1. Ut ~0-0!~ 13
  2. OI~0-0i~.15
  3. 01140-0533
  4. 01140-0535

ILLINOIS POLLUTION CONTROL BOARD
March 25, 1993
IN THE MATTER OF:
)
OMNIBUS CLEANUP OF THE VOLATILE
ORGANIC MATERIAL RACT RULES
)
R93-9
APPLICABLE TO OZONE NONATTAINNENT
)
(Rule Making)
AREAS: AMENDMENTS TO 35 ILL. ADM.
)
CODE PARTS 203, 211, 218 AND 219.
)
PROPOSED RULE.
FIRST NOTICE.
OPINION AND ORDER OF THE BOARD (by B. Forcade):
On March 16, 1993, the Illinois Environmental Protection
Agency (Agency) filed this proposal for rule making. The
proposal represents one part of Illinois’ submittal of a complete
state implementation plan (SIP). Pursuant to Section 182(a) of
the Clean Air Act, as amended in 1990, Illinois was to adopt and
submit its plan by November 15, 1992.
This proposal was filed pursuant to Section 28.5 of the
Environmental Protection Act (Act). (415 ILCS 5/28.5 (1992).)~
Pursuant to the provisions of that section the Board is required
to proceed within the set timefrarries toward the adoption of the
regulation. The Board has no discretion to adjust these time
frames under any circumstances. Today the Board acts to send
this proposal to first notice under the Illinois Administrative
Procedure Act without commenting on the merits of the proposal.
The following schedule indicates the deadlines by which the Board
must act as provided in Section 28.5.
First Notice
on or before March 30, 1993
First Hearing
on or before May 10, 1993
Second Hearing
on or before June 9, 1993
Third Hearing
on or before June 23, 1993
Second Notice
(if third hearing cancelled) on or before July 23, 1993
(if third hearing held)
on or before August 3, 1993
Final Adoption or Filing
21 days after receipt of JCAR
certification of no objection
The Board notes that the above dates are the deadlines as
established by Section 28.5 and do not represent actual hearing
dates or filing dates. While the schedule includes a second and
third hearing, these hearings may be cancelled if unnecessary.
The Board will proceed in this matter as prescribed in Section
28.5 and discussed in the Board’s resolution. (See RES 92-2
1 The Act was previously codified at Ill. Rev. Stat. 1991,
ch. 111 1/2 par. 1001
~j. ~.
Section 28.5 was adopted by P.A.
87—1213 which became effective on September 26, 1992.
0 L1O-014.09

2
(October 29, 1992 and December 3, 1992).)
The Agency has filed a “Motion for Waiver of Requirements”
with the proposal. The Agency requests waiver of the following
requirements: that the Agency submit the original and nine copies
of the original and nine copies of the entire regulatory
proposal, that the Agency submit an entire copy of the proposal
to the Attorney General and the Department of Energy and Natural
Resources (DENR), that copies of the incorporations by reference
be included with the proposal and that the Agency submit copies
of all documents on which it relied. The Agency requests that it
be permitted to file an original plus five complete copies of the
proposal and four partial copies. A partial copy does not
include the supporting exhibits. The Attorney General and DENR
have agreed with the Agency that a complete copy of the proposal
need not be served on them. The Agency notes that the
incorporations by reference were provided in previous rule
makings and therefore are already in the Board’s possession. The
Agency has provided the Board with one copy of some of the
documents on which it relied and notes that the other documents
are readily accessible or already in the Board’s possession. The
Board grants the Agency’s motion.
The Board notes that we have made some changes to the
proposal as submitted by the Agency to comport with filing and
other requirements of the Administration Code Unit of the
Secretary of State’s Office. The following changes were made to
the proposed regulations:
“Printed on Recycled Paper” on the first page was deleted;
the table of contents of Section 218 was repaginated to
remove hanging headings;
In Section 218 where Appendix was changed to APPENDIX the
strikeout was removed from the A;
In Subpart Q of Section 219 “Plant” was capitalized.
The following changes were made to the “Notice of
Proposed Rules”:
The heading was corrected to read Pollution Control Board;
“Printed on Recycled Paper” was deleted;
Citations to Ill. Rev. Stat. were updated to 1991;
III. was changed to Ill.;
Hearings were noted under question 11;
Unnecessary information was removed from questions 7 and 9;
0 L~O-0i~I a

3
Section numbers were combined on the same line where
possible;
Answers to question 12 were amended;
Illinois Register Issues were added for Section 203.
In the interest of administrative economy, the Board directs
the hearing officer to verify that persons on the notice list in
this proceeding wish to continue to receive mailings in this
proceeding.
ORDER
The Board directs the Clerk to cause the filing of the
following proposal for First Notice in the Illinois Register:
Section
203.101
203.103
203.104
203.107
203. 110
203.112
203.113
203.116
203.117
203.119
203.121
203.122
203. 123
203.124
203.125
203.126
203.127
203.128
203.131
203.134
203.136
203.145
TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE B: AIR POLLUTION
CHAPTER I: POLLUTION CONTROL BOARD
SUBCHAPTER a: PERMITS AND GENERAL PROVISIONS
PART 203
MAJOR STATIONARY SOURCES CONSTRUCTION AND MODIFICATION
SUBPART A: GENERAL PROVISIONS
0IL~0-Øi~,
1
1
Definitions
Actual Construction
Actual Emissions
Allowable Emissions
Available Growth Margin
Building, Structure and Facility
Commence
Construction
Dispersion Enhancement Techniques
Emission Baseline
Emission Offset
Emissions Unit
Federally Enforceable
Fugitive Emissions
Installation
Lowest Achievable Emission Rate
Nonattainment Area
Potential to Emit
Reasonable Further Progress
Secondary Emissions
Stationary Source
Volatile Organic Material (Repealed)

4
203.150
203.155
Public Participation
Severability (Repealed)
SUBPART B: MAJOR STATIONARY SOURCES IN NONATTAINMENT AREAS
Section
203.201
203.202
203.203
203 .204
203.205
203 .206
203.207
203.208
203.209
203.210
203.211
Prohibition
Coordination with Permit Requirement and Application
Pursuant to 35 Ill. Adm. Code 201
Construction Permit Requirement and Application
Duration of Construction Permit (Repealed)
Effect of Permits
Major Stationary Source
Major Modification of a Source
Net Emission Determination
Significant Emissions Determination
Relaxation of a Source-Specific Limitation
Permit Exemption Based on Fugitive Emissions
SUBPART C: REQUIREMENTS FOR MAJOR STATIONARY SOURCES IN
NONATTAINMENT AREAS
203.301
203.302
203.303
203.304
203.305
203.306
Lowest Achievable Emission Rate
Maintenance of Reasonable Further Progress and Emission
Offsets
Baseline and Emission Offsets Determination
Exceptions from Emissions Offset Requirement (Repealed)
Compliance by Existing Sources
Analysis of Alternatives
SUBPART F: OPERATION OF A MAJOR STATIONARY SOURCE OR MAJOR
MODIFICATION
Section
203.601
203.602
203.603
Lowest Achievable Emission Rate Compliance Requirement
Emission Offset Maintenance Requirement
Ambient Monitoring Requirement (Repealed)
SUBPART G: GENERAL MAINTENANCE OF EMISSION OFFSETS
Sect ion
203.701
General Maintenance of Emission Offsets
SUBPART H: OFFSETS FOR EMISSION INCREASES FROM ROCKET ENGINES
AND MOTOR FIRING
Section
203.801
Offsets for Emission Increases from Rocket Engines and
Motor Firing
AUTHORITY: Implementing Section 9.1 and 10 and authorized by

5
Section 27 and 28.5 of the Environmental Protection Act (Ill.
Rev. Stat. 1991, ch. 1ll~, pars. 1009.1, 1010 and 1027) (P.A. 87—
1213, effective September 26, 1992) 415 ILCS 5/9.1, 10, 27, and
28.5.
SOURCE: Adopted and codified at 7 Ill. Reg. 9344, effective July
22, 1983; codified at 7 Ill. Reg. 13588; amended in R85—20 at 12
Ill. Reg. 6118, effective March 22, 1988; amended in R91—24 at 16
Ill. Reg. 13551, effective August 24, 1992; amended in R92-21 at
17 Ill. Reg.
,
effective
__________________;
amended in
R93—
______
at 17 Ill. Reg.
_________,
effective
____________
Section 203.145
Volatile Organic Material (Repealed)
excluding carbon monoxide,
‘ -~.—-——,
acid,
metallic carbides or carbonates, and aminonium arbonate, which
participates in atmospheric photochcmical reactions.
1) Cyclic, branched, or linear, completely
fluorinated alkancs;
2)
Cyc1i~
r~
,
h’r.’inrthcd, or linear, completely
f-luorinatcd ethers with no unsaturations,
3) Cyclic, branched,
~
~
4~~.4_4
4) Sulfur containing perfluorocarbons,~~1cte1~with no
s and with su1r~
~
Ut ~0-0!~ 13
following, which have been determined to have
negligible photochemical reactivity: Methane; cthane;
methylenc chloride (dichlormcthane), 1,1,1
trichlorcthanc (methyl chloroform), 1,1,1 trichioro
2.2.2 trifluoroethanc (CFC 113): trichlorofluoromcthane
(CFC 11); dichlorodifl~ ~,cthan.. (CFC 12,
chlorodifluoromethanc (CFC 22); trifluoromcthane (FC
23); 1,2 dichioro 1,1,2,2 tctrafluorocthanc (CFC 114);
cloropentafluoroethanc (CFC 115); 1,1,1 trifluoro 2,2
dichlorocthanc (HCFC 123); 1,1,12 tetrafluoroetha-ne
(HFC 134a); 1,1 dichipro 1 fluorocthane (HCFC l4lb); 1
chloro 1,1 difluoroethane (HCFC 142b); 2 chioro 1,1,1,2
tetrafluoroethane (HCFC 124); pentafluoroethanc (HFC
125); 1,1,2,2 tetrafluoroethane (HFC 134); 1,1,1
trifluoroethanc (HFC 143a); 1,1 difluroethane (HFC
152a); and perfluorocarbon compounds which fall int-o
~-hc’~
1-~i-~.-~~’-
and fluroinc.

6
b) For purposes of determining VON emissions and
compliance with emissions limits, VOM will be measured
by the test methods in the approved implementation plan
or 40 CFR Part 60, Appendix A, incorporated by
reference at Sections 215.105, 218.112, and 219.112, as
applicable or by source specific test methods which
have been established pursuant to a permit issued
pursuant to a program approved or promulgated under
Title V of the Clean Air Act or under 40 CFfl Part 51,
Subpart I or Appendix 8, incorporated by refer-enee at
Sections 218.112 and 219.112 or under 40 CFR Part
52.21, incorporated by reference at Sections 218.112
and 219.112, as applicable. Where such a method also
measures compounds with negligible photochemical
reactivity, these negligibly reactive compounds may be
excluded as VON if the amount of such compounds is
accurately quantified, and such exclusions is approved
c) As a precondition to excluding these negligibly
reactive compounds as VON or at any time thereafter,
the Agency may require an owner or operator to provide
monitoring or testing methods and results
demonstrating, to the satisfaction of the Agency, the
amount of negligibly reactive compounds in the
sources’ s emissions.
d) The USEPA shall not be L
~
as to appropriate methods for testing or monitoring
negligibly reactive compounds if such determination is
not reflected in any of the provisions of paragraph
(2)
(Source: Repealed at
_____
Ill. Reg.
,
effective
________
O114Q_O14tL4~

7
TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE B: AIR POLLUTION
CHAPTER I: POLLUTION CONTROL BOARD
SUBCHAPTER c: EMISSION STANDARDS AND LIMITATIONS
FOR STATIONARY SOURCES
PART 211
DEFINITIONS AND GENERAL PROVISIONS
SUBPART A: GENERAL PROVISIONS
Incorporations by Reference
Abbreviations and Units
Other Definitions
Definitions (Repealed)
Accelacota
Accumulator
Acid Gases
Actual Heat Input
Adhesive
Aeration
Afterburner
Air Contaminant
Air Dried Coatings
Air Oxidation Process
Air Pollutant
Air Pollution
Air Pollution Control Equipment
Air Suspension Coater/Dryer
Airless Spray
Air Assisted Airless Spray
Annual Grain Through-Put
Application Area
Architectural Coating
As Applied
Asphalt
Asphalt Prime Coat
Automobile
Automobile or Light-Duty Truck Assembly Source or
Automobile or Light-Duty Truck Manufacturing Plant
Automobile or Light—Duty Truck Refinishing
Baked Coatings
Batch Loading
Bead-Dipping
Binders
British Thermal Unit
Brush or Wipe Coating
SUBPART B: DEFINITIONS
Section
211. 101
211. 102
Section
211. 121
211. 122
211. 130
211. 150
211. 170
211.210
211.230
211.250
211.290
211.310
211.330
211.350
211.370
211.390
211.410
211.430
211.450
211.470
211.490
211.510
211.530
211.550
211.570
211.590
211.610
211.630
211.650
211.670
211. 690
211.710
211.730
211.750
211.770

Back to top


OI~0-0i~.15

8
211.790
211.810
211.830
211.850
211.870
211.890
211.910
211.930
211.950
211.970
211.990
211. 1010
211. 1050
211. 1090
211. 1110
211. 1130
211. 1150
211. 1170
211. 1190
211. 1210
211. 1230
211. 1250
211. 1270
211. 1290
211. 1310
211. 1330
211. 1350
211. 1370
211. 1390
211. 1410
211. 1430
211. 1470
211. 1490
211. 1510
211. 1530
211.1550
211. 1570
211. 1590
211. 1610
211. 1630
211. 1650
211. 1670
211. 1690
211. 1710
211.1730
211. 1750
211. 1770
211. 1790
211. 1810
211.1830
211.1850
211. 1870
Bulk Gasoline Plant
Bulk Gasoline Terminal
Can
Can Coating
Can Coating Line
Capture
Capture Device
Capture Efficiency
Capture System
Certified Investigation
Choke Loading
Clean Air Act
Cleaning and Separating Operation
Clear Coating
Clear Topcoat
Closed Purge System
Closed Vent System
Coal Refuse
Coating
Coating Applicator
Coating Line
Coating Plant
Coil Coatiflg
Coil Coating Line
Cold Cleaning
Complete Combustion
Component
Concrete Curing Compounds
Concentrated Nitric Acid Manufacturing Process
Condensate
Condensible PM-b
Continuous Process
Control Device
Control Device Efficiency
Conventional Soybean Crushing Source
Conveyorized Degreasing
Crude Oil
Crude Oil Gathering
Crushing
Custody Transfer
Cutback Asphalt
Daily-Weighted Average VOM Content
p-~y
Degreaser
Delivery Vessel
Dip Coating
Distillate Fuel Oil
Drum
Dry Cleaning Operation or Dry Cleaning Facility
Dump-Pit Area
Effective Grate Area
Effluent Water Separator
O1L~O-0~I6

9
Enamel
Enclose
End Sealing Compound Coat
Ethanol Blend Gasoline
Excess Air
Excessive Release
Existing Grain-Drying Operation
Existing Grain-Handling Operation
Exterior Base Coat
Exterior End Coat
External Floating Roof
Extreme Performance Coating
Fabric Coating
Fabric Coating Line
Federally Enforceable Limitations and Conditions
Final Repair Coat
F irebox
Fixed-Roof Tank
Flexographic Printing
Flexographic Printing Line
Floating Roof
Fountain Solution
Freeboard Height
Fuel Combustion Emission Unit or Fuel Combustion
Emission Source
Fugitive Particulate Matter
Full Operating Flowrate
Gas Service
Gas/Gas Method
Gasoline
Gasoline Dispensing Operation or Gasoline Dispensing
Facility
Grain
Grain-Drying Operation
Grain—Handling and Conditioning Operation
Grain-Handling Operation
Green-Tire Spraying
Green Tires
Gross Heating Value
Gross Vehicle Weight Rating
Heated Airless Spray
Heatset
Heatset-Web-Off set Lithographic Printing Line
Heavy Liquid
Heavy Metals
Heavy Off-Highway Vehicle Products
Heavy Off-Highway Vehicle Products Coating
Heavy Off-Highway Vehicle Products Coating Line
Electrostatic Bell or Disc Spray
Electrostatic Spray
Emission Rate
Emission Unit
211. 1890
211. 1910
211. 1930
211. 1950
211. 1970
211. 1990
211. 2010
211.2050
211.2070
211. 2090
211.2110
211.2130
211.2150
211.2170
211. 2190
211. 2210
211.2230
211.2250
211.2270
211.2310
211.2330
211.2350
211.2370
211.2390
211.2410
211.2430
211.2450
211.2470
211.2490
211.2510
211.2530
211.2550
211.2570
211.2590
211.2650
211.2670
211.2690
211.2710
211.2730
211.2750
211.2770
211.2790
211.2810
211.2830
211.2850
211.2870
211.2890
211. 2910
211.2930
211.2950
01 L~O-Qi~
17

10
211.2970
211.2990
211.3010
211.3030
211. 3050
211.3070
211.3090
211.3110
211.3130
211.
3150
211.3170
211.3190
211.32 10
211.3230
211.3250
211.3270
211.
3290
211. 3310
211.3330
211.3350
211.3370
211.3390
211. 3410
211.3430
211.3450
211.3470
211.3490
211. 3510
211.3530
211.3550
211.3570
211.3590
211. 3610
211.3630
211.3650
211.3670
211.3690
211.3710
211.3730
211.3750
211.3770
211.3790
211. 3H0
211. 383~0
211.3850
211.3870
211.3890
211.3910
211.3930
211.3970
211.3990
211. 4010
High Temperature Aluminum Coating
High Volume Low Pressure (HVLP) Spray
Hood
Hot Well
Housekeeping Practices
In—Process Tank
In-Situ Sampling Systems
Incinerator
Indirect Heat Transfer
Ink
Interior Body Spray Coat
Internal—Floating Roof
Internal Transferring Area
Laccrners
Large Appliance
Large Appliance Coating
Large Appliance Coating Line
Light Liquid
Light-Duty Truck
Light Oil
Liquid/Gas Method
Liquid-Mounted Seal
Liquid Service
Liquids Dripping
Lithographic Printing Line
Load-Out Area
Low Solvent Coating
Magnet Wire
Magnet Wire Coating
Magnet Wire Coating Line
Major Dump Pit
Major Metropolitan Area
(MMA)
Major Population Area (MPA)
Manufacturing Process
Marine Terminal
Material Recovery Section
Maximum Theoretical Emissions
Metal Furniture
Metal Furniture Coating
Metal Furniture Coating Line
Metallic Shoe-Type Seal
Miscellaneous Fabricated Product Manufacturing Process
Miscellaneous Formulation Manufacturing Process
Miscellaneous Metal Parts and Products
Miscellaneous Metal Parts and Products Coating
Miscellaneous Metal Parts or Products Coating Line
Miscellaneous Organic Chemical Manufacturing Process
Mixing Operation
Monitor
Multiple Package Coating
New Grain-Drying Operation
New Grain-Handling Operation
0IL~0-0t~18

11
211.4030
211.4050
211.4070
211.4090
211.4110
211.4130
211.4150
211.4170
211.4190
211.4210
211.4230
211.4250
211.4270
211.4290
211.4310
211.4330
211.4350
211.4370
211.4390
211.4410
211.4430
211.4450
211.4470
211.4490
211. 4510
211.4530
211.4550
211.4590
211.4610
211.4630
211.4650
211.4670
211.4690
211.4710
211.4730
211.4750
211.4770
211.4790
211.4810
211.4870
211.4890
211.4910
211.4930
211.4950
211.4990
211.5030
211.5050
211.5070
No Detectable Volatile Organic Material Emissions
Non—contact Process Water Cooling Tower
Offset
One Hundred Percent Acid
One—Turn Storage Space
Opacity
Opaque Stains
Open Top Vapor Degreasing
Open-Ended Valve
Operator of a Gasoline Dispensing Operation or Operator
of a Gasoline Dispensing Facility
Organic Compound
Organic Material and Organic Materials
Organic Vapor
Oven
Overall Control
Overvarn i sh
Owner of a Gasoline Dispensing Operation or Owner of a
Gasoline Dispensing Facility
Owner or Operator
Packaging Rotogravure Printing
Packaging Rotogravure Printing Line
Pai1
Paint Manufacturing Source or Paint Manufacturing Plant
Paper Coating
Paper Coating Line
Particulate Matter
Parts Per Million (Volume) or PPM (Vol)
Person
Petroleum
Petroleum Liquid
Petroleum Refinery
Pharmaceutical
Pharmaceutical Coating Operation
Photochemically Reactive Material
Pigmented Coatings
Plant
Plasticizers
PM-lU
Pneumatic Rubber Tire Manufacture
Polybasic Organic Acid Partial Oxidation Manufacturing
Process
Polystyrene Plant
Polystyrene Resin
Portable Grain-Handling Equipment
Portland Cement Manufacturing Process Emission Source
Portland Cement Process or Portland Cement
Manufacturing Plant
Power Driven Fastener Coating
Pressure Release
Pressure Tank
Prime Coat
01 L~Q-0I~19

12
211.5090
211.5 US~
211.5130
211.5 15Q.
211. 5170
211.5185
211.5190
211.5210
211.5230
211.5250
211.5270
211. 5310
211.5330
211.5350
211.5370
211.5410
211.5430
211.5450
211.5470
211.5490
211.5510
211.5550
211.5570
211.5590
211.5610
211. 5630
211. 5650
211.5670
211.5690
211. 5710
211.5730
211.5750
211.5770
211.5790
211. 5810
211.5830
211. 5850
211.5870
211.5890
211. 5910
211.5930
211.5950
211.5970
211.5990
211.6010
211.6030
211.6050
211.6070
211.6090
211.6130
211. 6i5~
211.6190
Primer Surfacer Coat
Primer Surfacer Operation
Primers
Printing
Printing Line
Process Emission Source
Process Emission Unit
Process Unit
Process Unit Shutdown
Process Weight Rate
Production Equipment Exhaust System
Publication Rotogravure Printing Line
Purged Process Fluid
Reactor
Reasonably Available Control Technology (RACT)
Refiner
Refinery Fuel Gas
Refinery Fuel Gas System
Refinery Unit or Refinery Process Unit
Refrigerated Condenser
Reid Vapor Pressure
Repair Coat
Repaired
Residual Fuel Oil
Restricted Area
Retail Outlet
Ringelmann Chart
Roadway
Roll Coater
Roll Coating
Roll Printer
Roll Printing
Rotogravure Printing
Rotogravure Printing Line
Safety Relief Valve
Sandblast ing
Sanding Sealers
Screening
Sealer
Semi—Transparent Stains
Sensor
Set of Safety Relief Valves
Sheet Basecoat
Shotbiasting
Side—Seam Spray Coat
Smoke
Smokeless Flare
Solvent
Solvent Cleaning
Source
Specialty High Gloss Catalyzed Coating
Specialty Soybean Crushing Source
UI 4Q-0L~2O

13
211.6210
211.6230
211.6270
211.6290
211. 6310
211.6330
211.6350
211.6370
211.6390
211.6410
211.6430
211. 6450
211. 6470
211. 6490
211.6510
211.6530
211. 6550
211.6570
211.6590
211. 6610
211.6670
211. 6690
211.6730
211.6750
211.6770
211.6790
211.6810
211.6850
211. 6870
211.6890
211.6910
211.6930
211.6950
211.6970
211.6990
211.7010
211.7030
211.7070
211.7090
211.7110
211.7130
211.7150
211.7170
211.7190
211.7210
211.7230
211.7250
211.7270
211.7290
211.7310
Splash Loading
Stack
Standard Conditions
Standard Cubic Foot (scf)
Start-Up
Stationary Emission Source
Stationary Emission Unit
Stationary Source
Stationary Storage Tank
Storage Tank or Storage Vessel
Styrene Devolatilizer Unit
Styrene Recovery Unit
Submerged Loading Pipe
Substrate
Sulfuric Acid Mist
Surface Condenser
Synthetic Organic Chemical or Polymer Manufacturing
Plant
Tablet Coating Operation
Thirty-Day Rolling Average
Three-Piece Can
Topcoat
Topcoat Operation
Transfer Efficiency
Tread End Cementing
True Vapor Pressure
Turnaround
Two—Piece Can
Undertread Cementing
Unregulated Safety Relief Valve
Vacuum Producing System
Vacuum Service
Valves Not Externally Regulated
Vapor Balance System
Vapor Collection System
Vapor Control System
Vapor-Mounted Primary Seal
Vapor Recovery System
Vinyl Coating
Vinyl Coating Line
Volatile Organic Liquid (VOL)
Volatile Organic Material Content (VOMC)
Volatile Organic Material (VOM) or Volatile Organic
Compound (VOC)
Volatile Petroleum Liquid
Wash Coat
Wastewater (Oil/Water) Separator
Weak Nitric Acid Manufacturing Process
Web
Wholesale Purchase
-
Consumer
Wood_Furniture
Wood Furniture Coating
Ut ~Q-0~2 I

14
211.7330 Wood Furniture Coating Line
211.7350 Woodworking
Section 211.AppendixPPENDIX A Rule into Section Table
Section 211.AppendixPPENDIX B Section into Rule Table
AUTHORITY: Implementing Sections 9 and 10 and authorized by
Section 27 and 28.5 of the Environmental Protection Act (Ill.
Rev. Stat. 1991, ch. lll~,pars. 1009, 1010 and 1027), (P.A. 87—
1213, effective September 26, 1992) 415 ILCS 5/9, 10, 27 and
28.5.
SOURCE: Adopted as Chapter 2: Air Pollution, Rule 201:
Definitions, P71-23, 4 PCB 191, filed and effective April 14,
1972; amended in R74—2 and R75-5, 32 PCB 295, at 3 Ill. Reg. 5,
p. 777, effective February 3, 1979; amended in R78-3 and 4, 35
PCB 75 and 243, at 3 Ill. Req. 30, p. 124, effective July 28,
1979; amended in P80-5, at 7 Ill. Reg. 1244, effective January
21, 1983; codified at 7 Ill. Peg. 13590; amended in R82--1 (Docket
A) at 10 Ill. Reg. 12624, effective July 7, 1986; amended in
R85—2l(A) at 11 Ill. Peg. 11747, effective June 29, 1987; amended
in R86—34 at 11 Ill. Peg. 12267, effective July 10, 1987; amended
in P86—39 at 11 Ill. Reg. 20804, effective December 14, 1987;
amended in R82-14 and R86-37 at 12 Ill. Req. 787, effective
December 24, 1987; amended in R86—l8 at 12 Ill. Reg. 7284,
effective April 8, 1988; amended in P86—10 at 12 Ill Reg. 7621,
effective April 11, 1988; amended in R88—23 at 13 Ill. Peg.
10862, effective June 27, 1989; amended in P89-8 at 13 Ill. Req.
17457, effective January 1, 1990; amended in R89-16(A) at 14 Ill.
Peg. 9141, effective May 23, 1990; amended in R88—30(B) at 15
Ill. Reg. 5223, effective March 28, 1991; amended in P88—14 at 15
Ill. Peg. 7901, effective May 14, 1991; amended in R91—10 at 15
Ill. Peg. 15564, effective October 11, 1991; amended in P91-6 at
15 Ill. Req. 15673, effective October 14, 1991; amended in P91-22
at 16 Ill. Peg. 7656, effective May 1, 1992; amended in R9l-24 at
16 Ill. Peg. 13526, effective August 24, 1992; amended in P93-
at 17 Ill. Peg.
______,
effective
___________
Section 211.102
Abbreviations and Units
a) Abbreviations used in this Part include the following:
ASTM
American Society for Testing and
Materials
barrels (42 gallons)
btu
British thermal units (60°F)
°C
degrees Celsius or centigrade
cm
centimeters
cu in
cubic inches
degrees Fahrenheit
Ut ~O-0~22

15
FIP
Federal Implementation Plan
ft
feet
ft2
square feet
g
grams
gp~
gallons per minute
g/mole
grams per mole
gallons
hr
hours
in
inch
01
degrees Kelvin
kcal
kilocalories
kg
kilograms
kglhr
kilograms per hour
kPa
kilopascals; one thousand newtons per
square meter
liters
1/sec
liters per second
pounds
lbs/hr
pounds per hour
lbs/gal
pounds per gallon
LEL
lower explosive limit
m
meters
m2
square meters
cubic meters
milligrams
Megacirains, metric tons or tonnes
milliliters
mm
minutes
mega~ioules
mmHg
millimeters of mercury
natural draft opening
ppm (vol)
parts per million
ppmv
parts per million by volume
psi
pounds per square inch
psia
pounds per square inch absolute
psig
pounds per square inch gauge
PACT
reasonably available control technology
scf
standard cubic feet
scm
standard cubic meters
seconds
SIP
State Implementation Plan
TTE
temporary total enclosure
sq cm
square centimeters
sq in
square inches
T
short ton (2,000 lbs)
ton
short ton (2.000 lbs)
USEPA
United States Environmental Protection
Agency
volatile organic compounds
VOL
volatile organic liquids
volatile organic materials
01 1~Q-0t423

16
b) The following conversion factors are used in this Part.
English
Metric
1 gal
3.785 1
1,0001
psiagal
3,7856.897
kPa1
or
(51.713.785 mmHg)Tn3
2.205 lbs
1 kg
32°
0°C (273.15° K)
1 bbl
159.0 1
1 Cu in
16.39 ml
1 lb/gal
119,800 mg/l
1 ton
0.907 Mg
iT
0.907 Mg
(Source: Amended at
Ill. Peg.
______,
effective
SUBPART B: DEFINITIONS
Section 211.121
Other Definitions
All terms defined in 35 Ill. Adm. Code 201 which appear in 35
Ill. Adm. Code 211
-
219 have the definitions specified by 35
Ill. Adm. Code 201.102. Otherwise the definitions in See-i4-ef~
211.122 this Part shall apply.
(Source: Amended at
Ill. Reg.
______,
effective
__________
Section 211.122
Definitions (Repealed)
“Accelacota”: a pharmaceutical coating operation which
consists of a horizontally rotating perforated drum in
which tablets are placed, a coating is applied by
spraying and the coating is dried by the flow of air
oss the drum through the perforations.
“Accumulator”: The reservoir of a condensing unit
receiving the condensate from a surface nd~r~
“Acid Cases”:
For
the purposes of Scotion
9.4
of the
Environmental Protection Act (the Act) (Ill. Rev. Stat.
1987, oh. 111~, par. 1009.4), hydrogen chloride,
hydrogen fluoride and hydrogen bromide, which exist as
gases, liquid mist, or any combination thereof.
“Actual Heat Input”: The quantity of heat produced by
the combustion of fuel using the gross heating value of
the fuel.
“Aeration”: The practice of forcing air through bulk
stored grain to maintain the condition of the r~i~ir~~
“Afterburner”: A device in which materials in gaseous
01 ~0-0t42Li~

effluents are
“Air Dried Coating”: Coatings that dry by the use of
air or forced air at temperatures up to 363.15°K (194°
F).
“Air suspension coater/drycr”: a pharmaceutical
coating operation which consists of vertical chambers
in which tablets or particles arc placed, and a coating
is applied and then dried while the tablets or
particles are kept in a fluidizcd state by the passage
of air upward through the chambers.
“Annual Grain Through-Put”: Unless otherwise shown by
the owner or operator, annual grain through—put for
grain-handling operations, which have been in operation
for three consecutive years prior to June 30, 1975,
shall be determined by adding grain receipts and
shipments for the three previous fiscal years and
dividing the total by 6. The annual grain through-put
for grain-handling operations in operation for less
than three consecutive years prior to June 30, 1975,
shall be determined by a reasonable three-year
estimate; the owner or operator shall document the
reasonableness of his three-year estimate.
“Architectural Coating”: Any coating used for
residential or commercial buildings or their
appurtenances, or for industrial buildings which is
site applied.
“Asphalt”: The dark-brown to black cementitiouc
material (solid, semisolid or liquid in consistency) -of
which the main constituents arc bitumens which occur
naturally or as a residue of petroleum refining.
“Asphalt Prime Coat”: A low-viscosity liquid asphalt
applied to an absorbent surface as the first of more
than one asphalt coat.
“Automobile”: Any first division motor vehicle as that
term is defined in the Illinois Vehicle Code (Ill. Rev.
Stat. 1987, ch. 95~,pars 1-100 et seq.).
“Automobile or Light-Duty Truck Manufacturing Plant”:
A facility where parts arc manufactured or finished for
eventual inclusion into a finished automobile or
light-duty truck ready for sale to vehicle dealers, but
not including customizers, body shops and other
repainters.
“Automobile or Light Duty Truck Refinishing”: The
01 L~0-Ui~25
17

18
repainting of used automobiles or light duty trucks.
“Batch Loading”: The process of loading a number of
irtdividii-il
n.~irt~~ ~
tiim~
for
d’-~’
“Bead-Dipping”: The dipping of an assembled tire bead
into a solvent—based cement.
“British Thermal Unit”: The quantity of heat required
to raise one pound of water from 60°F to 61°F
(abbreviated btu).
-“Bulk Gasoline Plant”: Any gasoline storage and
distribution facility that receives gasoline from bulk
gasoline terminals by delivery vessels and distributes
gasoline
to gasoline dispensing facilities.
“Bulk Gasoline Terminal”: Any gasoline storage and
distribution facility that receives -gasoline by
pipeline, ship or barge, and distributes gasoline to
bulk gasoline plants or gasoline dispensing facilities.
“Can Coating”: The application of a coating material
to a single walled container
that
is manufactured from
metal sheets thinner than 29 gauge (0.0141 in).
“Certified Investigation”: A report signed by Illinois
Environmental Protection Agency (Agency) personnel
certifying whether a grain-handling operation (or
portion thereof) or grain—drying operation is causing
or tending to cause air pollution. Such report must
describe the signatory’s investigation, including a
summary of those facts on which he relies to certify
whether the grain-handling or grain-drying operation is
causing or threatening or allowing the discharge or
emission of any contaminant into the environment so as
to cause or tend to cause air pollution in Illinois,
either alone or in combination with contaminants from
other sources, or so as to violate regulations or
standards adopted by the Pollution Control Board
(Board) under the Environmental Protection Act (Act).
The certified investigation shall be open to a
reasonable public inspection and may be copied upon
payment of the actual cost of reproducing the original.
“Choke Loading”: That method of transferring grain
from the grain—handling operation to any vehicle for
~hipmcnt or delivery which precludes a free fall
velocity of grain from a discharge spout into the
receiving container.
“Cleaning and Separating Operation”: That operation
0 RO-Q’426

19
where foreign and undesired substances arc removed from
the grain.
“Clear Coating”: Coatings that lack color and opacity
or are transparent using the undercoat as a
ref
lectant
base or undertone color.
“Closed Purge System”: A system that is not open to
the atmosphere and that is composed of piping,
connections, and, if necessary, flow inducing devices
that transport liquid or vapor from a piece or pieces
of equipment to a control device, or return the liquid
or vapor to the process line.
“Closed Vent System”: A system that is not open to the
atmosphere and that is composed of piping, connections,
and, if necessary, flow inducing devices that transport
gas or vapor from a piece or pieces of equipment to a
control device, or return the gas or vapor to the
process line.
“Coal Refuse”: Waste products of coal mining, cleaning
and coal preparation operations containing coal, matrix
material, clay and other organic and inorganic
material.
“Coating”
“:
Fr~r
rnirnn’~sof this Part, acoatir2y
includes a material app~~
suostrate ror
decorative, protective or other functional purposes.
Such material shall include, but arc not limited to
paints, varnishes, scalers, adhesives, dilucnts and
thinners.
“Coating Applicator”: Equipment used to apply a
surface coating.
“Coating Line”: An operation where a surface coating
is applied to a material and subsequently the coating
is dried and/or cured.
“Coating Plant”: Any building, structure or
installation that contains a coating line and
which is
located on one or more contiguous or adjacent
properties and which is owned or operated by
the same
person (or by persons under common control).
“Coil Coating”: The application of a coating material
to any flat metal sheet or strip that comes in rolls or
coils.
“Cold Cleaning”: The process of cleaning and removing
soils from surfaces by spraying, brushing, flushing or
01 L~O-0I427

20
immersion while maintaining the organic solvent below
its boiling point. Wipe cleaning is not included in
this definition.
“Complete Combustion”: A process in which all carbon
contained in a fuel or gas stream is converted to
carbon dioxide.
“Component”: Any piece of equipment which has the
potential to leak volatile organic material including-i--
but not limited to, pump seals, compressor seals, seal
oil dcgassing vents, pipeline valves, pressure relief
devices, process drains and open ended valves. This
definition excludes valves which are not externally
r-egulatcd, flanges, and equipment in heavy liquid
service. For purposes of 35 Ill. Adm. Code 215.
&u~partQ, this definition also excludes bleed ports of
gear pumps in polymer service.
“Concentrated Nitric Acid Manufacturing Process”: Any
acid producing facility manufacturing nitric acid with
a concentration equal to or greater than 70 percent by
weight.
~Condensate”: Hydrocarbon liquid separated from
it-s
associated gasses which condenses due to changes in the
temperature or pressure and remains liquid at standard
conditions.
“Condcnsible PM-lO”: PM-b formed immediately or
shortly after discharge to the atmosphere, as measured
by the applicable test method specified in 35 Iii. Adm.
Code 212.110. Condensible particulate matter exists in
gaseous and/or vapor form prior to release to the
atmosphere, e.g., in the stack, and forms particulate
matter upon condensation when subject to conditions of
cooling and dilution in the atmosphere.
“Control Device”: Equipment, such as an afterburner,
adsorber, scrubber, condenser, cyclone or baghouse used
to remove or prevent the emission of air pollutants
from a contaminated exhaust stream. For purposes of
35
Ill. Adm. Code 215, Subpart Q, an enclosed combustion
device, vapor recovery system, flare, or closed
container.
“Conveyorized Degreasing”: The continuous process of
cleaning and removing soils from surfaces utilizing
either cold or vaporized solvents.
11C-rude Oil”: A naturally occurring mixture which
~ hydrocarbons and sulfur, nitrogen

21
derivatives of hydrocarbons and which is a liquid at
~-1~nd~rd
~nn~itiionr~
“Crude Oil Gathering”: The transportation of crude oil
o~-condensate after custody transfer between a
production facility and a reception point.
“Crushing”: The fragmentation of non—metallic minerals
by a machine such as a jaw, gyratory, cone, roll, rod,
mill, harnmcrmill, and impactor.
“Custody Transfer”: The transfer of produced petroleum
and/or condensate after processing and/or treating in
the producing operations, from storage tanks or
automatic transfer facilities to pipelines or any other
fo-rms of transportation.
“Cutback Asphalt”: Any asphalt which
has
been
liquified by blending with petroleum solvents other
than residual fuel oil and has not been emulsified with
water.
“flr~r”~
Any equipment or system used in solvent
cleaning.
“Delivery Vessel”: Any tank truck or trailer equipped
with a storage tank that is used for the transport of
gasoline to a stationary storage tank at a gasoline
dispensing facility, bulk gasoline plant or bulk
f~i~~n1
~ni~
t
rm~rii1
-
“Distillate Fuel Oil”: Fuel oils of
as specified in detailed requirements
grade
for
No.
fuel
1 or 2
oil
A.S.T.M. D 369—69 (1971).
“~y Cl4~ Facility”. A facility
uleaning of fabrics using an ccccntialiy
nunuqueuu~
oo1vr~nt
h’~j
m~rv-~
of onr or morr’ ‘~o1vrnt uhc~~
extraction of
excess solvent by spinning and drying by
tumbling in an airotream.
The facility includes, but
is not limited to, washers, dryers, filter and
purification s ystcmo. waste
disposal systems, holding
engaged in
~
grain-handling grain-drying operation.
“Effective Crate Area”: That a-rea of a dump—pit grate
through which air passes, or would pass, when
aspirated.
“Effluent Water Separator”: Any tank, box, sump or
C) 1 Li0-Q~2g
~nd attendant piping and
-~———-—., _.1_

22
other apparatus in which any
—, nfl
on or entrained or contained in water entering such
tank, box, sump or other
-
apparatus is
physically
.~p~iratedunu reinovea irom sucri w~ccr pcior
LU
outfall,
drainage or recovery of such water.
“Emission Rate”: Total quantity of any air contaminant
discharge into the atmosphere in any one-hour period.
“Enclose”: With respect to 35 Ill. Adm. Code 215
Subpart T, to cover any volatile organic liquid surface
that is exposed to the atmosphere.
“End Sealing Compound Coat”: A compound applied to can
ends which functions as a gasket when the end is
assembled on the can.
“Excess Air”: Air supplied in addition to the
theoretical quantity necessary for complete combustion
of ~ill
fm~’1
and/rn~’ rrimhii~tih1r’
w~’~r’ ~i~1
“Excessive Release”: A discharge of more than- 295g
(0.65 pounds~
~n
sulfide into
~ tmos~
-,
(JL ffl~LuUpLuI1~
r~rir~r-r’
in
any five
UL xxyuLuyeIl
1 FlU’ fl
minute perioc1~
“Existing Grain-Drying Operation”: Any grain-drying
operation the construction or modification of which was
commenced prior to June 3-0, 1975.
“Existing Grain-Handling Operation”: Any
grain—handling operation the construction or
modification of which was commenced prior to June 30,
19 7-5--
“Exterior Base Coat”: An initial coating applied to
the exterior of a can after the can body has been
~f-ormcd.
“Exterior End Coat”: A coating applied by rollers or
spraying to the exterior end of a can.
“External Floating Roof”: A storage vessel cover in an
open top tank consisting of a double deck or pontoon
single deck which is supported by the petroleum liquid
being contained and is equipped with a closure seal
between th~
dr~c~kc’~kic~
.rnd i-i~nk
w~11-~
“Extreme Per formance Coating”: Coatings
designed for
exposure to any of the following: the ambient
weather
conditions, temperatures above 368.15° 1
(203° F),
detergents, abrasive and scouring agents, solvents,
01t~00t4~30

23
environmental conditions.
“Fabric Coating”: The coating of a textile substratc-~
-ineluding operations where the coating impregnates the
substrate.
“Final Repair Coat”: The repainting of any coating
which is damaged during vehicle assembly.
“Firebox”: The chamber or compartment of a boiler or
furnace in which materials are burned, but not the
c~omhl1n1— i n-ri
i—~h-imht--’-r or
ift~-rhnrni~r
of -~n
i nr~i
ni-~r’~tnr
-
“Flcxographic Printing”: The application of words,
designs and pictures to a substrate by means of a roll
printing technique in which the pattern to be applied
is raised above the printing roll and the image carrier
is made of clastomcric materials.
“Floating Roof”: A roof on a stationary tank,
reservoir or other container which moves vertically
upon change in volume of the stored material.
“Freeboard Height”: For open top vapor degrcascrs, the
distance from the top of the vapor zone to the top of
the dcgreascr tank. For cold cleaning dcgrcascrs, the
distance from the solvent to the top of the degreaser
tank.
“Fuel Combustion Emission Source”: Any furnace, boiler
or similar equipment used for the primary purpose of
producing heat or power by indirect heat transfer.
...-‘
7~_’
—.
(z~.rl1Tnn
“Fugitive Particulate Hatter”: Any particulate matter
emitted into the atmosphere other than through a stack,
provided that nothing in this definition or in 35 Ill.
Adm. Code 2l2.Subpart K shall exempt any source from
compliance with other provisions -of 35 Ill. Adm. Code
212 otherwise applicable merely because of the absence
of a stack.
“Gas Service”: Means that the component contains
process fluid that is in the gaseous state at operating
conditions.
-R
“Fue’
‘~
System”
-~ ~
for collection
ref.~
fuel ~
includi~, but not limit-ed to, pipi~ -f-er
‘ ‘ -
~-i~ tail gas-
4~i
~
— -
piping
)lll
~J~1
1
nr’ry
I flhI~
procc~3~.UfliL..,
!u.LxJ..lly

Any petroleum
apor pressure of 4 pounds or greater
“Gasoline Dispensing Facility”: Any sit-c where
gasoline is transferred from a stationary storage tank
to- a motor vehicle gasoline tank used to provide fuel
to the engine of that motor vehicle.
“Grain”:
The whole kernel or seed of corn, wheat,
oats, soybeans and any other cereal or oil seed plant;
and the normal fines, dust and foreign matter which
results from harvesting, handling or conditioning.
The
grain shall be unaltered by grinding or processing.
“Grain—Drying Operation”:
Any operation, excluding
aeration, by which moisture is removed from grain and
which typically uses forced ventilation with the
addition
of heat.
“Grain-Handling and Conditioning Operation”: A grain
storage facility and its associate grain transfer,
c-leaning, drying, grinding and mixing operations.
“Grain—Handling Operation”: Any operation where one or
more of the following grain—related processes (other
than grain-drying operation, portable grain-handling
equipment, one-turn storage space, and excluding flour
mills and feed mills) are performed: receiving,
shipping, transferring, storing, mixing or treating of
grain or other processes pursuant to normal grain
operations.
“Green Tire Spraying”: The spraying of green tires,
both inside and outside, with release compounds which
help remove air from the tire during molding and
prevent the tire from sticking to the mold after
curing.
“Green Tires”: Assembled tires before molding and
curing have occurred.
“Gross Heating Value”: Amount of heat produced when a
unit quantity of fuol i~hurr~-d to ~nrhon r1icv~idr~~nd
w~cr vupor, and the water vapor condensed as described
in A.6.T.N. D—20l5—66, D—900—55, D—l826—64 and
D—240—64-~-
“Heavy Liquid”: Liquid with a true vapor pressure of
less than 0.3 kPa (0.04 psi) at 294.30 K
(700
F) or 0.1
Reid Vapor Pressure as determined by A.S.T.M. method
D-323; or which when distilled requires a temperature
of 300°F or greater to recover 10 of the liquid as
~~ü-QI~32
24
2

25
determined by A.S.T.N. method D-86.
~avy Nctals”: For the purposes ~~on 9.4 of the
Act, elemental, ionic, or combined forms of arsenic,
cadmium, mercury, chromium, nickel and lead.
“Heavy, Off-Highway Vehicle Products”: For the
purposes of Section 215.204(k), heavy off-highway
vehicle products shall include: heavy construction,
mining, farming or material handling equipment; heavy
industrial engines; diesel—electric locomotives and
associated power generation equipment; and the
components of such equipment or engines.
“Hot Well”:
receiving the
The reservoir of
condensate from
a
a
condensing
barometric
unit
condenser.
~lI-~
(r’r’r)i
riri
Pr-~nt4
~
Thr~~r’ ~ir~ti
vi
ti ~
~pecifically defined in the list of
“‘~~
practices develop-cd by the Joint EPA
Force and included herein under 35 Ill. Adm. Code
!.A.JCiS.~’_.jJ
T-,.-.~,,.—-.4.-fl.—,, ~
212.461.
“-Incinerator”: Combustion apparatus in which refuse is
burned.
“Indirect Heat Transfer”: Transfer of heat in such a
way that the source of heat does not come into direct
contact with process materials.
“In—Process Tank”: A container used for mixing,
blending, heating, reacting, holding, crystallizing,
evaporating, or cleaning operations in the manufacture
of pharmaceuticals.
“In—situ Sampling
Systems”: Nonextractive samplers or
in—i inr’omr~ir~r~-~
“Interior Body Spray Coat”: A coating applied by spray
to the interior of a can after the can body has been
formed.
“Internal Transferring Area”: Areas and associated
equipment used for conveying grain among the various
grain operations.
“Large Appliance Coating”: The application of a
coating material to the component metal parts
(including but not limited to doors, cases, lids,
panels and interior support parts)- of residential and
commercial washers, dryers, ranges, rcfrigerators-~
freezers, water heaters, dishwashers, trash compact
U L1~O-QI.~33

26
“Light-Duty Truck”: Any second division motor vehicle,
as that term is defined in the Illinois Vehicle Code,
(Ill. Rev. Stat. 1989,
oh.
95~,pars. 1 100 et seq.)
weighing less than 3854 kilograms (8500 pounds) gross.
“Liquid-Mounted Seal”: A primary seal mounted in
continuous contact with the liquid between the tank
wall and the floating roof edge around the
circumference of the roof.
“Liquid Service”: Means that the equipment or component
contains process fluid that is in a liquid statc at
operating conditions.
“Liquids Dripping”: Any visible leaking from a seal
-including spraying, misting, clouding and icc
formation.
“Tr~t-i—Cut ri-~--~”•
~ni.r
-tn-i
tjhr-’rr
grain i’~ tr~n~f~rrc~c1
from the grain-handling operation to any vehicle for
shipment or delivery.
“Low Solvent Coating”:
A coating
which contains less
organic solvent than
the conventional coatings used by
the inaustry.
~w
..~ventcoatings include
water-borne, higher solids, electro—depos.ition and
nowdc~r ~n~~ti
nri~
-
r
“Magnet Wire Coating”: The application of a coating of
electrically insulating varnish or enamel to conducting
wire to be used in el-ectrical machinery.
“Major Dump Pit”: Any dump- pit with an annual grain
through-puti of i~or~thnn
~OOOOfl
hn-thri~ or whirib
receives more than 40 of the annual
grain through—put
of the grain-handling operation.
“Major Metropolitan Area (MMA)”: Any county or group
of counties which is defined by
the following Table:
MAJOR METROPOLITAN AREAS IN ILLINOIS (MMA’c)
MMA COUNTIES INCLUDED
IN ~A
Decatur
Cook, Lake, Will, DuPage-,
McHenry, Kane, Crundy,
Kendall, Kankakec
01 ~

27
Rockford
Winnebago
Rock Island
--
Moline Rock Island
Springfield
Sangamon
St. Louis (Illinois)
St. Clair, Madison
Bloominaton
—-
Normal
McLean
“Major Population Area (HPA)”: Areas of major population
concentration in Illinois, as described below:
The area within the counties of Cook; Lake; Durage; Will;
the townships of Burton, Richmond, McHenry, Greenwood,
Nunda, Door, Algonquin, Crafton and the municipality of
Woodotock, plus a zone extending two miles beyond the
boundary of said municipality located in HcHcnry County;
the townships of Dundee, Rutland, Elgin, Plato, St.
Charles, Campton, Geneva, Blackberry, Batavia, Sugar
Creek and Aurora located in Kane County; and the
municipalities of Kankakec, Bradley and Bourbonnais, plus
a zonc extending two miles beyond the boundaries of said
municipalities in Kankakce County.
The area within the municipalities of Rockford and Loves
Park, plus a zone extending two miles beyond the
boundaries of said municipalities.
The area within the municipalities of Rock Island,
Molinc, East Molinc, Carbon Cliff, Milan, Oak Grove,
Silvis, Hampton, Greenwood and Coal Valley, plus a zone
extending two miles beyond the boundaries of said
municipalities.
The area within the municipalities of Calesburg and East
Galesburg, plus a zone extending two miles beyond the
boundaries of said municipalities.
The area within the municipalities of Bartonville, Peoria
and Peoria Heights, plus a zone extending two miles
beyond the boundaries of said municipalities.
The area within the municipalities of Pekin, North Pekin,
Marquette Heights, Creve Cocur and East Peoria, plus a
zone extending two miles beyond the boundaries of said
municipalities.
The area within the municipalities of Bloomington and
Normal, plus a zone extending two miles beyond the
boundaries of said municipalities.
The area within the municipalities of Champaign, Urbana
and Savoy, plus a zone extending two miles beyond the
boundaries of said municipalities.
0 RO-O~35

28
The area within the municipalities of Decatur, Mt. Z-ion,
Harristown and Forsyth, plus
a zone extending two miles
beyond the boundaries of said municipalities.
The area within the municipalities of Springfield, Loland
~i-o~rr’
Jerome, Southern View, Grandview, Sherman and
Chatham, plus a
zone extending two miles
beyond the
boundaries of said municipalities.
The area within the townships of Godfrey, Foster, Wood
River, Fort Russell, Chouteau, Edwardsville, Venice,
Nameoki, Alton, Granite City and- Collinsville located in
Madison County; and the townships of Stites, Canteen,
Ccntrevillc, Caseyville, St. Clair, Sugar Loaf and
Stookey located in St. Clair County.
omiss
feed stocks
-._._~__
“Miscellaneous Fabricated Product Manufacturing Process”:
A manufacturing process involving one or more of the
following applications,
including any drying and curing
of formulations, and capable of emitting volatile organic
material:
components products
Asphalt soluti
Asphalt to paper or felt
Coatings
-
— —
— 1
— — .s_
1~.
—4
series o~ ~oces~
~.__.1.fl
“Manufacturing Process”:
A process emission source
-or
-
~
used to côn”~
~
or other components
into a prouuuL, either for sale or for use as a component i-n
a subsequent manufacturing process.
“Marine Terminal”:
A facility primarily engaged in loading
and unloading watcrcraft.
material to ~
part which isor will be
“Metal Furniture Coating”: The application of a coating
~“~‘
-“‘
made of
metal or any metal
u~embled with— o-ther metal, wood,
~uuiie,
piu~.iuor ylass parts to form a furniture piece
including, but not limited to, tables, chairs, wastebaskets,
beds, desks, lockers, benches, shelving, file cabinets,
lamps and room dividers.
This definition shall not apply to
any coating
line coating metal parts or products that is
identified under the Standard Industrial Classification Code
for
———--
Mrior
Cronnq-~
~i:——
——,—-,——r-——,—-,——
~
U~ ~7
~.
I
~O
40 or 41

29
Coatings to plastic
Coatings to- rubber or glass
Curing of furniture adhesives in an oven which would emit
in excess of 10 tons of volatile organic material per
year if no air pollution control equipment were used
Disinfectant material to manufactured items
Plastic foam scrap or “fluff” from the manufacture of
foam containers and Dackacdng material to form resin
pellets
Resin solutions to fibe
Rubber solutions to molds
Viscose -solutions for food casings
The storage and handling of formulations associated with
the process described above.
The use and handling of organic liquids and other
substances for clean—up operations associated with the
process described above.
~~ancous Formulation Manufacturing Process”:
A manufacturing process which compounds one or more of
the following and is capable of emitting volatile
organic material:
Adhesives
Asphalt solutions
Caulks, sealants or waterproofing agents
Coatings, other than paint and ink
Concrete curing compounds
Dyes
Friction materials and compounds
Resin solutions
Rubber solutions
Viscose solutions
O1~0-Ot~37

30
The storage and handling of formulations associated with
the process described above.
The use and handling of organic liquids and other
substances for clean—up operations associated with the
process dcscribcd above.
“Miscellaneous Metal Parts and Products”: For the purpose
of 35 Ill. Adm. Code 215.204, miscellaneous metal parts and
products shall include farm machinery, garden machinery,
small appliances, commercial machinery, industrial
machinery, fabricated metal products and any other
industrial category which coats mctal parts or products
under the Standard Industrial Classification Code for Major
Groups 33, 34, 35, 36, 37, 38 or 39 with the exception of
the following: coating lines subject to 35 Ill. Adm. Code
2l5.204(a)-(i) and (k), automobile or light-duty truck
refinishing, the exterior of marine vessels and the
customized top coating of automobiles and trucks if
production is less than thirty-five vehicles per day.
-“Miscellaneous Organic Chemical Manufacturing Process”:
A manufacturing process which produces by chemical
reaction, one or more of the following organic compounds
or mixtures of organic compounds and which is capable
emitting volatile organic materials:
of
Chemicals listed in 35 Ill. Adm. Code 215. Appendix D.
Chlorinated and sulfonated compounds
Cosmetic, detergent, soap or surfactant intermediaries or
specialties and products
Disinfcctants
-P-ood
additives
~i1 and petroleum product additives
Plasticizer”
Resins or noi’:mcrs
~ubbcr
additives
Swe’etencrs
Varnishes
OI~0-0I~38

31
The storage and handling of formulations associated with
the process described above.
~
use and handling oi organic liquids and other
GUnscancCs ror cican-nn nnmtions associated with the
oce ss
.~
.~...
“Mixing Operation”: The operati-on of- combining two or more
in~ri~nt~, of which at least one is- a arain.
“New Grain-Drying Operation”: Any grain—drying operation
the construction or modification of which is commenced on o..
after June
~,
“New Grain-Handling Operation”: Any grain handling
onr’rptipn the construction of modification of which is
commenced on or after June 30, 1975.
“No Dctcctable Volatilc Organic Material Emissions” A
ui~c~1uLye
Ut VOiULiic
oryanic
1UULCL~iUi IULU LI1C UL~LtU~pu~L~
as indicated by an instrument reading of less than 500 ppm
above background as determined in accordance with 40 CFR
60.485(c).
“One Hundred Percent Acid”: Acid with a specific gravity of
1.8205 at 30°C in the case of sulfuric acid and 1.4952 at
30°C in the case of nitric acid.
with
“One—Turn
a total
Storage
annual
Space”:
thrL~-put
That space
not i~
used to store
of the
grain
total
bushel storage of that space.
t~Opacity~t: A condition which renders material partially or
wholly impervious to transmittance of light and causes
obstruction of an observer’s view. For the purposes of
these regulations, the following equivalence between opacity
and Ringclmann shall be cmployed:
Opacity
Ringclmann
10
0.5
C.
30
l.g
C..
-60
3.
80
4.
-100
5.
“Open Top Vapor Dcgreaoing”: The batch process of cleaning
and removing soils from surfaces by condensing hot solvent
~nr~r
on t~hc~
c~ni,-1r’r
metal n~-~r-ts.
01 ~0-0~39

32
“Operator of Gasoline Dispensing Facility”: Any person who
is the lessee of or operates, controls or supervises a
gasoline dispensing facility.
-
“Organic Compound”: Any compound of carbon, excluding
carbon monoxide, carbon dioxide, carbonic acid, metal
carbides or carbonates, and ammonium carbonate.
“Organic Material”: Any chemical compound of carbon
-including dilucnts and thinners which are liquids at
standard conditions and which are used as discolvers,
viscosity reducers or cleaning agents, but excluding
methane, carbon monoxide, carbon dioxide, carbonic acid,
metallic carbonic acid, metallic carbide, metallic
carbonates and ammonium carbonate.
~urganic naLcria,Ls”: ror tnc purposes ot
fl,
t~ceLion
n
— — .._
~J.4
F’.
A
UL
~
J_
LI1C
~
Act, any chemical compound of carbon, including diluents and
thinners which are liquids at standard conditions and which
arc used as dissolvcrs, viscosity reducers or cleaning
agents, and polychiorinated dibcnzo-p-dioxins,
polyohlorinated dibcnzofurans and polynuclear aromatic
hydrocarbons are organic materials, while methanc, carbon
monoxide, carbon dioxide, carbonic acid, metallic carbonic
acid, metallic carbide, metallic carbonates and ammoniun
carbonate are not organic materials.
“Organic Vapor”: Gaseous phase of an organic material or a
mixture of organic materials present in the atmoc~phere.
“Ovcrvarnish”: A coating applied directly over ink or
printing.
“Owner of Gasoline Dispensing Facility”: Any person who has
legal or equitable title to a stationary storage tank at a
gasoline dispensing facility.
“Packaging Rotogravure Printing”: Rotogravure printing upon
paper, paper board, metal foil, plastic film and other
substrates, which are, in subsequent operations, formed into
packaging products or labels for articles to be sold.
“Paint Manufacturing Plant”: A plant that mixes, blends, or
compounds enamels, lacquers, scalers, shellacs, stains,
varnishes or pigmented surface coatings.
“Paper Coating”: The application of a coating material to
paper or pressure sensitive tapes, regardless of substrate,
including web coating on plastic fibers and decorative
coatings on metal foil.
01 1.~Q-QL3t~O

33
“Particulate Matter”: Any solid or liquid material, other
than water, which exists in finely divided form.
“Petroleum Liquid”: Crude oil, condensate or any finished
or intermediate product manufactured at a petroleum
refinery, but not including Number 2 through Number 6 fuel
oils as specified in A.S.T.M. D-3-96-69,gas- turbine fuel oils
Numbers 2-CT through 4-CT as specified in A.S.T.M. D-2880—7l
or diesel fuel oils Numbers 2—D and 4-D, as specified in
A.S.T.N. D-975-68-.
“Pr’l-rnl
r-um
Ref incr~-
lrr’-rogene
J~
n~j
‘f-a~1ity
+~
r’r’IfTfl
~
rTr’
1
-n r~rr~
~ducL~~
gasoline,
distillate fuel oils, re~idual fuc’
oils, lubricants, or other products through distillation,
cracking, extraction or reforming of unfinished petroleum
derivatives.
“Pharmaceutical”: Any compound or mixture, other than food,
u-s-ed in the prevention, diagnosis, alleviation, treatment or
cure of disease in man and animal.
“Pharmaceutical Coating Operation”: A device in which a
coating is applied to a pharmaceutical, including any drying
or curing of the coating.
“Photocheniically Reactive Material”: Any organic material
with an aggregate of more than 20 percent of its total
volume composed of the chemical compounds classified below
or the composition of which exceeds any of the following
individual percentage composition limitations. Whenever any
photochemically reactive material or any constituent of any
organic material may be classified from its chemic-a-I-
structure into more than one of the above groups -of organic
materials it shall be considered as a member of the most
reactive group, that is, the group having the least
allowable percent of the total organic materials.
1~
A combination of hydrocarbons, alcohols, aldehydes,
estc ‘—s-7 cth
-‘~-~~‘.‘.-
F”
4-
-~
‘-‘ -
L
.
-a-”-
-“‘
~
-
cycl..—elcfinis
~
o-~-~
-~-
~‘..rccnt.
definition doe-s
‘ “~‘
_________
__.t_ I
~L_ t_
— —
I
IILL.
~
LU ~UL(II
I
ny I I~IIf-~
Thi
A combination of aromatic compounds with eight or more
carbon atoms
to the molecule except ethylbcnzenc: B
percent.
A combination of ethylbcnzenc, kctones having branched
hydrocarbon structures or toluene: 20 percent.
“Plant”: All of the pollutant-emitting activities which
belong to the same industrial grouping, arc located on one
OLt~QU~4l

34
control of the same person (or persons under common
control), except the activities of any marine vessel.
Pollutant-emitting activities shall be- considered as part of
the same industrial grouping if they belong to the same
major group (i.e., which have the same two-digit code) as
d-escribcd in the “Standard Industrial Classification
Manual”, 1987.
“PM-b”: particulate matter with an aerodynamic diameter
less than or equal to a nominal 10 micrometers, as measured
by the applicable test methods specified by rule. Ambient
air concentrations for PM-b arc usually expressed in
m-i-crograms per cubic meter (ug/mL)—-
“Pneumatic Rubber Tire Manufacture”: The production of
pneumatic rubber tires with a bead diameter up to but not
including 20.0 inches and cross section dimension up to 12.8
inches, but not including specialty tires for antique or
other vehicles when produced on equipment separate from
normal production lines for passenger or truck type tires.
“Polybasic Organic Acid Partial Oxidation Manufacturing
Process”: Any process involving partial oxidation of
hydrocarbons with air to manufacture polybasic acids or
their anhydridec, such as maleic anhydride, phthalic
anhydride, terephthalic acid, isophthalic acid, trimelletic
anhydridc.
“Portabl-e Grain-Handling Equipment”: Any equipment
~cxcluding portable grain dryers) that is designed and
maintained to be movable primarily for use in a
non-continuous operation for loading and unloading one—turn
storage space, and is not physically connected to the grain
elevator, provided that the manufacturer’s rated capacity of
the equipment does not exceed 10,000 bushels per hour.
“Portland Cement Manufacturing Process Emission Source”:
any items of process equipment or manufacturing processes
used in or associated with the production of portland
cement, including, but not limited to, a kiln, clinker
cooler, raw mill system, finish mill system, raw material
dryer, material storage bin or system, material conveyor
belt or other transfer system, material conveyor belt
transfer point, bagging operation, bulk unloading station,
or bulk loading station.
“Portland Cement Process” or “Portland Cement Manufacturing
Plant”: Any facility or plant manufacturing portland cement
by either the wet or dry process.
“Power Driven Fastener Coating”: The coating of nail,
01 i0-Qt~i~2

35
staple, brad and finish nail fasteners where such fasteners
are fabricated from wire or rod of 0.0254 inch diameter or
greater, where such fasteners are bonded into coils or
strips, such coils and strips containing a number of such
fasteners, which fasteners are manufactured for use in power
tools, and which fasteners must conform with formal
standards for specific uses established by various federal
~-iz~o
includir.; Federal Specificati.~~.
FF-N—lOSb of the General Services Administration dated
August 23, 197-7 (does not include any later amendments or
editions; U.S. Army Armament Research and Development
Command, Attn: DRDAR-TCT, Rock Island, IL 61201), Bulletin
UM-25d of the U.S. Department of Housing and Urban
Development
-
Federal Housing Administration dated
September 5, 1973 (does not include any later amendments or
editions; Department of HUD, 547 W. Jackson Blvd., Room
1005, Chicago, IL 60606), and the Model Building Code of the
Council of American Building Officials, and similar
standards. For the purposes of this definition, the terms
“brad” and “finish nail” refer to single leg fasteners
fabricated in the same manner as staples. The application
of coatings to staple, brad, a-nd finish nail fasteners may
be associated with the incremental forming of such fasteners
in a cyclic or repetitious manner (incremental fabrication)
or with the forming of strips of such fasteners as a unit
from a band of wires (unit fabrication).
“PPM (Vol)
-
(Parts per Million) (Volume)”: A volume/volume
ratio which expresses the volumetric concentration of
ri~r~oucair contaminant in a million unit voiumcs or
“~.
“Pressure Release”: The emission of materials resulting
from system pressure being greater than set pressure of the
pressure relief device.
“Pressure Tank”: A tank in which fluids arc stored at a
pressure greater than atmospheric pressure.
“Prime Coat”: The first film of coating material applied in
a multinle coat operation.
“Prime Surfacer Coat”: A film of coating material that
touches up areas on the surface not adequately covered by
L~C
rn—line coat. rczore application of the ~or~ coat.
“Process”: Any stationary emission source other than a fuel
combustion emission source or an incinerator.
H
TT~4 4- 11.
- -
r’. -‘.‘.‘.,.-‘.
4-
l~-,1
.-.
.4
4—
,—.
,-
.4.. ,-.
—.
intermediate or final products, one or more of the chemicals
listed in 35- Ill. Adm. Code 215.Appcndix
1’)~ A
rn-occss unit
~1n
r1~u~r~t~
,
riti
.~n
01 ~ü-0~3
~L~J
1 T fl
--_
U’
fl T
r U’
1~-f1
1~
~“
i~e~...dcntly~ 1~upp1lcd
~

36
or- raw materials and sufficient storage facilities for the
product.
“Process Unit Shutdown”: A work practice or operational
procedure that stops production from a process unit or part
of a process unit. An unscheduled work practice or
operational procedure that stops production from a process
unit or part of a process unit for less than 24 hours is not
a process unit shutdown. The use of spare components and
technically feasible bypassing of components without
stopping production is not a process unit shutdown.
“Process Weight Rate”: The actual weight or engineering
approximation thereof of all materials except liquid and
gaseous fuels and combustion air, introduced into any
process per hour. For a cyclical or batch operation, the
process weight rate shall be determined by dividing such
actual weight or engineering approximation thereof by the
number of hours of operation excluding any time during which
the equipment is idle. For continuous processes, the
process weight rate shall be determined by dividing such
actual weight or engineering approximation thereof by the
number of hours in one complete operation, excluding any
timc during which the equipment is idle.
“Production Equipment Exhaust System”: A system for
collecting and directing into the atmosphere emissions of
volatile organic material from reactors, centrifuges and
other process emission sources.
“Publicatic~-~et~~ Printing”: -~eta;~av~raprinti~
upon paper which is subsequently formed into books,
magazines, catalogues, brochures, directories, newspaper
supplements or other types of non-packaging printed
materials.
“Purged Process Fluid”: Liquid or vapor from a process unit
that contains volatile organic material and that results
from flushing or cleaning the sample line(s) of a process
unit so that an uncontaminated sample may then be taken for
testing or analysis.
“Reactor”: A vat, vessel or other device in which chemical
reactions take place.
“Reasonably Available Control Technology (RACT)”: The
lowest emission limitation that an emission source is
capable of meeting by the application of control technology
thM-~ i’~ i’-c’n~’ionnh1v n’~mi1~h1r~ n~~in1r’ringtechnological nnd
mi
1”
“Refinery Fuel Cas”: Any gas
— _1_
.! __~t_
S
~..a
L’..~.4,
ted by a
Ut
~Q-QL~i~t4

37
petroleum refinery process unit and which is combusted—a-t
the refinery, including any gaseous mixture of natural gas
and fuel gas.
“Refinery Unit, Process Unit or Unit”: A set of components
which arc a part of a basic process operation such as
distillation, hydrotreating, cracking or reforming of
hydrocarbons.
“Refrigerated Condenser”: A surface condenser in which the
coolant supplied to the condenser has been cooled by a
mechanical device, other than by a cooling tower or
evaporative spray cooling, such as a refrigeration unit or
steam chiller unit.
“Residual Fuel Oil”: Fuel oils of grade No. 4, 5 and 6 as
specified in detailed requirements for fuel oils A.S.T.M.
D—396—C9 (1971)
-“Restricted Area”: The area within the boundaries of any
--
“municipality” as
defined in the Illinois Municipal Code,
plus a zone extending one mile
beyond the
boundaries of any
such municipality having a population of 1000 or
more
according to the latest federal census.
“Ringelmann Chart”: The chart published and described in
the Bureau of Mines, U.S. Department of Interior,
Information Circular 8333 (Revision of 1C7718) May 1, 1967,
or any adaptation thereof which has been approved by the
Agency.
“Roadway”: Any street, highway, road, alley, sidewalk,
parking lot, airport, rail bed or terminal, bikeway,
pedestrian mall or other structure used for transportation
purposes.
“Roll Printing”: The application of words, designs and
pictures to a substrate usually by means of a series of hard
rubber or metal rolls each with only partial coverage.
“Rotogravure Printing”: The application of words, designs
and pictures to a substrate by means of a roll printing
technique in which the pattern to be applied is recessed
relative to the non—image area.
“Cafety
RelieF’
wni-cn
is
ucs5gncd to open in order
pressures within a vessel or pipe.
“Sandblasting”: The usc of a mixture of sand
‘-In rnc~’
iir-r’~ for
cleaning and/or polishing
and air at
any type of
surface.
4-.-.
,
..‘..—.l
normally
4.-.~’.-..-..-.
do
4,,...-,
_,
____.r,

38
“Screening”: Separating material according to size by
pressing undersized material through one or more mesh
surfaces (screens) in series, and retaining oversized
.~
1 on
1hc~ iiir’’~h ~iirf~r,r”~
( ‘~~—r”n-~’~
-
“Sensor”: A device that measu
change in a physical quantity
flow rate,
pH,
or liquid level.
es a physical quantity or the
uch as temperature, pressure,
“Set of Safety Relief Valves”: One or more safety relief
valves designed to open in order to relieve excessive
~
i n th~ ~‘~‘~m-r’ v”’~’~c’1 or ri i i,r~-
‘-‘-Sheet Bacecoat”: A coating applied to metal when the metal
is in sheet form to serve as either the exterior or interior
of a can for either two-piece or three-piece cans.
“Shotblasting”: The use of a mixture of any metallic or
non—metallic substance and air at high pressures for
cleaning and/or polishing any type of surface.
“Side-Seam Spray Coat”: A coating applied to the seam of a
three-piece can.
“Smoke”: Small gas—borne particles resulting from
incomplete combustion, consisting predominately but not
exclusively of carbon, ash and other combustible material,
that form a visible plume in the air.
“Smok~i~~
LIF1
tJF~1
~i
‘I- I
~
1 r
T
I
~U’U1
Ti
~.rn
.
-~
~
-
e~
e stack
our’~
rom
to
hil
which
nti on
Flare” A combus-ti
ut and th
~-_4.-.1..
.-‘..—,-~-‘.‘.‘._4,-.__.,‘.‘..~‘.4-’.,,.4.’.1
__________________________
~
in the
~~1’i-
the smoke other
part-i ~-1te Inat~&~remitted to the atinospher- from such
U’~iTTI r~~)iI
‘~T
othavc anappea”~-~
.t~t
4~—
fl-f 9
aar~er
~
~~1cmann
unart.
“Solvent Cleaning”: The process of cleaning soils from
surfaces by cold cleaning, open top vapor dcgrcasing or
conveyorizcd dcgrcasing.
“Specialty High Gloss Catalyzed Coating”: Commcrcia-l
contract finishing of material prepared for printers and
lithographers where the finishing process uses a
solvent-borne coating, formulated with a catalyst, in a
q-uantity of no more than 12,000 gallons/year as supplied,
where the coating machines- arc sheet fed and the coated
sheets are brought to a minimum surface temperature of 19-0°
F, and where the coated sheets are to achieve the minimum
specular reflectance index of 65 measured at a CO degree
angle with a gloss meter.
E~-
-.
‘-1
01
~Q-QL~L#6

39
“Splash Loading”: A method of loading a tank, railroad tank
car, tank truck or trailer by use of other than a submerged
loading pipe.
“Stack”: A flue or conduit, free—standing or with exhaust
port above the roof of the building on which it is mounted,
by which air contaminants are emitted into the atmosphere.
“Standard Conditions”: A temperature of 70° F and a
pressure of 14.7 pounds per square inch absolute (psia).
“Standard Cubic Foot (ccf)”: The volume
standard conditions.
of one cubic foot
of gas at
“Startup”: The setting in operation of an emission source
for any purpose.
I,
c!4—
.~
4-
-;
~_-~‘-.
An emissi,.....~
~
which i....
uot self-propelled.
“Stationary Storage Tank”: Any container of liquid or gas
which is designed and constructed to remain at one site--
“Submerged Loading Pipe”: Any loading pipe the discharge
opening of which is entirely submerged when the liquid level
is 6 inches above the bottom of the tank. When applied to a
tank which is loaded from the side, any loading pipe the
discharge of which is entirely submerged when the liquid
level is 18 inches or two times the loading pipe diameter,
whichever is greater, above the bottom of the tank. The
definition shall also apply to any loading pipe which is
continuously submerged during loading operations.
“Sulfuric Acid Mist”: Sulfuric ac-id mist as measured
according to the method specified in 35 Ill. Adni. Code
214.101(b).
“Surface Condenser”: A device which removes a substance
from a gas stream by reducing the temperature of the stream,
w-i-thout direct contact between the coolant and the stream.
~~ctic Organic Chemical or i-oiymer Manufacturing Plant”
A plant that produces, as intermediates or final products,
one or more of the chemicals or polymers listed in- 35 Ill.
Adm. Code 2l5.Appendix D.
“Tablet Coating Operation”: A pharmaceutical coating
operation in which tablets are coated.
“Top Coat”: A film of coating- material applied in—a
multiple coat operation other than the prime coat, final
repair coat or prime surfacer coat.
B I ~0-QL~47
‘I

40
“Transfer Efficiency”: Ratio of the amount of coating
deposited onto a part or product to the total amount of
r~o-if
I
ncr
~r~1 I
d’l u~r-r~
-
“Tread End Cementing”: The application of a solvent—based
cement to the tire tread ends.
“True Vapor Pressure”: The equilibrium partial pressure
exerted by a petroleum liquid as determined in accordance
with methods described in American Petroleum Institute
Bulletin 2517, “Evaporation Loss From Floating Roof Tanks”
+196-2-h-
“Turnaround”: The procedure of shutting down an operating
refinery unit, emptying gaseous and liquid contents to do
inspection, maintenance and repair work, and putting the
unit back into production.
“Undertread Cementing”: The application of a solvent based
cement to the underside of a tire tread.
“Unregulated Safety Relief Valve”: A safety relief valve
which cannot be actuated by a means other than high pressure
in the pipe or vessel which it protects.
“Vacuum Producing System”: Any reciprocating, rotary or
centrifugal blower or compressor, or any jet ejector or
device that creates suction from a pressure below
atmospheric and discharges against a greater pressure.
“Valves Not Externally -Regulated”: Valves that have no
external controls, such as in-line check valves.
“Vapor Balance System”: Any combination of pipes or hoses
which creates a closed system between the vapor spaces of an
~loadi~ tank and
~..
~ceivi~ tank ~ch that
..~..
displaced from the receiving tank are transferred to the
t.’mnlc
hr~ina nn1r~.-.~~—L
“Vapor Collection System’1: All piping, seals, hoses,
r~rc~nr~-~—v.icmum
w~nt~ rind othc~r no~i h1c~
sources between
processing unit
the gasoline delivery vessel
and/or the storage tanks and
and the vapor
vapor holder.
“Vapor Control System”: Any system that prevents release to
the atmosphere of organic material in the vapors displaced
from a tank during the transfer of gasoline.
“Vapor-Mounted Primary Seal”: A primary seal mounted with
an air space bounded by the bottom of the primary seal, the
tank wall, the liquid surface and the floating roof.
Dl
1~O-OLt48

