    middle-sized communities
    is refuted by testimony regarding Peoria
    which would need phosphate removal facilities
    even if phosphate deter-
    gents were banned.
    In any event,
    it would appear that operational
    cost
    br phosphate removal would be reduced by no more
    than 30
    if
    phosphate detergent
    is prohibited.
    Economic savings alone to the
    extent shown do not justify the adoption of
    a ban on phosphate
    detergents.
    We are mandated to control pollution.
    Economic
    reasonableness must be considered when
    a particular pollution con-
    trol measure is proposed.
    However, we do not believe
    the statute
    envisions our imposing
    a product ban
    for purposes
    of affecting
    economies on the local
    level.
    Likewise,
    considerations of safety
    are such
    that we do not feel
    justified in imposing the ban at this
    time until we are satisfied that replacements
    for phosphate do not
    possess toxic or caustic propensities
    creating substantial dangers
    to those using or in the vicinity
    of the product involved.
    By this
    holding, we are making no judgrn~ntthat all phosphate products
    are
    good and all sodium carbonate products
    are evil.
    The record demon-
    strates that it
    is
    the alkalinity and not the element that determines
    the
    danger.
    The evidence demonstrates
    that some phosphate—based
    detergents have high alkalinity with attributes
    of danger while some
    sodium
    carbonate
    products
    appear
    reasonably
    safe.
    However,
    we
    cannot conclude
    that
    on
    the
    basis
    of
    the
    limited
    testimony
    in
    this
    respect that an outright phosphate ban would be in
    the best interests
    of the public health,
    safety and general welfare.
    The record demon-
    strates that many sodium carbonate detergents do have high alkalinity
    with resulting dangers
    from causticity.
    While some evidence was introduced
    on both the safety
    and effectiveness
    of
    a particular non—phosphate detergent,
    these
    findings
    cannot be extrapolated
    to all non—phosphate detergents.
    The
    critical consideration in determining causticity
    is
    the percentage
    of
    alkalinity
    in
    a
    particular
    product
    and not the phosphate or sodium
    carbonate character of its base.
    The record is devoid of evidence
    demonstrating
    the comparative safety of non-phosphate cleaning products
    as
    a class.
    Opposition witnesses
    did offer evidence that on the
    average,
    non—phosphate products did contain
    a higher degree of alka-
    linity and,
    therefore,
    causticity,
    than phosphate—based products.
    The
    evidence did demonstrate
    that non-phosphate detergents with alka-
    line content on the order of 40
    exerted disruptive
    effects
    in mucous
    membranes in the stomach of dogs, rabbits
    and monkeys
    (R,202)
    .
    Other
    studies evaluating forty—six non—phosphate detergents demonstrated
    4
    89

    casually
    proceed
    on
    a
    dearth
    of
    information,
    The
    record
    does
    not
    adequately show
    the
    technical
    feasibility
    of
    the proposed
    ban
    Petitioner offered
    as
    additional areas
    of problem algae growth,
    the
    Illinois River in
    certain
    sectors,
    the Skokie Lagoons
    (R.49,
    370)
    ,
    certain sections
    of
    the banks of
    the
    Mississippi River,
    certain
    shallow,
    low-flow areas
    of
    the Kankakee River
    (R.327)
    ,
    and
    the
    North
    Branch of the Chicago River
    (R.370)
    No water quality data and no
    evidence
    of
    pollution
    problems
    in
    these
    areas
    due
    to
    algae
    growth
    were offered in support of these conclusions~ Absent supporting
    evidence or
    a showing of first-hand knowledge of the water quality
    of these areas,
    the mere conclusion that
    they suffer from nuisance
    algae growth
    is
    legally insufficient
    to
    persuade us
    on this
    issue.
    The proponent failed to establish that phosphorus
    poses
    a pollution problem in any flowing stream in Illinois.
    Beyond
    our previous decisions affecting the Fox River
    and Lake Michigan,
    we remain open to future evidence of nuisance
    algae blooms in other
    waters
    of the state.
    At present,
    the limited evidence of phosphorus
    pollution does not warrant
    a
    remedy
    of
    the
    magnitude
    of
    a
    state—wide
    prohibition on phosphate detergents.
    Nothing we do today restricts those Illinois
    coirurtunities
    along
    the Fox River or which discharge sewage effluent
    to Lake Michigan
    or other municipalities which may be faced with nuisance algae growth
    in their reservoirs
    or lakes
    from
    acting
    to reduce their local pollu-
    tion problems
    and to deal with their need to cut sewage treatment
    costs.
    Indeed,
    the ability
    to impress upon housekeepers
    the need
    to use discretion
    in purchasing detergents would seem considerably
    easier in
    a local area when undertaken by
    a local governing body than
    would
    he the
    case if a statewide ban
    of
    phosphate
    detergents
    were
    imposed.
    We
    do
    not
    rule
    out
    a
    reopening
    of
    this
    issue before the
    Board
    when
    clearer
    evidence
    exists
    of
    a
    threat
    of
    degradation of the
    waters
    of
    Illinois
    from
    phosphorus
    effluent.
    Nor do we restrict the possibility of holding rule—making
    hearings on
    a proposal to ban
    the
    sale
    of
    phosphate
    detergents
    on
    a
    regional basis
    in those
    areas affected by eutrophication,
    when
    the
    evidence
    of
    adequate
    available
    substitutes
    for
    phosphate
    detergents
    is
    more
    convincing.
    The
    record
    in
    this
    case
    demonstrates that
    a
    phosphate
    detergent
    ban
    would
    result
    in
    a further reduction
    of the
    total
    pounds
    of
    phosphorus
    discharged
    to
    a
    receiving
    body
    of
    water
    even when phosphorus is removed at the sewage treatment plant in order
    to meet an effluent standard
    (R.l32)
    .
    Given
    the
    threat
    that
    bottom
    deposits may pose
    a considerable long—term eutrophication problem
    (R.128,
    129)
    ,
    even if an effluent standard is being enforced in an
    area suffering from nuisance algae blooms,
    such
    a regional ban on
    phosphate detergents
    could,
    in
    the
    future, be
    a necessary step to
    reducing the total amount of phosphorus
    discharged
    to
    an
    over—enriched
    body
    of water.
    By our existing regulations, we have endeavored
    to

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