BEFORE
    THE
    ILLiNOIS
    POLLUTION
    CONTROL
    BOARD
    CLERK’S
    CVD
    OFFICE
    IN
    THE
    MATTER
    OF:
    PROPOSED
    AMENDMENTS
    TO
    )
    ACTION
    TIERED
    APPROACH
    OBJECTIVES
    TO
    CORRECTIVE
    )
    fl
    (35
    Ill.
    Adm.
    Code
    742)
    U
    r\
    1—
    NOTICE
    Dorothy
    Gunn,
    Clerk
    Bill
    Richardson
    Illinois
    Pollution
    Control
    Board
    Chief
    Legal
    Counsel
    James
    R. Thompson
    Center
    Illinois
    Dept.
    of
    Natural
    Resources
    100
    W.
    Randolph,
    Suite
    11-500
    One
    Natural
    Resources
    Way
    Chicago,
    Illinois
    60601
    Springfield,
    Illinois
    62702-127
    1
    (Via
    First
    Class
    Mail)
    (Via
    First
    Class
    Mail)
    Matt
    Dunn
    Environmental
    Bureau
    Chief
    Office
    of
    the
    Attorney
    General
    James
    R.
    Thompson
    Center
    100
    W. Randolph,
    12
    th
    Floor
    Chicago,
    Illinois
    60601
    (Via
    First
    Class
    Mail)
    PLEASE
    TAKE
    NOTICE
    that
    I
    have
    today
    filed
    with
    the
    Office
    of
    the
    Clerk
    of
    the
    Illinois
    Pollution
    Control
    Board
    the
    Illinois
    Environmental
    Protection
    Agency’s
    (“Illinois
    EPA”)
    Motion
    for
    Acceptance,
    Appearance
    of
    Attorney,
    Certification
    of
    Origination,
    Motion
    for
    Leave
    from
    Filing
    Requirement.
    List
    of
    Studies
    and
    Reports
    Used
    in
    Regulatory
    Development.
    Statement
    of
    Reasons,
    and
    the
    Proposed
    Amendments
    a
    copy
    of
    each
    of
    which
    is
    herewith
    served
    upon
    you.
    ILLINOIS
    ENVIRONMENTAL
    PROTECTION
    AGENCY
    By:______
    AsstantCornsel
    Division
    of
    Legal
    Counsel
    R09-
    (Rulemaking-Land)
    SEP
    03
    2008
    STATE
    OF
    LLINOIS
    Pollution
    Control
    Board
    )

    DATE: September
    2, 2008
    1021 North
    Grand
    Avenue East
    P.O.
    Box 19276
    Springfield,
    Illinois 62794-9276
    (217)782-5544

    BEFORE
    THE
    ILLTh4OIS
    POLLUTION
    CONTROL
    BOAECEVED
    LERK
    S
    OFFICE
    IN THE
    MATTER
    OF:
    )
    )
    R09-
    0’
    )
    032008
    PROPOSED
    AMENDMENTS
    TO
    )
    (Rulemaking-LandSTATE
    OF
    ‘WNOIS
    TIERED
    APPROACH
    TO
    CORRECTIVE
    )
    ‘01ttion
    Control
    Board
    ACTIONOBJECTIVES
    I
    (35
    Iii
    Adm
    Code
    742)
    MOTION
    FOR
    ACCEPTANCE
    NOW
    COMES
    the
    Illinois
    Environmental
    Protection
    Agency
    (“Illinois
    EPA”)
    and,
    pursuant
    to 35
    Iii.
    Adm.
    Code
    102.106,
    102.200,
    and
    102.202,
    moves
    the
    Illinois
    Pollution
    Control
    Board
    (“Board”)
    to accept
    the
    Illinois
    EPA’s
    proposal
    for
    hearing.
    This
    regulatory
    proposal
    includes:
    1) the
    Appearance
    for
    the
    attorney
    representing
    the
    Illinois
    EPA;
    2) Certification
    of
    Origination;
    3)
    the
    Statement
    of
    Reasons;
    and
    4)
    the
    Proposed
    Amendments.
    Respectfully
    submitted,
    ILLINOIS
    ENVIRONMENTAL
    PROTECTION
    AGENCY
    By:
    DATE:
    August
    6
    ,2008
    1021
    North
    Grand
    Avenue
    East
    P.O.
    Box
    19276
    Springfield,
    Illinois
    62794-9276
    (217)782-3397
    Director
    THIS
    FILING
    SUBMITTED
    ON
    RECYCLED
    PAPER

    IN
    THE MATTER
    OF:
    PROPOSED
    AMENDMENTS TO
    TIERED
    APPROACH
    TO
    CORRECTIVE
    ACTION
    OBJECTIVES
    (35
    Ill.
    Adm.
    Code 742)
    )
    R09-
    )
    (Rulemaking-Land)
    )
    )
    )
    The
    undersigned,
    as
    one of
    its attorneys,
    hereby
    enters
    her
    entry
    of
    Appearance
    on
    behalf
    of the
    Illinois
    Environmental
    Protection
    Agency.
    ILLINOIS
    ENVIRONMENTAL
    PROTECTION
    AGENCY
    By:
    DATE:
    September
    2, 2008
    1021 North
    Grand
    Avenue
    East
    P.O. Box
    19276
    Springfield,
    Illinois
    62794-9276
    (217)782-5544
    BEFORE
    THE
    ILLINOIS
    POLLUTION
    CONTROL
    BOARD
    OVED
    OFP1
    SEP
    032008
    STA1Eop
    POllution
    Controi
    ILLINOIS
    Board
    APPEARANCE
    l)
    f
    [
    .
    Division
    of
    Legal
    Counsel

    BEFORE
    THE
    ILLINOIS
    POLLUTION
    CONTROL
    BOARD
    CLEF?1css
    IN
    THE
    MATTER
    OF:
    )
    SEP
    03
    2008
    PROPOSED
    AMENDMENTS
    TO
    )
    (RulemkingLand)P0IkJtiOn
    °cojN
    8
    O1S
    TIERED
    APPROACH
    TO
    CORRECTiVE
    )
    oarcj
    ACTION
    OBJECTIVES
    )
    (35
    Iii
    Adm
    Code
    742)
    )
    )
    CERTIFICATION
    OF
    ORIGINATION
    NOW
    COMES
    the
    Illinois
    Environmental
    Protection
    Agency
    (“Illinois
    EPA”)
    and,
    pursuant
    to 35
    Ill.
    Adm.
    Code
    102.202(i),
    certifies
    that
    this
    proposal
    for
    amendments
    to
    35
    Ill.
    Adm.
    Code
    742
    amends
    the
    most
    recent
    version
    of that
    rule
    as
    published
    on the
    Illinois Pollution
    Control
    Board’s
    website.
    Respectfully
    submitted,
    ILLINOIS
    ENVIRONMENTAL
    PROTECTION
    AGENCY
    mberly
    Geving
    Assistant
    Counsel
    DATE: September
    2,
    2008
    1021
    North
    Grand
    Avenue
    East
    P.O.
    Box
    19276
    Springfield,
    Illinois
    62794-9276
    (217)782-5544

    BEFORE
    THE
    ILLINOIS
    POLLUTION
    CONTROL
    BO47
    14
    !Qt/o
    C°LL/NO,
    1N THE
    MATTER
    OF:
    )
    °1’8Orci
    )
    PROPOSED AMENDMENTS
    TO
    )
    R09-
    TIERED
    APPROACH TO
    CORRECTIVE
    )
    (Rulemaking-Land)
    ACTION
    OBJECTIVES
    )
    (35
    Ill.
    Adm.
    Code
    742)
    )
    )
    MOTION
    FOR
    LEAVE
    FROM
    FILING
    REQUIREMENT
    NOW
    COMES the
    Illinois
    Environmental
    Protection
    Agency
    (“Illinois
    EPA”)
    and, pursuant
    to
    35 Ill.
    Adm.
    Code
    10 1.500,
    moves
    the
    Illinois
    Pollution
    Control
    Board
    (“Board”)
    to waive
    the
    filing
    requirement
    pursuant
    to
    35 Ill.
    Adm.
    Code
    10
    1.306(a)
    for
    two
    of the
    Illinois
    EPA’s
    amended
    Incorporations
    by
    Reference.
    In
    support
    of
    its
    motion,
    the
    Illinois
    EPA
    asserts,
    and the
    Board
    has
    confirmed,
    that
    the
    titles
    for
    which
    this
    motion
    seeks
    relief
    from
    the
    filing
    requirement
    are
    already
    in
    the
    Board’s
    possession.
    Additionally,
    they
    are
    voluminous,
    multiple
    volume
    documents
    that
    would
    be
    unduly
    burdensome
    and
    costly
    to copy.
    WHEREFORE, the
    Illinois
    EPA
    seeks
    relief
    from
    the
    filing
    requirement
    for
    the
    following titles:
    (1)
    “Test
    Methods
    for Evaluating
    Solid
    Waste,
    PhysicallChemical
    Methods,”
    USEPA
    Publication
    No.
    SW-846,
    as amended
    by
    Updates
    I,
    II, ILk,
    JIB,
    III,
    lilA,
    and
    TuB,
    prepared
    by
    USEPA
    and
    available
    from
    National
    Technical
    Information
    Service,
    5285
    Port
    Royal
    Road,
    Springfield,
    VA
    22161
    or
    online
    at
    http
    ://www.epa.
    gov/epaoswer/hazwaste/test/main.htm
    ;
    and
    (2)
    United
    States
    Environmental
    Protection
    Agency,
    CFR
    Promulgated
    Test
    Methods,
    Method
    3C,
    “Determination
    of Carbon
    Dioxide,
    Methane,
    Nitrogen,
    and Oxygen
    from
    Stationary
    1

    Sources”
    and
    Method
    16,
    “Semicontinuous
    Determination
    of
    Sulfur
    Emissions
    from
    Stationary
    Sourées,”Technology
    Transfer
    Network,
    Emission
    Measurement
    Center,
    V
    (2007)
    available
    online
    at http
    ://www.epa.
    gov/ttnlemc/promgate.html.
    Respectfully
    submitted,
    ILLINOIS ENVIRONMENTAL
    PROTECTION
    AGENCY
    imberly
    Aj Geving
    Assistant
    Counsel
    Division
    of
    Legal
    Counsel
    DATED:
    September
    2,
    2008
    1021
    North
    Grand
    Avenue
    East
    P.O.
    Box
    19276
    Springfield, Illinois
    62794-9276
    2

    List of
    Studies
    and
    Reports
    Used
    in Regulatory Development
    American Petroleum
    Institute
    (Nov.
    2005).
    A
    Practical
    Strategy
    for Assessing
    the
    Subsurface
    Vapor-to-Indoor-Air
    Migration Pathway
    at
    Petroleum
    Hydrocarbon
    Sites.
    API
    Publication
    4741.
    http://www.itrcweb.org/Documents/VI-
    1
    .pdf
    Agency
    for
    Toxic
    Substances
    and
    Disease
    Registry
    (Jan.
    2004).
    Health
    Consultation:
    Active
    Soil Gas
    Data
    Review,
    Chillum
    Perc
    Site,
    Chillum,
    Prince
    Georges
    County, Maryland.
    http
    ://www.atsdr.cdc.
    gov/hac/PHAlchillumperc/cps
    p1
    .html
    Bibler,
    G. &
    Mason, E. (Nov.
    2005).
    Scrutiny
    of
    Indoor
    Air
    Pathway
    Affects
    Standards
    for
    Investigation
    and
    Cleanup.
    Daily
    Environment Report,
    11-10-05.
    http
    ://net2.gph.com//media!64E898D7D8F0423
    79F78727C
    1
    EC07A43
    .ashx
    California EPA,
    Department
    of
    Toxic
    Substances
    Control
    (Feb.
    2005).
    Interim
    Final
    Guidance
    for
    the
    Evaluation
    and
    Mitigation of
    Subsurface
    Vapor
    Intrusion
    to
    Indoor
    Air.
    http
    ://www.dtsc.ca.
    gov/assessingrisk/upload!herd
    pol
    eval
    subsurface
    vapor
    mt
    rusion
    interim_final.pdf
    California
    EPA,
    Department
    of Toxic
    Substances
    Control
    (Jan.
    2003).
    Advisory
    on
    Active
    Soil Gas
    Investigations.
    http
    ://www.dtsc.ca.gov/lawsregspolicies/policies/SiteCleanup/uploadlSMBR
    AD
    V_activesoilgasinvst.pdf
    Colorado
    Department
    of
    Public
    Health
    and
    Environment
    (Sept.
    2004).
    Draft
    Indoor
    Air
    Guidance.
    http://www.cdphe.state.co.us/HM/indoorair.pdf
    Department of the
    Army,
    U.S.
    Army
    Corps
    of
    Engineers
    (Sept
    1993).
    Indoor
    Radon
    Prevention
    and
    Mitigation.
    Technical
    Letter
    No.
    1110-3-438.
    http://www.wbdg.org/ccb/DOD/IJFC/ufc
    3_490_04a.pdf
    Fetter,
    C.W.
    (1994).
    Applied
    Hydrogeology,
    3
    Edition.
    Available
    at the
    Illinois
    EPA
    library,
    Call
    Number:
    551.48
    FETT
    1994
    Folkes,
    D.
    (Dec
    2002).
    Design,
    Effectiveness,
    and
    Reliability
    of
    Sub-Slab
    Depressurization
    Systems
    for
    Mitigation
    of
    Chlorinated
    Solvent
    Vapor
    Intrusion.
    EnviroGroup
    Limited.
    Presented
    at
    the
    U.S.
    EPA
    Seminar
    on Indoor
    Air
    Vapor
    Intrusion,
    San
    Francisco.
    http
    ://w’ww.
    envirogroup.comlpublications/folkes_epa_seminar.pdf
    Hartman,
    B.
    (Sept.
    2006).
    How
    to
    Collect
    Reliable
    Soil-Gas
    Data
    for
    Risk-Based
    Applications,
    Specifically
    Vapor
    Intrusion:
    Part
    Four,
    Updates
    on
    Soil-Gas
    Collection
    and
    Analytical
    Procedures.
    LUSTLine
    Bulletin
    #53.
    http
    ://www.handpmg.comllustline53
    -soil-gas-part-4.htm

    International
    Building
    Code
    (2006).
    Available
    at
    the
    Illinois
    EPA
    library
    upon
    request.
    Kremesec,
    V., Hopkins, H.
    and
    Thun,
    R. (Feb.
    2005).
    A
    View
    of
    the Evaluation
    of
    the
    Vapor
    Intrusion
    Pathway
    from
    Within
    the
    Petroleum
    Industry.
    EM
    Magazine,
    Air
    and
    Waste
    Management
    Association.
    http://www.astswmo.org/files/publications/tanks/2005
    SoilVaporMonitoringWork
    shop/Evaluation-of-Vapor-Intrusion-Pathway-Kxemesec.pdf
    Lyman,
    W.
    and
    Reehl,
    W.
    (1990).
    Handbook
    of
    Chemical
    Property
    Estimation
    Methods.
    Available
    at
    the
    Illinois
    EPA
    library,
    Call Number:
    547.3
    LYMA
    1990.
    McHugh,
    T.,
    Connor,
    J.,
    &
    Ahmad,
    F.
    (Mar.
    2005).
    An
    Empirical
    Analysis of the
    Groundwater-to-Indoor-Air
    Exposure
    Pathway:
    The
    Role
    of
    Background
    Concentrations
    in
    Indoor
    Air.
    Environmental
    Forensics,
    Vol.
    5,
    No.
    2.
    http://www.gsi-net.com/Publications
    /McHugh
    GW-Air
    2004.pdf
    Missouri
    Department
    of Natural
    Resources
    (April
    2005).
    Missouri
    Risk-Based
    Corrective
    Action
    for
    Petroleum
    Storage
    Tanks:
    Soil
    Gas
    Sampling
    Protocol.
    http
    ://www.dnr.mo.
    gov/env/hwp/tanks/docs/soil-gas-protocol-2005-04-2
    1
    .pdf
    New
    Hampshire
    Department
    of
    Environmental
    Services
    (April
    2005).
    Draft
    Vapor
    Intrusion
    Guidance.
    http
    ://www.des.state.nh.us/ORCB/doclist/pdf7vapor_intrusion.pdf
    New
    Jersey
    Department
    of
    Environmental
    Protection
    (June
    2005).
    Draft
    Vapor
    Intrusion
    Guidance.
    http
    ://www.state.nj
    .us/dep!srp/uidance/vaporintrusionJvig.htm
    New
    York
    Department
    of
    Environmental
    Conservation
    (Nov.
    2004).
    Evaluating
    the
    Potential
    for
    Vapor
    Intrusion
    at
    Past,
    Current
    and
    Future
    Sites,
    Draft.
    http
    ://www.ny-brownfields.comJPDF
    Files/Draft_Policy.pdf
    Pennsylvania
    Department
    of Environmental
    Protection
    (June
    2004).
    Land
    Recycling
    Program
    Technical
    Guidance
    Manual
    Section
    IV.A.4
    Vapor
    Intrusion
    into
    Buildings
    from
    Groundwater and
    Soil
    Under
    the Act
    2 Statewide
    Health
    Standard.
    http://164.156.71
    .80/VWRQ.asp?docid=2087d8407c0e0000000005
    110000051
    1&
    context=2&backlink=WXOD.aspx%3ffs%3
    d2087d8407c0e0000800005
    1000000
    510%26ft%3d1
    Persily,
    A.
    (March
    1999).
    Myths
    About
    Building
    Envelopes.
    ASHRAE
    Journal.
    http
    ://www.argonair.com/pdflMyth%2OAbout%2OBldg%2OEnv.pdf
    Siegel,
    L.
    (April
    2005).
    A Community View
    of
    Vapor
    Intrusion.
    Center
    for
    Public
    Environmental
    Oversight.
    http
    ://www.cpeo
    .org!pubs/CommunityView-V12.doc
    Stanin,
    F.
    (March
    2006).
    Vapor
    Intrusion:
    Breaking
    Through
    the
    Roadblocks
    to
    Progress.
    Superfund
    and
    Natural
    Resource
    Damages
    Litigation
    Committee
    Newsletter.
    Vol.

    3,No.
    1.
    http
    ://www.abanet.org/environlcommittees/superfundnatresdamages/newsletter/m
    arO6/superfundO3 06 .pdf
    The
    Star-Ledger
    (Aug.
    12, 2006).
    DEP
    to
    review
    sites
    after
    day-care
    fiasco.
    Newark,
    New
    Jersey.
    Available
    from
    the
    Illinois
    EPA
    library
    upon
    request.
    U.S.
    EPA
    (Mar.
    2008).
    Brownfields
    Technical
    Primer:
    Vapor
    Intrusion
    Considerations
    for
    Redevelopment.
    EPA 542-R-08-00
    1.
    http
    ://www.brownfieldstsc.org/pdfs/BTSC%2OVapor%20lntrusion%20Considerat
    ions%20for%20Redevelopment%2OEPA%20542-R-08-00
    1
    .pdf

    BEFORE
    THE
    ILLINOIS
    POLLUTION
    CONTROL
    BOARD
    SEp
    IN
    THE
    MATTER
    OF:
    )
    V
    )
    2008
    PROPOSED AMENDMENTS
    TO
    )
    R09-
    Uti
    Contro’IOIS
    TIERED
    APPROACH
    TO
    CORRECTIVE
    )
    (Rulemaking-Land)
    ACTION
    OBJECTIVES
    )
    (35
    Iii
    Adm
    Code
    742)
    )
    STATEMENT
    OF
    REASONS
    The
    Illinois
    Environmental
    Protection
    Agency
    (“Illinois
    EPA”)
    hereby
    submits
    its
    Statement
    of
    Reasons
    for
    the
    above-captioned
    matter
    to
    the
    Illinois
    Pollution
    Control
    Board
    (“Board”) pursuant
    to
    Section
    27
    of
    the
    Illinois
    Environmental
    Protection
    Act
    (“Act”)(41
    5
    ILCS
    5/27)
    and
    35
    Ill.
    Adm.
    Code
    102.200
    and
    102.202.
    I.
    FACTS
    IN
    SUPPORT,
    PURPOSE,
    AND
    EFFECT
    A.
    Background
    On
    December
    15,
    1995,
    P.A.
    89-43
    1
    (which
    added
    a
    new
    Title
    XVII
    to the
    Act)
    was
    signed
    into
    law by
    Governor
    Edgar.
    Pursuant
    to
    Section
    58.11(c)
    of the
    Act,
    Illinois
    EPA
    proposed
    regulations
    prescribing
    procedures
    and
    standards
    for
    the
    Illinois
    EPA’s
    administration
    of
    its
    duties
    under
    Title
    XVII.
    That
    proposal
    became
    known
    as
    the Tiered
    Approach
    to
    Corrective
    Action
    Objectives
    (“TACO”) under
    35 Ill.
    Adm.
    Code
    742,
    which
    established
    a
    system
    whereby sites
    undergoing
    remediation
    in
    the
    Site Remediation
    Program
    (“SRP”),
    the
    Leaking
    Underground
    Storage
    Tank
    (“LUST”)
    Program,
    and RCRA
    Part
    B Permits
    and
    Closures
    could
    use
    the methodology
    set
    forth
    in the
    TACO
    rules
    to
    determine
    remediation
    objectives.
    Since
    the
    inception
    of
    the
    initial
    rulemaking,
    TACO’
    s
    applicability
    has
    been
    expanded
    outside
    the
    three
    programs
    listed
    above.
    Part
    742
    established
    procedures
    for
    developing
    remediation
    objectives
    based
    on
    various
    risks
    to
    human
    health
    posed
    by environmental
    conditions
    at
    a site.
    Because
    human
    health
    may
    be
    1

    impacted
    by
    any
    type
    of
    environmental
    contamination,
    whether
    it
    originates
    from
    petroleum,
    metals,
    or some
    other
    type
    of waste,
    it
    was
    logical
    to
    create
    a single
    set of
    procedures
    that
    any
    of
    the
    land
    remediation
    programs
    could
    use
    to address
    contamination
    at
    any
    given
    site.
    What
    resulted
    was
    the
    TACO
    methodology,
    whereby
    risks
    posed
    to
    human
    health
    are
    evaluated,
    site
    conditions
    are
    assessed,
    and
    individuals
    propose
    remediation
    objectives
    to mitigate
    conditions
    at
    the
    site
    so that
    they
    no longer
    pose
    a
    threat
    to
    human
    health.
    The
    Board
    adopted
    TACO
    on
    June
    5, 1997
    (with
    three
    sub-dockets
    being
    adopted
    shortly
    thereafter).
    In
    May
    of
    2000,
    Illinois
    EPA
    proposed
    amendments
    to TACO
    that
    were
    necessitated
    by
    new
    technology,
    science,
    and
    programmatic
    changes.
    The
    Board
    adopted
    those
    amendments
    in
    December
    of
    2000,
    with
    two
    sub-dockets
    being
    adopted
    shortly
    thereafter.
    In
    2002
    and
    again
    in
    2005,
    the
    Board
    adopted
    additional
    amendments
    to
    TACO
    for
    the purpose
    of
    keeping
    the
    TACO
    procedures
    and
    requirements
    current
    and
    to
    improve
    standards
    and
    procedures
    so
    that
    end
    users
    of the
    rules
    can
    achieve
    accurate
    data
    results
    that
    are
    protective
    of human
    health.
    The
    new
    amendments
    propose
    to add
    the
    indoor
    inhalation
    exposure
    route
    to
    the
    existing
    risk-based
    methodology. The
    indoor
    inhalation
    pathway
    will
    be
    managed
    similarly
    to
    the
    current
    exposure
    routes
    under
    TACO.
    It follows
    the
    basic
    framework
    of
    TACO’s
    three
    tiers,
    calculates
    both
    residential
    and
    industrial/commercial
    remediation
    objectives,
    and
    allows
    for
    pathway
    exclusion.
    Individuals
    will
    assess
    indoor
    inhalation
    exposure
    using
    collected
    soil
    and
    groundwater
    or
    soil
    gas
    data
    and
    then
    apply
    a modified
    Johnson
    and
    Ettinger
    (J&E)
    model
    to
    develop
    remediation objectives.
    The
    modified
    J&E
    model
    simulates
    the
    migration
    of contaminants
    from
    a
    subsurface source
    to
    the air
    inside
    a
    building.
    Additional
    equations
    are presented
    that
    calculate
    acceptable
    soil,
    groundwater
    and
    soil
    gas
    remediation
    objectives.
    This
    modified
    J&E
    model
    used
    2

    in
    TACO
    contains
    18
    equations
    and
    56 parameters.
    Like
    the
    Soil
    Screening
    Level
    (“SSL”)
    and
    Risk
    Based
    Corrective
    Action
    (“RBCA”) models
    used
    for
    other
    exposure
    routes,
    modified
    J&E
    model
    parameters
    have
    conservative
    default
    values
    under
    Tier
    1
    that
    can
    be substituted
    for
    site-
    specific
    conditions
    under
    Tier
    2.
    Tier
    3
    allows
    the
    use
    of subsiab
    soil
    gas
    data
    to
    establish
    remediation
    objectives.
    A
    new
    Subpart
    L
    provides
    requirements
    for building
    control
    technologies
    to
    mitigate
    the
    potential
    for
    contaminated soil
    gas to
    enter
    the
    indoor
    air,
    an approach
    similar
    to
    engineered
    barriers
    under
    Subpart
    K.
    The
    effect
    of
    the
    proposed
    amendments
    is
    to
    protect
    building
    occupants
    from
    volatile
    chemicals
    that
    have
    the
    potential
    to migrate
    from
    the soil
    and
    groundwater
    to
    indoor
    air.
    This
    migration
    process
    has
    been
    colloquially
    referred
    to as
    “vapor
    intrusion.”
    There
    is
    no
    legislative
    or
    regulatory
    requirement
    to propose
    these
    amendments.
    Illinois
    EPA
    wants
    to
    broaden
    the
    exposure
    routes
    evaluated
    so as
    to fully
    protect
    public
    health
    from
    contaminated
    sites
    and
    to
    add more
    certainty
    to
    the release
    of liability
    provided
    by
    the
    No
    Further
    Remediation
    determination.
    Until
    now,
    Illinois
    EPA
    has
    evaluated
    vapor
    intrusion
    on a
    limited
    scale,
    when
    major
    indoor
    inhalation
    risks
    are
    suspected;
    case
    studies
    of
    these
    experiences
    will
    be submitted
    to
    the
    Board
    by
    Illinois
    EPA
    as
    part
    of its
    testimony.
    U.S.
    EPA
    recommends
    screening
    all
    sites
    that
    have
    the
    potential
    to
    cause
    indoor
    inhalation
    health
    risks.
    Other
    States
    have
    experienced
    public
    health
    crises
    and
    ensuing
    legal
    and
    financial
    challenges
    caused
    by
    vapor
    intrusion
    exposures
    at
    sites
    where
    the
    indoor
    inhalation
    pathway
    was not
    evaluated
    as part
    of
    the regulatory
    cleanup
    prior
    to
    issuance
    of
    the No
    Further
    Remediation
    letter
    or its
    equivalent.
    In
    March
    2008,
    ASTM
    International issued
    its Standard
    Practice
    for Assessment
    for Vapor
    Intrusion
    into
    Structures
    on
    Property
    Involved
    in Real
    Estate
    Transactions.
    Section
    9.2.2
    of
    the
    Standard
    instructs
    users
    to
    3

    apply
    State
    generic
    risk-based
    concentrations.
    Illinois
    EPA’s
    amendments
    would
    establish
    such
    numbers.
    The
    amendments
    also
    propose
    to
    update
    remediation
    objectives
    for all
    of the
    exposure
    routes
    and
    their
    corresponding
    populations:
    residential,
    industrial/commercial
    and
    construction
    worker.
    These
    changes
    are
    needed
    to keep
    the
    rule
    current
    with
    the
    scientific
    literature
    and
    protective
    of human
    health.
    B.
    Regulatory
    Development
    Illinois
    EPA
    convened
    an internal
    workgroup
    to create
    a
    methodology
    for
    evaluating
    the
    indoor
    inhalation
    pathway that
    would
    be
    compatible
    with
    and
    integrated
    into
    the
    existing
    TACO
    regulations. The
    workgroup
    began
    by
    reviewing
    the
    draft
    vapor
    intrusion
    guidance
    prepared
    by
    U.S.
    EPA
    and
    state-specific
    guidance
    prepared
    by New
    Jersey,
    New
    York,
    Pennsylvania,
    Missouri
    and
    Colorado,
    among
    others.
    Illinois
    EPA
    also
    retained
    the
    services
    of
    the
    RAIVI
    Group,
    a
    subcontractor
    with
    expert
    knowledge
    in contaminant
    fate
    and
    transport.
    On
    May
    25,
    2007,
    Illinois
    EPA
    sent
    a
    first
    working
    draft
    of
    the
    proposed
    amendments
    to
    the
    chairperson of
    the
    Site
    Remediation
    Advisory
    Committee
    (“SRAC”)
    for
    distribution
    to
    its
    members
    and
    the regulated
    community.
    After
    they
    had
    ample
    opportunity
    to
    review
    and
    comment, Illinois
    EPA
    met
    with
    SRAC
    members
    to
    discuss
    their
    comments
    and suggestions.
    Those
    meetings
    occurred
    on August
    27,
    2007;
    September
    27, 2007;
    November
    2,
    2007;
    and
    February
    6,
    2008.
    On
    May
    23,
    2008,
    Illinois
    EPA
    sent
    a
    revised
    draft
    to
    SRAC
    addressing
    the
    many
    issues
    raised
    by
    SRAC
    in writing
    and
    in
    meetings.
    On
    June
    19,
    2008,
    Illinois
    EPA
    met
    with
    SRAC
    to
    discuss
    the
    May
    2008
    version.
    That
    meeting
    resulted
    in
    additional
    changes
    which
    are
    now
    reflected
    in the
    proposal
    filed
    with
    the Board.
    Illinois
    EPA
    appreciates
    the
    comments,
    4

    issues
    and
    concerns
    raised
    by
    SRAC
    and
    the
    regulated
    community.
    Their
    thoughtfulness
    and
    thoroughness
    significantly
    improved
    the
    Agency’s
    proposal.
    Affected
    Sources
    and
    Facilities
    and
    Economic
    Impact
    Persons
    (as
    defined
    in
    Section
    58.2
    of
    the
    Act)
    affected
    by
    this
    rule
    include
    any
    and
    all
    persons
    undergoing
    remediation
    who
    are
    entitled
    to use
    a risk-based
    methodology
    for
    determining
    remediation
    objectives.
    Such
    persons
    would
    include,
    but
    not
    necessarily
    be
    limited
    to,
    those
    conducting
    remediation
    under
    the
    SRP,
    the LUST
    Program,
    RCRA
    Part
    B
    permits
    and
    closures,
    or other
    Illinois
    EPA
    remediation
    programs.
    The
    use
    of
    TACO
    in
    conjunction
    with
    various
    program
    regulations
    has
    accomplished
    the
    goal
    of putting
    many
    sites
    back
    into
    safe,
    productive
    use
    while
    significantly
    decreasing
    remediation
    expenses statewide.
    C.
    Environmental,
    Technical,
    and
    Economic
    Justification
    The
    original
    SSL
    and
    RBCA
    models
    from
    which
    TACO
    evolved
    included
    the
    indoor
    inhalation
    exposure
    route.
    Back
    in
    1997,
    when
    TACO
    was
    first
    adopted,
    Illinois
    EPA
    omitted
    the
    indoor
    inhalation
    exposure route
    intentionally,
    due
    to a
    lack
    of
    confidence
    in
    the existing
    scientific data.
    Ten years
    later,
    research
    gaps
    have
    narrowed
    substantially
    and
    Illinois
    EPA
    has
    been
    able
    to calculate
    soil,
    groundwater
    and
    soil
    gas
    remediation
    objectives
    for
    indoor
    inhalation
    using
    generally
    accepted
    modeling
    equations.
    The
    proposed
    indoor
    inhalation
    amendments
    will
    increase
    the
    cost
    of
    some
    site
    cleanups
    but
    will
    bring
    three
    important
    benefits.
    First,
    Illinois
    residents
    will
    be
    better
    protected
    from
    volatile
    chemicals
    migrating
    from
    contaminated
    sites.
    Second,
    site
    owners
    or
    other
    remediation
    applicants will
    receive
    expanded
    liability
    relief
    through
    issuance
    of
    a No
    Further
    Remediation
    letter
    that takes
    the indoor
    inhalation
    exposure
    route
    into
    account.
    Third,
    establishing
    5

    remediation
    objectives
    for the
    indoor
    inhalation
    pathway
    will
    facilitate
    property
    transactions.
    The
    benefit
    to the
    public
    should
    outweigh
    any
    additional
    remediation
    costs.
    The
    extent
    of the
    anticipated
    cost
    increases
    is
    unknown
    and
    expected
    to vary
    widely
    depending
    on site
    and contaminant
    characteristics
    and
    the
    willingness
    of affected
    property
    owner(s)
    to accept
    building
    control
    technologies
    and
    institutional
    controls.
    To
    further
    ease
    implementation
    of the
    new indoor
    inhalation
    pathway,
    the internal
    agency
    workgroup
    is
    preparing
    a
    guidance
    document
    containing
    detailed
    information
    on how
    to
    manage
    the exposure
    route
    under
    TACO’s
    three
    tiers.
    II.
    THE
    PROPOSED
    AMENDMENTS
    Inserting
    a
    new exposure
    route
    into
    TACO
    requires
    comprehensive
    changes
    to
    the existing
    regulations.
    As
    would
    be
    expected,
    these
    proposed
    amendments
    contain
    new
    definitions,
    equations,
    parameters,
    default
    remediation
    objectives,
    and
    mechanisms for
    managing
    the
    indoor
    inhalation
    pathway.
    What
    follows
    is a general
    overview
    of
    the changes
    proposed.
    A.
    Subpart
    A
    Illinois
    EPA
    proposes
    language
    in
    Sections
    742.110
    and 742.115
    to
    account
    for
    the
    inclusion
    of the
    modified
    J&E
    model
    and
    the
    indoor
    inhalation
    exposure
    route,
    respectively.
    B.
    Subpart
    B
    Amendments
    to Subpart
    B
    include:
    adding
    definitions
    for
    “Building,”
    “Building
    Control
    Technology,” “Volatile
    Chemicals,”
    “Soil
    Gas,”
    and
    “Soil
    Vapor Saturation
    Limit”;
    adding
    new
    incorporations
    by
    reference;
    adding
    an exception
    in
    Section
    742.225(b)(5)
    stating
    that
    compositing
    and
    averaging
    of
    sample
    results
    are prohibited
    under
    the
    indoor
    inhalation
    exposure
    route,
    except
    as
    approved
    by the
    Agency
    in
    Tier 3;
    and
    adding
    new
    Sections
    742.222
    and
    6

    742.227
    to
    allow
    for
    the
    use
    of
    soil
    gas data
    when
    determining
    remediation
    objectives
    for
    the
    indoor
    inhalation
    exposure
    route.
    C.
    Subpart
    C
    Illinois
    EPA
    inserted
    “Outdoor”
    before
    “Inhalation
    Exposure
    Route”
    in Section
    742.310
    and
    added
    Section
    742.3
    12 that
    states
    when
    the
    indoor
    inhalation
    exposure
    route
    may
    be
    excluded
    from
    consideration.
    As part
    of
    Section
    742.3 12,
    the pathway
    may be
    excluded
    by
    use
    of
    a
    building
    control
    technology
    that meets
    the
    requirements
    of Subpart
    L.
    D.
    SubpartE
    Illinois
    EPA
    added
    Section
    742.5
    15,
    which
    explains
    how
    to
    use the
    Tier
    1 indoor
    inhalation
    remediation
    objectives
    for
    soil gas,
    soil and
    groundwater
    in Appendix
    B,
    Table
    G.
    Under
    the
    indoor
    inhalation
    pathway,
    unless
    the
    route
    is excluded
    from
    consideration
    under
    Subpart
    C,
    site
    evaluators
    must
    demonstrate
    compliance
    with either:
    1)
    soil
    and
    groundwater,
    or
    2) soil
    gas.
    E.
    Subpart
    F
    Illinois
    EPA
    modified
    Section
    742.600
    to state
    that
    a
    calculated
    Tier 2 indoor
    inhalation
    remediation
    objective
    for
    soil cannot
    exceed
    the
    soil
    saturation
    limit
    and
    that a
    corresponding
    remediation
    objective
    for
    soil gas
    cannot
    exceed
    the
    soil
    vapor
    saturation
    limit.
    F.
    SubpartG
    Amendments
    to Subpart
    G
    include:
    changing
    Section
    742.700(g)
    to exclude
    the
    construction
    worker
    population
    from
    the indoor
    inhalation
    exposure
    route;
    adding
    Section
    742.717
    to
    require
    use
    of the
    modified
    J&E
    model
    and
    to explain
    how
    the
    J&E equations
    for
    soil
    and
    soil gas
    data
    are to
    be
    applied;
    and under
    Sections
    742.7
    17(i) and
    (j),
    describing
    when
    the
    7

    soil
    saturation
    limit
    and the soil
    vapor
    saturation
    limit
    are
    to be
    used as the
    soil and
    soil
    gas
    remediation
    objectives,
    respectively.
    G.
    Subpart H
    Amendments
    to Subpart
    H include:
    adding
    Section
    742.805(e)
    to
    require
    individuals
    to
    use Section
    742.8 12
    when developing
    Tier
    2 groundwater
    remediation
    objectives
    for the
    indoor
    inhalation
    exposure
    route; and
    adding
    Section
    742.8
    12 to explain
    how
    the
    J&E
    equations
    are
    to
    be used for
    developing
    groundwater
    remediation
    objectives.
    H.
    Subpart I
    Amendments
    to Subpart
    I include:
    adding Section
    742.935(a)
    to
    allow
    exposure
    route
    exclusion
    (as
    an alternative
    to Section
    742.312)
    for
    the
    indoor inhalation
    exposure
    route;
    adding
    Section
    742.935(b)
    to
    allow
    the use
    of soil
    gas
    data
    (as
    an alternative
    to
    Section
    742.227)
    to
    establish
    remediation
    objectives
    for
    the indoor
    inhalation
    exposure
    route;
    adding
    Section
    742.935(c)
    to allow
    the
    use of
    building control
    technologies
    (as an alternative
    to
    those
    described
    in Subpart
    L) as a means
    to prevent
    or mitigate
    human
    exposures
    under
    the indoor
    inhalation
    exposure
    route;
    and
    adjusting language
    elsewhere
    in this Subpart
    to account
    for
    this new
    Section.
    I.
    SubpartJ
    Illinois
    EPA
    added
    Section
    742.1000(a)(7)
    to
    require
    the use of
    institutional
    controls
    whenever
    remediation
    objectives
    are based
    on a building
    control
    technology.
    New
    Section
    742.1015(j)
    states
    that a groundwater
    ordinance
    may
    not
    be used
    to exclude
    the indoor
    inhalation
    exposure
    route.
    This
    is because
    an ordinance
    restricting
    the
    source of drinking
    water
    would
    be
    incapable
    of protecting
    the enclosed
    air
    space of
    a building
    from the migration
    of
    contaminants
    in the
    groundwater.
    J.
    SubpartL
    8

    Illinois
    EPA created
    this
    subpart
    to provide
    requirements
    for four
    types
    of
    building
    control
    technologies:
    sub-slab
    depressurization
    systems,
    sub-membrane
    depressurization
    systems,
    membrane
    barrier
    systems,
    and
    barriers
    created
    from
    geologic
    materials.
    K.
    Appendix
    A, Table
    A
    Illinois
    EPA
    updated
    the
    soil saturation
    limits
    due
    to revised
    chemical
    and
    physical
    properties
    and
    added
    a column
    to
    distinguish
    between
    the
    outdoor
    inhalation
    exposure
    route
    and
    the
    soil component
    of the
    groundwater
    ingestion
    exposure
    route.
    The difference
    in
    values
    is
    based
    on
    the fraction
    of
    organic
    carbon
    content
    (f
    0
    ).
    Three
    footnotes
    have
    also
    been
    added.
    L.
    AppendixA,TableE
    Illinois
    EPA
    added
    fifteen
    chemicals
    based
    on
    the
    proposed
    Groundwater
    Quality
    Standards
    (35
    Iii.
    Adm.
    Code
    Part
    620).
    The
    entire
    table
    has
    been
    alphabetized
    by
    target
    organ.
    M.
    Appendix
    A,
    Table
    F
    Illinois
    EPA added
    fifteen
    chemicals
    based
    on the
    proposed
    Groundwater
    Quality
    Standards
    (35
    Ill. Adm.
    Code
    Part
    620).
    The entire
    table
    has
    been
    alphabetized
    by target
    organ.
    N.
    Appendix
    A, Table
    I
    Illinois
    EPA
    added
    six
    new
    chemicals
    and
    updated
    some of
    the
    Acceptable
    Detection
    Limits
    (“ADLs”).
    Some of
    the toxicity
    values
    changed,
    resulting
    in
    changes
    to
    the
    Class
    I
    Groundwater
    Remediation
    Objectives
    and
    the
    1 in
    1,000,000
    Cancer
    Risk
    Concentration.
    0.
    Appendix
    A,
    Table
    J
    This
    is a
    new table
    identifying
    the 59
    TACO
    volatile
    chemicals
    that
    are
    considered
    contaminants
    of
    concern
    for
    the
    indoor
    inhalation
    exposure
    route.
    P.
    Appendix
    A,
    Table
    K
    This
    is a
    new
    table identifying
    the
    soil
    vapor saturation
    limits
    for
    the
    volatile
    9

    chemicals
    of
    concern
    for
    the
    indoor
    inhalation
    exposure
    route.
    Q.
    Appendix
    A,
    Table
    L
    This is
    a new
    table
    identifying
    the
    soil saturation
    limits
    for
    volatile
    chemicals
    for
    the
    indoor
    inhalation
    exposure
    route.
    A
    separate
    table
    is
    needed
    because
    the
    calculation
    of
    saturation
    limits
    for the
    indoor
    inhalation
    pathway
    uses
    parameter
    values
    different
    than
    those
    used
    to
    create
    Appendix
    A,
    Table
    A (i.e.,
    fraction
    organic
    carbon
    content
    and
    system
    temperature).
    R.
    Appendix
    B, Table
    A
    Illinois EPA
    updated
    remediation
    objectives
    for
    all
    exposure
    routes
    using
    the
    most
    current
    toxicity
    values
    and
    physical
    and
    chemical
    parameter
    values.
    We
    also
    updated
    the
    previously
    titled
    “Inhalation”
    column
    to “Outdoor Inhalation.”
    We
    modified
    two
    footnotes
    and
    added
    three
    others.
    S.
    Appendix
    B,
    Table
    B
    Illinois
    EPA
    updated
    remediation
    objectives
    for
    all
    exposure
    routes
    using
    the
    most
    current
    toxicity
    values
    and
    physical
    and
    chemical
    parameter
    values.
    We
    also
    updated
    the
    previously titled
    “Inhalation”
    columns
    to
    “Outdoor
    Inhalation.”
    We
    modified
    two
    footnotes
    and
    added
    four
    others.
    T.
    Appendix
    B,
    Table
    C
    Illinois
    EPA
    updated
    the
    pH specific
    soil
    remediation
    objectives
    for
    arsenic
    and
    added
    a
    footnote extending
    the pH
    range
    from
    8.75-9
    to
    8.75-11.0
    for
    Lead.
    U.
    Appendix
    B,
    Table
    D
    Illinois
    EPA
    added
    a
    footnote
    extending
    the
    pH
    range
    from
    8.75-9
    to
    8.75-11.0
    for Lead.
    V.
    Appendix
    B,
    Table
    E
    10

    Illinois
    EPA
    updated
    remediation
    objectives
    for
    the
    groundwater
    ingestion
    exposure
    route
    using
    the most
    current
    toxicity
    values
    and physical
    and chemical
    parameter
    values.
    We
    also
    renamed
    this table
    and
    added
    fifteen
    chemicals
    based
    on
    the
    proposed
    Groundwater
    Quality
    Standards
    (35
    Iii. Adm.
    Code
    Part 620).
    We
    added
    six
    new footnotes.
    W.
    Appendix
    B,
    Table
    F
    Illinois
    EPA
    updated
    the
    GW
    0b
    concentrations
    to reflect
    changes
    in
    the toxicity
    values
    and
    to
    keep
    pace
    with
    the
    proposed
    amendments
    to
    the
    Groundwater
    Quality
    Standards
    (35
    Iii.
    Adm.
    Code
    Part
    620).
    Fifteen
    new
    chemicals
    and
    one
    footnote
    have
    been
    added.
    X.
    Appendix
    B, Table
    G
    This
    is
    a new
    table
    containing
    the
    Tier
    1 remediation
    objectives
    for volatile
    chemicals
    under
    the
    indoor
    inhalation
    pathway.
    Residential
    and
    industriallcommercial
    values
    are
    given
    for
    soil
    gas,
    soil
    and
    groundwater.
    Y.
    Appendix
    C,
    Table
    B
    A
    few SSL
    parameters
    have
    been
    updated.
    Sources
    for
    the
    toxicity
    values
    have
    been
    updated
    to
    reflect
    changes
    in the
    USEPA’s
    hierarchy
    of human
    health
    toxicity
    values.
    Z.
    Appendix
    C,
    TableD
    A
    few
    RBCA
    parameters
    have
    been
    updated.
    Sources
    for
    the
    toxicity
    values
    have
    been
    updated
    to
    reflect
    changes
    in
    the
    USEPA’s hierarchy
    of human
    health
    toxicity
    values.
    AA.
    Appendix
    C,
    Table
    E
    Illinois
    EPA
    updated
    the
    default
    values
    for
    all chemicals
    (not
    just
    volatile
    chemicals)
    to
    be
    consistent with current
    scientific
    literature.
    We
    also
    inserted
    a new
    column
    of default
    values
    for
    Dimensionless
    Henry’s
    Law
    Constant
    at
    130
    C
    and
    added
    three
    new
    footnotes.
    All
    values
    are
    now
    expressed
    in
    scientific
    notation.
    11

    BB.
    Appendix
    C,
    Table
    F
    Illinois
    EPA
    added
    new
    methods
    for
    determining
    the
    following
    physical
    soil
    parameters:
    total
    soil
    porosity,
    air-filled
    soil
    porosity,
    and
    water-filled
    soil
    porosity.
    CC.
    Appendix
    C,
    Table
    I
    Illinois
    EPA
    added
    MCPP
    since
    it
    is
    one
    of
    the
    new
    chemicals
    proposed
    under
    the
    Groundwater
    Quality
    Standards
    (35 Ill.
    Adm.
    Code
    Part
    620)
    and
    deleted 2,4,5-TP
    (Silvex)
    because
    it no
    longer
    ionizes
    over
    the
    pH
    range
    of 4.5-9.0.
    DD.
    Appendix
    C, Table
    L
    This
    is a new
    table
    containing
    the
    J&E
    equations
    used
    in
    calculating
    remediation
    objectives
    for
    the
    indoor
    inhalation
    exposure
    route.
    EE.
    Appendix
    C, Table
    M
    This
    is
    a
    new
    table
    containing
    the
    J&E
    parameters
    used
    in
    calculating
    remediation
    objectives
    for
    the
    indoor
    inhalation
    exposure
    route.
    III.
    AGENCY
    WITNESSES
    AND
    SYNOPSIS
    OF
    TESTIMONY
    Illinois
    EPA
    will
    provide
    five
    witnesses
    who
    will
    be
    available
    to testify
    at
    hearing.
    The
    witnesses are
    Gary
    King,
    Thomas
    Homshaw,
    TraceyHurley,
    and
    Joyce
    Munie
    from
    Illinois
    EPA
    and
    Atul
    Saihotra
    from
    the
    RAM
    Group.
    Illinois
    EPA
    will
    submit
    written
    testimony
    in
    advance
    of
    the hearings
    pursuant
    to any
    hearing
    officer
    order
    that
    follows
    this
    proposal.
    Illinois
    EPA
    respectfully
    requests
    that
    the
    Board
    allow
    oral
    testimony
    of
    Illinois
    EPA’s witnesses
    in panel
    format
    rather
    than
    calling
    each
    individually.
    This
    has
    streamlined
    several
    regulatory
    hearings
    in the
    past
    and
    allows
    Illinois
    EPA
    to
    more
    fully
    respond
    to
    questions
    during
    the
    hearing,
    thereby
    promoting
    a
    more
    complete
    hearing
    record.
    12

    As
    a note
    to the
    Board,
    Illinois
    EPA
    does
    not
    have
    a Notice
    or
    Service
    List
    for
    purposes
    of this
    proposal.
    Therefore,
    we
    are
    sending
    this
    proposal
    to the
    individuals
    required
    by the
    Board’s
    procedural
    rules.
    Illinois
    EPA
    requests
    that
    once
    the Board
    establishes
    Notice
    and
    Service
    lists
    for
    this
    rulemaking
    that
    it send
    those
    to
    Illinois
    EPA
    so
    that
    we can
    properly
    serve
    parties
    with
    any
    future
    submittals.
    WHEREFORE,
    Illinois
    EPA
    requests
    that
    the Board
    accept
    this
    proposal
    in
    its
    entirety
    for hearing.
    Respectfully
    submitted,
    ILLINOIS
    ENVIRONMENTAL
    PROTECTION
    AGENCY
    Assistan
    Counsel
    Division
    of Legal
    Counsel
    DATED:
    September
    2, 2008
    1021
    North
    Grand
    Ave.
    East
    P.O.
    Box
    19276
    Springfield,
    Illinois
    62794-9276
    (217)
    782-5544
    13

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    TITLE
    35: ENVIRONMENTAL
    PROTECTION
    SUBTITLE
    G:
    WASTE
    DISPOSAL
    CHAPTER
    I: POLLUTION
    CONTROL
    BOARD
    SUBCHAPTER
    f:
    RISK
    BASED
    CLEANUP
    OBJECTIVES
    PART
    742
    TIERED
    APPROACH
    TO
    CORRECTIVE
    ACTION
    OBJECTIVES
    SUBPART
    A:
    INTRODUCTION
    Section
    742.100
    Intent
    and
    Purpose
    742.105
    Applicability
    742.110
    Overview
    of
    Tiered
    Approach
    742.115
    Key
    Elements
    742.120
    Site
    Characterization
    SUBPART
    B:
    GENERAL
    Section
    742.200
    Definitions
    742.205
    Severability
    742.210
    Incorporations
    by Reference
    742.2
    15
    Determination
    of Soil
    Attenuation
    Capacity
    742.220
    Determination
    of
    Soil
    Saturation
    Limit
    742.222
    Determination
    of Soil
    Vapor
    Saturation
    Limit
    742.225
    Demonstration
    of
    Compliance
    with
    Remediation
    Objectives
    742.227
    Demonstration
    of Compliance
    with
    Soil Gas
    Remediation
    Objectives
    for
    the
    Indoor
    Inhalation
    Exposure
    Route
    742.230
    Agency
    Review
    and
    Approval
    SUBPART
    C: EXPOSURE
    ROUTE
    EVALUATIONS
    Section
    742.300
    Exclusion
    of
    Exposure
    Route
    742.305
    Contaminant
    Source
    and Free
    Product
    Determination
    742.3
    10
    Outdoor
    Irthalation
    Exposure
    Route
    742.312
    Indoor
    Inhalation
    Exposure
    Route
    742.315
    Soil
    Ingestion
    Exposure
    Route
    742.320
    Groundwater
    Ingestion
    Exposure
    Route

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF PROPOSED
    AMENDMENTS
    SUBPART
    D:
    DETERMINING
    AREA
    BACKGROUND
    Section
    742.400
    Area
    Background
    742.405
    Determination
    of
    Area Background
    for
    Soil
    742.410
    Determination
    of Area
    Background
    for Groundwater
    742.415
    Use
    of Area
    Background
    Concentrations
    SUBPART
    E: TIER
    1
    EVALUATION
    Section
    742.500
    Tier
    1 Evaluation
    Overview
    742.505
    Tier 1
    Soil and
    Groundwater
    Remediation
    Objectives
    742.5
    10
    Tier
    1 Remediation
    Objectives
    Tables
    742.5
    15
    Tier 1
    Remediation
    Objectives
    Table for the
    Indoor
    Inhalation
    Exposure
    Route
    SUBPART
    F:
    TIER
    2
    GENERAL
    EVALUATION
    Section
    742.600
    Tier
    2
    Evaluation
    Overview
    742.605
    Land
    Use
    742.6 10
    Chemical
    and
    Site Properties
    SUBPART
    G:
    TIER 2 SOIL
    EVALUATION
    Section
    742.700
    Tier
    2
    Soil Evaluation
    Overview
    742.705
    Parameters
    for
    Soil
    Remediation
    Objective
    Equations
    742.7
    10
    SSL Soil
    Equations
    742.715
    RBCA
    Soil Equations
    742.717
    Indoor
    Inhalation
    Equations
    for
    Soil and
    Soil
    Gas
    742.720
    Chemicals
    with
    Cumulative
    Noncarcinogenic
    Effects
    SUBPART
    H: TIER
    2 GROUNDWATER
    EVALUATION
    Section
    742.800
    Tier
    2 Groundwater
    Evaluation
    Overview
    742.805
    Tier 2 Groundwater
    Remediation
    Objectives
    742.8
    10
    Calculations
    to
    Predict
    Impacts
    from Remaining
    Groundwater
    Contamination
    742.8 12
    Indoor
    Inhalation
    Equations

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF PROPOSED
    AMENDMENTS
    SUBPART
    I:
    TIER
    3
    EVALUATION
    Section
    742.900
    Tier
    3
    Evaluation
    Overview
    742.905
    Modifications
    of
    Parameters
    742.9
    10
    Alternative
    Models
    742.915
    Formal
    Risk
    Assessments
    742.920
    Impractical
    Remediation
    742.92
    5
    Exposure
    Routes
    742.930
    Derivation
    of
    Toxicological
    Data
    742.93
    5
    Indoor
    Inhalation
    Exposure
    Route
    SUBPART
    J: iNSTITUTIONAL
    CONTROLS
    Section
    742.1000
    Institutional Controls
    742.1005
    No
    Further
    Remediation
    Letters
    742.1010
    Environmental
    Land
    Use
    Controls
    742.1012
    Federally
    Owned
    Property:
    Land
    Use
    Control
    Memoranda
    of
    Agreement
    742.1015
    Ordinances
    742.1020
    Highway Authority
    Agreements
    and
    Highway
    Authority
    Agreement
    Memoranda
    of
    Agreement
    SUBPART
    K:
    ENGINEERED BARRIERS
    Section
    742.1100
    Engineered
    Barriers
    742.1105
    Engineered Barrier
    Requirements
    SUBPART L:
    BUILDING
    CONTROL
    TECHNOLOGIES
    Section
    742.1200
    Building
    Control
    Technologies
    742.1205
    Building
    Control
    Technology
    Proposals
    742.1210
    Building
    Control
    Technology
    Requirements
    APPENDIX A
    General
    ILLUSTRATION
    A Developing
    Soil Remediation
    Objectives Under
    the
    Tiered
    Approach
    TLLUSTRATION
    B
    Developing
    Groundwater
    Remediation
    Objectives
    Under
    the
    Tiered
    Approach

