ILLINOIS POLLUTION CONTROL BOARD
    September 25,
    1986
    IN THE MATTER OF:
    )
    )
    PROPOSED AMENDMENTS TO
    )
    35 Iii. Adm. Code 212.443
    )
    R85-33
    By-Product Coke Plants
    )
    ADOPTED RULE.
    FINAL ORDER.
    OPINION AND ORDER OF THE BOARD
    (by J. Theodore Meyer):
    This matter comes before the Board upon
    a December
    19,
    1985
    proposal for regulatory change filed by the Illinois
    Environmental Protection Agency (Agency), Citizens for
    a Better
    Environment
    (CBE) and various steel companies.
    This proposal
    represents
    the proposed settlement arising out of
    a lawsuit filed
    by CBE
    in Federal District Court against the Agency and various
    steel companies for failure to revise Illinois’ coke-battery and
    casthouse rules.
    First Notice was adopted on January 23,
    1986
    and published at
    10 Illinois Register 3731, February
    21,
    1986.
    Hearings were held on March 10 and 11,
    1986,
    in Chicago and
    Granite City, Illinois, respectively.
    On May 8,
    1986,
    the
    Department of Energy and Natural Resources issued a Negative
    Declaration for this proceeding stating that the net economic
    impact of the regulation
    is favorable and the cost of compliance
    are small or are borne entirely by the proponents
    of the
    regulations, and the Economic and Technical Advisory Committee
    concurred with this finding at its June 20,
    1986,
    meeting.
    Second Notice was adopted on June
    11,
    1986, and submitted to the
    Joint Committee on Administrative Rules
    (JCAR).
    JCAR determined
    that no objection would
    be issued to this proposed rulemaking
    provided certain modifications were made
    to the rules
    to enhance
    clarity.
    The Board has agreed to make these modifications and
    they appear in the Final Order.
    The following is
    a brief history
    of
    this
    proceeding.
    In 1979,
    the Agency submitted to USEPA proposed revisions to
    Illinois’
    State Implementation Plan (SIP) which included rules
    governing coke oven charging and pushing operations.
    These rules
    are presently codified at 35 Ill.
    Adin.
    Code 212.443(b) and (c).
    Both of these rules were disapproved for inclusion in
    Illinois’
    SIP by USEPA.
    In connection with this disapproval, CBE sued the
    Administrator of USEPA in federal court
    (CBE v. Thomas,
    No. 80-C-
    0003).
    As
    a result of settlement negotiations arising out of
    that suit,
    the Agency,
    CBE and various steel companies have
    proposed coke oven charging and pushing rules for adoption by the
    Board in lieu of federal promulgation of these rules.
    An
    explanation of these rules follows.
    72-451

    -2-
    The joint regulatory proposal submitted by the Agency, CBE
    and various steel companies includes emission limitations
    as well
    as inspection and compliance procedures for coke oven charging
    and pushing operations.
    (Ri
    p. i2L.~ There are currently three
    coke plants operating in Illinois to which these rules are
    applicable;
    Interlake,
    Inc., LTV Steel and Granite City Steel
    Corporation,
    a Division of National Steel Corporation.
    (Id.)
    Charging Operations
    Section 212.443(b)
    regulates coke oven charging operations
    and is divided into two subsections.
    Section 212.443(b)(i)
    establishes an opacity limitation applicable to fugitive
    emissions during charging operations and Section 212.443(b)(2)
    establishes
    a particulate matter emission limitation and an
    opacity limitation applicable to charging emissions control
    equipment.
    Section 212.443(b)(1)
    Mr. Anton Telford of the Agency testified that approximately
    1200 pounds of steel coke is needed to make one ton of blast
    furnace iron.
    In order to make steel coke,
    the proper blend of
    coals must be introduced
    (i.e., charged)
    into the coke oven
    in
    which the coal is converted to coke by baking the coal at
    approximately 24000
    F in the complete absence of air during
    a
    period of about
    16 hours.
    (Ri pp.
    16-17).
    In general,
    a charge can be defined as constituting the
    transfer of the blended coal into the coke oven from the larry
    car,
    the larry car being the equipment used to bring the coal
    from the coal hopper into
    a position on top of the oven.
    Section
    212.443(b)(1)(A)
    defines
    a charging operation as the time from
    the first introduction of coal into the first charge port of the
    coke oven via the larry car to the replacement of the final
    charge port lid.
    Mr. Telford testified that the addition of
    a
    definition of charging operations to the Illinois regulations
    remedies
    a deficiency which was cited by the USEPA as one of the
    bases for disapproval of the present charging rule.
    (Ri p.
    19).
    The charging operation itself involves
    a precise sequence of
    events called stage charging.
    Stage charging involves the
    charging of a coke oven from one larry car at
    a time while
    simultaneou’sly exhausting the coke oven gas, organic material,
    water and tar released from the coke oven being charged by
    a
    *There were two separate hearings conducted in this proceeding.
    The March
    10,
    1986 hearing transcripts will be designated
    “Ri”
    and the March 11,
    1986 hearing transcript will be designated
    “R2”.
    72-452

