1
ILLINOIS POLLUTION CONTROL BOARD
June 16, 2006
2
IN THE MATTER OF
)
3
)
PROPOSED NEW 35 ILL ADM. CODE) R06-25
4
225 CONTROL OF EMISSIONS FROM) (Rulemaking - Air)
LARGE COMBUSTION SOURCES )
5
(MERCURY)
)
6
TESTIMONY OF DR. GERALD KEELER
7
PART II
8
BEFORE MARIE E. TIPSORD
HEARING OFFICER
9
10
The testimony of Dr. Gerald Keeler, a
witness called in the rulemaking proceeding before the
11
Illinois Pollution Control Board taken on June 16, 2006,
at 9:00 a.m., at the offices of the Environmental
12
Protection Agency, Springfield, Illinois, before Holly
A. Schmid, Notary Public and Certified Shorthand
13
Reporter, CSR No. 084-98-254587 for the State of
Illinois.
14
15
16
17
18
19
20
21
22
23
24
Page1
1
A P P E A R A N C E S
2
MEMBERS OF THE ILLINOIS POLLUTION CONTROL BOARD:
Ms. Marie E. Tipsord, Hearing Officer;
3
Dr. G. Tanner Girard, Board Member;
Ms. Andrea S. Moore, Board Member;
4
Mr. Anand Rao, Board Staff;
Mr. Thomas Johnson, Board Staff;
5
Mr. Tim Fox, Board Staff;
Mr. Nicholas Melas, Board Staff;
6
Ms. Alisa Liu, Board Staff.
7
COUNSEL FOR THE ILLINOIS
ENVIRONMENTAL PROTECTION AGENCY:
8
Mr. Charles Matoesian;
Ms. Gina Roccaforte;
9
Mr. John Kim;
Mr. Richard Ayres;
10
11
COUNSEL FROM SCHIFF-HARDEN
Ms. Kathleen Bassi;
12
Mr. Stephen Bonebrake;
Mr. Sheldon Zabel;
13
Mr. Jim Ingram, Dynegy, Inc.
14
COUNSEL FROM JENNER & BLOCK
15
Mr. Bill Forcade;
Ms. Katherine Rahill.
16
COUNSEL FROM McGUIRE-WOODS:
17
Mr. James Harrington;
Mr. David Rieser.
18
COUNSEL FROM THE CHICAGO LEGAL CLINIC
19
Mr. Keith I. Harley
20
COUNSEL FROM MIDWEST GENERATION
Mr. Basil G. Constantelos
21
22
23
24
Page2
1
2
3
IDENTIFICATION
PG.
4
Exhibit 29:
5
5
Exhibit 30:
5
6
Exhibit 31:
95
7
Exhibit 32:
130
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
Page3
1
MADAM HEARING OFFICER: Good morning,
2
everyone. Welcome back. This is day five, and we're
3
making some good progress.
4
My name is Maria Tipsord. I'm the
5
hearing officer in this proceeding in No. RO6-25. My
6
opening will be fairly truncated, since I don't see any
7
new faces.
8
I just want to introduce the panel to
9
you today. Board member Dr. G. Tanner Girard; Board
10
Member Anand Rao; the far right Nicholas Melas. To my
11
far left, Tom Johnson, also a board member. Our
12
technical unit today is represented by Anand Rao. Tim
13
Fox is with us again today, and Matt Reed is joining us
14
today with the board staff.
15
Before we go back to Dr. Keeler's
16
testimony, Mr. Rieser, I believe you were going to have
17
some exhibits for me this morning.
18
MR. RIESER: Why, yes, I do. We have
19
copies of the preliminary results of Steubenville. I'm
20
giving one to Mr. Harley, right off the bat, "The
21
Preliminary Results for Steubenville Mercury Deposition
22
Source Apportionment Study" from Tim Opelt, April 27,
23
2005. I don't recall what number you have that at.
24
MADAM HEARING OFFICER: We're going to
Page4
1
mark that as Exhibit 29, if there's no objection.
2
Seeing none, that will be Exhibit 29.
3
(Exhibit 29 was admitted.)
4
MR. RIESER: Then the second one is
5
"The Ambient Measurements to Support Coal Combustion
6
Emission Research" October 21, Beijing, China presented
7
by Matthew S. Landis, 2005. Again, we are presenting a
8
copy to Mr. Harley. We'll mark that as Exhibit No. 30,
9
if there's no objection. Seeing none, we will mark that
10
as Exhibit No. 30.
11
(Exhibit 30 was admitted.)
12
MS. BASSI: What was 29?
13
MADAM HEARING OFFICER: 29 is the
14
preliminary results. And "The Ambient Measurement" is
15
the title page on the second one. That will be Exhibit
16
30. Thirty is the Beijing study; 29 is the U.S. EPA
17
preliminary. Have we got the exhibits straightened out?
18
Has everybody got 29 and 30? I believe we are ready to
19
start with Question No. 10 for Dr. Keeler.
20
DR. KEELER: Question No. 10: "In
21
using the source-receptor approach to determine the
22
source of wet deposition mercury, is it accurate that
23
you determine the source by analyzing for other
24
constituents associated with those sources? A, does
Page5
1
that analysis demonstrate the proximity of those
2
sources? B: Does this analysis differentiate among
3
different types of coal used?" I assume you're asking
4
source receptor modeling approach not -- in using the
5
source-receptor approach.
6
MR. RIESER: Correct.
7
DR. KEELER: If you're referring to
8
the multivarious statistical analysis approach, it does
9
not demonstrate the proximity of the sources, so the
10
answer to A is no. If you're asking about the combined
11
hybrid receptor modeling approach, the answer is yes, so
12
just to differentiate --
13
MR. RIESER CONTINUES:
14
Q. Just for the record I note that the term
15
source-receptor study is the one that you used in your
16
testimony. For example, in this second paragraph of the
17
conclusion, we talked about, on page 5, that says,
18
"Source receptor studies have recently been completed
19
that indicate the coal-fired utilities contributed,
20
approximately, 70 percent of the mercury," so it wasn't
21
a term I made up. It was something that I thought I
22
took directly from your testimony.
23
A. Right. All the methods that we use are
24
looking for source-receptor relationships, and I was
Page6
1
just asking a clarifying question. That's all. It's a
2
correct use of the term.
3
Q. Thank you.
4
DR. KEELER: Question No. 11 -- just
5
so it's clear, B, the answer was no. "In your
6
testimony, you state that coal combustion was clearly
7
dominant, in terms of explaining the mercury deposition,
8
approximately, 70 percent. What is the basis for this
9
figure?" Do you want me to answer this again?
10
MR. RIESER: Yes, please.
11
DR. KEELER: This was the average of
12
the results of the PMF and the Unmixed models.
13
MR. RIESER CONTINUES:
14
Q. Of the two years, correct?
15
A. For the two years.
16
Q. 2003 and 2004?
17
A. Right, for the two-year combined analysis.
18
Q. There were differences in meteorology
19
between the two years, were there not?
20
A. Yes, there was. I said the deposition was
21
quite different between the two years.
22
Q. And in 2004, if I recall your testimony,
23
was dominated by four major precipitation events. Is
24
that correct?
Page7
1
A. Actually, I don't recall saying four, but
2
if that's what I said.
3
Q. I think you said "several" I'm sorry, but
4
it was dominated by several large precipitation events?
5
A. Yes, that's correct.
6
Q. And in what way was it dominated by those
7
events?
8
A. Those were very large deposition totals
9
relative to the total amount for the entire year.
10
Q. And what does that mean with respect to
11
your findings, if any?
12
A. Well, in one respect what it means is that
13
for a model, such as a deterministic model, if a missed
14
accurately calculating the deposition for that one
15
event, it will significantly alter their source-receptor
16
relationship and the ultimate approportionment of
17
whatever came from whatever source.
18
Q. I'm sorry. What does its mean for the
19
findings of the receptor study, the one you performed?
20
A. Not much. I mean, it's just another
21
example. I was highlighting the fact that it can have a
22
few single events that can lead to very large
23
deposition, and it's important in a sense of if one is
24
trying to compare the results of a CMAQ or TEAM, or that
Page8
1
type of a model to a receptor modeling that those single
2
events are very, very important, in terms of the overall
3
deposition to that location for the entire year, and so
4
not accurately predicting them is a major error, so that
5
was the purpose in my presentations and in my comment.
6
Q. Does it also suggest that source-receptor
7
done in a year with -- let me ask this, did you consider
8
-- and I do see in your testimony it's "a few large
9
precipitation events," I'm sorry. Is it your belief
10
that these large precipitation events were unusual with
11
the relationship to the typical weather in Steubenville?
12
A. They are not unusual in the sense that we
13
see these large events, typically at every site that we
14
measure. The sites in Michigan, the sites in Vermont,
15
the sites in Florida, we'll see a couple of very large
16
events that contribute a fairly large percentage of the
17
total deposition in all the sites that we make
18
measurements at.
19
Q. Is it accurate that several of these
20
precipitation events you observed in Steubenville were
21
results of hurricanes that came up from the Gulf of
22
Mexico?
23
A. Two of the events were the result of
24
cyclones that came up from the Gulf. They were the
Page9
1
remnants of hurricanes and provided very large amounts
2
of precipitation.
3
Q. Had you done the study in 2004, and only
4
had the 2004 data, would that have skewed the data
5
higher than the usual data that you would see for
6
Steubenville because of the large precipitation events?
7
A. No.
8
Q. In what way would it not?
9
A. It turns out that, for those large
10
precipitation events, the source-receptor model
11
underestimated the total deposition for those events,
12
and in fact, underestimates them quite a bit. Extreme
13
events in statistical analyses tend to be smoothed out,
14
so those couple big events, in terms of the deposition
15
-- they were over a microgram per square meter per event
16
-- were underestimated, and therefore, would not have
17
overestimated or given more of an emphasis to those
18
events.
19
Q. But you stated in your testimony that, at
20
least, one of those events added 8 percent of the total
21
mass of mercury to the amount of mercury observed for
22
the year 2004.
23
A. That's correct.
24
Q. And you don't consider that a significant
Page10
1
additional amount based on that one storm?
2
A. No. The point of my testimony was that it
3
does -- 8 percent is a significant additional amount,
4
but you asked the question whether that had a
5
significant impact on the results of our source-receptor
6
modeling, and I said no.
7
Q. I understand. I see where the four event
8
comes from. I'm sorry, Madam Hearing Officer. Which
9
was the Beijing?
10
MADAM HEARING OFFICER: The Beijing
11
study is 30?
12
MR. RIESER CONTINUES:
13
Q. Thank you. If you turn to Exhibit 30,
14
there is an "EPA PMF Estimated, versus Measured Mercury
15
Deposition."
16
A. Yes, I see that.
17
Q. And it's a graph comparing mercury
18
deposition in events, and there are four peaks, at
19
least, four large peaks that are larger than the other
20
peaks in that graph.
21
A. Correct.
22
Q. Do those represent the significant
23
precipitation events that you discussed?
24
A. Those are, yes.
Page11
1
Q. So would you agree that, in order for the
2
source-receptor -- excuse me -- receptor modeling to --
3
strike that. Let's go on to the next question.
4
DR. KEELER: "What range of values is
5
represented by this approximate value?" An approximate,
6
that is. I'm sorry. What did I say?
7
MR. RIESER: I thought I heard you say
8
an approximate.
9
DR. KEELER: "An approximate" it says.
10
I'm sorry, if I mumbled my words. The PMF and Unmixed
11
numbers, if I said I think PMF came out to be,
12
approximately, 70, might have been 69, and Unmix was 74,
13
and so that's where the number of, approximately, 70.
14
That wasn't meant to be a mathematically-rounded number,
15
by any means. It was supposed to be an approximation.
16
MR. RIESER CONTINUES:
17
Q. I asked this, I suppose, indeed, but is
18
there a plus or minus range associated with that?
19
A. Yeah. As I said yesterday, I believe the
20
uncertainty, if you do it the same way for both of the
21
models, is around 15 percent.
22
Q. Thank you.
23
DR. KEELER: The question is asking,
24
"What is the purpose of expressing this as an
Page12
1
approximate value?" For the purpose of simplicity, and I
2
have already answered what level of uncertainty to place
3
on this figure, which is the 15 percent. Question 12:
4
"You state that `a meteorological analysis corroborates
5
that a substantial amount of the mercury deposition
6
found at the Steubenville site was due to local and
7
regional sources."
8
MR. RIESER CONTINUES:
9
Q. Let me stop you. You use the term
10
"corroborate." What findings do you have, aside from
11
the meteorologic, that indicate a substantial amount of
12
mercury was due to local and regional sources?
13
A. Well, if one takes the emission
14
inventories for the region for mercury, and looks at the
15
amount of mercury and other constituents that are there,
16
one can then see that the largest contributor in the
17
emissions inventory in that region is actually
18
coal-fired utilities, so again, that's what I'm saying
19
is we, again, find that this matches up with what the
20
EPA emission inventory tells us.
21
Q. The emissions inventory is of emissions,
22
not deposition, correct?
23
A. It is emissions inventory. It's the
24
actual amount of emissions estimated from the source.
Page13
1
Q. So the emissions inventory doesn't, in and
2
of itself, tell you what the deposition is, does it?
3
A. No, it does not, unless you use a
4
deterministic model to model from emissions to
5
deposition?
6
Q. As I understand it, you did not use a
7
deterministic model?
8
A. No, I did not.
9
Q. And so in what way did you arrive at the
10
finding through your study that a substantial amount of
11
mercury deposition found at the Steubenville site was
12
due to local and regional sources?
13
A. When one does a source-receptor modeling,
14
one will often take the data, do the analysis, determine
15
an estimate of what a local source contributions and
16
regional source contributions are and then use the local
17
emissions inventory to what we call -- it's not a
18
validation. It's a comparison to the results that you
19
find. It doesn't make sense, in terms of what was
20
emitted in the region, to what you actually predicted.
21
This is a very common practice. It's done in a lot of
22
receptor modeling results. For example, if you estimate
23
that diesel emissions are an important emissions are
24
important and go to an area, and there are no diesel
Page14
1
trucks estimated to have emissions in that area, then
2
you find your results very unsatisfying.
3
Q. What is it about the emissions inventory
4
that allows you to make a qualitative statement with
5
respect to the deposition in the area, as you say, it's
6
a substantial amount that was due to local and regional
7
sources?
8
A. Are you asking me about the emissions
9
inventory?
10
Q. I'm asking you what about the emissions
11
inventory allows you to make the statement that a
12
substantial amount of mercury deposition found at the
13
Steubenville site was due to local and regional sources?
14
A. We have observational evidence that shows
15
us that, when we have high concentrations of reactive
16
mercury in the atmosphere, we would expect that to be
17
removed fairly close by precipitating systems. Taking
18
this understanding of the processes, one can then take
19
and use that understanding when looking at, okay, here
20
are emissions that are, to a large fraction, greater
21
than 50 percent as estimated by the utilities to a
22
common form of reactive mercury. When one goes and
23
looks at when and where the precipitation fell, one can
24
then make an estimate that this mercury would have been
Page15
1
removed through wet deposition in that area.
2
Q. How do you know what the amount of
3
reactive gaseous mercury is emitted by the sources
4
around Steubenville?
5
A. It's in the emissions inventory.
6
Q. The amount of reactive gaseous mercury is
7
in the inventory?
8
A. That's right. They provide an estimate of
9
the percentage of reactive mercury, particulate mercury
10
and elemental mercury that's emitted from each source.
11
Q. Did you do anything to -- the emissions
12
inventory is from 1999. Is that correct?
13
A. That's correct.
14
Q. Did you do anything to evaluate whether
15
that emissions inventory was still accurate as of the
16
time you did your study?
17
A. We only have the data that is presented to
18
us, so the answer would be no. There was no follow-up.
19
We can only use the information that is provided to us,
20
so the same information that all the modelers use.
21
Q. Could you have taken steps to -- strike
22
that. Put it this way, yesterday, when I asked you
23
about the sources that were nearby, you said that you
24
didn't know what they were, and you directed us to the
Page16
1
EPA map.
2
A. I don't think that's what I said, that I
3
didn't know what they were. You asked me how many,
4
specifically, and how much power was produced by the
5
plants, and I believe I answered I didn't have that
6
number in front of me.
7
Q. Did you have --
8
A. I know exactly where the sources are, not
9
just the coal-fired utility, but all of the other
10
sources in the vicinity.
11
Q. Did you have that number in front of you
12
when you performed your study?
13
A. We combine all the analysis tools that we
14
have including the emissions inventories, the maps
15
showing the locations of all the sites, how much of the
16
mercury is emitted from all those, and trying to
17
understand the results of our modeling, yes.
18
Q. Now, of course, we are limited in that we
19
don't actually have a copy of your study, but were there
20
maps showing the locations of the power plants, the coal
21
used, and then megawattage included as part or your
22
study?