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED AMENDMENTS
    TABLE
    A
    Soil
    Saturation
    Limits
    (Csat)
    for
    Chemicals
    Whose
    Melting
    Point
    is Less
    than
    30°C
    TABLE
    B
    Tolerance
    Factor
    (K)
    TABLE
    C
    Coefficients
    {ANJ÷1}
    for
    W
    Test
    of Normality,
    for
    N2(1)50
    TABLE
    D
    Percentage
    Points
    of
    the W
    Test
    for
    n=3(1)50
    TABLE
    E
    Similar-Acting
    Noncarcinogenic
    Chemicals
    TABLE
    F
    Similar-Acting
    Carcinogenic
    Chemicals
    TABLE
    G
    Concentrations
    of
    Inorganic
    Chemicals
    in
    Background
    Soils
    TABLE
    H
    Concentrations
    of
    Polynuclear
    Aromatic
    Hydrocarbon
    Chemicals
    in
    Background
    Soils
    TABLE
    I
    Chemicals
    Whose
    Tier
    1
    Class
    I Groundwater
    Remediation
    Objective
    Exceeds
    the
    1 in
    1,000,000
    Cancer
    Risk
    Concentration
    TABLE
    J
    List
    of TACO
    Volatile
    Chemicals
    for
    the
    Indoor
    Inhalation
    Exposure
    Route
    TABLE
    K
    Soil
    Vapor
    Saturation Limits
    (CSa
    t
    )
    for Volatile
    Chemicals
    TABLE
    L
    Soil
    Saturation
    Limits
    (C)
    for
    Volatile
    Chemicals
    for
    the
    Indoor
    Inhalation
    Exposure
    Route
    APPENDIX
    B
    Tier
    1 Illustrations
    and Tables
    ILLUSTRATION
    A
    Tier
    1 Evaluation
    TABLE
    A
    Tier
    1
    Soil
    Remediation
    Objectives
    for Residential
    Properties
    TABLE
    B
    Tier
    1 Soil
    Remediation
    Objectives
    for
    Industrial/Commercial
    Properties
    TABLE
    C
    pH
    Specific
    Soil
    Remediation
    Objectives
    for
    Inorganics
    and
    Ionizing
    Organics
    for
    the
    Soil
    Component
    of the
    Groundwater
    Ingestion
    Route
    (Class
    I
    Groundwater)
    TABLE
    D
    pH
    Specific
    Soil Remediation
    Objectives
    for
    Jnorganics
    and
    Ionizing
    Organics
    for
    the
    Soil
    Component
    of the
    Groundwater Ingestion
    Route
    (Class
    II
    Groundwater)
    TABLE E
    Tier
    1
    Groundwater
    Remediation
    Objectives
    for
    the
    Groundwater
    Component
    of
    the
    Groundwater
    Ingestion
    Route
    TABLE
    F
    Values
    Used
    to
    Calculate
    the
    Tier
    1 Soil
    Remediation
    Objectives
    for
    the
    Soil
    Component
    of
    the
    Groundwater
    Ingestion
    Route
    TABLE
    G
    Tier
    1
    Indoor
    Inhalation
    Remediation
    Objectives
    for
    Residential
    and
    Industrial/Commercial
    Properties for
    the
    Indoor
    Inhalation
    Exposure
    Route
    APPENDIX
    C
    Tier 2
    Illustrations
    and
    Tables
    ILLUSTRATION
    A
    Tier
    2
    Evaluation
    for
    Soil
    ILLUSTRATION
    B Tier
    2
    Evaluation
    for
    Groundwater
    ILLUSTRATION
    C
    US
    Department
    of Agriculture
    Soil
    Texture
    Classification
    TABLE
    A
    SSL
    Equations
    TABLE
    B
    SSL
    Parameters
    TABLE
    C
    RBCA
    Equations

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    PROPOSED
    AMENDMENTS
    TABLE
    D
    RBCA
    Parameters
    TABLE
    B
    Default
    Physical
    and
    Chemical
    Parameters
    TABLE
    F
    Methods
    for
    Determining
    Physical
    Soil
    Parameters
    TABLE
    G
    Error
    Function
    (erf)
    TABLE
    H
    Q/C
    Values
    By Source
    Area
    TABLE
    I
    K
    0
    Values
    for
    Ionizing
    Organics
    as a
    Function
    of
    pH (cm
    3
    /g
    or
    L/kg
    or
    cm
    3
    water/gsoji)
    TABLE
    J
    Values
    to be
    Substituted
    for kd
    or ks
    when Evaluating
    Inorganics
    as a
    Function
    of
    pH (cm
    3
    /g
    or L/kg
    or
    cm
    3
    water/gsoii)
    TABLE
    K
    Parameter
    Estimates
    for
    Calculating
    Water-Filled
    Soil
    Porosity
    (Ow)
    TABLE
    L
    J&E
    Equations
    TABLE
    M
    J&E Parameters
    APPENDIX
    D
    Highway
    Authority
    Agreement
    APPENDIX
    E
    Highway
    Authority
    Agreement
    Memorandum
    of
    Agreement
    APPENDIX
    F
    Environmental
    Land
    Use
    Control
    APPENDIX
    G
    Model
    Ordinance
    APPENDIX
    H
    Memorandum
    of Understanding
    AUTHORITY: Implementing
    Sections
    22.4, 22.12,
    Title
    XVI,
    and
    Title
    XVII and
    authorized
    by
    Sections
    27
    and
    58.5
    of the
    Environmental
    Protection
    Act [415
    ILCS
    5/22.4,
    22.12,
    27,
    and
    58.5
    and
    Title XVI
    and
    Title XVII].
    SOURCE: Adopted
    in R97-12(A)
    at 21111.
    Reg. 7942,
    effective
    July
    1,
    1997;
    amended
    in
    R97-
    12(B)
    at
    21111.
    Reg.
    16391,
    effective
    December
    8,
    1997;
    amended
    in R97-12(C)
    at
    22
    111.
    Reg.
    10847,
    effective
    June
    8, 1998;
    amended
    in
    R00-19(A)
    at 25
    111.
    Reg. 651,
    effective
    January
    6,
    2001;
    amended
    in
    RO0-19(B)
    at
    25 Ill.
    Reg.
    10374,
    effective
    August
    15,
    2001;
    amended
    in
    R00-
    19(C)
    at
    26 Ill.
    Reg.
    2683,
    effective
    February
    5, 2002;
    amended
    in R06-10
    at
    31111. Reg.
    4063,
    effective
    February
    23,
    2007;
    amended
    at
    Ill. Reg.
    effective
    NOTE:
    Italics
    indicates
    statutory
    language.
    SUBPART
    A:
    INTRODUCTION
    Section
    742.110
    Overview
    of
    Tiered
    Approach
    a)
    This
    Part
    presents
    an approach
    for developing
    remediation
    objectives
    (see
    Appendix
    A,
    Illustrations
    A
    and
    B)
    that
    include
    an option
    for exclusion
    of
    pathways
    from further
    consideration,
    use of
    area
    background
    concentrations
    as
    remediation
    objectives
    and three
    tiers
    for
    selecting
    applicable
    remediation

    ILLiNOIS
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    objectives.
    An
    understanding
    of
    human
    exposure
    routes
    is
    necessary
    to
    properly
    conduct
    an evaluation
    under
    this
    approach.
    In
    some
    cases,
    applicable
    human
    exposure
    route(s)
    can
    be excluded
    from
    further
    consideration
    prior
    to any
    tier
    evaluation.
    Selecting
    which
    tier
    or combination
    of
    tiers to
    be used
    to
    develop
    remediation
    objectives
    is dependent
    on
    the site-specific
    conditions
    and
    remediation
    goals.
    Tier
    1 evaluations
    and
    Tier
    2 evaluations
    are
    not
    prerequisites
    to
    conducting
    Tier
    3 evaluations.
    b)
    A
    Tier
    1 evaluation
    compares
    the
    concentration
    of contaminants
    detected
    at a
    site
    to
    the corresponding
    remediation
    objectives
    for
    residential
    and
    industriaL
    t
    commercial
    properties
    contained
    in Appendix
    B,
    Tables
    A, B,
    C, D
    a4
    E
    and
    G.
    To complete
    a Tier
    1 evaluation,
    the
    extent
    and concentrations
    of the
    contaminants
    of
    concern,
    the
    groundwater
    class,
    the
    land
    use classification,
    human
    exposure
    routes
    at the
    site, and,
    if appropriate,
    soil pH,
    must
    be
    known.
    If
    remediation
    objectives
    are
    developed
    based
    on industrial/commercial
    property
    use,
    then
    institutional
    controls
    under
    Subpart
    J
    are required.
    c)
    A
    Tier
    2 evaluation
    uses
    the
    risk
    based
    equations
    from
    the Soil
    Screening
    Level
    (SSL
    Model)
    and Risk
    Based
    Corrective
    Action
    (RBCA
    Model)
    and
    modified
    Johnson
    and Ettinger
    Model
    (J
    &
    E Model)
    documents
    listed
    in Appendix
    C,
    Tables
    A ai4
    C,
    and
    L respectively.
    In addition
    to
    the
    information
    that
    is
    required
    for
    a Tier
    1 evaluation,
    site-specific
    information
    is
    used to
    calculate
    Tier
    2
    remediation
    objectives.
    As in
    Tier 1,
    Tier 2
    evaluates
    residential
    and
    industrial/commercial
    properties
    only.
    If
    remediation
    objectives
    are
    developed
    based
    on industrial/commercial
    property
    use,
    then
    institutional
    controls
    under
    Subpart
    J
    are
    required.
    d)
    A
    Tier
    3 evaluation
    allows
    alternative
    parameters
    and
    factors,
    not
    available
    under
    a
    Tier
    1 or Tier
    2 evaluation,
    to
    be
    considered
    when
    developing
    remediation
    objectives.
    Remediation
    objectives
    developed
    for conservation
    and
    agricultural
    properties
    can
    only
    be developed
    under
    Tier
    3.
    e)
    Remediation
    objectives
    may be
    developed
    using area
    background
    concentrations
    or
    any
    of the
    three
    tiers if
    the
    evaluation
    is conducted
    in accordance
    with
    applicable
    requirements
    in
    Subparts
    D through
    I.
    When contaminant
    concentrations
    do not
    exceed
    remediation
    objectives
    developed
    under
    one
    of
    the
    tiers
    or area
    background
    procedures
    under
    Subpart
    D,
    further
    evaluation
    under
    any
    of the
    other
    tiers is
    not
    required.
    (Source:
    Amended
    at
    Ill.
    Reg.
    effective•

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    Section
    742.115
    Key
    Elements
    To
    develop
    remediation
    objectives
    under
    this
    Part,
    the
    following key
    elements
    shall
    be
    addressed.
    a)
    Exposure Routes
    1)
    This
    Part
    identifies
    the
    following as potential
    exposure
    routes
    to be
    addressed:
    A)
    Outdoor
    Inhalation;
    Indoor
    Inhalation;
    C
    B)
    Soil
    ingestion;
    ]
    G)
    Groundwater
    ingestion; and
    E
    D)
    Dermal
    contact
    with
    soil.
    2)
    The
    evaluation
    of
    exposure
    routes
    under
    subsections
    (a)(1
    )(A),(a)(
    1
    )(B),
    and
    (a)(1)(C)
    and
    (a)(1’j(D)
    of
    this
    Section
    is
    required
    for
    all
    sites
    when
    developing
    remediation
    objectives
    or excluding
    exposure
    pathways.
    Evaluation
    of the
    dermal
    contact
    exposure
    route
    is
    required
    for
    use
    of
    RBCA
    equations
    in
    Appendix
    C,
    Table
    C
    or
    use
    of
    formal
    risk
    assessment
    under
    Section
    742.9
    15.
    3)
    The
    groundwater
    ingestion
    exposure
    route
    is comprised
    of
    two
    components:
    A)
    Migration
    from
    soil
    to groundwater
    (soil
    component);
    and
    B)
    Direct
    ingestion
    of
    groundwater
    (groundwater
    component).
    4
    The
    indoor
    inhalation
    exposure
    route
    is
    comprised
    of
    two
    components:
    Migration
    from
    soil
    through
    soil
    gas
    to
    indoor
    air
    (soil
    component);
    and
    Migration
    from
    groundwater
    through
    soil
    gas to
    indoor
    air
    (groundwater
    component).

    ILLINOIS
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    AMENDMENTS
    b)
    Contaminants
    of Concern
    The
    contaminants
    of concern
    to
    be
    remediated
    depend
    on
    the
    following:
    1)
    The
    materials
    and
    wastes
    managed
    at
    the
    site;
    2)
    The
    extent
    of the
    no
    further
    remediation
    determination
    being
    requested
    from
    the
    Agency
    pursuant
    to
    a
    specific
    program;
    and
    3)
    The
    requirements
    applicable
    to the
    specific
    program, as listed
    at
    Section
    742.105(b)
    under
    which
    the
    remediation
    is
    being
    performed.
    c)
    Land
    Use
    The
    present
    and
    post-remediation
    uses
    of
    the
    site
    where
    exposures
    may
    occur
    shall
    be
    evaluated.
    The
    land
    use
    of
    a
    site,
    or
    portion
    thereof,
    shall
    be
    classified
    as
    one
    of
    the
    following:
    1)
    Residential
    property;
    2)
    Conservation
    property;
    3)
    Agricultural
    property;
    or
    4)
    Jndustriallcommercial
    property.
    (Source: Amended
    at
    Ill.
    Reg.
    effective
    SUBPART
    B:
    GENERAL
    Section
    742.200
    Definitions
    Except
    as
    stated
    in
    this
    Section,
    or
    unless
    a
    different
    meaning
    of
    a
    word
    or
    term
    is clear
    from
    the
    context,
    the
    definition
    of
    words
    or
    terms
    in
    this
    Part
    shall
    be the
    same
    as that
    applied
    to
    the
    same
    words
    or
    terms
    in the
    Act.
    “Act” means
    the
    Illinois
    Environmental
    Protection
    Act
    [415
    ILCS
    5].

    ILLINOIS
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    AMENDMENTS
    “ADL”
    means
    Acceptable
    Detection
    Limit,
    which
    is
    the detectable
    concentration
    of
    a substance
    that
    is
    equal
    to
    the
    lowest
    appropriate
    Practical
    Quantitation
    Limit
    (PQL)
    as
    defined
    in
    this
    Section.
    “Agency”
    means
    the
    Illinois
    Environmental
    Protection
    Agency.
    “Agricultural Property”
    means
    any
    real
    property
    for
    which
    its
    present
    or
    post
    remediation
    use
    is
    for
    growing
    agricultural
    crops
    for
    food
    or
    feed
    either
    as
    harvested
    crops,
    cover
    crops
    or
    as pasture.
    This
    definition
    includes,
    -but
    is
    not
    limited
    to,
    properties
    used
    for
    confinement
    or
    grazing
    of
    livestock
    or poultry
    and
    for
    silviculture
    operations.
    Excluded
    from
    this
    definition
    are
    farm
    residences,
    farm
    outbuildings
    and
    agrichemical facilities.
    “Aquifer” means
    saturated
    (with
    groundwater)
    soils
    and
    geologic
    materials
    which
    are
    sufficiently
    permeable
    to
    readily
    yield
    economically
    useful
    quantities
    of
    water
    to
    wells,
    springs, or
    streams
    under
    ordinary
    hydraulic
    gradients.
    (Illinois
    Groundwater
    Protection
    Act
    [415
    ILCS
    5 5/3(a)])
    “Area
    Background”
    means
    concentrations
    of
    regulated
    substances
    that
    are
    consistently
    present
    in the
    environment
    in
    the
    vicinity
    ofa
    site
    that
    are
    the
    result
    of
    natural
    conditions or
    human
    activities,
    and
    not
    the result
    solely
    ofreleases
    at
    the
    site.
    [415
    ILCS
    5/58.2]
    “ASTM”
    means
    the
    American
    Society
    for
    Testing
    and
    Materials.
    “Board”
    means
    the
    Illinois
    Pollution
    Control
    Board.
    “Building”
    means
    a
    man-made
    structure with
    an
    enclosing roof
    and
    enclosing
    walls,
    except
    for
    windows
    and
    doors,
    that
    is
    intended
    for
    or
    supports
    any
    human
    occupancy
    for
    more
    than
    six
    consecutive
    months.
    “Building Control
    Technology”
    means
    any
    technology,
    barrier
    or
    geologic
    material
    that
    affects
    air
    flow
    or
    air
    pressure
    within
    a building
    for
    purposes
    of
    reducing
    contaminant
    migration
    to
    the
    indoor
    air.
    “Cancer Risk”
    means
    a
    unitless
    probability
    of
    an
    individual
    developing
    cancer
    from
    a
    defined
    exposure
    rate
    and
    frequency.
    “Cap”
    means
    a barrier
    designed
    to
    prevent
    the
    infiltration
    of
    precipitation
    or
    other
    surface
    water,
    or
    impede
    the ingestion
    or
    inhalation
    of
    contaminants.

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    “Carcinogen”
    means
    a
    contaminant
    that is
    classified
    as a
    category
    Al
    or A2
    carcinogen
    by the
    American
    Conference
    of Governmental
    Industrial
    Hygienists,
    a
    category
    1 or
    2A/2B
    carcinogen
    by
    the World
    Health
    Organization
    International
    Agency
    for
    Research
    on
    Cancer;
    a “human
    carcinogen”
    or
    “anticzpated
    human
    carcinogen”
    by
    the United
    States
    Department
    of
    Health
    and Human
    Service
    National
    Toxicological
    Program;
    or a category
    A or
    B1/B2
    carcinogen
    by
    the
    United
    States
    Environmental
    Protection
    Agency
    in the
    integrated
    risk
    information
    system
    or
    afinal
    rule
    issued in
    a Federal
    Register
    notice
    by the
    USEPA.
    [415
    ILCS
    5/5 8.2]
    “Class
    I
    Groundwater”
    means
    groundwater
    that
    meets
    the
    Class
    I:
    Potable
    Resource
    Groundwater
    criteria
    set forth
    in 35
    Ill.
    Adm.
    Code 620.
    “Class
    II
    Groundwater”
    means
    groundwater
    that meets
    the
    Class
    II: General
    Resource
    Groundwater
    criteria
    set
    forth
    in
    35 Ill.
    Adm. Code
    620.
    “Conservation
    Property”
    means
    any
    real property
    for
    which
    present
    or post
    remediation
    use is
    primarily
    for
    wildlife
    habitat.
    “Construction Worker”
    means
    a person
    engaged
    on
    a
    temporary
    basis
    to
    perform
    work
    involving
    invasive
    construction
    activities
    including,
    but
    not
    limited
    to,
    personnel
    performing
    demolition,
    earth-moving,
    building,
    and
    routine
    and
    emergency
    utility
    installation
    or
    repair activities.
    “Contaminant of Concern”
    or “Regulated
    Substance
    of
    Concern”
    means
    any
    contaminant
    that
    is
    expected
    to
    be present
    at
    the site
    based
    upon
    past
    and
    current
    land
    uses and
    associated
    releases
    that
    are
    known
    to
    the
    person
    conducting
    a
    remediation
    based
    upon
    reasonable
    inquiry
    [415
    ILCS
    5/58.2]
    “County
    highway”
    means
    county
    highway
    as
    defined
    in
    the
    Illinois
    Highway
    Code,
    [605
    ILCS
    5].
    “District
    road”
    means
    district
    road
    as
    defined
    in the
    Illinois
    Highway
    Code,
    [605
    ILCS
    5].
    “Engineered
    Barrier”
    means
    a barrier
    designed
    or
    verified
    using
    engineering
    practices
    that limits
    exposure
    to or
    controls
    migration
    of
    the contaminants
    of
    concern.
    “Environmental Land
    Use
    Control”
    means
    an
    instrument
    that
    meets the
    requirements
    of
    this Part
    and
    is
    placed
    in
    the
    chain
    of
    title
    to real
    property
    that

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    AMENDMENTS
    limits
    or
    places
    requirements
    upon
    the
    use
    of the
    property
    for
    the
    purpose
    of
    protecting
    human
    health
    or
    the
    environment,
    is
    binding
    upon
    the
    property
    owner,
    heirs,
    successors,
    assigns,
    and
    lessees,
    and
    runs
    in
    perpetuity
    or until
    the
    Agency
    approves, in
    writing, removal
    of the
    limitation
    or
    requirement
    from
    the
    chain
    of
    title.
    “Exposure
    Route”
    means
    the
    transport
    mechanism
    by
    which
    a
    contaminant
    of
    concern
    reaches
    a
    receptor.
    “Federally
    Owned
    Property”
    means
    real
    property
    owned
    in
    fee
    by
    the
    United
    States
    of America
    on
    which
    institutional
    controls are
    sought to be
    placed
    in
    accordance
    with
    this
    Subpart.
    “Federal
    Landholding
    Entity” means
    that
    federal
    department,
    agency,
    or
    instrumentality
    with
    the
    authority
    to occupy
    and
    control
    the
    day-to-day
    use,
    operation
    and
    management
    of Federally
    Owned
    Property.
    “Free
    Product” means
    a
    contaminant
    that
    is present
    as
    a non-aqueous
    phase
    liquid
    for
    chemicals
    whose
    melting
    point
    is
    less
    than
    300
    C
    (e.g.,
    liquid
    not
    dissolved
    in
    water).
    “GIS”
    means
    Geographic
    Information
    System.
    “GPS”
    means
    Global
    Positioning
    System.
    “Groundwater”
    means underground
    water
    which
    occurs
    within
    the
    saturated
    zone
    and
    geologic
    materials
    where
    thefluid
    pressure
    in the
    pore
    space
    is
    equal
    to
    or
    greater
    than
    atmospheric
    pressure.
    [415
    ILCS
    5/3.64]
    “Groundwater
    Quality
    Standards”
    means
    the
    standards
    for
    groundwater
    as
    set
    forth
    in
    35 Iii.
    Adm.
    Code
    620.
    “Hazard
    Quotient”
    means
    the
    ratio
    of
    a
    single
    substance
    exposure
    level
    during
    a
    specified
    time
    period
    to
    a
    reference
    dose
    for
    that
    substance
    derived
    from
    a
    similar
    exposure
    period.
    “Highway”
    means
    any
    public
    way
    for
    vehicular
    travel
    which
    has
    been
    laid
    out
    in
    pursuance
    of
    any
    law
    ofthis
    State,
    or
    of
    the
    Territory
    of
    Illinois,
    or
    which
    has
    been
    established
    by
    dedication,
    or
    used
    by
    the
    public
    as a
    highway
    for
    15
    years,
    or which
    has
    been
    or
    may
    be
    laid
    out and
    connect
    a
    subdivision
    or
    platted
    land
    with
    a
    public
    highway
    and
    which
    has
    been
    dedicated
    for
    the use
    of
    the
    owners
    of

    ILLINOIS
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    OF
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    the
    land included
    in
    the
    subdivision
    or
    platted
    land
    where
    there
    has
    been
    an
    acceptance
    and
    use
    under
    such
    dedication
    by such
    owners,
    and
    which
    has
    not
    been
    vacated
    in
    pursuance
    oflaw.
    The term
    “highway”
    includes
    rights
    of
    way,
    bridges,
    drainage
    structures,
    signs,
    guard
    rails,
    protective
    structures
    and
    all
    other
    structures
    and
    appurtenances
    necessaiy
    or convenient
    for
    vehicular
    traffic.
    A
    highway
    in
    a
    rural
    area
    may
    be called
    a
    “road”,
    while
    a highway
    in
    a
    municipal
    area
    may
    be called
    a
    “street”.
    (Illinois
    Highway
    Code
    [605
    JECS
    5/2-202])
    “Highway
    Authority”
    means
    the Department
    of
    Transportation
    with
    respect
    to
    a
    State
    highway;
    the
    Illinois
    State
    Toll
    Highway
    with
    respect
    to a
    toll
    highway;
    the
    County
    Board
    with
    respect
    to
    a county
    highway
    or a
    county
    unit
    district
    road
    fa
    discretionaryfunction
    is
    involved
    and
    the
    County
    Superintendent
    of
    Highways
    fa
    ministerialfunction
    is involved;
    the Highway
    Commissioner
    with
    respect
    to
    a
    township
    or district
    road
    not in
    a county
    unit
    road
    district;
    or the
    corporate
    authorities
    ofa
    municzpality
    with
    respect
    to
    a
    municipal
    street.
    (Illinois
    Highway
    Code
    [605
    ILCS
    5/2-213])
    “Human
    Exposure
    Pathway”
    means
    a physical
    condition
    which
    may
    allow
    for
    a
    risk
    to human
    health
    based
    on the
    presence
    of all
    of
    the
    following:
    contaminants
    of
    concern;
    an
    exposure
    route;
    and
    a receptor
    activity
    at the point
    of exposure
    that
    could
    result
    in contaminant
    of
    concern
    intake.
    “Industrial/Commercial
    Property”
    means
    any
    real property
    that
    does not
    meet
    the
    definition
    of
    residential
    property,
    conservation
    property
    or
    agricultural
    property.
    “Infiltration”
    means
    the amount
    of water
    entering
    into
    the ground
    as a result
    of
    precipitation.
    “Institutional
    Control”
    means
    a legal
    mechanism
    for
    imposing
    a restriction
    on
    land
    use, as
    described
    in Subpart
    J.
    “Land
    Use Control
    Memoranda
    of
    Agreement”
    mean
    agreements
    entered
    into
    between
    one
    or more
    agencies
    of the
    United
    States
    and
    the
    Illinois
    Environmental
    Protection
    Agency
    that
    limit or
    place requirements
    upon
    the
    use
    of Federally
    Owned
    Property
    for
    the purpose
    of protecting
    human
    health
    or the
    environment.
    “Man-Made
    Pathways”
    means
    constructed
    physical
    conditions
    that may
    allow
    for
    the
    transport
    of
    regulated
    substances
    including,
    but
    not limited
    to, sewers,
    utility
    lines,
    utility
    or
    elevator
    vaults,
    building
    foundations,
    basements,
    crawl
    spaces,
    drainage
    ditches,
    or previously
    excavated
    andfilled
    areas,
    or
    sumps.
    [415
    ILCS
    5/58.2]

    ILLINOIS
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    “Natural
    Pathways”
    means
    natural
    physical
    conditions
    that
    may
    allowfor
    the
    transport
    of
    regulated
    substances
    including,
    but
    not
    limited
    to, soil,
    groundwater,
    sand
    seams
    and
    lenses,
    and gravel
    seams
    and
    lenses.
    [415
    ILCS
    5/58.2]
    “Person”
    means
    an individual,
    trust,
    firm,
    joint
    stock
    company,
    joint
    venture,
    consortium,
    commercial
    entity,
    corporation
    (including
    a
    government
    corporation),
    partnership,
    association,
    state,
    municzpality,
    commission,
    political
    subdivision
    of
    a
    state,
    or
    any
    interstate
    body
    including
    the
    United
    States
    government
    and
    each
    department,
    agency,
    and instrumentality
    of
    the
    United
    States.
    [415
    ILCS
    5/58.2]
    “Point
    of Human
    Exposure”
    means
    the
    points
    at
    which
    human
    exposure
    to
    a
    contaminant
    of concern may
    reasonably
    be
    expected
    to occur.
    The
    point
    of
    human
    exposure
    is at
    the
    source,
    unless
    an
    institutional
    control
    limiting
    human
    exposure
    for
    the
    applicable
    exposure
    route
    has
    been
    or will
    be
    in place,
    in
    which
    case
    the point
    of
    human
    exposure
    will
    be the
    boundary
    of
    the
    institutional
    control.
    Point
    of
    human
    exposure
    may
    be at
    a different
    location
    than
    the point
    of
    compliance.
    “Populated
    Area”
    means
    an area
    within
    the boundaries
    of
    a municipality
    that
    has
    a
    population
    of
    10,000
    or
    greater
    based
    on the
    year
    2000
    or
    most
    recent
    census;
    or
    an
    area less
    than
    three
    miles
    from
    the
    boundary
    of
    a municipality
    that
    has
    a
    population
    of
    10,000
    or
    greater
    based
    on the
    year
    2000
    or
    most
    recent
    census.
    “Potable”
    means
    generally
    fitfor
    human
    consumption
    in
    accordance
    with
    accepted
    water
    supply
    principles
    and
    practices.
    (Illinois
    Groundwater
    Protection
    Act [415
    ILCS
    55/3(h)])
    “PQL”
    means
    practical
    quantitation
    limit
    or estimated
    quantitation
    limit,
    which
    is
    the
    lowest
    concentration
    that
    can be
    reliably
    measured
    within
    specified
    limits
    of
    precision
    and
    accuracy
    for
    a specific
    laboratory
    analytical
    method
    during
    routine
    laboratory
    operating
    conditions
    in
    accordance
    with
    “Test
    Methods
    for
    Evaluating
    Solid
    Wastes,
    Physical/Chemical
    Methods”,
    EPA
    Publication
    No.
    SW-846,
    incorporated
    by
    reference
    in
    Section
    742.210.
    When
    applied
    to filtered
    water
    samples,
    PQL
    includes
    the
    method
    detection
    limit
    or estimated
    detection
    limit
    in
    accordance
    with
    the applicable
    method
    revision
    in:
    “Methods
    for
    the
    Determination
    of Organic
    Compounds
    in
    Drinking
    Water”,
    Supplement
    II”,
    EPA

    ILLINOIS
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    PROPOSED
    AMENIMENTS
    Publication
    No.
    EPAJ600/4-88/039;
    “Methods
    for
    the
    Determination
    of Organic
    Compounds
    in
    Drinking
    Water,
    Supplement
    III”,
    EPA
    Publication
    No.
    EPA/600/R-95/131,
    all
    of which
    are
    incorporated
    by
    reference
    in
    Section
    742.210.
    “RBCA”
    means
    Risk
    Based
    Corrective
    Action
    as
    defined
    in
    ASTM
    E-1739-95,
    as
    incorporated
    by
    reference
    in
    Section
    742.2
    10.
    “RCRA”
    means
    the
    Resource
    Conservation
    and
    Recovery
    Act
    of
    1976
    (42
    U.S.C.
    6921).
    “Reference
    Concentration”
    or
    “RfC”
    means
    an
    estimate
    of a
    daily
    exposure,
    in
    units
    of
    milligrams
    of
    chemical
    per
    cubic
    meter
    of
    air
    (mg/m(3)),
    to the
    human
    population
    (including
    sensitive
    subgroups)
    that
    is
    likely
    to
    be
    without
    appreciable
    risk
    of
    deleterious
    effects
    during
    a portion
    of
    a
    lifetime
    (up
    to
    approximately
    seven
    years,
    subchronic)
    or
    for a
    lifetime
    (chronic).
    “Reference
    Dose”
    or “RfD”
    means
    an
    estimate
    of a
    daily
    exposure,
    in
    units
    of
    milligrams
    of
    chemical
    per
    kilogram
    of
    body
    weight
    per
    day
    (mg/kg/d),
    to
    the
    human
    population
    (including
    sensitive
    subgroups)
    that
    is
    likely
    to
    be
    without
    appreciable
    risk
    of
    deleterious effects
    during
    a
    portion
    of
    a lifetime
    (up
    to
    approximately
    seven
    years,
    subchronic)
    or
    for
    a
    lifetime
    (chronic).
    “Regulated
    Substance”
    means
    any
    hazardous
    substance
    as
    defined
    under
    Section
    101(14)
    of
    the
    Comprehensive
    Environmental
    Response,
    Compensation,
    and
    Liability
    Act
    of1980
    (F.L.
    96-510)
    and
    petroleum
    products
    including
    crude
    oil
    or
    any
    fraction
    thereof
    natural
    gas,
    natural
    gas
    liquids,
    liquefied
    natural
    gas,
    or
    synthetic
    gas
    usable
    for
    fuel
    (or
    mixtures
    of
    natural
    gas
    and
    such
    synthetic
    gas).
    [415
    ILCS
    5/58.2]
    “Residential
    Property”
    means
    any
    real
    property
    that
    is used
    for habitation
    by
    individuals,
    or where children
    have
    the
    opportunity
    for
    exposure
    to
    contaminants
    through soil
    ingestion
    or inhalation
    at
    educational
    facilities,
    health
    care
    facilities,
    child
    care
    facilities
    or
    outdoor
    recreational
    areas.
    [415
    ILCS
    5/58.2]
    “Right
    of
    Way”
    means
    the
    land,
    or
    interest
    therein,
    acquiredfor
    or
    devoted
    to
    a
    highway. (Illinois
    Highway
    Code
    [605
    ILCS
    5/2-2
    17])
    “Similar-Acting
    Chemicals”
    are
    chemical substances
    that
    have
    toxic
    or
    harmful
    effect
    on
    the
    same
    specific
    organ
    or
    organ
    system
    (see
    Appendix
    A.Tables
    E
    and

    ILLINOIS
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    POLLUTION
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    PROPOSED
    AMEI\DMENTS
    F
    for a
    list of
    similar-acting
    chemicals
    with
    noncarcinogenic
    and
    carcinogenic
    effects).
    “Site”
    means
    any single
    location,
    place,
    tract
    of
    land or
    parcel
    ofproperty,
    or
    portion
    thereof
    including
    contiguous
    property
    separated
    by
    a public
    right-of-way.
    415
    ILCS
    5/58.2]
    “Slurry
    Wall”
    means
    a
    man-made
    barrier
    made
    of
    geologic
    material
    which
    is
    constructed
    to prevent
    or
    impede
    the
    movement
    of
    contamination
    into
    a
    certain
    area.
    “Soil
    Gas”
    means
    the
    air
    existing
    in
    void
    spaces
    in the
    soil
    between
    the
    groundwater
    table
    and
    the ground
    surface.
    “Soil
    Saturation
    Limit”
    or
    “Csat”
    means
    the contaminant
    soil
    pore
    air
    and
    pore
    water
    are saturated
    wnu
    ule
    chemicai
    iiiu
    me
    adsorptive
    limits
    of
    the
    soil
    particles
    have
    been
    reached.
    the
    contaminant
    concentration
    at
    which
    the
    absorptive
    limits
    of
    the soil
    particles,
    the solubility
    limits
    of
    the
    available
    soil
    moisture,
    and
    saturation
    of
    soil pore
    air
    have
    been
    reached.
    Above
    the
    soil saturation
    concentration,
    the
    assumptions
    regarding
    vapor
    transport
    to
    air
    and/or
    dissolved
    phase
    transport
    to
    groundwater
    (for
    chemicals
    which
    are
    liquid
    at
    ambient
    soil
    temperatures)
    do
    not
    apply,
    and
    alternative
    modeling
    approaches
    are
    required.
    “Soil
    Vapor
    Saturation
    Limit”
    or
    means
    the
    maximum
    vapor
    concentration
    that
    can
    exist
    in the
    soil
    pore
    air at
    a
    given
    temperature
    and
    pressure.
    “Solubility”
    means
    a chemical
    specific maximum
    amount
    of
    solute
    that
    can
    dissolve
    in
    a specific
    amount
    of solvent
    (groundwater)
    at a specific
    temperature.
    “SPLP”
    means
    Synthetic
    Precipitation
    Leaching
    Procedure
    (Method
    1312)
    as
    published
    in
    “Test
    Methods
    for
    Evaluating
    Solid
    Waste,
    Physical/Chemical
    Methods”,
    USEPA
    Publication
    No. SW-846,
    as
    incorporated
    by
    reference
    in
    Section
    742.2
    10.
    “SSL”
    means
    Soil
    Screening
    Levels
    as
    defined
    ih
    USEPA’s
    Soil
    Screening
    Guidance:
    User’s
    Guide
    and
    Technical
    Background
    Document,
    as
    incorporated
    by
    reference
    in
    Section
    742.210.
    “State
    highway”
    means
    state
    highway
    as defined
    in
    the
    Illinois
    Highway
    Code
    [605
    ILCS
    5].

    ILLINOIS
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    “Stratigraphic
    Unit”
    means
    a
    site-specific
    geologic
    unit
    of
    native
    deposited
    material
    and/or
    bedrock
    of
    varying
    thickness
    (e.g.,
    sand,
    gravel,
    silt,
    clay,
    bedrock, etc.).
    A
    change
    in
    stratigraphic
    unit
    is recognized
    by
    a clearly
    distinct
    contrast
    in geologic
    material
    or
    a
    change
    in
    physical
    features within
    a zone
    of
    gradation. For
    the
    purposes
    of
    this
    Part,
    a change
    in
    stratigraphic
    unit
    is
    identified
    by
    one
    or
    a combination
    of differences
    in physical
    features
    such
    as
    texture,
    cementation,
    fabric,
    composition,
    density,
    and/or
    permeability
    of
    the
    native
    material
    and/or
    bedrock.
    “Street”
    means
    street
    as
    defined
    in the
    Illinois
    Highway
    Code
    [605
    ILCS
    5].
    “TCLP”
    means
    Toxicity
    Characteristic
    Leaching
    Procedure
    (Method
    1311)
    as
    published in
    “Test
    Methods
    for Evaluating
    Solid
    Waste,
    Physical/Chemical
    Methods”, USEPA
    Publication
    No.
    SW-846,
    as incorporated
    by
    reference
    in
    Section
    742.210.
    “Toll
    highway”
    means
    toll
    highway
    as
    defined
    in
    the
    Illinois
    Highway
    Code
    [605
    ILCS
    5].
    “Total
    Petroleum
    Hydrocarbon
    (TPH)”
    means
    the
    additive
    total
    of all
    petroleum
    hydrocarbons
    found
    in an
    analytical
    sample.
    “Township
    road”
    means
    township
    road
    as
    defined
    in the
    Illinois
    Highway
    Code
    [605
    ILCS
    5].
    “Volatile Chemicals”
    means
    chemicals
    with
    a Dimensionless
    Henry’s
    Law
    Constant
    of
    greater
    than
    1.9 x
    1
    02
    or
    a vapor
    pressure
    greater
    than
    0.1
    Torr
    (mniHg) at 25°C.
    For
    purposes
    of
    the
    indoor
    inhalation
    exposure
    route,
    elemental
    mercury
    is included in
    this
    definition.
    “Volatile
    Organic
    Compounds
    (VOCs)”
    means
    organic
    chemical
    analytes
    identified
    as
    volatiles
    as
    published
    in
    “Test
    Methods for
    Evaluating
    Solid
    Waste,
    Physical/Chemical
    Methods”,
    USEPA
    Publication
    No.
    SW
    846
    (incorporated-by
    reference in
    Section
    742.210),
    method
    numbers
    8011,
    8015B,
    8021B,
    8031,
    8260B,
    831
    5A,
    and
    83
    16. For
    analytes
    not
    listed
    in any
    category
    in
    those
    methods,
    those
    analytes
    which
    have
    a
    boiling
    point
    less
    than
    200°
    C
    and
    a
    vapor
    pressure
    greater
    than
    0.1
    Toff
    (
    Hg)
    at 20°
    C.
    (Source: Amended at
    Ill.
    Reg.
    effective

    ILLINOIS
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    Section
    742.2
    10
    Incorporations
    by Reference
    a)
    The
    Board
    incorporates
    the following
    material
    by
    reference:
    Agency
    for
    Toxic
    Substances
    and Disease
    Registry
    (ATSDR)
    Minimal
    Risk
    Levels
    (MRLs),
    U.S.
    Environmental
    Protection
    Agency,
    1600 Clifton
    Road,
    Mailstop
    F32,
    Atlanta,
    Georgia
    30333,
    (770) 488-3357
    (December
    2006).
    ASTM.
    American
    Society for
    Testing
    and
    Materials
    International,
    100
    Barr
    Harbor
    Drive,
    West
    Conshohocken,
    PA
    19428-2959.
    (610)
    832-9585.
    ASTM
    D 2974-00,
    Standard
    Test
    Methods
    for
    Moisture,
    Ash
    and
    Organic
    Matter
    of Peat
    and Other
    Organic
    Soils,
    approved
    August 10,
    2000.
    ASTM
    D 248
    8-00, Standard
    Practice
    for
    Description
    and
    Identification
    of
    Soils
    (Visual-Manual
    Procedure),
    approved
    February
    10, 2000.
    ASTM
    D
    15 56-00,
    Standard
    Test Method
    for
    Density
    and Unit
    Weight
    of
    Soil in
    Place by the
    Sand-Cone
    Method,
    approved
    March
    10, 2000.
    ASTM
    D 2
    167-94,
    Standard
    Test
    Method
    for Density
    and
    Unit
    Weight
    of
    Soil
    in Place
    by the
    Rubber
    Balloon
    Method,
    approved
    March
    15,
    1994.
    ASTM
    D 2922-01,
    Standard
    Test
    Methods
    for Density
    of
    Soil and
    Soil-
    Aggregate
    in
    Place
    by Nuclear
    Methods
    (Shallow
    Depth),
    approved
    June
    10, 2001.
    ASTM
    D 2937-OOel,
    Standard Test
    Method
    for
    Density
    of Soil
    in
    Place
    by
    the
    Drive-Cylinder
    Method,
    approved
    June
    10,
    2000.
    ASTM
    D 854-02,
    Standard
    Test
    Methods
    for Specific
    Gravity
    of
    Soil
    Solids
    by Water
    Pycnometer,
    approved
    July 10,
    2002.
    ASTM
    D 22
    16-98,
    Standard
    Test
    Method
    for
    Laboratory
    Determination
    of
    Water
    (Moisture)
    Content
    of Soil
    and
    Rock
    by
    Mass, approved
    February
    10, 1998.
    ASTM
    D 4959-00,
    Standard
    Test
    Method
    for
    Determination
    of
    Water
    (Moisture)
    Content
    of
    Soil by Direct
    Heating,
    approved
    March
    10,
    2000.

    ILLiNOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    ASTM
    D 4643-00,
    Standard
    Test
    Method
    for
    Determination
    of
    Water
    (Moisture)
    Content
    of
    Soil
    by
    the
    Microwave
    Oven
    Method,
    approved
    February
    10, 2000.
    ASTM
    D
    5084-03,
    Standard
    Test
    Methods
    for
    Measurement
    of
    Hydraulic
    Conductivity
    of Saturated Porous
    Materials Using
    a
    Flexible
    Wall
    Permeameter,
    approved
    November
    1, 2003.
    ASTM
    D
    422-63
    (2002),
    Standard
    Test
    Method
    for
    Particle-Size
    Analysis
    of Soils,
    approved
    November
    10,
    2002.
    ASTM
    D
    1140-00,
    Standard
    Test
    Methods
    for
    Amount
    of
    Material
    in
    Soils
    Finer
    than
    the
    No.
    200
    (75
    pin)
    Sieve,
    approved
    June
    10,
    2000.
    ASTM
    D 3017-01,
    Standard
    Test
    Method for
    Water
    Content
    of
    Soil
    and
    Rock
    in Place
    by
    Nuclear
    Methods
    (Shallow
    Depth),
    approved
    June
    10,
    2001.
    ASTM
    D
    4525-90
    (2001),
    Standard
    Test
    Method
    for
    Permeability
    of
    Rocks
    by
    Flowing
    Air,
    approved
    May
    25,
    1990.
    ASTM
    D
    2487-00,
    Standard
    Classification of
    Soils
    for
    Engineering
    Purposes
    (Unified
    Soil
    Classification
    System),
    approved
    March
    10,
    2000.
    ASTM
    D 1945-03,
    Standard
    Test
    Method
    for
    Analysis
    of
    Natural
    Gas by
    Gas
    Chromatography,
    approved
    May
    10,
    2003
    ASTM
    D
    1946-90,
    Standard Practice
    for
    Analysis
    of
    Reformed
    Gas
    by
    Gas
    Chromatography,
    approved
    June
    1, 2006
    ASTM
    E 1527-00,
    Standard
    Practice
    for
    Environmental
    Site
    Assessments:
    Phase
    I
    Environmental
    Site
    Assessment
    Process,
    approved
    May
    10,
    2000.
    Vol.
    11.04.
    ASTM
    B
    1739-95
    (2002),
    Standard
    Guide
    for Risk-Based
    Corrective
    Action
    Applied
    at Petroleum Release
    Sites,
    approved
    September
    10,
    1995.
    ASTM
    E
    2121-03,
    Standard
    Practice
    for
    Installing
    Radon
    Mitigation
    Systems
    in
    Existing
    Low-Rise
    Residential
    Buildings,
    approved
    February
    10,
    2003.

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    ASTM
    E 2600-08,
    Standard
    Practice
    for Assessment
    for
    Vapor
    Intrusion
    into
    Structures
    on
    Property
    Involved
    in
    Real
    Estate
    Transactions,
    approved
    March
    7, 2008.
    Barnes,
    Donald
    G.
    and Dourson,
    Michael.
    (1988).
    Reference
    Dose
    (RiD):
    Description and
    Use
    in
    Health
    Risk
    Assessments.
    Regulatory
    Toxicology
    and
    Pharmacology.
    8,
    47 1-486.
    EPRI.
    Electric
    Power
    Research
    Institute.
    3420
    Hiliview
    Avenue,
    Palo
    Alto,
    California
    94304.
    (650)
    855-2121.
    Polycyclic
    Aromatic
    Hydrocarbons
    (PAHs)
    in Surface
    Soil
    in
    Illinois:
    Background
    PARs,
    EPRI,
    Palo
    Alto,
    CA,
    We
    Energies,
    Milwaukee,
    WI,
    and
    IEPA,
    Springfield,
    IL: 2004.
    1011376.
    “Reference
    Handbook
    for
    Site-Specific
    Assessment
    of Subsurface
    Vapor
    Intrusion
    to Indoor
    Air,”
    Electric
    Power
    Research
    Institute
    (EPRI),
    Inc.,
    Program
    No.
    1008492,
    (March 2005).
    GPO.
    Superintendent
    of
    Documents,
    U.S.
    Government
    Printing
    Office,
    Washington,
    DC
    20401,
    (202)
    783-3238.
    USEPA
    Guidelines
    for
    Carcinogenic
    Risk
    Assessment,
    51
    Fed.
    Reg.
    33992-34003
    (September
    24,
    1986).
    “Test
    Methods
    for
    Evaluating
    Solid
    Waste,
    Physical/Chemical
    Methods!!,
    USEPA
    Publication
    number
    SW-846
    (Third
    Edition,
    Final
    Update
    lilA,
    April
    1998),
    as amended
    by
    Updates
    I, HA,
    III,
    and
    lIlA
    (Document
    No.
    955-001-00000-1).
    “Methods
    for the
    Determination
    of
    Organic
    Compounds
    in Drinking
    Water”,
    EPA
    Publication
    No. EPA/600/4-88/039
    (December
    1988
    (Revised
    July
    1991)).
    “Methods
    for
    the
    Determination
    of Organic
    Compounds
    in Drinking
    Water,
    Supplement
    I”,
    EPA Publication
    No.
    EPA/600/4-90/020
    (July
    1990).
    “Methods
    for
    the
    Determination
    of Organic
    Compounds
    in
    Drinking
    Water,
    Supplement
    II”,
    EPA
    Publication
    No.
    EPA/600/R-92/129
    (August
    1992).

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    “Methods
    for
    the
    Determination
    of
    Organic
    Compounds
    in Drinking
    Water,
    Supplement
    III”, EPA
    Publication
    No.
    EPA/600/R-95/13
    1
    (August
    1995).
    “Guidance
    for
    Data Quality
    Assessment,
    Practical
    Methods
    for
    Data
    Analysis,
    EPA
    QA/G-9,
    QAOO
    Update,”
    EPAI600tR-96/084
    (July
    2000).
    Available
    at
    www.epa.gov/quality/qs-docs/g9-final.pdf.
    “Assessment
    of Vapor
    Intrusion
    in Homes
    Near
    the
    Raymark
    Superfund
    Site
    Using
    Basement
    and
    Sub-Slab
    Air Samples”,
    EPA
    Publication
    No.
    EPA/600/R-
    05/147
    (March
    2006).
    “Model
    Standards
    and Techniques
    for
    Control
    of Radon
    in
    New
    Residential
    Buildings”
    EPA
    Publication
    No. EPA/402/R-94/009
    (March
    1994).
    IRIS.
    Integrated
    Risk Information
    System,
    National
    Center
    for
    Environmental
    Assessment,
    U.S.
    Environmental
    Protection
    Agency,
    26
    West Martin
    Luther
    King
    Drive,
    MS-190,
    Cincinnati,
    OH 45268,
    (513)
    569-7254.
    “Reference
    Dose
    (RfD):
    Description
    and
    Use in
    Health
    Risk
    Assessments”,
    Background
    Document
    1A
    (March
    15,
    1993).
    “EPA
    Approach
    for
    Assessing
    the
    Risks
    Associated
    with Chronic
    Exposures
    to
    Carcinogens”,
    Background
    Document
    2
    (January
    17,
    1992).
    Johnson,
    Paul
    C.
    (2005).
    Identification
    of Application
    Specific
    Critical
    Inputs
    for
    the
    1991
    Johnson
    and
    Ettinger
    Vapor
    Intrusion
    Algorithm.
    Ground
    Water
    Monitoring
    and
    Remediation.
    25(1),
    63-78.
    Murray,
    Donald
    M.
    and
    Burmaster,
    David
    E.
    (1995).
    Residential
    Air
    Exchapg
    Rates
    in the
    United
    States:
    Empirical
    and
    Estimated
    Parametric
    Distributions
    b1
    Season
    and Climatic
    Region.
    Risk
    Analysis.
    15(4),
    459-465.
    Nelson,
    D.W.,
    and
    L.E. Sommers
    (1982).
    Total
    carbon,
    organic
    carbon,
    and
    organic
    matter.
    In:
    A.L.
    Page
    (ed.),
    Methods
    of Soil
    Analysis.
    Part
    2.
    Chemical
    and
    Microbiological
    Properties.
    2nd
    Edition,
    pp.
    539-579,
    American
    Society
    of
    Agronomy.
    Madison,
    WI.
    NTIS.
    National
    Technical
    Information
    Service,
    5285
    Port
    Royal
    Road,
    Springfield,
    VA
    22161,
    (703)
    487-4600.

    ILL1NOIS
    REGISTER
    POLLUTION
    CONTROL BOARD
    NOTICE OF
    PROPOSED
    AMENDMENTS
    “Calculating
    Upper
    Confidence Limits
    for
    Exposure Point
    Concentrations
    at
    Hazardous
    Waste
    Sites,”
    USEPA
    Office
    of
    Emergency
    and
    Remedial
    Response,
    OSWER 9285.6-10
    (December
    2002),
    PB
    2003-104982.
    “Evaluating
    the
    Vapor
    Intrusion
    to Indoor
    Air
    Pathway
    from
    Groundwater
    and
    Soils,”
    OSWER Draft
    Guidance.
    EPA
    Publication
    No.
    EPA/530D-
    02/004
    (November
    2002).
    “Exposures
    Factors
    Handbook,
    Vol.
    I: General
    Factors”,
    EPA
    Publication
    No.
    EPA!600/P-95/OO2Fa
    (August
    1997).
    “Exposures
    Factors
    Handbook,
    Vol.
    II:
    Food
    Ingestion
    Factors”,
    EPA
    Publication
    No.
    EPAJ600/P-95/OO2Fb
    (August
    1997).
    “Exposures
    Factors
    Handbook,
    Vol.
    ifi:
    Activity
    Factors”,
    EPA
    Publication
    No.
    EPAI600IP-95/OO2Fc
    (August
    1997).
    “Risk
    Assessment
    Guidance
    for
    Superfund,
    Vol.
    I:;
    Human
    Health
    Evaluation
    Manual,
    Supplemental
    Guidance:
    Standard
    Default
    Exposure
    Factors”,
    OSWER Directive
    9285.6-03 (March
    1991).
    “Rapid
    Assessment
    of
    Exposure
    to Particulate
    Emissions
    from
    Surface
    Contamination
    Sites,”
    EPA
    Publication
    No.
    EPA/600/8-85/002
    (February
    1985),
    PB
    85-192219.
    “Risk
    Assessment
    Guidance
    for
    Superfund,
    Volume
    I;
    Human
    Health
    Evaluation
    Manual
    (Part
    A)”,
    Interim
    Final,
    EPA
    Publication
    No.
    EPAJ54O/1-89/002
    (December
    1989).
    “Risk
    Assessment
    Guidance
    for
    Superfund,
    Volume
    I; Human
    Health
    Evaluation Manual,
    Supplemental
    Guidance,
    Dermal
    Risk
    Assessment
    Interim
    Guidance”,
    Draft
    (August
    18,
    1992).
    “Risk
    Assessment
    Guidance
    for
    Superfund,
    Vol.
    I:
    Human
    Health
    Evaluation
    Manual
    (Part
    E,
    Supplemental
    Guidance
    for
    Dermal
    Risk
    Assessment)
    Interim”,
    EPA
    Publication
    No.
    EPAJ54O/RJ99/005
    (September
    2001).
    “Soil
    Screening
    Guidance:
    Technical Background
    Document”,
    EPA
    Publication
    No.
    EPA!540/R-95/128,
    PB
    96-963502
    (May
    1996).

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED AMENDMENTS
    “Soil
    Screening
    Guidance:
    User’s
    Guide”,
    EPA
    Publication
    No.
    EPA/540/R-96/018,
    PB
    96-963505
    (April
    1996).
    “Superfund
    Exposure
    Assessment
    Manual”,
    EPA
    Publication
    No.
    EPA/540/1-88/001
    (April
    1988).
    “Supplemental
    Guidance
    for Developing
    Soil Screening
    Levels
    for
    Superfund
    Sites”,
    OSWER
    Directive
    9355.4-24
    (December
    2002).
    “Technical
    Background
    Document
    for
    Draft
    Soil
    Screening
    Level
    Framework,
    Review
    Draft,”
    EPA
    Publication
    No.
    EPAJ54O-R-94-106.
    PB95-963532. (July
    1994).
    “Users
    Guide
    for
    Evaluating
    Subsurface
    Vapor
    Intrusion
    into
    Buildings,”
    EPA.
    EPAJ68/W-02/33,
    (February
    2004).
    Polynuclear
    Aromatic
    Hydrocarbon
    Background
    Study
    City
    of
    Chicago,
    Tetra
    Tech
    Em
    Inc., 200
    E.
    Randolph
    Drive,
    Suite
    4700,
    Chicago,
    IL 60601,
    February
    24,
    2003.
    Polycyclic
    Aromatic
    Hydrocarbons
    PM{s)
    in
    Surface
    Soil
    ni Illinois:
    Background
    PAils,
    EPRI,
    Palo
    Alto,
    CA,
    We
    Energies,
    Milwaukee,
    WI,
    and
    IEPA,
    Springfield,
    IL:
    2004.
    1011376.
    EPRI,
    3412
    Hillview
    Avenue,
    Palo
    Altos
    CA
    94304,
    (800)
    313
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    Facility
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    (EPA
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    W-89-031),
    4
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    1989).
    United
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    Agency,
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    Environmental
    Information (2000).
    “Guidance
    for
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    Quality
    Assessment, Practical
    Methods
    for Data
    Analysis,”
    EPA
    QAIG-9,
    QAOO
    update.
    EPA
    Publication
    No.
    EPA/600/R-96-084.
    (Available
    online
    at
    www.epa.gov/oswer/riskassessment/pdf/ucl.pdf).
    United
    States
    Environmental
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    Agency,
    Office
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    Solid
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    Emergency
    Response
    (2003).
    “Human
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    in
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    Risk
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    OSWER Directive
    9285.7-53. (Available
    online
    at
    http
    ://www.
    epa. gov/oswer/riskassessment/pdflhhmemo.pdf).

