1. PROCEDURAL HISTORY
    2. Summary of Public Comments
    3. 2005 FIRST NOTICE COMMENTS
      1. Opposition to the Proposed Section 302.207(d)
    4. The Radium Water Quality Standard Expressed as a Long-Term A
      1. Whether Consideration of Economic Factors Was Proper
      2. Sediment Monitoring
    5. New Data Submitted by the City of Joliet
    6. Radioactive Water Treatment Residuals
      1. The Agency’s Public Comment (PC 50)
      2. Consistent With Board Regulations
      3. Consistent With the Record
      4. Protective of Drinking Water Intakes
      5. Relief For POTWs
      6. DISCUSSION OF SECOND-NOTICE PROPOSAL
    7. Consideration of Economic Factors
      1. Radium General Use Water Quality Standard Expressed as a Lon
    8. Public and Food Processing Water Supply Standard
    9. CONCLUSION
      1. ORDER

ILLINOIS POLLUTION CONTROL BOARD
December 15, 2005
IN THE MATTER OF:
)
)
REVISIONS TO RADIUM WATER QUALITY
)
R04-21
STANDARDS: PROPOSED NEW 35 ILL. ADM. )
(Rulemaking – Water)
CODE 302.307 and AMENDMENTS TO
)
35 ILL. ADM. CODE 302.207 and 302.525
)
Proposed Rule. Second Notice.
OPINION AND ORDER OF THE BOARD (by N.J. Melas):
Today the Board proposes revisions to the general use water quality standard for radium
based on new facts and public comments the Board has received since the 2005 second first-
notice publication. At first notice in 2004, the Board adopted the proposal filed by the Illinois
Environmental Protection Agency (Agency). At second first notice in 2005, the Board proposed
a general use water quality standard of 3.75 picocuries per liter (pCi/L) radium 226 and 228
combined (combined radium) applicable to all general use waters of the State. In addition, the
Board proposed a general use water quality standard of 30 pCi/L combined radium applicable to
waters receiving discharge from publicly owned treatment works (POTWs). The 30 pCi/L
standard applied from the point of discharge to one mile downstream of the discharge outfall and
was incorporated as a new Section 302.207(d).
The Board adopts the proposed rule for second-notice review by the Joint Committee on
Administrative Rules (JCAR) pursuant to the Illinois Administrative Procedure Act (5 ILCS
100/1-1
et seq
.). The Board received 13 public comments subsequent to the 2005 first-notice
publication, and the proposal adopted here is substantively changed from that adopted in the
2005 first notice opinion and order in light of those comments. Today the Board amends the
general use water quality standard for combined radium 226 and 228 adopted for the 2005 first
notice. The Board retains the standard of 3.75 pCi/L combined radium 226 and 228, but sets the
standard as an annual average value, rather than an instantaneous maximum standard.
The Board finds that the changes to the Board’s 2005 first-notice proposal adopted today
are warranted. The comments received during the 2005 first-notice period clearly indicate a
need for further amendments to this section. The record consistently demonstrates a need to
maintain a general use water quality standard, protective both of human health and the
environment. The Board invited and received comments on the new Section 302.207(d)
proposed the 2005 first notice. The additional data and comments received enhanced the record
with respect to actual levels of combined radium contained in water before and after treatment by
Northern Illinois publicly owned treatment works. The Board finds that based on the record,
today’s proposal meets the Board’s stated objectives while also tailoring the general use water
quality standard for radium to the nature of radionuclides in Illinois ecosystems.

 
2
In this opinion, the Board provides the procedural history of this rulemaking, an
overview of the public comments received, and a discussion of the second-notice proposal.
OVERVIEW OF THE PROPOSED CHANGES IN RADIUM WATER QUALITY
STANDARDS FOR SECOND NOTICE
The Board modifies the general use water quality standard for combined radium 226 and
228 adopted for the 2005 first notice. The Board retains the standard of 3.75 pCi/L combined
radium 226 and 228, but sets the standard as an annual average value, rather than an
instantaneous maximum standard, as proposed for the 2005 first notice. This standard, as before,
applies to all general use waters of the State, including stream segments that receive discharge
from POTWs, as well as the Lake Michigan Basin. In addition, today’s proposal eliminates the
separate water quality standard of 30 pCi/L adopted at second first notice for stream segments
that receive discharge from POTWs. Finally, the Board adopts a 5pCi/L combined radium 226
and 228 standard for Public and Food Processing Water Supplies as an instantaneous maximum
standard for public and food processing water supply intakes.
The Board finds that today’s proposal for second notice more precisely achieves the
Agency’s goal of relieving a regulatory burden for many existing POTWs that may not comply
with the existing general use radium water quality standards while remaining protective of the
most sensitive designated use of the State’s waters. Dischargers such as POTWs will benefit
because compliance with the proposed standard is based on a long-term average.
PROCEDURAL HISTORY
On January 13, 2004, the Agency filed a proposal to amend Part 302 of the Board’s water
quality standards.
1
The Agency proposed to change the general use and Lake Michigan water
quality standards for radium from 1 pCi/L radium 226 to 5 pCi/L combined radium 226 and 228
and apply the proposed standards specifically to surface waters used for public and food
processing water supplies. According to the Agency, these changes would make the radium
water quality standards consistent with the federal finished water maximum contaminant level
(MCL) and ensure the protection of surface water intakes for raw drinking water in the State.
The Agency argued the proposed changes would also relieve a regulatory burden for many
existing POTWs that receive, treat, and discharge wastewater from public water supplies that
remove radium from high radium groundwater.
The Board accepted this proposal for hearing on January 22, 2004. The Board has held
five days of hearings before the Board hearing officer, members, and staff. The first hearing was
held on April 1, 2004, at the James R. Thompson Center in Chicago.
2
The second hearing was
1
The Agency’s Statement of Reasons included in the rulemaking proposal will be cited as
“Statement at _.”
2
The transcript of the first hearing will be cited as “Tr.1 at _.”