23
A. The publication has a map showing all the
24
locations of the coal-fired utilities based on the 1990
Page17
1
information that was provided -- 1999, excuse me. I
2
misspoke. And I would have to go back and remember if
3
in the manuscript version that we submitted, whether it
4
had anything showing the actual amount of mercury that
5
was emitted from each stack. I don't recall that, but
6
it does show, geographically, where the plants were
7
located.
8
Q. So your report identifies specific power
9
plants as contributing to the mercury levels that you
10
observed in Steubenville. Is that correct?
11
A. No. As I mentioned yesterday, the
12
receptor modeling approach does not allow you to
13
identify a particular power plant. It identifies source
14
contributions from coal combustion.
15
Q. Then what was the point of including a map
16
of certain power plants in your study?
17
A. It's very important when you're publishing
18
any type of paper in international journals to show
19
people the location of where you are studying and the
20
major emissions sources in that vicinity. This is
21
common practice in the scientific literature.
22
Q. So the point was just to show the
23
location. Did you have other features, such as items of
24
historical interest in Steubenville?
Page18
1
A. This was a scientific peer-reviewed
2
literature paper. It's not a historical overview of the
3
area of Steubenville.
4
Q. I'm trying to understand why, if the point
5
of a receptor study, such as the one you performed, is
6
that it's not, A, can't use it to identify specific
7
sources, and B, it's not important to know what those
8
sources are, I'm trying to understand why you would
9
identify specific sources within the study, itself.
10
A. Again, you have misinterpreted and
11
misquoted what I said. A, I did not say it was not
12
important to know are the individual sources are. B, I
13
didn't say that individual sources are not important,
14
and I've been working in Eastern Ohio, Western
15
Pennsylvania air shed understanding the sources of, not
16
just mercury, but other compounds for over 20 years. I
17
have driven that area myself more hours than I can tell
18
you. I have spent an enormous amount of time on the
19
grown. I have actually gone around and photographed the
20
sources. Identified that, in fact, they were in the
21
locations that were given because, in the early days, we
22
were given locations for plants that actually didn't
23
coincide with where the plants were located, so we
24
actually went and verified that they were there, so I
Page19
1
have a long historical context, in terms of the research
2
I have been doing in that area. I published my first
3
source receptor paper on aerosols and their sources in
4
the Southwestern Pennsylvania area in 1986, so this is
5
not something that is new to me, and I think, from over
6
20 years worth of scientific experience, I believe I
7
have a good sense for what information is important to
8
provide in a scientific peer-reviewed paper and what's
9
not, and so I'm not sure why you keep saying I'm
10
referring to these things as being unimportant.
11
Q. Well, in your testimony, on page four, in
12
the paragraph that begins, "Multivariant statistical
13
receptor models have been successfully used to apportion
14
sources of mercury deposited in South Florida and
15
elsewhere." What you say after that in the next
16
sentence is, "These techniques have the advantage of not
17
requiring prior measurements of source profiles or
18
emission inventories." Similarly, in your report, which
19
is attached as Exhibit B, and I believe it's on page 18,
20
again, in a paragraph that begins with the statement,
21
"Regarding multivariant statistical receptor models,"
22
there's a sentence right before the end of the paragraph
23
that says, "Again, both techniques referring to
24
statistical techniques such as Unmix and deposit matrix
Page20
1
factorization, both techniques have the advantage of not
2
requiring prior measurements and source profiles or
3
emission inventories." So since you identify an
4
important, positive point that it doesn't require -- the
5
studies you performed don't require emissions
6
inventories, I'm having trouble understanding what role
7
they have to play in the findings that you make, and
8
obviously, I'm hampered that I don't have the actual
9
report in front of me.
10
A. I will try to say it again in a different
11
way, so perhaps it's more clear. Receptor modeling
12
allows you to estimate the source contributions by
13
source category for the pollutants that you're looking
14
at. It does not identify the specific stack or source,
15
a specific company that emitted the pollutant. You
16
asked the question about corroboration, and this is how
17
we got into discussing emissions and emissions
18
inventories, what we call "source reconciliation." If
19
one does a receptor modeling study, one that comes to
20
mind is one Glenn Kass did in the early 70's looking at
21
the sources in the Los Angeles Basin. He was looking at
22
the source of L and L carbon (phonetic) and basically,
23
did a receptor modeling very similar to what we done in
24
this study, and estimated the contributions to L and L
Page21
1
carbon and then went, as a corroborating piece of
2
information, took the inventory that estimated, from a
3
source perspective, how much carbon came from all the
4
sources in LA to see if he could get an approximate
5
balance. What goes up, has to come down. If you
6
estimate an overabundance of material that you can't
7
corroborate with observations or with emissions
8
estimates, then it gives you some idea that the
9
emissions are not correct or that there are other
10
sources contributing that perhaps the emission inventory
11
didn't conclude, so this is a standard practice in the
12
field, but it does not require -- receptor modeling does
13
not require the use of emissions data.
14
Q. Did you quantify the amount of mercury
15
deposition that you expected to find in Steubenville
16
based on the emissions inventory?
17
A. No, sir.
18
Q. In what way did the review of the
19
emissions inventory, then, corroborate the finding that
20
a substantial amount of mercury deposition found at the
21
Steubenville site was due to local and regional sources?
22
MADAM HEARING OFFICER: With all due
23
respect, I think that's where this all started. I think
24
he answered that question in the beginning.
Page22
1
MR. RIESER: Well, I'm really limited
2
here because I don't think he did answer the question.
3
He said he looked at the inventory and that supported
4
the finding that a substantial amount of mercury
5
deposition found at the Steubenville site was due to
6
local and regional studies because that finding is
7
corroborated by other information I have to assume
8
that's a finding, and again, I don't have the report in
9
front of me.
10
MADAM HEARING OFFICER: You have made
11
that point several times this morning, as well.
12
MR. RIESER: Right, but the point
13
being says he looked at the emissions inventory. We
14
don't know what plants he looked at. We don't know what
15
particular things he found. We don't know whether this
16
was a qualitative or quantitative finding of his.
17
MADAM HEARING OFFICER: I understand
18
that, but he has also repeatedly stated that the
19
receptor modeling does not look at individual plants.
20
It looks at a source category. Am I characterizing that
21
correctly?
22
DR. KEELER: Correct.
23
MR. MATOESIAN: Yes, and he's answered
24
that several times, category of sources you can trace
Page23
1
back to.
2
MR. RIESER: Thank you.
3
DR. KEELER: Just for the record, I
4
did state that we use the emissions inventory from the
5
1999 modeling that EPA did, the same inventory that was
6
used in the CAMR Rule, and we looked at all the
7
emissions for the entire Midwest, and actually, for all
8
the entire Eastern United States, so --
9
MR. RIESER:
10
Q. What I would like, then, is a list of the
11
plants that Dr. Keeler identified as being the plants
12
that he looked at the inventory for to identify the
13
amount of mercury that corroborated this finding.
14
A. It's the entire list that's in the CAMR
15
Rule, so if you want the entire listing, you can get
16
that on the EPA website.
17
MADAM HEARING OFFICER: Once again,
18
Dr. Keeler, when you start telling us to get stuff, that
19
means the Agency needs to provide it to us, if you have
20
not already. We need that as an exhibit.
21
MR. RIESER CONTINUES:
22
Q. I'm sorry, the entire list of all power
23
plants in the country?
24
A. That's the list we used and we looked at
Page24
1
the plants east of the Mississippi.
2
Q. Did you look at a specific range of plants
3
for this study, all the plants in the Mississippi --
4
A. We did not look at specific plants, as I
5
said earlier. We looked at the region.
6
Q. Well, I'm --
7
A. We didn't identify -- we did not identify
8
individual plant contributions that are in the receptor
9
modeling, or in terms of trying to understand the
10
contribution of a particular plant. That's not in the
11
scope of the work that we did.
12
MR. RIESER: I don't think it's unfair
13
to ask what plants, to get a list of the plants.
14
MADAM HEARING OFFICER: I have already
15
asked them.
16
MR. RIESER: I'm hearing "region" and
17
"list." I'm not hearing, "I looked at these plants,"
18
and I'm assuming there is a list.
19
MR. MATOESIAN: He stated this --
20
MR. RIESER: I'm not done talking.
21
I'm assuming there is a list of plants that he looked at
22
because he describes, "We looked at these RGM's, and we
23
calculated the RGM's with the" -- blah, blah blah, and
24
that's what we need to corroborate, the meteorological
Page25
1
findings, so I would like a list of those plants.
2
MR. MATOESIAN: I believe you directed
3
us to provide that and as he stated, it was a list of
4
plants east of the Mississippi, I believe.
5
DR. KEELER: Right.
6
MS. BASSI CONTINUES:
7
Q. Sorry to jump into this fray, but please
8
correct me if I'm wrong, and that's my question. I
9
thought, at one point, you said that, in your
10
manuscript, or in your published data, or some place,
11
there was a map on which you identified the plants that
12
were in the region or in the vicinity or in the local
13
area, or however you defined it, but it sounded to me as
14
if you were saying that there were certain power plants,
15
perhaps, other types of sources that were on a map
16
around the Steubenville area that is plotted on a map
17
that you have identified as dots on a map. Is that
18
correct?
19
A. That's correct. In the submitted version
20
of the paper we submitted, a figure, which had a copy --
21
I mean had a spot showing the location of the
22
Steubenville site, and then had within -- I would say it
23
showed the greater Steubenville area, including most of
24
Ohio, half of Pennsylvania, down to the south of it, up
Page26
1
to the north. It didn't include a large area. It was
2
really meant to show where Steubenville is, but it did
3
include a point showing a major source of mercury from
4
the `99 inventory plotted on that.
5
Q. Then somehow that got expanded to the
6
entire emissions inventory used in the CAMR?
7
A. Because there are two different questions.
8
One was asking a question about figures, and one was
9
asking what we look at when we look at the emissions,
10
and I was trying to be clear about that.
11
Q. So when you looked at the emissions to
12
corroborate your findings from your study, you were
13
looking at more than just what was plotted on your map.
14
Is that correct?
15
A. That is correct.
16
MR. ZABEL CONTINUES:
17
Q. Maybe this is obvious, but it seems to me
18
we have been dancing around the question of why we can't
19
get a copy of the draft report.
20
A. It's not a report. It's a manuscript that
21
was submitted to a scientific journal that's in the
22
review process. We've already been given reviews, and
23
we're in the process of finalizing that paper. The
24
paper will be provided to everyone, once the paper is
Page27
1
sent for publication. One other thing that is very
2
difficult today, especially when doing environmental
3
research, is to maintain the integrity of the scientific
4
research publication process, and one of the reasons why
5
we didn't want to make presentations and do briefings in
6
front of the EPA, until we had our final analysis was
7
because these results, then, get misinterpreted. People
8
that don't do scientific research often don't understand
9
the process that science is -- you learn as you go. You
10
make corrections and improvements to the scientific
11
research that you are doing, and that, at times, if you
12
don't have the data that you would like at hand, you get
13
that data, and people provide new data. You submit your
14
information and you refine your analysis, and if
15
versions of publications are going around prior to you
16
actually submitting it to the peer-reviewed literature,
17
then the whole process becomes -- basically, the
18
integrity of the process disappears.
19
Q. I'm sorry. My question wasn't answered.
20
A. I'm saying that this hearing has come at a
21
time where the paper has not come out in press, yet, so
22
that's the reason why the paper hasn't been provided.
23
Q. I perfectly understand that. I want to
24
know is there some legal reason why we cannot have that
Page28
1
document as it exists today? They are asking this Board
2
to rely on what you're saying is in that paper. We have
3
no chance to judge that. If I were in litigation, I
4
could get it in Discovery. I could order it produced.
5
They want this Board to rely on what Dr. Keeler is
6
telling us. I have no reason to think he's not telling
7
us the truth, but I can't check it. I don't know of a
8
legal reason -- if there is one, counsel can tell me --
9
why we can't have copy of that draft.
10
MADAM HEARING OFFICER: I actually
11
believe that yesterday Dr. Keeler invoked intellectual
12
property.
13
MR. ZABEL: Then he can have it under
14
confidentiality. We won't publish it. That's not the
15
point.
16
DR. KEELER: I'm not sure how to
17
answer you. I just know that I know that, in terms of
18
the scientific peer review process, this is not
19
appropriate and --
20
DR. GIRARD: Could I ask a question.
21
You say it's been reviewed. Have you already submitted
22
the revised paper to the journal?
23
DR. KEELER: No, we have not. It's --
24
right now it's under going, again, another level of
Page29
1
review at the Agency, so it's not a finalized document,
2
yet, and that's the main reason why -- if I hadn't
3
submitted the final version, I would have no problem
4
with sharing that, but again, this is -- it's one of
5
these thing that it's just not done this way.
6
MR. RAO: And based on the comments
7
you have received from this peer-review committee, does
8
it change your results or conclusions in any way?
9
DR. KEELER: No, it does not.
10
MS. MOORE: Is the peer view committee
11
looking at it now within the EPA?
12
DR. KEELER: Yes. It's an internal
13
review.
14
MS. MOORE: Given the fact that your
15
findings are U.S. EPA excuse me -- are a little
16
different than the direction that the U.S. EPA has
17
thought to go in regard to mercury, don't you think
18
there would be some chance that the release of this
19
paper might be held for some period of time for further
20
and further and further peer review?
21
DR. KEELER: I don't believe they,
22
legally, can hold up the publication. I'm the one that
23
has to then make a determination that, okay, we are not
24
going to wait anymore, so we have a deadline of July 1
Page30
1
to return the final version of the paper to the Journal,
2
and so that's the drop dead deadline for all of their
3
discussions and review, no matter what, in my mind.
4
MS. MOORE: So July 1 it would
5
actually be available?
6
DR. KEELER: That should be -- that's
7
correct. It should be available around the July 1 time
8
frame.
9
MS. MOORE: It would be pretty clear
10
to you then if there were some other reason they didn't
11
want to release it, not that that kind of thing would
12
ever happen.
13
MS. BASSI: Certainly not in Illinois.
14
DR. KEELER: I think that's correct.
15
MR. ZABEL CONTINUES:
16
Q. Is my understanding correct, Doctor,
17
that's the version you would be willing to release, the
18
July 1 version?
19
A. The version that we will submit as a final
20
version to the Journal will be the one I'm happy to
21
share.
22
Q. Then I guess my only inquiry would be
23
whether we can have Dr. Keeler back after our experts
24
have had a chance to study that.
Page31
1
A. It all depends on when.
2
MR. RIESER: It would be my
3
suggestion, frankly, that, if it's going to be released
4
by July 1, it would be my suggestion we just halt the
5
cross-examination here --
6
MADAM HEARING OFFICER: We're not
7
going to halt the cross-examination because, if it
8
doesn't happen July 1, and we're right here arguing
9
about whether or not the Steubenville study is going to
10
be issued. We're -- we'll continue on.
11
Here's what I'm going to do. I'm
12
going to direct the Agency to provide a copy of the
13
Steubenville report no later than July 5. If it can't
14
be available by July 5, then I will be willing to hear
15
motions at that point.
16
MR. ZABEL: I will have a motion at
17
that point, Madam Hearing Officer.
18
MADAM HEARING OFFICER: I just want to
19
put it off, in case we can get to --
20
MR. ZABEL: I will reserve my motion,
21
until the end of the Fourth of July holiday.
22
DR. KEELER: Can I just make one
23
point? I'm not going to be in town -- I'm actually going
24
to be in the field, until about July 10, so I'm not
Page32
1
going to be dealing with this at all. I told you July
2
1, just so that you would know that that's when we have
3
to do it, but I'm not going to be in town to be able to
4
do anything in regards to this, until I get back on
5
about July 10. I think I get back to town late on July
6
9, so putting a date of July 5 is not going to work for
7
me. I'm just telling you. I have other commitments
8
that I have made previously. This hearing got postponed
9
from May, to now, and I had to cancel two different
10
trips that I had planned for June in order to be here
11
this week, and I can't cancel any more in the future
12
because it involves field work, and I have contracts
13
that are obligating me to be in the field.
14
MR. RIESER: We're just asking for the
15
report, not you.
16
DR. KEELER: But if EPA responds back
17
to me with whatever the final comments and all that kind
18
of stuff very late in the game -- I'm hoping I get it
19
before that, so I can get this taken care of, but if
20
they get it back to me June 30 or something like that,
21
I'm going to have a really hard time in dealing with
22
that. I don't know what will happen. That's out of my
23
hands.
24
MR. ZABEL: Madam Hearing Officer, I
Page33
1
will make my motion, regardless. I understand his
2
difficulty. I'm giving up most of Father's Day with my
3
children because of this hearing on Monday, so I'm
4
sympathetic doctor, but at some point, we need the
5
evidence in the record, and if it isn't there, I will
6
make my motion.
7
DR. GIRARD: One problem we have got
8
is that we have already got partial -- we have partial
9
information in the record now, which you already said is
10
not final. It seems to me that really need to talk with
11
your attorneys to see if it is possible to put a draft
12
copy, as it is now, in the record. There's no way it's
13
going to be released for publication. We take trade
14
secrets all the time in cases, so you need to talk with
15
your attorneys. I think it would short circuit some of
16
this questions by three or four hours, if you could
17
simply look at what methods were used, and a lot of
18
these questions go to procedures. They don't go to
19
results at all. So I think you need to go talk with
20
your attorneys.