    —3—
    steam jet into one or two large pipes which conduct the gases and
    other materials to the by-products plant.
    The total charging
    time is normally four to five minutes, and the leakage of visible
    particulate emissions to the ambient air during this time is
    subject to the charging rule.
    (Ri p.
    17).
    Section 212.443(b)(i)(A) provides that visible particulate
    emissions from coke oven charging operations shall not exceed a
    total of 125 seconds over
    5 consecutive charges with the
    exception that one charge out of any
    20 consecutive charges may
    be deemed
    an uncountable charge.
    Under this procedure,
    a total
    of at least
    6 charges must be observed and recorded and another
    charge may not be disregarded until
    after the 21st charge has
    been completed.
    (Ri.
    p.
    20).
    The Agency states that
    it is their
    belief that this standard constitutes reasonably available
    control technology (RACT) for coke oven charging operations in
    Illinois
    (Ri p.
    21).
    This opinion
    is based on the fact that
    IJSEPA stated
    in its final rulemaking on the present charging rule
    that such
    a standard constitutes
    RACT.
    (Ri pp.
    21-22).
    Section 212.443(b)(1)(B) establishes the procedures for
    determining compliance with the visible emissions limitation for
    charging operations.
    Mr. Cezary Krzynowski of the Agency
    testified that the addition of procedures for determining
    compliance with the visible emissions limitation remedies another
    deficiency which was cited by the USEPA as one of the bases for
    its disapproval of the present charging rule.
    (RI p. 46).
    The inspection procedures of Section 212.443(b)(1)(B)
    require that
    a qualified observer who is certified to read
    visible emissions pursuant to 35 Ill. Adm. Code 230.Appendix A
    (40 CFR 60, Appendix A, Method
    9) position himself on the topside
    of the coke oven battery with
    a cumulative stopwatch so that an
    unobstructed view can be obtained of the charging larry car and
    charging ports and that the visible emissions
    from these sources
    can be timed during a charge.
    The qualified observer then
    determines and records
    the total number of seconds of visible
    emissions timed for that oven and battery,
    including the start
    and stop time for the charging operation.
    This procedure
    continues for five consecutive charges unless the observer deems
    one an uncountable charge
    in which case the procedure would
    continue until at least five consecutive charges are observed.
    (Ri pp. 46—47).
    212.443(b) (2)
    Section 212.443(b)(2) establishes standards applicable to
    emissions from charging emissions control equipment.
    Mr. Teiford
    testified that the Agency is only aware of one coke plant in
    Illinois which uses control equipment to capture charging
    emissions and that facility
    is operated by LTV Steel; LTV’s
    charging emissions control equipment operates by exhausting the
    72-453

