ILLINOIS POLLUTION CONTROL BOARD
    December 19, 1996
    IN THE MATTER OF:
    TRIENNIAL WATER QUALITY REVIEW
    AMENDMENTS TO 35 ILL. ADM. CODE
    302.202, 302.212, 302.213, 304.122, and
    304.301 (Ammonia Nitrogen)
    )
    )
    )
    )
    )
    )
    R94-1(B)
    (Rulemaking - Water)
    Adopted Rule. Final Order.
    OPINION AND ORDER OF THE BOARD (by R.C. Flemal and C.A. Manning):
    This matter comes before the Board on a regulatory proposal filed on February 24,
    1994 by the Illinois Environmental Protection Agency (Agency). In a prior action the Board
    promulgated portions of that proposal. Today the Board takes final action on the remaining
    provisions of the Agency’s proposal, those relating to ammonia.
    The Board's responsibility in this matter arises from the Environmental Protection Act
    (Act) (415 ILCS 5/1
    et seq.
    (1994)). The Board is charged therein to "determine, define, and
    implement the environmental control standards applicable in the state of Illinois”. (415 ILCS
    5/5(b) (1994).) More generally, the Board's rulemaking charge is based on the system of
    checks and balances integral to the Illinois environmental governance: the Board bears
    responsibility for the rulemaking and principal adjudicatory functions, while the Agency bears
    primary responsibility for the administration of the Act and Board regulations. The latter
    includes administering today's amendments.
    The Agency filed the instant proposal as part of its required review of the applicable
    water quality standards of Illinois pursuant to the Federal Water Pollution Control Act,
    commonly known as the Clean Water Act (CWA) (33 U.S.C. § 1251
    et seq
    . (1993)). Under
    section 101-607 of the CWA, the Agency is required to periodically, but at least every three
    years, review the water quality standards applicable in the State. This review, which is
    commonly known as the "triennial review”, lends its name to the instant proceeding.
    PROCEDURAL HISTORY
    The Board originally opened Docket R94-1 to consider amendments to the Board’s
    lead, mercury, and ammonia water quality regulations, as proposed by the Agency. Hearings
    to consider the full proposal were held before Board Hearing Officer Diane O’Neill on
    November 10, 1994 in Chicago, Illinois, and on November 22, 1994 in Springfield, Illinois;

    2
    testimony was received from the Agency, as well as from other interested persons
    1
    . Content
    of the testimony is detailed in the Board’s first notice opinion
    2
    .
    On December 8, 1994 an alternative proposal was filed under the sponsorship of a
    number of potentially affected dischargers
    3
    . The alternative proposal focused exclusively on
    concerns associated with the ammonia provisions of the then current proposal. An additional
    hearing was held on January 26, 1995 in Chicago, Illinois.
    Following a period of public comment
    4
    and a pre-hearing conference held on
    November 8, 1995, the Board by order of January 4, 1996 severed the docket. The Board
    determined that the record supported moving forward with those portions of the initial
    proposal that dealt with lead and mercury (Sections 302.208 and 302.407). These items were
    placed in docket R94-1(A). The lead and mercury provisions subsequently proceeded through
    first and second notice, and were adopted by Board order of May 16, 1996.
    In contrast, the Board determined that the ammonia provisions required additional
    development. Docket R94-1(B) was accordingly opened in the January 4, 1996 order to allow
    continued review of the ammonia provisions (Sections 302.202, 302.212, 302.213, 304.122,
    and 304.301) of the Agency’s proposal.
    Public hearings for Docket R94-1(B) were held before Board Hearing Officer Diane
    O’Neill on February 22 and 23, 1996 in Chicago, Illinois. The Board again received
    testimony from the Agency, as well as from other interested persons.
    On April 8, 1996 the Agency filed, as part of PC 8(B), an amended ammonia proposal.
    On July 18, 1996 the Board adopted the amended proposal for first notice. First notice
    publication of the amendments to Part 302 occurred in the
    Illinois Register
    on August 9, 1996
    at 20 Ill. Reg. 10539. The proposed amendments to Part 304 were published on August 16,
    1996 at 20 Ill. Reg. 10760.
    1
      
    For purposes of citation herein, hearing transcripts are cited according to hearing number and
    page (e.g., Tr1. at __), prefiled testimony is cited according to author and page (e.g., Mosher at
    ___) or to Exhibit number (Exh.), public comments are cited by the abbreviation “PC”..
    2
    Anyone interested in reviewing the full procedural history of this case may consult the first
    notice opinion. See In the Matter of: TRIENNIAL WATER QUALITY REVIEW:
    AMENDMENTS TO 35 ILL. ADM. CODE 302.202, 302.212, 302.213, 304.122, AND
    304.301, First Notice Opinion and Order, July 18, 1996.
    3
    The proponents consisted of the Cites of Batavia, Geneva, Moline, St. Charles, Sterling, and Rock
    Falls, identified in the early stages of the record as “the Cities”. In later filings, with changed
    membership, the proponents became identified as “the Ammonia Group”.
    4
    The interested person is directed to the Board’s first notice opinion for a summary of all of the
    public comments.