 
3
held on May 6, 2004, at the Board’s offices in Springfield.
3
Both hearings allowed the
proponent and any other interested party the opportunity to present testimony on the merits and
economic impact of the rulemaking proposal.
On June 2, 2004, WRT Environmental (Illinois), L.L.C. (WRT Environmental) moved
the Board for an additional merit hearing. On July 8, 2004, the Board adopted the Agency’s
proposal for publication of first notice in the
Illinois Register,
but noted by hearing officer order
that the Board would grant WRT Environmental’s motion for a third hearing. First notice was
published in the
Illinois Register
on August 6, 2004. 28 Ill. Reg. 32, pg. 10887,
eff
. Aug. 6,
2004. First-notice publication in the
Illinois Register
began a public comment period for
interested persons to file comments with the Board. The Board granted the motion and held a
third hearing on August 25, 2004, in Springfield.
4
The Board gave notice of hearings a fourth
time and they continued on October 21 and 22, 2004, in Chicago.
5
On April 7, 2005, the Board adopted the proposal, with modifications, for publication of
the 2005 first notice in the
Illinois Register
. The 2005 first notice was published in the
Illinois
Register
on April 11, 2005. 29 Ill. Reg. 17, pg. 5782,
eff.
Apr. 11, 2005. Second first-notice
publication began another 45-day public comment period. On May 13, 2005, the City of Joliet
(Joliet) moved the Board to extend the public comment period through August 15, 2005. The
Board granted the motion and extended the comment period as requested.
The Board received 12 additional public comments during the second first-notice
comment period. After the close of public comment, WRT Environmental moved the Board for
leave to file a supplemental public comment, accompanied by the supplemental public comment.
The Board grants WRT Environmental’s motion and accepts the supplemental public comment.
Summary of Public Comments
The Board received 13 additional comments subsequent to second first-notice
publication, for a total of 52 public comments in this proceeding. The additional comments
consist primarily of those that oppose the Board’s second first-notice proposal and those that
support the proposed standard of 3.75 pCi/L combined radium, but oppose the separate 30 pCi/L
standard up to one-mile below POTW discharges.
Those that submitted comments opposing the Board’s proposal include the directors of
Citizens Against Ruining the Environment (CARE) (PC 40, 42, and 43), the City of Joliet
(Joliet) (PC 46), and the Fox River Reclamation District (PC 51). The following commenters
reject the proposed Section 302.207(d) and offer support for the 3.75 pCi/L standard, however,
propose that compliance be measured as a long-term average: the United States Environmental
3
The transcript of the second hearing will be cited as “Tr.2 at _.”
4
The transcript of the third hearing will be cited as “Tr.3 at _.”
5
The transcript of the fourth hearing will be cited as “Tr.4 at _.”

 
4
Protection Agency (USEPA) (PC 41), the Sierra Club and the Environmental Law and Policy
Center (Envrionmental Groups) (PC 44), WRT Environmental (PC 48), and the Illinois
Environmental Protection Agency (PC 50).
2005 FIRST NOTICE COMMENTS
During the 2005 first notice comment period, the participants in this rulemaking
discussed both the 3.75 pCi/L general use water quality standard as well as the 30 pCi/L standard
for streams receiving discharge from POTWs that the Board adopted at the 2005 first notice. A
review of the public comments reveals that a majority of the participants supported the general
use standard and the most disagreement arose over the separate standard provided for POTWs.
Below the Board discusses the comments and provides reasons for today’s divergence from the
2005 proposed rule adopted for first notice. Because the Agency is the proponent of this
rulemaking, the Board will discuss the Agency’s 2005 first-notice comment separately below.
Opposition to the Proposed Section 302.207(d)
In its public comment, the USEPA expressed concern that the proposal did not
adequately demonstrate that 30 pCi/L within a one-mile mixing zone would provide a level of
protection consistent with the 3.75 pCi/L value, nor any other independent level of protection for
the designated use. The USEPA also states it is not clear how the proposed 30 pCi/L standard
would be implemented to protect possible downstream public water supply intakes.
In its public comment, CARE strongly objects to the addition of Section 302.207(d) of
the Board’s 2005 proposal. PC 45. CARE states that proposed Section 302.207(d) is premature
and will be until 2009. Non-compliant public water suppliers have until 2007 to come into
compliance with the Federal drinking water standards. According to CARE, by the end of 2008,
many of the problems anticipated by the Board’s proposed Section 302.207(d) may be resolved.
Therefore, CARE advises that the Board abstain from establishing a rule like 302.207(d) until
public water supplies achieve compliance since many of the techniques they employ may
eliminate or substantially reduce the amount of radium in wastewater.
CARE also states that the proposed Section 302.207(d) establishes a “de facto” mixing
zone without having followed the well-developed regulatory approach the Agency must follow
in reviewing mixing zones. CARE contends that an approach that allows for regulatory
flexibility under specific circumstances as judged on a case-by-case basis is “far preferable than
the categorical, ‘carte blanche’ for POTWs contained in proposed rule 302.207(d).”
Joliet commented that the Board ignored the recommendation of the Division of Nuclear
Safety (DNS), and instead “gave great weight to the testimony provided by Water Remediation
Technology.” The Board’s proposal, however, does not directly follow either party’s proposal.
The standard proposed by the DNS was a standard applied to cleanups of spills containing
radium. A general use water quality standard must take into consideration the exposure of the
most sensitive use of the water body to the radium levels over a lifetime. In particular, the
Board’s standard reflects the effects of radium on the reproductive cycles of aquatic wildlife.