    —4—
    coke oven through the larry car, the larry car fugitive gas
    igniter and subsequently to a stationary venturi scrubber.
    Section 212.443(b)(2)(A) provides that
    a mass emission
    limitation oE 0.020 grains per dry standard cubic foot be
    applicable
    to particulate matter emissions from charging
    emissions control equipment.
    Compliance with this mass emission
    limitation shall be determined pursuant to the procedures
    set out
    in
    35 Ill. Adm. Code 230, Appendix A, Methods
    1 through
    5 which
    are the procedures specified for stack testing.
    Section 212.443(b)(2)(B) provides that the opacity of
    emissions from charging emissions control equipment shall not
    exceed an average of
    20,
    averaging the total number of readings
    taken at
    15-second intervals during a charge.
    Compliance with
    this limitation shall be determined pursuant to 35 Iii. Adm. Code
    230, Appendix A
    (40 CFR 60, Appendix A, Method 9) except for the
    number of
    readings or observations required.
    Mr. Krzynowski
    testified that this exception for the number of readings required
    refers to the requirement
    in Section 2.4 of Method
    9 that a
    minimum of 24 observations be made and that opacity be determined
    as an average of 24 consecutive observations recorded at 15-
    second intervals.
    This exception is necessitated by the fact
    that
    a charge generally lasts less than 6 minutes and the intent
    of the regulation is that compliance with the 20
    opacity
    standard be determined as an average of the total number of
    readings taken at 15-second intervals over the duration of
    a
    charge.
    (Ri. pp. 48—49).
    Lastly,
    Section 2i2.443(b)(2)(C) requires that the opacity
    readings from the charging emissions control equipment be taken
    concurrently with the observations of fugitive particulate
    matter.
    Two qualified observers
    shall take these readings.
    Pushing Operations
    Section 212.443(c)
    regulates coke oven pushing operations
    and is divided into two subsections.
    Section 212.443(c)(1)
    establishes an opacity limitation applicable to fugitive
    emissions during pushing operations and Section 212.443(c) (2)
    establishes
    a particulate matter and an opacity limitation
    applicable to pushing emissions control equipment.
    Section 212.443(c)(1)
    Mr. Teiford also described what constitutes
    a “push.”
    He
    testified that after the coal has cooked sufficiently,
    the end
    doors on the coke ovens are removed and the cooked coal
    is pushed
    out of the oven by
    a pushing machine.
    The cooked coal which is
    now coke exits the coke oven on the opposite side from the
    pushing machine through a piece of duct called
    a coke guide which
    interfaces with the oven on one side and the coke receiver car on
    72-454

    —5-
    the other
    side and falls into
    a hooded receiver car.
    After the
    coke falls into the receiver car,
    which is on
    a track,
    the car
    moves down to the quench tower or quench device at which the coke
    is cooled with water to reduce its temperature from 2,000°Fto
    approximately 400°F.
    A push takes about one and a half minutes
    from the time
    the coke falls into the receiver or until the car
    enters the quench tower or quench device.
    (Ri pp.
    24-25).
    Section 212.443(c)(1)(A) provides that emissions of fugitive
    particulate matter from pushing operations
    shall not exceed an
    average of 20
    opacity for four consecutive pushes considering
    the highest average of six consecutive readings
    in each push.
    Mr. Teiford testified that this procedure allows
    a brief
    surge of
    visible particulate emissions during the pushing of the coke into
    the receiver car to be mitigated by less emissions during the
    movement of
    the receiver car to the quenching tower or device.
    (Ri pp. 26-27).
    Mr. Telford also testified that all of the coke
    facilities in Illinois can meet this standard and that this
    standard constitutes RACT.
    He based this latter conclusion on
    the fact that USEPA stated
    in its final rulemaking on the Indiana
    Steel State Implementation Plan that such an opacity standard
    constitutes
    RACT.
    (Ri p.
    27).
    Section 212.443(c)(1)(B)
    sets forth the procedures to be
    followed by the qualified observer when conducting opacity
    readings of fugitive emissions during pushing operations.
    The
    procedures account for the fact that opacity readings are taken
    over the duration
    of
    a push including readings as the receiving
    car travels
    to the quench tower or device by requiring that the
    qualified observer position himself so that the entire pushing
    operation can be observed.
    The procedures also require that
    emissions from the receiving car and associated equipment,
    the
    coke oven and the stand pipe on the coke side of the oven being
    pushed be read.
    (Ri p.
    52).
    The observation procedures are to
    be conducted pursuant to (40 CFR
    60, Appendix A, Method 9) except
    that Section 2.5 for data reduction shall be used.
    This
    exception to Method 9 procedures is necessary to account for the
    fact that a push lasts less than six minutes.
    (Ri
    p. 53).
    Section 212.443(c)(2)
    Section 212.443(c)(2) establishes standards applicable to
    emissions from pushing emissions control equipment.
    Mr. Telford
    testified that two types
    of pushing emissions control systems are
    in use in Illinois,
    a mobile hood receiver connected to a
    stationary emissions collector and
    a mobile hooded receiver car
    equipped with a mobile emissions collector.
    (Ri p.
    33).
    Section 212.443 (c)(2)(A) establishes a mass emission
    limitations of 0.040 pounds
    of particulate matter per ton of coke
    pushed.
    Mr. Telford testified that all the coke facilities in
    Illinois are capable of meeting this standard and such standard
    72-455