    3
    On November 21, 1996 the Board adopted the ammonia provisions for second notice.
    On December 17, 1996 the Joint Committee on Administrative Rules (JCAR) voted “no
    objection” to the Board taking final action on this matter.
    OVERVIEW OF TODAY’S AMENDMENTS
    Today’s amendments have two major provisions. The first deals with the General Use
    Water Quality Standards for un-ionized ammonia. The second deals with managing discharges
    of ammonia to certain waterways.
    Ammonia: General Use Water Quality Standards
    The Board’s water quality standards are found at 35 Ill. Adm. Code 302. At interest
    today are the Board’s General Use Water Quality Standards for ammonia, found at 35 Ill.
    Adm. Code 302.212.
    One of the General Use Water Quality Standards for ammonia is a total ammonia
    nitrogen standard of 15 mg/L. That standard is not changed today.
    The current standards also include an un-ionized ammonia of 0.04 mg/L, applicable at
    times when total ammonia nitrogen concentrations are between 1.5 mg/L and 15 mg/L. This
    standard is today replaced by four separate un-ionized ammonia standards: acute and chronic
    un-ionized ammonia standards applicable in the summer months, and acute and chronic un-
    ionized ammonia standards applicable in the winter months. The four values are:
    Acute Standard (AS) - Summer
    0.33 mg/L
    Chronic Standard (CS) - Summer
    0.057 mg/L
    Acute Standard (AS) - Winter
    0.14 mg/L
    Chronic Standard (CS) - Winter
    0.025 mg/L
    Revised tables showing the allowable total ammonia nitrogen concentrations at each of
    the four un-ionized ammonia standards are also included in today’s amendments.
    Effluent Modified Waters (Ammonia)
    Today's new Sections 302.213 and 304.122(c) and (d) define and give the Agency
    authority to implement a new concept in water quality management, Effluent Modified Waters
    (EMW). EMWs are waters downstream from an effluent outfall and outside of any allowable
    mixing zone, wherein discharges to the EMW are driven by general effluent standards rather
    than by back-calculation from the water quality standards. EMWs are to be identified by the
    Agency.
    For an EMW designation to apply, there must be a showing that total ammonia
    discharge concentrations are 1.5 mg/L or less in summer and 4.0 mg/L or less in winter, that
    the existing level of treatment will be maintained, and that new or increased ammonia loadings

    4
    to the stream would meet nondegradation standards in the stream. Further, acute ammonia
    standards must be met, and there can be no known uses of the stream that would be adversely
    affected by the discharge.
    Today’s action also includes repeal of Section 302.301, which provided for an
    exception to compliance with water quality standards for certain discharges during the winter
    months. This section expired by its own terms on July 1, 1991. The EMW provisions are
    intended to replace in part Section 302.301.
    DISCUSSION
    It is the Board’s responsibility whenever it engages in rulemaking to assure that the
    rule, as adopted, protects the environment, as well as conserves the public and private
    resources needed to maintain that protection. It is often a daunting responsibility.
    Nevertheless, we believe rules that are simultaneously environmentally responsive and
    economically responsible can be achieved. We further believe that today’s action represents
    such a balance.
    Our experience also reflects that we are most likely to achieve well-balanced rules
    when we have the active participation of the various interested and affected persons during the
    rulemaking process. That has certainly occurred here. The Board has benefited from the
    active participation of the Illinois Association of Wastewater Agencies (IAWA), the association
    that represents all municipal dischargers in Illinois; the United States Environmental Protection
    Agency (USEPA); environmental groups including the Sierra Club and Trout Unlimited; and a
    number of communities (exemplified by the Ammonia Group) and other dischargers. Today’s
    amendments have evolved over the tenure of this rulemaking proceeding in reaction to the
    perspectives of the participants. It reached maturity, we believe, in April 1996 when the
    Agency filed its amended proposal (PC 8(B)). That proposal not only provided resolution of
    some of the contentious issues that had been raised during the hearing process, but also
    reflected consideration of environmental responsiveness and economic responsibility that is
    necessary for the Board to adopt the proposal.
    In the remaining portions of this opinion we set forth the rationale for today’s action.
    Additionally, because today’s adopted rules do not include all the provisions advocated by all
    participants, we also explain why those provisions were not included. Moreover, we note that
    most of the discussion that follows focuses on the ammonia standards (Section 302.212). We
    emphasize that it is these standards and their environmental consequences, and the
    consequences related to National Pollutant Discharge Elimination System (NPDES) permits,
    that have been the focal point of this proceeding and consequently are the focal point of our
    discussion here.

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    Environmental Impact
    The Board’s action today is based on the need to protect the State’s lakes and streams
    from an elevated concentration of ammonia. Ammonia at elevated concentrations is toxic to
    aquatic organisms. Healthy aquatic communities are an integral part of a healthy environment.
    Accordingly, maintenance of a healthy environment requires placing a ceiling (i.e., a standard)
    on the amount of ammonia in our lakes and streams. The value of the ceiling (i.e., the value
    of standard) should be set at a level that prevents toxicity to the aquatic organisms.
    We are fortunate that ammonia’s effects on aquatic organisms constitute one of the
    better-studied aspects of environmental toxicology. We therefore know the concentrations at
    which ammonia becomes toxic to a large number of aquatic organisms, including a variety of
    fishes, shellfish, insects, and other invertebrates indigenous to Illinois waters. This
    information is summarized in the USEPA’s “Ambient Water Quality Criteria for Ammonia -
    1984”, also known as the National Criteria Document (NCD) for ammonia. This document is
    present in the record as Exhibit E of the Agency’s original proposal.
    We are also fortunate that there is a straightforward procedure used to convert raw
    toxicological data, such as that contained in the NCD, into meaningful water quality standards.
    This procedure essentially consists of identifying the aquatic species that are present and that
    need protection, noting the record of toxicology information for the species and contaminant at
    issue, and by using a set of protocols, deriving the ceiling value(s) that ensure the survival of
    the species at issue. The protocols are well-developed and accepted. They can be found in the
    USEPA’s “Guidelines for Deriving Numerical National Water Quality Criteria for the
    Protection of Aquatic Organisms and Their Uses”. This document is present in the record as
    Exhibit D of the Agency’s original proposal. The protocols are also contained in the Board’s
    own regulations at 35 Ill. Adm. Code 302.Subpart F.
    The Agency has carried out the exercise of calculating standards necessary to protect
    aquatic life indigenous to Illinois. They have used the most recent data, including some data
    more recent than that provided in the NCD. On this basis, the Agency proposed water quality
    standards that are necessary to assure protection of aquatic life in the General Use waters of
    this State. We also note that the NCD provides a “default” set of standards, premised on the
    presence of ammonia-sensitive species that do not exist in Illinois General Use waters. By
    recalculating the standards using only indigenous species, the Agency was able to propose
    standards less stringent than would follow from simply accepting the “default” standards.
    Moreover, we believe that a large number of participants in this proceeding agree with
    us fully, or in major part, concerning the need for the water quality standards in today’s
    amendments. We do note, however, that not all participants held this viewpoint. There is a
    perspective that the standards are not stringent enough, while another perspective is that the
    standards are too stringent.
    The view that the standards are insufficiently stringent stems, in part, from the
    observation that there are some waters in Illinois where unusually ammonia-sensitive fishes,

