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    ILLINOIS POLLUTION CONTROL BOARD
    June 16, 2006
    2
    IN THE MATTER OF
    )
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    )
    PROPOSED NEW 35 ILL ADM. CODE) R06-25
    4
    225 CONTROL OF EMISSIONS FROM) (Rulemaking - Air)
    LARGE COMBUSTION SOURCES )
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    (MERCURY)
    )
    6
    TESTIMONY OF DR. GERALD KEELER
    7
    PART II
    8
    BEFORE MARIE E. TIPSORD
    HEARING OFFICER
    9
    10
    The testimony of Dr. Gerald Keeler, a
    witness called in the rulemaking proceeding before the
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    Illinois Pollution Control Board taken on June 16, 2006,
    at 9:00 a.m., at the offices of the Environmental
    12
    Protection Agency, Springfield, Illinois, before Holly
    A. Schmid, Notary Public and Certified Shorthand
    13
    Reporter, CSR No. 084-98-254587 for the State of
    Illinois.
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    Page1

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    A P P E A R A N C E S
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    MEMBERS OF THE ILLINOIS POLLUTION CONTROL BOARD:
    Ms. Marie E. Tipsord, Hearing Officer;
    3
    Dr. G. Tanner Girard, Board Member;
    Ms. Andrea S. Moore, Board Member;
    4
    Mr. Anand Rao, Board Staff;
    Mr. Thomas Johnson, Board Staff;
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    Mr. Tim Fox, Board Staff;
    Mr. Nicholas Melas, Board Staff;
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    Ms. Alisa Liu, Board Staff.
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    COUNSEL FOR THE ILLINOIS
    ENVIRONMENTAL PROTECTION AGENCY:
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    Mr. Charles Matoesian;
    Ms. Gina Roccaforte;
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    Mr. John Kim;
    Mr. Richard Ayres;
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    COUNSEL FROM SCHIFF-HARDEN
    Ms. Kathleen Bassi;
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    Mr. Stephen Bonebrake;
    Mr. Sheldon Zabel;
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    Mr. Jim Ingram, Dynegy, Inc.
    14
    COUNSEL FROM JENNER & BLOCK
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    Mr. Bill Forcade;
    Ms. Katherine Rahill.
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    COUNSEL FROM McGUIRE-WOODS:
    17
    Mr. James Harrington;
    Mr. David Rieser.
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    COUNSEL FROM THE CHICAGO LEGAL CLINIC
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    Mr. Keith I. Harley
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    COUNSEL FROM MIDWEST GENERATION
    Mr. Basil G. Constantelos
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    Page2

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    IDENTIFICATION
    PG.
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    Exhibit 29:
    5
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    Exhibit 30:
    5
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    Exhibit 31:
    95
    7
    Exhibit 32:
    130
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    Page3

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    MADAM HEARING OFFICER: Good morning,
    2
    everyone. Welcome back. This is day five, and we're
    3
    making some good progress.
    4
    My name is Maria Tipsord. I'm the
    5
    hearing officer in this proceeding in No. RO6-25. My
    6
    opening will be fairly truncated, since I don't see any
    7
    new faces.
    8
    I just want to introduce the panel to
    9
    you today. Board member Dr. G. Tanner Girard; Board
    10
    Member Anand Rao; the far right Nicholas Melas. To my
    11
    far left, Tom Johnson, also a board member. Our
    12
    technical unit today is represented by Anand Rao. Tim
    13
    Fox is with us again today, and Matt Reed is joining us
    14
    today with the board staff.
    15
    Before we go back to Dr. Keeler's
    16
    testimony, Mr. Rieser, I believe you were going to have
    17
    some exhibits for me this morning.
    18
    MR. RIESER: Why, yes, I do. We have
    19
    copies of the preliminary results of Steubenville. I'm
    20
    giving one to Mr. Harley, right off the bat, "The
    21
    Preliminary Results for Steubenville Mercury Deposition
    22
    Source Apportionment Study" from Tim Opelt, April 27,
    23
    2005. I don't recall what number you have that at.
    24
    MADAM HEARING OFFICER: We're going to
    Page4

    1
    mark that as Exhibit 29, if there's no objection.
    2
    Seeing none, that will be Exhibit 29.
    3
    (Exhibit 29 was admitted.)
    4
    MR. RIESER: Then the second one is
    5
    "The Ambient Measurements to Support Coal Combustion
    6
    Emission Research" October 21, Beijing, China presented
    7
    by Matthew S. Landis, 2005. Again, we are presenting a
    8
    copy to Mr. Harley. We'll mark that as Exhibit No. 30,
    9
    if there's no objection. Seeing none, we will mark that
    10
    as Exhibit No. 30.
    11
    (Exhibit 30 was admitted.)
    12
    MS. BASSI: What was 29?
    13
    MADAM HEARING OFFICER: 29 is the
    14
    preliminary results. And "The Ambient Measurement" is
    15
    the title page on the second one. That will be Exhibit
    16
    30. Thirty is the Beijing study; 29 is the U.S. EPA
    17
    preliminary. Have we got the exhibits straightened out?
    18
    Has everybody got 29 and 30? I believe we are ready to
    19
    start with Question No. 10 for Dr. Keeler.
    20
    DR. KEELER: Question No. 10: "In
    21
    using the source-receptor approach to determine the
    22
    source of wet deposition mercury, is it accurate that
    23
    you determine the source by analyzing for other
    24
    constituents associated with those sources? A, does
    Page5

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    that analysis demonstrate the proximity of those
    2
    sources? B: Does this analysis differentiate among
    3
    different types of coal used?" I assume you're asking
    4
    source receptor modeling approach not -- in using the
    5
    source-receptor approach.
    6
    MR. RIESER: Correct.
    7
    DR. KEELER: If you're referring to
    8
    the multivarious statistical analysis approach, it does
    9
    not demonstrate the proximity of the sources, so the
    10
    answer to A is no. If you're asking about the combined
    11
    hybrid receptor modeling approach, the answer is yes, so
    12
    just to differentiate --
    13
    MR. RIESER CONTINUES:
    14
    Q. Just for the record I note that the term
    15
    source-receptor study is the one that you used in your
    16
    testimony. For example, in this second paragraph of the
    17
    conclusion, we talked about, on page 5, that says,
    18
    "Source receptor studies have recently been completed
    19
    that indicate the coal-fired utilities contributed,
    20
    approximately, 70 percent of the mercury," so it wasn't
    21
    a term I made up. It was something that I thought I
    22
    took directly from your testimony.
    23
    A. Right. All the methods that we use are
    24
    looking for source-receptor relationships, and I was
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    just asking a clarifying question. That's all. It's a
    2
    correct use of the term.
    3
    Q. Thank you.
    4
    DR. KEELER: Question No. 11 -- just
    5
    so it's clear, B, the answer was no. "In your
    6
    testimony, you state that coal combustion was clearly
    7
    dominant, in terms of explaining the mercury deposition,
    8
    approximately, 70 percent. What is the basis for this
    9
    figure?" Do you want me to answer this again?
    10
    MR. RIESER: Yes, please.
    11
    DR. KEELER: This was the average of
    12
    the results of the PMF and the Unmixed models.
    13
    MR. RIESER CONTINUES:
    14
    Q. Of the two years, correct?
    15
    A. For the two years.
    16
    Q. 2003 and 2004?
    17
    A. Right, for the two-year combined analysis.
    18
    Q. There were differences in meteorology
    19
    between the two years, were there not?
    20
    A. Yes, there was. I said the deposition was
    21
    quite different between the two years.
    22
    Q. And in 2004, if I recall your testimony,
    23
    was dominated by four major precipitation events. Is
    24
    that correct?
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    A. Actually, I don't recall saying four, but
    2
    if that's what I said.
    3
    Q. I think you said "several" I'm sorry, but
    4
    it was dominated by several large precipitation events?
    5
    A. Yes, that's correct.
    6
    Q. And in what way was it dominated by those
    7
    events?
    8
    A. Those were very large deposition totals
    9
    relative to the total amount for the entire year.
    10
    Q. And what does that mean with respect to
    11
    your findings, if any?
    12
    A. Well, in one respect what it means is that
    13
    for a model, such as a deterministic model, if a missed
    14
    accurately calculating the deposition for that one
    15
    event, it will significantly alter their source-receptor
    16
    relationship and the ultimate approportionment of
    17
    whatever came from whatever source.
    18
    Q. I'm sorry. What does its mean for the
    19
    findings of the receptor study, the one you performed?
    20
    A. Not much. I mean, it's just another
    21
    example. I was highlighting the fact that it can have a
    22
    few single events that can lead to very large
    23
    deposition, and it's important in a sense of if one is
    24
    trying to compare the results of a CMAQ or TEAM, or that
    Page8

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    type of a model to a receptor modeling that those single
    2
    events are very, very important, in terms of the overall
    3
    deposition to that location for the entire year, and so
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    not accurately predicting them is a major error, so that
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    was the purpose in my presentations and in my comment.
    6
    Q. Does it also suggest that source-receptor
    7
    done in a year with -- let me ask this, did you consider
    8
    -- and I do see in your testimony it's "a few large
    9
    precipitation events," I'm sorry. Is it your belief
    10
    that these large precipitation events were unusual with
    11
    the relationship to the typical weather in Steubenville?
    12
    A. They are not unusual in the sense that we
    13
    see these large events, typically at every site that we
    14
    measure. The sites in Michigan, the sites in Vermont,
    15
    the sites in Florida, we'll see a couple of very large
    16
    events that contribute a fairly large percentage of the
    17
    total deposition in all the sites that we make
    18
    measurements at.
    19
    Q. Is it accurate that several of these
    20
    precipitation events you observed in Steubenville were
    21
    results of hurricanes that came up from the Gulf of
    22
    Mexico?
    23
    A. Two of the events were the result of
    24
    cyclones that came up from the Gulf. They were the
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    remnants of hurricanes and provided very large amounts
    2
    of precipitation.
    3
    Q. Had you done the study in 2004, and only
    4
    had the 2004 data, would that have skewed the data
    5
    higher than the usual data that you would see for
    6
    Steubenville because of the large precipitation events?
    7
    A. No.
    8
    Q. In what way would it not?
    9
    A. It turns out that, for those large
    10
    precipitation events, the source-receptor model
    11
    underestimated the total deposition for those events,
    12
    and in fact, underestimates them quite a bit. Extreme
    13
    events in statistical analyses tend to be smoothed out,
    14
    so those couple big events, in terms of the deposition
    15
    -- they were over a microgram per square meter per event
    16
    -- were underestimated, and therefore, would not have
    17
    overestimated or given more of an emphasis to those
    18
    events.
    19
    Q. But you stated in your testimony that, at
    20
    least, one of those events added 8 percent of the total
    21
    mass of mercury to the amount of mercury observed for
    22
    the year 2004.
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    A. That's correct.
    24
    Q. And you don't consider that a significant
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    additional amount based on that one storm?
    2
    A. No. The point of my testimony was that it
    3
    does -- 8 percent is a significant additional amount,
    4
    but you asked the question whether that had a
    5
    significant impact on the results of our source-receptor
    6
    modeling, and I said no.
    7
    Q. I understand. I see where the four event
    8
    comes from. I'm sorry, Madam Hearing Officer. Which
    9
    was the Beijing?
    10
    MADAM HEARING OFFICER: The Beijing
    11
    study is 30?
    12
    MR. RIESER CONTINUES:
    13
    Q. Thank you. If you turn to Exhibit 30,
    14
    there is an "EPA PMF Estimated, versus Measured Mercury
    15
    Deposition."
    16
    A. Yes, I see that.
    17
    Q. And it's a graph comparing mercury
    18
    deposition in events, and there are four peaks, at
    19
    least, four large peaks that are larger than the other
    20
    peaks in that graph.
    21
    A. Correct.
    22
    Q. Do those represent the significant
    23
    precipitation events that you discussed?
    24
    A. Those are, yes.
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    Q. So would you agree that, in order for the
    2
    source-receptor -- excuse me -- receptor modeling to --
    3
    strike that. Let's go on to the next question.
    4
    DR. KEELER: "What range of values is
    5
    represented by this approximate value?" An approximate,
    6
    that is. I'm sorry. What did I say?
    7
    MR. RIESER: I thought I heard you say
    8
    an approximate.
    9
    DR. KEELER: "An approximate" it says.
    10
    I'm sorry, if I mumbled my words. The PMF and Unmixed
    11
    numbers, if I said I think PMF came out to be,
    12
    approximately, 70, might have been 69, and Unmix was 74,
    13
    and so that's where the number of, approximately, 70.
    14
    That wasn't meant to be a mathematically-rounded number,
    15
    by any means. It was supposed to be an approximation.
    16
    MR. RIESER CONTINUES:
    17
    Q. I asked this, I suppose, indeed, but is
    18
    there a plus or minus range associated with that?
    19
    A. Yeah. As I said yesterday, I believe the
    20
    uncertainty, if you do it the same way for both of the
    21
    models, is around 15 percent.
    22
    Q. Thank you.
    23
    DR. KEELER: The question is asking,
    24
    "What is the purpose of expressing this as an
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    approximate value?" For the purpose of simplicity, and I
    2
    have already answered what level of uncertainty to place
    3
    on this figure, which is the 15 percent. Question 12:
    4
    "You state that `a meteorological analysis corroborates
    5
    that a substantial amount of the mercury deposition
    6
    found at the Steubenville site was due to local and
    7
    regional sources."
    8
    MR. RIESER CONTINUES:
    9
    Q. Let me stop you. You use the term
    10
    "corroborate." What findings do you have, aside from
    11
    the meteorologic, that indicate a substantial amount of
    12
    mercury was due to local and regional sources?
    13
    A. Well, if one takes the emission
    14
    inventories for the region for mercury, and looks at the
    15
    amount of mercury and other constituents that are there,
    16
    one can then see that the largest contributor in the
    17
    emissions inventory in that region is actually
    18
    coal-fired utilities, so again, that's what I'm saying
    19
    is we, again, find that this matches up with what the
    20
    EPA emission inventory tells us.
    21
    Q. The emissions inventory is of emissions,
    22
    not deposition, correct?
    23
    A. It is emissions inventory. It's the
    24
    actual amount of emissions estimated from the source.
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    Q. So the emissions inventory doesn't, in and
    2
    of itself, tell you what the deposition is, does it?
    3
    A. No, it does not, unless you use a
    4
    deterministic model to model from emissions to
    5
    deposition?
    6
    Q. As I understand it, you did not use a
    7
    deterministic model?
    8
    A. No, I did not.
    9
    Q. And so in what way did you arrive at the
    10
    finding through your study that a substantial amount of
    11
    mercury deposition found at the Steubenville site was
    12
    due to local and regional sources?
    13
    A. When one does a source-receptor modeling,
    14
    one will often take the data, do the analysis, determine
    15
    an estimate of what a local source contributions and
    16
    regional source contributions are and then use the local
    17
    emissions inventory to what we call -- it's not a
    18
    validation. It's a comparison to the results that you
    19
    find. It doesn't make sense, in terms of what was
    20
    emitted in the region, to what you actually predicted.
    21
    This is a very common practice. It's done in a lot of
    22
    receptor modeling results. For example, if you estimate
    23
    that diesel emissions are an important emissions are
    24
    important and go to an area, and there are no diesel
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    trucks estimated to have emissions in that area, then
    2
    you find your results very unsatisfying.
    3
    Q. What is it about the emissions inventory
    4
    that allows you to make a qualitative statement with
    5
    respect to the deposition in the area, as you say, it's
    6
    a substantial amount that was due to local and regional
    7
    sources?
    8
    A. Are you asking me about the emissions
    9
    inventory?
    10
    Q. I'm asking you what about the emissions
    11
    inventory allows you to make the statement that a
    12
    substantial amount of mercury deposition found at the
    13
    Steubenville site was due to local and regional sources?
    14
    A. We have observational evidence that shows
    15
    us that, when we have high concentrations of reactive
    16
    mercury in the atmosphere, we would expect that to be
    17
    removed fairly close by precipitating systems. Taking
    18
    this understanding of the processes, one can then take
    19
    and use that understanding when looking at, okay, here
    20
    are emissions that are, to a large fraction, greater
    21
    than 50 percent as estimated by the utilities to a
    22
    common form of reactive mercury. When one goes and
    23
    looks at when and where the precipitation fell, one can
    24
    then make an estimate that this mercury would have been
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    removed through wet deposition in that area.
    2
    Q. How do you know what the amount of
    3
    reactive gaseous mercury is emitted by the sources
    4
    around Steubenville?
    5
    A. It's in the emissions inventory.
    6
    Q. The amount of reactive gaseous mercury is
    7
    in the inventory?
    8
    A. That's right. They provide an estimate of
    9
    the percentage of reactive mercury, particulate mercury
    10
    and elemental mercury that's emitted from each source.
    11
    Q. Did you do anything to -- the emissions
    12
    inventory is from 1999. Is that correct?
    13
    A. That's correct.
    14
    Q. Did you do anything to evaluate whether
    15
    that emissions inventory was still accurate as of the
    16
    time you did your study?
    17
    A. We only have the data that is presented to
    18
    us, so the answer would be no. There was no follow-up.
    19
    We can only use the information that is provided to us,
    20
    so the same information that all the modelers use.
    21
    Q. Could you have taken steps to -- strike
    22
    that. Put it this way, yesterday, when I asked you
    23
    about the sources that were nearby, you said that you
    24
    didn't know what they were, and you directed us to the
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    EPA map.
    2
    A. I don't think that's what I said, that I
    3
    didn't know what they were. You asked me how many,
    4
    specifically, and how much power was produced by the
    5
    plants, and I believe I answered I didn't have that
    6
    number in front of me.
    7
    Q. Did you have --
    8
    A. I know exactly where the sources are, not
    9
    just the coal-fired utility, but all of the other
    10
    sources in the vicinity.
    11
    Q. Did you have that number in front of you
    12
    when you performed your study?
    13
    A. We combine all the analysis tools that we
    14
    have including the emissions inventories, the maps
    15
    showing the locations of all the sites, how much of the
    16
    mercury is emitted from all those, and trying to
    17
    understand the results of our modeling, yes.
    18
    Q. Now, of course, we are limited in that we
    19
    don't actually have a copy of your study, but were there
    20
    maps showing the locations of the power plants, the coal
    21
    used, and then megawattage included as part or your
    22
    study?
    23
    A. The publication has a map showing all the
    24
    locations of the coal-fired utilities based on the 1990
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    1
    information that was provided -- 1999, excuse me. I
    2
    misspoke. And I would have to go back and remember if
    3
    in the manuscript version that we submitted, whether it
    4
    had anything showing the actual amount of mercury that
    5
    was emitted from each stack. I don't recall that, but
    6
    it does show, geographically, where the plants were
    7
    located.
    8
    Q. So your report identifies specific power
    9
    plants as contributing to the mercury levels that you
    10
    observed in Steubenville. Is that correct?
    11
    A. No. As I mentioned yesterday, the
    12
    receptor modeling approach does not allow you to
    13
    identify a particular power plant. It identifies source
    14
    contributions from coal combustion.
    15
    Q. Then what was the point of including a map
    16
    of certain power plants in your study?
    17
    A. It's very important when you're publishing
    18
    any type of paper in international journals to show
    19
    people the location of where you are studying and the
    20
    major emissions sources in that vicinity. This is
    21
    common practice in the scientific literature.
    22
    Q. So the point was just to show the
    23
    location. Did you have other features, such as items of
    24
    historical interest in Steubenville?
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    A. This was a scientific peer-reviewed
    2
    literature paper. It's not a historical overview of the
    3
    area of Steubenville.
    4
    Q. I'm trying to understand why, if the point
    5
    of a receptor study, such as the one you performed, is
    6
    that it's not, A, can't use it to identify specific
    7
    sources, and B, it's not important to know what those
    8
    sources are, I'm trying to understand why you would
    9
    identify specific sources within the study, itself.
    10
    A. Again, you have misinterpreted and
    11
    misquoted what I said. A, I did not say it was not
    12
    important to know are the individual sources are. B, I
    13
    didn't say that individual sources are not important,
    14
    and I've been working in Eastern Ohio, Western
    15
    Pennsylvania air shed understanding the sources of, not
    16
    just mercury, but other compounds for over 20 years. I
    17
    have driven that area myself more hours than I can tell
    18
    you. I have spent an enormous amount of time on the
    19
    grown. I have actually gone around and photographed the
    20
    sources. Identified that, in fact, they were in the
    21
    locations that were given because, in the early days, we
    22
    were given locations for plants that actually didn't
    23
    coincide with where the plants were located, so we
    24
    actually went and verified that they were there, so I
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    1
    have a long historical context, in terms of the research
    2
    I have been doing in that area. I published my first
    3
    source receptor paper on aerosols and their sources in
    4
    the Southwestern Pennsylvania area in 1986, so this is
    5
    not something that is new to me, and I think, from over
    6
    20 years worth of scientific experience, I believe I
    7
    have a good sense for what information is important to
    8
    provide in a scientific peer-reviewed paper and what's
    9
    not, and so I'm not sure why you keep saying I'm
    10
    referring to these things as being unimportant.
    11
    Q. Well, in your testimony, on page four, in
    12
    the paragraph that begins, "Multivariant statistical
    13
    receptor models have been successfully used to apportion
    14
    sources of mercury deposited in South Florida and
    15
    elsewhere." What you say after that in the next
    16
    sentence is, "These techniques have the advantage of not
    17
    requiring prior measurements of source profiles or
    18
    emission inventories." Similarly, in your report, which
    19
    is attached as Exhibit B, and I believe it's on page 18,
    20
    again, in a paragraph that begins with the statement,
    21
    "Regarding multivariant statistical receptor models,"
    22
    there's a sentence right before the end of the paragraph
    23
    that says, "Again, both techniques referring to
    24
    statistical techniques such as Unmix and deposit matrix
    Page20