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    United
    States
    Environmental
    Protection
    Agency,
    Compendium
    of Methods
    for
    Determination
    of
    Toxic
    Organic
    Compounds
    in
    Ambient
    Air,
    Second
    Edition,
    EPA
    Publication
    No.
    EPA/625/R-96/0
    lOb,
    January
    1999
    available
    at
    http
    ://www.epa.
    gov/ttnamti
    1/files/ambient/airtox/tocomp99.pdf
    United
    States
    Environmental
    Protection
    Agency,
    Test
    Methods
    for
    Evaluating
    Solid
    Waste,
    Physical/Chemical
    Methods,
    SW-846 through
    Revision
    IVB
    (February
    2007)
    available
    at
    http://www.epa.gov/sw-846/main.htm
    United
    States
    Environmental
    Protection
    Agency,
    CFR
    Promulgated
    Test
    Methods,
    Methods
    3C
    and
    16,
    Technology
    Transfer
    Network, Emission
    Measurement
    Center, (2007)
    available
    at http
    ://www.epa.
    gov/ttnlemc/promgate.html
    “Vapor Intrusion
    Pathway: A
    Practical
    Guide,”
    Technical
    and
    Regulatory
    Guidance.
    Interstate
    Technology
    and
    Regulatory
    Council
    (January
    2007).
    b)
    CFR
    (Code
    of
    Federal
    Regulations).
    Available
    from
    the Superintendent
    of
    Documents,
    U.S.
    Government
    Printing
    Office,
    Washington,
    D.C.
    20402
    (202)783-3238:
    40
    CFR
    761
    (1998).
    c)
    This
    Section
    incorporates
    no
    later
    editions
    or
    amendments.
    (Source: Amended
    at
    Ill.
    Reg.
    effective
    Section
    742.220
    Determination
    of Soil
    Saturation
    Limit
    a)
    For
    any
    organic
    contaminant
    that
    has
    a
    melting
    point
    below
    3
    0°C,
    the
    remediation
    objective
    for
    the
    outdoor
    and
    indoor
    inhalation
    exposure
    route
    developed
    under
    Tier
    2
    shall
    not
    exceed
    the
    soil
    saturation
    limit,
    as
    determined
    under
    subsection
    (c)
    of
    this
    Section.
    b)
    For
    any
    organic
    contaminant
    that
    has
    a
    melting
    point
    below
    30°C,
    the
    remediation
    objective under
    Tier
    2 for
    the
    soil
    component
    of
    the
    groundwater
    ingestion
    exposure route
    shall
    not
    exceed
    the
    soil
    saturation
    limit,
    as
    determined
    under
    subsection
    (c) of
    this
    Section.
    c)
    The
    soil
    saturation
    limit
    shall
    be:

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    1)
    The
    value
    listed
    in
    Appendix
    A, Table
    A
    for that
    specific
    contaminant.
    For
    the indoor
    inhalation
    exposure
    route,
    the
    value
    listed
    in
    Appendix
    A,
    Table
    L
    shall
    be
    uscjj
    2)
    A
    value
    derived
    from
    Equation
    S29
    in Appendix
    C,
    Table
    A-ef.
    For
    the
    indoor
    inhalation
    exposure
    route,
    the value
    derived
    from
    Equation
    J&E6a
    in
    Appendix
    C,
    Table
    L
    shall
    be
    used:
    or
    3)
    A
    value
    derived
    from
    another
    method
    approved
    by
    the Agency.
    (Source:
    Amended
    at
    Ill.
    Reg.
    effective
    Section
    742.222
    Determination
    of Soil
    Vapor
    Saturation
    Limit
    For
    any
    volatile
    chemical,
    the
    soil
    gas
    remediation
    objective
    for
    the
    indoor
    inhalation
    exposure
    route
    developed
    under
    Tier 2
    shall
    not exceed
    the
    soil
    vapor
    saturation
    limit,
    as determined
    under
    subsection
    (b)
    of
    this
    Section.
    The
    soil
    vapor
    saturation
    limit
    shall
    be:
    1)
    The
    value
    listed
    in Appendix
    A,
    Table
    K
    for
    that
    specific
    contaminant:
    2)
    A
    value
    derived
    from
    Equation
    J&E6b
    in Appendix
    C,
    Table
    L:
    or
    3)
    A
    value
    derived
    from
    another
    method
    approved
    by
    the
    Agency.
    (Source:
    Added
    at
    Ill.
    Reg.
    effective
    Section
    742.225
    Demonstration
    of
    Compliance with
    Remediation
    Objectives
    Compliance
    is
    achieved
    if each
    sample
    result
    does
    not exceed
    that
    respective
    remediation
    objective
    unless
    a person
    elects
    to
    proceed
    under
    subsections
    (c),
    (d)
    and
    (e)
    of
    this
    Section.
    a)
    Compliance
    with
    groundwater
    remediation
    objectives
    developed
    under
    Subparts
    D
    through
    F
    and
    H through
    I shall
    be
    demonstrated
    by
    comparing
    the
    contaminant
    concentrations
    of
    discrete
    samples
    at
    each
    sample
    point
    to the
    applicable
    groundwater remediation
    objective.
    Sample
    points
    shall
    be
    determined
    by
    the
    program
    under
    which
    remediation
    is performed.
    b)
    Unless
    the
    person
    elects
    to
    composite
    samples
    or
    average
    sampling
    results
    as
    provided
    in
    subsections
    (c)
    and
    (d) of
    this
    Section,
    compliance
    with
    soil

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    POLLUTION
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    OF PROPOSED
    AMENDMENTS
    remediation
    objectives
    developed
    under
    Subparts
    D
    through
    G
    and
    I
    shall
    be
    demonstrated
    by
    comparing
    the
    contaminant
    concentrations
    of
    discrete
    samples
    to
    the
    applicable
    soil
    remediation
    objective.
    1)
    Except
    as
    provided
    in
    subsections
    (c) and
    (d)
    of this
    Section,
    compositing
    of samples
    is not
    allowed.
    2)
    Except
    as provided
    in
    subsections
    (c)
    and
    (d) of
    this Section,
    averaging
    of
    sample
    results
    is
    not
    allowed.
    3)
    Notwithstanding
    subsections
    (c)
    and
    (d) of
    this Section,
    compositing
    of
    samples
    and averaging
    of sample
    results
    is
    not allowed
    for the
    construction
    worker
    population.
    4)
    The number
    of
    sampling
    points
    required
    to
    demonstrate
    compliance
    is
    determined
    by
    the requirements
    applicable
    to
    the
    program
    under
    which
    remediation
    is
    performed.
    Except
    as
    determined
    through
    a
    plan approved
    by
    the Agency
    in
    Tier
    3,
    compositing
    and
    averaging
    of
    sample
    results
    are not
    allowed
    for
    the
    indoor
    inhalation
    exposure
    route.
    c)
    If
    a person
    chooses
    to
    composite
    soil
    samples
    or
    average
    soil sample
    results
    to
    demonstrate
    compliance
    relative
    to
    the
    soil
    component
    of
    the
    groundwater
    ingestion
    exposure
    route,
    the
    following
    requirements
    apply:
    1)
    A
    minimum
    of
    two sampling
    locations
    for
    every
    0.5 acre
    of
    contaminated
    area is
    required,
    with
    discrete
    samples
    at
    each
    sample
    location
    obtained
    at
    every two
    feet
    of depth,
    beginning
    at
    six
    inches
    below
    the ground
    surface
    for surface
    contamination
    and
    at the
    upper
    limit
    of contamination
    for
    subsurface
    contamination
    and
    continuing
    through
    the
    zone
    of
    contamination.
    Alternatively,
    a sampling
    method
    may
    be approved
    by
    the
    Agency
    based
    on an
    appropriately
    designed
    site-specific
    evaluation.
    Samples
    obtained
    at or below
    the
    water
    table
    shall
    not be
    used in
    compositing or averaging.
    2)
    For
    contaminants
    of
    concern
    other
    than volatile
    organic
    contaminants
    chemicals:
    A)
    Discrete
    samples
    from
    the
    same
    boring
    may
    be
    composited;
    or

    ILLiNOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    B)
    Discrete
    sample
    results
    from
    the
    same
    boring
    may
    be averaged.
    3)
    For volatile
    organic
    contaminants
    chemicals:
    A)
    Compositing
    of
    samples
    is
    not allowed.
    B)
    Discrete
    sample
    results
    from
    the
    same
    boring
    may
    be
    averaged.
    4)
    Composite
    samples
    may
    not
    be
    averaged.
    An
    arithmetic
    average
    may
    be
    calculated
    for discrete
    samples
    collected
    at
    every
    two
    feet
    of depth
    through
    the
    zone
    of contamination
    as
    specified
    above
    in Section
    742.225(c)(1)
    of
    this Section.
    d)
    If
    a person
    chooses
    to composite
    soil
    samples
    or average
    soil
    sample
    results
    to
    demonstrate
    compliance
    relative
    to the
    outdoor
    inhalation
    exposure
    route
    or
    ingestion
    exposure
    routes,
    the
    following
    requirements
    apply:
    1)
    A person
    shall submit
    a
    sampling
    plan
    for
    Agency
    approval,
    based
    upon
    a
    site-specific
    evaluation;
    2)
    For volatile
    organic
    compounds
    chemicals,
    compositing
    of
    samples
    is
    not
    allowed;
    and
    3)
    All
    samples
    shall
    be collected
    within
    the
    contaminated
    area.
    4)
    Composite
    samples
    may
    not
    be averaged.
    Procedures
    specified
    in
    “Calculating
    Upper
    Confidence
    Limits
    for
    Exposure
    Point
    Concentrations
    at
    Hazardous
    Waste
    Sites”,
    USEPA
    Office
    of
    Emergency
    and
    Remedial
    Response,
    OSWER
    9285.6-10
    (December
    2002),
    as incorporated
    by
    reference
    in Section
    742.210,
    or an
    alternative
    procedure
    approved
    by
    the
    Agency,
    shall be
    used
    to determine
    sample
    averages.
    e)
    When
    averaging
    under
    this
    Section,
    if no
    more
    than
    15% of
    sample
    results
    are
    reported
    as
    “non-detect”,
    “no contamination”,
    “below
    detection
    limits”,
    or
    similar
    terms,
    such
    results
    shall
    be
    included
    in
    the averaging
    calculations
    as one-half
    the
    reported
    analytical
    detection
    limit
    for
    the
    contaminant.
    However,
    when
    performing
    a
    test
    for normal
    or
    lognormal
    distribution
    for
    the purpose
    of
    calculating
    a 95%
    Upper
    Confidence
    Limit
    of the mean
    for
    a contaminant,
    a
    person
    may
    substitute
    for
    each
    non-detect
    value a
    randomly
    generated
    value
    between,
    but not
    including,
    zero
    and
    the reported
    analytical
    detection
    limit.
    If
    more
    than
    15%
    of
    sample
    results
    are
    “non-detect”,
    procedures
    specified
    in

    ILLINOIS
    REGISTER
    POLLUTION
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    OF
    PROPOSED
    AMENDMENTS
    “Guidance
    for
    Data
    Quality
    Assessment,
    Practical
    Methods
    for
    Data
    Analysis,
    EPA
    QAJG-9,
    QAOO
    Update”, EPA!600/R-96/084
    (July
    2000),
    as
    incorporated
    by
    reference
    in
    Section
    742.2
    10,
    or
    an
    alternative
    procedure
    approved
    by
    the
    Agency
    shall
    be
    used
    to address
    the
    non-detect
    values,
    or
    another
    statistically
    valid
    procedure
    approved
    by
    the
    Agency
    may
    be
    used
    to
    determine
    an
    average.
    f)
    All
    soil
    samples
    collected after
    August
    15,
    2001,
    shall
    be
    reported
    on
    a dry
    weight
    basis
    for the
    purpose
    of
    demonstrating
    compliance,
    with
    the exception
    of
    the
    TCLP
    and
    SPLP
    and
    the
    property
    pH.
    (Source:
    Amended
    at
    Reg.
    effective
    Section 742.227
    Demonstration
    of
    Compliance with
    Soil
    Gas
    Remediation
    Objectives
    for
    the
    Indoor
    Inhalation
    Exposure
    Route
    Compliance
    shall
    be
    demonstrated
    by
    comparing
    the
    contaminant
    concentrations
    of
    discrete
    samples
    at
    each
    sample point
    to
    the applicable
    soil
    gas
    remediation
    objective
    contained
    in
    Appendix
    B,
    Table
    G.
    Sample
    points
    shall
    be
    determined
    by
    the program
    under
    which
    remediation
    is
    performed.
    )
    When
    collecting
    soil
    gas
    samples:
    1)
    Use
    rigid-wall
    tubing
    made
    of nylon
    or Teflon®
    or
    other
    material
    approved
    by
    the
    Agency;
    2)
    Use
    gas-tight,
    inert
    containers
    to
    hold
    the
    sample.
    For
    light
    sensitive
    or
    halogenated
    volatile
    chemicals,
    these
    containers
    shall
    be
    opaque
    or
    dark-
    colored;
    3)
    Purge
    three
    volumes
    before
    obtaining
    each
    discrete
    soil
    gas
    sample;
    4)
    Use
    a tracer
    of isopropyl
    alcohol
    or
    other
    leak
    compound
    approved
    by
    the
    Agency;
    and
    5)
    Limit
    the
    flow
    rate
    to
    200
    ml/min.
    Soil
    gas samples
    shall
    be analyzed
    using
    a National
    Environmental
    Laboratory
    Accreditation
    Program
    (NELAP)
    certified
    laboratory.

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF PROPOSED
    AMENDMENTS
    Soil gas
    remediation
    objectives
    shall
    be compared
    to
    concentrations
    of
    soil
    gas
    collected
    at a depth
    at
    least
    3 feet
    below
    ground
    surface
    and above
    the
    saturated
    zone.
    (Source:
    Added
    at
    Reg.
    effective
    SUBPART
    C:
    EXPOSURE
    ROUTE
    EVALUATIONS
    Section
    742.310
    Outdoor
    Inhalation
    Exposure
    Route
    The
    outdoor
    inhalation
    exposure
    route
    may
    be
    excluded
    from
    consideration
    if:
    a)
    The requirements
    of Sections
    742.300
    and 742.305
    are
    met;
    b)
    An approved
    engineered
    barrier
    is in
    place
    that meets
    the
    requirements
    of
    Subpart
    K;
    c)
    Safety
    precautions
    for
    the
    construction
    worker
    are
    taken
    if the
    Tier
    1
    construction
    worker
    remediation
    objectives
    are exceeded;
    and
    d)
    An
    institutional
    control,
    in
    accordance
    with
    Subpart
    J, will
    be
    placed
    on
    the
    property.
    (Source:
    Amended
    at
    Reg.
    effective
    Section
    742.312
    Indoor
    Inhalation
    Exposure
    Route
    The
    indoor
    inhalation
    exposure
    route
    may
    be
    excluded
    from
    consideration
    if:
    None
    of
    the contaminants
    of concern
    are
    listed
    on Appendix
    A,
    Table
    J
    and
    none
    of the
    contaminants
    of
    concern
    are
    volatile
    chemicals,
    as
    defined
    in
    Section
    742.200;
    or
    The
    following
    requirements
    in
    subsections
    (b)(1)(A)
    or
    (B),
    and
    (b)(2’)
    and
    (b)(3)
    are
    met:
    No
    building
    or man-made
    pathway
    exists
    or
    will
    be
    placed
    above
    the
    contaminated
    soil
    or
    groundwater;
    or
    An
    approved
    building
    control
    technology
    is
    in place
    that
    meets
    the
    requirements
    of Subpart
    L;
    and

    ILLiNOIS
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    AME1DMENTS
    The
    requirements
    of Sections
    742.300
    and
    742.3
    05 are
    met
    and
    An
    institutional
    control,
    in accordance
    with
    Subpart
    J,
    will
    be
    placed
    on
    the property.
    (Source:
    Added
    at
    Reg.
    effective
    SUBPART
    D:
    DETERMINING
    AREA
    BACKGROUND
    Section
    742.405
    Determination
    of
    Area
    Background
    for
    Soil
    a)
    Soil
    sampling
    results
    shall
    be
    obtained
    for
    purposes
    of determining
    area
    background
    levels
    in
    accordance
    with
    the
    following
    procedures:
    1)
    For volatile
    organic
    contaminants
    chemicals,
    sample
    results
    shall
    be
    based
    on discrete
    samples;
    2)
    Unless
    an
    alternative
    method
    is
    approved
    by
    the
    Agency,
    for
    contaminants
    other
    than
    volatile
    organic
    contaminants
    chemicals,
    sample
    results
    shall
    be
    based
    on
    discrete
    samples
    or
    composite
    samples.
    If
    a
    person
    elects
    to
    use
    composite
    samples,
    each
    0.5
    acre
    of the
    area
    to be
    sampled
    shall
    be
    divided
    into
    quadrants
    and
    5 aliquots
    of
    equal
    volume
    per quadrant
    shall
    be
    composited
    into
    1 sample;
    3)
    Samples
    shall
    be
    collected
    from
    similar
    depths
    and
    soil
    types,
    which
    shall
    be consistent
    with
    the
    depths
    and
    soil
    types
    in which
    maximum
    levels
    of
    contaminants
    are
    found
    in the
    areas
    of
    known
    or
    suspected
    releases;
    and
    4)
    Samples
    shall
    be
    collected
    from
    areas
    of the
    site
    or adjacent
    to
    the
    site
    that
    are unaffected
    by
    known
    or
    suspected
    releases
    at
    or
    from
    the
    site.
    If
    the
    sample
    results
    show
    an impact
    from
    releases
    at
    or from
    the
    site,
    then
    the
    sample
    results
    shall
    not
    be
    included
    in
    determining
    area
    background
    levels
    under
    this
    Part.
    b)
    Area
    background
    shall
    be
    determined
    according
    to
    one
    of
    the
    following
    approaches:
    1)
    Statewide
    Area
    Background
    Approach:

    ILLINOIS
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    AMENDMENTS
    A)
    The
    concentrations
    of
    inorganic
    chemicals
    in
    background
    soils
    listed
    in
    Appendix
    A,
    Table
    G may
    be
    used
    as
    the
    upper
    limit
    of
    the
    area
    background
    concentration
    for
    the
    site.
    The
    first
    column
    to
    the
    right
    of
    the
    chemical
    name
    presents inorganic
    chemicals
    in
    background
    soils
    for
    counties
    within
    Metropolitan
    Statistical
    Areas.
    Counties
    within
    Metropolitan
    Statistical
    Areas
    are
    identified
    in
    Appendix
    A,
    Table
    G,
    Footnote
    a.
    Sites
    located
    in
    counties
    outside
    Metropolitan
    Statistical
    Areas
    shall
    use
    the
    concentrations
    of
    inorganic
    chemicals
    in background
    soils
    shown
    in
    the
    second
    column
    to
    the
    right
    of
    the
    chemical
    name.
    B)
    Soil
    area
    background
    concentrations
    determined
    according
    to
    this
    statewide
    area
    background
    approach
    shall
    be
    used
    as
    provided
    in
    Section
    742.415(b)
    of
    this
    Part.
    For
    each
    parameter
    whose
    sampling
    results
    demonstrate
    concentrations
    above
    those
    in
    Appendix
    A,
    Table
    G,
    the
    person
    shall
    develop
    appropriate
    soil
    remediation
    objectives
    in
    accordance
    with
    this
    Part,
    or may
    determine
    area
    background
    in
    accordance
    with
    subsection
    (b)(2)
    of
    this
    Section.
    2)
    A
    statistically
    valid
    approach
    for
    determining
    area
    background
    concentrations
    appropriate
    for the
    characteristics
    of the
    data
    set,
    and
    approved
    by
    the
    Agency.
    (Source: Amended
    at
    Reg.
    effective
    SUBPART
    E: TIER
    1 EVALUATION
    Section 742.500
    Tier
    1 Evaluation
    Overview
    a)
    A
    Tier
    1
    evaluation
    compares
    the
    concentration
    of
    each
    contaminant
    of concern
    detected at a
    site
    to
    the
    baseline
    remediation
    objectives
    provided
    in
    Appendix
    B,
    Tables
    A, B,
    C,
    D
    and
    E
    and
    G.
    Use
    of
    Tier
    1
    remediation
    objectives
    requires
    only
    limited
    site-specific
    information:
    concentrations
    of
    contaminants
    of
    concern,
    groundwater
    classification,
    land
    use
    classification,
    and,
    if
    appropriate,
    soil
    pH.
    (See
    Appendix
    B,
    Illustration
    A.)
    b)
    Although Tier
    1
    allows
    for
    differentiation
    between
    residential and
    industrial/commercial
    property
    use
    of a
    site,
    an
    institutional
    control
    under
    Subpart
    J
    is
    required
    where
    remediation
    objectives
    are
    based
    on
    an
    industrial/commercial
    property
    use.

    ILUNOIS
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    OF
    PROPOSED
    AMENDMENTS
    c)
    Any
    given
    exposure
    route
    is
    not
    a
    concern
    if the
    concentration
    of
    each
    contaminant
    of
    concern
    detected
    at
    the
    site
    is
    below
    the
    Tier
    1
    value
    of
    that
    given
    route.
    In
    such
    a
    case,
    no further
    evaluation
    of
    that
    route
    is
    necessary.
    (Source: Amended
    at
    Reg.
    effective
    Section
    742.505
    Tier
    1
    Soil
    and
    Groundwater
    Remediation
    Objectives
    a)
    Soil
    1)
    Outdoor
    Inhalation
    Exposure
    Route
    A)
    The
    Tier
    1
    soil
    remediation
    objectives
    for
    this
    exposure
    route
    based
    upon
    residential
    property
    use
    are listed
    in Appendix
    B,
    Table
    A.
    B)
    The
    Tier
    1 soil
    remediation
    objectives
    for
    this
    exposure
    route
    based
    upon
    industrial/commercial
    property
    use
    are
    listed
    in
    Appendix
    B,
    Table
    B.
    Soil
    remediation
    objective
    determinations
    relying
    on
    this table
    require
    use of
    institutional
    controls
    in
    accordance
    with
    Subpart
    J.
    2)
    Ingestion
    Exposure
    Route
    A)
    The
    Tier
    1
    soil
    remediation
    objectives
    for
    this
    exposure
    route
    based
    upon
    residential
    property
    use
    are
    listed
    in
    Appendix
    B,
    Table
    A.
    B)
    The
    Tier
    1
    soil
    remediation
    objectives
    for
    this
    exposure
    route
    based
    upon
    industrial/commercial
    property
    use
    are
    listed
    in
    Appendix
    B,
    Table
    B.
    Soil
    remediation
    objective
    determinations
    relying
    on
    this
    table
    require
    use
    of
    institutional
    controls
    in
    accordance
    with
    Subpart
    J.
    3)
    Soil
    Component
    of
    the
    Groundwater
    Ingestion
    Route
    A)
    The
    Tier
    1 soil
    remediation objectives
    for
    this
    exposure
    route
    based
    upon
    residential
    property
    use
    are
    listed
    in
    Appendix
    B,
    Table
    A.

    ILLINOIS
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    B)
    The Tier
    1
    soil remediation
    objectives
    for
    this
    exposure
    route
    based
    upon
    industrial/commercial
    property
    use
    are listed
    in
    Appendix
    B,
    Table
    B.
    C)
    The pH-dependent
    Tier
    1
    soil remediation
    objectives
    for
    identified
    ionizable
    organics
    or
    inorganics
    for
    the
    soil
    component
    of
    the
    groundwater
    ingestion
    exposure
    route
    (based
    on
    the
    total
    amount
    of contaminants
    present
    in
    the
    soil
    sample
    results
    and
    groundwater
    classification)
    are
    provided
    in Appendix
    B,
    Tables
    C
    and
    D.
    D)
    Values
    used
    to calculate
    the
    Tier
    1
    soil
    remediation
    objectives
    for
    this
    exposure
    route
    are
    listed
    in
    Appendix
    B,
    Table
    F.
    4)
    Evaluation
    of
    the
    dermal
    contact
    with
    soil
    exposure
    route
    is not
    required
    under
    Tier
    1.
    For
    the
    soil component
    of the
    indoor
    inhalation
    exposure
    route,
    the
    requirements
    of
    Section
    742.515
    shall
    be
    followed.
    b)
    Groundwater
    1)
    The
    Tier 1
    groundwater
    remediation
    objectives
    for the
    groundwater
    component
    of
    the groundwater
    ingestion
    route
    are
    listed
    in
    Appendix
    B,
    Table
    E.
    2)
    The Tier
    1
    groundwater
    remediation
    objectives
    for this
    exposure
    route
    are
    given
    for
    Class
    I
    and
    Class
    II
    groundwaters,
    respectively.
    3)
    The
    evaluation
    of
    35 Ill.
    Adm.
    Code
    620.615
    regarding
    mixtures
    of
    similar-acting
    chemicals
    shall
    be
    considered
    satisfied
    for Class
    I
    groundwater
    at
    the point
    of
    human
    exposure if:
    A)
    No
    more
    than
    one
    similar-acting
    noncarcinogenic
    chemical
    as
    listed
    in
    Appendix
    A,
    Table
    E is
    detected
    in
    the groundwater
    at the
    site;
    and
    B)
    No carcinogenic contaminant
    of
    concern
    as
    listed
    in
    Appendix
    A,
    Table
    I is
    detected
    in
    any
    groundwater
    sample
    associated
    with
    the
    site, using
    analytical
    procedures
    capable
    of
    achieving
    either
    the
    1
    in
    1,000,000
    cancer
    risk
    concentration
    or
    the
    ADL,
    whichever
    is
    greater.

    ILLINOIS
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    4)
    If the
    conditions
    of
    subsection
    (b)(3)
    of this
    Section
    are
    not met,
    the
    Class
    I
    groundwater
    remediation
    objectives
    set
    forth
    in
    Appendix
    B,
    Table
    E
    shall
    be
    corrected
    for the
    cumulative
    effect
    of
    mixtures
    of
    similar-acting
    chemicals
    using the
    following
    methodologies:
    A)
    For
    noncarcinogenic
    chemicals,
    the methodologies
    set forth
    at
    Section
    742.805(c)
    or
    Section
    742.915(h)
    shall
    be used;
    and
    B)
    For
    carcinogenic
    chemicals,
    the methodologies
    set forth
    at
    Section
    742.805(d)
    or
    Section
    742.9
    15(h)
    shall
    be
    used.
    )
    For
    the groundwater
    component
    of the
    indoor
    inhalation
    exposure
    route,
    the
    requirements
    of Section
    742.515
    shall
    be
    followed.
    (Source:
    Amended
    at
    Reg.
    effective
    Section
    742.5
    10
    Tier 1
    Remediation
    Objectives
    Tables
    a)
    Soil
    remediation
    objectives
    are listed
    in
    Appendix
    B,
    Tables
    A, B,
    C
    and
    D,
    except
    for
    the
    indoor
    inhalation
    exposure
    route,
    in
    which
    the requirements
    of
    Section
    742.5
    15 and
    Appendix
    B,
    Table
    G shall
    be
    followed.
    1)
    Appendix
    B,
    Table
    A
    is based
    upon
    residential
    property
    use.
    A)
    The
    first
    column
    to the
    right
    of the
    chemical
    name
    lists
    soil
    remediation
    objectives
    for the
    soil
    ingestion
    exposure
    route.
    B)
    The
    second
    column
    lists
    the
    soil remediation
    objectives
    for
    the
    outdoor
    inhalation
    exposure
    route.
    C)
    The third
    and
    fourth
    columns
    list
    soil
    remediation
    objectives
    for
    the
    soil
    component
    of
    the
    groundwater
    ingestion
    exposure
    route
    for
    the
    respective
    classes
    of
    groundwater:
    i)
    Class
    I groundwater;
    and
    ii)
    Class
    II groundwater.
    D)
    The
    final
    colunm
    lists
    the Acceptable
    Detection
    Limit
    (ADL),
    only
    where
    applicable.

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    AMENDMENTS
    2)
    Appendix
    B,
    Table
    B
    is
    based
    upon
    industrial/commercial
    property
    use.
    A)
    The
    first
    and
    third columns
    to the
    right
    of the
    chemical
    name
    list
    the
    soil
    remediation
    objectives
    for the
    soil
    ingestion
    exposure
    route
    based
    on two
    receptor
    populations:
    i)
    Industrial/commercial;
    and
    ii)
    Construction
    worker.
    B)
    The
    second
    and
    fourth
    columns
    to
    the right
    of the
    chemical
    name
    list
    the
    soil remediation
    objectives
    for
    the outdoor
    inhalation
    exposure
    route
    based
    on two
    receptor
    populations:
    i)
    Industrial/commercial;
    and
    ii)
    Construction
    worker.
    C)
    The
    fifth
    and
    sixth
    columns
    to the
    right
    of the
    chemical
    name
    list
    the
    soil
    remediation
    objectives
    for the
    soil
    component
    of
    the
    groundwater
    ingestion
    exposure
    route
    for
    two
    classes
    of
    groundwater:
    i)
    Class
    I groundwater;
    and
    ii)
    Class
    II
    groundwater.
    j
    The
    final column
    lists the
    acceptable
    detection
    limit
    (ADL),
    only
    where
    applicable.
    3)
    Appendix
    B, Tables
    C
    and D
    set
    forth
    pH
    specific
    soil remediation
    objectives
    for inorganic
    and ionizing
    organic
    chemicals
    for
    the soil
    component
    of the
    groundwater
    ingestion
    route.
    A)
    Table
    C
    sets
    forth
    remediation
    objectives
    based
    on Class
    I
    groundwater
    and Table
    D sets
    forth
    remediation
    objectives
    based
    on Class
    II groundwater.
    B)
    The
    first
    column
    in
    Tables
    C
    and
    D lists
    the
    chemical
    names.

    ILLINOIS
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    AMENDMENTS
    C)
    The
    second
    through
    ninth
    columns
    to
    the
    right
    of the
    chemical
    names
    list
    the
    pH
    based
    soil
    remediation
    objectives.
    4)
    For
    the
    inorganic
    chemicals
    listed in Appendix
    B,
    Tables
    A
    and
    B,
    the
    soil
    component
    of the
    groundwater
    ingestion
    exposure
    route
    shall
    be
    evaluated
    using
    TCLP (SW-846
    Method
    1311)
    or
    SPLP
    (SW-846
    Method
    1312),
    incorporated
    by
    reference at
    Section 742.2
    10
    unless
    a
    person
    chooses
    to
    evaluate
    the
    soil
    component
    on
    the
    basis
    of
    the
    total
    amount
    of
    contaminant
    in
    a
    soil
    sample
    result
    in
    accordance
    with
    subsection
    (a)(5)
    of
    this
    Section.
    5)
    For
    those
    inorganic
    and
    ionizing’ organic
    chemicals
    listed
    in Appendix
    B,
    Tables
    C
    and
    D,
    if
    a
    person elects
    to evaluate
    the
    soil
    component
    of
    the
    groundwater
    ingestion
    exposure
    route
    based
    on
    the
    total
    amount
    of
    contaminant
    in
    a
    soil
    sample
    result
    (rather
    than
    TCLP
    or
    SPLP
    analysis),
    the
    person
    shall
    determine
    the
    soil
    pH
    at
    the
    site
    and
    then
    select
    the
    appropriate
    soil
    remediation
    objectives
    based
    on
    Class
    I
    and
    Class
    II
    groundwaters
    from
    Tables
    C
    and
    D,
    respectively.
    If
    the
    soil
    pH
    is
    less
    than
    4.5
    or
    greater
    than
    9.0,
    then
    Tables
    C
    and
    D
    cannot
    be
    used.
    6)
    Unless one
    or
    more
    exposure
    routes
    are
    excluded
    from
    consideration
    under
    Subpart
    C,
    the
    most
    stringent
    soil
    remediation
    objective
    of
    the
    exposure
    routes
    (i.e.,
    soil
    ingestion
    exposure
    route,
    outdoor and
    indoor
    inhalation
    exposure
    routes,
    and
    soil
    component
    of
    the
    groundwater
    ingestion
    exposure
    route)
    shall
    be
    compared
    to
    the
    concentrations
    of
    soil
    contaminants
    of
    concern
    measured
    at
    the
    site.
    When
    using
    Appendix
    B,
    Table
    B
    to
    select
    soil
    remediation
    objectives
    for
    the
    ingestion
    exposure
    route
    and
    outdoor
    inhalation
    exposure
    routes,
    the
    remediation
    objective
    shall
    be
    the
    more
    stringent
    soil
    remediation
    objective
    of
    the
    industrial/commercial
    populations
    and
    construction
    worker
    populations.
    7)
    Confirmation
    sample
    results
    may
    be
    averaged
    or
    soil
    samples
    may
    be
    composited
    in
    accordance
    with
    Section
    742.225.
    8)
    If
    a
    soil
    remediation
    objective
    for
    a chemical
    is
    less
    than
    the
    ADL,
    the
    ADL
    shall
    serve
    as
    the
    soil
    remediation
    objective.
    b)
    Groundwater
    remediation
    objectives
    for
    the
    groundwater
    component
    of the
    groundwater
    ingestion
    exposure
    route
    are
    listed
    in
    Appendix
    B, Table
    E.
    However,
    Appendix
    B,
    Table
    E must
    be
    corrected
    for
    cumulative
    effect
    of

    ILLINOIS
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    POLLUTION
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    AMENDMENTS
    mixtures
    of
    similar-acting
    noncarcinogenic
    chemicals
    as set
    forth
    in
    Section
    742.505(b)(3).
    1)
    The first
    colunm
    to the
    right
    of the chemical
    name
    lists
    groundwater
    remediation
    objectives
    for Class
    I
    groundwater,
    and
    the
    second
    colunm
    lists the
    groundwater
    remediation
    objectives
    for Class
    II
    groundwater.
    2)
    To use
    Appendix
    B, Table
    E
    of this
    Part, the
    35 Iii.
    Adm.
    Code
    620
    classification
    for
    groundwater
    at the site
    shall
    be determined.
    The
    concentrations
    of
    groundwater
    contaminants
    of
    concern
    at
    the site
    are
    compared
    to
    the applicable
    Tier
    1 groundwater
    remediation
    objectives
    for
    the
    groundwater
    component
    of the
    groundwater
    ingestion
    exposure
    route
    in
    Appendix
    B, Table
    E.
    c)
    For
    contaminants
    of
    concern
    not
    listed
    in Appendix
    B,
    Tables
    A, B
    and
    E,
    a
    person
    may
    request
    site-specific
    remediation
    objectives
    from
    the
    Agency
    or
    propose
    site-specific
    remediation
    objectives
    in
    accordance
    with
    35 Ill. Adm.
    Code
    620,
    Subpart
    I
    of
    this Part,
    or
    both.
    (Source:
    Amended
    at
    Ill.
    Reg.
    effective
    Section
    742.5
    15
    Tier
    1
    Remediation
    Objectives
    Table
    for
    the Indoor
    Inhalation
    Exposure
    Route
    Soil
    remediation
    objectives
    for the
    indoor
    inhalation
    exposure
    route
    are listed
    in
    ppendix
    B,
    Table
    G.
    1)
    The
    first
    column
    to
    the right
    of
    the
    chemical
    name
    lists
    the
    soil
    remediation
    objectives
    for residential
    receptors.
    2)
    The second
    column
    lists the
    soil remediation
    objectives
    for
    industriallcommercial
    receptors.
    3)
    The third
    column
    lists
    the
    Acceptable
    Detection
    Limit (ADL),
    only
    where
    applicable.
    If the
    soil remediation
    objective
    for
    a volatile
    chemical
    is
    less
    than
    the
    ADL,
    the
    ADL
    shall serve
    as
    the
    soil
    remediation
    objective.
    j
    Groundwater
    remediation
    objectives
    for
    the
    indoor
    inhalation
    exposure
    route
    are
    listed
    in
    Appendix
    B.
    Table
    G.

    ILLINOIS
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    AMENDMENTS
    1)
    The
    fourth
    column
    to
    the
    right
    of
    the chemical
    name
    lists
    the
    groundwater
    remediation
    objective
    for
    residential
    receptors.
    2)
    The
    fifth column
    to
    the
    right
    of
    the
    chemical
    name
    lists
    the
    groundwater
    remediation
    objective
    for
    industrial/commercial
    receptors.
    Soil
    gas
    remediation objectives
    for
    the
    indoor
    inhalation
    exposure
    route
    are
    listed
    in
    Appendix
    B,
    Table
    G.
    1)
    The
    sixth
    colunm
    to the
    right
    of
    the
    chemical
    names
    lists
    the
    soil
    gas
    remediation objectives
    for residential
    receptors.
    2)
    The
    seventh
    column
    to
    the
    right
    of the
    chemical
    name
    lists
    the
    soil
    gas
    remediation
    objectives
    for
    industriallcommercial
    receptors.
    Unless
    the
    indoor
    inhalation
    exposure
    route
    is
    excluded
    from
    consideration
    under
    Subpart
    C,
    Tier
    1
    remediation
    objectives
    for the
    indoor
    inhalation
    exposure
    route
    shall
    be
    used
    for:
    1)
    soil
    and
    groundwater,
    or
    2)
    soil
    gas.
    ci
    If using
    soil
    and
    groundwater
    remediation
    objectives
    to
    demonstrate
    compliance,
    then
    in accordance
    with
    Section
    742.51
    O(a)(6), the
    most
    stringent
    soil
    remediation
    objective
    and
    the
    most
    stringent
    groundwater
    remediation
    objective
    of
    the
    exposure
    routes
    from
    Appendix
    B,
    Tables
    A, B,
    E,
    and
    G
    shall
    be
    applied
    to
    the
    site,
    unless
    one
    or
    more
    exposure
    routes
    are
    excluded
    under
    Subpart
    C.
    Where
    a
    route(s)
    is
    excluded,
    use
    the most
    stringent
    remediation
    objective
    of
    the
    routes
    remaining.
    fl
    For
    volatile
    chemicals
    not
    listed
    in
    Appendix
    B,
    Table
    G. a
    person
    may
    request
    site-specific
    remediation
    objectives
    from
    the
    Agency
    or
    propose
    site-specific
    remediation
    objectives
    in
    accordance
    with
    Subpart
    I
    of
    this
    Part,
    or
    both.
    (Source:
    Added at
    Ill.
    Reg.
    effective
    SUBPART F:
    TIER
    2
    GENERAL
    EVALUATION
    Section
    742.600
    Tier
    2 Evaluation
    Overview
    a)
    Tier
    2
    remediation objectives
    are
    developed
    through
    the
    use
    of equations
    which
    allow
    site-specific
    data
    to
    be
    used.
    (See
    Appendix
    C, Illustrations
    A
    and
    B.)
    The

    ILLINOIS
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    AMENDMENTS
    equations, identified
    in
    Appendix
    C,
    Tables
    A,
    a4
    C, and
    L
    may
    be
    used
    to
    develop
    Tier
    2
    remediation
    objectives.
    b)
    Tier
    2 evaluation
    is only
    required
    for
    contaminants
    of concern and
    corresponding
    exposure
    routes
    (except
    where
    excluded
    from
    further
    consideration
    under
    Subpart
    C)
    exceeding
    the
    Tier
    1
    remediation
    objectires.
    When
    conducting
    Tier
    2
    evaluations,
    the
    values
    used
    in
    the
    calculations
    must
    have
    the
    appropriate
    units
    of
    measure
    as
    identified
    in
    Appendix
    C,
    Tables
    B, a4
    D,
    and
    M.
    c)
    Any
    development
    of remediation
    objectives
    using
    site-specific
    information
    or
    equations
    outside
    the
    Tier
    2
    framework
    shall
    be
    evaluated
    under
    Tier
    3.
    d)
    Any
    development
    of
    a remediation
    objective
    under
    Tier
    2
    shall
    not
    use
    a
    target
    hazard
    quotient
    greater
    than
    one
    at the
    point
    of human exposure
    or
    a target
    cancer
    risk
    greater
    than
    1
    in
    1,000,000
    at the
    point
    of
    human
    exposure.
    e)
    In conducting
    a Tier
    2
    evaluation,
    the
    following
    conditions
    shall
    be
    met:
    1)
    For
    each
    discrete
    sample,
    the
    total
    soil
    contaminant
    concentration
    of
    either
    a
    single
    contaminant
    or
    multiple
    contaminants
    of
    concern
    shall
    not
    exceed
    the
    attenuation
    capacity
    of
    the
    soil
    as
    provided
    in Section 742.215.
    2)
    Remediation
    objectives
    for
    noncarcinogenic
    compounds which
    affect
    the
    same
    target
    organ,
    organ
    system
    or
    similar
    mode
    of
    action
    shall
    meet
    the
    requirements
    of Section
    742.720.
    3)
    The
    soil
    remediation
    objectives
    based
    on
    the
    outdoor and
    indoor
    inhalation
    exposure
    routes
    and
    the
    soil
    component
    of
    the
    groundwater
    ingestion
    exposure
    routes
    shall
    not
    exceed
    the
    soil
    saturation
    limit
    as
    provided
    in
    Section
    742.220.
    4
    The
    soil
    gas
    remediation
    objectives
    based
    on
    the
    indoor
    inhalation
    exposure
    route
    shall
    not
    exceed
    the
    soil
    vapor
    saturation
    limit
    as
    provided
    in
    Section
    742.222.
    Tier
    2 remediation
    objectives
    for
    the
    indoor
    inhalation
    exposure
    route
    shall
    be
    calculated, as
    appropriate,
    for
    1)
    soil
    and
    groundwater,
    or
    2)
    soil
    gas.
    g
    If the
    calculated
    Tier
    2
    soil
    remediation
    objective
    for
    an applicable
    exposure
    route
    is more
    stringent
    than
    the corresponding
    Tier
    1 remediation
    objective, then
    the
    Tier
    1
    remediation
    objective
    applies.

    ILLINOIS
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    g)
    If the
    calculated
    Tier
    2 soil
    remediation
    objective
    for
    an
    exposure
    route
    is
    more
    stringent
    than
    the Tier
    1
    soil remediation
    objective(s)
    for
    the
    other
    exposure
    routes,
    then
    the
    Tier
    2
    calculated
    soil remediation
    objective
    applies
    and
    Tier
    2 soil
    remediation
    objectives
    for
    the
    other
    exposure
    routes
    are
    not
    required.
    j)
    If
    the calculated
    Tier
    2 soil
    remediation
    objective
    is
    less
    stringent
    than
    one
    or
    more
    of
    the
    soil
    remediation
    objectives
    for the
    remaining
    exposure
    routes,
    then
    the
    Tier
    2 values
    are
    calculated
    for
    the
    remaining
    exposure
    route(s)
    and
    the
    most
    stringent
    Tier
    2
    calculated value
    applies.
    (Source: Amended
    at
    Ill.
    Reg.
    effective
    Section
    742.605
    Land
    Use
    a)
    Present
    and
    post-remediation
    land
    use
    is
    evaluated
    in a
    Tier
    2 evaluation.
    Acceptable
    exposure
    factors
    for
    the
    Tier
    2 evaluation
    for
    residential,
    industrial/commercial,
    and
    construction
    worker
    populations
    are
    provided
    in
    the
    far right
    column
    of
    Appendix
    C,
    Tables
    B
    a4
    D
    1 and
    M.
    Use
    of
    exposure
    factors
    different
    from
    those
    in
    Appendix
    C,
    Tables
    B,
    n4
    D, and
    M must
    be
    approved
    by
    the
    Agency
    as
    part of
    a Tier
    3
    evaluation.
    b)
    If
    a Tier
    2 evaluation
    is
    based
    on an
    industrial/commercial
    property
    use,
    then:
    1)
    Construction worker
    populations
    shall
    also
    be evaluated;
    and
    2)
    Institutional controls
    are required
    in accordance
    with
    Subpart
    J.
    (Source:
    Amended
    at
    Ill.
    Reg.
    effective
    Section
    742.6
    10
    Chemical
    and Site
    Properties
    a)
    Physical
    and
    Chemical Properties
    of
    Contaminants
    Tier 2
    evaluations
    require information
    on
    the physical
    and
    chemical
    properties
    of
    the contaminants
    of
    concern.
    The
    physical
    and
    chemical
    properties
    used
    in
    a Tier
    2
    evaluation
    are
    contained
    in Appendix
    C,
    Table
    E.
    If
    the site
    has
    contaminants
    not
    included
    in this
    table,
    a person
    may
    request
    the
    Agency
    to provide
    the
    applicable
    physical
    and
    chemical
    input
    values
    or
    may propose
    input
    values
    under
    Subpart
    I. If
    a person
    proposes
    to
    apply
    values
    other
    than
    those
    in Appendix
    C,

    ILLINOIS
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    AMENDMENTS
    Table
    E, or
    those
    provided
    by
    the
    Agency,
    the
    evaluation
    shall
    be
    considered
    under
    Tier
    3.
    b)
    Soil
    and
    Groundwater
    Parameters
    1)
    A
    Tier
    2
    evaluation
    requires
    examination
    of soil
    and
    groundwater
    parameters.
    The
    parameters
    that
    may
    be
    varied,
    and
    the
    conditions
    under
    which
    these
    parameters
    are
    determined
    as
    part
    of Tier
    2,
    are
    summarized
    in
    Appendix
    C,
    Tables
    B
    1
    and
    D
    1
    and
    M.
    If
    a person
    proposes
    to vary
    site-
    specific
    parameters outside
    of
    the framework
    of
    these
    tables,
    the
    evaluation
    shall
    be
    considered
    under
    Tier
    3.
    2)
    To determine
    site-specific
    physical
    soil
    parameters,
    a minimum
    of
    one
    boring
    per
    0.5
    acre
    of
    contamination
    shall
    be
    collected.
    This
    boring
    must
    be
    deep
    enough
    to
    allow
    the
    collection
    of the
    required
    field
    measurements.
    The
    site-specific
    physical
    soil
    parameters
    must
    be
    determined
    from
    the
    portion
    of
    the
    boring representing
    the
    stratigraphic
    unit(s)
    being
    evaluated.
    For
    example,
    if
    evaluating
    the
    soil
    component
    of the
    groundwater
    ingestion
    exposure
    route,
    two
    samples
    from
    the
    boring
    will
    be
    required:
    A)
    A
    sample
    of
    the
    predominant
    soil
    type
    for
    the
    vadose
    zone;
    and
    B)
    A sample
    of
    the
    predominant
    soil
    type
    for
    the
    saturated
    zone.
    3)
    A
    site-specific
    SSL
    dilution
    factor
    (used
    in
    developing
    soil
    remediation
    objectives based
    upon
    the
    protection
    of groundwater)
    may
    be
    determined
    by
    substituting
    site
    information
    in
    Equation
    S22
    in
    Appendix
    C,
    Table
    A.
    To
    make
    this
    demonstration,
    a
    minimum
    of
    three
    monitoring
    wells
    shall
    be
    used
    to
    determine
    the
    hydraulic
    gradient.
    As
    an alternative,
    the
    default
    dilution
    factor
    value
    listed
    in
    Appendix
    C,
    Table
    B may
    be
    used.
    If
    monitoring
    wells
    are
    used
    to
    determine
    the
    hydraulic
    gradient,
    the
    soil
    taken
    from
    the
    borings
    shall
    be
    visually
    inspected
    to
    ensure
    there
    are
    no
    significant
    differences in
    the
    stratigraphy.
    If there
    are
    similar
    soil
    types
    in
    the field,
    one
    boring
    shall
    be
    used
    to
    determine
    the
    site-specific
    physical
    soil
    parameters.
    If
    there
    are
    significant
    differences,
    all
    of
    the
    borings
    shall
    be
    evaluated
    before
    determining
    the
    site-specific
    physical
    soil
    parameters
    for
    the
    site.
    4)
    Not
    all
    of
    the
    parameters
    identified
    in
    Appendix
    C,
    Tables
    B
    1
    and
    D1
    and
    Mneed
    to be
    determined
    on a
    site-specific
    basis.
    A
    person
    may
    choose
    to

    ILLINOIS
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    OF PROPOSED AMENDMENTS
    collect
    partial
    site-specific
    information
    and
    use
    default
    values
    as
    listed
    in
    Appendix
    C,
    Tables
    B
    and D
    and
    M for
    the
    rest
    of the
    parameters.
    (Source: Amended
    at
    Ill.
    Reg.
    effective
    SUBPART
    G:
    TIER
    2
    SOIL
    EVALUATION
    Section
    742.700
    Tier 2
    Soil
    Evaluation
    Overview
    a)
    Tier
    2 remediation
    objectives
    are
    developed
    through the
    use of
    models
    which
    allow
    site-specific
    data
    to
    be considered.
    Appendix
    C,
    Tables
    A
    and
    C,
    and
    L
    list
    equations
    that shall
    be
    used
    under
    a
    Tier
    2
    evaluation
    to calculate
    soil
    remediation
    objectives
    prescribed
    by
    SSL
    and RBCA,
    and
    the modified
    J&E
    models,
    respectively.
    (See
    also
    Appendix
    C,
    Illustration
    A.)
    b)
    Appendix
    C,
    Table
    A lists
    equations
    that
    are used
    under
    the
    SSL
    model.
    (See
    also
    Appendix
    C,
    Illustration
    A.)
    The
    SSL
    model
    has
    equations
    to
    evaluate
    the
    following
    human
    exposure
    routes:
    1)
    Soil
    ingestion
    exposure
    route;
    2)
    Outdoor
    Inhalation
    exposure
    route
    for:
    A)
    Organic
    contaminants;
    B)
    Fugitive
    dust;
    and
    3)
    Soil
    component
    of
    the groundwater
    ingestiOn
    exposure
    route.
    c)
    Evaluation
    of
    the
    dermal
    exposure
    route
    is
    not
    required
    under
    the SSL
    model.
    d)
    Appendix
    C,
    Table
    C
    lists
    equations
    that
    are
    used
    under
    the
    RBCA
    model.
    (See
    also
    Appendix
    C,
    Illustration
    A.)
    The
    RBCA
    model
    has
    equations
    to
    evaluate
    human
    exposure
    based
    on
    the
    following:
    1)
    The
    combined
    exposure
    routes
    of outdoor
    inhalation
    of
    vapors
    and
    particulates,
    soil ingestion
    and
    dermal
    contact
    with
    soil;
    2)
    The
    ambient
    vapor
    inhalation
    (outdoor)
    outdoor
    inhalation
    exposure
    route
    from
    subsurface
    soils;

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
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    NOTICE
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    PROPOSED
    AMENDMENTS
    Appendix
    C,
    Table
    L
    lists
    equations
    that
    are
    used
    under
    the
    modified
    J&E
    model.
    The
    modified
    J&E
    model
    has
    equations
    to evaluate
    human
    exposure
    by
    the
    indoor
    inhalation
    exposure
    route.
    The
    modified
    model
    allows
    for the
    development
    of
    soil
    remediation
    objectives
    and soil
    gas
    remediation
    objectives.
    e)
    The
    equations
    in
    either
    Appendix
    C,
    Table
    1
    A 8f
    C,
    or L
    may
    be
    used
    to
    calculate
    remediation
    objectives
    for
    each contaminant
    of concern
    under
    Tier
    2, if
    the
    following
    requirements
    are met:
    1)
    The
    Tier 2
    soil
    remediation
    objectives
    for
    the ingestion
    and
    outdoor
    inhalation
    exposure
    routes
    shall
    use the
    applicable
    equations
    from
    the
    same
    approach
    (i.e.,
    SSL equations
    in
    Appendix
    C,
    Table
    C).
    For
    the
    indoor
    inhalation
    exposure
    route,
    only
    the J&E
    equations
    can
    be
    used.
    2)
    The
    equations
    used
    to
    calculate
    soil
    remediation
    objectives
    for
    the soil
    component
    of the
    groundwater ingestion
    exposure
    route
    are
    not
    dependent
    on the
    approach utilized
    to
    calculate
    soil
    remediation
    objectives
    for
    the
    other
    exposure
    routes.
    For
    example,
    it is acceptable
    to
    use
    the
    SSL
    equations
    for calculating
    Tier
    2
    soil
    remediation
    objectives
    for
    the
    ingestion
    and
    outdoor
    inhalation
    exposure
    routes,
    and
    the
    RBCA
    equations
    for
    calculating
    Tier
    2
    soil
    remediation
    objectives
    for
    the
    soil
    component
    of
    the
    groundwater
    ingestion
    exposure
    route.
    3)
    Combining
    equations
    from
    Appendix
    C,
    Tables
    A,
    awl
    C,
    and
    L
    to
    form
    a
    new
    model
    is
    not
    allowed.
    In
    addition,
    Appendix
    C,
    Tables
    A,
    and
    C,
    and
    L
    must
    use
    their
    own
    applicable
    parameters
    identified
    in
    Appendix
    C,
    Tables
    B
    1 awl
    D
    1
    and M,
    respectively.
    g
    #
    In calculating
    soil remediation objectives
    for
    industrial/commercial
    property
    use,
    applicable calculations
    shall
    be
    performed
    twice:
    once
    using
    industrial/commercial
    population default
    values
    and
    once
    using
    construction
    worker
    population
    default
    values.
    The
    more
    stringent
    soil
    remediation
    objectives
    derived
    from
    these
    calculations
    must
    be
    used
    for
    further
    Tier
    2
    evaluations.
    The
    indoor
    inhalation
    exposure
    route
    does
    not apply
    to the
    construction
    worker
    population.
    g
    Tier
    2 data
    sheets
    provided
    by
    the
    Agency
    shall
    be
    used
    to present
    calculated
    Tier
    2
    remediation
    objectives,
    if
    required
    by
    the
    particular
    program
    for
    which
    remediation
    is being
    performed.