 
5
On this point, Joliet states that it is unlikely that sensitive species live in the receiving
streams of plants that are expected to violate the proposed standard. PC 46 at 5. For example,
Joliet states that Don Blancher, PhD of Toxicological and Environmental Associates, Inc. opined
that low flow streams represent poor or unsuitable habitat for species like muskrat and the length
of time for exposure in these areas would be minimal.
Id
. Dr. Blancher based his determination
on the U.S. Fish and Wildlife Services Habitat Suitability Index Model for muskrat which
indicates that muskrat habitat is in streams with flow rates of 0.4 c.f.s. to 30 c.f.s. in waters with
depth greater than 18 inches.
Joliet argues that because no sensitive species live downstream of impacted treatment
plants in Illinois, there is no reason to establish such a restrictive standard. For this reason, Joliet
concludes that the standard of 60 pCi/L radium, proposed by the Illinois Emergency
Management Agency, DNS, is appropriate. Joliet also supports the DNS suggestion to apply a
safety factor of 2.0 for a water quality standard of 30 pCi/L combined radium.
Joliet contends the Board’s proposal for the 2005 first notice does not consider other
radium discharges in Illinois that do not originate from wastewater treatment plants. In the way
of examples, Joliet provides sources such as deep wells used for irrigation of golf courses and
agriculture, deep wells used during testing, and fire hydrants. PC 46 at 4. However, Joliet did
not provide any specific examples or levels of radium contained by such releases.
WRT Environmental agrees with the USEPA’s comment that the proposed Section
302.207(d) provides no level of protection consistent with the designated use. Further, WRT
Environmental contends that the proposed standard of Section 302.207(d) is not “‛based on
sound scientific rationale,’ as required by the [Clean Water Act] CWA.” PC 48 at 10; citing 40
C.F.R. 131.11(a)(1). WRT Environmental concludes that the “one-mile exemption zone” is
contrary to federal and state law and unsupported by the record. WRT Environmental urges the
Board to delete the proposed Section 302.207(d).
The Radium Water Quality Standard Expressed as a Long-Term Average
The USEPA recommends that the Board express the proposed standard as an average
value over some period of time to reflect long-term exposure, rather than an instantaneous value.
As an example, the USEPA refers to its Great Lakes Water Quality Guidance (40 C.F.R. 132),
which recommends that waste load allocations based on wildlife standard be calculated using the
90-day, 10-year low flow as the design flow. The USEPA continues that if the Board takes this
approach, it should also implement a 5 pCi/L Public and Food Processing Water Supply standard
as an instantaneous maximum standard to ensure that public water supplies meet the Federal
drinking water maximum contaminant level for radium.
The Environmental Groups agree with the USEPA’s argument that an average value
radium standard is consistent with the goal not to exceed the biota dose limit of 0.1 rad/day for
riparian animals. PC 44 at 4. Nonetheless, the environmental groups emphasize that if such an
approach is taken, it is even more important to monitor in-stream sediment outside of that zone.

 
6
Joliet also does not object to the use of an annual average, and states in fact, that the use
of the annual average would reduce the number of plants with potential violations from nine
plants to between two and six.
Whether Consideration of Economic Factors Was Proper
According to the environmental groups, economic factors should not be considered in
setting general use water quality standards, and even considering economic factors, there is no
evidence it would be costly to comply with the combined 3.75 pCi/L standard anywhere.
The environmental groups state that economic factors should not be taken into account in
setting the numeric standards that are protective of uses. The appropriate considerations are
whether the designated uses are “based on a sound scientific rationale” and protect the “most
sensitive use.” PC 44 at 2; citing 40 C.F.R. 131.11(a);
People v. PCB, 103 Ill. 2d 441, 469 N.E.
2d 1102, 1108 (Ill. 1984). On the other hand, state the environmental groups, economic factors
are irrelevant to setting such criteria. PC 44 at 2; citing
Mississippi Commission on Natural
Resources v. Costle, 625 F.2d 1269, 1277 (5th Cir. 1980).
The environmental groups further state that the hearing record contains no testimony
showing that the 3.75 pCi/L standard would be costly for any discharger. PC 44 at 3. The
environmental groups state that new post-hearing data submitted by Joliet indicates that in-
stream levels of combined radium were less than 1.5 pCi/L at all locations tested. The data also
showed, state the environmental groups, that almost all of the communities would meet the 3.75
pCi/L standard with a standard mixing zone. The environmental groups conclude that even if it
was considered, there is no substantial economic reason for the proposed Section 302.207(d).
Id
.
Sediment Monitoring
The Environmental Groups support the Board’s reliance on the Department of Energy
(DOE) technical standard
6
as guidance to establish a water quality standard for combined radium
applicable to general use waters and the Lake Michigan Basin. PC 44 at 3. However, the
environmental groups note that the proposed standard of 3.75 pCi/L does not consider the
contribution of radium from stream sediment.
Id
. Therefore, the environmental groups
recommend that the Board include in the rule a requirement that the Agency must include in
POTW permits a requirement to monitor stream sediment at a point outside of the mixing zone.
The environmental groups state that monitoring would ensure that radium particles were not
building up in the sediment and exceeding the biota dose limit of 0.1 rad/day.
Id
.
CARE also advocates a comprehensive review by the Agency of the adequacy of Illinois’
regulations concerning radium that originates in drinking water. PC 43 at 4. It is inadvisable,
6
See
Hearing Exhibit 15, “A Graded Approach for Evaluating Radiation Doses to Aquatic and
Terrestrial Biota (DOE-STD-1 153-2002),” for Use in DOE Compliance and Risk Assessment
Activities, U.S. Department of Energy, Domotor, Stephen, July 2002.

