ILLINOIS POLLUTION CONTROL BOARD
November 6, 1997
IN THE MATTER OF:
)
)
R96-10
RCRA UPDATE, USEPA
)
(Identical in Substance Rules)
REGULATIONS (July 1, 1995, through
)
December 31, 1995)
)
____________________________________
IN THE MATTER OF:
)
)
R97-3
UIC UPDATE, USEPA REGULATIONS
)
(Identical-in-Substance Rules)
(January 1, 1996, through June 30, 1996)
)
____________________________________
IN THE MATTER OF:
)
)
R97-5
RCRA UPDATE, USEPA
)
(Identical in Substance Rules)
REGULATIONS (January 1, 1996,
)
through June 30, 1996)
)
Adopted Rule. Final Order.
ORDER OF THE BOARD (by K.M. Hennessey):
Pursuant to Section 13(c) and 22.4(a) of the Environmental Protection Act
(Act), 415 ILCS 5/13(c) & 22.4(a) (1996), the Board proposes amendments to the
Resource Conservation and Recovery Act of 1976 (RCRA Subtitle C) hazardous waste
regulations.
Section 22.4(a) provides for quick adoption of regulations that are “identical in
substance” to federal regulations adopted by the U.S. Environmental Protection Agency
(USEPA) to implement Sections 3001 through 3005 of the Resource Conservation and
Recovery Act of 1976 (RCRA Subtitle C), 42 U.S.C. §§ 6921-6925 (1996), and that
Title VII of the Act and Section 5 of the Administrative Procedure Act (APA), 5 ILCS
100/5-35 & 5-40 (1996), shall not apply. Because this rulemaking is not subject to
Section 5 of the APA, it is not subject to first notice or to second notice review by the
Joint Committee on Administrative Rules (JCAR). The federal RCRA Subtitle C
regulations are found at 40 CFR 260 through 268, 270 through 271, 273, and 279.
This order is supported by an opinion adopted on the same day. The Board will
submit Notices of Adopted Amendments for publication in the Illinois Register 30 days
after the date of this order, in order to allow USEPA an opportunity to review them
2
before they are filed and become effective. The complete text of the proposed rules
follows.
IT IS SO ORDERED.
I, Dorothy M. Gunn, Clerk of the Illinois Pollution Control Board, certify that
the above order was adopted on the 6th day of November 1997, by a vote of 7-0.
Dorothy M. Gunn, Clerk
Illinois Pollution Control Board
3
TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE G: WASTE DISPOSAL
CHAPTER I: POLLUTION CONTROL BOARD
SUBCHAPTER b: PERMITS
PART 702
RCRA AND UIC PERMIT PROGRAMS
SUBPART A: GENERAL PROVISIONS
Section
702.101
Purpose, Scope, and Applicability
702.102
Purpose and Scope (Repealed)
702.103
Confidentiality of Information Submitted to the Agency or Board
702.104
References
702.105
Rulemaking
702.106
Adoption of Agency Criteria
702.107
Permit Appeals and Review of Agency Determinations
702.108
Variances and Adjusted Standards
702.109
Enforcement Actions
702.110
Definitions
SUBPART B: PERMIT APPLICATIONS
Section
702.120
Permit Application
702.121
Who Applies
702.122
Completeness
702.123
Information Requirements
702.124
Recordkeeping
702.125
Continuation of Expiring Permits
702.126
Signatories to Permit Applications and Reports
SUBPART C: PERMIT CONDITIONS
Section
702.140
Conditions Applicable to all Permits
702.141
Duty to Comply
702.142
Duty to Reapply
702.143
Need to Halt or Reduce Activity Not a Defense
702.144
Duty to Mitigate
702.145
Proper Operation and Maintenance
702.146
Permit Actions
702.147
Property Rights
702.148
Duty to Provide Information
702.149
Inspection and Entry
702.150
Monitoring and Records
702.151
Signature Requirements
4
702.152
Reporting Requirements
702.160
Establishing Permit Conditions
702.161
Duration of Permits
702.162
Schedules of Compliance
702.163
Alternative Schedules of Compliance
702.164
Recording and Reporting
SUBPART D: ISSUED PERMITS
Section
702.181
Effect of a Permit
702.182
Transfer
702.183
Modification
702.184
Causes for Modification
702.185
Facility Siting
702.186
Revocation
702.187
Minor Modifications
AUTHORITY: Implementing Sections 13 and 22.4 and authorized by Section 27 of
the Environmental Protection Act [415 ILCS 5/13, 22.4 and 27].
SOURCE: Adopted in R81-32, 47 PCB 93, at 6 Ill. Reg. 12479, effective May 17,
1982; amended in R82-19, at 53 PCB 131, 7 Ill. Reg. 14352, effective May 17, 1982;
amended in R84-9 at 9 Ill. Reg. 11926, effective July 24, 1985; amended in R85-23 at
10 Ill. Reg. 13274, effective July 29, 1986; amended in R86-1 at 10 Ill. Reg. 14083,
effective August 12, 1986; amended in R86-28 at 11 Ill. Reg. 6131, effective March
24, 1987; amended in R87-5 at 11 Ill. Reg. 19376, effective November 12, 1987;
amended in R87-26 at 12 Ill. Reg. 2579, effective January 15, 1988; amended in R87-
29 at 12 Ill. Reg. 6673, effective March 28, 1988; amended in R87-39 at 12 Ill. Reg.
13083, effective July 29, 1988; amended in R89-1 at 13 Ill. Reg. 18452, effective
November 13, 1989; amended in R89-2 at 14 Ill. Reg. 3089, effective February 20,
1990; amended in R89-9 at 14 Ill. Reg. 6273, effective April 16, 1990; amended in
R92-10 at 17 Ill. Reg. 5769, effective March 26, 1993; amended in R93-16 at 18 Ill.
Reg. 6918, effective April 26, 1994; amended in R94-5 at 18 Ill. Reg. 18284, effective
December 20, 1994; amended in R95-6 at 19 Ill. Reg. 9913, effective June 27, 1995;
amended in R95-20 at 20 Ill. Reg. 11210, effective August 1, 1996; amended in R96-
10/R97-3/R97-5 at 21 Ill. Reg. ________, effective ____________________.
SUBPART A: GENERAL PROVISIONS
Section 702.110
Definitions
The following definitions apply to 35 Ill. Adm. Code 702, 703, 704, and 705. Terms
not defined in this Section have the meaning given by the appropriate Act. When a
defined term appears in a definition, the defined term is sometimes placed within
5
quotation marks as to an aid to readers. When a definition applies primarily to one or
more programs, those programs appear in parentheses after the defined terms.
“Act” or “Environmental Protection Act” means the Environmental
Protection Act [415 ILCS 5].
“Administrator” means the Administrator of the United States
Environmental Protection Agency, or an authorized representative.
“Agency” means the Illinois Environmental Protection Agency.
“Application” means the Agency forms for applying for a permit. For
RCRA, application also includes the information required by the Agency
under 35 Ill. Adm. Code 703.182 through 703.212 (contents of Part B
of the RCRA application).
“Appropriate act and regulations” means the Resource Conservation and
Recovery Act (RCRA); Safe Drinking Water Act (SDWA); or the
“Environmental Protection Act”, whichever is applicable; and applicable
regulations promulgated under those statutes.
“Approved program or approved State” means a State or interstate
program that has been approved or authorized by USEPA under 40 CFR
271 (199296) (RCRA) or Section 1422 of the SDWA (UIC).
“Aquifer” (RCRA and UIC) means a geological “formation”, group of
formations, or part of a formation that is capable of yielding a significant
amount of water to a well or spring.
“Area of review” (UIC) means the area surrounding an injection well
described according to the criteria set forth in 35 Ill. Adm. Code
730.106, or in the case of an area permit, the project area plus a
circumscribing area the width of that is either 402 meters (1/4 of a mile)
or a number calculated according to the criteria set forth in 35 Ill. Adm.
Code 730.106.
“Board” means the Illinois Pollution Control Board.
“Closure” (RCRA) means the act of securing a “Hazardous Waste
Management Facility” pursuant to the requirements of 35 Ill. Adm.
Code 724.
“Component” (RCRA) means any constituent part of a unit or any group
of constituent parts of a unit that are assembled to perform a specific
function (e.g., a pump seal, pump, kiln liner, or kiln thermocouple).
6
“Contaminant” (UIC) means any physical, chemical, biological, or
radiological substance or matter in water.
“Corrective action management unit” or “CAMU” means an area within
a facility that is designated by the Agency under 35 Ill. Adm. Code
724.Subpart S for the purpose of implementing corrective action
requirements under 35 Ill. Adm. Code 724.201 and RCRA section
3008(h). A CAMU shall only be used for the management of
remediation wastes pursuant to implementing such corrective action
requirements at the facility.
BOARD NOTE: USEPA must also designate a CAMU until it grants
this authority to the Agency. See the note following 35 Ill. Adm. Code
724.652.
“CWA” means the Clean Water Act (formerly referred to as the Federal
Water Pollution Control Act or Federal Water Pollution Control Act
Amendments of 1972), P.L. 92-500, as amended by P.L. 95-217 and
P.L. 95-576; 33 U.S.C. 1251 et seq. (199296).
“Date of approval by USEPA of the Illinois UIC program” means
March 3, 1984.
“Director” means the Director of the Illinois Environmental Protection
Agency or the Director’s designee.
“Disposal” (RCRA) means the discharge, deposit, injection, dumping,
spilling, leaking, or placing of any “hazardous waste” into or on any
land or water so that such hazardous waste or any constituent of the
waste may enter the environment or be emitted into the air or discharged
into any waters, including groundwater.
“Disposal Ffacility” (RCRA) means a facility or part of a facility at
which “hazardous waste” is intentionally placed into or on the land or
water, and at which hazardous waste will remain after closure. The term
disposal facility does not include a corrective action management unit
into which remediation wastes are placed.
“Draft Ppermit” means a document prepared under 35 Ill. Adm. Code
705.141 indicating the Agency’s tentative decision to issue, deny,
modify, terminate, or reissue a “permit”. A notice of intent to deny a
permit, as discussed in 35 Ill. Adm. Code 705.141, is a type of “draft
permit”. A denial of a request for modification, as discussed in 35 Ill.
Adm. Code 705.128, is not a “draft permit”. A “proposed permit” is
not a “draft permit”.
7
“Drilling Mmud” (UIC) means a heavy suspension used in drilling an
“injection well”, introduced down the drill pipe and through the drill bit.
“Elementary neutralization unit” means a device which:
Is used for neutralizing wastes that are hazardous wastes only
because they exhibit the corrosivity characteristics defined in 35
Ill. Adm. Code 721.122, or are listed in 35 Ill. Adm. Code
721.Subpart D only for this reason; and
Meets the definition of tank, tank system, container, transport
vehicle or vessel in 35 Ill. Adm. Code 720.110.
“Emergency Ppermit” means a RCRA or UIC “permit” issued in
accordance with 35 Ill. Adm. Code 703.221 or 704.163, respectively.
“Environmental Protection Agency” (“EPA” or “USEPA”) means the
United States Environmental Protection Agency.
“Exempted aquifer” (UIC) means an “aquifer” or its portion that meets
the criteria in the definition of “underground source of drinking water”
but which has been exempted according to the procedures in 35 Ill.
Adm. Code 702.105, 704.104, and 704.123(b).
“Existing hazardous waste management (HWM) facility” or “existing
facility” means a facility that was in operation or for which construction
commenced on or before November 19, 1980. A facility has
commenced construction if:
The owner or operator has obtained the Federal, State, and local
approvals or permits necessary to begin physical construction;
and
Either:
A continuous on-site, physical construction program has
begun; or
The owner or operator has entered into contractual
obligations--that cannot be cancelled canceled or modified
without substantial loss--for physical construction of the
facility to be completed within a reasonable time.
8
“Existing injection well” (UIC) means an “injection well” other than a
“new injection well”.
“Facility mailing list” means the mailing list for a facility maintained by
the Agency in accordance with 35 Ill. Adm. Code 705.163(a).
“Facility or activity” means any “HWM facility”, UIC “injection well”,
or any other facility or activity (including land or appurtenances thereto)
that is subject to regulations under the Illinois RCRA or UIC program.
“Facility mailing list” (RCRA) means the mailing list for a facility
maintained by the Agency in accordance with 35 Ill. Adm. Code
705.163.
“Federal, Sstate, and local approvals or permits necessary to begin
physical construction” means permits and approvals required under
Federal, State, or local hazardous waste control statutes, regulations, or
ordinances. (See 35 Ill. Adm. Code 700.102.)
“Final authorization” (RCRA) means approval by USEPA of the Illinois
Hazardous Waste Management Program that has met the requirements of
Section 3006(b) of RCRA and the applicable requirements of 40 CFR
271, Subpart A (199296). USEPA granted initial final authorization on
January 31, 1986.
“Fluid” (UIC) means any material or substance that flows or moves
whether in a semisolid, liquid, sludge, gas, or any other form or state.
“Formation” (UIC) means a body of rock characterized by a degree of
lithologic homogeneity that is prevailingly, but not necessarily, tabular
and is mappable on the earth’s surface or traceable in the subsurface.
“Formation fluid” (UIC) means “fluid” present in a “formation” under
natural conditions, as opposed to introduced fluids, such as “drilling
mud”.
“Functionally equivalent component” (RCRA) means a component that
performs the same function or measurement and which meets or exceeds
the performance specifications of another component.
“Generator” (RCRA) means any person, by site location, whose act or
process produces “hazardous waste” identified or listed in 35 Ill. Adm.
Code 721.
9
“Groundwater” (RCRA and UIC) means a water below the land surface
in a zone of saturation.
“Hazardous Wwaste” (RCRA and UIC) means a hazardous waste as
defined in 35 Ill. Adm. Code 721.103.
“Hazardous waste management facility” (“HWM facility”) means all
contiguous land and structures, other appurtenances, and improvements
on the land, used for treating, storing, or disposing of “hazardous
waste”. A facility may consist of several “treatment”, “storage”, or
“disposal” operational units (for example, one or more landfills, surface
impoundments, or combinations of them).
“HWM facility” (RCRA) means “Hazardous Waste Management
facility”.
“Injection well” (RCRA and UIC) means a “well” into which “fluids”
are being injected.
“Injection zone” (UIC) means a geological “formation”, group of
formations, or part of a formation receiving fluids through a “well”.
“In operation” (RCRA) means a facility that is treating, storing, or
disposing of “hazardous waste”.
“Interim authorization” (RCRA) means approval by USEPA of the
Illinois Hazardous Waste Management program that has met the
requirements of Section 3006(g)(2) of RCRA and applicable
requirements of 40 CFR 271 (199296). This happened on May 17,
1982.
“Interstate agency” means an agency of two or more states established
by or under an agreement or compact approved by the Congress, or any
other agency of two or more states having substantial powers or duties
pertaining to the control of pollution as determined and approved by the
Administrator under the “appropriate Act and regulations”.
“Major facility” means any RCRA or UIC “facility or activity”
classified as such by the Regional Administrator or the Agency.
“Manifest” (RCRA and UIC) means the shipping document originated
and signed by the “generator” that contains the information required by
35 Ill. Adm. Code 722.Subpart B.
10
“National Pollutant Discharge Elimination System” means the program
for issuing, modifying, revoking and reissuing, terminating, monitoring,
and enforcing permits and imposing and enforcing pretreatment
requirements under Section 12(f) of the Environmental Protection Act
and 35 Ill. Adm. Code 309.Subpart A and 310. The term includes an
“approved program”.
“New HWM facility” (RCRA) means a “Hazardous Waste Management
facility” that began operation or for which construction commenced after
November 19, 1980.
“New injection well” (UIC) means a “well” that began injection after
the UIC program for the State of Illinois applicable to the well is
approved.
“Off-site” (RCRA) means any site that is not “on-site”.
“On-site” (RCRA) means on the same or geographically contiguous
property that may be divided by public or private right(s)-of-way,
provided the entrance and exit between the properties is at a cross-roads
intersection, and access is by crossing as opposed to going along, the
right(s)-of-way. Non-contiguous properties owned by the same person
but connected by a right-of-way that the person controls and to which the
public does not have access, is also considered on-site property.
“Owner or operator” means the owner or operator of any “facility or
activity” subject to regulation under the RCRA or UIC programs.
“Permit” means an authorization, license, or equivalent control
document issued to implement the requirements of this Part and 35 Ill.
Adm. Code 703, 704, and 705.
“Permit” includes RCRA “permit by rule” (35 Ill. Adm. Code
703.141), UIC area permit (35 Ill. Adm. Code 704.162), and RCRA or
UIC “Emergency Permit” (35 Ill. Adm. Code 703.221 and 704.163).
“Permit” does not include RCRA interim status (35 Ill. Adm. Code
703.153 through 703.157), UIC authorization by rule (35 Ill. Adm.
Code 704.Subpart C), or any permit that has not yet been the subject of
final Agency action, such as a “Draft Permit” or a “Proposed Permit”.
“Person” means any individual, partnership, co-partnership, firm,
company, corporation, association, joint stock company, trust, estate,
political subdivision, state agency, or any other legal entity, or their
legal representative, agency, or assigns.
11
“Physical construction” (RCRA) means excavation, movement of earth,
erection of forms or structures or similar activity to prepare an “HWM
facility” to accept “hazardous waste”.
“Plugging” (UIC) means the act or process of stopping the flow of
water, oil, or gas into or out of a formation through a borehole or well
penetrating that formation.
“POTW” means “publicly owned treatment works”.
“Project” (UIC) means a group of wells in a single operation.
“Publicly owned treatment works” (“POTW”) is as defined in 35 Ill.
Adm. Code 310.
“Radioactive waste” (UIC) means any waste that contains radioactive
material in concentrations that exceed those listed in 10 CFR 20,
Appendix B, Table II, Column 2, incorporated by reference in 35 Ill.
Adm. Code 720.111.
“RCRA” means the Solid Waste Disposal Act as amended by the
Resource Conservation and Recovery Act of 1976 (P.L. 94-580, as
amended by P.L. 95-609, P.L. 96-510, 42 U.S.C. 6901 et seq.
(199296)). For the purposes of regulation under 35 Ill. Adm. Code 700
through 705, 720 through 728, and 739, “RCRA” refers only to RCRA
Subtitle C. This does not include the RCRA Subtitle D (municipal solid
waste landfill) regulations, found in 35 Ill. Adm. Code 810 through 815,
and the RCRA Subtitle I (underground storage tank) regulations found in
35 Ill. Adm. Code 731 and 732.
“RCRA permit” means a permit required under Section 21(f) of the
Environmental Protection Act.
“Regional Administrator” means the Regional Administrator for the
USEPA Region in which the facility is located or the Regional
Administrator’s designee.
“Schedule of compliance” means a schedule of remedial measures
included in a “permit”, including an enforceable sequence of interim
requirements (for example, actions, operations, or milestone events)
leading to compliance with the “appropriate Act and regulations”.
“SDWA” means the Safe Drinking Water Act (P.L. 93-523, as
amended, 42 U.S.C. 300f et seq. (199296)).
12
“Site” means the land or water area where any “facility or activity” is
physically located or conducted, including adjacent land used in
connection with the facility or activity.
“SIC Ccode” means codes pursuant to the Standard Industrial
Classification Manual incorporated by reference in 35 Ill. Adm. Code
720.111.
“State” means the State of Illinois.
“State Director” means the Director of the Illinois Environmental
Protection Agency.
“State/EPA Aagreement” means an agreement between the Regional
Administrator and the State that coordinates USEPA and State activities,
responsibilities, and programs including those under the RCRA and
SDWA.
“Storage” (RCRA) means the holding of “hazardous waste” for a
temporary period, at the end of which the hazardous waste is treated,
disposed, or stored elsewhere.
“Stratum (plural strata)” (UIC) means a single sedimentary bed or layer,
regardless of thickness, that consists of generally the same kind of rock
material.
“Total dissolved solids” (UIC) means the total dissolved (filterable)
solids as determined by use of the method specified in 40 CFR 136,
incorporated by reference in 35 Ill. Adm. Code 720.111.
“Transfer facility” means any transportation related facility including
loading docks, parking areas, storage areas, and other similar areas
where shipments of hazardous wastes are held during the normal course
of transportation.
“Transferee” (UIC) means the owner or operator receiving ownership or
operational control of the well.
“Transferor” (UIC) means the owner or operator transferring ownership
or operational control of the well.
“Transporter” (RCRA) means a person engaged in the off-site
transportation of “hazardous waste” by air, rail, highway, or water.
13
“Treatment” (RCRA) means any method, technique, process, including
neutralization, designed to change the physical, chemical, or biological
character or composition of any “hazardous waste” so as to neutralize
such wastes, or so as to recover energy or material resources from the
waste, or so as to render such wastes non-hazardous, or less hazardous;
safer to transport, store, or dispose of; or amenable for recovery,
amenable for storage, or reduced in volume.
“UIC” means the Underground Injection Control program.
“Underground Iinjection” (UIC) means a “well injection”.
“Underground source of drinking water” (“USDW”) (RCRA and UIC)
means an “aquifer” or its portion:
Which:
Supplies any public water system; or
Contains a sufficient quantity of groundwater to supply a
public water system; and
Currently supplies drinking water for human
consumption; or
Contains less than 10,000 mg/1 total dissolved solids; and
That is not an “exempted aquifer”.
“USDW” (RCRA and UIC) means an “underground source of drinking
water”.
“Wastewater treatment unit” means a device which:
Is part of a wastewater treatment facility that is subject to
regulation under 35 Ill. Adm. Code 309.Subpart A or 310; and
Receives and treats or stores an influent wastewater that is a
hazardous waste as defined in 35 Ill. Adm. Code 721.103, or
generates and accumulates a wastewater treatment sludge that is a
hazardous waste as defined in 35 Ill. Adm. Code 721.103, or
treats or stores a wastewater treatment sludge that is a hazardous
waste as defined in 35 Ill. Adm. Code 721.103; and
14
Meets the definition of tank or tank system in 35 Ill. Adm. Code
720.110.
“Well” (UIC) means a bored, drilled, or driven shaft, or a dug hole,
whose depth is greater than the largest surface dimension.
“Well injection” (UIC) means the subsurface emplacement of “fluids”
through a bored, drilled, or driven “well”; or through a dug well, where
the depth of the dug well is greater than the largest surface dimension.
BOARD NOTE: Derived from 40 CFR 144.3 (199496) and 270.2
(199496), as amended at 60 Fed. Reg. 33914 (June 29, 1995).
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE G: WASTE DISPOSAL
CHAPTER I: POLLUTION CONTROL BOARD
SUBCHAPTER b: PERMITS
PART 703
RCRA PERMIT PROGRAM
SUBPART A: GENERAL PROVISIONS
Section
703.100
Scope and Relation to Other Parts
703.101
Purpose
703.110
References
SUBPART B: PROHIBITIONS
Section
703.120
Prohibitions in General
703.121
RCRA Permits
703.122
Specific Inclusions in Permit Program
703.123
Specific Exclusions from Permit Program
703.124
Discharges of Hazardous Waste
703.125
Reapplications
703.126
Initial Applications
703.127
Federal Permits (Repealed)
SUBPART C: AUTHORIZATION BY RULE AND INTERIM
STATUS
Section
703.140
Purpose and Scope
15
703.141
Permits by Rule
703.150
Application by Existing HWM Facilities and Interim Status
Qualifications
703.151
Application by New HWM Facilities
703.152
Amended Part A Application
703.153
Qualifying for Interim Status
703.154
Prohibitions During Interim Status
703.155
Changes During Interim Status
703.156
Interim Status Standards
703.157
Grounds for Termination of Interim Status
703.158
Permits for Less Than an Entire Facility
703.159
Closure by Removal
703.160
Procedures for Closure Determination
SUBPART D: APPLICATIONS
Section
703.180
Applications in General
703.181
Contents of Part A
703.182
Contents of Part B
703.183
General Information
703.184
Facility Location Information
703.185
Groundwater Protection Information
703.186
Exposure Information
703.187
Solid Waste Management Units
703.188
Other Information
703.191
Public Participation: Pre-Application Public Notice and Meeting
703.192
Public Participation: Public Notice of Application
703.193
Public Participation: Information Repository
703.200
Specific Part B Application Information
703.201
Containers
703.202
Tank Systems
703.203
Surface Impoundments
703.204
Waste Piles
703.205
Incinerators that Burn Hazardous Waste
703.206
Land Treatment
703.207
Landfills
703.208
Boilers and Industrial Furnaces Burning Hazardous Waste
703.209
Miscellaneous Units
703.210
Process Vents
703.211
Equipment
703.212
Drip Pads
703.213
Air Emission Controls for Tanks, Surface Impoundments, and
Containers
SUBPART E: SHORT TERM AND PHASED PERMITS
16
Section
703.221
Emergency Permits
703.222
Incinerator Conditions Prior to Trial Burn
703.223
Incinerator Conditions During Trial Burn
703.224
Incinerator Conditions After Trial Burn
703.225
Trial Burns for Existing Incinerators
703.230
Land Treatment Demonstration
703.231
Research, Development and Demonstration Permits
703.232
Permits for Boilers and Industrial Furnaces Burning Hazardous Waste
SUBPART F: PERMIT CONDITIONS OR DENIAL
Section
703.240
Permit Denial
703.241
Establishing Permit Conditions
703.242
Noncompliance Pursuant to Emergency Permit
703.243
Monitoring
703.244
Notice of Planned Changes (Repealed)
703.245
Twenty-four Hour Reporting
703.246
Reporting Requirements
703.247
Anticipated Noncompliance
703.248
Information Repository
SUBPART G: CHANGES TO PERMITS
Section
703.260
Transfer
703.270
Modification
703.271
Causes for Modification
703.272
Causes for Modification or Reissuance
703.273
Facility Siting
703.280
Permit Modification at the Request of the Permittee
703.281
Class 1 Modifications
703.282
Class 2 Modifications
703.283
Class 3 Modifications
703.Appendix A
Classification of Permit Modifications
AUTHORITY: Implementing Section 22.4 and authorized by Section 27 of the
Environmental Protection Act [415 ILCS 5/22.4 and 27].
SOURCE: Adopted in R82-19, 53 PCB 131, at 7 Ill. Reg. 14289, effective October
12, 1983; amended in R83-24 at 8 Ill. Reg. 206, effective December 27, 1983;
amended in R84-9 at 9 Ill. Reg. 11899, effective July 24, 1985; amended in R85-22 at
10 Ill. Reg. 1110, effective January 2, 1986; amended in R85-23 at 10 Ill. Reg. 13284,
effective July 28, 1986; amended in R86-1 at 10 Ill. Reg. 14093, effective August 12,
1986; amended in R86-19 at 10 Ill. Reg. 20702, effective December 2, 1986; amended
17
in R86-28 at 11 Ill. Reg. 6121, effective March 24, 1987; amended in R86-46 at 11 Ill.
Reg. 13543, effective August 4, 1987; amended in R87-5 at 11 Ill. Reg. 19383,
effective November 12, 1987; amended in R87-26 at 12 Ill. Reg. 2584, effective
January 15, 1988; amended in R87-39 at 12 Ill. Reg. 13069, effective July 29, 1988;
amended in R88-16 at 13 Ill. Reg. 447, effective December 27, 1988; amended in
R89-1 at 13 Ill. Reg. 18477, effective November 13, 1989; amended in R89-9 at 14
Ill. Reg. 6278, effective April 16, 1990; amended in R90-2 at 14 Ill. Reg. 14492,
effective August 22, 1990; amended in R90-11 at 15 Ill. Reg. 9616, effective June 17,
1991; amended in R91-1 at 15 Ill. Reg. 14554, effective September 30, 1991; amended
in R91-13 at 16 Ill Reg. 9767, effective June 9, 1992; amended in R92-10 at 17 Ill.
Reg. 5774, effective March 26, 1993; amended in R93-4 at 17 Ill. Reg. 20794,
effective November 22, 1993; amended in R93-16 at 18 Ill. Reg. 6898, effective April
26, 1994; amended in R94-7 at 18 Ill. Reg. 12392, effective July 29, 1994; amended
in R94-5 at 18 Ill. Reg. 18316, effective December 20, 1994; amended in R95-6 at 19
Ill. Reg. 9920, effective June 27, 1995; amended in R95-20 at 20 Ill. Reg. 11225,
effective August 1, 1996; amended in R96-10/R97-3/R97-5 at 21 Ill. Reg. ________,
effective ____________________.
SUBPART D: APPLICATIONS
Section 703.183
General Information
The following information is required in the Part B application for all HWM facilities,
except as 35 Ill. Adm. Code 724.101 provides otherwise:
a)
A general description of the facility;
b)
Chemical and physical analyses of the hazardous wastes and hazardous
debris to be handled at the facility. At a minimum, these analyses must
contain all the information which must be known to treat, store or
dispose of the wastes properly in accordance with 35 Ill. Adm. Code
724;
c)
A copy of the waste analysis plan required by 35 Ill. Adm. Code
724.113(b) and, if applicable, 35 Ill. Adm. Code 724.113(c);
d)
A description of the security procedures and equipment required by 35
Ill. Adm. Code 724.114, or a justification demonstrating the reasons for
requesting a waiver of this requirement;
e)
A copy of the general inspection schedule required by 35 Ill. Adm. Code
724.115(b). Include where applicable, as part of the inspection
schedule, specific requirements in 35 Ill. Adm. Code 724.274,
724.293(i), 724.295, 724.326, 724.354, 724.373, 724.403, 724.702,
18
724.933, 724.952, 724.953, 724.958, 724.984, 724.985, 724.986, and
724.988, and 724.991;
f)
A justification of any request for a waiver of the preparedness and
prevention requirements of 35 Ill. Adm. Code 724.Subpart C;
g)
A copy of the contingency plan required by 35 Ill. Adm. Code
724.Subpart D;
BOARD NOTE: Include, where applicable, as part of the contingency
plan, specific requirements in 35 Ill. Adm. Code 724.327 and 724.355.
35 Ill. Adm. Code 724.355 has not yet been adopted.
h)
A description of procedures, structures, or equipment used at the facility
to:
1)
Prevent hazards in unloading operations (for example, ramps, or
special forklifts);
2)
Prevent runoff from hazardous waste handling areas to other
areas of the facility or environment, or to prevent flooding (for
example, berms, dikes, or trenches);
3)
Prevent contamination of water supplies;
4)
Mitigate effects of equipment failure and power outages;
5)
Prevent undue exposure of personnel to hazardous waste (for
example, protective clothing); and
6)
Prevent releases to the atmosphere.
i)
A description of precautions to prevent accidental ignition or reaction of
ignitable, reactive, or incompatible wastes, as required to demonstrate
compliance with 35 Ill. Adm. Code 724.117, including documentation
demonstrating compliance with 35 Ill. Adm. Code 724.117(c);
j)
Traffic pattern, estimated volume (number and types of vehicles), and
control (for example, show turns across traffic lanes and stacking lanes,
if appropriate); describe access road surfacing and load bearing capacity;
and show traffic control signals;
k)
Facility location information, as required by Section 703.184;
19
l)
An outline of both the introductory and continuing training programs by
the owner or operator to prepare persons to operate or maintain the
HWM facility in a safe manner, as required to demonstrate compliance
with 35 Ill. Adm. Code 724.116. A brief description of how training
will be designed to meet actual job tasks in accordance with
requirements in 35 Ill. Adm. Code 724.116(a)(3);
m)
A copy of the closure plan and, where applicable, the post-closure plan
required by 35 Ill. Adm. Code 724.212, 724.218, and 724.297. Include
where applicable, as part of the plans, specific requirements in 35 Ill.
Adm. Code 724.278, 724.297, 724.328, 724.358, 724.380, 724.410,
724.451, 724.701, and 724.703;
n)
For hazardous waste disposal units that have been closed, documentation
that notices required under 35 Ill. Adm Adm. Code 724.219 have been
filed;
o)
The most recent closure cost estimate for the facility, prepared in
accordance with 35 Ill. Adm. Code 724.242, and a copy of the
documentation required to demonstrate financial assurance under 35 Ill.
Adm. Code 724.243. For a new facility, a copy of the required
documentation may be submitted 60 days prior to the initial receipt of
hazardous wastes, if it is later than the submission of the Part B permit
application;
p)
Where applicable, the most recent post-closure cost estimate for the
facility, prepared in accordance with 35 Ill. Adm. Code 724.244, plus a
copy of the documentation required to demonstrate financial assurance
under 35 Ill. Adm. Code 724.245. For a new facility, a copy of the
required documentation may be submitted 60 days prior to the initial
receipt of hazardous wastes, if it is later than the submission of the Part
B permit application;
q)
Where applicable, a copy of the insurance policy or other documentation
which comprises compliance with the requirements of 35 Ill. Adm. Code
724.247. For a new facility, documentation showing the amount of
insurance meeting the specification of 35 Ill. Adm. Code 724.247(a)
and, if applicable, 35 Ill. Adm. Code 724.247(b) that the owner or
operator plans to have in effect before initial receipt of hazardous waste
for treatment, storage, or disposal. A request for an alternative level of
required coverage for a new or existing facility may be submitted as
specified in 35 Ill. Adm. Code 724.247(c);
r)
A topographic map showing a distance of 1000 feet around the facility at
a scale of 2.5 centimeters (1 inch) equal to not more than 61.0 meters
20
(200 feet). Contours must be shown on the map. The contour interval
must be sufficient to clearly show the pattern of surface water flow in
the vicinity of and from each operational unit of the facility. For
example, contours with an interval of 1.5 meters (5 feet), if relief is
greater than 6.1 meters (20 feet), or an interval of 0.6 meters (2 feet), if
relief is less than 6.1 meters (20 feet). Owners and operators of HWM
facilities located in mountainous areas shall use larger contour intervals
to adequately show topographic profiles of facilities. The map must
clearly show the following:
1)
Map scale and date;
2)
100-year floodplain area;
3)
Surface waters including intermittent streams;
4)
Surrounding land uses (e.g., residential, commercial,
agricultural, recreational, etc.);
5)
A wind rose (i.e., prevailing windspeed and direction);
6)
Orientation of the map (north arrow);
7)
Legal boundaries of the HWM facility site;
8)
Access control (e.g., fences, gates, etc.);
9)
Injection and withdrawal wells both on-site and off-site;
10)
Buildings; treatment, storage, or disposal operations; or other
structures (e.g., recreation areas, runoff control systems, access
and internal roads, storm, sanitary and process sewage systems,
loading and unloading areas, fire control facilities, etc.);
11)
Barriers for drainage or flood control;
12)
Location of operational units within the HWM facility site, where
hazardous waste is (or will be) treated, stored, or disposed
(include equipment cleanup areas);
BOARD NOTE: For large HWM facilities, the Agency shall
allow the use of other scales on a case by case basis.
21
s)
Applicants shall submit such information as the Agency determines is
necessary for it to determine whether to issue a permit and what
conditions to impose in any permit issued; and
t)
For land disposal facilities, if a case-by-case extension has been
approved under 35 Ill. Adm. Code 728.105 or if a petition has been
approved under 35 Ill. Adm. Code 728.106, a copy of the notice of
approval of the extension or of approval of the petition is required.;
u)
A summary of the pre-application meeting, along with a list of attendees
and their addresses, and copies of any written comments or materials
submitted at the meeting, as required under 35 Ill. Adm. Code
703.191(c).
BOARD NOTE: Derived from 40 CFR 270.14(b) (19946), as amended
at 5961 Fed. Reg. 6295259996 (Dec. 6, 1994Nov. 25, 1996).
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 703.191 Public Participation: Pre-Application Public Notice and Meeting
a)
Applicability. The requirements of this Section shall apply to any
RCRA Part B application seeking an initial permit for a hazardous waste
management unit. The requirements of this Section shall also apply to
any RCRA Part B application seeking renewal of a permit for such a
unit, where the renewal application is proposing a significant change in
facility operations. For the purposes of this Section, a “significant
change” is any change that would qualify as a class 3 permit
modification under Sections 703.283 and 703.Appendix A. The
requirements of this Section do not apply to permit modifications under
Sections 703.280 through 703.283 or to applications that are submitted
for the sole purpose of conducting post-closure activities or post-closure
activities and corrective action at a facility.
b)
Prior to the submission of a RCRA Part B permit application for a
facility, the applicant must hold at least one meeting with the public in
order to solicit questions from the community and inform the community
of its proposed hazardous waste management activities. The applicant
shall post a sign-in sheet or otherwise provide a voluntary opportunity
for attendees to provide their names and addresses.
c)
The applicant shall submit to the Agency, as part of its RCRA Part B
permit application, a summary of the meeting, along with the list of
attendees and their addresses developed under subsection (b) of this
22
Section and copies of any written comments or materials submitted at the
meeting, in accordance with Section 703.183.
d)
The applicant must provide public notice of the pre-application meeting
at least 30 days prior to the meeting. The applicant must maintain
documentation of the notice and provide that documentation to the
permitting agency upon request.
1)
The applicant shall provide public notice in each of the following
forms:
A)
A newspaper advertisement. The applicant shall publish a
notice in a newspaper of general circulation in the county
that hosts the proposed location of the facility. The notice
must fulfill the requirements set forth in subsection (d)(2)
of this Section. In addition, the Agency shall instruct the
applicant to publish the notice in newspapers of general
circulation in adjacent counties, where the Agency
determines that such publication is necessary to inform the
affected public. The notice must be published as a display
advertisement.
B)
A visible and accessible sign. The applicant shall post a
notice on a clearly marked sign at or near the facility.
The notice must fulfill the requirements set forth in
subsection (d)(2) of this Section. If the applicant places
the sign on the facility property, then the sign must be
large enough to be readable from the nearest point where
the public would pass by the site.
C)
A broadcast media announcement. The applicant shall
broadcast a notice at least once on at least one local radio
station or television station. The notice must fulfill the
requirements set forth in subsection (d)(2) of this Section.
The applicant may employ another medium with prior
approval of the Agency.
D)
A notice to the Agency. The applicant shall send a copy
of the newspaper notice to the permitting agency and to
the appropriate units of State and local government, in
accordance with 35 Ill. Adm. Code 705.163(a).
2)
The notices required under subsection (d)(1) of this Section must
include:
23
A)
The date, time, and location of the meeting;
B)
A brief description of the purpose of the meeting;
C)
A brief description of the facility and proposed
operations, including the address or a map (e.g., a
sketched or copied street map) of the facility location;
D)
A statement encouraging people to contact the facility at
least 72 hours before the meeting if they need special
access to participate in the meeting; and
E)
The name, address, and telephone number of a contact
person for the applicant.
BOARD NOTE: Derived from 40 CFR 124.31 (1996).
Source: Added at 21 Ill. Reg. ________, effective ____________________)
Section 703.192 Public Participation: Public Notice of Application
a)
Applicability. The requirements of this Section shall apply to any
RCRA Part B application seeking an initial permit for a hazardous waste
management unit. The requirements of this Section shall also apply to
any RCRA Part B application seeking renewal of a permit for such a unit
under 35 Ill. Adm. Code 702.125. The requirements of this Section do
not apply to permit modifications under Sections 703.280 through
703.283 or a permit application submitted for the sole purpose of
conducting post-closure activities or post-closure activities and corrective
action at a facility.
b)
Notification at application submittal.
1)
The Agency shall provide public notice as set forth in 35 Ill.
Adm. Code 705.161, and notice to appropriate units of State and
local government as set forth in 35 Ill. Adm. Code
705.163(a)(5), that a Part B permit application has been
submitted to the Agency and is available for review.
2)
The notice shall be published within 30 calendar days after the
application is received by the Agency. The notice must include:
A)
The name and telephone number of the applicant’s contact
person;
24
B)
The name and telephone number of the appropriate
Agency regional office, as directed by the Agency, and a
mailing address to which information, opinions, and
inquiries may be directed throughout the permit review
process;
C)
An address to which people can write in order to be put
on the facility mailing list;
D)
The location where copies of the permit application and
any supporting documents can be viewed and copied;
E)
A brief description of the facility and proposed
operations, including the address or a map (e.g., a
sketched or copied street map) of the facility location on
the front page of the notice; and
F)
The date that the application was submitted.
c)
Concurrent with the notice required under subsection (b) of this Section,
the Agency shall place the permit application and any supporting
documents in a location accessible to the public in the vicinity of the
facility or at the Agency regional office appropriate for the facility.
BOARD NOTE: Derived from 40 CFR 124.32 (1996).
Source: Added at 21 Ill. Reg. ________, effective ____________________)
Section 703.193 Public Participation: Information Repository
a)
Applicability. The requirements of this Section shall apply to any
application seeking a RCRA permit for a hazardous waste management
unit.
b)
The Agency shall assess the need for an information repository on a
case-by-case basis. When assessing the need for an information
repository, the Agency shall consider a variety of factors, including the
following: the level of public interest; the type of facility; the presence
of an existing repository; and the proximity to the nearest copy of the
administrative record. If the Agency determines, at any time after
submittal of a permit application, that there is a need for a repository,
then the Agency shall notify the facility that it must establish and
maintain an information repository. (See Section 703.248 for similar
provisions relating to the information repository during the life of a
permit.)
25
c)
The information repository must contain all documents, reports, data,
and information deemed necessary by the Agency to fulfill the purposes
for which the repository is established. The Agency will have the
discretion to limit the contents of the repository.
d)
The information repository must be located and maintained at a site
chosen by the facility. If the Agency determines that the chosen site is
unsuitable for the purposes and persons for which it was established, due
to problems with the location, hours of availability, access, or other
relevant considerations, then the Agency shall specify a more appropriate
site.
e)
The Agency shall specify requirements for the applicant for informing
the public about the information repository. At a minimum, the Agency
shall require the facility to provide a written notice about the information
repository to all individuals on the facility mailing list.
f)
The facility owner or operator shall be responsible for maintaining and
updating the repository with appropriate information throughout a time
period specified by the Agency. The Agency may close the repository if
it determines that the repository is no longer needed based on its
consideration of the factors in subsection (b) of this Section.
BOARD NOTE: Derived from 40 CFR 124.33 (1996).
Source: Added at 21 Ill. Reg. ________, effective ____________________)
Section 703.213
Air Emission Controls for Tanks, Surface Impoundments, and
Containers
Except as otherwise provided in 35 Ill. Adm. Code 724.101, owners and operators of
tanks, surface impoundments, or containers that use air emission controls in accordance
with the requirements of 35 Ill. Adm. Code 724.Subpart CC shall provide the
following additional information:
a)
Documentation for each floating roof cover installed on a tank subject to
35 Ill. Adm. Code 724.984(b)(2) or 724.984(b)(3)(d)(1) or (d)(2) that
includes information prepared by the owner or operator or provided by
the cover manufacturer or vendor describing the cover design, and
certification by the owner or operator that the cover meets the applicable
design specifications, as listed in 35 Ill. Adm. Code 725.991(c)(e)(1) or
(f)(1).
26
b)
Identification of each container area subject to the requirements of 35 Ill.
Adm. Code 724.Subpart CC and certification by the owner or operator
that the requirements of this Subpart are met.
c)
Documentation for each enclosure used to control air pollutant emissions
from containers in accordance with the requirements of 35 Ill. Adm.
Code 724.984(d)(5) or 724.986(b)(2)(A)(e)(1)(ii) that includes
information prepared by the owner or operator or provided by the
manufacturer or vendor describing the enclosure design, and certification
by the owner or operator that the enclosure meets the specifications
listed in 35 Ill. Adm. Code 725.987(b)(2)(B)records for the most recent
set of calculations and measurements performed by the owner or
operator to verify that the enclosure meets the criteria of a permanent
total enclosure, as specified in “Procedure T--Criteria for and
Verification of a Permanent or Temporary Total Enclosure” under 40
CFR 52.741, appendix B, incorporated by reference in 35 Ill. Adm.
Code 720.111.
d)
Documentation for each floating membrane cover installed on a surface
impoundment in accordance with the requirements of 35 Ill. Adm. Code
724.985(c) that includes information prepared by the owner or operator
or provided by the cover manufacturer or vendor describing the cover
design, and certification by the owner or operator that the cover meets
the specifications listed in 35 Ill. Adm. Code 725.986(e)264.985(c)(1).
e)
Documentation for each closed-vent system and control device installed
in accordance with the requirements of 35 Ill. Adm. Code 724.987 that
includes design and performance information, as specified in Section
703.124(c) and (d).
f)
An emission monitoring plan for both Method 21 in 40 CFR 60,
appendix A, incorporated by reference in 35 Ill. Adm. Code 720.111,
and control device monitoring methods. This plan must include the
following information: monitoring points, monitoring methods for
control devices, monitoring frequency, procedures for documenting
exceedances, and procedures for mitigating noncompliances.
g)
When an owner or operator of a facility subject to 35 Ill. Adm. Code
725.Subpart CC cannot comply with 35 Ill. Adm. Code 724.Subpart CC
by the date of permit issuance, the schedule of implementation required
under 35 Ill. Adm. Code 725.982.
BOARD NOTE: Derived from 40 CFR 270.27(a), added at 59 Fed.
Reg. 62952 (Dec. 6, 1994) (1996), as amended at 61 Fed. Reg. 59996
(Nov. 25, 1996).
27
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
SUBPART E: SHORT TERM AND PHASED PERMITS
Section 703.221
Emergency Permits
a)
Notwithstanding any other provision of this Part or 35 Ill. Adm. Code
702 or 705, in the event that the Agency finds an imminent and
substantial endangerment to human health or the environment the
Agency may issue a temporary emergency permit:
1)
To a non-permitted facility to allow treatment, storage or disposal
of hazardous waste; or
2)
To a permitted facility to allow treatment, storage or disposal of a
hazardous waste not covered by an effective permit.
b)
This emergency permit:
1)
May be oral or written. If oral, it shallmust be followed in five
days by a written emergency permit;
2)
Shall not exceed 90 days in duration;
3)
Shall clearly specify the hazardous wastes to be received and the
manner and location of their treatment, storage or disposal;
4)
May be terminated by the Agency at any time without process if
it determines that termination is appropriate to protect human
health and the environment;
5)
Shall be accompanied by a public notice published under 35 Ill.
Adm. Code 705.162 including:
A)
Name and address of the office granting the emergency
authorization;
B)
Name and location of the permitted HWM facility;
C)
A brief description of the wastes involved;
D)
A brief description of the action authorized and reasons
for authorizing it; and
28
E)
Duration of the emergency permit; and
6)
Shall incorporate, to the extent possible and not inconsistent with
the emergency situation, all applicable requirements of this Part
and 35 Ill. Adm. Code 724.
7)
Emergency permits which would authorize actions not in
compliance with Board rules, other than procedural requirements,
require a variance or provisional variance pursuant to Title IX of
the Environmental Protection Act and 35 Ill. Adm. Code 104.
(Board NoteBOARD NOTE: SeeDerived from 40 CFR 270.61
(1996).)
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 703.223
Incinerator Conditions During Trial Burn
For the purposes of determining feasibility of compliance with the performance
standards of 35 Ill. Adm. Code 724.443 and of determining adequate operating
conditions under 35 Ill. Adm. Code 724.445, the Agency shall establish conditions in
the permit to a new hazardous waste incinerator to be effective during the trial burn.
a)
Applicants shall propose a trial burn plan, prepared under subsection (b)
belowof this Section with Part B of the permit application;
b)
The trial burn plan must include the following information:
1)
An analysis of each waste or mixture of wastes to be burned that
includes:
A)
Heat value of the waste in the form and composition in
which it will be burned;
B)
Viscosity (if applicable), or description of physical form
of the waste;
C)
An identification of any hazardous organic constituents
listed in 35 Ill. Adm. Code 721.Appendix H, that are
present in the waste to be burned, except that the applicant
need not analyze for constituents listed in 35 Ill. Adm.
Code 721.Appendix H that would reasonably not be
expected to be found in the waste. The constituents
excluded from analysis must be identified, and the basis
29
for their exclusion stated. The waste analysis must rely
on analytical techniques specified in “Test Methods for
the Evaluation of Solid Waste, Physical/Chemical
Methods”, U.S. EPA Publication SW-846, as
incorporated by reference at 35 Ill. Adm. Code 720.111
and Section 703.110, or their equivalent;
D)
An approximate quantification of the hazardous
constituents identified in the waste, within the precision
produced by the analytical methods specified in “Test
Methods for the Evaluation of Solid Waste,
Physical/Chemical Methods”, U.S. EPA Publication SW-
846, as incorporated by reference at 35 Ill. Adm. Code
720.111 and Section 703.110, or their equivalent;
2)
A detailed engineering description of the incinerator for which
the permit is sought including:
A)
Manufacturer’s name and model number of incinerator (if
available);
B)
Type of incinerator;
C)
Linear dimensions of the incinerator unit including the
cross sectional area of combustion chamber;
D)
Description of the auxiliary fuel system (type/feed);
E)
Capacity of prime mover;
F)
Description of automatic waste feed cut-off system(s);
G)
Stack gas monitoring and pollution control equipment;
H)
Nozzle and burner design;
I)
Construction materials;
J)
Location and description of temperature, pressure and
flow indicating and control devices;
3)
A detailed description of sampling and monitoring procedures,
including sampling and monitoring locations in the system, the
equipment to be used, sampling and monitoring frequency and
planned analytical procedures for sample analysis;
30
4)
A detailed test schedule for each waste for which the trial burn is
planned including date(s), duration, quantity of waste to be
burned and other factors relevant to the Agency’s decision under
subsection (e) belowof this Section;
5)
A detailed test protocol, including, for each waste identified, the
ranges of temperature, waste feed rate, combustion gas velocity,
use of auxiliary fuel and any other relevant parameters that will
be varied to affect the destruction and removal efficiency of the
incinerator;
6)
A description of, and planned operating conditions for, any
emission control equipment that will be used;
7)
Procedures for rapidly stopping waste feed, shutting down the
incinerator and controlling emissions in the event of an
equipment malfunction;
8)
Such other information as the Agency reasonably finds necessary
to determine whether to approve the trial burn plan in light of the
purposes of this subsection (b) and the criteria in subsection (e)
belowof this Section. Such information must be requested by the
Agency pursuant to 35 Ill. Adm. Code 705.123.
c)
The Agency, in reviewing the trial burn plan, shall evaluate the
sufficiency of the information provided and shall require the applicant,
pursuant to 35 Ill. Adm. Code 705.123, to supplement this information,
if necessary, to achieve the purposes of this subsectionSection;
d)
Based on the waste analysis data in the trial burn plan, the Agency shall
specify as trial Principal Organic Hazardous Constituents (POHCs),
those constituents for which destruction and removal efficiencies must be
calculated during the trial burn. These trial POHCs must be specified by
the Agency based on its estimate of the difficulty of incineration of the
constituents identified in the waste analysis, their concentration or mass
in the waste feed, and, for wastes listed in 35 Ill. Adm. Code
721.Subpart D, the hazardous waste organic constituent of constituents
identified in 35 Ill. Adm. Code 721.Appendix G or H as the basis for
listing;
e)
The Agency shall approve a trial burn plan if it finds that:
31
1)
The trial burn is likely to determine whether the incinerator
performance standard required by 35 Ill. Adm. Code 724.443 can
be met;
2)
The trial burn itself will not present an imminent hazard to
human health or the environment;
3)
The trial burn will help the Agency to determine operating
requirements to be specified under 35 Ill. Adm. Code 724.445;
and
4)
The information sought in subsections (e)(1) and (e)(3) aboveof
this Section cannot reasonably be developed through other means;
f)
The Agency shall send a notice to all persons on the facility mailing list,
as set forth in 35 Ill. Adm. Code 705.161(a), and to the appropriate
units of State and local government, as set forth in 35 Ill. Adm. Code
705.163(a)(5), announcing the scheduled commencement and completion
dates for the trial burn. The applicant may not commence the trial burn
until after the Agency has issued such notice.
1)
This notice must be mailed within a reasonable time period
before the scheduled trial burn. An additional notice is not
required if the trial burn is delayed due to circumstances beyond
the control of the facility or the Agency.
2)
This notice must contain:
A)
The name and telephone number of the applicant’s contact
person;
B)
The name and telephone number of the Agency regional
office appropriate for the facility;
C)
The location where the approved trial burn plan and any
supporting documents can be reviewed and copied; and
D)
An expected time period for commencement and
completion of the trial burn;
fg)
During each approved trial burn (or as soon after the burn as is
practicable), the applicant shall make the following determinations:
1)
A quantitative analysis of the trial POHCs, in the waste feed to
the incinerator;
32
2)
A quantitative analysis of the exhaust gas for the concentration
and mass emissions of the trial POHC’s, molecular oxygen and
hydrogen chloride (HCl);
3)
A quantitative analysis of the scrubber water (if any), ash
residues and other residues, for the purpose of estimating the fate
of the trial POHCs;
4)
A computation of destruction and removal efficiency (DRE), in
accordance with the DRE formula specified in 35 Ill. Adm. Code
724.443(a);
5)
If the HCl (hydrogen chloride) emission rate exceeds 1.8
kilograms of HCl per hour (4 pounds per hour), a computation of
HCl removal efficiency in accordance with 35 Ill. Adm. Code
724.443(b);
6)
A computation of particulate emissions, in accordance with 35
Ill. Adm. Code 724.443(c);
7)
An identification of sources of fugitive emissions and their means
of control;
8)
A measurement of average, maximum and minimum
temperatures and combustion gas velocity;
9)
A continuous measurement of carbon monoxide (CO) in the
exhaust gas;
10)
Such other information as the Agency specifies as necessary to
ensure that the trial burn will determine compliance with the
performance standards in 35 Ill. Adm. Code 724.443 and to
establish the operating conditions required by 35 Ill. Adm. Code
724.445 as necessary to meet that performance standard.;
gh)
The applicant shall submit to the Agency a certification that the trial
burn has been carried out in accordance with the approved trial burn
plan, and shall submit the results of all the determinations required in
subsection (f) above(g) of this Section. This submission must be made
within 90 days of completion of the trial burn, or later if approved by
the Agency;
hi)
All data collected during any trial burn must be submitted to the Agency
following the completion of the trial burn;
33
ij)
All submissions required by this subsection Section must be certified on
behalf of the applicant by the signature of a person authorized to sign a
permit application or a report under 35 Ill. Adm. Code 702.126;
jk)
Based on the results of the trial burn, the Agency shall set the operating
requirements in the final permit according to 35 Ill. Adm. Code
724.445. The permit modification must proceed as a minor modification
according to Section 703.280.
BOARD NOTE: Derived from 40 CFR 270.62(ab)(1993), as amended
at 58 Fed. Reg. 46051 (Aug. 31, 1993) (1996).
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 703.225
Trial Burns for Existing Incinerators
For the purpose of determining feasibility of compliance with the performance
standards of 35 Ill. Adm. Code 724.443 and of determining adequate operating
conditions under 35 Ill. Adm. Code 724.445, the applicant for a permit for an existing
hazardous waste incinerator shall prepare and submit a trial burn plan and perform a
trial burn in accordance with Sections 703.205(b) and 703.223(b) through (ie) and (g)
through (j), or, instead, submit other information as specified in Section 703.205(c).
The Agency shall announce its intention to approve the trial burn plan in accordance
with the timing and distribution requirements of Section 703.223(f). The contents of
the notice must include: the name and telephone number of a contact person at the
facility; the name and telephone number of a contact office at the Agency; the location
where the trial burn plan and any supporting documents can be reviewed and copied;
and a schedule of the activities that are required prior to permit issuance, including the
anticipated time schedule for Agency approval of the plan and the time period during
which the trial burn would be conducted. Applicants submitting information under
Section 703.205(a) are exempt from compliance with 35 Ill. Adm. Code 724.443 and
724.445 and, therefore, are exempt from the requirement to conduct a trial burn.
Applicants whothat submit trial burn plans and receive approval before submission of a
permit application shall complete the trial burn and submit the results, specified in
Section 703.223(fg), with Part B of the permit application. If completion of this
process conflicts with the date set for submission of the Part B application, the
applicant shall contact the Agency to establish a later date for submission of the Part B
application or the trial burn results. Trial burn results must be submitted prior to
issuance of the permit. When the applicant submits a trial burn plan with Part B of the
permit application, the Agency shall specify a time period prior to permit issuance in
which the trial burn must be conducted and the results submitted.
BOARD NOTE: Derived from 40 CFR 270.62(d) (198896), as amended at 54 Fed.
Reg. 4288, January 30, 1989.)
34
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 703.232
Permits for Boilers and Industrial Furnaces Burning Hazardous
Waste
a)
General. Owners and operators of new boilers and industrial furnaces
(those not operating under the interim status standards of 35 Ill. Adm.
Code 726.203) are subject to subsection (b) through (f) belowof this
Section. Boilers and industrial furnaces operating under the interim
status standards of 35 Ill. Adm. Code 726.203 are subject to subsection
(g) belowof this Section.
b)
Permit operating periods for new boilers and industrial furnaces. A
permit for a new boiler or industrial furnace must specify appropriate
conditions for the following operating periods:
1)
Pretrial burn period. For the period beginning with initial
introduction of hazardous waste and ending with initiation of the
trial burn, and only for the minimum time required to bring the
boiler or industrial furnace to a point of operation readiness to
conduct a trial burn, not to exceed 720 hours operating time
when burning hazardous waste, the Agency shall establish in the
Pretrial Burn Period of the permit conditions, including but not
limited to allowable hazardous waste feed rates and operating
conditions. The Agency shall extend the duration of this
operational period once, for up to 720 additional hours, at the
request of the applicant when good cause is shown. The permit
most be modified to reflect the extension according to Section
703.280 et seq.