    ILLiNOIS
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    POLLUTION
    CONTROL
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    NOTICE
    OF
    PROPOSED
    AME1DMENTS
    j
    h
    The
    RBCA
    equations
    which
    rely
    on
    the
    parameter
    Soil
    Water
    Sorption
    Coefficient
    (ks)
    can
    only
    be
    used
    for
    ionizing
    organics
    and
    inorganics
    by
    substituting
    values
    for
    k
    from
    Appendix
    C,
    Tables
    I
    and
    J,
    respectively.
    This
    will
    also
    require
    the
    determination
    of a
    site-specific
    value
    for
    soil
    pH.
    (Source: Amended
    at
    Ill.
    Reg.
    effective
    Section
    742.705
    Parameters
    for
    Soil
    Remediation
    Objective
    Equations
    a)
    Appendix
    C,
    Tables
    B
    1
    aii4
    D
    1
    and
    M
    list
    the
    input
    parameters
    for
    the
    SSL
    1
    aftd
    RBCA
    1
    and
    J&E
    equations,
    respectively.
    The
    first
    column
    lists
    each
    symbol
    as
    it
    is
    presented
    in
    the
    equation.
    The
    next column
    defines
    the
    parameters.
    The
    third
    column
    shows
    the
    units
    for
    the
    parameters.
    The
    fourth
    column
    identifies
    where
    infonnation
    on
    the
    parameters
    can
    be obtained
    (i.e.,
    field
    measurement,
    applicable
    equation(s),
    reference
    source,
    or default
    value). The
    last
    column
    identifies
    how
    the
    parameters
    can be
    generated.
    b)
    Default Values
    Default
    values
    are
    numerical
    values
    specified
    for
    use
    in
    the
    Tier
    2
    equations.
    The
    fourth
    column
    of
    Appendix
    C,
    Tables
    and
    1
    and
    M
    denotes
    if
    the
    default
    values
    are
    from
    the
    SSL
    model,
    RBCA model,
    the
    modified
    J&E
    model
    or
    some
    other
    source.
    The
    last
    column
    of Appendix
    C,
    Tables
    B
    1
    and
    D,
    and
    M
    lists
    the
    numerical
    values
    for
    the
    default
    values
    used
    in
    the
    SSL
    1
    and
    RBCA,
    and
    J&E
    equations, respectively.
    c)
    Site-specific
    Information
    Site-specific
    information
    is a
    parameter
    measured,
    obtained,
    or
    determined
    from
    the
    site
    to
    calculate
    Tier
    2
    remediation
    objectives.
    The
    fourth
    column
    of
    Appendix
    C,
    Tables
    B
    1 and
    D,
    and
    M
    identifies those
    site-specific
    parameters
    that
    may
    require
    direct
    field
    measurement.
    For
    some
    parameters,
    numerical
    default
    inputs
    have
    been
    provided
    in
    the
    last
    column
    of
    Appendix
    C,
    Tables
    B
    1
    and
    D1
    and
    M
    to
    substitute for
    site-specific
    information.
    In some
    cases,
    information
    on
    the
    receptor
    or
    soil
    type
    is required
    to
    select
    the
    applicable
    numerical
    default
    inputs.
    Site-specific
    information
    includes:
    1)
    Physical
    soil
    parameters identified
    in
    Appendix
    C,
    Table
    F.
    The
    second
    column
    identifies
    the
    location
    where
    the
    sample
    is to
    be
    collected.
    Acceptable
    methods
    for
    measuring
    or
    calculating
    these
    soil
    parameters
    are
    identified
    in
    the
    last
    column
    of
    Appendix
    C,
    Table
    F;

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    2)
    Institutional
    controls
    or engineered
    barriers, pursuant
    to
    Subparts
    J and
    K,
    describe
    applicable
    institutional
    controls
    and
    engineered
    barriers
    under
    a
    Tier
    2 evaluation;
    and
    3)
    Land
    use
    classification
    d)
    Toxicological-specific
    Information
    1)
    Toxicological-specific
    information
    is
    used
    to
    calculate
    Tier
    2
    remediation
    objectives
    for
    the
    following
    parameters,
    if applicable:
    A)
    Oral
    Chronic
    Reference
    Dose
    (RiD
    0
    ,
    expressed
    in mg/kg-d);
    B)
    Oral
    Subchronic
    Reference
    Dose
    (RfD,
    expressed
    in
    mg/kg-d,
    shall
    be
    used
    for
    construction
    worker
    remediation
    objective
    calculations);
    C)
    Oral
    Slope
    Factor
    (SF
    0
    ,
    expressed
    in
    (mg/kg-d)’);
    D)
    Inhalation
    Unit
    Risk
    Factor
    (TJRF
    expressed
    in (ig/m
    3
    )’);
    E)
    Inhalation
    Chronic
    Reference
    Concentration
    (RfC,
    expressed
    in
    mg/rn
    3
    );
    F)
    Inhalation
    Subchronic Reference
    Concentration
    (RfC,
    expressed
    in
    mg/rn
    3
    ,
    shall
    be
    used
    for
    construction
    worker
    remediation
    objective
    calculations);
    G)
    Inhalation Chronic
    Reference
    Dose
    (RlD,
    expressed
    in
    mg/kg-d);
    H)
    Inhalation
    Subchronic Reference
    Dose
    (RlD,
    expressed
    in
    mg/kg
    d,
    shall
    be
    used
    for
    construction
    worker
    remediation
    objective
    calculations);
    and
    I)
    Inhalation
    Slope
    Factor
    (SF
    1
    ,
    expressed
    in (mg/kg-d)’);
    2)
    Toxicological
    information
    can
    be
    obtained
    from
    S
    by
    following
    the
    guidelines
    in OSWER Directive
    9285.7-53,
    as
    incorporated
    by
    reference
    in
    Section
    742.2
    10,
    or
    the
    program
    under
    which
    the
    remediation
    is
    being
    performed.

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    e)
    Chemical-specific
    Information
    Chemical-specific
    information
    used to
    calculate
    Tier
    2 remediation
    objectives
    is
    listed
    in Appendix
    C,
    Table
    E.
    f)
    Calculations
    Calculating
    numerical
    values
    for
    some
    parameters
    requires
    the
    use of
    equations
    listed
    in Appendix
    C, Table
    A
    er
    C
    and
    L.
    The
    parameters
    that
    are
    calculated
    are
    listed in
    Appendix
    C,
    Tables
    B
    and
    D,
    and M.
    (Source:
    Amended
    at
    Reg.
    effective
    Section
    742.7 10
    SSL Soil
    Equations
    a)
    This
    Section
    sets
    forth
    the
    equations
    and
    parameters
    used
    to
    develop
    Tier
    2
    soil
    remediation
    objectives
    for the
    three
    exposure
    routes
    using
    the
    SSL
    approach.
    b)
    Soil
    Ingestion
    Exposure
    Route
    1)
    Equations
    S
    1 through
    S3 form
    the basis
    for
    calculating
    Tier 2
    remediation
    objectives
    for the
    soil ingestion
    exposure
    route using
    the
    SSL
    approach.
    Equation
    Si
    is used
    to
    calculate
    soil
    remediation
    objectives
    for
    noncarcinogenic
    contaminants.
    Equations
    S2
    and
    S3
    are used
    to
    calculate
    soil
    remediation
    objectives
    for
    carcinogenic
    contaminants
    for
    residential
    populations
    and
    industrial/commercial
    and
    construction
    worker
    populations, respectively.
    2)
    For
    Equations
    Si through
    S3,
    the
    SSL default
    values
    cannot
    be
    modified
    with
    site-specific
    information.
    c)
    Outdoor
    Inhalation
    Exposure
    Route
    1)
    Equations
    S4
    through
    S16,
    S26
    and
    S27 are
    used to
    calculate
    Tier
    2
    soil
    remediation
    objectives
    for the
    outdoor
    inhalation
    exposure
    route
    using
    the
    SSL
    approach.
    To
    address
    this
    exposure
    route,
    organic
    contaminants
    and
    mercury
    must be
    evaluated
    separately
    from
    fugitive
    dust
    using
    their
    own
    equations
    set
    forth
    in subsections
    (c)(2) and
    (c)(3)
    of this
    Section,
    respectively.

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    2)
    Organic
    Contaminants
    A)
    Equations
    S4
    through Si
    0
    are
    used
    to calculate
    Tier 2
    soil
    remediation
    objectives
    for organic
    contaminants
    and
    mercury
    based
    on the outdoor
    inhalation
    exposure route.
    Equation
    S4 is
    used
    to calculate
    soil
    remediation
    objectives
    for
    noncarcinogenic
    organic
    contaminants
    in
    soil
    for
    residential
    and
    industrial/commercial
    populations.
    Equation
    S5 is
    used to
    calculate
    soil
    remediation
    objectives
    for noncarcinogenic
    organic
    contaminants
    and
    mercury
    in
    soil
    for
    construction
    worker
    populations.
    Equation
    S6
    is used
    to
    calculate soil
    remediation
    objectives
    for
    carcinogenic
    organic contaminants
    in soil
    for
    residential
    and industriallcommercial
    populations.
    Equation
    S7 is
    used to calculate
    soil
    remediation
    objectives
    for
    carcinogenic
    organic
    contaminants
    in
    soil for construction
    worker
    populations.
    Equations
    S8 through
    Sb,
    S27
    and
    S28
    are used
    for
    calculating
    numerical
    values
    for
    some
    of the parameters
    in
    Equations
    S4
    through
    S7.
    B)
    For Equation
    S4, a numerical
    value
    for the
    Volatilization
    Factor
    (VP)
    can
    be
    calculated
    in accordance
    with
    subsection
    (c)(2)(F)
    of
    this
    Section.
    The
    remaining
    parameters
    in Equation
    S4
    have
    either
    SSL
    default
    values listed
    in Appendix
    C,
    Table
    B
    or
    toxicological-
    specific
    information
    (i.e.,
    RfC),
    which
    can
    be obtained
    from
    IRIS
    or requested
    from the
    program
    under which
    the
    remediation
    is
    being
    performed.
    C)
    For
    Equation
    S5,
    a numerical
    value for the
    Volatilization
    Factor
    adjusted
    for
    Agitation
    (VF’) can
    be
    calculated
    in
    accordance
    with
    subsection
    (c)(2)(G)
    of
    this
    Section.
    The
    remaining
    parameters
    in
    Equation
    S5
    have either
    SSL default
    values
    listed
    in
    Appendix
    C,
    Table
    B or toxicological-specific
    information
    (i.e.,
    RfC),
    which
    can be obtained
    from
    IRIS
    or
    requested
    from the
    program
    under
    which
    the
    remediation
    is being
    performed.
    D)
    For Equation
    S6,
    a
    numerical
    value
    for VF can
    be
    calculated
    in
    accordance
    with
    subsection
    (c)(2)(F)
    of this Section.
    The
    remaining
    parameters
    in Equation
    S6 have
    either
    default
    values
    listed
    in Appendix
    C, Table
    B or toxicological-specific
    information
    (i.e.,
    URF), which
    can be
    obtained
    from IRIS
    or
    requested
    from
    the
    program
    under which
    the
    remediation
    is being
    performed.

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    B)
    For
    Equation
    S7,
    a
    numerical
    value
    for
    VF’
    can
    be
    calculated
    in
    accordance
    with
    subsection
    (c)(2)(G)
    of
    this
    Section.
    The
    remaining
    parameters
    in
    Equation
    S7 have
    either
    default
    values
    listed
    in Appendix
    C,
    Table
    B
    or
    toxicological-specific
    information
    (i.e.,
    URF),
    which
    can
    be obtained
    from
    IRIS
    or
    requested
    from
    the
    program
    under
    which
    the
    remediation
    is
    being
    performed.
    F)
    The
    VF
    can
    be
    calculated
    for
    residential
    and
    industrial/commercial
    populations
    using
    one
    of
    the
    following
    equations
    based
    on
    the
    information
    known
    about
    the
    contaminant
    source
    and
    receptor
    population:
    i)
    Equation
    S8,
    in
    conjunction
    with
    Equation
    SlO,
    is
    used
    to
    calculate
    VF
    assuming
    an
    infinite
    source
    of
    contamination;
    or
    ii)
    If the
    area
    and
    depth
    of
    the
    contaminant
    source
    are
    known
    or can
    be
    estimated
    reliably,
    mass
    limit
    considerations
    may
    be
    used
    to
    calculate
    VF
    using
    Equation
    S26.
    G)
    The
    VF’
    can
    be
    calculated
    for
    the
    construction
    worker
    populations
    using
    one
    of the
    following
    equations
    based
    on
    the
    information
    known
    about
    the
    contaminant
    source:
    i)
    Equation
    S9 is
    used
    to
    calculate
    VF’
    assuming
    an infinite
    source
    of contamination;
    or
    ii)
    If
    the
    area
    and
    depth
    of
    the
    contaminant
    source
    are
    known
    or
    can
    be
    estimated
    reliably,
    mass
    limit
    considerations
    may
    be
    used
    to
    calculate
    VF’
    using
    Equation
    S27.
    3)
    Fugitive
    Dust
    A)
    Equations
    S
    11
    through
    S16
    are
    used
    to calculate
    Tier
    2 soil
    remediation
    objectives using
    the
    SSL
    fugitive
    dust
    model
    for
    the
    outdoor
    inhalation
    exposure
    route.
    Equation
    Sil
    is
    used
    to
    calculate
    soil
    remediation
    objectives
    for
    noncarcinogenic
    contaminants
    in fugitive
    dust
    for
    residential
    and
    industrial/commercial
    populations.
    Equation S12
    is
    used
    to
    calculate
    soil
    remediation
    objectives
    for
    noncarcinogenic

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    AMENDMENTS
    contaminants
    in fugitive
    dust
    for
    construction
    worker
    populations.
    Equation
    S
    13 is used
    to calculate
    soil
    remediation
    objectives
    for
    carcinogenic
    contaminants
    in
    fugitive
    dust for
    residential
    and
    industrial/commercial
    populations.
    Equation
    S14 is
    used
    to
    calculate
    soil remediation
    objectives
    for
    carcinogenic
    contaminants
    in fugitive
    dust
    for
    construction
    worker
    populations.
    Equations
    Si
    5
    and
    Si
    6 are
    used for
    calculating
    numerical
    quantities
    for
    some
    of the
    parameters
    in
    Equations
    Sil through
    Si4.
    B)
    For
    Equation
    Sli,
    a numerical
    value
    can
    be calculated
    for
    the
    Particulate
    Emission
    Factor
    (PEF)
    using
    Equation
    S15.
    This
    equation
    relies
    on
    various
    input parameters
    from
    a variety
    of
    sources.
    The
    remaining
    parameters
    in
    Equation
    S11
    have
    either
    SSL
    default
    values
    listed
    in Appendix
    C,
    Table
    B
    or
    toxicological-
    specific
    information
    (i.e.,
    RfC),
    which
    can
    be
    obtained
    from
    IRIS
    or
    requested
    from
    the program
    under
    which
    the
    remediation
    is
    being
    performed.
    C)
    For
    Equation
    Si2,
    a
    numerical
    value
    for
    the
    Particulate
    Emission
    Factor
    for
    Construction
    Worker
    (PEF’)
    can be
    calculated
    using
    Equation
    S16.
    The
    remaining
    parameters
    in
    Equation
    Si2
    have
    either
    SSL
    default
    values
    listed
    in
    Appendix
    C, Table
    B
    or
    toxicological-specific
    information
    (i.e.,
    RfC),
    which
    can
    be
    obtained
    from
    IRIS
    or
    requested
    from
    the
    program
    under
    which
    the
    remediation
    is
    being performed.
    D)
    For
    Equation
    S13,
    a numerical
    value
    for PEF
    can
    be calculated
    using
    Equation
    S15.
    The
    remaining
    parameters
    in
    Equation
    Si3
    have
    either
    default
    values
    listed
    in Appendix
    C,
    Table B
    or
    toxicological-specific
    information
    (i.e.,
    URF),
    which
    can
    be
    obtained
    from
    IRIS or
    requested
    from
    the
    program
    under
    which
    the
    remediation
    is
    being
    performed.
    E)
    For
    Equation
    S14, a
    numerical
    value
    for PEF’
    can
    be
    calculated
    using
    Equation
    Si6.
    The
    remaining
    parameters
    in Equation
    Si4
    have either
    default
    values
    listed
    in
    Appendix
    C,
    Table
    B
    or
    toxicological-specific
    information
    (i.e.,
    URF),
    which
    can
    be
    obtained
    from
    IRIS
    or
    requested
    from the
    program
    under
    which
    the
    remediation
    is
    being
    performed.
    d)
    Soil
    Component
    of
    the Groundwater
    Ingestion
    Exposure
    Route

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    AMENDMENTS
    The
    Tier
    2 remediation
    objective for
    the
    soil
    component
    of
    the
    groundwater
    ingestion
    exposure
    route
    can
    be
    calculated
    using
    one
    of
    the
    following
    equations
    based
    on
    the
    information
    known
    about
    the
    contaminant
    source
    and
    receptor
    population:
    1)
    Equation
    S17
    is
    used
    to
    calculate
    the
    remediation
    objective
    assuming
    an
    infinite
    source
    of
    contamination.
    A)
    The
    numerical
    quantities
    for
    four
    parameters
    in
    Equation
    S17,
    the
    Target
    Soil
    Leachate
    Concentration
    (C),
    Soil-Water
    Partition
    Coefficient
    (K)
    for
    non-ionizing
    organics,
    Water-Filled
    Soil
    Porosity Theta
    w
    (9w)
    and
    Air-Filled
    Soil
    Porosity
    Theta
    a
    (Oa),
    are
    calculated
    using
    Equations
    S18,
    S19,
    S20
    and
    S21,
    respectively.
    Equations
    S22,
    S23,
    S24
    and
    S25
    are
    also
    needed
    to
    calculate
    numerical
    values
    for
    Equations
    S18
    and
    S21.
    The
    pH-
    dependent
    Kd
    values
    for
    ionizing
    organics
    can
    be
    calculated
    using
    Equation
    Sl9
    and
    the
    pH-dependent
    Koc
    values
    in
    Appendix
    C,
    Table
    I.
    B)
    The
    remaining
    parameters
    in
    Equation
    Si
    7
    are
    Henry’s
    Law
    Constant
    (H’),
    a chemical
    specific
    value
    listed
    in
    Appendix
    C,
    Table
    E
    and
    Dry
    Soil
    Bulk
    Density
    (Pb),
    a
    site-specific
    based
    value
    listed
    in
    Appendix
    C,
    Table
    B.
    C)
    The
    default value
    for
    GW
    0b
    is
    the
    Tier
    1
    groundwater
    objective.
    For
    chemicals
    for
    which
    there
    is
    no
    Tier
    1
    groundwater
    remediation
    objective,
    the
    value
    for
    GW
    0b
    shall
    be
    the
    concentration
    determined
    according
    to
    the
    proccdures
    specified
    in
    35
    Iii.
    Adm.
    Code
    620,
    Subpart
    F.
    As
    an
    alternative
    to
    using
    Tier
    1
    groundwater
    remediation
    objectives
    or
    concentrations
    determined
    according
    to
    the
    procedures
    specified
    in
    35
    Iii.
    Adm.
    Code
    620,
    Subpart
    F.
    GW
    0b
    may
    be developed
    using
    Equations
    R25
    and
    R26,
    if approved
    institutional
    controls
    are
    in place
    as
    required
    in
    Subpart
    J.
    2)
    If
    the
    area
    and
    depth
    of
    the
    contaminant
    source
    are
    known
    or
    can
    be
    estimated
    reliably,
    mass
    limit
    considerations
    may
    be
    used
    to
    calculate
    the
    remediation
    objective
    for
    this
    exposure
    route
    using
    Equation S28.
    The
    parameters
    in
    Equation
    S28
    have
    default
    values
    listed
    in Appendix
    C,
    Table
    B.

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    OF
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    AMENIMENTS
    (Source: Amended
    at
    Ill.
    Reg.
    effective
    Section
    742.715
    RBCA
    Soil
    Equations
    a)
    This
    Section
    presents
    the
    RBCA
    model and
    describes
    the
    equations
    and
    parameters
    used
    to
    develop
    Tier
    2
    soil
    remediation
    objectives.
    b)
    Ingestion,
    Outdoor Inhalation,
    and
    Dermal
    Contact
    1)
    The
    two
    sets
    of
    equations
    in
    subsections
    (b)(2)
    and
    (b)(3)
    of
    this
    Section
    shall
    be
    used
    to
    generate
    Tier
    2 soil
    remediation
    objectives
    for
    the
    combined
    ingestion,
    outdoor
    inhalation,
    and
    dermal
    contact
    with
    soil
    exposure
    routes.
    2)
    Combined Exposure
    Routes
    of Soil
    Ingestion,
    Outdoor
    Inhalation
    of
    Vapors
    and
    Particulates,
    and
    Dermal
    Contact
    with
    Soil
    A)
    Equations
    Ri
    and
    R2
    form
    the
    basis
    for deriving
    Tier
    2
    remediation
    objectives
    for the
    set
    of
    equations that
    evaluates
    the
    combined
    exposure
    routes
    of soil
    ingestion,
    outdoor
    inhalation
    of
    vapors
    and
    particulates,
    and
    dermal
    contact
    with
    soil
    using
    the
    RBCA
    approach.
    Equation
    Ri
    is used
    to
    calculate
    soil
    remediation
    objectives
    for
    carcinogenic
    contaminants.
    Equation
    R2
    is
    used
    to
    calculate
    soil
    remediation
    objectives
    for
    noncarcinogenic
    contaminants.
    Soil
    remediation
    objectives
    for
    the
    ambient
    vapor
    inhalation
    (outdoor)
    outdoor inhalation
    exposure
    route
    from
    subsurface
    soils
    must
    also
    be
    calculated
    in accordance
    with
    the
    procedures
    outlined
    in
    subsection
    (b)(3)
    of
    this
    Section
    and
    compared
    to the
    values
    generated
    from
    Equations
    Ri
    or R2.
    The
    smaller
    value
    (i.e.,
    Ri
    and
    R2
    compared
    to R7
    and
    R8,
    respectively)
    from
    these
    calculations
    is the
    Tier
    2
    soil
    remediation
    objective
    for
    the
    combined
    exposure
    routes
    of
    soil
    ingestion,
    outdoor
    inhalation,
    and
    dermal
    contact
    with
    soil.
    B)
    In
    Equation
    Ri,
    numerical
    values
    are
    calculated
    for
    two
    parameters:
    i)
    The
    volatilization
    factor
    for
    surficial
    soils
    (VF)
    using
    Equations
    R3
    and
    R4;
    and

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    ii)
    The
    volatilization
    factor
    for
    subsurface
    soils
    regarding
    particulates
    (VF)
    using
    Equation
    R5.
    C)
    VF
    8
    uses
    Equations
    R3
    and R4
    to
    derive
    a
    numerical
    value.
    Equation
    R3
    requires
    the
    use
    of
    Equation
    R6.
    Both
    equations
    must
    be
    used
    to
    calculate
    the
    The
    lowest
    calculated
    value
    from
    these
    equations
    must
    be
    substituted
    into
    Equation
    Ri.
    D)
    The
    remaining
    parameters
    in
    Equation
    Ri
    have
    either
    default
    values
    listed
    in
    Appendix
    C,
    Table
    D
    or
    toxicological-specific
    information
    (i.e.,
    SF
    0
    ,
    SF
    1
    ),
    which
    can
    be
    obtained
    from
    IRIS
    or
    requested
    from
    the program
    under
    which
    the
    remediation
    is
    being
    performed.
    B)
    For
    Equation
    R2,
    the
    parameters
    VF
    and
    VF
    are
    calculated.
    The
    remaining
    parameters
    in
    Equation R2
    have
    either
    default
    values
    listed
    in
    Appendix
    C,
    Table
    D
    or
    toxicological-specific
    information
    (i.e.,
    RfDO,
    RiD
    1
    ),
    which
    can
    be
    obtained
    from
    IRIS
    or
    requested
    from
    the
    program
    under
    which
    the
    remediation
    is
    being
    performed.
    F)
    For
    chemicals
    other
    than
    inorganics
    which
    do
    not
    have
    default
    values
    for
    the
    dermal
    absorption
    factor
    (RAFd)
    in Appendix
    C,
    Table
    D,
    a
    dermal
    absorption
    factor
    of
    0.5
    shall
    be
    used
    for
    Equations
    Ri
    and
    R2.
    For
    inorganics,
    dermal absorption
    may
    be
    disregarded
    (i.e.,
    RAFd
    =
    0).
    3)
    Ambient
    Vapor
    Inhalation
    (outdoor)
    Outdoor
    Inhalation
    exposure
    route
    from
    Subsurface
    Soils
    (soil
    below
    one
    meter)
    A)
    Equations
    R7
    and
    R8
    form
    the basis
    for
    deriving
    Tier
    2
    remediation
    objectives
    for
    the
    ambient
    vapor
    inhalation
    (outdoor)
    outdoor
    inhalation
    exposure
    route
    from
    subsurface
    soils
    using
    the
    RBCA
    approach.
    Equation
    R7
    is used
    to
    calculate
    soil
    remediation
    objectives
    for
    carcinogenic
    contaminants.
    Equation
    R8
    is used
    to
    calculate
    soil
    remediation
    objectives
    for
    noncarcinogenic
    contaminants.
    B)
    For
    Equation
    R7,
    the
    carcinogenic
    risk-based
    screening
    level
    for
    air
    (RBSLair)
    and
    the
    volatilization
    factor
    for
    soils
    below
    one
    meter
    to
    ambient
    air
    (VFsamb)
    have
    numerical
    values
    that
    are
    calculated

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    using
    Equations
    R9
    and
    Ri
    1, respectively.
    Both
    equations
    rely
    on
    input
    parameters
    from
    a variety
    of
    sources.
    C)
    The
    noncarcinogenic
    risk-based
    screening
    level
    for
    air
    (RBSLair)
    and
    the
    volatilization
    factor
    for
    soils
    below
    one
    meter
    to
    ambient
    air
    (VFsamb)
    in Equation
    R8
    have
    numerical
    values
    that
    can
    be
    calculated
    using
    Equations
    RiO
    and
    Ri 1,
    respectively.
    c)
    Soil
    Component
    of
    the Groundwater
    Ingestion
    Exposure
    Route
    1)
    Equation
    R12
    forms
    the
    basis
    for deriving
    Tier
    2 remediation
    objectives
    for
    the soil
    component
    of the
    groundwater
    ingestion
    exposure
    route
    using
    the
    RBCA
    approach.
    The
    parameters,
    groundwater
    at
    the
    source
    (GWsource)
    and
    Leaching
    Factor
    (LF),
    have
    numerical
    values
    that
    are
    calculated
    using
    Equations
    Ri
    3
    and
    R14,
    respectively.
    2)
    Equation
    Ri
    3
    requires
    numerical
    values
    that
    are
    calculated
    using
    Equation
    R15.
    3)
    Equation
    R14
    requires
    numerical
    values
    that
    are
    calculated
    using
    Equations
    R21,
    R22,
    and
    R24.
    For
    non-ionizing
    organics,
    the
    Soil
    Water
    Sorption
    Coefficient
    k
    shall
    be
    calculated
    using
    Equation
    R20.
    For
    ionizing
    organics and
    inorganics,
    the
    values
    for
    (ks)
    are listed
    in
    Appendix
    C,
    Tables
    I and
    J,
    respectively.
    The pH-dependent
    k
    values
    for
    ionizing
    organics
    can
    be
    calculated
    using
    Equation
    R20
    and the
    pH-dependent
    values
    in Appendix
    C,
    Table
    I.
    The remaining
    parameters
    in
    Equation
    Ri4
    are
    field
    measurements
    or
    default
    values
    listed
    in
    Appendix
    C,
    Table
    D.
    d)
    The
    default
    value
    for
    GWcomp
    is the
    Tier
    1 groundwater
    remediation
    objective.
    For
    chemicals for which
    there
    is no
    Tier
    1
    groundwater
    remediation
    objective,
    the
    value
    for
    GWcomp
    shall
    be
    the
    concentration
    determined
    according
    to the
    procedures
    specified
    in
    35
    Ill.
    Adm.
    Code
    620,
    Subpart
    F.
    As an
    alternative
    to
    using
    the
    above
    concentrations,
    GWcomp
    may
    be
    developed
    using
    Equations
    R25
    and
    R26,
    if
    approved
    institutional
    controls
    are
    in
    place
    as
    may be
    required
    in
    SubpartJ.
    (Source:
    Amended
    at
    Ill. Reg.
    effective
    Section
    742.7
    17
    Indoor
    Inhalation
    Equations
    for
    Soil
    and
    Soil
    Gas

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    This
    Section
    sets
    forth
    the
    equations
    and
    parameters
    to
    be
    used
    to
    develop
    Tier
    2
    soil
    and
    soil
    gas
    remediation
    objectives
    for
    the
    indoor
    inhalation
    exposure
    route
    using
    the modified
    J&E
    model.
    Equations
    J&E1
    and
    J&E2
    calculate,
    for
    carcinogens
    and
    noncarcinogens
    respectively,
    an
    acceptable
    concentration
    of
    the
    contaminant
    of concern
    in
    indoor
    air
    that
    adequately
    protects
    humans
    who
    inhale
    this
    air.
    Equation
    J&E3
    converts
    indoor air concentrations
    from
    parts
    per
    million
    volume
    to
    milligrams
    per
    cubic
    meter.
    Equation
    J&E4
    calculates
    an
    acceptable
    concentration
    of
    the
    contaminant
    of
    concern in
    the
    soil
    gas
    at the
    source
    of
    contamination.
    This
    calculation
    is
    made
    using:
    (1)
    an attenuation
    factor
    developed
    in
    accordance
    with
    Equations
    J&E8b
    through
    18;
    and
    (2)
    the acceptable
    concentration
    of
    the
    contaminant
    of concern
    in
    indoor
    air
    calculated
    in
    accordance
    with
    Equation
    J&E1
    (for
    carcinogens)
    or
    J&E2
    (for
    noncarcinogens).
    4
    The
    attenuation
    factor
    (Equation J&E8b)
    accounts
    for
    the
    following
    processes:
    fl
    Migration
    of
    contaminants
    from
    the
    source
    upwards
    through
    the
    vadose
    zone;
    )
    Migration of
    contaminants
    through
    the
    earthen
    filled
    cracks
    in
    the
    slab-on-
    grade
    or
    basement
    floor
    and
    walls;
    and
    Mixing
    of
    the
    contaminants
    with
    air
    inside
    the
    building.
    Equation
    J&E8b
    is
    used
    where
    diffusion
    is the
    dominant
    transport
    mechanism.
    In
    this
    scenario,
    the
    Q-i
    value
    equals
    zero.
    Equations
    J&E9a
    through
    J&E18
    calculate
    input
    parameters
    for
    Equation
    J&E8b
    (the
    equation
    used
    to calculate
    an attenuation
    factor).
    These
    equations
    assume
    there
    are
    “n”
    different
    soil
    layers
    between
    the source
    of
    the
    contamination
    and
    the
    floor
    of
    the
    building.
    Equations
    J&E11, 16,
    17
    and
    18
    shall
    be used
    to
    calculate
    the
    needed
    parameters
    for
    each
    of
    the
    n
    layers
    (the
    general
    soil
    layer
    is
    referred
    to
    as
    soil
    layer
    “i”
    and
    i
    =
    1,2,
    .
    .
    .n).
    Equations
    J&E16,
    17,
    and
    18
    shall
    also
    be
    used
    to
    calculate
    needed
    parameters
    for
    the
    soil
    in
    the cracks
    of
    the
    floor
    of
    the
    building
    (it
    is
    through
    these
    cracks
    that
    contaminants
    flow
    from
    the
    subsurface
    and
    into
    the
    building).

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    g
    The default
    representative
    subsurface
    temperature
    for
    Henry’s
    Law
    Constant
    is
    13°C.
    This
    value
    shall
    be used,
    as
    appropriate,
    in
    all calculations
    needed
    to
    represent
    the system
    by
    which
    contaminants
    migrate
    through
    the
    subsurface.
    Equation
    J&E5
    calculates
    an
    acceptable
    soil
    remediation
    objective
    using:
    (1)
    the
    soil
    gas remediation
    objective
    calculated
    in
    accordance
    with
    Equation
    J&E4
    and
    (2)
    the
    assumption
    that
    this gas
    is in
    equilibrium
    with
    the
    contaminated
    soil
    at
    the
    source.
    The
    calculated
    soil
    remediation
    objective
    shall
    be
    compared
    with
    the
    saturated
    soil
    concentration
    (Cm,
    Equation
    J&E6a)
    for
    each
    chemical
    with
    a melting
    point
    less
    than
    3 0°C.
    The calculated
    C
    shall
    use the
    default
    representative
    subsurface
    temperature
    specified
    in
    742.717
    (g).
    If the
    calculated
    soil
    remediation
    objective
    is
    greater
    than
    C,
    then
    Cis
    used
    as
    the
    soil
    remediation
    objective.
    fl
    The
    calculated
    soil
    gas
    remediation
    objective
    shall
    be
    compared
    with
    the
    saturated
    vapor
    concentration
    (CSat,
    Equation
    J&E6b)
    for
    each
    volatile
    chemical.
    The
    calculated
    Csat
    shall
    use the
    default
    representative
    subsurface
    temperature
    specified
    in
    742.717(g).
    If
    the calculated
    soil gas
    remediation
    objective
    is
    greater
    than
    CSat,
    then
    Csat
    is
    used
    as
    the
    soil
    gas remediation
    objective.
    Ic)
    The
    calculated
    soil
    gas
    remediation
    objective
    shall
    be
    compared
    to
    concentrations
    of
    soil
    gas
    collected
    at a
    depth
    at
    least
    3
    feet
    below
    ground
    surface
    and
    above
    the
    saturated
    zone. If
    a valid
    sample
    cannot
    be collected,
    a
    soil
    gas
    sampling
    plan
    shall
    be approved
    by
    the
    Agency
    under
    Tier
    3.
    (Source:
    Added
    at
    Ill.
    Reg.
    effective
    SUBPART
    H:
    TIER
    2 GROUNDWATER
    EVALUATION
    Section
    742.805
    Tier
    2 Groundwater
    Remediation
    Objectives
    a)
    To
    develop
    a
    groundwater
    remediation
    objective
    under
    this
    Section
    that
    exceeds
    the
    applicable
    Tier
    1 groundwater
    remediation
    objective,
    or
    for which
    there
    is no
    Tier
    I groundwater
    remediation
    objective,
    a
    person
    may
    request
    approval
    from
    the
    Agency
    if the
    person
    has performed
    the following:
    1)
    Identified
    the
    horizontal
    and
    vertical
    extent
    of
    groundwater
    for
    which
    the
    Tier
    2 groundwater
    remediation
    objective
    is
    sought;

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    2)
    Taken
    corrective
    action,
    to
    the
    maximum
    extent
    practicable
    to
    remove
    any
    free
    product;
    3)
    Using
    Equation
    R26 in
    accordance
    with
    Section
    742.8
    10,
    demonstrated
    that
    the
    concentration
    of any
    contaminant
    of concern
    in
    groundwater
    will
    meet:
    A)
    The
    applicable
    Tier
    1
    groundwater
    remediation
    objective
    at
    the
    point
    of
    human
    exposure;
    or
    B)
    For
    any
    contaminant
    of
    concern
    for
    which
    there
    is
    no Tier
    1
    groundwater
    remediation
    objective,
    the concentration
    determined
    according
    to the
    procedures
    specified in
    35 III.
    Adm.
    Code
    620
    at
    the
    point
    of human
    exposure.
    A person
    may
    request
    the
    Agency
    to
    provide
    these
    concentrations
    or may
    propose
    these
    concentrations
    under
    Subpart
    I;
    4)
    Using
    Equation
    R26
    in accordance
    with
    Section
    742.8
    10,
    demonstrated
    that
    the
    concentration
    of
    any
    contaminant
    of
    concern
    in
    groundwater
    within
    the minimum
    or
    designated
    maximum
    setback
    zone
    of
    an
    existing
    potable
    water
    supply
    well
    will
    meet
    the
    applicable
    Tier
    1
    groundwater
    remediation
    objective
    or, if
    there
    is
    no
    Tier
    1
    groundwater
    remediation
    objective,
    the
    concentration
    determined
    according
    to
    the procedures
    specified
    in
    35
    Ill. Adm.
    Code
    620.
    A
    person
    may
    request
    the
    Agency
    to
    provide
    these
    concentrations
    or
    may
    propose
    these
    concentrations
    under
    Subpart
    I;
    5)
    Using
    Equation
    R26
    in accordance
    with
    Section
    742.8
    10,
    demonstrated
    that
    the
    concentration
    of
    any
    contaminant
    of concern
    in
    groundwater
    discharging
    into
    a
    surface
    water
    will
    meet
    the applicable
    water
    quality
    standard
    under
    35 Ill.
    Adm.
    Code
    302;
    6)
    Demonstrated
    that
    the
    source
    of
    the
    release
    is
    not
    located
    within
    the
    minimum
    or designated
    maximum
    setback
    zone
    or
    within
    a
    regulated
    recharge
    area
    of
    an
    existing
    potable
    water
    supply
    well;
    and
    7)
    If the
    selected
    corrective
    action
    includes
    an
    engineered
    barrier
    as set
    forth
    in Subpart
    K to
    minimize
    migration
    of contaminant
    of
    concern
    from
    the
    soil
    to
    the
    groundwater,
    demonstrated
    that
    the engineered
    barrier
    will
    remain
    in
    place
    for
    post-remediation
    land
    use
    through
    an
    institutional
    control
    as
    set
    forth
    in
    Subpart
    J.

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    b)
    A
    groundwater
    remediation
    objective
    that
    exceeds
    the
    water
    solubility
    of
    that
    chemical
    (refer
    to
    Appendix
    C,
    Table
    E
    for solubility
    values)
    is
    not
    allowed.
    c)
    The
    contaminants
    of concern
    for which
    a Tier
    1
    remediation
    objective
    has
    been
    developed
    shall
    be
    included
    in
    any
    mixture
    of similar-acting
    chemicals
    under
    consideration
    in Tier
    2.
    The
    evaluation
    of 35
    Ill.
    Adm.
    Code
    620.6
    15
    regarding
    mixtures
    of
    similar-acting
    chemicals
    shall
    be
    considered
    satisfied
    for
    Class
    I
    groundwater
    at
    the
    point
    of
    human
    exposure
    if either
    of
    the following
    requirements
    are achieved:
    1)
    Calculate
    the
    weighted
    average
    using
    the following
    equations:
    w
    x1
    X,
    X
    3
    X
    eve
    -
    + CUOx
    2
    ÷
    CUOx
    3
    +
    + CUOX
    where:
    Wave
    =
    Weighted
    Average
    x1 through
    xa
    =
    Concentration
    of each
    individual
    contaminant
    at
    the
    location
    of concern.
    Note
    that,
    depending
    on
    the
    target
    organ,
    the
    actual
    number
    of
    contaminants
    will
    range
    from
    2 to
    33.
    CUOxa
    =
    A
    Tier
    1
    or
    Tier 2
    remediation
    objective
    must
    be
    developed
    for
    each
    xa.
    A)
    If the
    value
    of the
    weighted
    average
    calculated
    in accordance
    with
    the
    equations
    above
    is
    less than
    or equal
    to
    1.0,
    then
    the
    remediation
    objectives
    are
    met for
    those
    chemicals.
    B)
    If
    the
    value
    of the
    weighted
    average
    calculated
    in accordance
    with
    the
    equations
    above
    is greater
    than
    1.0,
    then
    additional
    remediation
    must
    be
    carried
    out
    until
    the level
    of
    contaminants
    remaining
    in
    the
    remediated area
    has
    a
    weighted
    average
    calculated
    in
    accordance
    with
    the
    equation
    above
    less than
    or equal
    to
    one;
    or
    2)
    Divide
    each
    individual
    chemical’s
    remediation
    objective
    by
    the
    number
    of
    chemicals
    in
    that
    specific
    target
    organ
    group
    that
    were
    detected
    at
    the
    site.
    Each
    of
    the
    contaminant
    concentrations
    at
    the
    site is
    then
    compared
    to
    the

    ILLINOIS
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    remediation
    objectives
    that
    have
    been
    adjusted
    to
    account
    for this
    potential
    additivity.
    d)
    The
    evaluation
    of
    35 Ill.
    Adm.
    Code
    620.615
    regarding
    mixtures
    of
    similar-acting
    chemicals
    are
    considered
    satisfied
    if the
    cumulative
    risk
    from
    any
    contaminant(s)
    of
    concern
    listed
    in Appendix
    A,
    Table
    I, plus
    any
    other
    contaminant(s)
    of
    concern
    detected
    in groundwater
    and
    listed
    in Appendix
    A,
    Table
    F
    as
    affecting
    the
    same
    target
    organlorgan
    system
    as
    the
    contaminant(s)
    of concern
    detected
    from
    Appendix
    A,
    Table
    I,
    does
    not exceed
    1 in
    10,000.
    Groundwater
    remediation
    objectives
    for
    the
    indoor
    inhalation
    exposure
    route
    shall
    be
    developed
    in accordance
    with
    Section
    742.8
    12.
    (Source:
    Amended
    at
    Ill. Reg.
    effective
    Section
    742.8
    12
    Indoor
    Inhalation
    Equations
    Groundwater remediation
    objectives
    for
    the
    indoor
    inhalation
    exposure
    route
    are
    calculated
    ujpg
    the modified
    J&E
    model
    as described
    in
    Section
    742.7
    17,
    except
    as
    follows:
    In
    Equation
    J&E9a,
    the
    total
    number
    of
    layers
    of
    soil
    that
    contaminants
    migrate
    through
    from
    the
    source
    to
    the
    building
    shall
    include
    a
    capillary
    fringe
    layer.
    The
    thickness
    of
    the capillary
    fringe
    layer
    is
    17
    cm.
    The
    volumetric
    water
    content
    of
    the capillary
    fringe
    shall
    be 90
    %
    of
    the
    total
    porosity
    of
    the
    soil
    that
    comprises
    the
    capillary
    fringe.
    cii
    Equation
    J&E7
    calculates
    an
    acceptable
    groundwater
    remediation
    objective.
    This
    calculation
    is made
    using:
    (1)
    the
    soil
    gas remediation
    objective
    calculated
    in
    accordance
    with
    Equation
    J&E4,
    and
    (2)
    the
    assumption
    that
    this
    gas
    is
    in
    equilibrium
    with
    any contamination
    in the
    groundwater.
    (Source:
    Added
    at
    Ill.
    Reg.
    effective
    SUBPART
    I:
    TIER
    3 EVALUATION
    Section
    742.900
    Tier
    3
    Evaluation
    Overview
    a)
    Tier
    3
    sets
    forth
    a
    flexible
    framework
    to develop
    remediation
    objectives
    outside
    of
    the
    requirements
    of Tiers
    1
    and 2.
    Although
    Tier
    1 and
    Tier
    2 evaluations
    are
    not

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    prerequisites to
    conduct
    Tier
    3
    evaluations,
    data
    from
    Tier
    1 and
    Tier
    2
    can
    assist
    in
    developing remediation
    objectives
    under
    a
    Tier
    3
    evaluation.
    b)
    The
    level
    of
    detail
    required
    to
    adequately
    characterize
    a site
    depends
    on
    the
    particular
    use
    of Tier
    3.
    Tier
    3 can
    require
    additional
    investigative
    efforts
    beyond
    those
    described
    in
    Tier
    2 to
    characterize
    the
    physical
    setting
    of
    the site.
    However,
    in
    situations
    where
    remedial
    efforts
    have
    simply
    reached
    a
    physical
    obstruction
    additional
    investigation
    may
    not
    be
    necessary
    for
    a
    Tier
    3
    submittal.
    c)
    Situations
    that
    can
    be
    considered
    for
    a
    Tier
    3 evaluation
    include,
    but
    are not
    limited
    to:
    1)
    Modification
    of
    parameters
    not
    allowed
    under
    Tier
    2;
    2)
    Use
    of
    models
    different
    from
    those
    used
    in
    Tier
    2;
    3)
    Use
    of
    additional
    site
    data to
    improve
    or
    confirm
    predictions
    of
    exposed
    receptors
    to
    contaminants
    of
    concern;
    4)
    Analysis
    of
    site-specific
    risks
    using
    formal
    risk
    assessment,
    probabilistic
    data
    analysis,
    and
    sophisticated fate
    and
    transport
    models
    (e.g.,
    requesting
    a
    target
    hazard
    quotient
    greater
    than
    1 or
    a
    target
    cancer
    risk
    greater
    than
    1
    in
    1,000,000);
    5)
    Requests
    for
    site-specific
    remediation
    objectives
    because
    an
    assessment
    indicates
    further
    remediation
    is
    not practical;
    6)
    Incomplete
    human
    exposure
    pathway(s)
    not
    excluded
    under
    Subpart
    C;
    7)
    Use
    of
    toxicological-specific
    information
    not
    available
    from
    the
    sources
    listed
    in Tier
    2;
    8)
    Land
    uses
    which
    are
    substantially
    different
    from
    the
    assumed
    residential
    or
    industriallcommercial
    property
    uses
    of
    a
    site
    (e.g.,
    a
    site
    will
    be
    used
    for
    recreation
    in
    the future
    and cannot
    be
    evaluated
    in Tier
    1
    or
    2);
    a4
    9)
    Requests
    for
    site-specific
    remediation
    objectives
    that
    exceed
    Tier
    1
    groundwater
    remediation
    objectives
    so
    long
    as
    the following
    is
    demonstrated:

    ILLiNOIS
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    PROPOSED
    AMENDMENTS
    A)
    To
    the
    extent
    practical,
    the
    exceedance
    ofthe
    groundwater
    quality
    standard
    has
    been minimized
    and beneficial
    use
    appropriate
    to the
    groundwater
    that
    was impacted
    has
    been
    returned;
    and
    B)
    Any
    threat
    to
    human
    health
    or
    the
    environment
    has
    been
    minimized.
    [415
    ILCS
    5/58.5(d)(4)(A)]
    and
    IQ)
    Use
    of
    building
    control
    technologies,
    other
    than
    those
    described
    in
    Subpart
    L, to
    prevent
    completion
    of
    the
    indoor
    inhalation
    exposure
    route.
    d)
    For
    requests
    of
    a
    target
    cancer
    risk
    ranging
    between
    1 in
    1,000,000
    and
    1
    in
    10,000
    at the
    point
    of human
    exposure
    or a
    target
    hazard
    quotient
    greater
    than
    1
    at
    the
    point
    of
    human
    exposure,
    the
    requirements
    of
    Section
    742.915
    shall
    be
    followed.
    Requests
    for
    a
    target
    cancer
    risk
    exceeding
    1 in 10,000
    at the
    point
    of
    human
    exposure
    are not
    allowed.
    e)
    Requests
    for
    approval
    of a
    Tier
    3 evaluation
    must
    be
    submitted
    to
    the
    Agency
    for
    review
    under
    the
    specific
    program
    under
    which
    remediation
    is performed.
    When
    reviewing
    a
    submittal
    under
    Tier
    3,
    the Agency
    shall
    consider
    whether
    the
    interpretations
    and
    conclusions
    reached
    are supported
    by the
    information
    gathered.
    [415
    ILCS
    58.7(e)(1)j.
    The
    Agency
    shall
    approve
    a Tier
    3
    evaluation
    if
    the
    person
    submits
    the
    information
    required
    under
    this
    Part
    and
    establishes
    through
    such
    information
    that
    public
    health
    is protected
    and
    that
    specified
    risks
    to
    human
    health
    and
    the environment
    have
    been
    minimized.
    f)
    If
    contaminants
    of
    concern
    include
    polychiorinated
    biphenyls
    (PCB5),
    requests
    for
    approval
    of
    a Tier
    3 evaluation
    must
    additionally
    address
    the
    applicability
    of
    40
    CFR
    761.
    (Source:
    Amended
    at
    Ill.
    Reg.
    effective
    Section
    742.920
    Impractical
    Remediation
    Any
    request
    for
    site-specific
    remediation
    objectives
    due
    to impracticality
    of
    remediation
    shall
    be
    submitted
    to
    the
    Agency
    for
    review
    and
    approval.
    Any
    request
    for
    site-specific
    remediation
    obi
    ectives
    due
    to
    impracticality
    of
    remediation
    that
    involves
    the
    indoor
    inhalation
    exposure
    route
    shall
    follow
    Section
    742.93
    5
    in lieu
    of
    this
    Section.
    A
    submittal
    under
    this
    Section
    shall
    include
    the
    following
    information:
    a)
    The
    reason(s)
    why
    the
    remediation
    is
    impractical;

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    b)
    The
    extent
    of
    contamination;
    c)
    Geology,
    including
    soil types;
    d)
    The
    potential
    impact
    to groundwater;
    e)
    Results
    and locations
    of sampling
    events;
    f)
    Map
    of the area,
    including
    all
    utilities
    and
    structures;
    and
    g)
    Present
    and
    post-remediation
    uses of
    the area
    of
    contamination,
    including
    human
    receptors
    at risk.
    (Source:
    Amended
    at
    Ill. Reg.
    effective
    Section
    742.925
    Exposure
    Routes
    Technical
    information
    may
    demonstrate
    that
    there
    is no actual
    or
    potential
    impact
    of
    contaminants
    of concern
    to receptors
    from
    a
    particular
    exposure
    route.
    In
    these
    instances,
    a
    demonstration
    excluding
    an
    exposure
    route
    shall be submitted
    to the
    Agency
    for review
    and
    approval.
    A
    demonstration
    that involves
    the
    indoor
    inhalation
    exposure
    route
    shall follow
    Section
    742.93
    5 in
    lieu
    of this Section.
    A
    submittal
    under
    this
    Section
    shall
    include
    the
    following
    information:
    a)
    A
    description
    of
    the route evaluated;
    b)
    A description
    of
    the site and
    physical
    site characteristics;
    c)
    A
    discussion
    of
    the result and
    possibility
    of the route
    becoming
    active
    in the
    future;
    and
    d)
    Technical
    support
    that
    may
    include,
    but
    is not limited
    to,
    the following:
    1)
    a discussion
    of the
    natural or
    man-made
    barriers
    to
    that exposure
    route;
    2)
    calculations
    and
    modeling;
    3)
    physical
    and
    chemical properties
    of
    contaminants
    of concern;
    and
    4)
    contaminant
    migration
    properties.

    ILUNOIS
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    OF
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    AMENDMENTS
    (Source:
    Amended
    at
    Ill. Reg.
    effective
    Section
    742.935
    Indoor
    Inhalation
    Exposure
    Route
    Site
    information
    may
    demonstrate
    that
    there
    is no actual
    or
    potential
    impact
    of
    contaminants
    of concern
    to receptors
    from
    the
    indoor
    inhalation
    exposure
    route.
    In
    such
    instances,
    a
    demonstration
    excluding
    the exposure
    route
    shall
    be
    submitted
    to
    the
    Agency
    for
    review
    and approval.
    A
    submittal
    under
    this
    Section
    shall
    include
    the
    following
    information:
    fl
    A
    description
    of
    the
    site, physical
    site
    characteristics,
    existing
    and
    planned
    buildings,
    and
    existing
    and
    planned
    manmade
    pathways;
    A
    discussion
    of the
    possibility
    of the
    route
    becoming active
    in the
    future;
    and
    Site
    information
    relevant
    to
    the
    demonstration
    including,
    but
    not
    limited
    to.
    the
    following:
    Calculations
    and modeling
    used to
    establish
    remediation
    objectives.
    The
    calculations
    and
    modeling
    shall account
    for
    contaminant
    transport
    through
    the
    mechanisms
    of
    diffusion
    and
    advection.
    Lu
    If the
    contamination
    is more
    than 5
    feet from
    an
    existing
    or
    potential
    building
    or man-made
    pathway,
    a value
    of
    zero
    for
    the
    volumetric
    flow
    rate of
    soil gas
    from
    the subsurface
    into
    the
    enclosed
    space
    shall be
    used.
    A
    Qj
    value
    of zero
    means
    that
    the
    controlling
    mode
    of contaminant
    transport
    is
    diffusion
    and not
    advective
    or pressure-driven
    movement
    of
    contaminants
    through
    the
    soil and
    into
    the
    building.
    Lu)
    If
    the
    contamination
    is
    within
    5 feet
    of
    an
    existing
    or potential
    building
    or
    man-made
    pathway,
    then a
    Qj
    value
    of 83.33
    cm
    3
    /sec
    shall
    be
    used in
    calculating
    the Tier
    3
    remediation
    objectives,
    unless
    additional
    site-specific
    information
    indicates
    a different
    remediation
    objective
    is reasonable
    and
    appropriate.
    )
    Proposals
    to
    use
    soil gas
    data,
    including
    subslab
    samples,
    in
    establishing
    remediation
    objectives.
    Any
    proposal
    to
    use
    soil
    gas data
    shall
    meet
    the
    requirements
    of
    subsection
    (b)
    of this
    Section
    and
    Section
    742.227.