21
(At which point, a break was taken.)
22
MADAM HEARING OFFICER: Back on the
23
record.
24
MR. MATOESIAN: In response to the
Page34
1
question of -- on the question of Dr. Keeler's report,
2
we're going to have to talk to the U.S. EPA about
3
whether it can be released and what portion, so we
4
cannot today commit to the July 5 date. We are going to
5
reach out to them, and hopefully, get an answer by early
6
next week, Monday, perhaps Tuesday. Then give you a
7
more definitive answer then. That's the best we can do
8
at this point.
9
MADAM HEARING OFFICER: Mr. Zabel.
10
MR. ZABEL: May I add to my request
11
then that we also, if we receive anything, receive the
12
200 pages or thereabouts of commentary that Dr. Keeler
13
indicated he received from U.S. EPA? You are going to
14
be talking to U.S. EPA, so you might as well talk to
15
them about both.
16
MR. MATOESIAN: We will bring that
17
issue up, as well, to them.
18
MR. RIESER: One other item, which I
19
asked for yesterday, was if the LADCO presentation could
20
be provided and I think Dr. Keeler said he would look
21
for it.
22
DR. KEELER: It's being photocopied as
23
we speak I believe.
24
MR. RIESER: Great. Thank you.
Page35
1
MADAM HEARING OFFICER: At this point,
2
then, we will move on with the cross-examination of
3
Dr. Keeler, and we will address issues considering the
4
availability or unavailability of the Steubenville study
5
published report at a later date.
6
MR. RIESER: I think we are on 12-A.
7
DR. KEELER: 12-A: "In your
8
testimony, how do you define "local" and "regional"
9
sources?" I believe I answered that previously. We had
10
an extended discussion about that yesterday, so that's
11
been answered. B: "Are the sources described in this
12
state limited to coal-burning sources?" No, they are
13
not.
14
DR. RIESER CONTINUES:
15
Q. What other sources are?
16
A. I believe I answered this yesterday, as
17
well. Iron and steel production, municipal waste
18
incineration, refining, metals production I think were
19
the sources that I mentioned yesterday. C: "Is the
20
deposition" --
21
Q. I'm sorry --
22
A. "Limited to wet deposition?"
23
Q. I'm sorry, one question on that. In
24
identifying where the sources -- were the sources you
Page36
1
identified as a result of the receptor sampling and
2
modeling or as a result of the review of the emissions
3
inventory?
4
A. Only the receptor modeling.
5
Q. Thank you.
6
DR. KEELER: C, "Is the deposition
7
described here limited to wet deposition?" The source
8
apportionment results receptor modeling performed were
9
only including the wet deposition?
10
MR. HARLEY CONTINUES:
11
Q. Dr. Keeler, mindful of the fact that the
12
source apportionment was based on wet deposition, on
13
days when it didn't rain, when there was only dry
14
deposition, do you have an opinion about how that might
15
have effected the results of the work that you did at
16
Steubenville?
17
A. As part of this overall project, we will
18
be looking at, both, wet and dry deposition. Again,
19
this was the first paper that we attempted to get into
20
the scientific journal, the wet deposition took
21
precedence. The dry deposition work is ongoing, and
22
it's going to be based on the extensive on-site
23
meteorological measurements, as well as the reactive
24
gaseous mercury, particulate mercury, and elemental
Page37
1
mercury measurements that we're actually making on site.
2
We have, at this time, not modelled the deposition using
3
the ambient data. However, based on our past projects,
4
we would assume -- not one would assume. The dry
5
deposition component should be a significant additional
6
loading of mercury to this ecosystem. In our studies in
7
Detroit, where we were in areas with similar source
8
contributions, or similar source densities, the portions
9
of dry deposition was -- well, the dry deposition that
10
was about half of the overall deposition that we saw at
11
the site at Steubenville was different in terms of the
12
mix of sources than Detroit is, so we expect to see some
13
different contributions, and so forth, but dry
14
deposition is half the story we believe, and in an area
15
with lots of sources, dry deposition could dominate the
16
local deposition to this area.
17
Q. To be clear, that would be added to what
18
you have already presented in your testimony about
19
deposition through precipitation?
20
A. Yeah. The wet deposition -- just to be
21
clear, the wet deposition that we modelled and think
22
that 70 percent of which is coming from coal-fired
23
utilities, is only about half of the total deposition,
24
so mercury enters the waterbody by wet deposition, and
Page38
1
then there is a whole other amount of mercury that
2
enters through mercury that's in the air, basically,
3
interacting with the surface and falling to that
4
surface, so at this point, we haven't really apportioned
5
half of the total deposition, which is again, part of
6
the goal, but that's further down the road.
7
Q. Based on previous work that you have done,
8
would you reasonably expect that the utility
9
contribution to dry deposition would be present in the
10
same proportion as it is for wet deposition?
11
A. The importance of wet, versus dry, can
12
vary from one spot to another, but based on, again, past
13
experience, I would expect that the sources that are
14
within the 50-mile radius of Steubenville will have a
15
major importance, in terms of the dry deposition and
16
influence in the ambient levels of mercury in the air at
17
Steubenville.
18
CROSS EXAMINATION BY MR. HARRINGTON:
19
Q. I don't believe you answered the question
20
as to whether utilities would have the same impact on
21
dry as wet deposition. Could you comment on that
22
further, please?
23
A. I can't give you a quantitative answer to
24
be specific on that. I would expect them to be a
Page39
1
significant contributor to the dry deposition. I
2
cannot, because I have not done that analysis, give you
3
a quantitative number what percentage of dry deposition
4
to coal-fired power plants is.
5
Q. Do things such as steel mills, metal
6
working refineries have potentially and proportionate
7
greater impact on dry deposition?
8
A. We're talking about dry deposition of
9
mercury, right?
10
Q. Dry deposition of mercury in Steubenville.
11
Keep it within the context of --
12
A. Again, local sources, if they are closer
13
to the site and have different forms of mercury that
14
they are emitting, would have a different contribution
15
than coal-fired utilities would, yes.
16
Q. Thank you.
17
MR. RIESER CONTINUES:
18
Q. And during the 2003-2004 sampling, did you
19
measure dry deposition in Steubenville?
20
A. We did not measure continuously for the
21
2003-2004 time period a direct measurement of dry
22
deposition that's analogous to what we did for wet
23
deposition. What we have done and what we plan to do to
24
provide that estimate is to use ambient concentrations
Page40
1
of mercury that have been measured, so we have
2
continuous measurements of reactive gaseous mercury,
3
elemental mercury, particulate mercury that are
4
performed on an hourly time basis together with the
5
onsite meteorological data, and we will model the dry
6
deposition quantity to the surface at the Steubenville
7
site. As part of intensive periods, we have direct
8
measurements of mercury of dry deposition using
9
surrogate surfaces, and other techniques, which all of
10
these techniques have uncertainties, so we compare those
11
measurements together with models to come up with a best
12
estimate for dry deposition of mercury in Steubenville,
13
but again, that analysis is not completed.
14
MR. HARLEY CONTINUES:
15
Q. In talking about the conduct of your
16
ongoing research, you testified yesterday that you have
17
assembled, but not compiled data for wet deposition for
18
the year 2005. Is that correct?
19
A. The database is not finalized. We haven't
20
compiled all of the trace element data and mercury data
21
and ion data at this point.
22
Q. Based on your firsthand review of the data
23
as it now exists, do you have an opinion as to whether
24
or not the information from 2005 is consistent with what
Page41
1
you saw in 2004, 2003, or is it just too early?
2
A. We haven't done any source apportionment
3
modeling on the 2005 data at all because the data is not
4
completed. The total amount of mercury deposition in
5
Steubenville in 2005 which is the data that is done I
6
don't have the exact number in front of me, but it's
7
greater than the average. It's more than 2003, and I
8
think less than 2004, so it's in the same vicinity.
9
MR. BONEBRAKE CONTINUES:
10
Q. Is the relative proportion of different
11
species of mercury deposited different in wet
12
deposition, as opposed to dry deposition?
13
A. The answer to that question -- I'm going
14
to try to simplify it. The reactive gaseous mercury
15
forms and the particulate mercury forms are the ones
16
that will most readily go into precipitation. When we
17
analyze our samples for our precipitation samples for
18
these species we see a very wide range in how much
19
reactive particulate is there and part of that is
20
because the reactions occur in the precipitation sample,
21
itself, giving us somewhat an uncertain answer as to how
22
much particulate was there, in the first place.
23
Reactive mercury is also going to dominate the dry
24
deposition because of its properties. It has a very
Page42
1
high deposition velocity, and so similar to wet
2
deposition, reactive mercury is going to dominate in wet
3
deposition, and also going to dominate in dry
4
deposition, so in the absence of precipitation, you
5
would expect do see a fairly rapid depreciation of the
6
reactive mercury to the surface similarly as if it was
7
going into cloud water, so I would expect reactive
8
mercury to dominate, both, the wet and the dry. The one
9
part, the dry deposition, that is less well understood,
10
and is not included in the models, and the models that I
11
have reviewed in the current literature is the uptake of
12
elemental mercury by force canopies and into the plant
13
materials. This form of mercury and this deposition
14
loss is something that's not characterized well, but
15
it's a significant amount of mercury on an annual basis.
16
It can be as much as three times the wet deposition to a
17
forested ecosystem. It's not a simple answer.
18
Q. The deposition -- the mercury uptake in
19
the forest canopy that you just mentioned, would you
20
anticipate that that ultimately ends up in the
21
environment, and if so, what portion of the environment,
22
aside from the trees, themselves?
23
A. Well, what we've quantified thus far is
24
the mercury that's taken up in deciduous leaves and
Page43
1
confer needles and so forth in the forest canopy. That
2
material, at least, for the deciduous trees -- every
3
fall, that material drops from the trees and falls to
4
the forest floor, so mercury gets bound up in the
5
organic matter and that material is bound to decompose
6
like the other plant material and start working through
7
the process of weathering and so forth, go into the
8
soils, and some of it will run off, depending on the
9
ecosystem structure, so it's a delayed signal, in terms
10
of deposition to the forest canopy uptake through the
11
growing season, deposition and then a slow process where
12
it will then slowly make its way to the ecosystem.
13
MR. ZABEL CONTINUES:
14
Q. Just for my benefit, Doctor, you mentioned
15
in discussing dry deposition the use of surrogate
16
surfaces. Explain to me what that is or what that
17
means.
18
A. Sure. One of difficulties in making
19
measurements of the deposition of any pollutant, whether
20
it's mercury or sulfur or any pollutant that's in the
21
atmosphere, is that the surface of the earth is complex.
22
Trees present a very complex surface in an urban area,
23
buildings and roads and sidewalks, all those surfaces
24
are very complex, in terms of the surface area, the
Page44
1
composition, how they move, how the wind and meteorology
2
influences those, and so we can't make a replicate of a
3
building and stick it up and then somehow wash the
4
building down to get how much pollutant was deposited
5
into that building, so we come up with a surrogate,
6
something what we hope will mimic the surface, so we use
7
a variety of different surfaces, and when we do this, we
8
try to provide surfaces that have properties that won't
9
artificially enhance the deposition, so there are other
10
dynamic surfaces. Sometimes we will use a water surface
11
if we are trying to look at and estimate the amount of
12
mercury that's deposited into the Great Lakes, for
13
example. If we're trying to assimilate the deposition
14
to a specific type of surface, we would put that
15
material on a small aerodynamic surface and actually
16
measure how much deposits to that, and then to verify
17
that we're getting reasonable results, we actually then
18
use models to estimate how much mercury deposited to
19
that small surface, and then use an understanding of the
20
landscape and some of the information that we can get
21
from a remote sense to tell us about how the landscapes
22
change and the proportion of different types of trees
23
and vegetation and plants and so forth to come up with a
24
larger estimate of the deposition.
Page45
1
Q. So in doing that, you use multiple
2
surrogates, I take it, for different types of surfaces?
3
A. We use more than one type of surrogate
4
surface, that's correct.
5
MADAM HEARING OFFICER: Anything else?
6
Moving on to D, I believe.
7
DR. KEELER: D: "What meteorological
8
analysis was performed to demonstrate this statement?"
9
We used a combination of meteorological analysis tools
10
to perform the meteorological interpretation for this
11
project. This included detailed plotting analysis of
12
surface and upper air meteorological maps, backward air
13
mass trajectories, NEX-RAD precipitation data sets,
14
together with statistical techniques, such as cluster
15
analysis to institute meteorological influences on the
16
deposition.
17
MR. RIESER CONTINUES:
18
Q. If you look at Exhibit 29, which is the
19
Beijing, China, Landis Report, there are -- there's a
20
page after the page we looked at before called "Hy-split
21
Back Trajectories."
22
A. Yes. That's what I was referring to in my
23
statement.
24
Q. So these are two examples of the back
Page46
1
trajectory?
2
MADAM HEARING OFFICER: Point of
3
clarification, the Beijing study is Exhibit 30. 29 is
4
the preliminary results. That's right. 30 is the
5
Beijing study.
6
MR. RIESER CONTINUES:
7
Q. I had two identical exhibits. Sorry about
8
that. Exhibit 30. Doctor, you're there. "Hy-split
9
Back Trajectories."
10
A. Yes.
11
Q. So these are examples of the type of work
12
that you would do?
13
A. These are examples of one of the tools
14
that I listed there. These are the -- as I said, the
15
backward air mass trajectories.
16
Q. What information do using these as
17
examples -- what information do these provide to you?
18
A. If you look at these plots, these plots,
19
basically, the trajectories are calculated to correspond
20
to the maximum hour of the precipitation for a couple of
21
the precipitation results we received in Steubenville,
22
and these black lines represent the center of
23
probability of mass that air would have had thought
24
going backwards from Steubenville and where the air mass
Page47
1
would have come from moving backwards in time and I
2
think it's six-hour increments, and that's what those
3
little stars are.
4
Q. The stars are six-hour increments?
5
A. I believe so, yes. That's going back 72
6
hours. These are three-day back trajectories.
7
Q. Then there are graphs below these that are
8
on the side that says "HPA." Would you tell us what
9
these rep?
10
A. Yes. The bottom plots HPA is a unit of
11
pressure, and so this gives us a vertical slice looking
12
up in the atmosphere of the height that the air mass was
13
predicted to be at, so again, if you start at
14
Steubenville, or to the right, looking at the first here
15
moving backwards in time, it shows that our site was at
16
the surface, and then the air mass actually came moving
17
backwards in time, and went up into the atmosphere a
18
little bit into the higher into the mix layer and then
19
up as it went backwards and slowly came down again.
20
Q. Did these examples -- again, do these also
21
represent the difficulty in identifying the proximity of
22
regional source because the three days' time travelled
23
put you pretty far away from Steubenville? Can you be
24
more specific about the difficulties you had to -- why
Page48
1
do you select three days? Let me ask that.
2
A. For the purposes of this demonstration,
3
three days was selected because, when you start going
4
back further, you actually have missing data in the data
5
streams, and you wind up actually having the model
6
condition calculate very often, so we use three days
7
because, as part of that the original analysis we did
8
back in the late 80's looking at some of the utility
9
acid precipitation data, we found that three days
10
represented some synoptic meteorological conditions very
11
well, and that going further -- actually, the
12
uncertainty in the trajectory calculation was back much
13
more than three days which was so great to make them
14
unreliable.
15
Q. Looking up, again, at the specific
16
question of 12, "Meteorologic analysis corroborates that
17
a substantial amount of the mercury deposition found at
18
the Steubenville site was due to local and regional
19
sources," would the local and regional sources be
20
sources that contribute mercury emissions to the
21
atmosphere or all along the lines of these back
22
trajectories?
23
A. The line here, again, is meant to
24
represent the most probable path, so as you move
Page49
1
backwards in time, the path that actually the air mass
2
could have taken actually grows wider, so if you were to
3
take and draw an increasing, like, wedge of air moving
4
backwards in time, it actually encompasses a larger area
5
than what's shown by just this line. This is just a
6
representation, and so what we do then is to use this as
7
a guide, and then take the surface and upper air
8
meteorological maps together with the NEX-RAD to help
9
this in terms of guiding us in terms of the timing for
10
how quickly the air mass has moved, where the
11
precipitation fell along this trajectory, and what
12
sources could have fallen into this kind of large area
13
that surrounds this line that you see here, and so you
14
put that all together and together with the known source
15
locations to be able to then say, "Here's the sphere
16
that we think has contributed to the deposition at that
17
point."
18
Q. When you -- tell us what "NEX-RAD" is, I'm
19
sorry.
20
A. NEX-RAD is the weather radar that you see
21
presented on the television. It's the nice way to show
22
the storms for Springfield, show the nice, heavy
23
thunderstorms that come through in different colors, so
24
it's next-generation radar is what it stands for.