A)
Applicants must submit a statement, with part Part B of
the permit application, that suggests the conditions
necessary to operate in compliance with the standards of
35 Ill. Adm. Code 726.204 through 726.207 during this
period. This statement should include, at a minimum,
restrictions on the applicable operating requirements
identified in 35 Ill. Adm. Code 726.202 (e).
B)
The Agency shall review this statement and any other
relevant information submitted with part Part B of the
permit application and specify requirements for this period
sufficient to meet the performance standards of 35 Ill.
35
Adm. Code 726.204 through 726.207 based on the
Agency’s engineering judgment.
2)
Trial burn period. For the duration of the trial burn, the Agency
shall establish conditions in the permit for the purposes of
determining feasibility of compliance with the performance
standards of 35 Ill. Adm. Code 726.204 through 726.207 and
determining adequate operating conditions under 35 Ill. Adm.
Code 726.202(e). Applicants shall propose a trial burn plan,
prepared under subsection (c) belowof this Section, to be
submitted with part Part B of the permit application.
3)
Post-trial burn period.
A)
For the period immediately following completion of the
trial burn, and only for the minimum period sufficient to
allow sample analysis, data computation and submission
of the trial burn results by the applicant, and review of the
trial burn results and modification of the facility permit by
the Agency to reflect the trial burn results, the Agency
shall establish the operating requirements most likely to
ensure compliance with the performance standards of 35
Ill. Adm. Code 726.204 through 726.207 based on the
Agency’s engineering judgment.
B)
Applicants shall submit a statement, with part Part B of
the application, that identifies the conditions necessary to
operate during this period in compliance with the
performance standards of 35 Ill. Adm. Code 726.204
through 726.207. This statement should include, at a
minimum, restrictions on the operating requirements
provided by 35 Ill. Adm. Code 726.202 (e).
C)
The Agency shall review this statement and any other
relevant information submitted with part Part B of the
permit application and specify requirements of this period
sufficient to meet the performance standards of 35 Ill.
Adm. Code 726.204 through 726.207 based on the
Agency’s engineering judgment.
4)
Final permit period. For the final period of operation the Agency
shall develop operating requirements in conformance with 35 Ill.
Adm. Code 726.202(e) that reflect conditions in the trial burn
plan and are likely to ensure compliance with the performance
standards of 35 Ill. Adm. Code 726.204 through 726.207. Based
36
on the trial burn results, the Agency shall make any necessary
modifications to the operating requirements to ensure compliance
with the performance standards. The permit modification must
proceed according to Section 703.280 et seq.
c)
Requirements for trial burn plans. The trial burn plan must include the
following information. The Agency, in reviewing the trial burn plan,
shall evaluate the sufficiency of the information provided and may
require the applicant to supplement this information, if necessary, to
achieve the purposes of this subsection.
1)
An analysis of each feed stream, including hazardous waste,
other fuels, and industrial furnace feed stocks, as fired, that
includes:
A)
Heating value, levels of antimony, arsenic, barium,
beryllium, cadmium, chromium, lead, mercury, silver,
thallium, total chlorine/chloride, and ash; and
B)
Viscosity or description of the physical form of the feed
stream;.
2)
An analysis of each hazardous waste, as fired, including:
A)
An identification of any hazardous organic constituents
listed in 35 Ill. Adm. Code 721.Appendix H that are
present in the feed stream, except that the applicant need
not analyze for constituents listed in 721.Appendix H that
would reasonably not be expected to be found in the
hazardous waste. The constituents excluded from analysis
must be identified as the basis for this exclusion
explained. The analysis must be conducted in accordance
with analytical techniques specified in “Test Methods for
the Evaluation of Solid Waste, Physical/Chemical
Methods”, U.S. EPA Publication SW-846, as
incorporated by reference at 35 Ill. Adm. Code 720.111
and Section 703.110, or their equivalent.
B)
An approximate quantification of the hazardous
constituents identified in the hazardous waste, within the
precision produced by the analytical methods specified in
“Test Methods for the Evaluation of Solid Waste,
Physical/Chemical Methods”, U.S. EPA Publication SW-
846, as incorporated by reference at 35 Ill. Adm. Code
720.111 and Section 703.110, or other equivalent.
37
C)
A description of blending procedures, if applicable, prior
to firing the hazardous waste, including a detailed analysis
of the hazardous waste prior to blending, an analysis of
the material with which the hazardous waste prior to
blending, an analysis of the material with which the
hazardous waste is blended, and blending ratios.
3)
A detailed engineering description of the boiler or industrial
furnace, including:
A)
Manufacturer’s name and model number of the boiler or
industrial furnace;
B)
Type of boiler or industrial furnace;
C)
Maximum design capacity in appropriate units;
D)
Description of the Feed feed system for the hazardous
waste, and, as appropriate, other fuels and industrial
furnace feedstocks;
E)
Capacity of hazardous waste feed system;
F)
Description of automatic hazardous waste feed cutoff
system(s); and
G)
Description of any pollution control system; and
H)
Description of stack gas monitoring and any pollution
control monitoring systems.
4)
A detailed description of sampling and monitoring procedures
including sampling and monitoring locations in the system, the
equipment to be used, sampling and monitoring frequency, and
sample analysis.
5)
A detailed test schedule for each hazardous waste for which the
trial burn is planned, including date(s), duration, quantity of
hazardous waste to be burned, and other factors relevant to the
Agency’s decision under subsection (b)(2) aboveof this Section.
6)
A detailed test protocol, including, for each hazardous waste
identified, the ranges of hazardous waste feed rate, and, as
appropriate, the feed rates of other fuels and industrial furnace
38
feedstocks, and any other relevant parameters that may affect the
ability of the boiler or industrial furnace to meet the performance
standards in 35 Ill. Adm. Code 726.204 through 726.207.
7)
A description of and planned operating conditions for any
emission control equipment that will be used.
8)
Procedures for rapidly stopping the hazardous waste feed and
controlling emissions in the event of an equipment malfunction.
9)
Such other information as the Agency finds necessary to
determine whether to approve the trial burn plan in light of the
purposes of this subsection and the criteria in subsection (b)(2)
aboveof this Section.
d)
Trial burn procedures.
1)
A trial burn must be conducted to demonstrate conformance with
the standards of 35 Ill. Adm. Code 726.104 through 726.107.
2)
The Agency shall approve a trial burn plan if the Agency finds
that:
A)
The trial burn is likely to determine whether the boiler or
industrial furnace can meet the performance standards of
35 Ill. Adm. Code 726.104 through 726.107.
B)
The trial burn itself will not present an imminent hazard
to human health and the environment;
C)
The trial burn will help the Agency to determine operating
requirements to be specified under 35 Ill. Adm. Code
726.102(e); and
D)
The information sought in the trial burn cannot reasonably
be developed through other means.
3)
The Agency shall send a notice to all persons on the facility
mailing list, as set forth in 35 Ill. Adm. Code 705.161(a), and to
the appropriate units of State and local government, as set forth
in 35 Ill. Adm. Code 705.163(a)(5), announcing the scheduled
commencement and completion dates for the trial burn. The
applicant may not commence the trial burn until after the Agency
has issued such notice.
39
A)
This notice must be mailed within a reasonable time
period before the trial burn. An additional notice is not
required if the trial burn is delayed due to circumstances
beyond the control of the facility or the Agency.
B)
This notice must contain:
i)
The name and telephone number of applicant’s
contact person;
ii)
The name and telephone number of the Agency
regional office appropriate for the facility;
iii)
The location where the approved trial burn plan
and any supporting documents can be reviewed
and copied; and
iv)
An expected time period for commencement and
completion of the trial burn.
34)
The applicant shall submit to the Agency a certification that the
trial burn has been carried out in accordance with the approved
trial burn plan, and submit the results of all the determinations
required in subsection (c) above of this Section. The Agency
shall, in the trial burn plan, require that the submission be made
within 90 days after completion of the trial burn, or later if the
Agency determines that a later date is acceptable.
45)
All data collected during any trial burn must be submitted to the
Agency following completion of the trial burn.
56)
All submissions required by this subsection must be certified on
behalf of the applicant by the signature of a person authorized to
sign a permit application or a report under 35 Ill. Adm. Code
702.126.
e)
Special procedures for DRE trial burns. When a DRE trial burn is
required under 35 Ill. Adm. Code 726.104, the Agency shall specify
(based on the hazardous waste analysis data and other information in the
trial burn plan) as trial Principal Organic Hazardous Constituents
(POHCs) those compounds for which destruction and removal
efficiencies must be calculated during the trial burn. These trial POHCs
will be specified by the Agency based on information including the
Agency’s estimate of the difficulty of destroying the constituents
identified in the hazardous waste analysis, their concentrations or mass
40
in the hazardous waste feed, and, for hazardous waste containing or
derived from wastes listed in 35 Ill. Adm. Code 721.Subpart D, the
hazardous waste organic constituent(s) identified in 35 Ill. Adm. Code
721.Appendix G as the basis for listing.
f)
Determinations based on trial burn. During each approved trial burn (or
as soon after the burn as is practicable), the applicant shall make the
following determinations:
1)
A quantitative analysis of the levels of antimony, arsenic,
barium, beryllium, cadmium, chromium, lead, mercury,
thallium, silver, and chlorine/chloride, in the feed streams
(hazardous waste, other fuels, and industrial furnace feedstocks);
2)
When a DRE trial burn is required under 35 Ill. Adm. Code
726.204(a):
A)
A quantitative analysis of the trial POHCs in the
hazardous waste feed;
B)
A quantitative analysis of the stack gas for the
concentration and mass emissions of the trial POHCs; and
C)
A computation of (DRE), in accordance with the DRE
formula specified in 35 Ill. Adm. Code 726.204(a).
3)
When a trial burn for chlorinated dioxins and furans is required
under 35 Ill. Adm. Code 726.204(e), a quantitative analysis of
the stack gas for the concentration and mass emission rate of the
2,3,7,8-chlorinated tetra- through octa-congeners of chlorinated
dibenzo-p-dioxins and furans, and a computation showing
conformance with the emission standard.
4)
When a trial burn for PM, metals, or HCl/Chlorine gas is
required under 35 Ill. Adm. Code 726.205, 726.206(c) or (d) or
726.207(b)(2) or (c), a quantitative analysis of the stack gas for
the concentrations and mass emissions of PM, metals, or HCl and
chlorine gas and computations showing conformance with the
applicable emission performance standards;
5)
When a trial burn for DRE, metals, and HCl/Chlorine gas is
required under 35 Ill. Adm. Code 726.204(a), 726.206(c) or (d),
or 726.207(b)(2) or (c), a quantitative analysis of the scrubber
water (if any), ash residues, other residues, and products for the
41
purpose of estimating the fate of the trial POHCs, metals, and
chlorine/chloride;
6)
An identification of sources of fugitive emissions and their means
of control;
7)
A continuous measurement of carbon monoxide (CO), oxygen,
and, where required, hydrocarbons (HC), in the stack gas; and
8)
Such other information as the Agency specifies as necessary to
ensure that the trial burn will determine compliance with the
performance standards 35 Ill. Adm. Code 726.204 through
726.207 and to establish the operating conditions required by 35
Ill. Adm. Code 726.204 through 726.207 and of determining
adequate operating conditions under 35 Ill. Adm. Code 726.203,
and to establish the operating conditions required by 35 Ill. Adm.
Code 726.202(e) as necessary to meet those performance
standards.
g)
Interim status boilers and industrial furnaces. fFor the purpose of
determining feasibility of compliance with the performance standards of
35 Ill. Adm. Code 726.204 through 726.207 and of determining
adequate operating conditions under 35 Ill. Adm. Code 726.203,
applicants owning or operating existing boilers or industrial furnaces
operated under the interim status standards of 35 Ill. Adm. Code
726.203 shall either prepare and submit a trial burn plan and perform a
trial burn in accordance with the requirements of the Section or submit
other information as specified in Section 703.208(a)(6). The Agency
shall announce its intention to approve of the trial burn plan in
accordance with the timing and distribution requirements of subsection
(d)(3) of this Section. The contents of the notice must include: the
name and telephone number of a contact person at the facility; the name
and telephone number of Agency regional office appropriate for the
facility; the location where the trial burn plan and any supporting
documents can be reviewed and copied; and a schedule of the activities
that are required prior to permit issuance, including the anticipated time
schedule for agency approval of the plan and the time periods during
which the trial burn would be conducted. Applicants that submit a trial
burn plan and receive approval before submission of the part Part B
permit application shall complete the trial burn and submit the results
specified in subsection (f) above of this Section with the part Part B
permit application. If completion of this process conflicts with the date
set for submission of the part Part B application, the applicant shall
contact the Agency to establish a later date for submission of the part
Part B application or the trial burn results. If the applicant submits a
42
trial burn plan with part Part B of the permit application, the trial burn
must be conducted and the results submitted within a time period prior to
permit issuance to be specified by the Agency.
BOARD NOTE: Derived from 40 CFR 270.66 (19926), as amended at
58 Fed. Reg. 46051 (Aug. 31, 1993).
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
SUBPART F: PERMIT CONDITIONS OR DENIAL
Section 703.240
Permit Denial
The Agency may, pursuant to the procedures of 35 Ill. Adm. Code 705, deny the
permit application either in its entirety or only as to the active life of a HWM facility
or unit only.
BOARD NOTE: Derived from 40 CFR 270.29 (1996), as adopted at 54 Fed. Reg.
9607, March 7, 1989.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 703.248 Information Repository
The Agency may require the permittee to establish and maintain an information
repository at any time, based on the factors set forth in Section 703.193(b). The
information repository shall be governed by the provisions in Section 703.193(c)
through (f).
BOARD NOTE: Derived from 40 CFR 270.30(m) (1996).
(Source: Added at 21 Ill. Reg. ________, effective ____________________)
SUBPART G: CHANGES TO PERMITS
Section 703.260
Transfer
a)
A permit may be transferred by the permittee to a new owner or operator
only if the permit has been modified or reissued (under subsection (b) or
Section 703.272) to identify the new permittee and incorporate such
other requirements as are necessary under the appropriate Act. The new
owner or operator to whom the permit is transferred shall comply with
all the terms and conditions specified in such permit.
43
b)
Changes in the ownership or operational control of a facility must be
made as a Class 1 modification with the prior written approval of the
Agency in accordance with Section 703.281. The new owner or
operator shall submit a revised permit application no later than 90 days
prior to the scheduled change. A written agreement containing a specific
date for transfer of permit responsibility between the current and new
permittees must also be submitted to the Agency. When a transfer of
ownership or operational control occurs, the old owner or operator shall
comply with the requirements of 35 Ill. Adm. Code 724.Subpart H
(Financial Requirements), until the new owner or operator has
demonstrated compliance with that Subpart. The new owner or operator
shall demonstrate compliance with that Subpart within six months after
the date of change of operational control of the facility. Upon
demonstration to the Agency by the new owner or operator of
compliance with that Subpart, the Agency shall notify the old owner or
operator that the old owner or operator no longer needs to comply with
that Subpart as of the date of demonstration.
BOARD NOTE: Derived from 40 CFR 270.40, as amended at 53 Fed.
Reg. 37934, September 28, 1988. (1996).
BOARD NOTE: The new operator may be required to employ a chief
operator whothat is certified pursuant to 35 Ill. Adm. Code 745.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE G: WASTE DISPOSAL
CHAPTER I: POLLUTION CONTROL BOARD
SUBCHAPTER c: HAZARDOUS WASTE OPERATING
REQUIREMENTS
PART 720
HAZARDOUS WASTE MANAGEMENT SYSTEM: GENERAL
SUBPART A: GENERAL PROVISIONS
Section
720.101
Purpose, Scope, and Applicability
720.102
Availability of Information; Confidentiality of Information
720.103
Use of Number and Gender
SUBPART B: DEFINITIONS
Section
44
720.110
Definitions
720.111
References
SUBPART C: RULEMAKING PETITIONS AND OTHER
PROCEDURES
Section
720.120
Rulemaking
720.121
Alternative Equivalent Testing Methods
720.122
Waste Delisting
720.123
Petitions for Regulation as Universal Waste
720.130
Procedures for Solid Waste Determinations
720.131
Solid Waste Determinations
720.132
Boiler Determinations
720.133
Procedures for Determinations
720.140
Additional regulation of certain hazardous waste Recycling Activities on
a case-by-case Basis
720.141
Procedures for case-by-case regulation of hazardous waste Recycling
Activities
720.Appendix A
Overview of 40 CFR, Subtitle C Regulations
AUTHORITY: Implementing Section 22.4 and authorized by Section 27 of the
Environmental Protection Act [415 ILCS 5/22.4 and 27].
SOURCE: Adopted in R81-22, 43 PCB 427, at 5 Ill. Reg. 9781, effective May 17,
1982; amended and codified in R81-22, 45 PCB 317, at 6 Ill. Reg. 4828, effective
May 17, 1982; amended in R82-19 at 7 Ill. Reg. 14015, effective October 12, 1983;
amended in R84-9, 53 PCB 131 at 9 Ill. Reg. 11819, effective July 24, 1985; amended
in R85-22 at 10 Ill. Reg. 968, effective January 2, 1986; amended in R86-1 at 10 Ill.
Reg. 13998, effective August 12, 1986; amended in R86-19 at 10 Ill. Reg. 20630,
effective December 2, 1986; amended in R86-28 at 11 Ill. Reg. 6017, effective March
24, 1987; amended in R86-46 at 11 Ill. Reg. 13435, effective August 4, 1987;
amended in R87-5 at 11 Ill. Reg. 19280, effective November 12, 1987; amended in
R87-26 at 12 Ill. Reg. 2450, effective January 15, 1988; amended in R87-39 at 12 Ill.
Reg. 12999, effective July 29, 1988; amended in R88-16 at 13 Ill. Reg. 362, effective
December 27, 1988; amended in R89-1 at 13 Ill. Reg. 18278, effective November 13,
1989; amended in R89-2 at 14 Ill. Reg. 3075, effective February 20, 1990; amended in
R89-9 at 14 Ill. Reg. 6225, effective April 16, 1990; amended in R90-10 at 14 Ill.
Reg. 16450, effective September 25, 1990; amended in R90-17 at 15 Ill. Reg. 7934,
effective May 9, 1991; amended in R90-11 at 15 Ill. Reg. 9323, effective June 17,
1991; amended in R91-1 at 15 Ill. Reg. 14446, effective September 30, 1991; amended
in R91-13 at 16 Ill. Reg. 9489, effective June 9, 1992; amended in R92-1 at 16 Ill.
Reg. 17636, effective November 6, 1992; amended in R92-10 at 17 Ill. Reg. 5625,
effective March 26, 1993; amended in R93-4 at 17 Ill. Reg. 20545, effective
November 22, 1993; amended in R93-16 at 18 Ill. Reg. 6720, effective April 26,
45
1994; amended in R94-7 at 18 Ill. Reg. 12160, effective July 29, 1994; amended in
R94-17 at 18 Ill. Reg. 17480, effective November 23, 1994; amended in R95-6 at 19
Ill. Reg. 9508, effective June 27, 1995; amended in R95-20 at 20 Ill. Reg. 10929,
August 1, 1996; amended in R96-10/R97-3/R97-5 at 21 Ill. Reg. ________, effective
____________________.
SUBPART A: GENERAL PROVISIONS
Section 720.101
Purpose, Scope, and Applicability
a)
This Part provides definitions of terms, general standards and overview
information applicable to 35 Ill. Adm. Code 720 through 725, and 728,
733, and 739.
b)
In this Part:
2)
Section 720.103 establishes rules of grammatical construction for
35 Ill. Adm. Code 720 through 725, and 728, 733, and 739.
3)
Section 720.110 defines terms which are used in 35 Ill. Adm.
Code 720 through 725, and 728, 733, and 739.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 720.102
Availability of Information; Confidentiality of Information
a)
Availability and confidentiality of information is governed by Illinois
law, including Sections 7 and 7.1 of the Environmental Protection Act
(Ill. Rev. Stat. 1983, ch. 111 1/2, pars. 1007 and 1007.1) [415 ILCS
5/7 and 7.1] and 35 Ill. Adm. Code 101.107 and 120.
b)
Information required under 35 Ill. Adm. Code 722.153(a) and 722.183
that is submitted in a notification of intent to export a hazardous waste
will be provided to the U.S. Department of State and the appropriate
authorities in the transit and receiving or importing countries regardless
of any claims of confidentiality or trade secret.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
SUBPART B: DEFINITIONS
Section 720.111
References
46
a)
The following publications are incorporated by reference:
ACI. Available from the American Concrete Institute, Box
19150, Redford Station, Detroit, Michigan 48219:
ACI 318-83: “Building Code Requirements for
Reinforced Concrete”, adopted September, 1983.
ANSI. Available from the American National Standards
Institute, 1430 Broadway, New York, New York 10018, 212-
354-3300:
ANSI B31.3 and B31.4. See ASME/ANSI B31.3 and
B31.4.
ACI. Available from the American Concrete Institute, Box
19150, Redford Station, Detroit, Michigan 48219:
ACI 318-83: “Building Code Requirements for
Reinforced Concrete”, adopted September, 1983.
API. Available from the American Petroleum Institute, 1220 L
Street, N.W., Washington, D.C. 20005, 202-682-8000:
“Cathodic Protection of Underground Petroleum Storage
Tanks and Piping Systems”, API Recommended Practice
1632, Second Edition, December, 1987.
“Evaporative Loss from External Floating-Roof Tanks”,
API Publication 2517, Third Edition, February, 1989.
“Guide for Inspection of Refinery Equipment, Chapter
XIII, Atmospheric and Low Pressure Storage Tanks”, 4th
Edition, 1981, reaffirmed December, 1987.
“Installation of Underground Petroleum Storage
Systems”, API Recommended Practice 1615, Fourth
Edition, November, 1987.
APTI. Available from the Air and Waste Management
Association, Box 2861, Pittsburgh, PA 15230, 412-232-3444:
APTI Course 415: Control of Gaseous Emissions,
USEPA Publication EPA-450/2-81-005, December, 1981.
47
ASME. Available from the American Society of Mechanical
Engineers, 345 East 47th Street, New York, NY 10017, 212-
705-7722:
“Chemical Plant and Petroleum Refinery Piping”,
ASME/ANSI B31.3-1987, as supplemented by B31.3a-
1988 and B31.3b-1988. Also available from ANSI.
“Liquid Transportation Systems for Hydrocarbons, Liquid
Petroleum Gas, Anhydrous Ammonia, and Alcohols”,
ASME/ANSI B31.4-1986, as supplemented by B31.4a-
1987. Also available from ANSI.
ASTM. Available from American Society for Testing and
Materials, 1916 Race Street, Philadelphia, PA 19103, 215-299-
5400:
ASTM C 94-90, Standard Specification for Ready-Mixed
Concrete, approved March 30, 1990.
ASTM D 88-87, Standard Test Method for Saybolt
Viscosity, April 24, 1981, reapproved January, 1987.
ASTM D 93-85, Standard Test Methods for Flash Point
by Pensky-Martens Closed Tester, approved October 25,
1985.
ASTM D 1946-90, Standard Practice for Analysis of
Reformed Gas by Gas Chromatography, Approved March
30, 1990.
ASTM D 2161-87, Standard Practice for Conversion of
Kinematic Viscosity to Saybolt Universal or to Saybolt
Furol Viscosity, March 27, 1987.
ASTM D 2267-88, Standard Test Method for Aromatics
in Light Naphthas and Aviation Gasolines by Gas
Chromatography, approved November 17, 1988.
ASTM D 2382-88, Standard Test Method for Heat of
Combustion of Hydrocarbon Fuels by Bomb Calorimeter
(High Precision Method), approved October 31, 1988.
ASTM D 2879-86, Standard Test Method for Vapor
Pressure-Temperature Relationship and Initial
48
Decomposition Temperature of Liquids by Isoteniscope,
approved October 31, 1986.
ASTM D 2879-92, Standard Test Method for Vapor
Pressure-Temperature Relationship and Initial
Decomposition Temperature of Liquids by Isoteniscope,
approved 1992.
ASTM D 3828-87, Standard Test Methods for Flash Point
of Liquids by Setaflash Closed Tester, approved
December 14, 1988.
ASTM E 168-88, Standard Practices for General
Techniques of Infrared Quantitative Analysis, approved
May 27, 1988.
ASTM E 169-87, Standard Practices for General
Techniques of Ultraviolet-Visible Quantitative Analysis,
approved February 1, 1987.
ASTM E 260-85, Standard Practice for Packed Column
Gas Chromatography, approved June 28, 1985.
ASTM E 926-88 C, Standard Test Methods for Preparing
Refuse-Derived Fuel (RDF) Samples for Analysis of
Metals, Bomb-Acid Digestion Method, approved March
25, 1988.
ASTM Method G 21-70 (1984a) -- Standard Practice for
Determining Resistance of Synthetic Polymer Materials to
Fungi.
ASTM Method G 22-76 (1984b) -- Standard Practice for
Determining Resistance of Plastics to Bacteria.
GPO. Available from the Superintendent of Documents, U.S.
Government Printing Office, Washington, D.C. 20402, 202-
783-3238:
Standard Industrial Classification Manual (1972), and
1977 Supplement, republished in 1983.
“Test Methods for Evaluating Solid Waste,
Physical/Chemical Methods”, USEPA Publication number
SW-846 (Third Edition, November, 1986), as amended
49
by Updates I (July, 1992), II (September, 1994), IIA
(August, 1993), and IIB (January, 1995) (Document
Number 955-001-00000-1).
NACE. Available from the National Association of Corrosion
Engineers, 1400 South Creek Dr., Houston, TX 77084, 713-
492-0535:
“Control of External Corrosion on Metallic Buried,
Partially Buried, or Submerged Liquid Storage Systems”,
NACE Recommended Practice RP0285-85, approved
March, 1985.
NFPA. Available from the National Fire Protection Association,
Batterymarch Park, Boston, MA 02269, 617-770-3000 or 800-
344-3555:
“Flammable and Combustible Liquids Code” NFPA 30,
issued July 17, 1987. Also available from ANSI.
NTIS. Available from the U.S. Department of Commerce,
National Technical Information Service, 5285 Port Royal Road,
Springfield, VA 22161, 703-487-4600:
“Generic Quality Assurance Project Plan for Land
Disposal Restrictions Program”, EPA/530-SW-87-011,
March 15, 1987. (Document number PB 88-170766.)
“Guidance on Air Quality Models”, Revised 1986.
(Document number PB86-245-248 (Guideline) and PB88-
150-958 (Supplement)).
“Methods for Chemical Analysis of Water and Wastes”,
Third Edition, March, 1983. (Document number PB 84-
128677).
“Methods Manual for Compliance with BIF Regulations”,
December, 1990. (Document number PB91-120-006).
“Petitions to Delist Hazardous Wastes -- A Guidance
Manual, Second Edition”, EPA/530-SW-85-003R-93-007,
April, 1985March, 1993. (Document Number PB 85-
19448893-169 365).
50
“Procedures Manual for Ground Water Monitoring at
Solid Waste Disposal Facilities”, EPA-530/SW-611,
1977. (Document number PB 84-174820).
“Screening Procedures for Estimating the Air Quality
Impact of Stationary Sources”, October, 1992,
Publication Number EPA-450/R-92-019.
OECD. Organisation for Economic Co-operation and
Development, Environment Directorate, 2 rue Andre Pascal,
75775 Paris Cedex 16, France):
OECD Guideline for Testing of Chemicals, Method 301B:
“CO
2
Evolution (Modified Sturm Test)”, adopted 17 July
1992.
Table 2.B of the Annex of OECD Council Decision
C(88)90(Final) of 27 May 1988.
STI. Available from the Steel Tank Institute, 728 Anthony Trail,
Northbrook, IL 60062, 708-498-1980:
“Standard for Dual Wall Underground Steel Storage
Tanks” (1986).
USEPA. Available from United States Environmental Protection
Agency, Office of Drinking Water, State Programs Division,
WH 550 E, Washington, D.C. 20460:
“Technical Assistance Document: Corrosion, Its
Detection and Control in Injection Wells”, EPA 570/9-87-
002, August, 1987.
USEPA. Available from Receptor Analysis Branch, USEPA
(MD-14), Research Triangle Park, NC 27711:
“Screening Procedures for Estimating the Air Quality
Impact of Stationary Sources, Revised”, October, 1992,
Publication Number EPA-450/R-92-019.
USEPA. Available from RCRA Information Center (RIC), 1235
Jefferson-Davis Highway, first floor, Arlington, VA 22203
(Docket # F-94-IEHF-FFFFF):
51
OECD Amber List of Wastes, Appendix 4 to the OECD
Council Decision C(92)39/FINAL (Concerning the
Control of Transfrontier Movements of Wastes Destined
for Recovery Operations) (May 1993).
OECD Green List of Wastes, Appendix 3 to the OECD
Council Decision C(92)39/FINAL (Concerning the
Control of Transfrontier Movements of Wastes Destined
for Recovery Operations) (May 1994).
OECD Red List of Wastes, Appendix 5 to the OECD
Council Decision C(92)39/FINAL (Concerning the
Control of Transfrontier Movements of Wastes Destined
for Recovery Operations) (May 1993).
Table 2.B of the Annex of OECD Council Decision
C(88)90(Final) (May 27, 1988).
b)
Code of Federal Regulations. Available from the Superintendent of
Documents, U.S. Government Printing Office, Washington, D.C.
20401, 202-783-3238:
10 CFR 20, Appendix B (19946)
40 CFR 51.100(ii) (19946)
40 CFR 51, Subpart W (19946)
40 CFR 52.741, Appendix B (1996)
40 CFR 60 (19946), as amended at 59 Fed. Reg. 62924 (Dec. 6,
1994)
40 CFR 61, Subpart V (19946)
40 CFR 136 (19946), as amended at 60 Fed. Reg. 17160 (Apr.
4, 1995)
40 CFR 142 (19946)
40 CFR 220 (19946)
40 CFR 260.20 (19946)
40 CFR 264 (19946)
52
40 CFR 268.Appendix IX (19946)
40 CFR 302.4, 302.5 and 302.6 (19946)
40 CFR 761 (19946)
49 CFR 171 (19956)
49 CFR 173 (19956)
49 CFR 178 (19946)
c)
Federal Statutes
Section 3004 of the Resource Conservation and Recovery Act (42
U.S.C. 6901 et seq.), as amended through December 31, 1987.
Sections 201(v), 201(w), and 360b(j) of the Federal Food, Drug, and
Cosmetic Act (FFDCA; 21 U.S.C. §§ 321(v), 321(w) & 512(j)), as
amended through October 25, 1994.
d)
This Section incorporates no later editions or amendments.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE G: WASTE DISPOSAL
CHAPTER I: POLLUTION CONTROL BOARD
SUBCHAPTER c: HAZARDOUS WASTE OPERATING
REQUIREMENTS
PART 721
IDENTIFICATION AND LISTING OF HAZARDOUS WASTE
SUBPART A: GENERAL PROVISIONS
Section
721.101
Purpose and Scope
721.102
Definition of Solid Waste
721.103
Definition of Hazardous Waste
721.104
Exclusions
721.105
Special Requirements for Hazardous Waste Generated by Small Quantity
Generators
721.106
Requirements for Recyclable Materials
53
721.107
Residues of Hazardous Waste in Empty Containers
721.108
PCB Wastes Regulated under TSCA
721.109
Requirements for Universal Waste
SUBPART B: CRITERIA FOR IDENTIFYING THE
CHARACTERISTICS OF HAZARDOUS WASTE AND FOR LISTING
HAZARDOUS WASTES
Section
721.110
Criteria for Identifying the Characteristics of Hazardous Waste
721.111
Criteria for Listing Hazardous Waste
SUBPART C: CHARACTERISTICS OF HAZARDOUS WASTE
Section
721.120
General
721.121
Characteristic of Ignitability
721.122
Characteristic of Corrosivity
721.123
Characteristic of Reactivity
721.124
Toxicity Characteristic
SUBPART D: LISTS OF HAZARDOUS WASTE
Section
721.130
General
721.131
Hazardous Wastes From Nonspecific Sources
721.132
Hazardous Waste from Specific Sources
721.133
Discarded Commercial Chemical Products, Off-Specification Species,
Container Residues, and Spill Residues Thereof
721.135
Wood Preserving Wastes
721.Appendix A
Representative Sampling Methods
721.Appendix B
Method 1311 Toxicity Characteristic Leaching Procedure (TCLP)
721.Appendix C
Chemical Analysis Test Methods
Table A
Analytical Characteristics of Organic Chemicals (Repealed)
Table B
Analytical Characteristics of Inorganic Species (Repealed)
Table C
Sample Preparation/Sample Introduction Techniques (Repealed)
721.Appendix G
Basis for Listing Hazardous Wastes
721.Appendix H
Hazardous Constituents
721.Appendix I
Wastes Excluded by Administrative Action
Table A
Wastes Excluded by U.S. EPA under 40 CFR 260.20 and 260.22
from Non-Specific Sources
Table B
Wastes Excluded by USEPA under 40 CFR 260.20 and 260.22
from Specific Sources
Table C
Wastes Excluded by U.S. EPA under 40 CFR 260.20 and 260.22
from Commercial Chemical Products, Off-Specification Species,
Container Residues, and Soil Residues Thereof
Table D
Wastes Excluded by the Board by Adjusted Standard
54
721.Appendix J
Method of Analysis for Chlorinated Dibenzo-p-Dioxins and
Dibenzofurans (Repealed)
721.Appendix Z
Table to Section 721.102
AUTHORITY: Implementing Section 22.4 and authorized by Section 27 of the
Environmental Protection Act [415 ILCS 5/22.4 and 27].
SOURCE: Adopted in R81-22, 43 PCB 427, at 5 Ill. Reg. 9781, effective May 17,
1982; amended and codified in R81-22, 45 PCB 317, at 6 Ill. Reg. 4828, effective as
noted in 35 Ill. Adm. Code May 17, 1982; amended in R82-18, 51 PCB 31, at 7 Ill.
Reg. 2518, effective February 22, 1983; amended in R82-19, 53 PCB 131, at 7 Ill.
Reg. 13999, effective October 12, 1983; amended in R84-34, 61 PCB 247, at 8 Ill.
Reg. 24562, effective December 11, 1984; amended in R84-9, at 9 Ill. Reg. 11834,
effective July 24, 1985; amended in R85-22 at 10 Ill. Reg. 998, effective January 2,
1986; amended in R85-2 at 10 Ill. Reg. 8112, effective May 2, 1986; amended in R86-
1 at 10 Ill. Reg. 14002, effective August 12, 1986; amended in R86-19 at 10 Ill. Reg.
20647, effective December 2, 1986; amended in R86-28 at 11 Ill. Reg. 6035, effective
March 24, 1987; amended in R86-46 at 11 Ill. Reg. 13466, effective August 4, 1987;
amended in R87-32 at 11 Ill. Reg. 16698, effective September 30, 1987; amended in
R87-5 at 11 Ill. Reg. 19303, effective November 12, 1987; amended in R87-26 at 12
Ill. Reg. 2456, effective January 15, 1988; amended in R87-30 at 12 Ill. Reg. 12070,
effective July 12, 1988; amended in R87-39 at 12 Ill. Reg. 13006, effective July 29,
1988; amended in R88-16 at 13 Ill. Reg. 382, effective December 27, 1988; amended
in R89-1 at 13 Ill. Reg. 18300, effective November 13, 1989; amended in R90-2 at 14
Ill. Reg. 14401, effective August 22, 1990; amended in R90-10 at 14 Ill. Reg. 16472,
effective September 25, 1990; amended in R90-17 at 15 Ill. Reg. 7950, effective May
9, 1991; amended in R90-11 at 15 Ill. Reg. 9332, effective June 17, 1991; amended in
R91-1 at 15 Ill. Reg. 14473, effective September 30, 1991; amended in R91-12 at 16
Ill. Reg. 2155, effective January 27, 1992; amended in R91-26 at 16 Ill. Reg. 2600,
effective February 3, 1992; amended in R91-13 at 16 Ill. Reg. 9519, effective June 9,
1992; amended in R92-1 at 16 Ill. Reg. 17666, effective November 6, 1992; amended
in R92-10 at 17 Ill. Reg. 5650, effective March 26, 1993; amended in R93-4 at 17 Ill.
Reg. 20568, effective November 22, 1993; amended in R93-16 at 18 Ill. Reg. 6741,
effective April 26, 1994; amended in R94-7 at 18 Ill. Reg. 12175, effective July 29,
1994; amended in R94-17 at 18 Ill. Reg. 17490, effective November 23, 1994;
amended in R95-6 at 19 Ill. Reg. 9522, effective June 27, 1995; amended in R95-20 at
20 Ill. Reg. 10963, August 1, 1996; amended in R96-10/R97-3/R97-5 at 21 Ill. Reg.
________, effective ____________________.
SUBPART A: GENERAL PROVISIONS
Section 721.104
Exclusions
55
a)
Materials that are not solid wastes. The following materials are not solid
wastes for the purpose of this Part:
1)
Sewage:
A)
Domestic sewage; and
B)
Any mixture of domestic sewage and other waste that
passes through a sewer system to publicly-owned
treatment works for treatment.
C)
“Domestic sewage” means untreated sanitary wastes that
pass through a sewer system.
2)
Industrial wastewater discharges that are point source discharges
with NPDES permits issued by the Agency pursuant to Section
12(f) of the Environmental Protection Act and 35 Ill. Adm. Code
309.
BOARD NOTE: This exclusion applies only to the actual point
source discharge. It does not exclude industrial wastewaters
while they are being collected, stored, or treated before
discharge, nor does it exclude sludges that are generated by
industrial wastewater treatment.
3)
Irrigation return flows.
4)
Source, special nuclear, or by-product material as defined by the
Atomic Energy Act of 1954, as amended (42 U.S.C. 2011 et
seq.).
5)
Materials subjected to in-situ mining techniques that are not
removed from the ground as part of the extraction process.
6)
Pulping liquors (i.e., black liquor) that are reclaimed in a pulping
liquor recovery furnace and then reused in the pulping process,
unless accumulated speculatively, as defined in Section
721.101(c).
7)
Spent sulfuric acid used to produce virgin sulfuric acid unless it is
accumulated speculatively, as defined in Section 721.101(c).
8)
Secondary materials that are reclaimed and returned to the
original process or processes in which they were generated where
they are reused in the production process, provided:
56
A)
Only tank storage is involved, and the entire process
through completion of reclamation is closed by being
entirely connected with pipes or other comparable
enclosed means of conveyance;
B)
Reclamation does not involve controlled flame combustion
(such as occurs in boilers, industrial furnaces or
incinerators);
C)
The secondary materials are never accumulated in such
tanks for over twelve months without being reclaimed;
and
D)
The reclaimed material is not used to produce a fuel or
used to produce products that are used in a manner
constituting disposal.
9)
Wood preserving wastes.
A)
Spent wood preserving solutions that have been used and
which are reclaimed and reused for their original intended
purpose; and
B)
Wastewaters from the wood preserving process that have
been reclaimed and which are reused to treat wood.
10)
Hazardous waste numbers K060, K087, K141, K142, K143,
K144, K145, K147, and K148, and any wastes from the coke by-
products processes that are hazardous only because they exhibit
the toxicity characteristic specified in Section 721.124, when
subsequent to generation these materials are recycled to coke
ovens, to the tar recovery process as a feedstock to produce coal
tar, or are mixed with coal tar prior to the tar’s sale or refining.
This exclusion is conditioned on there being no land disposal of
the waste from the point it is generated to the point it is recycled
to coke ovens, to tar recovery, to the tar refining processes, or
prior to when it is mixed with coal.
11)
Nonwastewater splash condenser dross residue from the treatment
of hazardous waste number K061 in high temperature metals
recovery units, provided it is shipped in drums (if shipped) and
not land disposed before recovery.
57
12)
Recovered oil from petroleum refining, exploration, and
production and from transportation incident thereto that is to be
inserted into the petroleum refining process (SIC Code 2911)
along with normal process streams prior to crude distillation or
catalytic crackingat or before a point (other than direct insertion
into a coker) where contaminants are removed. This exclusion
applies to recovered oil stored or transported prior to insertion,
except that the oil must not be stored in a manner involving
placement on the land and the oil must not be accumulated
speculatively before being recycled. Recovered oil is oil that has
been reclaimed from secondary materials (such as wastewater)
generated from normal petroleum refining, exploration, and
production, and from transportation practices. Recovered oil
includes oil that is recovered from refinery wastewater collection
and treatment systems, oil recovered from oil and gas drilling
operations, and oil recovered from wastes removed from crude
oil storage tanks. Recovered oil does not include (among other
things) oil-bearing hazardous wastes listed in 721.Subpart D of
this Part (e.g., K048 through K052, F037, and F038). However,
oil recovered from such wastes may be considered recovered oil.
Recovered oil also does not include used oil as defined in 35 Ill.
Adm. Code 739.100.
b)
Solid wastes that are not hazardous wastes. The following solid wastes
are not hazardous wastes:
1)
Household waste, including household waste that has been
collected, transported, stored, treated, disposed, recovered (e.g.,
refuse-derived fuel), or reused. “Household waste” means any
waste material (including garbage, trash, and sanitary wastes in
septic tanks) derived from households (including single and
multiple residences, hotels, and motels, bunkhouses, ranger
stations, crew quarters, campgrounds, picnic grounds, and day-
use recreation areas). A resource recovery facility managing
municipal solid waste shall not be deemed to be treating, storing,
disposing of, or otherwise managing hazardous wastes for the
purposes of regulation under this Part, if such facility:
A)
Receives and burns only:
i)
Household waste (from single and multiple
dwellings, hotels, motels, and other residential
sources); and
58
ii)
Solid waste from commercial or industrial sources
that does not contain hazardous waste, and
B)
Such facility does not accept hazardous waste and the
owner or operator of such facility has established
contractual requirements or other appropriate notification
or inspection procedures to assure that hazardous wastes
are not received at or burned in such facility.
BOARD NOTE: The U.S. Supreme Court determined, in
City of Chicago v. Environmental Defense Fund, Inc., --
U.S. --, 114 S. Ct. 1588 (1994), that this exclusion and
RCRA section 3001(i) (42 U.S.C. § 6921(i)) do not
exclude the ash from facilities covered by this subsection
from regulation as a hazardous waste. At 59 Fed. Reg.
29372 (June 7, 1994), USEPA granted facilities managing
ash from such facilities that is determined a hazardous
waste under 721.Subpart C of this Part until December 7,
1994 to file a Part A permit application pursuant to 35 Ill.
Adm. Code 703.181. At 60 Fed. Reg. 6666 (Feb. 3,
1995), USEPA stated that it interpreted that the point at
which ash becomes subject to RCRA Subtitle C regulation
is when that material leaves the combustion building
(including connected air pollution control equipment).
2)
Solid wastes generated by any of the following that are returned
to the soil as fertilizers:
A)
The growing and harvesting of agricultural crops, or
B)
The raising of animals, including animal manures.
3)
Mining overburden returned to the mine site.
4)
Fly ash waste, bottom ash waste, slag waste, and flue gas
emission control waste generated primarily from the combustion
of coal or other fossil fuels, except as provided in 35 Ill. Adm.
Code 726.212 for facilities that burn or process hazardous waste.
5)
Drilling fluids, produced waters, and other wastes associated with
the exploration, development, or production of crude oil, natural
gas, or geothermal energy.
6)
Chromium wastes:
59
A)
Wastes that fail the test for the toxicity characteristic
(Sections 721.124 and 721.Appendix B) because
chromium is present or which are are listed in
721.Subpart D of this Part due to the presence of
chromium, that do not fail the test for the toxicity
characteristic for any other constituent or which are not
listed due to the presence of any other constituent, and
that do not fail the test for any other characteristic, if it is
shown by a waste generator or by waste generators that:
i)
The chromium in the waste is exclusively (or
nearly exclusively) trivalent chromium;
ii)
The waste is generated from an industrial process
that uses trivalent chromium exclusively (or nearly
exclusively) and the process does not generate
hexavalent chromium; and
iii)
The waste is typically and frequently managed in
non-oxidizing environments.
B)
Specific wastes that meet the standard in subsection
(b)(6)(A) aboveof this Section (so long as they do not fail
the test for the toxicity characteristic for any other
constituent and do not exhibit any other characteristic)
are:
i)
Chrome (blue) trimmings generated by the
following subcategories of the leather tanning and
finishing industry: hair pulp/chrome tan/retan/wet
finish, hair save/chrome tan/retan/wet finish,
retan/wet finish, no beamhouse, through-the-blue,
and shearling;
ii)
Chrome (blue) shavings generated by the following
subcategories of the leather tanning and finishing
industry: hair pulp/chrome tan/retan/wet finish,
hair save/chrome tan/retan/wet finish, retan/wet
finish, no beamhouse, through-the-blue, and
shearling;
iii)
Buffing dust generated by the following
subcategories of the leather tanning and finishing
industry: hair pulp/chrome tan/retan/wet finish,
60
hair save/chrome tan/retan/wet finish, retan/wet
finish, no beamhouse, through-the-blue;
iv)
Sewer screenings generated by the following
subcategories of the leather tanning and finishing
industry: hair pulp/chrome tan/retan/wet finish,
hair save/chrome tan/retan/wet finish, retan/wet
finish, no beamhouse, through-the-blue, and
shearling;
v)
Wastewater treatment sludges generated by the
following subcategories of the leather tanning and
finishing industry: hair pulp/chrome tan/retan/wet
finish, hair save/chrome tan/retan/wet finish,
retan/wet finish, no beamhouse, through-the-blue,
and shearling;
vi)
Wastewater treatment sludges generated by the
following subcategories of the leather tanning and
finishing industry: hair pulp/chrome tan/retan/wet
finish, hair save/chrome tan/retan/wet finish, and
through-the-blue;
vii)
Waste scrap leather from the leather tanning
industry, the shoe manufacturing industry, and
other leather product manufacturing industries; and
viii)
Wastewater treatment sludges from the production
of titanium dioxide pigment using chromium-
bearing ores by the chloride process.
7)
Solid waste from the extraction, beneficiation, and processing of
ores and minerals (including coal, phosphate rock, and
overburden from the mining of uranium ore), except as provided
by 35 Ill. Adm. Code 726.212 for facilities that burn or process
hazardous waste. For purposes of this subsection, beneficiation
of ores and minerals is restricted to the following activities:
crushing, grinding, washing, dissolution, crystallization,
filtration, sorting, sizing, drying, sintering, pelletizing,
briquetting, calcining to remove water or carbon dioxide,
roasting, autoclaving or chlorination in preparation for leaching
(except where the roasting or autoclaving or chlorination and
leaching sequence produces a final or intermediate product that
does not undergo further beneficiation or processing), gravity
concentration, magnetic separation, electrostatic separation,
61
floatation, ion exchange, solvent extraction, electrowinning,
precipitation, amalgamation, and heap, dump, vat tank, and in
situ leaching. For the purposes of this subsection, solid waste
from the processing of ores and minerals includes only the
following wastes:
A)
Slag from primary copper processing,
B)
Slag from primary lead processing,
C)
Red and brown muds from bauxite refining,
D)
Phosphogypsum from phosphoric acid production,
E)
Slag from elemental phosphorus production,
F)
Gasifier ash from coal gasification,
G)
Process wastewater from coal gasification,
H)
Calcium sulfate wastewater treatment plant sludge from
primary copper processing,
I)
Slag tailings from primary copper processing,
J)
Fluorogypsum from hydrofluoric acid production,
K)
Process wastewater from hydrofluoric acid production,
L)
Air pollution control dust or sludge from iron blast
furnaces,
M)
Iron blast furnace slag,
N)
Treated residue from roasting and leaching of chrome ore,
O)
Process wastewater from primary magnesium processing
by the anhydrous process,
P)
Process wastewater from phosphoric acid production,
Q)
Basic oxygen furnace and open hearth furnace air
pollution control dust or sludge from carbon steel
production,
62
R)
Basic oxygen furnace and open hearth furnace slag from
carbon steel production,
S)
Chloride processing waste solids from titanium
tetrachloride production, and
T)
Slag from primary zinc smelting.
8)
Cement kiln dust waste, except as provided by 35 Ill. Adm. Code
726.212 for facilities that burn or process hazardous waste.
9)
Solid waste that consists of discarded arsenical-treated wood or
wood products that fails the test for the toxicity characteristic for
hazardous waste codes D004 through D017 and which is not a
hazardous waste for any other reason if the waste is generated by
persons that utilize the arsenical-treated wood and wood products
for these materials’ intended end use.
10)
Petroleum-contaminated media and debris that fail the test for the
toxicity characteristic of Section 721.124 (hazardous waste codes
D018 through D043 only) and which are subject to corrective
action regulations under 35 Ill. Adm. Code 731.
11)
This subsection corresponds with 40 CFR 261.4(b)(11), which
expired by its own terms on January 25, 1993. This statement
maintains structural parity with USEPA regulations.
12)
Used chlorofluorocarbon refrigerants from totally enclosed heat
transfer equipment, including mobile air conditioning systems,
mobile refrigeration, and commercial and industrial air
conditioning and refrigeration systems, that uses chlorofluoro-
carbons as the heat transfer fluid in a refrigeration cycle,
provided the refrigerant is reclaimed for further use.
13)
Non-terne plated used oil filters that are not mixed with wastes
listed in 721.Subpart D of this Part, if these oil filters have been
gravity hot-drained using one of the following methods:
A)
Puncturing the filter anti-drain back valve or the filter
dome end and hot-draining;
B)
Hot-draining and crushing;
C)
Dismantling and hot-draining; or
63
D)
Any other equivalent hot-draining method that will
remove used oil.
14)
Used oil re-refining distillation bottoms that are used as feedstock
to manufacture asphalt products.
c)
Hazardous wastes that are exempted from certain regulations. A
hazardous waste that is generated in a product or raw material storage
tank, a product or raw material transport vehicle or vessel, a product or
raw material pipeline, or in a manufacturing process unit, or an
associated non-waste-treatment manufacturing unit, is not subject to
regulation under 35 Ill. Adm. Code 702, 703, 705, and 722 through
725, and 728 or to the notification requirements of Section 3010 of
RCRA until it exits the unit in which it was generated, unless the unit is
a surface impoundment, or unless the hazardous waste remains in the
unit more than 90 days after the unit ceases to be operated for
manufacturing or for storage or transportation of product or raw
materials.
d)
Samples
1)
Except as provided in subsection (d)(2) belowof this Section, a
sample of solid waste or a sample of water, soil, or air that is
collected for the sole purpose of testing to determine its
characteristics or composition is not subject to any requirements
of this Part or 35 Ill. Adm. Code 702, 703, 705, and 722 through
728. The sample qualifies when:
A)
The sample is being transported to a laboratory for the
purpose of testing;
B)
The sample is being transported back to the sample
collector after testing;
C)
The sample is being stored by the sample collector before
transport to a laboratory for testing;
D)
The sample is being stored in a laboratory before testing;
E)
The sample is being stored in a laboratory for testing but
before it is returned to the sample collector; or
F)
The sample is being stored temporarily in the laboratory
after testing for a specific purpose (for example, until
64
conclusion of a court case or enforcement action where
further testing of the sample may be necessary).
2)
In order to qualify for the exemption in subsection (d)(1)(A) or
(d)(1)(B) aboveof this Section, a sample collector shipping
samples to a laboratory and a laboratory returning samples to a
sample collector shall:
A)
Comply with U.S. Department of Transportation (DOT),
U.S. Postal Service (USPS), or any other applicable
shipping requirements; or
B)
Comply with the following requirements if the sample
collector determines that DOT, USPS, or other shipping
requirements do not apply to the shipment of the sample:
i)
Assure that the following information accompanies
the sample: The sample collector’s name, mailing
address, and telephone number; the laboratory’s
name, mailing address, and telephone number; the
quantity of the sample; the date of the shipment;
and a description of the sample.
ii)
Package the sample so that it does not leak, spill,
or vaporize from its packaging.
3)
This exemption does not apply if the laboratory determines that
the waste is hazardous but the laboratory is no longer meeting
any of the conditions stated in subsection (d)(1) aboveof this
Section.
e)
Treatability study samples.
1)
Except as is provided in subsection (e)(2) belowof this Section, a
person that generates or collects samples for the purpose of
conducting treatability studies, as defined in 35 Ill. Adm. Code
720.110, are not subject to any requirement of 35 Ill. Adm. Code
721 through 723 or to the notification requirements of Section
3010 of the Resource Conservation and Recovery Act. Nor are
such samples included in the quantity determinations of Section
721.105 and 35 Ill. Adm. Code 722.134(d) when:
A)
The sample is being collected and prepared for
transportation by the generator or sample collector;
65
B)
The sample is being accumulated or stored by the
generator or sample collector prior to transportation to a
laboratory or testing facility; or
C)
The sample is being transported to the laboratory or
testing facility for the purpose of conducting a treatability
study.
2)
The exemption in subsection (e)(1) aboveof this Section is
applicable to samples of hazardous waste being collected and
shipped for the purpose of conducting treatability studies
provided that:
A)
The generator or sample collector uses (in “treatability
studies”) no more than 10,000 kg of media contaminated
with non-acute hazardous waste, 1000 kg of non-acute
hazardous waste other than contaminated media, 1 kg of
acute hazardous waste, or 2500 kg of media contaminated
with acute hazardous waste for each process being
evaluated for each generated wastestream;
B)
The mass of each shipment does not exceed 10,000 kg;
the 10,000 kg quantity may be all media contaminated
with non-acute hazardous waste, or may include 2500 kg
of media contaminated with acute hazardous waste, 1000
kg of hazardous waste, and 1 kg of acute hazardous
waste;
C)
The sample must be packaged so that it does not leak,
spill, or vaporize from its packaging during shipment and
the requirements of subsections (e)(2)(C)(i) or
(e)(2)(C)(ii), belowof this Section, are met.
i)
The transportation of each sample shipment
complies with U.S. Department of Transportation
(DOT), U.S. Postal Service (USPS), or any other
applicable shipping requirements; or
ii)
If the DOT, USPS, or other shipping requirements
do not apply to the shipment of the sample, the
following information must accompany the
sample: The name, mailing address, and
telephone number of the originator of the sample;
the name, address, and telephone number of the
facility that will perform the treatability study; the
66
quantity of the sample; the date of the shipment;
and, a description of the sample, including its
USEPA hazardous waste number;
D)
The sample is shipped to a laboratory or testing facility
that is exempt under subsection (f) belowof this Section,
or has an appropriate RCRA permit or interim status;
E)
The generator or sample collector maintains the following
records for a period ending three years after completion of
the treatability study:
i)
Copies of the shipping documents;
ii)
A copy of the contract with the facility conducting
the treatability study;
iii)
Documentation showing: The amount of waste
shipped under this exemption; the name, address,
and USEPA identification number of the
laboratory or testing facility that received the
waste; the date the shipment was made; and
whether or not unused samples and residues were
returned to the generator; and
F)
The generator reports the information required in
subsection (e)(2)(E)(iii) aboveof this Section in its report
under 35 Ill. Adm. Code 722.141.
3)
The Agency may grant requests on a case-by-case basis for up to
an additional two years for treatability studies involving
bioremediation. The Agency may grant requests, on a case-by-
case basis, for quantity limits in excess of those specified in
subsections (e)(2)(A), and (e)(2)(B), above and (f)(4) belowof
this Section, for up to an additional 5000 kg of media
contaminated with non-acute hazardous waste, 500 kg of non-
acute hazardous waste, 2500 kg of media contaminated with acute
hazardous waste, and 1 kg of acute hazardous waste:
A)
In response to requests for authorization to ship, store,
and conduct further treatability studies on additional
quantities in advance of commencing treatability studies.
Factors to be considered in reviewing such requests
include the nature of the technology, the type of process
(e.g., batch versus continuous), the size of the unit
67
undergoing testing (particularly in relation to scale-up
considerations), the time or quantity of material required
to reach steady-state operating conditions, or test design
considerations, such as mass balance calculations.
B)
In response to requests for authorization to ship, store,
and conduct treatability studies on additional quantities
after initiation or completion of initial treatability studies
when: There has been an equipment or mechanical failure
during the conduct of the treatability study, there is need
to verify the results of a previously-conducted treatability
study, there is a need to study and analyze alternative
techniques within a previously-evaluated treatment
process, or there is a need to do further evaluation of an
ongoing treatability study to determine final specifications
for treatment.
C)
The additional quantities allowed and timeframes allowed
in subsections (e)(3)(A) and (e)(3)(B) aboveof this Section
are subject to all the provisions in subsections (e)(1) and
(e)(2)(B) through (e)(2)(F) aboveof this Section. The
generator or sample collector shall apply to the Agency
and provide in writing the following information:
i)
The reason why the generator or sample collector
requires additional time or quantity of sample for
the treatability study evaluation and the additional
time or quantity needed;
ii)
Documentation accounting for all samples of
hazardous waste from the wastestream that have
been sent for or undergone treatability studies,
including the date each previous sample from the
waste stream was shipped, the quantity of each
previous shipment, the laboratory or testing facility
to which it was shipped, what treatability study
processes were conducted on each sample shipped,
and the available results of each treatability study;
iii)
A description of the technical modifications or
change in specifications that will be evaluated and
the expected results;
iv)
If such further study is being required due to
equipment or mechanical failure, the applicant
68
shall include information regarding the reason for
the failure or breakdown and also include what
procedures or equipment improvements have been
made to protect against further breakdowns; and
v)
Such other information as the Agency determines
is necessary.