    —6-
    constitutes RACT.
    (Ri pp. 35-36).
    Be based this latter
    conclusion on the fact that for those systems using mobile
    collectors, the standard is identical to the lowest achievable
    etnission rate limit currently applicable to
    such
    a system.
    )tlso,
    for those systems using stationary collectors,
    the Agency
    believes that 0.040 pounds of particulates per ton of coke pushed
    constitutes
    an appropriate RACT limitation since 0.030 pounds of
    particulate per ton of coke pushed has been determined to be the
    best available control technology for such systems.
    (Ri p.
    36).
    Section 212.443(c)(2)(fl) establishes
    an opacity limitation
    for the pushing emissions control system.
    The rule states that
    the opacity from such control equipment shall not exceed 20.
    For
    a push of less than six minutes, the number of 15-second
    readings
    shall
    be averaged.
    Again, Method
    9 of 40 CFR 60,
    Appendix A governs the observation procedures and Section 2.5 for
    data reduction shall not apply for pushes less than six minutes
    in duration.
    As
    a final note, on August 15,
    1986, the Board received
    JCAR’s formal certification that no objection will be issued on
    this rulemaking provided that the Board make some non-substantive
    modifications to the rules
    as submitted for Second Notice.
    The
    modifications suggested by JCAR relate to the opacity reading
    procedure and the Board has agreed to clarify that all observers
    conducting opacity reading be qualified pursuant to 40 CFR 60,
    ~ppendix P~,Method
    9
    (35 III. ~dm. Code 230J~ppendixM.
    ORDER
    The Board hereby adopts the following amendments to 35
    Iii.
    Adm. Code 212.443:
    TITLE
    35:
    ENVIRONMENTAL PROTECTION
    SUBTITLE
    B:
    AIR POLLUTION
    CHAPTER
    I:
    POLLUTION CONTROL BOARD
    SUBCHAPTER
    c:
    EMISSION STANDARDS AND LIMITATIONS
    FOR STATIONARY SOURCES
    PART 212
    VISUAL AND PARTICULATE MATTER EMISSIONS
    Section 212.443
    By-Product Coke Plants
    a)
    Subpart
    B shall not apply
    to by-product coke plants.
    b)
    Charging:
    No person
    sl’tall
    cause
    or allow ~he em~ss~on
    e? vtsi~lepe~e~e
    ~
    ?~om e~’je~ok~
    ~‘#a~
    e1~argingepera~ionw1’~eneoal ~s ~e~ng eharged~exeept
    o
    ~ot~l e~no ~,torethan ~
    seeonds over
    5
    72-456

    —7—
    eonseeu~ivesoven ehargesT or in the ease o?
    existing
    ?ive meter eeke bo~erieshaving three ebarging parts~
    ?or
    a total e~r~omere than 2~ seconds ever
    5
    censeetitive even ehargesT
    1)
    Uncaptured Emissions
    A)
    No person
    shall cause or allow the emission of
    visible particulate matter from any coke oven
    charging operation, from the introduction of
    coal into the first charge port,
    as indicated
    by the first mechanical movement of the coal
    feeding mechanism on the larry car,
    to the
    replacement of the final charge port lid for
    more than
    a total of
    125 seconds over
    5
    consecutive charges; provided however that
    1
    charge out of any 20 consecutive charges may
    be deemed an uncountable charge
    at the option
    of the operator.
    B)
    Compliance with the limitation set forth in
    subsection
    (A) shall be determined in the
    following manner:
    i)
    Observation of charging emissions shall
    be made from any point or points on the
    topside
    of
    a coke oven battery from i~hich
    a qualified observer can obtain an
    unobstructed view of the charging
    operation
    ii)
    The qualified observer shall time the
    visible emissions with
    a stopwatch while
    observing the charging operation.
    Only
    emissions from the charge port and any
    part
    of the larry car shall be timed.
    The observation shall commence as soon as
    coal is introduced into the first charge
    port
    as indicated by the first mechanical
    movement of the coal feeding mechanism on
    the larry car and shall terminate when
    the last charge port lid has been
    replaced.
    Simultaneous emissions from
    more than one emission point shall be
    timed and recorded
    as one emission and
    shall not be added individually to the
    total time.
    iii) The qualified observer shall determine
    and record the total number of seconds
    that charging emissions are visible
    during the charging of coal to the coke
    oven.
    72-457

