ILLINOIS REGISTER
ENVIRONMENTAL PROTECTION AGENCY
NOTICE OF PROPOSED RULES
1)
Heading of the Part: Standards and Limitations for Organic Material Emissions for Area
Sources
2)
Code Citation: 35 III. Adm Code Part 223
3)
Section Numbers:
?
Proposed Action:
223.100?
New
223.105
?
New
223.110
?
New
223.120
?
New
223.200?
New
223.201?
New
223.205?
New
223.206
?
New
223.207?
New
223.208?
New
223.209?
New
223.210?
New
223.220?
New
223.230?
New
223.240
?
New
223.245?
New
223.250
?
New
223.255?
New
223.260?
New
223.265?
New
223.270
?
New
223.275?
New
223.280?
New
223.285?
New
223.300
?
New
223.305?
New
223.307
?
New
223.310
?
New
223.320
?
New
223.330?
New
223.340
?
New
223.350
?
New
223.360?
New
223.370?
New
ILLINOIS REGISTER
ENVIRONMENTAL PROTECTION AGENCY
NOTICE OF PROPOSED RULES
223.400
New
223.405
New
223.407
New
223.410
New
223.420
New
223.430
New
223.440
New
223.450
New
223.460
New
Appendix A
New
Appendix B New
4)
Statutory Authority: Sections 27 and 28 of the Illinois Environmental Protection Act.
[415 ILCS 5/27 and 28]
5)
A Complete Description of the Subiects and Issues Involved : These regulations are
proposed in order to attain the new USEPA ozone NAAQS by 2010 and to protect the
health of Illinois citizens. The regulations seek to reduce volatile organic material
emissions ("VOM") from various consumer products, architectural and industrial
maintenance products, and aerosol coatings. If adopted, the rule will take effect on
January 1, 2009. These products represent significant, yet widely diffuse, sources of VOM
and are comprised of the various forms of consumer products used by individual
households and small businesses. Together, these items emit about 10% of the total
anthropogenic VOM emissions from sources in Illinois.
6)
Published studies or reports, and sources of underlying data, used to compose this
rulemaking: The regulatory proposal included the Illinois EPA's
Technical Support
Document
that relied on several published studies and reports. Copies of the documents
the Illinois EPA relied upon are available for review with the Pollution Control Board.
7)
Will this proposed rule replace an emergency rule currently in effect? No.
8)
Does this rulemaking contain an automatic repeal date? No.
9)
Does this proposed rule (amendment, repealer) contain incorporations by reference? Yes.
10)
Are there any other proposed amendments pending on this Part? No.
ILLINOIS REGISTER
ENVIRONMENTAL PROTECTION AGENCY
NOTICE OF PROPOSED RULES
11) Statement of Statewide Policy Objective: This proposed rule does not create or enlarge a
State mandate, as defined in Section 3(b) of the State Mandates Act. [30 ILCS 805/3(b)
(2002)].
12) Time Place and Manner in which interested persons may comment on this proposed
rulemaking: The Illinois Environmental Protection Agency will accept written public
comments on this proposal for a period of forty-five (45) days after the date of
publication in the Illinois Register. Comments should reference the Consumer
Products/AIM/Aerosol Rule and be addressed to:
Charles E. Matoesian
Assistant Counsel
Illinois Environmental Protection Agency
Division of Legal Counsel
1021 North Grand Avenue East
P.O. Box 19726
Springfield, Illinois 62794-9276
217/782-5544
217/782-9143( TDD)
13) Initial
Regulatory Flexibility Analysis:
A)
Types of small businesses, small municipalities and not for profit corporations
affected: This
proposed regulation will have a modest impact on small
businesses throughout the State.
B)
Reporting
, Bookkeeping or other procedures required for compliance: No new
forms of recordkeeping are projected to be needed. Although a new topic for
some companies, most calculations will be familiar. Standard bookkeeping and
recordkeeping skills will suffice. Many larger companies are already performing
the reporting, bookkeeping and compliance duties in other states.
C)
Types of professional skills necessary for compliance: Traditional accounting
skills and recordkeeping skills will suffice. No new professional skills will be
necessary.
14) Regulatory
Agenda on which this rulemaking was summarized: July 2007
ILLINOIS REGISTER
ENVIRONMENTAL PROTECTION AGENCY
NOTICE OF PROPOSED RULES
The full text of the Proposed Rule(s) begins on the nextpage:
TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE B: AIR POLLUTION
CHAPTER
I:
POLLUTION CONTROL BOARD
SUBCHAPTER
PART 223
STANDARDS AND LIMITATIONS FOR ORGANIC MATERIAL EMISSIONS FOR AREA
SOURCES
SUBPART A: GENERAL PROVISIONS
Section
?
223.100?
Severability
?
223.105?
Abbreviations and Acronyms
?
223.120?
Incorporations by Reference
SUBPART B: CONSUMER AND COMMERCIAL PRODUCTS
Section
?
223.200
?
Purpose
?
223.201
?
Applicability
?
223.203
?
Definitions for Subpart B
?
223.205
?
Standards
?
223.206?
Diluted Products
?
223.207
?
Products registered under FIFRA
?
223.208?
Requirements for Aerosol Adhesives
?
223.209?
Requirements for Floor Wax Strippers
?
223.210?
Products Containing Ozone-Depleting Compounds
?
223.220?
Requirements for Charcoal Lighter Material
?
223.230?
Exemptions
?
223.240
?
Innovative Product Exemption
?
223.245
?
Alternative Control Plans
?
223.250?
Product Dating
?
223.255?
Additional Product Dating Requirements
?
223.260
?
Most Restrictive Limit
?
223.265?
Additional Labeling Requirements for Aerosol Adhesives, Adhesive Removers,
Electronic Cleaner, Electrical Cleaner, Energized Electrical Cleaner, and Contact
Adhesives
?
223.270
?
Reporting Requirements
?
223.275
?
Special Recordkeeping Requirements for Consumer Products that Contain
Perchloroethylene or Methylene Chloride
?
223.280?
Calculating Illinois Sales
?
223.285?
Test Methods
SUBPART C: ARCHITECTURAL AND INDUSTRIAL MAINTENANCE COATINGS
Section
223.300
?
Purpose
223.305?
Applicability
223.307?
Definitions for Subpart C
223.310?
Standards
223.320?
Container Labeling Requirements
223.330?
Reporting Requirements
223.340?
Compliance Provisions and Test Methods
223.350?
Alternative Test Methods
223.360?
Methacrylate Traffic Coating Markings
223.370?
Test Methods
SUBPART D: AEROSOL COATINGS
Section
223.400?
Purpose
223.405?
Applicability
223.407?
Definitions for Subpart D
223.410
?
Limits and Requirements for Aerosol Coating Products
223.420?
Exemptions
223.430?
Most Restrictive Limit
223.440
?
Labeling Requirements
223.450?
Reporting Requirements
223.460?
Test Methods
APPENDIX A
?MAXIMUM
INCREMENTAL REACTIVITY
APPENDIX B
?MIR
VALUES FOR HYDROCARBON SOLVENTS
AUTHORITY : Implementing Section 10 [415 ILCS 5/10] and authorized by Sections 27 and 28
of the Environmental Protection Act [415 ILCS 5/27 and 28] .
SOURCE: Adopted at _ Ill . Reg. , effective
SUBPART A : GENERAL PROVISIONS
Section 223.100
?
Severability
If any Section, subsection, or clause of this Part is found invalid, such finding shall not
affect the validity of this Part as a whole or any Section, subsection, or clause not found invalid.
Section 223.105
?
Abbreviations and Acronyms
Unless otherwise specified within this Part, the abbreviations used in this Part shall be the
same as those found in 35 Ill. Adm. Code 211. The following abbreviations and
acronyms are used in this Part:
2
ACP
Act
Agency
ASTM
BAAQMD
CARB
CFCs
CO2
°F
FDA
FIFRA
FRP
HVOM
HCFCs
HFCs
LVP-VOM
MIR
MVOM
N2
N20
OER
PCBTF
PWMIR
ROC
ROG
SCAQMD
USEPA
ULKR
ULM1R
ULMR
VOM
Alternative Control Plan
Environmental Protection Act [415 ILCS 5/1 et seq .]
Illinois Environmental Protection Agency
American Society for Testing and Materials
Bay Area Air Quality Management District
California Air Resources Board
Degrees Celsius
Chlorofluorocarbons
Carbon Dioxide
Degrees Fahrenheit
United States Food and Drug Administration
Federal Insecticide, Fungicide, and Rodenticide Act, 7 U.S.C. §§136
through 136y
Fiberglass reinforced plastic
High Volatility Organic Material
Hydrochlorofluorocarbons
Hydro fluorocarbons
Low Vapor Pressure – Volatile Organic Material
Maximum Incremental Reactivity
Medium Volatility Organic Material
Nitrogen
Nitrous Oxide
Original Equipment Manufacturer
Parachlorobenzotrifluoride
Product-Weighted Maximum Incremental Reactivity
Reactive Organic Compound
Reactive Organic Gas
South Coast Air Quality Management District
United States Environmental Protection Agency
Upper-Limit Kinetic Reactivity
Upper-Limit Maximum Incremental Reactivity
Upper-Limit Mechanistic Reactivity
Volatile Organic Material
Section 223.120
?
Incorporations
by
Reference
The following materials are incorporated by reference. These incorporations do not
include any later amendments or editions.
a)
?
40 CFR 59, Subpart D, Appendix A, Determination of Volatile Matter Content of
Methacrylate Multicomponent Coatings Used as Traffic Marking Coatings, 64
Fed. Reg. 35002 (June 30, 1999).
40 CFR 59, Subpart C, National Volatile Organic Compound Emission
Standards for Consumer Products, (April 4, 2004).
3
c)
40 CFR 60, Appendix A, Method 24, Determination of Volatile Matter
Content, Water Content, Density, Volume Solids, and Weight Solids of
Surface Coatings (July 1, 2006).
d)
40 CFR 82, Subpart A, Production and Consumption Controls, Appendices A and
B July 1, 2006.
e)
29 CFR 1910.1200(d)(4), Hazard Communication July 1, 2006.
0
?
American Society for Testing and Materials (ASTM), 1916 Race Street,
Philadelphia, PA, 19103.
1)
ASTM E119-05a, Standard Test Methods for Fire Tests of Building
Construction and Materials, approved November 1, 2005.
2)
ASTM Designation D523-89, Standard Test Method for Specular Gloss,
approved May 10, 1999.
3)
ASTM D1640-03, Standard Test Methods for Drying, Curing, or Film
Formation of Organic Coatings at Room Temperature, approved
December 1, 2003.
4)
ASTM Method D 3912-95, Test Method for Chemical Resistance of
Coating Used in Light-Water Nuclear Power Plants, approved 2001.
5)
ASTM Method D 4082-02, Test Method for Effects of Radiation on
Coatings Used in Light-Water Nuclear Power Plants, approved 2002.
6)
ASTM Designation D4214-98, Standard Test Methods for Evaluating the
Degree of Chalking of Exterior Paint Films, approved August 10, 1998.
7)
ASTM D1613-03, Standard Test Method for Acidity in Volatile Solvents
and Chemical Intermediates Used in Paint, Varnish, Lacquer, and Related
Products, approved October 1, 2003.
8)
ASTM E84-07, Standard Test Method for Surface Burning Characteristics
of Building Materials, approved 2007.
9)
ASTM D4359-90, Standard Test Method for Determining Whether a
Material is a Liquid or a Solid, approved 2006.
10)
ASTM E260-96, Standard Practice for Packed Column Gas
Chromatography, reapproved 2006.
4
11)
ASTM D5043-04, Standard Test Methods for Field Identification of
Coatings, approved 2004.
12)
ASTM E2167-01, "Standard Guide for Selection and Use of Stone
Consolidants" (see section 4, Stone Consolidant), approved 2001.
13)
ASTM C836-06, Specification for High Solids Content, Cold Liquid-
Applied Elastomeric Waterproofing Membrane for Use with Separate
Wearing Course, approved 2006.
g)
South Coast Air Quality Management District (SCAQMD) Method 304-91,
Determination of Volatile Organic Compounds in Various Materials, revised
February 1996.
h)
SCAQMD Method 303-91, Determination of Exempt Compounds, revised
February 1993.
SCAQMD Method 318-95, Determination of Weight Percent Elemental Metal in
Coatings by X-Ray Diffraction, approved August 10, 1998.
j)
Bay Area Air Quality Management District (BAAQMD) Method 43,
Determination of Volatile Methylsiloxanes in Solvent-Based Coatings, Inks, and
Related Materials, amended May 18, 2005.
k)
BAAQMD Method 41, Determination of Volatile Organic Compounds in
Solvent-Based Coatings and Related Materials Containing Parachlorobenzotri
fluoride, amended May 18, 2005.
1) California Air Resources Board (CARB) Method 310, Determination of Volatile
Organic Compounds in Consumer Products and Reactive Organic Compounds in
Aerosol Coating Products, amended May 5, 2005.
m)
SCAQMD Rule 1174, Ignition Method Compliance Certification Protocol
(February 27, 1991).
n)
Cal. Admin. Code title 17 § 94509(h), Standards for Consumer Products (2005).
o)
California Code, Health and Safety Code, § 41712(h)(2) (2005).
p)
Cal. Admin. Code title 17, Article 4, Alternate Control Plan §§ 94540-94555,
(1996).
q)
Cal. Admin. Code title 17 § 94511, Innovative Products (1997)..
r)
Cal. Admin. Code title 17 § 94503.5, Innovative Products (1996).
5
s)
7 USC 136 to 136y, FIFRA, Environmental Pesticide Control, published January
19, 2004, in Supplement III of the 2000 Edition of the United States Code.
t)
Federal Specification MMM-A-18I D, Adhesives, Phenol, Resorcinol, or
Melamine Base (1980).
SUBPART B: CONSUMER AND COMMERCIAL PRODUCTS
Section 223.200 Purpose
The purpose of this Subpart is to limit emissions of volatile organic materials (VOMs) by
requiring reductions in the VOM content of consumer and commercial products.
Section 223.201 Applicability
Except as provided in Section 223.230, below, this Subpart shall apply to any person who sells,
supplies, offers for sale, or manufactures consumer products on or after January 1, 2009, for use
in Illinois.
Section 223.203 Definitions for Subpart B
The definitions contained in this Section apply only to the provisions of this Subpart. Unless
otherwise defined herein, the definitions of terms used in this Subpart shall have the meanings
specified for those terms in 35 111. Adm. Code Part 211.
"Adhesive" means for purposes of this Part, any product that is used to bond one surface
to another by attachment. This does not include products used on humans and animals,
adhesive tape, contact paper, wallpaper, shelf liners, or any other product with an
adhesive incorporated onto or in an inert substrate. For "Contact Adhesive," adhesive
does not include units of product, less packaging, which consist of more than one gallon.
For "Construction, Panel, and Floor Covering Adhesive," and "General Purpose
Adhesive," "Adhesive" does not include units of product, less packaging, which weigh
more than one pound and consist of more than 16 fluid ounces. This limitation does not
apply to aerosol adhesives.
"Adhesive Remover" means a product designed to remove adhesives from either a
specific substrate or a variety of substrates. "Adhesive Remover" does not include
products that remove adhesives intended exclusively for use on humans or animals.
For the purpose of this definition and "Adhesive Remover" subcategories below,
the term "Adhesive" shall mean a substance used to bond one or more materials.
Adhesive includes, but is not limited to caulks, sealants, glues, or similar
substances used for the purpose of forming a bond.
6
"Floor and Wall Covering Adhesive Remover" means a product designed or
labeled to remove floor or wall coverings and associated adhesive from the
underlying substrate.
"Gasket or Thread Locking Adhesive Remover" means a product designed or
labeled to remove gaskets or thread locking adhesives. Products labeled for dual
use as a paint stripper and gasket remover and/or thread locking adhesive remover
are considered "Gasket or Thread Locking Adhesive Remover."
"General Purpose Adhesive Remover" means a product designed or labeled to
remove cyanoacrylate adhesives as well as non-reactive adhesives or residue from
a variety of substrates. "General Purpose Adhesive Remover" includes, but is not
limited to the following: products that remove thermoplastic adhesives, pressure
sensitive adhesives, dextrine or starchbased adhesives, casein glues, rubber or
latex-based adhesives, and products that remove stickers, decals, stencils, or
similar materials. "General Purpose Adhesive Remover" does not include "Floor
or Wall Covering Adhesive Remover."
"Specialty Adhesive Remover" means a product designed to remove reactive
adhesives from a variety of substrates. Reactive adhesives include adhesives that
require a hardener or catalyst in order for the bond to occur. Examples of reactive
adhesives include, but are not limited to epoxies, urethanes, and silicones.
"Specialty Adhesive Remover" does not include "Gasket or Thread Locking
Adhesive Remover."
"Aerosol adhesive" means an aerosol product in which the spray mechanism is
permanently housed in a nonrefillable can designed for hand-held application without the
need for ancillary hoses or spray equipment. This does not include "special purpose
spray adhesives," "mist spray adhesives" and "web spray adhesives."
"Aerosol cooking spray" means any aerosol product designed either to reduce sticking on
cooking and baking surfaces or to be applied on food, or both.
"Aerosol Product" means a pressurized spray system that dispenses product ingredients
by means of a propellant contained in a product or a product's container, or by means of a
mechanically induced force. "Aerosol Product" does not include "Pump Spray."
"Agricultural use" means the use of any pesticide or method or device for the control of
pests in connection with the commercial production, storage, or processing of any animal
or plant crop. This does not include the sale or use of pesticides in properly labeled
packages or containers that are intended for home use, use in structural pest control,
industrial or institutional use. For the purposes of this definition only:
"Home use" means use in a household or its immediate environment;
7
"Structural pest control" means a use requiring a license under the Structural Pest
Control Act, 225 ILCS 235;
"Industrial use" means use for or in a manufacturing, mining, or chemical process
or use in the operation of factories, processing plants, and similar sites; or
"Institutional use" means use within the lines of, or on property necessary for the
operation of, buildings such as hospitals, schools, libraries, auditoriums, and
office complexes.
"Air Freshener" means any consumer product including, but not limited to, sprays, wicks,
powders, and crystals, designed for the purpose of masking odors, or freshening,
cleaning, scenting, or deodorizing the air. "Air Freshener" does not include products that
are used on the human body, products that function primarily as cleaning products as
indicated on a product label, "Toilet/Urinal Care Products," disinfectant products
claiming to deodorize by killing germs on surfaces, or institutional and industrial
disinfectants when offered for sale solely through institutional and industrial channels of
distribution.
"Air Freshener" does include spray disinfectants and other products that are expressly
represented for use as air fresheners, except institutional and industrial disinfectants when
offered for sale through institutional and industrial channels of distribution. To
determine whether a product is an air freshener, all verbal and visual representations
regarding product use on the label or packaging and in the product's literature and
advertising may be considered. The presence of, and representations about, a product's
fragrance and ability to deodorize (resulting from surface application) shall not constitute
a claim of air freshening.
"All Other Carbon-Containing Compounds" means all other compounds which contain at
least one carbon atom and are not listed under Section 223.205(a) or are a "LVP-VOM."
"All Other Forms" means all consumer product forms for which no form-specific VOM
standard is specified. Unless specified otherwise by the applicable VOM standard, "All
Other Forms" include, but are not limited to, solids, liquids, wicks, powders, crystals, and
cloth or paper wipes (towelettes).
"Alternative Control Plan or ACP" means any emissions averaging program approved by
the Agency pursuant to the provisions of this regulation.
"Antimicrobial Hand or Body Cleaner or Soap" means a cleaner or soap which is
designed to reduce the level of microorganisms on the skin through germicidal activity.
This includes, but is not limited to, antimicrobial hand or body washes/cleaners,
foodhandler hand washes, healthcare personnel hand washes, pre-operative skin
preparations and surgical scrubs. "Antimicrobial Hand or Body Cleaner or Soap" does
not include prescription drug products, antiperspirants, "Astringent/Toner," deodorant,
"Facial Cleaner or Soap," "General-use Hand or Body Cleaner or Soap," "Hand
8
Dishwashing Detergent" (including antimicrobial), "Heavy-duty Hand Cleaner or Soap,"
"Medicated Astringent/Medicated Toner," and "Rubbing Alcohol."
"Antiperspirant" means any product including, but not limited to, aerosols, roll-ons,
sticks, pumps, pads, creams, and squeeze-bottles, that is intended by the manufacturer to
be used to reduce perspiration in the human axilla by at least 20 percent in at least 50
percent of a target population.
"Anti-Static Product" means a product that is labeled to eliminate, prevent, or inhibit the
accumulation of static electricity. "Anti-Static Product" does not include "Electronic
Cleaner," "Floor Polish or Wax," "Floor Coating," and products that meet the definition
of "Aerosol Coating Product" or "Architectural Coating."
"Appurtenance" means any accessory to a stationary structure coated at the site of
installation, whether installed or detached, including but no limited to, bathroom and
kitchen fixtures, cabinets, concrete forms, doors, elevators, fences, hand railings, heating
equipment, air conditioning equipment, and other fixed mechanical equipment or
stationary tools, lampposts, partitions pipes and piping systems, rain gutters and
downspouts, stairways, fixed ladders, catwalks and fire escapes, and window screens.
"Architectural Coating" means for purposes of this Part, a coating to be applied to
stationary structures or the appurtenances at the site of installation, to portable buildings
at the site of installation, to pavements, or to curbs. Coatings applied in shop applications
or to non-stationary structures such as airplanes, ships, boats, railcars, and automobiles,
and adhesives are not considered "Architectural Coatings" for the purposes of this rule.
"Astringent/Toner" means any product not regulated as a drug by the United States Food
and Drug Administration (FDA) which is applied to the skin for the purpose of cleaning
or tightening pores. This category also includes clarifiers and substrate-impregnated
products. This category does not include any hand, face, or body cleaner or soap product,
"Medicated Astringent/Medicated Toner," cold cream, lotion, or antiperspirant.
"Automotive Brake Cleaner" means a cleaning product designed to remove oil, grease,
brake fluid, brake pad material or dirt from motor vehicle brake mechanisms.
"Automotive Hard Paste Wax" means an automotive wax or polish which is designed to
protect and improve the appearance of automotive paint surfaces, and is a solid at room
temperature, and contains 0% water by formulation.
"Automotive Instant Detailer" means a product designed for use in a pump spray that is
applied to the painted surface of automobiles and wiped off prior to the product being
allowed to dry.
"Automotive Rubbing or Polishing Compound" means a product designed primarily to
remove oxidation, old paint, scratches or swirl marks, and other defects from the painted
surfaces of motor vehicles without leaving a protective bather.
9
"Automotive Wax, Polish, Sealant, or Glaze" means a product designed to seal out
moisture, increase gloss, or otherwise enhance a motor vehicle's painted surfaces. This
includes, but is not limited to, products designed for use in autobody repair shops and
drive-through car washes, as well as products designed for the general public. The term
does not include "Automotive Rubbing or Polishing Compounds," automotive wash and
wax products, surfactant-containing car wash products, and products designed for use on
unpainted surfaces such as bare metal, chrome, glass, or plastic.
"Automotive Windshield Washer Fluid" means any liquid designed for use in a motor
vehicle windshield washer system either as an antifreeze or for the purpose of cleaning,
washing, or wetting the windshield. This does not include fluids placed by the
manufacturer in a new vehicle.
"Bathroom and Tile Cleaner" means a product designed to clean tile or surfaces in
bathrooms. The term does not include products designed primarily to clean toilet bowls,
toilet tanks or urinals.
"Bug and Tar Remover" means a product labeled to remove either or both of the
following from painted motor vehicle surfaces without causing damage to the finish:
biological-type residues such as insect carcasses, tree sap and road grime, such as road
tar, roadway paint markings, and asphalt.
"Carburetor or Fuel-Injection Air Intake Cleaners" means a product designed to remove
fuel deposits, dirt, or other contaminants from a carburetor, choke, throttle body of a fuel-
injection system, or associated linkages, excluding products designed exclusively to be
introduced directly into the fuel lines or fuel storage tank prior to introduction into the
carburetor or fuel injectors.
"Carpet and Upholstery Cleaner" means a cleaning product designed for the purpose of
eliminating dirt and stains on rugs, carpeting, and the interior of motor vehicles and/or on
household furniture or objects upholstered or covered with fabrics such as wool, cotton,
nylon or other synthetic fabrics. This includes, but is not limited to, products that make
fabric protectant claims. The term does not include "General Purpose Cleaners," "Spot
Removers," vinyl or leather cleaners, dry cleaning fluids, or products designed
exclusively for use at industrial facilities engaged in furniture or carpet manufacturing.
"Charcoal Lighter Material" means any combustible material designed to be applied on,
incorporated in, added to, or used with charcoal to enhance ignition. The term does not
include any of the following: electrical starters and probes, metallic cylinders using paper
tinder, natural gas, propane, and fat wood.
"Colorant" means for purposes of Subpart B, any pigment or coloring material used in a
consumer product for an aesthetic effect, or to dramatize an ingredient. For purposes of
Subpart C, "Colorant" means a concentrated pigment dispersion in water, solvent, and/or
10
binder that is added to an architectural coating after packaging in sale units to produce the
desired color.
"Construction, Panel, and Floor Covering Adhesive" means any one-component
adhesive that is designed exclusively for the installation, remodeling, maintenance, or
repair of structural and building components that include, but are not limited to, beams,
trusses, studs, paneling (including, but not limited to, drywall or drywall laminates,
fiberglass reinforced plastic (FRP), plywood, particle board, insulation board,
pre-decorated hardboard or tileboard), ceiling and acoustical tile, molding, fixtures,
countertops or countertop laminates, cove or wall bases, flooring or subflooring; or floor
or wall coverings that include, but are not limited to, wood or simulated wood covering,
carpet, carpet pad or cushion, vinyl-backed carpet, flexible flooring material, nonresilient
flooring material, mirror tiles and other types of tiles, and artificial grass. The term does
not include "Floor Seam Sealer."
"Consumer" means any person who purchases or acquires any consumer product for
personal, family, household, or institutional use. Persons acquiring a consumer product
for resale are not "consumers" for that product.
"Consumer Product" means a chemically formulated product used by household and
institutional consumers including, but not limited to detergents, cleaning compounds,
polishes, floor finishes, cosmetics, personal care products; home, lawn, and garden
products, disinfectants, sanitizers, aerosol paints, and automotive specialty products.
"Consumer Product" does not include other paint products, furniture coatings, or
architectural coatings. As used in this rule, "Consumer Products" shall also refer to
"Aerosol Adhesives," including "Aerosol Adhesives" used for consumer, industrial or
commercial uses.
"Contact Adhesive" means an adhesive that is designed for application to both surfaces to
be bonded together, and is allowed to dry before the two surfaces are placed in contact
with each other, and forms an immediate bond that is impossible, or difficult, to
reposition after both adhesive-coated surfaces are placed in contact with each other, and
does not need sustained pressure or clamping of surfaces after the adhesive-coated
surfaces have been brought together using sufficient momentary pressure to establish full
contact between both surfaces. The term does not include rubber cements that are
primarily intended for use on paper substrates. "Contact Adhesive" also does not include
vulcanizing fluids that are designed and labeled for tire repair only.
"Contact Adhesive - General Purpose" means any contact adhesive that is not a "Contact
Adhesive - Special Purpose."
