1. BEFORE THE ILLINOIS POLLUTION CONTROL BOARD
  2. NOTICE
  3. SEE ATTACHED SERVICE LIST
  4. BEFORE THE ILLINOIS POLLUTION CONTROL BOARD
  5. MOTION TO AMEND RULEMAKING PROPOSAL
      1. BEFORE THE ILLINOIS POLLUTION CONTROL BOARD
      2. AMENDED TESTIMONY OF JAMES E. STAUDT, Ph.D.
      3. I. BACKGROUND AND QUALIFICATIONS
      4. II. SUMMARY OF TESTIMONY
      5. Mercury Emissions From Coal Fired Power Plants
      6. Mercury Removal from Coal
      7. Mercury Behavior In the Furnace and Cobenefit Capture
      8. Mercury-Specific Controls, Especially Sorbent Injection
      9. Controlling Mercury from IL Units
      10. Cost of the IL Rule Compared to US EPA’s CAMR
      11. Costs are Likely to Be Less in the Future
  6. STATE OF ILLINOIS )
  7. ) SS
  8. COUNTY OF SANGAMON )
  9. CERTIFICATE OF SERVICE
  10. SEE ATTACHED SERVICE LIST
  11. SERVICE LIST 06-25

BEFORE THE ILLINOIS POLLUTION CONTROL BOARD
IN THE MATTER OF:
)
)
R06-25
PROPOSED NEW 35 ILL. ADM. CODE 225
)
(Rulemaking – Air)
CONTROL OF EMISSIONS FROM
)
LARGE COMBUSTION SOURCES (MERCURY) )

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NOTICE
TO:
Dorothy Gunn
Clerk
Illinois Pollution Control Board
James R. Thompson Center
100 West Randolph St., Suite 11-500
Chicago, IL 60601-3218

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SEE ATTACHED SERVICE LIST
PLEASE TAKE NOTICE that I have today filed with the Office of the Clerk of the
Illinois Pollution Control Board the MOTION TO AMEND RULEMAKING PROPOSAL,
MOTION FOR LEAVE TO FILE INSTANTER AMENDED TESTIMONY OF JAMES E.
STAUDT, Ph.D., and AMENDED TESTIMONY OF JAMES E. STAUDT, Ph.D., a copy of
which is herewith served upon you.
ILLINOIS ENVIRONMENTAL
PROTECTION AGENCY
By: ______________________
Gina Roccaforte
Assistant Counsel
Division of Legal Counsel
DATED: May 23, 2006
1021 North Grand Avenue East
P. O. Box 19276
Springfield, IL 62794-9276
THIS FILING IS SUBMITTED
217/782-5544
ON RECYCLED PAPER
ELECTRONIC FILING, RECEIVED, CLERK'S OFFICE, MAY 23, 2006

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BEFORE THE ILLINOIS POLLUTION CONTROL BOARD
IN THE MATTER OF:
)
)
R06-25
PROPOSED NEW 35 ILL. ADM. CODE 225
)
(Rulemaking – Air)
CONTROL OF EMISSIONS FROM
)
LARGE COMBUSTION SOURCES (MERCURY) )

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MOTION TO AMEND RULEMAKING PROPOSAL
NOW COMES the Proponent, the ILLINOIS ENVIRONMENTAL
PROTECTION AGENCY (Illinois EPA), by its attorneys, and pursuant to 35 Ill. Adm.
Code 101.500 and 102.402, moves that the Illinois Pollution Control Board (Board)
amend proposed new Part 225 to add new Sections 225.234 and 225.238 to Subpart B. In
support of its Motion, the Illinois EPA states as follows:
On March 14, 2006, the Illinois EPA filed a proposal with the Board to add a new
Part 225, 35 Ill. Adm. Code Part 225, entitled "Control of Emissions from Large
Combustion Sources" to control the emissions of mercury from coal-fired electric
generating units (EGUs) beginning in 2009. The Illinois EPA's proposal is intended to
meet certain obligations of the State of Illinois under the federal Clean Air Act (CAA), 42
U.S.C. § 7401
et seq
.; specifically, to satisfy Illinois' obligation to submit a State plan to
address the requirements of the Clean Air Mercury Rule (CAMR),
see
, 70
Fed. Reg.
28606 (May 18, 2005). Under CAMR, states are required to submit State plans to the
United States Environmental Protection Agency by no later than November 17, 2006.
Id
.
at 28649; 40 CFR § 60.24(h)(2).
The Illinois EPA engaged in extensive outreach on this proposal. In January
2006, the Illinois EPA commenced regular meetings with representatives of the affected
ELECTRONIC FILING, RECEIVED, CLERK'S OFFICE, MAY 23, 2006

2
sources and public interest groups and the Illinois EPA distributed working drafts of the
proposed rule to such parties.
During the formulation of the proposed rule, the Illinois EPA considered
including a Temporary Technology Based Standard (TTBS) to provide additional
regulatory flexibility for compliance with the proposed rule. This concept was presented
at several of the stakeholder meetings. A limited number of comments were received;
however, no stakeholders stated that they would utilize such a standard.
After the filing of the rulemaking proposal, a number of stakeholders requested
the provisions of the TTBS. In addition, further review by Illinois EPA staff and an
expert retained by the Illinois EPA identified additional circumstances related to practices
and configurations of sources in the State that warrant the inclusion of the TTBS.
Therefore, the Illinois EPA is now proposing to amend the rulemaking proposal as set
forth in this motion.
The TTBS, as proposed, addresses both new and existing sources with EGUs. In
order to provide additional, appropriate flexibility for compliance by both new and
existing sources with EGUs, separate provisions encompassing the TTBS are warranted.
Those EGUs that satisfy relevant eligibility requirements may demonstrate compliance
with control requirements for mercury emissions via the TTBS provisions for a specified
and limited time frame. Accordingly, the Illinois EPA recommends the acceptance by
the Board of the following amendment to proposed new Part 225 to add new Sections
225.234 and 225.238:
ELECTRONIC FILING, RECEIVED, CLERK'S OFFICE, MAY 23, 2006