 
7
according to CARE, to consider the water quality issue in isolation without also considering
related issues such as the land application of POTW biosolids that contain radium.
Id
.
New Data Submitted by the City of Joliet
Joliet identified fourteen treatment plants as having potential problems complying with
the proposed standards. Joliet collected wastewater plant data from eleven of those plants, seven
of which would violate an instantaneously applicable standard of 3.75 pCi/L combined radium.
The data does not demonstrate the actual radium levels one mile downstream of the POTWs’
discharge.
WRT Environmental interprets Joliet’s data to reveal that most communities can meet the
3.75 pCi/L standard even before applying averaging factors for grab and composite sampling, or
before mixing in the receiving stream. PC at 4; citing 35 Ill. Adm. Code 304.104; PC 46, Att. 1.
The Environmental Groups state they could not comment on dischargers from communities A
and B because of the lack of information regarding the nature of the receiving water bodies and
uncertainty with the Monmouth data. PC 44 at 3. Like Joliet, the environmental groups state
that the data suggests that the rest of the dischargers would be able to meet the 3.75 pCi/L
standard with a standard mixing zone, if needed. According to the environmental groups, the
new data further suggests that there is no substantial economic reason for the special pCi/L
mixing zone included in the Board’s proposal.
Id.
Radioactive Water Treatment Residuals
WRT Environmental states that it supports the proposed 3.75 pCi/L combined standard,
yet urges the Board to open an inquiry docket or present a warning comment on the amended
rule to address the issue of residual solids or sludge. PC 48 at 12. WRT Environmental takes
the position that the sludge issue is not only a part, but “the
major issue in this proceeding.” PC
at 48.
By repealing the 1 pCi/L radium 226 limit, WRT Environmental contends the Board
should not simultaneously “open the door for the disposal into waterways of sludge that was
previously illegal and regulated.” PC 48 at 17. To prevent this, WRT Environmental proposes
that the Board insert a warning comment into its rules referring to a USEPA guidance manual
regarding the management of radionuclide residuals from drinking water treatment technologies,
or alternatively, initiate hearings on the adequacy of existing regulations for radionuclides.
Because the proposed rulemaking fails to address the re-introduction of radioactive
residuals into the environment following treatment, WRT Environmental claims the rulemaking
violates applicable Illinois environmental law, such as the Illinois Pollution Prevention Act, the
Illinois Groundwater Protection Act, the Illinois Low Level Radioactive Waste Management
Act, the Illinois Endangered Species Act, and the Environmental Protection Act. PC 48 at 19.
In summary, WRT Environmental reiterates its support for the As Low As Reasonably
Achievable (ALARA) standard. WRT continues that the ALARA philosophy would not include

 
8
the proposed Section 302.207(d), or allowing an unnecessary risk of radium exposure to POTW
workers.
The Agency’s Public Comment (PC 50)
The Agency prefers its original January 2004 proposal and disagrees with the Board’s
reliance on certain technical documents incorporated into the record and cited in the Board’s
2005 first-notice opinion and order. However, in its 2005 first-notice public comment, the
Agency offers suggestions on “the best way to achieve [the Board’s] goals within the framework
established in its April 2005 Opinion and Order and the requirements of the Clean Water Act.”
PC 50 at 3.
As discussed below, the Agency favors the USEPA’s recommendation of using long-term
averaging for the radium general use water quality standard and suggests how it may implement
such a standard. The Agency states that using “long term flow values in developing mixing
zones would more closely achieve the Board’s stated goals.” PC 50 at 6.
Consistent With Board Regulations
The Agency suggests the Board should regulate radium based on an annual average
concentration of radium present in the water body due to the nature of radium. The Agency
states that, for example, in Subtitle E of the Board’s regulations (35 Ill. Adm. Code 501-580),
bioaccumulative substances such as PCBs or DDT are regulated based on concentrations present
during 90Q10 or higher stream flow conditions. PC 50 at 7. The Agency explains that 90Q10 is
the average minimum 90 day low flow that is predicted to occur once every 10 years. The
Agency states that using this approach, discharged concentrations of the regulated substance will
be diluted much of the time due to a water body having a higher than 90Q10 flow.
Id
.
Therefore, the Agency states the concentration of substances remains acceptably low and
wildlife species are protected.
Id
.
The Agency provides two additional examples where the Board uses a flow value other
than 7Q10: (1) harmonic mean flow values used for the Human Nonthreshold Criterion of the
Board’s water quality standards; and (2) an annual average used in the Human Health Standard
used for mercury and benzene. PC 50 at 8. Radium is different because it affects wildlife
through simple exposure, rather than bioaccumulation. For this reason, argues the Agency, it is
more appropriate to regulate radium based on long-term averaging, rather than an instantaneous
standard. For all of these reasons, the Agency recommends that the Board adopt a General Use
and Lake Michigan Basin radium water quality standard of 3.75 pCi/L combined radium based
on an annual average concentration in the water body. PC 50 at 8-9.
Consistent With the Record
The Agency asserts this recommendation is consistent with the use of the biota dose
assessment of the DOE model. This document models the reproductive effects of radium on
riparian mammals that occur over a lifetime of exposure to radium concentrations in the