    ILLINOIS
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    AMENDMENTS
    Proposals
    to use
    building
    control
    technologies
    supporting
    the
    demonstration.
    Proposals
    to use
    building
    control
    technologies
    shall
    meet
    subsection
    (c)
    of
    this
    Section
    or Subpart
    L of
    this Part;
    Any
    proposals
    to
    use soil
    gas
    data,
    including
    subslab
    samples,
    to establish
    remediation
    objectives
    for the
    indoor
    inhalation
    exposure
    route
    shall
    be
    submitted
    to
    the
    Agency
    for
    review
    and
    approval.
    Proposals
    to
    use
    soil gas
    data
    in accordance
    with
    Section
    742.227
    shall
    follow
    the
    requirements
    of
    Section
    742.227
    instead
    of
    this
    Section. A
    submittal
    under
    this
    Section
    shall
    include
    the
    following
    information:
    1)
    Scaled
    map
    of the
    area,
    showing
    all
    buildings
    and
    man-made
    pathways
    (current
    and planned);
    The current
    extent
    of
    contamination;
    Geology,
    including
    soil
    types;
    4
    Depth
    to
    groundwater
    (including
    seasonal
    variation)
    and
    flow
    direction;
    )
    Location
    of soil
    gas
    sampling
    points;
    and
    A
    discussion
    of
    soil
    gas
    sampling
    procedures
    that,
    at
    a minimum,
    addresses
    the
    following:
    sampling
    equipment;
    soil
    gas
    collection
    protocol,
    including
    field
    tests and
    weather
    conditions;
    and
    laboratory
    analytical
    methods.
    ç
    Any
    proposals
    to use
    building
    control
    technologies
    as
    a
    means
    to
    prevent
    or
    mitigate
    human
    exposures under
    the
    indoor
    inhalation
    exposure
    route
    shall
    be
    submitted
    to the
    Agency
    for
    review
    and
    approval.
    Proposals
    to
    use
    a
    building
    control
    technology
    in
    accordance
    with
    Subpart
    L shall
    follow
    the
    requirements of
    Subpart
    L
    instead
    of this
    Section.
    A submittal under
    this
    Section
    shall
    include
    the
    following
    information:
    j.
    A
    description
    of
    the site
    and
    physical
    site characteristics;
    )
    The current extent
    of
    contamination;

    ILLiNOIS
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    Geology,
    including
    soil types;
    4)
    Results
    and
    locations
    of
    sampling
    events;
    Scaled
    map
    of the
    area,
    including
    all
    buildings
    and
    man-made
    pathways;
    )
    A
    description
    of
    building
    characteristics
    and
    methods
    of
    construction,
    inc1udig
    description
    of man-made
    pathways;
    7)
    Present
    and
    post-remediation
    uses of
    the
    land
    above
    the area
    of
    contamination,
    including
    human
    receptors
    at risk;
    )
    A
    description
    of
    any building
    control
    technologies
    currently
    in
    place or
    proposed
    for
    installation
    that
    can reduce
    or
    eliminate
    the potential
    for
    completion
    of the
    exposure
    route,
    including
    design
    and
    construction
    specifications;
    )
    Information
    regarding
    the
    effectiveness
    of
    any building
    control
    technologies
    currently
    in place
    or proposed
    for
    installation
    and
    a schedule
    for
    performance
    testing
    to show
    the effectiveness
    of the
    control
    technology.
    For
    buildings
    not
    yet
    constructed,
    an approved
    building
    control
    technology
    shall
    be in
    place
    and
    operational
    prior to
    human
    occupancy;
    jQ)
    Identification
    of
    documents
    reviewed
    and the
    criteria
    used
    in the
    documents
    for
    determining
    whether
    building
    control
    technologies
    are
    effective
    and how
    those
    criteria
    compare
    to
    existing
    or
    potential
    buildings
    or
    man-made
    pathways
    at
    the
    site;
    and
    jj)
    A
    description
    as
    to how
    the effectiveness
    of
    the
    building
    control
    technologies
    will
    be
    operated
    and
    maintained
    for
    the life
    of the
    buildings
    and
    man-made
    pathways,
    or
    until soil
    and
    groundwater
    contaminant
    concentrations
    have reached
    remediation
    objectives
    that are
    approved
    by the
    Agency.
    This
    includes
    provisions
    for
    potential
    extended
    system
    inoperability
    due
    to
    power
    failure
    or
    other
    disruption.
    (Source:
    Added
    at
    Ill.
    Reg.
    effective
    SUBPART
    J:
    ]NSTITUTIONAL
    CONTROLS
    Section
    742.1000
    Institutional
    Controls

    ILLINOIS
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    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF PROPOSED
    AMENDMENTS
    a)
    Institutional controls
    in accordance
    with
    this
    Subpart
    must
    be
    placed
    on the
    property
    when
    remediation
    objectives
    are
    based
    on
    any
    of
    the following
    assumptions:
    1)
    Industrial/Commercial
    property
    use;
    2)
    Target
    cancer
    risk
    greater
    than
    1 in
    1,000,000;
    3)
    Target
    hazard
    quotient
    greater
    than
    1;
    4)
    Engineered
    barriers;
    5)
    The
    point
    of human
    exposure
    is
    located
    at
    a place
    other
    than
    at
    the
    source;
    6)
    Exclusion
    of exposure
    routes;
    Of
    7,)
    Use
    of an
    indoor
    inhalation
    building
    control
    technology;
    or
    )
    7
    Any
    combination
    of the
    above.
    b)
    The
    Agency
    shall
    not
    approve
    any remediation
    objective
    under
    this Part
    that
    is
    based
    on
    the
    use of
    institutional
    controls
    unless
    the
    person
    has
    proposed
    institutional
    controls
    meeting
    the
    requirements
    of
    this
    Subpart
    and
    the
    requirements
    of the
    specific
    program
    under
    which
    the
    institutional
    control
    is
    proposed.
    A
    proposal
    for
    approval
    of
    institutional
    controls
    shall
    provide
    identification
    of the
    selected
    institutional
    controls
    from
    among
    the types
    recognized
    in
    this
    Subpart.
    c)
    The
    following
    instruments
    may
    be
    institutional
    controls
    subject
    to the
    requirements of
    this
    Subpart
    J
    and
    the requirements
    of the
    specific
    program
    under
    which
    the
    institutional
    control
    is proposed:
    1)
    No
    Further
    Remediation
    Letters;
    2)
    Environmental
    Land
    Use
    Controls;
    3)
    Land
    Use
    Control
    Memoranda
    of
    Agreement;
    4)
    Ordinances
    adopted
    and
    administered
    by
    a unit
    of local
    government;

    ILLINOIS
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    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    5)
    Agreements
    between
    a
    property
    owner
    (or,
    in
    the
    case
    of a
    petroleum
    leaking
    underground
    storage
    tank,
    the
    owner
    or
    operator
    of
    the tank)
    and
    a
    highway
    authority
    with
    respect
    to
    any contamination
    remaining
    under
    highways;
    and
    6)
    Agreements
    between
    a highway
    authority,
    which
    is
    also the
    property
    owner
    (or, in
    the case
    of
    a
    petroleum
    leaking
    underground
    storage
    tank,
    the owner
    or operator
    of the
    tank)
    and the
    Agency
    with
    respect
    to any
    contamination
    remaining
    under
    the
    highways.
    d)
    No
    Further
    Remediation
    Letters
    and
    Environmental
    Land
    Use
    Controls
    that
    meet
    the
    requirements
    of
    this
    Subpart
    and
    the
    recording
    requirements
    of
    the
    program
    under
    which
    remediation
    is
    being performed
    are
    transferred
    with
    the property.
    (Source:
    Amended
    at
    Ill.
    Reg.
    effective
    Section
    742.1010
    Environmental
    Land
    Use
    Controls
    a)
    An
    Environmental
    Land
    Use
    Control
    (ELUC)
    is
    an
    institutional
    control
    that
    may
    be
    used under
    this
    Part
    to impose
    land
    use
    limitations
    or
    requirements
    related
    to
    environmental
    contamination.
    ELUCs
    are
    only
    effective
    when
    approved
    by
    the
    Agency
    in accordance
    with
    this Part.
    Activities
    or
    uses
    that may
    be limited
    or
    required
    include,
    but are
    not
    limited
    to, prohibition
    of
    use
    of
    groundwater
    for
    potable
    purposes,
    restriction
    to industrial/commercial
    uses,
    operation
    or
    maintenance
    of
    engineered
    barriers,
    indoor
    inhalation
    building
    control
    technologies,
    or worker
    safety
    plans.
    ELUCs
    may
    be
    used in
    the
    following
    circumstances:
    1)
    When
    No Further
    Remediation
    Letters
    are not
    available,
    including
    but
    not
    limited
    to
    when
    contamination
    has
    migrated
    off-site
    or outside
    the
    remediation
    site; or
    2)
    When
    No
    Further
    Remediation
    Letters
    are
    not
    issued
    under
    the
    program
    for
    which
    a
    person
    is
    undergoing
    remediation.
    b)
    Recording
    requirements:
    1)
    An
    ELUC
    approved
    by
    the
    Agency
    pursuant
    to this
    Section
    must
    be
    recorded
    in
    the
    Office
    of
    the Recorder
    or
    Registrar
    of Titles
    for
    the
    county
    in which
    the
    property
    that
    is
    the
    subject
    of the
    ELUC
    is
    located.
    A
    copy
    of the
    ELUC
    demonstrating
    that
    it has been
    recorded
    must
    be submitted
    to

    ILLINOIS
    REGISTER
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    OF
    PROPOSED
    AMENDMENTS
    the
    Agency
    before
    the
    Agency
    will
    issue
    a no
    further
    remediation
    determination.
    2)
    An ELUC
    approved
    under
    this Section
    will
    not become
    effective
    until
    officially
    recorded
    in
    the chain
    of
    title
    for
    the
    property
    that
    is the
    subject
    of the
    ELUC
    in
    accordance
    with
    subsection
    (b)(1)
    of
    this
    Section.
    3)
    Reference
    to
    the
    recorded
    ELUC
    must
    be made
    in
    the
    instrument
    memorializing
    the
    Agency’s
    no further
    remediation
    determination.
    Recording
    of the
    no
    further
    remediation
    determination
    and
    confirmation
    of
    recording
    must
    be
    in
    accordance
    with
    the
    requirements
    of the
    program
    under
    which
    the
    determination
    was
    issued.
    4)
    The
    requirements
    of
    this
    Section
    do
    not
    apply
    to Federally
    Owned
    Property
    for
    which
    the
    Federal
    Landholding
    Entity
    does
    not have
    the
    authority
    under
    federal
    law
    to
    record
    land
    use
    limitations
    on the
    chain
    of
    title.
    5)
    The
    requirements
    of this
    Section
    apply
    only
    to
    those
    sites
    for
    which
    a
    request
    for
    a no further
    remediation
    determination
    has
    not yet
    been
    made
    to the
    Agency
    by
    January
    6, 2001.
    c)
    Duration:
    1)
    Except
    as
    provided
    in
    this
    subsection
    (c),
    an
    ELUC
    shall
    remain
    in
    effect
    in perpetuity.
    2)
    At no
    time
    shall
    any
    site
    for
    which
    an
    ELUC
    has
    been
    imposed
    as
    a result
    of remediation
    activities
    under
    this
    Part
    be
    used
    in a manner
    inconsistent
    with
    the
    land
    use
    limitation
    unless
    attainment
    of
    objectives
    appropriate
    for
    the
    new
    land
    use
    is achieved
    and
    a new
    no
    further
    remediation
    determination
    has
    been
    obtained and
    recorded
    in
    accordance
    with
    the
    program
    under
    which
    the ELUC
    was
    first imposed
    or the
    Site
    Remediation
    Program
    (35 Ill.
    Adm.
    Code
    740).
    [415
    ILCS
    5
    8.8(c)].
    In
    addition,
    the
    appropriate
    release
    or
    modification
    of the
    ELUC
    must
    be
    prepared
    by
    the
    Agency
    and
    filed
    on
    the
    chain
    of
    title
    for
    the
    property
    that
    is the
    subject
    of
    the
    ELUC.
    A)
    For
    a
    Leaking
    Underground
    Storage
    Tank
    (LUST)
    site
    under
    35
    Ill. Adm.
    Code
    731
    or
    732
    or a Site
    Remediation
    Program
    site
    under
    35
    Ill.
    Adm.
    Code
    740,
    an
    ELUC
    maybe
    released
    or

    ILLINOIS
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    PROPOSED
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    modified
    oniy
    if
    the
    NFR
    Letter
    is
    also
    modified
    under
    the
    Site
    Remediation
    Program
    to
    reflect
    the change;
    B)
    For
    a RCRA
    site
    under
    35 Ill.
    Adm.
    Code
    721
    730,
    an ELUC
    may
    be
    released
    or
    modified
    only
    if
    there
    is also
    an amended
    certification
    of
    closure
    or
    a
    permit
    modification.
    3)
    In addition
    to
    any
    other
    remedies
    that
    may
    be
    available,
    a failure
    to
    comply
    with
    the limitations
    or
    requirements
    of
    an ELUC
    may
    result
    in
    voidance
    of
    an
    Agency no
    further
    remediation
    determination
    in
    accordance
    with
    the
    program
    under
    which
    the
    determination
    was
    made.
    The
    failure
    to
    comply with
    the
    limitations
    or
    requirements
    of
    an
    ELUC
    may
    also
    be
    grounds
    for
    an
    enforcement
    action
    pursuant
    to Title
    VIII
    of
    the
    Act.
    d)
    An
    ELUC
    submitted
    to
    the Agency
    must
    match
    the
    form
    and
    contain
    the
    same
    substance,
    except
    for
    variable elements
    (e.g.,
    name
    of
    property
    owner),
    as the
    model
    in
    Appendix
    F and
    must
    contain
    the
    following
    elements:
    1)
    Name
    of
    property
    owners
    and
    declaration
    of
    property
    ownership;
    2)
    Identification
    of the
    property
    to
    which
    the
    ELUC
    applies
    by
    common
    address,
    legal
    description,
    and
    Real
    Estate
    Tax
    Index/Parcel
    Index
    Number;
    3)
    A reference to
    the
    Bureau
    of Land
    LPC
    numbers
    or
    10-digit
    identification
    numbers
    under
    which
    the
    remediation
    was
    conducted;
    4)
    A
    statement
    of the
    reason
    for
    the
    land
    use
    limitation
    or
    requirement
    relative
    to protecting human
    health
    and
    the
    surrounding
    environment
    from
    soil,
    groundwater,
    andlor
    other
    environmental
    contamination;
    5)
    The
    language
    instituting
    such
    land
    use
    limitations
    or
    requirements;
    6)
    A statement
    that
    the
    limitations
    or
    requirements
    apply
    to the
    current
    owners,
    occupants,
    and
    all
    heirs,
    successors,
    assigns,
    and
    lessees;
    7)
    A
    statement
    that
    the
    limitations
    or
    requirements
    apply
    in
    perpetuity
    or
    until:

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    A)
    The
    Agency determines
    that
    there
    is
    no longer
    a need for
    the
    ELUC;
    B)
    The Agency,
    upon
    written
    request, issues
    to the site that
    received
    the
    no further remediation
    determination
    that
    relies
    on the
    ELUC
    a
    new no further
    remediation
    determination
    approving
    modification
    or removal
    of the
    limitations
    or
    requirements;
    C)
    The
    new
    no further
    remediation
    determination
    is filed
    on
    the
    chain
    of title
    of the site
    subject to the no
    further remediation
    determination;
    and
    D)
    A
    release
    or modification
    of
    the
    land
    use limitation
    is filed
    on
    the
    chain
    of title for the property
    that is
    the subject
    of the
    ELUC;
    8)
    Scaled site
    maps showing:
    A)
    The legal
    boundary
    of the
    property to which
    the ELUC
    applies;
    B)
    The
    horizontal
    and
    vertical
    extent
    of contaminants
    of
    concern
    above applicable
    remediation
    objectives
    for
    soil and
    groundwater
    to which the
    ELUC applies;
    C)
    Any physical
    features to
    which an ELUC
    applies (e.g.,
    engineered
    barriers,
    monitoring
    wells,
    caps, indoor
    inhalation
    building
    control
    technologies);
    and
    D)
    The nature, location
    of the
    source, and direction
    of
    movement
    of
    the
    contaminants
    of concern;
    9)
    A statement
    that
    any information
    regarding
    the remediation
    performed
    on
    the property for which
    the ELUC
    is necessary may
    be
    obtained
    from
    the
    Agency
    through
    a request
    under
    the
    Freedom
    of Information
    Act
    [5
    ILCS
    140] and rules
    promulgated
    thereunder;
    and
    10)
    The dated, notarized
    signatures
    of the
    property
    owners
    or authorized
    agent.
    (Source:
    Amended at
    Ill. Reg.
    effective
    Section 742.1015
    Ordinances

    ILLINOIS
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    CONTROL
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    OF
    PROPOSED
    AMENDMENTS
    a)
    An
    ordinance
    adopted
    by
    a unit
    of local
    government
    that
    effectively
    prohibits
    the
    installation
    of potable
    water
    supply
    wells
    (and
    the
    use
    of such
    wells)
    may
    be
    used
    as an
    institutional
    control
    to meet
    the requirements
    of Section
    742.320(d)
    or
    742.805(a)(3)
    if the
    requirements
    of
    this
    Section
    are
    met.
    A
    model
    ordinance
    is
    found
    in
    Appendix
    G.
    Ordinances
    prohibiting
    the
    installation
    of
    potable
    water
    supply
    wells
    (and
    the
    use
    of such
    wells)
    that
    do not
    expressly
    prohibit
    the
    installation
    of
    potable
    water
    supply
    wells
    (and
    the
    use of
    such
    wells)
    by
    units
    of
    local
    government
    may
    be
    acceptable
    as
    institutional
    controls
    if the
    requirements
    of this
    Section
    are met
    and
    a Memorandum
    of
    Understanding
    (MOU)
    is
    entered
    into
    under
    subsection
    (i)
    of this
    Section.
    For
    purposes
    of this
    Section,
    a
    unit
    of
    local
    government
    is
    considered
    to
    be expressly
    prohibited
    from
    installing
    and
    using
    potable
    water
    supply
    wells
    only
    if
    the unit
    of
    local
    government
    is
    included
    in the
    prohibition
    provision
    by
    name.
    The
    prohibition
    required
    by
    this
    Section
    shall
    satisfy
    the
    following
    requirements
    at
    a
    minimum:
    1)
    The
    prohibition
    shall
    not
    allow
    exceptions
    for
    potable
    water
    well
    installation
    and
    use other
    than
    for the
    adopting
    unit
    of
    local
    government;
    2)
    The
    prohibition
    shall
    apply
    at
    all
    depths
    and
    shall
    not
    be
    limited
    to
    particular
    aquifers
    or other
    geologic
    formations;
    3)
    If
    the prohibition
    does
    not
    apply
    everywhere
    within
    the
    boundaries
    of the
    unit
    of
    local
    government,
    the
    limited
    area
    to which
    the
    prohibition
    applies
    shall
    be
    easily
    identifiable
    and clearly
    defined
    by the
    ordinance
    (e.g.,
    narrative
    descriptions
    accompanied
    by maps
    with
    legends
    or
    labels
    showing
    prohibition
    boundaries,
    narrative
    descriptions
    using
    fixed,
    common
    reference
    points
    such
    as
    street
    names).
    Boundaries
    of
    prohibitions
    limited
    by
    area
    shall
    be fixed
    by
    the
    terms
    of
    the
    ordinance
    and
    shall
    not
    be
    subject
    to
    change
    without
    amending
    the ordinance
    in
    which
    the
    prohibition
    has
    been
    adopted
    (e.g.,
    no
    boundaries
    defined
    with
    reference
    to zoning
    districts
    or
    the availability
    of
    the
    public
    water
    supply);
    and
    4)
    The
    prohibition
    shall
    not
    in
    any way
    restrict
    or limit
    the
    Agency’s
    approval
    of the
    use
    of the
    ordinance
    as
    an
    institutional
    control
    pursuant
    to
    this
    Part
    (e.g.,
    no
    restrictions
    based
    on
    remediation
    program
    participation,
    no
    restrictions
    on
    persons
    performing
    remediation
    within
    the
    prohibition
    area
    who
    may
    use
    the
    ordinance).

    ILLINOIS
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    b)
    A
    request
    for
    approval
    of a
    local
    ordinance
    as an
    institutional
    control
    shall
    provide
    the following:
    1)
    A copy
    of
    the
    ordinance
    restricting
    groundwater
    use certified
    by an
    official
    of the
    unit of
    local government
    in
    which
    the
    site
    is located
    that
    it is
    a
    true
    and
    accurate
    copy of
    the ordinance,
    unless
    the Agency
    and
    the
    unit
    of local
    government
    have entered
    an
    agreement
    under
    subsection
    (i)
    of
    this
    Section,
    in
    which
    case
    the
    request
    may
    alternatively
    reference
    the
    MOU.
    The
    ordinance
    must
    demonstrate
    that
    potable
    use
    of groundwater
    from
    potable
    water
    supply
    wells
    is
    prohibited;
    2)
    A scaled
    map(s)
    delineating
    the
    area
    and extent
    of
    groundwater
    contamination
    modeled
    above
    the
    applicable
    remediation
    objectives
    includingany
    measured
    data
    showing
    concentrations
    of
    contaminants
    of
    concern
    in
    which
    the
    applicable
    remediation
    objectives
    are
    exceeded;
    3)
    A scaled
    map
    delineating
    the
    boundaries
    of
    all properties
    under
    which
    groundwater
    is
    located
    which
    exceeds
    the
    applicable
    groundwater
    remediation
    objectives;
    4)
    Information
    identifying
    the
    current
    owner(s)
    of
    each property
    identified
    in
    subsection
    (b)(3)
    of this
    Section;
    and
    5)
    A
    copy of
    the proposed
    written
    notification
    to
    the unit
    of local
    government
    that
    adopted
    the ordinance
    and to
    the
    current
    owners
    identified
    in
    subsection
    (b)(4)
    of this
    Section
    that includes
    the
    following
    information:
    A)
    The
    name
    and address
    of the
    unit
    of
    local
    government
    that
    adopted
    the
    ordinance;
    B)
    The
    ordinance’s
    citation;
    C)
    A
    description
    of
    the
    property
    being
    sent
    notice
    by adequate
    legal
    description,
    reference
    to
    a
    plat
    showing
    the boundaries
    of
    the
    property,
    or by
    accurate
    street
    address;
    D)
    Identification
    of the
    party
    requesting
    to
    use
    the
    groundwater
    ordinance
    as
    an institutional
    control,
    and a
    statement
    that
    the
    party
    has
    requested
    approval
    from
    the Agency
    to use the
    ordinance
    as
    an
    institutional
    control;

    ILLINOIS
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    E)
    A statement
    that
    use
    of the
    ordinance
    as an
    institutional
    control
    allows
    contamination
    above
    groundwater
    ingestion
    remediation
    objectives
    to
    remain
    in
    groundwater
    beneath
    the
    affected
    properties,
    and
    that
    the
    ordinance
    strictly
    prohibits
    human
    and
    domestic
    consumption
    of
    the
    groundwater;
    F)
    A
    statement
    as
    to the
    nature
    of
    the
    release
    and
    response
    action
    with
    the
    site
    name,
    site
    address,
    and
    Agency
    site
    number
    or
    Illinois
    inventory
    identification
    number;
    and
    G)
    A statement
    that
    more
    information
    about
    the
    remediation
    site
    may
    be
    obtained
    by
    contacting
    the
    party
    requesting
    the
    use
    of
    the
    groundwater
    ordinance
    as an
    institutional
    control
    or
    by
    submitting
    a
    FOIA
    request
    to
    the
    Agency.
    c)
    Written
    notification
    proposed
    pursuant
    to
    subsection
    (b)(5)
    of this
    Section
    must
    be
    sent
    to the
    unit
    of
    local
    government
    that
    adopted
    the
    ordinance
    as
    well
    as
    all
    current
    property
    owners identified
    in
    subsection
    (b)(4).
    Written
    proof
    that
    the
    notification
    was
    sent
    to
    the
    unit
    of
    local
    government
    and
    the
    property
    owners
    shall
    be
    submitted
    to the
    Agency
    within
    45
    days
    from
    the
    date
    the
    Agency’s
    no
    further
    remediation
    determination
    is
    recorded.
    Such
    proof
    may
    consist
    of the
    return
    card
    from
    certified
    mail,
    return
    receipt
    requested,
    a
    notarized
    certificate
    of service,
    or
    a
    notarized
    affidavit.
    d)
    Unless
    the Agency
    and
    the
    unit
    of
    local
    government
    have
    entered
    into
    a
    MOU
    under
    subsection
    (i)
    of this
    Section,
    the
    current
    owner
    or
    successors
    in
    interest
    of
    a
    site
    who
    have
    received
    approval
    of
    use of
    an
    ordinance
    as
    an
    institutional
    control
    under
    this
    Section shall:
    1)
    Monitor
    activities
    of
    the
    unit
    of local
    government
    relative
    to
    variance
    requests
    or
    changes
    in
    the
    ordinance
    relative
    to
    the
    use
    ofpotable
    groundwater
    at properties
    identified
    in
    subsection
    (b)(3)
    of
    this
    Section;
    and
    2)
    Notify
    the
    Agency
    of
    any
    approved variance
    requests
    or
    ordinance
    changes
    within
    30
    days
    after
    the
    date
    such
    action
    has
    been
    approved.
    e)
    The
    information
    required
    in subsections
    (b)(
    1)
    through
    (b)(5)
    of this
    Section
    and
    the
    Agency
    letter
    approving
    the
    groundwater
    remediation
    objective
    shall
    be
    submitted to
    the
    unit
    of
    local
    government.
    Proof
    that
    the
    information
    has
    been
    filed
    with
    the
    unit
    of
    local
    government
    shall
    be
    provided
    to
    the
    Agency.

    ILLiNOIS
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    POLLUTION
    CONTROL
    BOARD
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    f)
    Any ordinance
    or MOU
    used
    as
    an
    institutional
    control
    pursuant
    to this
    Section
    shall
    be recorded
    in
    the
    Office
    of the
    Recorder
    or
    Registrar
    of Titles
    of the
    county
    in
    which
    the site
    is
    located
    together
    with the
    instrument
    memorializing
    the
    Agency’s
    no
    further
    remediation
    determination
    pursuant
    to the
    specific
    program
    within
    45
    days
    after receipt
    of the
    Agency’s
    no further
    remediation
    determination.
    g)
    An
    institutional
    control
    approved
    under
    this
    Section
    shall
    not
    become
    effective
    until
    officially
    recorded
    in accordance
    with subsection
    (f)
    of this
    Section.
    The
    person
    receiving
    the
    approval
    shall
    obtain
    and
    submit
    to the
    Agency
    within
    30
    days
    after
    recording
    a copy
    of
    the institutional
    control
    demonstrating
    that
    it
    has
    been
    recorded.
    h)
    The
    following
    shall
    be
    grounds
    for
    voidance
    of the
    ordinance
    as an
    institutional
    control
    and
    the
    instrument
    memorializing
    the
    Agency’s
    no further
    remediation
    determination:
    1)
    Modification
    of
    the ordinance
    by the
    unit
    of
    local
    government
    to
    allow
    potable
    use
    of
    groundwater;
    2)
    Approval
    of
    a
    site-specific
    request,
    such
    as a
    variance,
    to allow
    potable
    use of
    groundwater
    at a site
    identified
    in
    subsection
    (b)(3) of
    this
    Section;
    3)
    Violation
    of
    the terms
    of
    an
    institutional
    control
    recorded
    under
    Section
    742.1005
    or
    Section
    742.1010;
    or
    4)
    Failure
    to
    provide
    notification
    and
    proof
    of such
    notification
    pursuant
    to
    subsection
    (c)
    of this
    Section.
    i)
    The Agency
    and
    a
    unit
    of local
    government
    may
    enter
    into
    a
    MOU
    under this
    Section
    if the
    unit
    of local
    government
    has
    adopted
    an
    ordinance
    satisfying
    subsection
    (a) of
    this
    Section
    and
    if
    the requirements
    of
    this
    subsection
    are
    met.
    The
    MOU
    submitted
    to the
    Agency
    must
    match
    the
    form
    and
    contain
    the
    same
    substance
    as the
    model
    in Appendix
    H
    and
    shall
    include
    the
    following:
    1)
    Identification
    of
    the authority
    of
    the unit
    of
    local
    government
    to
    enter
    the
    MOU;
    2)
    Identification
    of
    the legal
    boundaries,
    or
    equivalent,
    under
    which
    the
    ordinance
    is applicable;

    ILLINOIS
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    3)
    A
    certified
    copy
    of
    the ordinance;
    4)
    A
    commitment
    by
    the
    unit of
    local
    government
    to notify
    the
    Agency
    of
    any
    variance
    requests
    or proposed
    ordinance
    changes
    at
    least
    30
    days
    prior
    to
    the
    date the
    local
    government
    is
    scheduled
    to
    take
    action
    on
    the
    request
    or proposed
    change;
    5)
    A
    commitment
    by
    the
    unit
    of local
    government
    to
    maintain
    a registry
    of all
    sites
    within
    the unit
    of
    local
    government
    that
    have
    received
    no
    further
    remediation
    determinations
    pursuant
    to
    specific
    programs;
    and
    6)
    If the
    ordinance
    does
    not expressly
    prohibit
    the installation
    of
    potable
    water
    supply
    wells
    (and
    the
    use
    of
    such
    wells)
    by
    units
    of
    local
    government,
    a conimitment
    by
    the
    unit
    of
    local
    govermnent:
    A)
    To
    review
    the
    registry
    of
    sites
    established
    under
    subsection
    (i)(5)
    of
    this Section
    prior
    to
    siting
    potable
    water
    supply
    wells
    within
    the
    area
    covered
    by the
    ordinance;
    B)
    To
    determine
    whether
    the
    potential
    source
    of potable
    water
    may
    be
    or has
    been
    affected
    by
    contamination
    left
    in place
    at
    those
    sites;
    and
    C)
    To
    take
    whatever
    steps
    are
    necessary
    to
    ensure
    that
    the
    potential
    source
    of
    potable
    water
    is
    protected
    from
    the
    contamination
    or
    treated
    before
    it is
    used
    as a potable
    water
    supply.
    fl
    A
    groundwater
    ordinance may
    not
    be used
    to
    exclude
    the
    indoor
    inhalation
    exposure route.
    (Source:
    Amended
    at
    Ill. Reg.
    effective
    SUBPART
    K:
    ENGINEERED
    BARRIERS
    Section
    742.1105
    Engineered
    Barrier
    Requirements
    a)
    Natural
    attenuation,
    access
    controls,
    and
    point
    of use
    treatment
    shall
    not
    be
    considered engineered
    barriers.
    Engineered
    barriers
    may
    not
    be used
    to
    prevent
    direct
    human
    exposure
    to groundwater
    without
    the
    use
    of
    institutional
    controls.

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    b)
    For purposes
    of
    determining
    remediation
    objectives
    under
    Tier
    1, engineered
    barriers
    are
    not recognized.
    c)
    The
    following
    engineered
    barriers
    are
    recognized
    for
    purposes
    of calculating
    remediation
    objectives
    that exceed
    residential
    remediation
    objectives:
    1)
    For
    the soil
    component
    of the
    groundwater
    ingestion
    exposure
    route,
    the
    following
    engineered
    barriers
    are
    recognized
    if they
    prevent
    completion
    of
    the exposure
    pathway:
    A)
    Caps
    or
    walls
    constructed
    of compacted
    clay,
    asphalt,
    concrete
    or
    other
    material
    approved
    by the
    Agency;
    and
    B)
    Permanent
    structures
    such
    as
    buildings
    and
    highways.
    2)
    For
    the soil
    ingestion
    exposure
    route,
    the
    following
    engineered
    barriers
    are
    recognized
    if they
    prevent
    completion
    of the
    exposure
    pathway:
    A)
    Caps
    or
    walls
    constructed
    of
    compacted
    clay,
    asphalt,
    concrete,
    or
    other material
    approved
    by
    the Agency;
    B)
    Permanent
    structures
    such
    as buildings
    and
    highways;
    and
    C)
    Soil, sand,
    gravel,
    or other
    geologic
    materials
    that:
    i)
    Cover
    the
    contaminated
    media;
    ii)
    Meet
    the soil
    remediation
    objectives
    under
    Subpart
    E
    for
    residential
    property
    for contaminants
    of
    concern;
    and
    iii)
    Are
    a
    minimum
    of three
    feet in
    depth.
    3)
    For the
    outdoor
    inhalation
    exposure
    route,
    the
    following
    engineered
    barriers
    are
    recognized
    if
    they
    prevent
    completion
    of
    the exposure
    pathway:
    A)
    Caps
    or
    walls
    constructed
    of
    compacted
    clay,
    asphalt,
    concrete,
    or
    other
    material
    approved
    by
    the Agency;
    B)
    Permanent
    structures
    such
    as
    buildings
    and
    highways;
    and

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    C)
    Soil,
    sand,
    gravel,
    or
    other
    geologic
    materials
    that:
    i)
    Cover
    the
    contaminated
    media;
    ii)
    Meet
    the
    soil
    remediation
    objectives
    under
    Subpart
    E
    for
    residential
    property
    for
    contaminants
    of
    concern;
    and
    iii)
    Are
    a minimum
    often
    feet
    in
    depth
    and
    not
    within
    ten
    feet
    of
    any
    manmade
    pathway.
    4)
    For
    the
    ingestion
    of groundwater
    exposure
    route,
    the
    following
    engineered
    barriers
    are
    recognized
    if they
    prevent
    completion
    of
    the
    exposure
    pathway:
    A)
    Slurry
    walls;
    and
    B)
    Hydraulic
    control
    of groundwater.
    d)
    Unless
    otherwise
    prohibited
    under
    Section
    742.1100,
    any
    other
    type
    of
    engineered
    barrier
    may
    be
    proposed
    if it will
    be
    as
    effective
    as
    the
    options
    listed
    in
    subsection
    (c)
    of this
    Section.
    (Source:
    Amended
    at
    Ill.
    Reg.
    effective
    SUBPART
    L:
    BUILDING
    CONTROL
    TECHNOLOGIES
    Section
    742.1200
    Building
    Control
    Technologies
    Any
    person
    who
    develops
    remediation
    objectives
    under
    this
    Part
    based
    on
    building
    control
    technologies
    shall
    meet
    the
    requirements
    of
    this
    Subpart
    and
    the
    requirements
    of
    Subpart
    J
    relative
    to institutional
    controls.
    The
    Agency
    shall
    not
    approve
    any
    remediation
    objective
    under
    this Part
    that
    is
    based
    on the
    use
    of
    building
    control
    technologies
    unless
    the person
    has
    proposed
    building
    control
    technologies
    meeting
    the
    requirements
    of this
    Subpart
    and
    Subpart
    J
    relative
    to
    institutional
    controls.
    The
    use
    of building
    control
    technologies
    can
    be recognized
    in determining
    remediation
    objectives
    only
    if
    the
    building
    control
    technologies
    are
    intended
    for
    use
    as part
    of
    the
    final
    corrective
    action.

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    For
    buildings
    not
    yet
    constructed,
    an
    approved
    building
    control
    technology
    shall
    be in
    place
    and
    operational
    prior
    to human
    occupancy.
    Any no
    further
    remediation
    determination
    based
    upon
    the
    use
    of
    building
    control
    technologies
    shall
    require
    effective maintenance
    of
    the
    building control
    technology.
    The maintenance
    requirements
    shall be
    included
    in
    an
    institutional
    control under
    Subpart
    J.
    This
    institutional
    control
    shall
    address provisions
    for
    inoperability
    by requiring
    the
    following
    if the
    building
    control
    technology
    is
    rendered
    inoperable:
    1)
    The
    site owner/operator
    shall
    notify
    building
    occupants
    and
    workers
    in
    advance
    of
    intrusive activities.
    Such
    notification
    shall
    enumerate
    the
    contaminant
    of concern
    known
    to be present;
    and
    The
    site
    owner/operator
    shall
    require
    building
    occupants
    and
    workers
    to
    implement
    protective
    measures consistent
    with good
    industrial
    hygiene
    practice.
    Failure to
    maintain
    a building
    control
    technology
    in accordance
    with
    that
    no
    further
    remediation
    determination
    shall
    be
    grounds
    for
    voidance
    of the
    determination
    and
    the
    instrument
    memorializing
    the
    Agency’s
    no
    further
    remediation
    determination.
    (Source:
    Added
    at
    Ill. Reg.
    effective
    Section
    742.1205
    Building
    Control
    Technology
    Proposals
    A
    proposal
    to use
    a
    building
    control technology
    under
    this
    Subpart shall
    include
    the
    followiig
    information:
    A
    description
    of
    the
    site
    and physical
    site characteristics;
    The
    current
    extent
    and
    modeled migration
    of contamination;
    Geology,
    including
    soil types;
    4
    Results
    and
    locations
    of sampling
    events;
    Scaled
    map
    of the
    area, including
    all
    buildings
    and man-made
    pathways;

    ILLINOIS
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    A
    description
    of
    building characteristics
    and
    methods
    of
    construction,
    including
    a
    description of
    man-made
    pathways;
    and
    g
    Present
    and
    post-remediation
    uses
    of the
    land
    above
    the
    area
    of
    contamination,
    including
    human
    receptors
    at
    risk.
    (Source:
    Added
    at
    Ill.
    Reg.
    effective
    Section
    742.1210
    Building
    Control
    Technology
    Requirements
    )
    Natural
    attenuation,
    access
    controls,
    and
    point
    of use
    treatment
    shall
    not
    be
    considered building
    control
    technologies.
    )
    For
    purposes
    of
    determining
    remediation
    objectives
    under
    Tier
    1,
    building
    control
    technologies
    are not
    recognized.
    The
    following
    building
    control
    technologies
    are recognized
    for
    purposes
    of
    determining
    remediation
    objectives
    that
    exceed
    residential
    remediation
    objectives:
    1)
    Sub-slab depressurization
    (SSD)
    systems
    meeting
    the
    following
    requirements:
    A suction pit is
    installed
    that is
    at least
    4
    cubic
    feet
    and
    extends
    at
    least
    16
    inches
    below
    the
    slab:
    A
    PVC
    pipe
    of
    at
    least
    4
    inches
    in
    diameter
    extends
    from
    the
    suction
    pit
    to
    the intake
    side of
    an
    in-line
    fan
    with
    a
    flow
    rate
    of
    at
    least
    5.7
    cubic
    meters/mm
    at
    249 pascals;
    )
    All
    visible
    cracks
    and
    joints
    in the
    slab
    (including
    the
    place
    where
    the
    pipe
    exits
    the
    slab)
    are
    sealed;
    The
    pipe
    exhausts
    outside
    the
    building
    at least
    10
    feet
    above
    ground
    and
    at
    least
    10
    feet
    from
    any door
    or
    window;
    and
    An additional
    suction
    pit meeting
    the
    requirements
    of
    (A)
    shall
    be
    installed
    in
    any
    area
    separated
    by a
    sub-slab
    grade
    beam.
    Sub-membrane depressurization
    (SMD)
    systems
    meeting
    the
    following
    requirements:

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    A
    non-woven
    geotextile
    is installed
    on
    the
    exposed
    earthen
    material;
    A
    cross-laminated
    polyethylene
    membrane
    liner
    at
    least
    0.15
    mm
    (or
    6
    miD
    thick
    is
    placed
    over
    the
    geotextile
    and
    sealed
    to
    foundation
    walls
    using
    acrylic
    latex
    adhesive;
    )
    A
    4-inch
    diameter
    PVC
    pipe
    extends
    from
    a hole
    cut
    in
    the
    liner
    to
    the
    intake
    side
    of
    an
    in-line
    fan with
    a
    flow
    rate
    of
    at least
    5.7
    cubic
    meters/mm
    at 249
    pascals;
    The
    pipe
    is sealed
    to the
    liner;
    The
    pipe
    exhausts
    outside
    the
    building
    at least
    10
    feet
    above
    ground
    and
    at
    least
    10 feet
    from
    any
    door
    or
    window;
    and
    A
    smoke
    test
    of
    the
    membrane
    system,
    in
    accordance
    with
    the
    manufacturer’s
    requirements,
    is
    preformed
    to
    ensure
    no
    leaks
    exist.
    Where
    leaks
    are
    identified,
    appropriate
    repairs
    are undertaken
    and
    smoke
    testing
    repeated
    until
    no
    leaks
    are detected.
    Membrane
    barrier
    systems
    meeting
    the
    following
    requirements:
    The membrane
    is impermeable
    to
    volatile
    chemicals
    and
    is
    not
    less
    than
    1.5 mm
    (or
    60
    mu)
    thick;
    The
    membrane
    is sealed
    to
    foundation
    walls
    and
    any
    penetrating
    pipes:
    The membrane
    is installed
    in accordance
    with
    the manufacturer’s
    requirements
    and
    by
    an
    applicator
    trained
    and
    approved
    by the
    manufacturer.
    j
    A smoke
    test
    of the
    membrane
    system,
    in
    accordance
    with
    the
    manufacturer’s
    requirements,
    is performed
    to
    ensure
    no
    leaks
    exist.
    Where
    leaks
    are
    identified,
    appropriate
    repairs
    are
    undertaken
    and
    smoke
    testing
    repeated
    until
    no leaks
    are
    detected;
    The
    membrane
    is
    puncture
    resistant
    to slab
    installation
    construction activities;
    and

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    Construction
    activities
    following
    membrane
    installation
    do
    not
    damage,
    puncture
    or tear
    the
    membrane
    or
    otherwise
    compromise
    its
    ability
    to prevent
    the migration
    of
    volatile
    chemicals.
    4)
    Geologic
    materials
    meeting
    the following
    requirements:
    )
    The
    geologic
    materials
    cover
    the
    contaminated
    soil
    and
    groundwater;
    )
    The
    geologic
    materials
    meet
    the
    soil
    remediation
    objectives
    for
    the
    indoor
    inhalation
    exposure
    route
    under
    Subpart
    E
    for
    residential
    property
    for
    the
    contaminants
    of
    concern;
    and
    )
    The
    geologic
    materials
    have
    sufficient
    depth
    such
    that,
    using
    Tier
    2
    or Tier
    3
    evaluation
    procedures
    as
    approved
    by
    the
    Agency,
    completion
    of
    the exposure
    route
    is
    prevented
    for
    any
    building
    or
    man-made
    pathway.
    (Source: Added
    at
    Ill.
    Reg.
    effective

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    Section
    742.APPENDIX
    A:
    General
    Section
    742.TABLE
    A:
    Soil Saturation
    Limits
    (Csat)
    for
    Chemicals
    Whose
    Melting
    Point
    is
    Less
    than
    30° C
    1,2 Dichioroeti
    1,2
    Dichloropropanc
    4T

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    PROPOSED
    AMENDMENTS
    For
    the
    Soil
    Component
    of
    For the
    Outdoor
    the
    Groundwater
    Inhalation
    Ingestion
    Exposure
    Routea
    Exposure
    Route”
    CAS
    No.
    Chemical
    Name
    C(rng/kg)
    C
    (mg/çg
    67-64-1
    Acetone
    1.OOE+05
    2.OOE+05
    71-43-2
    Benzene
    8
    .OOE+02
    5. 80E+02
    111-44-4
    Bis(2-chloroethyl)ether
    3.OOE+03
    3.90E+03
    1 17-81-7
    Bis(2-ethylhexyl)phthalate
    2.OOE+02
    6.80E+01
    75-27-4
    Bromodichioromethane
    (Dichiorobromomethane)
    2.80E+03
    2.OOE+03
    75-25-2
    Bromoform
    2.00E+03
    1.20E+03
    71-36-3
    Butanol
    1.OOE+04
    1.60E+04
    78-93-3
    2-Butanone
    (MEK)
    2.50E+04
    4.50E+04
    85-68-7
    Butyl
    benzyl
    phthalate
    1.OOE+03
    3.40E+02
    75-15-0
    Carbon
    disulfide
    8.50E+02
    5.20E+02
    56-23-5
    Carbon
    tetrachioride
    1.20E+03
    5.60E+02
    108-90-7
    Chlorobenzene
    (Monochlorobenzene)
    6.20E+02
    2.90E+02
    124-48-1
    Chlorodibromomethane
    (Dibromochioromethane)
    1 .40E+03
    8.90E+02
    67-66-3
    Chloroform
    3.40E+03
    2.50E+03
    95-57-8
    2-Chlorophenol
    b
    (ionizable
    organic)
    1.OOE+05
    7.OOE+04
    75-99-0
    Dalapon
    I .20E+05
    1
    .90E+05
    96-12-8
    1
    ,2-Dibromo-3
    -chloropropane
    6.90E+02
    4.30E+02
    106-93-4
    1,2-Dibromoethane
    (Ethylene
    dibromide)
    1.60E+03
    1.20E+03
    84-74-2
    Di-n-butyl
    phthalate
    2.60E+03
    8.80E+02
    95-50-1
    1,2-Dichlorobenzene
    (o-Dichlorobenzene)
    5.60E+02
    2.1OE+02
    75-71-8
    Dichiorofluoromethane
    8.70E+04
    4.30E+02

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    Component
    of
    For the
    Outdoor
    the
    Groundwater
    Inhalation
    Ingestion
    Exposure
    Rout&’
    ciosure
    Route’
    CAS
    No.
    Chemical
    Name
    C
    (mg/kg)
    C
    (mg/kg)
    75-34-3
    1.1
    -Dichioroethane
    1
    .70E+03
    1
    .40E+03
    107-06-2
    l,2-Dichloroethane
    (Ethylene
    dichloride)
    l.90E+03
    2.1OE+03
    75-35-4
    1,1
    -Dichioroethylene
    1 .40E+03
    9.1
    OE+02
    156-59-2
    cis- 1 ,2-Dichloroethylene
    1
    .30E+03
    i
    .oo+o
    1 5
    6-60-5
    trans-i
    ,2-Dichloroethylene
    3 .OOE+03
    2.1
    OE+03
    78-87-5
    1
    ,2-Dichloropropane
    1 .20E+03
    8.70E+02
    542-75-6
    1
    ,3-Dichloropropene
    (1,3
    -Dichioropropylene,
    cis
    + trans)
    1
    .OOE+03
    8.50E+02
    84-66-2
    Diethyl
    phthalate
    2.20E+03
    9.20E+02
    105-67-9
    2,4-Dimethylphenol
    1.OOE+04
    4.70E+03
    1
    17-84-0
    Di-n-octyl
    phthalate
    i.60E+0i
    5.20E+00
    123-91-i
    p-Dioxane
    1.OOE+05
    2.OOE+05
    100-41-4
    Ethylbenzene
    3
    .50E+02
    1 .50E+02
    77-47-4
    Hexachiorocyclopentadiene
    1
    .30E+02
    4.40E+0
    1
    78-59-1
    Isophorone
    3.OOE+03
    3.OOE+03
    98-82-8
    Isopropylbenzene
    (Cumene)
    9.40E+02
    4.OOE+02
    7439-97-6
    Mercury
    (elemental)
    3.1OE+00
    3.1OE+00
    72-43-5
    Methoxychlor
    i.40E+01
    4.50E+00
    74-83-9
    Methyl
    bromide
    (Bromomethane)
    3.1 OE+03
    3
    .60E+03
    1
    634-04
    .4
    Methyl
    tertiary-butyl
    ether
    8 .40E+03
    1.1
    OE+04
    75-09-2
    Methylene
    chloride
    (Dichloromethane)
    2.5
    OE+03
    3 .OOE+03
    9
    8-95-3
    Nitrobenzene
    7.1
    OE+02
    5
    .90E+02

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    CASNo.
    Chemical Name
    621-64-7
    n-Nitrosodi-n-propylamine
    1 .90E+03
    100-42-5
    Styrene
    6.30E+02
    127-1
    8-4
    Tetrachloroethylene
    (Perchioroethylene)
    8 .OOE+02
    108-88-3
    Toluene
    5.80E+02
    120-82-1
    1
    ,2,4-Trichlorobenzene
    3
    .40E+02
    71
    -5 5-6
    1,1,1
    -Trichloroethane
    1.3
    OE+03
    79-00-5
    1,1,2-Trichioroethane
    1.80E+03
    79-01-6
    Trichioroethylene
    1 .20E+03
    75-69-4
    Trichiorofluoromethane
    1 .80E+03
    108-05-4
    Vinyl
    acetate
    2.26E+03
    75-01-4
    Vinyl
    chloride
    2.60E+03
    108-38-3
    m-Xylene
    4.1OE+02
    95-47-6
    o-Xylene
    3.70E+02
    106-42-3
    p-Xylene
    3.30E+02
    1330-20-7
    Xylenes
    (total)
    2.80E+02
    Soil
    Saturation
    Limits
    calculated
    using
    an
    foc
    of
    0.006
    g/g
    and
    a system
    temperature
    of 25°C.
    Soil
    Saturation
    Limits
    calculated
    using
    an foc
    of 0.002
    g/g
    and
    a
    system
    temperature
    of 25°C.
    c,
    for pH
    of 6.8.
    If
    soil
    pH
    is other
    than
    6.8. a
    site-specific
    C
    should
    be
    calculated
    using
    equations
    S19
    and
    S29 and
    the
    For
    the Outdoor
    Inhalation
    Exposure
    Routea
    (mg/kg)
    For
    the
    Soil
    Component
    of
    the
    Groundwater
    Ingestion
    sure
    Routeb
    csajrnwkg)
    pH-specific
    Koc
    values
    in
    Appendix
    C Table
    I.
    (Source:
    Amended
    at
    Ill. Reg.
    effective
    )

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    Section
    742.APPENDJX
    A General
    Section
    742.TABLE
    E
    Similar-Acting
    Noncarcinogenic
    Chemicals
    Adrcnal
    Cland
    Nitrobenzene
    1,2,4
    Trichlorobenzene
    (Ingestion
    only)
    Kidney
    Acetone (Ingestion
    only)
    Cadmium
    (Ingestion
    only)
    Chlorobenzene
    Dalapon
    1,1
    Dichloroethane
    Di
    n octyl
    phthalate
    (Ingestion
    only)
    Endosulfan
    Ethylbenzene
    Fluoranthene
    Methyl
    tertiary
    butyl
    ether
    (Inhalation
    only)
    Nitrobenzene
    Toluene
    (Ingestion
    only)
    2,4,5
    Trichiorophenol
    Vinyl
    acetate
    (Ingestion
    only)
    Liver
    Acenaphthene
    Acetone
    (Ingestion
    only)
    Butylbenzyl phthalate
    (Ingestion
    only)
    Chlorobenzene
    (Ingestion
    only)
    1,1
    Dichloroethylene
    (Ingestion
    only)
    Di
    n
    octyl
    phthalate
    (Ingestion
    only)
    Ethylbenzene
    Fluoranthene
    Methyl tertiary
    butyl
    ether
    (Inhalation
    only)
    Nitrobenzene
    Picloram
    Styrene
    (Ingestion only)
    2,4,5
    TP (Silvex)
    Toluene
    (Ingestion
    only)
    1’IA
    (Inhalation
    only)
    Central
    Nervous
    System
    Butanol
    (Ingestion
    only)
    Cyanide
    (amenable)
    2,4
    Dimethylphenol
    Endrin
    Manganese
    2 Methylphenol
    Mercury
    (Inhalation
    only)
    Styrene
    (Inhalation
    only)
    Toluene
    (Inhalation only)
    Xylenes
    (Ingestion
    only)
    Circulatory
    System
    Antimony
    Barium
    (Ingestion
    only)
    2,4
    D
    cis
    1,2
    Dichloro
    ethylene
    (Ingestion
    only)
    Nitrobenzene
    trans
    1,2 Dichioroethylene
    (Ingestion
    only)
    2,4 Dimethylphenol
    Fluoranthene
    Fluorene
    Styrene
    (Ingestion only)
    Zie
    Gastrointestinal
    System
    Beryllium
    (Ingestion
    only)
    Endothall
    Hexachiorocyclopentadiene
    (Ingestion
    only)
    Methyl
    bromide
    (Ingestion
    only)
    Methyl
    tertiary
    butyl
    ether
    (Ingestion
    only)
    — ,—,
    2,4,5
    Trichlorophenol

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    2,4 Dichiorophenol
    p
    Chioroaniline
    Mercury
    (gestion
    only)
    Reproductive
    System
    Bamim
    (Inhalation
    only)
    Boron
    (Ingestion
    only)
    Carbon disulfide
    2
    Chiorophenol
    (Ingestion
    only)
    1,2 Dibromo
    3
    Chioropropane
    (Inhalation
    only)
    Dinoseb
    Ethylbenzene
    (Inhalation
    only)
    Methoxychior
    Phenol
    Respiratory
    System
    1,2 Dichioropropane
    (Inhalation
    only)
    1,3 Dichioropropylene
    (Inhalation
    only)
    Hexachiorocyclopentadiene
    (Inhalation
    only)
    Methyl
    bromide (Inhalation
    only)
    Nanhthalene
    (Inhalation
    only)
    Toluene
    (Inhalation
    only)
    Vinyl
    acetate
    (Inhalation
    only)
    Cholincstcrase
    Inhibition
    Aldicarb
    Carbofuran
    Decreased
    Body Weight
    C pins
    and
    Circulatory
    System
    Effects
    Atrazine
    Simazine

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    Adrenal
    Gland
    Decreased
    Body
    Weight
    Gain
    (continued)
    Isopropylbenzene
    Ensosulfan
    2-Methylphenol
    (o-cresol)
    Cholinesterase
    Inhibition
    Naphthalene
    (ingestion
    only)
    Aldicarb
    Nickel
    (ingestion
    only)
    Carbofuran
    n-Nitrosodiphenylamine
    Phenol
    (ingestion
    only)
    Circulatory
    System
    Simazine
    Alachlor
    Tetrachioroethylene
    (ingestion
    only)
    Antimony
    (ingestion
    only)
    1,1,1-Trichioroethane
    (ingestion
    only)
    Benzene
    Vinyl
    acetate
    (ingestion
    only)
    Cobalt
    (ingestion
    only)
    Xylenes
    (Res.
    &
    TIC
    only)
    (ingestion
    only)
    2,4-D
    cis-l,2-Dichloroethylene
    (ingestion
    only)
    Endocrine
    System
    2,4-Dimethylphenol
    Cyanide
    2,4-Dinitrotoluene
    1
    ,2-Dibromoethane
    (ingestion
    only)
    2,6-Dinitrotoluene
    Di-n-octyl
    phthalate
    (ingestion
    only)
    Ensosulfan
    Nitrobenzene
    Fluoranthene
    l,2,4-Trichlorobenzene
    (ingestion
    only)
    Fluorene
    Methylene
    Chloride
    (inhalation
    only)
    Nickel
    (Res.
    &
    I/C
    only)
    (inhalation
    only)
    2,4-Dinitrophenol
    Nitrate
    as
    N
    n-Nitrosodiphenylamine
    Nitrobenzene
    Polychiorinated
    biphenyls
    (PCBs)
    Selenium
    Trichioroethylene
    Simazine
    Styrene
    (ingestion
    only)
    Gastrointestinal
    System
    1,3
    ,5-Trinitrobenzene
    Beryllium
    (ingestion
    only)
    Zinc
    Copper
    1 ,3-Dichloropropene
    (cis
    +
    trans)
    (ingestion
    only)
    Decreased
    Body
    Weight
    Gain
    Endothall
    Atrazine
    Fluoride
    Bis(2-chloroethyl)ether
    Hexachiorocyclopentadiene
    (ingestion
    only)
    Cyanide
    Iron
    1
    ,2-Dichlorobenzene
    (inhalation
    only)
    Methyl
    bromide
    (ingestion
    only)
    Diethyl
    phthalate
    (ingestion
    only)
    Methyl
    tertiary-butyl
    ether
    (ingestion
    only)