Page50
1
Q. So going back to your description of this
2
you describe sort of a -- since I'm used to ground water
3
what I will call an inverse plume where it spreads out
4
from the back and focuses in at the front end. Is that
5
an apt description?
6
A. I'm not a ground water person, but plume
7
is okay.
8
Q. So back to that question, would it be in
9
the way you did the study that all of the sources that
10
you identify within this area, looking at this first map
11
on the left, which starts at, essentially, the Rio
12
Grand, all the sources within that area leading up to
13
Steubenville would be included in your analysis of the
14
mercury emissions that fall at Steubenville?
15
A. We will utilize going as far back as the
16
trajectory would tell us for the three days. We
17
actually look at the meteorological numbers for the
18
entire country when we are doing this, but we would look
19
at and investigate any potential influences that would
20
occur along that entire path.
21
Q. So when you talk about local -- we had an
22
extended discussion yesterday I understand about local
23
and regional sources and things like that, and you were
24
-- again, correct me if I'm mistaken -- but you were
Page51
1
concerned that the local and regional as the proximity
2
issue was problematic because, in your mind, it really
3
wasn't meteorologic?
4
A. That's correct.
5
Q. The meteorology that's described in this
6
first plot, the one on the left on this Exhibit 30,
7
would suggest that the mercury that's being contributed
8
into Steubenville that you measured came from sources
9
along this line and then spread out as far as the data
10
shows that the air mass moved. Is that correct?
11
A. I believe what you're trying to convey is
12
correct.
13
Q. Is it, again, looking at this map, is it
14
the assumption that you're going back three days because
15
that's an understanding of what's useful data? Is that
16
the way to say that? After three days it gets mushy?
17
A. Yes.
18
Q. It doesn't really tell you anything. Do
19
you have any assumption, and I asked this yesterday, but
20
there is a good graphical representation of it. Do you
21
have any assumptions that any amount of mercury comes
22
into this back end that you have got at the Rio Grand in
23
looking at how much mercury is being deposited in
24
Steubenville?
Page52
1
A. Again, let me see if I understand what
2
you're asking me. This line, or whatever, that goes
3
back toward the Rio Grand here, we don't add up
4
emissions along that line or suggest that emissions
5
are -- that's not included in our analysis. There are
6
no assumptions in terms of the analysis. What we would
7
do is we would take and look at the entire upwind
8
history of this precipitation event. One tool to look
9
at where the air mass came from would be this line, and
10
along this line we would look at things, such as did it
11
rain? What was the precipitation rate moving backwards
12
i time along this line, and what we found is that, by
13
using precipitation, you can look to see whether the
14
probability that the pollutant would be removed is
15
greater in times when precipitation along these back
16
trajectories is high or not, so we look at the storms,
17
and in this case, this one that's for May 8, it turned
18
out that the air mass actually wasn't moving very fast.
19
If you look at those stars there, there are a few stars
20
very close to Steubenville, so the air mass was not
21
moving very fast. In fact, those first four or five
22
stars there reflect the meteorological situation at the
23
time, which basically, had a storm which stalled out in
24
that area, so the storm was a big storm. Things didn't
Page53
1
move very quickly and the precipitation would have been
2
washing out all of the reactive mercury, and all of the
3
other very reactive pollutants from the atmosphere and
4
cleaning things up for a very long time, so that the air
5
masses that could have contributed to the loading that
6
was occurring through that storm couldn't come from very
7
far, and so this is how we do that type of analysis, and
8
one can take and model that specific storm and compare
9
that against using observations because there are no
10
assumptions in the observations. It's meteorological
11
data that we have and we don't look at a line underneath
12
the map. We actually look at the whole area, and we,
13
basically, say, from this, we know that we had a very
14
slow-moving air mass that took a long time for it to
15
actually go anywhere, so we are talking about emissions
16
that were in the vicinity of the Steubenville area. The
17
ones that were coming from Southern Ohio that were --
18
the emissions sources were, basically, emitting up into
19
that area, and then that storm was staying there, and it
20
was precipitating out for an extended period of time, so
21
that the air mass, by the time it got up towards,
22
Steubenville had already been washed out. The air that
23
was in that storm had already had a great deal of
24
removal and cleansing, just to put it in simple terms,
Page54
1
so the highest probability of where the air masses that
2
fed the clouds could have come from had to have been in
3
that general vicinity. Again, I'm saying Southern Ohio,
4
Northern Kentucky, that general area, based on the
5
service meteorological data our on site, data as well as
6
using this as a tool. When you start talking about
7
meteorological analysis and showing maps and so forth,
8
everyone turns off and goes to sleep in your talk, but
9
when you show a trajectory plot, people get the idea
10
that the air started down somewhere in Texas and that's
11
the path that it took before it got to Ohio, so it's
12
simplification for presentation purposes, but by no
13
means is it what we use as the definitive answer because
14
there's very complex three-dimensional flows that occur
15
in the atmosphere, and one has to take those into
16
account, as well, when one is looking at what potential
17
source areas could have contributed.
18
Q. So that description is what tells you that
19
the mercury deposited in Steubenville came from the
20
specific area you described, Southern Ohio, Kentucky,
21
and not from, say, Houston, which is more or less passed
22
-- is that correct?
23
A. Yes, in simple terms.
24
Q. In doing that analysis, do you have to
Page55
1
take into account the atmospheric chemistry in
2
transformations of mercury in the atmosphere?
3
A. We do rely on our understanding of the
4
reactivity of mercury and the chemistry of mercury in
5
order to be able to look at what distance scales we
6
think things could take place on. However, there are no
7
assumptions made. We use what our best available
8
understanding is based on, both, our observation data
9
that we have taken, both, at Steubenville and at our
10
Michigan sites, together with what is published in the
11
literature.
12
Q. And is that understanding -- you use the
13
term "understanding." Is that correct?
14
A. I believe that's what I said, yes.
15
Q. Is that understanding different than the
16
atmospheric transformation of mercury which are
17
described in the deterministic models?
18
A. That would depend upon the specific
19
deterministic model. This gets to the whole question
20
that I raised yesterday about the uncertainties in the
21
models.
22
Q. Let's use CMAQ to narrow it down?
23
A. CMAQ -- the version of CMAQ that EPA uses
24
has a very simplistic atmospheric chemistry for mercury.
Page56
1
There are lots of issues in that chemistry. It does not
2
include all the relevant reactions that we understand
3
today. It doesn't include the most up-to-date reaction
4
rates, so I would say no. We rely upon more than that.
5
Q. And have you published or is there another
6
paper published paper that you rely on that identifies
7
the atmospheric transformation reactions that you rely
8
on in doing your work?
9
A. We have papers. We have a paper that we
10
have submitted to -- see, we have a paper that we
11
submitted to a peer-reviewed scientific journal that
12
details some of our deterministic modeling, which is not
13
at all what was done here, but that's not really
14
relevant to the situation, but it incorporates some of
15
the mercury chemistry that we rely on. I mean, some of
16
these chemical reactions and updating the atmospheric
17
chemistry happened very rapidly. I was just in Russia
18
at a mercury meeting a long-range transport mercury
19
meeting in Moscow and learned of some new reactions that
20
had just come out, so we rely upon, both, what our
21
colleagues tell us at meetings, as well as what the
22
peer-reviewed literature has. I don't write down, and I
23
don't have, like, a publication where I have listed all
24
the atmospheric chemistry that I rely on. I rely on
Page57
1
what's in the peer-reviewed literature.
2
Q. I guess what the bottom line of what I'm
3
trying to get at is what Sheldon would say is, is there
4
a way that we can see how you describe the atmospheric
5
transformation reactions? I assume there is some type
6
of mathematical equation or part of your model or
7
something that another person can look at and apply in a
8
similar setting and test.
9
A. We don't use chemical reactions in our
10
modeling. I stated yesterday that the receptor modeling
11
does not use chemical reactions. We only used observed
12
information.
13
Q. Then I completely misunderstood because I
14
thought you said that, in evaluating where mercury came
15
from, you made certain judgments, decisions about the
16
atmospheric chemistry that mercury undergoes.
17
A. What we use as our understanding that
18
reactive mercury is removed very easily with
19
precipitation, which we have published and have
20
observations that show this, and that elemental mercury
21
is not removed as rapid, so again, this is based on
22
observation of published work, and in understanding the
23
information, we have an idea of how long reactive
24
mercury would last in the atmosphere based on almost
Page58
1
instantaneous removal in precipitating systems. That's
2
the atmosphere chemistry that I'm referring to is that
3
there are different chemical properties of mercury forms
4
that may get removed at different time scales.
5
Q. Do you have a numeric rate that you use to
6
evaluate the removal of reactive gaseous mercury?
7
A. No, sir.
8
Q. When you say it's rapidly removed, what's
9
the quantification of rapidly?
10
A. Well, we have hourly data, and you will
11
see within an hour time frame a very rapid, so within an
12
hour time frame, we see a significant -- more than 50
13
percent -- removal of the mercury within one hour of the
14
onset of precipitation.
15
Q. When you talking about that data, what
16
you're talking about is the data at your wet deposition
17
sampling locations, correct?
18
A. That's correct.
19
Q. So the storm begins at five o'clock. At
20
5:15, you have a sample that's got a lot of mercury in
21
it. At 6:15, there's no mercury, just --
22
A. The reactive mercury would have dropped,
23
that's right.
24
Q. And what does that -- but is it correct
Page59
1
that you use that data to make decisions as to how much
2
reactive gaseous mercury is in the air mass that's
3
moving into Steubenville?
4
A. No. There's no assumption there.
5
Q. So how do you know how much mercury is in
6
the air mass that's moving into Steubenville or where
7
it's from?
8
A. We have on-site measurements of the
9
reactive mercury at the site. There's no assumption.
10
That is my point.
11
Q. What does it tell you -- what does that
12
data tell you about -- well, step back. That's why
13
you're not in position to identify the proximity of the
14
sources based on the samples that you do at
15
Steubenville, correct?
16
A. We have not done a detailed source
17
apportionment of the ambient mercury at Steubenville,
18
yet. What we have done at this point is look to see
19
specific episodes when we have high reactive and
20
particulate mercury to see what the meteorological
21
conditions were like and where the air was coming from
22
based on on-site meteorological measurements, as well as
23
other meteorological data, such as the trajectories, to
24
see if there is a strong association, so whether we see
Page60
1
repeated pattern of things like high sulfur dioxide,
2
high reactive mercury, high nitrous oxide, high CO,
3
whatever the on-site measurements we have, high
4
particulates, and then we analyze the particulates for
5
there elemental composition, as well, so we can look for
6
the same tracers in the air as we see in the
7
precipitation, and that analysis has not been completed,
8
yet, because we collect four samples a day. That would
9
collect them for -- well, we're on our third year now,
10
and it's thousands of samples that we are in the process
11
of analyzing, so that analysis and information will
12
come. We do see strong relationships that winds that
13
flow from the south, southwest with higher mercury
14
levels and higher S02 (phonetic) concentrations that are
15
indicative of transport from fossil-fuel-burning plants
16
from coal-burning plants.
17
Q. What tells you that those are fossil
18
burning plants, again, looking at this first map as an
19
example in Kentucky, Ohio River Valley and not Houston?
20
A. Well, we have an idea of the location of
21
where the fossil-fuel-burning facilities are, where all
22
the sources are, and then we can look along that swath
23
that we think where the air could have possibly come
24
from, and we look at the inventory to tell us what the
Page61
1
possible sources could have been. It's an aid, not as a
2
quantitative tool.
3
Q. Then you have to make -- then you have to
4
evaluate whether precipitation events have washed out
5
mercury that could come from other sources along that
6
line. Is that correct?
7
A. That's right. It's something I have been
8
working on for more than 20 years, so in my best expert
9
judgment, I have done this for multiple pollutants,
10
including mercury, and I feel like I have a very good
11
handle on this situation, and on this type of analysis.
12
Q. If there was an example where there was an
13
air mass moving into Steubenville, and there was no rain
14
fall events going on along the line back to Texas, what
15
would the results of Steubenville look like?
16
A. You know, I would have to go and look to
17
see if we had those type of events in order for me to be
18
able to predict because you can draw the same line
19
moving from Steubenville to Texas, and depending upon
20
the winds, how strong the winds were, and at all those
21
segments, what the atmosphere was like, the stability of
22
the atmosphere along the trajectory, the temperature
23
profile, all these different meteorological parameters
24
would affect disbursion, the chemistry, the transport,
Page62
1
and the dry deposition that occurred along that
2
trajectory. One of the things that, if one was to take
3
and estimate how much mercury you would expect left in
4
an air mass that was submitted to Texas, by the time it
5
got to Steubenville, one can take and estimate how much
6
you would have expected to have loss from dry
7
deposition, how much you might expected to have lost
8
from chemical reactions, and just by the air mass being
9
deluded as you got there and when you get that far back
10
in time, there's very small contribution that you would
11
see in Steubenville from sources way back in Texas, but
12
that's a general comment. I would have to look at
13
specific information to give you a quantitative answer.
14
Q. In doing that estimate that you just
15
described, one of the factors would be the atmosphere
16
transformation that mercury undergoes --
17
A. Yes.
18
Q. -- during that time of travel?
19
A. Yes, sir.
20
MR. HARLEY CONTINUES:
21
Q. The May 8 event that you described on your
22
hy-split trajectory, is that one of the days during that
23
year where there was an event that precipitation led to
24
a significant deposition of mercury in Steubenville?
Page63
1
A. Yeah. That was one of the four largest
2
events depositing. Again, I think I've given a figure
3
of maybe the four largest or the several largest, as
4
much as 8 percent of the annual total, so these are
5
significant events that occurred at this site.
6
Q. In the two-year period of 2003, 2004, how
7
many total mercury rains have there been on Steubenville
8
comparable to the event on May 8 where we have
9
hyperloading of mercury on Steubenville?
10
A. Gee, I don't have that in front of me. My
11
memory is that we had in the two-year period about eight
12
events that were greater than .6 micrograms per meter
13
squared I believe, which that's a big event. And then a
14
couple that were greater than one, and again, if you are
15
looking at 10 to 20 micrograms per square meter at a
16
year at a site, if you get more than one in one rain
17
event, that's a significant contribution in that one
18
day.
19
Q. There was one other question I had. The
20
CMAQ model, you gave some reasons why the CMAQ model is
21
it not as precise as the receptor-based approach that
22
you used in Steubenville. One question I had about the
23
CMAQ model is you said the CMAQ model underestimated
24
mercury loading in Steubenville by comparison to the
Page64
1
results of the work that you have done. Is that
2
correct?
3
A. Yeah. Just to qualify, the CMAQ for 2001
4
is where they calculated that 43 percent was coming from
5
coal-fired utility boilers. Our data is from 2003,
6
2004, we did have the opportunity to compare our
7
Michigan network sites for the 2001 year, together with
8
our estimated for Vermont, and the CMAQ model
9
underestimated the deposition that we measured at our
10
Michigan sites and at the Vermont site for 2001. It was
11
off by a factor of two at one site, as I recall, so it
12
grossly underestimated the total deposition at our sites
13
that we had measuring in 2001. The way you phrased it,
14
"CMAQ being less precise" I think the way I would rather
15
phrase it is that these type of models are more
16
uncertain, that there are more parameters and processes
17
that are poorly defined in these models, which make
18
their uncertainties greater and the conclusions drawn
19
from those models much greater than I would say that
20
they are from the receptor modeling. That's a correct
21
statement.
22
Q. Is the CMAQ model a model which accounts
23
for, both, wet and dry deposition of mercury?
24
A. Yes, it does.
Page65
1
Q. And is it fair to characterize your
2
testimony as indicating that, in the Steubenville
3
situation, your modeling of wet deposition alone was
4
greater than the CMAQ model of, both, wet and dry
5
deposition at that site?
6
A. My memory tells me that CMAQ actually
7
estimated a greater dry deposition at Steubenville than
8
it did for wet deposition for the 2001 year, so no, our
9
wet deposition wasn't greater than the CMAQ's total. I
10
believe the CMAQ total was around 30 micrograms per
11
square meter, or 34. It's hard to tell from the
12
modeling because they do it in colors with ranges, but
13
that, again, I'm just going from my memory of what Russ
14
Bullock presented, but I believe that that's true, that
15
the dry deposition was greater in this area than the wet
16
deposition was. Using the CMAQ model, not from our
17
observations.
18
MR. BONEBRAKE CONTINUES:
19
Q. On the May 8 back trajectory, a line, is
20
that, essentially, indicative of a wind direction from
21
the southwest?
22
A. Yeah. The line that starts at
23
Steubenville or the line that starts at the site there
24
on the border of Pennsylvania and Ohio, if you follow
Page66
1
that backwards towards the bottom of the left page that
2
is trying to illustrate the most likely path that an air
3
mass took before it got to Steubenville.
4
Q. In this particular case, through Texas and
5
Louisiana, the air mass was moving from the southwest
6
and northeast?
7
A. That's correct, southwest.
8
Q. Yesterday we talked a little about wind
9
directions in Illinois. My understanding from your
10
testimony was that, in the winter season in Illinois,
11
the wind direction is frequently from the northwest. Is
12
that correct?
