TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE G: WASTE DISPOSAL
CHAPTER I: POLLUTION CONTROL BOARD
SUBCHAPTER f: RISK BASED CLEANUP OBJECTIVES
PART 742
TIERED APPROACH TO CORRECTIVE ACTION OBJECTIVES
SUBPART A: INTRODUCTION
| Section |
| 742.100 | Intent and Purpose |
| 742.105 | Applicability |
| 742.110 | Overview of Tiered Approach |
| 742.115 | Key Elements |
| 742.120 | Site Characterization |
| SUBPART B: GENERAL | |
Section
| 742.200 | Definitions |
| 742.205 | Severability |
| 742.210 | Incorporations by Reference |
| 742.215 | Determination of Soil Attenuation Capacity |
| 742.220 | Determination of Soil Saturation Limit |
| 742.222 | Determination of Soil Vapor Saturation Limit |
| 742.225 | Demonstration of Compliance with Soil and Groundwater Remediation Objectives |
| 742.227 | Demonstration of Compliance with Soil Gas Remediation Objectives for the Outdoor and Indoor Inhalation Exposure Routes |
| 742.230 | Agency Review and Approval |
SUBPART C: EXPOSURE ROUTE EVALUATIONS
Section
| 742.300 | Exclusion of Exposure Route |
| 742.305 | Contaminant Source and Free Product Determination |
| 742.310 | Outdoor Inhalation Exposure Route |
| 742.312 | Indoor Inhalation Exposure Route |
| 742.315 | Soil Ingestion Exposure Route |
| 742.320 | Groundwater Ingestion Exposure Route |
SUBPART D: DETERMINING AREA BACKGROUND
Section
| 742.400 | Area Background |
| 742.405 | Determination of Area Background for Soil |
| 742.410 | Determination of Area Background for Groundwater |
| 742.415 | Use of Area Background Concentrations |
SUBPART E: TIER 1 EVALUATION
Section 742.500 Tier 1 Evaluation Overview 742.505 Tier 1 Soil, Soil Gas and Groundwater Remediation Objectives 742.510 Tier 1 Remediation Objectives Tables for the Ingestion, Outdoor Inhalation, and Soil Component of the Groundwater Ingestion Exposure Routes 742.515 Tier 1 Remediation Objectives Tables for the Indoor Inhalation Exposure Route
SUBPART F: TIER 2 GENERAL EVALUATION
Section 742.600 Tier 2 Evaluation Overview 742.605 Land Use 742.610 Chemical and Site Properties
SUBPART G: TIER 2 SOIL AND SOIL GAS EVALUATION
Section
742.700 Tier 2 Soil and Soil Gas Evaluation Overview 742.705 Parameters for Soil Remediation Objective Equations 742.710 SSL Soil Equations 742.712 SSL Soil Gas Equation for the Outdoor Inhalation Exposure Route 742.715 RBCA Soil Equations 742.717 J&E Soil Gas Equations for the Indoor Inhalation Exposure Route 742.720 Chemicals with Cumulative Noncarcinogenic Effects
SUBPART H: TIER 2 GROUNDWATER EVALUATION
Section 742.800 Tier 2 Groundwater Evaluation Overview 742.805 Tier 2 Groundwater Remediation Objectives 742.810 RBCA Calculations to Predict Impacts from Remaining Groundwater Contamination 742.812 J&E Groundwater Equations for the Indoor Inhalation Exposure Route
SUBPART I: TIER 3 EVALUATION
ection 742.900 Tier 3 Evaluation Overview 742.905 Modifications of Parameters 742.910 Alternative Models 742.915 Formal Risk Assessments 742.920 Impractical Remediation 742.925 Exposure Routes 742.930 Derivation of Toxicological Data 742.935 Indoor Inhalation Exposure Route
SUBPART J: INSTITUTIONAL CONTROLS
Section
742.1000 Institutional Controls 742.1005 No Further Remediation Letters 742.1010 Environmental Land Use Controls 742.1012 Federally Owned Property: Land Use Control Memoranda of Agreement 742.1015 Ordinances 742.1020 Highway Authority Agreements and Highway Authority Agreement Memoranda of Agreement
SUBPART K: ENGINEERED BARRIERS
Section
742.1100 Engineered Barriers 742.1105 Engineered Barrier Requirements
Section 742.1200 Building Control Technologies 742.1205 Building Control Technology Proposals 742.1210 Building Control Technology Requirements
742.APPENDIX A General Developing Soil Remediation Objectives Under the Tiered Approach
742.ILLUSTRATION B Developing Groundwater Remediation Objectives Under the Tiered Approach 742.TABLE A Soil Saturation Limits (Csat) for Chemicals Whose Melting Point is Less Than 30° C 742.TABLE B Tolerance Factor (K) 742.TABLE C Coefficients {AN-I+1} for W Test of Normality, for N=2(1)50 742.TABLE D Percentage Points of the W Test for n=3(1)50 742.TABLE E Similar-Acting Noncarcinogenic Chemicals 742.TABLE F Similar-Acting Carcinogenic Chemicals 742.TABLE G Concentrations of Inorganic Chemicals in Background Soils
742.TABLE H Concentrations of Polynuclear Aromatic Hydrocarbon Chemicals in Background Soils 742.TABLE I Chemicals Whose Tier 1 Class I Groundwater Remediation Objective Exceeds the 1 in 1,000,000 Cancer Risk Concentration 742.TABLE J List of TACO Volatile Chemicals for the Indoor Inhalation Exposure Route 742.TABLE K Soil Vapor Saturation Limits (Cvsat) for Volatile Chemicals 742.APPENDIX B Tier 1 Illustrations and Tables
742.TABLE A Tier 1 Soil Remediation Objectives for Residential Properties 742.TABLE B Tier 1 Soil Remediation Objectives for Industrial/Commercial Properties 742.TABLE C pH Specific Soil Remediation Objectives for Inorganics and Ionizing Organics for the Soil Component of the Groundwater Ingestion Route (Class I Groundwater) 742.TABLE D pH Specific Soil Remediation Objectives for Inorganics and Ionizing Organics for the Soil Component of the Groundwater Ingestion Route (Class II Groundwater) 742.TABLE E Tier 1 Groundwater Remediation Objectives for the Groundwater Component of the Groundwater Ingestion Route 742.TABLE F Values Used to Calculate the Tier 1 Soil Remediation Objectives for the Soil Component of the Groundwater Ingestion Route 742.TABLE G Soil Gas Remediation Objectives for the Outdoor Inhalation Exposure Route 742.TABLE H Tier 1 Soil Gas and Groundwater Remediation Objectives for the Indoor Inhalation Exposure Route – Diffusion and Advection 742.TABLE I Tier 1 Soil Gas and Groundwater Remediation Objectives for the Indoor Inhalation Exposure Route – Diffusion Only
742.APPENDIX C Tier 2 Illustrations and Tables Tier 2 Evaluation for Soil 742.ILLUSTRATION B Tier 2 Evaluation for Groundwater 742.ILLUSTRATION C US Department of Agriculture Soil Texture Classification 742.TABLE A SSL Equations 742.TABLE B SSL Parameters 742.TABLE C RBCA Equations 742.TABLE D RBCA Parameters 742.TABLE E Default Physical and Chemical Parameters 742.TABLE F Methods for Determining Physical Soil Parameters 742.TABLE G Error Function (erf) 742.TABLE H Q/C Values by Source Area 742.TABLE I Koc Values for Ionizing Organics as a Function of pH (cm3/g or L/kg or cm3water/gsoil) 742.TABLE J Values to be Substituted for kd or ks when Evaluating Inorganics as a Function of pH (cm3/g or L/kg or cm3water/gsoil) 742.TABLE K Parameter Estimates for Calculating Water-Filled Soil Porosity (q w) 742.TABLE L J&E Equations 742.TABLE M J&E Parameters 742.APPENDIX D Highway Authority Agreement 742.APPENDIX E Highway Authority Agreement Memorandum of Agreement 742.APPENDIX F Environmental Land Use Control 742.APPENDIX G Model Ordinance 742.APPENDIX H Memorandum of Understanding AUTHORITY: Implementing Sections 22.4, 22.12, Title XVI, and Title XVII and authorized by Sections 27 and 58.5 of the Environmental Protection Act [415 ILCS 5/22.4, 22.12, 27, and 58.5 and Title XVI and Title XVII]. SOURCE: Adopted in R97-12(A) at 21 Ill. Reg. 7942, effective July 1, 1997; amended in R97-12(B) at 21 Ill. Reg. 16391, effective December 8, 1997; amended in R97-12(C) at 22 Ill. Reg. 10847, effective June 8, 1998; amended in R00-19(A) at 25 Ill. Reg. 651, effective January 6, 2001; amended in R00-19(B) at 25 Ill. Reg. 10374, effective August 15, 2001; amended in R00-19(C) at 26 Ill. Reg. 2683, effective February 5, 2002; amended in R06-10 at 31 Ill. Reg. 4063, effective February 23, 2007; amended in R11-09 at 37 Ill. Reg. 7506, effective July 15, 2013. NOTE: Italics indicates statutory language. SUBPART A: INTRODUCTION
Section 742.100 Intent and Purpose
a) This Part sets forth procedures for evaluating the risk to human health posed by environmental conditions and developing remediation objectives that achieve acceptable risk levels.
b) The purpose of these procedures is to provide for the adequate protection of human health and the environment based on the risks to human health posed by environmental conditions while incorporating site related information.
Section 742.105 Applicability
a) Any person, including a person required to perform an investigation pursuant to the Illinois Environmental Protection Act [415 ILCS 5] (Act), may elect to proceed under this Part to the extent allowed by State or federal law and regulations and the provisions of this Part and subject to the exceptions listed in subsection (h) below. A person proceeding under this Part may do so to the extent such actions are consistent with the requirements of the program under which site remediation is being addressed.
b) This Part is to be used in conjunction with the procedures and requirements applicable to the following programs:
1) Leaking Underground Storage Tanks (35 Ill. Adm. Code 731 and 734);
2) Site Remediation Program (35 Ill. Adm. Code 740); and
3) RCRA Part B Permits and Closure Plans (35 Ill. Adm. Code 724 and 725).
c) The procedures in this Part may not be used if their use would delay response action to address imminent and substantial threats to human health and the environment. This Part may only be used after actions to address such threats have been completed.
d) This Part may be used to develop remediation objectives to protect surface waters, sediments or ecological concerns, when consistent with the regulations of other programs, and as approved by the Agency.
e) A no further remediation determination issued by the Agency prior to July 1, 1997 pursuant to Section 4(y) of the Act or one of the programs listed in subsection (b) of this Section that approves completion of remedial action relative to a release shall remain in effect in accordance with the terms of that determination.
f) Site specific groundwater remediation objectives determined under this Part for contaminants of concern may exceed the groundwater quality standards established pursuant to the rules promulgated under the Illinois Groundwater Protection Act [415 ILCS 55] as long as done in accordance with Sections 742.805 and 742.900(c)(9). (See 415 ILCS 5/58.5(d)(4))
g) Where contaminants of concern include polychlorinated byphenyls (PCBs), a person may need to evaluate the applicability of regulations adopted under the Toxic Substances Control Act (15 USC 2601).
h) This Part may not be used in lieu of the procedures and requirements applicable to landfills under 35 Ill. Adm. Code 807 or 811 through 814.
i) An evaluation of the indoor inhalation exposure route under this Part addresses the potential of contaminants present in soil gas or groundwater to reach human receptors within buildings. This Part does not address the remediation or mitigation of any contamination within a building from a source other than soil gas or groundwater, such as the building structure itself and products within the building.
(Source: Amended at 37 Ill. Reg. 7506, effective July 15, 2013)
Section 742.110 Overview of Tiered Approach
a) This Part presents an approach for developing remediation objectives (see Appendix A, Illustrations A and B) that include an option for exclusion of pathways from further consideration, use of area background concentrations as remediation objectives and three tiers for selecting applicable remediation objectives. An understanding of human exposure routes is necessary to properly conduct an evaluation under this approach. In some cases, applicable human exposure routes can be excluded from further consideration prior to any tier evaluation. Selecting which tier or combination of tiers to be used to develop remediation objectives is dependent on the site-specific conditions and remediation goals. Tier 1 evaluations and Tier 2 evaluations are not prerequisites to conducting Tier 3 evaluations.
b) A Tier 1 evaluation compares the concentration of contaminants detected at a site to the corresponding remediation objectives for residential and industrial/commercial properties contained in Appendix B, Tables A, B, C, D, E, G, H and I. To complete a Tier 1 evaluation, the extent and concentrations of the contaminants of concern, the groundwater class, the land use classification, human exposure routes at the site, and, if appropriate, soil pH, must be known. If remediation objectives are developed based on industrial/commercial property use, then institutional controls under Subpart J are required. For the indoor inhalation exposure route, institutional controls under Subpart J are required to use remediation objectives in Appendix B, Table H or Table I.
c) A Tier 2 evaluation uses the risk based equations from the Soil Screening Level (SSL) model, Risk Based Corrective Action (RBCA) model and modified Johnson and Ettinger (J&E) model documents listed in Appendix C, Tables A, C and L, respectively. In addition to the information that is required for a Tier 1 evaluation, site-specific information is used to calculate Tier 2 remediation objectives. As in Tier 1, Tier 2 evaluates residential and industrial/commercial properties only. If remediation objectives are developed based on industrial/commercial property use, then institutional controls under Subpart J are required. For the indoor inhalation exposure route, institutional controls under Subpart J are required to develop remediation objectives pursuant to Appendix C, Table L.
d) A Tier 3 evaluation allows alternative parameters and factors, not available under a Tier 1 or Tier 2 evaluation, to be considered when developing remediation objectives. Remediation objectives developed for conservation and agricultural properties can only be developed under Tier 3.
e) Remediation objectives may be developed using area background concentrations or any of the three tiers if the evaluation is conducted in accordance with applicable requirements in Subparts D through I. When contaminant concentrations do not exceed remediation objectives developed under one of the tiers or area background procedures under Subpart D, further evaluation under any of the other tiers is not required.
(Source: Amended at 37 Ill. Reg. 7506, effective July 15, 2013)
Section 742.115 Key Elements
To develop remediation objectives under this Part, the following key elements shall be addressed.
a) Exposure Routes
1) This Part identifies the following as potential exposure routes to be addressed:
A) Outdoor inhalation;
B) Indoor inhalation;
C) Soil ingestion;
D) Groundwater ingestion; and
E) Dermal contact with soil.
2) The evaluation of exposure routes under subsections (a)(1)(A), (a)(1)(B), (a)(1)(C) and (a)(1)(D) is required for all sites when developing remediation objectives or excluding exposure pathways. Evaluation of the dermal contact exposure route is required for use of RBCA equations in Appendix C, Table C or use of formal risk assessment under Section 742.915.
3) The groundwater ingestion exposure route is comprised of two components:
A) Migration from soil to groundwater (soil component); and
B) Direct ingestion of groundwater (groundwater component).
4) The outdoor inhalation route is comprised of two components:
A) Migration from soil through soil gas to outdoor air (soil component); and
B) Migration from soil gas to outdoor air (soil gas component).
5) The indoor inhalation exposure route is comprised of two components:
A) Migration from soil gas to indoor air (soil gas component); and
B) Migration from groundwater through soil gas to indoor air (groundwater component).
b) Contaminants of Concern
The contaminants of concern to be remediated depend on the following:
1) The materials and wastes managed at the site;
2) The extent of the no further remediation determination being requested from the Agency pursuant to a specific program; and
3) The requirements applicable to the specific program, as listed at Section 742.105(b) under which the remediation is being performed.
c) Land Use
The present and post-remediation uses of the site where exposures may occur shall be evaluated. The land use of a site, or portion thereof, shall be classified as one of the following:
1) Residential property;
2) Conservation property;
3) Agricultural property; or
4) Industrial/commercial property.
d) Environmental Media of Concern
This Part provides procedures for developing remediation objectives for the following environmental media:
1) Soil;
2) Soil gas;
3) Groundwater.
(Source: Amended at 37 Ill. Reg. 7506, effective July 15, 2013)
Section 742.120 Site Characterization
Characterization of the extent and concentrations of contamination at a site shall be performed before beginning development of remediation objectives. The actual steps and methods taken to characterize a site are determined by the requirements applicable to the specific program under which site remediation is being addressed.
SUBPART B: GENERAL
Section 742.200 Definitions
Except as stated in this Section, or unless a different meaning of a word or term is clear from the context, the definition of words or terms in this Part shall be the same as that applied to the same words or terms in the Act.
“Act” means the Illinois Environmental Protection Act [415 ILCS 5].
“ADL” means Acceptable Detection Limit, which is the detectable concentration of a substance that is equal to the lowest appropriate Practical Quantitation Limit (PQL) as defined in this Section.
“Agency” means the Illinois Environmental Protection Agency.
“Agricultural Property” means any real property for which its present or post-remediation use is for growing agricultural crops for food or feed either as harvested crops, cover crops or as pasture. This definition includes, but is not limited to, properties used for confinement or grazing of livestock or poultry and for silviculture operations. Excluded from this definition are farm residences, farm outbuildings and agrichemical facilities.
“Aquifer” means saturated (with groundwater) soils and geologic materials which are sufficiently permeable to readily yield economically useful quantities of water to wells, springs, or streams under ordinary hydraulic gradients. (Illinois Groundwater Protection Act [415 ILCS 55/3(a)])
“Area Background” means concentrations of regulated substances that are consistently present in the environment in the vicinity of a site that are the result of natural conditions or human activities, and not the result solely of releases at the site. [415 ILCS 5/58.2]
“ASTM” means the American Society for Testing and Materials.
“Board” means the Illinois Pollution Control Board.
“Building” means a man-made structure with an enclosing roof and enclosing walls (except for windows and doors) that is fit for any human occupancy for at least six consecutive months.
“Building Control Technology” means any technology or barrier that affects air flow or air pressure within a building for purposes of reducing or preventing contaminant migration to the indoor air.
“Cancer Risk” means a unitless probability of an individual developing cancer from a defined exposure rate and frequency.
“Cap” means a barrier designed to prevent the infiltration of precipitation or other surface water, or impede the ingestion or inhalation of contaminants.
“Capillary Fringe” means the zone above the water table in which water is held by surface tension. Water in the capillary fringe is under a pressure less than atmospheric.
“Carcinogen” means a contaminant that is classified as a category A1 or A2 carcinogen by the American Conference of Governmental Industrial Hygienists; a category 1 or 2A/2B carcinogen by the World Health Organization's International Agency for Research on Cancer; a "human carcinogen" or "anticipated human carcinogen" by the United States Department of Health and Human Service National Toxicological Program; or a category A or B1/B2 carcinogen or as “carcinogenic to humans” or “likely to be carcinogenic to humans” by the United States Environmental Protection Agency in the integrated risk information system or a final rule issued in a Federal Register notice by the USEPA. [415 ILCS 5/58.2]
“Class I Groundwater” means groundwater that meets the Class I: Potable Resource Groundwater criteria set forth in 35 Ill. Adm. Code 620.
“Class II Groundwater” means groundwater that meets the Class II: General Resource Groundwater criteria set forth in 35 Ill. Adm. Code 620.
“Conservation Property” means any real property for which present or post-remediation use is primarily for wildlife habitat.
“Construction Worker” means a person engaged on a temporary basis to perform work involving invasive construction activities including, but not limited to, personnel performing demolition, earth-moving, building, and routine and emergency utility installation or repair activities.
“Contaminant of Concern” or "Regulated Substance of Concern" means any contaminant that is expected to be present at the site based upon past and current land uses and associated releases that are known to the person conducting a remediation based upon reasonable inquiry. [415 ILCS 5/58.2]
“County Highway” means county highway as defined in the Illinois Highway Code [605 ILCS 5].
“District Road” means district road as defined in the Illinois Highway Code [605 ILCS 5].
“Engineered Barrier” means a barrier designed or verified using engineering practices that limits exposure to or controls migration of the contaminants of concern.
“Environmental Land Use Control” means an instrument that meets the requirements of this Part and is placed in the chain of title to real property that limits or places requirements upon the use of the property for the purpose of protecting human health or the environment, is binding upon the property owner, heirs, successors, assigns, and lessees, and runs in perpetuity or until the Agency approves, in writing, removal of the limitation or requirement from the chain of title.
“Exposure Route” means the transport mechanism by which a contaminant of concern reaches a receptor.
“Federally Owned Property” means real property owned in fee by the United States of America on which institutional controls are sought to be placed in accordance with this Subpart.
“Federal Landholding Entity” means that federal department, agency, or instrumentality with the authority to occupy and control the day-to-day use, operation and management of Federally Owned Property.
“Free Product” means a contaminant that is present as a non-aqueous phase liquid for chemicals whose melting point is less than 30 ° C (e.g., liquid not dissolved in water).
“GIS” means Geographic Information System.
“GPS” means Global Positioning System.
“Groundwater" means underground water which occurs within the saturated zone and geologic materials where the fluid pressure in the pore space is equal to or greater than atmospheric pressure. [415 ILCS 5/3.64]
“Groundwater Quality Standards” means the standards for groundwater as set forth in 35 Ill. Adm. Code 620.
“Hazard Quotient” means the ratio of a single substance exposure level during a specified time period to a reference dose for that substance derived from a similar exposure period.
“Highway” means any public way for vehicular travel which has been laid out in pursuance of any law of this State, or of the Territory of Illinois, or which has been established by dedication, or used by the public as a highway for 15 years, or which has been or may be laid out and connect a subdivision or platted land with a public highway and which has been dedicated for the use of the owners of the land included in the subdivision or platted land where there has been an acceptance and use under such dedication by such owners, and which has not been vacated in pursuance of law. The term "highway" includes rights of way, bridges, drainage structures, signs, guard rails, protective structures and all other structures and appurtenances necessary or convenient for vehicular traffic. A highway in a rural area may be called a "road", while a highway in a municipal area may be called a "street". (Illinois Highway Code [605 ILCS 5/2-202])
“Highway Authority” means the Department of Transportation with respect to a State highway; the Illinois State Toll Highway with respect to a toll highway; the County Board with respect to a county highway or a county unit district road if a discretionary function is involved and the County Superintendent of Highways if a ministerial function is involved; the Highway Commissioner with respect to a township or district road not in a county unit road district; or the corporate authorities of a municipality with respect to a municipal street. (Illinois Highway Code [605 ILCS 5/2-213])
“Human Exposure Pathway” means a physical condition which may allow for a risk to human health based on the presence of all of the following: contaminants of concern; an exposure route; and a receptor activity at the point of exposure that could result in contaminant of concern intake.
“Industrial/Commercial Property” means any real property that does not meet the definition of residential property, conservation property or agricultural property.
“Infiltration” means the amount of water entering into the ground as a result of precipitation.
“Institutional Control” means a legal mechanism for imposing a restriction on land use, as described in Subpart J.
“Intrusive activities” means activities that would affect potential flow of contaminants into a building (e.g., breaching the integrity of a foundation due to repairs or installation of utilities).
“Land Use Control Memoranda of Agreement” mean agreements entered into between one or more agencies of the United States and the Illinois Environmental Protection Agency that limit or place requirements upon the use of Federally Owned Property for the purpose of protecting human health or the environment.
“Man-Made Pathways” means constructed physical conditions that may allow for the transport of regulated substances including, but not limited to, sewers, utility lines, utility or elevator vaults, building foundations, basements, crawl spaces, drainage ditches, previously excavated and filled areas or sumps. [415 ILCS 5/58.2]
“Natural Pathways” means natural physical conditions that may allow for the transport of regulated substances including, but not limited to, soil, groundwater, sand seams and lenses, and gravel seams and lenses. [415 ILCS 5/58.2]
“Person” means an individual, trust, firm, joint stock company, joint venture, consortium, commercial entity, corporation (including a government corporation), partnership, association, state, municipality, commission, political subdivision of a state, or any interstate body including the United States government and each department, agency, and instrumentality of the United States. [415 ILCS 5/58.2]
“Point of Human Exposure” means the points at which human exposure to a contaminant of concern may reasonably be expected to occur. The point of human exposure is at the source, unless an institutional control limiting human exposure for the applicable exposure route has been or will be in place, in which case the point of human exposure will be the boundary of the institutional control. Point of human exposure may be at a different location than the point of compliance.
“Populated Area” means:
an area within the boundaries of a municipality that has a population of 10,000 or greater based on the year 2000 or most recent census; or
an area less than three miles from the boundary of a municipality that has a population of 10,000 or greater based on the year 2000 or most recent census.
“Potable” means generally fit for human consumption in accordance with accepted water supply principles and practices. (Illinois Groundwater Protection Act [415 ILCS 55/3(h)])
“PQL” means practical quantitation limit or estimated quantitation limit, which is the lowest concentration that can be reliably measured within specified limits of precision and accuracy for a specific laboratory analytical method during routine laboratory operating conditions in accordance with “Test Methods for Evaluating Solid Wastes, Physical/Chemical Methods”, EPA Publication No. SW-846, incorporated by reference in Section 742.210. When applied to filtered water samples, PQL includes the method detection limit or estimated detection limit in accordance with the applicable method revision in: “Methods for the Determination of Organic Compounds in Drinking Water”, Supplement II”, EPA Publication No. EPA/600/4-88/039; “Methods for the Determination of Organic Compounds in Drinking Water, Supplement III”, EPA Publication No. EPA/600/R-95/131, all of which are incorporated by reference in Section 742.210.
“Qsoil” means the volumetric flow rate of soil gas from the subsurface into the enclosed building space.
“RBCA” means Risk Based Corrective Action as defined in ASTM E-1739-95, as incorporated by reference in Section 742.210.
“RCRA” means the Resource Conservation and Recovery Act of 1976 (42 USC 6921).
“Reference Concentration” or “RfC” means an estimate of a daily exposure, in units of milligrams of chemical per cubic meter of air (mg/m3), to the human population (including sensitive subgroups) that is likely to be without appreciable risk of deleterious effects during a portion of a lifetime (up to approximately seven years, subchronic) or for a lifetime (chronic).
“Reference Dose” or “RfD” means an estimate of a daily exposure, in units of milligrams of chemical per kilogram of body weight per day (mg/kg/d), to the human population (including sensitive subgroups) that is likely to be without appreciable risk of deleterious effects during a portion of a lifetime (up to approximately seven years, subchronic) or for a lifetime (chronic).
“Regulated Substance” means any hazardous substance as defined under Section 101(14) of the Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (P.L. 96-510) and petroleum products including crude oil or any fraction thereof, natural gas, natural gas liquids, liquefied natural gas, or synthetic gas usable for fuel (or mixtures of natural gas and such synthetic gas). [415 ILCS 5/58.2]
“Rendered inoperable” means having become unable to operate effectively, including, but not limited to, being shut down as part of routine maintenance or due to a malfunction, power failure, or vandalism.
“Residential Property” means any real property that is used for habitation by individuals, or where children have the opportunity for exposure to contaminants through ingestion or inhalation (indoor or outdoor) at educational facilities, health care facilities, child care facilities or recreational areas. [415 ILCS 5/58.2]
“Right of Way” means the land, or interest therein, acquired for or devoted to a highway. (Illinois Highway Code [605 ILCS 5/2-217])
“Saturated Zone” means a subsurface zone in which all the interstices or voids are filled with water under pressure greater than that of the atmosphere.
“Similar-Acting Chemicals” are chemical substances that have toxic or harmful effect on the same specific organ or organ system (see Appendix A.Tables E and F for a list of similar-acting chemicals with noncarcinogenic and carcinogenic effects).
“Site” means any single location, place, tract of land or parcel of property, or portion thereof, including contiguous property separated by a public right-of-way. [415 ILCS 5/58.2]
“Slurry Wall” means a man-made barrier made of geologic material which is constructed to prevent or impede the movement of contamination into a certain area.
“Soil Gas” means the air existing in void spaces in the soil between the groundwater table and the ground surface.
“Soil Saturation Limit” or “Csat” means the contaminant concentration at which the absorptive limits of the soil particles, the solubility limits of the available soil moisture, and saturation of soil pore air have been reached. Above the soil saturation concentration, the assumptions regarding vapor transport to air and/or dissolved phase transport to groundwater (for chemicals that are liquid at ambient soil temperatures) do not apply, and alternative modeling approaches are required.
“Soil Vapor Saturation Limit” or “Cvsat” means the maximum vapor concentration that can exist in the soil pore air at a given temperature and pressure.
“Solubility” means a chemical specific maximum amount of solute that can dissolve in a specific amount of solvent (groundwater) at a specific temperature.
“SPLP” means Synthetic Precipitation Leaching Procedure (Method 1312) as published in “Test Methods for Evaluating Solid Waste, Physical/Chemical Methods”, USEPA Publication No. SW-846, as incorporated by reference in Section 742.210.
“SSL” means Soil Screening Levels as defined in USEPA’s Soil Screening Guidance: User's Guide and Technical Background Document, as incorporated by reference in Section 742.210.
“State Highway” means State highway as defined in the Illinois Highway Code [605 ILCS 5].
“Stratigraphic Unit” means a site-specific geologic unit of native deposited material and/or bedrock of varying thickness (e.g., sand, gravel, silt, clay, bedrock, etc.). A change in stratigraphic unit is recognized by a clearly distinct contrast in geologic material or a change in physical features within a zone of gradation. For the purposes of this Part, a change in stratigraphic unit is identified by one or a combination of differences in physical features such as texture, cementation, fabric, composition, density, and/or permeability of the native material and/or bedrock.
“Street” means street as defined in the Illinois Highway Code [605 ILCS 5].
“TCLP” means Toxicity Characteristic Leaching Procedure (Method 1311) as published in "Test Methods for Evaluating Solid Waste, Physical/Chemical Methods", USEPA Publication No. SW-846, as incorporated by reference in Section 742.210.
“Toll Highway” means toll highway as defined in the Illinois Highway Code [605 ILCS 5].
“Total Petroleum Hydrocarbon” or “TPH” means the additive total of all petroleum hydrocarbons found in an analytical sample.
“Township Road” means township road as defined in the Illinois Highway Code [605 ILCS 5].
“Unconfined Aquifer” means an aquifer whose upper surface is a water table free to fluctuate under atmospheric pressure.
“Volatile Chemicals” means chemicals with a Dimensionless Henry’s Law Constant of greater than 1.9 x 10-2 or a vapor pressure greater than 0.1 Torr (mmHg) at 25°C. For purposes of the indoor inhalation exposure route, elemental mercury is included in this definition.
“Water Table” means the top water surface of an unconfined aquifer at atmospheric pressure.
(Source: Amended at 37 Ill. Reg. 7506, effective July 15, 2013)
Section 742.205 Severability
If any provision of this Part or its application to any person or under any circumstances is adjudged invalid, such adjudication shall not affect the validity of this Part as a whole or any portion not adjudged invalid.
Section 742.210 Incorporations by Reference
a) The Board incorporates the following material by reference:
Agency for Toxic Substances and Disease Registry (ATSDR) Minimal Risk Levels (MRLs), U.S. Environmental Protection Agency, 1600 Clifton Road, Mailstop F32, Atlanta, Georgia 30333, (770) 488-3357 (November 2007).
ASTM International. 100 Barr Harbor Drive, West Conshohocken PA 19428-2959, (610) 832-9585.
ASTM D 2974-00, Standard Test Methods for Moisture, Ash and Organic Matter of Peat and Other Organic Soils, approved August 10, 2000.
ASTM D 2488-00, Standard Practice for Description and Identification of Soils (Visual-Manual Procedure), approved February 10, 2000.
ASTM D 1556-00, Standard Test Method for Density and Unit Weight of Soil in Place by the Sand-Cone Method, approved March 10, 2000.
ASTM D 2167-94, Standard Test Method for Density and Unit Weight of Soil in Place by the Rubber Balloon Method, approved March 15, 1994.
ASTM D 2922-01, Standard Test Methods for Density of Soil and Soil-Aggregate in Place by Nuclear Methods (Shallow Depth), approved June 10, 2001.
ASTM D 2937-00e1, Standard Test Method for Density of Soil in Place by the Drive-Cylinder Method, approved June 10, 2000.
ASTM D 854-02, Standard Test Methods for Specific Gravity of Soil Solids by Water Pycnometer, approved July 10, 2002.
ASTM D 2216-98, Standard Test Method for Laboratory Determination of Water (Moisture) Content of Soil and Rock by Mass, approved February 10, 1998.
ASTM D 4959-00, Standard Test Method for Determination of Water (Moisture) Content of Soil by Direct Heating, approved March 10, 2000.
ASTM D 4643-00, Standard Test Method for Determination of Water (Moisture) Content of Soil by the Microwave Oven Method, approved February 10, 2000.
ASTM D 5084-03, Standard Test Methods for Measurement of Hydraulic Conductivity of Saturated Porous Materials Using a Flexible Wall Permeameter, approved November 1, 2003.
ASTM D 422-63 (2002), Standard Test Method for Particle-Size Analysis of Soils, approved November 10, 2002.
ASTM D 1140-00, Standard Test Methods for Amount of Material in Soils Finer than the No. 200 (75 m m) Sieve, approved June 10, 2000.
ASTM D 3017-01, Standard Test Method for Water Content of Soil and Rock in Place by Nuclear Methods (Shallow Depth), approved June 10, 2001.
ASTM D 4525-90 (2001), Standard Test Method for Permeability of Rocks by Flowing Air, approved May 25, 1990.
ASTM D 2487-00, Standard Classification of Soils for Engineering Purposes (Unified Soil Classification System), approved March 10, 2000.
ASTM D 1945-03, Standard Test Method for Analysis of Natural Gas by Gas Chromatography, approved May 10, 2003.
ASTM D 1946-90, Standard Practice for Analysis of Reformed Gas by Gas Chromatography, approved June 1, 2006.
ASTM E 1527-00, Standard Practice for Environmental Site Assessments: Phase I Environmental Site Assessment Process, approved May 10, 2000. Vol. 11.04.
ASTM E 1739-95 (2002), Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites, approved September 10, 1995.
ASTM E 2121-09, Standard Practice for Installing Radon Mitigation Systems in Existing Low-Rise Residential Buildings, approved November 1, 2009.
ASTM E 2600-10, Standard Practice for Assessment for Vapor Intrusion into Structures on Property Involved in Real Estate Transactions, approved June 2010.
API. American Petroleum Institute, 1220 L Street, NW, Washington DC 20005-4070 (202) 682-8000.
BIOVAPOR-A 1-D Vapor Intrusion Model with Oxygen-Limited Aerobic Biodegradation, Version 2.0 (January 2010).
Barnes, Donald G. and Dourson, Michael. (1988). Reference Dose (RfD): Description and Use in Health Risk Assessments. Regulatory Toxicology and Pharmacology. 8, 471-486.
EPRI. Electric Power Research Institute. 3420 Hillview Avenue, Palo Alto, California 94304. (650) 855-2121.
Polycyclic Aromatic Hydrocarbons (PAHs) in Surface Soil in Illinois: Background PAHs, EPRI, Palo Alto CA, We Energies, Milwaukee WI and IEPA, Springfield IL: 2004. 1011376.
Reference Handbook for Site-Specific Assessment of Subsurface Vapor Intrusion to Indoor Air, Electric Power Research Institute (EPRI), Inc., Program No. 1008492 (March 2005).
GPO. Superintendent of Documents, U.S. Government Printing Office, Washington, DC 20401, (202) 783-3238.
USEPA Guidelines for Carcinogenic Risk Assessment, 51 Fed. Reg. 33992-34003 (September 24, 1986).
“Test Methods for Evaluating Solid Waste, Physical/Chemical Methods”, USEPA Publication number SW-846 (Third Edition, Final Update IIIA, April 1998), as amended by Updates I, IIA, III, and IIIA (Document No. 955-001-00000-1).
“Methods for the Determination of Organic Compounds in Drinking Water”, EPA Publication No. EPA/600/4-88/039 (December 1988 (Revised July 1991)).
“Methods for the Determination of Organic Compounds in Drinking Water, Supplement I”, EPA Publication No. EPA/600/4-90/020 (July 1990).
“Methods for the Determination of Organic Compounds in Drinking Water, Supplement II”, EPA Publication No. EPA/600/R-92/129 (August 1992).
“Methods for the Determination of Organic Compounds in Drinking Water, Supplement III”, EPA Publication No. EPA/600/R-95/131 (August 1995).
“Guidance for Data Quality Assessment, Practical Methods for Data Analysis, EPA QA/G-9, QAOO Update,” EPA/600/R-96/084 (July 2000). Available at www.epa.gov/quality/qs-docs/g9-final.pdf .
“Assessment of Vapor Intrusion in Homes Near the Raymark Superfund Site Using Basement and Sub-Slab Air Samples”, EPA Publication No. EPA/600/R-05/147 (March 2006).
“Model Standards and Techniques for Control of Radon in New Residential Buildings” EPA Publication No. EPA/402/R-94/009 (March 1994).
“Radon Reduction Techniques for Existing Detached Houses: Technical Guidance (Third Edition) for Active Soil Depressurization Systems”, EPA Publication No. EPA/625/R-93/011 (October 1993).
Illinois Environmental Protection Agency, 1021 N. Grand Ave East, Springfield IL 62701, (217) 785-0830.
“A Summary of Selected Background Conditions for Inorganics in Soil”, Publication No. IEPA/ENV/94-161 (August 1994).
IRIS. Integrated Risk Information System, National Center for Environmental Assessment, U.S. Environmental Protection Agency, 26 West Martin Luther King Drive, MS-190, Cincinnati, OH 45268, (513) 569-7254.
“Reference Dose (RfD): Description and Use in Health Risk Assessments”, Background Document 1A (March 15, 1993).
“EPA Approach for Assessing the Risks Associated with Chronic Exposures to Carcinogens”, Background Document 2 (January 17, 1992).
Johnson, Paul C. (2005). Identification of Application Specific Critical Inputs for the 1991 Johnson and Ettinger Vapor Intrusion Algorithm. Ground Water Monitoring and Remediation. 25(1), 63-78.
Murray, Donald M. and Burmaster, David E. (1995). Residential Air Exchange Rates in the United States: Empirical and Estimated Parametric Distributions by Season and Climatic Region. Risk Analysis. 15(4), 459-465.
Nelson, D.W., and L.E. Sommers (1982). Total carbon, organic carbon, and organic matter. In: A.L. Page (ed.), Methods of Soil Analysis. Part 2. Chemical and Microbiological Properties. 2nd Edition, pp. 539-579, American Society of Agronomy. Madison, WI.
NTIS. National Technical Information Service, 5285 Port Royal Road, Springfield, VA 22161, (703) 487-4600.
“Calculating Upper Confidence Limits for Exposure Point Concentrations at Hazardous Waste Sites,” USEPA Office of Emergency and Remedial Response, OSWER 9285.6-10 (December 2002), PB 2003-104982.
“Evaluating the Vapor Intrusion to Indoor Air Pathway from Groundwater and Soils”, OSWER Draft Guidance. EPA Publication No. EPA/530D-02/004 (November 2002).
“Exposures Factors Handbook, Vol. I: General Factors”, EPA Publication No. EPA/600/P-95/002Fa (August 1997).
“Exposures Factors Handbook, Vol. II: Food Ingestion Factors”, EPA Publication No. EPA/600/P-95/002Fb (August 1997).
“Exposures Factors Handbook, Vol. III: Activity Factors”, EPA Publication No. EPA/600/P-95/002Fc (August 1997).
“Risk Assessment Guidance for Superfund, Vol. I: Human Health Evaluation Manual, Supplemental Guidance: Standard Default Exposure Factors”, OSWER Directive 9285.6-03 (March 1991).
“Rapid Assessment of Exposure to Particulate Emissions from Surface Contamination Sites”, EPA Publication No. EPA/600/8-85/002 (February 1985), PB 85-192219.
“Risk Assessment Guidance for Superfund, Vol. I: Human Health Evaluation Manual (Part E, Supplemental Guidance for Dermal Risk Assessment) Final”, EPA Publication No. EPA/540/R/99/005 (July 2004).
“Risk Assessment Guidance for Superfund, Vol. 1: Human Health Evaluation Manual (Part F, Supplemental Guidance for Inhalation Risk Assessment) Final”, EPA Publication No. 540-R-070-002 (January 2009).
“Soil Screening Guidance: Technical Background Document”, EPA Publication No. EPA/540/R-95/128, PB 96-963502 (May 1996).
“Soil Screening Guidance: User’s Guide”, EPA Publication No. EPA/540/R-96/018, PB 96-963505 (April 1996).
“Superfund Exposure Assessment Manual”, EPA Publication No. EPA/540/1-88/001 (April 1988).
“Supplemental Guidance for Developing Soil Screening Levels for Superfund Sites”, OSWER Directive 9355.4-24 (December 2002).
“User’s Guide for Evaluating Subsurface Vapor Intrusion into Buildings”, EPA Publication No. EPA/68/W-02/33 (February 2004).
Polynuclear Aromatic Hydrocarbon Background Study, City of Chicago, Illinois, Tetra Tech Em Inc., 200 E. Randolph Drive, Suite 4700, Chicago IL 60601, February 24, 2003.
RCRA Facility Investigation Guidance, Interim Final, developed by USEPA (EPA 530/SW-89-031), 4 volumes (May 1989).
United States Environmental Protection Agency, Office of Environmental Information (2000). “Guidance for Data Quality Assessment, Practical Methods for Data Analysis,” EPA QA/G-9, QAOO update. EPA Publication No. EPA/600/R-96-084. (Available at www.epa.gov/oswer/riskassessment/pdf/ucl.pdf ).
United States Environmental Protection Agency, Office of Solid Waste and Emergency Response (2003). “Human Health Toxicity Values in Superfund Risk Assessments,” OSWER Directive 9285.7-53. (Available at http://www.epa.gov/oswer/riskassessment/pdf/hhmemo.pdf )
United States Environmental Protection Agency, Compendium of Methods for Determination of Toxic Organic Compounds in Ambient Air, Second Edition, EPA Publication No. EPA/625/R-96/010b, January 1999, available at http://www.epa.gov/ttnamti1/files/ambient/airtox/tocomp99.pdf .
United States Environmental Protection Agency, Test Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW-846 through Revision IVB (February 2007), available at http://www.epa.gov/sw-846/main.htm .
United States Environmental Protection Agency, CFR Promulgated Test Methods, Methods 3C and 16, Technology Transfer Network, Emission Measurement Center (2007), available at http://www.epa.gov/ttn/emc/promgate.html .
United States Environmental Protection Agency. “Guidelines for Carcinogen Risk Assessment (2005)”. U. S. Environmental Protection Agency, Washington, DC, EPA Publication No. EPA/630/P-03/001F, 2005. (Available at http://cfpub.epa.gov/ncea/raf/recordisplay.cfm?deid=116283 .)
“Vapor Intrusion Pathway: A Practical Guide”, Technical and Regulatory Guidance. Interstate Technology and Regulatory Council (January 2007).
b) CFR (Code of Federal Regulations). Available from the Superintendent of Documents, U.S. Government Printing Office, Washington, D.C. 20402 (202)783-3238:
40 CFR 761 (1998).
c) This Section incorporates no later editions or amendments.
(Source: Amended at 37 Ill. Reg. 7506, effective July 15, 2013)
Section 742.215 Determination of Soil Attenuation Capacity
a) The concentrations of organic contaminants of concern remaining in the soil shall not exceed the attenuation capacity of the soil, as determined under subsection (b) of this Section.
b) The soil attenuation capacity is not exceeded if:
1) The sum of the organic contaminant residual concentrations analyzed for the purposes of the remediation program for which the analysis is performed, at each discrete sampling point, is less than the natural organic carbon fraction of the soil. If the information relative to the concentration of other organic contaminants is available, such information shall be included in the sum. The natural organic carbon fraction (foc) shall be either:
A) A default value of 6000 mg/kg for soils within the top meter and 2000 mg/kg for soils below one meter of the surface; or
B) A site-specific value as measured by the analytical method referenced in Appendix C, Table F, multiplied by 0.58 to estimate the fraction of organic carbon, as stated in, Nelson and Sommers (1982), as incorporated by reference in Section 742.210;
2) The total petroleum hydrocarbon concentration is less than the natural organic carbon fraction of the soil as demonstrated using a method approved by the Agency. The method selected shall be appropriate for the contaminants of concern to be addressed; or
3) Another method, approved by the Agency, shows that the soil attenuation capacity is not exceeded.
(Source: Amended at 31 Ill. Reg. 4063, effective February 23, 2007)
Section 742.220 Determination of Soil Saturation Limit
a) For any organic contaminant that has a melting point below 30oC, the remediation objective for the outdoor inhalation exposure route developed under Tier 2 shall not exceed the soil saturation limit, as determined under subsection (c).
b) For any organic contaminant that has a melting point below 30oC, the remediation objective under Tier 2 for the soil component of the groundwater ingestion exposure route shall not exceed the soil saturation limit, as determined under subsection (c).
c) The soil saturation limit shall be:
1) The value listed in Appendix A, Table A for that specific contaminant;
2) A value derived from Equation S29 in Appendix C, Table A; or
3) A value derived from another method approved by the Agency.