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    System
    4-Chioroaniline
    2,4-Dichiorophenol
    Mercury
    (ingestion
    only)
    Polychiorinated
    biphenyls (PCBs)
    Kidney
    Acetone
    (ingestion
    only)
    Aldrin
    (CW
    only)
    Barium
    Bromodichioromethane
    (ingestion
    only)
    Cadmium
    2,4-D
    Dalapon
    1,1
    -Dichloroethane
    1
    ,2-Dichloroethane
    (CW
    only)
    (ingestion
    only)
    Ensosulfan
    Ethylbenzene (ingestion
    only)
    Fluoranthene
    gamma-HCH
    (gamma-BHC)
    Hexachloroethane
    (ingestion
    only)
    Isopropylbenzene
    MCPP
    Methyl
    tertiary-butyl
    ether
    (inhalation
    only)
    Nitrobenzene
    Pentachlorophenol
    Pene
    Toluene
    (ingestion
    only)
    2,4,5-Trichiorophenol
    Vinyl
    acetate
    (ingestion
    only)
    Liver
    Acenaphthene
    Aldrin
    (Res.
    &
    TIC
    only)
    Bis(2-ethylhexyl)phthalate
    (Res.&
    TIC
    only)
    (ingestion
    only)
    Bromoform
    Butyl
    Benzyl
    Phthalate
    (ingestion
    only)
    Carbon
    Tetrachloride
    Liver
    (continued)
    Chlorobenzene
    (ingestion
    only)
    Chlorodibromomethane
    (ingestion
    only)
    Chloroform
    2,4-D
    DDT
    1 ,2-Dibromoethane
    (ingestion
    only)
    1
    ,2-Dichlorobenzene
    (CW
    only)
    (ingestion
    only)
    1
    ,4-Dichlorobenzene
    Dichlorodifluoromethane
    1
    ,2-Dichloroethane
    (inhalation
    only)
    1,1
    -Dichloroethylene
    trans-i
    ,2-Dichloroethylene
    1
    ,2-Dichloropropane
    (in estion
    Dieldrin
    (Res.
    &
    TIC
    only)
    2,4-Dinitrotoluene
    2,6-Dinitrotoluene
    Di-n-octyl
    phthalate
    (ingestion
    only)
    p-Dioxane
    Endrin
    Ethylbenzene
    (ingestion
    only)
    Fluoranthene
    Heptachlor
    Heptachlor
    epoxide
    Hexachlorobenzene
    alpha-HCH
    (alpha-BHC)
    gamma-HCH
    (gamma-BHC)
    RMX
    Isophorone
    (inhalation
    only)
    Methyl
    tertiary-butyl
    ether
    Methylene
    Chloride
    (ingestion
    only)
    Nitrobenzene
    Pentachlorophenol
    Phenol
    (inhalation
    only)
    Picloram
    Styrene
    (ingestion
    only)
    Tetrachioroethylene
    (ingestion
    only)
    Toxaphene
    (CW
    only)
    Chlordane
    2,4,5-TP
    (Silvex)

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Liver
    (continued)
    Reproductive
    System
    (continued)
    1
    ,2,4-Trichlorobenzene
    (inhalation
    only)
    Carbofuran
    1,1,1
    -Trichloroethane
    (inhalation
    only)
    Carbon
    disulfide
    (ingestion
    only)
    1,1
    ,2-Trichloroethane
    (ingestion
    only)
    2-Chlorophenol
    2,4,5
    -Trichlorophenol
    1
    ,2-Dibromo-3
    -chloropropane
    2,4,6-Trinitrotoluene
    1
    ,2-Dibromoethane
    (ingestion
    only)
    Vinyl
    Chloride
    Dicamba
    Dinoseb
    Mortality
    Ethylbenzene
    (inhalation
    only)
    Di-n-butyl phthalate
    (ingestion
    only)
    Isophorone
    (inhalation
    only)
    Xylenes
    (Res.
    &
    IJC
    only)
    (ingestion
    only)
    Reproductive
    System
    (continued)
    Nervous
    System
    Methoxychlor
    Butanol
    (ingestion
    only)
    RDX
    Carbon
    disulfide
    (inhalation
    only)
    2,4,6-Trichlorophenol
    Cyanide
    Dieldrin
    (CW only)
    Respiratory
    System
    2,4-Dimethyiphenol
    Antimony
    (inhalation
    only)
    2,4-Dinitrotoluene
    Benzoic
    Acid
    (inhalation
    only)
    2,6-Dinitrotoluene
    Beryllium
    (inhalation
    only)
    Endrin
    Cadmium
    (inhalation
    only)
    Hexachloroethane
    (inhalation
    only)
    (CW
    only)
    Chromium
    (hex)
    (inhalation
    only)
    Manganese
    Cobalt
    (inhalation
    only)
    Mercury
    (inhalation
    only)
    1 ,2-Dibromoethane
    (inhalation
    only)
    2-Methylphenol
    (o-cresol)
    trans-i
    ,2-Dichloroethylene
    (inhalation
    only)
    Phenol
    (inhalation
    only)
    1
    ,2-Dichloropropane
    (inhalation
    ojy1
    Selenium
    1 ,3-Dichloropropene
    (cis
    +
    trans)(inhalation
    only)
    Styrene
    (inhalation only)
    Hexachlorocyclopentadiene
    (inhalation
    only
    Tetrachloroethylene
    (inhalation
    only)
    Methyl
    bromide
    (inhalation
    only)
    Toluene
    (inhalation
    only)
    Naphthalene
    (inhalation
    only)
    Trichloroethylene
    Nickel
    (inhalation
    only)
    Xylenes
    (CW
    only)
    (ingestion
    only)
    Vinyl
    acetate
    (inhalation
    only)
    Xylenes
    (inhalation
    only)
    Skin
    Reproductive
    System
    Arsenic
    (ingestion
    only)
    Arsenic
    (inhalation
    only)
    Polychlorinated
    biphenyls
    (PCBs)
    Bis(2-ethylhexyl)phthalate
    (CW
    only)
    (ingestion
    only)
    Selenium
    Boron
    Silver
    2-Butanone

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Spleen
    1,3 -Dinotrobenzene
    1,3 ,5-Trinitrobenzene
    Notes:
    Res.
    = Residential
    receptor
    TIC
    = Industrial
    Commercial receptor
    CW
    =
    Construction
    Worker
    receptor
    (Source:
    Amended
    at
    Ill. Reg.
    effective

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF PROPOSED
    AMENDMENTS
    Section
    742.APPENDIX A:
    General
    Section
    742.TABLE
    F: Similar-Acting
    Carcinogenic
    Chemicals
    Kidney
    Bromodichioromethane
    (Ingestion
    only)
    Chiorofomi (Ingestion
    only)
    1,2
    Dibromo
    3 chloropropane
    (Ingestion
    only)
    2,4
    Dinitrotoluene
    2,6
    Dinitrotoluene
    Hexachlorobenzene
    Liver
    Aidrin
    Bis(2
    chloroethyl)ether
    Bis(2
    ethylhexyl)phthalate
    (Ingestion
    only)
    Carbazole
    Carbon
    tetracl””
    Chlordane
    Chlorofc
    /T
    DDD
    DDE
    DDT
    1,2 Dib
    I
    T
    romo
    3 chioropropane
    (Ingestion
    only)
    i ,
    i)ibromoetflane(Ingestion
    only)
    3,3’ Dichlorobenzidine
    1,2
    Dichioroethane
    1,2 Dichioropropane
    (Ingestion
    only)
    1,3
    Dichloropropylene
    (Ingestion
    only)
    Dieldrin
    A
    2:6
    Dinitrotoluene
    Heptachior
    Heptachlor
    epoxide
    Hexachlorobenzene
    alpha
    HCH
    a
    I.T(TT IT
    Methyl;ehlori&
    N Nitrosodiphen
    KT KT...1
    .
    r,m 9
    .uane)
    4
    2
    iiamine
    Pentachiorophenol

    Tetrachioroethylene
    Trichioroethylene
    2,4,6
    Trichiorophenol
    Toxaphene
    Vinyl
    chloride
    (‘rriil
    nfrrr
    Srctm
    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF PROPOSED
    AMENDMENTS
    Benzene
    2,4,6
    Trichlhl
    arnr
    nr
    fln’trnintpctinn1
    qv’tpm
    Benzo(aanthracene
    (LL1LISJJ/
    Benzo(k)fluoranthene
    Benzo(a)pyrene
    Chrysene
    Dibenzo(a,h)anthracene
    11
    1
    I
    T
    Bromoform
    42
    F”
    I
    ‘) T’
    only)
    )
    romo
    3
    chloropropane
    (Ingestion
    only)
    iinromoethane
    (Ingestion
    only)
    1,3
    Dichloropropyiene
    (Ingestion
    only)
    g
    Arsenic
    (Inhalation
    only)
    Beryllium
    (Inhalation
    only)
    Cadmium
    (Inhalation
    only)
    Chromium,
    hexavalent
    (Inhalation
    only)
    1,3
    Dichloropropylene
    (Inhalation
    only)
    Methylene chloride
    (Inhalation
    only)
    N
    Nitrosodi
    n
    “vlamine
    Nickel
    (Inhalation
    only)
    Vinyl
    chloride
    Nasal
    Cavity
    1,2
    Dibromo
    3
    chloropropane
    (Inhalation
    only)
    1-2
    Dibromoethane
    (Inhalation
    only)
    \T
    propylamin

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Bladder
    3,30
    Dichlorobenzidine
    1,3 Dichioropropylene
    (Ingestion
    only)
    N Nitrosodiphenylamine

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AME1DMENTS
    Bladder
    Liver
    (continued)
    1
    ,3-Dichloropropene
    (cis
    +
    trans)
    (ingestion
    only)
    Chloroform
    n-Nitrosodiphenylamine
    DDD
    DDE
    Circulatory
    System
    DDT
    Benzene
    1
    ,2-Dichloropropane
    1
    ,2-Dibromoethane
    Dieldrin
    1
    ,2-Dichloroethane
    2,4-Dinitrotoluene
    Pentachlorophenol
    2,6-Dinitrotoluene
    2,4,6-Trichlorophenol
    p-Dioxane
    Heptachior
    Gall
    Bladder
    Heptachior
    epoxide
    p-Dioxane
    (inhalation
    only)
    Hexachlorobenzene
    alpha-HCH
    (alpha—BHC’)
    Gastrointestinal System
    gamma-HCH
    (gamma-BHC)
    Benzo(a)anthracene
    (ingestion
    only)
    Methylene
    Chloride
    Benzo(b)fluoranthene
    (ingestion
    only)
    n-Nitrosodiphenylamine
    (inhalation
    only)
    Benzo(k)flouranthene
    (ingestion
    only)
    n-Nitrosodi-n-propylamine
    Benzo(apene (ingestion
    only)
    Pentachlorophenol
    Bromoform
    Polychiorinated
    biphenyls
    (PCBs)
    Chrysene
    (ingestion
    only)
    Tetrachloroethylene
    Dibenzo(a,h)anthracene
    (ingestion
    only)
    Toxaphene
    1
    ,2-Dibromoethane
    (ingestion
    only)
    Trichloroethylene
    Indeno(1,2,3-cd)pyrene
    (ingestion
    only)
    Vinyl
    Chloride
    (I/C
    &
    CW)
    Vinyl
    Chloride
    (Res.)
    Kidney
    Bromodichioromethane
    (ingestion
    only)
    Mammary
    Gland
    Chloroform
    (ingestion
    only)
    3,3
    ‘-Dichlorobenzidine
    1
    ,2-Dibromo-3-chloropropane
    (ingestion
    only)
    2,4-Dinitrotoluene
    2,6-Dinitrotoluene
    Liver
    Aldrin
    Respiratory
    System
    Bis(2-chloroethyl)ether
    Arsenic
    (inhalation
    only)
    Bis(2-ethylhexyl)phthalate
    Benzo(a)anthracene
    (inhalation
    only)
    Carbazole
    Benzo(b)fluoranthene
    (inhalation
    only)
    Carbon
    Tetrachloride
    Benzo(k)flouranthene
    (inhalation
    only)
    Chiordane
    Benzo(a)pyrene
    (inhalation
    only)

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Respiratory
    System (continued)
    Beryllium
    Cadmium
    Chromium
    (hexavalent
    ion)
    Chrysene
    (inhalation
    only)
    Cobalt
    Dibenzo(a,h)anthracene
    (inhalation
    only)
    1
    ,2-Dibromo-3
    -chioropropane
    (inhalation
    only)
    1
    ,2-Dibromoethane
    (inhalation
    only)
    p-Dioxane (inhalation
    only)
    Trichloroethylene
    Notes:
    Res.
    =
    Residential
    receptor
    I/C
    =
    Industrial Commercial
    receptor
    CW
    =
    Construction
    Worker
    receptor
    (Source: Amended
    at
    Ill.
    Reg.
    effective

    ILLiNOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Section
    742.APPENDIX
    A
    General
    Section
    742.TABLE
    I
    Chemicals
    Whose
    Tier
    1
    Class
    I
    Groundwater
    Remediation
    Objective
    Exceeds
    the
    1
    in 1,000,000
    Cancer
    Risk
    Concentration
    Chemical
    Class
    I
    Groundwater
    1 in
    1,000,000
    Cancer
    ADL
    Remediation
    Objective
    Risk
    Concentration
    (mg/L)
    (mgIL)
    (mg/L)
    Aidrin
    0.014
    0.000005
    0.014
    Benzo(a)anthracene
    0.00013
    0.00012
    0.00013
    Benzo(a)pyrene
    0.0002
    0.000012
    0.00023
    Benzo’b)fluoranthene
    0.00018
    0.00012
    0.00018
    Bis(2-chloroethyl)ether
    0.01
    0.000077
    0.01
    Bis(2-ethylhexyl)phthalate
    0.006
    0.0061
    0.0027
    (Di(2-ethylhexyl)phthalate)
    Carbazole
    0.0043
    0.0043
    NA
    Carbon
    Tetrachloride
    0.005
    0.00066
    0.000
    1
    Chlordane
    0.002
    0.000066
    0.00014
    NA
    DDD
    0.014
    0.00023
    0.014
    DDE
    0.01
    0.00023
    0.01
    DDT
    0.006
    0.00023
    0.006
    Dibenzo(a,h)anthracene
    0.0003
    0.000012
    0.0003
    1
    ,2-Dibromo-3-chloropropane
    0.0002
    0.000061
    0.001
    1,2-Dibromoethane
    0.00005
    0.00002
    0.001
    3,3-Dichlorobenzidine
    0.02
    0.00019
    0.02
    1
    ,2-Dichloroethane
    0.005
    0.00094
    0.0003
    1,2-Dichioropropane
    0.005
    0.0024
    0.00006
    1,3-Dichioropropene
    0.001
    0.00085
    0.001
    Dieldrin
    0.009
    0.0000053
    0.009
    2,6-Dinitrotoluene
    0.00031
    0.0001
    0.00031
    Heptachior
    0.0004
    0.000019
    0.013
    Heptachior
    epoxide
    0.0002
    0.0000094
    0.015
    Hexachlorobenzene
    0.00006
    0.000053
    0.00006
    Alpha-HCH
    0.00011
    0.000014
    0.000111
    Gamma-HCH
    (gamnia-BHC)
    0.0002
    0.000066
    0.014
    Tetrachloroethylene
    0.005
    0.0016
    0.0004
    Toxaphene
    0.003
    0.000077
    0.00086
    NA
    Vinyl
    chloride
    (Non-residential)
    0.002
    0.00012
    0.0002
    Vinyl
    chloride
    (Residential)
    0.002
    0.000045
    0.000057
    0.0002
    Ionizable
    Organics
    Inorganics
    Arsenic
    0.000057
    0.001
    N-Nitrosodi-n-nropylamine
    Pentachiorophenol
    2,4,6-Trichiorophenol
    0.00 18
    0.001
    0.01
    0.000012
    0.00071
    0.007
    0.00
    18
    0.000076
    0.01
    (Source: Appendix
    A,
    Table
    I renumbered
    from
    Appendix
    A,
    Table
    H and
    amended
    at
    Ill.
    Reg.
    effective

    0
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    4
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    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Section
    742.
    APPENDIX
    A:
    Tier
    1 Illustrations
    and
    Tables
    Section
    742.
    TABLE
    K:
    Soil
    Vapor
    Saturation
    Limits
    (C
    t
    )
    for
    Volatile
    Chemicals
    CAS
    No.
    Chemical
    Name
    çsa
    t
    (mg/rn
    3
    )
    67-64-1
    Acetone
    7.50E+05
    71-43-2
    Benzene
    4.20E+05
    111-44-4
    Bis(2-chloroethyl)ether
    1 .20E+04
    75-27-4
    Brornodichioromethane
    4.50E+05
    75-25-2
    Bromoform
    7.80E+04
    7
    1-36-3
    Butanol
    2.90E+04
    78-93-3
    2-Butanone
    (MEK)
    3.80E+05
    75-15-0
    Carbon
    disulfide
    1.50E+06
    56-23
    -5
    Carbon
    tetrachloride
    1
    .00E+06
    1
    08-90-7
    Chlorobenzene
    7.40E+04
    124-48-1
    Chlorodibromornethane
    5
    .70E+04
    67-66-3
    Chloroform
    1
    .30E+06
    95-57-8
    2-Chlorophenol
    (ionizable
    organic)
    1
    .70E+04
    75-99-0
    Dalapon
    1 .50E+03
    96-12-8
    1 ,2-Dibromo-3 -chloropropane
    7. 80E+03
    106-93-4
    1 ,2-Dibrornoethane
    1 .40E+05
    95-50-1
    l,2-Dichlorobenzene
    1
    .1OE+04
    106-46-7
    1 ,4-Dichlorobenzene
    8
    .40E+03
    75-71-8
    Dichlorodifluoromethane
    3 .30E+07
    75-34-3
    1,1-Dichloroethane
    1
    .30E+06
    107-06-2
    1 ,2-Dichloroethane
    4.40E+05
    75-35-4
    1,1
    -Dichloroethylene
    3 .30E+06

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    CAS
    No.
    Chemical
    Name
    çsa
    t
    (mg/rn
    3
    )
    156-59-2
    cis-
    1
    ,2-Dichloroethylene
    1.1
    OE+06
    156-60-5
    trans-i
    ,2-Dichloroethylene
    1. 80E+06
    78-87-5
    1 ,2-Dichloropropane
    3 .20E+05
    542-75-6
    1,3
    -Dichioropropylene
    (cis
    + trans)
    2.1 OE+05
    123-91-1
    p-Dioxane
    1.90E+05
    100-41-4
    Ethylbenzene
    5.90E+04
    76-44-8
    Heptachior
    8.30E+00
    118-74-1
    Hexachlorobenzene
    2. 80E-0
    1
    77-47
    -4
    Hexachiorocyclopentadiene
    9.1 OE+02
    67-72-1
    Hexachioroethane
    2. 80E+03
    78-59-i
    Isophorone
    3.40E+03
    98-82-8
    Isopropylbenzene
    (Cumene)
    3
    .OOE+04
    7439-97-6
    Mercury
    (elemental)
    2.20E+01
    74-83-9
    Methyl
    bromide
    8.60E+06
    1
    63 4-04-4
    Methyl
    tertiary-butyl
    ether
    1
    .20E+06
    75-09-2
    Methylene
    chloride
    2.OOE+06
    93-65-2
    2-Methylnaphthalene
    5.3 OE+02
    1634-04-4
    2-Methylphenol
    (o-cresol)
    i
    . 80E+03
    91-20-3
    Naphthalene
    6.20E+02
    98-95-3
    Nitrobenzene
    i.70E+03
    621-64-7
    n-Nitrosodi-n-propylamine
    9.50E+02
    108-95-2
    Phenol
    1.50E+03
    1336-36-3
    Polychiorinated
    biphenyls
    PCBs)
    9.OOE+00
    100-42-5
    Styrene
    3.40E+04

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    CAS
    No.
    Chemical
    Name
    csa
    t
    (mg/rn
    3
    )
    127-18-4
    Tetrach1oroethyleiç
    l.80E+05
    108-88-3
    Toluene
    l.40E+05
    120-82-1
    1
    ,2,4-Trichlorobenzene
    4.30E+03
    71
    -5
    5-6
    1,1,1
    -Trichioroethane
    8
    .70E+05
    79-00-5
    1,1
    ,2-Trichloroethane
    1
    .70E+05
    79-01-6
    Trichioroethylene
    5.3
    OE+05
    75-69-4
    Trichlorofluoromethane
    6.30E+06
    108-05-4
    Vinyl
    acetate
    4.30E+05
    75-01-4
    Vinyl
    chloride
    1.1OE+07
    108-38-3
    m-Xylene
    5.20E+04
    95-47-6
    o-Xylene
    4.1OE+04
    106-42-3
    p-Xylene
    5.50E+04
    1330-20-7
    Xylenes
    (total)
    4.90E+04
    (Source:
    Added
    at
    Ill.
    Reg.
    effective

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Section
    742. APPENDIX
    A:
    Tier
    1 Illustrations
    and Tables
    Section
    742.
    TABLE
    L: Soil
    Saturation
    Limits
    (Cct)
    for Volatile
    Chemicals
    for
    the
    Indoor
    Inhalation
    Exposure
    Routea
    CAS
    No.
    Chemical
    Name
    sat(fflg/kg)
    67-64-1
    Acetone
    1.OOE+05
    7 1-43-2
    Benzene
    4.OOE+02
    11 1-44-4
    Bis(2-chloroethyl)ether
    2.20E+03
    75-27-4
    Bromodichioromethane
    1 .40E+03
    75-25-2
    Bromoform
    8.80E+02
    7 1-36-3
    Butanol
    8.30E+03
    75-15-0
    Carbon
    disulfide
    4.50E+02
    78-93-3
    2-Butanone
    (MEK)
    2.30E+04
    56-23
    -5
    Carbon
    tetrachioride
    5.OOE+02
    108-90-7
    Chlorobenzene
    2.40E+02
    124-48-1
    Chlorodibromomethane
    6.30E+02
    67-66-3
    Chloroform
    1 .70E+03
    95-57-8
    2-Chiorophenol
    (ionizable
    organic)
    4.90E+04
    75-99-0
    Dalapon
    9.90E+O4b
    96-12-8
    1 ,2-Dibromo-3
    -chloropropane
    3.1 0E+02’
    106-93-4
    1 ,2-Dibromoethane
    8.1 OE+02
    95-50-1
    1 ,2-Dichlorobenzene
    2.OOE+02
    1 0 6-46-7
    1 ,4-Dichlorobenzene
    1 .30E+02
    75-71-8
    Dichiorodifluoromethane
    4.90E+02
    75-34-3
    1,1 -Dichloroethane
    9.70E+02
    107-06-2
    1 ,2-Dichloroethane
    1 .20E+03

    ILLiNOIS
    REGISTER
    POLLUTION CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    CAS
    No.
    Chemical
    Name
    atLmWkg)
    75-35-4
    1, 1-Dichioroethylene
    7.60E+02
    1 56-59-2
    cis-l
    ,2-Dichloroethylene
    7.OOE+02
    156-60-5
    trans-1,2-Dichloroethylene
    1
    .60E+03
    78-87-5
    1
    ,2-Dichloropropane
    5
    :90E+02
    542-75-6
    1
    ,3-Dichloropropylene
    (cis
    + trans)
    6.OOE+02
    123-91-1
    p-Dioxane
    l.OOE+05
    100-41-4
    Ethylbenzene
    1 .30E+02
    76-44-8
    Heptachlor
    1 .1OE+00
    1
    1 8-74-1
    Hexachlorobenzene
    2.50E-0
    1
    77-47-4
    Hexachlorocyclopentadiene
    4.40E+0
    1
    67-72-1
    Hexachioroethane
    1
    .60E+02
    78-59-1
    Isophorone
    1 .80E+03
    98-82-8
    Isopropylbenzene
    (Cumene)
    3
    .70E+02
    7439-97-6
    Mercury
    (elemental)
    4.50E-01
    74-83-9
    Methyl
    bromide
    2.30E+03
    1634-04-4
    Methyl
    tertiary-butyl ether
    6.30E+03
    75-09-2
    Methylene
    chloride
    1
    .80E+03
    93-65-2
    2-Methylnaphthalene
    8
    .20E+0
    1
    1634-04-4
    2-Methylphenol
    (o-cresol)
    4.80E+03
    91
    -20-3
    Naphthalene
    3
    .40E+0
    1
    98-95-3
    Nitrobenzene
    3.80E+02
    62
    1-64-7
    n-Nifrosodi-n-propylamine
    1.30E+03
    108-95-2
    Phenol
    1.20E+04
    1336-36-3
    Polychlorinated biphenyls
    (PCBs)
    NA

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL BOARD
    NOTICE
    OF PROPOSED AMENDMENTS
    CAS
    No.
    Chemical
    Name
    mg/kg)
    100-42-5
    Styrene
    2.30E+02
    127-18-4
    Tetrachloroethylene
    2.90E+02
    108-88-3
    Toluene
    2.40E+02
    120-82-1
    1 ,2,4-Trichlorobenzene
    9.80E+02
    71-55-6
    1.1,1
    -Trichioroethane
    5
    .60E+02
    79-00-5
    1,1
    .2-Trichioroethane
    9.OOE+02
    79-01-6
    Trichioroethylene
    5
    .20E+02
    75-69-4
    Trichlorofluoromethane
    9
    .50E+02
    108-05-4
    Vinyl
    acetate
    2.20E+03
    75-01-4
    Vinyl
    chloride
    2.5E+03
    108-38-3
    m-Xylene
    1.50E+00
    9
    5-47-6
    o-Xylene
    1 .40E+02
    106-42-3
    p-Xylene
    1
    .20E+02
    1330-20-7
    Xylenes
    (total)
    1.OOE+02b
    The
    Soil
    Saturation
    Limit
    was
    calculated
    using
    an
    foc of 0.002
    gIg
    and a
    system
    temoerature
    of
    13°C.
    The
    Soil
    Saturation
    Limit
    calculated
    at 25°
    C.
    (Source:
    Added
    at
    Ill.
    Reg.
    effective

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    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Exposure
    Route-Specific
    Values
    for
    Soils
    Values
    for
    the
    Soil
    Component
    of
    the
    Groundwater
    Ingestion
    Exposure
    Route
    Vl-uea
    CAS
    No.
    Chemical
    Name
    Ingestion
    Outdoor
    Inhalation
    Class
    I
    Class
    II
    ADL
    (mg/kg)
    (mg/kg)
    (mg/kg)
    (mg/kg)
    (mg/kg)
    7440-62-2
    j
    Vanadium
    550b
    C
    ]
    0.O49
    0.lmt
    *
    7440-66-6
    ]
    Zinc’
    23,000
    24000b
    lOmt
    *
    “*“
    indicates
    that
    the
    ADL
    is
    less
    than
    or
    equal
    to
    the
    specified
    remediation
    objective.
    NA
    means
    not
    available;
    no
    PQL
    or
    EQL
    available
    in
    USEPA
    analytical
    methods.

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Chemical
    Name
    and
    Soil
    Remediation
    Objective
    Notations
    Soil
    remediation
    objectives
    based
    on
    human
    health
    criteria
    only.
    Calculated
    values
    correspond
    to
    a
    target
    hazard
    quotient
    of
    1.
    No
    toxicity
    criteria
    available
    for
    the
    route
    of
    exposure.
    IC’
    a
    b
    C
    d
    non
    saturation
    concentration
    .
    ,,-‘-the
    concentration
    at
    which
    the
    absorptive
    limits
    of
    the
    soil
    particles,
    the
    solubility
    limits
    of
    the
    available
    soil
    moisture,
    and
    saturation
    of
    soil
    pore
    air
    ha’.’e
    been
    reached.
    Above
    the
    soil
    saturation
    concentration,
    the
    assumptions
    regarding
    vapor
    transport
    to
    air
    and1or
    dissolved
    phase
    transport
    to
    groundwater
    (for
    chemicals
    which
    are
    liquid
    at
    ambient
    soil
    temperatures)
    have
    been
    violated,
    and
    alternative
    modeling
    approaches
    are
    required.
    Calculated
    Tier
    I
    remediation
    objective
    exceeds
    ihc
    value
    of
    the
    chemical
    in
    soil.
    Therefore,
    the
    C,
    of
    the
    chemical
    is
    shown.
    Calculated
    values
    correspond
    to
    a
    cancer
    risk
    level
    of
    1
    in
    1,000,000.
    See
    Appendix
    B,
    Table
    G
    for
    soil
    and
    soil
    gas
    remediation
    objectives
    for
    residential
    properties
    for
    the
    indoor
    inhalation
    exposure
    route.
    g
    Chemical-specific
    properties
    are
    such
    that
    this
    route
    is
    not
    of
    concern
    at
    any
    soil
    contaminant
    concentration.
    h
    40
    CFR
    761
    contains
    applicability
    requirements
    and
    methodologies
    for
    the
    development
    of
    PCB
    remediation
    objectives.
    Requests
    for
    approval
    of
    a
    Tier
    3
    evaluation
    must
    address
    the
    applicability
    of
    40
    CFR
    761.
    Soil
    remediation
    objective
    for
    pH
    of
    6.8.
    If
    soil
    pH
    is
    other
    than
    6.8,
    refer
    to
    Appendix
    B,
    Tables
    C
    and
    D
    of
    this
    Part.
    Ingestion
    soil
    remediation
    objective
    adjusted
    by
    a
    factor
    of
    0.5
    to
    account
    for
    dermal
    route.
    k
    A
    preliminary
    remediation
    goal
    of
    400
    mg/kg
    has
    been
    set
    for
    lead
    based
    on
    Revised
    Interim
    Soil
    Lead
    Guidance
    for
    C’ERC’LA
    Sites
    and
    RCRA
    C’orrective
    Action
    Facilities,
    OSWER
    Directive
    #9355.4-12.
    Potential
    for
    soil-plant-human
    exposure.
    The
    person
    conducting
    the
    remediation
    has
    the
    option
    to
    use:
    1)
    TCLP
    or
    SPLP
    test
    results
    to
    compare
    with
    the
    remediation
    objectives
    listed
    in
    this
    Table;
    2)
    where
    applicable,
    the
    total
    amount
    of
    contaminant
    in
    the
    soil
    sample
    results
    to
    compare
    with
    pH
    specific
    remediation
    objectives
    listed
    in
    Appendix
    B,
    Table
    C
    or
    D
    of
    this
    Part
    (see
    Section
    742.510);
    or
    3)
    the
    appropriate
    background
    value
    listed
    in
    Appendix
    A,
    Table
    G.
    If
    the
    person
    conducting
    the
    remediation
    wishes
    to
    calculate
    soil
    remediation
    objectives
    based
    on
    background
    concentrations,
    this
    should
    be
    done
    in
    accordance
    with
    Subpart
    D
    of
    this
    Part.
    The
    Agency
    reserves
    the
    right
    to
    evaluate
    the
    potential
    for
    remaining
    contaminant
    concentrations
    to
    pose
    significant
    threats
    to
    crops,
    livestock,
    or
    wildlife.
    °
    For
    agricheniical
    facilities,
    remediation
    objectives
    for
    surficial
    soils
    which
    are
    based
    on
    field
    application
    rates
    may
    be
    more
    appropriate
    for
    currently
    registered
    pesticides.
    Consult
    the
    Agency
    for
    further
    information.
    For
    agrichemical
    facilities,
    soil
    remediation
    objectives
    based
    on
    site-specific
    background
    concentrations
    of
    Nitrate
    as
    N
    maybe
    more
    appropriate.
    Such
    determinations
    shall
    be
    conducted
    in
    accordance
    with
    the
    procedures
    set
    forth
    in
    Subparts
    D
    and
    I
    of
    this
    Part.
    q
    The
    TCLP
    extraction
    must
    be
    done
    using
    water
    at
    a
    pH
    of
    7.0.
    Value
    based
    on
    dietary
    Reference
    Dose.
    Value
    based
    on
    the
    Groundwater
    Quality
    Standard
    for
    this
    chemical
    pursuant
    to
    35
    Ill.
    Adrn.
    Code
    620.
    Value
    for
    Ingestion
    based
    on
    Reference
    Dose
    for
    Mercuric
    chloride
    (CAS
    No.
    7487-94-7);
    value
    for
    Inhalation
    based
    on
    Reference
    Concentration
    for
    elemental
    Mercury
    (CAS
    No.
    743
    9-97-6).
    Inhalation
    remediation
    objective
    only
    applies
    at
    sites
    where
    elemental
    mercury
    is
    a
    contaminant
    of
    concern.
    For
    the
    ingestion
    route
    for
    arsenic,
    see
    742.Appendix
    A,
    Table
    G.
    U
    Value
    based
    on
    Reference
    Dose
    for
    Thallium
    sulfate
    (CAS
    No.
    7446-1
    8-6).
    V
    Value
    based
    on
    Reference
    Dose
    adjusted
    for
    dietary
    intake.
    V
    For
    sites
    located
    in
    any
    populated
    area
    as
    defined
    in
    Section
    742.200,
    Appendix
    A,
    Table
    H
    may
    be
    used.
    U
    The
    remediation
    objectives
    for
    these
    chemicals
    must
    also
    include
    the
    construction
    worker
    inhalation
    objective
    in
    Appendix
    B,
    Table
    B.

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Values
    for
    total
    Chromium
    based
    on
    toxicity
    data
    for
    hexavalent
    Chromium.
    Values
    based
    on
    maximum
    contaminant
    level.
    (Source:
    Amended
    at
    Ill.
    Reg.
    effective

    ILLiNOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Section
    742.APPENDIX
    B
    Tier
    1
    Illustrations
    and
    Tables
    Section
    742.Table
    B
    Tier
    1
    Soil
    Remediation
    Objectivesa
    for
    Industrial/Commercial
    Propertiesa
    Exposure
    Route-Specific
    Values
    for
    Soils
    Values
    for
    the
    Soil
    Component
    of
    the
    Groundwater
    Ingestion
    Exposure
    Route
    Values
    Industrial!
    -
    Construction
    Commercial
    Worker
    CAS
    No.
    Chemical
    Ingestion
    Outdoor
    Ingestion
    Outdoor
    Class
    I
    Class
    II
    ADL
    Name
    (mg/kg)
    Inhalation
    (mg/kg)
    Inhalation
    (mg/kg)
    (mg/kg)
    (mg/kg)
    (mg/kg)
    (mg/kg)
    83-32-9
    Acenaphthene
    [
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    NA
    [60-8
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    116-06-3
    ]
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    2,000b
    ]
    0,044
    O.014r
    0,07
    0.068r
    NA
    309-00-2
    1
    Aldrin
    04
    ow
    }
    b
    73e
    94
    04
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    44
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    J
    047
    *

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Exposure
    Route-Specific
    Values
    for
    Soils
    Constiuction
    Worker
    Values
    for
    the
    Soil
    Component
    of
    the
    Groundwater
    Ingestion
    Exposure
    Route
    Values
    Industrial!
    -
    Commercial
    CAS
    No.
    Chemical
    Ingestion
    Outdoor
    Ingestion
    Outdoor
    Class
    I
    Class
    II
    ADL
    Inhalation
    (mg/kg)
    Inhalation
    (mg/kg)
    (mg/kg)
    (mg/kg)
    Name
    (mg/kg)
    (mg/kg)
    (mg/kg)
    56-55-3
    Benzo(a)anthracene
    8
    78e
    400’
    170e
    .e
    2.lr
    8
    hf
    *
    205-99-2
    Benzo(b)fluoranthene
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    8
    180e
    170e
    —“
    26ff
    75r
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    2
    38r
    *
    207-08-9
    Benzo(k)fluroanthene
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    l,700e
    49
    48r
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    24ff
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    50-32-8
    [Benzo(a)pyrene
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    f
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    *
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    Bis(2-chloroethyl)ether
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    0.00036e
    0.00036
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    891J0e
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    31,000
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    31,000
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    92e
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    2,000e
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    75-27-4
    Bromodichloromethane
    [752s2
    Bromoform
    720e
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    04
    77Z
    04
    77Z
    *
    71-36-3
    Butanol
    200
    ,000b
    10000d
    200000b
    10,000’s
    17b
    [
    17
    NA
    78-93-3
    2-Butanone
    (MEK)
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    120000
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    85-68-7
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    86-74-8
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    290e
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    6,200e
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    [
    24
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    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Exposure
    Route-Specific
    Values
    for
    Soils
    Values
    for
    the
    Soil
    Component
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    the
    Groundwater
    Ingestion
    Exposure
    Route
    M4ue&
    Industrial!
    -
    Construction
    Commercial
    Worker
    CAS
    No.
    Chemical
    Ingestion
    Outdoor
    Ingestion
    1
    Outdoor
    Class
    I
    Class
    II
    ADL
    Name
    (mg/kg)
    Inhalation
    (mg/kg)
    I
    Inhalation
    (mg/kg)
    (mg/kg)
    (mg/kg)
    (mg/kg)
    (mg/kg)
    1563-66-2
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    ILliNOIS
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    AMENDMENTS
    Values
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    Groundwater
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    Exposure
    Route
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    Exposure
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    -
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    Construction
    Worker
    CAS
    No.
    Chemical
    Ingestion
    Outdoor
    Ingestion
    Outdoor
    Class
    I
    Class
    II
    ADL
    Name
    (mg/kg)
    Inhalation
    (mg/kg)
    Inhalation
    (mg/kg)
    (mg/kg)
    (mg/kg)
    (mg/kg)
    (mg/kg)
    91-94-1
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    Exposure
    Route-Specific
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    Soils
    Values
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    Outdoor
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    I
    Class
    II
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    Inhalation
    (mg/kg)
    Inhalation
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    (mg/kg)
    (mg/kg)
    (mg/kg)
    (mg/kg)
    (mg/kg)
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    ILLiNOIS
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    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Exposure
    Route-Specific
    Values
    for
    Soils
    Values
    for
    the
    Soil
    Component
    of
    the
    Groundwater
    Ingestion
    Exposure
    Route
    Vakies
    Industrial!
    -
    Construction
    Commercial
    Worker
    CAS
    No.
    Chemical
    Ingestion
    Outdoor
    Ingestion
    Outdoor
    Class
    I
    Class
    II
    ADL
    Name
    (mg/kg)
    Inhalation
    (mg/kg)
    Inhalation
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    (mg/kg)
    (mg/kg)
    (mg/kg)
    (mg/kg)
    (mg/kg)
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    0.66

    ILLINOIS
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    CAS
    No.
    Chemical
    Name
    Inorganics
    7440-36-0
    Antimony
    7440-38-2
    Arsenic1’
    7440-39-3
    Barium
    7440-41-7
    ]
    Beryllium
    7440-42-8
    Boron
    7440-43-9
    Cadmium”
    7440-70-2
    Calcium
    16887-00-6
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    Chromium,
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    16065-83-1
    Chromium,
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    POLLUTION
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    OF
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    AMENDMENTS
    Exposure
    Route-Specific
    Values
    for
    Soils
    Industrial!
    -
    Construction
    Commercial
    Worker
    Values
    for
    the
    Soil
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    Groundwater
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    0
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    H
    I
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    c
    ;
    I
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    CI)
    CO
    I
    C)
    0
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    0
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    0
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    0.
    0
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    .
    z
    C/)
    0)
    >
    CO
    C
    0)
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    C)
    0
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    00
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    -Ct-
    •-
    C/
    0
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    (4
    0
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    0)
    r
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    0
    0
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    0
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    C’)
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    C’)
    N
    t t N
    N
    CrC
    r
    t
    -
    N
    N
    CrC
    N
    N
    NN
    NN

    CAS
    No.
    Chemical
    Name
    14797-73-0
    Perchiorate
    7723-14-0
    Phosphorus
    7440-09-7
    Potassium
    7782-49-2
    Selenium”
    7440-22-4
    Silver
    7440-23
    -5
    Sodium
    14808-79-8
    Sulfate
    7440-28-0
    Thallium
    7440-62-2
    Vanadium
    7440-66-6
    Zinc’
    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Exposure
    Route-Specific
    Values
    for
    Soils
    “*“
    indicates
    that
    the
    ADL
    is
    less
    than
    or
    equal
    to
    the
    specified
    remediation
    objective.
    NA
    means
    Not
    Available;
    no
    PQL
    or
    EQL
    available
    in
    USEPA
    analytical
    methods.

    ILLiNOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Chemical
    Name
    and
    Soil
    Remediation
    Objective
    Notations
    (2d,
    5th
    thru
    8th
    Columns)
    Soil
    remediation
    objectives
    based
    on
    human
    health
    criteria
    only.
    Calculated
    values
    correspond
    to
    a
    target
    hazard
    quotient
    of
    1.
    No
    toxicity
    criteria
    available
    for
    this
    route
    of
    exposure.
    b
    d
    Soil
    saturation
    concentration
    (C)
    the
    concentration
    at
    which
    the
    absorptive
    limits
    of
    the
    soil
    particles,
    the
    solubility
    limits
    of
    the
    available
    soil
    moisture,
    and
    saturation-of
    soil
    pore
    air
    have
    been
    reached.
    Above
    the
    soil
    saturation
    concentration,
    the
    assumptions
    regarding
    vapor
    transport
    to
    air
    andior
    dissolved
    phase
    transport
    to
    groundwater
    (for
    chemicals
    which
    are
    liquid
    at
    ambient
    soil
    temperatures)
    have
    been
    violated,
    and
    alternative
    modeling
    approaches
    are
    required.
    Calculated
    Tier
    I
    remediation
    objective
    exceeds
    value
    of
    the
    chemical
    in
    soil.
    Therefore,
    the
    C,
    of
    the
    chemical
    is
    shown.
    Calculated
    values
    correspond
    to
    a
    cancer
    risk
    level
    of
    1
    in
    1,000,000.
    See
    Appendix
    B,
    Table
    G
    for
    soil
    remediation
    objectives
    for
    industrial/commercial
    properties
    for
    the
    indoor
    inhalation
    exposure
    route.
    g
    Chemical-specific
    properties
    are
    such
    that
    this
    route
    is
    not
    of
    concern
    at
    any
    soil
    contaminant
    concentration.
    h
    40
    CFR
    761
    contains
    applicability
    requirements
    and
    methodologies
    for
    the
    development
    of
    PCB
    remediation
    objectives.
    Requests
    for
    approval
    of
    a
    Tier
    3
    evaluation
    must
    address
    the
    applicability
    of
    40
    CFR
    761.
    Soil
    remediation
    objective
    for
    pH
    of
    6.8.
    If
    soil
    pH
    is
    other
    than
    6.8,
    refer
    to
    Appendix
    B,
    Tables
    C
    and
    D
    in
    this
    Part.
    Ingestion
    soil
    remediation
    objective
    adjusted
    by
    a
    factor
    of
    0.5
    to
    account
    for
    dermal
    route.
    See
    Appendix
    B,
    Table
    G
    for
    soil
    gas
    remediation
    objectives
    for
    industrial/commercial
    properties
    for
    the
    indoor
    inhalation
    exposure
    route..
    Potential
    for
    soil-plant-human
    exposure.
    m
    The
    person
    conducting
    the
    remediation
    has
    the
    option
    to
    use:
    (1)
    TCLP
    or
    SPLP
    test
    results
    to
    compare
    with
    the
    remediation
    objectives
    listed
    in
    this
    Table;
    (2)
    the
    total
    amount
    of
    contaminant
    in
    the
    soil
    sample
    results
    to
    compare
    with
    pH
    specific
    remediation
    objectives
    listed
    in
    Appendix
    B,
    Table
    C
    or
    D
    of
    this
    Part
    (see
    Section
    742.510);
    or
    (3)
    the
    appropriate
    background
    value
    listed
    in
    Appendix
    A,
    Table
    G.
    If
    the
    person
    conducting
    the
    remediation
    wishes
    to
    calculate
    soil
    remediation
    objectives
    based
    on
    background
    concentrations,
    this
    should
    be
    done
    in
    accordance
    with
    Subpart
    D
    of
    this
    Part.
    The
    Agency
    reserves
    the
    right
    to
    evaluate
    the
    potential
    for
    remaining
    contaminant
    concentrations
    to
    pose
    significant
    threats
    to
    crops,
    livestock,
    or
    wildlife.
    °
    For
    agrichemical
    facilities,
    remediation
    objectives
    for
    surficial
    soils
    which
    are
    based
    on
    field
    application
    rates
    may
    be
    more
    appropriate
    for
    currently
    registered
    pesticides.
    Consult
    the
    Agency
    for
    further
    information.
    For
    agrichemical
    facilities,
    soil
    remediation
    objectives
    based
    on
    site-specific
    background
    concentrations
    of
    Nitrate
    as
    N
    may
    be
    more
    appropriate.
    Such
    determinations
    shall
    be
    conducted
    in
    accordance
    with
    the
    procedures
    set
    forth
    in
    Subparts
    D
    and
    I
    of
    this
    Part.
    q
    The
    TCLP
    extraction
    must
    be
    done
    using
    water
    at
    a
    pH
    of
    7.0.
    r
    \ralue
    based
    on
    dietary
    Reference
    Dose.
    Value
    based
    on
    the
    Groundwater
    quality
    Standard
    for
    this
    chemical
    pursuant
    to
    35
    Ill.
    Adm.
    Code
    620.
    S
    Value
    for
    Ingestion
    based
    on
    Reference
    Dose
    for
    Mercuric
    chloride
    (CAS
    No.
    7487-94-7);
    value
    for
    Inhalation
    based
    on
    Reference
    Concentration
    for
    elemental
    Mercury
    (CAS
    No.
    743
    9-97-6).
    Inhalation
    remediation
    objective
    only
    applies
    at
    sites
    where
    elemental
    mercury
    is
    a
    contaminant
    of
    concern.
    For
    the
    ingestion
    route
    for
    arsenic
    for
    industrial/commercial,
    see
    742.Appendix
    A,
    Table
    G.
    U
    Value
    based
    on
    Reference
    Dose
    for
    Thallium
    sulfate
    (CAS
    No.
    7446-1
    8-6).
    W
    Value
    based
    on
    Reference
    Dose
    adjusted
    for
    dietary
    intake.
    *
    n
    For
    any
    populated
    areas
    as
    defined
    in
    Section
    742.200,
    Appendix
    A,
    Table
    H
    may
    be
    used.
    Value
    based
    on
    maintaining
    fetal
    blood
    lead
    below
    10
    ug/dl,
    using
    the
    USEPA
    adults
    Blood
    Lead
    Model.
    Values
    for
    total
    Chromium
    based
    on
    toxicity
    data
    for
    hexavalent
    Chromium.
    z
    Values
    based
    on
    a
    maximum
    contaminant
    level.
    (Source:
    Amended
    at
    Ill.
    Reg.
    effective

    ILLiNOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Section
    742.APPENDIX
    B
    Tier
    1
    Illustrations
    and
    Tables
    Section
    742.Table
    C
    pH
    Specific
    Soil
    Remediation
    Objectives
    for
    Inorganics
    and
    Ionizing
    Organics
    for
    the
    Soil
    Component
    of
    the
    Groundwater
    Ingestion
    Route
    (Class
    I
    Groundwater)
    Chemical
    (totals)
    pH
    4.5
    to
    pH
    4.75
    pH
    5.25
    pH
    5.75
    pH
    6.25
    pH
    6.65
    pH
    6.9
    pH
    7.25
    pH
    7.75
    pH
    8.25
    pH
    8.75
    (mg/kg)
    4.74
    to
    5.24
    to
    5.74
    to
    6.24
    to
    6.64
    to
    6.89
    to
    7.24
    to
    7.74
    to
    8.24
    to
    8.74
    to
    9.0
    Inorganics
    Antimony
    55
    5
    55555555
    Arsenic
    25
    25.2
    25.4
    25.6
    295.8
    295.8
    296
    1462
    26.4
    36.6
    Barium
    260
    490
    850
    1,200
    1,500
    1,600
    1,700
    1,800
    2,100
    a
    Beryllium
    1.1
    2.1
    3.4
    6.6
    22
    63
    140
    1,000
    8,000
    a
    Cadmium
    1.0
    1.7
    2.7
    3.7
    5.2
    7.5
    11
    59
    430
    a
    Chromium
    (+6)
    70
    62
    54
    46
    40
    38
    36
    32
    28
    24
    21
    Copper
    330
    580
    2,100
    11,000
    59,000
    130,000
    200,000
    330,000
    330,000
    aa
    Cyanide
    40
    40
    40
    40
    40
    40
    40
    40
    40
    40
    40
    Lead
    23
    23
    23
    23
    107
    107
    107
    107
    107
    107
    282k
    Mercury
    0.01
    0.01’
    0.03
    0.15
    0.89
    2.1
    3.3
    6.4
    8.0
    a
    a
    Nickel
    20
    36
    56
    76
    100
    130
    180
    700
    3,800
    a
    Selenium
    24
    17
    12
    8.8
    6.3
    5.2
    4.5
    3.3
    2.4
    1.8
    1.3
    Silver
    0.24
    0.33
    0.62
    1.5
    4.4
    8.5
    13
    39
    110
    a

    ILLiNOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Chemical
    (totals)
    pH
    4.5
    to
    4.75
    pH
    5.25
    pH
    5.75
    pH
    6.25
    pH
    6.65
    pH
    6.9
    pH
    7.25
    pH
    7.75
    pH
    8.25
    pH
    8.75
    (mg/kg)
    4.74
    to
    5.24
    to
    5.74
    to
    6.24
    to
    6.64
    to
    6.89
    to
    7.24
    to
    7.74
    to
    8.24
    to
    8.74
    to
    9.0
    Thallium
    1.6
    1.8
    2.0
    2.4
    2.6
    2.8
    3.0
    3.4
    3.8
    4.4
    4.9
    Vanadium
    980
    980
    980
    980
    980
    980
    980
    980
    980
    980
    980
    Zinc
    1,000
    1,800
    2,600
    3,600
    5,100
    6,200
    7,500
    16,000
    53,000
    a
    Organics
    BenzoicAcid
    440140
    420120
    4-1-0120
    400110
    400110
    4.00110
    400110
    400110
    400110
    400110
    400110
    2-.Chlorophenol
    4-.0L3
    40j
    4Gj.
    40L3
    =6t
    2211
    2,4-Dichiorophenol
    1-036
    1-03
    1-03.6
    4-05
    10
    4-011
    4011
    04611
    o6911
    04611
    04807
    Dinoseb
    40.72
    440.39
    1410.
    18
    0420.093
    043.0.06
    1
    0440.054
    0440.051
    0,2-70.048
    0460.046
    0460.046
    0450.046
    MCPP
    (Mecoprop)
    Q4I
    Q934
    QQ
    2J
    Pentachiorophenol
    04411
    034L4
    0A4Q
    007ZZ
    004Qj
    000.l2
    002
    002
    002(L085
    02Q4
    2,4,5
    TP
    (Silvex)
    26
    1-6
    4-2
    44
    44
    14
    -14
    44
    44
    14
    44
    2,4,5-
    400740
    3.90740
    3.90720
    4-70670
    340550
    2-70440
    270360
    4-70180
    6485
    3446
    2433
    Trichiorophenol
    2,4,6-
    04-71.3
    0461.2
    0441
    0290.73
    0200.43
    0450.31
    0430.26
    0,090.19
    0,070.17
    0,070.16
    0070.16
    Trichiorophenol
    a
    No
    data
    available
    for
    this
    pH
    range.
    b
    For
    Lead,
    this
    value
    maybe
    used
    up
    to
    a
    pH
    of
    11.0.
    (Source:
    Amended
    at
    Ill.
    Reg.
    effective

    ILLiNOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Section
    742.APPENDIX
    B
    Tier
    1
    Illustrations
    and
    Tables
    Section
    742.Table
    D
    pH
    Specific
    Soil
    Remediation
    Objectives
    for
    Inorganics
    and
    Ionizing
    Organics
    for
    the
    Soil
    Component
    of
    the
    Groundwater
    Ingestion
    Route
    (Class
    II
    Groundwater)
    Chemical
    (totals)
    pH
    4.5
    to
    pH
    4.75
    pH
    5.25
    pH
    5.75
    pH
    6.25
    pH
    6.65
    pH
    6.9
    pH
    7.25
    pH
    7.75
    pH
    8.25
    pH
    8.75
    (mg/kg)
    4.74
    to
    5.24
    to
    5.74
    to
    6.24
    to
    6.64
    to
    6.89
    to
    7.24
    to
    7.74
    to
    8.24
    to
    8.74
    to
    9.0
    Inorganics
    Antimony
    20
    20
    20
    20
    20
    20
    20
    20
    20
    20
    20
    Arsenic
    100
    100
    100
    110
    110
    120
    120
    120
    120
    130
    130
    Barium
    260
    490
    850
    1,200
    1,500
    1,600
    1,700
    1,800
    2,100
    a
    Beryllium
    140
    260
    420
    820
    2,800
    7,900
    17,000
    130,000
    1,000,000
    a
    Cadmium
    10
    17
    27
    37
    52
    75
    110
    590
    4,300
    a
    a
    Chromium
    (+6)
    No
    Data
    No
    Data
    No
    Data
    No
    Data
    No
    Data
    No
    Data
    No
    Data
    No
    Data
    No
    Data
    No
    Data
    No
    Data
    Copper
    330
    580
    2,100
    11,000
    59,000
    130,000
    200,000
    330,000
    330,000
    a
    a
    Cyanide
    120
    120
    120
    120
    120
    120
    120
    120
    120
    120
    120
    Lead
    300
    300
    300
    300
    1,420
    1,420
    1,420
    1,420
    1,420
    1,420
    3,RIOk
    Mercury
    0.05
    0.06
    0.14
    0.75
    4.4
    10
    16
    32
    40
    a
    a
    Nickel
    400
    730
    1,100
    1,500
    2,000
    2,600
    3,500
    14,000
    76,000
    a
    a
    Selenium
    24
    17
    12
    8.8
    6.3
    5.2
    4.5
    3.3
    2.4
    1.8
    1.3
    Thallium
    16
    18
    20
    24
    26
    28
    30
    34
    38
    44
    49
    Zinc
    2,000
    3,600
    5,200
    7,200
    10,000
    12,000
    15,000
    32,000
    110,000
    a