3
Section 225.234 Temporary Technology-Based Standard for EGUs at Existing Sources
a)
General
1)
At a source with EGUs that commenced commercial operation on
or before December 31, 2008, for an EGU that meets the eligibility
criteria in subsection (b) of this Section, as an alternative to
compliance with the mercury emission standards in Section
225.230 of this Subpart, the owner or operator of the EGU may
temporarily comply with the requirements of this Section, through
June 30, 2015, as further provided in subsections (c), (d), and (e) of
this Section.
2)
An EGU that is complying with the emission control requirements
of this Subpart by operating under this Section may not be
included in a compliance demonstration involving other EGUs
during the period that it is operating under this Section.
3)
The owner or operator of an EGU that is complying with this
Subpart by means of this Section is not excused from applicable
monitoring, recordkeeping, and reporting requirements in Sections
225.240 through 225.290 of this Subpart.
b)
Eligibility
To be eligible to operate an EGU under this Section, the following criteria
shall be met for the EGU:
1)
The EGU is equipped and operated with the air pollution control
equipment or systems that include injection of halogenated
activated carbon and either (1) a cold-side electrostatic precipitator
or (2) a fabric filter.
2)
The owner or operator of the EGU is injecting halogenated
activated carbon in an optimum manner for control of mercury
emissions, which shall include injection of Alstrom, Norit, Sorbent
Technologies, or other halogenated activated carbon that the owner
or operator of the EGU shows to have similar or better
effectiveness for control of mercury emissions, at least at the
following rates, unless other provisions for injection of
halogenated activated carbon are established in a federally
enforceable operating permit issued for the EGU, with an injection
system designed for effective absorption of mercury, considering
the configuration of the EGU and its ductwork. For this purpose,
flue gas flow rate shall be determined for the point of sorbent
injection, provided, however, that this flow rate may be assumed to
ELECTRONIC FILING, RECEIVED, CLERK'S OFFICE, MAY 23, 2006

4
be identical to the stack flow rate if the gas temperatures at the
point of injection and the stack are normally within 100º F, or may
otherwise be calculated from the stack flow rate, corrected for the
difference in gas temperatures.
A)
For an EGU firing subbituminous coal, 5.0 pounds per
million actual cubic feet.
B)
For an EGU firing bituminous coal, 10.0 pounds per
million actual cubic feet.
C)
For an EGU firing a blend of subbituminous and
bituminous coal, a rate that is the weighted average of the
above rates, based on the blend of coal being fired.
D)
A rate or rates set on a unit-specific basis that are lower
than the rate specified above to the extent that the owner or
operator of the EGU demonstrates that such rate or rates are
needed so that carbon injection would not increase
particulate matter emissions or opacity so as to threaten
compliance with applicable regulatory requirements for
particulate matter or opacity.
3)
The total capacity of the EGUs that operate under this Section does
not exceed the applicable value below:
A)
For the owner or operator of more than one existing source
with EGUs, 25 percent of the total rated capacity, in MW,
of all the EGUs at such existing sources that it owns or
operates, other than any EGUs operating pursuant to
Section 225.235 of this Subpart.
B)
For the owner or operator of only a single existing source
with EGUs (i.e., City, Water, Light & Power, City of
Springfield, ID 167120AAO; Electric Energy, Inc., ID
127855AAC; Kincaid Generating Station, ID 021814AAB;
and Southern Illinois Power Cooperative/Marion
Generating Station, ID 199856AAC), 25 percent of the
total rated capacity, in MW, of the all the EGUs at such
existing sources, other than any EGUs operating pursuant
to Section 225.235 of this Subpart.
c)
Compliance Requirements
1)
Emission Control Requirements
ELECTRONIC FILING, RECEIVED, CLERK'S OFFICE, MAY 23, 2006