    6
    particularly salmonid fishes, including trout, are present. We agree that such waters do exist,
    although they are quite limited. It is because they are limited in extent that we do not today
    support incorporating salmonid fishes into any derivation of ammonia standards for Illinois
    General Use waters. We believe that the General Use Water Quality Standards should have
    general applicability and are accordingly an inappropriate vehicle to address support of very
    special and geographically-restricted areas. The Board observes that it has long utilized special
    standards for special needs
    5
    and that it will always entertain proposals to utilize this concept to
    give necessary protection to any Illinois waters that have special needs, including needs based
    on the presence of trout or other organisms.
    The opposing viewpoint that the standards are too stringent stems largely from the
    observation that many streams seem to be healthy now
    6
    , with the status quo ammonia
    standards. In fact, the Agency itself observes that only short reaches of streams in Illinois
    today warrant classification as “ammonia impaired”.
    The Board fully agrees that Illinois waters are on the whole fairly healthy under current
    ammonia standards. However, we disagree that this is a reason not to undertake today’s
    action. Our waters are healthy because they are not badly impacted by ammonia. By adopting
    today’s ammonia standards, we identify, based on the best science, the standards that are
    necessary to maintain high quality waters where high quality waters now exist.
    The Issue of Permit Limits
    As we note above, we find that today’s adopted standards are necessary to protect
    aquatic life generally in Illinois. Were this the sole issue before the Board, this proceeding
    would in all likelihood have been completed a long time ago, and the standards we adopt today
    would have been adopted significantly earlier.
    The fact of the matter is that this has not happened, and it has not happened because
    water quality standards serve more than the one purpose of defining the ceiling concentration
    necessary to protect life in our streams and lakes. Water quality standards also serve the very
    practical purpose of being the beginning point for determining limits in discharge permits. It
    is in this second purpose, and in fears that permit limits might change as a result of modifying
    the standards, that the disagreement in this proceeding has been most pronounced.
    The problem is essentially making practice comport with theory. The theory is that it
    is possible to determine the maximum amount that any discharger may discharge into a stream
    5
    The Board maintains a section in its water quality rules titled "Water Use Designations and Site
    Specific Water Quality Standards" at 35 Ill. Adm. Code Part 303. The Board promulgates the
    standards that are necessary to support special uses.
    6
    The record is indeed full of anecdotal information regarding the success of fisherman in the
    General Use waters of Illinois.

    7
    by determining the maximum amount the discharger may release without causing the in-stream
    water quality standard to be exceeded. Unfortunately, the theory falls short in practice.
    There are too many variables in most discharger/water body pairs to make simple
    associations between the discharger and in-stream water quality. Variations in the operations
    of the discharging plant, variations in discharge concentration, plus variations in stream flow,
    stream mixing, ambient in-stream concentrations, up-stream activities, and even season of the
    year, all contribute to the confounding of any simple relationship.
    Nevertheless, difficult or not, it is necessary that it be determined how much anyone
    can discharge without causing the water quality standards to be violated. It is necessary
    because it is the law that discharges be limited so as not to cause or contribute to water quality
    violations. It is also the law that no one may discharge unless they have a permit that specifies
    the limits of their discharging (i.e., they must have an NPDES permit).
    Under the Act, the Agency makes the determination of what limits are permissible in
    any Illinois NPDES permits. In turn, this Board reviews such Agency decisions that are
    contested. Moreover, the USEPA has oversight granted to it by Congress over all NPDES
    permits and may disapprove those that are found by USEPA to be inappropriate.
    The permitting decision begins by the Agency noting the applicable water quality
    standard(s) and using this information, in combination with other stream-specific and
    discharger-specific information, to come up with requisite permit limits. There is an “Agency
    way” of doing this that involves a mass balance procedure. The Agency procedure is not
    necessarily the only way the requisite permit limits could be determined, nor is it necessarily
    the way permitting authorities in other states accomplish this task. It is, however, a procedure
    that is established and has the endorsement of the USEPA.
    Clearly, from the earliest stages of this proceeding a principal and even sole concern of
    many of the participants from the regulated community has been that the Agency would use
    the proposed ammonia standards as the basis for imposing new, more stringent NPDES
    ammonia permit limits. More stringent NPDES permit limits could in turn require more
    extensive treatment and treatment facilities, each of which could impose a perceived
    unnecessary cost upon the discharger. This concern was certainly brought into focus when the
    Agency, at a hearing in November 1994, identified 20 municipal treatment facilities that, in
    the worst case, it believed would need to have the effluent limits in their NPDES permits
    adjusted downward, as a result of the new water quality standards, to such degree that
    additional treatment would be required.
    This concern has been compounded by the fact that none of the dischargers are able to
    determine what NPDES permit limits they would face under the proposed rules, short of
    actually applying for a new NPDES permit under the new standards and seeing what permit
    limits would be derived by the Agency. Nor could they tell in advance what might provide a
    successful basis for challenge should they disagree with new permit limits. Thus, none of the