41
“Vinyl Coating”: The application of a topcoat or printing
to vir~yl coated fabric or vinyl —sh~L~ provided, however,
that the appl-ication of an organisol or plastisol is not
V.LIly.&. eu~.tLifly
“Volatile Organic Liquid”: Any liquid which contains
volatile organic material.
“Volatile Organic Material”: Any organic compound which
participates in atmospheric photochemical reactions unless
specifically exempted from this definition. For purposes of
determining compliance with emission limits, volatile
organic material shall be measured by the reference test
methods incorporated by reference in 35 Ill. Adm. Code
215.105. Where such a method also -inad-vertently measures
compounds with negligible photochcmical reactivity, an owner
or operator may exclude these negligibly reactive compounds.
For purposes of this definition, the following organic
compounds have been determined to have negligible
nho~oc~hm’mi~.-i1rr~. tiv-it-~r nnt~l
~
not ‘u’cilnti im’ nrcc.-inin
materials:
I’Mt.
I
— -— — _.1 .~ ~C -, - -
‘~~1
~hT~vroi-1if1~ioromh-inr-. (ce—~~
—I
Chloropcntafluoroethanc (CFC-115)
2—Chloro-l, 1,1, 2—tetrafluorocthanc ~HCFC—124)
Dichiorodifluoromethanc (CFC-l2)
coroethanc
(HCFC-l4lb)
~.hane (Methylene chloride)
Dichlorotctrafluorocthane (CFC-1l-4)
Dichiorotrifluoroethane (HCFC—123)
1, l-Difluorocthane (HFC-152a)
Ethane
Methane
Pentafluoroethane (HFC-125)
Tetrafluoroethane (HFC-l34a)
1, 1,2,2—Tctrafluorocthane (HFC-134)
Trichloroethane (Methyl ohl c~roforin\
1_1Lin~_4
~—.1-~1
,-~-...--..
.-.4—
1,
__,
.t,,—.__
_)
_-,
(Methyl chloroform)-
(CFC 11)-
ne (CFC—l13)
and the following classes of compounds:
Cyclic, branched, or linear, completely fluorinated
alkanes.
Cyclic, branched, or linear, completely fluorinated
ethers with no uns-aturations.
UI i~Q-Qt4i49
~~~~1
—,
m..-4
,-.~,.1
Trichlorotrif luoroeth

42
Cyclic, branched, or linear, completely fluorinated
tertiary amines with no unsaturations.
Sulphur-containing perfluorocarbons
and with sulfur bonds only to carbon
with
and
no unsaturations
fluorine.
&G’ NOTE: USEPA ~ the A;c~cy ~ay ~ ~irc~c~.4~ering
to demonstrate the amount of an exempted compound in a
source’s emissions on a case—by—ease basis as—a-
pre—conu~ excmpt~~
compounu unacr ocrtuin
circumstances, such as whe-re VOMs and exempted compounds
are mixed together, there are a large number of exempted
compounds, or the chemical composition of the exempted
compounds is not known. Sec 35 Ill. Adm. Code 215.108;
56 Fed Reg. 11419-20.
“Volatile Organic Material Content” or “VONC”: the
emissions of volatile organic material which would result
from the exposure of a coating, printing ink, fountain
solution, tire spray, dry cleaning waste or other similar
material to the air, including a~ydrying or curing, in the
absence of any control equipment. VOMC is typically
expressed as kilogram (kg) VON/liter (lb VON/gallon) of
coating or coating solids, or kg VON/kg (lb VOM/lb) of
coating solids, of coating material or material.
“Volatile Petroleum Liquid”: Any petroleum liquid with a
true vapor pressure that is greater than 1.5 psia (78
millimeters of mercury) at standard conditions.
“Wastcwater (Oil/Water) Separator”: Any device or piece of
equipment which utilizes the difference in density between
oil and water to remove oil and associated chemicals of
water, or any device, such as a flocculation tank or a
clarifier, which removes petroleum derived compounds from
waste water.
“Weak Nitric Acid Manufacturing Process”: Any acid
producing facility manufacturing nitric acid with a
concentration of less than 70 percent by weight.
“Woodworking”: The shaping, sawing, grinding, smoothing,
nn.lishing and making into products of any form or shape of
wood.
(Source: Repealed at
Ill. Reg.
_____,
effective
________
Section 211.130 Accelacota
“Accelacota” means a pharmaceutical coating operation which
consists of a horizontally rotating perforated drum in which
tablets are placed, a coating is applied by spraying, and the
U
tL~O-U1~50
4—-’-’

43
coating is dried by the flow of air across the drum through the
perforations.
(Source: Added at
Ill. Reg.
_____,
effective
_________
Section 211. 150 Accumulator
“Accumulator” means the reservoir of a condensing unit receiving
the condensate from a surface condenser.
(Source: Added at
Ill. Reg.
_____,
effective
____________)
Section 211.170 Acid Gases
“Acid gases” means, for the purposes of Section 9.4 of the
Environmental Protection Act (the Act) (Ill. Rev. Stat. 1991, ch.
lll~,par. 1009.4) t415 ILCS 5/9.41, hydrogen chloride, hydrogen
fluoride and hydrogen bromide, which exist as gases, liquid mist,
or any combination thereof.
(Source: Added at
Ill. Reg.
_____,
effective
____________
Section 211.210 Actual Heat Input
“Actual heat input” means the quantity of heat produced by the
combustion of fuel using the gross heating value of the fuel.
(Source: Added at
Ill. Reg.
_____,
effective
)
Section 211.230 Adhesive
“Adhesive” means any substance or mixture of substances intended
to serve as a joining compound.
(Source: Added at
Ill. Reg.
_____
,
effective
)
Section 211.250 Aeration
“Aeration” means the practice of forcing air through bulk stored
grain to maintain the condition of the grain.
(Source: Added at
Ill. Reg.______
,
effective
____________)
Section 211.290 Afterburner
“Afterburner” means a control device in which materials in
gaseous effluent are combusted.
(Source: Added at
Ill. Reg.
_____,
effective
___________)
Section 211.310 Air Contaminant
01 ~Q-0~5~

44
“Air contaminant” means any solid, liquid, or gaseous matter, any
odor, or any form of energy, that is capable of being released
into the atmosphere.
(Source: Added at
Ill. Reg.
____,
effective
___________
Section 211.330 Air Dried Coatings
“Air dried coatings” means any coatings that dry by use of air or
forced air at temperatures up to 363.l5°I (194°F).
(Source: Added at
Ill. Reg
effective
____________
Section 211.350 Air Oxidation Process
“Air oxidation process” means any unit process including
ammoxidation and oxychlorination which uses air or a combination
of air and oxygen as an oxidant in combination with one or more
organic reactants to produce one or more organic compounds.
(Source: Added at
Ill. Reg.
_____,
effective
____________)
Section 211.370 Air Pollutant
“Air pollutant” means an air pollution agent or combination of
such agents, including any physical, chemical, biological,
radioactive (including source material, special nuclear material,
and byproduct material) substance or matter which is emitted into
or otherwise enters the atmosphere. Such term includes any
precursors to the formation of any air pollutant, to the extent
that the relevant statute or rule has identified such precursor
or precursors for particular purpose for which the term “air
pollutant” is used.
(Source: Added at
Ill. Reg.
_____,
effective
___________)
Section 211.390 Air Pollution
“Air pollution” means the presence in the atmosphere of one or
more air contaminants in sufficient quantities and of such
characteristics and duration as to be iniurious to human, plant,
or animal life, to health, or to property, or to unreasonably
interfere with the enjoyment of life or property.
(Source: Added at
Ill. Req.
_____,
effective
__________
Section 211.410 Air Pollution Control Equipment
“Air pollution control equipment” means any equipment or
apparatus of a type intended to eliminate, prevent, reduce or
control the emission of air contaminants to the atmosphere.
0 L~Q-Q1~52

45
(Board Note: The requirements to obtain permits for air
pollution control equipment, in 35 Ill. Adm. Code 201.Subpart C,
apply to such equipment intended to eliminate, prevent, reduce or
control the emissions of
specified
air contaminants from
stationary emission units.
(Source: Added at
Ill. Reg.
_____,
effective
____________
Section 211.430 Air Suspension Coater/Dryer
“Air suspension coater/dryer” means a pharmaceutical coating
operation which consists of vertical chambers in which tablets or
particles are placed, and a coating is applied and then dried
while the tablets or particles are kept in a fluidized state by
the passage of air upward through the chambers.
(Source: Added at
Ill. Reg.
_____,
effective
____________
Section 211.450 Airless Spray
“Airless spray” means a spray coating method in which the coating
is atomized by forcing it through a small opening at high
pressure. The coating liquid is not mixed with air before
exiting from the nozzle.
(Source: Added at
Ill. Reg.
_____
,
effective
____________
Section 211.470 Air Assisted Airless Spray
“Air assisted airless spray” means a spray coating method which
combines compressed air with hydraulic pressure to atomize the
coating material into finer droplets than is achieved with pure
airless spray. Lower hydraulic pressure is used than with
airless spray.
(Source: Added at
Ill. Reg.
_____,
effective
____________)
Section 211.490 Annual Grain Through-Put
“Annual grain through—put” unless otherwise shown bV the owner or
operator, annual grain through—put for grain—handling operations,
which have been in operation for three consecutive years prior to
June 30, 1975, shall be determined by adding grain receipts and
shipments for the three previous fiscal years and dividing the
total by 6. The annual grain through-put for grain-handling
operations in operation for less than three consecutive years
prior to June 30, 1975, shall be determined bY a reasonable
three—year ‘estimate; the owner or operator shall document the
reasonableness of his three—year estimate.
(Source: Added at
Ill. Reg.
_____,
effective
____________)
01 ~O-O~53

46
Section 211.510 Application Area
“Application area” means an area where a coating is applied by
dipping, spraying or other techniques.
(Source: Added at
Ill. Reg.
_____,
effective
Section 211.530 Architectural Coating
“Architectural coating” means any coating used for residential
or
commercial buildings or their appurtenances, or for industrial
buildings, which is site applied.
-
(Source: Added at
Ill. Req.
effective
Section 211.550 As Applied
“As applied” means the formulation of a coating during
application on or impregnation into a substrate, including any
dilution solvents or thinners added at the source before
application of the coating.
(Source: Added at
Ill. Reg.
effective
Section 211.570 Asphalt
)
“Asphalt” means the dark—brown to black cementitious material
(solid, semisolid, or liquid in
~
of which the main
constituents are bitumens which occur naturally or as a residue
of petroleum refining.
(Source: Added at
Ill. Reg.
_____,
effective
____________)
Section 211.590 Asphalt Prime Coat
“Asphalt prime coat” means a low-viscosity liquid asphalt applied
to an absorbent surface as the first of more than one asphalt
coat.
(Source: Added at
Ill. Req.
_____,
effective
___________
Section 211.610 Automobile
“Automobile” means a motor vehicle designed for carrying no more
than 12 passengers.
(Source: Added at
Ill. Reg.
_____,
effective
____________)
Section 211.630 Automobile or Light-Duty Truck Assembly Source
or Automobile or Light-Duty Truck Manufacturing
Plant
01 ~Q_Q~45t4

47
“Automobile or light—duty truck assembly source” or “Automobile
or light—duty truck manufacturing plant” means a source where
parts are assembled or finished for eventual inclusion into a
finished automobile or light-duty truck ready for sale to vehicle
dealers, but not including customizers, body shops, and other
repainters.
(Source: Added at
Ill. Reg.
_____,
effective
___________)
Section 211.650 Automobile or Light-Duty Truck Refinishing
“Automobile or light-duty truck refinishing” means the repainting
of used automobiles and light-duty trucks.
(Source: Added at
Ill. Reg.
_____,
effective
___________
Section 211.670 Baked Coatings
“Baked coatings” means any coating which is cured or dried in an
oven where the oven air temperature exceeds 90°C (194°F).
(Source: Added at
Ill. Req.
_____,
effective
___________)
Section 211.690 Batch Loading
“Batch loading” means, with respect to solvent cleaning, the
process of loading a number of individual parts at the same time
for degreasing.
(Source: Added at
Ill. Reg.
_____,
effective
____________)
Section 211.710 Bead-Dipping
“Bead-dipping” means the dipping of an assembled tire -bead into a
solvent—based cement.
(Source: Added at
Ill. Reg.
_____,
effective
___________)
Section 211.730 Binders
“Binders” means organic materials and resins which do not contain
VON.
(Source: Added at
Ill. Req.
_____,
effective
___________)
Section 211.750 British Thermal Unit
“British Thermal Unit” means the quantity of heat required to
raise one pound of water from 60°Fto 61°F (abbreviated btu).
(Source: Added at
Ill. Reg.
_____,
effective
____________
01 ~0-0~55

48
Section 211.770 Brush or Wipe Coating
“Brush or wipe coating” means a manual method of applying a
coating using a brush, cloth, or similar obiect.
(Source: Added at
Ill. Reg.
_____,
effective
____________
Section 211.790 Bulk Gasoline Plant
“Bulk gasoline plant” means, for purposes of 35 Ill.
Adm. Code 215, any gasoline storage and distribution
source that receives gasoline from bulk gasoline
terminals by delivery vessels and distributes gasoline
to gasoline dispensing operations.
~j “Bulk gasoline plant” means, for purposes of 35 Ill.
Adm. Code 218 and 219, a gasoline storage and
distribution source with an average throughput of
76,000 1 (20,000 gal) or less on a 30—day rolling
average that distributes gasoline to gasoline
dispensing operations.
(Source: Added at
Ill. Reg.
_____,
effective
____________)
Section 211.810 Bulk Gasoline Terminal
“Bulk gasoline terminal” means any gasoline storage and
distribution source that receives gasoline by pipeline, ship or
barge, and distributes gasoline
to bulk gasoline plants or
gasoline dispensing operations.
(Source:
Added at —
Ill. Reg.
_____,
effective
____________)
Section 211.830 Can
“Can” means any cylindrical single walled metal container, with
or without a top, cover, spout or handles, with walls thinner
than 29 gauge (0.0141 inch) into which solid or liquid materials
may be packaged.
(Source: Added at
Ill. Reg.
_____,
effective
___________
Section 211.850 Can Coating
“Can coating” means any protective, decorative or functional
coating applied onto the surface of a can or a metal sheet or
metal part which is made into a can.
(Source: Added at
Ill. Reg.
_____,
effective
___________
Section 211.870 Can Coating Line

49
“Can coating line” means a coating line in which any protective,
decorative, or functional coating is applied onto the surface of
a can or a metal sheet or metal Part which is made into a can.
(Source: Added at
Ill. Reg.
_____
effective
Section 211.890 Capture
“Capture” means the containment or recovery of emissions from an
emission unit for direction into a duct which may be exhausted
through a stack or vent to a control device. The overall
abatement of emissions from an emission unit with an add—on
control device is a function both of the capture efficiency and
of the control device efficiency.
(Source: Added at
Ill. Peg.
_____,
effective
____________)
Section 211.910 Capture Device
“Capture device” means a hood, enclosed room, floor sweep or
other means of collecting volatile organic material or other air
contaminants into a duct. The pollutant can then be directed to
a pollution control device such as an afterburner, carbon
adsorber, fabric filter or scrubber. Sometimes the term is used
loosely to include the control device.
(Source: Added at
Ill. Reg.
_____,
effective
Section 211.830 Capture Efficiency
“Capture efficiency” means, for purposes of 35 Ill. Adm. Code 218
and 219, the weight of VON entering a capture system and
delivered to a control device divided by the weight of VON
generated bY an emission unit, during a particular time period,
expressed as a percentage.
(Source: Added at
Ill. Peg.
effective
Section 211.850 Capture System
“Capture system” means all equipment (including, but not limited
to, hoods, ducts, fans, ovens, dryers, etc.) used to contain,
collect and transport an air contaminant to a control device.
(Source: Added at
Ill. Reg.
effective
Section 211.970 Certified Investigation
“Certified investigation” means a report signed bY Illinois
Envonr~ti~l Pin
r~tInn
Agency (Agency) personnel certjfvincf
whether a grain-handling operation (or portion thereof) or
grain—drying operation is causing or tending to cause air
-----
U i~o-Ot~57

50
pollution. Such report must describe the signatory’s
investigation, including a summary of those facts on which the
signatory relies to certify whether the grain—handling or
grain—drvin~ operation is causing or threatening or allowing the
discharge or emission of anY contaminant into the environment so
as to cause or tend to cause air pollution in Illinois, either
alone or in combination with contaminants from other sources, or
so as to violate regulations or standards adopted by the
Pollution Control Board (Board) under the Environmental
Protection Act (Act). The certified investigation shall be open
to a reasonable public inspection and may be copied upon payment
of the actual cost of reproducing the original.
(Source: Added at
Ill. Peg.
_____,
effective
___________)
Section 211.990 Choke Loading
“Choke loading” means that method of transferring grain from the
grain-handling operation to any vehicle for shipment or delivery
which precludes a free fall velocity of grain from a discharge
spout into the receiving container.
(Source: Added at
Ill. Reg.
_____,
effective
___________
Section 211.1010 Clean Air Act
“Clean Air Act” means the Clean Air Act Amendments of 1970 (42
U.S.C. ~7401 et seq.), as amended in 1977 and 1990.
(Source: Added at
Ill. Peg.
_____,
effective
____________
Section 211.1050 Cleaning and Separating Operation
“Cleaning and separating operation” means that operation where
foreign and undesired substances are removed from the grain.
(Source: Added at
Ill. Reg.
,
effective
___________
Section 211.1090 Clear Coating
“Clear coating” means coatings that lack color and opacity or are
transparent using the undercoat as a reflectant base or undertone
color.
(Source: Added at
Ill. Req.
_____
,
effective
____________
Section 211.1110 Clear Topcoat
“Clear topcoat” means the final coating which contains binders,
but not opaque pigments, and is specifically formulated to form a
transparent or translucent solid protective film.
0 k0-0t~58

51
(Source: Added at
Ill. Reg.
_____,
effective
Section 211.1130 Closed Purge System
“Closed purge system” means a system that is not open to the
atmosphere and that is composed of piping, connections, and, if
necessary, flow inducing devices that transport liquid or vapor
from a piece or pieces of equipment to a control device, or
return the liquid or vapor to the process line.
(Source: Added at
Ill. Peg.
_____/
effective
____________
Section 211.1150 Closed Vent System
“Closed vent system” means a system that is not open to the
atmosphere and is composed of piping, connections, and, if
necessary, flow inducing devices that transport gas or vapor from
a piece or pieces of equipment to a control device.
(Source: Added at
Ill. Req.
_____,
effective
____________
Section 211.1170 Coal Refuse
“Coal refuse” means waste products of coal mining, cleaning and
coal preparation operations containing coal, matrix materialL
clay and other organic and inorganic material.
(Source: Added at
Ill. Reg.
_____,
effective
____________
Section 211.1190 Coating
~j. “Coating” means, for purposes of 35 Ill. Adm. Code 215,
a material applied to a substrate for decorative,
protective or other functional purposes. Such material
shall include, but are not limited to paints,
varnishes, sealers, adhesives, diluents and thinners.
j~j “Coating” means, for purposes of 35 Ill. Adm. Code 218
and 219, a material applied onto or impregnated into a
substrate for protective, decorative, or functional
purposes. Such materials include, but are not limited
to, paints, varnishes, sealers, adhesives, thinners,
diluents, and inks.
(Source: Added at
Ill. Peg.
_____,
effective
____________
Section 211.1210 Coating Applicator
“Coating applicator” means equipment used to apply a coating.
(Source: Added at
Ill. Peg.
_____,
effective
0
l4QO1~9

52
Section 211.1230 Coating Line
“Coating line” means, for purposes of 35 Ill. Adm. Code
215, an operation where a surface coating is applied to
a material and subsequently the coating is dried and/or
cured.
bi. “Coating line” means, for purposes of 35 Ill. Adm. Code
218 and 219, an operation consisting of a series of one
or more coating applicators and any associated
flash—off areas, drying areas, and ovens wherein a
coating is applied, dried, and/or cured. A coating
line ends at the point where the coating is dried or
cured, or prior to any subsequent application of a
different coating. It is not necessary for an
operation to have an oven or a flash—off area in order
to be included in this definition.
(Source: Added at
Ill. Peg.
_____,
effective
____________
Section 211.1250 Coating Plant
“Coating plant” means any building, structure or installation
that contains a coating line and which is located on one or more
contiguous or adjacent properties and which is owned or operated
by the same person (or by persons under common control).
(Source: Added at
Ill. Peg.
_____,
effective
____________)
Section 211.1270 Coil Coating
“Coil coating” means any protective, decorative or functional
coating which is applied onto any flat metal sheet or strip which
is delivered to the coating line as a roll or coil, unwound and
coated as a continuous substrate.
(Source: Added at
Ill. Peg.
_____/
effective
____________)
Section 211.1290 Coil Coating Line
“Coil coating line” means a coating line in which any protective,
decorative or functional coating is applied onto any flat metal
sheet or strip which is delivered to the coating line as a roll
or coil, unwound and coated as a continuous substrate.
(Source: Added at
Ill. Peg.
_____,
effective
___________
Section 211.1310 Cold Cleaning
“Cold cleaning” means the process of cleaning and removing soils
from surfaces by spraying, brushing, flushing, or immersion while
maintaining the organic solvent below its boiling point. Wipe
01 L~.Q—QL460

53
cleaning is not included in this definition.
(Source: Added at
Ill. Req.
_____,
effective
Section 211.1330 Complete Combustion
“Complete combustion” means a process in which all carbon
contained in a fuel or gas stream is converted to carbon dioxide.
(Source: Added at
Ill. Peg.
,
effective
____________
Section 211.1350 Component
“Component” means any piece of equipment which has the potential
to leak volatile organic material (VOM) including, but not
limited to, pump seals, compressor seals, seal oil degassing
vents, pipeline valves, pressure relief devices, process drains,
and open ended valves and lines, and flanges. For purposes of
Subparts Q and R in 35 Ill. Adm. Code 215, 218 and 219, this
definition excludes valves which are not externally regulated,
flanges, and equipment in heavy liquid service. For purposes of
Subpart 0 of 35 Ill. Adm. Code 215, 218 and 219, this definition
also excludes bleed ports of gear pumps in polymer service.
(Source: Added at
Ill. Req.
,
effective
____________-
Section 211.1370 Concrete Curing Compounds
“Concrete curing compounds” means any coating applied to freshly
poured concrete to retard the evaporation of water.
(Source: Added at
Ill. Req.
_____,
effective
____________
Section 211.1390 Concentrated Nitric Acid Manufacturing Process
“Concentrated nitric acid manufacturing process” means any acid
producing facility manufacturing nitric acid with a cOncentration
egual to or greater than 70 percent by weight.
(Source: Added at
Ill. Peg.
,
effective
___________
Section 211.1410 Condensate
“Condensate” means volatile organic liquid separated from its
associated gases, which condenses due to changes in the
temperature or pressure and remains liquid at standard
conditions.
(Source: Added at
Ill. Peg.
_____,
effective
___________
Section 211.1430 Condensible PM—b
O1~O-0L~61

54
“Condensible PM-b” means PM-b formed immediately or shortly
after discharge to the atmosphere, as measured by the applicable
test method specified in 35 Ill. Adm. Code 212.110. Condensible
particulate matter exists in gaseous and/or vapor form prior to
release to the atmosphere, e.g., in the stack, and forms
particulate matter upon condensation when subiect to conditions
of cooling and dilution in the atmosphere.
(Source: Added at
Ill. Peg.
_____,
effective
____________
Section 211.1470 Continuous Process
“Continuous process” means, with respect to manufacture of
polystyrene resin, a method of manufacture in which the styrene
raw material is delivered on a continuous basis to the reactor in
which the styrene is polymerized to polystyrene.
(Source: Added at
Ill. Req.
_____,
effective
____________)
Section 211.1490 Control Device
“Control device” means equipment (such as an afterburner,
adsorber, fabric filter or scrubber) used to remove or prevent
the emission of an air contaminant from a contaminated exhaust
stream.
(Source: Added at
Ill. Req.
_____,
effective
____________)
Section 211.1510 Control Device Efficiency
“Control device efficiency” means, for purposes of 35 Ill. Adm.
Code 218 and 219, the weight of VOM generated by an emission unit
which is destroyed or removed by a control device, divided by the
weight of VON generated by such unit entering the control device,
during a particular time period, expressed as a percentage.
(Source: Added at
Ill. Req.
_____/
effective
____________
Section 211.1530 Conventional Soybean Crushing Source
“Conventional soybean crushing source” means any hexane
extraction soybean crushing equipment that uses direct contact
steam for desolventizing and producing toasted soy meals.
(Source: Added at
Ill. Req.
_____,
effective
____________
Section 211.1550 Conveyorized Degreasing
“Conveyorized degreasing” means the continuous process of
cleaning and removing soils from surfaces utilizing either cold
or vaporized solvents.
0~Q0~62

55
(Source: Added at
Ill. Peg.
_____/
effective
____________)
Section 211.1570 Crude Oil
“Crude oil” means a naturally occurring mixture which consists of
hydrocarbons and sulfur, nitrogen, or oxygen derivatives of
hydrocarbons and which is a liquid at standard conditions.
(Source: Added at
Ill. Req.
_____/
effective
____________
Section 211.1590 Crude Oil Gathering
“Crude oil gathering” means the transportation of crude oil or
condensate after custody transfer between a production site and a
reception point.
(Source: Added at
Ill. Req.
_____,
effective
____________)
Section 211.1610 Crushing
“Crushing” means the fragmentation of non—metallic minerals by a
machine such as a jaw, gyratory, cone, roll, rod, mill,
hammermill, and impactor.
(Source: Added at
Ill. Req.
_____,
effective
___________
Section 211.1630 Custody Transfer
“Custody transfer” means the transfer of produced petroleum
and/or condensate after Processing and/or treating in the
producing operations, from storage tanks or automatic transfer
systems to pipelines or any other forms of transportation.
(Source: Added at
Ill. Req.
_____,
effective
____________
Section 211.1650 Cutback Asphalt
“Cutback asphalt” means any asphalt which has been liquified by
blending with petroleum solvents other than residual fuel oil and
has not been emulsified with water.
(Source: Added at
Ill. Peg.
_____,
effective
____________)
Section 211.1670 Daily-Weighted Average VON Content
“Daily—weighted average VON content” means the average VON
content of two or more coatings as applied on a coating line
during any day, taking into account the fraction of total coating
volume that each coating represents, as calculated with the
following equation:
n
U

56
VON~=
E
V1C~
11~T
i=1
where:
The average VON content of two or more
coatings as applied each day on a coating
line in units of kg VON/b (lbs VOM/gal) of
coating (minus water and any compounds which
are specifically exempted from the definition
of VON),
n
=
The number of different coatings as applied
each day on a coating line,
=
The volume of each coating (minus water and
any compounds which are specifically exempted
from the definition of VON) as applied each
day on a coating line in units of 1 (gal).
=
The VON content of each coating as applied
each day on a coating line in units of kg
VON/b (lbs VON/gal) of coating (minus water
and any compounds which are specifically
exempted from the definition of VON), and
=
The total volume of all coatings (minus water
and any compounds which are specifically
exempted from the definition of VOM) as
applied each day on a coating line in units
of 1 (gal)
(Source: Added at
Ill. Peg.
_____,
effective
____________)
Section 211.1690
“Day” means the consecutive 24 hours beginning at 12:00 AN
(midnight) local time.
(Source: Added at
Ill. Peg.
_____,
effective
____________)
Section 211.1710 Degreaser
“Degreaser” means any equipment or system used in solvent
cleaning.
(Source: Added at
Ill. Peg.
_____,
effective
____________)
Section 211.1730 Delivery Vessel
“Delivery vessel” means any tank truck or trailer equipped with a
storage tank that is used for the transport of gasoline to a
0 L~0-0~46~

57
stationary storage tank at a gasoline dispensing operation, bulk
gasoline plant, or bulk gasoline terminal.
(Source: Added at
Ill. Peg.
_____,
effective
___________-
Section 211.1750 Dip Coating
“Dip coating” means a method of applying coatings in which the
part is submerged in a tank filled with the coating.
(Source: Added at
Ill. Req.
_____/
effective
___________
Section 211.1770 Distillate Fuel Oil
“Distillate fuel oil” means fuel oils of grade No. 1 or 2 as
specified in detailed requirements for fuel oil ASTN D-369-69
(1971) incorporated by reference in 35 Ill. Adm. Code 218.112 and
219.112.
(Source: Added at
Ill. Req.
_____,
effective
___________
Section 211.1790 Drum
“Drum” means any cylindrical shipping container of 13 to
110-gallon capacity.
(Source: Added at
Ill. Req.
_____,
effective
____________)
Section 211.1810 Dry Cleaning Operation or Dry Cleaning
Facility
“Dry cleaning operation” or “Dry cleaning facility” means the
cleaning of fabrics using an essentially nonaqueous solvent by
means of one or more solvent washes, extraction of excess solvent
by spinning and drying by tumbling in an airstream. The dry
cleaning operation or facility includes, but is not limited to,
washers, dryers, filter and purification systems, waste disposal
systems, holding tanks, pumps and attendant piping and valves.
(Source: Added at
Ill. Reg.
_____,
effective
_________
)
Section 211.1830 Dump-Pit Area
“Dump—pit area” means any area where grain is received at a
grain-handling or grain-drying operation.
(Source: Added at
Ill. Req.
_____,
effective
________
Section 211.1850 Effective Grate Area
“Effective grate area” means that area of a dump—pit grate
through which air passes, or would pass, when aspirated.
01 ~0-0t~65

58
(Source: Added at
Ill. Peg.
_____,
effective
____________)
Section 211.1870 Effluent Water Separator
“Effluent water separator” means any tank, box, sump or other
apparatus in which any organic material floating on or entrained
or contained in water entering such tank, box, sump or other
apparatus is physically separated and removed from such water
prior to outfall, drainage or recovery of such water.
(Source: Added at
Ill. Req.
~,
effective
____________)
Section 211.1890 Electrostatic Bell or Disc Spray
“Electrostatic bell or disc spray” means an electrostatic spray
coating method in which a rapidly-spinning bell- or disc-shaped
applicator is used to create a fine mist and apply the coating
with high transfer efficiency.
(Source: Added at
Ill. Peg.
_____,
effective
___________)
Section 211.1910 Electrostatic Spray
“Electrostatic spray” means a spray coating method in which
opposite electrical charges are applied to the substrate and the
coating. The coating is attracted to the oblect due to the
electrostatic potential between them.
(Source: Added at
Ill. Req.
_____,
effective
___________)
Section 211.1930 Emission Pate
“Emission rate” means, if not otherwise stated in a specific
provision, the total quantity of a particular specified air
contaminant discharged into the atmosphere in any one—hour
period. For example, if not otherwise specified in 35 Ill. Adm.
Code 218 or 219, emission rate means the total quantity of
volatile organic material discharged into the atmosphere in any
one—hour period.
(Source: Added at
Ill. Peg.
_____,
effective
___________
Section 211.1950 Emission Unit
“Emission unit” means any part or activity at a stationary source
that emits or has the potential to emit any air pollutant.
(Source: Added at
Ill. Req.
_____,
effective
____________
Section 211.1970 Enamel
“Enamel” means a coating that cures by chemical cross—linking of
01 ~Q-0L~66

59
its base resin. Enamels can be distinguished from lacquers
because enamels are not readily resoluble in their original
solvent.
(Source: Added at
Ill. Req.
_____,
effective
____________)
Section 211.1990 Enclose
“Enclose” means, for purpose of 35 Ill. Adm. Code 215.481(c),
215.482(b) .218.481(c), 218.482(b), 219.481(c) and 219.482(b)
,
to
cover any volatile organic liquid surface that is exposed to the
atmosphere.
(Source: Added at
Ill. Peg.
_____,
effective
____________
Section 211.2010 End Sealing Compound Coat
“End sealing compound coat” means a can coating applied to can
ends which functions as a gasket when the end is assembled onto
the can.
(Source: Added at
Ill. Req.
_____,
effective
____________/
Section 211.2050 Ethanol Blend Gasoline
“Ethanol blend gasoline” means a mixture of gasoline and at least
9 ethanol by volume.
(Source: Added at
Ill. Req.
_____,
effective
Section 211.2070 Excess Air
“Excess air” means air supplied in addition to the theoretical
quantity necessary for complete
combustion of all fuel and/q~
combustible waste
material.
Ill. Peg.
effective
Excessive Release
(Source: Added at
Section 211.2090
“Excessive ~
means, for purposes of 35 Ill. Adm. Code
215.144, 218.144 and 219.144,
p
discharge of more than 295 g
(0.65 bbs) of mercaptans and/or hydrogen sulfide into the
atmosphere in any 5-minute period.
(Source: Added at
Ill. Peg.
_____,
effective
____________)
Section 211.2110 Existing Grain-Drying Operation
“Existing grain—drying operation” means any grain-drying
operation the construction or modification of which was commenced
prior to June 30, 1975.
01 ~0-0~67

60
(Source: Added at
Ill. Req
effective
___________)
Section 211.2130 Existing Grain-Handling Operation
“Existing grain-handling operation” means any grain-handling
operation the construction or modification of which was commenced
prior to June 30, 1975.
(Source: Added at
Ill. Req.
_____,
effective
___________
Section 211.2150 Exterior Base Coat
“Exterior base coat” means a can coating applied to the exterior
of a two-piece can body to provide protection to the metal or to
provide background for any lithographic or printing operation.
(Source: Added at
Ill. Req.
_____,
effective
___________)
Section 211.2170 Exterior End Coat
“Exterior end coat” means a can coating applied to the exterior
end of a can to provide protection to the metal.
(Source: Added at
Ill. Req.
_____,
effective
___________
Section 211.2190 External Floating Roof
“External floating roof” means a cover over an open top storage
tank consistIng of a double deck or pontoon single deck which
rests upon and is supported by the volatile organic liquid being
contained and is equipped with a closure seal or seals to close
the space between the roof edge and tank shell.
(Source: Added at
Ill. Req.
_____,
effective
-
)
Section 211.2210 Extreme Performance Coating
“Extreme performance coating” means any coating which during
intended use is exposed to any or all of the following: ambient
weather conditions; temperatures consistently above 95°C (203°F);
detergents; abrasive and scouring agents; solvents; or corrosive
atmospheres.
(Source: Added at
Ill. Peg.
_____,
effective
___________
Section 211.2230 Fabric Coating
“Fabric coating” means any protective, decorative or functional
coating which is applied onto or impregnated into a textile
fabric which is delivered to the coating line as a roll, unwound
and coated as a continuous substrate.
0 I ~3-OLe68

61
(Source: Added at
Ill. Req.
_____,
effective
___________)
Section 211.2250 Fabric Coating Line
“Fabric coating line” means a coating line in which any
protective, decorative, or functional coating is applied onto or
impregnated into a textile fabric which is delivered to the
coating line as a roll, unwound and coated as a continuous
substrate.
(Source: Added at
Ill. Req.
_____,
effective
____________
Section 211.2270 Federally Enforceable Limitations and
Conditions
“Federally enforceable limitations and conditions” means all
limitations and conditions which are enforceable by the
Administrator of the USEPA, including those requirements
developed pursuant to 40 CFR Parts 60 and 61; requirements within
any applicable implementation plan; and any permit requirements
established pursuant to 40 CFR 52.21 or 40 CFR 52.737 or under
regulations approved pursuant to 40 CFR Part 51 Subpart I, 40 CFR
51.166 and 40 CFR Part 70.
(Source: Added at
Ill. Req.
_____,
effective
____________)
Section 211.2310 Final Repair Coat
“Final repair coat” means, with respect to automobile or
light-duty truck assembly or manufacturing, a coating which is
used to repaint topcoat which is damaged during vehicle
assembly.
(Source: Added at
Ill. Req.
____,
effective
____________)
Section 211.2330 Firebox
“Firebox” means the chamber or compartment of a boiler or furnace
in which materials are burned, but not the combustion chamber or
afterburner of an incinerator.
(Source: Added at
Ill. Req.
_____,
effective
___________)
Section 211.2350 Fixed—Roof Tank
“Fixed—roof tank” means a cylindrical shell with a permanently
affixed roof.
(Source: Added at
Ill. Reg.
_____,
effective
____________)
Section 211.2370 Flexographic Printing
fl L~.U-OL~.69

62
“Flexographic printing” means a roll printing technique in which
the pattern to be applied is raised above the printing roll and
the image carrier is made of rubber or other elastomeric
materials.
(Source: Added at
Ill. Req.
_____,
effective
___________)
Section 211.2390 Flexographic Printing Line
“Flexographic printing line” means a printing line performing
flexographic printing.
(Source: Added at
Ill. Req.
_____,
effective
____________
Section 211.2410 Floating Roof
“Floating roof” means a roof on a stationary tank, reservoir, or
other container which moves vertically upon chan~e in volume of
the stored material.
(Source: Added at
Ill. Req.
_____,
effective
____________
Section 211.2430 Fountain Solution
“Fountain solution” means the solution used in certain methods of
printing which is applied to the image plate to maintain
hydrophilic properties of the non-image areas.
(Source: Added at
Ill. Reg.
_____,
effective
___________
Section 211.2450 Freeboard Height
“Freeboard height” means, for open top vapor degreasers, the
distance from the top of the vapor zone to the top of the
degreaser tank, and for cold cleaning degreasers, the distance
from the solvent to the top of the degreaser tank.
(Source: Added at
Ill. Req.
_____,
effective
____________
Section 211.2470 Fuel Combustion Emission Unit or Fuel
Combustion Emission Source
“Fuel combustion emission unit” or “Fuel combustion emission
source” means any furnace, boiler, or similar eauipment used for
the primary purpose of producing heat or power by indirect heat
transfer.
(Source: Added at
Ill. Peg.
_____,
effective
________
Section 211.2490 Fugitive Particulate Matter
“Fugitive particulate matter” means any particulate matter
UI ~0-~t~70

63
emitted into the atmosphere other than through a stack, provided
that nothing in this definition or in 35 Ill. Adm. Code 212,
Subpart K shall exempt any emission unit from compliance with
other provisions of 35 Ill. Adm. Code 212 otherwise applicable
merely because of the absence of a stack.
(Source: Added at
Ill. Peg.
_____,
effective
____________)
Section 211.2510 Full Operating Flowrate
“Full operating flowrate” means maximum operating capacity of the
source, emission unit or process unit, as applicable.
(Source: Added at
Ill. Peg.
_____,
effective
__________
Section 211.2530 Gas Service
“Gas service” means that the equipment or component contains
process fluid that is in the gaseous state at operating
conditions.
(Source: Added at
Ill. Req.
_____
,
effective
Section 211.2550 Gas/Gas Method
“Gas/gas method” means either of two methods for determining VON
capture efficiency which rely only on gas phase measurements.
The first method requires construction of a temporary total
enclosure (TTE) to ensure that all would—be fugitive emissions
are measured. The second method uses the building or room which
houses the coating line, printing line or other emission unit as
an enclosure. The second method requires that all other VON
lines or emission units within the room be shut down while the
test is performed, but all fans and blowers within the room must
be operated according to normal procedures.
(Source: Added at
Ill. Req.
effective
Section 211.2570 Gasoline
“Gasoline” means any petroleum distillate or petroleum
distillate/alcohol blend having a Reid vapor pressure of 27.6 kPa
or greater which is used as a fuel for internal combustion
engines.
(Source: Added at
Ill. Req.
_____,
effective
___________
Section 211.2590 Gasoline Dispensing Operation or Gasoline
Dispensing Facility
“Gasoline dispensing operation” or “Gasoline dispensing facility”
means any site where gasoline is transferred from a stationary
01
L~3-OL~7
I

64
storage tank to a motor vehicle gasoline tank used to provide
fuel to the engine of that motor vehicle.
(Source: Added at
Ill. Req.
_____,
effective
___________
Section 211.2650 Grain
“Grain” means the whole kernel or seed of corn, wheat, oats,
soybeans and any other cereal or oil seed plant and the normal
fines, dust and foreign matter which results from harvesting,
handling or conditioning. The grain shall be unaltered by
grinding or processing.
(Source: Added at
Ill. Peg.
_____,
effective
___________)
Section 211.2670
Grain-Drying Operation
“Grain-drying operation” means any operation, excluding aeration,
by which moisture is removed from grain
and which typically uses
forced ventilation with the addition of heat.
(Source: Added at
Ill. Req.
_____,
effective
____________)
Section 211.2690 Grain-Handling and Conditioning Operation
“Grain—handling and conditioning operation” means a grain storage
facility and its associate grain transfer, cleaning, drying,
grinding and mixing operations.
(Source: Added at
Ill. Peg.
_____,
effective
____________
Section 211.2710 Grain-Handling Operation
“Grain—handling operation” means any operation where one or more
of the following grain-related processes (other than grain-drying
operation, portable grain—handling equipment, one—turn storage
space, and excluding flour mills and feed mills) are performed:
receiving, shipping, transferring, storing, mixing or treating of
grain or other processes pursuant to normal grain operations.
(Source: Added at
Ill. Req.
_____
,
effective
____________)
Section 211.2730 Green-Tire Spraying
“Green tire spraying” means the spraying of green tires, both
inside and outside, with release compounds which help remove air
from the tire during molding and prevent the tire from sticking
to the mold after curing.
(Source: Added at
Ill. Req.
_____,
effective
Section 211.2750 Green Tires
0 1iQ-fJL~72

65
“Green tires” means assembled tires before molding and curing
have occurred.
(Source: Added at
Ill. Req.
_____,
effective
___________
Section 211.2770 Gross Heating Value
“Gross heating value” means amount of heat produced when a unit
quantity of fuel is burned to carbon dioxide and water vapor, and
the water vapor condensed as described in A.S.T.N. D2015-66,
D900—55, D1826-64 and D240—64 incorporated by reference in
Section 211.101 of this Part.
(Source: Added at
Ill. Req.
_____
,
effective
____________
Section 211.2790 Gross Vehicle Weight Rating
“Gross vehicle weight rating” means the value specified by the
manufacturer as the maximum design loaded weight of a single
vehicle.
(Source: Added at
Ill. Req.
_____
,
effective
____________
Section 211.2810 Heated Airless Spray
“Heated airless spray” means an airless spray coating method in
which the coating is heated lust prior to application.
(Source: Added at
Ill. Req.
_____,
effective
____________
Section 211.2830 Heatset
“Heatset” means a class of lithography which requires a heated
dryer to solidify the printing inks.
(Source: Added at
Ill. Req.
_____,
effective
____________/
Section 211.2850 Heatset-Web-Off set Lithographic Printing Line
“Heatset-web-offset lithographic printing line” means a
lithographic printing line in which a blanket cylinder is used to
transfer ink from a plate cylinder to a substrate continuously
fed from a roll or an extension process and an oven is used to
solidify the printing inks.
(Source: Added at
Ill. Req.
_____,
effective
___________)
Section 211.2870 Heavy Liquid
“Heavy liquid” means liquid with a true vapor pressure of less
than 0.3 kPa (0.04 psi) at 294.3°K (70°F) established in a
standard reference text or as determined by ASTM method D2879-86
01 ~~-0~73

66
(incorporated by reference in 35 Ill. Adm. Code 218.112 and
219.112); or which has 01 Reid Vapor Pressure as determined by
ASTM method D323-82 (incorporated bY reference in 35 Ill. Adm.
Code 215.105, 218.112 and 219.112); or which when distilled
requires a temperature of 42l.95°K (300°F) or greater to recover
10 percent of the liquid as determined bY ASTM method D86-82
(incorporated by reference in 35 Ill. Adm. Code 215.105, 218.112
and 219.112).
(Source: Added at
Ill. Peg.
_____,
effective
____________)
Section 211.2890 Heavy Metals
“Heavy metals” means, for the purposes of Section 9.4 of the Act,
elemental, ionic, or combined forms of arsenic, cadmium, mercury,
chromium, nickel and lead.
(Source: Added at
Ill. Req.
_____,
effective
____________
Section 211.2910 Heavy Off-Highway Vehicle Products
“Heavy off—highway vehicle products” means heavy construction,
mining, farming, or material handling equipment; heavy industrial
engines; diesel—electric locomotives and associated power
generation equipment; and the constituent parts of such equipment
or engines.
(Source: Added at
Ill. Req.
_____,
effective
____________
Section 211.2930 Heavy Off-Highway Vehicle Products Coating
“Heavy off—highway vehicle products coating” means any
protective, decorative or functional coating applied onto the
surface of heavy off—highway vehicle products. However, a high
temperature
aluminum coating to a diesel—electric locomotive in
Cook County is not a heavy off-highway vehicle products coating.
(Source: Added at
Ill. Req.
_____,
effective
____________)
Section 211.2950 Heavy Off-Highway Vehicle Products Coating
Line
“Heavy off—highway vehicle products coating line” means a coating
line in which any protective, decorative, or functional coating
is applied onto the surface of heavy off-highway vehicle
products.
However, application of a high temperature aluminum
coating to a diesel—electric
locomotive in Cook County is not a
heavy off-highway vehicle products coating line or part of a
heavy off-highway vehicle products coating line.
(Source: Added at
Ill. Peg.
_____,
effective
01 I4QQ1471~

67
Section 211.2970
High Temperature Aluminum Coating
“High temperature aluminum coating” means a coating that is
certified to withstand a temperature of 537.8°C (1000°F) for 24
hours.
(Source: Added at
Ill. Peg.
_____,
effective
____________
Section 211.2990 High Volume Low Pressure (HVLP) Spray
“High volume low pressure (HVLP) spray” means equipment used to
apply coatings by means of a spray gun which operates between 0.1
and 10 psig air pressure.
(Source: Added at
Ill. Peg.
_____,
effective
Section 211.3010 Hood
“Hood” means a partial enclosure or canopy for capturing and
exhausting, by means of a draft, the organic vapors or other
fumes produced from a coating line, printing line or other
emission unit.
(Source: Added at
Ill. Req.
_____
effective
Section 211.3030 Hot Well
“Hot well” means the reservoir of a condensing unit receiving the
condensate from a barometric condenser.
(Source: Added at
Ill. Req.
effective
Section 211.3050 Housekeeping Practices
“Housekeeping practices” means those activities specifically
defined in the list of housekeeping
practices developed by the
Joint EPA
-
Industry Task Force and
included herein under 35 Ill.
Adm. Code 212.461.
(Source: Added at
Ill. Req.
Section 211.3070 In-Process Tank
effective
“In—process tank” means, with respect to manufacture of
pharmaceuticals, a container used for mixing, blending, heatina
reacting, holding, crystallizing, evaporating or cleaning
operations.
(Source: Added at
Ill. Req.
_____,
effective
_______
Section 211.3090 In—Situ Sampling Systems
01
1~.0-QL75

68
“In—situ sampling systems” means nonextractive samplers or
in—line samplers.
(Source: Added at
Ill. Req.
_____,
effective
____________)
Section 211.3110 Incinerator
“Incinerator” means a combustion apparatus in which refuse is
burned.
-
(Source: Added at
Ill. Req.
_____,
effective
____________)
Section 211.3130 Indirect Heat Transfer
“Indirect heat transfer” means transfer of heat in such a way
that the source of heat does not come into direct contact with
process materials.
(Source: Added at
Ill. Req.
_____,
effective
___________)
Section 211.3150 Ink
“Ink” means a coating used in printing, impressing, or
transferring words, pictures, designs or other images onto a
substrate.
(Source: Added at
Ill. Req.
_____,
effective
____________)
Section 211.3170 Interior Body Spray Coat
“Interior body spray coat” means a can coating applied by spray
to the interior of a can body.
(Source: Added at
Ill. Req.
_____,
effective
____________)
Section 211.3190 Internal-Floating Roof
“Internal—floating roof” means a cover or roof in a fixed—roof
tank which rests upon and is supported by the volatile organic
liquid being contained and is equipped with a closure seal or
seals to close the space between the roof edge and tank shell.
(Source: Added at
Ill. Req.
_____,
effective
___________)
Section 211.3210 Internal Transferring Area
“Internal transferring area” means areas and associated equipment
used for conveying grain among the various grain operations.
(Source: Added at
Ill. Peg.
_____,
effective
____________)
Section 211.3230 Lacquers
01 ~u-0L~76

69
“Lacquers” means, with respect to coating of wood furniture, any
clear wood finishes formulated with nitrocellulose or synthetic
resins to dry by evaporation without chemical reaction, including
clear lacquer sanding sealers.
(Source: Added at
Ill. Reg.
_____,
effective
____________
Section 211.3250 Large Appliance
“Large appliance” means any residential and commercial washers,
dryers, ranges, refrigerators, freezers, water heaters,
dishwashers, trash compactors, air conditioners, and other
similar products.
(Source: Added at
Ill. Req.
_____
,
effective
___________
Section 211.3270 Large Appliance Coating
“Large appliance coating” means any protective, decorative or
functional coating applied onto the surface of large appliances
or to the constituent metal parts (including, but not limited to,
doors, cases, lids, panels, and Interior support parts) of large
appliances.
(Source: Added at
Ill. Reg.
_____,
effective
____________)
Section 211.3290 Large Appliance Coating Line
“Large appliance coating line” means a coating line in which any
protective, decorative, or functional coating is applied onto the
surface of large appliances or to the constituent metal parts
(including but not limited to doors, cases, lids, panels and
interior parts) of large appliances.
(Source: Added at
Ill. Peg.
_____,
effective
____________
Section 211.3310 Light Liquid
“Light liquid” means VON in the liquid state which is not defined
as heavy liquid.
(Source: Added at
Ill. Peg.
_____,
effective
___________
Section 211.3330 Light-Duty Truck
“Light—duty truck” means any motor vehicle with a gross vehicle
weight rating of 3,850 kg or less, designed mainly to transport
property.
(Source: Added at
Ill. Req.
_____,
effective
Section 211.3350 Light Oil
01 1~0-01.77

70
“Light oil” means a liquid condensed or absorbed from coke oven
gas composed of benzene, toluene, and xylene.
(Source: Added at
Ill. Req.
_____,
effective
___________-
Section 211.3370 Liquid/Gas Method
“Liquid/gas method” means either of two methods for determining
VOM capture efficiency which require both gas phase and liquid
phase measurements and analysis. The first method requires
construction of a temporary total enclosure (TTE) to ensure that
all would—be fugitive emissions are measured. The second method
uses the building or room which houses the coating line, printing
line or other emission unit as an enclosure. The second method
requires that all other VON lines or emission units within the
room be shut down while the test is performed, but all fans and
blowers within the room must be operated according to normal
procedures.
(Source: Added at
Ill. Reg.
_____,
effective
___________)
Section 211.3390 Liquid-Mounted Seal
“Liquid—mounted seal” means a primary seal mounted in continuous
contact with the liquid between the tank wall and the floating
roof edge around the circumference of the roof.
(Source: Added at
Ill. Req.
_____,
effective
____________
Section 211.3410 Liquid Service
“Liquid service” means that the equipment or component contains
process fluid that is in a liquid state at operating conditions.
(Source: Added at
Ill. Req.
_____,
effective
____________
Section 211.3430 Liquids Dripping
“Liquids dripping” means any visible leaking from a seal
including spraying, misting, clouding and ice formation.
(Source: Added at
Ill. Req.
_____,
effective
____________/
Section 211.3450 Lithographic Printing Line
“Lithographic printing line” means a web or sheetfed printing
line in which each roll printer uses a roll where both the image
and non—image areas are essentially in the same plane
(planograpliic).
(Source: Added at
Ill. Req.
_____,
effective
01 L~0-0~78

71
Section 211.3470 Load-Out Area
“Load—out area” means any area where grain is transferred from
the grain-handling operation to any vehicle for shipment or
delivery.
(Source: Added at
Ill. Req.
_____,
effective
___________
Section 211.3490 Low Solvent Coating
“Low solvent coating” means a coating which contains less organic
solvent than the conventional coatings used by the industry. Low
solvent coatings include water—borne, higher solids,
electro—deposition and powder coatings.
(Source: Added at
Ill. Req.
_____,
effective
____________
Section 211.3510 Magnet Wire
“Magnet wire” means aluminum or copper wire which may
subsequently be used in an electromagnetic device.
(Source: Added at
Ill. Req.
_____,
effective
____________
Section 211.3530 Magnet Wire Coating
“Magnet wire coating” means any electrically insulating varnish
or enamel or other protective, decorative or functional coating
applied onto the surface of magnet wire.
(Source: Added at
Ill. Req.
effective
Section 211.3550 Magnet Wire Coating Line
“Magnet wire coating line” means a coating line in which any
electrically insulating varnish or enamel or other protective,
decorative, or functional coating is applied onto the surface of
magnet wire.
(Source: Added at
Ill. Req.
effective
Section 211.3570 Malor Dump Pit
“Malor dump pit” means any dump pit with an annual grain
through—put of more than 300,000 bushels, or which receives more
than 40 of the annual grain through-put of the grain-handling
operation.
(Source: Added at
Ill. Req.
_____,
effective
Section 211.3590 Malor Metropolitan Area (MMA)
o I ~o-Qt.479

72
“Nalor Metropolitan Area
(MMA)”
means any countY or group of
counties_which is defined by the following Table:
MAJOR METROPOLITAN AREAS IN ILLINOIS
(MMA’s)
COUNTIES INCLUDED IN NMA
Champaign-Urbana
Champaign
Chicago
Cook, Lake, Will, DuPaqe,
McHenry, Kane, Grundy~
Kendall, Kankakee
Decatur
Macon
Peoria
Peoria, Tazewell
Rockford
Winnebago
Rock Island
Moline
Rock Island
Springfield
Sangamon
St. Louis (Illinois)
St. Clair, Madison
Bloomington
Normal
McLean
(Source: Added at
Ill. Req.
_____,
effective
____________)
Section 211.3610 Malor Population Area (MPA)
“Malor Population Area (MPA)” means areas of inalor population
concentration in Illinois, as described below:
The area within the counties of Cook; Lake; DuPacie;
Will; the townships of Burton, Richmond, McHenry,
Greenwood, Nunda, Door, Algonquin, Grafton and the
municipality of Woodstock, plus a zone extending two
miles beyond the boundary of said municipality located
in McHenrv County; the townships of Dundee, Rutland,
Elgin, Plato, St. Charles, Campton, Geneva, Blackberry,
Batavia, Sugar Creek and Aurora located in Kane County;
and the municipalities of Kankakee, Bradley and
Bourbonnais, plus a zone extending two miles beyond the
boundaries of said municipalities in Kankakee County.
The area within the municipalities of Rockford and
Loves Park, plus a zone extending two miles beyond the
boundaries of said municipalities.
The area within the municipalities of Rock Island,
Noline, East Moline, Carbon Cliff, Milan, Oak Grove,
Sibyls, Hampton, Greenwood and Coal Valley, plus a zone
extending two miles beyond the boundaries of said
municipalities.
The area within the municipalities of Galesburci and
East Galesburg, ~1us a zone extending two miles beyond
the boundaries of said municipalities.
01 ~0-0L~8O

73
The area within the municipalities of Bartonville,
Peoria and Peoria Heights, plus a zone extending two
miles beyond the boundaries of said municipalities.
The area within the municipalities of Pekin, North
Pekin, Marquette Heights, Creve Coeur and East Peoria,
plus a zone extending two miles beyond the boundaries
of said municipalities.
The area within the municipalities of Bloomington and
Normal, plus a zone extending two miles beyond the
boundaries of said municipalities.
The area within the municipalities of Champaign, Urbana
and Savoy, plus a zone extending two miles beyond the
boundaries of said municipalities.
The area within the municipalities of Decatur, Mt.
Zion, Harristown and Forsyth, plus a zone extending two
miles beyond the boundaries of said municipalities.
The area within the municipalities of Springfield,
Leland Grove, Jerome, Southern View, Grandview, Sherman
and Chatham, plus a zone extending two miles beyond the
boundaries of said municipalities.
The area within the townships of Godfrey, Foster, Wood
River, Fort Russell, Chouteau, Edwardsville, Venice,
Nameoki, Alton, Granite City and Collinsville located
in Madison County; and the townships of Stites,
Canteen, Centreville, Caseyville, St. Clair, Sugar Loaf
and Stookey located in St. Clair County.
(Source: Added at
Ill. Req.
_____,
effective
____________)
Section 211.3630 Manufacturing Process
“Manufacturing process” means a method whereby a process emission
unit or series of process emission units is used to convert raw
materials, feed stocks, subassemblies, or other constituent parts
into a product, either for sale or for use in a subsequent
manufacturing process.
(Source: Added at
Ill. Peg.
_____,
effective
____________)
Section 211.3650 Marine Terminal
“Marine terminal” means a facility primarily engaged in loading
and unloading watercraft.
(Source: Added at
Ill. Req.
_____,
effective
01 ~0-0t~8I

74
Section 211.3670 Material Recovery Section
“Material recovery section” means, with respect to manufacture of
polystyrene resin, any equipment designed to transport and
recover styrene monomer and other impurities from other products
and by-products in a polystyrene plant, including but not limited
to the styrene devolatizer unit and stvrene recovery unit.
(Source: Added at
Ill. Peg.
_____,
effective
____________)
Section 211.3690 Maximum Theoretical Emissions
“Maximum theoretical emissions” means the quantity of volatile
organic material emissions that theoretically could be emitted by
a stationary source before add—on controls based on the design
capacity or maximum production capacity of the source and 8760
hours per year. The design capacity or maximum production
capacity includes use of coating(s) or ink(s) with the highest
volatile organic material content actually used in practice by
the source, provided, however, the Agency shall, when
appropriate, and upon request by the permit applicant, limit the
“maximum theoretical emissions” of a source by the imposition of
conditions in a federally enforceable operating permit for such
source. Such conditions shall not be inconsistent with
requirements of the Clean Air Act, as amended, or any applicable
requirements established by the Board. Such conditions shall be
established in place of design capacity or maximum production
capacity in calculating the “maximum theoretical emissions” for
such source and may include, among other things, the
establishment of production limitations, capacity limitations, or
limitations on the volatile organic material content of coatings
or inks, or the hours of operation of any emission unit, or a
combination of any such limitations. Production or capacity
limitations shall be established on a basis of no longer than one
month except in those cases where a limit spanning a longer
period of time is appropriate. In such cases, a limit or
limitation must not exceed an annual limit rolled on a basis of
at most a month; that is, for example, a monthly production or a
capacity level must be determined for each parameter subiect to a
production or capacity limitation and added to the eleven prior
monthly levels for monthly comparison with the annual limit. Any
production or capacity limitations shall be verified through
appropriate recordkeeping.
(Board Note: The USEPA may deem operating permits which do not
conform to the operating permit program requirements and the
requirements of USEPA’s underlying regulations, including the
requirement that limitations be quantifiable and enforceable as a
practical matter, not “federally enforceable.”)
(Source: Added at
Ill. Req.
_____,
effective
___________)
UI ~U-UL1!82

75
Section 211.3710 Metal Furniture
“Metal furniture” means a furniture piece including, but not
limited to, tables, chairs, waste baskets, beds, desks, lockers,
benches, shelving, file cabinets, lamps, and room dividers made
in whole or in part of metal.
Ill. Req.
effective
Metal Furniture Coating
(Source:
Section
Added at
211.3730
“Metal furniture coating” means any protective, decorative or
fiir~1
coatina ~
-~-~1~-~
the surface of any metal
furniture or any metal part which will be assembled with other
metal, wood, fabric, plastic or glass parts to form metal
furniture. However, an adhesive is not a metal furniture
coating.
(Source: Added at
Ill. Req.
_____/
effective
Section 211.3750 Metal Furniture Coating Line
“Metal furniture coating line” means a coating line in which any
protective, decorative, or functional coating is applied onto the
surface of any metal furniture or any metal part which will be
assembled with other metal, wood, fabric or glass parts to form
metal furniture. However, application of an adhesive is not a
metal furniture coating line or part of a metal furniture coating
line.
(Source: Added at
Ill. Req.
_____/
effective
___________)
Section 211.3770 Metallic Shoe—Type Seal
“Metallic shoe—type seal” means a primary or secondary seal
constructed of metal sheets (shoes) which are loined together to
form a ring, springs or levers which attach the shoes to the
floating roof and hold the shoes against the tank wall, and a
coated membrane which is suspended from the shoes to the floating
roof.
(Source: Added at
Ill. Req.
_____/
effective
___________)
Section 211.3790 Miscellaneous Fabricated Product
Manufacturing Process
“Miscellaneous fabricated product manufacturing process” means:
A’ manufacturing process involving one or more of the
following applications, including any drying and curing
of formulations, and capable of emitting VON:
UI ~4O-QL~83

76
Adhesives to fabricate or assemble parts or
products;
Asphalt solutions to paper or fiberboard;
Asphalt to paper or felt;
Coatings or dye to leather;
Coatings to plastic;
Coatings to rubber or glass;
Disinfectant material to manufactured items;
Plastic foam scrap or “fluff” from the manufacture
of foam containers and packaging material to form
resin pellets;
Resin solutions to fiber substances;
Rubber solutions to molds or
Viscose solutions for food casings.
The storage and handling of formulations associated
with the process described above and the use and
handling of organic liquids and other substances for
clean—up operations associated with the process
described in this definition would be included.
(Source: Added at
Ill. Req.
_____,
effective
____________)
Section 211.3810 Miscellaneous Formulation Nanufacng
Process
“Miscellaneous formulation manufacturing process” means:
A manufacturing process which compounds one or more of
the following and is capable of emitting VOM:
Adhesives;
Asphalt solutions;
Caulks, sealants, or waterproofing agents;
Coatings, other than paint and ink;
Concrete curing compounds;
Dyes
0 I~0-0’~6~

77
Friction materials and compounds;
Resin solutions;
Rubber solutions or
Viscose solutions.
The storage and handling of formulations associated
with the process described above, and the use and
handling of organic liquids and other substances for
clean—up operations associated with the process
described in this definition would be included.
(Source: Added at
Ill. Req.
_____
,
effective
____________
Section 211.3830 Miscellaneous Metal Parts and Products
“Miscellaneous metal Parts and products” for the purpose of 35
Ill. Adm. Code 215. Subpart F, shall include farm machinery,
garden machinery, small appliances, commercial machinery,
industrial machinery, fabricated metal products and any other
industrial category in which metal parts or products under the
Standard Industrial Classification Code for Nalor Groups 33, 34,
35, 36, 37, 38 or 39 are coated, with the exception of the
following: coating lines sublect to 35 Ill. Adm. Code 215.204(a)
through (i~ and (k), architectural coatings, automobile or
light-duty truck refinishing, the exterior of marine vessels and
the customized to~coating of automobiles and trucks if
production is less than thirty-five vehicles per day.
(Source: Added at
Ill. Peg.
_____/
effective
____________)
Section 211.3850 Miscellaneous Metal Parts~pd Products
Coating
“Miscellaneous metal parts and products coating” means, for
purposes of 35 Ill. Adm. Code 218 and 219, any protective,
decorative or functional coating applied onto the surface of any
metal part or metal product, even if attached to or combined with
a nonmetal Part or product
~j Including but not limited to underbody anti-chip (e.g.,
underbody plastisol) automobile and light-duty truck
coatings
~ But not including the following coatings which are
subject to seParate regulations: can coatings, coil
c’oatings, metal furniture coatings, large appliance
coatings, magnet wire coatings, and prime coat, primer
surfacer coat, topcoat and final repair coat for
automobile and light-duty trucks; and
UI 1i.O-O1~85

78
~ Not including the following coatings: architectural
coatings, automobile or light-duty truck refinishing
coatings, coatings applied to the exterior of marine
vessels, coatings applied to the exterior of airplanes,
customized topcoat for automobiles and trucks if
production is less than 35 vehicles per day, and high
temperature aluminum coating applied to diesel—electric
locomotives in Cook County.
(Source: Added at
Ill. Req.
_____/
effective
___________)
Section 211.3870 Miscellaneous Metal Parts or Products Coating
Line
“Miscellaneous metal parts or products coating line” means, for
purposes of 35 Ill. Adm. Code 218 and 219, a coating line in
which any protective, decorative, or functional coating is
applied onto the surface of any metal part or metal product, even
if attached to or combined with a nonmetal part or product
~j Including but not limited to underbody anti-chip (e.g.,
underbody plastisol) automobile and light-duty truck
coatings
~j But not including the following coatings which are
sublect to separate regulations: can coatings, coil
coatings, metal furniture coatings, large appliance
coatings, magnet wire coatings, and prime coat, primer
surfacer coat, topcoat and final repair coat for
automobile and light-duty trucks; and
gj Not including the following coatings: architectural
coatings, automobile or light-duty truck refinishing
coatings, coatings applied to the exterior of marine
vessels, coatings applied to the exterior of airplanes,
customized topcoat for automobiles and trucks if
production is less than 35 vehicles per day, and high
temperature aluminum coating applied to diesel—electric
locomotives in Cook County.
(Source: Added at
Ill. Reg.
_____,
effective
____________)
Section 211.3890 Miscellaneous Organic Chemical Manufacturing
Process
“Miscellaneous organic chemical manufacturing process” means:
A manufacturing process which produces1 by chemical
reaction, one or more of the following organic
compounds or mixtures of organic compounds and which is
capable of emitting volatile organic material (VOM):
Ot~Q0~86

79
Chemicals listed in Appendix A of 35 Ill. Adm.
Code 215, 218 or 219, as applicable;
Chlorinated and sulfonated compounds;
Cosmetic, detergent, soap, or surfactant
intermediaries or specialties and products;
Disinfectants;
Food additives;
Oil and petroleum product additives;
Plasticizers~
Resins or polymers;
Rubber additives;
Sweeteners or
Varnishes.
The storage and handling of formulations associated
with the process described above and the use and
handling of organic liquids and other substances for
clean—up operations associated with the process
described in this definition would be included.
(Source: Added at
Ill. Peg.
,
effective
___________
Section 211.3910 Mixing Operation
“Mixing operation” means the operation of combining two or more
ingredients, of which at least one is a grain.
(Source: Added at
Ill. Req.
_____,
effective
____________)
Section 211.3930 Monitor
“Monitor” means to measure and record.
(Source: Added at
Ill. Req.
,
effective
___________
Section 211.3970 Multiple Package Coating
“Multiple package coating” means a coating made from more than
one different ingredient which must be mixed prior to using and
has a limited pot life due to the chemical reaction which occurs
upon mixing.
01 i40-QLe87

80
(Source: Added at
Ill. Peg.
_____/
effective
____________)
Section 211.3990 New Grain-Drying Operation
“New grain—drying operation” means any grain—drying operation the
construction or modification of which commenced on or after June
30, 1975.
(Source: Added at
Ill. Reg.
_____/
effective
____________
Section 211.4010 New Grain-Handling Operation
“New grain—handling operation” means any grain-handling operation
the construction or modification of which commenced on or after
June 30, 1975.
(Source: Added at
Ill. Req.
_____,
effective
____________
Section 211.4030 No Detectable Volatile Organic Material
Emissions
“No detectable volatile organic material emissions” means a
discharge of volatile organic material into the atmosphere as
indicated by an instrument reading of less than 500 ppm above
background as determined in accordance with 40 CFR 60.485(c)
(incorporated by reference in 35 Ill. Adm. Code 215.105, 218.112,
and 219.112).
(Source: Added at
Ill. Peg.
_____,
effective
____________
Section 211.4050 Non-contact Process Water Cooling Tower
“Non—contact process water cooling tower” means a towerlike
device in which water is cooled by contact with atmospheric air
and evaporation, where such water has been or will be used for
cooling of a process stream where VON is present without
intentional direct contact of the cooling water and process
stream.
(Source: Added at
Ill. Reg.
_____,
effective
____________
Section 211.4070 Offset
“Offset” means, with respect to printing, use of a blanket
cylinder to transfer ink from the plate cylinder to the surface
to be printed.
(Source: Added at
Ill. Peg.
_____,
effective
____________)
Section 211.4090 One Hundred Percent Acid
“One hundred percent acid” means, with respect to sulfuric and
01 ~O-0~88

81
nitric acids, acid with a specific gravity of 1.8205 at 30°C in
the case of sulfuric acid and 1.4952 at 30° C in the case of
nitric acid.
(Source: Added at
Ill. Peg.
_____,
effective
____________
Section 211.4110 One-Turn Storage SPace
“One—turn storage space” means that space used to store grain
with a total annual through-put not in excess of the total bushel
storage of that space.
(Source: Added at
Ill. Req.
_____/
effective
___________
Section 211.4130 Opacity
“Opacity” means a condition which renders material partially or
wholly impervious to transmittance of light and causes
obstruction of an observer’s view. For the purposes of these
regulations, the following equivalence between opacity and
Ringelmann shall be employed:
Opacity Percent
Ringelmann
100
5.
(Source: Added at
Ill. Req.
_____,
effective
____________)
Section 211.4150 Opaque Stains
“Opaque stains” means all stains that are not semi—transparent
stains.
(Source: Added at
Ill. Peg.
_____,
effective
___________
Section 211.4170 Open Top Vapor Degreasing
“Open to~vapor degreasing” means the batch process of cleaning
and removing soils from surfaces by condensing hot solvent vapor
on the colder metal parts.
(Source: Added at
Ill. Req.
_____,
effective
____________)
Section 211.4190 Open—Ended Valve
“Open—ended valve” means any valve, except pressure relief
0li~00i489

82
devices, having one side of the valve in contact with process
fluid and one side open to the atmosphere, either directly or
through open Piping.
(Source: Added at
Ill. Peg.
_____/
effective
___________
Section 211.4210 Operator of a Gasoline Dispensing Operation
or Operator of a Gasoline Dispensing Facility
“Operator of gasoline dispensing operation” or “Operator of a
gasoline dispensing facility” means any person who is the lessee
of or operates, controls or supervises a gasoline dispensing
operation or a gasoline dispensing facility.
(Source: Added at
Ill. Req.
_____,
effective
____________)
Section 211.4230 Organic Compound
“Organic compound” means any compound of carbon, excluding carbon
monoxide, carbon dioxide, carbonic acid, metallic carbides or
carbonates, and ammonium carbonate.
(Source: Added at
Ill. Reg.
_____,
effective
___________
Section 211.4250 Organic Material and Organic Materials
~j “Organic materials” means, for the purposes of Section
9.4 of the Act, any chemical compound of carbon,
including diluents and thinners which are liquids at
standard conditions and which are used as dissolvers,
viscosity reducers or cleaning agents, including
polychlorinated dibenzo-p-dioxins, polychlorinated
dibenzofurans and ~olvnuclear aromatic hydrocarbons but
excluding methane, carbon monoxide, carbon dioxide,
carbonic acid, metallic carbonic acid, metallic
carbide, metallic carbonates and ammoniun carbonate are
not organic materials.
~j “Organic material” means, for the purpose of 35 Ill.
Adin. Code 215, 218 and 219, any chemical compound of
carbon including diluents and thinners which are
liquids at standard conditions and which are used as
dissolvers, viscosity reducers, or cleaning agents, but
excluding methane, carbon monoxide, carbon dioxide,
carbonic acid, metallic carbonic acid, metallic
carbide, metallic carbonates, and ammonium carbonate.
(Source: Added at
Ill. Req.
_____/
effective
____________)
Section 211.4270 Organic Vapor
01 i40~0!.~90

83
“Organic vp~or”means the gaseous phase of an organic material or
a mixture of organic materials present in the atmosphere.
(Source: Added at
Ill. Req.
_____,
effective
____________
Section 211.4290 Oven
“Oven” means, with respect to a coating line or printing line, a
chamber within which heat is used for one or more of the
following purposes: dry, bake, cure, or polymerize p coating or
ink.
(Source: Added at
Ill. Req.
,
effective
____________
Section 211.4310 Overall Control
“Overall control” means the product of the capture efficiency and
the control device efficiency.
(Source: Added at
Ill. Peg.
_____,
effective
___________)
Section 211.4330 Overvarnish
“Overvarnish” means a transparent coating applied directly over
ink or coating.
(Source: Added at
Ill. Req.
_____,
effective
____________
Section 211.4350 Owner of a Gasoline Dispensing Operation or
Owner of a Gasoline Dispensing Facility
“Owner of a gasoline dispensing operation” or “Owner of a
gasoline dispensing facility” means any person who has legal or
equitable title to a stationary storage tank at a gasoline
dispensing operation.
(Source: Added at
Ill. Peg.
_____,
effective
____________)
Section 211.4370 Owner or Operator
“Owner or operator” means any person who owns, operates, leases,
controls, or supervises a source, an emission unit or air
pollution control equipment.
(Source: Added at
Ill. Req.
_____/
effective
___________
Section 211.4390 Packaging Rotogravure Printing
“Packaging rotogravure printing” means rotogravure Printing
U~Ofl
paper. paper board, metal foil, plastic film, and other
substrates, which are, in subsequent operations, formed into
packaging Products or labels for articles to be sold.

84
(Source: Added at
Ill. Req.
_____,
effective
_______
Section 211.4410 Packaging Rotogravure Printing Line
“Packaging rotogravure Printing line” means a rotogravure
printing line performing packaging rotogravure printing.
(Source: Added at
Ill. Reg.
_____,
effective
____________)
Section 211.4430 Pail
“Pail” means any cylindrical shipping container of 1 to 12—gallon
capacity and constructed of 29—gauge and heavier material.
(Source: Added at
Ill. Peg.
_____,
effective
___________
Section 211.4450 Paint Manufacturing Source or Paint
Manufacturing Plant
“Paint manufacturing source” or “Paint manufacturing plant” means
a source that mixes, blends, or compounds enamels, lacquers,
sealers, shellacs, stains, varnishes, or pigmented surface
coatings.
(Source: Added at
Ill. Peg.
_____,
effective
____________
Section 211.4470 Paper Coating
“Paper coating” means any protective, decorative or functional
coating applied on paper, plastic film, or metallic foil to make
certain products, including but not limited to adhesive tapes and
labels, book covers, post cards, office copier paper, drafting
paper, or pressure sensitive tapes. For purposes of 35 Ill. Adm.
Code 218 and 219, paper coating includes coatings applied by
impregnation or saturation.
(Source: Added at
Ill. Reg.
_____,
effective
____________)
Section 211.4490 Paper Coating Line
“Paper coating line” means a coating line in which any
protective, decorative, or functional coating is applied on,
saturated into, or impregnated into paper, plastic film, or
metallic foil to make certain products, including but not limited
to adhesive tapes and labels, book covers, post cards, office
copier paper, drafting paper and pressure sensitive tapes. For
purposes of 35 Ill. Adm. Code 218 and 219, a paper coating line
includes saturation or impregnation.
(Source: Added at
Ill. Req.
_____,
effective
Section 211.4510 Particulate Matter
B I ~0-0~92

85
“Particulate matter” means any solid or liquid material, other
than water, which exists in finely divided form.
(Source: Added at
Ill. Req.
_____,
effective
____________)
Section 211.4530 Parts Per Million (Volume) or PPM (Vol)
“Parts per million (volume)” or “PPM (vol)” means a volume/volume
ratio which expresses the volumetric concentration of gaseous air
contaminant in a million unit volume of gas.
(Source: Added at
Ill. Peg.
_____,
effective
___________)
Section 211.4550 Person
“Person” means any individual; corporation; partnership; firm;
association; trust; estate; public or private institution; group;
state; municipality; political subdivision of a state; any
agency. department, or instrumentality of the United States; and
any officer, agent, or employee of any of the above.
(Source: Added at
Ill. Req.
_____,
effective
___________)
Section 211.4590 Petroleum
“Petroleum” means the crude oil removed from the earth and the
oils derived from tar sands, shale, and coal.
(Source: Added at
Ill. Peg.
_____,
effective
____________
Section 211.4610 Petroleum Liquid
“Petroleum liquid” means crude oil, condensate or any finished or
intermediate product manufactured at a petroleum refinery, but
not including Number 2 through Number 6 fuel oils as specified in
ASTM D-396-69 (incorporated by reference in 35 Ill. Adm. Code
218.112 and 219.112), gas turbine fuel oils Numbers 2-GT through
4-GT as specified in ASTM D-2880-7l (incorporated by reference in
Sections 218.112 and 219.112) or diesel fuel oils Numbers 2—D and
4-D, as specified in ASTM D-975-68 (incorporated by reference in
35 Ill. Adm. Code 218.112 and 219.112).
(Source: Added at
Ill. Req.
_____/
effective
____________)
Section 211.4630 Petroleum Refinery
“Petroleum refinery” means any source engaged in producing
gasoline, kerosene, distillate fuel oils, residual fuel oils,
lubricants, or other products through distillation of petroleum,
or through redistillation, cracking, or reforming of unfinished
petroleum derivatives.
01 1~Q-0L~93

86
(Source: Added at
Ill. Req.
_____/
effective
Section 211.4650 Pharmaceutical
“Pharmaceutical” means any compound or mixture, other than food,
used in the prevention, diagnosis, alleviation, treatment, or
cure of disease in human and animal.
(Source: Added at
Ill. Req.
_____,
effective
____________
Section 211.4670 Pharmaceutical Coating Operation
“Pharmaceutical coating operation” means a device in which a
coating is applied to a pharmaceutical, including air drying or
curing of the coating.
(Source: Added at
Ill. Req.
_____,
effective
____________)
Section 211.4690 Photochemically Reactive Material
“Photochemically reactive material” means any organic material
with an aggregate of more than 20 percent of its total volume
composed of the chemical compounds classified below or the
composition of which exceeds any of the following individual
percentage composition limitations. Whenever any photochemically
reactive material or any constituent of any organic material may
be classified from its chemical structure into more than one of
the above groups of organic materials, it shall be considered as
a member of the most reactive group, that is, the group having
the least allowable percent of the total organic materials.
A combination of hydrocarbons, alcohols, aldehydes.
esters, ethers or ketones having an olefinic or
cyclo—olefinic types of unsaturation: 5 percent. This
definition does not apply to perchloroethylene or
trichboroethylene.
A combination of aromatic compounds with eight or more
carbon atoms to the molecule except ethylbenzene: 8
percent.
A combination of ethylbenzene, ketones having branched
hydrocarbon structures or toluene: 20 percent.
(Source: Added at
Ill. Req.
_____,
effective
____________
Section 211.4710 Pigmented Coatings
“Pigmented coatings” means opaque coatings containing binders and
colored pigments which are formulated to conceal the wood surface
either as an undercoat or topcoat.
31 ~Q-Q~9~

87
(Source: Added at
Ill. Req.
_____,
effective
____________)
Section 211.4730 Plant
“Plant” means, for purposes other than 35 Ill. Adm. Code 215, 218
and 219, all of the pollutant-emitting activities which belong to
the same industrial grouping, are located on one or more
contiguous or adjacent properties, and are under the control of
the same person (or persons under common control), except the
activities of any marine vessel. Pollutant-emitting activities
shall be considered as part of the same industrial grouping if
they bebon~to the same malor group (i.e.
,
which have the same
two-digit code) as described in the “Standard Industrial
Classification Manual,” 1987 (incorporated bY reference in 35
Ill. Adm. Code 218.112 and 219.112).
(Source: Added at
Ill. Req.
_____,
effective
___________)
Section 211.4750 Plasticizers
“Plasticizers” means substances added to a polymer composition to
soften and add flexibility to the product.
(Source: Added at
Ill. Req.
_____,
effective
____________)
Section 211.4770 PM—b
“PM—b” means particulate matter with an aerodynamic diameter
less than or equal to a nominal 10 micrometers, as measured bY
the applicable test methods specified by rule. Ambient air
concentrations for PM—1O are usually expressed in micrograms per
cubic meter (ug/m3).
(Source: Added at
Ill. Peg.
_____,
effective
___________
Section 211.4790 Pneumatic Rubber Tire Manufacture
“Pneumatic rubber tire manufacture” means the production of
pneumatic rubber tires with a bead diameter up to but not
including 20.0 inches and cross section dimension up to 12.8
inches, but not including specialty tires for antique or other
vehicles when produced on equipment separate from normal
production lines for passenger or truck tv~etires.
(Source: Added at
Ill. Req.
_____,
effective
___________
Section 211.4810 Polybasic Organic Acid Partial Oxidation
Manufacturing Process
“Polybasic organic acid partial oxidation manufacturing process”
means any process involving partial oxidation of hydrocarbons
with air to manufacture polybasic acids or their anhydrides. such
01 i~0-0t495

88
as maleic anhydride, phthalic anhydride, terephthalic acid,
isophthalic acid, trimelletic anhydride.
(Source: Added at
Ill. Req.
_____/
effective
_________
Section 211.4870 Polystyrene Plant
“Polystyrene plant” means any plant using styrene to manufacture
polystyrene resin.
(Source: Added at
Ill. Req.
_____,
effective
____________
Section 211.4890 Polystyrene Resin
“Polystyrene resin” means a substance consisting of styrene
polymer and additives which is manufactured at a polystyrene
plant.
(Source: Added at
Ill. Reg.
_____/
effective
____________)
Section 211.4910 Portable Grain-Handling Equipment
“Portable grain—handling equipment” means any equipment
(excluding portable grain dryers) that is designed and maintained
to be movable primarily for use in a non-continuous operation for
loading and unloading one—turn storage space and is not
physically connected to the grain elevator, provided that the
manufacturer’s rated capacity of the equipment does not exceed
10,000 bushels per hour.
(Source: Added at
Ill. Req.
_____/
effective
___________
Section 211.4930 Portland Cement Manufacturing Process
Emission Source
“Portland cement manufacturing process emission source” means any
items of process equipment or manufacturing processes used in or
associated with the production of portland cement, including, but
not limited to, a kiln, clinker cooler, raw mill system, finish
mill system, raw material dryer, material storage bin or system,
material conveyor belt or other transfer system, material
conveyor belt transfer point, bagging operation, bulk unloading
station, or bulk loading station.
(Source: Added at
Ill. Peg.
_____,
effective
____________)
Section 211.4950 Portland Cement Process or Portland Cement
Manufacturing Plant
“Portland cement process” or “Portland cement manufacturing
plant” means any facility or plant manufacturing portland cement
by either the wet or dry process.
O1L~O-O1496

89
(Source: Added at
Ill. Req.
_____,
effective
Section 211.4990 Power Driven Fastener Coating
“Power driven fastener coating” means the coating of nail,
staple, brad and finish nail fasteners where such fasteners are
fabricated from wire or rod of 0.0254 inch diameter or greater,
where such fasteners are bonded into coils or strips, such coils
and strips containing a number of such fasteners, which fasteners
are manufactured for use in power tools, and which fasteners must
conform with formal standards for specific uses established by
various federal and national organizations including Federal
Specification FF-N-105b of the General Services Administration
dated August 23, 1977 (does not include any later amendments or
editions; U.S. Army Armament Research and Development Command,
Attn: DRDAR-TST, Rock Island, IL 61201), Bulletin UN-25d of the
U.S. Department of Housing and Urban Development
-
Federal
Housing Administration dated September 5, 1973 (does not include
any later amendments or editions; Department of HUD, 547 W.
Jackson Blvd., Room 1005, Chicago, IL 60606), and the Model
Building Code of the Council of American Building Officials, and
similar standards. For the purposes of this definition, the
terms “brad” and “finish nail” refer to single leg fasteners
fabricated in the same manner as staples. The application of
coatings to staple, brad, and finish nail fasteners may be
associated with the incremental forming of such fasteners in a
cyclic or repetitious manner (incremental fabrication) or with
the forming of strips of such fasteners as a unit from a band of
wires (unit fabrication).
(Source: Added at
Ill. Req.
_____,
effective
____________)
Section 211.5030 Pressure Release
“Pressure release” means the emission of materials resulting from
system pressure being greater than set pressure of the pressure
relief device.
(Source: Added at
Ill. Req.
_____,
effective
____________
Section 211.5050 Pressure Tank
“Pressure tank” means a tank in which fluids are stored at a
pressure greater than atmospheric pressure.
(Source: Added at
Ill. Peg.
_____,
effective
____________
Section 211.5070 Prime Coat
“Prime coat” means the first of two or more coatings applied to a
substrate in a multiple coat operation.
01 ~~-O~97

90
(Source: Added at
Ill. Req.
_____,
effective
Section 211.5090 Primer Surfacer Coat
“Primer surfacer coat” means a coating used to touch up areas on
the surface of automobile or bight-duty truck bodies not
adequately covered by the prime coat before application of the
top coat. The primer surfacer coat is applied between the prime
coat and topcoat. An anti-chip coating applied to main body
p~rts (e.g., rocker panels, bottom of doors and fenders, and
leading edge of roof) is a primer surfacer coat. The primer
surfacer coat is also referred to as a “guide coat.”
(Source: Added at
Ill. Req.
_____,
effective
____________
Section 211.5110 Primer Surfacer Operation
“Primer surfacer operation” means the application area(s),
flashoff area(s) and oven(s) that are used to apply and dry or
cure primer surfacer coat on a single assembly line.
(Source: Added at
Ill. Req.
_____,
effective
____________
Section 211.5130 Primers
“Primers” means any coatings formulated and applied to substrates
to provide a firm bond between the substrate and subsequent
coats.
(Source: Added at
Ill. Req.
_____,
effective
____________)
Section 211.5150 Printing
“Printing” means the application of words, designs, pictures, or
other images to a substrate using ink.
(Source: Added at
Ill. Req.
_____,
effective
____________)
Section 211.5170 Printing Line
“Printing line” means an operation consisting of a series of one
or more roll printers and any associated roll coaters, drying
areas, and ovens wherein one or more coatings are applied, dried,
and/or cured.
(Source: Added at
Ill. Req.
_____,
effective
___________
Section 211. 5185 Process Emission Source
“Process emission source” means any stationary emission source
other than a fuel combustion emission unit or an incinerator.
O1L~O_0!49B

91
(Source: Added at
Ill. Req.
_____,
effective
Section 211.5190 Process Emission Unit
“Process emission unit1’ means any stationary emission unit other
than a fuel combustion emission unit or an incinerator.
(Source: Added at
Ill. Req.
_____,
effective
____________
Section 211.5210 Process Unit
“Process unit” means equipment and components assembled to
produce, as intermediate or final products, one or more
chemicals. A process unit can operate independently if supplied
with sufficient feed or raw materials and sufficient storage
facilities for the product. For purposes of Subpart Q of Parts
215, 218 and 219, a process unit must produce one or more of the
chemicals listed in Appendix A of 35 Ill. Adm. Code 215, 218 or
219, as applicable.
(Source: Added at
Ill. Reg.
_____,
effective
____________)
Section 211.5230 Process Unit Shutdown
“Process unit shutdown” means a work practice or operational
procedure that stops production from a process unit or part of a
process unit. An unscheduled work practice or operational
procedure that stops production from a process unit or part of a
process unit for less than 24 hours is not a process unit
shutdown. The use of spare equipment and components and
technically feasible bypassing of equipment and components
without stopping production is not a process unit shutdown.
(Source: Added at
Ill. Req.
_____/
effective
____________)
Section 211.5250 Process Weight Rate
“Process weight rate” means the actual weight or engineering
approximation thereof of all materials except liquid and gaseous
fuels and combustion air introduced into any process per hour.
For a cyclical or batch operation, the process weight rate shall
be determined by dividing such actual weight or engineering
approximation thereof by the number of hours of operation
excluding any time during which the equipment is idle. For
continuous processes, the process weight rate shall be determined
by dividing such actual weight or engineering approximation
thereof by the number of hours in one complete operation,
excluding any time during which the equipment is idle.
(Source: Added at
Ill. Req.
_____,
effective
_____
Section 211.5270 Production Equipment Exhaust System
01 L~OQt1!99

92
“Production equipment exhaust system” means a system for
collecting and directing into the atmosphere emissions of
volatile organic material from reactors, centrifuges, and other
process emission units.
(Source: Added at
Ill. Req.
effective
Section 211.5310 Publication Rotogravure Printing Line
“Publication rotogravure printing line” means a rotogravure
printing line printing upon parer which is subsequently formed
into books, magazines, catalogues, brochures, directories,
newspaper supplements or other types of non—packaging printed
materials.
(Source: Added at
Ill. Req.
effective
Section 211.5330 Purged Process Fluid
“Purged process fluid” means liquid or vapor from a process unit
that contains volatile organic material and that results from
flushing or cleaning the sample line(s) of a process unit so that
an uncontaminated sample may then be taken for testing or
analysis.
(Source: Added at
Ill. Req.
_____/
effective
Section 211.5350 Reactor
“Reactor” means a vat, vessel, or other device in which chemical
reactions take place.
(Source: Added at
Ill. Peg.
_____,
effective
____________
Section 211.5370 Reasonably Available Control Technology
(PACT)
“Reasonably available control technology (PACT)” means the lowest
emission limitation that an emission unit is capable of meetjnq
by the application of control technology that is reasonably
available considering technological and economic feasibility.
(Source: Added at
Ill. Req.
_____,
effective
____________)
Section 211.5410 Refiner
“Refiner” means any person who owns, leases, operates, controls,
or supervises a refinery.
(Source: Added at
Ill. Req.
_____/
effective
____________)
Section 211.5430 Refinery Fuel Gas
01 ~~-0500

93
“Refinery fuel gas” means any gas which is generated by a
petroleum refinery process unit and which is combusted at the
refinery, including any gaseous mixture of natural gas and fuel
gas.
(Source: Added at
Ill. Req.
_____,
effective
____________
Section 211.5450 Refinery Fuel Gas System
“Refinery fuel gas system” means a system for collection of
refinery fuel gas including, but not limited to, piping for
collecting tail gas from various process units, mixing drums and
controls, and distribution piping.
(Source: Added at
Ill. Req.
_____/
effective
____________)
Section 211.5470 Refinery Unit or Refinery Process Unit
“Refinery unit” or “Refinery process unit” means a set of
equipment which are a part of a basic process operation such as
distillation, hydrotreating, cracking, or reforming of
hydrocarbons.
(Source: Added at
Ill. Req.
_____/
effective
____________)
Section 211.5490 Refrigerated Condenser
“Refrigerated condenser” means a surface condenser in which the
coolant supplied to the condenser has been cooled by a mechanical
device, other than by a cooling tower or evaporative spray
cooling, such as refrigeration unit or steam chiller unit.
(Source: Added at
Ill. Req.
_____,
effective
____________)
Section 211.5510 Reid Vapor Pressure
“Reid vapor pressure” means the absolute vapor pressure of
volatile crude oil and volatile nonviscous petroleum liquids
except liquified petroleum gases as determined by the method
referenced in the Section where the term is used or by ASTM
D323-89 (if not referenced in the Section where the term is
used), incorporated by reference in 35 Ill. Adm. Code 218.112 and
219.112.
(Source: Added at
Ill. Req.
_____,
effective
___________
Section 211.5550 Repair Coat
“Repair coat” means, with respect to coating wood furniture,
coatings used to correct imperfections or damage to furniture
surface.
01
L~.Q-Q50

94
(Source: Added at
Ill. Peg.
_____,
effective
Section 211.5570 Repaired
“Repaired” means, for the purpose of Subpart 0 of 35 Ill. Adm.
Code 215, 218 and 219, that equipment or a component has been
adjusted, or otherwise altered, to eliminate a leak.
(Source: Added at
Ill. Req.
_____/
effective
____________)
Section 211.5590 Residual Fuel Oil
“Residual fuel oil” means fuel oils of grade No. 4, 5 and 6 as
specified in detailed requirements for fuel oils A.S.T.M.
D-396-69 (1971) incorporated by reference in 35 Ill. Adm. Code
218.112 and 219.112.
(Source: Added at
Ill. Req.
_____,
effective
____________
Section 211.5610 Restricted Area
“Restricted area” means the area within the boundaries of any
“municipality” as defined in the Illinois Municipal Code, plus a
zone extending one mile beyond the boundaries of any such
municipality having a population of 1000 or more according to the
latest federal census.
(Source: Added at
Ill. Req.
_____,
effective
____________)
Section 211.5630 Retail Outlet
“Retail outlet” means any gasoline dispensing operation at which
gasoline is sold or offered for sale for use in motor vehicles.
(Source: Added at
Ill. Req.
/
effective
____________)
Section 211.5650 Ringelmann Chart
“Ringelmann chart” means the chart published and described in the
Bureau of Nines, U.S. Department of Interior, Information
Circular 8333 (Revision of 1C7718) May 1, 1967, or any adaptation
thereof which has been approved by the Agency.
(Source: Added at
Ill. Req.
_____,
effective
____________)
Section 211.5670 Roadway
“Roadway” means any street, highway, road, alley, sidewalk,
parking lot’, airport, rail bed or terminal, bikeway, pedestrian
mall or other structure used for transportation purposes.
(Source: Added at
Ill. Req.
_____,
effective
0 I ~D-O502

95
Section 211.5690 Roll Coater
“Roll coater” means an apparatus used for roll coating.
(Source: Added at
Ill. Req.
_____,
effective
___________)
Section 211.5710 Roll Coating
“Poll coating” means a method of applying a coating to a moving
substrate by means of rotating hard rubber, elastomeric or metal
rolls.
(Source: Added at
Ill. Req.
_____/
effective
____________
Section 211.5730 Roll Printer
“Roll printer” means an apparatus used for roll printing.
(Source: Added at
Ill. Req.
_____,
effective
____________)
Section 211.5750 Roll Printing
“Poll printing” means the method of printing bY means of a series
of rolls, usually of hard rubber or metal, each with only partial
coverage.
(Source: Added at
Ill. Req.
_____,
effective
____________)
Section 211.5770 Rotogravure Printing
“Rotogravure printing” means roll printing in which the pattern
to be applied is recessed in the roll relative to the non-image
area.
(Source: Added at
Ill. Peg.
_____,
effective
____________)
Section 211.5790 Rotogravure Printing Line
“Rotogravure printing line” means a printing line performing
rotogravure printing.
(Source: Added at
Ill. Peg.
_____,
effective
_____________
Section 211.5810 Safety Relief Valve
“Safety relief valve” means a valve which is normally closed and
which is designed to open in order to relieve excessive pressures
within a vessel or pipe.
(Source: Added at
Ill. Req.
_____/
effective
____________)
Section 211.5830 Sandblasting
01
~Q-U503

96
“Sandblasting” means the use of a mixture of sand and air at high
pressures for cleaning and/or polishing any type of surface.
(Source: Added at
Ill. Req.
_____,
effective
____________
Section 211.5850 Sanding Sealers
“Sanding sealers” means any coatings formulated for and applied
to bare wood for sanding and to seal the wood for subsequent
application of varnish. To be considered a sanding sealer a
coating must be clearly labelled as such.
(Source: Added at
Ill. Req.
_____/
effective
____________)
Section 211.5870 Screening
“Screening” means separating material according to size by
pressing undersized material through one or more mesh surfaces
(screens) in series, and retaining oversized material on the mesh
surfaces (screens).
(Source: Added at
Ill. Peg.
_____,
effective
____________
Section 211.5890 Sealer
“Sealer” means a coating containing binders which seals wood
prior to the application of the subsequent coatings.
(Source: Added at
Ill. Req.
_____,
effective
____________
Section 211.5910 Semi-Transparent Stains
“Semi—transparent stains” means stains containing dyes or semi-
transparent pigments which are formulated to enhance wood qr~in
and change the color of the surface but not to conceal the
surface, including, but not limited to, sap stain, toner,
non—grain raising stains, pad stain, or spatter stain.
(Source: Added at
Ill. Req.
_____,
effective
____________)
Section 211.5930 Sensor
“Sensor” means a device that measures a physical quantity or the
change in a physical quantity such as temperature, pressure, flow
rate, PH, or liquid bevel.
(Source: Added at
Ill. Req.
_____
/
effective
_____________
Section 211.5950 Set of Safety Relief Valves
“Set of safety relief valves” means one or more safety relief
valves designed to open in order to relieve excessive pressures
o ~0-050~

97
in the same vessel or pipe.
(Source: Added at
Ill. Peg.
_____/
effective
_____________)
Section 211.5970 Sheet Basecoat
“Sheet basecoat” means a coating applied to metal when the metal
is in sheet form to serve as either the exterior or interior of a
can for either two—piece or three—piece cans.
(Source: Added at
Ill. Req.
_____,
effective
____________
Section 211.5990 Shotblasting
“Shotblasting” means the use of a mixture of any metallic or
non—metallic substance and air at high pressures for cleaning
and/or polishing any type of surface.
(Source: Added at
Ill. Req.
_____/
effective
_____________
Section 211.6010 Side-Seam Spray Coat
“Side—seam spray coat” means a can coating applied to the seam of
a three—piece can.
(Source: Added at
Ill. Req.
_____/
effective
_____________
Section 211.6030 Smoke
“Smoke” means small gas-borne particles resulting from incomplete
combustion, consisting predominately but not exclusively of
carbon, ash and other combustible material, that form a visible
plume in the air.
(Source: Added at
Ill. Req.
_____/
effective
____________)
Section 211.6050 Smokeless Flare
“Smokeless flare” means a combustion unit and the stack to which
it is affixed in which organic material achieves combustion by
burning in the atmosphere such that the smoke or other
particulate matter emitted to the atmosphere from such combustion
does not have an appearance density or shade darker that No. 1 of
the Ringlemann Char~
(Source: Added at
Ill. Req.
_____,
effective
_____________/
Section 211.6070 Solvent
“Solvent” means a liquid substance that is used to dissolve or
dilute another substance. This term includes, but is not limited
to organic materials used as dissolvers, viscosity reducers,
01 ~O-0505

98
degreasing agents, or cleaning agents.
(Source: Added at
Ill. Peg
effective
____________
Section 211.6090 Solvent Cleaning
“Solvent cleaning” means the process of cleaning soils from
surfaces by cold cleaning, open top vapor degreasing, or
conveyorized deqreasing.
(Source: Added at
Ill. Req.
_____,
effective
_____________)
Section 211.6130 Source
“Source” means any stationary source (or any group of stationary
sources that are located on one or more contiguous or adjacent
properties, and are under common control of the same person or
persons under common control) belonging to a single major
industrial grouping. For the purposes of defining “source,” a
stationary source or group of stationary sources shall be
considered part of a single industrial grouping if all of the
pollutant emitting activities at such source or group of sources
on contiguous or ad-lacent property belong to the same Major Group
(i.e., all have the same two-digit code) as described in the
Standard Industrial Classification Manual, 1987 (incorporated by
reference in 35 Ill. Adin. Code 218.112 and 219.112).
(Source: Added at
Ill. Req.
_____,
effective
_____________)
Section 211.6150 Specialty High Gloss Catalyzed Coating
“Specialty high gloss catalyzed coating” means commercial
contract finishing of material prepared for printers and
lithographers where the finishing process uses a solvent—borne
coating, formulated with a catalyst, in a quantity of no more
than 12,000 gallons/year as supplied, where the coating machines
are sheet fed and the coated sheets are brought to a minimum
surface temperature of 190°F, and where the coated sheets are to
achieve the minimum specular reflectance index of 65 measured at
a 60 degree angle with a gloss meter.
(Source: Added at
Ill. Req.
_____
,
effective
____________
Section 211.6190 Specialty Soybean Crushing Source
“Specialty soybean crushing source” means any hexane extraction
soybean crushing equipment using indirect steam heat in flash or
vapor desolventizers as the primary method of desolventizinq and
producing specialty solvent extracted soy flakes, grits or flour.
(Source: Added at
Ill. Req.
,
effective
_____________)
01 L~.Q-U506

99
Section 211.6210 Splash Loading
“Splash loading” means a method of loading a tank, railroad tank
car, tank truck, or trailer by use of other than a submerged
loading pipe.
(Source: Added at
Ill. Peg.
_____,
effective
_____________)
Section 211.6230 Stack
“Stack” means a flue or conduit, free—standing or with exhaust
port above the roof of the building on which it is mounted, by
which air contaminants are emitted into the atmosphere.
(Source: Added at
Ill. Req.
_____,
effective
_____________)
Section 211.6270 Standard Conditions
“Standard conditions” means a temperature of 70°Fand a pressure
of 14.7 psia.
(Source: Added at
Ill. Req.
_____,
effective
____________)
Section 211.6290 Standard Cubic Foot (scf)
“Standard cubic foot (scf)” means the volume of one cubic foot of
gas at standard conditions.
(Source: Added at
Ill. Req.
_____,
effective
____________
Section 211.6310 Start-Up
“Start—up” means the setting in operation of an emission unit for
any purpose.
(Source: Added at
Ill. Req.
_____,
effective
_____________)
Section 211.6330 Stationary Emission Source
“Stationary emission source” means an emission source which is
not self-propelled.
(Source: Added at
Ill. Peg.
____,
effective
____________
Section 211.6350 Stationary Emission Unit
“Stationary emission unit” means an emission unit which is not
self-propelled.
(Source: Added at
Ill. Peg.
_____,
effective
_____________
Section 211.6370 Stationary Source
Ut LO-Q507

100
“Stationary source” means any building, structure, facility, or
installation that emits or may emit any air pollutant.
(Source: Added at
Ill. Req.
_____,
effective
____________
Section 211.6390 Stationary Storage Tank
“Stationary storage tank” means any container of liquid or gas
which is designed and constructed to remain at one site.
(Source: Added at
Ill. Peg.
_____
,
effective
____________
Section 211.6410 Storage Tank or Storage Vessel
“Storage tank or storage vessel” means any tank, reservoir or
container used for the storage of liquid or gaseous material.
(Source: Added at
Ill. Peg.
_____,
effective
____________
Section 211.6430 Styrene Devolatilizer Unit
“Styrene devolatilizer unit” means equipment performing the
function of separating unreacted styrene monomer and other
volatile components from polystyrene in a vacuum devolatilizer.
(Source: Added at
Ill. Req.
_____,
effective
____________
Section 211.6450 Styrene Recovery Unit
“Styrene recovery unit” means equipment performing the function
of separating styrene monomer from other less volatile components
of the styrene devolatilizer unit’s output. The separated
stvrene monomer may be reused as a raw material in the
polystyrene plant.
(Source: Added at
Ill. Req.
_____,
effective
____________
Section 211.6470 Submerged Loading Pipe
~j “Submerged loading pipe” means, for purposes of 35 Ill.
Adm. Code 215, any loading Pipe the discharge opening
of which is entirely submerged when the liquid level is
6 inches above the bottom of the tank. When applied to
a tank which is loaded from the side, any loading pipe
the discharge of which is entirely submerged when the
liquid level is 18 inches or two times the loading pipe
diameter, whichever is greater, above the bottom of the
tank. The definition shall also ap~lvto any loading
pipe which is continuously submerged during loading
operations.
~j “Submerged loading pine” means, for purposes of 35 Ill.
01 L~Q-O503

101
Adm. Code 218 and 219, any discharge pipe or nozzle
which meets either of the following conditions:
fl Where the tank is filled from the top, the end of
the discharge pipe or nozzle must be totally
submerged when the liquid level is 15 cm (6 in.)
above the bottom of the tank.
~I Where the tank is filled from the side, the
discharge pipe or nozzle must be totally submerged
when the liquid level is 46 cm (18 in.) above the
bottom of the tank.
(Source: Added at
Ill. Req.
_____,
effective
_____________
Section 211.6490 Substrate
“Substrate” means the surface onto which a coating is applied or
into which a coating is impregnated.
(Source: Added at
Ill. Req.
_____/
effective
____________
Section 211.6510 Sulfuric Acid Mist
“Sulfuric acid mist” means sulfuric acid mist as measured
according to the method specified in 35 Ill. Adm. Code
214.101(b).
(Source: Added at
Ill. Peg.
_____,
effective
____________
Section 211.6530 Surface Condenser
“Surface condenser” means a device which removes a substance from
a gas stream by reducing the temperature of the stream, without
direct contact between the coolant and the stream.
(Source: Added at
Ill. Req.
_____/
effective
____________/
Section 211.6550 Synthetic Organic Chemical or Polymer
Manufacturing Plant
“Synthetic organic chemical or polymer manufacturing plant” means
a source that produces, as intermediates or final products,
chemicals or polymers.
(Source: Added at
Ill. Peg.
_____,
effective
_______
)
Section 211.6570 Tablet Coating Operation
“Tablet coating operation” means a pharmaceutical coating
operation in which tablets are coated.
01 t~~-U5Q9

102
(Source: Added at
Ill. Peg.
_____,
effective
Section 211.6590 Thirty-Day Rolling Average
“Thirty—day rolling average” means any value arithmetically
averaged over any consecutive thirty-days.
(Source: Added at
Ill. Req.
_____,
effective
_________
Section 211.6610 Three-Piece Can
“Three—piece can” means a can which is made from a rectangular
sheet and two circular ends.
(Source: Added at
Ill. Req.
_____,
effective
____________)
Section 211.6670 Topcoat
“Topcoat” means a coating applied to a substrate in a multiple
coat operation other than prime coat, primer surfacer coat or
final repair coat.
(Source: Added at
Ill. Reg.
effective
Section 211.6690 Topcoat Operation
“Topcoat operation” means the application area(s), flash-off
area(s), and oven(s) used to apply and dry or cure the topcoat
(except final off-line repair) on automobile or light-duty truck
bodies or body parts on a single assembly line.
(Source: Added at
Ill. Req.
effective
Section 211.6730 Transfer Efficiency
“Transfer efficiency”
~‘-~
the ratio of the amount of coating
solids deposited onto a part or product to the total amount of
coating solids used, during a particular time period.
(Source: Added at
Ill. Req.
_____,
effective
____________)
Section 211.6750 Tread End Cementing
“Tread end cementing” means the application of a solvent-based
cement to the tire tread ends.
(Source: Added at
Ill. Req.
_____,
effective
____________/
Section 211.6770 True Vapor Pressure
“True vapor pressure” means the equilibrium partial pressure
exerted by a volatile organic liquid as determined in accordance
01 ~tQ-Q510

103
with methods described in American Petroleum Institute Bulletin
2517, “Evaporation Loss From Floating Roof Tanks,” second
edition, February 1980 (incorporated by reference in 35 Ill. Adm.
Code 218.112 and 219.112)
(Source: Added at
Ill. Peg.
_____,
effective
____________
Section 211.6790 Turnaround
“Turnaround” means, with respect to a refinery process unit, the
procedure of shutting down an operating refinery unit, emptying
gaseous and liquid contents to do inspection, maintenance and
repair work, and putting the unit back into production.
(Source: Added at
Ill. Req.
_____/
effective
____________)
Section 211.6810 Two-Piece Can
“Two-piece can” means a can that consists of a body manufactured
i.e., drawn, from a single piece of metal and one top or end.
(Source: Added at
Ill. Peg.
_____/
effective
____________)
Section 211.6850 Undertread Cementing
“Undertread cementing” means the application of a solvent—based
cement to the underside of a tire tread.
(Source: Added at
Ill. Req.
_____/
effective
____________)
Section 211.6870 Unregulated Safety Relief Valve
“Unregulated safety relief valve” means a safety relief valve
which cannot be actuated by a means other than high pressure in
the pipe or vessel which it protects.
(Source: Added at
Ill. Req.
_____/
effective
____________)
Section 211.6890 Vacuum Producing System
“Vacuum producing system” means any reciprocating, rotary, or
centrifugal blower or compressor or any jet elector or device
that creates suction from a pressure below atmospheric and
discharges against a greater pressure.
(Source: Added at
Ill. Peg.
_____/
effective
____________)
Section 211.6910 Vacuum Service
“Vacuum service” means, for the purpose of Subpart p of this 35
Ill. Adm. Code 215, 218 and 219, equipment or a component which
is operating at an internal pressure that is at least 5 kPa (0.73
OkO-051 I

104
psia) below ambient pressure.
(Source: Added at
Ill. Req.
_____,
effective
Section 211.6930 Valves Not Externally Regulated
“Valves not externally regulated” means valves that have no
provision for external adjustment or governance during their
operation, such as in—line check valves.
(Source: Added at
Ill. Req.
,
effective
__________
Section 211.6950 Vapor Balance System
“Vapor balance system” means any combination of Pipes or hoses
which creates a closed system between the vapor spaces of an
unloading tank and a receiving tank such that vapors displaced
from the receiving tank are transferred to the tank being
unloaded.
(Source: Added at
Ill. Req.
_____/
effective
Section 211.6970 Vapor Collection System
“Vapor collection system” means all piping, seals, hoses,
connections, pressure-vacuum vents, and other components between
the gasoline delivery vessel and the vapor processing unit and/or
the storage tanks and vapor holder.
(Source: Added at
Ill. Req.
effective
Section 211.6990 Vapor Control System
“Vapor control system” means any system that limits or prevents
release to the atmosphere of organic material in the vapors
displaced from a tank during the transfer of gasoline or other
volatile organic liquid.
(Source: Added at
Ill. Req.
_____,
effective
____________
Section 211.7010 Vapor-Mounted Primary Seal
“Vapor—mounted primary seal” means a primary seal mounted with an
air space bounded by the bottom of the primary seal, the tank
wall, the liquid surface and the floating roof.
(Source: Added at
Ill. Peg.
_____,
effective
___________
Section 211’. 7030 Vapor Recovery System
“VaDor recovery system” means, with respect to a storage tank,
storing a volatile organic liquid, a vapor gathering system
01 Li.Q-05 12

105
capable of collecting all volatile organic material (VON) vapors
and gases discharged from the storage tank and a vapor disposal
system capable of processing such VOM vapors and gases so as to
prevent their emission to the atmosphere.
(Source: Added at
Ill. Req.
effective
Section 211.7070 Vinyl Coating
“Vinyl coating” means any protective, decorative or functional
coating or ink applied to vinyl or urethane or vinyl or urethane
coated fabric which is delivered to a coating line or printing
line as a roll, unwound and coated as a continuous substrate.
However, a plastisol is not a vinyl coating.
(Source: Added at
Ill. Req.
effective
Section 211.7090 Vinyl Coating Line
“Vinyl coating line” means a coating line in which any
protective, decorative or functional coating or ink is applied
onto vinyl or urethane or vinyl or urethane coated fabric which
is delivered to a coating line or printing line as a roll,
unwound and coated as a continuous substrate. However,
application of a plastisol to vinyl or urethane or vinyl or
urethane coated fabric is not a vinyl coating line or part of a
vinyl coating line.
(Source: Added at
Ill. Reg.
effective
Section 211.7110 Volatile Organic Liquid (VOL)
“Volatile organic liquid (VOL)” means any substance which is
liquid at storage conditions and which contains volatile organic
material.
(Source: Added at
Ill. Req.
_____/
effective
___________
Section 211.7130 Volatile Organic Material Content (VOMC)
“Volatile organic material content (VOMC)” means, for the purpose
of 35 Ill. Adm. Code 215, the emissions of volatile organic
material which would result from the exposure of a coating,
printing ink, fountain solution, tire spray, dry cleaning waste
or other similar material to the air, including any drying or
curing, in the absence of any control equipment. VONC is
typically expressed as kilogram (kg) VON/liter (lb VON/gallon) of
coating or coating solids, or kg VON/kg (lb VON/lb) of coating
solids, coating or material.
(Source: Added at
Ill. Reg.
_____,
effective
01 ~0-05 13

106
Section 211.7150 Volatile Organic Material (VOM) or Volatile
Organic Compound (VOC)
“Volatile organic material (VON)” or “Volatile organic compound
(VOC)” means any compound of carbon, excluding carbon monoxide,
carbon dioxide, carbonic acid, metallic carbides or carbonates,
and ammonium carbonate, which participates in atmospheric
photochemical reactions.
~j This includes any such organic compound other than the
following, which have been determined to have
negligible photochemical reactivity: Methane; ethane;
methylene chloride (dichlormethane),
1,l,1-trjchborethane (methyl chloroform);
b,1,1—trichloro—2,2,2—trjfluoroethane (CFC—ll3);
trichlorofluoromethane (CFC-ll);
dichlorodifluoromethane (CFC-l2); chlorodifluoromethane
(CFC-22); trifluoroinethane (FC—23); l,2-dichloro
1,1,2,2-tetrafluoroethane (CFC—l14);
cloropentafluoroethane (CFC-l15); 1,1, 1—trifluoro
2 ,2-dichboroethane (HCFC-123); 1,1, 12-tetrafluoroethane
(HFC-l34a); 1,l-dichloro 1-f luoroethane (HCFC-141b);
1-chloro 1, b-difluoroethane (HCFC-142b);
2-chloro-1,l, 1,2-tetrafluoroethane (HCFC-124);
pentafluoroethane (HFC-125); 1,1,2, 2-tetrafluoroethane
(HFC—134); 1,1,1—trifluoroethane (HFC—l43a);
1, 1—difluroethane (HFC-l52a); and perfluorocarbon
compounds which fall into these classes:
~j Cyclic, branched, or linear, completely
fluorinated alkanes
~j Cyclic, branched, or linear, completely
fluorinated ethers with nounsaturations
~j Cyclic, branched, or linear, completely
fluorinated tertiary amines with no unsaturations
and
4j Sulfur containing perfluorocarbons with no
unsaturations and with sulfur bonds only to carbon
and fluorine.
~j For purposes of determining VOM emissions and
compliance with emissions limits, VON will be measured
by the test methods in the approved implementation plan
or 40 CFR Part 60, Appendix A, incorporated by
reference at 35 Ill. Adm. Code 215.105, 218.112, and
219.112, as applicable or by source-specific test
methods which have been established Pursuant to a
permit issued pursuant to a program approved or
promulgated under Title V of the Clean Air Act or under
Ok0-U5I1~

107
40 CFR Part 51, Subpart I or Appendix S. incorporated
by reference at 35 Ill. Adm. Code 218.112 and 219.112
or under 40 CFR Part 52.21, incorporated by reference
at 35 Ill. Adm. Code 218.112 and 219.112, as
applicable. Where such a method also measures
compounds with negligible photochemical reactivity,
these negligibly-reactive compounds may be excluded as
VON if the amount of such compounds is accurately
quantified, and such exclusions is approved by the
Agency.
~j As a precondition to excluding these
negligibly-reactive compounds as VON or at any time
thereafter, the Agency may require an owner or operator
to provide monitoring or testing methods and results
demonstrating, to the satisfaction of the Agency, the
amount of negligibly—reactive compounds in the source’s
emissions.
~j The USEPA shall not be bound by any State determination
as to appropriate methods for testing or monitoring
negligibly-reactive compounds if such determination is
not reflected in any of the test methods in subsection
(b) above.
(Source: Added at
Ill. Req.
_____,
effective
___________
Section 211.7170 Volatile Petroleum Liquid
“Volatile petroleum liquid” means any petroleum liquid with a
true vapor pressure that is greater than 1.5 psia (78 millimeters
of mercury) at standard conditions.
(Source: Added at
Ill. Peg.
_____,
effective
Section 211.7190 Wash Coat
“Wash coat” means a coating containing binders which seals wood
surfaces, prevents undesired staining, and controls penetration.
(Source:
Added at
Ill. Peg.
_____,
effective
____________)
Section 211.7210 Wastewater (Oil/Water) Separator
“Wastewater (oil/water) separator” means any device or piece of
equipment which utilizes the difference in density between oil
and water to remove oil and associated chemicals from water, or
any device, such as a flocculation tank or a clarifier, which
removes petroleum derived compounds from waste water.
(Source:
Added at
Ill. Req.
_____,
effective
____________)
01 ~0-U5 IS

108
Section 211.7230 Weak Nitric Acid Manufacturing Process
“Weak nitric acid manufacturing process” means any acid producing
facility manufacturing nitric acid with a concentration of less
than 70 percent by weight.
(Source: Added at
Ill. Req.
_____,
effective
___________/
Section 211.7250
“Web” means a substrate which is coated or printed as a
continuous substrate after being unrolled from the roll in which
the substrate is delivered to a line.
(Source: Added at
Ill. Req.
_____,
effective
___________
Section 211.7270 Wholesale Purchase
-
Consumer
“Wholesale purchase
consumer” means any person or organization
that purchases or obtains gasoline from a supplier for ultimate
consumption or use in motor vehicles and receives delivery of
gasoline into a storage tank with a capacity of at least 2082
liters (550 gallons) owned and controlled by that person.
(Source: Added at
Ill. Req.
_____,
effective
___________
Section 211.7290 Wood Furniture
“Wood furniture” means room furnishings including cabinets
(kitchen, bath, and vanity), tables, chairs, beds, sofas,
shutters, art objects, wood paneling, wood flooring, and any
other coated furnishings made of wood, wood composition, or
fabricated wood materials.
(Source: Added at
Ill. Req.
_____,
effective
___________)
Section 211.7310 Wood Furniture Coating
“Wood furniture coating” means any protective, decorative or
functional coating applied to wood furniture or wood furniture
parts.
(Source: Added at
Ill. Req.
_____,
effective
___________)
Section 211.7330 Wood Furniture Coating Line
“Wood furniture coating line” means a coating line in which any
protective, decorative, or functional coating is applied to wood
furniture or wood furniture parts.
(Source: Amended at
Ill. Req.
______,
effective
_________)
01 ~Q-05l 6

109
Section 211.7350 Woodworking
“Woodworking” means the shaping, sawing, grinding, smoothing,
polishing and making into products of any form or shape of wood.
(Source: Added at
Ill. Req.
_____,
effective
___________)
üii~QO5t7

110
SUBTITLE B: AIR POLLUTION
CHAPTER I: POLLUTION CONTROL BOARD
SUBCHAPTER c: EMISSIONS STANDARDS AND LIMITATIONS
FOR STATIONARY SOURCES
PART 218
ORGANIC MATERIAL EMISSION STANDARDS ANO LIMITATIONS FOR THE
CHICAGO AREA
SUBPART A: GENERAL PROVISIONS
Section
218.100
218.101
218.102
218.103
218.104
218.105
218.106
218.107
218.108
218.109
218.110
218.111
218. 112
Introduction
Clcan-up and Di~po~alOpcration~Savings Clause
Abbreviations and Conversion Factors
Applicability
Definitions
Test Methods and Procedures
Compliance Dates
Operation of Afterburners
Exemptions, Variations, and Alternative Means of
Control or Compliance Determinations
Vapor Pressure of Volatile Organic Liquids
Vapor Pressure of Organic Material or Solvents
Vapor Pressure of Volatile Organic Material
Incorporations by Reference
SUBPART B: ORGANIC EMISSIONS FROM STORAGE AND LOADING OPERATIONS
Section
218. 121
218. 122
218. 123
218.124
218.125
218. 126
Storage Containers
Loading Operations
Petroleum Liquid Storage Tanks
External Floating Roofs
Compliance Dates (Repealed)
Compliance Plan (Repealed)
SUBPART C: ORGANIC EMISSIONS FROM MISCELLANEOUS EQUIPMENT
Separation Operations
Pumps and Compressors
Vapor B lowdown
Safety Relief Valves
Solvent Cleaning in General
Cold Cleaning
Open Top Vapor Degreasing
Conveyorized Degreasing
Section
218.141
218. 142
218. 143
218. 144
Section
218. 181
218.182
218. 183
218.184
SUBPART E: SOLVENT CLEANING
01
‘4O~J5I8

111
Emission Limitations for Manufacturing PlantG
Daily-Weighted Average Limitations
Solids Basis Calculation
Alternative Emission Limitations
Exemptions from Emission Limitations
Exemption from General Rule on Use of Organic Material
Compliance Schedule
Pecordkeepinq and Reporting
SUBPART G: USE OF ORGANIC MATERIAL
Use of Organic Material
Alternative Standard
Fuel Combustion Emission Sourcc~Units
Operations with Compliance Program
SUBPART H: PRINTING AND PUBLISHING
Flexographic and Rotogravure Printing
Applicability
Compliance Schedule
Recordkeepirig and Reporting
Heatset~Web~Offset Lithographic Printing
SUBPART Q: LEAKS FROM SYNTHETIC ORGANIC CHEMICAL AND POLYMER
MANUFACTURING EQUIPMENT PLANT
General Requirements
Inspection Program Plan for Leaks
Inspection Program for Leaks
Repairing Leaks
Recordkeeping for Leaks
Report for Leaks
Alternative Program for Leaks
Open-e~nded Valves
Standards for Control Devices
Compliance Date (Repealed)
SUBPART R: PETROLEUM REFINING AND RELATED INDUSTRIES;
ASPHALT MATERIALS
Section
218.441 Petroleum Refinery Waste Gas Disposal
0I~4OO5I9
Compliance Schedule (Repealed)
Test Methods
SUBPART F: COATING OPERATIONS
218.185
218.186
Sect ion
218.204
218. 205
218. 206
218.207
218.208
218.209
218.210
218. 211
Sect ion
218.301
218.302
218.303
218.304
Section
218.401
218.402
218. 403
218.404
218.405
Section
218.421
218.422
218.423
218.424
218.425
218.426
218.427
218.428
218.429
218. 430

112
218.442
218.443
218.444
218.445
218.446
218.447
218.448
218.449
218.450
218.451
218.452
218.453
Vacuum Producing Systems
Wastewater (Oil/Water) Separator
Process Unit Turnarounds
Leaks: General Requirements
Monitoring Program Plan for Leaks
Monitoring Program for Leaks
Recordkeepinq for Leaks
Reporting for Leaks
Alternative Program for Leaks
Sealing Device Requirements
Compliance Schedule for Leaks
Compliance Dates (Repealed)
SUBPART 5: RUBBER AND MISCELLANEOUS PLASTIC PRODUCTS
Section
218.461
218.462
218.463
218.464
218.465
218.466
Section
218.480
218.481
218.482
218.483
218.484
218.485
218.486
218.487
218 .488
218.489
Section
218.521
218.525
218.526
218.527
Section
218.541
Manufacture of Pneumatic Rubber Tires
Green Tire Spraying Operations
Alternative Emission Reduction Systems
Emission Testing
Compliance Dates (Repealed)
Compliance Plan (Repealed)
SUBPART T: PHARMACEUTICAL MANUFACTURING
Applicability of Subpart T
Control of Reactors, Distillation Units, Crystallizers,
Centrifuges and Vacuum Dryers
Control of Air Dryers, Production Equipment Exhaust
Systems and Filters
Material Storage and Transfer
In—Process Tanks
Leaks
Other Emission Sourccc Units
Testing
Monitoring and flccordkccping for Air Pollution Control
Equipment
Recordkeeping for Air Pollution Control Equipment
SUBPART V: AIR OXIDATION PROCESSES
Definitions (Repealed)
Emission Limitations for Air Oxidation Processes
Testing and Monitoring
Compliance Date (Repealed)
SUBPART W: AGRICULTURE
Pesticide Exception
01140-0520

113
SUBPART X: CONSTRUCTION
Paving Operations
Cutback Asphalt
Bulk Gasoline Plants
Bulk Gasoline Terminals
Gasoline Dispensing Facilitic~Qperations
Gasoline Delivery Vessels
Gasoline Volatility Standards
Gasoline Dispensing Sourcc~ Operations
Motor Vehicle
Fueling Operations
SUBPART Z: DRY CLEANERS
Perchloroethylene Dry Cleaners
Exemptions
Leaks
Compliance Dates (Repealed)
Compliance Plan (Repealed)
Exception to Compliance Plan (Repealed)
Standards for Petroleum Solvent Dry Cleaners
Operating Practices for Petroleum Solvent Dry Cleaners
Program for Inspection and Repair of Leaks
Testing and Monitoring
Exemption for Petroleum Solvent Dry Cleaners
Compliance Dates (Repealed)
Compliance Plan (Repealed)
SUBPART AA: PAINT AND INK MANUFACTURING
Applicability
Exemption for Waterbase Material and HeatsetzOff set Ink
Permit Conditions
Open-~~opMills, Tanks, Vats or Vessels
Grinding Mills
Storage Tanks
Leaks
Clean Up
Compliance Schedule
Recordkeeping and Reporting
Architectural Coatings
SUBPART Y: GASOLINE DISTRIBUTION
Section
218.561
218.562
218 .563
Section
218.581
218 .582
218.583
218.584
218.585
218.586
Section
218.601
218.602
218.603
218. 604
218.605
218.606
218. 607
218. 608
218. 609
218.610
218.611
218.612
218.613
Section
218.620
218.621
218.623
218.624
218.625
218. 626
218.628
218.630
218.636
218.637

114
SUBPART BB: POLYSTYRENE PLANTS
Section
218.875218.640 Applicability of Subpart BB
218.877218.642 Emissions Limitations at Polystyrene Plants
218.886218.644 Emissions Testing
218.875 Applicability of Subpart BB (Renumbered)
218.877 Emissions Limitation at Polystyrene Plants (Renumbered)
218.879 Compliance Date (Repealed)
218.881 Compliance Plan (Repealed)
218.883 Special Requirements for Compliance Plan (Repealed)
218.886 Emissions Testing (Renumbered)
SUBPART PP: MISCELLANEOUS FABRICATED PRODUCT MANUFACTURING
PROCESSES
Section
218.920 Applicability
218.923 Permit Conditions
218.926 Control Requirements
218.927 Compliance Schedule
218.928 Testing
SUBPART
QQ:
MISCELLANEOUS FORMULATION MANUFACTURING PROCESSES
Section
218.940 Applicability
218.943 Permit Conditions
218.946 Control Requirements
218.947 Compliance Schedule
218.948 Testing
SUBPART PR: MISCELLANEOUS ORGANIC CHEMICAL MANUFACTURING
PROCESSES
Section
218.960 Applicability
218.963 Permit Conditions
218.966 Control Requirements
218.967 Compliance Schedule
218.968 Testing
SUBPART TT: OTHER EMISSION SOURCES UNITS
Section
218.980 Applicability
218.983 Permit Conditions
218.986 Control Requirements
218.987 Compliance Schedule
218.988 Testing
01140-0522

115
SUBPART UU: RECORDKEEPING AND REPORTING FOR NON—CTC SOURCES
Section
218.990 Exempt Emission Sourcc~ Units
218.991 Subject Emission Sourcc~ Units
Section 218.AppcndixPPENDIX A:
List of Chemicals Defining
Synthetic Organic Chemical and
Polymer Manufacturing
Section 2l8.AppcndixPPENDIX B:
VOM Measurement Techniques for
Capture Efficiency
Section 2l8.AppcndixPPENDIX C:
Reference Methods and
Procedures
Section 218.AppcndixPPENDIX D:
Coefficients for the Total
Resource Effectiveness Index
(TRE) Equation
AUTHORITY: Implementing Section 10 and authorized by Section
28.5 of the Environmental Protection Act (Ill. Rev. Stat. 1991,
ch. l11~, par. 1010), (P.A. 87—1213, effective September 26,
1992) C4l5 ILCS 5/10 and 28.5
SOURCE: Adopted at P91—7 at 15 Ill. Peg. 12231, effective August
16, 1991; amended in P91-23 at 16 Ill. Req. 13564, effective
August 24, 1992; amended in P91—28 and P91—30 at 16 Ill. Req.
13864, effective August 24, 1992; amended in P93—9 at 17 Ill.
Peg.
—,
effective
_______________
SUBPART A: GENERAL PROVISIONS
Section 218.100
Introduction
a) This Part contains standards and limitations for
emissions of organic material and volatile organic
material from stationary sources located in the Chicago
area, which is comprised of Cook, DuPage, Kane, Lake,
NcHenry and Will Counties and Aux Sable Township and
Goose Lake Township in Grundy County and Oswego
Township in Kendall County.
b) Sources subject to this Part may be subject to the
following:
1) Permits required under 35 Ill. Adm. Code 2O1~-
~
2) Air quality standards under 35 Ill. Adm. Code
24 si-.
C)
This Part is divided into Subparts which are grouped as
follows:
01140-0523

116
1) Subpart A: General Provisionsj
2) Subparts B-F: Emissions from equipment and
operations in common to more than one industry;
3) Subpart G: Emissions from use of organic
material;
4) Subparts H-e~4PR: Special rRules for various
industry groups.
~j Subpart TT: Rules for emission units not
otherwise addressed.
~j. Subpart UU: Recordkeeping and reporting for
equipment and operations addressed by Subparts PP,
00, PR, and TT.
(Source: Amended at
Ill. Req.
______,
effective
___________)
Section 218.101
Cleanup and Disposal OpcrationSavings Clause
Emission of organic material released during clean—up
operations
and disposal shall be included with other
emissions of organic
matcria~ trom the related emission source or air pollution
control equipment in determining total emissions.
~j Every owner or operator of an emission unit formerly
subject to 35 Ill. Adm. Code Part 215 shall have
complied with its standards and limitations by the
dates and schedules applicable to the emission unit in
accordance with 35 Ill. Adm. Code 215 or upon initial
start—up. Compliance with all compliance dates or
schedules found in 35 Ill. Adm. Code 215 are not
superseded bY this Part and remain in full force and
effect.
~j Nothing in this Part shall affect the responsibility of
any owner or operator that is now or has been subject
to the FIP to comply with its requirements thereunder
by the dates specified in the FIP.
(Source: Section repealed, new Section adopted at
_____
Ill.
Req.
_______,
effective _______________________
Section 218.102
Abbreviations and Conversion Factors
a) The following abbreviations are used in this Part:
Amcrican ~oeic~y Lor ‘rc3Ling and Material
bbl
barrels (42 gallons)
degrees Celsius or centigrade
01 14O-U52Li.

fft~
ml
~c-r
117
square meters
rmhi
c~
~..il1igrr~m~
SIP
State Implementation Plan
TTE
temporary total enclosure
sq cm
square centimeters
sq in
square inches
English ton
ton
English ton
UCEPA
United States
Environm~I1L
VOC
volatile organic compounds
VOL
volatile organic liquids
VON
volatile organic materials
01 ‘40-0525
centimeters
cubic inches
degrees Fahrenheit
Federal Iinplemcntati
cu in
FIP
ft
kcal
gallons per mlnnt~
grams per ~
gallons
hours
I
nr~hr’’-~
degrees
Kcl~.~
kilocalorie~
kilograms
fly
kilograms per hour
-.
kilopascals; one thousand newtons per square
meter
11
tr~rq
l/sc’~’
lbs
lbs/hr
lbs/gal
liters per second
pounds
n p.s.
An
.-.
1..
ruin,,:;
F’
~
~as
A’A~.~
t”~~•’—
SL~.# ~.4A_
-p~ -~perq~’
lower explosi
1I
I
T~1
Megagrams, metric tons
rn-
millilitcrs
ii
ml
niitic’~i
xncgajoulcs
mm Hg
millimeters of mercury
NDO
natural draft opening
ppm
parts per million
ppmv
parts per million by volume
psi
pounds per square
inch
psia
pounds per square inch absolute
psig
pounds per square inch gauge
scf
standard cubic feet
scm
standard cubic meters
~1
____A__
— ~
r.__J_. — _i_.
I
-i

118
b) The following conversion
-‘,-
~
English Metric
lgal
~qc:; 1
1,000 gal 3,785 1 or 3.785 m~.
2.205 lbs
1~—bbl
159 .0 1
1 cu in 16.39 ml
i iD/~ti
iLJ,~UU
flhi~/J
0.907
Mg
0.907 Mg
1 ton
1T
The abbreviations and conversion factors of 35 Ill. Adm. Code 211
apply to this Part.
(Source: Amended at
Ill. Req.
______,
effective
Section 218.103
Applicability
The provisions of this Part shall apply to all sources located in
the Chicago area, which is composed of Cook, DuPage, Kane, Lake,
McHenry or Will Counties, or Aux Sable Township or Goose Lake
Township in Grundy County or Oswego Township in Kendall County.
a) The provisions of this Part shall become effective
on July 1, 1991 with the following exceptions:
1) The provisions of this Part shall become effective
on September 1, 1991 for each appellant, including
the constituents represented by appellants who are
associations, who has appealed the federal
implementation plan (FIP) for the Chicago area
(Illinois Regulatory Group v. USEPA, No. 90-2778
(and consolidated cases) (7th Cir.)).
The effectiveness of any provision of this Part
applicable to any individual source or category of
sources which has appealed the FIP shall be stayed
to the extend that such individual -source or
category of sourcea received a stay of the
effectiveness of the FIP from UCEPA or from a
eeurt. When the court has taken final action or
when USEPA has published in the
Federal Register final action to revise or affirm
the provisions of the FIP specifically applicable
f-ru
‘-illrh I
nr~I ~ri rlu-u
1
~runri-’r-
catcgr~
ruf’ ~nurr~r-~
or such stay is terminated, the Board shall take
corresponding action, if necessary, by the
adoption of a peremptory rule pursuant to 35 Ill.
Adm. Code 102.347 and Section 5.03 of the
01140-0526
—— ;;, ,
2)

119
roe~
Stat. 1989, ph. 127, ch. 1005.03).~
effectiveness of any provision of this Part
applicable to any individual source or category of
sources which has appealed the FIP shall be stayed
to the extent that such individual source or
category of sources received a stay of the
effectivenessfrom
the USEPA
ofor thefromFIP,thependingcourt
inreconsiderationthe FIP appeal1
cited in subsection 218.103(a) (1) above. When
USEPA has published in the Federal Register final
action to revise or affirm the provisions of the
FIP specifically applicable to such individual
source or category of sources or such stay is
otherwise terminated, the Board shall take
corresponding action and the Agency shall submit
such action to USEPA for approval. Until such
time as USEPA approves the corresponding amendment
to this Part, the FIP rule shall remain the
applicable implementation plan for that source or
category of sources under the Clean Air Act.
3) The provisions of this Part shall become effective
on November 15, 1992 for all sources located in
Aux Sable Township or Goose Lake Township in
Grundy County or in Oswego Township in Kendall
County.
b) The provisions of the Part shall not apply to Viskase
Corporation; Alisteel, Incorporated; Stepan Company; or
Ford Motor Company to the extent such source has
obtained an adjusted standard from the Board or an
exclusion from the General Assembly for any Subpart of
this Part or of 35 Ill. Adm. Code 215.
(Board Note: Subsection 218.103(b) of this Section shall be
effective at the federal level only upon approval by USEPA.)
(Source: Amended at
Ill. Req.
______,
effective
_________
Section 218.104
Definitions
The following ~erms arc actincu Lor
LnC purpose of
this Part.
“Accelacota” means a pharmaceutical coating operation
which consists of a horizontally rotating perforated
drum in which tablets arc placed, a coating is applied
~y spraying, and the coating is dried by the flow of
~ir acrocs the drum through the perforations.
“Accumulator” means the reservoir of a condensing unit
receiving the condensate from a surface condenser.
01140-0527

120
“Acid Cases” means for the purposes of Section 9.4 of
thcEnvir:~:t~
(Jf1I11E~LEIL~
I
~:~t~tion Act (the Act) (Ill Rev
D-t.UL.
IJ~I,
OH. LLi
1/2, par.
LLJUJ.’*) ,
uyuroycn
chloride, hydrogen fluoride and hydrogen bromide, which
exist as gases, liquid mist, or any combination
thereof.
“Actual emissions” means the actual quantity
-of
VOM
emissions from an emi-ssion source during a particular
time period.
“Actual Heat Input” means the quantity of heat produced
by the combustion of fuel using the gross heating value
of the fuel.
“Adhesive” means any substance or mixture of substances
“Afterburner” means a control device in which materials
in gaseous effluent arc combuctcd.
“Air contaminant” means any solid, liquid, or gaseous
matter, any odor, or any form of energy, that is
capable of being released into the atmosphere from an
emission source.
“Air dried coatings” means any coatings that dry by use
of air or forced air at temperatures- up to 363.15~I
(194°F).
“Air pollution” means the presence in the atmosphere of
one or more air contaminants in sufficient quantities
and of such characteristics and duration as to be
injurious to human, plant, or animal life, to health,
or to property, or to 1rn~-~-~nrmh1vir~rfr’rc~uith
thc~
~
,-.~
1 4 .r-~
“Air pollution control equipment” means any equipment
-or facility of a type intended to eliminate, prevent,
reduce or control the emission of specified air
contaminants to the atmosphere.
“Air suspension coatcr/drycr” means a pharmaceutical
coating operation which consists of vertical chambers
in which tablets or particles arc placed, and a coating
is applied and then dried while the tablets or
particles arc kept in a fluidized state by the passage
of air upward through the chambers.
“Airless spray” means
the coating is atoniiz
~-‘------~
high pr’~’
a spray coating method in which
d by forcing it through a small
rc. The coating liquid is not
01140-0528
4*
V ‘
1*4
1*?
‘.~
j
oina_4
~
1*~t1F’
1.1
1_ta £1.4

121
mixed with air before exiting from the nozzle.
“Air—acs~Lcu uiriess spruy~ means a spray coati.~
method which combines compressed air with hydraulic
pressure to atomize the coating material into finer
droplets than is achieved with pure airless spray.
Lower hydraulic pressure is used than with airless
spray.
“Allowable emissions” means the quantity of VOM
emissions during a particular time period from a
stationary source calculated using the maximum rated
capacity of the source (unless restricted by federally
enforceable limitations on operating rate, hours of
operation, or both) and the most stringent of: the
applicable standards in 40 CFR Parts 60 and 61; the
applicable implementation plan; or a federally
enforceable permit.
“Ambient air quality standards” means those standards
designed to protect the public health and welfare
codified in 40 CFR Part 50 and promulgated from time to
time by the USEPA pursuant to authority contained in
Section 108 of the Clean Air Act, 42 U.&.C. 7401 ct
seq., as amended from time to time.
“Applicator” means a device used in a coating line to
apply coating.
“As applied” means the exact formulation of a coating
during application on or impregnation into a substrate.
“Architectural Coating” means any coating used for
residential or commercial buildings or their
appurtenances, or for industrial buildings, which is
site applied.
“Asphalt” means the dark-brown to black cemcntitious
material (solid, semisolid, or liquid in consistency)
of which the main constituents arc bitumens which occur
naturally or as a residue of petroleum refining.
“Asphalt Prime Coat” means a low-viscosity liquid
asphalt applied to an absorbent surface as the first of
more than one asphalt coat.
“Automobile” means a motor vehicle capable of carrying
no more than 12 paoscngcr~s.
“Automobile or light-duty truck assembly plant” means a
facility where parts are assembled or finished for
eventual inclusion into a finished automobile or light-
01140-0529

122
duty truck ready for sale to vehicle dealers, but not
including customizers, body s-hops, and other
rcpainters.
“Automobile or light-duty truck refinishing” means the
repainting of usect automo~-iics and light-duty trucks.
dried in an oven where the
~0°C (194°F).
4-
1 _ —_
— _1_ I _t_
I
“Batch Loading”
_n ~
_~._1~
“Bead-Dipping” means the dipping of an assembled tire
bead into a solvent-based cement.
“Binders” means organic materials and resins which do
not contain VON.
“Bituminous coatings” means black or brownish coating
materials which are soluble in carbon disulfide, which
consist mainly of hydrocarbons, and which are obtained
from natural deposits or as residues from the
distillation of crude oils or of low grades of coal.
“British Thermal Unit” means the quantity of heat
required to raise one pound of water from 60°Fto 61°F
(abbreviated btu).
“Brush or wipe coating” means a manual method of
applying a coating using a brush, cloth, or similar
object.
“Bulk gasoline plant” means a gasoline storage and
distribution facility with an average throughput of
76,000 1 (20,000 gal) or less on a 30—day rolling
average that distributes gasoline to gasoline
dispensing facilities.
“Bulk Gasoline Terminal” means any gasoline storage and
distribution facility that receives gasoline by
pipeline, ship or barge, and distributes gasoline to
bulk gasoline plants or gasoline dispensing facilities.
“Can” means any metal container, with or without a top,
cover, spout or handles, into which solid or liquid
materials are packaged.
“Can coating” means any coating applied on a single
tznl 1~t1
r~runt-ni
-~t-h-~fI
~z mrunnfrur!t—n~—i~r1
from
m~f~1 ~
01140-0530

123
thinner than 29 gauge (0.0141 in.).
“Can coating
means a facility that includes one or
more can coating line(s).
•1(~nru r~ru~ut—ing1
~
mc~nn~,~
r~rurut~inr~
1 i
nu~
in which
protective, decorative, or functional coating is
applied onto the surface of cans or -can components.
“Capture” means the containment or recovery of
emissions from a process for direction into a duct
which may be exhausted through a stack or vent to a
control device. The overall abatement of emissions
fr-am a process with an add—on control device is a
function both of the capture efficiency and of the
control device.
“Capture device” means a hood, enclosed room floor
sweep or other means of collecting solvent or other
po-Ilutants into a duct. The pollutant can then be
iirr~r~tic’c1 to n nrul
intl run r~runtrru1 dr~vi
r~r~~ur~h
as an
~.1’1y
afterburner or carbon acisorber. Sometimes the term is
us-ed loosely to include the control device.
~.1 —
proc~.
A 4
the fraction of all VOM
directed to an
“Capture system” means all equipment (inaludi-ng, but
not limited to, hoods,
ducts, fans, ovens, dryers,
etc.) used to contain, collect and transport an air
po-Ilutant to a control device.
“Clean Air Act” means
the Clean Air Act of 1963, as
amended, including the Clean Air Act Amendments of
1977, (42 U.S.C. 7401 ct seq.), and the Clean Air Act
Amendments of 1990, (P.L. 101-549).
“Clear coating” means coatings that lack color and
opacity or arc transparent using the undercoat as a
~~f1i~c~’tnt
hv~r~t-ur nn~i-~rtnnc~r~ru1rur
“Clear topcoat” means the final coating which contains
binders, but not opaque pigments, and is specifically
formulated to form a transparent or translucent solid
protective film.
“G-Ioscd Purge System” means a system that is not open
to the atmosphere and that is composed of piping,
connections, and, if necessary, flow inducing- devices
that transport liquid or vapor from a piece -or pieces
e-f equipment to a control device, or return the liquid
0 I 140-053 I

—1:-
124
“Closed vent system” means a system t4~
4,-.
to
the atmospherc and is composed of piping, connections,
and, if necessary,
flow inducing devices that transport
gas or vapor from an emission source to a control
device.
1” fl1~fl fl
1
Tfl;1
I fl
r
I .1 I I
r~
I-I-!II
OJILO O.E
imprcqn~tc~c1
~~rur~-,t
I
~rr’
or
“Coatin;”
into
~
~-.1-
prot~~8VVe,
d
functional purposes. Such materials include, but arc
not limited to, paints, varnishes,sealers, adhesives,
thinners, diluents, and inks.
“Coating applicator” means equipment used to apply a
coating.
“-Coating line” means an operation consisting of a
series of one or more coating applicators and any
associated flash—off areas, drying areas, and ovens
wherein a surface coating is applied, dried, or cured.
(It is not necessary for an operation to have an oven,
or flash-off area, or drying area to be included in
this definition.)
“Coating plant” means any plant that contains one or
more coating line(s).
“Coil” means any flat metal sheet or strip that is
rolled or wound in concentric rings.
“Coil ~~ing”
~
applied
~.aj
flat
iuetal sheet or strip that comes in rolls or coils.
“Coil coating facility” means a facility that includes
one or more coil coating line(s).
“Coil coating line” means a coating line in which any
protective, decorative or functional coating is applied
onto the surface of flat metal sheets, strips, rolls,
or coils for industrial or commercial use.
“Cold cleaning” means the process of cleaning and
removing soils from surfaces by spraying, brushing,
flushing, or immersion- while maintaining the organic
solvent below its boiling point. Wipe cleaning is not
included in this definition.
“Complete Combustion” means a process in which all
carbon contained in a fuel or gas stream is converted
to carbon dioxide.
01 L~.Q-0532

125
“Component” means, with respect to synthetic organic
chemical and polymer manufacturing equipment, and
petroleum refining and related industries, any piece of
equipment which has the potential to leak VON
including, but not limited to, pump seals, compressor
seals, seal oil degassing vents, pipeline valves,
pressure relief devices, process drains, and open ended
pipes. This definition excludes valves which are not
externally regulated, flanges, and equipment in heavy
liquid service. For purposes of Subpart
Q
of this
Part, this definition also excludes bleed ports of gear
pumps in polymer service.
“Concrete curing compounds” means any coating applied
to freshly poured concrete to retard the evaporation of
water.
‘~Condensate” means volatile organic liquid separated
from its associated gases, which condenses due to
changes in the temperature or pressure and remains
liquid at standard conditions.
“Continuous process” means, with respect to polystyrene
resin, a method of manufacture in which the styrene raw
material is delivered on a continuous basis to the
reactor in which the styrenc is polymerized to
polystyrene.
“Control device” means equipment (such as an
afterburner or adsorbcr) used to remove or prevent the
emission of air pollutants from a contaminated exhaust
stream.
“Control devi
pollution prevented by a control device and the
pollution introduced to the control device, expressed
as a percentage.
“Conveyorized degreasing” means the continuous process
of cleaning and removing soils from surfaces utilizing
either cold or vaporized solvents.
“Crude oil” means a naturally occurring mixture which
consists of hydrocarbons and sulfur, nitrogen, or
oxygen- derivatives of hydrocarbons and which is a
liquid at standard conditions.
“Crude oil gathering” mcans the transportation of crude
oil or condensate after custody transfer between a
production facility and a reception point.
“Custody transfer” means the transfer of produced

Back to top


01140-0533

126
petroleum and/or condensate after processing and/or
treating in the producing operations, from storage
tanks or automatic transfer facilities to pipelines or
any other forms of transportation.
“Cutback Asphalt” means any asphalt which has been
liqui-ficd by blending with petroleum solvents other
than residual fuel oil and has not been emulsified with
water.
“Daily—weighted average VON content” means the average
VOM content of two or more coatings as applied on a
coating line during any day, taking into account the
fraction of total coating volume that each coating
represents, as calculated with the following equation:
VO
~•—
E-
i~-l
where:
V-O14~-
The average VON content of two or more
coatings as applied each day on a
coating line in units of kg VOM/l (lbs
VON/gal) of coating (minus water and any
compounds which arc specifically
exempted from the definition of VOM),
The number of different coatings as
applied each day on a coating line,
VT
Thc voiiimr’
of
r’~r~h
r~runting (minuG
—~
1*4~
compounas which arc specifically
exempted from the definition of VON) as
applied each day on a coating line in
units of 1 (gal).
content of eacha coatingcoatinglineas in
The VON each day ~~lbs ~
applied kg VON/i ~r and any ed from the
units of (minus wate exempt of
coating c specifica and
which
of VON),
definiti
all coatings (minus
1 volume of
which arc
The totad any comPoOd from thCcach day
water ally cxemPtas applied 1 (gal).
sPecific of VON) n units of
d~~fl~titingline
i
on a coa
OIL~O_053~

“Day” means the consecutive 24 hours beginning at 12:00
(midnight) local time.
“Dcgrcaser” means any equipment or system used in
solvent cleaning.
“Delivery vessel” means any tank truck or trailer
equipped with a storage tank that is used for the
transport of gasoline to a stationary storage tank at-a
gasoline dispensing facility, —bulk gasoline plant,
bulk gasoline terminal.
or
“Dip coating” means a method of applying coatings in
which the part is submerged in a tank filled with
coating.
the
“Distillate Fuel Oil” means fuel oils of grade No. 1 or
2 as specified
in
~
r~nlr~m~nt~ for fuel oil
“Dry Cleaning Facility” means a facility engaged in the
cleaning of fabrics using an essentially nonaqucous
solvent by means of one or more solvent washes,
extraction of excess solvent by spinning and drying by
tumbling in an -airstream. The facility includes, but
is not limited to, washers, dryers, filter and
purification systems, waste disposal systems, holding
tanks, pumps and attendant piping and valves~-
“Effluent Water Separator” means any tank, box, sump or
other apparatus in which any organic material floating
on or entrained or contained in water entering such
tank, box, cump or other apparatus is physically
separated and removed from such water prior to outfall,
drainage or recovery of such water.
“Electrostatic bell or disc spray” means an
electrostatic spray coating method in which a
rapidly-spinning bell- or disc-shaped applicator is
used to create a fine mist and apply the coating with
high transfer efficiency.
“Electrostatic spray” means a spray coating method in
which opposite electrical charges are applied to the
substrate and the coating. The coating is attracted to
the object due to the electrostatic potential between
them.
“Emission Rate” means total quantity of any air
contaminant discharge into the atmosphere in any

Back to top


01140-0535
127
(1971)
- --

128
ItEmission source” and “source” mean any facility from
which VON is emitted or capable of being emitted into
the atmosphere.
“Enamel” means a coating that cures by chemical
cross—linking of its base resin. Enamels can be
d-istinguishcd from lacquers- because
readily resoluble in their original
enamels arc
solvent.
not
cover any VOL surface that is
~asP
a-~~d.g~1
~
~
•~~l~l~11~
“Extreme environmental conditions” means exposure to
~nv
or
~i1 of thr~ foilrutJlnrz! ~mhic~nt-~c’~thor
(203°F); detergents; abrasi
A
solvents; or corrosive atmospheres.
ing agents
“Extreme performance coating” means any coating which
during intended usc is exposed to extreme environmental
conditions.
“Fabric coating” means any coating applied on textile
fabric. Fabric coating includes the application of
01140-0536
I.
1-Ti—
— — — U
a
i~_
~
iLE~id
scaling compound coat” means a compound applied to
ean ends which functions as a gasket when the end is
a-sscmbled onto the can.
“Excess Air” means air supplied in addition to the
theoretical quantity necessary for complete combustion
of all fuel and/or combustible waste material.
-11-Excessivc release” means a discharge of more than 205
g (0.65 lbc) of iaercaptans and/or hydrogen sulfide into
the atmosphere in any 5—minute period.
“Exterior base coat” means a coating applied to the
exterior of a can body, or flat sheet to provide
protection to the metal or to provide background for
any lithographic or printing operation.
-“--Exterior end coat” means a coating applied to the
exterior end of a can to provide protection to the
metal.
“External floating roof” means a cover over an open top
storage tank consisting of a double deck or pontoon
aingle deck which rests upon and -is supported by the
volatile organic liquid being contained and is equipped
with- a closure seal or seals to close the space between

129
coatings by impregnation.
ting facility” means a
c or more fabric coating li
“Fabric coating line” means a coating line in which any
protective, decorative, or functional coating or
reinforcing material is applied on or impregnated into
a textile fabric.
“Federally enforceable” means all limitations and
conditions which arc enforceable by the Administrator
including those requirements developed pursuant to 40
CFR Parts 60 and 61; requirements within any applicable
implementation plan; and any permit requirements
established pursuant to 40 CFR 52.21 or under
regulations approved pursuant to 40 CFR Part 51 Subpart
I and 40 CFR 51.166.
“Final repair coat” means the repainting of any topcoat
which is damaged during vehicle assembly.
“Pl~ruhov”
means
chamber
-eompar4-”-~ent of
-~-
boil
~n which inatcrial.~ure bur~d, but not the
combustion chamber or afterburner of an incinerator.
“Fixed-roof tank” means a cylindrical shell with a
permanently affixed roof.
-~
“Flexographic printing” means the application of words,
designs, and pictures to a substrate by means of a roll
printing technique in which the pattern to be applied
is raised above the printing roll and the image carrier
is made of clastomeric materials.
-
“Flcxographic printing line” means a printing line in
which each roll printer uses a roll with raised areas
for applying an image such as words, designs, or
pictures to a substrate. The image carrier on the roll
is made of rubber or other clastomeric material.
“Floating roof” means a roof on a stationary tank,
reservoir, or other container which moves vertically
upon change in volume of the stored material.
“Fountain solution” means the solution which is applied
to the image plate to maintain hydrophilic properties
of the non-image areas.
“Freeboard Height” means for open top vapor dogreasers,
the distance from the top of the vapor zone to the top
of the degreaser tank. For cold cleaning dogreascro,
01140-0537
~~1

A
130
_I__
~
4-
-
_~t
4-~
“Fuel combustion emission source” means any furnace,
boiler, or similar equipment used for the primary
purpose of producing heat or power by indirect heat
transfer.
“-Fuel gas system” means a system for collection of
refinery fuel gas including, but not limited to, piping
for collecting tail gas from various process units,
mixing drums and controls, and distribution piping.
“Gas service” means that the component contains process
fluid that is in the gaseous state at operating
conditions.
“Cas/gas method” means either of two methods for
determining capture which rely only on gas phase
measurements. The first method requires construction
of a temporary total enclosure (TTE) to ensure that all
would—be fugitive emissions arc measured. The second
method uses the building or room which houses the
facility as an enclosure. The second method requires
that all other VON sources within the room be shut down
while the test is performed, but all fans and blowers
within the room must be operated according to normal
procedures.
f4
-“-Ga
~U ~““
I ii E
-
mr~~1 Ti
~ Ti \1 rur~ V ~‘u1r-’, irn 1~,
~
I
r
I I
r~
U)T -U::
~trol
-‘izti1late,’~~-~
~‘--“-~
having
-~
‘~-~-~
“apor prcssr~
of 27.6 kPa or greater which is used as a fuel for
internal combustion engines.
~4~H
“Casoline dispensing facility” means any site where
gasoline is transferred from a stationary storage tank
to a motor vehicle gasoline tank used to provide fuel
to the engine of that motor vehicle.
“-Green Tire Spraying” means the spraying of green
tires, both inside and outside, with release compounds
which help remove air from the tire during molding and
prevent the tire from sticking to the mold aft-er
curing.
“Green Tires” means assembled tires before molding and
curing have occurred.
“Cross vehicle weight” means the manufacturer’s gross
weight rating for the individual vehicle.
“Cross vehicle weight rating” means the value specified
01140-0538

131
by the manufacturer as -the maximum design loaded weight
of a single vehicle.
~
airless spray” means
an airiess spray coaLing
method in which the coating is heated just prior to
application.
“Heatcet” means a class of web—offset lithography which
requires a heated dryer to solidify the printing inks.
“Heatset—web-offoct lithographic printing line” means a
lithographic printing line in which a blanket cylinder
is used to transfer ink from a plate cylinder to a
substrate continuously fed from a roll or an extension
process and an oven is used to solidify the printing
inks.
“Heavy liquid” means liquid with a true vapor pressure
~f 1~
than fl~ kP~
(fl~fl~psi) ~
~
(7flop~
established in a standard reference text or
as
determined by ASTM method D2879-86 (incorporated
by
reference in Section 218.112); or which has 0.1 Reid
Vapor Pressure as determined by ASTN method
D323-82
~incorporatea by rererence ~n Section 218.112); or
which when distilled requires a temperature of 421.95°K
(300°F) or greater to recover 10 percent of the liquid
as determined by ASTM method D86-82 (incorporated by
reference in Section 218.112).
“Heavy off-highway vehicle proth~cts” means, for the
purpose of Subpart F of this Part, heavy construction,
mining, farming, or material handling equipment; heavy
industrial engines; diesel—electric locomotives and
r~nc~ir~t
nowc~r
equipment; and the compnn.c~nf~
of
~ni~th
equipment or engines.
“Heavy off-highway vehicle products coating facility”
means a facility that includes one or more heavy
off-highway vehicle oroducts coating line(s).
“Heavy off—highway vcnicic products coating line” mea:_
a coating line in which any protective, decorative, or
functional coating is applied onto the surface of heavy
off-highway vehicle products.
“High temperature aluminum coating” means a c-eating
that is certified to withstand a temperature of 537.8°C
(‘1000°F) for 24 hours..
~i-ioocu-~--mcansa
~
or canopy
capturing and
-
means of a draft, the
01140-0539

132
organic vapors or other fumes rising from a coating
process or other souree--
“Hood capture efficiency” means the emissions from a
process which are captured by the hood and directed
into a control device, expressed as a percentage of
all
emissions.
“Hot well” means the reservoir of a condensing unit
receiving the condensate from a barometric condenser.
“Hour”
block period of
‘~‘
~
to 2:00am).
bicnding, heating, reacting, holding, cryctallizing,
evaporating or cleaning operations in the manufacture
of pharmaceuticals.
“In—situ Sampling Systems” means nonextractive samplers
or in-line samplers.
“In vacuum service” means, for the purpose of Subpart Q
of this Part, equipment which is operating at an
internal pressure that is at least 5 kPa (0.73 psia)
below ambient pressure.
“Incinerator” means a combustion apparatus in which
...
,
4
,.,-.
,
~
“Indirect heat transfer” means transfer of heat in such
a way that the source of heat does not come into direct
contact with process materials.
“Ink” means a coating used in printing, impressing, or
transferring an image onto a substrate.
“Interior body spray coat” means a coating applied
spray to the interior of a can body.
“Internal-fbating roof” means a cover or roof in
by
a
fixed-roof tank which rests upon and is supported
by
the volatile organic liquid being contained and is
equipped with a closure seal or seals to close the
space between the roof edge and tank shell.
I,,-
-‘
~
~
~od
finish....~ ......
with
n~tro~r11u1.o~
or
nt~hr’~i-ic~
rr~sins to dry by
caction, including
01140-05140
—~
‘-~‘~,
1~flflm,i
—_L
lacquer canding scalers.

133
“Light liquid” means VON in the liquid state which is
not defined
as heavy liquid.
~,b3u
ity gross vehicle weight or less
UIU~fl
I ~—
‘—
to transport property.
“Liquid/gas method” means either of two methods for
determining capture which require both gas phase and
liquid phase measurements and analysis. The first
method requires construction of a TTE. The second
method uses the building or room which houses the
facility as an enclosure. The second method requires
that all other VON sources within the room be shut down
while the test is performed, but all fans and blowers
within the room must be operated according to normal
procedures.
“Liquid—Mounted Seal” means a primary seal mounted in
continuous contact with the liquid between the tank
wall and the floating roof edge around the
circumference of the roof.
“Liquid
‘-~r’r~iir-&’ ~
-t-hM-
i-hr
i~y~mr-r~1
or
comDonerlt
r, e~i~ 4-
-
4
fluid that i~in a liquid state
operating conditions.
“Liquids Dripping” means any visible leaking from a
seal including spraying, misting, clouding and icc
formation.
01140-05141
“Large appliance” means any residential and commercial
washers, dryers, ranges, refrigerators, freezers, water
heaters, dishwashers, trash compactors, air
conditioners, and other similar products.
“Large appliance coating”
mr’-ir~
~1w
r~ontinrc
nnn1ir~ to
the component
~--
-•
4-
.4
~4--’
pa~-~(including,
~“~‘
1
Tfll Y-~UI
parts) of residential~ids,and~anels,commercialand
interi~_washers, supperdryers,4-
ranges, refrigerators, freezers, water heaters,
dishwashers, trash compactors, air conditioners, and
other similar products.
“Large appliance coating facility” means a facility
that includes one or more large appliance coating
line(s).
“Large appliance coating line” means a coating line in
which any protective, decorative, or functional coating
is applied onto the surface of large appliances.
~ight-duty
4-~”
vehicle rated at
~ ~
mainl2

graphic
- 4...
~
printing
~1-...4—-.-.4—.-.
line”
4
~-.
1
powder coat~y~.
“Magnet wire” means aluminum or copper wire formed into
an electromagnetic coil.
“Magnet wire coating” means any coating or electrically
insulating varnish or enamel applied to magnet wire.
“Magnet wire coating facility” means a facility that
includes one or more magnet wire coating line(s).
“Magnet wire coating line” means a coating line in
which any protective, decorative, or functional coating
is applied onto the surface of a magnet wire.
“Malfunction” means any sudden and unavoidable failure
of air pollution control equipment, process equipment,
.—. r. I~—
o op er at-c-
sat
...a
-_
as~,
- n~,...
a.. ns.a.
S
&~4b.J~t~.4S
.
1
m
L,L~aA
— n
LA
LS...A..
Failures that arc caused entirely or in part by poor
maintenance, careless operation, or any other
preventable upset condition or preventable equipment
breakdown shall not be considered malfunctions.
“Manufacturing process” means a method -whereby a
process emission source or series of process cmissio~~
sources is used to raw materials, feed stocks,
subassemblies, or other components into a product,
either for sale or for use as a component in a
subsequent manufacturing process.
“Material Recovery Section” means any equipment
dcsigned to transport and recover styreno monomer and
otncr impurities from other products and by—proaucto in
a polystyrene plant, including but not limited to the
styrcnc devolatilizer unit and styrene recovery unit.
“Maximum theoretical
emissions” means the quantity of
volatile organic
material emissions that theoretically
could be emitted by a stationary source
before add—on
contro..~
1
DQOCü
on the design capacity
production capacity of the source and 8760 hours per
year. The design capacity or maximum production
01140-05142
tI_I-
2 .1_i...
134
1_4-!__
I
I
excepL ~na~
~
an unwinding roll,
roll where both the
ncce~caril~
in which each roll printer
image and non—image areas
fed from
uses a
are
essentially in the same plane (planographic).
“~~-‘---
~“~ent Coating”
s.~sa.a
~.a ,
~. j.,.
solvent than th~
A
used by the industry. Low solvent coatings
include
water—borne, higher
solids, clcctro—dcposition and
-
means
ci
coating
r~o~r~-~
~
,.~
,
4..
4
.
~
4..
4

135
capacity includes use of coating(s) or ink(s) with the
highest volatile organic material content actually used
in practice by the source. Provided, however, the
Agency shall, when appropriate, and upon request by the
permit applicant, limit the “maximum theoretical
emissions” of a source by the imposition of conditions
in- a federally enforceable operating permit for such
source. Such conditions shall not be inconsistent with
requirement of the Clean Air Act, as amended, or any
applicable requirements established by the Board. Such
conditions shall be established in place of design
capacity or maximum production capacity in calculating
the “maximum theoretical emissions” for such source and
may include, among other things, the establishment of
production limitations, capacity limitations, emission
limitations, or limitations on the volatile organic
material content of coatings or inks, or the hours of
operation of any emission source, or a combination of
any such limitations-.
-
Production or capacity limitations shall be established
on basis of no longer than one month except in those
cases where a limit spanning a longer period of time is
appropriate. In such cases, a rolling limit” shall be
employed. Any production or capacity limitations shall
be verified through appropriate recordkeeping. (Board
Note: The US-EPA may deem operating permits which do
not conform to the operating permit program
requirements and the requirements of US-EPA’s underlying
regulations, including the requirement that limitations
be quantifiable and enforceable as a practical matter,
not “federally enforceable.”)
“Metal furniture” means a furniture piece including,
but not limited to, tables, chairs, waste baskets,
beds, desks, lockers, benches, shelving, file cabinets,
lamps, and room dividers.
“Metal furniture coating” means any non—adhesive
coating applied to any furniture piece made of metal or
any metal part which is or will be assembled with other
metal, wood, fabric, plastic or glass parts to form a
furniture piece including, but not limited to, tables,
chairs, waste baskets, beds, desks, lockers, benches,
shelving, file cabinets, lamps, and room dividers.
This definition shall not apply to any coating line
coating miscellaneous metal parts or products.
ttRH...4-
-~i ~
4 ~
coatii.g- facility” c~i~a facility
that includes one or more metal furniture coating
line(s).
01140-05143

136
“Metal furniture coating line” means a coating line in
which any protective, decorative, or functional coating
is applied onto the surface-of metal furniture.
“-Metallic shoe—type seal” means a primary or secondary
s--cal constructed of metal sheets (shoes) which arc
joined together to form a ring, springs, or levers
which attach the shoes to the floating roof and hold
the shoes against the tank wall, and a coated fabric
which is suspended from the shoes to the floating roof.
‘tM-iscellaneous fabricated product manufacturing
process” means:
A manufacturing proces-s involving one or more of the
following applications, including any drying and curing
of formulations, and capable of emitting VON:
to fabricate or assemble- components or
products
Asphalt solutions to paper or fiberboard
Asphalt to
or teit
Coatings or dye to leather
Coatings to plastic
Coatings to rubber or glass
wsintcctant matcriai to manuracturcu items
Plastic foam scrap or “fluff” from the manufacture
of foam containers and packaging material to form
resin pallets
Resin solutions to fiber substances
Viscose solutions
for food casings
The storage and handling of formulations associated
c~iththe process described above, and the use and
handling of organic liquids and other substances for
clean—up operations associated with the process
described in this definition.
“Miscellaneous
manufactur
-
occss”
means:
~ manuLuocuring process wnicn ~
one a
the following and is oaoablo of emitting VON:
0l140-05~414

Adhesives
137
Asphalt solutions
I _.L.
Coatings, other than paint and ink
Concrete curing compounds
Dyes
Friction materials and compounds
— .1..
Resin solutions
flnhhr-~r
~o1
nt~i
or~’~
Viscose solutions
The storage and handling of formulations associated
with the process described above, and the use and
handling of organic liquids and other substances for
clean—up operations associated with the process
described in this definition.
“Miscellaneous metal parts
or products”
means
any
metal
part or metal product, even if attached to or combined
with ci nonmetal part or product, except cans, coils,
metal furniture, large appliances, magnet wire,
automobiles, ships, and airplane bodies.
“Miscellaneous metal parts and products coating” means
any coating applied to any metal part or metal product,
even if attached to or combined with a nonmetal part or
product, except cans, coils, metal furniture, large
appliances, and magnet wire.
Prime coat, prime
surfacer coat, topcoat, and final repair coat for
automobiles and light-duty trucks arc not miscellaneous
metal parts and products coatings. However, underbody
anti-chip (e.g., underbody plastisol) automobile and
light—duty truck coatings are miscellaneous metal parts
and products coatings. Also, automobile or light-duty
truck refinishing coatings, coatings applied to the
exterior of marine vessels, coatings applied to the
exterior of airplanes, and the customized topcoating of
automobiles and trucks if production is less than 35
ehic~
~y arc not miscellaneous metal parts and
products coatings.
“Niscella
facility”
metal parts or products coating
a facility that includes one o:
01140-05145

138
~rL~
or nrouuct~
upu~’flU
ii
“Miscellaneous metal parts or products coating line”
~
.-~ r~oM-inrr
1inc~ in
tihirth mv.i ~rot~ti~jr~
decorative, or functional coating ic applied onto the
surface of miscellaneous metal parts or products.
“Miscellaneous organic chemical manufacturing process”
means:
A manufacturing process which produces, by chemical
reaction, one or more of the following organic
compounds or mixtures of organic compounds and whic
capable of emitting VON:
Chemicals listed in Appendix A of this Part
Chlorinated and sulfonated compounds
Cosmetic, detergent, soap, or surfactant
intermediaries or specialties and products
Disinfectants
Food additives
Oil and petroleum product additives
Plasticizers
Resins or polymers
Rubber additives
Sweeteners
Varnishes
The storage and handling of formulations associated
w~iththe process described above and the usc and
handling of organic liquids and other substances for
c-lean—up operations associated with the process
described in this definition.
“Monitor” means to measure and record.
“Multiple package coating” means a coating made from
more than one different ingredient which must be mixed
prior to using and has a limited pot life due to the
chemical reaction which occurs upon mixing.
“No Detectable Volatile Organic Material Emissions”
01140-05146

139
means a discharge of volatile organic matcriol into the
atmosphere as indicated by an instrument reading of
less than 500 ppm above background as determined in
accordance with 40 CFR 60.435(c).
“Offset” means, with respect to printing and publishing
operations, use of a blanket cylinder to transfer ink
from the plate cylinder to the surface to be printed.
“Opaque stains” means all stains that are not semi-
transparent stains.
“Open top vapor degreasing” means the batch process of
cleaning and removing soils from surfaces by condensing
hot solvent vapor on the colder metal parts.
“Open-ended valve” means any valve, except pressure
relief devices, having one side of the valve in contact
with process fluid and one side open to the atmosphere,
either directly or through open piping.
“Operator of Gasoline Dispensing Facility” means any
person who is the lessee of or operates, controls or
supervises a gasoline dispensing facility.
“Organic compound” means any compound of carbon,
excluding carbon monoxide, carbon dioxide, carbonic
acid, metallic carbides or carbonates, and ammonium
carbonate.
“organic material” means any chemical compound of
carbon including dilucnts and thinners which arc
liquids at standard conditions and which are us-ed as
dissolvers, viscosity reducers, or cleaning agents, but
excluding methane, carbon monoxide, carbon dioxide,
carbonic acid, metallic carbonic acid, metallic
carbide, metallic carbonates, and ammonium carbonate-.
“Organic vapor” means the gaseous phase of an organic
material or a mixture -of organic materials present in
the atmosphere.
“Oven” means a chamber within which heat is used for
one or more of the following purposes: dry, bake, cure,
or polymerize a coating or ink.
“Overall control” means the product of the capture
efficiency and the control device efficiency.
“uvcrvarnisn~means a transparent coating applied
directly over ink or coating.
01140-05147

140
-~‘-Owner of Gasoline Dispensing Facility” means any
person who has legal or equitable title to a stationary
storage tank at a gasoline dispensing facility.
“Owner or operator” means any person who owns,
operates, leascs, controls, or supervises an emission
source or air pollution control equipment.
“Packaging rotogravure printing” means rotogravure
printing upon paper, paper board, metal foil, plastic
film, and other substrates, which arc, in subsequent
operations, formed into packaging—products or labels
for ~r~ir~1r”~
to
hr~ ~r~1t-i
“Packaging rotogravure printing line” means a
rotogravure printing line in which surface coatings are
applied to paper, paperboard, foil, film, or other
substrates which arc to be used to produce containers,
packaging products, or labels for articles.
“Paint
manufar~turinri
n1~.nt”
mr.-~n~
~i
n1~nt that mivr~~
b-lends, or ~ompounas enamels, lacquers, scalers,
shellacs, stains, varnishes, or pigmented surface
coatings.
“Paper coating” means any coating applied on paper,
plastic film, or metallic foil to make certain
products, including (but not limited to) adhesivo tapes
and labels, book covers, post cards, office copier
paper, drafting—paper, or prcss~re sensitive tapes.
Paper coating includes the appl-ication of coatings by
impregnation- and/or saturation.
-
“Paper coating facility” means a facility that includes
one or more paper coating lines.
“Paper coating line” means a coating line in which any
protective, decorative, or functional coating is
applied on, saturated into, or impregnated into paper,
plastic film-, or metallic foil to make certain
products, including (but not limited to) adhesive tapes
and labels, book covers, post cards, office copier
paper, drafting paper, and pressure sensitive tapes.
“Parts per million (volume)” means a volume/volume
ritio ‘ihir,h
cx~rcsscs the volumctrir~—r~onn~-’-
-r~f
gaseous air contaminant in a million unit volume of
gas.
“Person” means any individual, corporation,
partnership, association, State, municipality,
political subdivision of a State~ any agency,
01140-05148

141
department, or instrumentality of the United States;
and any officer, agent, or employee thereof.
“Petroleum” means the crude oil removed from the earth
and the oils derived from tar sands, shale, and coal.
“Petroleum Liquid” means crude oil, condensate or any
finished or intermediate product manufactured at a
petroleum refinery, but not including Number 2 through
Number 6 fuel oils as specified in AS-TN D-396 69, gas
turbine fuel oils Numbers 2-CT through 4—CT as
specified in AS-TN D-2880-71 or diesel fuel oils Numbers
2-D and 4-D, as specified in AS-TN D-975-68.
“Petroleum refinery” means any facility engaged in
producing gasoline, kerosene, distillate fuel oils,
residual fuel oils, lubricants, or other products
through distillation of petroleum, or through
redistillation, cracking, or reforming of unfinished
petroleum derivatives.
“Pharmaceutical” means any compound or mixture, other
than food, iv~cdin the prevention, diagnosis,
alleviati~-...
-4--4-~-_~--4-
~
A4
4
animal.
Ti ,
..
n11m~,r, rind
‘~Pharmaceutical coating operation” means a device in
which a coating is applied to a pharmaceutical,
including air drying or curing of the coating.
“Photochemically Reactive Material” means any organic
material with an aggregate of more than 20 percent of
it-s total volume composed of the chemical compounds
classified below or the composition of which exceeds
any of the following individual percentage composition
limitations. Whenever any photochemicauly reactive
material or any constituent of any organic material may
be classified from its chemical structure into more
than one of the above groups of organic materials it
shall be considered as a member of the most reactive
group, that is, the group having the least allowable
percent of the total organic materials.
.—~
11
Ti
+~
A combination of hydrocarbons, alcohols,
a-ldchydcs, esters, ethers or kctones having an
o-lefinic
~‘-
cycl ilefini types -e~-____
-pe~e~4- This definiti~~Adoes not apply
~A~~Aylcne
,-..
e.. —
I,
or trichloroethylene.
,—
1
riri
A-
combination
of riroii~tir~ r~rimririiind~ uith
eight
or
atoms to the molecule
ethylbcnzcne: 8 percent.
01140-05149

-~
~
,—.—s4—4
142
~2
-4—
~—.
1
-~
i_~
percent.
“-Pigmented coatings” means opaque
coatings containing
b-inders and colored pigments which are formulated to
conceal the wood surface either as an undercoat or
topcoat--
mr’i
.~1_1
_~4~
_____________________________________________
c.thich
belong
to- the
same industrial grouping, are
located on one or more contiguous or adjacent
riroricri-~ir’~-~
rind
ri-p-~±
nndr~r thr~ r~ontro1 of thc~ ~irimc~
iii--ii-r~-—r’mitting
~
person (or
persons under
common control), except the
activities of any
marine vessel. Pollutant—emitting
activities shall b-c considered as part of the same
industrial grouping if they belong to the same “Major
Croup” (i.e., which have the same two—digit code) as
described in the “Standard Industrial Classification
Manual, l~337” (incorporated by reference in Section
218.112).
“Plasticizers” means
a substance added to a polymer
composition to soften and add flexibility to the
product.
“Pneumatic Rubber Tire Manufacture” means the
‘a~
~
‘4-4-’.’
~.
_L ~.‘S S
-‘-a
~.I
£.
nri~umatie‘ubber
tires with a bead
diameter up to but not including ~u.u
incne~ anu cro~.
section dimension up to 12.8 inches, but not including
specialty tires for antique or other vehicles
when
pL-o~uccu OH
~guipn’~cit~
~epuL~uLc
trom normui
pLOuUULiOfl
lines for passenger or truck type tires.
“Polystyrene Plant” means any plant using styrenc to
manufacturo
nnlv
vrc~nr~ rr~in..
substance consisting of
s-tyrenc poiymcr and additives which is manufactured at
a polystyrene plant.
“Pressure Release” means the
emission of materials
resulting
from system pressure being greater than set
pressure of the pressure relief device.
01140-0550
Resin”
“Pressure Tank” means a tank in which fluids arc stored
at a pr~”~
~
applied to a surface.

143
areas on the surface of automobile or light-duty truck
bodies not adequately covered by the prime coat before
application of the top coat. The prime surfacer coat
is applied between the prime coat and topcoat. An
anti-chip coating applied to main body parts (e.g.,
rocker panels, bottom of door-s and fenders, and leading
edge of roof) is a prime surfacer coat.
“Primers” means any coatings formulated and applied to
substrates to provide
a firm bond between the substrate
and subsequent coats.
“Printing” means the application of words, designs, and
pictures to a substrate using ink.
operation consisting
-of
sen
-ef
~1 pnint~
~A18-
rY’-’
roll coaters, drying areas, and ovens wherein one or
more coatings are applied, dried, and/or cured.
“Process” means any stationary emission source other
than a fuel combustion emission source or an
i
nc~i
nr~rritnr
-
“Process Unit” means components assembled to produce,
as intermediate or final products, one or more of the
‘ode 213 Appendix A.
-~
_t
~dcntly-~
supplied
~,44.i..
sufficient ~ecd or raw materials and
‘~‘~~4-
~
faciliti~s for the produc~.
~-
‘‘LILLL.UUJ.L,
4.. i~,
Lt1
I El
~)
-
J~tIlU
-
TiTO~’1’~
ni-iit
riin
~Ti~Tr’
-I
‘T1
r’
Ti
-
“Process Unit Shutdown” means a work
practice or
opcrationalprocedurc
that stops production from a
process unit or
part of a process unit. An unscheduled
work practice or
operational procedure that stop-s
production from
a process unit or
part of a process
unit for less than 24
hours is not
a process unit
shutdown. The usc of spare components and technically
feasible bypassing of components without stopping
production is not a process
unit shutdown.
“Production equipment exhaust
system” means
a system
for collecting and
directing into the atmosphere
emissions of volatile organic material from reactors,
centrifuges,
and other process emission sources.
“Publication rotogravure printing li-ne” means a
rotogravure printing line in which coatings are applied
~o paper which is subsequently formed into books,
magazines, catalogues, brochures, directories,
news~a~ersupplements, or other types of printed
material.
01140-0551

144
“Purged Process Fluid” means liquid or vapor from a
process unit that
contains volatile organic material
and that results from flushing or cleaning the sample
-1-me(s) of
a process unit so that an uncontaminated
sample may then be taken for testing or analysis.
“Reactor” means
a vat, vessel, or other device- in which
chemical reactions
take
place.
“Reasonably Available Control Technology (RACT)” means
fhr’
1 rit~rr’~t ,~m
~
i i—in 1 i
m
i
~—rif—
i
on t~h.—t ~i n r’m
i
~-‘~
i
on —~
rinrcir’
is capable of meeting by the appl-icati~5i contro~
technology that is reasonably available considering
technological and economic feasibility.
“Refiner” means any person who owns, leases, operates,
controls, or supervises a refinery.
-
“Refinery Fuel Gas”
-‘
notro1c~uiii
r~finor~
means any gas which
is
~
nnit rind
which
generated
is
by
.1
combusted at the refinery, including any gaseous
mixture of natural gas and fuel gas.
“Refinery unit, process unit or unit” means a set
of
components which arc a
part
-of a basic process
operation such
as distillation, hydrotr-cating,
cracking, or reforming of hydrocarbons.
“Refrigerated condenser” means a
surface condenser in
whir~h thr~ r~no1rint ~iinn1
—--i-
ir~l tn thr- prindr~n’~r’r hri~ hr~r-n
cooled by a mechanical device, other than by a cooling
tower
or evaporative spray cooling, such as
rofri ri~rriti on uni 1— or ‘~vt-orim t-,hi
11
r’r
unit -
“Reid vapor pressure” m
the vapor pressure of a
cans the standardized measure of
liquid in pounds per square
inch absolute (Psia) at
100°F (37.8°C)-.
“Repair coatings” means coatings used to correct
imperfections or damage to furniture surface.
-c-i
• -
Sit
.“~posc of Subpart
Q
of this
4-
14~k.1~~~
,Th -s.’ -.
___________________________________
Part, that
..._..~
~
~_
~
~.
~
~
-adjusted,
otherwise
altered, to eliminate a leak.
“Residual Fuel Oil” means fuel oils of grade No. 4, 5
and 6 as specified in detailed requirements for fuel
oils A.C.T.N. D—396 69 (1971).
“Retail Outlet” means any gasoline dispensing facility
at which gasoline is sold or offered for sale for use
01140-0552

__J__~__
~
_-.
145
“Roll coater” means an apparatus in which a uniform
layer of coating is applied by means of one or more
rolls across the entire width of a moving substrate.
“Roll printer” means an apparatus used in the
application of words, designs, and pictures to a
-substrate, usually by means of one or more rolls each
with only partial coverage.
“Roll printing” means the application of words,
designs, and pictures to a substrate usually by means
of a series of hard rubber or metal rolls each with
only partial coverage.
“Po~l1r~rcoating”
mc’nn~
mrthriri of rinn1~inri
r~oriting
to a sneer or strip in which the coating is transterred
by a roller or series of rollers.
“Rolling limit” means that a limit or limitation must
not exceed an annual limit rolled on a basis of at most
a month monthly basis; that is, for example, a monthly
production or capacity level
must be determined for
each parameter subject to a production or capacity
limitation and added
to the eleven prior monthly levels
for monthly comparison with the annual limit.
“Rotogravure printing” means the application of words,
designs, and pictures to a substrate by means of a roll
printing technique in which the pattern to be applied
is recessed relative to the non-image area.
“Rotogravure printing line” means a printing line in
which each
roll printer uses a roll with recessed areas
-for applying an image to a substrate.
“Safety relief
valve” means a valve which is normally
e1o~od rind whioh i~d i~~inr~d
to open in
order to
within a vessel or pipe.
“Sanding sealers-” means any
applied to bare wood for
s-a
coatings formulat
nding and to
s-cal
ed
the
for and
wood
for subsequent application
of varnish. To be
considered a sanding sealer
a
coating must be clearly
labelled
.-“
“Sealer” means a coating containing binders which seals
wood prior to the
application of the subsequent
coatings.
“Sensor”
means a device that measures a physical
01140-o553

146
quantity or the change in a physical quantity such as
temperature, pressure, flow rate, pH, or liquid level.
“Semi-transparent stains” means stains containing dyes
or semi-transparent pigments which arc formulated to
enhance wood grain and change the
color of the surface
but not to conceal the surface,
including, but not
limited to, sap stain, toner, non—grain raising stains,
pad stain, or spatter stain.
“Set of safety relief valves” means one or more -safety
relief valves designed to open in order to relieve
excessive pressures in the same vessel or pipe.
“Rh~ot hri~oorit” means
-‘
coating
~
i
r~r
the metal is- in sheet form to serve as either the
exteri.~.. intcri~. ~f a t~.5.
for ci...~
two—pi
three—piece can~
1
r-’r,
-u-ri mr~tri
1
whriru
“Side-scam spray coat” means a coating applied to the
seam of a three—piece can.
“Single coat” means one
coating application applied to
a
metal surface.
“Solvent” means a liquid sub-stance that is used to
dissolve or dilute another substance.
“Solvent cleaning” means the process of cleaning soils
from surfaces by cold cleaning, open top vapor
degreasing, or conveyorizcd dcgreasing.
“Specified air contaminant” means any air contaminant
as to which this Part contains emission standards or
other specific limitations.
“Splash loading” means a method of loading a tank,
railroad tank oar, tank truck, or trailer by use of
other than a submerged loading pipe.
IA
-
7
“Standard cubic foot (s-of)”
i~u.-u’i~
cubic foot
of gas at standard eunui~ions.
“Standard Industrial Classification
Manual” means the
Of
L&O-Ø5514
“Stack” means- a flue or conduit, free—standing or with
exhaust port above the roof
of the building on which it
is mounted, by which
the atmosphere.
air
contaminants are emitted into
“Standard conditions”
moans a temperature of
70°F and a
)yE;IJrr~
of
-
the
.1
volume of

~-
Office, Washington, DC
~
i~incorporuLeu ~iy
i-n Section 218.112).
reference
“Start—up” means the setting in operation of
emission source for any purpose.
“Stationary emission source” mean an emission
an
source
which is not s-elf-propelled.
“~torri~
trin1~
or
storage vessel” means any stationary
tank, reservoir
or container us-cd for the storage
V-GL.
“Styrene Devolatilizer Unit” means equipment performing
the function of separating unrcacted styrene monomer
and other volatile components from polystyrene in a
vric’~uum
dol
rit-~i
1 i ~.or
-
“Styrene
Recovery Unit” means- equipment
performing the
function of separating styrenc monomer from other less
volatile components of the styrenc devolatilizer unit-’s
output. The separated styrcne monomer may be reused as
a raw material in the polystyrene plant.
“Submerged loading pipe” means any discharge pipe or
nozzle which meets either of the following conditions:
Where the tank is filled from the top, the end of
the discharge
pipe or nozzle must be totally
submerged when the liquid level is 15- cm (6 in.)
above the bottom of the tank.
Where the tank is filled from the side, the
discharge pipe or nozzle must be totally submerged
when the liquid level is 46 cm (18 in.) above the
bottom of the tank.
“Substrate” means the surface onto which a coating is
applied or into which a coating is
impregnated.
condenser” means a device which removes
substance from a gas stream by reducing the temperature
of the stream, without direct contact between
the
coolant and the stream.
“Synthetic Organic Chemical
or Polymer Manufacturing
t~lant” means- a
plant that produces, as- intermediates- or
final products, one or more of the chemicals or
polymers listed in 35 Ill. Adm. Code
213 Appendix A.
01140-0555
147
Standard Industrial Classification
~anual
(1937)-,
~
.-~
.~
~J--~
I
- -
Government
— — — —
S..
_1
,_ — —
Printi~

148
“Tablet
coating operation”
means a pharmaceutical
coating operation in which tablets are coated.
“Thirty—day rolling average” means any value
ar ithmet i-cal ly
averaged over any consecutive
thirty-days.
“Three-
can” means a can which is made from a
rectangular sheet and two circular ends.
“Topcoat” means a coating applied in a multiple coat
riri~rri.r.ion
otner than prime coa~
~
repair coat,
sur~--i~-’~-
r.rri+
_i
fl
...__
~A.~
~
~
~
~
~
J
JJ~~
¼SS~
flash-off areas,
and bake ovens at a facility
~
.‘.-.~
which are
I
~
“Transfer efficiency” means the ratio of the amount of
coating solids deposited onto a part or product to the
total amount of coating solids used.
“Tread End Cementing” means the application of a
solvent-based cement to the tire tread ends.
“xrue vapor prcssure means- me equiiiDrium partial
pressure exerted by a volatile organic li-quid as-
determined in accordance with methods- described in
American Petroleum Institute Bulletin 2517,
“Evaporation Loss From Floating Roof Tanks-,”
second
edition, February
1980 -(incorporated by
reference in
Section 218.112).
“Turnaround” means
the procedure of shutting down an
operating refinery unit, emptying gaseous and liquid
contents to do inspection, maintenance and repair work,
and putting the unit back into production.
“Two—piece can” means- a can which is drawn from a
shallow cup and requires only
one end to be attached.
“Undercoaters” means any coatings formulated for and
applied to substrates to provide a smooth surface for
subsequent
coats.
“Undcrtread Cementing” means- the application of a
~o1vcnt based cement
to-
the undcrs-ide
of a tire tread.
~nrcgu1atcd
safety relief
.
valve which
cannot be actuated by a means other tnan
UI 140-0556
m~rin~
safety
1 4
-~e-
~
-dry,
~
the ~
~
~
final off—line
repair) on components of automobile or
light-duty truck bodies.
-

149
high pressure in the pipe or vessel which it protects.
‘~Vacuumproducing system” means any reciprocating-,
rotary, or centrifugal blower or compress-or or any jet
ejector or device that creates suction from a pressure
below atmo~nh~ricand di~-hrir-rc~rioriin~t a areater
pressure.
“Valves not externally regulated” means valves that
have no external controls-, such as in—line check
valves.
“Vapor balance system” means any combi-nation of pipes
or hoses -which creates a closed system between the
vapor s-paces of an unloading tank and a receiving tank
s-uch that vapors displaced from the receiving tank are
transferred to the tank being unloaded.
“Vapor collection system” -means all piping, seals,
hoses, connections, pressure-vacuum vents, and other
possible sources between the gasoline delivery vessel
and the vapor processing unit and/or the storage tanks
and vapor holder.
“Vapor control system” means any system that limits or
prevents release to the atmosphere of organic material
in the vapors displaced from a tank during the transfer
of gasoline.
“Vapor-Mounted Primary Seal” means- a primary seal
mounted with an air space bounded by the bottom of the
primary seal, the tank wall, the liquid surface and the
floating roof.
“Vapor recovery system” means
a vapor gathering system
capable
of collecting all VOM vapors and gas-cc
discharged from the storage tank and
a vapor disposal
system capable of processing such VOM vapors- and gases-
so as- to prevent their emission to the atmosphere.
“Vehicle” means a device by which any person or
property may be propelled, moved,
or drawn upon a
highway, excepting a device moved exclusively by human
power
or used exclusively upon stationary rails or
tracks.
“Vinyl coating” means any topcoat or printing ink
applied to vinyl coated fabric or vinyl sheets. Vinyl
coating does not include plasticols.
“Vinyl coating facility” means a facility that includes
one or more
vinyl coating line(s).
01140-0557

150
“Vinyl coating line” means a coating line in which any
protective, decorative
or functional coating is- applied
e-nmo
vinyl coaceci ra~ric or
v1n~..~L
~neem~-.
“Volatile organic liquid (VOL)” means any substance
which is liquid at storage conditions and which
contains
volatile organic compounds.
“Volatile organic material (VON) -or volatile
organic
compound (VOC)” means “volatile organic material (VON)
o-r volatile organic compound (VOC)”, as that term is
defined in 35 Ill. Adm. Code Part 211.
“Volatile Petroleum Liquid” means any petroleum liquid
with a true vapor pressure that is-
greater than 1.5
p-s-ia (78 millimeters of mercury)
at -standard
conditions.
“Wash coat” means a
coating containing binders which
seals wood surfaces, prevents undesired staining,
and
controls penetration.
“Wastcwater (Oil/Water) Separator” means any device or
1~densityiece ofbetweenequipmentoilwhichand
waterutilizesto removethe
d~fferenceoil
and
i55
associated chemicals- from water, or mv
~evic~ such
a iiocouiamion tank or a clarifier, wnicn removes-
cum
~
~SLI
flLtb~ ~
“Web”-
means a
substrate which is printed in
continuous
~o11—fcd nrccces.
ltWood furniture” means room furnishings including
cabinets- (kitchen, bath, and vanity), tables, chairs,
beds, sofas, shutters, art objects,
wood paneling, wood
-f--boring, and
any other coated furnishings made of
wood, wood
composition, or fabricated wood materials-.
“Woodworking” means- the shaping, sawing, grinding,
smoothing, polishing, and making into products of any
orm or shape of
wood-.
The definitions of 35 Ill. Adm. Code 211 apply
to this Part.
(Source: Amended at
Ill. Reg.
______,
effective
__________
OiL~O-3558
petrol
_.-~,_,~.4-__.
~
“Wood furniture coating faci-lity” means- a facility that
includes one or more wood furniture coating line(s).
“Wood furniture coating line” means- a
coati-ng line in
which any protective, decorative, or functional coating

151
Section 218.105
Test Methods and Procedures
a) Coatings, Inks and Fountain Solutions
The following test methods and procedures shall be used
to determine compliance of ~ applied coatings, inks,
and fountain solutions with the limitations set forth
in this Part.
-
1) Sampling: Samples collected for analyses shall be
one—liter taken into a one—liter container at a
location and time such that the sample will be
representative of the coating as applied (i.e.,
the sample shall include any dilution solvent or
other VON added during the manufacturing process).
The container must be tightly sealed immediately
after the sample is taken. Any solvent or other
VOM added after the sample is taken must be
measured and accounted for in the -calculations in
subsection (a) (3) of this Section. For multiple
package coatings, separate samples of each
component shall be obtained. A mixed sample shall
not be obtained as it will cure in the container.
Sampling procedures shall follow the guidelines
presented in:
A) ASTM D3925-8l(1985) standard practice for
sampling liquid paints and related pigment
coating. This practice is incorporated by
reference in Section 218.112 of this Part.
B)
ASTN E300-86 standard practice for sampling
industrial chemicals. This
practice is
incorporated by reference in Section 218.112
of this Part.
2) Analyses: The applicable analytical methods
specified below shall be used to determine the
composition of coatings, inks, or fountain
solutions as applied.
A)
Method 24 of 40 CFR 60,
Appendix A,
incorporated by reference in
Section 218.112
of this Part, shall be used to
determine the
VOM content and density of coatings. If it
is demonstrated to the satisfaction
of the
Agency and the
USEPA that plant coating
formulation data are equivalent to Method 24
results,
formulation data may be used.
In
the event of any
inconsistency between a
Method 24 test and a
facility’s formulation
data, the Method 24 test will govern.
J
L~i)
5 s

152
B) Method 24A of 40 CFR Part 60, Appendix A,
incorporated by reference in Section 218.112
of this Part, shall be used to determine the
VON content and density of rotogravure
printing inks and related coatings. If it is
demonstrated to the satisfaction of the
Agency and USEPA that the plant coating
formulation data are equivalent to Method 24A
results, formulation data may be used. In
the event of any inconsistency between a
Method 24A test and a facility’s formulation
data, the Method 24A test will govern.
C) The following ASTM methods are the analytical
procedures for determining VON:
i) ASTM Dl475-85:
Standard test method for
density of paint, varnish, lacquer and
related products. This test method is
incorporated by reference in Section
218.112 of this Part.
ii) ASTM D2369-87: Standard test method for
volatile content of a coating. This test
method is incorporated by reference in
Section 218.112 of this Part.
iii) ASTM D3792-86: Standard test method for
water content of water-reducible paints
by direct injection into a gas
chromatograph. This test method is
incorporated by reference in Section
218.112 of this Part.
iv) A5TM D40l7—8l(l987): Standard test
method for water content in paints and
paint materials by the Karl Fischer
method. This test method is incorporated
by reference in Section 218.112 of this
Part.
v) ASTN D4457-85: Standard test method for
determination of dichioromethane and
1,1,1, trichboroethane in paints and
coatings by direct injection into a gas
chromatograph. (The procedure
delineated above can be
used to develop
protocols for any compounds specifically
exempted from the definition of VON.)
This test method is incorporated by
reference in Section 218.112 of this
Part.
OIL&0- 0560

153
vi) ASTM D2697-86: Standard test method for
volume non—volatile matter in clear or
pigmented coatings. This test method is
incorporated by reference in Section
218.112 of this Part.
vii) ASTM D3980—87: Standard practice for
interlaboratory testing of paint and
related materials. This practice is
incorporated by reference in Section
218.112 of this Part.
viii)ASTM E180-85: Standard practice for
determining the precision data of ASTM
methods for analysis of and testing of
industrial chemicals. This practice is
incorporated by reference in Section
218.112 of this Part.
ix) ASTM D2372-85: Standard method of
separation of vehicle from solvent—
reducible paints. This method is
incorporated by reference in Section
218.112 of this Part.
D) Use of an adaptation to any of the analytical
methods specified in subsections (a) (2) (A),
(B), and (C) of this Section may not be used
unless approved by the
Agency
and USEPA. An
owner or operator must submit sufficient
documentation for the Agency and USEPA to
find that the analytical methods specified in
subsections (a) (2) (A), (B), and (C) of this
Section will yield inaccurate results and
that the proposed adaptation is appropriate.
3) Calculations: Calculations for determining the
VON content, water content and the content of any
compounds which are specifically exempted from the
definition of VON of coatings, inks and fountain
solutions as applied shall follow the guidance
provided in the following documents--;
A) “A Guide for Surface Coating Calculation”,
EPA-340/1-86-016, incorporated by reference
in Section 218.112 of this Part.
B) “Procedures for Certifying Quantity of
Volatile Organic Compounds Emitted by Paint,
Ink and Other Coatings” (revised June 1986),
EPA-450/3-84-0l9, incorporated by reference
in Section 218.112 of this Part.
0 I14Q-Q561

154
C)
“A Guide for Graphic Arts Calculations”,
August 1988, EPA-340/1-88—003, incorporated
by reference in Section 218.112 of this Part.
b) Automobile or Light-Duty Truck Test Protocol
fl The protocol for testing, including determining
the
transfer efficiencyT of coating applicators~
at primer surfacer operations and
topcoat coating
operations at an automobile or light-duty truck
assembly facility source shall follow the
procedures in:”Protocol for Determining the Daily
Volatile Organic Compound Emission Rate of
Automobile and Light-Duty Truck Topcoat
Operations” (“topcoat protocol”), December 1988,
EPA-450/3-88-0l8, incorporated by reference in
Section 218.112 of this Part.
21 Prior to testing pursuant to the topcoat protocol,
the owner or operator of a coating operation
subject to the topcoat or primer surfacer limit in
Sections 218.204(a) (2) or 218.204(a) (3) shall
submit a detailed testing proposal specifying the
method by which testing will be conducted and how
compliance will be demonstrated consistent with
the topcoat protocol. The proposal shall include,
at a minimum, a comprehensive plan (including a
rationale) for
determining the transfer efficiency
at each booth through the use of in-plant or pilot
testing, the selection of coatings to be tested
(for the purpose of determining transfer
efficiency) including the rationale for coating
groupings, the method
for determining the analytic
VOM
content of as applied coatings and-the
formulation solvent content of as applied
coatings, and a description of the records of
coating VOM content as applied and coating’s usage
which will be kept to demonstrate compliance.
Upon approval of the proposal by the Agency and
USEPA, the compliance demonstration for a coating
line may proceed.
c) Capture System Efficiency Test Protocols
1)
Applicability
The requirements of subsection (c) (2) of this
Section shall apply to all VON emitting processes
emission units employing capture equipment (e.g.,
hoods, ducts), except those cases noted below.
01 ~0-Q562

155
A) If an source instailsemission unit is
equipped with (or uses) a permanent total
enclosure (PTE) that meets Agency and USEPA
specifications, and which directs all VOM to
a control device, then the sourceemission
unit is exempted from the requirements
described in subsection (c) (2) of this
Section. The Agency and USEPA specifications
to determine whether a structure is
considered a PTE are given in Procedure T of
Appendix B of this Part. In this instance,
the capture efficiency is assumed to be 100
percent and the sourceemission unit is still
required to measure control efficiency using
appropriate test methods as specified in
subsection (d) of this Section.
B) If an source uses-emission unit is equipped
with (or uses) us-cs- a control device designed
to collect and recover VON (e.g., carbon
adsorber), an explicit measurement of capture
efficiency is not necessary provided that the
conditions given below are met. The overall
control of the system can be determined by
directly comparing the input liquid VON to
the recovered liquid VON. The general
procedure for use
in this situation is given
in 40
CFR 60.433,
incorporated by reference
in Section 218.112 of this Part, with the
following additional restrictions:
i) The source must be able to equate
solvent usage with solvent recovery on a
2-4-hour i~daily) basis-, rather than a
30-day weighted average, within 72 hours
following the 24-hour period. In
addition, one
of the following two
criteria must be met: Unless otherwise
specified in subsection (c) (1) (B) (ii)
below, the owner or operator shall
obtain data each operating day for the
solvent
usage and solvent recovery to
permit the determination of the solvent
recovery efficiency of the system each
operating day using a 7-day rolling
period. The recovery efficiency for
each operating day is computed as
the
ratio of the total recovered solvent for
that day and the most recent prior 6
operating days
to the total solvent
usage for the same
7—day period used for
the recovered solvent, rather
than a 30—
at 140-0563

156
day weighted average as given in 40 CFR
60.433 incorporated by reference at
Section 218.112 of this Part. This
ratio shall be expressed as a
percentage. The ratio shall be computed
within 72 hours following each 7-day
period. A source that believes that the
7-day rolling period is not
appropriate
may use an alternative multi—day rolling
p~iodnot to exceed 30 days, with the
approval of the Agency and USEPA. In
addition, the criteria in subsection
(c) (1) (B) (iii) or subsection
(c) (1) (B) (iv) below must be met.
£jJ The owner or operator of the source
engaged in printing located at 350 E.
22nd Street, Chicago, Illinois, shall
obtain data each operating day for the
solvent usage and solvent recovery to
permit the determination of the solvent
recovery efficiency of the system each
operating day using a 14—day rolling
period. The
recovery efficiency for
each operating day is computed as the
ratio of the total recovered solvent for
that day and
the
most recent prior 13
operating
days to the total solvent
usage for the same 14—day period used
for the recovered solvent, rather than a
30-day weighted average as given in 40
CFR 60.433, incorporated by reference in
Section 218.112 of this Part. This
ratio shall be expressed as a
percentage. The ratio shall be computed
within 17 days following each 14-day
period. In addition, the criteria in
subsection Cc) (1) (B) (iii) or subsection
(c) (1) (B) (iv) below must be met.
-i4-)-iii) The solvent recovery system (i.e.,
capture and control system) must be
dedicated to a single coating line,
printing line, or other discrete
activity that by itself is subject to an
applicable VON emission standard,
process
iinc
~e.g., one ~roccss ‘ine
venting to a carbon adsorber system), or
iii)jyj If the solvent recovery system controls
more than one coating line, printing
line or other discrete activity that by
0t140-Q5614

157
itself is sublect
to an applicable VON
emission standard, the overall control
(i.e. the total recovered VON divided by
the sum of liquid VON input from all
lines and other activities venting to
the control system) must meet or exceed
the most stringent standard applicable
to any line or other discrete activity
venting to the control system.multiplc
process lines, then the source must be
able to demonstrate that the overall
r~nn1—rr-,1 ( i
-
-
thr’ tr~tm
1 rr~rr’r~
solvent VON divided by th~ of liquid
VON input to all process lines venting
to the control system) meets or exceeds
the most stringent standard applicable
for any process line venting to the
control system.
2)
Specific Requirements
The capture efficiency of a~process lineemission
unit shall be measured using one of the four
protocols given below. Any error margin
associated with a test protocol may not be
incorporated into the results of a capture
efficiency test. If these techniques are not
suitable for a particular process, then the source
may usc an alternative capture efficiency protocol
may be used, provided that the
alternative
protocol is approved by the Agency and approved by
the USEPA as a SIP revision.
A) Gas/gas method using temporary total
enclosure (TTE). The Agency and
USEPA
specifications to determine whether a
temporary enclosure is considered a TTE are
given in Procedure T of Appendix B of this
Part. The capture efficiency equation to be
used for this protocol is:
CE
=
Gw/(Gw
+
Fw)
where:
CE
=
.ceapture efficiency, decimal
fraction~
Gw
=
~mass of VOM captured and delivered
to control device using a TTE~
Fw
=
~mass of fugitive VON that escapes
01140-0565

158
from a TTE.
Procedure G.2 contained in Appendix B of this
Part is used to obtain Gw. Procedure F.1 in
Appendix B of this Part is used to obtain Fw.
B) Liquid/gas method using TTE. The Agency and
USEPA specifications to determine whether a
temporary enclosure is considered a
TTE are
given in Procedure T of Appendix B of this
Part. The capture efficiency equation to be
used for this protocol is:
CE
=
(L
Fw)/L
where:
CE
=
Ceapture efficiency, decimal
fract i on~
L
=
~mass of liquid VOM input to
process emission unit
Fw
=
M~assof fugitive VON that escapes
from a TTE~
Procedure L contained in Appendix B of this
Part is used to obtain L. Procedure F.1 in
Appendix B of this Part is used to obtain Fw.
C) Gas/gas method using
the
building or room
(building or room enclosure)~ in which the
affected coating line, printing line or other
sourccemiss ion unit is 1ocated~as the
enclosure and in which “F” and “G” are
measured while operating only the affected
line or facilityemission unit. All fans and
blowers in the building or room must be
operated as they would under normal
production. The capture efficiency equation
to be used for this protocol is:
CE
=
G/(G + FB)
where:
CE
=
~eapture efficiency, decimal
fract ion~
G
=
~mass of VON captured and delivered
to control device~
011400566

159
FB
=
~mass of fugitive VON that escapes
from building enc1osure~
Procedure G.2 contained in Appendix B of this
Part is used to obtain G. Procedure F.2 in
Appendix B of this Part is used to obtain F8.
D) Liquid/gas method using the building or room
(building or room enclosure)~ in which the
affected coating line, printing line or other
s-ourceejnission unit is located~as the
enclosure and in which “F” and “L” are
measured while operating only the affected
line or facilityemission unit. All fans and
blowers in the building or room must be
operated as they would under normal
production.
The capture efficiency equation
to be used for this protocol is:
CE
=
(L
-
FB)/L
where:
CE
=
ceapture efficiency, decimal
fractionj.
L
=
amass of liquid VON input to
process emission unit
F8
=
~mass of fugitive VON that escapes
from building enc1osure~
Procedure L contained in Appendix B of this
Part is used to obtain L. Procedure F.2 in
Appendix B of this Part is used to obtain FB.
3) Recordkeeping and Reporting
A) All affected facilities-owners or oPerators
affected by this subsection must maintain a
copy of the capture efficiency protocol
submitted to the Agency and the USEPA on
file. All results of the appropriate test
methods and capture efficiency protocols must
be reported to the Agency within sixty (60)
days of the test date. A copy of the results
must be kept on file with the source for a
period of three (3) years.
B) If any changes are made to capture or control
equipment, then the
source
is required to
notify the Agency and the USEPA of these
011400567

160
changes and a new test may be required by the
Agency or the USEPA.
C) The source must notify the Agency 30 days
prior to performing any capture efficiency or
control test. At that time, the source must
notify the Agency which capture efficiency
protocol and control device test methods will
be used.
D) Sources utilizing a PTE must demonstrate that
this enclosure meets the requirement given in
Procedure T (in Appendix B of this Part) for
a PTE during any testing of their control
device.
E) Sources utilizing a TTE must demonstrate that
their TTE meets the requirements given in
Procedure T (in Appendix B of this Part) for
a TTE during testing of their control device.
The source must also provide documentation
that the quality assurance criteria for a TTE
have been achieved.
d)
Control Device Efficiency Testing and Monitoring
1) The control device
efficiency shall be determined
by simultaneously measuring the inlet and outlet
gas phase VOM concentrations and gas volumetric
flow rates in accordance with the gas phase test
methods specified in subsection (f) of this
Section.
2) Any owner or operator~
~j ~That uses an afterburner or carbon adsorber
to comply with any Section of this Part ~
shall use Agency and USEPA approved
continuous monitoring equipment which is
installed, calibrated, maintained, and
operated according to vendor specifications
at all times the afterburner or carbon
adsorber is in use except as provided in
subsection (d) (3) of this Section. The
continuous monitoring equipment must monitor
the following parameters:
A-)- il For each afterburner which does not have
a catalyst bed, the ~combustion
chamber
temperature of each afterburner.
B-)- jjJ For each
afterburner which has a
0_I 140-0568

161
catalyst bed, commonly known as a
catalytic afterburner, the ~emperature
rise across each catalytic afterburner
bed or VON concentration of exhaust.
£-)-
iii) For
each carbon adsorber, ~the VON
concentration of each carbon adsorption
bed exhaust or the exhaust of the bed
next in sequence to be desorbed.
~J Of an automobile or bight-duty truck primer
surfacer operation or topcoat operation
subject to subsection (d) (2)
(A) above, shall
keep a
separate record of the following data
for the control devices, unless alternative
Provisions are set forth in a permit pursuant
to Title V of the Clean Air Act:
il
For
thermal afterburners for which
combustion chamber temperature is
monitored, all 3—hour periods of
operation in which the average
combustion temperature was more than
28°C (50°F) below the average combustion
temperature measured during the most
recent performance test that
demonstrated that the operation was in
compliance.
j~J. For catalytic afterburners for which
temperature rise is
monitored, all
3-hour periods of operation in which the
average gas temperature before the
catalyst bed is more than 28°C (50°F)
below the average gas temperature
immediately before the catalyst bed
measured during the most recent
performance test that demonstrated that
the
operation was in compliance.
iii) For catalytic afterburners and carbon
adsorbers for which VON concentration is
monitored, all 3—hour periods of
operation during which the average VOM
concentration or the reading of organics
in the exhaust gases is more than 20
percent greater than the average exhaust
gas concentration or reading measured by
the organic
monitoring device during the
most recent determination of the
recovery efficiency of a carbon adsorber
or performance test for
p
catalytic
01110-0569

162
afterburner, which determination or test
demonstrated that the operation was in
compliance.
~J. An owner or operator that uses a carbon adsorber
to comply with Section 218.401 of this Part may
operate the adsorber during periods of monitoring
equipment malfunction, provided that:
~j The owner or operator notifies in writing the
Agency and
USEPA within, 10 days after the
conclusion of any 72 hour period
during which
the adsorber is operated and the associated
monitoring equipment is not operational, of
such monitoring equipment failure and
provides the duration of the malfunction, a
description of the repairs made to the
equipment, and the total to date of all hours
in the calendar year during which the
adsorber was operated and the associated
monitoring equipment was not operationaU
~j During such period of malfunction the
adsorber is operated using timed sequences as
the basis for periodic regeneration of the
adsorber
~j The period of such adsorber operation does
not exceed
360 hours in any calendar year
without the approval of the Agency and USEPA
and
pj The total of all hours in the calendar year
during which the adsorber was operated and
the associated
monitoring equipment was not
operational shall be reported, in writing~ to
the Agency and
USEPA by JanuarY 31st of the
following calendar year.
e)
Overall Efficiency
1) The overall efficiency of the emission control
system shall be determined as the product of the
capture system efficiency and the control device
efficiency or by the liquid/liquid
test protocol
as specified in
40 CFR 60.433, incorporated by
reference in Section 218.112 of this Part, (and
revised by subsection (c) (1) (B) of this Section)
for each solvent recovery system. In those cases
in which the overall efficiency is being
determined for an entire line, the capture
efficiency used to calculate the product of the
01140-0570

163
capture and control efficiency is the total
capture efficiency over the entire line.
2) For coating lines which are both chosen by the
owner or operator to comply with Section
2l8.207-(-a-)-~gj, (d), (e), (f), or (g) of this Part
by the alternative in Section 218.207(b) (2) ~
this Part and meet the criteria allowing them to
comply with Section 218.207 of this Part instead
of Section 218.204 of this Part, the overall
efficiency of the capture system and control
device, as determined by the test methods and
procedures specified in subsections (c), (d) and
(e) (1) of this Section, shall be no less than the
equivalent overall efficiency which shall be
calculated by the following equation:
E
=
(VOMa
-
VOM1/VONa) x 100
where:
E
=
Equivalent overall efficiency of the
capture system and control device as a
percentage-~j
VONa
=
Actual VON content of a coating, or the
daily-weighted average VON content of
two or more coatings (if more than one
coating is used), as applied to the
subject coating line as determined by
the applicable test methods and
procedures specified in subsection (a)
of this Section in units of kg VOM/l
(lb VOM/gal) of coating solids as
VOH~1= The
app 1
VOM
ied7~
emission limit specified in
Sections 218.207(a) or (b) 218.204 or
218.205 of this Part in units of kg
VOM/l (lb VOM/gal) of coating solids as
applied.
f) Volatile Organic Material Gas Phase Source Test Methods
The methods in 40
CFR Part
60, Appendix A, incorporated
by reference in Section 218.112 of this Part delineated
below shall be used to determine control device
efficiencies.
1) 40 CFR Part 60, Appendix A, Method 18, 25 or 25A,
incorporated by reference in Section 218.112 g~
this
Part as appropriate
to the conditions at the
01140-0571

164
site, shall be used to determine VOM
concentration. Method selection shall be based on
consideration of the diversity of organic species
present and their total concentration and on
consideration of the potential presence of
interfering gases.
Except as indicated in
subsections (f) (1) (A) and (B) below, the test
shall consist of three separate runs, each lasting
a minimum of 60 mm, unless the Agency and the
USEPA determine that process variables dictate
shorter sampling times.
A) When the method is to be used to determine
the efficiency of a carbon adsorption system
with a common exhaust stack for all the
individual adsorber vessels, the test shall
consist of three separate runs, each
coinciding with one or more complete
sequences through the adsorption cycles of
all the individual adsorber vessels.
B) When the method is to be used to determine
the efficiency of a carbon adsorption system
with individual exhaust stacks for each
adsorber vessel, each adsorber vessel shall
be tested individually. The test for each
adsorber vessel shall consist of three
separate runs. Each run shall coincide with
one or more complete adsorption cycles.
2) 40 CFR Part 60, Appendix A, Method 1 or lA,
incorporated by reference in Section 218.112 ~
this Part, shall be used for sample and velocity
traverses.
3) 40 CFR Part 60, Appendix A, Method 2, 2A, 2C or
2D, incorporated by reference in Section 218.112
of this Part, shall be used for velocity and
volumetric flow rates.
4) 40 CFR Part 60, Appendix A, Method 3, incorporated
by reference in Section 218.112 of this Part,
shall be used for gas analysis.
5) 40 CFR Part 60, Appendix A, Method 4, incorporated
by reference in Section 218.112 of this Part,
shall be used for stack gas moisture.
6’) 40 CFR Part 60, Appendix A, Methods 2, 2A, 2C, 2D,
3 and
4, incorporated by reference in
Section
218.112 of
this Part, shall be performed, as
applicable, at least
twice during each test run.
0 R0-0572

165
7) Use of an adaptation to any of the test methods
specified in subsections (f) (1), (2)
,
(3), (4)
(5) and (6) of this Section may not be used unless
approved by the Agency and the USEPA on a case by
case basis. An owner or operator must submit
sufficient documentation for the Agency and the
USEPA to find that the test methods specified in
subsections (f)(l), (2), (3), (4), (5) and (6) ~
this Section will yield inaccurate results and
that the proposed adaptation is appropriate.
g) Leak Detection Methods for Volatile Organic Material
Owners or operators required by this Part to carry out
a leak detection monitoring program shall comply with
the following requirements:
1) Leak Detection Monitoring
A) Monitoring shall comply with
40 CFR 60,
Appendix A, Method 21, incorporated by
reference in Section 218.112 of this Part.
B) The detection instrument shall meet the
performance criteria of Method 21.
C)
The instrument shall be calibrated before use
on each day of its use by the methods
specified in Method 21.
D) Calibration gases shall be:
i)
Zero air (less than lOppin of hydrocarbon
in air); and
-
ii) A mixture of methane or n—hexane and air
at a concentration of approximately, but
no less than, 10,000 ppm methane or
n—hexane.
E) The instrument
probe shall be traversed
around all
potential leak interfaces as close
to the
interface as possible as described in
Method 21.
-
2) When equipment is
tested for compliance with no
detectable emissions as required, the test shall
comply with the following requirements:
A) The requirements of subsections (g)(1)(A)
through (g) (1) (E) of this Section above shall
apply.
0I~0-O573

166
B) The background level shall be determined as
set forth in Method 21.
3)
Leak detection tests shall be performed consistent
with:
A) “APTI Course SI 417 controlling Volatile
Organic Compound Emissions from Leaking
Process Equipment”, EPA-450/2-82—015,
incorporated by reference in Section 218.112
of this Part.
B) “Portable Instrument User’s Manual for
Monitoring VOC Sources”, EPA-340/l-86-015,
incorporated by reference in Section 218.112
of this Part.
C)
“Protocols for Generating Unit-Specific
Emission Estimates for Equipment Leaks of VOC
and VHAP”,
EPA-450/3-88-OlO, incorporated by
reference in Section 218.112 of this Part.
D)
“Petroleum Refinery Enforcement Manual”,
EPA-340/l-80-008, incorporated by reference
in Section 218.122218.112 of this Part.
h) Bulk Gasoline Delivery System Test Protocol
1) The method
for determining the emissions of
gasoline from a vapor recovery system are
delineated in 40 CFR 60,
Subpart XX,
Section
60.503, incorporated by reference in Section
218.112 of this Part.
2) Other tests shall be performed consistent with:
A) “Inspection Manual for Control of Volatile
Organic Emissions from Gasoline Marketing
Operations: Appendix D”, EPA-340/l—80-0l2,
incorporated by reference in Section 218.112
of this Part.
B) “Control of Hydrocarbons from Tank Truck
Gasoline Loading Terminals: Appendix A”,
EPA-450/2—77-026, incorporated by reference
in Section 218.112 of this Part.
i) Notwithstanding other requirements of this Part, upon
request of the Agency where it is necessary to
demonstrate compliance, an owner or operator of an
emission source unit which is subject to this Part
shall, at his own expense,
conduct
tests in
accordance
0(140-05714

167
with the applicable test methods and procedures
specific in this Part. Nothing in this Section shall
limit the authority
of the USEPA pursuant to the Clean
Air Act, as amended, to
require testing.
jj. Stage II
Gasoline Vapor Recovery Test Methods
The methods for determining the acceptable
performance
of Stage II Gasoline Vapor Recovery System are
delineated in “Technical Guidance-Stage II Vapor
Recovery Systems for Control of Vehicle Refueling
Emissions at Gasoline Dispensing Facilities,” found at
EPA 450/3-91-022b and incorporated by reference in
Section 218.112 of this Part. Specifically, the test
methods are as follows:
fl
Dynamic Backpressure Test is a test procedure used
to determine the pressure drop (flow resistance)
through balance vapor collection and control
systems (including nozzles, vapor hoses, swivels,
dispenser piping, and underground piping) at
prescribed flow rates.
21
Pressure Decay/Leak Test is a test procedure used
to quantify the vapor tightness of a vapor
collection and control system installed at
gasoline dispensing facilities.
~J
Liquid Blockage Test is a test procedure used to
detect low points in any vapor collection and
control system where condensate may accumulate.
(Source: Amended at
Ill. Reg.
______,
effective
__________)
Section 218.106
Compliance Dates
a) Compliance with the requirements of all rules is
required by July, 1991, or September 1, 1991, for all
sources located in Cook, DuPage, Kane, Lake, McHenry or
Will Counties, consistent with the appropriate
provisions of Section 218.103 of this Part.
b) Compliance with the requirements of this Part is
required by November 15, 1993, for all sources located
in Aux Sable Township or Goose Lake Township in Grundy
County or in Oswego Township in Kendall County.
(Source: Amended at
Ill. Reg.
______,
effective
_________)
Section 218.107
Operation of Afterburners
The operation of any natural gas fired afterburner and capture
0! 110-0575

168
system used to comply with this Part is not required during the
period of November 1 of any year to April 1 of the following year
provided that the operation of such devices is not required for
purposes of occupational safety or health, or for the control of
toxic substances, odor nuisances, or other regulated pollutants.
(Source: Amended at
Ill. Reg.
______,
effective
__________)
Section 218.109
Vapor Pressure of Volatile Organic Liquids
a) If the VOL consists of only a single compound, the
vapor pressure shall be determined by ASTM Method
D2879-86 (incorporated by reference in Section 218.112
of this Part) or the vapor pressure may be obtained
from a published sourcepublication such as: Boublik,
T., V. Fried and E. Hala, “The Vapor Pressure of Pure
Substances,” Elsevier Scientific Publishing Co., New
York (1973); Perry’s Chemical Engineer’s Handbook,
McGraw-Hill Book Company (1984); CRC Handbook of
Chemistry and Physics, Chemical Rubber Publishing
Company (1986-87); and Lange’s Handbook of Chemistry,
John A. Dean, editor, McGraw-Hill Book Company (1985).
b) If the VOL is a mixture, the vapor pressure shall be
determined by ASTM Method D2879—86 (incorporated by
reference in Section 218.112) or by the following
equation:
n
E P~ X~
i=1
where:
n
==
NumberTotal
vaporof
componentspressure
ofin
thethe mixture~1mixture7~
i
=
Subscript denoting an individual
componentTi.
P~
=
Vapor pressure of a component determined
in accordance with Subpart A of this-
Partsubsection (a) of this Section
=
Mole fraction of the component in the
total mixture.
(Source: Amended at
Ill. Reg.
_____,
effective
___________
Section 218.110
Vapor Pressure of Organic Material or Solvent
01140-0576

169
a) If the organic material or solvent consists of only a
single compound, the vapor pressure shall be determined
by ASTM Method D2879-86 (incorporated by reference in
Section 218.112 of this Part) or the vapor pressure may
be obtained from a published source publication such
as:
Boublik, T., V. Fried and E. Hala, “The Vapor
Pressure of Pure Substances,” Elsevier Scientific
Publishing Co., New York (1973); Perry’s Chemical
Engineer’s Handbook, McGraw—Hill Book Company (1984);
CRC Handbook of Chemistry and Physics, Chemical Rubber
Publishing Company (1986—87); and Lange’s Handbook of
Chemistry, John A. Dean, editor, McGraw-Hill Book
Company (1985).
b) If the organic material or solvent is in a mixture made
up of both organic material compounds and compounds
which are not organic material, the vapor pressure
shall be determined by the following equation:
n
E P~ X~
Pvom P
=
i=l
n
E
1=1
where:
~om
=
Total vapor pressure of the portion of
the mixture which is composed of organic
material-7-~
n
=
Number of organic material components in
the mixtureTl
i
Subscript denoting an individual
component-~j,
=
Vapor pressure of an organic material
component determined in accordance with
Subpart A of this- Part subsection (a) of
this Section-i-
X~
=
Mole fraction of the organic material
component of the total mixture.
C)
If the organic
material or solvent is in a mixture made
up of only organic material compounds, the vapor
pressure shall be determined by ASTM Method D2879—86
(incorporated by reference in Section 218.112 of this
Part) or by the above equation.
01140-0577

170
(Source: Amended at
Ill. Reg.
______,
effective
_________)
Section 218.111
Vapor Pressure of Volatile Organic Material
a) If the VOM consists of only a single compound, the
vapor pressure shall be determined by ASTM Method
D2879-86 (incorporated by reference in Section 218.112
of this Part) or the vapor pressure may be obtained
from a published sourcepublication such as: Boublik,
T., V. Fried and E. Hala, “The Vapor Pressure of Pure
Substances,” Elsevier Scientific Publishing Co., New
York (1973); Perry’s Chemical Engineer’s Handbook,
McGraw-Hill Book Company (1984); CRC Handbook of
Chemistry and Physics, Chemical Rubber Publishing
Company (1986-87); and Lange’s Handbook of Chemistry,
John A. Dean, editor, McGraw-Hill Book Company (1985).
b) If the VON is in a mixture made up of both VOM
compounds and compounds which are not VON, the vapor
pressure shall be determined by the following equation:
n
E
E~
~vom
=
i=l
n
E X~
i= 1
where:
~vOrn
=
Total vapor pressure of the portion of
the mixture which is composed of VOMTI
n
=
Number of VON components in the
mixtureT~
i
=
Subscript denoting an individual
component-7-~
=
Vapor pressure of a VON component
determined in accordance with Subpart A
of this Part subsection (a) of this
Section-7-~
=
Mole fraction of the VOM component of
the total mixture.
c)
If the VON is in a mixture made up of only VON
compounds, the vapor pressure shall be determined by
ASTM Method D2879-86 (incorporated by reference in
Section 218.112 of this Part) or by the above equation.
01140-0578

171
(Source: Amended at
Ill. Reg.
______,
effective
__________)
Section 218.112
Incorporations by Reference
The following materials are incorporated by reference and do not
contain any subsequent additions or amendments:
a) American Society for Testing and Materials, 1916 Race
Street, Philadelphia, PA 19103:
1) ASTM D2879—86
2)
ASTM D323—82
3)
ASTM D86—82
4) ASTM D—369—69 (1971)
5)
ASTM
D—396—69
6) ASTM D2880—7l
7) ASTM D—975—68
8) ASTM D3925—81 (1985)
9)
ASTM E300—86
10) ASTM D1475—85
11) ASTM D2369—87
12) ASTM D3792—86
13) ASTM D4017—8l (1987)
14) ASTM D4457—85
15) ASTM D2697—86
16) ASTM D3980—87
17) ASTM E180—85
18) ASTM D2372—85
19) ASTM D97—66
20) ASTM E—l68—67 (1977)
21) ASTM
E—169—87
22)
ASTM E—260—91
23) ASTM D2504—83
24) ASTM D2382—83
~j ASTM D323—82 (approved 1982)
b) Standard Industrial Classification Manual, published by
Executive Office of the President, Office of Management
and Budget, Washington, D.C., 1987.
c) American Petroleum Institute Bulletin 2517,
“Evaporation Loss From Floating Roof Tanks”, Second
ed., February, 1980.
d) 40 CFR Part 60 (July 1, 10901991) and 40 CFR 60,
Appendix A, Method 24 (57 FR 30654, July 10, 1992).
e) 40 CFR Part 61 (July 1, 19901991)
f) 40 CFR Part 50 (July 1, 19891991)
g) 40 CFR Part 51 (July 1, 19891991)
01140-0579

172
h) 40 CFR Part 52 (July 1, 19891991)
j) 40 CFR Part 80 (July 1, 1991).
4~jj “A Guide for Surface Coating Calculation”, United
States Environmental Protection Agency, Washington,
D.C., EPA—340/l—86—016.
~-fl~j
“Procedures for Certifying Quantity of Volatile Organic
Compounds Emitted by Paint. Ink and Other Coating”,
(revised June 1986), United States Environmental
Protection Agency, Washington D.C., EPA-450/3-84—0l9.
~~)jj “A Guide for Graphic Arts Calculations”, August 1988,
United States Environmental Protection Agency,
Washington D.C., EPA-340/1—88-003.
-1~~“Protocol for Determining the Daily Volatile Organic
Compound Emission Rate of Automobile and Light-Duty
Truck Topcoat Operations”, December 1988, United States
Environmental Protection Agency, Washington D.C.,
EPA—450/3—88—0l8.
m)~fl.. “Control of Volatile Organic Emissions from
Manufacturing of Synthesized Pharmaceutical Products”..~
United States Environmental Protection Agency,
Washington, D.C., EPA-450/2—78—029.
~)~j “Control of Volatile Organic Compound Leaks from
Gasoline Tank Trucks and Vapor Collection Systems”,
Appendix B, United States Environmental Protection
Agency, Washington, D.C., EPA-450/2-78-05l.
e)pj “Control of Volatile Organic Compound Emissions from
Large Petroleum Dry Cleaners”, United States
Environmental Protection Agency, Washington, D.C.,
EPA—450/3—82—009.
q~ “APTI Course S1417 Controlling Volatile Organic
Compound Emissions from Leaking Process Equipment”,
United States Environmental Protection Agency,
Washington, D.C., EPA—450/2—82—015.
~j “Portable Instrument User’s Manual for Monitoring VOC
Sources”, United States Environmental Protection
Agency, Washington, D.C., EPA-340/1-86-015.
~j “Protocols for Generating Unit—Specific Emission
Estimates for Equipment Leaks of VOC and VHAP”, United
States Environmental Protection Agency, Washington,
D.C.
,
EPA—450/3—88—0b0.
0 IL1O-0580

173
~j “Petroleum Refinery Enforcement Manual”, United States
Environmental Protection Agency, Washington, D.C.,
EPA—340/1—80—008.
~ “Inspection Manual for Control of Volatile Organic
Emissions from Gasoline Marketing Operations: Appendix
D”, United States Environmental Protection Agency,
Washington. D.C., EPA—340/1—80--012.
yj “Control of Hydrocarbons from Tank Truck Gasoline
Loading Terminals: Appendix A”, United States
Environmental Protection Agency, Washington, D.C.,
EPA—450/2—77—026.
~fl
“Technical Guidance—Stage II Vapor Recovery Systems for
Control of Vehicle Refueling Emissions at Gasoline
Dispensing Facilities”, United States Environmental
Protection Agency, Washington, D.C., EPA-450/3-9l—022b.
~j California Air Resources Board, Compliance Division.
Compliance Assistance Program: Gasoline Marketing and
Distribution: Gasoline Facilities Phase I & II
(October 1988, rev. March 1991) (CARB Manual).
(Source: Amended at
Ill. Reg.
______,
effective
___________)
SUBPART B: ORGANIC EMISSIONS FROM STORAGE AND LOADING OPERATIONS
Section 218.121
Storage Containers
No person shall cause or allow the storage of any VOL with a
vapor pressure of 17.24 kPa (2.5 psia) or greater at 294.3~K
(70°F) or any gaseous organic material in any stationary tank,
reservoir or other container of more than 151 cubic meters
(40,000 gal) capacity unless such tank, reservoir or other
container:
a) Is a pressure tank capable of withstanding the vapor
pressure of such liquid or the pressure of the gas, so
as to prevent vapor or gas loss to the atmosphere at
all times; or,
b) Is designed and equipped with one of the following
vapor loss control devices:
1) A floating
roof
which
rests on
the
surface of
the
VOL
and
is
equipped
with a closure
seal
or
seals
between the roof edge and the tank wall. Such
floating roof shall not be permitted if the VOL
has a vapor pressure of 86.19 kPa (12.5 psia) or
greater at 294.3°K (70°F). No person shall cause
or allow the emission of air contaminants into the
01L1Q~O58I

174
atmosphere from any gauging or sampling devices
attached to such tanks, except during sampling or
maintenance operations.
2) A vapor recovery system consisting of:
A) A vapor gathering system capable of
collecting 85 or more of the uncontrolled
VOM that would be otherwise emitted to the
atmosphere; and,
B) A vapor disposal system capable of processing
such VON so as to prevent its emission to the
atmosphere. No person shall cause or allow
the emission of air contaminants into the
atmosphere from any gauging or sampling
devices attached to such tank, reservoir or
other container except during sampling.
3) Other equipment or means of equal efficiency
approved by the Agency according to the provisions
of 35 Ill. Adm. Code 201, and further processed
consistent with Section 218.108.
(Source: Amended at
Ill. Reg.
______,
effective
__________
Section 218.122
Loading Operations
a) No person shall cause or allow the discharge of more
than 3.6 kg/hr (8 lbs/hr) of organic material into the
atmosphere during the loading of any organic material
from the aggregate
loading
pipes of any loading
-facility area having through-put of greater than 151
cubic meters per day (40,000 gal/day) into any railroad
tank car, tank truck or trailer unless such loading
facilityarea is equipped with submerged loading pipes-i-
~ubmcrgcd fill or a device that is equally effective in
controlling emissions and is approved by the Agency
according to the provisions of 35 Ill. Adm. Code 201,
and further processed consistent with Section 218.108.
b) No person shall cause or allow the loading of any
organic material into any stationary tank having a
storage capacity of greater than 946 1 (250 gal),
unless such tank is equipped with a permanent submerged
loading pipe, submerged fill or an equivalent device
approved by the Agency according to the provisions of
35 Ill. Adm. Code 201, and further processed consistent
with Section 218.108 of this Part, or unless such tank
is a pressure tank as described in Section 218.121(a)
of this Part or is fitted with a recovery system as
described in Section 218.121(b) (2) of this Part.
01L1O_0582

175
c) Exception: If no odor nuisance exists the limitations
of this Section shall only apply to the loading of VOL
with a vapor pressure of 17.24 kPa (2.5 psia) or
greater at 294.3°K (70°F).
(Source: Amended at
Ill. Reg.
______,
effective
__________)
Section 218.123
Petroleum Liquid Storage Tanks
a) The requirements of subsection (b) of this Section
shall not apply to any stationary storage tank:
1) Equipped before January 1, 1979 with one of the
vapor loss control devices specified in Section
218.121(b) of this Part, except Section
218.121(b) (1) of this Part~
2) With a capacity of less than 151.42 cubic meters
(40,000 gal);
3) With a capacity of less than 1,600 cubic meters
(422,400 gal) and used to store produced crude oil
and condensate prior to custody transfer;
4) With a capacity of less than 1,430 cubic meters
(378,000 gal) and used to store produced oil or
condensate in crude oil gathering;
5) Subject to new source performance standards for
storage vessels of petroleum liquid, 35 Ill. Adm.
Code 230 40 CFR 60, as regulations promulgated by
the U.S. Environmental Protection Agency under
Section III of the Clean Air Act (42 USC 7411), as
amended. THE PROVISIONS OF SECTION III OF THE
CLEAN AIR ACT
...
ARE APPLICABLE IN THIS STATE AND
ARE ENFORCEABLE UNDER THE ENVIRONMENTAL
PROTECTION ACT1 (Ill. Rev. Stat. 1991, ch. l1l~,
Par. 1009.1(b)) f415 ILCS 5/9.1(b).
6) In which volatile petroleum liquid is not stored;
or
7) Which is a pressure tank as described in Section
218.121(a) of this Part.
b) Subject to subsection (a) of this Section no owner or
operator of a stationary storage tank shall cause or
allow the storage of any volatile petroleum liquid in
the tank unless:
1)
The tank
is
equipped with one
of the vapor loss
control devices specified in Section 218.121(b) Q1
01140-0583

176
this Part
2) There are no visible holes, tears or other defects
in the seal or any seal fabric or material of any
floating roof;
3) All openings of any floating roof deck, except
stub drains, are equipped with covers, lids or
seals such that:
A) The cover, lid or seal is in the closed
position at all times except when petroleum
liquid is transferred to or from the tank;
B) Automatic bleeder vents are closed at all
times except when the roof is floated off or
landed on the roof leg supports; and
C) Rim vents, if provided, are set to open when
the roof is being floated off the roof leg
supports or at the manufacturer’s recommended
setting;
4) Routine inspections of floating roof seals are
conducted through roof hatches once every six
months;
5) A complete inspection of the cover and seal of any
floating roof tank is made whenever the tank is
emptied for reasons other than the transfer of
petroleum liquid during the normal operation of
the tank, or whenever repairs are made as a result
of any semi—annual inspection or incidence of roof
damage
or
defect; and
6) A record of the results of each inspection
conducted under subsection (b) (4) or (b) (5) g~
this Section is maintained.
c) Owners and operators of petroleum liquid storage tanks
were required to have compliance schedules as
summarized in Appendix C to 35 Ill Adm. Code ~-3~-~.~
Appendix C.
(Source: Amended at
Ill. Reg.
_____,
effective
_________)
Section 218.124
External Floating Roofs
a) In addition to meeting the requirements of Section
218.123(b) of this Part, no owner or operator of a
stationary storage tank equipped with an external
floating roof shall cause or allow the storage of any
01140-05814

177
volatile petroleum liquid in the tank unless:
1) The tank has been fitted:
~)
With a continuous secondary seal extending
from the floating roof to the tank wall (rim
mounted secondary seal)~ or
~)
With aAny other device which controls- VON
emissions with an effectiveness equal to or
greater than a rim mounted secondary
~ea1--eguipment or means of equal efficiency
aPProved by the AQencY according to the
provisions of 35 Ill. Adm. Code 210, and
further processed consistent with Section
218.108 of this Part
2) Each seal closure device meets the following
requirements:
A) The seal is intact and uniformly in place
around the circumference of the floating roof
between the floating roof and
tank wall; and
B) The accumulated area
of gaps exceeding 0.32
centimeter (1/8 inch) in width between the
secondary seal and the tank wall shall not
exceed 21.2 square centimeters per meter of
tank diameter (1.0 square inches per foot of
tank diameter). Compliance with this
requirement shall be determined by:
iL
Physically measuring the length and
width of all gaps around the -entire
circumference of the secondary seal in
each place where a 0.32 cm (0.125 in.)
uniform diameter probe passes freely
(without forcing or binding against the
seal) between the seal and the tank
wall; and
~jJJ.
Summing the area of the individual gaps.
3) Emergency roof drains are provided with slotted
membrane fabric covers or equivalent covers across
at least 90 percent of the area of the opening;
4) Openings are equipped with projections into the
tank which remain below the liquid surface at all
times;
5) Inspections are conducted prior to May 1 of each
01 ~

178
year to insure compliance with subsection (a)
p1
this Section
6) The secondary seal gap is measured prior to May 1
of each year~and within 30 days of a written
request to demonstrate compliance with subsection
(2)(B) of this Section
7) Records of the types of volatile petroleum liquid
stored, the maximum true vapor pressure of the
liquid as stored, the results of the inspections
and the results of the secondary seal gap
measurements are maintained and available to the
Agency, upon verbal or written request, at any
reasonable time for a minimum of two years after
the date on which the record was made.
b) Subsection (a) above does not apply to any stationary
storage tank equipped with an external floating roof:
1) Exempted under Section 218.123(a) (2) through
218.123 (a) (6) of this Part
2) Of welded construction equipped with a metallic
type shoe seal having a secondary seal from the
top of the shoe seal to the tank wall
(shoe—mounted secondary seal);
3) Of welded construction equipped with a metallic
type shoe seal, a liquid—mounted foam seal, a
liquid-mounted liquid-filled-type seal, or other
closure device of equivalent control efficiency
approved by the Agency in which a petroleum liquid
with a true vapor pressure less than 27.6 kPa (4.0
psia) at 294.3°K (70°F) is stored; or
4) Used to store crude oil with a pour point of 50°F
or higher as determined by ASTM Standard D97-66
incorporated by reference in Section 218.112
p1
this Part.
(Source: Amended at
Ill. Reg.
______,
effective
__________
Section 218.125
Compliance Dates (Repealed)
Every owner or operator of an emis-s-ion source subject to 35 Ill.
Adm. Code 215, Subpart B, as- of December 31, 1987 shall have
complied with its standards and limitations- by December 31, 1987.
(Source: Repealed at
Ill. Reg.
______,
effective
_________)
Section 218.126
Compliance Plan (Repealed)
01 1~~.O-Q586

a) The owner or operator of an -emission source previously
subject to Section 215-. 125 shall have submitted to the
Agency a compliance plan as required by 35 Ill. Adm.
Code 201.241, including a project completion schedule
where applicable, no later than April 21, 1983.
b) Unless the submitted compliance plan or schedule was
disapproved by the Agency, the owner or operator of a
facility or emission source subject to the rules
specified in subsection (a) may operate the emission
source according to the plan and schedule as submitted.
c) The p-l~~n4-
~lc shall meet
the rcqui~...ents-of 35
Ill. Adm. Code 201.241 including specific interim date-s
as required in 35 Ill. Adm. Code 201.242.
r.
fr~g~
Amended at
Ill. Reg.
______,
effective
Vapor Blowdown
01140-0587
179
(Source: Repealed at
Ill. Reg.
______,
effective
_________)
SUBPART C: ORGANIC EMISSIONS FROM MISCELLANEOUS EQUIPMENT
Section 218.141
Separation Operations
a) No person shall use any single or multiple compartment
effluent water separator which receives effluent water
containing 757 1/day (200 gal/day) or more of organic
material from any equipment processing, refining,
treating, storing or handling organic material unless
such effluent water separator is equipped with air
pollution control equipment capable of reducing by 85
percent or more the uncontrolled organic material
emitted to the atmosphere. Exception: If no odor
nuisance exists the limitations of this subsection
shall not apply if the vapor pressure of the organic
material is below 17.24 kPa (2.5 psia) at 294.3°K
(70°F)
b) Subsection (a) of this Section shall not apply to water
and crude oil separation in the production of Illinois
crude oil, if the vapor pressure of such crude oil is
less than 34.5 kPa (5 psia).
(Source:
Section 218.143
No person shall cause or allow the emission of organic material
into the atmosphere from any vapor blowdown system or any safety
relief valve, except such safety relief valves not capable of
causing an ‘excessive release, unless such emission is controlled:
a) To 10 ppm equivalent methane (molecular weight 16.0) or
less; or,

180
b) By combustion in a smokeless flare; or,
c) By other air pollution control equipment approved by
the Agency according to the provisions of 35 Ill. Adm.
Code 201, and further processed consistent with Section
218.108 of this Part.
(Source: Amended at
Ill. Reg.
______,
effective
__________)
Section 218.144
Safety Relief Valves
Section 218.143 of this Part shall not apply to any set of
unregulated safety relief valves capable of causing excessive
releases, provided the owner or operator thereof, by October 1,
1972, supplied the Agency with the following:
a) A historical record of each such set (or, if such
records were unavailable, of similar sets which, by
virtue of operation under similar circumstances, may
reasonably have been presumed to have the same or
greater frequency of excessive releases) for a three—
year period immediately preceding October 1, 1972,
indicating:
1) Dates on which excessive releases occurred from
each such
set;
andT
2)
Duration
in minutes of
each such excessive
release; andT
3) Quantities (in pounds) of mercaptans and/or
hydrogen sulfide emitted into the atmosphere
during each such excessive release.
b) Proof, using such three—year historical records, that
no excessive release is likely to occur from any such
set either alone or in combination with such excessive
releases from other sets owned or operated by the same
person and located within a ten—mile radius from the
center point of any such set, more frequently than 3
times in any 12 month period;
c) Accurate maintenance records pursuant to the
requirements of subsection (a) of this Section and,
d) Proof, at three—year intervals, using such three—year
historical records, that such set conforms to the
requirements of subsection (c) of this Section.
(Source:
Amended at
Ill. Reg.
______,
effective
__________)
SUBPART E: SOLVENT CLEANING
01140-0588

181
Section 218.181
Solvent Cleaning in General
The requirements of this Subpart shall apply to all cold
cleaning, open top vapor degreasing, and conveyorized degreasing
operations which use volatile organic materials.
(Source: Amended at
Ill. Reg.
______,
effective
__________)
Section 218.182
Cold Cleaning
a)
Operating Procedures: No
person shall operate a cold
cleaning degreaser unless:
1)
Waste solvent is stored in covered containers only
and not disposed of in
such
a manner that more
than 20 of the waste solvent (by weight) is
allowed to evaporate into the atmosphere;
2) The cover of the degreaser is closed when parts
are not being handled; and
3) Parts are drained until dripping ceases.
b) Equipment Requirements: No person shall operate a cold
cleaning degreaser unless:
1) The degreaser is equipped with a cover which is
closed whenever parts are not being handled in the
cleaner. The cover shall be designed to be easily
operated with one hand or with the mechanical
assistance of springs, counter—weights or a
powered system if:
A) The solvent vapor pressure is greater than 2
kPa (15 mmHg or 0.3 psi) measured at 38°C
(100°F);
B)
The solvent is agitated; or
C)
The solvent is heated above ambient
room
temperature.
2)
The degreaser is equipped with a facilitydevice
for draining cleaned parts. The drainage facility
device shall be constructed so that parts are
enclosed under the cover
while draining unless:
A) The solvent vapor pressure is less than 4.3
kPa (32 mmHg or 0.6
psi) measured at 38°C
(100°F); or
B)
An internal drainage ~acilitydevice
cannot be
UI 140-0589

182
fitted into the cleaning system, in which
case the drainage -~-aeilitydevice may be
external.
3) The degreaser is equipped with one of the
following control devices if the vapor pressure of
the solvent is greater than 4.3 kPa (32 mmHg or
0.6 psi) measured at 38°C(100°F)or if the
solvent is heated above 50°C (120°F) or its
boiling point:
A) A freeboard height of 7/10 of the inside
width of the tank or 91 cm (36 in), whichever
is less; or
B) Any other equipment or system of equivalent
emission control as approved by the Agency
and further processed consistent with Section
218.108 of this Part. Such a system may
include a water cover, refrigerated chiller
or carbon adsorber.
4) A permanent conspicuous label summarizing the
operating procedure is affixed to the degreaser;
and
5) If a solvent spray is used, the degreaser is
equipped with a solid fluid stream spray, rather
than a fine, atomized or shower spray.
(Source: Amended at
Ill. Reg.
______,
effective
_________)
Section 218.183
Open Top Vapor Degreasing
a) Operating Requirements: No person shall operate an open
top vapor degreaser unless:
1) The cover of the degreaser is closed when
workloads are
not being processed through the
degreaser;
2) Solvent carryout emissions are minimized by:
A) Racking parts to allow complete drainage;
B)
Moving parts in and out of the degreaser at
less than 3.3 rn/mm (11 ft/mm);
C) Holding the parts in the vapor zone until
condensation ceases;
D) Tipping
out any pools of solvent on the
01140-0590

183
cleaned parts before removal from the vapor
zone; ~
E) Allowing parts to dry within the degreaser
until visually dry.
3) Porous or absorbent materials, such as cloth,
leather, wood or rope are not degreased;
4) Less than half of the degreaser’s open top area is
occupied with a workload;
5) The degreaser is not
loaded to the point where the
vapor level would drop more than 10 cm (4 in) when
the workload is removed from the vapor zone;
6) Spraying is done below the vapor level only;
7) Solvent leaks are repaired immediately;
8) Waste solvent is stored in covered containers only
and not disposed of in such a manner that more
than 20 of the waste solvent (by weight) is
allowed to evaporate into the atmosphere;
9) Water is not visually detectable in solvent
exiting from the water separator; and
10) Exhaust ventilation exceeding 20 cubic meters per
minute per square meter (65 cubic feet per minute
per square foot) of
degreaser
open area is not
used, unless
necessary to meet the requirements of
the Occupational Safety and Health Act (29 U.S.C.
Section 651 et seq.).
b) Equipment Requirements: No person shall operate an open
top vapor degreaser unless:
1) The degreaser is equipped with a cover designed to
open and close easily without disturbing the vapor
zone;
2) The degreaser is equipped with the following
switches:
A) A deviceOne which shuts off the sump heat
source if the amount of condenser coolant is
not sufficient to maintain the designed vapor
level; and
B) A dcviceQii~which shuts off the spray pump if
the vapor level drops more than 10 cm (4 in)
01140-0591

184
below the bottom condenser coil; and
C)
A deviccOne which shuts off the sump heat
source when the vapor level exceeds the
design level.
3) A permanent conspicuous label summarizing the
operating procedure is affixed to the degreaser;
4) The degreaser is equipped with one of the
following devices:
A) A freeboard height of 3/4 of the inside width
of the degreaser tank or 91 cm (36 in),
whichever is less; and if the degreaser
opening is greater than 1 square meter (10.8
square feet), a powered or mechanically
assisted cover; or
B) Any other equipment or system of equivalent
emission control as approved by the Agency
and further processed consistent with Section
218.108 of this Part. Such equipment or
system may include a refrigerated chiller, an
enclosed design or a carbon adsorption
system.
(Source: Amended at
Ill. Reg.
______
,
effective
_________)
Section 218.184
-
Conveyorized Degreasing
a) Operating Requirements: No person shall operate a
conveyorized degreaser unless:
1) Exhaust ventilation exceeding 20 cubic meters per
minute per square meter (65 cubic feet per minute
per square foot) of area of loading and unloading
opening is not used, unless necessary to meet the
requirements of the Occupational Safety and Health
Act (29 U.S.C. Section 651 et seq.);
2) Solvent
carryout emissions are
minimized by:
A) Racking parts for best drainage; and
B) Maintaining the vertical conveyor speed at
less than 3.3 rn/mm (11 ft/mm);
3) Waste solvent is stored in covered containers only
and not disposed of in such a manner that more
than 20 of the waste solvent (by weight) is
allowed to evaporate into the atmosphere;
01140-0592

185
4) Solvent leaks are repaired immediately;
5) Water is not visually detectable in solvent
exiting from the water separator; and
6) Downtime covers are placed over entrances and
exits of conveyorized degreasers immediately after
the conveyors and exhausts are shut down and not
removed until just before start—up.
b) Equipment Requirements: No person shall operate a
conveyorized degreaser unless:
1) The degreaser is equipped with a drying tunnel,
rotating (tumbling) basket or other equipment
sufficient to prevent cleaned parts from carrying
out solvent liquid or vapor;
2)
The degreaser is equipped with the following
switches:
A) A dcviccQj~which shuts off the sump heat
source if the amount of condenser coolant is
not sufficient to maintain the designed vapor
level;
B) A dcviccOne which shuts off the spray pump or
the conveyor if the vapor level drops more
than 10 cm (4 in) below the bottom condenser
coil; and
C) A dcviccQ~which shuts off the sump heat
source when the vapor level exceeds the
design level~~
3) The degreaser is equipped with openings for
entrances and exits that silhouette workloads so
that the average clearance between the parts and
the edge of the degreaser opening is less than 10
cm (4 in) or less than 10 percent of the width of
the opening;
4) The degreaser is equipped with downtime covers for
closing off entrances and exits when the degreaser
is shut down; and
5)
The degreaser is equipped
with one of
the
following control devices, if the air/vapor
interface is larger than 2.0 square meters (21.6
square feet)
A) A carbon adsorption system with ventilation
01140-0593

186
greater than or equal to 15 cubic meters per
minute per square meter (50 cubic feet per
minute per square foot) of air/vapor area
when downtime covers are open, and exhausting
less than 25 ppm of solvent by volume
averaged over a complete adsorption cycle; or
B) Any other equipment or system of equivalent
emission control as approved by the Agency,
and further processed consistent with Section
218.108 of this Part.
Such
equipment or
system may include a refrigerated chiller.
(Source: Amended at
Ill. Reg.
______,
effective
__________)
Section 218.185
Compliance Schedule (Repealed)
Every owner or operator of an emission source which was
p~e-vious-lyexempt from the requirements of Subpart E of 35 Ill.
Adm. Code 215 (Sections 215.182—215.184) because it satisfied the
criteria in cither 35 Ill. Adm. Code 215.18-1(a) or 35 Ill. Adm.
Code 215.181(b), shall comply with the requirements of this
Subpart on and after a date consistent with Section 218.106. A
~r~iavr~r’
trhir~hrliii
nnt
!ZM-i-zfy the criteria in either 35 I1l Ad-m
~r~mr~
(Source: Repealed at
Section 218.186
Ill. Reg.
______,
effective
_________)
Test Methods
The following test methods shall be used to demonstrate
compliance with this Subpart:
a) Vapor pressures shall be determined by using the
procedure specified in Section 218.110 of this Part.
b) Exhaust ventilation rates shall be determined by using
the procedures specified in Section 218.105(f) (3)
p1
this Part.
C) The performance of control devices shall be determined
by using the procedures specified in Section 218.105(f)
of this Part.
(Source: Amended at
Ill. Reg.
______,
effective
_________)
SUBPART F: COATING OPERATIONS
Section 218.204
Emission Limitations for Manufacturing Plants
Except as provided in Sections 218.205, 218.207 and 218.208
p1
01140-05914
Code 215.181(a)
the requirement
35 IlL ~
“~-‘
~~-84-f~-
of this- Subpart upon adoption.
~jjth

187
this Part, no owner or operator of a coating line shall apply at
any time any coating in which the VOM content exceeds the
following emission limitations for the specified coating. The
following emission limitations are expressed in units of VON per
volume of coating (minus water and any compounds which are
specifically exempted from the definition of VOM) as applied at
each coating applicator, except where noted. Compounds which are
specifically exempted from the definition of VON should, be
treated as water for the purpose of calculating the “less water”
part of the coating composition. Compliance with this Subpart
must be demonstrated through the applicable coating analysis test
methods and procedures specified in Section 218.105(a) of this
Part and the recordkeeping
and reporting requirements specified
in Section 218.211(c) of this Part except where noted. (Note:
The equation presented in Section 218.206 of this Part shall be
used to calculate emission limitations for determining compliance
by add—on controls, credits for transfer efficiency, emissions
trades and cross—line averaging.) The emission limitations are
as follows:
a) Automobile or Light-Duty
kg/i
lb/gal
Truck Coating
1) Prime coat
0.14
(1.2)
2) Primer surfacer coat
p.341.81
(2--&15.1)
(Note: The primer surfacer coat limitation is
based upon a transfer efficiency of 30 percent.
The use of transfer efficiency credits can be
allowed only if approved by the Agency and
approved by the USEPA as a SIP revision in units
of kg (lbs) of VOM per 1 (gal) of coating solids
deposited. Compliance with the limitation shall
be based on the daily—weighted average from an
entire primer surfacer operation. Compliance
shall be demonstrated in accordance with the
toPcoat protocol referenced in Section 218.105(b)
and the recordkeepinq and reporting requirements
specified in Section 218.211(f). Testing to
demonstrate compliance shall be performed in
accordance with the topcoat protocol and a
detailed testing proposal approved by the Agency
and USEPA specifying the method of demonstrating
compliance with the protocol. Section 218.205 does
not apply to the primer surfacer limitation.)
kg/l
lb/gal
3) Topcoat
1.81
(15.1)
(Note: The topcoat limitation is in units of kg
(lbs) of VON per 1 (gal) of coating solids
01140-0595

deposited. Compliance with the limitation shall
be based on the daily-weighted average VON content
from ~
entire topcoat operation (all topcoat
spray booths-, flash-off areas and bake ovens-).
Compliance shall be demonstrated in accordance
with the topcoat protocol -for automobiles and
light—duty trucks referenced in Section 218.105(b)
of this Part and the recordkeeping and reporting
requirements specified in Section 218.211(f).
Testing to demonstrate compliance shall be
performed in accordance with the topcoat protocol
and Section 2l&.205 does not apply to the topcoat
limitation.) At least 180 days- prior to the
initial compliance date, the owner or operator of
a coating line subject to the topcoat limitation
shall have submitted to the USEPA a detailed
testing proposal approved by the Agency and USEPA
specifying the method of demonstrating compliance
with the protocol. The proposal shall have
included, at a minimum, a comprehensive plan
(including a rationale) for determining the
transfer efficiency at each b~th thr~n~h tb~ n~
of in-plant, or pilot testing
cOQt~iiy..
to be tested
determining
transfer
nn~
1
r~
fr,r -.r~i1—I
nr~
(for the p
efficiency)
rcrrnir~i r~rr’~
urpose of
including the
an-i f~hr~i~’thn~-1
for
dcterminL.~ the analytic VON
~
coatings and the formulati~.
solvent
—~y
~‘
with the
1
t~tjri
L_L~F~L. () i
;~
.i riri I
1:—ri
U~U
4~.
r’
pr~tr~r’r~~
I
~~ancc
acmonstra~i~.,.
J-
________
218.205 of this Part does not apply
limitation.)
r~r’irftcnt
(-‘If
:‘I~
t-rit~--.
upon
upprovul
of
Vflf’
~
Tfl(-’
~t~’
Th.~1’J
kg/i
lb/gal
1) Sheet basecoat and
overvarnish
2)
Exterior basecoat and
overvarnish
Exterior end coat
5) Side seam spray coat
0.34
(2.8)
0.34
(2.8)
(4.2)
0.51
(4.2)
0.66
(5.5)
(3.7)
188
4-i-.,-.
~
,-.P
b) Can Coating
-..—_1
£~~-
Section
tc~ th~ topcoat
4) Final repair coat
kg/l
0.58
lb/gal
(4.8)
3)
Interior body spray coat 0.51
6)
End sealing compound coato.44
01140-0596

189
kg/l
lb/gal
c) Paper Coating
0.35
(2.9)
(Note: The paper coating limitation shall not apply to
any owner or operator of any paper coating line on
which printing is performed if the paper coating line
complies with the emissions limitations in Subpart H:
Printing and Publishing, Sections 218.401 of this Part
through 2l8.4-O4and other approvable requirements.)
kg/l
lb/gal
d)
Coil Coating
0.31
(2.6)
e) Fabric Coating
0.35
(2.9)
f) Vinyl Coating
0.45
(3.8)
g) Metal Furniture Coating
0.36
(3.0)
h) Large Appliance Coating
0.34
(2.8)
(Note: The limitation shall not apply to the use of
quick—drying lacquers for repair of scratches and nicks
that occur during assembly, provided that the volume of
coating does not exceed 0.95 1 (1 quart) in any one
rolling eight-hour period.)
kg/l
lb/gal
i) Magnet Wire Coating
0.20
(1.7)
j)
Miscellaneous Metal Parts and
Products Coating
1) Clear coating
0.52
(4.3)
2)
Air—dried coating
0.42
(3.5)
3) Extreme performance
0.42
(3.5)
coating
il
Steel pail and drum
(0.52)
(4.31
interior coating
4~)
All other coatings
0.36
(3.0)
kg/l
lb/gal
k) Heavy Off—Highway Vehicle
Products Coating
1)
Extreme performance
0.42
(3.5)
prime coat
01140_Q597

190
2) Extreme performance top- 0.42
(3.5)
coat (air dried)
3) Final repair coat
0.42
(3.5)
(air dried)
4) All other coatings are subject to the emission
limitations for miscellaneous metal parts and
products coatings in subsection
(j)
above.
1) Wood Furniture Coating
kg/l
lb/gal
1) Clear topcoat
0.67
(5.6)
2)
Opaque stain
0.56
(4.7)
3)
Pigmented coat
0.60
(5.0)
4) Repair coat
0.67
(5.6)
5) Sealer
0.67
(5.6)
6)
Semi—transparent stain
0.79
(6.6)
7) Wash coat
0.73
(6.1)
(Note: An owner or operator of a wood furniture
coating operation subject to this Section shall
apply all coatings, with the exception of no more
than 37.8 1 (10 gal) of coating per day used for
touch—up and repair operations, using one or more
of the following application systems: airless
spray application system, air—assisted airless
spray application system, electrostatic spray
application system, electrostatic bell -or disc
spray application system, heated airless spray
application system, roller coating, brush or wipe
coating application system, e~ dip coating
application system or high volume low pressure
(HVLP) application system.)
in) Existing Diesel-Electric Locomotive Coating Lines in
Cook County
kg/l
lb/gal
1) Extreme performance prime
coat
0.42
(3.5)
2) Extreme performance top-
coat (air dried)
0.42
(3.5)
3) Final repair coat
(air dried)
0.42
(3.5)
01140-0598

191
4) High-temperature aluminum
coating
0.72
(6.0)
5) All other coatings
0.36
(3.0)
(Source: Amended at
Ill. Reg.
______,
effective
_________)
Section 218.205
Daily-Weighted Average Limitations
-
No owner or operator of a coating line subject to the limitations
of Section 218.204 of this Part and
complying
by means of this
Section shall operate the subject coating line unless the owner
or operator has demonstrated compliance with subsection (a), (b),
(c), (d), (e) or (f) of this Section (depending upon the s-ourcc
category of coating) through the applicable coating analysis test
methods and procedures specified in Section 218.105(a) of this
Part and the recordkeeping and reporting requirements specified
in Section 218.211(d) of this Part:
a) No owner or operator of a coating line subject to only
one of the limitations from among Section
218.204(a) (1)
,
(a) (2)
,
(a) (4), (c)
,
(d)
,
(e)
,
(f)
,
(g)
(h), or (i) of this Part shall apply coatings on any
such coating line,
during any day, whose daily-weighted
average VON content exceeds the emission limitation to
which
the
coatings are subject.
b) No owner or operator of a miscellaneous metal parts and
products coating line subject to the limitations of
Section 218.204(j) of this Part shall apply coatings to
miscellaneous metal parts
or products on the subject
coating
line unless
the requirements in subsection
(b) (1) or (b) (2) below are met.
1)
For each coating line which applies multiple
coatings, all of which are subject to the same
numerical emission limitation within Section
218.204(j) during the same day (e.g., all coatings
used on the line are subject to 0.42 kg/i 3.5
lbs/gal),
the daily—weighted average VOM content
shall not exceed the coating VOM content limit
corresponding to the category of coating used, or
2)
For each coating line which applies coatings
subject to more than one numerical emission
limitation from more than one of the four coating
categories in Section 218.204(j) above, during the
same day, the owner or operator shall have a
site-specific
proposal approved by the Agency and
approved by the USEPA as a SIP revision.
To
receive approval, the requirements of USEPA’s
Emissions Trading Policy Statement (and related
01140-0599

192
policy) 51 Fed. Reg. 43814 (December 4, 1986),
must be satisfied.
c) No owner or operator of a can coating facilityline
subject to the limitations of Section ~j3..204(b)
p1
this Part shall operate the subject coating facility
line using a coating with a VON content in excess of
the limitations specified in Section ~j~.204(b)
p1
this Part unless all of the following requirements are
met:
1) An alternative daily emission limitation shall be
determined for
the can coatinq operation, i.e. for
all of the can coating lines at the source,
according to subsection (c) (2) below. Actual
daily emissions shall never exceed the alternative
daily emission limitation and shall be calculated
by use of the following equation.
n
Ed
=
E V~ C~
i=l
where:
Ed
=
Actual VON emissions for the day in
units of kg/day (lbs/day)-~-;
i
=
Subscript denoting a
specific
n
=
Totalcoatingnumberappliedof7~coatings applied in
the can coating operation, i.e. all
can coating lines at the source
V~
=
Volume of each coating applied for
the day in units of 1/day (gal/day)
of coating (minus water and any
compounds which are specifically
exempted from the definition of
VOM)~
C~
=
The VON content of each coating as
applied in units of kg VOM/l (lbs
VOM/gal) of coating (minus water
and any compounds which are
specifically exempted from the
definition of VOM).
2)
The alternative daily emission limitation
(Ad)
shall be determined for the can coating operation,
i.e. for all of the can coating lines at the
01 140-0&~ü

193
source~ on a daily basis as follows:
n
Ad=E V~ L~j~1 -C~j
i1
(D~
L~)
where:
Ad
=
The VOM emissions allowed for the
day in units
of kg/day (lbs/day)~~
i
=
Subscript denoting a specific
n
=
Total
coating
number
applied-
of
1~
surface coatings
applied in the can coating
operation-7-j..
C~
=
The VOM content of each surface
coating as applied in units of kg
VOM/l (lbs VOM/gal) of coating
(minus water and any compounds
which are specifically exempted
from the definition of VOM)-r~
D1
=
The density of VON in each coating
applied. For the purposes of
calculating 4-Ad, the density is
0.882 kg VON/i VON (7.36 lbs
VON/gal VOM)T1
=
Volume of each surface coating
applied for the day in units of 1
(gal) of coating (minus water and
any
compounds which are
specifically exempted from the
definition of VOM)Tj
L~
=
The VOM emission limitation for
each surface coating applied as
specified in Section 218.204(b)
p1
this Part in units of kg VOM/l (lbs
VON/gal) of
coating (minus water
and any
compounds which are
specifically exempted from the
definition of VOM).
d) No owner or operator of a heavy off—highway vehicle
products coating line subject to the limitations of
Section 218.204(k) of this Part shall apply coatings to
heavy off-highway vehicle products on the subject
coating line unless the requirements of subsection
01140-0601

194
(d) (1) or (d) (2) below are met.
1) For each coating line which applies multiple
coatings, all of which are subject to the same
numerical emission limitation within Section
218.204(k) above, during the same day (e.g., all
coatings used on the line are subject to 0.42 kg/l
3.5 lbs/gal),
the daily—weighted average VOM
content shall not exceed the coating VON content
limit corresponding to the category of coating
used, or
2)
For each coating line which applies coatings
subject to more than one numerical emission
limitation in Section 218.204(k) above, during the
same day, the owner or operator shall have a site
specific proposal approved by the Agency and
approved by the USEPA as a SIP revision. To
receive approval, the requirements of USEPA’s
Emissions Trading Policy Statement (and related
policy) 51 Fed. Req. 43814 (December 4. 1986),
must be satisfied.
e) No owner or operator of a wood furniture coating line
subject to the limitations of Section 218.204(1)
p1
this Part shall apply coatings to wood furniture on the
subject coating line unless the requirements of
subsection (e) (1) or subsection
(e) (2) below, in
addition to the requirements specified in the note to
Section 218.204(1) of this Part, are met.
1) For each coating line which applies multiple
coatings, all of which are subject to the same
numerical emission limitation within Section
218.204(1) above, during the same day (e.g., all
coatings used on the line are subject to 0.67 kg/i
5.6 lbs/gal), the daily-weighted average VON
content shall not exceed the coating VON content
limit corresponding to the category of coating
used, or
2)
For each coating line which applies coatings
subject to more than one numerical emission
limitation in Section 218.204(1) above, during the
same day, the owner or operator shall have a site
specific proposal approved by the Agency and
approved by the USEPA as a SIP revision.
To
receive approval, the requirements of USEPA’s
Emissions Trading Policy Statement (and related
policy) 51 Fed. Reg. 43814 (December 4, l986),
must be satisfied.
01140-0602

195
f) No owner or operator of an existing diesel—electric
locomotive coating line in Cook County, subject to the
limitations of Section 218.204(m) of this Part shall
apply coatings to diesel—electric locomotives on the
subject coating line unless the requirements of
subsection (b) (1) (f) (1) or (b) (2) (f) (2) of this Section
are met.
-
1) For each coating line which applies multiple
coatings, all of which are subject to the same
numerical emission limitation within Section
218.204(m) above, during the same day (e.g., all
coatings used on the line are subject to 0.42 kg/i
3.5 lbs/gal),
the daily-weighted average VOM
content shall not exceed the coating VOM content
limit corresponding to the category of coating
used, or
2) For each coating line which applies coatings
subject to more than one numerical emission
limitation in Section 218.204(m) above, during the
same day, the owner or operator shall have a site
specific proposal approved by the Agency and
approved by the USEPA as a SIP revision. To
receive approval, the requirements of USEPA’s
Emissions Trading Policy Statement (and related
policy) must be satisfied.
(Source: Amended at
Ill. Reg.
______,
effective
__________)
Section 218.206
Solids Basis Calculation
Limitations in terms of kg (lbs) of VOM emissions per 1 (gal) of
solids as applied at each coating applicator shall be determined
by the following equation:
S
=
C
1
-
(C/D)
where:
S
=
The limitation on VOM emissions in terms of
kg VOM/l (lbs VOM/gal) of so1idsT~
C
=
The limitation on VOM emissions in terms of
kg/i (lbs/gal) of coating (minus water and
any compounds which are specifically
excluded
from the definition of VOM) specified in
Section
218•204T
of this Part
D
The density of VON in the coating. For the
purposes of calculating 5, the density is
01140-0603

196
0.882 kg VON/i VON (7.36 lbs VON/gal VON).
(Source: Amended at
Ill. Req.
______,
effective
__________)
Section 218.207
Alternative Emission Limitations
a) Any owner or operator of a coating line subject to
Section 218.204 of this Part may comply with this
Section, rather than with Section 218.204 of this Part,
if a capture system and control device are operated at
all times the coating line is in operation and the
owner or operator demonstrates compliance with
subsections (c), (d), (e)
,
(f), (g) or (h) of this
Section (depending upon the source category) through
the applicable coating analysis and capture system and
control device efficiency test methods and procedures
specified in Section 218.105 of this Part and the
recordkeeping and reporting requirements specified in
Section 218.211(e) of this Part and the control device
is equipped with the applicable monitoring equipment
specified in Section 218.105(d) of this Part and the
monitoring equipment is installed, calibrated, operated
and maintained according to vendor specifications
at
all times the control device is in use. A capture
system and control device, which does not demonstrate
compliance with subsection (c), (d), (e), (f), (g) or
(h) of this Section may be used as an alternative to
compliance with Section 218.204 of this Part only if
the alternative is approved by the Agency and approved
by the USEPA as a SIP revision.
b)
Alternative Add-On Control Methodologies
1)
The coating line is equipped with a capture system
and control device that provides 81 percent
reduction in the overall emissions of VON from the
coating line and the control device has a 90
percent efficiency, or
2)
The system used to control VON from the coating
line is demonstrated to have an overall efficiency
sufficient to limit VOM emissions to no more than
what is allowed under Section 218.204 of this
Part.
Use of any control system other than an
afterburner,
carbon adsorption, condensation, or
absorption scrubber system can be allowed only if
approved by the Agency and approved by the USEPA
as a SIP revision.
The use of transfer efficiency
credits can be allowed only if approved by the
Agency and approved by the USEPA as a SIP
revision.
Baseline transfer efficiencies
and
transfer efficiency test methods must be approved
01 140-060Li.

197
by the Agency and the USEPA.
Such overall efficiency is to be determined as
follows:
A) eObtain the emission limitation from the
appropriate subsection in Section 218.204 of
this Part-~-j
B) eCalculate
“5”
according to the equation in
Section 218.206 of this Part-~-j.
C) eCalculate the overall efficiency required
according to Section 218.105(e) of this Part.
For the purposes of calculating this value,
according to the equation in Section
218.105(e) (2) of this Part, VON1 is equal to
the value of “5” as determined above in
subsection (b) (2) (B) of this Section.
c) No owner or operator of a coating line subject to only
one of the emission limitations from among Section
218.204(a) (1), (a) (2), (a) (4), (c)
,
(d)
,
(e)
,
(f)
,
(g)
(h) or
(i) of this Part and equipped with a capture
system and control device shall operate the subject
coating line unless the requirements in subsection
(b) (1) or (b) (2) above are met. No owner or operator
of a coating line subject to Section 218.204(a) (2) or
218.204(a) (3) and equipped with a capture system and
control device shall operate the coating line unless
the owner or operator demonstrates compliance with ~e
topcoat such limitation in accordance with the topcoat
protocol for automobile or light-duty
trucks referenced
in Section 218.105(b)
d) No owner or operator of a miscellaneous metal parts and
products coating line which applies one or more
coatings during the same day, all of which are subject
to the same numerical emission limitation within
Section 218.204(j) of this Part (e.g., all coatings
used on the line are subject to 0.42 kg/i 3.5
lbs/gal), and which is equipped with a capture system
and control device shall operate the subject coating
line unless the requirements in subsection (b) (1) or
(b) (2) above are met.
e) No owner or operator of a heavy off-highway vehicle
products coating line which applies one or more
coatings during the same day, all of which are subject
to the same numerical emission limitation within
Section 218.204(k) of this Part (e.g., all coatings
used on the line are subject to 0.42 kg/i 3.5
01140-0605

198
lbs/gal), and which is equipped with a capture system
and control device shall operate the subject coating
line unless the requirements in subsection (b) (1) or
(b) (2) above are met.
f) No owner or operator of an existing diesel—electric
locomotive coating line in Cook County which applies
one or more coatings during the same day, all of which
are subject to the same numerical emission limitation
within Section 218.204(m) of this Part (e.g., all
coatings used on the line are subject to 0.42 kg/l 3.5
lbs/gal),
and which is equipped with a capture system
and control device shall operate the subject coating
line unless the requirements in subsection (b) (1) or
(b) (2) above are met.
g) No owner or operator of a wood furniture coating line
which applies one or more coatings during the same day,
all of which are subject to the same numerical emission
limitation within Section 218.204(1) of this Part
(e.g., all coatings used on the line are subject to
0.67 kg/i 5.6 lbs/gal), and which is equipped with a
capture system and control device shall operate the
subject coating line unless the requirements in
subsection (b) (1) or (b) (2) of this Section are met.
If compliance is achieved by meeting the requirements
in subsection (b) (2) of this Part, then the provisions
in the note to Section 218.204(1) of this Part must
also be met.
h)
No owner or operator of a can coating facilityline
an4
which is equipped with a capture system and control
device shall operate the subject coating facilityline
unless the requirements in subsection (h) (1) or (h) (2)
below are met.
1) An alternative daily emission limitation shall be
determined for the
can coating operation, i.e. for
all of the can coating lines at the source,
according to Section 218.205(c) (2) of this Part.
Actual daily emissions shall never exceed the
alternative daily emission limitation and shall be
calculated by use of the following equation:
n
Ed
=
E V~ C~ (1—Fr
i=i
where:
Ed
=
Actual VOM emissions for the day in
units of kg/day (lbs/day)Tj
01140-0606

199
i
=
Subscript denoting the specific
coating appliedTj
n
=
Total number of surface coatings as
applied in the can coating
operat ion-7-~
V1
=
Volume of each coating as applied
for the day in units of 1/day
(gal/day) of coating (minus water
and any compounds which are
specifically exempted from the
definition of VOM)-~~
C~
=
The VON content of each coating as
applied in units of kg VON/i (lbs
VON/gal) of coating (minus water
and any compounds which are
specifically exempted from the
definition of VON) and
F1
=
Fraction, by weight, of VON
emissions from the surface coating,
reduced or prevented from being
emitted to the ambient air. This is
the overall efficiency of the
capture system
and control device~
2) The coating line is equipped with a capture system
and control device that provide 75 percent
reduction in the overall emissions of VON from the
coating line and the control device has a 90
percent efficiency.
(Source: Amended at
Ill. Reg.
______,
effective
__________)
Section 218.208
Exemptions From Emission Limitations
a) Exemptions for all sourcecoating categories except wood
furniture coating. The limitations of this Subpart
shall not apply
to coating lines within a facility
source, that otherwise would
be subject to the same
subsection of Section 218.204 (because they belong to
the same sourcecoating category, e.g. can coating)
provided that combined actual emissions of VON from all
lines at the facilitysource subject to that subsection
never exceed 6.8 kg/day
(15 lbs/day) before the
application of capture systems and control devices.
(For example, can coating lines within a plantsource
would not be subject to the limitations of Section
218.204(b) of this Part if the combined actual
emissions of VON from the can coating lines never
01140~0607

200
exceed 6.8 kg/day (15 lbs/day) before the application
of capture systems and control devices.)
Volatile
organic material emissions from heavy off—highway
vehicle products coating lines must be combined with
VON emissions from miscellaneous metal parts and
products coating lines to determine applicability. Any
owner or operator of a coating facilitysource shall
comply with the applicable coating analysis test
methods and procedures specified in Section 218.105(a)
of this Part and the recordkeeping and reporting
requirements specified in Section 218.211(a) of this
Part if total VOM emissions from the subject coating
lines are always less than or equal to 6.8 kg/day
(15 lbs/day) before the application of capture systems
and control devices and, therefore, are not subject to
the limitations of Section 218.204 of this Part.
Once
a category of coating lines at a facilitysource is
subject to the limitations in Section 218.204, of this
Part the coating lines are always subject to the
limitations in Section 218.204 of this Part.
b) Applicability for wood furniture coating
1) The limitations of this Subpart shall apply to a
plant’s-source’s wood furniture coating lines if
the plantsource contains process emission sources-
units, not regulated by Subparts B, E, F
(excluding Section 218.204(1) of this Part), H
(excluding Section 218.405), Q, R, S, T (excluding
Section 218.486 of this Part) ,V, X, 1, e~Z or BB
of this Part, which as a group both:
A) Hhave maximum theoretical emissions of 91 Mg
(100 tons) or more per calendar year of VON
if no air pollution control equipment were
used, and
B) A&re not limited to less than 91 Mg
(100 tons) of VON per calendar year if no
air pollution control equipment were used,
through production or capacity limitations
contained in a federally enforceable
construction permit or SIP revision.
2)
If a plantsource ceases to fulfill the criteria of
subsection (b) (1)
of this Section, the limitations
of Section 218.204(1) of this Part shall continue
to apply to any wood furniture coating line which
--
was ever subject to the limitations of Section
218.204(1) of this Part.
3)
For the purposes of subsection (b) of this
01140-0608

201
Section, an emission s-ourceunit shall be
considered regulated by a Subpart if it is subject
to the limitations of that Subpart. An emission
sourceunit is not considered regulated by a
Subpart if it is not sublect to the limits of that
Subpart, e.g.. the emission unit is covered by an
exemption in the Subpart or the ap~plicability
criteria of the Subpart are not met. its emissions
are below the applicability cutoff level or if the
source is- covered by an exemption.
4) Any owner or operator of a wood furniture coating
line to which the limitations of this Subpart are
not applicable due to the criteria in subsection
(b) of this Section shall, upon request by the
Agency or the USEPA, submit records to the Agency
and the USEPA within 30 calendar days from the
date of the request that document that the coating
line is exempt from the limitations of this
Subpart.
(Source: Amended at
Ill. Reg.
______,
effective
___________
Section 218.209
Exemption From General Rule on Use of Organic
Material
No owner or operator of a coating line subject to the limitations
of Section 218.204 of this Part is required to meet the
limitations of Subpart G (Section 218.301 or 218.302) of this
Part, after the date by which the coating line is required to
meet Section 218.204 of this Part.
(Source: Amended at
Ill. Reg.
______,
effective
__________)
Section 218.210
Compliance Schedule
Every owner or operator of a coating line (of a type included
within Section 218.204) of this Part shall comply with the
requirements of Section 218.204, 218.205, 218.207 or 218.208 and
Section 218.211 of this Part in accordance with the appropriate
compliance schedule as specified in subsection (a), (b), (c) or
(d) below:
a) No owner or operator of a coating line which is exempt
from the limitations of Section 218.204 of this Part
because of the criteria in Section 218.208(a) of this
Part shall operate said coating line on or after a date
consistent with Section 218.106 of this Part, unless
the owner or operator has complied with, and continues
to comply with, Section 218.211(b) of this Part. Wood
furniture coating lines are not subject to Section
218.211(b) of this Part.
01140-0609

202
b) No owner or operator of a coating line complying by
means of Section 218.204 of this Part shall operate
said coating line on or after a date consistent with
Section 218.106 of this Part, unless the owner or
operator has complied with, and continues to comply
with, Sections 218.204 and 218.211(c) of this Part.
c) No owner or operator of a coating line complying by
means of Section 218.205 of this Part shall operate
said coating line on or after a date consistent with
Section 218.106 of this Part, unless the owner or
operator has complied with, and continues to comply
with, Sections 218.205 and 218.211(d) of this Part.
d) No owner or operator of a coating line complying by
means of Section 218.207 of this Part shall operate
said coating line on or after a date consistent with
Section 218.106 of this Part, unless the owner or
operator has complied with, and continues to comply
with, Sections 218.207 and 218.211(e) of this Part.
(Source: Amended at
Ill. Reg.
______,
effective
__________)
Section 218.211
Recordkeeping and Reporting
a) The VOM content of each coating and the efficiency of
each capture system and control device shall be
determined by the applicable test methods and
procedures specified in Section 218.105 of this Part to
establish the records required under this Section.
b) Any owner or operator of a coating line which is
exempted from the limitations of Section 218.204
p1
this Part because of Section 218.208(a) of this Part
shall comply with the following:
1) By a date consistent with Section 218.106 of this
Part, the owner or operator of a facilitycoatinci
line or a group of coating lines referenced in
this subsection(b) of this Section shall certify
to the Agency that the facilitycoatinq line or
group of coating lines is exempt under the
provisions of Section 218.108(a) of this Part.
Such certification shall include:
A) A declaration that the facilitycoating line
or group of coating lines is exempt from the
limitations of Section 218.204 of this Part
because of Section 218.208(a) of this Part
and
B) Calculations which demonstrate that the
01140-0610

203
combined VON emissions from a-l-?r~J~coating
lines at the facilityg~group of coating
lines never exceed 6.8 kg (15 ibs) per day
before the application of capture systems and
control devices. The following equation
shall be used to calculate total VON
emissions:
mn
TCe
=
E
E (A1 B1)~
j=l i=l
where:
Tee
=
Total VON emissions from coating
lines at a facility each day before
the application of capture systems
and control devices in units of
kg/day (lbs/day)T~
m
=
Number of coating lines at the
facility source that otherwise
would be sub~iectto the same
subsection of Section 218.104 of
this Part (because they belong to
the same category, e.g., can
coating)
-~-~
j
=
Subscript denoting an individual
coating line-~-j.
n
=
Number of different coatings as
applied each day on each coating
line at the facility,~
i
=
Subscript denoting an individual
coating~~
A1
=
Weight of VON per volume of each
coating (minus water and any
compounds which are specifically
exempted from the definition of
VON) as applied each day on each
coating line at the facility in
units
of kg VOM/l (lbs VON/gal)j~.
and
B1
=
Volume of each coating (minus water
and any compounds which are
specifically exempted from the
definition of VOM) as applied each
day on each coating line at the
0114Q-06L I

204
facility in units of 1/day
(gal/day). The instrument or
method by which the owner or
operator accurately measured or
calculated the volume of each
coating as applied on each coating
line each day shall be described in
the certification to the Agency.
2) On and after a date consistent with Section
218.106 of this Part, the owner or operator of a
facility coating line or group of coating lines
referenced in this subsection shall collect and
record all of the following information each day
for each coating line and maintain the information
at the facilitysource for a period of three years:
A) The name and identification number of each
coating as applied on each coating line.
B) The weight of VON per volume and the volume
of each coating (minus water and any
compounds which are specifically exempted
from the definition of VON) as applied each
day on each coating line.
3) On and after a date consistent with Section
218.106 of this Part, the owner or operator of a
facility coating line or group of coating lines
exempted from the limitations of Section 218.204
of this Part because of Section 218.208(a) of this
Part shall notify the Agency of any record showing
that total VON emissions from the coating
facilityline or group of coating lines exceed 6.8
kg (15 ibs) in any day before the application of
capture systems and control devices by sending a
copy of such record to the Agency within 30 days
after the exceedance occurs.
c) Any owner or operator of a coating line subject to the
limitations of Section 218.204 of this Part other than
Section 218.204(a) (2) or (a)(3) and complying by means
of Section 218.204 of this Part shall comply with the
following:
1) By a date consistent with Section 218.106 of this
Part, or upon initial start—up of a new coating
line, or upon changing the method of compliance
from an existing subject coating line from Section
218.205 or Section 218.207 of this Part to Section
218.204 of this Part the owner or operator of a
subject coating line shall certify to the Agency
01140-0612

205
that the coating line will be in compliance with
Section 218.204 of this Part on and after a date
consistent with Section 218.106 of this Part, or
on and after the initial start-up date. Such
certification shall include:
A) The name and identification number of each
coating as applied
on each coating line.
B)
The weight of VON per volume of each coating
(minus water and any compounds which are
specifically exempted from the definition of
VOM) as applied each day on each coating
line.
e-)- For coating
lines subject to Section
218.204(a) (3) certification s-hall include:
ii)
iii)
line,
2) On and after a date consistent with Section
218.106 of this Part, or on and after the
initial
start—up date, the owner or operator of a sublect
coating line subject to the limitations- of Section
218.204 and complying by means- of Section 218.204
shall collect and record all of the following
information each day for each coating line and
01140-0613
The name and identification number of
cach coating 218.204(a) (3),
The name and identification number of
each coating
as applied on each coating
The weight of VON per volume of each
coating as applied on each coating line,
The instrument or method by which the
owner or operator will accurately
measure or calculate the volume of each
coating
as applied each day on each
coating line,
The method by which the owner or
operator will create and maintain
records each day as required in
subsection (c) (2) below for coating
lines sub~cct to Section 218.204(a) (3),
An—example format in which the records-
required in subsection (c)
(2) below for
coating lines subject to Section
218. 204 (a) (3)

206
maintain the information at the facility source
for a period of three years:
A) The name and identification number of each
coating as applied on each coating line.
B) The weight of VOM per volume of each coating
(minus water and any compounds which are
specifically exempted from the definition of
VON) as applied each day on each coating
line.
?-)-
For coating lines subject to Section
218.204(a) (3) the owner or operator s-hall
maintain all records- necessary to calculate
the daily—weighted average VOM content from
the coating line in accordance with the
proposal submitted, and proved by the USEPA,
pursuant to Section 218.204(a) (3).
3) On and after a date consistent with Section
218.106 of this Part, the owner or operator of a
subject coating line shall notify the Agency in
the following instances:
Any record showing violation of Section
218.204 of this Part shall be reported by
sending a copy of such record to the Agency
within 30 days following the occurrence of
the violation, except that any record showing
a violation of Section 218.204(a) (3) s-hail bc
reported by
-
-‘~‘--~‘
of such record to
the Agency within 15 days from the end of the
mrnt~h i n uh i
r~h thr~ u-i r~1~i—
i
t-~n t—~r~c~ivrrrd
-
B) At least 30 calendar days before changing the
method of compliance with Section 218.204
from Section 218.204 of this Part to Section
218.205 or Section 218.207 of this Part, the
owner or operator shall comply with all
requirements of subsection (d) (1) or (e) (1)
of this Section below, respectively. Upon
changing the method of compliance with
Section 218.204 from Section 218.204 of this
Part to Section 218.205 of this Part or
Section 218.207 of this Part, the
owner or
operator shall comply with all requirements
of
subsection (d) or (e) of this Section,
respectively.
G)-
For coating lines subject to Section
218.204 (a) (3) the owner or operator shall
0 I 140-06114
A)

207
notify the Agency of any change to the
topcoating operation at least 30 days before
the change is effected. The Agency shall
determine whether or not recertification
testing is required. If the Agency
determines- that recertification testing is
required, then the owner or operator s-hall
proposal
to the ~gcncy
4-_S
4-~.-.4-
within 30 days- and retest within 30 days- of
the
Agency’s ~pprovai
of the proposal.
d) Any owner or operator of a coating line subject to the
limitations of Section 218.204 of this Part
and
complying by means of Section 218.205 of this Part
shall comply with the following:
1) By a date consistent with Section 218.106 of this
Part, or upon initial start—up of a new coating
line, or upon changing the method of compliance
for an existing subject coating line from Section
218.204 or Section 218.207 of this Part to Section
218.205 of this Part the owner or operator of the
subject coating line shall certify to the Agency
that the coating line will be in compliance with
Section 218.205 of this Part on and after a date
consistent with Section 218.106 of this Part, or
on and after the initial start-up date. Such
certification shall include:
A) The name and identification number of each
coating line which will comply by means of
Section 218.205 of this Part.
B) The name and identification number of each
coating as applied on each coating line.
C) The weight of VON per volume and the volume
of each coating (minus water and any
compounds which are specifically exempted
from the definition of VON) as applied each
day on each coating line.
D) The instrument or method by which the owner
or operator will accurately measure or
calculate the volume of each coating as
applied each day on each coating line.
E) The method by which the owner or operator
will create and maintain records each day as
required in subsection (d) (2) of this
Section.
01140-0615

208
F) An example of the format in which the records
required in subsection (d) (2) of this Section
will be kept.
2) On and after a date consistent with Section
218.106 of this Part, or on and after the initial
start—up date, the owner or operator of a sublect
coating line subject to thc limitations of Section
218.204 and complying by means- of Sect-ion 218.205
shall collect and record all of the following
information each day for each coating line and
maintain the information at the facility source
for a period of three years:
A) The name and identification number of each
coating as applied on each coating line.
B) The weight of VON per volume and the volume
of each coating (minus water and any
compounds which are specifically exempted
from the definition of VON) as applied each
day on each coating line.
C) The daily-weighted average VON content of all
coatings as applied on each coating line as
defined in Section 218.104 of this Part.
3) On and after a date consistent with Section
218.106 of this Part, the owner or operator of a
subject coating line shall notify the Agency in
the following instances:
A) Any record showing violation of Section
218.205 of this Part shall be reported by
sending a copy of such record to the Agency
within 30 days following the occurrence of
the violation.
B) At least 30 calendar days before changing the
method of compliance with this subpart from
Section 218.205 of this Part to Section
218.204 or Section 218.207 of this Part, the
owner or operator shall comply with all
requirements of subsection (c) (1) or (e) (1)
of this Section, respectively. Upon changing
the method of compliance with this subpart
from Section 218.205 to Section 218.204 or
Section 218.207 of this Part, the owner or
operator shall comply with all requirements
of subsection (c) or (e) of this Section,
respectively.
S

209
e) Any owner or operator of a coating line subject to the
limitations of Section 218.207 of this Part and
complying by means of Section 218.207(c), (d), (e),
(f), (g) or (h) of this Part shall comply with the
following:
1) By a date consistent with Section 218.106 of this
Part, or upon initial start—up of a new coating
line, or upon changing the method of compliance
for an existing coating line from Section 218.204
or Section 218.205 of this Part to Section 218.207
of this Part, the owner or operator of the subject
coating line shall perform all tests and submit to
the Agency the results of all tests and
calculations necessary to demonstrate that the
subject coating line will be in compliance with
Section 218.207 of this Part on and after a date
consistent with Section 218.106 of this Part, or
on and after the initial start-up date.
2) On and after a date consistent with Section
218.106 of this Part, or on and after the initial
start—up date, the owner or operator of a subject
coating line subject to the limitations of Section
218.207 and complying by means- of Section
218.207(c), (d), (c), (f), (g), or (h) shall
collect and record all of the following
information each day for each coating line and
maintain the information at the facilitysource for
a period of three years:
A) The weight of VOM per volume of coating
solids as applied each day on each coating
line, if complying pursuant to Section
218.207(b) (2) of this Part.
B) Control device monitoring data.
C) A log of operating time for the capture
system, control device, monitoring equipment
and the associated coating line.
D) A maintenance log
for the capture system,
control device and monitoring equipment
detailing all routine and non—routine
maintenance performed including dates and
duration of any outages.
3) On and after a date consistent with Section
218.106 of this Part, the owner or operator of a
subject coating line shall notify the Agency in
the following instances:
01140-0617

210
A) Any record showing violation of Section
218.207 of this Part shall be reported by
sending a copy of such record to the Agency
within 30 days following the occurrence of
the violation.
B) At least 30 calendar days before changing the
method of compliance with this Subpart from
Section 218.207 of this Part to Section
218.204 or Section 218.205 of this Part, the
owner or operator shall comply with all
requirements of subsection (c) (1) or (d) (1)
of this Section, respectively. Upon changing
the method of compliance with this subpart
from Section 218.207 of this Part to Section
218.204 or Section 218.205 of this Part, the
owner or operator shall comply with all
requirements of subsection (C)
or (d) of this
Section, respectively.
~j Any owner or operator of a primer surfacer operation or
topcoat operation subject to the limitations of Section
218.204(a~(2) or (a) (3) of this Part shall comply with
the following:
fl
By a date consistent with Section 218.106 of this
Part, or upon initial start—up of a new coating
operation, the owner or operator of a subject
coating operation shall certify to the Agency that
the operation will be in compliance with Section
218.204 of this Part on and after a date
consistent with Section 218.106 of this Part, or
on and after the initial start-up date. Such
certification shall include:
~j The name and identification number of each
coating operation which will comply bY means
of Section 218.204 (a) (2) and (a) (3) of this
Part and the name and identification number
of each coating line in each coating
operation.
~ The name and identification number of each
coating as applied on
each coating line in
the coating operation.
çj
The weight of VON per volume of each coating
(minus water and any compounds which are
specifically exempted from the definition of
VOM) as applied each day on each coating
line.
01140-0618

211
Qj The transfer efficiency and control
efficiency measured for each coating line.
~j Test reports, including raw data and
calculations documenting the testing
performed to measure transfer efficiency and
control efficiency.
fi
The instrument or method by which the owner
or operator will accurately measure or
calculate the volume of each coating as
applied each day on each coating line.
~j The method by which the owner or operator
will create and maintain records each day as
required in subsection (f) (2) below.
~fl
An example format for presenting the records
required in subsection (f) (2) below.
~j On and after a date consistent with Section
218.106 of this Part, or on and after the initial
start-up date, the owner or operator of a sublect
coating operation shall collect and record all of
the following information each day for each
operation and maintain the information at the
source for a period of three years:
~j All information necessary to calculate the
daily-weighted average VON emissions from the
coating operations in kg (ibs) per 1 (gal) of
coating solids deposited in accordance with
the proposal submitted, and approved pursuant
to Section 218.204 (a) (2) or (a) (3) of this
Part including:
fl
The name and identification number of
each coating as applied on each
coating
operation.
j~J The weight of VON per volume of each
coating (minus water and any compounds
which are specifically exempted from the
definition of VON) as applied each day
on each coating operation.
~J
If
a control device(s) is used to control VON
emissions, control device monitoring data; a
log of operating time for the capture system.
control device, monitoring eguipment and the
associated coating operation; and a
maintenance log for the caPture system,
01140-0619

212
control device and monitoring equipment,
detailing all routine and non—routine
maintenance performed including dates and
duration
of any outages.
~j On and after a date consistent with Section
218.106 of this Part or on and after the initial
start-up date, the owner or operator of a subject
coating operation shall determine and record the
daily VOM emissions in kg (ibs) per 1 (gal) of
coating solids deposited in accordance with the
proposal submitted and approved pursuant to
Section 218.204 (a) (2) or (a) (3) of this Part
within 10 days from the end of the month and
maintain this information at the source for a
period of three years.
il
On and after a date consistent with Section
218.106 of this Part, the owner or operator of a
subject coating operation shall notify the Agency
in the following instances:
~j Any record showing a violation of Section
218.204(a) (2) or (a)(3) of this Part shall be
reported bY sending a copy of such record to
the Agency within 15 days from the end of the
month in which the violation occurred.
~j The owner or operator shall notify the Agency
of any change to the operation at least 30
days before the change is effected. The
Agency shall determine whether or not
compliance testing is required.
If the
AgenQy determines that compliance testing is
required, then the owner or operator shall
submit a testing proposal to the Agency
within 30 days and test within 30 days of the
approval of the proposal by the Agency and
USEPA.
(Source: Amended at
Ill. Reg.
______,
effective
___________
SUBPART G: USE OF ORGANIC MATERIAL
Section 218.301
Use of Organic Material
No person shall cause or allow the discharge of more than 3.6
kg/hr (8 lbs/hr) of organic material into the atmosphere from any
emission soürccunit, except as provided in Sections 218.302,
218.303, 218.304 of this Part and the following exception:
If no
odor nuisance exists the limitation of this Subpart shall
apply
only to photochemically reactive material.
01140-0620

213
(Source: Amended at
Ill. Reg.
______,
effective
___________
Section 218.302
Alternative Standard
Emissions of organic material in excess of those permitted by
Section 218.301 of this Part are allowable if such emissions are
controlled by one of the following methods:
a) Flame, thermal or catalytic incineration so as either
to reduce such emissions to 10 ppm equivalent methane
(molecular weight 16) or less, or to convert 85 percent
of the hydrocarbons to carbon dioxide and water; or,
b) A vapor recovery system which adsorbs and/or condenses
at least 85 percent of the total uncontrolled organic
material that would otherwise be emitted to the
atmosphere; or,
c) Any other air pollution control equipment approved by
the Agency and approved by the USEPA as a SIP revision
capable of reducing by 85 percent or more the
uncontrolled organic material that would be otherwise
emitted to the atmosphere.
(Source: Amended at
Ill. Reg.
______,
effective
___________
Section 218.303
Fuel Combustion Emission Sources-Units
The provisions of Sections 218.301 and 218.302 of this Part shall
not apply to fuel combustion emission sources-units.
(Source: Amended at
Ill. Reg.
______,
effective
___________
Section 218.304
Operations with Compliance Program
The provisions of Sections 218.301 and 218.302 of this Part shall
not apply to any owner, operator, user or manufacturer of paint,
varnish, lacquer, coatings or printing ink whose compliance
program and project completion schedule, as required by 35 Ill.
Adm. Code 201, provided for the reduction of organic material
used in such process to 20
percent or less of total volume by May
30, 1977.
(Source: Amended at
Ill. Req.
______,
effective
__________
SUBPART H: PRINTING AND PUBLISHING
Section 218.401
Flexographic and Rotogravure Printing
a) No owner or operator of a subject flexographic,
packaging rotogravure or publication rotogravure
printing line shall apply at any time any coating or
01140-iJ621

214
ink unless the VON content does not exceed the
limitation specified in either subsection (a) (1) or
(a) (2) below.
Compliance with this Section must be
demonstrated through the applicable coating or ink
analysis test methods and procedures specified in
Section 218.105(a) of this Part and the recordkeeping
and reporting requirements specified in Section
218.404(c) of this Part. As an alternative to
compliance with this subsection, a subject printing
line may meet the requirements of subsection (b) or (c)
below.
1) Forty percent VON by volume of the coating and ink
(minus water and any compounds which are
specifically exempted from the definition of VON),
or
2) Twenty-five percent VON by volume of the volatile
content in the coating and ink.
b) No owner or operator of a subject flexographic,
packaging rotogravure or publication rotogravure
printing line shall apply coatings or inks on the
subject printing line unless the weighted average, by
volume, VON content of all coatings and inks as applied
each day on the subject printing line does not exceed
the limitation specified in either subsection (a) (1)
(as determined by subsection (b) (i)j or subsection
(a)(~2)) (as determined by subsection (b)(2)j.
Compliance with this subsection must be demonstrated
through the applicable coating or ink analysis test
methods and procedures specified in Section 218.105(a)
of this Part and the recordkeeping and reporting
requirements specified in Section 218.404(d) of this
Part.
1) The following equation shall be used to determine
if the weighted average VON content of all
coatings and inks as applied each day on the
subject printing line exceeds the limitation
specified in subsection (a) (1) of this Section.
n
E C1 L1 (V~1+ VVOM1
VOM(j)(A)
=
i1
n
E L1 (V3~+ VVOMj
i ~1
0 I 140-0622

215
Where:
VOM(j)(A)
=
The weighted average VON content in
units of percent VON by volume of
all coatings and inks (minus water
and any compounds which are
specifically exempted from the
definition of VON) used each day~~
i
=
Subscript denoting a specific
coating or ink as applied~~
n
=
The number of different coatings
and/or inks as applied each day on
a printing line-7-~
C1
=
The VON content in units of percent
VON by volume of each coating or
ink as applied (minus water and any
compounds which are specifically
exempted from the definition of
VOM)-7-~
L1
=
The liquid volume of each coating
or ink as applied in units of 1
(ga1)-7-~
=
The volume fraction of solids in
each coating or ink as applied and
VVoMj
=
The volume fraction of VON in
each coating or ink as
applied.
2) The following equation shall be used to determine
if the weighted average VOM content of all
coatings and inks as applied each day on the
subject printing line exceeds the limitation
specified in subsection (a) (2) of this Section.
n
E C1 L1 VVMI
VON(j)(B)
=
i=1
n
E L1 VVM1
i=1
where:
VON(1)(3)
=
The weighted average VON content in
units of percent VON by volume of
01140-0623

216
the volatile content of all
coatings and inks used each dayTi.
i
=
Subscript denoting a specific
coating or ink as applied-~
n
=
The number of different coatings
and/or inks as applied each day on
each printing 1ine-~j
C1
=
The VON content in units of percent
VOM by volume of the volatile
matter in each coating or ink as
appl iedT~
L~
=
The liquid volume of each coating
or ink as applied in units of 1
(gal) and
VVMI
=
The volume fraction of volatile
matter in each coating or ink as
applied.
c) No owner or operator of a subject flexographic,
packaging rotogravure or publication rotogravure
printing line equipped with a capture system and
control device shall operate the subject printing line
unless the owner or operator meets the requirements in
subsection (c) (1), (c) (2), or (c) (3) and subsections
(c) (4)
,
(c) (5) and (c) (6) below.
1) A carbon adsorption system is used which reduces
the captured VON emissions by at least 90 percent
by weight, or
2) An incineration system is used which reduces the
captured VON emissions by at least
90 percent by
weight, or
3) An alternative VON emission reduction system is
used which is demonstrated to have at least a
90 percent control device efficiency, approved by
the Agency and approved by USEPA as a SIP
revision, and
4) The printing line is equipped with a capture
system and control device that provides an overall
reduction in VON emissions of at least:
A) 75 percent where a publication rotogravure
printing line is employed, or
01140-06214

217
B) 65 percent where a packaging rotogravure
printing line is employed, or
C) 60 percent where a flexographic printing line
is employed, and
5) The control device is equipped with the applicable
monitoring equipment specified in Section
218.105(d) (2) of this Part andT except as provided
in Section 218.105(d) (3) of this Part, the
monitoring equipment is installed, calibrated,
operated and maintained according to vendor
specifications at all times the control device is
in use, and
6) The capture system and control device are operated
at all times when the subject printing line is in
operation. The owner or operator shall
demonstrate compliance with this subsection by
using the applicable capture system and control
device test methods and procedures specified in
Section 218.105(c) through Section 218.105(f)
p1
this Part and by complying with the recordkeeping
and reporting requirements specified in Section
218.404(e) of this Part.
(Source: Amended at
Ill. Reg.
______,
effective
___________
Section 218.402
Applicability
a) The limitations of Section 218.401 of this Part apply
to all flexographic and rotogravure printing lines at a
subject facilitysource. All facilities-sources with
flexographic and/or rotogravure printing lines are
subject f-acilitiessources unless:
1) Total maximum theoretical emissions of VON from
all flexographic and rotogravure printing line(s)
(including solvents used for cleanup operations
associated with fiexographic and rotogravure
printing line(s)) at the facilitysource never
exceed 90.7 Mg (100 tons) per calendar year before
the application of capture systems and control
devices, or
2) A federally enforceable construction permit or SIP
revision for all flexographic and rotogravure
printing line(s) at a facilitysource requires the
owner or operator to limit production or capacity
of these printing line(s) to reduce total VON
emissions from all flexographic and rotogravure
printing line(s) to 90.7 Mg (100 tons) or less per
01140-0625

218
calendar year before the application of capture
systems and control devices.
b) Upon achieving compliance with this Subpart, the
emission source is flexographic and rotogravure
printing lines are not required to meet Subpart G
(Sections 218.301 or 2-l~-218.3-8-02 of this Part).
Emission sources Flexo~raphicand rotogravure printing
lines exempt from this Subpart are subject to Subpart G
(Sections 218.301 or 2-l-5-218.3-8-02 of this Part).
Rotogravure or flexographic equipment used for both
roll printing and paper coating is subject to this
Subpart.
c) Once subject to the limitations of Section 218.401, a
flexographic or rotogravure printing line is always
subject to the limitations of Section 218.401 of this
Part.
d) Any owner or operator of any flexographic or
rotogravure printing line that is exempt from the
limitations of Section 218.401 of this Part because of
the criteria in this Section is subject to the
recordkeeping and reporting requirements specified in
Section 218.404(b) of this Part.
(Source: Amended at
Ill.
Reg.
______,
effective
___________
Section 218.403
Compliance Schedule
Every owner or operator of a flexographic and/or rotogravure
printing line shall comply with the applicable requirements of
Section 218.401 and Section 218.404 of this Part in accordance
with the applicable compliance schedule specified in subsection
(a), (b)
,
(c) or (d) below:
a) No owner or operator of a flexographic or rotogravure
printing line which is exempt from the limitations of
Section 218.401 of this Part because of the criteria in
Section 218.402 of this Part shall operate said
printing line on or after a date consistent with
Section
218.106 of this Part, unless the owner or
operator has complied with, and continues to comply
with, Section 218.404(b) of this Part.
b) No owner or operator of a flexographic or rotogravure
printing line complying by means of Section 218.401(a)
of this Part shall operate said printing line on or
after a date consistent with Section 218.106 of this
Part, unless the owner or operator has complied with,
and continues to comply with, Section 218.401(a) and
Section 218.404(c) of this Part.
o
1140-0626

219
c) No owner or operator of a flexographic or rotogravure
printing line complying by means of Section 218.401(b)
of this Part shall operate said printing line on or
after a date consistent with Section 218.106 of this
Part, unless the owner or operator has complied with,
and continues to comply with, Section 218.401(b) and
Section 218.404(d) of this Part.
d)
No owner or operator of a flexographic or
rotogravure
printing line complying by means of Section 218.401(c)
of this Part shall operate said printing line on or
after a date consistent with Section 218.106 of this
Part, unless the owner or operator has complied with,
and continues to comply with, Section 218.401(c) and
Section 218.404(e) of this Part.
(Source: Amended at
Ill. Reg.
______,
effective
___________
Section 218.404
Recordkeeping and Reporting
a) The VOM content of each coating and ink and the
efficiency of each capture system and control device
shall be determined by the applicable test methods and
procedures specified in Section 218.105 of this Part to
establish the records required under this Section.
b) Any owner or operator of a printing line which is
exempted from the limitations of Section 218.401
p1
this Part because of the criteria in Section 218.402
p1
this Part shall comply with the following:
1) By a date consistent with Section 218.106 of this
Part, the owner or operator of a facility
flexographic and rotogravure printing line to
which this subsection is applicable shall certify
to the Agency that
the facility flexographic and
rotogravure printing line is exempt under the
provisions of Section 218.402 of this Part. Such
certification shall include:
A) A declaration that the facilityflexographic
and rotogravure printing line is exempt from
the limitations of the criteria in Section
218.401 of this Part because of Section
218.402 of this Part, and
B) Calculations which demonstrate that total
maximum theoretical
emissions of VON from all
flexographic and rotogravure printing lines
at the facilitysource never exceed 90.7
Mg
(100 tons) per calendar year before the
application of capture systems and control
01140-0627

220
devices. Total maximum theoretical emissions
of VON £or a flexographic or rotogravure
printing facilitysource
is the sum of maximum
theoretical
emissions of VON from each
flexographic and rotogravure printing line at
the facilitysource. The following equation
shall be used to calculate total maximum
theoretical emissions of VON per calendar
year before the application of capture
systems and control devices for each
flexographic and rotogravure printing line at
the facilitysource:
E~=AxB+l095 (CxDxF)
where:
E~
=
Total maximum theoretical emissions
of VOM from one flexographic or
rotogravure printing line in units
of kg/year (lbs/year)~~
A
=
Weight of VON per volume of solids
of the coating or ink with the
highest VON content as applied each
year on the printing line in units
of kg VOM/l
(lbs VON/gal) of
coating or ink solidsT~ an4
B
=
Total volume of solids for all
coatings and inks that can
potentially be applied each year on
the printing line in units of
1/year (gal/year). The instrument
and/or method by which the owner or
operator accurately measured or
calculated the volume of each
coating and ink as applied and the
amount that can potentially be
applied each year on the printing
line shall be described in the
certification
to the Agency--;
Weight of VON
per volume of
material for the c1eanu~material
or solvent with the highest VON
content as used each year on the
printing line in units of
K~/l
(lbs
VON/gal) of such material;
The greatest volume of cleanup
material or solvent used in any
01 li.0-0628

221
8—hour period and
F
=
The highest fraction of cleanup
material or solvent which is not
recycled or recovered for offsite
disposal during any 8-hour period.
2)
On and after a date consistent with Section
218.106 of this Part, the owner or operator of a
facility flexographic and rotogravure printing
line referenced in this subsection shall collect
and record all of
the following information each
year for each printing line and maintain the
information at the facilitysource for a period of
three years:
A)
The name and identification
number of each
coating and ink as applied on each printing
line.
B)
The VON content and the volume of each
coating and ink as applied each year on each
printing line.
3) On and after a date consistent with Section
218.106 of this Part, the owner or operator of a
facility £lexographic and rotogravure printing
line exempted from the limitations of Section
218.401 of this Part because of the criteria in
Section 218.402 of this Part
shall notify the
Agency of any record showing
that total maximum
theoretical emissions of VON from all printing
lines exceed 90.7 Mg (100 tons) in any calendar
year before the application of capture systems and
control devices by sending a copy of such
record
to the Agency within 30 days after the exceedance
occurs.
c)
Any
owner or operator of a printing line subject to the
limitations of Section 218.401 of this Part and
complying by means of Section 218.401(a) of this Part
shall comply with the following:
1)
By a date consistent with Section 218.106 of this
Part, or upon initial start-up of a new printing
line, or upon changing the method of compliance
from an existing subject printing line from
Section 218.401(b) or Section 218.401(c) of this
Part to Section 218.401(a) of this Part, the
owner
or operator of a subject printing line shall
certify to the Agency that the printing line will
be in compliance with Section 218.401(a) of this
01140-0629

222
Part on and after a date consistent with Section
218.106 of this Part, or on
and after the initial
start-up date. Such certification shall include:
A)
The name and identification
number of each
coating and ink as applied on each printing
line.
B)
The VON content of each coating and ink as
applied each day on each printing line.
2) On and after a date consistent with Section
218.106 of this Part, or on and after the initial
start—up date, the owner or operator of a printing
line subject to
the limitations of Section 218.401
of this Part and complying by means of Section
218.401(a) of
this Part shall collect and record
all of the following information each day for each
coating line and maintain the information at the
facilitysource for a period of three years:
A) The name and identification number of each
coating and ink as applied on each printing
line.
B)
The VON content of each coating and ink as
applied each day on each printing line.
3)
On and after a date consistent with Section
218.106 of this Part, the owner or operator of a
subject printing line shall notify the Agency in
the following instances:
A) Any record showing violation of Section
218.401(a) of this Part shall be reported by
sending a copy of such record to the Agency
within 30 days following the occurrence of
the violation.
B) At least 30 calendar
days before changing the
method of compliance with Section 218.401
p1
this Part from Section 218.401(a) of this
Part to Section 218.401(b) or (c) of this
Part, the owner or operator shall comply with
all requirements of subsection (b) (1)—or
(c) (1) Cd) (1) or (e) (1) of this Section,
respectively.
Upon changing the method of
compliance with Section 218.401 of this Part
from Section 218.401(a) of this Part to
Section 218.401(b) or (c) of this Part, the
owner or operator shall comply with all
requirements of subsection -(-~)-j4) or -(-e-)-j~j
01140-0630

223
of this Section, respectively.
d) Any owner or operator of a printing line subject to the
limitations of Section 218.401 of
this Part and
complying by means of Section
218.401(b) shall comply
with the following:
1)
By a date consistent with Section 218.106 of this
Part, or upon initial start-up of a new printing
line, or upon changing the method of compliance
for an existing subject printing line from Section
218.401(a) or (c) of this Part to Section
218.401(b) of this Part,
the owner or operator of
the subject printing line shall certify to the
Agency that the printing line will be in
compliance with Section 218.401(b) of this Part on
and after a date consistent with Section 218.106
of this Part, or on
and after the initial start-up
date. Such
certification shall include:
A) The name and identification number of each
printing
line which will comply by means of
Section 218.401(b) of this Part.
13) The name and identification number of each
coating and
ink available for use
on each
printing line.
C) The VON content of each coating and ink as
applied each day on each printing line.
D) The instrument or method by which the owner
or operator will accurately measure or
calculate the volume of each coating and ink
as applied each day on each printing line.
E) The method by which the owner or operator
will create and maintain records each day as
required in subsection -(-b~-~jj2) of this
Section.
F) An example of the format
in which the records
required in subsection (-è-)-j~1(2) of this
Section will be kept.
2)
On and after a date consistent with Section
218.106 of this Part, or on and after the initial
start—up date, the owner or operator of a printing
line subject to the limitations of Section 218.401
of this Part and complying by means of Section
218.401(b) of this Part shall collect and
record
all of the following information each day for each
01t400631

224
printing line and maintain the information at the
facilitysource for a period of three years:
A)
The name and identification
number of each
coating and ink
as applied on each printing
line.
B) The VON content and the
volume of each
coating and ink as applied each day on each
printing line.
C)
The daily-weighted average VON content of all
coatings and inks as applied on each printing
line.
3) On
and after a date consistent with Section
218.106 of this Part,
the owner or operator of a
subject printing line shall notify the Agency in
the following instances:
A) Any record showing violation of Section
218.401(b) of this Part shall be reported by
sending a copy of such record to the Agency
within 30 days
following the occurrence of
the violation.
B) At least 30 calendar
days
before changing the
method of compliance with Section 218.401
p1
this Part from Section 218.401(b) of this
Part to Section 218.401(a) or 218.401(c)
p1
this Part, the owner or operator shall comply
with all requirements of subsection (c) (1)
or
(e) (1) of this Section, respectively.
Upon
changing the method of compliance with
Section 218.401 of this Part from Section
218.401(b) of this Part to Section 218.401(a)
or
(C)
of this Part,
the owner or operator
shall comply with all requirements of
subsection (c) or (e) of this Section,
respectively.
e) Any owner or operator of a printing line subject to the
limitations of Section 218.401 of this Part and
complying by means of Section 218.401(c) of this Part
shall comply with the following:
1) By a date consistent with Section 218.106 of this
Part, or upon
initial start-up of a new printing
line, or upon changing the method of compliance
for an existing printing line from
Section
218.401(a) or (b) of this Part to Section
218.401(c) of this Part, the owner or operator of
0 1140-0632

225
the subject printing line shall perform all tests
and submit to the Agency the results of all
tests
and calculations necessary to demonstrate that the
subject printing line will be in compliance with
Section 218.401(c) of this Part on
and after a
date consistent with Section 218.106 of this Part,
or on and after the initial start-up date.
2)
On and after a date consistent with Section
218.106 of this Part, or on and after the initial
start—up date, the owner or operator of a printing
line subject to the limitations of Section 218.401
of this Part and complying by means of Section
218.401(c) of this Part shall collect and record
all of the following information each day for each
printing line and maintain the
information at the
facility for a period of three years:
A) Control device monitoring data.
B) A log of operating time for the capture
system, control device, monitoring equipment
and the associated printing line.
C) A maintenance log for the capture system,
control device and monitoring equipment
detailing all routine and non-routine
maintenance performed including dates and
duration of any outages.
3) On and after a date consistent with Section
218.106 of this Part, the owner
or operator of a
subject printing line shall notify the Agency in
the following instances:
A) Any record showing violation of Section
218.401(c) of this Part,
shall be reported by
sending a copy of such record to the Agency
within 30
days following the occurrence of
the violation.
B)
At least 30
calendar days before changing the
method of compliance with Section 218.401
p1
this Part
from Section 218.401(c) of this
Part to Section 218.401(a) or (b) of this
Part, the owner or operator
shall comply with
all requirements of subsection (c) (1) or
(d) (1) of this Section, respectively.
Upon
changing the method of compliance with
Section 218.401 of this Part from
Section
218.401(c) of this Part to Section 218.401(a)
or (b) of this Part, the owner or operator
01140-0633

226
shall comply with all requirements of
subsection (c) or (d)
of this Section,
respectively.
(Source:
Amended at
Ill. Reg.
______,
effective
_______
Section 218.405
Heatset-Web-Off set Lithographic Printing
a)
Applicability
1)
The limitations of subsection (b) below apply to
all heatset-web-off set lithographic printing lines
at a
subject facilitysource. All facilities
sources with heatset—web-offset lithographic
printing lines are subject facilities-sources
unless:
A) Total maximum theoretical emissions of VON
from all heatset—web—offset lithographic
printing lines at the facilitysource
never
exceed 90.7 Mg (100 tons) per calendar year
in the absence of air pollution control
equipment, or
B) A federally enforceable construction permit
or SIP revision
for all heatset—web-offset
lithographic printing 1inesj~jat a facility
source requires the owner or operator to
limit production or capacity of these
printing line(s) to reduce total VON
emissions from
all heatset—web-offset
lithographic printing line(s) to 90.7 Mg
(100 tons) per calendar year or less in the
absence of air pollution control equipment,
and
2)
Any owner or operator of any heatset—web—offset
lithographic printing line that is exempt from the
limitations in subsection (b) of this Section
because of the criteria in subsection (a) (1) p1
this Section shall be subject to the recordkeeping
and reporting requirements in subsection (c) (1)
p1
this Section.
b) Specific Provisions. No owner or operator of a subject
heatset—web—off set printing line may cause or allow the
operation of the subject heatset-web-off set printing
line unless the owner or operator meets the
requirements in subsection (b) (1) or (b) (2) and the
requirements in subsections (b) (3) and (b) (4) below.
1) An afterburner system is installed and operated
01140-06314

227
that reduces 90 percent of the VON emissions from
the dryer exhaust, or
2)
The fountain solution contains no more than
8 percent, by weight, of VON and a condensation
recovery system is installed and operated that
removes at least
75 percent of the non—isopropyl
alcohol organic materials from the dryer exhaust,
and
3)
The control device is equipped with the applicable
monitoring equipment specified in Section
218.105(d) (2) of this Part and the monitoring
equipment is installed,
calibrated,
operated and
maintained according to vendor
specifications at
all times the control device is in use, and
4)
The control device is operated at all times when
the subject printing line is in operation.
The
owner or operator shall demonstrate compliance
with this Section by using the applicable test
methods and procedures specified in Section
218.105(a), Cd), and (f) of this Part and by
complying with the recordkeeping and reporting
requirements specified in subsection (c) below.
c)
Recordkeeping and Reporting.
The VON content of each
fountain solution and ink and the efficiency of each
control device shall be determined by the applicable
test methods and procedures specified in Section
218.105 of this Part to establish the records
required
under this subsection.
1) Any owner or operator of a printing line which is
exempted from the limitations of subsection (b)
p1
this Section because of the criteria in
subsection
(a) of this Section shall comply with the
following:
A)
By a date consistent with Section 218.106
p1
this Part, the owner or operator of a
facility heatset- web-offset lithographic
printing line to which subsection (c)
(1)of
this Section is applicable shall certify to
the Agency that the facility heatset-web-
offset lithographic printing line is
exempt
under the provisions of subsection (a)
p1
this Section.
Such certification
shall
include:
i) A declaration that the facility heatset-
web-of fset lithographic printing line is
01140-0635

228
exempt from the limitations of
subsection (b) of this Section because.
of the criteria in subsection (a) p~
this Section, and
ii)
Calculations which demonstrate that
total maximum theoretical emissions of
VON from all heatset-web-offset
lithographic printing lines at the
facilitysource never exceed 90.7 Mg
(100 tons) per calendar year before the
application of air pollution control
equipment. Total maximum theoretical
emissions of VON for a heatset—web—
of f set lithographic printing facility
source is the sum of maximum theoretical
emissions of VOM from each heatset—web—
off set lithographic printing line at the
facilitysource.
The following equation
shall be used to
calculate total maximum
theoretical emissions of VON per
calendar year in the absence of air
pollution control equipment for each
heatset-web-offset lithographic printing
line at the facilitysource.
=
(A x B) + (C x D)+1095 (F x G x H)
100
where:
=
Total maximum theoretical
emissions of VON from one
heatset—web—offset printing
line in units of kg/year
(lbs/year)~j~
A
=
Weight of VOM per volume of
solids of ink with the highest
VON content as applied each
year on the printing line
in
units of kg VOM/l (lbs
VON/gal) of solids, and~
B
=
Total volume of solids for all
inks that can potentially be
applied each year on the
printing line in units of
1/year (gal/year). The
instrument or method by which
the owner or operator
accurately measured or
O~
14Q-0636

229
calculated the volume of each
ink as applied and the amount
that can potentially be
applied each year on the
printing line shall be
described in the certification
to the Agency--j
C
=
The weight percent VON of the
fountain solution with the
highest VON content--i
D
=
The total volume of fountain
solution that can potentially
be used each year on the
printing line in
units of
1/year (gal/year). The
instrument and/or method by
which the owner or operator
accurately measured or
calculated the volume of each
fountain solution used and the
amount that
can potentially be
used each year on the printing
line shall be described in the
certification
to the Agency-~j
Weight of VON per volume of
material for the cleanup
material or solvent with the
highest VON content as used
each year on the printing line
in units of Kg/i (lbs VON/gal)
of such material
B
=
The greatest volume of cleanup
material or solvent used in
any 8-hour period and
The highest fraction of
cleanup material or solvent
which is not recycled or
recovered for offsite disposal
during any 8-hour period.
B)
On and after a date consistent with Section
218.106 of this Part,
the owner or operator
of
a facilityheatset—web-off set lithographic
printing line
to which subsection (c) (1) of
this Section
is applicable shall collect and
record all of the following information each
year for each printing line and maintain the
01140-0637

230
information at the facilitysource for a
period of three years:
i)
The name and identification
of each
fountain solution and ink as applied on
each printing line.
ii)
The VON content and the volume of each
fountain solution and ink as applied
each year on each printing line.
C)
On and after a date consistent with Section
218.106 of this Part, the owner or operator
of a facilitysource exempted from the
limitations of subsection (b) of this Section
because of the criteria in subsection (a)
p1
this Section shall notify the Agency of any
record showing that total maximum theoretical
emissions of VON from all printing lines
exceed 90.7 Mg (100 tons) in any calendar
year in the absence of air pollution control
equipment by sending a copy of such record to
the Agency within 30 days after the
exceedance occurs.
2)
Any owner or operator of a printing line subject
to the limitations of subsection (b) of this
Section and complying by means of subsection
(b) (1) of this Section shall comply with the
following:
A)
By a date consistent with Section 218.106
p1
this Part, or upon initial
start—up of a new
printing line, or upon changing the method of
compliance for an existing printing line from
subsection (b) (2) to subsection (b) (1)
p1
this Section the owner or operator of the
subject printing line
shall perform all tests
and
submit to the Agency the results of all
tests and calculations necessary to
demonstrate that the subject printing line
will be in compliance with subsection (b) (1)
of this Section on and after a date
consistent with Section 218.106 of this Part,
or on and after the
initial start—up date.
B)
On and after a date consistent with Section
218.106 of this Part, or on and after the
initial start—up date, the owner or operator
of a printing line subject to the limitations
of subsection (b) of this Section and
complying by means of subsection (b) (1)
p1
01140-0638

231
this Section shall collect and record the
following information each day for each
printing line and maintain the information at
the facilitysource for a period of three
years:
i) Control device monitoring data.
ii) A log of operating time for the control
device, monitoring equipment and the
associated printing line.
iii) A maintenance log
for the control device
and
monitoring equipment detailing all
routine and nonroutine maintenance
performed including dates and duration
of any outages.
C)
On and after a date consistent with
Section
218.106 of this Part, the owner or operator
of a subject printing line shall notify the
Agency in the following instances:
i) Any record showing violation of
subsection (b) (1) of this Section shall
be reported by sending a copy of such
record to the Agency within 30 days
following the occurrence of the
violation.
ii)
At least 30 calendar days
before
changing the method of compliance with
subsection (b) of this Section from
subsection (b) (1) to (b) (2) of this
Section, the owner or operator shall
comply with all requirements of
subsection (c)
(3) (A) of this Section.
Upon changing the method of compliance
with subsection (b) of this Section from
subsection (b) (1) to (b) (2) of this
Section, the owner or operator shall
comply with all requirements of
subsection (c) (3) of this Section.
3)
Any owner or operator of a printing line subject
to the limitations of subsection (b) of this
Section and complying by means of subsection
(b) (2) of this
Section shall comply with the
following:
A)
By a date consistent with Section 218.106
p1
this Part, or upon initial start-up of a new
0 ~140-0639

232
printing line, or upon changing the method of
compliance for an existing printing line from
subsection (b) (1) to (b) (2) of this Section
the owner or operator of the subject printing
line shall perform
all tests and submit to
the Agency and the USEPA the results of all
tests and calculations necessary to
demonstrate that the subject printing line
will be in compliance with subsection (b) (2)
of this Section on and after a date
consistent with Section 218.106 of this Part,
or on and after the initial start—up date.
B) On and after a date consistent with Section
218.106 of this Part, or on and after the
initial start—up date, the owner or operator
of a printing line subject to the
limitations
of subsection (b) of this Section and
complying by means of
subsection (b) (2)
p1
this Section shall collect and record the
following
information each day for each
printing line and maintain the information at
the facilitysource for a period of
three years:
i)
The VON content of the fountain solution
used each day on each printing line.
ii)
A log of operating time for the control
device and the associated printing line.
iii) A maintenance log for the
control device
detailing all routine and non—routine
maintenance performed including dates
and duration of any outages.
C) On and after a date consistent with Section
218.106 of this Part, the owner or operator
of a subject printing line shall notify the
Agency in the following instances:
i)
Any record
showing violation of
subsection (b) (2) shall be reported by
sending a copy of such record to the
Agency within 30 days following the
occurrence of the
violation.
ii)
At least 30 calendar days before
changing the method of compliance with
subsection (b) of this Section from
subsection (b) (2) to (b) (1) of this
Section, the owner or operator shall
01140-06140

233
comply with all requirements of
subsection (c) (2) (A) of this Section.
Upon changing the method of compliance
with subsection (b) of this Section from
subsection (b) (2) to (b) (1) of this
Section, the owner or operator shall
comply with all requirements of
subsection (c) (2) of this Section.
d) Compliance Schedule. Every owner or operator of a
heatset-web-offset
lithographic printing line shall
comply with the applicable requirements of subsections
(b) and
(c) of this Section in accordance with the
applicable compliance schedule specified in subsection
(d) (1), (d) (2)
,
or (d) (3) below:
1) No owner or operator of a heatset—web—offset
lithographic printing
line which is exempt from
the limitations of subsection (b) of this Section
because of the criteria in subsection (a) of this
Section shall operate said printing line on or
after a date consistent with Section 218.106
p1
this Part, unless the owner or operator has
complied with, and
continues to comply with,
subsection -(-b-)-~~j(1)and (c) (1) of this Part.
2) No owner or operator of a heatset—web—offset
lithographic printing line complying by means of
subsection (b) (1) of this Section shall operate
said printing line on or after a date
consistent
with Section
218.106 of this Part, unless the
owner or operator has complied with, and continues
to comply with, subsection -(b) (2) (b) (1), (b) (3).
(b) (4) and (c) (2) of this Section.
3)
No owner or operator of a heatset—web—off set
lithographic printing line complying by means of
subsection (b) (2) of this Section shall operate
said printing line on or after a date consistent
with Section 218.106 of this Part, unless the
owner or operator has complied with, and continues
to comply with, subsection (b) (2), (b) (3). (b) (4)
(C)
(3) of this Section.
(Source: Amended at
Ill. Reg.
______,
effective
__________
SUBPART
Q:
LEAKS FROM SYNTHETIC ORGANIC CHEMICAL AND POLYMER
MANUFACTURING EQUIPMENT
Section 218.421
General Requirements
The owner or operator of a plant which processes more than 3660
01140-06141

234
mg/yr (4033 tons/year) gaseous and light liquid VON, and whose
components are used to manufacture the synthetic organic
chemicals or polymers listed in Appendix A, shall comply with
this Subpart. The provisions of this Subpart
are applicable to
components containing 10. percent or more by weight VON as
determined by ASTM method E-168, E-l69 and E-260, incorporated by
reference in Section 218.112 of this Part.
Those components that
are not process unit components are exempt from this Subpart.
A
component shall be considered to be leaking if
the VON is equal
to,
or is greater than 10,000 ppinv as methane or hexane as
determined by USEPA Reference Method 21, as specified at 40 CFR
60, Appendix A, incorporated by reference in Section 218.112 of
this Part, indication of liquids dripping, or indication by a
sensor that a seal or barrier fluid system has failed.
The
provisions of this Subpart are not applicable if the equipment
components are used to produce heavy liquid chemicals only from
heavy liquid feed or raw materials.
(Source:
Amended at
Ill. Reg.
______,
effective
___________
Section 218.422
Inspection Program Plan for Leaks
The owner or operator of a synthetic organic chemical or polymer
manufacturing plant subject to Section
218.421 of this Part shall
prepare an inspection program plan which contains, at a minimum:
a)
An identification
of all components and the period in
which each will be monitored pursuant to Section
218.423 of this Part.
b) The format for the monitoring log required by Section
218.425 of this Part.
c)
A description of the monitoring equipment to be used
when complying with Section 218.423 of
this Part, and
d) A description of the methods to be used to identify all
pipeline valves, pressure relief valves in
gaseous
service, all leaking components, and components
exempted under Section 218.423-f4-)-~jj~of this Part such
that they are obvious and can be located by both plant
personnel performing monitoring and Agency personnel
performing inspections.
(Source: Amended at
Ill. Reg.
______,
effective__________
Section 218.423
Inspection Program for Leaks
The owner or operator of a synthetic organic chemical or polymer
manufacturing plant subject to this ~ubpart
shall, for the
purposes of detecting leaks, conduct a component inspection
program using the test
methods specified in Method 21, 40 CFR 60,
01140-06142

235
Appendix A (1986), incorporated by reference in Section 218.112
of this Part, consistent with the following provisions:
a)
Test annually those components Operated near extreme
temperature or pressure such that
they would be unsafe
to routinely monitor and those
components which would
require the elevation of monitoring personnel higher
than two meters above permanent worker access
structures or surfaces.
b) Test quarterly all other pressure relief valves in gas
service, pumps in light liquid service, valves in light
liquid service and in gas service, and compressors.
c) If less than or equal to 2 percent of the valves in
light liquid service and in gas service tested pursuant
to subsection (b) of
this Section are found
~ to leak
for five consecutive quarters, no leak tests shall be
required for three consecutive quarters. Thereafter,
leak tests shall resume for the next quarter. If that
test shows less than or equal to 2 percent of the
valves in light liquid service and in gas service are
leaking, then no tests are required for the next
three quarters. If more than 2 percent are leaking,
then tests are required for the next five quarters.
d) Observe visually all pump seals weekly.
e) Test immediately any pump seal from which liquids are
observed dripping.
f)
Test any relief valve within 24 hours after it has
vented to the atmosphere.
g) Routine instrument monitoring of valves which are not
externally regulated, flanges, and equipment in heavy
liquid service, is not required. However, any valve
which is not externally regulated, flange or piece of
equipment in heavy liquid service that is found to be
leaking on
the basis of sight, smell or sound shall be
repaired as soon as practicable but no
later than
30 days after the leak is found.
h) Test immediately after repair
any component that was
found leaking.
i) Within one hour of its detection, a weatherproof,
readily visible tag, in bright colors such as red or
yellow, bearing an
identification number and the date
on which the leak was detected must be affixed on the
leaking component and remain in
place until the leaking
component i~ repaired.
01140-06143

236
j)
The following components are exempt from the monitoring
requirements in this Section:
1)
Any component that is in vacuum service, and
2) Any pressure relief
valve that is connected to an
operating flare header or vapor recovery device.
(Source:
Amended at
Ill. Reg.
______,
effective
__________)
Section 218.424
Repairing Leaks
All leaking components must be repaired and retested as soon as
practicable but no later than 15 days after the leak is found
unless the leaking component cannot be repaired
until the process
unit is shut down. Records of repairing
and retesting must be
maintained in accordance
with Section 218.425 and 218.426 of this
Part.
(Source: Amended at
Ill. Reg.
______,
effective
__________)
Section 218.425
Recordkeeping for Leaks
a) The owner or operator of a synthetic organic chemical
or polymer manufacturing plant shall maintain a leaking
components monitoring log which shall contain, at a
minimum, the following information:
1)
The name of the process unit where the component
is located;
2) The type
of component (e.g., valve, seal);
3) The identification number of the component;
4)
The date on which a leaking component is
discovered;
5) The date on which a
leaking component is repaired;
6) The date and instrument reading of the recheck
procedure after a leaking component is repaired;
7) A record of the calibration of the monitoring
instrument;
8) The identification number of leaking components
which cannot be repaired until process unit
shutdown; and
9) The total number of valves in light liquid service
and in gas
service inspected; the total number and
01140-061414

237
the percentage of
these valves found leaking
during the monitoring period.
b)
Copies of the monitoring log shall be retained by the
owner or operator for a minimum of two years after the
date on which the record was made or the report was
prepared.
c) Copies of the monitoring log shall
be made available to
the Agency~upon verbal or written request~ prior to or
at the time of inspection pursuant to Section 4(d) of
the
Environmental Protection Act (Act) (Ill. Rev. Stat.
199~,
ch. 111 1/2, pars. 1001 et seq.) 1415 ILCS 5/1
et seci.1 at any reasonable time.
(Source: Amended at
Ill. Reg.
,
effective
__________)
Section 218.426
Report for Leaks
The owner or operator of a synthetic organic chemical or polymer
manufacturing plant subject to Section 218.421 through 218.430
p1
this Part shall:
a)
Submit quarterly reports to the Agency on or before
March 31, June 30, September 30,
and December 31
of
each year, listing all leaking components identified
pursuant to Section 218.423 of this Part but not
repaired within 15 days, all leaking components
awaiting process unit shutdown, the total number of
components inspected, the type of components inspected,
and the total number of components found leaking, the
total number of valves in light liquid service and in
gas service inspected and the number and percentage of
valves in light liquid service and in gas service found
leaking.
b) Submit a signed statement with the report attesting
that all monitoring and repairs were performed as
required under Section 218.421 through 218.427 of this
Part.
(Source: Amended at
Ill. Reg.
______,
effective
___________
Section 218.427
Alternative Program for Leaks
The Agency shall approve an
alternative program of monitoring,
recordkeeping, or reporting to that prescribed in this Subpart
upon a demonstration by the owner or operator of such plant that
the alternative program will provide plantsource personnel and
Agency personnel with an equivalent ability to identify and
repair leaking components.
Any alternative
program can be
allowed if approved by the Agency and approved by the USEPA as a
01140-06145

238
SIP revision.
(Source:
Amended at
Ill. Reg.
______,
effective
___________)
Section 218.428
Open—Ended Valves
a) Each open-ended valve shall be equipped with a cap,
blind flange,
plug, or a second valve, except during
operations requiring fluid flow through the open-ended
valve.
b)
Each open—ended valve equipped with a
second valve
shall be operated in a manner such that the valve on
the process fluid end is closed before the second valve
is closed.
c) Components which are open—ended valves and which serve
as a sampling connection shall
be controlled such that
they comply with subsection(c) (1), Cc) (2) or (c) (3)
below. This requirement does not apply to in-situ
sampling systems. ÷
1) A closed purge system or closed vent system shall
return purged process
fluid to the process line
with no detectable VON emissions to the
atmosphere, or
2)
A closed purge system or closed vent system shall
collect and recycle purged process fluid to the
process line with no detectable
VON emissions to
the atmosphere, or
3) Purged process fluid shall
be transported to a
control device that complies with the requirements
of Section 218.429 of this Part. If a container is
used to transport purged process fluid to the
control device,
the container shall be a closed
container designed and used to reduce the
VON
emissions vented from purged process fluid after
transfer to no detectable VON emissions as
determined by USEPA Reference Method 21, as
specified in
40 CFR 60, Appendix A (1990 or 1991)
incorporated by reference in Section 218.112 of
this Part. For purposes of this Section, the
phrase “after transfer” shall refer to the time at
which the entire amount of purged process fluid
resulting from a flushing or cleaning of the
sample line enters the container, provided,
however, that purged process fluid may be
transferred from the initial container to another
closed container prior to disposal, e.g., to a
bulk
waste storage container.
01140-06146

239
d-)-
In—situ sampling systcms arc cxcmpt from subscction
(c).
(Source:
Amended at
Ill. Reg.
,
effective
__________)
Section 218.429
Standards for Control Devices
Control devices used to comply with Section 218.428(c) of this
Part shall comply with the following:
a)
If the control device is a vapor recovery system (for
example, condensers and adsorbers), it shall be
designed and operated to recover the VON emissions
vented to
it with an efficiency of 95 percent or
greater.
b)
If the control device is an enclosed combustion device,
it shall be designed and operated to reduce the VON
emissions vented to it with an efficiency of 95 percent
or greater, or to provide a minimum residence time of
0.75 seconds at
a minimum temperature of 816°C.
c) If the control device is a flare, it shall:
1)
Be designed for and operated with no visible
emissions as
determined by USEPA Reference Method
22, 40 CFR 60, Appendix A (1986), incorporated by
reference in Section 218.112, except for periods
not to exceed a total of
5 minutes during any 2
consecutive hours.
2)
Be operated with a pilot flame present at all
times and shall be monitored with a thermocouple
or any other equivalent device to detect the
presence of the pilot flame.
3)
Be steam—assisted, air assisted, or nonassisted.
4)
Be used only with the net heating value of the gas
being combusted being
11.2 NJ/scm (300 Btu/scf) or
greater if the flare is steam-assisted or
air-assisted; or with the net heating value of the
gas being combusted being 7.45 NJ/scm or greater
if the flare is nonassisted. The net heating
value of the gas being combusted shall be
calculated using the following equation:
n
Hr
=
Ki=l E
C1
H1
Where:
01140-06147

240
Hr
=
Net
heating value of the sample in
NJ/scm;
where the net enthalpy per
mole of of fgas is based on
combustion at 25°C and 760 mm Hg,
but the standard temperature for
determining the volume
corresponding to one mole is 20°C--;
K
=
Constant,
1.740 x 10~
(1/ppm) (g—inole/scm) (NJ/Kcal)
where
standard temperature for (g—mole/scm) is
C1
=
Concentration of sample component
i,
in ppm, as measured by USEPA
Reference Method 18, 40 CFR 60,
Appendix A (1986), and ASTM D
2504-83, both incorporated by
reference in Section 218.112,-j
=
Net heat
of combustion of sample
component i, kcal/g mole.
The
heats of combustion may be
determined using ASTM D 2382-83,
incorporated by reference in
Section 218.112
of this Part,
if
published values are not available
or cannot be calculated.
5) Steam-assisted and nonassisted flares shall be
designed
and operated with an exit velocity, as
determined by dividing the volumetric flowrate (in
units of standard temperature
and pressure), as
determined by USEPA Reference Method
2 or 2A, 40
CFR 60, Appendix A (1986) incorporated by
reference in Section 218.112 of this Part, as
appropriate; by the unobstructed (free) cross
sectional area of the flare tip, less than 18
rn/sec (60 ft/sec).
6) Air—assisted flares shall be designed and operated
with an
exit velocity less than the maximum
permitted velocity, Vmax,
as determined
by the
following equation:
Vmax
=
8.706
+
O.7O84(Hr)--:
Vmax
=
Maximum permitted velocity, m/see.~
01140-06148

241
8.706
=
Constant--j.
0.7084
=
Constant~
=
The net heating value as determined
in subsection (c) (4) of this
section.
d)
If the control device is a closed container, it shall
hr~
designed
and
nr~ratedto
reduce the VON crnissions,
vented
from
purged process fluid aftcr
dctectablc VON emissions as dctcrmincd
tran~L~r,
Lu
no
by USEPA
Rcfcrcncc Method 21 as specified at 40 CFR 60, Appendix
A (1986), incorporated by reference in
Section 218.112.
For purposes of this Section, the phrase “after
transfer” shall refer
to the time at which the entire
amount of purged process fluid resulting from a
flushing or cleaning of the sample line enters the
closed container or containers including
the final
container(s) prior to disposal. The following
information pertaining to
closed
vent systems
and
control devices sublect to Section 218.429 shall be
maintained by the owner or operator.
These records
shall be updated as necessary to describe current
operation and equipment. The records shall be
retained
at a readily accessible location at the source for a
minimum of two years after
the control device is
permanently shutdown.
~ Detailed schematics, design specifications, and
piping and instrumentation diagrams
ZL
The dates and
description of any changes in design
specifications
~j A description of the parameter or parameters
monitored and recorded as required in subsection
(f) (1) to ensure that the control devices are
operated and maintained in conformance with their
design and an explanation why
that parameter (or
parameters) was selected for monitoring.
e-)-
The owner or operator of a control device shall monitor
the control device to ensure that it is operated and
maintained in conformance with the manufacturer’s
specifications,
modified to the particular process
design.
~)
The control device shall be operated at all times when
emissions may be vented to it.
fl.
Owners and operators of control devices used to comply
with this Subpart shall monitor each control device to
ensure that the control device is operated and
01140-06149

242
maintained in conformance with
its
designs at all times
that emissions may be vented to it. This
monitoring
shall be conducted in accordance with Section
218.429(d) (3). The records prepared as part of this
monitoring activity shall include the dates of startup
and shutdown of control devices and identify periods
when the devices are not operated as designed,
including periods when a flare pilot light does not
have a flame.
gj The reguirements of subsections (d), (e) and (f) shall
not apply to a combustion device used for disposal of
purged process fluid which is subject to the BIF rules,
located at the source or which is subject to the RCRA
rules.
The owner or operator of such combustion device
shall satisfy applicable provisions of the RCRA or BIF
rules.
(Source: Amended at
Ill. Reg.
______,
effective
__________
Section 218.430
Compliance Date (Repealed)
The owner or operator of a synthetic organic chemical or polymer
manufacturing plant subject to 35 Ill. Adm. Code 215.430 through
215.438 as of December 31, 1987 shall have ~1i~
with the
standards
~.~ons
of those Cections no later than
December 31, 1987.
(Source:
Repealed at
Ill. Reg.
______,
effective
_________)
SUBPART R:
PETROLEUM REFINING AND RELATED INDUSTRIES;
ASPHALT MATERIALS
Section 218.441
Petroleum Refinery Waste Gas Disposal
a) Except as provided in subsection (b) or (c) of this
Section, no person shall cause or allow the discharge
of organic materials in excess of 100 ppm equivalent
methane (molecular weight 16.0) into the atmosphere
from:
1) Any catalyst regenerator of a petroleum cracking
system; or
2)
Any petroleum fluid coker; or
3) Any other waste gas stream from any petroleum
or
petrochemical manufacturing process.
b)
Exception.
Existing sources subject to subsection
(a) (3) of this Section may, alternatively, at their
election, comply with the organic material emission
01140-0650

243
limitations imposed by 35 Ill. Adm. Code 21~.30l or
2l~.302; provided, however, that there shall be no
increase in emissions from
such sources above the level
of emissions in existence on Nay 3, 1979.
c)
New Sources.
Sources subject to subsection (a) (3)
p1
this Section, construction of which commenced on or
after January 1, 1977, may, at their election, comply
with the following emission limitations:
1)
A maximum of eight pounds per hour of organic
material; or
2) Emission of organic material in excess of the
limitation of subsection (c) (1) of this Section is
allowable if such emissions are controlled by air
pollution control methods or equipment approved by
the Agency capable of reducing by 85 percent or
more the uncontrolled
organic material that would
otherwise be emitted to the atmosphere.
Such
methods
or equipment must
be approved by the
Agency and approved by the USEPA as a SIP
revision.
(Source: Amended at
Ill. Req.
______,
effective
__________
Section 218.443
Wastewater (Oil/Water) Separator
No owner
or operator of a petroleum refinery shall operate any
wastewater
(oil/water) separator at a
petroleum refinery unless
the separator is equipped with air pollution control
equipment
capable of reducing by 85 percent or
more the uncontrolled
organic material emitted to the atmosphere.
If no odor
nuisance
exists, the limitation of this Section shall not apply if the
vapor pressure of the organic material is below 10.34 kPa (1.5
psia) at 2~G4.3°K (70°F) at all times.
(Source: Amended at
Ill. Req.
______,
effective
___________)
Section 218.445
Leaks: General Requirements
a-)--The owner or operator of a petroleum refinery shall:
~a)
Develop a monitoring program plan consistent with the
provisions of Section 218.446;
2~b) Conduct a monitoring program consistent with the
provisions of Section 218.447;
~)
Record all leaking components which have a volatile
organic material concentration exceeding 10,000 ppm
consistent with the provisions of
Section 218.448;
Oi 140-065j

244
4~) Identify each component consistent with the monitoring
program plan submitted pursuant to
Section 218.446;
~)
Repair and retest the leaking components as soon as
possible within 22 days after the leak is found, but no
later than June 1
for
the purposes of Section
218.447(a) (1), unless
the leaking components cannot be
repaired until the unit is shut down for turnaround;
and
~)
Report to the Agency consistent with the provisions of
Section 218.449.
(Source: Amended at
Ill. Req.
______,
effective
___________
Section 218.446
Monitoring Program Plan for Leaks
The owner or operator of a petroleum refinery shall prepare a
monitoring program plan which contains, at a minimum:
a)
An identification of
all refinery components and the
period in which each will be
monitored pursuant to
Section 218.447 of this part
b) The format for the monitoring log required by Section
218.448 of this part
c) A description of the
monitoring equipment to be used
pursuant to Section 218.447 of this part and
d) A description of the methods to be used to identify all
pipeline valves, pressure relief valves in gaseous
service and all leaking components such that they are
obvious to both refinery personnel performing
monitoring and Agency personnel performing inspections.
(Source: Amended at
Ill. Reg.
______,
effective
__________)
Section 218.447
Monitoring Program for Leaks
a)
The owner or operator of a petroleum refinery subject
to Section 218.445 of this Part
shall, for the purpose
of detecting
leaks, conduct a component monitoring
program consistent with the following provisions:
1) Test once between March 1 and June
1 of each year,
by methods referenced in Section 218.105(g)
p1
this
Part, all
pump seals, pipeline valves in
liquid service and process drains~-~
2)
Test once each quarter of each calendar year, by
methods referenced in
Section 218.105(g) of this
01140-0652

245
Part, all pressure relief valves in gaseous
service, pipeline valves in gaseous service and
compressor seals--;
3) Inaccessible valves may be tested once each
calendar year instead of once each quarter of each
calendar year-a
4) Observe visually all pump seals weekly--~j
5) Test immediately any pump seal from which liquids
are observed dripping~j
6) Test any relief valve within 24 hours after it has
vented to the atmosphere~~and
7) Test immediately after repair any component that
was found leaking.
b) Storage tank valves and pressure relief devices
connected to an operating flare header or vapor
recovery device are exempt from the monitoring
requirements in subsection (a) of this Section.
c) The Agency or the USEPA may require more frequent
monitoring than would otherwise be required by
subsection (a) for components which are demonstrated to
have a history of leaking.
(Source: Amended at
Ill. Reg.
______,
effective
__________
Section 218.449
Reporting for Leaks
The owner or operator of a petroleum refinery shall:
a) Submit a report to the Agency prior to the 1st day of
both July and September listing all leaking components
identified pursuant to Section 218.447 of this Part but
not repaired within 22 days, all leaking components
awaiting unit turnaround, the total number of
components inspected and the total number of components
found leaking;
b) Submit a signed statement with the report attesting
that all monitoring and repairs were performed as
required under Sections 218.445 through 218.448 of this
Part.
(Source: Amended at
Ill. Reg.
______,
effective
___________)
Section 218.450
Alternative Program for Leaks
01140-0653

246
The Agency may approve an alternative program of monitoring,
recordkeeping or reporting to that prescribed in Sections 218.446
through 218.449 of this Part upon a demonstration by the owner or
operator of a petroleum refinery that the alternative program
will provide refinery, Agency and USEPA personnel with an
equivalent ability to identify and repair leaking components.
Any alternative program can be allowed only if approved by the
USEPA as a SIP revision.
(Source: Amended at
Ill. Reg.
______,
effective
__________)
Section 218.452
Compliance Schedule for Leaks
The owner or operator of a petroleum refinery shall adhere to the
increments of progress contained in the following schedule:
a) Have submitted to the U-SEPAAgency a monitoring program
consistent with Section 218.446 of this Part prior to
September 1, 1990.
b) Have submitted to the USEPAAgency the first monitoring
report pursuant to Section 218.449 of this Part prior
to October 1, 1990.
(Source: Amended at
Ill. Reg.
______,
effective
___________
Section 218.453
Compliance Dates (Repealed)
Every owner or operator of a petrolcum refinery subject to 35
Ill. Adm. Code 215, Subpart II as of December 31, 1987 shall
have
complied with its standards and limitations by December
31, 1987.
(Source: Repealed at
Ill. Reg.
______,
effective
_________
SUBPART S: RUBBER AND MISCELLANEOUS PLASTIC PRODUCTS
Section 218.461
Manufacture of Pneumatic Rubber Tires
The owner or operator of an undertread cementing, treadend
cementing or bead dipping operation at a pneumatic rubber tire
manufacturing facilitysource shall install and operate:
a) A capture system, with minimum capture efficiency of 65
percent by weight of VON for treadend cementing or bead
dipping operations and a capture system with a minimum
capture efficiency of 55.5 percent by weight of VON for
undertread cementing; and
b) A control device that meets the requirements of one of
the following:
1) A carbon adsorption system designed and operated
01140-06514

247
in a manner such that there is at least a 90
percent removal of VON by weight from the gases
ducted to the control device;
2) An afterburning system that oxidizes at least 90
percent of the captured nonmethane VONs (VON
measured as total combustible carbon) to carbon
dioxide and water; and
3) An alternative VON emission reduction system
demonstrated to have at least a 90 percent overall
reduction efficiency and approved by the Agency
and approved by the USEPA as a SIP revision.
(Source: Amended at
Ill. Reg.
~
effective
__________)
Section 218.462
Green Tire Spraying Operations
The owner or operator of a green tire spraying operation at a
pneumatic rubber tire manufacturing facili~ysource shall:
a) Install and operate:
1) A capture system with a minimum capture efficiency
of 90 percent by weight of VON; and
2) A control device that meets the requirements of
one of the following:
A) A carbon adsorption system designed and
operated in a manner such that there is at
least 90 percent removal of VOM by weight
from the ba-sesqases ducted to the control
device;
B) An afterburning system that oxidizes at least
90 percent of the captured nonmethane VON
(measured as total combustible carbon) to
carbon dioxide and water; or
C) An alternative VON emission reduction system
demonstrated to have at least a 90 percent
overall reduction efficiency and approved by
the Agency and approved by the USEPA as a SIP
revision.
b) Substitute for the normal solvent—based mold release
compound water—based sprays containing:
1) No more than five percent by volume of VOM as
applied for the inside of tires;
01140-0655

248
2) No more than ten percent by volume of VON as
applied for the outside of tires.
(Source: Amended at — Ill. Req.
______,
effective
__________)
Section 218.463
Alternative Emission Reduction Systems
In lieu of complying with Section 218.461 or 218.462 of this
Part, the owner or operator of an emission source may utilize an
alternative volatile organic emission reduction system, including
an alternative production process, which is demonstrated to be
equivalent to Section 218.461 or 218.462 of this Part on
the basis of emissions of volatile organic mattermaterial. A
treadend cementing operation shall be considered equivalent to
Section 218.461 or 218.462 of this Part for the purposes of this
Section if the total volatile organic emission from such
operation is 10 grams or less per tire.
(Source: Amended at
Ill. Reg.
______,
effective
__________
Section 218.464
Testiincs and MonitoringEmission Testing
a) Upon a reasonable request by the Agency, the owner or
operator of a VON emission source required to comply
with a limit of Sections 218.461 through 218.464 p1
this Part shall conduct emissions testing, at such
person’s own expense, to demonstrate compliance.
b) A person planning to conduct a VON emission test to
demonstrate compliance shall notify the Agency of that
intent not less than 30 days before the planned
initiation of the tests so the Agency may observe the
test.
(Source: Amended at — Ill. Reg.
,
effective
__________
Section 218.465
Compliance Dates (Repealed)
Every owner or operator of an emission source subject to 35 Ill.
Adm. Code 215, Subpart 6, as of December 31, 1987 shall have
complied with its standards and limitations—by December 31, 1987.
(Source: Repealed at — Ill. Reg.
______,
effective
__________
Section 218.466
Compliance Plan (Repealed)
a-)- The owner or operator of an emission source shall have
s~ubmittedto the Agency a compliance plan, pursuant to
35 Ill. Adm. Code 201, Subpart H, including a project
completion schedule where applicable, no later than
April 21, 1983.
U
14Q-0656

249
b)- Unless the submitted compliance plan or schedule was
disapproved by the Agency, the owner or operator of a
-facility or emission source may operate the emission
source according to the plan and schedule as submitted.
The plan anu scncaujc
snaii.
mccc cne regu~remcncs o~
-~
Ill. Adin. Code 201, Subpart H, including specific
interim dates as required in 35 III. Adm. Code 201.242.
(Source: Repealed at
Ill. Req
effective
__________)
SUBPART T: PHARMACEUTICAL MANUFACTURING
Section 218.480
Applicability
a) The rules of this Subpart, except for Sections 218.483
through 218.485 of this Part, apply to all emission
sourccsunits of VON, including but not limited to
reactors, distillation units, dryers, storage tanks for
VOL1 equipment for the transfer of VOL1 filters,
crystallizers, washers, laboratory hoods,
pharmaceutical coating operations, mixing operations
and centrifuges used in manufacturing, including
packaging, of pharmaceuticals, and emitting more than
6.8 kg/day (15 lbs/day) and more than 2,268 kg/year
(2.5 tons/year) of VON. If such an emission s-ourceunit
emits less than 2,268 kg/year (2.5 tons/year) of VON,
the requirements of this Subpart still apply to the
emission sourccuhit if VON emissions from the emission
sourceunit exceed 45.4 kgJday (100 lbs/day).
b) Notwithstanding subsection (a) of this Section, the air
suspension coater/dryer, fluid bed dryers, tunnel
dryers, and Accelacotas located in Libertyville
Township, Lake County, Illinois shall be exempt from
the rules of this Subpart, except for Sections 218.483
through 218.485, if emissions of VON not vented to air
pollution control equipment do not exceed the following
levels:
1) ~or the air suspension coater/dryer: 2,268
kg/year (2.5 tons/year);
2) -f~oreach fluid bed dryer: 4,535 kg/year
(5.0 tons/year);
3) ~or each tunnel dryer: 6,803 kg/year (7.5
tons/year)
j-
and
4) ~or each Accelacota: 6,803 kg/year
(7.5 tons/year).
01 L~0-Q656~1

250
c) Sections 218.483 through 218.485 of this Part apply to
a plantsource having one or more emission sourcesunits
that:
1) Are used to manufacture pharmaceuticals, and
2) Emit more than 6.8 kg/day (15 lbs/day) of VON and
more than 2,268 kg/year (2.5 tons/year) of VOM,
or, if less than 2,268 kg/year (2.5 tons/year),
these Sections still apply if emissions from one
or more sources exceed 45.4 kg/day (100 lbs/day).
d) No owner or operator shall violate any condition in a
permit when the condition results in exclusion of an
emission sourceunit from this Subpart.
e) Any pharmaceutical manufacturing source that becomes
subject to the provisions of this Subpart at any time
shall remain subject to the provisions of this Subpart
at all times.
f) Emissions subject to this Subpart shall be controlled
at all times consistent with the requirements set forth
in this Subpart.
g) Any control device required pursuant to this Subpart
shall be operated at all times when the source it is
controlling is operated.
h) Determinations of daily and annual emissions for
purposes of this Section shall be made using both data
on the hourly emission rate (or the emissions per unit
of throughput) and appropriate daily and annual data
from records of emission s-o~rceunit operation (or
material throughput or material consumption data). In
the absence of representative test data pursuant to
Section 218.487 of this Part for the hourly emission
rate (or the emissions per unit of throughput), such
items shall be calculated using engineering
calculations, including the methods described in
Appendix B of “Control of Volatile Organic Emissions
from Manufacturing of Synthesized Pharmaceutical
Products” (EPA-450/ 2-78-029), incorporated by
reference in Section 218.112 of this Part. (This
subsection shall not affect the Agency’s or the USEPA’s
authority to require emission tests to be performed
pursuant to Section 218.487 of this Part.)
(Source: Amended at
Ill. Reg.
______,
effective
__________
Section 218.481
Control of Reactors, Distillation Units,
Crystallizers, Centrifuges and Vacuum Dryers
UI 140-0657

251
a) The owner or operator shall equip all reactors,
distillation units, crystallizers, centrifuges and
vacuum dryers that are used to manufacture
pharmaceuticals with surface condensers or other air
pollution control equipment listed in subsection (b)
p1
this Section. If a surface condenser is used, it shall
be operated such that the condenser outlet gas
temperature does not exceed:
1) 248.2°K (-13°F) when condensing VON of vapor
pressure greater than 40.0 kPa (5.8 psi) at
294.3°I (70°F), or
2) 258.2°K (5°F) when condensing VON of vapor
pressure greater than 20.0 kPa (2.9 psi) at
294..3°R (70°F), or
3) 273.2°X (32°F) when condensing VON of vapor
pressure greater than 10.0 kPa (1.5 psi) at
294.3°K (70°F), or
4) 283.2°K (50°F) when condensing VON of vapor
pressure greater than 7.0 kPa (1.0 psi) at 294.3°K
(70°F), or
5) 298.2°K (77°F) when condensing VON of vapor
pressure greater than 3.45 kPa (0.5 psi) at
294.3°K (70°F)
b) If a scrubber, carbon adsorber, thermal afterburner,
catalytic afterburner, or other air pollution control
equipment other than a surface condenser is used, such
equipment shall provide a reduction in the emissions of
VON of 90 percent or more.
c) The owner or operator shall enclose all centrifuges
used to manufacture pharmaceuticals and that have an
exposed VOL surface, where the VON in the VOL has a
vapor pressure of 3.45 kPa (0.5 psi) or more at 294.3°K
(70°F), except as production, sampling, maintenance, or
inspection procedures require operator access.
(Source: Amended at
Ill. Req.
______,
effective
_________)
Section 218.482
Control of Air Dryers, Production Equipment
Exhaust Systems and Filters
a) The owner or operator of an air dryer or production
equipment exhaust system used to manufacture
pharmaceuticals shall control the emissions of VON from
such emission courcesunit by air pollution control
equipment which reduces by 90 percent or more the VON
01140-0658

252
that would otherwise be emitted into the atmosphere.
b) The owner or operator shall enclose all rotary vacuum
filters and other filters used to manufacture
pharmaceuticals and that have an exposed VOL surface,
where the VON in the VOL has a vapor pressure of 3.45
kPa (0.5 psi) or more at 294~°K(70°F),except as
production, sampling, maintenance, or inspection
procedures require operator access.
(Source: Amended at
Ill. Reg.
______,
effective
__________
Section 218.483
Material Storage and Transfer
The owner or operator of a pharmaceutical manufacturing
p1antsour~ shall:
a)
Provide a vapor balance system that is at least
90 percent effective in reducing VON emissions from
truck or railcar deliveries to storage tanks with
capacities equal
to or greater than 7.57 m3 (2,000 gal)
that store VOL with vapor pressures greater than
28.0 kPa (4.1 psi) at 294.3°K (70°F), and
b) Install, operate, and maintain pressure/vacuum
conservation vents set at 0.2 kPa (0.03 psi) or greater
on all storage tanks that store VOL with vapor
pressures greater than 10 kPa (1.5 psi) at 294.3°I
(70°F).
(Source:
Amended at
Ill. Reg.
______,
effective
___________)
Section 218.485
Leaks
The owner or operator of a pharmaceutical manufacturing
plantsource shall repair any component from which a leak of VOL
can be observed. The repair shall be completed as soon as
practicable but no later than 15 days after the leak is found.
If the leaking component cannot be repaired until the process
unit is shut down, the leaking component must then be repaired
before the unit is restarted.
(Source: Amended at
Ill. Reg.
______,
effective
__________
Section 218.486
Other Emission sources Units
The owner or operator of a washer, laboratory hood, tablet
coating operation, mixing operation or any other process emission
sourceunit not subject to Sections 218.481 through 218.485
p1
this Part, and used to manufacture pharmaceuticals shall control
the emissions of VON from such emission ~ourccsunits by:
UI i~0-Q659

253
a) Air pollution control equipment which reduces by
81 percent or more the VOM that would otherwise be
emitted to the atmosphere, or
b) A surface condenser which captures all the VON which
would otherwise be emitted to the atmosphere and which
meets the requirements of Section 218.481(a) of this
Part and (b)-.
(Source: Amended at
Ill. Reg.
______,
effective
___________)
Section 218.487
Testing
a) Upon request by the Agency or the TJSEPA, the owner or
operator of any VON emission source subject to this
Subpart or exempt from this Subpart by virtue of the
provisions of Section 218.480 of this Part shall, at
his own expense, demonstrate compliance to the Agency
and the USEPA by the methods or procedures listed in
Section 218.105(f) (1) of this Part.
b) A person planning to conduct a VON emissions test to
demonstrate compliance with this Subpart shall notify
the Agency and the USEPA of that intent not less than
30 calendar days before the planned initiation of the
test.
(Source: Amended at — Ill. Req.
______,
effective
__________
Section 218.489
Recordkeeping for Air Pollution Control
Equipment
a) The owner or operator of a pharmaceutical manufacturing
facility source shall maintain the following records:
1) Parameters listed in Section 218.488(a)-(4-)- of this
Part shall be recorded.
2) For sourcesemission units subject to Section
218.481, of this Part, the vapor pressure of VON
being controlled shall be recorded for every
process.
b) For any leak subject to Section 218.485 of this Part
which cannot be readily repaired within one hour after
detection, the following records shall be kept:
1) The name of the leaking equipment,
2) The date and time the leak is detected,
3) The action taken to repair the leak, and
0
140-0660

254
4) The datga and time the leak is repaired.
c) The following records shall be kept for emission
s-o-urcesunits subject to Section 218.484 of this Part
which contain VOL:
1) For maintenance and inspection:
A) The date and time each cover is opened,
B) The length of time the cover remains open,
and
C) The reason why the cover is opened.
2) For production and sampling, detailed written
procedures or manufacturing directions specifying
the circumstances under which covers may be opened
and the procedures for opening covers.
d) For each emission sourceunit used in the manufacture of
pharmaceuticals for which the owner or operator of a
pharmaceutical manufacturing plantsource claims
emission standards are not applicable, because the
emissions are below the applicability cutoffs in
Section 218.480(a) or 218.480(b) of this Part, the
owner or operator shall:
1) Maintain a demonstration including detailed
engineering calculations of the maximum daily and
annual emissions for each such emission s-e-urceunit
showing that the emissions are below the
applicability cutoffs in Section 218.480(a) or
218.480(b) of this Part, as appropriate, for the
current and prior calendar years;
2) Maintain appropriate operating records for each
such emission source to identify whether the
applicability cutoffs in Section 218.480(a) or
218.480(b) of this Part, as appropriate, are ever
exceeded; and
3) Provide written notification to the Agency and the
USEPA within 30 days of a determination that such
an emission sourccunit has exceeded the
applicability cutoffs in Section 218.480(a) or
218.480(b) of this Part, as appropriate.
e) Records required under subsection (a) of this Section
shall be maintained by the owner or operator for a
minimum of two years after the date on which they are
made.
0!
~~~0-066I