5
The owner or operator of an EGU that is operating pursuant to this
Section shall continue to maintain and operate the EGU to comply
with the criteria for eligibility for operation under this Section,
except during an evaluation of the current sorbent, alternative
sorbents or other techniques to control mercury emissions, as
provided by subsection (e) of this Section.
2)
Monitoring and Recordkeeping Requirements
In addition to complying with all applicable reporting requirements
in Sections 225.240 through 225.290 of this Subpart, the owner or
operator of an EGU operating pursuant to this Section shall also:
A)
Through December 31, 2012, maintain records of the usage
of activated carbon, the exhaust gas flow rate from the
EGU, and the activated carbon feed rate, in pounds per
million actual cubic feet of exhaust gas at the injection
point, on a weekly average.
B)
Beginning January 1, 2013, monitor activated carbon feed
rate to the EGU, flue gas temperature at the point of sorbent
injection, and exhaust gas flow rate from the EGU,
automatically recording this data and the activated carbon
feed rate, in pounds per million actual cubic feet of exhaust
gas at the injection point, on an hourly average.
C)
If a blend of bituminous and sub-bituminous coal is fired in
the EGU, records of the amount of each type or coal burned
and the required injection rate for injection of halogenated
activated carbon, on a weekly basis.
3)
Notification and Reporting Requirements
In addition to complying with all applicable reporting requirements
in Sections 225.240 through 225.290 of this Subpart, the owner or
operator of an EGU operating pursuant to this Section shall also
submit the following notifications and reports to the Agency:
A)
Written notification prior to the month in which any of the
following events will occur: the EGU will no longer be
eligible to operate under this Section due to a change in
operation; the type of coal fired in the EGU will change;
the mercury emission standard with which the owner or
operator is attempting to comply for the EGU will change;
or operation under this Section will be terminated.
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6
B)
Quarterly reports for the recordkeeping and monitoring
conducted pursuant to subsection (c)(2) of this Section.
C)
Annual reports detailing activities conducted for the EGU
to further improve control of mercury emissions, including
the measures taken during the past year and activities
planned for the current year.
d)
Applications to Operate under the Technology-Based Standard
1)
Application Deadlines
A)
The owner or operator of an EGU that is seeking to operate
the EGU under this Section shall submit an application to
the Agency no later than three months prior to the date that
compliance with Section 225.230 of this Subpart would
otherwise have to be demonstrated. For example, the
owner or operator of an EGU that is applying to operate the
EGU pursuant to this Section on June 30, 2010, when
compliance with applicable mercury emission standards
must be first demonstrated, shall apply by March 31, 2010
to operate under this Section.
B)
Unless the Agency finds that the EGU is not eligible to
operate under this Section or that the application for
operation under this Section does not meet the requirements
of subsection (d)(2) of this Section, the owner or operator
of the EGU is authorized to operate the EGU under this
Section beginning 60 days after receipt of the application
by the Agency.
C)
The owner or operator of an EGU operating pursuant to this
Section must reapply to operate pursuant to this Section:
i)
If it operated pursuant to this Section during the
period of June 2010 through December 2012 and it
seeks to operate pursuant to this Section during the
period from January 2013 through June 2015.
ii)
If it is planning a physical change to or a change in
the method of operation of the EGU, control
equipment or practices for injection of activated
carbon that is expected to reduce the level of control
of mercury emissions.
2)
Contents of Application
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7
An application to operate pursuant to this Section shall be
submitted as an application for a new or revised federally
enforceable operating permit for the EGU and include the
following:
A)
A formal request to operate pursuant to this Section
showing that the EGU is eligible to operate pursuant to this
Section and describing the reason for the request, the
measures that have been taken for control of mercury
emissions, and factors preventing more effective control of
mercury emissions from the EGU.
B)
The applicable mercury emission standard in Section
225.230(a) with which the owner or operator of the EGU is
attempting to comply and a summary of relevant mercury
emission data for the EGU.
C)
If a unit-specific rate or rates for carbon injection are
proposed pursuant to subsection (b)(2) of this Section,
detailed information to support the proposed injection rates.
D)
An action plan describing the measures that will be taken
while operating under this Section to improve control of
mercury emissions. This plan shall address measures such
as evaluation of alternative forms or sources of activated
carbon, changes to the injection system, changes to
operation of the unit that affect the effectiveness of
mercury absorption and collection, changes to the
particulate matter control device to improve performance
and changes to other emission control devices. For each
measure contained in the plan, the plan shall provide a
detailed description of the specific actions that are planned,
the reason that the measure is being pursued and the range
of improvement in control of mercury that is expected, and
the factors that affect the timing for carrying out the
measure, with the current schedule for the measure.
e)
Evaluation of Alternative Control Techniques for Mercury Emissions
1)
During an evaluation of the effectiveness of the current sorbent,
alternative sorbent, or other technique to control mercury
emissions, the owner or operator of an EGU operating under this
Section need not comply with the eligibility criteria for operation
under this Section as needed to carry out an evaluation of the
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8
practicality and effectiveness of such technique, as further
provided below:
A)
The owner or operator of the EGU shall conduct the
evaluation in accordance with a formal evaluation program
submitted to the Illinois EPA at least 30 days in advance.
B)
The duration and scope of the evaluation shall not exceed
the duration and scope reasonably needed to complete the
desired evaluation of the alternative control technique, as
initially addressed by the owner or owner in a support
document submitted with the evaluation program.
C)
Notwithstanding 35 Ill. Adm. Code 201.146(hhh), the
owner or operator of the EGU shall obtain a construction
permit for any new or modified air pollution control
equipment to be constructed as part of the evaluation of the
alternative control technique.
D)
The owner or operator of the EGU shall submit a report to
the Illinois EPA no later than 90 days after the conclusion
of the evaluation describing the evaluation that was
conducted and providing the results of the evaluation.
2)
If the evaluation of the alternative control technique shows less
effective control of mercury emissions from the EGU than
achieved with the prior control technique, the owner or operator of
the EGU shall resume use of the prior control technique. If the
evaluation of the alternative control technique shows comparable
effectiveness, the owner or operator of the EGU may either
continue to use the alternative control technique in an optimum
manner or resume use of the prior control technique. If the
evaluation of the alternative control technique shows more
effective control of mercury emissions, the owner or operator of
the EGU shall continue to use the alternative control technique in
an optimum manner, if it continues to operate under this Section.
Section 225.238 Temporary Technology-Based Standard for New Sources with EGUs
a)
General
1)
At a source with EGUs that previously had not had any EGUs that
commenced commercial operation before January 1, 2009, for an
EGU that meets the eligibility criteria in subsection (b) of this
Section, as an alternative to compliance with the mercury emission
standards in Section 225.237of this Subpart, the owner or operator
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9
of the EGU may temporarily comply with the requirements of this
Section, through December 31, 2018, as further provided in
subsections (c), (d), and (e) of this Section.
2)
An EGU that is complying with the emission control requirements
of this Subpart by operating under this Section may not be
included in a compliance demonstration involving other EGUs at
the source during the period that such standard is in effect.
3)
The owner or operator of an EGU that is complying with this
Subpart by means of this Section is not excused from applicable
monitoring, recordkeeping, and reporting requirements in Sections
225.240 through 225.290 of this Subpart.
b)
Eligibility
To be eligible to operate an EGU under this Section, the following criteria
shall be met for the EGU:
1)
The EGU is subject to Best Available Control Technology (BACT)
for emissions of sulfur dioxide, nitrogen oxides and particulate
matter and is equipped and operated with the air pollution control
equipment or systems specified below, as applicable to the category
of EGU:
A)
For coal-fired boilers, injection of halogenated activated
carbon.
B)
For an EGU firing fuel gas produced by coal gasification,
processing of the raw fuel gas prior to combustion for
removal of mercury with system a using activated carbon.
2)
For an EGU for which injection of halogenated activated carbon is
required by subsection (b)(1) of this Section, the owner or operator
of the EGU is injecting halogenated activated carbon in an
optimum manner for control of mercury emissions, which shall
include injection of Alstrom, Norit, Sorbent Technologies, or other
halogenated activated carbon that the owner or operator of the
EGU shows to have similar or better effectiveness for control of
mercury emissions, at least at the following rates, unless other
provisions for injection of halogenated activated carbon are
established in a federally enforceable operating permit issued for
the EGU, with an injection system designed for effective
absorption of mercury. For this purpose, flue gas flow rate shall be
determined for the point of sorbent injection, provided, however,
that this flow rate may be assumed to be identical to the stack flow
ELECTRONIC FILING, RECEIVED, CLERK'S OFFICE, MAY 23, 2006