    8
    “target 20” could tell whether they were indeed a worst case example, or in fact whether there
    was any consequence to them at all.
    Accordingly, a large part of the debate in this proceeding has focused on the
    methodology used by the Agency to derive permit limits from water quality standards.
    Indeed, uncertainty about this matter has been at the core of why this proceeding has taken so
    long. Although the Agency has included, in the record, guidelines that it follows in
    developing permits (See Exhs. 2L and 2M) and asserts that it intends to adopt regulations
    concerning the permitting procedures (Tr2. at 156; Tr3. at 261), the uncertainty still remains
    largely unaddressed.
    The Board has had to weigh whether the proposed standards could in fact move
    forward, while the issue of permit calculating procedures remained uncertain. The Board
    determined at first notice and second notice that the standards could move forward because we
    found that protection of the environment requires adoption of the new standards and because
    we found that during the protracted course of these proceedings many of the problematic issues
    for most ammonia dischargers were resolved. We find so again today.
    Some of the participants, particularly the Ammonia Group, have suggested that the
    Board itself adopt, as Board rules, procedures by which the Agency must calculate permit
    limits. We declined to do so. There are several reasons that support our decision, including
    that we are not ready today, in the absence of a record, to adopt or even consider for review
    such detailed, specific rules as would be necessary. Moreover, we are not today convinced
    that it is either appropriate or necessary to do so. The Agency is the State’s permitting
    authority, and we are reluctant to substantially alter the permitting structure in the way
    advocated without more justification than has yet been presented to us.
    This is not to say, however, that we put the issue of permit calculating procedures to
    rest. Indeed, we fully expect to look very closely at all permit calculation procedures brought
    to us in any ammonia permit appeal and to demand that the procedures be completely justified.
    Moreover, we stand ready to develop Board standards for the determination of permit limits to
    the degree our authority under the Act allows and as circumstances require. The Board also
    notes that under Section 28.1 of the Act the Board is authorized to grant an adjusted standard
    for those who can support such an adjustment.
    We finally note that the Ammonia Group also suggested that the Board provide by rule
    for the use of “scientifically defensible alternatives” to whatever water-quality based effluent
    limit procedure is used by the Agency. (PC 15(B) at 5.) The Board is not prepared at this
    time to do so, given that there is little evidence in the record to justify how details of this
    concept could be fashioned. However, as we note above, the Board intends to remain attentive
    to the ammonia permitting process and to whatever additional rulemaking efforts may be
    needed to assure that all NPDES permit limits are indeed “scientifically defensible”.

    9
    Economic Impact
    Costs and benefits are associated with both the ammonia standards and EMW
    provisions of today amendments.
    Adoption of the new water quality standards may require some facilities to incur costs
    if the facilities need to upgrade or add nitrification to their wastewater treatment to comply
    with new, lower permit limits. We cannot, however, at this point be certain whether any
    facilities will definitely find themselves in this position.
    As we noted, the Agency did, in the initial stages of this proceeding, identify 20
    municipal wastewater treatment facilities that it then believed might need upgrading, as the
    worst case scenario. (Mosher at 34.) The Agency estimated that the total cost of upgrading
    all of these facilities would be approximately $42 million. (Mosher at 34.) The Agency
    subsequently revised these figures downward to 11 facilities and a total cost of about $20
    million (Exh. 41 at 39), still as the worst-case scenario.
    Whether these latest cost figures are likely to occur remains uncertain. Since the
    Agency’s list includes only municipal dischargers, and some industrial discharges would
    conceivably also need treatment updates, the Agency figures may be underestimations.
    However, a number of the municipal dischargers that were on the Agency’s list, particularly
    those located on the Fox River, have made some forceful arguments during the course of this
    proceeding that, notwithstanding the Agency’s placing them on the list, they may not need to
    significantly upgrade their facilities to keep their receiving streams in compliance with the new
    standards.
    Another factor that confounds our ability to calculate the actual cost of today’s
    regulations is that some facilities will need to upgrade, including possibly adding additional
    ammonia removal capability, at some future date irrespective of whether the past or new
    standards are used. Ammonia removal occurs at facilities now because there are places where
    the safe ammonia carrying capacity of the receiving waters is taxed. As populations grow and
    discharge loadings increase, this will become progressively more the case whatever the in-
    stream ammonia standard may be. It would be inappropriate to totally attribute such growth-
    related needs for increased treatment to the small modifications of the ammonia standards
    today adopted.
     
    While there may be costs associated with today’s amendments, there are also distinct
    benefits. The new standards better protect Illinois’ waterways now and for the future. This,
    in turn, promises a better, cleaner, healthier environment for the State. A healthier
    environment is an enormous benefit, albeit even more difficult to quantify than are the costs.
    The benefits to the environment and the potential costs to some dischargers both stem
    from the portion of today’s amendments dealing with standards: the standards protect the
    environment, but some dischargers may have to provide better treatment so that the standards
    are achieved. We find that the balance presented in the instant case is not unreasonable.

    10
    There is also a substantial benefit associated with adoption of the EMW provisions of
    today’s amendments. Expiration of the winter ammonia exemption at 35 Ill. Adm. Code
    304.301 has produced a circumstance where many major municipal dischargers will have to
    comply with lowered winter ammonia permit limits. In many of these cases, compliance with
    the lowered limits will have implementation costs. The EMW provisions would provide an
    exemption similar to that previously available under Section 304.301 and hence allow the
    implementation costs to be avoided. The Agency estimates these avoidance costs to be
    approximately $157 million. (PC 12(B) at 11.)
    Effluent Modified Waters
    Of particular import to today’s amendments is the concept of EMW. This concept
    allows for environmental protection of those waterways needing protection at the same time
    that it minimizes the impact to dischargers to those waterways.
    The Board recognizes that the standard treatment methodology for ammonia nitrogen is
    nitrification in a biological treatment plant, usually activated sludge. This treatment method
    does not assure compliance with the chronic ammonia standards at all times outside of a
    mixing zone, especially in small streams. The Board further recognizes that additional
    treatment would come at great cost and with little or no benefit. The concept of EMW is
    employed to ensure that well-run treatment plants are not found to be routinely in violation
    where no harm is done to the aquatic environment.
    Status of the Amendments under Federal Law
    This proposal was accepted by the Board pursuant to Section 28.2 as a required rule to
    meet the requirements of the Clean Water Act. The Board is therefore required to adopt a rule
    that fully meets the applicable federal law and is consistent with Illinois statutes. The Board
    finds that today’s amendments meet the requirements of the Clean Water Act.
    ORDER
    The Board directs that the following amendments be submitted to the Secretary of State
    for final notice pursuant to Section 5-40 of the Illinois Administrative Procedure Act.
    TITLE 35: ENVIRONMENTAL PROTECTION
    SUBTITLE C: WATER POLLUTION
    CHAPTER I: POLLUTION CONTROL BOARD
    PART 302
    WATER QUALITY STANDARDS
    SUBPART A: GENERAL WATER QUALITY PROVISIONS