"Contact Adhesive - Special Purpose" means a contact adhesive that is used to bond
melamine-covered board, unprimed metal, unsupported vinyl, Teflon, ultra-high
molecular
weight polyethylene, rubber, high pressure laminate or wood veneer 1/16 inch
or less in thickness to any porous or nonporous surface, and is sold in units of product,
less packaging, that contain more than eight fluid ounces, or is used in automotive
11
applications that are either automotive under the- hood applications requiring heat, oil or
gasoline resistance, or body-side molding, automotive weatherstrip or decorative trim.
"Container/Packaging" means the part or parts of the consumer or institutional product
which serve only to contain, enclose, incorporate, deliver, dispense, wrap or store the
chemically formulated substance or mixture of substances which is solely responsible for
accomplishing the purposes for which the product was designed or intended. This
includes any article onto or into which the principal display panel and other
accompanying literature or graphics are incorporated, etched, printed or attached.
"Crawling Bug Insecticide" means any insecticide product that is designed for use against
ants, cockroaches, or other household crawling arthropods, including, but not limited to,
mites, silverfish or spiders, excluding products designed to be used exclusively on
humans or animals, or any house dust mite product. For the purposes of this definition
only:
"House dust mite product" means a product whose label, packaging, or
accompanying literature states that the product is suitable for use against house
dust mites, but does not indicate that the product is suitable for use against ants,
cockroaches, or other household crawling arthropods.
"House dust mite" means mites which feed primarily on skin cells shed in the
home by humans and pets and which belong to the phylum Arthropoda, the
subphylum Chelicerata, the class Arachnida, the subclass Acari, the order
Astigmata, and the family Pyroglyphidae.
"Date-Code" means the day, month and year on which the consumer product was
manufactured, filled, or packaged, or a code indicating such a date.
"Deodorant" means:
For products manufactured before January 1, 2009: any product including, but not
limited to, aerosols, roll-ons, sticks, pumps, pads, creams, and squeeze-bottles,
that is intended by the manufacturer to be used to minimize odor in the human
axilla by retarding the growth of bacteria which cause the decomposition of
perspiration.
For products manufactured on or after January 1, 2009: any product including, but
not limited to, aerosol, roll-ons, sticks, pumps, pads, creams, and squeeze-bottles,
that indicates or depicts on the container or packaging, or on any sticker or label
affixed thereto, that the product can be used on or applied to the human axilla to
provide a scent and/or minimize odor. A "Deodorant Body Spray" product that
indicates or depicts on the container or packaging, or on any sticker or label
affixed
thereto, that it can be used on or applied to the human axilla, is a
"Deodorant"
12
"Deodorant Body Spray" means
For products manufactured before January 1, 2009, a "Personal Fragrance
Product" with 20 percent or less fragrance.
For products manufactured on or after January 1, 2009, a "Personal Fragrance
Product" with 20 percent or less fragrance, that is designed for application all over
the human body to provide a scent. A "Deodorant Body Spray" product that
indicates or depicts on the container or packaging, or on any sticker or label
affixed thereto, that it can be used on or applied to the human axilla, is a
"Deodorant"
"Device" means any instrument or contrivance (other than a firearm) which is designed
for trapping, destroying, repelling, or mitigating any pest or any other form of plant or
animal life (other than man and other than bacterium, virus, or another microorganism on
or in living man or other living animals) but not including equipment used for the
application of pesticides when sold separately therefrom.
"Disinfectant" means any product intended to destroy or irreversibly inactivate infectious
or other undesirable bacteria, pathogenic fungi, or viruses on surfaces or inanimate
objects and whose label is registered under the Federal Insecticide, Fungicide, and
Rodenticide Act (FIFRA, 7 U.S.C. 136, et seq.). "Disinfectant" does not include any of
the following products designed solely for use on human or animals, products designed
for agricultural use, products designed solely for use in swimming pools, therapeutic
tubs, or hot tubs, products which, as indicated on the principal display panel or label, are
designed primarily for use as bathroom and tile cleaners, glass cleaners, general purpose
cleaners, toilet bowl cleaners, or metal polishes.
"Double Phase Aerosol Air Freshener" means an aerosol air freshener with the liquid
contents in two or more distinct phases that require the product container be shaken
before use to mix the phases, producing an emulsion.
"Dry Cleaning Fluid" means any non-aqueous liquid product designed and labeled
exclusively for use on fabrics which are labeled "for dry clean only," such as clothing or
drapery, or "S-coded" fabrics. This includes, but is not limited to, those products used by
commercial dry cleaners and commercial businesses that clean fabrics such as draperies
at the customer's residence or work place. The term does not include "Spot Remover" or
"Carpet and Upholstery Cleaner." For the purposes of this definition, "S-coded fabric"
means an upholstery fabric designed to be cleaned only with water-free spot cleaning
products as specified by the Joint Industry Fabric Standards Committee.
"Dusting Aid" means a product designed to assist in removing dust and other soils from
floors and other surfaces without leaving a wax or silicone based coating. The term does
not include "Pressurized Gas Duster".
13
"Electrical Cleaner" means a product labeled to remove heavy soils such as grease,
grime, or oil from electrical equipment, including, but not limited to, electric motors,
armatures, relays, electric panels, or generators. The term does not include "General
Purpose Cleaner," "General Purpose Degreaser," "Dusting Aid," "Electronic Cleaner,"
"Energized Electrical Cleaner," "Pressurized Gas Duster," "Engine Degreaser," "Anti-
Static Product," or products designed to clean the casings or housings of electrical
equipment.
"Electronic Cleaner" means a product labeled for the removal of dirt, moisture, dust, flux
or oxides from the internal components of electronic or precision equipment such as
circuit boards, and the internal components of electronic devices, including but not
limited to, radios, compact disc (CD) players, digital video disc (DVD) players, and
computers. "Electronic Cleaner" does not include "General Purpose Cleaner," "General
Purpose Degreaser," "Dusting Aid," "Pressurized Gas Duster," "Engine Degreaser,"
"Electrical Cleaner," "Energized Electrical Cleaner," "Anti-Static Product," or products
designed to clean the casings or housings of electronic equipment.
"Energized Electrical Cleaner" means a product that meets both of the following criteria:
The product is labeled to clean and/or degrease electrical equipment, where
cleaning and/or degreasing is accomplished when electrical current exists, or
when there is a residual electrical potential from a component, such as a capacitor;
The product label clearly displays the statements: "Energized Equipment use
only. Not to be used for motorized vehicle maintenance, or their parts."
This does not include "Electronic Cleaner."
"Engine Degreaser" means a cleaning product designed to remove grease, grime, oil and
other contaminants from the external surfaces of engines and other mechanical parts.
"Existing Product" means any formulation of the same product category and form sold,
supplied, manufactured, or offered for sale in Illinois prior to January 1, 2009, or any
subsequently introduced identical formulation.
"Fabric Protectant" means a product designed to be applied to fabric substrates to protect
the surface from soiling from dirt and other impurities or to reduce absorption of liquid
into the fabric's fibers. The term does not include waterproofers, products designed for
use solely on leather, or products designed for use solely on fabrics which are labeled
"for dry clean only" and sold in containers of 10 fluid ounces or less.
"Fabric Refresher" means a product labeled to neutralize or eliminate odors on non-
laundered fabric including, but not limited to, soft household surfaces, rugs, carpeting,
draperies, bedding, automotive interiors, footwear, athletic equipment, clothing and/or on
household furniture or objects upholstered or covered with fabrics such as, but not limited
to, wool, cotton, or nylon. "Fabric Refresher" does not include "Anti-static Product,"
14
"Carpet and Upholstery Cleaner," "Soft Household Surface Sanitizers," "Footwear or
Leather Care Product," "Spot Remover," or "Disinfectant," or products labeled for
application to both fabric and human skin.
For the purposes of this definition only, "Soft Household Surface Sanitizer"
means a product labeled to neutralize or eliminate odors on surfaces listed above
whose label is registered as a sanitizer under the Federal Insecticide, Fungicide,
and Rodenticide Act, (FIFRA, 7 U.S.C. 136 et seq.).
"Facial Cleaner or Soap" means a cleaner or soap designed primarily to clean the face
including, but not limited to facial cleansing creams, semisolids, liquids, lotions, and
substrate-impregnated forms. The term does not include prescription drug products,
"Antimicrobial Hand or Body Cleaner or Soap," "Astringent/Toner," "General-use Hand
or Body Cleaner or Soap," "Medicated Astringent/Medicated Toner," or "Rubbing
Alcohol."
"Fat Wood" means pieces of wood kindling with high naturally-occurring levels of sap or
resin which enhance ignition of the kindling, excluding any kindling with substances
added to enhance flammability, such as wax-covered or wax-impregnated wood-based
products.
"Faux Finishing Coating" means a coating labeled and formulated as a stain or a glaze to
create artistic effects including, but not limited to, dirt, old age, smoke damage, and
simulated marble and wood grain.
"Flea and Tick Insecticide" means any insecticide product that is designed for use against
fleas, ticks, their larvae, or their eggs. The term does not include products that are
designed to be used exclusively on humans or animals and their bedding.
"Flexible Flooring Material" means asphalt, cork, linoleum, no-wax, rubber, seamless
vinyl and vinyl composite flooring.
"Floor Coating" means an opaque coating that is labeled and formulated for application
to flooring, including, but not limited to, decks, porches, steps, and other horizontal
surfaces, which may be subjected to foot traffic.
"Floor Polish or Wax" means a wax, polish, or any other product designed to polish,
protect, or enhance floor surfaces by leaving a protective coating that is designed to be
periodically replenished. The term does not include "Spray Buff Products," products
designed solely for the purpose of cleaning floors, floor finish strippers, products
designed for unfinished wood floors, and coatings subject to architectural coatings
regulations.
"Floor Seam Sealer" means any product designed and labeled exclusively for bonding,
fusing, or sealing (coating) seams between adjoining rolls of installed flexible sheet
flooring.
15
"Floor Wax Stripper" means a product designed to remove natural or synthetic floor
polishes or waxes through breakdown of the polish or wax polymers, or by dissolving or
emulsifying the polish or wax. This does not include aerosol floor wax strippers or
products designed to remove floor wax solely through abrasion.
"Flying Bug Insecticide" means any insecticide product that is designed for use against
flying insects or other flying arthropods, including but not limited to flies, mosquitoes,
moths, or gnats. The term does not include "Wasp and Hornet Insecticide," products that
are designed to be used exclusively on humans or animals, or any moth-proofing product.
For the purposes of this definition only, "Moth-Proofing Product" means a
product whose label, packaging, or accompanying literature indicates that the
product is designed to protect fabrics from damage by moths, but does not
indicate that the product is suitable for use against flying insects or other flying
arthropods.
"Footwear or Leather Care Product" means any product designed or labeled to be applied
to footwear or to other leather articles/components, to maintain, enhance, clean, protect,
or modify the appearance, durability, fit, or flexibility of the footwear or leather
article/component. Footwear includes both leather and non-leather foot apparel.
"Footwear or Leather Care Product" does not include "Fabric Protectant," "General
Purpose Adhesive," "Contact Adhesive," "Vinyl/Fabric/Leather/Polycarbonate Coating,"
"Rubber and Vinyl Protectant," "Fabric Refresher," products solely for deodorizing, or
sealant products with adhesive properties used to create external protective layers greater
than two millimeters thick.
"Fragrance" means a substance or complex mixture of aroma chemicals, natural essential
oils, and other functional components with a combined vapor pressure not in excess of
two mm of Hg at 20°C, the sole purpose of which is to impart an odor or scent, or to
counteract a malodor.
"Furniture Maintenance Product" means a wax, polish, conditioner, or any other product
designed for the purpose of polishing, protecting or enhancing finished wood surfaces
other than floors. The term does not include "Dusting Aids," "Wood Cleaners" and
products designed solely for the purpose of cleaning, and products designed to leave a
permanent finish such as stains, sanding sealers and lacquers.
"Furniture Coating" means any paint designed for application to room furnishings
including, but not limited to, cabinets (kitchen, bath and vanity), tables, chairs, beds, and
sofas.
"Gel" means a colloid in which the disperse phase has combined with the continuous
phase
to
produce
a semisolid material, such as jelly.
16
"General Purpose Adhesive" means any non-aerosol adhesive designed for use on a
variety of substrates. The term does not include contact adhesives, construction, panel,
and floor covering adhesives, adhesives designed exclusively for application on one
specific category of substrates (i.e., substrates that are composed of similar materials,
such as different types of metals, paper products, ceramics, plastics, rubbers, or vinyls),
or adhesives designed exclusively for use on one specific category of articles (i.e., articles
that may be composed of different materials but perform a specific function, such as
gaskets, automotive trim, weather-stripping, or carpets).
"General Purpose Cleaner" means a product designed for general all-purpose cleaning, in
contrast to cleaning products designed to clean specific substrates in certain situations.
This includes products designed for general floor cleaning, kitchen or countertop
cleaning, and cleaners designed to be used on a variety of hard surfaces, and does not
include "General Purpose Degreasers" and "Electronic cleaners."
"General Purpose Degreaser" means any product labeled to remove or dissolve grease,
grime, oil and other oil-based contaminants from a variety of substrates, including
automotive or miscellaneous metallic parts. This does not include "Engine Degreaser,"
"General Purpose Cleaner," "Adhesive Remover," "Electronic Cleaner," "Electrical
Cleaner," "Energized Electrical Cleaner," "Metal Polish/Cleanser," products used
exclusively in "Solvent Cleaning Tanks or Related Equipment," or products that are sold
exclusively to establishments which manufacture or construct goods or commodities, and
labeled "not for retail sale."
"Solvent cleaning tanks or related equipment" includes, but is not limited to, cold
cleaners, vapor degreasers, conveyorized degreasers, film cleaning machines, or
products designed to clean miscellaneous metallic parts by immersion in a
container.
"General-use Hand or Body Cleaner or Soap" means a cleaner or soap designed to be
used routinely on the skin to clean or remove typical or common dirt and soils, including,
but not limited to, hand or body washes, dual-purpose shampoo-body cleaners, shower or
bath gels, and moisturizing cleaners or soaps. The term does not include prescription
drug products, "Antimicrobial Hand or Body Cleaner or Soap," "Astringent/Toner,"
"Facial Cleaner or Soap," "Hand Dishwashing Detergent" (including antimicrobial),
"Heavy-duty Hand Cleaner or Soap," "Medicated Astringent/Medicated Toner," or
"Rubbing Alcohol."
"Glass Cleaner" means a cleaning product designed primarily for cleaning surfaces made
of glass. The term does not include products designed solely for the purpose of cleaning
optical materials used in eyeglasses, photographic equipment, scientific equipment and
photocopying machines.
"Graffiti Remover" means a product labeled to remove spray paint, ink, marker, crayon,
lipstick, nail polish, or shoe polish, from a variety of non-cloth or nonfabric substrates.
The term does not include "Paint Remover or Stripper," "Nail Polish Remover," or "Spot
17
Remover." Products labeled for dual use as both a paint stripper and graffiti remover are
considered "Graffiti Removers.'
"Hair Mousse" means a hairstyling foam designed to facilitate styling of a coiffure and
provide limited holding power.
"Hair Shine" means any product designed for the primary purpose of creating a shine
when applied to the hair. This includes, but is not limited to, dual-use products designed
primarily to impart a sheen to the hair. The term does not include "Hair spray," "Hair
Mousse," "Hair Styling Product," "Hair Styling Gel," or products whose primary purpose
is to condition or hold the hair.
"Hair Styling Gel" means a consumer product manufactured before January 1, 2009, that
is a high viscosity, often gelatinous, product that contains a resin and is designed for the
application to hair to aid in styling and sculpting of the hair coiffure.
"Hair spray" means:
For products manufactured before January 1, 2009, a consumer product designed
primarily for the purpose of dispensing droplets of a resin on and into a hair
coiffure which will impart sufficient rigidity to the coiffure to establish or retain
the style for a period of time, and
For products manufactured on or after January 1, 2009, a consumer product that is
applied to styled hair, and is designed or labeled to provide sufficient rigidity, to
hold, retain and/or (finish) the style of the hair for a period of time. This includes
aerosol hair sprays, pump hair sprays, spray waxes; color, glitter, or sparkle
hairsprays that make finishing claims; and products that are both a styling and
finishing product. This does not include spray products that are intended to aid in
styling but does not provide finishing of a hairstyle. For the purposes of this Part,
"Finish" or "Finishing" means the maintaining and/or holding of previously styled
hair for a period of time. For the purposes of this Part, "Styling" means the
forming, sculpting, or manipulating the hair to temporarily alter the hair's shape.
"Hair Styling Product" means a consumer product manufactured on or after January 1,
2009, that is designed or labeled for the application to wet, damp or dry hair to aid in
defining, shaping, lifting, styling and/or sculpting of the hair. This includes, but is not
limited to hair balm, clay, cream, creme, curl straightener, gel, liquid, lotion, paste,
pomade, putty, root lifter, serum, spray gel, stick, temporary hair straightener, wax, spray
products that aid in styling but do not provide finishing of a hairstyle, and leave-in
volumizers, detanglers and/or conditioners that make styling claims. This does not
include "Hair Mousse" "Hair Shine," "Hair Spray," or shampoos and/or conditioners that
are rinsed from the hair prior to styling. For the purposes of this Part, "Finish" or
"Finishing" means
the maintaining and/or holding of previously styled hair for a period
of time. For the purposes of this Part, "Styling" means the forming, sculpting, or
manipulating the hair to temporarily alter the hair's shape.
18
"Heavy-Duty Hand Cleaner or Soap" means a product designed to clean or remove
difficult dirt and soils such as oil, grease, grime, tar, shellac, putty, printer's ink, paint,
graphite, cement, carbon, asphalt, or adhesives from the hand with or without the use of
water. The term does not include prescription drug products, "Antimicrobial Hand or
Body Cleaner or Soap," "Astringent/Toner," "Facial Cleaner or Soap," "General-use
Hand or Body Cleaner or Soap," "Medicated Astringent/Medicated Toner" or "Rubbing
Alcohol."
"Herbicide" means a pesticide product designed to kill or retard a plant's growth, but
excludes products that are for agricultural use, or restricted materials that require a permit
for use and possession.
"High Volatility Organic Material (HVOM)" or "High Volatility Organic Compound"
means any volatile organic material or volatile organic compound that exerts a vapor
pressure greater than 80 millimeters of Mercury (mm Hg) when measured at 20°C.
"Household Product" means any consumer product that is primarily designed to be used
inside or outside of living quarters or residences that are occupied or intended for
occupation by individuals, including the immediate surroundings.
"Illinois Sales" means the sales (net pounds of product, less packaging and container, per
year) in Illinois for either the calendar year immediately prior to the year that the
registration is due or, if that data is not available, any consecutive 12 month period
commencing no earlier than two years prior to the due date of the registration. If direct
sales data for Illinois is not available, sales may be estimated by prorating national or
regional sales data by population.
"Industrial use" means use for or in a manufacturing, mining, or chemical process or use
in the operation of factories, processing plants, and similar sites.
"Insecticide" means a pesticide product that is designed for use against insects or other
arthropods, but excluding products that are for agricultural use, for a use which requires a
structural pest control license under the Structural Pest Control Act, 225 ILCS 235, or
restricted materials that require a permit for use and possession.
"Insecticide Fogger" means any insecticide product designed to release all or most of its
content, as a fog or mist, into indoor areas during a single application.
"Institutional Product" or "Industrial and Institutional (1&I) Product" means a consumer
product that is designed for use in the maintenance or operation of an establishment that
manufactures, transports, or sells goods or commodities, or provides services for profit,
or is engaged in the nonprofit promotion of a particular public, educational, or charitable
cause. "Establishments" include, but are not limited to, government agencies, factories,
schools, hospitals, sanitariums, prisons, restaurants, hotels, stores, automobile service and
parts centers, health clubs, theaters, or transportation companies. This does not include
19
household products and products that are incorporated into or used exclusively in the
manufacture or construction of the goods or commodities at the site of the establishment.
"Label" means any written, printed, or graphic matter affixed to, applied to, attached to,
blown into, formed, molded into, embossed on, or appearing upon any consumer product
or consumer product package, for purposes of branding, identifying, or giving
information with respect to the product or to the contents of the package.
"Lacquer" means for purposes of Subparts B and C of this Part, a clear or opaque wood
coating, including clear lacquer sanding sealers, formulated with cellulosic or synthetic
resins to dry by evaporation without chemical reaction and to provide a solid, protective
film. For purposes of Subpart D of this Part, "Lacquer" means a thermoplastic film-
forming material dissolved in organic solvent, which dries primarily by solvent
evaporation, and is resoluble in its original solvent.
"Laundry Prewash" means a product that is designed for application to a fabric prior to
laundering and that supplements and contributes to the effectiveness of laundry
detergents and/or provides specialized performance.
"Laundry Starch Product" means a product that is designed for application to a fabric,
either during or after laundering, to impart and prolong a crisp, fresh look and may also
act to help ease ironing of the fabric. This includes, but is not limited to, fabric finish,
sizing, and starch.
"Lawn and Garden Insecticide" means an insecticide product labeled primarily to be used
in household lawn and garden areas to protect plants from insects or other arthropods.
Notwithstanding the requirements of Section 223.260 aerosol "Lawn and Garden
Insecticides" may claim to kill insects or other arthropods.
"Liquid" means a substance or mixture of substances which is capable of a visually
detectable flow as determined under ASTM D-4359-90(2000)el, including any
subsequent amendments or an equivalent method approved by the California Air
Resources Board. This does not include powders or other materials that are composed
entirely of solid particles.
"Lubricant" means a product designed to reduce friction, heat, noise, or wear between
moving parts, or to loosen rusted or immovable parts or mechanisms. This does not
include automotive power steering fluids; products for use inside power generating
motors, engines, and turbines, and their associated power-transfer gearboxes; two cycle
oils or other products designed to be added to fuels; products for use on the human body
or animals; or products that are sold exclusively to establishments which manufacture or
construct goods or commodities, and labeled "not for retail sale."
"LVP Content" means the total weight, in pounds, of LVP compounds in an ACP product
multiplied by 100 and divided by the product's total net weight (in pounds, excluding
container and packaging), expressed to the nearest 0.1.
20
"LVP-VOM" or "LVP-VOC" means a chemical "material" or "mixture" or "compound"
that contains at least one carbon atom and meets one of the following:
Has a vapor pressure less than 0.1 mm Hg at
20°C,
as determined by CARB
Method 310; or
Is a chemical "material" or "compound" with more than
12
carbon atoms, or a
chemical "mixture" comprised solely of "material" or a "compound" with more
than 12
carbon atoms as verified by formulation data, and the vapor pressure and
boiling point are unknown; or
Is a chemical "material" or "compound" with a boiling point greater than
216°C,
as determined by CARE Method 310; or
Is the weight percent of a chemical "mixture" that boils above
216° C, as
determined by CARB Method 310.
For the purposes of the definition of LVP-VOM, chemical "material" or
"compound" means a molecule of definite chemical formula and isomeric
structure, and chemical "mixture" means a substrate comprised of two or more
chemical "materials" or "compounds."
"Medicated Astringent /Medicated Toner" means any product regulated as a drug by the
FDA which is applied to the skin for the purpose of cleaning or tightening pores. This
includes, but is not limited to, clarifiers and substrate-impregnated products. The term
does not include hand, face, or body cleaner or soap products, "Astringent/Toner," cold
cream, lotion, antiperspirants, or products that must be purchased with a doctor's
prescription.
"Medium Volatility Organic Material (MVOM)" or "Medium Volatility Organic
Compound (MVOC)" means any volatile organic material or volatile organic compound
that exerts a vapor pressure greater than two mm Hg and less than or equal to 80 mm Hg
when measured at
20°C.
"Metal Polish /Cleanser" means any product designed primarily to improve the
appearance of finished metal, metallic, or metallized surfaces by physical or chemical
action. To "improve the appearance" means to remove or reduce stains, impurities, or
oxidation from surfaces or to make surfaces smooth and shiny. This includes, but is not
limited to, metal polishes used on brass, silver, chrome, copper, stainless steel and other
omamental metals. The term does not include "Automotive Wax, Polish, Sealant or
Glaze," wheel cleaner, "Paint Remover or Stripper," products designed and labeled
exclusively for automotive and marine detailing, or products designed for use in
degreasing tanks.
21
"Mist Spray Adhesive" means any aerosol which is not a special purpose spray adhesive
and which delivers a particle or mist spray, resulting in the formation of fine, discrete
particles that yield a generally uniform and smooth application of adhesive to the
substrate.
"Multi-purpose Dry Lubricant" means any lubricant which is designed and labeled to
provide lubricity by depositing a thin film of graphite, molybdenum disulfide ("moly"),
or polytetrafluoroethylene or closely related fluoropolymer ("teflon") on surfaces, and
designed for general purpose lubrication, or for use in a wide variety of applications.
"Multi-purpose Lubricant" means any lubricant designed for general purpose lubrication,
or for use in a wide variety of applications. The term does not include "Multi-purpose
Dry Lubricants," "Penetrants," or "Silicone-based Multi-purpose Lubricants."
"Multi-purpose Solvent" means any organic liquid designed to be used for a variety of
purposes, including cleaning or degreasing of a variety of substrates, or thinning,
dispersing or dissolving other organic materials. This includes solvents used in
institutional facilities, except for laboratory reagents used in analytical, educational,
research, scientific or other laboratories. This does not include solvents used in cold
cleaners, vapor degreasers, conveyorized degreasers or film cleaning machines, or
solvents that are incorporated into, or used exclusively in the manufacture or construction
of the goods or commodities at the site of the establishment.
"Nail Polish" means any clear or colored coating designed for application to the
fingernails or toenails and including but not limited to lacquers, enamels, acrylics, base
coats and top coats.
"Nail Polish Remover" means a product designed to remove nail polish and coatings
from fingernails or toenails.
"Non-aerosol Product" means any consumer product that is not dispensed by a
pressurized spray system.
"Non-Carbon Containing Compound" means any compound which does not contain any
carbon atoms.
"Nonresilient Flooring" means flooring of a mineral content which is not flexible. This
includes terrazzo, marble, slate, granite, brick, stone, ceramic tile and concrete.
"Non-Selective Terrestrial Herbicide" means a terrestrial herbicide product that is toxic
to plants without regard to species.
"Oven Cleaner" means any cleaning product designed to clean and to remove dried food
deposits from oven walls.
22
"Paint" means any pigmented liquid, liquefiable, or mastic composition designed for
application to a substrate in a thin layer which is converted to an opaque solid film after
application and is used for protection, decoration or identification, or to serve some
functional purpose such as the filling or concealing of surface irregularities or the
modification of light and heat radiation characteristics.
"Paint Remover or Stripper" means any product designed to strip or remove paints or
other related coatings, by chemical action, from a substrate without markedly affecting
the substrate. This does not include "Multi-purpose Solvents," paint brush cleaners,
products designed and labeled exclusively as "Graffiti Removers," and hand cleaner
products that claim to remove paints and other related coatings from skin.
"Penetrant" means a lubricant designed and labeled primarily to loosen metal parts that
have bonded together due to rusting, oxidation, or other causes. The term does not
include "Multi-purpose Lubricants" that claim to have penetrating qualities, but are not
labeled primarily to loosen bonded parts.
"Personal Fragrance Product" means any product which is applied to the human body or
clothing for the primary purpose of adding a scent or masking a malodor, including
cologne, perfume, aftershave, and toilet water. This does not include "Deodorant,"
medicated products designed primarily to alleviate fungal or bacterial growth on feet or
other areas of the body; mouthwashes, breath fresheners and deodorizers; lotions,
moisturizers, powders or other skin care products used primarily to alleviate skin
conditions such as dryness and irritations; products designed exclusively for use on
human genitalia; soaps, shampoos, and products primarily used to clean the human body;
and fragrance products designed to be used exclusively on non-human animals.