10
rate if the gas temperatures at the point of injection and the stack
are normally within 100º F, or may otherwise be calculated from
the stack flow rate, corrected for the difference in gas
temperatures.
A)
For an EGU firing subbituminous coal, 5.0 pounds per
million actual cubic feet.
B)
For an EGU firing bituminous coal, 10.0 pounds per
million actual cubic feet.
C)
For an EGU firing a blend of subbituminous and
bituminous coal, a rate that is the weighted average of the
above rates, based on the blend of coal being fired.
c)
Compliance Requirements
1)
Emission Control Requirements
The owner or operator of an EGU that is operating pursuant to this
Section shall continue to maintain and operate the EGU to comply
with the criteria for eligibility for operation under this Section,
except during an evaluation of the current sorbent, alternative
sorbents or other techniques to control mercury emissions, as
provided by subsection (e) of this Section.
2)
Monitoring and Recordkeeping Requirements
In addition to complying with all applicable reporting requirements
in Sections 225.240 through 225.290 of this Subpart, the owner or
operator of a new EGU operating pursuant to this Section shall
also:
A)
Monitor activated carbon feed rate to the EGU, flue gas
temperature at the point of sorbent injection, and exhaust
gas flow rate from the EGU, automatically recording this
data and the activated carbon feed rate, in pounds per
million actual cubic feet of exhaust gas at the injection
point, on an hourly average.
B)
If a blend of bituminous and sub-bituminous coal is fired in
the EGU, records of the amount of each type or coal burned
and the required injection rate for injection of halogenated
activated carbon, on a weekly basis.
3)
Notification and Reporting Requirements
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11
In addition to complying with all applicable reporting requirements
in Sections 225.240 through 225.290 of this Subpart, the owner or
operator of an EGU operating pursuant to this Section shall also
submit the following notifications and reports to the Agency:
A)
Written notification prior to the month in which any of the
following events will occur: the EGU will no longer be
eligible to operate under this Section due to a change in
operation; the type of coal fired in the EGU will change;
the mercury emission standard with which the owner or
operator is attempting to comply for the EGU will change;
or operation under this Section will be terminated.
B)
Quarterly reports for the recordkeeping and monitoring
conducted pursuant to subsection (c)(2) of this Section.
C)
Annual reports detailing activities conducted for the EGU
to further improve control of mercury emissions, including
the measures taken during the past year and activities
planned for the current year.
d)
Applications to Operate under the Technology-Based Standard
1)
Application Deadlines
A)
The owner or operator of an EGU that is seeking to operate
the EGU under this Section shall submit an application to
the Agency no later than three months prior to the date that
compliance with Section 225.237 of this Subpart would
otherwise have to be demonstrated.
B)
Unless the Agency finds that the EGU is not eligible to
operate under this Section or that the application for
operation under this Section does not meet the requirements
of subsection (d)(2) of this Section, the owner or operator
of the EGU is authorized to operate the EGU under this
Section beginning 60 days after receipt of the application
by the Agency.
C)
The owner or operator of an EGU operating pursuant to this
Section must reapply to operate pursuant to this Section if it
is planning a physical change to or a change in the method
of operation of the EGU, control equipment or practices for
injection of activated carbon that is expected to reduce the
level of control of mercury emissions.
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12
2)
Contents of Application
An application to operate pursuant to this Section shall be
submitted as an application for a new or revised federally
enforceable operating permit for the new EGU and include the
following:
A)
A formal request to operate pursuant to this Section
showing that the EGU is eligible to operate pursuant to this
Section and describing the reason for the request, the
measures that have been taken for control of mercury
emissions, and factors preventing more effective control of
mercury emissions from the EGU.
B)
The applicable mercury emission standard in Section
225.237 with which the owner or operator of the EGU is
attempting to comply and a summary of relevant mercury
emission data for the EGU.
C)
If a unit-specific rate or rates for carbon injection are
proposed pursuant to subsection (b)(2) of this Section,
detailed information to support the proposed injection rates.
D)
An action plan describing the measures that will be taken
while operating under this Section to improve control of
mercury emissions. This plan shall address measures such
as evaluation of alternative forms or sources of activated
carbon, changes to the injection system, changes to
operation of the unit that affect the effectiveness of
mercury absorption and collection, and changes to other
emission control devices. For each measure contained in
the plan, the plan shall provide a detailed description of the
specific actions that are planned, the reason that the
measure is being pursued and the range of improvement in
control of mercury that is expected, and the factors that
affect the timing for carrying out the measure, with the
current schedule for the measure.
e)
Evaluation of Alternative Control Techniques for Mercury Emissions
1)
During an evaluation of the effectiveness of the current sorbent,
alternative sorbent, or other technique to control mercury
emissions, the owner or operator of an EGU operating under this
Section need not comply with the eligibility criteria for operation
under this Section as needed to carry out an evaluation of the
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13
practicality and effectiveness of such technique, as further
provided below:
A)
The owner or operator of the EGU shall conduct the
evaluation in accordance with a formal evaluation program
submitted to the Illinois EPA at least 30 days in advance.
B)
The duration and scope of the evaluation shall not exceed
the duration and scope reasonably needed to complete the
desired evaluation of the alternative control technique, as
initially addressed by the owner or owner in a support
document submitted with the evaluation program.
C)
Notwithstanding 35 Ill. Adm. Code 201.146(hhh), the
owner or operator of the EGU shall obtain a construction
permit for any new or modified air pollution control
equipment to be constructed as part of the evaluation of the
alternative control technique.
D)
The owner or operator of the EGU shall submit a report to
the Illinois EPA no later than 90 days after the conclusion
of the evaluation describing the evaluation that was
conducted and providing the results of the evaluation.
2)
If the evaluation of the alternative control technique shows less
effective control of mercury emissions from the EGU than
achieved with the prior control technique, the owner or operator of
the EGU shall resume use of the prior control technique. If the
evaluation of the alternative control technique shows comparable
effectiveness, the owner or operator of the EGU may either
continue to use the alternative control technique in an optimum
manner or resume use of the prior control technique. If the
evaluation of the alternative control technique shows more
effective control of mercury emissions, the owner or operator of
the EGU shall continue to use the alternative control technique in
an optimum manner, if it continues to operate under this Section.
WHEREFORE, for the reasons set forth above, the Illinois EPA moves that the
Board amend proposed new Part 225 to add new Sections 225.234 and 225.238 to
Subpart B as set forth herein.
ELECTRONIC FILING, RECEIVED, CLERK'S OFFICE, MAY 23, 2006