(Source: Amended at 37 Ill. Reg. 7506, effective July 15, 2013)
Section 742.222 Determination of Soil Vapor Saturation Limit
a) For any volatile chemical, the soil gas remediation objective for the indoor and outdoor inhalation exposure routes developed under Tier 2 shall not exceed the soil vapor saturation limit, as determined under subsection (b).
b) The soil vapor saturation limit shall be:
1) The value listed in Appendix A, Table K for that specific contaminant; 2) A value derived from Equation J&E5 in Appendix C, Table L; or 3) A value derived from another method approved by the Agency. Section 742.225 Demonstration of Compliance with Soil and Groundwater Remediation Objectives Compliance with soil and groundwater remediation objectives is achieved if each sample result does not exceed that respective remediation objective unless a person elects to proceed under subsections (c), (d) and (e). a) Compliance with groundwater remediation objectives developed under Subparts D through F and H through I shall be demonstrated by comparing the contaminant concentrations of discrete samples at each sample point to the applicable groundwater remediation objective. Sample points shall be determined by the program under which remediation is performed. b) Unless the person elects to composite samples or average sampling results as provided in subsections (c) and (d), compliance with soil remediation objectives developed under Subparts D through G and I shall be demonstrated by comparing the contaminant concentrations of discrete samples to the applicable soil remediation objective. 1) Except as provided in subsections (c) and (d), compositing of samples is not allowed. 2) Except as provided in subsections (c) and (d), averaging of sample results is not allowed. 3) Notwithstanding subsections (c) and (d), compositing of samples and averaging of sample results is not allowed for the construction worker population. 4) The number of sampling points required to demonstrate compliance is determined by the requirements applicable to the program under which remediation is performed. c) If a person chooses to composite soil samples or average soil sample results to demonstrate compliance relative to the soil component of the groundwater ingestion exposure route, the following requirements apply: 1) A minimum of two sampling locations for every 0.5 acre of contaminated area is required, with discrete samples at each sample location obtained at every two feet of depth, beginning at six inches below the ground surface for surface contamination and at the upper limit of contamination for subsurface contamination and continuing through the zone of contamination. Alternatively, a sampling method may be approved by the Agency based on an appropriately designed site-specific evaluation. Samples obtained at or below the water table shall not be used in compositing or averaging. 2) For contaminants of concern other than volatile chemicals: A) Discrete samples from the same boring may be composited; or B) Discrete sample results from the same boring may be averaged. 3) For volatile chemicals: A) Compositing of samples is not allowed. B) Discrete sample results from the same boring may be averaged. 4) Composite samples may not be averaged. An arithmetic average may be calculated for discrete samples collected at every two feet of depth through the zone of contamination as specified in subsection (c)(1). d) If a person chooses to composite soil samples or average soil sample results to demonstrate compliance relative to the outdoor inhalation exposure route or ingestion exposure route, the following requirements apply: 1) A person shall submit a sampling plan for Agency approval, based upon a site-specific evaluation; 2) For volatile chemicals, compositing of samples is not allowed; 3) All samples shall be collected within the contaminated area; 4) Composite samples may not be averaged. Procedures specified in “Calculating Upper Confidence Limits for Exposure Point Concentrations at Hazardous Waste Sites”, USEPA Office of Emergency and Remedial Response, OSWER 9285.6-10 (December 2002), as incorporated by reference in Section 742.210, or an alternative procedure approved by the Agency, shall be used to determine sample averages. e) When averaging under this Section, if no more than 15% of sample results are reported as “non-detect”, “no contamination”, “below detection limits”, or similar terms, such results shall be included in the averaging calculations as one-half the reported analytical detection limit for the contaminant. However, when performing a test for normal or lognormal distribution for the purpose of calculating a 95% Upper Confidence Limit of the mean for a contaminant, a person may substitute for each non-detect value a randomly generated value between, but not including, zero and the reported analytical detection limit. If more than 15% of sample results are "non-detect", procedures specified in “Guidance for Data Quality Assessment, Practical Methods for Data Analysis, EPA QA/G-9, QA00 Update”, EPA/600/R-96/084 (July 2000), as incorporated by reference in Section 742.210, or an alternative procedure approved by the Agency shall be used to address the non-detect values, or another statistically valid procedure approved by the Agency may be used to determine an average.
f) All soil samples collected after August 15, 2001 shall be reported on a dry weight basis for the purpose of demonstrating compliance, with the exception of the TCLP and SPLP and the property pH. (Source: Amended at 37 Ill. Reg. 7506, effective July 15, 2013) Section 742.227 Demonstration of Compliance with Soil Gas Remediation Objectives for the Outdoor and Indoor Inhalation Exposure Routes a) For purposes of the outdoor inhalation exposure route and the indoor inhalation exposure route, compliance with soil gas remediation objectives developed under any tier shall be demonstrated in accordance with this Section by comparing the contaminant concentrations of discrete samples at each sample point to the applicable soil gas remediation objective. b) This Section applies to exterior soil gas samples for the outdoor inhalation exposure route, near-slab soil gas samples collected outside of an existing building for the indoor inhalation exposure route, and exterior soil gas samples collected at the footprint of a potential building for the indoor inhalation exposure route. Proposals to use sub-slab soil gas data for the indoor inhalation exposure route shall follow Section 742.935(c). c) Sample points shall be determined by the program under which remediation is performed. d) When collecting soil gas samples:
1) Use rigid-wall tubing made of nylon or Teflon® or other material approved by the Agency; 2) Use gas-tight, inert containers to hold the sample. For light sensitive or halogenated volatile chemicals, these containers shall be opaque or dark-colored; 3) Purge three volumes before obtaining each discrete soil gas sample; 4) Use a helium tracer or other leak apparatus detection system approved by the Agency; and 5) Limit the flow rate to 200 ml/min. e) Soil gas samples shall be analyzed using a National Environmental Laboratory Accreditation Program (NELAP) certified laboratory. f) Soil gas remediation objectives shall be compared to concentrations of soil gas collected at a depth at least 3 feet below ground surface and above the saturated zone. (Source: Added at 37 Ill. Reg. 7506, effective July 15, 2013)
Section 742.230 Agency Review and Approval
a) Documents and requests filed with the Agency under this Part shall be submitted in accordance with the procedures applicable to the specific program under which remediation is performed.
b) Agency review and approval of documents and requests under this Part shall be performed in accordance with the procedures applicable to the specific program under which the remediation is performed.
SUBPART C: EXPOSURE ROUTE EVALUATIONS
Section 742.300 Exclusion of Exposure Routea) This Subpart sets forth requirements to demonstrate that an actual or potential impact to a receptor or potential receptor from a contaminant of concern can be excluded from consideration from one or more exposure routes. If an evaluation under this Subpart demonstrates the applicable requirements for excluding an exposure route are met, then the exposure route is excluded from consideration and no remediation objective(s) need be developed for that exposure route.
b) No exposure route may be excluded from consideration until characterization of the extent and concentrations of contaminants of concern at a site has been performed. The actual steps and methods taken to characterize a site shall be determined by the specific program requirements under which the site remediation is being addressed. c) As an alternative to the use of the requirements in this Subpart, a person may use the procedures for evaluation of exposure routes under Tier 3 as set forth in Section 742.925. (Source: Amended at 25 Ill. Reg. 10374, effective August 15, 2001) Section 742.305 Contaminant Source and Free Product Determination No exposure route shall be excluded from consideration relative to a contaminant of concern unless the following requirements are met: a) The sum of the concentrations of all organic contaminants of concern shall not exceed the attenuation capacity of the soil as determined under Section 742.215; b) The concentrations of any organic contaminants of concern remaining in the soil shall not exceed the soil saturation limit as determined under Section 742.220; c) Any soil which contains contaminants of concern shall not exhibit any of the characteristics of reactivity for hazardous waste as determined under 35 Ill. Adm. Code 721.123; d) Any soil which contains contaminants of concern shall not exhibit a pH less than or equal to 2.0 or greater than or equal to 12.5, as determined by SW-846 Method 9040B: pH Electrometric for soils with 20% or greater aqueous (moisture) content or by SW-846 Method 9045C: Soil pH for soils with less than 20% aqueous (moisture) content as incorporated by reference in Section 742.210; e) Any soil which contains contaminants of concern in the following list of inorganic chemicals or their salts shall not exhibit any of the characteristics of toxicity for hazardous waste as determined by 35 Ill. Adm. Code 721.124: arsenic, barium, cadmium, chromium, lead, mercury, selenium or silver; f) If contaminants of concern include polychlorinated biphenyls (PCBs), the concentration of any PCBs in the soil shall not exceed 50 parts per million as determined by SW-846 Methods; and g) The concentration of any contaminant of concern in soil gas shall not exceed 10% of its Lower Explosive Limit (LEL) as measured by a hand held combustible gas indicator that has been calibrated to manufacturer specifications. Section 742.310 Outdoor Inhalation Exposure Route The outdoor inhalation exposure route may be excluded from consideration if: a) The requirements in subsection (a)(1) or (a)(2) are met: 1) An approved engineered barrier is in place that meets the requirements of Subpart K; or
The only contaminants of concern are benzene, toluene, ethylbenzene, and total xylenes, and a demonstration of active biodegradation has been made for benzene, toluene, ethylbenzene, and total xylenes such that no outdoor inhalation exposure will occur. This demonstration shall be submitted to the Agency for review and approval; The requirements of Sections 742.300 and 742.305 are met; Safety precautions for the construction worker are taken if the Tier 1 construction worker remediation objectives are exceeded; and An institutional control, in accordance with Subpart J, will be placed on the property. (Source: Amended at 37 Ill. Reg. 7506, effective July 15, 2013 ) Section 742.312 Indoor Inhalation Exposure Route The indoor inhalation exposure route may be excluded from consideration if: None of the contaminants of concern are listed on Appendix A, Table J and none of the contaminants of concern are volatile chemicals, as defined in Section 742.200; or The requirements in subsections (b)(1)(A), (B) or (C) and (b)(2) and (b)(3) are met: Exclusion options when the contaminants of concern are volatile chemicals: No building or man-made pathway exists or will be placed above contaminated soil gas or groundwater exceeding Tier 1 remediation objectives for residential property (Appendix B, Table H), provided, however, that there is also no soil or groundwater contamination exceeding Tier 1 remediation objectives for residential property (Appendix B, Table A) or Class I groundwater (Appendix B, Table E) located 5 feet or less, horizontally, from any existing or potential building or man-made pathway; or An approved building control technology is in place or will be placed that meets the requirements of Subpart L; or If the contaminants of concern are benzene, toluene, ethylbenzene, and total xylenes only, a demonstration of active biodegradation has been made for benzene, toluene, ethylbenzene, and total xylenes such that no indoor inhalation exposure will occur. This demonstration shall be submitted to the Agency for review and approval; The requirements of Sections 742.300 and 742.305 are met; and An institutional control, in accordance with Subpart J, will be placed on the property. (Source: Added at 37 Ill. Reg. 7506, effective July 15, 2013) Section 742.315 Soil Ingestion Exposure Route The soil ingestion exposure route may be excluded from consideration if:
a) The requirements of Sections 742.300 and 742.305 are met; b) An approved engineered barrier is in place that meets the requirements of Subpart K; c) Safety precautions for the construction worker are taken if the Tier 1 construction worker remediation objectives are exceeded; and d) An institutional control, in accordance with Subpart J, will be placed on the property. (Source: Amended at 25 Ill. Reg. 10374, effective August 15, 2001) Section 742.320 Groundwater Ingestion Exposure Route
The groundwater ingestion exposure route may be excluded from consideration if:
a) The requirements of Sections 742.300 and 742.305 are met;
b) The corrective action measures have been completed to remove any free product to the maximum extent practicable;
c) The source of the release is not located within the minimum or designated maximum setback zone or within a regulated recharge area of a potable water supply well;
d) As demonstrated in accordance with Section 742.1015, for any area within the measured and modeled extent of groundwater contamination above what would otherwise be the applicable Tier 1 groundwater remediation objectives, an ordinance adopted by a unit of local government is in place that effectively prohibits the installation of potable water supply wells (and the use of such wells);
e) As demonstrated using Equation R26, in Appendix C, Table C, in accordance with Section 742.810, the concentration of any contaminant of concern in groundwater within the minimum or designated maximum setback zone of an existing potable water supply well will meet the applicable Tier 1 groundwater remediation objective; and
f) As demonstrated using Equation R26, in Appendix C, Table C, in accordance with Section 742.810, the concentration of any contaminant of concern in groundwater discharging into a surface water will meet the applicable surface water quality standard under 35 Ill. Adm. Code 302.
(Source: Amended at 31 Ill. Reg. 4063, effective February 23, 2007)
SUBPART D: DETERMINING AREA BACKGROUNDS
Section 742.400 Area Background
This Subpart provides procedures for determining area background concentrations for contaminants of concern. Except as described in Section 742.415(c) and (d) of this Subpart, area background concentrations may be used as remediation objectives for contaminants of concern at a site.
Section 742.405 Determination of Area Background for Soil
a) Soil sampling results shall be obtained for purposes of determining area background levels in accordance with the following procedures:
1) For volatile chemicals, sample results shall be based on discrete samples;
2) Unless an alternative method is approved by the Agency, for contaminants other than volatile chemicals, sample results shall be based on discrete samples or composite samples. If a person elects to use composite samples, each 0.5 acre of the area to be sampled shall be divided into quadrants and 5 aliquots of equal volume per quadrant shall be composited into 1 sample;
3) Samples shall be collected from similar depths and soil types, which shall be consistent with the depths and soil types in which maximum levels of contaminants are found in the areas of known or suspected releases; and
4) Samples shall be collected from areas of the site or adjacent to the site that are unaffected by known or suspected releases at or from the site. If the sample results show an impact from releases at or from the site, then the sample results shall not be included in determining area background levels under this Part.
b) Area background shall be determined according to one of the following approaches:
1) Statewide Area Background Approach:
A) The concentrations of inorganic chemicals in background soils listed in Appendix A, Table G may be used as the upper limit of the area background concentration for the site. The first column to the right of the chemical name presents inorganic chemicals in background soils for counties within Metropolitan Statistical Areas. Counties within Metropolitan Statistical Areas are identified in Appendix A, Table G, Footnote a. Sites located in counties outside Metropolitan Statistical Areas shall use the concentrations of inorganic chemicals in background soils shown in the second column to the right of the chemical name.
B) Soil area background concentrations determined according to this statewide area background approach shall be used as provided in Section 742.415(b) of this Part. For each parameter whose sampling results demonstrate concentrations above those in Appendix A, Table G, the person shall develop appropriate soil remediation objectives in accordance with this Part, or may determine area background in accordance with subsection (b)(2).
2) A statistically valid approach for determining area background concentrations appropriate for the characteristics of the data set, and approved by the Agency.
(Source: Amended at 37 Ill. Reg. 7506, effective July 15, 2013)
Section 742.410 Determination of Area Background for Groundwater
a) Groundwater sampling results shall be obtained for purposes of determining area background in accordance with the following procedures:
1) Samples shall be collected from areas of the site or adjacent to the site that are unaffected by releases at the site;
2) The background monitoring wells shall be sufficient in number to account for the spatial and temporal variability, size, and number of known or suspected off-site releases of contaminants of concern, and the hydrogeological setting of the site;
3) The samples shall be collected in consecutive quarters for a minimum of one year for each well unless another sample schedule is approved by the Agency;
4) The samples shall be collected from the same stratigraphic unit(s) as the groundwater contamination at the site; and
5) The background monitoring wells shall be located hydraulically upgradient from the release(s) of contaminants of concern, unless a person demonstrates to the Agency that the upgradient location is undefinable or infeasible.
b) Area background shall be determined according to one of the following approaches:
1) Prescriptive Approach:
A) If more than 15% of the groundwater sampling results for a chemical obtained in accordance with subsection (a) of this Section are less than the appropriate detection limit for that chemical, the Prescriptive Approach may not be used for that chemical. If 15% or less of the sampling results are less than the appropriate detection limit, a concentration equal to one-half the detection limit shall be used for that chemical in the calculations contained in this Prescriptive Approach.
B) The groundwater sampling results obtained in accordance with subsection (a) of this Section shall be used to determine if the sample set is normally distributed. The Shapiro-Wilk Test of Normality shall be used to determine whether the sample set is normally distributed, if the sample set for the background well(s) contains 50 or fewer samples. Values necessary for the Shapiro-Wilk Test of Normality shall be determined using Appendix A, Tables C and D. If the computed value of W is greater than the 5% Critical Value in Appendix A, Table D, the sample set shall be assumed to be normally distributed, and the Prescriptive Approach is allowed. If the computed value of W is less than 5% Critical Value in Appendix A, Table D, the sample set shall be assumed to not be normally distributed, and the Prescriptive Approach shall not be used.
C) If the sample set contains at least ten sample results, the Upper Tolerance Limit (UTL) of a normally distributed sample set may be calculated using the mean (x) and standard deviation(s), from:
UTL = x + (K · s),
where K = the one-sided normal tolerance factor for estimating the 95% upper confidence limit of the 95th percentile of a normal distribution. Values for K shall be determined using Appendix A, Table B.
D) If the sample set contains at least ten sample results, the UTL shall be the upper limit of the area background concentration for the site. If the sample set contains fewer than ten sample results, the maximum value of the sample set shall be the upper limit of the area background concentration for the site.
E) This Prescriptive Approach shall not be used for determining area background for the parameter pH.
2) Another statistically valid approach for determining area background concentrations appropriate for the characteristics of the data set, and approved by the Agency.
Section 742.415 Use of Area Background Concentrations
a) A person may request that area background concentration determined pursuant to Sections 742.405 and 742.410 be used according to the provisions of subsection (b) of this Section. Such request shall address the following:
1) The natural or man-made pathways of any suspected off-site contamination reaching the site;
2) Physical and chemical properties of suspected off-site contaminants of concern reaching the site; and
3) The location and justification of all background sampling points.
b) Except as specified in subsections (c) and (d) of this Section, an area background concentration may be used as follows:
1) To support a request to exclude a chemical as a contaminant of concern from further consideration for remediation at a site due to its presence as a result of background conditions; or
2) As a remediation objective for a contaminant of concern at a site in lieu of an objective developed pursuant to the other procedures of this Part.
c) An area background concentration shall not be used in the event that the Agency has determined in writing that the background level for a regulated substance poses an acute threat to human health or the environment at the site when considering the post-remedial action land use. (Section 58.5(b)(3) of the Act)
d) In the event that the concentration of a regulated substance of concern on the site exceeds a remediation objective adopted by the Board for residential land use, the property may not be converted to residential use unless such remediation objective or an alternative risk-based remediation objective for that regulated substance of concern is first achieved. If the land use is restricted, there shall be an institutional control in place in accordance with Subpart J. (Section 58.5(b)(2) of the Act)
(Source: Amended at 31 Ill. Reg. 4063, effective February 23, 2007)
SUBPART E: TIER 1 EVALUAION
Section 742.500 Tier 1 Evaluation Overview
Section 742.500 Tier 1 Evaluation Overview
a) A Tier 1 evaluation compares the concentration of each contaminant of concern detected at a site to the baseline remediation objectives provided in Appendix B, Tables A, B, C, D, E, G, H and I. Use of Tier 1 remediation objectives requires only limited site-specific information: concentrations of contaminants of concern, groundwater classification, land use classification, and, if appropriate, soil pH. (See Appendix B, Illustration A.)
b) Although Tier 1 allows for differentiation between residential and industrial/commercial property use of a site, an institutional control under Subpart J is required where remediation objectives are based on an industrial/commercial property use.
c) For the indoor inhalation exposure route:
1) Appendix B, Tables H and I apply only when the existing or potential building has a full concrete slab-on-grade or a full concrete basement floor and walls; and
2) Institutional controls under Subpart J are required to use remediation objectives in Appendix B, Table H or Table I.
d) Any given exposure route is not a concern if the concentration of each contaminant of concern detected at the site is below the Tier 1 value of that given route. In such a case, no further evaluation of that route is necessary.
(Source: Amended at 37 Ill. Reg. 7506, effective July 15, 2013)
Section 742.505 Tier 1 Soil, Soil Gas and Groundwater Remediation Objectives
a) Soil
1) Outdoor Inhalation Exposure Route
A) The Tier 1 soil remediation objectives for this exposure route based upon residential property use are listed in Appendix B, Table A.
B) The Tier 1 soil remediation objectives for this exposure route based upon industrial/commercial property use are listed in Appendix B, Table B. Soil remediation objective determinations relying on this table require use of institutional controls in accordance with Subpart J.
C) For this exposure route, it is acceptable to determine compliance by meeting either the soil or soil gas remediation objectives.
2) Ingestion Exposure Route
A) The Tier 1 soil remediation objectives for this exposure route based upon residential property use are listed in Appendix B, Table A.
B) The Tier 1 soil remediation objectives for this exposure route based upon industrial/commercial property use are listed in Appendix B, Table B. Soil remediation objective determinations relying on this table require use of institutional controls in accordance with Subpart J.
3) Soil Component of the Groundwater Ingestion Route
A) The Tier 1 soil remediation objectives for this exposure route based upon residential property use are listed in Appendix B, Table A.
B) The Tier 1 soil remediation objectives for this exposure route based upon industrial/commercial property use are listed in Appendix B, Table B.
C) The pH-dependent Tier 1 soil remediation objectives for identified ionizable organics or inorganics for the soil component of the groundwater ingestion exposure route (based on the total amount of contaminants present in the soil sample results and groundwater classification) are provided in Appendix B, Tables C and D.
D) Values used to calculate the Tier 1 soil remediation objectives for this exposure route are listed in Appendix B, Table F.
4) Evaluation of the dermal contact with soil exposure route is not required under Tier 1.
b) Soil Gas
1) Outdoor Inhalation Exposure Route
A) The Tier 1 soil gas remediation objectives for this exposure route based upon residential property use are listed in Appendix B, Table G.
B) The Tier 1 soil gas remediation objectives for this exposure route based upon industrial/commercial property use, including the construction worker population, are listed in Appendix B, Table G. Soil gas remediation objective determinations relying on an industrial/commercial scenario require use of institutional controls in accordance with Subpart J. C) For this exposure route, it is acceptable to determine compliance by meeting either the soil or soil gas remediation objectives. 2) Indoor Inhalation Exposure Route A) The Tier 1 soil gas remediation objectives for this exposure route are listed in Appendix B, Tables H and I. B) The Tier 1 soil gas remediation objectives for this exposure route are based on a default water-filled soil porosity value of 0.15 cm3/cm3 and the assumed presence of a building with a 10-cm thick, full concrete slab-on-grade. C) Appendix B, Table H shall be used when any soil or groundwater contamination is located 5 feet or less, vertically or horizontally, from the existing or potential building or man-made pathway. In this scenario, the mode of contaminant transport is both diffusion and advection, which sets the Qsoil value at 83.33 cm3/sec. Appendix B, Table H applies only when the existing or potential building has a full concrete slab-on-grade or a full concrete basement floor and walls. Pursuant to Section 742.1000(a)(9), soil gas remediation objective determinations relying on Appendix B, Table H require the use of institutional controls in accordance with Subpart J. D) Appendix B, Table I may be used only when all soil and groundwater contamination is located more than 5 feet, vertically and horizontally, from the existing or potential building or man-made pathway. In this scenario, the mode of contaminant transport is diffusion only, which sets the Qsoil value at 0.0 cm3/sec. Appendix B, Table I applies only when the existing or potential building has a full concrete slab-on-grade or a full concrete basement floor and walls. Pursuant to Section 742.1000(a)(7) and (a)(9), soil gas remediation objective determinations relying on Appendix B, Table I require the use of institutional controls in accordance with Subpart J. As an alternative to using Appendix B, Table I, it is permissible to use Appendix B, Table H. E) To determine whether the Qsoil value can be set at 0.0 cm3/sec, the site evaluator shall demonstrate that all soil and groundwater located 5 feet or less, vertically or horizontally, from the existing or potential building or man-made pathway meets the Tier 1 remediation objectives for residential property listed in Appendix B, Table A, and the Tier 1 remediation objectives for Class I groundwater listed in Appendix B, Table E, respectively.
c) Groundwater
1) The Tier 1 groundwater remediation objectives for the groundwater component of the groundwater ingestion route are listed in Appendix B, Table E.
2) The Tier 1 groundwater remediation objectives for this exposure route are given for Class I and Class II groundwaters, respectively.
3) The evaluation of 35 Ill. Adm. Code 620.615 regarding mixtures of similar-acting chemicals shall be considered satisfied for Class I groundwater at the point of human exposure if:
A) No more than one similar-acting noncarcinogenic chemical as listed in Appendix A, Table E is detected in the groundwater at the site; and
B) No carcinogenic contaminant of concern as listed in Appendix A, Table I is detected in any groundwater sample associated with the site, using analytical procedures capable of achieving either the 1 in 1,000,000 cancer risk concentration or the ADL, whichever is greater.
4) If the conditions of subsection (c)(3) of this Section are not met, the Class I groundwater remediation objectives set forth in Appendix B, Table E shall be corrected for the cumulative effect of mixtures of similar-acting chemicals using the following methodologies:
A) For noncarcinogenic chemicals, the methodologies set forth at Section 742.805(c) or Section 742.915(h) shall be used; and
B) For carcinogenic chemicals, the methodologies set forth at Section 742.805(d) or Section 742.915(h) shall be used.
5) For the groundwater component of the indoor inhalation exposure route, the Tier 1 groundwater remediation objectives are listed in Appendix B, Tables H and I.
A) The Tier 1 groundwater remediation objectives for this exposure route are based on a default water-filled soil porosity value of 0.15 cm3/cm3 and the assumed presence of a building with a 10-cm thick, full concrete slab-on-grade.
B) Appendix B, Table H shall be used when any soil or groundwater contamination is located 5 feet or less, vertically or horizontally, from the existing or potential building or man-made pathway. In this scenario, the mode of contaminant transport is both diffusion and advection, which sets the Qsoil value at 83.33 cm3/sec. Appendix B, Table H applies only when the existing or potential building has a full concrete slab-on-grade or a full concrete basement floor and walls. Pursuant to Section 742.1000(a)(9), groundwater remediation objective determinations relying on Appendix B, Table H require the use of institutional controls in accordance with Subpart J. C) Appendix B, Table I may be used only when all soil and groundwater contamination is located more than 5 feet, vertically and horizontally, from the existing or potential building or man-made pathway. In this scenario, the mode of contaminant transport is diffusion only, which sets the Qsoil value at 0.0 cm3/sec. Appendix B, Table I applies only when the existing or potential building has a full concrete slab-on-grade or a full concrete basement floor and walls. Pursuant to Section 742.1000(a)(7) and (a)(9), groundwater remediation objective determinations relying on Appendix B, Table I require the use of institutional controls in accordance with Subpart J. As an alternative to using Appendix B, Table I, it is permissible to use Appendix B, Table H. D) To determine whether the Qsoil value can be set at 0.0 cm3/sec, the site evaluator shall demonstrate that all soil and groundwater located 5 feet or less, vertically or horizontally, from the existing or potential building or man-made pathway meets the Tier 1 remediation objectives for residential property listed in Appendix B, Table A, and the Tier 1 remediation objectives for Class I groundwater listed in Appendix B, Table E, respectively. (Source: Amended at 37 Ill. Reg. 7506, effective July 15, 2013) Section 742.510 Tier 1 Remediation Objectives Tables for the Ingestion, Outdoor Inhalation and Soil Component of the Groundwater Ingestion Exposure Routes a) Soil remediation objectives are listed in Appendix B, Tables A, B, C and D. 1) Appendix B, Table A is based upon residential property use. A) The first column to the right of the chemical name lists soil remediation objectives for the soil ingestion exposure route. B) The second column lists the soil remediation objectives for the outdoor inhalation exposure route. C) The third and fourth columns list soil remediation objectives for the soil component of the groundwater ingestion exposure route for the respective classes of groundwater: i) Class I groundwater; and ii) Class II groundwater. D) The final column lists the Acceptable Detection Limit (ADL), only when applicable. 2) Appendix B, Table B is based upon industrial/commercial property use. A) The first and third columns to the right of the chemical name list the soil remediation objectives for the soil ingestion exposure route based on two receptor populations: i) Industrial/commercial; and ii) Construction worker. B) The second and fourth columns to the right of the chemical name list the soil remediation objectives for the outdoor inhalation exposure route based on two receptor populations: i) Industrial/commercial; and ii) Construction worker. C) The fifth and sixth columns to the right of the chemical name list the soil remediation objectives for the soil component of the groundwater ingestion exposure route for two classes of groundwater: i) Class I groundwater; and ii) Class II groundwater. D) The final column lists the acceptable detection limit (ADL), only when applicable. 3) Appendix B, Tables C and D set forth pH specific soil remediation objectives for inorganic and ionizing organic chemicals for the soil component of the groundwater ingestion route. A) Table C sets forth remediation objectives based on Class I groundwater and Table D sets forth remediation objectives based on Class II groundwater. B) The first column in Tables C and D lists the chemical names. C) The second through ninth columns to the right of the chemical names list the pH based soil remediation objectives. 4) For the inorganic chemicals listed in Appendix B, Tables A and B, the soil component of the groundwater ingestion exposure route shall be evaluated using TCLP (SW-846 Method 1311) or SPLP (SW-846 Method 1312), incorporated by reference at Section 742.210 unless a person chooses to evaluate the soil component on the basis of the total amount of contaminant in a soil sample result in accordance with subsection (a)(5) of this Section. 5) For those inorganic and ionizing organic chemicals listed in Appendix B, Tables C and D, if a person elects to evaluate the soil component of the groundwater ingestion exposure route based on the total amount of contaminant in a soil sample result (rather than TCLP or SPLP analysis), the person shall determine the soil pH at the site and then select the appropriate soil remediation objectives based on Class I and Class II groundwaters from Tables C and D, respectively. If the soil pH is less than 4.5 or greater than 9.0, then Tables C and D cannot be used. 6) Unless one or more exposure routes are excluded from consideration under Subpart C, the most stringent soil remediation objective of the exposure routes (i.e., soil ingestion exposure route, outdoor inhalation exposure route, and soil component of the groundwater ingestion exposure route) shall be compared to the concentrations of soil contaminants of concern measured at the site. When using Appendix B, Table B to select soil remediation objectives for the ingestion exposure route and outdoor inhalation exposure routes, the remediation objective shall be the more stringent soil remediation objective of the industrial/commercial populations and construction worker populations. 7) Confirmation sample results may be averaged or soil samples may be composited in accordance with Section 742.225. 8) If a soil remediation objective for a chemical is less than the ADL, the ADL shall serve as the soil remediation objective. b) Groundwater remediation objectives for the groundwater component of the groundwater ingestion exposure route are listed in Appendix B, Table E. However, Appendix B, Table E must be corrected for cumulative effect of mixtures of similar-acting noncarcinogenic chemicals as set forth in Section 742.505(c)(3) and (c)(4). 1) The first column to the right of the chemical name lists groundwater remediation objectives for Class I groundwater, and the second column lists the groundwater remediation objectives for Class II groundwater. 2) To use Appendix B, Table E of this Part, the 35 Ill. Adm. Code 620 classification for groundwater at the site shall be determined. The concentrations of groundwater contaminants of concern at the site are compared to the applicable Tier 1 groundwater remediation objectives for the groundwater component of the groundwater ingestion exposure route in Appendix B, Table E. c) Soil gas remediation objectives for the outdoor inhalation exposure route are listed in Appendix B, Table G. 1) The first column to the right of the chemical name lists the soil gas remediation objectives for residential populations. 2) The second and third columns to the right of the chemical names list the soil gas remediation objectives for the outdoor inhalation exposure route based on two receptor populations: A) Industrial/commercial; and B) Construction worker. d) For contaminants of concern not listed in Appendix B, Tables A, B, E, and G, a person may request site-specific remediation objectives from the Agency or propose site-specific remediation objectives in accordance with 35 Ill. Adm. Code 620, Subpart I of this Part, or both. Section 742.515 Tier 1 Remediation Objectives Tables for the Indoor Inhalation Exposure Route a) For the indoor inhalation exposure route: 1) Appendix B, Tables H and I apply only when the existing or potential building has a full concrete slab-on-grade or a full concrete basement floor and walls; and 2) Institutional controls under Subpart J are required to use remediation objectives in Appendix B, Table H or Table I. b) When the mode of contaminant transport is both diffusion and advection as described in Section 742.505 (i.e., any soil or groundwater contamination is located 5 feet or less, vertically or horizontally, from the existing or potential building or man-made pathway), the remediation objectives for soil gas or groundwater listed in Appendix B, Table H shall be used. 1) The first column to the right of the chemical name lists the soil gas remediation objectives for residential receptors. 2) The second column lists the soil gas remediation objectives for industrial/commercial receptors. 3) The third column lists the groundwater remediation objectives for residential receptors. 4) The fourth column lists the groundwater remediation objectives for industrial/commercial receptors. c) Only when the mode of contaminant transport is diffusion only as described in Section 742.505 (i.e., all soil and groundwater contamination is located more than 5 feet, vertically and horizontally, from the existing or potential building or man-made pathway), the remediation objectives for soil gas and groundwater listed in Appendix B, Table I may be used. 1) The first column to the right of the chemical name lists the soil gas remediation objectives for residential receptors. 2) The second column lists the soil gas remediation objectives for industrial/commercial receptors. 3) The third column lists the groundwater remediation objectives for residential receptors. 4) The fourth column lists the groundwater remediation objectives for industrial/commercial receptors. d) If using Appendix B, Table H, compliance is determined by meeting either the soil gas remediation objectives or the groundwater remediation objectives. e) If using Appendix B, Table I, compliance is determined by meeting both the soil gas remediation objectives and the groundwater remediation objectives. f) For volatile chemicals not listed in Appendix B, Table H or I, a person may request site-specific remediation objectives from the Agency or propose site-specific remediation objectives in accordance with Subpart I, or both. g) As an alternative to using Appendix B, Table I pursuant to subsection (c), it is permissible to use Appendix B, Table H pursuant to subsection (b).
SUBPART F: TIER 2 GENERAL EVALUATION
Section 742.600 Tier 2 Evaluation Overview
a) Tier 2 remediation objectives are developed through the use of equations which allow site-specific data to be used. (See Appendix C, Illustrations A and B.) The equations, identified in Appendix C, Tables A, C, and L may be used to develop Tier 2 remediation objectives.
b) Tier 2 evaluation is only required for contaminants of concern and corresponding exposure routes (except where excluded from further consideration under Subpart C) exceeding the Tier 1 remediation objectives. When conducting Tier 2 evaluations, the values used in the calculations must have the appropriate units of measure as identified in Appendix C, Tables B, D, and M.
c) Any development of remediation objectives using site-specific information or equations outside the Tier 2 framework shall be evaluated under Tier 3.
d) Any development of a remediation objective under Tier 2 shall not use a target hazard quotient greater than one at the point of human exposure or a target cancer risk greater than 1 in 1,000,000 at the point of human exposure.
e) In conducting a Tier 2 evaluation, the following conditions shall be met:
1) For each discrete sample, the total soil contaminant concentration of either a single contaminant or multiple contaminants of concern shall not exceed the attenuation capacity of the soil as provided in Section 742.215.
2) Remediation objectives for noncarcinogenic compounds which affect the same target organ, organ system or similar mode of action shall meet the requirements of Section 742.720.
3) The soil remediation objectives based on the outdoor inhalation exposure route and the soil component of the groundwater ingestion exposure routes shall not exceed the soil saturation limit as provided in Section 742.220.
4) The soil gas remediation objectives based on the indoor and outdoor inhalation exposure routes shall not exceed the soil vapor saturation limit provided pursuant to Section 742.222.
f) Tier 2 remediation objectives for the indoor inhalation exposure route shall be calculated for either soil gas or groundwater if a Qsoil value of 83.33 cm3/sec is used.
g) Tier 2 remediation objectives for the indoor inhalation exposure route shall be calculated for both soil gas and groundwater if a Qsoil value of 0.0 cm3/sec is used.
h) If the calculated Tier 2 soil remediation objective for an applicable exposure route is more stringent than the corresponding Tier 1 remediation objective, then the Tier 1 remediation objective applies.
i) If the calculated Tier 2 soil remediation objective for an exposure route is more stringent than the Tier 1 soil remediation objectives for the other exposure routes, then the Tier 2 calculated soil remediation objective applies and Tier 2 soil remediation objectives for the other exposure routes are not required.
j) If the calculated Tier 2 soil remediation objective is less stringent than one or more of the soil remediation objectives for the remaining exposure routes, then the Tier 2 values are calculated for the remaining exposure routes and the most stringent Tier 2 calculated value applies.
k) If a contaminant has both carcinogenic and noncarcinogenic effects for any applicable exposure route or receptor, remediation objectives shall be calculated for each effect and the more stringent remediation objective shall apply. The toxicological-specific information is described in Section 742.705(d).
l) For the indoor inhalation exposure route:
1) Appendix C, Table L applies only when the existing or potential building has a full concrete slab-on-grade or a full concrete basement floor and walls; and
2) Institutional controls under Subpart J are required to develop remediation objectives pursuant to Appendix C, Table L.
(Source: Amended at 37 Ill. Reg. 7506, effective July 15, 2013)
Section 742.605 Land Use
a) Present and post-remediation land use is evaluated in a Tier 2 evaluation. Acceptable exposure factors for the Tier 2 evaluation for residential, industrial/commercial, and construction worker populations are provided in the far right column of Appendix C, Tables B, D, and M. Use of exposure factors different from those in Appendix C, Tables B, D, and M must be approved by the Agency as part of a Tier 3 evaluation.
b) If a Tier 2 evaluation is based on an industrial/commercial property use, then:
1) Construction worker populations shall also be evaluated, except for the indoor inhalation exposure route; and
2) Institutional controls are required in accordance with Subpart J.
c) For the indoor inhalation exposure route, institutional controls under Subpart J are required to develop remediation objectives pursuant to Appendix C, Table L.
(Source: Amended at 37 Ill. Reg. 7506, effective July 15, 2013)
Section 742.610 Chemical and Site Properties
a) Physical and Chemical Properties of Contaminants
Tier 2 evaluations require information on the physical and chemical properties of the contaminants of concern. The physical and chemical properties used in a Tier 2 evaluation are contained in Appendix C, Table E. If the site has contaminants not included in this table, a person may request the Agency to provide the applicable physical and chemical input values or may propose input values under Subpart I. If a person proposes to apply values other than those in Appendix C, Table E, or those provided by the Agency, the evaluation shall be considered under Tier 3.
b) Soil and Groundwater Parameters
1) A Tier 2 evaluation requires examination of soil and groundwater parameters. The parameters that may be varied, and the conditions under which these parameters are determined as part of Tier 2, are summarized in Appendix C, Tables B, D, and M. If a person proposes to vary site-specific parameters outside of the framework of these tables, the evaluation shall be considered under Tier 3.
2) To determine site-specific physical soil parameters, a minimum of one boring per 0.5 acre of contamination shall be collected. This boring must be deep enough to allow the collection of the required field measurements. The site-specific physical soil parameters must be determined from the portion of the boring representing the stratigraphic units being evaluated. For example, if evaluating the soil component of the groundwater ingestion exposure route, two samples from the boring will be required:
A) A sample of the predominant soil type for the vadose zone; and
B) A sample of the predominant soil type for the saturated zone.
3) A site-specific SSL dilution factor (used in developing soil remediation objectives based upon the protection of groundwater) may be determined by substituting site information in Equation S22 in Appendix C, Table A. To make this demonstration, a minimum of three monitoring wells shall be used to determine the hydraulic gradient. As an alternative, the default dilution factor value listed in Appendix C, Table B may be used. If monitoring wells are used to determine the hydraulic gradient, the soil taken from the borings shall be visually inspected to ensure there are no significant differences in the stratigraphy. If there are similar soil types in the field, one boring shall be used to determine the site-specific physical soil parameters. If there are significant differences, all of the borings shall be evaluated before determining the site-specific physical soil parameters for the site.
4) Not all of the parameters identified in Appendix C, Tables B, D, and M need to be determined on a site-specific basis. A person may choose to collect partial site-specific information and use default values as listed in Appendix C, Tables B, D, and M for the rest of the parameters.
(Source: Amended at 37 Ill. Reg. 7506, effective July 15, 2013)
SUBPART G: TIER 2 SOIL EVALUATION
Section 742.700 Tier 2 Soil and Soil Gas Evaluation Overview
a) Tier 2 remediation objectives are developed through the use of models which allow site-specific data to be considered. Appendix C, Tables A, C, and L list equations that shall be used under a Tier 2 evaluation to calculate soil remediation objectives prescribed by the SSL, RBCA, and modified J&E models, respectively. (See also Appendix C, Illustration A.)
b) Appendix C, Table A lists equations that are used under the SSL model. (See also Appendix C, Illustration A.) The SSL model has equations to evaluate the following human exposure routes:
1) Soil ingestion exposure route;
2) Outdoor Inhalation exposure route; and
3) Soil component of the groundwater ingestion exposure route.
c) Evaluation of the dermal exposure route is not required under the SSL model.
d) Appendix C, Table C lists equations that are used under the RBCA model. (See also Appendix C, Illustration A.) The RBCA model has equations to evaluate human exposure based on the following:
1) The combined exposure routes of outdoor inhalation of vapors and particulates, soil ingestion and dermal contact with soil;
2) The outdoor inhalation exposure route from subsurface soils;
3) Soil component of the groundwater ingestion exposure route; and
4) Groundwater ingestion exposure route.
e) Appendix C, Table L lists equations that are used under the modified J&E model. The modified J&E model has equations to evaluate human exposure by the indoor inhalation exposure route. The modified model allows for the development of soil gas remediation objectives. For the indoor inhalation exposure route:
1) Appendix C, Table L applies only when the existing or potential building has a full concrete slab-on-grade or a full concrete basement floor and walls; and
2) Institutional controls under Subpart J are required to develop soil gas remediation objectives pursuant to Appendix C, Table L.
f) The equations in either Appendix C, Table A, C, or L may be used to calculate remediation objectives for each contaminant of concern under Tier 2, if the following requirements are met:
1) The Tier 2 soil or soil gas remediation objectives for the ingestion and outdoor inhalation exposure routes shall use the applicable equations from the same approach (i.e., SSL equations in Appendix C, Table C). For the indoor inhalation exposure route, only the J&E equations can be used.
2) The equations used to calculate soil remediation objectives for the soil component of the groundwater ingestion exposure route are not dependent on the approach utilized to calculate soil remediation objectives for the other exposure routes. For example, it is acceptable to use the SSL equations for calculating Tier 2 soil remediation objectives for the ingestion and outdoor inhalation exposure routes, and the RBCA equations for calculating Tier 2 soil remediation objectives for the soil component of the groundwater ingestion exposure route.
3) Combining equations from Appendix C, Tables A, C, and L to form a new model is not allowed. In addition, Appendix C, Tables A, C, and L must use their own applicable parameters identified in Appendix C, Tables B, D, and M, respectively.
g) In calculating soil or soil gas remediation objectives for industrial/commercial property use, applicable calculations shall be performed twice: once using industrial/commercial population default values and once using construction worker population default values. The more stringent soil or soil gas remediation objectives derived from these calculations must be used for further Tier 2 evaluations. The indoor inhalation exposure route does not apply to the construction worker population.
h) Tier 2 data sheets provided by the Agency shall be used to present calculated Tier 2 remediation objectives, if required by the particular program for which remediation is being performed.
i) The RBCA equations which rely on the parameter Soil Water Sorption Coefficient (ks) can only be used for ionizing organics and inorganics by substituting values for ks from Appendix C, Tables I and J, respectively. This will also require the determination of a site-specific value for soil pH.
j) For the outdoor inhalation exposure route, it is acceptable to use either Section 742.710 to develop a soil remediation objective or Section 742.712 to develop a soil gas remediation objective to determine compliance with the pathway.
(Source: Amended at 37 Ill. Reg. 7506, effective July 15, 2013)
Section 742.705 Parameters for Soil Remediation Objective Equations
a) Appendix C, Tables B, D, and M list the input parameters for the SSL, RBCA, and J&E equations, respectively. The first column lists each symbol as it is presented in the equation. The next column defines the parameters. The third column shows the units for the parameters. The fourth column identifies where information on the parameters can be obtained (i.e., field measurement, applicable equations, reference source, or default value). The last column identifies how the parameters can be generated.
b) Default Values
Default values are numerical values specified for use in the Tier 2 equations. The fourth column of Appendix C, Tables B, D, and M denotes if the default values are from the SSL model, RBCA model, modified J&E model or some other source. The last column of Appendix C, Tables B, D, and M lists the numerical values for the default values used in the SSL, RBCA, and J&E equations, respectively.
c) Site-specific Information
Site-specific information is a parameter measured, obtained, or determined from the site to calculate Tier 2 remediation objectives. The fourth column of Appendix C, Tables B, D, and M identifies those site-specific parameters that may require direct field measurement. For some parameters, numerical default inputs have been provided in the last column of Appendix C, Tables B, D, and M to substitute for site-specific information. In some cases, information on the receptor or soil type is required to select the applicable numerical default inputs. Site-specific information includes:
1) Physical soil parameters identified in Appendix C, Table F. The second column identifies the location where the sample is to be collected. Acceptable methods for measuring or calculating these soil parameters are identified in the last column of Appendix C, Table F;
2) Institutional controls or engineered barriers, pursuant to Subparts J and K, describe applicable institutional controls and engineered barriers under a Tier 2 evaluation; and
3) Land use classification
d) Toxicological-specific Information
1) Toxicological-specific information is used to calculate Tier 2 remediation objectives for the following parameters, if applicable:
A) Oral Chronic Reference Dose (RfDo, expressed in mg/kg-d);
B) Oral Subchronic Reference Dose (RfDs, expressed in mg/kg-d, shall be used for construction worker remediation objective calculations);
C) Oral Slope Factor (SFo, expressed in (mg/kg-d)-1);
D) Inhalation Unit Risk Factor (URF expressed in ( m g/m3)-1);
E) Inhalation Chronic Reference Concentration (RfC, expressed in mg/m3);
F) Inhalation Subchronic Reference Concentration (RfCs, expressed in mg/m3, shall be used for construction worker remediation objective calculations);
G) Inhalation Chronic Reference Dose (RfDi, expressed in mg/kg-d);
H) Inhalation Subchronic Reference Dose (RfDis, expressed in mg/kg-d, shall be used for construction worker remediation objective calculations); and
I) Inhalation Slope Factor (SFi, expressed in (mg/kg-d)-1);
2) Toxicological information can be obtained by following the guidelines in OSWER Directive 9285.7-53, as incorporated by reference in Section 742.210, or the program under which the remediation is being performed.
e) Chemical-specific Information
Chemical-specific information used to calculate Tier 2 remediation objectives is listed in Appendix C, Table E.
f) Calculations
Calculating numerical values for some parameters requires the use of equations listed in Appendix C, Tables A, C, and L. The parameters that are calculated are listed in Appendix C, Tables B, D, and M.
(Source: Amended at 37 Ill. Reg. 7506, effective July 15, 2013)
Section 742.710 SSL Soil Equations
a) This Section sets forth the equations and parameters used to develop Tier 2 soil remediation objectives for the three exposure routes using the SSL approach.
b) Soil Ingestion Exposure Route
1) Equations S1 through S3 form the basis for calculating Tier 2 remediation objectives for the soil ingestion exposure route using the SSL approach. Equation S1 is used to calculate soil remediation objectives for noncarcinogenic contaminants. Equations S2 and S3 are used to calculate soil remediation objectives for carcinogenic contaminants for residential populations and industrial/commercial and construction worker populations, respectively.
2) For Equations S1 through S3, the SSL default values cannot be modified with site-specific information.
c) Outdoor Inhalation Exposure Route
1) Equations S4 through S16, S26 and S27 are used to calculate Tier 2 soil remediation objectives for the outdoor inhalation exposure route using the SSL approach. To address this exposure route, organic contaminants and mercury must be evaluated separately from fugitive dust using their own equations set forth in subsections (c)(2) and (c)(3), respectively.