"Pesticide" means and includes any substance br mixture of substances labeled, designed,
or intended for use in preventing, destroying, repelling or mitigating any pest, or any
substance or mixture of substances labeled, designed, or intended for use as a defoliant,
desiccant, or plant regulator, provided that the term "Pesticide" will not include any
substance, mixture of substances, or device which the United States Environmental
Protection Agency does not consider to be a pesticide.
"Photograph Coating" means a coating designed and labeled exclusively to be applied to
finished photographs to allow corrective retouching, protection of the image, changes in
gloss level, or to cover fingerprints.
"Pressurized Gas Duster" means a pressurized product labeled to remove dust from a
surface solely by means of mass air or gas flow, including surfaces such as photographs,
photographic film negatives, computer keyboards, and other types of surfaces that cannot
be cleaned with solvents. This does not include "Dusting Aid."
"Principal Display Panel or Panels" means that part, or those parts of a label that are so
designed as to most likely be displayed, presented, shown or examined under normal and
customary conditions of display or purchase. Whenever a principal display panel appears
23
more than once, all requirements pertaining to the "Principal Display Panel" shall pertain
to all such "Principal Display Panels."
"Product Brand Name" means the name of the product exactly as it appears on the
principal display panel of the product.
"Product Category" means the applicable category which best describes the product as
listed in this Section 223.203 and in the limits in Section 223.205(a).
"Product Form" for the purpose of complying with Section 223.270 only, means the
applicable form which most accurately describes the product's dispensing form as
follows:
A = Aerosol Product
S = Solid
P = Pump Spray
L = Liquid
SS = Semisolid
0 = Other
"Product Line" means a group of products of identical form and function belonging to the
same product category(ies).
"Pump Spray" means a packaging system in which the product ingredients within the
container are not under pressure and in which the product is expelled only while a
pumping action is applied to a button, trigger or other actuator.
"Responsible ACP Party" means the company, firm or establishment which is listed on
the ACP product's label. If the label lists two or more companies, firms, or
establishments, the "Responsible ACP Party" is the party which the ACP product was
"manufactured for" or "distributed by," as noted on the label.
"Restricted Materials" means pesticides established as restricted materials under
applicable Illinois Laws or Regulations.
"Roll-on Product" means any antiperspirant or deodorant that dispenses active
ingredients by rolling a wetted ball or wetted cylinder on the affected area.
"Rubber and Vinyl Protectant" means any product designed to protect, preserve or renew
vinyl, rubber, and plastic on vehicles, tires, luggage, furniture, and household products
such as vinyl covers, clothing, and accessories. This does not include products primarily
designed to clean the wheel rim, such as aluminum or magnesium wheel cleaners, and
tire cleaners that do not leave an appearance-enhancing or protective substance on the
tire.
24
"Rubbing Alcohol" means any product containing isopropyl alcohol (also called
isopropanol) or denatured ethanol and labeled for topical use, usually to decrease germs
in minor cuts and scrapes, to relieve minor muscle aches, as a rubefacient, and for
massage.
"Rust Preventive Coating" means a coating formulated exclusively for nonindustrial use
to prevent the corrosion of metal surfaces and labeled as specified in Section 223.320(f).
"Sanding Sealer" means for purposes of this Part, a clear or semi-transparent wood
coating labeled and formulated for application to bare wood to seal the wood and to
provide a coat that can be abraded to create a smooth surface for subsequent applications
of coatings. A "Sanding Sealer" that also meets the definition of a "Lacquer" is not
included in this category, but it is included in the "Lacquer" category.
"Sealant and Caulking Compound" means any product with adhesive properties that is
designed to fill, seal, waterproof, or weatherproof gaps or joints between two surfaces.
This does not include roof cements and roof sealants, insulating foams, removable
caulking compounds, clear/paintable/water resistant caulking compounds, floor seam
sealers, products designed exclusively for automotive uses, or sealers that are applied as
continuous coatings. The term also does not include units of product, less packaging,
which weigh more than one pound and consist of more than 16 fluid ounces.
For the purposes of this definition only, "removable caulking compounds" means
a compound which temporarily seals windows or doors for three to six month
time intervals, and "clear/paintable/water resistant caulking compounds" means a
compound which contains no appreciable level of opaque fillers or pigments;
transmits most or all visible light through the caulk when cured; is paintable; and
is immediately resistant to precipitation upon application.
"Semisolid" means a product that, at room temperature, will not pour, but will spread or
deform easily, including but not limited to gels, pastes, and greases.
"Shaving Cream" means an aerosol product which dispenses a foam lather intended to be
used with a blade or cartridge razor, or other wet-shaving system, in the removal of facial
or other bodily hair. The term does not include "Shaving Gel."
"Shaving Gel" means an aerosol product which dispenses a post-foaming semisolid
designed to be used with a blade, cartridge razor, or other shaving system in the removal
of facial or other bodily hair. This does not include "Shaving Cream."
"Silicone-based Multi-purpose Lubricant" means any lubricant which is designed and
labeled to provide lubricity primarily through the use of silicone compounds including,
but not limited to, polydimethylsiloxane; and designed and labeled for general purpose
lubrication, or for use in a wide variety of applications. The term does not include
products designed and labeled exclusively to
release manufactured products from molds.
25
"Single Phase Aerosol Air Freshener" means an aerosol air freshener with the liquid
contents in a single homogeneous phase and which does not require that the product
container be shaken before use.
"Solid" means a substance or mixture of substances which, either whole or subdivided
(such as the particles comprising a powder), is not capable of visually detectable flow as
determined under ASTM D-4359-90(2000)el, or an equivalent method approved by the
California Air Resources Board.
"Special Purpose Spray Adhesive" means an aerosol adhesive that meets any of the
following definitions:
"Mounting Adhesive" means an aerosol adhesive designed to permanently mount
photographs, artwork, and any other drawn or printed media to a backing (paper,
board, cloth, etc.) without causing discoloration to the artwork.
"Flexible vinyl adhesive" means an aerosol adhesive designed to bond flexible
vinyl to substrates. Flexible vinyl means a nonrigid polyvinyl chloride plastic
with at least five percent, by weight, of plasticizer content. A plasticizer is a
material, such as a high boiling point organic solvent, that is incorporated into a
plastic to increase its flexibility, workability, or distensibility, and may be
determined using ASTM Method E260-91, or from product formulation data or an
equivalent method approved by the CARB.
"Polystyrene Foam Adhesive" means an aerosol adhesive designed to bond
polystyrene foam to substrates.
"Automobile Headliner Adhesive" means an aerosol adhesive designed to bond
together layers in motor vehicle headliners.
"Polyolefin Adhesive" means an aerosol adhesive designed to bond polyolefins to
substrates.
"Laminate Repair/Edgebanding Adhesive" means an aerosol adhesive designed
for:
The touch-up or repair of items laminated with high pressure laminates
(e.g., lifted edges, delaminates, etc.); or
The touch-up, repair, or attachment of edgebanding materials, including
but not limited to, other laminates, synthetic marble, veneers, wood
molding, and decorative metals.
For the purposes of this definition "high pressure laminate" means sheet
materials which consist of paper, fabric, or other core material that have
26
been laminated at temperatures exceeding 265 degrees F, and at pressures
between 1,000 and 1,400 psi.
"Automotive Engine Compartment Adhesive" means an aerosol adhesive
designed for use in motor vehicle under-the-hood applications which require oil
and plasticizer resistance, as well as high shear strength, at temperatures of 200 -
275 degrees F.
"Spot Remover" means any product labeled to clean localized areas, or remove localized
spots or stains on cloth or fabric such as drapes, carpets, upholstery, and clothing, that
does not require subsequent laundering to achieve stain removal. This does not include
"Dry Cleaning Fluid," "Laundry Prewash," or "Multi-purpose Solvent."
"Spray Buff Product" means a product designed to restore a worn floor finish in
conjunction with a floor buffing machine and special pad.
"Stick Product" means any antiperspirant or deodorant that contains active ingredients in
a solid matrix form, and that dispenses the active ingredients by frictional action on the
affected area.
"Structural Waterproof Adhesive" means an adhesive whose bond lines are resistant to
conditions of continuous immersion in fresh or salt water, and that conforms with Federal
Specification MMM-A-181D (Type 1, Grade A), and MIL-A-4605 (Type A, Grade A
and Grade C), per the Federal Consumer Products Regulation 40 CFR59 Subpart C.
"Terrestrial" means to live on or grow from land.
"Tire Sealant and Inflation" means any pressurized product that is designed to
temporarily inflate and seal a leaking tire.
"Toilet/Urinal Care Product" means any product designed or labeled to clean and/or to
deodorize toilet bowls, toilet tanks, or urinals. Toilet bowls, toilet tanks, or urinals
includes, but is not limited to, toilets or urinals connected to permanent plumbing in
buildings and other structures, portable toilets or urinals placed at temporary or remote
locations, and toilet or urinals in vehicles such as buses, recreational motor homes, boats,
ships, and aircraft. This does not include "Bathroom and Tile Cleaner" or "General
Purpose Cleaner."
"Type A Propellant" means a compressed gas such as CO
2, N2 , N2
0, or compressed air
which is used as a propellant, and is either incorporated with the product or contained in a
separate chamber within the product's packaging.
"Type B Propellant" means any halocarbon which is used as a propellent including
chlorofluorocarbons (CFCs), hydrochlorofluorocarbons (HCFCs), and
hydrofluorocarbons (HFCs).
27
"Type C Propellant" means any propellent which is not a Type A or Type
B propellant,
including propane, isobutane, n-butane, and dimethyl ether (also known as dimethyl
oxide).
"Undercoating" means any aerosol product designed to impart a protective, non-paint
layer to the undercarriage, trunk interior, and/or firewall of motor vehicles to prevent the
formation of rust or to deaden sound. This includes, but is not limited to, rubberized,
mastic, or asphaltic products.
"Usage Directions" means the text or graphics on the product's principal display panel,
label, or accompanying literature which describes to the end user how and in what
quantity the product is to be used.
"VOM Content" means, for purposes of Subpart B of this Part, except for charcoal lighter
products, the total weight of VOM in a product expressed as a percentage of the product
weight (exclusive of the container or packaging), as determined pursuant to Section
223.285(a) and (b).
For charcoal lighter material products only,
VOC Content –
(Certified Emissions x 100)
Certified Use Rate
Certified
Emissions?
The emissions level for products approved by the
Agency under Section 223.220, as determined pursuant to
South Coast Air Quality Management District Rule 1174
Ignition Method Compliance Certification Protocol
(February 27, 1991), expressed to the nearest 0.001 pound
CH2
per start.
Certified
Use Rate
The usage level for products approved by the
Agency under Section 223.220, as determined pursuant to
South Coast Air Quality Management District Rule 1174
Ignition Method Compliance Certification Protocol
(February 27, 1991), expressed to the nearest 0.001 pound
certified product used per start.
For purposes of Subpart C of this Part, "VOM Content" means the weight of
VOM per volume of coating, calculated according to the procedures specified in
subsection 223.340(a).
"Wasp and Hornet Insecticide" means any insecticide product that is designed for use
against wasps, hornets, yellow jackets or bees by allowing the user to spray from a
distance a directed stream or burst at the intended insects, or their hiding place.
28
"Waterproofer" means a product designed and labeled exclusively to repel water from
fabric or leather substrates, excluding "Fabric Protectants".
"Wax" means a material or synthetic thermoplastic substance generally of high molecular
weight hydrocarbons or high molecular weight esters of fatty acids or alcohols, except
glycerol and high polymers (plastics). This includes, but is not limited to, substances
derived from the secretions of plants and animals such as carnuba wax and beeswax,
substances of a mineral origin such as ozocerite and paraffin, and synthetic polymers
such as polyethylene.
"Web Spray Adhesive" means any aerosol adhesive which is not a mist spray or special
purpose spray adhesive.
"Wood Cleaner" means a product labeled to clean wooden materials including but not
limited to decking, fences, flooring, logs, cabinetry, and furniture. The term does not
include "Dusting Aid," "General Purpose Cleaner," "Furniture Maintenance Product,"
"Floor Wax Stripper," "Floor Polish or Wax," or products designed and labeled
exclusively to preserve or color wood.
"Wood Floor Wax" means wax-based products for use solely on wood floors.
Section 223.205 Standards
a) Except
as provided in Section 223.207, Section 223.230, Section 223.240, or
Section 223.245, no person shall sell, supply, offer for sale, or manufacture for
sale in Illinois any consumer product manufactured on or after January 1, 2009,
which contains VOMs in excess of the limits specified below:
Affected Product
%
VOM by Weight
1) Adhesives - Aerosol
A) Mist Spray
65
B)
Web Spray
55
C)
Special Purpose Spray Adhesives
i)
Mounting, Automotive Engine Compartment, and
Flexible Vinyl
70
ii)
Polystyrene Foam and Automotive Headliner
65
iii)
Polyolefin and Laminate Repair / Edgebanding
60
29
?
2)?
Adhesive Removers
A)
Floor or Wall Covering
?
5
B)
Gasket or Thread Locking
?
50
C)
General Purpose
?
20
D)
Specialty?
70
?
3)
?
Adhesives - Construction, Panel, and Floor Contact
? 15
?
4)?
Adhesives - General Purpose
?
10
?
5)?
Adhesives – Structural Waterproof
?
15
?
6)?
Adhesives
A)
Contact General Purpose
?
55
B)
Contact Special Purpose
?
80
?
7)?
Air Fresheners
A)
Single-Phase Aerosol?
30
B)
Double Phase Aerosol
?
25
C)
Liquids / Pump Sprays
?
18
D)
Solids / Semisolids
?
3
?
8)
?
Antiperspirants
A) Aerosol
?
40 HVOM
10 MVOM
B)
Non-Aerosol
?
0 HVOM
0 MVOM
?
9)?
Anti-Static Non-Aerosol
?
11
?
10)?
Automotive Brake Cleaners
?
45
?
11)?
Automotive Rubbing or Polishing Compound
?
17
30
12)
?
Automotive Wax, Polish, Sealant, or Glaze
A)
Hard Paste Waxes?
45
B)
Instant Detailers?
3
C)
All Other Forms
?
15
13)?
Automotive Windshield Washer Fluids
?
35
14)?
Bathroom and Tile Cleaners
A) Aerosol?
7
B)
All Other Forms?
5
15) Bug and Tar Remover
?
40
16)?
Carburetor or Fuel-Injection Air Intake Cleaners
?
45
17)?
Carpet and Upholstery Cleaners
A)
Aerosol
?
7
B)
Non-Aerosol (Dilutables)
?
0.1
C)
Non-Aerosol (Ready-to-Use)
?
3.0
18)?
Charcoal Lighter Material
?
see Section 223.220
19)
?
Cooking Spray – Aerosol
?
18
20)?
Deodorants
A)
Aerosol
?
0 HVOM
10 MVOM
B)
Non-Aerosol
?
0 HVOM
0 MVOM
21)?
Dusting Aides
A)
Aerosol
?
25
B)
All Other Forms?
7
31
?
22)?
Electrical Cleaner?
45
?
23)?
Electronic Cleaner
?
75
?
24)?
Engine Degreasers
A) Aerosol?
35
B) Non-Aerosol?
5
?
25)
?
Fabric Protectants
?
60
?
26)
?
Fabric Refresher
A)
Aerosol
?
15
B)
Non-aerosol
?
6
?
27)?
Floor Polishes / Waxes
A)
Products for Flexible Flooring Materials
?
7
B)
Products for Nonresilient Flooring
?
10
C)
Wood Floor Wax
?
90
?
28)?
Floor Wax Strippers
?
see Section 223.209
?
29)?
Footwear or Leather Care Products
A)
Aerosol
?
75
B) Solid?
55
C)
Other forms
?
15
?
30)?
Furniture Maintenance Products
A)
Aerosol
?
17
B)
All Other Forms Except Solid or Paste
?
7
?
31)?
General Purpose Cleaners
A)?
Aerosol
?
10
32
B)?
Non-Aerosol
?
4
?
32)
?
General Purpose Degreasers
A)
Aerosol?
50
B) Non-Aerosol?
4
?
33)?
Glass Cleaners
A)
Aerosol
?
12
B)
Non-Aerosol
?
4
?
34)
?
Graffiti Remover
A)
Aerosol
?
50
B)
Non-Aerosol
?
30
?
35)?
Hair Mousses?
6
?
36)?
Hairshines
?
55
?
37)?
Hairsprays
?
55
?
38)
?
Hair Styling Gels?
6
?
39)
?
Hair Styling Products
A)
Aerosol and Pump Sprays
?
6
B)
All other forms
?
2
?
40)?
Heavy Duty Hand Cleaner or Soap
?
8
?
41)
?
Insecticides
A)
Crawling Bug (Aerosol)
?
15
B)
Crawling Bug (All Other Forms)
?
20
C)
Flea and Tick
?
25
33
D)
Flying Bug (Aerosol)?
25
E)
Flying Bug (All Other Forms)
?
35
F) Foggers?
45
G)
Lawn and Garden (Aerosol)
?
20
H)
Lawn and Garden (All Other Forms)?
3
I)
Wasp and Hornet
?
40
?
42)
?
Laundry Prewash
A)
Aerosols / Solids
?
22
B) All Other Forms?
5
?
43)?
Laundry Starch Products
?
5
?
44)
?
Metal Polishes / Cleansers?
30
?
45)?
Multi-Purpose Lubricant
(Excluding Solid or Semi-Solid Products)
?
50
?
46)?
Nail Polish Removers
?
75
?
47)?
Non-Selective Terrestrial Herbicide - Non-Aerosol
?
3
?
48)?
Oven Cleaners
A)
Aerosols / Pump Sprays?
8
B)
Liquids?
5
?
49)?
Paint Remover or Strippers
?
50
?
50)?
Penetrants?
50
?
51)?
Rubber and Vinyl Protectants
A)
Aerosol
?
10
B)
Non-Aerosol?
3
?
52)?
Sealants and Caulking Compounds
?
4
34
53)
?
Shaving Creams
?
5
54)?
Shaving Gel
?
7
55)?
Silicone-Based Multi-Purpose Lubricants
(Excluding Solid or Semi-Solid Products)
?
60
56)?
Spot Removers
A) Aerosol?
25
B) Non-Aerosol?
8
57)?
Tire Sealants and Inflators
?
20
58)?
Toilet/Urinal Care
A)
Aerosol
?
10
B)
Non-Aerosol
?
3
59)?
Undercoatings – Aerosols
?
40
60)?
Wood Cleaner
A)
Aerosol?
17
B)
Non-Aerosol
?
4
b)?
No person shall sell, supply, offer for sale, or manufacture for sale in Illinois, on
or after January
1, 2009,
any antiperspirant or deodorant that contains any
compound listed below:
Benzene
Ethylene Dibromide
Ethylene Dichloride
Hexavalent Chromium
Asbestos
Cadmium (metallic cadmium and cadmium compounds)
Carbon Tetrachloride
Trichloroethylene
Chloroform
Vinyl Chloride
Inorganic Arsenic
35
Nickel (metallic nickel and inorganic nickel compounds)
Perchloroethylene
Formaldehyde
1,3-Butadiene
Inorganic Lead
Dibenzo-p-dioxins and dibenzofurans chlorinated in the 2,3,7 and 8
positions and containing 4,5,6 or 7 chlorine atoms
Section
223.206?
Diluted Products
a)?
For consumer products for which the label, packaging, or accompanying literature
specifically states that the product should be diluted with water or non-VOM
solvent prior to use, the limits specified in Section 223.205(a) must apply to the
product only after the minimum recommended dilution has taken place.
For purposes of subsection (a) of this Section, the minimum recommended
dilution shall not include recommendations for incidental use of a concentrated
product to deal with limited special applications such as hard-to-remove soils or
stains.
c)
For consumer products for which the label, packaging, or accompanying literature
states that the product should be diluted with any VOM solvent prior to use, the
limits specified in Section 223.205(a) shall apply to the product only after the
maximum recommended dilution has taken place.
Section
223.207?
Products registered under FIFRA
For those consumer products that are registered under the Federal Insecticide, Fungicide, and
Rodenticide Act, (FIFRA, 7 U.S.C. Section 136-136y), the effective date of the VOM standards
will be January 1, 2010.
Section 223.208
?
Requirements for Aerosol Adhesives
a)
As specified in California Code section 41712(h)(2), the standards for aerosol
adhesives apply to all uses of aerosol adhesives, including consumer, industrial,
and commercial uses. Except
as
otherwise provided in Sections 223.207,
223.230, 223.240, 223.245, and 223.207, no person shall sell, supply, offer for
sale, use or manufacture for sale in Illinois any aerosol adhesive which, at the
time of sale, use, or manufacture, contains VOMs in excess of the specified
standard.
b)
"Special Purpose Spray Adhesive."
1)?
In order to qualify as a "Special Purpose Spray Adhesive" the product
must meet one or more of the definitions for "Special Purpose Spray
Adhesive" specified in Section 223.203, but if the product label
36
indicates that the product is suitable for use on any substrate or application
not listed in one of the definitions for "Special Purpose Spray Adhesive,"
then the product shall be classified as either a "Web Spray Adhesive" or a
"Mist Spray Adhesive."
2)
?
If a product meets more than one of the definitions specified in Section
223.203 for "Special Purpose Spray Adhesive" and is not classified as a
"Web Spray Adhesive" or "Mist Spray Adhesive" under Section 223.203,
then the VOC limit for the product shall be the lowest applicable VOM
limit specified in Section 223.205(a).
c)
Effective January 1, 2009, no person shall sell, supply, offer for sale, or
manufacture for use in Illinois any aerosol adhesive which contains any of the
following compounds: methylene chloride, perchloroethylene, or
trichloroethylene.
d)
All aerosol adhesives must comply with the labeling requirements specified in
Section 223.265.
Section 223.209?
Requirements for Floor Wax Strippers
On or after January 1, 2009, no person shall sell, supply, offer for sale, or manufacture for use in
Illinois any floor wax stripper unless the following requirements are met:
a)
The label of each non-aerosol floor wax stripper must specify a dilution ratio for
light or medium build-up of polish that results in an as-used VOM concentration
of three percent by weight or less;
b)
If a non-aerosol floor wax stripper is also intended to be used for removal of
heavy build-up of polish, the label of that floor wax stripper must specify a
dilution ratio for heavy build-up of polish that results in an as-used VOM
concentration of 12% by weight or less; and
c)
The terms "light build-up," "medium build-up," or "heavy build-up" are not
specifically required, as long as comparable terminology is used.
Section
223.210?
Products Containing Ozone-Depleting Compounds
a)?
For any consumer product for which standards are specified under Section
223.205(a), no person shall sell, supply, offer for sale, or manufacture for sale in
Illinois any consumer product which contains any of the following ozone-
depleting compounds:
1)
Trichlorofluoromethane (CFC-11);
2)
Dichlorodifluoromethane (CFC-12);
37
3)
1,1,1 -trichloro-2,2,2-tri fluoroethane (CFC- 113);
4)
1-chloro-1,1 -di fluoro-2-chloro-2,2-di fluoroethane (CFC-114);
5)
Chloropentafluoroethane (CFC-I15);
6)
Bromochlorodifluoromethane (Halon 1211);
7)
Bromotrifluoromethane (Halon 1301);
8)
Dibromotetrafluoroethane (Halon 2402);
9)
Chlorodifluoromethane (HCFC-22);
10)
2,2- dichloro - 1,1,1 -tri fluoroethane (HCFC-123);
11)
2-chloro- 1, 1,1,2-tetrafluoroethane (HCFC- 124);
12)
1,1 -dichloro -1- fluor° ethane (HCFC-141b);
13)
1-chloro-1,1 - di fluoroethane (HCFC-142b);
14)
1,1,1 -trichloroethane; and
15)
Carbon tetrachloride.
b)
The requirements in subsection (a) of this Section, shall not apply to any product
formulation existing as of January 1, 2009, that complies with Section 223.205(a)
or is reformulated to meet Section 223.205(a), provided the ozone-depleting
compound content of the reformulated product does not increase.
c)
The requirements in subsection (a) of this Section shall not apply to any ozone
depleting compounds that may be present as impurities in a consumer product in
an amount equal to or less than 0.01% by weight of the product.
Section
223.220
Requirements for Charcoal Lighter Material
a) No
person shall sell, supply, or offer for sale on or after January 1, 2009, any
charcoal lighter material product unless at the time of the transaction the
manufacturer can demonstrate that they have been issued an effective certification
by the CARB under the Consumer Products provisions under Subchapter 8.5,
Article 2, Section 94509(h), of Title 17 of the California Code of Regulations.
This certification remains in effect for Illinois for as long as the CARB
certification remains in effect.
38
b)
Alternatively, the person may demonstrate that at the time of the transaction the
manufacturer had been issued a certification by an air pollution agency of another
state and the USEPA that was current at the time of the transaction.
c)
Upon request by the Agency, a manufacturer claiming to have a certification as
specified in subsection (a) of this Section, must submit to the Agency a copy of
the certification decision, including all conditions applicable to the certification
established by CARB or the air pollution agency of another state and the USEPA.
Section
223.230
Exemptions
a)
This regulation shall not apply to any consumer product manufactured in Illinois
for shipment and use outside of Illinois, as long as the manufacturer or distributor
can demonstrate both that the consumer product is intended for shipment and use
outside of Illinois, and that the manufacturer or distributor has taken reasonable,
prudent precautions to assure that the consumer product is not distributed to
Illinois. This exemption shall not apply to consumer products that are sold,
supplied, or offered for sale by any person to retail outlets in Illinois.
b)
For antiperspirants or deodorants, ethanol shall not be considered a medium
volatility organic material (MVOM) for purposes of the content standards
specified in Section 223.205(a).
c)
The VOM limits specified in Section 223.205(a) shall not apply to fragrances up
to a combined level of two percent by weight contained in any consumer product
and shall not apply to colorants up to a combined level of two percent by weight
contained in any antiperspirant or deodorant.
d)
The requirements of Section 223.205(a) for antiperspirants or deodorants shall not
apply to those volatile organic materials that contain more than 10 carbon atoms
per molecule and for which the vapor pressure is unknown, or that have a vapor
pressure of two mm Hg or less at 20°C.
e)
The VOM limits specified in Section 223.205(a) shall not apply to any LVP-
VOM.
The requirements of Section 223.250 shall not apply to consumer products
registered under the Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA,
7 U.S.C. Section 136/136y).
The VOM limits specified in Section 223.205(a) shall not apply to air fresheners
that are comprised entirely of fragrance, less compounds not defined as VOMs
under Section 211.7150 or exempted under subsection 223.230W.
h) The
VOM limits specified in Section 223.205(a) shall not apply to insecticides
containing at least 98% para-dichlorobenzene;
39
i)
The VOM limits specified in Section 223.205(a) shall not apply to adhesives sold
in containers of one fluid ounce or less.
j)
The VOM limits specified in Section 223.205(a) shall not apply to bait station
insecticides. For the purpose of this section, bait station insecticides are
containers enclosing an insecticidal bait that is not more than 0.5 ounce by
weight, where the bait is designed to be ingested by insects and is composed of
solid material feeding stimulants with less than five percent active ingredients.
Section 223.240?