    1
    factorization, both techniques have the advantage of not
    2
    requiring prior measurements and source profiles or
    3
    emission inventories." So since you identify an
    4
    important, positive point that it doesn't require -- the
    5
    studies you performed don't require emissions
    6
    inventories, I'm having trouble understanding what role
    7
    they have to play in the findings that you make, and
    8
    obviously, I'm hampered that I don't have the actual
    9
    report in front of me.
    10
    A. I will try to say it again in a different
    11
    way, so perhaps it's more clear. Receptor modeling
    12
    allows you to estimate the source contributions by
    13
    source category for the pollutants that you're looking
    14
    at. It does not identify the specific stack or source,
    15
    a specific company that emitted the pollutant. You
    16
    asked the question about corroboration, and this is how
    17
    we got into discussing emissions and emissions
    18
    inventories, what we call "source reconciliation." If
    19
    one does a receptor modeling study, one that comes to
    20
    mind is one Glenn Kass did in the early 70's looking at
    21
    the sources in the Los Angeles Basin. He was looking at
    22
    the source of L and L carbon (phonetic) and basically,
    23
    did a receptor modeling very similar to what we done in
    24
    this study, and estimated the contributions to L and L
    Page21

    1
    carbon and then went, as a corroborating piece of
    2
    information, took the inventory that estimated, from a
    3
    source perspective, how much carbon came from all the
    4
    sources in LA to see if he could get an approximate
    5
    balance. What goes up, has to come down. If you
    6
    estimate an overabundance of material that you can't
    7
    corroborate with observations or with emissions
    8
    estimates, then it gives you some idea that the
    9
    emissions are not correct or that there are other
    10
    sources contributing that perhaps the emission inventory
    11
    didn't conclude, so this is a standard practice in the
    12
    field, but it does not require -- receptor modeling does
    13
    not require the use of emissions data.
    14
    Q. Did you quantify the amount of mercury
    15
    deposition that you expected to find in Steubenville
    16
    based on the emissions inventory?
    17
    A. No, sir.
    18
    Q. In what way did the review of the
    19
    emissions inventory, then, corroborate the finding that
    20
    a substantial amount of mercury deposition found at the
    21
    Steubenville site was due to local and regional sources?
    22
    MADAM HEARING OFFICER: With all due
    23
    respect, I think that's where this all started. I think
    24
    he answered that question in the beginning.
    Page22

    1
    MR. RIESER: Well, I'm really limited
    2
    here because I don't think he did answer the question.
    3
    He said he looked at the inventory and that supported
    4
    the finding that a substantial amount of mercury
    5
    deposition found at the Steubenville site was due to
    6
    local and regional studies because that finding is
    7
    corroborated by other information I have to assume
    8
    that's a finding, and again, I don't have the report in
    9
    front of me.
    10
    MADAM HEARING OFFICER: You have made
    11
    that point several times this morning, as well.
    12
    MR. RIESER: Right, but the point
    13
    being says he looked at the emissions inventory. We
    14
    don't know what plants he looked at. We don't know what
    15
    particular things he found. We don't know whether this
    16
    was a qualitative or quantitative finding of his.
    17
    MADAM HEARING OFFICER: I understand
    18
    that, but he has also repeatedly stated that the
    19
    receptor modeling does not look at individual plants.
    20
    It looks at a source category. Am I characterizing that
    21
    correctly?
    22
    DR. KEELER: Correct.
    23
    MR. MATOESIAN: Yes, and he's answered
    24
    that several times, category of sources you can trace
    Page23

    1
    back to.
    2
    MR. RIESER: Thank you.
    3
    DR. KEELER: Just for the record, I
    4
    did state that we use the emissions inventory from the
    5
    1999 modeling that EPA did, the same inventory that was
    6
    used in the CAMR Rule, and we looked at all the
    7
    emissions for the entire Midwest, and actually, for all
    8
    the entire Eastern United States, so --
    9
    MR. RIESER:
    10
    Q. What I would like, then, is a list of the
    11
    plants that Dr. Keeler identified as being the plants
    12
    that he looked at the inventory for to identify the
    13
    amount of mercury that corroborated this finding.
    14
    A. It's the entire list that's in the CAMR
    15
    Rule, so if you want the entire listing, you can get
    16
    that on the EPA website.
    17
    MADAM HEARING OFFICER: Once again,
    18
    Dr. Keeler, when you start telling us to get stuff, that
    19
    means the Agency needs to provide it to us, if you have
    20
    not already. We need that as an exhibit.
    21
    MR. RIESER CONTINUES:
    22
    Q. I'm sorry, the entire list of all power
    23
    plants in the country?
    24
    A. That's the list we used and we looked at
    Page24

    1
    the plants east of the Mississippi.
    2
    Q. Did you look at a specific range of plants
    3
    for this study, all the plants in the Mississippi --
    4
    A. We did not look at specific plants, as I
    5
    said earlier. We looked at the region.
    6
    Q. Well, I'm --
    7
    A. We didn't identify -- we did not identify
    8
    individual plant contributions that are in the receptor
    9
    modeling, or in terms of trying to understand the
    10
    contribution of a particular plant. That's not in the
    11
    scope of the work that we did.
    12
    MR. RIESER: I don't think it's unfair
    13
    to ask what plants, to get a list of the plants.
    14
    MADAM HEARING OFFICER: I have already
    15
    asked them.
    16
    MR. RIESER: I'm hearing "region" and
    17
    "list." I'm not hearing, "I looked at these plants,"
    18
    and I'm assuming there is a list.
    19
    MR. MATOESIAN: He stated this --
    20
    MR. RIESER: I'm not done talking.
    21
    I'm assuming there is a list of plants that he looked at
    22
    because he describes, "We looked at these RGM's, and we
    23
    calculated the RGM's with the" -- blah, blah blah, and
    24
    that's what we need to corroborate, the meteorological
    Page25

    1
    findings, so I would like a list of those plants.
    2
    MR. MATOESIAN: I believe you directed
    3
    us to provide that and as he stated, it was a list of
    4
    plants east of the Mississippi, I believe.
    5
    DR. KEELER: Right.
    6
    MS. BASSI CONTINUES:
    7
    Q. Sorry to jump into this fray, but please
    8
    correct me if I'm wrong, and that's my question. I
    9
    thought, at one point, you said that, in your
    10
    manuscript, or in your published data, or some place,
    11
    there was a map on which you identified the plants that
    12
    were in the region or in the vicinity or in the local
    13
    area, or however you defined it, but it sounded to me as
    14
    if you were saying that there were certain power plants,
    15
    perhaps, other types of sources that were on a map
    16
    around the Steubenville area that is plotted on a map
    17
    that you have identified as dots on a map. Is that
    18
    correct?
    19
    A. That's correct. In the submitted version
    20
    of the paper we submitted, a figure, which had a copy --
    21
    I mean had a spot showing the location of the
    22
    Steubenville site, and then had within -- I would say it
    23
    showed the greater Steubenville area, including most of
    24
    Ohio, half of Pennsylvania, down to the south of it, up
    Page26

    1
    to the north. It didn't include a large area. It was
    2
    really meant to show where Steubenville is, but it did
    3
    include a point showing a major source of mercury from
    4
    the `99 inventory plotted on that.
    5
    Q. Then somehow that got expanded to the
    6
    entire emissions inventory used in the CAMR?
    7
    A. Because there are two different questions.
    8
    One was asking a question about figures, and one was
    9
    asking what we look at when we look at the emissions,
    10
    and I was trying to be clear about that.
    11
    Q. So when you looked at the emissions to
    12
    corroborate your findings from your study, you were
    13
    looking at more than just what was plotted on your map.
    14
    Is that correct?
    15
    A. That is correct.
    16
    MR. ZABEL CONTINUES:
    17
    Q. Maybe this is obvious, but it seems to me
    18
    we have been dancing around the question of why we can't
    19
    get a copy of the draft report.
    20
    A. It's not a report. It's a manuscript that
    21
    was submitted to a scientific journal that's in the
    22
    review process. We've already been given reviews, and
    23
    we're in the process of finalizing that paper. The
    24
    paper will be provided to everyone, once the paper is
    Page27

    1
    sent for publication. One other thing that is very
    2
    difficult today, especially when doing environmental
    3
    research, is to maintain the integrity of the scientific
    4
    research publication process, and one of the reasons why
    5
    we didn't want to make presentations and do briefings in
    6
    front of the EPA, until we had our final analysis was
    7
    because these results, then, get misinterpreted. People
    8
    that don't do scientific research often don't understand
    9
    the process that science is -- you learn as you go. You
    10
    make corrections and improvements to the scientific
    11
    research that you are doing, and that, at times, if you
    12
    don't have the data that you would like at hand, you get
    13
    that data, and people provide new data. You submit your
    14
    information and you refine your analysis, and if
    15
    versions of publications are going around prior to you
    16
    actually submitting it to the peer-reviewed literature,
    17
    then the whole process becomes -- basically, the
    18
    integrity of the process disappears.
    19
    Q. I'm sorry. My question wasn't answered.
    20
    A. I'm saying that this hearing has come at a
    21
    time where the paper has not come out in press, yet, so
    22
    that's the reason why the paper hasn't been provided.
    23
    Q. I perfectly understand that. I want to
    24
    know is there some legal reason why we cannot have that
    Page28

    1
    document as it exists today? They are asking this Board
    2
    to rely on what you're saying is in that paper. We have
    3
    no chance to judge that. If I were in litigation, I
    4
    could get it in Discovery. I could order it produced.
    5
    They want this Board to rely on what Dr. Keeler is
    6
    telling us. I have no reason to think he's not telling
    7
    us the truth, but I can't check it. I don't know of a
    8
    legal reason -- if there is one, counsel can tell me --
    9
    why we can't have copy of that draft.
    10
    MADAM HEARING OFFICER: I actually
    11
    believe that yesterday Dr. Keeler invoked intellectual
    12
    property.
    13
    MR. ZABEL: Then he can have it under
    14
    confidentiality. We won't publish it. That's not the
    15
    point.
    16
    DR. KEELER: I'm not sure how to
    17
    answer you. I just know that I know that, in terms of
    18
    the scientific peer review process, this is not
    19
    appropriate and --
    20
    DR. GIRARD: Could I ask a question.
    21
    You say it's been reviewed. Have you already submitted
    22
    the revised paper to the journal?
    23
    DR. KEELER: No, we have not. It's --
    24
    right now it's under going, again, another level of
    Page29

    1
    review at the Agency, so it's not a finalized document,
    2
    yet, and that's the main reason why -- if I hadn't
    3
    submitted the final version, I would have no problem
    4
    with sharing that, but again, this is -- it's one of
    5
    these thing that it's just not done this way.
    6
    MR. RAO: And based on the comments
    7
    you have received from this peer-review committee, does
    8
    it change your results or conclusions in any way?
    9
    DR. KEELER: No, it does not.
    10
    MS. MOORE: Is the peer view committee
    11
    looking at it now within the EPA?
    12
    DR. KEELER: Yes. It's an internal
    13
    review.
    14
    MS. MOORE: Given the fact that your
    15
    findings are U.S. EPA excuse me -- are a little
    16
    different than the direction that the U.S. EPA has
    17
    thought to go in regard to mercury, don't you think
    18
    there would be some chance that the release of this
    19
    paper might be held for some period of time for further
    20
    and further and further peer review?
    21
    DR. KEELER: I don't believe they,
    22
    legally, can hold up the publication. I'm the one that
    23
    has to then make a determination that, okay, we are not
    24
    going to wait anymore, so we have a deadline of July 1
    Page30

    1
    to return the final version of the paper to the Journal,
    2
    and so that's the drop dead deadline for all of their
    3
    discussions and review, no matter what, in my mind.
    4
    MS. MOORE: So July 1 it would
    5
    actually be available?
    6
    DR. KEELER: That should be -- that's
    7
    correct. It should be available around the July 1 time
    8
    frame.
    9
    MS. MOORE: It would be pretty clear
    10
    to you then if there were some other reason they didn't
    11
    want to release it, not that that kind of thing would
    12
    ever happen.
    13
    MS. BASSI: Certainly not in Illinois.
    14
    DR. KEELER: I think that's correct.
    15
    MR. ZABEL CONTINUES:
    16
    Q. Is my understanding correct, Doctor,
    17
    that's the version you would be willing to release, the
    18
    July 1 version?
    19
    A. The version that we will submit as a final
    20
    version to the Journal will be the one I'm happy to
    21
    share.
    22
    Q. Then I guess my only inquiry would be
    23
    whether we can have Dr. Keeler back after our experts
    24
    have had a chance to study that.
    Page31

    1
    A. It all depends on when.
    2
    MR. RIESER: It would be my
    3
    suggestion, frankly, that, if it's going to be released
    4
    by July 1, it would be my suggestion we just halt the
    5
    cross-examination here --
    6
    MADAM HEARING OFFICER: We're not
    7
    going to halt the cross-examination because, if it
    8
    doesn't happen July 1, and we're right here arguing
    9
    about whether or not the Steubenville study is going to
    10
    be issued. We're -- we'll continue on.
    11
    Here's what I'm going to do. I'm
    12
    going to direct the Agency to provide a copy of the
    13
    Steubenville report no later than July 5. If it can't
    14
    be available by July 5, then I will be willing to hear
    15
    motions at that point.
    16
    MR. ZABEL: I will have a motion at
    17
    that point, Madam Hearing Officer.
    18
    MADAM HEARING OFFICER: I just want to
    19
    put it off, in case we can get to --
    20
    MR. ZABEL: I will reserve my motion,
    21
    until the end of the Fourth of July holiday.
    22
    DR. KEELER: Can I just make one
    23
    point? I'm not going to be in town -- I'm actually going
    24
    to be in the field, until about July 10, so I'm not
    Page32

    1
    going to be dealing with this at all. I told you July
    2
    1, just so that you would know that that's when we have
    3
    to do it, but I'm not going to be in town to be able to
    4
    do anything in regards to this, until I get back on
    5
    about July 10. I think I get back to town late on July
    6
    9, so putting a date of July 5 is not going to work for
    7
    me. I'm just telling you. I have other commitments
    8
    that I have made previously. This hearing got postponed
    9
    from May, to now, and I had to cancel two different
    10
    trips that I had planned for June in order to be here
    11
    this week, and I can't cancel any more in the future
    12
    because it involves field work, and I have contracts
    13
    that are obligating me to be in the field.
    14
    MR. RIESER: We're just asking for the
    15
    report, not you.
    16
    DR. KEELER: But if EPA responds back
    17
    to me with whatever the final comments and all that kind
    18
    of stuff very late in the game -- I'm hoping I get it
    19
    before that, so I can get this taken care of, but if
    20
    they get it back to me June 30 or something like that,
    21
    I'm going to have a really hard time in dealing with
    22
    that. I don't know what will happen. That's out of my
    23
    hands.
    24
    MR. ZABEL: Madam Hearing Officer, I
    Page33

    1
    will make my motion, regardless. I understand his
    2
    difficulty. I'm giving up most of Father's Day with my
    3
    children because of this hearing on Monday, so I'm
    4
    sympathetic doctor, but at some point, we need the
    5
    evidence in the record, and if it isn't there, I will
    6
    make my motion.
    7
    DR. GIRARD: One problem we have got
    8
    is that we have already got partial -- we have partial
    9
    information in the record now, which you already said is
    10
    not final. It seems to me that really need to talk with
    11
    your attorneys to see if it is possible to put a draft
    12
    copy, as it is now, in the record. There's no way it's
    13
    going to be released for publication. We take trade
    14
    secrets all the time in cases, so you need to talk with
    15
    your attorneys. I think it would short circuit some of
    16
    this questions by three or four hours, if you could
    17
    simply look at what methods were used, and a lot of
    18
    these questions go to procedures. They don't go to
    19
    results at all. So I think you need to go talk with
    20
    your attorneys.
    21
    (At which point, a break was taken.)
    22
    MADAM HEARING OFFICER: Back on the
    23
    record.
    24
    MR. MATOESIAN: In response to the
    Page34