13
A. Yeah. The Great Lakes region, as a whole,
14
has a higher frequency of winds from the north,
15
northwest during the wintertime as a result of synoptic
16
meteorological conditions.
17
Q. And during the summer months, are winds in
18
the state of Illinois most typically from the southwest?
19
A. From the data I looked at for O'Hare, it
20
appears as if the south is the dominant winds with
21
south, southwest being one of the more frequent wind
22
directions, but knowing that westerly winds are also the
23
dominant wind areas during the summer.
24
Q. Would O'Hare's -- would the direction of
Page67
1
wind at O'Hare be impacted by Lake Michigan?
2
A. Yes.
3
Q. So would the data from O'Hare, in your
4
view, be representative of the rest of the state of
5
Illinois?
6
A. No. If you look at wind measurements made
7
in Southern Illinois, you see a slight variation in that
8
overall pattern. You might have slightly more winds
9
from the south than you would at O'Hare, so the winds
10
will change slightly. The dominant wind direction still
11
is going to be west with a southerly component being
12
strongest.
13
Q. With respect to the northwest portion of
14
the state of Illinois, would you expect, then, that
15
during the winter months the predominant wind direction
16
would be from the northwest and then the summer months
17
it would be from the southwest?
18
A. South, southwest. From what I have seen
19
for -- and again, I haven't looked at a climatological
20
average, but that's about right.
21
Q. What would you view, Dr. Keeler, to be the
22
states which contain upwind sources of mercury with
23
respect to the state of Illinois?
24
A. Again, taking what you said in terms of
Page68
1
the dominant wind directions, you would have the states
2
of Missouri, Iowa, and farther to the west would be
3
upwind of Illinois, and then the states to the south,
4
Kentucky, Tennessee, Louisiana, Alabama.
5
Q. Would Texas also be in that list?
6
A. Texas would be in that list, as well.
7
Q. One other question for you, Dr. Keeler.
8
You mentioned in response to a question from Mr. Harley
9
that you had done, as I understand it, a comparison of
10
CMAQ predictions to Michigan deposition data that you
11
had available to you. Is that correct?
12
A. Yes.
13
Q. Is that comparison in a published article?
14
A. No, it's not.
15
Q. Is that comparison publicly available?
16
A. You know, is it in Dr. Landis' briefing?
17
MADAM HEARING OFFICER: Exhibit 30,
18
Beijing Exhibit 30, yes.
19
DR. KEELER: It says, "Comparison of
20
CMAQ Model Versus" --
21
Q. Back toward the end of the document.
22
MADAM HEARING OFFICER: Yeah,
23
two-thirds back he said. "Comparison of CMAQ Model
24
versus UMAQL Measured Mercury Wet Deposition Testimony."
Page69
1
MR. BONEBRAKE CONTINUES:
2
Q. Is that correct, Dr. Keeler, that's the
3
page you're on?
4
A. Yes, and refers to the left column to
5
Dexter, Michigan.
6
Q. Helston, Michigan?
7
A. That's correct.
8
Q. Both, the CMAQ predictions and the
9
deposition data that you were using in the comparison
10
were both from 2001?
11
A. Yes, sir. These numbers were provided to
12
Dr. Landis I believe by Russ Bullock of U.S. EPA, and
13
these are the actual data that went into the CAMR
14
modeling.
15
Q. Is there a discussion of this comparison
16
in the study that's been at issue today in terms of
17
what --
18
A. No. This is an additional analysis. The
19
Michigan site data is not included in the Ohio paper.
20
Q. Other than what's in this particular page,
21
has the comparison or the bases of the comparison
22
otherwise been made publicly available?
23
A. All of the Michigan data for 2001 is in
24
peer-reviewed publications and the CMAQ model results
Page70
1
are in the public docket that was filed by IEPA.
2
Q. So --
3
A. So it's all public.
4
Q. From your perspective, then, someone could
5
take the publicly-available information in those
6
documents and repeat the comparison?
7
A. Yes, sir.
8
MR. ZABEL CONTINUES:
9
Q. Earlier I think you said, in doing the
10
corroboration using a Michigan inventory, you looked at
11
sources east of the Mississippi. Is that correct?.
12
A. I said that was the area that we focused
13
on, yes.
14
Q. You didn't use, for a particular
15
corroboration, also sources east of the Mississippi?
16
A. Again, for trying to speak generally to be
17
inclusive of all the work that we did for a particular
18
event, we would use our understanding of the
19
meteorologic and transport for a particular period, such
20
as the May 8 period, where we would focus on those
21
sources, and sources that were to the southwest, for
22
example, in the most highest probable transport area, so
23
we wouldn't be then taking out the list of sources from
24
Minnesota and Wisconsin at that time to look at -- in
Page71
1
order to think about the May 8 event. On another day
2
where the flow came from those directions, we would look
3
at another set of sources that would help us interpret
4
that specific day. We didn't limit our analysis to a
5
number of sources. We had the entire -- plotted all of
6
the sources plotted in 1999 EPA database together with a
7
list of all those sources and the estimated fraction of
8
mercury emitted from each source in each fraction as a
9
tool to guide us in terms of our interpretation.
10
Q. That was sort of the point of my question,
11
and the May 8 is a good example. There's some subset of
12
sources east of the Mississippi you would have used in
13
looking at emission inventories for them?
14
A. Again, we would have focused on the
15
sources in the states which we thought had a probability
16
of contributing on a specific day for a specific event.
17
Q. Just to make this perfectly clear to me,
18
there are coal-fired plants in Tampa Bay in Florida.
19
They would not have been included, would they, in your
20
May 8 analysis?
21
A. I would say that I did not look at Tampa
22
Bay power plants on interpretation of the May 8.
23
Q. On that May 8 one, both, Louisiana and
24
Texas I believe are west of the Mississippi, were they
Page72
1
not?
2
A. That would be a geographically-correct
3
answer.
4
Q. And in fact, Minnesota -- for instance, if
5
you're looking in the other direction, although I
6
understand Minnesota has a dispute on which side of the
7
Mississippi they are in, at least, part of it is west of
8
the Mississippi, is it not?
9
A. Yes, it is. In my use of east of the
10
Mississippi and west of the Mississippi, I was trying to
11
give a general division line, but as I mentioned
12
earlier, I was not trying to distinguish an absolute
13
line of demarcation for any of the analysis.
14
Q. Well, then in the May 8 case, would you
15
have looked at cases in Louisiana and Texas?
16
A. We would have looked at sources along that
17
trajectory, yes, or in that area that would be indicated
18
by that air mass trajectory, yes.
19
Q. In answer to one of the questions I
20
understand that cone gets wider the far away from
21
Steubenville you get?
22
A. That's right. So sources all the way up
23
from Kansas to Atlanta, Atlanta area, Georgia would also
24
have been considered in looking in the backward upwind
Page73
1
path.
2
Q. Most of Texas, I take it, at that point?
3
A. Yes.
4
Q. Thank you.
5
MADAM HEARING OFFICER: Anything
6
further? I believe 12-E --
7
MR. RIESER CONTINUES:
8
Q. This will actually address some of the
9
questions, but since Mr. Harley brought up the
10
comparison of CMAQ and the receptor modeling, it's
11
correct, isn't it, that CMAQ in your type of receptors
12
study are designed to achieve two different results. Is
13
that correct? It's designed for two different purposes.
14
Is that correct?
15
A. How a model is used is defined by the user
16
and so in my case, which I can attest to, we were using
17
receptor models to calculate how much mercury was
18
deposited via wet deposition from the major source
19
categories for the period of 2003-2004. So that
20
apportionment to source categories was our objective,
21
and that's where we did the modeling. Why EPA did the
22
CMAQ modeling for 2001? As I understand, it was to
23
estimate the contributions from all the major sources to
24
the deposition of mercury across the entire United
Page74
1
States, so by definition, it has a broader purpose, and
2
was not looking at one site. It was not looking at just
3
wet deposition. It looked at wet, dry, and ambient, so
4
yes, they have -- they have different purposes, but to
5
say CMAQ model has one purpose and the type modeling we
6
did had only one purpose, it really depends on what the
7
user was using that model for.
8
Q. The CMAQ model, among its utilities, is
9
that it can be used for predictions. Isn't that
10
correct?
11
A. Yes, sir.
12
Q. So you can use it to decide what would
13
happen, as an example reflected in Exhibit 30, "Utility
14
zero out," of what mercury deposition would look like if
15
there were no utility emissions?
16
A. Yeah. I believe, like you said, in
17
Exhibit 30, I believe that map included a couple special
18
plots. Maybe I'm wrong.
19
Q. You're correct. There is a CMAQ simulated
20
total mercury deposition for 2001 and underneath it
21
says, "Utility zero out," and prior to that, there's a
22
base case CMAQ simulated total mercury for 2001 base
23
case, so as we said, you can use CMAQ to, as an example,
24
take out all of the utility emissions and see what
Page75
1
things look like?
2
A. Correct.
3
Q. Can you use your model to do that?
4
A. The receptor model, by definition, does
5
not have a predictive capability.
6
Q. So if I -- well, let me ask you, if you
7
assumed that the coal-fired power plants, within a 50
8
kilometer range of Steubenville, ceased to operate,
9
would you have any conclusion as to what that would do
10
to the mercury deposition in Steubenville?
11
A. Based on our work, what I would say is
12
that if the coal-fired utilities, regardless of
13
location, stopped emitting, so they were zeroed out, we
14
would see close to a 70 percent reduction in the mercury
15
deposition that we measured at Steubenville.
16
Q. Could that conclusion, in making that
17
statement, what you were referring to are not the
18
coal-fired utilities within a 50 kilometer distance from
19
Steubenville, but all coal-fired utilities in the United
20
States?
21
A. We -- again, based on our analysis, our
22
meteorological analysis, we will consider sources that
23
were beyond regional, so very long range sources, so
24
ones that are the western part of the United States
Page76
1
would contribute very little to that total and part of
2
that is backed up by just looking at the deposition data
3
that's in the Western United States, which is very low.
4
It's for around four micrograms per square meter, so I
5
would say that it's the sources in the eastern United
6
States coal-fired utilities in the Eastern United States
7
which are contributing that 70 percent, and if those
8
were reduced, we would see that commensurate drop in the
9
mercury deposition at that site for those years that we
10
modelled.
11
Q. But you wouldn't be able to use your
12
receptor model to determine what would happen at
13
Steubenville if, for example, all the power plants in
14
the state of Ohio reduced mercury emissions by 70
15
percent?
16
A. No. The model is not capable of
17
predicting calculations.
18
MADAM HEARING OFFICER: Are we ready,
19
then -- I believe we have answered 12-E and I think
20
perhaps 12-F already. In the discussion we had this
21
morning, E is, "Does the analysis differentiate between
22
sources located at different distances?" and we have had
23
substantial discussion about --
24
MR. RIESER: Correct, yes.
Page77
1
MADAM HEARING OFFICER: F is, "Have
2
you quantified the substantial amount as used in this
3
statement?"
4
MR. RIESER: I was looking at the
5
wrong number, yes, correct.
6
MADAM HEARING OFFICER: And we
7
answered 13-A and B yesterday, so 13-C.
8
DR. KEELER: I actually believe I
9
answered this one as well. "Are they fired with
10
bituminous or sub-bituminous coal?" Again, in the
11
complete listing of the emissions sources and the EPA
12
inventory, it lists the type of coal burned. I believe
13
there is a mix of plants that burn, both, bituminous and
14
sub-bituminous. Some are all sub-bituminous and some
15
are -- a few that are bituminous, so there's a
16
combination. D: "Does the chemical profile of
17
bituminous as opposed to sub-bituminous affect the
18
amount and type of mercury emitted by a coal-burning
19
generating unit?" Again, I believe I answered this
20
yesterday in saying that I'm not an expert on control,
21
and so perhaps, an expert for the State will provide --
22
later will talk about how various control will affect
23
the emissions, but clearly, the type of coal burned will
24
have an influence on the type of type and form of
Page78
1
mercury, in respect to whether it's reactive mercury or
2
gaseous mercury or particulate mercury and we talked
3
about the importance of chlorine and fly ash content and
4
iron and others things in the coal that would cause
5
those differences. E: "Would you expect a different
6
result at Steubenville if the surrounding units burned
7
sub-bituminous coal?" I don't have the ability to
8
provide an answer to that question. I don't understand
9
exactly what you are asking. I assume that the power
10
plants in the area are not -- from an inventory, some do
11
burn sub-bituminous coal, so I'm not sure if you are
12
asking me if all the plants in the Steubenville area
13
burn sub-bituminous but I see --
14
Q. I am asking, if all the power plants
15
surrounding Steubenville burn sub-bituminous coal, would
16
you expect a different result?
17
A. Again, I guess I'm not prepared to answer
18
that question. I think I would have to have more
19
understanding of how changing to a different coal type
20
for the various types of controls that are used in that
21
area would affect speciation and I'm not prepared to
22
answer that.
23
MADAM HEARING OFFICER: And I believe
24
you have answered 13-F, as well, whether airborne
Page79
1
sources of mercury are located within 50 miles.
2
DR. KEELER: So G: "In what way, if
3
any, are the conditions at Steubenville analogous to the
4
conditions in Illinois?"
5
MR. RIESER: To be honest, there was
6
some movement in that answer, so if we get too
7
repetitive, cut us off, but I would like to go through
8
this because I heard two different things, to be honest.
9
MR. KIM: Could you clarify what you
10
mean because Dr. Keeler did describe the distinctions in
11
terms of meteorological conditions and so forth and I
12
recall him going into something about topography. Were
13
you wanting something beyond that, something different?
14
MR. RIESER: What we're looking for is
15
whether the findings with respect to Steubenville are
16
analogous to Illinois, and some of that discussion has
17
to do with things that were discussed and things weren't
18
discussed. I heard, on the one side, Steubenville was
19
typical, but in some ways, it's obviously atypical due
20
to the amount of power plants that are around, so I
21
think we need to walk through each of the features and
22
talk about them.
23
MR. KIM: There again, I'm just for my
24
sake just trying to get it clear. You said, "What we
Page80
1
want to know is whether the finding at Steubenville are
2
analogous to Illinois." When you say the findings at
3
Steubenville are analogous, you have to be comparing
4
that to some findings in Illinois, I assume, so are you
5
referring to something specific, or are you saying can
6
the findings in Steubenville be transferred to Illinois?
7
MR. RIESER: I'm assuming this
8
testimony he has presented had some meaning to the Board
9
as far as what the study means and the decisions they
10
should make with respect to Illinois, so I do think we
11
have to decide how applicable these findings are to
12
Illinois.
13
MR. KIM: I agree. The only reason
14
I'm saying that is he's already provided testimony that
15
he believed the findings could be applied, not only to
16
Illinois, but to other locales, once you take individual
17
variances into account. With this question on its own
18
is read, it seems like you are referring to something
19
specific, some kind of fact-specific situation or --
20
MR. RIESER: I'm happy to break it
21
down if the question, itself, is not clear. I'm happy
22
to break it down and go through each of the issues that
23
I had in mind and maybe that will take care.
24
MR. KIM: Let's do that.
Page81
1
MR. AYRES: I thought we had a
2
discussion that went for, at least, a half an hour.
3
MR. KIM: I think, if you break it
4
down, my guess is some of that stuff has already been
5
answered, but if you want to break it down, that's fine.
6
MR. AYRES: There was a discussion
7
that was very fact specific, and then we talked about
8
the transferability of the learning, if you will, from
9
Steubenville. Do you recall that?
10
MR. RIESER: I recall that and my
11
problem is my recollection is -- my recollection is that
12
the answer wasn't clear. There are, obviously, some
13
informational issues that are portable and Steubenville
14
was a very specific place that has the conditions that
15
are represented because of conditions that are specific
16
to Steubenville.
17
MR. KIM: Sure.
18
MR. RIESER: Seriously, I think we
19
could have got through this pretty quickly.
20
MR. KIM: I wanted to be clear.
21
MR. RIESER CONTINUES:
22
Q. I honestly don't mean to belabor the
23
point, but I just don't think it was clear on the
24
record. Let me ask, Steubenville is in a river valley.
Page82
1
Is that correct?
2
A. The city of Steubenville has part of its
3
boundaries that fall in the Ohio River Valley, that's
4
correct.
5
Q. Was the sampling location in the part of
6
Steubenville that was in the River Valley?
7
A. You get down to, I think, definitions. I
8
think, technically, that whole area is in the Ohio River
9
Valley, but just to be clear, in terms of topography,
10
the site was not down on the river in the valley. It
11
was actually up on top of the area that then flattens
12
out going to the west in Ohio, so it was not down in the
13
valley where local sources would have inundated the data
14
that we were getting. It was actually up on top, and I
15
think, like, 400 feet above the river, to be clear.
16
Q. Is the meteorology of the Ohio River
17
Valley, as you have described it, different than the
18
meteorology one would typically see in Springfield,
19
Illinois?