    11
    Section
    302.100
    Definitions
    302.101
    Scope and Applicability
    302.102
    Allowed Mixing, Mixing Zones and ZIDs
    302.103
    Stream Flows
    302.104
    Main River Temperatures
    302.105
    Nondegradation
    SUBPART B: GENERAL USE WATER
    QUALITY STANDARDS
    Section
    302.201
    Scope and Applicability
    302.202
    Purpose
    302.203
    Offensive Conditions
    302.204
    pH
    302.205
    Phosphorus
    302.206
    Dissolved Oxygen
    302.207
    Radioactivity
    302.208
    Numeric Standards for Chemical Constituents
    302.210
    Other Toxic Substances
    302.211
    Temperature
    302.212
    Ammonia Nitrogen and Un-ionized Ammonia
    302.213
    Effluent Modified Waters (Ammonia)
    SUBPART C: PUBLIC AND FOOD
    PROCESSING WATER SUPPLY STANDARDS
    Section
    302.301
    Scope and Applicability
    302.302
    Algicide Permits
    302.303
    Finished Water Standards
    302.304
    Chemical Constituents
    302.305
    Other Contaminants
    302.306
    Fecal Coliform
    SUBPART D: SECONDARY CONTACT AND
    INDIGENOUS AQUATIC LIFE STANDARDS
    Section
    302.401
    Scope and Applicability
    302.402
    Purpose
    302.403
    Unnatural Sludge
    302.404
    pH
    302.405
    Dissolved Oxygen

    12
    302.406
    Fecal Coliform (Repealed)
    302.407
    Chemical Constituents
    302.408
    Temperature
    302.409
    Cyanide
    302.410
    Substances Toxic to Aquatic Life
    SUBPART E: LAKE MICHIGAN WATER
    QUALITY STANDARDS
    Section
    302.501
    Scope and Applicability
    302.502
    Dissolved Oxygen
    302.503
    pH
    302.504
    Chemical Constituents
    302.505
    Fecal Coliform
    302.506
    Temperature
    302.507
    Existing Sources on January 1, 1971
    302.508
    Sources under Construction But Not in Operation on January 1, 1971
    302.509
    Other Sources
    SUBPART F: PROCEDURES FOR
    DETERMINING WATER QUALITY CRITERIA
    Section
    302.601
    Scope and Applicability
    302.603
    Definitions
    302.604
    Mathematical Abbreviations
    302.606
    Data Requirements
    302.612
    Determining the Acute Aquatic Toxicity Criterion for an Individual Substance -
    General Procedures
    302.615
    Determining the Acute Aquatic Toxicity Criterion - Toxicity Independent of Water
    Chemistry
    302.618
    Determining the Acute Aquatic Toxicity Criterion - Toxicity Dependent on Water
    Chemistry
    302.621
    Determining the Acute Aquatic Toxicity Criterion - Procedures for Combinations of
    Substances
    302.627
    Determining the Chronic Aquatic Toxicity Criterion for an Individual Substance -
    General Procedures
    302.630
    Determining the Chronic Aquatic Toxicity Criterion - Procedure for Combination of
    Substances
    302.633
    The Wild and Domestic Animal Protection Criterion
    302.642
    The Human Threshold Criterion
    302.645
    Determining the Acceptable Daily Intake
    302.648
    Determining the Human Threshold Criterion
    302.651
    The Human Nonthreshold Criterion

    13
    302.654
    Determining the Risk Associated Intake
    302.657
    Determining the Human Nonthreshold Criterion
    302.658
    Stream Flow for Application of Human Nonthreshold Criterion
    302.660
    Bioconcentration Factor
    302.663
    Determination of Bioconcentration Factor
    302.666
    Utilizing the Bioconcentration Factor
    302.669
    Listing of Derived Criteria
    Appendix A
    References to Previous Rules
    Appendix B
    Sources of Codified Sections
    AUTHORITY: Implementing Section 13 and authorized by Section 27 of the Environmental
    Protection Act [415 ILCS 5/13 and 27].
    SOURCE: Filed with the Secretary of State January 1, 1978; amended at 2 Ill. Reg. 44, p. 151,
    effective November 2, 1978; amended at 3 Ill. Reg. 20, p. 95, effective May 17, 1979: amended at
    3 Ill. Reg. 25, p. 190, effective June 21, 1979; codified at 6 Ill. Reg. 7818, amended at 6 Ill. Reg.
    11161, effective September 7, 1982; amended at 6 Ill. Reg. 13750, effective October 26, 1982;
    peremptory amendments at 10 Ill. Reg. 461, effective December 23, 1985; amended in R87-27 at
    12 Ill. Reg. 9911, effective May 27, 1988; amended in R85-29 at 12 Ill. Reg. 12082, effective July
    11, 1988; amended in R88-1 at 13 Ill. Reg. 5998, effective April 18, 1989; amended in R88-21(A)
    at 14 Ill. Reg. 2899, effective February 13, 1990; amended in R88-21(B) at 14 Ill. Reg. 11974,
    effective July 9, 1990; amended in R94-1(A) at 20 Ill. Reg. 7682, effective May 24, 1996;
    amended in R94-1(B) at ________ Ill. Reg. _____________, effective
    _________________________
    BOARD NOTE: This Part implements the Illinois Environmental Protection Act as of July 1,
    1994.
    Section 302.202 Purpose
    The General Use standards will protect the State's water for aquatic life (except as provided in
    Section 302.213), wildlife, agricultural use, secondary contact use and most industrial uses and
    ensure the aesthetic quality of the State's aquatic environment. Primary contact uses are
    protected for all General Use waters whose physical configuration permits such use.
    (Source: Amended at Ill. Reg. , effective )
    Section 302.212 Total Ammonia Nitrogen and Un-ionized Ammonia
    a)
    Total ammonia Ammonia nitrogen (as N: STORET Storet Number
    3161600610) shall in no case exceed 15 mg/lL.