    1
    question of -- on the question of Dr. Keeler's report,
    2
    we're going to have to talk to the U.S. EPA about
    3
    whether it can be released and what portion, so we
    4
    cannot today commit to the July 5 date. We are going to
    5
    reach out to them, and hopefully, get an answer by early
    6
    next week, Monday, perhaps Tuesday. Then give you a
    7
    more definitive answer then. That's the best we can do
    8
    at this point.
    9
    MADAM HEARING OFFICER: Mr. Zabel.
    10
    MR. ZABEL: May I add to my request
    11
    then that we also, if we receive anything, receive the
    12
    200 pages or thereabouts of commentary that Dr. Keeler
    13
    indicated he received from U.S. EPA? You are going to
    14
    be talking to U.S. EPA, so you might as well talk to
    15
    them about both.
    16
    MR. MATOESIAN: We will bring that
    17
    issue up, as well, to them.
    18
    MR. RIESER: One other item, which I
    19
    asked for yesterday, was if the LADCO presentation could
    20
    be provided and I think Dr. Keeler said he would look
    21
    for it.
    22
    DR. KEELER: It's being photocopied as
    23
    we speak I believe.
    24
    MR. RIESER: Great. Thank you.
    Page35

    1
    MADAM HEARING OFFICER: At this point,
    2
    then, we will move on with the cross-examination of
    3
    Dr. Keeler, and we will address issues considering the
    4
    availability or unavailability of the Steubenville study
    5
    published report at a later date.
    6
    MR. RIESER: I think we are on 12-A.
    7
    DR. KEELER: 12-A: "In your
    8
    testimony, how do you define "local" and "regional"
    9
    sources?" I believe I answered that previously. We had
    10
    an extended discussion about that yesterday, so that's
    11
    been answered. B: "Are the sources described in this
    12
    state limited to coal-burning sources?" No, they are
    13
    not.
    14
    DR. RIESER CONTINUES:
    15
    Q. What other sources are?
    16
    A. I believe I answered this yesterday, as
    17
    well. Iron and steel production, municipal waste
    18
    incineration, refining, metals production I think were
    19
    the sources that I mentioned yesterday. C: "Is the
    20
    deposition" --
    21
    Q. I'm sorry --
    22
    A. "Limited to wet deposition?"
    23
    Q. I'm sorry, one question on that. In
    24
    identifying where the sources -- were the sources you
    Page36

    1
    identified as a result of the receptor sampling and
    2
    modeling or as a result of the review of the emissions
    3
    inventory?
    4
    A. Only the receptor modeling.
    5
    Q. Thank you.
    6
    DR. KEELER: C, "Is the deposition
    7
    described here limited to wet deposition?" The source
    8
    apportionment results receptor modeling performed were
    9
    only including the wet deposition?
    10
    MR. HARLEY CONTINUES:
    11
    Q. Dr. Keeler, mindful of the fact that the
    12
    source apportionment was based on wet deposition, on
    13
    days when it didn't rain, when there was only dry
    14
    deposition, do you have an opinion about how that might
    15
    have effected the results of the work that you did at
    16
    Steubenville?
    17
    A. As part of this overall project, we will
    18
    be looking at, both, wet and dry deposition. Again,
    19
    this was the first paper that we attempted to get into
    20
    the scientific journal, the wet deposition took
    21
    precedence. The dry deposition work is ongoing, and
    22
    it's going to be based on the extensive on-site
    23
    meteorological measurements, as well as the reactive
    24
    gaseous mercury, particulate mercury, and elemental
    Page37

    1
    mercury measurements that we're actually making on site.
    2
    We have, at this time, not modelled the deposition using
    3
    the ambient data. However, based on our past projects,
    4
    we would assume -- not one would assume. The dry
    5
    deposition component should be a significant additional
    6
    loading of mercury to this ecosystem. In our studies in
    7
    Detroit, where we were in areas with similar source
    8
    contributions, or similar source densities, the portions
    9
    of dry deposition was -- well, the dry deposition that
    10
    was about half of the overall deposition that we saw at
    11
    the site at Steubenville was different in terms of the
    12
    mix of sources than Detroit is, so we expect to see some
    13
    different contributions, and so forth, but dry
    14
    deposition is half the story we believe, and in an area
    15
    with lots of sources, dry deposition could dominate the
    16
    local deposition to this area.
    17
    Q. To be clear, that would be added to what
    18
    you have already presented in your testimony about
    19
    deposition through precipitation?
    20
    A. Yeah. The wet deposition -- just to be
    21
    clear, the wet deposition that we modelled and think
    22
    that 70 percent of which is coming from coal-fired
    23
    utilities, is only about half of the total deposition,
    24
    so mercury enters the waterbody by wet deposition, and
    Page38

    1
    then there is a whole other amount of mercury that
    2
    enters through mercury that's in the air, basically,
    3
    interacting with the surface and falling to that
    4
    surface, so at this point, we haven't really apportioned
    5
    half of the total deposition, which is again, part of
    6
    the goal, but that's further down the road.
    7
    Q. Based on previous work that you have done,
    8
    would you reasonably expect that the utility
    9
    contribution to dry deposition would be present in the
    10
    same proportion as it is for wet deposition?
    11
    A. The importance of wet, versus dry, can
    12
    vary from one spot to another, but based on, again, past
    13
    experience, I would expect that the sources that are
    14
    within the 50-mile radius of Steubenville will have a
    15
    major importance, in terms of the dry deposition and
    16
    influence in the ambient levels of mercury in the air at
    17
    Steubenville.
    18
    CROSS EXAMINATION BY MR. HARRINGTON:
    19
    Q. I don't believe you answered the question
    20
    as to whether utilities would have the same impact on
    21
    dry as wet deposition. Could you comment on that
    22
    further, please?
    23
    A. I can't give you a quantitative answer to
    24
    be specific on that. I would expect them to be a
    Page39

    1
    significant contributor to the dry deposition. I
    2
    cannot, because I have not done that analysis, give you
    3
    a quantitative number what percentage of dry deposition
    4
    to coal-fired power plants is.
    5
    Q. Do things such as steel mills, metal
    6
    working refineries have potentially and proportionate
    7
    greater impact on dry deposition?
    8
    A. We're talking about dry deposition of
    9
    mercury, right?
    10
    Q. Dry deposition of mercury in Steubenville.
    11
    Keep it within the context of --
    12
    A. Again, local sources, if they are closer
    13
    to the site and have different forms of mercury that
    14
    they are emitting, would have a different contribution
    15
    than coal-fired utilities would, yes.
    16
    Q. Thank you.
    17
    MR. RIESER CONTINUES:
    18
    Q. And during the 2003-2004 sampling, did you
    19
    measure dry deposition in Steubenville?
    20
    A. We did not measure continuously for the
    21
    2003-2004 time period a direct measurement of dry
    22
    deposition that's analogous to what we did for wet
    23
    deposition. What we have done and what we plan to do to
    24
    provide that estimate is to use ambient concentrations
    Page40

    1
    of mercury that have been measured, so we have
    2
    continuous measurements of reactive gaseous mercury,
    3
    elemental mercury, particulate mercury that are
    4
    performed on an hourly time basis together with the
    5
    onsite meteorological data, and we will model the dry
    6
    deposition quantity to the surface at the Steubenville
    7
    site. As part of intensive periods, we have direct
    8
    measurements of mercury of dry deposition using
    9
    surrogate surfaces, and other techniques, which all of
    10
    these techniques have uncertainties, so we compare those
    11
    measurements together with models to come up with a best
    12
    estimate for dry deposition of mercury in Steubenville,
    13
    but again, that analysis is not completed.
    14
    MR. HARLEY CONTINUES:
    15
    Q. In talking about the conduct of your
    16
    ongoing research, you testified yesterday that you have
    17
    assembled, but not compiled data for wet deposition for
    18
    the year 2005. Is that correct?
    19
    A. The database is not finalized. We haven't
    20
    compiled all of the trace element data and mercury data
    21
    and ion data at this point.
    22
    Q. Based on your firsthand review of the data
    23
    as it now exists, do you have an opinion as to whether
    24
    or not the information from 2005 is consistent with what
    Page41

    1
    you saw in 2004, 2003, or is it just too early?
    2
    A. We haven't done any source apportionment
    3
    modeling on the 2005 data at all because the data is not
    4
    completed. The total amount of mercury deposition in
    5
    Steubenville in 2005 which is the data that is done I
    6
    don't have the exact number in front of me, but it's
    7
    greater than the average. It's more than 2003, and I
    8
    think less than 2004, so it's in the same vicinity.
    9
    MR. BONEBRAKE CONTINUES:
    10
    Q. Is the relative proportion of different
    11
    species of mercury deposited different in wet
    12
    deposition, as opposed to dry deposition?
    13
    A. The answer to that question -- I'm going
    14
    to try to simplify it. The reactive gaseous mercury
    15
    forms and the particulate mercury forms are the ones
    16
    that will most readily go into precipitation. When we
    17
    analyze our samples for our precipitation samples for
    18
    these species we see a very wide range in how much
    19
    reactive particulate is there and part of that is
    20
    because the reactions occur in the precipitation sample,
    21
    itself, giving us somewhat an uncertain answer as to how
    22
    much particulate was there, in the first place.
    23
    Reactive mercury is also going to dominate the dry
    24
    deposition because of its properties. It has a very
    Page42

    1
    high deposition velocity, and so similar to wet
    2
    deposition, reactive mercury is going to dominate in wet
    3
    deposition, and also going to dominate in dry
    4
    deposition, so in the absence of precipitation, you
    5
    would expect do see a fairly rapid depreciation of the
    6
    reactive mercury to the surface similarly as if it was
    7
    going into cloud water, so I would expect reactive
    8
    mercury to dominate, both, the wet and the dry. The one
    9
    part, the dry deposition, that is less well understood,
    10
    and is not included in the models, and the models that I
    11
    have reviewed in the current literature is the uptake of
    12
    elemental mercury by force canopies and into the plant
    13
    materials. This form of mercury and this deposition
    14
    loss is something that's not characterized well, but
    15
    it's a significant amount of mercury on an annual basis.
    16
    It can be as much as three times the wet deposition to a
    17
    forested ecosystem. It's not a simple answer.
    18
    Q. The deposition -- the mercury uptake in
    19
    the forest canopy that you just mentioned, would you
    20
    anticipate that that ultimately ends up in the
    21
    environment, and if so, what portion of the environment,
    22
    aside from the trees, themselves?
    23
    A. Well, what we've quantified thus far is
    24
    the mercury that's taken up in deciduous leaves and
    Page43

    1
    confer needles and so forth in the forest canopy. That
    2
    material, at least, for the deciduous trees -- every
    3
    fall, that material drops from the trees and falls to
    4
    the forest floor, so mercury gets bound up in the
    5
    organic matter and that material is bound to decompose
    6
    like the other plant material and start working through
    7
    the process of weathering and so forth, go into the
    8
    soils, and some of it will run off, depending on the
    9
    ecosystem structure, so it's a delayed signal, in terms
    10
    of deposition to the forest canopy uptake through the
    11
    growing season, deposition and then a slow process where
    12
    it will then slowly make its way to the ecosystem.
    13
    MR. ZABEL CONTINUES:
    14
    Q. Just for my benefit, Doctor, you mentioned
    15
    in discussing dry deposition the use of surrogate
    16
    surfaces. Explain to me what that is or what that
    17
    means.
    18
    A. Sure. One of difficulties in making
    19
    measurements of the deposition of any pollutant, whether
    20
    it's mercury or sulfur or any pollutant that's in the
    21
    atmosphere, is that the surface of the earth is complex.
    22
    Trees present a very complex surface in an urban area,
    23
    buildings and roads and sidewalks, all those surfaces
    24
    are very complex, in terms of the surface area, the
    Page44

    1
    composition, how they move, how the wind and meteorology
    2
    influences those, and so we can't make a replicate of a
    3
    building and stick it up and then somehow wash the
    4
    building down to get how much pollutant was deposited
    5
    into that building, so we come up with a surrogate,
    6
    something what we hope will mimic the surface, so we use
    7
    a variety of different surfaces, and when we do this, we
    8
    try to provide surfaces that have properties that won't
    9
    artificially enhance the deposition, so there are other
    10
    dynamic surfaces. Sometimes we will use a water surface
    11
    if we are trying to look at and estimate the amount of
    12
    mercury that's deposited into the Great Lakes, for
    13
    example. If we're trying to assimilate the deposition
    14
    to a specific type of surface, we would put that
    15
    material on a small aerodynamic surface and actually
    16
    measure how much deposits to that, and then to verify
    17
    that we're getting reasonable results, we actually then
    18
    use models to estimate how much mercury deposited to
    19
    that small surface, and then use an understanding of the
    20
    landscape and some of the information that we can get
    21
    from a remote sense to tell us about how the landscapes
    22
    change and the proportion of different types of trees
    23
    and vegetation and plants and so forth to come up with a
    24
    larger estimate of the deposition.
    Page45

    1
    Q. So in doing that, you use multiple
    2
    surrogates, I take it, for different types of surfaces?
    3
    A. We use more than one type of surrogate
    4
    surface, that's correct.
    5
    MADAM HEARING OFFICER: Anything else?
    6
    Moving on to D, I believe.
    7
    DR. KEELER: D: "What meteorological
    8
    analysis was performed to demonstrate this statement?"
    9
    We used a combination of meteorological analysis tools
    10
    to perform the meteorological interpretation for this
    11
    project. This included detailed plotting analysis of
    12
    surface and upper air meteorological maps, backward air
    13
    mass trajectories, NEX-RAD precipitation data sets,
    14
    together with statistical techniques, such as cluster
    15
    analysis to institute meteorological influences on the
    16
    deposition.
    17
    MR. RIESER CONTINUES:
    18
    Q. If you look at Exhibit 29, which is the
    19
    Beijing, China, Landis Report, there are -- there's a
    20
    page after the page we looked at before called "Hy-split
    21
    Back Trajectories."
    22
    A. Yes. That's what I was referring to in my
    23
    statement.
    24
    Q. So these are two examples of the back
    Page46

    1
    trajectory?
    2
    MADAM HEARING OFFICER: Point of
    3
    clarification, the Beijing study is Exhibit 30. 29 is
    4
    the preliminary results. That's right. 30 is the
    5
    Beijing study.
    6
    MR. RIESER CONTINUES:
    7
    Q. I had two identical exhibits. Sorry about
    8
    that. Exhibit 30. Doctor, you're there. "Hy-split
    9
    Back Trajectories."
    10
    A. Yes.
    11
    Q. So these are examples of the type of work
    12
    that you would do?
    13
    A. These are examples of one of the tools
    14
    that I listed there. These are the -- as I said, the
    15
    backward air mass trajectories.
    16
    Q. What information do using these as
    17
    examples -- what information do these provide to you?
    18
    A. If you look at these plots, these plots,
    19
    basically, the trajectories are calculated to correspond
    20
    to the maximum hour of the precipitation for a couple of
    21
    the precipitation results we received in Steubenville,
    22
    and these black lines represent the center of
    23
    probability of mass that air would have had thought
    24
    going backwards from Steubenville and where the air mass
    Page47

    1
    would have come from moving backwards in time and I
    2
    think it's six-hour increments, and that's what those
    3
    little stars are.
    4
    Q. The stars are six-hour increments?
    5
    A. I believe so, yes. That's going back 72
    6
    hours. These are three-day back trajectories.
    7
    Q. Then there are graphs below these that are
    8
    on the side that says "HPA." Would you tell us what
    9
    these rep?
    10
    A. Yes. The bottom plots HPA is a unit of
    11
    pressure, and so this gives us a vertical slice looking
    12
    up in the atmosphere of the height that the air mass was
    13
    predicted to be at, so again, if you start at
    14
    Steubenville, or to the right, looking at the first here
    15
    moving backwards in time, it shows that our site was at
    16
    the surface, and then the air mass actually came moving
    17
    backwards in time, and went up into the atmosphere a
    18
    little bit into the higher into the mix layer and then
    19
    up as it went backwards and slowly came down again.
    20
    Q. Did these examples -- again, do these also
    21
    represent the difficulty in identifying the proximity of
    22
    regional source because the three days' time travelled
    23
    put you pretty far away from Steubenville? Can you be
    24
    more specific about the difficulties you had to -- why
    Page48

    1
    do you select three days? Let me ask that.
    2
    A. For the purposes of this demonstration,
    3
    three days was selected because, when you start going
    4
    back further, you actually have missing data in the data
    5
    streams, and you wind up actually having the model
    6
    condition calculate very often, so we use three days
    7
    because, as part of that the original analysis we did
    8
    back in the late 80's looking at some of the utility
    9
    acid precipitation data, we found that three days
    10
    represented some synoptic meteorological conditions very
    11
    well, and that going further -- actually, the
    12
    uncertainty in the trajectory calculation was back much
    13
    more than three days which was so great to make them
    14
    unreliable.
    15
    Q. Looking up, again, at the specific
    16
    question of 12, "Meteorologic analysis corroborates that
    17
    a substantial amount of the mercury deposition found at
    18
    the Steubenville site was due to local and regional
    19
    sources," would the local and regional sources be
    20
    sources that contribute mercury emissions to the
    21
    atmosphere or all along the lines of these back
    22
    trajectories?
    23
    A. The line here, again, is meant to
    24
    represent the most probable path, so as you move
    Page49

    1
    backwards in time, the path that actually the air mass
    2
    could have taken actually grows wider, so if you were to
    3
    take and draw an increasing, like, wedge of air moving
    4
    backwards in time, it actually encompasses a larger area
    5
    than what's shown by just this line. This is just a
    6
    representation, and so what we do then is to use this as
    7
    a guide, and then take the surface and upper air
    8
    meteorological maps together with the NEX-RAD to help
    9
    this in terms of guiding us in terms of the timing for
    10
    how quickly the air mass has moved, where the
    11
    precipitation fell along this trajectory, and what
    12
    sources could have fallen into this kind of large area
    13
    that surrounds this line that you see here, and so you
    14
    put that all together and together with the known source
    15
    locations to be able to then say, "Here's the sphere
    16
    that we think has contributed to the deposition at that
    17
    point."
    18
    Q. When you -- tell us what "NEX-RAD" is, I'm
    19
    sorry.
    20
    A. NEX-RAD is the weather radar that you see
    21
    presented on the television. It's the nice way to show
    22
    the storms for Springfield, show the nice, heavy
    23
    thunderstorms that come through in different colors, so
    24
    it's next-generation radar is what it stands for.
    Page50