4)
Final Agency determinations pursuant to this subsection may be
appealed to the Board.
f)
Samples undergoing treatability studies at laboratories or testing
facilities. Samples undergoing treatability studies and the laboratory or
testing facility conducting such treatability studies (to the extent such
facilities are not otherwise subject to RCRA requirements) are not
subject to any requirement of this Part, or of 35 Ill. Adm. Code 702,
703, 705, 722 through 726, and 728 or to the notification requirements
of Section 3010 of the Resource Conservation and Recovery Act,
provided that the requirements of subsections (f)(1) through (f)(11)
belowof this Section are met. A mobile treatment unit may qualify as a
testing facility subject to subsections (f)(1) through (f)(11) belowof this
Section. Where a group of mobile treatment units are located at the
same site, the limitations specified in subsections (f)(1) through (f)(11)
belowof this Section apply to the entire group of mobile treatment units
collectively as if the group were one mobile treatment unit.
1)
No less than 45 days before conducting treatability studies, the
facility notifies the Agency in writing that it intends to conduct
treatability studies under this subsection (f).
2)
The laboratory or testing facility conducting the treatability study
has a USEPA identification number.
3)
No more than a total of 10,000 kg of “as received” media
contaminated with non-acute hazardous waste, 2500 kg of media
contaminated with acute hazardous waste, or 250 kg of other “as
received” hazardous waste is subject to initiation of treatment in
all treatability studies in any single day. “As received” waste
refers to the waste as received in the shipment from the generator
or sample collector.
4)
The quantity of “as received” hazardous waste stored at the
facility for the purpose of evaluation in treatability studies does
not exceed 10,000 kg, the total of which can include 10,000 kg
of media contaminated with non-acute hazardous waste, 2500 kg
69
of media contaminated with acute hazardous waste, 1000 kg of
non-acute hazardous wastes other than contaminated media, and 1
kg of acute hazardous waste. This quantity limitation does not
include treatment materials (including nonhazardous solid waste)
added to “as received” hazardous waste.
5)
No more than 90 days have elapsed since the treatability study for
the sample was completed, or no more than one year (two years
for treatability studies involving bioremediation) has elapsed
since the generator or sample collector shipped the sample to the
laboratory or testing facility, whichever date first occurs. Up to
500 kg of treated material from a particular waste stream from
treatability studies may be archived for future evaluation up to
five years from the date of initial receipt. Quantities of materials
archived are counted against the total storage limit for the
facility.
6)
The treatability study does not involve the placement of
hazardous waste on the land or open burning of hazardous waste.
7)
The facility maintains records for three years following
completion of each study that show compliance with the
treatment rate limits and the storage time and quantity limits.
The following specific information must be included for each
treatability study conducted:
A)
The name, address, and USEPA identification number of
the generator or sample collector of each waste sample;
B)
The date the shipment was received;
C)
The quantity of waste accepted;
D)
The quantity of “as received” waste in storage each day;
E)
The date the treatment study was initiated and the amount
of “as received” waste introduced to treatment each day;
F)
The date the treatability study was concluded;
G)
The date any unused sample or residues generated from
the treatability study were returned to the generator or
sample collector or, if sent to a designated facility, the
name of the facility and the USEPA identification
number.
70
8)
The facility keeps, on-site, a copy of the treatability study
contract and all shipping papers associated with the transport of
treatability study samples to and from the facility for a period
ending three years from the completion date of each treatability
study.
9)
The facility prepares and submits a report to the Agency by
March 15 of each year that estimates the number of studies and
the amount of waste expected to be used in treatability studies
during the current year, and includes the following information
for the previous calendar year:
A)
The name, address, and USEPA identification number of
the facility conducting the treatability studies;
B)
The types (by process) of treatability studies conducted;
C)
The names and addresses of persons for whom studies
have been conducted (including their USEPA
identification numbers);
D)
The total quantity of waste in storage each day;
E)
The quantity and types of waste subjected to treatability
studies;
F)
When each treatability study was conducted; and
G)
The final disposition of residues and unused sample from
each treatability study.
10)
The facility determines whether any unused sample or residues
generated by the treatability study are hazardous waste under
Section 721.103 and, if so, are subject to 35 Ill. Adm. Code 702,
703, and 721 through 728, unless the residues and unused
samples are returned to the sample originator under the
exemption of subsection (e) exemption aboveof this Section.
11)
The facility notifies the Agency by letter when the facility is no
longer planning to conduct any treatability studies at the site.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
71
Section 721.105
Special Requirements for Hazardous Waste Generated by Small
Quantity Generators
a)
A generator is a conditionally exempt small quantity generator in a
calendar month if it generates no more than 100 kilograms of hazardous
waste in that month. 35 Ill. Adm. Code 700 explains the relation of this
to the 100 kg/mo exception of 35 Ill. Adm. Code 809.
b)
Except for those wastes identified in subsections (e), (f), (g) and (j)
belowof this Section, a conditionally exempt small quantity generator’s
hazardous wastes are not subject to regulation under 35 Ill. Adm. Code
702, 703, 705 and 722 through 726 and 728, and the notification
requirements of Section 3010 of Resource Conservation and Recovery
Act, provided the generator complies with the requirements of
subsections (f), (g) and (j) belowof this Section.
c)
When making the quantity determinations of this Part and 35 Ill. Adm.
Code 722, the generator must include all hazardous waste that it
generates, except the following hazardous waste:
1)
Hazardous waste that is exempt from regulation under Section
721.104(c) through (f), 721.106(a)(3), 721.107(a)(1), or
721.108;
2)
Hazardous waste that is managed immediately upon generation
only in on-site elementary neutralization units, wastewater
treatment units, or totally enclosed treatment facilities, as defined
in 35 Ill. Adm. Code 720.110;
3)
Hazardous waste that is recycled, without prior storage or
accumulation, only in an on-site process subject to regulation
under Section 721.106(c)(2);
4)
Hazardous waste that is used oil managed under the requirements
of Section 721.106(a)(4) and 35 Ill. Adm. Code 739;
5)
Hazardous waste that is spent lead-acid batteries managed under
the requirements of 35 Ill. Adm. Code 726.Subpart G; and
6)
Hazardous waste that is universal waste managed under Section
721.109 and 35 Ill. Adm. Code 733.
d)
In determining the quantity of hazardous waste it generates, a generator
need not include:
72
1)
Hazardous waste when it is removed from on-site storage; or
2)
Hazardous waste produced by on-site treatment (including
reclamation) of its hazardous waste so long as the hazardous
waste that is treated was counted once; or
3)
Spent materials that are generated, reclaimed and subsequently
reused on-site, so long as such spent materials have been counted
once.
e)
If a generator generates acute hazardous waste in a calendar month in
quantities greater than set forth below, all quantities of that acute
hazardous waste are subject to full regulation under 35 Ill. Adm. Code
702, 703, 705 and 722 through 726 and 728, and the notification
requirements of Section 3010 of the Resource Conservation and
Recovery Act:
1)
A total of one kilogram of one or more of the acute hazardous
wastes listed in Section 721.131, 721.132, or 721.133(e); or
2)
A total of 100 kilograms of any residue or contaminated soil,
waste or other debris resulting from the clean-up of a spill, into
or on any land or water, of any one or more of the acute
hazardous wastes listed in Section 721.131, 721.132, or
721.133(e).
BOARD NOTE: “Full regulation” means those regulations
applicable to generators of greater than 1000 kg of non-acute
hazardous waste in a calendar month.
f)
In order for acute hazardous wastes generated by a generator of acute
hazardous wastes in quantities equal to or less than those set forth in
subsection (e)(1) or (e)(2) aboveof this Section to be excluded from full
regulation under this Section, the generator must comply with the
following requirements:
1)
35 Ill. Adm. Code 722.111.
2)
The generator may accumulate acute hazardous waste on-site. If
the generator accumulates at any time acute hazardous wastes in
quantities greater than set forth in subsection (e)(1) or (e)(2)
aboveof this Section, all of those accumulated wastes are subject
to regulation under 35 Ill. Adm. Code 702, 703, 705 and 722
through 726 and 728, and the applicable notification requirements
of Section 3010 of the Resource Conservation and Recovery Act.
73
The time period of 35 Ill. Adm. Code 722.134(a), for
accumulation of wastes on-site, begins when the accumulated
wastes exceed the applicable exclusion limit.
3)
A conditionally exempt shallsmall quantity generator may either
treat or dispose of its acute hazardous waste in an on-site facility
or ensure delivery to an off-site storage, treatment, storage, or
disposal facility, provided that if the on-site or off-site facility is
located in the United States, it fulfillsany of which, if located in
the United States, meets any of the following conditions :
A)
The facility is permitted under 35 Ill. Adm. Code 702 and
703;
B)
The facility has interim status under 35 Ill. Adm. Code
702, 703 and 725;
C)
The facility is authorized to manage hazardous waste by a
state with a hazardous waste management program
approved by USEPA pursuant to 40 CFR 271;
D)
The facility is permitted, licensed, or registered by a state
to manage municipal or industrial solid waste;
E)
The facility is a facility that:
i)
Beneficially uses or reuses or legitimately recycles
or reclaims its waste; or
ii)
Treats its waste prior to beneficial use or reuse, or
legitimate recycling or reclamation; or
F)
For universal waste managed under 35 Ill. Adm. Code
733 or 40 CFR 273, the facility is a universal waste
handler or destination facility subject to the requirements
of 35 Ill. Adm. Code 733 or 40 CFR 273.
g)
In order for hazardous waste generated by a conditionally exempt small
quantity generator in quantities of less than 100 kilograms of hazardous
waste during a calendar month to be excluded from full regulation under
this Section, the generator must comply with the following requirements:
1)
35 Ill. Adm. Code 722.111;
74
2)
The conditionally exempt small quantity generator may
accumulate hazardous waste on-site. If it accumulates at any
time more than a total of 1000 kilograms of the generator’s
hazardous waste, all of those accumulated wastes are subject to
regulation under the special provisions of 35 Ill. Adm. Code 722
applicable to generators of between 100 kg and 1000 kg of
hazardous waste in a calendar month as well as the requirements
of 35 Ill. Adm. Code 702, 703, 705 and 723 through 726 and
728, and the applicable notification requirements of Section 3010
of the Resource Conservation and Recovery Act. The time
period of 35 Ill. Adm. Code 722.134(d) for accumulation of
wastes on-site begins for a small quantity generator when the
accumulated wastes exceed 1000 kilograms;
3)
A conditionally exempt small quantity generator may either treat
or dispose of its hazardous waste in an on-site facility or ensure
delivery to an off-site storage, treatment, storage, or disposal
facility, provided that if the on-site or off-site facility is located
inany of which, if located in the United States, it fulfillsmeets
any of the following conditions :
A)
The facility is permitted under 35 Ill. Adm. Code 702 and
703;
B)
The facility has interim status under 35 Ill. Adm. Code
702, 703 and 725;
C)
The facility is authorized to manage hazardous waste by a
state with a hazardous waste management program
approved by USEPA under 40 CFR 271 (1986);
D)
The facility is permitted, licensed, or registered by a state
to manage municipal or industrial solid waste;
E)
The facility is a facility that:
i)
Beneficially uses or re-uses, or legitimately
recycles or reclaims the small quantity generator’s
waste; or
ii)
Treats its waste prior to beneficial use or re-use, or
legitimate recycling or reclamation; or
F)
For universal waste managed under 35 Ill. Adm. Code
733 or 40 CFR 273, the facility is a universal waste
75
handler or destination facility subject to the requirements
of 35 Ill. Adm. Code 733 or 40 CFR 273.
h)
Hazardous waste subject to the reduced requirements of this Section may
be mixed with non-hazardous waste and remain subject to these reduced
requirements even though the resultant mixture exceeds the quantity
limitations identified in this Section, unless the mixture meets any of the
characteristics of hazardous wastes identified in Subpart C.
i)
If a small quantity generator mixes a solid waste with a hazardous waste
that exceeds a quantity exclusion level of this Section, the mixture is
subject to full regulation.
j)
If a conditionally exempt small quantity generator’s hazardous wastes are
mixed with used oil, the mixture is subject to 35 Ill. Adm. Code 739, if
it is destined to be burned for energy recovery. Any material produced
from such a mixture by processing, blending, or other treatment is also
so regulated if it is destined to be burned for energy recovery.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 721.106
Requirements for Recyclable Materials
a)
Recyclable materials:
1)
Hazardous wastes that are recycled are subject to the
requirements for generators, transporters, and storage facilities of
subsections (b) and (c) belowof this Section, except for the
materials listed in subsections (a)(2) and (a)(3) belowof this
Section. Hazardous wastes that are recycled will be known as
“recyclable materials”.
2)
The following recyclable materials are not subject to the
requirements of this Section but are regulated under 35 Ill. Adm.
Code 726.Subparts C through H and all applicable provisions in
35 Ill. Adm. Code 702, 703, and 705.
A)
Recyclable materials used in a manner constituting
disposal (35 Ill. Adm. Code 726.Subpart C);
B)
Hazardous wastes burned for energy recovery in boilers
and industrial furnaces that are not regulated under 35 Ill.
Adm. Code 724.Subpart O or 725.Subpart O (35 Ill.
Adm. Code 726.Subpart H);
76
C)
Recyclable materials from which precious metals are
reclaimed (35 Ill. Adm. Code 726.Subpart F);
D)
Spent lead-acid batteries that are being reclaimed (35 Ill.
Adm. Code 726.Subpart G).
3)
The following recyclable materials are not subject to regulation
under 35 Ill. Adm. Code 722 through 726, 728, or 702, 703, or
705 and are not subject to the notification requirements of Section
3010 of the Resource Conservation and Recovery Act:
A)
Industrial ethyl alcohol that is reclaimed except that,
unless provided otherwise in an international agreement as
specified in 35 Ill. Adm. Code 722.158:
i)
A person initiating a shipment for reclamation in a
foreign country and any intermediary arranging for
the shipment shall comply with the requirements
applicable to a primary exporter in 35 Ill. Adm.
Code 722.153; 722.156(a)(1) through (a)(4),
(a)(6), and (b); and 722.157; shall export such
materials only upon consent of the receiving
country and in conformance with the USEPA
Acknowledgement of Consent, as defined in 35 Ill.
Adm. Code 722.Subpart E; and shall provide a
copy of the USEPA Acknowledgement of Consent
to the shipment to the transporter transporting the
shipment for export;
ii)
Transporters transporting a shipment for export
shall not accept a shipment if the transporter
knows that the shipment does not conform to the
USEPA Acknowledgement of Consent, shall
ensure that a copy of the USEPA
Acknowledgement of Consent accompanies the
shipment, and shall ensure that it is delivered to
the facility designated by the person initiating the
shipment;
B)
Scrap metal;
C)
Fuels produced from the refining of oil-bearing hazardous
wastes along with normal process streams at a petroleum
refining facility if such wastes result from normal
petroleum refining, production, and transportation
77
practices (this exemption does not apply to fuels produced
from oil recovered from oil-bearing hazardous waste
where such recovered oil is already excluded under
Section 721.104(a)(12));
D)
Petroleum refining wastes.
i)
Hazardous waste fuel produced from oil-bearing
hazardous wastes from petroleum refining,
production, or transportation practices or produced
from oil reclaimed from such hazardous wastes,
where such hazardous wastes are reintroduced into
a process that does not use distillation or does not
produce products from crude oil, so long as the
resulting fuel meets the used oil specification under
35 Ill. Adm. Code 726.140(e) and so long as no
other hazardous wastes are used to produce the
hazardous waste fuel;
ii)
Hazardous waste fuel produced from oil-bearing
hazardous waste from petroleum refining
production, and transportation practices, where
such hazardous wastes are reintroduced into a
refining process after a point at which
contaminants are removed, so long as the fuel
meets the used oil fuel specification under 35 Ill.
Adm. Code 726.140(e); and
iii)
Oil reclaimed from oil-bearing hazardous wastes
from petroleum refining, production, and
transportation practices, which reclaimed oil is
burned as a fuel without reintroduction to a
refining process, so long as the reclaimed oil meets
the used oil fuel specification under 35 Ill. Adm.
Code 726.140(e); and
E)
Petroleum coke produced from petroleum refinery
hazardous wastes containing oil by the same person that
generated the wastes unless the resulting coke product
exceeds one or more of the characteristics of hazardous
waste in 721.Subpart C.
4)
Used oil that is recycled and is also a hazardous waste solely
because it exhibits a hazardous characteristic is not subject to the
requirements of 35 Ill. Adm. Code 720 through 728, but it is
78
regulated under 35 Ill. Adm. Code 739. Used oil that is recycled
includes any used oil that is reused for any purpose following its
original use (including the purpose for which the oil was
originally used). Such term includes, but is not limited to, oil
that is re-refined, reclaimed, burned for energy recovery, or
reprocessed.
5)
Hazardous waste that is exported to or imported from designated
member countries of the Organization for Economic Cooperation
and Development (OECD), as defined in Section 722.158(a)(1),
for the purpose of recovery is subject to the requirements of 35
Ill. Adm. Code 722.Subpart H if it is subject to either the
hazardous waste manifesting requirements of 35 Ill. Adm. Code
722 or the universal waste management standards of 35 Ill. Adm.
Code 733.
b)
Generators and transporters of recyclable materials are subject to the
applicable requirements of 35 Ill. Adm. Code 722 and 723 and the
notification requirements under Section 3010 of the Resource
Conservation and Recovery Act, except as provided in subsection (a)
aboveof this Section.
c)
Storage and recycling:
1)
Owners or operators of facilities that store recyclable materials
before they are recycled are regulated under all applicable
provisions of 35 Ill. Adm. Code 702, 703, and 705;
724.Subparts A through L, AA, and BB, and CC; and
725.Subparts A through L, AA, and BB, and CC; 726; 728; and
the notification requirement under Section 3010 of the Resource
Conservation and Recovery Act, except as provided in subsection
(a) aboveof this Section. (The recycling process itself is exempt
from regulation, except as provided in subsection (d) belowof this
Section.)
2)
Owners or operators of facilities that recycle recyclable materials
without storing them before they are recycled are subject to the
following requirements, except as provided in subsection (a)
aboveof this Section:
A)
Notification requirements under Section 3010 of the
Resource Conservation and Recovery Act,
B)
35 Ill. Adm. Code 725.171 and 725.172 (dealing with the
use of the manifest and manifest discrepancies), and
79
C)
subsection (d) belowof this Section.
d)
Owners or operators of facilities required to have a RCRA permit
pursuant to 35 Ill. Adm. Code 703 with hazardous waste management
units that recycle hazardous wastes are subject to 35 Ill. Adm. Code
724.Subparts AA and BB and 725.Subparts AA and BB.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
SUBPART D: LISTS OF HAZARDOUS WASTE
Section 721.132
Hazardous Waste from Specific Sources
The following solid wastes are listed hazardous wastes from specific sources unless
they are excluded under 35 Ill. Adm. Code 720.120 and 720.122 and listed in Section
721.Appendix I.
EPA
Hazardous
Waste No.
Industry and Hazardous Waste
Hazard
Code
Wood Preservation:
K001
Bottom sediment sludge from the treatment of wastewaters from
wood preserving processes that use creosote or pentachloro-
phenol.
(T)
Inorganic Pigments:
K002
Wastewater treatment sludge from the production of chrome
yellow and orange pigments.
(T)
K003
Wastewater treatment sludge from the production of molybdate
orange pigments.
(T)
K004
Wastewater treatment sludge from the production of zinc yellow
pigments.
(T)
K005
Wastewater treatment sludge from the production of chrome
green pigments.
(T)
K006
Wastewater treatment sludge from the production of chrome
oxide green pigments (anhydrous and hydrated).
(T)
80
K007
Wastewater treatment sludge from the production of iron blue
pigments.
(T)
K008
Oven residue from the production of chrome oxide green
pigments.
(T)
Organic Chemicals:
K009
Distillation bottoms from the production of acetaldehyde from
ethylene.
(T)
K010
Distillation side cuts from the production of acetaldehyde from
ethylene.
(T)
K011
Bottom stream from the wastewater stripper in the production of
acrylonitrile.
(R,T)
K013
Bottom stream from the acetonitrile column in the production of
acrylonitrile.
(T)
K014
Bottoms from the acetonitrile purification column in the
production of acrylonitrile.
(T)
K015
Still bottoms from the distillation of benzyl chloride.
(T)
K016
Heavy ends or distillation residues from the production of
carbon tetrachloride.
(T)
K017
Heavy ends (still bottoms) from the purification column in the
production of epichlorohydrin.
(T)
K018
Heavy ends from the fractionation column in ethyl chloride
production.
(T)
K019
Heavy ends from the distillation of ethylene dichloride in
ethylene dichloride production.
(T)
K020
Heavy ends from the distillation of vinyl chloride in vinyl
chloride monomer production.
(T)
K021
Aqueous spent antimony catalyst waste from fluoromethanes
production.
(T)
K022
Distillation bottom tars from the production of phenol/acetone
(T)
81
from cumene.
K023
Distillation light ends from the production of phthalic anhydride
from naphthalene.
(T)
K024
Distillation bottoms from the production of phthalic anhydride
from naphthalene.
(T)
K093
Distillation light ends from the production of phthalic anhydride
from ortho-xylene.
(T)
K094
Distillation bottoms from the production of phthalic anhydride
from ortho-xylene.
(T)
K025
Distillation bottoms from the production of nitrobenzene by the
nitration of benzene.
(T)
K026
Stripping still tails from the production of methyl ethyl
pyridines.
(T)
K027
Centrifuge and distillation residues from toluene diisocyanate
production.
(R,T)
K028
Spent catalyst from the hydrochlorinator reactor in the
production of 1,1,1-trichloroethane.
(T)
K029
Waste from the product stream stripper in the production of
1,1,1-trichloroethane.
(T)
K095
Distillation bottoms from the production of 1,1,1-trichloro-
ethane.
(T)
K096
Heavy ends from the heavy ends column from the production of
1,1,1-trichloroethane.
(T)
K030
Column bottoms or heavy ends from the combined production
of trichloroethylene and perchloroethylene.
(T)
K083
Distillation bottoms from aniline production.
(T)
K103
Process residues from aniline extraction from the production of
aniline.
(T)
K104
Combined wastewater streams generated from
nitrobenzene/aniline production.
(T)
82
K085
Distillation or fractionation column bottoms
from the production of chlorobenzenes.
(T)
K105
Separated aqueous stream from the reactor product washing step
in the production of chlorobenzenes.
(T)
K107
Column bottoms from product separation from the production
of 1,1-dimethylhydrazine (UDMH) from carboxylic acid
hydrazides.
(C,T)
K108
Condensed column overheads from product separation and
condensed reactor vent gases from the production of 1,1-di-
methylhydrazine (UDMH) from carboxylic acid hydrazides.
(I,T)
K109
Spent filter cartridges from the product purification from the
production of 1,1-dimethylhydrazine (UDMH) from carboxylic
acid hydrazides.
(T)
K110
Condensed column overheads from intermediate separation from
the production of 1,1-dimethylhydrazine (UDMH) from
carboxylic acid hydrazides.
(T)
K111
Product wastewaters from the production of dinitrotoluene via
nitration of toluene.
(C,T)
K112
Reaction by-product water from the drying column in the
production of toluenediamine via hydrogenation of di-
nitrotoluene.
(T)
K113
Condensed liquid light ends from the purification of toluenedi-
amine in the production of toluenediamine via hydrogenation of
dinitrotoluene.
(T)
K114
Vicinals from the purification of toluene-diamine toluenedi-
amine in the production of toluenediamine via hydrogenation of
dinitrotoluene.
(T)
K115
Heavy ends from the purification of toluenediamine in the
production of toluenediamine via hydrogenation of di-
nitrotoluene.
(T)
K116
Organic condensate from the solvent recovery column in the
production of toluene diisocyanate via phosgenation of
toluenediamine.
(T)
83
K117
Wastewater from the reactor vent gas scrubber in the production
of ethylene dibromide via bromination of ethene.
(T)
K118
Spent adsorbent solids from purification of ethylene dibromide
in the production of ethylene dibromide via bromination of
ethene.
(T)
K136
Still bottoms from the purification of ethylene dibromide in the
production of ethylene dibromide via bromination of ethene.
(T)
K156
Organic waste (including heavy ends, still bottoms, light ends,
spent solvents, filtrates, and decantates) from the production of
carbamates and carbamoyl oximes. (This listing does not apply
to wastes generated from the manufacture of 3-iodo-2-propynyl
n-butylcarbamate.)
(T)
K157
Wastewaters (including scrubber waters, condenser waters,
washwaters, and separation waters) from the production of
carbamates and carbamoyl oximes. (This listing does not apply
to wastes generated from the manufacture of 3-iodo-2-propynyl
n-butylcarbamate.)
(T)
K158
Bag house dusts and filter/separation solids from the production
of carbamates and carbamoyl oximes. (This listing does not
apply to wastes generated from the manufacture of 3-iodo-2-
propynyl n-butylcarbamate.)
(T)
K159
Organics from the treatment of thiocarbamate wastes.
(T)
K160
Solids (including filter wastes, separation solids, and spent
catalysts) from the production of thiocarbamates and solids from
the treatment of thiocarbamate wastes.
(T)
K161
Purification solids (including filtration, evaporation, and
centrifugation solids), bag house dust and floor sweepings from
the production of dithiocarbamate acids and their salts. (This
listing does not include K125 or K126.)
(R,T)
Inorganic Chemicals:
K071
Brine purification muds from the mercury cell process in
chlorine production, where separately prepurified brine is not
used.
(T)
84
K073
Chlorinated hydrocarbon waste from the purification step of the
diaphragm cell process using graphite anodes in chlorine
production.
(T)
K106
Wastewater treatment sludge from the mercury cell process in
chlorine production.
(T)
Pesticides:
K031
By-product salts generated in the production of MSMA and
cacodylic acid.
(T)
K032
Wastewater treatment sludge from the production of chlordane.
(T)
K033
Wastewater and scrub water from the chlorination of
cyclopentadiene in the production of chlordane.
(T)
K034
Filter solids from the filtration of hexachlorocyclopentadiene in
the production of chlordane.
(T)
K097
Vacuum stripper discharge from the chlordane chlorinator in the
production of chlordane.
(T)
K035
Wastewater treatment sludges generated in the production of
creosote.
(T)
K036
Still bottoms from toluene reclamation distillation in the
production of disulfoton.
(T)
K037
Wastewater treatment sludges from the production of disulfoton.
(T)
K038
Wastewater from the washing and stripping of phorate
production.
(T)
K039
Filter cake from the filtration of diethylphosphorodithioic acid
in the production of phorate.
(T)
K040
Wastewater treatment sludge from the production of phorate.
(T)
K041
Wastewater treatment sludge from the production of toxaphene.
(T)
K098
Untreated process wastewater from the production of
toxaphene.
(T)
K042
Heavy ends or distillation residues from the distillation of tetra-
(T)
85
chlorobenzene in the production of 2,4,5-T.
K043
2,6-Dichlorophenol waste from the production of 2,4-D.
(T)
K099
Untreated wastewater from the production of 2,4-D.
(T)
K123
Process wastewater (including supernates, filtrates and
washwaters) from the production of ethylenebisdithiocarbamic
acid and its salts.
(T)
K124
Reactor vent scrubber water from the production of ethylenebis-
dithiocarbamic acid and its salts.
(C,T)
K125
Filtration, evaporation and centrifugation solids from the
production of ethylenebisdithiocarbamic acid and its salts.
(T)
K126
Baghouse dust and floor sweepings in milling and packaging
operations from the production or formulation of ethylenebisdi-
thiocarbamic acid and its salts.
(T)
K131
Wastewater from the reactor and spent sulfuric acid from the
acid dryer from the production of methyl bromide.
(C,T)
K132
Spent absorbent and wastewater separator solids from the
production of methyl bromide.
(T)
Explosives:
K044
Wastewater treatment sludges from the manufacturing and
processing of explosives.
(R)
K045
Spent carbon from the treatment of wastewater containing
explosives.
(R)
K046
Wastewater treatment sludges from the manufacturing,
formulation and loading of lead-based initiating compounds.
(T)
K047
Pink/red water from TNT operations.
(R)
Petroleum Refining:
K048
Dissolved air flotation (DAF) float from the petroleum refining
industry.
(T)
K049
Slop oil emulsion solids from the petroleum refining industry.
(T)
86
K050
Heat exchanger bundle cleaning sludge from the petroleum
refining industry.
(T)
K051
API separator sludge from the petroleum refining industry.
(T)
K052
Tank bottoms (leaded) from the petroleum refining industry.
(T)
Iron and Steel:
K061
Emission control dust/sludge from the primary production of
steel in electric furnaces.
(T)
K062
Spent pickle liquor generated by steel finishing operations of
facilities within the iron and steel industry (SIC Codes 331 and
332) (as defined in 35 Ill. Adm. Code 720.110).
(C,T)
Primary Copper:
K064
Acid plant blowdown slurry or sludge resulting from the
thickening of blowdown slurry from primary copper production.
(T)
Primary Lead:
K065
Surface impoundment solids contained in and dredged from
surface impoundments at primary lead smelting facilities.
(T)
Primary Zinc:
K066
Sludge from treatment of process wastewater or acid plant
blowdown from primary zinc production.
(T)
BOARD NOTE: This waste listing is the subject of a judicial
remand in American Mining Congress v. EPA, 907 F.2d 1179
(D.D.C. 1990). The Board intends that this listing not become
enforceable in Illinois until the first date upon which the Board
RCRA program becomes “not equivalent to the Federal
program”, within the meaning of Section 3006(b) of the RCRA
Act, 42 U.S.C. 6926(b), the Board RCRA rules become “less
stringent” than the USEPA rules, as this phrase is used in
Section 3009, 42 U.S.C. 6929, or the Board RCRA rules are
not “identical in substance” with the federal rules as that term is
intended by 415 ILCS 5/7.2 and 22.4 as a result of some action
by USEPA with regard to this listing in response to the
American Mining Congress remand.
87
Primary Aluminum:
K088
Spent potliners from primary aluminum reduction.
(T)
Ferroalloys:
K090
Emission control dust or sludge from ferrochromiumsilicon
production.
(T)
K091
Emission control dust or sludge from ferrochromium
production.
(T)
Secondary Lead:
K069
Emission control dust/sludge from secondary lead smelting.
(T)
BOARD NOTE: This listing is administratively stayed for
sludge generated from secondary acid scrubber systems. The
stay will remain in effect until this note is removed.
K100
Waste leaching solution from acid leaching of emission control
dust/sludge from secondary lead smelting.
(T)
Veterinary Pharmaceuticals:
K084
Wastewater treatment sludges generated during the production
of veterinary pharmaceuticals from arsenic or organo-arsenic
compounds.
(T)
K101
Distillation tar residues from the distillation of aniline-based
compounds in the production of veterinary pharmaceuticals
from arsenic or organoarsenic compounds.
(T)
K102
Residue from use of activated carbon for decolorization in the
production of veterinary pharmaceuticals from arsenic or
organo-arsenic compounds.
(T)
Ink Formulation:
K086
Solvent washes and sludges, caustic washes and sludges, or
water washes and sludges from cleaning tubs and equipment
used in the formulation of ink from pigments, driersdryers,
soaps and stabilizers containing chromium and lead.
(T)
Coking:
88
K060
Ammonia still lime sludge from coking operations.
(T)
K087
Decanter tank tar sludge from coking operations.
(T)
K141
Process residues from the recovery of coal tar, including, but
not limited to, collecting sump residues from the production of
coke from coal or the recovery of coke by-products produced
from coal. This listing does not include K087 (decanter tank tar
sludges from coking operations).
(T)
K142
Tar storage tank residues from the production of coke from coal
or from the recovery of coke by-products produced from coal.
(T)
K143
Process residues from the recovery of light oil, including, but
not limited to, those generated in stills, decanters, and wash oil
recovery units from the recovery of coke by-products produced
from coal.
(T)
K144
Wastewater sump residues from light oil refining, including, but
not limited to, intercepting or contamination sump sludges from
the recovery of coke by-products produced from coal.
(T)
K145
Residues from naphthalene collection and recovery operations
from the recovery of coke by-products produced from coal.
(T)
K147
Tar storage tank residues from coal tar refining.
(T)
K148
Residues from coal tar distillation, including but not limited to,
still bottoms.
(T)
K149
Distillation bottoms from the production of alpha- (or methyl-)
chlorinated toluenes, ring-chlorinated toluenes, benzoyl
chlorides, and compounds with mixtures of these functional
groups. (This waste does not include still bottoms from the
distillation of benzyl chloride.)
(T)
K150
Organic residuals, excluding spent carbon adsorbent, from the
spent chlorine gas and hydrochloric acid recovery processes
associated with the production of alpha- (or methyl-) chlorinated
toluenes, ring-chlorinated toluenes, benzoyl chlorides, and
compounds with mixtures of these functional groups.
(T)
K151
Wastewater treatment sludges, excluding neutralization and
biological sludges, generated during the treatment of
(T)
89
wastewaters from the production of alpha- (or methyl-)
chlorinated toluenes, ring-chlorinated toluenes, benzoyl
chlorides, and compounds with mixtures of these functional
groups.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 721.133
Discarded Commercial Chemical Products, Off-Specification
Species, Container Residues, and Spill Residues Thereof
The following materials or items are hazardous wastes if and when they are discarded
or intended to be discarded as described in Section 721.102(a)(2)(A), when they are
mixed with waste oil or used oil or other material and applied to the land for dust
suppression or road treatment, when they are otherwise applied to the land in lieu of
their original intended use or when they are contained in products that are applied to
land in lieu of their original intended use, or when, in lieu of their original intended
use, they are produced for use as (or as a component of) a fuel, distributed for use as a
fuel, or burned as a fuel.
a)
Any commercial chemical product, or manufacturing chemical
intermediate having the generic name listed in subsection (e) or (f)
belowof this Section.
b)
Any off-specification commercial chemical product or manufacturing
chemical intermediate which, if it met specifications, would have the
generic name listed in subsection (e) or (f) belowof this Section.
c)
Any residue remaining in a container or inner liner removed from a
container that has held any commercial chemical product or
manufacturing chemical intermediate having the generic name listed in
subsection (e) or (f) belowof this Section, unless the container is empty
as defined in Section 721.107(b)(3).
BOARD NOTE: Unless the residue is being beneficially used or reused,
or legitimately recycled or reclaimed, or being accumulated, stored,
transported, or treated prior to such use, reuse, recycling, or
reclamation, the Board considers the residue to be intended for discard,
and thus a hazardous waste. An example of a legitimate reuse of the
residue would be where the residue remains in the container and the
container is used to hold the same commercial chemical product or
manufacturing chemical intermediate it previously held. An example of
the discard of the residue would be where the drum is sent to a drum
reconditioner that reconditions the drum but discards the residue.
90
d)
Any residue or contaminated soil, water, or other debris resulting from
the cleanup of a spill into or on any land or water of any commercial
chemical product or manufacturing chemical intermediate having the
generic name listed in subsection (e) or (f) belowof this Section, or any
residue or contaminated soil, water, or other debris resulting from the
cleanup of a spill into or on any land or water, of any off-specification
chemical product or manufacturing chemical intermediate which, if it
met specifications, would have the generic name listed in subsection (e)
or (f) belowof this Section.
BOARD NOTE: The phrase “commercial chemical product or
manufacturing chemical intermediate having the generic name listed in
...” refers to a chemical substance that is manufactured or formulated for
commercial or manufacturing use which consists of the commercially
pure grade of the chemical, any technical grades of the chemical that are
produced or marketed, and all formulations in which the chemical is the
sole active ingredient. It does not refer to a material, such as a
manufacturing process waste, that contains any of the substances listed in
subsection (e) or (f) belowof this Section. Where a manufacturing
process waste is deemed to be a hazardous waste because it contains a
substance listed in subsection (e) or (f) belowof this Section, such waste
will be listed in either Sections 721.131 or 721.132 or will be identified
as a hazardous waste by the characteristics set forth in Subpart C.
e)
The commercial chemical products, manufacturing chemical
intermediates, or off-specification commercial chemical products or
manufacturing chemical intermediates referred to in subsections (a)
through (d) aboveof this Section, are identified as acute hazardous waste
(H) and are subject to the small quantity exclusion defined in Section
721.105(e). These wastes and their corresponding USEPA Hazardous
Waste Numbers are:
BOARD NOTE: For the convenience of the regulated community the
primary hazardous properties of these materials have been indicated by
the letters T (Toxicity), and R (Reactivity). The absence of a letter
indicates that the compound only is listed for acute toxicity.
Hazardous
Waste No.
Chemical
Abstracts No.
Substance
P023
107-20-0
Acetaldehyde, chloro-
P002
591-08-2
Acetamide, N-(aminothioxomethyl)
P057
640-19-7
Acetamide, 2-fluoro-
P058
62-74-8
Acetic acid, fluoro-, sodium salt
91
P002
591-08-2
1-Acetyl-2-thiourea
P003
107-02-8
Acrolein
P070
116-06-3
Aldicarb
P203
1646-88-4
Aldicarb sulfone
P004
309-00-2
Aldrin
P005
107-18-6
Allyl alcohol
P006
20859-73-8
Aluminum phosphide (R,T)
P007
2763-96-4
5-(Aminomethyl)-3-isoxazolol
P008
504-24-5
4-Aminopyridine
P009
131-74-8
Ammonium picrate (R)
P119
7803-55-6
Ammonium vanadate
P099
506-61-6
Argentate(1-), bis(cyano-C)-, potassium
P010
7778-39-4
Arsenic acid H
3
AsO
4
P012
1327-53-3
Arsenic oxide As
2
O
3
P011
1303-28-2
Arsenic oxide As
2
O
5
P011
1303-28-2
Arsenic pentoxide
P012
1327-53-3
Arsenic trioxide
P038
692-42-2
Arsine, diethyl-
P036
696-28-6
Arsonous dichloride, phenyl-
P054
151-56-4
Aziridine
P067
75-55-8
Aziridine, 2-methyl
P013
542-62-1
Barium cyanide
P024
106-47-8
Benzenamine, 4-chloro-
P077
100-01-6
Benzenamine, 4-nitro-
P028
100-44-7
Benzene, (chloromethyl)-
P042
51-43-4
1,2-Benzenediol, 4-[1-hydroxy-2-(methyl-
amino)ethyl]-, (R)-
P046
122-09-8
Benzeneethanamine, alpha,alpha-dimethyl-
P014
108-98-5
Benzenethiol
P127
1563-66-2
7-Benzofuranol, 2,3-dihydro-2,2-dimethyl-,
methylcarbamate
P188
57-64-7
Benzoic acid, 2-hydroxy-, compound with (3aS-
cis)-1,2,3,3a,8,8a-hexahydro-1,3a,8-trimethyl-
pyrrolo[2,3-b]indol-5-yl methylcarbamate ester
(1:1)
P001
81-81-2
*
2H-1-Benzopyran-2-one, 4-hydroxy-3-(3-oxo-1-
phenylbutyl)-, and salts, when present at
concentrations greater than 0.3%
P028
100-44-7
Benzyl chloride
P015
7440-41-7
Beryllium powder
P017
598-31-2
Bromoacetone
P018
357-57-3
Brucine
P045
39196-18-6
2-Butanone,3,3-dimethyl-1-(methylthio)-, O-
[methylamino)carbonyl] oxime
P021
592-01-8
Calcium cyanide
92
P021
592-01-8
Calcium cyanide Ca(CN)
2
P189
55285-14-8
Carbamic acid, [(dibutylamino)- thio]methyl-,
2,3-dihydro-2,2-dimethyl-7-benzofuranyl ester
P191
644-64-4
Carbamic acid, dimethyl-, 1-[(dimethyl-amino)-
carbonyl]-5-methyl-1H-pyrazol-3-yl ester
P192
119-38-0
Carbamic acid, dimethyl-, 3-methyl-1-(1-
methylethyl)-1H-pyrazol-5-yl ester
P190
1129-41-5
Carbamic acid, methyl-, 3-methylphenyl ester
P127
1563-66-2
Carbofuran
P022
75-15-0
Carbon disulfide
P095
75-44-5
Carbonic dichloride
P189
55285-14-8
Carbosulfan
P023
107-20-0
Chloroacetaldehyde
P024
106-47-8
p-Chloroaniline
P026
5344-82-1
1-(o-Chlorophenyl)thiourea
P027
542-76-7
3-Chloropropionitrile
P029
544-92-3
Copper cyanide
P029
544-92-3
Copper cyanide CuCN
P202
64-00-6
m-Cumenyl methylcarbamate
P030
Cyanides (soluble cyanide salts), not otherwise
specified
P031
460-19-5
Cyanogen
P033
506-77-4
Cyanogen chloride
P033
506-77-4
Cyanogen chloride CNCl
P034
131-89-5
2-Cyclohexyl-4,6-dinitrophenol
P016
542-88-1
Dichloromethyl ether
P036
696-28-6
Dichlorophenylarsine
P037
60-57-1
Dieldrin
P038
692-42-2
Diethylarsine
P041
311-45-5
Diethyl-p-nitrophenyl phosphate
P040
297-97-2
O,O-Diethyl O-pyrazinyl phosphorothioate
P043
55-91-4
Diisopropylfluorophosphate (DFP)
P191
644-64-4
Dimetilan
P004
309-00-2
1,4,5,8-Dimethanonaphthalene, 1,2,3,4,10,10-
hexachloro-1,4,4a,5,8,8a-hexahydro-,
(1alpha,4alpha,4abeta,5alpha,8alpha,8abeta)-
P060
465-73-6
1,4,5,8-Di-methanonaphthalene, 1,2,3,4,10,10-
hexachloro-1,4,4a,5,8,8a-hexahydro-,
(1alpha,4alpha,4abeta,5beta,8beta,8abeta)-
P037
60-57-1
2,7:3,6-Dimethanonaphth[2,3-b]oxirene,
3,4,5,6,9,9-hexachloro-1a,2,2a,3,6,6a,7,7a-
octahydro-,
(1aalpha,2beta,2aalpha,3beta,6beta,6aalpha,7be
ta,7aalpha)-
P051
72-20-8
*
2,7:3,6-Dimethanonaphth[2,3-b]oxirene,
93
3,4,5,6,9,9-hexachloro-1a,2,2a,3,6,6a,7,7a-
octahydro-,
(1aalpha,2beta,2abeta,3alpha,6alpha,6abeta,7be
ta,7aalpha)-, and metabolites
P044
60-51-5
Dimethoate
P046
122-09-8
alpha,alpha-Dimethylphenethylamine
P047
534-52-1
*
4,6-Dinitro-o-cresol and salts
P048
51-28-5
2,4-Dinitrophenol
P020
88-85-7
Dinoseb
P085
152-16-9
Diphosphoramide, octamethyl-
P111
107-49-3
Diphosphoric acid, tetraethyl ester
P039
298-04-4
Disulfoton
P049
541-53-7
Dithiobiuret
P185
26419-73-8
1,3-Dithiolane-2-carboxaldehyde, 2,4-dimethyl-
, O-[(methylamino)- carbonyl]oxime
P050
115-29-7
Endosulfan
P088
145-73-3
Endothall
P051
72-20-8
Endrin
P051
72-20-8
Endrin, and metabolites
P042
51-43-4
Epinephrine
P031
460-19-5
Ethanedinitrile
P194
23135-22-0
Ethanimidothioc acid, 2-(dimethylamino)-N-
[[(methylamino)carbonyl]oxy]-2-oxo-, methyl
ester
P066
16752-77-5
Ethanimidothioic acid, N-[[(methylamino)-
carbonyl]oxy]-, methyl ester
P101
107-12-0
Ethyl cyanide
P054
151-56-4
Ethylenimine
P097
52-85-7
Famphur
P056
7782-41-4
Fluorine
P057
640-19-7
Fluoroacetamide
P058
62-74-8
Fluoroacetic acid, sodium salt
P198
23422-53-9
Formetanate hydrochloride
P197
17702-57-7
Formparanate
P065
628-86-4
Fulminic acid, mercury (2+) salt (R,T)
P059
76-44-8
Heptachlor
P062
757-58-4
Hexaethyl tetraphosphate
P116
79-19-6
Hydrazinecarbothioamide
P068
60-34-4
Hydrazine, methyl-
P063
74-90-8
Hydrocyanic acid
P063
74-90-8
Hydrogen cyanide
P096
7803-51-2
Hydrogen phosphide
P060
465-73-6
Isodrin
P192
119-38-0
Isolan
P202
64-00-6
3-Isopropylphenyl-N-methylcarbamate
94
P007
2763-96-4
3(2H)-Isoxazolone, 5-(aminomethyl)-
P196
15339-36-3
Manganese, bis(dimethylcarbamodithioato-
S,S')-
P196
15339-36-3
Manganese dimethyldithiocarbamate
P092
62-38-4
Mercury, (acetato-O)phenyl-
P065
628-86-4
Mercury fulminate (R,T)
P082
62-75-9
Methanamine, N-methyl-N-nitroso-
P064
624-83-9
Methane, isocyanato-
P016
542-88-1
Methane, oxybis[chloro-
P112
509-14-8
Methane, tetranitro- (R)
P118
75-70-7
Methanethiol, trichloro-
P198
23422-53-9
Methanimidamide, N,N-dimethyl-N'-[3-
[[(methylamino)-carbonyl]oxy]phenyl]-,
monohydrochloride
P197
17702-57-7
Methanimidamide, N,N-dimethyl-N'-[2-methyl-
4-[[(methylamino)carbonyl]oxy]phenyl]-
P199
2032-65-7
Methiocarb
P050
115-29-7
6,9-Methano-2,4,3-benzodioxathiepen,
6,7,8,9,10,10-hexachloro-1,5,5a,6,9,9a-hexa-
hydro-, 3-oxide
P059
76-44-8
4,7-Methano-1H-indene, 1,4,5,6,7,8,8-hepta-
chloro-3a,4,7,7a-tetrahydro-
P066
16752-77-5
Methomyl
P068
60-34-4
Methyl hydrazine
P064
624-83-9
Methyl isocyanate
P069
75-86-5
2-Methyllactonitrile
P071
298-00-0
Methyl parathion
P190
1129-41-5
Metolcarb
P129
315-8-4
Mexacarbate
P072
86-88-4
alpha-Naphthylthiourea
P073
13463-39-3
Nickel carbonyl
P073
13463-39-3
Nickel carbonyl Ni(CO)
4
, (T-4)-
P074
557-19-7
Nickel cyanide
P074
557-19-7
Nickel cyanide Ni(CN)
2
P075
54-11-5
*
Nicotine, and salts
P076
10102-43-9
Nitric oxide
P077
100-01-6
p-Nitroaniline
P078
10102-44-0
Nitrogen dioxide
P076
10102-43-9
Nitrogen oxide NO
P078
10102-44-0
Nitrogen oxide NO
2
P081
55-63-0
Nitroglycerine (R)
P082
62-75-9
N-Nitrosodimethylamine
P084
4549-40-0
N-Nitrosomethylvinylamine
P085
152-16-9
Octamethylpyrophosphoramide
P087
20816-12-0
Osmium oxide OsO
4
, (T-4)-
95
P087
20816-12-0
Osmium tetroxide
P088
145-73-3
7-Oxabicyclo[2.2.1]heptane-2,3-dicarboxylic
acid
P194
23135-22-0
Oxamyl
P089
56-38-2
Parathion
P034
131-89-5
Phenol, 2-cyclohexyl-4,6-dinitro-
P128
315-18-4
Phenol, 4-(dimethylamino)-3,5-dimethyl-,
methylcarbamate (ester)
P199
2032-65-7
Phenol, (3,5-dimethyl-4-(methylthio)-, methyl-
carbamate
P048
51-28-5
Phenol, 2,4-dinitro-
P047
534-52-1
*
Phenol, 2-methyl-4,6-dinitro-, and salts
P202
64-00-6
Phenol, 3-(1-methylethyl)-, methyl carbamate
P201
2631-37-0
Phenol, 3-methyl-5-(1-methylethyl)-, methyl
carbamate
P020
88-85-7
Phenol, 2-(1-methylpropyl)-4,6-dinitro-
P009
131-74-8
Phenol, 2,4,6-trinitro-, ammonium salt (R)
P092
62-38-4
Phenylmercury acetate
P093
103-85-5
Phenylthiourea
P094
298-02-2
Phorate
P095
75-44-5
Phosgene
P096
7803-51-2
Phosphine
P041
311-45-5
Phosphoric acid, diethyl 4-nitrophenyl ester
P039
298-04-4
Phosphorodithioic acid, O,O-diethyl S-[2-
(ethylthio)ethyl] ester
P094
298-02-2
Phosphorodithioic acid, O,O-diethyl S-[(ethyl-
thio)methyl] ester
P044
60-51-5
Phosphorodithioic acid, O,O-dimethyl S-[2-
(methylamino)-2-oxoethyl]ester
P043
55-91-4
Phosphorofluoridic acid, bis(1-methylethyl)ester
P089
56-38-2
Phosphorothioic acid, O,O-diethyl O-(4-
nitrophenyl) ester
P040
297-97-2
Phosphorothioic acid, O,O-diethyl O-pyrazinyl
ester
P097
52-85-7
Phosphorothioic acid, O-[4-[(dimethylamino)-
sulfonyl)]phenyl] O,O-dimethyl ester
P071
298-00-0
Phosphorothioic acid, O,O-dimethyl O-(4-
nitrophenyl) ester
P204
57-47-6
Physostigmine
P188
57-64-7
Physostigmine salicylate
P110
78-00-2
Plumbane, tetraethyl-
P098
151-50-8
Potassium cyanide
P098
151-50-8
Potassium cyanide KCN
P099
506-61-6
Potassium silver cyanide
P201
2631-37-0
Promecarb
96
P203
1646-88-4
Propanal, 2-methyl-2-(methyl-sulfonyl)-, O-
[(methylamino)carbonyl] oxime
P070
116-06-3
Propanal, 2-methyl-2-(methylthio)-, O-
[(methylamino)carbonyl]oxime
P101
107-12-0
Propanenitrile
P027
542-76-7
Propanenitrile, 3-chloro-
P069
75-86-5
Propanenitrile, 2-hydroxy-2-methyl-
P081
55-63-0
1,2,3-Propanetriol, trinitrate- (R)
P017
598-31-2
2-Propanone, 1-bromo-
P102
107-19-7
Propargyl alcohol
P003
107-02-8
2-Propenal
P005
107-18-6
2-Propen-1-ol
P067
75-55-8
1,2-Propylenimine
P102
107-19-7
2-Propyn-1-ol
P008
504-24-5
4-Pyridinamine
P075
54-11-5
*
Pyridine, 3-(1-methyl-2-pyrrolidinyl)-, (S)- and
salts
P204
57-47-6
Pyrrolo[2,3-b]indol-5-ol, 1,2,3,3a,8,8a-hexa-
hydro-1,3a,8-trimethyl-, methylcarbamate
(ester), (3aS-cis)-
P114
12039-52-0
Selenious acid, dithallium (1+) salt
P103
630-10-4
Selenourea
P104
506-64-9
Silver cyanide
P104
506-64-9
Silver cyanide AgCN
P105
26628-22-8
Sodium azide
P106
143-33-9
Sodium cyanide
P106
143-33-9
Sodium cyanide NaCN
P108
57-24-9
*
Strychnidin-10-one, and salts
P018
357-57-3
Strychnidin-10-one, 2,3-dimethoxy-
P108
57-24-9
*
Strychnine and salts
P115
7446-18-6
Sulfuric acid, dithallium (1+) salt
P109
3689-24-5
Tetraethyldithiopyrophosphate
P110
78-00-2
Tetraethyl lead
P111
107-49-3
Tetraethylpyrophosphate
P112
509-14-8
Tetranitromethane (R)
P062
757-58-4
Tetraphosphoric acid, hexaethyl ester
P113
1314-32-5
Thallic oxide
P113
1314-32-5
Thallium oxide Tl
2
O
3
P114
12039-52-0
Thallium (I) selenite
P115
7446-18-6
Thallium (I) sulfate
P109
3689-24-5
Thiodiphosphoric acid, tetraethyl ester
P045
39196-18-4
Thiofanox
P049
541-53-7
Thioimidodicarbonic diamide [(H
2
N)C(S)]
2
NH
P014
108-98-5
Thiophenol
P116
79-19-6
Thiosemicarbazide
97
P026
5344-82-1
Thiourea, (2-chlorophenyl)-
P072
86-88-4
Thiourea, 1-naphthalenyl-
P093
103-85-5
Thiourea, phenyl-
P123
8001-35-2
Toxaphene
P185
26419-73-8
Tirpate
P118
75-70-7
Trichloromethanethiol
P119
7803-55-6
Vanadic acid, ammonium salt
P120
1314-62-1
Vanadium oxide V
2
O
5
P120
1314-62-1
Vanadium pentoxide
P084
4549-40-0
Vinylamine, N-methyl-N-nitroso-
P001
81-81-2
*
Warfarin, and salts, when present at
concentrations greater than 0.3%
P121
557-21-1
Zinc cyanide
P121
557-21-1
Zinc cyanide Zn(CN)
2
P205
137-30-4
Zinc, bis(dimethylcarbamodithioato-S,S')-
P122
1314-84-7
Zinc phosphide Zn
3
P
2
, when present at
concentrations greater than 10% (R,T)
P205
137-30-4
Ziram
BOARD NOTE: An asterisk (*) following the CAS number indicates
that the CAS number is given for the parent compound only.
f)
The commercial chemical products, manufacturing chemical
intermediates, or off-specification commercial chemical products
referred to in subsections (a) through (d) aboveof this Section, are
identified as toxic wastes (T) unless otherwise designated and are subject
to the small quantity exclusion defined in Section 721.105(a) and (g).
These wastes and their corresponding USEPA Hazardous Waste
Numbers are:
BOARD NOTE: For the convenience of the regulated community, the
primary hazardous properties of these materials have been indicated by
the letters T (Toxicity), R (Reactivity), I (Ignitability), and C
(Corrosivity). The absence of a letter indicates that the compound is
only listed for toxicity.
Hazardous
Waste No.
Chemical
Abstracts No.