2) Organic Contaminants
A) Equations S4 through S10 are used to calculate Tier 2 soil remediation objectives for organic contaminants and mercury based on the outdoor inhalation exposure route. Equation S4 is used to calculate soil remediation objectives for noncarcinogenic organic contaminants in soil for residential and industrial/commercial populations. Equation S5 is used to calculate soil remediation objectives for noncarcinogenic organic contaminants and mercury in soil for construction worker populations. Equation S6 is used to calculate soil remediation objectives for carcinogenic organic contaminants in soil for residential and industrial/commercial populations. Equation S7 is used to calculate soil remediation objectives for carcinogenic organic contaminants in soil for construction worker populations. Equations S8 through S10, S27 and S28 are used for calculating numerical values for some of the parameters in Equations S4 through S7.
B) For Equation S4, a numerical value for the Volatilization Factor (VF) can be calculated in accordance with subsection (c)(2)(F). The remaining parameters in Equation S4 have either SSL default values listed in Appendix C, Table B or toxicological-specific information (i.e., RfC), which can be obtained by following the guidelines in OSWER Directive 9285.7-53, as incorporated by reference in Section 742.210 or requested from the program under which the remediation is being performed.
C) For Equation S5, a numerical value for the Volatilization Factor adjusted for Agitation (VF') can be calculated in accordance with subsection (c)(2)(G). The remaining parameters in Equation S5 have either SSL default values listed in Appendix C, Table B or toxicological-specific information (i.e., RfC), which can be obtained by following the guidelines in OSWER Directive 9285.7-53, as incorporated by reference in Section 742.210 or requested from the program under which the remediation is being performed.
D) For Equation S6, a numerical value for VF can be calculated in accordance with subsection (c)(2)(F). The remaining parameters in Equation S6 have either default values listed in Appendix C, Table B or toxicological-specific information (i.e., URF), which can be obtained by following the guidelines in OSWER Directive 9285.7-53, as incorporated by reference in Section 742.210 or requested from the program under which the remediation is being performed.
E) For Equation S7, a numerical value for VF' can be calculated in accordance with subsection (c)(2)(G). The remaining parameters in Equation S7 have either default values listed in Appendix C, Table B or toxicological-specific information (i.e., URF), which can be obtained by following the guidelines in OSWER Directive 9285.7-53, as incorporated by reference in Section 742.210 or requested from the program under which the remediation is being performed.
F) The VF can be calculated for residential and industrial/commercial populations using one of the following equations based on the information known about the contaminant source and receptor population:
i) Equation S8, in conjunction with Equation S10, is used to calculate VF assuming an infinite source of contamination; or
ii) If the area and depth of the contaminant source are known or can be estimated reliably, mass limit considerations may be used to calculate VF using Equation S26.
G) The VF' can be calculated for the construction worker populations using one of the following equations based on the information known about the contaminant source:
i) Equation S9 is used to calculate VF' assuming an infinite source of contamination; or
ii) If the area and depth of the contaminant source are known or can be estimated reliably, mass limit considerations may be used to calculate VF' using Equation S27.
3) Fugitive Dust
A) Equations S11 through S16 are used to calculate Tier 2 soil remediation objectives using the SSL fugitive dust model for the outdoor inhalation exposure route. Equation S11 is used to calculate soil remediation objectives for noncarcinogenic contaminants in fugitive dust for residential and industrial/commercial populations. Equation S12 is used to calculate soil remediation objectives for noncarcinogenic contaminants in fugitive dust for construction worker populations. Equation S13 is used to calculate soil remediation objectives for carcinogenic contaminants in fugitive dust for residential and industrial/commercial populations. Equation S14 is used to calculate soil remediation objectives for carcinogenic contaminants in fugitive dust for construction worker populations. Equations S15 and S16 are used for calculating numerical quantities for some of the parameters in Equations S11 through S14.
B) For Equation S11, a numerical value can be calculated for the Particulate Emission Factor (PEF) using Equation S15. This equation relies on various input parameters from a variety of sources. The remaining parameters in Equation S11 have either SSL default values listed in Appendix C, Table B or toxicological-specific information (i.e., RfC), which can be obtained by following the guidelines in OSWER Directive 9285.7-53, as incorporated by reference in Section 742.210 or requested from the program under which the remediation is being performed.
C) For Equation S12, a numerical value for the Particulate Emission Factor for Construction Worker (PEF') can be calculated using Equation S16. The remaining parameters in Equation S12 have either SSL default values listed in Appendix C, Table B or toxicological-specific information (i.e., RfC), which can be obtained by following the guidelines in OSWER Directive 9285.7-53, as incorporated by reference in Section 742.210 or requested from the program under which the remediation is being performed.
D) For Equation S13, a numerical value for PEF can be calculated using Equation S15. The remaining parameters in Equation S13 have either default values listed in Appendix C, Table B or toxicological-specific information (i.e., URF), which can be obtained by following the guidelines in OSWER Directive 9285.7-53, as incorporated by reference in Section 742.210 or requested from the program under which the remediation is being performed.
E) For Equation S14, a numerical value for PEF' can be calculated using Equation S16. The remaining parameters in Equation S14 have either default values listed in Appendix C, Table B or toxicological-specific information (i.e., URF), which can be obtained by following the guidelines in OSWER Directive 9285.7-53, as incorporated by reference in Section 742.210 or requested from the program under which the remediation is being performed.
d) Soil Component of the Groundwater Ingestion Exposure Route
The Tier 2 remediation objective for the soil component of the groundwater ingestion exposure route can be calculated using one of the following equations based on the information known about the contaminant source and receptor population:
1) Equation S17 is used to calculate the remediation objective assuming an infinite source of contamination.
A) The numerical quantities for four parameters in Equation S17, the Target Soil Leachate Concentration (Cw), Soil-Water Partition Coefficient (Kd) for non-ionizing organics, Water-Filled Soil Porosity Theta w ( q w) and Air-Filled Soil Porosity Theta a ( q a), are calculated using Equations S18, S19, S20 and S21, respectively. Equations S22, S23, S24 and S25 are also needed to calculate numerical values for Equations S18 and S21. The pH-dependent Kd values for ionizing organics can be calculated using Equation S19 and the pH-dependent Koc values in Appendix C, Table I.
B) The remaining parameters in Equation S17 are Henry's Law Constant (H'), a chemical specific value listed in Appendix C, Table E and Dry Soil Bulk Density ( r b), a site-specific based value listed in Appendix C, Table B.
C) The default value for GWobj is the Tier 1 groundwater objective. For chemicals for which there is no Tier 1 groundwater remediation objective, the value for GWobj shall be the concentration determined according to the procedures specified in 35 Ill. Adm. Code 620, Subpart F. As an alternative to using Tier 1 groundwater remediation objectives or concentrations determined according to the procedures specified in 35 Ill. Adm. Code 620, Subpart F, GWobj may be developed using Equations R25 and R26, if approved institutional controls are in place as required in Subpart J.
2) If the area and depth of the contaminant source are known or can be estimated reliably, mass limit considerations may be used to calculate the remediation objective for this exposure route using Equation S28. The parameters in Equation S28 have default values listed in Appendix C, Table B.
(Source: Amended at 37 Ill. Reg. 7506, effective July 15, 2013)
Section 742.712 SSL Soil Gas Equation for the Outdoor Inhalation Exposure Route
a) This Section sets forth the equation and parameters used to develop Tier 2 soil gas remediation objectives for the outdoor inhalation exposure route using the SSL approach.
b) Equation S30 is used to calculate Tier 2 soil gas remediation objectives for the outdoor inhalation exposure route for residential, industrial/commercial, and construction worker populations.
c) Equations S4 through S16, S26 and S27, which calculate Tier 2 soil remediation objectives as described in Section 742.710(c), form the basis for developing the Tier 2 soil gas remediation objectives for the outdoor inhalation exposure route using the SSL model.
d) The remaining parameters used to calculate Equation S30 are listed in Appendix C, Table B, except for Dimensionless Henry’s Law Constant (25 ° C), a chemical specific value listed in Appendix C, Table E.
(Source: Added at 37 Ill. Reg. 7506, effective July 15, 2013)
Section 742.715 RBCA Soil Equations
a) This Section presents the RBCA model and describes the equations and parameters used to develop Tier 2 soil remediation objectives.
b) Ingestion, Outdoor Inhalation, and Dermal Contact
1) The two sets of equations in subsections (b)(2) and (b)(3) shall be used to generate Tier 2 soil remediation objectives for the combined ingestion, outdoor inhalation, and dermal contact with soil exposure routes.
2) Combined Exposure Routes of Soil Ingestion, Outdoor Inhalation of Vapors and Particulates, and Dermal Contact with Soil
A) Equations R1 and R2 form the basis for deriving Tier 2 remediation objectives for the set of equations that evaluates the combined exposure routes of soil ingestion, outdoor inhalation of vapors and particulates, and dermal contact with soil using the RBCA approach. Equation R1 is used to calculate soil remediation objectives for carcinogenic contaminants. Equation R2 is used to calculate soil remediation objectives for noncarcinogenic contaminants. Soil remediation objectives for the outdoor inhalation exposure route from subsurface soils must also be calculated in accordance with the procedures outlined in subsection (b)(3) of this Section and compared to the values generated from Equations R1 or R2. The smaller value (i.e., R1 and R2 compared to R7 and R8, respectively) from these calculations is the Tier 2 soil remediation objective for the combined exposure routes of soil ingestion, outdoor inhalation, and dermal contact with soil.
B) In Equation R1, numerical values are calculated for two parameters:
i) The volatilization factor for surficial soils (VFss) using Equations R3 and R4; and
ii) The volatilization factor for surficial soils regarding particulates (VFp) using Equation R5.
C) VFss uses Equations R3 and R4 to derive a numerical value. Equation R3 requires the use of Equation R6. Both equations must be used to calculate the VFss. The lowest calculated value from these equations must be substituted into Equation R1.
D) The remaining parameters in Equation R1 have either default values listed in Appendix C, Table D or toxicological-specific information (i.e., SFo, SFi), which can be obtained by following the guidelines in OSWER Directive 9285.7-53, as incorporated by reference in Section 742.210 or requested from the program under which the remediation is being performed.
E) For Equation R2, the parameters VFss and VFp are calculated. The remaining parameters in Equation R2 have either default values listed in Appendix C, Table D or toxicological-specific information (i.e., RfDo, RfDi), which can be obtained by following the guidelines in OSWER Directive 9285.7-53, as incorporated by reference in Section 742.210 or requested from the program under which the remediation is being performed.
F) For chemicals other than inorganics which do not have default values for the dermal absorption factor (RAFd) in Appendix C, Table D a dermal absorption factor of 0.5 shall be used for Equations R1 and R2. For inorganics, dermal absorption may be disregarded (i.e., RAFd = 0).
3) Outdoor Inhalation Exposure Route from Subsurface Soils (soil below one meter)
A) Equations R7 and R8 form the basis for deriving Tier 2 remediation objectives for the outdoor inhalation exposure route from subsurface soils using the RBCA approach. Equation R7 is used to calculate soil remediation objectives for carcinogenic contaminants. Equation R8 is used to calculate soil remediation objectives for noncarcinogenic contaminants.
B) For Equation R7, the carcinogenic risk-based screening level for air (RBSLair) and the volatilization factor for soils below one meter to ambient air (VFsamb) have numerical values that are calculated using Equations R9 and R11, respectively. Both equations rely on input parameters from a variety of sources.
C) The noncarcinogenic risk-based screening level for air (RBSLair) and the volatilization factor for soils below one meter to ambient air (VFsamb) in Equation R8 have numerical values that can be calculated using Equations R10 and R11, respectively.
c) Soil Component of the Groundwater Ingestion Exposure Route
1) Equation R12 forms the basis for deriving Tier 2 remediation objectives for the soil component of the groundwater ingestion exposure route using the RBCA approach. The parameters, groundwater at the source (GWsource) and Leaching Factor (LFsw), have numerical values that are calculated using Equations R13 and R14, respectively.
2) Equation R13 requires numerical values that are calculated using Equation R15.
3) Equation R14 requires numerical values that are calculated using Equations R21, R22, and R24. For non-ionizing organics, the Soil Water Sorption Coefficient (ks) shall be calculated using Equation R20. For ionizing organics and inorganics, the values for ks are listed in Appendix C, Tables I and J, respectively. The pH-dependent ks values for ionizing organics can be calculated using Equation R20 and the pH-dependent Koc values in Appendix C, Table I. The remaining parameters in Equation R14 are field measurements or default values listed in Appendix C, Table D.
d) The default value for GWcomp is the Tier 1 groundwater remediation objective. For chemicals for which there is no Tier 1 groundwater remediation objective, the value for GWcomp shall be the concentration determined according to the procedures specified in 35 Ill. Adm. Code 620, Subpart F. As an alternative to using the above concentrations, GWcomp may be developed using Equations R25 and R26, if approved institutional controls are in place as may be required in Subpart J.
(Source: Amended at 37 Ill. Reg. 7506, effective July 15, 2013)
Section 742.717 J&E Soil Gas Equations for the Indoor Inhalation Exposure Route
a) This Section sets forth the equations and parameters to be used to develop Tier 2 soil gas remediation objectives for the indoor inhalation exposure route using the modified J&E model.
b) Equations J&E1 and J&E2 calculate, for carcinogens and noncarcinogens, respectively, an acceptable concentration of the contaminant of concern in indoor air that adequately protects humans who inhale this air. Equation J&E3 converts indoor air concentrations from parts per million volume to milligrams per cubic meter.
c) Equation J&E4 calculates an acceptable concentration of the contaminant of concern in the soil gas at the source of contamination. This calculation is made using:
1) an attenuation factor developed in accordance with Equations J&E7 through 18; and
2) the acceptable concentration of the contaminant of concern in indoor air calculated in accordance with Equation J&E1 (for carcinogens) or J&E2 (for noncarcinogens).
d) The attenuation factor (Equation J&E7 or J&E8) accounts for the following processes:
1) Migration of contaminants from the source upwards through the vadose zone;
2) Migration of contaminants through the earthen filled cracks in the building’s full concrete slab-on-grade or full concrete basement floor and walls; and
3) Mixing of the contaminants with air inside the building.
e) Equation J&E7 must be used when the mode of contaminant transport is both diffusion and advection. In this scenario, the Qsoil value equals 83.33 cm3/sec as described in Section 742.505.
f) Equation J&E8 may be used only when the mode of contaminant transport is diffusion only. In this scenario, the Qsoil value equals 0.0 cm3/sec as described in Section 742.505. As an alternative to using Equation J&E8 pursuant to this subsection, it is permissible to use Equation J&E7, in which case the Qsoil value equals 83.33 cm3/sec as described in Section 742.505.
g) Equations J&E9a through J&E18 calculate input parameters for either Equation J&E7 or J&E8 (the equations used to calculate an attenuation factor). These equations assume there are “n” different soil layers between the source of the contamination and the floor of the building. Equations J&E11, 16, 17 and 18 shall be used to calculate the needed parameters for each of the n layers (the general soil layer is referred to as soil layer “i” and i = 1, 2, . . . n). Equations J&E16, 17, and 18 shall also be used to calculate needed parameters for the soil in the cracks of the building’s full concrete slab-on-grade or full concrete basement floor and walls (it is through these cracks that contaminated soil gas is assumed to flow from the subsurface into the building). As reflected in Equation J&E14, the only crack assumed to be present is the floor-wall seam gap. To calculate the surface area of the enclosed space at or below grade, Equation J&E12a shall be used for a building with a full concrete slab-on-grade and Equation J&E12b shall be used for a building with a full concrete basement floor and walls.
h) The default representative subsurface temperature for Henry’s Law Constant is 13 ° C. This value shall be used, as appropriate, in all calculations needed to represent the system by which contaminants migrate through the subsurface.
i) The calculated soil gas remediation objective shall be compared with the soil vapor saturation limit (Cvsat, Equation J&E5) for each volatile chemical. The calculated Cvsat shall use the default representative subsurface temperature specified in subsection (h). If the calculated soil gas remediation objective is greater than Cvsat, then Cvsat is used as the soil gas remediation objective.
j) The calculated soil gas remediation objective shall be compared to concentrations of soil gas collected at a depth at least 3 feet below ground surface and above the saturated zone. If a valid sample cannot be collected, a soil gas sampling plan shall be approved by the Agency under Tier 3.
(Source: Added at 37 Ill. Reg. 7506, effective July 15, 2013)
Section 742.720 Chemicals with Cumulative Noncarcinogenic Effects
Appendix A, Table E lists the groups of chemicals from Appendix B, Tables A and B that have remediation objectives based on noncarcinogenic toxicity and that affect the same target organ. If more than one chemical detected at a site affects the same target organ (i.e., has the same critical effect as defined by the RfD), the initially calculated remediation value for each chemical in the group shall be corrected for cumulative effects by one of the following two methods:
a) Calculate the weighted average using the following equations:
Wave =
where:
Wave= Weighted Average
x1 through xa = Concentration of each individual contaminant at
the location of concern. Note that, depending on the target organ/mode of action, the actual number of contaminants will range from 2 to 14.
CUOxa = A Tier 2 remediation objective must be developed
for each xa.
If the value of the weighted average calculated in accordance with the equations above is less than or equal to 1.0, then the remediation objectives are met for those chemicals.
If the value of the weighted average calculated in accordance with the equations above is greater than 1.0, then additional remediation must be carried out until the level of contaminants remaining in the remediated area has a weighted average calculated in accordance with the equation above less than or equal to one.
b) Divide each individual chemical's remediation objective by the number of chemicals in that specific target organ group that were detected at the site. Each of the contaminant concentrations at the site is then compared to the remediation objectives that have been adjusted to account for this potential additivity. For the noncarcinogenic contaminants listed in Appendix A, Table E, a respective soil remediation objective need be no lower than the respective value listed in Appendix B, Table A or B.
SUBPART H: TIER 2 GROUNDWATER EVALUATION
Section 742.800 Tier 2 Groundwater Evaluation Overview
If the contaminant concentrations in the groundwater exceed the applicable Tier 1 remediation objectives, a person has the following options:
a) Demonstrate that the groundwater ingestion exposure route is excluded from consideration pursuant to Subpart C;
b) Demonstrate that the groundwater contamination is at or below area background concentrations in accordance with Subpart D and, if necessary, an institutional control restricting usage of the groundwater is in place in accordance with Subpart J;
c) Remediate to Tier 1 remediation objectives;
d) Propose and obtain approval of Tier 2 groundwater remediation objectives in accordance with Section 742.805 and remediate to that level, if necessary;
e) Conduct a Tier 3 evaluation in accordance with Subpart I; or
f) Obtain approval from the Board to:
1) Reclassify the groundwater pursuant to 35 Ill. Adm. Code 620.260; or
2) Use an adjusted standard pursuant to Section 28.1 of the Act. [415 ILCS 5/28.1].
Section 742.805 Tier 2 Groundwater Remediation Objectives
a) To develop a groundwater remediation objective under this Section that exceeds the applicable Tier 1 groundwater remediation objective, or for which there is no Tier I groundwater remediation objective, a person may request approval from the Agency if the person has performed the following:
1) Identified the horizontal and vertical extent of groundwater for which the Tier 2 groundwater remediation objective is sought;
2) Taken corrective action, to the maximum extent practicable to remove any free product;
3) Using Equation R26 in accordance with Section 742.810, demonstrated that the concentration of any contaminant of concern in groundwater will meet:
A) The applicable Tier 1 groundwater remediation objective at the point of human exposure; or
B) For any contaminant of concern for which there is no Tier 1 groundwater remediation objective, the concentration determined according to the procedures specified in 35 Ill. Adm. Code 620 at the point of human exposure. A person may request the Agency to provide these concentrations or may propose these concentrations under Subpart I;
4) Using Equation R26 in accordance with Section 742.810, demonstrated that the concentration of any contaminant of concern in groundwater within the minimum or designated maximum setback zone of an existing potable water supply well will meet the applicable Tier 1 groundwater remediation objective or, if there is no Tier 1 groundwater remediation objective, the concentration determined according to the procedures specified in 35 Ill. Adm. Code 620. A person may request the Agency to provide these concentrations or may propose these concentrations under Subpart I;
5) Using Equation R26 in accordance with Section 742.810, demonstrated that the concentration of any contaminant of concern in groundwater discharging into a surface water will meet the applicable water quality standard under 35 Ill. Adm. Code 302;
6) Demonstrated that the source of the release is not located within the minimum or designated maximum setback zone or within a regulated recharge area of an existing potable water supply well; and
7) If the selected corrective action includes an engineered barrier as set forth in Subpart K to minimize migration of contaminants of concern from the soil to the groundwater, demonstrated that the engineered barrier will remain in place for post-remediation land use through an institutional control as set forth in Subpart J.
b) A groundwater remediation objective that exceeds the water solubility of that
chemical (refer to Appendix C, Table E for solubility values) is not allowed.
c) The contaminants of concern for which a Tier 1 remediation objective has been developed shall be included in any mixture of similar-acting chemicals under consideration in Tier 2. The evaluation of 35 Ill. Adm. Code 620.615 regarding mixtures of similar-acting chemicals shall be considered satisfied for Class I groundwater at the point of human exposure if either of the following requirements are achieved:
1) Calculate the weighted average using the following equations:
where:
Wave = Weighted Average
x1 through xa = Concentration of each individual contaminant at the location of concern. Note that, depending on the target organ, the actual number of contaminants will range from 2 to 33. CUOxa = A Tier 1 or Tier 2 remediation objective must be developed for each xa. A) If the value of the weighted average calculated in accordance with the equations above is less than or equal to 1.0, then the remediation objectives are met for those chemicals. B) If the value of the weighted average calculated in accordance with the equations above is greater than 1.0, then additional remediation must be carried out until the level of contaminants remaining in the remediated area has a weighted average calculated in accordance with the equation above less than or equal to one; or 2) Divide each individual chemical's remediation objective by the number of chemicals in that specific target organ group that were detected at the site. Each of the contaminant concentrations at the site is then compared to the remediation objectives that have been adjusted to account for this potential additivity. d) The evaluation of 35 Ill. Adm. Code 620.615 regarding mixtures of similar-acting chemicals is considered satisfied if the cumulative risk from any contaminants of concern listed in Appendix A, Table I, plus any other contaminants of concern detected in groundwater and listed in Appendix A, Table F as affecting the same target organ/organ system as the contaminants of concern detected from Appendix A, Table I, does not exceed 1 in 10,000. e) Groundwater remediation objectives for the indoor inhalation exposure route shall be developed in accordance with Section 742.812. For the indoor inhalation exposure route: 1) Appendix C, Table L applies only when the existing or potential building has a full concrete slab-on-grade or a full concrete basement floor and walls; and 2) Institutional controls under Subpart J are required to develop groundwater remediation objectives pursuant to Appendix C, Table L. (Source: Amended at 37 Ill. Reg. 7506, effective July 15, 2013)
Section 742.810 RBCA Calculations to Predict Impacts from Remaining Groundwater Contamination
a) Equation R26 predicts the contaminant concentration along the centerline of a groundwater plume emanating from a vertical planar source in the aquifer (dimensions Sw wide and Sd deep). This model accounts for both three-dimensional dispersion (x is the direction of groundwater flow, y is the other horizontal direction, and z is the vertical direction) and biodegradation.
1) The parameters in this equation are:
X = distance from the planar source to the location of concern, along the centerline of the groundwater plume (i.e., y=0, z=0)
Cx = the concentration of the contaminant at a distance X from the source, along the centerline of the plume
Csource = the greatest potential concentration of the contaminant of concern in the groundwater at the source of the contamination, based on the concentrations of contaminants in groundwater due to the release and the projected concentration of the contaminant migrating from the soil to the groundwater. As indicated above, the model assumes a planar source discharging groundwater at a concentration equal to Csource.
ax = dispersivity in the x direction (i.e., Equation R16)
ay = dispersivity in the y direction (i.e., Equation R17)
az = dispersivity in the z direction (i.e., Equation R18)
U = specific discharge (i.e., actual groundwater flow velocity through a porous medium; takes into account the fact that the groundwater actually flows only through the pores of the subsurface materials) where the aquifer hydraulic conductivity (K), the hydraulic gradient (I) and the total soil porosity q T must be known (i.e., Equation R19)
l= first order degradation constant obtained from Appendix C, Table E or from measured groundwater data
Sw = width of planar groundwater source in the y direction
Sd = depth of planar groundwater source in the z direction
2) The following parameters are determined through field measurements: U, K, I, q T, Sw, Sd.
A) The determination of values for U, K, I and q T can be obtained through the appropriate laboratory and field techniques;
B) From the immediate down-gradient edge of the source of the groundwater contamination values for Sw and Sd shall be determined. Sw is defined as the width of groundwater at the source which exceeds the Tier 1 groundwater remediation objective. Sd is defined as the depth of groundwater at the source which exceeds the Tier 1 groundwater remediation objective; and
C) Total soil porosity can also be calculated using Equation R23.
b) Once values are obtained for all the input parameters identified in subsection (a) of this Section, the contaminant concentration Cx along the centerline of the plume at a distance X from the source shall be calculated so that X is the distance from the down-gradient edge of the source of the contamination at the site to the point where the contaminant concentration is equal to the Tier 1 groundwater remediation objective or concentration determined according to the procedures specified in 35 Ill. Adm. Code 620, Subpart F.
1) If there are any potable water supply wells located within the calculated distance X, then the Tier 1 groundwater remediation objective or concentration shall be met at the edge of the minimum or designated maximum setback zone of the nearest potable water supply down-gradient of the source. To demonstrate that a minimum or maximum setback zone of a potable water supply well will not be impacted above the applicable Tier 1 groundwater remediation objective or concentration determined according to the procedures specified in 35 Ill. Adm. Code 620, Subpart F, X shall be the distance from the Csource location to the edge of the setback zone.
2) To demonstrate that no surface water is adversely impacted, X shall be the distance from the down-gradient edge of the source of the contamination site to the nearest surface water body. This calculation must show that the contaminant in the groundwater at this location (Cx) does not exceed the applicable water quality standard.
(Source: Amended at 37 Ill. Reg. 7506, effective July 15, 2013)
Section 742.812 J&E Groundwater Equations for the Indoor Inhalation Exposure Route
Groundwater remediation objectives for the indoor inhalation exposure route are calculated using the modified J&E model as described in Section 742.717, except as follows:
a) In Equation J&E9a, the total number of layers of soil that contaminants migrate through from the source to the building shall include a capillary fringe layer.
b) The thickness of the capillary fringe layer is 37.5 cm.
c) The volumetric water content of the capillary fringe shall be 90 % of the total porosity of the soil that comprises the capillary fringe.
d) Equations J&E7 and J&E8 calculate an acceptable groundwater remediation objective.
1) This calculation is made using:
A) the soil gas remediation objective calculated in accordance with Equation J&E4; and
B) the assumption that this gas is in equilibrium with any contamination in the groundwater.
2) Equation J&E7 must be used when the mode of contaminant transport is both diffusion and advection. In this scenario, the Qsoil value equals 83.33 cm3/sec as described in Section 742.505.
3) Equation J&E8 may be used only when the mode of contaminant transport is diffusion only. In this scenario, the Qsoil value equals 0.0 cm3/sec as described in Section 742.505. As an alternative to using Equation J&E8 pursuant to this subsection, it is permissible to use Equation J&E7, in which case the Qsoil value equals 83.33 cm3/sec as described in Section 742.505.
e) A groundwater remediation objective that exceeds the water solubility of that chemical (refer to Appendix C, Table E for solubility values) is not allowed. If the calculated groundwater remediation objective is greater than the water solubility of that chemical, then the solubility is used as the groundwater remediation objective.
(Source: Added at 37 Ill. Reg. 7506, effective July 15, 2013)
SUBPART I: TIER 3 EVALUATION
Section 742.900 Tier 3 Evaluation Overview
a) Tier 3 sets forth a flexible framework to develop remediation objectives outside of the requirements of Tiers 1 and 2. Although Tier 1 and Tier 2 evaluations are not prerequisites to conduct Tier 3 evaluations, data from Tier 1 and Tier 2 can assist in developing remediation objectives under a Tier 3 evaluation.
b) The level of detail required to adequately characterize a site depends on the particular use of Tier 3. Tier 3 can require additional investigative efforts beyond those described in Tier 2 to characterize the physical setting of the site. However, in situations where remedial efforts have simply reached a physical obstruction additional investigation may not be necessary for a Tier 3 submittal.
c) Situations that can be considered for a Tier 3 evaluation include, but are not limited to:
1) Modification of parameters not allowed under Tier 2;
2) Use of models different from those used in Tier 2;
3) Use of additional site data, such as results of indoor air sampling, to improve or confirm predictions of exposed receptors to contaminants of concern;
4) Analysis of site-specific risks using formal risk assessment, probabilistic data analysis, and sophisticated fate and transport models (e.g., requesting a target hazard quotient greater than 1 or a target cancer risk greater than 1 in 1,000,000);
5) Requests for site-specific remediation objectives because an assessment indicates further remediation is not practical;
6) Incomplete human exposure pathways not excluded under Subpart C;
7) Use of toxicological-specific information not available from the sources listed in Tier 2;
8) Land uses which are substantially different from the assumed residential or industrial/commercial property uses of a site (e.g., a site will be used for recreation in the future and cannot be evaluated in Tier 1 or 2);
9) Requests for site-specific remediation objectives that exceed Tier 1 groundwater remediation objectives so long as the following is demonstrated:
A) To the extent practical, the exceedance of the groundwater quality standard has been minimized and beneficial use appropriate to the groundwater that was impacted has been returned; and
B) Any threat to human health or the environment has been minimized [415 ILCS 5/58.5(d)(4)(A)]; and
10) Use of building control technologies, other than those described in Subpart L, to prevent completion of the indoor inhalation exposure route.
d) For requests of a target cancer risk ranging between 1 in 1,000,000 and 1 in 10,000 at the point of human exposure or a target hazard quotient greater than 1 at the point of human exposure, the requirements of Section 742.915 shall be followed. Requests for a target cancer risk exceeding 1 in 10,000 at the point of human exposure are not allowed.
e) Requests for approval of a Tier 3 evaluation must be submitted to the Agency for review under the specific program under which remediation is performed. When reviewing a submittal under Tier 3, the Agency shall consider whether the interpretations and conclusions reached are supported by the information gathered [415 ILCS 58.7(e)(1)]. The Agency shall approve a Tier 3 evaluation if the person submits the information required under this Part and establishes through such information that public health is protected and that specified risks to human health and the environment have been minimized.
f) If contaminants of concern include polychlorinated biphenyls (PCBs), requests for approval of a Tier 3 evaluation must additionally address the applicability of 40 CFR 761.
(Source: Amended at 37 Ill. Reg. 7506, effective July 15, 2013)
Section 742.905 Modifications of Parameters
Any proposed changes to Tier 2 parameters which are not provided for in Tier 2 shall be submitted to the Agency for review and approval. A submittal under this Section shall include the following information:
a) The justification for the modification; and
b) The technical and mathematical basis for the modification.
Section 742.910 Alternative Models
Any proposals for the use of models other than those specified in Tier 2 shall be submitted to the Agency for review and approval. A submittal under this Section shall include the following information:
a) Physical and chemical properties of contaminants of concern;
b) Contaminant movement properties;
c) Contaminant availability to receptors;
d) Receptor exposure to the contaminants of concern;
e) Mathematical and technical justification for the model proposed;
f) A licensed copy of the model, if the Agency does not have a licensed copy of the model currently available for use; and
g) Demonstration that the models were correctly applied.
Section 742.915 Formal Risk Assessments
A comprehensive site-specific risk assessment shall demonstrate that contaminants of concern at a site do not pose a significant risk to any human receptor. All site-specific risk assessments shall be submitted to the Agency for review and approval. A submittal under this Section shall address the following factors:
a) Whether the risk assessment procedure used is nationally recognized and accepted including, but not limited to, those procedures incorporated by reference in Section 742.210;
b) Whether the site-specific data reflect actual site conditions;
c) The adequacy of the investigation of present and post-remediation exposure routes and risks to receptors identified at the site;
d) The appropriateness of the sampling and analysis;
e) The adequacy and appropriateness of toxicity information;
f) The extent of contamination;
g) Whether the calculations were accurately performed;
h) Similar-acting chemicals shall be specifically addressed. At a minimum, the chemicals subject to this requirement are identified in Appendix A, Tables E and F; and
i) Proposals seeking to modify the target risk consistent with Section 742.900(d) shall address the following factors:
1) the presence of sensitive populations;
2) the number of receptors potentially impacted;
3) the duration of risk at the differing target levels; and
4) the characteristic of the chemicals of concern.
SOURCE: Amended at 21 Ill. Reg. 16391, effective December 8, 1997.
Section 742.920 Impractical Remediation
Any request for site-specific remediation objectives due to impracticality of remediation shall be submitted to the Agency for review and approval. Any request for site-specific remediation objectives due to impracticality of remediation that involves the indoor inhalation exposure route shall follow Section 742.935 in lieu of this Section. A submittal under this Section shall include the following information:
a) The reasons why the remediation is impractical;
b) The current extent and modeled migration of contamination;
c) Geology, including soil types and parameters;
d) The potential impact to groundwater;
e) Results and locations of sampling events;
f) Map of the area, including all utilities and structures; and
g) Present and post-remediation uses of the area of contamination, including human receptors at risk.
(Source: Amended at 37 Ill. Reg. 7506, effective July 15, 2013)
Section 742.925 Exposure Routes
Technical information may demonstrate that there is no actual or potential impact of contaminants of concern to receptors from a particular exposure route. In these instances, a demonstration excluding an exposure route shall be submitted to the Agency for review and approval. A demonstration that involves the indoor inhalation exposure route shall follow Section 742.935 in lieu of this Section. A submittal under this Section shall include the following information:
a) A description of the route evaluated;
b) A description of the site and physical site characteristics;
c) A discussion of the result and possibility of the route becoming active in the future; and
d) Technical support that may include, but is not limited to, the following:
1) a discussion of the natural or man-made barriers to that exposure route;
2) calculations and modeling;
3) physical and chemical properties of contaminants of concern; and
4) contaminant migration properties.
(Source: Amended at 37 Ill. Reg. 7506, effective July 15, 2013)
Section 742.930 Derivation of Toxicological Data
If toxicological-specific information is not available for one or more contaminants of concern from the sources incorporated by reference in Section 742.210, the derivations of toxicological-specific information shall be submitted for Agency review and approval.
Section 742.935 Indoor Inhalation Exposure Route
a) Exclusion of Exposure Route
Site information may demonstrate that there is no actual or potential impact of contaminants of concern to receptors from the indoor inhalation exposure route. In these instances, a demonstration excluding the exposure route shall be submitted to the Agency for review and approval. A submittal under this Section shall include the following information:
1) A description of the site, physical site characteristics, existing and planned buildings, and existing and planned man-made pathways; and
2) A discussion of the possibility of the route becoming active in the future.
b) Exclusion of Exposure Route Using Building Control Technologies
Any proposals to use building control technologies as a means to prevent or mitigate human exposures under the indoor inhalation exposure route that differ from the requirements of Subpart L shall be submitted to the Agency for review and approval. A submittal under this Section shall include the following information:
1) A description of the site and physical site characteristics;
2) The current extent and modeled migration of contamination;
3) Geology, including soil types and parameters;
4) Results and locations of sampling events;
5) Scaled map of the area, including all buildings and man-made pathways;
6) A description of building characteristics and methods of construction, including a description of man-made pathways;
7) Present and post-remediation uses of the land that are at issue due to the area of contamination, including human receptors at risk;
8) A description of any building control technologies currently in place or proposed for installation that can reduce or eliminate the potential for completion of the exposure route, including design and construction specifications;
9) Information regarding the effectiveness of any building control technologies currently in place or proposed for installation and a schedule for performance testing to show the effectiveness of the control technology. For buildings not yet constructed, an approved building control technology shall be in place and operational prior to human occupancy;
10) Identification of documents reviewed and the criteria used in the documents for determining whether building control technologies are effective and how those criteria compare to existing or potential buildings or man-made pathways at the site; and
11) A description as to how the effectiveness of the building control technologies will be operated and maintained for the life of the buildings and man-made pathways, or until soil gas and groundwater contaminant concentrations have reached remediation objectives that are approved by the Agency. This includes provisions for potential extended system inoperability due to power failure or other disruption.
c) Calculations and Modeling Used to Establish Soil Gas Remediation Objectives
The calculations and modeling shall account for contaminant transport through the mechanisms of diffusion and advection. Proposals to use soil gas data, including sub-slab samples, to establish remediation objectives for the indoor inhalation exposure route that differ from the requirements of Section 742.227 shall be submitted to the Agency for review and approval. A submittal under this Section shall include the following information:
1) Scaled map of the area, showing all buildings and man-made pathways (current and planned);
2) The current extent and modeled migration of contamination;
3) Geology, including soil types and parameters;
4) Depth to groundwater (including seasonal variation) and flow direction;
5) Location of soil gas sampling points;
6) A discussion of soil gas sampling procedures that, at a minimum, addresses the following:
A) sampling equipment;
B) soil gas collection protocol, including field tests and weather conditions; and
C) laboratory analytical methods.
d) Calculations and Modeling Used to Establish Soil Remediation Objectives
The calculations and modeling shall account for contaminant transport through the mechanisms of diffusion and advection. Any proposals to use soil data in lieu of soil gas data to establish remediation objectives for the indoor inhalation exposure route shall be submitted to the Agency for review and approval. A submittal under this Section shall include the following information:
1) Scaled map of the area, showing all buildings and man-made pathways (current and planned);
2) The current extent and modeled migration of contamination;
3) Geology, including soil types and parameters;
4) Location of soil sampling points;
5) A discussion of soil sampling procedures that, at a minimum, addresses the following:
A) sampling equipment;
B) soil collection protocol, including field tests and weather conditions; and
C) laboratory analytical methods;
6) Mathematical and technical justification for the model proposed; and
7) Demonstration that the model was correctly applied.
e) Calculations and Modeling Used to Establish Groundwater Remediation Objectives
The calculations and modeling shall account for contaminant transport through the mechanisms of diffusion and advection. Proposals to use groundwater data to establish remediation objectives for the indoor inhalation exposure route that differ from the requirements of Sections 742.805 and 742.812 shall be submitted to the Agency for review and approval. A submittal under this Section shall include the following information:
1) Scaled map of the area, showing all buildings and man-made pathways (current and planned);
2) The current extent and modeled migration of contamination;
3) Geology, including soil types and parameters and the thickness of the capillary fringe;
4) Depth to groundwater (including seasonal variation) and flow direction;
5) Results and locations of groundwater sampling events;
6) Mathematical and technical justification for the model proposed; and
7) Demonstration that the model was correctly applied.
(Source: Added at 37 Ill. Reg. 7506, effective July 15, 2013)
SUBPART J: INSTITUTIONAL CONTROLS
Section 742.1000 Institutional Controls
a) Institutional controls in accordance with this Subpart must be placed on the property when remediation objectives are based on any of the following assumptions:
1) Industrial/Commercial property use;
2) Target cancer risk greater than 1 in 1,000,000;
3) Target hazard quotient greater than 1;
4) Engineered barriers;
5) The point of human exposure is located at a place other than at the source;
6) Exclusion of exposure routes;
7) A diffusion only mode of contaminant transport for the indoor inhalation exposure route;
8) Use of an indoor inhalation building control technology;
9) For the indoor inhalation exposure route, the presence of a building with a full concrete slab-on-grade or a full concrete basement floor and walls; or
10) Any combination of the above.
b) The Agency shall not approve any remediation objective under this Part that is based on the use of institutional controls unless the person has proposed institutional controls meeting the requirements of this Subpart and the requirements of the specific program under which the institutional control is proposed. A proposal for approval of institutional controls shall provide identification of the selected institutional controls from among the types recognized in this Subpart.
c) The following instruments may be institutional controls subject to the requirements of this Subpart J and the requirements of the specific program under which the institutional control is proposed:
1) No Further Remediation Letters;
2) Environmental Land Use Controls;
3) Land Use Control Memoranda of Agreement;
4) Ordinances adopted and administered by a unit of local government;
5) Agreements between a property owner (or, in the case of a petroleum leaking underground storage tank, the owner or operator of the tank) and a highway authority with respect to any contamination remaining under highways; and
6) Agreements between a highway authority that is also the property owner (or, in the case of a petroleum leaking underground storage tank, the owner or operator of the tank) and the Agency with respect to any contamination remaining under the highways.
d) No Further Remediation Letters and Environmental Land Use Controls that meet the requirements of this Subpart and the recording requirements of the program under which remediation is being performed are transferred with the property.