    ILLTh1OIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Chemical
    (totals)
    pH
    4.5
    pH
    4.75
    pH
    5.25
    pH
    5.75
    pH
    6.25
    pH
    6.65
    pH
    6.9
    pH
    7.25
    pH
    7.75
    pH
    8.25
    pH
    8.75
    (mg/kg)
    to
    4.74
    to
    5.24
    to
    5.74
    to
    6.24
    to
    6.64
    to
    6.89
    to
    7.24
    to
    7.74
    to
    8.24
    to
    8.74
    to
    9.0
    Organics
    BenzoicAcid
    440140
    420120
    44-0120
    400110
    400110
    400110
    400110
    400110
    400110
    400110
    400110
    2-Chiorophenol
    20L.
    20L
    2GL
    20L
    20I
    20L
    4-9L.
    2411
    2,4-Dichiorophenol
    1-018
    4-0
    4-0
    4-0j
    1-0
    4-7
    4-0
    086
    0.699.
    05611
    04g07
    Dinoseb
    47.2
    443.9
    Wl.8
    20.93
    440.61
    340.54
    340.51
    240.48
    340.46
    340.46
    340.46
    MCPP
    (Mecoprop’)
    023
    0.19
    0.17
    0.17
    0.17
    0.17
    0.17
    0.17
    0.17
    0.17
    0.17
    Pentachiorophenol
    24i
    1-47
    0-3!
    034L4
    048Q1
    0-l-507
    042
    049A
    04-G9A
    04(4Q4
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    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Groundwater
    Remediation
    Objective
    CAS
    No.
    Chemical
    Name
    Class
    I
    f
    Class
    II
    (mg!L)
    I
    (mg!L)
    14808-79-8
    [Sulfate
    400
    400c
    7440-28-0
    [Thallium
    0.002c
    0.02°
    7440-62-2
    [Vanaciium
    .
    0.049
    7440-66-6
    [Zinc
    5.0°
    10°
    Chemical
    Name
    and
    Groundwater
    Remediation
    Objective
    Notations
    The groundwater remediation
    objective
    is equal
    to the
    ADL
    for carcinogens
    according
    to
    the procedures
    specified
    in
    35
    III.
    Adm.
    Code
    620
    or
    the I in
    1.000,000
    cancer
    risk
    level,
    whichever
    is
    greater.
    b
    Oral
    Reference
    Dose
    andior
    Reference
    Concentration
    under
    review
    by
    USEPA.
    Listed
    values
    subject
    to
    chge.
    These
    Groundwater
    Remediation Objectives
    are
    for
    the
    Direct
    Ingestion
    of
    Groundwater
    Component
    of
    the Groundwater
    Ingestion
    Route.
    For
    values
    to use
    when
    calculating
    the
    Soil
    Remediation
    Objective
    for the
    Soil
    Component
    of
    the Groundwater
    Ingestion
    Route,
    see
    Section
    742.Appendix
    B,
    Table
    F.
    °
    Value
    listed is
    also
    the
    Groundwater
    Quality
    Standard
    for
    this
    chemical
    pursuant
    to 35
    Ill. Adm.
    Code
    620.410
    for
    Class
    I
    Groundwater
    or
    35
    Ill.
    Adm.
    Code
    620.420
    for Class
    II Groundwater.
    d
    This
    chemical
    is
    included
    in the
    Total
    Dissolved
    Solids (TDS)
    Groundwater
    Quality
    Standard
    of
    1,200
    mg/l
    pursuant
    to 35
    Ill.
    Adm.
    Code
    620.410
    for
    Class
    I Groundwater
    or 35
    Ill.
    Adm.
    Code
    620.420
    for Class
    II Groundwater.
    e
    Value
    for non-carcinogens calculated
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    to
    the
    procedures
    in 35 Ill.
    Adm.
    Code
    620.Appendix A.
    (Source:
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    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF PROPOSED
    AMENDMENTS
    GW
    0b
    Concentration
    used
    to Calculate
    Tier
    1 Soil
    Remediation
    Objectives’
    CAS
    No.
    Chemical
    Name
    Class
    I
    Class
    II
    (mgIL)
    (mgIL)
    7440-22-4
    Silver
    0.05c
    17440-23-5
    Sodium
    14808-79-8
    Sulfate
    400c
    400c
    7440-28-0
    Thallium
    0.002’
    0.02’
    7440-62-2
    Vanadium
    O.O
    49
    c
    0.
    l
    7440-66-6
    Zinc
    5.0c
    lOc
    Chemical
    Name and
    Groundwater
    Remediation
    Objective
    Notations
    a
    The
    Equation
    S17
    is used
    to calculate
    the
    Soil
    Remediation
    Objective
    for the Soil
    Component
    of the
    Groundwater
    Ingestion
    b
    Route;
    this
    equation
    requires
    calculation
    of
    the
    Target
    Soil
    Leachate
    Concentration
    (C)
    from Equation
    S18:
    C
    = DF
    x
    GWObJ.
    Value
    listed is
    the
    Water Health
    Based
    Limit
    (HBL)
    for
    this chemical
    from
    Soil
    Screening
    Guidance:
    User’s Guide,
    incorporated
    by
    reference
    at Section
    742.210.
    The HBL
    is equal
    to the non-zero
    MCLG
    (if available);
    the MCL
    (if
    available);
    or,
    for carcinogens,
    a cancer
    risk
    of
    1
    .OE-6
    (based on
    a
    30
    year
    and
    350 days/year
    exposure
    scenario),
    and
    for
    noncarcinogens
    is equal
    to a Hazard
    Quotient
    of 1.0.
    NOTE: These
    GW
    0
    bJ
    concentrations
    are
    not
    equal to
    the
    Tier 1
    Groundwater
    Remediation
    Objectives
    for
    the Direct
    Ingestion
    of Groundwater
    Component
    of
    the Groundwater
    Ingestion
    Route,
    listed
    in
    Section
    742.Appendix
    B,
    Table
    E.
    C
    Value
    listed
    is also
    the
    Groundwater
    Quality
    Standard
    for
    this chemical
    pursuant
    to
    35
    Ill. Adm.
    Code 620.410
    for
    Class
    I
    Groundwater
    or 35
    III. Adm.
    Code
    620.420 for
    Class II
    Groundwater.
    d
    Value
    listed
    is
    equivalent
    to
    the Human
    Threshold
    Toxicant
    Advisory
    Concentration
    (H11’AC)
    calculated
    according
    to the
    methods
    in
    35
    Ill.
    Adm. Code
    620.Appendix
    A for
    noncarcinogens.
    For
    carcinogens,
    the value
    listed
    is
    equal
    to
    the
    1 .OE-6
    risk
    level
    (based
    on a 30
    year
    and 350
    days/year
    exposure
    scenario).
    (Source:
    Amended
    at
    Ill.
    Reg.
    effective
    )

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    ILLiNOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Soil
    Groundwater
    Soil
    Gas
    Chemical
    Name
    and
    Soil
    Remediation
    Objective
    Notations
    a
    Soil
    remediation
    objectives
    based
    on
    human
    health
    criteria
    only.
    b
    Calculated
    values
    correspond
    to
    a
    target
    hazard
    quotient
    of
    1.
    Calculated
    Tier
    I
    remediation
    objective
    exceeds
    the
    C,,
    value
    of
    the
    chemical
    in
    soil.
    Therefore,
    thç_
    of
    the
    chemical
    is
    shown.
    d
    Calculated
    values
    correspond
    to
    a
    cancer
    risk
    level
    of
    1
    in
    1,000,000.
    40
    CFR
    761
    contains
    applicability
    requirements
    and
    methodologies
    for
    the
    development
    of
    PCB
    remediation
    obiectives.
    Requests
    for
    approval
    of
    a
    Tier
    3
    evaluation
    must
    address
    the
    applicability
    of
    40
    CFR
    761.
    Calculated
    at
    25°C.
    For
    Dalapon
    the
    critical
    temperature
    (Tc)
    is
    not
    available.
    For
    Xylenes
    (total),
    the
    enthalpy
    of
    vaporization
    (Hv,b)
    at
    the
    normal
    boiling
    point
    is
    not
    available.
    Calculated
    Tier
    1
    remediation
    objective
    exceeds
    the
    Csat
    value
    of
    the
    chemical
    in
    soil
    gas.
    Therefore,
    the
    Csat
    of
    the
    chemical
    is
    shown.
    h
    Calculated
    Tier
    1
    remediation
    objective
    exceeds
    the
    solubility
    of
    the
    chemical
    in
    water.
    Therefore,
    the
    solubility
    of
    the
    chemicalis
    shown.
    Residential
    Industrial!
    ADL
    Residential
    Industrial!
    Residential
    Industrial/
    Chemical
    Name
    Commercial
    Commercial
    Commercial
    (mg/kg)
    (mg/kg)
    (mg/kg)
    (mg/L)
    (mg/L)
    (mg/m3)
    (mg/m3)
    Toluene
    240c
    240c
    *
    53()1
    53()I1
    140000g
    140000g
    l,2,4-Trichlorobenzene
    220b
    980’
    *
    35”
    35”
    1,600”
    4,300g
    l,l,l-Trichloroethane
    560c
    5(51JC
    *
    1300h
    1300h
    770,000”
    870
    ,000g
    1,1,2-Trichloroethane
    900c
    91J1JC
    *
    4,40011
    4400h
    170
    000’
    170
    000
    Trichloroethylene
    026d
    19d
    *
    0d
    6”
    l”
    1300d
    Trichlorofluoromethane
    31”
    190”
    *
    48
    26()
    970001)
    595000b
    Vinyl
    acetate
    2-flb
    1600b
    *
    2500b
    15000”
    28000b
    174000b
    Vinyl
    chloride
    0.011
    d
    *
    0rd
    OM”
    4413d
    m-Xylene
    *
    17,000
    b
    52000g
    o-Xylene
    98”
    l40’
    *
    15011
    1ch
    17000b
    52
    ,000g
    p-Xylene
    75”
    120c
    *
    12J”
    160001)
    55,000
    Xylenes
    (total)
    100c,f
    ,
    16000b
    49OOO
    Mercury
    is
    measured
    in
    mg/L.
    (Source:
    Added
    at
    Ill.
    Reg.
    effective
    )

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Section
    742.APPENDIX
    C
    Tier
    2
    Illustrations
    and
    Tables
    Section
    742.Table
    B
    SSL
    Parameters
    Symbol
    Parameter
    Units
    Source
    Parameter
    Value(s)
    AT
    Averaging
    Time
    for
    yr
    Residential
    =
    6
    Noncarcinogens
    in
    Industrial/Commercial
    25
    Ingestion
    Equation
    Construction
    Worker
    =
    0.1
    15
    AT
    Averaging
    Time
    for
    yr
    Residential
    =
    30
    Noncarcinogens
    in
    Industrial/Commercial
    =
    25
    Inhalation
    Equation
    Construction
    Worker
    0.1
    15
    AT
    Averaging
    Time
    for
    yr
    SSL
    70
    Carcinogens
    BW
    Body
    Weight
    kg
    Residential
    =
    15,
    noncarcinogens
    70,
    carcinogens
    Industrial/Commercial
    =
    70
    Construction
    Worker
    =
    70
    Csat
    Soil
    Saturation
    mg/kg
    Appendix
    A,
    Table
    A
    or
    Chemical-Specific
    or
    Concentration
    Equation
    S29
    in
    Calculated
    Value
    Appendix
    C,
    Table
    A
    C
    Target
    Soil
    Leachate
    mg/L
    Equation
    SI
    8
    in
    Groundwater
    Standard,
    Health
    Advisory
    Concentration
    Appendix
    C,
    Table
    A
    concentration,
    or
    Calculated
    Value
    d
    Mixing
    Zone
    Depth
    m
    SSL
    or
    2
    m
    or
    Equation
    S25
    in
    Calculated
    Value
    Appendix
    C,
    Table
    A
    da
    Aquifer
    Thickness
    m
    Field
    Measurement
    Site-Specific

    ILLiNOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Symbol
    [
    Parameter
    Units
    Source
    Parameter
    Value(s)
    d
    Depth
    of
    Source
    m
    Field
    Measurement
    or
    Estimation
    Site-Specific
    (Vertical
    thickness
    of
    contamination)
    DA
    Apparent
    Diffusivity
    cm2
    /s
    Equation
    S
    10
    in
    Calculated
    Value
    Appendix
    C,
    Table
    A
    D
    Diffusivity
    in
    Air
    cm2
    /s
    Appendix
    C,
    Table
    E
    Chemical-Specific
    D
    Diffusivity
    in
    Water
    cm2
    /s
    Appendix
    C,
    Table
    E
    Chemical-Specific
    DF
    Dilution
    Factor
    unitless
    Equation
    S22
    in
    20
    or
    Calculated
    Value
    Appendix
    C,
    Table
    A
    ED
    Exposure
    Duration
    for
    yr
    Industrial/Commercial
    =
    25
    Ingestion
    of
    Carcinogens
    Construction
    Worker
    =
    ED
    Exposure
    Duration
    for
    yr
    Residential
    =
    30
    Inhalation
    of
    Carcinogens
    Industrial/Commercial
    =
    25
    Construction
    Worker
    =
    ED
    Exposure
    Duration
    for
    yr
    Residential
    =
    6
    Ingestion
    of
    Industrial/Commercial
    =
    25
    Noncarcinogens
    Construction
    Worker
    =
    1
    ED
    Exposure
    Duration
    for
    yr
    Residential
    30
    Inhalation
    of
    Industrial/Commercial
    =
    25
    Noncarcinogens
    Construction
    Worker
    =
    1
    ED
    Exposure
    Duration
    for
    the
    yr
    Residential
    =
    30
    Direct
    Ingestion
    of
    Industrial/Commercial
    =
    25
    Groundwater
    Construction
    Worker
    =
    EDML
    Exposure
    Duration
    for
    yr
    SSL
    70
    Migration
    to
    Groundwater
    Mass-Limit
    Equation
    S28

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Symbol
    Parameter
    Units
    Source
    Parameter
    Value(s)
    EF
    Exposure
    Frequency
    d/yr
    Residential
    =
    350
    lndustriallConimercial
    =
    250
    Construction
    Worker
    =
    30
    F(x)
    Function
    dependent
    on
    unitless
    SSL
    0.
    194
    Urn/Ut
    f,
    Organic
    Carbon
    Content
    g/g
    SSL
    or
    Surface
    Soil
    0.006
    of
    Soil
    Field
    Measurement
    Subsurface
    soil
    =
    0.002,
    or
    (See
    Appendix
    C,
    Table
    F)
    Site-Specific
    GW0bJ
    Groundwater
    Remediation
    mg/L
    Appendix
    B,
    Table
    E,
    Chemical-Specific
    or
    Calculated
    Remediation
    Objective
    35
    IAC
    620.Subpart
    F,
    or
    Equation
    S23
    in
    Appendix
    C,
    Table
    A
    H’
    Henry’s
    Law
    Constant
    unitless
    Appendix
    C,
    Table
    E
    Chemical-Specific
    i
    Hydraulic
    Gradient
    rn/rn
    Field
    Measurement
    Site-Specific
    (See
    Appendix
    C,
    Table
    F)
    I
    Infiltration
    Rate
    rn/yr
    SSL
    0.3
    ‘M-i.
    Infiltration
    Rate
    for
    rn/yr
    SSL
    0.18
    Migration
    to
    Groundwater
    Mass-Limit
    Equation
    S28
    IFsoiiaâj
    Age
    Adjusted
    Soil
    (mg-yr)/(kg-d)
    SSL
    114
    .
    .
    Ingestion
    Factor
    for
    (residential)
    Carcinogens
    IR501
    Soil
    Ingestion
    Rate
    rng/d
    Residential
    =
    200
    Industrial/Commercial
    =
    50
    Construction
    Worker
    =
    480

    ILLNOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Symbol
    Parameter
    Units
    j
    Source
    [
    Parameter
    Value(s)
    lRw
    Daily
    Water
    Ingestion
    L/d
    Residential
    =
    2
    Rate
    IndustriallCommercial
    K
    Aquifer
    Hydraulic
    rn/yr
    Field
    Measurement
    Site-Specific
    Conductivity
    (See
    Appendix
    C,
    Table
    F)
    Kd
    (Non-ionizing
    Soil-Water
    Partition
    cm
    3/g
    or
    L/kg
    Equation
    SI
    9
    in
    Calculated
    Value
    organics)
    Coefficient
    Appendix
    C,
    Table
    A
    Kd
    (Ionizing
    organics)
    Soil-Water
    Partition
    crn3lg
    or
    L/kg
    Equation
    Sl
    9
    in
    Appendix
    C,
    Table
    A
    Chemical
    and
    pH-Specific
    (see
    Appendix
    Coefficient
    C,
    Table
    I)
    Kd
    (Inorganics)
    Soil-Water
    Partition
    cm3/g
    or
    L/kg
    Appendix
    C,
    Table
    J
    Chemical
    and
    pH-Specific
    Coefficient
    K0
    Organic
    Carbon
    Partition
    crn
    3/g
    or
    L/kg
    Appendix
    C,
    Table
    E
    Chemical-Specific
    Coefficient
    or
    Appendix
    C,
    Table
    I
    K,
    Saturated
    Hydraulic
    rn/yr
    Appendix
    C,
    Table
    K
    Site-Specific
    Conductivity
    Appendix
    C,
    Illustration
    C
    L
    Source
    Length
    Parallel
    to
    m
    Field
    Measurement
    Site-Specific
    Groundwater
    Flow
    PEF
    Particulate
    Emission
    m
    3/kg
    SSL
    or
    Equation
    S15
    in
    Appendix
    C,
    Residential
    1.32
    IO
    or
    Site-Specific
    Factor
    Table
    A
    Industrial/Commercial
    =
    1.24
    I
    o
    or
    Site-Specific
    PEF’
    Particulate
    Emission
    m
    3/kg
    Equation
    S16
    in
    Appendix
    C,
    Table
    A
    1.24
    108
    or
    Site-Specific
    Factor
    adjusted
    for
    using
    PEF
    (industrial/commercial)
    Agitation
    (construction
    worker)

    ILLiNOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Symbol
    Parameter
    Units
    [
    Source
    Parameter
    Value(s)
    QIC
    Inverse
    of
    the
    mean
    (gIm2-s)/(kg/m3
    )
    Appendix
    C,
    Table
    H
    Residential
    =
    68.81
    (
    used
    in
    VF
    equations)
    concentration
    at
    the
    center
    IndustriallCommercial
    85.81
    of
    a
    square
    source
    Construction
    Worker
    =
    85.81
    Q/C
    Inverse
    of
    the
    mean
    (g/m2-s)/(kg/m3
    )
    SSL
    or
    Appendix
    C,
    Table
    H
    Residential
    =
    90.80
    (used
    in
    PEF
    equations)
    concentration
    at
    the
    center
    Industrial/Commercial
    =
    85.81
    of
    a
    square source
    Construction
    Worker
    =
    85.81
    RIU
    Inhalation
    Reference
    mg/rn3
    IEPA
    (II’JS/HEAST
    Illinois
    EPA
    Toxicological-Specific
    Concentration
    (Note:
    for
    Construction
    Workers
    use
    subchronic
    reference
    concentrations)
    MDO
    Oral
    Reference
    Dose
    mg/(kg-d)
    IPA-RIS44S4
    Illinois
    EPA
    Toxicological-Specific
    (Note:
    for
    Construction
    Worker
    use
    subchronic
    reference
    doses)
    S
    Solubility
    in
    Water
    mg/L
    Appendix
    C,
    Table
    E
    Chemical-Specific
    SF0
    Oral
    Slope
    Factor
    (mg/kg-d)’
    IEPA
    (IPJS/HEAST)
    Illinois
    EPA
    Toxicological-Specific
    T
    Exposure
    Interval
    s
    Residential
    =
    9.5
    108
    Industrial/Commercial
    =
    7.9
    I
    o
    Construction
    Worker
    =
    3.6
    106
    TML
    Exposure
    Interval
    for
    yr
    SSL
    30
    Mass-Limit
    VolatilizationFactor
    Equation
    S26
    THQ
    Target
    Hazard
    Quotient
    unitless
    SSL
    1

    ILLiNOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Symbol
    Parameter
    Units
    Source
    Parameter
    Value(s)
    TR
    Target
    Cancer
    Risk
    unitless
    Residential
    1
    06
    at
    the
    point
    of
    human
    exposure
    Industrial/Commercial
    1
    06
    at
    the
    point
    of
    human
    exposure
    Construction
    Worker
    =
    lO
    at
    the
    point
    of
    human
    exposure
    Urn
    Mean
    Annual
    Windspeed
    rn/s
    SSL
    4.69
    URF
    Inhalation
    Unit
    Risk
    (ug/m3)1
    IEPA
    (IRIS/HEAST
    Illinois
    EPA
    Toxicological-Specific
    Factor
    U1
    EquivalentThreshold
    rn/s
    SSL
    11.32
    Value
    of
    Windspeed
    at
    7
    m
    V
    Fraction
    of
    Vegetative
    unitless
    SSL
    or
    Field
    Measurement
    0.5
    or
    Site-Specific
    Cover
    VF
    Volatilization
    Factor
    m
    3/kg
    Equation
    S8
    in
    Calculated
    Value
    Appendix
    C,
    Table
    A
    VF’
    Volatilization
    Factor
    m
    3/kg
    Equation
    S9
    in
    Calculated
    Value
    adjusted
    for
    Agitation
    Appendix
    C,
    Table
    A
    VFML
    Mass-Limit
    Volatilization
    m
    3/kg
    Equation
    S26
    in
    Calculated
    Value
    Factor
    Appendix
    C,
    Table
    A
    VF’ML
    Mass-Limit
    Volatilization
    m
    3/kg
    Equation
    S27
    in
    Calculated
    Value
    Factor
    adjusted
    for
    Appendix
    C,
    Table
    A
    Agitation

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    PROPOSED
    AMENDMENTS
    Symbol
    Parameter
    Units
    [
    Source
    Parameter
    Value(s)
    Total
    Soil
    Porosity
    LrdLsojj
    SSL
    or
    0.43,
    or
    Equation
    S24
    in
    Appendix
    C,
    Table
    A
    Gravel
    =
    0.25
    Sand
    =
    0.32
    Silt
    =
    0.40
    Clay
    0.36,
    or
    Calculated
    Value
    °a
    Air-Filled
    Soil
    Porosity
    LajJLsoij
    SSL
    or
    Surface
    Soil
    (top
    1
    meter)
    =
    0.28
    Equation
    S2l
    in
    Subsurface
    Soil
    (below
    1
    meter)
    =
    0.13,
    Appendix
    C,
    Table
    A
    or
    Gravel
    =
    0.05
    Sand=
    0.14
    Silt
    -
    0.24
    Clay=
    0.19,
    or
    Calculated
    Value
    Ow
    Water-Filled
    Soil
    Porosity
    LwateJLs011
    SSL
    or
    Surface
    Soil
    (top
    1
    meter)
    0.15
    Equation
    S20
    in
    Subsurface
    Soil
    (below
    1
    meter)
    =
    0.30,
    Appendix
    C,
    Table
    A
    or
    Gravel
    =
    0.20
    Sand
    =
    0.18
    Silt
    =
    0.16
    Clay
    =
    0.17,
    or
    Calculated
    Value

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    AMENDMENTS
    Symbol
    [
    Parameter
    Units
    Source
    Parameter
    Value(s)
    Pb
    Dry
    Soil
    Bulk
    Density
    kg/L
    or
    g/cm
    3
    SSL
    or
    1.5,
    or
    Field
    Measurement
    (See
    Appendix
    C,
    Table
    F)
    Silt=
    1.6
    Clay=
    1.7,
    or
    Site-Specific
    Ps
    Soil
    Particle
    Density
    g/cm
    3
    SSL
    or
    2.65,
    or
    Field
    Measurement
    (See
    Appendix
    C,
    Table
    F)
    Site-Specific
    psy
    Water
    Density
    glcm3
    SSL
    1/(2b+3)
    Exponential
    in
    Equation
    unitless
    Appendix
    C,
    Table
    K
    Site-Specific
    S20
    Appendix
    C,
    Illustration
    C
    USEPA,
    Office
    of
    Solid
    Waste
    and
    Emergency
    Response.
    EPA/SQO/R-95/036.
    Updated
    Quarterly.
    (Source:
    Amended
    at
    Ill.
    Reg.
    effective

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    AMENDMENTS
    Section
    742.APPENDIX
    C
    Tier
    2
    Illustrations
    and
    Tables
    Section
    742.Table
    D
    RBCA Parameters
    Symbol
    Parameter
    Units
    Source
    Parameter
    Value(s)
    AT
    Averaging
    Time
    for
    Carcinogens
    yr
    RBCA
    70
    AT
    Averaging
    Time
    for
    yr
    RBCA
    Residential
    =
    30
    Noncarcinogens
    Industrial/Commercial
    =
    25
    Construction
    Worker
    =
    0.115
    BW
    Adult
    Body
    Weight
    kg
    RBCA
    70
    Csource
    The
    greatest
    potential
    mg/L
    Field
    Measurement
    Site-Specific
    concentration
    of
    the
    contaminant
    of
    concern
    in
    the
    groundwater
    at
    the
    source
    of
    the
    contamination,
    based
    on
    the
    concentrations
    of
    contaminants
    in
    groundwater
    due
    to
    the
    release
    and
    the
    projected
    concentration
    of
    the
    contaminant
    migrating
    from
    the
    soil
    to
    the
    groundwater.
    C()
    Concentration
    of
    Contaminant
    in
    mg/L
    Equation
    R26
    in
    Calculated
    Value
    Groundwater
    at
    Distance
    X
    from
    Appendix
    C,
    Table
    C
    the
    source
    C(x)/Csource
    Steady-State
    Attenuation
    Along
    the
    unitless
    Equation
    Ri
    5
    in
    Calculated
    Value
    Centerline
    of
    a
    Dissolved
    Plume
    Appendix
    C,
    Table
    C
    d
    Lower
    Depth
    of
    Surficial
    Soil
    Zone
    cm
    Field
    Measurement
    100
    or
    Site-Specific
    (not
    to
    exceed
    100)

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    Value(s)
    D
    Diffusion
    Coefficient
    in
    Air
    cm2
    /s
    Appendix
    C,
    Table
    E
    Chemical-Specific
    Dtet
    Diffusion
    Coefficient
    in
    Water
    cm2
    /s
    Appendix
    C,
    Table
    B
    Chemical-Specific
    DS°
    Effective
    Diffusion
    Coefficient
    in
    cm2
    /s
    Equation
    R6
    in
    Calculated
    Value
    Soil
    Based
    on
    Vapor-Phase
    Appendix
    C,
    Table
    C
    Concentration
    ED
    Exposure
    Duration
    yr
    RBCA
    Residential
    =
    30
    Industrial/Commercial
    =
    25
    Construction
    Worker
    =
    EF
    Exposure
    Frequency
    d/yr
    RBCA
    Residential
    =
    350
    Industrial/Commercial
    =
    250
    Construction
    Worker
    =
    30
    erf
    Error
    Function
    unitless
    Appendix
    C,
    Table
    G
    Mathematical
    Function
    f
    Organic
    Carbon
    Content
    of
    Soil
    g/g
    RBCA
    or
    Surface
    Soil
    =
    0.006
    Field
    Measurement
    Subsurface
    Soil
    =
    0.002
    or
    (See
    Appendix
    C,
    Table
    F)
    Site-Specific
    GWcomp
    Groundwater
    Objective
    at
    the
    mg/L
    Appendix
    B,
    Table
    E,
    Site-Specific
    Compliance
    Point
    35
    IAC
    620.Subpart
    F,
    or
    Equation
    R25
    in
    Appendix
    C,
    Table
    C
    GWsource
    Groundwater
    Concentration
    at
    the
    mg/L
    Equation
    Rl3
    in
    Calculated
    Value
    Source
    Appendix
    C,
    Table
    C

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    AMENDMENTS
    Symbol
    Parameter
    Units
    Source
    (
    Parameter
    Value(s)
    H’
    Henry’s
    Law
    Constant
    cm3wate,Jcm3aj,
    Appendix
    C,
    Table
    E
    Chemical-Specific
    i
    Hydraulic
    Gradient
    cm/cm
    (unitless)
    Field
    Measurement
    Site-Specific
    (See
    Appendix
    C,
    Table
    F)
    I
    Infiltration
    Rate
    cm/yr
    RBCA
    30
    IRair
    Daily
    Outdoor
    Inhalation
    Rate
    m3/d
    RBCA
    20
    IR011
    Soil
    Ingestion
    Rate
    mg/d
    RBCA
    Residential
    =
    100
    Industrial/Commercial
    =
    50
    Construction
    Worker
    =
    480
    IR
    Daily
    Water
    Ingestion
    Rate
    L/d
    RBCA
    Residential
    =
    2
    Industrial/Commercial
    =
    K
    Aquifer
    Hydraulic
    Conductivity
    cm/d
    for
    Equations
    R15,
    R19
    Field
    Measurement
    Site-Specific
    and
    R26
    (See
    Appendix
    C,
    Table
    F)
    cm/yr
    for
    Equation
    R24
    K0
    Organic
    Carbon
    Partition
    cm3/g
    or
    L/kg
    Appendix
    C,
    Table
    E
    or
    Chemical-Specific
    Coefficient
    Appendix
    C,
    Table
    I
    k
    Soil
    Water
    Sorption
    Coefficient
    cm3,Jg,0j1
    Equation
    R20
    in
    Calculated
    Value
    (non-ionizing
    Appendix
    C,Table
    C
    organics)
    k,
    Soil
    Water
    Sorption
    Coefficient
    cm3vate,Jgso
    Equation
    R20
    in
    Appendix
    C,
    Chemical
    and
    pH-Specific
    (See
    (ionizing
    organics)
    Table
    C
    Appendix
    C,
    Table
    I)
    k,
    Soil
    Water
    Sorption
    Coefficient
    cm3,/g,0j1
    Appendix
    C,
    Table
    J
    Chemical
    and
    pH-Specific
    (
    inorganics)

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    AMENDMENTS
    Symbol
    Parameter
    [its
    ]
    Source
    Parameter
    Value(s)
    L
    Depth
    to
    Subsurface
    Soil
    Sources
    cm
    RBCA
    100
    LF
    Leaching
    Factor
    (mg/Lt)J
    Equation
    R14
    in
    Calculated
    Value
    (mg/kg,01)
    Appendix
    C,
    Table
    C
    M
    Soil
    to
    Skin
    Adherence
    Factor
    mg/cm
    2
    RBCA
    0.5
    Pe
    Particulate
    Emission
    Rate
    g/cm
    2-s
    RBCA
    6.9
    RAFd
    Dermal
    Relative
    Absorption
    Factor
    unitless
    RBCA
    0.5
    RAFd
    Dermal
    Relative
    Absorption
    Factor
    unitless
    RBCA
    0.05
    (PNAs)
    RAFd
    Dermal
    Relative
    Absorption
    Factor
    unitless
    RBCA
    0
    (
    inorganics)
    .
    .
    .
    RBCA
    RAFO
    Oral
    Relative
    Absorption
    Factor
    umtless
    1.0
    RBSLair
    Carcinogenic
    ug/m
    3
    Equation
    R9
    in
    Chemical-,
    Media-,
    and
    Exposure
    Risk-Based
    Screening
    Level
    for
    Appendix
    C,
    Table
    C
    Route-Specific
    Air
    RBSLair
    Noncarcinogenic
    ug/m
    3
    Equations
    RIO
    in
    Chemical-,
    Media-,
    and
    Exposure
    Risk-Based
    Screening
    Level
    for
    Appendix
    C,
    Table
    C
    Route-Specific
    Air
    RfD1
    Inhalation
    Reference
    Dose
    mg/kg-d
    JEPA
    (JRIS/HEAST)
    Illinois
    Toxicological-Specific
    EPA

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    AMENDMENTS
    Symbol
    [
    Parameter
    Units
    Source
    Parameter
    Value(s)
    RID0
    Oral
    Reference
    Dose
    mgl(kg-d)
    JEPA
    (LPJS/HEAST)
    Illinois
    Toxicological-Specific
    EPA
    (Note:
    for
    Construction
    Worker
    use
    subchronic
    reference
    doses)
    SA
    Skin
    Surface
    Area
    cm2/d
    RBCA
    3,160
    Symbol
    Parameter
    Units
    Source
    Parameter
    Value(s)
    Sd
    Source
    Width
    Perpendicular
    to
    cm
    Field
    Measurement•
    For
    Migration
    to
    Groundwater
    Route:
    Groundwater
    Flow
    Direction
    in
    Use
    200
    or
    Site-Specific
    Vertical
    Plane
    For
    Groundwater
    remediation
    .
    objective:
    Use
    Site-Specific
    S0
    Source
    Width
    Perpendicular
    to
    cm
    Field
    Measurement
    Site-Specific
    Groundwater
    Flow
    Direction
    in
    Horizontal
    Plane
    SF
    Inhalation
    Cancer
    Slope
    Factor
    (mg/kg-d)1
    IEPA
    (IPJS/HEAST
    Illinois
    Toxicological-Specific
    EPA
    SF0
    Oral
    Slope
    Factor
    (mgIkg-d)
    IEPA
    (IRISfHEAST
    Illinois
    Toxicological-Specific
    EPA
    THQ
    Target
    Hazard
    Quotient
    unitless
    RBCA

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    PROPOSED
    AMENDMENTS
    Symbol
    Parameter
    [
    Units
    [
    Source
    Parameter
    Value(s)
    TR
    Target
    Cancer
    Risk
    unitless
    RBCA
    Residential
    =
    1
    O
    at
    the
    point
    of
    human
    exposure
    Industrial/Commercial
    =
    1
    06
    at
    the
    point
    of
    human
    exposure
    Construction
    Worker
    =
    I
    O
    at
    the
    point
    of
    human
    exposure
    U
    Specific
    Discharge
    cm/d
    Equation
    RI
    9
    in
    Calculated
    Value
    Appendix
    C,
    Table
    C
    Symbol
    Parameter
    Units
    Source
    Parameter
    Value(s)
    Uaj
    Average
    Wind
    Speed
    Above
    cm/s
    RBCA
    225
    Ground
    Surface
    in
    Ambient
    Mixing
    Zone
    Ugw
    Groundwater
    Darcy
    Velocity
    cm/yr
    Equation
    R24
    in
    Calculated
    Value
    Appendix
    C,
    Table
    C
    VF
    ,
    Volatilization
    Factor
    for
    Surficial
    kg/rn
    3
    Equation
    R5
    in
    Calculated
    Value
    Soils
    Regarding
    Part
    iculates
    Appendix
    C,
    Table
    C
    VFsamb
    Volatilization
    Factor
    (Subsurface
    (mg/m
    3
    j)/(mg/kg
    0
    ji)
    or
    Equation
    Ri
    1
    in
    Calculated
    Value
    Soils
    to
    Ambient
    Air)
    kg/rn
    3
    Appendix
    C,
    Table
    C
    VF
    5
    Volatilization
    Factor
    for
    Surficial
    kg/rn
    3
    Use
    Equations
    R3
    and
    R4
    in
    Calculated
    Value
    from
    Equation
    R3
    or
    Soils
    Appendix
    C,
    Table
    C
    R4
    (whichever
    is
    less)
    W
    Width
    of
    Source
    Area
    Parallel
    to
    cm
    Field
    Measurement
    Site-Specific
    Direction
    to
    Wind
    or
    Groundwater
    Movement

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    PROPOSED
    AMENDMENTS
    Symbol
    Parameter
    [
    Units
    (
    Source
    Parameter
    Value(s)
    w
    Average
    Soil
    Moisture
    Content
    g1,Jg0jj
    RBCA
    or
    0.1,
    or
    Field
    Measurement
    (See
    Appendix
    C,
    Table
    F)
    Surface
    Soil
    (top
    1
    meter)
    0.1
    Subsurface
    Soil
    (below
    1
    meter)
    0.2,
    or
    Site-Specific
    X
    Distance
    along
    the
    Centerline
    of
    cm
    Field
    Measurement
    Site-Specific
    the
    Groundwater
    Plume
    Emanating
    from
    a
    Source.
    The
    x
    direction
    is
    the
    direction
    of
    groundwater
    flow
    ct,,
    Longitudinal
    Dispersitivity
    cm
    Equation
    RI
    6
    in
    Calculated
    Value
    Appendix
    C,
    Table
    C
    a>,
    Transverse
    Dispersitivity
    cm
    Equation
    R17
    in
    Calculated
    Value
    Appendix
    C,
    Table
    C
    a
    Vertical
    Dispersitivity
    cm
    Equation
    Rl
    8
    in
    Calculated
    Value
    Appendix
    C,
    Table
    C
    hair
    Ambient
    Air
    Mixing
    Zone
    Height
    cm
    RBCA
    200
    3gw
    Groundwater
    Mixing
    Zone
    cm
    RBCA
    200
    Thickness

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    AMENDMENTS
    Symbol
    Parameter
    Units
    Source
    fParameter
    Value(s)
    9
    Volumetric
    Air
    Content
    in
    Vadose
    cm
    3
    ajrJcm
    3sojj
    RBCA
    or
    Surface
    Soil
    (top
    1
    meter)
    =
    0.28
    Zone
    Soils
    Equation
    R2l
    in
    Subsurface
    Soil
    (below
    I
    meter)=
    0.13,
    Appendix
    C,
    Table
    C
    Or
    Gravel
    =
    0.05
    Sand
    =
    0.14
    Silt=
    0.16
    Clay
    =
    0.
    17,
    or
    Calculated
    Value
    0.
    Volumetric
    Water
    Content
    in
    cm
    3wateiJcm
    3
    soji
    RBCA
    or
    Surface
    Soil
    (top
    1
    meter)
    =
    0.15
    Vadose
    Zone
    Soils
    Equation
    R22
    in
    Subsurface
    Soil
    (below
    1
    meter)
    Appendix
    C,
    Table
    C
    0.30,
    or
    Gravel
    0.20
    Sand
    =
    0.18
    Silt=0.16
    Clay=
    0.17,
    or
    Calculated
    Value
    °T
    Total
    Soil
    Porosity
    cm
    3
    /cm
    3
    01
    RBCA
    or
    0.43,
    or
    Equation
    R23
    in
    Appendix
    C,
    Table
    C
    Gravel
    =
    0.25
    Sand
    =
    0.32
    Silt
    =
    0.40
    Clay=
    0.36,
    or
    Calculated
    Value
    First
    Order
    Degradation
    Constant
    d1
    Appendix
    C,
    Table
    E
    Chemical-Specific

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    AMENDMENTS
    Symbol
    Parameter
    [
    Units
    [
    Source
    Parameter
    Value(s)
    ii;
    pi
    3.1416
    Pb
    Soil
    Bulk
    Density
    g/cm3
    RBCA
    or
    1.5,
    or
    Field
    Measurement
    (See
    Appendix
    C,
    Table
    F)
    Gravel
    =
    2.0
    Sand=
    1.8
    Silt=
    1.6
    Clay=
    1.7,or
    Site-Specific
    p
    Water
    Density
    g/cm3
    RBCA
    t
    Averaging
    Time
    for
    Vapor
    Flux
    s
    RBCA
    9.46
    108
    a
    HEAST
    Health
    Effects
    Asesment
    Summary
    Table&—USEPA,
    Office
    of
    Solid
    Waste
    and
    Emergency
    Response.
    EPAJS4O/R-95/036.
    Updated
    Quarterly.
    (Source:
    Amended
    at
    Ill.
    Reg.
    effective

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Section
    742.APPENDIX
    C:
    Tier
    2
    Illustrations
    and
    Tables
    Section
    742.Table
    E:
    Default
    Physical
    and
    Chemical
    Parameters
    D4eftse11e
    Organic
    Solubility
    in
    Diffuivity
    in
    Air
    Diffucivity
    in
    Henry
    Law
    Carbon
    Water
    (5)
    D4
    Watei’-(
    Contrant
    (H)
    P-al4i-tioR
    Degradation
    CAS
    No.
    heiea1
    (mg/L)
    (em,1s
    eefei
    Constant
    (I’ee
    (Ykg
    Neutral
    Organicc
    83
    32
    9
    Acenaphthene
    444
    0.0421
    7.69E
    6
    0.00636
    7-Q80
    0.0034
    67
    64
    1
    Aeetee
    400OO0
    0-1-24
    1.1IE
    5
    0.00159
    0.0495
    -1-59-72
    60
    8
    Alachior
    24
    0,0-1-98
    5.69-B
    6
    0,0U000-14
    394
    No-Data
    116
    06
    3
    Aldicarb
    6000
    00305
    7.19E
    6
    0.0000000574
    -14
    0.O010
    309
    00
    2
    Aidrin
    0,-1-8
    0,01-3
    4.86E
    6
    0.00697
    2,450,000
    0.00059
    120
    12
    7
    Anthracene
    0,0434
    0324
    7.74E
    6
    0.00267
    29500
    0.00075
    1912
    24
    9
    Mfabe
    0
    0.025
    8
    00000008
    45-1-
    No
    Data
    71
    43
    2
    Benene
    1--50
    U88
    9.80E
    6
    042%
    &8
    0.0009

    ILLiNOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Dimensionless
    Ofganie
    Se4ubi44ty4fi
    Diffusivity
    in
    Air
    D&ffuwit’-i+
    Henrys
    Law
    Carbon
    Ofdef
    Water
    (S)
    (Di)
    Water
    (D)
    Constant
    (H)
    P4ii
    Degradation
    CAS
    No.
    heea4
    (ed/s)
    (25C
    Coefficient
    Getai+t
    EKee)
    (b4g)
    56
    55
    3
    Bee(aai4wacee
    0004
    005-1-0
    004
    0,G00-1-3.
    9-8000
    0O005-1-
    205
    99
    2
    Benzob)fluoranthene
    00G4-
    00226
    5.56E
    6
    0004&
    1,230,000
    0.00057
    207
    08
    9
    Bene(k)eranthene
    0000
    0.0226
    5.56E
    6
    0.000034
    1,230,000
    0.00016
    65
    85
    0
    Benzoic
    Acid
    O0
    004
    7.97E
    6
    0.000063
    1
    0.600
    Ne-Data
    50
    32
    8
    Benzo(a)p)Tene
    0.00162
    004
    9.OOE
    6
    000004é
    40000
    00006
    111
    ‘11
    1
    Bis(2
    chloroethyl)ether
    17,200
    0.0692
    7.53E
    6
    G00-8
    .1-54
    0.0019
    117
    81
    7
    Bis(2
    ethylhexyl)phthalate
    044
    0.0351
    3.66E
    6
    0.00000418
    15,100,000
    0.0018
    75
    27
    4
    Bromodichioromethane
    6740
    0.0298
    1.06E
    5
    0.0656
    5&0
    No
    Data
    75
    25
    2
    Bromoform
    3.400
    0.0149
    LO3E
    5
    0.0219
    0.0019
    71
    36
    3
    Butanol
    74,000
    0.0800
    9.30E
    6
    0.000361
    0.01283
    85
    68
    7
    Butyl
    Benzyl
    Phthalate
    0.0174
    4.83E
    6
    0.0000517
    57,500
    0003E
    86
    74
    8
    Carbazole
    748
    0.0390
    7.03E
    6
    0.000000626
    339Q
    No-Data

    ILLiNOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Dimensionless
    ganie
    eie
    Carbon
    Wate-
    D4
    Water
    (D
    eaat-W)
    atitiea
    Degfadatiea
    CAS
    No.
    Chemical
    gLb
    Coefficient
    Constant
    (b4Eg)
    (44)
    1563
    66
    2
    Gabewaa
    320
    00249
    643E-6
    .00377
    27
    Ne-Data
    75
    15
    0
    Carbon
    Disulfide
    4-5-1-90
    0404
    1
    pOE
    5
    1-24
    454
    No
    Data
    56
    23
    5
    Carbon
    Tetrachioride
    792
    0.0780
    8.80E
    6
    4-2
    1-74
    0.0019
    57
    74
    9
    Chiordane
    0056
    0.0118
    ‘137E
    6
    0.00199
    140000
    0.00025
    106
    ‘17
    8
    p
    Chloroaniline
    5200
    00482
    1.01E
    5
    0.0000136
    664
    Ne-Data
    108
    90
    7
    Chlorobenzene
    472
    0.0730
    8.70E
    6
    0443
    2-1-9
    0.0023
    124
    48
    1
    Ch1orodiromonqethane
    23600
    0.0196
    1.05E
    5
    0.0321
    634
    0.00385
    67
    66
    3
    Chloroform
    7.920
    0404
    1.OOE
    5
    04
    298
    0.00039
    95
    57
    8
    2-Ch1efepheae
    22,000
    0.0501
    9.46E
    6
    0,04-6
    3-88
    Ne-Data
    218
    01
    9
    0001-6
    0.0248
    6.21E
    6
    0.00388
    398,000
    0.00035
    94
    75
    7
    254—D
    680
    0.0231
    7.3
    1E-6
    0,00000044-
    45-1-
    0,003-85
    72
    54
    8
    4,4’
    DDD
    0,09
    00469
    ‘1.7613
    6
    0,0004-64
    1,000,000
    0.000062

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Dimenionles
    Organic
    Solubility
    in
    Diffuivity
    in
    Air
    Diffuzivity
    in
    He+i’y’s-baw
    Carbon
    Ofdef
    Water
    (S)
    (D1
    Geta-(I4)
    Degradation
    CAS
    No.
    Chemical
    (mg/L)
    Coefficient
    Contarit
    ee
    (Ykg)
    44)
    72
    55
    9
    4,4’
    DDE
    0.42
    0.0114
    5.87E
    6
    000.864
    1,170,000
    0000042
    50
    29
    3
    4,4’
    DDT
    002
    0.0137
    4.95E
    6
    000033.2
    2,630,000
    0.000062
    75
    99
    0
    Da1apo
    900,000
    0.0111
    946E4
    000000264
    &8
    0.005775
    5370
    3
    Dezo(aanthvaeene
    0.00249
    0.0202
    5.18E
    6
    000000040
    3-800.000
    ,00037
    96
    12
    8
    1,2
    Dibromo
    3
    4-200
    0.0212
    7.02E
    6
    0.00615
    4-2
    0.001925
    106
    93
    4
    4-2—Dib4’emeethane
    4200
    0.0287
    8.06E
    6
    0,030
    9
    0.005775
    84
    74
    2
    Di
    n
    butyl
    Phthalate
    4-4-4
    0.0138
    7.86E
    6
    000000000E
    33,900
    0.03013
    95
    50
    1
    1,2
    Dichlorobenzene
    4-56
    00690
    7.90E
    6
    0.0779
    6-1-’
    0.004-9
    106
    46
    7
    1,4-Dichlorebenzene
    73.4
    0.0690
    ?904
    0.0996
    647
    0.0019
    91
    94
    1
    3,3
    Dichlorobenzidine
    3.A4
    44-01-94
    6.74E
    6
    0,0000004-64
    724
    0.0019

    ILLiNOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Dimensionless
    Organic
    imt
    Solubility
    in
    Diffusivity
    in
    Air
    Diffusivity
    in
    Henrys
    Law
    Ca’ben
    Water
    (S)
    Water
    (D
    Constant
    (H)
    Paftii
    Degradation
    CAS
    No.
    G1emil
    (mg/L)
    Ceeffiei
    Constant
    fK)
    b4Eg)
    44)
    75
    34
    3
    1,1
    Dichioroethane
    5I060
    0.0742
    1.05E
    5
    04
    3-1-,6
    000W
    107
    06
    2
    1,2
    Dichioroethune
    520
    044
    9.90E
    6
    0.0401
    4-74
    0.0019
    75
    35
    1
    1,1
    Dichloroethylene
    2j250
    0.0900
    LO4E
    5
    4-07
    0.0053
    156
    59
    2
    Cis
    1,2
    Dichloroethylcne
    35O0
    00736
    1.13E
    5
    0467
    354
    000024
    156
    60
    5
    Trans
    1,2
    Dichloroethylene
    6300
    0.0707
    1.19E
    5
    0485
    524
    0.00021
    120
    83
    2
    2,4
    Dichlorophenol
    4400
    0.0346
    8.77E
    6
    0.00013
    4-47
    0.00027
    78
    87
    5
    1,2
    Dichloropropane
    2800
    0.0782
    8.73E
    6
    01-1-&
    434
    0.00027
    512
    75
    6
    1,3
    Dichloropropylene
    2.800
    0.0626
    1.OOE
    5
    0426
    454
    0044-
    (cis
    +
    trans)
    60
    57
    1
    Dieldrin
    0495
    0.0
    125
    4.71E
    6
    00006-l-9
    21,400
    0.00032
    81
    66
    2
    D4ethyl-Phthalate
    1-080
    0,0256
    6.3
    SE
    6
    000001-85
    25-8
    0.00619
    4-05
    67
    9
    24iethy1jefie1
    ?.8-70
    0.0584
    8,69E-4
    0.000082
    209
    0,0495
    51
    28
    5
    234-4ii#epheiel
    0.0273
    0,06E-e
    0.0000182
    004
    0.00132

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Dimensionless
    Organic
    F4rst
    Solubility
    in
    Diffusivity
    in
    Air
    Diffus+ty-m
    Henrys
    Law
    Caben
    Water
    (S)
    (Di)
    Water
    (D)
    Constant
    (H’)
    Partition
    Degadati
    CAS
    No.
    CheieaJ
    mgiL)
    (ed/s)
    (ens)
    WG)
    Ceeffcit
    Constant
    (K0)
    (Ykg)
    (44
    121
    14
    2
    2,4
    Dinirtotoluene
    270
    020
    7.06E
    6
    0.0000038
    954
    0.00192
    606
    20
    2
    2,6
    Dinitrotoluene
    1-8
    0.0327
    7.26E
    6
    0004
    692
    0.00192
    88
    85
    7
    Dinpseb
    0.0215
    6.62E
    6
    0.0000189
    -1-5-1-20
    0.002817
    117
    84
    0
    Di
    n
    octyl
    Phthalate
    002
    0.0151
    3.58E
    6
    0.00274
    83,200,000
    0.0019
    115
    297
    Endosulfan
    054
    0.0115
    4.55E
    6
    0.000459
    2440
    0.07629
    145
    73
    3
    Ess4ethal
    21,000
    00294-
    8.07E
    6
    0.0000000107
    0,29
    No
    Data
    72
    20
    8
    Endrin
    045
    0.0125
    4.74E
    6
    0.000308
    12,300
    0.00032
    100
    ‘11
    4
    Ethylbenzene
    1-69
    00750
    7.SOE
    6
    042
    0003
    206-44--0
    Fluoranthene
    0206
    0.0302
    6.35E
    6
    0.00066
    107,000
    0.000
    19
    86
    73
    7
    Fluorene
    1-9-8
    0.0363
    7.88E
    6
    0.00261
    13,800
    0,00069-1-
    76448
    Heptae1sef
    o,-i-g
    0.0112
    5.69E6
    60,7
    1,410,000
    044
    1024
    57
    3
    Heptachior
    epoxide
    02
    0.0132
    4.23E
    6
    0.00039
    83,200
    0.00063

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Dimensionless
    Organic
    Solubility
    in
    Diffusivity
    in
    Air
    Diffuswity-
    Henry’s
    Law
    afbe
    Order
    Water
    (S)
    Di)
    Water
    (D)
    Constant
    (H)
    Partition
    Degradation
    CAS
    No.
    Chemical
    (mg/L)
    (G1,1S)
    Geeffieierit
    Constant
    9o)
    Ykg
    118
    74
    1
    Hexachlorobenzene
    64
    0.0542
    5.91E
    6
    0.0541
    55,000
    0.00017
    319
    84
    6
    Alpha
    HCH
    (alpha
    BHC)
    Q
    0.0142
    7.34E
    6
    0.000435
    4-O
    0.0025
    58
    89
    9
    Gamma
    HCH
    (Lindane)
    6
    0.0
    142
    7.34E
    6
    0,000&74
    -1-070
    00029
    77
    47
    4
    Hexachlorocyclo
    1-4
    0.0161
    7.21E
    6
    4-44
    200,000
    -14
    Pcntadicnc
    67
    72
    1
    Hexachioroethane
    0.0025
    6.SOE
    6
    0459
    1-
    000W2
    193
    39
    5
    Indeno(l,2,3
    c,d)pyrene
    000002
    0.0190
    5.66E
    6
    0.0000656
    3,470,000
    7-8-59
    1
    1epherene
    12,000
    0062
    6.76E
    6
    0.000272
    464
    0.01238
    7439
    97
    6
    Mereery
    03G
    6.30E
    6
    0467-
    No
    Data
    72
    43
    5
    Methoxychior
    004
    00440
    4.46E
    6
    0000648
    97,700
    0.0019
    74
    83
    9
    Methyl
    Bromide
    15,200
    0.0728
    1.21E
    5
    0456
    4-04
    0.01824
    1634
    04
    4
    Methyl
    tertiary
    butyl
    ether
    51,000
    040
    1.IOE
    5
    0.0241
    -14-4
    No
    Data
    75
    09
    2
    Methylene
    Chloride
    13,000
    0-444-
    1.17E
    5
    00898
    4-1-4
    0044

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Dimenionlec
    Organic
    Solubility
    in
    Diffuzivity
    in
    Air
    Diffmivity
    in
    Henry’s
    Law
    Carbon
    Order
    Water
    (S)
    Water-
    Constant
    (H’)
    Paffition
    Degradation
    CAS
    No.
    Chemical
    (mg!L)
    em
    2
    ,1s
    Geef14ci
    Getai
    Eee
    YlEg
    95
    48
    7
    2
    Methylphenol
    (o
    creGofl
    24000
    0.0740
    8.30E
    6
    O0O49
    9-1-2
    0049
    91
    20
    3
    Nephtha1ee
    O059
    7.50E
    6
    00W8
    Q0Q
    0.0027
    98
    95
    3
    N4rebeefte
    0,0760
    8.60E
    6
    0000984
    64,6
    0.00
    176
    8640-6
    N
    Nitrocodiphenylamine
    354
    0.0312
    6.35E
    6
    0000205
    4-200
    0,04
    621
    61
    7
    N
    Nioodi
    n
    propylamine
    9890
    0.0515
    8.17E
    6
    0.0000923
    24,0
    0.0019
    87
    86
    5
    Pentachlorophenol
    1-950
    0.0560
    6.IOE
    6
    000004
    592
    0045
    108
    95
    2
    Phenol
    82800
    0.0820
    0,4-G&-6
    0.0000163
    284
    0,099
    1918
    02
    1
    Picloram
    420
    0.0255
    5.28E
    6
    0.00000000166
    -148
    No
    Data
    1336
    36
    3
    Polychlorinatedbiphenyls
    04
    a
    309009
    Ne-Data
    (PC&)
    129
    00
    0
    Pyreee
    0436
    0.0272
    7.24E
    6
    0.000151
    105,000
    0,000-1-8
    122
    31
    9
    Simazine
    S
    0,02-7
    7.36E
    6
    0.0000000133
    1-33-
    No
    Data
    100
    42
    5
    Styreae
    3-1-0
    0.0710
    8.OOE
    6
    044
    0.0033

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Q
    First
    Solubillty-ifi
    Diffuivity
    in
    Air
    Diffusivity
    in
    Heny!baw
    Ordef
    Water
    (S)
    Water
    (D)
    Constant
    (H)
    Partition
    Degradation
    CAS
    No.
    Chemical
    (mg/L)
    (e/s
    eeff1€ie+
    oa+t
    K
    0
    b4Egi
    44
    93
    72
    1
    2,4,5
    TP
    (Silvex)
    3-1-
    0.0191
    5.83E
    6
    0000003-a
    5-440
    No
    Data
    127
    18
    4
    Teftachioroethylene
    200
    0-0720
    8.20E
    6
    4-54-
    0-430096
    4-0848-3-
    Pekiefte
    4-26
    0.0
    870
    8.60E
    6
    0472
    4-82
    0-0-14
    8001
    35
    2
    Toxaphene
    04
    0-0-1-1-6
    4.34E
    6
    0-000246
    257,000
    No
    Data
    120
    82
    1
    1,2,4
    Trichlorobenzene
    300
    0.0300
    8.23E
    6
    0-0582
    1-3-7-80
    0.0019
    71
    55
    6
    1,1,1
    Trichloroethane
    4-33-o
    0.0780
    40E-6
    005
    1-1-0
    0.0013
    79005
    4--l
    ,2-Thchloreethane
    4420
    0.0780
    8-80E-6
    44-0374
    4-04
    0-00094-
    79
    0-1—6
    Th1ereethylee
    4-3-1-00
    0.0790
    9.1
    OE
    6
    0-422
    4-66
    0.00012
    95—95-4
    2,4,5
    Trichlorophenol
    45200
    0-0201-
    7.03E
    6
    0.000178
    4600
    0.00038
    8-8-064
    2,4,6
    Trichlorophenol
    8430
    0.0318
    6.25E
    6
    0-00034-9
    3-84
    0,00038
    108054
    Vinyl
    Acetate
    20,000
    0.0850
    9.20E
    6
    0-4324-
    544-
    No
    Data
    57
    01
    4
    Vinyl
    Chloride
    2?60
    04-06
    1.23E
    6
    -1-44
    1-8-6
    000024
    108383
    mXylene
    4-64
    0-0-743
    7.80E6
    0404-
    403
    0.0019