255
f) Copies of the records shall be made available to the
Agency or the USEPA upon verbal or written request.
(Source: Amended at
Ill. Req.
______,
effective
)
SUBPART V: AIR OXIDATION PROCESSES
Section 218.521
Definitions (Repealed)
ons of 35 Ill. Adm. Code 211, Section
definitions apply to this Subpart:
“Air Oxidation Process”: any unit process including
ammoxid~tion~nd r~rrh1nrir,.,tinn ~Thi~h uses ~ir nr ~
combination of air and oxygen as an oxidant in combination
with one or more organic reactants to produce one or more
organic compounds.
~Cost Effectiveness”: the annual expense for coot of
control of a given process stream divided by the reduction
in emissions of organic material of that stream.
“Flow (F)”: Vent stream flowratc (scm/mm) at a standard
temperature of 20°C.
“Full Operating Flowrate”: Maximum operating capacity of
the facility.
“Hourly Emissions
(E)”: Hourly emissions reported in kg/hr
measured at full opcrating flowrate-.
Value (H)”
Vent stream net heating value
(NJ/scm), where the net enthalpy per mole of ottgas
is
based
on combustion at
25°Cand 760 mm Hg, but the standard
temperature for determining the volume corresponding
to one
mole is 20°C,as in the definition of “Flow.”
“Process Vent Stream”:
An emission stream resulting from an
air oxidation process.
“Total Re
eLLCUCIVCnCOO
~n1I~
c~nt~i~ingany
gaseous stream vented to
the atmosphere from an air
oxidation process divided by $1600/Mg, using the criteria
and methods set forth in this Subpart and Appendices C and
(Source: Repealed at — Ill. Req.
______,
effective
__________
Section 218.525
Emission Limitations for Air Oxidation
Processes
Dl 140-0662
In addition to the dcfiniti