14
Respectfully submitted,
ILLINOIS ENVIRONMENTAL
PROTECTION AGENCY
By:
__________________
Charles E. Matoesian
Assistant Counsel
Division of Legal Counsel
__________________
Gina Roccaforte
Assistant Counsel
Division of Legal Counsel
DATED: May 23, 2006
1021 N. Grand Ave., East
P.O. Box 19276
Springfield, Illinois 62794-9276
217/782-5544
ELECTRONIC FILING, RECEIVED, CLERK'S OFFICE, MAY 23, 2006

BEFORE THE ILLINOIS POLLUTION CONTROL BOARD
IN THE MATTER OF:
)
)
R06-25
PROPOSED NEW 35 ILL. ADM. CODE 225
)
(Rulemaking – Air)
CONTROL OF EMISSIONS FROM
)
LARGE COMBUSTION SOURCES (MERCURY) )
MOTION FOR LEAVE TO FILE INSTANTER AMENDED TESTIMONY OF
JAMES E. STAUDT, Ph.D.
NOW COMES the Proponent, the Illinois Environmental Protection Agency
(Illinois EPA), by its attorneys, and pursuant to 35 Ill. Adm. Code 101.500 and 102.402,
hereby requests that the Illinois Pollution Control Board (Board) grant the Illinois EPA
leave to file instanter the Amended Testimony of James E. Statudt, Ph.D. In support of
this motion, the Illinois EPA states as follows:
1.
On May 19, 2006, following consideration of an emergency motion filed
by the Participants to this rulemaking proceeding, the Board’s assigned Hearing Officer
entered a scheduling order. The order included,
inter alia
, the acknowledgement that the
Illinois EPA would be submitting amended pre-filed testimony of Dr. James Staudt on
May 19, 2006, and that the Participants would in turn be required to submit pre-filed
questions on May 19, 2006 as well.
2.
Since the filing of Dr. Staudt’s amended testimony on May 19
th
, further
circumstances have transpired that require the further amendment of his testimony. For
reasons fully addressed in the Illinois EPA’s Motion to Amend Rulemaking Proposal,
filed contemporaneously on this date, Dr. Staudt’s testimony needs to be amended again
to explain and reflect the additional provisions sought for inclusion in the rulemaking
proposal.
ELECTRONIC FILING, RECEIVED, CLERK'S OFFICE, MAY 23, 2006

3.
Although the Illinois EPA regrets the timing of this latest request, the
amended pre-filed testimony of Dr. Staudt that is the subject of this motion is being
offered only two business days following the filing of the previous testimony. Further,
this amended testimony is necessary to accompany the language that is the subject of the
Motion to Amend Rulemaking Proposal.
WHEREFORE, for the reasons stated above, the Illinois EPA hereby respectfully
requests that the Board grant the Illinois EPA leave to file instanter the amended
testimony of Dr. Staudt.
Respectfully submitted,
ILLINOIS ENVIRONMENTAL PROTECTION AGENCY,
____________________________
John J. Kim
Managing Attorney
Air Regulatory Unit
Division of Legal Counsel
1021 North Grand Avenue East
P.O. Box 19276
Springfield, Illinois 62794-9276
217/782-5544
217/782-9143 (TDD)
Dated: May 23, 2006
ELECTRONIC FILING, RECEIVED, CLERK'S OFFICE, MAY 23, 2006

BEFORE THE ILLINOIS POLLUTION CONTROL BOARD
IN THE MATTER OF:
)
)
R06-25
PROPOSED NEW 35 ILL. ADM. CODE 225
)
(Rulemaking – Air)
CONTROL OF EMISSIONS FROM
)
LARGE COMBUSTION SOURCES (MERCURY) )
AMENDED TESTIMONY OF JAMES E. STAUDT, Ph.D.
I, James E. Staudt, have been retained by the Illinois Environmental Protection Agency (IL EPA)
as an expert in this electric power plant mercury emissions rule development.
I expect to testify at the hearing on the current state-of-the-art of mercury emissions control
technology for coal-fired power plants and the potential use of these control technologies by
Illinois coal-fired power plants to comply with the rule that has been proposed by IL EPA.
I.
BACKGROUND AND QUALIFICATIONS
I am currently the President of Andover Technology Partners (“ATP”). As President of ATP, I
have advised power plants, equipment suppliers and government agencies on ways to comply
with emissions regulations in cost-effective ways. For nearly twenty years, I have worked in the
field of air pollution control technology, including mercury emissions control. For the past nine
years (since 1997) I have been a consultant with my own business – Andover Technology
Partners. My primary area of business as a consultant is associated with my expertise relating to
the performance and cost of air pollution control technologies on power plants. Clients have
included the US EPA, power plant owners, technology suppliers, and others. I have published
several papers and reports, including papers in peer-reviewed journals and reports issued by the
US EPA, on mercury control technology and the cost of controlling mercury on power plants.
Several of these papers have been coauthored with staff of the US EPA. For most of the period
from 1988 to 1997 I was employed by companies that supplied air pollution control technology
(Research Cottrell and Fuel Tech) or power plant and refinery gas analyzers (Spectrum
Diagnostix, a subsidiary of Physical Sciences that was acquired by Western Research). As an
ELECTRONIC FILING, RECEIVED, CLERK'S OFFICE, MAY 23, 2006