(Source: Amended at 37 Ill. Reg. 7506, effective July 15, 2013)
Section 742.1005 No Further Remediation Letters
a) A No Further Remediation Letter issued by the Agency under 35 Ill. Adm. Code 732 or 740 may be used as an institutional control under this Part if the requirements of subsection (b) of this Section are met. b) A request for approval of a No Further Remediation Letter as an institutional control shall meet the requirements applicable to the specific program under which the remediation is performed. (Source: Amended at 25 Ill. Reg. 10374, effective August 15, 2001) Section 742.1010 Environmental Land Use Controls a) An Environmental Land Use Control (ELUC) is an institutional control that may be used under this Part to impose land use limitations or requirements related to environmental contamination. ELUCs are only effective when approved by the Agency in accordance with this Part. Activities or uses that may be limited or required include, but are not limited to, prohibition of use of groundwater for potable purposes, restriction to industrial/commercial uses, operation or maintenance of engineered barriers, indoor inhalation building control technologies, or worker safety plans. ELUCs may be used in the following circumstances: 1) When No Further Remediation Letters are not available, including but not limited to when contamination has migrated off-site or outside the remediation site; or 2) When No Further Remediation Letters are not issued under the program for which a person is undergoing remediation. b) Recording requirements: 1) An ELUC approved by the Agency pursuant to this Section must be recorded in the Office of the Recorder or Registrar of Titles for the county in which the property that is the subject of the ELUC is located. A copy of the ELUC demonstrating that it has been recorded must be submitted to the Agency before the Agency will issue a no further remediation determination. 2) An ELUC approved under this Section will not become effective until officially recorded in the chain of title for the property that is the subject of the ELUC in accordance with subsection (b)(1) of this Section. 3) Reference to the recorded ELUC must be made in the instrument memorializing the Agency’s no further remediation determination. Recording of the no further remediation determination and confirmation of recording must be in accordance with the requirements of the program under which the determination was issued. 4) The requirements of this Section do not apply to Federally Owned Property for which the Federal Landholding Entity does not have the authority under federal law to record land use limitations on the chain of title. 5) The requirements of this Section apply only to those sites for which a request for a no further remediation determination has not yet been made to the Agency by January 6, 2001. c) Duration: 1) Except as provided in this subsection (c), an ELUC shall remain in effect in perpetuity. 2) At no time shall any site for which an ELUC has been imposed as a result of remediation activities under this Part be used in a manner inconsistent with the land use limitation unless attainment of objectives appropriate for the new land use is achieved and a new no further remediation determination has been obtained and recorded in accordance with the program under which the ELUC was first imposed or the Site Remediation Program (35 Ill. Adm. Code 740) [415 ILCS 58.8(c)]. In addition, the appropriate release or modification of the ELUC must be prepared by the Agency and filed on the chain of title for the property that is the subject of the ELUC. A) For a Leaking Underground Storage Tank (LUST) site under 35 Ill. Adm. Code 731 or 734 or a Site Remediation Program site under 35 Ill. Adm. Code 740, an ELUC may be released or modified only if the NFR Letter is also modified under the Site Remediation Program to reflect the change; B) For a RCRA site under 35 Ill. Adm. Code 721-730, an ELUC may be released or modified only if there is also an amended certification of closure or a permit modification. 3) In addition to any other remedies that may be available, a failure to comply with the limitations or requirements of an ELUC may result in voidance of an Agency no further remediation determination in accordance with the program under which the determination was made. The failure to comply with the limitations or requirements of an ELUC may also be grounds for an enforcement action pursuant to Title VIII of the Act. d) An ELUC submitted to the Agency must match the form and contain the same substance, except for variable elements (e.g., name of property owner), as the model in Appendix F and must contain the following elements: 1) Name of property owners and declaration of property ownership; 2) Identification of the property to which the ELUC applies by common address, legal description, and Real Estate Tax Index/Parcel Index Number; 3) A reference to the Bureau of Land LPC numbers or 10-digit identification numbers under which the remediation was conducted; 4) A statement of the reason for the land use limitation or requirement relative to protecting human health and the surrounding environment from soil, groundwater, and/or other environmental contamination; 5) The language instituting such land use limitations or requirements; 6) A statement that the limitations or requirements apply to the current owners, occupants, and all heirs, successors, assigns, and lessees; 7) A statement that the limitations or requirements apply in perpetuity or until: A) The Agency determines that there is no longer a need for the ELUC; B) The Agency, upon written request, issues to the site that received the no further remediation determination that relies on the ELUC a new no further remediation determination approving modification or removal of the limitations or requirements; C) The new no further remediation determination is filed on the chain of title of the site subject to the no further remediation determination; and D) A release or modification of the land use limitation is filed on the chain of title for the property that is the subject of the ELUC; 8) Scaled site maps showing: A) The legal boundary of the property to which the ELUC applies; B) The horizontal and vertical extent of contaminants of concern above applicable remediation objectives for soil, groundwater, and soil gas to which the ELUC applies; C) Any physical features to which an ELUC applies (e.g., engineered barriers, monitoring wells, caps, indoor inhalation building control technologies); and D) The nature, location of the source, and direction of movement of the contaminants of concern; 9) A statement that any information regarding the remediation performed on the property for which the ELUC is necessary may be obtained from the Agency through a request under the Freedom of Information Act [5 ILCS 140] and rules promulgated thereunder; and The dated, notarized signatures of the property owners or authorized agent. Section 742.1012 Federally Owned Property: Land Use Control Memoranda of Agreement a) A Land Use Control Memorandum of Agreement (LUC MOA) between one or more agencies of the federal government and the Illinois Environmental Protection Agency is the institutional control that shall be used under this Part to impose land use limitations or restrictions related to environmental contamination on Federally Owned Property. A LUC MOA may be used only for Federally Owned Property. Each LUC MOA, at a minimum, must require that the Federal Landholding Entities responsible for the Federally Owned Property do the following:
1) Provide adequate identification of the location on the Federally Owned Property of each site with land use limitations or requirements. Such identification shall be by means of common address, notations in any available facility master land use plan, site specific GIS or GPS coordinates, plat maps, or any other means which identifies the site in question with particularity; 2) Implement periodic site inspection procedures to ensure adequate oversight by the Federal Landholding Entities of such land use limitation or requirement; 3) Implement procedures for the Federal Landholding Entities to periodically advise the Agency of continued compliance with the maintenance of the land use control and site inspection requirements included in the LUC MOA; 4) Implement procedures for the Federal Landholding Entities to notify the Agency of any planned or emergency changes in land use that may adversely impact any site with land use limitations or requirements; and 5) Notify the Agency at least 60 days in advance of a conveyance by deed or fee simple title, by the Federal Landholding Entities, of a site with land use limitations or requirements, to any entity that will not remain or become a Federal Landholding Entity, and provide the Agency with information about how the Federal Landholding Entities will ensure that the requirements of Section 742.1010 are to be satisfied upon conveyance of that site.
a) Any LUC MOA entered into pursuant to this Section remains effective only so long as title to the affected property is retained by the United States. (Source: Amended at 31 Ill. Reg. 4063, effective February 23, 2007) Section 742.1015 Ordinances a) An ordinance adopted by a unit of local government that effectively prohibits the installation of potable water supply wells (and the use of such wells) may be used as an institutional control to meet the requirements of Section 742.320(d) or 742.805(a)(3) if the requirements of this Section are met. A model ordinance is found in Appendix G. Ordinances prohibiting the installation of potable water supply wells (and the use of such wells) that do not expressly prohibit the installation of potable water supply wells (and the use of such wells) by units of local government may be acceptable as institutional controls if the requirements of this Section are met and a Memorandum of Understanding (MOU) is entered into under subsection (i) of this Section. For purposes of this Section, a unit of local government is considered to be expressly prohibited from installing and using potable water supply wells only if the unit of local government is included in the prohibition provision by name. The prohibition required by this Section shall satisfy the following requirements at a minimum: 1) The prohibition shall not allow exceptions for potable water well installation and use other than for the adopting unit of local government; 2) The prohibition shall apply at all depths and shall not be limited to particular aquifers or other geologic formations; 3) If the prohibition does not apply everywhere within the boundaries of the unit of local government, the limited area to which the prohibition applies shall be easily identifiable and clearly defined by the ordinance (e.g., narrative descriptions accompanied by maps with legends or labels showing prohibition boundaries, or narrative descriptions using fixed, common reference points such as street names). Boundaries of prohibitions limited by area shall be fixed by the terms of the ordinance and shall not be subject to change without amending the ordinance in which the prohibition has been adopted (e.g., no boundaries defined with reference to zoning districts or the availability of the public water supply); and 4) The prohibition shall not in any way restrict or limit the Agency’s approval of the use of the ordinance as an institutional control pursuant to this Part (e.g., no restrictions based on remediation program participation, no restrictions on persons performing remediation within the prohibition area who may use the ordinance). b) A request for approval of a local ordinance as an institutional control shall provide the following: 1) A copy of the ordinance restricting groundwater use certified by an official of the unit of local government in which the site is located that it is a true and accurate copy of the ordinance, unless the Agency and the unit of local government have entered an agreement under subsection (i) of this Section, in which case the request may alternatively reference the MOU. The ordinance must demonstrate that potable use of groundwater from potable water supply wells is prohibited; 2) A scaled map or maps delineating the area and extent of groundwater contamination modeled above the applicable remediation objectives including any measured data showing concentrations of contaminants of concern in which the applicable remediation objectives are exceeded; 3) A scaled map delineating the boundaries of all properties under which groundwater is located that exceeds the applicable groundwater remediation objectives; 4) Information identifying the current owners of each property identified in subsection (b)(3); and 5) A copy of the proposed written notification to the unit of local government that adopted the ordinance and to the current owners identified in subsection (b)(4) that includes the following information: A) The name and address of the unit of local government that adopted the ordinance; B) The ordinance’s citation; C) A description of the property being sent notice by adequate legal description, reference to a plat showing the boundaries of the property, or accurate street address; D) Identification of the party requesting to use the groundwater ordinance as an institutional control, and a statement that the party has requested approval from the Agency to use the ordinance as an institutional control; E) A statement that use of the ordinance as an institutional control allows contamination above groundwater ingestion remediation objectives to remain in groundwater beneath the affected properties, and that the ordinance strictly prohibits human and domestic consumption of the groundwater; F) A statement as to the nature of the release and response action with the site name, site address, and Agency site number or Illinois inventory identification number; and G) A statement that more information about the remediation site may be obtained by contacting the party requesting the use of the groundwater ordinance as an institutional control or by submitting a FOIA request to the Agency. c) Written notification proposed pursuant to subsection (b)(5) must be sent to the unit of local government that adopted the ordinance, as well as to all current property owners identified in subsection (b)(4). Written proof that the notification was sent to the unit of local government and the property owners shall be submitted to the Agency within 45 days from the date the Agency’s no further remediation determination is recorded. Such proof may consist of the return card from certified mail, return receipt requested, a notarized certificate of service, or a notarized affidavit. d) Unless the Agency and the unit of local government have entered into a MOU under subsection (i), the current owner or successors in interest of a site who have received approval of use of an ordinance as an institutional control under this Section shall: 1) Monitor activities of the unit of local government relative to variance requests or changes in the ordinance relative to the use of potable groundwater at properties identified in subsection (b)(3); and 2) Notify the Agency of any approved variance requests or ordinance changes within 30 days after the date such action has been approved. e) The information required in subsections (b)(1) through (b)(5) and the Agency letter approving the groundwater remediation objective shall be submitted to the unit of local government. Proof that the information has been filed with the unit of local government shall be provided to the Agency. f) Any ordinance or MOU used as an institutional control pursuant to this Section shall be recorded in the Office of the Recorder or Registrar of Titles of the county in which the site is located together with the instrument memorializing the Agency's no further remediation determination pursuant to the specific program within 45 days after receipt of the Agency's no further remediation determination. g) An institutional control approved under this Section shall not become effective until officially recorded in accordance with subsection (f). The person receiving the approval shall obtain and submit to the Agency within 30 days after recording a copy of the institutional control demonstrating that it has been recorded. h) The following shall be grounds for voidance of the ordinance as an institutional control and the instrument memorializing the Agency’s no further remediation determination: 1) Modification of the ordinance by the unit of local government to allow potable use of groundwater; 2) Approval of a site-specific request, such as a variance, to allow potable use of groundwater at a site identified in subsection (b)(3); 3) Violation of the terms of an institutional control recorded under Section 742.1005 or Section 742.1010; or 4) Failure to provide notification and proof of such notification pursuant to subsection (c). i) The Agency and a unit of local government may enter into a MOU under this Section if the unit of local government has adopted an ordinance satisfying subsection (a) and if the requirements of this subsection are met. The MOU submitted to the Agency must match the form and contain the same substance as the model in Appendix H and shall include the following: 1) Identification of the authority of the unit of local government to enter the MOU; 2) Identification of the legal boundaries, or equivalent, under which the ordinance is applicable; 3) A certified copy of the ordinance; 4) A commitment by the unit of local government to notify the Agency of any variance requests or proposed ordinance changes at least 30 days prior to the date the local government is scheduled to take action on the request or proposed change; 5) A commitment by the unit of local government to maintain a registry of all sites within the unit of local government that have received no further remediation determinations pursuant to specific programs; and 6) If the ordinance does not expressly prohibit the installation of potable water supply wells (and the use of such wells) by units of local government, a commitment by the unit of local government: A) To review the registry of sites established under subsection (i)(5) prior to siting potable water supply wells within the area covered by the ordinance; B) To determine whether the potential source of potable water may be or has been affected by contamination left in place at those sites; and C) To take whatever steps are necessary to ensure that the potential source of potable water is protected from the contamination or treated before it is used as a potable water supply. j) A groundwater ordinance may not be used to exclude the indoor inhalation exposure route. Section 742.1020 Highway Authority Agreements and Highway Authority Agreement Memoranda of Agreement a) An agreement with a highway authority may be used as an institutional control where the requirements of this Section are met and the Agency has determined that no further remediation is required as to the property(ies) to which the agreement is to apply. Highway Authority Agreements submitted to the Agency, except for those agreements with the Illinois Department of Transportation, must match the form and contain the same substance, except for variable elements, as the model in Appendix D. b) As part of the agreement the highway authority shall agree to: 1) Prohibit the use of groundwater under the highway right of way that is contaminated above residential Tier 1 remediation objectives from the release as a potable supply of water; and 2) Limit access to soil contamination under the highway right of way that is contaminated above residential Tier 1 or construction worker remediation objectives, whichever is less, from the release. Access to soil contamination may be allowed if, during and after any access, public health and the environment are protected. c) The agreement shall provide the following: 1) Fully executed signature blocks by the highway authority and the owner of the property (or, in the case of a petroleum leaking underground storage tank, the owner or operator of the tank) from which the release occurred; 2) A scaled map delineating the area and extent of soil and groundwater contamination above the applicable Tier 1 remediation objectives or a statement that either soil or groundwater is not contaminated above the applicable Tier 1 residential remediation objectives; 3) Information showing the concentration of contaminants of concern within the zone in which the applicable Tier 1 remediation objectives are exceeded; 4) A stipulation of the information required by subsections (c)(2) and (3) of this Section in the agreement if it is not practical to obtain the information by sampling the highway right-of-way; and
5) Information identifying the highway authority having jurisdiction. d) Highway Authority Agreements must be referenced in the instrument that is to be recorded on the chain of title for the remediation property.
e) Violation of the terms of an Agreement approved by the Agency as an institutional control under this Section shall be grounds for voidance of the Agreement as an institutional control and the instrument memorializing the Agency's no further remediation determination. f) Failure to provide all of the information required in subsections (b) and (c) of this Section will be grounds for denial of the Highway Authority Agreement as an institutional control. g) In instances in which the highway authority is also the property owner of the site, a Highway Authority Agreement may not be used. In such cases, the highway authority shall instead enter into a Highway Authority Agreement Memorandum of Agreement (HAA MOA) between the highway authority and the Agency. An HAA MOA may be used as an institutional control where the requirements of this Section are met and the Agency has determined that no further remediation is required as to the property(ies) to which the agreement is to apply. HAA MOAs submitted to the Agency must match the form and contain the same substance, except for variable elements, as the model in Appendix E. h) As part of the HAA MOA the highway authority shall agree to: 1) Prohibit the use of groundwater under the highway right of way that is contaminated above residential Tier 1 or construction worker remediation objectives, whichever are less, from the release as a potable supply of water; and 2) Limit access to soil contamination under the highway right of way that is contaminated above residential Tier 1 or construction worker remediation objectives, whichever are less, from the release. Access to soil contamination may be allowed if, during and after any access, public health and the environment are protected. i) The HAA MOA shall provide the following: 1) Information identifying the site by common address or legal description or both; 2) The Illinois Emergency Management Agency’s (IEMA) incident number for the site, if one has been assigned; 3) A scaled map delineating the current and estimated future area and extent of soil and groundwater contamination above the applicable Tier 1 or construction worker remediation objectives, whichever are less, or a statement that either soil or groundwater is not contaminated above the applicable Tier 1 residential remediation objectives; 4) Information prepared by the highway authority that lists each contaminant of concern that exceeds its Tier 1 residential or construction worker remediation objective, its Tier 1 residential remediation objective, and its concentrations within the zone where Tier 1 residential or construction worker remediation objectives, whichever is less, are exceeded; 5) A scaled map prepared by the highway authority showing the area of the highway authority’s right of way that is governed by the HAA MOA; 6) If samples have not been collected within the right of way because of impracticability, a stipulation by the parties that, based on modeling, soil and groundwater contamination exceeding Tier 1 residential or construction worker remediation objectives, whichever is less, does not and will not extend beyond the boundaries of the right-of-way; 7) A stipulation by the highway authority that it has jurisdiction over the right of way that gives it sole control over the use of the groundwater and access to the soil located within or beneath the right of way; 8) A stipulation by the highway authority that it agrees to limit access by itself and others to soil within the right of way exceeding Tier 1 residential or construction worker remediation objectives, whichever is less. Access may only be allowed if human health (including worker safety) and the environment are protected during and after any access. The highway authority may construct, reconstruct, improve, repair, maintain, and operate a highway upon the right of way, or allow others to do the same by permit. The highway authority and others using or working in the right of way under permit have the right to remove soil or groundwater from the right of way and dispose of the same in accordance with applicable environmental laws and regulations. The highway authority agrees to issue all permits for work in the right of way, and make all existing permits for work in the right of way, subject to the following or substantially similar conditions: A) As a condition of this permit the permittee shall request the office issuing this permit to identify sites in the right of way where a HAA MOA governs access to soil that exceeds the Tier 1 residential remediation objectives of 35 Ill. Adm. Code 742; and
B) The permittee shall take all measures necessary to protect human health (including worker safety) and the environment during and after any access to such soil; 9) A stipulation that the HAA MOA shall be referenced in the Agency’s no further remediation determination issued for the release(s); 10) A stipulation that the highway authority shall notify the Agency of any transfer of jurisdiction over the right of way at least 30 days prior to the date the transfer takes effect. The HAA MOA shall be null and void upon the transfer unless the transferee agrees to be bound by the agreement as if the transferee were an original party to the agreement. The transferee’s agreement to be bound by the terms of the agreement shall be memorialized at the time of transfer as a rider to this agreement that references the HAA MOA and is signed by the highway authority, or subsequent transferor, and the transferee; 11) A stipulation that the HAA MOA will become effective on the date the Agency issues a no further remediation determination for the release(s). It shall remain effective until the right of way is demonstrated to be suitable for unrestricted use and the Agency issues a new no further remediation determination to reflect there is no longer a need for the HAA MOA, or until the agreement is otherwise terminated or voided; 12) A stipulation that in addition to any other remedies that may be available, the Agency may bring suit to enforce the terms of the HAA MOA or may, at its sole discretion, declare the HAA MOA null and void if the highway authority or a transferee violates any term of the HAA MOA. The highway authority or transferee shall be notified in writing of any such declaration; and 13) A fully executed signature block by the highway authority and a block for the Agency’s Director. (Source: Amended at 31 Ill. Reg. 4063, effective February 23, 2007) SUBPART K: ENGINEERED BARRIERS Section 742.1100 Engineered Barriers a) Any person who develops remediation objectives under this Part based on engineered barriers shall meet the requirements of this Subpart and the requirements of Subpart J relative to institutional controls. b) The Agency shall not approve any remediation objective under this Part that is based on the use of engineered barriers unless the person has proposed engineered barriers meeting the requirements of this Subpart. c) The use of engineered barriers can be recognized in calculating remediation objectives only if the engineered barriers are intended for use as part of the final corrective action. d) Any no further remediation determination based upon the use of engineered barriers shall require effective maintenance of the engineered barrier. The maintenance requirements shall be included in an institutional control under Subpart J. This institutional control shall address provisions for temporary breaches of the barrier by requiring the following if intrusive construction work is to be performed in which the engineered barrier is to be temporarily breached: 1) The construction workers shall be notified by the site owner/operator in advance of intrusive activities. Such notification shall enumerate the contaminant of concern known to be present; and 2) The site owner/operator shall require construction workers to implement protective measures consistent with good industrial hygiene practice. e) Failure to maintain an engineered barrier in accordance with that no further remediation determination shall be grounds for voidance of the determination and the instrument memorializing the Agency's no further remediation determination. Section 742.1105 Engineered Barrier Requirements a) Natural attenuation, access controls, and point of use treatment shall not be considered engineered barriers. Engineered barriers may not be used to prevent direct human exposure to groundwater without the use of institutional controls. b) For purposes of determining remediation objectives under Tier 1, engineered barriers are not recognized. c) The following engineered barriers are recognized for purposes of calculating remediation objectives that exceed residential remediation objectives: 1) For the soil component of the groundwater ingestion exposure route, the following engineered barriers are recognized if they prevent completion of the exposure pathway: A) Caps or walls constructed of compacted clay, asphalt, concrete or other material approved by the Agency; and B) Permanent structures such as buildings and highways. 2) For the soil ingestion exposure route, the following engineered barriers are recognized if they prevent completion of the exposure pathway: A) Caps or walls constructed of compacted clay, asphalt, concrete, or other material approved by the Agency; B) Permanent structures such as buildings and highways; and C) Soil, sand, gravel, or other geologic materials that: i) Cover the contaminated media; ii) Meet the soil remediation objectives under Subpart E for residential property for contaminants of concern; and iii) Are a minimum of three feet in depth. 3) For the outdoor inhalation exposure route, the following engineered barriers are recognized if they prevent completion of the exposure pathway: A) Caps or walls constructed of compacted clay, asphalt, concrete, or other material approved by the Agency; B) Permanent structures such as buildings and highways; and C) Soil, sand, gravel, or other geologic materials that: i) Cover the contaminated media; ii) Meet the soil remediation objectives under Subpart E for residential property for contaminants of concern; and iii) Are a minimum of ten feet in depth and not within ten feet of any manmade pathway. 4) For the ingestion of groundwater exposure route, the following engineered barriers are recognized if they prevent completion of the exposure pathway: A) Slurry walls; and B) Hydraulic control of groundwater. d) Unless otherwise prohibited under Section 742.1100, any other type of engineered barrier may be proposed if it will be as effective as the options listed in subsection (c). (Source: Amended at 37 Ill. Reg. 7506, effective July 15, 2013)
SUBPART L: BUILDING CONTROL TECHNOLOGIES
Section 742.1200 Building Control Technologies
a) Any person who develops remediation objectives under this Part based on building control technologies shall meet the requirements of this Subpart and the requirements of Subpart J relative to institutional controls.
b) The Agency shall not approve any remediation objective under this Part that is based on the use of building control technologies unless the person has proposed building control technologies meeting the requirements of the following:
1) This Subpart L or Subpart I; and
2) Subpart J relative to institutional controls.
c) The use of building control technologies can be recognized in determining remediation objectives only if the building control technologies are intended for use as part of the final corrective action.
d) An approved building control technology shall be in place and operational prior to human occupancy.
e) Any no further remediation determination based upon the use of building control technologies shall require effective maintenance of the building control technology. The maintenance requirements shall be included in an institutional control under Subpart J. This institutional control shall address provisions for inoperability by requiring the following if the building control technology is rendered inoperable:
1) The site owner/operator shall notify building occupants and workers in advance of intrusive activities. The notification shall enumerate the contaminant of concern known to be present;
2) The site owner/operator shall require building occupants and workers to implement protective measures consistent with good industrial hygiene practice; and
3) For a school, the school administrator shall notify the Agency, the school board, and every parent or legal guardian for all enrolled students when a building control technology is rendered inoperable for a period of five consecutive calendar days during the school year when school is in session. For purposes of the preceding sentence, any occurrence of inoperability, regardless of its duration, results in the date of the occurrence constituting a day of inoperability. For purposes of this subsection (e)(3), the term “school” means any public educational facility in Illinois, including grounds and/or campus, consisting of students, comprising one or more grade groups or other identifiable groups, organized as one unit with one or more teachers to give instruction of a defined type. Public educational facility includes, but is not limited to, primary and secondary (kindergarten-12th grade), charter, vocational, alternative, and special education schools. Public educational facility does not include junior colleges, colleges, or universities. For purposes of this subsection (e)(3), the term “school administrator” means the school’s principal, or similar administrator responsible for the school’s operations, or his or her designee.
f) Failure to install or maintain a building control technology in accordance with a no further remediation determination shall be grounds for voidance of the determination and the instrument memorializing the Agency’s no further remediation determination.
(Source: Added at 37 Ill. Reg. 7506, effective July 15, 2013)
Section 742.1205 Building Control Technology Proposals
A proposal to use a building control technology under this Subpart shall include the following information:
a) A description of the site and physical site characteristics;
b) The current extent and modeled migration of contamination;
c) Geology, including soil types and parameters;
d) Results and locations of sampling events;
e) Scaled map of the area, including all buildings and man-made pathways;
f) A description of building characteristics and methods of construction, including a description of man-made pathways; and
g) Present and post-remediation uses of the land that are at issue due to the area of contamination, including human receptors at risk.
(Source: Added at 37 Ill. Reg. 7506, effective July 15, 2013)
Section 742.1210 Building Control Technology Requirements
a) Natural attenuation, access controls, and point of use treatment shall not be considered building control technologies.
b) For purposes of determining compliance with remediation objectives under Tier 1, building control technologies are not recognized.
c) The following building control technologies are recognized for purposes of pathway exclusion under Section 742.312.
1) Sub-slab depressurization (SSD) systems meeting the following requirements:A) A suction pit is installed that is at least two cubic feet and extends at least 6 inches below the slab (larger suction pits may be excavated as needed to achieve the performance criteria in subsection (c)(1)(B));
B) A PVC pipe of at least 3 inches in diameter extends from the suction pit to the intake side of an in-line fan capable of achieving a static vacuum of at least 0.25 inches water column (wc) at the suction point and measureable vacuum at the farthest edges of the area served by the suction pit under worst case conditions (all exhaust fans and heating systems running, during cold weather) as determined by a differential pressure reading of at least -0.003 inches wc below the slab or visible downward flow of air at test holes using chemical or smoke sticks;
C) All visible cracks and joints in the slab (including the place where the pipe exits the slab) and foundation walls are sealed;
D) The pipe exhausts outside the building at least 10 feet above ground and at least 10 feet from any door or window; andE) Additional suction pits meeting the requirements of subsection (c)(1)(A) shall be installed as necessary to achieve measureable vacuum below the slab in all areas, including in any area where subsurface or foundation conditions (e.g., a sub-slab grade beam) prevent adequate suction field extension.
2) Sub-membrane depressurization (SMD) systems meeting the following requirements:
A) A non-woven geotextile is installed on the exposed earthen material;
B) A cross-laminated polyethylene membrane liner at least 0.10 mm (or 4 mil) thick is placed over the geotextile and sealed to foundation walls using a low volatile adhesive that is recommended by the liner manufacturer (e.g., acrylic latex adhesive);
C) A 3 inch diameter PVC pipe extends from a hole cut in the liner to the intake side of an in-line fan capable of achieving a static vacuum of at least 0.25 inches water column (wc) at the riser pipe and measureable vacuum at the farthest edges of the liner under worst case conditions (all exhaust fans running during cold weather) as determined by a differential pressure reading of at least -0.003 inches wc below the liner or visible downward flow of air in test holes using chemical or smoke sticks;
D) The pipe is sealed to the liner;
E) The pipe exhausts outside the building at least 10 feet above ground and at least 10 feet from any door or window; and
F) No leaks based on smoke stick tests along the entire perimeter of the liner (i.e., at all sealed edges) with the fan running. Where leaks are identified, appropriate repairs are undertaken and smoke stick testing repeated until no leaks are detected.
3) Membrane barrier systems when placed below concrete slabs meeting the following requirements:
A) The membrane is impermeable to volatile chemicals and is not less than 1.5 mm (or 60 mil) thick;
B) The membrane is sealed to foundation walls and any penetrating pipes according to membrane manufacturer/installer recommendations;
C) The membrane is installed in accordance with the manufacturer’s requirements and by an applicator trained and approved by the manufacturer;
D) A smoke test of the membrane system (where smoke is injected below the installed liner prior to slab installation), in accordance with the manufacturer’s requirements, is performed to ensure no leaks exist. Where leaks are identified, appropriate repairs are undertaken and smoke testing repeated until no leaks are detected;
E) The membrane is puncture resistant to slab installation construction activities and protected by sand layers or geotextiles as recommended by the manufacturer; and
F) Construction activities following membrane installation do not damage, puncture or tear the membrane or otherwise compromise its ability to prevent the migration of volatile chemicals.
4) Vented raised floors meeting the following requirements:
A) An interconnected void system below the slab sufficient to allow free movement of air and communication of negative pressures to all points below the slab;
B) Sealing of all construction joints, open cracks, and penetrations through the slab (e.g., for utilities and riser pipes) with a low volatile caulk; and
C) At least one 3 inch diameter riser pipe venting to the atmosphere above the roof line (at least 10 feet from any doors or windows) for each 5000 square feet of membrane area, with the capability of converting passively vented floor systems to actively vented or SSD systems meeting the performance requirements of subsection (c)(1).
(Source: Added at 37 Ill. Reg. 7506, effective July 15, 2013)
Section 742.APPENDIX A: General
Section 742.Illustration A: Developing Soil Remediation Objectives Under the Tiered Approach
Section 742.APPENDIX A: General
Section 742.Illustration B: Developing Groundwater Remediation Objectives Under the Tiered Approach
Section 742.APPENDIX A: General
Section 742.TABLE A: Soil Saturation Limits (Csat) for Chemicals Whose Melting Point is Less Than 30 ° C
For the Outdoor Inhalation Exposure Routea
Csat (mg/kg)
Csat (mg/kg)
CAS No.
Chemical Name67-64-1 Acetone 71-43-2 Benzene 111-44-4 Bis(2-chloroethyl)ether 117-81-7 Bis(2-ethylhexyl)phthalate 75-27-4 Bromodichloromethane (Dichlorobromomethane) 75-25-2 Bromoform 71-36-3 Butanol 78-93-3 2-Butanone (MEK) 85-68-7 Butyl benzyl phthalate 75-15-0 Carbon disulfide 56-23-5 Carbon tetrachloride 108-90-7 Chlorobenzene (Monochlorobenzene) 124-48-1 Chlorodibromomethane (Dibromochloromethane) 67-66-3 Chloroform 95-57-8 2-Chlorophenol c (ionizable organic) 75-99-0 Dalapon 96-12-8 1,2-Dibromo-3-chloropropane 106-93-4 1,2-Dibromoethane (Ethylene dibromide) 84-74-2 Di-n-butyl phthalate 95-50-1 1,2-Dichlorobenzene (o-Dichlorobenzene) 75-71-8 Dichlorodifluoromethane 75-34-3 1,1-Dichloroethane 107-06-2 1,2-Dichloroethane (Ethylene dichloride) 75-35-4 1,1-Dichloroethylene 156-59-2 cis-1,2-Dichloroethylene 156-60-5 trans-1,2-Dichloroethylene 78-87-5 1,2-Dichloropropane 542-75-6 1,3-Dichloropropene (1,3-Dichloropropylene, cis + trans) 84-66-2
Diethyl phthalate 105-67-9 2,4-Dimethylphenol 117-84-0 Di-n-octyl phthalate 123-91-1 p-Dioxane 100-41-4 Ethylbenzene 77-47-4 Hexachlorocyclopentadiene 78-59-1 Isophorone 98-82-8 Isopropylbenzene (Cumene) 7439-97-6 Mercury (elemental) 74-83-9 Methyl bromide (Bromomethane) 1634-04-4 Methyl tertiary-butyl ether 75-09-2 Methylene chloride (Dichloromethane) 98-95-3 Nitrobenzene 621-64-7 n-Nitrosodi-n-propylamine 100-42-5 Styrene 127-18-4 Tetrachloroethylene (Perchloroethylene) 108-88-3 Toluene 120-82-1 1,2,4-Trichlorobenzene 71-55-6 1,1,1-Trichloroethane 79-00-5 1,1,2-Trichloroethane 79-01-6 Trichloroethylene 75-69-4 Trichlorofluoromethane 108-05-4 Vinyl acetate 75-01-4 Vinyl chloride 108-38-3 m-Xylene 95-47-6 o-Xylene 106-42-3 p-Xylene 1330-20-7 Xylenes (total)
a Soil Saturation Limits calculated using an foc of 0.006 g/g and a system temperature of 25 ° C.
b Soil Saturation Limits calculated using an foc of 0.002 g/g and a system temperature of 25 ° C.
c Csat for pH of 6.8. If soil pH is other than 6.8, a site-specific Csat should be calculated using equations S19 and S29 and the pH-specific Koc values in Appendix C Table I.
(Source: Amended at 37 Ill. Reg. 7506, effective July 15, 2013)
Section 742.APPENDIX A: General
Section 742.TABLE B: Tolerance Factor (K)
Tolerance factors (K) for one-sided normal tolerance intervals with probability level (confidence factor) Y = 0.95 and coverage P = 95%. n = number of samples collected.
Section 742.APPENDIX A: General
Section 742.TABLE C: Coefficients {AN-I+1} for W Test of Normality, for N=2(1)50
i/n 2 3 4 5 6 7 8 9 10 1 0.7071 0.7071 0.6872 0.6646 0.6431 0.6233 0.6052 0.5888 0.5739 2 --- .0000 .1677 .2413 .2806 .3031 .3164 .3244 .3291 3 --- --- --- .0000 .0875 .1401 .1743 .1976 .2141 4 --- --- --- --- --- .0000 .0561 .0947 .1224 5 --- --- --- --- --- --- --- .0000 .0399 i/n 1 0.5601 0.5475 0.5359 0.5251 0.5150 0.5056 0.4968 0.4886 0.4808 0.4734 2 .3315 .3325 .3325 .3318 .3306 .3290 .3273 .3253 .3232 .3211 3 .2260 .2347 .2412 .2460 .2495 .2521 .2540 .2553 .2561 .2565 4 .1429 .1586 .1707 .1802 .1878 .1939 .1988 .2027 .2059 .2085 5 .0695 .0922 .1099 .1240 .1353 .1447 .1524 .1587 .1641 .1686 6 0.0000 0.0303 0.0539 0.0727 0.0880 0.1005 0.1109 0.1197 0.1271 0.1334 7 --- --- .0000 .0240 .0433 .0593 .0725 .0837 .0932 .1013 8 --- --- --- --- .0000 .0196 .0359 .0496 .0612 .0711 9 --- --- --- --- --- --- .0000 .0163 .0303 .0422 10 --- --- --- --- --- --- --- --- .0000 .0140
i/n 1 0.4643 0.4590 0.4542 0.4493 0.4450 0.4407 0.4366 0.4328 0.4291 0.4254 2 .3185 .3156 .3126 .3098 .3069 .3043 .3018 .2992 .2968 .2944 3 .2578 .2571 .2563 .2554 .2543 .2533 .2522 .2510 .2499 .2487 4 .2119 .2131 .2139 .2145 .2148 .2151 .2152 .2151 .2150 .2148 5 .1736 .1764 .1787 .1807 .1822 .1836 .1848 .1857 .1864 .1870 6 0.1399 0.1443 0.1480 0.1512 0.1539 0.1563 0.1584 0.1601 0.1616 0.1630 7 .1092 .1150 .1201 .1245 .1283 .1316 .1346 .1372 .1395 .1415 8 .0804 .0878 .0941 .0997 .1046 .1089 .1128 .1162 .1192 .1219 9 .0530 .0618 .0696 .0764 .0823 .0876 .0923 .0965 .1002 .1036 10 .0263 .0368 .0459 .0539 .0610 .0672 .0728 .0778 .0822 .0862 11 0.0000 0.0122 0.0228 0.0321 0.0403 0.0476 0.0540 0.0598 0.0650 0.0697 12 --- --- .0000 .0107 .0200 .0284 .0358 .0424 .0483 .0537 13 --- --- --- --- .0000 .0094 .0178 .0253 .0320 .0381 14 --- --- --- --- --- --- .0000 .0084 .0159 .0227 15 --- --- --- --- --- --- --- --- .0000 .0076
i/n 1 0.4220 0.4188 0.4156 0.4127 0.4096 0.4068 0.4040 0.4015 0.3989 0.3964 2 .2921 .2898 .2876 .2854 .2834 .2813 .2794 .2774 .2755 .2737 3 .2475 .2463 .2451 .2439 .2427 .2415 .2403 .2391 .2380 .2368 4 .2145 .2141 .2137 .2132 .2127 .2121 .2116 .2110 .2104 .2098 5 .1874 .1878 .1880 .1882 .1883 .1883 .1883 .1881 .1880 .1878 i/n 6 0.1641 0.1651 0.1660 0.1667 0.1673 0.1678 0.1683 0.1686 0.1689 0.1691 7 .1433 .1449 .1463 .1475 .1487 .1496 .1503 .1513 .1520 .1526
8 .1243 .1265 .1284 .1301 .1317 .1331 .1344 .1356 .1366 .1376 9 .1066 .1093 .1118 .1140 .1160 .1179 .1196 .1211 .1225 .1237 10 .0899 .0931 .0961 .0988 .1013 .1036 .1056 .1075 .1092 .1108 11 0.0739 0.0777 0.0812 0.0844 0.0873 0.0900 0.0924 0.0947 0.0967 0.0986 12 .0585 .0629 .0669 .0706 .0739 .0770 .0798 .0824 .0848 .0870 13 .0435 .0485 .0530 .0572 .0610 .0645 .0677 .0706 .0733 .0759 14 .0289 .0344 .0395 .0441 .0484 .0523 .0559 .0592 .0622 .0651 15 .0144 .0206 .0262 .0314 .0361 .0404 .0444 .0481 .0515 .0546
16 0.0000 0.0068 0.0131 0.0187 0.0239 0.0287 0.0331 0.0372 0.0409 0.0444 17 --- --- .0000 .0062 .0119 .0172 .0220 .0264 .0305 .0343 18 --- --- --- --- .0000 .0057 .0110 .0158 .0203 .0244 19 --- --- --- --- --- --- .0000 .0053 .0101 .0146 20 --- --- --- --- --- --- --- --- .0000 .0049 i/n 1 0.3940 0.3917 0.3894 0.3872 0.3850 0.3830 0.3808 0.3789 0.3770 0.3751 2 .2719 .2701 .2684 .2667 .2651 .2635 .2620 .2604 .2589 .2574 3 .2357 .2345 .2334 .2323 .2313 .2302 .2291 .2281 .2271 .2260 4 .2091 .2085 .2078 .2072 .2065 .2058 .2052 .2045 .2038 .2032 5 .1876 .1874 .1871 .1868 .1865 .1862 .1859 .1855 .1851 .1847 i/n 6 0.1693 0.1694 0.1695 0.1695 0.1695 0.1695 0.1695 0.1693 0.1692 0.1691 7 .1531 .1535 .1539 .1542 .1545 .1548 .1550 .1551 .1553 .1554 8 .1384 .1392 .1398 .1405 .1410 .1415 .1420 .1423` .1427 .1430 9 .1249 .1259 .1269 .1278 .1286 .1293 .1300 .1306 .1312 .1317 10 .1123 .1136 .1149 .1160 .1170 .1180 .1189 .1197 .1205 .1212
11 0.1004 0.1020 0.1035 0.1049 0.1062 0.1073 0.1085 0.1095 0.1105 0.1113 12 .0891 .0909 .0927 .0943 .0959 .0972 .0986 .0998 .1010 .1020 13 .0782 .0804 .0824 .0842 .0860 .0876 .0892 .0906 .0919 .0932 14 .0677 .0701 .0724 .0745 .0775 .0785 .0801 .0817 .0832 .0846 15 .0575 .0602 .0628 .0651 .0673 .0694 .0713 .0731 .0748 .0764 16 0.0476 0.0506 0.0534 0.0560 0.0584 0.0607 0.0628 0.0648 0.0667 0.0685 17 .0379 .0411 .0442 .0471 .0497 .0522 .0546 .0568 .0588 .0608 18 .0283 .0318 .0352 .0383 .0412 .0439 .0465 .0489 .0511 .0532 19 .0188 .0227 .0263 .0296 .0328 .0357 .0385 .0411 .0436 .0459 20 .0094 .0136 .0175 .0211 .0245 .0277 .0307 .0335 .0361 .0386 21 0.0000 0.0045 0.0087 0.0126 0.0163 0.0197 0.0229 0.0259 0.0288 0.0314 22 --- --- .0000 .0042 .0081 .0118 .0153 .0185 .0215 .0244 23 --- --- --- --- .0000 .0039 .0076 .0111 .0143 .0174 24 --- --- --- --- --- --- .0000 .0037 .0071 .0104 25 --- --- --- --- --- --- --- --- .0000 .0035
Section 742.APPENDIX A: General
Section 742.TABLE D: Percentage Points of the W Test for n=3(1)50
3 0.753 0.767 4 0.687 0.748 5 0.686 0.762 6 0.713 0.788 7 0.730 0.803 8 0.749 0.818 9 0.764 0.829 10 0.781 0.842 11 0.792 0.850 12 0.805 0.859 13 0.814 0.866 14 0.825 0.874 15 0.835 0.881 16 0.844 0.887 17 0.851 0.892 18 0.858 0.897 19 0.863 0.901 20 0.868 0.905 21 0.873 0.908 22 0.878 0.911 23 0.881 0.914 24 0.884 0.916 25 0.888 0.918 26 0.891 0.920 27 0.894 0.923 28 0.896 0.924 29 0.898 0.926 30 0.900 0.927 31 0.902 0.929 32 0.904 0.930 33 0.906 0.931 34 0.908 0.933 35 0.910 0.934
(Source: Amended at 25 Ill. Reg. 10374, effective August 15,2001)
Section 742.APPENDIX A GeneralSection 742.TABLE E Similar-Acting Noncarcinogenic Chemicals
Adrenal Gland
Isopropylbenzene
Cholinesterase Inhibition
Aldicarb
Carbofuran
Circulatory System
Alachlor
Antimony (ingestion only)
Benzene
Cobalt (ingestion only)
2,4-D
cis-1,2-Dichloroethylene (ingestion only)
2,4-Dimethylphenol
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Ensosulfan
Fluoranthene
Fluorene
Methylene Chloride (inhalation only)
Nickel (Res. & I/C only) (inhalation only)
Nitrate as N
Nitrobenzene (ingestion only)
Selenium
Simazine
Styrene (ingestion only)
1,3,5-Trinitrobenzene
Zinc
Decreased Body Weight Gain
Atrazine
Bis(2-chloroethyl)ether
Cyanide
1,2-Dichlorobenzene (inhalation only)
Diethyl phthalate (ingestion only)
Ensosulfan
2-Methylphenol (o-cresol)
Naphthalene (ingestion only)
Nickel (ingestion only)
n-Nitrosodiphenylamine
Phenol (ingestion only)
Simazine
Tetrachloroethylene (ingestion only)
1,1,1-Trichloroethane (ingestion only)
Vinyl acetate (ingestion only)
Xylenes (Res. & I/C only) (ingestion only)
Endocrine System
Cyanide
1,2-Dibromoethane (ingestion only)
Di-n-octyl phthalate (ingestion only)
Nitrobenzene
1,2,4-Trichlorobenzene (ingestion only)
Eye
2,4-Dinitrophenol
n-Nitrosodiphenylamine
Polychlorinated biphenyls (PCBs)
Trichloroethylene
Gastrointestinal System
Beryllium (ingestion only)
Copper
1,3-Dichloropropene (cis + trans) (ingestion only)
Endothall
Fluoride
Hexachlorocyclopentadiene (ingestion only)
Iron
Methyl bromide (ingestion only)
Methyl tertiary-butyl ether (ingestion only)
Immune System
4-Chloroaniline
2,4-Dichlorophenol
Mercury (ingestion only )
Polychlorinated biphenyls (PCBs)
Kidney
Acetone (ingestion only)
Aldrin (CW only)
Barium
Bromodichloromethane (ingestion only)
Cadmium
2,4-D
Dalapon
1,1-Dichloroethane
1,2-Dichloroethane (CW only) (ingestion only)
Ensosulfan
Ethylbenzene (ingestion only)
Fluoranthene
gamma-HCH (gamma-BHC)
Hexachloroethane (ingestion only)
Isopropylbenzene
Mecoprop (MCPP)
Methyl tertiary-butyl ether (inhalation only)
Pentachlorophenol
Pyrene
Toluene (ingestion only)
2,4,5-Trichlorophenol
Vinyl acetate (ingestion only)
Liver
Acenapthene
Aldrin (Res. & I/C only)
Bis(2-ethylhexyl)phthalate (Res. & I/C only) (ingestion only)
Bromoform
Butyl Benzyl Phtalate (ingestion only )
Carbon Tetrachloride
Chlordane
Chlorobenzene (ingestion only)
Chlorodibromomethane (ingestion only)
Chloroform
2,4-D
DDT
1,2-Dibromoethane (ingestion only)
1,2-Dichlorobenezene (CW only) (ingestion only)
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,2-Dichloroethane (inhalation only)
1,1-Dichloroethylene
trans-1,2-Dichloroethylene
1,2-Dichloropropane (ingestion only)
Dieldrin (Res. & I/C only)
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Di-n-octyl phthalate (ingestion only)
p-Dioxane
Endrin
Ethylbenzene (ingestion only)
Fluoranthene
Heptachlor
Heptachlor epoxide
Hexachlorobenzene
alpha-HCH (alpha-BHC
gamma-HCH (gamma-BHC)
High Melting Explosive, Octogen (HMX)
Isophorone (inhalation only)
Methyl tertiary-butyl ether
Methylene Chloride (ingestion only)
Pentachlorophenol
Phenol (inhalation only )
Picloram
Styrene (ingestion only)
Tetrachloroethylene (ingestion only)
Toxaphene (CW only)
2,4,5-TP (Silvex)
1,2,4-Trichlorobenzene (inhalation only)
1,1,1-Trichloroethane (inhalation only)
1,1,2-Trichloroethane (ingestion only)
2,4,5-Trichlorophenol
2,4,6-Trinitrotoluene (TNT)
Vinyl Chloride
Mortality
Di-n-butyl phthalate (ingestion only)
Xylenes (Res. & I/C only) (ingestion only)
Nervous System
Butanol (ingestion only)
Carbon disulfide (inhalation only)
Cyanide
Dieldrin (CW only)
2,4-Dimethylphenol
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Endrin
Hexachloroethane (inhalation only) (CW only)
Manganese
Mercury (inhalation only)
2-Methylphenol (o-cresol)
Phenol (inhalation only)
Selenium
Styrene (inhalation only)
Tetrachloroethylene (inhalation only)
Toluene (inhalation only)
Trichloroethylene
Xylenes (CW only) (ingestion only)
Xylenes (inhalation only)
Reproductive System
Arsenic (inhalation only)
Bis(2-ethylhexyl)phthalate (CW only) (ingestion only)
Boron
2-Butanone
Carbofuran
Carbon disulfide (ingestion only)
2-Chlorophenol
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane (ingestion only)
Dicamba
Dinoseb
Ethylbenzene (inhalation only)
Isophorone (inhalation only)
Methoxychlor
Royal Demolition Explosive , Cyclonite (RDX)
2,4,6-Trichlorophenol
Respiratory System
Antimony (inhalation only)
Benzoic Acid (inhalation only)
Berryllium (inhalation only)
Cadmium (inhalation only)
Chromium (hex) (inhalation only)
Cobalt (inhalation only)
1,2-Dibromoethane (inhalation only)
trans-1,2-Dichloroethylene (inhalation only)
1,2-Dichloropropane (inhalation only)
1,3-Dichloropropene (cis + trans) (inhalation only)
Hexachlorocyclopentadiene (inhalation only)
Methyl bromide (inhalation only)
Naphtalene (inhalation only)
Nickel (inhalation only)
Nitrobenezene (inhalation only)
Vinyl acetate (inhalation only)
Skin
Arsenic (ingestion only)
Polychlorinated biphenyls (PCBs)
Selenium
Silver
Spleen
1,3-Dinotrobenzene
1,3,5-Trinitrobenzene
Notes:
Res. = Residential receptor
I/C = Industrial/Commercial receptor
CW = Construction Worker receptor
(Source: Amended at 37 Ill. Reg. 7506, effective July 15, 2013)
Section 742.APPENDIX A: General
Section 742.TABLE F: Similar-Acting Carcinogenic Chemicals
Bladder Liver (continued) 1,3-Dichloropropene (cis + trans) (ingestion only) Chlordane n-Nitrosodiphenylamine Chloroform DDD Circulatory System DDE Benzene DDT 1,2-Dibromoethane 1,2-Dichloropropane 1,2-Dichloroethane Dieldrin Pentachlorophenol 2,4-Dinitrotoluene 2,4,6-Trichlorophenol 2,6-Dinitrotoluene p-Dioxane Gall Bladder Heptachlor p-Dioxane (inhalation only) Heptachlor epoxide Hexachlorobenzene Gastrointestinal System alpha-HCH (alpha-BHC) Benzo(a)anthracene (ingestion only) gamma-HCH (gamma-BHC) Benzo(b)fluoranthene (ingestion only) Methylene Chloride Benzo(k)flouranthene (ingestion only) Nitrobenzene Benzo(a)pyrene (ingestion only) n-Nitrosodiphenylamine (inhalation only) Bromoform n-Nitrosodi-n-propylamine Chrysene (ingestion only) Pentachlorophenol Dibenzo(a,h)anthracene (ingestion only) Polychlorinated biphenyls (PCBs) 1,2-Dibromoethane (ingestion only) Tetrachloroethylene Indeno(1,2,3-cd)pyrene (ingestion only) Toxaphene Trichloroethylene Kidney Vinyl Chloride (I/C & CW) Bromodichloromethane (ingestion only) Vinyl Chloride (Res.) Chloroform (ingestion only) 1,2-Dibromo-3-chloropropane (ingestion only) Mammary Gland Nitrobenzene 3,3'-Dichlorobenzidine 2,4-Dinitrotoluene Liver 2,6-Dinitrotoluene Aldrin Bis(2-chloroethyl)ether Respiratory System Bis(2-ethylhexyl)phthalate Arsenic (inhalation only) Carbazole Benzo(a)anthracene (inhalation only) Carbon Tetrachloride Benzo(b)fluoranthene (inhalation only)
Respiratory System (continued)Benzo(k)flouranthene (inhalation only) Benzo(a)pyrene (inhalation only) Beryllium Cadmium Chromium (hexavalent ion) Chrysene (inhalation only) Cobalt Dibenzo(a,h)anthracene (inhalation only) 1,2-Dibromo-3-chloropropane (inhalation only) 1,2-Dibromoethane (inhalation only) 1,3-Dichloropropene (cis + trans) (inhalation only) p-Dioxane (inhalation only) Trichloroethylene
Notes: Res. = Residential receptor I/C = Industrial/Commercial receptor CW = Construction Worker receptor
(Source: Amended at 37 Ill. Reg. 7506, effective July 15, 2013)
Section 742.APPENDIX A GeneralSection 742.TABLE G Concentrations of Inorganic Chemicals in Background Soils
(Source: Amended at 31 Ill. Reg. 4063, effective February 23, 2007)
Chemical Name
Metropolitan
Statistical Areas
(mg/kg)
Metropolitan
Statistical Areas
(mg/kg)Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Cyanide Iron Lead Magnesium Manganese Mercury Nickel Potassium Selenium Silver Sodium Sulfate Sulfide Thallium Vanadium Zinc BOARD NOTE: Counties within Metropolitan Statistical Areas: Boone, Champaign, Clinton, Cook, DuPage, Grundy, Henry, Jersey, Kane, Kankakee, Kendall, Lake, Macon, Madison, McHenry, McLean, Menard, Monroe, Peoria, Rock Island, Sangamon, St. Clair, Tazewell, Will, Winnebago and Woodford.