256
a) No person shall cause or allow the emission of VON from
any process vent stream unless the process vent stream
is
vented to a combustion device which is designed and
operated
either:
1) To reduce the volatile organic emissions vented to
it with an efficiency of at least ninety eight
percent (98) by weight; or
2) To emit VON at a concentration less than twenty
parts per million by volume, dry basis.
b) ~L~.A~ir oxidation facilitiesprocess vent stream for
which an existing combustion device is employed to
control process VON emissions a~ej~not required to
meet the 98 percent emissions limit until the
combustion device is replaced for other reasons, which
shall be considered to include, but not be limited to,
normal maintenance, malfunction, accident, and
obsolescence. The combustion device is considered to be
replaced when:
1) All of the device is replaced; or
2) When the cost of the repair of the device or the
cost of replacement of part of the device exceeds
50 of the cost of replacing the entire device
with a device which complies.
c) The limitations of subsection (a) above do not apply to
any process vent stream or combination of process vent
streams which has a Total Resource Effectiveness Index
(TRE) greater than 1.0, as determined by the following
methods:
1) If an air oxidation process has more than one
process vent stream, TRE shall be based upon a
combination of the process vent streams.
2) TRE of a process vent stream shall be determined
according to the following equation:
TRE
=
E1~a+bF~+cF+dFH+e(FH)~+
)
where:
n
=
0.88j.
TRE
=
Total resource effectiveness
index-~
DI
140-0663

257
F
=
Vent stream flowrate (scm/mm), at
a standard temperature of 20°C--j
E
=
Hourly measured emissions in
kg/hr--i
H
=
Net heating value of vent stream
(NJ/scm), where the net enthalpy
per mole of offgas is based on
combustion at 25°Cand 760 mm Hg,
but the standard temperature for
determining the volume
corresponding to one mole is 20°C,
as in the definition of “Flow”--~
a, b, c,
d,e
and f= Coefficients obtained by use of
Appendix Ffl.
3) For nonchlorinated process vent streams, if the
net heating value, H, is greater than 3.6 MJ/scm,
F shall be replaced by Fl ~ for purposes of
calculating TRE. ~-3~ is computed as follows:
=
FH
/
3.6
where F and H are as defined in subsection (C) (2)
of this Section.
4) The actual numerical values used in the equation
described in subsection (c) (2) above shall be
determined as follows:
A) All reference methods and procedures for
determining the flow, (F), hourly emissions,
(E), and net heating, (H), value shall be in
accordance with Appendix C.
B) All coefficients described in subsection
(c) (2) of this Section shall be in accordance
with Appendix D.
(Source: Amended at — Ill. Req.
______,
effective
___________
Section 218.527
Compliance Date (Repealed)
each owner or operator of an emission source subject to 35 Ill.
Adm. Code 215, Subpart V1 as of December 31, 1987 shall have
complied with the standards and limitations of 35 Ill. Adm. Code
215, Subpart V, by December ii, i~i.
(Source: Repealed at — Ill. Reg.
______,
effective
_________)
0 140-06614

258
SUBPART W: AGRICULTURE
Section 218.541
Pesticide Exception
The provisions of Sections 218.301 and 218.302 of this Part shall
not apply to the spraying or use of insecticides, herbicides or
other pesticides.
(Source: Amended at
Ill. Reg.
______,
effective
__________
SUBPART X: CONSTRUCTION
Section 218.562
Paving Operations
The provisions of Sections 218.301 and 218.302 of this Part shall
not apply to the application of paving asphalt and pavement
marking paint from sunrise to sunset.
(Source: Amended at — Ill. Reg.
______
, effective
__________)
SUBPART Y: GASOLINE DISTRIBUTION
Section 218.581
Bulk Gasoline Plants
a) Subject to ~subsection (e) of this Section, no person
may cause or allow the transfer of gasoline from a
delivery vessel into a stationary storage tank located
at a bulk gasoline plant unless:
1) The delivery vessel and the stationary storage
tank are each equipped with a vapor collection
system that meets the requirements of subsection
(d) (4) of this SectionTl
2) Each vapor collection system is operating~i.
3) The delivery vessel displays the appropriate
sticker pursuant to the requirements of Sections
218.584 (b) or (d) of this Part~j
4) The pressure relief valve(s) on the stationary
storage tank and the delivery vessel are, set to
release at no less than 0.7 psi or the highest
pressure allowed by state or local fire codes or
the guidelines of the National Fire Prevention
Association-i-; and
5) The stationary storage tank is equipped with a
submerged loading pipe.
b) Subject to subsection (f) of this Section, no person
may cause or allow the transfer of gasoline from a
01
Li.0-0665

259
stationary storage tank located at a bulk gasoline
plant into a delivery vessel unless:
1) The requirements set forth in subsections (a) (1)
through (a) (4) of this Section are metT~and
2) Equipment is available at the bulk gasoline plant
to provide for the submerged filling of the
delivery vessel or the delivery vessel is equipped
for bottom loading.
c) Subject to subsection (e) of this Section, each owner
of a stationary storage tank located at a bulk gasoline
plant shall:
1) Equip each stationary storage tank with a vapor
control system that meets the requirements of
subsection (a) or (b) of this Section, whichever
is applicable~~
2) Provide instructions to the operator of the bulk
gasoline plant describing necessary maintenance
operations and procedures for prompt notification
of the owner in case of any malfunction of a
vapor control system-i-; and
3) Repair, replace or modify any worn out or
malfunctioning component or element of design.
d) Subject to subsection (e) of this Section, each
operator of a bulk gasoline plant shall:
1) Maintain and operate each vapor control system in
accordance with the owner’s instructionsTl
2) Promptly notify the owner of any scheduled
maintenance or malfunction requiring replacement
or repair of a major component of a vapor control
systemTj and
3) Maintain gauges, meters or other specified testing
devices in proper working order—rj
4) Operate the bulk plant vapor collection system and
gasoline loading equipment in a manner that
prevents:
A) Gauge pressure from exceeding 45.7 cm (18
in.) of water and vacuum from exceeding 15.2
cm (6 in.) of water, as measured as close as
possible to the vapor hose connection~j and
01140-0666

260
B) A reading equal to or greater than 100
percent of the lower explosive limit (LEL
measured as propane) when tested in
accordance with the procedure described in
“Control of Volatile Organic Compound Leaks
from Gasoline Tank Trucks and Vapor
Collection Systems”, Appendix B,
EPA 450/2-78—051, (incorporated by reference
in Section 218.112) of this Part-Ti and
C) Avoidable leaks of liquid during loading or
unloading operations.
5) Provide a pressure tap or equivalent on the bulk
plant vapor collection system in order to allow
the determination of compliance with subsection
(d) (4) (A) of this SectionT~and
6) Within 15 business days after discovery of any
leak by the owner, the operator, the Agency or the
USEPA, repair and retest a vapor collection system
which exceeds the limits of subsection (d) (4) (A)
or (B) of this Section.
e) The requirements of subsections (a), (c) and (d) of
this Section shall not apply to:
1) Any stationary storage tank with a capacity of
less than 2,177 1 (575 gal)—~-j or
2) Any bulk gasoline plant whose daily gasoline
throughput is less than 15,140 1 (4,000 gal/day)
on a thirty-day rolling average.
f) The requirements of subsection (b) of this Section
shall apply only to bulk gasoline plants whose daily
gasoline throughput is greater than or equal to 15,140
1 (4,000 gal/day) on a thirty—day rolling average.
g) Any bulk gasoline plant which is ever subject to
subsections (a), (b), (c), or (d) shall always be
subject to these paragraphs.
(Source: Amended at — Ill. Reg.
______,
effective
__________
Section 218.582
Bulk Gasoline Terminals
a) No person shall cause or allow the transfer of gasoline
into any delivery vessel from any bulk gasoline
terminal unless:
1) The bulk gasoline terminal is equipped with a
ci
I
140-0667

261
vapor control system that limits emission of VON
to 80 mg/i (0.00067 lbs/gal) of gasoline loaded;
2) The vapor control system is operating and all
vapors displaced in the loading of gasoline to the
delivery vessel are vented only to the vapor
control system;
3) There is no liquid drainage from the loading
device when it is not in use;
4) All loading and vapor return lines are equipped
with fittings which are vapor tight; and
5) The delivery vessel displays the appropriate
sticker pursuant to the requirements of Section
218.584(b) or (d) of this Part or, if the
terminal is driver—loaded, the terminal owner or
operator shall be deemed to be in compliance with
this Section when terminal access authorization is
limited to those owners and/or operators of
delivery vessels who have provided a current
certification as required by Section 218.584(c) (3)
of this Part.
Bulk gasoline tc
certain actions
rminals were required
to achieve compliance
to take
which are
summarized in 35 Ill. Adm. Code 215, Appendix C.
eb) The operator of a bulk gasoline terminal shall:
1) Operate the terminal vapor collection system and
gasoline loading equipment in a manner that
prevents:
A) Gauge pressure from exceeding 18 inches of
water and vacuum from exceeding 6 inches of
water as measured as close as possible to the
vapor hose connection; and
B) A reading equal to or greater than 100
percent of the lower explosive limit (LEL
measured as propane) when tested in
accordance with the procedure described in
EPA 450/2-78-051 Appendix B~incorporated by
reference in Section 218.112 of this Part
and
C) Avoidable leaks of liquid during loading or
unloading operations.
2) Provide a pressure tap or equivalent on the
0!
140-0668

262
terminal vapor collection system in order to allow
the determination of compliance with Section
218.582(d) (1) (A) of this Part and
3) Within 15 business days after discovery of the
leak by the owner, operator, or the Agency repair
and retest a vapor collection system which exceeds
the limits of subsection (c) (1) (A) or (B) of this
Section.
(Source: Amended at
Ill. Req.
______,
effective
__________)
Section 218.583
Gasoline Dispensing FaciliticsOperations
a) Subject to subsection (b) of this Section, no person
shall cause or allow the transfer of gasoline from any
delivery vessel into any stationary storage tank at a
gasoline dispensing facilityoperation unless:
1) The tank is equipped with a submerged loading
pipe; and
2) The vapors displaced from the storage tank during
filling are processed by a vapor control system
that includes one or more of the following:
A) A vapor collection system that meets the
requirements of subsection (d) (4) of this
Section or
B) A refrigeration—condensation system or any
other system approved by the Agency and
approved by the USEPA as a SIP revision, that
recovers at least 90 percent by weight of all
vaporized organic material from the equipment
being controlled; and
C) The delivery vessel displays the appropriate
sticker pursuant to the requirements of
Section 218.584(b) or (d) of this Part.
b) The requirements of subsection (a) (2) above shall not
apply to transfers of gasoline to a stationary storage
tank at a gasoline dispensing facilityoperation if:
1) The tank is equipped with a floating roof, or
other system of equal or better emission control
approved by the Agency and approved by the USEPA
as a SIP revision;
2) The tank has a capacity of less than 2000 gallons
and was in place and operating before January 1,
01140-0669

263
1979; or
3) The tank has a capacity of less than 575 gallons.
c) Subject to subsection (b) above, each owner of a
gasoline dispensing facilityoperation shall:
1) Install all control systems and make all process
modifications required by subsection (a) of this
Section
2) Provide instructions to the operator of the
gasoline dispensing facilit-yoperation describing
necessary maintenance operations and procedures
for prompt notification of
the
owner in case of
any malfunction of a vapor control system; and
3) Repair, replace or modify any worn out or
malfunctioning component or element of design.
d) Subject to subsection (b) of this Section, each
operator of a gasoline dispensing f-acilityqperation
shall:
1) Maintain and operate each vapor control system in
accordance with the owner’s instructions;
2) Promptly notify the owner of any scheduled
maintenance or malfunction requiring replacement
or repair of a major component of a vapor control
system;
3) Maintain gauges, meters or other specified testing
devices in proper working order;
4) Operate the vapor collection system and delivery
vessel unloading points in a manner that prevents:
A) A reading equal to or greater than 100
percent of the lower explosive limit (LEL
measured as propane) when tested in
accordance with the procedure described in
EPA 450/2-78-051 Appendix B, and
B) Avoidable leaks of liquid during the filling
of storage tanks; and
5) Within 15 business days after discovery of the
leak by the owner, operator, or the Agency, repair
and retest a vapor collection system which exceeds
the limits of subsection (d) (4) (A) above.
C-’ ~.
01
14U-ub70

264
e-)- Gasoline dispensing facilities wcrc required to take
certain actions to achieve compliance which arc
summarized in 35 Ill. Adm. Code 215, ~‘noendixC.
(Source: Amended at — Ill. Reg.
______,
effective
_________
Section 218.584
Gasoline Delivery Vessels
a) Any delivery vessel equipped for vapor control by use
of vapor collection equipment:
1) Shall have a vapor space connection that is
equipped with fittings which are vapor tight;
2) Shall have its hatches closed at all times during
loading or unloading operations, unless a top
loading vapor recovery system is used;
3) Shall not internally exceed a gauge pressure of 18
inches of water or a vacuum of 6 inches of water;
4) Shall be designed and maintained to be vapor tight
at all times during normal operations;
5) Shall not be refilled in Illinois at other than:
A) A bulk gasoline terminal that complies with
the requirements of Section 218.582 of this
Part or
B) A bulk gasoline plant that complies with the
requirements of Section 218.581(b) of this
Part.
6) Shall be tested annually in accordance with Method
27, 40 CFR 60, Appendix A, incorporated by
reference in Section 218.105. Each vessel must be
repaired and retested within 15 business days
after discovery of the leak by the owner,
operator, or the Agency, when it fails to sustain:
A) A pressure drop of no more than three inches
of water in five minutes; and
B) A vacuum drop of no more than three inches of
water in five minutes.
b) Any delivery vessel meeting the requirements of
subsection (a) of this Section shall have a sticker
affixed to the tank adjacent to the tank manufacturer’s
data plate which contains the tester’s name, the tank
identification number and the date of the test. The
01140-067 I

265
sticker shall be
in a form prescribed by the Agency,
and, for those delivery vessels subject to 35 Ill. Adm.
Code 215 as of December 31, 1987 shall have been
displayed no later than December 31, 1987.
c) The owner or operator of a delivery vessel shall:
1) Maintain copies of any test required under
subsection (a) (6) of this Section for a period of
3 years;
2) Provide copies of these tests to the Agency upon
request; and
3) Provide annual test result certification to bulk
gasoline plants and terminals where the delivery
vessel is loaded.
d) Any delivery vessel which has undergone and passed a
test in another state which has a USEPA-approved leak
testing and certification program will satisfy the
requirements of subsection (a) of this Section.
Delivery vessels must display a sticker, decal or
stencil approved by the state where tested or comply
with the requirements of subsection (b) of this
Section. All such stickers, decals or stencils shall
have been displayed no later than December 31, 1987,
for delivery vessels subject to 35 Iii. Adm. Code 215
as of December 31, 1987.
(Source: Amended at
Ill. Req.
______,
effective
__________
Section 218.585
Gasoline Volatility Standards
a) No person shall sell, offer for sale, dispense, supply,
offer for supply, or transport for use in Illinois
gasoline whose Reid vapor pressure exceeds the
applicable limitations set forth in subsections (b) and
(c) of this Section during the regulatory control
periods, which shall be July ~y 1 to August 31
September 15 for retail outlets, wholesale
purchaser—consumer, facilities operations, and all
other facilities operations.
b) The Reid vapor pressure of gasoline, a measure of its
volatility, shall not exceed 9.&Q psi (65.5 62.07 kPa)
during the regulatory control period in 1990 and each
year thereafter.
C) The Reid vapor pressure of ethanol blend gasolines
shall not exceed the limitations for gasoline set forth
in subsection (b) of this Section by more than 1.0 psi
01140-0672

266
(6.9 kPa). Notwithstanding this limitation, blenders
of ethanol blend gasolines whose Reid vapor pressure is
less than 1.0 psi above the base stock gasoline
immediately after blending with ethanol are prohibited
from adding butane or any product that will increase
the Reid vapor pressure of the blended gasoline.
d) All sampling of gasoline required pursuant to the
provisions of this Section shall be conducted by one or
more of the following approved methods or procedures
which are incorporated by reference in Section 215.105.
1) For manual sampling, ASTM D4057;
2) For automatic sampling, ASTN D4l77;
3) Sampling procedures for Fuel Volatility, 40 CFR 80
Appendix D.
e) The Reid vapor pressure of gasoline shall be measured
in accordance with either test method ASTM D323 or a
modification of ASTM D323 known as the “dry method” as
set forth in 40 CFR 80, Appendix E, incorporated by
reference in 35 Ill. Adm. Code 24-~218.~G~-112of this
Part. For gasoline —
oxygenate blends which contain
water—extractable oxygenates, the Reid vapor pressure
shall be measured using the dry method test.
f) The ethanol content of ethanol blend gasolines shall be
determined by use of one of the approved testing
methodologies specified in 40 CFR 80, Appendix F,
incorporated by reference in 35 Ill. Adm. Code
~4~218.4-9~-112of this Part.
g) Any alternate to the sampling or testing methods or
procedures contained in subsections (d), (e), and (f)
of this Section must be approved by the Agency, which
shall consider data comparing the performance of the
proposed alternative to the performance of one or more
approved test methods or procedures. Such data shall
accompany any request for Agency approval of any
alternate test procedure. If the Agency determines
that such data demonstrates that the proposed
alternative will achieve results equivalent to the
approved test methods or procedures, the Agency shall
approve the proposed alternative.
h) Each refiner or supplier that distributes gasoline or
ethanol blends shall:
1) During the regulatory control period, state that
the Reid vapor pressure of all gasoline or ethanol
01140-0673

267
blends leaving the refinery or distribution
facility operation for use in Illinois complies
with the Reid vapor pressure limitations set forth
in 35 Ill. Adm. Code ~j~.585(b) and (c). Any
facilityoperation receiving this gasoline shall be
provided with a copy of an invoice, bill of
lading, or other documentation used in normal
business practice stating that the Reid vapor
pressure of the gasoline complies with the State
Reid vapor pressure standard.
2) Maintain records for a period of one year on the
Reid vapor pressure, quantity shipped and date of
delivery of any gasoline or ethanol blends leaving
the refinery or distribution facility operation
for use in Illinois. The Agency shall be provided
with copies of such records if requested.
(Source: Amended at — Ill. Req.
______,
effective
___________
Section 218.586
Gasoline Dispensing Facilities Operations —
Motor Vehicle Fueling Operations
a) For the purposes of this e~ection, the following
definitions apply.
1) Average M~onthly~yolume÷ means tThe amount of
motor vehicle fuel dispensed per month from a
gasoline dispensing facility operation based upon
a monthly average for the 2—year period of
November, 1990 through October, 1992 or, if not
available, the monthly average for the most recent
twelve calendar months. Monthly averages are to
include only those months when the facility
operation was operating.
Certified÷means aAny vapor collection and control
system which has been tested and approved by CARB
as having a vapor recovery and removal efficiency
of at least 95 (by weight) shall constitute a
certified vapor collection and control system.
CARB testing and approval is pursuant to the CARE
manual, hereby incorporated by reference ~
218.112 of this Part (California Air Resourcc~
Board, Compliance Division, Compliance Assistance
Program: Facilities Phase I & II (October 1988,
rev. March 1991 CARE Manual)). This incorporation
4—--.-’..-.~—----.
later addit~ons or amcnctme-nt~.
3) Completion of installation÷mean~tThe successful
passing of one or more of the following tests
applicable to the installed vapor collection and
01140-06714
2)

268
control system:
Dynamic Backpressure Test,
Pressure Decay/Leak Test, and Liquid Blockage
Test~ (United States Environmental Protection
Agency, Washington D.C.,
r~i&—u—i-ii—uu~j.
These tests are hereby incorporated by reference
at 218.112 of this Part. This incorporation
includes no later additions or amendments.
4) Constructed+ means fFabricated, erected or
installed; refers to any facility, emission source
or air pollution control equipment.
5) CARB÷means California Air Resources Board, P.O.
Box 2815, Sacramento, CA 95812.
6) Employee÷means aAny person who performs work for
an employer.
7) FacilityOperation÷means aAny building, structure,
installation, operation or combination thereof
located on contiguous properties and under common
ownership that provides for the dispensing of
motor vehicle fuel.
8) Gasoline ~ispensing Facility operation: means
~Any facilityoperatkQn where motor vehicle fuel is
dispensed into motor vehicle fuel tanks or
portable containers from a storage tank with a
capacity of 2176 liters (575 gallons) or more.
9) Modification+ means aAny change, removal or
addition, other than an identical replacement, of
any component contained within the vapor
collection and control system.
10) Motor Vyehiclei- means aAny self-propelled vehicle
powered by an internal combustion engine
including, but not limited to, automobiles and
trucks. Specifically excluded from this
definition are watercraft and aircraft.
11) Motor ~Mehicle ~uel~ means aAny petroleum
distillate having a Reid vapor pressure of more
than 27.6 kilopascals (kPa) (four pounds per
square inch) and which is used to power motor
vehicles.
12) Owner or ~Qperator÷ means aAny person who owns,
leases, operates, manages, supervises or controls
(directly or indirectly) a gasoline dispensing
facilityoperation.
n Ltfl-0675

269
13) Reid ~yapor Ppressure÷~or gasoline, 4~ shall be
measured in accordance with either the method ASTM
D323 or a modification of ASTM D323 known as the
“dry method” as set forth in 40 CFR 80, Appendix
E, incorporated by references in 35 Ill. Adm. Code
215.105218.112 of this Part.
14) Vapor ~ollection and ~ontro1 S~ystem÷means aAny
system certified by CARB which limits the
discharge to the atmosphere of motor vehicle fuel
vapors displaced during the dispensing of motor
vehicle fuel into motor vehicle fuel tanks.
b) The provisions of subsection (c) of this Section below
shall apply to any gasoline dispensing facility
operation which dispenses an average monthly volume of
more than 10,000 gallons of motor vehicle fuel per
month. Compliance shall be demonstrated in accordance
with the schedule provided in subsection (d) of this
Section below.
c) No owner or operator of a gasoline dispensing facility
operation subject to the requirements of subsection (b)
of this Section above shall cause or allow the
dispensing of motor vehicle fuel at any time from a
motor fuel dispenser unless the dispenser is equipped
with and utilizes a vapor collection and control system
which is properly installed and operated as provided
below:
1) Any vapor collection and control system installed,
used or maintained has been CARB certified.
2) Any vapor collection and control system utilized
is maintained in accordance with the
manufacturer’s specifications and the
certification.
3) No elements or components of a vapor collection
and control system are modified, removed, replaced
or otherwise rendered inoperative in a manner
which prevents the system from performing in
accordance with its certification and design
specifications.
4) A vapor collection and control system has no
defective, malfunctioning or missing components.
5) Operators and employees of the gasoline dispensing
facility operation are trained and instructed in
the proper operation and maintenance of a vapor
collection and control system.
01140-0676

270
6) Instructions are posted in a conspicuous and
visible place within the motor fuel dispensing
area and describe the proper method of dispensing
motor vehicle fuel with the use of the vapor
collection and control system.
d) In conjunction with the compliance provisions of
Section 218.105 of this Part, facilitiesoperations
subject to the requirements of subsection (c) above
shall demonstrate compliance according to the
following:
1) FacilitiesOperations that commenced construction
after November 1, 1990, must comply by Nay 1,
1993.
2) Faciliticspperations that commenced construction
before November 1, 1990, and dispense an average
monthly volume of more than 100,000 gallons of
motor fuel per month must comply by November 1,
1993.
3) FacilitiesOperations that commenced construction
before November 1, 1990, and dispense an average
monthly volume of less than 100,000 gallons of
motor fuel per month must comply by November 1,
1994.
4) New facilitiesoperations constructed after the
adoption of this Section shall comply with the
requirements of subsection (c) above upon startup
of the facilityoperation.
5) Existing facilitiesoperations previously exempted
from but which become subject to the requirements
of subsection (C) above after May 1, 1993 shall
comply with the requirements of subsection (c)
above within six calendar months of the date from
which the facilityoperation becomes subject.
e) Any gasoline dispensing facility operation that becomes
subject to the provisions of subsection (c) above at
any time shall remain subject to the provisions of
subsection (c) above at all times.
f) Upon request by the Agency, the owner or operator of a
gasoline dispensing facilityoperation which claims to
be exempt from the requirements of this Section shall
submit records to the Agency within 30 calendar days
from the date of the request which demonstrate that the
gasoline dispensing facilityoperation is in fact
exempt.
01140-0677

271
g) Recordkeeping and reporting:
1)
Any gasoline dispensing f-a-cilityoperation subject
to subsection (c) above shall retain at the
facility operation copies of the registration
information required at subsection (h) below.
2) Records and reports required pursuant to this
subsection shall be made available to the Agency
upon request. Records and reports which shall be
maintained by the owner or operator of the
gasoline dispensing facilityoperation shall
clearly demonstrate:
A) That a certified vapor collection and control
system has been installed and tested to
verify its performance according to its
specifications.
B) That proper maintenance has been conducted in
accordance with the manufacturer’s
specifications and requirements.
C) The time period and duration of all
malfunctions of the vapor collection and
control system.
D) The motor vehicle fuel throughput of the
facilitypperation for each calendar month of
the previous year.
E) That operators and employees are trained and
instructed in the proper operation and
maintenance of the vapor collection and
control system and informed as to the
potential penalties associated with the
violation of any provision of this Section.
h) Any gasoline dispensing facilityqperation subject to
subsection (c) above shall be exempt from the permit
requirements specified under 35 Ill. Adm. Code 201.142,
201.143 and 201.144 for its vapor collection and
control systems, provided that:
1) Upon the installation of a vapor collection and
control system, the owner or operator of the
gasoline dispensing facilityoperation submits to
the Agency a registration which provides at
minimum the facility operation name and address,
signature of the owner or operator, the CARE
Executive Order Number for the vapor collection
and control system to be utilized, the number of
01140-0678

272
nozzles (excluding diesel or kerosene) used for
motor vehicle refueling, the monthly average
volume of motor vehicle fuel dispensed, the
location (including contact person’s name,
address, and telephone number) of records and
reports required by this Section, and the date of
completion of installation of the vapor collection
and control system.
2) The registration is submitted to the Agency within
30 days of completion of such installation.
3) A copy of the registration information is
maintained at the gasoline dispensing facility
operation.
4) Upon the modification of an existing vapor
collection and control system, the owner or
operator of the gasoline dispensing facility
operation submits to the Agency a registration
that details the changes to the information
provided in the previous registration of the vapor
collection and control system and which includes
the signature of the owner or operator. The
registration must be submitted to the Agency
within 30 days of completion of such modification.
(Source: Amended at
______
Ill. Req.
________,
effective
)
SUBPART Z: DRY CLEANERS
Section 218.601
Perchloroethylene Dry Cleaners
The owner or operator of a dry cleaning facilityoperation which
uses perchioroethylene shall:
a) Vent the entire dryer exhaust through a properly
designed and functioning carbon adsorption system or
equally effective control device; and
b) Emit no more than 100 ppmv of VOM from the dryer
control device before dilution, or achieve a 90 percent
average reduction before dilution; and
c) Immediately repair all components found to be leaking
liquid VOM; and
d)
Cook or treat all diatomaceous earth filters so that
the residue contains 25 kg (55 lb) or less of VOM per
100 kg (220 lb) of wet waste material; and
e)
Reduce the VON from all solvent stills to 60 kg (132
01140-0679

273
lb) or less per 100 kg (220 lb) of wet waste material;
and
f) Drain all filtration cartridges in the filter housing
or other sealed container for at least
24 hours before
discarding the cartridges; and
g) Dry all
drained filtration cartridges in equipment
connected to
an emission reduction system or in a
manner
that will eliminate emission of VON to the
atmosphere.
(Source: Amended at — Ill. Reg.
______,
effective
__________)
Section 218.602
Exemptions
The provisions of Section
218.601 of this Part are not applicable
to perchloroethylene dry cleaning operations which are
coin—operated or to
dry cleaning facilitiesoperation
consuming
less than 30 gal per month (360 gal per
year) of
perchioroethylene.
(Source: Amended at — Ill. Reg.
, effective
__________)
Section 218.603
Leaks
The presence of leaks shall be determined for purposes of Section
218.601(c)
of this Part by a
visual inspection of the following:
hose connections, unions, couplings and valves; machine door
gaskets and seatings; filter head gasket and seating; pumps; base
tanks and storage containers; water separators; filter sludge
recovery; distillation unit; diverter valves; saturated lint from
lint baskets; and cartridge filters.
(Source: Amended at
Ill. Reg.
, effective
_________
Section 218.604
Compliance Dates (Repealed)
Every owner or operator of an emission source previously subject
to 35 Ill. Adm. Code 215, Subpart Z, shall have complied with its
standards and limitations in accordance with the applicable dates
set forth in 35 Iii. AdTn. Code 215.604.
(Source: Repealed at
Ill. Req.
______,
effective
_________)
Section 218.605
Compliance Plan (Repealed)
The owner or operator of an emission source subject
this Subpart shall have submitted to the Agency a
to
compliance plan, pursuant to 35 Ill. Adm. Code 201,
Subpart H, including a project completion schedule
where applicable, no later than, for Section 218.601(a)
01140-0680

274
a-nd (b), April 21, 1983.
b-)- Unless the submitted compliance plan or schedule was
disapproved by the Agency, the owner or operator of a
facility or emission source may operate the emission
s-o-urcc according to the plan and schedule
e-~-
The plan and schedule shall meet the requirements of 35
111. Adm. Code 201, Subpart H, including specific
interim dates as ~~uii-~d in 35 Ill. Adm. Code 201.242.
(Source: Repealed at
Ill. Req.
______,
effective
_________)
Section 218.606
Exception to Compliance Plan (Repealed)
Coin-operated dry cleaning operations and dry cleaning facilities
consuminrc less than 30 rcal r~r’r
mnnt~h (~fl
r~alper year) of
jenc arc
t or obtain an
J~ccrnr~v
approved compliance plan or project completion schedule.
(Source: Repealed at
Ill. Reg.
______,
effective
__________)
Section 218.608
Operating Practices for Petroleum Solvent Dry
Cleaners
In order to minimize fugitive solvent emissions, the owner or
operator of a petroleum solvent dry cleaning -facilitysource shall
employ good housekeeping practices including the following:
a) General Housekeeping Requirements
1) Equipment containing solvent (washers, dryers,
extractors and filters) shall remain closed at all
times except during load transfer and maintenance.
Lint filter and button trap covers shall remain
closed except when solvent—laden material is being
removed.
2) Cans, buckets, barrels and other containers of
solvent or of solvent—laden material shall be
covered except when in use.
3) Solvent-laden material shall be exposed to the
atmosphere only for the minimum time necessary for
load transfer.
b) Installation and operation of equipment:
1) All cartridge filters shall be enclosed and
operated in accordance with the procedures and
specifications recommended by the manufacturer for
the cartridge filter. After installation, the
01140-0681

275
cartridges shall be inspected, monitored and
maintained in accordance with the manufacturer’s
recommendations; and
2) Vents on containers for new solvent and for
solvent—containing waste shall be constructed and
maintained so as to minimize solvent vapor
emissions. Criteria for the minimization of
solvent vapor emissions include the elimination of
solvent buckets and barrels standing open to the
atmosphere, and the repair of gaskets and seals
that expose solvent—rich environments to the
atmosphere, to be determined through visual
inspection.
(Source: Amended at
Ill. Req.
~, effective
___________)
Section 218.609
Program for Inspection and Repair of Leaks
a) The owner or operator of a petroleum solvent dry
cleaning facilitysource shall conduct the following
visual inspections on a weekly basis:
1) Washers, dryers, solvent filters, settling tanks,
vacuum stills and containers and conveyors of
petroleum solvent shall be inspected for visible
leaks of solvent liquid.
2) Pipes, hoses-and fittings shall be inspected for
active dripping or dampness.
3) Pumps and filters shall be inspected for leaks
around seals and access covers.
4) Gaskets and seals shall be inspected for wear and
defects.
b) Leaks of petroleum solvent liquid and vapors shall be
repaired within three working days of detection, unless
necessary replacement parts are not on site.
1) If necessary, repair parts shall be ordered within
three working days of detection of the leak.
2) The leak shall be repaired within three days of
delivery of necessary parts.
(Source: Amended at
Ill. Req.
______,
effective
___________)
Section 218.610
Testing and Monitoring
a) Compliance with Sections 218.607(b) (2), 218.608 and
01140-0682

276
218.609 of this Part shall be determined by visual
inspection; and
b) Compliance with Sections 218.607(a) (2) and (b) (1)
p1
this Part shall be determined by methods described in
EPA-450/3-82—009 (1982) incorporated by reference in
Section 218.112 of this Part.
c) If a control device is used to comply with Section
218.607(a) (1) of this Part, then compliance shall be
determined using 40 CFR 60 Appendix A, Method 25 (1984)
incorporated by reference in Section 218.112 of this
Part.
(Source: Amended at
Ill. Req.
_____,
effective
Section 218.611
Exemption for Petroleum Solvent Dry Cleaners
The provisions of Sections 218.607 through 218.610 of this Part
shall not apply to petroleum solvent dry cleaning facilities
sources whose emissions of VOM do not exceed 91 megagrams (100
tons) per year in the absence of pollution control equipment or
whose emissions of VON, as limited by the operating permit, will
not exceed 91 megagrams (100 tons) per year in the absence of
pollution control equipment.
-
(Source: Amended at
Ill. Reg.
effective
)
Section 218.612
Compliance Dates j~epealed)
oowncr~ anu upcrucor~
o~ cnu~ion sourocs
~UDJCCL CO i-~ iii. i~UI1I.
Code 215.6-07 through 215.609 as of December 31, 1987 shall have
1 i
ed with the
~......
—set
~
as
‘.~# j_
?~t7~_..s
_:~I:i~_...
£
December 3-1, 1987.
(Source: Repealed at
Ill. Req.
______,
effective
_________)
Section 218.613
Compliance Plan ~Repealed)
a-)-- The owner or operator of an
-r
1
I
‘a
fl_..
,~.—
-.
I
,-k(Im.
~_I~)(1(~
I
“~— (—~
~
~
~‘
have submitted to the Agency a
comp
including a project completion schedule
where
applicable, no- later than May 31, 1987.
rPhc~
plnn
nrirl
hr’rlulr’
‘~h~11m~r’f
thr’
~requircmcnts r~f ~
j
I -
I ‘J-’
I
~-~r1~1I
,
(Source: Repealed at
Ill. Req.
______,
effective
_________)
SUBPART AA: PAINT AND INK MANUFACTURING
01140-0683
source subject to
-
1a~-
2
—‘— —
liance p’~’
Ill. Adm. Code 201.

277
Section 218.620
Applicability
a) This ,~subpartshall apply to all paint and ink
manufacturing plantosources which:
1) Include process emission ~ourccsunitsnot subject
to Subparts B, E, F (excluding Section 218.204(1)
of this Part), H jexcluding Section 218.405 p1
this Part),
Q,
R, S, T (excluding Section 218.486
of this Part), V, X, Y, Z or BE of this Part; and
which as a group both:
A) Hhave maximum theoretical emissions of 91 Mg
(100 tons) or more per calendar year of VON
if no air pollution control equipment were
used, and
B) Asre not limited to less than 91 Mg (100
tons) of VON emissions per calendar year in
the absence of air pollution control
equipment, through production or capacity
limitations contained in a federally
enforceable construction permit or a SIP
revision, or
2) Produce more than 7,570,820 1 (2,000,000 gal) per
calendar year of paint or ink formulations, which
contain less than 10 percent (by weight) water,
and ink formulations not containing as the primary
solvents water, Magie oil or glycol.
b) For the purposes of this Subpart, uncontrolled VON
emissions are
the emissions of VON which would result
if no air pollution control equipment were used.
(Source: Amended at — Ill. Reg.
______,
effective
__________
Section 218.621
Exemption for Waterbase Material and
Heatset-Offset Ink
The requirements of Sections 218.624~ and 218.625 and Section
218.628(a) of this Part shall not apply to equipment while it is
being used to produce either:
a) p~aintor ink formulations which contain 10 percent or
more
(by weight) water, or
b) 4~,nkscontaining Magie oil and glycol as the primary
solvent.
(Source:
Amended at — Ill. Reg.
______,
effective
__________)
01140-06614

278
Section 218.623
Permit Conditions
No person shall violate any condition in a permit when the
condition results in exclusion of the p-lantsource or an emission
sourceunit from this Subpart.
(Source: Amended at
Ill. Req.
______,
effective
___________)
Section 218.624
Open-~Top Mills, Tanks, Vats or Vessels
No person shall operate an open—top mill, tank, vat or vessel
with a volume of more than 45 1 (12 gal) for the production of
paint or ink unless:
a) The mill, tank, vat or vessel is equipped with a cover
which completely covers the mill, tank, vat or vessel
opening except for an opening no larger than necessary
to allow for safe clearance for a mixer shaft. Such
cover shall extend at least 1.27 cm (0.5 in) beyond the
outer rim of the opening or be attached to the rim.
b) The cover remains closed except when production,
sampling, maintenance or inspection procedures require
access.
c) The cover is maintained in good condition such that,
when in place, it maintains contact with the rim of the
opening for at least 90 percent of the circumference of
the rim.
(Source: Amended at
Ill. Reg.
, effective
___________
Section 218.628
Leaks
The owner or operator of a paint or ink manufacturing plantsource
shall, for the purpose of detecting leaks, conduct an equipment
monitoring program as set forth below:
a) Each pump shall be checked by visual inspection each
calendar week for indications of leaks, that is,
liquids dripping from the pump seal. If there are
indications of liquids dripping from the pump seal, the
pump shall be repaired as soon as practicable, but no
later than 15 calendar days after the leak is detected.
b) Any pump, valve, pressure relief valve, sampling
connection, open—ended valve and flange or connector
containing a fluid which is at least 10 percent VOM by
weight which appears to be leaking on the basis of
sight, smell or sound shall be repaired as soon as
practicable, but no later than 15 calendar days after
the leak is detected.
0 1140-0685

279
c) A weather proof, readily visible tag, in bright colors
such as red or yellow, bearing an identification number
and the date on which the leak was detected shall be
attached to leaking equipment. The tag may be removed
upon repair, that is, when the equipment is adjusted or
otherwise altered to allow operation without leaking.
d) When a leak is detected, the owner or operator shall
record the date of detection and repair and the record
shall be retained at the plantsource for at least two
years from the date of each detection or each repair
attempt. The record shall be made available to any
person upon verbal or written request during business
hours.
(Source: Amended at
Ill. Reg.
______,
effective
__________
Section 218.636
Compliance Schedule
Every owner or operator of a an emission source subject to the
control requirements of this Subpart shall comply with the
requirements thereof on and after a date consistent with Section
218.106 of this Part.
(Source: Amended at
Ill. Reg.
______,
effective
___________)
Section 218.637
Recordkeeping and Reporting
a) Upon request by the Agency, the owner or operator of an
emission source which claims to be exempt from the
requirements of this Subpart shall submit records to
the Agency within 30 calendar days from the date of the
request which document that the emission source is in
fact exempt from this Subpart. These records shall
include (but are not limited to) the percent water (by
weight) in the paint or ink being produced and the
quantity of Magie oil, glycol and other solvents in the
ink being produced.
b) Every owner or operator of a~emission source which is
subject to the requirements of this Subpart shall
maintain all records necessary to demonstrate
compliance with those requirements at the facility
-
source for three years.
(Source: Amended at — Ill. Reg.
______,
effective
___________)
SUBPART BB: POLYSTYRENE PLANTS
Section 218.875218.640 Applicability of Subpart BE
The provisions of this Subpart shall apply to polystyrene plants:
01140-0686

280
a) Which use continuous processes to manufacture
polystyrene - polybutadiene co-polymer; and
b) Which fall within Standard Industrial Classification
Group No. 282, Industry No. 2821, except that the
manufacture of polystyrene resins need not be the
primary manufacturing process at the plant.
(Source: Renumbered from Section 218.875 and amended at
____
Ill. Reg.
_____,
effective
___________)
Section 218.877218.642 Emissions Limitation at Polystyrene
Plants
No person shall cause or allow the emissions of VOM from the
material recovery section to exceed 0.12 kg of Volatile Organic
Material per 1000 kg of polystyrene resin produced.
(Source: Renumbered from Section 218.877 at
Ill. Req.
effective
_______________)
Section 218.886218.644 Emissions Testing
a) Upon a reasonable request by the Agency, the owner or
operator of a polystyrene plant subject to this Subpart
shall at his own expense demonstrate compliance by use
of the following method: 40 CFR 60, Appendix A, Method
25
Determination of Total Gaseous Non-Methane Organic
Emissions as Carbon (1984), incorporated by reference
in Section 218.112 of this Part.
b) A person planning to conduct a VON emissions test to
demonstrate compliance with this Subpart shall notify
the Agency of that intent not less than 30 days before
the planned initiation of the tests so the Agency may
observe the test.
(Source: Renumbered from Section 218.886 and amended at
Ill. Req.
_____,
effective
__________)
Section 218.875
Applicability of Subpart BE (Renumbered)
(Source: Renumbered to Section 218.640 at
Ill. Req.
effective
______________)
Section 218.877
Emissions Limitation at Polystyrene Plants
(Renumbered)
-
(Source: Renumbered to Section 218.642 at
Ill. Req.
effective
______________)
Section 218.879
Compliance Date (Repealed)
01140-0687

281
Every owner
and operator of an emission source
subject to 35 Ill.
Adm. Code 215, Subpart BE, as of December 31, 1987, shall have
complied with its standards
and limitations by December 31, 1987.
(Source: Repealed at
Ill. Req.
______,
effective
)
Section 218.881
Compliance Plan (Repealed)
subject to the requirements of 35 Ill. Adm. Code 215
Subpart EB shall have submitted to the Agency a
cp~ç~
1
1-—
—-
-
~1
r—
1
‘a~i
201, Subpar~
~i J~IFl(~~~
rii.lrI
in uoc~oru~nce
w,.LI..U
.~ iii. ~ium. ~uue
1~
~
including a project completion hr’i’~ln1r’~
~ ~
December 1, 1987.
Unless the submitted compliance plan or schedule was
disapproved by the Agency, the owner or operator of a
facility or emission source subject to this Subpart may
operate the emission source according to the plan and
schedule as submitted.
mh~
plan m-w-1 ~-u-hr’tiii1
-
— 1
1
‘~
I’.
.-~4 4—1-.
..~
~-...-—.
Ill. Adm. Code 201, Subpart H and Section 218.883.
-r r’m
c’T1
(Source: Repealed at
Ill. Req.
, effective
)
Section 218.883
Special Requirements for Compliance Plan
(Repealed)
ources subject to this Subpart,
blc compliance
a-)-
A-4-
-
emissions limitation
which is subject t
~)-
Quantificatj
4—1-.
—‘ ~-.... 4
.-. .—.
e-)- A-description of the procedures and methods used to
determine the emissions of VON
4-)- A description of the meti
.~,411 I~
~
ciemonstrate compliance with the allowable plantwide
emission limitation (Section 215.877), including a
mc~thôt1 r~f I ‘nvr~r~f—i.i
‘rr’r’~r~rt~11r’n’i‘nrc ~nrI
mni ~ i nn
.‘r,,
1 -s4-
4
—.—...~—_z
~
(Source: Repealed at
Section 218.886
Ill. Reg.
______,
effective
________
Emissions Testing (Renumbered)
(Source: Renumbered to Section 218.644 at
effective
__________________)
Ill. Req.
_____
01140-0688
a-)-
—A
‘~1
r~f
-~

282
SUBPART PP: MISCELLANEOUS FABRICATED PRODUCT MANUFACTURING
PROCESSES
Section 218.920
Applicability
a) The requirements of this Subpart shall apply to a
plant’ssource’s miscellaneous fabricated product
manufacturing process emission ~-ourccsunitswhich are
not included within any of the ~seurce categories
specified in Subparts B, E, F, H,
Q,
R, 5, ~ V, X, Y~
e~Z
or BB if the plantsource is subject to this
Subpart. A plantsource is subject to this Subpart if
it contains process emission sourccsunits, not
regulated by Subparts B, E, F (excluding Section
218.204(1) of this Part), H (excluding Section 218.405
of this Part), Q, R, S, T (excluding Section 218.486 of
this Part), V, X, Y~e~Z or BE of this Part; which as
a group both:
1) llhave maximum theoretical emissions of 91 Mg (100
tons) or more per calendar year of VON if no air
pollution control equipment were used, and
2) hare not limited to less than 91 Mg (100 tons) of
VON emissions per calendar year in the absence of
air pollution control equipment, through
production or capacity limitations contained in a
federally enforceable construction permit or a SIP
revision.
b) If a plantsource ceases to fulfill the criteria of
subsection (a)above, the requirements of this Subpart
shall continue to apply to a miscellaneous fabricated
products manufacturing process emission sourccunit
which was ever subject to the control requirements of
Section 218.926 of this Part.
c) No limits under this Subpart shall apply to emission
-s-ourccsunits with emissions of VON to the atmosphere
less than or equal to 0.91 Mg (1.0 ton) per calendar
year if the total emissions from such sources emission
units not complying with Section 218.926 does not
exceed 4.5 Mg (5.0 tons) per calendar year of this
Part.
d) For the purposes of this Subpart, an emission
-so-urceunit shall be considered regulated by a Subpart
if it is subject to the limits of that Subpart. An
emission sourceunit is not considered regulated by a
Subpart if it is not subject to the limits of that
Subpart, e.g.
,
the emission unit is covered by an
exemption in the Subpart or the applicability criteria
01140-0689

283
of the Subpart are not met. its cmi~sionsaro- below
the applicability cutoff level or if the source is
covered by an excm~4~
e) For the purposes of this Subpart, uncontrolled VON
emissions are the emissions of VOM which would result
if no air pollution control equipment were used.
(Source: Amended at — Ill. Req.
______,
effective
__________
Section 218.923
Permit Conditions
No person shall violate any condition in a permit when the
condition results in exclusion of the plantsource or an emission
-s-ourceunit from this Subpart~
(Source: Amended at — Ill. Req.
______,
effective
___________
Section 218.926
Control Requirements
Every owner or operator of an emission sourcemiscellaneous
fabricated product manufacturing process emission unit subject to
this Subpart shall comply with the requirements of subsection
(a) , (b) or (c) of this Section:
a) Emission capture and control techniques which achieve
an overall reduction in uncontrolled VON emissions of
at least 81 percent from each emission unit, or
(Board Note: For the purpose of this provision, an
emission unit is any cart or activity at a source of a
type that by itself is sublect to control requirements
in other Subparts of this Part or 40 CFR 60,
incorporated by reference in Section 218.112, e.g., a
coating line, a printing line, a process unit, a
wastewater system, or other eciuipment, or is otherwise
any Part or activity at a source.)
b) For coating lines, the daily-weighted average VON
content shall not exceed 0.42 kg VOM/1 (3.5 lbs
VON/gal) of coating as applied (minus water and any
compounds which are specifically exempted from the
definition of VON) during any day. Owners and
operators complying with this Section are not required
to comply with Section 218.301 of this Part, or
c) An alternative control plan which has been approved by
the Agency and approved by the USEPA as a SIP revision.
(Source: Amended at — Ill. Reg.
______,
effective
Section 218.927
Compliance Schedule
01140-0690

284
Every owner or operator of an emission e-our-e-cunit subject to the
control requirements of this Subpart shall comply with the
requirements thereof on and after a date consistent with Section
218.106 of this Part.
-
‘(Source: Amended at — Ill. Req.
______,
effective
__________
Section 218.928
Testing
a) When in the opinion of the Agency it is necessary to
conduct testing to demonstrate compliance with Section
281.926, the owner or operator of a VON emission
-s-ourccunit subject to the requirements of this Subpart
shall, at his own expense, conduct such tests in
accordance with the applicable test methods and
procedures specified in Section 218.105.
b) Nothing in this Section shall limit the authority of
the USEPA pursuant to the Clean Air Act, as amended, to
require testing.
(Source: Amended at — Ill. Req.
______,
effective
___________
SUBPART QQ: MISCELLANEOUS FORNULATION MANUFACTURING PROCESSES
Section 218.940
Applicability
a) The requirements of this Subpart shall apply to a
p-i-ant’ ssource’s miscellaneous formulation manufacturing
process emission courcesunits,, which are not included
within any of the source categories specified in
Subparts B, E, F, H, Q, R, S, ~ V, X, Y~e~Z or BE of
this Part if the plantsource is subject to this
Subpart. A plantsource is subject to this Subpart if
it contains process emission sourcesunits, not
regulated by Subparts B, E, F (excluding Section
218.204(1) of this Part), H (excluding Section 218.405
of this Part), Q, R, S, T (excluding Section 218.486 of
this Part)~V, X,
Y,
e~ Z or BE of this Part; which as
a group both:
1) U1~avemaximum theoretical emissions of 91 Mg (100
tons) or more per calendar year of VOM if no air
pollution control equipment were used, and
2) hare not limited to less than 91 Mg (100 tons) of
VON emissions per calendar year in the absence of
air pollution control equipment, through
production or capacity limitations contained in a
federally enforceable construction permit or a SIP
revision.
01140-0691

285
b) If a plantsource ceases to fulfill the criteria of
subsection (a) of this Section, the requirements of
this Subpart shall continue to apply to a miscellaneous
formulation manufacturing process emission sourceunit
which was ever subject to the control requirements of
Section 218.946 of this Part.
c) No limits under this Subpart shall apply to emission
sourcesunits with emissions of VON to the atmosphere
less than or equal to 2.3 Mg (2.5 tons) per calendar
year if the total emissions from such emission units
sources not complying with this Section does not exceed
4.5 Mg (5.0 tons) per calendar year.
d)
-
For the purposes of this Subpart, an emission
sourccunit shall be considered regulated by a Subpart
if it is subject to the limits of that Subpart. An
emission sourccunit is not considered regulated by a
Subpart if it is not subject to the limits of that
Subpart, e.g., the emission unit is covered by an
exemption in the Subpart or the applicability criteria
of the Subpart are not met. its emissions arc below the
applicability cutoff level or if the source is covered
by an exemption.
e) For the purposes of this Subpart, uncontrolled VOM
emissions are the emissions of VOM which would result
if no air pollution control equipment were used.
(Source: Amended at
Ill. Req.
______,
effective
__________)
Section 218.943
Permit Conditions
No person shall violate any condition in a permit when the
condition results in exclusion of the plantsource or an emission
sourceunit from this Subpart.
(Source: Amended at — Ill. Req.
______,
effective
__________
Section 218.946
Control Requirements
Every owner or operator of ai~miscellaneous formulation
manufacturing process emission sourceunit subject to this Subpart
shall comply with the requirements of subsection (a) or (b)
below.
a) Emission capture and control techniques which achieve
an overall reduction in uncontrolled VON emissions of
at least 81 percent from each emission unit, or
(Board Note: For the purpose of this provision, an
emission unit is any part or activity at a source of a
01140-0692

286
tyPe that by itself is subject to control requirements
in other Subparts of this Part or 40 CFR 60,
incorporated by reference in Section 218.112, e.g., a
coating line, a printing line, a process unit, a
wastewater system, or other equipment. or is otherwise
anY part or activity at a source.)
b) An alternative control plan which has been approved by
the Agency and approved by the USEPA as a SIP revision.
(Source: Amended at — Ill. Req.
______,
effective
__________)
Section 218.947
Compliance Schedule
Every owner or operator of an emission sourceunit subject to the
control requirements of this Subpart shall comply with the
requirements thereof on and after a date consistent with Section
218.106 of this Part.
(Source: Amended at
Ill. Req.
_____,
effective
__________
Section 218.948
Testing
a) When in the opinion of the Agency it is necessary to
conduct testing to demonstrate compliance with Section
218.946 of this Part, the owner or operator of a VON
emission sourceunit subject to the requirements of this
Subpart shall, at his own expense, conduct such tests
in accordance with the applicable test methods and
procedures specified in Section 218.105 of this Part.
b) Nothing in this Section shall limit the authority of
the USEPA pursuant to the Clean Air Act, as amended, to
require testing.
(Source: Amended at — Ill. Reg.
______,
effective
___________
SUBPART RR: MISCELLANEOUS ORGANIC CHEMICAL MANUFACTURING
PROCESSES
Section 218.960
Applicability
a) The requirements of this Subpart shall apply to a
p-iant’ssource’s miscellaneous organic chemical
manufacturing process emission source~units which are
not included within any of the s-ourcc categories
specified in Subparts B, E, F, H, Q, R, 5, L,,. V, X, Y~
-Z--or or EB of this Part, if the plantsource is subject
to this Subpart. A p-lantsource is subject to this
Subpart if it contains process emission sourcesunits,
not regulated by Subparts B, E, F (excluding Section
218.204(1) of this Part), H (excluding Section 218.405
140-0693

287
of this Part),
Q,
R, S, T (excluding Section 218.486 of
this Part), V, X,
Y~e~Z
or BB of this Part; which as
a group both:
1) ll1~ave maximum theoretical emissions of 91 Mg (100
tons) or more per calendar year of VON if no air
pollution control equipment were used, and
2) Aare not limited to less than 91 Mg (100 tons) of
VON emissions per calendar year in the absence of
air pollution control equipment, through
production or capacity limitations contained in a
federally enforceable construction permit or a SIP
revision.
b) If a plantsource ceases to fulfill the criteria of
Subsection (a) of this Section, the requirements of
this Subpart shall continue to apply to a miscellaneous
organic chemical manufacturing process emission
sourccunit which was ever subject to the control
requirements of Section 218.966 of this Part.
C)
No limits under this Subpart shall apply to emission
sourccsunits with emissions of VON to the atmosphere
less than or equal to 0.91 Mg (1.0 ton) per calendar
year if the total emissions from such emission units
~ourccs not complying with Section 218.966 of this Part
does not exceed 4.5 Mg (5.0 tons) per calendar year.
d) For the purposes of this Subpart, an emission source
unit shall be considered regulated by a Subpart if it
is subject to the limits of that Subpart. An emission
sourceunit is not considered regulated by a Subpart if
it is not subiect to the limits of that Subpart, e.g.,
the emission unit is covered by an exemption in the
Subpart or the applicability criteria of the Subpart
are not met. its emissions are below the applicability
cutoff level or if the source is covered hv an
exemption.
e) For the purposes of this Subpart, uncontrolled VON
emissions are the emissions of VON which would result
if no air pollution control equipment were used.
(Source: Amended at — Ill. Reg.
______,
effective
__________
Section 218.963
Permit Conditions
No person shall violate any condition in a permit when the
condition results in exclusion of the plantsource or an emission
sourceunit from this Subpart.
Qt140-069~

288
(Source: Amended at
Ill. Req.
______,
effective
___________)
Section 218.966
Control Requirements
Every owner or operator of an emission soureca miscellaneous
organic chemical manufacturing process emission unit subject to
this Subpart shall comply with the requirements of subsection (a)
or (b) below.
a) Emission capture and control techniques which achieve
an overall reduction in uncontrolled VON emissions of
at least 81 percent from each emission unit, or
(Board Note: For the purpose of this provision, an
emission unit is any part or activity at a source of a
type that by itself is subiect to control requirements
in other Subparts of this Part or 40 CFR 60,
incorporated by reference in Section 218.112, e.g., a
coating line, a printing line, a process unit, a
wastewater system, or other equipment, or is otherwise
any part or activity at a source.)
b) An alternative control plan which has been approved by
the Agency and approved by the USEPA as a SIP revision.
~j Any leaks from components subiect to the control
requirements of this Subpart shall be subject to the
following control measures:
fl
Repair any component from which a leak of VOL can
be observed. The repair shall be completed as soon
as practicable but no later than 15 days after the
leak is found, unless the leaking component cannot
be repaired until the process unit is shut down,
in which case the leaking component must be
repaired before the unit is restarted.
21
For any leak which cannot be readily repaired
within one hour after detection, the following
records, as set forth in this subsection, shall be
kept. These records shall be maintained by the
owner or operator for a minimum of two years after
the date on which they are made. Copies of the
records shall be made available to the Agency or
USEPA upon verbal or written request.
~j The name and identification of the leaking
component
~j.. The date and time the leak is detected
~ The action taken to repair the leak; and
01140-0695

289
P1 The date and time the leak is repaired.
(Source: Amended at — Ill. Req.
______,
effective
__________)
Section 218.967
Compliance Schedule
Every owner or operator of an emission ~ourceunit subject to the
control requirements of this Subpart shall comply with the
requirements of this Subpart on and after a date consistent with
Section 218.106 of this Part.
(Source: Amended at — Ill. Reg.
______,
effective
___________)
Section 218.968
Testing
a) When in the opinion of the Agency it is necessary to
conduct testing to demonstrate compliance with Section
218.966 of this Part, the owner or operator of a VON
emission sourccunit subject to the requirements of this
Subpart shall, at his own expense, conduct such tests
in accordance with the applicable test methods and
procedures specified in Section 218.105 of this Part.
b) Nothing in this Section shall limit the authority of
the USEPA pursuant to the Clean Air Act, as amended, to
require testing.
(Source: Amended at
Ill. Req.
______,
effective
__________)
SUBPART TT: OTHER EMISSION -SOURCES UNITS
Section 218.980
Applicability
a) The requirements of this Subpart shall apply to a
p-lant-’--s-source’s VON emission sourcesunits, which are
not included within any of the -s-o-urcc categories
specified in Subparts B, E, F, H, Q, R, S, ~ V, X, Y,
Z, AA, ~ PP, QQ, or RR of this Part, or are not
exempted from permitting requirements pursuant to 35
Ill. Adm. Code 201.146, if the plantsource is subject
to this Subpart. A p-lantsource is subject to this
Subpart if it contains process emission sourc-eounits,
not regulated by Subparts B, E, F (excluding Section
218.204(1) of this Part), H (excluding Section 218.405
of this Part), Q, R, S, T (excluding Section 218.486 of
this Part), V, X, Y e~ Z or BB of this Part, which as
a group both:
1) H~avemaximum theoretical emissions of 91 Mg (100
tons) or more per calendar year of VOM if no air
pollution control equipment were used, and
01140-0696

290
2) ~re not limited to less than 91 Mg (100 tons) of
VON emissions per calendar year in the absence of
air pollution control equipment, through
production or capacity limitations contained in a
federally enforceable construction or operating
permit or a SIP revision.
b) If a plantsource ceases to fulfill the criteria of
subsection (a), of this Section the requirements of
this Subpart shall continue to apply to an emission
s-ourccunit which was ever subject to the control
requirements of Section 218.986 of this Part.
c) No limits under this Subpart shall apply to emission
sourccsunits with emissions of VON to the atmosphere
less than or equal to 2.3 Mg (2.5 tons) per calendar
year if the total emissions from such emission units
-s-ourccs not complying with Section 218.986 of this Part
does not exceed 4.5 Mg (5.0 tons) per calendar year.
d) For the purposes of this Subpart, an emission s-our-ce
unit shall be considered regulated by a Subpart if it
is subject to the limits of that Subpart. An emission
sourceunit is not considered regulated by a Subpart if
it is not subject to the limits of that Subpart, e.g.,
the emission unit is covered by an exemption in the
Subpart or the applicability criteria of the Subpart
are not met. its emissions arc below the applicability
cutoff level or if the source is covered by an
exemption.
e) The control requirements in Subparts ~
QQ,
RR, SS and
TT shall not apply to sewage treatment plantsy~.
vegetable oil extraction and processing plants, coke
ovens (including by—product recovery plants), fuel
combustion sources-~-jbakeries-nj barge loading
facilitiesTj, jet engine test cells-1~pharmaceutical
manufacturing production of polystyrene foam insulation
board -(-including storage and extrusion of scrap where
blowing agent is added to the polystyrene resin at the
plant source-)-. but not including blending and
preliminary expansion of resin prior to molding where
blowing agent is incorporated into the polystyrene
resin bY the producer of the resin7~production of
polystyrene foam packaging -(-not including blending and
preliminary expansion of resin prior to molding where
blowing agent is incorporated into the polystyrene
resin bY the producer of the resin; and storage and
extrusion of scrap where blowing agent is added to the
polystyrene resin at the plantsource3—rj and iron and
steel production.
01140-0697

291
(Source: Amended at — Ill. Req.
______,
effective
__________
Section 218.983
Permit Conditions
No person shall violate any condition in a permit when the
condition results in exclusion of the plantsource or an emission
sourceunit from this Subpart.
(Source: Amended at — Ill. Reg.
, effective
___________
Section 218.986
Control Requirements
Every owner or operator of an emission sourccunit subject to this
Subpart shall comply with the requirements of subsection (a), (b)
or (c) below.
a) Emission capture and control equipment which achieve an
overall reduction in uncontrolled VON emissions of at
least 81 percent from each emission unit, or
(Board Note: For the purpose of this provision, an
emission unit is any part or activity at a source of a
type that by itself is subject to control requirements
in other Subparts of this Part or 40 CFR 60,
incorporated by reference in Section 218.112, e.g., a
coating line, a printing line, a process unit, a
wastewater system, or other eguipment, or is otherwise
any part or activity at a source.)
b) For coating lines, the daily-weighted average VOM
content shall not exceed 0.42 kg VOMf1 (3.5 lbs
VON/gal) of coating (minus water and any compounds
which are specifically exempted from the definition of
VON) as applied during any day. Owners and operators
complying with this Section are not required to comply
with Section 218.301 of this Part, or
c) An alternative control plan which has been approved by
the Agency and approved by the USEPA as a SIP revision.
~j Non—contact process water cooling towers which are
subject to the control requirements of this Subpart
shall comply with the following control measures no
later than August 15, 1994 or upon initial startup:
,3j The owner or operator of a non—contact process
water cooling tower shall perform the following
actions to control emissions of volatile organic
material (VON) from such a tower:
~j Inspect and monitor such tower to identify
leaks of VON into the water, as further
Q1L~Q-06-98

292
specified in subsection (d) (3) below
~j When a leak is identified, initiate and carry
out steps to identify the specific leaking
component or components as soon as
practicable, as further specified in
subsection (d)(4) below.
Qj When a leaking component is identified which:
j) Can be removed from service without
disrupting production, remove the
component from service
j~J,. Cannot be removed from service without
disrupting production, undertake repair
of the component at the next reasonable
opportunity to do so including any
period when the component is out of
service for scheduled maintenance, as
further specified in subsection (d) (4)
below
~j. Maintain records of inspection and monitoring
activities, identification of leaks and
leaking components, elimination and repair of
leaks, and operation of equipment as related
to these activities, as further specified in
subsection (d) (5) below.
,~j A VON leak shall be considered to exist in a non-
contact process water cooling water system if the
VON emissions or VON content exceed background
levels as determined by monitoring conducted in
accordance with subsection (d) (3) (A) below.
,~j The owner or operator of an non—contact process
water cooling tower shall carry out an inspection
and monitoring program to identify VOM leaks in
the cooling water system.
~j The owner or operator of a non—contact
process water cooling tower shall submit to
the Agency a proposed monitoring program,
accompanied by technical justification for
the Program, including justification for the
sampling location(s), Parameter (s) selected
for measurement, monitoring and inspection
frequency, and the criteria used relative to
the monitored parameters to determine whether
a leak exists as specified in subsection
(d)(2) above.
OI~0-O69g

293
~j This inspection and monitoring program for
non—contact process water cooling towers
shall include, but shall not be limited to:
jj Monitoring of each such tower with a
water flow rate of 25,000 gallons per
minute or more at a petroleum refinery
at least weekly and monitoring of other
towers at least monthly
jjj Inspection of each such tower at least
weekly if monitoring is not performed at
least weekly.
~ This inspection and monitoring program shall
be carried out in accordance with written
procedures which the Agency shall specify as
a condition in a federally enforceable
operating permit. These procedures shall
include the VON background levels for the
cooling tower as established by the owner or
operator through monitoring; describe the
locations at which samples will be taken;
identify the parameter(s) to be measured, the
frequency of measurements, and the procedures
for monitoring each such tower, that is,
taking of samples and other subsequent
handling and analyzing of samples; provide
the criteria used to determine that a leak
exists as specified in subsection (d) (2)
above; and describe the records which will be
maintained.
P1 A non—contact process water cooling tower is
exempt from the requirements of subsections
(d) (3) (B) and (d) (3) (C) above if all
equipment where leaks of VON into cooling
water may occur is operated at a minimum
pressure in the cooling water of at least 35
kPa greater than the maximum pressure in the
process fluid.
j) The repair of a leak in a non—contact process
water cooling tower shall be considered to be
completed in an acceptable manner as follows:
~j Efforts to identify and locate the leaking
components are initiated as soon as
practicable, but in no event later than three
days after detection of the leak in the
cooling water tower
01140-0700

294
~j Leaking components shall be repaired or
removed from service as soon as possible but
no later than 30 days after the leak in the
cooling water tower is detected, unless the
leaking components cannot be repaired until
the next scheduled shutdown for maintenance.
~j The owner or operator of a non—contact process
water cooling tower shall keen records as set
forth below in this subsection. These records
shall be retained at a readily accessible location
at the source and shall be available for
inspection and copying by the Agency for at least
3 years:
~ Records of inspection and monitoring
activity
~j Records of each leak identified in such
tower, with date, time and nature of
observation or measured level of parameter~
~ Records of activity to identify leaking
components, with date initiated, summary of
components inspected with dates, and method
of inspection and observations
P1 Records of activity to remove a leaking
component from service or repair a leaking
component, with date initiated and completed,
description of actions taken and the basis
for determining the leak in such tower has
been eliminated. If the leaking component is
not identified, repaired or eliminated within
30 days of initial identification of a leak
in such tower, this report shall include
specific reasons why the leak could not be
eliminated sooner including all other
intervening periods when the process unit was
out of service, actions taken to minimize VON
losses prior to elimination of the leak and
any actions taken to prevent the recurrence
of a leak of this type.
~j The owner or operator of a non—contact process
water cooling tower shall submit an annual report
to the Agency which provides:
~j The number of leaks identified in each
cooling tower;
A general description of activity to repair
01140-0701

295
or eliminate leaks which were identified
~ Identification of each leak which was not
repaired in 30 days from the date of
identification of a leak in such a tower,
with description of the leaks, explanation
why the leak was not repaired in 30 days
p1 Identification of any periods when required
inspection and monitoring activities were not
carried out.
,~j Any leaks from comPonents subject to the control
requirements of this Subpart shall be subject to the
following control measures:
fl Repair any comPonent from which a leak of VOL can
be observed. The repair shall be comPleted as soon
as practicable but no later than 15 days after the
leak is found, unless the leaking component cannot
be repaired until the process unit is shut down,
in which case the leaking component must be
repaired before the unit is restarted.
21
For any leak which cannot be readily repaired
within one hour after detection, the following
records, as set forth below in this subsection,
shall be kept. These records shall be maintained
by the owner or operator for a minimum of two
years after the date on which they are made.
Copies of the records shall be made available to
the Agency or USEPA upon verbal or written
request.
~j The name and identification of the leaking
component
~j The date and time the leak is detected~
çj The action taken to repair the leak; and
121
The date and time the leak is repaired.
(Source: Amended at
Ill. Req.
______,
effective
___________)
Section 218.987
Compliance Schedule
Every owner or operator of an emissions sourccunit which is
subject to this Subpart shall comply with the requirements of
this Subpart on and after a date consistent with Section 218.106
of this Part.
01140-0702

296
(Source: Amended at — Ill. Req.
______,
effective
___________)
Section 218.988
Testing
a) When in the opinion of the Agency it is necessary to
conduct testing to demonstrate compliance with Section
218.986 of this Part, the owner or operator of a VON
emission sourceunit subject to the requirements of this
Subpart shall, at his own expense, conduct such tests
in accordance with the applicable test methods and
procedures specified in Section 218.105 of this Part.
b) Nothing in this Section shall limit the authority of
the USEPA pursuant to the Clean Air Act, as amended, to
require testing.
(Source: Amended at
Ill. Req.
______,
effective
___________)
SUBPART UU: RECORDKEEPING AND REPORTING FOR HON-CTC SOURCES
Section 218.990
Exempt Emission SourcesUnits
Upon request by the Agency, the owner or operator of an emission
unit source which is exempt from the requirements of Subparts PP,
QQ, RR, TT or Section 218.208(b) of this Part shall submit
records to the Agency within 30 calendar days from the date of
the request that document that the emission unit source is exempt
from those requirements.
(Source: Amended at — Ill. Req.
_____,
effective
__________
Section 218.991
Subject Emission S-ourccsUnits
a) Any owner or operator of a VOM emission sourceunit
which is subject to the requirements of Subpart PP, QQ,
RR or TT and complying by the use of emission capture
and control equipment shall comply with the following:
1) By a date consistent with Section 218.106 of this
Part, or upon initial start-up of a new emission
sourceunit, the owner or operator of the subject
VOM emission s-ourceunit shall demonstrate to the
Agency that the subject emission sourocunit will
be in compliance on and after a date consistent
with Section 218.106 of this Part, or on and after
the initial start-up date by submitting to the
Agency all calculations and other supporting data,
including descriptions and results of any tests
the owner or operator may have performed.
2) On and after a date consistent with Section
218.106 of this Part, or on and after the initial
01140-0703

297
start—up date, the owner or operator of a subject
VOM emission source shall collect and record all
of the following information each day and maintain
the information at the -f-acilitysource for a period
of three years:
A) Control device monitoring data.
B) A log of operating time for the capture
system, control device, monitoring equipment
and the associated emission source.
C) A maintenance log for the capture system,
control device and monitoring equipment
detailing all routine and non—routine
maintenance performed including dates and
duration of any outages.
3) On and after a date consistent with Section
218.106 of this Part, the owner or operator of a
subject VON emission source shall notify the
Agency in the following instances:
A) Any record showing a violation of the
requirements of Subpart PP, QQ, RR or TT
shall be reported by sending a copy of such
redord to the Agency within 30 days following
the occurrence of the violation.
B) At least 30 calendar days before changing the
method of compliance with Subpart PP or TT
from the use of capture systems and control
devices to the use of complying coatings, the
owner or operator shall comply with all
requirements of subsection (b) (1) of this
Section. Upon changing the method of
compliance with Subpart PP or TT from the use
of capture systems and control devices to the
use of complying coatings, the owner or
operator shall comply with all requirements
of subsection (b) of this Section.
4) A) When in the opinion of the Agency it is
necessary to conduct testing to demonstrate
compliance with this Subpart, the owner or
operator of a VOM emission source subject to
the requirements of this Subpart shall, at
his own expense, conduct such tests in
accordance with the applicable test methods
and procedures specified in Section 218.105
of this Part.
01 140-O7~i.~

298
B) Nothing in this Section shall limit the
authority of the USEPA pursuant to the Clean
Air Act, as amended, to require testing.
b) Any owner or operator of a coating line which is
subject to the requirements of Subpart PP or TT and
complying by means of the daily-weighted average VOM
content limitation shall comply with the following:
1) By a date consistent with Section 218.106 of this
Part, or upon initial start-up of a coating line
subject to Subpart PP or TT, the owner or operator
of the subject coating line shall certify to the
Agency that the coating line will be in compliance
on and after a date consistent with Section
218.106 of this Part, or on and after the initial
start-up date. Such certification shall include:
A) The name and identification number of each
coating line which will comply by means of
the daily-weighted average VON content
limitation.
B) The name and identification number of each
coating as applied on each coating line.
C) The weight of VON per volume and the volume
of each coating (minus water and any
compounds which are specifically exempted
from the definition of VON) as applied each
day on each coating line.
D) The instrument or method by which the owner
or operator will accurately measure or
calculate the volume of each coating as
applied each day on each coating line.
E) The method by which the owner or operator
will create and maintain records each day as
required in subsection (b) (2) of this
Section.
F) An example of the format in which the records
required in subsection (b) (2) of this Section
will be kept.
2) On and after a date consistent with Section
218.106 of this Part, or on and after the initial
start—up date, the owner or operator of a subject
coating line shall collect and record all of the
following information each day for each coating
line and maintain the information at the
01140-0705

299
facilit-ysource for a period of three years:
A) The name and identification number of each
coating as applied on each coating line.
B) The weight of VON per volume and the volume
of each coating (minus water and any
compounds which are specifically exempted
from the definition of VON) as applied each
day on each coating line.
C) The daily—weighted average VOM content of all
coatings as applied on each coating line as
defined in Section 218.104 of this Part.
3) On and after a date consistent with Section
218.106 of this Part, the owner or operator of a
subject coating line shall notify the Agency in
the following instances:
A) Any record showing violation of the
requirements of Subpart PP or TT shall be
reported by sending a copy of such record to
the Agency and the USEPA within 30 days
following the occurrence of the violation.
B) At least 30 calendar days before changing the
method of compliance with Subpart PP or TT
from the use of complying coatings to the use
capture systems and control devices, the
owner or operator shall comply with all
requirements of subsection (a) (1) of this
Section. Upon changing the method of
compliance with Subpart PP or TT from the use
of complying coatings to the use capture
systems and control devices, the owner or
operator shall comply with all requirements
of subsection (a) of this Section.
c) Any owner or operator of a VON emission source which is
subject to the requirements of Subpart PP, QQ, RR or TT
and complying by means of an alternative control plan
which has been approved by the Agency and approved by
the USEPA as a SIP revision shall comply with the
recordkeeping and reporting requirements specified in
the alternative control plan.
-
(Source: Amended at — Ill. Req.
______,
effective
01140-0706