Substance
U394
30558-43-1
A2213
U365
2212-67-1
H-Azepine-1-carbothioic acid, hexahydro-, S-
ethyl ester
U001
75-07-0
Acetaldehyde (I)
U034
75-87-6
Acetaldehyde, trichloro-
98
U187
62-44-2
Acetamide, N-(4-ethoxyphenyl)-
U005
53-96-3
Acetamide, N-9H-fluoren-2-yl-
U240
P 94-75-7
Acetic acid, (2,4-dichlorophenoxy)-, salts and
esters
U112
141-78-6
Acetic acid, ethyl ester (I)
U144
301-04-2
Acetic acid, lead (2+) salt
U214
563-68-8
Acetic acid, thallium (1+) salt
See F027
93-76-5
Acetic acid, (2,4,5-trichlorophenoxy)-
UOO2
67-64-1
Acetone (I)
UOO3
75-05-8
Acetonitrile (I,T)
U004
98-86-2
Acetophenone
U005
53-96-3
2-Acetylaminofluorene
U006
75-36-5
Acetyl chloride (C,R,T)
U007
79-06-1
Acrylamide
U008
79-10-7
Acrylic acid (I)
U009
107-13-1
Acrylonitrile
U011
61-82-5
Amitrole
U012
62-53-3
Aniline (I,T)
U136
75-60-5
Arsinic acid, dimethyl-
U014
492-80-8
Auramine
U015
115-02-6
Azaserine
U010
50-07-7
Azirino[2',3':3,4]pyrrolo[1,2-a]indole-4,7-di-
one, 6-amino-8-[[(aminocarbonyl)oxy]methyl]-
1,1a,2,8,8a,8b-hexahydro-8a-methoxy-5-
methyl-, [1a-S-
(1aalpha,8beta,8aalpha,8balpha)]-
U280
101-27-9
Barban
U278
22781-23-3
Bendiocarb
U364
22961-82-6
Bendiocarb phenol
U271
17804-35-2
Benomyl
U157
56-49-5
Benz[j]aceanthrylene, 1,2-dihydro-3-methyl-
U016
225-51-4
Benz(c)acridine
U017
98-87-3
Benzal chloride
U192
23950-58-5
Benzamide, 3,5-dichloro-N-(1,1-dimethyl-2-
propynyl)-
U018
56-55-3
Benz[a]anthracene
U094
57-97-6
Benz[a]anthracene, 7,12-dimethyl-
U012
62-53-3
Benzenamine (I,T)
U014
492-80-8
Benzenamine, 4,4'-carbonimidoylbis[N,N-di-
methyl-
U049
3165-93-3
Benzenamine, 4-chloro-2-methyl-,
hydrochloride
U093
60-11-7
Benzenamine, N,N-dimethyl-4-(phenylazo)-
U328
95-53-4
Benzenamine, 2-methyl-
U353
106-49-0
Benzenamine, 4-methyl-
99
U158
101-14-4
Benzenamine, 4,4'-methylenebis[2-chloro-
U222
636-21-5
Benzenamine, 2-methyl-, hydrochloride
U181
99-55-8
Benzenamine, 2-methyl-5-nitro-
U019
71-43-2
Benzene (I,T)
U038
510-15-6
Benzeneacetic acid, 4-chloro-alpha-(4-chloro-
phenyl)-alpha-hydroxy-, ethyl ester
U030
101-55-3
Benzene, 1-bromo-4-phenoxy-
U035
305-03-3
Benzenebutanoic acid, 4-[bis(2-chloroethyl)-
amino]-
U037
108-90-7
Benzene, chloro-
U221
25376-45-8
Benzenediamine, ar-methyl-
U028
117-81-7
1,2-Benzenedicarboxylic acid, bis(2-ethylhexyl)
ester
U069
84-74-2
1,2-Benzenedicarboxylic acid, dibutyl ester
U088
84-66-2
1,2-Benzenedicarboxylic acid, diethyl ester
U102
131-11-3
1,2-Benzenedicarboxylic acid, dimethyl ester
U107
117-84-0
1,2-Benzenedicarboxylic acid, dioctyl ester
U070
95-50-1
Benzene, 1,2-dichloro-
U071
541-73-1
Benzene, 1,3-dichloro-
U072
106-46-7
Benzene, 1,4-dichloro-
U060
72-54-8
Benzene, 1,1'-(2,2-dichloroethylidene)bis[4-
chloro-
U017
98-87-3
Benzene, (dichloromethyl)-
U223
26471-62-5
Benzene, 1,3-diisocyanatomethyl- (R,T)
U239
1330-20-7
Benzene, dimethyl- (I,T)
U201
108-46-3
1,3-Benzenediol
U127
118-74-1
Benzene, hexachloro-
U056
110-82-7
Benzene, hexahydro- (I)
U220
108-88-3
Benzene, methyl-
U105
121-14-2
Benzene, 1-methyl-2,4-dinitro-
U106
606-20-2
Benzene, 2-methyl-1,3-dinitro-
U055
98-82-8
Benzene, (1-methylethyl)- (I)
U169
98-95-3
Benzene, nitro-
U183
608-93-5
Benzene, pentachloro-
U185
82-68-8
Benzene, pentachloronitro-
U020
98-09-9
Benzenesulfonic acid chloride (C,R)
U020
98-09-9
Benzenesulfonyl chloride (C,R)
U207
95-94-3
Benzene, 1,2,4,5-tetrachloro-
U061
50-29-3
Benzene, 1,1'-(2,2,2-trichloroethylidene)bis[4-
chloro-
U247
72-43-5
Benzene, 1,1'-(2,2,2-trichloroethylidene)bis[4-
methoxy-
U023
98-07-7
Benzene, (trichloromethyl)-
U234
99-35-4
Benzene, 1,3,5-trinitro-
U021
92-87-5
Benzidene
100
U202
P 81-07-2
1,2-Benzisothiazol-3(2H)-one, 1,1-dioxide, and
salts
U203
94-59-7
1,3-Benzodioxole, 5-(2-propenyl)-
U141
120-58-1
1,3-Benzodioxole, 5-(1-propenyl)-
U090
94-58-6
1,3-Benzodioxole, 5-propyl-
U278
22781-23-3
1,3-Benzodioxol-4-ol, 2,2-dimethyl-, methyl
carbamate
U364
22961-82-6
1,3-Benzodioxol-4-ol, 2,2-dimethyl-
U367
1563-38-8
7-Benzofuranol, 2,3-dihydro-2,2-dimethyl-
U064
189-55-9
Benzo[rst]pentaphene
U248
P 81-81-2
2H-1-Benzopyran-2-one, 4-hydroxy-3-(3-oxo-1-
phenylbutyl)-, and salts, when present at
concentrations of 0.3% or less
U022
50-32-8
Benzo[a]pyrene
U197
106-51-4
p-Benzoquinone
U023
98-07-7
Benzotrichloride (C,R,T)
U085
1464-53-5
2,2'-Bioxirane
U021
92-87-5
[1,1'-Biphenyl]-4,4'-diamine
U073
91-94-1
[1,1'-Biphenyl]-4,4'-diamine, 3,3'-dichloro-
U091
119-90-4
[1,1'-Biphenyl]-4,4'-diamine, 3,3'-dimethoxy-
U095
119-93-7
[1,1'-Biphenyl]-4,4'-diamine, 3,3'-dimethyl-
U401
97-74-5
Bis(dimethylthiocarbamoyl) sulfide
U400
120-54-7
Bis(pentamethylene)thiuram tetrasulfide
U225
75-25-2
Bromoform
U030
101-55-3
4-Bromophenyl phenyl ether
U128
87-68-3
1,3-Butadiene, 1,1,2,3,4,4-hexachloro-
U172
924-16-3
1-Butanamine, N-butyl-N-nitroso-
U031
71-36-3
1-Butanol (I)
U159
78-93-3
2-Butanone (I,T)
U160
1338-23-4
2-Butanone, peroxide (R,T)
U053
4170-30-3
2-Butenal
U074
764-41-0
2-Butene, 1,4-dichloro- (I,T)
U143
303-34-4
2-Butenoic acid, 2-methyl-, 7-[[2,3-dihydroxy-
2-(1-methoxyethyl)-3-methyl-1-oxobutoxy]-
methyl]-2,3,5,7a-tetrahydro-1H-pyrrolizin-1-yl
ester, [1S-[1alpha(Z), 7(2S*,3R*), 7aalpha]]-
U031
71-36-3
n-Butyl alcohol (I)
U392
2008-41-5
Butylate
U136
75-60-5
Cacodylic acid
U032
13765-19-0
Calcium chromate
U372
10605-21-7
Carbamic acid, 1H-benzimidazol-2-yl, methyl
ester
U271
17804-35-2
Carbamic acid, [1-[(butylamino)carbonyl]-1H-
benzimidazol-2-yl]-, methyl ester
U375
55406-53-6
Carbamic acid, butyl-, 3-iodo-2-propynyl ester
101
U280
101-27-9
Carbamic acid, (3-chlorophenyl)-, 4-chloro-2-
butynyl ester
U238
51-79-6
Carbamic acid, ethyl ester
U178
615-53-2
Carbamic acid, methylnitroso-, ethyl ester
U373
122-42-9
Carbamic acid, phenyl-, 1-methylethyl ester
U409
23564-05-8
Carbamic acid, [1,2-phenylenebis(imino-
carbonothioyl)]bis-, dimethyl ester
U097
79-44-7
Carbamic chloride, dimethyl-
U379
136-30-1
Carbamodithioic acid, dibutyl, sodium salt
U277
95-06-7
Carbamodithioic acid, diethyl-, 2-chloro-2-
propenyl ester
U381
148-18-5
Carbamodithioic acid, diethyl-, sodium salt
U383
128-03-0
Carbamodithioic acid, dimethyl, potassium salt
U382
128-04-1
Carbamodithioic acid, dimethyl-, sodium salt
U376
144-34-3
Carbamodithioic acid, dimethyl-, tetraanhydro-
sulfide with orthothioselenious acid
U114
P 111-54-6
Carbamodithioic acid, 1,2-ethanediylbis-, salts
and esters
U378
51026-28-9
Carbamodithioic acid, (hydroxymethyl)methyl-,
monopotassium salt
U384
137-42-8
Carbamodithioic acid, methyl-, monosodium
salt
U377
137-41-7
Carbamodithioic acid, methyl,- monopotassium
salt
U062
2303-16-4
Carbamothioic acid, bis(1-methylethyl)-, S-
(2,3-dichloro-2-propenyl) ester
U389
2303-17-5
Carbamothioic acid, bis(1-methylethyl)-, S-
(2,3,3-trichloro-2-propenyl) ester
U392
2008-41-5
Carbamothioic acid, bis(2-methylpropyl)-, S-
ethyl ester
U391
1114-71-2
Carbamothioic acid, butylethyl-, S-propyl ester
U386
1134-23-2
Carbamothioic acid, cyclohexylethyl-, S-ethyl
ester
U390
759-94-4
Carbamothioic acid, dipropyl-, S-ethyl ester
U387
52888-80-9
Carbamothioic acid, dipropyl-, S-(phenyl-
methyl) ester
U385
1929-77-7
Carbamothioic acid, dipropyl-, S-propyl ester
U279
63-25-2
Carbaryl
U372
10605-21-7
Carbendazim
U367
1563-38-8
Carbofuran phenol
U215
6533-73-9
Carbonic acid, dithallium (1+) salt
U033
353-50-4
Carbonic difluoride
U156
79-22-1
Carbonochloridic acid, methyl ester (I,T)
U033
353-50-4
Carbon oxyfluoride (R,T)
U211
56-23-5
Carbon tetrachloride
102
U034
75-87-6
Chloral
U035
305-03-3
Chlorambucil
U036
57-74-9
Chlordanealpha and gamma isomers
U026
494-03-1
Chlornaphazin
U037
108-90-7
Chlorobenzene
U038
510-15-6
Chlorobenzilate
U039
59-50-7
p-Chloro-m-cresol
U042
110-75-8
2-Chloroethyl vinyl ether
U044
67-66-3
Chloroform
U046
107-30-2
Chloromethyl methyl ether
U047
91-58-7
beta-Chloronaphthalene
U048
95-57-8
o-Chlorophenol
U049
3165-93-3
4-Chloro-o-toluidine, hydrochloride
U032
13765-19-0
Chromic acid H
2
CrO
4
, calcium salt
U050
218-01-9
Chrysene
U393
137-29-1
Copper, bis(dimethylcarbamodithioato-S,S')-
U393
137-29-1
Copper dimethyldithiocarbamate
U051
Creosote
U052
1319-77-3
Cresol (Cresylic acid)
U053
4170-30-3
Crotonaldehyde
U055
98-82-8
Cumeme (I)
U246
506-68-3
Cyanogen bromide CNBr
U386
1134-23-2
Cycloate
U197
106-51-4
2,5-Cyclohexadiene-1,4-dione
U056
110-82-7
Cyclohexane (I)
U129
58-89-9
Cyclohexane, 1,2,3,4,5,6-hexachloro-,
(1alpha,2alpha,3beta,4alpha,5alpha,6beta)-
U057
108-94-1
Cyclohexanone (I)
U130
77-47-4
1,3-Cyclopentadiene, 1,2,3,4,5,5-hexachloro-
U058
50-18-0
Cyclophosphamide
U240
P 94-75-7
2,4-D, salts and esters
U059
20830-81-3
Daunomycin
U366
533-74-4
Dazomet
U060
72-54-8
DDD
U061
50-29-3
DDT
U062
2303-16-4
Diallate
U063
53-70-3
Dibenz[a,h]anthracene
U064
189-55-9
Dibenzo[a,i]pyrene
U066
96-12-8
1,2-Dibromo-3-chloropropane
U069
84-74-2
Dibutyl phthalate
U070
95-50-1
o-Dichlorobenzene
U071
541-73-1
m-Dichlorobenzene
U072
106-46-7
p-Dichlorobenzene
U073
91-94-1
3,3'-Dichlorobenzidine
U074
764-41-0
1,4-Dichloro-2-butene (I,T)
103
U075
75-71-8
Dichlorodifluoromethane
U078
75-35-4
1,1-Dichloroethylene
U079
156-60-5
1,2-Dichloroethylene
U025
111-44-4
Dichloroethyl ether
U027
108-60-1
Dichloroisopropyl ether
U024
111-91-1
Dichloromethoxy ethane
U081
120-83-2
2,4-Dichlorophenol
U082
87-65-0
2,6-Dichlorophenol
U084
542-75-6
1,3-Dichloropropene
U085
1464-53-5
1,2:3,4-Diepoxybutane (I,T)
U395
5952-26-1
Diethylene glycol, dicarbamate
U108
123-91-1
1,4-Diethyleneoxide
U028
117-81-7
Diethylhexyl phthalate
U086
1615-80-1
N,N'-Diethylhydrazine
U087
3288-58-2
O,O-Diethyl S-methyl dithiophosphate
U088
84-66-2
Diethyl phthalate
U089
56-53-1
Diethylstilbestrol
U090
94-58-6
Dihydrosafrole
U091
119-90-4
3,3'-Dimethoxybenzidine
U092
124-40-3
Dimethylamine (I)
U093
60-11-7
p-Dimethylaminoazobenzene
U094
57-97-6
7,12-Dimethylbenz[a]anthracene
U095
119-93-7
3,3'-Dimethylbenzidine
U096
80-15-9
alpha, alpha-Dimethylbenzylhydroperoxide (R)
U097
79-44-7
Dimethylcarbamoyl chloride
U098
57-14-7
1,1-Dimethylhydrazine
U099
540-73-8
1,2-Dimethylhydrazine
U101
105-67-9
2,4-Dimethylphenol
U102
131-11-3
Dimethyl phthalate
U103
77-78-1
Dimethyl sulfate
U105
121-14-2
2,4-Dinitrotoluene
U106
606-20-2
2,6-Dinitrotoluene
U107
117-84-0
Di-n-octyl phthalate
U108
123-91-1
1,4-Dioxane
U109
122-66-7
1,2-Diphenylhydrazine
U110
142-84-7
Dipropylamine (I)
U111
621-64-7
Di-n-propylnitrosamine
U403
97-77-8
Disulfiram
U041
106-89-8
Epichlorohydrin
U390
759-94-4
EPTC
U001
75-07-0
Ethanal (I)
U404
121-44-8
Ethanamine, N,N-diethyl-
U174
55-18-5
Ethanamine, N-ethyl-N-nitroso-
U155
91-80-5
1,2-Ethanediamine, N,N-dimethyl-N'-2-
pyridinyl-N'-(2-thienylmethyl)-
104
U067
106-93-4
Ethane, 1,2-dibromo-
U076
75-34-3
Ethane, 1,1-dichloro-
U077
107-06-2
Ethane, 1,2-dichloro-
U131
67-72-1
Ethane, hexachloro-
U024
111-91-1
Ethane, 1,1'-[methylenebis(oxy)]bis[2-chloro-
U117
60-29-7
Ethane, 1,1'-oxybis- (I)
U025
111-44-4
Ethane, 1,1'-oxybis[2-chloro-
U184
76-01-7
Ethane, pentachloro-
U208
630-20-6
Ethane, 1,1,1,2-tetrachloro-
U209
79-34-5
Ethane, 1,1,2,2-tetrachloro-
U218
62-55-5
Ethanethioamide
U226
71-55-6
Ethane, 1,1,1-trichloro-
U227
79-00-5
Ethane, 1,1,2-trichloro-
U410
59669-26-0
Ethanimidothioic acid, N,N'- [thiobis[(methyl-
imino)carbonyloxy]]bis-, dimethyl ester
U394
30558-43-1
Ethanimidothioic acid, 2-(dimethylamino)-N-
hydroxy-2-oxo-, methyl ester
U359
110-80-5
Ethanol, 2-ethoxy-
U173
1116-54-7
Ethanol, 2,2'-(nitrosoimino)bis-
U395
5952-26-1
Ethanol, 2,2'-oxybis-, dicarbamate
U004
98-86-2
Ethanone, 1-phenyl-
U043
75-01-4
Ethene, chloro-
U042
110-75-8
Ethene, (2-chloroethoxy)-
U078
75-35-4
Ethene, 1,1-dichloro-
U079
156-60-5
Ethene, 1,2-dichloro-, (E)-
U210
127-18-4
Ethene, tetrachloro-
U228
79-01-6
Ethene, trichloro-
U112
141-78-6
Ethyl acetate (I)
U113
140-88-5
Ethyl acrylate (I)
U238
51-79-6
Ethyl carbamate (urethane)
U117
60-29-7
Ethyl ether
U114
P 111-54-6
Ethylenebisdithiocarbamic acid, salts and esters
U067
106-93-4
Ethylene dibromide
U077
107-06-2
Ethylene dichloride
U359
110-80-5
Ethylene glycol monoethyl ether
U115
75-21-8
Ethylene oxide (I,T)
U116
96-45-7
Ethylenethiourea
U076
75-34-3
Ethylidene dichloride
U118
97-63-2
Ethyl methacrylate
U119
62-50-0
Ethyl methanesulfonate
U407
14324-55-1
Ethyl Ziram
U396
14484-64-1
Ferbam
U120
206-44-0
Fluoranthene
U122
50-00-0
Formaldehyde
U123
64-18-6
Formic acid (C,T)
105
U124
110-00-9
Furan (I)
U125
98-01-1
2-Furancarboxaldehyde (I)
U147
108-31-6
2,5-Furandione
U213
109-99-9
Furan, tetrahydro- (I)
U125
98-01-1
Furfural (I)
U124
110-00-9
Furfuran (I)
U206
18883-66-4
Glucopyranose, 2-deoxy-2-(3-methyl-3-nitroso-
ureido)-, D-
U206
18883-66-4
D-Glucose, 2-deoxy-2-[[(methylnitrosoamino)-
carbonyl]amino]-
U126
765-34-4
Glycidylaldehyde
U163
70-25-7
Guanidine, N-methyl-N'-nitro-N-nitroso-
U127
118-74-1
Hexachlorobenzene
U128
87-68-3
Hexachlorobutadiene
U130
77-47-4
Hexachlorocyclopentadiene
U131
67-72-1
Hexachloroethane
U132
70-30-4
Hexachlorophene
U243
1888-71-7
Hexachloropropene
U133
302-01-2
Hydrazine (R,T)
U086
1615-80-1
Hydrazine, 1,2-diethyl-
U098
57-14-7
Hydrazine, 1,1-dimethyl-
U099
540-73-8
Hydrazine, 1,2-dimethyl-
U109
122-66-7
Hydrazine, 1,2-diphenyl-
U134
7664-39-3
Hydrofluoric acid (C,T)
U134
7664-39-3
Hydrogen fluoride (C,T)
U135
7783-06-4
Hydrogen sulfide
U135
7783-06-4
Hydrogen sulfide H
2
S
U096
80-15-9
Hydroperoxide, 1-methyl-1-phenylethyl- (R)
U116
96-45-7
2-Imidazolidinethione
U137
193-39-5
Indeno[1,2,3-cd]pyrene
U375
55406-53-6
3-Iodo-2-propynyl n-butylcarbamate
U396
14484-64-1
Iron, tris(dimethylcarbamodithioato-S,S')-
U190
85-44-9
1,3-Isobenzofurandione
U140
78-83-1
Isobutyl alcohol (I,T)
U141
120-58-1
Isosafrole
U142
143-50-0
Kepone
U143
303-34-4
Lasiocarpene
U144
301-04-2
Lead acetate
U146
1335-32-6
Lead, bis(acetato-O)tetrahydroxytri-
U145
7446-27-7
Lead phosphate
U146
1335-32-6
Lead subacetate
U129
58-89-9
Lindane
U163
70-25-7
MNNG
U147
108-31-6
Maleic anhydride
U148
123-33-1
Maleic hydrazide
106
U149
109-77-3
Malononitrile
U150
148-82-3
Melphalan
U151
7439-97-6
Mercury
U384
137-42-8
Metam Sodium
U152
126-98-7
Methacrylonitrile (I,T)
U092
124-40-3
Methanamine, N-methyl- (I)
U029
74-83-9
Methane, bromo-
U045
74-87-3
Methane, chloro- (I,T)
U046
107-30-2
Methane, chloromethoxy-
U068
74-95-3
Methane, dibromo-
U080
75-09-2
Methane, dichloro-
U075
75-71-8
Methane, dichlorodifluoro-
U138
74-88-4
Methane, iodo-
U119
62-50-0
Methanesulfonic acid, ethyl ester
U211
56-23-5
Methane, tetrachloro-
U153
74-93-1
Methanethiol (I,T)
U225
75-25-2
Methane, tribromo-
U044
67-66-3
Methane, trichloro-
U121
75-69-4
Methane, trichlorofluoro-
U036
57-74-9
4,7-Methano-1H-indene, 1,2,4,5,6,7,8,8-
octachloro-2,3,3a,4,7,7a-hexahydro-
U154
67-56-1
Methanol (I)
U155
91-80-5
Methapyrilene
U142
143-50-0
1,3,4-Metheno-2H-cyclobuta[cd]pentalen-2-
one, 1,1a,3,3a,4,5,5,5a,5b,6-decachloro-
octahydro-
U247
72-43-5
Methoxychlor
U154
67-56-1
Methyl alcohol (I)
U029
74-83-9
Methyl bromide
U186
504-60-9
1-Methylbutadiene (I)
U045
74-87-3
Methyl chloride (I,T)
U156
79-22-1
Methyl chlorocarbonate (I,T)
U226
71-55-6
Methylchloroform
U157
56-49-5
3-Methylcholanthrene
U158
101-14-4
4,4'-Methylenebis(2-chloroaniline)
U068
74-95-3
Methylene bromide
U080
75-09-2
Methylene chloride
U159
78-93-3
Methyl ethyl ketone (MEK) (I,T)
U160
1338-23-4
Methyl ethyl ketone peroxide (R,T)
U138
74-88-4
Methyl iodide
U161
108-10-1
Methyl isobutyl ketone (I)
U162
80-62-6
Methyl methacrylate (I,T)
U161
108-10-1
4-Methyl-2-pentanone (I)
U164
56-04-2
Methylthiouracil
U010
50-07-7
Mitomycin C
107
U365
2212-67-1
Molinate
U059
20830-81-3
5,12-Naphthacenedione, 8-acetyl-10-[(3-amino-
2,3,6-trideoxy)-alpha-L-lyxo-hexapyranosyl)-
oxyl]-7,8,9,10-tetrahydro-6,8,11-trihydroxy-1-
methoxy-, (8S-cis)-
U167
134-32-7
1-Naphthalenamine
U168
91-59-8
2-Naphthalenamine
U026
494-03-1
Naphthaleneamine, N,N'-bis(2-chloroethyl)-
U165
91-20-3
Naphthalene
U047
91-58-7
Naphthalene, 2-chloro-
U166
130-15-4
1,4-Naphthalenedione
U236
72-57-1
2,7-Naphthalenedisulfonic acid, 3,3'-[(3,3'-di-
methyl-[1,1'-biphenyl]-4,4'-diyl)bis(azo)bis[5-
amino-4-hydroxy]-, tetrasodium salt
U279
63-25-2
1-Naphthalenol, methylcarbamate
U166
130-15-4
1,4-Naphthoquinone
U167
134-32-7
alpha-Naphthylamine
U168
91-59-8
beta-Naphthylamine
U217
10102-45-1
Nitric acid, thallium (1+) salt
U169
98-95-3
Nitrobenzene (I,T)
U170
100-02-7
p-Nitrophenol
U171
79-46-9
2-Nitropropane (I,T)
U172
924-16-3
N-Nitrosodi-n-butylamine
U173
1116-54-7
N-Nitrosodiethanolamine
U174
55-18-5
N-Nitrosodiethylamine
U176
759-73-9
N-Nitroso-N-ethylurea
U177
684-93-5
N-Nitroso-N-methylurea
U178
615-53-2
N-Nitroso-N-methylurethane
U179
100-75-4
N-Nitrosopiperidine
U180
930-55-2
N-Nitrosopyrrolidine
U181
99-55-8
5-Nitro-o-toluidine
U193
1120-71-4
1,2-Oxathiolane, 2,2-dioxide
U058
50-18-0
2H-1,3,2-Oxazaphosphorin-2-amine, N,N-bis-
(2-chloroethyl)tetrahydro-, 2-oxide
U115
75-21-8
Oxirane (I,T)
U126
765-34-4
Oxiranecarboxyaldehyde
U041
106-89-8
Oxirane, (chloromethyl)-
U182
123-63-7
Paraldehyde
U391
1114-71-2
Pebulate
U183
608-93-5
Pentachlorobenzene
U184
76-01-7
Pentachloroethane
U185
82-68-8
Pentachloronitrobenzene (PCNB)
See F027
87-86-5
Pentachlorophenol
U161
108-10-1
Pentanol, 4-methyl-
U186
504-60-9
1,3-Pentadiene (I)
108
U187
62-44-2
Phenacetin
U188
108-95-2
Phenol
U048
95-57-8
Phenol, 2-chloro-
U039
59-50-7
Phenol, 4-chloro-3-methyl-
U081
120-83-2
Phenol, 2,4-dichloro-
U082
87-65-0
Phenol, 2,6-dichloro-
U089
56-53-1
Phenol, 4,4'-(1,2-diethyl-1,2-ethenediyl)bis-,
(E)-
U101
105-67-9
Phenol, 2,4-dimethyl-
U052
1319-77-3
Phenol, methyl-
U132
70-30-4
Phenol, 2,2'-methylenebis[3,4,6-trichloro-
U411
114-26-1
Phenol, 2-(1-methylethoxy)-, methylcarbamate
U170
100-02-7
Phenol, 4-nitro-
See F027
87-86-5
Phenol, pentachloro-
See F027
58-90-2
Phenol, 2,3,4,6-tetrachloro-
See F027
95-95-4
Phenol, 2,4,5-trichloro-
See F027
88-06-2
Phenol, 2,4,6-trichloro-
U150
148-82-3
L-Phenylalanine, 4-[bis(2-chloroethyl)amino]-
U145
7446-27-7
Phosphoric acid, lead (2+) salt (2:3)
U087
3288-58-2
Phosphorodithioic acid, O,O-diethyl S-methyl
ester
U189
1314-80-3
Phosphorus sulfide (R)
U190
85-44-9
Phthalic anhydride
U191
109-06-8
2-Picoline
U179
100-75-4
Piperidine, 1-nitroso-
U400
120-54-7
Piperidine, 1,1'-(tetrathiodicarbonothioyl)-bis-
U383
128-03-0
Potassium dimethyldithiocarbamate
U378
51026-28-9
Potassium n-hydroxymethyl-n-methyldi-thio-
carbamate
U377
137-41-7
Potassium n-methyldithiocarbamate
U192
23950-58-5
Pronamide
U194
107-10-8
1-Propanamine (I,T)
U111
621-64-7
1-Propanamine, N-nitroso-N-propyl-
U110
142-84-7
1-Propanamine, N-propyl- (I)
U066
96-12-8
Propane, 1,2-dibromo-3-chloro-
U083
78-87-5
Propane, 1,2-dichloro-
U149
109-77-3
Propanedinitrile
U171
79-46-9
Propane, 2-nitro- (I,T)
U027
108-60-1
Propane, 2,2'-oxybis[2-chloro-
See F027
93-72-1
Propanoic acid, 2-(2,4,5-trichlorophenoxy)-
U193
1120-71-4
1,3-Propane sultone
U235
126-72-7
1-Propanol, 2,3-dibromo-, phosphate (3:1)
U140
78-83-1
1-Propanol, 2-methyl- (I,T)
U002
67-64-1
2-Propanone (I)
U007
79-06-1
2-Propenamide
109
U084
542-75-6
1-Propene, 1,3-dichloro-
U243
1888-71-7
1-Propene, 1,1,2,3,3,3-hexachloro-
U009
107-13-1
2-Propenenitrile
U152
126-98-7
2-Propenenitrile, 2-methyl- (I,T)
U008
79-10-7
2-Propenoic acid (I)
U113
140-88-5
2-Propenoic acid, ethyl ester (I)
U118
97-63-2
2-Propenoic acid, 2-methyl-, ethyl ester
U162
80-62-6
2-Propenoic acid, 2-methyl-, methyl ester (I,T)
U373
122-42-9
Propham
U411
114-26-1
Propoxur
See F027
93-72-1
Propionic acid, 2-(2,4,5-trichlorophenoxy)-
U194
107-10-8
n-Propylamine (I,T)
U083
78-87-5
Propylene dichloride
U387
52888-80-9
Prosulfocarb
U148
123-33-1
3,6-Pyridazinedione, 1,2-dihydro-
U196
110-86-1
Pyridine
U191
109-06-8
Pyridine, 2-methyl-
U237
66-75-1
2,4-(1H,3H)-Pyrimidinedione, 5-[bis(2-chloro-
ethyl)amino]-
U164
58-04-2
4(1H)-Pyrimidinone, 2,3-dihydro-6-methyl-2-
thioxo-
U180
930-55-2
Pyrrolidine, 1-nitroso-
U200
50-55-5
Reserpine
U201
108-46-3
Resorcinol
U202
P 81-07-2
Saccharin and salts
U203
94-59-7
Safrole
U204
7783-00-8
Selenious acid
U204
7783-00-8
Selenium dioxide
U205
7488-56-4
Selenium sulfide
U205
7488-56-4
Selenium sulfide SeS
2
(R,T)
U376
144-34-3
Selenium, tetrakis(dimethyldithiocarbamate)
U015
115-02-6
L-Serine, diazoacetate (ester)
See F027
93-72-1
Silvex (2,4,5-TP)
U379
136-30-1
Sodium dibutyldithiocarbamate
U381
148-18-5
Sodium diethyldithiocarbamate
U382
128-04-1
Sodium dimethyldithiocarbamate
U206
18883-66-4
Streptozotocin
U277
95-06-7
Sulfallate
U103
77-78-1
Sulfuric acid, dimethyl ester
U189
1314-80-3
Sulfur phosphide (R)
See F027
93-76-5
2,4,5-T
U402
1634-02-2
Tetrabutylthiuram disulfide
U207
95-94-3
1,2,4,5-Tetrachlorobenzene
U208
630-20-6
1,1,1,2-Tetrachloroethane
U209
79-34-5
1,1,2,2-Tetrachloroethane
110
U210
127-18-4
Tetrachloroethylene
See F027
58-90-2
2,3,4,6-Tetrachlorophenol
U213
109-99-9
Tetrahydrofuran (I)
U401
97-74-5
Tetramethylthiuram monosulfide
U366
533-74-4
2H-1,3,5-Thiadiazine- 2-thione, tetrahydro-3,5-
dimethyl-
U214
563-68-8
Thallium (I) acetate
U215
6533-73-9
Thallium (I) carbonate
U216
7791-12-0
Thallium (I) chloride
U216
7791-12-0
Thallium chloride TlCl
U217
10102-45-1
Thallium (I) nitrate
U218
62-55-5
Thioacetamide
U410
59669-26-0
Thiodicarb
U153
74-93-1
Thiomethanol (I,T)
U402
1634-02-2
Thioperoxydicarbonic diamide, tetrabutyl
U403
97-77-8
Thioperoxydicarbonic diamide, tetraethyl
U244
137-26-8
Thioperoxydicarbonic diamide [(H
2
N)C(S)]
2
S
2
,
tetramethyl-
U409
23564-05-8
Thiophanate-methyl
U219
62-56-6
Thiourea
U244
137-26-8
Thiram
U220
108-88-3
Toluene
U221
25376-45-8
Toluenediamine
U223
26471-62-5
Toluene diisocyanate (R,T)
U328
95-53-4
o-Toluidine
U353
106-49-0
p-Toluidine
U222
636-21-5
o-Toluidine hydrochloride
U389
2303-17-5
Triallate
U011
61-82-5
1H-1,2,4-Triazol-3-amine
U227
79-00-5
1,1,2-Trichloroethane
U228
79-01-6
Trichloroethylene
U121
75-69-4
Trichloromonofluoromethane
See F027
95-95-4
2,4,5-Trichlorophenol
See F027
88-06-2
2,4,6-Trichlorophenol
U404
121-44-8
Triethylamine
U234
99-35-4
1,3,5-Trinitrobenzene (R,T)
U182
123-63-7
1,3,5-Trioxane, 2,4,6-trimethyl-
U235
126-72-7
Tris(2,3-dibromopropyl) phosphate
U236
72-57-1
Trypan blue
U237
66-75-1
Uracil mustard
U176
759-73-9
Urea, N-ethyl-N-nitroso-
U177
684-93-5
Urea, N-methyl-N-nitroso-
U385
1929-77-7
Vernolate
U043
75-01-4
Vinyl chloride
U248
P 81-81-2
Warfarin, and salts, when present at
111
concentrations of 0.3% or less
U239
1330-20-7
Xylene (I)
U200
50-55-5
Yohimban-16-carboxylic acid, 11,17-dimeth-
oxy-18-[(3,4,5-trimethoxybenzoyl)oxy]-,
methyl ester,
(3beta,16beta,17alpha,18beta,20alpha)-
U407
14324-55-1
Zinc, bis(diethylcarbamodithioato-S,S')-
U249
1314-84-7
Zinc phosphide Zn
3
P
2
, when present at
concentrations of 10% or less
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 721.Appendix G
Basis for Listing Hazardous Wastes
EPA
hazardous
waste No.
Hazardous constituents for which listed
F001
Tetrachloroethylene, methylene chloride, trichloroethylene, 1,1,1-
trichloroethane, carbon tetrachloride, chlorinated fluorocarbons.
F002
Tetrachloroethylene, methylene chloride, trichloroethylene, 1,1,1-
trichloroethane, 1,1,2-trichlorethane, chlorobenzene, 1,1,2-trichloro-1,2,2-
trifluoroethane, ortho-dichlorobenzene, trichlorofluoromethane.
F003
N.A.
F004
Cresols and cresylic acid, nitrobenzene.
F005
Toluene, methyl ethyl ketone, carbon disulfide, isobutanol, pyridine, 2-
ethoxyethanol, benzene, 2-nitropropane.
F006
Cadmium, hexavalent chromium, nickel, cyanide (complexed).
F007
Cyanide (salts).
F008
Cyanide (salts).
F009
Cyanide (salts).
F010
Cyanide (salts).
F011
Cyanide (salts).
F012
Cyanide (complexed).
F019
Hexavalent chromium, cyanide (complexed).
F020
Tetra- and pentachlorodibenzo-p-dioxins; tetra- and pentachlorodibenzofurans;
tri- and tetrachlorophenols and their clorophenoxy derivative acids, esters,
ethers, amines and other salts.
F021
Penta- and hexachlorodibenzo-p-dioxins; penta- and hexachlorodibenzofurans;
pentachlorophenol and its derivatives.
F022
Tetra-, penta- and hexachlorodibenzo-p-dioxins; tetra-, penta- and
hexachlorodibenzofurans.
112
F023
Tetra- and pentachlorodibenzo-p-dioxins; tetra- and pentachlorodibenzofurans;
tri- and tetra- chlorophenols and their chlorophenoxy derivative acids, esters,
ethers, amines and other salts.
F024
Chloromethane, dichloromethane, trichloromethane, carbon tetrachloride,
chloroethylene, 1,1-dichloroethane, 1,2-dichloroethane, trans-1,2-
dichloroethylene, 1,1-dichloroethylene, 1,1,1-trichloroethane, 1,1,2-
trichloroethane, trichloroethylene, 1,1,1,2-tetrachloroethane, 1,1,2,2-
tetrachloroethane, tetrachloroethylene, pentachloroethane, hexachloroethane,
allyl chloride (3-chloropropene), dichloropropane, dichloropropene, 2-chloro-
1,3-butadiene, hexachloro-1,3-butadiene, hexachlorochylopentadiene,
hexachlorocylohexane, benzene, chlorobenzene, dichlorobenzenes, 1,2,4-
trichlorobenzene, tetrachlorobenzenes, pentachlorobenzene, hexachlorobenzene,
toluene, naphthalene.
F025
Chloromethane, dicloromethane, trichloromethane; carbon tetrachloride;
chloroethylene; 1,1-dichloroethane; 1,2-dichloroethane; trans-1,2-
dichloroethylene; 1,1-dichloroethylene; 1,1,1-trichloroethane; 1,1,2-
trichloroethane; trichloroethylene; 1,1,1,2-tetrachloroethane; 1,1,2,2-
tetrachloroethane; tetrachloroethylene; pentachloroethane; hexachloroethane;
allyl chloride (3-chloropropene); dichloropropane; dichloropropene; 2-chloro-
1,3-butadiene; hexachloro-1,3-butadiene; hexachlorocyclopentadiene; benzene;
chlorobenzene; dichlorobenzene; 1,2,4-trichlorobenzene; tetrachlorobenzene;
pentachlorobenzene; hexachlorobenzene; toluene; naphthalene.
F026
Tetra-, penta-, and hexachlorodibenzo-p-dioxins; tetra-, penta-, and
hexachlorodibenzofurans.
F027
Tetra-, penta, and hexachlorodibenzo-p-dioxins; tetra-, penta-, and
hexachlorodibenzofurans; tri-, tetra-, and pentachlorophenols and their
chlorophenoxy derivative acids, esters, ethers, amine and other salts.
F028
Tetra-, penta-, and hexachlorodibenzo-p-dixonsdioxins; tetra-, penta-, and
hexachlorodibenzofurans; tri-, tetra-, and pentachlorophenols and their
chlorophenoxy derivative acids, esters, ethers, amine and other salts.
F032
Benz(a)anthracene, benzo(a)pyrene, dibenz(a,h)anthracene, indeno(1,2,3-
cd)pyrene, pentachlorophenol, arsenic, chromium, tetra-, penta-, hexa-,
heptachlorordibenzo-p-dioxins, tetra-, penta-, hexa-, heptachlorodibenzofurans.
F034
Benz(a)anthracene, benzo(k)fluoranthene, benzo(a)pyrene,
dibenz(a,h)anthracene, indeno(1,2,3-cd)pyrene, naphthalene, arsenic chromium.
F035
Arsenic, chromium and lead.
F037
Benzene, benzo(a)pyrene, chrysene, lead, chromium.
F038
Benzene, benzo(a)pyrene, chrysene, lead, chromium.
F039
All constituents for which treatment standards are specified for multi-source
leachate (wastewaters and non-wastewaters) under 35 Ill. Adm. Code 728.Table
B (Constituent Concentrations in Waste).
K001
Pentachlorophenol, phenol, 2-chlorophenol, p-chloro-m-cresol, 2,4-
dimethylphenol, 2,4- dinitrophenol, trichlorophenols, tetrachlorophenols, 2,4-
dinitrophenol, cresosote, chrysene, naphthalene, fluoranthene,
113
benzo(b)fluoranthene, benzo(a)pyrene, indeno(1,2,3-cd)pyrene, benz(a)
anthracene, dibenz(a)anthracene, acenaphthalene.
K002
Hexavalent chromium, lead.
K003
Hexavalent chromium, lead.
K004
Hexavalent chromium.
K005
Hexavalent chromium, lead.
K006
Hexavalent chromium.
K007
Cyanide (complexed), hexavalent chromium.
K008
Hexavalent chromium.
K009
Chloroform, formaldehyde, methylene chloride, methyl chloride, paraldehyde,
formic acid.
K010
Chloroform, formaldehyde, methylene chloride, methyl chloride, paraldehyde,
formic acid, chloroacetaldehyde.
K011
Acrylonitrile, acetonitrile, hydrocyanic acid.
K013
Hydrocyanic acid, acrylonitrile, acetonitrile.
K014
Acetonitrile, acrylamide.
K015
Benzyl chloride, chlorobenzene, toluene, benzotrichloride.
K016
Hexachlorobenzene, hexachlorobutadiene, carbon tetrachloride,
hexachloroethane, perchloroethylene.
K017
Epichlorohydrin, chloroethers [bis(chloromethyl) ether and bis- (2-chloroethyl)
ethers], trichloropropane, dichloropropanols.
K018
1,2-dichloroethane, trichloroethylene, hexachlorobutadiene, hexachlorobenzene.
K019
Ethylene dichloride, 1,1,1-trichloroethane, 1,1,2-trichloroethane,
tetrachloroethanes (1,1,2,2-tetrachloroethane and 1,1,1,2-tetrachloroethane),
trichloroethylene, tetrachloroethylene, carbon tetrachloride, chloroform, vinyl
chloride, vinylidene chloride.
K020
Ethylene dichloride, 1,1,1-trichloroethane, 1,1,2-trichloroethane, tetrachloro-
ethanes (1,1,2,2-tetrachloroethane and 1,1,1,2-tetrachloroethane),
trichloroethylene, tetrachloroethylene, carbon tetrachloride, chloroform, vinyl
chloride, vinylidene chloride.
K021
Antimony, carbon tetrachloride, chloroform.
K022
Phenol, tars (polycyclic aromatic hydrocarbons).
K023
Phthalic anhydride, maleic anhydride.
K024
Phthalic anhydride, 1,4-naphthoguinone.
K025
Meta-dinitrobenzene, 2,4-dinitrotoluene.
K026
Paraldehyde, pyridines, 2-picoline.
K027
Toluene diisocyanate, toluene-2,4-diamine.
K028
1,1,1-trichloroethane, vinyl chloride.
K029
1,2-dichloroethane, 1,1,1-trichloroethane, vinyl chloride, vinylidene chloride,
chloroform.
K030
Hexachlorobenzene, hexachlorobutadiene, hexachloroethane, 1,1,1,2-
tetrachloroethane, 1,1,2,2-tetrachloroethane, ethylene dichloride.
K031
Arsenic.
K032
Hexachlorocyclopentadiene.
K033
Hexachlorocyclopentadiene.
114
K034
Hexachlorocyclopentadiene.
K035
Creosote, chrysene, naphthalene, fluoranthene, benzo(b) fluoranthene,
benzo(a)-pyrene, indeno(1,2,3-cd) pyrene, benzo(a)anthracene,
dibenzo(a)anthracene, acenaphthalene.
K036
Toluene, phosphorodithioic and phosphorothioic acid esters.
K037
Toluene, phosphorodithioic and phosphorothioic acid esters.
K038
Phorate, formaldehyde, phosphorodithioic and phosphorothioic acid esters.
K039
Phosphorodithioic and phosphorothioic acid esters.
K040
Phorate, formaldehyde, phosphorodithioic and phosphorothioic acid esters.
K041
Toxaphene.
K042
Hexachlorobenzene, ortho-dichlorobenzene.
K043
2,4-dichlorophenol, 2,6-dichlorophenol, 2,4,6-trichlorophenol.
K044
N.A.
K045
N.A.
K046
Lead.
K047
N.A.
K048
Hexavalent chromium, lead.
K049
Hexavalent chromium, lead.
K050
Hexavalent chromium.
K051
Hexavalent chromium, lead.
K052
Lead.
K060
Cyanide, naphthalene, phenolic compounds, arsenic.
K061
Hexavalent chromium, lead, cadmium.
K062
Hexavalent chromium, lead.
K064
Lead, cadmium.
K065
Lead, cadmium.
K066
Lead, cadmium.
K069
Hexavalent chromium, lead, cadmium.
K071
Mercury.
K073
Chloroform, carbon tetrachloride, hexachloroethane, trichloroethane,
tetrachloroethylene, dichloroethylene, 1,1,2,2-tetrachloroethane.
K083
Aniline, diphenylamine, nitrobenzene, phenylenediamine.
K084
Arsenic.
K085
Benzene, dichlorobenzenes, trichlorobenzenes, tetrachlorobenzenes,
pentachlorobenzene, hexachlorobenzene, benzyl chloride.
K086
Lead, hexavalent chromium.
K087
Phenol, naphthalene.
K088
Cyanide (complexes).
K090
Chromium.
K091
Chromium.
K093
Phthalic anhydride, maleic anhydride.
K094
Phthalic anhydride.
K095
1,1,2-trichloroethane, 1,1,1,2-tetrachloroethane, 1,1,2,2-tetrachloroethane.
K096
1,2-dichloroethane, 1,1,1-trichloroethane, 1,1,2-trichloroethane.
K097
Chlordane, heptachlor.
115
K098
Toxaphene.
K099
2,4-dichlorophenol, 2,4,6-trichlorophenol.
K100
Hexavalent chromium, lead, cadmium.
K101
Arsenic.
K102
Arsenic.
K103
Aniline, nitrobenzene, phenylenediamine.
K104
Aniline, benzene, diphenylamine, nitrobenzene, phynylenediamine.
K105
Benzene, monochlorobenzene, dichlorobenzenes, 2,4,6-trichlorophenol.
K106
Mercury.
K111
2,4-Dinitrotoluene.
K112
2,4-Toluenediamine, o-toluidine, p-toluidine, aniline.
K113
2,4-Toluenediamine, o-toluidine, p-toluidine, aniline.
K114
2,4-Toluenediamine, o-toluidine, p-toluidine.
K115
2,4-Toluenediamine.
K116
Carbon tetrachloride, tetrachloroethylene, chloroform, phosgene.
K117
Ethylene dibromide.
K118
Ethylene dibromide.
K123
Ethylene thiourea.
K124
Ethylene thiourea.
K125
Ethylene thiourea.
K126
Ethylene thiourea.
K131
Dimethyl sulfate, methyl bromide.
K132
Methyl bromide.
K136
Ethylene dibromide.
K141
Benzene, benz(a)anthracene, benzo(a)pyrene, benzo(b)fluoranthene,
benzo(k)fluoranthene, dibenz(a,h)anthracene, indeno(1,2,3-cd)pyrene.
K142
Benzene, benz(a)anthracene, benzo(a)pyrene, benzo(b)fluoranthene,
benzo(k)fluoranthene, dibenz(a,h)anthracene, indeno(1,2,3-cd)pyrene.
K143
Benzene, benz(a)anthracene, benzo(b)fluoranthene, benzo(k)fluoranthene.
K144
Benzene, benz(a)anthracene, benzo(a)pyrene, benzo(b)fluoranthene,
benzo(k)fluoranthene, dibenz(a,h)anthracene.
K145
Benzene, benz(a)anthracene, benzo(a)pyrene, dibenz(a,h)anthracene,
naphthalene.
K147
Benzene, benz(a)anthracene, benzo(a)pyrene, benzo(b)fluoranthene,
benzo(k)fluoranthene, dibenz(a,h)anthracene, indeno(1,2,3-cd)pyrene.
K148
Benz(a)anthracene, benzo(a)pyrene, benzo(b)fluoranthene,
benzo(k)fluoranthene, dibenz(a,h)anthracene, indeno(1,2,3-cd)pyrene.
K149
Benzotrichloride, benzyl chloride, chloroform, chloromethane, chlorobenzene,
1,4-dichlorobenzene, hexachlorobenzene, pentachlorobenzene, 1,2,4,5-
tetrachlorobenzene, toluene.
K150
Carbon tetrachloride, chloroform, chloromethane, 1,4-dichlorobenzene,
hexachlorobenzene, pentachlorobenzene, 1,2,4,5-tetrachlorobenzene, 1,1,2,2-
tetrachloroethane, tetrachloroethylene, 1,2,4-trichlorobenzene.
K151
Benzene, carbon tetrachloride, chloroform, hexachlorobenzene,
pentachlorobenzene, toluene, 1,2,4,5-tetrachlorobenzene, tetrachloroethylene.
116
K156
Benomyl, carbaryl, carbendazim, carbofuran, carbosulfan, formaldehyde,
methylene chloride, triethylamine.
K157
Carbon tetrachloride, formaldehyde, methyl chloride, methylene chloride,
pyridine, triethylamine.
K158
Benomyl, carbendazim, carbofuran, carbosulfan, chloroform, methylene
chloride.
K159
Benzene, butylate, EPTC, molinate, pebulate, vernolate.
K160 Benzene, butylate, EPTC, molinate, pebulate, vernolate.
K161
Antimony, arsenic, metam-sodium, ziram.
N.A.--Waste is hazardous because it fails the test for the
characteristic of ignitability, corrosivity or reactivity.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 721.Appendix H
Hazardous Constituents
Common Name
Chemical Abstracts Name
Chemical
Abstracts
Number
Hazard
ous
Waste
Numbe
r
A2213
Ethanimidothioic acid, 2-
(dimethylamino)-N-hydroxy-2-
oxo-, methyl ester
30558-43-1
U394
Acetonitrile
Same
75-05-8
U003
Acetophenone
Ethanone, 1-phenyl-
98-86-2
U004
2-Acetylaminofluorene
Acetamide, N-9H-fluoren-2-yl-
53-96-3
UOO5
Acetyl chloride
Same
75-36-5
U006
1-Acetyl-2-thiourea
Acetamide, N-
(aminothioxomethyl)-
591-08-2
P002
Acrolein
2-Propenal
107-02-8
P003
Acrylamide
2-Propenamide
79-06-1
U007
Acrylonitrile
2-Propenenitrile
107-13-1
U009
Aflatoxins
Same
1402-68-2
Aldicarb
Propanal, 2-methyl-2-
(methylthio)-, O-
[(methylamino)carbonyl]oxime
116-06-3
P070
Aldicarb sulfone
Propanal, 2-methyl-2- (methyl-
sulfonyl)-, O-[(methylamino)-
carbonyl]oxime
1646-88-4
P203
Aldrin
1,4,5,8-Dimethanonaphthalene,
1,2,3,4,10,10-hexachloro-
309-00-2
P004
117
1,4,4a,5,8,8a-hexahydro-, (1-
alpha,4-alpha,4a-beta,5-
alpha,8-alpha,8a-beta)-
Allyl alcohol
2-Propen-1-ol
107-18-6
P005
Allyl chloride
1-Propene, 3-chloro-
107-18-6
Aluminum phosphide
Same
20859-73-8
P006
4-Aminobiphenyl
[1,1'-Biphenyl]-4-amine
92-67-1
5-(Aminomethyl)-3-isoxazolol
3(2H)-Isoxazolone, 5-(amino-
methyl)-
2763-96-4
P007
4-Aminopyridine
4-Pyridinamine
504-24-5
P008
Amitrole
1H-1,2,4-Triazol-3-amine
61-82-5
U011
Ammonium vanadate
Vanadic acid, ammonium salt
7803-55-6
U119
Aniline
Benzenamine
62-53-3
U012
Antimony
Same
7440-36-0
Antimony compounds, N.O.S. (not
otherwise specified)
Aramite
Sulfurous acid, 2-chloroethyl-,
2-[4-(1,1-dimethylethyl)-
phenoxy]-1-methylethyl ester
140-57-8
Arsenic
Arsenic
7440-38-2
Arsenic compounds, N.O.S.
Arsenic acid
Arsenic acid H
3
AsO
4
7778-39-4
P010
Arsenic pentoxide
Arsenic oxide As
2
O
5
1303-28-2
PO11
Arsenic trioxide
Arsenic oxide As
2
O
3
1327-53-3
P012
Auramine
Benzenamine, 4,4'-carbon-
imidoylbis[N, N-dimethyl-
492-80-8
U014
Azaserine
L-Serine, diazoacetate (ester)
115-02-6
U015
Barban
Carbamic acid, (3-chloro-
phenyl)-, 4-chloro-2-butynyl
ester
101-27-9
U280
Barium
Same
7440-39-3
Barium compounds, N.O.S.
Barium cyanide
Same
542-62-1
P013
Bendiocarb
1,3-Benzodioxol-4-ol-2,2-
dimethyl-, methyl carbamate
22781-23-3
U278
Bendiocarb phenol
1,3-Benzodioxol-4-ol-2,2-
dimethyl-,
22961-82-6
U364
Benomyl
Carbamic acid, [1- [(butyl-
amino)carbonyl]-1H-benz-
imidazol-2-yl]-, methyl ester
17804-35-2
U271
Benz[c]acridine
Same
225-51-4
U016
Benz[a]anthracene
Same
56-55-3
U018
Benzal chloride
Benzene, (dichloromethyl)-
98-87-3
U017
Benzene
Same
71-43-2
U018
Benzenearsonic acid
Arsonic acid, phenyl-
98-05-5
118
Benzidine
[1,1'-Biphenyl]-4,4'-diamine
92-87-5
U021
Benzo[b]fluoranthene
Benz[e]acephenanthrylene
205-99-2
Benzo[j]fluoranthene
Same
205-82-3
Benzo(k)fluoranthene
Same
207-08-9
Benzo[a]pyrene
Same
50-32-8
U022
p-Benzoquinone
2,5-Cyclohexadiene-1,4-dione
106-51-4
U197
Benzotrichloride
Benzene, (trichloromethyl)-
98-07-7
U023
Benzyl chloride
Benzene, (chloromethyl)-
100-44-7
P028
Beryllium powder
Same
7440-41-7
P015
Beryllium compounds, N.O.S.
Bis(pentamethylene)thiuram
tetrasulfide
Piperidine, 1,1'-(tetrathio-
dicarbonothioyl)-bis-
120-54-7
U400
Bromoacetone
2-Propanone, 1-bromo-
598-31-2
P017
Bromoform
Methane, tribromo-
75-25-2
U225
4-Bromophenyl phenyl ether
Benzene, 1-bromo-4-phenoxy-
101-55-3
U030
Brucine
Strychnidin-10-one, 2,3-
dimethoxy-
357-57-3
P018
Butylate
Carbamothioic acid, bis(2-
methylpropyl)-, S-ethyl ester
2008-41-5
U392
Butyl benzyl phthalate
1,2-Benzenedicarboxylic acid,
butyl phenylmethyl ester
85-68-7
Cacodylic acid
Arsenic acid, dimethyl-
75-60-5
U136
Cadmium
Same
7440-43-9
Cadmium compounds, N.O.S.
Calcium chromate
Chromic acid H
2
CrO
4
, calcium
salt
13765-19-0
U032
Calcium cyanide
Calcium cyanide Ca(CN)
2
592-01-8
P021
Carbaryl
1-Naphthalenol, methyl-
carbamate
63-25-2
U279
Carbendazim
Carbamic acid, 1H-benz-
imidazol-2-yl, methyl ester
10605-21-7
U372
Carbofuran
7-Benzofuranol, 2,3-dihydro-
2,2-dimethyl-, methylcarbamate
1563-66-2
P127
Carbofuran phenol
7-Benzofuranol, 2,3-dihydro-
2,2-dimethyl-
1563-38-8
U367
Carbosulfan
Carbamic acid, [(dibutyl-
amino)thio] methyl-, 2,3-
dihydro-2,2-dimethyl-7-benzo-
furanyl ester
55285-14-8
P189
Carbon disulfide
Same
75-15-0
P022
Carbon oxyfluoride
Carbonic difuoride
353-50-4
U033
Carbon tetrachloride
Methane, tetrachloro-
56-23-5
U211
Chloral
Acetaldehyde, trichloro-
75-87-6
U034
Chlorambucil
Benzenebutanoic acid, 4[bis-(2-
chloroethyl)amino]-
305-03-3
U035
119
Chlordane
4,7-Methano-1H-indene,
1,2,4,5,6,7,8,8-octachloro-
2,3,3a,4,7,7a-hexahydro-
57-74-9
U036
Chlordane, alpha and gamma
isomers
U036
Chlorinated benzenes, N.O.S.
Chlorinated ethane, N.O.S.
Chlorinated fluorocarbons, N.O.S.
Chlorinated naphthalene, N.O.S.
Chlorinated phenol, N.O.S.
Chlornaphazine
Naphthalenamine, N,N'-bis(2-
chloroethyl)-
494-03-1
U026
Chloroacetaldehyde
Acetaldehyde, chloro-
107-20-0
P023
Chloroalkyl ethers, N.O.S.
p-Chloroaniline
Benzenamine, 4-chloro-
106-47-8
P024
Chlorobenzene
Benzene, chloro-
108-90-7
U037
Chlorobenzilate
Benzeneacetic acid, 4-chloro-
alpha-(4-chlorophenyl)-alpha-
hydroxy-, ethyl ester
510-15-6
U038
p-Chloro-m-cresol
Phenol, 4-chloro-3-methyl-
59-50-7
U039
2-Chloroethyl vinyl ether
Ethene, (2-chloroethoxy)-
110-75-8
U042
Chloroform
Methane, trichloro-
67-66-3
U044
Chloromethyl methyl ether
Methane, chloromethoxy-
107-30-2
U046
beta-Chloronaphthalene
Naphthalene, 2-chloro-
91-58-7
U047
o-Chlorophenol
Phenol, 2-chloro-
95-57-8
U048
1-(o-Chlorophenyl)thiourea
Thiourea, (2-chlorophenyl)-
5344-82-1
P026
Chloroprene
1,3-Butadiene, 2-chloro-
126-99-8
3-Chloropropionitrile
Propanenitrile, 3-chloro-
542-76-7
P027
Chromium
Same
7440-47-3
Chromium compounds, N.O.S.
Chrysene
Same
218-01-9
U050
Citrus red No. 2
2-Naphthalenol, 1-[(2,5-
dimethoxyphenyl)azo]-
6358-53-8
Coal tar creosote
Same
8007-45-2
Copper cyanide
Copper cyanide CuCN
544-92-3
P029
Copper dimethyldithiocarbamate
Copper, bis(dimethylcarbamo-
dithioato-S,S')-,
137-29-1
U393
Creosote
Same
U051
Cresols (Cresylic acid)
Phenol, methyl-
1319-77-3
U052
Crotonaldehyde
2-Butenal
4170-30-3
U053
m-Cumenyl methylcarbamate
Phenol, 3-(methylethyl)-,
methyl carbamate
64-00-6
P202
Cyanides (soluble salts and
complexes), N.O.S.
P030
Cyanogen
Ethanedinitrile
460-19-5
P031
120
Cyanogen bromide
Cyanogen bromide (CN)Br
506-68-3
U246
Cyanogen chloride
Cyanogen chloride (CN)Cl
506-77-4
P033
Cycasin
Beta-D-glucopyranoside,
(methyl-ONN-azoxy)methyl-
14901-08-7
Cycloate
Carbamothioic acid, cyclo-
hexylethyl-, S-ethyl ester
1134-23-2
U386
2-Cyclohexyl-4,6-dinitrophenol
Phenol, 2-cyclohexyl-4,6-
dinitro-
131-89-5
P034
Cyclophosphamide
2H-1,3,2-Oxazaphosphorin-2-
amine, N,N-bis(2-chloro-
ethyl)tetrahydro-, 2-oxide
50-18-0
U058
2,4-D
Acetic acid, (2,4-dichloro-
phenoxy)-
94-75-7
U240
2,4-D, salts and esters
Acetic acid, (2,4-
dichlorophenoxy)-, salts and
esters
U240
Daunomycin
5, 12-Naphthacenedione, 8-
acetyl-10-[(3-amino-2,3,6-
trideoxy-alpha-L-lyxo-hexo-
pyranosyl)oxy]-7,8,9,10-
tetrahydro-6,8,11-trihydroxy-l-
methoxy-, 8S-cis)-
20830-81-3
U059
Dazomet
2H-1,3,5-thiadiazine-2-thione,
tetrahydro-3,5-dimethyl
533-74-4
U366
DDD
Benzene, 1,1'-(2,2-dichloro-
ethylidene)bis[4-chloro-
72-54-8
U060
DDE
Benzene, 1,1'-(dichloroethenyl-
idene)bis[4-chloro-
72-55-9
DDT
Benzene, 1,1'-(2,2,2-trichloro-
ethylidene)bis[4-chloro-
50-29-3
U061
Diallate
Carbamothioic acid, bis(1-
methylethyl)-, S-(2,3-dichloro-
2-propenyl) ester
2303-16-4
U062
Dibenz[a,h]acridine
Same
226-36-8
Dibenz[a,j]acridine
Same
224-42-0
Dibenz[a,h]anthracene
Same
53-70-3
U063
7H-Dibenzo[c,g]carbazole
Same
194-59-2
Dibenzo[a,e]pyrene
Naphtho[1,2,3,4-def]chrysene
192-65-4
Dibenzo[a,h]pyrene
Dibenzo[b,def]chrysene
189-64-0
Dibenzo[a,i]pyrene
Benzo[rst]pentaphene
189-55-9
U064
1,2-Dibromo-3-chloropropane
Propane, 1,2-dibromo-3-chloro-
96-12-8
U066
Dibutyl phthalate
1,2-Benzenedicarboxylic acid,
dibutyl ester
84-74-2
U069
o-Dichlorobenzene
Benzene, 1,2-dichloro-
95-50-1
U070
m-Dichlorobenzene
Benzene, 1,3-dichloro-
541-73-1
U071
121
p-Dichlorobenzene
Benzene, 1,4-dichloro-
106-46-7
U072
Dichlorobenzene, N.O.S.