2
employee of these companies over this period I sold, designed, and commissioned air pollution
control technology at numerous power plants and industrial facilities.
I received my M.S. (1986) and Ph.D. (1987) in Mechanical Engineering from the Massachusetts
Institute of Technology. I received my B.S. in Mechanical Engineering from the U.S. Naval
Academy in 1979. From 1979 to 1984 I served as a commissioned officer in the U.S. Navy in
the Engineering Department of a nuclear-powered aircraft carrier.
II.
SUMMARY OF TESTIMONY
At the Hearing I expect to testify on how mercury emissions from coal power plants can be
controlled and what those controls are expected to cost Illinois power plants that will be required
to comply with the proposed mercury control rule should it be finalized. By reference, my
testimony includes Section 8 of the Technical Support Document (TSD): Technological
Feasibility of Controlling Mercury Emissions from Coal-fired Power Plants in Illinois.
Mercury Emissions From Coal Fired Power Plants
The mercury emissions from a coal-fired power plant are the result of the mercury content in the
coal that is burned and the extent that processes in the boiler prevent the mercury from being
released with the exhaust gases of the power plant. Mercury may be removed from the coal prior
to combustion of the coal. This may be achieved by coal cleaning or by some other treatment of
the coal. Or, mercury may be removed from the boiler flue gases by Air Pollution Control
(APC) equipment. Sometimes the APC equipment that removes the mercury is equipment that is
installed primarily to remove other pollutants, such as Particle Matter (PM) or acid gases in a
Flue Gas Desulfurization system (FGD, also called SO
2
scrubbers). Mercury removal in this
manner is called co-benefit mercury removal. Mercury may also be removed by air pollution
control systems that are specifically designed to remove mercury from the flue gases.
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Mercury Removal from Coal
Run of mine (ROM) bituminous coal is frequently cleaned for the following purposes:
Removal of impurities to improve the heating value of the coal
Reduction of transportation costs for coal to the power plant and ash from the power
plant
Maintenance of ash content in coal supply within contract requirements
Removal of sulfur, mainly as pyrites, lowering SO
2
emissions when the coal is burned.
However, cleaning ROM coal will provide the added benefit of removing mercury from the coal.
This is because mercury in the coal is preferentially associated with pyrites and other non-
combustible materials that are removed in coal washing. Mercury removal from the coal before
combustion through washing will contribute to lower mercury emissions from the plant.
Mercury Behavior In the Furnace and Cobenefit Capture
Mercury that is present in trace amounts in the coal is released from the coal during combustion.
At furnace conditions, the released mercury is present in a gaseous state in the elemental form
that is denoted as Hg
o
. As the combustion exhaust gases cool in the boiler, chemistry shifts to
favor an oxidized, or ionic, form of mercury, denoted as Hg
2+
. Some of the Hg
2+
is adsorbed
onto particles to form Hg
p.
The Hg
p
is readily captured in PM emission control devices that all
IL coal power plants are equipped with – ESPs or fabric filters. Hg
2+
is water soluble and can be
captured by FGD systems if they are installed. However, not all of the Hg
o
becomes Hg
2+
or Hg
p
due to limitations on the chemistry that result from several factors, such as concentration of
chlorine (the most common form of Hg
2+
is HgCl
2
), flue gas temperature, and other factors. As a
result of this, the level of cobenefit mercury capture in the PM emission control devices or SO
2
scrubbers may vary based upon the type of equipment, the constituents in the coal, and other
factors. NOx controls, such as Selective Catalytic Reduction (SCR) and combustion staging, can
enhance the capture that is achieved in PM or SO
2
controls. Results of measurements of co-
benefit mercury removal rates taken in response to the U.S. EPA’s Information Collection
Request (ICR) as part of the development of the federal Clean Air Mercury Rule and subsequent
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test programs since the ICR program provided data that indicates that the following cobenefit
removal rates may be expected:
For pulverized-coal boilers firing bituminous coal and equipped with SCR, and ESP, and
wet FGD, co-benefit mercury capture is expected to be about 90%.
For pulverized-coal boilers firing bituminous coal and equipped with an ESP, co-benefit
mercury capture is expected to be in the range of about 30%-50%.
For boilers firing bituminous coal in a circulating fluidized bed (CFB) arrangement with
a fabric filter, co-benefit mercury capture over 90% is expected to be achieved.
For pulverized-coal boilers firing subbituminous coal and equipped with only an ESP,
low co-benefit mercury capture is expected.
For pulverized-coal boilers firing any kind of coal and equipped with only a hot-side
ESP, co-benefit mercury capture is expected to be low.
Cobenefit controls may be optimized through a variety of techniques that are described in more
detail in the TSD. Depending upon the fuel being fired and the boiler’s configuration,
optimization methods can significantly improve cobenefit mercury removal.
Mercury-Specific Controls, Especially Sorbent Injection
The previous section addressed the important factors impacting mercury capture by co-benefit
from NOx, PM or SO
2
control technologies. As discussed, boilers that fire subbituminous coal –
which there currently are many of in Illinois – are not likely to achieve high levels of mercury
removal from co-benefits alone. Some of the bituminous coal fired boilers may not achieve
adequately low mercury emissions by co-benefits alone. Therefore, these plants may need
additional controls to achieve the levels of mercury removal that are being required in the
proposed rule.
Although many mercury control methods are under development, sorbent injection is clearly the
most developed. It is the only approach that has been tested on several coal-fired boilers firing a
wide range of fuels. Power companies have entered contracts for commercial systems, some
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with statutory requirements to achieve 90% or more mercury removal. Moreover, injection of
sorbent, particularly Powdered Activated Carbon (PAC), has been used for mercury control on
hundreds of municipal waste combustors in the United States and in Europe for several years.
The equipment is fairly simple, relatively easy to install, relatively inexpensive in capital cost,
and it is well understood. The sorbent, PAC, is widely available from several suppliers.
There are three ways that the sorbent can be admitted to the gas stream:
Normal sorbent injection – upstream of the existing ESP or fabric filter and the most
inexpensive approach. Typical capital cost is around $2/KW
TOXECON – An acronym for TOXic Emission CONtrol device. This entails retrofitting
a fabric filter downstream of the existing ESP and injecting the sorbent into the gas
stream between the ESP and the fabric filter with the fabric filter capturing the sorbent.
This approach has been shown to work very effectively to provide over 90% removal for
any fuel. It also keeps captured fly ash segregated from captured sorbent, an advantage
for plants that market their fly ash. However, this is a more costly approach, with higher
capital cost than normal sorbent injection.
TOXECON-II. This is a newer approach that entails injecting the sorbent between fields
of the ESP. Upstream ESP fields capture most of the fly ash and downstream ESP fields
capture the sorbent and a small amount of fly ash. This approach can have advantages
for power plants that sell their fly ash.
Sorbent injection technology for mercury control from coal-fired boilers has been a very active
area of research because the low capital cost of the technology and ease of retrofit make it an
attractive retrofit control method. The TSD lists over three dozen full scale field trials on
operating electric utility boilers that I am aware of – all but a few having been completed. These
tests have been on a wide range of coals and boiler configurations. Some tests have lasted only a
few days, some for over 30 days of continuous operation and at least one for over a year.
Virtually all of this testing has been in the last five years and most in the last 2-3 years. So, the
technology has advanced rapidly over the last few years and experience from just a few years
ago may be obsolete. This is especially true when considering the new sorbents that have been
developed specifically for use on coal-fired boilers.
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Although untreated PAC, as is used in municipal waste incinerators, has been tested and shown
to be effective in some coal-fired boiler applications, experience has shown that for most coal-
fired boiler applications PAC sorbents that are treated with halogens on the surface of the PAC
are much more effective. Unlike untreated PACs, which have a wide range of industrial
applications, halogenated PAC sorbents were specifically formulated to address the mercury
capture needs of coal-fired boilers. As a result, halogenated PAC sorbents are the current state-
of-the-art for most applications and few users would consider untreated PAC for high removal
rates except possibly where a fabric filter was installed.
Controlling Mercury from IL Units
It is my opinion that the coal-fired units in the state of Illinois are capable of meeting the
requirements of the proposed mercury control rule at a cost close to that described in the TSD.
Because of the different coal types and boiler configurations, not all units will use the same
approach. There is a risk that a small number of coal-fired units in Illinois may need a
Temporary Technology Based Standard (TTBS) until they bring their emissions reductions in
compliance with the emission reduction requirements of the rule. However, this would result in
a very small increase in the overall cost of the program over what is described in the TSD.
Most of the boilers in IL fire subbituminous coal. For subbituminous coals, such as Powder
River Basin (PRB) coals that are used widely in Illinois, halogenated PAC has been shown to be
very effective at several full-scale coal-fired boiler installations providing 90% or more removal.
At several sites injection of the halogenated PAC has shown that it provides over 90% mercury
removal at treatment rates of about 3 pounds of sorbent per million actual cubic feet of flue gas
(lb/MMacf) when injected upstream of a cold-side ESP. This testing includes at least two 30-day
continuous trials where 93% or more mercury removal was achieved over the period. This
treatment rate for 90% or more removal is equivalent to about 200 pounds per hour of sorbent on
a 300 MW plant at full load, or about $180/hour in sorbent cost with sorbent priced at about
$0.90/lb. When injected upstream of a fabric filter, as will be possible on a few Dynegy units
that, under consent decree, are required to retrofit fabric filters, the sorbent requirements are far
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7
less and the mercury removal is even higher. For subbituminous coal, the results of the field
trials with halogenated PAC sorbent at various sites have been remarkably consistent from site to
site. The consistency of these results from site to site suggests high confidence in the
performance on other units firing similar fuels, such as many of the PRB fired units in Illinois.
There is a risk, however, that on some subbituminous-fired units the design of the existing
particulate control device may limit the injection rate of sorbent due to PM control issues or the
use of SO
3
flue gas conditioning may limit sorbent effectiveness – thereby limiting mercury
emissions reduction. But, this risk is likely to be small due to the very low halogenated sorbent
injection rates that have been shown to be necessary on PRB fuel fired boilers and because there
are alternative flue gas conditioning methods that may be used. Therefore, I would expect few,
if any units would use a TTBS until they could comply with the reduction requirements of the
rule.
For those bituminous coal units that are equipped with SCR and FGD, they are likely already
achieving close to 90% removal or the output based limit of 0.008 lb/GWhr. Those that are not
already at these levels of control are close enough that they can achieve the remainder through an
optimization method, such as scrubber optimization, or a scrubber chemical additive, which will
be a modest cost. Or, these units may use sorbent injection to achieve the very modest
incremental reduction needed. Most of the pulverized coal capacity firing bituminous coal that is
not equipped with SCR and FGD are firing low to medium sulfur coal. Dynegy’s Vermillion
plant will be equipped with a fabric filter in the future. With the fabric filter I expect Vermillion
will have very high cobenefit mercury removal – close to 90% - and can readily achieve over
90% removal with sorbent injection. There is also a bituminous unit at Marion that uses CFB
technology and a fabric filter. Most likely, this unit already achieves over 90% mercury
removal. But, it could easily add sorbent injection to achieve over 90% removal if necessary.
A small fraction of the unscrubbed bituminous capacity fires some high-sulfur coal. But, some
of these units (Hutsonville) are reported to be shifting to low-sulfur western coal as they deplete
their high-sulfur coal inventories. Full-scale tests have shown that halogenated sorbents can
achieve high removal rates on low to medium sulfur bituminous coal, albeit at somewhat higher
injection concentrations than for PRB fuels. Combined with some cobenefit removal, 90%
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8
mercury removal with halogenated sorbent injection in the range of 6-7 lb/MMacf has been
shown on low-medium sulfur bituminous units. For the unscrubbed high-sulfur coal capacity,
less mercury removal is likely. However, the unscrubbed high-sulfur units are Meredosia boilers
1-4 and are small, low capacity-factor units that are co-located on a site with a much larger unit
that fires low-sulfur western coal. I expect that the much larger Merodosia #5 is capable of over
90% removal with halogenated activated carbon. It is possible that Meredosia boilers 1-5 may
be able to average under the provisions of the IL rule to achieve the facility-wide target emission
reduction. Alternatively, it may be possible for the smaller Meredosia boilers 1-4 to shift to the
same low-sulfur coal that is burned in #5, which I expect would address the concern. Or, these
units might reduce mercury with sorbent injection and use a TTBS until they can bring their
emissions within the control requirements of the rule.
There are two units in Illinois – Waukegan 7 and Will County 3 - that are equipped with hot-side
ESPs and have not announced plans to install fabric filters. Using a TOXECON system, these
units can readily achieve 90% or more mercury removal. TOXECON has been assumed for
these units in the cost estimate of the TSD. Although TOXECON is more costly than a normal
sorbent injection system, a TOXECON system offers advantages with regard to PM emissions
control, lower sorbent usage, and also segregates the fly ash from the collected sorbent.
Cost of the IL Rule Compared to US EPA’s CAMR
US EPA’s CAMR rule sets a 2010 allowance cap that requires IL plants to remove about 70% of
the mercury in the coal or purchase the equivalent number of mercury allowances. A stricter cap
is required in 2018. Because a mercury allowance market does not exist yet and prices are very
uncertain, relying on allowances for compliance with CAMR in 2010 is very risky. Moreover,
subbituminous units are among the least expensive units to control with sorbent injection. As a
result, I expect that most or all of the subbituminous units in IL will install sorbent injection
systems regardless of an IL mercury rule. Therefore, the cost of the IL rule over that of CAMR
during the period from 2010 to 2018 may be estimated as only the incremental cost from 70%
control to 90% control and is mainly the cost of additional sorbent. When comparing the cost of
complying with the proposed IL rule with the cost of complying with CAMR, I determined that
ELECTRONIC FILING, RECEIVED, CLERK'S OFFICE, MAY 23, 2006