300
Section 218.APPENDIX A
LIST OF CHEMICALS DEFINING SYNTHETIC ORGANIC CHEMICAL AND POLYMER
MANUFACTURING
CAS No. a
Chemical
105—57—7
Acetal
75-07-0
Acetaldehyde
107—89-1
Acetaldol
60-35-5
Acetamide
103—84-4
Acetanilide
64-19-7
Acetic acid
108-24-7
Acetic anhydride
67-64-1
Acetone
75-86-5
Acetone cyanohydrin
75-05-8
Acetonitrile
98-86-2
Acetophenone
75-36-5
Acetyl chloride
74—86—2
Acetylene
107—02—8
Acrolein
79-06-1
Acrylamide
79—10—7
Acrylic acid & esters
107-13-1
Acrylonitrile
124—04—9
Adipic acid
111—69—3
Adiponitrile
(b)
Alkyl naphthalenes
107—18—6
Allyl alcohol
107—05—1
Allyl chloride
1321—11-5
Aminobenzoic acid
111-41—1
Aminoethylethanolanuine
123—30-8
p-aminophenol
628-63—7,
Amyl acetates
123—92—2
.7l~4l~Oc
Amyl alcohols
110—58—7
Amyl amine
543—59—9
Amyl chloride
Amyl mercaptans
1322-06-1
Amyl phenol
62—53—3
Aniline
142—04—1
Aniline hydrochloride
29191—52—4
Anisidine
100—66—3
Anisole
118—92—3
Anthranilic acid
84-65-1
Anthraquinone
100—52—7
Benzaldehyde
55-21—0
Benzamide
71-43-2
Benzene
98-48—6
Benzenedisulfonic acid
CAS No. a
Chemical
98-11-3
Benzenesulfonic acid
134—81—6
Benzil
76—93—7
Benzilic acid
65—85—0
Benzoic acid
01140-0707

301
119—53—9
Benzoin
100-47-0
Benzonitrile
119-61-9
Benzophenone
98-07—7
Benzotrichloride
98—88—4
Benzoyl chloride
100-51—6
Benzyl alcohol
100—46-9
Benzylamine
120-51-4
Benzyl benzoate
100-44-7
Benzyl chloride
98-87-3
Benzyl dichloride
92-52-4
Biphenyl
80-05-7
Bisphenol A
10-86-1
Bromobenzene
27497-51-4
Bromonaphthalene
106-99-0
Butadiene
106—98—9
1—butene
123-86-4
n-butyl acetate
141-32-2
n-butyl acrylate
71-36—3
n—butyl alcohol
78—92-2
s—butyl alcohol
75—65—0
t-butyl alcohol
109-73-9
n-butylamine
13952—84-6
s-butylamine
75-64-9
t-butylamine
98-73-7
p—tert-butyl benzoic acid
107—88—0
1,3—butylene qlycol
123-72-8
n-butyraldehyde
107-92-6
Butyric acid
106-31-0
Butyric anhydride
109-74-0
Butyronitrile
105-60-2
Caprolactam
75—1-50
Carbon disulfide
558-13-4
Carbon tetrabromide
55-23-5
Carbon tetrachloride
9004—35—7
Cellulose acetate
79-11-8
Chloroacetic acid
108-42-9
m—chloroaniline
95—51-2
o—chloroaniline
106-47-8
p-chloroaniline
35913-09-8
Chlorobenzaldehyde
108-90-7
Chlorobenzene
118-91-2,
Chlorobenzoic acid
535—80—8,
CAS No. a
Chemical
74—11—3c
2136-81—4,
Chlorobenzotrichloride
2136—89—2,
5216—2 S~l~
1321-03-5
Chlorobenzoyl chloride
75-45-6
Chlorodifluoroethane
25497-29—4
Chlorodifluoromethane
67-66—3
Chloroform
01140-0708

302
25586-43-0
Chloronaphthalene
88—73—3
o-chloronitrobenzene
100-00-5
p-chloronitrobenzene
25167-80-0
Chlorophenols
126-99-8
Chloroprene
7790-94-5
Chlorosulfonic acid
108-41-8
m-chlorotoluene
95-49—8
o-chlorotoluene
106-43-4
p-chlorotoluene
75-72-9
Chlorotrifluoromethane
108—39—4
m—cresol
95-48—7
o—cresol
106—44—5
p—cresol
1319-77-3
Mixed cresols
1319—77-3
Cresylic acid
4170—30-0
Crotonaldehyde
3724—65-0
Crontonic acid
98—82-8
Cumene
80-15-9
Cumene hydroperoxide
372-09—8
Cyanoacetic acid
506—77-4
Cyanoqen chloride
108—80-5
Cyanuric acid
108—77—0
Cyanuric chloride
110-82—7
Cyclohexane
108—93—0
Cyclohexanol
108—94—1
Cyclohexanone
110-83-8
Cyclohexene
108—91-8
Cyclohexylamine
111-78-4
Cyclooctadiene
112—30-1
Decanol
123-42—2
Diacetone alcohol
27576—04—1
Diaminobenzoic acid
95—76—1,
Dichloroaniline
95—82—9,
554—00—7,
608—27—5,
608—31—1,
626—43—7,
CAS No. a
Chemical
27134—27—6,
57311—92—9c
541-73-1
m-dichlorobenzene
95—50—1
o-dichlorobenzene
106-46-7
p-dichlorobenzene
75-71—8
Dichiorodifluoromethane
111-44-4
Dichloroethyl ether
107—06—2
l,2-dichloroethane (EDC)
96-23-1
Dichlorohydrin
26952—23—8
Dichloropropene
101—83-7
Dicyclohexylamine
109—89-7
Diethylamine
111—46—6
Diethylene qlycol
011400709

303
112-36—7
Diethylene glycol diethyl ether
111-96-6
Diethylene qlycol dimethyl
ether
112—34—5
Diethylene glycol monobutyl
ether
124-17-7
Diethylene qlycol mononbutyl
ether
acetate
111-90-0
Diethylene glycol monoethyl
-
ether
112-15-2
Diethylene glycol monoethyl
ether acetate
111-77-3
Diethylene glycol monomethyl
ether
64—67—5
Diethyl sulfate
75-37—6
Difluoroethane
25167—70-8
Diisobutylene
26761—40—0
Diisodecyl phthalate
27554—26-3
Diisooctyl phthalate
674—82-8
Diketene
124—40-3
Dimethylamine
121—69-7
N,N-dimethylaniline
115-10-6
N,N-dimethyl ether
68-12-2
N,N-dimethylformamide
57-14-7
Dimethylhydrazine
77-78—1
Dimethyl sulfate
75-18—3
Dimethyl sulfide
67-68—5
Dimethyl sulf oxide
120-61-6
Dimethyl terephthalate
99—34—3
3,5—dinitrobenzoic acid
51-28—5
Dinitrophenol
Dinitrotoluene
123—91-1
Dioxane
646—06-0
Dioxilane
CAS No. a
Chemical
122—39-4
Diphenylamine
101-84-4
Diphenyl oxide
102—08-9
Diphenyl thiourea
25265—71—8
Dipropylene qlycol
25378—22-7
Dodecene
28675—17-4
Dodecylaniline
27193—86—8
Dodecylphenol
106-89-8
Epichlorohydrin
64-17-5
Ethanol
l4l~43~5c
Ethanolamines
14 1-78-6
Ethyl acetate
141-97-9
Ethyl acetoacetate
140-88-5
Ethyl acrylate
75-04—7
Ethylamine
100-41-4
Ethylbenzene
74-96-4
Ethyl bromide
9004-57-3
Ethylcellulose
01140-0710

304
75-00-3
Ethyl chloride
105-39-5
Ethyl chloroacetate
105-56-6
Ethylcyanoacetate
74—85—1
Ethylene
96—49—1
Ethylene carbonate
107-07-3
Ethylene chlorohydrin
107-15-3
Ethylenediainine
106-93-4
Ethylene dibromide
107—21-1
Ethylene glycol
111-55-7
Ethylene glycol diacetate
110-71-4
Ethylene glycol dimethyl ether
111-76-2
Ethylene qlycol monobutyl ether
112-07-2
Ethylene glycol monobutyl ether
acetate
110-80-5
Ethylene glycol monoethyl ether
111—15-9
Ethylene glycol monoethyl ether
acetate
109-86-4
Ethylene glycol monoethyl ether
110-49-6
Ethylene glycol inonomethyl
ether acetate
122-99-6
Ethylene glycol monophenyl
ether
2807-30-9
Ethylene glycol monopropyl
ether
75-21—8
Ethylene oxide
60-29-7
Ethyl ether
104-76-7
2-ethylhexanol
122-51-0
Ethyl orthoformate
95-92-1
Ethyl oxalate
41892-71-1
Ethyl sodium oxaloacetate
CAS No. a
Chemical
50-00-0
Formaldehyde
75-12-7
Formainide
64-18-6
Formic acid
110-17-8
Fumaric acid
98—01—1
Furfural
56-81-5
Glycerol (Synthetic)
26545-73-7
Glycerol dichlorohydrin
25791—96-2
Glycerol triether
56—40—6
Glycine
107—22—2
Glyoxal
118—74-1
Hexachlorobenzene
67—72—1
Hexachloroethane
36653-82-4
Hexadecyl alcohol
124-09-4
Hexamethylenediamine
629-11-8
Hexamethylene glycol
100-97-0
Hexamethylenetetramine
74—90-8
Hydrogen cyanide
123-31-9
Hydroquinone
99-96-7
p-hydroxybenzoic acid
26760—64—5
Isoainylene
78—83-1
Isobutanol
01140-0711

305
110-19—0
Isobutyl acetate
115-11-7
Isobutylene
78-84-2
Isobutyraldehyde
79—31-2
Isobutyric acid
25339—17—7
Isodecanol
26952-21-6
Isooctyl alcohol
78-78-4
Isopentane
78-59-1
Isophorone
121-91-5
Isophthalic acid
78—79—5
Isoprene
67-63-0
Isoptopanol
108-21-4
Isopropyl acetate
75—31-0
Isopropylamine
75—29-6
Isopropyl chloride
25168-06—3
Isopropylphenol
463-51-4
Ketene
(b)
Linear alkyl sulfonate*
123-01-3
Linear alkylbenzene
110—16—7
Naleic acid
108-31-6
Maleic anhydride
6915—15—7
Malic acid
141-79—7
Mesityl oxide
121-47—1
Metanilic acid
79-41-4
Methacrylic acid
563-47—3
Methallyl chloride
67—56-1
Methanol
CAS No. a
Chemical
79—20-9
Methyl acetate
105-45—3
Methyl acetoacetate
74—89-5
Nethylamine
100-61-8
n-methylaniline
74-83-9
Methyl bromide
37365-71-2
Methyl butynol
74—87-3
Methyl chloride
108-87-2
Methyl cyclohexane
1331-22-2
Methyl cyclohexanone
75-09-2
Methylene chloride
101-77-9
Methylene dianiline
101-68-8
Methylene diphenyl diisocyanate
78-93-3
Methyl ethyl ketone
107-31-3
Methyl formate
108-11-2
Methyl isobutyl carbinol
108-10-1
Methyl isobutyl ketone
80-62-6
Methyl methacrylate
77-75-8
Methylpentynol
98—83-9
B-methylstyrene
110-91—8
Morpholine
85—47-2
a-naphthalene sulfonic acid
120-18-3
B-naphthalene sulfonic acid
90-15-3
a-naphthol
135-19-3
B-naphthol
75-98-9
Neopentanoic acid
01140-0712

306
88-74—4
o—nitroaniline
100-01-6
p—nitroaniline
91-23—6
o—nitroanisole
100—17-4
p—nitroanisole
98-95—3
Nitrobenzene
Nitrobenzoic acid (o, m & p)
79-24-3
Nitroethane
75-52-5
Nitromethane
88-75-5
Nitrophenol
25322-01-4
Nitropropane
1321-12-6
Nitrotoluene
27215—95—8
Nonene
25154—52—3
Nonylphenol
27193-28—8
Octylphenol
123—63-7
Paraldehyde
115-77-5
Pentaerythritol
109—66-0
n-pentane
109-67-1
1-pentene
127-18-4
Perchloroethylene
594-42-3
Perchloromethyl mercaptan
94—70—2
o-phenetidine
156—43-4
p—phenetidine
CAS No.
a
Chemical
108—95—2
Phenol
98-67—9,
Phenolsulfonic acids
585—38—6,
609—46—1,
91-40-7
Phenyl anthranilic acid
(b)
Phenylenediamine
75-44-5
Phosqene
85-44-9
Phthalic anhydride
85-41-6
Phthalimide
108—99—6
b—picoline
110-85-0
Piperazine
9003-29-6,
Polybutenes
25322—68-3
Polyethylene glycol
25322-69-4
Polypropylene qlycol
123-38-6
Propionaldehyde
79-09-4
Propionic acid
71-23—8
n-propyl alcohol
107-10-8
Propylamine
540-54-5
Propyl chloride
115-07-1
Propylene
127-00-4
Propylene chlorohydrin
78—87—5
Propylene dichloride
57-55-6
Propylene glycol
75-56-9
Propylene oxide
110—86—1
Pyridine
106—51—4
Quinone
108—46—3
Resorcinol
01140-0713

307
27138—57-4
Resorcylic acid
69—72—7
Salicylic acid
127—09-3
Sodium acetate
532-32-1
Sodium benzoate
9004—32—4
Sodium carboxymethyl cellulose
3926—62—3
Sodium chioroacetate
141-53-7
Sodium formate
139-02-6
Sodium phenate
110-44-1
Sorbic acid
100-42-5
Styrene
110-15-6
Succinic acid
110—61—2
Succinitrile
121—57—3
Sulfanilic acid
126—33-0
Sulfolane
1401—55—4
Tannic acid
100-21-0
Terephthalic acid
Tetrachloroethanes
CAS No. a
Chemical
117-08-8
Tetrachlorophthalic anhydride
78-00-2
Tetraethyllead
119-64-2
Tetrahydronaphthalene
85-43-8
Tetrahydrophthalic anhydride
75-74-1
Tetrainethyllead
110-60-1
Tetrainethylenediamine
110-18-9
Tetramethylethylenediamine
108-88-3
Toluene
95—80—7
Toluene—2, 4-diamine
584-84-9
Toluene—2 , 4-diisocyanate
26471—62-5
Toluene diisocyanates (mixture)
1333-07—9
Toluene sulfonamide
Toluenesulfonic acids
98—59—9
Toluene sulfonyl chloride
26915—12—8
Toluidines
87-61-6,
Trichlorobenzenes
108—70—3,
l2O—82—lc
7 1-55-6
1,1, l-trichloroethane
79—00-5
1, l,2-trichloroethane
79—01-6
Trichioroethylene
75-69-4
Trichiorofluoromethane
9 6-18-4
1,2, 3—trichloropropane
7 6—13—1
1,1, 2—trichloro—l, 2, 2—trifluoro
ethane
121—44—8
Triethylainine
112-27-6
Triethylene glycol
112-49-2
Triethylene glycoldimethyl
ether
7756-94-7
Triisobutylene
75-50-3
Trimethylamine
57—13—6
Urea
108—05-4
Vinyl acetate
75-01—4
Vinyl chloride
01140-07114

308
75-35-4
Vinylidene chloride
25013—15—4
Vinyl toluene
1330-20-7
Xylenes (mixed)
95-47-6
o—xylene
106-42—3
p—xylene
1300—71—6
Xylenol
1300-73—8
Xylidine
(b)
methyl tert-butyl ether
9002-88-4
Polyethylene
(b)
Polypropylene
9009-53-6
Polystyrene
a) CAS numbers refer to the Chemical Abstracts Reqistery
numbers assigned to specific chemicals, isomers or mixtures
of chemicals. Some isomers or mixtures that are covered by
the standards do not have CAS numbers assigned to them. The
standards apply to all of the chemicals listed, whether CAS
numbers have been assigned or not.
b) No CAS number(s) have been assigned to this chemical, to its
isomers, or mixtures containing these chemicals.
c) CAS numbers for some of the isomers are listed: the
standards apply to all of the isomers and mixtures, even if
CAS numbers have not been assigned.
(Source: Amended at
Ill. Reg.
______,
effective
___________
0 1140-0715

309
Section 218.APPENDIX B
VOM MEASUREMENT TECHNIQUES FOR CAPTURE EFFICIENCY
Procedure G.l - Captured VOGM Emissions
1. INTRODUCTION
1.1 Applicability. This procedure is applicable for determining
the volatile organic materialseompounds (VOG~j) content of
captured gas streams. It is intended to be used as a segment in
the development of liquid/gas or gas/gas protocols for
determining VO~jcapture efficiency (CE) for surface coating and
printing operations. The procedure may not be acceptable in
certain site—specific situations, e.g., when: (1) direct fired
heaters or other circumstances affect the quantity of VO~jat the
control device inlet; and (2) particulate organic aerosols are
formed in the process and are present in the captured emissions.
1.2 Principle. The amount of VOG~jcaptured (G) is calculated as
the sum of the products of the VOGM content (CGj), the flow rate
(Q~), and the sample time (Ta) from each captured emissions
point.
1.3 Estimated Measurement Uncertainty. The measurement
uncertainties are estimated for each captured or fugitive
emissions point as follows: Q0
=
5.5 percent and
C0~
=
±5.0percent. Based on t~iese numbers, the probable
uncertainty for G is estimated at about ±7.4percent.
1.4 Sampling Requirements. A capture efficiency test shall
consist of at least three sampling runs. The sampling time for
each run should be at least 8 hours, unless otherwise approved.
1.5 Notes. Because this procedure is often applied in highly
explosive areas, caution and care should be exercised in choosing
appropriate equipment and installing and using the equipment.
Mention of trade names or company products does not constitute
endorsement. All gas concentrations (percent, ppm) are by
volume, unless otherwise noted.
2. APPARATUS AND REAGENTS
2.1 Gas VOGN Concentration. A schematic of the measurement
system is shown in Figure 1. The main components are described
below:
2.1.1 Sample Probe. Stainless steel, or equivalent. The probe
shall be heated to prevent VGG~jcondensation.
2.1.2 Calibration Valve Assembly. Three-way valve assembly at
the outlet of sample probe to direct the zero and calibration
gases to the analyzer. Other methods, such as quick—connect
01140-0716

310
lines, to route calibration gases to the outlet of the sample
probe are acceptable.
2.1.3 Sample Line. Stainless steel or Teflon tubing to
transport the sample gas to the analyzer. The sample line must
be heated to prevent condensation.
2.1.4 Sample Pump. A leak-free pump, to pull the sample gas
through the system at a flow rate sufficient to minimize the
response time of the measurement system. The components of the
pump that contact the gas stream shall be constructed of
stainless steel or Teflon. The sample pump must be heated to
prevent condensation.
2.1.5 Sample Flow Rate Control. A sample flow rate control
valve and rotameter, or equivalent, to maintain a constant
sampling rate within 10 percent. The flow rate control valve and
rotameter must be heated to prevent condensation. A control
valve may also be located on the sample pump bypass 1oop to
assist in controlling the sample pressure and flow rate.
2.1.6 Sample Gas Manifold. Capable of diverting a portion of
the sample gas stream to the flame ionization analyzer (FIA), and
the remainder to the bypass discharge vent. The manifold
components shall be constructed of stainless steel or Teflon. If
captured or fugitive emissions are to be measured at multiple
locations, the measurement system shall be designed to use
separate sampling probes, lines, and pumps for each measurement
location and a common sample gas manifold and FIA. The sample
gas manifold and connecting lines to the FIA must be heated to
prevent condensation.
2.1.7 Organic Concentration Analyzer. An FIA with a span value
of 1.5 times the expected concentration as propane; however,
other span values may be used if it can be demonstrated that they
would provide more accurate measurements. The system shall be
capable of meeting or exceeding the following specifications:
2.1.7.1 Zero Drift. Less than ±3.0percent of the span value.
2.1.7.2 Calibration Drift. Less than ±3.0percent of the span
value.
2.1.7.3 Calibration Error. Less than ±5.0percent of the
calibration gas value.
2.1.7.4 Response Time. Less than 30 seconds.
2.1.8 Integrator/Data Acquisition System. An analog or digital
device or computerized data acquisition system used to integrate
the FIA response or compute the average response and record
measurement data. The minimum data sampling frequency for
01140-0717

311
computing average or integrated values is one measurement value
every 5 seconds. The device shall be capable of recording
average values at least once per minute.
2.1.9 Calibration and Other Gases. Gases used for calibration,
fuel, and combustion air (if required) are contained in
compressed gas cylinders. All calibration gases shall be
traceable to NIST standards and shall be certified by the
manufacturer to ±1percent of the tag value. Additionally, the
manufacturer of the cylinder should provide a recommended shelf
life for each calibration gas cylinder over which the
concentration does not change more than ±2percent from the
certified value. For calibration gas values not generally
available, alternative methods for preparing calibration gas
mixtures, such as dilution systems, may be used with prior
approval.
2.1.9.1 Fuel. A 40 percent H2/60 percent He or 40 percent H2/60
percent N2 gas mixture is recommended to avoid an oxygen
synergism effect that reportedly occurs when oxygen concentration
varies significantly from a mean value.
2.1.9.2 Carrier Gas. High purity air with less than 1 ppm of
organic material (as propane or carbon equivalent) or less than
0.1 percent of the span value, whichever is greater.
2.1.9.3 FIA Linearity Calibration Gases. Low-, mid-, and
high—range gas mixture standards with nominal propane
concentrations of 20—30, 45-55, and 70—80 percent of the span
value in air, respectively. Other calibration values and other
span values may be used if it can be shown that more accurate
measurements would be achieved.
2.1.10 Particulate Filter. An in-stack or an out-of-stack glass
fiber filter is recommended if exhaust gas particulate loading is
significant. An out-of-stack filter must be heated to prevent
any condensation unless it can be demonstrated that no
condensation occurs.
2.2 Captured Emissions Volumetric Flow Rate.
2.2.1 Method 2 or 2A Apparatus. For determining volumetric flow
rate.
2.2.2 Method 3 Apparatus and Reagents. For determining
molecular weight of the gas stream. An estimate of the molecular
weight of the gas stream may be used if it can be justified.
2.2.3 Method 4 Apparatus and Reagents. For determining moisture
content, if necessary.
3. DETERMINATION OF VOLUMETRIC FLOW RATE OF CAPTURED EMISSIONS
01140-0718

312
3.1 Locate all points where emissions are captured from the
affected -f-acilityeinission unit. Using Method 1, determine the
sampling points. Be sure to check each site for cyclonic or
swirling flow.
3.2 Measure the velocity at each sampling site at least once
every hour during each samplinq run using Method 2 or 2A.
4. DETERMINATION OF VOGN CONTENT OF CAPTURED EMISSIONS
4.1 Analysis Duration. Measure the VO~jresponses at each
captured emissions point during the entire test run or, if
applicable, while the process is operating. If there are
multiple captured emission locations, design a sampling system to
allow a single FIA to be used to determine the VOG~.Jresponses at
all sampling locations.
4.2 Gas VOGN Concentration.
4.2.1 Assemble the sample train as shown in Figure 1. Calibrate
the FIA according to the procedure in Section 5.1.
4.2.2 Conduct a system check according to the procedure in
Section 5.3.
4.2.3 Install the sample probe so that the probe is centrally
located in the stack, pipe, or duct, and is sealed tightly at the
stack port connection.
4.2.4 Inject zero gas at the calibration valve assembly. Allow
the measurement system response to reach zero. Measure the
system response time as the time required for the system to reach
the effluent concentration after the calibration valve has been
returned to the effluent sampling position.
4.2.5 Conduct a system check before and a system drift check
after each sampling run according to the procedures in Sections
5.2 and 5.3. If the drift check following a run indicates
unacceptable performance, the run is not valid. The tester may
elect to perform system drift checks during the run not to exceed
one drift check per hour.
4.2.6 Verify that the sample lines, filter, and pump
temperatures are 120 ±5°C.
4.2.7 Begin sampling at the start of the test period and
continue to sample during the entire run. Record the starting
and ending times and any required process information as
appropriate. If multiple captured emission locations are sampled
using a single FIA, sample at each location for the same amount
of time (e.q., 2 minutes) and continue to switch from one
0 1140-07
19

313
location to another for the entire test run. Be sure that total
sampling time at each location is the same at the end of the test
run. Collect at least 4 separate measurements from each sample
point during each hour of testing. Disregard the measurements at
each sampling location until two times the response time of the
measurement system has elapsed. Continue sampling for at least 1
minute and record the concentration measurements.
4.3 Background Concentration.
4.3.1 Locate all I’IDO’s of the TTE. A sampling point shall be
centrally located outside of the TTE at 4 equivalent diameters
from each NDO, if possible. If there are more than 6 NDO’s,
choose 6 sampling points evenly spaced among the NDO’s.
4.3.2 Assemble the sample train as shown in Figure 2. Calibrate
the FIA and conduct a system check according to the procedures in
Sections 5.1 and 5.3. NOTE: This sample train shall be a
separate sampling train from the one to measure the captured
emissions.
4.3.3 Position the probe at the sampling location.
4.3.4 Determine the response time, conduct the system check and
sample according to the procedures described in Sections 4.2.4 to
4.2.7.
4.4 Alternative Procedure. The direct interface sampling and
analysis procedure described in Section 7.2 of Method 18 may be
used to determine the gas VOC concentration. The system must be
designed to collect and analyze at least one sample every 10
minutes.
5. CALIBRATION AND QUALITY ASSURANCE
5.1 FIA Calibration and Linearity Check. Make necessary
adjustments to the air and fuel supplies for the FIA and ignite
the burner. Allow the FIA to warm up for the period recommended
by the manufacturer. Inject a calibration gas into the
measurement system and adjust the back—pressure regulator to the
value required to achieve the flow rates specified by the
manufacturer. Inject the zero— and the high—range calibration
gases and adjust the analyzer calibration to provide the proper
responses. Inject the low— and mid—range gases and record the
responses of the measurement system. The calibration and
linearity of the system are acceptable if the responses for all
four gases are within 5 percent of the respective gas values. If
the performance of the system is not acceptable, repair or adjust
the system and repeat the linearity check. Conduct a calibration
and linearity check after assembling the analysis system and
after a major change is made to the system.
0! 140-0720

314
5.2 Systems Drift Checks. Select the calibration gas that most
closely approximates the concentration of the captured emissions
for conducting the drift checks. Introduce the zero and
calibration gas at the calibration valve assembly and verify that
the appropriate gas flow rate and pressure are present at the
FIA. Record the measurement system responses to the zero and
calibration gases. The performance of the system is acceptable
if the difference between the drift check measurement and the
value obtained in Section 5.1 is less than 3 percent of the span
value. Conduct the system drift checks at the end of each run.
5.3 System Check. Inject the high range calibration gas at the
inlet of the sampling probe and record the response. The
performance of the system is acceptable if the measurement system
response is within 5 percent of the value obtained in Section 5.1
for the high range calibration gas. Conduct a system check
before and after each test run.
5.4 Analysis Audit. Immediately before each test analyze an
audit cylinder as described in Section 5.2. The analysis audit
must agree with the audit cylinder concentration within 10
percent.
6. NOMENCLATURE
A~
=
area of NDO i, ft2-~
AN
=
total area of all NDO’s in the enclosure, ft2--~
CBj
=
corrected average VOGM concentration of background
emissions at point i, ppm propane--j
CB
=
average background concentration, ppm propane-~
C0~
=
corrected average VOGM concentration of captured
emissions at point j, ppm propane~
CDH
=
average measured concentration for the drift check
calibration gas, ppm propane--j.
C0~
average system drift check concentration for zero
concentration gas, ppm propane-~j
CR
=
actual concentration of the drift check
calibration gas, ppm propane~-j.
C1
=
uncorrected average background VOG~concentration
measured at point i, ppm propane--j
C~
=
uncorrected average VOGN concentration measured at
point j, ppm propane-~
01140-0721

315
G
=
total VOG~content of captured emissions, kg-~-~
K1
=
1.830
x
io6
kg/(m3-ppm)-~j
n
=
number of measurement points~-j.
=
average effluent volumetric flow rate corrected to
standard conditions at captured emissions pointj,
m3 / min~j
Tc
=
total duration of captured emissions sampling run,
mm.
7. CALCULATIONS
7.1 Total VOG~Captured Emissions.
n
G
=
E
(CGj
-
C8
)
~ T0 K1
Eq. 1
j
=1
7.2 VOGI~jConcentration of the Captured Emissions at Point
j.
CGj
=
(C~
— CDO)
CR
Eq. 2
— CDO
7.3 Background VOGM Concentration at Point i.
CBI
=
(C1
CDO)
CR
Eq. 3
7.4 Average Background Concentration.
CDH
C50
n
C3
=
E
1-1
C51A1
Eq. 4
nAN
NOTE: If the concentration at each point is within 20 percent of
the average concentration of all points, the terms “A1” and “AN”
may be deleted from Equation 4.
Procedure G.2 - Captured VOGM Emissions (Dilution Technique)
1. INTRODUCTION
1.1 Applicability. This procedure is applicable for determining
the volatile organic eompoundsmaterials (VOGI~j) content of
captured gas streams. It is intended to be used as a segment in
the development of a gas/gas protocol in which fugitive emissions
are measured for determining VOG~capture efficiency (CE) for
surface coating and printing operations. A dilution system is
01140-0722

316
used to reduce the VOGM concentration of the captured emission to
about the same concentration as the fugitive emissions. The
procedure may not be acceptable in certain site—specific
situations, e.g., when: (1) direct fired heaters or other
circumstances affect the quantity of VOGI~j at the control device
inlet; and
(2)
particulate organic aerosols are formed in the
process and are present in the captured emissions.
1.2 Principle. The amount of VOGN captured (G) is calculated as
the sum of the products of the VOGI~jcontent (C0~), the flow rate
and the sampling time (Tc) from each captured emissions
point.
1.3 Estimated Measurement Uncertainty. The measurement
uncertainties are estimated for each captured or fugitive
emissions point as follows:
=
±5.5percent and CGj
=
±5
percent. Based on these numbers, the probable uncertainty for G
is estimated at about ±7.4 percent.
1.4 Sampling Requirements. A capture efficiency test shall
consist of at least three sampling runs. The sampling time for
each run should be at least
8
hours, unless otherwise approved.
1.5 Notes. Because this procedure is often applied in highly
explosive areas, caution and care should be exercised in choosing
appropriate equipment and installing and using the equipment.
Mention of trade names or company products does not constitute
endorsement. All gas concentrations (percent, ppm) are by
volume, unless otherwise noted.
2. APPARATUS AND REAGENTS
2.1 Gas VOGM Concentration. A schematic of the measurement
system is shown in Figure 1. The main components are described
below:
2.1.1 Dilution System. A Kipp in-stack dilution probe and
controller or similar device may be used. The dilution rate may
be changed by substituting different critical orifices or
adjustments of the aspirator supply pressure. The dilution
system shall be heated to prevent VOGM condensation. Note: An
out-of-stack dilution device may be used.
2.1.2 Calibration Valve Assembly. Three-way valve assembly at
the outlet of sample probe to direct the zero and calibration
gases to the analyzer. Other methods, such as quick—connect
lines, to route calibration gases to the outlet of the sample
probe are acceptable.
2.1.3 Sample Line. Stainless steel or Teflon tubing to
transport the sample gas to the analyzer. The sample line must
be heated to prevent condensation.
0 I 140-0723

317
2.1.4 Sample Pump. A leak-free pump, to pull the sample gas
through the system at a flow rate sufficient to minimize the
response time of the measurement system. The components of the
pump that contact the gas stream shall be constructed of
stainless steel or Teflon. The sample pump must be heated to
prevent condensation.
2.1.5 Sample Flow Rate Control. A sample flow rate control
valve and rotameter, or equivalent, to maintain a constant
sampling rate within 10 percent. The flow control valve and
rotameter must be heated to prevent condensation. A control
valve may also be located on the sample pump bypass loop to
assist in controlling the sample pressure and flow rate.
2.1.6 Sample Gas Manifold. Capable of diverting a portion of
the sample gas stream to the flame ionization analyzer (FIA), and
the remainder to the bypass discharge vent. The manifold
components shall be constructed of stainless steel or Teflon. If
captured or fugitive emissions are to be measured at multiple
locations, the measurement system shall be designed to use
separate sampling probes, lines, and pumps for each measurement
location and a common sample gas manifold and FIA. The sample
gas manifold and connecting lines to the FIA must be heated to
prevent condensation.
2.1.7 Organic Concentration Analyzer. An FIA with a span value
of 1.5 times the expected concentration as propane; however,
other span values may be used if it can be demonstrated that they
would provide more accurate measurements. The system shall be
capable of meeting or exceeding the following specifications:
2.1.7.1 Zero Drift. Less than ±3.0percent of the span value.
2.1.7.2 Calibration Drift. Less than ±3.0percent of the span
value.
2.1.7.3 Calibration Error. Less than ±5.0percent of the
calibration gas value.
2.1.7.4 Response Time. Less than 30 seconds.
2.1.8 Integrator/Data Acquisition System. An analog or digital
device or computerized data acquisition system used to integrate
the FIA response or compute the average response and record
measurement data. The minimum data sampling frequency for
computing average or integrated values is one measurement value
every 5 seconds. The device shall be capable of recording
average values at least once per minute.
2.1.9 Calibration and Other Gases. Gases used for calibration,
fuel, and combustion air (if required) are contained in
compressed gas cylinders. All calibration gases shall be
UI ~40-07214

318
traceable to NIST standards and shall be certified by the
manufacturer to ±1percent of the tag value. Additionally, the
manufacturer of the cylinder should provide a recommended shelf
life for each calibration gas cylinder over which the
concentration does not change more than ±2 percent from the
certified value. For calibration gas values not generally
available, alternative methods for preparing calibration gas
mixtures, such as dilution systems, may be used with prior
approval.
2.1.9.1 Fuel. A 40 percent H2/60 percent He or 40 percent H2/60
percent N2 gas mixture is recommended to avoid an oxygen
synergism effect that reportedly occurs when oxygen concentration
varies significantly from a mean value.
2.1.9.2 Carrier Gas and Dilution Air Supply. High purity air
with less than 1 ppm of organic material (as propane or carbon
equivalent) or less than 0.1 percent of the span value, whichever
is greater.
2.1.9.3 FIA Linearity Calibration Gases. Low-, mid-, and
high—range gas mixture standards with nominal propane
concentrations of 20-30, 45-55, and 70—80 percent of the span
value in air, respectively. Other calibration values and other
span values may be used if it can be shown that more accurate
measurements would be achieved.
2.1.9.4 Dilution Check Gas. Gas mixture standard containing
propane in air, approximately half the span value after dilution.
2.1.10 Particulate Filter. An in-stack or an out-of-stack glass
fiber filter is recommended if exhaust gas particulate loading is
significant. An out-of-stack filter must be heated to prevent
any condensation unless it can be demonstrated that no
condensation occurs.
2.2 Captured Emissions Volumetric Flow Rate.
2.2.1 Method 2 or 2A Apparatus. For determining volumetric flow
rate.
2.2.2 Method 3 Apparatus and Reagents. For determining
molecular weight of the gas stream. An estimate of the molecular
weight of the gas stream may be used if it can be justified.
2.2.3 Method 4 Apparatus and Reagents. For determining moisture
content, if necessary.
3. DETERMINATION OF VOLUMETRIC FLOW RATE OF CAPTURED EMISSIONS
3.1 Locate all points where emissions are captured from the
affected facility. Using Method 1, determine the sampling points.
I 1. ñ
-

319
Be sure to check each site for cyclonic or swirling flow.
3.2 Measure the velocity at each sampling site at least once
every hour during each sampling run using Method 2 or 2A.
4. DETERMINATION OF VOG!j CONTENT OF CAPTURED EMISSIONS
4.1 Analysis Duration. Measure the VOGM responses at each
captured emissions point during the entire test run or, if
applicable, while the process is operating. If there are a
multiple captured emissions locations, design a sampling system
to allow a single FIA to be used to determine the VO~ responses
at all sampling locations.
4.2 Gas VOG~JConcentration.
4.2.1 Assemble the sample train as shown in Figure 1. Calibrate
the FIA according to the procedure in Section 5.1.
4.2.2 Set the dilution ratio and determine the dilution factor
according to the procedure in Section 5.3.
4.2.3 Conduct a system check according to the procedure in
Section 5.4.
4.2.4 Install the sample probe so that the probe is centrally
located in the stack, pipe, or duct, and is sealed tightly at the
stack port connection.
4.2.5 Inject zero gas at the calibration valve assembly.
Measure the system response time as the time required for the
system to reach the effluent concentration after the calibration
valve has been returned to the effluent sampling position.
4.2.6 Conduct a system check before and a system drift check
after each sampling run according to the procedures in Sections
5.2 and 5.4. If the drift check following a run indicates
unacceptable performance, the run is not valid. The tester may
elect to perform system drift checks during the run not to exceed
one drift check per hour.
4.2.7 Verify that the sample lines, filter, and pump
temperatures are 120 ±5°C.
4.2.8 Begin sampling at the start of the test period and
continue to sample during the entire run. Record the starting
and ending times and any required process information as
appropriate. If multiple captured emission locations are sampled
using a single FIA, sample at each location for the same amount
of time (e.g., 2 minutes) and continue to switch from one
location to another for the entire test run. Be sure that total
sampling time at each location is the same at the end of the test

320
run. Collect at least 4 separate measurements from each sample
point during each hour of testing. Disregard the measurements at
each sampling location until two times the response time of the
measurement system has elapsed. Continue sampling for at least 1
minute and record the concentration measurements.
4.3 Background Concentration.
4.3.1 Locate all NDO’s of the TTE. A sampling point shall be
centrally located outside of the TTE at 4 equivalent diameters
from each NDO, if possible. If there are more than 6 NDO’s,
choose 6 sampling points evenly spaced among the NDO’s.
4.3.2 Assemble the sample train as shown in Figure 2. Calibrate
the FIA and conduct a system check according to the procedures in
Sections 5.1 and
5.4.
4.3.3 Position the probe at the sampling location.
4.3.4 Determine the response time, conduct the system check and
sample according to the procedures described in Sections 4.2.4 to
4.2.8.
4.4 Alternative Procedure. The direct interface sampling and
analysis procedure described in Section 7.2 of Method 18 may be
used to determine the gas VOG~jconcentration. The system must be
designed to collect and analyze at least one sample every 10
minutes.
5. CALIBRATION AND QUALITY ASSURANCE
5.1 FIA Calibration and Linearity Check. Make necessary
adjustments to the air and fuel supplies for the FIA and ignite
the burner. Allow the FIA to warm up for the period recommended
by the manufacturer. Inject a calibration gas into the
measurement system after the dilution system and adjust the back—
pressure regulator to the value required to achieve the flow
rates specified by the manufacturer. Inject the zero— and the
hiqh—range calibration gases and adjust the analyzer calibration
to provide the proper responses. Inject the low— and mid—range
gases and record the responses of the measurement system. The
calibration and linearity of the system are acceptable if the
responses for all four gases are within 5 percent of the
respective gas values. If the performance of the system is not
acceptable, repair or adjust the system and repeat the linearity
check. Conduct a calibration and linearity check after
assembling the analysis system and after a major change is made
to the system.
5.2 Systems Drift Checks. Select the calibration gas that most
closely approximates the concentration of the diluted captured
01140-0727

321
emissions for conducting the drift checks. Introduce the zero
and calibration gas at the calibration valve assembly and verify
that the appropriate gas flow rate and pressure are present at
the FIA. Record the measurement system responses to the zero and
calibration gases. The performance of the system is acceptable
if the difference between the drift check measurement and the
value obtained in Section 5.1 is less than 3 percent of the span
value. Conduct the system drift check at the end of each run.
5.3 Determination of Dilution Factor. Inject the dilution check
gas into the measurement system before the dilution system and
record the response. Calculate the dilution factor using
Equation 3.
5.4 System Check. Inject the high range calibration gas at the
inlet to the sampling probe while the dilution air is turned off.
Record the response. The performance of the system is acceptable
if the measurement system response is within 5 percent of the
value obtained in Section 5.1 for the high range calibration gas.
Conduct a system check before and after each test run.
5.5 Analysis Audit. Immediately before each test analyze an
audit cylinder as described in Section 5.2. The analysis audit
must agree with the audit cylinder concentration within 10
percent.
6. NOMENCLATURE
A~
=
area of NDO i, ft2~j
AN
=
total area of all NDO’s in the enclosure, ft2--j
CA
=
actual concentration of the dilution check gas,
ppm propane-~
C3~
=
corrected average VOG~concentration of background
emissions at point i, ppm propane-~
CB
=
average background concentration, ppm propane--;
CDH
average measured concentration for the drift check
calibration gas, ppm propane--j
CD0
=
average system drift check concentration for zero
concentration
gas, ppm propane--j
=
actual concentration of the drift check
calibration gas, ppm propane--j
C~
=
uncorrected average background VOG~concentration
measured at point i, ppm propane--;
01140-0728

322
C~
=
uncorrected average VOG?J concentration measured at
point j, ppm propane-a
CM
=
measured concentration of the dilution check gas,
ppm propane--j
DF
=
dilution factor-~
G
=
total VOC~content of captured emissions, kq~-j.
K1
=
1.830 x 106 kg/(m3-ppm)--~.
n
=
number of measurement points--i.
Q0~
=
average effluent volumetric flow rate corrected to
standard conditions at captured emissions point j,
m3 /min--i.
Tc
=
total duration of capture efficiency sampling run,
mm.
7. CALCULATIONS
7.1 Total VOG~1 Captured Emissions.
n
G
=
E CGj ~Gj Tc K1
Eq. 1
7.2 VOG~JConcentration of the Captured Emissions at Point j.
CGj
=
DF (C~
CD0)
CR
Eq. 2
CDH
CD0
7.3 Dilution Factor.
=
CA
Eq. ~
CM
7.4 Background VO?~Concentration at Point i.
C31
=
(C1
C50)
CR
Eq. 4
7.5 Average Background Concentration.CDH
C50
n
E C3~A~
C3
=
i=1
Eq. 5
nAN
01140-0729

323
NOTE: If the concentration at each point is within 20 percent of
the average concentration of all points, the terms ~A1t1and “AN”
may be deleted from Equation 4.
Procedure F.2
-
Fugitive VOGM Emissions from Building Enclosures
1. INTRODUCTION
1.1 Applicability. This procedure is applicable for determining
the fugitive volatile organic compoundomaterials (VOGIj) emissions
from a building enclosure (BE). It is intended to be used as a
segment in the development of liquid/gas or gas/gas protocols for
determining VOG~jcapture efficiency (CE) for surface coating and
printing operations.
1.2 Principle. The total amount of fugitive VOG~emissions (FB)
from the BE is calculated as the sum of the products of the VOGM
content (CF~) of each fugitive emissions point, its flow rate
(QF~)’ and ~ime (TF).
1.3 Measurement Uncertainty. The measurement uncertainties are
estimated for each fugitive emissions point as follows:
=
±5.0percent and CFj
=
±5.0percent. Based on these numbers, the
probable uncertainty for F3 is estimated at about ±11.2percent.
1.4 Sampling Requirements. A capture efficiency test shall
consist of at least -three sampling runs. The sampling time for
each run should be at least 8 hours, unless otherwise approved.
1.5 Notes. Because this procedure is often applied in highly
explosive areas, caution and care should be exercised in choosing
appropriate equipment and installing and using the equipment.
Mention of trade names or company products does not constitute
endorsement. All gas concentrations (percent, ppm) are by
volume, unless otherwise noted.
2. APPARATUS AND REAGENTS
2.1 Gas VOG~Concentration. A schematic of the measurement
system is shown in Figure 1. The main components are described
below:
-
2.1.1 Sample Probe. Stainless steel, or equivalent. The probe
shall be heated to prevent VOG~condensation.
2.1.2 Calibration Valve Assembly. Three-way valve assembly at
the outlet of sample probe to direct the zero and calibration
gases to the analyzer. Other methods, such as quick—connect
lines, to route calibration gases to the outlet of the sample
probe are acceptable.
2.1.3 Sample Line. Stainless steel or Teflon tubing to
01140-0730

324
transport the sample gas to the analyzer. The sample line must
be heated to prevent condensation.
2.1.4 Sample Pump. A leak-free pump, to pull the sample gas
through the system at a flow rate sufficient to minimize the
response time of the measurement system. The components of the
pump that contact the gas stream shall be constructed of
stainless steel or Teflon. The sample pump must be heated to
prevent condensation.
2.1.5 Sample Flow Rate Control. A sample flow rate control
valve and rotameter, or equivalent, to maintain a constant
sampling rate within 10 percent. The flow rate control valve and
rotameter must be heated to prevent condensation. A control
valve may also be located on the sample pump bypass loop to
assist in controlling the sample pressure and flow rate.
2.1.6 Sample Gas Manifold. Capable of diverting a portion of
the sample gas stream to the flame ionization analyzer (FIA), and
the remainder to the bypass discharge vent. The manifold
components shall be constructed of stainless steel or Teflon. If
emissions are to be measured at multiple locations, the
measurement system shall be designed to use separate sampling
probes, lines, and pumps for each measurement location and a
common sample gas manifold and FIA. The sample gas manifold must
be heated to prevent condensation.
2.1.7 Organic Concentration Analyzer. An FIA with a span value
of 1.5 times the expected concentration as propane; however,
other span values may be used if it can be demonstrated that they
would provide more accurate measurements. The system shall be
capable of meeting or exceeding the following specifications:
2.1.7.1 Zero Drift. Less than ±3.0percent of the span value.
2.1.7.2 Calibration Drift. Less than ±3.0percent of the span
value.
2.1.7.3 Calibration Error. Less than ±5.0percent of the
calibration gas value.
2.1.7.4 Response Time. Less than 30 seconds.
2.1.8 Integrator/Data Acquisition System. An analog or digital
device or computerized data acquisition system used to integrate
the FIA response or compute the average response and record
measurement data. The minimum data sampling frequency for
computing average or inteqrated values is one measurement value
every 5 seconds. The device shall be capable of recording
average values at least once per minute.
2.1.9 Calibration and Other Gases. Gases used for calibration,
01140-0731

325
fuel, and combustion air (if required) are contained in
compressed gas cylinders. All calibration gases shall be
traceable to NIST standards and shall be certified by the
manufacturer to ±1percent of the tag value. Additionally, the
manufacturer of the cylinder should provide a recommended shelf
life for each calibration gas cylinder over which the
concentration does not change more than ±2percent from the
certified value. For calibration gas values not generally
available, alternative methods £ or preparing calibration gas
mixtures, such as dilution systems, may be used with prior
approval.
2.1.9.1 Fuel. A 40 percent 112/60 percent He or 40 percent 112/60
percent N2 gas mixture is recommended to avoid an oxygen
synergism effect that reportedly occurs when oxygen concentration
varies significantly from a mean value.
2.1.9.2 Carrier Gas. High purity air with less than 1 ppm of
organic material (propane or carbon equivalent) or less than 0.1
percent of the span value, whichever is greater.
2.1.9.3 FIA Linearity Calibration Gases. Low-, mid-, and
high—range gas mixture standards with nominal propane
concentrations of 20—30, 45-55, and 70-80 percent of the span
value in air, respectively. Other calibration values and other
span values may be used if it can be shown that more accurate
measurements would be achieved.
2.1.10 Particulate Filter. An in—stack or an out-of-stack glass
fiber filter is recommended if exhaust gas particulate loading is
significant. An out-of-stack filter must be heated to prevent
any condensation unless it can be demonstrated that no
condensation occurs.
2.2 Fugitive Emissions Volumetric Flow Rate.
2.2.1 Flow Direction Indicators. Any means of indicating inward
or outward flow, such as light plastic film or paper streamers,
smoke tubes, filaments, and sensory perception.
2.2.2 Method 2 or 2A Apparatus. For determining volumetric flow
rate. Anemometers or similar devices calibrated according to the
manufacturer’s instructions may be used when low velocities are
present. Vane anemometers (Young—maximum response propeller),
specialized pitots with electronic manometers (e.g., Shortridqe
Instruments Inc., Airdata Nultimeter 860) are commercially
available with measurement thresholds of 15 and 8 mpm (50 and
25 fpm), respectively.
2.2.3 Method 3 Apparatus and Reagents. For determining
molecular weight of the gas stream. An estimate of the molecular
weight of the gas stream may be used if it can be justified.
01140-0732

326
2.2.4 Method 4 Apparatus and Reagents. For determining moisture
content, if necessary.
3. DETERMINATION OF VOLUMETRIC FLOW RATE OF FUGITIVE EMISSIONS
31 Preliminary Determinations. The purpose of this exercise is
to determine
which exhaust points should be measured for volumetric flow rates
and VOGM concentrations.
-3.1.1 Forced Draft Openings. Identify all forced draft
openings. Determine the volumetric flow rate according to Method
2.
3.1.2 NDO’s Exhaust Points. The NDO’s in the roof of a facility
the building or room in which the emission unit is located are
considered to be exhaust points. Determine volumetric flow rate
from these NDO’s. Divide the cross—sectional area according to
Method 1 using 12 equal areas. Use the appropriate velocity
measurement devices, e.g., propeller anemometers.
3.1.3 Other NDO’s.
3.1.3.1 This step is optional. Determine the exhaust flow rate,
including that of the control device, from the enclosure and the
intake air flow rate. If the exhaust flow rate divided by the
intake air flow rate is greater than 1.1, then all other NDO’s
are not considered to be significant exhaust points.
3.1.3.2 If the option above is not taken, identify all other
NDO’s and other potential points through which fugitive emissions
may escape the enclosure. Then use the following criteria to
determine whether flow rates and VO~jconcentrations need to be
measured:
3.1.3.2.1 Using the appropriate flow direction indicator,
determine the flow direction. An NDO with zero or inward flow is
not an exhaust point.
3.1.3.2.2 Measure the outward volumetric flow rate from the
remainder of the NDO’s. If the collective flow rate is 2
percent, or less, of the flow rate from Sections 3.1.1 and 3.1.2,
then these NDO’s, except those within two equivalent diameters
(based on NDO opening) from
.~,
VOG~sourcc~emittingpoint, may be
considered to be non—exhaust points.
3.1.3.2.3 If the percentage calculated in Section 3.1.3.2.2 is
greater than 2 percent, those NDO’s (except those within two
equivalent diameters from a VOGM -sourcc~emjttingpoint) whose
volumetric flow rate total 2 percent of the flow rate from
Sections 3.1.1 and 3.1.2 may be considered as non—exhaust points.
All remaining NDO’s shall be measured for volumetric flow rate
01140-0733

327
and
VOG~concentrations during the CE test.
3.1.3.2.4 The tester may choose to measure VOGI~j concentrations
at the forced exhaust points and the NDO’s. If the total VOGIj
emissions from the NDO’s are less than 2 percent of the emissions
from the forced draft and roof NDO’s, then these NDO’s may be
eliminated from further consideration.
3.2 Determination of Flow Rates.
3.2.1 Measure the volumetric flow rate at all locations
identified as exhaust points in Section 3.1. Divide each exhaust
opening into 9 equal areas for rectangular openings and 8 for
circular openings.
3.2.2 Measure the velocity at each site at least once every hour
during each sampling run using Method 2 or 2A, if applicable, or
using the low velocity instruments in Section 2.2.2.
4. DETERMINATION OF VOGM CONTENT OF FUGITIVE EMISSIONS
4.1 Analysis Duration. Measure the VOG~responses at each
fuqitive emission point during the entire test run or, if
applicable, while the process is operating. If there are
multiple emissions locations, design a sampling system to allow a
single FIA to be used to determine the VOG~responses at all
sampling locations.
4.2 Gas VOG~Concentration.
4.2.1 Assemble the sample train as shown in Figure 1. Calibrate
the FIA and conduct a system check according to the procedures in
Sections 5.1 and 5.3, respectively.
4.2.2 Install the sample probe so that the probe is centrally
located in the stack, pipe, or duct, and is sealed tightly at the
stack port connection.
4.2.3 Inject zero gas at the calibration valve assembly. Allow
the measurement system response to reach zero. Measure the
system response time as the time required for the system to reach
the effluent concentration after the calibration valve has been
returned to the effluent sampling position.
4.2.4 Conduct a system check before and a system drift check
after each sampling run according to the procedures in Sections
5.2 and 5.3. If the drift check following a run indicates
unacceptable performance, the run is not valid. The tester may
elect to perform drift checks during the run not to exceed one
drift check per hour.
01140-07314

328
4.2.5 Verify that the sample lines, filter, and pump
temperatures are 120 ±5°C.
4.2.6 Begin sampling at the start of the test period and
continue to sample during the entire run. Record the starting
and ending times and any required process information as
appropriate. If multiple emission locations are sampled using a
single FIA, sample at each location for the same amount of time
(e.g., 2 minutes) and continue to switch from one location to
another for the entire test run. Be sure that total sampling
time at each location is the same at the end of the test run.
Collect at least 4 separate measurements from each sample point
during each hour of testing. Disregard the response measurements
at each sampling location until two times the response time of
the measurement system has elapsed. Continue sampling for at
least 1 minute and record the concentration measurements.
4.3 Alternative Procedure The direct interface sampling and
analysis procedure described in Section 7.2 of Method 18 may be
used to determine the gas VO?~concentration. The system must be
designed to collect and analyze at least one sample every 10
minutes.
5. CALIBRATION AND QUALITY ASSURANCE
-
5.1 FIA Calibration and Linearity Check. Make necessary
adjustments to the air and fuel supplies for the FIA and ignite
the burner. Allow the FIA to warm up for the period recommended
by the manufacturer. Inject a calibration gas into the
measurement system and adjust the back—pressure regulator to the
value required to achieve the flow rates specified by the
manufacturer. Inject the zero— and the high—range calibration
gases and adjust the analyzer calibration to provide the proper
responses. Inject the low— and mid—range gases and record the
responses of the measurement system. The calibration and
linearity of the system are acceptable if the responses for all
four gases are within 5 percent of the respective gas values. If
the performance of the system is not acceptable, repair or adjust
the system and repeat the linearity check. Conduct a calibration
and linearity check after assembling the analysis system and
after a major change is made to the system.
5.2 Systems Drift Checks. Select the calibration gas that most
closely approximates the concentration of the captured emissions
for conducting the drift checks. Introduce the zero and
calibration gas at the calibration valve assembly and verify that
the appropriate gas flow rate and pressure are present at the
FIA. Record the measurement system responses to the zero and
calibration gases. The performance of the system is acceptable
if the difference between the drift check measurement and the
value obtained in Section 5.1 is less than 3 percent of the span
value. Conduct a system drift check at the end of each run.
01140-0735

329
5.3 System Check. Inject the high range calibration gas at the
inlet of the sampling probe and record the response. The
performance of the system is acceptable if the measurement system
response is within 5 percent of the value obtained in Section 5.1
for the high range calibration gas. Conduct a system check
before each test run.
5.4 Analysis Audit. Immediately before each test analyze an
audit cylinder as described in Section 5.2. The analysis audit
must agree with the audit cylinder concentration within 10
percent.
6. NOMENCLATURE
CDH
=
average measured concentration for the drift check
calibration gas, ppm propane--j
CDO
=
average system drift check concentration for zero
concentration gas, ppm propane--i
CFj
=
corrected average VOGM concentration of fugitive
emissions at point j, ppm propane-~j
CR
=
actual concentration of the drift check
calibration gas, ppm propane-a-;
C~
=
uncorrected average VOG~concentration measured at
point j, ppm propane--j~
FB
=
total VOGM content of fugitive emissions from the
building, k~-~j
K1
=
1.830 x l0 kg/(m3-ppm)-~
n
=
number of measurement points-~j
QFj
=
average effluent volumetric flow rate corrected to
standard conditions at fugitive emissions point j,
m3
/
min--;
TF
=
total duration of capture efficiency sampling run,
mm.
7. CALCULATIONS
7.1 Total VOGN Fugitive Emissions From the Building.
n
F8
=
&
CFj QF~ Tp K1
Eq. 1
j=1
7.2 VOQM Concentration of the Fugitive Emissions at Point j.
01140-0736

330
CFj
=
(C~ - C50)
C5
Eq. 2
Procedure F.1 — Fugitive VOG~CDH
EmissionsC50
from Temporary Enclosures
1. INTRODUCTION
1.1 Applicability. This procedure is applicable for determining
the fugitive volatile organic compounthimaterials (VOG~) emissions
from a temporary total enclosure (TTE). It is intended to be
used as a segment in the development of liquid/gas or gas/gas
protocols for determining VOG~Jcapture efficiency (CE) for
surface coating and printing operations.
1.2 Principle. The amount of fugitive VOGt~Iemissions (F) from
the TTE is calculated as the sum of the products of the VOG~
content (CFj), the flow rate (QFj)’ and the sampling time (TF)
from each fugitive emissions point.
1.3 Estimated Measurement Uncertainty. The measurement
uncertainties are estimated for each fugitive emission point
as follows:
=
±5.5percent and CF~
=
±5.0percent. Based on
these numbers, the probable uncertainty for F is estimated at
about ±7.4percent.
1.4 Sampling Requirements. A capture efficiency test shall
consist of at least three sampling runs. The sampling time for
each run should be at least 8 hours, unless otherwise approved.
1.5 Notes. Because this procedure is often applied in highly
explosive areas, caution and care should be exercised in choosing
appropriate equipment and installing and using the equipment.
Mention of trade names or company products does not constitute
endorsement. All gas concentrations (percent, ppm) are by
volume, unless otherwise noted.
2. APPARATUS AND REAGENTS
2.1 Gas VOGH Concentration. A schematic of the measurement
system is shown in Figure 1. The main components are described
below:
2.1.1 Sample Probe. Stainless steel, or equivalent. The probe
shall be heated to prevent VOGIj condensation.
2.1.2 Calibration Valve Assembly. Three—way valve assembly at
the outlet of sample probe to direct the zero and calibration
gases to the analyzer. Other methods, such as quick—connect
lines, to route calibration gases to the outlet of the sample
probe are acceptable.
2.1.3 Sample Line. Stainless steel or Teflon tubing to
01140-0737

331
transport the sample gas to the analyzer. The sample line must
be heated to prevent condensation.
2.1.4 Sample Pump. A leak—free pump, to pull the sample gas
through the system at a flow rate sufficient to minimize the
response time of the measurement system. The components of the
pump that contact the gas stream shall be constructed of
stainless steel or Teflon. The sample pump must be heated to
prevent condensation.
2.1.5 Sample Flow Rate Control. A sample flow rate control
valve and rotameter, or equivalent, to maintain a constant
sampling rate within 10 percent. The flow control valve and
rotameter must be heated to prevent condensation. A control
valve may also be located on the sample pump bypass loop to
assist in controlling the sample pressure and flow rate.
2.1.6 Sample Gas Manifold. Capable of diverting a portion of
the sample gas stream to the flame ionization analyzer (FIA), and
the remainder to the bypass discharge vent. The manifold
components shall be constructed of stainless steel or Teflon. If
emissions are to be measured at multiple locations, the
measurement system shall be designed to use separate sampling
probes, lines, and pumps for each measurement location and a
common sample gas manifold and FIA. The sample gas manifold and
connecting lines to the FIA must be heated to prevent
condensation.
2.1.7 Organic Concentration Analyzer. An FIA with a span value
of 1.5 times the expected concentration as propane; however,
other span values may be used if it can be demonstrated that they
would provide more accurate measurements. The system shall be
capable of meeting or exceeding the following specifications:
2.1.7.1 Zero Drift. Less than ±3.0percent of the span value.
2.1.7.2 Calibration Drift. Less than ±3.0percent of the span
value.
2.1.7.3 Calibration Error. Less than ±5.0percent of the
calibration gas value.
2.1.7.4 Response Time. Less than 30 seconds.
2.1.8 Integrator/Data Acquisition System. An analog or digital
device or ‘computerized data acquisition system used to integrate
the FIA response or compute the average response and record
measurement data. The minimum data sampling frequency for
computing average or integrated values is one measurement value
every 5 seconds. The device shall be capable of recording
average values at least once per minute.
UI ~0-0738

332
2.1.9 Calibration and Other Gases. Gases used for calibration,
fuel, and combustion air (if required) are contained in
compressed gas cylinders. All calibration gases shall be
traceable to NIST standards and shall be certified by the
manufacturer to ±1percent of the tag value. Additionally, the
manufacturer of the cylinder should provide a recommended shelf
life for each calibration gas cylinder over which the
concentration does not change more than ±2 percent from the
certified value. For calibration gas values not generally
available, alternative methods for preparing calibration gas
mixtures, such as dilution systems, may be used with prior
approval.
2,1.9.1 Fuel. A 40 percent H2/60 percent He or 40 percent H2/60
percent N2 gas mixture is recommended to avoid an oxygen
synergism effect that reportedly occurs when oxygen concentration
varies significantly from a mean value.
2.1.9.2 Carrier Gas. High purity air with less than 1 ppm of
organic material (as propane or carbon equivalent) or less than
0.1 percent of the span value, whichever is greater.
2.1.9.3 FIA Linearity Calibration Gases. Low—, mid-, and
high—range gas mixture standards with nominal propane
concentrations of 20-30, 45-55, and 70-80 percent of the span
value in air, respectively. Other calibration values and other
span values may be used if it can be shown that more accurate
measurements would be achieved.
2.1.10 Particulate Filter. An in—stack or an out-of-stack glass
fiber filter is recommended if exhaust gas particulate loading is
significant. An out-of-stack filter must be heated to prevent
any condensation unless it can be demonstrated that no
condensation occurs.
2.2 Fugitive Emissions Volumetric Flow Rate.
2.2.1 Method 2 or 2A Apparatus. For determining volumetric flow
rate.
2.2.2 Method 3 Apparatus and Reagents. For determining
molecular weight of the gas stream. An estimate of the molecular
weight of the gas stream may be used if it can be justified.
2.2.3 Method 4 Apparatus and Reagents. For determining moisture
content, if necessary.
2.3 Temporary Total Enclosure. The criteria for designing a TTE
are discussed in Procedure T.
3. DETERMINATION OF VOLUMETRIC FLOW RATE OF FUGITIVE ENISSIONS
01140-0739

333
3.1 Locate all points where emissions are exhausted from the
TTE. Using Method 1, determine the sampling points. Be sure to
check each site for cyclonic or swirling flow.
3.2 Measure the velocity at each sampling site at least once
every hour during each sampling run using Method 2 or 2A.
4. DETERMINATION OF VOG?J CONTENT OF FUGITIVE EMISSIONS
4.1 Analysis Duration. Measure the VOGM responses at each
fugitive emission point during the entire test run or, if
applicable, while the process is operating. If there are
multiple emission locations, design a sampling system to allow a
single FIA to be used to determine the VOGM responses at all
sampling locations.
4.2 Gas VOG~Concentration.
4.2.1 Assemble the sample train as shown in Figure 1. Calibrate
the FIA and conduct a system check according to the procedures in
Sections 5.1 and 5.3, respectively.
4.2.2 Install the sample probe so that the probe is centrally
located in the stack, pipe, or duct, and is sealed tightly at the
stack port connection.
4.2.3 Inject zero gas at the calibration valve assembly. Allow
the measurement system response to reach zero. Measure the
system response time as the time required for the system to reach
the effluent concentration after the calibration valve has been
returned to the effluent sampling position.
4.2.4 Conduct a system check before and a system drift check
after each sampling run according to the procedures in Sections
5.2 and 5.3. If the drift check following a run indicates
unacceptable performance, the run is not valid. The tester may
elect to perform system drift checks during the run not to exceed
one drift check per hour.
4.2.5 Verify that the sample lines, filter, and pump
temperatures are 120 ±5°C.
4.2.6 Begin sampling at the start of the test period and
continue to sample during the entire run. Record the starting
and ending times and any required process information as
appropriate. If multiple emission locations are sampled using a
single FIA, sample at each location for the same amount of time
(e.g., 2 minutes) and continue to switch from one location to
another for the entire test run. Be sure that total sampling
time at each location is the same at the end of the test run.
Collect at least 4 separate measurements from each sample point
during each hour of testing. Disregard the response measurements
01140-07140

334
at each sampling location until two times the response time of
the measurement system has elapsed. Continue sampling for at
least 1 minute and record the concentration measurements.
4.3 Background Concentration.
4.3.1 Determination of VOG~Background Concentration.
4.3.1.1 Locate all NDO’s of the TTE. A sampling point shall be
centrally located outside of the TTE at 4 equivalent diameters
from each NDO, if possible. If there are more than 6 NDO’s,
choose 6 sampling points evenly spaced among the NDO’s.
4.3.1.2 Assemble the sample train as shown in Figure 2.
Calibrate the FIA and conduct a system check according to the
procedures in Sections 5.1 and 5.3.
4.3.1.3 Position the probe at the sampling location.
4.3.1.4 Determine the response time, conduct the system check
and sample according to the procedures described in Sections
4.2.3 to 4.2.6.
4.4 Alternative Procedure. The direct interface sampling and
analysis procedure described in Section 7.2 of Method 18 may be
used to determine the gas VOG~ concentration. The system must be
designed to collect and analyze at least one sample every 10
minutes.
5. CALIBRATION AND QUALITY ASSURANCE
5.1 FIA Calibration and Linearity Check. Make necessary
adjustments to the air and fuel supplies for the FIA and ignite
the burner. Allow the FIA to warm up for the period recommended
by the manufacturer. Inject a calibration gas into the
measurement system and adjust the back—pressure regulator to the
value required to achieve the flow rates specified by the
manufacturer. Inject the zero- and the high-range calibration
gases and adjust the analyzer calibration to provide the proper
responses. Inject the low— and mid—range gases and record the
responses of the measurement system. The calibration and
linearity of the system are acceptable if the responses for all
four gases are within 5 percent of the respective gas values. If
the performance of the system is not acceptable, repair or adjust
the system and repeat the linearity check. Conduct a calibration
and linearity check after assembling the analysis system and
after a major change is made to the system.
5.2 Systems Drift Checks. Select the calibration gas
concentration that most closely approximates that of the fugitive
gas emissions to conduct the drift checks. Introduce the zero
and calibration gas at the calibration valve assembly and verify
01140-07141

335
that the appropriate gas flow rate and pressure are present at
the FIA. Record the measurement system responses to the zero and
calibration gases. The performance of the system is acceptable
if the difference between the drift check measurement and the
value obtained in Section 5.1 is less than 3 percent of the span
value. Conduct a system drift check at the end of each run.
5.3 System Check. Inject the high range calibration gas at the
inlet of the sampling probe and record the response. The
performance of the system is acceptable if the measurement system
response is within 5 percent of the value obtained in Section 5.1
for the high range calibration gas. Conduct a system check
before each test run.
5.4 Analysis Audit. Immediately before each test analyze an
audit cylinder as described in Section 5.2. The analysis audit
must agree with the audit cylinder concentration within 10
percent.
6. NOMENCLATURE
A1
=
area of NDO i, ft2,-~
AN
=
total area of all NDO’s in the enclosure, ft2--L
C31
=
corrected average VOGM concentration of background
emissions at point i, ppm propane.j
CB
=
average background concentration, ppm propane--;
CDH
=
average measured concentration for the drift check
calibration
gas, ppm propane-~
CD0
=
average system drift check concentration for zero
concentration gas, ppm propane--;
CFj
=
corrected average VOG~concentration of fugitive
emissions at point j, ppm propane--;
C5
=
actual concentration of the drift check
calibration gas, ppm propane--.:
C1
=
uncorrected average background VOG~concentration
measured at point i, ppm propane-~j
C~
=
uncorrected average VOG~ concentration measured at
point j, ppm propane-ri
G
=
total VOGM content of captured emissions, kg-~
K1
=
1.830 X l0~ kg/(m3—ppm)--~.
01140-07142

336
n
=
number of measurement points--j.
=
average effluent volumetric flow rate corrected to
standard
conditions at fugitive emissions point j, m3/min--j.
TF
=
total duration of fugitive emissions sampling run,
mm.
7. CALCULATIONS
7.1 Total VOG~Fugitive Emissions.
n
F
=
E
(CFj
CB
)
QF~ T~K1 Eq. 1
j=l
7.2 VOG~Concentration of the Fugitive Emissions at Point j.
CFj
=
(C~
C50)
Eq. 2
7.3 Background VOGM ConcentrationC55
— C50
at Point i.
C3~
=
(C1
C50)
C5
Eq. 3
7.4 Average Background Concentration.C55
— C50
n
2 CBIAI
C3i1
Eq. 5
NOTE: If the concentration at each point is within 20 percent of
the average concentration of all points, the terms “At” and “AN”
may be deleted from Equation 4.
Procedure L
-
VOG~Input
1. INTRODUCTION
1.1 Applicability. This procedure is applicable for determining
the input of volatile organic Qompound~materials (VOG~fl. It is
intended to be used as a segment in the development of liquid/gas
protocols for determining VOG~Icapture efficiency (CE) for
surface coating and printing operations.
1.2 Principle. The amount of VOG~ introduced to the process
(L) is the sum of the products of the weight (W) of each VOGM
containing liquid (ink, paint, solvent, etc.) used and its VOG~
content (V). A sample of each VOG~jcontaining liquid is analyzed
01140-07143

337
with a flame ionization analyzer (FIA) to determine V.
1.3 Estimated Measurement Uncertainty. The measurement
uncertainties are estimated for each VO~jcontaining liquid as
follows: W
=
2.0 percent and V
=
±12.0percent. Based on these
numbers, the probable uncertainty for L is estimated at about
±12.2percent for each VO~Jcontaining liquid.
1.4 Sampling Requirements. A capture efficiency test shall
consist of at least three sampling runs. The sampling time for
each run should be at least 8 hours, unless otherwise approved.
1.5 Notes. Because this procedure is often applied in highly
explosive areas, caution and care should be exercised in choosing
appropriate equipment and installing and using the equipment.
Mention of trade names or company products does not constitute
endorsement. All gas concentrations (percent, ppm) are by
volume, unless otherwise noted.
2. APPARATUS AND REAGENTS
2.1 Liquid Weight.
2.1.1 Balances/Digital Scales. To weigh drums of VO~’J
containing liquids to within 0.2 lb.
2.1.2 Volume Measurement Apparatus (Alternative). Volume
meters, flow meters, density measurement equipment, etc., as
needed to achieve same accuracy as direct weight measurements.
2.2 VO~IjContent (Flame Ionization Analyzer Technique). The
liquid sample analysis system is shown in Figures 1 and 2. The
following equipment is required:
2.2.1 Sample Collection Can. An appropriately sized metal can
to be used to collect VO~ containing materials. The can must be
constructed in such a way that it can be grounded to the coating
container.
2.2.2 Needle Valves. To control gas flow.
2.2.3 Regulators. For carrier gas and calibration gas
cylinders.
2.2.4 Tubing. Teflon or stainless steel tubing with diameters
and lengths determined by connection requirements of equipment.
The tubing between the sample oven outlet and the FIA shall be
heated to maintain a temperature of 120 ±5°C.
2.2.5 Atmospheric Vent. A tee and 0- to 0.5-liter/mm rotameter
placed in the sampling line between the carrier gas cylinder and
the VOGM sample vessel to release the excess carrier gas. A
Øt140-07~414

338
toggle valve placed between the tee and the rotameter facilitates
leak tests of the analysis system.
2.2.6 Thermometer. Capable of measuring the temperature of the
hot water bath to within 1°C.
2.2.7 Sample Oven. Heated enclosure, containing calibration gas
coil heaters, critical orifice, aspirator, and other liquid
sample analysis components, capable of maintaining a temperature
of 120 ±5°C.
2.2.8 Gas Coil Heaters. Sufficient lengths of stainless steel
or Teflon tubing to allow zero and calibration gases to be heated
to the sample oven temperature before entering the critical
orifice or aspirator.
2.2.9 Water Bath. Capable of heating and maintaining a sample
vessel temperature of 100 ±5°C.
2.2.10 Analytical Balance. To measure ±0.001g.
2.2.11 Disposable Syringes. 2-cc or 5—cc.
2.2.12 Sample Vessel. Glass, 40-ml septum vial. A separate
vessel is needed for each sample.
2.2.13 Rubber Stopper. Two-hole stopper to accommodate 3.2-mm
(1/8-in.) Teflon tubing, appropriately sized to fit the opening
of the sample vessel. The rubber stopper should be wrapped in
Teflon tape to provide a tighter seal and to prevent any reaction
of the sample with the rubber stopper. Alternatively, any
leak—free closure fabricated of non—reactive materials and
accommodating the necessary tubing fittings may be used.
2.2.14 Critical Orifices. Calibrated critical orifices capable
of providing constant flow rates from 50 to 250 ml/min at known
pressure drops. Sapphire orifice assemblies (available from
O’Keefe Controls Company) and glass capillary tubing have been
found to be adequate for this application.
2.2.15 Vacuum Gauge. 0- to 760-mm (0- to 30-in.) Hg U-Tube
manometer or vacuum gauge.
2.2.16 Pressure Gauge. Bourdon gauge capable of measuring the
maximum air pressure at the aspirator inlet (e.g., 100 psig).
2.2.17 Aspirator. A device capable of generating sufficient
vacuum at the sample vessel to create critical flow through the
calibrated orifice when sufficient air pressure is present at the
aspirator inlet. The aspirator must also provide sufficient
sample pressure to operate the FIA. The sample is also mixed
with the dilution gas within the aspirator.
01140-07145

339
2.2.18 Soap Bubble Meter. Of an appropriate size to calibrate
the critical orifices in the system.
2.2.19 Organic Concentration Analyzer. An FIA with a span value
of 1.5 times the expected concentration as propane; however other
span values may be used if it can be demonstrated that they would
provide more accurate measurements. The system shall be capable
of meeting or exceeding the following specifications:
2.2.19.1 Zero Drift. Less than ±3.0percent of the span value.
2.2.19.2 Calibration Drift. Less than ±3.0percent of span
value.
2.2.19.3 Calibration Error. Less than ±5.0percent of the
calibration gas value.
2.2.20 Integrator/Data Acquisition System. An analog or digital
device or computerized data acquisition system used to integrate
the FIA response or compute the average response and record
measurement data. The minimum data sampling frequency for
computing average or integrated values is one measurement value
every 5 seconds. The device shall be capable of recording
average values at least once per minute.
2.2.21 Chart Recorder (Optional). A chart recorder or similar
device is recommended to provide a continuous analog display of
the measurement results during the liquid sample analysis.
2.2.22 Calibration and Other Gases. For calibration, fuel, and
combustion air (if required) contained in compressed gas
cylinders. All calibration gases shall be traceable to NIST
standards and shall be certified by the manufacturer to ±1
percent of the tag value. Additionally, the manufacturer of the
cylinder should provide a recommended shelf life for each
calibration gas cylinder over which the concentration does not
change more than ±2 percent from the certified value. For
calibration gas values not generally available, alternative
methods for preparing calibration gas mixtures, such as dilution
systems, may be used with prior approval.
2.2.22.1 Fuel. A 40 percent H2/60 percent He or 40 percent
H2/60 percent N2 gas mixture is recommended to avoid an oxygen
synergism effect that reportedly occurs when oxygen concentration
varies significantly from a mean value.
2.2.22.2 Carrier Gas. High purity air with less than 1 ppm of
organic material (as propane) or less than 0.1 percent of the
span value, whichever is greater.
2.2.22.3 FIA Linearity Calibration Gases. Low-, mid—, and
high—range gas mixture standards with nominal propane
01140-07146

340
concentrations of 20-30, 45-55, and 70-80 percent of the span
value in air, respectively. Other calibration values and other
span values may be used if it can be shown that more accurate
measurements would be achieved.
2.2.22.4 System Calibration Gas. Gas mixture standard
containing propane in air, approximating the undiluted VO~J
concentration expected for the liquid samples.
3. DETERMINATION OF LIQUID INPUT WEIGHT
3.1 Weight Difference. Determine the amount of material
introduced to the process as the weight difference of the feed
material before and after each sampling run. In determining the
total VOG~jcontaining liquid usage, account for: (a) the initial
(beginning) VO~ containing liquid mixture; (b) any solvent added
during the test run; (c) any coating added during the test run;
and (d) any residual VO~jcontaining liquid mixture remaining at
the end of the sample run.
3.1.1 Identify all points where VO~I’j containing liquids are
introduced to the process. To obtain an accurate measurement of
VOGM containing liquids, start with an empty fountain (if
applicable). After completing the run, drain the liquid in the
fountain back into the liquid drum (if possible), and weigh the
drum again. Weigh the VOG~containing liquids to ±0.5percent of
the total weight (full) or ±0.1percent of the total weight of
VOGN containing liquid used during the sample run, whichever is
less. If the residual liquid cannot be returned to the drum,
drain the fountain into a preweighed empty drum to determine the
final weight of the liquid.
3.1.2 If it is not possible to measure a single representative
mixture, then weigh the various components separately (e.g., if
solvent is added during the sampling run, weigh the solvent
before it is added to the mixture). If a fresh drum of VOGM
containing liquid is needed during the run, then weigh both the
empty drum and fresh drum.
3.2 Volume Measurement (Alternative). If direct weight
measurements are not feasible, the tester may use volume meters
and flow rate meters (and density measurements) to determine the
weight of liquids used if it can be demonstrated that the
technique produces results equivalent to the direct weight
measurements. If a single representative mixture cannot be
measured, measure the components separately.
4. DETERMINATION OF VOGN CONTENT IN INPUT LIQUIDS
4.1 Collection of Liquid Samples.
4.1.1 Collect a 100-ml or larger sample of the VOGM containing
01140-07147

341
liquid mixture at each application location at the beginning and
end of each test run. A separate sample should be taken of each
VOG~ containing liquid added to the application mixture during
the test run. If a fresh drum is needed during the sampling run,
then obtain a sample from the fresh drum.
4.1.2 When collecting the sample, ground the sample container to
the coating drum. Fill the sample container as close to the rim
as possible to minimize the amount of headspace.
4.1.3 After the sample is collected, seal the container so the
sample cannot leak out or evaporate.
4.1.4 Label the container to identify clearly the contents.
4.2 Liquid Sample VOG~Content.
4.2.1 Assemble the liquid VOG~content analysis system as shown
in Figure 1.
4.2.2 Permanently identify all of the critical orifices that may
be used. Calibrate each critical orifice under the expected
operating conditions (i.e., sample vacuum and temperature)
against a volume meter as described in Section 5.3.
4.2.3 Label and tare the sample vessels (including the stoppers
and caps) and the syringes.
4.2.4 Install an empty sample vessel and perform a leak test of
the system. Close the carrier gas valve and atmospheric vent and
evacuate the sample vessel to 250 mm (10 in.) Hg absolute or less
using the aspirator. Close the toggle valve at the inlet to the
aspirator and observe the vacuum for at least one minute. If
there is any change in the sample pressure, release the vacuum,
adjust or repair the apparatus as necessary and repeat the leak
test.
4.2.5 Perform the analyzer calibration and linearity checks
according to the procedure in Section 5.1. Record the responses
to each of the calibration gases and the back—pressure setting of
the FIA.
4.2.6 Establish the appropriate dilution ratio by adjusting the
aspirator air supply or substituting critical orifices. Operate
the aspirator at a vacuum of at least 25 mm (1 in.) Hg greater
than the vacuum necessary to achieve critical flow. Select the
dilution ratio so that the maximum response of the FIA to the
sample does not exceed the high—range calibration gas.
4.2.7 Perform system calibration checks at two levels by
introducing compressed gases at the inlet to the sample vessel
while the aspirator and dilution devices are operating. Perform
01140-07148

342
these checks using the carrier gas (zero concentration) and the
system calibration gas. If the response to the carrier gas
exceeds ±0.5percent of span, clean or repair the apparatus and
repeat the check. Adjust the dilution ratio as necessary to
achieve the correct response to the upscale check, but do not
adjust the analyzer calibration. Record the identification of
the orifice, aspirator air supply pressure, FIA back—pressure,
and the responses of the FIA to the carrier and system
calibration gases.
4.2.8 After completing the above checks, inject the system
calibration gas for approximately 10 minutes. Time the exact
duration of the gas injection using a stopwatch. Determine the
area under the FIA response curve and calculate the system
response factor based on the sample gas flow rate, gas
concentration, and the duration of the injection as compared to
the integrated response using Equations 2 and 3.
4.2.9 Verify that the sample oven and sample line temperatures
are 120 ±5°Cand that the water bath temperature is 100 ±5°C.
4.2.10 Fill a tared syringe with approximately 1 g of the VOQ~
containing liquid and weigh it. Transfer the liquid to a tared
sample vessel. Plug the sample vessel to minimize sample loss.
Weigh the sample vessel containing the liquid to determine the
amount of sample actually received. Also, as a quality control
check, weigh the empty syringe to determine the amount of
material delivered. The two coating sample weights should agree
within ±0.02g. If not, repeat the procedure until an acceptable
sample is obtained.
4.2.11 Connect the vessel to the analysis system. Adjust the
aspirator supply pressure to the correct value. Open the valve
on the carrier gas supply to the sample vessel and adjust it to
provide a slight excess flow to the atmospheric vent. As soon as
the initial response of the FIA begins to decrease, immerse the
sample vessel in the water bath. (Applying heat to the sample
vessel too soon may cause the FID response to exceed the
calibrated range of the instrument, and thus invalidate the
analysis.)
4.2.12 Continuously measure and record the response of the FIA
until all of the volatile material has been evaporated from the
sample and the instrument response has returned to the baseline
(i.e., response less than 0.5 percent of the span value).
Observe the aspirator supply pressure, FIA back-pressure,
atmospheric vent, and other system operating parameters during
the run; repeat the analysis procedure if any of these parameters
deviate from the values established during the system calibration
checks in Section 4.2.7. After each sample perform the drift
check described in Section 5.2. If the drift check results are
acceptable, calculate the VOGM content of the sample using the
01140-07149

343
equations in Section 7. Integrate the area under the FIA
response curve, or determine the average concentration response
and the duration of sample analysis.
5. CALIBRATION AND QUALITY ASSURANCE
5.1 FIA Calibration and Linearity Check. Make necessary
adjustments to the air and fuel supplies for the FIA and ignite
the burner. Allow the FIA to warm up for the period recommended
by the manufacturer. Inject a calibration gas into the
measurement system and adjust the back—pressure regulator to the
value required to achieve the flow rates specified by the
manufacturer. Inject the zero- and the high—range calibration
gases and adjust the analyzer calibration to provide the proper
responses. Inject the low— and mid—range gases and record the
responses of the measurement system. The calibration and
linearity of the system are acceptable if the responses for all
four gases are within 5 percent of the respective gas values. If
the performance of the system is not acceptable, repair or adjust
the system and repeat the linearity check. Conduct a calibration
and linearity check after assembling the analysis system and
after a major change is made to the system.
5.2 Systems Drift Checks. After each sample, repeat the system
calibration checks in Section 4.2.7 before any adjustments to the
FIA or measurement system are made. If the zero or calibration
drift exceeds ±3percent of the span value, discard the result
and repeat the analysis.
5.3 Critical Orifice Calibration.
5.3.1 Each critical orifice must be calibrated at the specific
operating conditions that it will be used. Therefore, assemble
all components of the liquid sample analysis system as shown in
Figure 3. A stopwatch is also required.
5.3.2 Turn on the sample oven, sample line, and water bath
heaters and allow the system to reach the proper operating
temperature. Adjust the aspirator to a vacuum of 380 mm (15 in.)
Hg vacuum. Measure the time required for one soap bubble to move
a known distance and record barometric pressure.
5.3.3 Repeat the calibration procedure at a vacuum of 406 mm (16
in.) Hg and at 25-mm (1-in.) Hg intervals until three consecutive
determinations provide the same flow rate. Calculate the
critical flow rate for the orifice in ml/min at standard
conditions. Record the vacuum necessary to achieve critical
flow.
6. NOMENCLATURE
AL
=
area under the response curve of the liquid
01140-0750

344
sample, area count-~-j..
A3
=
area under the response curve of the calibration
gas, area count-u.
C~
=
actual concentration of system calibration gas,
ppm propane--j
K
=
1.830 x l0~ g/(ml-ppm)~
L
=
total VOG~content of liquid input, kg-ri
ML
=
mass of liquid sample delivered to the sample
vessel, g-~-j
q
=
flow rate through critical orifice, ml/min-~.
RF
=
liquid analysis system response factor, g/area
count--i
=
total gas injection time for system calibration
gas during integrator calibration, min--j
VFj
=
final VOGN fraction of VOGN containing liquid
j-~-j
V1~
=
initial VOG~fraction of VOGM containing liquid
j~L
VAj
=
VOG~fraction of VOGN containing liquid j added
during the run--j~.
V
=
VOG~jfraction of liquid sample--i
=
weight of VOGN containing liquid j remaining at
end of the run, kg--j
W1~
=
weight of VOG~containing liquid j at beginning of
the run, kg--i
=
weight of VOGM containing liquid j added during
the run, kg.
7. CALCULATIONS
7.1 Total VOG~Content of the Input VOG~Containing Liquid.
n
nn
L
=
2 V1~W~
=
V~iWFj ± 2 VAj W~ R
Eq. 1
j=1
3=1
j=1
7.2 Liquid Sample Analysis System Response Factor for Systems
Using Integrators, Grams/Area Counts.
nt140-07S~

345
RF
=
~s ~ T3.j~
Eq. 2
As
7.3 VOG~Content of the Liquid Sample.
V
=
Eq. 3
ML
Procedure T
Criteria for and Verification of a Permanent or
Temporary Total Enclosure
1. INTRODUCTION
1.1 Applicability. This procedure is used to determine whether
a permanent or temporary enclosure meets the criteria of a total
enclosure.
1.2 Principle. An enclosure is evaluated against a set of
criteria. If the criteria are met and if all the exhaust gases
are ducted to a control device, then the volatile organic
compoun-d-~materials (VOG~) capture efficiency (CE) is assumed to
be 100 percent and CE need not be measured. However, if part of
the exhaust gas stream is not ducted to a control device, CE must
be determined.
2. DEFINITIONS
2.1 Natural Draft Opening (NDO) -- Any permanent opening in the
enclosure that remains open during operation of the f-acuity
emission unit and is not connected to a duct in which a fan is
installed.
2.2 Permanent Total Enclosure (PTE)
--
A permanently installed
enclosure that completely surrounds a~ source of emissionsunit
such that all VOGM emissions are captured and contained for
discharge through a control device.
2.3 Temporary Total Enclosure (TTE)
--
A temporarily installed
enclosure that completely surrounds a~ source of emissionsunit
such that all VOGN emissions are captured and contained for
discharge through ducts that allow for the accurate measurement
of VOGN rates.
3. CRITERIA OF A TEMPORARY TOTAL ENCLOSURE
3.1 Any NDO shall be at least 4 equivalent opening diameters
from each VOGN emitting point.
3.2 Any exhaust point from the enclosure shall be at least 4
equivalent duct or hood diameters from each NDO.
3.3 The total area of all NDO’s shall not exceed 5 percent of
~flL~0-0752

346
the surface area of the enclosure’s four walls, floor, and
ceiling.
3.4 The average facial velocity (FV) of air through all NDO’s
shall be at least 3,600 m/hr (200 fpm). The direction of air
through all NDO’s shall be into the enclosure.
3.5 All access doors and windows whose areas are not included in
Section 3.3 and are not included in the calculation in Section
3.4 shall be closed during routine operation of the
proccsriemissiOfl unit.
4. CRITERIA OF A PERMANENT TOTAL ENCLOSURE
4.1 Same as Sections 3.1 and 3.3
-
3.5.
4.2 All VOG~emissions must be captured and contained for
discharge through a control device.
5. PROCEDURE
5.1 Determine the equivalent diameters of the NDO’s and
determine the distances from each VOG~emitting point to all
NDO’s. Determine the equivalent diameter of each exhaust duct or
hood and its distance to all NDO’s. Calculate the distances in
terms of equivalent diameters. The number of equivalent
diameters shall be at least 4.
5.2 Measure the total area (At) of the enclosure and the total
area (AN) of all NDO’s of the enclosure. Calculate the NDO to
enclosure area ratio (NEAR) as follows:
NEAR
=
AN/At
The NEAR must be 0.05.
5.3 Measure the volumetric flow rate, corrected to standard
conditions, of each gas stream exiting the enclosure through an
exhaust duct or hood using EPA Method 2. In some cases (e.g.,
when the building is the enclosure), it may be necessary to
measure the volumetric flow rate, corrected to standard
conditions, of each gas stream entering the enclosure through a
forced makeup air duct using Method 2. Calculate FV using the
following equation:
FV
=
Q0
QI/AN
where:
=
the sum of the volumetric flow from all gas
streams exiting the enclosure through an exhaust
duct or hood.
01140-0753

347
=
the sum of the volumetric flow from all gas
streams into the enclosure through a forced makeup
air duct; zero, if there is no forced makeup air
into the enclosure.
AN
=
total area of all NDO’s in enclosure.
The FV shall be at least 3,600 m/hr (200 fpm).
5.4 Verify that the direction of air flow through all NDO’s is
inward. Use streamers, smoke tubes, tracer gases, etc. Strips
of plastic wrapping film have been found to be effective.
Monitor the direction of air flow at intervals of at least 10
minutes £or at least 1 hour.
6. QUALITY ASSURANCE
6.1 The success of this protocol lies in designing the TTE to
simulate the conditions that exist without the TTE, i.e., the
effect of the TTE on the normal flow patterns around the affected
facili-tyemission unit or the amount of fugitive VOGM emissions
should be minimal. The TTE must enclose the application
stations, coating reservoirs, and all areas from the application
station to the oven. The oven does not have to be enclosed if it
is under negative pressure. The NDO’s of the temporary enclosure
and a fugitive exhaust fan must be properly sized and placed.
6.2. Estimate the ventilation rate of the TTE that best
simulates the conditions that exist without the TTE, i.e., the
effect of the TTE on the normal flow patterns around the affected
facilityemission unit or the amount of fugitive VOG~emissions
should be minimal. Figure 1 may be used as an aid. Measure the
concentration (CG) and flow rate (QG) of the captured gas stream,
specify a safe concentration (CF) for the fugitive gas stream,
estimate the CE, and then use the plot in Figure 1 to determine
the volumetric flowrate of the fugitive gas stream (QF)~ A
fugitive VOG~jemission exhaust fan that has a variable flow
control is desirable.
6.2.1 Monitor the concentration of VOGU into the capture device
without the TTE. To minimize the effect of temporal variation on
the captured emissions, the baseline measurement should be made
over as long a time period as practical. However, the process
conditions must be the same for the measurement in Section 6.2.3
as they are for this baseline measurement. This may require
short measuring times for this quality control check before and
after the construction of the TTE.
6.2.2 After the TTE is constructed, monitor the VOG~
concentration inside the TTE. This concentration shall not
continue to increase and must not exceed the safe level according
to OSHA requirements for permissible exposure limits. An
0 140-075k

348
increase in VOG~concentration indicates poor TTE design or poor
capture efficiency.
6.2.3 Monitor the concentration of VOG~into the capture device
with the TTE. To limit the effect of the TTE on the process, the
VOGN concentration with and without the TTE must be within ±10
percent. If the measurements do not agree, adjust the
ventilation rate from the TTE until they agree within 10 percent.
(Source: Amended at
Ill. Reg.
______,
effective
01140-0755

349
Section 218.APPENDIX C
REFERENCE TEST METHODS AND PROCEDURESFOR AIR OXIDATION PROCESSES
Introduction
This Appendix presents the reference methods and procedures
required for implementing Reasonably Available Control Technology
(RACT). Methods and procedures are identified for two types of
~ACT implementation:
a) Determination of VOG~destruction efficiency for evaluating
compliance with the 98 weight percent VOG~reduction or 20
ppmv emission limit specified in Sections 215.520 through
215.527; and
b) Determination of of f gas flowrate, hourly emissions and
stream net heating value for calculating TRE.
All reference methods identified in this Appendix refer to the
reference methods specified at 40 CFR 60, Appendix A,
incorporated by reference in Section 215.105.
VOGM DESTRUCTION EFFICIENCY DETERMINATION
The following reference methods and procedures are required for
determining compliance with the percent destruction efficiency
specified in Sections 215.520 through 215.527.
a) Reference Method 1 or 1A for selection of the sampling site.
The control device inlet sampling site for determination of
vent stream molar composition or total organic compound
destruction efficiency shall be prior to the inlet of any
control device and after all recovery devices.
b) Reference Methods 2, 2A, 2C or 2D for determination of the
volumetric flowrate.
c) Reference Method 3 to measure oxygen concentration of the
air dilution correction. The emission sample shall be
corrected to 3 percent oxygen.
d) Reference Method 18 to determine the concentration of total
organic compounds (minus methane and ethane) in the control
device outlet and total organic compound reduction
efficiency of the control device.
TRE DETERMINATION
The following reference methods and procedures are required for
determining the offgas flowrate, hourly emissions, and the net
heating value of the gas combusted to calculate the vent stream
TRE.
01140-0756

350
a) Reference Method 1 or 1A for selection of the sampling site.
The sampling site for the vent stream flowrate and molar
composition determination prescribed in (b) and (C) shall be
prior to the inlet of any combustion device, prior to any
post—reactor dilution of the stream with air and prior to
any post-reactor introduction of halogenated compounds into
the vent stream. Subject to the preceding restrictions on
the sampling site, it shall be after the final recovery
device. If any gas stream other than the air oxidation vent
stream is normally conducted through the recovery system of
the affected facility, such stream shall be rerouted or
turned off while the vent stream is sampled, but shall be
routed normally prior to the measuring of the initial value
of the monitored parameters for determining compliance with
the recommended RACT. If the air oxidation vent stream is
normally routed through any equipment which is not a part of
the air oxidation process as defined in 35 Ill. Adm. Code
211.122, such equipment shall be bypassed by the vent stream
while the vent stream is sampled, but shall not be bypassed
during the measurement of the initial value of the monitored
parameters for determining compliance with Subpart V.
b) The molar composition of the vent stream shall be determined
using the following methods:
1) Reference Method 18 to measure the concentration of all
organics, including those containing halogens, unless a
significant portion of the compounds of interest are
polymeric (high molecular weight), can polymerize
before analysis or have low vapor pressures, in which
case Reference Method 25(a) shall be used.
2) ASTM D1946-67 (reapproved 1977), incorporated by
reference in Section 215.105, to measure the
concentration of carbon monoxide and hydrogen.
3) Reference Method 4 to measure the content of water
vapor, if necessary.
c) The volumetric flowrate shall be determined using Reference
Method 2, 2A, 2C or 2D, as appropriate.
d) The net heating value of the vent stream shall be calculated
using the following equation:
n
H=K 2 CiHi
i= 1
Where:
H
=
Net heating value of the sample, NJ/scm, where the
01140-0757

351
net enthalpy per mole of offgas is based on
combustion at 25°Cand 760 mm Hg, but the standard
temperature for determining the volume
corresponding to one mole is 20°C,as in the
definition of F (vent stream flowrate) below.
K
=
Constant, 1.740 x 10~ (1/ppm) (mole/scm)
(MJ/kcal) where standard temperature for mole/scm
is 20°C.
Ci
=
Concentration of sample component i, reported on a
wet basis, in ppm, as measured by Reference Method
18 or ASTM D1946-67 (reapproved 1977),
incorporated by reference in Section 215.105.
Hi
=
Net heat of combustion of sample component i,
kcal/mole based on combustion at 25°Cand 760 mm
Hg. If published values are not available or
cannot be calculated, the heats of combustion of
vent stream components are required to be
determined using ASTM D2382-76, incorporated by
reference in Section 215.105.
e) The emission rate of total organic compounds in the process
vent stream shall be calculated using the following
equation:
n
E=K F 2 CiMi
i=1
Where:
E
=
Emission rate of total organic compounds (minus
methane and ethane) in the sample in kg/hr--;
K
=
Constant 2.494 x 106 (1/ppm) (mole/scm) (kg/g)
(min/hr), where standard temperature for
(mole/scm) is 20°C-~-;
Mi
=
Molecular weight of sample component i (g/mole)--;
F
=
Vent stream flowrate (scm/mm), at a standard
temperature of 20°C.
f) The total vent stream concentration (by volume) of compounds
containing halogens (ppmv, by compound) shall be summed from
the individual concentrations of compounds containing
halogens which were measured by Reference Method 18.
(Source: Amended at
Ill. Reg.
______,
effective
01140-0758

352
Section 218.APPENDIX D
COEFFICIENTS FOR THE TOTAL RESOURCE EFFECTIVENESS INDEX (TRE)
EQUATION
This Appendix contains values for the total resource
effectiveness index (TRE) equation in Subpart V.
If a flow rate falls exactly on the boundary between the
indicated ranges, the operator shall use the row in which the
flow rate is maximum.
COEFFICIENTS FOR TRE EQUATION FOR CHLORINATED PROCESS
VENT STREAMS WITH
NET HEATING VALUE LESS THAN OR EQUAL TO 3.5 NJ/scm
FLOW RATE
COEFFICIENTS FOR TRE EQUATION FOR CHLORINATED PROCESS
VENT STREAMS WITH
NET HEATING VALUE GREATER THAN 3.5 NJ/scm
FLOW RATE
COEFFICIENTS FOR TRE EQUATION FOR NONCHLORINATED PROCESS
VENT STREAMS WITH
NET HEATING VALUE LESS THAN OR EQUAL TO 0.48 NJ/scm
COEFFICIENTS FOR TRE EQUATION FOR NONCHLORINATED PROCESS
01140-0759
Mm.
0.0
13. 5
700.
1400.
2100.
2800.
(scm/mm)
Max.
a
b
c
d
e
f
13.5 48.73 0.
0.404 —0.1632 0.
0.
700. 42.35 0.624 0.404 —0.1632 0.
0.0245
1400. 84.38 0.678 0.404 —0.1632 0.
0.0346
2100. 126.41 0.712 0.404 —0.1632 0.
0.0424
2800. 168.44 0.747 0.404 —0.1632 0.
0.0490
3500. 210.47 0.758 0.404 —0.1632
0.
0.0548
Mm.
0.
13. 5
700.
1400.
2100.
2800.
(scm/mm)
Max.
a
13.5 47.76
700. 41.58
1400. 82.84
2100. 123.10
2800. 165.36
3500. 206.62
bc
0.
—0.292
0.605 —0.292
0.658 —0.292
0.691 —0.292
0.715 —0.292
0.734 —0.292
d
0.
0.
0.
0.
0.
0.
e
0.
0.
0.
0.
0.
0.
f
0.
0.0245
0.0346
0. 0424
0.0490
0. 0548
FLOW RATE
(scm/mm)
Mm. Max.
a
b
c
d
e
f
0. 13.5 19.05 0.
0.113 —0.214
0.
0.
13.5 1350. 16.61 0.239 0.113 —0.214 0.
0.0245
1350. 2700. 32.91 0.260
0.113 —0.214 0.
0.0346
2700. 4050. 49.21 0.273 0.113 —0.214 0.
0.0424

353
(Source: Amended at
Ill. Reg.
_______,
effective
01140-0760
VENT STREAMS
WITH NET HEATING VALUE GREATER THAN 0.48 AND LESS THAN OR
EQUAL TO 1.9 NJ/scm
FLOW RATE
(scm/mm)
Mm. Max. a
b
c
d
e
f
0.
13.5 19.74 0.
0.400 —0.202 0.
0.
13.5 1350. 18.30 0.138 0.400 —0.202 0.
0.0245
1350. 2700. 36.28 0.150 0.400 —0.202 0.
0.0346
2700. 4050. 54.26 0.158 0.400 —0.202 0.
0.0424
COEFFICIENTS FOR TRE EQUATION FOR NONCHLORINATED PROCESS
VENT STREAMS
WITH NET HEATING VALUE GREATER THAN 1.9 AND LESS THAN OR
EQUAL TO 3.6 NJ/scm
FLOW RATE
(scm/mm)
Mm. Max. a
b
c
d
e
f
.0 13.5 15.24 0.
0.033 0.
0.
0.
13.5 1190. 13.63 0.157 0.033 0.
0.
0.0245
1190. 2380. 26.95 0.171 0.033 0.
0.
0.0346
2380. 3570.
40.27 0.179 0.033 0.
0.
0.0424
COEFFICIENTS FOR TRE EQUATION FOR NONCHLORINATED PROCESS
VENT STREAMS WITH
NET HEATING VALUE GREATER THAN 3.6 MG/scm
FLOW RATE
(scm/mm)
Mm. Max.
a
b c
d
e
f
0.
13.5
15.24
0. 0.
0.0090 0.
0.
13.5 1190. 13.63 0. 0.
0.0090 0.0503
0.0245
1190. 2380. 26.95 0. 0.
0.0090 0.0546 0.0346
2380. 3570. 40.27
0. 0.
0.0090 0.0573 0.0424

354
TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE B: AIR POLLUTION
CHAPTER I: POLLUTION CONTROL BOARD
SUBCHAPTER C: EMISSIONS STANDARDS AND LIMITATIONS
FOR STATIONARY SOURCES
PART 219
ORGANIC MATERIAL EMISSION STANDARDS AND LIMITATIONS
FOR STATIONARY SOURCES
SUBPART A: GENERAL PROVISIONS
Introduction
Clean up and Diopozal OpcrationsS~
Abbreviations and Conversion Factors
Applicability
Definitions
Test Methods and Procedures
Compliance Dates
Operation of Afterburners
Exemptions, Variations, and Alternative Means of
Control or Compliance Determinations
Vapor Pressure of Volatile Organic Liquids
Vapor Pressure of Organic Material or Solvente
Vapor Pressure of Volatile Organic Material
Incorporations by Reference
SUBPART B: ORGANIC EMISSIONS FROM STORAGE AND LOADING OPERATIONS
Section
219.121 Storage Containers
219.122 Loading Operations
219.123 Petroleum Liquid Storage Tanks
219.124 External Floating Roofs
219.125 Compliance Dates (Repealed)
219.126 Compliance Plan (Repealed)
SUBPART C: ORGANIC EMISSIONS FROM MISCELLANEOUS EQUIPMENT
Section
219.141 Separation Operations
219.142 Pumps and Compressors
219.143 Vapor Blowdown
219.144 Safety Relief Valves
SUBPART E: SOLVENT CLEANING
Solvent Cleaning in General
Cold Cleaning
Open Top Vapor Degreasing
01140-0761
Section
219.100
219. 101
219.102
219. 103
219. 104
219.105
219.106
219.107
219. 108
219.109
219.110
219.111
219.112
-vings Clause
Section
219.181
219. 182
219. 183

355
219.184 Conveyorized Degreasing
219.185 Compliance Schedule (Repealed)
219.186 Test Methods
SUBPART F: COATING OPERATIONS
for Manufacturi nc
Daily-Weighted Average Limitations
Solids Basis Calculation
Alternative Emission Limitations
Exemptions from Emission Limitations
Exemption from General Rule on Use of Organic Material
Compliance Schedule
Recordkeeping and Reporting
SUBPART G: USE OF ORGANIC MATERIAL
Use of Organic Material
Alternative Standard
Fuel Combustion Emission fourccsunits
Operations with Compliance Program
SUBPART H: PRINTING AND PUBLISHING
Flexographic and Rotogravure Printing
Applicability
Compliance Schedule
Recordkeeping and Reporting
Heatset-Web-Offset Lithographic Printing
Q: LEAKS FROM SYNTHETIC ORGANIC CHEMICAL AND POLYMER
MANUFACTURING EQUIPMENT PLANT
General Requirements
Inspection Program Plan for Leaks
Inspection Program for Leaks
Repairing Leaks
Recordkeeping for Leaks
Report for Leaks
Alternative Program for Leaks
Open-e~ndedValves
Standards for Control Devices
Compliance Date (Repealed)
SUBPART R: PETROLEUM REFINING AND RELATED INDUSTRIES;
ASPHALT MATERIALS
Section
Emission Limitations
Section
219.204
219.205
219.206
219.207
219.208
219.209
219.210
219.211
Section
219.301
219.302
219.303
219.304
Section
219. 401
219.402
219.403
219.404
219.405
SUBPART
Section
219. 421
219.422
219.423
219.424
219.425
219.426
219.427
219.428
219.429
219. 430
01140-0762

356
219. 441
219.442
219.443
219.444
219.445
219.446
219.447
219 .448
219.449
219.450
219.451
219.452
219.453
Petroleum Refinery Waste Gas Disposal
Vacuum Producing Systems
Wastewater (Oil/Water) Separator
Process Unit Turnarounds
Leaks: General Requirements
Monitoring Program Plan for Leaks
Monitoring Program for Leaks
Recordkeeping for Leaks
Reporting for Leaks
Alternative Program for Leaks
Sealing Device Requirements
Compliance Schedule for Leaks
Compliance Dates (Repealed)
Section
219.480
219.481
SUBPART 5: RUBBER AND MISCELLANEOUS PLASTIC PRODUCTS
Manufacture of Pneumatic Rubber Tires
Green Tire Spraying Operations
Alternative Emission Reduction Systems
Emission Testing
Compliance Dates (Repealed)
Compliance Plan (Repealed)
SUBPART T: PHARMACEUTICAL MANUFACTURING
Applicability of Subpart T
Control of Reactors, Distillation Units, Crystallizers,
Centrifuges and Vacuum Dryers
219.482 Control of Air Dryers, Production Equipment Exhaust
Systems and Filters
Material Storage and Transfer
In—Process Tanks
Leaks
Other Emission Sourccc Units
Testing
Monitoring and Rccordkceping for Air Pollution Control
Equipment
219.489 Recordkeeping for Air Pollution Control Equipment
SUBPART V: AIR OXIDATION PROCESSES
Definitions (Repealed)
Emission Limitations for Air Oxidation Processes
Testing and Monitoring
Compliance Date (Repealed)
SUBPART W: AGRICULTURE
Section
219.461
219.462
219. 463
219.464
219.465
219.466
219.483
219. 484
219.485
219.486
219.487
219.488
Section
219.521
219.525
219.526
219.527
Section
01140-0763

357
219.541 Pesticide Exception
SUBPART X: CONSTRUCTION
Section
219.561
219.562
219.563
Section
219.581
219.582
219.583
219.584
219.585
219.586
Architectural Coatings
Paving Operations
Cutback Asphalt
SUBPART Y: GASOLINE DISTRIBUTION
Bulk Gasoline Plants
Bulk Gasoline Terminals
Gasoline Dispensing FaciliticsOperation
Gasoline Delivery Vessels
Gasoline Volatility Standards
Gasoline Dispensing Sources Operations - Motor Vehicle
Fueling Operations
SUBPART Z: DRY CLEANERS
Section
219.601
219.602
219
.
603
219.604
219.605
219.606
219.607
219.608
219.609
219.610
219.611
219.612
219.613
Perchloroethylene Dry Cleaners
Exemptions
Leaks
Compliance Dates (Repealed)
Compliance Plan
f
Repealed)
Exception to Compliance Plan (Repealed)
Standards for Petroleum Solvent Dry Cleaners
Operating Practices for Petroleum Solvent Dry
Program for Inspection and Repair of Leaks
Testing and Monitoring
Exemption for Petroleum Solvent Dry Cleaners
Compliance Dates (Repealed)
Compliance Plan (Repealed)
Cleaners
SUBPART AA: PAINT AND INK MANUFACTURING
Applicability
Exemption for Waterbase Material and Heatset~
Ink
Permit Conditions
Open-~TopMills, Tanks, Vats or Vessels
Grinding Mills
Storage Tanks
Leaks
Clean Up
Compliance Schedule
Recordkeeping and Reporting
Section
219.620
219.621
219
.
623
219.624
219.625
219.626
219.628
219.630
219.636
219. 637
Offset
01140-07614

358
SUBPART BB: POLYSTYRENE PLANTS
Section
2-10.3752l9.640 Applicability of Subpart BE
2-19.8-7-~219.642 Emissions Limitations at Polystyrene Plants
219.886219.644 Emissions Testing
Applicability of Subpart BB (Renumbered)
Emissions Limitation at Polystyrene Plants (Renumbered)
Compliance Date (RePealed)
Compliance Plan (Repealed)
Special Requirements for Compliance Plan (Repealed)
Emissions Testing (Renumbered)
SUBPART Pt’: MISCELLANEOUS FABRICATED PRODUCT
MANUFACTURING PROCESSES
Section
219.920
219.923
219.926
219.927
219.928
Applicability
Permit Conditions
Control Requirements
Compliance Schedule
Testing
SUBPART QQ: MISCELLANEOUS FORMULATION MANUFACTURING PROCESSES
Section
219.940
219.943
219.946
219.947
219.948
Section
219.960
219.963
219.966
219.967
219.9 68
Section
2 19.980
219.983
219.986
2 19.987
219.988
Applicability
Permit Conditions
Control Requirements
Compliance Schedule
Testing
SUBPART RR: MISCELLANEOUS ORGANIC CHEMICAL
MANUFACTURING PROCESSES
Applicability
Permit Conditions
Control Requirements
Compliance Schedule
Testing
SUBPART TT: OTHER EMISSION SOURCES UNITS
Applicability
Permit Conditions
Control Requirements
Compliance Schedule
Testing
SUBPART UU: RECORDKEEPING AND REPORTING-
0 1.
140
-
0765
219.875
219.877
219.879
219.881
219
.
883
219.886

359
Section
219.990 Exempt Emission SourcesUnits
219.991 Subject Emission SourccsUnits
Section 219.AppcndixPPENDIX A:
List of Chemicals Defining
Synthetic Organic Chemical and
Polymer Manufacturing
Section 2l9.AppcndixPPENDIX B:
VON Measurement Techniques for
Capture Efficiency
Section 219.AppcndiXPPENDIX C:
Reference Methods and
Procedures
Section 219.AppcndixPPENDIX D:
Coefficients for the Total
Resource Effectiveness Index
(TRE) Equation
AUTHORITY: Implementing Section 10 and authorized by Section
28.5 of the Environmental Protection Act (Ill. Rev. Stat. 1991,
ch. 111~,par. 1010) ((P.A. 87—1213, effective September 26,
1992) 415 ILCS 5/10 and 28.5.
SOURCE: Adopted at R9l-8 at 15 Ill. Reg. 12491, effective August
16, 1991; amended in R91-24 at 16 Ill. Reg. 13597, effective
August 24, 1992; amended in R91—30 at 16 Ill. Reg. 13883,
effective August 24, 1992; amended in
___________
at
Ill.
Reg.
_______,
effective _________________
SUBPART A: GENERAL PROVISIONS
Section 219.100
Introduction
a) This Part contains standards and limitations for
emissions of organic material and volatile organic
material from stationary sources located in the Metro~
East area, which is comprised of Madison, Monroe, and
St. Clair Counties.
b) Sources subject to this Part may be subject to the
following:
1) Permits required under 35 Ill. Adm. Code 2Ol-- ~jiç~,
2) Air quality standards under 35 Ill. Adm. Code
243i-~
c) This Part is divided into Subparts which are grouped as
follows:
1) Subpart A: General Provisions~
2) Subparts B-F: Emissions from equipment and
operations in common to more than one industry;
0 L~.O-0766

360
3) Subpart G: Emissions from use of organic
material;
4) Subparts H-e~8~: Special r~ules for various
industry groups.
~j- SubPart TT: Rules for emission units not
otherwise addressed.
~j SubPart UU: Recordkeeping and reporting for
equipment and operation addressed by Subparts PP.
00. RR, and TT.
(Source: Amended at
_____,
Ill. Reg.
_____,
effective
_______)
Section 219.101
Cleanup and Disposal OperationSavings Clause
Emission of organic material released during clean-up operations
and disposal shall be included with other emissions of organic
material from the related emission sourcc or air pollution
control equipment in determining total emissions.
Every owner or operator of an emission unit formerly subject to
35 Ill, Adm. Code 215 shall have complied with its standards and
limitations by the dates and schedules applicable to the emission
unit in accordance with Part 215 or upon initial start-up.
Compliance with all compliance dates or schedules found in Part
215 are not superseded bY this Part and remain in full force and
effect.
(Source: Section repealed, new Section added at
______,
Ill.
Reg.
, effective
_________________________)
Section 219.102
Abbreviations and Conversion Factors
a-)- The following- abbreviations arc used in this Part:
At~eficanSociety for Testi~
barrels (42 gallons)
_____
aegrccs
~
-
centimeters
cubic inches
degrees Fahrenhei-t
Federal Implementation Plan
feet
square feet
grams
gallons per minute
grams per mole
gallons
hours
inches
01140-0767
rw~
(1
r~
ASTM
OC
cu in
FIt’
g
g/molc
gal

kca I
kg
kg/hr
1/sec
lbs
/
hr
lbs/gal
mg
Mg
ft
ininHg
pp~
ppmv
psia
p~s4g
scf
kilocalories
kilograms
kilograms per hour
kilopascals; one t
meter
liters
1itc~
pounds
-~
sceonci
nounds
hr~irr
pouncL
-
per gallon
lower explosive limit
meters
square meter
cubic meters
milligrams
Mcgagrams, m
milliliters
minutes
mcgaj oulcG
8~p
TTE
sq cm
sq in
UCEPA
V~M
State Implementation Plan
temporary total enclosure
square centimeters
square inches
English ton
English ton
United States Environment~
volatile organic compounds
volatile organic liquids
volatile organic materials
~)-
The following conversion factors arc used in this Part.
~nglish
Metric
1 gal
1,000 gal
1 psia
2.205 lbs
1 bbl
1 Cu in
1 lb/gal
1 ton
3.785 1
3,785 1 oj
6.897 kfla
1 kg
i~59.0 I
16.39 ml
119,800 mg/I
0.907 Mg
01140-0768
361
and newtons per square
part3 per million
parts per million by volume
pounds per square inch
pounds per square inch absolut~
pounds per oquare inch gauge
1
3.785 m~
(51.71 mm Hg)

362
0.907 Mg
The abbreviations and conversion factors of 35 Ill. Adm. Code 211
apply to this Part.
(Source: Amended at
____,
Ill. Reg.
____
effective
__________)
Section 219.104
Definitions
The following
iiu~
arc defined for the purpose of this Part.
“Accelacota” means a pharmaceutical coating operation
which consists of a horizontally rotating perforated
drum in which tablets arc placed, a coating is applied
by spraying, and the coating is dried by the flow of
air across the drum through the perforations.
“Accumulator1’ means the reservoir of a condensing un-it
receiving the condensate from a surface condenser.
“Acid Cases” means for the purposes of Section 9.4 of
the Environmental Protection Act (the Act) (Ill. Rev.
Stat. 1937, oh. 111 1/2, par. 1009.4), hydrogen
chloride, hydrogen fluoride and hydrogen bromide, which
exist as gases, liquid mist, or any combination
thereof.
“Actual emissions” means the actual quantity of VON
emissions from an emission source during a particular
time period.
“Actual Heat Input” means the quantity of heat produced
by the combustion of fuel using the gross heating value
of the fuel.
“Adhesive” means any substance or mixture of substances
intended to serve as a joining compound..
“Afterburner” means a control device in which materials
in
rc~
mhii~~tt~r1
“Air con
matter,
taminant”
any odor,
means any solid,
or any form of c
liquid, or
ncrgy, that
gasco
is
us
capable of being released into the atmosphere from an
emisr~ion ~ourc~~.
t dry by
1r~
36 3.15~K
“Air dried coatings” means any ~n~1ngs
of ai.. ~orccd ai~~t ~
up-
(194°F)
“Air pollution” means the presence in the atmosphere of
one or more air contaminants in sufficient quantities
01140-0769
n.~
11

363
and of such characteristics and duration as to be
injurious to human, plant, or animal life, to health,
er—to property, or to-unreasonably interfere with the
enjoyment of life or property.
“Air pollution control equipment” means any equipment
or facility of a type intended to eliminate, prevent,
reduce or control the emission of specified air
contaminants to the atmosphere.
“Air suspension coatcr/dryer” means a pharmaceutical
coating operation which consists of vertical chambers
in which tablets or particles are placed, and a coating
is applied and then dried while the tablets or
particles arc kept in a fluidized -state by the passage
of air upward through the chambers.
r 1
~.
rrr
~
means a spray
the coating is atomized by forcing it
through a small
opening at high pressure. The coating liquid
is not
mxed with air before exiting from the
nozzle.
.
~r~tinri
mi~thrw1
in
whir-~h
“~4~—assi~~air
•1 ~
y..
—‘
w.
t,
method which combines compressed air with hydraulic
pressure to atomize the coating material into finer
droplets than is achieved with pure airless spray.
Lower hydraulic pressure is used than with airless
spray.
“Allowable emissions” means the quantity of VON
emissions during a particular time period from a
stationary source calculated using the maximum rated
capacity of the source (unless restricted by federally
enforceable limitations on operating rate, hours of
operation, or both) and the most c~tringcntof: the
applicable
standards in 40 CFR Parts 60 and 61; the
applicable implementation plan; or a federally
enforceable permit.
“Ambient air quality standards” means those standards
designed to protect the public health and welfare
codified in 40 CFR Part 50 and promulgated from time to
time by the USEPA pursuant to authority contained in
Section 108 of the Clean Air Act, 42 U.S.C. 7401 et
seq., as amended from time to time.
“Applicator” means a device used in a coating line to
apply coating.
“-As applied” means the exact formulation of a coating
during application on or impregnation into a substrate.
01140-0770

364
“Architectural Coating” means any
coating used for
residential or commercial buildings or their
appurtenances,
or for industrial buildings, which is
site applied.
“Asphalt” means the dark-brown to
material (solid, semisolid, or 11
black ccmcntitious
quid in coneistency)
naturally or as a residue of petroleum refining.
p.
~
~.,
Prii~c Coat” ~a~s a ~-v4~~ity
liquid
asphalt applied to an absorbent surface as the first of
mcn~
thrn
nnr’
~
ji-
“Automobile” means a motor vehicle capable of carrying
“Automobile or light-duty truck assembly plant” means a
facility where parts arc assembled or finished for
eventual inclusion into a finished automobile or
light-duty truck ready for sale to vehicle dealers, but
not including customizers, body shops, and other
repainters.
“Automobile or light-duty truck refinishing” means the
repainting of used automobiles and light-duty trucks.
11-Baked coatings” means any coating which is cured or
dried in an oven where the oven air temperature exceeds
90°C (194°F).
“Batch Loading” means the process of loading a number
of individual parts at the same time for degrcasing.
“Bead-Dipping” means the dipping of an assembled tire
bead into a solvent—based cement.
“-Binders” means organic materials and resins which do
not contain VON.
“Bituminous coatings” means black or brownish coating
materials which arc soluble in carbon disulfide, which
consist mainly of hydrocarbons, and which arc obtained
from natural deposits or as residues from the
distillation of crude oils or of low grades of coal.
“British Thermal Unit” means the quantity of heat
required to raise one pound of water from 60°Fto 61°F
(abbreviated btu).
“Brush or wipe coating” means a manual method of
applying a coating using a brush, cloth, or similar
of 140-0771

object.
365
“Bulk gasoline plant” means a gasoline storage and
distribution facility wit-h an average throughput of
76.000 1 (20.000 gal) or less on a 30—day rolling
average that distr~-~ gasoline to gasoline
dispensing faciliti~.
distribution facility that receives gasoline by
pipeline, ship or barge, and distributes gasoline to
bulk gasoline plants or gasoline dispensing facilities.
“Can” means any metal container, with or without a top-,
cover, spout or handles, into which solid or liquid
materials are ~k~rit~d~
“Can coating” means any coating applied on a single
walled container that is manufactured from metal sheets
thin’ne~r
vn~.._.
-, ‘~
gauge (0
1 A
I
--
is...
facility that includes one or
‘--/-
“Can coating line” means a coating line in which any
protective, decorative, or functional coating is
applied onto the surface of cans or can components.
“Capture” means the containment or recovery of
emissions from a process for direction into a duct
which may be exhausted through a stack or vent to a
control device. The overall abatement of emissions
from a prosess with an add—on control device is a
function both of the capture efficiency and of the
control device.
“Capture device” means a hood, enclosed room floor
sweep or other means of collecting solvent or other
-
-
n,1_.t.
-
,
.1-4—_nt—
attcrburncr or carbon adsorb-er. Sometimes the term is
used loosely to- include the control device.
“Capture efficiency” means the fraction of all VON
generated by a process that are directed to an
abatement or recovery device.
“Capture system” means all equipment (including, but
n~t 1imi~ to, hoods, ducts, f~n~
etc.) used to contain, collect and transport
pollutant to a control device.
01140-0772
pol1ut~..~...cintc
~
The pol~....
~
~ ~be
directed to a pollution control device such as an

366
~
?~... 7~p.4.U
4—1-.~ t11..-.n
7~4
amended, including the Clean Air Act Amendments of
1977, (42 U.S.C. 7401 et seq.), and the Clean Air Act
Amendments of 1990, (P.L. 101—549).
“Clear coating” means coatings that lack color and
opacity or are transparent using the undercoat as a
reflcctant base or undertone color.
“Clear topcoat” means the final coating which contains
binders, but not opaque pigments, and is specifically
formulated to form a transparent or translucent solid
“Closed Purge System” means a system that is not open
to- the atmosphere and that is composed of piping,
connections, and, if necessary, flow inducing devices
that transport liquid or vapor from a piece or pieces
of equipment to a control device, or return the liquid
“Closed vent system” means a system that is not open to
the atmosphere and is composed of piping, connections,
and, if necessary, flow inducing devices that transport
gas or vapor from an emission source to a control
device.
“Coating” means a material applied onto or impregnated
into a substrate for protective, decorative, or
.
purposes. Such materials include, but arc
not limited to, paints, varnishcs,scalcrs, adhesives,
thinners, diluents, and inks.
“Coati..~
coating.
“Coating line” means an operation consisting of a
~eri~ of onc~
or ~nort~
nri ~nru1
i
tr~r~
-~nd ,nv
associated flash-off areas, drying areas, and ovens
wherein a surface coating is applied, dried, or cured.
~(Itis not necessary for an operation to have an
oven,
or flash—off area, or
this definition.)
drying
area to be included in
l!Coati;-~g plcrt”
more coating line~s).
“Coil” means any flat metal sheet or strip that is
rolled or wound in concentric rings.
“Coil coating” means any coating applied on any flat
metal sheet or strip that comes in rolls or coils.
01140-0773
~-- applicator” means equipment used to apply u
Ii’-” 1flfT.r1~
~.1ny plant that contaim.i iuc
0L

367
“Coil coating facility” means a facility that includes
one or more coil coating line(s).
“Coil coating line” moans a coating line in which any
protective, decorative or functional coating is applied
onto the surface of flat metal sheets, strips, rolls,
or coils for industrial or commercial use.
“Cold cleaning” means the process of cleaning and
removing soils from surfaces by spraying, brushing,
flushing, or immersion while maintaining the organic
solvent below its boiling point. Wipe cleaning is not
included in this definition.
“Complete Combustion” means a process in which all
carbon contained in a fuel or gas stream is converted
to carbon dioxide.
“component” means, with respect to synthetic organic
chemical and polymer manufacturing equipment, and
petroleum refining and related industries, any piece of
equipment which has the potential to leak VON
including, but not limited to, pump seals, compressor
seals, seal oil degassing vents, pipeline valves,
pressure relief devices, process drains, and open ended
pipes. This definition excludes valves which arc not
externally regulated, flanges, and equipment -in heavy
liquid service. For purposes of Subpart Q of thi-e
Part, this definition also excludes bleed ports of gear
pumps in polymer service.
“-Concrete curing compounds” means any coating applied
to freshly poured concrete to retard the evaporation of
water.
“Condensate” means volatile organic liquid separated
from its associated gazes, which condenses due to
changes in the temperature or pressure and remains
liquid at standard conditions.
“Continuous- process” means, with respect to polystyrene
resin, a method of manufacture in which the styrenc raw
material is delivered on a continuous basis to the
reactor in which the styrenc is rir11~rmcrized to
polystyrene.
“Control device” means equipment (such as an
aftcrburne~
emission of
or
~U~UL~ULJ
U~CU LU rCIUOVC
Or prevent the
air pollutants from a contaminated exhaust
stream.
“Control device efficiency” means the ratio of the
01
~4O-077E~

_-1 ~__~j_.2
368
n~.4 1-~
~
device and th~..
pollution introduced to the conLr-o1 ucv~ce, expressed
as a percentage.
“Convcyorizcd degreasing” means the continuous proces~s
of cleaning and removing soils from surfaces utilizing
either cold or vaporized solvents.
“Crude oil” means a naturally occurring mixture which
consists of hydrocarbons and sulfur, nitrogen, or
oxygen derivatives of hydrocarbons and which is -a-
liquid at standard conditions.
~a a
.j
~
•flLhJ
3~_ ~s. s.aa a_akFs.a~
~.
S.. .J.
.a a
“Cutback Asphalt” means any asphalt which has been
liquified by blending with petroleum solvents other
than residual fuel oil and has not been emulsified with
water.
“Daily-
-~
..ight~
VON content of two or more coatings as applied-
coating line during any day, taking into account the
frrirt~irrn of total
rri~itinci
volume that each coatinci
-,
as calculated with the following equation:
-r’s-i
r~1rTD
VflM ~
~
fhr’
~Jr~1-agc
coatings as applied each day on a
coating line in units of kg VOM/l (lbs
VON/gal) of coating (minus water and any
compounds which arc specifically
exempted from the definition of VON),
number of different coatings as
coating line,
ic vojume of each coating (minus
01140-0775
“Crude oil gathering” means the transportation of crude
oil or condensate after custody transfer between a
production facility and a reception point.
“Custody transfer” means the transfer of produced
petroleum and/or condensate after processing and/or
treating in the producing operations, from storage
tanks or automatic transfer facilities to pipelines or
-
E VT-~~G~J/V~
where:
r~fl.
applied each day on a

rind
any compounds which
:;r
r’rl ri—rym
thr~ rir’finifimn
r~i-
v.
~ecif I
applied cacn
..~
..~
coating line in
units of 1 (gal).
-.3
L~~
11’
;i
-01
The VON content of each coating as
applied each day on a coating line in
units of kg VOM/l (lbs VON/gal) of
coating (minus water and any compounds
which arc specifically exempted from the
definition of VON), and
mt
— S.. — — -——
‘1
f all coatings (minus
epecifically exempted from the
definition of VON) as applied each day
on a coating line in units of 1 (gal)-.
“Day” means the consecutive 24 hours beginning at 12:00
AN (midnight) local time.
“Degreaser” means any equipment or system used in
solvent cleaning.
“Delivery vessel” means any tank truck or trailer
equipped with a storage tank that is used for the
transport of gasoline to a stationary storage tank at a
gasoline dispensing facility, bulk gasoline plant, or
bulk gasoline terminal.
“Dip coating” means a method of applying coatings in
which the part is submerged in a tank filled with the
coating.
“Distillate Fuel Oil” means fuel oils of grade No. 1 or
2 as specified in detailed requirements for fuel oil
ASTN D—369—69 (1971).
“Dry Cleaning Facility” means a facility engaged in the
cleaning of fabrics using an essentially nonaqucous
solvent by mean-s of one or more solvent washes,
extraction of excess solvent by spinning and drying by
tumbling in an airstrcam. The facility includes, but
is not limited to, washers, dryers, filter and
purification systems, waste disposal systems, holding
tanks, pumps and attendant piping and valves.
-11-Effluent Water Separator” means any tank, box, sump or
other apparatus in which any organic material floating
on or entrained or contained in water entering such
tank, box, sump or other apparatus is physically
separated and removed from such water prior to outfall,
01 140-077~
369

“Electrostatic bell or disc spray” means an
~1eetrn~itntie ~nrm.’ ~o~i-tinamethod in which a
_~r)e~
jL
~..... miz~ -~--~
-ipply
coatL.-.~,
rapidly-spinning
h~11-or~i
~e-~hnr
used to create ~
1- ;1 rir~
I I r;1
ic1r
~
“Enclose” means to cover any VOL surface that is
exposed to the atmosphere.
-~-~naceaiing compounL
compouna app~~
can ends which functions as a gasket when the end is
~o~ieinh1edonto the e~n
“Excess
Air” means air supplied in addition to the
-~_IiL..J.LL
L. I Li.
I I
I
I I.
i
s~v rinr~’~..i
rv
frr
compleLe comblL;t~
of all fuel anu1~ comou~~~~
“Excessive release” means a discharge of more than 295
g (0.65 ibs) of mercaptans. and/or hydrogen sulfide into
the atmosphere in any 5-minute period.
“Exterior base coat” means a coating applied to the
exterior of a can body, or flat sheet to provide
protection to the metal or to provide background for
any lithographic or printing operation.
“Exterior end coat” means a coating applied to the
exterior end of a can to provide protection to the
metal.
“External floating roof” means a cover over an open top
0~
140-0777
370
.1
high transfer efficiency.
“Electrostatic spray” means a spray coating method in
which oDDosite electrical charges are applied to the
T~tT
surstratc and the coating. The coat.L..~.., attracted to
the object due to the electrostatic potential between
them.
“Emission Rate” means total quantity of any air
contaminant discharge into the atmosphere in any
onc—hour period.
“Emission source” and “source” mean any facility from
which VON is emitted or capable of being emitted into
the atmosphere.
“Enamel” means a coating that cures by chemical
cross—linking of its base resin. Enamels can be
di~tinmii~hed
from lacquers
he~u~e
en~me1~nrc nn-~
readily resoluble in their original solvent.