20
MR. KIM: I think this has been
21
answered. I think he went through an extended
22
discussion about meteorological distinctions between
23
Steubenville and other parts of any other part of the
24
country. I think his specific testimony was you are not
Page83
1
going to find that replicated anywhere, but
2
Steubenville.
3
MR. RIESER CONTINUES:
4
Q. Is that your testimony?
5
A. I think what I said yesterday was that the
6
conditions at Steubenville, in terms of the overall
7
source-receptor relationships, which meteorology is a
8
part of, are specific, to a point, and that those would
9
be unique to Steubenville. The question is whether the
10
conditions in Steubenville make it anomalous, or somehow
11
unique where the results would not be transferable to
12
somewhere else in Ohio, somewhere else in the Great
13
Lakes or in Illinois and I would suggest that the
14
conditions are not unique or anomalous to make them so
15
they are not usable or transferable to conditions that
16
we would have in Illinois.
17
Q. What are the conditions that are not
18
anomalous?
19
A. The weather in Ohio, just as it is in
20
Indiana, Illinois, Michigan, Minnesota, Wisconsin, are
21
all controlled by synoptic meteorology, which is the
22
large scale movement of the highest and low pressure
23
systems across the Great Lakes, so unlike some places
24
where they have some dominant feature, such as Bermuda
Page84
1
high, which may dominate the weather in a certain
2
location, that might make it different than another one.
3
The Great Lakes, themselves, are dominated by synoptic
4
meteorological transport, and therefore, as long as
5
you're taking into account the specific meteorology that
6
occurs at that spot, it's not going to be all that much
7
different. The controlling factors are not that much
8
different for Illinois than Ohio.
9
Q. Do the presence of a large number of power
10
plants surrounding Steubenville, does that factor make
11
it anomalous to other locations?
12
A. Again, I think I said this before, but I
13
believe that the high density of power plants in the
14
Steubenville area is a prime reason why power plants are
15
a prime contributor to the extremely high deposition
16
that we see there. However, in another place which
17
would have a similar density, I believe you would see a
18
similar result.
19
Q. So to see a similar result, you would need
20
a similar density of power plants?
21
A. You could get similar amounts of
22
deposition different ways, but if you want to ensure
23
that you saw elevated, like, 70 percent contribution of
24
the power plants, you would need to have a significant
Page85
1
emissions, upwind emissions, in the local vicinity.
2
Again, the upwind vicinity, to be clear, of the receptor
3
model or the receptor site.
4
Q. When you use "upwind vicinity" in that
5
sentence, what, specifically, do you mean?
6
A. The greater region.
7
Q. What is "the greater region"?
8
A. The local and regional area surrounding
9
the receptor.
10
Q. The local and regional areas we defined --
11
A. Previously.
12
MR. ZABEL CONTINUES:
13
Q. Dr. Keeler, what is the closest coal-fired
14
power plant to your monitoring site?
15
A. I believe it's the Samis plant located
16
about seven kilometers north of the Steubenville
17
location.
18
Q. Is the Samis plant on the river?
19
A. Yes, sir.
20
Q. What's the height of the stacks of the
21
Samis plant? Do you know?
22
A. It's fairly tall. I could look it up, if
23
you would like me to, but my guess is it's 400 or 500
24
feet.
Page86
1
Q. But it's on the river?
2
A. Yes.
3
Q. So it's 400 feet lower than your
4
monitoring site?
5
A. The base of the plant is 400 feet lower,
6
and because it's seven miles up the river, I actually
7
don't know if it's the top of the topographic change,
8
which would make it more than 400 feet.
9
Q. Seven miles or seven kilometers? There is
10
a slight difference.
11
A. I believe it's seven miles.
12
Q. Was there any conversation of plume impact
13
from the Samis plant?
14
A. We actually looked for plume impact on the
15
Samis plant in out ambient data. We have not modelled
16
specific events, but we believe that we see, again,
17
plume impacts at our site. We haven't definitively
18
looked and said, "This is the Samis plant," but we do
19
see indications of a coal-fired utility to the north of
20
our site impacting the levels of mercury in SO2 and
21
other things that we have seen there.
22
Q. North of the plant would not be on the
23
river, I take it? I'm not familiar with the geography.
24
I'm just asking.
Page87
1
A. Yes, it is.
2
Q. So it would be lower than the monitoring
3
site, as well?
4
A. The height of the stack might be
5
comparable in height to the elevation of the monitoring
6
station.
7
Q. How far away is that plant?
8
A. I'm sorry?
9
Q. You said same as the north?
10
A. Yes.
11
Q. I thought you identified the second plant.
12
A. No.
13
Q. We were just talking about Samis?
14
A. That's correct.
15
MADAM HEARING OFFICER: Question H,
16
then.
17
DR. KEELER: "Is this high density of
18
coal-fired units reflected in the CMAQ modeling
19
performed by U.S. EPA?" Again, basing my answer
20
completely on the figure that you can see in the Exhibit
21
30, the one we were just referring to, the base case, I
22
would say yes. Question I: "Is it reflected in the
23
TEAM modeling performed by AER?" My answer is I don't
24
have a recollection of seeing that output. I may have
Page88
1
seen it. I just don't recall whether it was reflected
2
or not.
3
Q. Was it part of the literature that you
4
reviewed and you talked about reviewing model an --
5
A. I have read several papers in the
6
peer-reviewed literature that described and talked about
7
TEAM model and so forth. I just don't recall seeing or
8
visually cueing in on some area that had a specific
9
impact from a specific source type.
10
MADAM HEARING OFFICER: Mr. Rieser, I
11
believe that you asked earlier I got the answers to J
12
and K on the comparison of the Steubenville research
13
with the CMAQ.
14
MR. RIESER CONTINUES:
15
Q. That's correct, but I have one follow-up
16
on that, which is sort of the opposite. Do you know
17
what steps the U.S. EPA has taken to compare the results
18
of CMAQ to your work in Steubenville and what their
19
findings were?
20
A. Only, again, what you can see presented in
21
Landis presentation, that is the only thing I'm aware
22
of.
23
Q. Are you aware of the response to
24
significant public comments received in response to the
Page89
1
revision of the December, 2000, regulatory findings on
2
the emissions of hazardous air pollutants from the
3
utility, electric utility, steam generating units, and
4
the removal of coal- and oil-fired -- the
5
reconsideration technical support document that came
6
out?
7
A. I got an E-mail as an announcement from
8
someone saying that this report came out. I have not
9
had a chance to, either, down load it, or read any of
10
the pages.
11
Q. So you haven't read the response that says
12
the results of the Steubenville, Ohio, receptor modeling
13
study corrected by EPA, ORD, Office of Research and
14
Development, that Dr. Landis -- are consistent with
15
those entangled by the CMAQ modeling?
16
A. Okay.
17
Q. You have read that?
18
A. No, I have not.
19
Q. So you haven't had a chance to review why
20
they say that and determine a response?
21
A. No. I have not downloaded that report or
22
read any portion of it.
23
Q. Thank you.
24
MADAM HEARING OFFICER: L.
Page90
1
DR. KEELER: May I make a follow-up
2
comment? I think it's important to know that my modeling
3
half compares to my measurement half. The idea of a
4
good comparison is a different definition, and so in the
5
EPA case, without having read what they actually say,
6
they might view a 43 percent contribution based on the
7
2001 year to be fairly similar to a 70, plus or minus, a
8
14 or 15 percent contribution from the receptor
9
modeling, so just to know how they interpret "good" and
10
the words that you used for that. I know that they are
11
trying to put the best fit on that as they can.
12
MADAM HEARING OFFICER: Mr. Rieser,
13
what exactly were you reading from?
14
MR. RIESER: I was reading from the
15
Technical Support Document, which is attached to the
16
reconsideration of the CAMR, mercury CAMR that the EPA
17
announced on June 9 of 2006. It was in the Federal
18
Register on that date, which would be 71 Fed Reg. 33388
19
through 333402. I'm not sure if that's -- I have just
20
been advised that this is the Federal Register for the
21
actual reconsideration discussion, which actually
22
contains a little bit of this in there. The response to
23
comments which I read is not in the Federal Register.
24
It's on the U.S. EPA website, so I will be happy to
Page91
1
provide a copy to you.
2
MADAM HEARING OFFICER: Thank you very
3
much. For the record, obviously, since this isn't the
4
federal register it's a public document and obviously,
5
we, at the Board, look at the Federal Register, but for
6
purposes of the record, it's probably best if we also
7
put the Federal Register reconsideration of CAMR in the
8
record at the same time. Do you have a clean copy of
9
that?
10
MR. RIESER: I have clean copies of
11
either one, so if I may, if I could bring some copies
12
Monday --
13
MADAM HEARING OFFICER: That would be
14
great. Thank you.
15
DR. KEELER: Are we -- K is gone.
16
"What steps have you taken to compare the results of
17
your Steubenville work with the EPRI TEAM deposition
18
models, which was included in the CAMR docket?" Again,
19
this was not the scope of work, nor the scientific
20
objective of the project that I performed, so it was not
21
done. Obviously, M is not applicable. That finishes
22
Ameren's questions.
23
MR. KIM: I asked for a short break
24
because when we might have neglected to send him the
Page92
1
four questions that were presented by Prairie State and
2
I think he confirmed that he hadn't seem them, and I
3
think some of them may have been answered, but I want to
4
make sure that we get all the questions answered.
5
MADAM HEARING OFFICER: I think
6
Question No. 1, "Have the details of Steubenville model
7
been made publicly available?" That's similar to the
8
Ameren -- quite a bit of discussion. Second, "You state
9
that 70 percent of the mercury wet deposition in
10
Steubenville comes from coal-fired power plants. How
11
far have you traced back power plant plumes to reach
12
that conclusion?" Hundreds of miles, and we also
13
discussed that today.
14
DR. KEELER: Much longer than that.
15
MADAM HEARING OFFICER: So I think
16
question No. 3 you might want to elaborate.
17
DR. KEELER: "Have you modeled what
18
wet mercury deposition is predicted in Steubenville
19
after implementation of CAMR? I actually just answered
20
this question to some extent. Our model does not have
21
predictive capability, so we are not able to do that.
22
So the rest of the question is not applicable and 4:
23
"Would you expect coal-fired power plants to contribute
24
70 percent of the mercury to wet deposition at every
Page93
1
location this the United States?" One of the things I
2
think would be worthwhile just pointing out -- the
3
answer is no, and one of the things that's worth
4
pointing out is when you hear these estimates of 8 to 10
5
percent of the mercury deposition in United States is
6
from U.S. sources it's kind of a small number. They are
7
talking about the entire land area of the United States.
8
Every one single square area and most of the coal-fired
9
utilities are in the Eastern United States, the eastern
10
one-third of the United States, and you would not expect
11
to see 70 percent contribution to Southern New Mexico,
12
so obviously, you would not expect that. Continuing
13
with that question, if not, what is the contribution of
14
the Illinois coal-fired power plants to mercury wet
15
deposition in Illinois?" I'm not sure exactly how the
16
questions are connected, but again, I don't have a
17
quantitative estimate for that to answer that question.
18
MADAM HEARING OFFICER: Anything
19
further?
20
MR. RIESER: Just to note for the
21
record that Mr. Bonebrake advised me that he had, in a
22
fit of preparation, actually brought copies of the
23
reconsideration for the federal register, and so we will
24
present those now. Giving the first copy to Mr. Harley.
Page94
1
MADAM HEARING OFFICER: I will mark
2
this. This is the actual Federal Register from June 9,
3
2006. It's the reconsideration. It's not the comments.
4
We will mark this as Exhibit 31, if there's no
5
objection. Seeing none, it's Exhibit 31.
6
(Exhibit No. 31 was admitted.)
7
MR. FORCADE CONTINUES:
8
Q. Yes. If I could, I would like to ask a
9
Steubenville question. If I could, I would like to
10
direct your attention to three documents in the record
11
and sort of lay a frame work for the questions. The
12
first one is Ms. Willhite's testimony on page 3. Why
13
don't you grab that. In particular, in that document on
14
the middle paragraph contribution from point sources,
15
there was a sentence, "It was determined that the total
16
of all waste water discharges to receiving rivers and
17
streams in Illinois provide an average annual loading of
18
45 pounds of mercury." Do you see that?
19
A. I do.
20
Q. The second would be --
21
MADAM HEARING OFFICER: For the
22
record, Ms. Willhite's testimony is Exhibit No. 8.
23
MR. FORCADE CONTINUES:
24
Q. Would be the Technical Support Document at
Page95
1
pages 68 and 69. On the bottom of 68 and top of 69 in
2
the reference to total mercury loading from MPTS
3
sources, and the third one would be your prepared
4
testimony at page five, the last paragraph, in which you
5
talk about the importance of coal-fired power plants to
6
the loading of mercury in large lakes and many down
7
inland lake which is have been identified as impaired
8
waters. The distinction I'm trying to suggest here is we
9
have talked a great deal about deposition, but we have
10
not particularly identified as much background
11
information on loading to the lakes and streams, and I
12
would like to ask a few questions, if I could, to
13
explore that.
14
First, would you say that past and
15
present loading to lakes and streams, particularly
16
impaired streams, is important in determining the amount
17
of mercury available for methylation?
18
A. Yes. It is important, and I would like to
19
add that some of the more recent research that had been
20
performed through the halogen project (phonetic) and
21
other work which has been published by Cindy Gilmore
22
suggests that it's the mercury that's recently deposited
23
from the atmosphere that is the most important in terms
24
of cycling and methylation and contamination of the
Page96
1
ecosystem.
2
Q. I'm still trying to restrict right now my
3
questions to the loading to streams. You, again,
4
mentioned deposition.
5
A. Because deposition is the primary input to
6
most streams.
7
Q. You're running a bit of ahead, if you
8
wouldn't mind. Would you identify what you would
9
consider to be the sources of loading of mercury to
10
impaired lakes and streams?
11
A. Well, there's tributary inputs that load.
12
There's nonpoint sources from agricultural and animal
13
feed lots. All of the runoff from industry sites,
14
basically, runoff from the land into tributaries and
15
then direct discharges from point sources into either
16
tributaries or inputs to those lakes and streams.
17
Q. Have you done any studies to try and
18
evaluate those specific forms of loadings and quantify
19
them?
20
A. Anywhere?
21
Q. Yeah. Let's start with anywhere.
22
A. Yes.
23
Q. Could you tell me what studies you have
24
done?
Page97
1
A. We did a rather large study in the city of
2
Detroit trying to -- not trying, with the objective to
3
quantify the importance of atmospheric deposition and
4
the goal of trying to identify the most significant
5
sources of mercury and PCB's to the receiving waters
6
that feed into the city of Detroit's waste water
7
treatment facility.
8
Q. I'm sorry. Was that loading to the sewers
9
and waste water treatment facility?
10
A. Yes. In other words, we worked with the
11
city of Detroit's waste water -- the water and sewer
12
department to quantify how much mercury was coming into
13
the head of their waste water treatment plant from all
14
of their network, which is a fairly large network of
15
homes, industry, combined storm sewer overflows and so
16
forth, and then to look at how much mercury they then
17
discharged, and part of this was wrapped around their
18
MPDS permit looking at how much affluent mercury they
19
put out and what forms, and how far of this was related
20
to atmosphere I think deposition.
21
Q. So you have done studies on the amount of
22
and source of mercury entering into a public-owned
23
treatment work?
24
A. Yes.
Page98
1
Q. Have you done similar studies for a stream
2
or lake?
3
A. We have not done an exhaustive study in
4
trying to estimate the inputs to a specific tributary.
5
We have done some monitoring in the state of Michigan
6
trying to look at kind of upstream-downstream
7
relationships for mercury on rivers in Michigan, but
8
again, those were not meant to be exhaustive, in terms
9
of, specifically, quantifying the runoff from
10
agriculture, versus industrial discharge. It was just
11
trying to see if we could find an influence of an urban
12
area on a specific river or tributary.
13
Q. Could you identify the number or name of
14
those studies for me, so I can ask some questions on
15
them?
16
A. The one was -- I don't know what the
17
initial name was, but it was something like "Mercury
18
Levels in Michigan Rivers and Surface Waters" done with
19
the Michigan DEQ in the 90's. I actually don't remember
20
the exact year, sometime in the 90's, though, and then
21
the other study we did was something mercury PCB's and
22
cadminium (phonetic) in affluent -- at the city of
23
Detroit's waste water treatment plant, something like
24
that.
Page99
1
Q. The second one you mentioned, would that
2
be the POTW study you discussed earlier or was that a
3
third?
4
A. No. That's the same one.
5
Q. So excluding the publicly-owned treatment
6
works, as far as streams lakes and rivers are concerned,
7
you have one study which was the 1990 Michigan study.
8
Is that correct?
9
A. Where we look, specifically, at streams
10
and rivers.
11
Q. The loading of mercury to streams and
12
rivers.
13
A. Again, as I mentioned, it wasn't a study
14
looking at -- it was looking at levels of mercury kind
15
of upstream and downstream of different urban areas or
16
towns, so that would be my only experience.
17
Q. Regarding the 1990 -- do you want to call
18
it study or do you have another term?