Benzene, dichloro-
25321-22-6
3,3'-Dichlorobenzidine
[1,1'-Biphenyl]-4,4'-diamine,
3,3'-dichloro-
91-94-1
U073
1,4-Dichloro-2-butene
2-Butene, 1,4-dichloro-
764-41-0
U074
Dichlorodifluoromethane
Methane, dichlorodifluoro-
75-71-8
U075
Dichloroethylene, N.O.S.
Dichloroethylene
25323-30-2
1,1-Dichloroethylene
Ethene, 1,1-dichloro-
75-35-4
U078
1,2-Dichloroethylene
Ethene, 1,2-dichloro-, (E)-
156-60-5
U079
Dichloroethyl ether
Ethane, 1,1'-oxybis[2-chloro-
111-44-4
U025
Dichloroisopropyl ether
Propane, 2,2'-oxybis[2-chloro-
108-60-1
U027
Dichloromethoxyethane
Ethane, 1,1'-[methylenebis-
(oxy)bis[2-chloro-
111-91-1
U024
Dichloromethyl ether
Methane, oxybis[chloro-
542-88-1
P016
2,4-Dichlorophenol
Phenol, 2,4-dichloro-
120-83-2
U081
2,6-Dichlorophenol
Phenol, 2,6-dichloro-
87-65-0
U082
Dichlorophenylarsine
Arsonous dichloride, phenyl-
696-28-6
P036
Dichloropropane, N.O.S.
Propane, dichloro-
26638-19-7
Dichloropropanol, N.O.S.
Propanol, dichloro-
26545-73-3
Dichloropropene, N.O.S.
1-Propene, dichloro-
26952-23-8
1,3-Dichloropropene
1-Propene, 1,3-dichloro-
542-75-6
U084
Dieldrin
2,7:3,6-Dimethanonaphth[2, 3-
b]oxirene,3,4,5,6,9,9-hexa-
chloro-1a,2,2a,3,6, 6a,7,7a-
octahydro-,
(1aalpha,2beta,2aalpha,3beta,6
beta,6aalpha,7beta,7aalpha)-
60-57-1
P037
1,2:3,4-Diepoxybutane
2,2'-Bioxirane
1464-53-5
U085
Diethylarsine
Arsine, diethyl-
692-42-2
P038
Diethylene glycol, dicarbamate
Ethanol, 2,2'-oxybis-,
dicarbamate
5952-26-1
U395
1,4-Diethyleneoxide
1,4-Dioxane
123-91-1
U108
Diethylhexyl phthalate
1,2-Benzenedicarboxylic acid,
bis(2-ethylhexyl) ester
117-81-7
U028
N,N'-Diethylhydrazine
Hydrazine, 1,2-diethyl-
1615-80-1
U086
O,O-Diethyl-S-methyl dithio-
phosphate
Phosphorodithioic acid, O,O-
diethyl S-methyl ester
3288-58-2
U087
Diethyl-p-nitrophenyl phosphate
Phosphoric acid, diethyl 4-
nitrophenyl ester
311-45-5
P041
Diethyl phthalate
1,2-Benzenedicarboxylic acid,
diethyl ester
84-66-2
U088
O,O-Diethyl O-pyrazinyl
phosphorothioate
Phosphorothioic acid, O,O-
diethyl O-pyrazinyl ester
297-97-2
P040
Diethylstilbestrol
Phenol, 4,4'-(1,2-diethyl-1,2-
ethenediyl)bis-, (E)-
56-53-1
U089
122
Dihydrosafrole
1,3-Benzodioxole, 5-propyl-
94-58-6
U090
Diisopropylfluorophosphate (DFP)
Phosphorofluoridic acid, bis(1-
methylethyl) ester
55-91-4
P043
Dimethoate
Phosphorodithioic acid, O,O-
dimethyl S-[2-(methylamino)-2-
oxoethyl] ester
60-51-5
P044
Dimetilan
Carbamic acid, dimethyl-, 1-
[(dimethylamino) carbonyl]-5-
methyl-1H-pyrazol-3-yl ester
644-64-4
P191
3,3'-Dimethoxybenzidine
[1,1'-Biphenyl]-4,4'-diamine,
3,3'-dimethoxy-
119-90-4
U091
p-Dimethylaminoazobenzene
Benzenamine, N,N-dimethyl-4-
(phenylazo)-
60-11-7
U093
7,12-Dimethylbenz[a]anthracene
Benz[a]anthracene, 7,12-
dimethyl-
57-97-6
U094
3,3'-Dimethylbenzidine
[1,1'-Biphenyl]-4,4'-diamine,
3,3'-dimethyl-
119-93-7
U095
Dimethylcarbamoyl chloride
Carbamic chloride, dimethyl-
79-44-7
U097
1,1-Dimethylhydrazine
Hydrazine, 1,1-dimethyl-
57-14-7
U098
1,2-Dimethylhydrazine
Hydrazine, 1,2-dimethyl-
540-73-8
U099
alpha,alpha-Dimethylphen-
ethylamine
Benzeneethanamine, alpha,
alpha-dimethyl-
122-09-8
P046
2,4-Dimethylphenol
Phenol, 2,4-dimethyl-
105-67-9
U101
Dimethylphthalate
1,2-Benzenedicarboxylic acid,
dimethyl ester
131-11-3
U102
Dimethyl sulfate
Sulfuric acid, dimethyl ester
77-78-1
U103
Dinitrobenzene, N.O.S.
Benzene, dinitro-
25154-54-5
4,6-Dinitro-o-cresol
Phenol, 2-methyl-4,6-dinitro-
534-52-1
P047
4,6-Dinitro-o-cresol salts
P047
2,4-Dinitrophenol
Phenol, 2,4-dinitro-
51-28-5
P048
2,4-Dinitrotoluene
Benzene, 1-methyl-2,4-dinitro-
121-14-2
U105
2,6-Dinitrotoluene
Benzene, 2-methyl-1,3-dinitro-
606-20-2
U106
Dinoseb
Phenol, 2-(1-methylpropyl)-
4,6-dinitro-
88-85-7
P020
Di-n-octyl phthalate
1,2-Benzenedicarboxylic acid,
dioctyl ester
117-84-0
U107
Diphenylamine
Benzenamine, N-phenyl-
122-39-4
1,2-Diphenylhydrazine
Hydrazine, 1,2-diphenyl-
122-66-7
U109
Di-n-propylnitrosamine
1-Propanamine, N-nitroso-N-
propyl-
621-64-7
U111
Disulfiram
Thioperoxydicarbonic diamide,
tetraethyl
97-77-8
U403
Disulfoton
Phosphorodithioic acid, O,O-
diethyl S-[2-(ethylthio)ethyl]
ester
298-04-4
P039
123
Dithiobiuret
Thioimidodicarbonic diamide
[(H
2
N)C(S)]
2
NH
541-53-7
P049
Endosulfan
6, 9-Methano-2,4,3-benzo-
dioxathiepen,6,7,8,9,10,10-
hexachloro-1,5,5a,6,9,9a-
hexahydro-, 3-oxide,
115-29-7
P050
Endothal
7-Oxabicyclo[2.2.1]heptane-
2,3-dicarboxylic acid
145-73-3
P088
Endrin
2,7:3,6-Dimethanonaphth[2,3-
b]oxirene, 3,4,5,6,9,9-hexa-
chloro-1a,2,2a,3,6,6a,7,7a-
octahydro-, (1a
alpha,2beta,2abeta,3alpha,6alph
a,6abeta,7beta,7aalpha)-,
72-20-8
P051
Endrin metabolites
P051
Epichlorohydrin
Oxirane, (chloromethyl)-
106-89-8
U041
Epinephrine
1,2-Benzenediol, 4-[1-hydroxy-
2-(methylamino)ethyl]-, (R)-
51-43-4
P042
EPTC
Carbamothioic acid, dipropyl-,
S-ethyl ester
759-94-4
U390
Ethyl carbamate (urethane)
Carbamic acid, ethyl ester
51-79-6
U238
Ethyl cyanide
Propanenitrile
107-12-0
P101
Ethylenebisdithiocarbamic acid
Carbamodithioic acid, 1,2-
ethanediylbis-
111-54-6
U114
Ethylenebisdithiocarbamic acid,
salts and esters
U114
Ethylene dibromide
Ethane, 1,2-dibromo-
106-93-4
U067
Ethylene dichloride
Ethane, 1,2-dichloro-
107-06-2
U077
Ethylene glycol monoethyl ether
Ethanol, 2-ethoxy-
110-80-5
U359
Ethyleneimine
Aziridine
151-56-4
P054
Ethylene oxide
Oxirane
75-21-8
U115
Ethylenethiourea
2-Imidazolidinethione
96-45-7
U116
Ethylidine dichloride
Ethane, 1,1-dichloro-
75-34-3
U076
Ethyl methacrylate
2-Propenoic acid, 2-methyl-,
ethyl ester
97-63-2
U118
Ethyl methanesulfonate
Methanesulfonic acid, ethyl
ester
62-50-0
U119
Ethyl Ziram
Zinc, bis(diethylcarbamo-
dithioato-S,S')-
14324-55-1
U407
Famphur
Phosphorothioc acid, O-[4-
[(dimethylamino)sulfonyl]-
phenyl] O,O-dimethyl ester
52-85-7
P097
Ferbam
Iron, tris(dimethylcarbamo-
dithioato-S,S')-,
14484-64-1
U396
Fluoranthene
Same
206-44-0
U120
124
Fluorine
Same
7782-41-4
P056
Fluoroacetamide
Acetamide, 2-fluoro-
640-19-7
P057
Fluoroacetic acid, sodium salt
Acetic acid, fluoro-, sodium
salt
62-74-8
P058
Formaldehyde
Same
50-00-0
U122
Formetanate hydrochloride
Methanimidamide, N,N-
dimethyl-N'-[3-[[(methyl-
amino)carbonyl]oxy]phenyl]-,
monohydrochloride
23422-53-9
P198
Formic acid
Same
64-18-16
U123
Formparanate
Methanimidamide, N,N-
dimethyl-N'-[2-methyl-4-
[[(methylamino)carbonyl]oxy]-
phenyl]-
17702-57-7
P197
Glycidylaldehyde
Oxiranecarboxaldehyde
765-34-4
U126
Halomethanes, N.O.S.
Heptachlor
4,7-Methano-1H-
indene,1,4,5,6,7,8,8-
heptachloro-3a,4,7,7a-tetra-
hydro-
76-44-8
P059
Heptachlor epoxide
2,5-Methano-2H-indeno[1,
2b]oxirene, 2,3,4,5,6,7,7-
heptachloro-1a,1b,5,5a,6,6a-
hexahydro-,
(1aalpha,1bbeta,2alpha,5alpha,
5abeta,6beta,6aalpha)-
1024-57-3
Heptachlor epoxide (alpha, beta,
and gamma isomers)
Heptachlorodibenzofurans
Heptachlorodibenzo-p-dioxins
Hexachlorobenzene
Benzene, hexachloro-
118-74-1
U127
Hexachlorobutadiene
1,3-Butadiene, 1,1,2,3,4,4-
hexachloro-
87-68-3
U128
Hexachlorocyclo-pentadiene
1,3-Cyclopentadiene,
1,2,3,4,5,5-hexachloro-
77-47-4
U130
Hexachlorodibenzo-p-dioxins
Hexachlorodibenzofurans
Hexachloroethane
Ethane, hexachloro-
67-72-1
U131
Hexachlorophene
Phenol, 2,2'-methylene-
bis[3,4,6-trichloro-
70-30-4
U132
Hexachloropropene
1-Propene, 1,1,2,3,3,3-
hexachloro-
1888-71-7
U243
Hexaethyltetraphosphate
Tetraphosphoric acid, hexaethyl
ester
757-58-4
P062
Hydrazine
Same
302-01-2
U133
125
Hydrogen cyanide
Hydrocyanic acid
74-90-8
P063
Hydrogen fluoride
Hydrofluoric acid
7664-39-3
U134
Hydrogen sulfide
Hydrogen sulfide H2S
7783-06-4
U135
Indeno[1,2,3-cd]pyrene
Same
193-39-5
U137
3-Iodo-2-propynyl-n-butylcarbamate
Carbamic acid, butyl-, 3-iodo-
2-propynyl ester
55406-53-6
U375
Isobutyl alcohol
1-Propanol, 2-methyl-
78-83-1
U140
Isodrin
1,4:5,8-Dimethanonaph-
thalene,1,2,3,4,10,10-hexa-
chloro-1,4,4a,5,8,8a-
hexahydro-,
(1alpha,4alpha,4abeta,5beta,8b
eta,8abeta)-,
465-73-6
P060
Isolan
Carbamic acid, dimethyl-, 3-
methyl-1-(1-methylethyl)-1H-
pyrazol-5-yl ester
119-38-0
P192
Isosafrole
1,3-Benzodioxole, 5-(1-
propenyl)-
120-58-1
U141
Kepone
1,3,4-Metheno-2H-cyclobuta-
[cd]pentalen-2-one,
1,1a,3,3a,4,5,5,5a,5b,6-
decachlorooctahydro-,
143-50-0
U142
Lasiocarpine
2-Butenoic acid, 2-methyl-, 7-
[[2,3-dihydroxy-2-(1-
methoxyethyl)-3-methyl-1-
oxobutoxy]methyl]-2,3,5,7a-
tetrahydro-1H-pyrrolizin-l-yl
ester, [1S-[1-
alpha(Z),7(2S*,3R*),7aalpha]]-
303-34-1
U143
Lead
Same
7439-92-1
Lead and compounds, N.O.S.
Lead acetate
Acetic acid, lead (2+) salt
301-04-2
U144
Lead phosphate
Phosphoric acid, lead (2+) salt
(2:3)
7446-27-7
U145
Lead subacetate
Lead, bis(acetato-O)tetra-
hydroxytri-
1335-32-6
U146
Lindane
Cyclohexane, 1,2,3,4,5,6-hexa-
chloro-,
1alpha,2alpha,3beta,4alpha,5al
pha,6beta)-
58-89-9
U129
Maleic anhydride
2,5-Furandione
108-31-6
U147
Maleic hydrazide
3,6-Pyridazinedione, 1,2-
dihydro-
123-33-1
U148
Malononitrile
Propanedinitrile
109-77-3
U149
Manganese dimethyldithiocarbamate
Manganese, bis(dimethyl-
15339-36-3
P196
126
carbamodithioato-S,S')-,
Melphalan
L-Phenylalanine, 4-[bis(2-
chloroethyl)amino]-
148-82-3
U150
Mercury
Same
7439-97-6
U151
Mercury compounds, N.O.S.
Mercury fulminate
Fulminic acid, mercury (2+)
salt
628-86-4
P065
Metam Sodium
Carbamodithioic acid, methyl-,
monosodium salt
137-42-8
U384
Methacrylonitrile
2-Propenenitrile, 2-methyl-
126-98-7
U152
Methapyrilene
1,2-Ethanediamine, N,N-
dimethyl-N'-2-pyridinyl-N'-(2-
thienylmethyl)-
91-80-5
U155
Methiocarb
Phenol, (3,5-dimethyl-4-
(methylthio)-, methylcarbamate
2032-65-7
P199
Metholmyl
Ethanimidothioic acid, N-
[[(methylamino)carbonyl]oxy]-,
methyl ester
16752-77-5
P066
Methoxychlor
Benzene, 1,1'-(2,2,2-trichloro-
ethylidene)bis[4-methoxy-
72-43-5
U247
Methyl bromide
Methane, bromo-
74-83-9
U029
Methyl chloride
Methane, chloro-
74-87-3
U045
Methylchlorocarbonate
Carbonochloridic acid, methyl
ester
79-22-1
U156
Methyl chloroform
Ethane, 1,1,1-trichloro-
71-55-6
U226
3-Methylcholanthrene
Benz[j]aceanthrylene, 1,2-
dihydro-3-methyl-
56-49-5
U157
4,4'-Methylenebis(2-chloroaniline)
Benzenamine, 4,4'-methylene-
bis[2-chloro-
101-14-4
U158
Methylene bromide
Methane, dibromo-
74-95-3
U068
Methylene chloride
Methane, dichloro-
75-09-2
U080
Methyl ethyl ketone (MEK)
2-Butanone
78-93-3
U159
Methyl ethyl ketone peroxide
2-Butanone, peroxide
1338-23-4
U160
Methyl hydrazine
Hydrazine, methyl-
60-34-4
P068
Methyl iodide
Methane, iodo-
74-88-4
U138
Methyl isocyanate
Methane, isocyanato-
624-83-9
P064
2-Methyllactonitrile
Propanenitrile, 2-hydroxy-2-
methyl-
75-86-5
P069
Methyl methacrylate
2-Propenoic acid, 2-methyl-,
methyl ester
80-62-6
U162
Methyl methanesulfonate
Methanesulfonic acid, methyl
ester
66-27-3
Methyl parathion
Phosphorothioic acid, O,O-
dimethyl O-(4-nitrophenyl)
ester
298-00-0
P071
127
Methylthiouracil
4-(1H)-Pyrimidinone, 2,3-
dihydro-6-methyl-2-thioxo-
56-04-2
U164
Metolcarb
Carbamic acid, methyl-, 3-
methylphenyl ester
1129-41-5
P190
Mexacarbate
Phenol, 4-(dimethylamino)-3,5-
dimethyl-, methylcarbamate
(ester)
315-18-4
P128
Mitomycin C
Azirino[2', 3':3, 4]pyrrolo[1,
2-a]indole-4, 7-dione, 6-amino-
8-[[(aminocarbonyl)oxy]-
methyl]-1,1a,2,8,8a,8b-
hexahydro-8a-methoxy-5-
methyl-, [1a-S-
(1aalpha,8beta,8aalpha,8balpha
)]-,
50-07-7
U010
Molinate
1H-Azepine-1-carbothioic acid,
hexahydro-, S-ethyl ester
2212-67-1
U365
MNNG
Guanidine, N-methyl-N'-nitro-
N-nitroso-
70-25-7
U163
Mustard gas
Ethane, 1,1'-thiobis[2-chloro-
505-60-2
U165
Naphthalene
Same
91-20-3
U165
1,4-Naphthoquinone
1,4-Naphthalenedione
130-15-4
U166
alpha-Naphthylamine
1-Naphthalenamine
134-32-7
U167
beta-Naphthylamine
2-Naphthalenamine
91-59-8
U168
alpha-Naphthylthiourea
Thiourea, 1-naphthalenyl-
86-88-4
P072
Nickel
Same
7440-02-0
Nickel compounds, N.O.S.
Nickel carbonyl
Nickel carbonyl Ni(CO)
4
, (T-
4)-
13463-39-3
P073
Nickel cyanide
Nickel cyanide Ni(CN)
2
557-19-7
P074
Nicotine
Pyridine, 3-(1-methyl-2-
pyrrolidinyl)-, (S)-
54-11-5
P075
Nicotine salts
P075
Nitric oxide
Nitrogen oxide NO
10102-43-9
P076
p-Nitroaniline
Benzenamine, 4-nitro-
100-01-6
P077
Nitrobenzene
Benzene, nitro-
98-95-3
P078
Nitrogen dioxide
Nitrogen oxide NO
2
10102-44-0
P078
Nitrogen mustard
Ethanamine, 2-chloro-N-(2-
chloroethyl)-N-methyl-
51-75-2
Nitrogen mustard, hydrochloride
salt
Nitrogen mustard N-oxide
Ethanamine, 2-chloro-N-(2-
chloroethyl)-N-methyl-, N-
oxide
126-85-2
Nitrogen mustard, N-oxide,
128
hydrochloride salt
Nitroglycerin
1,2,3-Propanetriol, trinitrate
55-63-0
P081
p-Nitrophenol
Phenol, 4-nitro-
100-02-7
U170
2-Nitropropane
Propane, 2-nitro-
79-46-9
U171
Nitrosamines, N.O.S.
35576-91-1
N-Nitrosodi-n-butylamine
1-Butanamine, N-butyl-N-
nitroso-
924-16-3
U172
N-Nitrosodiethanolamine
Ethanol, 2,2'-(nitrosoimino)bis-
1116-54-7
U173
N-Nitrosodiethylamine
Ethanamine, N-ethyl-N-nitroso-
55-18-5
U174
N-Nitrosodimethylamine
Methanamine, N-methyl-N-
nitroso-
62-75-9
P082
N-Nitroso-N-ethylurea
Urea, N-ethyl-N-nitroso-
759-73-9
U176
N-Nitrosomethylethylamine
Ethanamine, N-methyl-N-
nitroso-
10595-95-6
N-Nitroso-N-methylurea
Urea, N-methyl-N-nitroso-
684-93-5
U177
N-Nitroso-N-methylurethane
Carbamic acid, methylnitroso-,
ethyl ester
615-53-2
U178
N-Nitrosomethylvinylamine
Vinylamine, N-methyl-N-
nitroso-
4549-40-0
P084
N-Nitrosomorpholine
Morpholine, 4-nitroso-
59-89-2
N-Nitrosonornicotine
Pyridine, 3-(1-nitroso-2-
pyrrolidinyl)-, (S)-
16543-55-8
N-Nitrosopiperidine
Piperidine, 1-nitroso-
100-75-4
U179
N-Nitrosopyrrolidine
Pyrrolidine, 1-nitroso-
930-55-2
U180
N-Nitrososarcosine
Glycine, N-methyl-N-nitroso-
13256-22-9
5-Nitro-o-toluidine
Benzenamine, 2-methyl-5-nitro-
99-55-8
U181
Octamethylpyrophosphoramide
Diphosphoramide, octamethyl-
152-16-9
P085
Osmium tetroxide
Osmium oxide OsO
4
, (T-4)
20816-12-0
P087
Oxamyl
Ethanimidothioc acid, 2-
(dimethylamino)-N-[[(methyl-
amino)carbonyl]oxy]-2-oxo-,
methyl ester
23135-22-0
P194
Paraldehyde
1,3,5-Trioxane, 2,4,6-tri-
methyl-
123-63-7
U182
Parathion
Phosphorothioic acid, O,O-
diethyl O-(4-nitrophenyl) ester
56-38-2
P089
Pebulate
Carbamothioic acid, butylethyl-
, S-propyl ester
1114-71-2
U391
Pentachlorobenzene
Benzene, pentachloro-
608-93-5
U183
Pentachlorodibenzo-p-dioxins
Pentachlorodibenzofurans
Pentachloroethane
Ethane, pentachloro-
76-01-7
U184
Pentachloronitrobenzene (PCNB)
Benzene, pentachloronitro-
82-68-8
U185
Pentachlorophenol
Phenol, pentachloro-
87-86-5
See
F027
129
Phenacetin
Acetamide, N-(4-
ethoxyphenyl)-
62-44-2
U187
Phenol
Same
108-95-2
U188
Phenylenediamine
Benzenediamine
25265-76-3
Phenylmercury acetate
Mercury, (acetato-O)phenyl-
62-38-4
P092
Phenylthiourea
Thiourea, phenyl-
103-85-5
P093
Phosgene
Carbonic dichloride
75-44-5
P095
Phosphine
Same
7803-51-2
P096
Phorate
Phosphorodithioic acid, O,O-
diethyl S-[(ethylthio)methyl]
ester
298-02-2
P094
Phthalic acid esters, N.O.S.
Phthalic anhydride
1,3-Isobenzofurandione
85-44-9
U190
Physostigmine
Pyrrolo[2,3-b]indol-5-ol,
1,2,3,3a,8,8a-hexahydro-
1,3a,8-trimethyl-, methyl-
carbamate (ester), (3aS-cis)-
57-47-6
P204
Physostigmine salicylate
Benzoic acid, 2-hydroxy-,
compound with (3aS-cis)-
1,2,3,3a,8,8a-hexahydro-
1,3a,8-trimethylpyrrolo[2,3-b]-
indol-5-yl methylcarbamate
ester (1:1)
57-64-7
P188
2-Picoline
Pyridine, 2-methyl-
109-06-8
U191
Polychlorinated biphenyls, N.O.S.
Potassium cyanide
Same
151-50-8
P098
Potassium dimethyldithiocarbamate
Carbamodithioc acid, dimethyl,
potassium salt
128-03-0
U383
Potassium n-hydroxymethyl-n-
methyl-dithiocarbamate
Carbamodithioc acid, (hydroxy-
methyl)methyl-, monopotassium
salt
51026-28-9
U378
Potassium n-methyldithiocarbamate
Carbamodithioc acid, methyl-
monopotassium salt
137-41-7
U377
Potassium silver cyanide
Argentate(1-), bis(cyano-C)-,
potassium)
506-61-6
P099
Potassium pentachlorophenate
Pentachlorophenol, potassium
salt
7778736
None
Promecarb
Phenol, 3-methyl-5-(1-methyl-
ethyl)-, methyl carbamate
2631-37-0
P201
Pronamide
Benzamide, 3,5-dichloro-N-
(1,1-dimethyl-2-propynyl)-
23950-58-5
U192
1,3-Propane sultone
1,2-Oxathiolane, 2,2-dioxide
1120-71-4
U193
Propham
Carbamic acid, phenyl-, 1-
methylethyl ester
122-42-9
U373
Propoxur
Phenol, 2-(1-methylethoxy)-,
114-26-1
U411
130
methylcarbamate
n-Propylamine
1-Propanamine
107-10-8
U194
Propargyl alcohol
2-Propyn-1-ol
107-19-7
P102
Propylene dichloride
Propane, 1,2-dichloro-
78-87-5
U083
1,2-Propylenimine
Aziridine, 2-methyl-
75-55-8
P067
Propylthiouracil
4(1H)-Pyrimidinone, 2,3-
dihydro-6-propyl-2-thioxo-
51-52-5
Prosulfocarb
Carbamothioic acid, dipropyl-,
S-(phenylmethyl) ester
52888-80-9
U387
Pyridine
Same
110-86-1
U196
Reserpine
Yohimban-16-carboxylic acid,
11,17-dimethoxy-18-[(3,4,5-tri-
methoxybenzoyl)oxy]-, methyl
ester,
(3beta,16beta,17alpha,18beta,2
0alpha)-,
50-55-5
U200
Resorcinol
1,3-Benzenediol
108-46-3
U201
Saccharin
1,2-Benzisothiazol-3(2H)-one,
1,1-dioxide
81-07-2
U202
Saccharin salts
U202
Safrole
1,3-Benzodioxole, 5-(2-
propenyl)-
94-59-7
U203
Selenium
Same
7782-49-2
Selenium compounds, N.O.S.
Selenium dioxide
Selenious acid
7783-00-8
U204
Selenium sulfide
Selenium sulfide SeS
2
7488-56-4
U205
Selenium, tetrakis(dimethyl-
dithiocarbamate
Carbamodithioic acid,
dimethyl-, tetraanhydrosulfide
with orthothioselenious acid
144-34-3
U376
Selenourea
Same
630-10-4
P103
Silver
Same
7440-22-4
Silver compounds, N.O.S.
Silver cyanide
Silver cyanide AgCN
506-64-9
P104
Silvex (2,4,5-TP)
Propanoic acid, 2-(2,4,5-
trichlorophenoxy)-
93-72-1
See
F027
Sodium cyanide
Sodium cyanide NaCN
143-33-9
P106
Sodium dibutyldithiocarbamate
Carbamodithioic acid, dibutyl-,
sodium salt
136-30-1
U379
Sodium diethyldithiocarbamate
Carbamodithioic acid, diethyl-,
sodium salt
148-18-5
U381
Sodium dimethyldithiocarbamate
Carbamodithioic acid,
dimethyl-, sodium salt
128-04-1
U382
Sodium pentachlorophenate
Pentachlorophenol, sodium salt
131522
None
Streptozotocin
D-Glucose, 2-deoxy-2-
[[methylnitrosoamino)ca-
18883-66-4
U206
131
rbonyl]amino]-
Strychnine
Strychnidin-10-one
57-24-9
P108
Strychnine salts
P108
Sulfallate
Carbamodithioic acid, diethyl-,
2-chloro-2-propenyl ester
95-06-7
U277
TCDD
Dibenzo[b,e][1,4]dioxin,
2,3,7,8-tetrachloro-
1746-01-6
Tetrabutylthiuram disulfide
Thioperoxydicarbonic diamide,
tetrabutyl
1634-02-2
U402
Tetrabutylmethylthiuram
monosulfide
Bis(dimethylthiocarbamoyl)
sulfide
97-74-5
U401
1,2,4,5-Tetrachlorobenzene
Benzene, 1,2,4,5-tetrachloro-
95-94-3
U207
Tetrachlorodibenzo-p-dioxins
Tetrachlorodibenzofurans
Tetrachloroethane, N.O.S.
Ethane, tetrachloro-, N.O.S.
25322-20-7
1,1,1,2-Tetrachloroethane
Ethane, 1,1,1,2-tetrachloro-
630-20-6
U208
1,1,2,2-Tetrachloroethane
Ethane, 1,1,2,2-tetrachloro-
79-34-5
U209
Tetrachloroethylene
Ethene, tetrachloro-
127-18-4
U210
2,3,4,6-Tetrachlorophenol
Phenol, 2,3,4,6-tetrachloro-
58-90-2
See
F027
2,3,4,6-Tetrachlorophenol,
potassium salt
Same
53535276
None
2,3,4,6-Tetrachlorophenol, sodium
salt
Same
25567559
None
Tetraethyldithiopyrophosphate
Thiodiphosphoric acid,
tetraethyl ester
3689-24-5
P109
Tetraethyl lead
Plumbane, tetraethyl-
78-00-2
P110
Tetraethylpyrophosphate
Diphosphoric acid, tetraethyl
ester
107-49-3
P111
Tetranitromethane
Methane, tetranitro-
509-14-8
P112
Thallium
Same
7440-28-0
Thallium compounds
Thallic oxide
Thallium oxide Tl
2
O
3
1314-32-5
P113
Thallium (I) acetate
Acetic acid, thallium (1+) salt
563-68-8
U214
Thallium (I) carbonate
Carbonic acid, dithallium (1+)
salt
6533-73-9
U215
Thallium (I) chloride
Thallium chloride TlCl
7791-12-0
U216
Thallium (I) nitrate
Nitric acid, thallium (1+) salt
10102-45-1
U217
Thallium selenite
Selenious acid, dithallium (1+)
salt
12039-52-0
P114
Thallium (I) sulfate
Sulfuric acid, dithallium (1+)
salt
7446-18-6
P115
Thioacetamide
Ethanethioamide
62-55-5
U218
Thiodicarb
Ethanimidothioic acid, N,N'-
[thiobis[(methylimino)-
59669-26-0
U410
132
carbonyloxy]]-bis-, dimethyl
ester
Thiofanox
2-Butanone, 3,3-dimethyl-1-
(methylthio)-, O-
[(methylamino)carbonyl]oxime
39196-18-4
P045
Thiophanate-methyl
Carbamic acid, [1,2-
phyenylenebis(iminocarbono-
thioyl)]-bis-, dimethyl ester
23564-05-8
U409
Thiomethanol
Methanethiol
74-93-1
U153
Thiophenol
Benzenethiol
108-98-5
P014
Thiosemicarbazide
Hydrazinecarbothioamide
79-19-6
P116
Thiourea
Same
62-56-6
P219
Thiram
Thioperoxydicarbonic diamide
[(H
2
N)C(S)]
2
S
2
, tetramethyl-
137-26-8
U244
Tirpate
1,3-Dithiolane-2-carbox-
aldehyde, 2,4-dimethyl-, O-
[(methylamino)carbonyl] oxime
26419-73-8
P185
Toluene
Benzene, methyl-
108-88-3
U220
Toluenediamine
Benzenediamine, ar-methyl-
25376-45-8
U221
Toluene-2,4-diamine
1,3-Benzenediamine, 4-methyl-
95-80-7
Toluene-2,6-diamine
1,3-Benzenediamine, 2-methyl-
823-40-5
Toluene-3,4-diamine
1,2-Benzenediamine, 4-methyl-
496-72-0
Toluene diisocyanate
Benzene, 1,3-diisocyanato-
methyl-
26471-62-5
U223
o-Toluidine
Benzenamine, 2-methyl-
95-53-4
U328
o-Toluidine hydrochloride
Benzeneamine, 2-methyl-,
hydrochloride
636-21-5
U222
p-Toluidine
Benzenamine, 4-methyl-
106-49-0
U353
Toxaphene
Same
8001-35-2
P123
Triallate
Carbamothioic acid, bis(1-
methylethyl)-, S-(2,3,3-tri-
chloro-2-propenyl) ester
2303-17-5
U389
1,2,4-Trichlorobenzene
Benzene, 1,2,4-trichloro-
120-82-1
1,1,2-Trichloroethane
Ethane, 1,1,2-trichloro-
79-00-5
U227
Trichloroethylene
Ethene, trichloro-
79-01-6
U228
Trichloromethanethiol
Methanethiol, trichloro-
75-70-7
P118
Trichloromonofluoromethane
Methane, trichlorofluoro-
75-69-4
U121
2,4,5-Trichlorophenol
Phenol, 2,4,5-trichloro-
95-95-4
See
F027
2,4,6-Trichlorophenol
Phenol, 2,4,6-trichloro-
88-06-2
See
F027
2,4,5-T
Acetic acid, (2,4,5-trichloro-
phenoxy)-
93-76-5
See
F027
Trichloropropane, N.O.S.
25735-29-9
1,2,3-Trichloropropane
Propane, 1,2,3-trichloro-
96-18-4
133
Triethylamine
Ethanamine, N,N-diethyl-
121-44-8
U404
O,O,O-Triethylphosphorothioate
Phosphorothioic acid, O,O,O-
triethyl ester
126-68-1
1,3,5-Trinitrobenzene
Benzene, 1,3,5-trinitro-
99-35-4
U234
Tris(l-aziridinyl)phosphine sulfide
Aziridine, 1,1',1"-phosphino-
thioylidynetris-
52-24-4
Tris(2,3-dibromopropyl) phosphate
1-Propanol, 2,3-dibromo-,
phosphate (3:1)
126-72-7
U235
Trypan blue
2,7-Naphthalenedisulfonic acid,
3,3'-[(3,3'-dimethyl[1,1'-
biphenyl]-4,4'-diyl)-
bis(azo)]bis[5-amino-4-
hydroxy-, tetrasodium salt
72-57-1
U236
Uracil mustard
2,4-(1H,3H)-Pyrimidinedione,
5-[bis(2-chloroethyl)amino]-
66-75-1
U237
Vanadium pentoxide
Vanadium oxide V
2
O
5
1314-62-1
P120
Vernolate
Carbamothioc acid, dipropyl-,
S-propyl ester
1929-77-7
U385
Vinyl chloride
Ethene, chloro-
75-01-4
U043
Warfarin
2H-1-Benzopyran-2-one, 4-
hydroxy-3-(3-oxo-1-phenyl-
butyl)-, when present at
concentrations less than 0.3%
81-81-2
U248
Warfarin
2H-1-Benzopyran-2-one, 4-
hydroxy-3-(3-oxo-1-phenyl-
butyl)-, when present at
concentrations greater than
0.3%
81-81-2
P001
Warfarin salts, when present at
concentrations less than 0.3%
U248
Warfarin salts, when present at
concentrations greater than 0.3%
P001
Zinc cyanide
Zinc cyanide Zn(CN)
2
557-21-1
P121
Zinc phosphide
Zinc phosphide P
2
Zn
3
, when
present at concentrations greater
than 10%
1314-84-7
P122
Zinc phosphide
Zinc phosphide P
2
Zn
3
, when
present at concentrations of
10% or less
1314-84-7
U249
Ziram
Zinc, bis(dimethylcarbamo-
dithioato-S,S')- (T-4)-
137-30-4
P205
Note: The abbreviation N.O.S. (not otherwise specified) signifies those members of
the general class not specifically listed by name in this Section.
134
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE G: WASTE DISPOSAL
CHAPTER I: POLLUTION CONTROL BOARD
SUBCHAPTER c: HAZARDOUS WASTE OPERATING
REQUIREMENTS
PART 722
STANDARDS APPLICABLE TO GENERATORS OF HAZARDOUS
WASTE
SUBPART A: GENERAL
Section
722.110
Purpose, Scope and Applicability
722.111
Hazardous Waste Determination
722.112
USEPA Identification Numbers
SUBPART B: THE MANIFEST
Section
722.120
General Requirements
722.121
Acquisition of Manifests
722.122
Number of Copies
722.123
Use of the Manifest
SUBPART C: PRE-TRANSPORT REQUIREMENTS
Section
722.130
Packaging
722.131
Labeling
722.132
Marking
722.133
Placarding
722.134
Accumulation Time
SUBPART D: RECORDKEEPING AND REPORTING
Section
722.140
Recordkeeping
722.141
Annual Reporting
722.142
Exception Reporting
722.143
Additional Reporting
722.144
Special Requirements for Generators of between 100 and 1000 kilograms
per month
SUBPART E: EXPORTS OF HAZARDOUS WASTE
Section
135
722.150
Applicability
722.151
Definitions
722.152
General Requirements
722.153
Notification of Intent to Export
722.154
Special Manifest Requirements
722.155
Exception Report
722.156
Annual Reports
722.157
Recordkeeping
722.158
International Agreements
SUBPART F: IMPORTS OF HAZARDOUS WASTE
Section
722.160
Imports of Hazardous Waste
SUBPART G: FARMERS
Section
722.170
Farmers
SUBPART H: TRANSFRONTIER SHIPMENTS OF HAZARDOUS
WASTE FOR RECOVERY WITHIN THE OECD
Section
722.180 Applicability
722.181 Definitions
722.182 General Conditions
722.183 Notification and Consent
722.184 Tracking Document
722.185 Contracts
722.186 Provisions Relating to Recognized Traders
722.187 Reporting and Recordkeeping
722.189 OECD Waste Lists
722.Appendix A
Hazardous Waste Manifest
AUTHORITY: Implementing Section 22.4 and authorized by Section 27 of the
Environmental Protection Act [415 ILCS 5/22.4 and 27].
SOURCE: Adopted in R81-22, 43 PCB 427, at 5 Ill. Reg. 9781, effective May 17,
1982; amended and codified in R81-22, 45 PCB 317, at 6 Ill. Reg. 4828, effective
May 17, 1982; amended in R82-18, 51 PCB 31, at 7 Ill. Reg. 2518, effective February
22, 1983; amended in R84-9 at 9 Ill. Reg. 11950, effective July 24, 1985; amended in
R85-22 at 10 Ill. Reg. 1131, effective January 2, 1986; amended in R86-1 at 10 Ill.
Reg. 14112, effective August 12, 1986; amended in R86-19 at 10 Ill. Reg. 20709,
effective December 2, 1986; amended in R86-46 at 11 Ill. Reg. 13555, effective
August 4, 1987; amended in R87-5 at 11 Ill. Reg. 19392, effective November 12,
1987; amended in R87-39 at 12 Ill. Reg. 13129, effective July 29, 1988; amended in
136
R88-16 at 13 Ill. Reg. 452, effective December 27, 1988; amended in R89-1 at 13 Ill.
Reg. 18523, effective November 13, 1989; amended in R90-10 at 14 Ill. Reg. 16653,
effective September 25, 1990; amended in R90-11 at 15 Ill. Reg. 9644, effective June
17, 1991; amended in R91-1 at 15 Ill. Reg. 14562, effective October 1, 1991;
amended in R91-13 at 16 Ill. Reg. 9833, effective June 9, 1992; amended in R92-1 at
16 Ill. Reg. 17696, effective November 6, 1992; amended in R93-4 at 17 Ill. Reg.
20822, effective November 22, 1993; amended in R95-6 at 19 Ill. Reg. 9935, effective
June 27, 1995; amended in R95-20 at 20 Ill. Reg. 11236, effective August 1, 1996;
amended in R96-10/R97-3/R97-5 at 21 Ill. Reg. ________, effective
____________________.
SUBPART A: GENERAL
Section 722.110
Purpose, Scope and Applicability
a)
These regulations establish standards for generators of hazardous waste.
b)
35 Ill. Adm. Code 721.105(c) and (d) must be used to determine the
applicability of provisions of this Part that are dependent on calculations
of the quantity of hazardous waste generated per month.
c)
A generator whothat treats, stores or disposes of hazardous waste on-site
must only comply with the following Sections of this Part with respect to
that waste: Section 722.111 for determining whether or not the
generator has a hazardous waste, Section 722.112 for obtaining an
USEPA identification number, Section 722.140(c) and (d) for
recordkeeping, Section 722.143 for additional reporting and, if
applicable, Section 722.170 for farmers.
d)
Any person whothat exports or imports hazardous waste into the United
States subject to the hazardous waste manifesting requirements of this
Part or subject to the universal waste management standards of 35 Ill.
Adm. Code 733 to or from countries listed in Section 722.158(a)(1) for
recovery must comply with the standards applicable to generators
established in this PartSubpart H of this Part.
e)
A farmer whothat generates waste pesticides which are hazardous waste
and whothat complies with all of the requirements of Section 722.151 is
not required to comply with other standards in this Part, or 35 Ill. Adm.
Code 702, 703, 724 725 or 728 with respect to such pesticides.
f)
A person whothat generates a hazardous waste as defined by 35 Ill.
Adm. Code 721 is subject to the compliance requirements and penalties
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prescribed in Title VIII and XII of the Environmental Protection Act if
he does not comply with the requirements of this Part.
g)
An owner or operator whothat initiates a shipment of hazardous waste
from a treatment, storage or disposal facility must comply with the
generator standards established in this Part.
BOARD NOTE: The provisions of Section 722.134 are applicable to
the on-site accumulation of hazardous waste by generators. Therefore,
the provisions of Section 722.134 only apply to owners or operators
whothat are shipping hazardous waste which they generated at that
facility. A generator whothat treats, stores or disposes of hazardous
waste on-site must comply with the applicable standards and permit
requirements set forth in 35 Ill. Adm. Code 702, 703, 724, 725, 726
and 728.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
SUBPART C: PRE-TRANSPORT REQUIREMENTS
Section 722.134
Accumulation Time
a)
Except as provided in subsections (d), (e), or (f) belowof this Section, a
generator is exempt from all the requirements in 35 Ill. Adm. Code
725.Subparts G and H, except for 35 Ill. Adm. Code 725.211 and
725.214, and may accumulate hazardous waste on-site for 90 days or
less without a permit or without having interim status, provided that:
1)
The waste is placed:
A)
In containers and the generator complies with 35 Ill.
Adm. Code 725.Subparts I, AA, BB, and CC; or
B)
In tanks and the generator complies with 35 Ill. Adm.
Code 725.Subparts J, (except 35 Ill. Adm. Code
725.297(c) and 725.300), AA, BB, and CC; or
C)
On drip pads and the generator complies with 35 Ill.
Adm. Code 725.Subpart W and maintains the following
records at the facility:
i)
A description of the procedures that will be
followed to ensure that all wastes are removed
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from the drip pad and associated collection system
at least once every 90 days, and
ii)
Documentation of each waste removal, including
the quantity of waste removed from the drip pad
and the sump or collection system and the date and
time of removal; or
D)
In containment buildings and the generator complies with
35 Ill. Adm. Code 725.Subpart DD (has placed its
Professional Engineer (PE) certification that the building
complies with the design standards specified in 35 Ill.
Adm. Code 725.1101 in the facility’s operating record
prior to the date of initial operation of the unit). The
owner or operator shall maintain the following records at
the facility:
i)
A written description of procedures to ensure that
each waste volume remains in the unit for no more
than 90 days, a written description of the waste
generation and management practices for the
facility showing that they are consistent with
respecting the 90 day limit, and documentation that
the procedures are complied with; or
ii)
Documentation that the unit is emptied at least
once every 90 days.;
BOARD NOTE: The “in addition” hanging
subsection that appears in the Federal rules after
40 CFR 262.34(a)(1)(iv)(B) is in the introduction
to subsection (a) aboveof this Section.
2)
The date upon which each period of accumulation begins is
clearly marked and visible for inspection on each container;
3)
While being accumulated on-site, each container and tank is
labeled or marked clearly with the words “Hazardous Waste”,;
and
4)
The generator complies with the requirements for treatment,
storage, and disposal facility owners or operators in 35 Ill. Adm.
Code 725.Subparts C and D and with 35 Ill. Adm. Code 725.116
and 728.107(a)(4).
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b)
A generator that accumulates hazardous waste for more than 90 days is
an operator of a storage facility and is subject to the requirements of 35
Ill. Adm. Code 724 and 725 and the permit requirements of 35 Ill.
Adm. Code 702, 703 and 705 unless the generator has been granted an
extension of the 90-day period. If hazardous wastes must remain on-site
for longer than 90 days due to unforeseen, temporary, and
uncontrollable circumstances, the generator may seek an extension of up
to 30 days by means of a variance or provisional variance, pursuant to
Section 37 of the Environmental Protection Act and 35 Ill. Adm. Code
180 (Agency procedural regulations).
c)
Accumulation near the point of generation.
1)
A generator may accumulate as much as 55 gallons of hazardous
waste or one quart of acutely hazardous waste listed in 35 Ill.
Adm. Code 721.133(e) in containers at or near any point of
generation where wastes initially accumulate that is under the
control of the operator of the process generating the waste
without a permit or interim status and without complying with
subsection (a) aboveof this Section, provided the generator:
A)
Complies with 35 Ill. Adm. Code 725.271, 725.272 and
725.273(a), and
B)
Marks the generator’s containers either with the words
“Hazardous Waste” or with other words that identify the
contents of the containers.
2)
A generator that accumulates either hazardous waste or acutely
hazardous waste listed in 35 Ill. Adm. Code 721.133(e) in excess
of the amounts listed in subsection (c)(1) aboveof this Section at
or near any point of generation must, with respect to that amount
of excess waste, comply within three days with subsection (a)
aboveof this Section or other applicable provisions of this
Chapter. During the three day period the generator must
continue to comply with subsection (c)(1) aboveof this Section.
The generator must mark the container holding the excess
accumulation of hazardous waste with the date the excess amount
began accumulating.
d)
A generator that generates greater than 100 kilograms but less than 1000
kilograms of hazardous waste in a calendar month may accumulate
hazardous waste on-site for 180 days or less without a permit or without
having interim status provided that:
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1)
The quantity of waste accumulated on-site never exceeds 6000
kilograms;
2)
The generator complies with the requirements of 35 Ill. Adm.
Code 725.Subpart I (except 35 Ill. Adm. Code 725.276 and
725.278);
3)
The generator complies with the requirements of 35 Ill. Adm.
Code 725.301;
4)
The generator complies with the requirements of subsections
(a)(2) and (c)(3) aboveof this Section, 35 Ill. Adm. Code
725.Subpart C, and 35 Ill. Adm. Code 728.107(a)(4); and
5)
The generator complies with the following requirements:
A)
At all times there must be at least one employee either on
the premises or on call (i.e., available to respond to an
emergency by reaching the facility within a short period
of time) with the responsibility for coordinating all
emergency response measures specified in subsection
(d)(5)(D) belowof this Section. The employee is the
emergency coordinator.
B)
The generator shall post the following information next to
the telephone:
i)
The name and telephone number of the emergency
coordinator;
ii)
Location of fire extinguishers and spill control
material and, if present, fire alarm; and
iii)
The telephone number of the fire department,
unless the facility has a direct alarm.
C)
The generator shall ensure that all employees are
thoroughly familiar with proper waste handling and
emergency procedures, relevant to their responsibilities
during normal facility operations and emergencies;.
D)
The emergency coordinator or designee shall respond to
any emergencies that arise. The applicable responses are
as follows:
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i)
In the event of a fire, call the fire department or
attempt to extinguish it using a fire extinguisher;
ii)
In the event of a spill, contain the flow of
hazardous waste to the extent possible and, as soon
as is practicable, clean up the hazardous waste and
any contaminated materials or soil;
iii)
In the event of a fire, explosion, or other release
that could threaten human health outside the
facility, or when the generator has knowledge that
a spill has reached surface water, the generator
shall immediately notify the National Response
Center (using its 24-hour toll free number 800-
424-8802). The report must include the following
information: the name, address, and U.S. EPA
identification number (35 Ill. Adm. CodeSection
722.112 of this Part) of the generator; the date,
time, and type of incident (e.g., spill or fire); the
quantity and type of hazardous waste involved in
the incident; the extent of injuries, if any; and the
estimated quantity and disposition of recoverable
materials, if any.
e)
A generator that generates greater than 100 kilograms but less than 1000
kilograms of hazardous waste in a calendar month and that must
transport the waste or offer the waste for transportation over a distance
of 200 miles or more for off-site treatment, storage, or disposal may
accumulate hazardous waste on-site for 270 days or less without a permit
or without having interim status, provided that the generator complies
with the requirements of subsection (d) aboveof this Section.
f)
A generator that generates greater than 100 kilograms but less than 1000
kilograms of hazardous waste in a calendar month and that accumulates
hazardous waste in quantities exceeding 6000 kg or accumulates
hazardous waste for more than 180 days (or for more than 270 days if
the generator must transport the waste or offer the waste for
transportation over a distance of 200 miles or more) is an operator of a
storage facility and is subject to the requirements of 35 Ill. Adm. Code
724 and 725 and the permit requirements of 35 Ill. Adm. Code 703
unless the generator has been granted an extension to the 180-day (or
270-day if applicable) period. If hazardous wastes must remain on-site
for longer than 180 days (or 270 days if applicable) due to unforeseen,
temporary, and uncontrollable circumstances, the generator may seek an
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extension of up to 30 days by means of variance or provisional variance
pursuant to Section 37 of the Environmental Protection Act.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
SUBPART E: EXPORTS OF HAZARDOUS WASTE
Section 722.153
Notification of Intent to Export
a)
The Board incorporates by reference 40 CFR 262.53 (199196), as
amended at 56 Fed. Reg. 43705, September 4, 1991. This Part
incorporates no future editions or amendments.
b)
A primary exporter of hazardous waste shall notify USEPA in
accordance with 40 CFR 262.53 (1996).
c)
The primary exporter shall send the Agency a copy of theeach notice
sent to USEPA pursuant to subsection (b) aboveof this Section.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 722.156
Annual Reports
a)
The Board incorporates by reference 40 CFR 262.56 (199196), as
amended at 56 Fed. Reg. 43705, September 4, 1991. This Part
incorporates no future editions or amendments.
b)
Primary exporters of hazardous waste shall file with USEPA, no later
than March 1 of each year, a report as specified in 40 CFR 262.56
(1996).
c)
The primary exporter shall send the Agency a copy of theeach report
sent to USEPA.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 722.158 International Agreements
a)
Any person that exports or imports hazardous waste subject to either the
manifest requirements of this Part or the universal waste management
standards of 35 Ill. Adm. Code 733 which is shipped to or from
designated member countries of the Organization for Economic
Cooperation and Development (OECD), as defined in subsection (a)(1)
of this Section, for purposes of recovery is subject to the requirements of
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722.Subpart H. The requirements of Subparts E and F of this Part do
not apply where 722.Subpart H applies.
1)
For the purposes of this Subpart, the designated OECD countries
are Australia, Austria, Belgium, Denmark, Finland, France,
Germany, Greece, Iceland, Ireland, Italy, Japan, Luxembourg,
Netherlands, New Zealand, Norway, Portugal, Spain, Sweden,
Switzerland, Turkey, the United Kingdom, and the United States.
2)
Only for the purposes of transit under this Subpart, Canada and
Mexico are considered OECD member countries.
b)
Any person that exports hazardous waste to or imports hazardous waste
from any designated OECD member country for purposes other than
recovery (e.g., incineration, disposal), Mexico (for any purpose), or
Canada (for any purpose) remains subject to the requirements of
Subparts E and F of this Part.
(Source: Added at 21 Ill. Reg. ________, effective ______________________)
SUBPART H: TRANSFRONTIER SHIPMENTS OF HAZARDOUS
WASTE FOR RECOVERY WITHIN THE OECD
Section 722.180 Applicability
a)
The requirements of this Subpart apply to imports and exports of wastes
that are considered hazardous under U.S. national procedures and which
are destined for recovery operations in any of the countries listed in
Section 722.158(a)(1). A waste is considered hazardous under U.S.
national procedures if it meets the definition of hazardous waste in 35
Ill. Adm. Code 721.103 and it is subject to either the manifesting
requirements in Subpart B of this Part, to the universal waste
management standards of 35 Ill. Adm. Code 733.
b)
Any person (notifier, consignee, or recovery facility operator) that mixes
two or more wastes (including hazardous and non-hazardous wastes) or
otherwise subjects two or more wastes (including hazardous and non-
hazardous wastes) to physical or chemical transformation operations, and
thereby creates a new hazardous waste, becomes a generator and
assumes all subsequent generator duties under this Subchapter and any
notifier duties under this Subpart, as applicable.
(Source: Added at 21 Ill. Reg. ________, effective ______________________)
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Section 722.181 Definitions
The following definitions apply to this Subpart:
“Competent authorities” means the regulatory authorities of concerned
countries having jurisdiction over transfrontier movements of wastes
destined for recovery operations.
“Concerned countries” means the exporting and importing OECD
member countries and any OECD member countries of transit.
“Consignee” means the person to whom possession or other form of
legal control of the waste is assigned at the time the waste is received in
the importing country.
“Country of transit” means any designated OECD country in Section
722.158(a)(1) and (a)(2) other than the exporting or importing country
across which a transfrontier movement of wastes is planned or takes
place.
“Exporting country” means any designated OECD member country in
Section 722.158(a)(1) from which a transfrontier movement of wastes is
planned or has commenced.
“Importing country” means any designated OECD country in Section
722.158(a)(1) to which a transfrontier movement of wastes is planned or
takes place for the purpose of submitting the wastes to recovery
operations therein.
“Notifier” means the person under the jurisdiction of the exporting
country that has, or will have at the time the planned transfrontier
movement commences, possession or other forms of legal control of the
wastes and that proposes their transfrontier movement for the ultimate
purpose of submitting them to recovery operations. When the United
States (U.S.) is the exporting country, notifier is interpreted to mean a
person domiciled in the U.S.
“OECD area” means all land or marine areas under the national
jurisdiction of any designated OECD member country in Section
722.158. When the regulations refer to shipments to or from an OECD
country, this means OECD area.
“Recognized trader” means a person that, with appropriate authorization
of concerned countries, acts in the role of principal to purchase and
subsequently sell wastes; this person has legal control of such wastes
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from time of purchase to time of sale; such a person may act to arrange
and facilitate transfrontier movements of wastes destined for recovery
operations.
“Recovery facility” means an entity which, under applicable domestic
law, is operating or is authorized to operate in the importing country to
receive wastes and to perform recovery operations on them.
“Recovery operations” means activities leading to resource recovery,
recycling, reclamation, direct re-use, or alternative uses, as listed in
Table 2.B of the Annex of OECD Council Decision C(88)90(Final) of
27 May 1988, incorporated by reference in 35 Ill. Adm. Code 720.111,
which include the following activities:
R1
Use as a fuel (other than in direct incineration) or other
means to generate energy,
R2
Solvent reclamation or regeneration,
R3
Recycling or reclamation of organic substances which are
not used as solvents,
R4
Recycling or reclamation of metals and metal compounds,
R5
Recycling or reclamation of other inorganic materials,
R6
Regeneration of acids or bases,
R7
Recovery of components used for pollution control,
R8
Recovery of components from catalysts,
R9
Used oil re-refining or other reuses of previously used oil,
R10
Land treatment resulting in benefit to agriculture or
ecological improvement,
R11
Uses of residual materials obtained from any of the
operations numbered R1 through R10,
R12
Exchange of wastes for submission to any of the
operations numbered R1 through R11, and
R13
Accumulation of material intended for any operation in
Table 2.B.
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“Transfrontier movement” means any shipment of wastes destined for
recovery operations from an area under the national jurisdiction of one
OECD member country to an area under the national jurisdiction of
another OECD member country.
(Source: Added at 21 Ill. Reg. ________, effective ______________________)
Section 722.182 General Conditions
a)
Scope. The level of control for exports and imports of waste is indicated
by assignment of the waste to a green, amber, or red list and by U.S.
national procedures, as defined in Section 722.180(a). The green,
amber, and red lists are incorporated by reference in 35 Ill. Adm. Code
720.111(b).
1)
Wastes on the green list are subject to existing controls normally
applied to commercial transactions, except as provided below:
A)
Green-list wastes that are considered hazardous under
U.S. national procedures are subject to amber-list
controls.
B)
Green-list wastes that are sufficiently contaminated or
mixed with amber-list wastes, such that the waste or waste
mixture is considered hazardous under U.S. national
procedures, are subject to amber-list controls.