    1
    Q. So going back to your description of this
    2
    you describe sort of a -- since I'm used to ground water
    3
    what I will call an inverse plume where it spreads out
    4
    from the back and focuses in at the front end. Is that
    5
    an apt description?
    6
    A. I'm not a ground water person, but plume
    7
    is okay.
    8
    Q. So back to that question, would it be in
    9
    the way you did the study that all of the sources that
    10
    you identify within this area, looking at this first map
    11
    on the left, which starts at, essentially, the Rio
    12
    Grand, all the sources within that area leading up to
    13
    Steubenville would be included in your analysis of the
    14
    mercury emissions that fall at Steubenville?
    15
    A. We will utilize going as far back as the
    16
    trajectory would tell us for the three days. We
    17
    actually look at the meteorological numbers for the
    18
    entire country when we are doing this, but we would look
    19
    at and investigate any potential influences that would
    20
    occur along that entire path.
    21
    Q. So when you talk about local -- we had an
    22
    extended discussion yesterday I understand about local
    23
    and regional sources and things like that, and you were
    24
    -- again, correct me if I'm mistaken -- but you were
    Page51

    1
    concerned that the local and regional as the proximity
    2
    issue was problematic because, in your mind, it really
    3
    wasn't meteorologic?
    4
    A. That's correct.
    5
    Q. The meteorology that's described in this
    6
    first plot, the one on the left on this Exhibit 30,
    7
    would suggest that the mercury that's being contributed
    8
    into Steubenville that you measured came from sources
    9
    along this line and then spread out as far as the data
    10
    shows that the air mass moved. Is that correct?
    11
    A. I believe what you're trying to convey is
    12
    correct.
    13
    Q. Is it, again, looking at this map, is it
    14
    the assumption that you're going back three days because
    15
    that's an understanding of what's useful data? Is that
    16
    the way to say that? After three days it gets mushy?
    17
    A. Yes.
    18
    Q. It doesn't really tell you anything. Do
    19
    you have any assumption, and I asked this yesterday, but
    20
    there is a good graphical representation of it. Do you
    21
    have any assumptions that any amount of mercury comes
    22
    into this back end that you have got at the Rio Grand in
    23
    looking at how much mercury is being deposited in
    24
    Steubenville?
    Page52

    1
    A. Again, let me see if I understand what
    2
    you're asking me. This line, or whatever, that goes
    3
    back toward the Rio Grand here, we don't add up
    4
    emissions along that line or suggest that emissions
    5
    are -- that's not included in our analysis. There are
    6
    no assumptions in terms of the analysis. What we would
    7
    do is we would take and look at the entire upwind
    8
    history of this precipitation event. One tool to look
    9
    at where the air mass came from would be this line, and
    10
    along this line we would look at things, such as did it
    11
    rain? What was the precipitation rate moving backwards
    12
    i time along this line, and what we found is that, by
    13
    using precipitation, you can look to see whether the
    14
    probability that the pollutant would be removed is
    15
    greater in times when precipitation along these back
    16
    trajectories is high or not, so we look at the storms,
    17
    and in this case, this one that's for May 8, it turned
    18
    out that the air mass actually wasn't moving very fast.
    19
    If you look at those stars there, there are a few stars
    20
    very close to Steubenville, so the air mass was not
    21
    moving very fast. In fact, those first four or five
    22
    stars there reflect the meteorological situation at the
    23
    time, which basically, had a storm which stalled out in
    24
    that area, so the storm was a big storm. Things didn't
    Page53

    1
    move very quickly and the precipitation would have been
    2
    washing out all of the reactive mercury, and all of the
    3
    other very reactive pollutants from the atmosphere and
    4
    cleaning things up for a very long time, so that the air
    5
    masses that could have contributed to the loading that
    6
    was occurring through that storm couldn't come from very
    7
    far, and so this is how we do that type of analysis, and
    8
    one can take and model that specific storm and compare
    9
    that against using observations because there are no
    10
    assumptions in the observations. It's meteorological
    11
    data that we have and we don't look at a line underneath
    12
    the map. We actually look at the whole area, and we,
    13
    basically, say, from this, we know that we had a very
    14
    slow-moving air mass that took a long time for it to
    15
    actually go anywhere, so we are talking about emissions
    16
    that were in the vicinity of the Steubenville area. The
    17
    ones that were coming from Southern Ohio that were --
    18
    the emissions sources were, basically, emitting up into
    19
    that area, and then that storm was staying there, and it
    20
    was precipitating out for an extended period of time, so
    21
    that the air mass, by the time it got up towards,
    22
    Steubenville had already been washed out. The air that
    23
    was in that storm had already had a great deal of
    24
    removal and cleansing, just to put it in simple terms,
    Page54

    1
    so the highest probability of where the air masses that
    2
    fed the clouds could have come from had to have been in
    3
    that general vicinity. Again, I'm saying Southern Ohio,
    4
    Northern Kentucky, that general area, based on the
    5
    service meteorological data our on site, data as well as
    6
    using this as a tool. When you start talking about
    7
    meteorological analysis and showing maps and so forth,
    8
    everyone turns off and goes to sleep in your talk, but
    9
    when you show a trajectory plot, people get the idea
    10
    that the air started down somewhere in Texas and that's
    11
    the path that it took before it got to Ohio, so it's
    12
    simplification for presentation purposes, but by no
    13
    means is it what we use as the definitive answer because
    14
    there's very complex three-dimensional flows that occur
    15
    in the atmosphere, and one has to take those into
    16
    account, as well, when one is looking at what potential
    17
    source areas could have contributed.
    18
    Q. So that description is what tells you that
    19
    the mercury deposited in Steubenville came from the
    20
    specific area you described, Southern Ohio, Kentucky,
    21
    and not from, say, Houston, which is more or less passed
    22
    -- is that correct?
    23
    A. Yes, in simple terms.
    24
    Q. In doing that analysis, do you have to
    Page55

    1
    take into account the atmospheric chemistry in
    2
    transformations of mercury in the atmosphere?
    3
    A. We do rely on our understanding of the
    4
    reactivity of mercury and the chemistry of mercury in
    5
    order to be able to look at what distance scales we
    6
    think things could take place on. However, there are no
    7
    assumptions made. We use what our best available
    8
    understanding is based on, both, our observation data
    9
    that we have taken, both, at Steubenville and at our
    10
    Michigan sites, together with what is published in the
    11
    literature.
    12
    Q. And is that understanding -- you use the
    13
    term "understanding." Is that correct?
    14
    A. I believe that's what I said, yes.
    15
    Q. Is that understanding different than the
    16
    atmospheric transformation of mercury which are
    17
    described in the deterministic models?
    18
    A. That would depend upon the specific
    19
    deterministic model. This gets to the whole question
    20
    that I raised yesterday about the uncertainties in the
    21
    models.
    22
    Q. Let's use CMAQ to narrow it down?
    23
    A. CMAQ -- the version of CMAQ that EPA uses
    24
    has a very simplistic atmospheric chemistry for mercury.
    Page56

    1
    There are lots of issues in that chemistry. It does not
    2
    include all the relevant reactions that we understand
    3
    today. It doesn't include the most up-to-date reaction
    4
    rates, so I would say no. We rely upon more than that.
    5
    Q. And have you published or is there another
    6
    paper published paper that you rely on that identifies
    7
    the atmospheric transformation reactions that you rely
    8
    on in doing your work?
    9
    A. We have papers. We have a paper that we
    10
    have submitted to -- see, we have a paper that we
    11
    submitted to a peer-reviewed scientific journal that
    12
    details some of our deterministic modeling, which is not
    13
    at all what was done here, but that's not really
    14
    relevant to the situation, but it incorporates some of
    15
    the mercury chemistry that we rely on. I mean, some of
    16
    these chemical reactions and updating the atmospheric
    17
    chemistry happened very rapidly. I was just in Russia
    18
    at a mercury meeting a long-range transport mercury
    19
    meeting in Moscow and learned of some new reactions that
    20
    had just come out, so we rely upon, both, what our
    21
    colleagues tell us at meetings, as well as what the
    22
    peer-reviewed literature has. I don't write down, and I
    23
    don't have, like, a publication where I have listed all
    24
    the atmospheric chemistry that I rely on. I rely on
    Page57

    1
    what's in the peer-reviewed literature.
    2
    Q. I guess what the bottom line of what I'm
    3
    trying to get at is what Sheldon would say is, is there
    4
    a way that we can see how you describe the atmospheric
    5
    transformation reactions? I assume there is some type
    6
    of mathematical equation or part of your model or
    7
    something that another person can look at and apply in a
    8
    similar setting and test.
    9
    A. We don't use chemical reactions in our
    10
    modeling. I stated yesterday that the receptor modeling
    11
    does not use chemical reactions. We only used observed
    12
    information.
    13
    Q. Then I completely misunderstood because I
    14
    thought you said that, in evaluating where mercury came
    15
    from, you made certain judgments, decisions about the
    16
    atmospheric chemistry that mercury undergoes.
    17
    A. What we use as our understanding that
    18
    reactive mercury is removed very easily with
    19
    precipitation, which we have published and have
    20
    observations that show this, and that elemental mercury
    21
    is not removed as rapid, so again, this is based on
    22
    observation of published work, and in understanding the
    23
    information, we have an idea of how long reactive
    24
    mercury would last in the atmosphere based on almost
    Page58

    1
    instantaneous removal in precipitating systems. That's
    2
    the atmosphere chemistry that I'm referring to is that
    3
    there are different chemical properties of mercury forms
    4
    that may get removed at different time scales.
    5
    Q. Do you have a numeric rate that you use to
    6
    evaluate the removal of reactive gaseous mercury?
    7
    A. No, sir.
    8
    Q. When you say it's rapidly removed, what's
    9
    the quantification of rapidly?
    10
    A. Well, we have hourly data, and you will
    11
    see within an hour time frame a very rapid, so within an
    12
    hour time frame, we see a significant -- more than 50
    13
    percent -- removal of the mercury within one hour of the
    14
    onset of precipitation.
    15
    Q. When you talking about that data, what
    16
    you're talking about is the data at your wet deposition
    17
    sampling locations, correct?
    18
    A. That's correct.
    19
    Q. So the storm begins at five o'clock. At
    20
    5:15, you have a sample that's got a lot of mercury in
    21
    it. At 6:15, there's no mercury, just --
    22
    A. The reactive mercury would have dropped,
    23
    that's right.
    24
    Q. And what does that -- but is it correct
    Page59

    1
    that you use that data to make decisions as to how much
    2
    reactive gaseous mercury is in the air mass that's
    3
    moving into Steubenville?
    4
    A. No. There's no assumption there.
    5
    Q. So how do you know how much mercury is in
    6
    the air mass that's moving into Steubenville or where
    7
    it's from?
    8
    A. We have on-site measurements of the
    9
    reactive mercury at the site. There's no assumption.
    10
    That is my point.
    11
    Q. What does it tell you -- what does that
    12
    data tell you about -- well, step back. That's why
    13
    you're not in position to identify the proximity of the
    14
    sources based on the samples that you do at
    15
    Steubenville, correct?
    16
    A. We have not done a detailed source
    17
    apportionment of the ambient mercury at Steubenville,
    18
    yet. What we have done at this point is look to see
    19
    specific episodes when we have high reactive and
    20
    particulate mercury to see what the meteorological
    21
    conditions were like and where the air was coming from
    22
    based on on-site meteorological measurements, as well as
    23
    other meteorological data, such as the trajectories, to
    24
    see if there is a strong association, so whether we see
    Page60

    1
    repeated pattern of things like high sulfur dioxide,
    2
    high reactive mercury, high nitrous oxide, high CO,
    3
    whatever the on-site measurements we have, high
    4
    particulates, and then we analyze the particulates for
    5
    there elemental composition, as well, so we can look for
    6
    the same tracers in the air as we see in the
    7
    precipitation, and that analysis has not been completed,
    8
    yet, because we collect four samples a day. That would
    9
    collect them for -- well, we're on our third year now,
    10
    and it's thousands of samples that we are in the process
    11
    of analyzing, so that analysis and information will
    12
    come. We do see strong relationships that winds that
    13
    flow from the south, southwest with higher mercury
    14
    levels and higher S02 (phonetic) concentrations that are
    15
    indicative of transport from fossil-fuel-burning plants
    16
    from coal-burning plants.
    17
    Q. What tells you that those are fossil
    18
    burning plants, again, looking at this first map as an
    19
    example in Kentucky, Ohio River Valley and not Houston?
    20
    A. Well, we have an idea of the location of
    21
    where the fossil-fuel-burning facilities are, where all
    22
    the sources are, and then we can look along that swath
    23
    that we think where the air could have possibly come
    24
    from, and we look at the inventory to tell us what the
    Page61

    1
    possible sources could have been. It's an aid, not as a
    2
    quantitative tool.
    3
    Q. Then you have to make -- then you have to
    4
    evaluate whether precipitation events have washed out
    5
    mercury that could come from other sources along that
    6
    line. Is that correct?
    7
    A. That's right. It's something I have been
    8
    working on for more than 20 years, so in my best expert
    9
    judgment, I have done this for multiple pollutants,
    10
    including mercury, and I feel like I have a very good
    11
    handle on this situation, and on this type of analysis.
    12
    Q. If there was an example where there was an
    13
    air mass moving into Steubenville, and there was no rain
    14
    fall events going on along the line back to Texas, what
    15
    would the results of Steubenville look like?
    16
    A. You know, I would have to go and look to
    17
    see if we had those type of events in order for me to be
    18
    able to predict because you can draw the same line
    19
    moving from Steubenville to Texas, and depending upon
    20
    the winds, how strong the winds were, and at all those
    21
    segments, what the atmosphere was like, the stability of
    22
    the atmosphere along the trajectory, the temperature
    23
    profile, all these different meteorological parameters
    24
    would affect disbursion, the chemistry, the transport,
    Page62

    1
    and the dry deposition that occurred along that
    2
    trajectory. One of the things that, if one was to take
    3
    and estimate how much mercury you would expect left in
    4
    an air mass that was submitted to Texas, by the time it
    5
    got to Steubenville, one can take and estimate how much
    6
    you would have expected to have loss from dry
    7
    deposition, how much you might expected to have lost
    8
    from chemical reactions, and just by the air mass being
    9
    deluded as you got there and when you get that far back
    10
    in time, there's very small contribution that you would
    11
    see in Steubenville from sources way back in Texas, but
    12
    that's a general comment. I would have to look at
    13
    specific information to give you a quantitative answer.
    14
    Q. In doing that estimate that you just
    15
    described, one of the factors would be the atmosphere
    16
    transformation that mercury undergoes --
    17
    A. Yes.
    18
    Q. -- during that time of travel?
    19
    A. Yes, sir.
    20
    MR. HARLEY CONTINUES:
    21
    Q. The May 8 event that you described on your
    22
    hy-split trajectory, is that one of the days during that
    23
    year where there was an event that precipitation led to
    24
    a significant deposition of mercury in Steubenville?
    Page63

    1
    A. Yeah. That was one of the four largest
    2
    events depositing. Again, I think I've given a figure
    3
    of maybe the four largest or the several largest, as
    4
    much as 8 percent of the annual total, so these are
    5
    significant events that occurred at this site.
    6
    Q. In the two-year period of 2003, 2004, how
    7
    many total mercury rains have there been on Steubenville
    8
    comparable to the event on May 8 where we have
    9
    hyperloading of mercury on Steubenville?
    10
    A. Gee, I don't have that in front of me. My
    11
    memory is that we had in the two-year period about eight
    12
    events that were greater than .6 micrograms per meter
    13
    squared I believe, which that's a big event. And then a
    14
    couple that were greater than one, and again, if you are
    15
    looking at 10 to 20 micrograms per square meter at a
    16
    year at a site, if you get more than one in one rain
    17
    event, that's a significant contribution in that one
    18
    day.
    19
    Q. There was one other question I had. The
    20
    CMAQ model, you gave some reasons why the CMAQ model is
    21
    it not as precise as the receptor-based approach that
    22
    you used in Steubenville. One question I had about the
    23
    CMAQ model is you said the CMAQ model underestimated
    24
    mercury loading in Steubenville by comparison to the
    Page64

    1
    results of the work that you have done. Is that
    2
    correct?
    3
    A. Yeah. Just to qualify, the CMAQ for 2001
    4
    is where they calculated that 43 percent was coming from
    5
    coal-fired utility boilers. Our data is from 2003,
    6
    2004, we did have the opportunity to compare our
    7
    Michigan network sites for the 2001 year, together with
    8
    our estimated for Vermont, and the CMAQ model
    9
    underestimated the deposition that we measured at our
    10
    Michigan sites and at the Vermont site for 2001. It was
    11
    off by a factor of two at one site, as I recall, so it
    12
    grossly underestimated the total deposition at our sites
    13
    that we had measuring in 2001. The way you phrased it,
    14
    "CMAQ being less precise" I think the way I would rather
    15
    phrase it is that these type of models are more
    16
    uncertain, that there are more parameters and processes
    17
    that are poorly defined in these models, which make
    18
    their uncertainties greater and the conclusions drawn
    19
    from those models much greater than I would say that
    20
    they are from the receptor modeling. That's a correct
    21
    statement.
    22
    Q. Is the CMAQ model a model which accounts
    23
    for, both, wet and dry deposition of mercury?
    24
    A. Yes, it does.
    Page65

    1
    Q. And is it fair to characterize your
    2
    testimony as indicating that, in the Steubenville
    3
    situation, your modeling of wet deposition alone was
    4
    greater than the CMAQ model of, both, wet and dry
    5
    deposition at that site?
    6
    A. My memory tells me that CMAQ actually
    7
    estimated a greater dry deposition at Steubenville than
    8
    it did for wet deposition for the 2001 year, so no, our
    9
    wet deposition wasn't greater than the CMAQ's total. I
    10
    believe the CMAQ total was around 30 micrograms per
    11
    square meter, or 34. It's hard to tell from the
    12
    modeling because they do it in colors with ranges, but
    13
    that, again, I'm just going from my memory of what Russ
    14
    Bullock presented, but I believe that that's true, that
    15
    the dry deposition was greater in this area than the wet
    16
    deposition was. Using the CMAQ model, not from our
    17
    observations.
    18
    MR. BONEBRAKE CONTINUES:
    19
    Q. On the May 8 back trajectory, a line, is
    20
    that, essentially, indicative of a wind direction from
    21
    the southwest?
    22
    A. Yeah. The line that starts at
    23
    Steubenville or the line that starts at the site there
    24
    on the border of Pennsylvania and Ohio, if you follow
    Page66

    1
    that backwards towards the bottom of the left page that
    2
    is trying to illustrate the most likely path that an air
    3
    mass took before it got to Steubenville.
    4
    Q. In this particular case, through Texas and
    5
    Louisiana, the air mass was moving from the southwest
    6
    and northeast?
    7
    A. That's correct, southwest.
    8
    Q. Yesterday we talked a little about wind
    9
    directions in Illinois. My understanding from your
    10
    testimony was that, in the winter season in Illinois,
    11
    the wind direction is frequently from the northwest. Is
    12
    that correct?
    13
    A. Yeah. The Great Lakes region, as a whole,
    14
    has a higher frequency of winds from the north,
    15
    northwest during the wintertime as a result of synoptic
    16
    meteorological conditions.
    17
    Q. And during the summer months, are winds in
    18
    the state of Illinois most typically from the southwest?
    19
    A. From the data I looked at for O'Hare, it
    20
    appears as if the south is the dominant winds with
    21
    south, southwest being one of the more frequent wind
    22
    directions, but knowing that westerly winds are also the
    23
    dominant wind areas during the summer.
    24
    Q. Would O'Hare's -- would the direction of
    Page67