 
9
environment. PC at 9. The Agency states that the exposure period used in the DOE model is
consistent with the Agency’s annual average exposure period recommendation. PC 50 at 9.
Protective of Drinking Water Intakes
The Agency asserts that the Board has “removed the use of a Public and Food Processing
Water Supply standard matching the U.S. EPA’s MCL for radium in drinking water.” PC 50 at
10. The Agency recommends that the 5 pCi/L drinking water standard should remain an
instantaneously applied standard applicable to drinking water intakes at all times.
Id
. While it is
not aware of any present or potential situations where an upstream discharge would cause a
Public and Food Processing Water Supply surface water intake to exceed 5 pCi/L, the Agency
agrees that the standard should be adopted as a safeguard.
Id
.
Relief For POTWs
The Agency concludes that of the impacted POTWs, many or most would have difficulty
complying with the instantaneously applied combined standard of 3.75 pCi/L, even one mile
below their discharge point as those standards are currently implemented. PC 50 at 11.
However, the Agency concludes from the data submitted by Joliet that the 3.75 pCi/L standard
based on long term averaging will likely provide relief to many of the impacted dischargers in a
way that is protective of the most sensitive uses of all waters of the State of Illinois. PC 50 at 12.
Further, as evidenced by the Agency’s proposed regulatory language, the Agency recommends
that the Board allow mixing in low flow streams that receive radium discharge to provide relief
to a few POTWs that discharge to such streams. PC 50 at 12.
The Agency’s (PC 50) Proposed Regulatory Language
Section 302.207
Radioactivity
a)
Gross beta (STORET number 03501) concentration shall not exceed 100
picocuries per liter (pCi/L).
b)
Concentrations of radium 226 (STORET number 09501) and sStrontium 90
(STORET number 13501) concentration must not exceed
1 and 2 picocuries per
liter (pCi/L)
respectively.
c)
The annual average radium 226 and radium 228 (STORET number 11503)
combined concentration must not exceed 3.75 picocuries per liter (pCi/L).
1)
For purpose of this subsection, the requirement of Section 302.102(b)(8)
of this Part that mixing is not allowed in receiving waters which have a
zero minimum seven day low flow which occurs once every ten years does
not apply; and
2)
Mixing zones for radium dischargers may be calculated using the annual
average stream flow present at the point of discharge.

 
10
SUBPART C: PUBLIC AND FOOD PROCESSING WATER SUPPLY STANDARDS
Section 302.307
Radium 226 and 228
Radium 226 and 228 (STORET number 11503) combined concentration must not exceed 5
picocuries per liter (pCi/L) at any time.
SUBPART E: LAKE MICHIGAN BASIN WATER QUALITY STANDARDS
Section 302.525
Radioactivity
Except as provided in Section 302.102, all waters of the Lake Michigan Basin must meet the
following concentrations
in any sample:
a) Gross beta (STORET number 0351) concentrations must not exceed 100 picocuries
per liter (pCi/L).
b)
Concentrations of radium 226 (STORET number 09501) and sStrontium 90
(STORET number 13501) concentration shall not exceed
1 and 2 picocuries per liter
(pCi/L)
respectively.
c)
The annual average radium 226 and 228 (STORET number 11503) combined
concentration must not exceed 3.75 picocuries per liter (pCi/L).
DISCUSSION OF SECOND-NOTICE PROPOSAL
Below the Board analyzes the participants’ recommendations and other issues raised in
public comments. The Board will also discuss the second-notice changes and give reasons for
the changes.
The parties generally agree that evidence exists demonstrating that a general use water
quality standard for radium 226 and 228 combined must be retained to afford protection to most
sensitive use of Illinois waters, the protection of riparian mammals. The parties, excluding the
Agency, also generally agree that the DOE technical standard provides the necessary guidance to
establish a water quality standard for combined radium applicable to general use waters and the
Lake Michigan basin. CARE and the Fox River Reclamation District both oppose the 3.75
pCi/L combined radium standard that the Board adopted for second first-notice, CARE finding
the standard too “weak,” and Fox River Reclamation District supporting no general use standard
at all.
The Board disagrees with Joliet’s comment that the USEPA in “their June 10, 2005 letter
to the Hearing Officer makes it clear that the proposed rule will not be approved by the USEPA.”
PC 46. In fact, the USEPA, in an
informal
review of the rule, stated it “does not anticipate
disapproval of the General Use standard of 3.75 pCi/L.” PC 41. After considering all of the

 
11
comments, the Board retains the 3.75 pCi/L combined radium limit as a general use water quality
standard for second-notice.
The Board does not agree that treatment residuals should be addressed in this rulemaking.
This rule only amends Part 302 of the Board’s water quality rules and cannot open a new part at
this late date in the proceeding.
Consideration of Economic Factors
Several of the public comments stated that economic factors should not be taken into
account in setting the numeric standards that are protective of designated uses.
See e.g
. PC 44 at
2; PC 48 at 8. However, the Board is required by statute to consider economic impacts of each
rulemaking it considers.
Under Section 13 of the Act, the Board is granted rulemaking authority to establish water
quality standards. 415 ILCS 5/13(a)(1) (2004);
see
Granite City Steel Co.,
et al
v. PCB, 155 Ill.
2d 149, 613 N.E.2d 719 (1993). In promulgating those regulations, the Board is governed by
Section 27 of the Act. 415 ILCS 5/27 (2004). For example, Section 27(a) provides “the Board
shall take into account the . . . technical feasibility and economic reasonableness of measuring or
reducing the particular type of pollution.”
Id
. Section 27(b)(1) requires the Department of
Commerce and Community Affairs (now the Department of Commerce and Economic
Opportunity) to conduct a study of the economic impact of the proposed rules, and subpart (b)(2)
of that section requires the Board to “conduct at least one hearing on the economic impact of
those new rules.” 415 ILCS 5/27(b)(1), (2) (2004). Finally, the Board must “in its written
opinion, make a determination, based upon the evidence in the public hearing record, including
but not limited to the economic impact study, as to whether the proposed rule has any adverse
economic impact on the people of the State of Illinois.” 415 ILCS 5/27(b)(2) (2004).
Economic impact relates to the impact on the community.
See
Citizens’ Utilities Co. v.
PCB, 152 Ill. App. 3d 122, 504 N.E.2d 224 (1987). Therefore, as required by statute, the Board
properly considered the potential economic impacts the proposed rule would have on POTWs, as
well as the economic impact when costs of compliance for POTWs are filtered down to citizens
in the form of increased rates.
Further, support for a general use water quality limit of 30 pCi/L, that the Board
proposed in Section 302.207(d), was not based solely on economic factors. In fact, as stated in
the Board’s April 7, 2005 opinion and order, “this limit is based on IEMA’s recommendation of
using the NRC limit and Joliet’s suggestion of applying a factor of safety of 2.” The Illinois
Emergency Management Agency (IEMA) adopted the U.S. Nuclear Regulatory Commission’s
effluent concentration limit for radium; a standard that relates directly to radiation dose for
humans. 32 Ill. Adm. Code 340, Appendix B, Table 2. The effluent concentration limit for
radium in water is 60 pCi/L combined radium, which if ingested continuously over the course of
a year, would produce a total effective dose equivalent of 50 millirem. PC 24. At IEMA’s
suggestion, the Board applied a factor of safety of two to arrive at the 30 pCi/L combined radium
water quality limit. Nonetheless, the Board explicitly invited comments from the participants on
this provision, which the Board analyzes in the following paragraphs.