19
A. Which one are you referring to?
20
Q. The 1990 Michigan --
21
A. Michigan study. That's fine. When you
22
are asking me that, you are not asking me to talk about
23
the Lake Michigan Mass Balance Study.
24
Q. No. I'm asking you what you have done to
Page100
1
evaluate the mercury loading to streams and rivers.
2
A. That's not my main focus area, in terms of
3
research.
4
Q. I understand, so the 1990 Michigan study
5
was the only one that you can point to, specifically.
6
Is that correct?
7
A. I guess, yes.
8
Q. Could you describe in detail what you did
9
in that study?
10
A. We made measurements of -- well, I should
11
say the Michigan DEQ took water samples using the
12
systems that we developed to measure total and dissolved
13
mercury and other metals in a series of rivers, and I
14
believe maybe lakes and across the lake and in
15
situations where they could make a measurement, and say,
16
upstream of Ann Arbor and downstream of Ann Arbor in the
17
Huron River, for example, to see if there's an influence
18
of the runoff and inputs of metals and mercury into the
19
stream related to that area, so it was a way to get some
20
survey data across the state.
21
Q. When you say the Michigan Department of
22
Environmental Quality samples, these were water quality
23
samples?
24
A. Water quality, only.
Page101
1
Q. Water quality, only. Do you have an idea
2
of, approximately, how many sites were studied or
3
samples were taken?
4
A. I don't recall the total numbers. It was
5
in the hundreds.
6
Q. Was it a large geographic area or was it a
7
single stream segment?
8
A. I know that it encompassed the entire
9
lower peninsula.
10
Q. Of Michigan?
11
A. Yes.
12
Q. That would be a big study, then.
13
A. Yes, sir.
14
Q. What was your function, then, to take the
15
analytical results from Michigan DEQ and evaluate them
16
in some way?
17
A. No. Our lab that was doing that provided
18
the sampling equipment and did all the analytical
19
determinations of mercury and metal concentrations in
20
the samples collected and provided them with the
21
recorded findings. Because that's outside my typical
22
area of research, I didn't spend any time evaluating the
23
data, other than for the quality of the information that
24
was collected.
Page102
1
Q. Did you draw any conclusions from the data
2
or was your evaluation simply, "Here's the analytical
3
results"?
4
A. As you had described, "Here's the
5
analytical results."
6
Q. So you performed no evaluation of the
7
sources or impacts or --
8
A. No, sir.
9
Q. Have you done any evaluations of the
10
loading of mercury to stream segments, other than this
11
that would be relevant to determining the amount of
12
mercury coming into the lakes and streams?
13
A. I think I have said that my expertise is
14
not in tributary or aquatic science. It's in
15
atmospheric science, so I have not performed input
16
analysis.
17
Q. Do you have any method or are you aware of
18
any additional reports that have been done which
19
evaluate the amount of loading to specific stream
20
segments of mercury comparing, for example, air
21
deposition, versus upstream water deposition?
22
A. Well, there was an extensive amount of
23
work down by the University of Wisconsin and the USGS,
24
as part of the Lake Michigan Mass Balance study in
Page103
1
looking to -- I don't know how many tributaries into
2
Lake Michigan, and I know they have done an exhaustive
3
amount of work for Lake Superior for exactly that same
4
purpose for mercury and trace elements, and I have seen
5
presentations, and I know there's, at least, a few
6
publications in the peer-reviewed literature on that.
7
Q. The analytical results that you conducted
8
for the Michigan study, those are water quality
9
evaluations for mercury water analysis for mercury
10
content?
11
A. Yeah. They were analysis of liquid
12
samples that were taken from surface bodies of water.
13
Q. When were those done?
14
A. I said I believe it's in the mid 90's. I
15
don't recall the exact date.
16
Q. Do you happen to recall what analytical
17
method you used to test the mercury?
18
A. Sure. I used coal vapor atomic
19
fluorescence for the mercury and I used ion-coupled
20
masstometry (phonetic) for the trace element analysis.
21
Q. So would that be Method 1631, Provision E
22
of the mercury analysis?
23
A. That protocol came out after, but our
24
protocol is almost identical. I mean, we did not follow
Page104
1
their protocol. We have our own protocol that has been
2
subjected to Agency peer review, and proved quality
3
assurance, quality control plans that we use in all of
4
our work.
5
Q. What was your method detection limit?
6
A. For that study, I would have to go back.
7
I don't recall the detection limits for the 40-some
8
elements that we did.
9
Q. I'm sorry, restricting my evaluation here
10
to mercury.
11
A. Again, I don't recall, but it was for
12
that -- we determine a method detection limit for every
13
study we do, based on the actual data, which is defined
14
as seven times the standard deviation of repeated
15
analysis of a low standard, and I don't remember the
16
exact number. It's -- I believe it's around a tenth of
17
a nanogram per liter, could be lower than that.
18
Q. Prior to the 1990 Michigan study, did you
19
do other evaluations of mercury concentrations in water?
20
A. I did determinations of mercury in cloud
21
water and fog water, yes.
22
Q. What time period would that be in?
23
A. Late 80's.
24
Q. Did you use the functional equivalent of
Page105
1
1631 for those tests, too?
2
A. No. We used a much more elaborate and
3
exhaustive technique that requires a nuclear reactor. I
4
did this work at the Institute of Technology while I was
5
visiting scientists there.
6
Q. Prior to 1990, if you did not have access
7
to a nuclear reactor, would you not have commonly used
8
Method 245 or a similar method for determining mercury
9
content in waters?
10
A. I'm not sure I can answer that question.
11
I'm not 100 percent certain I know what "Method 245" is,
12
and I know that -- well, I'm not sure I can answer that
13
question.
14
Q. If you had conducted a water analysis for
15
mercury prior to the 1990's, and prior to the
16
implementation of your test protocol, do you know,
17
approximately, what the method detection limit would
18
have been available for those prior test methods?
19
A. If you are talking about research methods
20
or are you talking about those that would have been used
21
by states or EPA? I mean --
22
Q. States and EPA and facilities subject to
23
mercury testing.
24
A. You are asking me to give you a historical
Page106
1
account of the analytical techniques through the 80's?
2
Q. That would be one way of getting to my
3
question, but another way would be to say is it your
4
understanding that Method 1631 is described as being,
5
approximately, 250 times more sensitive than the prior
6
testing protocols for mercury with significant increase
7
in lowering of the method detection limit?
8
A. I don't know the numerical number, but
9
from the early 1980's, the methods that were used such
10
as atomic absorption and coal vapor atomic absorption
11
have detection limits that were much higher, so they
12
were unable to see the small quantities of mercury that
13
we can see, starting in the late 80's. For some reason,
14
they were already beginning to use those low-level
15
techniques in the early 80's. Nick Bloom and Bill
16
Fitzgerald and his students at the University of
17
Connecticut had these techniques at their disposal. The
18
widespread use of those were regulatory, and other
19
monitoring purposes did not happen in the 80's.
20
Q. I believe it would be 1990 would be I
21
think the first -- do you happen to recall when the
22
first version of Method 1631 came out or its equivalent,
23
which uses the nanogram detection limit?
24
A. I don't know the exact date because I
Page107
1
restarted using something that was similar before that
2
method and it actually worked its way through the
3
system.
4
Q. Would you believe it would be common,
5
prior to that time, for the detection limit to have been
6
about one part per billion or slightly less for most of
7
the common analytical procedure in use by states and
8
dischargers?
9
A. Well, my understanding, again -- and I
10
can't say this is for most or I can't put a quantitative
11
number on it, but I would say that most places that were
12
doing fish contaminant work and so forth had, at least,
13
a detection limit of 150 parts per trillion maximum
14
before they moved to coal vapor atomic fluorescence and
15
some of the other techniques, so it was quite a bit
16
higher than the .1. I mean, that's a thousand fold
17
different than I just quoted you 150 parts per trillion
18
versus the .1 that we are able to do now.
19
Q. But that was for --
20
A. Total mercury.
21
Q. Tissue evaluation?
22
A. Mercury analysis. Are you asking me for
23
surface water?
24
Q. All my questions relate to mercury testing
Page108
1
for surface water.
2
A. I don't know the exact number to give you,
3
but your basic premise is correct, that detention limits
4
were very high and could have been approaching a part
5
per billion prior to the advent of the work that
6
Fitzgerald and his students did in the early 80's.
7
Q. If you were to evaluate the loading to a
8
stream, as you mention on page five of your testimony,
9
how would you determine the components, other than air
10
deposition?
11
A. Again, this is outside my area of
12
expertise, but I did participate in the Lake Michigan
13
Mass Balance study and from working collaboratively with
14
the University of Wisconsin and the USGS and people who
15
did that work, as I understand it, they make
16
measurements of the hydrograph, the flow of water coming
17
in from all the major tributaries they think are
18
important, and then try to take samples for mercury
19
using approved clean techniques to then ascertain what
20
the amount of mercury coming in along at different flows
21
from that tributary, and then sum those numbers up, so
22
they are a flow-proportioned calculation of how much
23
mercury would enter into the body of water that you are
24
interested in and studying. That's, more or less, what
Page109
1
they did for all the tributaries for Lake Michigan. In
2
doing that, you come up with a total mass that entered
3
Lake Michigan from the Sheboygan River, and you do that
4
for every single one of them, so it requires an enormous
5
amount of work and a lot of monitoring.
6
Q. If you were to evaluate, for example, an
7
impaired lake or stream in Illinois in an attempt to
8
determine the amount of air deposition in loading to
9
that stream and compare it to the loading from other
10
sources, what would you do for the air deposition
11
portion to determine loading of that stream?
12
A. You are asking me, personally, what I
13
would do?
14
Q. Yes.
15
A. If it was a specific stream that I was
16
interested in, I first have to evaluate how long that
17
stream was, whether I felt that one monitoring location
18
would represent what would be coming into that stream if
19
it was extremely long, 20 miles long, or if it's
20
something longer than that, I would evaluate what point
21
sources were contributing to that stream, and then look
22
at the land use types around that stream, and then make
23
a determination whether I needed to put one or two
24
deposition where I would collect the amount of
Page110
1
precipitation that fell and I gauge it, so I would have
2
a number of rain gauges and so forth along there, so I
3
could get an accurate description of the amount of
4
precipitation that fell into the stream and maybe even
5
put multiple gauges on that stream, so I could get the
6
flow of that stream, so I could have a good idea of then
7
the mass of whatever contaminant I was looking into the
8
stream, but it would be very stream specific, and it
9
would require some analysis of the situation and on-site
10
recognizance and so forth.
11
Q. If you were to complete such a study and
12
determine what you felt was an appropriate level of
13
loading from air deposition, that would simply be one
14
component of the loading to that particular stream
15
segment, wouldn't it?
16
A. Yes, sir.
17
Q. And there would be another section at
18
which would be the water component, sediment component.
19
Those other components would all contribute to the total
20
loading?
21
A. I didn't say explicit, but clearly, you
22
would have to make repeated measurements of the stream,
23
the water body of interest, both, the liquid sample, as
24
well as the sediments, anything else you think could
Page111
1
have contributed to the loading or movement of the
2
contaminant through that stream.
3
Q. There would be no way that you could
4
possibly determine the relative proportion of the air
5
loading to that stream segment without knowing the other
6
components of contribution, would there?
7
A. If I was an engineering firm who was
8
requested to make a determination of the importance of
9
runoff, atmospheric deposition and so forth, I would use
10
my best expert judgment and use what data was available
11
to estimate the importance of these. In many cases you
12
don't have the actual measurements, so you have to use
13
expert judgment, and use whatever available measurements
14
are there to give an estimate for that. In the best of
15
all worlds, I would like to have measurements. I'm a
16
very measurement-greedy person. I like to have
17
measurements for all those things that I said, so I can
18
be certain of my conclusion. However, in making a best
19
estimate judgment, one would use the available data that
20
you had and put some air bars on how precise or
21
imprecise you would be able to estimate the various
22
inputs.
23
Q. Directing your attention to page three of
24
Ms. Willhite's testimony and page 69 of the Technical
Page112
1
Support Document, in which it suggests that the average
2
MPDS has loading to Illinois streams was 45 pounds and
3
then comparing that to 7,022 pounds per year of mercury
4
emissions, that evaluation wouldn't give you any way of
5
determining for an impaired stream what portion was
6
coming from air deposition and what portion was coming
7
from other sources, would it?
8
A. Those two facts by themselves do not allow
9
you to calculate the specific proportion coming from the
10
atmosphere, versus what was coming from the tributary to
11
a specific stream.
12
Q. Would a portion of the reason be because
13
it talks about emissions to the atmosphere, rather than
14
amount loaded to the Illinois streams from air
15
deposition?
16
A. I think that's one source of uncertainty,
17
yes.
18
Q. There would be no evaluation in the
19
sentence that you see there about other contributing
20
sources, such as sediment movement, nonpoint runoff,
21
combined sewer overflows, types like that?
22
A. I'm sorry. I don't know where you are
23
referring to.
24
Q. The reference to the 40 pounds of MPDS
Page113
1
loading compared to the 7,022 pounds of air emissions,
2
it makes no reference to any contribution coming from
3
surface runoff from sedimentation moving downstream or
4
other sources, does it?
5
A. I don't see any listed here.
6
Q. And would you consider that to be one
7
possible input to the stream loading for an impaired
8
water?
9
A. Yes. There is one potential input to a
10
potentially impaired water, yeah.
11
Q. Would you have any information that would
12
allow you to draw a rough conclusion of the amount of
13
stream loading to a particular stream segment that would
14
come from air deposition, versus other sources,
15
generally?
16
A. I wasn't asked to look at this or address
17
that, and that's not, again, in my typical line of
18
research. If I was asked to do something like that, I
19
may be able to put that information together, but I did
20
not do that, and this is the first time I have actually
21
thought able calculating something like that. I mean,
22
we have looked at this issue, in terms of looking at one
23
of the things we found on the Lake Michigan Mass Balance
24
Study was there a fairly large amount of the input to
Page114
1
tributaries that they couldn't account for by looking at
2
runoff from agricultural areas or runoff from surfaces
3
and so forth, which we did a rough calculation and
4
determined that most of those was probably from
5
atmospheric, so it was the mercury that was in the rain
6
that fell to the ground, and then wound up running off
7
into the tributary. It was in the soluble phase, and so
8
forth, but that kind of gets at what you're asking me
9
here, but I have not addressed that question,
10
specifically, in this case.
11
Q. Right, but what you're talking about there
12
is mercury entering in the equatous (phonetic) phase.
13
Is that correct? You're not talking about --
14
A. Yeah. The river has water in it and the
15
rain fell and fed and goes as a liquid into the river,
16
yeah.
17
Q. So for the evaluations that you were doing
18
in Michigan, and for the discussion you just had, would
19
you use filtered samples to determine the mercury
20
content?
21
A. If I wanted to understand the mechanism
22
and the physiochemical transport from various fields and
23
so forth, I would take a total sample and definitely
24
filter it, so I could look at the total and dissolved
Page115
1
phase, yes.
2
Q. And historically --
3
MADAM HEARING OFFICER: I apologize
4
for interrupting, but are you going to be able to wrap
5
this up? I don't want to cut you short, but it's 10
6
after 12, and we've been back at for a couple hours, so
7
if it's going to take another 20 minutes or so we might
8
want to go ahead and take a break, but if it's only
9
going to take a couple -- it's up to you.
10
MR. FORCADE: I'm not sure whether
11
it's going to take me five or 15. I'm not sure.
12
MADAM HEARING OFFICER: Let's go ahead
13
and go to lunch because we have been back at it for a
14
couple of hours.
15
MR. FORCADE: That's fine. I just
16
don't know.
17
(At which time, the proceedings were
18
adjourned for a lunch break.)
19
MADAM HEARING OFFICER: I believe
20
Mr. Forcade was asking Dr. Keeler some questions. Let's
21
go back.
22
MR. FORCADE CONTINUES:
23
Q. We had a lengthy discussion at lunch about
24
the co-benefits discussion about the co-benefits of
Page116
1
concluding the testimony as early as possible on a
2
Friday afternoon, so I may be able to conclude with one
3
or two more questions. Dr. Keeler, if I'm not
4
characterizing this correctly, please let me know, but I
5
believe that you've made attempts to identify the source
6
of mercury deposition by what is, essentially, a
7
fingerprinting to identify the source categories. Is
8
that a paraphrase?
9
A. No. That's correct.
10
Q. Have you done anything to try and identify
11
the mercury present in fish in a similar manner?
12
A. I, personally, have not.
13
Q. That's it.
14
MR. HARRINGTON CONTINUES:
15
Q. One question. The City of Detroit Study
16
that you did concerning BOTW's, do you know whether
17
there was any effort to characterize, either bypasses or
18
combined sewer overflows during that study and their
19
impact on receiving waters.
20
A. Our study was focused completely on
21
quantifying the importance of atmospheric deposition on
22
PCB's, mercury to the waters that hit the head of the
23
plant, and we didn't really look at issues of bypass or
24
combined sewer overflows. We made measurements in the
Page117
1
system, but we did not look at those issues.