Innovative Product Exemption
a)
Any manufacturer of consumer products which have been granted an Innovative
Product exemption by the CARB under the Innovative Products provisions in
Subchapter 8.5, Article 2, Section 94511, or Subchapter 8.5, Article 1, Section
94503.5 of Title 17 of the California Code of Regulations shall be exempt from
the limits in 223.205(a) for the period of time that the CARB Innovative Products
exemption remains in effect, provided that all consumer products within the
CARB Innovative Products exemption are contained in the limits in 223.205(a) of
this regulation. Any manufacturer claiming such an exemption on this basis must
submit to the Agency a copy of the CARB Innovative Product exemption decision
(i.e., the Executive Order), including all conditions established by CARB
applicable to the exemption.
b)
Recordkeeping and Availability of Requested Information.
1)
All information specified in the innovative product exemption approving
an innovative product application shall be maintained by the responsible
party for a minimum of three years after the expiration of such exemption.
Such records shall be clearly legible and maintained in good condition
during this period.
2)
The records specified in (1) of this subsection shall be made available to
the Agency, or its authorized representative, upon request.
Section
223.245
?
Alternative Compliance Plans
a)
The purpose of this section is to provide an alternative method to comply with the
limits in Section 223.205(a). This alternative is provided by allowing responsible
ACP parties the option of voluntarily entering into separate ACPs for consumer
products, as specified in this Subpart. Only responsible ACP parties for consumer
products may enter into an ACP.
b)
Any manufacturer of consumer products which have been granted an ACP
Agreement by the CARB under the provisions in Subchapter 8.5, Article 4,
Sections 94540-94555, of Title 17 of the California Code of Regulations shall be
40
exempt from the limits in Section 223.205(a) for the period of time that the
CARB ACP Agreement remains in effect provided that all ACP Products used for
emissions credits within the CARB ACP Agreement are contained in Section
223.205(a) of this regulation. Any manufacturer claiming such an ACP
Agreement on this basis must submit to the Agency a copy of the CARB ACP
decision (i.e., the Executive Order), including all conditions established by CARB
applicable to the exemption.
c) Recordkeeping
and Availability of Requested Information.
1)
All information specified in the ACP Agreement approving an ACP shall
be maintained by the responsible ACP party for a minimum of three years
after the expiration of such ACP. Such records shall be clearly legible and
maintained in good condition during this period.
2)
The records specified in (1) of this subsection shall be made available to
the Agency or its authorized representative upon request.
Section 223.250 Product
Dating
a)
Each manufacturer of a consumer product subject to Section 223.205(a) shall
clearly display on each consumer product container or package, the day, month,
and year on which the product was manufactured, or a code indicating such date.
b)
A manufacturer who uses the following code to indicate the date of manufacture
shall not be subject to the requirements of Section 223.255(a), if the code is
represented separately from other codes on the product container so that it is
easily recognizable:
YY DDD = year year day day day
Where:
YY = Two digits representing the year in which the product was manufactured,
DDD = Three digits representing the day of the year on which the product was
manufactured, with "001" representing the first day of the year, "002"
representing the second day of the year, and so forth (i.e., the "Julian
date")
c)
This date or code shall be displayed on each consumer product container or
package no later than twelve months prior to the effective date of the applicable
standard specified in Section 223.205(a).
d)
The date or datecode information shall be located on the container or inside the
cover/cap so that
it
is readily observable or obtainable by simply removing the
41
cap/cover without irreversibly disassembling any part of the container or
packaging. For the purposes of this subsection, information may be displayed on
the bottom of a container as long as it is clearly legible without removing any
product packaging.
e)?
The requirements of this Section 223.250 shall not apply to products containing
no VOMs (as defined in Section 223.203), or containing VOMs at 0.10% by
weight or less.
Section 223.255?
Additional Product Dating Requirements
a)
?
If a manufacturer uses a code other than specified in 223.250(b) indicating the
date of manufacture for any consumer product subject to Section 223.205(a), an
explanation of the date portion of the code must be filed with the Agency no later
than 12 months prior to the effective date of the applicable standard specified in
Section 223.205.
b)?
If a manufacturer changes any code indicating the date of manufacture for any
consumer product subject to Section 223.255(a), an explanation of the modified
code must be submitted to the Agency before any products displaying the
modified code are sold, supplied, or offered for sale in Illinois.
c)
?
No person shall erase, alter, deface, or otherwise remove or make illegible any
date or code indicating the date of manufacture from any regulated product
container without the express authorization of the manufacturer. No manufacturer
shall affix a date-code that is not true for the date the item was manufactured.
d)
?
Date code explanations for codes indicating the date of manufacture are public
information and may not be claimed as confidential.
Section 223.260
?
Most Restrictive Limit
a)
Products manufactured before January 1, 2009, and FIFRA-registered
Insecticides manufactured before January 1, 2010.
Notwithstanding the definition of "product category" in Section 223.203, if
anywhere on the principal display panel of any consumer product manufactured
before January 1, 2009, or any FIFRA-registered insecticide manufactured before
January 1, 2010, any representation is made that the product may be used as, or is
suitable for use as, a consumer product for which a lower VOC limit is specified
in Section 223.205(a), then the lowest VOC limit shall apply. This requirement
does not apply to general purpose cleaners, antiperspirant/deodorant products and
insecticide foggers.
b)
Products manufactured on or after January 1, 2009, and FIFRA-registered
Insecticides manufactured on or after January 1, 2010.
42
Notwithstanding the definition of "Product Category" in Section 223.203, if
anywhere on the container or packaging of any consumer product manufactured
on or after January 1, 2009, or any FIFRA-registered insecticide manufactured on
or after January 1, 2010, or on any sticker or label affixed thereto, any
representation is made that the product may be used as, or is suitable for use as, a
consumer product for which a lower VOC limit is specified in Section 223.205(a),
then the lowest VOM limit shall apply. This requirement does not apply to
general purpose cleaners, antiperspirant/deodorant products and insecticide
foggers.
Section 223.265
?
Additional Labeling Requirements for Aerosol Adhesives, Adhesive
Removers, Electronic Cleaners, Electrical Cleaners, Energized
Electrical Cleaners, and Contact Adhesives
a)?
In addition to the requirements specified in Sections 223.250, 223.260, and
223.270, both the manufacturer and responsible party for each aerosol adhesive,
adhesive remover, electronic cleaner, electrical cleaner, energized electrical
cleaner, and contact adhesive product subject to this regulation shall ensure that
all products clearly display the following information on each product container
which is manufactured on or after January 1, 2009.
1)
?
The product category as specified in Section 223.205(a) or an abbreviation
of the category shall be displayed.
The applicable VOM standard for the product that is specified in Section
223.205(a) except for Energized Electrical Cleaner, expressed as a
percentage by weight, shall be displayed unless the product is included in
an alternative control plan approved by the Agency, as provided in
Sections 223.240, and 223.245, and the product exceeds the applicable
VOM standard;
3)
If the product is included in an alternative control plan approved
by the Agency, and the product exceeds the applicable VOM
standard specified in Section 223.205(a), the product shall be
labeled with the term "ACP" or "ACP product";
4)
If the product is classified as a special purpose spray adhesive, the
applicable substrate and/or application or an abbreviation of the substrate
and/or application that qualifies the product as special purpose shall be
displayed.
5)
If the manufacturer or responsible party uses an abbreviation as allowed
by this Section 223.265, an explanation of the abbreviation must be filed
with the Agency before the abbreviation is used.
43
b)
The information required in Section 223.250(a), shall be displayed on the product
container such that it is readily observable without removing or disassembling any
portion of the product container or packaging. For the purposes of this
subsection, information may be displayed on the bottom of a container as long as
it is clearly legible without removing any product packaging.
c)
No person shall remove, alter, conceal, or deface the information required in
Subsection 223.265(a) prior to final sale of the product.
Section
223.270
Reporting Requirements
a) Upon request, a responsible party must submit to the Agency any of the following
information within 30 days of a request by the Agency:
1) The
name, address, and telephone number of the responsible party and the
name and telephone number of the party's designated contact person;
2) For each product subject to Section 223.205(a):
A)
The product brand name;
B)
The product label;
C)
The product category to which the consumer product belongs;
D)
The applicable product form(s) listed separately; and
E)
An identification of the product as a household product,
institutional product, or both;
3) Separate
Illinois sales in pounds per year, to the nearest pound, and the
method used to calculate Illinois sales for each product form;
4) For
information submitted by multiple companies, an identification of
each company which is submitting relevant data separate from that
submitted by the responsible party. All information from each company
shall be submitted by the date requested by the Agency;
5) For each product brand name and form, the net percent by weight of the
total product, less container and packaging, comprised of the following,
rounded to the nearest one-tenth of a percent (0.1%):
A)
Total Section 223.205(a) compounds;
B)
Total LVP-VOMs that are not fragrances;
44
C)
Total all other carbon-containing compounds that are not
fragrances;
D)
Total all non-carbon-containing compounds;
E)
Total fragrance;
F)
For products containing greater than two percent by weight
fragrance:
i)?
The percent of fragrance that are LVP-VOMs; and
The percent of fragrance that are all other carbon-
containing compounds; and
G)
Total paradichlorobenzene;
6) For each product brand name and form, the identity, including the specific
chemical name and associated Chemical Abstract Services (CAS) number,
of the following:
A)
Each Section 223.205(a) compound; and
B)
Each LVP-VOM that is not a fragrance; and
7)
?
If the product includes a propellant, the following:
A)
The weight percent comprised of propellant for each product; and
B)
An identification of the type of propellant, such as Type A, Type
B, Type C, or a blend of the different types.
b)?
In addition to the requirements of subsection (a)(6) of this Section the responsible
party shall report or shall arrange to have reported to the Agency, the net percent
by weight of each ozone-depleting compound which is:
1)
Listed in Section 223.210(a); and
2)
Contained in a product subject to reporting under subsection (a) of this
Section in any amount greater than 0.1% by weight.
c)
?
In addition, all manufacturers must submit to the Agency the information
requested in subsections (a) and (b) above upon commencement of the selling of
each such product in Illinois.
45
Section 223.275
?
Special Recordkeeping Requirements for Consumer Products that
Contain Perchloroethylene or Methylene Chloride
a)
The requirements of this Section shall apply to all responsible parties for
consumer products that are subject to Section 223.205(a) and contain
perchloroethylene or methylene chloride and Energized Electrical Cleaners as
defined in Section 223.203, that contain perchloroethylene or methylene chloride.
For the purposes of this Section, a product "contains perchloroethylene or
methylene chloride" if the product contains 1.0 percent or more by weight
(exclusive of the container or packaging) of either perchloroethylene or methylene
chloride.
b)
For each consumer product that contains perchloroethylene or methylene chloride,
the responsible party shall report the following information for products sold in
Illinois, upon request of the Agency, within 30 days written notice:
1)
The product brand name and a copy of the product label with legible usage
instructions;
2)
The product category to which the consumer product belongs;
3)
The applicable product form(s) (listed separately);
4)
For each product form listed in (3), the total sales in Illinois during the
calendar year to the nearest pound (exclusive of the container or
packaging), and the method used for calculating the Illinois sales; and
5)
The weight percent, to the nearest 0.10 percent, of perchloroethylene and
methylene chloride in the consumer product.
Section 223.280
?
Calculating Illinois Sales
If direct sales data for Illinois are not available, sales may be estimated by prorating national or
regional sales data by population.
Section 223.285
Test Methods
a)
Testing to determine compliance with the requirements of this Subpart shall be
performed using CARB Method 310, Determination of Volatile Organic Materials
(VOM) in Consumer Products, adopted September 25, 1997, and as last amended
on May 5, 2005, which is incorporated by reference in Section 223.120.
b)
Compliance with the requirements of this Subpart may also be demonstrated
through calculation of the VOM content from records of the amounts of
constituents used to make the product pursuant to the following criteria:
46
1) Accurate manufacturing records shall be kept for each day of production
of the amount and chemical composition of the individual product
constituents;
2) Records required by (1), above, shall be kept for at least three years;
3) For (4), below, the following shall apply:
A)
"A" means the total net weight of unit excluding container and
packaging;
B)
"B" means the total weight of all VOMs per unit; and
C)
"C" means the total weight of all exempted VOMs per unit;
4) For
the purposes of this section, the VOM content shall be calculated by
subtracting the total weight of VOMs exempted under Section 223.230 per
unit from the total weight of all VOMs per unit, divided by the total net
weight of unit excluding container and packaging and the product,
multiplied by 100 as in the formula below:
VOM Content = B - C x 100
A
5) If
product records appear to demonstrate compliance with the VOM limits,
but these records are contradicted by product testing performed using
CARB Method 310, the results of CARB Method 310 shall take
precedence over the product records and may be used to establish a
violation of the requirements of this chapter.
c)
Testing to determine whether a product is a liquid or solid shall be performed
using ASTM D4359-90 (2000)el, which is incorporated by reference in Section
223.120 or an equivalent method approved by the CARB.
d)
Testing to determine compliance with the certification requirements for charcoal
lighter material shall be performed using the procedures specified in the
SCAQMD Test Protocol Rule 1174 Ignition Method Compliance Certification
Protocol dated February 28, 1991, which is incorporated by reference in Section
223.120.
e)
Testing to determine distillation points of petroleum distillate-based charcoal
lighter materials shall be performed using ASTM D86-04b, 2004 edition, which is
incorporated by reference in Section 223.120 or an equivalent method
approved
by the CARB.
47
No person shall create, alter, falsify, or otherwise modify records in such a way
that the records do not accurately reflect the constituents used to manufacture a
product, the chemical composition of the individual product, and any other test,
processes, or records used in connection with product manufacture.
SUBPART C: ARCHITECTURAL AND INDUSTRIAL MAINTENANCE COATINGS
Section 223.300?
Purpose
The purpose of this Subpart is to limit emissions of VOMs by requiring reductions in the VOM
content of architectural and industrial maintenance coatings and required work practices to
minimize VOM emissions in the application of architectural and industrial maintenance coatings
to surfaces.
Section 223.305
?
Applicability
This Subpart is applicable to any person who supplies, sells, offers for sale, or manufacturers any
architectural coating for use within the state of Illinois, as well as any person who applies or
solicits the application of any architectural coating within Illinois. This Subpart does not apply
to:
a)
Any architectural coating that is sold or manufactured for use outside of the state
of Illinois or for shipment to other manufacturers for reformulation or
repackaging.
b)
Any aerosol coating product.
c)
Any architectural coating that is sold in a container with a volume of one liter
(1.057 quart) or less.
Section
223.307
Definitions for Subpart
C
The definitions contained in this Section apply only to the provisions of this Subpart. Unless
otherwise defined herein, the definitions of terms used in this Subpart shall have the meanings
specified for those terms in 35 Ill. Adm. Code Part 211.
"Adhesive" means any chemical substance that is applied for the purpose of bonding two
surfaces together other than by mechanical means.
"Aerosol Coating Product" means a pressurized coating product containing pigments or
resins that dispenses product ingredients by means of a propellant, and is packaged in a
disposable can
for hand-held application or for use in specialized equipment for ground
traffic/marking applications.
48
"Antenna Coating" means a coating labeled and formulated exclusively for application to
equipment and associated structural appurtenances that are used to receive or transmit
electromagnetic signals.
"Antifouling Coating" means a coating labeled and formulated for application to
submerged stationary structures and their appurtenances to prevent or reduce the
attachment of marine or freshwater biological organisms. To qualify as an "Antifouling
Coating," the coating must be registered with the USEPA under the Federal Insecticide,
Fungicide and Rodenticide Act (7 U.S.C. Section 136 et. seq.)
"Appurtenance" means any accessory to a stationary structure coated at the site of
installation, whether installed or detached, including but no limited to, bathroom and
kitchen fixtures, cabinets, concrete forms, doors, elevators, fences, hand railings, heating
equipment, air conditioning equipment, and other fixed mechanical equipment or
stationary tools, lampposts, partitions pipes and piping systems, rain gutters and
downspouts, stairways, fixed ladders, catwalks and fire escapes, and window screens.
"Architectural Coating" means a coating to be applied to stationary structures or the
appurtenances at the site of installation, to portable buildings at the site of installation, to
pavements, or to curbs. Coatings applied in shop applications or to non-stationary
structures such as airplanes, ships, boats, railcars, and automobiles, and adhesives are not
considered architectural coatings for the purposes of this rule.
"Bitumens" means black or brown materials including, but not limited to, asphalt, tar,
pitch, and asphaltite that are soluble in carbon disulfide, consist mainly of hydrocarbons,
and are obtained from natural deposits or as residues from the distillation of crude
petroleum or coal.
"Bituminous Roof Coating" means a coating which incorporates "Bitumens" that is
labeled and formulated exclusively for roofing.
"Bituminous Roof Primer" means a primer which incorporates "Bitumens" that is labeled
and formulated exclusively for roofing.
"Bond Breaker" means a coating labeled and formulated for application between layers
of concrete to prevent a freshly poured top layer of concrete from bonding to the layer
over which it is poured.
"Calcamine Recoaters" means a flat solvent borns coatings formulated and recommended
specifically for recoating calcamine-painted ceilings and other calcamine-painted
substrates.
"Clear Brushing Lacquers" means clear wood finishes, excluding clear lacquer sanding
sealers, formulated with nitrocellulose or synthetic resins to dry by solvent evaporation
without chemical reaction and to provide a solid, protective film, which are intended
exclusively for application by brush and which are labeled as specified in subsection
49
223.320(e).
"Clear Wood Coatings" means clear and semi-transparent coatings, including lacquers
and varnishes, applied to wood substrates to provide a transparent or translucent solid
film.
"Coating" means for purposes of this Part, a material applied onto or impregnated into a
substrate for protective, decorative, or functional purposes. Such materials include, but
are not limited to, paints, varnishes, sealers, and stains.
"Colorant" means a concentrated pigment dispersion in water, solvent, and/or binder that
is added to an architectural coating after packaging in sale units to produce the desired
color.
"Concrete Curing Compound" means for purposes of this Part, a coating labeled and
formulated for application to freshly poured concrete to retard the evaporation of water.
"Conversion Varnish" means a clear acid-curing coating with an alkyd or other resin
blended with amino resins and supplied as a single component or two-component
product. Conversion varnishes produce a hard, durable, clear finish designed for
professional application to wood flooring. Film formation is the result of an acid-
catalyzed condensation reaction, affecting a transetherification at the reactive ethers of
the amino resins.
"Dry Fog Coating" means a coating labeled and formulated only for spray application
such that overspray droplets dry before subsequent contact with incidental surfaces in the
vicinity of the surface coating activity.
"Exempt Compound" means a compound identified as exempt under the definition of
Volatile Organic Material (VOM) in Part 211.7150. The exempt compound content of a
coating shall be determined by USEPA Method 24 or South Coast Air Quality
Management District (SCAQMD) Method 303-91 (Revised February 1993), incorporated
by reference on Section 223.120.
"Faux Finishing Coating" means a coating labeled and formulated as a stain or a glaze to
create artistic effects including, but not limited to, dirt, old age, smoke damage, and
simulated marble and wood grain.
"Fire-Resistive Coating" means an opaque coating labeled and formulated to protect the
structural integrity by increasing the fire endurance of interior or exterior steel and other
structural materials, that has been fire tested and rated by a testing agency and approved
by building code officials for use in bringing assemblies of structural materials into
compliance with federal, state, and local building code requirements. The fire-resistive
coating and the testing agency must be approved by building code officials. The
fire-resistive coating shall be tested in accordance with ASTM Designation E 119-98,
incorporated by reference in Section 223.120.
50
"Fire-Retardant Coating" means a coating labeled and formulated to retard ignition and
flame spread, that has been fire tested and rated by a testing agency approved by building
code officials for use in bringing building and construction materials into compliance
with federal, state, and local building code requirements. The fire-retardant coating and
the testing agency must be approved by building code officials. The fire-retardant
coating shall be tested in accordance with ASTM Designation E 84-99, incorporate by
reference in Section 223.120.
"Flat Coating" means a coating that is not defined under any other definition in this rule
and that registers gloss less than 15 on an 85-degree meter or less than five on a
60-degree meter according to ASTM Designation D 523-89 (1999), incorporated by
reference in Section 223.120.
"Floor Coating" means an opaque coating that is labeled and formulated for application
to flooring, including, but not limited to, decks, porches, steps, and other horizontal
surfaces, which may be subjected to foot traffic.
"Flow Coating" means a coating labeled and formulated exclusively for use by electric
power companies or their subcontractors to maintain the protective coating systems
present on utility transformer units.
"Form-Release Compound" means a coating labeled and formulated for application to a
concrete form to prevent the freshly poured concrete from bonding to the form. The form
may consist of wood, metal, or some material other than concrete.
"Graphic Arts Coating or Sign Paint" means a coating labeled and formulated for
hand-application by artists using brush or roller techniques to indoor and outdoor signs
(excluding structural components) and murals including letter enamels, poster colors,
copy blockers, and bulletin enamels.
"High-Temperature Coating" means a high performance coating, excluding engine paint,
labeled and formulated for application to substrates exposed continuously or
intermittently to temperatures above 204°C (400°F).
"Impacted Immersion Coating" means a high performance maintenance coating
formulated and recommended for application to steel structures subject to immersion in
turbulent, debris-laden water. These coatings are specifically resistant to high-energy
impact damage by floating ice or debris.
"Industrial Maintenance Coating" means a high performance architectural coating,
including primers, sealers, undercoaters, intermediate coats, and topcoats, formulated for
application to substrates exposed to one or more of the following extreme environmental
conditions listed below, and labeled as specified in subsection 223.320(d):
51
Immersion in water, wastewater, or chemical solutions (aqueous and non-aqueous
solutions), or chronic exposures of interior surfaces to moisture condensation;
Acute or chronic exposure to corrosive, caustic, or acidic agents, or to chemicals,
chemical fumes, or chemical mixtures or solutions;
Repeated exposure to temperatures above 121°C (250°F);
Repeated (frequent) heavy abrasion, including mechanical wear and repeated
(frequent) scrubbing with industrial solvents, cleansers, or scouring agents; or
Exterior exposure of metal structures and structural components.
"Lacquer" means a clear or opaque wood coating, including clear lacquer sanding sealers,
formulated with cellulosic or synthetic resins to dry by evaporation without chemical
reaction and to provide a solid, protective film.
"Low-Solids Coating" means a coating containing 0.12 kilogram or less of solids per liter
(1 pound or less of solids per gallon) of coating material.
"Magnesite Cement Coating" means a coating labeled and formulated for application to
magnesite cement decking to protect the magnesite cement substrate from erosion by
water.
"Mastic Texture Coating" means a coating labeled and formulated to cover holes and
minor cracks and to conceal surface irregularities, and is applied in a single coat of at
least 10 mils (0.010 inch) dry film thickness.
"Metallic Pigmented Coating" means a coating containing at least 48 grams of elemental
metallic pigment per liter of coating as applied (0.4 pounds per gallon), when tested in
accordance with SCAQMD Method 318-95, incorporated by reference in Section
223.120.
"Multi-Color Coating" means a coating that is packaged in a single container and that
exhibits more than one color when applied in a single coat.
"Non-flat Coating" means a coating that is not defined under any other definition in this
rule and that registers a gloss of 15 or greater on an 85-degree meter and five or greater
on a 60 degree meter according to ASTM Designation D 523-89 (1999), incorporated by
reference in Section 223.120 or an equivalent method approved by the California Air
Resources Board.
"Non-flat - High Gloss Coating" means a non-flat coating that registers a gloss of 70 or
above on a 60-degree meter according to ASTM Designation D 523-89 (1999),
incorporated by reference into Section 223.120 or an equivalent method approved by the
52
CARB.
"Nonindustrial Use" means any use of architectural coatings except in the construction or
maintenance of any of the following: facilities used in the manufacturing of goods and
commodities, transportation infrastructure, including highways, bridges, airports and
railroads, facilities used in mining activities, including petroleum extraction, utilities
infrastructure, including power generation and distribution, and water treatment and
distribution systems.
"Nuclear Coating" means a protective coating formulated and recommended to seal
porous surfaces such as steel (or concrete) that otherwise would be subject to intrusions
by radioactive materials. These coatings must be resistant to long-term (service life)
cumulative radiation exposure [ASTM Method D 4082-89], relatively easy to
decontaminate, and resistant to various chemicals to which the coatings are likely to be
exposed [ASTM Method D 3912-80].
"Post-Consumer Coating" means a finished coating that would have been disposed of in a
landfill, having completed its usefulness to a consumer, and does not include
manufacturing wastes.
"Pre-Treatment Wash Primer" means a primer that contains a minimum of 0.5 acid, by
weight, when tested in accordance with ASTM Designation D 1613-03, incorporated by
reference into Section 223.120 or an equivalent method approved by the CARB, that is
labeled and formulated for application directly to bare metal surfaces to provide corrosion
resistance and to promote adhesion of subsequent topcoats.
"Primer" means for purposes of this Part, a coating labeled and formulated for application
to a substrate to provide a firm bind between the substrate and subsequent coats.
"Quick-Dry Enamel" means a non-flat coating that is labeled as specified in subsection
223.320(h) and that is formulated to have the following characteristics:
Is capable of being applied directly from the container under normal conditions
with ambient temperatures between 16 and 27°C (60 and 80°F); and
When tested in accordance with ASTM Designation D 1640-03, incorporated by
reference in Section 223.120, or an equivalent method approved by the CARB,
sets to touch in two hours or less, is tack free in four hours or less, and dries hard
in eight hours or less by the mechanical test method; and
Has a dried film gloss of 70 or above on a 60-degree meter.
"Quick-Dry Primer Sealer and Undercoater" means a "Primer," "Sealer," or
"Undercoater" that is dry to the touch in 30 minutes and can be re-coated in two hours
when tested in accordance with ASTM Designation D 1640-03, incorporated by reference
in Section 223.120 or an equivalent method approved by the CARE.
53
"Recycled Coating" means an architectural coating formulated such that not less than 50
percent of the total weight consists of secondary and post-consumer coating, with not less
than 10 percent of the total weight consisting of post-consumer coating.
"Residence" means areas where people reside or lodge, including, but not limited to,
single and multiple family dwellings, condominiums, mobile homes, apartment
complexes, motels, and hotels.
"Roof Coating" means a non-bituminous coating labeled and formulated exclusively for
application to roofs for the primary purpose of preventing penetration of the substrate by
water or reflecting heat and ultraviolet radiation. Metallic pigmented roof coatings which
qualify as metallic pigmented coatings, shall not be considered in this category, but shall
be considered to be in the metallic pigmented coatings category.
"Rust Preventive Coating" means a coating formulated exclusively for nonindustrial use
to prevent the corrosion of metal surfaces and labeled as specified in Section 223.320(f).
"Sanding Sealer" means for purposes of this Part, a clear or semi-transparent wood
coating labeled and formulated for application to bare wood to seal the wood and to
provide a coat that can be abraded to create a smooth surface for subsequent applications
of coatings. A "Sanding Sealer" that also meets the definition of a "Lacquer" is not
included in this category, but it is included in the "Lacquer" category.
"Sealer" means for purposes of this Part, a coating labeled and formulated for application
to a substrate for one or more of the following purposes: to prevent subsequent coatings
from being absorbed by the substrate, or to prevent harm to subsequent coatings by
materials in the substrate.
"Secondary Coating (Rework)" means a fragment of a finished coating or a finished
coating from a manufacturing process that has converted resources into a commodity of
real economic value, but does not include excess virgin resources of the manufacturing
process.
"Shellac" means a clear or opaque coating formulated solely with the resinous secretions
of the lac beetle (Laciffer lacca), thinned with alcohol, and formulated to dry by
evaporation without a chemical reaction.