    1
    wind at O'Hare be impacted by Lake Michigan?
    2
    A. Yes.
    3
    Q. So would the data from O'Hare, in your
    4
    view, be representative of the rest of the state of
    5
    Illinois?
    6
    A. No. If you look at wind measurements made
    7
    in Southern Illinois, you see a slight variation in that
    8
    overall pattern. You might have slightly more winds
    9
    from the south than you would at O'Hare, so the winds
    10
    will change slightly. The dominant wind direction still
    11
    is going to be west with a southerly component being
    12
    strongest.
    13
    Q. With respect to the northwest portion of
    14
    the state of Illinois, would you expect, then, that
    15
    during the winter months the predominant wind direction
    16
    would be from the northwest and then the summer months
    17
    it would be from the southwest?
    18
    A. South, southwest. From what I have seen
    19
    for -- and again, I haven't looked at a climatological
    20
    average, but that's about right.
    21
    Q. What would you view, Dr. Keeler, to be the
    22
    states which contain upwind sources of mercury with
    23
    respect to the state of Illinois?
    24
    A. Again, taking what you said in terms of
    Page68

    1
    the dominant wind directions, you would have the states
    2
    of Missouri, Iowa, and farther to the west would be
    3
    upwind of Illinois, and then the states to the south,
    4
    Kentucky, Tennessee, Louisiana, Alabama.
    5
    Q. Would Texas also be in that list?
    6
    A. Texas would be in that list, as well.
    7
    Q. One other question for you, Dr. Keeler.
    8
    You mentioned in response to a question from Mr. Harley
    9
    that you had done, as I understand it, a comparison of
    10
    CMAQ predictions to Michigan deposition data that you
    11
    had available to you. Is that correct?
    12
    A. Yes.
    13
    Q. Is that comparison in a published article?
    14
    A. No, it's not.
    15
    Q. Is that comparison publicly available?
    16
    A. You know, is it in Dr. Landis' briefing?
    17
    MADAM HEARING OFFICER: Exhibit 30,
    18
    Beijing Exhibit 30, yes.
    19
    DR. KEELER: It says, "Comparison of
    20
    CMAQ Model Versus" --
    21
    Q. Back toward the end of the document.
    22
    MADAM HEARING OFFICER: Yeah,
    23
    two-thirds back he said. "Comparison of CMAQ Model
    24
    versus UMAQL Measured Mercury Wet Deposition Testimony."
    Page69

    1
    MR. BONEBRAKE CONTINUES:
    2
    Q. Is that correct, Dr. Keeler, that's the
    3
    page you're on?
    4
    A. Yes, and refers to the left column to
    5
    Dexter, Michigan.
    6
    Q. Helston, Michigan?
    7
    A. That's correct.
    8
    Q. Both, the CMAQ predictions and the
    9
    deposition data that you were using in the comparison
    10
    were both from 2001?
    11
    A. Yes, sir. These numbers were provided to
    12
    Dr. Landis I believe by Russ Bullock of U.S. EPA, and
    13
    these are the actual data that went into the CAMR
    14
    modeling.
    15
    Q. Is there a discussion of this comparison
    16
    in the study that's been at issue today in terms of
    17
    what --
    18
    A. No. This is an additional analysis. The
    19
    Michigan site data is not included in the Ohio paper.
    20
    Q. Other than what's in this particular page,
    21
    has the comparison or the bases of the comparison
    22
    otherwise been made publicly available?
    23
    A. All of the Michigan data for 2001 is in
    24
    peer-reviewed publications and the CMAQ model results
    Page70

    1
    are in the public docket that was filed by IEPA.
    2
    Q. So --
    3
    A. So it's all public.
    4
    Q. From your perspective, then, someone could
    5
    take the publicly-available information in those
    6
    documents and repeat the comparison?
    7
    A. Yes, sir.
    8
    MR. ZABEL CONTINUES:
    9
    Q. Earlier I think you said, in doing the
    10
    corroboration using a Michigan inventory, you looked at
    11
    sources east of the Mississippi. Is that correct?.
    12
    A. I said that was the area that we focused
    13
    on, yes.
    14
    Q. You didn't use, for a particular
    15
    corroboration, also sources east of the Mississippi?
    16
    A. Again, for trying to speak generally to be
    17
    inclusive of all the work that we did for a particular
    18
    event, we would use our understanding of the
    19
    meteorologic and transport for a particular period, such
    20
    as the May 8 period, where we would focus on those
    21
    sources, and sources that were to the southwest, for
    22
    example, in the most highest probable transport area, so
    23
    we wouldn't be then taking out the list of sources from
    24
    Minnesota and Wisconsin at that time to look at -- in
    Page71

    1
    order to think about the May 8 event. On another day
    2
    where the flow came from those directions, we would look
    3
    at another set of sources that would help us interpret
    4
    that specific day. We didn't limit our analysis to a
    5
    number of sources. We had the entire -- plotted all of
    6
    the sources plotted in 1999 EPA database together with a
    7
    list of all those sources and the estimated fraction of
    8
    mercury emitted from each source in each fraction as a
    9
    tool to guide us in terms of our interpretation.
    10
    Q. That was sort of the point of my question,
    11
    and the May 8 is a good example. There's some subset of
    12
    sources east of the Mississippi you would have used in
    13
    looking at emission inventories for them?
    14
    A. Again, we would have focused on the
    15
    sources in the states which we thought had a probability
    16
    of contributing on a specific day for a specific event.
    17
    Q. Just to make this perfectly clear to me,
    18
    there are coal-fired plants in Tampa Bay in Florida.
    19
    They would not have been included, would they, in your
    20
    May 8 analysis?
    21
    A. I would say that I did not look at Tampa
    22
    Bay power plants on interpretation of the May 8.
    23
    Q. On that May 8 one, both, Louisiana and
    24
    Texas I believe are west of the Mississippi, were they
    Page72

    1
    not?
    2
    A. That would be a geographically-correct
    3
    answer.
    4
    Q. And in fact, Minnesota -- for instance, if
    5
    you're looking in the other direction, although I
    6
    understand Minnesota has a dispute on which side of the
    7
    Mississippi they are in, at least, part of it is west of
    8
    the Mississippi, is it not?
    9
    A. Yes, it is. In my use of east of the
    10
    Mississippi and west of the Mississippi, I was trying to
    11
    give a general division line, but as I mentioned
    12
    earlier, I was not trying to distinguish an absolute
    13
    line of demarcation for any of the analysis.
    14
    Q. Well, then in the May 8 case, would you
    15
    have looked at cases in Louisiana and Texas?
    16
    A. We would have looked at sources along that
    17
    trajectory, yes, or in that area that would be indicated
    18
    by that air mass trajectory, yes.
    19
    Q. In answer to one of the questions I
    20
    understand that cone gets wider the far away from
    21
    Steubenville you get?
    22
    A. That's right. So sources all the way up
    23
    from Kansas to Atlanta, Atlanta area, Georgia would also
    24
    have been considered in looking in the backward upwind
    Page73

    1
    path.
    2
    Q. Most of Texas, I take it, at that point?
    3
    A. Yes.
    4
    Q. Thank you.
    5
    MADAM HEARING OFFICER: Anything
    6
    further? I believe 12-E --
    7
    MR. RIESER CONTINUES:
    8
    Q. This will actually address some of the
    9
    questions, but since Mr. Harley brought up the
    10
    comparison of CMAQ and the receptor modeling, it's
    11
    correct, isn't it, that CMAQ in your type of receptors
    12
    study are designed to achieve two different results. Is
    13
    that correct? It's designed for two different purposes.
    14
    Is that correct?
    15
    A. How a model is used is defined by the user
    16
    and so in my case, which I can attest to, we were using
    17
    receptor models to calculate how much mercury was
    18
    deposited via wet deposition from the major source
    19
    categories for the period of 2003-2004. So that
    20
    apportionment to source categories was our objective,
    21
    and that's where we did the modeling. Why EPA did the
    22
    CMAQ modeling for 2001? As I understand, it was to
    23
    estimate the contributions from all the major sources to
    24
    the deposition of mercury across the entire United
    Page74

    1
    States, so by definition, it has a broader purpose, and
    2
    was not looking at one site. It was not looking at just
    3
    wet deposition. It looked at wet, dry, and ambient, so
    4
    yes, they have -- they have different purposes, but to
    5
    say CMAQ model has one purpose and the type modeling we
    6
    did had only one purpose, it really depends on what the
    7
    user was using that model for.
    8
    Q. The CMAQ model, among its utilities, is
    9
    that it can be used for predictions. Isn't that
    10
    correct?
    11
    A. Yes, sir.
    12
    Q. So you can use it to decide what would
    13
    happen, as an example reflected in Exhibit 30, "Utility
    14
    zero out," of what mercury deposition would look like if
    15
    there were no utility emissions?
    16
    A. Yeah. I believe, like you said, in
    17
    Exhibit 30, I believe that map included a couple special
    18
    plots. Maybe I'm wrong.
    19
    Q. You're correct. There is a CMAQ simulated
    20
    total mercury deposition for 2001 and underneath it
    21
    says, "Utility zero out," and prior to that, there's a
    22
    base case CMAQ simulated total mercury for 2001 base
    23
    case, so as we said, you can use CMAQ to, as an example,
    24
    take out all of the utility emissions and see what
    Page75

    1
    things look like?
    2
    A. Correct.
    3
    Q. Can you use your model to do that?
    4
    A. The receptor model, by definition, does
    5
    not have a predictive capability.
    6
    Q. So if I -- well, let me ask you, if you
    7
    assumed that the coal-fired power plants, within a 50
    8
    kilometer range of Steubenville, ceased to operate,
    9
    would you have any conclusion as to what that would do
    10
    to the mercury deposition in Steubenville?
    11
    A. Based on our work, what I would say is
    12
    that if the coal-fired utilities, regardless of
    13
    location, stopped emitting, so they were zeroed out, we
    14
    would see close to a 70 percent reduction in the mercury
    15
    deposition that we measured at Steubenville.
    16
    Q. Could that conclusion, in making that
    17
    statement, what you were referring to are not the
    18
    coal-fired utilities within a 50 kilometer distance from
    19
    Steubenville, but all coal-fired utilities in the United
    20
    States?
    21
    A. We -- again, based on our analysis, our
    22
    meteorological analysis, we will consider sources that
    23
    were beyond regional, so very long range sources, so
    24
    ones that are the western part of the United States
    Page76

    1
    would contribute very little to that total and part of
    2
    that is backed up by just looking at the deposition data
    3
    that's in the Western United States, which is very low.
    4
    It's for around four micrograms per square meter, so I
    5
    would say that it's the sources in the eastern United
    6
    States coal-fired utilities in the Eastern United States
    7
    which are contributing that 70 percent, and if those
    8
    were reduced, we would see that commensurate drop in the
    9
    mercury deposition at that site for those years that we
    10
    modelled.
    11
    Q. But you wouldn't be able to use your
    12
    receptor model to determine what would happen at
    13
    Steubenville if, for example, all the power plants in
    14
    the state of Ohio reduced mercury emissions by 70
    15
    percent?
    16
    A. No. The model is not capable of
    17
    predicting calculations.
    18
    MADAM HEARING OFFICER: Are we ready,
    19
    then -- I believe we have answered 12-E and I think
    20
    perhaps 12-F already. In the discussion we had this
    21
    morning, E is, "Does the analysis differentiate between
    22
    sources located at different distances?" and we have had
    23
    substantial discussion about --
    24
    MR. RIESER: Correct, yes.
    Page77

    1
    MADAM HEARING OFFICER: F is, "Have
    2
    you quantified the substantial amount as used in this
    3
    statement?"
    4
    MR. RIESER: I was looking at the
    5
    wrong number, yes, correct.
    6
    MADAM HEARING OFFICER: And we
    7
    answered 13-A and B yesterday, so 13-C.
    8
    DR. KEELER: I actually believe I
    9
    answered this one as well. "Are they fired with
    10
    bituminous or sub-bituminous coal?" Again, in the
    11
    complete listing of the emissions sources and the EPA
    12
    inventory, it lists the type of coal burned. I believe
    13
    there is a mix of plants that burn, both, bituminous and
    14
    sub-bituminous. Some are all sub-bituminous and some
    15
    are -- a few that are bituminous, so there's a
    16
    combination. D: "Does the chemical profile of
    17
    bituminous as opposed to sub-bituminous affect the
    18
    amount and type of mercury emitted by a coal-burning
    19
    generating unit?" Again, I believe I answered this
    20
    yesterday in saying that I'm not an expert on control,
    21
    and so perhaps, an expert for the State will provide --
    22
    later will talk about how various control will affect
    23
    the emissions, but clearly, the type of coal burned will
    24
    have an influence on the type of type and form of
    Page78

    1
    mercury, in respect to whether it's reactive mercury or
    2
    gaseous mercury or particulate mercury and we talked
    3
    about the importance of chlorine and fly ash content and
    4
    iron and others things in the coal that would cause
    5
    those differences. E: "Would you expect a different
    6
    result at Steubenville if the surrounding units burned
    7
    sub-bituminous coal?" I don't have the ability to
    8
    provide an answer to that question. I don't understand
    9
    exactly what you are asking. I assume that the power
    10
    plants in the area are not -- from an inventory, some do
    11
    burn sub-bituminous coal, so I'm not sure if you are
    12
    asking me if all the plants in the Steubenville area
    13
    burn sub-bituminous but I see --
    14
    Q. I am asking, if all the power plants
    15
    surrounding Steubenville burn sub-bituminous coal, would
    16
    you expect a different result?
    17
    A. Again, I guess I'm not prepared to answer
    18
    that question. I think I would have to have more
    19
    understanding of how changing to a different coal type
    20
    for the various types of controls that are used in that
    21
    area would affect speciation and I'm not prepared to
    22
    answer that.
    23
    MADAM HEARING OFFICER: And I believe
    24
    you have answered 13-F, as well, whether airborne
    Page79

    1
    sources of mercury are located within 50 miles.
    2
    DR. KEELER: So G: "In what way, if
    3
    any, are the conditions at Steubenville analogous to the
    4
    conditions in Illinois?"
    5
    MR. RIESER: To be honest, there was
    6
    some movement in that answer, so if we get too
    7
    repetitive, cut us off, but I would like to go through
    8
    this because I heard two different things, to be honest.
    9
    MR. KIM: Could you clarify what you
    10
    mean because Dr. Keeler did describe the distinctions in
    11
    terms of meteorological conditions and so forth and I
    12
    recall him going into something about topography. Were
    13
    you wanting something beyond that, something different?
    14
    MR. RIESER: What we're looking for is
    15
    whether the findings with respect to Steubenville are
    16
    analogous to Illinois, and some of that discussion has
    17
    to do with things that were discussed and things weren't
    18
    discussed. I heard, on the one side, Steubenville was
    19
    typical, but in some ways, it's obviously atypical due
    20
    to the amount of power plants that are around, so I
    21
    think we need to walk through each of the features and
    22
    talk about them.
    23
    MR. KIM: There again, I'm just for my
    24
    sake just trying to get it clear. You said, "What we
    Page80

    1
    want to know is whether the finding at Steubenville are
    2
    analogous to Illinois." When you say the findings at
    3
    Steubenville are analogous, you have to be comparing
    4
    that to some findings in Illinois, I assume, so are you
    5
    referring to something specific, or are you saying can
    6
    the findings in Steubenville be transferred to Illinois?
    7
    MR. RIESER: I'm assuming this
    8
    testimony he has presented had some meaning to the Board
    9
    as far as what the study means and the decisions they
    10
    should make with respect to Illinois, so I do think we
    11
    have to decide how applicable these findings are to
    12
    Illinois.
    13
    MR. KIM: I agree. The only reason
    14
    I'm saying that is he's already provided testimony that
    15
    he believed the findings could be applied, not only to
    16
    Illinois, but to other locales, once you take individual
    17
    variances into account. With this question on its own
    18
    is read, it seems like you are referring to something
    19
    specific, some kind of fact-specific situation or --
    20
    MR. RIESER: I'm happy to break it
    21
    down if the question, itself, is not clear. I'm happy
    22
    to break it down and go through each of the issues that
    23
    I had in mind and maybe that will take care.
    24
    MR. KIM: Let's do that.
    Page81

    1
    MR. AYRES: I thought we had a
    2
    discussion that went for, at least, a half an hour.
    3
    MR. KIM: I think, if you break it
    4
    down, my guess is some of that stuff has already been
    5
    answered, but if you want to break it down, that's fine.
    6
    MR. AYRES: There was a discussion
    7
    that was very fact specific, and then we talked about
    8
    the transferability of the learning, if you will, from
    9
    Steubenville. Do you recall that?
    10
    MR. RIESER: I recall that and my
    11
    problem is my recollection is -- my recollection is that
    12
    the answer wasn't clear. There are, obviously, some
    13
    informational issues that are portable and Steubenville
    14
    was a very specific place that has the conditions that
    15
    are represented because of conditions that are specific
    16
    to Steubenville.
    17
    MR. KIM: Sure.
    18
    MR. RIESER: Seriously, I think we
    19
    could have got through this pretty quickly.
    20
    MR. KIM: I wanted to be clear.
    21
    MR. RIESER CONTINUES:
    22
    Q. I honestly don't mean to belabor the
    23
    point, but I just don't think it was clear on the
    24
    record. Let me ask, Steubenville is in a river valley.
    Page82

    1
    Is that correct?
    2
    A. The city of Steubenville has part of its
    3
    boundaries that fall in the Ohio River Valley, that's
    4
    correct.
    5
    Q. Was the sampling location in the part of
    6
    Steubenville that was in the River Valley?
    7
    A. You get down to, I think, definitions. I
    8
    think, technically, that whole area is in the Ohio River
    9
    Valley, but just to be clear, in terms of topography,
    10
    the site was not down on the river in the valley. It
    11
    was actually up on top of the area that then flattens
    12
    out going to the west in Ohio, so it was not down in the
    13
    valley where local sources would have inundated the data
    14
    that we were getting. It was actually up on top, and I
    15
    think, like, 400 feet above the river, to be clear.
    16
    Q. Is the meteorology of the Ohio River
    17
    Valley, as you have described it, different than the
    18
    meteorology one would typically see in Springfield,
    19
    Illinois?
    20
    MR. KIM: I think this has been
    21
    answered. I think he went through an extended
    22
    discussion about meteorological distinctions between
    23
    Steubenville and other parts of any other part of the
    24
    country. I think his specific testimony was you are not
    Page83