Section 742.APPENDIX A: General
Section 742.TABLE H Concentrations of Polynuclear Aromatic Hydrocarbon Chemicals in Background Soils
Chemical Name
mg/kg
(mg/kg)
Areasc
(mg/kg)2-Methylnaphthalene Acenaphthene Acenaphthylene Anthracene Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(g,h,i)perylene Benzo(k)fluoranthene Chrysene Dibenzo(a,h)anthracene Fluoranthene Fluorene Indeno(1,2,3-c,d)pyrene Naphthalene Phenanthrene Pyrene a Chicago means within the corporate limits of the City of Chicago. b Metropolitan area means a populated area, as defined in Section 742.200, (other than the City of Chicago) that is located within any county in a Metropolitan Statistical Area listed in Appendix A, Table G, footnote a.
c Non-Metropolitan area means a populated area, as defined in Section 742.200, that is not located within any county in a Metropolitan Statistical Area listed in Appendix A, Table G, footnote a.
(Source: Appendix A, Table H renumbered to Appendix A, Table I and new Appendix A, Table H Added at 31 Ill. Reg. 4063, effective February 23, 2007)
Section 742.APPENDIX A General
Section 742.TABLE I Chemicals Whose Tier 1 Class I Groundwater Remediation Objective Exceeds the 1 in 1,000,000 Cancer Risk Concentration
(Source: Appendix A, Table I renumbered from Appendix A, Table H and amended at 31 Ill. Reg. 4063, effective February 23, 2007)
ChemicalClass I Groundwater
Remediation Objective
(mg/L)1 in 1,000,000 Cancer
Risk Concentration
(mg/L)
ADL
(mg/L)Aldrin 0.014 0.000005 0.014 Benzo(a)pyrene 0.0002 0.000012 0.00023 Bis(2-chloroethyl)ether 0.01 0.000077 0.01 Bis(2-ethylhexyl)phthalate (Di(2-ethylhexyl)phthalate) 0.006 0.0061 0.0027 Carbon Tetrachloride 0.005 0.00066 0.0001 Chlordane 0.002 0.000066 0.00014 DDD 0.014 0.00023 0.014 DDE 0.01 0.00023 0.01 DDT 0.006 0.00023 0.006 Dibenzo(a,h)anthracene 0.0003 0.000012 0.0003 1,2-Dibromo-3-chloropropane 0.0002 0.000061 0.001 1,2-Dibromoethane 0.00005 0.00002 0.001 3,3'-Dichlorobenzidine 0.02 0.00019 0.02 1,2-Dichloroethane 0.005 0.00094 0.0003 Dieldrin 0.009 0.0000053 0.009 2,6-Dinitrotoluene 0.00031 0.0001 0.00031 Heptachlor 0.0004 0.000019 0.013 Heptachlor epoxide 0.0002 0.0000094 0.015 Hexachlorobenzene 0.00006 0.000053 0.00006 Alpha-HCH 0.00011 0.000014 0.000111 Tetrachloroethylene 0.005 0.0016 0.0004 Toxaphene 0.003 0.000077 0.00086 Vinyl chloride 0.002 0.000045 0.0002 Ionizable Organics N-Nitrosodi-n-propylamine 0.0018 0.000012 0.0018 Pentachlorophenol 0.001 0.00071 0.000076 2,4,6-Trichlorophenol 0.01 0.007 0.01 Inorganics Arsenic 0.05 0.000057 0.001
Section 742.Table J: List of TACO Volatile Chemicals for the Indoor Inhalation
Exposure Route
CAS No. Chemical 67-64-1 Acetone 71-43-2 Benzene 111-44-4 Bis(2-chloroethyl)ether 75-27-4 Bromodichloromethane 75-25-2 Bromoform 71-36-3 Butanol 78-93-3 2-Butanone (MEK) 75-15-0 Carbon disulfide 56-23-5 Carbon tetrachloride 108-90-7 Chlorobenzene 124-48-1 Chlorodibromomethane 67-66-3 Chloroform 95-57-8 2-Chlorophenol 75-99-0 Dalapon 96-12-8 1,2-dibromo-3-chloropropane 106-93-4 1,2-Dibromoethane 95-50-1 1,2-Dichlorobenzene 106-46-7 1,4-Dichlorobenzene 75-71-8 Dichlorodifluoromethane 75-34-3 1,1-Dichloroethane 107-06-2 1,2-Dichloroethane 75-35-4 1,1-Dichloroethylene 156-59-2 cis-1,2-Dichloroethylene 156-60-5 trans-1,2-Dichloroethylene 78-87-5 1,2-Dichloropropane 542-75-6 1,3-Dichloropropylene (cis + trans) 123-91-1 p-Dioxane 100-41-4 Ethylbenzene 76-44-8 Heptachlor 118-74-1 Hexachlorobenzene 77-47-4 Hexachlorocyclopentadiene 67-72-1 Hexachloroethane 78-59-1 Isophorone
98-82-8 Isopropylbenzene (Cumene) 7439-97-6 Mercury 74-83-9 Methyl bromide 1634-04-4 Methyl tertiary-butyl ether 75-09-2 Methylene chloride 93-65-2 2-Methylnaphthalene 95-48-7 2-Methylphenol (o-cresol) 91-20-3 Naphthalene 98-95-3 Nitrobenzene 621-64-7 n-Nitrosodi-n-propylamine 108-95-2 Phenol 1336-36-3 Polychlorinated biphenyls (PCBs) 100-42-5 Styrene 127-18-4 Tetrachloroethylene 108-88-3 Toluene 120-82-1 1,2,4-Trichlorobenzene 71-55-6 1,1,1-Trichloroethane 79-00-5 1,1,2-Trichloroethane 79-01-6 Trichloroethylene 75-69-4 Trichlorofluoromethane 108-05-4 Vinyl acetate 75-01-4 Vinyl chloride 108-38-3 m-Xylene 95-47-6 o-Xylene 106-42-3 p-Xylene 1330-20-7 Xylenes (total) (Source: Added at 37 Ill. Reg. 7506, effective July 15, 2013)
Section 742.APPENDIX A: General
Section 742.TABLE K: Soil Vapor Saturation Limits (Cvsat) for Volatile Chemicals
CAS No. Chemical Name 67-64-1 Acetone 71-43-2 Benzene 111-44-4 Bis(2-chloroethyl)ether 75-27-4 Bromodichloromethane 75-25-2 Bromoform 71-36-3 Butanol 78-93-3 2-Butanone (MEK) 75-15-0 Carbon disulfide 56-23-5 Carbon tetrachloride 108-90-7 Chlorobenzene 124-48-1 Chlorodibromomethane 67-66-3 Chloroform 95-57-8 2-Chlorophenol (ionizable organic) 75-99-0 Dalapon 96-12-8 1,2-Dibromo-3-chloropropane 106-93-4 1,2-Dibromoethane 95-50-1 1,2-Dichlorobenzene 106-46-7 1,4-Dichlorobenzene 75-71-8 Dichlorodifluoromethane 75-34-3 1,1-Dichloroethane 107-06-2 1,2-Dichloroethane 75-35-4 1,1-Dichloroethylene 156-59-2 cis-1,2-Dichloroethylene 156-60-5 trans-1,2-Dichloroethylene 78-87-5 1,2-Dichloropropane 542-75-6 1,3-Dichloropropylene (cis + trans) 123-91-1 p-Dioxane 100-41-4 Ethylbenzene 76-44-8 Heptachlor 118-74-1 Hexachlorobenzene 77-47-4 Hexachlorocyclopentadiene 67-72-1 Hexachloroethane 78-59-1 Isophorone 98-82-8 Isopropylbenzene (Cumene) 7439-97-6 Mercury (elemental) 74-83-9 Methyl bromide 1634-04-4 Methyl tertiary-butyl ether 75-09-2 Methylene chloride 93-65-2 2-Methylnaphthalene 1634-04-4 2-Methylphenol (o-cresol) 91-20-3 Naphthalene 98-95-3 Nitrobenzene 621-64-7 n-Nitrosodi-n-propylamine 108-95-2 Phenol 1336-36-3 Polychlorinated biphenyls (PCBs) 100-42-5 Styrene 127-18-4 Tetrachloroethylene 108-88-3 Toluene 120-82-1 1,2,4-Trichlorobenzene 71-55-6 1,1,1-Trichloroethane 79-00-5 1,1,2-Trichloroethane 79-01-6 Trichloroethylene 75-69-4 Trichlorofluoromethane 108-05-4 Vinyl acetate 75-01-4 Vinyl chloride 108-38-3 m-Xylene 95-47-6 o-Xylene 106-42-3 p-Xylene 1330-20-7 Xylenes (total) (Source: Added at 37 Ill. Reg. 7506, effective July 15, 2013)
Section 742.APPENDIX B Tier 1 Illustrations and Tables
Section 742.Illustration A Tier 1 Evaluation
(Source: Amended at 31 Ill. Reg. 4063, effective February 23, 2007)
Section 742.APPENDIX B Tier 1 Illustrations and Tables
Section 742.TABLE A Tier 1 Soil Remediation Objectivesa for Residential Properties
Soil Component of the Groundwater Ingestion Exposure Route
ValuesCAS No. Chemical Name
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)83-32-9 Acenaphthene 67-64-1 Acetone 15972-60-8 Alachloro 116-06-3 Aldicarbo 309-00-2 Aldrin 120-12-7 Anthracene 1912-24-9 Atrazineo 71-43-2 Benzene 56-55-3 Benzo(a)anthracene 205-99-2 Benzo(b)fluoranthene
Soil Component of the Groundwater Ingestion Exposure Route
ValuesCAS No. Chemical Name
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)207-08-9 Benzo(k)fluroanthene 50-32-8 Benzo(a)pyrene 111-44-4 Bis(2-chloroethyl)ether 117-81-7 Bis(2-ethylhexyl)phthalate 75-27-4 Bromodichloromethane
(Dichlorobromomethane)75-25-2 Bromoform 71-36-3 Butanol 85-68-7 Butyl benzyl phthalate 86-74-8 Carbazole 1563-66-2 Carbofurano 75-15-0 Carbon disulfide
Soil Component of the Groundwater Ingestion Exposure Route
ValuesCAS No. Chemical Name
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)56-23-5 Carbon tetrachloride 57-74-9 Chlordane 106-47-8 4-Chloroaniline
(p-Chloroaniline)108-90-7 Chlorobenzene
(Monochlorobenzene)124-48-1 Chlorodibromomethane
(Dibromochloromethane)67-66-3 Chloroform 218-01-9 Chrysene
94-75-7 2,4-Do 75-99-0 Dalapono 72-54-8 DDD 72-55-9 DDE
Soil Component of the Groundwater Ingestion Exposure Route
ValuesCAS No. Chemical Name
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)50-29-3 DDT 53-70-3 Dibenzo(a,h)anthracene 96-12-8 1,2-Dibromo-3-chloropropane 106-93-4 1,2-Dibromoethane
(Ethylene dibromide)84-74-2 Di-n-butyl phthalate 95-50-1 1,2-Dichlorobenzene
(o – Dichlorobenzene)106-46-7 1,4-Dichlorobenzene
(p – Dichlorobenzene)91-94-1 3,3'-Dichlorobenzidine 75-34-3 1,1-Dichloroethane
Soil Component of the Groundwater Ingestion Exposure Route
ValuesCAS No. Chemical Name
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)107-06-2 1,2-Dichloroethane
(Ethylene dichloride)75-35-4 1,1-Dichloroethylene 156-59-2 cis-1,2-Dichloroethylene 156-60-5 trans-1,2-Dichloroethylene 78-87-5 1,2-Dichloropropane 542-75-6 1,3-Dichloropropene
(1,3-Dichloropropylene, cis + trans)60-57-1 Dieldrinn 84-66-2 Diethyl phthalate 105-67-9 2,4-Dimethylphenol 121-14-2 2,4-Dinitrotoluene
Soil Component of the Groundwater Ingestion Exposure Route
ValuesCAS No. Chemical Name
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)ADL
(mg/kg)606-20-2 2,6-Dinitrotoluene 0.260 117-84-0 Di-n-octyl phthalate * 115-29-7 Endosulfano * 145-73-3 Endothallo NA 72-20-8 Endrin * 100-41-4 Ethylbenzene * 206-44-0 Fluoranthene * 86-73-7 Fluorene * 76-44-8 Heptachlor 0.871 1024-57-3 Heptachlor epoxide 1.005 118-74-1 Hexachlorobenzene * 319-84-6 Alpha-HCH (alpha-BHC) 0.0074
Soil Component of the Groundwater Ingestion Exposure Route
ValuesCAS No. Chemical Name
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)58-89-9 Gamma-HCH (Lindane)n 77-47-4 Hexachlorocyclopentadiene 67-72-1 Hexachloroethane 193-39-5 Indeno(1,2,3-c,d)pyrene 78-59-1 Isophorone 72-43-5 Methoxychloro 74-83-9 Methyl bromide
(Bromomethane)1634-04-4 Methyl tertiary-butyl ether 75-09-2 Methylene chloride
(Dichloromethane)95-48-7 2-Methylphenol
(o – Cresol)91-20-3 Naphthalene 98-95-3 Nitrobenzene
Soil Component of the Groundwater Ingestion Exposure Route
ValuesCAS No. Chemical Name
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)86-30-6 N-Nitrosodiphenylamine 621-64-7 N-Nitrosodi-n-propylamine 108-95-2 Phenol 1918-02-1 Picloramo 1336-36-3 Polychlorinated biphenyls (PCBs)n 129-00-0 Pyrene 122-34-9 Simazineo 100-42-5 Styrene 127-18-4 Tetrachloroethylene
(Perchloroethylene)108-88-3 Toluene
Soil Component of the Groundwater Ingestion Exposure Route
ValuesCAS No. Chemical Name
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)8001-35-2 Toxaphenen 120-82-1 1,2,4-Trichlorobenzene 71-55-6 1,1,1-Trichloroethane 79-00-5 1,1,2-Trichloroethane 79-01-6 Trichloroethylene 108-05-4 Vinyl acetate 75-01-4 Vinyl chloride 108-38-3 m-Xylene 95-47-6 o-Xylene 106-42-3 p-Xylene
Soil Component of the Groundwater Ingestion Exposure Route
ValuesCAS No. Chemical Name
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)1330-20-7 Xylenes (total) Ionizable Organics 65-85-0 Benzoic Acid 95-57-8 2-Chlorophenol 120-83-2 2,4-Dichlorophenol 51-28-5 2,4-Dinitrophenol 88-85-7 Dinosebo 87-86-5 Pentachlorophenol 93-72-1 2,4,5-TP
(Silvex)95-95-4 2,4,5-Trichlorophenol 88-06-2 2,4,6 Trichlorophenol
Soil Component of the Groundwater Ingestion Exposure Route
ValuesCAS No. Chemical Name
(mg/kg)
(mg/kg)
(mg/L)
(mg/L)
(mg/kg)Inorganics 7440-36-0 Antimony 7440-38-2 Arsenicl,n 7440-39-3 Barium 7440-41-7 Beryllium 7440-42-8 Boron 7440-43-9 Cadmiuml,n 7440-70-2 Calciumn 16887-00-6 Chloride 7440-47-3 Chromium, total 16065-83-1 Chromium, ion, trivalent 18540-29-9 Chromium, ion, hexavalent
Soil Component of the Groundwater Ingestion Exposure Route
ValuesCAS No. Chemical Name
(mg/kg)
(mg/kg)
(mg/L)
(mg/L)
(mg/kg)7440-48-4 Cobalt 7440-50-8 Coppern 57-12-5 Cyanide (amenable) 7782-41-4 Fluoride 15438-31-0 Iron 7439-92-1 Lead 7439-95-4 Magnesiumn 7439-96-5 Manganese 7439-97-6 Mercuryl,n,s 7440-02-0 Nickell 14797-55-8 Nitrate as Np 7723-14-0 Phosphorusn
Soil Component of the Groundwater Ingestion Exposure Route
ValuesCAS No. Chemical Name
(mg/kg)
(mg/kg)
(mg/L)
(mg/L)
(mg/kg)7440-09-7 Potassiumn 7782-49-2 Seleniuml,n 7440-22-4 Silver 7440-23-5 Sodiumn 14808-79-8 Sulfate 7440-28-0 Thallium 7440-62-2 Vanadium 7440-66-6 Zincl
“*” indicates that the ADL is less than or equal to the specified remediation objective.
NA means not available; no PQL or EQL available in USEPA analytical methods.
Chemical Name and Soil Remediation Objective Notations
a Soil remediation objectives based on human health criteria only.
b Calculated values correspond to a target hazard quotient of 1.
c No toxicity criteria available for the route of exposure.
d Soil saturation concentration (C [sat]) = the concentration at which the absorptive limits of the soil particles, the solubility limits of the available soil moisture, and saturation of soil pore air have been reached. Above the soil saturation concentration, the assumptions regarding vapor transport to air and/or dissolved phase transport to groundwater (for chemicals which are liquid at ambient soil temperatures) have been violated, and alternative modeling approaches are required.
e Calculated values correspond to a cancer risk level of 1 in 1,000,000.
g Chemical-specific properties are such that this route is not of concern at any soil contaminant concentration.
h 40 CFR 761 contains applicability requirements and methodologies for the development of PCB remediation objectives. Requests for approval of a Tier 3 evaluation must address the applicability of 40 CFR 761.
I Soil remediation objective for pH of 6.8. If soil pH is other than 6.8, refer to Appendix B, Tables C and D of this Part.
j Ingestion soil remediation objective adjusted by a factor of 0.5 to account for dermal route.
k A preliminary remediation goal of 400 mg/kg has been set for lead based on Revised Interim Soil Lead Guidance for CERCLA Sites and RCRA Corrective Action Facilities, OSWER Directive #9355.4-12.
l Potential for soil-plant-human exposure.
m The person conducting the remediation has the option to use: 1) TCLP or SPLP test results to compare with the remediation objectives listed in this Table; 2) where applicable, the total amount of contaminant in the soil sample results to compare with pH specific remediation objectives listed in Appendix B, Table C or D of this Part (see Section 742.510); or 3) the appropriate background value listed in Appendix A, Table G. If the person conducting the remediation wishes to calculate soil remediation objectives based on background concentrations, this should be done in accordance with Subpart D of this Part.
n The Agency reserves the right to evaluate the potential for remaining contaminant concentrations to pose significant threats to crops, livestock, or wildlife.
o For agrichemical facilities, remediation objectives for surficial soils which are based on field application rates may be more appropriate for currently registered pesticides. Consult the Agency for further information.
p For agrichemical facilities, soil remediation objectives based on site-specific background concentrations of Nitrate as N may be more appropriate. Such determinations shall be conducted in accordance with the procedures set forth in Subparts D and I of this Part.
q The TCLP extraction must be done using water at a pH of 7.0.
r Value based on dietary Reference Dose.
s Value for Ingestion based on Reference Dose for Mercuric chloride (CAS No. 7487-94-7); value for Inhalation based on Reference Concentration for elemental Mercury (CAS No. 7439-97-6). Inhalation remediation objective only applies at sites where elemental mercury is a contaminant of concern.
t For the ingestion route for arsenic, see 742.Appendix A, Table G.
u Value based on Reference Dose for Thallium sulfate (CAS No. 7446-18-6).
v Value based on Reference Dose adjusted for dietary intake.
w For sites located in any populated area as defined in Section 742.200, Appendix A, Table H may be used.
x The remediation objectives for these chemicals must also include the construction worker inhalation objective in Appendix B, Table B.(Source: Amended at 31 Ill. Reg. 4063, effective February 23, 2007)
Section 742.APPENDIX B Tier 1 Illustrations and Tables
Section 742.Table B Tier 1 Soil Remediation Objectivesa for Industrial/Commercial Properties
Exposure Route-Specific Values for Soils
Soil Component of the Groundwater Ingestion Exposure Route
Values
CommercialConstruction
Worker
Name
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)ADL
(mg/kg)83-32-9 Acenaphthene 120,000b -----c 120,000b -----c 570b 2,900 67-64-1 Acetone ----g 100,000d ----g 100,000d 25b 25 15972-60-8 Alachloro 72e -----c 1,600e -----c 0.04 0.2 116-06-3 Aldicarbo 2,000b -----c 200b -----c 0.013 0.07 309-00-2 Aldrin 0.3e 6.6e 6.1b 9.3e 0.5e 2.5 120-12-7 Anthracene 610,000b -----c 610,000b -----c 12,000b 59,000 1912-24-9 Atrazineo 72,000b -----c 7,100b -----c 0.066 0.33 71-43-2 Benzene 100e 1.6 e 2,300e 2.2 e 0.03 0.17
Exposure Route-Specific Values for Soils
Soil Component of the Groundwater Ingestion Exposure Route
Values
CommercialConstruction
Worker
NameIngestion
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)ADL
(mg/kg)56-55-3 Benzo(a)anthracene 8e -----c 170e -----c 2 8 205-99-2 Benzo(b)fluoranthene 8e -----c 170e -----c 5 25 207-08-9 Benzo(k)fluroanthene 78e -----c 1,700e -----c 49 250 50-32-8 Benzo(a)pyrene 0.8e,x -----c 17e -----c 8 82 111-44-4 Bis(2-chloroethyl)ether 5e 0.47e 75e 0.66e 0.0004e, 0.0004 117-81-7 Bis(2-ethylhexyl)phthalate 410e 31,000d 4,100b 31,000d 3,600 31,000d 75-27-4 Bromodichloromethane
(Dichlorobromomethane)92e 3,000d 2,000e 3,000d 0.6 0.6 75-25-2 Bromoform 720e 100e 16,000e 140e 0.8 0.8 71-36-3 Butanol 200,000b 10,000d 200,000b 10,000d 17b 17 85-68-7 Butyl benzyl phthalate 410,000b 930d 410,000b 930d 930d 930d 86-74-8 Carbazole 290e -----c 6,200e -----c 0.6e 2.8
Exposure Route-Specific Values for Soils
Soil Component of the Groundwater Ingestion Exposure Route
Values
CommercialConstruction
Worker
Name
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)ADL
(mg/kg)1563-66-2 Carbofurano 10,000b -----c 1,000b -----c 0.22 1.1 75-15-0 Carbon disulfide 200,000b 720d 20,000b 9.0b 32b 160 56-23-5 Carbon tetrachloride 44e 0.64e 410b 0.90e 0.07 0.33 57-74-9 Chlordane 16 e 140 e 100 b 22b 10 48 106-47-8 4 – Chloroaniline
(p-Chloroaniline)8,200b -----c 820b -----c 0.7b 0.7 108-90-7 Chlorobenzene
(Monochlorobenzene)41,000b 210b 4,100b 1.3b 1 6.5 124-48-1 Chlorodibromomethane
(Dibromochloromethane)41,000b 1,300d 41,000b 1,300d 0.4 0.4 67-66-3 Chloroform 940e 0.54e 2,000b 0.76e 0.6 2.9 218-01-9 Chrysene 780e -----c 17,000e -----e 160 800 94-75-7 2,4-Do 20,000b -----c 2,000b -----c 1.5 7.7
Exposure Route-Specific Values for Soils
Soil Component of the Groundwater Ingestion Exposure Route
Values
CommercialConstruction
Worker
Name
(mg/kg)
(mg/kg)
(mg/kg)Inhalation
(mg/kg)Class I
(mg/kg)
(mg/kg)ADL
(mg/kg)75-99-0 Dalapono 61,000b -----c 6,100b -----c 0.85 8.5 72-54-8 DDD 24e -----c 520e -----c 16e 80 72-55-9 DDE 17e -----c 370e -----c 54e 270 50-29-3 DDT 17e 1,500e 100b 2,100e 32e 160 53-70-3 Dibenzo(a,h)anthracene 0.8e -----c 17e -----c 2 7.6 96-12-8 1,2-Dibromo-3-chloropropane 4e 17b 89e 0.11b 0.002 0.02 106-93-4 1,2-Dibromoethane
(Ethylene dibromide)2.9e 0.12e 62e 0.16e 0.0004 0.004 84-74-2 Di-n-butyl phthalate 200,000b 2,300d 200,000b 2,300d 2,300d 2,300d 95-50-1 1,2-Dichlorobenzene
(o – Dichlorobenzene)180,000b 560d 18,000b 310b 17 43 106-46-7 1,4-Dichlorobenzene
(p – Dichlorobenzene)-----c 17,000b -----c 340b 2 11
Exposure Route-Specific Values for Soils
Soil Component of the Groundwater Ingestion Exposure Route
Values
CommercialConstruction
WorkerChemical
Name
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)ADL
(mg/kg)91-94-1 3,3’-Dichlorobenzidine 13e -----c 280e -----c 0.007e, 0.033 75-34-3 1,1-Dichloroethane 200,000b 1,700d 200,000b 130b 23b 110 107-06-2 1,2-Dichloroethane
(Ethylene dichloride)63e 0.70e 1,400e 0.99e 0.02 0.1 75-35-4 1,1-Dichloroethylene 100,000b 470b 10,000b 3.0b 0.06 0.3 156-59-2 cis-1,2-Dichloroethylene 20,000b 1,200d 20,000b 1,200d 0.4 1.1 156-60-5 Trans-1,2-Dichloroethylene 41,000b 3,100d 41,000b 3,100d 0.7 3.4 78-87-5 1,2-Dichloropropane 84e 23b 1,800e 0.50b 0.03 0.15 542-75-6 1,3-Dichloropropene
(1,3-Dichloropropylene, cis + trans)57e 2.1e 1,200e 0.39b 0.004e 0.02 60-57-1 Dieldrinn 0.4e 2.2e 7.8e 3.1e 0.004e 0.02 84-66-2 Diethyl phthalate 1,000,000b 2,000d 1,000,000b 2,000d 470b 470
Exposure Route-Specific Values for Soils
Soil Component of the Groundwater Ingestion Exposure Route
Values
CommercialConstruction
Worker
Name
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)105-67-9 2,4-Dimethylphenol 41,000b -----c 41,000b -----c 9b 9 121-14-2 2,4-Dinitrotoluene 8.4e -----c 180e -----c 0.0008e, 0.0008 606-20-2 2,6-Dinitrotoluene 8.4e -----c 180e -----c 0.0007e, 0.0007 117-84-0 Di-n-octyl phthalate 41,000e 10,000d 4,100b 10,000d 10,000d 10,000d 115-29-7 Endosulfano 12,000b -----c 1,200b -----c 18b 90 145-73-3 Endothallo 41,000c -----c 4,100b -----c 0.4 0.4 72-20-8 Endrin 610b -----c 61b -----c 1 5 100-41-4 Ethylbenzene 200,000b 400d 20,000b 58b 13 19 206-44-0 Fluoranthene 82,000b -----c 82,000b -----c 4,300b 21,000 86-73-7 Fluorene 82,000b -----c 82,000b -----c 560b 2,800 76-44-8 Heptachlor 1e 11e 28e 16e 23 110
Exposure Route-Specific Values for Soils
Soil Component of the Groundwater Ingestion Exposure Route
Values
CommercialConstruction
WorkerChemical
Name
(mg/kg)
(mg/kg)
(mg/kg)Inhalation
(mg/kg)
(mg/kg)
(mg/kg)ADL
(mg/kg)1024-57-3 Heptachlor epoxide 0.6e 9.2e 2.7b 13e 0.7 3.3 118-74-1 Hexachlorobenzene 4e 1.8e 78e 2.6e 2 11 319-84-6 Alpha-HCH (alpha-BHC) 0.9e 1.5e 20e 2.1e 0.0005e, 0.003 58-89-9 Gamma-HCH (Lindane)n 4e -----c 96e -----c 0.009 0.047 77-47-4 Hexachlorocyclopentadiene 14,000b 16b 14,000b 1.1b 400 2,200d 67-72-1 Hexachloroethane 2,000b -----c 2,000b -----c 0.5b 2.6 193-39-5 Indeno(1,2,3-c,d)pyrene 8e -----c 170e -----c 14 69 78-59-1 Isophorone 410,000b 4,600d 410,000b 4,600d 8b 8 72-43-5 Methoxychloro 10,000b -----c 1,000b -----c 160 780 74-83-9 Methyl bromide
(Bromomethane)2,900b 15b 1,000b 3.9b 0.2b 1.2
Exposure Route-Specific Values for Soils
Soil Component of the Groundwater Ingestion Exposure Route
Values
CommercialConstruction
Worker
Name
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)Class I
(mg/kg)ClassII
(mg/kg)
(mg/kg)1634-04-4 Methyl tertiary-butyl ether 20,000b 8,800d 2,000b 140b 0.32 0.32 75-09-2 Methylene chloride
(Dichloromethane)760e 24e 12,000b 34e 0.02e 0.2 95-48-7 2-Methylphenol
(o – Cresol)100,000b -----c 100,000b -----c 15b 15 86-30-6 N-Nitrosodiphenylamine 1,200e -----c 25,000e -----c 1e 5.6 621-64-7 N-Nitrosodi-n-propylamine 0.8e -----c 18e -----c 0.00005e 0.00005 91-20-3 Naphthalene 41,000b 270b 4,100b 1.8b 12b 18 98-95-3 Nitrobenzene 1,000b 140b 1,000b 9.4b 0.1b 0.1 108-95-2 Phenol 610,000b -----c 61,000b -----c 100b 100 1918-02-1 Picloramo 140,000b -----c 14,000b -----c 2 20 1336-36-3 Polychlorinated biphenyls (PCBs)n 1h -----c,h 1h -----c,h -----h -----h 129-00-0 Pyrene 61,000b -----c 61,000b -----c 4,200b 21,000
Exposure Route-Specific Values for Soils
Soil Component of the Groundwater Ingestion Exposure Route
Values
CommercialConstruction
WorkerChemical
Name
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)ClassII
(mg/kg)
(mg/kg)122-34-9 Simazineo 10,000b -----c 1,000b -----c 0.04 0.37 100-42-5 Styrene 410,000b 1,500d 41,000b 430b 4 18 127-18-4 Tetrachloroethylene
(Perchloroethylene)110e 20e 2,400e 28e 0.06 0.3 108-88-3 Toluene 410,000b 650d 410,000b 42b 12 29 8001-35-2 Toxaphenen 5.2e 170e 110e 240e 31 150 120-82-1 1,2,4-Trichlorobenzene 20,000b 3,200d 2,000b 920b 5 53 71-55-6 1,1,1-Trichloroethane -----c 1,200d -----c 1,200d 2 9.6 79-00-5 1,1,2-Trichloroethane 8,200b 1,800d 8,200b 1,800d 0.02 0.3 79-01-6 Trichloroethylene 520e 8.9e 1,200b 12e 0.06 0.3 108-05-4 Vinyl acetate 1,000,000b 1,600b 200,000b 10b 170b 170
Exposure Route-Specific Values for Soils
Soil Component of the Groundwater Ingestion Exposure Route
Values
CommercialConstruction
Worker
Name
(mg/kg)Inhalation
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)ADL
(mg/kg)75-01-4 Vinyl chloride 7.9e 1.1e 170e 1.1b 0.01 0.07 108-38-3 m-Xylene 410,000b 420d 41,000b 6.4b 210 210 95-47-6 o-Xylene 410,000b 410d 41,000b 6.5b 190 190 106-42-3 p-Xylene 410,000b 460d 41,000b 5.9b 200 200 1330-20-7 Xylenes (total) 410,000b 320d 41,000b 5.6b 150 150 Ionizable Organics 65-85-0 Benzoic Acid 1,000,000b -----c 820,000b -----c 400b,i 400i 95-57-8 2-Chlorophenol 10,000b 53,000d 10,000b 53,000d 4b, i 20i 120-83-2 2,4-Dichlorophenol 6,100b -----c 610b -----c 1b, i 1i 51-28-5 2,4-Dinitrophenol 4,100b -----c 410b -----c 0.2b, i 0.2i 88-85-7 Dinosebo 2,000b -----c 200b -----c 0.34b, i 3.4i
Exposure Route-Specific Values for Soils
Soil Component of the Groundwater Ingestion Exposure Route
Values
CommercialConstruction
Worker
Name
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)ADL
(mg/kg)87-86-5 Pentachlorophenol 24e,j -----c 520e,j -----c 0.03 i 0.14i 93-72-1 2,4,5-TP
(Silvex)16,000b -----c 1,600b -----c 11i 55i 95-95-4 2,4,5-Trichlorophenol 200,000b -----c 200,000b -----c 270b, i 1,400i 88-06-2 2,4,6- Trichlorophenol 520e 390e 11,000e 540e 0.2e, i 0.77i
Exposure Route-Specific Values for Soils
Soil Component of the Groundwater Ingestion Exposure Route
Values
CommercialConstruction
Worker
Name
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)
(mg/L)
(mg/L)
(mg/kg)Inorganics 7440-36-0 Antimony 820b -----c 82b -----c 0.006m 0.024m 7440-38-2 Arsenicl,n ---t 1,200e 61b 25,000e 0.05m 0.2m 7440-39-3 Barium 140,000b 910,000b 14,000b 870,000b 2.0m 2.0m 7440-41-7 Beryllium 4,100b 2,100e 410b 44,000e 0.004m 0.5m 7440-42-8 Boron 410,000b ---c 41,000b ---c 2.0m 2.0m 7440-43-9 Cadmiuml,n 2,000b,r 2,800e 200b,r 59,000e 0.005m 0.05m 7440-70-2 Calciumn ---g ---c ---g ---c ---c ---c 16887-00-6 Chloride -------c -----c -----c -----c 200m 200m 7440-47-3 Chromium, total 6,100 b 420e 4,100b 690b 0.1m 1.0m 16065-83-1 Chromium, ion, trivalent 1,000,000b -----c 310,000b -----c -----g -----g 18540-29-9 Chromium, ion, hexavalent 6,100b 420e 4,100b 690b ----- -----
Exposure Route-Specific Values for SoilsSoil Component of the Groundwater Ingestion Exposure Route
Values
CommercialConstruction
Worker
Name
(mg/kg)
(mg/kg)
(mg/kg)
(mg/kg)
(mg/L)Class II
(mg/L)
(mg/kg)7440-48-4 Cobalt 120,000b -----c 12,000b -----c 1.0m 1.0m 7440-50-8 Coppern 82,000b -----c 8,200b -----c 0.65m 0.65m 57-12-5 Cyanide (amenable) 41,000b -----c 4,100b -----c 0.2q,m 0.6q,m 7782-41-4 Fluoride 120,000b -----c 12,000b -----c 4.0m 4.0m 15438-31-0 Iron -----c -----c -----c -----c 5.0m 5.0m 7439-92-1 Lead 800y -----c 700y -----c 0.0075m 0.1m 7439-95-4 Magnesiumn ---g ---c 730,000 ---c ---c ---c
7439-96-5 Manganese 41,000 b,w 91,000b 4,100 b,w 8,700b 0.15m 10.0m 7439-97-6 Mercuryl,n,s 610b 16b 61b 0.1b 0.002m 0.01m 7440-02-0 Nickell 41,000b 21,000e 4,100b 440,000e 0.1m 2.0m 14797-55-8 Nitrate as Np 1,000,000b -----c 330,000b -----c 10.0q, m 100q 7723-14-0 Phosphorusn ---g ---c ---g ---c ---c ---c
Exposure Route-Specific Values for Soils
Soil Component of the Groundwater Ingestion Exposure Route
Values
CommercialConstruction
Worker
Name
(mg/kg)
(mg/kg)Ingestion
(mg/kg)Inhalation
(mg/kg)
(mg/L)
(mg/L)
(mg/kg)7440-09-7 Potassiumn ---g ---c ---g ---c ---c ---c 7782-49-2 Seleniuml,n 10,000b -----c 1,000b -----c 0.05m 0.05m 7440-22-4 Silver 10,000b -----c 1,000b -----c 0.05m ----- 7440-23-5 Sodiumn ---g ---c ---g ---c ---c ---c 14808-79-8 Sulfate -----c -----c -----c -----c 400m 400m 7440-28-0 Thallium 160b,u -----c 160b,u -----c 0.002m 0.02m 7440-62-2 Vanadium 14,000b -----c 1,400b -----c 0.049m 0.1m 7440-66-6 Zincl 610,000b -----c 61,000b -----c 5.0m 10m
“*” indicates that the ADL is less than or equal to the specified remediation objective.
NA means Not Available; no PQL or EQL available in USEPA analytical methods.
Chemical Name and Soil Remediation Objective Notations (2nd, 5th thru 8th Columns)
a oil remediation objectives based on human health criteria only.
b Calculated values correspond to a target hazard quotient of 1.
c No toxicity criteria available for this route of exposure.
d Soil saturation concentration (C[sat]) = the concentration at which the absorptive limits of the soil particles, the solubility limits of the available soil moisture, and saturation of soil pore air have been reached. Above the soil saturation concentration, the assumptions regarding vapor transport to air and/or dissolved phase transport to groundwater (for chemicals which are liquid at ambient soil temperatures) have been violated, and alternative modeling approaches are required.
e Calculated values correspond to a cancer risk level of 1 in 1,000,000.
g Chemical-specific properties are such that this route is not of concern at any soil contaminant concentration.
h 40 CFR 761 contains applicability requirements and methodologies for the development of PCB remediation objectives. Requests for approval of a Tier 3 evaluation must address the applicability of 40 CFR 761.
i Soil remediation objective for pH of 6.8. If soil pH is other than 6.8, refer to Appendix B, Tables C and D in this Part.
j Ingestion soil remediation objective adjusted by a factor of 0.5 to account for dermal route.
l Potential for soil-plant-human exposure.
m The person conducting the remediation has the option to use: (1) TCLP or SPLP test results to compare with the remediation objectives listed in this Table; (2) the total amount of contaminant in the soil sample results to compare with pH specific remediation objectives listed in Appendix B, Table C or D of this Part (see Section 742.510); or (3) the appropriate background value listed in Appendix A, Table G. If the person conducting the remediation wishes to calculate soil remediation objectives based on background concentrations, this should be done in accordance with Subpart D of this Part.
n The Agency reserves the right to evaluate the potential for remaining contaminant concentrations to pose significant threats to crops, livestock, or wildlife.
o For agrichemical facilities, remediation objectives for surficial soils which are based on field application rates may be more appropriate for currently registered pesticides. Consult the Agency for further information.
p For agrichemical facilities, soil remediation objectives based on site-specific background concentrations of Nitrate as N may be more appropriate. Such determinations shall be conducted in accordance with the procedures set forth in Subparts D and I of this Part.
q The TCLP extraction must be done using water at a pH of 7.0.
r Value based on dietary Reference Dose.
s Value for Ingestion based on Reference Dose for Mercuric chloride (CAS No. 7487-94-7); value for Inhalation based on Reference Concentration for elemental Mercury (CAS No. 7439-97-6). Inhalation remediation objective only applies at sites where elemental mercury is a contaminant of concern.
t For the ingestion route for arsenic for industrial/commercial, see 742.Appendix A, Table G.
u Value based on Reference Dose for Thallium sulfate (CAS No. 7446-18-6).
w Value based on Reference Dose adjusted for dietary intake.
x For any populated areas as defined in Section 742.200, Appendix A, Table H may be used.
y Value based on maintaining fetal blood lead below 10 ug/d1, using the USEPA adults Blood Lead Model.(Source: Amended at 31 Ill. Reg. 4063, effective February 23, 2007)
Section 742.APPENDIX B Tier 1 Illustrations and Tables
Section 742.Table C pH Specific Soil Remediation Objectives for Inorganics and Ionizing Organics for the Soil Component of the Groundwater Ingestion Route (Class I Groundwater)
Chemical (totals)
(mg/kg)pH 4.5 to 4.74 pH 4.75 to 5.24 pH 5.25 to 5.74 pH 5.75 to 6.24 pH 6.25 to 6.64 pH 6.65 to 6.89 pH 6.9
to 7.24pH 7.25
to 7.74pH 7.75
to 8.24pH 8.25
to 8.74pH 8.75
to 9.0Inorganics Antimony 5 5 5 5 5 5 5 5 5 5 5 Arsenic 25 26 27 28 29 29 29 30 31 32 33 Barium 260 490 850 1,200 1,500 1,600 1,700 1,800 2,100 __a __a Beryllium 1.1 2.1 3.4 6.6 22 63 140 1,000 8,000 __a __a Cadmium 1.0 1.7 2.7 3.7 5.2 7.5 11 59 430 __a __a Chromium (+6) 70 62 54 46 40 38 36 32 28 24 21 Copper 330 580 2,100 11,000 59,000 130,000 200,000 330,000 330,000 __a __a Cyanide 40 40 40 40 40 40 40 40 40 40 40 Lead 23 23 23 23 107 107 107 107 107 107 282 Mercury 0.01 0.01` 0.03 0.15 0.89 2.1 3.3 6.4 8.0 __a __a Nickel 20 36 56 76 100 130 180 700 3,800 __a __a Selenium 24 17 12 8.8 6.3 5.2 4.5 3.3 2.4 1.8 1.3 Silver 0.24 0.33 0.62 1.5 4.4 8.5 13 39 110 __a __a Thallium 1.6 1.8 2.0 2.4 2.6 2.8 3.0 3.4 3.8 4.4 4.9 Vanadium 980 980 980 980 980 980 980 980 980 980 980 Zinc 1,000 1,800 2,600 3,600 5,100 6,200 7,500 16,000 53,000 __a __a
Organics Benzoic Acid 440 420 410 400 400 400 400 400 400 400 400 2-Chlorophenol 4.0 4.0 4.0 4.0 3.9 3.9 3.9 3.6 3.1 2.2 1.5 2,4-Dichlorophenol 1.0 1.0 1.0 1.0 1.0 1.0 1.0 0.86 0.69 0.56 0.48 Dinoseb 8.4 4.5 1.9 0.82 0.43 0.34 0.31 0.27 0.25 0.25 0.25 Pentachlorophenol 0.54 0.32 0.15 0.07 0.04 0.03 0.02 0.02 0.02 0.02 0.02 2,4,5-TP (Silvex) 26 16 12 11 11 11 11 11 11 11 11 2,4,5-Trichlorophenol 400 390 390 370 320 270 230 130 64 36 26 2,4,6-Trichlorophenol 0.37 0.36 0.34 0.29 0.20 0.15 0.13 0.09 0.07 0.07 0.07 a No data available for this pH range.
(Source: Amended at 31 Ill. Reg. 4063, effective February 23, 2007)
Section 742.APPENDIX B Tier 1 Illustrations and Tables
Section 742.Table D pH Specific Soil Remediation Objectives for Inorganics and Ionizing Organics for the Soil Component of the Groundwater Ingestion Route (Class II Groundwater)
Chemical (totals)
(mg/kg)pH 4.5 to 4.74 pH 4.75 to 5.24 pH 5.25 to 5.74 pH 5.75 to 6.24 pH 6.25 to 6.64 pH 6.65 to 6.89 pH 6.9
to 7.24pH 7.25
to 7.74pH 7.75
to 8.24pH 8.25
to 8.74pH 8.75
to 9.0Inorganics Antimony 20 20 20 20 20 20 20 20 20 20 20 Arsenic 100 100 100 110 110 120 120 120 120 130 130 Barium 260 490 850 1,200 1,500 1,600 1,700 1,800 2,100 __a __a Beryllium 140 260 420 820 2,800 7,900 17,000 130,000 1,000,000 __a __a Cadmium 10 17 27 37 52 75 110 590 4,300 __a __a Chromium (+6) No Data No Data No Data No Data No Data No Data No Data No Data No Data No Data No Data Copper 330 580 2,100 11,000 59,000 130,000 200,000 330,000 330,000 __a __a Cyanide 120 120 120 120 120 120 120 120 120 120 120 Lead 300 300 300 300 1,420 1,420 1,420 1,420 1,420 1,420 3,760 Mercury 0.05 0.06 0.14 0.75 4.4 10 16 32 40 __a __a Nickel 400 730 1,100 1,500 2,000 2,600 3,500 14,000 76,000 __a __a Selenium 24 17 12 8.8 6.3 5.2 4.5 3.3 2.4 1.8 1.3 Thallium 16 18 20 24 26 28 30 34 38 44 49 Zinc 2,000 3,600 5,200 7,200 10,000 12,000 15,000 32,000 110,000 __a __a Organics Benzoic Acid 440 420 410 400 400 400 400 400 400 400 400 2-Chlorophenol 20 20 20 20 20 20 19 3.6 3.1 2.2 1.5 2,4- Dichlorophenol
1.0 1.0 1.0 1.0 1.0 1.0 1.0 0.86 0.69 0.56 0.48 Dinoseb 84 45 19 8.2 4.3 3.4 3.1 2.7 2.5 2.5 2.5 Pentachlorophenol 2.7 1.6 0.75 0.33 0.18 0.15 0.12 0.11 0.10 0.10 0.10 2,4,5-TP (Silvex) 130 79 62 57 55 55 55 55 55 55 55 2,4,5-Trichlorophenol 2,000 2,000 1,900 1,800 1,600 1,400 1,200 640 64 36 26 2,4,6-Trichlorophenol 1.9 1.8 1.7 1.4 1.0 0.77 0.13 0.09 0.07 0.07 0.07 a No data available for this pH range.