    -8-
    iv)
    For each charge observed,
    the qualified
    observer shall record the total number of
    seconds of visible emissions, the clock
    time for the initiation and completion of
    the chargin~~peration and the battery
    identification and oven number.
    v)
    The qualified observer shall not record
    any emissions observed after all charji~g
    port lids have been firmly seated
    ~ollow±ng removal of the larry car, such
    as emissions occurring when a lid has
    been temporarily removed to permit
    spilled coal to be swept into the oven.
    Vi)
    In the event that observations from a
    charge are interrupted the data from the
    charge
    shall be invalidated and the
    qualified observer shall note on his
    observation sheet the reason for
    invalidating the data.
    The qualified
    observer shall then resume observation of
    the next consecutive charge or charges
    and continue until
    a set of five charges
    has been recorded.
    Charges immediately
    preceding and following interrupted
    observations shall
    be considered
    consecutive.
    2)
    Emissions from Control Equipment
    A)
    Emissions of particulate matter from control
    equipment used to capture emissions during
    charging shall not exceed 0.046 gm/dscm (0.020
    gr/dscf).
    Compliance shall
    be determined in
    accordance with the procedures set forth in
    35
    Ill. Adm. Code 230.Appendix
    A
    (40 CFR 60,
    Appendix A, Methods 1-5).
    B)
    The opacity of emissions from control
    equipment shall not exceed an average of 20,
    averaging the total number of readings
    taken.
    Opacity readings shall be taken at 15-
    second intervals from the introduction of coal
    into the first charge port as
    indicated by the
    first mechanical movement of the coal feeding
    mechanism on the larry car to the replacement
    of the final charge port lid.
    Compliance
    shall
    be determined
    in accordance with
    35 Ill.
    Adm. Code 230.Appendix A
    (40
    CFR 60, Appendix
    A,
    Method 9), except for the number of
    readings required.
    72-458

    —9-
    C)
    Opacity readings of emissions from control
    equipment shall
    be taken concurrently with
    observations of fugitive particulate matter.
    Two_qualified observers shall be required.
    3)
    qualified observers referenced
    in subsection
    (b)
    shall
    be certified pursuant to 35
    Iii.
    Adtn. Code
    230.Appendix A
    (40 CFR 60, Appendix A, Method 9).
    c)
    Pushing:
    All coke ?aeilities shall be equipped with
    pushing systems with pa
    ulate
    eemtroi equipment which
    shall be designed
    to capture at least 90 o?
    all
    particulate emissions ?rom pushing operationsT
    The
    particulate control equipment shall be operated end
    maintained in
    a manner to achieve the design
    e??ieieney~ 1?
    a stationery hood system is usedT the
    particulate emissions ?rom the outlet
    e?
    ~eid
    pertieulate control equipment shall net exceed ~0
    mg/dsem ~9~03 gr,edse?.~7 1?
    a closely hooded mobile
    system is used in eenneetion with the operation o?
    an
    existing coke even battery with the emissions exhausted
    directly to the particulate control equipment~the
    particulate emissions ?rem the outlet e?
    said
    particulate control equipment shall net exceed
    140
    mg’dsem ~0~96 gri’dse?4~
    1)
    Uncaptured Emissions
    A)
    Emissions of fugitive particulate matter from
    pushing operations shall not exceed an average
    of 20
    opacity for
    4 consecutive pushes
    considerin~gthe highest
    average of six
    consecutive readings in each push.
    Opacity
    readings shall be taken at 15-second
    intervals, beginning from the time the coke
    falls into the receiving car or is first
    visible as it emerges from the coke guide
    whichever occurs earlier, until the receiving
    car enters the guench tower or quenching
    device.
    For
    a push of less than
    90 seconds
    duration,
    the actual number of 15-second
    readings shall
    be averaged.
    B)
    Opacity readings shall be taken by a qualified
    observer located in
    a position where the oven
    being pushed,
    the coke receiving car and the
    path to the quench tower are visible.
    The
    opacity shall
    be read as the emissions rise
    and_clear_the top of the coke battery gas
    mains.
    The qualified observer shall record
    opacity readings of emissions originating at
    72-459