    1
    going to find that replicated anywhere, but
    2
    Steubenville.
    3
    MR. RIESER CONTINUES:
    4
    Q. Is that your testimony?
    5
    A. I think what I said yesterday was that the
    6
    conditions at Steubenville, in terms of the overall
    7
    source-receptor relationships, which meteorology is a
    8
    part of, are specific, to a point, and that those would
    9
    be unique to Steubenville. The question is whether the
    10
    conditions in Steubenville make it anomalous, or somehow
    11
    unique where the results would not be transferable to
    12
    somewhere else in Ohio, somewhere else in the Great
    13
    Lakes or in Illinois and I would suggest that the
    14
    conditions are not unique or anomalous to make them so
    15
    they are not usable or transferable to conditions that
    16
    we would have in Illinois.
    17
    Q. What are the conditions that are not
    18
    anomalous?
    19
    A. The weather in Ohio, just as it is in
    20
    Indiana, Illinois, Michigan, Minnesota, Wisconsin, are
    21
    all controlled by synoptic meteorology, which is the
    22
    large scale movement of the highest and low pressure
    23
    systems across the Great Lakes, so unlike some places
    24
    where they have some dominant feature, such as Bermuda
    Page84

    1
    high, which may dominate the weather in a certain
    2
    location, that might make it different than another one.
    3
    The Great Lakes, themselves, are dominated by synoptic
    4
    meteorological transport, and therefore, as long as
    5
    you're taking into account the specific meteorology that
    6
    occurs at that spot, it's not going to be all that much
    7
    different. The controlling factors are not that much
    8
    different for Illinois than Ohio.
    9
    Q. Do the presence of a large number of power
    10
    plants surrounding Steubenville, does that factor make
    11
    it anomalous to other locations?
    12
    A. Again, I think I said this before, but I
    13
    believe that the high density of power plants in the
    14
    Steubenville area is a prime reason why power plants are
    15
    a prime contributor to the extremely high deposition
    16
    that we see there. However, in another place which
    17
    would have a similar density, I believe you would see a
    18
    similar result.
    19
    Q. So to see a similar result, you would need
    20
    a similar density of power plants?
    21
    A. You could get similar amounts of
    22
    deposition different ways, but if you want to ensure
    23
    that you saw elevated, like, 70 percent contribution of
    24
    the power plants, you would need to have a significant
    Page85

    1
    emissions, upwind emissions, in the local vicinity.
    2
    Again, the upwind vicinity, to be clear, of the receptor
    3
    model or the receptor site.
    4
    Q. When you use "upwind vicinity" in that
    5
    sentence, what, specifically, do you mean?
    6
    A. The greater region.
    7
    Q. What is "the greater region"?
    8
    A. The local and regional area surrounding
    9
    the receptor.
    10
    Q. The local and regional areas we defined --
    11
    A. Previously.
    12
    MR. ZABEL CONTINUES:
    13
    Q. Dr. Keeler, what is the closest coal-fired
    14
    power plant to your monitoring site?
    15
    A. I believe it's the Samis plant located
    16
    about seven kilometers north of the Steubenville
    17
    location.
    18
    Q. Is the Samis plant on the river?
    19
    A. Yes, sir.
    20
    Q. What's the height of the stacks of the
    21
    Samis plant? Do you know?
    22
    A. It's fairly tall. I could look it up, if
    23
    you would like me to, but my guess is it's 400 or 500
    24
    feet.
    Page86

    1
    Q. But it's on the river?
    2
    A. Yes.
    3
    Q. So it's 400 feet lower than your
    4
    monitoring site?
    5
    A. The base of the plant is 400 feet lower,
    6
    and because it's seven miles up the river, I actually
    7
    don't know if it's the top of the topographic change,
    8
    which would make it more than 400 feet.
    9
    Q. Seven miles or seven kilometers? There is
    10
    a slight difference.
    11
    A. I believe it's seven miles.
    12
    Q. Was there any conversation of plume impact
    13
    from the Samis plant?
    14
    A. We actually looked for plume impact on the
    15
    Samis plant in out ambient data. We have not modelled
    16
    specific events, but we believe that we see, again,
    17
    plume impacts at our site. We haven't definitively
    18
    looked and said, "This is the Samis plant," but we do
    19
    see indications of a coal-fired utility to the north of
    20
    our site impacting the levels of mercury in SO2 and
    21
    other things that we have seen there.
    22
    Q. North of the plant would not be on the
    23
    river, I take it? I'm not familiar with the geography.
    24
    I'm just asking.
    Page87

    1
    A. Yes, it is.
    2
    Q. So it would be lower than the monitoring
    3
    site, as well?
    4
    A. The height of the stack might be
    5
    comparable in height to the elevation of the monitoring
    6
    station.
    7
    Q. How far away is that plant?
    8
    A. I'm sorry?
    9
    Q. You said same as the north?
    10
    A. Yes.
    11
    Q. I thought you identified the second plant.
    12
    A. No.
    13
    Q. We were just talking about Samis?
    14
    A. That's correct.
    15
    MADAM HEARING OFFICER: Question H,
    16
    then.
    17
    DR. KEELER: "Is this high density of
    18
    coal-fired units reflected in the CMAQ modeling
    19
    performed by U.S. EPA?" Again, basing my answer
    20
    completely on the figure that you can see in the Exhibit
    21
    30, the one we were just referring to, the base case, I
    22
    would say yes. Question I: "Is it reflected in the
    23
    TEAM modeling performed by AER?" My answer is I don't
    24
    have a recollection of seeing that output. I may have
    Page88

    1
    seen it. I just don't recall whether it was reflected
    2
    or not.
    3
    Q. Was it part of the literature that you
    4
    reviewed and you talked about reviewing model an --
    5
    A. I have read several papers in the
    6
    peer-reviewed literature that described and talked about
    7
    TEAM model and so forth. I just don't recall seeing or
    8
    visually cueing in on some area that had a specific
    9
    impact from a specific source type.
    10
    MADAM HEARING OFFICER: Mr. Rieser, I
    11
    believe that you asked earlier I got the answers to J
    12
    and K on the comparison of the Steubenville research
    13
    with the CMAQ.
    14
    MR. RIESER CONTINUES:
    15
    Q. That's correct, but I have one follow-up
    16
    on that, which is sort of the opposite. Do you know
    17
    what steps the U.S. EPA has taken to compare the results
    18
    of CMAQ to your work in Steubenville and what their
    19
    findings were?
    20
    A. Only, again, what you can see presented in
    21
    Landis presentation, that is the only thing I'm aware
    22
    of.
    23
    Q. Are you aware of the response to
    24
    significant public comments received in response to the
    Page89

    1
    revision of the December, 2000, regulatory findings on
    2
    the emissions of hazardous air pollutants from the
    3
    utility, electric utility, steam generating units, and
    4
    the removal of coal- and oil-fired -- the
    5
    reconsideration technical support document that came
    6
    out?
    7
    A. I got an E-mail as an announcement from
    8
    someone saying that this report came out. I have not
    9
    had a chance to, either, down load it, or read any of
    10
    the pages.
    11
    Q. So you haven't read the response that says
    12
    the results of the Steubenville, Ohio, receptor modeling
    13
    study corrected by EPA, ORD, Office of Research and
    14
    Development, that Dr. Landis -- are consistent with
    15
    those entangled by the CMAQ modeling?
    16
    A. Okay.
    17
    Q. You have read that?
    18
    A. No, I have not.
    19
    Q. So you haven't had a chance to review why
    20
    they say that and determine a response?
    21
    A. No. I have not downloaded that report or
    22
    read any portion of it.
    23
    Q. Thank you.
    24
    MADAM HEARING OFFICER: L.
    Page90

    1
    DR. KEELER: May I make a follow-up
    2
    comment? I think it's important to know that my modeling
    3
    half compares to my measurement half. The idea of a
    4
    good comparison is a different definition, and so in the
    5
    EPA case, without having read what they actually say,
    6
    they might view a 43 percent contribution based on the
    7
    2001 year to be fairly similar to a 70, plus or minus, a
    8
    14 or 15 percent contribution from the receptor
    9
    modeling, so just to know how they interpret "good" and
    10
    the words that you used for that. I know that they are
    11
    trying to put the best fit on that as they can.
    12
    MADAM HEARING OFFICER: Mr. Rieser,
    13
    what exactly were you reading from?
    14
    MR. RIESER: I was reading from the
    15
    Technical Support Document, which is attached to the
    16
    reconsideration of the CAMR, mercury CAMR that the EPA
    17
    announced on June 9 of 2006. It was in the Federal
    18
    Register on that date, which would be 71 Fed Reg. 33388
    19
    through 333402. I'm not sure if that's -- I have just
    20
    been advised that this is the Federal Register for the
    21
    actual reconsideration discussion, which actually
    22
    contains a little bit of this in there. The response to
    23
    comments which I read is not in the Federal Register.
    24
    It's on the U.S. EPA website, so I will be happy to
    Page91

    1
    provide a copy to you.
    2
    MADAM HEARING OFFICER: Thank you very
    3
    much. For the record, obviously, since this isn't the
    4
    federal register it's a public document and obviously,
    5
    we, at the Board, look at the Federal Register, but for
    6
    purposes of the record, it's probably best if we also
    7
    put the Federal Register reconsideration of CAMR in the
    8
    record at the same time. Do you have a clean copy of
    9
    that?
    10
    MR. RIESER: I have clean copies of
    11
    either one, so if I may, if I could bring some copies
    12
    Monday --
    13
    MADAM HEARING OFFICER: That would be
    14
    great. Thank you.
    15
    DR. KEELER: Are we -- K is gone.
    16
    "What steps have you taken to compare the results of
    17
    your Steubenville work with the EPRI TEAM deposition
    18
    models, which was included in the CAMR docket?" Again,
    19
    this was not the scope of work, nor the scientific
    20
    objective of the project that I performed, so it was not
    21
    done. Obviously, M is not applicable. That finishes
    22
    Ameren's questions.
    23
    MR. KIM: I asked for a short break
    24
    because when we might have neglected to send him the
    Page92

    1
    four questions that were presented by Prairie State and
    2
    I think he confirmed that he hadn't seem them, and I
    3
    think some of them may have been answered, but I want to
    4
    make sure that we get all the questions answered.
    5
    MADAM HEARING OFFICER: I think
    6
    Question No. 1, "Have the details of Steubenville model
    7
    been made publicly available?" That's similar to the
    8
    Ameren -- quite a bit of discussion. Second, "You state
    9
    that 70 percent of the mercury wet deposition in
    10
    Steubenville comes from coal-fired power plants. How
    11
    far have you traced back power plant plumes to reach
    12
    that conclusion?" Hundreds of miles, and we also
    13
    discussed that today.
    14
    DR. KEELER: Much longer than that.
    15
    MADAM HEARING OFFICER: So I think
    16
    question No. 3 you might want to elaborate.
    17
    DR. KEELER: "Have you modeled what
    18
    wet mercury deposition is predicted in Steubenville
    19
    after implementation of CAMR? I actually just answered
    20
    this question to some extent. Our model does not have
    21
    predictive capability, so we are not able to do that.
    22
    So the rest of the question is not applicable and 4:
    23
    "Would you expect coal-fired power plants to contribute
    24
    70 percent of the mercury to wet deposition at every
    Page93

    1
    location this the United States?" One of the things I
    2
    think would be worthwhile just pointing out -- the
    3
    answer is no, and one of the things that's worth
    4
    pointing out is when you hear these estimates of 8 to 10
    5
    percent of the mercury deposition in United States is
    6
    from U.S. sources it's kind of a small number. They are
    7
    talking about the entire land area of the United States.
    8
    Every one single square area and most of the coal-fired
    9
    utilities are in the Eastern United States, the eastern
    10
    one-third of the United States, and you would not expect
    11
    to see 70 percent contribution to Southern New Mexico,
    12
    so obviously, you would not expect that. Continuing
    13
    with that question, if not, what is the contribution of
    14
    the Illinois coal-fired power plants to mercury wet
    15
    deposition in Illinois?" I'm not sure exactly how the
    16
    questions are connected, but again, I don't have a
    17
    quantitative estimate for that to answer that question.
    18
    MADAM HEARING OFFICER: Anything
    19
    further?
    20
    MR. RIESER: Just to note for the
    21
    record that Mr. Bonebrake advised me that he had, in a
    22
    fit of preparation, actually brought copies of the
    23
    reconsideration for the federal register, and so we will
    24
    present those now. Giving the first copy to Mr. Harley.
    Page94

    1
    MADAM HEARING OFFICER: I will mark
    2
    this. This is the actual Federal Register from June 9,
    3
    2006. It's the reconsideration. It's not the comments.
    4
    We will mark this as Exhibit 31, if there's no
    5
    objection. Seeing none, it's Exhibit 31.
    6
    (Exhibit No. 31 was admitted.)
    7
    MR. FORCADE CONTINUES:
    8
    Q. Yes. If I could, I would like to ask a
    9
    Steubenville question. If I could, I would like to
    10
    direct your attention to three documents in the record
    11
    and sort of lay a frame work for the questions. The
    12
    first one is Ms. Willhite's testimony on page 3. Why
    13
    don't you grab that. In particular, in that document on
    14
    the middle paragraph contribution from point sources,
    15
    there was a sentence, "It was determined that the total
    16
    of all waste water discharges to receiving rivers and
    17
    streams in Illinois provide an average annual loading of
    18
    45 pounds of mercury." Do you see that?
    19
    A. I do.
    20
    Q. The second would be --
    21
    MADAM HEARING OFFICER: For the
    22
    record, Ms. Willhite's testimony is Exhibit No. 8.
    23
    MR. FORCADE CONTINUES:
    24
    Q. Would be the Technical Support Document at
    Page95

    1
    pages 68 and 69. On the bottom of 68 and top of 69 in
    2
    the reference to total mercury loading from MPTS
    3
    sources, and the third one would be your prepared
    4
    testimony at page five, the last paragraph, in which you
    5
    talk about the importance of coal-fired power plants to
    6
    the loading of mercury in large lakes and many down
    7
    inland lake which is have been identified as impaired
    8
    waters. The distinction I'm trying to suggest here is we
    9
    have talked a great deal about deposition, but we have
    10
    not particularly identified as much background
    11
    information on loading to the lakes and streams, and I
    12
    would like to ask a few questions, if I could, to
    13
    explore that.
    14
    First, would you say that past and
    15
    present loading to lakes and streams, particularly
    16
    impaired streams, is important in determining the amount
    17
    of mercury available for methylation?
    18
    A. Yes. It is important, and I would like to
    19
    add that some of the more recent research that had been
    20
    performed through the halogen project (phonetic) and
    21
    other work which has been published by Cindy Gilmore
    22
    suggests that it's the mercury that's recently deposited
    23
    from the atmosphere that is the most important in terms
    24
    of cycling and methylation and contamination of the
    Page96

    1
    ecosystem.
    2
    Q. I'm still trying to restrict right now my
    3
    questions to the loading to streams. You, again,
    4
    mentioned deposition.
    5
    A. Because deposition is the primary input to
    6
    most streams.
    7
    Q. You're running a bit of ahead, if you
    8
    wouldn't mind. Would you identify what you would
    9
    consider to be the sources of loading of mercury to
    10
    impaired lakes and streams?
    11
    A. Well, there's tributary inputs that load.
    12
    There's nonpoint sources from agricultural and animal
    13
    feed lots. All of the runoff from industry sites,
    14
    basically, runoff from the land into tributaries and
    15
    then direct discharges from point sources into either
    16
    tributaries or inputs to those lakes and streams.
    17
    Q. Have you done any studies to try and
    18
    evaluate those specific forms of loadings and quantify
    19
    them?
    20
    A. Anywhere?
    21
    Q. Yeah. Let's start with anywhere.
    22
    A. Yes.
    23
    Q. Could you tell me what studies you have
    24
    done?
    Page97

    1
    A. We did a rather large study in the city of
    2
    Detroit trying to -- not trying, with the objective to
    3
    quantify the importance of atmospheric deposition and
    4
    the goal of trying to identify the most significant
    5
    sources of mercury and PCB's to the receiving waters
    6
    that feed into the city of Detroit's waste water
    7
    treatment facility.
    8
    Q. I'm sorry. Was that loading to the sewers
    9
    and waste water treatment facility?
    10
    A. Yes. In other words, we worked with the
    11
    city of Detroit's waste water -- the water and sewer
    12
    department to quantify how much mercury was coming into
    13
    the head of their waste water treatment plant from all
    14
    of their network, which is a fairly large network of
    15
    homes, industry, combined storm sewer overflows and so
    16
    forth, and then to look at how much mercury they then
    17
    discharged, and part of this was wrapped around their
    18
    MPDS permit looking at how much affluent mercury they
    19
    put out and what forms, and how far of this was related
    20
    to atmosphere I think deposition.
    21
    Q. So you have done studies on the amount of
    22
    and source of mercury entering into a public-owned
    23
    treatment work?
    24
    A. Yes.
    Page98

    1
    Q. Have you done similar studies for a stream
    2
    or lake?
    3
    A. We have not done an exhaustive study in
    4
    trying to estimate the inputs to a specific tributary.
    5
    We have done some monitoring in the state of Michigan
    6
    trying to look at kind of upstream-downstream
    7
    relationships for mercury on rivers in Michigan, but
    8
    again, those were not meant to be exhaustive, in terms
    9
    of, specifically, quantifying the runoff from
    10
    agriculture, versus industrial discharge. It was just
    11
    trying to see if we could find an influence of an urban
    12
    area on a specific river or tributary.
    13
    Q. Could you identify the number or name of
    14
    those studies for me, so I can ask some questions on
    15
    them?
    16
    A. The one was -- I don't know what the
    17
    initial name was, but it was something like "Mercury
    18
    Levels in Michigan Rivers and Surface Waters" done with
    19
    the Michigan DEQ in the 90's. I actually don't remember
    20
    the exact year, sometime in the 90's, though, and then
    21
    the other study we did was something mercury PCB's and
    22
    cadminium (phonetic) in affluent -- at the city of
    23
    Detroit's waste water treatment plant, something like
    24
    that.
    Page99

    1
    Q. The second one you mentioned, would that
    2
    be the POTW study you discussed earlier or was that a
    3
    third?
    4
    A. No. That's the same one.
    5
    Q. So excluding the publicly-owned treatment
    6
    works, as far as streams lakes and rivers are concerned,
    7
    you have one study which was the 1990 Michigan study.
    8
    Is that correct?
    9
    A. Where we look, specifically, at streams
    10
    and rivers.
    11
    Q. The loading of mercury to streams and
    12
    rivers.
    13
    A. Again, as I mentioned, it wasn't a study
    14
    looking at -- it was looking at levels of mercury kind
    15
    of upstream and downstream of different urban areas or
    16
    towns, so that would be my only experience.
    17
    Q. Regarding the 1990 -- do you want to call
    18
    it study or do you have another term?
    19
    A. Which one are you referring to?
    20
    Q. The 1990 Michigan --
    21
    A. Michigan study. That's fine. When you
    22
    are asking me that, you are not asking me to talk about
    23
    the Lake Michigan Mass Balance Study.
    24
    Q. No. I'm asking you what you have done to
    Page100