9
the state-wide incremental cost of the IL rule over CAMR was roughly $32-$37 million per year
spread across all of the Illinois units for the period 2010-2018. In the event that some units
comply through a TTBS until they can achieve the required mercury emission reductions, the
cost difference will be only slightly higher. There is, however, a small risk that some units will
be unable to comply with the rule as anticipated in the TSD due to the limitation on the allowable
MW that may use a TTBS. In this case, these units will require more costly controls. However,
I believe that the limitation on the amount of generating capacity that may use a TTBS is likely
to be sufficient to address the small number of units that may require extra time to comply.
Therefore, more costly controls are likely to be avoided.
In 2018 the CAMR allowance cap is such that it will require about 90% or more mercury
removal from the coal or purchase of an equivalent number of allowances. Therefore, in 2018
and thereafter the IL rule incurs little or no additional cost of compliance over CAMR.
Costs are Likely to Be Less in the Future
The state-of-the-art of mercury sorbent technology is improving. As discussed in the TSD, there
are several emerging sorbent technologies that may improve mercury capture performance
beyond what is possible with the currently available halogenated PACs and will thereby reduce
the cost of control while improving mercury capture efficiency. New activated carbon sorbent
formulations that are designed to address higher sulfur applications will be tested this year.
Mineral-based sorbents are also under development and these sorbents are designed to address
concerns about the impact of sorbent on marketable coal combustion products. These new
sorbents are designed to work with the same PAC injection systems that utilities would install for
compliance with the IL rule. So, investments in hardware will not be wasted if utilities switch to
newer, improved sorbents that will likely be available in the future. Therefore, it is likely that in
2009 and beyond the mercury removal technology performance will be greater than it is now and
the cost will be less than what I have estimated with today’s state-of-the-art.
ELECTRONIC FILING, RECEIVED, CLERK'S OFFICE, MAY 23, 2006