"Shop Application" means the application of a coating to a product or a component of a
product in or on the premises of a factory or a shop as part of a manufacturing,
production, or repairing process (e.g., original equipment manufacturing coatings).
"Solicit" means to require for use or to specify by written or oral contract.
"Specialty Primer, Sealer, and Undercoater" means a coating labeled as specified
in
subsection 223.320(g) and that is formulated for application to a substrate to seal fire,
54
smoke, or water damage; to condition excessively chalky surfaces, to seal in
efflorescence, or to block stains. An excessively chalky surface is one that is defined as
having a chalk rating of four or less as determined by ASTM Designation D 4214-98,
incorporated by reference in Section 223.120 or an equivalent method approved by the
CARB.
"Stain" means a clear, semi-transparent, or opaque coating labeled and formulated to
change the color of a surface, but not conceal the grain pattern or texture.
"Stone Consolidant" means a coating that is labeled and formulated for application to
stone substrates to repair historical structures that have been damaged by weathering or
other decay mechanisms. Stone Consolidants must penetrate into stone substrates to
create bonds between particles and consolidate deteriorated material. Stone Consolidants
must be specified and used in accordance with ASTM E2167-01, incorporated by
reference in Section 223.120.
Stone Consolidants are for professional use only and must be labeled as such, in
accordance with the labeling requirements in Section 223.320.
"Swimming Pool Coating" means a coating labeled and formulated to coat the interior of
swimming pools and to resist swimming pool chemicals.
"Swimming Pool Repair and Maintenance Coating" means a rubber-based coating
labeled and formulated to be used over existing rubber-based coatings for the repair and
maintenance of swimming pools.
"Temperature-Indicator Safety Coating" means a coating labeled and formulated as a
color-changing indicator coating for the purpose of monitoring the temperature and safety
of the substrate, underlying piping, or underlying equipment, and for application to
substrates exposed continuously or intermittently to temperatures above 204°C (400°F).
"Thermoplastic Rubber Coating and Mastics" means a coating or mastic formulated and
recommended for application to roofing or other structural surfaces and that incorporates
no less than 40 percent by weight of thermoplastic rubbers in the total resin solids and
may also contain other ingredients including, but not limited to, fillers, pigments and
modifying resins.
"Tint Base" means an architectural coating to which colorant is added after packaging in
sale units to produce a desired color.
"Traffic Marking Coating" means a coating labeled and formulated for marking and
striping streets, highways, or other traffic surfaces including, but not limited to, curbs,
berets, driveways, parking lots, sidewalks, and airport runways.
55
"Undercoater" means a coating labeled and formulated to provide a smooth surface for
subsequent coatings.
"Varnish" means a clear or semi-transparent wood coating, excluding lacquers and
shellacs, formulated to dry by chemical reaction on exposure to air. Varnishes may
contain small amounts of pigment to color a surface, or to control the fetal sheen or gloss
of the finish.
"VOC Content" shall have the same meaning as "VOM Content."
"VOM Content" means the weight of VOM per volume of coating, calculated according
to the procedures specified in subsection 223.400(a).
"Waterproofing Concrete/Masonry Sealers" means clear or pigmented sealers that are
formulated for sealing concrete and masonry to provide resistance against water, alkalis,
acids, ultraviolet light, or staining.
"Waterproofing Sealer" means a coating labeled and formulated for application to a
porous substrate for the primary purpose of preventing the penetration of water.
"Wood Preservative" means a coating labeled and formulated to protect exposed wood
from decay or insect attack that is registered with both the USEPA under the Federal
Insecticide, Fungicide, and Rodenticide Act (7 U.S.C. section 136, et. seq.).
Section 223.310 Standards
a)?
VOM Content Limits: Except as provided in subsections 223.310(c), no person
shall manufacture, blend, or repackage for sale within Illinois, supply, sell, or offer for
sale within Illinois, or solicit for application or apply within Illinois, any architectural
coating manufactured on or after January 1, 2009, which contains a VOM content in
excess of the corresponding limit specified below:
VOM Content Limit
Grams/liter (Pounds/gallon)
Coating Category
1)
?
Flat Coatings
100 (0.8)
2)
?
Non-flat Coatings
150 (1.3)
3)
?
Non-flat- High Gloss Coatings
250
(2.1)
Specialty Coatings
4)
?
Antenna Coatings
530
(4.4)
56
5)
Antifouling Coatings
400
(3.3)
6)
Bituminous Roof Coatings
300
(2.5)
7)
Bituminous Roof Primers
350
(2.9)
8)
Bond Breakers
350
(2.9)
9)
Calcamine Recoaters
475
(4.0)
10)
Clear Wood Coatings
A)?
Clear Brushing Lacquers
680 (5.7)
B)
?
Lacquers
(including lacquer sanding sealers)
550
(4.6)
C)?
Sanding Sealers
(other than lacquer sanding sealers)
350
(2.9)
D)
?
Varnishes
350
(2.9)
11)
Concrete Curing Compounds
350
(2.9)
12)
Conversion Varnish
725
(6.0)
13)
Dry Fog Coatings
400
(3.3)
14)
Faux Finishing Coatings
350
(2.9)
15)
Fire-Resistive Coatings
350
(2.9)
16)
Fire-Retardant Coatings
A)
?
Clear
650 (5.4)
B)?
Opaque
350
(2.9)
17)
Floor Coatings
250
(2.1)
18)
Flow Coatings
420
(3.5)
19)
Form
-
Release Compounds
250
(2.1)
20)
Graphic
Arts Coatings (Sign Paints)
500
(4.2)
57
21)
High-Temperature Coatings
420
(3.5)
22)
Impacted Immersion Coating
780
(6.5)
23)
Industrial Maintenance Coatings
340
(2.8)
24)
Low-Solids Coatings
120
(1.0)
25)
Magnesite Cement Coatings
450
(3.8)
26)
Mastic Texture Coatings
300
(2.5)
27)
Metallic Pigmented Coatings
500
(4.2)
28)
Multi-Color Coatings
250
(2.1)
29)
Nuclear Coating
550
(4.6)
30)
Pre-Treatment Wash Primers
420
(3.5)
31)
Primers, Sealers, and Undercoaters
200
(1.7)
32)
Quick-Dry Enamels
250
(2.1)
33)
Quick-Dry Primers, Sealers and Undercoaters
200
(1.7)
34)
Recycled Coatings
250
(2.1)
35)
Roof Coatings
250
(2.1)
36)
Rust Preventative Coatings
400
(3.3)
37)
Shellacs
A)?
Clear
730 (6.1)
B)
?
Opaque
550 (4.6)
38)
Specialty Primers, Sealers, and Undercoaters
350
(2.9)
39)
Stains
250
(2.1)
40)
Stone Consolidants
450
(3.8)
41)
Swimming Pool Coatings
340
(2.8)
58
42)
Swimming Pool Repair and Maintenance Coatings 340
(2.8)
43)
Temperature-Indicator Safety Coatings
550
(4.6)
44)
Thermoplastic Rubber Coatings and Mastics
550
(4.6)
45)
Traffic Marking Coatings
150
(1.3)
46)
Waterproofing Concrete/Masonry Sealers
400
(3.3)
47)
Waterproofing Sealers
250
(2.1)
48)
Wood Preservatives
350
(2.9)
(Board Note: Conversion factor: one pound VOM per gallon (U.S.) = 119.95 grams per liter.)
b)
Limits are expressed in grams of VOM per liter of coating thinned to the
manufacturer's maximum recommendation, excluding the volume of any water,
exempt compounds, or colorant added to tint bases. "Manufacturers maximum
recommendation" means the maximum recommendation for thinning that is
indicated on the label or lid of the coating container.
c)
Most Restrictive VOM Limit. If anywhere on the container of any architectural
coating, or any label or sticker affixed to the container, or in any sales,
advertising, or technical literature supplied by a manufacturer or anyone acting on
their behalf, any representation is made that indicates that the coating meets the
definition of or is recommended for use for more than one of the coating
categories listed in Section 223.310(a), then the most restrictive VOM content
limit shall apply. This provision does not apply to the coating categories specified
in subsections (c)(1) through (c)(20) below:
1)
Lacquer coatings (including lacquer sanding sealers);
2)
Metallic pigmented coatings;
3)
Shellacs;
4)
Fire-retardant coatings;
5)
Pretreatment wash primers;
6)
Industrial maintenance coatings;
7)
Low-solids coatings;
59
8)
Wood preservatives;
9)
High-temperature coatings;
10)
Temperature-indicator safety coatings;
11)
Antenna coatings;
12)
Antifouling coatings;
13)
Flow coatings;
14)
Bituminous roof primers;
15)
Specialty primers, sealers, and undercoaters.
16)
Conversion Varnish
17)
Calcimine Recoaters
18)
Impacted Immersion Coatings
19)
Nuclear Coatings
20)
Thermoplastic Rubber Coating and Mastics
d)
Painting Practices. All architectural coating containers used to apply the contents
therein to a surface directly from the container by pouring, siphoning, brushing,
rolling, padding, ragging, or other means, shall be closed when not in use. These
architectural coatings containers include, but are not limited to, drums, buckets,
cans, pails, trays, or other application containers. Containers of any
VOM-containing materials used for thinning and cleanup shall also be closed
when not in use.
e)
Thinning. No person who applies or solicits the application of any architectural
coating shall apply a coating that is thinned to exceed the applicable VOM limit
specified in Section 223.310(a).
Rust Preventive Coatings. No person shall apply or solicit the application of any
rust preventive coating for industrial use unless such a rust preventive coating
complies with the industrial maintenance coating VOM limit specified in Section
223.310(a). If the coating is also regulated under another Part, the more
restrictive limit shall apply.
g)
?Coatings
Not Listed in Section 223.310(a). For any coating that does not meet
any of the definitions for the specialty coatings categories listed in Section
60
223.310(a), the VOM content limit shall be determined by classifying the coating
as a flat coating, a non-flat coating, or a non-flat high-gloss coating, based on its
gloss, as defined in Section 223.307, and the corresponding flat or non-flat
coating limit shall apply.
Section
223.320
Container Labeling Requirements
Each manufacturer of any architectural coatings subject to this Subpart shall display the
information listed in subsections 223.320(a) through 223.320(j) on the coating container (or
label) in which the coating is sold or distributed.
a) Date
Code. The date the coating was manufactured, or a date code
representing the date, shall be indicated on the label, lid, or bottom of the
container. If the manufacturer uses a date code for any coating, the
manufacturer shall file an explanation of each code with the Agency.
b) Thinning
Recommendations. A statement of the manufacturer's
recommendation regarding thinning of the coating shall be indicated on
the label or lid of the container. This requirement does not apply to the
thinning of architectural coatings with water. If thinning of the coating
prior to use is not necessary, the recommendation must specify that the
coating is to be applied without thinning.
c) VOM
Content. Each container of any coating subject to this rule shall display
either the maximum or the actual VOM content of the coating, as supplied, or the
actual VOM content including the maximum thinning as recommended by the
manufacturer. VOM content shall be displayed in grams of VOM per liter of
coating. VOM content displayed shall be calculated using product formulation
data, or shall be determined using the test methods in subsection 223.340(b). The
equations in subsection 223.340(a) shall be used to calculate VOM content.
d) Industrial
Maintenance Coatings. In addition to the information specified
in subsection (a), (b), and (c), each manufacturer of any industrial
maintenance coating subject to this rule shall display on the label or the lid
of the container in which the coating is sold or distributed one or more of
the descriptions listed in subsections (d)(1) through (d)(3):
1)
"For industrial use only;"
2)
"For professional use only;"
3)
"Not for residential use" or "Not intended for residential use."
e) Clear
Brushing Lacquers. The labels of all clear brushing lacquers shall promi-
nently display the statements "For brush application only," and "This product
must not be thinned or sprayed."
61
0
?
Rust Preventive Coatings. The labels of all rust preventive coatings shall
prominently display the statement "For Metal Substrates Only."
g)
Specialty Primers, Sealers, and Undercoaters. The labels of all specialty
primers, sealers, and undercoaters shall prominently display one or more
of the descriptions listed in subsection (g)(1) through (g)(5):
1)
"For blocking stains;"
2)
"For fire-damaged substrates;"
3)
"For smoke-damaged substrates;"
4)
"For water-damaged substrates;"
5)
"For excessively chalky substrates."
h) Quick Dry Enamels. The labels of all quick dry enamels shall prominently
display the words "Quick Dry" and the dry hard time.
Non-Flat High-Gloss Coatings. The labels of all non-flat high-gloss
coatings shall prominently display the words "High Gloss."
Stone Consolidants: Effective January 1, 2010, the labels of all Stone
Consolidants shall prominently display the statement "Stone Consolidant - For
Professional Use Only".
Section
223.330
Record Keeping and Reporting Requirements
a) Clear
Brushing Lacquers. Each manufacturer of clear brushing lacquers shall
report the following information for products sold in Illinois, upon request of the
Agency, within 30 days written notice:
1)
The number of gallons of clear brushing lacquers sold in the state during
the preceding calendar year; and
2)
The method used by the manufacturer to calculate state sales.
b) Rust
Preventive Coatings. Each manufacturer of rust preventive coatings shall
report the following information for products sold in Illinois, upon request of the
Agency, within 30 days written notice:
1) The number of gallons of rust preventive coatings sold
in
the state during
the preceding calendar year; and
62
2)
?
The method used by the manufacturer to calculate state sales.
c)
?
Specialty Primers, Sealers, and Undercoaters. Each manufacturer of specialty
primers, sealers, and undercoaters shall report the following information for
products sold in Illinois, upon request of the Agency, within 30 days written
notice:
1)
The number of gallons of specialty primers, sealers, and undercoaters sold
in the state during the preceding calendar year; and
2)
The method used by the manufacturer to calculate state sales.
d)
?
Toxic Exempt Compounds. For each architectural coating that contains
perchloroethylene or methylene chloride, the manufacturer shall report the
following information for products sold in Illinois, upon request of the Agency,
within 30 days written notice:
1)
The product brand name and a copy of the product label with the legible
usage instructions;
2)
The product category listed in Section 223.210(a) to which the coating
belongs;
3)
The total sales in Illinois during the calendar year to the nearest gallon;
and
4)
The volume percent, to the nearest 0.10 percent, of perchloroethylene and
methylene chloride in the coating.
e)
?
Recycled Coatings.
1)
Manufacturers of recycled coatings must submit a letter to the Agency
self-certifying their status as a Recycled Paint Manufacturer upon request
of the Agency, within 30 days written notice.
2)
Each recycled coatings manufacturer shall report the following
information for products sold in Illinois, upon request of the Agency,
within 30 days written notice:
A)
The number of gallons of recycled coatings sold in the state during
the preceding calendar year; and
B)
The method used by the manufacturer to calculate state sales.
63
f)
?
Bituminous Coatings. Each manufacturer of "Bituminous Roof Coatings" or
"Bituminous Roof Primers" shall report the following information for products
sold in Illinois, upon request of the Agency, within 30 days written notice:
1)
The number of gallons of "Bituminous Roof Coatings" or "Bituminous
Roof Primers" sold in the state during the preceding calendar year; and
2)
The method used by the manufacturer to calculate state sales.
Section
223.340?
Compliance Provisions and Test Methods
a)?
Calculation of VOM Content. For the purpose of determining compliance with
the VOM content limits in Section 223.310(a), the VOM content of a coating
shall be determined by using the procedures described in subsections
223.340(a)(I) or 223.340(a)(2), as appropriate. The VOM content of a tint base
shall be determined without colorant that is added after the tint base is
manufactured.
1)
With the exception of low solids coatings, determine the VOM content in
grams of VOM per liter of coating thinned to the manufacturer's maximum
recommendation, excluding the volume of any water and exempt
compounds. Determine the VOM content as follows:
VOM Content =
?
(Ws - Ww - Wem)
(Vm - Vw - Vem)
Where:
VOM content = grams of VOM per liter of coating
Ws
?
= weight of volatiles, in grams
Ww
?
= weight of water, in grams
Wem?
= weight of exempt materials, in grams
Vm?
= volume of coating, in liters
Vw
?
= volume of water, in liters
Vem?
= volume of exempt materials, in liters
2)
For low solids coatings, determine the VOM content in units of grams of
VOM per liter of coating thinned to the manufacturer's maximum
recommendation, including the volume of any water and exempt
compounds. Determine the VOM content as follows:
VOM Content (Is) =
(Ws - Ww - Wem)
(Vm)
64
Where:
VOM content (Is) =
Ws
Ww
Wem
Vm
the VOM content of a low solids coating in grams per liter
of coating
= weight of volatile, in grams
= weight of water, in grams
= weight of exempt materials, in grams
= volume of coating, in liters
b) VOM
Content of Coatings. To determine the physical properties of a coating in
order to perform the calculations in subsection 223.340(a), the reference method
for VOM content is USEPA Method 24, incorporated by reference in Section
223.120, except as provided in subsections 223.350 and 223.360. An alternative
method to determine the VOM content of coatings is SCAQMD Method 304-91
(Revised February 1996), incorporated by reference in Section 223.120. The
exempt compounds content shall be determined by SCAQMD Method 303-91
(Revised August 1996), incorporated by reference in subsection Section 223.120.
To determine the VOM content of a coating, the manufacturer may use USEPA
Method 24, or an equivalent alternative method, as provided in Section 223.350,
formulation data, or any other reasonable means for predicting that the coating
has been formulated as intended (e.g. quality assurance checks, recordkeeping).
However, if there are any inconsistencies between the results of a Method 24 test
and any other means for determining VOM content, the Method 24 results will
govern, except when an equivalent alternative method is approved as specified in
Section 223.350. The Agency may require the manufacturer to conduct a Method
24 analysis.
Section 223.350 Alternative
Test Methods
Other test methods demonstrated to provide results that are acceptable for purposes of deter-
mining compliance with subsection 223.340(b), after review and approved in writing by the
Agency and the USEPA may also be used.
Section 223.360 Methacrylate
Traffic Coating Markings
Analysis of methacrylate multi-component coatings used as traffic marking coatings shall be
conducted according to a modification of USEPA Method 24 (40 CFR 59, subpart D, Appendix
A), incorporated by reference in Section 223.120 or an equivalent method approved by the
CARB. This method has not been approved for methacrylate multi-component coatings used for
purposes other than as traffic marking coatings or for other classes of multi-component coatings.
Section
223.370
Test Methods
The following test methods are incorporated by reference herein, and shall be used to test
coatings subject to the provisions of this Subpart:
65
a)
Flame Spread Index. The flame spread index of a fire-retardant coating shall be
determined by the ASTM Designation E 84-99, "Standard Test Method for
Surface Burning Characteristics of Building Materials," (see Section 223.307,
Fire-Retardant Coating) or an equivalent method approved by the CARE.
b)
Fire-Resistance Rating. The fire-resistance rating of a fire-resistive coating shall
be determined by ASTM designation E 119-98, "Standard Test Methods for Fire
Tests of Building Construction Materials," (see Section 223.307, Fire-Resistive
Coating) or an equivalent method approved by the CARB.
c)
Gloss Determination. The gloss of a coating shall be determined by ASTM
Designation D 523-89 (1999), "Standard Test Method for Specular Gloss," (see
Section 223.307, Flat Coating, Non-flat Coating, Non-flat - High-Gloss Coating,
and Quick Dry Enamel) or an equivalent method approved by the CARB.
d)
Metal Content of Coatings. The metallic content of a coating shall be determined
by SCAQMD Method 318-95, "Determination of Weight Percent Elemental
Metal in Coatings by X-Ray Diffraction," SCAQMD "Laboratory Methods of
Analysis for Enforcement Samples," (see Section 223.307, Metallic Pigmented
Coating).
e)
Acid Content of Coatings. The acid content of a coating shall be determined by
ASTM Designation D 1613-96, "Standard Test Method for Acidity in Volatile
Solvents and Chemical Intermediates Used in Paint, Varnish, Lacquer and Related
Products," (see Section 223.307, Pre-Treatment Wash Primer) or an equivalent
method approved by the CARE.
Drying Times. The set-to-touch, dry-hard, dry-to-touch and dry-to-recoat times
of a coating shall be determined by ASTM Designation D 1640-95, "Standard
Methods for Drying, Curing, or Film Formation of Organic Coatings at Room
Temperature," (see Section 223.307, QuickDry Enamel and Quick-Dry Primer,
Sealer, and Undercoater). The tack free time of a quick-dry enamel coating shall
be determined by the Mechanical Test Method of ASTM Designation D 1640-95
or an equivalent method approved by the CARB.
g)
Surface Chalkiness. The chalkiness of a surface shall be determined using ASTM
Designation D 4214-98, "Standard Test Methods for Evaluating the Degree of
Chalking of Exterior Paint Films," (see Section 223.307, Specialty Primer, Sealer,
and Undercoater) or an equivalent method approved by the CARB.
h)
Exempt Compounds – Siloxanes. Exempt compounds that are cyclic, branched,
or linear, completely methylated siloxanes, shall be analyzed as exempt com-
pounds for compliance with Section 223.340 by BAAQMD Method 43,
"Determination of Volatile Methylsiloxanes in Solvent-Based Coatings, Inks, and
Related Materials," BAAQMD Manual of Procedures, Volume III, adopted
66
November 6, 1996, (see Section 223.307, Volatile Organic Material, and
subsection 223.340(b)).
Exempt Compounds - Parachlorobenzotrifluoride (PCBTF). The exempt
compound parachlorobenzotri fluoride, shall be analyzed as an exempt compound
for compliance with Section 223.400 by BAAQMD Method 41, "Determination
of Volatile Organic Compounds in Solvent-Based Coatings and Related Materials
Containing Parachlorobenzotrifluoride," BAAQMD Manual of Procedures,
Volume
III, adopted December 20, 1995, (see Section 223.307, Volatile Organic
Material, and subsection 223.340(b)).
Exempt Compounds. The content of compounds exempt under USEPA Method
24 shall be analyzed by SCAQMD Method 303-91 (Revised 1993),
"Determination of Exempt Compounds," SCAQMD "Laboratory Methods of
Analysis for Enforcement Samples," (see Section 223.307, Volatile Organic
Material, and subsection 223.340(b)).
k)
?
VOM Content of Coatings. The VOM content of a coating shall be determined
by USEPA Method 24 as it exists in Appendix A of 40 Code of Federal
Regulations (CFR) Part 60, "Determination of Volatile Matter Content, Water
Content, Density, Volume Solids, and Weight Solids of Surface Coatings," (see
subsection 223.340(b)) or an equivalent method approved by the CARB.
1)?
Alternative VOM Content of Coatings. The VOM content of coatings may be
analyzed by either USEPA Method 24 or SCAQMD Method 304-91 (Revised
1996), "Determination of Volatile Organic Compounds (VOC) in Various
Materials," SCAQMD "Laboratory Methods of Analysis for Enforcement
Samples," (see subsection 223.340(b)).
m)?
Methacrylate Traffic Marking Coatings. The VOM content of methacrylate
muticomponent coatings used
as
traffic marking coatings shall be analyzed by the
procedures in 40 CFR part 59, subpart D, appendix A, "Determination of Volatile
Matter Content of Methacrylate Multicomponent Coatings Used as Traffic
Marking Coatings," (September 11, 1998), (see subsection 223.360) or an
equivalent method approved by the CARB.
SUBPART D: AEROSOL COATINGS
Section 223.400 Purpose
The purpose of this Subpart is to limit emissions of volatile organic materials (VOMs) by
requiring reductions in the VOM content of Aerosol Coating products.
Section 223.405 Applicability
67
This Subpart shall apply to any person who sells, supplies, offers for sale, applies, or
manufactures aerosol coating products for use in the state of Illinois, except as provided
in
Section 223.420.
Section 223.407 Definitions for Subpart D
The definitions contained in this Section apply only to the provisions of this Subpart. Unless
otherwise defined herein, the definitions of terms used in this Subpart shall have the meanings
specified for those terms in 35 Ill. Adm. Code Part 211.
"Adhesive" means a product used to bond one surface to another.
"Aerosol Coating Product" means a pressurized coating product containing pigments or
resins that dispenses product ingredients by means of a propellant, and is packaged in a
disposable can for hand-held application or for use in specialized equipment for ground
traffic/marking applications.
"Anti-Static Spray" means a product used to prevent or inhibit the accumulation of static
electricity.
"Art Fixative or Sealant" means a clear coating, including art varnish, workable art
fixative, and ceramic coating, which is designed and labeled exclusively for application
to paintings, pencil, chalk, or pastel drawings, ceramic art pieces, or other closely related
art uses, in order to provide a final protective coating or to fix preliminary stages of
artwork while providing a workable surface for subsequent revisions.
"Auto Body Primer" means an automotive primer or primer surfacer coating designed
and labeled exclusively to be applied to a vehicle body substrate for the purposes of
corrosion resistance and building a repair area to a condition in which, after drying, it can
be sanded to a smooth surface.
"Automotive Bumper and Trim Product" means a product, including adhesion promoters
and chip sealants, designed and labeled exclusively to repair and refinish automotive
bumpers and plastic trim parts.
"Automotive Underbody Coating" means a flexible coating which contains asphalt or
rubber and is designed and labeled exclusively for use on the underbody of motor
vehicles to resist rust, abrasion and vibration, and to deaden sound.
"Aviation Propeller Coating" means a coating designed and labeled exclusively to
provide abrasion resistance and corrosion protection for aircraft propellers.
"Aviation or Marine Primer" means a coating designed and labeled exclusively to meet
federal
specification TT-P-1757.
68
"Base Reactive Organic Gas Mixture" (Base ROG Mixture) means the mixture of
reactive organic gases utilized in deriving the MIR scale.
"Belt Dressing" means a product applied on auto fan bells, water pump belting, power
transmission belting, and industrial and farm machinery belting to prevent slipping, and
to extend belt life.
"Cleaner" means a product designed and labeled primarily to remove soil or other
contaminants from surfaces.
"Clear Coating" means a coating which is colorless, containing resins but no pigments
except flatting agents, and is designed and labeled to form a transparent or translucent
solid film.
"Coating Solids" means the nonvolatile portion of an aerosol coating product, consisting
of the film forming ingredients, including pigments and resins.
"Commercial Application" means the use of aerosol coating products in the production of
goods, or the providing of services for profit, including touch-up and repair.
"Corrosion Resistant Brass, Bronze, or Copper Coating" means a clear coating designed
and labeled exclusively to prevent tarnish and corrosion of uncoated brass, bronze, or
copper metal surfaces.
"Distributor" means any person to whom a consumer product is sold or supplied for the
purposes of resale or distribution in commerce, except that manufacturers, retailers, and
consumers are not distributors.
"Dye" means a product containing no resins which is used to color a surface or object
without building a film.
"Electrical Coating" means a coating designed and labeled exclusively as such, which is
used exclusively to coat electrical components such as wire windings on electric motors
to provide insulation and protection from corrosion.
"Enamel" means a coating which cures by chemical cross-linking of its base resin and is
not resoluble in its original solvent.
"Engine Paint" means a coating designed and labeled exclusively to coat engines and
their components.
"Exact Match Finish, Engine Paint" means a coating which meets all of the
following criteria:
The product is designed and labeled exclusively to exactly match the
color of an original, factory-applied engine paint;
69
The product is labeled with the manufacturer's name for which they
were formulated; and
The product is labeled with one of the following:
The original equipment manufacturer's (O.E.M.) color code
number;
The color name; or
Other designation identifying the specific O.E.M. color to the
purchaser.