    1
    evaluate the mercury loading to streams and rivers.
    2
    A. That's not my main focus area, in terms of
    3
    research.
    4
    Q. I understand, so the 1990 Michigan study
    5
    was the only one that you can point to, specifically.
    6
    Is that correct?
    7
    A. I guess, yes.
    8
    Q. Could you describe in detail what you did
    9
    in that study?
    10
    A. We made measurements of -- well, I should
    11
    say the Michigan DEQ took water samples using the
    12
    systems that we developed to measure total and dissolved
    13
    mercury and other metals in a series of rivers, and I
    14
    believe maybe lakes and across the lake and in
    15
    situations where they could make a measurement, and say,
    16
    upstream of Ann Arbor and downstream of Ann Arbor in the
    17
    Huron River, for example, to see if there's an influence
    18
    of the runoff and inputs of metals and mercury into the
    19
    stream related to that area, so it was a way to get some
    20
    survey data across the state.
    21
    Q. When you say the Michigan Department of
    22
    Environmental Quality samples, these were water quality
    23
    samples?
    24
    A. Water quality, only.
    Page101

    1
    Q. Water quality, only. Do you have an idea
    2
    of, approximately, how many sites were studied or
    3
    samples were taken?
    4
    A. I don't recall the total numbers. It was
    5
    in the hundreds.
    6
    Q. Was it a large geographic area or was it a
    7
    single stream segment?
    8
    A. I know that it encompassed the entire
    9
    lower peninsula.
    10
    Q. Of Michigan?
    11
    A. Yes.
    12
    Q. That would be a big study, then.
    13
    A. Yes, sir.
    14
    Q. What was your function, then, to take the
    15
    analytical results from Michigan DEQ and evaluate them
    16
    in some way?
    17
    A. No. Our lab that was doing that provided
    18
    the sampling equipment and did all the analytical
    19
    determinations of mercury and metal concentrations in
    20
    the samples collected and provided them with the
    21
    recorded findings. Because that's outside my typical
    22
    area of research, I didn't spend any time evaluating the
    23
    data, other than for the quality of the information that
    24
    was collected.
    Page102

    1
    Q. Did you draw any conclusions from the data
    2
    or was your evaluation simply, "Here's the analytical
    3
    results"?
    4
    A. As you had described, "Here's the
    5
    analytical results."
    6
    Q. So you performed no evaluation of the
    7
    sources or impacts or --
    8
    A. No, sir.
    9
    Q. Have you done any evaluations of the
    10
    loading of mercury to stream segments, other than this
    11
    that would be relevant to determining the amount of
    12
    mercury coming into the lakes and streams?
    13
    A. I think I have said that my expertise is
    14
    not in tributary or aquatic science. It's in
    15
    atmospheric science, so I have not performed input
    16
    analysis.
    17
    Q. Do you have any method or are you aware of
    18
    any additional reports that have been done which
    19
    evaluate the amount of loading to specific stream
    20
    segments of mercury comparing, for example, air
    21
    deposition, versus upstream water deposition?
    22
    A. Well, there was an extensive amount of
    23
    work down by the University of Wisconsin and the USGS,
    24
    as part of the Lake Michigan Mass Balance study in
    Page103

    1
    looking to -- I don't know how many tributaries into
    2
    Lake Michigan, and I know they have done an exhaustive
    3
    amount of work for Lake Superior for exactly that same
    4
    purpose for mercury and trace elements, and I have seen
    5
    presentations, and I know there's, at least, a few
    6
    publications in the peer-reviewed literature on that.
    7
    Q. The analytical results that you conducted
    8
    for the Michigan study, those are water quality
    9
    evaluations for mercury water analysis for mercury
    10
    content?
    11
    A. Yeah. They were analysis of liquid
    12
    samples that were taken from surface bodies of water.
    13
    Q. When were those done?
    14
    A. I said I believe it's in the mid 90's. I
    15
    don't recall the exact date.
    16
    Q. Do you happen to recall what analytical
    17
    method you used to test the mercury?
    18
    A. Sure. I used coal vapor atomic
    19
    fluorescence for the mercury and I used ion-coupled
    20
    masstometry (phonetic) for the trace element analysis.
    21
    Q. So would that be Method 1631, Provision E
    22
    of the mercury analysis?
    23
    A. That protocol came out after, but our
    24
    protocol is almost identical. I mean, we did not follow
    Page104

    1
    their protocol. We have our own protocol that has been
    2
    subjected to Agency peer review, and proved quality
    3
    assurance, quality control plans that we use in all of
    4
    our work.
    5
    Q. What was your method detection limit?
    6
    A. For that study, I would have to go back.
    7
    I don't recall the detection limits for the 40-some
    8
    elements that we did.
    9
    Q. I'm sorry, restricting my evaluation here
    10
    to mercury.
    11
    A. Again, I don't recall, but it was for
    12
    that -- we determine a method detection limit for every
    13
    study we do, based on the actual data, which is defined
    14
    as seven times the standard deviation of repeated
    15
    analysis of a low standard, and I don't remember the
    16
    exact number. It's -- I believe it's around a tenth of
    17
    a nanogram per liter, could be lower than that.
    18
    Q. Prior to the 1990 Michigan study, did you
    19
    do other evaluations of mercury concentrations in water?
    20
    A. I did determinations of mercury in cloud
    21
    water and fog water, yes.
    22
    Q. What time period would that be in?
    23
    A. Late 80's.
    24
    Q. Did you use the functional equivalent of
    Page105

    1
    1631 for those tests, too?
    2
    A. No. We used a much more elaborate and
    3
    exhaustive technique that requires a nuclear reactor. I
    4
    did this work at the Institute of Technology while I was
    5
    visiting scientists there.
    6
    Q. Prior to 1990, if you did not have access
    7
    to a nuclear reactor, would you not have commonly used
    8
    Method 245 or a similar method for determining mercury
    9
    content in waters?
    10
    A. I'm not sure I can answer that question.
    11
    I'm not 100 percent certain I know what "Method 245" is,
    12
    and I know that -- well, I'm not sure I can answer that
    13
    question.
    14
    Q. If you had conducted a water analysis for
    15
    mercury prior to the 1990's, and prior to the
    16
    implementation of your test protocol, do you know,
    17
    approximately, what the method detection limit would
    18
    have been available for those prior test methods?
    19
    A. If you are talking about research methods
    20
    or are you talking about those that would have been used
    21
    by states or EPA? I mean --
    22
    Q. States and EPA and facilities subject to
    23
    mercury testing.
    24
    A. You are asking me to give you a historical
    Page106

    1
    account of the analytical techniques through the 80's?
    2
    Q. That would be one way of getting to my
    3
    question, but another way would be to say is it your
    4
    understanding that Method 1631 is described as being,
    5
    approximately, 250 times more sensitive than the prior
    6
    testing protocols for mercury with significant increase
    7
    in lowering of the method detection limit?
    8
    A. I don't know the numerical number, but
    9
    from the early 1980's, the methods that were used such
    10
    as atomic absorption and coal vapor atomic absorption
    11
    have detection limits that were much higher, so they
    12
    were unable to see the small quantities of mercury that
    13
    we can see, starting in the late 80's. For some reason,
    14
    they were already beginning to use those low-level
    15
    techniques in the early 80's. Nick Bloom and Bill
    16
    Fitzgerald and his students at the University of
    17
    Connecticut had these techniques at their disposal. The
    18
    widespread use of those were regulatory, and other
    19
    monitoring purposes did not happen in the 80's.
    20
    Q. I believe it would be 1990 would be I
    21
    think the first -- do you happen to recall when the
    22
    first version of Method 1631 came out or its equivalent,
    23
    which uses the nanogram detection limit?
    24
    A. I don't know the exact date because I
    Page107

    1
    restarted using something that was similar before that
    2
    method and it actually worked its way through the
    3
    system.
    4
    Q. Would you believe it would be common,
    5
    prior to that time, for the detection limit to have been
    6
    about one part per billion or slightly less for most of
    7
    the common analytical procedure in use by states and
    8
    dischargers?
    9
    A. Well, my understanding, again -- and I
    10
    can't say this is for most or I can't put a quantitative
    11
    number on it, but I would say that most places that were
    12
    doing fish contaminant work and so forth had, at least,
    13
    a detection limit of 150 parts per trillion maximum
    14
    before they moved to coal vapor atomic fluorescence and
    15
    some of the other techniques, so it was quite a bit
    16
    higher than the .1. I mean, that's a thousand fold
    17
    different than I just quoted you 150 parts per trillion
    18
    versus the .1 that we are able to do now.
    19
    Q. But that was for --
    20
    A. Total mercury.
    21
    Q. Tissue evaluation?
    22
    A. Mercury analysis. Are you asking me for
    23
    surface water?
    24
    Q. All my questions relate to mercury testing
    Page108

    1
    for surface water.
    2
    A. I don't know the exact number to give you,
    3
    but your basic premise is correct, that detention limits
    4
    were very high and could have been approaching a part
    5
    per billion prior to the advent of the work that
    6
    Fitzgerald and his students did in the early 80's.
    7
    Q. If you were to evaluate the loading to a
    8
    stream, as you mention on page five of your testimony,
    9
    how would you determine the components, other than air
    10
    deposition?
    11
    A. Again, this is outside my area of
    12
    expertise, but I did participate in the Lake Michigan
    13
    Mass Balance study and from working collaboratively with
    14
    the University of Wisconsin and the USGS and people who
    15
    did that work, as I understand it, they make
    16
    measurements of the hydrograph, the flow of water coming
    17
    in from all the major tributaries they think are
    18
    important, and then try to take samples for mercury
    19
    using approved clean techniques to then ascertain what
    20
    the amount of mercury coming in along at different flows
    21
    from that tributary, and then sum those numbers up, so
    22
    they are a flow-proportioned calculation of how much
    23
    mercury would enter into the body of water that you are
    24
    interested in and studying. That's, more or less, what
    Page109

    1
    they did for all the tributaries for Lake Michigan. In
    2
    doing that, you come up with a total mass that entered
    3
    Lake Michigan from the Sheboygan River, and you do that
    4
    for every single one of them, so it requires an enormous
    5
    amount of work and a lot of monitoring.
    6
    Q. If you were to evaluate, for example, an
    7
    impaired lake or stream in Illinois in an attempt to
    8
    determine the amount of air deposition in loading to
    9
    that stream and compare it to the loading from other
    10
    sources, what would you do for the air deposition
    11
    portion to determine loading of that stream?
    12
    A. You are asking me, personally, what I
    13
    would do?
    14
    Q. Yes.
    15
    A. If it was a specific stream that I was
    16
    interested in, I first have to evaluate how long that
    17
    stream was, whether I felt that one monitoring location
    18
    would represent what would be coming into that stream if
    19
    it was extremely long, 20 miles long, or if it's
    20
    something longer than that, I would evaluate what point
    21
    sources were contributing to that stream, and then look
    22
    at the land use types around that stream, and then make
    23
    a determination whether I needed to put one or two
    24
    deposition where I would collect the amount of
    Page110

    1
    precipitation that fell and I gauge it, so I would have
    2
    a number of rain gauges and so forth along there, so I
    3
    could get an accurate description of the amount of
    4
    precipitation that fell into the stream and maybe even
    5
    put multiple gauges on that stream, so I could get the
    6
    flow of that stream, so I could have a good idea of then
    7
    the mass of whatever contaminant I was looking into the
    8
    stream, but it would be very stream specific, and it
    9
    would require some analysis of the situation and on-site
    10
    recognizance and so forth.
    11
    Q. If you were to complete such a study and
    12
    determine what you felt was an appropriate level of
    13
    loading from air deposition, that would simply be one
    14
    component of the loading to that particular stream
    15
    segment, wouldn't it?
    16
    A. Yes, sir.
    17
    Q. And there would be another section at
    18
    which would be the water component, sediment component.
    19
    Those other components would all contribute to the total
    20
    loading?
    21
    A. I didn't say explicit, but clearly, you
    22
    would have to make repeated measurements of the stream,
    23
    the water body of interest, both, the liquid sample, as
    24
    well as the sediments, anything else you think could
    Page111

    1
    have contributed to the loading or movement of the
    2
    contaminant through that stream.
    3
    Q. There would be no way that you could
    4
    possibly determine the relative proportion of the air
    5
    loading to that stream segment without knowing the other
    6
    components of contribution, would there?
    7
    A. If I was an engineering firm who was
    8
    requested to make a determination of the importance of
    9
    runoff, atmospheric deposition and so forth, I would use
    10
    my best expert judgment and use what data was available
    11
    to estimate the importance of these. In many cases you
    12
    don't have the actual measurements, so you have to use
    13
    expert judgment, and use whatever available measurements
    14
    are there to give an estimate for that. In the best of
    15
    all worlds, I would like to have measurements. I'm a
    16
    very measurement-greedy person. I like to have
    17
    measurements for all those things that I said, so I can
    18
    be certain of my conclusion. However, in making a best
    19
    estimate judgment, one would use the available data that
    20
    you had and put some air bars on how precise or
    21
    imprecise you would be able to estimate the various
    22
    inputs.
    23
    Q. Directing your attention to page three of
    24
    Ms. Willhite's testimony and page 69 of the Technical
    Page112

    1
    Support Document, in which it suggests that the average
    2
    MPDS has loading to Illinois streams was 45 pounds and
    3
    then comparing that to 7,022 pounds per year of mercury
    4
    emissions, that evaluation wouldn't give you any way of
    5
    determining for an impaired stream what portion was
    6
    coming from air deposition and what portion was coming
    7
    from other sources, would it?
    8
    A. Those two facts by themselves do not allow
    9
    you to calculate the specific proportion coming from the
    10
    atmosphere, versus what was coming from the tributary to
    11
    a specific stream.
    12
    Q. Would a portion of the reason be because
    13
    it talks about emissions to the atmosphere, rather than
    14
    amount loaded to the Illinois streams from air
    15
    deposition?
    16
    A. I think that's one source of uncertainty,
    17
    yes.
    18
    Q. There would be no evaluation in the
    19
    sentence that you see there about other contributing
    20
    sources, such as sediment movement, nonpoint runoff,
    21
    combined sewer overflows, types like that?
    22
    A. I'm sorry. I don't know where you are
    23
    referring to.
    24
    Q. The reference to the 40 pounds of MPDS
    Page113

    1
    loading compared to the 7,022 pounds of air emissions,
    2
    it makes no reference to any contribution coming from
    3
    surface runoff from sedimentation moving downstream or
    4
    other sources, does it?
    5
    A. I don't see any listed here.
    6
    Q. And would you consider that to be one
    7
    possible input to the stream loading for an impaired
    8
    water?
    9
    A. Yes. There is one potential input to a
    10
    potentially impaired water, yeah.
    11
    Q. Would you have any information that would
    12
    allow you to draw a rough conclusion of the amount of
    13
    stream loading to a particular stream segment that would
    14
    come from air deposition, versus other sources,
    15
    generally?
    16
    A. I wasn't asked to look at this or address
    17
    that, and that's not, again, in my typical line of
    18
    research. If I was asked to do something like that, I
    19
    may be able to put that information together, but I did
    20
    not do that, and this is the first time I have actually
    21
    thought able calculating something like that. I mean,
    22
    we have looked at this issue, in terms of looking at one
    23
    of the things we found on the Lake Michigan Mass Balance
    24
    Study was there a fairly large amount of the input to
    Page114

    1
    tributaries that they couldn't account for by looking at
    2
    runoff from agricultural areas or runoff from surfaces
    3
    and so forth, which we did a rough calculation and
    4
    determined that most of those was probably from
    5
    atmospheric, so it was the mercury that was in the rain
    6
    that fell to the ground, and then wound up running off
    7
    into the tributary. It was in the soluble phase, and so
    8
    forth, but that kind of gets at what you're asking me
    9
    here, but I have not addressed that question,
    10
    specifically, in this case.
    11
    Q. Right, but what you're talking about there
    12
    is mercury entering in the equatous (phonetic) phase.
    13
    Is that correct? You're not talking about --
    14
    A. Yeah. The river has water in it and the
    15
    rain fell and fed and goes as a liquid into the river,
    16
    yeah.
    17
    Q. So for the evaluations that you were doing
    18
    in Michigan, and for the discussion you just had, would
    19
    you use filtered samples to determine the mercury
    20
    content?
    21
    A. If I wanted to understand the mechanism
    22
    and the physiochemical transport from various fields and
    23
    so forth, I would take a total sample and definitely
    24
    filter it, so I could look at the total and dissolved
    Page115

    1
    phase, yes.
    2
    Q. And historically --
    3
    MADAM HEARING OFFICER: I apologize
    4
    for interrupting, but are you going to be able to wrap
    5
    this up? I don't want to cut you short, but it's 10
    6
    after 12, and we've been back at for a couple hours, so
    7
    if it's going to take another 20 minutes or so we might
    8
    want to go ahead and take a break, but if it's only
    9
    going to take a couple -- it's up to you.
    10
    MR. FORCADE: I'm not sure whether
    11
    it's going to take me five or 15. I'm not sure.
    12
    MADAM HEARING OFFICER: Let's go ahead
    13
    and go to lunch because we have been back at it for a
    14
    couple of hours.
    15
    MR. FORCADE: That's fine. I just
    16
    don't know.
    17
    (At which time, the proceedings were
    18
    adjourned for a lunch break.)
    19
    MADAM HEARING OFFICER: I believe
    20
    Mr. Forcade was asking Dr. Keeler some questions. Let's
    21
    go back.
    22
    MR. FORCADE CONTINUES:
    23
    Q. We had a lengthy discussion at lunch about
    24
    the co-benefits discussion about the co-benefits of
    Page116

    1
    concluding the testimony as early as possible on a
    2
    Friday afternoon, so I may be able to conclude with one
    3
    or two more questions. Dr. Keeler, if I'm not
    4
    characterizing this correctly, please let me know, but I
    5
    believe that you've made attempts to identify the source
    6
    of mercury deposition by what is, essentially, a
    7
    fingerprinting to identify the source categories. Is
    8
    that a paraphrase?
    9
    A. No. That's correct.
    10
    Q. Have you done anything to try and identify
    11
    the mercury present in fish in a similar manner?
    12
    A. I, personally, have not.
    13
    Q. That's it.
    14
    MR. HARRINGTON CONTINUES:
    15
    Q. One question. The City of Detroit Study
    16
    that you did concerning BOTW's, do you know whether
    17
    there was any effort to characterize, either bypasses or
    18
    combined sewer overflows during that study and their
    19
    impact on receiving waters.
    20
    A. Our study was focused completely on
    21
    quantifying the importance of atmospheric deposition on
    22
    PCB's, mercury to the waters that hit the head of the
    23
    plant, and we didn't really look at issues of bypass or
    24
    combined sewer overflows. We made measurements in the
    Page117