(Source: Amended at 31 Ill. Reg. 4063, effective February 23, 2007)
Section 742.APPENDIX B Tier 1 Illustrations and Tables
Section 742.TABLE E Tier 1 Groundwater Remediation Objectives for the Groundwater Component of the Groundwater Ingestion Route
Chemical Name Organics
(mg/L)
(mg/L)83-32-9 Acenaphthene 0.42 2.1 67-64-1 Acetone 6.3 6.3 15972-60-8 Alachlor 0.002c 0.01c 116-06-3 Aldicarb 0.003c 0.015c 309-00-2 Aldrin 0.014a 0.07 120-12-7 Anthracene 2.1 10.5 1912-24-9 Atrazine 0.003c 0.015c 71-43-2 Benzene 0.005c 0.025c 56-55-3 Benzo(a)anthracene 0.00013a 0.00065 205-99-2 Benzo(b)fluoranthene 0.00018a 0.0009 207-08-9 Benzo(k)fluroanthene 0.00017a 0.00085 50-32-8 Benzo(a)pyrene 0.0002a,c 0.002c 65-85-0 Benzoic Acid 28 28 111-44-4 Bis(2-chloroethyl)ether 0.01a 0.01 117-81-7 Bis(2-ethylhexyl)phthalate (Di(2-ethylhexyl)phthalate) 0.006c 0.06c 75-27-4 Bromodichloromethane
(Dichlorobromomethane)0.0002a 0.0002 75-25-2 Bromoform 0.001a 0.001 71-36-3 Butanol 0.7 0.7 85-68-7 Butyl benzyl phthalate 1.4 7.0 86-74-8 Carbazole --- --- 1563-66-2 Carbofuran 0.04c 0.2c 75-15-0 Carbon disulfide 0.7 3.5 56-23-5 Carbon tetrachloride 0.005c 0.025c 57-74-9 Chlordane 0.002c 0.01c
Chemical Name
(mg/L)
(mg/L)106-47-8 4-Chloroaniline (r-Chloroaniline) 108-90-7 Chlorobenzene
(Monochlorobenzene)0.1c 0.5c 124-48-1 Chlorodibromomethane
(Dibromochloromethane)0.14 0.14 67-66-3 Chloroform 0.0002a 0.001 95-57-8 2-Chlorophenol (pH 4.9-7.3) 0.035 0.175 2-Chlorophenol (pH 7.4-8.0) 0.035 0.035 218-01-9 Chrysene 0.0015a 0.0075 94-75-7 2,4-D 0.07c 0.35c 75-99-0 Dalapon 0.2c 2.0c 72-54-8 DDD 0.014a 0.07 72-55-9 DDE 0.01a 0.05 50-29-3 DDT 0.006a 0.03 53-70-3 Dibenzo(a,h)anthracene 0.0003a 0.0015 96-12-8 1,2-Dibromo-3-chloropropane 0.0002c 0.002 c 106-93-4 1,2-Dibromoethane
(Ethylene dibromide)0.00005c 0.0005c 84-74-2 Di-n-butyl phthalate 0.7 3.5 95-50-1 1,2-Dichlorobenzene
(o – Dichlorobenzene)0.6c 1.5c 106-46-7 1,4-Dichlorobenzene
(p – Dichlorobenzene)0.075c 0.375c 91-94-1 3,3’-Dichlorobenzidine 0.02a 0.1 75-34-3 1,1-Dichloroethane 0.7 3.5 107-06-2 1,2-Dichloroethane
(Ethylene dichloride)0.005c 0.025c 75-35-4 1,1-Dichloroethyleneb 0.007c 0.035c 156-59-2 cis-1,2-Dichloroethylene 0.07c 0.2c 156-60-5 trans-1,2-Dichloroethylene 0.1c 0.5c 120-83-2 2,4-Dichlorophenol 0.021 0.021 78-87-5 1,2-Dichloropropane 0.005c 0.025c 542-75-6 1,3-Dichloropropene
(1,3-Dichloropropylene, cis + trans)0.001a 0.005
Chemical Name
(mg/L)
(mg/L)60-57-1 Dieldrin 0.009a 0.045 84-66-2 Diethyl phthalate 5.6 5.6 105-67-9 2,4-Dimethylphenol 0.14 0.14 51-28-5 2,4-Dinitrophenol 0.014 0.014 121-14-2 2,4-Dinitrotoluene 0.00002a 0.00002 606-20-2 2,6-Dinitrotoluene 0.00031a 0.00031 88-85-7 Dinoseb 0.007c 0.07c 117-84-0 Di-n-octyl phthalate 0.14 0.7 115-29-7 Endosulfan 0.042 0.21 145-73-3 Endothall 0.1c 0.1c 72-20-8 Endrin 0.002c 0.01c 100-41-4 Ethylbenzene 0.7c 1.0c 206-44-0 Fluoranthene 0.28 1.4 86-73-7 Fluorene 0.28 1.4 76-44-8 Heptachlor 0.0004c 0.002c 1024-57-3 Heptachlor epoxide 0.0002c 0.001c 118-74-1 Hexachlorobenzene 0.00006a 0.0003 319-84-6 alpha-HCH (alpha-BHC) 0.00011a 0.00055 58-89-9 Gamma-HCH (Lindane) 0.0002c 0.001c 77-47-4 Hexachlorocyclopentadiene 0.05c 0.5c 67-72-1 Hexachloroethane 0.007 0.035 193-39-5 Indeno(1,2,3-c,d)pyrene 0.00043a 0.00215 78-59-1 Isophorone 1.4 1.4 72-43-5 Methoxychlor 0.04c 0.2c 74-83-9 Methyl bromide
(Bromomethane)0.0098 0.049 1634-04-4 Methyl tertiary-butyl ether 0.07 0.07 75-09-2 Methylene chloride
(Dichloromethane)0.005c 0.05c 95-48-7 2-Methylphenol (o-Cresol) 0.35 0.35 91-20-3 Naphthalene 0.14 0.22 98-95-3 Nitrobenzeneb 0.0035 0.0035
Chemical Name
(mg/L)
(mg/L)86-30-6 N-Nitrosodiphenylamine 0.0032 a 0.016 621-64-7 N-Nitrosodi-n-propylamine 0.0018 a 0.0018 87-86-5 Pentachlorophenol 0.001c 0.005c 108-95-2 Phenol 0.1c 0.1c 1918-02-1 Picloram 0.5c 5.0c 1336-36-3 Polychlorinated biphenyls (PCBs) 0.0005c 0.0025c 129-00-0 Pyrene 0.21 1.05 122-34-9 Simazine 0.004c 0.04c 100-42-5 Styrene 0.1c 0.5c 93-72-1 2,4,5-TP
(Silvex)0.05c 0.25c 127-18-4 Tetrachloroethylene
(Perchloroethylene)0.005c 0.025c 108-88-3 Toluene 1.0c 2.5c 8001-35-2 Toxaphene 0.003c 0.015c 120-82-1 1,2,4-Trichlorobenzene 0.07c 0.7c 71-55-6 1,1,1-Trichloroethaneb 0.2c 1.0c 79-00-5 1,1,2-Trichloroethane 0.005c 0.05c 79-01-6 Trichloroethylene 0.005c 0.025c 95-95-4 2,4,5-Trichlorophenol (pH 4.9-7.8) 0.7 3.5 2,4,5-Trichlorophenol (pH 7.9-8.0) 0.7 0.7 88-06-2 2,4,6-Trichlorophenol (pH 4.9-6.8) 0.01a 0.05 2,4,6-Trichlorophenol (pH 6.9-8.0) 0.01 0.01 108-05-4 Vinyl acetate 7.0 7.0 75-01-4 Vinyl chloride 0.002c 0.01c 1330-20-7 Xylenes (total) 10.0c 10.0c
Chemical Name
(mg/L)
(mg/L)Inorganics 7440-36-0 Antimony 0.006c 0.024c 7440-38-2 Arsenic 0.05c 0.2c 7440-39-3 Barium 2.0c 2.0c 7440-41-7 Beryllium 0.004c 0.5c 7440-42-8 Boron 2.0c 2.0c 7440-43-9 Cadmium 0.005c 0.05c 7440-70-2 Calcium ---d ---d 16887-00-6 Chloride 200c 200c 7440-47-3 Chromium, total 0.1c 1.0c 18540-29-9 Chromium, ion, hexavalent --- --- 7440-48-4 Cobalt 1.0c 1.0c 7440-50-8 Copper 0.65c 0.65c 57-12-5 Cyanide 0.2c 0.6c 7782-41-4 Fluoride 4.0c 4.0c
15438-31-0 Iron 5.0c 5.0c 7439-92-1 Lead 0.0075c 0.1c 7439-95-4 Magnesium ---d ---d 7439-96-5 Manganese 0.15c 10.0c 7439-97-6 Mercury 0.002c 0.01c 7440-02-0 Nickel 0.1c 2.0c 14797-55-8 Nitrate as N 10.0c 100c 7723-14-0 Phosphorus ---d ---d 7440-09-7 Potassium ---d ---d 7782-49-2 Selenium 0.05c 0.05c
Chemical Name
(mg/L)
(mg/L)7440-22-4 Silver 0.05c --- 7440-23-5 Sodium ---d ---d 14808-79-8 Sulfate 400c 400c 7440-28-0 Thallium 0.002c 0.02c 7440-62-2 Vanadiumb 0.049 0.1 7440-66-6 Zinc 5.0c 10c
Chemical Name and Groundwater Remediation Objective Notations
a The groundwater remediation objective is equal to the ADL for carcinogens according to the procedures specified in 35 Ill. Adm. Code 620.
b Oral Reference Dose and/or Reference Concentration under review by USEPA. Listed values subject to change.
c Value listed is also the Groundwater Quality Standard for this chemical pursuant to 35 Ill. Adm. Code 620.410 for Class I Groundwater or 35 Ill. Adm. Code 620.420 for Class II Groundwater.
d This chemical is included in the Total Dissolved Solids (TDS) Groundwater Quality Standard of 1,200 mg/l pursuant to 35 Ill. Adm. Code 620.410 for Class I Groundwater or 35 Ill. Adm. Code 620.420 for Class II Groundwater.
(Source: Amended at 31 Ill. Reg. 4063, effective February 23, 2007)
Section 742.APPENDIX B Tier 1 Illustrations and Tables
Section 742.TABLE F Values Used to Calculate the Tier 1 Soil Remediation Objectives for the Soil Component of the Groundwater Ingestion Route
Tier 1 Soil Remediation ObjectivesaChemical Name Organics
(mg/L)
(mg/L)83-32-9 Acenaphthene 2.0b 10 67-64-1 Acetone 6.3 6.3 15972-60-8 Alachlor 0.002c 0.01c 116-06-3 Aldicarb 0.003c 0.015c 309-00-2 Aldrin 5.0E-6b 2.5E-5 120-12-7 Anthracene 10b 50 1912-24-9 Atrazine 0.003c 0.015c 71-43-2 Benzene 0.005c 0.025c 56-55-3 Benzo(a)anthracene 0.0001b 0.0005 205-99-2 Benzo(b)fluoranthene 0.0001b 0.0005 207-08-9 Benzo(k)fluroanthene 0.001b 0.005 50-32-8 Benzo(a)pyrene 0.0002a,c 0.002c 65-85-0 Benzoic Acid 100b 100 111-44-4 Bis(2-chloroethyl)ether 8.0E-5b 8.0E-5 117-81-7 Bis(2-ethylhexyl)phthalate (Di(2-ethylhexyl)phthalate) 0.006a,c 0.06c 75-27-4 Bromodichloromethane
(Dichlorobromomethane)0.1b 0.1 75-25-2 Bromoform 0.1b 0.01 71-36-3 Butanol 4.0b 4.0 85-68-7 Butyl benzyl phthalate 7.0b 35 86-74-8 Carbazole 0.004b 0.02 1563-66-2 Carbofuran 0.04c 0.2c 75-15-0 Carbon disulfide 4.0b 20 56-23-5 Carbon tetrachloride 0.005c 0.025c 57-74-9 Chlordane 0.002c 0.01c
Tier 1 Soil Remediation ObjectivesaChemical Name
(mg/L)
(mg/L)4-Chloroaniline ( r -Chloroaniline) 108-90-7 Chlorobenzene
(Monochlorobenzene)0.1c 0.5c 124-48-1 Chlorodibromomethane
(Dibromochloromethane)0.06b 0.06 67-66-3 Chloroform 0.1b 0.5 95-57-8 2-Chlorophenol (pH 4.9-7.3) 0.2b 1.0 2-Chlorophenol (pH 7.4-8.0) 0.2 0.2 218-01-9 Chrysene 0.1b 0.05 94-75-7 2,4-D 0.07c 0.35c 75-99-0 Dalapon 0.2c 2.0c 72-54-8 DDD 0.0004b 0.002 72-55-9 DDE 0.0003b 0.0015 50-29-3 DDT 0.0003b 0.0015 53-70-3 Dibenzo(a,h)anthracene 1.0E-5b 5.0E-5 96-12-8 1,2-Dibromo-3-chloropropane 0.0002c 0.002 c 106-93-4 1,2-Dibromoethane
(Ethylene dibromide)0.00005a,c 0.0005c 84-74-2 Di-n-butyl phthalate 4.0b 20 95-50-1 1,2-Dichlorobenzene
(o – Dichlorobenzene)0.6c 1.5c 106-46-7 1,4-Dichlorobenzene
(p – Dichlorobenzene)0.075c 0.375c 91-94-1 3,3’-Dichlorobenzidine 0.0002b 0.001 75-34-3 1,1-Dichloroethane 4.0b 20 107-06-2 1,2-Dichloroethane
(Ethylene dichloride)0.005c 0.025c 75-35-4 1,1-Dichloroethylene 0.007c 0.035c 156-59-2 cis-1,2-Dichloroethylene 0.07c 0.2c 156-60-5 trans-1,2-Dichloroethylene 0.1c 0.5c 120-83-2 2,4-Dichlorophenol 0.1b 0.1 78-97-5 1,2-Dichloropropane 0.005c 0.025c 542-75-6 1,3-Dichloropropene
(1,3-Dichloropropylene, cis + trans)0.0005b 0.0025
Tier 1 Soil Remediation ObjectivesaChemical Name
(mg/L)
(mg/L)60-57-1 Dieldrin 5.0E-6b 2.5E-5 84-66-2 Diethyl phthalate 30b 30 105-67-9 2,4-Dimethylphenol 0.7b 0.7 51-28-5 2,4-Dinitrophenol 0.04b 0.04 121-14-2 2,4-Dinitrotoluene 0.0001b 0.0001 606-20-2 2,6-Dinitrotoluene 0.0001 0.0001 88-85-7 Dinoseb 0.007c 0.07c 117-84-0 Di-n-octyl phthalate 0.7b 3.5 115-29-7 Endosulfan 0.2b 1.0 145-73-3 Endothall 0.1c 0.1c 72-20-8 Endrin 0.002c 0.01c 100-41-4 Ethylbenzene 0.7c 1.0c 206-44-0 Fluoranthene 1.0b 5.0 86-73-7 Fluorene 1.0b 5.0 76-44-8 Heptachlor 0.0004c 0.002c 1024-57-3 Heptachlor epoxide 0.0002c 0.001c 118-74-1 Hexachlorobenzene 0.001b 0.005 319-84-6 alpha-HCH (alpha-BHC) 1.0E-5b 5.0E-5 58-89-9 Gamma-HCH (Lindane) 0.0002c 0.001c 77-47-4 Hexachlorocyclopentadiene 0.05c 0.5c 67-72-1 Hexachloroethane 0.007 0.035 193-39-5 Indeno(1,2,3-c,d)pyrene 0.0001b 0.0005 78-59-1 Isophorone 1.4 1.4 72-43-5 Methoxychlor 0.04c 0.2c 74-83-9 Methyl bromide
(Bromomethane)0.05b 0.25 1634-04-4 Methyl tertiary-butyl ether 0.07 0.07 75-09-2 Methylene chloride
(Dichloromethane)0.005c 0.05c 95-48-7 2-Methylphenol (o-Cresol) 2.0b 2.0 91-20-3 Naphthalene 0.14 0.22 98-95-3 Nitrobenzene 0.02b 0.02
Tier 1 Soil Remediation ObjectivesaChemical Name
(mg/L)
(mg/L)86-30-6 N-Nitrosodiphenylamine 0.02b 0.1 621-64-7 N-Nitrosodi-n-propylamine 1.0E-5b 1.0E-5 87-86-5 Pentachlorophenol 0.001a,c 0.005c 108-95-2 Phenol 0.1c 0.1c 1918-02-1 Picloram 0.5c 5.0c 1336-36-3 Polychlorinated biphenyls (PCBs) --- --- 129-00-0 Pyrene 1.0b 5.0 122-34-9 Simazine 0.004c 0.04c 100-42-5 Styrene 0.1c 0.5c 93-72-1 2,4,5-TP
(Silvex)0.05c 0.25c 127-18-4 Tetrachloroethylene
(Perchloroethylene)0.005c 0.025c 108-88-3 Toluene 1.0c 2.5c 8001-35-2 Toxaphene 0.003c 0.015c 120-82-1 1,2,4-Trichlorobenzene 0.07c 0.7c 71-55-6 1,1,1-Trichloroethane 0.2c 1.0c 79-00-5 1,1,2-Trichloroethane 0.005c 0.05c 79-01-6 Trichloroethylene 0.005c 0.025c 95-95-4 2,4,5-Trichlorophenol (pH 4.9-7.8) 4.0b 20 2,4,5-Trichlorophenol (pH 7.9-8.0) 4.0 4.0 88-06-2 2,4,6-Trichlorophenol (pH 4.9-6.8) 0.008b 0.04 2.4.6-Trichlorophenol (pH 6.9-8.0) 0.008 0.008 108-05-4 Vinyl acetate 40b 40 75-01-4 Vinyl chloride 0.002c 0.01c 1330-20-7 Xylenes (total) 10.0c 10.0c
Tier 1 Soil Remediation ObjectivesaChemical Name
(mg/L)
(mg/L)Inorganics 7440-36-0 Antimony 0.006c 0.024c 7440-38-2 Arsenic 0.05c 0.2c 7440-39-3 Barium 2.0c 2.0c 7440-41-7 Beryllium 0.004c 0.5c 7440-42-8 Boron 2.0c 2.0c 7440-43-9 Cadmium 0.005c 0.05c 7440-70-2 Calcium --- --- 16887-00-6 Chloride 200c 200c 7440-47-3 Chromium, total 0.1c 1.0c 18540-29-9 Chromium, ion, hexavalent --- --- 7440-48-4 Cobalt 1.0c 1.0c 7440-50-8 Copper 0.65c 0.65c 57-12-5 Cyanide 0.2c 0.6c 7782-41-4 Fluoride 4.0c 4.0c
15438-31-0 Iron 5.0c 5.0c 7439-92-1 Lead 0.0075c 0.1c 7439-95-4 Magnesium --- --- 7439-96-5 Manganese 0.15c 10.0c 7439-97-6 Mercury 0.002c 0.01c 7440-02-0 Nickel 0.1c 2.0c 14797-55-8 Nitrate as N 10.0c 100c
Tier 1 Soil Remediation ObjectivesaChemical Name
(mg/L)
(mg/L)7723-14-0 Phosphorus --- --- 7440-09-7 Potassium --- --- 7782-49-2 Selenium 0.05c 0.05c 7440-22-4 Silver 0.05c --- 7440-23-5 Sodium --- --- 14808-79-8 Sulfate 400c 400c 7440-28-0 Thallium 0.002c 0.02c 7440-62-2 Vanadium 0.049 0.1 7440-66-6 Zinc 5.0c 10c
Chemical Name and Groundwater Remediation Objective Notations
a The Equation S17 is used to calculate the Soil Remediation Objective for the Soil Component of the Groundwater Ingestion Route; this equation requires calculation of the Target Soil Leachate Concentration (Cw) from Equation S18: Cw = DF x GWobj.
b Value listed is the Water Health Based Limit (HBL) for this chemical from Soil Screening Guidance: User’s Guide, incorporated by reference at Section 742.210. The HBL is equal to the non-zero MCLG (if available); the MCL (if available); or, for carcinogens, a cancer risk of 1.0E-6, and for noncarcinogens is equal to a Hazard Quotient of 1.0. NOTE: These GWobj concentrations are not equal to the Tier 1 Groundwater Remediation Objectives for the Direct Ingestion of Groundwater Component of the Groundwater Ingestion Route, listed in Section 742.Appendix B, Table E.
c Value listed is also the Groundwater Quality Standard for this chemical pursuant to 35 Ill. Adm. Code 620.410 for Class I Groundwater or 35 Ill. Adm. Code 620.420 for Class II Groundwater.
(Source: Amended at 31 Ill. Reg. 4063, effective February 23, 2007)
Section 742.APPENDIX B: Tier 1 Illustrations and Tables
Section 742.TABLE G: Tier 1 Soil Gas Remediation Objectives for the Outdoor Inhalation Exposure Routea
(mg/m3)
(mg/m3)
(mg/m3)
67-64-1 Acetone 750,000e 750,000e 750,000e 71-43-2 Benzene 420c 800c 1,100c 111-44-4 Bis(2-chloroethyl)ether 1.3c 2.4c 3.4c 75-27-4 Bromodichloromethane 450,000e 450,000e 450,000e 75-25-2 Bromoform 1,800c 3,500c 4,900c 71-36-3 Butanol 29,000e 29,000e 29,000e 78-93-3 2-Butanone (MEK) 380,000e 380,000e 15,000b 75-15-0 Carbon disulfide 1,500,000e 1,500,000e 48,000b 56-23-5 Carbon tetrachloride 290c 550c 770c 108-90-7 Chlorobenzene 36,000b 57,000b 3,700b 124-48-1 Chlorodibromomethane 57,000e 57,000e 150b 67-66-3 Chloroform 110c 200c 290c 95-57-8 2-Chlorophenol 17,000e 17,000e 17,000e 75-99-0 Dalapon 1,500e 1,500e 1,500e 96-12-8 1,2-Dibromo-3-chloropropane 0.14c 0.27c 0.38c 106-93-4 1,2-Dibromoethane 2.9c 5.6c 7.9c 95-50-1 1,2-Dichlorobenzene 11,000e 11,000e 6,700b 106-46-7 1,4-Dichlorobenzene 8,400e 8,400e 6,400b 75-71-8 Dichlorodifluoromethane 890,000b 1,400,000b 92,000b 75-34-3 1,1-Dichloroethane 870,000b 1,300,000e 90,000b 107-06-2 1,2-Dichloroethane 67c 130c 180c 75-35-4 1,1-Dichloroethylene 520,000b 820,000b 5,300b 156-59-2 cis-1,2-Dichloroethylene 1,100,000e 1,100,000e 1,100,000e 156-60-5 trans-1,2-Dichloroethylene 120,000b 190,000b 12,000b 78-87-5 1,2-Dichloropropane 240c 470c 110c 542-75-6 1,3-Dichloropropylene (cis + trans) 1,900c 3,700c 1,400c 123-91-1 p-Dioxane 16c 30c 42c 100-41-4 Ethylbenzene 59,000e 59,000e 8,500b 76-44-8 Heptachlor 0.40c 0.76c 1.1c 118-74-1 Hexachlorobenzene 0.26c 0.28e 0.28e 77-47-4 Hexachlorocyclopentadiene 85b 140b 440b 67-72-1 Hexachloroethane 2,800e 2,800e 2,800e 78-59-1 Isophorone 3,400e 3,400e 1,500b 98-82-8 Isopropylbenzene (Cumene) 30,000e 30,000e 30,000e 7439-97-6 Mercuryf 22e 22e 0.62b 74-83-9 Methyl bromide 12,000b 19,000b 2,400b 1634-04-4 Methyl tertiary-butyl ether 1,200,000e 1,200,000e 23,000b 75-09-2 Methylene chloride 6,100c 12,000c 5,100b 91-57-6 2-Methylnaphthalene 530e 530e 530e 95-48-7 2-Methylphenol (o-cresol) 1,800e 1,800e 410b 91-20-3 Naphthalene 560b 620e 5.8b 98-95-3 Nitrobenzene 6.5c 12c 10b 621-64-7 n-Nitrosodi-n-propylamine 0.056c 0.11c 0.15c 108-95-2 Phenol 1,500e 1,500e 79b 1336-36-3 Polychlorinated biphenyls (PCBs) ---d ---d ---d 100-42-5 Styrene 34,000e 34,000e 16,000b 127-18-4 Tetrachloroethylene 360c 690c 970c 108-88-3 Toluene 140,000e 140,000e 50,000b 120-82-1 1,2,4-Trichlorobenzene 1,000b 1,600b 110b 71-55-6 1,1,1-Trichloroethane 870,000e 870,000e 89,000b 79-00-5 1,1,2-Trichloroethane 170,000e 170,000e 170,000e 79-01-6 Trichloroethylene 1,700c 3,300c 1,500b 75-69-4 Trichlorofluoromethane 2,100,000b 3,400,000b 220,000b 108-05-4 Vinyl acetate 160,000b 250,000b 1,600b 75-01-4 Vinyl chloride 780c 3,000c 3,000b 108-38-3 m-Xylene 52,000e 52,000e 3,100b 95-47-6 o-Xylene 41,000e 41,000e 2,600b 106-42-3 p-Xylene 55,000e 55,000e 3,300b 1330-20-7 Xylenes (total) 49,000e 49,000e 2,900b
Chemical Name and Remediation Objective Notations
a For the outdoor inhalation exposure route, it is acceptable to determine compliance by meeting either the soil or soil gas remediation objectives. The soil remediation objectives for the outdoor inhalation route are located in Appendix B, Tables A and B.
b Calculated values correspond to a target hazard quotient of 1.
c Calculated values correspond to a cancer risk level of 1 in 1,000,000.
d PCBs are a mixture of different congeners. The appropriate values to use for the physical/chemical and toxicity parameters depend on the congeners present at the site. Persons remediating sites should consult with IEPA Bureau of Land (BOL) if calculation of Tier 2 or 3 remediation objectives is desired.
e The value shown is the Cvsat value of the chemical in soil gas. The Cvsat of the chemical becomes the remediation objective if the calculated value exceeds the Cvsat value or if there are no toxicity criteria available for the inhalation route of exposure.
f Value for the inhalation exposure route is based on Reference Concentration for elemental Mercury (CAS No. 7439-97-6). Inhalation remediation objectives only apply at sites where elemental Mercury is a contaminant of concern.
(Source: Added at 37 Ill. Reg. 7506, effective July 15, 2013)
Section 742.APPENDIX B: Tier 1 Illustrations and Tables
Section 742.TABLE H: Tier 1 Soil Gas and Groundwater Remediation Objectives for the Indoor Inhalation Exposure Route – Diffusion and Advectionj
Qsoil equals 83.33 cm3/seca
Groundwater CAS No. Chemical Name
(mg/m3)
(mg/m3)
(mg/L)
(mg/L)67-64-1 Acetone 71-43-2 Benzene 111-44-4 Bis(2-chloroethyl)ether 75-27-4 Bromodichloromethane 75-25-2 Bromoform 71-36-3 Butanol 78-93-3 2-Butanone (MEK) 75-15-0 Carbon disulfide 56-23-5 Carbon tetrachloride 108-90-7 Chlorobenzene 124-48-1 Chlorodibromomethane 67-66-3 Chloroform 95-57-8 2-Chlorophenol 75-99-0 Dalapone 96-12-8 1,2-Dibromo-3-chloropropanee 106-93-4 1,2-Dibromoethane 95-50-1 1,2-Dichlorobenzene 106-46-7 1,4-Dichlorobenzene 75-71-8 Dichlorodifluoromethane 75-34-3 1,1-Dichloroethane 107-06-2 1,2-Dichloroethane 75-35-4 1,1-Dichloroethylene 156-59-2 cis-1,2-Dichloroethylene 156-60-5 trans-1,2-Dichloroethylene 78-87-5 1,2-Dichloropropane 542-75-6 1,3-Dichloropropylene (cis + trans) 123-91-1 p-Dioxane 100-41-4 Ethylbenzene 76-44-8 Heptachlor 118-74-1 Hexachlorobenzene 77-47-4 Hexachlorocyclopentadiene 67-72-1 Hexachloroethane 78-59-1 Isophorone 98-82-8 Isopropylbenzene (Cumene) 7439-97-6 Mercuryh 74-83-9 Methyl bromide 1634-04-4 Methyl tertiary-butyl ether 75-09-2 Methylene chloride 91-57-6 2-Methylnaphthalene 95-48-7 2-Methylphenol (o-cresol) 91-20-3 Naphthalene 98-95-3 Nitrobenzene 621-64-7 n-Nitrosodi-n-propylamine 108-95-2 Phenol 1336-36-3 Polychlorinated biphenyls (PCBs) 100-42-5 Styrene 127-18-4 Tetrachloroethylene 108-88-3 Toluene 120-82-1 1,2,4-Trichlorobenzene 71-55-6 1,1,1-Trichloroethane 79-00-5 1,1,2-Trichloroethane 79-01-6 Trichloroethylene 75-69-4 Trichlorofluoromethane 108-05-4 Vinyl acetate 75-01-4 Vinyl chloride 108-38-3 m-Xylene 95-47-6 o-Xylene 106-42-3 p-Xylene 1330-20-7 Xylenes (total)e
Chemical Name and Remediation Objective Notations
a Compliance is determined by meeting either the soil gas remediation objectives or the groundwater remediation objectives. See Sections 742.505 and 742.515.
b Calculated values correspond to a target hazard quotient of 1.
c Calculated values correspond to a cancer risk level of 1 in 1,000,000.
d PCBs are a mixture of different congeners. The appropriate values to use for the physical/chemical and toxicity parameters depend on the congeners present at the site. Persons remediating sites should consult with BOL if calculation of Tier 2 or 3 remediation objectives is desired.
e Groundwater remediation objective calculated at 25°C. For Dalapon and 1,2-Dibromo-3-chloropropane, the critical temperature (Tc) and enthalpy of vaporization at the normal boiling point (Hv,b) are not available. For Xylenes (total), the enthalpy of vaporization at the normal boiling point (Hv,b) is not available.
f The value shown is the Cvsat value of the chemical in soil gas. The Cvsat of the chemical becomes the remediation objective if the calculated value exceeds the Cvsat value or if there are no toxicity criteria available for the inhalation route of exposure.
g The value shown is the solubility of the chemical in water. The solubility of the chemical becomes the remediation objective if the calculated value exceeds the solubility or if there are no toxicity criteria available for the ingestion route of exposure.
h Value for the inhalation exposure route is based on Reference Concentration for elemental Mercury (CAS No. 7439-97-6). Inhalation remediation objectives only apply at sites where elemental Mercury is a contaminant of concern.
i The value shown is the Groundwater Remediation Objective listed in Appendix B, Table E.
j Calculated values for the remediation objectives in this table are based on the assumption that the existing or potential building has a full concrete slab-on-grade, though the remediation objectives in this table are also considered protective of occupants of buildings with full concrete basement floors and walls. This table applies only when the existing or potential building has a full concrete slab-on-grade or a full concrete basement floor and walls. Institutional controls under Subpart J are required to use remediation objectives in this table. This table does not apply when the existing or potential building has neither a full concrete slab-on-grade nor a full concrete basement floor and walls, such as a building with an earthen crawl space, an earthen floor, a stone foundation, a partial concrete floor, or a sump. In such cases, site evaluators have the option of excluding the indoor inhalation exposure route under Section 742.312, meeting the building control technology requirements under Subpart L, or proposing an alternative approach under Tier 3.
(Source: Added at 37 Ill. Reg. 7506, effective July 15, 2013)
Section 742.APPENDIX B: Tier 1 Illustrations and Tables
Section 742.TABLE I: Tier 1 Soil Gas and Groundwater Remediation Objectives for the Indoor Inhalation Exposure Route – Diffusion Only j
Qsoil equals 0.0 cm3/seca,b
Groundwater CAS No. Chemical Name
(mg/m3)
(mg/m3)
(mg/L)
(mg/L)Acetone Benzene Bis(2-chloroethyl)ether Bromodichloromethane Bromoform Butanol 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chlorodibromomethane Chloroform 2-Chlorophenol Dalaponf 1,2-Dibromo-3-chloropropanef 1,2-Dibromoethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethylene cis-1,2-Dichloroethylene trans-1,2-Dichloroethylene 1,2-Dichloropropane 1,3-Dichloropropylene (cis + trans) p-Dioxane Ethylbenzene Heptachlor Hexachlorobenzene Hexachlorocyclopentadiene Hexachloroethane Isophorone Isopropylbenzene (Cumene) Mercuryi Methyl bromide Methyl tertiary-butyl ether Methylene chloride 2-Methylnaphthalene 2-Methylphenol (o-cresol) Naphthalene Nitrobenzene n-Nitrosodi-n-propylamine Phenol Polychlorinated biphenyls (PCBs) Styrene Tetrachloroethylene Toluene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethylene Trichlorofluoromethane Vinyl acetate Vinyl chloride m-Xylene o-Xylene p-Xylene Xylenes (total)f
Chemical Name and Remediation Objective Notations
a Compliance is determined by meeting both the soil gas remediation objectives and the groundwater remediation objectives. See Sections 742.505 and 742.515.
b Remediation objectives relying on this table require use of institutional controls in accordance with Subpart J.
c Calculated values correspond to a target hazard quotient of 1.
d Calculated values correspond to a cancer risk level of 1 in 1,000,000.
e PCBs are a mixture of different congeners. The appropriate values to use for the physical/chemical and toxicity parameters depend on the congeners present at the site. Persons remediating sites should consult with BOL if calculation of Tier 2 or 3 remediation objectives is desired
f Groundwater remediation objective calculated at 25°C. For Dalapon and 1,2-Dibromo-3-chloropropane, the critical temperature (Tc) and enthalpy of vaporization at the normal boiling point (Hv,b) are not available. For Xylenes (total), the enthalpy of vaporization at the normal boiling point (Hv,b) is not available.
g The value shown is the Cvsat value of the chemical in soil gas. The Cvsat of the chemical becomes the remediation objective if the calculated value exceeds the Cvsat value or if there are no toxicity criteria available for the inhalation route of exposure.
h The value shown is the solubility of the chemical in water. The solubility of the chemical becomes the remediation objective if the calculated value exceeds the solubility or if there are no toxicity criteria available for the inhalation route of exposure.
i Value for the inhalation exposure route is based on Reference Concentration for elemental Mercury (CAS No. 7439-97-6). Inhalation remediation objectives only apply at sites where elemental Mercury is a contaminant of concern.
j Calculated values for the remediation objectives in this table are based on the assumption that the existing or potential building has a full concrete slab-on-grade, though the remediation objectives in this table are also considered protective of occupants of buildings with full concrete basement floors and walls. This table applies only when the existing or potential building has a full concrete slab-on-grade or a full concrete basement floor and walls. Institutional controls under Subpart J are required to use remediation objectives in this table. This table does not apply when the existing or potential building has neither a full concrete slab-on-grade nor a full concrete basement floor and walls, such as a building with an earthen crawl space, an earthen floor, a stone foundation, a partial concrete floor, or a sump. In such cases, site evaluators have the option of excluding the indoor inhalation exposure route under Section 742.312, meeting the building control technology requirements under Subpart L, or proposing an alternative approach under Tier 3.
(Source: Added at 37 Ill. Reg. 7506, effective July 15, 2013)
Section 742.APPENDIX C Tier 2 Illustrations and Tables
Section 742.Illustration A Tier 2 Evaluation for Soil
(Source: Amended at 31 Ill. Reg. 4063, effective February 23, 2007)
Section 742.APPENDIX C Tier 2 Illustrations and Tables
Section 742.Illustration B Tier 2 Evaluation for Groundwater
(Source: Amended at 31 Ill. Reg. 4063, effective February 23, 2007)
Section 742.APPENDIX C Tier 2 Illustrations and Tables
Section 742.Illustration C U.S. Department of Agriculture Soil Texture Classification
(Source: Amended at 31 Ill. Reg. 4063, effective February 23, 2007)
Section 742.APPENDIX C: Tier 2 Illustrations and Tables
Section 742.Table A: SSL Equations
Equations for Soil Ingestion Exposure Route Remediation Objectives for Noncarcinogenic Contaminants
(mg/kg)
S1Remediation Objectives for Carcinogenic Contaminants - Residential
(mg/kg)
S2Remediation Objectives for Carcinogenic
Contaminants - Industrial/ Commercial, Construction Worker
(mg/kg)
S3Equations for Inhalation Exposure Route (Organic Contaminants and Mercury)
Remediation Objectives for Noncarcinogenic Contaminants - Residential, Industrial/ Commercial (mg/kg) 
S4Remediation Objectives for Noncarcinogenic Contaminants - Construction Worker (mg/kg) 
S5Remediation Objectives for Carcinogenic Contaminants - Residential, Industrial/ Commercial (mg/kg) 
S6Remediation Objectives for Carcinogenic Contaminants - Construction Worker (mg/kg)
S7Equation for Derivation of the Volatilization Factor - Residential, Industrial/ Commercial, VF (m3/kg) 
S8Equation for Derivation of the Volatilization Factor - Construction Worker, VF ¢ (m3/kg) 
S9Equation for Derivation
of Apparent Diffusivity, DA (cm2/s)
S10Equations for Inhalation Exposure Route (Fugitive Dusts) Remediation Objectives for Noncarcinogenic Contaminants - Residential, Industrial/Commercial (mg/kg) 
S11Remediation Objectives for Noncarcinogenic Contaminants - Construction Worker (mg/kg) 
S12
Remediation Objectives for Carcinogenic Contaminants - Residential, Industrial/ Commercial (mg/kg) 
S13
Remediation Objectives for Carcinogenic Contaminants - Construction Worker (mg/kg) 
S14
Equation for Derivation of Particulate Emission Factor, PEF (m3/kg) 
S15
Equation for Derivation of Particulate Emission Factor, PEF ¢ - Construction Worker (m3/kg) 
NOTE: PEF must be the industrial/commercial value
S16
Equations for the Soil Component of the Groundwater Ingestion Exposure Route Remediation Objective
(mg/kg)
NOTE: This equation can only be used to model contaminant migration not in the water bearing unit.
S17Target Soil Leachate Concentration, Cw
(mg/L)
S18
Soil-Water Partition Coefficient, Kd
(cm3/g)
S19
Water-Filled Soil Porosity, q w
(Lwater/Lsoil)
S20
Air-Filled Soil Porosity, q a
(Lair/Lsoil)
S21Dilution Factor, DF (unitless) 
S22
Groundwater Remediation Objective for Carcinogenic Contaminants, GWobj
(mg/L)
S23
Total Soil Porosity, h
(Lpore/Lsoil)
S24
Equation for Estimation of Mixing Zone Depth, d
(m)
S25
Mass-Limit Equations for Inhalation Exposure Route and Soil Component of the Groundwater Ingestion Exposure Route Mass-Limit Volatilization Factor for the Inhalation Exposure Route - Residential, Industrial/ Commercial, VF (m3/kg) 
NOTE: This equation may be used when vertical thickness of contamination is known or can be estimated reliably.
S26
Mass-Limit Volatilization Factor for Inhalation Exposure Route - Construction Worker, VF ¢ - (m3/kg)
S27
Mass-Limit Remediation Objective for Soil Component of the Groundwater Ingestion Exposure Route (mg/kg)
NOTE: This equation may be used when vertical thickness is known or can be estimated reliably.
S28Equation for Derivation of the Soil Saturation Limit, Csat
S29Equation for the soil gas component of the Outdoor Inhalation Exposure Route
ROsoil gas=ROsoil×H×ρb×1000H'×θa+θw+Kd×ρb
S30
(Source: Amended at 37 Ill. Reg. 7506, effective July 15, 2013)
Section 742.APPENDIX C: Tier 2 Illustrations and Tables
Section 742.Table B: SSL Parameters
Symbol Parameter Units Source Parameter Value(s) AT Averaging Time for Noncarcinogens in Ingestion Equation yr Residential = 6
Industrial/Commercial = 25
Construction Worker = 0.115AT Averaging Time for Noncarcinogens in Inhalation Equation yr Residential = 30
Industrial/Commercial = 25
Construction Worker = 0.115ATc Averaging Time for Carcinogens yr SSL 70 BW Body Weight kg Residential = 15, noncarcinogens
70, carcinogens
Industrial/Commercial = 70
Construction Worker = 70Csat Soil Saturation Concentration mg/kg Appendix A, Table A or
Equation S29 in
Appendix C, Table AChemical-Specific or
Calculated ValueCw Target Soil Leachate Concentration mg/L Equation S18 in
Appendix C, Table AGroundwater Standard, Health Advisory concentration, or
Calculated Valued Mixing Zone Depth m SSL or
Equation S25 in
Appendix C, Table A2 m or
Calculated Valueda Aquifer Thickness m Field Measurement Site-Specific ds Depth of Source (Vertical thickness of contamination)
m Field Measurement or Estimation Site-Specific DA Apparent Diffusivity cm2/s Equation S10 in
Appendix C, Table ACalculated Value Di Diffusivity in Air cm2/s Appendix C, Table E Chemical-Specific Dw Diffusivity in Water cm2/s Appendix C, Table E Chemical-Specific DF Dilution Factor unitless Equation S22 in
Appendix C, Table A20 or Calculated Value ED Exposure Duration for Ingestion of Carcinogens yr Industrial/Commercial = 25
Construction Worker = 1ED Exposure Duration for Inhalation of Carcinogens yr Residential = 30
Industrial/Commercial = 25
Construction Worker = 1ED Exposure Duration for Ingestion of Noncarcinogens yr Residential = 6
Industrial/Commercial = 25
Construction Worker = 1ED Exposure Duration for Inhalation of Noncarcinogens yr Residential = 30
Industrial/Commercial = 25
Construction Worker = 1ED Exposure Duration for the Direct Ingestion of Groundwater yr Residential = 30
Industrial/Commercial = 25
Construction Worker = 1EDM-L Exposure Duration for Migration to Groundwater Mass-Limit Equation S28 yr SSL 70 EF Exposure Frequency d/yr Residential = 350
Industrial/Commercial = 250
Construction Worker = 30F(x) Function dependent on Um/Ut unitless SSL 0.194 foc Organic Carbon Content of Soil g/g SSL or
Field Measurement
(See Appendix C, Table F)Surface Soil = 0.006
Subsurface soil = 0.002, or
Site-SpecificGWobj Groundwater Remediation Remediation Objective mg/L Appendix B, Table E,
35 IAC 620.Subpart F, or Equation S23 in
Appendix C, Table AChemical-Specific or Calculated H' Henry’s Law Constant unitless Appendix C, Table E Chemical-Specific i Hydraulic Gradient m/m Field Measurement
(See Appendix C, Table F)Site-Specific I Infiltration Rate m/yr SSL 0.3 IM-L Infiltration Rate for Migration to Groundwater Mass-Limit Equation S28 m/yr SSL 0.18 IFsoil-adj (residential)
Age Adjusted Soil Ingestion Factor for Carcinogens (mg-yr)/(kg-d) SSL 114 IRsoil Soil Ingestion Rate mg/d Residential = 200
Industrial/Commercial = 50
Construction Worker = 480IRW Daily Water Ingestion Rate L/d Residential = 2
Industrial/Commercial = 1K Aquifer Hydraulic Conductivity m/yr Field Measurement
(See Appendix C, Table F)Site-Specific Kd (Non-ionizing organics)
Soil-Water Partition Coefficient cm3/g or L/kg Equation S19 in
Appendix C, Table ACalculated Value Kd (Ionizing organics)
Soil-Water Partition Coefficient cm3/g or L/kg Equation S19 in Appendix C, Table A Chemical and pH-Specific (see Appendix C, Table I) Kd (Inorganics) Soil-Water Partition Coefficient cm3/g or L/kg Appendix C, Table J Chemical and pH-Specific Koc Organic Carbon Partition Coefficient cm3/g or L/kg Appendix C, Table E
or Appendix C, Table IChemical-Specific Ks Saturated Hydraulic Conductivity m/yr Appendix C, Table K
Appendix C, Illustration CSite-Specific L Source Length Parallel to Groundwater Flow m Field Measurement Site-Specific PEF Particulate Emission
Factorm3/kg SSL or Equation S15 in Appendix C, Table A Residential = 1.32 · 109 or Site-Specific
Industrial/Commercial = 1.24 · 109 or Site-SpecificPEF ¢ Particulate Emission Factor adjusted for Agitation (construction worker) m3/kg Equation S16 in Appendix C, Table A using PEF (industrial/commercial) 1.24 · 108 or Site-Specific Q/C
(used in VF equations)Inverse of the mean concentration at the center of a square source (g/m2-s)/(kg/m3) Appendix C, Table H Residential = 68.81
Industrial/Commercial = 85.81
Construction Worker = 85.81
Q/C
(used in PEF equations)Inverse of the mean concentration at the center of a square source (g/m2-s)/(kg/m3) SSL or Appendix C, Table H Residential = 90.80
Industrial/Commercial = 85.81
Construction Worker = 85.81RfC Inhalation Reference Concentration mg/m3 Illinois EPA: http://www.epa.state.il.us/land/taco/toxicity-values.xls Toxicological-Specific
(Note: for Construction Workers use subchronic reference concentrations)RfDo Oral Reference Dose mg/(kg-d) Illinois EPA: http://www.epa.state.il.us/land/taco/toxicity-values.xls Toxicological-Specific
(Note: for Construction Worker use subchronic reference doses)ROsoil Soil remediation objective mg/kg Equation S30 in Appendix C, Table A Calculated value ROsoil gas Soil gas remediation objective mg/m3 Equation S30 in Appendix C, Table A Calculated value S Solubility in Water mg/L Appendix C, Table E Chemical-Specific SFo Oral Slope Factor (mg/kg-d)-1 Illinois EPA: http://www.epa.state.il.us/land/taco/toxicity-values.xls Toxicological-Specific T Exposure Interval s Residential = 9.5 · 108
Industrial/Commercial = 7.9 · 108
Construction Worker = 3.6 · 106TM-L Exposure Interval for Mass-Limit Volatilization Factor Equation S26 yr SSL 30 THQ Target Hazard Quotient unitless SSL 1 TR Target Cancer Risk unitless Residential = 10-6 at the point of human exposure
Industrial/Commercial = 10-6 at the point of human exposure
Construction Worker = 10-6 at the point of human exposureUm Mean Annual Windspeed m/s SSL 4.69 URF Inhalation Unit Risk Factor (ug/m3)-1 Illinois EPA: http://www.epa.state.il.us/land/taco/toxicity-values.xls Toxicological-Specific Ut Equivalent Threshold Value of Windspeed at 7 m m/s SSL 11.32 V Fraction of Vegetative Cover unitless SSL or Field Measurement 0.5 or Site-Specific VF Volatilization Factor m3/kg Equation S8 in
Appendix C, Table ACalculated Value VF ¢ Volatilization Factor adjusted for Agitation m3/kg Equation S9 in
Appendix C, Table ACalculated Value VFM-L Mass-Limit Volatilization Factor m3/kg Equation S26 in
Appendix C, Table ACalculated Value VF ¢ M-L Mass-Limit Volatilization Factor adjusted for Agitation m3/kg Equation S27 in
Appendix C, Table ACalculated Value h Total Soil Porosity Lpore/Lsoil SSL or
Equation S24 in
Appendix C, Table A0.43, or
Gravel = 0.25
Sand = 0.32
Silt = 0.40
Clay = 0.36, or
Calculated Valueqa Air-Filled Soil Porosity Lair/Lsoil SSL or
Equation S21 in
Appendix C, Table ASurface Soil (top 1 meter) = 0.28
Subsurface Soil (below 1 meter) = 0.13, or
Gravel = 0.05
Sand = 0.14
Silt - 0.24
Clay = 0.19, or
Calculated Valueqw Water-Filled Soil Porosity Lwater/Lsoil SSL or
Equation S20 in
Appendix C, Table ASurface Soil (top 1 meter) = 0.15
Subsurface Soil (below 1 meter) = 0.30, or
Gravel = 0.20
Sand = 0.18
Silt = 0.16
Clay = 0.17, or
Calculated Valuerb Dry Soil Bulk Density kg/L or g/cm3 SSL or
Field Measurement
(See Appendix C, Table F)1.5, or Gravel = 2.0
Sand = 1.8
Silt = 1.6
Clay = 1.7, orSite-Specific
rs Soil Particle Density g/cm3 SSL or
Field Measurement
(See Appendix C, Table F)2.65, or Site-Specific
rw Water Density g/cm3 SSL 1 1/(2b+3) Exponential in Equation S20 unitless Appendix C, Table K
Appendix C, Illustration CSite-Specific (Source: Amended at 37 Ill. Reg. 7506, effective July 15, 2013)
Section 742.APPENDIX C Tier 2 Illustrations and Tables
Section 742.Table C RBCA Equations
Equations for the combined exposures routes of soil ingestion inhalation of vapors and particulates, and Remediation Objectives for Carcinogenic Contaminants (mg/kg) 
R1dermal contact with soil Remediation Objectives for Non-carcinogenic Contaminants (mg/kg) 
R2Volatilization Factor for Surficial Soils, VFss
(kg/m3)
Whichever is less between R3 and R4
R3
R4
Volatilization Factor for Surficial Soils Regarding Particulates, VFp
(kg/m3)
R5Effective Diffusion Coefficient in Soil Based on Vapor-Phase Concentration Dseff
(cm2/s)
R6Equations for the ambient vapor inhalation (outdoor) route fromsubsurface soils Remediation Objectives for Carcinogenic Contaminants (mg/kg) 
R7Remediation Objectives for Non-carcinogenic Contaminants (mg/kg)
R8
Carcinogenic Risk-Based Screening Level for Air, RBSLair
(ug/m3)
R9Noncarcinogenic Risk-Based Screening Level for Air, RBSLair
(ug/m3)
R10Volatilization Factor - Subsurface Soil to Ambient Air, VFsamb
(mg/m3)/(mg/kgsoil)
R11
Equations for the Soil Component of the Groundwater
Ingestion ExposureRemediation Objective
(mg/kg)
NOTE: This equation can only be used to model contaminant migration not in the water bearing unit.