    14
    b) If ammonia nitrogen is less than 15 mg/1 and greater than or equal to 1.5 mg/1,
    then un-ionized ammonia (as N) shall not exceed 0.04 mg/1.
    b)
    Un-ionized ammonia nitrogen (as N: STORET Number 00612) shall not exceed
    the acute and chronic standards given below subject to the provisions of Section
    302.208(a) and (b), and Section 302.213 of this Part.
    1)
    From April through October, the Acute Standard (AS) shall be 0.33
    mg/L and the Chronic Standard (CS) shall be 0.057 mg/L.
    2)
    From November through March, the AS shall be 0.14 mg/L and the CS
    shall be 0.025 mg/L.
    c) Ammonia nitrogen concentrations of less than 1.5 mg/1 are lawful regardless of
    un-ionized ammonia concentration.
    cd)
    For purposes of this Ssection, the concentration of un-ionized ammonia nitrogen
    as N and total ammonia nitrogen as N shall be computed according to the
    following equations:
    U = 1.0013N
    (1+10
    x
    )
    U =
    N
    [0.94412(1+10
    x
    ) + 0.0559]
    and N = U [0.94412(1+10
    x
    )+0.0559]
    where: X = 0.09018 + 2729.92 - pH
    (T + 273.16)
    U =
    Concentration of un-ionized ammonia as N in mg/L
    N =
    Concentration of ammonia nitrogen as N in mg/lL
    T =
    Temperature in degrees Celsius
    de)
    The following tables indicates the maximum total ammonia nitrogen
    concentrations (mg/lL as N) allowable pursuant to subsections (a) and (b) of this
    Section for certain combinations of pH and temperature:

    15
    AMMONIA NITROGEN
    WATER QUALITY STANDARD (mg/l)
    TEMP.
    pH
    0
    C
    (
    0
    F)
    6.0
    6.5
    7.0
    7.5
    8.0
    8.5
    9.0
    5
    (41)
    15
    15
    15
    9.6
    3.1
    1.5
    1.5
    10
    (50)
    15
    15
    15
    6.5
    2.1
    1.5
    1.5
    15
    (59)
    15
    15
    13.9
    4.4
    1.5
    1.5
    1.5
    20
    (68)
    15
    15
    9.6
    3.1
    1.5
    1.5
    1.5
    25
    (77)
    15
    15
    6.7
    2.1
    1.5
    1.5
    1.5
    30
    (86)
    15
    14.9
    4.7
    1.5
    1.5
    1.5
    1.5
    35
    (95)
    15
    10.7
    3.4
    1.5
    1.5
    1.5
    1.5
    1) Summer (April through October) Acute un-ionized ammonia 0.33 mg/L
    pH
    6.5
    7.0
    7.5
    7.75
    8.0
    8.25
    8.5
    9.0
    0
    F
    0
    C
    55
    12.8
    15.0
    15.0
    15.0
    15.0
    13.8
    7.9
    4.6
    1.7
    60 15.6 15.0 15.0 15.0 15.0 11.2 6.5 3.8 1.4
    65
    18.3
    15.0
    15.0 15.0 15.0 9.8 5.3 3.1 1.2
    70
    21.1
    15.0
    15.0
    15.0
    13.2
    7.6
    4.4
    2.6
    1.1
    75
    23.9
    15.0
    15.0
    15.0
    10.9
    6.3
    3.7
    2.2
    0.9
    80
    26.7
    15.0
    15.0
    15.0
    9.0
    5.2 3.1 1.9
    0.8
    85
    29.4
    15.0
    15.0
    13.1
    7.5
    4.4
    2.6 1.6
    0.7
    90
    32.2
    15.0
    15.0
    10.9
    6.3
    3.7
    2.2
    1.4
    0.7
    2) Summer (April through October) Chronic un-ionized ammonia 0.057 mg/L
    pH
    6.5
    7.0
    7.5
    7.75
    8.0
    8.25
    8.5
    9.0
    0
    F
    0
    C
    55
    12.8
    15.0
    15.0
    7.4
    4.2
    2.4
    1.4
    0.8
    0.3
    60
    15.6
    15.0
    15.0
    7.0
    3.4
    1.9
    1.1
    0.7
    0.2
    65
    18.3
    15.0
    15.0
    4.9
    2.8
    1.6
    0.9
    0.5
    0.2
    70
    21.1
    15.0
    12.6
    4.0
    2.3
    1.3
    0.8
    0.5
    0.2
    75
    23.9
    15.0
    10.3
    3.3
    1.9
    1.1
    0.6
    0.4
    0.2
    80
    26.7
    15.0
    8.6
    2.7
    1.6
    0.9
    0.5
    0.3
    0.1
    85
    29.4
    15.0
    7.8
    2.3
    1.3
    0.8
    0.4
    0.3
    0.1
    90
    32.2
    15.0
    5.8
    1.9
    1.1
    0.6
    0.4
    0.2
    0.1