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Dimensionless
    Ofgaie
    Solubility
    in
    Diffusivity
    in
    Air
    Diffusivity
    in
    Henrys
    Law
    Carbon
    Ofdef
    Watef-(S)
    (Di)
    Watei-(D)
    1afttion
    Degradation
    CAS
    No.
    Che+iiieal
    (mg/L)
    (ems)
    (€is)
    Coefficient
    Constant
    EKOC)
    E)
    (b44g)
    (44)
    95
    47
    6
    o-Xy1e*e
    47g
    1
    .00E
    5
    O,24-
    106
    ‘12
    3
    p
    Xylene
    4-8
    0.0769
    8ME
    6
    0344
    0.0019
    1330
    20
    7
    Xy1eiies-(eta1)
    1-ge
    0.0720
    9.34E
    6
    04&
    260
    0.0019
    Chemical
    Abstracts
    Service
    (CAS)
    registry
    number.
    This
    number
    in
    the
    foat
    xxx
    xx
    x,
    is
    unique
    for
    each
    chemical
    and
    allows
    efficient
    searching
    on
    computerized
    data
    bases.
    Soi1
    Remediation
    objectives
    are
    deteined
    oursuant
    AO
    CD
    71
    as
    incomorated
    P72’)
    10,1
    (+T,.
    T
    TPD
    A
    “DflD
    Spill
    Cleanup
    D,-1
    ,‘
    f
    ,,,,
    ,.+,,-..
    (Source:
    Amended
    at
    ,..-..-.,,,1÷.4÷1,
    t?(T
    .-.;i
    ‘.“,
    1
    Ill.
    Reg.
    effective

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Dimensionless
    Dimensionless
    Organic
    Carbon
    ftt
    Yppi
    Solubility
    in
    Diffusivity
    Diffusivity
    in
    Henry’s
    Law
    Henry’s
    Law
    Partition
    Order
    Pressure
    Water
    (S)
    in
    Air
    (Di)
    Water
    Constant
    (H’)
    Constant
    (H’)
    Coefficient
    Degradation
    CAS
    No.
    Chemical
    (mgIL)
    (cm2/s)
    (cm2ls)
    (25°C)
    (13°C)
    Constant
    n1’l1
    LI
    L2
    For
    the
    indoor
    inhalation
    exposure
    route
    Neutral
    Organics
    83-32-9
    Acenaphthene
    3.60E+00
    4.76E-02
    7.69E-06
    6.60E-03
    b
    6.30E+03
    3.40E-03
    2.50E03
    67-64-1
    Acetone
    1.OOE+06
    l.24E-01
    l.14E-05
    1.60E-03
    9.73E-04
    7.80E-01
    4.95E-02
    2.30E+02
    15972-60-8
    Alachlor
    2.40E+02
    2.l3E-02
    5.28E-06
    3.40E-06
    b
    3.20E+03
    No
    Data
    2.20E-05
    116-06-3
    Aldicarb
    6.03E+03
    3.18E-02
    7.24E-06
    5.90E-08
    b
    l.29E+01
    l.09E-03
    3.47E-05
    309-00-2
    Aldrin
    1.70E-02
    l.96E-02
    4.86E-06
    7.OOE-03
    b
    2.50E+05
    5.90E-04
    6.OOE-06
    120-12-7
    Anthracene
    4.30E-02
    3.85E-02
    7.74E-06
    2.70E-03
    b
    2.50E+04
    7.50E-04
    2.70E-06
    1912-24-9
    Atrazine
    7.OOE+01
    2.59E-02
    6.67E-06
    9.68E-08
    b
    3.63E+02
    No
    Data
    2.70E-07
    71-43-2
    Benzene
    1.80E+03
    8.80E-02
    l.02E-05
    2.30E-01
    l.34B-01
    5.OOE+01
    9.OOE-04
    9.50E+01
    56-55-3
    Benzo(a)anthracene
    9.40E-03
    5.IOE-02
    9.00E-06
    l.39E-04
    b
    4.OOE+05
    5.10E-04
    l.lOE-07
    205-99-2
    Benzo(b)fluoranthene
    1.50E-03
    2.23E-02
    5.56E-06
    4.55E-03
    b
    l.05E+06
    5.70E-04
    5.OOE-07
    207-08-9
    Benzo(k)fluoranthene
    8.OOE-04
    2.23E-02
    5.56E-06
    3.40E-05
    b
    1.OOE+06
    l.60E-04
    2.OOE-09
    65-85-0
    Benzoic
    Acid
    3.40E+03
    7.02E-02
    7.97E-06
    l.56E-06
    b
    1.21E+OOd
    No
    Data
    7.OOE-04

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Dimensionless
    Dimensionless
    Organic
    Carbon
    t
    Solubility
    in
    Diffusivity
    Diffusivity
    in
    Henry’s
    Law
    Henry’s
    Law
    Partition
    Order
    Pressure
    Water
    (S)
    in
    Air
    (Di)
    Water
    (D)
    Constant
    (H)
    Constant
    (H’)
    Coefficient
    Degradation
    CAS
    No.
    Chemical
    (mgIL)
    (cm2/s)
    (cm2/s)
    (25°C)
    (13°C)
    (LC)
    Constant
    (mn/Hg)
    tiLkg
    For
    the
    indoor
    inhalation
    exposure
    route
    50-32-8
    Benzo(a)pyrene
    1.60E-03
    4.30E-02
    9.49E-06
    4.50E-05
    b
    7.90E+05
    6.50E-04
    5.50E-09
    111-44-4
    Bis(2-chloroethyl)ether
    1.72E+04
    4.13E-02
    7.53E-06
    7.40E-04
    2.94E-04
    1.26E+01
    1.90E-03
    1.55E+00
    117-81-7
    Bis(2-ethylhexyl)phthalate
    3.40E-01
    3.51
    E-02
    3.66E-06
    4.1
    OE-06
    b
    1
    .00E+05
    I
    .80E-03
    6.80E-08
    75-27-4
    Bromodichioromethane
    6.70E+03
    5.61E-02
    1.06E-05
    6.60E-02
    3.71E-02
    5.OOE+01
    No
    Data
    5.OOE+01
    75-25-2
    Bromoform
    3.IOE+03
    1.49E-02
    l.03E-05
    2.l9E-02
    1.06E-02
    9.12E+0l
    1.90E-03
    5.51E+00
    71-36-3
    Butanol
    7.40E+04
    8.OOE-02
    9.30E-06
    3.61E-04
    1.55E-04
    6.OOB+00
    1.28E-02
    7.OOE+00
    78-93-3
    2-Butanone
    (MEK)
    2.20E+05
    8.08E-02
    9.8E-06
    2.30E-03
    1.32E-03
    2.OOE+00
    4.95E-02
    9.50E+0I
    85-68-7
    ButylBenzylPhthalate
    2.70E+00
    1.99E-02
    4.89E-06
    5.30E-05
    b
    6.30E±04
    3.85E-03
    8.30E-06
    86-74-8
    Carbazole
    1.20E+00
    4.17E-02
    7.45E-06
    3.60E-06
    b
    4.OOE+03
    No
    Data
    7.OOE-04
    1563-66-2
    Carbofuran
    3.20E+02
    2.37E-02
    5.95E-06
    1.27E-07
    b
    1.91E+02
    No
    Data
    4.85E-06
    75-15-0
    Carbon
    Disulfide
    1.20E+03
    1.04E-01
    1.OOE-05
    1.23E+00
    8.06E-01
    6.30E+01
    No
    Data
    3,60E+02
    56-23-5
    Carbon
    Tetrachloride
    7.90E+02
    7.80E-02
    8.80E-06
    1.23E+00
    7.48E-01
    2.OOE+02
    I.90E-03
    1.20E+02
    57-74-9
    Chlordane
    5.60E-02
    1.79E-02
    4.37E-06
    2.OOE-03
    b
    2.50E+05
    2.50E-04
    9.80E-06

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Dimensionless
    Dimensionless
    Organic
    Carbon
    First
    Solubility
    in
    Diffusivity
    Difflisivity
    in
    Henry’s
    Law
    Henry’s
    Law
    Partition
    Order
    Pressure
    Water
    (S)
    in
    Air
    (Di)
    Water
    (D
    Constant
    (H’)
    Constant
    (H’)
    Coefficient
    Degradation
    CAS
    No.
    Chemical
    (mg/L)
    (cm2ls)
    (cm2/s)
    (25°C)
    (13°C)
    Constant
    (L
    For
    the
    indoor
    inhalation
    exposure
    route
    106-47-8
    p-Chloroaniline
    5.30E+03
    6.99E-02
    1.OIE-05
    4.76E-05
    b
    6.31E+0l
    No
    Data
    1.23E-02
    108-90-7
    Chlorobenzene
    4.70E+02
    7.30E-02
    8.70E-06
    1.50E-01
    7.93E-02
    2.OOE+02
    2.30E-03
    1.20E+01
    124-48-1
    Chiorodibromomethane
    2.60E+03
    3.66E-02
    L05E-05
    3.20E-02
    2.07E-02
    6.92E+0l
    3.85E-03
    4.90E+00
    67-66-3
    Chloroform
    7.90E+03
    1.04E-Ol
    l.OOE-05
    l.50E-0l
    9.18E-02
    5.OOE+01
    3.90E-04
    2.OOE-1-02
    95-57-8
    2-Chiorophenol
    2.20E+05
    6.61E-02
    9.46E-06
    1.60E-02
    7.28E-03
    5.93E+Old
    No
    Data
    2.34E+00
    218-01-9
    Chrysene
    6.30E-03
    2.44E-02
    6.21E-06
    3.90E-03
    b
    4.OOE+05
    3.50E04
    6.20E09
    94-75-7
    6.77E+02
    5.88E-02
    6.49E-06
    4.18E-07
    b
    5.75E+02
    3.85E-03
    6.OOE-07
    72-54-8
    4,4’-DDD
    9.OOE-02
    2.27E-02
    5.79E-06
    l.60E-04
    b
    7.90E+05
    6.20E-05
    6.70E-07
    72-55-9
    4,4-DDE
    l.20E-01
    2.38E-02
    5.87E-06
    8.60E-04
    b
    4.OOE+05
    6.20E-05
    6.OOE-06
    50-29-3
    4,4’-DDT
    2.50E-02
    1.99E-02
    4.95E-06
    3.30E-04
    b
    2.OOE+06
    6.20E-05
    1.60E-07
    75-99-0
    Dalapon
    9.OOE+05
    6.08E-02
    9.45E-06
    2.64E-06
    4.80E+00
    5.78E-03
    l.90E-01
    53-70-3
    Dibenzo(a,h)anthracene
    2.50E-03
    2.1
    lE-02
    5.24E-06
    6.lOE-07
    b
    2.50E+06
    3.70E-04
    1.OOE-10
    96-12-8
    1,2-Dibromo-3-
    1.20E+03
    2.68E-02
    7.02E-06
    6.20E03c
    NA
    7.90E+0l
    l.93E-03
    5.80E-0l
    chioropropane

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Dimensionless
    Dimensionless
    Organic
    Carbon
    First
    Solubility
    in
    Diffusivity
    Diffusivity
    in
    Henry’s
    Law
    Henry’s
    Law
    Partition
    Qr
    Pressure
    Water
    (S)
    in
    Air
    (Di)
    Water
    (D
    Constant
    (H’)
    Constant
    (H’)
    Coefficient
    Degradation
    CAS
    No.
    Chemical
    (mgIL)
    (cm2/s)
    (cm2/s)
    (25°C)
    (13°C)
    Constant
    For
    the
    indoor
    inhalation
    exposure
    route
    106-93-4
    1,2-Dibromoethane
    4.OOE+03
    4.37E-02
    8.44E-06
    3.OOE-02
    l.54E-02
    5.OOE+0l
    5.78E-03
    l.30E+0l
    84-74-2
    Di-n-butyl
    Phthalate
    l.IOE+0l
    4.38E-02
    7.86E-06
    7.40E-05
    b
    4.00E+04
    3.O1E-02
    7.30E-05
    1918-00-9
    Dicamba
    4.50E+03
    2.37E-02
    5.95E-06
    2.18E-09
    b
    2.95E+00
    No
    Data
    3.38E-05
    95-50-1
    l,2-Dichlorobenzene
    l.56E+02
    6.90E-02
    7.90F-06
    7.79E-02
    3.56E-02
    5.75E+02
    1.90E-03
    l.36E+00
    106-46-7
    1,4-Dichlorobenzene
    7.90E+0l
    6.90E-02
    7.90E-06
    9.80E-02
    4.69E-02
    7.90E+02
    l.90E-03
    1.OOE+00
    91-94-1
    3,3-Dichlorobenzidine
    3.IOE+00
    2.59E-02
    6.74E-06
    l.60E-07
    b
    2.82E+03
    l.90F-03
    3.71E-08
    75-71-8
    Dichlorodifluoromethane
    2.80E+02
    7.60E-02
    l.08E-05
    l.41E+01
    8.14E+00
    6.17E+0l
    l.92E-03
    4.85E+03
    75-34-3
    1,1-Dichioroethane
    5.1OE+03
    7.42E-02
    LOSE-OS
    2.30E-01
    1.42E-0l
    3.20E+0l
    1.90E-03
    2.30E+02
    107-06-2
    1,2-Dichioroethane
    8.50E+03
    1.04E-02
    9.90E-06
    4.OOE-02
    2.29E-02
    2.OOE+01
    1.90E-03
    7.90E+0l
    75-35-4
    1,1
    -Dichloroethylene
    2.30E+03
    9.OOE-02
    1
    .04E-05
    1.1
    OE+00
    7.1
    OE-0
    I
    5.OOE+0i
    5.30E-03
    6.OOE+02
    156-59-2
    Cis-1,2-Dichloroethylene
    3.50E+03
    8.86E-02
    1.13E-05
    1.70E-01
    1.OOE-01
    4.OOE+01
    2.40E-04
    2.OOE+02
    156-60-5
    Trans-i
    ,2-Dichloroethylene
    6.30E+03
    7.03E-02
    1.1
    9E-05
    3
    .90E-0
    I
    2.43E-0
    I
    5.OOE+0
    I
    2.40E-04
    3
    .30E+02
    120-83-2
    2.4-Dichlorophenol
    4.50E+03
    4.89E-02
    8.77E-06
    1.30E-04
    b
    7.32E+02d
    2.70E-04
    6.70F-02

    ILLiNOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Dimensionless
    Dimensionless
    Organic
    Carbon
    First
    Solubility
    in
    Diffusivity
    Diffusivity
    in
    Henry’s
    Law
    Henry’s
    Law
    Partition
    Order
    Pressure
    Water
    (S)
    in
    Air
    (Di)
    Water
    (D
    Constant
    (H’)
    Constant
    (H)
    Coefficient
    Degradation
    ‘mm/H
    CAS
    No.
    Chemical
    (mg/L)
    (cm
    2/s)
    (cm
    2/s)
    (25°C)
    (13°C)
    OC
    Constant
    g
    ULk
    For
    the
    indoor
    inhalation
    exposure_route
    78-87-5
    1.2-Dichioropropane
    2.80E+03
    7.82E-02
    8.73E-06
    l.IOE-0l
    6.52E-02
    5.OOE+0l
    2.70E-04
    5.20E+Ol
    542-75-6
    1,3-Dichloropropylene
    2.80E+03
    6.26E-02
    l.OOE-05
    7.40E-0l
    3.98E-01
    2.OOE+01
    6.IOE-02
    3.40E+0l
    (cis+trans)
    60-57-I
    Dieldrin
    2.OOE-0l
    1.92E-02
    4.74E-06
    6.2E-04
    b
    2.50E+04
    3.20F.-04
    5.9E-06
    84-66-2
    Diethyl
    Phthalate
    l.10E+03
    2.49E-02
    6.35E-06
    I.80E-05
    b
    3.20E+02
    6.19E-03
    1.60E-03
    105-67-9
    2,4-Dimethyiphenol
    7.90E+03
    6.43E-02
    8.69E-06
    8.20E-05
    b
    2.OOE+02
    4.95E-02
    9.80E-02
    75-71-8
    1,3-Dinitrobenzene
    8.60E+02
    4.55E-02
    8.46E-06
    2.30E-07
    b
    3.20E+01
    l.92E-03
    9.OOE-04
    51-28-5
    2,4-Dinitrophenol
    2.79E+03
    2.73E-02
    9.06E-06
    1.82E-05
    b
    3.24E+0l
    l.32E-03
    5.1OE-03
    121-14-2
    2,4-Dinitrotoluene
    2.70E+02
    2.03E-0l
    7.06E-06
    3.80E-06
    b
    8.90E+01
    1.92E-03
    l.47E-04
    606-20-2
    2,6-Dinitrotoluene
    1.82E+02
    3.70E-02
    7.76E-06
    3.06E-05
    b
    4.90E+0l
    l.92E-03
    5.67E-04
    88-85-7
    Dinoseb
    5.20E+01
    2.45E-02
    6.25E-06
    I.87E-05
    b
    9.17E+0l’
    2.82E-03
    7.50E-05
    117-84-0
    Di-n-octyl
    Phthalate
    2.OOE-02
    1.73E-02
    4.17E-06
    2.74E-03
    b
    l.30E+05
    1.90E-03
    2.60E-06
    123-91-1
    p-Dioxane
    1.OOE+06
    2.29E-01
    1.02E-05
    1.97E-04
    1.07E-04
    7.20E-01
    l.92E-03
    3.81E+01
    115-29-7
    Endosulfan
    5.1OE-01
    1.85E-02
    4.55E-06
    4.51E-04
    b
    5.OOE+03
    7.63E-02
    1.OOE-05

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARI
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Dimensionless
    Dimensionless
    Organic
    Carbon
    First
    Solubility
    in
    Diffusivity
    Diffusivity
    in
    Henry’s
    Law
    Henry’s
    Law
    Partition
    Order
    Pressure
    Water
    (S)
    in
    Air
    (Di)
    Water
    (D)
    Constant
    (H’)
    Constant
    (H’)
    Coefficient
    Degradation
    CAS
    No.
    Chemical
    (mg/L)
    (cm2/s)
    (cm2/s)
    (25°C)
    (13°C)
    KOCJ
    Constant
    (L
    For
    the
    indoor
    inhalation
    exposure
    route
    145-73-3
    Endothall
    2.lOE+04
    2.91E-02
    8.07E-06
    l.58E-14
    b
    7.59E+0l
    No
    Data
    l.57E-l0
    72-20-8
    Endrin
    2.50E-01
    l.92E-02
    4.74E-6
    3.08E-04
    b
    3.20E+04
    3.20E-04
    3.OOE-06
    100-41-4
    Ethylbenzene
    l.70E+02
    7.50E-02
    7.80E-06
    3.24E-0l
    1.64E-01
    3.20E+02
    3.00E-03
    9.60E+00
    206-44-0
    Fluoranthene
    2.06E-0l
    2.51E-02
    6.35E-06
    6.60E-04
    b
    7.40E+04
    l.90E-04
    l.23E-08
    86-73-7
    Fluorene
    2.OOE+00
    4.40E-02
    7.88E-06
    2.62E-03
    b
    l.30E+04
    6.91E-04
    6.30E-04
    76-44-8
    Heptachlor
    l.80E-01
    2.23E-02
    5.69E-06
    6.07E-02
    l.73E-02
    3.OOE+03
    l,30E-0l
    4.OOE-04
    1024-57-3
    Heptachlor
    epoxide
    2.OOE-01
    2.19E-02
    5.57E-06
    3.90E-04
    2.OOE+05
    6.30E-04
    1.90E-05
    118-74-1
    Hexachlorobenzene
    6.20E-03
    5
    .42E-02
    5.91
    E-06
    5
    .33E-02
    1
    .35E-02
    2.OOE+04
    I
    .70E-04
    1.
    80E-05
    3
    19-84-6
    Alpha-HCH
    (alpha-BHC)
    2.OOE+00
    2.04E-02
    5.04E-06
    4.51E-04
    b
    5.OOE+03
    2.50E-03
    4.50E-05
    58-89-9
    Gamma-HCH
    (Lindane)
    7.30E+00
    2.75E-02
    7.34E-06
    5.74E-04
    b
    3.OOE+03
    2.90E-03
    4.IOE-04
    2691-41-0
    HMX
    5.OOE+00
    2.69E-02
    7.15E-06
    8.67E-10
    3.55E-08
    l.40E+00
    No
    Data
    3.30E-l4
    77-47-4
    Hexachlorocyclo-
    l.80E-i-00
    2.79E-02
    7.21E-06
    1.1
    IE+00
    4.22E-01
    l.20E+04
    1.20E-02
    5.96E-02
    Pentadiene
    67-72-I
    Hexachloroethane
    5.OOE+0l
    2.50E-03
    6.80E-06
    1.59E-01
    7.26E-02
    1.50E+03
    1.92E-03
    2.IOE-01

    ILLiNOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Dimensionless
    Dimensionless
    Organic
    Carbon
    First
    Solubility
    in
    Diffusivity
    Diffusivity
    in
    Henrys
    Law
    Henrys
    Law
    Partition
    Order
    Pressure
    Water
    (S)
    in
    Air
    (Di)
    Water
    (D
    Constant
    (H)
    Constant
    (H’)
    Coefficient
    Degradation
    CAS
    No.
    Chemical
    (mgIL)
    (cm2/s)
    (cm2/s)
    (25°C)
    (13°C)
    Constant
    (mr’Hg)
    (L
    For
    the
    indoor
    Lct
    inhalation
    exposure
    route
    193-39-5
    Indeno(1,2,3-c,d)pyrene
    2.20E-05
    2.25E-02
    5.66E-06
    6.5611-05
    b
    3.1OE+06
    4.7011-04
    1.OOE-10
    78-59-1
    Isophorone
    1.2011+04
    6.2311-02
    6.7611-06
    2.72E-04
    l.12E-04
    2.50E+01
    1.2411-02
    4.3811-01
    98-82-8
    Isopropylbenzene
    6.lOE+01
    6.50E-02
    7.1OE-06
    4.92E+01
    2.IOE+01
    1.0211+03
    4.3311-02
    4.50E+00
    (Cumene)
    93-65-2
    MCPP
    (Mecoprop)
    8.95E+02
    2.40E-02
    6.05E-06
    7.7011-09
    b
    l.
    84E+Old
    3.8511-03
    2.44E-05
    7439-97-6
    Mercury
    6.OOE-02
    7.l4E-02
    3.0111-05
    4.51E-01
    1.5911-01
    8.70E+03
    No
    Data
    2.OOE-03
    72-43-5
    Methoxychlor
    4.50E-02
    1.84E-02
    4.46E-06
    6.56E-04
    5.0011+04
    1.9011-03
    6.00E-07
    74-83-9
    Methyl
    Bromide
    l.50E+04
    7.2811-02
    l.21E-05
    2.5611-01
    1.7911-01
    1.0011+01
    1.82E-02
    1.62E+03
    1634-04-4
    Methyl
    tertiary-butyl
    ether
    5.IOE+04
    8.59E-01
    1.1011-05
    2.4211-02
    1.50E-02
    1.0011+01
    1.93E-03
    2.50E+02
    75-09-2
    Methylene
    Chloride
    1.3011+04
    1.0111-01
    1.17E-05
    9.02E-02
    5.70E-02
    1.30E+01
    1.20E-02
    4.30E+02
    93-65-2
    2-Methylnaphthalene
    2.50E+01
    5.2211-02
    7.75E-06
    2.1OE-02
    6.95E-03
    1.60E+03
    No
    Data
    6.80E-02
    95-48-7
    2-Methyiphenol
    (o-cresol)
    2.6011+04
    7.40E-02
    8.30E-06
    4.9211-05
    2.OOE-05
    4.20E+Ol
    4.9511-02
    2.9911-01
    91-20-3
    Naphthalene
    3.IOE+01
    5.90E-02
    7.50E-06
    1.9711-02
    8.2911-03
    5.0011+02
    2.70E-03
    8.50E-02
    98-95-3
    Nitrobenzene
    2.09E+03
    7.60E-02
    8.60E-06
    9.8411-04
    3.99E-04
    4.00E+Ol
    1.76E-03
    2.40E-01

    ILLiNOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Dimensionless
    Dimensionless
    Organic
    Carbon
    ji:st
    Solubility
    in
    Diffusivity
    Diffusivity
    in
    Henrys
    Law
    Henrys
    Law
    Partition
    Order
    Pressure
    Water
    (S)
    in
    Air
    (Di)
    Water
    (D
    Constant
    (H)
    Constant
    (H)
    Coefficient
    Degradation
    CAS
    No.
    Chemical
    (mg/L)
    (cm2/s)
    (cm2/s)
    (25°C)
    (13°C)
    Constant
    (mm/Hg)
    (L
    For
    the
    indoor
    inhalation
    exposure
    route
    86-30-6
    N-Nitrosodiphenylamine
    3.50E+0l
    2.83E-02
    7.l9E-06
    2.IOE-04
    b
    1.OOE+03
    l.OOE-02
    6.70E-04
    621-64-7
    N-Nitrosodi-n-propylamine
    9.89E+03
    5.87E-02
    8.17E-06
    9.20E-05
    5.48E-05
    l.45E+0l
    l.90E-03
    1.30E-Ol
    87-86-5
    Pentachlorophenol
    2.OOE+03
    5.60E-02
    6.1OE-06
    9.84E-07
    b
    2.77E+03d
    4.50E-04
    3.20E-05
    108-95-2
    Phenol
    8.30E+04
    8.20E-02
    9.1OE-06
    l.64E-05
    6.67E-06
    2.OOE+O1
    9.90E-02
    280E-0l
    1918-02-1
    Picloram
    4.30E+02
    2.26E-02
    5.64E-06
    2.19E-12
    2.00E+00
    No
    Data
    7.21E-11
    1336-36-3
    Polychiorinated
    biphenyls
    a
    a
    a
    a
    b
    a
    a
    a
    (PCBs)
    129-00-0
    Pyrene
    1.40E+00
    2.77E-02
    7.24E-06
    4.51E-04
    b
    6.3lE+04
    l.80E-04
    4.60E-06
    121-82-4
    RDX
    5.97E+01
    3.llE-02
    8.49E-06
    2.OIE-11
    b
    7.20E+00
    No
    Data
    4.IOE-09
    122-34-9
    Simazine
    6.20E+00
    2.48E-02
    6.28E-06
    3.80E-08
    b
    l.32E+02
    No
    Data
    2.21E-08
    100-42-5
    Styrene
    3.lOE+02
    7.IOE-02
    8.OOE-06
    1.1IE-01
    5.48E-03
    3.16E+02
    3.30E03
    6.1OE+00
    93-72-1
    2,4,5-TP(Silvex)
    7.IOE+01
    2.30E-02
    5.83E-06
    3.71E-07
    13
    5.50E+03
    No
    Data
    9.97E-06
    127-18-4
    Tetrachloroethylene
    2.OOE+02
    7.20E-02
    8.20E-06
    7.38E-0l
    4.OOE-Ol
    6.3lE+02
    9.60E-04
    1.90F+Ol
    108-88-3
    Toluene
    5.30E+02
    8.70E-02
    8.60E-06
    2.7lE-0l
    1.49E-01
    1.58E+02
    1.IOE-02
    2.80E+01

    ILLiNOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Dimensionless
    Dimensionless
    Organic
    Carbon
    First
    Solubility
    in
    Diffusivity
    Diffisivity
    in
    Henry’s
    Law
    Henrys
    Law
    Partition
    Order
    Pressure
    Water
    (S’)
    in
    Air
    (Di)
    Water
    (D
    Constant
    (H’)
    Constant
    (H’)
    Coefficient
    Degradation
    CAS
    No.
    Chemical
    (mg/L)
    (cm
    2/s)
    (cm
    2/s)
    (25°C)
    (13°C)
    Constant
    (mm/Hg)
    Lkg)
    For
    the
    indoor
    inhalation
    ,
    exposure
    route
    8001-35-2
    Toxaphene
    7.40E-01
    2.16E-02
    5.51E-06
    2.46E-04
    b
    5.O1E+04
    No
    Data
    9.80E-07
    120-82-1
    1
    ,2,4-Trichlorobenzene
    3
    .50E+0
    1
    3
    .00E-02
    8.23E-06
    5
    .74E-02
    2.38E-02
    1
    .58E+03
    I
    .90E-03
    4.30E-0
    I
    71-55-6
    1,1,1-Trichioroethane
    1.30E+03
    7.80E-02
    8.80E-06
    6.97E-01
    4.21E-01
    1.26E+02
    1.30E-03
    1.20E+02
    79-00-5
    1,1,2-Trichloroethane
    4.40E+03
    7.80E-02
    8.80E-06
    3.73E-02
    1.98E-02
    5.OIE+01
    9.50E-04
    2.30E+01
    79-01-6
    Trichioroethylene
    l.50E+03
    7.90E-02
    9.1OE-06
    4.1OE-01
    2.41E-01
    1.OOE+02
    4.20E-04
    7.30E+01
    75-69-4
    Trichlorofluoromethane
    1.1OE+03
    8.70E-02
    9.70E-06
    9.70E-02
    3.98E+00
    1.30E+02
    9.63E-04
    2000
    95-95-4
    2,4,5-Trichiorophenol
    8.00E+02
    2.9IE-02
    7.03E-06
    3.53E-04
    b
    2.68E+03d
    3.80E-04
    2.40E-02
    88-06-2
    2,4,6-Trichiorophenol
    l.20E+03
    2.61E-02
    6.36E-06
    1.78E-04
    b
    8.78E+02’
    3.80E-04
    2.OOE-02
    108-05-4
    Vinyl
    Acetate
    2.OOE+04
    8.50E-02
    9.20E-06
    2.09E-02
    l.l8E-02
    4.57E+00
    No
    Data
    9.OOE+01
    99-35-4
    1,3,5-Trinitrobenzene
    2.80E+02
    2.41E-02
    6.08E-06
    3.30E-10
    b
    1.60E+0I
    No
    Data
    6.40E-06
    118-96-7
    2,4,6-Trinitrotoluene
    l.24E+02
    2.94E-02
    7.90E-06
    4.87E-09
    b
    3.72E+01
    l.92E-03
    2.02E-06
    57-01-4
    Vinyl
    Chloride
    8.80E+03
    1.06E-Ol
    1.23E-06
    1.1IE+00
    8.14E-0l
    1.58E+0l
    2.40E-04
    3.OOE-t03
    108-38-3
    m-Xylene
    l.60E+02
    7.OOE-02
    7.80E-06
    2.99E-0l
    I.52E-0l
    3.98E+02
    l.90E-03
    8.50E+00

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Dimensionless
    Dimensionless
    Organic
    Carbon
    jt
    Solubility
    in
    Diffusivity
    Diffusivity
    in
    Henrys
    Law
    Henry’s
    Law
    Partition
    Order
    Pressure
    Water
    (S)
    in
    Air
    (Di)
    Water
    (DW
    Constant
    (H’)
    Constant
    (H’)
    Coefficient
    Degradation
    CAS
    No.
    Chemical
    (mgIL)
    (cm2/s)
    (cm2/s
    (25°C)
    (13°C)
    Constant
    (mm/Hg)
    LiLk)
    For
    the
    indoor
    inhalation
    exposure
    route
    95-47-6
    o-Xylene
    l.80E+02
    8.70E-02
    l.OOE-05
    2.13E-0l
    l.07E-0l
    3.l6E+02
    l.90E-03
    6.60E+00
    106-42-3
    p-Xylene
    l.60E+02
    7.69E-02
    8.44E-06
    3.l6E-01
    l.59E-01
    3.16E+02
    l.90E-03
    8.90E+00
    1330-20-7
    Xylenes
    (total)
    1.lOE+02
    7.35E-02
    9.23E-06
    2.71E-01
    NA
    3.98E+02
    1.90E-03
    8.OOE+00
    Chemical
    Abstracts
    Service
    (CAS)
    registry
    number.
    This
    number
    in
    the
    format
    xxx-xx-x,
    is
    unique
    for
    each
    chemical
    and
    allows
    efficient
    searching
    on
    computerized
    data
    bases.
    a
    Soil
    Remediation
    objectives
    are
    determined
    pursuant
    to
    40
    CFR
    761,
    as
    incorporated
    by
    reference
    at
    Section
    732.104
    (the
    USEPA
    ‘PCB
    Spill
    Cleanup
    Policy”.
    for
    most
    sites;
    persons
    remediating
    sites
    should
    consult
    with
    BOL
    if
    calculation
    of
    Tier
    2
    soil
    remediation
    obiectives
    is
    desired.
    b
    Dimensionless
    Henry’s
    Law
    Constant
    at
    13°C
    is
    not
    calculated
    because
    the
    chemical
    is
    not
    volatile
    and
    does
    not
    require
    evaluation
    under
    the
    indoor
    inhalation
    exposure
    route.
    °
    Dimensionless
    Henry’s
    Law
    Constant
    =
    20°C
    d
    These
    chemicals
    are
    ionizing
    and
    its
    Kc,.
    value
    will
    change
    with
    pH.
    The
    K3,.
    values
    listed
    in
    this
    table
    is
    the
    effective
    K,,.
    at
    pH
    of
    6.8.
    If
    the
    site-specific
    pH
    is
    values
    other
    than
    6.8,
    the
    K0.
    value
    listed
    in
    Section
    742.
    Appendix
    C,
    Table
    I
    should
    be
    used.
    (Source:
    Added
    at
    Ill.
    Reg.
    effective

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF PROPOSED
    AMENDMENTS
    Section
    742.APPENDIX
    C: Tier
    2
    Illustrations
    and Tables
    Section
    742.Table
    F: Methods
    for Determining
    Physical
    Soil Parameters
    Methods
    for
    Determining
    Physical
    Soil
    Parameters
    Parameter
    Sampling
    Locationa
    Method
    ASTM
    - D
    1556-90
    Sand
    Cone
    Methodb
    Pb
    (soil
    bulk
    density)
    Surface
    ASTM
    - D
    2167-94
    Rubber
    Balloon
    Methodb
    ASTM
    - D
    2922-9 1
    Nuclear
    Method’
    Subsurface
    ASTM
    - D
    2937-94
    Drive
    Cylinder
    Method’
    Ps
    (soil
    particle
    density)
    Surface
    or Subsurface
    ASTM
    - D
    854-92
    Specific
    Gravity
    of Soil’
    w (moisture
    content)
    Surface
    or Subsurface
    ASTM
    - D 4959-89
    (Reapproved
    1994)
    Standardb
    ASTM
    - D
    4643
    -93
    Microwave
    Oven’
    ASTM
    - D2216-92
    Laboratory
    Determination’
    ASTM
    -
    D3017-88
    (Reapproved
    1993)
    Nuclear
    Methodb
    Equivalent
    USEPA
    Method
    (e.g.,
    sample
    preparation
    procedures
    described
    in
    methods
    3541
    or
    3550)
    ASTM
    - D 2974-00
    f
    0
    (fraction
    organic
    carbon
    Surface
    or Subsurface
    content)
    Moisture,
    Ash,
    and
    Organic
    Matter
    t
    appropriately
    adjusted
    to
    estimate
    the
    fraction
    of
    organic
    carbon
    as stated
    in Nelson
    and
    Sommers
    (1982)

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Methods
    for Determining
    Physical
    Soil
    Parameters
    Parameter
    Sampling
    Locationa
    Method
    r or
    °T
    (total
    soil
    .
    porosity)
    Surface
    or Subsurface
    Equation
    S24 in Appendix
    C
    Table
    A for
    SSL
    Model
    or
    (calculated)
    Equation
    R23 in
    Appendix
    C,
    Table
    C
    for
    RBCA
    Model,
    or
    Equation
    J&E 16
    in Appendj
    Table
    L
    for J&E
    Model
    9a
    or
    °as
    (air-filled
    soil porosity)
    Surface
    or
    Subsurface
    Equation
    S21
    in Appendix
    C,
    (calculated)
    Table A
    for SSL
    Model,
    or
    Equation
    R21
    in Appendix
    C,
    Table
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    8.9
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    a
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    (Source:
    Amended
    at
    Ill.
    Reg.
    effective
    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    [
    As
    Ba
    Be
    Cd
    Cr
    (+3)
    Cr
    (+6)
    Hg
    Ni
    Ag
    Se
    Ti
    Zn
    Pb
    3.3E+Ol
    a
    a
    a
    a
    1.1E+01
    2
    2
    1.2E+00
    l.2E+02
    1.9E+03
    L_____
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    a
    a
    a
    a
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    a
    a
    a
    1.1E+00
    l.2E+02
    a
    1.9E+03b

    ILLiNOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Section
    742.APPENDIX
    C:
    Tier
    2
    Tables
    Section
    742.Table
    L:
    J&E
    Equations
    TRxAT
    x365
    For
    carcinogenic
    contaminants
    RO,,dOO
    air
    =
    J&E1
    Indoor
    air
    remediation
    ED
    x
    EF
    x
    URF
    x
    1000
    objectives
    (mg/rn
    3
    )
    For
    noncarcinogenic
    =
    THQ
    x
    AT,,
    x
    365
    x
    RfC
    contaminants
    ROI,jdQQraj,.
    ED
    x
    EF
    To
    convert
    mg/rn
    3
    from
    parts
    per
    million
    volume
    mg
    /
    m3
    =
    ppm
    x
    MW
    24.45
    R
    °jndoor-air
    Soil
    gas
    remediation
    ROsojigas
    =
    obiective
    (mg/rn
    3
    )
    a
    Soil
    remediation
    ROsojigas
    (o
    +
    Kd
    X
    Pb
    +
    X
    objectives
    (mg/kg)
    RO
    501
    H-
    XPb
    xl000
    Saturated
    soil
    S
    x
    [(Kd
    X
    Pb)
    +
    OW
    +
    (HTS
    x
    Oa
    )j
    concentration
    (mg/kg)
    Csat
    J&E6a
    Pb

    ILLiNOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    PxMW
    6
    Soil
    Vapor
    Saturation
    c’
    =
    x
    10
    Limitx
    R
    x
    T
    J&E6b
    (mg/m3-air)
    RO
    0
    j
    1g
    J&E7
    Groundwater
    remediation
    objectives
    RO
    =
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    I
    x
    exp
    Attenuation
    factor
    for
    cases
    [
    D1
    x
    AB
    x
    “ii
    J&E8a
    where
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    is
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    pressure
    x
    LT
    )J
    X
    A
    crack
    Jj
    difference
    between
    the
    building
    Qbld
    and
    the
    subsurface
    soil
    a
    =
    crack
    7’
    Q
    =
    83.33
    cm
    3
    /sec
    P
    1
    x
    A
    crack
    Qwg
    X
    LT
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    X
    T
    L
    crack
    ex
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    1
    ,
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    I
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    crack
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    D’
    x
    AB
    where
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    pressure
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    between
    the
    Qbldg
    X
    LT
    building
    and
    the
    subsurface
    soil
    a
    =
    QO
    cm
    3
    /sec
    [i
    +1
    x
    AB
    +
    (
    D
    x
    AB
    x
    LC,.UCk
    J&E8b
    Qbldg
    x
    L)
    LT
    x
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    A
    crack
    JJ

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    LT
    J&E9a
    Total
    overall
    effective
    diffusion
    coefficient
    for
    L,
    /
    vapor
    transport
    in
    porous
    1=1
    media
    for
    multiple
    soil
    layers
    (cm
    2
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    ‘I
    In
    Equation
    J&E9a,
    the
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    L.
    =
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    J&E9b
    .
    condition
    must
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    satisfied:
    j=1
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    to
    building
    J&E1O
    separation
    (cm)
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    D
    LF
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    N
    /
    D
    N
    I
    J&Ell
    coefficientfor
    each
    soil
    =
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    —-—
    l+
    —--—
    layer
    (cm
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    I
    \
    Ti)
    \.
    TSIR
    T,i)
    Surface
    area
    of
    enclosed
    space
    at
    or
    below
    grade
    For
    a
    slab-on-grade
    building
    AB
    (LB
    x
    WB)
    J&E12a
    (cm2)
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    are
    of
    enclosed
    space
    at
    or
    below
    grade
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    a
    building
    with
    a
    basement
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    =
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    X
    WB)
    +
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    LF
    X
    L
    8
    )
    +
    (2><
    LF
    X
    WB)
    J&E12b
    (cm2)
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    ventilation
    rate
    (
    LB
    x
    WB
    x
    HB
    x
    ER
    (cm
    3
    /s)
    Qbldg
    3600

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMEI\UMENTS
    Area
    of
    total
    cracks
    (cm2)
    A
    crack
    =
    2
    (LB
    +
    WB
    )
    J&E14
    Effective
    diffusion
    r
    p3.33
    N
    +
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    “q’
    333
    N
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    through
    the
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    =
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    I
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    (cm2/s)
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    i
    2
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    I
    I
    2
    \
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    ,,
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    TS
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    )
    PbI
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    porosity
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    J&E16
    PS
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    =
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    v
    J
    Air-filled
    porosity
    Oa
    =
    J&E18
    (Source:
    Added
    at
    Ill.
    Reg.
    effective
    )

    ILLiNOIS
    REGISTER
    Section
    742.APPENDIX
    C:
    Tier
    2
    Tables
    Section
    742.Table
    M:
    J&E
    Parameters
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Symbol
    Parameter
    Units
    Source
    Tier
    1
    or
    Calculated
    Value
    Surface
    area
    of
    enclosed
    space
    cm
    2
    Equation J&E
    I
    2a
    or
    I
    2b,
    Appendix
    C.
    Residential
    =
    I
    x
    106
    Industrial/Commercial
    =
    4.0
    x
    106
    at
    or
    below
    grade
    Table
    L
    Area
    of
    total
    cracks
    cm
    2
    Equation
    J&E
    14,
    Appendix
    C,
    Table
    L
    Calculated
    Value
    AT
    Averaging
    time
    for
    carcinogens
    y
    SSL,
    Page
    2-12
    Residential
    =
    30
    AT
    Averaging
    time
    for
    noncarcinogens
    Industrial/Commercial
    =
    25
    Soil
    saturation
    concentration
    Equation
    J&E
    6a,
    Appendix
    C,
    Table
    L
    Chemical-Specific
    or
    Calculated
    Value
    Soil
    vapor
    concentration
    mglm
    3-air
    Equation
    J&E
    6b,
    Appendix
    C,
    Table
    L
    Chemical-Specific
    or
    Calculated
    Value
    y
    Effective
    diffusion
    coefficient
    through
    the
    cm
    2
    Is
    Equation
    J&E
    15,
    Appendix
    C,
    Table
    L
    Calculated
    Value
    cracks
    D,
    Diffusivity
    in
    air
    cm
    2/s
    Appendix
    C,
    Table
    A
    Chemical-Specific
    D
    Effective
    diffusion
    coefficient
    of
    soil
    layer
    i
    cm
    2/s
    Equation
    J&E
    1
    1,
    Appendix
    C,
    Table
    L
    Calculated
    Value

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Symbol
    Parameter
    Units
    1
    Source
    Tier
    1
    or
    Calculated
    Value
    Distance
    from
    ground
    surface
    to
    top
    of
    Soil
    Contamination
    =
    152.4
    Psource
    cm
    Field
    Measurement
    Groundwater
    Contamination
    =
    304.8
    contamination
    Site-Specific
    DT
    Total
    overall
    effective
    diffusion
    coefficient
    cm
    2/s
    Eciuation
    J&E
    9a,
    Appendix
    C,
    Table
    L
    Calculated
    Value
    D
    Diffusivity
    in
    water
    cm2/s
    Appendix
    C,
    Table
    E
    Chemical-Specific
    Residential
    =
    30
    ED
    Exposure
    duration
    SSL
    Page
    2-
    12
    Industrial/Commercial
    =
    25
    Residential
    350
    EF
    Exposure
    frequency
    day/year
    SSL
    Page
    2-12
    Industrial/Commercial
    =
    250
    Residential
    =
    0.53
    ER
    Air
    exchange
    rate
    exchanges
    per
    hour
    Illinois
    EPA
    Industrial/Commercial
    =
    0.93
    SSL
    or
    Field
    Measurement
    f
    Fraction
    organic
    carbon
    content
    gg
    0.002
    or
    Site-Specific
    Appendix
    C,
    Table
    F

    ILLiNOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENEMENTS
    Symbol
    Parameter
    Units
    fsource
    [
    Tier
    1
    or
    Calculated
    Value
    Slab
    on
    Grade
    Residential
    =
    244
    Industrial/Commercial
    =
    305
    or
    Site-Specific
    iir
    Height
    of
    building
    Illinois
    EPA
    Basement
    Residential
    =
    427
    Industrial/Commercial
    =
    488
    or
    Site-Specific
    Dimensionless
    Henry’s
    law
    constant
    at
    the
    Appendix
    C,
    Table
    B
    Wrs
    system
    (soifl
    temperature
    unitless
    Chemical-Specific
    c
    1d
    Soil-water
    partition
    coefficient
    pf/g
    Equation
    S
    19,
    Appendix
    C,
    Table
    A
    Calculated
    Value
    K
    Organic
    carbon
    partition
    coefficient
    gfg
    Appendix
    C,
    Table
    E
    or
    Appendix
    C,
    Table
    I
    Chemical-Specific
    La
    Residential
    =
    1000
    Length
    of
    building
    cm
    Illinois
    EPA
    Industrial/Commercial
    =
    2000
    Lk
    Slab
    thickness
    cm
    US
    EPA,
    2004
    10
    LF
    Distance
    from
    ground
    surface
    to
    bottom
    of
    slab
    cm
    US
    EPA,
    2004
    10
    (slab
    on
    grade)
    200
    (basement)

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Sbol
    Parameter
    Units
    Source
    Tier
    I
    or
    Calculated
    Value
    Field
    Measurement
    Site-Specific
    L
    Thickness
    of
    soil
    layer
    i
    cm
    For
    capillary
    fringe,
    USEPA,
    2004
    For
    capillary
    fringe,
    17
    cm
    Distance
    from
    bottom
    of
    slab
    to
    top
    of
    Field
    Measurement
    or
    Equation
    J&E
    10,
    LT
    cm
    142.4
    or
    Site-Specific
    contamination
    Appendix
    C,
    Table
    L
    MW
    Molecular
    weight
    g/mole
    Illinois
    EPA
    Chemical-Specific
    Total
    number
    of
    layers
    of
    different
    types
    of
    soil
    vapors
    migrate
    through
    from
    source
    to
    building
    unitless
    Field
    measurement
    Site-Specific
    (if
    source
    is
    groundwater,
    include
    a
    capillary
    fringe
    layer
    of
    17
    cm
    as
    one
    of
    the
    layers)
    P
    Vapor
    Pressure
    atm
    Illinois
    EPA
    Chemical-Specific
    Slab
    on
    Grade
    Residential
    =
    3.59
    x
    i0
    Industrial/Commercial
    =
    3.15
    x
    I
    or
    Site-Specific
    Q
    Building
    ventilation
    rate
    cm3/s
    Equation
    J&E
    13,
    Appendix
    C,
    Table
    L
    Basement
    Residential
    =
    6.28
    x
    Industrial/Commercial
    5.04
    x
    i0
    or
    Site-Specific

    ILLiNOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Sbo1
    Parameter
    Units
    Source
    Tier
    1
    or
    Calculated
    Value
    Zero
    under
    Tiers
    1
    and
    2
    US
    EPA,
    2004
    Volumetric
    flow
    rate
    of
    soil
    gas
    into
    the
    cm3
    /s
    Part
    742.5
    05(a)(2)(D)
    and
    Under
    Tier
    3,
    zero
    if
    LT
    is
    greater
    than
    enclosed
    space
    Part
    742.505(b)(5)
    5
    feet
    (152
    cm)
    83.33
    if
    LT
    is
    less
    than
    5
    feet
    (152
    cm)
    R
    Ideal
    gas
    constant
    atrn-L/mol-K
    US
    EPA,
    2004
    0.08206
    RfC
    Reference
    concentration
    Illinois
    EPA
    Toxicological-Specific
    Appendix
    B,
    Table
    E,
    or
    Equation
    J&E
    Chemical-Specific
    Groundwater
    remediation
    objective
    Appendix
    C,
    Table
    L
    Qindoor-air
    Indoor
    air
    remediation
    objective
    mg/rn3
    Equations
    J&E
    1-2.
    Appendix
    C,
    Table
    L
    Calculated
    Value
    Appendix
    B,
    Tables
    A
    or
    B
    or
    Equation
    J&E
    5,
    Tier
    1
    or
    Calculated
    Value
    Q01
    Soil
    remediation
    objective
    Appendix
    C,
    Table
    L
    Qsogas
    Soil
    gas
    remediation
    objective
    mg/rn3
    Equation
    J&E
    4,
    Appendix
    C,
    Table
    L
    Calculated
    Value
    Solubility
    in
    water
    Appendix
    C,
    Table
    E
    Chemical-Specific

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Symbol
    Parameter
    Source
    Tier
    1
    or
    Calculated
    Value
    T
    Temperature
    K
    US
    EPA,
    2004
    286
    (converted
    from
    1
    3°C)
    ThQ
    Target
    hazard
    quotient
    for
    a
    chemical
    unitless
    SSL
    .
    Residential
    =
    l0
    at
    the
    point
    of
    human
    Target
    risk
    or
    the
    increased
    chance
    of
    -
    SSL
    exposure
    TR
    developing
    cancer
    over
    a
    lifetime
    due
    to
    unitless
    Industrial/Commercial
    =
    10
    at
    the
    exposure
    to
    a
    chemical
    point
    of
    human
    exposure
    URF
    Unit
    risk
    factor
    (uglm
    3)
    -i
    Illinois
    EPA
    Toxicological-
    Specific
    w
    Floor-wall
    seam
    gap
    cm
    US
    EPA,
    2004
    W
    Moisture
    content
    g
    of
    water/g
    of
    soil
    Field
    Measurement,
    Appendix
    C.
    Table
    F
    Site-Specific
    Residential
    =
    1000
    W
    Width
    of
    building
    cm
    Illinois
    EPA
    Industrial/Commercial
    =
    2000
    or
    Site-Specific
    ii
    Attenuation
    factor
    (groundwater)
    unitless
    Equations
    J&E
    8a
    or
    8b,
    Appendix
    C,
    Table
    L
    Site-Specific

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Parameter
    Air-filled
    soil
    porosity
    Air-filled
    porosity
    for
    soil
    in
    cracks
    Total
    porosity
    for
    soil
    in
    cracks
    Water-filled
    soil
    porosity
    Water-filled
    porosity
    for
    soil
    in
    cracks
    Source
    Tier
    1
    or
    Calculated
    Value
    Equation
    J&E
    18,
    Appendix
    C,
    Table
    L
    0.28
    or
    Calculated
    Value
    endix
    C,
    Table
    A
    0.28
    0.28
    or
    Calculated
    Value
    For
    capillary
    fringe,
    ea
    0.1
    eT
    Equation
    S24,
    Appendix
    C,
    Table
    A
    ndix
    C,
    Table
    L
    Equation
    J&E
    17,
    Appendix
    C,
    Table
    L
    Equation
    S20,
    Appendix
    C,
    Table
    A
    Water-filled
    porosity
    of
    soil
    layer
    i
    0.43
    0.43
    or
    Calculated
    Value
    0.15
    or
    Calculated
    Value
    0.15
    0.15
    or
    Calculated
    Value
    For
    capillary
    fringe
    0.3
    75
    or
    0.9
    eT.
    SSL
    or
    Field
    Measurement
    1.5
    or
    Calculated
    Value
    Appendix
    C,
    Table
    F

    ILLINOIS
    REGISTER
    POLLUTION
    CONTROL
    BOARD
    NOTICE
    OF
    PROPOSED
    AMENDMENTS
    Symbol
    Parameter
    Units
    Source
    Tier
    I
    or
    Calculated
    Value
    j
    Soil
    particle
    density
    /3
    Field
    Measurement,
    Appendix
    C,
    Table
    F
    or
    2.65
    or
    Calculated
    Value
    SSL
    j
    Density
    of
    water
    Illinois
    EPA
    I
    SSL
    “Technical
    Background
    Document
    for
    Draft
    Soil
    Screening
    Level
    Framework,
    Review
    Draft”,
    July
    1994SSG
    “Soil
    Screening
    Guidance:
    User’s
    Guide”
    EPAI54O/R-961018,
    April
    1996
    US
    EPA,
    2004a.
    Users
    Guide
    for
    Evaluating
    Subsurface
    Vapor
    Intrusion
    into
    Buildings.
    February
    2004.
    (Source:
    Added
    at
    Ill.
    Reg.
    effective

    STATE
    OF
    ILLINOIS
    )
    GE
    )
    ‘3P
    032008
    COUNTY
    OF
    SANGAMON
    )
    co,/JN0Is
    PROOF
    OF
    SERVICE
    ard
    I,
    the undersigned,
    on
    oath
    state
    that
    I
    have
    served
    the
    attached
    Motion
    for
    Acceptance, Appearance
    of
    Attorney,
    Certification
    of
    Origination,
    Motion
    for
    Leave
    from
    Filing
    Requirement,
    List
    of Studies
    and
    Reports
    Used
    in
    Regulatory
    Development,
    Statement
    of
    Reasons,
    and
    the
    Proposed
    Amendments
    upon
    the
    persons
    to
    whom
    they
    are
    directed,
    by
    placing
    a
    copy
    of each
    in an
    envelope
    addressed
    to:
    Dorothy
    Gunn,
    Clerk
    Bill
    Richardson
    Illinois
    Pollution Control
    Board
    Chief
    Legal
    Counsel
    James
    R.
    Thompson
    Center
    Illinois
    Dept.
    of
    Natural
    Resources
    100
    W.
    Randolph,
    Suite
    11-500
    One
    Natural
    Resources
    Way
    Chicago, Illinois
    60601
    Springfield,
    Illinois
    62702-1271
    Matt
    Dunn
    Environmental
    Bureau
    Chief
    Office
    of
    the
    Attorney
    General
    James
    R.
    Thompson
    Center
    100
    W.
    Randolph,
    12
    th
    Floor
    Chicago,
    Illinois
    60601
    and
    mailing
    them
    (First
    Class
    Mail)
    from
    Springfield,
    Illinois
    on
    September
    2,
    2008,
    with
    sufficient
    postage
    affixed
    as
    indicated
    SUBSCRIBED
    AND
    SWORN TO
    BEFORE
    ME
    This
    day
    of
    September,
    2008.
    Notary Public
    OFFICIAL
    SEAL
    BRENDA
    BOEHNER
    :
    NOTARY
    PUBliC,
    STATE
    OF
    IWNOS
    :
    MY
    COMMISSION
    EXPIRES
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