C)
Green-list wastes that are sufficiently contaminated or
mixed with other wastes subject to red-list controls, such
that the waste or waste mixture is considered hazardous
under U.S. national procedures, must be handled in
accordance with the red-list controls.
2)
Wastes on the amber list that are considered hazardous under
U.S. national procedures, as defined in Section 722.180(a), are
subject to the amber-list controls of this Subpart. If amber-list
wastes are sufficiently contaminated or mixed with other wastes
subject to red-list controls, such that the waste or waste mixture
is considered hazardous under U.S. national procedures, the
wastes must be handled in accordance with the red-list controls.
3)
Wastes on the red list that are considered hazardous under U.S.
national procedures, as defined in Section 722.180(a), are subject
to the red-list controls of this Subpart.
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BOARD NOTE: Some wastes on the amber or red lists are not
listed or otherwise identified as hazardous under RCRA (e.g.,
polychlorinated biphenyls) and therefore are not subject to the
amber- or red-list controls of this Subpart. Regardless of the
status of the waste under RCRA, however, other federal
environmental statutes (e.g., the Toxic Substances Control Act)
may restrict certain waste imports or exports. Such restrictions
continue to apply without regard to this Subpart.
4)
Wastes not yet assigned to a list are eligible for transfrontier
movements, as follows:
A)
If such wastes are considered hazardous under U.S.
national procedures, as defined in Section 722.180(a),
these wastes are subject to the red-list controls; or
B)
If such wastes are not considered hazardous under U.S.
national procedures, as defined in Section 722.180(a),
such wastes may move as though they appeared on the
green list.
b)
General conditions applicable to transfrontier movements of hazardous
waste.
1)
The waste must be destined for recovery operations at a facility
that, under applicable domestic law, is operating or is authorized
to operate in the importing country;
2)
The transfrontier movement must be in compliance with
applicable international transport agreements; and
BOARD NOTE: These international agreements include, but are
not limited to, the Chicago Convention (1944), ADR (1957),
ADNR (1970), MARPOL Convention (1973/1978), SOLAS
Convention (1974), IMDG Code (1985), COTIF (1985), and
RID (1985).
3)
Any transit of waste through a non-OECD member country must
be conducted in compliance with all applicable international and
national laws and regulations.
c)
Provisions relating to re-export for recovery to a third country.
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1)
Re-export of wastes subject to the amber-list control system from
the U.S., as the importing country, to a third country listed in
Section 722.158(a)(1) may occur only after a notifier in the U.S.
provides notification to and obtains consent of the competent
authorities in the third country, the original exporting country,
and new transit countries. The notification must comply with the
notice and consent procedures in Section 722.183 for all
concerned countries and the original exporting country. The
competent authorities of the original exporting country, as well as
the competent authorities of all other concerned countries, have
30 days to object to the proposed movement.
A)
The 30-day period begins once the competent authorities
of both the initial exporting country and new importing
country issue Acknowledgments of Receipt of the
notification.
B)
The transfrontier movement may commence if no
objection has been lodged after the 30-day period has
passed or immediately after written consent is received
from all relevant OECD importing and transit countries.
2)
Re-export of waste subject to the red-list control system from the
original importing country to a third country listed in Section
722.158(a)(1) may occur only following notification of the
competent authorities of the third country, the original exporting
country, and new transit countries by a notifier in the original
importing country in accordance with Section 722.183. The
transfrontier movement may not proceed until receipt by the
original importing country of written consent from the competent
authorities of the third country, the original exporting country,
and new transit countries.
3)
In the case of re-export of amber- or red-list wastes to a country
other than those in Section 722.158(a)(1), notification to and
consent of the competent authorities of the original OECD
member country of export and any OECD member countries of
transit is required as specified in subsections (c)(1) and (c)(2) of
this Section in addition to compliance with all international
agreements and arrangements to which the first importing OECD
member country is a party and all applicable regulatory
requirements for exports from the first importing country.
(Source: Added at 21 Ill. Reg. ________, effective ______________________)
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Section 722.183 Notification and Consent
a)
Applicability. Consent must be obtained from the competent authorities
of the relevant OECD importing and transit countries prior to exporting
hazardous waste destined for recovery operations subject to this Subpart.
Hazardous wastes subject to amber-list controls are subject to the
requirements of subsection (b) of this Section; hazardous wastes subject
to red-list controls are subject to the requirements of subsection (c) of
this Section; and wastes not identified on any list are subject to the
requirements of subsection (d) of this Section.
b)
Amber-list wastes. The export from the U.S. of hazardous wastes, as
described in Section 722.180(a), that appear on the amber list is
prohibited unless the notification and consent requirements of subsection
(b)(1) or subsection (b)(2) of this Section are met.
1)
Transactions requiring specific consent:
A)
Notification. At least 45 days prior to commencement of
the transfrontier movement, the notifier must provide
written notification in English of the proposed
transfrontier movement to the Office of Enforcement and
Compliance Assurance, Office of Compliance,
Enforcement Planning, Targeting and Data Division
(2222A), Environmental Protection Agency, 401 M St.,
SW, Washington, DC 20460, and the Illinois
Environmental Protection Agency, Bureau of Land,
Division of Land Pollution Control, P.O. Box 19276,
Springfield, IL 62794-9276, with the words “Attention:
OECD Export Notification” prominently displayed on the
envelope. This notification must include all of the
information identified in subsection (e) of this Section. In
cases where wastes having similar physical and chemical
characteristics, the same United Nations classification,
and the same RCRA waste codes are to be sent
periodically to the same recovery facility by the same
notifier, the notifier may submit one notification of intent
to export these wastes in multiple shipments during a
period of up to one year.
B)
Tacit consent. If no objection has been lodged by any
concerned country (i.e., exporting, importing, or transit
countries) to a notification provided pursuant to subsection
(b)(1)(A) of this Section within 30 days after the date of
issuance of the Acknowledgment of Receipt of notification
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by the competent authority of the importing country, the
transfrontier movement may commence. Tacit consent
expires one calendar year after the close of the 30 day
period; renotification and renewal of all consents is
required for exports after that date.
C)
Written consent. If the competent authorities of all the
relevant OECD importing and transit countries provide
written consent in a period less than 30 days, the
transfrontier movement may commence immediately after
all necessary consents are received. Written consent
expires for each relevant OECD importing and transit
country one calendar year after the date of that country’s
consent unless otherwise specified; renotification and
renewal of each expired consent is required for exports
after that date.
2)
Shipments to facilities pre-approved by the competent authorities
of the importing countries to accept specific wastes for recovery:
A)
The notifier must provide USEPA and the Agency the
information identified in subsection (e) of this Section in
English, at least 10 days in advance of commencing
shipment to a pre-approved facility. The notification
should indicate that the recovery facility is pre-approved,
and may apply to a single specific shipment or to multiple
shipments as described in subsection (b)(1)(A) of this
Section. This information must be sent to the Office of
Enforcement and Compliance Assurance, Office of
Compliance, Enforcement Planning, Targeting and Data
Division (2222A), Environmental Protection Agency, 401
M St., SW., Washington, DC 20460, and the Illinois
Environmental Protection Agency, Bureau of Land,
Division of Land Pollution Control, P.O. Box 19276,
Springfield, IL 62794-9276, with the words “OECD
Export Notification--Pre-approved Facility” prominently
displayed on the envelope.
B)
Shipments may commence after the notification required
in subsection (b)(1)(A) of this Section has been received
by the competent authorities of all concerned countries,
unless the notifier has received information indicating that
the competent authorities of one or more concerned
countries objects to the shipment.
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c)
Red-list wastes. The export from the U.S. of hazardous wastes, as
described in Section 722.180(a), that appear on the red list is prohibited
unless notice is given pursuant to subsection (b)(1)(A) of this Section and
the notifier receives written consent from the importing country and any
transit countries prior to commencement of the transfrontier movement.
d)
Unlisted wastes. Wastes not assigned to the green, amber, or red list
that are considered hazardous under U.S. national procedures, as defined
in Section 722.180(a), are subject to the notification and consent
requirements established for red-list wastes in accordance with
subsection (c) of this Section. Unlisted wastes that are not considered
hazardous under U.S. national procedures, as defined in Section
722.180(a), are not subject to amber or red controls when exported or
imported.
e)
Notification information. Notifications submitted under this Section
must include:
1)
Serial number or other accepted identifier of the notification
form;
2)
Notifier name and USEPA identification number (if applicable),
address, and telephone and telefax numbers;
3)
Importing recovery facility name, address, telephone and telefax
numbers, and technologies employed;
4)
Consignee name (if not the owner or operator of the recovery
facility), address, and telephone and telefax numbers; whether the
consignee will engage in waste exchange or storage prior to
delivering the waste to the final recovery facility; and
identification of recovery operations to be employed at the final
recovery facility;
5)
Intended transporters or their agents;
6)
Country of export and relevant competent authority and point of
departure;
7)
Countries of transit and relevant competent authorities and points
of entry and departure;
8)
Country of import and relevant competent authority and point of
entry;
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9)
Statement of whether the notification is a single notification or a
general notification. If general, include period of validity
requested;
10)
Date foreseen for commencement of transfrontier movement;
11)
Designation of waste type(s) from the appropriate list (amber or
red and waste list code), descriptions of each waste type,
estimated total quantity of each, RCRA waste code, and United
Nations number for each waste type; and
12)
Certification/Declaration signed by the notifier that states as
follows:
“I certify that the above information is complete and correct to
the best of my knowledge. I also certify that legally-enforceable
written contractual obligations have been entered into, and that
any applicable insurance or other financial guarantees are or shall
be in force covering the transfrontier movement.
Name: _____________________________________
Signature: __________________________________
Date: _____________________________________”
BOARD NOTE: The U.S. does not currently require financial
assurance; however, U.S. exporters may be asked by other
governments to provide and certify to such assurance as a
condition of obtaining consent to a proposed movement.
(Source: Added at 21 Ill. Reg. ________, effective ______________________)
Section 722.184 Tracking Document
a)
All U.S. parties subject to the contract provisions of Section 722.185
must ensure that a tracking document meeting the conditions of
subsection (b) of this Section accompanies each transfrontier shipment of
wastes subject to amber-list or red-list controls from the initiation of the
shipment until it reaches the final recovery facility, including cases in
which the waste is stored or exchanged by the consignee prior to
shipment to the final recovery facility, except as provided in Section
262.184(a)(1) and (a)(2).
153
1)
For shipments of hazardous waste within the U.S. solely by water
(bulk shipments only), the generator must forward the tracking
document with the manifest to the last water (bulk shipment)
transporter to handle the waste in the U.S. if exported by water
(in accordance with the manifest routing procedures at Section
722.123(c)).
2)
For rail shipments of hazardous waste within the U.S. which
originate at the site of generation, the generator must forward the
tracking document with the manifest (in accordance with the
routing procedures for the manifest in Section 722.123(d)) to the
next non-rail transporter, if any, or the last rail transporter to
handle the waste in the U.S. if exported by rail.
b)
The tracking document must include all information required under
Section 722.183 (for notification) and the following:
1)
The date shipment commenced;
2)
The name (if not notifier), address, and telephone and telefax
numbers of primary exporter;
3)
The company name and USEPA identification number of all
transporters;
4)
Identification (license, registered name or registration number) of
means of transport, including types of packaging;
5)
Any special precautions to be taken by transporters;
6)
A certification or declaration signed by notifier that no objection
to the shipment has been lodged as follows:
“I certify that the above information is complete and correct to
the best of my knowledge. I also certify that legally-enforceable
written contractual obligations have been entered into, that any
applicable insurance or other financial guarantees are or shall be
in force covering the transfrontier movement, and that:”
“1. All necessary consents have been received;” OR
“2. The shipment is directed at a recovery facility within the
OECD area and no objection has been received from any of the
concerned countries within the 30 day tacit consent period;” OR
154
“3. The shipment is directed at a recovery facility pre-authorized
for that type of waste within the OECD area, such an
authorization has not been revoked, and no objection has been
received from any of the concerned countries.”
(delete sentences that are not applicable)
Name: _____________________________________
Signature: __________________________________
Date: _____________________________________”; and
7)
The appropriate signatures for each custody transfer (e.g.,
transporter, consignee, and owner or operator of the recovery
facility).
c)
Notifiers also must comply with the special manifest requirements of
Section 722.154(a), (b), (c), (e), and (i) and consignees must comply
with the import requirements of Subpart F of this Part.
d)
Each U.S. person that has physical custody of the waste from the time
the movement commences until it arrives at the recovery facility must
sign the tracking document (e.g., transporter, consignee, and owner or
operator of the recovery facility).
e)
Within three working days of the receipt of imports subject to this
Subpart, the owner or operator of the U.S. recovery facility must send
signed copies of the tracking document to the notifier, to the Office of
Enforcement and Compliance Assurance, Office of Compliance,
Enforcement Planning, Targeting and Data Division (2222A),
Environmental Protection Agency, 401 M St., SW., Washington, DC
20460, and to the competent authorities of the exporting and transit
countries.
(Source: Added at 21 Ill. Reg. ________, effective ______________________)
Section 722.185 Contracts
a)
Transfrontier movements of hazardous wastes subject to amber or red
control procedures are prohibited unless they occur under the terms of a
valid written contract, chain of contracts, or equivalent arrangements
(when the movement occurs between parties controlled by the same
corporate or legal entity). Such contracts or equivalent arrangements
must be executed by the notifier and the owner or operator of the
155
recovery facility, and must specify responsibilities for each. Contracts
or equivalent arrangements are valid for the purposes of this Section only
if persons assuming obligations under the contracts or equivalent
arrangements have appropriate legal status to conduct the operations
specified in the contract or equivalent arrangement.
b)
Contracts or equivalent arrangements must specify the following names
and USEPA identification numbers, where available:
1)
The generator of each type of waste;
2)
Each person that will have physical custody of the wastes;
3)
Each person that will have legal control of the wastes; and
4)
The recovery facility.
c)
Contracts or equivalent arrangements must specify which party to the
contract will assume responsibility for alternate management of the
wastes if its disposition cannot be carried out as described in the
notification of intent to export. In such cases, contracts must specify the
following:
1)
That the person having actual possession or physical control over
the wastes will immediately inform the notifier and the competent
authorities of the exporting and importing countries and, if the
wastes are located in a country of transit, the competent
authorities of that country; and
2)
That the person specified in the contract will assume
responsibility for the adequate management of the wastes in
compliance with applicable laws and regulations including, if
necessary, arranging their return to the original country of
export.
d)
Contracts must specify that the consignee will provide the notification
required in Section 722.182(c) prior to re-export of controlled wastes to
a third country.
e)
Contracts or equivalent arrangements must include provisions for
financial guarantees, if required by the competent authorities of any
concerned country, in accordance with applicable national or
international law requirements.
156
BOARD NOTE: Financial guarantees so required are intended to
provide for alternative recycling, disposal, or other means of sound
management of the wastes in cases where arrangements for the shipment
and the recovery operations cannot be carried out as foreseen. The U.S.
does not require such financial guarantees at this time; however, some
OECD countries do. It is the responsibility of the notifier to ascertain
and comply with such requirements; in some cases, transporters or
consignees may refuse to enter into the necessary contracts absent
specific references or certifications to financial guarantees.
f)
Contracts or equivalent arrangements must contain provisions requiring
each contracting party to comply with all applicable requirements of this
Subpart.
g)
Upon request by USEPA or the Agency, U.S. notifiers, consignees, or
recovery facilities shall submit to USEPA and the Agency copies of
contracts, chain of contracts, or equivalent arrangements (when the
movement occurs between parties controlled by the same corporate or
legal entity). Information contained in the contracts or equivalent
arrangements for which a claim of confidentiality is asserted in
accordance with 35 Ill. Adm. Code 120 will be treated as confidential
and will be disclosed by the Agency only as provided in 35 Ill. Adm.
Code 120.
BOARD NOTE: Although the U.S. does not require routine submission
of contracts at this time, OECD Council Decision C(92)39/FINAL
allows members to impose such requirements. When other OECD
countries require submission of partial or complete copies of the contract
as a condition to granting consent to proposed movements, USEPA or
the Agency will request the required information; absent submission of
such information, some OECD countries may deny consent for the
proposed movement.
(Source: Added at 21 Ill. Reg. ________, effective ______________________)
Section 722.186 Provisions Relating to Recognized Traders
a)
A recognized trader that takes physical custody of a waste and conducts
recovery operations (including storage prior to recovery) is acting as the
owner or operator of a recovery facility and must be so authorized in
accordance with all applicable federal laws.
b)
A recognized trader acting as a notifier or consignee for transfrontier
shipments of waste must comply with all the notifier or consignee
requirements of this Subpart.
157
(Source: Added at 21 Ill. Reg. ________, effective ______________________)
Section 722.187 Reporting and Recordkeeping
a)
Annual reports. For all waste movements subject to this Subpart,
persons (e.g., notifiers, recognized traders) that meet the definition of
primary exporter in Section 722.151 shall file an annual report with the
Office of Enforcement and Compliance Assurance, Office of
Compliance, Enforcement Planning, Targeting and Data Division
(2222A), U.S. Environmental Protection Agency, 401 M St., SW.,
Washington, DC 20460 and the Illinois Environmental Protection
Agency, Bureau of Land, Division of Land Pollution Control, P.O. Box
19276, Springfield, IL 62706-9276, no later than March 1 of each year
summarizing the types, quantities, frequency, and ultimate destination of
all such hazardous waste exported during the previous calendar year. (If
the primary exporter is required to file an annual report for waste
exports that are not covered under this Subpart, the person filing may
include all export information in one report provided the following
information on exports of waste destined for recovery within the
designated OECD member countries is contained in a separate Section).
Such reports shall include the following information:
1)
The USEPA identification number, name, and mailing and site
address of the notifier filing the report;
2)
The calendar year covered by the report;
3)
The name and site address of each final recovery facility;
4)
By final recovery facility, for each hazardous waste exported, a
description of the hazardous waste, the USEPA hazardous waste
number (from 35 Ill. Adm. Code 721.Subpart C or 721.Subpart
D), the designation of waste type(s) from the OECD waste list
and applicable waste code from the OECD lists, DOT hazard
class, the name and USEPA identification number (where
applicable) for each transporter used, the total amount of
hazardous waste shipped pursuant to this Subpart, and number of
shipments pursuant to each notification;
5)
In even numbered years, for each hazardous waste exported,
except for hazardous waste produced by exporters of greater than
100 kilograms (kg) but less than 1000 kg in a calendar month,
and except for hazardous waste for which information was
already provided pursuant to Section 722.141:
158
A)
A description of the efforts undertaken during the year to
reduce the volume and toxicity of waste generated; and
B)
A description of the changes in volume and toxicity of the
waste actually achieved during the year in comparison to
previous years to the extent such information is available
for years prior to 1984; and
6)
A certification signed by the person acting as primary exporter
that states as follows:
“I certify under penalty of law that I have personally examined
and am familiar with the information submitted in this and all
attached documents, and that based on my inquiry of those
individuals immediately responsible for obtaining the
information, I believe that the submitted information is true,
accurate, and complete. I am aware that there are significant
penalties for submitting false information including the possibility
of fine and imprisonment.”
b)
Exception reports. Any person that meets the definition of primary
exporter in Section 722.151 shall file with USEPA and the Agency an
exception report in lieu of the requirements of Section 722.142 if any of
the following occurs:
1)
The person has not received a copy of the tracking documentation
signed by the transporter stating point of departure of the waste
from the United States within 45 days from the date it was
accepted by the initial transporter;
2)
Within 90 days from the date the waste was accepted by the
initial transporter, the notifier has not received written
confirmation from the recovery facility that the hazardous waste
was received; or
3)
The waste is returned to the United States.
c)
Recordkeeping.
1)
Persons that meet the definition of primary exporter in Section
722.151 shall keep the following records:
A)
A copy of each notification of intent to export and all
written consents obtained from the competent authorities
159
of concerned countries, for a period of at least three years
from the date the hazardous waste was accepted by the
initial transporter;
B)
A copy of each annual report, for a period of at least three
years from the due date of the report; and
C)
A copy of any exception reports and a copy of each
confirmation of delivery (i.e., tracking documentation)
sent by the recovery facility to the notifier, for at least
three years from the date the hazardous waste was
accepted by the initial transporter or received by the
recovery facility, whichever is applicable.
2)
The periods of retention referred to in this Section are extended
automatically during the course of any unresolved enforcement
action regarding the regulated activity or as requested by USEPA
or the Agency.
(Source: Added at 21 Ill. Reg. ________, effective ______________________)
Section 722.189 OECD Waste Lists
a)
General. For the purposes of this Subpart, a waste is considered
hazardous under U.S. national procedures, and hence subject to this
Subpart, if the waste:
1)
Meets the federal definition of hazardous waste in 35 Ill. Adm.
Code 721.103; and
2)
Is subject to either the hazardous waste manifesting requirements
of Subpart B of this Part or the universal waste management
standards of 35 Ill. Adm. Code 733.
b)
If a waste is hazardous under subsection (a) of this Section and it appears
on the amber or red list, it is subject to either the amber- or red-list
requirements, as appropriate.
c)
If a waste is hazardous under subsection (a) of this Section and it does
not appear on either the amber or red list, it is subject to the red-list
requirements.
d)
The appropriate control procedures for hazardous wastes and hazardous
waste mixtures are addressed in Section 722.182.
160
e)
The OECD Green List of Wastes (revised May 1994), Amber List of
Wastes (revised May 1993), and Red List of Wastes (revised May 1993),
as set forth in Appendix 3, Appendix 4 and Appendix 5, respectively, to
the OECD Council Decision C(92)39/FINAL (Concerning the Control
of Transfrontier Movements of Wastes Destined for Recovery
Operations), incorporated by reference in 35 Ill. Adm. Code 720.111.
(Source: Added at 21 Ill. Reg. ________, effective ______________________)
TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE G: WASTE DISPOSAL
CHAPTER I: POLLUTION CONTROL BOARD
SUBCHAPTER c: HAZARDOUS WASTE OPERATING
REQUIREMENTS
PART 723
STANDARDS APPLICABLE TO TRANSPORTERS OF
HAZARDOUS WASTE
SUBPART A: GENERAL
Section
723.110
Scope
723.111
USEPA Identification Number
723.112
Transfer Facility Requirements
SUBPART B: COMPLIANCE WITH THE MANIFEST SYSTEM
AND RECORDKEEPING
Section
723.120
The Manifest System
723.121
Compliance with the Manifest
723.122
Recordkeeping
SUBPART C: HAZARDOUS WASTE DISCHARGES
Section
723.130
Immediate Action
723.131
Discharge Clean Up
AUTHORITY: Implementing Section 22.4 and authorized by Section 27 of the
Environmental Protection Act [415 ILCS 5/22.4 and 27].
SOURCE: Adopted in R81-22, 43 PCB 427, at 5 Ill. Reg. 9781, effective May 17,
1982; amended and codified in R81-22, 45 PCB 17, at 6 Ill. Reg. 4828, effective May
17, 1982; amended in R84-9, at 9 Ill. Reg. 11961, effective July 24, 1985; amended in
R86-19, at 10 Ill. Reg. 20718, effective December 2, 1986; amended in R86-46 at 11
161
Ill. Reg. 13570, effective August 4, 1987; amended in R87-5 at 11 Ill. Reg. 19412,
effective November 12, 1987; amended in R95-6 at 19 Ill. Reg. 9945, effective June
27, 1995; amended in R96-10/R97-3/R97-5 at 21 Ill. Reg. ________, effective
____________________.
SUBPART A: GENERAL
Section 723.110
Scope
a)
These regulations establish standards which apply to persons transporting
hazardous waste into, out of or through Illinois if the transportation
requires a manifest under Part35 Ill. Adm. Code 722.
b)
These regulations do not apply to on-site transportation of hazardous
waste by generators or by owners or operators of permitted hazardous
waste management facilities.
c)
A transporter of hazardous waste must also comply with Part35 Ill.
Adm. Code 722, “Standards Applicable to Generators of Hazardous
Waste”, if he:
1)
Transports hazardous waste into the United States from abroad;
or
2)
Mixes hazardous waste of different DOT shipping descriptions by
placing them into a single container.
BOARD NOTE: Transporters whothat store hazardous waste are
required to comply with the storage standards in Parts35 Ill.
Adm. Code 724 and 725 and the permit requirements of 40 CFR
Part 122.
d)
Part 700 contains rules concerning application of other Board
regulations.A transporter of hazardous waste subject to the manifesting
requirements of 35 Ill. Adm. Code 722 or the waste management
standards of 35 Ill. Adm. Code 733 that is being imported from or
exported to any of the countries listed in 35 Ill. Adm. Code
722.158(a)(1) for purposes of recovery is subject to this Subpart and to
all other relevant requirements of 35 Ill. Adm. Code 722.Subpart H,
including, but not limited to, 35 Ill. Adm. Code 722.184 for tracking
documents.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
162
SUBPART B: COMPLIANCE WITH THE MANIFEST SYSTEM
AND RECORDKEEPING
Section 723.120
The Manifest System
a)
No acceptance without a manifest.
1)
A transporter shall not accept hazardous waste from a generator
unless it is accompanied by a manifest signed in accordance with
the provisions of 35 Ill. Adm. Code 722.120. In the case of
exports other than those subject to 35 Ill. Adm. Code
722.Subpart H, a transporter shall not accept such waste from a
primary exporter or other person:
1A)
If the transporter knows the shipment does not conform
with the USEPA Acknowledgement of Consent (as
defined in 35 Ill. Adm. Code 722.151); and
2B)
Unless, in addition to a manifest signed in accordance
with 35 Ill. Adm. Code 722.120, the waste is also
accompanied by a USEPA Acknowledgement of Consent
which, except for shipment by rail, is attached to the
manifest (or shipping paper for exports by water (bulk
shipment)).
2)
For exports of hazardous waste subject to the requirements of 35
Ill. Adm. Code 722.Subpart H, a transporter may not accept
hazardous waste without a tracking document that includes all
information required by 35 Ill. Adm. Code 722.184.
b)
Before transporting the hazardous waste, the transporter shall sign and
date the manifest acknowledging acceptance of the hazardous waste from
the generator. The transporter shall return a signed copy to the
generator before leaving the generator’s property.
c)
The transporter shall ensure that the manifest accompanies the hazardous
waste. In the case of exports, the transporter shall ensure that a copy of
the USEPA Acknowledgement of Consent also accompanies the
hazardous waste.
d)
A transporter whothat delivers a hazardous waste to another transporter
or to the designated facility shall:
163
1)
Obtain the date of delivery and the handwritten signature of that
transporter or of the owner or operator of the designated facility
on the manifest; and
2)
Retain one copy of the manifest in accordance with Section
723.122; and
3)
Give the remaining copies of the manifest to the accepting
transporter or designated facility.
e)
The requirements of subsections (c), (d) and (f) do not apply to water
(bulk shipment) transporters if:
1)
The hazardous waste is delivered by water (bulk shipment) to the
designated facility; and
2)
A shipping paper containing all the information required on the
manifest (excluding the USEPA identification numbers, generator
certification and signatures) accompanies the hazardous waste
and, for exports, a USEPA Acknowledgement of Consent
accompanies the hazardous waste; and
3)
The delivering transporter obtains the date of delivery and
handwritten signature of the owner or operator designated facility
on either the manifest or the shipping paper; and
4)
The person delivering the hazardous waste to the initial water
(bulk shipment) transporter obtains the date of delivery and
signature of the water (bulk shipment) transporter on the manifest
and forwards it to the designated facility; and
5)
A copy of the shipping paper or manifest is retained by each
water (bulk shipment) transporter in accordance with Section
723.122.
f)
For shipments involving rail transportation, the requirements of
subsections (c), (d) and (e) do not apply and the following requirements
do apply:
1)
When accepting hazardous waste from a non-rail transporter, the
initial rail transporter shall:
A)
Sign and date the manifest acknowledging acceptance of
the hazardous waste;
164
B)
Return a signed copy of the manifest to the non-rail
transporter;
C)
Forward at least three copies of the manifest to:
i)
The next non-rail transporter, if any; or,
ii)
The designated facility, if the shipment is delivered
to that facility by rail; or
iii)
The last rail transporter designated to handle the
waste in the United States;
D)
Retain one copy of the manifest and rail shipping paper in
accordance with Section 723.122.
2)
Rail transporters shall ensure that a shipping paper containing all
the information required on the manifest (excluding the USEPA
identification numbers, generator certification and signatures)
and, for exports, a USEPA Acknowledgement of Consent
accompanies the hazardous waste at all times.
(Board NoteBOARD NOTE: Intermediate rail transporters are
not required to sign either the manifest or shipping paper.)
3)
When delivering hazardous waste to the designated facility, a rail
transporter shall:
A)
Obtain the date of delivery and handwritten signature of
the owner or operator of the designated facility on the
manifest or the shipping paper (if the manifest has not
been received by the facility); and
B)
Retain a copy of the manifest or signed shipping paper in
accordance with Section 723.122.
4)
When delivering hazardous waste to a non-rail transporter a rail
transporter shall:
A)
Obtain the date of delivery and the handwritten signature
of the next non-rail transporter on the manifest; and
B)
Retain a copy of the manifest in accordance with Section
723.122.
165
5)
Before accepting hazardous waste from a rail transporter, a non-
rail transporter shall sign and date the manifest and provide a
copy to the rail transporter.
g)
Transporters whothat transport hazardous waste out of the United States
shall:
1)
Indicate on the manifest the date the hazardous waste left the
United States; and
2)
Sign the manifest and retain one copy in accordance with Section
723.122(c); and
3)
Return a signed copy of the manifest to the generator; and
4)
Give a copy of the manifest to a United States Customs official at
the point of departure from the United States.
h)
A transporter transporting hazardous waste from a generator whothat
generates greater than 100 kilograms but less than 1000 kilograms of
hazardous waste in a calendar month need not comply with the
requirements of this Section or those of Section 723.122 provided that:
1)
The waste is being transported pursuant to a reclamation
agreement provided for in 35 Ill. Adm. Code 722.120(e);
2)
The transporter records, on a log or shipping paper, the following
information for each shipment:
A)
The name, address and USEPA Identification Number (35
Ill. Adm. Code 722.112) of the generator of the waste;
B)
The quantity of waste accepted;
C)
All shipping information required by the United States
Department of Transportation;
D)
The date the waste is accepted; and
3)
The transporter carries this record when transporting waste to the
reclamation facility; and
4)
The transporter retains these records for a period of at least three
years after termination or expiration of the agreement.
166
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE G: WASTE DISPOSAL
CHAPTER I: POLLUTION CONTROL BOARD
SUBCHAPTER c: HAZARDOUS WASTE OPERATING
REQUIREMENTS
PART 724
STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS
WASTE TREATMENT, STORAGE, AND DISPOSAL FACILITIES
SUBPART A: GENERAL PROVISIONS
Section
724.101
Purpose, Scope and Applicability
724.103
Relationship to Interim Status Standards
SUBPART B: GENERAL FACILITY STANDARDS
Section
724.110
Applicability
724.111
Identification Number
724.112
Required Notices
724.113
General Waste Analysis
724.114
Security
724.115
General Inspection Requirements
724.116
Personnel Training
724.117
General Requirements for Ignitable, Reactive or Incompatible Wastes
724.118
Location Standards
724.119
Construction Quality Assurance Program
SUBPART C: PREPAREDNESS AND PREVENTION
Section
724.130
Applicability
724.131
Design and Operation of Facility
724.132
Required Equipment
724.133
Testing and Maintenance of Equipment
724.134
Access to Communications or Alarm System
724.135
Required Aisle Space
724.137
Arrangements with Local Authorities
SUBPART D: CONTINGENCY PLAN AND EMERGENCY
PROCEDURES
Section
724.150
Applicability
167
724.151
Purpose and Implementation of Contingency Plan
724.152
Content of Contingency Plan
724.153
Copies of Contingency Plan
724.154
Amendment of Contingency Plan
724.155
Emergency Coordinator
724.156
Emergency Procedures
SUBPART E: MANIFEST SYSTEM, RECORDKEEPING AND
REPORTING
Section
724.170
Applicability
724.171
Use of Manifest System
724.172
Manifest Discrepancies
724.173
Operating Record
724.174
Availability, Retention and Disposition of Records
724.175
Annual Report
724.176
Unmanifested Waste Report
724.177
Additional Reports
SUBPART F: RELEASES FROM SOLID WASTE MANAGEMENT
UNITS
Section
724.190
Applicability
724.191
Required Programs
724.192
Groundwater Protection Standard
724.193
Hazardous Constituents
724.194
Concentration Limits
724.195
Point of Compliance
724.196
Compliance Period
724.197
General Groundwater Monitoring Requirements
724.198
Detection Monitoring Program
724.199
Compliance Monitoring Program
724.200
Corrective Action Program
724.201
Corrective Action for Solid Waste Management Units
SUBPART G: CLOSURE AND POST-CLOSURE
Section
724.210
Applicability
724.211
Closure Performance Standard
724.212
Closure Plan; Amendment of Plan
724.213
Closure; Time Allowed For Closure
724.214
Disposal or Decontamination of Equipment, Structures and Soils
724.215
Certification of Closure
724.216
Survey Plat
724.217
Post-closure Care and Use of Property
168
724.218
Post-closure Plan; Amendment of Plan
724.219
Post-closure Notices
724.220
Certification of Completion of Post-closure Care
SUBPART H: FINANCIAL REQUIREMENTS
Section
724.240
Applicability
724.241
Definitions of Terms As Used In This Subpart
724.242
Cost Estimate for Closure
724.243
Financial Assurance for Closure
724.244
Cost Estimate for Post-closure Care
724.245
Financial Assurance for Post-closure Care
724.246
Use of a Mechanism for Financial Assurance of Both Closure and Post-
closure Care
724.247
Liability Requirements
724.248
Incapacity of Owners or Operators, Guarantors or Financial Institutions
724.251
Wording of the Instruments
SUBPART I: USE AND MANAGEMENT OF CONTAINERS
Section
724.270
Applicability
724.271
Condition of Containers
724.272
Compatibility of Waste With Container
724.273
Management of Containers
724.274
Inspections
724.275
Containment
724.276
Special Requirements for Ignitable or Reactive Waste
724.277
Special Requirements for Incompatible Wastes
724.278
Closure
724.279
Air Emission Standards
SUBPART J: TANK SYSTEMS
Section
724.290
Applicability
724.291
Assessment of Existing Tank System’s Integrity
724.292
Design and Installation of New Tank Systems or Components
724.293
Containment and Detection of Releases
724.294
General Operating Requirements
724.295
Inspections
724.296
Response to Leaks or Spills and Disposition of Leaking or unfit-for-use
Tank Systems
724.297
Closure and Post-Closure Care
724.298
Special Requirements for Ignitable or Reactive Waste
724.299
Special Requirements for Incompatible Wastes
724.300
Air Emission Standards
169
SUBPART K: SURFACE IMPOUNDMENTS
Section
724.320
Applicability
724.321
Design and Operating Requirements
724.322
Action Leakage Rate
724.323
Response Actions
724.326
Monitoring and Inspection
724.327
Emergency Repairs; Contingency Plans
724.328
Closure and Post-closure Care
724.329
Special Requirements for Ignitable or Reactive Waste
724.330
Special Requirements for Incompatible Wastes
724.331
Special Requirements for Hazardous Wastes F020, F021, F022, F023,
F026 and F027
724.332
Air Emission Standards
SUBPART L: WASTE PILES
Section
724.350
Applicability
724.351
Design and Operating Requirements
724.352
Action Leakage Rate
724.353
Response Action Plan
724.354
Monitoring and Inspection
724.356
Special Requirements for Ignitable or Reactive Waste
724.357
Special Requirements for Incompatible Wastes
724.358
Closure and Post-closure Care
724.359
Special Requirements for Hazardous Wastes F020, F021, F022, F023,
F026 and F027
SUBPART M: LAND TREATMENT
Section
724.370
Applicability
724.371
Treatment Program
724.372
Treatment Demonstration
724.373
Design and Operating Requirements
724.376
Food-chain Crops
724.378
Unsaturated Zone Monitoring
724.379
Recordkeeping
724.380
Closure and Post-closure Care
724.381
Special Requirements for Ignitable or Reactive Waste
724.382
Special Requirements for Incompatible Wastes
724.383
Special Requirements for Hazardous Wastes F020, F021, F022, F023,
F026 and F027
SUBPART N: LANDFILLS
170
Section
724.400
Applicability
724.401
Design and Operating Requirements
724.402
Action Leakage Rate
724.403
Monitoring and Inspection
724.404
Response Actions
724.409
Surveying and Recordkeeping
724.410
Closure and Post-closure Care
724.412
Special Requirements for Ignitable or Reactive Waste
724.413
Special Requirements for Incompatible Wastes
724.414
Special Requirements for Bulk and Containerized Liquids
724.415
Special Requirements for Containers
724.416
Disposal of Small Containers of Hazardous Waste in Overpacked Drums
(Lab Packs)
724.417
Special Requirements for Hazardous Wastes F020, F021, F022, F023,
F026 and F027
SUBPART O: INCINERATORS
Section
724.440
Applicability
724.441
Waste Analysis
724.442
Principal Organic Hazardous Constituents (POHCs)
724.443
Performance Standards
724.444
Hazardous Waste Incinerator Permits
724.445
Operating Requirements
724.447
Monitoring and Inspections
724.451
Closure
SUBPART S: CORRECTIVE ACTION FOR SOLID WASTE
MANAGEMENT UNITS
Section
724.652
Corrective Action Management Units
724.653
Temporary Units
SUBPART W: DRIP PADS
Section
724.670
Applicability
724.671
Assessment of existing drip pad integrity
724.672
Design and installation of new drip pads
724.673
Design and operating requirements
724.674
Inspections
724.675
Closure
SUBPART X: MISCELLANEOUS UNITS
Section
171
724.700
Applicability
724.701
Environmental Performance Standards
724.702
Monitoring, Analysis, Inspection, Response, Reporting and Corrective
Action
724.703
Post-closure Care
SUBPART AA: AIR EMISSION STANDARDS FOR PROCESS
VENTS
Section
724.930
Applicability
724.931
Definitions
724.932
Standards: Process Vents
724.933
Standards: Closed-vent Systems and Control Devices
724.934
Test methods and procedures
724.935
Recordkeeping requirements
724.936
Reporting Requirements
SUBPART BB: AIR EMISSION STANDARDS FOR EQUIPMENT
LEAKS
Section
724.950
Applicability
724.951
Definitions
724.952
Standards: Pumps in Light Liquid Service
724.953
Standards: Compressors
724.954
Standards: Pressure Relief Devices in Gas/Vapor Service
724.955
Standards: Sampling Connecting Systems
724.956
Standards: Open-ended Valves or Lines
724.957
Standards: Valves in Gas/Vapor or Light Liquid Service
724.958
Standards: Pumps, Valves, Pressure Relief Devices and Other
Connectors
724.959
Standards: Delay of Repair
724.960
Standards: Closed-vent Systems and Control Devices
724.961
Alternative Percentage Standard for Valves
724.962
Skip Period Alternative for Valves
724.963
Test Methods and Procedures
724.964
Recordkeeping Requirements
724.965
Reporting Requirements
SUBPART CC: AIR EMISSION STANDARDS FOR TANKS,
SURFACE IMPOUNDMENTS, AND CONTAINERS
Section
724.980
Applicability
724.981
Definitions
724.982
Standards: General
724.983
Waste Determination Procedures
172
724.984
Standards: Tanks
724.985
Standards: Surface Impoundments
724.986
Standards: Containers
724.987
Standards: Closed-vent Systems and Control Devices
724.988
Inspection and Monitoring Requirements
724.989
Recordkeeping Requirements
724.990
Reporting Requirements
724.991
Alternative Control Requirements for Tanks
SUBPART DD: CONTAINMENT BUILDINGS
Section
724.1100
Applicability
724.1101
Design and operating standards
724.1102
Closure and Post-closure Care
724.Appendix A
Recordkeeping Instructions
724.Appendix B
EPA Report Form and Instructions (Repealed)
724.Appendix D
Cochran’s Approximation to the Behrens-Fisher Student’s T-Test
724.Appendix E
Examples of Potentially Incompatible Waste
724.Appendix I
Groundwater Monitoring List
AUTHORITY: Implementing Section 22.4 and authorized by Section 27 of the
Environmental Protection Act [415 ILCS 5/22.4 and 27].
SOURCE: Adopted in R82-19, 53 PCB 131, at 7 Ill. Reg. 14059, effective October
12, 1983; amended in R84-9 at 9 Ill. Reg. 11964, effective July 24, 1985; amended in
R85-22 at 10 Ill. Reg. 1136, effective January 2, 1986; amended in R86-1 at 10 Ill.
Reg. 14119, effective August 12, 1986; amended in R86-28 at 11 Ill. Reg. 6138,
effective March 24, 1987; amended in R86-28 at 11 Ill. Reg. 8684, effective April 21,
1987; amended in R86-46 at 11 Ill. Reg. 13577, effective August 4, 1987; amended in
R87-5 at 11 Ill. Reg. 19397, effective November 12, 1987; amended in R87-39 at 12
Ill. Reg. 13135, effective July 29, 1988; amended in R88-16 at 13 Ill. Reg. 458,
effective December 28, 1988; amended in R89-1 at 13 Ill. Reg. 18527, effective
November 13, 1989; amended in R90-2 at 14 Ill. Reg. 14511, effective August 22,
1990; amended in R90-10 at 14 Ill. Reg. 16658, effective September 25, 1990;
amended in R90-11 at 15 Ill. Reg. 9654, effective June 17, 1991; amended in R91-1 at
15 Ill. Reg. 14572, effective October 1, 1991; amended in R91-13 at 16 Ill. Reg.
9833, effective June 9, 1992; amended in R92-1 at 16 Ill. Reg. 17702, effective
November 6, 1992; amended in R92-10 at 17 Ill. Reg. 5806, effective March 26,
1993; amended in R93-4 at 17 Ill. Reg. 20830, effective November 22, 1993; amended
in R93-16 at 18 Ill. Reg. 6973, effective April 26, 1994; amended in R94-7 at 18 Ill.
Reg. 12487, effective July 29, 1994; amended in R94-17 at 18 Ill. Reg. 17601,
effective November 23, 1994; amended in R95-6 at 19 Ill. Reg. 9951, effective June
27, 1995; amended in R95-20 at 20 Ill. Reg. 11244, August 1, 1996; amended in R96-
10/R97-3/R97-5 at 21 Ill. Reg. ________, effective ____________________.
173
SUBPART B: GENERAL FACILITY STANDARDS
Section 724.112
Required Notices
a)
Receipt from a foreign source.
1)
The owner or operator of a facility that has arranged to receive
hazardous waste from a foreign source must notify the Regional
Administrator in writing at least four weeks in advance of the
date the waste is expected to arrive at the facility. Notice of
subsequent shipments of the same waste from the same foreign
source is not required.
2)
The owner or operator of a recovery facility that has arranged to
receive hazardous waste subject to 35 Ill. Adm. Code
722.Subpart H must provide a copy of the tracking document
bearing all required signatures to the notifier, to the Office of
Enforcement and Compliance Assurance, Office of Compliance,
Enforcement Planning, Targeting and Data Division (2222A),
Environmental Protection Agency, 401 M St., SW, Washington,
DC 20460; to the Bureau of Land, Division of Land Pollution
Control, Illinois Environmental Protection Agency, P.O. Box
19276, Springfield, IL 62794-9276; and to the competent
authorities of all other concerned countries within three working
days of receipt of the shipment. The original of the signed
tracking document must be maintained at the facility for at least
three years.
b)
The owner or operator of a facility that receives hazardous waste from
an off-site source (except where the owner or operator is also the
generator) must inform the generator in writing that the owner or
operator has the appropriate permit(s) for, and will accept, the waste the
generator is shipping. The owner or operator must keep a copy of this
written notice as part of the operating record.
c)
Before transferring ownership or operation of a facility during its
operating life, or of a disposal facility during the post-closure care
period, the owner or operator must notify the new owner or operator in
writing of the requirements of this Part and 35 Ill. Adm. Code 702 and
703.
BOARD NOTE: An owner’s or operator’s failure to notify the new
owner or operator of the requirements of this Part in no way relieves the
174
new owner or operator of his obligation to comply with all applicable
requirements.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 724.113
General Waste Analysis
a)
Analysis:
1)
Before an owner or operator treats, stores, or disposes of any
hazardous wastes, or non-hazardous wastes if applicable under
Section 724.213(d), the owner or operator shall obtain a detailed
chemical and physical analysis of a representative sample of the
wastes. At a minimum, the analysis must contain all the
information that must be known to treat, store, or dispose of the
waste in accordance with this Part and 35 Ill. Adm. Code 728.
2)
The analysis may include data developed under 35 Ill. Adm.
Code 721 and existing published or documented data on the
hazardous waste or on hazardous waste generated from similar
processes.
BOARD NOTE: For example, the facility’s records of analyses
performed on the waste before the effective date of these
regulations or studies conducted on hazardous waste generated
from processes similar to that which generated the waste to be
managed at the facility may be included in the data base required
to comply with subsection (a)(1) aboveof this Section. The
owner or operator of an off-site facility may arrange for the
generator of the hazardous waste to supply part or all of the
information required by subsection (a)(1) aboveof this Section,
except as otherwise specified in 35 Ill. Adm. Code 728.107(b)
and (c). If the generator does not supply the information, and the
owner or operator chooses to accept a hazardous waste, the
owner or operator is responsible for obtaining the information
required to comply with this Section.
3)
The analysis must be repeated as necessary to ensure that it is
accurate and up to date. At a minimum, the analysis must be
repeated:
A)
When the owner or operator is notified, or has reason to
believe, that the process or operation generating the
hazardous waste, or non-hazardous waste if applicable
under Section 724.213(d), has changed; and
175
B)
For off-site facilities, when the results of the inspection
required in subsection (a)(4) belowof this Section indicate
that the hazardous waste received at the facility does not
match the waste designated on the accompanying manifest
or shipping paper.
4)
The owner or operator of an off-site facility shall inspect and, if
necessary, analyze each hazardous waste shipment received at the
facility to determine whether it matches the identity of the waste
specified on the accompanying manifest or shipping paper.
b)
The owner or operator shall develop and follow a written waste analysis
plan that describes the procedures that it will carry out to comply with
subsection (a) aboveof this Section. The owner or operator shall keep
this plan at the facility. At a minimum, the plan must specify:
1)
The parameters for which each hazardous waste, or non-
hazardous waste if applicable under Section 724.213(d), will be
analyzed and the rationale for the selection of these parameters
(i.e., how analysis for these parameters will provide sufficient
information on the waste’s properties to comply with subsection
(a) aboveof this Section).
2)
The test methods that will be used to test for these parameters.
3)
The sampling method that will be used to obtain a representative
sample of the waste to be analyzed. A representative sample may
be obtained using either:
A)
One of the sampling methods described in 35 Ill. Adm.
Code 721.Appendix A; or
B)
An equivalent sampling method.
BOARD NOTE: See 35 Ill. Adm. Code 720.121.
4)
The frequency with which the initial analysis of the waste will be
reviewed or repeated to ensure that the analysis is accurate and up
to date.
5)
For off-site facilities, the waste analyses that hazardous waste
generators have agreed to supply.
176
6)
Where applicable, the methods that will be used to meet the
additional waste analysis requirements for specific waste
management methods as specified in Sections 724.117, 724.414,
724.441, 724.934(d), 724.963(d), and 724.983 and 35 Ill. Adm.
Code 728.107.
7)
For surface impoundments exempted from land disposal
restrictions under 35 Ill. Adm. Code 728.104(a), the procedures
and schedules for:
A)
The sampling of impoundment contents;
B)
The analysis of test data; and
C)
The annual removal of residues that are not delisted under
35 Ill. Adm. Code 720.122 or which exhibit a
characteristic of hazardous waste and either:
i)
Do not meet applicable treatment standards of 35
Ill. Adm. Code 728.Subpart D; or
ii)
Where no treatment standards have been
established, such residues are prohibited from land
disposal under 35 Ill. Adm. Code 728.132 or
728.139 or such residues are prohibited from land
disposal under 35 Ill. Adm. Code 728.133(f).
8)
For owners and operators seeking an exemption to the air
emission standards of 724.Subpart CC in accordance with Section
724.982:
A)
TIf direct measurement is used for the waste
determination, the procedures and schedules for waste
sampling and analysis and the analysis of test data to
verify the exemption, and.
B)
Each generator’s notice and certification of the volatile
organic concentration in the waste if the waste is received
from off siteIf knowledge of the waste is used for the
waste determination, any information prepared by the
facility owner or operator or by the generator of the
waste, if the waste is received from off-site, that is used
as the basis for knowledge of the waste.
177
c)
For off-site facilities, the waste analysis plan required in subsection (b)
aboveof this Section must also specify the procedures that will be used to
inspect and, if necessary, analyze each shipment of hazardous waste
received at the facility to ensure that it matches the identity of the waste
designated on the accompanying manifest or shipping paper. At a
minimum, the plan must describe:
1)
The procedures that will be used to determine the identity of each
movement of waste managed at the facility;
2)
The sampling method that will be used to obtain a representative
sample of the waste to be identified, if the identification method
includes sampling; and
3)
The procedures that the owner or operator of an off-site landfill
receiving containerized hazardous waste will use to determine
whether a hazardous waste generator or treater has added a
biodegradable sorbent to the waste in the container.
BOARD NOTE: 35 Ill. Adm. Code 703 requires that the waste
analysis plan be submitted with Part B of the permit application.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
SUBPART E: MANIFEST SYSTEM, RECORDKEEPING AND
REPORTING
Section 724.171
Use of Manifest System
a)
If a facility receives hazardous waste accompanied by a manifest, the
owner or operator, or the owner or operator’s agent, must:
1)
Sign and date each copy of the manifest to certify that the
hazardous waste covered by the manifest was received;
2)
Note any significant discrepancies in the manifest (as defined in
Section 724.172(a)) on each copy of the manifest;
BOARD NOTE: The Board does not intend that the owner or
operator of a facility whose procedures under Section 724.113(c)
include waste analysis must perform that analysis before signing
the manifest and giving it to the transporter. Section 724.172(b),
however, requires reporting an unreconciled discrepancy
discovered during later analysis.
178
3)
Immediately give the transporter at least one copy of the signed
manifest;
4)
Within 30 days after the delivery, send a copy of the manifest to
the generator and to the Agency; and
5)
Retain at the facility a copy of each manifest for at least three
years from the date of delivery.
b)
If a facility receives, from a rail or water (bulk shipment) transporter,
hazardous waste which is accompanied by a shipping paper containing
all the information required on the manifest (excluding the USEPA
identification numbers, generator’s certification, and signatures), the
owner or operator, or the owner or operator’s agent, must:
1)
Sign and date each copy of the manifest or shipping paper (if the
manifest has not been received) to certify that the hazardous
waste covered by the manifest or shipping paper was received;
2)
Note any significant discrepancies (as defined in Section
724.172(a)) in the manifest or shipping paper (if the manifest has
not been received) on each copy of the manifest or shipping
paper.;
BOARD NOTE: The Board does not intend that the owner or
operator of a facility whose procedures under Section 724.113(c)
include waste analysis must perform that analysis before signing
the shipping paper and giving it to the transporter. Section
724.172(b), however, requires reporting an unreconciled
discrepancy discovered during later analysis.
3)
Immediately give the rail or water (bulk shipment) transporter at
least one copy of the manifest or shipping paper (if the manifest
has not been received);
4)
Within 30 days after the delivery, send a copy of the signed and
dated manifest to the generator and to the Agency; however, if
the manifest has not been received within 30 days after delivery,
the owner or operator, or the owner or operator’s agent, must
send a copy of the shipping paper signed and dated to the
generator; and
179
BOARD NOTE: Section 722.123(c) requires the generator to
send three copies of the manifest to the facility when hazardous
waste is sent by rail or water (bulk shipment).
5)
Retain at the facility a copy of the manifest and shipping paper (if
signed in lieu of the manifest at the time of delivery) for at least
three years from the date of delivery.
c)
Whenever a shipment of hazardous waste is initiated from a facility, the
owner or operator of that facility must comply with the requirements of
35 Ill. Adm. Code 722.
BOARD NOTE: The provisions of 35 Ill. Adm. Code 722.134 are
applicable to the on-site accumulation of hazardous wastes by generators.
Therefore, the provisions of Section 722.134 only apply to owners or
operators whothat are shipping hazardous waste which they generated at
that facility.
d)
Within three working days of the receipt of a shipment subject to 35 Ill.
Adm. Code 722.Subpart H, the owner or operator of the facility must
provide a copy of the tracking document bearing all required signatures
to the notifier; to the Office of Enforcement and Compliance Assurance,
Office of Compliance, Enforcement Planning, Targeting and Data
Division (2222A), Environmental Protection Agency, 401 M St., SW,
Washington, DC 20460; to the Bureau of Land, Division of Land
Pollution Control, Illinois Environmental Protection Agency, P.O. Box
19276, Springfield, IL 62794-9276; and to competent authorities of all
other concerned countries. The original copy of the tracking document
must be maintained at the facility for at least three years from the date of
signature.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
SUBPART I: USE AND MANAGEMENT OF CONTAINERS
Section 724.279
Air Emission Standards
The owner or operator shall manage all hazardous waste placed in a container in
accordance with the requirements of 724.Subparts AA, BB, and CC.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
SUBPART J: TANK SYSTEMS
180
Section 724.300
Air Emission Standards
The owner or operator shall manage all hazardous waste placed in a tank in accordance
with the requirements of 724.Subparts AA, BB, and CC.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
SUBPART K: SURFACE IMPOUNDMENTS
Section 724.332
Air Emission Standards
The owner or operator shall manage all hazardous waste placed in a surface
impoundment in accordance with the requirements of 724.Subparts BB and CC.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
SUBPART N: LANDFILLS
Section 724.414
Special Requirements for Bulk and Containerized Liquids
a)
This subsection corresponds with 40 CFR 264.314(a), which pertains to
pre May 8, 1985 actions, a date long since passed. This statement
maintains structural consistency with U.S. EPA rules.
b)
The placement of bulk or non-containerized liquid hazardous waste or
hazardous waste containing free liquids (whether or not sorbents have
been added) in any landfill is prohibited.
c)
To demonstrate the absence or presence of free liquids in either a
containerized or a bulk waste, the following test must be used: Method
9095 (Paint Filter Liquids Test) as described in “Test Methods for
Evaluating Solid Wastes, Physical/Chemical Methods”, U.S. EPA
Publication No. SW-846, incorporated by reference in 35 Ill. Adm.
Code 720.111.
d)
Containers holding free liquids must not be placed in a landfill unless;:
1)
All free-standing liquid:
A)
has been removed by decanting or other methods;
181
B)
has been mixed with sorbent or solidified so that free-
standing liquid is no longer observed; or
C)
has been otherwise eliminated; or
2)
The container is very small, such as an ampule; or
3)
The container is designed to hold free liquids for use other than
storage, such as a battery or capacitor; or
4)
The container is a lab pack as defined in Section 724.416 and is
disposed of in accordance with Section 724.416.
e)
Sorbents used to treat free liquids to be disposed of in landfills must be
nonbiodegradable. Nonbiodegradable sorbents are: materials listed or
described in subsection (e)(1) belowof this Section; materials that pass
one of the tests in subsection (e)(2) belowof this Section; or materials
that are determined by the Board to be nonbiodegradable through the 35
Ill. Adm. Code 106 adjusted standard process.
1)
Nonbiodegradable sorbents are:
A)
Inorganic minerals, other inorganic materials, and
elemental carbon (e.g., aluminosilicates, clays, smectites,
Fuller’s earth, bentonite, calcium bentonite,
montmorillonite, calcined montmorillonite, kaolinite,
micas (illite), vermiculites, zeolites; calcium carbonate
(organic free limestone); oxides/hydroxides, alumina,
lime, silica (sand), diatomaceous earth; perlite (volcanic
glass); expanded volcanic rock; volcanic ash; cement kiln
dust; fly ash; rice hull ash; activated charcoal (activated
carbon)); or
B)
High molecular weight synthetic polymers (e.g.,
polyethylene, high density polyethylene (HDPE),
polypropylene, polystrene, poly urethanepolyurethane,
polyacrylate, polynorborene, polyisobutylene, ground
synthetic rubber, cross-linked allylstrene and tertiary butyl
copolymers). This does not include polymers derived
from biological material or polymers specifically designed
to be degradable; or
C)
Mixtures of these nonbiodegradable materials.
2)
Tests for nonbiodegradable sorbents:
182
A)
The sorbent material is determined to be nonbiodegradable
under ASTM Method G21-70 (1984a)--”Standard Practice
for Determining Resistance of Synthetic Polymer
Materials to Fungi”, incorporated by reference in 35 Ill.
Adm. Code 720.111; or
B)
The sorbent material is determined to be nonbiodegradable
under ASTM Method G22-76 (1984b)--”Standard Practice
for Determining Resistance of Plastics to Bacteria”,
incorporated by reference in 35 Ill. Adm. Code 720.111.;
or
C)
The sorbent material is determined to be non-
biodegradable under OECD test 301B (CO
2
Evolution
(Modified Sturm Test)), incorporated by reference in 35
Ill. Adm. Code 720.111.
f)
The placement of any liquid that is not a hazardous waste in a landfill is
prohibited (35 Ill. Adm. Code 729.311).