"Exact Match Finish, Automotive" means a topcoat which meets all of the following
criteria:
The product is designed and labeled exclusively to exactly match the
color of an original, factory-applied automotive coating during the
touch-up of automobile finishes;
The product is labeled with the manufacturer's name for which they
were formulated; and
The product is labeled with one of the following:
The original equipment manufacturer's (O.E.M.) color code
number;
The color name; or
Other designation identifying the specific O.E.M. color to the
purchaser. Not withstanding the foregoing, automotive clear
coatings designed and labeled exclusively for use over
automotive exact match finishes to replicate the original
factory applied finish shall be considered to be automotive
exact match finishes.
"Exact Match Finish, Industrial" means a coating which meets all of the following
criteria:
The product is designed and labeled exclusively to exactly match the color of an
original, factory-applied industrial coating during the touch-up of manufactured
products;
70
The product is labeled with the manufacturer's name for which they
were formulated; and
The product is labeled with one of the following:
The original equipment manufacturer's (O.E.M.) color code
number;
The color name; or
Other designation identifying the specific O.E.M. color to the
purchaser.
"Flat Paint Products" means a coating which, when fully dry, registers specular gloss less
than or equal to
15
on an 85° gloss meter, or less than or equal to five on a 60
0 gloss
meter, or which is labeled as a flat coating.
"Flatting Agent" means a compound added to a coating to reduce the gloss of the coating
without adding color to the coating.
"Floral Spray" means a coating designed and labeled exclusively for use on fresh flowers,
dried flowers, or other items in a floral arrangement for the purposes of coloring,
preserving or protecting their appearance.
"Fluorescent Coating" means a coating labeled as such, which converts absorbed
incident light energy into emitted light of a different hue.
"Glass Coating" means a coating designed and labeled exclusively for use on glass or
other transparent material to create a soft, translucent light effect, or to create a tinted or
darkened color while retaining transparency.
"Ground Traffic/Marking Coating" means a coating designed and labeled exclusively to
be applied to dirt, gravel, grass, concrete, asphalt, warehouse floors, or parking lots.
Such coatings must be in a container equipped with a valve and sprayhead designed to
direct the spray toward the surface when the can is held in an inverted vertical position.
"High-Temperature Coating" means a high performance coating, excluding engine paint,
labeled and formulated for application to substrates exposed continuously or
intermittently to temperatures above 204°C (400°F).
"Hobby/Model/Craft Coating" means a coating which is designed and labeled exclusively
for hobby applications and is sold in aerosol containers of six ounces by weight or less.
"Ingredient" means a component of an aerosol coating product.
71
"Ink" means a fluid or viscous substance used in the printing industry to produce letters,
symbols or illustrations, but not to coat an entire surface.
"Lacquer" means a thermoplastic film-forming material dissolved in organic solvent,
which dries primarily by solvent evaporation, and is resoluble in its original solvent.
"Layout Fluid" (or toolmaker's ink) means a coating designed and labeled exclusively to
be sprayed on metal, glass or plastic, to provide a glare-free surface on which to scribe
designs, patterns or engineering guide lines prior to shaping the piece.
"Leather preservative or cleaner" means a leather treatment material applied exclusively
to clean or preserve leather.
"Lubricant" means a substance such as oil, petroleum distillates, grease, graphite,
silicone, lithium, etc. that is used to reduce friction, heat, or wear when applied between
surfaces.
"Manufacturer" means any person who imports, manufactures, assembles, produces,
packages, repackages, or relabels a consumer product.
"Marine Spar Varnish" means a coating designed and labeled exclusively to provide a
protective sealant for marine wood products.
"Maskant" means a coating applied directly to a component to protect surface areas when
chemical milling, anodizing, aging, bonding, plating, etching, or performing other
chemical operations on the surface of the component.
"Maximum Incremental Reactivity" (MIR) means the maximum change in weight of
ozone formed by adding a compound to the "Base ROG Mixture" per weight of
compound added, expressed to hundredths of a gram (g 0
3/g
ROC). MIR values for
individual compounds and hydrocarbon solvents are specified in Appendices A and B to
this Part.
"Metallic Coating" means a topcoat which contains at least 0.5 percent by weight
elemental metallic pigment in the formulation, including propellant, and is labeled as
"metallic", or with the name of a specific metallic finish such as "gold," "silver," or
"bronze."
"Mold Release" means a coating applied to molds to prevent products from sticking to
the surfaces of the mold.
"Multi-Component Kit" means an aerosol spray paint system which requires the
application of more than one component (e.g. foundation coat and top coat), where both
components are
sold together in one package.
72
"Nonflat Paint Product" means a coating which, when fully dry, registers a specular gloss
greater than 15 on an 85° gloss meter or greater than five on a 60
0
gloss meter.
"Ozone" means a colorless gas with a pungent odor, having the molecular form 03.
"Percent VOM By Weight" means the ratio of the weight of VOM to the total weight of
the product contents expressed as follows:
Percent VOM By Weight =
(WvoM/
Wtotal
)
x 100
Where:
For products containing no water and no volatile compounds exempt
from the definition of VOM: WvoM = the weight of volatile
materials;
For products containing water or exempt compounds: Wvom = the
weight of volatile compounds, less water, and less compounds exempt
from the VOM definition in Section 223.407; and
Wtow
= the total weight of the product contents.
"Photograph Coating" means a coating designed and labeled exclusively to be applied to
finished photographs to allow corrective retouching, protection of the image, changes in
gloss level, or to cover fingerprints.
"Pleasure Craft" means privately owned vessels used for noncommercial purposes.
"Pleasure Craft Finish Primer/Surfacer/Undercoater" means a coating designed and
labeled exclusively to be applied prior to the application of a pleasure craft topcoat for
the purpose of corrosion resistance and adhesion of the topcoat, and which promotes a
uniform surface by filling in surface imperfections.
"Pleasure Craft Topcoat" means a coating designed and labeled exclusively to be applied
to a pleasure craft as a final coat above the waterline and below the waterline when stored
out of water. This category does not include clear coatings.
"Polyolefin Adhesion Promoter" means a coating designed and labeled exclusively to be
applied to a polyolefin or polyolefin copolymer surface of automotive body parts,
bumpers, or trim parts to provide a bond between the surface and subsequent coats.
"Primer" means for purposes of this Part, a coating labeled and formulated for application
to a substrate to provide a firm bind between the substrate and subsequent coats.
"Product-Weighted M1R" (PWMIR) means the sum of all weighted-MIR for all
ingredients in a product subject to this article. The PWMIR is the total product reactivity
73
expressed to hundredths of a gram of ozone formed per gram of product (excluding
container and packaging) and calculated according to the following equations:
Weighted MIR (Wtd-MIR) ingredient = MIR x Weight fraction
ingredient,
and,
Product Weighted MIR = (Wtd-MIR) i
+ (Wtd-MIR)2
+...+ (Wtd-
MIR)n
Where,
MLR = ingredient MIR, as specified in Section 223.410(m);
Wtd-MIR = MIR of each ingredient in a product multiplied by the
weight fraction of that ingredient, as shown in (a);
1,2,3,...,n = each ingredient in the product up to the total n ingredients
in the product.
"Propellant" means a liquefied or compressed gas that is used in whole or in part to expel
a liquid or any other material from the same self-pressurized container or from a separate
container.
"Reactivity Limit" means the maximum "Product-Weighted MIR" allowed in an aerosol
coating product that is subject to the limits specified in Section 223.410(c) for a specific
category, expressed as g 0
3/g product.
"Reactive Organic Compound (ROC)" means any compound that has the potential, once
emitted, to contribute to ozone formation in the troposphere.
"Responsible Party" means the company, firm or establishment which is listed on the
product's label. If the label lists two companies, firms or establishments, the responsible
party is the party which the product was "manufactured for" or "distributed by," as noted
on the label.
"Retailer" means any person who sells, supplies, or offers consumer products for sale
directly to consumers.
"Retail Outlet" means for purposes of this Part, any establishment at which consumer
products are sold, supplied, or offered for sale directly to consumers.
"Rust Converter" means a product designed and labeled exclusively to convert rust to an
inert material and which contains a minimum acid content of 0.5 percent by weight, and a
maximum coating solids content of 0.5 percent by weight.
74
"Shellac Sealer" means a clear or pigmented coating formulated solely with the resinous
secretion of the lac beetle (Laccifer lacca), thinned with alcohol, and formulated to dry by
evaporation without a chemical reaction.
"Slip-Resistant Coating" means a coating designed and labeled exclusively as such,
which is formulated with synthetic grit and used as a safety coating.
"Spatter Coating/Multicolor Coating" means a coating labeled exclusively as such
wherein spots, globules, or spatters of contrasting colors appear on or within the surface
of a contrasting or similar background.
"Stain" means a clear, semi-transparent, or opaque coating labeled and formulated to
change the color of a surface, but not conceal the grain pattern or texture.
"Upper-Limit Kinetic Reactivity" (ULKR) means the maximum percentage of the
emitted ROC which has reacted. For Subpart D, the ULKR is one hundred percent and is
used to calculate the ULMIR.
"Upper-Limit Mechanistic Reactivity" (ULMR) means the maximum gram(s) of ozone
formed per gram of reactive organic compound (ROC) reacting. The ULMR is used to
calculate the ULMIR.
"Upper-Limit MIR" (ULMIR) means the upper-limit kinetic reactivity (ULKR)
multiplied by the upper-limit mechanistic reactivity (ULMR), as calculated using the
following equation:
ULMIR = Upper Limit KR x Upper Limit MR.
The units for ULMIR are g 03/g
ROC.
"Vinyl/Fabric/Leather/Polycarbonate Coating" means a coating designed and labeled
exclusively to coat vinyl, fabric, leather, or polycarbonate substrates.
"Webbing/Veiling Coating" means a coating designed and labeled exclusively to
provide a stranded to spider webbed appearance when applied.
"Weight Fraction" means the weight of an ingredient divided by the total net weight of
the product, expressed to thousandths of a gram of ingredient per gram of product
(excluding container and packaging). The weight fraction is calculated according to the
following equation:
Weight Fraction =?
Weight of the Ingredient
Total Product Net Weight
(excluding container and packaging).
75
"Weld-Through Primer" means a coating designed and labeled exclusively to provide a
bridging or conducting effect for corrosion protection following welding.
"Wood Stain" means a coating which is formulated to change the color of a wood surface
but not conceal the surface.
"Wood Touch-Up/Repair/Restoration" means a coating designed and labeled exclusively
to provide an exact color or sheen match on finished wood products.
"Working Day" means any day between Monday through Friday, inclusive, except for
days that are federal holidays.
Section 223.410
?
Limits and Requirements for Aerosol Coating Products
a)
Compliance with Limits. Aerosol coating products manufactured beginning
January 1, 2009, shall comply with the reactivity requirements specified in
Section 223.410(b).
b)
Reactivity Limits for Aerosol Coating Products.
Except as provided in Sections 223.410(a) and 223.420, no person shall sell,
supply, offer for sale, apply, or manufacture for use in Illinois, any aerosol
coating product which, at the time of sale, use, or manufacture, contains reactive
organic compounds that have a PWMIR in excess of the limits specified below
after January 1, 2009.
Aerosol Coating Category
?
Product-Weighted
MIR
in
Grams Ozone per Gram
Product (gO
3/g
product)
1)
General Coatings
A) Clear Coatings
1.50
B) Flat Paint Products
1.20
C) Fluorescent Coatings
1.75
D) Metallic Coatings
1.90
E) Nonflat Paint Products
1.40
F) Primers
1.20
76
2)
Specialty Coatings
A) Art Fixatives or Sealants
1.80
B) Auto Body Primers
1.55
C) Automotive Bumper
and Trim Products
1.75
D) Aviation or Marine Primers
2.00
E) Aviation Propeller Coatings
2.50
F) Corrosion Resistant Brass,
1.80
Bronze, or Copper Coatings
G) Exact Match Finishes:
1) Engine Enamel
1.70
2) Automotive
1.50
3) Industrial
2.05
H) Floral Sprays
1.70
I) Glass Coatings
1.40
J) Ground Traffic/Marking Coatings
1.20
K) High Temperature Coatings
1.85
L) Hobby/Model/Craft Coatings:
1) Enamel
1.45
2) Lacquer
2.70
3) Clear or Metallic
1.60
M) Marine Spar Varnishes
0.90
N) Photograph Coatings
1.00
0) Pleasure Craft Finish Primers,
1.05
77
Surfacers or Undercoaters
P) Pleasure Craft Topcoats
0.60
Q) Polyolefin Adhesion Promoters
2.50
R) Shellac Sealers:
1) Clear
1.00
2) Pigmented
0.95
S) Slip-Resistant Coatings
2.45
T) Spatter/Multicolor Coatings
1.05
U) Vinyl/Fabric/Leather/Polycarbonate Coatings
1.55
V) Webbing/Veil Coatings
0.85
W) Weld-Through Primers
1.00
X) Wood Stains
1.40
Y) Wood Touch-Up, Repair
or Restoration Coatings
1.50
c)
If an aerosol coating product is subject to both a general coating limit and a
specialty coating limit, as listed in subsection 223.410(b), and the product meets
all the criteria of the applicable specialty coating category as defined in Section
223.407, then the specialty coating limit shall apply instead of the general coating
limit.
d)
Notwithstanding the provisions of Sections 223.410(c) and 223.430, high
temperature coatings that contain at least 0.5 percent by weight of an elemental
metallic pigment in the formulation, including propellant, shall be subject to the
limit specified for metallic coatings.
e)
Notwithstanding the provisions of Section 223.410(a) and (b), an aerosol coating
product manufactured prior to each of the effective dates specified for that
product in Section 223.410(b) may be sold, supplied, offered for sale, or applied
for up to January 1, 2012. This subsection (f) does not apply to any product
which does not display on the product container or package the date on which the
product was manufactured, or a code indicating such date.
f)
Products Containing Methylene Chloride or Trichloroethylene.
78
1)?
For any aerosol coating product subject to the reactivity limits specified in
Section 223.410(b), no person shall sell, supply, offer for sale, apply, or
manufacture for use in Illinois any aerosol coating product which contains
methylene chloride or trichloroethylene.
2)?
The requirements of this Section shall not apply to any aerosol coating
product containing methylene chloride or trichloroethylene that is present
as an impurity in a combined amount equal to or less than 0.01% by
weight of the product.
g)
Products Containing Perchloroethylene or Ozone Depleting Substances.
I)
?
For any aerosol coating product subject to the reactivity limits specified in
Section 223.410(6), no person shall sell, supply, offer for sale, apply, or
manufacture for use in Illinois any aerosol coating product which contains
perchloroethylene.
2)
?
For any aerosol coating product subject to the reactivity limits specified in
Section 223.410(b), no person shall sell, supply, offer for sale, apply, or
manufacture for use in Illinois any aerosol coating product which contains
an ozone depleting substance identified by the USEPA in the Code of
Federal Regulations, 40 CFR Part 82, Subpart A, under Appendices A and
B, July 1, 1998.
3)
?
The requirements of Section 223.410(g)(1) and (g)(2) shall not apply to
any aerosol coating product containing perchloroethylene, or an ozone
depleting substance as identified in Section 223.410(g)(1) or (g)(2), that
are present as impurities in a combined amount equal to or less than 0.01%
by weight of the product.
h)?
Multicomponent Kits.
1)?
No person shall sell, supply, offer for sale, apply, or manufacture for use
in Illinois any multi-component kit, as defined in Section 223.407, in
which the total weight of VOM and methylene chloride contained in the
multi-component kit (Total VOM +
MC)actual
is greater than the total
weight of VOM and methylene chloride that would be allowed in the
multi-component kit if each component product in the kit had separately
met the applicable VOM standards (Total VOM+as
MC)standard
calculated
below:
(Total VOM +
MC)actual
(VOM1 x W1) + (MCI x W1) (VOM2
x W2) -I-
(MC2
x W2)
+ (VOM„ x
?
+ (MC„ x Wn)
79
(Total VOM + MC
)slam ard
(STD, x W 1 ) + (STD2
x W2)
+ (STD,, x
Where:
VOM =?
the percent by weight VOM of the
component product
MC =?
the percent by weight methylene chloride of
the Component product
STD =?
the VOM standard specified in Section
223.410(a) which applies to the component product
the weight of the product contents
(excluding container)
Subscript 1 denotes the first component product in the kit
Subscript 2 denotes the second component product in the kit
Subscript n denotes any additional component product
2)?
No person shall sell, supply, offer for sale, apply, or manufacture for use
in Illinois any multi-component kit, as defined in Section 223.407, in
which the Kit PWMIR is greater than the Total Reactivity Limit. The
Total Reactivity Limit represents the limit that would be allowed in the
multi-component kit if each component product in the kit had separately
met the applicable Reactivity Limit. The Kit PWMIR and Total
Reactivity Limit are calculated as in equations (A), (B) and (C) below:
A)
Kit PWMIR = (PWMIR ( , ) x W1 ) + (PWMIR(2)
x W2) +...+ (PWMIR(n) x
B)
Total Reactivity Limit = (RL, x W I ) + (RL2 x W2) +...+ (RL„ x
C)
Kit PWMIR <?
Total Reactivity Limit
Where:
the weight of the product contents (excluding
container)
RL?
=?
the Reactivity Limit specified in Section 223.410(b)
Subscript 1 denotes the first component product in the kit
Subscript 2 denotes the second component product in the kit
Subscript n denotes any additional component product
No person shall sell, supply, offer for sale, apply, or manufacture for use in the
state of Illinois any aerosol coating product assembled by adding bulk paint to
aerosol containers of propellant, unless such products comply with the reactivity
limits specified in Section 223.410(b) for products subject to those limits.
80
Assignment of Maximum Incremental Reactivity (MIR) Values.
1) In order to calculate the PWMIR of aerosol coating products as specified
in Section
223.407,
the MIR values of product ingredients are assigned as
follows:
A)
Any ingredient which does not contain carbon is assigned a MIR
value of 0.0.
B)
Any aerosol coating solid, including but not limited to resins,
pigments, fillers, plasticizers, and extenders is assigned a MIR
value of 0.0.
C)
For any ROC not covered under subparagraphs (A) and (B) of this
paragraph (1), each ROC is assigned the MIR value set forth in
Appendices A and B to this Part.
D)
Except as provided in paragraph
(3)
of this subsection, only ROCs
listed in Appendices A and B to this Part, can be used to comply
with the reactivity limits specified in Section
223.410(6).
E)
All individual compounds in an amount equal to or exceeding 0.1
percent shall be considered ingredients in calculating the PWMIR.
Such individual compounds shall be considered ingredients
whether or not they are reported by the manufacturer pursuant to
Appendix A and B.
?
2)
?
Calculating PWMIR Values.
A)
The MIR values dated January 1,
2009,
shall be used to calculate
the PWMIR for aerosol coating products.
B)
If a new ROC is added to Appendices A and B to this regulation,
then the new ROC may be used in aerosol coating products, and
the MIR value for the new ROC shall be used to calculate the
PWMIR after the effective date of the MIR value.
3)
The MIR value for any aromatic hydrocarbon solvent with a boiling range
different from the ranges specified in subsection (b) of Appendix B of this
Part shall be assigned as follows:
A)
?
If the solvent dry point is lower than or equal to
420
degrees F, the
MIR value specified in subsection (b) of Appendix B of this Part
for Bin 23 shall be used.
81
B)?
If the solvent initial boiling point is higher than 420 degrees F, the
MIR value specified in subsection (b) of Appendix B of this Part
for Bin 24 shall be used.
Section
223.420?
Exemptions
a)
This Subpart shall not apply to aerosol lubricants, mold releases, automotive
underbody coatings, electrical coatings, cleaners, belt dressings, anti-static sprays,
layout fluids and removers, adhesives, maskants, rust converters, dyes, inks, and
leather preservatives or cleaners.
b)
This Subpart shall not apply to any aerosol coating product manufactured in
Illinois for shipment and use outside of Illinois.
c)
The provisions of this Subpart shall not apply to a manufacturer, distributor, or
responsible party who sells, supplies, or offers for sale in Illinois an aerosol
coating product that does not comply with the limits specified in subsection
223.410(b), as long as the manufacturer, distributor, or responsible party can
demonstrate both that the aerosol coating product is intended for shipment and use
outside of Illinois, and that the manufacturer, distributor, or responsible party has
taken reasonable prudent precautions to assure that the aerosol coating product is
not distributed to Illinois. This subsection (c) does not apply to aerosol coating
products that are sold, supplied, or offered for sale by any person to retail outlets
in Illinois.
d)
The requirements in subsection 223.410(b) prohibiting the application of aerosol
coating products that exceed the limits specified in the subsection 223.410(b)
shall apply only to commercial application of aerosol coating products.
Section 223.430
?
Most Restrictive Limit
Except as otherwise provided in Section 223.410(c), if anywhere on the container of any aerosol
coating product subject to the specified limits in subsection 223.410(b), or on any sticker or label
affixed thereto, or in any sales or advertising literature, any representation is made that the
product may be used as, or is suitable for use as a product for which a lower limit is specified,
then the lowest applicable limit shall apply.
Section 223.440
?
Labeling Requirements
a)?
Both the manufacturer and responsible party for each aerosol coating product
subject to this Subpart shall ensure that all products clearly display the following
information on each product container which is manufactured 90 days or later
after the effective date of this Subpart.
82
1)
The applicable reactivity limit for the product that is specified in Section
223.410(b);
2)
The aerosol coating category as defined in Section 223.407, or an
abbreviation of the coating category; and
3)
The day, month, and year on which the product was manufactured, or a
code indicating such date.
b)
The information required in Section 223.440(a), shall be displayed on the product
container such that it is readily observable without removing or disassembling any
portion of the product container or packaging. For the purposes of this
subsection, information may be displayed on the bottom of a container as long as
it is clearly legible without removing any product packaging.
c)
No person shall remove, alter, conceal, or deface the information required in
Section 223.440(a) prior to final sale of the product.
d)
For any aerosol coating product subject to Section 223.410(a), if the manufacturer
or responsible party uses a code indicating the date of manufacture or an
abbreviation of the coating category as defined in Section 223.407, an explanation
of the code or abbreviation must be filed with the Agency prior to the use of the
code or abbreviation.
Section 223.450 Reporting
Requirements
a)
Any responsible party for an aerosol coating product subject to this article which
is sold, supplied, or offered for sale in Illinois, must supply the Agency, upon
request, with the following information within 30 days of the effective date of this
Subpart: the company name, mail address, contact person, and the telephone
number of the contact person. For responsible parties who do not manufacture
their own aerosol coating products, the responsible party shall also supply the
information specified in this subsection (a) for those manufacturers which
produce products for the responsible party. The responsible party shall also notify
the Agency within 30 days of any change in the information supplied to the
Agency pursuant to this subsection (a).
b)
Upon 30 days written notice, each manufacturer or responsible party subject to
this Subpart shall submit to the Agency a written report with all of the following
information for each product they manufacture under their name or another
company's name:
1)
The brand name of the product;
2)
Upon request, a copy of the product label;
3)
The owner of the trademark or brand names;
4)
The product category as defined in Section 223.407;
83
?
5)
?
The annual Illinois sales in pounds per year and the method
used to calculate Illinois annual sales;
?
6)?
Product formulation data:For products subject to the reactivity limits
specified in Section 223.410(c), the WMIR and the weight fraction of all
ingredients including: water, solids, each ROC, and any compounds
assigned a MIR value of zero as specified in Section 223.410(j), and
Appendices A or B to this Part. Each ROC must be reported as an
ingredient if it is present in an amount greater than or equal to 0.1% by
weight of the final aerosol coatings formulation. If an individual ROC is
present in an amount less than 0.1% by weight, then it does not need to be
reported as an ingredient. In addition, an impurity that meets the
following definition does not need to be reported as an ingredient.
For the purpose of this section, an "impurity" means an individual
chemical compound present in a raw material which is incorporated into
the final aerosol coatings formulation, if the compound is present below
the following amounts in the raw material:
A)
For individual compounds that are carcinogens, as
defined in 29 CFR section 1910.1200(d)(4), each
compound must be present in an amount less than
0.1% by weight in order to be considered an
"impurity."
B)
For all other compounds present in a raw material,
a compound must be present in an amount less
than one percent by weight in order to be considered
an "impurity";
?
7)?
An identification of each product brand name as a "household,"
"industrial," or "both" product; and
?
8)
?
Any other information necessary to determine the emissions or the
product-weighted MIR from aerosol coating products. The information
requested in this Subsection 223.450(6) may be supplied as an average for
a group of aerosol coating products within the same coating category
when the products do not vary in VOM content by more than two percent
(by weight), and the coatings are based on the same resin type, or the
products are color variations of the same product (even if the coatings vary
by more than two percent in VOM content).
c) Upon written request, the responsible party for aerosol coating products subject to this
Subpart shall supply the Agency with a list of all exempt compounds contained in any
aerosol coating product within 15 working days.
?
Section
223.460 Test Methods
84
Compliance with the requirements of this Subpart shall be determined by using the following test
methods, which are incorporated by reference herein. Alternative test methods which are shown
to accurately determine the VOM content, ingredient name and weight percent of each
ingredient, exempt compound content, metal content, specular gloss, or acid content may also be
used after approval in writing by the Agency:
a)
The VOM content of all aerosol coating products subject to the provisions of this
Subpart shall be determined by the procedures set forth in "Air Resources Board
Method 310, Determination of Volatile Organic Compounds (VOM) in Consumer
Products and Reactive Organic Compounds in Aerosol Coating Products,"
adopted September 25, 1997, and as last amended on May 5, 2005.
b)
Testing for Products Subject to the Reactivity Limits Specified in Section
223.410(b).
1)
The ingredients and the amount of each ingredient of all aerosol coating
products subject to the provisions of this Subpart shall be determined by
the procedures set forth in "Air Resources Board Method 310,
Determination of Volatile Organic Compounds (VOM) in Consumer
Products," adopted September 25, 1997 and as last amended on May 5,
2005.
2)
Upon written notification from the Agency, the aerosol coating
manufacturer shall have 10 working days to provide to the Agency the
following information for products selected for testing:
A)
The product category as defined in Section 223.407;
B)
The PWMIR;
C)
The weight fraction of all ingredients including: water, solids, each
ROC, and any compounds assigned a MIR value of zero as
specified in sections 223.410(j), and Appendices A and B to this
Part. Each ROC must be reported as an ingredient if it is present in
an amount greater than or equal to 0.1% by weight of the final
aerosol coatings formulation. If an individual ROC is present in an
amount less than 0.1% by weight, then it does not need to be
reported as an ingredient. In addition, an impurity that meets the
following definition does not need to be reported as an ingredient.
For the purpose of this section, an "impurity" means an individual
chemical compound present in a raw material which is
incorporated into the final aerosol coatings formulation, if the
compound is present below the following amounts in the raw
material:
85
For individual compounds that are carcinogens, as defined
in 29 CFR Section 1910.1200(d)(4), each compound must
be present in an amount less than 0.1% by weight in order
to be considered an "impurity."
For all other compounds present in a raw material, a
compound must be present in an'amount less than one
percent by weight in order to be considered an "impurity";
D) Any
other information necessary to determine the PWMIR of the
aerosol coating products to be tested.