 
12
Radium General Use Water Quality Standard Expressed as a Long-Term Average
As discussed at the 2005 first notice, the 3.75 pCi/L limit is based on the DOE technical
standard that meets the biota dose limit of 0.1 rad/d for riparian animals. Based on the evidence
in the record, the Board finds this general use standard will be protective of human health and
the environment, including aquatic life and riparian mammals, and ensure that high levels of
radium cannot be discharged into Illinois waterways.
In today’s proposal, the Board expresses that limit as an average measured over the
length of a year. Therefore, while the concentration of radium 226 and 228 combined may be
higher than 3.75 pCi/L at times due to environmental conditions, the water body will still meet
the standard as long as the concentration averaged over the period of a year remains at or below
3.75 pCi/L. Determining compliance in this way will provide relief to POTWs while more
precisely tailoring the standard to meet the Board’s goal of protecting riparian mammals.
The DOE technical document supports considering temporal variability of contamination
in the environment when evaluating doses to biota. Exh. 15, M2-27. The DOE document
explains that radionuclide concentrations in surface water, compared to concentrations in
sediments or surface soil, can change relatively rapidly. Exh. 15, M2-28. Further, site-specific
conditions such as storm water flows or seasonal occurrences like high flow conditions may
produce wide variations of exposure to receptors.
Id
.
The DOE document provides reasons why it is appropriate to use time averaging in
applying the daily dose limits for biota. Exh. 15, M2-28. First, daily dose limits are intended to
protect whole populations of a species, rather than individuals, where a primary concern is the
effect of contaminants on reproductive capability over the normal reproductive lifetime.
Id
.
Second, the studies used as bases for the daily dose limits were obtained primarily from studies
involving chronic exposure, where the average dose rate in the population varied substantially,
over exposure times ranging from several months to several years.
Id
.
Third, single acute doses, even doses 10-30 times higher than the daily dose limit,
appeared tolerable, based on studies involving short-term exposures, so long as the recovery time
between doses was sufficiently long (30-60 days), and the daily dose rate was limited in
accordance with the standards. Exh. 15, M2-29. Fourth, the average doses were the primary
bases for the DOE document’s conclusions regarding early mortality and the impairment of
reproductive capability.
Id
. According to the DOE document, the dose limits were not intended
as limits on each day of exposure, but rather, as limits on the average dose rates encountered
from conception through reproductive age. For these reasons, the DOE document suggests that
“averaging times as long as one year may be appropriate for reproducing members of
populations of the most radiosensitive organisms.” Exh. 15, M2-29. Fifth, radioecological
studies
7
demonstrate that radiation effects are observed at the population and community level
only for annual doses greater than about 400 rad or 1 rad/day.
Id
.
7
The DOE document provides that these were studies done at highly contaminated sites in the
former Soviet Union (Polikarpov 1994). Exh. 15, M2-29.

 
13
Therefore, based on the record, the Board also finds the long-term averaging approach
appropriate given the nature of radium as well as the bases used for establishing the method for
determining the daily dose limit. Radium does affect wildlife through simple exposure, yet the
primary concern regarding exposure is the chronic effects of radium that result from
bioconcentration and bioaccumulation such as cancer and reproductive and developmental
effects. Thus, the Board finds that a combined radium standard, expressed as a limit on the
annual average of daily dose rates encountered from conception through reproductive age, will
adequately protect the most sensitive designated use of Illinois water bodies. The 3.75 pCi/L
combined radium standard does not include any contributions of radium from sediment because
the record does not contain any data supporting or refuting the contribution of radium from
stream sediments in Illinois waters.
Additionally, the new data submitted by Joliet regarding Northern Illinois POTWs
indicates that expressing the general use water quality limit as a long-term average will provide
relief for a majority of the affected POTWs. According to Joliet, the use of the annual average
would reduce the number of plants with potential violations to between two and six. PC 46 at 3.
Today’s proposal does not incorporate the Agency’s suggestion of allowing for mixing
even if the stream has a zero 7Q10 flow. The Agency does not support this portion of its
proposal with evidence contained in the record, stating only that allowing mixing zones in
dischargers’ permits would provide relief for POTWs. The Board finds that the proposed water
quality standard expressed as an annual average provides relief for the majority of POTWs,
while also protecting the most sensitive use of general use waters. Any dischargers that cannot
comply may seek an adjusted standard or other relief from the Board upon making the proper
showing.
In today’s proposal, the Board eliminates the 30 pCi/L water quality standard applicable
up to one-mile downstream of POTW discharges. Simultaneously, the Board expresses the 3.75
pCi/L standard as an annual average concentration of combined radium rather than as an
instantaneous standard.
Public and Food Processing Water Supply Standard
As suggested by the USEPA and the Agency, today the Board also adopts a Public and
Food Processing Water Supply standard of 5 pCi/L combined radium 226 and 228 to ensure that
public water supplies meet the Federal drinking water maximum contaminant level for radium.
Since the proposed general use standard is based on a long-term average concentration, an
instantaneous surface water intake standard will ensure protection from upstream discharges that
could cause a Public and Food Processing Water Supply to exceed 5 pCi/L.
CONCLUSION
To protect all designated uses of Illinois waters, the Board retains the 3.75 pCi/L
combined radium 226 and 228 standard applicable to general use waters and the Lake Michigan
Basin proposed in 2005. Today’s proposal, however, diverges from the Board’s 2005 proposal