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
SUBPART AA: AIR EMISSION STANDARDS FOR PROCESS
VENTS
Section 724.930
Applicability
a)
This Subpart applies to owners and operators of facilities that treat, store
or dispose of hazardous wastes (except as provided in Section 724.101).
b)
Except for Sections 724.934(d) and (e), this Subpart applies to process
vents associated with distillation, fractionation, thin-film evaporation,
solvent extraction, or air or steam stripping operations that manage
hazardous wastes with organic concentrations of at least 10 ppmw (parts
per million by weight), if these operations are conducted in:
1)
Units that are subject to the permitting requirements of 35 Ill.
Adm. Code 703; or
2)
A unit (including a hHazardous waste recycling units) that areis
not exempt from permitting under the provisions of 35 Ill. Adm.
Code 722.134(a) (i.e., a hazardous waste recycling unit that is
not a 90-day tank or container) and that is located onat a
183
hazardous waste management facilitiesy otherwise subject to the
permitting requirements of 35 Ill. Adm. Code 703.; or
3)
A unit that is exempt from permitting under the provisions of 35
Ill. Adm. Code 722.134(a) (i.e., a 90-day tank or container).
c)
If the owner or operator of process vents subject to the requirements of
Sections 724.932 through 724.936 has received a RCRA permit prior to
December 21, 1990, the requirements of Sections 724.932 through
724.936 must be incorporated when the permit is reissued under 35 Ill.
Adm. Code 705.201 or reviewed under 35 Ill. Adm. Code 702.161.
BOARD NOTE: The requirements of Sections 724.932 through
724.936 apply to process vents on hazardous waste recycling units
previously exempt under 35 Ill. Adm. Code 721.106(c)(1). Other
exemptions under 35 Ill. Adm. Code 721.104, 722.134 and 724.101(g)
are not affected by these requirements.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 724.933
Standards: Closed-vent Systems and Control Devices
a)
Compliance Required.
1)
Owners or operators of closed-vent systems and control devices
used to comply with provisions of this Part shall comply with the
provisions of this Section.
2)
The owner or operator of an existing facility that cannot install a
closed-vent system and control device to comply with the
provisions of this Subpart on the effective date that the facility
becomes subject to the provisions of this Subpart shall prepare an
implementation schedule that includes dates by which the closed-
vent system and control device will be installed and in operation.
The controls must be installed as soon as possible, but the
implementation schedule may allow up to 1830 months after the
effective date that the facility becomes subject to this Subpart for
installation and startup. All units that begin operation after
December 21, 1990, must comply with the rules immediately
(i.e., must have control devices installed and operating on startup
of the affected unit); the 2-year implementation schedule does not
apply to these units.
b)
A control device involving vapor recovery (e.g., a condenser or
adsorber) must be designed and operated to recover the organic vapors
184
vented to it with an efficiency of 95 weight percent or greater unless the
total organic emission limits of Section 724.932(a)(1) for all affected
process vents is attained at an efficiency less than 95 weight percent.
c)
An enclosed combustion device (e.g., a vapor incinerator, boiler, or
process heater) must be designed and operated to reduce the organic
emissions vented to it by 95 weight percent or greater; to achieve a total
organic compound concentration of 20 ppmv, expressed as the sum of
the actual compounds and not in carbon equivalents, on a dry basis,
corrected to 3three percent oxygen; or to provide a minimum residence
time of 0.50 seconds at a minimum temperature of 760° C. If a boiler
or process heater is used as the control device, then the vent stream must
be introduced into the flame zone of the boiler or process heater.
d)
Flares:
1)
A flare must be designed for and operated with no visible
emissions, as determined by the methods specified in subsection
(e)(1), except for periods not to exceed a total of 5 minutes
during any 2 consecutive hours.
2)
A flare must be operated with a flame present at all times, as
determined by the methods specified in subsection (f)(2)(C)
belowof this Section.
3)
A flare must be used only if the net heating value of the gas
being combusted is 11.2 MJ/scm (300 Btu/scf) or greater and the
flare is steam-assisted or air-assisted or if the net heating value of
the gas being combusted is 7.45 MJ/scm (200 Btu/scf) or greater
and the flare is nonassisted. The net heating value of the gas
being combusted must be determined by the methods specified in
subsection (e)(2) belowof this Section.
4)
Exit Velocity.
A)
A steam-assisted or nonassisted flare must be designed for
and operated with an exit velocity, as determined by the
methods specified in subsection (e)(3) belowof this
Section, less than 18.3 m/s (60 ft/s), except as provided in
subsections (d)(4)(B) and (d)(4)(C) belowof this Section.
B)
A steam-assisted or nonassisted flare designed for and
operated with an exit velocity, as determined by the
methods specified in subsection (e)(3) belowof this
Section, equal to or greater than 18.3 m/s (60 ft/s) but
185
less than 122 m/s (400 ft/s) is allowed if the net heating
value of the gas being combusted is greater than 37.3
MJ/scm (1000 Btu/scf).
C)
A steam-assisted or nonassisted flare designed for and
operated with an exit velocity, as determined by the
methods specified in subsection (e)(3) belowof this
Section, less than the velocity, V, as determined by the
method specified in subsection (e)(4) belowof this Section
and less than 122 m/s (400 ft/s) is allowed.
5)
An air-assisted flare must be designed and operated with an exit
velocity less than the velocity, V, as determined by the method
specified in subsection (e)(5) belowof this Section.
6)
A flare used to comply with this Section must be steam-assisted,
air-assisted, or nonassisted.
e)
Compliance determination and equations.
1)
Reference Method 22 in 40 CFR 60, incorporated by reference in
35 Ill. Adm. Code 720.111, must be used to determine the
compliance of a flare with the visible emission provisions of this
Subpart. The observation period is 2 hours and must be used
according to Method 22.
2)
The net heating value of the gas being combusted in a flare must
be calculated using the following equation:
Where:
H
T
is the net heating value of the sample in MJ/scm;
where the net enthalpy per mole of offgas is based on
combustion at 25° C and 760 mm Hg, but the standard
temperature for determining the volume corrersponding to
1 mole is 20° C.
T
i
i
H
= K
i
n
C
H
×
=
∑
×
1
186
K = 1.74 E -7 1.74
×
10
7
(1/ppm)(g mol/scm)(MJ/kcal)
where standard temperature for (g mol/scm) 20° C.
S(Xi) means the sum of the values of X for each
component i, from i=1 to n.
C
i
is the concentration of sample component i in ppm on a
wet basis, as measured for organics by Reference Method
18 in 40 CFR 60, and for carbon monoxide, by ASTM D
1946-90, incorporated by reference in 35 Ill. Adm. Code
720.111.
H
i
is the net heat of combustion of sample component i,
kcal/gmol at 25° C and 760 mm Hg. The heats of
combustion must be determined using ASTM D 2382,
incorporated by reference in 35 Ill. Adm. Code 720.111,
if published values are not available or cannot be
calculated.
3)
The actual exit velocity of a flare must be determined by dividing
the volumetric flow rate (in units of standard temperature and
pressure), as determined by Reference Methods 2, 2A, 2C, or 2D
in 40 CFR 60, incorporated by reference in 35 Ill. Adm. Code
720.111, as appropriate, by the unobstructed (free) cross-
sectional area of the flare tip.
4)
The maximum allowed velocity in m/s, V
max
, for a flare
complying with subsection (d)(4)(C) must be determined by the
following equation:
log(
)
(
.
) /
.
V
H
T
=
+
288
317
(
)
(
)
log
.
.
max
10
288
317
V
H
T
=
+
Where:
log
10
means logarithm to the base 10
H
T
is the net heating value as determined in subsection
(e)(2).
187
5)
The maximum allowed velocity in m/s, V
max
, for an air-assisted
flare must be determined by the following equation:
max
.
.
V
H
T
=
+
8 706
0 7084
Where:
H
T
is the net heating value as determined in subsection
(e)(2) belowof this Section.
f)
The owner or operator shall monitor and inspect each control device
required to comply with this Section to ensure proper operation and
maintenance of the control device by implementing the following
requirements:
1)
Install, calibrate, maintain, and operate according to the
manufacturer’s specifications a flow indicator that provides a
record of stream flow from each affected process vent to the
control device at least once every hour. The flow indicator
sensor must be installed in the vent stream at the nearest feasible
point to the control device inlet but before the point at which the
vent streams are combined.
2)
Install, calibrate, maintain, and operate according to the
manufacturer’s specifications a device to continuously monitor
control device operation as specified below:
A)
For a thermal vapor incinerator, a temperature monitoring
device equipped with a continuous recorder. The device
must have accuracy of ±1 percent% of the temperature
being monitored in ° C or ±0.5° C, whichever is greater.
The temperature sensor must be installed at a location in
the combustion chamber downstream of the combustion
zone.
B)
For a catalytic vapor incinerator, a temperature
monitoring device equipped with a continuous recorder.
The device must be capable of monitoring temperature at
two locations and have an accuracy of ±1 percent% of
the temperature being monitored in ° C or ±0.5° C,
whichever is greater. One temperature sensor must be
installed in the vent stream at the nearest feasible point to
the catalyst bed inlet and a second temperature sensor
188
must be installed in the vent stream at the nearest feasible
point to the catalyst bed outlet.
C)
For a flare, a heat sensing monitoring device equipped
with a continuous recorder that indicates the continuous
ignition of the pilot flame.
D)
For a boiler or process heater having a design heat input
capacity less than 44 MW, a temperature monitoring
device equipped with a continuous recorder. The device
must have an accuracy of ±1 percent% of the temperature
being monitored in ° C or ±0.5° C, whichever is greater.
The temperature sensor must be installed at a location in
the furnace downstream of the combustion zone.
E)
For a boiler or process heater having a design heat input
capacity greater than or equal to 44 MW, a monitoring
device equipped with a continuous recorder to measure
parameters that indicate good combustion operating
practices are being used.
F)
For a condenser, either:
i)
A monitoring device equipped with a continuous
recorder to measure the concentration level of the
organic compounds in the exhaust vent stream
from the condenser; or
ii)
A temperature monitoring device equipped with a
continuous recorder. The device must be capable
of monitoring temperature at two locations and
havewith an accuracy of ±1 percent% of the
temperature being monitored in ° C or ±0.5° C,
whichever is greater. OneThe temperature sensor
must be installed at a location in the exhaust vent
stream from the condenser, and a second
temperature sensor must be installed at a location
in the coolant fluid exiting the condenser (i.e.,
product side).
G)
For a carbon adsorption system that regenerates the
carbon bed directly in the control device such as a fixed-
bed carbon adsorber, either:
189
i)
A monitoring device equipped with a continuous
recorder to measure the concentration level of the
organic compounds in the exhaust vent stream
from the carbon bed, or
ii)
A monitoring device equipped with a continuous
recorder to measure a parameter that indicates the
carbon bed is regenerated on a regular,
predetermined time cycle.
3)
Inspect the readings from each monitoring device required by
subsections (f)(1) and (f)(2) at least once each operating day to
check control device operation and, if necessary, immediately
implement the corrective measures necessary to ensure the
control device operates in compliance with the requirements of
this Section.
g)
An owner or operator using a carbon adsorption system such as a fixed-
bed carbon adsorber that regenerates the carbon bed directly onsite in the
control device shall replace the existing carbon in the control device with
fresh carbon at a regular, predetermined time interval that is no longer
than the carbon service life established as a requirement of Section
724.935(b)(4)(C)(vi).
h)
An owner or operator using a carbon adsorption system such as a carbon
canister that does not regenerate the carbon bed directly onsite in the
control device shall replace the existing carbon in the control device with
fresh carbon on a regular basis by using one of the following procedures:
1)
Monitor the concentration level of the organic compounds in the
exhaust vent stream from the carbon adsorption system on a
regular schedule, and replace the existing carbon with fresh
carbon immediately when carbon breakthrough is indicated. The
monitoring frequency must be daily or at an interval no greater
than 20 percent% of the time required to consume the total
carbon working capacity established as a requirement of Section
724.935(b)(4)(C)(vii), whichever is longer.
2)
Replace the existing carbon with fresh carbon at a regular,
predetermined time interval that is less than the design carbon
replacement interval established as a requirement of Section
724.935(b)(4)(C)(vii).
i)
An alternative operational or process parameter may be monitored if the
operator demonstrates that the parameter will ensure that the control
190
device is operated in conformance with these standards and the control
device’s design specifications.
j)
An owner or operator of an affected facility seeking to comply with the
provisions of this Part by using a control device other than a thermal
vapor incinerator, catalytic vapor incinerator, flare, boiler, process
heater, condenser, or carbon adsorption system is required to develop
documentation including sufficient information to describe the control
device operation and identify the process parameter or parameters that
indicate proper operation and maintenance of the control device.
k)
Closed vent systems.A closed-vent system must meet either of the
following design requirements:
1)
CA closed-vent systems must be designed for andto operated with
no detectable emissions, as indicated by an instrument reading of
less than 500 ppmv above background and by visual inspections,
as determined by the methods specified at Section 724.934(b).,
and by visual inspections; or
2)
Closed-vent systems must be monitored to determine compliance
with this Section during the initial leak detection monitoring,
which must be conducted by the date that the facility becomes
subject to the provisions of this Section annually, and at other
times as specified in the RCRA permit. For the annual leak
detection monitoring after the initial leak detection monitoring,
the owner or operator is not required to monitor those closed-vent
system components that operate in vacuum service or those
closed-vent system joints, seams, or other connections that are
permanently or semi-permanently sealed (e.g., a welded joint
between two sections of metal pipe or a bolted and gasketed pipe
flange).A closed-vent system must be designed to operate at a
pressure below atmospheric pressure. The system must be
equipped with at least one pressure gauge or other pressure
measurement device that can be read from a readily accessible
location to verify that negative pressure is being maintained in the
closed-vent system when the control device is operating.
3)
Detectable emissions, as indicated by an instrument reading
greater than 500 ppm and visual inspections, must be controlled
as soon as practicable, but not later than 15 calendar days after
the emission is detected.
4)
A first attempt at repair must be made no later than 5 calendar
days after the emission is detected..
191
l)
The owner or operator shall monitor and inspect each closed-vent system
required to comply with this Section to ensure proper operation and
maintenance of the closed-vent system by implementing the following
requirements:
1)
Each closed-vent system that is used to comply with subsection
(k)(1) of this Section shall be inspected and monitored in
accordance with the following requirements:
A)
An initial leak detection monitoring of the closed-vent
system shall be conducted by the owner or operator on or
before the date that the system becomes subject to this
Section. The owner or operator shall monitor the closed-
vent system components and connections using the
procedures specified in Section 724.934(b) to demonstrate
that the closed-vent system operates with no detectable
emissions, as indicated by an instrument reading of less
than 500 ppmv of this Section background.
B)
After initial leak detection monitoring required in
subsection (l)(1)(A) of this Section, the owner or operator
shall inspect and monitor the closed-vent system as
follows:
i)
Closed-vent system joints, seams, or other
connections that are permanently or semi-
permanently sealed (e.g., a welded joint between
two sections of hard piping or a bolted and
gasketed ducting flange) must be visually inspected
at least once per year to check for defects that
could result in air pollutant emissions. The owner
or operator shall monitor a component or
connection using the procedures specified in
Section 724.934(b) to demonstrate that it operates
with no detectable emissions following any time
the component is repaired or replaced (e.g., a
section of damaged hard piping is replaced with
new hard piping) or the connection is unsealed
(e.g., a flange is unbolted).
ii)
Closed-vent system components or connections
other than those specified in subsection (l)(1)(B)(i)
of this Section must be monitored annually and at
other times as requested by the Regional
192
Administrator, except as provided for in subsection
(o) of this Section, using the procedures specified
in Section 724.934(b) to demonstrate that the
components or connections operate with no
detectable emissions.
C)
In the event that a defect or leak is detected, the owner or
operator shall repair the defect or leak in accordance with
the requirements of subsection (l)(3) of this Section.
D)
The owner or operator shall maintain a record of the
inspection and monitoring in accordance with the
requirements specified in Section 724.935.
2)
Each closed-vent system that is used to comply with subsection
(k)(2) of this Section must be inspected and monitored in
accordance with the following requirements:
A)
The closed-vent system must be visually inspected by the
owner or operator to check for defects that could result in
air pollutant emissions. Defects include, but are not
limited to, visible cracks, holes, or gaps in ductwork or
piping or loose connections.
B)
The owner or operator shall perform an initial inspection
of the closed-vent system on or before the date that the
system becomes subject to this Section. Thereafter, the
owner or operator shall perform the inspections at least
once every year.
C)
In the event that a defect or leak is detected, the owner or
operator shall repair the defect in accordance with the
requirements of subsection (l)(3) of this Section.
D)
The owner or operator shall maintain a record of the
inspection and monitoring in accordance with the
requirements specified in Section 724.935.
3)
The owner or operator shall repair all detected defects as follows:
A)
Detectable emissions, as indicated by visual inspection or
by an instrument reading greater than 500 ppmv above
background, must be controlled as soon as practicable, but
not later than 15 calendar days after the emission is
193
detected, except as provided for in subsection (l)(3)(C) of
this Section.
B)
A first attempt at repair must be made no later than five
calendar days after the emission is detected.
C)
Delay of repair of a closed-vent system for which leaks
have been detected is allowed if the repair is technically
infeasible without a process unit shutdown, or if the
owner or operator determines that emissions resulting
from immediate repair would be greater than the fugitive
emissions likely to result from delay of repair. Repair of
such equipment must be completed by the end of the next
process unit shutdown.
D)
The owner or operator shall maintain a record of the
defect repair in accordance with the requirements
specified in Section 724.935.
lm)
CA closed-vent systems andor control devices used to comply with
provisions of this Subpart must be operated at all times when emissions
may be vented to themit.
mn)
The owner or operator using a carbon adsorption system to control air
pollutant emissions shall document that all carbon removed that is a
hazardous waste and that is removed from a carbon adsorption system to
comply with subsections (g) and (h) abovethe control device is managed
in one of the following manners, regardless of the volatile organic
concentration of the carbon:
1)
It is regenerated or reactivated in a thermal treatment unit that is
permitted under 724.Subpart X,meets one of the following:
A)
The owner or operator of the unit has been issued a final
permit under 35 Ill. Adm. Code 702, 703, and 705 that
implements the requirements of 724.Subpart X; or
B)
The unit is equipped with and operating air emission
controls in accordance with the applicable requirements of
724.Subparts AA and CC or 35 Ill. Adm. Code
725.Subparts AA and CC; or
C)
The unit is equipped with and operating air emission
controls in accordance with a national emission standard
194
for hazardous air pollutants under 40 CFR 61 or 40 CFR
63.
2)
It is incinerated by a process that is permitted under 724.Subpart
O, orin a hazardous waste incinerator for which the owner or
operator has done either of the following:
A)
The owner or operator has been issued a final permit
under 35 Ill. Adm. Code 702, 703, and 705 that
implements the requirements of 724.Subpart O, or
B)
The owner or operator has certified compliance in
accordance with the interim status requirements of 35 Ill.
Adm. Code 725.Subpart O.
3)
It is burned in a boiler or industrial furnace that is permitted
under 724.Subpart H.for which the owner or operator has done
either of the following:
A)
The owner or operator has been issued a final permit
under 35 Ill. Adm. Code 702, 703, and 705 that
implements the requirements of 35 Ill. Adm. Code
726.Subpart H, or
B)
The owner or operator has designed and operates the
boiler or industrial furnace in accordance with the interim
status requirements of 35 Ill. Adm. Code 726.Subpart H.
o)
Any components of a closed-vent system that are designated, as
described in Section 724.935(c)(9), as unsafe to monitor are exempt
from the requirements of subsection (l)(1)(B)(ii) of this Section if both of
the following conditions are fulfilled:
1)
The owner or operator of the closed-vent system has determined
that the components of the closed-vent system are unsafe to
monitor because monitoring personnel would be exposed to an
immediate danger as a consequence of complying with subsection
(l)(1)(B)(ii) of this Section; and
2)
The owner or operator of the closed-vent system adheres to a
written plan that requires monitoring the closed-vent system
components using the procedure specified in subsection
(l)(1)(B)(ii) as frequently as practicable during safe-to-monitor
times.
195
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 724.934
Test methods and procedures
a)
Each owner or operator subject to the provisions of this Subpart shall
comply with the test methods and procedures requirements provided in
this Section
b)
When a closed-vent system is tested for compliance with no detectable
emissions, as required in Section 724.933(kl), the test must comply with
the following requirements:
1)
Monitoring must comply with Reference Method 21 in 40 CFR
60, incorporated by reference in 35 Ill. Adm. Code 720.111.
2)
The detection instrument must meet the performance criteria of
Reference Method 21.
3)
The instrument must be calibrated before use on each day of its
use by the procedures specified in Reference Method 21.
4)
Calibration gases must be:
A)
Zero air (less than 10 ppm of hydrocarbon in air).
B)
A mixture of methane or n-hexane and air at a
concentration of approximately, but less than, 10,000 ppm
methane or n-hexane.
5)
The background level must be determined as set forth in
Reference Method 21.
6)
The instrument probe must be traversed around all potential leak
interfaces as close to the interface as possible as described in
Reference Method 21.
7)
The arithmetic difference between the maximum concentration
indicated by the instrument and the background level is compared
with 500 ppm for determining compliance.
c)
Performance tests to determine compliance with Section 724.932(a) and
with the total organic compound concentration limit of Section
724.933(c) must comply with the following:
196
1)
Performance tests to determine total organic compound
concentrations and mass flow rates entering and exiting control
devices must be conducted and data reduced in accordance with
the following reference methods and calculation procedures:
A)
Method 2 in 40 CFR 60 for velocity and volumetric flow
rate.
B)
Method 18 in 40 CFR 60 for organic content.
C)
Each performance test must consist of three separate runs,
each run conducted for at least 1 hour under the
conditions that exist when the hazardous waste
management unit is operating at the highest load or
capacity level reasonably expected to occur. For the
purpose of determining total organic compound
concentrations and mass flow rates, the average of results
of all runs applies. The average must be computed on a
time-weighed basis.
D)
Total organic mass flow rates must be determined by the
following equation:
F = K * Q * SUM(Ci * MWi)
Where:
F is the total organic mass flow rate, kg/h.
K = 4.16 E -8, conversion factor for molar
volume, kg-mol/cubic m, at 293 K and 760 mm
Hg.
Q = volumetric flow rate of gases entering or
exiting control device, dscm/h, as determined by
Method 2 in 40 CFR 60, incorporated by reference
in 35 Ill. Adm. Code 720.111.
SUM(Xi) means the sum of the values of X for
each component i, from i=1 to n.
n = number of organic compounds in the vent gas.
197
Ci is the organic concentration in ppm, dry basis,
of compound i in the vent gas, as determined by
Method 18 in 40 CFR 60.
MWi is the molecular weight of organic compound
i in the vent gas, kg/kg-mol.
Where:
E
h
= The total organic mass flow rate, kg/h.
Q
2sd
= The volumetric flow rate of gases entering
or exiting control device, dscm/h, as
determined by Method 2 in 40 CFR 60,
incorporated by reference in 35 Ill. Adm.
Code 720.111.
n = The number of organic compounds in the
vent gas.
C
i
= The organic concentration in ppm, dry
basis, of compound i in the vent gas, as
determined by Method 18 in 40 CFR 60.
MW
i
= The molecular weight of organic
compound i in the vent gas, kg/kg-mol.
0.0416 = The conversion factor for molar
volume, kg-mol/m
3
, at 293 K and 760 mm
Hg.
10
-6
= The conversion factor from ppm.
E)
The annual total organic emission rate must be determined
by the following equation:
A = F *
×
HOURS
h
2sd
i
i
-6
E
= Q
x(
n
i = 1
C
x MW
)x0.0416x10
∑
198
Where:
A is total organic emission rate, kg/y.
F is the total organic mass flow rate, kg/h, as
calculated in subsection (c)(1)(D) of this Section.
HOURS is the total annual hours of operation for
the affected unit.
F)
Total organic emissions from all affected process vents at
the facility must be determined by summing the hourly
total organic mass emissions rates (F as determined in
subsection (c)(1)(D) of this Section) and by summing the
annual total organic mass emission rates (A as determined
in subsection (c)(1)(E) of this Section) for all affected
process vents at the facility.
2)
The owner or operator shall record such process information as is
necessary to determine the conditions of the performance tests.
Operations during periods of startup, shutdown and malfunction
do not constitute representative conditions for the purpose of a
performance test.
3)
The owner or operator of an affected facility shall provide, or
cause to be provided, performance testing facilities as follows:
A)
Sampling ports adequate for the test methods specified in
subsection (c)(1) of this Section.
B)
Safe sampling platform(s).
C)
Safe access to sampling platform(s).
D)
Utilities for sampling and testing equipment.
4)
For the purpose of making compliance determinations, the time-
weighted average of the results of the three runs must apply. In
the event that a sample is accidentally lost or conditions occur in
which one of the three runs must be discontinued because of
forced shutdown, failure of an irreplaceable portion of the sample
train, extreme meteorological conditions or other circumstances
beyond the owner or operator’s control, compliance may, upon
199
the Agency’s approval, be determined using the average of the
results of the two other runs.
d)
To show that a process vent associated with a hazardous waste
distillation, fractionation, thin-film evaporation, solvent extraction, or
air or steam stripping operation is not subject to the requirements of this
Subpart, the owner or operator shall make an initial determination that
the time-weighted, annual average total organic concentration of the
waste managed by the waste management unit is less than 10 ppmw
using one of the following two methods:
1)
Direct measurement of the organic concentration of the waste
using the following procedures:
A)
The owner or operator shall take a minimum of four grab
samples of waste for each wastestream managed in the
affected unit under process conditions expected to cause
the maximum waste organic concentration.
B)
For waste generated onsite, the grab samples must be
collected at a point before the waste is exposed to the
atmosphere such as in an enclosed pipe or other closed
system that is used to transfer the waste after generation to
the first affected distillation, fractionation, thin-film
evaporation, solvent extraction, or air or steam stripping
operation. For waste generated offsite, the grab samples
must be collected at the inlet to the first waste
management unit that receives the waste provided the
waste has been transferred to the facility in a closed
system such as a tank truck and the waste is not diluted or
mixed with other waste.
C)
Each sample must be analyzed and the total organic
concentration of the sample must be computed using
Method 9060 or 8240 of SW-846, (incorporated by
reference under 35 Ill. Adm. Code 720.111.
D)
The arithmetic mean of the results of the analyses of the
four samples apply for each wastestream managed in the
unit in determining the time-weighted, annual average
total organic concentration of the waste. The time-
weighted average is to be calculated using the annual
quantity of each waste stream processed and the mean
organic concentration of each wastestream managed in the
unit.
200
2)
Using knowledge of the waste to determine that its total organic
concentration is less than 10 ppmw. Documentation of the waste
determination is required. Examples of documentation that must
be used to support a determination under this subsection (d)(2)
include:
A)
Production process information documenting that no
organic compounds are used.;
B)
Information that the waste is generated by a process that is
identical to a process at the same or another facility that
has previously been demonstrated by direct measurement
to generate a wastestream having a total organic content
less than 10 ppmw,; or
C)
Prior speciation analysis results on the same wastestream
where it is also documented that no process changes have
occurred since that analysis that could affect the waste
total organic concentration.
e)
The determination that a distillation, fractionation, thin-film evaporation,
solvent extraction, or air or steam stripping operations which that
manages hazardous wastes with that have time-weighted, annual average
total organic concentrations less than 10 ppmw must be made as follows:
1)
By the effective date that the facility becomes subject to the
provisions of this Subpart or by the date when the waste is first
managed in a waste management unit, whichever is later; and
2)
For continuously generated waste, annually; or
3)
Whenever there is a change in the waste being managed or a
change in the process that generates or treats the waste.
f)
When an owner or operator and the Agency do not agree on whether a
distillation, fractionation, thin-film evaporation, solvent extraction, or
air or steam stripping operation manages a hazardous waste with organic
concentrations of at least 10 ppmw based on knowledge of the waste, the
procedures in Method 8240 in SW-846, incorporated by reference in 35
Ill. Adm. Code 720.111, must be used to resolve the dispute.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 724.935
Recordkeeping requirements
201
a)
Compliance Required.
1)
Each owner or operator subject to the provisions of this Subpart
shall comply with the recordkeeping requirements of this Section.
2)
An owner or operator of more than one hazardous waste
management unit subject to the provisions of this Subpart may
comply with the recordkeeping requirements for these hazardous
waste management units in one recordkeeping system if the
system identifies each record by each hazardous waste
management unit.
b)
Owners and operators shall record the following information in the
facility operating record:
1)
For facilities that comply with the provisions of Section
724.933(a)(2), an implementation schedule that includes dates by
which the closed-vent system and control device will be installed
and in operation. The schedule must also include a rationale of
why the installation cannot be completed at an earlier date. The
implementation schedule must be in the facility operating record
by the effective date that the facility becomes subject to the
provisions of this Subpart.
2)
Up-to-date documentation of compliance with the process vent
standards in Section 724.932, including:
A)
Information and data identifying all affected process
vents, annual throughput and operating hours of each
affected unit, estimated emission rates for each affected
vent and for the overall facility (i.e., the total emissions
for all affected vents at the facility), and the approximate
location within the facility of each affected unit (e.g.,
identify the hazardous waste management units on a
facility plot plan).
B)
Information and data supporting determination of vent
emissions and emission reductions achieved by add-on
control devices based on engineering calculations or
source tests. For the purpose of determining compliance,
determinations of vent emissions and emission reductions
must be made using operating parameter values (e.g.,
temperatures, flow rates, or vent stream organic
compounds and concentrations) that represent the
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conditions that result in maximum organic emissions, such
as when the waste management unit is operating at the
highest load or capacity level reasonably expected to
occur. If the owner or operator takes any action (e.g.,
managing a waste of different composition or increasing
operating hours of affected waste management units) that
would result in an increase in total organic emissions from
affected process vents at the facility, then a new
determination is required.
3)
Where an owner or operator chooses to use test data to determine
the organic removal efficiency or total organic compound
concentration achieved by the control device, a performance test
plan. The test plan must include:
A)
A description of how it is determined that the planned test
is going to be conducted when the hazardous waste
management unit is operating at the highest load or
capacity level reasonably expected to occur. This must
include the estimated or design flow rate and organic
content of each vent stream and define the acceptable
operating ranges of key process and control device
parameters during the test program.
B)
A detailed engineering description of the closed-vent
system and control device including:
i)
Manufacturer’s name and model number of control
device.
ii)
Type of control device.
iii)
Dimensions of the control device.
iv)
Capacity.
v)
Construction materials.
C)
A detailed description of sampling and monitoring
procedures, including sampling and monitoring locations
in the system, the equipment to be used, sampling and
monitoring frequency, and planned analytical procedures
for sample analysis.
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4)
Documentation of compliance with Section 724.933 must include
the following information:
A)
A list of all information references and sources used in
preparing the documentation.
B)
Records, including the dates of each compliance test
required by Section 724.933(k).
C)
If engineering calculations are used, a design analysis,
specifications, drawings, schematics, and piping and
instrumentation diagrams based on the appropriate
sections of APTI Course 415 (incorporated by reference
in 35 Ill. Adm. Code 720.111) or other engineering texts,
approved by the Agency, that present basic control device
design information. Documentation provided by the
control device manufacturer or vendor that describes the
control device design in accordance with subsections
(b)(4)(C)(i) through (vii), belowof this Section, may be
used to comply with this requirement. The design
analysis must address the vent stream characteristics and
control device operation parameters as specified below.
i)
For a thermal vapor incinerator, the design
analysis must consider the vent stream
composition, constituent concentrations and flow
rate. The design analysis must also establish the
design minimum and average temperature in the
combustion zone and the combustion zone
residence time.
ii)
For a catalytic vapor incinerator, the design
analysis must consider the vent stream
composition, constituent concentrations, and flow
rate. The design analysis must also establish the
design minimum and average temperatures across
the catalyst bed inlet and outlet.
iii)
For a boiler or process heater, the design analysis
must consider the vent stream composition,
constituent concentrations and flow rate. The
design analysis must also establish the design
minimum and average flame zone temperatures,
combustion zone residence time and description of
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method and location where the vent stream is
introduced into the combustion zone.
iv)
For a flare, the design analysis must consider the
vent stream composition, constituent
concentrations, and flow rate. The design analysis
must also consider the requirements specified in
Section 724.933(d).
v)
For a condenser, the design analysis must consider
the vent stream composition, constituent
concentrations, flow rate, relative humidity and
temperature. The design analysis must also
establish the design outlet organic compound
concentration level, design average temperature of
the condenser exhaust vent stream and design
average temperatures of the coolant fluid at the
condenser inlet and outlet.
vi)
For a carbon adsorption system such as a fixed-bed
adsorber that regenerates the carbon bed directly
onsite in the control device, the design analysis
must consider the vent stream composition,
constituent concentrations, flow rate, relative
humidity and temperature. The design analysis
must also establish the design exhaust vent stream
organic compound concentration level, number and
capacity of carbon beds, type and working capacity
of activated carbon used for carbon beds, design
total steam flow over the period of each complete
carbon bed regeneration cycle, duration of the
carbon bed steaming and cooling/drying cycles,
design carbon bed temperature after regeneration,
design carbon bed regeneration time and design
service life of carbon.
vii)
For a carbon adsorption system such as a carbon
canister that does not regenerate the carbon bed
directly onsite in the control device, the design
analysis must consider the vent stream
composition, constituent concentrations, flow rate,
relative humidity and temperature. The design
analysis must also establish the design outlet
organic concentration level, capacity of carbon
bed, type and working capacity of activated carbon
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used for carbon bed and design carbon replacement
interval based on the total carbon working capacity
of the control device and source operating
schedule.
D)
A statement signed and dated by the owner or operator
certifying that the operating parameters used in the design
analysis reasonably represent the conditions that exist
when the hazardous waste management unit is or would
be operating at the highest load or capacity level
reasonably expected to occur.
E)
A statement signed and dated by the owner or operator
certifying that the control device is designed to operate at
an efficiency of 95 percent% or greater unless the total
organic concentration limit of Section 724.932(a) is
achieved at an efficiency less than 95 weight percent or
the total organic emission limits of Section 724.932(a) for
affected process vents at the facility are attained by a
control device involving vapor recovery at an efficiency
less than 95 weight percent. A statement provided by the
control device manufacturer or vendor certifying that the
control equipment meets the design specifications may be
used to comply with this requirement.
F)
If performance tests are used to demonstrate compliance,
all test results.
c)
Design documentation and monitoring operating and inspection
information for each closed-vent system and control device required to
comply with the provisions of this Part must be recorded and kept up-to-
date in the facility operating record. The information must include:
1)
Description and date of each modification that is made to the
closed-vent system or control device design.
2)
Identification of operating parameter, description of monitoring
device, and diagram of monitoring sensor location or locations
used to comply with Section 724.933(f)(1) and (2).
3)
Monitoring, operating and inspection information required by
Section 724.933(f) through (k).
4)
Date, time and duration of each period that occurs while the
control device is operating when any monitored parameter
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exceeds the value established in the control device design analysis
as specified below:
A)
For a thermal vapor incinerator designed to operate with a
minimum residence time of 0.50 second at a minimum
temperature of 760° C, any period when the combustion
temperature is below 760° C.
B)
For a thermal vapor incinerator designed to operate with
an organic emission reduction efficiency of 95 weight
percent or greater, any period when the combustion zone
temperature is more than 28° C below the design average
combustion zone temperature established as a requirement
of subsection (b)(4)(C)(i), aboveof this Section.
C)
For a catalytic vapor incinerator, any period when:
i)
Temperature of the vent stream at the catalyst bed
inlet is more than 28° C below the average
temperature of the inlet vent stream established as
a requirement of subsection (b)(4)(C)(ii), aboveof
this Section; or
ii)
Temperature difference across the catalyst bed is
less than 80 percent% of the design average
temperature difference established as a requirement
of subsection (b)(4)(C)(ii), aboveof this Section.
D)
For a boiler or process heater, any period when:
i)
Flame zone temperature is more than 28° C below
the design average flame zone temperature
established as a requirement of subsection
(b)(4)(C)(iii), aboveof this Section; or
ii)
Position changes where the vent stream is
introduced to the combustion zone from the
location established as a requirement of subsection
(b)(4)(C)(iii), aboveof this Section.
E)
For a flare, period when the pilot flame is not ignited.
F)
For a condenser that complies with Section
724.933(f)(2)(F)(i), any period when the organic
compound concentration level or readings of organic
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compounds in the exhaust vent stream from the condenser
are more than 20 percent% greater than the design outlet
organic compound concentration level established as a
requirement of subsection (b)(4)(C)(v), aboveof this
Section.
G)
For a condenser that complies with Section
724.933(f)(2)(F)(ii), any period when:
i)
Temperature of the exhaust vent stream from the
condenser is more than 6° C above the design
average exhaust vent stream temperature
established as a requirement of subsection
(b)(4)(C)(v), aboveof this Section.
ii)
Temperature of the coolant fluid exiting the
condenser is more than 6° C above the design
average coolant fluid temperature at the condenser
outlet established as a requirement of subsection
(b)(4)(C)(v), aboveof this Section.
H)
For a carbon adsorption system such as a fixed-bed carbon
adsorber that regenerates the carbon bed directly onsite in
the control device and complies with Section
724.933(f)(2)(G)(i), any period when the organic
compound concentration level or readings of organic
compounds in the exhaust vent stream from the carbon
bed are more than 20 percent% greater than the design
exhaust vent stream organic compound concentration level
established as a requirement of subsection (b)(4)(C)(vi),
aboveof this Section.
I)
For a carbon adsorption system such as a fixed-bed carbon
adsorber that regenerates the carbon bed directly onsite in
the control device and complies with Section
724.933(f)(2)(G)(ii), any period when the vent stream
continues to flow through the control device beyond the
predetermined carbon bed regeneration time established as
a requirement of subsection (b)(4)(C)(vi), aboveof this
Section.
5)
Explanation for each period recorded under subsection (c)(4),
above,of this Section of the cause for control device operating
parameter exceeding the design value and the measures
implemented to correct the control device operation.
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6)
For a carbon adsorption system operated subject to requirements
specified in Section 724.933(g) or (h)(2), any date when existing
carbon in the control device is replaced with fresh carbon.
7)
For a carbon adsorption system operated subject to requirements
specified in Section 724.933(h)(1), a log that records:
A)
Date and time when control device is monitored for
carbon breakthrough and the monitoring device reading.
B)
Date when existing carbon in the control device is
replaced with fresh carbon.
8)
Date of each control device startup and shutdown.
9)
An owner or operator designating any components of a closed-
vent system as unsafe to monitor pursuant to Section 724.933(o)
shall record in a log that is kept in the facility operating record
the identification of closed-vent system components that are
designated as unsafe to monitor in accordance with the
requirements of Section 724.933(o), an explanation for each
closed-vent system component stating why the closed-vent system
component is unsafe to monitor, and the plan for monitoring each
closed-vent system component.
10)
When each leak is detected as specified in Section 724.933(l), the
following information must be recorded:
A)
The instrument identification number, the closed-vent
system component identification number, and the operator
name, initials, or identification number.
B)
The date the leak was detected and the date of first
attempt to repair the leak.
C)
The date of successful repair of the leak.
D)
Maximum instrument reading measured by Method 21 of
40 CFR 60, appendix A, incorporated by reference in 35
Ill. Adm. Code 720.111, after it is successfully repaired
or determined to be nonrepairable.
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E)
“Repair delayed” and the reason for the delay if a leak is
not repaired within 15 calendar days after discovery of the
leak.
i)
The owner or operator may develop a written
procedure that identifies the conditions that justify
a delay of repair. In such cases, reasons for delay
of repair may be documented by citing the relevant
sections of the written procedure.
ii)
If delay of repair was caused by depletion of
stocked parts, there must be documentation that the
spare parts were sufficiently stocked on-site before
depletion and the reason for depletion.
d)
Records of the monitoring, operating, and inspection information
required by subsections (c)(3) through (c)(810), above,of this Section
needmust be kept onlyat least 3 years following the date of each
occurrence, measurement, corrective action, or record.
e)
For a control device other than a thermal vapor incinerator, catalytic
vapor incinerator, flare, boiler, process heater, condenser or carbon
adsorption system, the Agency shall specify the appropriate
recordkeeping requirements.
f)
Up-to-date information and data used to determine whether or not a
process vent is subject to the requirements in Section 724.932, including
supporting documentation as required by Section 724.934(d)(2), when
application of the knowledge of the nature of the hazardous wastestream
or the process by which it was produced is used, must be recorded in a
log that is kept in the facility operating record.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
SUBPART BB: AIR EMISSION STANDARDS FOR EQUIPMENT
LEAKS
Section 724.950
Applicability
a)
The regulations in this Subpart apply to owners and operators of
facilities that treat, store, or dispose of hazardous wastes (except as
provided in Section 724.101).
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b)
Except as provided in Section 724.964(k), this Subpart applies to
equipment that contains or contacts hazardous wastes with organic
concentrations of at least 10 percent% by weight that are managed in one
of the following:
1)
UA units that areis subject to the RCRA permitting requirements
of 35 Ill. Adm. Code 702, 703, and 705, or
2)
HA unit (including a hazardous waste recycling units) that areis
not exempt from permitting under the provisions of 35 Ill. Adm.
Code 722.134(a) (i.e., a hazardous waste recycling unit that is
not a “90-day” tank or container) and that is located onat a
hazardous waste management facilitiesy otherwise subject to the
permitting requirements of 35 Ill. Adm. Code 702, 703, and
705., or
3)
A unit that is exempt from permitting under the provisions of 35
Ill. Adm. Code 722.134(a) (i.e., a “90-day” tank or container).
c)
If the owner or operator of equipment subject to the requirements of
Sections 724.952 through 724.965 has received a RCRA permit prior to
December 21, 1990, the requirements of Sections 724.952 through
724.965 must be incorporated when the permit is reissued under 35 Ill.
Adm. Code 705.201 or reviewed under 35 Ill. Adm. Code 702.161.
d)
Each piece of equipment to which this Subpart applies must be marked
in such a manner that it can be distinguished readily from other pieces of
equipment.
e)
Equipment that is in vacuum service is excluded from the requirements
of Sections 724.952 to 724.960, if it is identified as required in Section
724.964(g)(5).
f)
Equipment that contains or contacts hazardous waste with an organic
concentration of at least 10% by weight for a period of less than 300
hours per calendar year is excluded from the requirements of Sections
264.952 through 264.960 if it is identified as required in Section
724.964(g)(6).
BOARD NOTE: The requirements of Sections 724.952 through
724.965 apply to equipment associated with hazardous waste recycling
units previously exempt under 35 Ill. Adm. Code 721.106(c)(1). Other
exemptions under 35 Ill. Adm. Code 721.104, 722.134 and 724.101(g)
are not affected by these requirements.
211
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 724.955
Standards: Sampling Connecting Systems
a)
Each sampling connection system must be equipped with a closed-purge,
closed-loop, system or closed-vent system. This system must collect the
sample purge for return to the process or for routing to the appropriate
treatment system. Gases displaced during filling of the sample container
are not required to be collected or captured.
b)
Each closed-purge, closed-loop, system or closed-vent system as
required in subsection (a) must meet one of the following requirements:
1)
Return the purged hazardous waste streamprocess fluid directly to
the hazardous waste management process line with no detectable
emissions to atmosphere; or
2)
Collect and recycle the purged hazardous waste stream with no
detectable emissions to atmosphereprocess fluid; or
3)
Be designed and operated to capture and transport all the purged
hazardous wastestreamprocess fluid to a waste management unit
that complies with the applicable requirements of Sections
724.984 through 724.986 or a control device that complies with
the requirements of Section 724.960.
c)
In-situ sampling systems and sampling systems without purges are
exempt from the requirements of subsections (a) and (b) of this Section.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 724.958
Standards: Pumps, Valves, Pressure Relief Devices and Other
Connectors
a)
Pumps and valves in heavy liquid service, pressure relief devices in light
liquid or heavy liquid service and flanges and other connectors must be
monitored within 5 days by the method specified in Section 724.963(b),
if evidence of a potential leak is found by visual, audible, olfactory, or
any other detection method.
b)
If an instrument reading of 10,000 ppm or greater is measured, a leak is
detected.
c)
Repairs
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1)
When a leak is detected, it must be repaired as soon as
practicable, but not later than 15 calendar days after it is
detected, except as provided in Section 724.959.
2)
The first attempt at repair must be made no later than 5 calendar
days after each leak is detected.
d)
First attempts at repair include, but are not limited to, the best practices
described under Section 724.957(e).
e)
Any connector that is inaccessible or is ceramic or ceramic-lined (e.g.,
porcelain, glass, or glass-lined) is exempt from the monitoring
requirements of subsection (a) of this Section and from the
recordkeeping requirements of Section 724.964.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 724.964
Recordkeeping Requirements
a)
Lumping Units
1)
Each owner or operator subject to the provisions of this Subpart
shall comply with the recordkeeping requirements of this Section.
2)
An owner or operator of more than one hazardous waste
management unit subject to the provisions of this Subpart may
comply with the recordkeeping requirements for these hazardous
waste management units in one recordkeeping system if the
system identifies each record by each hazardous waste
management unit.
b)
Owners and operators shall record the following information in the
facility operating record:
1)
For each piece of equipment to which this Subpart applies:
A)
Equipment identification number and hazardous waste
management unit identification.
B)
Approximate locations within the facility (e.g., identify
the hazardous waste management unit on a facility plot
plan).
C)
Type of equipment (e.g., a pump or pipeline valve).
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D)
Percent-by-weight total organics in the hazardous
wastestream at the equipment.
E)
Hazardous waste state at the equipment (e.g., gas-vapor
or liquid).
F)
Method of compliance with the standard (e.g., “monthly
leak detection and repair” or “equipped with dual
mechanical seals”).
2)
fFor facilities than comply with the provisions of Section
724.933(a)(2), an implementation schedule as specified in that
Section.
3)
Where an owner or operator chooses to use test data to
demonstrate the organic removal efficiency or total organic
compound concentration achieved by the control device, a
performance test plan as specified in Section 724.935(b)(3).
4)
Documentation of compliance with Section 724.960, including
the detailed design documentation or performance test results
specified in Section 724.935(b)(4).
c)
When each leak is detected as specified in Sections 724.952, 724.953,
724.957 or 724.958, the following requirements apply:
1)
A weatherproof and readily visible identification, marked with
the equipment identification number, the date evidence of a
potential leak was found in accordance with Section 724.958(a),
and the date the leak was detected, must be attached to the
leaking equipment.
2)
The identification on equipment except on a valve, may be
removed after it has been repaired.
3)
The identification on a valve may be removed after it has been
monitored for 2 successive months as specified in Section
724.957(c) and no leak has been detected during those 2 months.
d)
When each leak is detected as specified in Sections 724.952, 724.953,
724.957 or 724.958, the following information must be recorded in an
inspection log and must be kept in the facility operating record:
1)
The instrument and operator identification numbers and the
equipment identification number.
214
2)
The date evidence of a potential leak was found in accordance
with Section 724.958(a).
3)
The date the leak was detected and the dates of each attempt to
repair the leak.
4)
Repair methods applied in each attempt to repair the leak.
5)
“Above 10,000”, if the maximum instrument reading measured
by the methods specified in Section 724.963(b) after each repair
attempt is equal to or greater than 10,000 ppm.
6)
“Repair delayed” and the reason for the delay if a leak is not
repaired within 15 calendar days after discovery of the leak.
7)
Documentation supporting the delay of repair of a valve in
compliance with Section 724.959(c).
8)
The signature of the owner or operator (or designate) whose
decision it was that repair could not be effected without a
hazardous waste management unit shutdown.
9)
The expected date of successful repair of the leak if a leak is not
repaired within 15 calendar days.
10)
The date of successful repair of the leak.
e)
Design documentation and monitoring, operating and inspection
information for each closed-vent system and control device required to
comply with the provisions of Section 724.960 must be recorded and
kept up-to-date in the facility operating record as specified in Section
724.935(c)(1) and (c)(2), and monitoring, operating and inspection
information in Section 724.935(c)(3) through (c)(8).
f)
For a control device other than a thermal vapor incinerator, catalytic
vapor incinerator, flare, boiler, process heater, condenser, or carbon
adsorption system, the Agency shall specify the appropriate
recordkeeping requirements, indicating proper operation and
maintenance of the control device, in the RCRA permit.
g)
The following information pertaining to all equipment subject to the
requirements in Sections 724.952 through 724.960 must be recorded in a
log that is kept in the facility operating record:
215
1)
A list of identification numbers for equipment (except welded
fittings) subject to the requirements of this Subpart.
2)
List of Equipment
A)
A list of identification numbers for equipment that the
owner or operator elects to designate for no detectable
emissions, as indicated by an instrument reading of less
than 500 ppm above background, under the provisions of
Sections 724.952(e), 724.953(i) and 724.957(f).
B)
The designation of this equipment as subject to the
requirements of Sections 724.952(e), 724.953(i) or
724.957(f) must be signed by the owner or operator.
3)
A list of equipment identification numbers for pressure relief
devices required to comply with Section 724.954(a).
4)
Compliance tests.
A)
The dates of each compliance test required in Sections
724.952(e), 724.953(i), 724.954 and 724.957(f).
B)
The background level measured during each compliance
test.
C)
The maximum instrument reading measured at the
equipment during each compliance test.
5)
A list of identification numbers for equipment in vacuum service.
6)
Identification, either by list or location (area or group), of
equipment that contains or contacts hazardous waste with an
organic concentration of at least 10% by weight for a period of
less than 300 hours per year.
h)
The following information pertaining to all valves subject to the
requirements of Section 724.957(g) and (h) must be recorded in a log
that is kept in the facility operating record:
1)
A list of identification numbers for valves that are designated as
unsafe to monitor, an explanation for each valve stating why the
valve is unsafe to monitor, and the plan for monitoring each
valve.
216
2)
A list of identification numbers for valves that are designated as
difficult to monitor, an explanation for each valve stating why the
valve is difficult to monitor, and the planned schedule for
monitoring each valve.
i)
The following information must be recorded in the facility operating
record for valves complying with Section 724.962:
1)
A schedule of monitoring.
2)
The percent of valves found leaking during each monitoring
period.
j)
The following information must be recorded in a log that is kept in the
facility operating record:
1)
Criteria required in Sections 724.952(d)(5)(B) and 724.953(e)(2)
and an explanation of the design criteria.
2)
Any changes to these criteria and the reasons for the changes.
k)
The following information must be recorded in a log that is kept in the
facility operating record for use in determining exemptions as provided
in Section 724.950 and other specific Subparts:
1)
An analysis determining the design capacity of the hazardous
waste management unit.
2)
A statement listing the hazardous waste influent to and effluent
from each hazardous waste management unit subject to the
requirements in Sections 724.960 and an analysis determining
whether these hazardous wastes are heavy liquids.
3)
An up-to-date analysis and the supporting information and data
used to determine whether or not equipment is subject to the
requirements in Sections 724.952 through 724.960. The record
must include supporting documentation as required by Section
724.963(d)(3) when application of the knowledge of the nature of
the hazardous wastestream or the process by which it was
produced is used. If the owner or operator takes any action
(e.g., changing the process that produced the waste) that could
result in an increase in the total organic content of the waste
contained in or contacted by equipment determined not to be
subject to the requirements in Sections 724.952 through 724.960,
then a new determination is required.
217
l)
Records of the equipment leak information required by subsection (d) of
this Section and the operating information required by subsection (e) of
this Section need be kept only 3 years.
m)
The owner or operator of any facility that is subject to this Subpart and
to regulations at 40 CFR 60, Subpart VV, or 40 CFR 61, Subpart V,
incorporated by reference in 35 Ill. Adm. Code 720.111, may elect to
determine compliance with this Subpart by documentation either
pursuant to Section 724.964, or pursuant to those provisions of 40 CFR
60 or 61, to the extent that the documentation under the regulation at 40
CFR 60 or 61 duplicates the documentation required under this Subpart.
The documentation under the regulation at 40 CFR 60 or 61 must be
kept with or made readily available with the facility operating record.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
SUBPART CC: AIR EMISSION STANDARDS FOR TANKS,
SURFACE IMPOUNDMENTS, AND CONTAINERS
Section 724.980
Applicability
a)
The requirements of this Subpart apply, effective October 6, 1996, to
owners and operators of all facilities that treat, store, or dispose of
hazardous waste in tanks, surface impoundments, or containers subject to
724.Subparts I, J, or K, except as Section 724.101 and subsection (b)
belowof this Section provide otherwise.
BOARD NOTE: USEPA adopted these regulations at 59 Fed. Reg.
62896 (Dec. 6, 1994), effective June 6, 1995. At 60 Fed. Reg. 26828
(May 19, 1995), 60 Fed. Reg. 56952 (Nov. 13, 1995), and 61 Fed.
Reg. 28508 (June 5, 1996), USEPA delayed the effective date until
October 6, 1996. If action by USEPA or a decision of a federal court
changes the effectiveness of these regulations, the Board does not intend
that the 724.Subpart CC rules be enforceable to the extent that they
become more stringent that the federal regulations upon which they are
based.
b)
The requirements of this Subpart do not apply to the following waste
management units at the facility:
1)
A waste management unit that holds hazardous waste placed in
the unit before October 6, 1996, and in which no hazardous
waste is added to the unit on or after this date.
218
2)
A container that has a design capacity less than or equal to 0.1 m
3
(3.5 ft
3
or 26.4 gal).
3)
A tank in which an owner or operator has stopped adding
hazardous waste and the owner or operator has begun
implementing or completed closure pursuant to an approved
closure plan.
4)
A surface impoundment in which an owner or operator has
stopped adding hazardous waste (except to implement an
approved closure plan) and the owner or operator has begun
implementing or completed closure pursuant to an approved
closure plan.
5)
A waste management unit that is used solely for on-site treatment
or storage of hazardous waste that is generated as the result of
implementing remedial activities required pursuant to the Act or
Board regulations or under the corrective action authorities of
RCRA sections 3004(u), 3004(v) or 3008(h); CERCLA
authorities; or similar federal or state authorities.
6)
A waste management unit that is used solely for the management
of radioactive mixed waste in accordance with all applicable
regulations under the authority of the Atomic Energy Act (42
U.S.C. 2011 et seq.) and the Nuclear Waste Policy Act.
7)
A hazardous waste management unit that the owner or operator
certifies is equipped with and operating air emission controls in
accordance with the requirements of an applicable federal Clean
Air Act regulation codified under 40 CFR 60, 61, or 63. For the
purpose of complying with this subsection (b)(7), a tank for
which the air emission control includes an enclosure, as opposed
to a cover, must be in compliance with the enclosure and control
device requirements of Section 724.984(i), except as provided in
Section 724.982(c)(5).
8)
A tank that has a process vent, as defined in 35 Ill. Adm. Code
724.931.
c)
For the owner and operator of a facility subject to this Subpart and
whothat received a final RCRA permit prior to October 6, 1996, the
requirements of this Subpart shall be incorporated into the permit when
the permit is reissued, renewed, or modified in accordance with the
requirements of 35 Ill. Adm. Code 703 and 705. Until such date when
219
the owner and operator receives a final permit incorporating the
requirements of this Subpart, the owner and operator is subject to the
requirements of 35 Ill. Adm. Code 725.Subpart CC.
d)
The requirements of this Subpart, except for the recordkeeping
requirements specified in Section 724.989(i), are stayed for a tank or
container used for the management of hazardous waste generated by
organic peroxide manufacturing and its associated laboratory operations,
when the owner or operator of the unit meets all of the following
conditions:
1)
The owner or operator identifies that the tank or container
receives hazardous waste generated by an organic peroxide
manufacturing process producing more than one functional family
of organic peroxides or multiple organic peroxides within one
functional family, that one or more of these organic peroxides
could potentially undergo self-accelerating thermal decomposition
at or below ambient temperatures, and that organic peroxides are
the predominant products manufactured by the process. For the
purposes of this subsection, “organic peroxide” means an organic
compound that contains the bivalent -O-O- structure and which
may be considered to be a sturctural structural derivative of
hydrogen peroxide where one or both of the hydrogen atoms has
been replaced by an organic radical.
2)
The owner or operator prepares documentation, in accordance
with Section 724.989(i), explaining why an undue safety hazard
would be created if air emission controls specified in Sections
724.984 through 724.987 are installed and operated on the tanks
and containers used at the facility to manage the hazardous waste
generated by the organic peroxide manufacturing process or
processes meeting the conditions of subsection (d)(1) aboveof this
Section.
3)
The owner or operator notifies the Agency in writing that
hazardous waste generated by an organic peroxide manufacturing
process or processes meeting the conditions of subsection (d)(1)
aboveof this Section are managed at the facility in tanks or
containers meeting the conditions of subsection (d)(2) aboveof
this Section. The notification must state the name and address of
the facility and be signed and dated by an authorized
representative of the facility owner or operator.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
220
Section 724.982
Standards: General
a)
This Section applies to the management of hazardous waste in tanks,
surface impoundments, and containers subject to this Subpart.
b)
The owner or operator shall control air emissions from each waste
management unit in accordance with standards specified in Section
724.984 through 724.987, as applicable to the waste management unit,
except as provided for in subsection (c) belowof this Section.
c)
A waste management unittank, surface impoundment, or container is
exempted from standards specified in Sections 724.984 through 724.987,
as applicable, provided that all hazardous waste placed in the waste
management unit is determined by the owner or operator to meet
eitherone of the following conditions:
1)
The average VO concentration of theA tank, surface
impoundment, or container for which all hazardous waste
entering the unit has an average VO concentration at the point of
waste origination isof less than 100500 parts per million by
weight (ppmw). The average VO concentration shall be
determined by the procedures specified in Section 724.983(a).
The owner or operator shall review and update, as necessary, this
determination at least once every 12 months following the date of
the initial determination for the hazardous waste streams entering
the unit.