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STATE OF ILLINOIS
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COUNTY OF SANGAMON
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CERTIFICATE OF SERVICE
I, the undersigned, an attorney, state that I have served electronically the attached
MOTION TO AMEND RULEMAKING PROPOSAL, MOTION FOR LEAVE TO FILE
INSTANTER AMENDED TESTIMONY OF JAMES E. STAUDT, Ph.D., and
AMENDED TESTIMONY OF JAMES E. STAUDT, Ph.D. upon the following person:
Dorothy Gunn
Clerk
Illinois Pollution Control Board
James R. Thompson Center
100 West Randolph St., Suite 11-500
Chicago, IL 60601-3218
and mailing it by first-class mail from Springfield, Illinois, with sufficient postage affixed
to the following persons:

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SEE ATTACHED SERVICE LIST
ILLINOIS ENVIRONMENTAL
PROTECTION AGENCY,
__________________________
Gina Roccaforte
Assistant Counsel
Division of Legal Counsel
Dated: May 23, 2006
1021 North Grand Avenue East
Springfield, Illinois 62794-9276
(217) 782-5544
ELECTRONIC FILING, RECEIVED, CLERK'S OFFICE, MAY 23, 2006

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SERVICE LIST 06-25
Marie Tipsord
Hearing Officer
Illinois Pollution Control Board
James R. Thompson Center
100 West Randolph St., Suite 11-500
Chicago, IL 60601-3218
James T. Harrington
David L. Rieser
McGuire Woods LLP
77 West Wacker, Suite 4100
Chicago, IL 60601
Bill S. Forcade
Jenner & Block LLP
One IBM Plaza
Chicago, IL 60611
William A. Murray
Special Assistant Corporation Counsel
Office of Public Utilities
800 East Monroe
Springfield, IL 62757
S. David Farris
Environmental, Health and Safety
Manager
Office of Public Utilities
City of Springfield
201 East Lake Shore Drive
Springfield, IL 62757
Faith E. Bugel
Howard A. Lerner
Meleah Geertsma
Environmental Law and Policy Center
35 East Wacker Drive
Suite 1300
Chicago, IL 60601
Keith I. Harley
Chicago Legal Clinic
205 West Monroe Street, 4th Floor
Chicago, IL 60606
Christopher W. Newcomb
Karaganis, White & Magel, Ltd.
414 North Orleans Street
Suite 810
Chicago, IL 60610
Katherine D. Hodge
N. LaDonna Driver
Hodge Dwyer Zeman
3150 Roland Avenue
Post Office Box 5776
Springfield, IL 62705-5776
Kathleen C. Bassi
Sheldon A. Zabel
Stephen J. Bonebrake
Joshua R. More
Glenna L. Gilbert
Schiff Hardin LLP
6600 Sears Tower
233 South Wacker Drive
Chicago, IL 60606
Bruce Nilles
Attorney
Sierra Club
214 N. Henry Street, Suite 203
Madison, WI 53703
Katherine M. Rahill
Jenner & Block LLP
One IBM Plaza
Chicago, IL 60611
ELECTRONIC FILING, RECEIVED, CLERK'S OFFICE, MAY 23, 2006

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