371
storage tank consisting of a double deck or pontoon
single deck which rests upon and is
supported by the
volatile organic liquid being contained and is equipped
with a closure seal or seals to- close the space between
the roof edge and tank shell.
“Extreme environmental conditions” means exposure to
any or all of the following: ambient weather
conditions; temperatures consistently above 95°C
+203°F); detergents; abrasive and scouring agents;
solvents; or corrosive atmospheres.
“Extreme performance coating” means any coating which
during intended use is exposed to extreme environmental
conditions.
“Fabric coating” means any coating applied on textile
fabric. Fabric coating includes the application of
coatings by impregnation.
“Fabric coating facility” means a facility that
includes one or more fabric coating lines.
“Fabric coating line” means a coating line in which any
pro
decor-’~~’-“- functional coating
reinrorcing material, is applied on or iniprcgnate~ into
n
te~ti1c~fnhric
ally enforceable”
—.11 ~
~
OOfls~a.~
which arc enforceable by the Administrator
including those requirements developed pursuant to 40
CFR Parts 60 and 61; requirements
within any applicable
impi-ementation plan; and any permit requirements
established pursuant to 40 CFR 52.21 or under
regulations approved pursuant to 40 CFR Part 51 Subpart
I and 40 CPu 51.166.
“Final repair coat” means the repainting of any topcoat
which is damaged during vehicle assembly.
“Firebox” means the chamber or compartment of a boiler
or furnace in which materials arc burned, but not the
combustion chamber or afterburner of an incinerator.
“Fixed-roof tank” means a cylindrical shell with a
permanently affixed roof.
(‘~Ff1~
printing” ~a~z the- ap~1icaticn-e’-
~‘~‘I”~f3
.-~
designs, and pictures to a substrate by means of a roll
printing technique in which the pattern to be applied
is raised above the printing roll and the image carrier
is made of clastoiueric materials.
0
i~O-077B

dCsiyit~i,
UL
The image carrier on the roll
“Floating roof” means a roof on
stationary tank,
reservoir, or other container which moves vertieui..ly
upon change in
volume of the stored material.
“Fountain solution” means the solution which is applied
to the image plate to maintain hydrophilic properties
of the non—image areas.
“Freeboard Height” means for open top vapor degreacers,
the distance from the top of the vapor zone to the top
of the dcgrcaser tank. For cold cleaning degrcascrs,
the distance from the solvent to the top of the
dcgrcascr tank.
“Fuel combustion emission source” means any furnace,
boiler, or similar equipment used for the primary
purpose of producing heat or power by indirect heat
transfer.
“Fuel gas system” means a system for collection of
refinery fuel gas including, but not limited to, piping
for collecting tail gas from various process units,
mixing drums and controls, and distribution piping.
“Gas service” means that the component contains process
fluid that is in the gaseous state at operating
“Gas/gas method” means either of two methods for
determining capture which rely only on gas phase
rp 1~.—.
~4...
4—
,,4.,
~
4
of a temporary total enclosure
would-bc fugitive emissions
are
(TTE) to ensure
measured. The
that all
second
method uses the
building or room which houses
the
facility ~... enclosure. -~..
~
requires
that all other VON
within the room be shut
.,.L1,.,
A_1__
.L,__J_.
I
__r..._........,
1_~L
‘I’t
fl_
___‘I
1_’S
down
wxiiie i..ite
LC.3L .ie
perLornicu,
~ ~ii .Lun~ ~riu i~iower~
within
the room must be operated according to normal
procedures.
“Gasoline” means any petroleum distillate or petroleum
distillate/alcohol blend having a Reid vapor pressure
of 27.6 kfla or greater which is used as a fuel for
internal combustion engines.
“Casolinc dispensing facility” means any site where
secona
U
4UU779
372
“Flexographic printing line” means a printing line in
which each roll printer uses a roll with raised areas
for applying an image

373
gasoline is transferred from a
stationary storage tank
to a motor vehicle gasoline tank used to provide fuel
to the engine of that
motor
vehicle.
11-Grccn Tire Spraying” means the spraying of green
tires, both inside and
outside, with release compounds
which help remove air from the tire during molding and
prevent the tire from sticking to the mold after
curing
“Green Tires” means assembled tires before molding and
curing have occurred.
“Cross vehicle weight” means the manufacturer’s gross
weight rating for
the individual vehicle.
“Cross vehicle weight rating” means the value specified
by
the
manufacturer as
the maximum design loaded weight
of a c inglc vehicle.
“T~1entr’t~
~
soray”
...— ....—
....~
spray coating
method in which the coating is heated
just prior to
application.
“Heatzct” means a
class of web-offset lithography which
requires a heated dryer to solidify the printing inks.
“Heatsct-web-off
set lithographic printing line” means a
lithographic printing line in which a blanket cylinder
is used to transfer ink from a plate cylinder to a
substrate continuously fed from a roll or an extension
process and an
oven is
used
to solidify the printing
inks.
“Heavy liquid” means liquid with
a true vapor pressure
nf
1c~
thnn fl~
kPn (OO~.
r~i1 nt~ 2~4.’~°~ (~7fl°P~I
established in a-
-
-‘I
text or as-
determined by A&TM method D28 79-86 (incorporated by
reference in Section 219.112) ; or which has 0.1 Reid
Vapor Pressure as determined
by ASTN method D3-23--82
(incorporated by reference in
Section 219.112); or
which when distilled requires
a temperature of
421.95°I
(300°fl
or greater to recover
10 percent of the liquid
as determined by ASTN method D86-82 (incorporated by
~ir~e
a. S.~.a.S..a, V~.A_
in Feotion 2VL.1 12’~
-
~,1
.1..
£‘.,.
S.,
4..
~
a a’...—.a
0~140-0780
purpose of ~u~part
F of this Part, heavy conctructi~aa,
mining, farming, or
material
handling equipment; heavy
industrial
engines; diesel—electric locomotives and
associated power equipment; and the
components of such

374
“Heavy off-highway vehicle products coating facility”
means a facility that includes one or more heavy
off-highway vehicle products coating line(s).
1~Hcavy
off—highway vehicle products coating line” means
a- coating line in which any protective, decorative, or
functional coating is applied onto the surface of heavy
off-highway vehicle products.
“High temperature aluminum coating” means a coating
that is certified to withstand a temperature of 5-37.8°C
(1000°F) for 24 hours.
“Hood” means a partial enclosure or canopy for
capturing and exhausting, by means of a draft, the
organic vapors or other fumes rising from a coating
process or other source.
“Hood capture efficiency” means the emissions from a
process which arc captured by the hood and directed
into a control device, expressed as a percentage of all
emissions.
“Hot well” means the reservoir of a condensing unit
receiving the condensate from a barometric condenser.
“Hour” means a block period of 60 minutes (e.g., 1:00am
to 2:00am).
“I-n—process tank” means a container us-cd for mixing,
blending, heating, reacting, holding, crystallizing,
ev~aporatingor cleaning operations in the manufacture
of pharmaceuticals.
“In—situ Sampling Systems” means nonextractivc samplers
or in—line samplers.
incni~m
~“~pose of -Subpart
Q
,~.—
..~
.4...
4 nfl
.4-.
forthc~-.,
of th~~
S..~ ‘.‘.~.pincflt
which ~
ii~r~n~l
pressure
LIIUL i~ UL ~
~
ic
~u.
i~
p~ia)
~e~ow ambient pressure.
“Incinerator” means a combustion apparatus in which
refuse i r~ hnrnei
-
“Indirect heat transfer” means transfer of heat in
such
a ~way that the source of heat does not come into direct
contact with process
materials.
“Ink” means a coating used in printing,
impressing, or
transferring an image onto a substrate.
011400781

375
“Interior body spray coat” means
a coating applied by
spray to the interior 0-f a can body.
“Internal-floating
roof” means a cover or root in a
fixed—roof tank which rests- upon and is supported by
the volatile organic liquid being contained and is
equipped with a closure seal or seals to close the
space between the roof edge and tank shell.
“T.nnquers”
means
any
nlcnr ~ond fini~hc~ formii1nt~d
with
nitrocellulose or synthetic resins to dry by
evaporation without chemical reaction, including clear
lacquer sanding scalers.
“Large appliance” means any residential and commercial
washers, dryers, ranges, refrigerators, freezers, water
heaters, dishwashers, trash compactors, air
conditioners, and other similar products.
“Large appliance coating” means any coating applied to
the component metal parts (including, but not limited
to, doors,
cases, lids, panels, and interior support
parts) of residential and co~crcial washers, dryers,
ranges, refrigerators, freezers, water heaters,
dishwashers, trash compactors, air conditioners, and
other ~imi mr nro~u~
“Large appliance coating facility” means a facility
that includes one or more large appliance coating
line(s).
“Large appliance coating line”
a coating line in
wni~n uny proccetive-, aecora~ivc, or i unu~ioriu~UOULiIi~
is applied onto
the surface of large appliances.
“Light liquid” means VON in the liquid state which is
not defined as heavy liquid.
“Light—duty truck” means any motor vehicle rated at
3,850 kg gross- vehicle weight or less, designed mainly
to transport property.
“Liquid/gas method” means either of two methods for
determining capture which require both gas phase and
liquid phase measurements and analysis. The first
method requires construction of a TTE. The second
method uses the building or room which houses the
facility as an enclosure. The second method requires
that all other VON- sources within the room be shut down
while the test is performed, but all fans and blowers
~ji
4 h I ii f Ii e r r~rim
mi1
‘~rt- hc’ or~ r ni—c
t’i n r~ord I nr~
ri i-~rvrm n
1
01 t~0-O782

376
procedures.
“Liquid—Nount-ed Seal” means a
primary seal mounted in
continuous contact with the liquid between the tank
wall and the floating roof edge around the
circumference of the roof.
“Liquid service” means that the equipment or component
contains- process fluid that is in a liquid state at
operating conditions.
“Liquids Dripping” means any visible leaking from
a
seal including spraying, misting, clouding and ice
formation.
“Lithographic printing line” moans a printing line,
except that the substrate is not necessarily fed from
an unwinding roll, in which each roll
printer uses a
roll
where both the image
and
non—image areas arc
essentially in the same plane (planographic).
“Low Solvent Coating” means a coating which
contains
less organic solvent than the conventional coatings
used by the industry.
Low solvent coatings include
wn1-~r-hovrir’ hi-rthr’r -~r~1Iti~,
c1ectr-o-depo~itinn nni’i
coatings.
“Magnet wire” means aluminum
an electromagnetic coil.
or
any
copper wire
coating or
formed into
“Magnet wire coating” means
electrically
insulating varnish or enamel
applied to magnet wire.
“Magnet wire coating facility” mcans
a facility that
includes one or more magnet wire coating line(s) .
“Magnet wire coating line” means a coating line in
which any protective, decorative, or functional coating
is applied onto the surface of a magnet wire.
“Malfunction” means
any sudden and unavoidable failure
of air pollution control equipment, process equipment,
or a process to operate in a normal or usual manner.
Failures that are caused entirely or in part by poor
maintenance, careless operation, or any
other
preventable upset condition or preventable equipment
breakdown shall not
be
considered malfunctions.
“Manufacturing process” means a method whereby a
process emission source or series of process emission
I
~
u~ed
t~
mu
mater I
n 1 ~
-
0 1L~0-0783
product,

subsequent
377
“Material Recovery Section” means any equipment
designed ~—~-p~
~‘r~
and rccovcr styrene monomer and
rwn~T im~ur11-1r~
ri-rim
ofhr’r r~vr~ductoand
by—products
in
a ~O...2
ja.~...a.’....
plant, includi~iç
styrene dcvolatilizer unit and styrene recovery unit.
1
mn
r~.—‘ fl
-~
“Maximum theoretical emissions” means the quantity of
volatile organic material emissions that theoretically
-could be emitted by a stationary source before add—on
controls- based on the design capacity or maximum
production capacity of the source and 8760 hours per
year. The design capacity or maximum production
capacity includes use of coating(s) or ink(s) with the
highest vo-latile organic material content actually used
in practice by the source. Provided, however, the
Agency shall, when appropriate, and upon request by the
permit applicant, limit the “maximum theoretical
emissions-” of a source by the imposition of conditions
in a federally enforceable operating permit for such
source. Such conditions shall not be inconsistent with
requirement of the Clean Air Act, as amended, or any
applicable requirements established by the Board. Such
conditions shall be established in place of design
capacity or maximum production capacity in calculating
the “maximum theoretical emissions” for such source and
may include, among other things, the establishment of
production limitations, capacity limitations, emission
limitations, or limitati-ons on the volatile organic
material content of coatings or inks, or
the hours- of
operation of any emission source, or a combination of
any such limitations.
Production or capacity
limitations s-hall
be
established
on basis of no longer than one month except in those
cases where a limit s-panning a longer period of time is
appropriate. In such cases, a rolling limit” shall be
employed. Any production or capacity limitations s-hall
be verified through appropriate recordkccping. (Board
Note: The UCEPA may deem operating perxnits which do
not conform to the operating permit program
requirements and the requirements of USEPA’s underlying
regulations,
including the requirement that limitations
be quantifiable and enforceable
as a practical matter,
not “federn11~’ enforceable.”)
“Metal furniture” means a furniture piece including,
but not limited to, tables, chairs, waste baskets,
beds, desks, lockers, benches, shelving, file cabinets,
mm
rriom
dividers-.
01 ~0-078L.~

378
~
means any non-adhesi..
coating applied to any furniture piece made of metal or
any metal part which is- or will be assembled with other
metal, wood, fabric, plastic or glass parts to form a
furniture piece including, but not
limited to, tables,
aba-irs, was-to baskets, beds, desks, lockers, benches,
shelving, file cabinets, lamps-, and room dividers.
Th-is definition shall not apply to any coating line
coating miscellaneous metal parts or products-.
“Metal furniture coating facility” means- a facility
that includes one or more
metal
furniture coating
line(s).
“Metal furniture coating line” means- a coating line in
which any protective, decorative, or functi-onal coating
is- applied onto the surface of metal furniture.
“Metallic shoe—type seal” means- a primary or secondary
seal constructed of metal sheets (shoes-) which ar-c
joined together to form a ring, springs, or levers
which attach the shoes to the floating roof and hold
the shoes- against the tank wall, and a coated fabric
which is suspended from the shoes to the floating roof.
icllaneous taor~tcat~cu
nmouuci~. manuiaut.uring
--
A manufacturing process involving one or more of
the following applications,
including any drying
and curing of
formulations, and capable of
emitting VON:
Adhesives to fabricate or assemble components
or products
Asphalt solutions
to
paper or fiberboar-d
Asphalt to paper or felt
Coatings or dye to leather
n~
~
Coatings to rubber or glass
Disinfectant material to manufactured i~’~”~
Plastic foam scrap or “fluff” from the
manufacture of foam containers- and packaging
material t-o form resin pallcts
01 ~0-0785

379
~in solution
Viscose solutions for food casings
The storage and handling of formulations
associated with the process described above, and
the use and handling of organic liquids- and other
substances for clean—up operations associated with
the nrpcess- described in this definition.
means“Miscellaneous
:
formulation manufactur1
A manufacturing process which compounds one or
more of the following and is capable of emitting
VON:
Adhesives
Asphalt solutions
Caulks, scalants, or waterproofing agents
Coatings, other than paint and ink
Concrete curing—comoounds
Dyes
Friction materials and comDounas
1(c3ln solutions
flubbcr solutions
Viscose solutions
The storage and handling of formulations
associated with the process described above, and
the use and handling of organic liquids and other
substances for clean—up operations associated with
the process described in this definition.
“Miscellaneous metal parts or products” means any metal
part or metal product, even if attached to or
combined
with
a
nonmetal part or product, except
cans,
coils,
metal furniture, large appliances, magnet wire,
automobiles, s-hips-, and airplane bodies.
“Miscellaneous- metal parts and products coating” means
any coating applied to any metal part or metal product,
even if attached to or combined with a nonmetal part or
01 ~o-0786

“M~isccllaneousmetal
r
or-ill r~r
I
parts
~..
~eating
~
aiaa.~,
-l4~~in which an1 protccti~e~
decorative, or functional coating
is applied onto the
surface of
miscellaneous metal parts or products.
“Misccllancous organic chemical manufacturing process”
means:
A manufacturing process which produces, by
chemical reaction, one or more of the following
organic compounds or mixtures of organic compounds
and which is capable of omitting VON:
Chemicals
listed in Appendix A of this Part
Cosmetic, detergent, soap, or
intermediaries or specialties
surfactant
and products
Disinfectants
Fond ndditive~
Oil and petroleum p
additives
Resins or pol~crs
t?iuhhr’r
nrld
it-i
~r”~
Sweetener-s
Ut b~U-0787
product, e
app-liances
380
-I .C.._~__
±
.S_.._.__
~
surfacer coat, topcoat, and final repair coat for
automobiles and light—duty trucks arc not miscellaneous
metal parts and products coatings. However, underbody
anti—chip (e.g., underbody plasticol) automobile and
light-duty truck coatings are miscellaneous metal parts
a-nd products coatings. Also, automobile or light-duty
truck refinishing coatings, coatings- applied to the
exterior of marine vessels-, coatings applied to the
exterior of aii~plancs, and the customized topcoating of
a-utcmobilcc and trucks if production is less than 35
vehicles per day arc not miscellaneous metal parts and
products coatings.
“Miscellaneous metal parts or products coating
facility” means a facility that includes one or—more
miscellaneous metal parts or products coating lines.

Varnishes
381
The storage and handling of formulations
associated with the process- described ab_ -
the use and handling of organic liquids and other
substances for clean—up operations associated with
th-~nmoc~~ described in this defini~ion~
to measure and reeor-d
“Multiple package coating”
more tnan uw. ~rrercnt ....ngrcctient which must be mixed
prior to using and has a limited pot life due to the
chemical reaction which occurs upon mixing.
“No Detectable Volati-le Organic Material Emissions”
means a discharge of volatile organic material into the
atmosphere as indicated by an instrument reading -of
less than 500 ppm above background as determined in
accordance with 40 CFR 60.485(c).
“Offset” means, with respect to printing and publishing
oncrni-ion~ n’~c
of n hlnnki—F ct’lindcr to
tmnn~fcr in-k
from the plate cylinder to—the surface to be printed.
t stains.
11-Open
top vapor
dcgrcao-ing” means the batch process of
cleaning and removing soils from surfaces by condensing
hot solvent vapor on the colder metal parts.
“Open—ended valve” means any valve, except pressure
relief devices, having one side of the valve in contact
with process fluid and one side open to the atmosphere,
either directly or through open piping.
“Operator of Gasoline Dispensing Facility” means any
person
who is the lessee of or
operates, controls or
supervises- a gasoline dispensing facility.
“Organic compound” means any
compound of carbon,
excluding carbon monoxide, carbon dioxide, carbonic
ac-id, metallic carbides or carbonates,
and ammonium
carbonate.
“Organic material”
means any chemical
compound of
carbon including diluents
and thinners which are
lirniirl-i nt ‘~t-nnrinrd r~orir1it-irin~ nrid
trhir~h
nrc iu’~cd
vi~uo~.i.~.Lyr~uuucr~,
UL
w.eanlng agents, but
excluding methane, carbon monoxide, carbon- dioxide,
carbonic acid, metallic carbonic acid, metallic
~_I___
-~-_
01 L~Q-Q788

382
carbide,
“Organic
metallic carb
vapor” means
onatos, and
the gaseous
ainmonium
phase of
carbonate.
an organic
material or a mixture
of organic materials present in
the atmo sphere.
urpose~:
• I Ii. t~
‘~mbcr Wlthlaa ,qhich heat i.... ~ed for
~‘
-~ngp
~
1——i—
,
~-
It r~yv.—.eS,—~.S.—.n,sr.~
vi a a
4.. p~.fl
Th
,LL~~A
a
a
U
a
v.a.
operatcs, leases, controls, or supervises- an emission
source or air pollution control equipment.
“Packaging rotogravure printing” means rotogravure
printing upon paper, paper board, mcta-l foil, plastic
film, and other substrates, which are, in subsequent
operations, formed into packaging products or labels
for articles to be sold.
“Packaging rotogravure printing line” means a
rotogravure printing line in which surface coatings arc
applied to paper, paperboard, foil, film, or other
substrates which are to be used to produce containers,
packaging products, or labels for articles.
“Paint manufacturing plant” means a plant that mixes,
blends, or compounds enamels, lacquers, scalers,
shellacs, stains, varnishes-, or pigmented surface
coatings-.
“Paper coating” means any coating applied on paper,
plastic film, or metallic foil to
make certain
products, including (but not limited to) adhesive tapes
and labels, book covers, post cards, office copier
paper, drafting paper, or pressure sensitive tapes.
Paper coating includes the application of coatings by
impregnation and/or saturation.
“Paper coating facility” means a facility that includes
one or more paper coating lines.
01
L~o-EJ789
mr~an~
~i
(TITi fT f)i-
TTI ~T4~
(1
T
iT fl UT T Li
I I oW I
or polymerizc
“Overall control” means the product of the capture
efficiency and the control device efficiency.
“Overvarnish” means a transparent coating applied
directly over ink or coating.
“Owner of Casoline Dispensing Facility” means any
person who has legal or equitable title to a stationary
storage tank at a gasoline dispensing facility.

383
“Paper coating line” means a coating line in which any
p~-otectivo, decorative, or functional coating is
applied on, saturated into, or impregnated into paper,
plastic film, or metallic foil to make certain
products, including (but not limited to) adhesive tapes-
and labels, book covers-, post cards-, office copier
paper, drafting paper, and pressure sensitive tapes.
“Parts per million (volume)” means a volume/volume
ratio which expresses the volumetric concentration of
gaseous air contaminant in a million unit volume of
gas-i-
“Person” means any individual, corporation,
partnership, association,
S-tate, municipality-i-
political subdivision of a State; any agency,
department, or instrumentality of the United States;
and any officer, agent, or employee thereof.
“Petroleum” means the crude oil removed from- the earth
and the oils derived from tar sands, shale, and coal.
“Petroleum Liquid” means crude oil, condensate or any
finished or intermediate product manufactured at a
petroleum refinery, but not including Number 2 through
Number 6 fuel oils as specified in ASTM D-396-69, gas
turbine fuel oils Numbers 2-CT through 4-CT as
specified in ASTM D-2880-7l or diesel fuel oils
Numbers
~‘
~
and
-~—‘~ -~
soccified in ASTM ~
“Petroleum refinery” means any facility engaged in
producing gasoline, kerosene, distillate
fuel oils,
residual fuel oils, lubricants, or other products
through distillation of petroleum, or through
redistillation,
cracking-, or reforming of unfinished
n~trn1r~iimzicri~rn1-~ivc-~-~
“Pharmaceutical” means any compound or mixture, other
than food, used in the prevention, diagnosis,
aiicv~.ation,
treatment,
--
~.
,____,,,___~~
~
uiseas-c
,P
in
--
numan and
animal.
“Pharmaceutical coating operation” means a device in
which a coating is applied to a pharmaceutical,
including air drying or curing of the coating.
“Photochemically Reactive Material” means- any organic
material with an aggregate of more than 20 percent of
its total volume composed of the chemical compounds
classified
below or the composition of which exceeds
any of the following individual percentage composition
limitations. Whenever any photochomically reactive
01 ~~-Q790

384
material or any constituent of any organic material
may
be classified from its chemical structure into more
than one of the above groups of organic materials it
shall be considered as a member of the most reactive
group, that is, the group having the least allowable
percent of the total
organic materials.
~~at
aldehydes, esters, ethers or icctonc~having an
olefinic or cyolo—olefinic types of unsaturation:
5 percent. This definition
does not apply
perchloroethylcne or trichloroethylene.
to
A combLa...—
t±~..,a,~ .aa. ,...a...2~?a....
more carbon atoms to the molecule except
cth~r1h~n~~nr’, $~ r~rvit~
A combination of ethylbenzcne, ketones having
branched hydrocarbon structures or toluenc: 20
percent.
“Pigmented coatings-” means opaque coatings- containing
binders and colored pigments which are formulated to
conceal the wood surface either as- an undercoat or
topcoat.
“Plant” means- all of the pollutant-emitting activities-
which belong to the same industrial grouping, arc
located on one or more contiguous- or adjacent
properties, and arc under the control of the same
person (or persons
under common control), except
the
activities
of any marine vessel.
Pollutant-emitting
activities- shall be considered as part of the same
industrial grouping if they belong to the same “Major
Croup” (i.e., which have the same two—digit code) as
described in the “Standard Industrial Classification
(incorporated by reference in Section
“Plasticizers” means a substance added to a polymer
composition to soften and add flexibility to the
product.
“Pneumatic Rubber Tire Manufacture” means the
production of pneumatic rubber tires with a bead
diameter up to but not including 20.0 inches- and cross
section dimension up to 12.8 inches, but not including
specialty tires- for antique or other vehicles when
produced on equipment separate from normal production
lines for passenger or truck type tires-.
“Polystyren~
~
means- any plant using styrene to
0! kO-079 1
comoounds with eight or

styrenc polymer and additivcs which is-manufactured a-t
a polystyrene plant.
“Pressure Release” means the emission of materials-
resulting from system pressure being greater than set
pressure of the pressure relief -device.
~Pressurp Tank” means a tank in which fluids arc stored
at a pressure greater than atmospheric pressure.
the first of two or more coatings
“Prime surfacer coat” moans a coating us-cd to touch up
areas on the surface of automobile or light-duty truck
bodies not adequately covered by the prime coat before
application of the top coat.
The prime surfacer coat
is applied between the prime coat and topcoat. An
anti-chip coating applied to main
body parts (e.g.,
rocker panels, bottom of doors and fenders, and leading
edge of roof) is a prime surfacer coat.
“Primers” means any coatings formulated and applied to
substrates to provide a firm bond between the substrate
and subsequent coats.
“Printing” means the application of words, designs, and
pictures to a substrate using ink.
~‘Printing line” means
an operation consisting of a
~ric~ of onc or ~orr roll
printers and an-u
orintx’d
roll coatcrs, drying areas, and ovens wherein one or
more coatings arc applied, dried, and/or cured.
-“Process” means any stationary emission source other
than a fuel combustion emission source or an
incinerator.
“Process Unit” means components assembled to produce,
as intermediate or final products, one or
more
of the
chemicals listed in 35 Ill. Adm. Code 219 Appendix A.
k process unit can operate independently if supplied
with sufficient feed or raw materials- and sufficient
storage facilities
for the product.
“Process Unit Shutdown” means a work practice or
operational procedure that s-tops production from a
process unit or part of a process unit.
An unscheduled
work practice or operational procedure that
stops
0 I L~.Q-3792
385
manuracture poiystyrene resin.
_J.I..
_.~
II
l.a..—

386
production from a process unit or part of a process
unit for less than 24 hours- is not a process- unit
shutdown.
The us-c of spare components- and technically
feasible bypassing of components without stopping
production is not a
process unit shutdown.
“Production equipment exhaust system” means a system
f-or
collecting and
directing
into the atmosphere
emissions- of
volatile
organic material from reactors,
centrifuges, and
other process emission sources.
“Publication rotogravure printing line” means- a
rotogravure printing line in which coatings are applied
to paper which is- subsequently formed into books,
magazines, catalogues,
brochures-,
directories,
newspaper supplements-, or other types- of printed
material.
~urged Process Fluid” means liquid or vapor from a
process-
unit that contains volatile organic material
and that results from flushing or cleaning the sample
line(s) of a process unit so that an uncontaminated
sample may then be taken for testing or analysis.
“Reactor” means a vat, vessel, or other device in which
chemical reactions take place.
-~
~-4.
rnr’
ifThc..
r’rni
~r,tirri
nn
~J
~y ~v~lablc Ci 1 Technol~ (RACT)~
~l
I
4en ‘4.mitation that an
is capable of meeting by the application of control
technology that is reasonably available considering
technological and economic feasibility.
.-
1UCUfl~3
. .
rvn
~~f~1i-rrT~
“Refiner” means any person who owns, leases, operates-,
controls, or supervises a refinery.
“Refinery Fuel Gas” means any gas- which is generated by
a petroleum refinery process unit and which is
combusted at the refinery, including any gaseous
mixture of natural gas- and fuel gas.
“Refinery unit, process- unit or unit” moans- a set of
components which arc a part of a basic process
operation such
as distillation, hydrotrcating,
-c-racking, or reforming of hydrocarbons.
“Refrigerated condenser” means a surface condenser in
which the coolant supplied to the condenser has been
cooled by a
mechanical device, other than by
a cooling
tower or evaporative spray cooling, such a-s
r~fri~crntion
unit or steam cliillcr
unit.
01 ~0-0793

387
“Reid vapor pressure” mcans
the standardized measure of
the vapor pressure of a liquid in pounds per square
inch absolute (Ps-ia) at 100°F (37.8°C).
“Repair coatings” means coatings used to correct
imperfections or damage to furniture surface.
Th
#~S-
l.a —
..or the
~
Part, that equipment component has b
“Residual Fuel Oil” means fuel oils of grade No. 4, 5
and 6 as specified in detailed requirements for fuel
oils A.S.T.M. D—396—69 (1071).
“Retail Outlet” means- any gasoline dispensing facility
at
which gasoline is sold or offered for sale for us-c
in motor
v~hiclr~.
“Roll copter” means an apparatus in which a uniform
layer of coating is applied by means- of one or more
roiis across tne entire wiutn oi a moving ~u~tr~.ttc.
“Roll printer”
means an apparatus used in the
application of words, designs, and pictures to a
substrate, usually by means of one or more rolls each
with only partial coverage.
“Roll printing” means the application of words,
designs, and pictures to a substrate usually by means-
of a s-cries of hard rubber or metal rolls each with
only partial coverage.
“Roller coating” means a method of applying a coating
to a sheet or strip in which the coating is transferred
by a roller or series of rollers.
“Rolling limit” means- that a limit or limitation must
not exceed an annual limit rolled on a basis of at most
a month monthly basis; that is, for example, a monthly
4 1I
1
.-.4—
-l-~-.
~4 ~4—
~
4
,..
each parameter subject to a production or capacity
limitation and added to the eleven prior monthly levels
for monthly comparison with the annual limit.
“Rotogravure printing” means the application of words,
designs, and pictures to a substrate by means of a roll
printing technique in which the pattern to be applied
is recessed relative to the non—image area.
“Rotogravure printing line” moans a printing line in
which each roll printer uses- a roll with recessed areas-
0 ~O-07914
~ur~nar
~Qofthi...
adjusted, or
production or

for applying
388
-
.l....a -
“Safety relicf valye” means a valve whidh is normally
closed and which is- designed to open in order to
~e-licve excessive pressures- within a vessel or pipe.
“Sanding scalers” means any coatings formulated for and
applied to bare wood for sanding and to seal the wood
-f-o-r
subsequent application of varnish.
To be
considered a sanding scaler a coating must be clearly
labelled as such.
“Scaler” means a coating containing binders which seals
wood
prior
to
the application of the subsequent
-e-eatingc.
“r~enspr”
-~
iIc’-ui nr’ t~h~-fmc~~iirr~.~ ~h~.r’~i
r~~l
quantity or the change in a physical quantity such as
temperature, pressure, flow rate, pH, or liquid level.
“-Semi-transparent stains” means stains containing dyes-
or semi-transparent pigments which are formulated to
ennance wooa
~—
and cha..~ the colcr of the ~f-a-~.....
but not to conceal the surface, including, but not
1-imited to, sap stain, toner, non—grain raising stains,
pad stain, or spatter stain.
“Set of safety relief valves” means one or more safety
relief valves designed to open in order to relieve
excessive pressures in the -same vessel or pipe.
“-Sheet basccoat” means a coating applied to metal when
t-hc metal is- in sheet form to serve as either the
-exterior or interior of a can for either two-piece or
~.as..
a...’.—
“Side—s-cam spray coat” means a coating applied to the
s-eam
of a three—piece can.
“Single -coat” means one coating application applied to
a metal surface.
“-Solvent” moans a liquid substance that is us-ed to
dissolve or dilute another substance.
“Solvent cleaning” means the process of cleaning soils
from surfaces by cold cleaning, open top vapor
d-cgreasing, or conveyorized dcgreasing.
“Specified air contaminant” means any air contaminant
as to which this- Part contains emission standards or
othor
~Trnr~cific
limit~tinn~
01
~o-0795

389
“Splash loading” means a method of loading
ci
tank,
railroad tank car, tank truck,
or trailer by use of
other than a submerged loading pipe.
“Stack” means a flue or conduit, free—standing or with
exhaust port above the roof of the building on which it
is mounted, by which air contaminants arc emitted into
the atmosphere.
“Standard conditions” means- a temperature of
7-0°Fand a
pressure 0-f 14.7 ps-ia.
-“Standard cubic foot (s-of)” means the volume of one
cubic foot of gas at standard conditions.
“Standard Industrial Classification Manual” means the
Standard Industrial Class-ificati-on Manual (1987),
Superintendent of Documents, U.S. Government Printing
Office, Washington, DC 20402 (incorporated by reference
in Section 219.112).
“Start—up”
means the setting in operation of an
emission source for any purpose.
“Stationary emission source” mean an emission source
which is- not self-propelled.
-“-Storage tank or storage vessel” means any stationary
tank, reservoir or container used
f-or the storage of
VOL.
“Ctyrcne Devolatilizcr Unit” moans equipment performing
the function of separating urircacted styrenc monomer
and other volatile components from polystyrene in a
vacuum devolatilizer.
“Ctyrene Recovery Unit” means- equipment performing the
f-unction of separating styrene monomer from other loss
volatile components of the s-tyrcne-dcvolatilizer
unit’s
output.
The separated otyrenc monomer may be reused as
a raw material in the polystyrene p1-ant.
“Submerged loading pipe” means any discharge pipe or
nozzle which meets either of the following conditions:
Where the tank is filled from tnc top, tne ena OL
the discharge pipe or nozzle must be totally
submerged when the liquid level is- 15 cm (6 in.)
above the bottom of the tank.
Where the tank is filled from the s-ide, the
discharge pipe or nozzle must be totally submerged
0! i~0-0796

390
the liquid lcv~
~,a ~a-P
4—~-~~—~
4...—~....1,.
/,ta
~
the
“Substrate” means the
cc onto which a coating is-
ting is impregnated.
means a device which removes- a
~_1__
J~
“Trans-f
~
+1~
ting solids deposited
-part
total amount of coating solids- us-cd.
“Tread End Cementing” means
~lvont-bas-cdcement to the t
the application
“True vapor pressure” means the equilibrium partial
pressure exerted by a volatile organic liquid as-
determined in accordance with methods- described in
American Petroleum Institute Bulletin 2517,
“Evaporation Loss From Floating Roof Tanks,” second
edition, February 1980 (incorporated by reference in
Section 210.112).
“Turnaround” means- the procedure of shutting down a-n
0
substance from a gas stream by reducing
LIIe
L-~1apeLutUre
of the stream, without direct contact between the
coolant and the stream.
“Synthetic Organic Chemical or Polymer ~anufacturing
Plant” means- a plant that produces, as- intermediates or
final products, one or more of the chemicals or
polymers- listed in 35 Ill. Adm. Code 219 Appendix A.
“Tablet coating operation” means- a pharmaceutical
coating operation in which tablets arc coated.
“Thirty—day rolling average” means any value
arithmetically averaged over any consecutive
thirty-days.
“Three-piece can” means a can which is- made from a
rectangular sheet and two circular ends.
“Topcoat” means a coating applied in a multiple coat
operation other than prime coat, final repair coat, or
prime surfacer coat.
“Topcoat operation” means- all topcoat spray booths-,
flash-off areas-, and bake ovens at a facility which arc
used to apply, dry, or cure the final coatings (except
final off-line repair) on component-s of automobile or
light-duty truck bodies.
r’
r~fio of the amount
~oduct to
of
the

operating
Unregulated safety relief valve” means a safety relief
valve which cannot be actuated by a means other than
h-igh pressure in the pipe or vessel which it protects.
“Vacuum producing system” means any reciprocating,
rotary, or centrifugal blower or compressor or any jet
ejector or device that creates suction from a pressure
below atmospheric and discharges against a greater
pressure.
1tValves not externally regulated” means valves- that
have no external controls, such as in—line check
‘~a1vcs.
“Vapor balance system” means any combination of pipes
or hoses which creates a closed system between the
vapor spaces- of an unloading tank and
ci
receiving tang
such that vapors displaced from the receiving tank are
transferred to the tank being unloaded.
“Vapor collection system” means all piping, seals,
hoses, connections, pressure—vacuum vents, and other
possible sources between the gasoline delivery vessel
and the vapor processing unit and/or the storage tanks
and vapor holder.
“Vapor control system” means any system that limits or
prevents- release to the atmosphere of or-ganic material
in the vapors displaced from a tank during the transfer
of gasoline.
“Vapor—Mounted Primary Seal” means- a primary seal
mounted with an air space bounded by the bottom of the
primary zeal, the tank wall, the liquid ~urfaco and the
floating roof.
ri-co-~rcr~’
s-~wi1r~m”
means a vapor gathering sy’~icn~i
-
y.--
01 L~.Q-0798
391
contents to do incpcction, maintenance and rcpair work,
and
putting the unit back into
production-i-
“Two—piece can” means a
can which is drawn from a
s-hallow cup
and requires only one
end to be attached.
“Undcrooatcrs” moans any coatings formulated for and
applied to substrates to provide
a smooth surface for
subsequent coats.
“Undcrtread Cementing” means
the application of a
1—r,
1—hr’
11n~~r’~i~i— of ~ tirr’
+~rc.,rL
.1
.1
....apable of collcctL.., ~...llVOM ...pors and

392
discharged from the storage tank and a vapor disposal
system capable of processing such VOM vapors a-nd gases-
so as to prevent their emission to the atmosphere.
“Vehicle” means a device by which any person o-~
property may be propelled, moved, or drawn upon a
highway, excepting a device moved exclusively by human
power or used exclusively upon stationary rails or
tracks.
“Vinyl coating” means any topcoat or printing ink
applied to vinyl coated fabric or vinyl sheets. Vinyl
coating does- not include plas-tis-ols-.
“Vinyl coating facility” means a facility that includes
one or more vinyl coating line(s).
“Vinyl coating line” means a coating line in which any
orat~c~tiiv~,decorative or functional coating is applied
“Volatile organic liquid (VOL)” means any substance
which is- liquid at storage conditions and whioh
contains volatile organic compounds.
1
1
I
_
~_~...!
—I
21
V ..t.4.
Ia.
~
£LLLL CCI~4.CL~
~V~fl
JJJ.
~V SF..L ~3L~ 4. 4.~
S_IJ.
ct...
.1..
s...
compound (VOC)” means “volatile organic material (VOM)
or volatile
organic compound (VOC)”,
as that term is
defined in 35 Ill. Adm. Code Part 211.
“-Volatile Petroleum Liquid” means- any petroleum liquid
with a true vapor pressure that is greater than 1.5
ps-ia (78 millimeters of mercury) at standar4
conditions.
“Wash coat” means a coating containing binders which
seals wood surfaces-, prevents undesired staining, and
controls ~cnctration.
“Was-tcwatcr (Oil/Water) Separator” means any device or
piece of equipment which utilizes the difference in
density between oil and water to remove oil and
associated chemicals- from water, or any device, s-us-h as
a flocculation tank or a clarifier, which removes
petroleum derived compounds from waste water.
“Web” moans a substrate which is printed in continuous-
roll—fed press-cs.
“Wood furniture” means room furnishings including
cabinets (kitchen, bath, and vanity), tables, chairs-,
beds,
sofas, shutters-, art
objects, wood paneling, wood
01 ~40O799

393
flooring, and any other coated furnishings- ma-dc of
wood, wood composition, or fabricated wood matcrials-~-
“Wood furniture coating facility” means a facility that
includes one or more wood furniture coating line(s).
“Wood furniture coating line” means a coating line in
which any protective, decorative, or functional coating
is- ~
onto wooa rurniturc.
“Woodworking” means the shaping, sawing, grinding,
smoothing, polishing, and making into products of any
form or shape of wood.
The definitions of 35 Ill. Adm. Code 211 apply to this Part.
(Source:
Amended at
Ill. Reg.
______,
effective
__________)
Section 219.105
Test Methods and Procedures
a) Coatings, Inks and Fountain Solutions
The following test methods and procedures shall be used
to determine compliance of as applied coatings, inks,
and fountain solutions with the limitations set forth
in this Part.
1) Sampling: Samples collected for analyses shall be
one—liter taken into a one—liter container at a
location and time such that the sample will be
representative of the coating as applied (i.e.,
the sample shall include any dilution solvent or
other VOM added during the manufacturing process).
The container must be tightly sealed immediately
after the sample is taken. Any solvent or other
VOM added after the sample is taken must be
measured and accounted for in the calculations in
subsection (a) (3) of this Section. For multiple
package coatings, separate samples of each
component shall be obtained. A mixed sample shall
not be obtained as it will cure in the container.
Sampling procedures shall follow the guidelines
presented in:
A) ASTM D3925—81(1985) standard practice for
sampling liquid paints and related pigment
coating. This practice is incorporated by
reference in Section 219.112 of this Part.
B) ASTM E300-86 standard practice for sampling
industrial chemicals. This practice is
01 L10-0800

394
incorporated
by reference in Section 219.112
of this Part.
2) Analyses: The applicable analytical methods
specified below shall be used to determine the
composition of coatings, inks, or fountain
solutions as applied.
A) Method 24 of 40 CFR 60, Appendix A,
incorporated by reference in Section 219.112
of this Part, shall be used to determine the
VON content and density of coatings. If it
is demonstrated to the satisfaction of the
Agency and the USEPA that plant coating
formulation data are equivalent to Method 24
results, formulation data may be used. In
the event of any inconsistency between a
Method 24 test and a facility’s formulation
data, the Method 24 test will govern.
B) Method 24A of 40 CFR Part 60, Appendix A,
incorporated by reference in Section 219.112,
shall be used to determine the VOM content
and density of rotogravure printing inks and
related coatings. If it is demonstrated to
the satisfaction of the Agency and USEPA that
the plant coating formulation data are
equivalent to Method 24A results, formulation
data may be used. In the event of any
inconsistency between a Method 24A test and a
facility’s formulation data, the Method 24A
test will govern.
C) The following ASTM methods are the analytical
procedures for determining VON:
i) ASTM D1475-85: Standard test method for
density of paint, varnish, lacquer and
related products. This test method is
incorporated by reference in Section
219.112 of this Part.
ii) ASTN D2369-87: Standard test method for
volatile content of a coating. This test
method is incorporated by reference in
Section 219.112 of this Part.
iii) ASTM D3792-86: Standard test method for
water content of water—reducible paints
by direct injection into a gas
chromatograph. This test method is
incorporated by reference in Section
01 L~0-U8OI

395
219.112 of this Part.
iv) ASTM D40l7-81(l987): Standard test
method for water content in paints and
paint materials by the Karl Fischer
method. This test method is incorporated
by reference in Section 219.112 of this
Part.
v)
ASTM D4457-85: Standard test method for
determination of dichioromethane and
1,1,1, trichloroetháne in paints and
coatings by direct injection into a gas
chromatograph. (The procedure
delineated above can be used to develop
protocols for any compounds specifically
exempted
from the definition of VON.)
This test method is incorporated by
reference in Section 219.112 of this
Part.
vi) ASTM D2697-86: Standard test method for
volume non—volatile matter in clear or
pigmented coatings. This test method is
incorporated by reference in Section
219.112 of this Part.
vii) ASTM D3980-87: Standard practice for
interlaboratory testing of paint and
related materials. This practice is
incorporated by reference in Section
219.112 of this Part.
viii)ASTM El80—85: Standard practice for
determining the precision data of ASTM
methods for analysis of and testing of
industrial chemicals. This practice is
incorporated by reference in Section
219.112 of this Part.
ix) ASTN D2372-85: Standard method of
separation of vehicle from
solvent-reducible paints. This method is
incorporated by reference in Section
219.112 of this Part.
D) Use of an adaptation to any of the analytical
methods specified in subsections (a) (2) (A),
(B), and (C) of this Section may not be used
unless approved by the Agency and USEPA. An
owner or operator must submit sufficient
documentation for the Agency and USEPA to
01 ~O-O802

396
find that the analytical methods specified in
subsections (a)(2)(A), (B), and (C) of this
Section will yield inaccurate results and
that the proposed adaptation is appropriate.
3) Calculations: Calculations for determining the
VON content, water content and the content of any
compounds which are specifically exempted from the
definition of VOM of coatings, inks and fountain
solutions as applied shall follow the guidance
provided in
the following documents--:
A) “A Guide for
Surface Coating Calculation”,
EPA-340/1-86-016, incorporated by reference
in Section 219.112 of this Part.
B) “Procedures for Certifying Quantity of
Volatile Organic Compounds Emitted by Paint,
Ink and Other Coatings” (revised June 1986),
EPA-450/3—84—019, incorporated by reference
in Section 219.112 of this Part.
C) “A Guide for Graphic Arts Calculations”,
August 1988, EPA—340/l—88-003, incorporated
by reference in Section 219.112 of this Part.
b) Automobile or Light-Duty Truck Test Protocol
~ The protocol for testing, including determining
the transfer efficiencyT of coating applicators~
at primer surfacer operations and topcoat coating
operations at an automobile or light-duty truck
assembly facility source shall follow the
procedure in: “Protocol for Determining the Daily
Volatile Organic Compound Emission Rate of
Automobile and Light-Duty Truck Topcoat
Operations” (“topcoat protocol”), December 1988,
EPA-450/3-88-018, incorporated by reference in
Section 219.112 of this Part.
~ Prior to testing pursuant to the topcoat protocol,
the owner or operator of a coating operation
sublect to the topcoat or primer surfacer limit in
Sections 219.204(a) (2) or 219.204(a) (3) shall
submit a detailed testing proposal specifying the
method by which testing will be conducted and how
compliance will be demonstrated consistent with
the topcoat protocol.- The proposal shall include,
at a minimum, a comprehensive plan (including a
rationale) for determining the transfer efficiency
at each booth through the use of in—plant or pilot
testing, the selection of coatings to be tested
01 I~0-0803

397
(for the purpose of determining transfer
efficiency) including the rationale for coating
groupings, the method for determining the analytic
VOM content of as applied coatings and the
formulation solvent content of as applied
coatings, and a description of the records of
coating VON content as applied and coating’s usage
which will be kept to demonstrate compliance.
Upon approval of the proposal by the Agency and
USEPA, the compliance demonstration for a coating
line may proceed.
c) Capture System Efficiency Test Protocols
1) Applicability
The requirements of subsection (c) (2) of this
Section shall apply to all VON emitting processee
emission units employing capture equipment (e.g.,
hoods, ducts), except those cases noted below.
A) If a source installs-an emission unit is
equipped with (or uses) a permanent total
enclosure (PTE) that meets Agency and USEPA
specifications, and which directs all VON to
a control device, then the sourccemission
unit is exempted from the requirements
described in subsection (c) (2) of this
Section. The Agency and USEPA specifications
to determine whether a structure is
considered a PTE are given in Procedure T of
Appendix B of this Part. In this instance,
the capture efficiency is assumed to be 100
percent and the sourceemission unit is still
required to measure control efficiency using
appropriate test methods as specified in
subsection (d) of this Section.
B) If a source uses-an emission unit is eguipped
with (or uses) a control device designed to
collect and recover VON (e.g., carbon
adsorber), an explicit measurement of capture
efficiency is not necessary provided that the
conditicns given below are met. The overall
control of the system can be determined by
directly comparing the input liquid VON to
the recovered liquid VON. The general
procedure for use in this situation is given
in 40 CFR 60.433, incorporated by reference
in Section 219.112 of this Part, with the
following additional restrictions:
01 ~O-08OL~

398
i) The source must be able to equate
solvent usage with solvent recovery on a
24-hour (daily) basis, rather than a
30-day weighted average, within 72 hours
following the 24-hour period.
In
addition, one of the following two
criteria
must be met: Unless otherwise
specified in subsection (c) (1) (B) (ii)
below, the source owner or operator
shall obtain data each operating da~ for
the solvent usage and solvent recovery
to permit the determination of the
solvent recovery efficiency of the
system each operating daY using a 7-day
rolling period.
The recovery efficiency
for each operating day is computed as
the ratio of the total recovered solvent
for that day and the most recent prior 6
operating days to the total solvent
usage for the same 7—day period used for
the recovered solvent, rather than a 30—
day weighted average as given in 40 CFR
60.433 incorporated by reference in
Section 219.112 of this Part. This
ratio shall be expressed as a
percentage. The ratio shall be computed
within 72 hours following each 7-day
period. A source that believes that the
7-day rolling period is not appropriate
may use an alternative multi—day rolling
period not to exceed 30 days, with the
approval of the Agency and USEPA. In
addition, the criteria in subsection
(c) (1) (B) (iii) or subsection
(c) (1) (B) (iv) below must be met.
ii) The owner or operator of the source
en~a~edin printing located at 350 E.
22nd Street, Chicago, Illinois, shall
obtain data each operating day for the
solvent usage and solvent recovery to
permit the determination of the solvent
recovery efficiency of the system each
operating day using a 14-day rolling
period. The recovery efficiency for
each operating day is computed as the
ratio of the total recovered solvent for
that day and the most recent prior 13
operating days to the total solvent
usage for the same
14—day
period used
for
the
recovered solvent, rather than a
30-day weighted average as given in 40
0
~0-0805

399
CFR 60.433, incorporated by reference at
Section 219.112 of this Part.
This
ratio shall be expressed as a
percentage. The ratio
shall be computed
within 17 days following each 14-day
period. In
addition, the criteria in
subsection (c) (1) (B) (iii) or subsection
(c) (1) (B) (iv) below must be met.
The solvent recovery system (i.e.,
capture and control system) must be
dedicated to a single coating line,
printing line, or other discrete
activity that by itself is sublect to an
applicable VON emission standard,
process- line (e.g., one process line
venting to a carbon adsorbcr system), or
If the solvent recovery system controls
more than one coating line, printing
line or other discrete activity that by
itself is subject to an applicable VON
emission standard, the overall control
(i.e. the total recovered VON divided by
the sum of -liquid VOM input from all
lines and other activities venting to
the control system) must meet or exceed
the most stringent standard ap~licab1e
to any line or other discrete activity
venting to the control system.multiplc
process lines, then the source must be
able to demonstrate that the overall
1
/
4
4..
~...
.4.. 4....~
-S..-.-.
4
~o1vcnt VOM divided by the ourn of liquid
VOM
input to all process- lines venting
to the control system) meets or exceeds-
t~hc’~
iiio~* ‘~tringcnt ~r~d
-
2) Specific Requirements
The capture efficiency of a process- 1ine~
emission unit shall be measured using one of the
four protocols given below. Any error margin
associated with a test protocol may not be
incorporated into the- results of a capture
efficiency test. If these techniques are not
suitable for a particular process, then the source
may u-s-c an alternative capture efficiency protocol
may be used, provided that the alternative
protocol is approved by the Agency and approved by
0806
~i~)-iii)
iii)
LiL
~~icabl
for any proces~
~
venting to ~ie
control system.

400
the USEPA as a SIP revision.
A) Gas/gas method using temporary total
enclosure (TTE). The Agency and USEPA
specifications to determine whether a
temporary enclosure is considered a TTE are
given in Procedure T of Appendix B of this
Part. The capture efficiency equation to be
used for this protocol is:
CE
=
Gw/(Gw + Fw)
where:
CE
=
capture efficiency, decimal
fract ion~
Gw
=
mass of VOM captured and delivered
to
control device using a TTE~
Fw
=
mass of fugitive VON that escapes
from a TTE.
Procedure G.2 contained in Appendix B of this
Part is used to obtain Gw. Procedure F.1 in
Appendix B of this Part is used to obtain Fw.
B) Liquid/gas method using TTE. The Agency and
USEPA specifications to determine whether a
temporary enclosure is considered a TTE are
given in Procedure T of Appendix B of this
Part. The capture efficiency equation to be
used for this protocol is:
CE
=
(L
-
Fw)IL
where:
CE
=
capture efficiency, decimal
fract ionj~.
L
=
mass of liquid VON input to process
emission unit
Fw
=
mass of fugitive VON that escapes
from a TTE.
Procedure L contained in Appendix B of this
Part is used to obtain L. Procedure F.l in
Appendix B of this Part is used to obtain Fw.
C)
Gas/gas method using the building or room
01 ~4O-08O7

401
(building or room enclosure)~in which the
affected coating line, printing line or other
sourceemission unit is located~as the
enclosure and in which “F” and “G” are
measured while operating only the affected
line or facilityemission unit. All fans and
blowers in the building or room must be
operated as they would under normal
production. The capture efficiency equation
to be used for this protocol is:
CE
=
G/(G + PB)
where:
CE
=
capture efficiency, decimal
fractionj
G
=
mass of VON captured and delivered
to control devicei.
FB
=
mass of fugitive VON that escapes
from building enclosure~
Procedure G.2 contained in Appendix B of this
Part is used to obtain G. Procedure F.2 in
Appendix B of this Part is used to obtain FB.
D) Liquid/gas method using the building or room
(building or room enclosure)~ in which the
affected coating line, printing line or other
s-ourccemission unit is located~ as the
enclosure and in which “F” and “L” are
measured while operating only the affected
line facility emission unit. All fans and
blowers in the building or room must be
operated as they would under normal
production. The capture efficiency equation
to be used for this protocol is:
CE
=
(L
-
FB)/L
where:
CE
=
capture efficiency, decimal
fract±onl
L
=
mass of liquid VON input to process
emission unit
FB
=
mass of fugitive VON that escapes
from building enclosures.
01 ~0-0808

402
Procedure L contained in Appendix B of this
Part is used to obtain L. Procedure P.2 in
Appendix B of this Part is used to obtain PB.
3) Recordkeeping and Reporting
A) All affected facilities-owners or operator
affected by this subsection must maintain a
copy of the capture efficiency protocol
submitted to the Agency and the USEPA on
file. All results of the appropriate test
methods and capture efficiency protocols must
be reported to the Agency within sixty (60)
days of the test date. A copy of the results
must be kept on file with the source for a
period of three (3) years.
B) If any changes are made to capture or control
equipment, then the source is required to
notify the Agency and the USEPA of these
changes and a new test may be required by the
Agency or the USEPA.
C) The source must notify the Agency 30 days
prior to performing any capture efficiency or
control test. At that time, the source must
notify the Agency which capture efficiency
protocol and control device test methods will
be used.
D) Sources utilizing a PTE must demonstrate that
this enclosure meets the requirement given in
Procedure T (in Appendix B of this Part) for
a PTE during any testing of their control
device.
E) Sources utilizing a TTE must demonstrate that
their TTE meets the requirements given in
Procedure T (in Appendix B of this Part) for
a TTE during testing of their control device.
The source must also provide documentation
that the quality assurance criteria for a TTE
have been achieved.
d) Control Device Efficiency Testing and Nonitoring
1) The control device efficiency shall be determined
by simultaneously measuring the inlet and outlet
gas phase VON concentrations and gas volumetric
flow rates in accordance with the gas phase test
methods specified in subsection (f) of this
Section.
0! ~O-0809

403
2) Any owner or operatorl
~j
~That uses an afterburner or carbon adsorber
to comply with any Section of this Part
Z12.
shall use
Agency and USEPA approved
continuous monitoring equipment which is
installed, calibrated, maintained, and
operated according to vendor specifications
at all times the afterburner or carbon
adsorber is in use except as provided in
subsection (d) (3) of this Section.
The
continuous monitoring equipment must monitor
the following parameters:
A~- .j~ For each afterburner which does not have
a catalyst bed, the Geombustion chamber
temperature of each afterburner.
&)- jj).. For each afterburner which has a
catalyst bed, commonly known as a
catalytic afterburner, the ~emperature
rise across each catalytic afterburner
bed or VON concentration of exhaust.
G)- iii) For each carbon adsorber, ~rtheVON
concentration of each carbon adsorption
bed exhaust or the exhaust of the bed
next in seciuence to be desorbed.
~j Of an automobile or lia~ht-dutytruck primer
surfacer operation or topcoat operation
sublect to subsection (d) (2) (A) above, shall
keep a separate record of the following data
for the control devices, unless alternative
provisions are set forth in a permit pursuant
to Title V of the Clean Air Act:
Jj
For thermal afterburners for which
combustion chamber temperature is
monitored, all 3—hour periods of
operation in which the average
combustion temperature was more than
28°C (50°F) below the average combustion
temperature measured during the most
recent performance test that
demonstrated that the operation was in
compliance.
j~j.. For catalytic afterburners for which
temperature rise is monitored, all
3-hour periods of operation in which the
average gas temperature before the
OkO-OBI 0

404
catalyst bed is more than 28°C (50°F)
below the average gas temperature
immediately before the catalyst bed
measured during the most recent
performance test that demonstrated that
the operation was in compliance.
iii) For catalytic afterburners and carbon
adsorbers for which VON concentration is
monitored, all 3—hour periods of
operation during which the average VON
concentration or the reading of organics
in the exhaust gases is more than 20
percent greater than the average exhaust
gas concentration or reading measured by
the organic monitoring device during the
most recent determination of the
recovery efficiency of a carbon adsorber
or performance test for a catalytic
afterburner, which determination or test
that demonstrated that the operation was
in compliance.
~j An owner or operator that uses a carbon adsorber
to comply with Section 219.401 of this Part may
operate the adsorber during periods of monitoring
equipment malfunction, provided that:
j~.j. The owner or operator notifies in writing the
Agency and USEPA, within 10 days after the
conclusion of any 72 hour period during which
the adsorber is operated and the associated
monitoring equipment is not operational, of
such monitoring equipment failure and
provides the duration of the malfunction, a
description of the repairs made to the
equipment. and the total to date of all hours
in the calendar year during which the
adsorber was operated and the
associated
monitoring equipment was not operational
~j
During such period of malfunction the
adsorber is
operated using timed sequences as
the basis for
periodic regeneration of the
ads orber
Qj The period of such adsorber operation does
not exceed 360 hours in any calendar year
without the approval of the Agency and USEPA
and
Qj.. The total of all hours in the calendar year
01~0-081I

405
during which the adsorber was operated and
the associated monitoring equipment was not
operational shall be reported, in writing, to
the Agency and USEPA by JanuarY 31st of the
following calendar year.
e) Overall Efficiency
1) The overall efficiency of the emission control
system shall be determined as the product of the
capture system efficiency and the control device
efficiency or by the liquid/liquid test protocol
as specified in 40 CFR 60.433, incorporated by
reference in Section 219.112 of this Part, (and
revised by subsection (c) (1) (B) of this Ssction)
for each solvent recovery system. In those cases
in which the overall efficiency is being
determined for an entire line, the capture
efficiency used to calculate the product of the
capture and control efficiency is the total
capture efficiency over the entire line.
2) For coating lines which are both chosen by the
owner or operator to comply with Section
219.207(a), (d), (e), (f), or (g) of this Part by
the alternative in Section 219.207(b) (2) of this
Part and meet the criteria allowing them to comply
with Section 219.207 instead of Section 219.204 ~
this part, the overall efficiency of the capture
system and control device, as determined by the
test methods and procedures specified in
subsections (c), (d) and (e) (1) of this Section,
shall be no less than the equivalent overall
efficiency which shall be calculated by the
following equation:
E
=
(VONa
VOM1/VONa) x 100
where:
E
=
Equivalent overall efficiency of the
capture system and control device as a
percentage~j..
VOMa
=
Actual VON content of a coating, or the
daily-weighted average VON content of
two or more coatings (if more than one
coating is used), as applied to the
subject coating line as determined by
the applicable test methods and
procedures specified in subsection
(a) (-4) (i) of this Part in units of kg
01 ~0-0812

406
VON/l
(lb VON/gal) of coating solids as
appl iedTl
VON1
=
The VON emission limit specified in
Section 219.207(a) or (b)- Sections
219.204 or 219.205 of this Part in units
of kg VON/l (lb VON/gal) of coating
solids as applied.
f) Volatile Organic Material Gas Phase Source Test Methods
The methods in 40 CFR Part 60, Appendix A, incorporated
by reference in Section 219.112 of this Part delineated
below shall be used to determine control device
efficiencies.
1) 40 CFR Part 60, Appendix A, Method 18, 25 or 25A,
incorporated by reference in Section 219.112 g~
this Part as appropriate to the conditions at the
site, shall be used to determine VON
concentration. Method selection shall be based on
consideration of the diversity of organic species
present and their total concentration and on
consideration of the potential presence of
interfering gases. Except as indicated in
subsections (f) (1) (A) and (B) below, the test
shall consist of three separate runs, each lasting
a minimum of 60 mm, unless the Agency and the
USEPA determine that process variables dictate
shorter sampling times.
A) When the method is to be used to determine
the efficiency of a carbon adsorption system
with a common exhaust stack for all the
individual adsorber vessels, the test shall
consist of three separate runs, each
coinciding with one or more complete
sequences through the adsorption cycles of
all the individual adsorber vessels.
B)
When the method is to be used to determine
the efficiency of a carbon adsorption system
with individual exhaust stacks for each
adsorber vessel, each adsorber vessel shall
be tested individually.
The test for each
adsorber vessel shall consist of three
separate runs. Each run shall coincide with
one or more complete adsorption cycles.
2)
40 CFR Part 60, Appendix A, Method 1 or 1A,
incorporated by reference in Section 219.112 ~
01 ~O-0813

407
this Part, shall be used for sample and velocity
traverses.
3) 40 CFR Part 60, Appendix A, Method 2, 2A, 2C or
2D, incorporated by reference in Section 219.112
of this Part, shall be used for velocity and
volumetric flow rates.
4) 40 CFR Part 60, Appendix A, Method 3, incorporated
by reference in Section 219.112 of this Part,
shall be used for gas analysis.
5) 40 CFR Part 60, Appendix A, Method 4, incorporated
by reference in Section 219.112 of this Part,
shall be used for stack gas moisture.
6) 40 CFR Part 60, Appendix A, Methods 2, 2A, 2C, 2D,
3 and 4, incorporated by reference in Section
219.112 of this Part, shall be performed, as
applicable, at least twice during each test run.
7) Use of an adaptation to any of the test methods
specified in subsections (f) (1), (2), (3), (4),
(5) and (6) of this Section may not be used unless
approved by the Agency and the USEPA on a case bY
case basis. An owner or operator must submit
sufficient documentation for the Agency and the
USEPA to find that the test methods specified in
subsections (f)(l), (2), (3), (4),
(5) and (6) ~
this Section will yield inaccurate results and
that the proposed adaptation is appropriate.
g)
Leak Detection Methods for Volatile Organic Material
Owners or operators required by this Part to carry out
a leak detection monitoring program shall comply with
the following requirements:
1) Leak Detection Monitoring
A) Monitoring shall comply with 40 CFR 60,
Appendix A, Method 21, incorporated by
reference in Section 219.112 of this Part.
B) The detection instrument shall meet the
performance criteria of Method 21.
C) The instrument shall be calibrated before use
on each day of its use by the methods
specified in Method 21.
D) Calibration gases shall be:
01 1~O-081
1~

408
i)
Zero air (less than loppm of hydrocarbon
in air); and
ii)
A mixture of methane or n—hexane and air
at a concentration of approximately, but
no less than, 10,000 ppm methane or
n-hexane.
E) The instrument probe shall be traversed
around all potential leak interfaces as close
to the interface as possible as described in
Method 21.
2) When equipment is tested for compliance with no
detectable emissions as required, the test shall
comply with the following requirements:
A) The requirements of subsections (g) (1) (A)
through (g) (1) (E) of this Section above shall
apply.
B) The background level shall be determined as
set forth in Method 21.
3) Leak detection tests shall be performed consistent
with:
A) “APTI Course SI 417 controlling Volatile
Organic Compound Emissions from Leaking
Process Equipment”, EPA—450/2—82-0l5,
incorporated by reference in Section 219.112
of this Part.
B)
“Portable Instrument User’s Manual for
Monitoring VOGM Sources”, EPA—340/ 1—86-015,
incorporated by reference in Section 219.112
of this Part.
C) “Protocols for Generating Unit-Specific
Emission Estimates for Equipment Leaks of
VOG~and VHAP”, EPA-450/3—88-01O,
incorporated by reference in Section 219.112
of this Part.
D) “Petroleum Refinery Enforcement Manual”,
EPA-340/1-80-008, incorporated by reference
in Section 210.122219.112 of this Part.
h) Bulk Gasoline Delivery System Test Protocol
1) The method for determining the emissions of
gasoline from a vapor recovery system are
01
~0-08
15

409
delineated in 40 CFR 60, Subpart XX, Section
60.503, incorporated by reference in Section
219.112 of this Part.
2) Other tests shall be performed consistent with:
A) “Inspection Manual for Control of Volatile
Organic Emissions from Gasoline Marketing
Operations:
Appendix D”, EPA-340/ 1-80-012,
incorporated by reference in Section 219.112
of this Part.
B) “Control of Hydrocarbons from Tank Truck
Gasoline Loading Terminals: Appendix A”,
EPA-450/2-77-026, incorporated by reference
in Section 219.112 of this Part.
i) Notwithstanding other requirements of this Part, upon
request of the Agency where it is necessary to
demonstrate compliance, an owner or operator of an
emission source unit which is subject to this Part
shall, at his own expense, conduct tests in accordance
with the applicable test methods and procedures
specific in this Part. Nothing in this Section shall
limit the authority of the USEPA pursuant to the Clean
Air Act, as amended, to require testing.
jI Stage II Gasoline Vapor Recovery Test Methods
The methods for determining the accePtable performance
of Stage II Gasoline Vapor Recovery System are
delineated in “Technical Guidance-Stage II VaPor
Recovery Systems for Control of Vehicle Refueling
Emissions at Gasoline Dispensing Facilities,” found at
EPA 450/3—91-022b and incorporated by reference in
Section 219.112 of this Part. Specifically, the test
methods are as follows:
fl
Dynamic Backpressure Test is a test procedure used
to determine the pressure drop (flow resistance)
through balance vapor collection and control
systems (including nozzles, vapor hoses. swivels,
dispenser piping, and underground piping) at
prescribed flow rates.
Z).
Pressure Decay/Leak Test is a test procedure used
to guantify the vapor tightness of a vapor
collection and control system installed at
gasoline dispensing facilities.
~j. Liquid Blockage Test is a test procedure used to
detect low points in any vapor collection and

410
control system where condensate may accumulate.
(Source: Amended at
Ill. Reg.
______,
effective
_________
Section 219.106
Compliance Dates
Compliance with the requirements of all rules is required by May
15, 1992, consistent with the provisions of Section 219.103 ~
this Part.
(Source: Amended at
Ill. Reg.
______,
effective
___________)
Section 219.107
operation of Afterburners
The operation of any natural gas fired afterburner and capture
system used to comply with this Part is not required during the
period of November 1 of any year to April 1 of the following year
provided that the operation of such devices is not required for
purposes of occupational safety or health, or for the control of
toxic substances, odor nuisances, or other regulated pollutants.
(Source: Amended at
Ill. Reg.
______,
effective
___________)
Section 219.109
Vapor Pressure of Volatile Organic Liquids
a) If the VOL consists of only a single compound, the
vapor pressure shall be determined by ASTM Method
D2879-86 (incorporated by reference in Section 219.112
of this Part) or the vapor pressure may be obtained
from a published sourcepublication such as: Boublik,
T., V. Fried and E. Hala, “The Vapor Pressure of Pure
Substances,” Elsevier Scientific Publishing Co., New
York (1973); Perry’s Chemical Engineer’s Handbook,
McGraw-Hill Book Company (1984); CRC Handbook of
Chemistry and Physics, Chemical Rubber Publishing
Company (1986-87); and Lange’s Handbook of Chemistry,
John A. Dean, editor, McGraw-Hill Book Company (1985).
b) If the VOL is a mixture, the vapor pressure shall be
determined by ASTN Method D2879-86 (incorporated by
reference in Section 219.112 of this Part) or by the
following equation:
n
Pvo1
=
E
1l
P~X~
where:
=
Total vapor pressure of the mixture,-~
n
=
Number of components in the mixtureTi.
0! ~0-0817

411
i
=
Subscript denoting an individual
component7j..
=
Vapor pressure of a component determined
in accordance with Subpart A of this
Partsubsection (a) of this Section
=
Mole fraction of the component in the
total mixture.
(Source: Amended at — Ill. Reg.
______,
effective
___________
Section 219.110
Vapor Pressure of Organic Material or Solvent
a) If the organic material or solvent consists of only a
single compound, the vapor pressure shall be determined
by ASTM Method D2879-86 (incorporated by reference in
Section 219.112 of this Part) or the vapor pressure may
be obtained from a published s--ourcepublication such as:
Boublik, T., V. Fried and E. Hala, “The Vapor Pressure
of Pure Substances,” Elsevier Scientific Publishing
Co., New York
(1973); Perry’s Chemical Engineer’s
Handbook, McGraw-Hill Book Company (1984); CRC Handbook
of Chemistry and Physics, Chemical Rubber Publishing
Company (1986-87); and Lange’s Handbook of Chemistry,
John A. Dean, editor, McGraw-Hill Book Company (1985).
b) If the organic material or solvent is in a mixture made
up of both organic material compounds and compounds
which are not organic material, the vapor pressure
shall be determined by the following equation:
n
~om
Ei=1 P~X1
n
Ri=1
X1
where:
=
Total vapor pressure of the portion of
the mixture which is composed of organic
materialTj..
n
=
Number of organic material components in
the mixture~-j.
i
=
Subscript
denoting an individual
comp onentT.L
=
Vapor pressure of an organic material
01 L~O-0818

412
component determined in accordance with
Subpart A of this- Partsubsection (a) of
this Section-nj
=
Mole fraction of the organic material
component of the total mixture.
c) If the organic material or solvent is in a mixture made
up of only organic material compounds, the vapor
pressure shall be determined by ASTM Method D2879—86
(incorporated by reference in Section 219.112 of this
Part)
or by the above equation.
(Source: Amended at
Ill. Reg.
______,
effective
__________/
Section 219.111
Vapor Pressure of Volatile Organic Material
a) If the VON consists of only a single compound, the
vapor pressure shall be determined by ASTM Method
D2879-86 (incorporated by reference in Section 219.112
of this Part) or the vapor pressure may be obtained
from a published sourccpublication such as: Boublik,
T., V. Fried and E. Hala, “The Vapor Pressure of Pure
Substances,” Elsevier Scientific Publishing Co., New
York (1973); Perry’s Chemical Engineer’s Handbook,
McGraw-Hill Book Company (1984); CRC Handbook of
Chemistry and Physics, Chemical Rubber Publishing
Company (1986-87); and Lange’ s Handbook of Chemistry,
John A. Dean, editor, McGraw-Hill Book Company (1985).
b) If the VON is in a mixture made up of both VON
compounds and compounds which are not VON, the vapor
pressure shall be determined by the following equation:
n
~vom
E
i=1
P1X1
n
E
i=1
where:
~Vom
=
Total vapor pressure of the portion
of the mixture which is composed of
VOMTI
n
=
Number of VON components in the
mixture-ri..
i
=
Subscript
denoting an individual
component-i-;
01 L~O-0819

413
=
Vapor pressure of a VON component
determined in accordance with
Subpart A of this
Partsubsection
(a) of this Section-~-j~.
=
Mole fraction of the VON component
of the total mixture.
c)
If the VON is in a mixture made up of only VOM
compounds, the vapor pressure shall be determined by
ASTN Method D2879—86 (incorporated by reference in
Section 219.112 of this Part) or by the above equation.
(Source: Amended at — Ill. Reg.
______,
effective
___________
Section 219.112
Incorporations by Reference
The following materials are incorporated by reference and do not
contain any subsequent additions or amendments:
a) American Society for Testing and Materials, 1916 Race
Street, Philadelphia, PA 19103:
1)
ASTN D2879—86
2)
ASTM D323—82
3)
ASTM D86—82
4) ASTM D—369—69 (1971)
5) ASTM D—396—69
6)
ASTM D2880—71
7)
ASTM D—975—68
8)
ASTM D3925—81 (1985)
9) ASTM E300—86
10)
ASTN D1475—85
11)
ASTM D2369—87
12) ASTM D3792—86
13) ASTM D4017—81 (1987)
14) ASTM D4457—85
15) ASTM D2697—86
16) ASTM D3980—87
17) ASTN E180—85
18) ASTM D2372—85
19) ASTM D97—66
20)
ASTN E—168—87 (1977)
21) ASTM E—169~~
22) ASTM
E—260—91
23)
ASTM D2504—83
24) ASTN D2382—83
j~j.. ASTM D323-82 (approved 1982)
b) Standard Industrial Classification Manual, published by
Executive Office of the President, Office of Management
and Budget, Washington, D.C., 1987.
01 ~O-0820

414
c) American Petroleum Institute Bulletin 2517,
“Evaporation Loss From Floating Roof Tanks”, Second
ed., February, 1980.
d)
40 CFR Part 60 (July 1, 10901991) and 40 CFR 60,
Appendix A, Method 24 (57 FR 30654, July 10, 1992).
e) 40 CFR Part 61 (July 1, 1-0901991).
f) 40 CFR Part 50 (July 1, 19801991).
g) 40 CFR Part 51 (July 1, 10891991).
h) 40 CFR Part 52 (July 1, 10391991).
~j 40 CFR Part 80 (July 1, 1991).
~.)-jj“A Guide for Surface Coating Calculation”, United
States Environmental Protection Agency, Washington,
D.C., EPA—340/1—86—016.
-~j-)-~çJ “Procedures for Certifying Quantity of Volatile Organic
Compounds Emitted by Paint, Ink and Other Coating”~
(revised June 1986), United States Environmental
Protection Agency, Washington D.C., EPA-450/3-84-019.
k~)-fl “A Guide for Graphic Arts Calculations”, August 1988,
United States Environmental Protection Agency,
Washington D.C., EPA-340/l—88-003.
~-~j “Protocol for Determining the Daily Volatile Organic
Compound Emission Rate of Automobile and Light-Duty
Truck Topcoat Operations”, December 1988, United States
Environmental Protection Agency, Washington D.C.,
EPA—450/3—88—0l8.
m-)-j~ “Control of Volatile Organic Emissions from
Manufacturing of Synthesized Pharmaceutical Products”,
United States Environmental Protection Agency,
Washington, D.C., EPA—450/2—78-029.
n-)-gj “Control of Volatile Organic Compound Leaks from
Gasoline Tank Trucks and Vapor Collection Systems”,
Appendix B, United States Environmental Protection
Agency, Washington, D.C., EPA—450/2-78-051.
e~-pj“Control of Volatile Organic Compound emissions from
Large Petroleum Dry Cleaners”, United States
Environmental Protection Agency, Washington, D. C.,
EPA—450/3—82—009.
qj “APTI
Course
S1417 Controlling Volatile Organic
0
i~-082~

415
Compound Emissions from Leaking Process Equipment”,
United States Environmental Protection Agency,
Washington, D.C., EPA-450/2—82—015.
~ “Portable Instrument User’s Manual for Monitoring VOM
Sources”, United States Environmental Protection
Agency, Washington, D.C., EPA—340/1-86—015.
~
“Protocols for Generating Unit—Specific Emission
Estimates for Equipment Leaks of VON and VHAP”J United
States Environmental Protection Agency, Washington,
D.C., EPA—450/3—88—010.
~j “Petroleum Refinery Enforcement Manual”, United States
Environmental Protection Agency, Washington, D.C.,
EPA—340/l—80—008.
~fl
“Inspection Manual for Control of Volatile Organic
Emissions from Gasoline Marketing Operations: Appendix
D”, United States Environmental Protection Agency,
Washington, D.C., EPA-340/1—80—0l2.
iL “Control of Hydrocarbons from Tank Truck Gasoline
Loading Terminals: Appendix A”, United States
Environmental Protection Agency, Washington, D.C.,
EPA—450/2—77—026.
~ “Technical Guidance—Stage II Vapor Recovery Systems for
Control of Vehicle Refueling Emissions at Gasoline
Dispensing Facilities”, United States Environmental
Protection Agency, Washington, D.C., EPA-450/3-91-022b.
2c1
California Air Resources Board, Compliance Division.
Compliance Assistance Program: Gasoline Marketing and
Distribution:
Gasoline Facilities
Phase I & II
(October 1988, rev. March 1991) (CARB Manual).
(Source: Amended at
Ill. Reg.
______,
effective
__________)
SUBPART B: ORGANIC EMISSIONS FROM STORAGE AND LOADING OPERATIONS
Section 219.121
Storage Containers
No person shall cause or allow the storage of any VOL with a
vapor pressure of 17.24 kPa (2.5 psia) or greater at 294.3°I
(70°F) or any gaseous organic material in any stationary tank,
reservoir or other container of more than 151 cubic meters
(40,000 gal) capacity unless such tank, reservoir or other
container:
a) Is a pressure tank capable of withstanding the vapor
pressure of such liquid or the pressure of the gas, so
01 L~O-O822

416
as to prevent vapor or gas loss to the atmosphere at
all times; or,
b) Is
designed and equipped with one of the following
vapor loss control devices:
1) A floating roof which rests on the surface of the
VOL and is equipped with a closure seal or seals
between the roof edge and the tank wall. Such
floating roof shall not be permitted if the VOL
has a
vapor pressure of
86.19 kPa (12.5 psia) or
greater
at 294.3°K(70°F). No person shall cause
or allow
the emission of air contaminants into the
atmosphere from any gauging or sampling devices
attached to such tanks, except during sampling or
maintenance operations.
2) A vapor recovery system consisting of:
A) A vapor gathering system capable of
collecting 85 or more of the uncontrolled
VON that would be otherwise emitted to the
atmosphere; and,
B) A vapor disposal system capable of processing
such VON so as to prevent its emission to the
atmosphere. No person shall cause or allow
the emission of air contaminants into the
atmosphere from any gauging or sampling
devices attached to such tank, reservoir or
other container except during sampling.
3)
Other equipment or means of equal efficiency
approved by the Agency according to the provisions
of 35 Ill. Adm. Code 201, and further processed
consistent with Section 219.108 of this Part.
(Source: Amended at — Ill. Reg.
______,
effective
_________)
Section 219.122
Loading Operations
a) No person shall cause or allow the discharge of more
than 3.6 kg/hr (8 lbs/hr) of organic material into the
atmosphere during the loading of any organic material
from the aggregate loading pipes of any loading
facilityarea having through-put of greater than 151
cubic meters per day (40,000 gal/day) into any railroad
tank car, tank truck or trailer unless such loading
facilityarea is equipped with submerged loading pipes
submerged fill or a device that is equally effective in
controlling emissions and is approved by the Agency
according to the provisions of 35 Ill. Adm. Code 201,
01
i~.O-0823

417
and further processed consistent with Section 219.108
of this Part.
b) No person shall cause or allow the loading of any
organic material into any stationary
tank having a
storage capacity of greater than 946 1 (250 gal),
unless such tank is equipped with a permanent submerged
loading pipe, submerged fill or an equivalent device
approved by the Agency according to the provisions of
35 Ill. Adm. Code 201, and further processed consistent
with Section 219.108 of this Part, or unless such tank
is a pressure tank as described in Section 219.121(a)
of this Part or is fitted with a recovery system as
described in Section 219.121(b) (2) of this Part.
c) Exception: If no odor nuisance exists the limitations
of
this Section shall
only apply to the loading of VOL
with a vapor pressure of 17.24 kPa (2.5 psia) or
greater at 294.3°K (70°F).
(Source: Amended at — Ill. Reg.
______,
effective
_________)
Section 219.123
Petroleum Liquid Storage Tanks
a) The requirements of subsection (b) of this Section
shall not apply to any stationary storage tank:
1) Equipped before January 1, 1979 with one of the
vapor loss control devices specified in Section
219.121(b) of this Part, except Section
219.121(b) (1)
of
this Part
2) With a capacity of less than 151.42 cubic meters
(40,000 gal);
3)
With a capacity of less than 1,600 cubic meters
(422,400 gal) and used to store produced crude oil
and condensate prior to custody transfer;
4)
With
a capacity of less than 1,430 cubic meters
(378,000 gal) and used to store produced oil or
condensate in crude oil gathering;
5) Subject to new source performance standards for
storage vessels of petroleum liquid, 35 Ill. Adm.
Code 230 40 CFR 60, as regulations promulgated by
the U.S. Environmental Protection Agency under
Section
III of the Clean Air Act (42 USC 7411), as
amended. THE PROVISIONS
OF SECTION III OF THE
CLEAN AIR ACT
...
ARE APPLICABLE IN THIS STATE AND
ARE ENFORCEABLE UNDER THE ENVIRONMENTAL
PROTECTION ACT1 (Ill. Rev. Stat. 1991, ch. 1l1~,
011~00821~

418
Par. 1009.1(b)) 415 ILCS 5/9.l(b)1
6) In which volatile petroleum liquid is not stored;
or
7)
Which is a pressure tank as described in Section
219.121(a) of this Part.
b) Subject to subsection (a) of this Section no owner or
operator of a stationary storage tank shall cause or
allow the storage of any VOL in the tank unless:
1) The tank is equipped with one of the vapor loss
control devices specified in Section 219.121(b) p~
this Part
2) There are no visible holes, tears or other defects
in the seal or any seal fabric or material of any
floating roof;
3) All openings of any floating roof deck, except
stub drains, are equipped with covers, lids or
seals such that:
A) The cover, lid or seal is in the closed
position at all times except when petroleum
liquid is transferred to or from the tank;
B) Automatic bleeder vents are closed at all
times except when the roof is floated off or
landed on the roof leg supports; and
C)
Rim vents, if provided, are set to open when
the roof is being floated off the roof leg
supports or at the manufacturer’s recommended
setting;
4) Routine inspections of floating roof seals are
conducted through roof hatches once every six
months;
5) A complete inspection of the cover and seal of any
floating roof tank is made whenever the tank is
emptied for reasons other than the transfer of
petroleum liquid during the normal operation of
the tank, or whenever repairs are made as a result
of any semi—annual inspection or incidence of roof
damage or defect; and
6) A record of the results of each inspection
conducted under subsection (b) (4) or (b) (5) ~
this Section is maintained.
01
~0-0825

419
c) Owners and operators of petroleum liquid storage tanks
were required to have compliance schedules as
summarized in Appendix C to 35 Ill Adm. Code 2-~
219 .Appendix C.
(Source: Amended at
______,
Ill. Reg.
_____,
effective
_______)
Section 219.124
External Floating Roofs
a) In addition to meeting the requirements of Section
219.123(b) of this Part, no owner or operator of a
stationary storage tank equipped with an external
floating roof shall cause or allow the storage of any
volatile petroleum liquid in the tank unless:
1) The tank has been fitted:
~ fitted w~itha continuous secondary seal
extending from the floating roof to the tank
wall (rim mounted secondary seal)~or
~j With any other device which controls- VON
emissions with an effectiveness equal to or
greater than a rim mounted secondary seal;
equipment or means of eaual efficiency
approved bY the Agency according to the
provisions of 35 Ill. Adm. Code 210, and
further processed consistent with Section
219.108 of this Part.
2) Each seal closure device meets the following
requirements:
A) The seal is intact and uniformly in place
around the circumference of the floating roof
between the floating roof and tank wall; and
B) The accumulated area of gaps exceeding 0.32
centimeter (1/8 inch) in width between the
secondary seal and the tank wall shall not
exceed 21.2 square centimeters per meter of
tank diameter (1.0 square inche~per foot of
tank diameter). Compliance with this
requirement shall be determined by:
LL
Physically measuring the length and
width of all gaps around the entire
circumference of the secondary seal in
each place where a 0.32 cm (0.125 in.)
uniform diameter probe passes freely
(without forcing or binding against the
seal) between the seal and the tank
0 I ~0-0826

420
wall; and
~J
Summing the area of the individual gaps.
3) Emergency roof drains are provided with slotted
membrane fabric covers or equivalent covers across
at least 90 percent of the area of the opening;
4) Openings are equipped with projections into the
tank which remain below the liquid surface at all
times;
5) Inspections are conducted prior to May 1 of each
year to insure compliance with subsection (a) ~
this Section
6)
The secondary seal gap is measured prior to May 1
of each year~and within 30 days of a written
request to demonstrate compliance with subsection
(2) (B) of this Section
7)
Records of the types of volatile petroleum liquid
stored, the maximum true vapor pressure of the
liquid as stored, the results of the inspections
and the results of the secondary seal gap
measurements are maintained and available to the
Agency, upon verbal or written request, at any
reasonable time for a minimum of two years after
the date on which the record was made.
b) Subsection (a) above does not apply to any stationary
storage tank equipped with an external floating roof:
1)
Exempted under Section 219.123(a) (2) through
219.123(a) (6) of this Part
2) Of welded construction equipped with a metallic
type shoe seal having a secondary seal from the
top of the shoe seal to the tank wall
(shoe—mounted secondary seal);
3)
Of welded construction equipped with a metallic
type shoe seal, a liquid—mounted foam seal, a
liquid-mounted liquid-filled-type seal, or other
closure device of equivalent control efficiency
approved by the Agency in which a petroleum liquid
with a true vapor pressure less than 27.6 kPa (4.0
psia) at 294.3°K (70°F) is stored; or
4) Used to store crude oil with a pour point of 50°F
or higher as determined by ASTM Standard D97-66
incorporated by reference in Section 219.112
~i
01
L~Q-0827

this Part
421
(Source: Amended at — Ill. Reg.
______,
effective
__________)
Section 21&~.l25
Compliance Dates (Repealed)
Every owner or operator of an emission source subject to 35 Ill.
Adm. Code 215, Subpart B, as of December 31, 1987 s-hall have
r~mn1ir~d with it~
~t~~n-ri~,
~nr1
1imitnt~inn,
h~.r
fl~r~mh~r
~1. 1-’)R7
(Source: Repealed at — Ill.
Reg.
______,
effective
)
Section 219.126
Compliance Plan (Repealed)
The owner or operator of an emission source previously
subject to Section 215.125 shall have submitted to the
Agency a compliance plan as required by 35 Ill. Adm.
Code 201.241, including a project completion schedule
where applicable, no later than April 21, 1983.
Unless the submitted compliance plan or schedule was
...~.sapproveaby the Agency, the owner or operator
facility or emission source subject to the rules
specified in cubs-cation (a) may opcr-atc the emission
~UULUC
~UUULUifl~
LU LI1~
piun
anu
The plan and schedule shall meet
~uii~uuic ~ submitted.
the requirements of 35
Ill. Adm. Code 201.241
including specific interim dates
as required in 35 Ill. Adm. Code 201.242.
(Source: Repealed at — Ill. Reg.
______,
effective
_________)
SUBPART C: ORGANIC EMISSIONS FROM MISCELLANEOUS EQUIPMENT
Section 219.141
Separation Operations
a) No person shall use any single or multiple compartment
effluent water separator which receives effluent water
containing 757 1/day (200 gal/day) or more of organic
material from any equipment processing, refining,
treating, storing or handling organic material unless
such effluent water separator is equipped with air
pollution control equipment capable of reducing by 85
percent or more the uncontrolled organic material
emitted to the atmosphere. Exception: If no odor
nuisance exists the limitations of this subsection
shall not apply if the vapor pressure of the organic
material is below 17.24 kPa (2.5 psia) at 294.3°K
(70°F).
b) Subsection (a) of this Section shall not apply to water
and crude oil separation in the production of Illinois
0 I ~O-UB28

.
.
.

422
crude oil, if the vapor pressure of such crude oil is
less than 34.5 kPa (5 psia).
(Source: Amended at
______
, Ill. Reg.
_____,
effective
_______
Section 219.143
Vapor Blowdown
No person shall cause or allow the emission of organic material
into the atmosphere from any vapor blowdown system or any safety
relief valve, except such safety relief valves not capable of
causing an excessive release, unless such emission is controlled:
a) To 10 ppm equivalent methane (molecular weight 16.0) or
less; or,
b) By combustion in a smokeless flare; or,
c) By other air pollution control equipment approved by
the Agency according to the provisions of 35 Ill. Adm.
Code 201, and further processed consistent with Section
219.108 of this Part.
(Source: Amended at
Ill. Reg.
______,
effective
__________)
Section 219.144
Safety Relief Valves
Section 219.143 of this Part shall not apply to any set of
unregulated safety relief valves capable of causing excessive
releases, provided the owner or operator thereof, by October 1,
1972, supplied the Agency with the following:
a) A historical record of each such set (or, if such
records were unavailable, of similar sets which, by
virtue of operation under similar circumstances, may
reasonably have been presumed to have the same or
greater frequency of excessive releases) for a
three-year period immediately preceding October 1,
1972, indicating:
1) Dates on which excessive releases occurred from
each such set; and
2) Duration in minutes of each such excessive
release; and
3) Quantities (in pounds) of mercaptans and/or
hydrogen sulfide emitted into the atmosphere
during each such excessive release.
b) Proof, using such three—year historical records, that
no excessive release is likely to occur from any such
set either alone or in combination with such excessive
01
~~.Q-Q829

423
releases from other sets owned or operated by the same
person and located within a ten—mile radius from the
center point of any such set, more frequently than 3
times in any 12 month period;
c) Accurate maintenance records pursuant to the
requirements of subsection (a) of this Section and,
d) Proof, at three—year intervals, using such three—year
historical records, that such set conforms to the
requirements of subsection (c) of this Section.
(Source: Amended at
Ill. Reg.
______,
effective
__________)
SUBPART E: SOLVENT CLEANING
Section 219.181
Solvent Cleaning in General
The requirements of this Subpart shall apply to all cold
cleaning, open top vapor degreasing, and conveyorized degreasing
operations which use volatile organic materials.
(Source: Amended at
Ill. Reg.
______
, effective
___________
Section 219.182
Cold Cleaning
a) Operating Procedures: No person shall operate a cold
cleaning degreaser unless:
1) Waste solvent is stored in covered containers only
and not disposed of in such a manner that more
than 20 of the waste solvent (by weight) is
allowed to evaporate into the atmosphere;
2) The cover of the degreaser is closed when parts
are not being handled; and
3) Parts are drained until dripping ceases.
b) Equipment Requirements: No person shall operate a cold
cleaning degreaser unless:
1) The degreaser is equipped with a cover which is
closed whenever parts are not being handled in the
cleaner. The cover shall be designed to be easily
operated with one hand or with the mechanical
assistance of springs, counter—weights or a
powered system if:
A) The solvent vapor pressure is greater than 2
kPa (15 mmHg or 0.3 psi) measured at 38°C
(100°F);
01 ~0-O830

424
B) The solvent is agitated; or
C) The solvent is heated above ambient room
temperature.
2) The degreaser is equipped with a facilitydevice
for draining cleaned parts. The drainage
facilitydevice shall be constructed so that parts
are enclosed under the cover while draining
unless:
A) The solvent vapor pressure is less than 4.3
kPa (32 mmHg or 0.6 psi) measured at 38°C
(100°F); or
B) An internal drainage facilitydevice cannot be
fitted into the cleaning system, in which
case the drainage facilitydevice may be
external.
3) The degreaser is equipped with one of the
following control devices if the vapor pressure of
the solvent is greater than 4.3 kPa (32 mmHg or
0.6 psi) measured at 38°C(100°F) or if the
solvent is heated above 50°C (120°F) or its
boiling point:
A) A freeboard height of 7/10 of the inside
width of the tank or 91 cm (36 in), whichever
is less; or
B) Any other equipment or system of equivalent
emission control as approved by the Agency
and further processed consistent with Section
219.108 of this Part. Such a system may
include a water cover, refrigerated chiller
or carbon adsorber.
4) A permanent conspicuous label summarizing the
operating procedure is affixed to the degreaser;
and
5) If a solvent spray is used, the degreaser is
equipped with a solid fluid stream spray, rather
than a fine, atomized or shower spray.
(Source: Amended at
______,
Ill. Reg.
_______,
effective
______
Section 219.183
Open Top Vapor Degreasing
a) Operating Requirements: No person shall operate an
open top vapor degreaser unless:
01 ~O-O33I

425
1) The cover of the degreaser is closed when
workloads are not being processed through the
degreaser
2) Solvent carryout emissions are minimized by:
A) Racking parts to allow complete drainage;
B) Moving parts in and out of the degreaser at
less than 3.3 m/min (11 ft/mm);
C) Holding the parts in the vapor zone until
condensation ceases;
D) Tipping out any pools of solvent on the
cleaned parts before removal from the vapor
zone; ~
E) Allowing parts to dry within the degreaser
until visually dry.
3) Porous or absorbent materials, such as cloth,
leather, wood or rope are not degreased;
4) Less than half of the degreaser’s open top area is
occupied with a workload;
5) The degreaser is not loaded to the point where the
vapor level would drop more than 10 cm (4 in) when
the workload is removed from the vapor zone;
6)
Spraying is done below the vapor level only;
7) Solvent leaks are repaired immediately;
8) Waste solvent is stored in covered containers only
and not disposed of in such a manner that more
than 20 of the waste solvent (by weight) is
allowed to evaporate into the atmosphere;
9)
Water is not visually detectable in solvent
exiting from the water separator; and
10) Exhaust ventilation exceeding 20 cubic meters per
minute per square meter (65 cubic feet per minute
per square foot) of degreaser open area is not
used, unless necessary to meet the requirements of
the Occupational Safety and Health Act (29 U.S.C.
Section 651 et seq.).
b) Equipment Requirements: No person shall operate an
open top vapor degreaser unless:
01 1~O-0332

426
1) The degreaser is equipped with a cover designed to
open and close easily without disturbing the vapor
zone;
2) The degreaser is equipped with the following
switches:
A) A devic-cOne which shuts off the sump heat
source if the amount of condenser coolant is
not sufficient to maintain the designed vapor
level; and
B) A deviccQ~~which shuts off the spray pump if
the vapor level drops more than 10 cm (4 in)
below the bottom condenser coil; and
C) A deviccOne which shuts off the sump heat
source when the vapor level exceeds the
design level~
3) A permanent conspicuous label summarizing the
operating procedure is affixed to the degreaser;
4) The degreaser is equipped with one of the
following devices:
A) A freeboard height of 3/4 of the inside width
of the degreaser tank or 91 cm (36 in),
whichever is less; and if the degreaser
opening is greater than 1 square meter (10.8
ft2), a powered or mechanically assisted
cover; or
B) Any other equipment or system of equivalent
emission control as approved by the Agency
and further processed consistent with Section
219.108 of this Part. Such equipment or
system may include a refrigerated chiller, an
enclosed design or a carbon adsorption
system.
(Source: Amended at
_____,
Ill. Reg.
______,
effective
_______)
Section 219.184
Conveyorized Degreasing
a) Operating Requirements: No person shall operate a
conveyorized degreaser unless:
1) Exhaust ventilation exceeding 20 cubic meters per
minute per square meter (65 cubic feet per minute
per square foot) of area of loading and unloading
opening is not used, unless necessary to meet the
01 L~.0-O333

427
requirements of the Occupational Safety and Health
Act (29 U.S.C. Section 651 et seq.);
2)
Solvent carryout emissions are minimized by:
A) Racking parts for best drainage; and
B) Maintaining the vertical conveyor speed at
less than 3.3 m/min (11 ft/mm);
3) Waste solvent is stored in covered containers only
and not disposed of in such a manner that more
than 20 of the waste solvent (by weight) is
allowed to evaporate into the atmosphere;
4) Solvent leaks are repaired immediately;
5) Water is not visually detectable in solvent
exiting from the water separator; and
6) Downtime covers are placed over entrances and
exits of conveyorized degreasers immediately after
the conveyors and exhausts are shut down and not
removed until just before start—up.
b) Equipment Requirements: No person shall operate a
conveyorized degreaser unless:
1) The degreaser is equipped with a drying tunnel,
rotating (tumbling) basket or other equipment
sufficient to prevent cleaned parts from carrying
out solvent liquid or vapor;
2) The degreaser is equipped with the following
switches:
A) A deviceQ~~which shuts off the sump heat
source if the amount of condenser coolant is
not sufficient to maintain the designed vapor
level;
B) A deviceQ~which shuts off the spray pump or
the conveyor if the vapor level drops more
than 10 cm (4 in) below the bottom condenser
coil; and
C)
A- dcviccQ~ which shuts off the sump heat
sour-ce when the vapor level exceeds the
design level;
3) The degreaser is equipped with openings for
entrances and exits that silhouette workloads so
01
~O-O83t~

428
that the average clearance between the parts and
the edge of the degreaser opening is less than 10
cm (4 in) or less than 10 percent of the width of
the opening;
4) The degreaser is equipped with downtime covers for
closing off entrances and exits when the degreaser
is shut down; and
5) The degreaser is equipped with one of the
following control devices, if the air/vapor
interface is larger than 2.0 square meters (21.6
ft2)
A) A carbon adsorption system with ventilation
greater than or equal to 15 cubic meters per
minute per square meter (50 cubic feet per
minute per square foot) of air/vapor area
when downtime covers are open, and exhausting
less than 25 ppm of solvent by volume
averaged over a complete adsorption cycle; or
B) Any other equipment or system of equivalent
emission control as approved by the Agency,
and further processed consistent with Section
219.108 of this Part. Such equipment or
system may include a refrigerated chiller.
(Source: Amended at
_____,
Ill. Req.
______,
effective
_______)
Section 219.185
Compliance Schedule (Repealed)
Every owner or
operator of an emission source which was
previously exempt from the requirements of Subpart E of 35 Ill.
Adm. Code 215 (Sections 215.182—215.134) because it satisfied the
~itcria in either 35 Ill. Adm. Code 215.181(a)
35 Ill. Adm.
Code 215.181(b), s-hall comply with the requirements of this
Subpart on and after a date consistent with Section 219.106. A
source which did not satisfy the criteria in either 35 Ill. Adm.
Code 215.181(a) or 35 Ill. Adm. Code 215.181(b) shall comply with
the requirements of this Subpart upon adoption.
(Source: Repealed at — Ill. Reg.
______,
effective
__________)
Section 219.186
Test Methods
The following test methods shall be used to demonstrate
compliance with this Subpart:
a) Vapor pressures shall be determined by using the
procedure specified in Section 219.110 of this Part.
01
L~0-Q035

429
b) Exhaust ventilation rates shall be determined by using
the procedures specified in Section 219.105(f) (3) ~
this Part.
C) The performance of control devices shall be determined
by using the procedures specified in Section 219.105(f)
of this Part.
(Source: Amended at
_____,
Ill. Reg.
______,
effective
_______
SUBPART F: COATING OPERATIONS
Section 219.204
Emission Limitations for Nanuiact.uririri £,ianLc
Except as provided in Sections 219.205, 219.207 and 219.208 of
this Part, no owner or operator of a coating line shall apply at
any time any coating in which the VOM content exceeds the
following emission limitations for the specified coating. The
following emission limitations are expressed in units of VON per
volume of coating (minus water and any compounds which are
specifically exempted from the definition of VON) as applied at
each coating applicator, except where noted. Compounds which are
specifically exempted from the definition of VOM should be
treated as water for the purpose of calculating the “less water”
part of the coating composition. Compliance with this Subpart
must be demonstrated through the applicable coating analysis test
methods and procedures specified in Section 219.105(a) of this
Part and the recordkeeping and reporting requirements specified
in Section 219.211(c) of this Part. (Note: The equation
presented in Section 219.206 of this Part shall be used to
calculate emission limitations for determining compliance by
add—on controls, credits for transfer efficiency, emissions
trades and cross—line averaging.) The emission limitations are
as follows:
a) Automobile or Light-Duty Truck Coating
kg/i
lb/gal
1) Prime coat
0.14
(1.2)
2) Primer surfacer coat
O.341.8l
(~2—-&15.l)
(Note: The primer surfacer coat limitation is
based upon a transfer efficiency of 30 percent.
The use of transfer efficiency credits- can ~e
allowed only if approved by the Agency and
approved by the UCEPA as a SIP revisionin units of
kg (lbs) of VON per 1 (gal) of coating solids
deposited. Compliance with the limitation shall
be based on the daily-weighted average from an
entire primer surfacer operation. Compliance
shall be demonstrated in accordance with the
topcoat protocol referenced in Section 219.105(b)
01
~0-0636

430
and the recordkeeping and reporting requirements
specified in Section 219.211(f). Testing to
demonstrate compliance shall be performed in
accordance with the topcoat protocol and a
detailed testing proposal approved by the Agency
and USEPA specifying the method of demonstrating
compliance with the protocol. Section 219.205
does not apply to the primer surfacer limitation.)
kg/i
lb/gal
3) Topcoat
1.81
(15.1)
(Note: The topcoat limitation is in units of kg
(ibs) of VON per 1 (gal) of coating solids
deposited. Compliance with the limitation shall
be based on the daily-weighted average VON content
from ~ean entire topcoat operation (all topcoat
spray booths-, flash—off areas and bake ovens).
Compliance shall be demonstrated in accordance
with the topcoat protocol f-or automobiles- and
light—duty trucks referenced in Section 219.105(b)
of this Part and the recordkeepinq and reporting
requirements specified in Section 219.211(f).
Testing to demonstrate compliance shall be
performed in accordance with the topcoat protocol
Section 219.205 does not apply to the topcoat
limitation.) At least i80 days- prior to the
initial compliance date, the owner or operator o-f-
a coating line subject to the topcoat limitation
shall have submitted to the USEPA a detailed
testing proposal approved by the Agency and USEPA
specifying the method of demonstrating compliance
with the protocol. The proposal shall have
included, at a minimum, a comprehensive plan
(including a rationale) for determining the
transfer efficiency at each booth through the use
of in—plant, or pilot testing; the selection of
coatings to be tested (for the purpose of
determining transfer efficiency) including the
rationale for coating groupings-; and the method
for determining the analytic VON content of as
applied coatings and the formulation solvent
content of as- applied coatings. Upon approval of
~e protocol by the USEPA, the source may proceed
with the compliance demonstration. Section
219.205 of this Part does not apply to the topcoat
limitation.)
kg/i
lb/gal
4) Final repair coat
0.58
(4.8)
b) Can Coating
kg/i
lb/gal
01 ~0-0837

431
1) Sheet basecoat and overvarnish 0.34
(2.8)
2)
Exterior basecoat and
overvarnish
0.34
(2.8)
3)
Interior body spray coat
0.51
(4.2)
4) Exterior end
coat
0.51
(4.2)
5) Side seam spray coat
0.66
(5.5)
6) End sealing compound coat
0.44
(3.7)
kg/i
lb/gal
c) Paper Coating
0.35
(2.9)
(Note: The paper coating limitation shall not apply to
any owner or operator of any paper coating line on
which printing is performed if the paper coating line
complies with the emissions limitations in Subpart H:
Printing and Publishing, Sections 219.401 through
2-19.404.)-of this Part and other approvable
requirements.)
kg/i
lb/gal
d) Coil Coating
0.31
(2.6)
e) Fabric Coating
0.35
(2.9)
f) Vinyl Coating
0.45
(3.8)
g) Metal Furniture Coating
0.36
(3.0)
h) Large Appliance Coating
0.34
(2.8)
(Note: The limitation shall not apply to the use of
quick—drying lacquers for repair of scratches and nicks
that occur during assembly, provided that the volume of
coating does not exceed 0.95 1 (1 quart) in any one
rolling eight-hour period.)
kg/i
lb/gal
i)
Magnet Wire Coating
0.20
(1.7)
j)
Miscellaneous Metal
Parts and Products Coating
kg/i
lb/gal
1)
Clear coating
0.52
(4.3)
2)
Air-dried coating
0.42
(3.5)
3)
Extreme performance coating
0.42
(3.5)
01 ~0-0838

432
j) Steel pail and drum interior
coating
0.52
(4.3)
4~) All other coatings
0.36
(3.0)
k) Heavy Off-Highway Vehicle Products Coating
kg/i
lb/gal
1) Extreme performance prime coat 0.42
(3.5)
2) Extreme performance top—coat
(air dried)
0.42
(3.5)
3) Final repair coat (air dried) 0.42
(3.5)
4) All other coatings are subject to the emission
limitations for miscellaneous metal parts and
products coatings in subsection (j) above.
1) Wood Furniture Coating
kg/i
lb/gal
1) Clear topcoat
0.67
(5.6)
2) Opaque stain
0.56
(4.7)
3) Pigmented coat
0.60
(5.0)
4) Repair coat
0.67
(5.6)
5)
Sealer
0.67
(5.6)
6)
Semi-transparent stain
0.79
(6.6)
7) Wash coat
0.73
(6.1)
(Note: An owner or operator of a wood furniture
coating operation subject to this Section shall
apply all coatings, with the exception of no more
than 37.8 1 (10 gal) of coating per day used for
touch—up and repair operations, using one or more
of the following application systems: airless
spray application system, air-assisted airless
spray application system, electrostatic spray
application system, electrostatic bell or
disc-spray application system, heated airless
spray application system, roller coating, brush or
wipe coating application system, e~ dip coating
application system or high volume low pressure
(HVLP) application system.)
(Source: Amended at — Ill. Reg.
_____,
effective
Section 219.205
Daily-Weighted Average Limitations
o
L~Q-0B39

433
No owner or operator of a coating line subject to the limitations
of Section 219.204 of this Part and complying by means of this
Section shall operate the subject coating line unless the owner
or operator has demonstrated compliance with subsection~ (a),
(b), (c), (d), (e) or (f) of this Section (depending upon the
s-ourcc category of coating) through the applicable coating
analysis test methods and procedures specified in Section
219.105(a) of this Part and the recordkeeping and reporting
requirements specified in Section 219.211(d) of this Part:
a) No owner or operator of a coating line subject to only
one of the
limitations from among Section 219.204(a) (1), -(-a)(2),
(a)
(4), (c) , (d) , (e) , (f) ,
(g)
, (Ii), or (i) of this
Part shall apply coatings on any such coating line,
during any day, whose daily-weighted average VON
content exceeds the emission limitation to which the
coatings are subject.
b) No owner or operator of a miscellaneous metal parts and
products coating line subject to the limitations of
Section 219.204(j) of this Part shall apply coatings to
miscellaneous metal parts or products on the subject
coating line unless the requirements in subsection
(b) (1) or (b) (2) of this Section below are met.
1) For each coating line which applies multiple
coatings, all of which are subject to the same
numerical emission limitation within Section
219.204(j) above, during
the same day (e.g., all
coatings used on the line are subject to 0.42 kg/l
3.5 lbs/gal), the daily-weighted average VON
content shall not exceed the coating VOM content
limit corresponding to the category of coating
used, or
2) For each coating line which applies coatings
subiect to more than one numerical emission
limitation from more than one of the four coating
categories in Section 219.204(j)
above, during the
same day, the owner or operator shall have a
site-specific proposal approved by the Agency and
approved by the USEPA as a SIP revision. To
receive approval, the requirements of USEPA’s
Emissions Trading Policy Statement (and related
policy)
51 Fed. Reg. 43814 (December 4, 1986),
must be satisfied.
c)
No owner or operator of a can coating facilityline
subject to the limitations of Section ~2~.204(b) ~
this Part shall operate the subject coating
facilityline using a coating with a VOM content in
01
1~0-Q8L40

434
excess of the limitations specified in Section
2-l-~U.204(b) of this Part unless all of the following
requirements are met:
1) An alternative daily emission limitation for the
can coating operation. i.e. for all the can
coating lines at the source, shall be determined
according to subsection (c) (2) below. Actual
daily emissions shall never exceed the alternative
daily emission limitation and shall be calculated
by use of the following equation.
n
Ed
=
E
i=i
V1C1
where:
Ed
=
Actual VOM emissions for the day in
units of kg/day (lbs/day)-~
i
=
Subscript denoting a specific
coating applied~~
n
=
Total number of coatings applied in
the can coating operation i.e. all
can coating lines at the source
=
Volume of each coating applied for
the day in units of 1/day (gal/day)
of coating (minus water and any
compounds which are specifically
exempted from the definition of
VOM)~
C~
=
The VON content of each coating as
applied in units of kg VON/i (lbs
VON/gal) of coating (minus water
and any compounds which are
specifically exempted from the
definition of VOM).
2) The alternative daily emission limitation (Ad)
shall be determined for the can coating operation,
i.e. for all the can coating lines at the source,
on a daily basis as follows:
n
Aa
E V1L~j~~ Cjj
i=l
(D~ — L~)
where:
Qtt~0-081~1

435
Ad
=
The VOM emissions allowed for the
day in units of kg/day (lbs/day)-~-j
i
=
Subscript denoting a specific
coating applied-~-;~
n
=
Total number of surface coatings
applied in the can coating
operat i on-7j
C~
=
The VON content of each surface
coating as applied in units of kg
VON/i (lbs VON/gal) of coating
(minus water and any compounds
which are specifically exempted
from the definition of VOM)T~
D~
=
The density of VON in each coating
applied. For the purposes of
calculating
4-~,
the density is
0.882 kg VOM/l VON (7.36 lbs
VON/gal VOM)T~
Vj
=
Volume of each surface coating
applied for the day in units of 1
(gal) of coating (minus water and
any compounds which are
specifically exempted from the
definition of VOM)T~
=
The VON emission limitation for
each surface coating applied as
specified in Section 219.204(b) ~
this Part in units of kg VON/i (lbs
VON/gal) of coating (minus water
and any compounds which are
specifically exempted from the
definition of VON).
d) No owner or operator of a heavy off—highway vehicle
products coating line subject to the limitations of
Section 219.204(k) of this Part shall apply coatings to
heavy off-highway vehicle products on the subject
coating line unless the requirements of subsection
(d) (1) or (d) (2) below are met.
1) For each coating line which applies multiple
coatings, all of which are subject to the same
numerical emission limitation within Section
219.204(k) above, during the same day (e.g., all
coatings used on the line are subject to 0.42 kg/i
3.5
lbs/gal),
the daily-weighted average VON
01L~0-08t”2

436
content shall not exceed the coating VON content
limit corresponding to the category of coating
used, or
2) For each coating line which applies coatings
subject to more than one numerical emission
limitation in Section 219.204(k)
above,
during the
same day, the owner or operator shall have a site
specific proposal approved by the Agency and
approved by the USEPA as a SIP revision. To
receive approval, the requirements of USEPA’s
Emissions Trading Policy Statement (and related
policy) 51 Fed. Req. 43814 (December 4, 1986) must
be satisfied.
e) No owner or operator of a wood furniture coating line
subject to the limitations of Section 219.204(1) ~
this Part shall apply coatings to wood furniture on the
subject coating line unless the requirements of
subsection (e) (1) or subsection (e) (2) below, in
addition to the requirements specified in the note to
Section 219.204(1) of this Part, are met.
1)
For each coating line which applies multiple
coatings, all of which are subject to the same
numerical emission limitation within Section
219.204(1) above, during the same day (e.g., all
coatings used on the line are subject to 0.67 kg/i
5.6 lbs/gal), the daily-weighted average VON
content shall not exceed the coating VON content
limit corresponding to the category of coating
used, or
2) For each coating line which applies coatings
subject to more than one numerical emission
limitation in Section 219.204(1) above, during the
same day, the owner or operator shall have a site
specific proposal approved by the Agency and
approved by the USEPA as a SIP revision. To
receive approval, the requirements of USEPA’s
Emissions Trading Policy Statement (and related
policy) 51 Fed. Reg. 43814 (December
4, 1986),
must be satisfied.
(Source: Amended at — Ill.
Reg.
______,
effective
_________
Section 219.206
Solids Basis Calculation
Limitations in terms of kg (lbs) of VOM emissions per 1 (gal) of
solids as applied at each coating applicator shall be determined
by the following equation:
01 i~O_081~3

437
S=
C
1
(C/D)
where:
S
=
The limitation on VON emissions in terms of
kg VON/l (lbs VON/gal) of solidsTl
C
=
The limitation on VON emissions in terms of
kg/i (lbs/gal) of coating (minus water and
any compounds which are specifically excluded
from the definition of VON) specified in
Section 2l9.2O4~j..
D
=
The density of VOM in the coating. For the
purposes of calculating 5, the density is
0.882 kg VOM/l VOM (7.36 lbs VON/gal VON).
(Source: Amended at
_____,
Ill. Req.
______,
effective
_______)
Section 219.207
Alternative Emission Limitations
a) Any owner or operator of a coating line subject to
Section 219.204 of this Part may comply with this
Section, rather than with Section 219.204 of this Part,
if a capture system and control device are operated at
all times the coating line is in operation and the
owner or operator demonstrates compliance with
subsections (c), (d), (e), (f), (g) or (h) of this
Section (depending upon the source category) through
the applicable coating analysis and capture system and
control device efficiency test methods and procedures
specified in Section 219.105 of this Part and the
recordkeeping and reporting requirements specified in
Section 219.211(e) of this Part and the control device
is equipped with the applicable monitoring equipment
specified in Section 219.105(d) of this Part and the
monitoring equipment is installed, calibrated, operated
and maintained according to vendor specifications at
all times the control device is in use. A capture
system and control device, which does not demonstrate
compliance with subsection (c), (d), (e), (f), (g) or
(Ii) of this Section may be used as an alternative to
compliance with Section 219.204 of this Part only if
the alternative is approved by the Agency and approved
by the USEPA as a SIP revision.
b) Alternative Add-On Control Methodologies
1) The coating line is equipped with a capture system
and control device that provides 81 percent
reduction in the overall emissions of VON from the
01
i4Q-Q8t~I~

438
coating line and the control device has a 90
percent efficiency, or
2) The system used to control VON from the coating
line is demonstrated to have an overall efficiency
sufficient to limit VOM emissions to no more than
what is allowed under Section 219.204 of this
Part. Use of any control system other than an
afterburner, carbon adsorption, condensation, or
absorption scrubber system can be allowed only if
approved by the Agency and approved by the USEPA
as a SIP revision. The use of transfer efficiency
credits can be allowed only if approved by the
Agency and approved by the USEPA as a SIP
revision. Baseline transfer efficiencies and
transfer efficiency test methods must be approved
by the Agency and the USEPA.
Such overall efficiency is to be determined as
follows:
A) eQbtain the emission limitation from the
appropriate subsection in Section 219.204 p~
this Part,
B) e~alculate “S” according to the equation in
Section 219.206 of this Part,
C) e~alcu1atethe overall efficiency required
according to Section 219.105(e) of this Part.
For the purposes of calculating this value,
according to the equation in Section
219.105(e) (2) of this Part, VON1 is equal to
the value of “5” as determined above in
subsection (b) (2) (B) of this Section.
c) No owner or operator of a coating line subject to only
one of the emission limitations from among Section
219.204 (a) (1), -(-a) (2-h- (a) (4), (c) , (d) , (e) (f) ~ (g)
(h) or (i) of this Part and equipped with a capture
system and control device shall operate the subject
coating line unless the requirements in subsection
(b) (1) or (b) (2) above are met. No owner or operator
of a coating line subject to Section 219.204 (a)(2) or
(a) (3) of this Part and equipped with a capture system
and control device shall operate the coating line
unless the owner or operator demonstrates compliance
with ~he topcoat such limitation in accordance with the
topcoat protocol for automobile or light-duty trucks
referenced in Section 219.105(b) of this Part.
d) No owner or operator of a miscellaneous metal parts and
01
~O-O6Li.5

439
products coating line which applies one or more
coatings during the same day, all of which are subject
to the same numerical emission limitation within
Section 219.204(j) of this Part (e.g., all coatings
used on the line are subject to 0.42 kg/i 3.5
lbs/gal), and which is equipped with a capture system
and control device shall operate the subject coating
line unless the requirements in subsection (b) (1) or
(b) (2) above are met.
e) No owner or operator of a heavy off—highway vehicle
products coating line which applies one or more
coatings during the same day, all of which are subject
to the same numerical emission limitation within
Section 219.204(k) (e.g., all coatings used on the line
are subject to 0.42 kg/i 3.5 lbs/gal), and which is
equipped with a capture system and control device shall
operate the subject coating line unless the
requirements in subsection (b) (1) or (b) (2) above are
met.
i-)-
No- owner or operator of an existing diesel—electric
locomotive coating line which applies- one or more
coatings during the same day, all of which arc subject
to the same numerical emission limitation within
Cection 219.204(m) (e.g., all coatings us-ed on the line
are subject to 0.42 kg/l 3.5 lbs/gal)) , and which is-
equipped with a capture system and control device shall
~~te the subject coating ~nc
~-
subsection (b) (1) or (b) (2) are
g-)-~No owner or operator of a wood furniture coating line
which applies one or more coatings during the same day,
all of which are subject to the same numerical emission
limitation within Section 219.204(1) of this Part
(e.g., all coatings used on the line are subject to
0.67 kg/i 5.6 lbs/galJ), and which is equipped with a
capture system and control device shall operate the
subject coating line unless the requirements in
subsection (b) (1) or (b) (2) of this Section are met.
If compliance is achieved by meeting the requirements
in subsection (b) (2) of this Section, then the
provisions in the note to Section 219.204(1) of this
Part must also be met.
h-)-gj No owner or operator of a can coating faciiityline and
equipped with a capture system and control device shall
operate the subject coating facilityline unless the
requirements in subsection (h) (1) or (h) (2) below are
met.
1) An alternative daily emission limitation for the
01 t~Q-Q8t46

440
can coating operation, i.e. for all the can
coating lines at the source, shall be determined
according to Section 219.205(c) (2) of this Part.
Actual daily emissions shall never exceed the
alternative daily emission limitation and shall be
calculated by use of the following equation:
n
Ed
=
E V1C1 (i-Ft
1=1
where:
Ed
=
Actual VOM emissions for the day in
units of kg/day (lbs/day)~~
i
=
Subscript denoting the specific
coating app1ied-~-;
n
=
Total number of surface coatings as
applied in the can coating
operat
I
=
Volume of each coating as applied
for the day in units of 1/day
(gal/day) of coating (minus water
and any compounds which are
specifically exempted from the
definition of VOM)-~j
C~
=
The VON content of each coating as
applied in units of kg VOM/i (lbs
VOM/gal) of coating (minus water
and any compounds which are
specifically exempted from the
definition of VOM)j
F~
=
Fraction, by weight, of VON
emissions from the surface coating,
reduced or prevented from being
emitted to the ambient air. This is
the overall efficiency of the
capture system and control device~
2) The coating line is equipped with a capture system
and control device that provide 75 percent
reduction in the overall emissions of VON from the
coating line and the control device has a 90
percent efficiency.
(Source: Amended at — Ill. Req.
______,
effective
01 L~0-08Li~7

441
Section 219.208
Exemptions From Emission Limitations
a) Exemptions for all sourc-ecoatinq categories except wood
furniture coating. The limitations of this Subpart
shall not apply to coating lines within a
facilitysource, that otherwise would be subject to the
same subsection of Section 219.204 (because they belong
to the same sourcecoating category, e.g. can coating),
provided that combined actual emissions of VON from all
lines at the faci1it-ysourc~subject to that subsection
never exceed 6.8 kg/day (15 lbs/day) before the
application of capture systems and control devices.
(For example, can coating lines within a p-laritsource
would not be subject to the limitations of Section
219.204(b) of this Part if the combined actual
emissions of VON from the can coating lines never
exceed 6.8 kg/day (15 lbs/day) before the application
of capture systems and control devices.) Volatile
organic material emissions from heavy off—highway
vehicle products coating lines must be combined with
VON emissions from miscellaneous metal parts and
products coating lines to determine applicability. Any
owner or operator of a coating facilitysource shall
comply with the applicable coating analysis test
methods and procedures specified in Section 219.105(a)
of this Part and the recordkeeping and reporting
requirements specified in Section 219.211(a) of this
Part if total VON emissions from the subject coating
lines are always less than or equal to 6.8 kg/day
(15 lbs/day) before the application of capture systems
and control devices and, therefore, are not subject to
the limitations of Section 219.204 of this Part. Once
a category of coating lines at a facilitysource is
subject to the limitations in Section 219.204 of this
Part, the coating lines are always subject to the
limitations in Section 219.204 of this Part.
b) Applicability for wood furniture coating
1) The limitations of this Subpart shall apply to a
plant’s-source’s wood furniture coating lines if
the p-1-antsource contains process emission
sourcecunits, not regulated by Subparts B, E, F
(excluding Section 219.204(1) of this Part), H
(excluding Section 219.405 of this Part),
Q,
R, S,
T (excluding Section 219.486 of this Part), V, X,
e~Z or BB of this Part, which as a group both:
A) hfiave maximum theoretical emissions of 91 Mg
(100 tons) or more per calendar year of VON
if no air pollution control equipment were
used, and
01 ~O-Q8~8

442
B)
a~re not limited to less than 91 Mg
(100 tons) of VOM per calendar year if no air
pollution control equipment were used,
through production or capacity limitations
contained in a federally enforceable
construction permit or SIP revision.
2) If a p-1antsou~c~ceases to fulfill the criteria of
subsection (b) (1) of this Section, the limitations
of Section 219.204(1) of this Part shall continue
to apply to any wood furniture coating line which
was ever subject to the limitations of Section
219.204(1) of this Part.
3) For the purposes of subsection (b) of this
Section, an emission -s-eurccunit shall be
considered regulated by a Subpart if it is subject
to the limitations of that Subpart. An emission
sourceunit is not considered regulated by a
Subpart if it is not sublect to the limits of that
Subpart, e.g., the emission unit is covered by an
exemption in the Subpart or the applicability
criteria of the Subpart are not met. its ciniss-ions-
arc below the applicability cutoff level or if the
source is covered by an exemption.
4) Any owner or operator of a wood furniture coating
line to which the limitations of this Subpart are
not applicable due to the criteria in subsection
(b) of this Section shall, upon request by the
Agency or the USEPA, submit records to the Agency
and the USEPA within 30 calendar days from the
date of the request that document that the coating
line is exempt from the limitations of this
Subpart.
(Source: Amended at
Ill. Req.
______,
effective
__________)
Section 219.209
Exemption From General Rule on Use of Organic
Material
No owner or operator of a coating line subject to the limitations
of Section 219.204 of this Part is required to meet the
limitations of Subpart G (Section 219.301 or 219.302) of this
Part, after the date by which the coating line is required to
meet Section 219.204 of this Part.
(Source: Amended at — Ill. Reg.
______,
effective
________
Section 219.210
Compliance Schedule
Every owner or operator of a coating line (of a type included
01 ~0-08L~.g

443
within Section 219.204 of this Part) shall comply with the
requirements of Section 219.204, 219.205k 219.207 or 219.208 and
Section 219.211 of this Part in accordance with the appropriate
compliance schedule as specified in subsection (a), (b), (c) or
(d) below:
a) No owner or operator of a coating line which is
exempt
from the limitations of Section 219.204 of this Part
because of the criteria in Section 219.208(a) of this
Part shall operate said coating line on or after a date
consistent with Section 219.106 of this Part, unless
the owner or operator has complied with, and continues
to comply with, Section 219.211(b) of this Part. Wood
furniture coating lines are not subject to Section
219.211(b) of this Part.
b) No owner or operator of a coating line complying by
means of Section 219.204 of this Part shall operate
said coating line on or after a date consistent with
Section 219.106 of this Part, unless the owner or
operator has complied with, and continues to comply
with, Sections 219.204 and 219.211(c) of this Part.
c) No owner or operator of a coating line complying by
means of Section 219.205 of this Part shall operate
said coating line on or after a date consistent with
Section 219.106 of this Part, unless the owner or
operator has complied with, and continues to comply
with, Sections 219.205 and 219.211(d) of this Part.
d) No owner or operator of a coating line complying by
means of Section 219.207 of this Part shall operate
said coating line on or after a date consistent with
Section 219.106 of this Part, unless the owner or
operator has complied with, and continues to comply
with, Sections 219.207 and 219.211(e) of this Part.
(Source: Amended at — Ill. Reg.
, effective
___________/
Section 219.211
Recordkeeping and Reporting
a) The VON content of each coating and the efficiency of
each capture system and control device shall be
determined by the applicable test methods and
procedures specified in Section 219.105 of this Part to
establish the records required under this Section.
b) Any owner or operator of a coating line which is
exempted from the limitations of Section 219.204 g~.
this Part because of Section 219.208(a) of this Part
shall comply with the following:
01 i40-0850

444
1) By a date consistent with Section 219.106 of this
Part, the owner or operator of a facilitycoating
line or group of coating lines referenced in this
subsection
jJ~I
of this Section shall certify to
the Agency that the facilitycoating line or group
of coating lines is exempt under the provisions of
Section 219.208(a) of this Part. Such
certification shall include:
A) A declaration that the facilitycoating line
is exempt from the limitations of Section
219.204 of this Part because of Section
219.208(a) of this Part and
B) Calculations which demonstrate that the
combined VON emissions from a~the coating
line and all other coating lines in the same
category at the facility never exceed 6.8 kg
(15 lbs) per day before the application of
capture systems and control devices. The
following equation shall be used to calculate
total VON emissions:
mn
Te
=
E
E (A1 B1)~
j=1 1=1
where:
T~= Total VON emissions from coating lines
at a facility each day before the
application of capture systems and
control devices in units of kg/day
(lbs/day)T1
m
=
Number of coating lines at the
facilitysource that otherwise would
be subject to the same subsection
of Section 219.104 of this Part
(because they belong to the same
category, e.g., can coating)~~
j
=
Subscript denoting an individual
coating line-ri.
n
=
Number of different coatings as
applied each day on each coating
line at the facility,i.
I
=
Subscript denoting an individual
coating~
01 L~U-035I

445
A1
=
Weight of VON per volume of each
coating (minus water and any
compounds which are specifically
exempted from the definition of
VON) as applied each day on each
coating line at the facility in
units of kg VON/i (lbs VOM/gal)~
B1
=
Volume of each coating (minus water
and any compounds which are
specifically exempted from the
definition of VON) as applied each
day on each coating line at the
facility in units of i/day
(gal/day). The instrument or
method by which the owner or
operator accurately measured or
calculated the volume of each
coating as applied on each coating
line each day shall be described in
the certification to the Agency.
2)
On and after a date consistent with Section
219.106 of this Part, the owner or operator of a
facilitycoating line or group of lines referenced
in this subsection shall collect and record all of
the following information each day for each
coating line and maintain the information at the
faciiitysource for a period of three years:
A) The name and identification number of each
coating as applied on each coating line.
B) The weight of VON per volume and the volume
of each coating (minus water and any
compounds which are specifically exempted
from the definition of VON) as applied each
day on each coating line.
3) On and after a date consistent with Section
219.106 of this Part, the owner or operator of a
facilitycoating line or group of coating lines
exempted from the limitations
of Section 219.204
of this Part because of Section 219.208(a) of this
Part shall notify the Agency of any record showing
that total VON emissions from the coating
facilityline or group of coating lines exceed
6.8 kg (15 lbs) in any day before the application
of capture systems and control devices by sending
a copy of such record to the Agency within 30 days
after the exceedance occurs.
01 L~O-0852