R12Route Groundwater at the source, GWsource
(mg/L)
R13Leaching Factor,
LFsw
(mg/Lwater)/(mg/kgsoil)
R14Steady-State Attenuation Along the Centerline of a Dissolved Plume,
C(x)/Csource
NOTE:
1. This equation does not predict the contaminant flow within bedrock and may not accurately predict downgradient concentrations in the presence of a confining layer.
2. If the value of the First Order Degradation Constant (l) is not readily available, then set l = 0.
R15Longitudinal Dispersivity, a x
(cm)
R16
Transverse Dispersivity, a y
(cm)
R17
Vertical Dispersivity, a z
(cm)
R18Specific Discharge, U
(cm/d)
R19Soil-Water Sorption Coefficient, ks 
R20Volumetric Air Content in Vadose Zone Soils, q as
(cm3air/cm3soil)
R21Volumetric Water Content in Vadose Zone Soils, q ws
(cm3water/cm3soil)
R22Total Soil Porosity, q T
(cm3/cm3soil)
R23
Groundwater Darcy Velocity, Ugw
(cm/yr)
R24
Equations for the Groundwater Ingestion Exposure Route Remediation Objective for Carcinogenic Contaminants
(mg/L)
R25Dissolved Hydrocarbon Concentration along Centerline, C(x)
(mg/L water)
NOTE:1. This equation does not predict the contaminant flow within bedrock and may not accurately predict downgradient concentrations in the presence of a confining layer.
2. If the value of the First Order Degradation Constant ( l ) is not readily available, then set l = 0.
R26
(Source: Amended at 31 Ill. Reg. 4063, effective February 23, 2007)
Section 742.APPENDIX C Tier 2 Illustrations and Tables
Section 742.Table D RBCA Parameters
Symbol Parameter Units Source Parameter Value(s) ATc Averaging Time for Carcinogens yr RBCA 70 ATn Averaging Time for Noncarcinogens yr RBCA Residential = 30
Industrial/Commercial = 25
Construction Worker = 0.115BW Adult Body Weight kg RBCA 70 Csource The greatest potential concentration of the contaminant of concern in the groundwater at the source of the contamination, based on the concentrations of contaminants in groundwater due to the release and the projected concentration of the contaminant migrating from the soil to the groundwater. mg/L Field Measurement Site-Specific C(x) Concentration of Contaminant in Groundwater at Distance X from the source mg/L Equation R26 in
Appendix C, Table CCalculated Value
Symbol Parameter Units Source Parameter Value(s) C(x)/Csource Steady-State Attenuation Along the Centerline of a Dissolved Plume unitless Equation R15 in
Appendix C, Table CCalculated Value d Lower Depth of Surficial Soil Zone cm Field Measurement 100 or
Site-Specific (not to exceed 100)Dair Diffusion Coefficient in Air cm2/s Appendix C, Table E Chemical-Specific Dwater Diffusion Coefficient in Water cm2/s Appendix C, Table E Chemical-Specific Dseff Effective Diffusion Coefficient in Soil Based on Vapor-Phase Concentration cm2/s Equation R6 in
Appendix C, Table CCalculated Value ED Exposure Duration yr RBCA Residential = 30
Industrial/Commercial = 25
Construction Worker = 1EF Exposure Frequency d/yr RBCA Residential = 350
Industrial/Commercial = 250
Construction Worker = 30erf Error Function unitless Appendix C, Table G Mathematical Function
Symbol Parameter Units Source Parameter Value(s) foc Organic Carbon Content of Soil g/g RBCA or
Field Measurement
(See Appendix C, Table F)Surface Soil = 0.006
Subsurface Soil = 0.002 or
Site-SpecificGWcomp Groundwater Objective at the Compliance Point mg/L Appendix B, Table E,
35 IAC 620.Subpart F, or
Equation R25 in Appendix C, Table CSite-Specific GWsource Groundwater Concentration at the Source mg/L Equation R13 in
Appendix C, Table CCalculated Value H’ Henry’s Law Constant cm3water/cm3air Appendix C, Table E Chemical-Specific i Hydraulic Gradient cm/cm (unitless) Field Measurement
(See Appendix C, Table F)Site-Specific I Infiltration Rate cm/yr RBCA 30 IRair Daily Outdoor Inhalation Rate m3/d RBCA 20 IRsoil Soil Ingestion Rate mg/d RBCA Residential = 100
Industrial/Commercial = 50
Construction Worker = 480IRw Daily Water Ingestion Rate L/d RBCA Residential = 2
Industrial/Commercial = 1
Symbol Parameter Units Source Parameter Value(s) K Aquifer Hydraulic Conductivity cm/d for Equations R15, R19 and R26
cm/yr for Equation R24Field Measurement
(See Appendix C, Table F)Site-Specific Koc Organic Carbon Partition Coefficient cm3/g or L/kg Appendix C, Table E or
Appendix C, Table IChemical-Specific ks
(non-ionizing organics)Soil Water Sorption Coefficient cm3water/gsoil Equation R20 in
Appendix C,Table CCalculated Value ks
(ionizing organics)Soil Water Sorption Coefficient cm3water/gsoil Equation R20 in Appendix C, Table C Chemical and pH-Specific (See Appendix C, Table I) ks
(inorganics)Soil Water Sorption Coefficient cm3water/gsoil Appendix C, Table J Chemical and pH-Specific Ls Depth to Subsurface Soil Sources cm RBCA 100 LF sw Leaching Factor (mg/Lwater)/
(mg/kgsoil)Equation R14 in
Appendix C, Table CCalculated Value M Soil to Skin Adherence Factor mg/cm2 RBCA 0.5
Symbol Parameter Units Source Parameter Value(s) Pe Particulate Emission Rate g/cm2-s RBCA 6.9 · 10-14 RAFd
Dermal Relative Absorption Factor unitless RBCA 0.5 RAFd
(PNAs)Dermal Relative Absorption Factor unitless RBCA 0.05 RAFd
(inorganics)Dermal Relative Absorption Factor unitless RBCA 0 RAFo Oral Relative Absorption Factor unitless RBCA 1.0 RBSLair Carcinogenic
Risk-Based Screening Level for Airug/m3 Equation R9 in
Appendix C, Table CChemical-, Media-, and Exposure Route-Specific RBSLair Noncarcinogenic
Risk-Based Screening Level for Airug/m3 Equations R10 in
Appendix C, Table CChemical-, Media-, and Exposure Route-Specific RfDi Inhalation Reference Dose mg/kg-d IEPA (IRIS/HEASTa) Toxicological-Specific RfDo Oral Reference Dose mg/(kg-d) IEPA (IRIS/HEASTa) Toxicological-Specific
(Note: for Construction Worker use subchronic reference doses)SA Skin Surface Area cm2/d RBCA 3,160
Symbol Parameter Units Source Parameter Value(s) Sd Source Width Perpendicular to Groundwater Flow Direction in Vertical Plane cm Field Measurement For Migration to Groundwater Route:
Use 200 or Site-Specific
For Groundwater remediation objective:
Use Site-SpecificSw Source Width Perpendicular to Groundwater Flow Direction in Horizontal Plane cm Field Measurement Site-Specific SFi Inhalation Cancer Slope Factor (mg/kg-d)-1 IEPA (IRIS/HEASTa) Toxicological-Specific SFo Oral Slope Factor (mg/kg-d)-1 IEPA (IRIS/HEASTa) Toxicological-Specific THQ Target Hazard Quotient unitless RBCA 1 TR Target Cancer Risk unitless RBCA Residential = 10-6 at the point of human exposure
Industrial/Commercial = 10-6 at the point of human exposure
Construction Worker = 10-6 at the point of human exposureU Specific Discharge cm/d Equation R19 in
Appendix C, Table CCalculated Value
Symbol Parameter Units Source Parameter Value(s) Uair Average Wind Speed Above Ground Surface in Ambient Mixing Zone cm/s RBCA 225 Ugw Groundwater Darcy Velocity cm/yr Equation R24 in
Appendix C, Table CCalculated Value VF p Volatilization Factor for Surficial Soils Regarding Particulates kg/m3 Equation R5 in
Appendix C, Table CCalculated Value VFsamb Volatilization Factor (Subsurface Soils to Ambient Air) (mg/m3air)/(mg/kgsoil) or
kg/m3Equation R11 in
Appendix C, Table CCalculated Value VFss Volatilization Factor for Surficial Soils kg/m3 Use Equations R3 and R4 in Appendix C, Table C Calculated Value from Equation R3 or R4 (whichever is less) W Width of Source Area Parallel to Direction to Wind or Groundwater Movement cm Field Measurement Site-Specific
Symbol Parameter Units Source Parameter Value(s) w Average Soil Moisture Content gwater/gsoil RBCA or
Field Measurement
(See Appendix C, Table F)0.1, or
Surface Soil (top 1 meter) = 0.1
Subsurface Soil (below 1 meter) = 0.2, or
Site-SpecificX Distance along the Centerline of the Groundwater Plume Emanating from a Source. The x direction is the direction of groundwater flow cm Field Measurement Site-Specific ax Longitudinal Dispersitivity cm Equation R16 in
Appendix C, Table CCalculated Value ay Transverse Dispersitivity cm Equation R17 in
Appendix C, Table CCalculated Value az Vertical Dispersitivity cm Equation R18 in
Appendix C, Table CCalculated Value dair Ambient Air Mixing Zone Height cm RBCA 200
Symbol Parameter Units Source Parameter Value(s) dgw Groundwater Mixing Zone Thickness cm RBCA 200 qas Volumetric Air Content in Vadose Zone Soils cm3air/cm3soil RBCA or
Equation R21 in
Appendix C, Table CSurface Soil (top 1 meter) = 0.28
Subsurface Soil (below 1 meter)= 0.13,
Or
Gravel = 0.05
Sand = 0.14
Silt = 0.16
Clay = 0.17, or
Calculated Valueqws Volumetric Water Content in Vadose Zone Soils cm3water/cm3soil RBCA or
Equation R22 in
Appendix C, Table CSurface Soil (top 1 meter) = 0.15
Subsurface Soil (below 1 meter) =
0.30,
or
Gravel = 0.20
Sand = 0.18
Silt = 0.16
Clay = 0.17, or
Calculated Value
Symbol Parameter Units Source Parameter Value(s) qT Total Soil Porosity cm3/cm3soil RBCA or
Equation R23 in
Appendix C, Table C0.43, or
Gravel = 0.25
Sand = 0.32
Silt = 0.40
Clay = 0.36, or
Calculated Valuel First Order Degradation Constant d-1 Appendix C, Table E Chemical-Specific p pi 3.1416
rb Soil Bulk Density g/cm3 RBCA or
Field Measurement
(See Appendix C, Table F)1.5, or
Gravel = 2.0
Sand = 1.8
Silt = 1.6
Clay = 1.7, or
Site-Specificrw Water Density g/cm3 RBCA 1 t Averaging Time for Vapor Flux s RBCA 9.46 · 108
a HEAST = Health Effects Assessment Summary Tables. USEPA, Office of Solid Waste and Emergency Response. EPA/540/R95/036. Updated Quarterly.
(Source: Amended at 31 Ill. Reg. 4063, effective February 23, 2007)
Section 742.APPENDIX C: Tier 2 Illustrations and Tables
Section 742.Table E: Default Physical and Chemical Parameterse
CAS No.
Chemical
Solubility in Water (S)
(mg/L)
Diffusivity in Air (Di)
(cm2/s)
Diffusivity in Water (Dw)
(cm2/s)Dimensionless
Henry’s Law Constant (H')
(25oC)Dimensionless
Henry’s Law Constant (H') (13oC)
For the indoor inhalation exposure routeOrganic Carbon Partition Coefficient (Koc)
(L/kg)First
Order
Degradation Constant
( l )
(d-1)Vapor Pressure (mm/Hg)
Neutral Organics 83-32-9 Acenaphthene 3.60E+00 4.76E-02 7.69E-06 6.60E-03 -------b 6.30E+03 3.40E-03 2.50E-03 67-64-1 Acetone 1.00E+06 1.24E-01 1.14E-05 1.60E-03 9.73E-04 7.80E-01 4.95E-02 2.30E+02 15972-60-8 Alachlor 2.40E+02 2.13E-02 5.28E-06 3.40E-06 -------b 3.20E+03 No Data 2.20E-05 116-06-3 Aldicarb 6.03E+03 3.18E-02 7.24E-06 5.90E-08 -------b 1.29E+01 1.09E-03 3.47E-05 309-00-2 Aldrin 1.70E-02 1.96E-02 4.86E-06 7.00E-03 -------b 2.50E+05 5.90E-04 6.00E-06 120-12-7 Anthracene 4.30E-02 3.85E-02 7.74E-06 2.70E-03 -------b 2.50E+04 7.50E-04 2.70E-06 1912-24-9 Atrazine 7.00E+01 2.59E-02 6.67E-06 9.68E-08 -------b 3.63E+02 No Data 2.70E-07 71-43-2 Benzene 1.80E+03 8.80E-02 1.02E-05 2.30E-01 1.34E-01 5.00E+01 9.00E-04 9.50E+01
56-55-3 Benzo(a)
anthracene9.40E-03 5.10E-02 9.00E-06 1.39E-04 -------b 4.00E+05 5.10E-04 1.10E-07 205-99-2 Benzo(b)
fluoranthene1.50E-03 2.23E-02 5.56E-06 4.55E-03 -------b 1.05E+06 5.70E-04 5.00E-07 207-08-9 Benzo(k)
fluoranthene8.00E-04 2.23E-02 5.56E-06 3.40E-05 -------b 1.00E+06 1.60E-04 2.00E-09 65-85-0 Benzoic Acid 3.40E+03 7.02E-02 7.97E-06 1.56E-06 -------b 1.21E+00d No Data 7.00E-04 50-32-8 Benzo(a)pyrene 1.60E-03 4.30E-02 9.49E-06 4.50E-05 -------b 7.90E+05 6.50E-04 5.50E-09 111-44-4 Bis(2-chloroethyl)ether 1.72E+04 4.13E-02 7.53E-06 7.40E-04 2.94E-04 1.26E+01 1.90E-03 1.55E+00 117-81-7 Bis(2-ethylhexyl)
phthalate3.40E-01 3.51E-02 3.66E-06 4.10E-06 -------b 1.00E+05 1.80E-03 6.80E-08 75-27-4 Bromodichloro-methane 6.70E+03 5.61E-02 1.06E-05 6.60E-02 3.71E-02 5.00E+01 No Data 5.00E+01 75-25-2 Bromoform 3.10E+03 1.49E-02 1.03E-05 2.19E-02 1.06E-02 9.12E+01 1.90E-03 5.51E+00 71-36-3 Butanol 7.40E+04 8.00E-02 9.30E-06 3.61E-04 1.55E-04 6.00E+00 1.28E-02 7.00E+00 78-93-3 2-Butanone (MEK) 2.20E+05 8.08E-02 9.8E-06 2.30E-03 1.32E-03 2.00E+00 4.95E-02 9.50E+01 85-68-7 Butyl Benzyl Phthalate 2.70E+00 1.99E-02 4.89E-06 5.30E-05 -------b 6.30E+04 3.85E-03 8.30E-06 86-74-8 Carbazole 1.20E+00 4.17E-02 7.45E-06 3.60E-06 -------b 4.00E+03 No Data 7.00E-04
1563-66-2 Carbofuran 3.20E+02 2.37E-02 5.95E-06 1.27E-07 -------b 1.91E+02 No Data 4.85E-06 75-15-0 Carbon Disulfide 1.20E+03 1.04E-01 1.00E-05 1.23E+00 8.06E-01 6.30E+01 No Data 3.60E+02 56-23-5 Carbon Tetrachloride 7.90E+02 7.80E-02 8.80E-06 1.23E+00 7.48E-01 2.00E+02 1.90E-03 1.20E+02 57-74-9 Chlordane 5.60E-02 1.79E-02 4.37E-06 2.00E-03 -------b 2.50E+05 2.50E-04 9.80E-06 106-47-8 p-Chloroaniline 5.30E+03 6.99E-02 1.01E-05 4.76E-05 -------b 6.31E+01 No Data 1.23E-02 108-90-7 Chlorobenzene 4.70E+02 7.30E-02 8.70E-06 1.50E-01 7.93E-02 2.00E+02 2.30E-03 1.20E+01 124-48-1 Chlorodibromo-methane 2.60E+03 3.66E-02 1.05E-05 3.20E-02 2.07E-02 6.92E+01 3.85E-03 4.90E+00 67-66-3 Chloroform 7.90E+03 1.04E-01 1.00E-05 1.50E-01 9.18E-02 5.00E+01 3.90E-04 2.00E+02 95-57-8 2-Chlorophenol 2.20E+04 6.61E-02 9.46E-06 1.60E-02 7.28E-03 5.93E+01d No Data 2.34E+00 218-01-9 Chrysene 6.30E-03 2.44E-02 6.21E-06 3.90E-03 -------b 4.00E+05 3.50E-04 6.20E-09 94-75-7 2,4-D 6.77E+02 5.88E-02 6.49E-06 4.18E-07 -------b 5.75E+02 3.85E-03 6.00E-07 72-54-8 4,4'-DDD 9.00E-02 2.27E-02 5.79E-06 1.60E-04 -------b 7.90E+05 6.20E-05 6.70E-07
72-55-9 4,4'-DDE 1.20E-01 2.38E-02 5.87E-06 8.60E-04 -------b 4.00E+05 6.20E-05 6.00E-06 50-29-3 4,4'-DDT 2.50E-02 1.99E-02 4.95E-06 3.30E-04 -------b 2.00E+06 6.20E-05 1.60E-07 75-99-0 Dalapon 9.00E+05 6.08E-02 9.45E-06 2.64E-06 NA 4.80E+00 5.78E-03 1.90E-01 53-70-3 Dibenzo(a,h)
anthracene2.50E-03 2.11E-02 5.24E-06 6.10E-07 -------b 2.50E+06 3.70E-04 1.00E-10 96-12-8 1,2-Dibromo-3-chloropropane 1.20E+03 2.68E-02 7.02E-06 6.20E-03c NA 7.90E+01 1.93E-03 5.80E-01 106-93-4 1,2-Dibromoethane 4.00E+03 4.37E-02 8.44E-06 3.00E-02 1.54E-02 5.00E+01 5.78E-03 1.30E+01 84-74-2 Di-n-butyl Phthalate 1.10E+01 4.38E-02 7.86E-06 7.40E-05 -------a 4.00E+04 3.01E-02 7.30E-05 1918-00-9 Dicamba 4.50E+03 2.37E-02 5.95E-06 2.18E-09 -------a 2.95E+00 No Data 3.38E-05 95-50-1 1,2-Dichlorobenzene 1.56E+02 6.90E-02 7.90E-06 7.79E-02 3.56E-02 5.75E+02 1.90E-03 1.36E+00 106-46-7 1,4-Dichlorobenzene 7.90E+01 6.90E-02 7.90E-06 9.80E-02 4.69E-02 7.90E+02 1.90E-03 1.00E+00 91-94-1 3,3-Dichloro-benzidine 3.10E+00 2.59E-02 6.74E-06 1.60E-07 -------a 2.82E+03 1.90E-03 3.71E-08 75-71-8 Dichlorodifluoro-methane 2.80E+02 7.60E-02 1.08E-05 1.41E+01 8.14E+00 6.17E+01 1.92E-03 4.85E+03
75-34-3 1,1-Dichloroethane 5.10E+03 7.42E-02 1.05E-05 2.30E-01 1.42E-01 3.20E+01 1.90E-03 2.30E+02 107-06-2 1,2-Dichloroethane 8.50E+03 1.04E-02 9.90E-06 4.00E-02 2.29E-02 2.00E+01 1.90E-03 7.90E+01 75-35-4 1,1-Dichloroethylene 2.30E+03 9.00E-02 1.04E-05 1.10E+00 7.10E-01 5.00E+01 5.30E-03 6.00E+02 156-59-2 cis-1,2-Dichloroethylene 3.50E+03 8.86E-02 1.13E-05 1.70E-01 1.00E-01 4.00E+01 2.40E-04 2.00E+02 156-60-5 trans-1,2-Dichloroethylene 6.30E+03 7.03E-02 1.19E-05 3.90E-01 2.43E-01 5.00E+01 2.40E-04 3.30E+02 120-83-2 2,4-Dichlorophenol 4.50E+03 4.89E-02 8.77E-06 1.30E-04 -------a 7.32E+02d 2.70E-04 6.70E-02 78-87-5 1,2-Dichloropropane 2.80E+03 7.82E-02 8.73E-06 1.10E-01 6.52E-02 5.00E+01 2.70E-04 5.20E+01 542-75-6 1,3-Dichloro-propylene
(cis + trans)2.80E+03 6.26E-02 1.00E-05 7.40E-01 3.98E-01 2.00E+01 6.10E-02 3.40E+01 60-57-1 Dieldrin 2.00E-01 1.92E-02 4.74E-06 6.2E-04 -------a 2.50E+04 3.20E-04 5.9E-06 84-66-2 Diethyl Phthalate 1.10E+03 2.49E-02 6.35E-06 1.80E-05 -------a 3.20E+02 6.19E-03 1.60E-03 105-67-9 2,4-Dimethylphenol 7.90E+03 6.43E-02 8.69E-06 8.20E-05 -------a 2.00E+02 4.95E-02 9.80E-02 75-71-8 1,3-Dinitrobenzene 8.60E+02 4.55E-02 8.46E-06 2.30E-07 -------a 3.20E+01 1.92E-03 9.00E-04 51-28-5 2,4-Dinitrophenol 2.79E+03 2.73E-02 9.06E-06 1.82E-05 -------a 3.24E+01 1.32E-03 5.10E-03
121-14-2 2,4-Dinitrotoluene 2.70E+02 2.03E-01 7.06E-06 3.80E-06 -------a 8.90E+01 1.92E-03 1.47E-04 606-20-2 2,6-Dinitrotoluene 1.82E+02 3.70E-02 7.76E-06 3.06E-05 -------a 4.90E+01 1.92E-03 5.67E-04 88-85-7 Dinoseb 5.20E+01 2.45E-02 6.25E-06 1.87E-05 -------a 9.17E+01d 2.82E-03 7.50E-05 117-84-0 Di-n-octyl Phthalate 2.00E-02 1.73E-02 4.17E-06 2.74E-03 -------a 1.30E+05 1.90E-03 2.60E-06 123-91-1 p-Dioxane 1.00E+06 2.29E-01 1.02E-05 1.97E-04 1.07E-04 7.20E-01 1.92E-03 3.81E+01 115-29-7 Endosulfan 5.10E-01 1.85E-02 4.55E-06 4.51E-04 -------a 5.00E+03 7.63E-02 1.00E-05 145-73-3 Endothall 2.10E+04 2.91E-02 8.07E-06 1.58E-14 -------a 7.59E+01 No Data 1.57E-10 72-20-8 Endrin 2.50E-01 1.92E-02 4.74E-6 3.08E-04 -------a 3.20E+04 3.20E-04 3.00E-06 100-41-4 Ethylbenzene 1.70E+02 7.50E-02 7.80E-06 3.24E-01 1.64E-01 3.20E+02 3.00E-03 9.60E+00 206-44-0 Fluoranthene 2.06E-01 2.51E-02 6.35E-06 6.60E-04 -------a 7.40E+04 1.90E-04 1.23E-08 86-73-7 Fluorene 2.00E+00 4.40E-02 7.88E-06 2.62E-03 -------a 1.30E+04 6.91E-04 6.30E-04 76-44-8 Heptachlor 1.80E-01 2.23E-02 5.69E-06 6.07E-02 1.73E-02 3.00E+03 1.30E-01 4.00E-04 1024-57-3 Heptachlor epoxide 2.00E-01 2.19E-02 5.57E-06 3.90E-04 -------a 2.00E+05 6.30E-04 1.90E-05
118-74-1 Hexachloro-benzene 6.20E-03 5.42E-02 5.91E-06 5.33E-02 1.35E-02 2.00E+04 1.70E-04 1.80E-05 319-84-6 Alpha-HCH (alpha-BHC) 2.00E+00 2.04E-02 5.04E-06 4.51E-04 -------a 5.00E+03 2.50E-03 4.50E-05 58-89-9 Gamma-HCH (Lindane) 7.30E+00 2.75E-02 7.34E-06 5.74E-04 -------a 3.00E+03 2.90E-03 4.10E-04 2691-41-0 High Melting Explosive, Octogen (HMX) 5.00E+00 2.69E-02 7.15E-06 8.67E-10 3.55E-08 1.40E+00 No Data 3.30E-14 77-47-4 Hexachlorocyclo-
Pentadiene1.80E+00 2.79E-02 7.21E-06 1.11E+00 4.22E-01 1.20E+04 1.20E-02 5.96E-02 67-72-1 Hexachloroethane 5.00E+01 2.50E-03 6.80E-06 1.59E-01 7.26E-02 1.50E+03 1.92E-03 2.10E-01 193-39-5 Indeno(1,2,3-c,d)pyrene 2.20E-05 2.25E-02 5.66E-06 6.56E-05 -------a 3.10E+06 4.70E-04 1.00E-10 78-59-1 Isophorone 1.20E+04 6.23E-02 6.76E-06 2.72E-04 1.12E-04 2.50E+01 1.24E-02 4.38E-01 98-82-8 Isopropylbenzene (Cumene) 6.10E+01 6.50E-02 7.10E-06 4.92E+01 2.10E+01 1.02E+03 4.33E-02 4.50E+00 93-65-2 Mecoprop (MCPP) 8.95E+02 2.40E-02 6.05E-06 7.70E-09 -------a 1.84E+01d 3.85E-03 2.44E-05 7439-97-6 Mercury 6.00E-02 7.14E-02 3.01E-05 4.51E-01 1.59E-01 8.70E+03 No Data 2.00E-03 72-43-5 Methoxychlor 4.50E-02 1.84E-02 4.46E-06 6.56E-04 -------a 5.00E+04 1.90E-03 6.00E-07 74-83-9 Methyl Bromide 1.50E+04 7.28E-02 1.21E-05 2.56E-01 1.79E-01 1.00E+01 1.82E-02 1.62E+03 1634-04-4 Methyl tertiary-butyl ether 5.10E+04 8.59E-02 1.10E-05 2.42E-02 1.50E-02 1.00E+01 No Data 2.50E+02 75-09-2 Methylene Chloride 1.30E+04 1.01E-01 1.17E-05 9.02E-02 5.70E-02 1.30E+01 1.20E-02 4.30E+02
93-65-2 2-Methyl-naphthalene 2.50E+01 5.22E-02 7.75E-06 2.10E-02 6.95E-03 1.60E+03 No Data 6.80E-02 95-48-7 2-Methylphenol (o-cresol) 2.60E+04 7.40E-02 8.30E-06 4.92E-05 2.00E-05 4.20E+01 4.95E-02 2.99E-01 91-20-3 Naphthalene 3.10E+01 5.90E-02 7.50E-06 1.97E-02 8.29E-03 5.00E+02 2.70E-03 8.50E-02 98-95-3 Nitrobenzene 2.09E+03 7.60E-02 8.60E-06 9.84E-04 3.99E-04 4.00E+01 1.76E-03 2.40E-01 86-30-6 N-Nitrosodiphenyl-amine 3.50E+01 2.83E-02 7.19E-06 2.10E-04 -------a 1.00E+03 1.00E-02 6.70E-04 621-64-7 N-Nitrosodi-n-propylamine 9.89E+03 5.87E-02 8.17E-06 9.20E-05 5.48E-05 1.45E+01 1.90E-03 1.30E-01 87-86-5 Pentachloro-phenol 2.00E+03 5.60E-02 6.10E-06 9.84E-07 -------a 2.77E+03d 4.50E-04 3.20E-05 108-95-2 Phenol 8.30E+04 8.20E-02 9.10E-06 1.64E-05 6.67E-06 2.00E+01 9.90E-02 2.80E-01 1918-02-1 Picloram 4.30E+02 2.26E-02 5.64E-06 2.19E-12 -------a 2.00E+00 No Data 7.21E-11 1336-36-3 Polychlorinated biphenyls (PCBs) -------a -------a -------a -------a -------a -------a -------a -------a 129-00-0 Pyrene 1.40E+00 2.77E-02 7.24E-06 4.51E-04 -------a 6.31E+04 1.80E-04 4.60E-06 121-82-4 Royal Demolition Explosive, Cyclonite (RDX) 5.97E+01 3.11E-02 8.49E-06 2.01E-11 -------a 7.20E+00 No Data 4.10E-09 122-34-9 Simazine 6.20E+00 2.48E-02 6.28E-06 3.80E-08 -------a 1.32E+02 No Data 2.21E-08 100-42-5 Styrene 3.10E+02 7.10E-02 8.00E-06 1.11E-01 5.48E-03 3.16E+02 3.30E-03 6.10E+00 93-72-1 2,4,5-TP (Silvex) 7.10E+01 2.30E-02 5.83E-06 3.71E-07 -------a 5.50E+03 No Data 9.97E-06
127-18-4 Tetrachloro-ethylene 2.00E+02 7.20E-02 8.20E-06 7.38E-01 4.00E-01 6.31E+02 9.60E-04 1.90E+01 108-88-3 Toluene 5.30E+02 8.70E-02 8.60E-06 2.71E-01 1.49E-01 1.58E+02 1.10E-02 2.80E+01 8001-35-2 Toxaphene 7.40E-01 2.16E-02 5.51E-06 2.46E-04 -------a 5.01E+04 No Data 9.80E-07 120-82-1 1,2,4-Trichlorobenzene 3.50E+01 3.00E-02 8.23E-06 5.74E-02 2.38E-02 1.58E+03 1.90E-03 4.30E-01 71-55-6 1,1,1-Trichloroethane 1.30E+03 7.80E-02 8.80E-06 6.97E-01 4.21E-01 1.26E+02 1.30E-03 1.20E+02 79-00-5 1,1,2-Trichloroethane 4.40E+03 7.80E-02 8.80E-06 3.73E-02 1.98E-02 5.01E+01 9.50E-04 2.30E+01 79-01-6 Trichloroethylene 1.50E+03 7.90E-02 9.10E-06 4.10E-01 2.41E-01 1.00E+02 4.20E-04 7.30E+01 75-69-4 Trichlorofluoro-methane 1.10E+03 8.70E-02 9.70E-06 3.98E+00 2.69E+00 1.30E+02 9.63E-04 8.00E+02 95-95-4 2,4,5-Trichlorophenol 1.20E+03 2.91E-02 7.03E-06 1.78E-04 -------a 2.68E+03d 3.80E-04 2.40E-02 88-06-2 2,4,6-Trichlorophenol 8.00E+02 2.61E-02 6.36E-06 3.53E-04 -------a 8.78E+02 d 3.80E-04 2.00E-02 108-05-4 Vinyl Acetate 2.00E+04 8.50E-02 9.20E-06 2.09E-02 1.18E-02 4.57E+00 No Data 9.00E+01 99-35-4 1,3,5-Trinitrobenzene 2.80E+02 2.41E-02 6.08E-06 3.30E-10 -------a 1.60E+01 No Data 6.40E-06 118-96-7 2,4,6-Trinitrotoluene (TNT) 1.24E+02 2.94E-02 7.90E-06 4.87E-09 -------a 3.72E+01 1.92E-03 2.02E-06 57-01-4 Vinyl Chloride 8.80E+03 1.06E-01 1.23E-06 1.11E+00 8.14E-01 1.58E+01 2.40E-04 3.00E+03 108-38-3 m-Xylene 1.60E+02 7.00E-02 7.80E-06 2.99E-01 1.52E-01 3.98E+02 1.90E-03 8.50E+00
95-47-6 o-Xylene 1.80E+02 8.70E-02 1.00E-05 2.13E-01 1.07E-01 3.16E+02 1.90E-03 6.60E+00 106-42-3 p-Xylene 1.60E+02 7.69E-02 8.44E-06 3.16E-01 1.59E-01 3.16E+02 1.90E-03 8.90E+00 1330-20-7 Xylenes (total) 1.10E+02 7.35E-02 9.23E-06 2.71E-01 NA 3.98E+02 1.90E-03 8.00E+00 Chemical Abstracts Service (CAS) registry number. This number in the format xxx-xx-x, is unique for each chemical and allows efficient searching on computerized data bases.
a Soil remediation objectives are determined pursuant to 40 CFR 761, as incorporated by reference at Section 742.210(b) (the USEPA “PCB Spill Cleanup Policy”), for most sites; persons remediating sites should consult with BOL if calculation of Tier 2 or 3 remediation objectives is desired. PCBs are a mixture of different congeners. The appropriate values to use for the physical/chemical parameters depend on congeners present at the site.
b Dimensionless Henry’s Law Constant at 13°C is not calculated because the chemical is not volatile and does not require evaluation under the indoor inhalation exposure route.
c Dimensionless Henry’s Law Constant = 20°C
d These chemicals are ionizing and its Koc value will change with pH. The Koc values listed in this table is the effective Koc at pH of 6.8. If the site-specific pH is values other than 6.8, the Koc value listed in Section 742, Appendix C, Table I should be used.
e The values in this table were taken from the following sources (in order of preference): SCDMS online database (http://www.epa.gov/superfund/sites/npl/hrsres/tools/scdm.htm ); CHEMFATE online database (http://www.srcinc.com/what-we-do/databaseforms.aspx?id=381 ); PhysProp online database (http://www.srcinc.com/what-we-do/databaseforms.aspx?id-386 ); Water9 (http://www.epa.gov/ttn/chief/software/water/ ) for diffusivity values; and Handbook of Environmental Degradation Rates by P.H. Howard (1991) for first order degradation constant values.
(Source: Amended at 37 Ill. Reg. 7506, effective July 15, 2013)
Section 742.APPENDIX C: Tier 2 Illustrations and Tables
Section 742.Table F: Methods for Determining Physical Soil Parameters
Methods for Determining Physical Soil Parameters
Parameter Sampling Locationa Method
rb (soil bulk density)
SurfaceASTM - D 1556-90
Sand Cone MethodbASTM - D 2167-94
Rubber Balloon MethodbASTM - D 2922-91
Nuclear MethodbSubsurface ASTM - D 2937-94
Drive Cylinder Methodbrs (soil particle density) Surface or Subsurface ASTM - D 854-92
Specific Gravity of Soilb
w (moisture content)
Surface or SubsurfaceASTM - D 4959-89
(Reapproved 1994)
StandardbASTM - D 4643-93
Microwave OvenbASTM - D2216-92
Laboratory Determinationb
ASTM - D3017-88
(Reapproved 1993)
Nuclear MethodbEquivalent USEPA Method (e.g., sample preparation procedures described in methods 3541 or 3550)
foc (fraction organic carbon content)
Surface or SubsurfaceASTM - D 2974-00
Moisture, Ash, and Organic Matter appropriately adjusted to estimate the fraction of organic carbon as stated in Nelson and Sommers (1982)bh or q T (total soil porosity) Surface or Subsurface (calculated) Equation S24 in Appendix C, Table A for SSL Model, or Equation R23 in Appendix C, Table C for RBCA Model, or
Equation J&E 16 in Appendix C, Table L for J&E Modelqa or q as (air-filled soil porosity) Surface or Subsurface (calculated) Equation S21 in Appendix C, Table A for SSL Model, or Equation R21 in Appendix C, Table C for RBCA Model, or Equation J&E 18 in Appendix C, Table L for J&E Model qw or q ws (water-filled soil porosity) Surface or Subsurface (calculated) Equation S20 in Appendix C, Table A for SSL Model, or Equation R22 in Appendix C, Table C for RBCA Model, or Equation J&E 17 in Appendix C, Table L for J&E Model
ASTM - D 5084-90
Flexible Wall PermeameterbK (hydraulic conductivity) Surface or Subsurface Pump Test Slug Test i (hydraulic gradient) Surface or Subsurface Field Measurement
a This is the location where the sample is collected
b As incorporated by reference in Section 742.120.
(Source: Amended at 37 Ill. Reg. 7506, effective July 15, 2013)
Section 742.APPENDIX C: Tier 2 Tables and Illustrations
Section 742.Table G: Error Function (erf)
erfβ=2π0βe-ε2dε
1.3 0.934008 0 0 1.4 0.952285 0.05 0.056372 1.5 0.966105 0.1 0.112463 1.6 0.976348 0.15 0.167996 1.7 0.983790 0.2 0.222703 1.8 0.989091 0.25 0.276326 1.9 0.992790 0.3 0.328627 2.0 0.995322 0.35 0.379382 2.1 0.997021 0.4 0.428392 2.2 0.998137 0.45 0.475482 2.3 0.998857 0.5 0.520500 2.4 0.999311 0.55 0.563323 2.5 0.999593 0.6 0.603856 2.6 0.999764 0.65 0.642029 2.7 0.999866 0.7 0.677801 2.8 0.999925 0.75 0.711156 2.9 0.999959 0.8 0.742101 3.0 0.999978 0.85 0.770668 0.9 0.796908 0.95 0.820891 1.0 0.842701 1.1 0.880205 1.2 0.910314
Section 742.APPENDIX C Tier 2 Illustrations and Tables
Section 742.Table H Q/C Values by Source Area
(Acres)
(g/m2-s per kg/m3)(Source: Amended at 31 Ill. Reg. 4063, effective February 23, 2007)
Section 742.APPENDIX C TABLE I: Koc Values for Ionizing Organics as a Function of pH (cm3/g or L/kg or cm3water/gsoil)
pH
Benzoic Acid
2-Chloro- phenol2,4-
Dichloro-phenol
Pentachloro-phenol2,4,5-Trichloro-phenol 2,4,6-Trichloro-phenol
Dinoseb
2,4,5-TP
(Silvex)4.5 1.07E+01 3.98E+02 1.59E+02 1.34E+04 2.37E+03 1.06E+03 3.00E+04 1.28E+04 4.6 9.16E+00 3.98E+02 1.59E+02 1.24E+04 2.37E+03 1.05E+03 2.71E+04 1.13E+04 4.7 7.79E+00 3.98E+02 1.59E+02 1.13E+04 2.37E+03 1.05E+03 2.41E+04 1.01E+04 4.8 6.58E+00 3.98E+02 1.59E+02 1.02E+04 2.37E+03 1.05E+03 2.12E+04 9.16E+03 4.9 5.54E+00 3.98E+02 1.59E+02 9.05E+03 2.37E+03 1.04E+03 1.85E+04 8.40E+03 5.0 4.62E+00 3.98E+02 1.59E+02 7.96E+03 2.36E+03 1.03E+03 1.59E+04 7.76E+03 5.1 3.86E+00 3.98E+02 1.59E+02 6.93E+03 2.36E+03 1.02E+03 1.36E+04 7.30E+03 5.2 3.23E+00 3.98E+02 1.59E+02 5.97E+03 2.35E+03 1.01E+03 1.15E+04 6.91E+03 5.3 2.70E+00 3.98E+02 1.59E+02 5.10E+03 2.34E+03 9.99E+02 9.66E+03 6.60E+03 5.4 2.27E+00 3.98E+02 1.58E+02 4.32E+03 2.33E+03 9.82E+02 8.10E+03 6.36E+03 5.5 1.92E+00 3.97E+02 1.58E+02 3.65E+03 2.32E+03 9.62E+02 6.77E+03 6.16E+03 5.6 1.63E+00 3.97E+02 1.58E+02 3.07E+03 2.31E+03 9.38E+02 5.65E+03 6.00E+03 5.7 1.40E+00 3.97E+02 1.58E+02 2.58E+03 2.29E+03 9.10E+02 4.73E+03 5.88E+03 5.8 1.22E+00 3.97E+02 1.58E+02 2.18E+03 2.27E+03 8.77E+02 3.97E+03 5.78E+03 5.9 1.07E+00 3.97E+02 1.57E+02 1.84E+03 2.24E+03 8.39E+02 3.35E+03 5.70E+03 6.0 9.50E-01 3.96E+02 1.57E+02 1.56E+03 2.21E+03 7.96E+02 2.84E+03 5.64E+03 6.1 8.54E-01 3.96E+02 1.57E+02 1.33E+03 2.17E+03 7.48E+02 2.43E+03 5.59E+03 6.2 7.78E-01 3.96E+02 1.56E+02 1.15E+03 2.12E+03 6.97E+02 2.10E+03 5.55E+03 6.3 7.19E-01 3.95E+02 1.55E+02 9.98E+02 2.06E+03 6.44E+02 1.83E+03 5.52E+03 6.4 6.69E-01 3.94E+02 1.54E+02 8.77E+02 1.99E+03 5.89E+02 1.62E+03 5.50E+03 6.5 6.31E-01 3.93E+02 1.53E+02 7.81E+02 1.91E+03 5.33E+02 1.45E+03 5.48E+03 6.6 6.00E-01 3.92E+02 1.52E+02 7.03E+02 1.82E+03 4.80E+02 1.32E+03 5.46E+03 6.7 5.74E-01 3.90E+02 1.50E+02 6.40E+02 1.71E+03 4.29E+02 1.21E+03 5.45E+03 6.8 5.55E-01 3.88E+02 1.47E+02 5.92E+02 1.60E+03 3.81E+02 1.12E+03 5.44E+03 6.9 5.39E-01 3.86E+02 1.45E+02 5.52E+02 1.47E+03 3.38E+02 1.05E+03 5.43E+03 7.0 5.28E-01 3.83E+02 1.41E+02 5.21E+02 1.34E+03 3.00E+02 9.96E+02 5.43E+03 7.1 5.18E-01 3.79E+02 1.38E+02 4.96E+02 1.21E+03 2.67E+02 9.52E+02 5.42E+03 7.2 5.10E-01 3.75E+02 1.33E+02 4.76E+02 1.07E+03 2.39E+02 9.18E+02 5.42E+03 7.3 5.04E-01 3.69E+02 1.28E+02 4.61E+02 9.43E+02 2.15E+02 8.90E+02 5.42E+03 7.4 4.99E-01 3.62E+02 1.21E+02 4.47E+02 8.19E+02 1.95E+02 8.68E+02 5.41E+03 7.5 4.95E-01 3.54E+02 1.14E+02 4.37E+02 7.03E+02 1.78E+02 8.50E+02 5.41E+03 7.6 4.92E-01 3.44E+02 1.07E+02 4.29E+02 5.99E+02 1.64E+02 8.36E+02 5.41E+03 7.7 4.86E-01 3.33E+02 9.84E+01 4.23E+02 5.07E+02 1.53E+02 8.25E+02 5.41E+03 7.8 4.86E-01 3.19E+02 8.97E+01 4.18E+02 4.26E+02 1.44E+02 8.17E+02 5.41E+03 7.9 4.85E-01 3.04E+02 8.07E+01 4.14E+02 3.57E+02 1.37E+02 8.10E+02 5.41E+03 8.0 4.85E-01 2.86E+02 7.17E+01 4.10E+02 2.98E+02 1.31E+02 8.04E+02 5.41E+03 8.1 4.84E-01 2.67E+02 6.30E+01 4.09E+02 2.49E+02 1.26E+02 8.00E+02 5.40E+03 8.2 4.84E-01 2.46E+02 5.47E+01 4.07E+02 2.08E+02 1.22E+02 7.97E+02 5.40E+03 8.3 4.83E-01 2.24E+02 4.40E+01 4.05E+02 1.75E+02 1.19E+02 7.93E+02 5.40E+03 8.4 4.83E-01 2.02E+02 4.00E+01 4.04E+02 1.48E+02 1.17E+02 7.91E+02 5.40E+03 8.5 4.82E-01 1.80E+02 3.38E+01 4.03E+02 1.25E+02 1.15E+02 7.89E+02 5.40E+03 8.6 4.82E-01 1.58E+02 2.84E+01 4.02E+02 1.08E+02 1.13E+02 7.88E+02 5.40E+03 8.7 4.82E-01 1.37E+02 2.38E+01 4.02E+02 9.31E+02 1.12E+02 7.87E+02 5.40E+03 8.8 4.81E-01 1.18E+02 1.99E+01 4.01E+02 8.16E+02 1.11E+02 7.86E+02 5.40E+03 8.9 4.81E-01 1.00E+02 1.66E+01 4.01E+02 7.23E+01 1.10E+02 7.85E+02 5.40E+03 9.0 4.80E-01 8.47E+01 1.39E+01 4.00E+02 6.48E+01 1.09E+02 7.85E+02 5.40E+03 (Source: Amended at 31 Ill. Reg. 4063, effective February 23, 2007)
Section 742.APPENDIX C: Tier 2 Illustrations and Tables
Section 742.TABLE J Values to be Substituted for kd or ks when Evaluating Inorganics as a Function of pH (cm3/g or L/kg or cm3water/gsoil)
pH As Ba Be Cd Cr (+3) Cr (+6) Hg Ni Ag Se Tl Zn Pb 4.9 2.5E+01 1.1E+01 2.3E+01 1.5E+01 1.2E+03 3.1E+01 4.0E-02 1.6E+01 1.0E-01 1.8E+01 4.4E+01 1.6E+01 1.5E+01 5.0 2.5E+01 1.2E+01 2.6E+01 1.7E+01 1.9E+03 3.1E+01 6.0E-02 1.8E+01 1.3E-01 1.7E+01 4.5E+01 1.8E+01 1.5E+01 5.1 2.5E+01 1.4E+01 2.8E+01 1.9E+01 3.0E+03 3.0E+01 9.0E-02 2.0E+01 1.6E-01 1.6E+01 4.6E+01 1.9E+01 1.5E+01 5.2 2.6E+01 1.5E+01 3.1E+01 2.1E+01 4.9E+03 2.9E+01 1.4E-01 2.2E+01 2.1E-01 1.5E+01 4.7E+01 2.1E+01 1.5E+01 5.3 2.6E+01 1.7E+01 3.5E+01 2.3E+01 8.1E+03 2.8E+01 2.0E-01 2.4E+01 2.6E-01 1.4E+01 4.8E+01 2.3E+01 1.5E+01 5.4 2.6E+01 1.9E+01 3.8E+01 2.5E+01 1.3E+04 2.7E+01 3.0E-01 2.6E+01 3.3E-01 1.3E+01 5.0E+01 2.5E+01 1.5E+01 5.5 2.6E+01 2.1E+01 4.2E+01 2.7E+01 2.1E+04 2.7E+01 4.6E-01 2.8E+01 4.2E-01 1.2E+01 5.1E+01 2.6E+01 1.5E+01 5.6 2.6E+01 2.2E+01 4.7E+01 2.9E+01 3.5E+04 2.6E+01 6.9E-01 3.0E+01 5.3E-01 1.1E+01 5.2E+01 2.8E+01 1.5E+01 5.7 2.7E+01 2.4E+01 5.3E+01 3.1E+01 5.5E+04 2.5E+01 1.0E-00 3.2E+01 6.7E-01 1.1E+01 5.4E+01 3.0E+01 1.5E+01 5.8 2.7E+01 2.6E+01 6.0E+01 3.3E+01 8.7E+04 2.5E+01 1.6E-00 3.4E+01 8.4E-01 9.8E+00 5.5E+01 3.2E+01 1.5E+01 5.9 2.7E+01 2.8E+01 6.9E+01 3.5E+01 1.3E+05 2.4E+01 2.3E-00 3.6E+01 1.1E+00 9.2E+00 5.6E+01 3.4E+01 1.5E+01 6.0 2.7E+01 3.0E+01 8.2E+01 3.7E+01 2.0E+05 2.3E+01 3.5E-00 3.8E+01 1.3E+00 8.6E+00 5.8E+01 3.6E+01 1.5E+01 6.1 2.7E+01 3.1E+01 9.9E+01 4.0E+01 3.0E+05 2.3E+01 5.1E-00 4.0E+01 1.7E+00 8.0E+00 5.9E+01 3.9E+01 1.5E+01 6.2 2.8E+01 3.3E+01 1.2E+02 4.2E+01 4.2E+05 2.2E+01 7.5E-00 4.2E+01 2.1E+00 7.5E+00 6.1E+01 4.2E+01 1.5E+01 6.3 2.8E+01 3.5E+01 1.6E+02 4.4E+01 5.8E+05 2.2E+01 1.1E+01 4.5E+01 2.7E+00 7.0E+00 6.2E+01 4.4E+01 1.5E+01 6.4 2.8E+01 3.6E+01 2.1E+02 4.8E+01 7.7E+05 2.1E+01 1.6E+01 4.7E+01 3.4E+00 6.5E+00 6.4E+01 4.7E+01 7.1E+02 6.5 2.8E+01 3.7E+01 2.8E+02 5.2E+01 9.9E+05 2.0E+01 2.2E+01 5.0E+01 4.2E+00 6.1E+00 6.6E+01 5.1E+01 7.1E+02 6.6 2.8E+01 3.9E+01 3.9E+02 5.7E+01 1.2E+06 2.0E+01 3.0E+01 5.4E+01 5.3E+00 5.7E+00 6.7E+01 5.4E+01 7.1E+02 6.7 2.9E+01 4.0E+01 5.5E+02 6.4E+01 1.5E+06 1.9E+01 4.0E+01 5.8E+01 6.6E+00 5.3E+00 6.9E+01 5.8E+01 7.1E+02 6.8 2.9E+01 4.1E+01 7.9E+02 7.5E+01 1.8E+06 1.9E+01 5.2E+01 6.5E+01 8.3E+00 5.0E+00 7.1E+01 6.2E+01 7.1E+02 6.9 2.9E+01 4.2E+01 1.1E+03 9.1E+01 2.1E+06 1.8E+01 6.6E+01 7.4E+01 1.0E+01 4.7E+00 7.3E+01 6.8E+01 7.1E+02 7.0 2.9E+01 4.2E+01 1.7E+03 1.1E+02 2.5E+06 1.8E+01 8.2E+01 8.8E+01 1.3E+01 4.3E+00 7.4E+01 7.5E+01 7.1E+02 7.1 2.9E+01 4.3E+01 2.5E+03 1.5E+02 2.8E+06 1.7E+01 9.9E+01 1.1E+02 1.6E+01 4.1E+00 7.6E+01 8.3E+01 7.1E+02 7.2 3.0E+01 4.4E+01 3.8E+03 2.0E+02 3.1E+06 1.7E+01 1.2E+02 1.4E+02 2.0E+01 3.8E+00 7.8E+01 9.5E+01 7.1E+02 7.3 3.0E+01 4.4E+01 5.7E+03 2.8E+02 3.4E+06 1.6E+01 1.3E+02 1.8E+02 2.5E+01 3.5E+00 8.0E+01 1.1E+02 7.1E+02 7.4 3.0E+01 4.5E+01 8.6E+03 4.0E+02 3.7E+06 1.6E+01 1.5E+02 2.5E+02 3.1E+01 3.3E+00 8.2E+01 1.3E+02 7.1E+02 7.5 3.0E+01 4.6E+01 1.3E+04 5.9E+02 3.9E+06 1.6E+01 1.6E+02 3.5E+02 3.9E+01 3.1E+00 8.5E+01 1.6E+02 7.1E+02 7.6 3.1E+01 4.6E+01 2.0E+04 8.7E+02 4.1E+06 1.5E+01 1.7E+02 4.9E+02 4.8E+01 2.9E+00 8.7E+01 1.9E+02 7.1E+02 7.7 3.1E+01 4.7E+01 3.0E+04 1.3E+03 4.2E+06 1.5E+01 1.8E+02 7.0E+02 5.9E+01 2.7E+00 8.9E+01 2.4E+02 7.1E+02 7.8 3.1E+01 4.9E+01 4.6E+04 1.9E+03 4.3E+06 1.4E+01 1.9E+02 9.9E+02 7.3E+01 2.5E+00 9.1E+01 3.1E+02 7.1E+02 7.9 3.1E+01 5.0E+01 6.9E+04 2.9E+03 4.3E+06 1.4E+01 1.9E+02 1.4E+03 8.9E+01 2.4E+00 9.4E+01 4.0E+02 7.1E+02 8.0 3.1E+01 5.2E+01 1.0E+05 4.3E+03 4.3E+06 1.4E+01 2.0E+02 1.9E+03 1.1E+02 2.2E+00 9.6E+01 5.3E+02 7.1E+02 8.1 3.2E+01 ---a ---a ---a ---a 1.3E+01 ---a ---a ---a 2.1E+00 1.0E+02 ---a 7.1E+02 8.2 3.2E+01 ---a ---a ---a ---a 1.3E+01 ---a ---a ---a 1.9E+00 1.0E+02 ---a 7.1E+02 8.3 3.2E+01 ---a ---a ---a ---a 1.3E+01 ---a ---a ---a 1.8E+00 1.0E+02 ---a 7.1E+02 8.4 3.2E+01 ---a ---a ---a ---a 1.2E+01 ---a ---a ---a 1.7E+00 1.1E+02 ---a 7.1E+02 8.5 3.2E+01 ---a ---a ---a ---a 1.2E+01 ---a ---a ---a 1.6E+00 1.1E+02 ---a 7.1E+02 8.6 3.3E+01 ---a ---a ---a ---a 1.2E+01 ---a ---a ---a 1.5E+00 1.1E+02 ---a 7.1E+02 8.7 3.3E+01 ---a ---a ---a ---a 1.2E+01 ---a ---a ---a 1.4E+00 1.2E+02 ---a 7.1E+02 8.8 3.3E+01 ---a ---a ---a ---a 1.1E+01 ---a ---a ---a 1.3E+00 1.2E+02 ---a 1.9E+03 8.9 3.3E+01 ---a ---a ---a ---a 1.1E+01 ---a ---a ---a 1.2E+00 1.2E+02 ---a 1.9E+03 9.0 3.3E+01 ---a ---a ---a ---a 1.0E+01 ---a ---a ---a 1.1E+00 1.2E+02 ---a 1.9E+03
a No data available for this pH.(Source: Amended at 31 Ill. Reg. 4063, effective February 23, 2007)
Section 742.APPENDIX C Tier 2 Illustrations and Tables
Section 742.TABLE K Parameter Estimates for Calculating Water-Filled Soil Porosity ( q w)
Conductivity, Ks
(m/yr)1,830 0.090 540 0.085 230 0.080 120 0.074 60 0.073 40 0.058 13 0.054 20 0.050 10 0.042 8 0.042 5 0.039
a The appropriate texture classification is determined by a particle size analysis by ASTM D2488-93 as incorporated by reference in Section 742.210 and the U.S. Department of Agriculture Soil Textural Triangle shown in Appendix C, Illustration C.