    -10-
    the receiving car and associated equipment and
    the coke oven, including the standpipe on the
    coke side of the oven being pushed.
    Opacity
    readings shall be taken
    in accordance with the
    procedures
    set forth in
    35
    Ill. Adm. Code 230.
    Appendix
    A
    (40 CFR 60, Appendix A, Method 9),
    except that Section 2.5 for data reduction
    shall not be used.
    The qualified observer
    referenced
    in this subsection
    shall be
    certified pursuant to
    35 Ill. Adm. Code
    230.Appendix A
    (40 CFR 60, Appendix A, Method
    9).
    2)
    Emissions from Control Equipment
    A)
    The~particulateemissions from control
    equipment used
    to control emissions during
    pushing operations
    shall not exceed 0.040
    pounds per ton of coke pushed.
    Compliance
    shall be determined
    in accordance with the
    procedures
    set forth in
    35 Ill.
    Adm. Code 230.
    Appendix
    A
    (40 CFR 60, Appendix A, Methods
    1-
    5) and shall be based on an arithmetic average
    of three runs
    (stack tests) and the
    calculations shall
    be based on the duration of
    a push as defined
    in subsection (c)(1)(A).
    B)
    The opacity of emissions from control
    equipment used
    to control emissions during
    pushing operations
    shall not exceed 20.
    For
    a push
    of less than six minutes duration, the
    actual number of 15-second readings taken
    shall be averaged.
    Compliance shall be
    determined
    in accordance with 35 Ill. Adm.
    Code 230.Appendix
    A
    (40 CFR 60, Appendix A,
    Method
    9),
    except that Section 2.5 for data
    reduction shall not be used for pushes of less
    than six minutes duration.
    d)
    Coke Oven Doors:
    1)
    No person shall
    cause or allow visible emissions
    from more than 10
    of all coke oven doors at any
    time.
    Compliance shall be determined by
    a one pass
    observation of all coke oven doors on any one
    battery.
    2)
    No person shall cause or allow the operation of
    a
    coke oven unless there is on the plant premises at
    all times
    an adequate inventory of spare coke oven
    doors and seals and unless there is
    a readily
    available coke over door repair facility.
    72-460

    —11—
    e)
    Coke Oven Lids:
    No person shall cause or allow visible
    emission from more than 5
    of all coke oven lids at any
    time.
    Compliance shall be determined by
    a one pass
    observation of all coke oven lids.
    f)
    Coke Oven Offtake Piping:
    No person shall cause or
    allow visible emissions from more than 10
    of all coke
    oven offtake piping at any time.
    Compliance shall
    be
    determined by a one pass observation of all coke oven
    ofttake piping.
    g)
    Coke Oven Combustion Stack:
    No person shall
    cause or
    allow the emission of particulate matter from
    a coke
    oven combustion stack to exceed
    110 mg/dscm (0.05
    gr/dscf).
    h)
    Quenching:
    All coke oven quench towers shall be
    equipped with grit arrestors or equipment of comparable
    effectiveness.
    The make-up water shall not directly
    include coke by-product plant effluent.
    Total dissolved
    solids concentrations in the make-up water shall not
    exceed 1500 mg/i.
    Provided however that the limitations
    on the quality of quench make-up water shall not apply
    where the operator employs an equivalent method of
    control as determined by the Agency.
    i)
    Work Rules:
    No person shall cause or allow the
    operation of
    a by-product coke plant except in
    accordance with operating and maintenance work
    rules
    approved by the Agency.
    IT IS SO ORDERED.
    I, Dorothy M. Cunn,
    Clerk of the Illinois Pollution Control
    Board, hereby certify that the abc~weOpinion and Order was
    adopted on the
    ~7~Z
    day of ~
    ,
    1986 by a vote
    of
    ~-O
    ~___
    Dorothy
    M. Gun4~,Clerk
    Illinois Pollution Control Board
    72-461

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