446
c) Any owner or operator of a coating line subject to the
limitations of Section 219.204 of this Part other than
Section 219.204 (a) (2) and (a) (3) and complying by means
of Section 219.204 of this Part shall comply with the
following:
1) By a date consistent with Section 219.106 of this
Part, or upon initial start-up of a new coating
line, or upon changing the method of compliance
from an existing subject coating line from Section
219.205 or Section 219.207 to Section 219.204 of
this Part the owner or operator of a subject
coating line shall certify to the Agency that the
coating line will be in compliance with Section
219.204 of this Part on and after a date
consistent with Section 219.106 of this Part, or
on and after the initial start-up date. Such
certification shall include:
A) The name and identification number of each
coating as applied on each coating line.
B) The weight of VON per volume of each coating
(minus water and any compounds which are
specifically exempted from the definition of
VOM) as applied each day on each coating
line.
For coating lines subject to Section
210.204 (a) (3) certIfication snaii lnciuue:
4-)- The name and identification number of
each coating line which will comply by
means- of Section 219.204(a) (3),
4-i-)- The name and identification number of
each coatinr~as- ~,r~r~1icdon each coatina
line,
iii) The weight of VON per volume of each
coating as applied on each coating line,
The instrument or method by which the
owner or operator will accurately
measure or calculate the volume of each
coating as applied each day on each
coating linc-~-
v-)- The method by which the owner
operator will create and maintain
records each day as required i-n
~fl
~t-0-0353

447
subsection (c) (2) below for coating
-1-i-nec subject to Section 219.204(a) (3),
v-i-)- An example format in which the records
required in subsection (c) (2) below for
coating lines subject to Section
219.204(a) (3).
2) On and after a date consistent with Section
219.106 of this Part, or on and after the initial
start—up date, the owner or operator of a sublect
coating line subject to the limitations of &ection
219.204 and complying by means- of Section 219.204
shall collect and record all of the following
information each day for each coating line and
maintain the information at the facilitysource for
a period of three years:
A) The name and identification number of each
coating as applied on each coating line.
B) The weight of VOM per volume of each coating
(minus water and any compounds which are
specifically exempted from the definition of
VON) as applied each day on each coating
line.
?-)-
For coating lines subject to Section
218.204(a) (3) the owner or operator shall
maintain all records- necessary to calculate
the daily-weighted average VON content from
the coating line in accordance with the
proposal submitted, and approved by the
USEPA~ rnir~uantto Section 218.204(a) (3).
3)
On and after a date consistent with Section
219.106 of this Part, the owner or operator of a
subject coating line shall notify the Agency in
the following instances:
A) Any record showing violation of Section
219.204 of this Part shall be reported by
sending a copy of such record to the Agency
within 30 days following the occurrence of
the violation, except that any record showing
a violation of Section 219.204(a) (3) shall be
reported by sending a copy of such record to
the Agency within 15 days from the end of the
month in which the violation occurred.
B) At least 30 calendar days before changing the
method of compliance with Section 219.204
01 1~0-085I4

448
from Section 219.204 to Section 219.205 or
Section 219.207 of this Part, the owner or
operator shall comply with all requirements
of subsection (d) (1) or (e) (1) below,
respectively. Upon changing the method of
compliance with Section 219.204 from Section
219.204 to Section 219.205 or Section 219.207
of this Part, the owner or operator shall
comply with all requirements of subsection
(d) or (e) of this Section, respectively.
G)- For coating lines- subject to Section
219.204(a) (3), the owner or operator shall
notify the Agency of any change to ~he
topcoating operation at least 30 days before
the change is effected.
The Agency s-hall
determine whether or not determines that
recertification testing is required, then ~e
owner or operator s-hall submit a proposal to
the Agency to test within 30 days and retest
within 30 days of the Agency’s- approval of
the rn-rrnosal.
d) Any owner or operator of a coating line subject to the
limitations of Section 219.204 of this Part and
complying by means of Section 219.205 of this Part
shall comply with the following:
1) By a date consistent with Section 219.106 of this
Part, or upon initial start—up of a new coating
line, or upon changing the method of compliance
for an existing subject coating line from Section
219.204 or Section 219.207 to Section 219.205 ~
this Part the owner or operator of the subject
coating line shall certify to the Agency that the
coating line will be in compliance with Section
219.205 on and after a date consistent with
Section 219.106 of this Part, or on and after the
initial start-up date. Such certification shall
include:
A) The name and identification number of each
coating line which will comply by means of
Section 219.205 of this Part.
B) The name and identification number of each
coating as applied on each coating line.
C)
The weight of VOM per volume and the volume
of each coating (minus water and any
compounds which are specifically exempted
from the definition of VON) as applied each
01
~0-U855

449
day on each coating line.
D) The instrument or method by which the owner
or operator will accurately measure or
calculate the volume of each coating as
applied each day on each coating line.
E) The method by which the owner or operator
will create and maintain records each day as
required in subsection (d) (2) of this
Section.
F) An example of the format in which the records
required in subsection (d) (2) of this Section
will be kept.
2) On and after a date consistent with Section
219.106 of this Part, or on and after the initial
start—up date, the owner or operator of a sublect
coating line subject to the limitations of Section
219.204 and complying by means of Section 219.205
shall collect and record all of the following
information each day for each coating line and
maintain the information at the facilitysource for
a period of three years:
A) The name and identification number of each
coating as applied on each coating line.
B)
The weight of VOM per volume and the volume
of each coating (minus water and any
compounds which are specifically exempted
from the definition of VON) as applied each
day on each coating line.
C)
The daily-weighted average VON content of all
coatings
as applied on each coating line as
defined in Section 219.104 of this Part.
3) On and after a date consistent with Section
219.106 of this Part, the owner or operator of a
subject coating line shall notify the Agency in
the following instances:
A) Any record showing violation of Section
219.205 of this Part shall be reported by
sending a copy of such record to the Agency
within 30 days following the occurrence of
the violation.
B)
At least 30 calendar days before changing the
method of compliance with this subpart from
01 ~0-0856

450
Section 219.205 to Section 219.204 or Section
219.207 of this Part, the owner or operator
shall comply with all requirements of
subsection (c) (1) or (e) (1) of this Section,
respectively. Upon changing the method of
compliance with this subpart from Section
219.205 to Section 219.204 or Section 219.207
of this Part, the owner or operator shall
comply with all requirements of subsection
(c) or (e) of this Section, respectively.
e)
Any owner or operator of a coating
line subject to the
limitations of Section 219.207 and complying by means
of Section 219.207(c), (d), (e), (f), (g) or (h) ~
this Part shall comply with the following:
1) By a date consistent with Section 219.106 of this
Part, or upon initial start—up of a new coating
line, or upon changing the method of compliance
for an existing coating line from Section 219.204
or Section 219.205 to Section 219.207 of this
Part, the owner or operator of the subject coating
line shall perform all tests and submit to the
Agency the results of all tests and calculations
necessary to demonstrate that the subject coating
line will be in compliance with Section 219.207 Q~
this Part on and after a date consistent with
Section 219.106 of this Part, or on and after the
initial start-up date.
2) On and after a date consistent with Section
219.106 of this Part, or on and after the initial
start—up date, the owner or operator of a coating
line subject to the limitations of Section 219.207
subject and complying by means of Section
219.207(c), (d), (e), (f), (g), or (h) shall
collect and record all of the following
information each day for each coating line and
maintain the information at the facilitysource for
a period of three years:
A) The weight of VON per volume of coating
solids as applied each day on each coating
line, if complying pursuant to Section
219.207(b) (2) of this Part.
B) Control device monitoring data.
C)
A log of operating time for the capture
system, control device, monitoring equipment
and the associated coating line.
01 ~Q-0857

451
D) A maintenance log for the capture system,
control device and monitoring equipment
detailing all routine and non—routine
maintenance performed including dates and
duration of any outages.
3) On and after a date consistent with Section
219.106 of this Part, the owner or operator of a
subject coating line shall notify the Agency in
the following instances:
A)
Any record showing violation of Section
219.207 of this Part shall be reported by
sending a copy of such record to the Agency
within 30 days following the occurrence of
the violation.
B) At least 30 calendar days before changing the
method of compliance with this Subpart from
Section 219.207 to Section 219.204 or Section
219.205 of this Part, the owner or operator
shall comply with all requirements of
subsection (c) (1) or (d) (1) of this Section,
respectively. Upon changing the method of
compliance with this subpart from Section
219.207 to Section 219.204 or Section 219.205
of this Part, the owner or operator shall
comply with all requirements of subsection
(c) or (d) of this Section, respectively.
~j. Any owner or operator of a primer surfacer operation or
topcoat operation subject to the limitations of Section
219.204 (a) (2) or (a) (3)of this Part shall comply with
the following:
-
fl
By a date consistent with Section 219.106 of this
Part, or upon initial
start—up of a new coating
operation, the owner or operator of a subject
coating operation shall certify to the Agency that
the operation will be in compliance with Section
219.204 of this Part on and after a date
consistent with Section 219.106 of this Part, or
on and after the initial
start-up date. Such
certification shall include:
~j The name and identification number of each
coating operation which will comply by means
of Section 219.204(a) (2) and (a)(3) of this
Part and the name and identification
number
of each coating line in each coating
operation.
0
~0-Q858

452
~j The name and identification number of each
coating as applied on each coating line in
the coating operation.
~j The weight of VON ~er volume of each coating
(minus water and any compounds which are
specifically exempted from the definition of
VON) as applied each day on each coating
line.
pj The transfer efficiency and control
efficiency measured for each coating line.
~j Test reports, including raw data and
calculations documenting the testing
performed to measure transfer efficiency and
control efficiency.
fi
The instrument or method by which the owner
or operator will accurately measure or
calculate the volume of each coating as
applied each day on each coating line.
~j The method by which the owner or operator
will create and maintain records each daY as
reguired in subsection (f) (2) below.
~iL
An example format for presenting the records
required in subsection (f) (2) below.
~j On and after a date consistent with Section
219.106 of this Part, or on and after the initial
start—up date, the owner or operator of a sublect
coating operation shall collect and record all of
the following information each day for each
topcoat or primer surfacer coating operation and
maintain the information at the source for a
period of three years:
~j All information necessary to calculate the
daily—weighted average VOM emissions from the
coating operations in kg (lbs) per 1 (gal) of
coating solids deposited in accordance with
the proposal submitted, and approved pursuant
to Section 219.204(a) (2) or (a)(3) of this
Part including:
il
The name and identification number of
each coating as applied on each coating
operation.
LiL
The weight of VON per volume of each
01 L~.0-0859

453
coating (minus water and any compounds
which are specifically exempted from the
definition of VON) as applied each day
on each coating operation.
~J
If
a control device(s) is used to control VOM
emissions, control device monitoring data; a
log of operating time for the capture system,
control device, monitoring equipment and the
associated coating operation; and a
maintenance log for the capture system.
control device and monitoring equipment.
detailing all routine and non—routine
maintenance performed including dates and
duration of any outages.
~j On and after a date consistent with Section
219.106 of this Part or on and after the initial
start—up date, the owner or operator of a subject
coating operation shall determine and record the
daily VON emissions in kg(lbs) per 1 (gal) of
coating solids deposited in accordance with the
proposal submitted and approved pursuant to
Section 219.204(a) (2) or (a) (3) of this Part
within 10 days from the end of the month and
maintain this information at the source for a
period of three years.
il
On and
after a date consistent with Section
219.106 of this Part, the owner or operator of a
subject coating operation shall notify the A~encv
in the following instances:
~
Any record showing
a violation of Section
219.204 (a) (2) or (a) (3) of this Part shall be
reported by sending a copy of such record to
the Agency within 15 days from the end of the
month in which the violation occurred.
~j The owner or operator shall notify the Agency
of any change to the operation at least 30
days before the change is effected.
The
Agency shall determine whether or not
compliance testing is required. If the
Agency determines that compliance testing is
required, then the owner or operator shall
submit a testing proposal to the
Agency
within 30 days and test within 30 days of the
approval of the proposal by the Agency and
USEPA.
(Source: Amended at — Ill. Req.
______,
effective
OiL~i-
0860

454
SUBPART G: USE OF ORGANIC MATERIAL
Section 219.301
Use of Organic Material
No person shall cause or allow the discharge of more than 3.6
kg/hr (8 lbs/hr) of organic material into the atmosphere from any
emission sourccunit, except as provided in Sections 219.302,
219.303, 219.304 of this Part and the following exception: If no
odor nuisance exists the limitation of this Subpart shall apply
only to photochemically reactive material.
(Source: Amended at — Ill.
Reg.
_____,
effective
__________
Section 219.302
Alternative Standard
Emissions of organic material in excess of those permitted by
Section 219.301 of this Part are allowable if such emissions are
controlled by one of the following methods:
a) Flame, thermal or catalytic incineration so as either
to reduce such emissions to 10 ppm equivalent methane
(molecular weight 16) or less, or to convert 85 percent
of the hydrocarbons to carbon dioxide and water; or,
b) A vapor recovery system which adsorbs and/or condenses
at least 85 percent of the total uncontrolled organic
material that would otherwise be emitted to the
atmosphere; or,
c) Any other air pollution control equipment approved by
the Agency and approved by the USEPA as a SIP revision
capable of reducing by 85 percent or more the
uncontrolled organic material that would be otherwise
emitted to the atmosphere.
(Source: Amended at — Ill. Reg.
______,
effective
__________
Section 219.303
Fuel Combustion Emission Sources-Units
The provisions of Sections 219.301 and 219.302 of this Part shall
not apply to fuel combustion emission s-ourccsunits.
(Source: Amended at — Ill. Req.
______,
effective
___________
Section 219.304
Operations with Compliance Program
The provisions of Sections 219.301 and 219.302 of this Part shall
not apply to any owner, operator, user or manufacturer of paint,
varnish, lacquer, coatings or printing ink whose compliance
program and project completion schedule, as required by 35 Ill.
Adm. Code 201, provided for the reduction of organic material
used in such process to 20 percent or less of total volume by May
01 Li0-086
I

455
30, 1977.
(Source: Amended at — Ill. Req.
______,
effective
____
SUBPART H: PRINTING AND PUBLISHING
Section 219.401
Flexographic and Rotogravure Printing
a) No owner or operator of a subject flexographic,
packaging rotogravure or publication rotogravure
printing line shall apply at any time any coating or
ink unless the VON content does not exceed the
limitation specified in either subsection (a) (1) or
(a) (2) below. Compliance with this Section must be
demonstrated through the applicable coating or ink
analysis test methods and procedures specified in
Section 219.105(a) and the recordkeeping and reporting
requirements specified in Section 219.404(c) of this
Part. As an alternative to compliance with this
subsection, a subject printing line may meet the
requirements of subsection (b) or (c) below.
1) Forty percent VOM by volume of the coating and ink
(minus water and any compounds which are
specifically exempted from the definition of VOM),
or
2) Twenty-five percent VON by volume of the volatile
content in the coating and ink.
b) No owner or operator of a subject flexographic,
packaging rotogravure or publication rotogravure
printing line shall apply coatings or inks on the
subject printing line unless the weighted average, by
volume, VON content of all coatings and inks as applied
each day on the subject printing line does not exceed
the limitation specified in either subsection (a) (1)
(as determined by subsection (b) (l)j or subsection
(a)
(~))
(as determined by subsection (b) (2) of this
Section). Compliance with this subsection must be
demonstrated through
the applicable coating or ink
analysis test methods and procedures specified in
Section 219.105(a) of this Part and the recordkeeping
and reporting requirements specified in Section
219.404(d) of this Part.
1) The following equation shall be used to determine
if the weighted average VOM content of all
coatings and inks as applied each day on the
subject printing line exceeds the limitation
specified in subsection (a) (1) of this Section.
0IL~O- 0862

456
n
E C1 L1 (V~1+ VVOM1)
i=41
VOM(i)(A)
=
_______________________
n
E L1 (V~~+ VvoMi)
i=-i1
Where:
VON(L)(A)
=
The weighted average VOM content in
units of percent VON by volume of
all coatings and inks (minus water
and any compounds which are
specifically exempted from the
definition of VON) used each day-ri.
=
Subscript denoting a specific
coating or ink as applied~
n
=
The number of different coatings
and/or inks as applied each day on
a printing line-ri.
C1
=
The VOM content in units of percent
VOM by volume of each coating or
ink as applied (minus water and any
compounds which are specifically
exempted from the definition of
VON) ~ui.
L1
=
The liquid volume of each coating
or ink as applied in units of 1
(ga1)-~-~
=
The volume fraction of solids in each
coating or ink as applied, andi.
VVOM1
=
The volume fraction of VON in each
coating or ink as applied.
2) The following equation shall be used to determine
if the weighted average
VON content of all
coatings and inks as applied each day on the
subject printing
line exceeds
the limitation
specified in subsection (a) (2) of this Section.
n
E
C1 L1 VVMI
VON(~)(5)
=
i=1
n
o~t1o-0863

457
E
L1 ~~/Mj
i=l
where:
VOM(I)(B)
=
The weighted average VON content in
units of percent VON by volume of
the volatile content of all
coatings and inks used each day,-~
i
=
Subscript denoting a specific coating or
ink as app1ie4,~
n
=
The number of different coatings and/or
inks as applied
each day on each
printing linei.
C1
=
The VOM content in
units of percent VON
by volume of the volatile matter in each
coating or ink as
app liedi.
=
The liquid volume of each coating or ink
as applied in units of 1 (gal), andi.
VVMI
=
The volume fraction of volatile matter
in each coating or ink as applied.
c) No owner or operator of a subject flexographic,
packaging rotogravure or publication rotogravure
printing line equipped with a capture system and
control device shall operate the subject printing line
unless the owner or operator meets the requirements in
subsection (c) (1), (c) (2) or (c) (3) and subsections
(c)(4), (c)(5) and (c)(6) below.
1) A carbon adsorption system is used which reduces
the captured VON emissions by at least 90 percent
by weight, or
2) An incineration system is used which reduces the
captured VOM emissions by at least 90 percent by
weight, or
3)
An alternative VON emission reduction system is
used which is demonstrated to have at least a
90 percent control device efficiency, approved by
the Agency and approved by USEPA as a SIP
revision, and
4) The
printing line
is equipped with a capture
system and control device that provides an overall
ULLfLJUO

458
reduction in VOM emissions of at least:
A) 75 percent where a publication rotogravure
printing line is employed, or
B) 65 percent where a packaging rotogravure
printing line is employed, or
C)
60 percent where a flexographic printing line
is employed, and
5) The control device is equipped with the applicable
monitoring equipment specified in Section
219.105(d) (2) of this Part and, except as provided
in Section 219.105(d) (3) of this Part, the
monitoring equipment is installed, calibrated,
operated and maintained according to vendor
specifications at all times the control device is
in use, and
6) The capture system and control device are operated
at all times when the subject printing line is in
operation. The owner or operator shall
demonstrate compliance with this subsection by
using the applicable capture system and control
device test methods and procedures specified in
Section 219.105(c) of this Part through Section
219.105(f) of this Part and by complying with the
recordkeeping and reporting requirements specified
in Section 219.404(e) of this Part.
(Source: Amended at
Ill. Reg.
______,
effective
___________
Section 219.402
Applicability
a) The limitations of Section 219.401 of this Part apply
to all flexographic and rotogravure printing lines at a
subject facilitysource. All facilities-sources with
flexographic and/or rotogravure printing lines are
subject facilities-sources unless:
1) Total maximum theoretical emissions of VON from
all flexographic and rotogravure printing line(s)
(including solvents used for cleanup operations
associated with flexographic and rotogravure
printing line(s)),
at the facilitysource
never
exceed 90.7 Mg 100 tons) per calendar year before
the application of capture systems and control
devices, or
2) A federally enforceable construction permit or SIP
revision for all
flexographic and rotogravure
0
i ~O-0Q55

459
printing line(s) at a facilitysource requires the
owner or operator to limit production or capacity
of these printing line(s) to reduce total VON
emissions from all flexographic and rotogravure
printing line(s) to 90.7 Mg (100 tons) or less per
calendar year before the application of capture
systems and control devices.
b) Upon achieving compliance with this Subpart, the
emission source is-f lexographic and rotogravure printing
lines are not required to meet Subpart G (Sections
219.301 or 219.302 of this Part). Emission sources
Flexographic and rotogravure printing lines exempt from
this Subpart are subject to Subpart G (Sections 219.301
or -24-5-~j~.-8-~02of this Part). Rotogravure or
flexographic equipment used for both roll printing and
paper coating is subject to this Subpart.
c) Once subject to the limitations of Section 219.401
~i
this Part, a flexographic or rotogravure printing line
is always subject to the limitations of Section 219.401
of this Part.
d) Any owner or operator of any flexographic or
rotogravure printing line that is exempt from the
limitations of Section 219.401 of this Part because of
the criteria in this Section is subject to the
recordkeeping and reporting requirements specified in
Section 219.404(b) of this Part.
(Source: Amended at — Ill. Req.
______,
effective
___________
Section 219.403
Compliance Schedule
Every owner or operator of a flexographic and/or rotogravure
printing line shall comply with the applicable requirements of
Section 219.401 and Section 219.404 of this Part in accordance
with the applicable compliance schedule specified in subsection
(a) , (b) , (c) or (d) below:
a) No owner or operator of a flexographic or rotogravure
printing line which is exempt from the limitations of
Section 219.401 of this Part because of the criteria in
Section 219.402 of this
Part shall operate said
printing line on or after a date consistent with
Section 219.106 of this Part, unless the owner or
operator has complied with, and continues to comply
with, Section 219.404(b) of this Part.
b) No owner or operator of a flexographic or rotogravure
printing line complying by means of Section 219.401(a)
of this Part shall operate said printing line on or
81 ~0-0866

460
after a date consistent with Section 219.106 of this
Part, unless the owner or operator has complied with,
and continues to comply with, Section 219.401(a) ~
this Part and Section 219.404(c) of this Part.
c) No owner or operator of a flexographic or rotogravure
printing line complying by means of Section 219.401(b)
of this Part shall operate said printing line on or
after a date consistent with Section 219.106 of this
Part, unless the owner or operator has complied with,
and continues to comply with, Section 219.401(b) and
Section 219.404(d) of this Part.
d) No owner or operator of a flexographic or rotogravure
printing line complying by means of Section 219.401(c)
of this Part shall operate said printing line on or
after a date consistent with Section 219.106 of this
Part, unless the owner or operator has complied with,
and continues to comply with, Section 219.401(c) and
Section 219.404(e) of this Part.
(Source: Amended at
Ill. Reg.
______,
effective
__________
Section 219.404
Recordkeeping and Reporting
a) The VON content of each coating and ink and the
efficiency of each capture system and control device
shall be determined by the applicable test methods and
procedures specified in Section 219.105 of this Part to
establish the records required under this Section.
b) Any owner or operator of a printing line which is
exempted from the limitations of Section 219.401
~i
this Part because of the criteria in Section 219.402 Qi
this Part shall comply with the following:
1)
By a date consistent with Section 219.106 of this
Part, the owner or operator of a
facilityflexographic and rotogravure printing line
to which this subsection is applicable shall
certify to the Agency that the facility
flexographic and rotogravure printing line is
exempt under the provisions of Section 219.402 g~
this Part. Such certification shall include:
A) A declaration that the facilityflexographic
and rotogravure printing line is exempt from
the limitations of the criteria in Section
219.401 because of Section 219.402 of this
Part, and
B)
Calculations which demonstrate that total
0 ~O-O867

461
maximum theoretical emissions of VOM from all
flexographic and rotogravure printing lines
at the facilitysource never exceed 90.7 Mg
(100 tons) per calendar year before the
application of capture systems and control
devices.
Total maximum theoretical
emissions
of VON for a flexographic or rotogravure
printing facilitysource is the sum of maximum
theoretical emissions of VON from each
flexographic and rotogravure printing line at
the facilitysource. The following equation
shall be used to calculate total maximum
theoretical emissions of VOM per calendar
year before the application of capture
systems and control devices for each
flexographic and rotogravure printing line at
the facilitysource:
A x B + 1095 (C x D x F)
where:
E~
Total maximum theoretical emissions
of VON from one flexographic or
rotogravure printing line in units
of kg/year (lbsfyear)i.
A
=
Weight of VOM per volume of solids
of the coating or ink with the
highest VON content as applied each
year on the printing line in units
of kg VOM/l (lbs VON/gal) of
coating or ink solids and~
B
=
Total volume of solids for all
coatings and inks that can
potentially be applied each year on
the printing line in units of
1/year (gal/year). The instrument
and/or method by which the owner or
operator accurately measured or
calculated the volume of each
coating and ink as applied and the
amount that can potentially be
applied each year on the printing
line shall be described in the
certification to the Agency-~
Weight of VOM per volume of
material for the cleanup material
or solvent with the highest VON
content as used each year on the
UI ~0-0868

462
printing line in units of Kg/l (lbs
VON/gal) of such material
D
=
The greatest volume of cleanup
material or solvent used in any
8-hour period
F
=
The highest fraction of cleanup
material or solvent which is not
recycled or recovered for offsite
disposal during any 8-hour period.
2) On and after a date consistent with Section
219.106 of this Part, the owner or operator of a
facility referenced in this subsection shall
collect and record all of the following
information each year for each printing line and
maintain the information at the facilitysource for
a period of three years:
A) The name and identification number of each
coating and ink as applied on each printing
line.
B) The VON content and the volume of each
coating and ink as applied each year on each
printing line.
3) On and after a date consistent with Section
219.106 of this Part, the owner or operator of a
facility exempted from the limitations of Section
219.401 of this Part because of the criteria in
Section 219.402 of this Part shall notify the
Agency of any record showing that total maximum
theoretical emissions of VON from all printing
lines exceed 90.7 Mg (100 tons) in any calendar
year before the application of capture systems and
control devices by sending a copy of such record
to the Agency within 30 days after the exceedance
occurs.
c) Any owner or operator of a printing line subject to the
limitations of Section 219.401 of this Part and
complying by means of Section 219.401(a) of this Part
shall comply with the following:
1) By a date consistent with Section 219.106 of this
Part, or upon initial start-up of
a new printing
line, or upon changing the method of compliance
from an existing subject printing line from
Section 219.401(b) or Section 219.401(c) to
Section 219.401(a) of
this Part, the owner or
0 ~0-O869

463
operator of a subject printing line shall certify
to the Agency that the printing line will be in
compliance with Section 219.401(a) of this Part on
and after a date consistent with Section 219.106
of this Part, or on and after the initial start-up
date. Such certification shall include:
A) The name and identification number of each
coating and ink as applied on each printing
line.
B) The VON content of each coating and ink as
applied each day on each printing line.
2) On and after a date consistent with Section
219.106 of this Part, or on and after the initial
start—up date,
the owner or operator of a printing
line subject to the limitations of Section 219.401
of this Part and complying by means of Section
219.401(a) of this Part shall collect and record
all of the following information each day for each
coating line and maintain the information at the
facility source for a period of three years:
A) The name and identification number of each
coating and ink as applied on each printing
line.
B) The VON content of each coating and ink as
applied each day on each printing line.
3) On and after a date consistent with Section
219.106 of this Part, the owner or operator of a
subject printing
line shall notify the Agency in
the following instances:
A) Any record showing violation of Section
219.401(a) of this Part shall be reported by
sending a copy of such record to the Agency
within 30 days following the occurrence of
the violation.
B) At least 30 calendar days before changing the
method of compliance with Section 219.401
~i
this Part from Section 219.401(a) to Section
219.401(b) or (c) of
this Part, the owner or
operator shall comply with all requirements
of subsection (b) (1)- or (c) (1) (d) (1) or
(e) (1) of this Section, respectively. Upon
changing the method of compliance with
Section 219.401 of this Part from Section
219.401(a) to Section 219.401(b) or (c) ~
01 ~0-0870

464
this Part, the owner or operator shall comply
with all requirements of subsection -(-è-)-j~~or
-(-e-)-(e) of this Section, respectively.
d) Any owner or operator of a printing line subject to the
limitations of Section 219.401 of this Part and
complying by means of Section 219.401(b) of this Part
shall comply with the following:
1) By a date consistent with Section 219.106 of this
Part, or upon initial start-up of a new printing
line, or upon changing the method of compliance
for an existing subject printing line from Section
219.401(a) or (c) to Section 219.401(b) of this
Part, the owner or operator of the subject
printing line shall certify to the Agency that the
printing line will be in compliance with Section
219.401(b) of this Part on and after a date
consistent with Section 219.106 of this Part, or
on and after the initial start-up date. Such
certification shall include:
A) The name and identification number of each
printing line which will comply by means of
Section 219.401(b) of this Part.
B) The name and identification number of each
coating and ink available for use on each
printing line.
C) The VON content of each coating and ink as
applied each day on each printing line.
D) The instrument or method by which the owner
or operator will accurately measure or
calculate the volume of each coating and ink
as applied each day on each printing line.
E) The method by which the owner or operator
will create and maintain records each day as
required in subsection -f~-)-j~~(2)of this
Section.
F) An example of the format in which the records
required in subsection -(-~-)-j~j(2)of this
Section will be kept.
2) On and after a date consistent with Section
219.106 of this Part, or on and after the initial
start—up date, the owner or operator of a printing
line subject
to the limitations of Section 219.401
and complying by means of Section 219.401(b)
~i
01
~0-087I

465
this Part shall collect and record all of the
following information each day for each printing
line and maintain the information at the
facilitysource for a period of three years:
A) The name and identification number of each
coating and ink as applied on each printing
line.
B) The VON content and the volume of each
coating and ink as applied each day on each
printing line.
C) The daily-weighted average VOM content of all
coatings and inks as applied on each printing
line.
3) On and after a date consistent with Section
219.106 of this Part, the owner or operator of a
subject printing line shall notify the Agency in
the following instances:
A) Any record showing violation of Section
219.401(b) of this Part shall be reported by
sending a copy of such record to the Agency
within 30 days following the occurrence of
the violation.
B) At least 30 calendar days before changing the
method of compliance with Section 219.401 p~
this Part from Section 219.401(b) to Section
219.401(a) or 219.401(c) of this Part, the
owner or operator shall comply with all
requirements of subsection (c) (1) or (e) (1)
of this Section, respectively.
Upon changing
the method of compliance with Section 219.401
of this Part from Section 219.401(b) to
Section 219.401(a) or (c) of this Part, the
owner or operator shall comply with all
requirements of subsection (c) or (e) of this
Section, respectively.
e) Any owner or operator of a printing line subject to the
limitations of Section 219.401 of this Part and
complying by means of Section 219.401(c) of this Part
shall comply with the following:
1) By a date consistent with Section 219.106 of this
Part, or upon initial start-up of a new printing
line, or upon changing the method of compliance
for an existing printing line from Section
219.401(a) or (b) to Section 219.401(c) of thi~
01 ~0-0872

466
Part, the owner or operator of the subject
printing line shall perform all tests and submit
to the Agency the results of all tests and
calculations necessary to demonstrate that the
subject printing line will be in compliance with
Section 219.401(c) of this Part on and after a
date consistent with Section 219.106 of this Part,
or on and after the initial start-up date.
2) On and after a date consistent with Section
219.106 of this Part, or on and after the initial
start—up date, the owner or operator of a printing
line subject to the limitations of Section 219.401
of this Part and complying by means of Section
219.401(c) of this Part shall collect and record
all of the following information each day for each
printing line and maintain the information at the
facility for a period of three years:
A) Control device monitoring data.
B) A log of operating time for the capture
system, control device, monitoring equipment
and the associated printing line.
C) A maintenance log for the capture system,
control device and monitoring equipment
detailing all routine and non—routine
maintenance performed including dates and
duration of any outages.
3) On and after a date consistent with Section
219.106 of this Part, the owner or operator of a
subject printing line shall notify the Agency in
the following instances:
A) Any record showing violation of Section
219.401(c) of this Part, shall be reported by
sending a copy of such record to the Agency
within 30 days following the occurrence of
the violation.
B) At least 30 calendar days before changing the
method of compliance with Section 219.401 g~
this Part from Section 219.401(c) to Section
219.401(a) or (b) of this
Part, the owner or
operator shall comply with all requirements
of subsection (c) (1) or (d) (1) of this
Section, respectively. Upon changing the
method of compliance with Section 219.401 ~
this Part from Section 219.401(c) to Section
219.401(a) or (b) of this Part, the owner or
01 ~0-0873

467
operator shall comply with all requirements
of subsection (c) or (d) of this Section,
respectively.
(Source: Amended at — Ill. Req.
______,
effective
__________
Section 219.405
Heatset-Web-Off set Lithographic Printing
a) Applicability
1) The limitations of subsection (b) below apply to
all heatset-web-offset lithographic printing lines
at a subject facilitysource. All facilities
sources with heatset-web-offset lithographic
printing lines are subject facilities sources
unless:
A) Total maximum theoretical emissions of VOM
from all heatset-web-offset lithographic
printing lines at the facilitysource never
exceed 90.7 Mg (100 tons) per calendar year
in the absence of air pollution control
equipment, or
B) A federally enforceable construction permit
or SIP revision for all heatset—web-off set
lithographic printing lines(s) at a
facilitysource requires the owner or operator
to limit production or capacity of these
printing line(s) to reduce total VON
emissions from all heatset—web—off set
lithographic printing line(s) to 90.7 Mg
(100 tons) per calendar year or less in the
absence of air pollution control equipment,
and
2) Any owner or operator of any heatset—web—offset
lithographic printing line that is exempt from the
limitations in subsection (b) of this Section
because of the criteria in subsection (a) (1) g~
this Section shall be subject to the recordkeeping
and reporting requirements in subsection
(c)
(1) ç~.
this Section.
b) Specific Provisions. No owner or operator of a subject
heatset—web—offset printing line may cause or allow the
operation of the subject heatset—web-off set printing
line unless the owner or operator meets the
requirements in subsection (b) (1) or (b) (2) and the
requirements in subsections (b) (3) and (b) (4) below.
1) An afterburner system is installed and operated
01 ~0-087L~

468
that reduces 90 percent of the VON emissions from
the dryer exhaust, or
2) The fountain solution contains no more than
8 percent, by weight, of VON and a condensation
recovery system is installed and operated that
removes at least 75 percent of the non—isopropyl
alcohol organic materials from the dryer exhaust,
and
3) The control device is equipped with the applicable
monitoring equipment specified in Section
219.105(d) (2) of this Part and the monitoring
equipment is installed, calibrated, operated and
maintained according to vendor specifications at
all times the control device is in use, and
4) The control device is operated at all times when
the subject printing line is in operation. The
owner or operator shall demonstrate compliance
with this Section by using the applicable test
methods and procedures specified in Section
219.105(a), (d), and (f) of this Part and by
complying with the recordkeeping and reporting
requirements specified in subsection (c) below.
c) Recordkeeping and Reporting. The VON content of each
fountain solution and ink and the efficiency of each
control device shall be determined by the applicable
test methods and procedures specified in Section
219.105 of this Part to establish the records required
under this subsection.
1) Any owner or operator of a printing line which is
exempted from the limitations of subsection (b)
~t
this Section because of the criteria in subsection
(a) of this Section shall comply with the
following:
A) By a date consistent with Section 219.106 ~
this Part, the owner or operator of a
facility heatset-web-off set lithographic
printing line to which subsection (c) (1) ~
this Section is applicable shall certify to
the Agency that the facility is heatset-
web-offset lithographic printing line exempt
under the provisions of subsection (a) ~
this Section. Such certification shall
include:
1) A
declaration that the facility heatset-
web-offset lithographic printing line is
0114.0-0875

469
exempt from the limitations of
subsection (b) of this Section because
of the criteria in subsection (a) of
this Section, and
ii) Calculations which demonstrate that
total maximum theoretical emissions of
VON from all heatset-web-offset
lithographic printing lines at the
facilitysource never exceed 90.7 Mg
(100 tons) per calendar year before the
application of air pollution control
equipment. Total maximum theoretical
emissions of VON for a heatset—
web-offset lithographic printing
facility source is the sum of maximum
theoretical emissions of VOM from each
heatset-web—offset lithographic printing
line at the facility. The following
equation shall be used to calculate
total maximum theoretical emissions of
VON per calendar year in the absence of
air pollution control equipment for each
heatset-web—off set lithographic printing
line at the facilitysource.
E~
=
(A x B) + (C x D)+1095 (F x G
x H)
100
where:
=
Total maximum theoretical
emissions of VOM from one
heatset-web-offset printing
line in units of kg/year
(lbs/year) Ti.
A
=
Weight of VOM per volume of
solids of ink with the highest
VON content as applied each
year on the printing line in
units of kg VOM/l (lbs
VON/gal) of solids,- and~
B
=
Total volume of solids for all
inks that can potentially be
applied each year on the
printing line in units of
1/year (gal/year). The
instrument or method by which
the owner or operator
accurately measured or
01~~P—O876

470
calculated the volume of each
ink as applied and the amount
that can potentially be
applied each year on the
printing line shall be
described in the certification
to the Agency-ri
C
=
The weight percent VON of the
fountain solution with the
highest VON content--1
D
=
The total volume of fountain
solution that can potentially
be used each year on the
printing line in units of
1/year (gal/year). The
instrument and/or method by
which the owner or operator
accurately measured or
calculated the volume of each
fountain solution used and the
amount that can potentially be
used each year on the printing
line shall be described in the
certification to the Agency--i
F
=
Weight of VON per volume of
material for the cleanup
material or solvent with the
highest VON content as used
each year on the printing line
in units of Kg/l (lbs VON/gal)
of such material;
The greatest volume of cleanup
material or solvent used in
any 8-hour period;
The highest fraction of
cleanup material or solvent
which is not recycled or
recovered for offsite disposal
during any 8-hour period.
B) On and after a date consistent with Section
219.106 of this Part, the owner or operator
of a facility heatset-web-off set lithographic
printing line to which subsection (c) (1) g~
this Section is applicable shall collect and
record all of the following information each
year for each printing line and maintain the
01
L~0-0877

471
information at the facilitysource for a
period of three years:
i) The name and identification of each
fountain solution and ink as applied on
each printing line.
ii) The VON content and the volume of each
fountain solution and ink as applied
each year on each printing line.
C) On and after a date consistent with Section
219.106 of this Part, the owner or operator
of a facilityheatset-web-off set lithographic
printing line exempted from the limitations
of subsection (b) of this Section because of
the criteria in subsection (a) of this
Section shall notify the Agency of any record
showing that total maximum theoretical
emissions of VON from all printing lines
exceed 90.7 Mg (100 tons) in any calendar
year in the absence of air pollution control
equipment by sending a copy of such record to
the Agency within 30 days after the
exceedance occurs.
2) Any owner or operator of a printing line subject
to the limitations of subsection (b) of this
Section and complying by means of subsection
(b) (1) of this Section shall comply with the
following:
A) By a date consistent with Section 219.106 ~
this Part, or upon initial start—up of a new
printing line, or upon changing the method of
compliance for an existing printing line from
subsection (b) (2) to subsection (b) (1) of
this Section the owner or operator of the
subject printing line shall perform all tests
and submit to the Agency the results of all
tests and calculations necessary to
demonstrate that the subject printing line
will be in compliance with subsection (b) (1)
of this Section on and after a date
consistent with Section 219.106 of this Part,
or on and after the initial start-up date.
B) On and after a date consistent with Section
219.106 of this Part, or on and after the
initial start-up date, the owner or operator
of a printing line subject to the limitations
of subsection (b) of this Section and
DI ~i.O-Q878

472
complying by means of subsection (b)(l) p~
this Section shall collect and record the
following information each day for each
printing line and maintain the information at
the facilitysource for a period of three
years:
i) Control device monitoring data.
ii) A log of operating time for the control
device, monitoring equipment and the
associated printing line.
iii) A maintenance log for the control device
and monitoring equipment detailing all
routine and nonroutine maintenance
performed including dates and duration
of any outages.
C) On and after a date consistent with Section
219.106 of this Part, the owner or operator
of a subject printing line shall notify the
Agency in the following instances:
i) Any record showing violation of
subsection (b) (1) of this Section shall
be reported by sending a copy of such
record to the Agency within 30 days
following the occurrence of the
violation.
ii) At least 30 calendar days before
changing the method of compliance with
subsection (b) of this Section from
subsection (b) (1) to (b) (2) of this
Section, the owner or operator shall
comply with all requirements of
subsection (c) (3) (A) of this Section.
Upon changing the method of compliance
with subsection (b) from subsection
(b) (1) to (b) (2) of this Section, the
owner or operator shall comply with all
requirements of subsection (c) (3)
ci
this Section.
3) Any owner or operator of a printing line subject
to the limitations of subsection (b) of this
Section and complying by means of subsection
(b) (2) of this Section shall comply with the
following:
A) By a date consistent with Section 219.106
Q~.
01
~0-0879

473
this Part, or upon initial start—up of a new
printing line, or upon changing the method of
compliance for an existing printing line from
subsection (b) (1) to (b) (2) of this Section
the owner or operator of the subject printing
line shall perform all tests and submit to
the Agency and the USEPA the results of all
tests and calculations necessary to
demonstrate that the subject printing line
will be in compliance with subsection (b) (2)
of this Section on and after a date
consistent with Section 219.106 of this Part,
or on and after the initial start-up date.
B) On and after a date consistent with Section
219.106 of this Part, or on and after the
initial start-up date, the owner or operator
of a printing line subject to the limitations
of subsection (b) of this Section and
complying by means of subsection (b)
(2)
~
this Section shall collect and record the
following information each day for each
printing line and maintain the information at
the facilitysource for a period of three
years:
i) The VON content of the fountain solution
used each day on each printing line.
ii) A log of operating time for the control
device and the associated printing line.
iii) A maintenance log for the control device
detailing all routine and non-routine
maintenance performed including dates
and duration of any outages.
C) On and after a date consistent with Section
219.106 of this Part, the owner or operator
of a subject printing line shall notify the
Agency in the following instances:
i) Any record showing violation of
subsection (b) (2) of this Section shall
be reported by sending a copy of such
record to the Agency within 30 days
following the occurrence of the
violation.
ii) At least 30 calendar days before
changing the method of compliance with
subsection (b) of this Section
from

474
subsection (b) (2) to (b) (1) of this
Section, the owner or operator shall
comply with all requirements of
subsection (c) (2) (A) of this Section.
Upon changing the method of compliance
with subsection (b) from subsection
(b) (2) to (b) (1) of this Section, the
owner or operator shall comply with all
requirements of subsection (c) (2) ~
this Section.
d) Compliance Schedule. Every owner or operator of a
heatset-web-offset lithographic printing line shall
comply with the applicable requirements of subsections
(b) and (c) of this Section in accordance with the
applicable compliance schedule specified in subsection
(d) (1) , (d)
(2)
,
or (d) (3) below:
1) No owner or operator of a heatset—web-offset
lithographic printing line which is exempt from
the limitations of subsection (b) of this Section
because of the criteria in subsection (a) of this
Section shall operate said printing line on or
after a date consistent with Section 219.106 of
this Part, unless the owner or operator has
complied with, and continues to comply with,
subsection -(4Dfj~j(1) and (c) (1) of this Section.
2) No owner or operator of a heatset—web—offset
lithographic printing line complying by means of
subsection (b) (1) of this Section shall operate
said printing line on or after a date consistent
with Section 219.106 of this Part, unless the
owner or operator has complied with, and continues
to comply with, subsection (b) (2) (b) (1), (b) (3),
(b) (4) and (c) (2) of this Section.
3) No owner or operator of a heatset—web—off set
lithographic printing line complying by means of
subsection (b) (2) of this Section shall operate
said printing line on or after a date consistent
with Section 219.106 of this Part, unless the
owner or operator has complied with, and continues
to comply with, subsection (b)(2), (b)(3), (b)(4I~
~
(c) (3) of this Section.
(Source: Amended at
Ill. Reg.
______,
effective
__________
)
SUBPART
Q:
LEAKS FROM SYNTHETIC ORGANIC CHEMICAL AND POLYMER
MANUFACTURING EQUIPMENT PLANT
Section 219.421
General Requirements
81
t4.Q-0881

475
The owner or operator of a plant which processes more than 3660
mg/yr (4033 tons/year) gaseous and light liquid VOM, and whose
components are used to manufacture the synthetic organic
chemicals or polymers listed in Appendix A, shall comply with
this Subpart. The provisions of this Subpart are applicable to
components containing 10 percent or more by weight VON as
determined by ASTM method E—168, E-169 and E-260, incorporated by
reference in Section 219.112 of this Part. Those components that
are not process unit components are exempt from this Subpart. A
component shall be considered to be leaking if the VON is equal
to, or is greater than 10,000 ppmv as methane or hexane as
determined by USEPA Reference Method 21, as specified at 40 CFR
60, Appendix A, incorporated by reference in Section 219.112
~i
this Part, indication of liquids dripping, or indication by a
sensor that a seal or barrier fluid system has failed. The
provisions of this Subpart are not applicable if the equipment
components are used to produce heavy liquid chemicals only from
heavy liquid feed or raw materials.
(Source: Amended at
Ill. Reg.
______
, effective
__________
Section 219.422
Inspection Program Plan for Leaks
The owner or operator of a synthetic organic chemical or polymer
manufacturing plant subject to Section 219.421 of this Part shall
prepare an inspection program plan which contains, at a minimum:
a) An identification of all components and the period in
which each will be monitored pursuant to Section
219.423 of this Part.
b) The format for the monitoring log required by Section
219.425 of this Part.
c) A description of the monitoring equipment to be used
when complying with Section 219.423 of this Part, and
d) A description of the methods to be used to identify all
pipeline valves, pressure relief valves in gaseous
service, all leaking components, and components
exempted under Section 219.423-f4)-~jj.
g~.this Part such
that they are obvious and can be located by both plant
personnel performing monitoring and Agency personnel
performing inspections.
(Source: Amended at — Ill.
Req.
______,
effective
__________
Section 219.423
Inspection Program for Leaks
The owner or operator of a synthetic organic chemical or polymer
manufacturing plant subject to this
~subpart shall, for the
purposes of detecting leaks, conduct a component inspection
01
~0-O882

476
program using the test methods specified in Method 21, 40 CFR 60,
Appendix A (1986), incorporated by reference in Section 219.112
of this Part, consistent with the following provisions:
a) Test annually those components operated near extreme
temperature or pressure such that they would be unsafe
to routinely monitor and those components which would
require the elevation of monitoring personnel higher
than two meters above permanent worker access
structures or surfaces.
b) Test quarterly all other pressure relief valves in gas
service, pumps in light liquid service, valves in light
liquid service and in gas service, and compressors.
c)
If less than or equal to 2 percent of the valves in
light liquid service and in gas service tested pursuant
to subsection (b) of this Section are found ne~to leak
for five consecutive quarters, no leak tests shall be
required for three consecutive quarters. Thereafter,
leak tests shall resume for the next quarter. If that
test shows less than or equal to 2 percent of the
valves in light liquid service and in gas service are
leaking, then no tests are required for the next
three quarters. If more than 2 percent are leaking,
then tests are required for the next five quarters.
d) Observe visually all pump seals weekly.
e) Test immediately any pump seal from which liquids are
observed dripping.
f) Test any relief valve within 24 hours after it has
vented to the atmosphere.
g) Routine instrument monitoring of valves which are not
externally regulated, flanges, and equipment in heavy
liquid service, is not required. However, any valve
which is not externally regulated, flange or piece of
equipment in heavy liquid service that is found to be
leaking on the basis of sight, smell or sound shall be
repaired as soon as practicable but no later than
30 days after the leak is found.
h) Test immediately after repair any component that was
found leaking.
i) Within one hour of its detection, a weatherproof,
~eadily visible tag, in bright colors such as red or
yellow, bearing an identification
number and the date
on which the leak was detected must be affixed on the
leaking component and remain in place until the leaking
o
~O-0883

477
component is repaired.
j) The following components are exempt from the monitoring
requirements in this Section:
1) Any component that is in vacuum service, and
2) Any pressure relief valve that is connected to an
operating flare header or vapor recovery device.
(Source: Amended at — Ill. Req.
______,
effective
___________
Section 219.424
Repairing Leaks
All leaking components must be repaired and retested as soon as
practicable but no later than 15 days after the leak is found
unless the leaking component cannot be repaired until the process
unit is shut down. Records of repairing and retesting must be
maintained in accordance with Section 219.425 and 219.426 of this
Part.
(Source: Amended at
_____,
Ill. Req.
______,
effective
_______)
Section 219.425
Recordkeepinq for Leaks
a) The owner or operator of a synthetic organic chemical
or polymer manufacturing plant shall maintain a leaking
components monitoring log which shall contain, at a
minimum, the following information:
1) The name of the process unit where the component
is located;
2) The type of component (e.g., valve, seal);
3) The identification number of the component;
4) The date on which a leaking component is
discovered;
5) The date on which a leaking component is repaired;
6) The date and instrument reading of the recheck
procedure after a leaking component is repaired;
7) A record of the calibration of the
monitoring
instrument;
8) The identification number of leaking components
which cannot
be repaired until process unit
shutdown; and
OIL4.U-088’4

478
9) The total number of valves in light liquid service
and in gas service inspected; the total number and
the percentage of these valves found leaking
during the monitoring period.
b) Copies of the monitoring log shall be retained by the
owner or operator for a minimum of two years after the
date on which the record was made or the report was
prepared.
c) Copies of the monitoring log shall be made available to
the Agency~upon verbal or written request~prior to or
at the time of inspection pursuant to Section 4(d) of
the Environmental Protection Act (Act) (Ill. Rev. Stat.
19&9~, ch. 11l~,pars. 1001 et seq.) 1415 ILCS 5/1 et
seq. at any reasonable time.
(Source: Amended at
Ill. Req.
______,
effective
__________
Section 219.426
Report for Leaks
The owner or operator of a synthetic organic chemical or polymer
manufacturing plant subject to Section 219.421 through 219.430 g~
this Part shall:
a) Submit quarterly reports to the Agency on or before
March 31, June 30, September 30, and December 31 of
each year, listing all leaking components identified
pursuant to Section 219.423 of this Part but not
repaired within 15 days, all leaking components
awaiting process unit shutdown, the total number of
components inspected, the type of components inspected,
and the total number of components found leaking, the
total number of valves in light liquid service and in
gas service inspected and the number and percentage of
valves in light liquid service and in gas service found
leaking.
b) Submit a signed statement with the report attesting
that all monitoring and repairs were performed as
required under Section 219.421 through 219.427 of this
Part.
(Source: Amended at
Ill. Reg.
______,
effective
__________
Section 219.427
Alternative Program for Leaks
The Agency shall approve an alternative program of monitoring,
recordkeeping, or reporting to that prescribed in this Subpart
upon a demonstration by the owner or operator of such plant that
the alternative program will provide plantsource personnel and
Agency personnel with an equivalent ability to identify and
01
~O-0885

479
repair leaking components. Any alternative program can be
allowed when approved by the Agency and approved by the USEPA as
a SIP revision.
(Source: Amended at — Ill. Req.
______,
effective
__________
Section 219.428
Open-Ended Valves
a) Each open-ended valve shall be equipped with a cap,
blind flange, plug, or a second valve, except during
operations requiring fluid flow through the open-ended
valve.
b) Each open—ended valve equipped with a second valve
shall be operated in a manner such that the valve on
the process fluid end
is closed before the second valve
is closed.
c) Components which are open—ended valves and which serve
as a sampling connection shall be controlled such that
they comply with subsection (c) (1), (c) (2) or (c) (3)
below. This reguirement does not apply to in-situ
sampling systems
.
÷
1) A closed purge system or closed vent system shall
return purged process fluid to the process line
with no detectable volatile organic material
emissions to the atmosphere, or
2) A closed purge system or closed vent system shall
collect and recycle purged process fluid to the
process line with no detectable volatile organic
material emissions to the atmosphere, or
3) Purged process fluid shall be transported to a
control device that complies with the requirements
of Section 219.429 of this part. If a container
is used to transport purged process fluid to
the
control device, the container shall be a closed
container designed and used to reduce the VON
emissions vented from purged process fluid after
transfer to no detectable VOM emissions as
determined by USEPA Reference Method 21, as
specified in 40 CFR 60, Appendix A (1990 or 1991)
incorporated by reference in Section 219.112 of
this Part. For purposes of this Section, the
phrase “after transfer” shall refer to the time at
which the entire amount of purged process fluid
resulting from a flushing or cleaning of the
sample line enters the container, provided,
however, that purged process fluid may be
transferred from the initial container to another
01
~0-0886

480
closed container prior to disposal, e.g., to a
bulk waste storage container.
d) In-situ sampling systems are exempt from subsection
(c).
(Source: Amended at
_____,
Ill. Reg.
, effective
_______)
Section 219.429
Standards for Control Devices
Control devices used to comply with Section 219.428(c) of this
Part shall comply with the following:
a) If the control device is a vapor recovery system (for
example, condensers and adsorbers), it shall be
designed and operated to recover the volatile organic
material emissions vented to it with an efficiency of
95 percent or greater.
b) If the control device is an enclosed combustion device,
it shall be designed and operated to reduce the
volatile organic material emissions vented to it with
an efficiency of 95 percent or greater, or to provide a
minimum residence time of 0.75 seconds at a minimum
temperature of 816°C.
c) If the control device is a flare, it shall:
1) Be designed for and operated with no visible
emissions as determined by USEPA Reference Method
22, 40 CFR 60, Appendix A (1986), incorporated by
reference in Section 219.112 of this Part, except
for periods not to exceed a total of 5 minutes
during any 2 consecutive hours.
2) Be operated with a pilot flame present at all
times and shall be monitored with a thermocouple
or any other equivalent device to detect the
presence of the pilot flame.
3) Be steam—assisted, air—assisted, or nonassisted.
4) Be used only with the net heating value of the gas
being combusted being 11.2 NJ/scm (300 Btu/scf) or
greater if the flare is steam—assisted or air—
assisted; or with the net heating value of the gas
being combusted being 7.45 NJ/scm or greater if
the flare is nonassisted. The net heating value
of the gas being combusted shall be calculated
using the following equation:
01
~~.O-O887

481
n
Hr
=
K E C1H~
1=1
Where:
Hr
=
Net heating value of the sample in
MJ/scm; where the net enthalpy per
mole of offgas is based on
combustion at 25°Cand 760 mm Hg,
but the standard temperature for
determining the volume
corresponding to one mole is 20°C--i.
K
=
Constant,
1.740 x l0~ (1/ppm) (q-mole/scm) (MJ/Kcal)
where
standard temperature for (q-mole/scm) is
C1
=
Concentration of sample component
i, in ppm, as measured by USEPA
Reference Method 18, 40 CFR 60,
Appendix A (1986), and ASTM D
2504-83, both incorporated by
reference in Section 219.112 of
this Part~-i.
H1
=
Net heat of combustion of sample
component i, kcal/g mole. The
heats of combustion may be
determined using ASTN D 2382-83,
incorporated by reference in
Section 219.112 of this Part, if
published values are not available
or cannot be calculated.
5) Steam—assisted and nonassisted flares shall be
designed and operated with an exit velocity, as
determined by dividing the volumetric flowrate (in
units of standard temperature and pressure), as
determined by USEPA Reference Method 2 or 2A, 40
CFR 60, Appendix A (1986) incorporated by
reference in Section 219.112 of this Part, as
appropriate; by the unobstructed (free) cross
sectional area of the flare tip, less than 18
mfsec (60 ft/sec).
6) Air-assisted flares shall be designed and operated
0 i L~0.-Q888

482
with an exit velocity less than the maximum
permitted velocity, Vn~ax, as determined by the
following equation:
Vmax
8.706 + O.7O84(Hr)~
V~ax
Maximum permitted
velocity, m/sec--i.
8.706
Constant--i
0.7084
Constant--i.
Hr
The net heating value as
determined in subsection
(c)
(4) of this section.
If the control device is a closed container, it shall
be designed and operated to reduce the volatile organic
material emissions, vented from purged process fluid
after transfer, to no detectable volatile organic
material emissions as determined by UCEPA Reference
Method 21 as specified at 40 CFR—6O, Appendix A (1986),
incorporated by reference in Section 219.112. For
nf 1—hi P.r’i—~tion, the phr~i~~~
~iffr’-r
t-—~~,~f~kr”
s-hall rc~ to the time at which the cntL.
purged process fluid resulting from a flusning or
cleaning of the s-ample line enters the closed container
or containers including the final container(s) prior to
disposal. The following information pertaining to
closed vent systems and control devices sublect to
Section 219.429 shall be maintained by the owner or
operator. These records shall be updated as necessary
to describe current operation and equipment. The
records shall be retained as a readily accessible
location at the source for a minimum of two years after
the control device is permanently shutdown.
~j. Detailed schematics, design specifications~ and
piping and instrumentation diagrams
~j The dates and description of any changes in design
specifications
~j A description of the parameter or parameters
monitored and recorded as required in subsection
(f) (1) to ensure that the control devices are
operated and maintained in conformance with their
design and an explanation why that parameter (or
parameters) was selected for monitoring.
e-)- The owner or operator of a control device s-hall monitor
the control device to ensure that it is operated and
maintained in conformance with the manufacturer’-s
0
~o-0889
‘~mr~iirtt r~f
d)

483
specifications, modified to th
design.
#e) The control device shall be operated at all times when
emissions may be vented to it.
~j Owners and oPerators of control devices used to comply
with this Subpart shall monitor each control device to
ensure that the control device is operated and
maintained in conformance with its designs at all times
that emissions may be vented to it. This monitoring
shall be conducted in accordance with Section
219.429(d)(3). The records prepared as Part of this
monitoring activity shall include the dates of startup
and shutdown of control devices and identify periods
when the devices are not operated as designed,
including periods when a flare pilot light does not
have a flame.
gj The reguirements of subsections (d), (e) and (f) shall
not apply to a combustion device used for disposal of
~ur~ed process fluid which is sublect to the BIF rules,
located at the source or which is subiect to the RCRA
rules. The owner or operator of such combustion device
shall satisfy applicable provisions of the RCRA or BIF
rules.
(Source:
Amended at
Ill. Req.
______,
effective
__________
Section 219.430
Compliance Date (RePealed)
The owner or operator of a synthetic organic chemical or polymer
manufacturing plant subject to 35 Ill. Adm. Code 215.430 through
215.438 as- of December 31, 1987 s-hall have complied with the
standards and limitations of those Sections no later than
December 31, 1987.
(Source: Repealed at
Ill. Req
effective
_________)
SUBPART R: PETROLEUM REFINING AND RELATED INDUSTRIES;
ASPHALT MATERIALS
Section 219.441
Petroleum Refinery Waste Gas Disposal
a) Except as provided in subsection (b) or (c) of this
Section, no person shall cause or allow the discharge
of organic materials in excess of 100 ppm equivalent
methane (molecular weight 16.0) into the atmosphere
from:
1) Any catalyst regenerator of a petroleum cracking
system; or
01 i.0-089O

484
2)
Any petroleum fluid coker; or
3) Any other waste gas stream from any petroleum or
petrochemical manufacturing process.
b) Exception. Existing sources subject to subsection
(a) (3) of this Section may, alternatively,
at their
election, comply with the organic material emission
limitations imposed by 35 Ill. Adm. Code 21~.301 or
21~.302; provided, however, that there shall be no
increase in emissions from such sources above the level
of emissions in existence on May 3, 1979.
c)
New Sources. Sources subject to subsection (a) (3) ~
this Section, construction of which commenced on or
after January 1, 1977, may, at their election, comply
with the following emission limitations:
1) A maximum of eight pounds per hour of organic
material; or
2) Emission of organic material in excess of the
limitation of subsection (c) (1) of this Section is
allowable if such emissions are controlled by air
pollution control methods or equipment approved by
the Agency capable of reducing by 85 percent or
more the uncontrolled organic material that would
otherwise be emitted to the atmosphere. Such
methods or equipment must be approved by the
Agency and approved by the USEPA as a SIP
revision.
(Source: Amended at
Ill. Req.
______,
effective
__________
Section 219.443
Wastewater (Oil/Water) Separator
No owner or operator of a petroleum refinery shall operate any
wastewater (oil/water) separator at a petroleum refinery unless
the separator is equipped with air pollution control equipment
capable of reducing by 85 percent or more the uncontrolled
organic material emitted to the atmosphere. If no odor nuisance
exists, the limitation of this Section shall not apply if the
vapor pressure of the organic material is below 10.34 kPa (1.5
psia) at 2~4.3°K(70°F) at all times.
(Source: Amended at — Ill. Req.
______,
effective
__________
Section 219.445
Leaks: General Requirements
a-~-The owner or operator of a petroleum refinery shall:
~)
Develop a monitoring program plan consistent with the
o i
~o-089

485
provisions of Section 219.446 of this Part
a-b) Conduct a monitoring program consistent with the
provisions of Section 219.447 of this Part
3ç) Record all leaking components which have a volatile
organic material concentration exceeding 10,000 ppm
consistent with the provisions of Section 219.448 ~
this Part
4d) Identify each component consistent with the monitoring
program plan submitted pursuant to Section 219.446
~i
this Part
~)
Repair and retest the leaking components as soon as
possible within 22 days after the leak is found, but no
later than June 1 for the purposes of Section
219.447 (a) (1) of this Part, unless the leaking
components cannot be repaired until the unit is shut
down for turnaround; and
6~) Report to the Agency consistent with the provisions of
Section 219.449 of this Part.
(Source: Amended at — Ill. Reg.
______,
effective
__________
Section 219.446
Monitoring Program Plan for Leaks
The owner or operator of a petroleum refinery shall prepare a
monitoring program plan which contains, at a minimum:
a) An identification of all refinery components and the
period in which each will be monitored pursuant to
Section 219.447 of this Part
b) The format for the monitoring log required by Section
219.448 of this Part
c) A description of the monitoring equipment to be used
pursuant to Section 219.447 of this Part and
d) A description of the methods to be used to identify all
pipeline valves, pressure relief valves in gaseous
service and all leaking components such that they are
obvious to both refinery personnel performing
monitoring and Agency personnel performing inspections.
(Source: Amended at
_____,
Ill.
Req.
______,
effective
_______)
Section 219.447
Monitoring Program for Leaks
a) The owner or operator of a petroleum refinery subject
01
~O-0892

486
to Section 219.445 of this Part shall, for the purpose
of detecting leaks, conduct a component monitoring
program consistent with the following provisions:
1) Test once between March 1 and June 1 of each year,
by methods referenced in Section 219.105(g)
Q~
this Part, all pump seals, pipeline valves in
liquid service and process drains--i.
2) Test once each quarter of each calendar year, by
methods referenced in Section 219.105(g) of this
Part, all pressure relief valves in gaseous
service, pipeline valves in gaseous service and
compressor sea1s--~
3) Inaccessible valves may be tested once each
calendar year instead of once each quarter of each
calendar year--i
4)
Observe visually all pump seals weekly--i
5) Test immediately any pump seal from which liquids
are observed dripping,-i.
6) Test any relief valve within 24 hours after it has
vented to the atmosphere,-~and
7) Test immediately after repair any component that
was found leaking.
b) Storage tank valves and pressure relief devices
connected to
an operating flare header or vapor
recovery device are exempt from the monitoring
requirements in subsection (a) of this Section.
c) The Agency may require more frequent monitoring than
would otherwise be required by subsection (a) of this
Section for components which are demonstrated to have a
history of leaking.
(Source: Amended at — Ill. Reg.
______,
effective
___________
Section 219.449
Reporting for Leaks
The owner or operator of a petroleum refinery shall:
a) Submit a report to the Agency prior to the 1st day of
both July and September listing all leaking components
identified pursuant to Section 219.447 of this Part but
not repaired within 22 days, all leaking components
awaiting unit turnaround, the total number of
components inspected and the total number of components
01 ~0-0893

487
found leaking;
b) Submit a signed statement with the report attesting
that all monitoring and repairs were performed as
required under Sections 219.445 through 219.448 of this
Part.
(Source: Amended at
Ill. Reg.
______,
effective
__________
Section 219.450
Alternative Program for Leaks
The Agency may approve an alternative program of monitoring,
recordkeeping or reporting to that prescribed in Sections 219.446
through 219.449 of this Part upon a demonstration by the owner or
operator of a petroleum refinery that the alternative program
will provide refinery, Agency and USEPA personnel with an
equivalent ability to identify and repair leaking components.
Any alternative program can be allowed only if approved by the
USEPA as a SIP revision.
(Source: Amended at
Ill. Req.
______,
effective
___________)
Section 219.452
Compliance Schedule for Leaks
The owner or operator of a petroleum refinery shall adhere to the
increments of progress contained in the following schedule:
a) Submit to the Agency a monitoring program consistent
with Section 219.446 of this Part prior to July 1, 1991
or a date consistent with Section 219.106 of this Part.
b) Submit to the Agency the first monitoring report
pursuant to Section 219.449 of this Part prior to
August 1, 1991 or a date consistent with Section
219.106 of this Part.
(Source: Amended at — Ill. Req.
______,
effective
__________
Section 218.453
Compliance Dates (Repealed)
Every owner or operator of a petroleum refinery subject to 35
fl1. Adin. Code 215, Subpart R as- of December 31, 1987 s-hall have
complied with its standards and limitations by December 31, 1987.
(Source:
Repealed at
Ill.
Req.
______,
effective
________)
SUBPART S: RUBBER AND MISCELLANEOUS PLASTIC PRODUCTS
Section 219.461
Manufacture of Pneumatic Rubber Tires
The owner or operator of an undertread cementing, treadend
cementing or bead dipping operation at a pneumatic rubber tire
a i~0-089Li.

488
manufacturing facilitysource shall install and operate:
a) A capture system, with minimum capture efficiency of 65
percent by weight of VON for treadend cementing or bead
dipping operations and a capture system with a minimum
capture efficiency of 55.5 percent by weight of VON for
undertread cementing; and
b) A control device that meets the requirements of one of
the following:
1) A carbon adsorption system designed and operated
in a manner such that there is at least a 90
percent removal of VON by weight from the gases
ducted to the control device;
2) An afterburning system that oxidizes at least 90
percent of the captured nonmethane VON (VON
measured as total combustible carbon) to carbon
dioxide and water; and
3) An alternative VOM emission reduction system
demonstrated to have at least a 90 percent overall
reduction efficiency and approved by the Agency
and approved by the USEPA.
(Source: Amended at — Ill. Reg.
______,
effective
__________
Section 219.462
Green Tire Spraying Operations
The owner or operator of a green tire spraying operation at a
pneumatic rubber tire manufacturing facilitysource shall:
a)
Install and operate:
1) A capture system with a minimum capture efficiency
of 90 percent by weight of VON; and
2) A control device that meets the requirements of
one of the following:
A) A carbon adsorption system designed and
operated in a manner such that there is at
least 90 percent removal of VOM by weight
from the bases-gases ducted to the control
device;
B) An afterburning system that oxidizes at least
90 percent of the captured nonmethane VON
(measured as total combustible carbon) to
carbon dioxide and water; or
0 ~L’~u-u

489
C) An alternative VON emission reduction system
demonstrated to have at least a 90 percent
overall reduction efficiency approved by the
Agency and approved by the USEPA as a SIP
revision.
b) Substitute for the normal solvent—based mold release
compound water—based sprays containing:
1) No more than five percent by volume of VON as
applied for the inside of tires;
2) No more than ten percent by volume of VOM as
applied for the outside of tires.
(Source: Amended at — Ill. Req.
______,
effective
__________)
Section 219.463
Alternative Emission Reduction Systems
In lieu of complying with Section 219.461 or 219.462 of this
Part, the owner or operator of an emission source may utilize an
alternative volatile organic emission reduction system, including
an alternative production process, which is demonstrated to be
equivalent to Section 219.461 or 219.462 of this Part on the
basis of emissions of volatile organic matter materia~i. A
treadend cementing operation shall be considered equivalent to
Section 219.461 or 219.462 of this Part for the purposes of this
Section if the total volatile organic emission from such
operation is 10 grams or less per tire.
(Source: Amended at
Ill. Req.
_____,
effective
__________)
Section 219.464
Testing and MonitoringEmission Testing
a) Upon a reasonable request by the Agency, the owner or
operator of a VON emission source required to comply
with a limit of Sections 219.461 through 219.464 ~
this Part shall conduct emissions testing, at such
person’s own expense, to demonstrate compliance.
b) A person planning to conduct a VON emission test to
demonstrate compliance shall notify the Agency of that
intent not less than 30 days before the planned
initiation of the tests so the Agency may observe the
test.
(Source: Amended at — Ill. Reg.
______,
effective
___________)
Section 218’.465
Compliance Dates (Repealed)
Every owner or operator of an emission source subject to 35 Ill.
Adm. Code 215, Subpart C, as of December 31, 1987 s-hall have
U ~O-O896

490
complied with its standards and limitations by December 31, 1987.
(Source: Repealed at — Ill. Reg.
______,
effective
__________)
Section 219.466
Compliance Plan (Repealed)
a-)- The owner or operator of an emission source shall have
submitted to the Agency a compliance plan, pursuant to
35 Ill. Adm. Code 201, Subpart H, including a project
completion schedule where applicable, no later than
April 21, 1983.
.b-)- Unless the submitted compliance plan or schedule was
disapproved by the Agency, the owner or operator of a
faci1i~v or emission source may operate the emission
source according to the plan and schedule as- cuDmittcu-.
e-)- The plan and schedule shall meet the requirements of 35
Ill. Adm. Code 201, Subpart H, including specific
~cs as required in 35 Ill. Adm. Code 201.242.
(Source: Repealed at
Ill. Reg.
______,
effective
__________)
SUBPART T: PHARMACEUTICAL MANUFACTURING
Section 219.480
Applicability
a) The rules of this Subpart, except for Sections 219.483
through 219.485, apply to all emission sources-units of
VON, including but not limited to reactors,
distillation units, dryers, storage tanks for VOL,
equipment for the transfer of VOL, filters,
crystallizers, washers, laboratory hoods,
pharmaceutical coating operations, mixing operations
and centrifuges used in manufacturing, including
packaging, of pharmaceuticals, and emitting more than
6.8 kg/day (15 lbs/day) and more than 2,268 kg/year
(2.5 tons/year) of VON. If suchai~emission sourcep~p~t
emits less than 2,268 kg/year (2.5 tons/year) of VON,
the requirements of this Subpart still apply to the
emission sourceunit if VOM emissions from the emission
s-eurceunit exceed 45.4 kg/day (100 lbs/day).
b-)- Notwithstanding subsection (a), the air suspension
coater/drycr,
fluid bed dryers, tunnel dryers, and
Accelacotas
located in Libertyville Township, Lake
County, Illinois shall be exempt from the rules of this
Subpart, except for Sections 219.483 through 219.485,
if emissions of VON not vented to air pollution control
equipment do not exceed the following levels:
suspension coaLer/aLycr: 2,268 kg/year
01 ~0-0897

491
(2.5 tons/year);
ior
c~.unriuia i~ca
(5.0 tons/year)
.3-)- for each tunnel dryer: 6,803 kg/year (7.5
tons/year); and
4-)- for each Accelacota: 6,803 kg/year
(7.5 tons/year).
e-)-~j Sections 219.483 through 219.485 of this Part apply to
a plantsource having one or more emission sources-units
that:
1) Are used to manufacture pharmaceuticals, and
2) Emit more than 6.8 kg/day (15 lbs/day) of VON and
more than 2,268 kg/year (2.5 tons/year) of VOM,
or, if less than 2,268 kg/year (2.5 tons/year),
these Sections still apply if emissions from one
or more sources exceed 45.4 kg/day (100 lbs/day).
4-)-gj No owner or operator shall violate any condition in a
permit when the condition results in exclusion of an
emission sourceunit from this Subpart.
e-)-~J. Any pharmaceutical manufacturing source that becomes
subject to the provisions of this Subpart at any time
shall remain subject to the provisions of this Subpart
at all times.
~~-)-~I.
Emissions subject to this Subpart shall be controlled
at all times consistent with the requirements set forth
in this Subpart.
~-)-fl
Any control device required pursuant to this Subpart
shall be operated at all times when the source it is
controlling is operated.
~-)-gjDeterminations of daily and annual emissions for
purposes of this Section shall be made using both data
on the hourly emission rate (or the emissions per unit
of throughput) and appropriate daily and annual data
from records of emission sourceunit operation (or
material throughput or material consumption data). In
the absence of representative test data pursuant to
Section 219.487 of this Part for the hourly emission
rate (or the emissions per unit of throughput), such
items shall be calculated using engineering
calculations,
including the methods described in
Appendix B of “Control of Volatile Organic Emissions
01 1~.0-0898

492
from Manufacturing of Synthesized Pharmaceutical
Products” (EPA-450/2-78-029), incorporated by reference
in Section 219.112 of this Part. (This subsection
shall not affect the Agency’s or the USEPA’s authority
to require emission tests to be performed pursuant to
Section 219.487 of this Part.)
(Source: Amended at — Ill. Req.
______,
effective
___________
Section 219.481
Control of Reactors, Distillation Units,
Crystallizers, Centrifuges and Vacuum Dryers
a) The owner or operator shall equip all reactors,
distillation units, crystallizers, centrifuges and
vacuum dryers that are used to manufacture
pharmaceuticals with surface condensers or other air
pollution control equipment listed in subsection (b) g~
this Section. If a surface condenser is used, it shall
be operated such that the condenser outlet gas
temperature does not exceed:
1) 248.2°K (-13°F) when condensing VOM of vapor
pressure greater than 40.0 kPa (5.8 psi) at
294.3°K (70°F), or
2) 258.2°K (5°F) when condensing VON of vapor
pressure greater than 20.0 kPa (2.9 psi) at
294.3°K (70°F), or
3) 273.2°K (32°F) when condensing VOM of vapor
pressure greater than 10.0 kPa (1.5 psi) at
294.3°K (70°F), or
4) 283.2°K (50°F) when condensing VOM of vapor
pressure greater than 7.0 kPa (1.0 psi) at 294.3°K
(70°F), or
5) 298.2°K (77°F) when condensing VOM of vapor
pressure greater than 3.45 kPa (0.5 psi) at
294.3°K (70°F).
b) If a scrubber, carbon adsorber, thermal afterburner,
catalytic afterburner, or other air pollution control
equipment other than a surface condenser is used, such
equipment shall provide a reduction in the emissions of
VON of 90 percent or more.
c) The owner or operator shall enclose all centrifuges
used to manufacture pharmaceuticals and that have an
exposed VOL surface, where the VON in the VOL has a
vapor pressure of 3.45 kPa (0.5 psi) or more at 294.3°K
(70°F), except as production, sampling, maintenance, or
U! ~O-O899

493
inspection procedures require operator access.
(Source: Amended at
_____,
Ill. Req.
______,
effective
_______)
Section 219.482
Control of Air Dryers, Production Equipment
Exhaust Systems and Filters
a) The owner or operator of an air dryer or production
equipment exhaust system used to manufacture
pharmaceuticals shall control the emissions of VON from
such emission s-ourcesunits by air pollution control
equipment which reduces by 90 percent or more the VON
that would otherwise be emitted into the atmosphere.
b) The owner or operator shall enclose all rotary vacuum
filters and other filters used to manufacture
pharmaceuticals and that have an exposed VOL surface,
where the VON in the VOL has a vapor pressure of 3.45
kPa (0.5 psi) or more at 294~°K(70°F), except as
production, sampling, maintenance, or inspection
procedures require operator access.
(Source: Amended at
Ill. Req.
______,
effective
___________)
Section 219.483
Material Storage and Transfer
The owner or operator of a pharmaceutical manufacturing
plantsource shall:
a) Provide a vapor balance system that is at least
90 percent effective in reducing VOM emissions from
truck or railcar deliveries to storage tanks with
capacities equal to or greater than 7.57 m3 (2,000 gal)
that store VOL with vapor pressures greater than
28.0 kPa (4.1 psi) at 294.3°K (70°F), and
b) Install, operate, and maintain pressure/vacuum
conservation vents set at 0.2 kPa (0.03 psi) or greater
on all storage tanks that store VOL with vapor
pressures greater than 10 kPa (1.5 psi) at 294.3°K
(70°F)
(Source:
Amended at
Ill.
Reg.
______,
effective
__________
Section 219.485
Leaks
The owner or operator of a pharmaceutical manufacturing
plantsource shall repair any component from which a leak of VOL
can be obse~rved. The repair shall be completed as soon as
practicable but no later than 15 days after the leak is found.
If the leaking component cannot be repaired until the process
unit is shut down, the leaking component must then be repaired
01
~O-O9OO

494
before the unit is restarted.
(Source: Amended at
Ill. Req.
______,
effective
Section 219.486
Other Emission Sources Units
The owner or operator of a washer, laboratory hood, tablet
coating operation, mixing operation or any other process emission
sour-ceunit not subject to Sections 219.481 through 219.485 ~
this Part, and used to manufacture pharmaceuticals shall control
the emissions of VON from such emission sourcesunits by:
a) Air pollution control equipment which reduces by
81 percent or more the VON that would otherwise be
emitted to the atmosphere, or
b) A surface condenser which captures all the VOM which
would otherwise be emitted to the atmosphere and which
meets the requirements of Section 219.481(a) of this
Part and (b).
(Source: Amended at
Ill. Reg.
______,
effective
___________
Section 219.487
Testing
a) Upon request by the Agency or the USEPA, the owner or
operator of any VON emission source subject to this
Subpart or exempt from this Subpart by virtue of the
provisions
of Section 219.480 of this Part shall, at
his own expense, demonstrate compliance to the Agency
and the USEPA by the methods or procedures listed in
Section 219.105(f) (1) of this Part.
b) A person planning to conduct a VOM emissions test to
demonstrate compliance with this Subpart shall notify
the Agency and the USEPA of that intent not less than
30 calendar days before the planned initiation of the
test.
(Source: Amended at
_____,
Ill. Req.
______,
effective
_______)
Section 219.489
Recordkeeping f or Air Pollution Control
Equipment
a) The owner or operator of a pharmaceutical manufacturing
facilitysource shall maintain the following records:
1) Parameters listed in Section 219.488(a) of this
Part
-E~-~-
shall be recorded.
2) For sourcesemission units subject to Section
o i
~o-o9OI

495
219.481 of this Part, the vapor pressure of VON
being controlled shall be recorded for every
process.
b) For any leak subject to Section 219.485 of this Part
which cannot be readily repaired within one hour after
detection, the following records shall be kept:
1) The name of the leaking equipment,
2)
The date and time the leak is detected,
3) The action taken to repair the leak, and
4) The datae and time the leak is repaired.
c) The following records shall be kept for emission
sources-units subject to Section 219.484 of this Part
which contain VOL:
1) For maintenance and inspection:
A) The date and time each cover is opened,
B) The length of time the cover remains open,
and
C) The reason why the cover is opened.
2) For production and sampling, detailed written
procedures or manufacturing directions specifying
the circumstances under which covers may be opened
and the procedures for opening covers.
d) For each emission sourceunit used in the manufacture of
pharmaceuticals for which the owner or operator of a
pharmaceutical manufacturing plantsource claims
emission standards are not applicable, because the
emissions are below the applicability cutoffs in
Section 219.480(a) or 219.480(b) of this Part, the
owner or operator shall:
1) Maintain a demonstration including detailed
engineering calculations of the maximum daily and
annual emissions for each such emission source
unit showing that the emissions are below the
applicability cutoffs in Section 219.480(a) or
219.480(b) of this Part, as appropriate, for the
current and prior calendar years;
2) Maintain appropriate operating records for each
such emission source to identify whether the
0 i~~-09O2

496
applicability cutoffs in Section 219.480(a) or
219.480(b) of this Part, as appropriate, are ever
exceeded; and
3) Provide written notification to the Agency and the
USEPA within 30 days of a determination that such
an emission sourceunit has exceeded the
applicability cutoffs in Section 219.480(a) or
219.480(b) of this Part, as appropriate.
e) Records required under subsection (a) of this Section
shall be maintained by the owner or operator for a
minimum of two years after the date on which they are
made.
f) Copies of the records shall be made available to the
Agency or the USEPA upon verbal or written request.
(Source: Amended at — Ill. Reg.
______,
effective
_________
SUBPART V: AIR OXIDATION PROCESSES
Section 219.521
Definitions (Repealed)
In additi~
following
of 35 Ill. Adm
ons apply to this Subpart:
“Air Oxidation Process”: any unit process includin
ammoxidation and oxychlorination which uses air or
g
a
combination of air and oxygen as an oxidant in
combination with one or more organic reactants to
produce one or more organic compounds.
“Cost Effectiveness”: the annual expense for cost
of
contro±
I
yivell piuue~
stream divided by the reaucti~
in emissions of organic material of that stream.
“Flow (F)”: Vent stream flowratc (scm/mm) at a
standard temperature of 20°C.
“Full Operating Flowratc”: Maximum operating capacity
of the facility.
“Hourly Emissions (Er’: Hourly emissions reported in
kg/hr measured at full operating flowratc.
“Net Heating Value (H)”: Vent stream net heating value
(NJ/scm), where the net cntha.lpy per mole of offgas is
based on combustion at 25°Cand 760 mm Hg, but the
standard temperature for determining the volume
r~~ir~rc
~
~‘.‘‘‘~‘
.i’-~
~‘fl°C,
~
ir, 1-h-’
ir,iticrn
of “Flow.
‘I
a1L~O
-0903
~1c 211, th

497
“Process Vent Stream”: An emission stream resulting
from an air oxidation process-.
“Total Resource Effectiveness Index (TRE)”: Cost
effectiveness in dollars per megagram of controlling
any gaseous stream vented to the atmosphere from an air
oxidation process divided by $1600/Mg, using the
eritsri~ ~ ~sthods- s-ct
fr~h ir, 1hi~ ~iihr~rf
~,r1
Appendices C and D.
(Source: Repealed at
Section 219.525
Ill. Req.
______,
effective
__________
Emission Limitations for Air Oxidation
Processes
a) No person shall cause or allow the emission of volatile
organic material (VOM) from any process vent stream
unless the process vent stream is vented to a
combustion device which is designed and operated
either:
1) To reduce the volatile organic emissions vented to
it with an efficiency of at least ninety eight
percent (98) by weight; or
2) To emit VON at a concentration less than twenty
parts per million by volume, dry basis.
b)
AnAair oxidation facilitiesprccess
vent stream for
which an existing combustion device is employed to
control process VON emissions a~ej~not required to
meet the 98 percent emissions limit until the
combustion device is replaced for other reasons, which
shall be considered to include, but not be limited to,
normal maintenance, malfunction, accident, and
obsolescence. The combustion device is considered to
be replaced when:
1) All of the device is replaced; or
2)
When the cost of the repair of the device or the
cost of replacement of part of the device exceeds
50 of the cost of replacing the entire device
with a device which complies.
c) The limitations of subsection (a) above do not apply to
any process vent stream or combination of process vent
streams which has a Total Resource Effectiveness Index
(TRE) greater than 1.0, as determined by the following
methods:
1)
If an air oxidation process has more than one
01140-09014

498
process vent stream, TRE shall be based upon a
combination of the process vent streams.
2)
TRE of a process vent stream shall be determined
according to the following equation:
TRE
=
E1 a + bF~+ cF + dFH + e(FH)~ +
where:fF0~5
n
=
0.881
TRE
=
Total resource effectiveness
index--i
F
=
Vent stream flowrate (scm/mm), at
a standard temperature of 20°C--1
E
=
Hourly measured emissions in
kg/hr--i
H
=
Net heating value of vent stream
(MJ/scm), where the net enthalpy
per mole of offgas is based on
combustion at 25°Cand 760 mm Hg,
but the standard temperature for
determining the volume
corresponding to one mole is 20°C,
as in the definition of “Flow”--l
a,b, c,
d,e
and f
Coefficients obtained by use
of Appendix
~p.
3) For nonchiorinated process vent streams, if the
net heating value, H, is greater than 3.6 NJ/scm,
F shall be replaced by ~ or purposes of
calculating TRE. ~ is computed as follows:
=
FH
/
3.6
where F and H are as defined in subsection (c) (2).
4) The actual numerical values used in the equation
described in subsection (c) (2) above shall be
determined as follows:
A) All reference methods and procedures for
determining the flow, (F), hourly emissions,
(E), and net heating, (H), value shall be in
accordance with Appendix C.
U i.~.O-09O5

499
B) All coefficients described in subsection
(c) (2) of this Section shall be in accordance
with Appendix D.
(Source: Amended at
Ill. Req.
______,
effective
__________
Section 219.527
Compliance Date (Repealed)
Each owner or operator of an emission source subject to 35 Ill.
Adm. Code 215, Subpart V, as of December 31, 1987 shall have
complied with the standards and limitations of 35 Ill. Adm. Code
215, Subpart V, by December 31, 1987.
(Source: Repealed at
Ill. Reg.
, effective
__________)
SUBPART W: AGRICULTURE
Section 219.541
Pesticide Exception
The provisions of Sections 219.301 and 219.302 of this Part shall
not apply to the spraying or use of insecticides, herbicides or
other pesticides.
(Source: Amended at — Ill. Req.
______,
effective
__________
SUBPART X: CONSTRUCTION
Section 219.562
Paving Operations
The provisions of Sections 219.301 and 219.302 of this Part shall
not apply to the application of paving asphalt and pavement
marking paint from sunrise to sunset.
(Source: Amended at — Ill. Req.
______,
effective
___________)
SUBPART 1: GASOLINE DISTRIBUTION
Section 219.581
Bulk Gasoline Plants
a) Subject to &subsection (e) of this Section, no person
may cause or allow the transfer of gasoline from a
delivery vessel into a stationary storage tank located
at a bulk gasoline plant unless÷1
1) The delivery vessel and the stationary
storage tank are each equipped with a vapor
collection system that meets the requirements of
subsection (d) (4) of this SectionTl
2)
Each vapor collection system is operating~~
3)
The delivery vessel displays the appropriate
Ui1~O-
0906

500
sticker pursuant to the requirements of Sections
219.584 (b) or (d) of this PartTl
4) The pressure relief valve(s) on the stationary
storage tank and the delivery vessel are set to
release at no less than 0.7 psi or the highest
pressure allowed by state or local fire codes or
the guidelines of the National Fire Prevention
AssociationTl and
5) The stationary storage tank is equipped with a
submerged loading pipe.
b) Subject to subsection (f) of this Section, no person
may cause or allow the transfer of gasoline from a
stationary storage tank located at a bulk gasoline
plant into a delivery vessel unless:
1) The requirements set forth in subsections (a) (1)
through (a) (4) of this Section are metTl and
2)
Equipment is available at the bulk gasoline plant
to provide for the submerged filling of the
delivery vessel or the delivery vessel is equipped
for bottom loading.
c) Subject to subsection (e) of this Section, each owner
of a stationary storage tank located at a bulk gasoline
plant shall:
1) Equip each stationary storage tank with a vapor
control system that meets the requirements of
subsection (a) or (b) of this Section, whichever
is applicableTl
2) Provide instructions to the operator of the bulk
gasoline plant describing necessary maintenance
operations and procedures for prompt notification
of the owner in case of any malfunction of a vapor
control system,1 and
3) Repair, replace or modify any worn out or
malfunctioning component or element of design.
d) Subject to subsection (e) of this Section, each
operator of a bulk gasoline plant shall:
1) Maintain and operate each vapor control system in
accordance with the owner’s instructionsTl
2) Promptly notify the owner of any scheduled
maintenance or malfunction requiring replacement
a 140-0907

501
or repair of a major component of a vapor control
system~~and
3) Maintain gauges, meters or other specified testing
devices in proper working orderTl
4) Operate the bulk plant vapor collection system and
gasoline loading equipment in a manner that
prevents:
A) Gauge pressure from exceeding 45.7 cm (18
in.) of water and vacuum from exceeding 15.2
cm (6 in.) of water, as measured as close as
possible to the vapor hose connectionTl and
B) A reading equal to or greater than 100
percent of the lower explosive limit (LEL
measured as propane) when tested in
accordance with the procedure described in
“Control of Volatile Organic Compound Leaks
from Gasoline Tank Trucks and Vapor
Collection Systems”, Appendix B, EPA 450/
2-78-051, (incorporated by reference in
Section 219.112 of this Part)T1 and
C) Avoidable leaks of liquid during loading or
unloading operations.
5) Provide a pressure tap or equivalent on the bulk
plant vapor collection system in order to allow
the determination of compliance with subsection
(d) (4) (A) of this Section-rI and
6) Within 15 business days after discovery of any
leak by the owner, the operator, the Agency or the
USEPA, repair and retest a vapor collection system
which exceeds the limits of subsection (d) (4) (A)
or (B) of this Section.
e) The requirements of subsections (a), (c) and (d) ~
this Section shall not apply to:
1)
Any stationary storage tank with a capacity of
less than 2,177 1 (575 gal)-~-~or
2) Any bulk gasoline plant whose daily gasoline
throughput is less than 15,140 1 (4,000 gal/day)
on a thirty-day rolling average.
f) The requirements of subsection (b) shall apply only to
bulk gasoline plants whose daily gasoline throughput is
greater than or equal to 15,140 1 (4,000 gal/day) on a
U ;0—0908

502
thirty-day rolling average.
q) Any bulk gasoline plant which is ever subject to
subsections (a), (b), (c), or (d) of this Section shall
always be subject to these paragraphs.
(Source: Amended at — Ill. Req.
______,
effective
___________
Section 219.582
Bulk Gasoline Terminals
a)
No
person shall cause or allow the transfer of gasoline
into any delivery vessel from any bulk gasoline
terminal unless:
1) The bulk gasoline terminal is equipped with a
vapor control system that limits emission of VON
to 80 mq/l (0.00067 lbs/gal) of gasoline loaded;
2) The vapor control system is operating and all
vapors displaced in the loading of gasoline to the
delivery vessel are vented only to the vapor
control system;
3) There is no liquid drainage from the loading
device when it is not in use;
4) All loading and vapor return lines are equipped
with fittings which are vapor tight; and
5) The delivery vessel displays the appropriate
sticker pursuant to the requirements of Section
219.584(b) or (d) of this Part or, if the
terminal is driver-loaded, the terminal owner or
operator shall be deemed to be in compliance with
this Section when terminal access authorization
is
limited to those owners and/or operators of
delivery vessels who have provided a current
certification as required by Section 219.584(c) (3)
of this Part.
Bulk gasoline terminals were required to take certain
actions to achieve compliance which are
215, Appendix C.
summarized in
35 Ill. 1~.dm. Code
e~) The operator of a bulk gasoline terminal shall:
1) Operate the terminal vapor collection system and
gasoline loading equipment in a manner that
prevents:
A) Gauge pressure from exceeding 18 inches of
water and vacuum from exceeding 6 inches of
01 140U909

503
water as measured as close as possible to the
vapor hose connection; and
B) A reading equal to or greater than 100
percent of the lower explosive limit (LEL
measured as propane) when tested in
accordance with the procedure described in
EPA 450/2-78-051 Appendix B~incorporated by
reference in Section 219.112 of this Part
and
C) Avoidable leaks of liquid during loading or
unloading operations.
2) Provide a pressure tap or equivalent on the
terminal vapor collection system in order to allow
the determination of compliance with Section
219.582(d) (1) (A) of this Part and
3) Within 15 business days after discovery of the
leak by the owner, operator, or the Agency repair
and retest a vapor collection system which exceeds
the limits of subsection (c) (1) (A) or (B) of this
Section.
(Source:
Amended at
Ill. Req.
______,
effective
___________)
Section 219.583
Gasoline Dispensing Facilitiesqperations
a) Subject to subsection (b) of this Section, no person
shall cause or allow the transfer of gasoline from any
delivery vessel into any stationary storage tank at a
gasoline dispensing facilityoperation unless:
1) The tank is equipped with a submerged loading
pipe; and
2) The vapors displaced from the storage tank during
filling are processed by a vapor control system
that includes one or more of the following:
A) A vapor collection system that meets the
requirements of subsection (d) (4) of this
Section or
B) A refrigeration—condensation system or any
other system approved by the Agency and
approved by the USEPA as a SIP revision, that
recovers at least 90 percent by weight of all
vaporized organic material from the equipment
being controlled; and
01140-0910

504
C) The delivery vessel displays the appropriate
sticker pursuant to the requirements of
Section 219.584(b) or (d) of this Part.
b) The requirements of subsection (a) (2) above shall not
apply to transfers of gasoline to a stationary storage
tank at a gasoline dispensing facilityoperation if:
1) The tank is equipped with a floating roof, or
other system of equal or better emission control
as approved by the Agency and approved by the
USEPA as a SIP revision;
2) The tank has a capacity of less than 2000 gallons
and was in place and operating before January 1,
1979; or
3) The tank has a capacity of less than 575 gallons.
c) Subject to subsection (b) above, each owner of a
gasoline dispensing facilityoperation shall:
1) Install all control systems and make all process
modifications required by subsection (a) of this
Section
2) Provide instructions to the operator of the
gasoline dispensing facilityoperation describing
necessary maintenance operations and procedures
for prompt notification of the owner in case of
any malfunction of a vapor control system; and
3) Repair, replace or modify any worn out or
malfunctioning component or element of design.
d)
Subject to subsection (b) of this Section, each
operator of a gasoline dispensing facility operation
shall:
1) Maintain and operate each vapor control system in
accordance with the owner’s instructions;
2) Promptly notify the owner of any scheduled
maintenance or malfunction requiring replacement
or repair of a major component of a vapor control
system;
3) Maintain gauges, meters or other specified testing
devices in proper working order;
4) Operate the vapor collection system and delivery
vessel unloading points in a manner that prevents:
01140-0911

505
A) A reading equal to or greater than 100
percent of the lower explosive limit (LEL
measured as propane) when tested in
accordance with the procedure described in
EPA 450/2-78-051 Appendix B, and
B) Avoidable leaks of liquid during the filling
of storage tanks; and
5) Within 15 business days after discovery of the
leak by the owner, operator, or the Agency, repair
and retest a vapor collection system which exceeds
the limits of subsection (d) (4) (A) above.
Gasoline dispensi.ny LaciiiLlcs- were required to take
certain actions to achieve compliance which are
summarized in 35 Ill. Adm. Code 215, Appendix C.
(Source: Amended at
Ill. Req
effective
___________
Section 219.584
Gasoline Delivery Vessels
a) Any delivery vessel equipped for vapor control by use
of vapor collection equipment:
1) Shall have a vapor space connection that is
equipped with fittings which are vapor tight;
2) Shall have its hatches closed at all times during
loading or unloading operations, unless a top
loading vapor recovery system is used;
3)
Shall not internally exceed a gauge pressure of 18
inches of water or a vacuum of 6 inches of water;
4) Shall be designed and maintained to be vapor tight
at all times during normal operations;
5) Shall not be refilled in Illinois at other than:
A) A bulk gasoline terminal that complies with
the requirements of Section 219.582 of this
Part or
B) A bulk gasoline plant that complies with the
requirements of Section 219.581(b) of this
Part.
6’) Shall be tested annually in accordance with Method
27, 40 CFR 60, Appendix A, incorporated by
reference in Section 219.105 of this Part.
Each
vessel must be repaired and retested within 15
01 it,0-091 2

506
business days after discovery of the leak by the
owner, operator, or the Agency, when it fails to
sustain:
A) A pressure drop of no more than three inches
of water in five minutes; and
B) A vacuum drop of no more than three inches of
water in five minutes.
b) Any delivery vessel meeting the requirements of
subsection (a) of this Section shall have a sticker
affixed to the tank adjacent to the tank manufacturer’s
data plate which contains the tester’s name, the tank
identification number and the date of the test. The
sticker shall be in a form prescribed by the Agency,
and, for those delivery vessels subject to 35 Ill. Adm.
Code 215 as of December 31, 1987 shall have been
displayed no later than December 31, 1987.
c) The owner or operator of a delivery vessel shall:
1) Maintain copies of any test required under
subsection (a) (6) of this Section for a period of
3 years;
2) Provide copies of these tests to the Agency upon
request; and
3) Provide annual test result certification to bulk
gasoline plants and terminals where the delivery
vessel is loaded.
d) Any delivery vessel which has undergone and passed a
test in another state which has a USEPA-approved leak
testing and certification program will satisfy the
requirements of subsection (a) of this Section.
Delivery vessels must display a sticker, decal or
stencil approved by the state where tested or comply
with the requirements of subsection (b) of this
Section. All such stickers, decals or stencils shall
have been displayed no later than December 31, 1987,
for delivery vessels subject to 35 Ill. Adm. Code 215
as of December 31, 1987.
(Source: Amended at
Ill. Req.
______,
effective
___________
Section 219.585
Gasoline Volatility Standards
a) No person shall sell, offer for sale, dispense, supply,
offer for supply, or transport for use in Illinois
gasoline whose Reid vapor pressure exceeds the
0 140-0913

507
applicable limitations set forth in subsections (b) and
(c) of this Section during the regulatory control
periods, which shall be July ~j~y1 to August 31
September 15 for retail outlets, wholesale
purchaser—consumer facilities, and all other
facilities.
b) The Reid vapor pressure of gasoline, a measure of its
volatility, shall not exceed 9.ff5Q psi (65.562.07 kPa)
during the regulatory control period in 1990 and each
year thereafter.
c) The Reid vapor pressure of ethanol blend gasolines
shall not exceed the limitations for gasoline set forth
in subsection (b) of this Section by more than 1.0 psi
(6.9 kPa). Notwithstanding this limitation, blenders
of ethanol blend gasolines whose Reid vapor pressure is
less than 1.0 psi above the base stock gasoline
immediately after blending with ethanol are prohibited
from adding butane or any product that will increase
the Reid vapor pressure of the blended gasoline.
d) All sampling of gasoline required pursuant to the
provisions of this Section shall be conducted by one or
more of the following approved methods or procedures
which are incorporated by reference in Section 215.105.
1)
For manual sampling, ASTN D4057;
2) For automatic sampling, ASTM D4177;
3)
Sampling procedures for Fuel Volatility,
40 CFR 80
Appendix D.
e) The Reid vapor pressure of gasoline shall be measured
in accordance with either test method ASTN D323 or a
modification of ASTM D323 known as the “dry method” as
set forth in 40 CFR 80, Appendix E, incorporated by
reference in 35 Ill. Adm. Code Q-~219.~G~112of this
Part. For gasoline — oxygenate blends which contain
water—extractable oxygenates, the Reid vapor pressure
shall be measured using the dry method test.
f) The ethanol content of ethanol blend gasolines shall be
determined by use of one of the approved testing
methodologies specified in 40 CFR 80, Appendix F,
incorporated by reference in 35 Ill. Adm. Code
2-3~219.~
of this Part.
g) Any alternate to the sampling or testing methods or
procedures contained in subsections (d), (e), and (f)
of this Section must be approved by the Agency, which
01140-09114

508
shall consider data comparing the performance of the
proposed alternative to the performance of one or more
approved test methods or procedures. Such data shall
accompany any request for Agency approval of any
alternate test procedure. If the Agency determines
that such data demonstrates that the proposed
alternative will achieve results equivalent to the
approved test methods or will achieve results
equivalent to the approved test methods or procedures,
the Agency shall approve the proposed alternative.
h) Each refiner or supplier that distributes gasoline or
ethanol blends shall:
1) During the regulatory control period, state that
the Reid vapor pressure of all gasoline or ethanol
blends leaving the refinery or distribution
facility for use in Illinois complies with the
Reid vapor pressure limitations set forth in 35
Ill. Adm. Code -2-~5219.585(b)
and (c) of this Part.
Any facilitysource receiving this gasoline shall
be provided with a copy of an invoice, bill of
lading, or other documentation used in normal
business practice stating that the Reid vapor
pressure of the gasoline complies with the State
Reid vapor pressure standard.
2) Maintain records for a period of one year on the
Reid vapor pressure, quantity shipped and date of
delivery of any gasoline or ethanol blends leaving
the refinery or distribution facility for use in
Illinois. The Agency shall be provided with
copies of such records if requested.
(Source: Amended at — Ill. Req.
______,
effective
___________
Section 219.586
Gasoline Dispensing Facilities-Operations
-
Motor Vehicle Fueling Operations
a) For the purposes of this e~ection, the following
definitions apply.
1) Average M~onthly~yolume÷ means tThe amount of
motor vehicle fuel dispensed per month from a
gasoline dispensing facility operation based upon
a monthly average for the 2—year period of
November, 1990 through October, 1992 or, if not
available, the monthly average for the most recent
twelve calendar months. Monthly averages are to
include only those months when the facility
operation was operating.
0
I
140-0915

509
Certified+ means aAny vapor collection and control
system which has been tested and approved by CARB
as having a vapor recovery and removal efficiency
of at least 95 (by weight) shall constitute a
certified vapor collection and control system.
CARB testing and approval is pursuant to the CARB
manual, hereby incorporated by reference ~
219.112 of this Part (California Air Resources
Board, Compliance Division, Compliance Assistance
Program: Facilities Phase I ~ II (October 1988,
rev. March 1091 CARD Manual). This incorporation
~includcs no later addit...ons or amcnamcnt.~..
3) Completion of installation+ means tThe successful
passing of one or more of the following tests
applicable to the installed vapor collection and
control system: Dynamic Backpressure Test,
Pressure Decay/Leak Test, and Liquid Blockage
Test~ (United States Environmental Protection
Agency, Washington D.C., EPA-450/3---9l- 002b).
These tests arc hereby incorporated by reference
at 219.112 of this Part.
This incorporation
includes no later additions or amendments-.)
4) Constructed+ means fFabricated, erected or
installed; refers to any
facility, emission source
or air pollution control equipment.
5) CARB÷means California Air Resources Board, P.O.
Box 2815, Sacramento, CA 95812.
6) Employee÷means a?rny person who performs work for
an employer.
7) FacilityOperation÷means aAny building, structure,
installation, operation
or combination thereof
located on contiguous properties and under common
ownership that provides for the dispensing of
motor vehicle fuel.
8) Gasoline ~ispensing Facilityoperation÷means aAny
facility operation where motor vehicle fuel is
dispensed into motor vehicle fuel tanks or
portable containers from a storage tank with a
capacity of 2176 liters
(575 gallons) or more.
9) Modification+ means aAny change, removal or
addition, other than an identical replacement, of
any component contained within the vapor
collection and control system.
10) Motor ~yehicle÷ means aAny self-propelled vehicle
O~1400916
2)

510
powered by an internal combustion engine
including, but not limited to, automobiles and
trucks. Specifically excluded from this
definition are watercraft and aircraft.
11) Motor ~yehicle ~ue1÷ means aAny petroleum
distillate having a Reid vapor pressure of more
than 27.6 kilopascals
(kPa) (four pounds per
square inch) and which is used to power motor
vehicles.
12)
Owner or Ooperator÷ means aAny person who owns,
leases, operates, manages, supervises or controls
(directly or indirectly) a gasoline dispensing
facilityoperation.
13) Reid zvapor Ppressure÷fFor gasoline, ~ shall be
measured in accordance with either the method ASTM
D323 or a modification of ASTM D323 known as the
“dry method” as set forth in 40 CFR 80, Appendix
E, incorporated by references in 35 Ill. Adm. Code
215.105219.112 of this Part.
14) Vapor ~ollection and Gcontrol S~ystem÷means aAny
system certified by CARB which limits the
discharge to the atmosphere
of motor vehicle fuel
vapors displaced during the dispensing of motor
vehicle fuel into motor vehicle fuel tanks.
b) The provisions of subsection (c) below shall apply to
any gasoline dispensing facilityoperation
which
dispenses an average monthly volume of more than 10,000
gallons of motor vehicle fuel per month. Compliance
shall be demonstrated in accordance with the schedule
provided in subsection (d) below.
c) No owner or operator of a gasoline dispensing facility
operation subject to the requirements of subsection (b)
above shall cause or allow the dispensing of motor
vehicle fuel at any time from
a motor fuel dispenser
unless the dispenser is equipped with and utilizes
a
vapor collection and control system which is properly
installed and operated as provided below:
1) Any vapor collection and control system installed,
used or maintained has been GARB certified.
2)
Any vapor collection and control system utilized
is maintained in accordance with the
manufacturer’s specifications
and the
certification.
UI 140-0917

511
3) No elements or components of a vapor collection
and control system are modified, removed, replaced
or otherwise rendered inoperative in a manner
which prevents the system from performing in
accordance with its certification
and design
specifications.
4) A vapor collection and control system has no
defective, malfunctioning or missing components.
5) Operators and employees of the gasoline dispensing
facilityoperation are trained and instructed in
the proper operation and maintenance of a vapor
collection and control system.
6) Instructions are posted in a conspicuous and
visible place within the motor fuel dispensing
area and describe the proper method of dispensing
motor vehicle fuel with the use of the vapor
collection and control system.
d) In conjunction with the compliance provisions of
Section 219.105 of this Part, facilities-operations
subject to the requirements of subsection (c) above
shall demonstrate compliance according to the
following:
1) Facilities-Operations that commenced construction
after November 1, 1990, must comply by May 1,
1993.
2) Facilities-Operations that commenced construction
before November 1, 1990, and dispense an average
monthly volume of more than 100,000 gallons of
motor fuel per month must comply by November 1,
1993.
3) Facilities-Operations that commenced construction
before November 1, 1990, and dispense an average
monthly volume of less than 100,000 gallons of
motor fuel per month must comply by November 1,
1994.
4) New facilities-operations constructed after the
adoption of this Section shall comply with the
requirements of subsection (c) above upon startup
of the facilityoperation.
5) Existing facilitiesoperations previously exempted
from but which become subject to the requirements
of subsection
(c)
above after May 1, 1993 shall
comply with the requirements of subsection (c)
01140~0918

512
above within six calendar months of the date from
which the facilityoperation becomes subject.
e) Any gasoline dispensing facilityoperation that becomes
subject to the provisions of subsection (c) above at
any time shall remain subject to the provisions of
subsection (c) above at all times.
f) Upon request by the Agency, the owner or operator of a
gasoline dispensing facilityoperation which claims to
be exempt from the requirements of this Section shall
submit records to the Agency within 30 calendar days
from the date of the request which demonstrate that the
gasoline dispensing facilityoperation is in fact
exempt.
q) Recordkeeping and reporting:
1) Any gasoline dispensing facilityoperation subject
to subsection (c) above shall retain at the
facilityoperation copies of the registration
information required at subsection (h) below.
2)
Records and reports required pursuant to this
subsection shall be made available to the Agency
upon request. Records and reports which shall be
maintained by the owner or operator of the
gasoline dispensing facility operation shall
clearly demonstrate:
A) That a certified vapor collection and control
system has been installed and tested to
verify its performance according to its
specifications.
B) That proper maintenance has been conducted in
accordance with the manufacturer’s
specifications and requirements.
C) The time period and duration of all
malfunctions of the vapor collection and
control system.
D) The motor vehicle fuel throughput of the
facilityoperation for each calendar month of
the previous year.
E) That operators and employees are trained and
instructed in the proper operation and
maintenance of the vapor collection and
control system and informed as to the
potential penalties associated with the

513
violation of any provision of this Section.
h) Any gasoline dispensing facilityoperation subject to
subsection (c) above shall be exempt from the permit
requirements specified under 35 Ill. Adm. Code 201.142,
201.143 and 201.144 of this Part for its vapor
collection and control systems, provided that:
1) Upon the installation of a vapor collection and
control system, the owner or operator of the
gasoline dispensing facilityoperation submits to
the Agency a registration which provides at
minimum the facilityoperation name and address,
signature of the owner or operator, the GARB
Executive Order Number for the vapor collection
and control system to be utilized, the number of
nozzles (excluding diesel or kerosene) used for
motor vehicle refueling, the monthly average
volume of motor vehicle fuel dispensed, the
location (including contact person’s name,
address, and telephone number) of records and
reports required by this Section, and the date of
completion of installation of the vapor collection
and control system.
2) The registration is submitted to the Agency within
30 days of completion of such installation.
3) A copy of the registration information is
maintained at the gasoline dispensing
facilityoperation.
4)
Upon the modification of an existing vapor
collection and control system, the owner or
operator of the gasoline dispensing facility
operation submits to the Agency a registration
that details the changes to the information
provided in the previous registration of the vapor
collection and control system and which includes
the signature of the owner or operator. The
registration must be submitted to the Agency
within 30 days of completion of such modification.
(Source: Amended at
_____
Ill. Req.
_______,
effective
______)
SUBPART Z: DRY CLEANERS
Section 219.601
Perchloroethylene Dry Cleaners
The owner or operator of a dry cleaning facility operation which
uses perchloroethylene shall:
a i 140-0920

514
a) Vent the entire dryer exhaust through a properly
designed and functioning carbon adsorption system or
equally effective control device; and
b) Emit no more than 100 ppmv of VOM from the dryer
control device before dilution, or achieve a 90 percent
average reduction before dilution; and
c) Immediately repair all components found to be leaking
liquid VOM; and
d) Cook or treat all diatomaceous earth filters so that
the residue contains 25 kg (55 lb) or less of volatile
organic material per 100 kg (220 lb) of wet waste
material; and
e) Reduce the vVOM from all solvent stills to 60 kg (132
lb) or less per 100 kg (220 lb) of wet waste material;
and
f) Drain all filtration cartridges in the filter housing
or other sealed container for at least 24 hours before
discarding the cartridges; and
g) Dry all drained filtration cartridges in equipment
connected to an emission reduction system or in a
manner that will eliminate emission of volatile organic
material to the atmosphere.
(Source: Amended at
Ill. Req.
______,
effective
__________
Section 219.602
Exemptions
The provisions of Section 219.601 are not applicable to
perchloroethylene dry cleaning operations which are coin—operated
or to dry cleaning facilities-operation consuming less than 30 gal
per month (360 gal per year) of perchioroethylene.
(Source: Amended at — Ill. Reg.
______
, effective
___________)
Section 219.603
Leaks
The presence of leaks shall be determined for purposes of Section
219.601(c) of this Part by a visual inspection of the following:
hose connections, unions, couplings and valves; machine door
gaskets and seatings; filter head gasket and seating; pumps; base
tanks and storage containers; water separators; filter sludge
recovery; distillation unit; diverter valves; saturated lint from
lint baskets; and cartridge filters.
(Source: Amended at — Ill.
Req.
______,
effective
_________)
0 ~L~fl-092l

515
Section 219.604
Compliance Dates (Repealed)
~
to 35 Ill. Adm. Code 215, Subpart Z, shall have complied with its
standards and limitations in accordance with the applicable dates
‘~r’t~frn-th
~in 3~ T11 7~c~1m Crdc~ 21~~O4
(Source:
Repealed at
Section 219.605
Ill. Req.
______,
effective
__________)
Compliance Plan (Repealed)
The owner or operator of an emission source subject to
this Subpart s-hall have submitted to the Agency a
compliance plan, pursuant to 35 Ill. Adm. Code 201,
Subpart H, including a project completion schedule
where applicable, no later than, for Section 219.601(a)
and (b) , April 21, 1983.
Unless- the submitted compliance plan or schedule was
disapproved by the Agency, the owner or operator of a
facility or emission source may operate the emission
source according to the plan and schedule as- submitted.
The plan and schedule shall meet the requirements of 35
Ill. Adm. Code 20~, ~u~part H, including speci~
interim dates as required in 35 Ill. Adm. Code 201.242.
(Source: Repealed at
— Ill. Reg.
_______
effective
)
Section 219.606
Exception to Compliance Plan (Repealed)
Coin-operated dry cleaning operations and dry cleaning facilities
consuming less than
30 gal per month (360 gal per year) of
perchlorocthyleno are not required to submit or obtain
an Agency
approved compliance plan or project completion schedule.
(Source: Repealed at
Ill. Req
, effective
__________)
Section 219.608
Operating Practices for Petroleum Solvent Dry
Cleaners
In order to minimize fugitive solvent emissions, the owner or
operator of a petroleum solvent
dry cleaning facilitysource shall
employ good housekeeping practices including the following:
a)
General Housekeeping Requirements
1) Equipment containing solvent (washers, dryers,
extractors and filters) shall remain closed at all
times except during load transfer and maintenance.
Lint filter and button trap covers shall
remain
0
140-0922

516
closed except when solvent—laden material is being
removed.
2)
Cans, buckets, barrels and other containers of
solvent or of solvent—laden material shall be
covered except when in use.
3) Solvent-laden material shall be exposed to the
atmosphere only for the minimum time necessary for
load transfer.
b) Installation and operation of equipment:
1) All cartridge filters shall be enclosed and
operated in accordance with the procedures and
specifications recommended by the manufacturer for
the cartridge filter. After installation, the
cartridges shall be inspected, monitored and
maintained in accordance with the manufacturer’s
recommendations; and
2) Vents on containers for new solvent and for
solvent—containing waste shall be constructed and
maintained so as to minimize solvent vapor
emissions. Criteria for the minimization of
solvent vapor emissions include the elimination of
solvent buckets and barrels standing open to the
atmosphere, and the repair of gaskets and seals
that expose solvent—rich environments to the
atmosphere, to be determined through visual
inspection.
(Source:
Amended at
Ill. Req.
______,
effective
__________)
Section 219.609
Program for Inspection and Repair of Leaks
a)
The owner or operator of a petroleum solvent
dry
cleaning facilitysource shall conduct the following
visual inspections on a weekly basis:
1)
Washers,
dryers, solvent filters, settling tanks,
vacuum stills and containers and conveyors of
petroleum solvent shall be inspected for visible
leaks of solvent liquid.
2) Pipes, hoses and fittings shall be inspected for
active dripping or dampness.
3) Pumps and filters shall be inspected for leaks
around seals and access covers.
4) Gaskets and seals shall be inspected for wear and
01140-8923

517
defects.
b) Leaks of petroleum solvent liquid and vapors shall be
repaired within three working days of detection, unless
necessary replacement parts are not on site.
1) If necessary, repair parts shall be ordered within
three working days of detection of the leak.
2)
The leak shall be repaired within three days of
delivery of necessary parts.
(Source: Amended at — Ill. Reg.
______,
effective
___________
Section 219.610
Testing and Monitoring
a) Compliance with Sections 219.607(b) (2) , 219.608 and
219.609 of this Part shall be determined by visual
inspection; and
b)
Compliance with Sections 219.607 (a) (2) and (b) (1) ~
this Part shall be determined by methods described in
EPA—450/3-82-009 (1982) incorporated by reference in
Section 219.112 of this Part.
c) If a control device is used to comply with Section
219.607(a) (1) of this Part, then compliance shall be
determined using 40 CFR 60 Appendix A, Method 25 (1984)
incorporated by reference in Section 219.112 of this
Part.
(Source: Amended at
Ill. Reg.
______,
effective
___________
Section 219.611
Exemption for Petroleum Solvent Dry Cleaners
The provisions of Sections 219.607 through 219.610 of this Part
shall not apply to petroleum solvent dry cleaning facilities
sources whose emissions of volatile organic material do not
exceed 91 Mg (100 tons) per year in the absence of pollution
control equipment or whose emissions of VOM, as limited by the
operating permit, will not exceed 91 Mg (100 tons) per year in
the absence of pollution control equipment.
(Source: Amended at
Ill. Req.
______,
effective
__________
Section 219.612
Compliance Dates (Repealed)
Owners and operators of emission sources subject to 35 Ill. Adm.
Code 215.607 through 215.609 as of December 31, 1987 shall have
complied with the requirements set forth therein no later than
r-
0
140-09214
~ecemrcr
31, 1087.

518
(Source: Repealed at
Ill. Peg.
______,
effective
_________
Section 219.613
Compliance Plan (Repealed)
The owner
~nh~~t
t~
or
~
operator of an
T11
~m
~
emission source formerly
~l~610(a) as of May 31,
-
Aacnc” comDliapr~
b)- The plan and schedule s-hall meet the requirements of 35
Ill. Adm. Code 20~1~
(Source: Repealed at — Ill.
Req.
______,
effective
__________)
SUBPART AA: PAINT AND INK MANUFACTURING
Section 219.620
Applicability
a) This s~ubpartshall apply to all paint and ink
manufacturing plantssources which:
1) Include process emission sources-units not subject
to Subparts B, E, F (excluding Section 219.204(1)
of this Part), H ~exc1uding
Section 219.405 ~
this Part), Q, R, 5, P (excluding Section 219.486
of this Part), V, X, Y~e~Z or BB of this Part;
and which as a group both:
A) ~llave maximum theoretical emissions of 91 Mg
(100 tons) or more per calendar year of VON
if no air
pollution control equipment were
used, and
B) a~renot limited to less than 91 Mg (100
tons) of VON emissions per calendar year in
the absence of air pollution control
equipment, through production or capacity
limitations contained in a federally
enforceable construction permit or a SIP
revision, or
2)
Produce more than 7,570,820 1 (2,000,000 gal) per
calendar year of paint or ink formulations,
which
contain less than 10 percent (by weight) water,
and ink formulations not containing as the primary
solvents water, Maqie oil or glycol.
b) For the purposes of this Subpart, uncontrolled VON
emissions are the emissions of VON which would result
if no air pollution control equipment were used.
o~00925
i9.~
shall h~ submitted to th~
4~..,
including a project coxapletio~ schedule wh.~
applicable, no later than May 31, 1087.