    1
    system, but we did not look at those issues.
    2
    Q. Was there significant measurable mercury
    3
    in the influence of the BOTW's?
    4
    A. We measure mercury in every sample we
    5
    collect, and yes, there was measurable mercury. Again,
    6
    our detection limits are a tenth of a part per trillion,
    7
    so you see mercury in the drinking water you have in
    8
    front of you. It's probably not of any concern.
    9
    Q. To put another way, mercury is everywhere
    10
    in the natural environment, correct?
    11
    A. Yes.
    12
    Q. Do you recall what the levels of mercury
    13
    were in the influence of publicly-owned treatment works?
    14
    A. The influence concentrations varied from
    15
    100 to 400 nanograms per liter.
    16
    Q. Thank you.
    17
    MR. FORCADE CONTINUES:
    18
    Q. Dr. Keeler, you just mentioned in response
    19
    to Mr. Harrington's question that you found mercury in
    20
    many locations. Would you expect, at that level of
    21
    detection, that you would find mercury in many MBTS
    22
    discharges (phonetic)?
    23
    A. I believe I would see mercury at least in
    24
    the trace quantities in the part per trillion level in
    Page118

    1
    all discharges.
    2
    Q. Thank you.
    3
    MR. BONEBRAKE CONTINUES:
    4
    Q. Just one other follow-up, do you recall
    5
    the eruption of Mt. St. Helens around 1980?
    6
    A. I remember it very well, yes.
    7
    Q. Was that eruption a significant source of
    8
    mercury air emissions?
    9
    A. Volcanoes are thought to be one of the
    10
    prime natural sources that put mercury into the earth's
    11
    atmosphere.
    12
    Q. Has there been any estimate of the amount
    13
    of mercury emitted into the air that resulted from that
    14
    eruption?
    15
    A. It's possible someone did a calculation.
    16
    I'm not aware of that that number.
    17
    Q. Have you ever seen a comparison of that
    18
    number, whatever it may be, to mercury emissions from
    19
    electric-generating units?
    20
    A. Again, I don't recall Mt. St. Helens, in
    21
    specific. I know that people have looked at volcanic
    22
    emissions from Italian volcanoes and a couple of others
    23
    around the world, but I don't recall Mt. St. Helens,
    24
    specifically, but it's a pretty large number. If
    Page119

    1
    volcanoes were going off continuously all the time or
    2
    every year, it would certainly change the global budget
    3
    of mercury in the atmosphere. Mt. St. Helens, if you
    4
    remember, gave us very beautiful sunsets and put a lot
    5
    of ash and sulfuric acid up in the stratosphere, so it
    6
    shot -- not only did it put a huge ash over a small
    7
    area, but it also shot a lot of stuff up into high
    8
    levels in the atmosphere, so it definitely was seen
    9
    everywhere.
    10
    Q. In fact, the mercury that went up high
    11
    levels of atmosphere, would that suggest what mercury
    12
    would have been dropping onto the ground or into the
    13
    waters for a significant period of time after the
    14
    eruption?
    15
    A. Whatever came out of the volcano,
    16
    including mercury, would have been emitted into high
    17
    altitudes and some of that perhaps could have been
    18
    removed, since a large of amount went up in the
    19
    stratosphere. I'm sure a great deal of it is probably
    20
    still up there.
    21
    Q. Thank you.
    22
    MR. HARLEY CONTINUES:
    23
    Q. At the beginning of your responses to the
    24
    questions that were posed by Mr. Forcade, you began to
    Page120

    1
    describe a study -- actually, there are two authors of
    2
    that study who were looking at the relative contribution
    3
    of atmospheric deposition to recent contribution and
    4
    cycling. Do you recall your reference to that study?
    5
    A. I'm sorry. I must have post-lunch brain
    6
    deadness. Help me a little bit.
    7
    Q. You were talking about the total loading
    8
    and methylation issue, and you began to talk about a
    9
    study, which I took to mean that recent contributions of
    10
    atmospheric deposition were most important, in terms of
    11
    methylation and also most important, in terms of
    12
    cycling, and I felt that you had more to say about that,
    13
    and I would like to hear what you had to say about that
    14
    study.
    15
    A. You're referring to I believe I referenced
    16
    Cindy Gilmore and Dave Griminhoff's (phonetic) work, as
    17
    well I think Jim Hurley from the University of Wisconsin
    18
    in the water chemistry program. Actually, there's a
    19
    fairly large group doing some work in METALLICAS, so
    20
    there's a couple different studies there, but what the
    21
    issue is there have been for years -- in fact, the
    22
    thought was that the methylmercury that was entering
    23
    into ecosystems and bioaccumulating was coming from the
    24
    bottom sediments over time and some of this born out in
    Page121

    1
    Florida through some studies, but over time, people
    2
    started to say, well, they couldn't explain the amount
    3
    of mercury and methylmercury, specifically, and as they
    4
    got better and better at making methylmercury
    5
    measurements and the BIODA and in the fish and through
    6
    the ecosystem, they started to hypothesize that the
    7
    mercury that was actually cycling, so going from the
    8
    reactive mercury form methylated by the bacteria, and
    9
    then going into the organisms was actually the mercury
    10
    that was falling out of the sky today, so the stuff that
    11
    falls out today gets chemically transformed and actually
    12
    winds up -- that's the mercury that winds up
    13
    contaminating the fish so Cindy Gilmore and colleagues
    14
    have done some studies where they have actually taken
    15
    and used as a tracer an isotope of mercury. It's one of
    16
    the masses of mercury, and they can get this mercury
    17
    from Oak Ridge National Laboratories, and other places,
    18
    and they can put that in the system in different
    19
    compartments and look to see where it goes, and in fact,
    20
    the mercury that they put in just as precipitation would
    21
    have been gone into the lake is what they actually are
    22
    now seeing coming up from the ecosystem in a fairly
    23
    rapid fashion, so their experiments are duplicating what
    24
    their hypothesis -- or confirming their hypothesis that
    Page122

    1
    what's important is what's falling out of the sky into
    2
    the ecosystem, and that's much more mobile and moving
    3
    through the ecosystem at a much faster rate than the
    4
    stuff that's buried down in sediment. In fact, some of
    5
    the stuff that's buried in sediments likely will not
    6
    become a problem at all over a very, very long
    7
    geological time frame, so that's the conclusion that
    8
    they drew. Now, again, that's the study that they have
    9
    performed thus far, and I know at the Wisconsin Mercury
    10
    Meeting that's coming up in August that more results
    11
    from that METALLICAS study will be presented.
    12
    MR. FORCADE CONTINUES:
    13
    Q. Dr. Keeler, you made reference to the fact
    14
    that the mercury that is more recently deposited into
    15
    the stream from the air, did they do comparative
    16
    evaluations of the isotopes by depositing mercury in the
    17
    water environment.
    18
    A. Yes, they did. They actually put it in
    19
    the sediments. They put it directly into the water.
    20
    They deposited it in the air. Then they actually
    21
    sprayed it on the forest ecosystem, and watched that as
    22
    it made its way to the forest and to the forest floor
    23
    and into the body of water that they were studying.
    24
    Q. Could you give me a date or name?
    Page123

    1
    A. METALLICAS, and I'm trying to think of who
    2
    the lead investigator was, but if you look up Gilmore or
    3
    Griminhoff or Hurley, I think John Rude up in Canada is
    4
    a principal in that. It's a fairly large team. I know
    5
    Steve Linberg and Jim Hurley were also involved. It's a
    6
    team of about 15 different people from, both, U.S. and
    7
    Canada that are doing that work.
    8
    DR. KEELER: The key is trying to get
    9
    at what's most important in terms of contaminating the
    10
    environment, and that's what the focus of that whole
    11
    study is and the indication is that it's recent
    12
    deposition really is the most important.
    13
    MR. FORCADE: When the questions are
    14
    over, I have a procedural question for Mr. Kim.
    15
    MR. BONEBRAKE CONTINUES:
    16
    Q. I'm just curious. You just talked about
    17
    the relative significant of more recent deposition.
    18
    Does the answer change, Dr. Keeler, in waterbodies in
    19
    which the sediment is stirred up for reasons maybe
    20
    associated with a hurricane in an area or perhaps
    21
    seasonal flooding or drudging.
    22
    A. It really depends upon how the mercury is
    23
    bound in the sediment or in the soil or whatever you are
    24
    referring to there. If it's tightly bound, it may not
    Page124

    1
    be biologically available. Mercury that's in sand,
    2
    copper sludge that they get from a copper mine, like up
    3
    in the UP of Michigan, for example, is not thought to be
    4
    very biologically available, so if it's in that form,
    5
    it's stirred up it may not actually lead to a higher
    6
    methylation rate. If it's in a bioavailable form, then
    7
    yes, it could.
    8
    Q. So would it be your sense that the
    9
    question of the relative significance of recent
    10
    deposition is going to be a question whose answer is
    11
    somewhat variable depending upon the particular
    12
    characteristics of a water body?
    13
    A. It would be characteristic of a frequency
    14
    of disturbance and the type of disturbance and the
    15
    characteristics of the water body and the inputs, yes.
    16
    All those things would be important to take in mind,
    17
    take into account.
    18
    DR. GIRARD CONTINUES:
    19
    Q. I hate to bring up Steubenville again, but
    20
    Dr. Keeler, I seem to recall that you talked about doing
    21
    air sampling every hour during that study looking at
    22
    mercury levels in the air. Was I correct in that?
    23
    A. Yes, you were correct.
    24
    Q. When you had rain events, and you had this
    Page125

    1
    sampling going on every hour, did the amount of mercury
    2
    in the air change after the rain event?
    3
    A. Again, we haven't done an exhaustive study
    4
    of every single rain event, but for the ones that we
    5
    could match up or that we did match up the ambient that
    6
    you do see a very rapid dropout in the reactive mercury
    7
    and you see a smaller, but significant, drop in the
    8
    particulate mercury levels, as well, with a very -- or a
    9
    less of a decrease in the elemental mercury
    10
    concentrations, so we see that, not just at
    11
    Steubenville, but we see that in our mercury sites in
    12
    Michigan, as well, both, in Detroit and at the site in
    13
    Dexter, which is about 30 miles to the west of Ann
    14
    Arbor, so you do see what's in ambient air increasing
    15
    precipitating systems.
    16
    Q. You hate to quantify it because the data
    17
    hasn't been fully processed, but just ballpark. I mean,
    18
    are we talking just a 50 percent reduction or 100
    19
    percent reduction? What kind of a reductions are you
    20
    looking at after a rain event?
    21
    A. If it's a prolonged rain, if it's a rain
    22
    that lasts more than an hour because that's hour time
    23
    frame of our measurement, so we have to have something
    24
    that goes longer than an hour in order for me to answer
    Page126

    1
    your question. If it's a longer rain that goes more
    2
    than an hour, you will see complete depletion of the
    3
    reactive mercury from the air. Particulate mercury is
    4
    already very low, so that goes to nothing, as well, and
    5
    elemental will stay, approximately, with a background is
    6
    1.5 nanograms per cubic meter and doesn't really change
    7
    much in terms of through a rain event, so after an
    8
    event, say, that's over an hour where it reduces the
    9
    mercury in the air down to zero, how quickly do you see
    10
    the mercury levels go back up? It really depends upon
    11
    the reason that the rain fell. If it was a frontal
    12
    system where the wind is changed, sometime it doesn't
    13
    come back up for quite a wile. If the wind stays coming
    14
    from the same direction, as soon as the rain is over,
    15
    there will be a period of time where it could be like
    16
    the next hour or the hour after that you will see it
    17
    start to raise back up again, so there is a one-to-one
    18
    correspondence. I just haven't quantified it, but at
    19
    our site in Dexter, we actually -- did quantify it for a
    20
    period or time and it was exactly a 50 percent reduction
    21
    an hour after the rain came, but then we were making
    22
    measurements every other hour, so that we couldn't -- it
    23
    wasn't as clean. For a long rain, you see it go right
    24
    to nothing. For a rain that lasted 30 minutes, the
    Page127

    1
    following hour reactive mercury would be half as much,
    2
    and then whether it came back up or not depended upon
    3
    which way the wind was blowing. The reactive and
    4
    particulate mercury concentrations that we see at
    5
    Steubenville and in Michigan are very wind directional
    6
    and very transport specific. We get transport from the
    7
    north in Michigan, for example, we see very little often
    8
    with strong winds, especially during the wintertime and
    9
    in the summertime, when the wins switch around, you see
    10
    very high concentrations, but with very specific wind
    11
    directions, and it always responds the same when it
    12
    comes to precipitation. We do not have any examples of
    13
    high RGM with precipitating events going through for
    14
    multiple hours where it stays up and that goes along
    15
    with the understanding of how soluble and reactive
    16
    mercury is in the atmosphere.
    17
    MR. FORCADE: If I could have a
    18
    procedural question. Earlier this week in the panel
    19
    discussion I asked a series of questions about MPDS
    20
    discharges mercury content and the contribution of total
    21
    loading as described on page 69 of the Technical Support
    22
    Document. There are two references supporting that in
    23
    the Technical Support Document, and both of those
    24
    references are incorrect. They have absolutely nothing
    Page128

    1
    to do with calculating mercury, affluent limitations.
    2
    As far as I'm concerned right now, there is no support
    3
    for those tables. I have asked -- and I don't need the
    4
    information today -- but there's a significant open
    5
    question which I need information from the Agency to
    6
    explore, and I would like to just, not for purposes of
    7
    asking questions today, just remind them that that is a
    8
    significant open question that I need to explore for the
    9
    conclusion of these hearings next Friday.
    10
    MR. KIM: Indeed, Mr. Forcade did
    11
    raise that. We tried to initially provide the documents
    12
    that were referenced, and I think I am in agreement with
    13
    him that it doesn't really seem to mesh up with what was
    14
    in there, so we are in the process of getting that
    15
    information, and I'm pretty certain we are going to have
    16
    it for you Monday or Tuesday, at the latest, next week.
    17
    So if it could wait until then.
    18
    MR. FORCADE: That's fine with me.
    19
    MR. KIM: It's not forgotten.
    20
    MADAM HEARING OFFICER: There were a
    21
    couple of things today that we had talked about from
    22
    Dr. Keeler. One was I believe you have in front of you.
    23
    MR. KIM: Actually , I was going to
    24
    say there were a couple things I was going to bring up
    Page129

    1
    just to sort of close some loops. METALLICUS, the
    2
    acronym, I can give you what that stands for, if you
    3
    want that. And then the last thing -- this was just
    4
    something that was referenced after trying to get a copy
    5
    of the Powerpoint presentation that Dr. Keeler made
    6
    reference to a while back and I think it's -- I think
    7
    the Board and the Agency were the only people that
    8
    didn't actually have this. I think I have two copies.
    9
    MADAM HEARING OFFICER: If there's no
    10
    objection, we will mark this as Exhibit No. 32. Seeing
    11
    none, "Mercury Deposition in the Great Lakes Region,
    12
    James Keeler, University of Michigan Air Quality
    13
    Laboratories" is marked as Exhibit 32.
    14
    (Exhibit No. 32 was admitted.)
    15
    MR. KIM: I believe this is maybe in
    16
    more specific with some nice pictures, but it's,
    17
    essentially, everything that -- there is a Far Side
    18
    cartoon I think it's pretty much a Powerpoint
    19
    presentation of everything that's been testified to thus
    20
    far, but we did want to make sure we got that in. It
    21
    took a little while because it was all in color and we
    22
    had technical difficulties. We have no more color ink
    23
    left in the building.
    24
    MADAM HEARING OFFICER: The other item
    Page130

    1
    that we discussed this morning was the emissions data
    2
    that was a part and a map. Mr. Matoesian was talking
    3
    about that this morning and you said you would get that
    4
    for us.
    5
    MR. KIM: Yes.
    6
    MADAM HEARING OFFICER: Are we still
    7
    in the process of looking for that?
    8
    MR. KIM: That's information that we
    9
    are going to have to print out I think from U.S. EPA's
    10
    website, so that might -- we'll get that, but it may not
    11
    be until Monday or Tuesday.
    12
    MADAM HEARING OFFICER: That's fine.
    13
    I just wanted to double check on that.
    14
    MR. KIM: We have four copiers on the
    15
    Division of Legal Counsel floor. At any given time, one
    16
    of them is working, so I'm assuming that ratio holds
    17
    true throughout the Agency.
    18
    MADAM HEARING OFFICER: Is there
    19
    anything else for Dr. Keeler?
    20
    MR. RIESER: Maybe one thing to do.
    21
    Obviously, we visually observed the LADCO report at the
    22
    time it was given, but we haven't had a chance to look
    23
    at it. Perhaps if Dr. Keeler can sit for another hour
    24
    or, so maybe we can proceed with Dr. Hornshaw give us a
    Page131

    1
    chance to look at this, and then if we can come back.
    2
    It shouldn't take that long, but I just need to check to
    3
    see if there's any other questions.
    4
    MADAM HEARING OFFICER: Is that
    5
    possible, Dr. Keeler?
    6
    DR. KEELER: That's about right. I
    7
    have another hour and 10 minutes.
    8
    MR. RIESER: If it would help, the
    9
    minute I'm ready to ask some questions, if I have any
    10
    one way or the other, I can put my hand up. I hate to
    11
    interrupt the flow of somebody else's questioning.
    12
    MR. KIM: Two airlines in Springfield,
    13
    so I think our people are just struggling to hold on to
    14
    the reservations they have got, but that's fine. If,
    15
    during his testimony you want to just interrupt, that's
    16
    fine with us.
    17
    MADAM HEARING OFFICER: Then shall we
    18
    begin with Dr. Hornshaw? Before that, Dr. Keeler I want
    19
    to, personally, thank you very much. It's been very
    20
    enlightening.
    21
    22
    23
    24
    Page132

    1
    STATE OF ILLINOIS)
    2
    COUNTY OF ST. CLAIR)SS
    3
    4
    I, Holly A. Schmid, a Notary Public in
    5
    and for the County of Williamson, DO HEREBY CERTIFY that
    6
    pursuant to agreement between counsel there appeared
    7
    before me on June 16, 2006, at the office of the
    8
    Illinois Pollution Control Board, Springfield, Illinois,
    9
    Dr. Gerald Keeler, who was first duly sworn by me to
    10
    testify the whole truth of his knowledge touching upon
    11
    the matter in controversy aforesaid so far as he should
    12
    be examined and his examination was taken by me in
    13
    shorthand and afterwards transcribed upon the typewriter
    14
    (but not signed by the deponent, his signature having
    15
    been waived by agreement of counsel) and said deposition
    16
    is herewith returned.
    17
    IN WITNESS WHEREOF I have hereunto set
    18
    my hand and affixed my Notarial Seal this 30th day of
    19
    June, 2006.
    20
    __________________________
    21
    HOLLY A. SCHMID
    22
    Notary Public -- CSR
    23
    084-98-254587
    24
    Page133

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