    16
    3) Winter (November through March) Acute un-ionized ammonia 0.14 mg/L
    pH
    6.5
    7.0
    7.5
    7.75
    8.0
    8.25
    8.5
    9.0
    0
    F
    0
    C
    32
    0.0
    15.0
    15.0
    15.0
    15.0
    15.0
    9.2
    5.2
    1.7
    35
    1.7
    15.0
    15.0
    15.0
    15.0
    14.1
    8.0
    4.5
    1.5
    40
    4.4
    15.0
    15.0
    15.0
    15.0
    11.3
    6.4
    3.7
    1.3
    45
    7.2
    15.0
    15.0
    15.0
    15.0
    9.0
    5.1
    2.9
    1.0
    50
    10.0
    15.0
    15.0
    15.0
    12.8
    7.3
    4.1
    2.4
    0.9
    55
    12.8
    15.0
    15.0
    15.0
    10.3
    5.9
    3.4
    2.0
    0.7
    60
    15.6
    15.0
    15.0
    14.8
    8.4
    4.8
    2.7
    1.6
    0.6
    4) Winter (November through March) Chronic un-ionized ammonia 0.025mg/L
    pH
    6.5
    7.0
    7.5
    7.75
    8.0
    8.25
    8.5
    9.0
    0
    F
    0
    C
    32
    0.0
    15.0
    15.0
    9.1
    5.1
    2.9
    1.6
    0.9
    0.3
    35
    1.7
    15.0
    15.0
    7.9
    4.4
    2.5
    1.4
    0.8
    0.3
    40
    4.4
    15.0
    15.0
    6.3
    3.6
    2.0
    1.1
    0.7
    0.2
    45
    7.2
    15.0
    15.0
    5.0
    2.8
    1.6
    0.9
    0.5
    0.2
    50
    10.0
    15.0
    12.7
    4.0
    2.3
    1.3
    0.7
    0.4
    0.2
    55
    12.8
    15.0
    10.2
    3.3
    1.8
    1.0
    0.6
    0.3
    0.1
    60
    15.6
    15.0
    8.3
    2.6
    1.5
    0.9
    0.5
    0.3
    0.1
    (Source: Amended at Ill. Reg. , effective )
    Section 302.213 Effluent Modified Waters (Ammonia)
    a) Effluent modified waters are those waters or portions of waters that the Agency
    has determined, pursuant to 35 Ill. Adm. Code 309: Subpart A, to have the
    potential to exceed, and are therefore not subject to, the chronic ammonia
    standards of Section 302.212(b) downstream of an effluent outfall and outside of
    any allowable mixing zone. The Agency shall not identify a waterbody as an
    effluent modified water if it:
    1) has uses known to be adversely impacted by ammonia as designated
    under 35 Ill. Adm. Code 303.201 outside of any allowable mixing zone;
    or
    2)
    exceeds the acute standard of Section 302.212(b) of this Part.
    b) All effluent discharges to an effluent modified water must meet the requirements
    of 35 Ill. Adm. Code 304.122(d) prior to dilution with the receiving water.
    (Source: Added at Ill. Reg. ________________, effective __________________)

    17
    PART 304
    EFFLUENT STANDARDS
    SUBPART A: GENERAL EFFLUENT STANDARDS
    Section
    304.101
    Preamble
    304.102
    Dilution
    304.103
    Background Concentrations
    304.104
    Averaging
    304.105
    Violation of Water Quality Standards
    304.106
    Offensive Discharges
    304.120
    Deoxygenating Wastes
    304.121
    Bacteria
    304.122
    Total Ammonia Nitrogen (as N: STORET number 00610)
    304.123
    Phosphorus (STORET number 00665)
    304.124
    Additional Contaminants
    304.125
    pH
    304.126
    Mercury
    304.140
    Delays in Upgrading (Repealed)
    304.141
    NPDES Effluent Standards
    304.142
    New Source Performance Standards (Repealed)
    SUBPART B: SITE SPECIFIC RULES AND
    EXCEPTIONS NOT OF GENERAL APPLICABILITY
    Section
    304.201
    Wastewater Treatment Plant Discharges of the Metropolitan Sanitary District of
    Greater Chicago
    304.202
    Chlor-alkali Mercury Discharges in St. Clair County
    304.203
    Copper Discharges by Olin Corporation
    304.204
    Schoenberger Creek: Groundwater Discharges
    304.205
    John Deere Foundry Discharges
    304.206
    Alton Water Company Treatment Plant Discharges
    304.207
    Galesburg Sanitary District Deoxygenating Wastes Discharges
    304.208
    City of Lockport Treatment Plant Discharges
    304.209
    Wood River Station Total Suspended Solids Discharges
    304.210
    Alton Wastewater Treatment Plant Discharges
    304.211
    Discharges From Borden Chemicals and Plastics Operating Limited Partnership
    Into an Unnamed Tributary of Long Point Slough
    304.212
    Sanitary District of Decatur Discharges
    304.213
    UNO-VEN Refinery Ammonia Discharge
    304.214
    Mobil Oil Refinery Ammonia Discharge
    304.215
    City of Tuscola Wastewater Treatment Facility Discharges