519
(Source: Amended at — Ill. Peg.
______,
effective
__________)
Section 219.621
Exemption for Waterbase Material and
Heatset-Offset Ink
The requirements of Sections 219.624 and 219.625 and Section
219.628(a) of this Part shall not apply to equipment while it is
being used to produce either:
a)
p~aint or ink formulations which contain 10 percent or
more (by weight) water, or
b) ~nks containing Nagie oil and glycol as the primary
solvent.
(Source: Amended at
Ill. Req.
______,
effective
__________/
Section 219.623
Permit Conditions
No person shall violate any condition in a permit when the
condition results in exclusion of the plantsource or an emission
sourccunit from this Subpart.
(Source: Amended at — Ill. Reg.
______,
effective
__________
Section 219.624
Open-#~opMills, Tanks, Vats or Vessels
No
person shall operate an open—top mill, tank, vat or vessel
with a volume of more than 45 1 (12 gal) for the production of
paint or ink unless:
a) The mill, tank, vat or vessel is equipped with a cover
which completely covers the mill, tank, vat or vessel
opening except for an opening no larger than necessary
to allow for safe clearance for a mixer shaft. Such
cover shall extend at least 1.27 cm (0.5 in.) beyond
the outer rim of the opening or be attached to the rim.
b) The cover remains closed except when production,
sampling, maintenance or inspection procedures require
access.
c) The cover is maintained in good condition such that,
when in place, it maintains contact with the rim of the
opening for at least 90 percent of the circumference of
the rim.
(Source: Amended at
Ill. Req.
______,
effective
___________)
Section 219.628
Leaks
The owner or operator of a paint or ink manufacturing plantsource
o
140-0926

520
shall, for the purpose of detecting leaks, conduct an equipment
monitoring program as set forth below:
a) Each pump shall be checked by visual inspection each
calendar week for indications of leaks, that is,
liquids dripping from the pump seal. If there are
indications of liquids dripping from the pump seal, the
pump shall be repaired as soon as practicable,
but no
later than 15 calendar days after the leak is detected.
b)
Any pump, valve, pressure relief valve, sampling
connection, open—ended valve and flange or connector
containing a fluid which is at least 10 percent VON by
weight which appears to be leaking on the basis of
sight, smell or sound shall be repaired as soon as
practicable, but no later than 15 calendar days after
the leak is detected.
c)
A weather proof, readily visible tag, in bright colors
such as red or yellow, bearing an identification number
and the date on which the leak was detected shall be
attached to leaking equipment. The tag may be removed
upon repair, that is, when the equipment is adjusted or
otherwise altered to allow operation without leaking.
d)
When a leak is detected, the owner or operator shall
record the date of detection and repair and the record
shall be retained at the plantsource for at least two
years from the date of each detection or each repair
attempt. The record shall be made available to any
person upon verbal or written request during business
hours.
(Source:
Amended at
Ill. Req.
______,
effective
___________
Section 219.636
Compliance Schedule
Every owner or operator of an emission source subject to the
control requirements of this Subpart shall comply with the
requirements thereof on and after a date consistent with Section
219.106 of this Part.
(Source:
Amended at
Ill. Req.
______,
effective
___________)
Section 219.637
Recordkeeping and Reporting
a)
Upon request by the Agency, the owner or operator of ai~
emission source which claims to be exempt from the
requirements of this Subpart shall submit records to
the Agency within 30 calendar days from the date of the
request which document that the emission source
is in fact exempt from this Subpart.
These records
01140-0927

521
shall include (but are not limited to) the percent
water (by weight) in the paint or ink being produced
and the quantity of Maqie oil, glycol and other
solvents in the ink being produced.
b) Every owner or operator of an emission source which is
subject to the requirements of this Subpart shall
maintain all records necessary to demonstrate
compliance with those requirements at the
facilitysource for three years.
(Source: Amended at — Ill. Reg.
______,
effective
__________
SUBPART BB: POLYSTYRENE PLANTS
Section 219.875219.640
Applicability of Subpart EB
The provisions of this Subpart shall apply to polystyrene plants:
a) Which use continuous processes to manufacture
polystyrene - polybutadiene co-polymer; and
b) Which fall within Standard Industrial Classification
Group No. 282, Industry No. 2821, except that the
manufacture of polystyrene resins need not be the
primary manufacturing process at the plant.
(Source:
Renumbered from Section 219.875 and amended at
____
Ill. Req.
,
effective
___________
Section 210.877219.642 Emissions Limitation at Polystyrene
Plants
No person shall cause or allow the emissions of VOM from the
material recovery section to exceed 0.12 kg of VON per 1000 kg of
polystyrene resin produced.
(Source: Renumbered from Section 219.877 at
Ill.
Req.
effective
________________)
Section 219.836219.644 Emissions Testing
a)
Upon a reasonable request by the Agency, the owner or
operator of a polystyrene plant subject to this Subpart
shall at his own expense demonstrate compliance by use
of the following method: 40 CFR 60, Appendix A, Method
25
Determination of Total Gaseous Non—Methane Organic
Emissions as Carbon (1984), incorporated by reference
in Section 219.112 of this Part.
b)
A person planning to conduct a VON emissions test to
demonstrate compliance with this Subpart shall notify
~ 14Q-0928

522
the Agency of that intent not less than 30 days before
the planned initiation of the tests so the Agency may
observe the test.
(Source: Renumbered from Section 219.886 and amended at
____
Ill. Peg.
_____,
effective
__________
Section 219.875
Applicability of Subpart BB (Renumbered)
(Source: Renumbered to Section 219.640 at
Ill. Peg.
effective
_______________)
Section 219.877
Emissions Limitation at Polystyrene Plants
(Renumbered)
(Source: Renumbered to Section 219.642 at
Ill. Peg.
effective
______________)
Section 219.879
Compliance Date (Repealed)
Every owner and operator of an emission source subject to 35 Ill.
Adm. Code 215, Subpart BB, as of December 31, 10S7, shall have
complied with its standards and limitations by December 31, 1987.
(Source: Repealed at
Ill. Peg.
______,
effective
__________)
Section 219.881
Compliance Plan (Repealed)
a-)- The owner or operator of an emission source formerly
subject to the requirements of 35 Ill. Adm. Code 215
Subpart BE s-hall have submitted to the Agency a
compliance plan in accordance with 35 Ill. Adm. Code
201, Subpart H, including a project completion schedule
on or before December 1, 1087.
-b-)- Unless the submitted compliance plan or schedule was
disapproved by the Agency, the owner or operator of a
facility or emission source subject to this Subpart may
operate the emission source according to the plan and
schedule as submitted.
e-)- The plan and schedule shall meet the requirements of 35
Ill. Adm. Code 201, Subpart H and Section 210.883.
(Source:
Repealed at
Ill. Peg.
______,
effective
__________)
Section 219.883
Special Requirements for Compliance Plan
(Repealed)
For sources subject to this
plan shall include:
0\
~~-09Z9

523
a-)- A description of each process which is subject to an
emissions limitation
b-)-
Quantification of the emissions from each process-
e-)- A description of the procedures and methods used to
determine the emissions of VOM
8-)- A description of the methods which will be us-ed to
demonstrate compliance with the allowable plantwidc
emission limitation (Section 215.877), including a
method of inventory, recor~k
in~ and emission
measurement.
(Source: Repealed at
Ill. Req.
______,
effective
_________)
Section 218.886
Emissions Testing (Renumbered)
(Source:
Renumbered to Section 218.644 at
____
Ill. Peg.
effective
__________________)
SUBPART PP: MISCELLANEOUS FABRICATED PRODUCT
MANUFACTURING PROCESSES
Section 219.920 Applicability
a) The requirements of this Subpart shall apply to a
plant’s-source’s miscellaneous fabricated product
manufacturing process emission sources-units which are
not included within any of the source categories
specified in Subparts B, E, F, H, Q, R, 5,
L~.
V, X, Y~
or Z or BB if the plantsource is subject to this
Subpart. A plantsource is subject to this Subpart if
it contains process emission ~-Gurcc3 units, not
regulated by Subparts B, E, F (excluding Section
219.204(1) of this Part), H (excluding Section 219.405
of this Part), Q, R, 5, P, (excluding Section 219.486
of this Part), V, X, Y~or Z or BE of this Part; which
as a group both:
1)
1~jave maximum theoretical
emissions of 91 Mg (100
tons) or more per calendar year of VON if no air
pollution control equipment were used, and
2)
aAre not limited to less than 91 Mg (100 tons) of
VON emissions per calendar year in the absence of
air pollution control equipment, through
production or capacity limitations contained in a
federally enforceable construction permit or a SIP
revision.
b)
If a
plantsource ceases to fulfill the criteria of
01140-0930

524
subsection (a)above, the requirements of this Subpart
shall continue to apply to a miscellaneous fabricated
products manufacturing process emission sourceunit
which was ever subject to the control requirements of
Section 219.926 of this Part.
c)
No limits under this Subpart shall apply to emission
sources-units with emissions of VON to the atmosphere
less than or equal to 0.91 Mg (1.0 ton) per calendar
year if the total emissions from such sources emission
units not complying with Section 219.926 of this Part
does not exceed 4.5/Mg (5.0 tons) per calendar year.
d) For the purposes of this Subpart, an emission
sourccunit shall be considered regulated by a Subpart
if it is subject to the limits of that Subpart. An
emission sourceunit is not considered regulated by a
Subpart if it is not sublect to the limits of that
Subpart, e.g., the emission unit is covered by an
exemption in the Subpart or the applicability criteria
of the Subpart are not met.
its emissions are below
the applicability
cutoff level or if the source is
covered by an exemption.
e) For the purposes of this Subpart, uncontrolled VON
emissions are the emissions of VON which would result
if no air pollution control equipment were used.
(Source:
Amended at
Ill. Req.
______,
effective
__________)
Section 219.923
Permit Conditions
No person shall violate any condition in a permit when the
condition results in exclusion of the plantsource or an emission
sourceunit from this Subpart~
(Source: Amended at
Ill. Req.
______,
effective
___________
Section 219.926
Control Requirements
Every owner or operator of an emission sourcemiscellaneous
fabricated product manufacturing process emission unit subject to
this Subpart shall comply with the requirements of subsection
(a), (b) or
(C)
of this Section:
a) Emission capture and control techniques which achieve
an overall reduction in uncontrolled VON emissions of
at least 81 percent from each emission unit, or
(Board Note:
For the purpose of this provision, an
emission unit is any part or activity at a source of a
type that by itself is sublect to control requirements
3 I
140-0931

525
in other Subparts of this Part or
40 CFR 60L
incorporated by reference in Section 219.112, e.g., a
coating line, a printing line, a process unit, a
wastewater system, or other equipment, or is otherwise
any part or activity at a source.)
b) For coating lines, the daily-weighted average VON
content shall not exceed 0.42 kg VOM/l (3.5 lbs
VON/gal) of coating as applied (minus water and any
compounds which are specifically exempted from the
definition of VON) during any day. Owners and
operators complying with this Section are not required
to comply with Section 219.301 of this Part, or
c)
An alternative control plan which has been approved by
the Agency and approved by the USEPA as a SIP revision.
(Source: Amended at
Ill. Req.
______,
effective
___________)
Section 219.927
Compliance Schedule
Every owner or operator of an emission sourceunit subject to the
control requirements of this Subpart shall comply with the
requirements thereof on and after a date consistent with Section
219.106 of this Part.
(Source: Amended at — Ill. Req.
______,
effective
__________)
Section 219.928
Testing
a) When in the opinion of the Agency it is necessary to
conduct testing to demonstrate compliance with Section
219.926 of this Part, the owner or operator of a VON
emission sourceunit subject to the requirements of this
Subpart shall, at his own expense, conduct such tests
in accordance with the applicable test methods and
procedures specified in Section 219.105 of this Part.
b) Nothing in this Section shall limit the authority of
the USEPA pursuant to the Clean Air Act, as amended, to
require testing.
(Source: Amended at
Ill. Req.
______,
effective
__________)
SUBPART
QQ:
MISCELLANEOUS FORMULATION MANUFACTURING PROCESSES
Section 219.940
Applicability
a) The requirements of this Subpart shall apply to a
plant’s-source’s miscellaneous formulation manufacturing
process emission sources-units, which are not included
within any of the source categories specified in
01140-0932

526
Subparts B, E, F, H, Q, R, 5, ~ V, X, Y~or Z or BB of
this Part if the plantsource is subject to this
Subpart. A plantsource is subject to this Subpart if
it contains process emission sources-units, not
regulated by Subparts B, E, F (excluding Section
219.204(1) of this Part), H (excluding Section 219.405
of this Part), Q, R, 5, T (excluding Section 219.486 of
this Part), V, X, Y~or Z or BB of this Part; which as
a group both:
1) 1~Havemaximum theoretical emissions of 91 Mg (100
tons) or more per calendar year of VOM if no air
pollution control equipment were used, and
2) e-~renot limited to less than 91 Mg (100 tons) of
VON emissions per calendar year in the absence of
air pollution control equipment, through
production or capacity limitations contained in a
federally enforceable construction permit or a SIP
revision.
b) If a plantsource ceases to fulfill the criteria of
subsection (a) of this Section, the requirements of
this Subpart shall continue to apply to a miscellaneous
formulation manufacturing process emission source unit
which was ever subject to the control requirements of
Section 219.946 of this Part.
c) No limits under this Subpart shall apply to emission
sources-units with emissions of VOM to the atmosphere
less than or equal to 2.3 Mg (2.5 tons) per calendar
year if the total emissions from such sources- emission
units not complying with this Section does not exceed
4.5 Mg (5.0 tons) per calendar year.
d) For the purposes of this Subpart, an emission
sourceunit shall be considered regulated by a Subpart
if it is subject to the limits of that Subpart. An
emission sourccunit is not considered regulated by a
Subpart if it is not sublect to the limits of that
Subpart, e.g., the emission unit is covered by an
exemption in the Subpart or the applicability criteria
of the Subpart are not met. its emissions are below the
applicability cutoff level or if the source is covered
by an exemption.
e) For the purposes of this Subpart, uncontrolled VOM
emissions are the emissions of VON which would result
if no air pollution control equipment were used.
(Source: Amended at
Ill. Peg.
______,
effective
___________)
01140-0933

527
Section 219.943
Permit Conditions
No person shall violate any condition in a permit when the
condition results in exclusion of the plantsource or an emission
sourccunit from this Subpart.
(Source: Amended at —
Ill. Req.
______,
effective
__________
Section 219.946
Control Requirements
Every owner or operator of an emission sourcea miscellaneous
formulation manufacturing process emission unit subject to this
Subpart shall comply with the requirements of subsection (a) or
(b) below.
a) Emission capture and control techniques which achieve
an overall reduction in uncontrolled VOM emissions of
at least 81 percent from each emission unit, or
(Board Note: For the purpose of this provision, an
emission unit is any part or activity at a source of a
type that by itself is sublect to control requirements
in other Subparts of this Part or 40 CFR 60,
incorporated by reference in Section 219.112, e.g., a
coating line, a printing line, a process unit, a
wastewater system, or other equipment, or is otherwise
any part or activity at a source.)
b) An alternative control plan which has been approved by
the Agency and approved by the USEPA as a SIP revision.
(Source: Amended at
Ill. Peg.
______,
effective
___________)
Section 219.947
Compliance Schedule
Every owner or operator of an emission sourccunit subject to the
control requirements of this Subpart shall comply with the
requirements thereof on and after a date consistent with Section
219.106 of this Part.
(Source: Amended at — Ill. Req.
______,
effective
__________)
Section 219.948
Testing
a) When in the opinion of the Agency it is necessary to
conduct testing to demonstrate compliance with Section
219.946 of this Part, the owner or operator of a VOM
emission sourceunit subject to the requirements of this
Subpart shall, at his own expense, conduct such tests
in accordance with the applicable test methods and
procedures specified in Section 219.105 of this Part.
01
L~.0-093L~

528
b)
Nothing in this Section shall limit the authority of
the USEPA pursuant to the Clean Air Act, as amended, to
require testing.
(Source: Amended at
Ill. Req.
______,
effective
___________/
SUBPART PR: MISCELLANEOUS ORGANIC CHEMICAL
MANUFACTURING PROCESSES
Section 219.960
Applicability
a) The requirements of this Subpart shall apply to a
plant’s-source’s miscellaneous organic chemical
manufacturing process emission sources-units which are
not included within any of the source categories
specified in Subparts B, E, F, H, Q, R, S, T~V, X, Y~
or Z or BB of this Part, if the plantsource is subject
to this Subpart. A plantsource is subject to this
Subpart if it contains process emission sources-units,
not regulated by Subparts B, E, F (excluding Section
219.204(1) of this Part), H (excluding Section 219.405
of this Part), Q, R, 5, T (excluding Section 219.486 of
this Part) V, X, Y~or Z or BE of this Part; which as a
group both:
1) hllave maximum theoretical emissions of 91 Mg (100
tons) or more per calendar year of VON if no air
pollution control equipment were used, and
2) a~renot limited to less than 91 Mg (100 tons) of
VON emissions per calendar year in the absence of
air pollution control equipment, through
production or capacity limitations contained in a
federally enforceable construction permit or a SIP
revision.
b) If a plantsource ceases to fulfill the criteria of
Subsection (a) of this Section, the requirements of
this Subpart shall continue to apply to a miscellaneous
organic chemical manufacturing process emission source
unit which was ever subject to the control requirements
of Section 219.966 of this Part.
c) No limits under this Subpart shall apply to emission
sourccsunits with emissions of VOM to the atmosphere
less than or equal to 0.91 Mg (1.0 ton) per calendar
year if the total emissions from such sources emission
units not complying with Section 219.966 of this Part
does not exceed 4.5 Mg (5.0 tons) per calendar year.
d) For the purposes of this Subpart, an emission source
unit shall be considered regulated by a Subpart if it
01140-0935

529
is subject to the limits of that Subpart. An emission
sourceunit is not considered regulated by a Subpart if
it is not subiect to the limits of that
Subpart, e.g.,
the emission unit is covered bY an exemption in the
Subpart or the applicability criteria of the Subpart
are not met. its omissions arc below the applicability
cutoff level or if the source is covered by an
exemption.
e) For the purposes of
this Subpart, uncontrolled VON
emissions are the emissions of
VON which would result
if no air pollution control equipment were used.
(Source: Amended at — Ill. Req.
______,
effective
___________
Section 219.963
Permit Conditions
No person shall violate any condition in a permit when the
condition results in exclusion of the plantsource or an emission
sourccunit from this Subpart.
(Source: Amended at
Ill. Req.
______,
effective
__________)
Section 219.966
Control Requirements
Every owner or operator of an emission s-ourcemiscellaneous
organic chemical manufacturing process emission unit, subject to
this Subpart shall comply with the requirements of subsection (a)
or (b) below.
a) Emission capture and control techniques which achieve
an overall reduction in uncontrolled VON emissions of
at least 81 percent from each emission unit, or
(Board Note: For the purpose of this provision, an
emission unit is any part or activity at a source of a
tYPe that by itself is subject to control requirements
in other Subparts of this Part or 40 CFR 60,
incorporated by reference in Section 219.112, e.g., a
coating line, a printing line, a process unit, a
wastewater system, or other equipment, or is otherwise
any part or activity at a source.)
b) An alternative control plan which has been approved by
the Agency and approved by the USEPA as a SIP revision.
AnY leaks from components sublect to the control
requirements of this 5ub~artshall be sublect to the
following control measures:
fl
Repair any component from which a leak of VOL can
be observed. The repair shall be completed as soon
01140-0936

530
as practicable but no later than 15 days after the
leak is found, unless the leaking component cannot
be repaired until the process unit is shut down,
in which case the leaking component must be
repaired before the unit is restarted.
~j For any leak which cannot be readily repaired
within one hour after detection, the following
records, as set forth in this subsection, shall be
kept. These records shall be maintained by the
owner or operator for a minimum of two years after
the date on which they are made. Copies of the
records shall be made available to the Agency or
USEPA upon verbal or written request.
~j
The name and identification
of the leaking
component
~j. The date and time the leak is detected~
~j The action taken to repair the leak; and
pj The date and time the leak is repaired.
(Source: Amended at — Ill. Req.
______,
effective
___________
Section 219.967
Compliance Schedule
Every owner or operator of an emission s-ourccunit subject to the
control requirements of this Subpart shall comply with the
requirements of this Subpart on and after a date consistent with
Section 219.106 of this Part.
(Source:
Amended at
Ill. Req.
_____,
effective
__________)
Section 219.968
Testing
a) When in the opinion of the Agency it is necessary to
conduct testing to demonstrate compliance with Section
219.966 of this Part,
the owner or operator of a VON
emission sourceunit subject to the requirements of this
Subpart shall, at his own expense, conduct such tests
in accordance with the applicable test methods and
procedures specified in Section 219.105 of this Part.
b)
Nothing in this Section shall limit the authority of
the USEPA pursuant to the Clean Air Act, as amended, to
require testing.
(Source:
Amended at
Ill. Peg.
______,
effective
__________)
SUBPART TT: OTHER EMISSION SOURCES UNITS
01 L~Q-o937

531
Section 219.980
Applicability
a) The requirements of
this Subpart
shall apply to a
plant’s-source’s VOM emission sources-units, which are
not included within any of the source categories
specified in Subparts B, E, F, H, Q, R, S, ~ V, X,
Y,
Z, AA, ~ PP, QQ, or PR of this Part, or are not
exempted from permitting requirements pursuant to 35
Ill. Adm. Code 201.146, if the plantsource is subject
to this Subpart. A plantsource is subject to this
Subpart if it contains process emission sources-units,
not regulated by Subparts B, E, F (excluding Section
219.204(1) of this Part), H (excluding Section 219.405
of this Part), Q, P, 5, T, (excluding Section 218.486
of this Part), V, X, Y or~Z or BE of this Part, which
as a group both:
1) ~Have maximum theoretical emissions of 91 Mg (100
tons) or more per calendar year of VON if no air
pollution control equipment were used, and
2)
a~re not limited to less than 91 Mg (100 tons) of
VON emissions per calendar year in the absence of
air pollution control equipment, through
production or capacity limitations contained in a
federally enforceable construction or operating
permit or a SIP revision.
b) If a plantsource ceases to fulfill the criteria of
subsection (a) of this Section, the requirements of
this Subpart shall continue to apply to an emission
sourceunit which was ever subject to the control
requirements of Section 219.986 of this Part.
c) No limits under this Subpart shall apply to emission
sources-units with emissions of VON to the atmosphere
less than or equal to 2.3 Mg (2.5 tons) per calendar
year if the total emissions from such sources emission
unit not complying with Section 219.986 of this Part
does not exceed 4.5 Mg (5.0 tons) per calendar year.
d) For the purposes of this Subpart, an emission source
unit shall be considered regulated by a Subpart if it
is subject to the limits of that Subpart. An emission
s-ourccunit is not considered regulated by a Subpart if
it is not sublect to the limits of that Subpart, e.g..
the emission unit is covered by an exemption in the
Subpart or the applicability criteria of the Subpart
a~enot met. its emissions are below the applicability
cutoff level or if the source is covered by an
exemption.
o
140-0938

532
e) The control requirements in Subparts ~ QQ, RR-~SS and
TT shall not apply to sewage treatment p1ants-~j
vegetable oil extraction and processing plants,j. coke
ovens (including by—product recovery p1ants)-~-~fuel
combustion sources,-~bakeriesTl barge loading
facilitiesT~ jet engine test cellsT~pharmaceutical
manufacturing production of polystyrene foam insulation
board -(-including storage and extrusion of scrap~where
blowing agent is added to the polystyrene resin at the
plantsource~~ but not including blending and
preliminary expansion of resin prior to molding where a
blowing agent is incorporated into the polystyrene
resin bY the producer of the resinr~production of
polystyrene foam packaging -?not including blending and
preliminary expansion of resin prior to molding where
blowing agent is incorporated into the polystyrene
resin by the Producer of the resin; and storage and
extrusion of scrap where blowing agent is added to the
polystyrene resin at the plantsource)7j. and iron and
steel production.
(Source: Amended at
Ill. Req.
______,
effective
__________/
Section
219.983
Permit Conditions
No person shall violate any condition in a permit when the
condition results in exclusion of the plantsource or an emission
sourceunit from this Subpart.
(Source: Amended at — Ill. Req.
______,
effective
__________
Section 219.986
Control Requirements
Every owner or operator of an emission sourccunit subject to this
Subpart shall comply with the requirements of subsection (a), (b)
or (c) below.
a) Emission capture and control equipment which achieve an
overall reduction in uncontrolled VON emissions of at
least 81 percent from each emission unit, or
(Board Note: For the purpose of this provision, an
emission unit is any part or activity at a source of a
tv~e that by itself is sublect to control requirements
in other Subparts of this Part or 40 CFR 60,
incorporated bY reference in Section 219.112, e.g., a
coating line, a printing line, a process unit, a
wastewater system. or other equipment, or is otherwise
any part or activity at a source.)
b)
For coating lines, the daily-weighted average VOM
content shall not exceed 0.42 kg VOM/l (3.5 lbs
01140-0939

533
VON/gal) of coating (minus water and any compounds
which are specifically exempted from the definition of
VON) as applied during any day. Owners and operators
complying with this Section are not required to comply
with Section 219.301 of this Part, or
c)
An alternative control plan which has been approved by
the Agency and approved by the USEPA as a SIP revision.
~j Non—contact process water cooling towers which are
sublect to the control requirements of this Subpart
shall comply with the following control measures no
later than August 15, 1994 or upon initial startup:
~j The owner or operator of a non—contact process
water cooling tower shall perform the following
actions to control emissions of volatile organic
material (VOM) from such a tower:
~j Inspect and monitor such tower to identify
leaks of VOM into the water, as further
specified in subsection (d) (3) below
~J
When a leak is identified, initiate and carry
out steps to identify the specific leaking
component or components as soon as
practicable,
as further specified in
subsection (d) (4) below.
Qj When a leaking component is identified which:
fl
Can be removed from service without
disrupting production, remove the
component from service
~J,j
Cannot be removed from service without
disrupting production, undertake repair
of the component at the next reasonable
opportunity to
do so including any
period when the component is out of
service for scheduled maintenance, as
further specified in subsection (d) (4)
below
P1
Maintain records of inspection and monitoring
activities,
identification
of leaks and
leaking components, elimination and repair of
leaks, and operation of equipment as related
to these activities, as further specified in
subsection Cd) (5) below.
~j A VON leak shall be considered to exist in a non-
01 140-09~O

534
contact process water cooling water system if the
VON emissions or VON content exceed background
levels as determined by monitoring conducted in.
accordance with subsection (d) (3) (A) below.
,~j The owner or operator of an non—contact process
water cooling tower shall carry out an inspection
and monitoring program to identify VON leaks in
the cooling water system.
~j The owner or operator of a non—contact
process water cooling tower shall submit to
the Agency a proposed monitoring program,
accompanied by technical lustification
for
the program, including lustification for the
sampling location(s) , parameter(s) selected
for measurement, monitoring and inspection
frequency, and the criteria used relative to
the monitored parameters to determine whether
a leak exists as specified in subsection
(d)(2) above.
~j This inspection and monitoring program for
non—contact process water cooling towers
shall include, but shall not be limited to:
j~ Monitoring of each such tower with a
water flow rate of 25,000 gallons per
minute or more at a petroleum refinery
at least weekly and monitoring of other
towers at least monthly
JJJ
Inspection of each such tower at least
weekly if monitoring is not performed at
least weekly.
,~j This inspection and monitoring program shall
be carried out in accordance with written
procedures which the Agency shall specify as
a condition in a federally enforceable
operating permit. These procedures shall
include the VOM background levels f or the
cooling tower as established by the owner or
operator through monitoring; describe the
locations at which samples will be taken;
identify the parameter(s) to be measured, the
frequency of measurements, and the procedures
for monitoring each such tower, that is,
taking of samples and other subsequent
handling and analyzing of samples; provide
the criteria used to determine that a leak
exists as specified in subsection (d) (2)
~fl14fJ-09L4l

535
above; and describe the records which will be
maintained.
j3j A non—contact process water cooling tower is
exempt from the requirements of subsections
(d) (3) (B) and (d) (3) (C) above, if all
equipment, where leaks of VON into cooling
water may occur, is operated at a minimum
pressure in the cooling water of at least 35
kPa greater than the maximum pressure in the
process fluid.
il
The repair of a leak in a non—contact process
water cooling tower shall be considered to be
completed in an acceptable manner as follows:
~ Efforts to identify and locate the leaking
comPonents are initiated as soon as
practicable, but in no event later than three
days after detection of the leak in the
cooling water tower
~j Leaking components shall be repaired or
removed from service as soon as possible but
no later than 30 days after the leak in the
cooling water tower is detected, unless the
leaking components cannot be repaired until
the next scheduled shutdown for maintenance.
~ The owner or operator of a non—contact process
water cooling tower shall keep records as set
forth below in this subsection. These records
shall be retained at a readily accessible location
at the source and shall be available for
inspection and copying bY the A~encvfor at least
3 years:
~ Records of inspection and monitoring
activity
~j Records of each leak identified in such
tower, with date, time and nature of
observation or measured level of Parameter
~ Records of activity to identify leaking
components, with date
initiated, summary of
components inspected with dates, and method
of inspection and observations
P1 Records of activity to remove a leaking
component from service or repair a leaking
component, with date initiated and completed,
01
140-09i~2

536
description of actions taken and the basis
for determining the leak in such tower has
been eliminated. If the leaking component is
not identified, repaired or eliminated within
30 days of initial identification of a leak
in such tower. this report shall include
specific reasons why the leak could not be
eliminated sooner including all other
intervening periods when the process unit was
out of service, actions taken to minimize VON
losses prior to elimination of the leak and
any actions taken to prevent the recurrence
of a leak of this type.
~j The owner or operator of a non—contact process
water cooling tower shall submit an annual report
to the Agency which provides:
~j The number of leaks identified in each
cooling tower
~J.
A general description of activity to
repair
or eliminate leaks which were identified
~j.. Identification of each leak which
was
not
repaired in 30 days from the date of
identification of a leak in such a tower,
with description of the leaks, explanation
why the leak was not repaired in 30 days
P1
Identification
of any periods when required
inspection and monitoring activities
were not
carried out.
~j. Any leaks from components subiect to the control
requirements of this Subpart shall be subiect to the
following control measures:
~j Repair any component from which a leak of VOL can
be observed. The repair shall be completed as soon
as practicable but no later than
15 days after the
leak is found, unless the leaking component cannot
be repaired until the process unit is shut down,
in which case the leaking component must be
repaired before the unit is restarted.
21
For any leak which cannot be readily repaired
within one hour after detection, the following
records, as set forth below in this subsection,
shall be kept. These records shall be maintained
by the owner or operator for a minimum of two
years after the date on which they are made.
01
140-091~3

537
Copies of the records shall be made available to
the Agency or USEPA upon verbal or written
request.
~j The name and identification of the leaking
component
~j The date and time the leak is detected
,çj The action taken to repair the leak; and
P1 The date and time the leak is repaired.
(Source: Amended at — Ill. Req.
______,
effective
__________
Section 219.987
Compliance Schedule
Every owner or operator of an emissions sourceunit which is
subject to this Subpart shall comply with the requirements of
this Subpart on and after a date consistent with Section 219.106
of this Part.
(Source: Amended at
Ill. Req.
______,
effective
___________)
Section 219.988
Testing
a) When in the opinion of the Agency it is necessary to
conduct testing to demonstrate compliance with Section
219.986 of this Part, the owner or operator of a VON
emission sourccunit subject to the requirements of this
Subpart shall, at his own expense, conduct such tests
in accordance with the applicable test methods and
procedures specified in Section 219.105.
b) Nothing in this Section shall limit the authority of
the USEPA pursuant to the Clean Air Act, as amended, to
require testing.
(Source: Amended at
Ill. Req.
______,
effective
___________)
SUBPART UU: RECORDKEEPING AND REPORTING FOR NOfl-CTC SOURCES
Section 219.990
Exempt Emission Sources-Units
Upon request by the Agency, the owner or operator of an emission
unit source which is exempt from the requirements of Subparts PP,
QQ, PR, TT or Section 219.208(b) of this Part shall submit
records to the Agency within 30 calendar days from the date of
the request that document that the emission unit source is exempt
from those requirements.
(Source: Amended at
Ill. Req.
______,
effective
01
L~0-Q9L~~

538
Section 219.991
Subject Emission Sources-Units
a) Any owner or operator of a VON emission sourceunit
which is subject to the requirements of Subpart PP, QQ,
P.R
or TT and complying by the use of emission capture
and control equipment shall comply with the following:
1) By a date consistent with Section 219.106 of this
Part, or upon initial start—up of a new emission
sourceunit, the owner or operator of the subject
VOM emission spurceunit shall demonstrate to the
Agency the that the subject emission sourceunit
will be in compliance on and after a date
consistent with Section 219.106 of this Part, or
on and after the initial start-up date by
submitting to the Agency all calculations and
other supporting data, including descriptions and
results of any tests the owner or operator may
have performed.
2)
On and after a date consistent with Section
219.106 of this Part, or on and after the initial
start—up date, the owner or operator of a subject
VON emission source shall collect and record all
of the following information each day and maintain
the information at the facilitysource for a period
of three years:
A) Control device monitoring data.
B)
A log of operating time for the capture
system, control device, monitoring equipment
and the associated emission source.
C) A maintenance log for the capture system,
control device and monitoring equipment
detailing all routine and non—routine
maintenance performed including dates and
duration of any outages.
3)
On and after a date consistent with Section
219.106 of this Part, the owner or operator of a
subject VON emission source shall notify the
Agency in the following instances:
A) Any record showing a violation of the
requirements of Subpart PP, QQ, PR or TT
shall be reported by sending a copy of such
record to the Agency within 30 days following
the occurrence of the violation.
B) At least 30 calendar days before changing the
01140-09145

539
method of compliance with Subpart PP or TT
from the use of capture systems and control
devices to the use of complying coatings, the
owner or operator shall comply with all
requirements of subsection (b) (1) of this
Section. Upon changing the method of
compliance with Subpart PP or TT from the use
of capture systems and control devices to the
use of complying coatings, the owner or
operator shall comply with all requirements
of subsection (b) of this Section.
4) A) When in the opinion of the Agency it is
necessary to conduct testing to demonstrate
compliance with this Subpart, the owner or
operator of a VON emission source subject to
the requirements of this Subpart shall, at
his own expense, conduct such tests in
accordance with the applicable test methods
and procedures specified in Section 219.105
of this Part.
B) Nothing in this Section shall limit the
authority of the USEPA pursuant to the Clean
Air Act, as amended, to require testing.
b) Any owner or operator of a coating line which is
subject to the requirements of Subpart PP or TT and
complying by means of the daily-weighted average VOM
content limitation shall comply with the following:
1) By a date consistent with Section 219.106 of this
Part, or upon initial start-up of a coating line
subject to Subpart PP or TT, the owner or operator
of the subject coating line shall certify to the
Agency that the coating line will be in compliance
on and after a date consistent with Section
219.106 of this Part, or on and after the initial
start-up date. Such certification shall include:
A)
The name and identification
number of each
coating line which will comply by means of
the daily-weighted average VON content
limitation.
B) The name and identification number of each
coating as applied on each coating line.
C) The weight of VON per volume and the volume
of each coating (minus water and any
compounds which are specifically
exempted
from the definition of VON) as applied each
01140-09146

540
day on each coating line.
D) The instrument or method by which the owner
or operator will accurately measure or
calculate the volume of each coating as
applied each day on each coating line.
E) The method by which the owner or operator
will create and maintain records each day as
required in subsection (b) (2).
F) An example of the format in which the records
required in subsection (b) (2) of this Section
will be kept.
2) On and after a date consistent with Section
219.106 of this Part, or on and after the initial
start—up date, the owner or operator of a subject
coating line shall collect and record all of the
following information each day for each coating
line and maintain the information at the
facilitysource for a period of three years:
A) The name and identification number of each
coating as applied on each coating line.
B) The weight of VON per volume and the volume
of each coating (minus water and any
compounds which are specifically
exempted
from the definition of VON) as applied each
day on each coating line.
C) The daily-weighted average VON content of all
coatings as applied on each coating line as
defined in Section 219.104 of this Part.
3) On and after a date consistent with Section
219.106 of this Part, the owner or operator of a
subject coating line shall notify the Agency in
the following instances:
A) Any record showing violation of the
requirements of Subpart PP or TT shall be
reported by sending a copy of such record to
the Agency within 30 days following the
occurrence of the violation.
B)
At least 30 calendar days before changing the
method of compliance with Subpart PP or TT
from the use of complying coatings to the use
capture systems and control devices, the
owner or operator shall comply with all
01140-09147

541
requirements of subsection (a) (1) of this
Section. Upon changing the method of
compliance with Subpart PP or TT from the use
of complying coatings to the use capture
systems and control devices, the owner or
operator shall comply with all requirements
of subsection (a) of this Section.
c)
Any owner or operator of a VON emission source which is
subject to the requirements of Subpart PP, QQ, PR or TT
and complying by means of an alternative control plan
which has been approved by the Agency and approved by
the USEPA as a SIP revision shall comply with the
recordkeeping and reporting requirements specified in
the alternative control plan.
(Source: Amended at — Ill. Peg.
______,
effective
a 140-09149

542
Section 219.APPENDIX A
LIST OF CHEMICALS DEFINING SYNTHETIC ORGANIC CHEMICAL AND
POLYMER MANUFACTURING
CAS No. a
Chemical
105—57—7
Acetal
75-07-0
Acetaldehyde
107—89-1
Acetaldol
60-35-5
Acetamide
103-84—4
Acetanilide
64-19-7
Acetic acid
108-24-7
Acetic anhydride
67-64-1
Acetone
75-86-5
Acetone cyanohydrin
75-05-8
Acetonitrile
98-86-2
Acetophenone
75-36-5
Acetyl chloride
74-86-2
Acetylene
107—02—8
Acrolein
79—06-1
Acrylamide
79—10-7
Acrylic acid & esters
107-13—1
Acrylonitrile
124—04—9
Adipic acid
111-69—3
Adiponitrile
(b)
Alkyl naphthalenes
107—18—6
Allyl alcohol
107—05—1
Allyl chloride
1321-11-5
Aminobenzoic acid
111-41—1
Aminoethylethanolamine
123-30-8
p-aminophenol
628—63—7,
Amyl acetates
123—92—2
7l~.4l~Oc
Amyl alcohols
110-58—7
Amyl amine
543—59-9
Amyl chloride
Amyl mercaptans
1322—06-1
Amyl phenol
62—53—3
Aniline
142-04—1
Aniline hydrochloride
29191—52—4
Anisidine
100—66—3
Anisole
118-92-3
Anthranilic acid
84-65-1
Anthraquinone
100—52—7
Benzaldehyde
55—21—0
Benzamide
71—43—2
Benzene
98—48-6
Benzenedisulfonic
acid
98—11-3
Benzenesulfonic acid
134—81—6
Benzil
76—93—7
Benzilic acid
65—85—0
Benzoic acid
0 140-09149

543
119—53—9
Benzoin
100—47—0
Benzonitrile
119—61-9
Benzophenone
98-07-7
Benzotrichloride
98—88—4
Benzoyl chloride
100-51—6
Benzyl alcohol
100-46—9
Benzylamine
120-51—4
Benzyl benzoate
100-44—7
Benzyl chloride
98-87-3
Benzyl dichloride
92—52-4
Biphenyl
80-05—7
Bisphenol A
10-86-1
Bromobenzene
27497-51-4
Bromonaphthalene
106-99-0
Butadiene
106—98-9
1-butene
123-86-4
n-butyl acetate
141-32—2
n—butyl acrylate
71-36-3
n-butyl alcohol
78-92—2
s-butyl alcohol
75—65—0
t—butyl alcohol
109-73-9
n-butylamine
13952—84—6
s—butylamine
75—64—9
t—butylamine
98—73—7
p—tert—butyl benzoic acid
107—88—0
1,3—butylene glycol
123—72-8
n—butyraldehyde
107-92-6
Butyric acid
106-31-0
Butyric anhydride
109-74-0
Butyronitrile
105-60-2
Caprolactam
75—1—50
Carbon disulfide
558-13—4
Carbon tetrabromide
55-23-5
Carbon tetrachloride
9004—35-7
Cellulose acetate
79—11-8
Chloroacetic acid
108—42—9
xn-chloroaniline
95-51—2
o-chloroaniline
106-47—8
p-chloroaniline
35913-09—8
Chlorobenzaldehyde
108-90-7
Chlorobenzene
118—91—2,
Chlorobenzoic acid
535—80—8,
74—11—3c
2136—81-4,
Chlorobenzotrichloride
2136—89—2,
5216—2 S_ic
1321—03-5
Chlorobenzoyl chloride
75-45—6
Chlorodifluoroethane
25497-29—4
Chlorodifluoromethane
67-66—3
Chloroform
25586—43—0
Chloronaphthalene
0 140-0950

544
88—73—3
o—chloronitrobenzene
100-00-5
p-chloronitrobenzene
25167-80-0
Chlorophenols
126-99-8
Chloroprene
7790-94-5
Chlorosulfonic acid
108-41-8
m-chlorotoluene
95-49-8
o-chlorotoluene
106-43-4
p-chlorotoluene
75-72-9
Chlorotrifluoromethane
108-39—4
m—cresol
95-48—7
o—cresol
106—44-5
p—cresol
1319-77-3
Mixed cresols
1319—77—3
Cresylic acid
4170-30-0
Crotonaldehyde
3724—65-0
Crontonic acid
98-82-8
Cumene
80-15-9
Cumene hydroperoxide
372-09-8
Cyanoacetic acid
506-77-4
Cyanogen chloride
108-80-5
Cyanuric acid
108-77-0
Cyanuric chloride
110-82-7
Cyclohexane
108-93-0
Cyclohexanol
108-94-1
Cyclohexanone
110-83—8
Cyclohexene
108-91-8
Cyclohexylamine
111-78-4
Cyclooctadiene
112—30—1
Decanol
123-42—2
Diacetone alcohol
27576-04-1
Diaminobenzoic acid
95-76-1,
Dichloroaniline
9 5—82—9,
554—00—7,
608—27—5,
608—31—1,
626—43—7,
27134—27—6,
541-73-1
m-dichlorobenzene
95-50-1
o-dichlorobenzene
106-46-7
p-dichlorobenzene
75-71-8
Dichlorodifluoromethane
111-44-4
Dichloroethyl ether
107—06—2
1, 2—dichioroethane
(EDC)
96-23-1
Dichlorohydrin
26952-23-8
Dichloropropene
101-83-7
Dicyclohexylamine
109-89-7
Diethylamine
111-46-6
Diethylene glycol
112-36-7
Diethylene glycol diethyl
ether
01400951

545
111-96-6
Diethylene glycol dimethyl
ether
112-34-5
Diethylene glycol monobutyl
ether
124-17-7
Diethylene glycol mononbutyl
ether acetate
111-90-0
Diethylene glycol monoethyl
ether
112-15-2
Diethylene glycol monoethyl
ether acetate
111-77-3
Diethylene glycol monoraethyl
ether
64-67—S
Diethyl sulfate
75-37—6
Difluoroethane
25167—70-8
Diisobutylene
26761—40-0
Diisodecyl
phthalate
27554—26-3
Diisooctyl phthalate
674—82-8
Diketene
124-40-3
Dimethylamine
121-69-7
N,N-dimethylaniline
115-10-6
N,N-dimethyl ether
68-12-2
N, N-dimethylformamide
57-14-7
Dimethylhydrazine
77-78—1
Dimethyl sulfate
75—18—3
Dimethyl sulfide
67-68-5
Dimethyl sulfoxide
120-61-6
Dimethyl terephthalate
99-34—3
3,5-dinitrobenzoic
acid
51-28—5
Dinitrophenol
Dinitrotolyene
123—91-1
Dioxane
646—06-0
Dioxilane
122—39-4
Diphenylamine
101—84-4
Diphenyl oxide
102—08-9
Diphenyl thiourea
25265—71-8
Dipropylene glycol
25378—22-7
Dodecene
28675—17—4
Dodecylaniline
27193—86-8
Dodecylphenol
106—89-8
Epichlorohydrin
64—17—5
Ethanol
14143sc
Ethanolamines
141—78-6
Ethyl acetate
14 1—97-9
Ethyl acetoacetate
14 0—88-5
Ethyl acrylate
75-04—7
Ethylamine
100—41-4
Ethylbenzene
74-96-4
Ethyl bromide
9004-57—3
Ethylcellulose
75-00—3
Ethyl chloride
105-39-5
Ethyl chioroacetate
105-56-6
Ethylcyanoacetate
0
L~.0-0952

546
74-85-1
Ethylene
96-49—1
Ethylene carbonate
107-07—3
Ethylene chlorohydrin
107-15-3
Ethylenediamine
106-93-4
Ethylene dibromide
107-21-1
Ethylene qlycol
111-55—7
Ethylene glycol diacetate
110-71-4
Ethylene glycol dimethyl ether
111-76-2
Ethylene glycol monobutyl
ether
112-07-2
Ethylene glycol monobutyl
ether acetate
110-80—5
Ethylene glycol monoethyl
ether
111-15-9
Ethylene glycol monoethyl
ether acetate
109-86-4
Ethylene glycol monoethyl
ether
110-49-6
Ethylene glycol monomethyl
ether acetate
122-99-6
Ethylene glycol monophenyl
ether
2807-30-9
Ethylene glycol monopropyi
ether
75-21-8
Ethylene oxide
60-29-7
Ethyl ether
104-76-7
2-ethylhexanol
122-51-0
Ethyl orthoformate
95-92-1
Ethyl oxalate
41892-71-1
Ethyl sodium oxaloacetate
50-00-0
Formaldehyde
75-12—7
Formamide
64-18-6
Formic acid
110-17—8
Fumaric acid
98-01-1
Furfural
56-81-5
Glycerol (Synthetic)
26545-73-7
Glycerol dichlorohydrin
25791-96-2
Glycerol triether
56—40—6
Glycine
107—22—2
Glyoxal
118-74-1
Hexachlorobenzene
67-72-1
Hexachloroethane
36653-82-4
Hexadecyl alcohol
124-09-4
Hexamethylenediamine
629-11-8
Hexamethylene glycol
100-97-0
Hexamethylenetetramine
74-90-8
Hydrogen cyanide
123-31-9
Hydroquinone
99-96-7
p-hydroxybenzoic acid
26760—64—S
Isoamylene
78-83-1
Isobutanol
110-19-0
Isobutyl acetate
01140-0953

547
l15117
Isobutylene
78-84-2
Isobutyraldehyde
79-31-2
Isobutyric acid
25339—17-7
Isodecanol
26952—21—6
Isooctyl alcohol
78-78—4
Isopentane
78-59—1
Isophorone
121—91-5
Isophthalic acid
78—79—5
Isoprene
67-63—0
Isopropanol
108-21-4
Isopropyl acetate
75-31-0
Isopropylamine
75-29-6
Isopropyl chloride
25168—06-3
Isopropylphenol
463-51-4
Ketene
(b)
Linear alkyl sulfonate*
123-01—3
Linear alkylbenzene
110—16—7
Maleic acid
108-31-6
Maleic anhydride
6915—15—7
Malic acid
141-79-7
Mesityl oxide
121-47-1
Metanilic acid
79-41—4
Methacrylic acid
563—47-3
Methallyl chloride
67-56-1
Methanol
79-20-9
Methyl acetate
105-45-3
Methyl acetoacetate
74-89—5
Methylamine
100-61—8
n—methylaniline
74-83-9
Methyl bromide
37365-71-2
Methyl butynol
74-87-3
Methyl chloride
108-87-2
Methyl cyclohexane
1331-22-2
Methyl cyclohexanone
75-09-2
Methylene chloride
101-77—9
Methylene dianiline
101-68-8
Methylene diphenyl
diisocyanate
78-93-3
Methyl ethyl ketone
107-31-3
Methyl formate
108—11-2
Methyl isobutyl carbinol
108-10-1
Methyl isobutyl ketone
80-62-6
Methyl methacrylate
77-75-8
Nethylpentynol
98-83-9
B-methylstyrene
110-91-8
Morpholine
85-47—2
a—naphthalene sulfonic acid
120-18-3
B—naphthaiene sulfonic acid
90-15-3
a—naphthol
135-19—3
B-naphthol
75-98-9
Neopentanoic acid
88-74-4
o-nitroaniline
01140-09514

548
100-01-6
p-nitroaniline
91-23-6
o-nitroanisole
100-17-4
p-nitroanisole
98-95-3
Nitrobenzene
Nitrobenzoic acid (0, m & p)
79—24-3
Nitroethane
75-52-S
Nitromethane
88-75-S
Nitrophenol
25322-01-4
Nitropropane
1321-12-6
Nitrotoluene
27215—95—8
Nonene
25154-52-3
Nonylphenol
27193-28-8
Octylphenol
123-63-7
Paraldehyde
115-77-S
Pentaerythritol
109—66-0
n-pentane
109—67-1
l—pentene
127-18-4
Perchloroethylene
594-42-3
Perchloromethyl mercaptan
94-70-2
o-phenetidine
156-43-4
p-phenetidine
108—95—2
Phenol
98—67-9,
Phenolsulfonic acids
585—38—6,
609—46—1,
91-40-7
Phenyl anthranilic acid
(b)
Phenylenediamine
75-44-5
Phosgene
85-44-9
Phthalic anhydride
85-41-6
Phthalimide
108-99-6
b-picoline
110—85—0
Piperazine
9003-29-6,
Polybutenes
25322-68-3
Polyethylene glycol
25322-69-4
Polypropylene glycol
123-38-6
Propionaldehyde
79-09-4
Propionic acid
71-23-8
n-propyl alcohol
107-10-8
Propylamine
540-54-5
Propyl chloride
115-07-1
Propylene
127-00-4
Propylene chlorohydrin
78-87-5
Propylene dichloride
57-55-6
Propylene qlycol
75-S6-9
Propylene oxide
110861
Pyridine
106-51-4
Quinone
108—46—3
Resorcinol
27138-S7-4
Resorcylic acid
69-72-7
Salicylic acid
01140-0955

549
127-09-3
Sodium acetate
532-32-1
Sodium benzoate
9004-32-4
Sodium carboxymethyl cellulose
3926-62-3
Sodium chloroacetate
141—53—7
Sodium formate
139-02-6
Sodium phenate
110-44—1
Sorbic acid
100-42—5
Styrene
110—15—6
Succinic acid
110—61—2
Succinitrile
121—57—3
Sulfanilic acid
126—33—0
Sulfolane
1401—55-4
Tannic acid
100—21-0
Terephthaiic acid
Tetrachloroethanes
117-08-8
Tetrachlorophthalic anhydride
78-00-2
Tetraethyllead
119-64-2
Tetrahydronaphthalene
85-43-8
Tetrahydrophthalic anhydride
75-74-1
Tetramethyllead
110-60-1
Tetramethylenediamine
110-18-9
Tetramethylethylenediamine
108-88—3
Toluene
95—80-7
Toluene-2
, 4—diamine
584-84-9
Toluene-2, 4—diisocyanate
26471-62-S
Toluene diisocyanates
(mixture)
1333-07-9
Toluene sulfonamide
Toluenesulfonic acids
98—59-9
Toluene sulfonyl chloride
26915—12—8
Toluidines
87—61-6,
Trichlorobenzenes
108—70—3,
l2O—82—lc
71-55-6
1,1, l-trichloroethane
79-00-S
1,1, 2—trichloroethane
79-01-6
Trichloroethylene
75-69-4
Trichlorofluoromethane
9 6-18—4
1,2, 3—trichloropropane
76—13—1
1,1, 2—trichloro—l, 2, 2—trifluor
oethane
121-44-8
Triethylamine
112-27—6
Triethylene glycol
112-49-2
Triethylene glycoldimethyl
ether
7756—94—7
Triisobutylene
75-50-3
Trimethylamine
57—13—6
Urea
108-05—4
Vinyl acetate
75—01-4
Vinyl chloride
75-35-4
Vinylidene chloride
25013—15-4
Vinyl toluene
(flL~0-Qg56

550
1330-20-7
Xylenes (mixed)
95—47—6
o—xylene
106—42—3
p—xylene
1300—71—6
Xylenol
1300—73—8
Xylidine
(b)
methyl tert-butyl ether
9002-88-4
Polyethylene
(b)
Polypropylene
9009-53-6
Polystyrene
a) CAS numbers refer to the Chemical Abstracts Peqistery
numbers assigned to specific chemicals, isomers or
mixtures of chemicals. Some isomers or mixtures that
are covered by the standards do not have CAS numbers
assigned to them. The standards apply to all of the
chemicals listed, whether CAS numbers have been
assigned or not.
b) No CAS number(s) have been assigned to this chemical,
to its isomers, or mixtures containing these chemicals.
c) CAS numbers for some of the isomers are listed: the
standards apply to all of the isomers and mixtures,
even if CAS numbers have not been assigned.
(Source: Amended at
Ill. Peg.
______,
effective
_________
0 140-0957

551
Section 219.APPENDIX B
VOM MEASUREMENT TECHNIQUES FOP CAPTURE EFFICIENCY
Procedure G.1 - Captured VOQ~JEmissions
1. INTRODUCTION
1.1 Applicability. This procedure is applicable for determining
the volatile organic compounds-materials (VOGIj) content of
captured gas streams. It is intended to be used as a segment in
the development of liquid/gas or gas/gas protocols for
determining VO~jcapture efficiency (CE) for surface coating and
printing operations. The procedure may not be acceptable in
certain site-specific situations, e.g., when: (1) direct fired
heaters or other circumstances affect the quantity of VO~ at the
control device inlet; and (2) particulate organic aerosols are
formed in the process and are present in the captured emissions.
1.2 Principle. The amount of VO~ captured (G) is calculated as
the sum of the products of the VO~Jcontent (CGj), the flow rate
and the sample time (Tc) from each captured emissions
point.
1.3 Estimated Measurement Uncertainty. The measurement
uncertainties are estimated for each captured or fugitive
emissions point as follows: QGj 5.5 percent and
CGj
=
±5.0percent. Based on these numbers, the probable
uncertainty for G is estimated at about ±7~4percent.
1.4 Sampling Requirements. A capture efficiency test shall
consist of at least three sampling runs. The sampling time for
each run should be at least 8 hours, unless otherwise approved.
1.5 Notes. Because this procedure is often applied in highly
explosive areas, caution and care should be exercised in choosing
appropriate equipment and installing and using the equipment.
Mention of trade names or company products does not constitute
endorsement. All gas concentrations (percent, ppm) are by
volume, unless otherwise noted.
2. APPARATUS
AND REAGENTS
2.1 Gas VOGM Concentration. A schematic of the measurement
system is shown in Figure 1. The main components are described
below:
2.1.1 Sample Probe. Stainless steel, or equivalent. The probe
shall be heated to prevent VOGM condensation.
2.1.2 Calibration Valve Assembly. Three-way valve assembly at
the outlet of sample probe to direct the zero and calibration
gases to the analyzer.
Other methods, such as quick—connect
o
1400958

552
lines, to route calibration gases to the outlet of the sample
probe are acceptable.
2.1.3 Sample Line. Stainless steel or Teflon tubing to
transport the sample gas to the analyzer. The sample line must
be heated to prevent condensation.
2.1.4 Sample Pump. A leak-free pump, to pull the sample gas
through the system at a flow rate sufficient to minimize the
response time of the measurement system. The components of the
pump that contact the gas stream shall be constructed of
stainless steel or Teflon. The sample pump must be heated to
prevent condensation.
2.1.5 Sample Flow Rate Control. A sample flow rate control
valve and rotameter, or equivalent, to maintain a constant
sampling rate within 10 percent. The flow rate control valve and
rotameter must be heated to prevent condensation. A control
valve may also be located on the sample pump bypass loop to
assist in controlling the sample pressure and flow rate.
2.1.6 Sample Gas Manifold. Capable of diverting a portion of
the sample gas stream to the flame ionization analyzer (FIA), and
the remainder to the bypass discharge vent. The manifold
components shall be constructed of stainless steel or Teflon. If
captured or fugitive emissions are to be measured at multiple
locations, the measurement system shall be designed to use
separate sampling probes, lines, and pumps for each measurement
location and a common sample gas manifold and FIA. The sample
gas manifold and connecting lines to the FIA must be heated to
prevent condensation.
2.1.7 Organic Concentration Analyzer. An FIA with a span value
of 1.5 times the expected concentration as propane; however,
other span values may be used if it can be demonstrated that they
would provide more accurate measurements. The system shall be
capable of meeting or exceeding the following specifications:
2.1.7.1 Zero Drift. Less than ±3.0percent of the span value.
2.1.7.2 Calibration Drift. Less than ±3.0percent of the span
value.
2.1.7.3 Calibration Error. Less than ±5.0percent of the
calibration gas value.
2.1.7.4 Response Time. Less than 30 seconds.
2.1.8 Integrator/Data Acquisition System. An analog or digital
device or computerized data acquisition system used to integrate
the FIA response or compute the average response and record
measurement data.
The minimum data sampling frequency for
01140-0959

553
computing average or integrated values is one measurement value
every 5 seconds. The device shall be capable of recording
average values at least once per minute.
2.1.9 Calibration and Other Gases. Gases used for calibration,
fuel, and combustion air (if required) are contained in
compressed gas cylinders. All calibration gases shall be
traceable to NIST standards and shall be certified by the
manufacturer to ±1percent of the tag value. Additionally, the
manufacturer of the cylinder should provide a recommended shelf
life for each calibration gas cylinder over which the
concentration does not change more than ±2percent from the
certified value. For calibration gas values not generally
available, alternative methods for preparing calibration gas
mixtures, such as dilution systems, may be used with prior
approval.
2.1.9.1 Fuel. A 40 percent H2/60 percent He or 40 percent H2/60
percent N2 gas mixture is recommended to avoid an oxygen
synergism effect that reportedly occurs when oxygen concentration
varies significantly from a mean value.
2.1.9.2 Carrier Gas. High purity air with less than 1 ppm of
organic material (as propane or carbon equivalent) or less than
0.1 percent of the span value, whichever is greater.
2.1.9.3 FIA Linearity Calibration Gases. Low—, mid-, and
high—range gas mixture standards with nominal propane
concentrations of 20—30, 45-55, and 70-80 percent of the span
value in air, respectively.
Other calibration values and other
span values may be used if it can be shown that more accurate
measurements would be achieved.
2.1.10 Particulate Filter. An in-stack or an out-of—stack glass
fiber filter is recommended if exhaust gas particulate loading is
significant. An out-of—stack filter must be heated to prevent
any condensation unless
it can be demonstrated that no
condensation occurs.
2.2 Captured Emissions Volumetric Flow Pate.
2.2.1 Method 2 or 2A Apparatus. For determining volumetric flow
rate.
2.2.2 Method 3 Apparatus and Reagents. For determining
molecular weight of the gas stream. An estimate of the molecular
weight of the gas stream may be used if it can be justified.
2.2.3
Method 4 Apparatus and Reagents.
For determining moisture
content, if necessary.
3.
DETERMINATION OF VOLUMETRIC FLOW
RATE
OF CAPTURED EMISSIONS
01140 0960

554
3.1 Locate all points where emissions are captured from the
affected facilityemission
unit.
Using Method 1, determine the
sampling points. Be sure to check each site for cyclonic or
swirling flow.
3.2 Measure the velocity at each sampling site at least once
every hour during each sampling run using Method 2 or 2A.
4.
DETERMINATION OF VOGM CONTENT OF CAPTURED EMISSIONS
4.1 Analysis Duration. Measure the VO?~jresponses at each
captured emissions point during the entire test run or, if
applicable, while the process is operating. If there are
multiple captured emission locations, design a sampling system to
allow a single FIA to be used to determine the VO~ responses at
all sampling locations.
4.2 Gas VOGM Concentration.
4.2.1 Assemble the sample train as shown in Figure 1. Calibrate
the FIA according to the procedure in Section 5.1.
4.2.2 Conduct a system check according to the procedure in
Section 5.3.
4.2.3 Install the sample probe so that the probe is centrally
located in the stack, pipe, or duct, and is sealed tightly at the
stack port connection.
4.2.4 Inject zero gas at the calibration valve assembly. Allow
the measurement system response to reach zero. Measure the
system response time as the time required for the system to reach
the effluent concentration after the calibration valve has been
returned to the effluent sampling position.
4.2.5 Conduct a system check before and a system drift check
after each sampling
run according to the procedures in Sections
5.2 and 5.3. If the drift
check following a run indicates
unacceptable performance, the run is not valid. The tester may
elect to perform system drift checks during the run not to exceed
one drift check per hour.
4.2.6
Verify that the sample lines, filter,
and pump
temperatures are 120 ±5°C.
4.2.7 Begin sampling at the start of the test period and
continue to sample during the entire run.
Record the starting
and ending times and any required process information as
appropriate. If multiple
captured emission locations are sampled
using a single FIA, sample at each location for the same amount
of time (e.g., 2 minutes) and continue to switch from one
location to another for the entire test run. Be sure that total
01140-0961

555
sampling time at each location is the same at the end of the test
run. Collect at least 4 separate measurements from each sample
point during each hour of testing. Disregard the measurements at
each sampling location until two times the response time of the
measurement system has elapsed. Continue sampling for at least 1
minute and record the concentration measurements.
4.3 Background Concentration.
4.3.1 Locate all NDO’s of the TTE. A sampling point shall be
centrally located outside of the TTE at 4 equivalent diameters
from each NDO, if possible. If there are more than 6 NDO’s,
choose 6 sampling points evenly spaced among the NDO’s.
4.3.2 Assemble the sample train as shown in Figure 2. Calibrate
the FIA and conduct a system check according to the procedures in
Sections 5.1 and 5.3. NOTE: This sample train shall be a
separate sampling train from the one to measure the captured
emissions.
4.3.3 Position the probe at the sampling location.
4.3.4 Determine the response time, conduct the system check and
sample according to the procedures described in Sections 4.2.4 to
4.2.7.
4.4 Alternative Procedure. The direct interface sampling and
analysis procedure described in Section 7.2 of Method 18 may be
used to determine the
gas
voq~
concentration. The system must be designed to collect
and analyze at least one sample every 10 minutes.
5. CALIBRATION AND QUALITY ASSURANCE
5.1 FIA Calibration and Linearity Check. Make necessary
adjustments to the air and fuel supplies for the FIA and ignite
the burner. Allow the FIA to warm up for the period recommended
by the manufacturer. Inject a calibration gas into the
measurement system and adjust the back—pressure regulator to the
value required to achieve the flow rates specified by the
manufacturer. Inject the zero— and the high—range calibration
gases and adjust the analyzer calibration to provide the proper
responses. Inject the low— and mid—range gases and record the
responses of the measurement system.
The calibration and
linearity of the system are acceptable if the responses for
all
four gases are within 5 percent of the respective gas
values. If
the performance of the system is not acceptable, repair or adjust
the system and repeat the linearity check. Conduct a calibration
and linearity check after assembling the
analysis system and
after a major change is made to the system.
5.2 Systems Drift Checks. Select the calibration gas that most
01140-0962

556
closely approximates the concentration of the captured emissions
for conducting the drift checks. Introduce the zero and
calibration gas at the calibration valve assembly and verify that
the appropriate gas flow rate and pressure are present at the
FIA. Record the measurement system responses to the zero and
calibration gases. The performance of the system is acceptable
if the difference between the drift check measurement and the
value obtained in Section 5.1 is less than 3 percent of the span
value. Conduct the system drift checks at the end of each run.
5.3 System Check. Inject the high range calibration gas at the
inlet of the sampling probe and record the response. The
performance of the system is acceptable if the measurement system
response is within 5 percent of the value obtained in Section 5.1
for the high range calibration gas. Conduct a system check
before and after each test run.
5.4 Analysis Audit. Immediately before each test analyze an
audit cylinder as described in Section 5.2. The analysis audit
must agree with the audit cylinder concentration within 10
percent.
6. NOMENCLATURE
=
area of
NDO i,
ft2-rj
AN
=
total area of all NDO’s in the enclosure,
ft2-rj
C51
=
corrected average VOCN concentration of background
emissions at point i, ppm propane--j
C8
=
average background concentration,
ppm propane--j..
=
corrected average \TOCM concentration of captured
emissions at point j,
ppm propane-~j
=
average measured concentration for the drift check
calibration gas, ppm propane--j.
CDO
=
average system drift check concentration for zero
concentration gas, ppm propane~-j
CH
=
actual concentration of the drift check
calibration gas, ppm propane--;
C1
=
uncorrected average background VOC~concentration
measured at point i, ppm propane-u.
C~
=
uncorrected average VOC~concentration measured at
point j, ppm propane-~
G
=
total VOC~ content of captured emissions, kg--j.
01140-0963

557
K1
=
1.830 x l06 kg/(m3-ppm)--j
n
=
number of measurement points~-j.
=
average effluent volumetric flow rate corrected to
standard conditions at captured emissions point j,
m3 /min~-~
Tc
=
total duration of captured emissions sampling run,
mm.
7. CALCULATIONS
7.1 Total VOGI~Captured Emissions.
n
G
E (C0~
- C8
)
~ Tc K1
Eq. 1
j=1
7.2 VO~ Concentration of the Captured Emissions at Point j.
=
(C~
-
C00)
Eq. 2
7.3 Background VOG~ConcentrationCDH
— C00
at Point i.
CBI (C1 - CDO)
CH
Eq. 3
7.4 Average Background
CDHConcentration.
C00
n
E C3~A~
CB
=
i-i
Eq. 4
nAN
NOTE: If the concentration at each point is within 20 percent of
the average concentration of all points, the terms “A11’ and “AN”
may be deleted from Equation 4.
Procedure G.2 - Captured VO~jEmissions (Dilution Technique)
1. INTRODUCTION
1.1 Applicability. This procedure is applicable for determining
the volatile organic compounds-materials (VOG~) content of
captured gas streams. It is intended to be used as a segment in
the development of a gas/gas protocol in which fugitive emissions
are measured for determining VO~ capture efficiency
(CE) for surface coating and printing operations. A dilution
system is used to reduce the VOGN concentration of the captured
01140-09614

558
emission to about the same concentration as the fugitive
emissions. The procedure may not be acceptable in certain
site—specific situations, e.g., when: (1) direct fired heaters or
other circumstances affect the quantity of VOGI’~ at the control
device inlet; and (2) particulate organic aerosols are formed in
the process and are present in the captured emissions.
1.2 Principle. The amount of VOG~captured (G) is calculated as
the sum of the products of the VOG~content (CGj), the flow rate
and the sampling time (Tc) from each captured emissions
point.
1.3 Estimated Measurement Uncertainty. The measurement
uncertainties are estimated for each captured or fugitive
emissions point as follows: QGj
=
±5.5
percent and CGj
=
±5
percent. Based on these numbers, the probable uncertainty for G
is estimated at about ±7.4 percent.
1.4 Sampling Requirements. A capture efficiency test shall
consist of at least three sampling runs. The sampling time for
each run should be at least 8 hours, unless otherwise approved.
1.5 Notes. Because this procedure is often applied in highly
explosive areas, caution and care should be exercised in choosing
appropriate equipment and installing and using the equipment.
Mention of trade names
or company products does not constitute
endorsement. All gas concentrations (percent, ppm) are by
volume, unless otherwise noted.
2.
APPARATUS AND REAGENTS
2.1 Gas VOGM Concentration. A schematic of the measurement
system is shown in Figure 1. The main components are described
below:
2.1.1 Dilution System. A Kipp in-stack dilution probe and
controller or similar device may be used. The dilution rate may
be changed by substituting different critical orifices or
adjustments of the aspirator supply pressure. The dilution
system shall be heated to prevent VOG~condensation. Note: An
out-of-stack dilution device may be used.
2.1.2 Calibration Valve Assembly. Three-way valve assembly at
the outlet of sample probe to direct the zero and calibration
gases to the analyzer.
Other methods, such as quick—connect
lines, to route calibration gases to the outlet of the sample
probe are acceptable.
2.1.3 Sample Line. Stainless steel or Teflon tubing to
transport the sample gas to the analyzer. The sample line must
be heated to prevent condensation.
0!
140-0955

559
2.1.4 Sample Pump. A leak-free pump, to pull the sample gas
through the system at a flow rate sufficient to minimize the
response time of the measurement system. The components of the
pump that contact the gas stream shall be constructed of
stainless steel or Teflon. The sample pump must be heated to
prevent condensation.
2.1.5 Sample Flow Rate Control. A sample flow rate control
valve and rotameter, or equivalent, to maintain a constant
sampling rate within 10 percent. The flow control valve and
rotameter must be heated to prevent condensation. A control
valve may also be located on the sample pump bypass loop to
assist in controlling the sample pressure and flow rate.
2.1.6 Sample Gas Manifold. Capable of diverting a portion of
the sample gas stream to the flame ionization analyzer (FIA), and
the remainder to the bypass discharge vent. The manifold
components shall be constructed of stainless steel or Teflon. If
captured or fugitive emissions are to be measured at multiple
locations, the measurement system shall be designed to use
separate sampling probes, lines, and pumps for each measurement
location and a common sample gas manifold and FIA.
The sample
gas manifold and connecting lines to the FIA must be heated to
prevent condensation.
2.1.7 Organic Concentration Analyzer. An FIA with a span value
of 1.5 times the expected concentration as propane; however,
other span values may be used if it can be demonstrated that they
would provide more accurate measurements.
The system shall be
capable of meeting or exceeding the following specifications:
2.1.7.1 Zero Drift. Less than ±3.0percent of the span value.
2.1.7.2 Calibration Drift. Less than ±3.0 percent of the span
value.
2.1.7.3 Calibration Error. Less than ±5.0 percent of the
calibration gas value.
2.1.7.4 Response Time. Less than 30 seconds.
2.1.8 Integrator/Data Acquisition System. An analog or digital
device or computerized
data acquisition system used to integrate
the FIA response or compute the average response and record
measurement data. The minimum data sampling frequency for
computing average or integrated values is one measurement value
every 5 seconds.
The device shall be capable of recording
average values at least once per minute.
2.1.9 Calibration and Other Gases. Gases used for calibration,
fuel, and combustion air (if required) are contained in
compressed gas cylinders. All calibration gases shall be
01140-0966

560
traceable to MIST standards and shall be certified by the
manufacturer to ±1percent of the tag value. Additionally, the
manufacturer of the cylinder should provide a recommended shelf
life for each calibration gas cylinder over which the
concentration does not change more than ±2percent from the
certified value. For calibration gas values not generally
available, alternative methods for preparing calibration gas
mixtures, such as dilution systems, may be used with prior
approval.
2.1.9.1 Fuel. A 40 percent H2/60 percent He or 40 percent H2/60
percent N2 gas mixture is recommended to avoid an oxygen
synergism effect that reportedly occurs when oxygen concentration
varies significantly
from a mean value.
2.1.9.2 Carrier Gas and Dilution Air Supply. High purity air
with less than 1 ppm of organic material (as propane or carbon
equivalent) or less than
0.1 percent of the span value, whichever
is greater.
2.1.9.3 FIA Linearity Calibration Gases. Low-, mid-, and
high—range gas mixture standards with nominal propane
concentrations of 20-30, 45-55,
and 70-80 percent of the span
value
in air, respectively.
Other calibration values and other
span values may be used if it can be shown that more accurate
measurements would be achieved.
2.1.9.4 Dilution Check Gas. Gas mixture standard containing
propane in air, approximately half the span value after dilution.
2.1.10 Particulate Filter. An in—stack or an out-of-stack glass
fiber filter is recommended if exhaust gas particulate loading is
significant. An
out-of-stack filter must be heated to prevent
any condensation unless it can be demonstrated that no
condensation occurs.
2.2 Captured Emissions Volumetric Flow Rate.
2.2.1 Method 2 or 2A Apparatus. For determining volumetric flow
rate.
2.2.2
Method 3 Apparatus and Reagents.
For determining
molecular weight of the gas stream. An estimate of the molecular
weight of the gas stream may be used if it can be justified.
2.2.3 Method 4 Apparatus and Reagents. For determining moisture
content, if necessary.
3. DETERMINATION OF VOLUMETRIC FLOW RATE OF CAPTURED EMISSIONS
3.1 Locate all points where emissions are captured from the
affected facility. Using Method 1, determine the sampling points.
0 11400967

561
Be sure to check each site for cyclonic or swirling flow.
3.2 Measure the velocity at each sampling site at least once
every hour during each sampling run using Method 2 or 2A.
4. DETERMINATION OF VOG~ CONTENT OF CAPTURED EMISSIONS
4.1 Analysis Duration. Measure the VOG~responses at each
captured emissions point during the entire test run or, if
applicable, while the process is operating. If there are a
multiple captured emissions locations, design a sampling system
to allow a single FIA to be used to determine the VOG~responses
at all sampling locations.
4.2 Gas VOGM Concentration.
4.2.1 Assemble the sample train as shown in Figure 1. Calibrate
the FIA according to the procedure in Section 5.1.
4.2.2 Set the dilution ratio and determine the dilution factor
according to the procedure in Section 5.3.
4.2.3 Conduct a system check according to the procedure in
Section 5.4.
4.2.4 Install the sample probe so that the probe is centrally
located in the stack, pipe, or duct, and is sealed tightly at the
stack port connection.
4.2.5 Inject zero gas at the calibration valve assembly.
Measure the system response time as the time required for the
system to reach the effluent concentration after the calibration
valve has been returned to the effluent sampling position.
4.2.6 Conduct a system check before and a system drift check
after each sampling run according to the procedures in Sections
5.2 and 5.4. If the drift check following a run indicates
unacceptable performance, the run is not valid. The tester may
elect to perform system drift checks during the run not to exceed
one drift check per hour.
4.2.7 Verify that the sample lines, filter, and pump
temperatures are 120 ±5°C.
4.2.8 Begin sampling at the start of the test period and
continue to sample during the entire run. Record the starting
and ending times and any required process information as
appropriate.
If multiple captured emission locations are sampled
using a single FIA, sample at each location for the same amount
of time (e.g., 2 minutes) and continue to switch from one
location to another for the entire test run. Be sure that total
~\~.~o_o968

562
sampling time at each location is the same at the end of the test
run. Collect at least 4 separate measurements from each sample
point during each hour of testing. Disregard the measurements at
each sampling location until two times the response time of the
measurement system has elapsed. Continue sampling for at least 1
minute and record the concentration measurements.
4.3 Background Concentration.
4.3.1 Locate all NDO’s of the TTE. A sampling point shall be
centrally located outside of the TTE at 4 equivalent diameters
from each NDO, if possible. If there are more than 6 NDO’s,
choose 6 sampling points evenly spaced among the NDO’s.
4.3.2 Assemble the sample train as shown in Figure 2. Calibrate
the FIA and conduct a system check according to the procedures in
Sections 5.1 and 5.4.
4.3.3 Position the probe at the sampling location.
4.3.4 Determine the response time, conduct the system check and
sample according to the procedures described in Sections 4.2.4 to
4.2.8.
4.4 Alternative Procedure. The direct interface sampling and
analysis procedure described in Section 7.2 of Method 18 may be
used to determine the gas VOG~concentration. The system must be
designed to collect and analyze at least one sample every 10
minutes.
S. CALIBRATION AND QUALITY ASSURANCE
5.1 FIA Calibration and Linearity Check. Make necessary
adjustments to the air and fuel supplies
for the FIA and ignite
the burner. Allow the FIA to warm up for the period recommended
by the manufacturer. Inject a calibration gas into the
measurement system after the dilution system and adjust the back—
pressure regulator to the value required to achieve the flow
rates specified by the manufacturer. Inject the zero— and the
high—range calibration gases and adjust the analyzer calibration
to provide the proper responses. Inject the low— and mid—range
gases and record the responses of the measurement system. The
calibration and
linearity of the system are acceptable if the
responses for all four gases are within 5 percent of the
respective gas values. If the performance of the system is not
acceptable, repair or adjust the system and repeat the linearity
check. Conduct a calibration and linearity check after
assembling the analysis system and after a major change is made
to the system.
5.2 Systems Drift Checks. Select the calibration gas that most
Q~
L~.Q-09S9

563
closely approximates the concentration of the diluted captured
emissions for conducting the drift checks. Introduce the zero
and calibration gas at the calibration valve assembly and verify
that the appropriate gas flow rate and pressure are present at
the FIA. Record the measurement system responses to the zero and
calibration gases. The performance
of the system is acceptable
if the difference
between the drift check measurement and the
value obtained in Section 5.1 is less than
3 percent of the span
value. Conduct the system drift check at the end of each run.
5.3 Determination of Dilution Factor. Inject the dilution check
gas into the measurement system before the dilution system and
record the response. Calculate the dilution factor using
Equation 3.
5.4 System Check. Inject the high range calibration gas at the
inlet to the sampling probe while the dilution air is turned off.
Record the response.
The performance of the system is acceptable
if the measurement system response is within 5 percent of the
value obtained in Section 5.1 for the high range calibration gas.
Conduct a system check before and after each test run.
5.5 Analysis Audit. Immediately before each test analyze an
audit cylinder as described in Section 5.2. The analysis audit
must agree with the audit cylinder concentration within 10
percent.
6. NOMENCLATURE
A1
=
area of NDO i, ft2-~
AN
=
total area of
all NDO’s in the enclosure, ft2--j
CA
=
actual concentration of the dilution check gas,
ppm propane-~j
C51
=
corrected average VOCM concentration of background
emissions at point i, ppm propane~-;
C5
=
average
background concentration, ppm propane-~
CDH
=
average measured concentration for the drift check
calibration gas, ppm propane--;
C00
=
average system
drift check concentration for zero
concentration gas, ppm propane--j.
=
actual concentration of the drift check
calibration gas, ppm propane--;
C1
=
uncorrected average background VOCM concentration
measured at point i, ppm propane--j
01140-0970

564
C~
=
uncorrected average VOC~concentration measured at
point j, ppm propane-~
CM
=
measured concentration of the dilution check gas,
ppm propane--;~
DF
=
dilution factor--j.
G
=
total VOC~content of captured emissions, kg--j.
K1
=
1.830 x 106 kg/(m3-ppm)--~.
n
=
number of measurement points--;
QG~
=
average
effluent volumetric flow rate corrected to
standard conditions at captured emissions point j,
m3/min--j
Tc
=
total duration of capture efficiency sampling run,
mm.
7.
CALCULATIONS
7.1 Total VOGM Captured Emissions.
n
G
=
E CGj QG~ Tc K1 Eq. 1
j=1
7.2 VOG~Concentration of the Captured Emissions at Point j.
CGj
=
DF (C~
-
C00)
CH
Eq. 2
CDH~CDo
7.3 Dilution Factor.
DF
=
CA
Eq. 3
CM
7.4 Background VOGM Concentration at Point i.
C51
=
(C~
C00)
CH
Eq. 4
CDH
CDO
7.5 Average Background Concentration.
n
CB
=
i=1
E C5~ A1
Eq. 5
nAN
I

565
NOTE: If the concentration at each point is within 20 percent of
the average concentration of all points, the terms “A1” and “AN”
may be deleted from Equation 4.
Procedure F.2 - Fugitive VOG~Emissions from Building Enclosures
1. INTRODUCTION
1.1 Applicability. This procedure is applicable for determining
the fugitive volatile organic compounds-materials (VOGM) emissions
from a building enclosure (BE). It is intended to be used as a
segment
in the development of liquid/gas or gas/gas protocols for
determining VOG~capture efficiency (CE) for surface coating and
printing operations.
1.2
Principle. The total amount
of fugitive VOG~emissions (FB)
from the BE is calculated as the sum of the products of the VOGN
content (CF~) of each fugitive emissions point, its flow rate
(QF~)’
and fime (TF).
1.3 Measurement Uncertainty.
The measurement uncertainties
are
estimated for each fugitive emissions point as follows: QF~
=
±5.0percent and CFj
=
±5.0percent. Based on these numbers, the
probable uncertainty for F5 is estimated at about ±11.2 percent.
1.4 Sampling Requirements. A capture efficiency test shall
consist of at least three sampling runs. The sampling time for
each run should be at least 8 hours, unless otherwise approved.
1.5 Notes. Because this procedure is often applied in highly
explosive areas, caution and care should be exercised in choosing
appropriate equipment and installing and using the equipment.
Mention of trade names or company products does not constitute
endorsement.
All gas concentrations
(percent, ppm) are by
volume, unless otherwise noted.
2. APPARATUS AND REAGENTS
2.1 Gas VO?M Concentration.
A schematic of the
measurement
system is shown in Figure 1. The main components are described
below:
2.1.1
Sample Probe.
Stainless steel, or equivalent.
The probe
shall be heated to prevent VOG~condensation.
2.1.2
Calibration Valve Assembly.
Three-way valve assembly at
the outlet of sample probe to direct the zero and calibration
gases to the analyzer. Other methods, such as quick—connect
lines, to route calibration gases to the outlet of the sample
probe are acceptable.
2.1.3 Sample Line. Stainless steel or Teflon tubing to
0 11400972

566
transport the sample gas to
the analyzer. The sample line must
be heated to prevent condensation.
2.1.4 Sample Pump.
A leak-free pump, to pull the sample gas
through
the system at a
flow rate sufficient to minimize the
response time of the measurement system. The components of the
pump that contact the gas stream shall be constructed of
stainless steel or Teflon. The sample pump must be heated to
prevent condensation.
2.1.5 Sample Flow Rate Control. A sample flow rate control
valve and rotameter, or equivalent, to maintain a constant
sampling rate within 10 percent. The flow rate control valve and
rotameter must be heated to prevent condensation. A control
valve may also be located on the sample pump bypass loop to
assist in controlling the sample
pressure and flow rate.
2.1.6 Sample Gas Manifold. Capable of diverting a portion of
the sample gas stream to the flame ionization analyzer (FIA), and
the remainder to the bypass discharge vent. The manifold
components shall be constructed of stainless steel or Teflon. If
emissions are to be measured at multiple locations, the
measurement system shall be designed to
use separate sampling
probes, lines, and pumps for
each measurement location and a
common sample gas manifold and FIA. The sample
gas manifold must
be heated to prevent condensation.
2.1.7 Organic Concentration Analyzer. An FIA with a span value
of 1.5 times the expected concentration as propane; however,
other span values may be used if it can be demonstrated that they
would provide more accurate measurements. The system shall be
capable of meeting or exceeding the following specifications:
2.1.7.1
Zero Drift.
Less than ±3.0 percent of the span value.
2.1.7.2 Calibration Drift. Less than ±3.0percent of the span
value.
2.1.7.3 Calibration Error. Less than ±5.0 percent of the
calibration gas value.
2.1.7.4 Response Time. Less than 30 seconds.
2.1.8 Integrator/Data
Acquisition System. An analog or digital
device or computerized data acquisition system used to integrate
the FIA response or compute the average response and record
measurement data. The minimum
data sampling frequency for
computing average or integrated values is one measurement value
every S seconds.
The device shall be capable of recording
average values at least once per minute.
2.1.9
Calibration and Other Gases.
Gases used for calibration,
01140-0973

567
fuel, and combustion air (if required) are contained in
compressed gas cylinders.
All calibration gases shall be
traceable to NIST standards and shall
be certified by the
manufacturer to ±1percent of the tag value. Additionally, the
manufacturer of the cylinder
should provide a recommended shelf
life for each calibration gas cylinder over which the
concentration does not change more than
±2percent from the
certified value.
For calibration gas values not generally
available, alternative methods for preparing calibration gas
mixtures, such as dilution systems, may be used with prior
approval.
2.1.9.1
Fuel.
A 40 percent H2/60 percent He or 40 percent H2/60
percent N2 gas mixture is recommended to avoid an oxygen
synergism effect that reportedly occurs when oxygen concentration
varies significantly from a mean value.
2.1.9.2 Carrier Gas. High purity air with less than 1 ppm of
organic material (propane or carbon equivalent) or less than 0.1
percent of the span value, whichever is greater.
2.1.9.3
FIA Linearity Calibration Gases.
Low-, mid-, and
high—range gas mixture standards with nominal propane
concentrations of 20-30, 45-55, and 70-80 percent of the span
value in air, respectively.
Other calibration values and other
span values may be used if it can be shown that more accurate
measurements would be achieved.
2.1.10
Particulate
Filter.
An in-stack or an out-of-stack glass
fiber filter is recommended if exhaust gas particulate loading is
significant.
An out-of-stack filter must be heated to prevent
any condensation unless it can be demonstrated that no
condensation occurs.
2.2 Fugitive Emissions Volumetric Flow Rate.
2.2.1
Flow Direction Indicators.
Any means of indicating inward
or outward flow, such as light plastic film or paper streamers,
smoke tubes, filaments, and sensory perception.
2.2.2
Method 2 or 2A Apparatus.
For determining volumetric flow
rate.
Anemometers or similar devices calibrated according to the
manufacturer’s instructions may be used when low velocities are
present.
Vane anemometers (Young—maximum response propeller),
specialized pitots with electronic manometers (e.g., Shortridge
Instruments Inc., Airdata Nultimeter 860) are commercially
available with measurement thresholds of 15 and 8 mpm (50 and
25
fpm), respectively.
2.2.3
Method 3 Apparatus and Reagents.
For determining
molecular weight of the gas stream.
An estimate of the molecular
weight of the gas stream may be used if it can be justified.
01140-09714

568
2.2.4 Method 4 Apparatus and Reagents. For determining moisture
content, if necessary.
3. DETERMINATION OF VOLUMETRIC FLOW RATE OF FUGITIVE EMISSIONS
3.1 Preliminary Determinations. The purpose of this exercise is
to determine which exhaust points should be measured for
volumetric flow rates and VOG~Jconcentrations.
3.1.1
Forced Draft Openings.
Identify all forced draft
openings.
Determine the volumetric flow rate according to Method
2.
3.1.2
NDO’s Exhaust Points.
The NDO’s in the roof of a
facilitythe building or room in which
the emission unit is
located are considered to be exhaust points.
Determine
volumetric flow rate from these MDC’S.
Divide the
cross—sectional area according to Method 1 using 12 equal areas.
Use the
appropriate velocity measurement devices, e.g., propeller
anemometers.
3.1.3 Other NDO’s.
3.1.3.1
This step is optional.
Determine the exhaust flow rate,
including that of the control device, from the enclosure and the
intake air flow rate.
If the exhaust flow rate divided by the
intake air flow rate is greater than 1.1, then all other NDO’s
are not considered to be significant exhaust points.
3.1.3.2
If the option above is not taken, identify all other
NDO’s and other potential points through which fugitive emissions
may escape the enclosure.
Then use the following criteria to determine whether flow rates
and VOGM concentrations
need to be measured:
3.1.3.2.1
Using the appropriate flow direction indicator,
determine the flow direction. An NDO with zero or inward flow is
not an exhaust point.
3.1.3.2.2
Measure the outward volumetric flow rate from the
remainder of the NDO’s. If the collective flow rate is 2
percent, or less, of the flow rate from Sections 3.1.1 and 3.1.2,
then these NDO’s, except those within two equivalent diameters
(based on NDO opening) from ~VOGM s-ourccs-emitting point, may be
considered to be non-exhaust points.
3.1.3.2.3
If the percentage calculated in Section 3.1.3.2.2 is
greater than 2 percent, those NDO’s (except those within two
equivalent diameters from ~VOG~ sources-emitting point) whose
volumetric flow rate total 2 percent of the flow rate from
Sections 3.1.1 and 3.1.2 may be considered as non-exhaust points.
01140-0975

569
All remaining NDO’s shall be measured for volumetric flow rate
and VOGM concentrations during the CE test.
3.1.3.2.4 The tester may choose to measure VOG~ concentrations
at the forced exhaust points and the NDO’s. If the total VOG~J
emissions from the NDO’s are less than 2 percent of the emissions
from the forced draft and roof NDO’~s, then these NDO’s may be
eliminated from further consideration.
3.2 Determination of Flow Rates.
3.2.1 Measure the volumetric flow rate at all locations
identified as exhaust points in Section 3.1. Divide each exhaust
opening into 9 equal areas for rectangular openings and 8 for
circular openings.
3.2.2 Measure the velocity at each site at least once every hour
during each sampling run using Method 2 or 2A, if applicable, or
using the low velocity instruments in Section 2.2.2.
4. DETERMINATION OF VOGN CONTENT OF FUGITIVE EMISSIONS
4.1 Analysis Duration. Measure the VOG~responses at each
fugitive emission point during the entire test run or, if
applicable, while the process is operating.
If there are
multiple emissions locations, design a sampling system to allow a
single FIA to be used to determine the VOG~responses at all
sampling locations.
4.2 Gas VO~jConcentration.
4.2.1 Assemble the sample train as shown in Figure 1. Calibrate
the FIA and conduct a system check according to the procedures in
Sections 5.1 and 5.3, respectively.
4.2.2
Install the sample probe so that the probe is centrally
located in the stack, pipe, or duct, and is sealed tightly at the
stack port connection.
4.2.3
Inject zero gas at the calibration valve assembly.
Allow
the measurement system response to reach zero.
Measure the
system response time as the time required for the system to reach
the effluent concentration after the calibration valve has been
returned to the effluent sampling position.
4.2.4 Conduct a system check before and a system drift check
after each sampling run according to the procedures in Sections
5.2
and 5.3.
If the drift check following a run indicates
unacceptable performance, the run is not valid.
The tester may
elect to perform drift checks during the run not to exceed one
drift check per hour.
01140-0976

570
4.2.5 Verify that the sample lines, filter, and pump
temperatures are 120 ±5°C.
4.2.6 Begin sampling at the start of the test period and
continue to sample during the entire run. Record the starting
and ending times and any required process information as
appropriate. If multiple emission locations are sampled using a
single FIA, sample at each location for the same amount of time
(e.g., 2 minutes) and continue to switch from one location to
another for the entire test run. Be sure that total sampling
time at each location is the same at the end of the test run.
Collect at least 4 separate measurements from each sample point
during each hour of testing. Disregard the response measurements
at each sampling location until two times the response time of
the measurement system has elapsed. Continue sampling for at
least 1 minute and record the concentration measurements.
4.3 Alternative Procedure The direct interface sampling and
analysis procedure described in Section 7.2 of Method 18 may be
used to determine the gas VOG~concentration. The system must be
designed to collect and analyze at least one sample every 10
minutes.
5. CALIBRATION AND QUALITY ASSURANCE
5.1 FIA Calibration and Linearity Check. Make necessary
adjustments to the air and fuel supplies for the FIA and ignite
the burner. Allow the FIA to warm up for the period recommended
by the manufacturer. Inject a calibration gas into the
measurement system and adjust the back—pressure regulator to the
value required to achieve the flow rates specified by the
manufacturer. Inject the zero— and the high—range calibration
gases and adjust the analyzer calibration to provide the proper
responses. Inject the low— and mid—range gases and record the
responses of the measurement system. The calibration and
linearity of the system are acceptable if the responses for all
four gases are within 5 percent of the respective gas values. If
the performance of the system is not acceptable, repair or adjust
the system and repeat the linearity check. Conduct a calibration
and linearity check after assembling the analysis system and
after a major change is made to the system.
5.2 Systems Drift Checks. Select the calibration gas that most
closely approximates the concentration of the captured emissions
for conducting the drift checks. Introduce the zero and
calibration gas at the calibration valve assembly and verify that
the appropriate gas flow rate and pressure are present at the
FIA. Record the measurement system responses to the zero and
calibration~gases. The performance of the system is acceptable
if the difference between the drift check measurement and the
value obtained in Section 5.1 is less than 3 percent of the span
value. Conduct a system drift check at the end of each run.
01140-0977

571
5.3 System Check. Inject the high range calibration gas at the
inlet of the sampling probe and record the response. The
performance of the system is acceptable if the measurement system
response is within 5 percent of the value obtained in Section 5.1
for the high range calibration gas. Conduct a system check
before each test run.
5.4 Analysis Audit. Immediately before each test analyze an
audit cylinder as described in Section 5.2. The analysis audit
must agree with the audit cylinder concentration within 10
percent.
6.
NOMENCLATURE
=
average measured concentration for the drift check
calibration gas, ppm propane-~j
C00
=
average system drift check concentration for zero
concentration gas, ppm propane--j
CFj
=
corrected average VOGN concentration of fugitive
emissions at point j, ppm propane--;
=
actual concentration of the drift check
calibration gas, ppm propane-~j
C~
=
uncorrected average VOG~ concentration measured at
point j, ppm propane.~
F5
=
total VOG~content of fugitive emissions from the
building, kg-~
K1
=
1.830 x 10-6 kg/(m3-ppm)~-j.
n
=
number of measurement points-i-;
=
average effluent volumetric flow rate corrected to
standard conditions at fugitive emissions point j,
TF
=
total duration of capture efficiency sampling run,
mm.
7. CALCULATIONS
7.1 Total VOG~Fugitive Emissions From the Building.
n
F5
=
E CF.~ ~ TF K1
Eq. 1
j=1
7.2 VOGM Concentration of the Fugitive Emissions at Point j.
U 140-0978

572
CFj
=
(C~
— C00)
CH
Eq. 2
— CDO
Procedure F.1 — Fugitive VOGM Emissions from Temporary Enclosures
1. INTRODUCTION
1.1 Applicability. This procedure is applicable for determining
the fugitive volatile organic compounds-materials (VOGI~j) emissions
from a temporary total enclosure (TTE). It is intended to be
used as a segment in the development of liquid/gas or gas/gas
protocols for determining VOG~capture efficiency (CE) for
surface coating and printing operations.
1.2 Principle. The amount of fugitive VOG~emissions (F) from
the TTE is calculated as the sum of the products of the VOG~
content (CFj), the flow rate (QFj)’ and the sampling time (TF)
from each fugitive emissions point.
1.3 Estimated Measurement Uncertainty. The measurement
uncertainties are estimated for each fugitive emission point as
follows: QF~=±5.5 percent and CFj
=
±5.0percent. Based on
these numbers, the probable uncertainty for F is estimated at
about ±7.4percent.
1.4 Sampling Requirements. A capture efficiency test shall
consist of at least three sampling runs.
The sampling time for
each run should be at least 8 hours, unless otherwise approved.
1.5 Notes. Because this procedure is often applied in highly
explosive areas, caution and care should be exercised in choosing
appropriate equipment and installing and using the equipment.
Mention of trade names or company products does not constitute
endorsement. All gas concentrations (percent, ppm) are by
volume, unless otherwise noted.
2.
APPARATUS AND REAGENTS
2.1 Gas VOGM Concentration.
A schematic of the measurement
system is shown in Figure 1. The main components are described
below:
2.1.1
Sample Probe.
Stainless steel, or equivalent.
The probe
shall be heated to prevent VOG~condensation.
2.1.2 Calibration
Valve Assembly. Three-way valve assembly at
the outlet of sample probe to direct the zero and calibration
gases to the analyzer.
Other methods, such as quick-connect
lines, to route calibration gases to the outlet of the sample
probe are acceptable.
0 140-0979

573
2.1.3
Sample Line.
Stainless steel or Teflon tubing to
transport the sample gas to the analyzer. The sample line must
be heated to prevent condensation.
2.1.4 Sample Pump. A leak-free pump, to pull the sample gas
through the system at a flow rate sufficient to minimize the
response time of the measurement system. The components of the
pump that contact the gas stream shall be constructed of
stainless steel or Teflon. The sample pump must be heated to
prevent condensation.
2.1.5 Sample Flow Rate Control. A sample flow rate control
valve and rotameter, or equivalent, to maintain a constant
sampling rate within 10 percent.
The flow control valve and
rotameter must be heated to prevent condensation. A control
valve may also be located on the sample pump bypass 1oop to
assist in controlling the sample pressure and flow rate.
2.1.6 Sample Gas Manifold. Capable of diverting a portion of
the sample gas stream to the flame ionization analyzer (FIA), and
the remainder to the bypass discharge vent.
The manifold
components shall be constructed of stainless steel or Teflon.
If
emissions are to be measured at multiple locations, the
measurement system shall be designed to use separate sampling
probes, lines, and pumps for each
measurement location and a
common sample gas manifold and FIA.
The sample gas manifold and
connecting lines to the FIA must be heated to prevent
condensation.
2.1.7 Organic Concentration Analyzer. An FIA with a span value
of 1.5 times the expected concentration as propane; however,
other span values may be used if it can be demonstrated that they
would provide more accurate measurements.
The system shall be
capable of meeting or exceeding the following specifications:
2.1.7.1 Zero Drift. Less than ±3.0percent of the span value.
2.1.7.2 Calibration Drift. Less than ±3.0percent of the span
value.
2.1.7.3
Calibration Error.
Less than ±5.0 percent of the
calibration gas value.
2.1.7.4
Response Time. Less than 30 seconds.
2.1.8
Integrator/Data
Acquisition System. An analog or digital
device or computerized data acquisition system used to integrate
the FIA response or compute the average response and record
measurement data.
The minimum data sampling frequency for
computing average or integrated values is one measurement value
every 5 seconds.
The device shall be capable of recording
average values at least once per minute.
01140-0980

574
2.1.9 Calibration and Other Gases. Gases used for calibration,
fuel, and combustion air (if required) are contained in
compressed gas cylinders. All calibration gases shall be
traceable to NIST standards and shall be certified by the
manufacturer to ±1percent of the tag value. Additionally, the
manufacturer of the cylinder should provide a recommended shelf
life for each calibration
gas cylinder over which the
concentration does not change more than ±2 percent from the
certified value.
For calibration gas values not generally
available, alternative methods for preparing calibration gas
mixtures, such as dilution systems, may be used with prior
approval.
2.1.9.1
Fuel.
A 40 percent H2/60 percent He or 40 percent H2/60
percent N2 gas mixture is recommended to avoid an oxygen
synergism effect that reportedly occurs when oxygen concentration
varies significantly
from a mean value.
2.1.9.2
Carrier Gas. High purity air with less than 1 ppm of
organic material (as propane or carbon equivalent) or less than
0.1 percent of the span value, whichever is greater.
2.1.9.3 FIA Linearity Calibration Gases. Low-, mid-, and
high—range gas mixture standards with nominal propane
concentrations of 20-30, 45-55, and 70-80 percent of the span
value in air, respectively.
Other calibration values and other
span values may be used if it can be shown that more accurate
measurements would be achieved.
2.1.10 Particulate Filter.
An in-stack or an out-of—stack glass
fiber filter is recommended if exhaust gas particulate
loading is
significant.
An out-of-stack filter must be heated to prevent
any condensation unless it can be demonstrated that no
condensation occurs.
2.2 Fugitive Emissions Volumetric Flow Rate.
2.2.1
Method 2 or 2A Apparatus.
For determining volumetric flow
rate.
2.2.2
Method 3 Apparatus and Reagents.
For determining
molecular weight of the gas stream.
An estimate of the molecular
weight of the gas stream may be used if it can be justified.
2.2.3 Method 4 Apparatus and Reagents. For determining moisture
content, if necessary.
2.3 Temporary Total Enclosure.
The criteria
for designing a TTE
are discussed in Procedure T.
3.
DETERMINATION OF VOLUMETRIC FLOW RATE OF FUGITIVE EMISSIONS
01140-0981

575
3.1 Locate all points where emissions are exhausted from the
TTE. Using Method 1, determine the sampling points. Be sure to
check each site for cyclonic or swirling flow.
3.2 Measure the velocity at each sampling site at least once
every hour during each sampling run using Method 2 or 2A.
4. DETERMINATION OF VOG~ CONTENT OF FUGITIVE EMISSIONS
4.1 Analysis Duration. Measure the VOG~ responses at each
fugitive emission point during the entire test run or, if
applicable, while the process is operating. If there are
multiple emission locations, design a sampling system to allow a
single FIA to be used to determine the VOC~responses at all
sampling locations.
4.2 Gas VOGM Concentration.
4.2.1 Assemble the sample train as shown in Figure 1. Calibrate
the FIA and conduct a system check according to the procedures in
Sections 5.1 and 5.3, respectively.
4.2.2
Install the sample probe so that the probe is centrally
located in the stack, pipe, or duct, and is sealed tightly at the
stack port connection.
4.2.3 Inject zero gas at the calibration valve assembly. Allow
the measurement system response to reach zero. Measure the
system response time as the time required for the system to reach
the effluent concentration after the calibration valve has been
returned to the effluent sampling position.
4.2.4 Conduct a system check before and a system drift check
after each sampling run according to the procedures in Sections
5.2
and 5.3.
If the drift check following a run indicates
unacceptable performance, the run is not valid.
The tester may
elect to perform system drift checks during the run not to exceed
one drift check per hour.
4.2.5
Verify that the sample lines, filter, and pump
temperatures are 120 ±5°C.
4.2.6 Begin sampling at the start of the test period and
continue to sample during the entire run. Record the starting
and ending times and any required process information as
appropriate.
If multiple emission locations are sampled using a
single FIA, sample at each location for the same amount of time
(e.g., 2 minutes) and continue to switch from one location to
another for’the entire test run. Be sure that total sampling
time at each location is the same at the end of the test run.
Collect at least 4 separate measurements from each sample point
during each hour of testing.
Disregard the response measurements
01140-0982

576
at each sampling location until two times the response time of
the measurement system has elapsed. Continue sampling for at
least 1 minute and record the concentration measurements.
4.3 Background Concentration.
4.3.1 Determination of VOGN Background Concentration.
4.3.1.1 Locate all NDO’s of the TTE. A sampling point shall be
centrally located outside of the TTE at 4 equivalent diameters
from each NDO, if possible. If there are more than 6 NDO’s,
choose 6 sampling points evenly spaced among the NDO’s.
4.3.1.2 Assemble the sample train as shown in Figure 2.
Calibrate the FIA and conduct a system check according to the
procedures in Sections 5.1 and 5.3.
4.3.1.3 Position the probe at the sampling location.
4.3.1.4 Determine the response time, conduct the system check
and sample according to the procedures described in Sections
4.2.3 to 4.2.6.
4.4 Alternative Procedure. The direct interface sampling and
analysis procedure described in Section 7.2 of Method 18 may be
used to determine the gas VOG~concentration. The system must be
designed to collect and analyze at least one sample every 10
minutes.
5. CALIBRATION AND QUALITY ASSURANCE
5.1
FIA Calibration and Linearity Check. Make necessary
adjustments to the air and fuel supplies for the FIA and ignite
the burner.
Allow the FIA to warm up for the period recommended
by the manufacturer. Inject a calibration gas into the
measurement system and adjust the back—pressure regulator to the
value required to achieve the flow rates specified by the
manufacturer.
Inject the zero— and the high—range calibration
gases and adjust the analyzer calibration to provide the proper
responses.
Inject the low— and mid—range gases and record the
responses of the measurement system.
The calibration
and
linearity of the system are acceptable if the responses for all
four gases are within 5 percent of the respective gas values.
If
the performance of the system is not acceptable, repair or adjust
the system and repeat the linearity check.
Conduct a calibration
and linearity check after assembling the analysis system and
after a major change is made to the system.
5.2 Systems Drift Checks. Select the calibration gas
concentration that most closely approximates that of the fugitive
gas emissions to conduct the drift checks.
Introduce the zero
and calibration gas at the calibration valve assembly and verify
01140-0983

577
that the appropriate gas flow rate and
pressure are present at
the FIA. Record
the measurement system responses to the zero and
calibration gases.
The performance of the system is acceptable
if the difference between the drift check measurement and the
value obtained in Section 5.1 is less than 3 percent of the span
value.
Conduct a system drift check at the end of each run.
5.3 System Check. Inject the high range calibration gas at the
inlet of the sampling probe and record
the response. The
performance of the system is acceptable if the measurement system
response is within 5 percent of the value obtained in Section 5.1
for the high range calibration gas. Conduct a system check
before each test run.
5.4
Analysis Audit. Immediately before each test analyze an
audit cylinder as described in Section 5.2. The analysis audit
must agree with
the audit cylinder concentration within 10
percent.
6. NOMENCLATURE
A1
=
area of NDO i,
ft2~-j~.
AN
=
total area of all NDO’s in the enclosure, ft2-rj
C51
=
corrected average VOGM concentration
of background
emissions at point i, ppm propane--j.
C3
=
average background concentration,
ppm propane--i
COM
=
average measured concentration for the drift check
calibration gas, ppm propane--i
C00
=
average system drift check concentration f or zero
concentration gas, ppm propane-~j
CFj
corrected average VOGM concentration
of fugitive
emissions at point
j, ppm propane~-;
CM
=
actual concentration of the drift check
calibration gas, ppm propane--i
C~
=
uncorrected average background VOG~concentration
measured at point i, ppm propane-~-j
C~
=
uncorrected average VOGM concentration measured at
point
j,
ppm propane-~
G
=
total VOGI~j content of captured emissions, kg--i
K1
=
1.830 x 10-6 kg/(m3-ppm)-~
01 ~4009814

578
n
=
number of measurement points--;
=
average effluent volumetric flow rate corrected to
standard conditions at fugitive emissions point j,
TF
=
total duration of fugitive emissions sampling run,
mm.
7. CALCULATIONS
7.1 Total VOGN Fugitive Emissions.
n
F
=
E
(CFj -
C5
)
QF~ TF
K1
Eq. 1
j=1
7.2 VOGM Concentration of the Fugitive Emissions at Point j.
CFj
=
(C~
— C00)
CM
Eq. 2
7.3
Background VOG~Concentration
C00
at Point i.
CB1
=
(C1 - C00)
CH
Eq. 3
7.4 Average BackgroundCDHConcentration.
C00
n
C3
=
i=1E
CBI A1
Eq. 5
nAN
NOTE: If the concentration at each point is within 20 percent of
the average concentration of all points, the terms “A1” and “AN”
may be deleted from Equation 4.
Procedure L - VOGN Input
1. INTRODUCTION
1.1 Applicability.
This procedure is applicable for determining
the input of volatile
organic compounds-materials (VOG~). It is
intended to be used as a segment in the development of liquid/gas
protocols for determining VOG~capture efficiency
(CE) for
surface coating and printing operations.
1.2 Principle.
The amount of VOGN introduced to the process
(L) is the sum
of the products of the weight (W) of each VOG~
01140-0985

579
containing liquid (ink,
paint, solvent, etc.) used and its VOG~
content (V). A sample of each VOG~containing liquid is analyzed
with a flame ionization analyzer (FIA) to determine V.
1.3 Estimated Measurement Uncertainty. The measurement
uncertainties are estimated for each VOG~containing liquid as
follows: W
=
±2.0percent and V
=
±12.0 percent. Based on these
numbers, the probable uncertainty for L is estimated at about
±12.2 percent for each VOG~containing liquid.
1.4 Sampling
Requirements. A capture efficiency test shall consist of at
least three sampling runs. The sampling time for each run should
be at least 8 hours, unless otherwise approved.
1.5 Notes.
Because this procedure is often applied in highly
explosive areas, caution and care should be exercised in choosing
appropriate equipment and installing and using the equipment.
Mention of trade names or company products does not constitute
endorsement. All gas
concentrations (percent, ppm) are by
volume, unless otherwise noted.
2.
APPARATUS
AND REAGENTS
2.1 Liquid Weight.
2.1.1
Balances/Digital
Scales.
To weigh drums of VOGM
containing liquids to within 0.2 lb.
2.1.2
Volume Measurement Apparatus (Alternative).
Volume
meters, flow meters, density measurement equipment, etc., as
needed to achieve same accuracy as direct weight measurements.
2.2 VOG~J Content (Flame Ionization Analyzer Technique).
The
liquid sample analysis system is shown in Figures 1 and 2. The
following equipment is required:
2.2.1
Sample Collection Can. An appropriately sized metal can
to be used to collect VOG~containing materials. The can must be
constructed in such a way that it can be grounded to the coating
container.
2.2.2
Needle Valves.
To control gas flow.
2.2.3 Regulators.
For carrier gas and calibration gas
cylinders.
2.2.4 Tubing.
Teflon or stainless steel tubing with diameters
and lengths determined by connection requirements of equipment.
The tubing between the sample oven outlet and the FIA shall be
heated to maintain a temperature of 120 ±5°C.
2.2.S Atmospheric Vent. A tee and 0- to 0.5-liter/mm
rotameter
placed in the sampling line between the carrier gas cylinder and
0 140-0986

580
the VOGM sample vessel to release the excess carrier gas. A
toggle valve placed between the tee and the rotameter facilitates
leak tests of the analysis system.
2.2.6
Thermometer.
Capable of measuring the temperature of the
hot water bath to within 1°C.
2.2.7 Sample Oven. Heated
enclosure, containing calibration gas
coil heaters, critical orifice, aspirator, and other liquid
sample analysis components, capable of maintaining a temperature
of 120 ±5°C.
2.2.8 Gas Coil Heaters. Sufficient lengths of stainless steel
or Teflon tubing to allow zero and calibration gases to be heated
to
the sample oven temperature before entering the critical
orifice or aspirator.
2.2.9 Water Bath.
Capable of heating and maintaining a sample
vessel temperature of 100 ±5°C.
2.2.10 Analytical Balance. To measure ±0.001 g.
2.2.11
Disposable Syringes.
2—cc or 5-cc.
2.2.12
Sample Vessel.
Glass, 40-ml septum vial.
A separate
vessel is needed for each sample.
2.2.13
Rubber Stopper.
Two-hole stopper to accommodate 3.2-mm
(1/8-in.) Teflon tubing, appropriately sized to fit the opening
of the sample vessel.
The rubber stopper should be wrapped in
Teflon tape to provide a tighter seal and to prevent any reaction
of the sample with the rubber stopper.
Alternatively,
any
leak—free closure fabricated of non—reactive materials and
accommodating the necessary tubing fittings may be used.
2.2.14
Critical Orifices.
Calibrated critical orifices capable
of providing constant flow rates from 50 to 250 ml/min at known
pressure drops. Sapphire
orifice assemblies (available from
O’Keefe Controls Company) and glass capillary tubing have been
found to be adequate for this application.
2.2.15 Vacuum Gauge. 0— to 760-mm (0- to 30—in.) Hg U-Tube
manometer or vacuum gauge.
2.2.16
Pressure Gauge. Bourdon gauge capable of measuring the
maximum air pressure at the aspirator inlet (e.g., 100 psig).
2.2.17 Aspirator. A device capable of generating sufficient
vacuum at the sample vessel to create critical flow through the
calibrated orifice when sufficient air pressure is present at the
aspirator inlet.
The aspirator must also provide sufficient
sample pressure to operate the FIA. The sample is also mixed
01140-0987

581
with the dilution gas within the aspirator.
2.2.18 Soap Bubble Meter. Of an appropriate size to calibrate
the critical
orifices in the system.
2.2.19
Organic Concentration Analyzer.
An FIA with a span value
of 1.5 times the expected concentration
as propane; however other
span values may be used if it can be demonstrated that they would
provide more accurate measurements.
The system shall be capable
of meeting or exceeding the following specifications:
2.2.19.1 Zero Drift. Less than ±3.0percent of the span value.
2.2.19.2
Calibration Drift.
Less than ±3.0 percent of span
value.
2.2.19.3
Calibration Error.
Less than ±5.0 percent of the
calibration gas value.
2.2.20
Integrator/Data
Acquisit~ion System.
An analog or digital
device or computerized data acquisition system used to integrate
the FIA response or compute the average response and record
measurement data. The minimum data sampling frequency for
computing average or integrated values is one measurement value
every 5 seconds.
The device shall be capable of recording
average values at least once per minute.
2.2.21
Chart Recorder (Optional).
A chart recorder or similar
device is recommended to provide a continuous analog display of
the measurement results during the liquid sample analysis.
2.2.22
Calibration and Other Gases.
For calibration,
fuel, and
combustion air (if required) contained in compressed gas
cylinders. All calibration gases shall be traceable to NIST
standards and shall be certified by the manufacturer to ±1
percent of the tag value.
Additionally,
the manufacturer of the
cylinder should provide a recommended shelf—life for each
calibration gas cylinder over which the concentration does nor
change more than ±2 percent from the certified value.
For
calibration gas values not generally available, alternative
methods for preparing calibration gas mixtures, such as dilution
systems, may be used with prior approval.
2.2.22.1
Fuel.
A 40 percent H2/60 percent He or 40 percent
H2/60 percent N2 gas mixture is recommended to avoid an oxygen
synergism effect that reportedly occurs when oxygen concentration
varies significantly
from a mean value.
22.22.2
Carrier Gas. High purity air with less than 1 ppm of
organic material (as propane) or less than 0.1 percent of the
span value, whichever is greater.
01140-0988

582
2.2.22.3
FIA Linearity Calibration Gases.
Low-, mid-, and
high—range gas mixture standards with nominal propane
concentrations
of 20-30, 45—55, and 70—80 percent of the span
value in air, respectively.
Other calibration values and other
span values may be used if it can be shown that more accurate
measurements would be achieved.
2.2.22.4
System Calibration Gas. Gas mixture standard
containing propane in air, approximating the undiluted VOG~
concentration expected for the liquid samples.
3.
DETERMINATION OF LIQUID INPUT WEIGHT
3.1 Weight Difference.
Determine the amount of material
introduced to the process as the
weight difference of the feed
material before and after each sampling run.
In determining the
total VOG~containing liquid usage, account for:
(a) the initial
(beginning) VOGN containing liquid mixture; (b) any solvent added
during the test run; (c) any coating added during the test run;
and (d) any residual VOG~containing liquid mixture remaining at
the end of the sample run.
3.1.1 Identify all points where VOG~containing liquids are
introduced to the process.
To obtain an accurate measurement of
VOGM containing liquids, start with an empty fountain (if
applicable).
After completing the run, drain the liquid in the
fountain back into the liquid drum (if possible), and weigh the
drum again. Weigh the VOGN containing liquids to ±0.5percent of
the total weight (full) or ±0.1 percent of the total weight of
VOGM containing liquid used during the sample run, whichever is
less. If the residual liquid cannot
be returned to the drum,
drain the fountain into a preweighed empty drum to determine the
final weight of the liquid.
3.1.2
If it is not possible to measure a single representative
mixture, then weigh the various components separately (e.g., if
solvent is added during the sampling run, weigh the solvent
before it is added to the mixture). If a fresh drum of VOGM
containing liquid is needed during the run, then weigh both the
empty drum and fresh drum.
3.2 Volume Measurement (Alternative).
If direct weight
measurements are not feasible, the tester may use volume meters
and flow rate meters (and density measurements) to determine the
weight of liquids used if it can be demonstrated that the
technique produces results equivalent to the direct weight
measurements.
If a single representative
mixture cannot be
measured, measure the components separately.
4. DETERMINATION OF VOGM CONTENT IN INPUT LIQUIDS
4.1 Collection of Liquid Samples.
01140-0989

583
4.1.1 Collect a lOO-ml or larger sample of the VOGM containing
liquid mixture at each application location at the beginning and
end of each test run. A separate sample should be taken of each
VOG~containing liquid added to the application mixture during
the test run.
If a fresh drum is needed during the sampling run,
then obtain a sample from the fresh drum.
4.1.2
When collecting the sample, ground the sample container to
the coating drum. Fill the sample container as close to the rim
as possible to minimize the amount of headspace.
4.1.3
After the sample is collected, seal the container so the
sample cannot leak out or evaporate.
4.1.4 Label the container to
identify clearly the contents.
4.2
Liquid Sample VOGN Content.
4.2.1
Assemble the liquid VOGN content analysis system as shown
in Figure 1.
4.2.2
Permanently identify all of the critical orifices that may
be used. Calibrate each critical orifice under the expected
operating conditions (i.e.,
sample vacuum and temperature)
against a volume meter as described in Section 5.3.
4.2.3
Label and tare the sample vessels (including the stoppers
and caps) and the syringes.
4.2.4
Install an empty sample vessel and perform a leak test of
the system.
Close the carrier gas valve and atmospheric vent and
evacuate the sample vessel to 250 mm (10 in.) Hg absolute or less
using the aspirator.
Close the toggle valve at the inlet to the
aspirator and observe the vacuum for at least one minute.
If
there is any change in the sample pressure, release the vacuum,
adjust or repair the apparatus as necessary and repeat the leak
test.
4.2.5
Perform the analyzer calibration and linearity checks
according to the procedure in Section 5.1.
Record the responses
to each of the calibration
gases and the back—pressure setting of
the FIA.
4.2.6
Establish the appropriate dilution ratio by adjusting the
aspirator air supply or substituting
critical orifices.
Operate
the aspirator at a vacuum of at least 25 mm (1 in.) Hg greater
than the vacuum necessary to achieve critical
flow.
Select the
dilution ratio so that the maximum response of the FIA to the
sample does not exceed the high—range calibration gas.
4.2.7 Perform system calibration checks at
two
levels by
introducing compressed gases at the inlet to the sample vessel
o
140-0990

584
while the aspirator and dilution devices are operating.
Perform
these checks using the carrier gas (zero concentration) and the
system calibration gas. If the response to the carrier gas
exceeds ±0.5percent of span, clean or repair the apparatus and
repeat the check. Adjust the dilution ratio as necessary to
achieve the correct response to the upscale check, but do not
adjust the analyzer calibration.
Record the identification
of
the orifice, aspirator air supply pressure, FIA back—pressure,
and the responses of the FIA to the carrier and system
calibration gases.
4.2.8 After completing the above checks, inject the system
calibration gas for approximately
10 minutes. Time the exact
duration of the gas injection using a stopwatch.
Determine the
area under the FIA response curve and calculate the system
response factor based on the sample gas flow rate, gas
concentration,
and the duration of the injection as compared to
the integrated response using Equations 2 and 3.
4.2.9
Verify that the sample oven and sample line temperatures
are 120 ±5°Cand that the water bath temperature is 100 ±5°C.
4.2.10
Fill a tared syringe with approximately 1 g of the VOGN
containing liquid and weigh it.
Transfer the liquid to a tared
sample vessel.
Plug the sample vessel to minimize sample loss.
Weigh the sample vessel containing the liquid to determine the
amount of sample actually received.
Also, as a quality control
check, weigh the empty syringe to determine the amount of
material delivered.
The two coating sample weights should agree
within ±0.02 g. If not, repeat the procedure until an acceptable
sample is obtained.
4.2.11
Connect the vessel to the analysis system.
Adjust the
aspirator supply pressure to the correct value.
Open the valve
on the carrier gas supply to the sample vessel and adjust it to
provide a slight excess flow to the atmospheric vent.
As soon as
the initial response of the FIA begins to decrease, immerse the
sample vessel in the water bath.
(Applying heat to the sample
vessel too soon may cause the FID response to exceed the
calibrated range
of the instrument, and thus invalidate the
analysis.)
4.2.12
Continuously measure and record the response of the FIA
until all of the volatile material has been evaporated from the
sample and the instrument response has returned to the baseline
(i.e., response less than 0.5 percent of the span value).
Observe the aspirator supply pressure, FIA back—pressure,
atmospheric vent, and other system operating parameters during
the run; repeat the analysis procedure if any of these parameters
deviate from the values established during the system calibration
checks in Section 4.2.7.
After each sample perform the drift
check described in Section 5.2.
If the drift check results are
01140-0991

585
acceptable, calculate the VOGM content of the sample using the
equations in Section 7. Integrate the area under the FIA
response curve, or determine the average concentration response
and the duration of sample analysis.
5. CALIBRATION AND QUALITY ASSURANCE
5.1 FIA Calibration and Linearity Check. Make necessary
adjustments to the air and fuel supplies for the FIA and ignite
the burner.
Allow the FIA to warm up for the period recommended
by the manufacturer.
Inject a calibration gas into the
measurement system and adjust the back-pressure regulator to the
value required to achieve the flow rates specified by the
manufacturer.
Inject the zero— and the high—range calibration
gases and adjust the analyzer calibration to provide the proper
responses.
Inject the low— and mid—range gases and record the
responses of the measurement system.
The calibration and
linearity of the system are acceptable if the responses for all
four gases are within
5 percent of the respective gas values. If
the performance of the system is not acceptable, repair or adjust
the system and repeat the linearity
check. Conduct a calibration
and linearity check after assembling the analysis system and
after a major change is made to the system.
5.2 Systems Drift Checks. After each sample, repeat the system
calibration
checks in Section 4.2.7 before any adjustments to the
FIA or measurement system are made. If the zero or calibration
drift exceeds ±3 percent of the span value, discard the result
and repeat the analysis.
5.3
Critical Orifice Calibration.
5.3.1 Each critical orifice must be calibrated at the specific
operating conditions that it will be used.
Therefore, assemble
all components of the liquid sample analysis system as shown in
Figure 3. A stopwatch is also required.
5.3.2
Turn on the sample oven, sample line, and water bath
heaters and allow the system to reach the proper operating
temperature.
Adjust the aspirator to a vacuum of 380 mm (15 in.)
Hg vacuum. Measure the time required for one soap bubble to move
a known distance and record barometric pressure.
5.3.3
Repeat the calibration
procedure at a vacuum of 406 mm (16
in.) Hg and at 25-mm (1-in.) Hg intervals until three consecutive
determinations provide the same flow rate.
Calculate the
critical flow rate for the orifice in ml/min at standard
conditions.
Record the vacuum necessary to achieve critical
flow.
6.
NOMENCLATURE
r)
‘~0-0992

586
AL
=
area under the response curve of the liquid
sample, area count--;
As
=
area under the response curve of the calibration
gas, area count--j.
C~
=
actual concentration of system calibration
gas,
ppm propane--j
K
=
1.830 x l0~
g/(ml-ppm)-~
L
=
total VOGN content of liquid input, kg--i
ML
=
mass of liquid sample delivered to the sample
vessel, g--j
q
=
flow
rate through critical orifice, ml/min--.;
RF
=
liquid analysis system response factor, g/area
count--j
Ts
=
total gas injection time
for system calibration
gas during integrator calibration, min--;
VFj
==
initialfinal
VOGMVOGMfractionfractionofofVOGNVOGMcontainingcontainingliquidliquidj--1
=
VOGN fraction of VOGN containing liquid
j
added
during the run--i
V
=
VOGN fraction of liquid sample--i
=
weight of VOGM containing liquid j remaining at
end of the run, kg--;
W1~
=
weight of VOGN containing liquid
j at beginning of
the run, kg~-j~.
=
weight of VOGN containing liquid j added during
the run, kg.
7. CALCULATIONS
7.1 Total VOGN Content of the Input VOGN Containing Liquid.
n
n
fl
L
=
E V~W1~
=
VFj WFj + E VAj W~ R
Eq. 1
j=1
j=1
j=1
7.2 Liquid Sample Analysis System Response Factor for Systems
01140-0993

587
Using Integrators, Grams/Area Counts.
RF
=
~s ~ T5J~
Eq. 2
As
7.3 VOGN Content of the Liquid Sample.
V
=
Eq. 3
ML
Procedure T
Criteria for and Verification of a Permanent or
Temporary Total Enclosure
1. INTRODUCTION
1.1 Applicability. This procedure is used to determine whether
a permanent or temporary enclosure meets the criteria of a total
enclosure.
1.2 Principle. An enclosure is evaluated against a set of
criteria.
If the criteria are met and
if all the exhaust gases
are ducted to a control device, then the volatile organic
compounds-materials (VOGN) capture efficiency
(CE) is assumed to
be 100 percent and CE need not be measured. However, if part of
the exhaust gas stream is not ducted to a control device, CE must
be determined.
2.
DEFINITIONS
2.1 Natural Draft Opening (NDO)
--
Any permanent opening in the
enclosure that remains open during operation of the facility
emission unit and is not connected to a duct in which a fan is
installed.
2.2 Permanent Total Enclosure (PTE)
--
A permanently installed
enclosure that completely surrounds a~ source of emissioneunit
such that all VOGN emissions are captured and contained for
discharge through a control device.
2.3 Temporary Total Enclosure (TTE)
-- A temporarily installed
enclosure that completely surrounds a~ source of eimissionsunit
such that all VOGN emissions are captured and contained for
discharge through ducts that allow for the accurate measurement
of VOGN rates.
3.
CRITERIA OF A TEMPORARY TOTAL ENCLOSURE
3.1 Any NDO shall be at least
4 equivalent opening diameters
from each
VOGN
emitting point.
3.2 Any exhaust point from the enclosure shall be at least 4
equivalent duct or hood diameters from each NDO.
r~i 1t11-Q9g~

588
3.3 The total area of all NDO’s shall not exceed
5 percent of
the surface area of the enclosure’s four walls, floor, and
ceiling.
3.4 The average facial velocity (FV) of air through all NDO’s
shall be at least 3,600 m/hr (200 fpm). The direction of air
through all NDO’s shall be into the enclosure.
3.5
All access doors and windows whose areas are not included in
Section 3.3 and are not included in the calculation in Section
3.4 shall be closed
during routine operation of the
proces-semission unit.
4.
CRITERIA OF A PERMANENT TOTAL ENCLOSURE
4.1 Same as Sections 3.1 and 3.3 — 3.5.
4.2 All VOGN emissions must be captured and contained for
discharge through a control device.
5. PROCEDURE
5.1 Determine the equivalent diameters of the NDO’s and
determine the distances from each VOGN
emitting point to all
NDO’s. Determine the equivalent diameter of each exhaust duct or
hood and its distance to all NDO’s. Calculate the distances in
terms of equivalent diameters. The number of equivalent
diameters shall be at least 4.
5.2 Measure the total area (At) of the enclosure and the total
area (AN) of all NDO’s of the enclosure. Calculate the NDO to
enclosure area ratio (NEAR) as follows:
NEAR
=
AN/At
The
NEAR
must be
0.05.
5.3 Measure the volumetric flow rate, corrected to standard
conditions, of each gas stream exiting the enclosure through an
exhaust duct or hood using EPA Method 2,
In some cases (e.g.,
when the building is the enclosure), it may be necessary to
measure the volumetric flow rate, corrected to standard
conditions, of each gas stream entering the enclosure through a
forced makeup air duct using Method 2.
Calculate FV using the
following equation:
FV
=
Q0
- QI/AN
where:
=
the sum of the volumetric flow from all gas
streams exiting the enclosure through an exhaust
01140-0995

589
duct or hood.
=
the sum of the volumetric flow from all gas
streams into the enclosure through a forced makeup
air duct; zero, if there is no forced makeup air
into the enclosure.
AN
=
total area of all NDO’s in enclosure.
The FV shall be at least 3,600 m/hr (200 fpm).
5.4 Verify that the direction of air flow through all NDO’Sis
inward.
Use streamers, smoke tubes, tracer gases, etc. Strips
of plastic wrapping film have been found to be effective.
Monitor the direction of air flow at intervals of at least 10
minutes for at least 1 hour.
6. QUALITY ASSURANCE
6.1 The success of this protocol lies in designing the TTE to
simulate the conditions that exist without the TTE, i.e., the
effect of the TTE on the normal flow patterns around the affected
~*~yemission
unit or the amount of fugitive VOGN emissions
should be minimal.
The TTE must enclose the application
stations, coating reservoirs, and all areas from the application
station to the oven. The oven does not have to be enclosed if it
15 under negative pressure. The NDO’s of the temporary enclosure
and a fugitive exhaust fan must be properly sized and placed.
6:2. Estimate the ventilation rate of the TTE that best
simulates the conditions that exist without the TTE, i.e., the
effect of the TTE on the normal flow patterns around the affected
f~ae*~4~yemissionunit or the amount of fugitive VOGN emissions
Should be minimal.
Figure 1 may be used as an aid.
Measure the
concentration
(CG) and flow rate (Q0) of the captured gas stream,
specify a safe concentration (CF) for the fugitive gas stream,
estimate the CE, and then use the plot in Figure 1 to determine
the volumetric flowrate of the fugitive gas stream (QF)’ A
fugitive
VOGM emission exhaust fan that has a variable flow
Control is desirable.
6.2.1
Monitor the concentration of VO~ into the capture device
Without the TTE. To minimize the effect of temporal variation on
the captured emissions, the baseline measurement should be made
Over as long a time period as practical.
However, the process
Conditions must be the same for the measurement in Section 6.2.3
as they are for this baseline measurement.
This may require
short measuring times for this quality control check before and
after the construction of the TTE.
6.2.2
After the TTE is constructed,
monitor the VOGM
~ncentration
inside the TTE. This concentration
shall not
*
L

590
continue to increase and must not exceed the safe level according
to OSHA requirements for permissible exposure limits. An
increase in VOGN concentration indicates poor TTE design or poor
capture efficiency.
6.2.3 Monitor the concentration of VOGN into the capture device
with the TTE. To limit the effect of the TTE on the process, the
VOGM
concentration with and without the TTE must be within ±10
percent. If the measurements do not agree, adjust the
ventilation rate from the TTE until they agree within 10 percent.
(Source: Amended at
Ill. Reg.
______,
effective
___________)
0 140-0997

591
Section 219.APPENDIX C
REFERENCE TEST METHODS AND PROCEDURESFOR AIR OXIDATION PROCESSES
Introduction
This Appendix presents
the reference methods and procedures
required for implementing Reasonably
Available Control Technology
(RACT).
Methods and procedures are identified for two types of
~ACT implementation:
a) Determination of VOG~destruction efficiency for evaluating
compliance with the 98 weight percent VOGN reduction or 20
ppmv emission limit specified in Sections 215.520 through
215.527; and
b) Determination of offgas flowrate, hourly emissions and
stream net heating value for calculating TRE.
All reference methods identified in this Appendix refer to the
reference methods specified at 40 CFR 60, Appendix A,
incorporated by reference in Section 215.105.
VOGM DESTRUCTION EFFICIENCY DETERMINATION
The following reference methods and procedures are required for
determining compliance with the percent destruction efficiency
specified in Sections 215.520 through 215.527.
a)
Reference Method 1 or lA for selection of the sampling site.
The control device inlet sampling site for determination of
vent stream molar composition or total organic compound
destruction efficiency shall be prior to the inlet of any
control device and after
all recovery devices.
b) Reference Methods 2, 2A, 2C or 2D for determination of the
volumetric flowrate.
C)
Reference Method
3 to measure oxygen concentration of the
air dilution correction. The emission sample shall be
corrected to 3 percent oxygen.
d) Reference Method 18 to determine the concentration of total
organic compounds (minus methane and ethane) in the control
device outlet and total organic compound reduction
efficiency of the control device.
TRE DETERMINATION
The following reference methods and procedures are required for
determining the offgas flowrate, hourly emissions, and the net
heating value of the gas combusted to calculate the vent stream
TRE.
0~ 140-0998

592
a)
Reference Method 1 or 1A for selection of the sampling site.
The sampling site for the vent stream flowrate and molar
composition determination prescribed in (b) and (c) shall be
prior to the inlet of any combustion device, prior to any
post-reactor dilution of the stream with air and prior to
any post—reactor introduction of halogenated compounds into
the vent stream. Subject to the preceding restrictions on
the sampling site, it shall be after the final recovery
device.
If any gas stream other than the air oxidation vent
stream is normally conducted through the recovery system of
the affected facility,
such stream shall be rerouted or
turned off while the vent stream is sampled, but shall be
routed normally prior to the measuring of the initial value
of the monitored parameters for determining compliance with
the recommended PACT. If the air oxidation vent stream is
normally routed through
any equipment which is not a part of
the air oxidation process as defined in 35 Ill. Adm. Code
211.122, such equipment shall be bypassed by the vent stream
while the vent stream is sampled, but shall not be bypassed
during the measurement of the initial value of the monitored
parameters for determining compliance with Subpart V.
b)
The molar composition of the vent stream shall be determined
using the following methods:
1)
Reference Method 18 to measure the concentration of all
organics, including those containing halogens, unless a
significant portion of the compounds of interest are
polymeric (high molecular weight), can polymerize
before analysis or have low vapor pressures, in which
case Reference Method 25(a) shall be used.
2)
ASTM D1946-67 (reapproved 1977), incorporated by
reference in Section 215.105,
to measure the
concentration of carbon monoxide and hydrogen.
3) Reference Method 4 to measure the content of water
vapor, if necessary.
c)
The volumetric flowrate shall be determined using Reference
Method 2, 2A, 2C or 2D, as appropriate.
d)
The net heating value of the vent stream shall be calculated
using the following equation:
n
H=K
E CiHi
i=1
Where:
H
=
Net heating value of the sample, MJ/scm, where the
0 140-0999

593
net enthalpy per mole of offgas is based on
combustion at 25°Cand 760 mm Hg, but the standard
temperature for determining the volume
corresponding to one mole is 20°C, as in the
definition of F (vent stream flowrate) below.
K
=
Constant, 1.740 x
io~ (1/ppm) (mole/scm)
(MJ/kcal) where standard temperature for mole/scm
is 20°C.
Ci
=
Concentration of sample component
i, reported on a
wet basis, in ppm, as measured by Reference Method
18 or ASTM D1946-67 (reapproved 1977),
incorporated by reference in Section 215.105.
Hi
=
Net heat of combustion of sample component i,
kcal/mole based on combustion at 25~Cand 760 mm
Hg. If published values are not available or
cannot be calculated, the heats of combustion of
vent stream components are required to be
determined using ASTM D2382-76, incorporated by
reference in Section 215.105.
e)
The emission rate of total organic compounds in the process
vent stream shall be calculated using the following
equation:
n
E=K F E CiMi
i=1
Where:
E
=
Emission rate of total
organic compounds (minus
methane and ethane) in the sample in kg/hr--;
K
=
Constant 2.494 x 106 (1/ppm) (mole/scm) (kg/g)
(min/hr), where standard temperature for
(mole/scm) is 20°C--;
Mi
=
Molecular weight of sample component i (g/mole)-~-;
F
=
Vent stream flowrate (scm/mm), at a standard
temperature of 20°C.
f)
The total vent stream concentration
(by volume) of compounds
containing halogens (ppmv, by compound) shall be summed from
the individual concentrations of compounds containing
halogens which were measured by Reference Method 18~
(Source:
Amended at
Ill. Reg.
______,
effective
___________)
f~fl_ flflf)

594
Section 219.APPENDIX D
COEFFICIENTS FOR THE TOTAL RESOURCE EFFECTIVENESS INDEX (TRE)
EQUATION
This Appendix contains values for the total resource
effectiveness index (TRE) equation in Subpart V.
If a flow rate falls exactly on the boundary between the
indicated ranges, the operator shall use the row in which the
flow rate is maximum.
COEFFICIENTS FOR TRE EQUATION FOR CHLORINATED PROCESS
VENT STREAMS WITH
NET HEATING VALUE LESS THAN OR EQUAL TO 3.5 MJ/scm
FLOW RATE
(scm/mm)
Mm. Max.
a
b
c
d
e
f
0.0 13.5 48.73 0.
0.404 —0.1632 0.
0.
13.5 700. 42.35 0.624 0.404 —0.1632 0.
0.0245
700. 1400.
84.38 0.678 0.404 —0.1632 0.
0.0346
1400.
2100.
126.41
0.712
0.404
—0.1632
0.
0.0424
2100.
2800.
168.44
0.747
0.404
—0.1632
0.
0.0490
2800.
3500.
210.47
0.758
0.404
—0.1632
0.
0.0548
COEFFICIENTS FOR TRE EQUATION FOR CHLORINATED PROCESS
VENT STREAMS WITH
NET HEATING VALUE GREATER THAN 3.5 NJ/scm
FLOW RATE
(scm/mm)
Mm.
Max.
a
b
c
d
e
f
0.
13.5 47.76 0.
—0.292 0.
0.
0.
13.5
700.
41.58
0.605 —0.292
0.
0.
0.0245
700.
1400.
82.84
0.658 —0.292
0.
0.
0.0346
1400.
2100.
123.10
0.691 —0.292
0.
0.
0.0424
2100. 2800. 165.36 0.715 —0.292 0.
0.
0.0490
2800.
3500.
206.62
0.734 —0.292
0.
0.
0.0548
COEFFICIENTS FOR TRE EQUATION FOR NONCHLORINATED PROCESS
VENT STREAMS WITH
NET HEATING VALUE LESS THAN OR EQUAL TO 0.48 MJ/scm
FLOW PATE
(scm/mm)
Mm.Max.
a
b
c
d
e
£
0.
13.5
19.05
0.
0.113
—0.214
0.
0.
13.5 1350.
16.61
0.239
0.113
—0.214
0.
0.0245
1350. 2700.~ 32.91 0.260 0.113 —0.214 0.
0.0346
2700.
4050.
49.21
0.273
0.113
—0.214
0.
0.0424
COEFFICIENTS FOR TRE EQUATION FOR NONCHLORINATED PROCESS
01140-1 00!

595
VENT STREAMS
WITH NET HEATING VALUE GREATER THAN 0.48 AND LESS THAN OR
EQUAL TO 1.9 NJ/scm
FLOW RATE
(scm/mm)
Mm. Max.
a
b
c
d
e
f
0.
13.5 19.74 0.
0.400 —0.202
0.
0.
13.5 1350.
18.30 0.138 0.400 —0.202 0.
0.0245
1350. 2700. 36.28 0.150 0.400 —0.202 0.
0.0346
2700. 4050. 54.26 0.158 0.400 —0.202 0.
0.0424
COEFFICIENTS FOR TRE EQUATION FOR NONCHLORINATED PROCESS
VENT STREAMS
WITH NET HEATING VALUE GREATER THAN 1.9 AND LESS THAN OR
EQUAL TO 3.6 MJ/scm
FLOW PATE
(scm/mi n)
Mm.Max.
a
b
c
d
e
f
.0
13.5
15.24
0.
0.033
0.
0.
0.
13.5 1190.
13.63
0.157 0.033
0.
0.
0.0245
1190. 2380. 26.95 0.171 0.033 0.
0.
0.0346
2380.
3570.
40.27
0.179 0.033
0.
0.
0.0424
COEFFICIENTS FOR TRE EQUATION FOR NONCHLORINATED
PROCESS
VENT STREAMS WITH
NET HEATING VALUE GREATER THAN 3.6 MG/scm
FLOW PATE
(scm/mm)
Mm.
Max.
a
b
c
d
e
£
0.
13.5 15.24 0. 0.
0.0090 0.
0.
13.5 1190.
13.63
0.
0.
0.0090
0.0503
0.0245
1190.
2380.
26.95
0.
0.
0.0090
0.0546
0.0346
2380.
3570.
40.27
0.
0.
0.0090
0.0573
0.0424
(Source:
Amended at
Ill. Peg.
______,
effective
___________
IT IS SO ORDERED.
I,
Dorothy M. Gunn, Clerk of the Illinois Pollution Control
Board, hereby certify that the above opinion and order was
adopted on the Z ~
day of
~
—._~
, 1993, by a vote
of ~ C
~1
~
// ~
Dorothy M. ~~unn, Clerk
Illinois Pollution Control Board
~U~/OO2

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