 
14
in that compliance with the standard is determined by the annual average of combined radium
concentrations. The proposal applies a 5.0 pCi/L standard to Public and Food Processing Water
Supply intakes as an instantaneous standard. The Board finds the proposal adopted today
economically reasonable and technically feasible.
The Board adopts this proposal for second-notice review by JCAR. The 45-day second-
notice period will begin on the date written notice is received by JCAR and the Board will accept
comments only from JCAR during the second-notice period.
See
35 Ill. Adm. Code 102.606.
ORDER
The Board proposes for second-notice review by JCAR the following amendments to 35
Ill. Adm. Code 302. Proposed deletions to the current rules are stricken, and proposed additions
are underlined.
TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE C: WATER POLLUTION
CHAPTER I: POLLUTION CONTROL BOARD
PART 302
WATER QUALITY STANDARDS
SUBPART A: GENERAL WATER QUALITY PROVISIONS
Section
302.100
Definitions
302.101
Scope and Applicability
302.102
Allowed Mixing, Mixing Zones and ZIDs
302.103
Stream Flows
302.104
Main River Temperatures
302.105
Antidegradation
SUBPART B: GENERAL USE WATER QUALITY STANDARDS
Section
302.201
Scope and Applicability
302.202
Purpose
302.203
Offensive Conditions
302.204
pH
302.205
Phosphorus
302.206
Dissolved Oxygen
302.207
Radioactivity
302.208
Numeric Standards for Chemical Constituents
302.209
Fecal Coliform
302.210
Other Toxic Substances
302.211
Temperature

15
302.212
Total Ammonia Nitrogen
302.213
Effluent Modified Waters (Ammonia)(Repealed)
SUBPART C: PUBLIC AND FOOD PROCESSING WATER SUPPLY STANDARDS
Section
302.301
Scope and Applicability
302.302
Algicide Permits
302.303
Finished Water Standards
302.304
Chemical Constituents
302.305
Other Contaminants
302.306
Fecal Coliform
302.207
Radium 226 and 228
SUBPART D: SECONDARY CONTACT AND INDIGENOUS AQUATIC LIFE
STANDARDS
Section
302.401
Scope and Applicability
302.402
Purpose
302.403
Unnatural Sludge
302.404
pH
302.405
Dissolved Oxygen
302.406
Fecal Coliform (Repealed)
302.407
Chemical Constituents
302.408
Temperature
302.409
Cyanide
302.410
Substances Toxic to Aquatic Life
SUBPART E: LAKE MICHIGAN BASIN WATER QUALITY STANDARDS
Section
302.501
Scope, Applicability, and Definitions
302.502
Dissolved Oxygen
302.503
pH
302.504
Chemical Constituents
302.505
Fecal Coliform
302.506
Temperature
302.507
Thermal Standards for Existing Sources on January 1, 1971
302.508
Thermal Standards for Sources Under Construction But Not In Operation on
January 1, 1971
302.509
Other Sources
302.510
Incorporations by Reference
302.515
Offensive Conditions
302.520
Regulation and Designation of Bioaccumulative Chemicals of Concern (BCCs)

16
302.521
Supplemental Antidegradation Provisions for Bioaccumulative Chemicals of
Concern (BCCs)
302.525
Radioactivity
302.530
Supplemental Mixing Provisions for Bioaccumulative Chemicals of Concern
(BCCs)
302.535
Ammonia Nitrogen
302.540
Other Toxic Substances
302.545
Data Requirements
302.550
Analytical Testing
302.553
Determining the Lake Michigan Aquatic Toxicity Criteria or Values - General
Procedures
302.555
Determining the Tier I Lake Michigan Acute Aquatic Toxicity Criterion
(LMAATC): Independent of Water Chemistry
302.560
Determining the Tier I Lake Michigan Basin Acute Aquatic Life Toxicity
Criterion (LMAATC): Dependent on Water Chemistry
302.563
Determining the Tier II Lake Michigan Basin Acute Aquatic Life Toxicity Value
(LMAATV)
302.565
Determining the Lake Michigan Basin Chronic Aquatic Life Toxicity Criterion
(LMCATC) or the Lake Michigan Basin Chronic Aquatic Life Toxicity Value
(LMCATV)
302.570
Procedures for Deriving Bioaccumulation Factors for the Lake Michigan Basin
302.575
Procedures for Deriving Tier I Water Quality Criteria and Values in the Lake
Michigan Basin to Protect Wildlife
302.580
Procedures for Deriving Water Quality Criteria and Values in the Lake Michigan
Basin to Protect Human Health – General
302.585
Procedures for Determining the Lake Michigan Basin Human Health Threshold
Criterion (LMHHTC) and the Lake Michigan Basin Human Health Threshold
Value (LMHHTV)
302.590
Procedures for Determining the Lake Michigan Basin Human Health
Nonthreshold Criterion (LMHHNC) or the Lake Michigan Basin Human Health
Nonthreshold Value (LMHHNV)
302.595
Listing of Bioaccumulative Chemicals of Concern, Derived Criteria and Values
SUBPART F: PROCEDURES FOR DETERMINING WATER QUALITY CRITERIA
Section
302.601
Scope and Applicability
302.603
Definitions
302.604
Mathematical Abbreviations
302.606
Data Requirements
302.612
Determining the Acute Aquatic Toxicity Criterion for an Individual Substance –
General Procedures
302.615
Determining the Acute Aquatic Toxicity Criterion - Toxicity Independent of
Water Chemistry
302.618
Determining the Acute Aquatic Toxicity Criterion - Toxicity Dependent on Water
Chemistry