    18
    304.216
    Newton Station Suspended Solids Discharges
    304.218
    City of Pana Phosphorus Discharge
    304.219
    North Shore Sanitary District phosphorus Discharges
    304.220
    East St. Louis Treatment Facility, Illinois-American Water Company
    304.221
    Ringwood Drive Manufacturing Facility in McHenry County
    304.222
    Intermittent Discharge of TRC
    SUBPART C: TEMPORARY EFFLUENT STANDARDS
    Section
    304.301
    Exception for Ammonia Nitrogen Water Quality Violations (Repealed)
    304.302
    City of Joliet East Side Wastewater Treatment Plant
    304.303
    Amerock Corporation, Rockford Facility
    Appendix A
    References to Previous Rules
    AUTHORITY: Implementing Section 13 and authorized by Section 27 of the Environmental
    Protection Act [415 ILCS 5/13 and 27].
    SOURCE: Filed with the Secretary of State January 1, 1978; amended at 2 Ill. Reg. 30, p.
    343, effective July 27, 1978; amended at 2 Ill. Reg. 44, p. 151, effective November 2, 1978;
    amended at 3 Ill. Reg. 20, p. 95, effective May 17, 1979; amended at 3 Ill. Reg. 25, p. 190,
    effective June 21, 1979; amended at 4 Ill. Reg. 20, p. 53 effective May 7, 1980; amended at 6
    Ill. Reg. 563, effective December 24, 1981; codified at 6 Ill. Reg. 7818: amended at 6 Ill.
    Reg. 11161, effective September 7, 1982; amended at 6 Ill. Reg. 13750, effective October 26,
    1982; amended at 7 Ill. Reg. 3020, effective March 4, 1983; amended at 7 Ill. Reg. 8111,
    effective June 23, 1983; amended at 7 Ill. Reg. 14515, effective October 14, 1983; amended
    at 7 Ill. Reg. 14910, effective November 14, 1983; amended at 8 Ill. Reg. 1600, effective
    January 18, 1984; amended at 8 Ill. Reg. 3687, effective March 14, 1984; amended at 8 Ill.
    Reg. 8237, effective June 8, 1984; amended at 9 Ill. Reg. 1379, effective January 21, 1985;
    amended at 9 Ill. Reg. 4510, effective March 22, 1985; peremptory amendment at 10 Ill. Reg.
    456, effective December 23, 1985; amended at 11 Ill. Reg. 3117, effective January 28, 1987;
    amended in R84-13 at 11 Ill. Reg. 7291 effective April 3, 1987; amended in R86-17(A) at 11
    Ill. Reg. 14748, effective August 24, 1987; amended in R84-16 at 12 Ill. Reg. 2445, effective
    January 15, 1988; amended in R83-23 at 12 Ill. Reg. 8658, effective May 10, 1988; amended
    in R87-27 at 12 Ill. Reg. 9905, effective May 27, 1988; amended in R82-7 at 12 Ill. Reg.
    10712, effective June 9, 1988; amended in R85-29 at 12 Ill. Reg. 12064, effective July 12,
    1988; amended in R87-22 at 12 Ill. Reg. 13966, effective August 23, 1988; amended in R86-3
    at 12 Ill. Reg. 20126, effective November 16, 1988; amended in R84-20 at 13 Ill. Reg. 851,
    effective January 9, 1989; amended in R85-11 at 13 Ill. Reg. 2060, effective February 6,
    1989; amended in R88-1 at 13 Ill. Reg. 5976, effective April 18, 1989; amended in R86-17B
    at 13 Ill. Reg. 7754, effective May 4, 1989; amended in R88-22 at 13 Ill. Reg. 8880, effective
    May 26, 1989; amended in R87-6 at 14 Ill. Reg. 6777, effective April 24, 1990; amended in
    R87-36 at 14 Ill. Reg. 9437, effective May 31, 1990; amended in R 88-21(B) at 14 Ill. Reg.
    12538, effective July 18, 1990; amended in R84-44 at 14 Ill. Reg. 20719, effective December

    19
    11, 1990; amended in R86-14 at 15 Ill. Reg. 241, effective December 18, 1990; amended in
    R93-8 at 18 Ill. Reg. 11574, effective July 7, 1994; amended in R87-33 at 18 Ill. Reg. 11574,
    effective July 7, 1994; amended in R95-14 at 20 Ill. Reg. 3528, effective February 8, 1996;
    amended in R94-1(B) at 20 Ill. Reg. , effective
    BOARD NOTE: This Part implements the Illinois Environmental Protection Act as of July 1,
    1994.
    Section 304.122 Total Ammonia Nitrogen (as N: STORET number 00610)
    a)
    No effluent from any source which discharges to the Illinois River, the Des
    Plaines River downstream of its confluence with the Chicago River System or
    the Calumet River System, and whose untreated waste load is 50,000 or more
    population equivalents shall contain more than 2.5 mg/lL of total ammonia
    nitrogen as N during the months of April through October, or 4 mg/lL at other
    times.
    b)
    Sources discharging to any of the above waters and whose untreated waste load
    cannot be computed on a population equivalent basis comparable to that used for
    municipal waste treatment plants and whose total ammonia nitrogen as N
    discharge exceeds 45.4 kg/day (100 pounds per day) shall not discharge an
    effluent of more than 3.0 mg/lL of total ammonia nitrogen as N.
    c)
    In addition to the effluent standards set forth in subsections (a) and (b) of this
    Section, all sources are subject to Section 304.105 unless the Agency determines
    as part of the NPDES Permit Program under 35 Ill. Adm. Code 309: Subpart A
    that alternate effluent standards are applicable pursuant to subsection (d) of this
    Section.
    d)
    All dischargers to effluent modified waters as defined at 35 Ill. Adm. Code
    302.213, except for treatment works qualifying under Section 304.120(c), shall
    have an effective NPDES permit with monthly average effluent limits of 1.5
    mg/L total ammonia as N during the months of April through October, and 4.0
    mg/L total ammonia as N at other times, as well as the following restrictions:
    1)
    Dischargers achieving lower ammonia concentrations than given above,
    yet not meeting the chronic water quality standards of 35 Ill. Adm. Code
    302.212(b), shall maintain their existing level of performance consistent
    with the facility's expected organic and hydraulic loadings for the
    duration of their NPDES permit.
    2)
    New or expanded discharges that increase ammonia loading to general
    use waters and/or create effluent modified waters or portions of waters
    must demonstrate compliance to the Agency with the nondegradation
    requirements at 35 Ill. Adm. Code 302.105.

    20
    (Source: Amended at Ill. Reg. ____________, effective )
    SUBPART C: TEMPORARY EFFLUENT STANDARDS
    Section 304.301 Exception for Ammonia Nitrogen Water Quality Violations (Repealed)
    a) Section 304.105 shall not apply to 35 Ill. Adm. Code 302.212 for any source
    during the months of November through March; except that during the months
    of November through March no source shall discharge an effluent containing a
    concentration of ammonia nitrogen greater than 4.0 mg/1 if the discharge, alone
    or in combination with other discharges, causes or contributes to a violation of
    35 Ill. Adm. Code 302.212.
    b) Compliance with the provisions of subsection (a) shall be achieved by March
    31, 1979, or such other date as required by NPDES permit, or as ordered by the
    Board Under Title VIII or Title IX of the Environmental Protection Act.
    c) After July 1, 1991, the exemption provided in this Section shall terminate.
    (Source: Repealed at Ill. Reg. ______________, effective )
    IT IS SO ORDERED.
    Board Member K.M. Hennessey abstained.
    I, Dorothy M. Gunn, Clerk of the Illinois Pollution Control Board, hereby certify that
    the above opinion and order was adopted on the _____ day of ___________, 1996 by a vote of
    ______________.
    ___________________________________
    Dorothy M. Gunn, Clerk
    Illinois Pollution Control Board

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