3) Final
determination of the PWMIR of the aerosol coatings shall be
determined using the information obtained from Appendix A and B.
c)
Metal Content. The metal content of metallic aerosol coating products shall be
determined by SCAQMD Test Method 318-95 "Determination of Weight Percent
Elemental Metal in Coatings by X-ray Diffraction" July 1996, which is
incorporated by reference in Section 223.120.
d)
Specular Gloss. Specular gloss of flat and nonflat coatings shall be determined by
ASTM Method D-523-89, March 31, 1989, which is incorporated by reference in
Section 223.120.
e)
Acid Content. The acid content of rust converters shall be determined by ASTM
Method D-1613-96, "Standard Test Method for Acidity in Volatile Solvents and
Chemical Intermediates Used in Paint, Varnish. Lacquer, and Related Products,
May 10, 1996, which is incorporated by reference in Section 223.120.
Lacquers. Lacquer aerosol coating products shall be identified according to the
procedures specified in ASTM Method D-5043-90, "Standard Test Methods for
Field Identification of Coatings," April 27, 1990, which is incorporated by
reference in Section 223.120.
APPENDIX A MAXIMUM
INCREMENTAL REACTIVITY
Tables of Maximum Incremental Reactivity (MIR) Values
MIR Values for Compounds.
Organic Compound
MIR Value
1.
Carbon Monoxide
0.06
2.
Methane
0.01
3.
Ethane
0.31
86
4. Propane
?
0.56
5. n-Butane
?
1.33
6. n-Pentane
?
1.54
7. n-Hexane
?
1.45
8.
n-Heptane
?
1.28
9.
n-Octane
?
1.11
10. n-Nonane
?
0.95
11.
n-Decane
?
0.83
12.
n-Undecane
?
0.74
13. n-Dodecane
?
0.66
14. n-Tridecane
?
0.62
15. n-Tetradecane
?
0.58
16. n-Pentadecane
?
0.53
17.
n-C16
?
0.52
18.
n-C17
?
0.49
19.
n-C18
?
0.44
20.
n-C19
?
0.44
21.
n-C20
?
0.42
22.
n-C21
?
0.40
23.
n-C22
?
0.38
24.
Isobutane
?
1.35
25. Isopentane
?
1.68
26. Neopentane
?
0.69
27.
Branched C5 Alkanes
?
1.68
28.
2,2-Dimethyl Butane
?
1.33
29.
2,3-Dimethyl Butane
?
1.14
30.
2-Methyl Pentane (Isohexane)
?
1.80
31.
3-Methyl Pentane
?
2.07
32.
Branched C6 Alkanes
?
1.53
33.
2,2,3-Trimethyl Butane
?
1.32
34.
2,2-Dimethyl Pentane
?
1.22
35. 2,3-Dimethyl Pentane
?
1.55
36.
2,4-Dimethyl Pentane
?
1.65
37.
2-Methyl Hexane
?
1.37
38.
3,3-Dimethyl Pentane
?
1.32
39. 3-Methyl Hexane
?
1.86
40.
Branched C7 Alkanes
?
1.63
41.
2,2,3,3-Tetramethyl Butane
?
0.44
42.
2,2,4-Trimethyl Pentane (Isooctane)
?
1.44
43.
2,2-Dimethyl Hexane
?
1.13
44.
2,3,4-Trimethyl Pentane
?
1.23
45.
2,3-Dimethyl Hexane
?
1.34
46.
2,4-Dimethyl Hexane
?
1.80
47.
2,5-Dimethyl Hexane
?
1.68
48.
2-Methyl Heptane
?
1.20
49.
3-Methyl Heptane
?
1.35
87
50.
4-Methyl Heptane
?
1.48
51.
Branched C8 Alkanes
?
1.57
52.
2,2,5-Trimethyl Hexane
?
1.33
53.
2,3,5-Trimethyl Hexane
?
1.33
54.
2,4-Dimethyl Heptane
?
1.48
55.
2-Methyl Octane
?
0.96
56. 3,3-Diethyl Pentane
?
1.35
57.
3,5-Dimethyl Heptane
?
1.63
58. 4-Ethyl Heptane
?
1.44
59.
4-Methyl Octane
?
1.08
60.
Branched C9 Alkanes
?
1.25
61.
2,4-Dimethyl Octane
?
1.09
62.
2,6-Dimethyl Octane
?
1.27
63. 2-Methyl Nonane
?
0.86
64. 3,4-Diethyl Hexane
?
1.20
65. 3-Methyl Nonane
?
0.89
66.
4-Methyl Nonane
?
0.99
67.
4-Propyl Heptane
?
1.24
68.
Branched CIO Alkanes
?
1.09
69.
2,6-Dimethyl Nonane
?
0.95
70.
3,5-Diethyl Heptane
?
1.21
71.
3-Methyl Decane
?
0.77
72. 4-Methyl Decane
?
0.80
73.
Branched C11 Alkanes
?
0.87
74. 2,3,4,6-Tetramethyl Heptane
?
1.26
75. 2,6-Diethyl Octane
?
1.09
76.
3,6-Dimethyl Decane
?
0.88
77.
3-Methyl Undecane
?
0.70
78. 5-Methyl Undecane
?
0.72
79.
Branched C i 2 Alkanes
?
0.80
80.
2,3,5,7-Tetramethyl Octane
?
1.06
81.
3,6-Dimethyl Undecane
?
0.82
82.
3,7-Diethyl Nonane
?
1.08
83.
3-Methyl Dodecane
?
0.64
84.
5-Methyl Dodecane
?
0.64
85.
Branched C13 Alkanes
?
0.73
86.
2,4,6,8-Tetramethyl Nonane
?
0.94
87.
2,3,6-Trimethyl 4-Isopropyl Heptane
?
1.24
88.
3,7-Dimethyl Dodecane
?
0.74
89.
3,8-Diethyl Decane
?
0.68
90.
3-Methyl Tridecane
?
0.57
91.
6-Methyl Tridecane
?
0.62
92.
Branched C14 Alkanes
?
0.67
93.
2,4,5,6,8-Pentamethyl Nonane
?
1.11
94.
2-Methyl 3,5-Diisopropyl Heptane
?
0.78
95.
3,7-Dimethyl Tridecane
?
0.64
88
96.?
3,9-Diethyl Undecane
0.62
97.?
3-Methyl Tetradecane
0.53
98.
?
6-Methyl Tetradecane
0.57
99.?
Branched C15 Alkanes
0.60
100. 2,6,8-Trimethyl 4-Isopropyl Nonane
0.76
101. 3-Methyl Pentadecane
0.50
102. 4,8-Dimethyl Tetradecane
0.55
103. 7-Methyl Pentadecane
0.51
104. Branched C16 Alkanes
0.54
105. 2,7-Dimethyl 3,5-Diisopropyl Heptane
0.69
106. Branched C17 Alkanes
0.51
107. Branched C18 Alkanes
0.48
108. Cyclopropane
0.10
109. Cyclobutane
1.05
110. Cyclopentane
2.69
111. Cyclohexane
1.46
112. Isopropyl Cyclopropane
1.52
113. Methylcyclopentane
2.42
114. C6 Cycloalkanes
1.46
115. 1,3-Dimethyl Cyclopentane
2.15
116. Cycloheptane
2.26
117. Ethyl Cyclopentane
2.27
118. Methylcyclohexane
1.99
119. C7 Cycloalkanes
1.99
120. C8 Bicycloalkanes
1.75
121. 1,3-Dimethyl Cyclohexane
1.72
122. Cyclooctane
1.73
123. Ethylcyclohexane
1.75
124. Propyl Cyclopentane
1.91
125. C8 Cycloalkanes
1.75
126. C9 Bicycloalkanes
1.57
127. 1,1,3-Trimethyl Cyclohexane
1.37
128. 1-Ethyl-4-Methyl Cyclohexane
1.62
129. Propyl Cyclohexane
1.47
130. C9 Cycloalkanes
1.55
131. C10 Bicycloalkanes
1.29
132. 1,3-Diethyl Cyclohexane
1.34
133. 1,4-Diethyl Cyclohexane
1.49
134. 1-Methyl-3-Isopropyl Cyclohexane
1.26
135. Butyl Cyclohexane
1.07
136. C10 Cycloalkanes
1.27
137. C11 Bicycloalkanes
1.01
138. 1,3-Diethyl-5-Methyl Cyclohexane
1.11
139. 1-Ethyl-2-Propyl Cyclohexane
0.95
140. Pentyl Cyclohexane
0.91
141. C11 Cycloalkanes
0.99
89
142. C12 Bicycloalkanes
0.88
143. C12 Cycloalkanes
0.87
144. 1,3,5-Triethyl Cyclohexane
1.06
145. 1-Methyl-4-Pentyl Cyclohexane
0.81
146. Hexyl Cyclohexane
0.75
147. C13 Bicycloalkanes
0.79
148. 1,3-Diethyl-5-Propyl Cyclohexane
0.96
149. 1-Methyl-2-Hexyl Cyclohexane
0.70
150. Heptyl Cyclohexane
0.66
151. C13 Cycloalkanes
0.78
152. C14 Bicycloalkanes
0.71
153. 1,3-Dipropy1-5-Ethyl Cyclohexane
0.94
154. 1-Methyl-4-Heptyl Cyclohexane
0.58
155. Octyl Cyclohexane
0.60
156. C14 Cycloalkanes
0.71
157. C15 Bicycloalkanes
0.69
158. 1,3,5-Tripropyl Cyclohexane
0.90
159. 1-Methyl-2-Octyl Cyclohexane
0.60
160. Nonyl Cyclohexane
0.54
161. C15 Cycloalkanes
0.68
162. 1,3-Dipropy1-5-Butyl Cyclohexane
0.77
163. 1-Methyl-4-Nonyl Cyclohexane
0.55
164. Decyl Cyclohexane
0.50
165. C16 Cycloalkanes
0.61
166. Ethene
9.08
167. Propene (Propylene)
11.58
168. 1-Butene
10.29
169. C4 Terminal Alkenes
10.29
170. 1-Pentene
7.79
171. 3-Methyl-1-Butene
6.99
172. C5 Terminal Alkenes
7.79
173. 1-Hexene
6.17
174. 3,3-Dimethy1-1-Butene
6.06
175. 3-Methyl-l-Pentene
6.22
176. 4-Methyl-1-Pentene
6.26
177. C6 Terminal Alkenes
6.17
178. 1-Heptene
4.20
179. 1-Octene
3.45
180. C8 Terminal Alkenes
3.45
181. 1-Nonene
2.76
182. C9 Terminal Alkenes
2.76
183. 1-Decene
2.28
184. C10 Terminal Alkenes
2.28
185. 1-Undecene
1.95
186. C11 Terminal Alkenes
1.95
187. C12 Terminal Alkenes
1.72
90
188. 1-Dodecene
1.72
189. 1-Tridecene
1.55
190. C13 Terminal Alkenes
1.55
191.?
1-Tetradecene
1.41
192. C14 Terminal Alkenes
1.41
193.
?
1-Pentadecene
1.27
194. CI5 Terminal Alkenes
1.27
195. 2-Methyl Pentene (Isobutene)
6.35
196. 2-Methyl-1-Butene
6.51
197. 2,3-Dimethyl-1-Butene
4.77
198. 2-Ethyl-I -Butene
5.04
199. 2-Methyl-I -Pentene
5.18
200. 2,3,3-Trimethyl-l-Butene
4.62
201. C7 Terminal Alkenes
4.20
202. 3-Methyl -2-Isopropyl- 1 -B utene
3.29
203. cis-2-Butene
13.22
204. trans-2-Butene
13.91
205. C4 Internal Alkenes
13.57
206. 2-Methyl-2-Butene
14.45
207. cis-2-Pentene
10.24
208. trans-2-Pentene
10.23
209. 2-Pentenes
10.23
210. C5 Internal Alkenes
10.23
211. 2,3-Dimethy1-2-Butene
13.32
212. 2-Methyl-2-Pentene
12.28
213. cis-2-Hexene
8.44
214. cis-3-Hexene
8.22
215. cis-3-Methyl-2-Pentene
12.84
216. cis-3-Methyl-2-Hexene
13.38
217. trans 3-Methyl-2-Hexene
14.17
218. trans 4-Methyl-2-Hexene
7.88
219. trans-2-Hexene
8.44
220. trans-3-Hexene
8.16
221. 2-Hexenes
8.44
222. C6 Internal Alkenes
8.44
223. 2,3-Dimethy1-2-Hex_ene
10.41
224. cis-3-Heptene
6.96
225. trans-4,4-Dimethyl-2-Pentene
6.99
226. trans-2-Heptene
7.33
227. trans-3-Heptene
6.96
228. 2-Heptenes
6.96
229. C7 Internal Alkenes
6.96
230. cis-4-Octene
5.94
231. trans-2,2-Dimethyl-3-Hexene
5.97
232. trans-2,5-Dimethyl-3-Hexene
5.44
233. trans-3-Octene
6.13
91
234. trans-4-Octene
5.90
235. 3-Octenes
6.13
236. C8 Internal Alkenes
5.90
237. 2,4,4-Trimethyl-2-Pentene
8.52
238. 3-Nonenes
5.31
239. C9 Internal Alkenes
5.31
240. trans-4-Nonene
5.23
241. 3,4-Diethyl-2-Hexene
3.95
242. cis-5-Decene
4.89
243. trans-4-Decene
4.50
244. CIO 3-Alkenes
4.50
245. CIO Internal Alkenes
4.50
246. trans-5-Undecene
4.23
247. C11 3-Alkenes
4.23
248. C11 Internal Alkenes
4.23
249. C12 2-Alkenes
3.75
250. C12 3-Alkenes
3.75
251. C12 Internal Alkenes
3.75
252. trans-5-Dodecene
3.74
253. trans-5-Tridecene
3.38
254. C13 3-Alkenes
3.38
255. 03 Internal Alkenes
3.38
256. trans-5-Tetradecene
3.08
257. C14 3-Alkenes
3.08
258. C14 Internal Alkenes
3.08
259. trans-5-Pentadecene
2.82
260. C15 3-Alkenes
2.82
261. C15 Internal Alkenes
2.82
262. C4 Alkenes
11.93
263. C5 Alkenes
9.01
264. C6 Alkenes
6.88
265. C7 Alkenes
5.76
266. C8 Alkenes
4.68
267. C9 Alkenes
4.03
268. C10 Alkenes
3.39
269. C11 Alkenes
3.09
270. C12 Alkenes
2.73
271. C13 Alkenes
2.46
272. C14 Alkenes
2.28
273. C15 Alkenes
2.06
274. Cyclopentene
7.38
275. 1-Methyl Cyclopentene
13.95
276. Cyclohexene
5.45
277. 1-Methyl
Cyclohexene
7.81
278. 4-Methyl Cyclohexene
4.48
279. 1,2-Dimethyl Cyclohexene
6.77
92
280.?
1,3-Butadiene
13.58
281. Isoprene
10.69
282. C6 Cyclic or Di-olefins
8.65
283. C7 Cyclic or Di-olefins
7.49
284. C8 Cyclic or Di-olefins
6.01
285. C9 Cyclic or Di-olefins
5.40
286. C10 Cyclic or Di-olefins
4.56
287. C11 Cyclic or Di-olefins
4.29
288. C12 Cyclic or Di-olefins
3.79
289. C13 Cyclic or Di-olefins
3.42
290. C14 Cyclic or Di-olefins
3.11
291. C15 Cyclic or Di-olefins
2.85
292. Cyclopentadiene
7.61
293. 3-Carene
3.21
294. a-Pinene (Pine Oil)
4.29
295. b-Pinene
3.28
296. d-Limonene (Dipentene or Orange Terpene)
3.99
297. Sabinene
3.67
298. Terpene
3.79
299. Styrene
1.95
300. a-Methyl Styrene
1.72
301. C9 Styrenes
1.72
302. C10 Styrenes
1.53
303. Benzene
0.81
304. Toluene
3.97
305. Ethyl Benzene
2.79
306. Cumene (Isopropyl Benzene)
2.32
307. n-Propyl Benzene
2.20
308. C9 Monosubstituted Benzenes
2.20
309. s-Butyl Benzene
1.97
310. C10 Monosubstituted Benzenes
1.97
311. n-Butyl Benzene
1.97
312. C11 Monosubstituted Benzenes
1.78
313. C12 Monosubstituted Benzenes
1.63
314. C13 Monosubstituted Benzenes
1.50
315. m-Xylene
10.61
316. o-Xylene
7.49
317. p-Xylene
4.25
318. C8 Disubstituted Benzenes
7.48
319. m-Ethyl Toluene
9.37
320. p-Ethyl Toluene
3.75
321. o-Ethyl Toluene
6.61
322. C9 Disubstituted Benzenes
6.61
323. o-Diethyl
Benzene
5.92
324. m-Diethyl Benzene
8.39
325. p-Diethyl Benzene
3.36
93
326. CIO Disubstituted Benzenes
5.92
327. C11 Disubstituted Benzenes
5.35
328. C12 Disubstituted Benzenes
4.90
329. C13 Disubstituted Benzenes
4.50
330. Isomers of Ethylbenzene
5.16
331. 1,2,3-Trimethyl Benzene
11.26
332. 1,2,4-Trimethyl Benzene
7.18
333. 1,3,5-Trimethyl Benzene
11.22
334. C9 Trisubstituted Benzenes
9.90
335. Isomers of Propylbenzene
6.12
336. 1,2,3,5-Tetramethyl Benzene
8.25
337. C10 Tetrasubstituted Benzenes
8.86
338. CIO Trisubstituted Benzenes
8.86
339. Isomers of Butylbenzene
5.48
340. C11 Pentasubstituted Benzenes
8.03
341. C11 Tetrasubstituted Benzenes
8.03
342. Cll Trisubstituted Benzenes
8.03
343. Isomers of Pentylbenzene
4.96
344. C12 Pentasubstituted Benzenes
7.33
345. C12 Hexasubstituted Benzenes
7.33
346. C12 Tetrasubstituted Benzenes
7.33
347. C12 Trisubstituted Benzenes
7.33
348. Isomers of Hexylbenzene
4.53
349. C13 Trisubstituted Benzenes
6.75
350. Indene
3.21
351. Indane
3.17
352. Naphthalene
3.26
353. Tetralin
2.83
354. Methyl Indans
2.83
355. Methyl Naphthalenes
4.61
356. 1-Methyl Naphthalene
4.61
357. 2-Methyl Naphthalene
4.61
358. C11 Tetralin or Indane
2.56
359. 2,3-Dimethyl Naphthalene
5.54
360. C12 Disubstituted Naphthalenes
5.54
361. Dimethyl Naphthalenes
5.54
362. C12 Monosubstituted Naphthalenes
4.20
363. C12 Tetralin or Indane
2.33
364. C13 Disubstituted Naphthalenes
5.08
365. C13 Trisubstituted Naphthalenes
5.08
366. C13 Monosubstituted Naphthalenes
3.86
367. Acetylene
1.25
368. Methyl Acetylene
6.45
369. 2-Butyne
16.33
370. Ethyl Acetylene
6.20
371. Methanol
0.71
94
372. Ethanol
1.69
373. Isopropanol (2-Propanol or Isopropyl Alcohol)
0.71
374. n-Propanol (n-Propyl Alcohol)
2.74
375. Isobutanol (Isobutyl Alcohol)
2.24
376. 1-Butanol (n-Butyl Alcohol)
3.34
377. 2-Butanol (s-Butyl Alcohol)
1.60
378. t-Butyl Alcohol
0.45
379. Cyclopentanol
1.96
380. 2-Pentanol
1.74
381. 3-Pentanol
1.73
382. n-Pentanol (Amyl Alcohol)
3.35
383. Isoamyl Alcohol (3-Methy1-1-Butanol)
2.73
384. 2-Methyl-I-Butanol
2.60
385. Cyclohexanol
2.25
386. 1-Hexanol
2.74
387. 2-Hexanol
2.46
388. 4-Methyl-2-Pentanol (Methyl Isobutyl Carbinol)
2.89
389. 1-Heptanol
2.21
390. Dimethylpentanol (2,3-Dimethyl-l-Pentanol)
2.51
391. 1-Octanol
2.01
392. 2-Ethyl-I-Hexanol (Ethyl Hexyl Alcohol)
2.20
393. 2-Octanol
2.16
394. 3-Octanol
2.57
395. 4-Octanol
3.07
396. 5-Methyl-I-Heptanol
1.95
397. Trimethylcyclohexanol
2.17
398. Dimethylheptanol (2,6-Dimethyl-2-Heptanol)
1.07
399. 2,6-Dimethy1-4-Heptanol
2.37
400. Menthol
1.70
401. Isodecyl Alcohol (8-Methyl-1-Nonanol)
1.23
402. 1-Decanol
1.22
403. 3,7-Dimethy1-1-Octanol
1.42
404. Trimethylnonanolthreoerythro; 2,6,8-Trimethyl-4-Nonanol
1.55
405. Ethylene Glycol
3.36
406. Propylene Glycol
2.75
407. 1,2-Butanediol
2.21
408. Glycerol (1,2,3-Propanetriol)
3.27
409. 1,4-Butanediol
3.22
410. Pentaerythritol
2.42
411. 1,2-Dihydroxy Hexane
2.75
412. 2-Methyl-2,4-Pentanediol
1.04
413. 2-Ethyl-1,3-Hexanediol
2.62
414. Dimethyl Ether
0.93
415. Trimethylene Oxide
5.22
416. 1,3-Dioxolane
5.47
417. Dimethoxymethane
1.04
95
418. Tetrahydrofuran
4.95
419. Diethyl Ether
4.01
420. 1,4-Dioxane
2.71
421. Alpha-Methyltetrahydrofuran
4.62
422. Tetrahydropyran
3.81
423. Ethyl Isopropyl Ether
3.86
424. Methyl n-Butyl Ether
3.66
425. Methyl t-Butyl Ether
0.78
426. 2,2-Dimethoxypropane
0.52
427. Di n-Propyl Ether
3.24
428. Ethyl n-Butyl Ether
3.86
429. Ethyl t-Butyl Ether
2.11
430. Methyl t-Amyl Ether
2.14
431. Di-isopropyl Ether
3.56
432. Ethylene Glycol Diethyl Ether; 1,2-Diethoxyethane
2.84
433. Acetal (1,1-Diethoxyethane)
3.68
434. 4,4-Dimethyl-3-Oxahexane
2.03
435. 2-Butyl Tetrahydrofuran
2.53
436. Di-Isobutyl Ether
1.29
437. Di-n-butyl Ether
3.17
438. 2-Methoxy-1-(2-Methoxy-l-Methylethoxy)-Propane
2.09
439. Di-n-Pentyl Ether
2.64
440. Ethylene Glycol Monomethyl Ether (2-Methoxyethanol)
2.98
441. Propylene Glycol Monomethyl Ether (1-Methoxy-2-Propanol)
2.62
442. 2-Ethoxyethanol
3.78
443. 2-Methoxy-l-Propanol
3.01
444. 3-Methoxy-l-Propanol
4.01
445. Diethylene Glycol
3.55
446. Tetrahydro-2-Furanmethanol
3.54
447. Propylene Glycol Monoethyl Ether (1-Ethoxy-2-Propanol)
3.25
448. Ethylene Glycol Monopropyl Ether (2-Propoxyethanol)
3.52
449. 3-Ethoxy-l-Propanol
4.24
450. 3-Methoxy-1-Butanol
0.97
451. Diethylene Glycol Methyl Ether [2-(2-Methoxyethoxy) Ethanol]
2.90
452. Propylene Glycol Monopropyl Ether (1-Propoxy-2-Propanol)
2.86
453. Ethylene Glycol Monobutyl Ether [2-Butoxyethanol]
2.90
454. 3-Methoxy-3-Methyl-Butanol
1.74
455. n-Propoxypropanol
3.84
456. 2-(2-Ethoxyethoxy) Ethanol
3.19
457. Dipropylene Glycol
2.48
458. Triethylene Glycol
3.41
459. Propylene Glycol t-Butyl Ether (1-tert-Butoxy-2-Propanol)
1.71
460. 2-tert-Butoxy-l-Propanol
1.81
461. n-Butoxy-2-Propanol
2.70
462. Dipropylene Glycol Methyl Ether Isomer
(1-Methoxy-2[2-Hydroxypropoxyl-Propane)
2.21
96
463. Dipropylene Glycol Methyl Ether Isomer
(2-[2-Methoxypropoxy]- I -Propanol)
2.70
464. 2-Hexyloxyethanol
2.45
465. 2-(2-Propoxyethoxy)
3.00
466. 2,2,4-Trimethy1-1,3-Pentanediol
1.74
467. 2-(2-Butoxyethoxy)-Ethanol
2.87
468. 2-[2-(2-Methoxyethoxy) Ethoxy] Ethanol
2.62
469. Dipropylene Glycol Ethyl Ether
2.75
470. Ethylene Glycol 2-Ethylhexyl Ether [2-(2-Ethylhexyloxy) Ethanol]
1.71
471. 2-[2-(2-Ethoxyethoxy) Ethoxy] Ethanol
2.66
472. Tetraethylene Glycol
2.84
473. 1-(Butoxyethoxy)-2-Propanol
2.08
474. 2-(2-Hexyloxyethoxy) Ethanol
2.03
475. Glycol Ether dpnb (1-(2-Butoxy-l-Methylethoxy)-2-Propanol)
1.96
476. 2-[2-(2-Propoxyethoxy) Ethoxy] Ethanol
2.46
477. 2-[2-(2-Butoxyethoxy) Ethoxy] Ethanol
2.24
478. Tripropylene Glycol Monomethyl Ether
1.90
479. 2,5,8,11-Tetraoxatridecan-13-ol
2.15
480. 3,6,9,12-Tetraoxahexadecan-l-ol
1.90
481. Cumene Hydroperoxide (1-Methyl-l-Phenylethylhydroperoxide)*
12.61
482. Methyl Formate
0.06
483. Ethyl Formate
0.52
484. Methyl Acetate
0.07
485. gamma- Butyrolactone
1.15
486. Ethyl Acetate
0.64
487. Methyl Propionate
0.71
488. n-Propyl Formate
0.93
489. Isopropyl Formate
0.42
490. Ethyl Propionate
0.79
491. Isopropyl Acetate
1.12
492. Methyl Butyrate
1.18
493. Methyl Isobutyrate
0.70
494. n-Butyl Formate
0.95
495. Propyl Acetate
0.87
496. Ethyl Butyrate
1.25
497. Isobutyl Acetate
0.67
498. Methyl Pivalate (2,2-Dimethyl Propanoic Acid Methyl Ester)
0.39
499. n-Butyl Acetate
0.89
500. n-Propyl Propionate
0.93
501. s-Butyl Acetate
1.43
502. t-Butyl Acetate
0.20
503. Butyl Propionate
0.89
504. Amyl Acetate
0.96
.505. n-Propyl Butyrate
1.17
506. Isoamyl Acetate (3-Methylbutyl Acetate)
1.18
507. 2-Methyl-1 -Butyl Acetate
1.17
97
508. EEP Solvent (Ethyl 3-Ethoxy Propionate)
3.61
509. 2,3-Dimethylbutyl Acetate
0.84
510. 2-Methylpentyl Acetate
1.11
511. 3-Methylpentyl Acetate
1.31
512. 4-Methylpentyl Acetate
0.92
513. Isobutyl Isobutyrate
0.61
514. n-Butyl Butyrate
1.12
515. n-Hexyl Acetate (Hexyl Acetate)
0.87
516. Methyl Amyl Acetate (4-Methyl-2-PentanolAcetate)
1.46
517. n-Pentyl Propionate
0.79
518. 2,4-Dimethylpentyl Acetate
0.98
519. 2-Methylhexyl Acetate
0.89
520. 3-Ethylpentyl Acetate
1.24
521. 3-Methylhexyl Acetate
1.01
522. 4-Methylhexyl Acetate
0.91
523. 5-Methylhexyl Acetate
0.79
524. Isoamyl Isobutyrate
0.89
525. n-Heptyl Acetate (Heptyl Acetate)
0.73
526. 2,4-Dimethylhexyl Acetate
0.93
527. 2-Ethyl-Hexyl Acetate
0.79
528. 3,4-Dimethylhexyl Acetate
1.16
529. 3,5-Dimethylhexyl Acetate
1.09
530. 3-Ethylhexyl Acetate
1.03
531. 3-Methylheptyl Acetate
0.76
532. 4,5-Dimethylhexyl Acetate
0.86
533. 4-Methylheptyl Acetate
0.72
534. 5-Methylheptyl Acetate
0.73
535. n-Octyl Acetate
0.64
536. 2,3,5-Trimethylhexyl Acetate
0.86
537. 2,3-Dimethylheptyl Acetate
0.84
538. 2,4-Dimethylheptyl Acetate
0.88
539. 2,5-Dimethylheptyl Acetate
0.86
540. 2-Methyloctyl Acetate
0.63
541. 3,5-Dimethylheptyl Acetate
1.01
542. 3,6-Dimethylheptyl Acetate
0.87
543. 3-Ethylheptyl Acetate
0.71
544. 4,5-Dimethylheptyl Acetate
0.96
545. 4,6-Dimethylheptyl Acetate
0.83
546. 4-Methyloctyl Acetate
0.68
547. 5-Methyloctyl Acetate
0.67
548. n-Nonyl Acetate
0.58
549. 3,6-Dimethyloctyl Acetate
0.88
550. 3-Isopropylheptyl Acetate
0.71
551. 4,6-Dimethyloctyl Acetate
0.85
552. 3,5,7-Trimethyloctyl Acetate
0.83
553. 3-Ethyl-6-Methyloctyl Acetate
0.80
98
554. 4,7-Dimethylnonyl Acetate
0.64
555. Methyl Dodecanoate (Methyl Laurate)
0.53
556. 2,3,5,7-Tetramethyloctyl Acetate
0.74
557. 3,5,7-Trimethylnonyl Acetate
0.76
558. 3,6,8-Trimethylnonyl Acetate
0.72
559. 2,4,6,8-Tetramethylnonyl Acetate
0.63
560. 3-Ethyl-6,7-Dimethylnonyl Acetate
0.76
561. 4,7,9-Trimethyldecyl Acetate
0.55
562. Methyl Myristate (Methyl Tetradecanoate)
0.47
563. 2,3,5,6,8-Pentaamethylnonyl Acetate
0.74
564. 3,5,7,9-Tetramethyldecyl Acetate
0.58
565. 5-Ethyl-3,6,8-Trimethylnonyl Acetate
0.77
566. Dimethyl Carbonate
0.06
567. Propylene Carbonate (4-Methyl-1,3-Dioxolan-2-one)
0.25
568. Methyl Lactate
2.75
569. 2-Methoxyethyl Acetate
1.18
570. Ethyl Lactate
2.71
571. Methyl Isopropyl Carbonate
0.69
572. Propylene Glycol Monomethyl Ether Acetate
(1-Methoxy-2-Propyl Acetate)
1.71
573. 2-Ethoxyethyl Acetate
1.90
574. 2-Methoxy-l-Propyl Acetate
1.12
575. Methoxypropanol Acetate
1.97
576. Dimethyl Succinate
0.23
577. Ethylene Glycol Diacetate
0.72
578. 1,2-Propylene Glycol Diacetate
0.94
579. Diisopropyl Carbonate
1.04
580. Dimethyl Glutarate
0.51
581. Ethylene Glycol Monobutyl Ether Acetate (2-Butoxyethyl Acetate)
1.67
582. Dimethyl Adipate
1.95
583. 2-(2-Ethoxyethoxy) Ethyl Acetate
1.50
584. Dipropylene Glycol n-Propyl Ether Isomer #1
2.13
585. Dipropylene Glycol Methyl Ether Acetate Isomer #1
1.41
586. Dipropylene Glycol Methyl Ether Acetate Isomer #2
1.58
587. Dipropylene Glycol Methyl Ether Acetate
1.49
588. Glyceryl Triacetate
0.57
589. 2-(2-Butoxyethoxy) Ethyl Acetate
1.38
590. Substituted C7 Ester (C12)
0.92
591.?