17
302.621
Determining the Acute Aquatic Toxicity Criterion - Procedure for Combinations
of Substances
302.627
Determining the Chronic Aquatic Toxicity Criterion for an Individual Substance -
General Procedures
302.630
Determining the Chronic Aquatic Toxicity Criterion - Procedure for
Combinations of Substances
302.633
The Wild and Domestic Animal Protection Criterion
302.642
The Human Threshold Criterion
302.645
Determining the Acceptable Daily Intake
302.648
Determining the Human Threshold Criterion
302.651
The Human Nonthreshold Criterion
302.654
Determining the Risk Associated Intake
302.657
Determining the Human Nonthreshold Criterion
302.658
Stream Flow for Application of Human Nonthreshold Criterion
302.660
Bioconcentration Factor
302.663
Determination of Bioconcentration Factor
302.666
Utilizing the Bioconcentration Factor
302.669
Listing of Derived Criteria
APPENDIX A
References to Previous Rules
APPENDIX B
Sources of Codified Sections
APPENDIX C
Maximum total ammonia nitrogen concentrations allowable for certain
combinations of pH and temperature
TABLE A
pH-Dependent Values of the AS (Acute Standard)
TABLE B
Temperature and pH-Dependent Values of the CS (Chronic Standard) for
Fish Early Life Stages Absent
TABLE C
Temperature and pH-Dependent Values of the CS (Chronic Standard) for
Fish Early Life Stages Present
AUTHORITY: Implementing Section 13 and authorized by Sections 11(b) and 27 of the
Environmental Protection Act [415 ILCS 5/13, 11(b), and 27]
SOURCE: Filed with the Secretary of State January 1, 1978; amended at 2 Ill. Reg. 44, p. 151,
effective November 2, 1978; amended at 3 Ill. Reg. 20, p. 95, effective May 17, 1979; amended
at 3 Ill. Reg. 25, p. 190, effective June 21, 1979; codified at 6 Ill. Reg. 7818; amended at 6 Ill.
Reg. 11161, effective September 7, 1982; amended at 6 Ill. Reg. 13750, effective October 26,
1982; amended at 8 Ill. Reg. 1629, effective January 18, 1984; peremptory amendments at 10 Ill.
Reg. 461, effective December 23, 1985; amended at R87-27 at 12 Ill. Reg. 9911, effective May
27, 1988; amended at R85-29 at 12 Ill. Reg. 12082, effective July 11, 1988; amended in R88-1 at
13 Ill. Reg. 5998, effective April 18, 1989; amended in R88-21(A) at 14 Ill. Reg. 2899, effective
February 13, 1990; amended in R88-21(B) at 14 Ill. Reg. 11974, effective July 9, 1990; amended
in R94-1(A) at 20 Ill. Reg. 7682, effective May 24, 1996; amended in R94-1(B) at 21 Ill. Reg.
370, effective December 23, 1996; expedited correction at 21 Ill. Reg. 6273, effective December
23, 1996; amended in R97-25 at 22 Ill. Reg. 1356, effective December 24, 1997; amended in
R99-8 at 23 Ill. Reg. 11249, effective August 26, 1999; amended in R01-13 at 26 Ill. Reg. 3505,
effective February 22, 2002; amended in R02-19 at 26 Ill. Reg. 16931, effective November 8,

18
2002; amended in R02-11 at 27 Ill. Reg. 166, effective December 20, 2002; amended in R_____
at _____ Ill. Reg. _____, effective ____________________.
SUBPART B: GENERAL USE WATER QUALITY STANDARDS
Section 302.207
Radioactivity
a)
Gross beta (STORET number 03501) concentration shall not exceed 100
picocuries per liter (pCi/L).
b)
Concentrations of radium 226 (STORET number 09501) and sStrontium 90
(STORET number 13501) concentration
must not exceed 1 and 2 picocuries per
liter (pCi/L)respectively
.
c)
The annual average radium 226 and 228 (STORET number 11503) combined
concentration must not exceed 3.75 picocuries per liter (pCi/L).
(Source: Amended at _____ Ill. Reg. __________, effective __________)
SUBPART C: PUBLIC AND FOOD PROCESSING WATER SUPPLY STANDARDS
Section 302.307
Radium 226 and 228
Radium 226 and 228 (STORET number 11503) combined concentration must not exceed 5
picocuries per liter (pCi/L) at any time.
(Source: Amended at _____ Ill. Reg. __________, effective __________)
SUBPART E: LAKE MICHIGAN BASIN WATER QUALITY STANDARDS
Section 302.525
Radioactivity
Except as provided in Section 302.102, all waters of the Lake Michigan Basin must meet the
following concentrations
in any sample:
a)
Gross beta (STORET number 03501) concentrations must not exceed 100
picocuries per liter (pCi/L).
b)
Concentrations of radium 226 (STORET number 09501) and sStrontium 90
(STORET number 13501) concentration
shall not exceed 1 and 2 picocuries per
liter (pCi/L)respectively
.
c)
The annual average radium 226 and 228 (STORET number 11503) combined
concentration must not exceed 3.75 picocuries per liter (pCi/L).
(Source: Amended at _____ Ill. Reg. __________, effective __________)

19
IT IS SO ORDERED.
I, Dorothy M. Gunn, Clerk of the Illinois Pollution Control Board, certify that the Board
adopted the above opinion and order on December 15, 2005, by a vote of 4-0.
Dorothy M. Gunn, Clerk
Illinois Pollution Control Board

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