b Where b is the soil-specific exponential parameter (unitless)
(Source: Amended at 31 Ill. Reg. 4063, effective February 23, 2007)
Section 742.APPENDIX C: Tier 2 Tables
Section 742.Table L: J&E Equationsa
Indoor air remediation objectives (mg/m3)
For carcinogenic contaminants
ROindoor air=TR×ATc×365daysyrED×EF×URF×1000μgmg
J&E1
For noncarcinogenic contaminants
ROindoor air=THQ×ATnc×365daysyr×RfCED×EF
J&E2
To convert mg/m3 from parts per million volume 
Note: 24.45 equals the molar volume of air in liters at normal temperature (25°C) and pressure (760 mm Hg).
J&E3
Soil gas remediation objective (mg/m3)
ROsoil gas= ROindoor airα
J&E4
Soil Vapor Saturation Limit
(mg/m3-air)
J&E5 Groundwater remediation objectives
ROgw=ROsoil gasHTS'×1000Lm3
J&E6
Attenuation factor
Attenuation factor when the mode of contaminant transport is both diffusion and advection
Qsoil = 83.33 cm3/sec
J&E7Attenuation factor when the mode of contaminant transport is diffusion only
Q soil = 0 cm3/sec
J&E8
Total overall effective diffusion coefficient for vapor transport in porous media for multiple soil layers (cm 2 /s) 
J&E9a
In Equation J&E9a, the following condition must be satisfied: 
J&E9b
Source to building separation (cm) 
J&E10
Effective diffusion coefficient for each soil layer (cm 2 /s) 
J&E11
Surface area of enclosed space at or below grade (cm 2 )
For a building with a full concrete slab-on-grade 
J&E12aSurface area of enclosed space at or below grade
(cm 2 )For a building with a full concrete basement floor and walls 
J&E12b Building ventilation rate (cm 3 /s)
Qbldg=LB×WB×HB×ER3600sechr
J&E13
Area of total cracks (cm 2 ) 
J&E14
Effective diffusion coefficient through the cracks (cm 2 /s)
J&E15
Total porosity 
J&E16 Water-filled soil porosity 
J&E17 Air-filled soil porosity 
J&E18
a This table contains equations based on the assumption that the existing or potential building has a full concrete slab-on-grade or a full concrete basement floor and walls. This table applies only when the existing or potential building has a full concrete slab-on-grade or a full concrete basement floor and walls. Institutional controls under Subpart J are required to develop remediation objectives pursuant to this table. This table does not apply when the existing or potential building has neither a full concrete slab-on-grade nor a full concrete basement floor and walls, such as a building with an earthen crawl space, an earthen floor, a stone foundation, a partial concrete floor, or a sump. In such cases, site evaluators have the option of excluding the indoor inhalation exposure route under Section 742.312, meeting the building control technology requirements under Subpart L, or proposing an alternative approach under Tier 3.
(Source: Added at 37 Ill. Reg. 7506, effective July 15, 2013)
Section 742.APPENDIX C: Tier 2 Tables
Section 742.Table M: J&E Parameters
Symbol
Parameter Units Source Tier 1 or Calculated Value AB Surface area of enclosed space
at or below gradecm2
Equation J&E 12a or 12b, Appendix C,
Table L
Residential = 1 x 106
Industrial/Commercial = 4.0 x 106
Acrack Area of total cracks cm2
Equation J&E 14, Appendix C, Table L
Calculated Value ATc Averaging time for carcinogens year
SSL, May 1996
70 ATnc Averaging time for noncarcinogens year
ATnc= ED
Residential = 30
Industrial/Commercial = 25
Cvsat
Soil vapor saturation limit mg/m3-air Equation J&E 5, Appendix C, Table L Chemical-Specific or Calculated Value Dcrackeff Effective diffusion coefficient through the cracks cm2 /s
Equation J&E 15, Appendix C, Table L
Calculated Value Di Diffusivity in air cm2 /s
Appendix C, Table E
Chemical-Specific Dieff Effective diffusion coefficient for each soil layer cm2 /s
Equation J&E 11, Appendix C, Table L
Calculated Value
Dsource
Distance from ground surface to top of contamination cm Field Measurement
Soil Gas Contamination = 152.4
Groundwater Contamination = 304.8
Site-Specific
DTeff
Total overall effective diffusion coefficient
cm2 /s Equation J&E 9a, Appendix C, Table L Calculated Value Dw Diffusivity in water cm2 /s
Appendix C, Table E
Chemical-Specific ED Exposure duration year
Residential: SSL, May 1996
Industrial/Commercial: SSL 2002Residential = 30
Industrial/Commercial = 25EF
Exposure frequency
day/year
Residential: SSL, May 1996
Industrial/Commercial: SSL 2002Residential = 350
Industrial/Commercial = 250ER Air exchange rate exchanges per hour
Illinois EPA
Residential = 0.53
Industrial/Commercial = 0.93
foc Fraction organic carbon content g/g
SSL, May 1996, or Field Measurement
Appendix C, Table F
0.002 or Site-Specific
HB Height of building cm
Illinois EPA
Slab on Grade
Residential = 244
Industrial/Commercial = 305
or Site-Specific in Tier 3
Basement
Residential = 427
Industrial/Commercial = 488
or Site-Specific in Tier 3
H’TS
Dimensionless Henry’s law constant at the system (soil) temperature
13˚C
unitless Appendix C, Table E
Chemical-Specific LB
Length of building cm
Illinois EPA
Residential = 1000
Industrial/Commercial = 2000
or Site-Specific in Tier 3
Lcrack Slab thickness cm
US EPA, Users Guide 2004
10 LF
Distance from ground surface to bottom of slab
cm
US EPA, Users Guide 2004
10 (slab on grade)
200 (basement)Li
Thickness of soil layer i
cm Field Measurement
For capillary fringe, USEPA, 2004Site-Specific
For capillary fringe, 37.5 cmLT Distance from bottom of slab to top of contamination cm
Field Measurement or Equation J&E 10, Appendix C, Table L
142.4 or Site-Specific
MW
Molecular weight g/mole
Illinois EPA
Chemical-Specific n
Total number of layers of different types of soil vapors migrate through from source to building
(if source is groundwater, include a capillary fringe layer of 37.5 cm as one of the layers)
unitless Field measurement Site-Specific P Vapor Pressure atm Appendix C, Table E Chemical-Specific Qbldg Building ventilation rate cm3/s
Equation J&E 13, Appendix C, Table L
Slab on Grade
Residential = 3.59 x 104
Industrial/Commercial = 3.15 x 105
or Site-Specific in Tier 3
Basement
Residential = 6.28 x 104
Industrial/Commercial = 5.04 x 105
or Site-Specific in Tier 3Qsoil
Volumetric flow rate of soil gas into the enclosed space
cm3/s
US EPA, Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings 2004
If LT is less than 5 feet (152 cm),
Qsoil equals 83.33
If LT is 5 feet (152 cm) or greater, Qsoil equals zero
An input value of zero requires an institutional control. See Section 742.505(b) and (c).
R Ideal gas constant atm-L/mol-K US EPA, Users Guide 2004 0.08206
RfC
Reference concentration
ug/m3
Illinois EPA: http://www.epa.state.il.us/land/taco/toxicity-values.xls
Toxicological-Specific
ROgw Groundwater remediation objective mg/L
Appendix B, Table E, or Equation J&E 6, Appendix C, Table L
Chemical-Specific or Calculated Value
ROindoor air
Indoor air remediation objective mg/m3 Equations J&E 1 and 2, Appendix C, Table L
Calculated Value
ROsoil gas
Soil gas remediation objective mg/m3
Equation J&E 4, Appendix C, Table L
Calculated Value S Solubility in water mg/L
Appendix C, Table E
Chemical-Specific T Temperature K US EPA, Users Guide 2004 286 (converted from 13oC) THQ Target hazard quotient for a chemical unitless
SSL, May 1996
1 TR
Target risk or the increased chance of developing cancer over a lifetime due to exposure to a chemical
unitless SSL, May 1996
Residential = 10-6 at the point of human exposure
Industrial/Commercial = 10-6 at the point of human exposure
URF
Unit risk factor (ug/m3) -1
Illinois EPA: http://www.epa.state.il.us/land/taco/toxicity-values.xls
Toxicological- Specific w Floor-wall seam gap cm
US EPA, Users Guide 20040.1 W Moisture content g of water/g of soil Field Measurement, Appendix C, Table F Site-Specific
WB
Width of building cm
Illinois EPA
Residential = 1000
Industrial/Commercial = 2000
or Site-Specific in Tier 3
α Attenuation factor unitless
Equations J&E 7 or 8, Appendix C, Table L
Site-Specific qa Air-filled soil porosity cm3/cm3
SSL, May 1996 or
Equation J&E 18, Appendix C, Table L
0.28 or Calculated Value
qa,crack Air-filled porosity for soil in cracks cm3/cm3
SSL, May 1996 or
Equation J&E 18, Appendix C, Table L
0.13
qa,i Air-filled porosity of soil layer i cm3/cm3
SSL, May 1996 or
Equation J&E 18, Appendix C, Table L
0.13 or Calculated Value
For capillary fringe, q a,i = 0.1 q T,i
qT,crack Total porosity for soil in cracks cm3/cm3
SSL, May 1996 or
Equation J&E 16, Appendix C, Table L
0.43
qT,i Total porosity of soil layer i cm3/cm3
SSL, May 1996 or
Equation J&E 16, Appendix C, Table L
0.43 or Calculated Value
qw Water-filled soil porosity cm3/cm3
SSL, May 1996 or
Equation J&E 17, Appendix C, Table L
0.15 or Calculated Value
qw,crack Water-filled porosity for soil in cracks cm3/cm3
SSL, May 1996 or
Equation J&E 17, Appendix C, Table L
0.15 qw,i Water-filled porosity of soil layer i cm3/cm3
SSL, May 1996 or
Equation J&E 17, Appendix C, Table L
For capillary fringe, US EPA, Users Guide 2004
0.15 or Calculated Value
For capillary fringe = 0.375 or 0.9 q T,i
rb Dry soil bulk density g/cm3
SSL, May 1996 or
Field Measurement, Appendix C, Table F
1.5 or Calculated Value rs,i Soil particle density g/cm3 SSL, May 1996 or
Field Measurement, Appendix C, Table F2.65 or Calculated Value rw Density of water g/cm3 Illinois EPA 1
(Source: Added at 37 Ill. Reg. 7506, effective July 15, 2013)
Section 742.APPENDIX D Highway Authority Agreement
HIGHWAY AUTHORITY AGREEMENT
This Agreement is entered into this ____ day of ________________, 200_ pursuant to 35 Ill. Adm. Code 742.1020 by and between the (1)__________________ (“Property Owner”) [or, in the case of a petroleum leaking underground storage tank, the owner/operator of the tank (“Owner/Operator”)] and (2) Name of Entity in Control of the Right-of-Way (“Highway Authority”), collectively known as the “Parties.”
[Use this paragraph for sites with petroleum leaking underground storage tank(s)] WHEREAS, ___________________ is the owner or operator of one or more leaking underground storage tanks presently or formerly located at common address or description of Site location (“the Site”);
[Use this paragraph for sites that do not have petroleum leaking underground storage tanks] WHEREAS , ____________________ is the owner of the property located at common address or description of Site location (“the Site”);
WHEREAS, as a result of one or more releases of contaminants [ insert either “from the above referenced underground storage tanks” or “at the above referenced Site” ] (“the Release(s)”), soil and/or groundwater contamination at the Site exceeds the Tier 1 residential remediation objectives of 35 Ill. Adm. Code 742;
WHEREAS, the soil and/or groundwater contamination exceeding Tier 1 residential remediation objectives extends or may extend into the Highway Authority’s right-of-way;
WHEREAS, the Owner/Operator or Property Owner is conducting corrective action in response to the Release(s);
WHEREAS, the Parties desire to prevent groundwater beneath the Highway Authority’s right-of-way that exceeds Tier 1 remediation objectives from use as a supply of potable or domestic water and to limit access to soil within the right-of-way that exceeds Tier 1 residential remediation objectives so that human health and the environment are protected during and after any access;
NOW, THEREFORE, the Parties agree as follows:
1. The recitals set forth above are incorporated by reference as if fully set forth herein.
2 . [Use this paragraph if IEMA has issued an incident number] The Illinois Emergency Management Agency has assigned incident number(s) to the Release(s).
3. Attached as Exhibit A is a scaled map(s) prepared by the [Owner/Operator or Property Owner] that shows the Site and surrounding area and delineates the current and estimated future extent of soil and groundwater contamination above the applicable Tier 1 residential remediation objectives as a result of the Release(s). [Use the following sentence if either soil or groundwater is not contaminated above applicable Tier 1 residential remediation objectives: [Soil] [Groundwater] is not contaminated above the applicable Tier 1 residential remediation objectives. ]
4. Attached as Exhibit B is a table(s) prepared by the [Owner/Operator or Property Owner] that lists each contaminant of concern that exceeds its Tier 1 residential remediation objective, its Tier 1 residential remediation objective and its concentrations within the zone where Tier 1 residential remediation objectives are exceeded. The locations of the concentrations listed in Exhibit B are identified on the map(s) in Exhibit A.
5. Attached as Exhibit C is a scaled map prepared by the [Owner/Operator or Property Owner] showing the area of the Highway Authority’s right-of-way that is governed by this agreement (“Right-of-Way”). Because Exhibit C is not a surveyed plat, the Right-of-Way boundary may be an approximation of the actual Right-of-Way lines.
6. [Use this paragraph if samples have not been collected within the Right-of-Way, sampling within the Right-of-Way is not practical, and contamination does not extend beyond the Right-of-Way]. Because the collection of samples within the Right-of-Way is not practical, the Parties stipulate that, based on modeling, soil and groundwater contamination exceeding Tier 1 residential remediation objectives does not and will not extend beyond the boundaries of the Right-of-Way.
7. The Highway Authority stipulates it has jurisdiction over the Right-of-Way that gives it sole control over the use of the groundwater and access to the soil located within or beneath the Right-of-Way.
8. The Highway Authority agrees to prohibit within the Right-of-Way all potable and domestic uses of groundwater exceeding Tier 1 residential remediation objectives.
9. The Highway Authority further agrees to limit access by itself and others to soil within the Right-of-Way exceeding Tier 1 residential remediation objectives. Access shall be allowed only if human health (including worker safety) and the environment are protected during and after any access. The Highway Authority may construct, reconstruct, improve, repair, maintain and operate a highway upon the Right-of-Way, or allow others to do the same by permit. In addition, the Highway Authority and others using or working in the Right-of-Way under permit have the right to remove soil or groundwater from the Right-of-Way and dispose of the same in accordance with applicable environmental laws and regulations. The Highway Authority agrees to issue all permits for work in the Right-of-Way, and make all existing permits for work in the Right-of-Way, subject to the following or a substantially similar condition:
As a condition of this permit the permittee shall request the office issuing this permit to identify sites in the Right-of-Way where a Highway Authority Agreement governs access to soil that exceeds the Tier 1 residential remediation objectives of 35 Ill. Adm. Code 742. The permittee shall take all measures necessary to protect human health (including worker safety) and the environment during and after any access to such soil.
10. This agreement shall be referenced in the Agency’s no further remediation determination issued for the Release(s).
11. The Agency shall be notified of any transfer of jurisdiction over the Right-of-Way at least 30 days prior to the date the transfer takes effect. This agreement shall be null and void upon the transfer unless the transferee agrees to be bound by this agreement as if the transferee were an original party to this agreement. The transferee’s agreement to be bound by the terms of this agreement shall be memorialized at the time of transfer in a writing ("Rider") that references this Highway Authority Agreement and is signed by the Highway Authority, or subsequent transferor, and the transferee.
12. This agreement shall become effective on the date the Agency issues a no further remediation determination for the Release(s). It shall remain effective until the Right-of-Way is demonstrated to be suitable for unrestricted use and the Agency issues a new no further remediation determination to reflect there is no longer a need for this agreement, or until the agreement is otherwise terminated or voided.
13. In addition to any other remedies that may be available, the Agency may bring suit to enforce the terms of this agreement or may, in its sole discretion, declare this agreement null and void if any of the Parties or any transferee violates any term of this agreement. The Parties or transferee shall be notified in writing of any such declaration.
14. This agreement shall be null and void if a court of competent jurisdiction strikes down any part or provision of the agreement.
15. This agreement supersedes any prior written or oral agreements or understandings between the Parties on the subject matter addressed herein. It may be altered, modified or amended only upon the written consent and agreement of the Parties.
16. Any notices or other correspondence regarding this agreement shall be sent to the Parties at following addresses:
Manager, Division of Remediation Management Property Owner or Owner/Operator
Bureau of Land [ Address ]
Illinois Environmental Protection Agency
P.O. Box 19276 ____________________________
Springfield, IL 62974-9276
____________________________
[Contact at Highway Authority]
[Address]
IN WITNESS WHEREOF, the Parties have caused this agreement to be signed by their duly authorized representatives.
[NAME OF LOCAL GOVERNMENT]
Date: _________________________ By: _______________________________________
Its: _______________________________________
Property Owner or Owner/Operator
Date: _________________________ By: _________________________________________
Title
(Source: Added at 31 Ill. Reg. 4063, effective February 23, 2007)
Section 742.APPENDIX E Highway Authority Agreement Memorandum of Agreement
HIGHWAY AUTHORITY AGREEMENT MEMORANDUM OF AGREEMENT
This Memorandum of Agreement is entered by and between the Illinois Environmental Protection Agency (“Agency”) and Name of Local Government (“Highway Authority”), collectively known as the “Parties.”
[Use this paragraph for sites with petroleum leaking underground storage tank(s)] WHEREAS, the Highway Authority is the owner or operator of one or more leaking underground storage tanks presently or formerly located at common address or description of Site location (“the Site”);
[Use this paragraph for sites where the highway authority is also the property owner] WHEREAS , the Highway Authority is the owner of the property located at common address or description of Site location (“the Site”);
WHEREAS, as a result of one or more releases of contaminants [ insert either “from the above referenced underground storage tanks” or “at the above referenced Site” ] (“the Release(s)”), soil and/or groundwater contamination at the Site exceeds the Tier 1 residential remediation objectives of 35 Ill. Adm. Code 742;
WHEREAS, the soil and/or groundwater contamination exceeding Tier 1 residential remediation objectives extends or may extend into the Highway Authority’s right-of-way adjacent to the Site;
WHEREAS, the Highway Authority is conducting corrective action in response to the Release(s);
WHEREAS, the Parties desire to prevent groundwater beneath the Highway Authority’s right-of-way that exceeds Tier 1 residential remediation objectives from use as a supply of potable or domestic water and to limit access to soil within the right-of-way that exceeds Tier 1 residential remediation objectives so that human health and the environment are protected during and after any access;
NOW, THEREFORE, the Parties agree as follows:
1. The recitals set forth above are incorporated by reference as if fully set forth herein.
2. [Use this paragraph if IEMA has issued an incident number] The Illinois Emergency Management Agency has assigned incident number(s) to the Release(s).
3. Attached as Exhibit A is a scaled map(s) prepared by the Highway Authority that shows the Site and surrounding area and delineates the current and estimated future extent of soil and groundwater contamination above the applicable Tier 1 residential remediation objectives as a result of the Release(s). [Use the following sentence if either soil or groundwater is not contaminated above applicable Tier 1 residential remediation objectives: [Soil] [Groundwater] is not contaminated above the applicable Tier 1 residential remediation objectives.]
4. Attached as Exhibit B is a table(s) prepared by the Highway Authority that lists each contaminant of concern that exceeds its Tier 1 residential remediation objective, its Tier 1 residential remediation objective and its concentrations within the zone where Tier 1 residential remediation objectives are exceeded. The locations of the concentrations listed in Exhibit B are identified on the map(s) in Exhibit A.
5. Attached as Exhibit C is a scaled map prepared by the Highway Authority showing the area of the Highway Authority’s right-of-way that is governed by this agreement (“Right-of-Way”). Because Exhibit C is not a surveyed plat, the Right-of-Way boundary may be an approximation of the actual Right-of-Way lines.
6. [Use this paragraph if samples have not been collected within the Right-of-Way, sampling within the Right-of-Way is not practical, and contamination does not extend beyond the Right-of-Way]. Because the collection of samples within the Right-of-Way is not practical, the Parties stipulate that, based on modeling, soil and groundwater contamination exceeding Tier 1 residential remediation objectives does not and will not extend beyond the boundaries of the Right-of-Way.
7. The Highway Authority stipulates it has jurisdiction over the Right-of-Way that gives it sole control over the use of the groundwater and access to the soil located within or beneath the Right-of-Way.
8. The Highway Authority agrees to prohibit within the Right-of-Way all potable and domestic uses of groundwater exceeding Tier 1 residential remediation objectives.
9. The Highway Authority further agrees to limit access by itself and others to soil within the Right-of-Way exceeding Tier 1 residential remediation objectives. Access shall be allowed only if human health (including worker safety) and the environment are protected during and after any access. The Highway Authority may construct, reconstruct, improve, repair, maintain and operate a highway upon the Right-of-Way, or allow others to do the same by permit. In addition, the Highway Authority and others using or working in the Right-of-Way under permit have the right to remove soil or groundwater from the Right-of-Way and dispose of the same in accordance with applicable environmental laws and regulations. The Highway Authority agrees to issue all permits for work in the Right-of-Way, and make all existing permits for work in the Right-of-Way, subject to the following or a substantially similar condition:
As a condition of this permit the permittee shall request the office issuing this permit to identify sites in the Right-of-Way where a Highway Authority Memorandum of Agreement governs access to soil that exceeds the Tier 1 residential remediation objectives of 35 Ill. Adm. Code 742. The permittee shall take all measures necessary to protect human health (including worker safety) and the environment during and after any access to such soil.
10. This agreement shall be referenced in the Agency’s no further remediation determination issued for the Release(s).
11. The Agency shall be notified of any transfer of jurisdiction over the Right-of-Way at least 30 days prior to the date the transfer takes effect. This agreement shall be null and void upon the transfer unless the transferee agrees to be bound by this agreement as if the transferee were an original party to this agreement. The transferee’s agreement to be bound by the terms of this agreement shall be memorialized at the time of transfer in a writing ("Rider") that references this Highway Authority Memorandum of Agreement and is signed by the Highway Authority, or subsequent transferor, and the transferee.
12. This agreement shall become effective on the date the Agency issues a no further remediation determination for the Release(s). It shall remain effective until the Right-of-Way is demonstrated to be suitable for unrestricted use and the Agency issues a new no further remediation determination to reflect there is no longer a need for this agreement, or until the agreement is otherwise terminated or voided.
13. In addition to any other remedies that may be available, the Agency may bring suit to enforce the terms of this agreement or may, in its sole discretion, declare this agreement null and void if the Highway Authority or a transferee violates any term of this agreement. The Highway Authority or transferee shall be notified in writing of any such declaration.
14. This agreement shall be null and void if a court of competent jurisdiction strikes down any part or provision of the agreement.
15. This agreement supersedes any prior written or oral agreements or understandings between the Parties on the subject matter addressed herein. It may be altered, modified or amended only upon the written consent and agreement of the Parties.
16. Any notices or other correspondence regarding this agreement shall be sent to the Parties at following addresses:
Manager, Division of Remediation Management
Bureau of Land
Illinois Environmental Protection Agency
P.O. Box 19276
Springfield, IL 62974-9276
[Contact at Highway Authority]
[Address]
IN WITNESS WHEREOF, the Parties have caused this agreement to be signed by their duly authorized representatives.
[NAME OF LOCAL GOVERNMENT]
Date: _________________________By: ___________________________________
Its: ____________________________________
ILLINOIS ENVIRONMENTAL PROTECTION AGENCY
Date: ____________________________By: ______________________________________
Director
(Source: Added at 31 Ill. Reg. 4063, effective February 23, 2007)
Section 742.APPENDIX F: Environmental Land Use Control
PREPARED BY:
Name: ___________________
___________________
Address: __________________
RETURN TO:
Name: ___________________
___________________
Address: __________________
THE ABOVE SPACE FOR RECORDER’S OFFICE
Model Environmental Land Use Control
THIS ENVIRONMENTAL LAND USE CONTROL (“ELUC”), is made this ________ day of _____________, 20__, by ________________________, (“Property Owner”) of the real property located at the common address____________________________________(“Property”).
WHEREAS, 415 ILCS 5/58.17 and 35 Ill. Adm. Code 742 provide for the use of an ELUC as an institutional control in order to impose land use limitations or requirements related to environmental contamination so that persons conducting remediation can obtain a No Further Remediation determination from the Illinois Environmental Protection Agency (“IEPA”). The reason for an ELUC is to ensure protection of human health and the environment. The limitations and requirements contained herein are necessary in order to protect against exposure to contaminated soil, groundwater, or soil gas that may be present on the property as a result of [ VARIABLE ] activities. Under 35 Ill. Adm. Code 742, the use of risk-based, site-specific remediation objectives may require the use of an ELUC on real property, and the ELUC may apply to certain physical features (e.g., engineered barriers, indoor inhalation building control technologies, monitoring wells, caps, etc.).
WHEREAS, __________________ [ the party performing remediation ] intends to request risk-based, site specific soil, groundwater, or soil gas remediation objectives from IEPA under 35 Ill. Adm. Code 742 to obtain risk-based closure of the site, identified by Bureau of Land [ 10-digit LPC or Identification number ] _________________ , utilizing an ELUC.
NOW, THEREFORE, the recitals set forth above are incorporated by reference as if fully
set forth herein, and the Property Owner agrees as follows:
Date: _________________________________By:_____________________________________
Director
Section One. Property Owner does hereby establish an ELUC on the real estate, situated in the County of ___________, State of Illinois and further described in Exhibit A attached hereto and incorporated herein by reference (the “Property”).
Attached as Exhibit B are site maps that show the legal boundary of the Property, any physical features to which the ELUC applies, the horizontal and vertical extent of the contaminants of concern above the applicable remediation objectives for soil, groundwater, or soil gas, and the nature, location of the source, and direction of movement of the contaminants of concern, as required under 35 Ill. Adm. Code 742.
Section Two. Property Owner represents and warrants he/she is the current owner of the Property and has the authority to record this ELUC on the chain of title for the Property with the Office of the Recorder or Registrar of Titles in ___________ County, Illinois.
Section Three. The Property Owner hereby agrees, for himself/herself , and his/her heirs, grantees, successors, assigns, transferees and any other owner, occupant, lessee, possessor or user of the Property or the holder of any portion thereof or interest therein, that [ INSERT RESTRICTION (e.g. the groundwater under the Property shall not be used as a potable supply of water, and any contaminated groundwater or soil that is removed, excavated, or disturbed from the Property described in Exhibit A herein must be handled in accordance with all applicable laws and regulations )].
Section Four. This ELUC is binding on the Property Owner, his/her heirs, grantees, successors, assigns, transferees and any other owner, occupant, lessee, possessor or user of the Property or the holder of any portion thereof or interest therein. This ELUC shall apply in perpetuity against the Property and shall not be released until the IEPA determines there is no longer a need for this ELUC as an institutional control; until the IEPA, upon written request, issues to the site that received the no further remediation determination a new no further remediation determination approving modification or removal of the limitation(s) or requirement(s); the new no further remediation determination is filed on the chain of title of the site subject to the no further remediation determination; and until a release or modification of the land use limitation or requirement is filed on the chain of title for the Property.
Section Five. Information regarding the remediation performed on the Property may be obtained from the IEPA through a request under the Freedom of Information Act (5 ILCS 140) and rules promulgated thereunder by providing the IEPA with the [10-digit LPC or identification number] listed above.
Section Six. The effective date of this ELUC shall be the date that it is officially recorded in the chain of title for the Property to which the ELUC applies.
WITNESS the following signatures:
Property Owner(s)
By:________________________________________________________________
Its: ________________________________________________________________
Date: _______________________________________________________________
STATE OF ILLINOIS )
) SS:
COUNTY OF )
I, ____________________________the undersigned, a Notary Public for said County and State, DO HEREBY CERTIFY, that ___________________ and __________________, personally known to me to be the Property Owner(s) of __________________________, and personally known to me to be the same persons whose names are subscribed to the foregoing instrument, appeared before me this day in person and severally acknowledged that in said capacities they signed and delivered the said instrument as their free and voluntary act for the uses and purposes therein set forth.
Given under my hand and official seal, this _____ day of ____________________, 20__.
Notary Public
STATE OF _________ )
) S.S.
COUNTY OF ________ )
I, ______________, a notary public, do hereby certify that before me this day in person appeared __________________________, personally known to me to be the Property Owner(s), of _______________________, each severally acknowledged that they signed and delivered the foregoing instrument as the Property Owner(s) herein set forth, and as their own free and voluntary act, for the uses and purposes herein set forth.
Given under my hand and seal this ________ day of _______________, 20__.
Notary Public
PIN NO. XX-XX-XXX-XXX-XXXX
(Parcel Index Number)
Exhibit A
The subject property is located in the City of ____________, __________ County, State of Illinois, commonly known as ______________________________, _________, Illinois and more particularly described as:
LIST THE COMMON ADDRESS;
LEGAL DESCRIPTION; AND
REAL ESTATE TAX INDEX OR PARCEL #
(PURSUANT TO SECTION 742. 1010(d)(2))
PIN NO. XX-XX-XXX-XXX-XXXX
Exhibit B
IN ACCORDANCE WITH SECTION 742.1010(d)(8)(A) through (D), PROVIDE ALL THE FOLLOWING ELEMENTS. ATTACH SEPARATE SHEETS, LABELED AS EXHIBIT B, WHERE NECESSARY.
(A) A scaled map showing the legal boundary of the property to which the ELUC applies.
(B) Scaled maps showing the horizontal and vertical extent of contaminants of concern above the applicable remediation objectives for soil, groundwater, and soil gas to which the ELUC applies.
(C) Scaled maps showing the physical features to which an ELUC applies (e.g., engineered barriers, indoor inhalation building control technologies, monitoring wells, caps, etc.).
(D) Scaled maps showing the nature, location of the source, and direction of movement of the contaminants of concern.
(Source: Amended at 37 Ill. Reg. 7506, effective July 15, 2013)
Section 742.APPENDIX G Model Ordinance
ORDINANCE NUMBER ________
AN ORDINANCE PROHIBITING THE USE OF GROUNDWATER AS A POTABLE WATER SUPPLY BY THE INSTALLATION OR USE OF POTABLE WATER SUPPLY WELLS OR BY ANY OTHER METHOD
WHEREAS, certain properties in the City [Village] of _______________, Illinois have been used over a period of time for commercial/industrial purposes; and
WHEREAS, because of said use, concentrations of certain chemical constituents in the groundwater beneath the City [Village] may exceed Class I groundwater quality standards for potable resource groundwater as set forth in 35 Illinois Administrative Code 620 or Tier 1 remediation objectives as set forth in 35 Illinois Administrative Code 742; and
WHEREAS, the City [Village] of _______________ desires to limit potential threats to human health from groundwater contamination while facilitating the redevelopment and productive use of properties that are the source of said chemical constituents;
NOW, THEREFORE, BE IT ORDAINED BY THE CITY COUNCIL OF THE CITY [VILLAGE] OF ______________________, ILLINOIS:
Section One. Use of groundwater as a potable water supply prohibited.
[Except for such uses or methods in existence before the effective date of this ordinance,] The use or attempt to use as a potable water supply groundwater from within the corporate limits of the City [Village] of ___________________, as a potable water supply, by the installation or drilling of wells or by any other method is hereby prohibited. This prohibition [expressly includes] [does not include] the City [Village] of ________________.
Section Two. Penalties.
Any person violating the provisions of this ordinance shall be subject to a fine of up to ___________ for each violation.
Section Three. Definitions.
“Person” is any individual, partnership, co-partnership, firm, company, limited liability company, corporation, association, joint stock company, trust, estate, political subdivision, or any other legal entity, or their legal representatives, agents or assigns.
“Potable water” is any water used for human or domestic consumption, including, but not limited to, water used for drinking, bathing, swimming, washing dishes, or preparing foods.
Section Four. Memorandum of Understanding.
'[This Section is only necessary if ordinance does not expressly prohibit installation of potable water supply wells by the city or village--could be separate resolution]
The Mayor of the City [Village] of ______________________ is hereby authorized and directed to enter into a Memorandum of Understanding with the Illinois Environmental Protection Agency (“Illinois EPA”) in which the City [Village] of _____________________ assumes responsibility for tracking all sites that have received no further remediation determinations from the Illinois EPA, notifying the Illinois EPA of changes to this ordinance, and taking certain precautions when siting public potable water supply wells.
Section Five. Repealer.
All ordinances or parts of ordinances in conflict with this ordinance are hereby repealed insofar as they are in conflict with this ordinance.
Section Six. Severability.
If any provision of this ordinance or its application to any person or under any circumstances is adjudged invalid, such adjudication shall not affect the validity of the ordinance as a whole or of any portion not adjudged invalid.
Section Seven. Effective date.
This ordinance shall be in full force and effect from and after its passage, approval and publication as required by law.
ADOPTED: _________________ APPROVED: ________________
(Date) (Date)
____________________________ ____________________________
(City Clerk) (Mayor)
Officially published this ______ day of _________________, 20___.
(Source: Added at 31 Ill. Reg. 4063, effective February 23, 2007)
Section 742.APPENDIX H Memorandum of Understanding
MEMORANDUM OF UNDERSTANDING BETWEEN ___________________________ AND THE ILLINOIS ENVIRONMENTAL PROTECTION AGENCY REGARDING THE USE OF A LOCAL GROUNDWATER OR WATER WELL ORDINANCE AS AN ENVIRONMENTAL INSTITUTIONAL CONTROL
I. PURPOSE AND INTENT
A. This Memorandum of Understanding (“MOU”) between _________________________ and the Illinois Environmental Protection Agency (“Illinois EPA”) is entered into for the purpose of satisfying the requirements of 35 Ill. Adm. Code 742.1015 for the use of groundwater or water well ordinances as environmental institutional controls. The Illinois EPA has reviewed the groundwater or water well ordinance of _______________________ (Attachment A) and determined that the ordinance prohibits the use of groundwater for potable purposes and/or the installation and use of new potable water supply wells by private entities but does not expressly prohibit those activities by the unit of local government itself. In such cases, 35 Ill. Adm. Code 742.1015(a) provides that the unit of local government may enter into an MOU with the Illinois EPA to allow the use of the ordinance as an institutional control.
B. The intent of this Memorandum of Understanding is to specify the responsibilities that must be assumed by the unit of local government to satisfy the requirements for MOUs as set forth at 35 Ill. Adm. Code 742.1015(i).
II. DECLARATIONS AND ASSUMPTION OF RESPONSIBILITY
In order to ensure the long-term integrity of the groundwater or water well ordinance as an environmental institutional control and that risk to human health and the environment from contamination left in place in reliance on the groundwater or water well ordinance is effectively managed, ___________________________ hereby assumes the following responsibilities pursuant to 35 Ill. Adm. Code 742.1015(d)(2) and (i):
A. ________________________ will notify the Illinois EPA Bureau of Land of any proposed ordinance changes or requests for variance at least 30 days prior to the date the local government is scheduled to take action on the proposed change or request (35 Ill. Adm. Code 742.1015(i)(4));
B. _________________________ will maintain a registry of all sites within its corporate limits that have received “No Further Remediation” determinations in reliance on the ordinance from the Illinois EPA (35 Ill. Adm. Code 742.1015(i)(5));
C. _________________________ will review the registry of sites established under paragraph II. B. prior to siting public potable water supply wells within the area covered by the ordinance (35 Ill. Adm. Code 742.1015(i)(6)(A));
D. _________________________ will determine whether the potential source of potable water has been or may be affected by contamination left in place at the sites tracked and reviewed under paragraphs II. B. and C. (35 Ill. Adm. Code 742.1015(i)(6)(B)); and
E. _________________________ will take action as necessary to ensure that the potential source of potable water is protected from contamination or treated before it is used as a potable water supply (35 Ill. Adm. Code 742.1015(i)(6)(C)).
NOTE: Notification under paragraph II. A. above or other communications concerning this MOU should be directed to:
Manager, Division of Remediation Management
Bureau of Land
Illinois Environmental Protection Agency
P.O. Box 19276
Springfield, IL 62794-9276
III. SUPPORTING DOCUMENTATION
The following documentation is required by 35 Ill. Adm. Code 742.1015(i) and is attached to this MOU:
A. Attachment A: A copy of the groundwater or water well ordinance certified by the city clerk or other official as the current, controlling law (35 Ill. Adm. Code 742.1015(i)(3));
B. Attachment B: Identification of the legal boundaries within which the ordinance is applicable (certification by city clerk or other official that the ordinance is applicable everywhere within the corporate limits; if ordinance is not applicable throughout the entire city or village, legal description and map of area showing sufficient detail to determine where ordinance is applicable) (35 Ill. Adm. Code 742.1015(i)(2));
C. Attachment C: A statement of the authority of the unit of local government to enter into the MOU (council resolution, code of ordinances, inherent powers of mayor or other official signing MOU -- attach copies) (35 Ill. Adm. Code 742.1015(i)(1)).
IN WITNESS WHEREOF, the lawful representatives of the parties have caused this MOU to be signed as follows:
FOR: __________________________________________
(Name of city or village)
BY: ___________________________________________ DATE: _____________
(Name and title of signatory)
FOR: Illinois Environmental Protection Agency
BY: ____________________________________________ DATE: _____________
Manager, Division of Remediation Management
Bureau of Land
(Source: Added at 31 Ill. Reg. 4063, effective February 23, 2007)