2
Q. Was there significant measurable mercury
3
in the influence of the BOTW's?
4
A. We measure mercury in every sample we
5
collect, and yes, there was measurable mercury. Again,
6
our detection limits are a tenth of a part per trillion,
7
so you see mercury in the drinking water you have in
8
front of you. It's probably not of any concern.
9
Q. To put another way, mercury is everywhere
10
in the natural environment, correct?
11
A. Yes.
12
Q. Do you recall what the levels of mercury
13
were in the influence of publicly-owned treatment works?
14
A. The influence concentrations varied from
15
100 to 400 nanograms per liter.
16
Q. Thank you.
17
MR. FORCADE CONTINUES:
18
Q. Dr. Keeler, you just mentioned in response
19
to Mr. Harrington's question that you found mercury in
20
many locations. Would you expect, at that level of
21
detection, that you would find mercury in many MBTS
22
discharges (phonetic)?
23
A. I believe I would see mercury at least in
24
the trace quantities in the part per trillion level in
Page118
1
all discharges.
2
Q. Thank you.
3
MR. BONEBRAKE CONTINUES:
4
Q. Just one other follow-up, do you recall
5
the eruption of Mt. St. Helens around 1980?
6
A. I remember it very well, yes.
7
Q. Was that eruption a significant source of
8
mercury air emissions?
9
A. Volcanoes are thought to be one of the
10
prime natural sources that put mercury into the earth's
11
atmosphere.
12
Q. Has there been any estimate of the amount
13
of mercury emitted into the air that resulted from that
14
eruption?
15
A. It's possible someone did a calculation.
16
I'm not aware of that that number.
17
Q. Have you ever seen a comparison of that
18
number, whatever it may be, to mercury emissions from
19
electric-generating units?
20
A. Again, I don't recall Mt. St. Helens, in
21
specific. I know that people have looked at volcanic
22
emissions from Italian volcanoes and a couple of others
23
around the world, but I don't recall Mt. St. Helens,
24
specifically, but it's a pretty large number. If
Page119
1
volcanoes were going off continuously all the time or
2
every year, it would certainly change the global budget
3
of mercury in the atmosphere. Mt. St. Helens, if you
4
remember, gave us very beautiful sunsets and put a lot
5
of ash and sulfuric acid up in the stratosphere, so it
6
shot -- not only did it put a huge ash over a small
7
area, but it also shot a lot of stuff up into high
8
levels in the atmosphere, so it definitely was seen
9
everywhere.
10
Q. In fact, the mercury that went up high
11
levels of atmosphere, would that suggest what mercury
12
would have been dropping onto the ground or into the
13
waters for a significant period of time after the
14
eruption?
15
A. Whatever came out of the volcano,
16
including mercury, would have been emitted into high
17
altitudes and some of that perhaps could have been
18
removed, since a large of amount went up in the
19
stratosphere. I'm sure a great deal of it is probably
20
still up there.
21
Q. Thank you.
22
MR. HARLEY CONTINUES:
23
Q. At the beginning of your responses to the
24
questions that were posed by Mr. Forcade, you began to
Page120
1
describe a study -- actually, there are two authors of
2
that study who were looking at the relative contribution
3
of atmospheric deposition to recent contribution and
4
cycling. Do you recall your reference to that study?
5
A. I'm sorry. I must have post-lunch brain
6
deadness. Help me a little bit.
7
Q. You were talking about the total loading
8
and methylation issue, and you began to talk about a
9
study, which I took to mean that recent contributions of
10
atmospheric deposition were most important, in terms of
11
methylation and also most important, in terms of
12
cycling, and I felt that you had more to say about that,
13
and I would like to hear what you had to say about that
14
study.
15
A. You're referring to I believe I referenced
16
Cindy Gilmore and Dave Griminhoff's (phonetic) work, as
17
well I think Jim Hurley from the University of Wisconsin
18
in the water chemistry program. Actually, there's a
19
fairly large group doing some work in METALLICAS, so
20
there's a couple different studies there, but what the
21
issue is there have been for years -- in fact, the
22
thought was that the methylmercury that was entering
23
into ecosystems and bioaccumulating was coming from the
24
bottom sediments over time and some of this born out in
Page121
1
Florida through some studies, but over time, people
2
started to say, well, they couldn't explain the amount
3
of mercury and methylmercury, specifically, and as they
4
got better and better at making methylmercury
5
measurements and the BIODA and in the fish and through
6
the ecosystem, they started to hypothesize that the
7
mercury that was actually cycling, so going from the
8
reactive mercury form methylated by the bacteria, and
9
then going into the organisms was actually the mercury
10
that was falling out of the sky today, so the stuff that
11
falls out today gets chemically transformed and actually
12
winds up -- that's the mercury that winds up
13
contaminating the fish so Cindy Gilmore and colleagues
14
have done some studies where they have actually taken
15
and used as a tracer an isotope of mercury. It's one of
16
the masses of mercury, and they can get this mercury
17
from Oak Ridge National Laboratories, and other places,
18
and they can put that in the system in different
19
compartments and look to see where it goes, and in fact,
20
the mercury that they put in just as precipitation would
21
have been gone into the lake is what they actually are
22
now seeing coming up from the ecosystem in a fairly
23
rapid fashion, so their experiments are duplicating what
24
their hypothesis -- or confirming their hypothesis that
Page122
1
what's important is what's falling out of the sky into
2
the ecosystem, and that's much more mobile and moving
3
through the ecosystem at a much faster rate than the
4
stuff that's buried down in sediment. In fact, some of
5
the stuff that's buried in sediments likely will not
6
become a problem at all over a very, very long
7
geological time frame, so that's the conclusion that
8
they drew. Now, again, that's the study that they have
9
performed thus far, and I know at the Wisconsin Mercury
10
Meeting that's coming up in August that more results
11
from that METALLICAS study will be presented.
12
MR. FORCADE CONTINUES:
13
Q. Dr. Keeler, you made reference to the fact
14
that the mercury that is more recently deposited into
15
the stream from the air, did they do comparative
16
evaluations of the isotopes by depositing mercury in the
17
water environment.
18
A. Yes, they did. They actually put it in
19
the sediments. They put it directly into the water.
20
They deposited it in the air. Then they actually
21
sprayed it on the forest ecosystem, and watched that as
22
it made its way to the forest and to the forest floor
23
and into the body of water that they were studying.
24
Q. Could you give me a date or name?
Page123
1
A. METALLICAS, and I'm trying to think of who
2
the lead investigator was, but if you look up Gilmore or
3
Griminhoff or Hurley, I think John Rude up in Canada is
4
a principal in that. It's a fairly large team. I know
5
Steve Linberg and Jim Hurley were also involved. It's a
6
team of about 15 different people from, both, U.S. and
7
Canada that are doing that work.
8
DR. KEELER: The key is trying to get
9
at what's most important in terms of contaminating the
10
environment, and that's what the focus of that whole
11
study is and the indication is that it's recent
12
deposition really is the most important.
13
MR. FORCADE: When the questions are
14
over, I have a procedural question for Mr. Kim.
15
MR. BONEBRAKE CONTINUES:
16
Q. I'm just curious. You just talked about
17
the relative significant of more recent deposition.
18
Does the answer change, Dr. Keeler, in waterbodies in
19
which the sediment is stirred up for reasons maybe
20
associated with a hurricane in an area or perhaps
21
seasonal flooding or drudging.
22
A. It really depends upon how the mercury is
23
bound in the sediment or in the soil or whatever you are
24
referring to there. If it's tightly bound, it may not
Page124
1
be biologically available. Mercury that's in sand,
2
copper sludge that they get from a copper mine, like up
3
in the UP of Michigan, for example, is not thought to be
4
very biologically available, so if it's in that form,
5
it's stirred up it may not actually lead to a higher
6
methylation rate. If it's in a bioavailable form, then
7
yes, it could.
8
Q. So would it be your sense that the
9
question of the relative significance of recent
10
deposition is going to be a question whose answer is
11
somewhat variable depending upon the particular
12
characteristics of a water body?
13
A. It would be characteristic of a frequency
14
of disturbance and the type of disturbance and the
15
characteristics of the water body and the inputs, yes.
16
All those things would be important to take in mind,
17
take into account.
18
DR. GIRARD CONTINUES:
19
Q. I hate to bring up Steubenville again, but
20
Dr. Keeler, I seem to recall that you talked about doing
21
air sampling every hour during that study looking at
22
mercury levels in the air. Was I correct in that?
23
A. Yes, you were correct.
24
Q. When you had rain events, and you had this
Page125
1
sampling going on every hour, did the amount of mercury
2
in the air change after the rain event?
3
A. Again, we haven't done an exhaustive study
4
of every single rain event, but for the ones that we
5
could match up or that we did match up the ambient that
6
you do see a very rapid dropout in the reactive mercury
7
and you see a smaller, but significant, drop in the
8
particulate mercury levels, as well, with a very -- or a
9
less of a decrease in the elemental mercury
10
concentrations, so we see that, not just at
11
Steubenville, but we see that in our mercury sites in
12
Michigan, as well, both, in Detroit and at the site in
13
Dexter, which is about 30 miles to the west of Ann
14
Arbor, so you do see what's in ambient air increasing
15
precipitating systems.
16
Q. You hate to quantify it because the data
17
hasn't been fully processed, but just ballpark. I mean,
18
are we talking just a 50 percent reduction or 100
19
percent reduction? What kind of a reductions are you
20
looking at after a rain event?
21
A. If it's a prolonged rain, if it's a rain
22
that lasts more than an hour because that's hour time
23
frame of our measurement, so we have to have something
24
that goes longer than an hour in order for me to answer
Page126
1
your question. If it's a longer rain that goes more
2
than an hour, you will see complete depletion of the
3
reactive mercury from the air. Particulate mercury is
4
already very low, so that goes to nothing, as well, and
5
elemental will stay, approximately, with a background is
6
1.5 nanograms per cubic meter and doesn't really change
7
much in terms of through a rain event, so after an
8
event, say, that's over an hour where it reduces the
9
mercury in the air down to zero, how quickly do you see
10
the mercury levels go back up? It really depends upon
11
the reason that the rain fell. If it was a frontal
12
system where the wind is changed, sometime it doesn't
13
come back up for quite a wile. If the wind stays coming
14
from the same direction, as soon as the rain is over,
15
there will be a period of time where it could be like
16
the next hour or the hour after that you will see it
17
start to raise back up again, so there is a one-to-one
18
correspondence. I just haven't quantified it, but at
19
our site in Dexter, we actually -- did quantify it for a
20
period or time and it was exactly a 50 percent reduction
21
an hour after the rain came, but then we were making
22
measurements every other hour, so that we couldn't -- it
23
wasn't as clean. For a long rain, you see it go right
24
to nothing. For a rain that lasted 30 minutes, the
Page127
1
following hour reactive mercury would be half as much,
2
and then whether it came back up or not depended upon
3
which way the wind was blowing. The reactive and
4
particulate mercury concentrations that we see at
5
Steubenville and in Michigan are very wind directional
6
and very transport specific. We get transport from the
7
north in Michigan, for example, we see very little often
8
with strong winds, especially during the wintertime and
9
in the summertime, when the wins switch around, you see
10
very high concentrations, but with very specific wind
11
directions, and it always responds the same when it
12
comes to precipitation. We do not have any examples of
13
high RGM with precipitating events going through for
14
multiple hours where it stays up and that goes along
15
with the understanding of how soluble and reactive
16
mercury is in the atmosphere.
17
MR. FORCADE: If I could have a
18
procedural question. Earlier this week in the panel
19
discussion I asked a series of questions about MPDS
20
discharges mercury content and the contribution of total
21
loading as described on page 69 of the Technical Support
22
Document. There are two references supporting that in
23
the Technical Support Document, and both of those
24
references are incorrect. They have absolutely nothing
Page128
1
to do with calculating mercury, affluent limitations.
2
As far as I'm concerned right now, there is no support
3
for those tables. I have asked -- and I don't need the
4
information today -- but there's a significant open
5
question which I need information from the Agency to
6
explore, and I would like to just, not for purposes of
7
asking questions today, just remind them that that is a
8
significant open question that I need to explore for the
9
conclusion of these hearings next Friday.
10
MR. KIM: Indeed, Mr. Forcade did
11
raise that. We tried to initially provide the documents
12
that were referenced, and I think I am in agreement with
13
him that it doesn't really seem to mesh up with what was
14
in there, so we are in the process of getting that
15
information, and I'm pretty certain we are going to have
16
it for you Monday or Tuesday, at the latest, next week.
17
So if it could wait until then.
18
MR. FORCADE: That's fine with me.
19
MR. KIM: It's not forgotten.
20
MADAM HEARING OFFICER: There were a
21
couple of things today that we had talked about from
22
Dr. Keeler. One was I believe you have in front of you.
23
MR. KIM: Actually , I was going to
24
say there were a couple things I was going to bring up
Page129
1
just to sort of close some loops. METALLICUS, the
2
acronym, I can give you what that stands for, if you
3
want that. And then the last thing -- this was just
4
something that was referenced after trying to get a copy
5
of the Powerpoint presentation that Dr. Keeler made
6
reference to a while back and I think it's -- I think
7
the Board and the Agency were the only people that
8
didn't actually have this. I think I have two copies.
9
MADAM HEARING OFFICER: If there's no
10
objection, we will mark this as Exhibit No. 32. Seeing
11
none, "Mercury Deposition in the Great Lakes Region,
12
James Keeler, University of Michigan Air Quality
13
Laboratories" is marked as Exhibit 32.
14
(Exhibit No. 32 was admitted.)
15
MR. KIM: I believe this is maybe in
16
more specific with some nice pictures, but it's,
17
essentially, everything that -- there is a Far Side
18
cartoon I think it's pretty much a Powerpoint
19
presentation of everything that's been testified to thus
20
far, but we did want to make sure we got that in. It
21
took a little while because it was all in color and we
22
had technical difficulties. We have no more color ink
23
left in the building.
24
MADAM HEARING OFFICER: The other item
Page130
1
that we discussed this morning was the emissions data
2
that was a part and a map. Mr. Matoesian was talking
3
about that this morning and you said you would get that
4
for us.
5
MR. KIM: Yes.
6
MADAM HEARING OFFICER: Are we still
7
in the process of looking for that?
8
MR. KIM: That's information that we
9
are going to have to print out I think from U.S. EPA's
10
website, so that might -- we'll get that, but it may not
11
be until Monday or Tuesday.
12
MADAM HEARING OFFICER: That's fine.
13
I just wanted to double check on that.
14
MR. KIM: We have four copiers on the
15
Division of Legal Counsel floor. At any given time, one
16
of them is working, so I'm assuming that ratio holds
17
true throughout the Agency.
18
MADAM HEARING OFFICER: Is there
19
anything else for Dr. Keeler?
20
MR. RIESER: Maybe one thing to do.
21
Obviously, we visually observed the LADCO report at the
22
time it was given, but we haven't had a chance to look
23
at it. Perhaps if Dr. Keeler can sit for another hour
24
or, so maybe we can proceed with Dr. Hornshaw give us a
Page131
1
chance to look at this, and then if we can come back.
2
It shouldn't take that long, but I just need to check to
3
see if there's any other questions.
4
MADAM HEARING OFFICER: Is that
5
possible, Dr. Keeler?
6
DR. KEELER: That's about right. I
7
have another hour and 10 minutes.
8
MR. RIESER: If it would help, the
9
minute I'm ready to ask some questions, if I have any
10
one way or the other, I can put my hand up. I hate to
11
interrupt the flow of somebody else's questioning.
12
MR. KIM: Two airlines in Springfield,
13
so I think our people are just struggling to hold on to
14
the reservations they have got, but that's fine. If,
15
during his testimony you want to just interrupt, that's
16
fine with us.
17
MADAM HEARING OFFICER: Then shall we
18
begin with Dr. Hornshaw? Before that, Dr. Keeler I want
19
to, personally, thank you very much. It's been very
20
enlightening.
21
22
23
24
Page132
1
STATE OF ILLINOIS)
2
COUNTY OF ST. CLAIR)SS
3
4
I, Holly A. Schmid, a Notary Public in
5
and for the County of Williamson, DO HEREBY CERTIFY that
6
pursuant to agreement between counsel there appeared
7
before me on June 16, 2006, at the office of the
8
Illinois Pollution Control Board, Springfield, Illinois,
9
Dr. Gerald Keeler, who was first duly sworn by me to
10
testify the whole truth of his knowledge touching upon
11
the matter in controversy aforesaid so far as he should
12
be examined and his examination was taken by me in
13
shorthand and afterwards transcribed upon the typewriter
14
(but not signed by the deponent, his signature having
15
been waived by agreement of counsel) and said deposition
16
is herewith returned.
17
IN WITNESS WHEREOF I have hereunto set
18
my hand and affixed my Notarial Seal this 30th day of
19
June, 2006.
20
__________________________
21
HOLLY A. SCHMID
22
Notary Public -- CSR
23
084-98-254587
24
Page133