1-Hydroxy-2,2,4-Trimethylpenty1-3-Isobutyrate
0.92
592. 3-Hydroxy-2,2,4-Trimethylpenty1-1-Isobutyrate
0.88
593. Hydroxy-2,2,4-Trimethylpentyl Isobutyrate Isomers
(2,2,4-Trimethy1-1,3-Pentanediol Monoisobutyrate)
0.89
594. Substituted C9 Ester (C12)
0.89
595. Dimethyl Sebacate
0.48
596. Diisopropyl Adipate
1.42
597. Ethylene Oxide
0.04
99
598. Propylene Oxide
0.32
599. 1,2-Epoxybutane (Ethyl Oxirane)
1.02
600. Formic Acid
0.08
601. Acetic Acid
0.50
602. Glycolic Acid (Hydroxyacetic Acid)
2.67
603. Peracetic Acid (Peroxyacetic Acid)*
12.62
604. Acrylic Acid
11.66
605. Propionic Acid
0.79
606. Methacrylic Acid
18.78
607. Isobutyric Acid
1.22
608. Butanoic Acid
1.78
609. Malic Acid
7.51
610. 3-Methylbutanoic Acid
4.26
611. Adipic Acid
3.37
612. 2-Ethyl Hexanoic Acid
3.49
613. Methyl Acrylate
12.24
614. Vinyl Acetate
3.26
615. 2-Methyl-2-Butene-3-ol (1,2-Dimethylpropy1-1-en-l-ol)
5.12
616. Ethyl Acrylate
8.78
617. Methyl Methacrylate
15.84
618. Hydroxypropyl Acrylate
5.56
619. n-Butyl Acrylate
5.52
620. n-Butyl Acrylate
5.52
621. Isobutyl Acrylate
5.05
622. Butyl Methacrylate
9.09
623. Isobutyl Methacrylate
8.99
624. Isobomyl Methacrylate*
8.64
625. a-Terpineol
5.16
626. 2-Ethyl-Hexyl Acrylate
2.42
627. Furan
16.54
628. Formaldehyde
8.97
629. Acetaldehyde
6.84
630. Propionaldehyde
7.89
631. 2-Methylpropanal
5.87
632. Butanal
6.74
633. C4 Aldehydes
6.74
634. 2,2-Dimethylpropanal (Pivaldehyde)
5.40
635. 3-Methylbutanal (Isovaleraldehyde)
5.52
636. Pentanal (Valeraldehyde)
5.76
637. C5 Aldehydes
5.76
638. Glutaraldehyde
4.79
639. Hexanal
4.98
640. C6 Aldehydes
4.98
641. Heptanal
4.23
642. C7 Aldehydes
4.23
643. 2-Methyl-Hexanal
3.97
100
644. Octanal
3.65
645. C8 Aldehydes
3.65
646. Glyoxal
14.22
647. Methyl Glyoxal
16.21
648. Acrolein
7.60
649. Crotonaldehyde
10.07
650. Methacrolein
6.23
651. Hydroxy Methacrolein
6.61
652. Benzaldehyde
0.00
653. Tolualdehyde
0.00
654. Acetone
0.43
655. Cyclobutanone
0.68
656. Methyl Ethyl Ketone (2-Butanone)
1.49
657. Cyclopentanone
1.43
658. C5 Cyclic Ketones
1.43
659. Methyl Propyl Ketone (2-Pentanone)
3.07
660. 3-Pentanone
1.45
661. C5 Ketones
3.07
662. Methyl Isopropyl Ketone
1.64
663. 2,4-Pentanedione
1.02
664. Cyclohexanone
1.61
665. C6 Cyclic Ketones
1.61
666. Methyl Isobutyl Ketone (4-Methyl-2-Pentanone)
4.31
667. Methyl n-Butyl Ketone (2-Hexanone)
3.55
668. Methyl t-Butyl Ketone
0.78
669. C6 Ketones
3.55
670. C7 Cyclic Ketones
1.41
671. Methyl Amyl Ketone (2-Heptanone)
2.80
672. 2-Methyl-3-Hexanone
1.79
673. Di-Isopropyl Ketone
1.63
674. C7 Ketones
2.80
675. 3-Methyl-2-Hexanone
2.81
676. Methyl Isoamyl Ketone (5-Methyl-2-Hexanone)
2.10
677. C8 Cyclic Ketones
1.25
678. 2-Octanone
1.66
679. C8 Ketones
1.66
680. C9 Cyclic Ketones
1.13
681. 2-Propyl Cyclohexanone
1.71
682. 4-Propyl Cyclohexanone
2.08
683. 2-Nonanone
1.30
684. Di-Isobutyl Ketone (2,6-Dimethyl-4-Heptanone)
2.94
685. C9 Ketones
1.30
686. C10 Cyclic Ketones
1.02
687. 2-Decanone
1.06
688. C10 Ketones
1.06
689. 2,6,8-Trimethyl-4-Nonanone; Isobutyl Heptyl Ketone
1.86
101
690. Biacetyl
20.73
691. Methylvinyl ketone
8.73
692. Mesityl Oxide (2-Methyl-2-Penten-4-one)
17.37
693. Isophorone (3,5,5-Trimethyl-2-Cyclohexenone)
10.58
694. 1-Nonene-4-one
3.39
695. Hydroxy Acetone
3.08
696. Dihydroxyacetone
4.02
697. Methoxy Acetone
2.14
698. Diacetone Alcohol (4-Hydroxy-4-Methyl-2-Pentanone)
0.68
699. Phenol
1.82
700. C7 Alkyl Phenols
2.34
701. m-Cresol
2.34
702. p-Cresol
2.34
703. o-Cresol
2.34
704. C8 Alkyl Phenols
2.07
705. C9 Alkyl Phenols
1.86
706. CIO Alkyl Phenols
1.68
707. C11 Alkyl Phenols
1.54
708. C12 Alkyl Phenols
1.42
709. 2-Phenoxyethanol; Ethylene Glycol Phenyl Ether
3.61
710. 1 -Phenoxy-2-Propanol
1.73
711. Nitrobenzene
0.07
712. Para Toluene Isocyanate
0.93
713. Toluene Diisocyanate (Mixed Isomers)
0.00
714. Methylene Diphenylene Diisocyanate
0.79
715. N-Methyl Acetamide*
19.70
716. Dimethyl Amine
9.37
717. Ethyl Amine
7.80
718. Trimethyl Amine
7.06
719. Triethyl Amine*
16.60
720. Diethylenetriamine*
13.03
721. Ethanolamine
5.97
722. Dimethylaminoethanol
4.76
723. Monoisopropanol Amine (1-Amino-2-Propanol)*
13.42
724. 2-Amino-2-Methyl-l-Propanol*
15.08
725. Diethanol Amine
4.05
726. Triethanolamine
2.76
727. Methyl Pyrrolidone (N-Methyl-2-Pyrrolidone)
2.56
728. Morpholine*
15.43
729. Nitroethane*
12.79
730. Nitromethane*
7.86
731. 1-Nitropropane*
16.16
732. 2-Nitropropane*
16.16
733. Dexpanthenol (Pantothenylol)*
9.35
734. Methyl Ethyl Ketoxime (Ethyl Methyl Ketone Oxime)*
22.04
735. Hydroxyethylethylene Urea*
14.75
102
736. Methyl Chloride
0.03
737. Methylene Chloride (Dichloromethane)
0.07
738. Methyl Bromide
0.02
739. Chloroform
0.03
740. Carbon Tetrachloride
0.00
741. Methylene Bromide
0.00
742. Vinyl Chloride
2.92
743. Ethyl Chloride
0.25
744.?
1,1-Dichloroethane
0.10
745.
?
1,2-Dichloroethane
0.10
746. Ethyl Bromide
0.11
747.
?
1,1,1-Trichloroethane
0.00
748.?
1,1,2-Trichloroethane
0.06
749. 1,2-Dibromoethane
0.05
750. n-Propyl Bromide
0.35
751. n-Butyl Bromide
0.60
752. trans-1,2-Dichloroethene
0.81
753. Trichloroethylene
0.60
754. Perchloroethylene
0.04
755. 2-(Chloro-Methyl)-3-Chloro Propene
1.13
756. Monochlorobenzene
0.36
757. p-Dichlorobenzene
0.20
758. Benzotrifluoride
0.26
759. PCBTF (p-Trifluoromethyl-Cl-Benzene)
0.11
760. HFC-134a (1,1,1,2-Tetrafluoroethane)*
0.00
761. HFC-152a (1,1-Di fluoroethane)*
0.00
762. Dimethyl Sulfoxide
6.90
763. Unspeciated C6 Alkanes
1.48
764. Unspeciated C7 Alkanes
1.79
765. Unspeciated C8 Alkanes
1.64
766. Unspeciated C9 Alkanes
2.13
767. Unspeciated C10 Alkanes
1.16
768. Unspeciated Cll Alkanes
0.90
769. Unspeciated C12 Alkanes
0.81
770. Unspeciated C13 Alkanes
0.73
771. Unspeciated C14 Alkanes
0.67
772. Unspeciated C15 Alkanes
0.61
773. Unspeciated C16 Alkanes
0.55
774. Unspeciated C17 Alkanes
0.52
775. Unspeciated C18 Alkanes
0.49
776. Unspeciated C10 Aromatics
5.48
777. Unspeciated C11 Aromatics
4.96
778. Unspeciated C12 Aromatics
4.53
779. Base ROG Mixture
3.71
780. Alkane, Mixed - Predominantly (Minimally 94%) C13-14
0.67
781. Oxo-Hexyl Acetate
1.03
103
782. Oxo-Heptyl Acetate
0.97
783. Oxo-Octyl Acetate
0.96
784. Oxo-Nonyl Acetate
0.85
785. Oxo-Decyl Acetate
0.83
786. Oxo-Dodecyl Acetate
0.72
787. Oxo-Tridecyl Acetate
0.67
ULMIR (as defined in Section 94521(a)(71), title 17, California Code of
Regulations).
APPENDIX B MIR VALUES FOR HYDROCARBON SOLVENTS
(a)
Aliphatic Hydrocarbon Solvents
Bin
Average Boiling
Boiling Point***
(degrees
F)
Criteria
MIR Value
1
80-205
Alkanes (< 2% Aromatics)
2.08
2
80-205
N-
&
Iso-Alkanes (
>
90% and
<
2%
Aromatics)
1.59
3
80-205
Cyclo-Alkanes (_>_ 90% and
<
2%
Aromatics)
2.52
4
80-205
Alkanes (2 to
<
8% Aromatics)
2.24
5
80-205
Alkanes (8 to 22% Aromatics)
2.56
6
>205-340
Alkanes (< 2% Aromatics)
1.41
7
>205-340
N-
&
Iso-Alkanes (
>
90% and
<
2%
Aromatics)
1.17
8
>205-340
Cyclo-Alkanes (
>
90% and
<
2%
Aromatics)
1.65
9
>205-340
Alkanes (2 to
<
8% Aromatics)
1.62
10
>205-340
Alkanes (8 to 22% Aromatics)
2.03
11
>340-460
Alkanes (< 2% Aromatics)
0.91
12
>340-460
N-
&
Iso-Alkanes (
>
90% and
<
2%
104
Aromatics)
0.81
13 >340-460
14 >340-460
15 >340-460
16 >460-580
17 >460-580
18 >460-580
19 >460-580
20 >460-580
Cyclo-Alkanes ( > 90% and < 2%
Aromatics)
1.01
Alkanes (2 to < 8% Aromatics)
1.21
Alkanes (8 to 22% Aromatics)
1.82
Alkanes (< 2% Aromatics)
0.57
N- & Iso-Alkanes ( > 90% and < 2%
Aromatics)
0.51
Cyclo-Alkanes ( > 90% and < 2%
Aromatics)
0.63
Alkanes (2 to < 8% Aromatics) 0.88
Alkanes (8 to 22% Aromatics)
1.49
*** Average Boiling Point = (Initial Boiling Point + Dry Point) /
2
(b) Aromatic Hydrocarbon Solvents
Bin Boiling Range
Criteria
MIR Value
(degrees F)
21 280-290
Aromatic Content (98%)
7.37
22 320-350
Aromatic Content (>98%)
7.51
23 355-420 Aromatic Content (>98%)
8.07
24 450-535
Aromatic Content (>98%)
5.00
* ULMIR (as defined in Section 94521(a)(71), title 17, California Code of
Regulations).
105
TECHNICAL SUPPORT DOCUMENT
for
CONTROL OF VOLATILE ORGANIC MATERIAL
EMISSIONS
from
CONSUMER AND COMMERCIAL PRODUCTS,
ARCHITECTURAL AND INDUSTRIAL
MAINTENANCE COATINGS, AND AEROSOL
COATINGS
AQPSTR 07-02
November 2007
ILLINOIS ENVIRONMENTAL PROTECTION AGENCY
1021 NORTH GRAND AVENUE EAST
P.O. BOX 19276
SPRINGFIELD, ILLINOIS
62794-9276
Table of Contents
List of Acronyms
?
2
Tables
?
3
1.0?
Introduction ?
4
2.0
?
Consumer
2.1?
Description
Products
of
?
Sources and Emissions
?
88
?
2.2?
Emissions in Illinois from Regulated Products
?
9
?
2.3?
Technical Feasibility of Controls
?
15
?
2.4?
Flexibility in Compliance Measures
?
19
?
2.5?
Economic Reasonableness
?
20
?
2.6?
Cost Effectiveness of Controls
?
?
21
2.7?
Reduction of VOM Emissions in Illinois
?
?
29
2.8?
Affected Sources and Compliance Measures
?
33
3.0?
Architectural and Industrial Maintenance Coatings
? ?
34
3.1?
Description of Sources and Emissions
?
?
34
3.53.73.63.43.23.3?
?
?
?
?
?
Reduction
Affected
Emissions
Economic
Technical
Cost Effectiveness
Sources
Feasibility
of
Reasonablenessin
Illinois
VOM
and
of
Emissions
from
of
ControlsCompliance
ControlsRegulated
?
?
in
?
IllinoisMeasuresProducts
?
?
?
454539354041
4.0?
Aerosol
4.34.24.1
?
?
?
Emissions
Description
Technical
Coatings
Feasibility
in
?
of
Illinois
Sources
from
of
and
ControlsRegulated
Emissions
?
Products
?
?
?
47464650
4.44.64.5
?
?
?
Flexibility
Economic
Cost Effectiveness
in
ReasonablenessCompliance
of ControlsMeasures
?
?
?
?
525256
4.7?
Reduction of VOM Emissions in Illinois ?
?
57
4.8
?
Affected Sources and Compliance Measures
?
58
5.0 Summary
?
60
6.0?
References
?
62
Appendix A:?
Potentially Affected Manufacturers in Illinois
?
65
1
List of Acronyms
ACP?
Alternative Control Plan
AIM?
Architectural and Industrial Maintenance
CAA?
Clean Air Act
CARB?
California Air Resources Board
CFR
?
Code of Federal Regulations
CO
?
Carbon Monoxide
CRF?
Cost Recovery Factor
ERWA?
Emission Reduction-Weighted Average
HVOM?
High Volatility Organic Materials
IEPA?
Illinois Environmental Protection Agency
IPP?
Innovative Products Provision
LADCO?
Lake Michigan Air Directors Consortium
MIR?
Maximum Incremental Reactivity
MRPO?
Midwest Regional Planning Organization
MVOM?
Medium Volatility Organic Materials
NAA?
Non Attainment Area
NAAQS
?
National Ambient Air Quality Standards
NOx
?
Nitrogen Oxides
OTC?
Ozone Transport Commission
PSU
?
Primers, Sealers, and Undercoaters
PWMIR?
Product Weighted Maximum Incremental Reactivity
SCM
? Suggested Control Measures
SIP
?
State Implementation Plan
SWA? Sales Weighted Average
Tpd
? Tons Per Day
USEPA?
United States Environmental Protection Agency
VOM? Volatile Organic Material
2
Tables
Table 2.2.1
?
Proposed Regulated Product Categories and Limits
?
9
Table 2.2.2?
Consumer Product Emission Factors by Category
?
15
Table 2.2.3 VOM Emissions Due to Consumer and Commercial Products
During the Ozone Season ?
16
Table 2.6.1?
Cost Effectiveness Estimates for Consumer Products ?
-22
Table 2.7.1
?
Estimated VOM Emission Reductions for Consumer Products.... 30
Table 3.2.1
?
AIM Coating Categories and VOM Limits
?
35
Table 3.2.2 VOM Emissions Due to AIM Coatings During the Ozone Season ..38
Table 3.5.1?
Producer Cost Per Gallon for AIM Coatings ?
42
Table 3.5.2 Estimated Cost Effectiveness for AIM Coating Control
?
43
Table 4.2.1 Aerosol Coating Categories and PWMIR Limits
?
47
Table 4.2.2 VOM Emissions Due to Aerosol Coating Products ?
50
Table 4.5.1?
Cost Estimates Per Can for Aerosol Coating Products
? 55
3
1.0
Introduction
Pursuant to Section 109 of the Clean Air Act, as amended in 1990, and to protect the
public health, the United States Environmental Protection Agency ("USEPA") revised
the national ambient air quality standard ("NAAQS") for ozone. Effective July 17, 1997
the USEPA lowered the NAAQS for ozone to 0.080 parts per million from the previous
0.120 parts per million. In addition, the time period used for measuring compliance was
increased from the previous 1 hour to 8 hours. In Illinois, Chicago and the Metro East St.
Louis area have been designated as moderate ozone nonattainment areas under the new
NAAQS. Included in the Chicago nonattainment area ("NAA") are Cook, DuPage,
Kane, Lake, McHenry, and Will counties, as well as the Aux Sable Township and Goose
Lake Township in Grundy County, and Oswego Township in Kendall County. The
Metro East St. Louis NAA is comprised of Jersey, Madison, Monroe, and St. Clair
counties.
The precursors to the formation of ozone include volatile organic materials ("VOM"),
oxides of nitrogen ("NOx") and carbon monoxide ("CO"). Ozone formation is most
active during the summer months because the reactions are dependent on direct sunlight
and high ambient temperatures. Ozone is a powerful oxidant and, as such, reacts readily
with a wide range of substances. In humans, ozone is an irritant to the respiratory system
and may damage lung and other tissues. This damage can lead to impaired breathing and
reduced immunity to disease for people in good health. The effects may be more severe
for young children, the elderly, and people with preexisting respiratory diseases such as
4
asthma, bronchitis, and emphysema. Ozone oxidation can also damage plant tissue,
reducing the yield of some crops, and damage certain other materials such as rubber.
In 1997, the USEPA revised the NAAQS for ozone to reflect improved scientific
understanding of the health impacts of the pollutant. The change from the previous 1
hour standard to the 8 hour standard is based on extensive air pollution research that
indicated ozone is more harmful when a person is exposed over a longer period of time
even if the ozone concentration is lower. As such, the revised 8 hour standard is more
stringent than the previous 1 hour standard. The 8 hour standard had an effective date of
June 15, 2004, with the 1 hour standard being revoked one year later on June 15, 2005
(40 CFR Part 81).
To protect the public health of the citizens of the State of Illinois, and in an effort to
attain the 8 hour ozone NAAQS by 2010 as required by Section 181(a) of the Clean Air
Act, the Illinois Environmental Protection Agency ("Illinois EPA") is proposing to
reduce VOM emissions from consumer and commercial products, architectural and
industrial maintenance ("AIM") coatings, and aerosol coatings.
Consumer and commercial products are currently regulated by the USEPA by the
consumer and commercial products rule promulgated on Sept. 11, 1998, and codified at
40 CFR Part 59 Subpart D. This national rule currently limits the VOM content of 24
product categories. VOM emissions from these categories are estimated to have been
reduced by 20 percent from uncontrolled levels. However, the emissions due to the 24
5
categories currently being regulated account for only 48 percent of the consumer and
commercial products emission inventory3.
Architectural and industrial maintenance coatings are currently regulated by the USEPA
by the AIM coatings rule promulgated on Sept. 11, 1998, and codified at 40 CFR Part 59
Subpart D. This national rule includes container labeling requirements and is estimated
to reduce VOM emissions from AIM coatings by approximately 20% from uncontrolled
levels.
Aerosol Coatings are considered to be a Group III Consumer Product, and accordingly
are also regulated by 40 CFR Part 59 Subpart D. Currently, federal and Illinois consumer
product regulations do not deal specifically with the reactivity of various organic
compounds. The proposed rule for aerosol coatings limits the content of various VOM
compounds based upon their reactivity and their likelihood to form ground level ozone.
This proposed rule is based upon the California Air Resources Board's ("CARB")
"Regulation for Reducing the Ozone Formed from Aerosol Coating Product Emissions" 11
that has been employing a reactivity based standard for all aerosol coatings since January
1, 2003.
Further reductions in the aforementioned categories will be beneficial to the environment
and are considered to be both economically reasonable and technologically feasible. It is
for these reasons that the Illinois EPA has proposed this rule controlling consumer and
commercial products, AIM coatings, and aerosol coatings.
6
In evaluating the potential reductions of VOM emissions from consumer and commercial
products, architectural and industrial maintenance coatings, and aerosol coatings, Illinois
EPA has reviewed the findings of several groups researching the issue. The groups are
MACTEC, an environmental firm that is under contract with the Lake Michigan Air
Directors Consortium ("LADCO"); the Ozone Transport Commission ("OTC"), an
organization in the eastern United States created under the Clean Air Act; and the
California Air Resources Board ("CARB"). The OTC and CARB have drafted candidate
measures for the reduction of VOM that go beyond the current federal VOM limits, and
MACTEC, CARB, and USEPA have projected the potential reductions and the
associated cost of additional control through these measures.
This technical support document is based on the review and application of the
aforementioned organizations, and addresses the economic reasonableness and
technological feasibility of further regulation to reduce VOM emissions from consumer
and commercial products, AIM coatings, and aerosol coating products by limiting the
solvent content in these products, or the amount of ozone formed when these products are
used. It is the position of the Illinois EPA that further regulation of these source
categories is an integral part of its state implementation plan ("SIP") for achieving
attainment of the NAAQS in Illinois.
7
?
2.0?
Consumer and Commercial Products
?
2.1
?
Description of Sources and Emissions
As defined by the USEPA in the federal rule, a consumer product is any household or
institutional product (including paints, coatings, and solvents), or substance, or article
(including any container or packaging) held by any person, the use, consumption, storage,
disposal, destruction, or decomposition of which may result in the release of VOC (40
CFR § 59.202). Consumer and commercial products are chemically formulated products
used by household and institutional consumers including, but not limited to, detergents;
cleaning compounds; polishes; floor finishes; cosmetics; personal care products; home,
lawn and garden products; disinfectants; sanitizers; aerosol paints; and automotive
specialty products; but does not include other paint products, furniture coatings, or
architectural coatings. The description consumer and commercial products also refers to
aerosol adhesives, including aerosol adhesives used for consumer, industrial, and
commercial uses.
Consumer and commercial products are sold to retail customers for personal, household,
or automotive use, along with products marketed by wholesale distributors for use in
commercial or industrial settings such as beauty shops, schools, and hospitals. This
source category description includes hundreds of products sold to individuals such as
personal care products, household products, automotive aftermarket products, adhesives
and sealants, insecticides, coatings and a range of other miscellaneous products.
8