2)
TA tank, surface impoundment, or container for which the
organic content of all the hazardous waste entering the waste
management unit has been reduced by an organic destruction or
removal process that achieves any one of the following
conditions:
A)
The process removes or destroys the organics contained in
the hazardous waste to a level such that the average VO
concentration of the hazardous waste at the point of waste
treatment is less than the exit concentration limit (C
t
)
established for the process. The average VO
concentration of the hazardous waste at the point of waste
treatment and the exit concentration limit for the process
shall be determined using the procedures specified in
Section 724.983(b).
B)
The process removes or destroys the organics contained in
the hazardous waste to a level such that the organic
221
reduction efficiency (R) for the process is equal to or
greater than 95 percent%, and the average VO
concentration of the hazardous waste at the point of waste
treatment is less than 50100 ppmw. The organic
reduction efficiency for the process and the average VO
concentration of the hazardous waste at the point of waste
treatment shall be determined using the procedures
specified in Section 724.983(b).
C)
The process removes or destroys the organics contained in
the hazardous waste to such a level such that the actual
organic mass removal rate (MR) for the process is equal
to or greater than the required organic mass removal rate
(RMR) established for the process. The required organic
mass removal rate and the actual organic mass removal
rate for the process shall must be determined using the
procedures specified in Section 724.983(b).
D)
The process is a biological process that destroys or
degrades the organics contained in the hazardous waste so
that either of the following conditions is met:
i)
The organic reduction efficiency (R) for the
process is equal to or greater than 95 percent%,
and the organic biodegradation efficiency (R
bio
) for
the process is equal to or greater than 95
percent%. The organic reduction efficiency and
the organic biodegradation efficiency for the
process shall be determined in accordance
withusing the procedures specified in Section
724.983(b).
ii)
The total actual organic mass biodegradation rate
(MR
bio
) for all hazardous waste treated by the
process is equal to or greater than the required
organic mass removal rate (RMR). The required
organic mass removal rate and the actual organic
mass biodegradation rate for the process shall be
determined using the procedures specified in
Section 724.983(b).
E)
The process removes or destroys the organics contained in
the hazardous waste and meets all of the following
conditions:
222
i)
All of the materials entering the process are
hazardous wastes.
ii)
From the point of waste origination through the
point where the hazardous waste enters the
treatment process, the hazardous waste is
continuously managed in waste management units
whichthat use air emission controls in accordance
with the standards specified in Sections 724.984
through 724.987, as applicable to the waste
management unit.
ii)
From the point of waste origination through the
point where the hazardous waste enters the
treatment process, any transfer of the hazardous
waste is accomplished through continuous hard-
piping or other closed system transfer that does not
allow exposure of the waste to the atmosphere.
BOARD NOTE: The USEPA considers a drain
system that meets the requirements of 40 CFR 63,
subpart RR, “National Emission Standards for
Individual Drain Systems”, to be a closed system.
iii)
The average VO concentration of the hazardous
waste at the point of waste treatment is less than
the lowest average VO concentration at the point
of waste origination, determined for each of the
individual hazardous waste streams entering the
process, or 100500 ppmw, whichever value is
lower. The average VO concentration of each
individual hazardous waste stream at the point of
waste origination shall be determined using the
procedures specified in Section 724.983(a). The
average VO concentration of the hazardous waste
at the point of waste treatment shall be determined
using the procedures specified in Section
724.983(b).
F)
A process that removes or destroys the organics contained
in the hazardous waste to a level such that the organic
reduction efficiency (R) for the process is equal to or
greater than 95% and the owner or operator certifies that
the average VO concentration at the point of waste
origination for each of the individual waste streams
223
entering the process is less than 10,000 ppmw. The
organic reduction efficiency for the process and the
average VO concentration of the hazardous waste at the
point of waste origination shall be determined using the
procedures specified in Section 724.983(b) and Section
724.983(a), respectively.
FG)
A hazardous waste incinerator for which either of the
owner or operator has eitherfollowing conditions is true:
i)
BThe owner or operator has been issued a final
permit under 35 Ill. Adm. Code 702, 703, and
705, and designs and operates the unit in
accordance with that implements the requirements
of 72435 Ill. Adm. Code 726.Subpart OH; or
ii)
HThe owner or operator has certified
compliancedesigned and operates the incinerator in
accordance with the interim status requirements of
35 Ill. Adm. Code 725.Subpart O.
GH)
A boiler or industrial furnace for which either of the
owner or operator has eitherfollowing conditions is true:
i)
BThe owner or operator has been issued a final
permit under 35 Ill. Adm. Code 702, 703, and
705, and designs and operates the unit in
accordance with that implements the requirements
of 35 Ill. Adm. Code 726.Subpart H; or
ii)
HThe owner or operator has certified
compliancedesigned and operates the boiler or
industrial furnace in accordance with the interim
status requirements of 35 Ill. Adm. Code
726.Subpart H.
I)
For the purpose of determining the performance of an
organic destruction or removal process in accordance with
the conditions in each of subsections (c)(2)(A) through
(c)(2)(F) of this Section, the owner or operator shall
account for VO concentrations determined to be below the
limit of detection of the analytical method by using the
following VO concentration:
224
i)
If Method 25D in 40 CFR 60, appendix A,
incorporated by reference in 35 Ill. Adm. Code
720.111, is used for the analysis, one-half the
blank value determined in the method.
ii)
If any other analytical method is used, one-half the
limit of detection established for the method.
3)
A tank used for biological treatment of hazardous waste in
accordance with the requirements of subsection (c)(2)(D) of this
Section.
4)
A tank, surface impoundment, or container for which all
hazardous waste placed in the unit fulfills either of the following
conditions:
A)
It meets the numerical concentration limits for organic
hazardous constituents, applicable to the hazardous waste,
as specified in 35 Ill. Adm. Code 728.Table T; or
B)
It has been treated by the treatment technology established
by USEPA for the waste in 35 Ill. Adm. Code
728.142(a), or treated by an equivalent method of
treatment approved by the Agency pursuant to 35 Ill.
Adm. Code 728.142(b).
5)
A tank used for bulk feed of hazardous waste to a waste
incinerator and all of the following conditions are met:
A)
The tank is located inside an enclosure vented to a control
device that is designed and operated in accordance with all
applicable requirements specified under 40 CFR 61,
subpart FF, “National Emission Standards for Benzene
Waste Operations”, incorporated by reference in 35 Ill.
Adm. Code 720.111, for a facility at which the total
annual benzene quantity from the facility waste is equal to
or greater than 10 megagrams (11 tons) per year;
B)
The enclosure and control device serving the tank were
installed and began operation prior to November 25,
1996; and
C)
The enclosure is designed and operated in accordance with
the criteria for a permanent total enclosure as specified in
“Procedure T--Criteria for and Verification of a
225
Permanent or Temporary Total Enclosure” under 40 CFR
52.741, appendix B, incorporated by reference in 35 Ill.
Adm. Code 720.111. The enclosure may have permanent
or temporary openings to allow worker access; passage of
material into or out of the enclosure by conveyor,
vehicles, or other mechanical or electrical equipment; or
to direct air flow into the enclosure. The owner or
operator shall perform the verification procedure for the
enclosure as specified in Section 5.0 to “Procedure T--
Criteria for and Verification of a Permanent or Temporary
Total Enclosure” annually.
d) When a process is used for the purpose of treating a hazardous waste to
meet one of the sets of conditions specified in subsections (c)(2)(A)
through (c)(2)(E) above, each material removed from or exiting the
process that is not a hazardous waste but which has an average VO
concentration equal to or greater than 100 ppmw shall be managed in a
waste management unit in accordance with the requirements of
subsection (b) above.
ed)
The Agency may at any time perform or request that the owner or
operator perform a waste determination for a hazardous waste managed
in a tank, surface impoundment, or container that is exempted from
using air emission controls under the provisions of this Section as
follows:
1)
The waste determination for average VO concentration of a
hazardous waste at the point of waste origination shall be
performed using direct measurement in accordance with the
applicable requirements of Section 724.983(a). The waste
determination for a hazardous waste at the point of waste
treatment shall be performed in accordance with the applicable
requirements of Section 724.983(b).
2)
In performing a waste determination pursuant to subsection (d)(1)
of this Section, the sample preparation and analysis shall be
conducted as follows:
A)
In accordance with the method used by the owner or
operator to perform the waste analysis, except in the case
specified in subsection (d)(2)(B) of this Section.
B)
If the Agency determines that the method used by the
owner or operator was not appropriate for the hazardous
waste managed in the tank, surface impoundment, or
226
container, then the Agency may choose an appropriate
method.
23)
Where the owner or operator is requested to perform the waste
determination, the Agency may elect to have an authorized
representative observe the collection of the hazardous waste
samples used for the analysis.
34)
Where the results of the waste determination performed or
requested by the Agency do not agree with the results of a waste
determination performed by the owner or operator using
knowledge of the waste, then the results of the waste
determination performed in accordance with the requirements of
subsection (ed)(1) aboveof this Section shall be used to establish
compliance with the requirements of this Subpart.
45)
Where the owner or operator has used an averaging period
greater than one hour for determining the average VO
concentration of a hazardous waste at the point of waste
origination, the Agency may elect to establish compliance with
this Subpart by performing or requesting that the owner or
operator perform a waste determination using direct measurement
based on waste samples collected within a one-hour period as
follows:
A)
The average VO concentration of the hazardous waste at
the point of waste origination shall be determined by
direct measurement in accordance with the requirements
of Section 724.983(a).
B)
Results of the waste determination performed or requested
by the Agency showing that the average VO concentration
of the hazardous waste at the point of waste origination is
equal to or greater than 100500 ppmw shall constitute
noncompliance with this Subpart, except in a case as
provided for in subsection (ed)(45)(C) belowof this
Section.
C)
Where the average VO concentration of the hazardous
waste at the point of waste origination previously has been
determined by the owner or operator using an averaging
period greater than one hour to be less than 100500 ppmw
but because of normal operating process variations the VO
concentration of the hazardous waste determined by direct
measurement for any given one-hour period may be equal
227
to or greater than 100500 ppmw, information that was
used by the owner or operator to determine the average
VO concentration of the hazardous waste (e.g., test
results, measurements, calculations, and other
documentation) and recorded in the facility records in
accordance with the requirements of Section 724.983(a)
and Section 724.989 shall be considered by the Agency
together with the results of the waste determination
performed or requested by the Agency in establishing
compliance with this Subpart.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 724.983
Waste Determination Procedures
a)
Waste determination procedure for average volatile organic (VO)
concentration of a hazardous waste at the point of waste origination.
1)
An owner or operator shall determine the average VO
concentration at the point of waste origination for each hazardous
waste placed in a waste management units exempted under the
provisions of Section 724.982(c)(1) from using air emission
controls in accordance with standards specified in Section
724.984 through Section 724.987, as applicable to the waste
management unit.
2)
The average VO concentration of a hazardous waste at the point
of waste origination for a hazardous waste shallmay be
determined in accordance with the procedures specified in 35 Ill.
Adm. Code 725.984(a)(2) through (a)(64).
b)
Waste determination procedures for treated hazardous waste.
1)
An owner or operator shall perform the applicable waste
determinations for each treated hazardous waste placed in a waste
management units exempted under the provisions of Section
724.982(c)(2) from using air emission controls in accordance
with standards specified in Sections 724.984 through 724.987, as
applicable to the waste management unit.
2)
The waste determination for a treated hazardous waste shall be
performed in accordance with the procedures specified in 35 Ill.
Adm. Code 725.984(b)(2) through (b)(109), as applicable to the
treated hazardous waste.
228
c)
Procedure to determine the maximum organic vapor pressure of a
hazardous waste in a tank.
1)
An owner or operator shall determine the maximum organic
vapor pressure for each hazardous waste placed in a tanks using
air emissionTank Level 1 controls in accordance with standards
specified in Section 724.984(c).
2)
The maximum organic vapor pressure of the hazardous waste
shallmay be determined in accordance with the procedures
specified in 35 Ill. Adm. Code 725.984(c)(2) through (c)(4).
d)
The procedure for determining no detectable organic emissions for the
purpose of complying with this Subpart must be conducted in accordance
with the procedures specified in 40 CFR 265.984(d).
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 724.984
Standards: Tanks
a) This Section applies to owners and operators of tanks subject to this
Subpart into which any hazardous waste is placed, except for the
following tanks:
1) A tank in which all hazardous waste entering the tank meets the
conditions specified in Section 724.982(c), or
2) A tank used for biological treatment of hazardous waste in
accordance with the requirements of Section 724.982(c)(2)(D).
b) The owner or operator shall place the hazardous waste into one of the
following tanks:
1) A tank equipped with a cover (e.g., a fixed roof) that is vented
through a closed-vent system to a control device in accordance
with the requirements specified in subsection (d) below;
2) A tank equipped with a fixed roof and internal floating roof in
accordance with the requirements of Section 724.991;
3) A tank equipped with an external floating roof in accordance with
the requirements of Section 724.991; or
4) A pressure tank that is designed to operate as a closed system
such that the tank operates with no detectable organic emissions
229
at all times that hazardous waste is in the tank except as provided
for in subsection (g) below.
c) As an alternative to complying with subsection (b) above, an owner or
operator may place hazardous waste in a tank equipped with a cover
(e.g., a fixed roof) meeting the requirements specified in subsection
(d)(1) below when the hazardous waste is determined to meet all of the
following conditions:
1) The hazardous waste is not mixed, stirred, agitated, or circulated
within the tank by the owner or operator using a process that
results in splashing, frothing, or visible turbulent flow on the
waste surface during normal process operations;
2) The hazardous waste in the tank is not heated by the owner or
operator except during conditions requiring that the waste be
heated to prevent the waste from freezing or to maintain adequate
waste flow conditions for continuing normal process operations;
3) The hazardous waste in the tank is not treated by the owner or
operator using a waste stabilization process or a process that
produces an exothermic reaction; and
4) The maximum organic vapor pressure of the hazardous waste in
the tank, as determined using the procedure specified in Section
724.983(c), is less than the following applicable value:
A) If the tank design capacity is equal to or greater than 151
m
3
(5333 ft
3
or 39,887 gal), then the maximum organic
vapor pressure shall be less than 5.2 kPa (0.75 psia or 39
mm Hg);
B) If the tank design capacity is equal to or greater than 75
m
3
(2649 ft
3
or 19,810 gal) but less than 151 m
3
(5333 ft
3
or 39,887 gal), then the maximum organic vapor pressure
shall be less than 27.6 kPa (4.0 psia or 207 mm Hg); or
C) If the tank design capacity is less than 75 m
3
(2649 ft
3
or
19,810 gal), then the maximum organic vapor pressure
shall be less than 76.6 kPa (11.1 psia or 574 mm Hg).
d) To comply with subsection (b)(1) above, the owner or operator shall
design, install, operate, and maintain a cover that vents the organic
vapors emitted from hazardous waste in the tank through a closed-vent
system connected to a control device.
230
1) The cover shall be designed and operated to meet the following
requirements:
A) The cover and all cover openings (e.g., access hatches,
sampling ports, and gauge wells) shall be designed to
operate with no detectable organic emissions when all
cover openings are secured in a closed, sealed position;
and
B) Each cover opening shall be secured in a closed, sealed
position (e.g., covered by a gasketed lid or cap) at all
times that hazardous waste is in the tank except as
provided for in subsection (f) below.
2) The closed-vent system and control device shall be designed and
operated in accordance with the requirements of Section 724.987.
e) The owner and operator shall install, operate, and maintain enclosed
pipes or other closed-systems to:
BOARD NOTE: U.S. EPA considers a drain system that meets the
requirements of 40 CFR 61.346(a)(1) or (b)(1) through (b)(3) to be a
“closed-system”. The Board intends that this meaning be included in the
use of that term for the purposes of this Subpart.
1) Transfer all hazardous waste to the tank from another tank,
surface impoundment, or container subject to this Subpart except
for those hazardous wastes that meet the conditions specified in
Section 724.982(c); and
2) Transfer all hazardous waste from the tank to another tank,
surface impoundment, or container subject to this Subpart except
for those hazardous wastes that meet the conditions specified in
Section 724.982(c).
f) Each cover opening shall be secured in a closed, sealed position (e.g.,
covered by a gasketed lid) at all times that hazardous waste is in the tank
except when it is necessary to use the cover opening to:
1) Add, remove, inspect, or sample the material in the tank;
2) Inspect, maintain, repair, or replace equipment located inside the
tank; or
231
3) Vent gases or vapors from the tank to a closed-vent system
connected to a control device that is designed and operated in
accordance with the requirements of Section 724.987.
g) One or more safety devices that vent directly to the atmosphere may be
used on the tank, cover, closed-vent system, or control device provided
each safety device meets all of the following conditions:
1) The safety device is not used for planned or routine venting of
organic vapors from the tank or closed-vent system connected to
a control device; and
2) The safety device remains in a closed, sealed position at all
times, except when an unplanned event requires that the device
open for the purpose of preventing physical damage or permanent
deformation of the tank, cover, closed-vent system, or control
device in accordance with good engineering and safety practices
for handling flammable, combustible, explosive, or other
hazardous materials. An example of an unplanned event is a
sudden power outage.
a)
The provisions of this Section apply to the control of air pollutant
emissions from tanks for which Section 724.982(b) references the use of
this Section for such air emission control.
b)
The owner or operator shall control air pollutant emissions from each
tank subject to this Section in accordance with the following
requirements, as applicable:
1)
For a tank that manages hazardous waste that meets all of the
conditions specified in subsections (b)(1)(A) through (b)(1)(C) of
this Section, the owner or operator shall control air pollutant
emissions from the tank in accordance with the Tank Level 1
controls specified in subsection (c) of this Section or the Tank
Level 2 controls specified in subsection (d) of this Section.
A)
The hazardous waste in the tank has a maximum organic
vapor pressure that is less than the maximum organic
vapor pressure limit for the tank’s design capacity
category as follows:
i)
For a tank design capacity equal to or greater than
151 m
3
(39,900 gal), the maximum organic vapor
pressure limit for the tank is 5.2 kPa (0.75 psig).
232
ii)
For a tank design capacity equal to or greater than
75 m
3
(19,800 gal) but less than 151 m
3
(39,900
gal), the maximum organic vapor pressure limit
for the tank is 27.6 kPa (4.00 psig).
iii)
For a tank design capacity less than 75 m
3
(19,800
gal), the maximum organic vapor pressure limit
for the tank is 76.6 kPa (11.1 psig).
B)
The hazardous waste in the tank is not heated by the
owner or operator to a temperature that is greater than the
temperature at which the maximum organic vapor
pressure of the hazardous waste is determined for the
purpose of complying with subsection (b)(1)(A) of this
Section.
C)
The hazardous waste in the tank is not treated by the
owner or operator using a waste stabilization process, as
defined in 35 Ill. Adm. Code 725.981.
2)
For a tank that manages hazardous waste that does not meet all of
the conditions specified in subsections (b)(1)(A) through
(b)(1)(C) of this Section, the owner or operator shall control air
pollutant emissions from the tank by using Tank Level 2 controls
in accordance with the requirements of subsection (d) of this
Section. Examples of tanks required to use Tank Level 2
controls include a tank used for a waste stabilization process and
a tank for which the hazardous waste in the tank has a maximum
organic vapor pressure that is equal to or greater than the
maximum organic vapor pressure limit for the tank’s design
capacity category as specified in subsection (b)(1)(A) of this
Section.
c)
Owners and operators controlling air pollutant emissions from a tank
using Tank Level 1 controls must meet the requirements specified in
subsections (c)(1) through (c)(4) of this Section:
1)
The owner or operator shall determine the maximum organic
vapor pressure for a hazardous waste to be managed in the tank
using Tank Level 1 controls before the first time the hazardous
waste is placed in the tank. The maximum organic vapor
pressure must be determined using the procedures specified in
Section 724.983(c). Thereafter, the owner or operator shall
perform a new determination whenever changes to the hazardous
waste managed in the tank could potentially cause the maximum
233
organic vapor pressure to increase to a level that is equal to or
greater than the maximum organic vapor pressure limit for the
tank design capacity category specified in subsection (b)(1)(A) of
this Section, as applicable to the tank.
2)
The tank must be equipped with a fixed roof designed to meet the
following specifications:
A)
The fixed roof and its closure devices must be designed to
form a continuous barrier over the entire surface area of
the hazardous waste in the tank. The fixed roof may be a
separate cover installed on the tank (e.g., a removable
cover mounted on an open-top tank) or may be an integral
part of the tank structural design (e.g., a horizontal
cylindrical tank equipped with a hatch).
B)
The fixed roof must be installed in a manner such that
there are no visible cracks, holes, gaps, or other open
spaces between roof Section joints or between the
interface of the roof edge and the tank wall.
C)
Each opening in the fixed roof must be either:
i)
Equipped with a closure device designed to operate
such that when the closure device is secured in the
closed position there are no visible cracks, holes,
gaps, or other open spaces in the closure device or
between the perimeter of the opening and the
closure device; or
ii)
Connected by a closed-vent system that is vented
to a control device. The control device must
remove or destroy organics in the vent stream, and
it must be operating whenever hazardous waste is
managed in the tank.
D)
The fixed roof and its closure devices must be made of
suitable materials that will minimize exposure of the
hazardous waste to the atmosphere, to the extent practical,
and will maintain the integrity of the fixed roof and
closure devices throughout their intended service life.
Factors to be considered when selecting the materials for
and designing the fixed roof and closure devices must
include the following: the organic vapor permeability; the
effects of any contact with the hazardous waste or its
234
vapors managed in the tank; the effects of outdoor
exposure to wind, moisture, and sunlight; and the
operating practices used for the tank on which the fixed
roof is installed.
3)
Whenever a hazardous waste is in the tank, the fixed roof must
be installed with each closure device secured in the closed
position, except as follows:
A)
Opening of closure devices or removal of the fixed roof is
allowed at the following times:
i)
To provide access to the tank for performing
routine inspection, maintenance, or other activities
needed for normal operations. Examples of such
activities include those times when a worker needs
to open a port to sample the liquid in the tank, or
when a worker needs to open a hatch to maintain
or repair equipment. Following completion of the
activity, the owner or operator shall promptly
secure the closure device in the closed position or
reinstall the cover, as applicable, to the tank.
ii)
To remove accumulated sludge or other residues
from the bottom of the tank.
B)
Opening of a spring-loaded pressure-vacuum relief valve,
conservation vent, or similar type of pressure relief device
which vents to the atmosphere is allowed during normal
operations for the purpose of maintaining the tank internal
pressure in accordance with the tank design specifications.
The device must be designed to operate with no detectable
organic emissions when the device is secured in the closed
position. The settings at which the device opens must be
established such that the device remains in the closed
position whenever the tank internal pressure is within the
internal pressure operating range determined by the owner
or operator based on the tank manufacturer
recommendations, applicable regulations, fire protection
and prevention codes, standard engineering codes and
practices, or other requirements for the safe handling of
flammable, ignitable, explosive, reactive, or hazardous
materials. Examples of normal operating conditions that
may require these devices to open are during those times
when the tank internal pressure exceeds the internal
235
pressure operating range for the tank as a result of loading
operations or diurnal ambient temperature fluctuations.
C)
Opening of a safety device, as defined in 35 Ill. Adm.
Code 725.981, is allowed at any time conditions require
doing so to avoid an unsafe condition.
4)
The owner or operator shall inspect the air emission control
equipment in accordance with the following requirements.
A)
The fixed roof and its closure devices must be visually
inspected by the owner or operator to check for defects
that could result in air pollutant emissions. Defects
include, but are not limited to, visible cracks, holes, or
gaps in the roof sections or between the roof and the tank
wall; broken, cracked, or otherwise damaged seals or
gaskets on closure devices; and broken or missing
hatches, access covers, caps, or other closure devices.
B)
The owner or operator shall perform an initial inspection
of the fixed roof and its closure devices on or before the
date that the tank becomes subject to this Section.
Thereafter, the owner or operator shall perform the
inspections at least once every year except under the
special conditions provided for in subsection (l) of this
Section.
C)
In the event that a defect is detected, the owner or
operator shall repair the defect in accordance with the
requirements of subsection (k) of this Section.
D)
The owner or operator shall maintain a record of the
inspection in accordance with the requirements specified
in Section 724.989(b).
d)
Owners and operators controlling air pollutant emissions from a tank
using Tank Level 2 controls must use one of the following tanks:
1)
A fixed-roof tank equipped with an internal floating roof in
accordance with the requirements specified in subsection (e) of
this Section;
2)
A tank equipped with an external floating roof in accordance with
the requirements specified in subsection (f) of this Section;
236
3)
A tank vented through a closed-vent system to a control device in
accordance with the requirements specified in subsection (g) of
this Section;
4)
A pressure tank designed and operated in accordance with the
requirements specified in subsection (h) of this Section; or
5)
A tank located inside an enclosure that is vented through a
closed-vent system to an enclosed combustion control device in
accordance with the requirements specified in subsection (i) of
this Section.
e)
The owner or operator that controls air pollutant emissions from a tank
using a fixed roof with an internal floating roof shall meet the
requirements specified in subsections (e)(1) through (e)(3) of this
Section.
1)
The tank must be equipped with a fixed roof and an internal
floating roof in accordance with the following requirements:
A)
The internal floating roof must be designed to float on the
liquid surface except when the floating roof must be
supported by the leg supports.
B)
The internal floating roof must be equipped with a
continuous seal between the wall of the tank and the
floating roof edge that meets either of the following
requirements:
i)
A single continuous seal that is either a liquid-
mounted seal or a metallic shoe seal, as defined in
35 Ill. Adm. Code 725.981; or
ii)
Two continuous seals mounted one of this Section
the other. The lower seal may be a vapor-mounted
seal.
C)
The internal floating roof must meet the following
specifications:
i)
Each opening in a noncontact internal floating roof
except for automatic bleeder vents (vacuum
breaker vents) and the rim space vents is to
provide a projection below the liquid surface.
237
ii)
Each opening in the internal floating roof must be
equipped with a gasketed cover or a gasketed lid
except for leg sleeves, automatic bleeder vents,
rim space vents, column wells, ladder wells,
sample wells, and stub drains.
iii)
Each penetration of the internal floating roof for
the purpose of sampling must have a slit fabric
cover that covers at least 90% of the opening.
iv)
Each automatic bleeder vent and rim space vent
must be gasketed.
v)
Each penetration of the internal floating roof that
allows for passage of a ladder must have a
gasketed sliding cover.
vi)
Each penetration of the internal floating roof that
allows for passage of a column supporting the
fixed roof must have a flexible fabric sleeve seal
or a gasketed sliding cover.
2)
The owner or operator shall operate the tank in accordance with
the following requirements:
A)
When the floating roof is resting on the leg supports, the
process of filling, emptying, or refilling must be
continuous and must be completed as soon as practical.
B)
Automatic bleeder vents are to be set closed at all times
when the roof is floating, except when the roof is being
floated off or is being landed on the leg supports.
C)
Prior to filling the tank, each cover, access hatch, gauge
float well or lid on any opening in the internal floating
roof must be bolted or fastened closed (i.e., no visible
gaps). Rim space vents must be set to open only when the
internal floating roof is not floating or when the pressure
beneath the rim exceeds the manufacturer’s recommended
setting.
3)
The owner or operator shall inspect the internal floating roof in
accordance with the procedures specified as follows:
238
A)
The floating roof and its closure devices must be visually
inspected by the owner or operator to check for defects
that could result in air pollutant emissions. Defects
include, but are not limited to, any of the following:
when the internal floating roof is not floating on the
surface of the liquid inside the tank; when liquid has
accumulated on top of the internal floating roof; when any
portion of the roof seals have detached from the roof rim;
when holes, tears, or other openings are visible in the seal
fabric; when the gaskets no longer close off the hazardous
waste surface from the atmosphere; or when the slotted
membrane has more than 10% open area.
B)
The owner or operator shall inspect the internal floating
roof components as follows, except as provided in
subsection (e)(3)(C) of this Section:
i)
Visually inspect the internal floating roof
components through openings on the fixed-roof
(e.g., manholes and roof hatches) at least once
every 12 months after initial fill, and
ii)
Visually inspect the internal floating roof, primary
seal, secondary seal (if one is in service), gaskets,
slotted membranes, and sleeve seals (if any) each
time the tank is emptied and degassed and at least
once every 10 years.
C)
As an alternative to performing the inspections specified
in subsection (e)(3)(B) of this Section for an internal
floating roof equipped with two continuous seals mounted
one above the other, the owner or operator may visually
inspect the internal floating roof, primary and secondary
seals, gaskets, slotted membranes, and sleeve seals (if
any) each time the tank is emptied and degassed and at
least every five years.
D)
Prior to each inspection required by subsection (e)(3)(B)
or (e)(3)(C) of this Section, the owner or operator shall
notify the Agency in advance of each inspection to
provide the Agency with the opportunity to have an
observer present during the inspection. The owner or
operator shall notify the Agency of the date and location
of the inspection as follows:
239
i)
Prior to each visual inspection of an internal
floating roof in a tank that has been emptied and
degassed, written notification must be prepared
and sent by the owner or operator so that it is
received by the Agency at least 30 calendar days
before refilling the tank, except when an
inspection is not planned, as provided for in
subsection (e)(3)(D)(ii) of this Section.
ii)
When a visual inspection is not planned and the
owner or operator could not have known about the
inspection 30 calendar days before refilling the
tank, the owner or operator shall notify the
Agency as soon as possible, but no later than seven
calendar days before refilling of the tank. This
notification may be made by telephone and
immediately followed by a written explanation for
why the inspection is unplanned. Alternatively,
written notification, including the explanation for
the unplanned inspection, may be sent so that it is
received by the Agency at least seven calendar
days before refilling the tank.
E)
In the event that a defect is detected, the owner or
operator shall repair the defect in accordance with the
requirements of subsection (k) of this Section.
F)
The owner or operator shall maintain a record of the
inspection in accordance with the requirements specified
in Section 724.989(b).
f)
The owner or operator that controls air pollutant emissions from a tank
using an external floating roof must meet the requirements specified in
subsections (f)(1) through (f)(3) of this Section.
1)
The owner or operator shall design the external floating roof in
accordance with the following requirements:
A)
The external floating roof must be designed to float on the
liquid surface except when the floating roof must be
supported by the leg supports.
B)
The floating roof must be equipped with two continuous
seals, one above the other, between the wall of the tank
and the roof edge. The lower seal is referred to as the
240
primary seal, and the upper seal is referred to as the
secondary seal.
i)
The primary seal must be a liquid-mounted seal or
a metallic shoe seal, as defined in 35 Ill. Adm.
Code 725.981. The total area of the gaps between
the tank wall and the primary seal must not exceed
212 square centimeters (cm
2
) per meter (10.0
square inches (in
2
) per foot) of tank diameter, and
the width of any portion of these gaps must not
exceed 3.8 centimeters (cm) (1.5 in). If a metallic
shoe seal is used for the primary seal, the metallic
shoe seal must be designed so that one end extends
into the liquid in the tank and the other end
extends a vertical distance of at least 61 cm (24 in)
above the liquid surface.
ii)
The secondary seal must be mounted above the
primary seal and cover the annular space between
the floating roof and the wall of the tank. The total
area of the gaps between the tank wall and the
secondary seal must not exceed 21.2 cm
2
per meter
(1.00 in
2
per foot) of tank diameter, and the width
of any portion of these gaps must not exceed 1.3
cm (0.51 in).
C)
The external floating roof must meet the following
specifications:
i)
Except for automatic bleeder vents (vacuum
breaker vents) and rim space vents, each opening
in a noncontact external floating roof must provide
a projection below the liquid surface.
ii)
Except for automatic bleeder vents, rim space
vents, roof drains, and leg sleeves, each opening
in the roof must be equipped with a gasketed
cover, seal, or lid.
iii)
Each access hatch and each gauge float well must
be equipped with a cover designed to be bolted or
fastened when the cover is secured in the closed
position.
241
iv)
Each automatic bleeder vent and each rim space
vent must be equipped with a gasket.
v)
Each roof drain that empties into the liquid
managed in the tank must be equipped with a
slotted membrane fabric cover that covers at least
90% of the area of the opening.
vi)
Each unslotted and slotted guide pole well must be
equipped with a gasketed sliding cover or a
flexible fabric sleeve seal.
vii)
Each unslotted guide pole must be equipped with a
gasketed cap on the end of the pole.
viii)
Each slotted guide pole must be equipped with a
gasketed float or other device which closes off the
liquid surface from the atmosphere.
ix)
Each gauge hatch and each sample well must be
equipped with a gasketed cover.
2)
The owner or operator shall operate the tank in accordance with
the following requirements:
A)
When the floating roof is resting on the leg supports, the
process of filling, emptying, or refilling must be
continuous and must be completed as soon as practical.
B)
Except for automatic bleeder vents, rim space vents, roof
drains, and leg sleeves, each opening in the roof must be
secured and maintained in a closed position at all times
except when the closure device must be open for access.
C)
Covers on each access hatch and each gauge float well
must be bolted or fastened when secured in the closed
position.
D)
Automatic bleeder vents must be set closed at all times
when the roof is floating, except when the roof is being
floated off or is being landed on the leg supports.
E)
Rim space vents must be set to open only at those times
that the roof is being floated off the roof leg supports or
242
when the pressure beneath the rim seal exceeds the
manufacturer’s recommended setting.
F)
The cap on the end of each unslotted guide pole must be
secured in the closed position at all times except when
measuring the level or collecting samples of the liquid in
the tank.
G)
The cover on each gauge hatch or sample well must be
secured in the closed position at all times except when the
hatch or well must be opened for access.
H)
Both the primary seal and the secondary seal must
completely cover the annular space between the external
floating roof and the wall of the tank in a continuous
fashion except during inspections.
3)
The owner or operator shall inspect the external floating roof in
accordance with the procedures specified as follows:
A)
The owner or operator shall measure the external floating
roof seal gaps in accordance with the following
requirements:
i)
The owner or operator shall perform measurements
of gaps between the tank wall and the primary seal
within 60 calendar days after initial operation of
the tank following installation of the floating roof
and, thereafter, at least once every five years.
ii)
The owner or operator shall perform measurements
of gaps between the tank wall and the secondary
seal within 60 calendar days after initial operation
of the tank following installation of the floating
roof and, thereafter, at least once every year.
iii)
If a tank ceases to hold hazardous waste for a
period of one year or more, subsequent
introduction of hazardous waste into the tank must
be considered an initial operation for the purposes
of subsections (f)(3)(A)(i) and (f)(3)(A)(ii) of this
Section.
iv)
The owner or operator shall determine the total
surface area of gaps in the primary seal and in the
243
secondary seal individually using the procedure of
subsection (f)(3)(D) of this Section.
v)
In the event that the seal gap measurements do not
conform to the specifications in subsection
(f)(1)(B) of this Section, the owner or operator
shall repair the defect in accordance with the
requirements of subsection (k) of this Section.
vi)
The owner or operator shall maintain a record of
the inspection in accordance with the requirements
specified in Section 724.989(b).
B)
The owner or operator shall visually inspect the external
floating roof in accordance with the following
requirements:
i)
The floating roof and its closure devices must be
visually inspected by the owner or operator to
check for defects that could result in air pollutant
emissions. Defects include, but are not limited to,
any of the following conditions: holes, tears, or
other openings in the rim seal or seal fabric of the
floating roof; a rim seal detached from the floating
roof; all or a portion of the floating roof deck
being submerged below the surface of the liquid in
the tank; broken, cracked, or otherwise damaged
seals or gaskets on closure devices; and broken or
missing hatches, access covers, caps, or other
closure devices.
ii)
The owner or operator shall perform an initial
inspection of the external floating roof and its
closure devices on or before the date that the tank
becomes subject to this Section. Thereafter, the
owner or operator shall perform the inspections at
least once every year except for the special
conditions provided for in subsection (l) of this
Section.
iii)
In the event that a defect is detected, the owner or
operator shall repair the defect in accordance with
the requirements of subsection (k) of this Section.
244
iv)
The owner or operator shall maintain a record of
the inspection in accordance with the requirements
specified in Section 724.989(b).
C)
Prior to each inspection required by subsection (f)(3)(A)
or (f)(3)(B), the owner or operator shall notify the Agency
in advance of each inspection to provide the Agency with
the opportunity to have an observer present during the
inspection. The owner or operator shall notify the
Agency of the date and location of the inspection as
follows:
i)
Prior to each inspection to measure external
floating roof seal gaps as required under subsection
(f)(3)(A) of this Section, written notification must
be prepared and sent by the owner or operator so
that it is received by the Agency at least 30
calendar days before the date the measurements are
scheduled to be performed.
ii)
Prior to each visual inspection of an external
floating roof in a tank that has been emptied and
degassed, written notification must be prepared
and sent by the owner or operator so that it is
received by the Agency at least 30 calendar days
before refilling the tank, except when an
inspection is not planned as provided for in
subsection (f)(3)(C)(iii) of this Section.
iii)
When a visual inspection is not planned and the
owner or operator could not have known about the
inspection 30 calendar days before refilling the
tank, the owner or operator shall notify the
Agency as soon as possible, but no later than seven
calendar days before refilling of the tank. This
notification may be made by telephone and
immediately followed by a written explanation for
why the inspection is unplanned. Alternatively,
written notification, including the explanation for
the unplanned inspection, may be sent so that it is
received by the Agency at least seven calendar
days before refilling the tank.
D)
Procedure for determining the total surface area of gaps in
the primary seal and the secondary seal:
245
i)
The seal gap measurements must be performed at
one or more floating roof levels when the roof is
floating off the roof supports.
ii)
Seal gaps, if any, must be measured around the
entire perimeter of the floating roof in each place
where a 0.32 cm (0.125 in) diameter uniform
probe passes freely (without forcing or binding
against the seal) between the seal and the wall of
the tank and measure the circumferential distance
of each such location.
iii)
For a seal gap measured under subsection (f)(3) of
this Section, the gap surface area must be
determined by using probes of various widths to
measure accurately the actual distance from the
tank wall to the seal and multiplying each such
width by its respective circumferential distance.
iv)
The total gap area must be calculated by adding
the gap surface areas determined for each
identified gap location for the primary seal and the
secondary seal individually, and then dividing the
sum for each seal type by the nominal perimeter of
the tank. These total gap areas for the primary
seal and secondary seal are then compared to the
respective standards for the seal type, as specified
in subsection (f)(1)(B) of this Section.
BOARD NOTE: Subsections (f)(3)(D)(i) through
(f)(3)(D)(iv) correspond with 40 CFR
264.1084(f)(3)(i)(D)(1) through (f)(3)(i)(D)(4),
which the Board has codified here to comport with
Illinois Administrative Code format requirements.
g)
The owner or operator that controls air pollutant emissions from a tank
by venting the tank to a control device shall meet the requirements
specified in subsections (g)(1) through (g)(3) of this Section.
1)
The tank must be covered by a fixed roof and vented directly
through a closed-vent system to a control device in accordance
with the following requirements:
246
A)
The fixed roof and its closure devices must be designed to
form a continuous barrier over the entire surface area of
the liquid in the tank.
B)
Each opening in the fixed roof not vented to the control
device must be equipped with a closure device. If the
pressure in the vapor headspace underneath the fixed roof
is less than atmospheric pressure when the control device
is operating, the closure devices must be designed to
operate such that when the closure device is secured in the
closed position there are no visible cracks, holes, gaps, or
other open spaces in the closure device or between the
perimeter of the cover opening and the closure device. If
the pressure in the vapor headspace underneath the fixed
roof is equal to or greater than atmospheric pressure when
the control device is operating, the closure device must be
designed to operate with no detectable organic emissions.
C)
The fixed roof and its closure devices must be made of
suitable materials that will minimize exposure of the
hazardous waste to the atmosphere, to the extent practical,
and will maintain the integrity of the fixed roof and
closure devices throughout their intended service life.
Factors to be considered when selecting the materials for
and designing the fixed roof and closure devices must
include the following: organic vapor permeability; the
effects of any contact with the liquid and its vapor
managed in the tank; the effects of outdoor exposure to
wind, moisture, and sunlight; and the operating practices
used for the tank on which the fixed roof is installed.
D)
The closed-vent system and control device must be
designed and operated in accordance with the
requirements of Section 724.987.
2)
Whenever a hazardous waste is in the tank, the fixed roof must
be installed with each closure device secured in the closed
position and the vapor headspace underneath the fixed roof
vented to the control device except as follows:
A)
Venting to the control device is not required, and opening
of closure devices or removal of the fixed roof is allowed
at the following times:
247
i)
To provide access to the tank for performing
routine inspection, maintenance, or other activities
needed for normal operations. Examples of such
activities include those times when a worker needs
to open a port to sample liquid in the tank, or
when a worker needs to open a hatch to maintain
or repair equipment. Following completion of the
activity, the owner or operator shall promptly
secure the closure device in the closed position or
reinstall the cover, as applicable, to the tank.
ii)
To remove accumulated sludge or other residues
from the bottom of a tank.
B)
Opening of a safety device, as defined in 35 Ill. Adm.
Code 725.981, is allowed at any time conditions require
doing so to avoid an unsafe condition.
3)
The owner or operator shall inspect and monitor the air emission
control equipment in accordance with the following procedures:
A)
The fixed roof and its closure devices must be visually
inspected by the owner or operator to check for defects
that could result in air pollutant emissions. Defects
include, but are not limited to, any of the following:
visible cracks, holes, or gaps in the roof sections or
between the roof and the tank wall; broken, cracked, or
otherwise damaged seals or gaskets on closure devices;
and broken or missing hatches, access covers, caps, or
other closure devices.
B)
The closed-vent system and control device must be
inspected and monitored by the owner or operator in
accordance with the procedures specified in Section
724.987.
C)
The owner or operator shall perform an initial inspection
of the air emission control equipment on or before the
date that the tank becomes subject to this Section.
Thereafter, the owner or operator shall perform the
inspections at least once every year except for the special
conditions provided for in subsection (l) of this Section.
248
D)
In the event that a defect is detected, the owner or
operator shall repair the defect in accordance with the
requirements of subsection (k) of this Section.
E)
The owner or operator shall maintain a record of the
inspection in accordance with the requirements specified
in Section 724.989(b).
h)
The owner or operator that controls air pollutant emissions by using a
pressure tank must meet the following requirements:
1)
The tank must be designed not to vent to the atmosphere as a
result of compression of the vapor headspace in the tank during
filling of the tank to its design capacity.
2)
All tank openings must be equipped with closure devices
designed to operate with no detectable organic emissions as
determined using the procedure specified in Section 724.983(d).
3)
Whenever a hazardous waste is in the tank, the tank must be
operated as a closed system that does not vent to the atmosphere
except in the event that a safety device, as defined in 35 Ill.
Adm. Code 725.981, is required to open to avoid an unsafe
condition.
i)
The owner or operator that controls air pollutant emissions by using an
enclosure vented through a closed-vent system to an enclosed combustion
control device must meet the requirements specified in subsections (i)(1)
through (i)(4) of this Section.
1)
The tank must be located inside an enclosure. The enclosure
must be designed and operated in accordance with the criteria for
a permanent total enclosure, as specified in “Procedure T--
Criteria for and Verification of a Permanent or Temporary Total
Enclosure” under 40 CFR 52.741, appendix B, incorporated by
reference in 35 Ill. Adm. Code 720.111. The enclosure may have
permanent or temporary openings to allow worker access;
passage of material into or out of the enclosure by conveyor,
vehicles, or other mechanical means; entry of permanent
mechanical or electrical equipment; or direct airflow into the
enclosure. The owner or operator shall perform the verification
procedure for the enclosure, as specified in Section 5.0 to
“Procedure T--Criteria for and Verification of a Permanent or
Temporary Total Enclosure”, initially when the enclosure is first
installed and, thereafter, annually.
249
2)
The enclosure must be vented through a closed-vent system to an
enclosed combustion control device that is designed and operated
in accordance with the standards for either a vapor incinerator,
boiler, or process heater specified in Section 724.987.
3)
Safety devices, as defined in 35 Ill. Adm. Code 725.981, may be
installed and operated as necessary on any enclosure, closed-vent
system, or control device used to comply with the requirements
of subsections (i)(1) and (i)(2) of this Section.
4)
The owner or operator shall inspect and monitor the closed-vent
system and control device as specified in Section 724.987.
j)
The owner or operator shall transfer hazardous waste to a tank subject to
this Section in accordance with the following requirements:
1)
Transfer of hazardous waste, except as provided in subsection
(j)(2) of this Section, to the tank from another tank subject to this
Section or from a surface impoundment subject to Section
724.985 must be conducted using continuous hard-piping or
another closed system that does not allow exposure of the
hazardous waste to the atmosphere. For the purpose of
complying with this provision, an individual drain system is
considered to be a closed system when it meets the requirements
of 40 CFR 63, subpart RR, “National Emission Standards for
Individual Drain Systems”, incorporated by reference in 35 Ill.
Adm. Code 720.111.
2)
The requirements of subsection (j)(1) of this Section do not apply
when transferring a hazardous waste to the tank under any of the
following conditions:
A)
The hazardous waste meets the average VO concentration
conditions specified in Section 724.982(c)(1) at the point
of waste origination.
B)
The hazardous waste has been treated by an organic
destruction or removal process to meet the requirements in
Section 724.982(c)(2).
k)
The owner or operator shall repair each defect detected during an
inspection performed in accordance with the requirements of subsection
(c)(4), (e)(3), (f)(3), or (g)(3) of this Section, as follows:
250
1)
The owner or operator shall make first efforts at repair of the
defect no later than five calendar days after detection, and repair
must be completed as soon as possible but no later than 45
calendar days after detection except as provided in subsection
(k)(2) of this Section.
2)
Repair of a defect may be delayed beyond 45 calendar days if the
owner or operator determines that repair of the defect requires
emptying or temporary removal from service of the tank and no
alternative tank capacity is available at the site to accept the
hazardous waste normally managed in the tank. In this case, the
owner or operator shall repair the defect the next time the process
or unit that is generating the hazardous waste managed in the tank
stops operation. Repair of the defect must be completed before
the process or unit resumes operation.
l)
Following the initial inspection and monitoring of the cover, as required
by the applicable provisions of this Subpart, subsequent inspection and
monitoring may be performed at intervals longer than one year under the
following special conditions:
1)
In the case when inspecting or monitoring the cover would
expose a worker to dangerous, hazardous, or other unsafe
conditions, then the owner or operator may designate a cover as
an “unsafe to inspect and monitor cover” and comply with all of
the following requirements:
A)
Prepare a written explanation for the cover stating the
reasons why the cover is unsafe to visually inspect or to
monitor, if required.
B)
Develop and implement a written plan and schedule to
inspect and monitor the cover, using the procedures
specified in the applicable Section of this Subpart, as
frequently as practicable during those times when a
worker can safely access the cover.
2)
In the case when a tank is buried partially or entirely
underground, an owner or operator is required to inspect and
monitor, as required by the applicable provisions of this Section,
only those portions of the tank cover and those connections to the
tank (e.g., fill ports, access hatches, gauge wells, etc.) that are
located on or above the ground surface.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
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Section 724.985
Standards: Surface Impoundments
a) This Section applies to owners and operators of surface impoundments
subject to this Subpart into which any hazardous waste is placed except
for the following surface impoundments:
1) A surface impoundment in which all hazardous waste entering the
surface impoundment meets the conditions specified in Section
724.982(c); or
2) A surface impoundment used for biological treatment of
hazardous waste in accordance with the requirements of Section
724.982(c)(2)(D).
b) The owner or operator shall place the hazardous waste into a surface
impoundment equipped with a cover (e.g., an air-supported structure or
a rigid cover) that is vented through a closed-vent system to a control
device meeting the requirements specified in subsection (d) below.
c) As an alternative to complying with subsection (b) above, an owner or
operator may place hazardous waste in a surface impoundment equipped
with a floating membrane cover meeting the requirements specified in
subsection (e) below when the hazardous waste is determined to meet all
of the following conditions:
1) The hazardous waste is not mixed, stirred, agitated, or circulated
within the surface impoundment by the owner or operator using a
process that results in splashing, frothing, or visible turbulent
flow on the waste surface during normal process operations;
2) The hazardous waste in the surface impoundment is not heated by
the owner or operator; and
3) The hazardous waste is not treated by the owner or operator using
a waste stabilization process or a process that produces an
exothermic reaction.
d) To comply with subsection (b)(1) above, the owner or operator shall
design, install, operate, and maintain a cover that vents the organic
vapors emitted from hazardous waste in the surface impoundment
through a closed-vent system connected to a control device.
1) The cover shall be designed and operated to meet the following
requirements:
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A) The cover and all cover openings (e.g., access hatches,
sampling ports, and gauge wells) shall be designed to
operate with no detectable organic emissions when all
cover openings are secured in a closed, sealed position;
B) Each cover opening shall be secured in the closed, sealed
position (e.g., covered by a gasketed lid or cap) at all
times that hazardous waste is in the surface impoundment,
except as provided for in subsection (g) below; and
C) The closed-vent system and control device shall be
designed and operated in accordance with Section
724.987.
e) To comply with subsection (c) above, the owner or operator shall
design, install, operate, and maintain a floating membrane cover that
meets all of the requirements specified in 35 Ill. Adm. Code
725.986(e)(1) through (e)(4).
f) The owner or operator shall install, operate, and maintain enclosed pipes
or other closed-systems to:
BOARD NOTE: U.S. EPA considers a drain system that meets the
requirements of 40 CFR 61.346(a)(1) or (b)(1) through (b)(3) to be a
“closed-system”. The Board intends that this meaning be included in the
use of that term for the purposes of this Subpart.
1) Transfer all hazardous waste to the surface impoundment from
another tank, surface impoundment, or container subject to this
Subpart except for those hazardous wastes that meet the
conditions specified in Section 724.982(c); and
2) Transfer all hazardous waste from the surface impoundment to
another tank, surface impoundment, or container subject to this
Subpart except for those hazardous wastes that meet the
conditions specified in Section 724.982(c).
g) Each cover opening shall be secured in the closed, sealed position (e.g.,
a cover by a gasketed lid or cap) at all times that hazardous waste is in
the surface impoundment except when it is necessary to use the cover
opening to:
1) Add, remove, inspect, or sample the material in the surface
impoundment;
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2) Inspect, maintain, repair, or replace equipment located
underneath the cover;
3) Remove treatment residues from the surface impoundment in
accordance with the requirements of 35 Ill. Adm. Code 728.4; or
4) Vent gases or vapors from the surface impoundment to a closed-
vent system connected to a control device that is designed and
operated in accordance with the requirements of Section 724.987.
h) One or more safety devices that vent directly to the atmosphere may be
installed on the cover, closed-vent system, or control device provided
each device meets all of the following conditions:
1) The safety device is not used for planned or routine venting of
organic vapors from the surface impoundment or the closed-vent
system connected to a control device; and
2) The safety device remains in a closed, sealed position at all
times, except when an unplanned event requires that the device
open for the purpose of preventing physical damage or permanent
deformation of the cover, closed-vent system, or control device
in accordance with good engineering and safety practices for
handling flammable, combustible, explosive, or other hazardous
materials. An example of an unplanned event is a sudden power
outage.
a)
The provisions of this Section apply to the control of air pollutant
emissions from surface impoundments for which Section 724.982(b)
references the use of this Section for such air emission control.
b)
The owner or operator shall control air pollutant emissions from the
surface impoundment by installing and operating either of the following:
1)
A floating membrane cover in accordance with the provisions
specified in subsection (c) of this Section; or
2)
A cover that is vented through a closed-vent system to a control
device in accordance with the provisions specified in subsection
(d) of this Section.
c)
The owner or operator that controls air pollutant emissions from a
surface impoundment using a floating membrane cover must meet the
254
requirements specified in subsections (c)(1) through (c)(3) of this
Section.
1)
The surface impoundment must be equipped with a floating
membrane cover designed to meet the following specifications:
A)
The floating membrane cover must be designed to float on
the liquid surface during normal operations and form a
continuous barrier over the entire surface area of the
liquid.
B)
The cover must be fabricated from a synthetic membrane
material that is either:
i)
High density polyethylene (HDPE) with a
thickness no less than 2.5 millimeters (mm) (0.098
in); or
ii)
A material or a composite of different materials
determined to have both organic permeability
properties that are equivalent to those of the
material listed in subsection (c)(1)(B)(i) of this
Section and chemical and physical properties that
maintain the material integrity for the intended
service life of the material.
C)
The cover must be installed in such a manner that there
are no visible cracks, holes, gaps, or other open spaces
between cover section seams or between the interface of
the cover edge and its foundation mountings.
D)
Except as provided for in subsection (c)(1)(E) of this
Section, each opening in the floating membrane cover
must be equipped with a closure device so designed as to
operate that when the closure device is secured in the
closed position there are no visible cracks, holes, gaps, or
other open spaces in the closure device or between the
perimeter of the cover opening and the closure device.
E)
The floating membrane cover may be equipped with one
or more emergency cover drains for removal of
stormwater. Each emergency cover drain must be
equipped with a slotted membrane fabric cover that covers
at least 90% of the area of the opening or a flexible fabric
sleeve seal.
255
F)
The closure devices must be made of suitable materials
that will minimize exposure of the hazardous waste to the
atmosphere, to the extent practical, and will maintain the
integrity of the closure devices throughout their intended
service life. Factors to be considered when selecting the
materials of construction and designing the cover and
closure devices must include the following: the organic
vapor permeability; the effects of any contact with the
liquid and its vapor managed in the surface impoundment;
the effects of outdoor exposure to wind, moisture, and
sunlight; and the operating practices used for the surface
impoundment on which the floating membrane cover is
installed.
2)
Whenever a hazardous waste is in the surface impoundment, the
floating membrane cover must float on the liquid and each
closure device must be secured in the closed position, except as
follows:
A)
Opening of closure devices or removal of the cover is
allowed at the following times:
i)
To provide access to the surface impoundment for
performing routine inspection, maintenance, or
other activities needed for normal operations.
Examples of such activities include those times
when a worker needs to open a port to sample the
liquid in the surface impoundment, or when a
worker needs to open a hatch to maintain or repair
equipment. Following completion of the activity,
the owner or operator shall promptly replace the
cover and secure the closure device in the closed
position, as applicable.
ii)
To remove accumulated sludge or other residues
from the bottom of surface impoundment.
B)
Opening of a safety device, as defined in 35 Ill. Adm.
Code 725.981, is allowed at any time conditions require
doing so to avoid an unsafe condition.
3)
The owner or operator shall inspect the floating membrane cover
in accordance with the following procedures:
256
A)
The floating membrane cover and its closure devices must
be visually inspected by the owner or operator to check
for defects that could result in air pollutant emissions.
Defects include, but are not limited to, visible cracks,
holes, or gaps in the cover section seams or between the
interface of the cover edge and its foundation mountings;
broken, cracked, or otherwise damaged seals or gaskets
on closure devices; and broken or missing hatches, access
covers, caps, or other closure devices.
B)
The owner or operator shall perform an initial inspection
of the floating membrane cover and its closure devices on
or before the date that the surface impoundment becomes
subject to this Section. Thereafter, the owner or operator
shall perform the inspections at least once every year
except for the special conditions provided for in
subsection (g) of this Section.
C)
In the event that a defect is detected, the owner or
operator shall repair the defect in accordance with the
requirements of subsection (f) of this Section.
D)
The owner or operator shall maintain a record of the
inspection in accordance with the requirements specified
in Section 724.989(c).
d)
The owner or operator that controls air pollutant emissions from a
surface impoundment using a cover vented to a control device shall meet
the requirements specified in subsections (d)(1) through (d)(3) of this
Section.
1)
The surface impoundment must be covered by a cover and vented
directly through a closed-vent system to a control device in
accordance with the following requirements:
A)
The cover and its closure devices must be designed to
form a continuous barrier over the entire surface area of
the liquid in the surface impoundment.
B)
Each opening in the cover not vented to the control device
must be equipped with a closure device. If the pressure in
the vapor headspace underneath the cover is less than
atmospheric pressure when the control device is operating,
the closure devices must be designed to operate such that
when the closure device is secured in the closed position
257
there are no visible cracks, holes, gaps, or other open
spaces in the closure device or between the perimeter of
the cover opening and the closure device. If the pressure
in the vapor headspace underneath the cover is equal to or
greater than atmospheric pressure when the control device
is operating, the closure device must be designed to
operate with no detectable organic emissions using the
procedure specified in Section 724.983(d).
C)
The cover and its closure devices must be made of
suitable materials that will minimize exposure of the
hazardous waste to the atmosphere, to the extent practical,
and will maintain the integrity of the cover and closure
devices throughout their intended service life. Factors to
be considered when selecting the materials for and
designing the cover and closure devices must include the
following: the organic vapor permeability; the effects of
any contact with the liquid or its vapors managed in the
surface impoundment; the effects of outdoor exposure to
wind, moisture, and sunlight; and the operating practices
used for the surface impoundment on which the cover is
installed.
D)
The closed-vent system and control device must be
designed and operated in accordance with the
requirements of Section 724.987.
2)
Whenever a hazardous waste is in the surface impoundment, the
cover must be installed with each closure device secured in the
closed position and the vapor headspace underneath the cover
vented to the control device except as follows:
A)
Venting to the control device is not required, and opening
of closure devices or removal of the cover is allowed at
the following times:
i)
To provide access to the surface impoundment for
performing routine inspection, maintenance, or
other activities needed for normal operations.
Examples of such activities include those times
when a worker needs to open a port to sample
liquid in the surface impoundment, or when a
worker needs to open a hatch to maintain or repair
equipment. Following completion of the activity,
the owner or operator shall promptly secure the
258
closure device in the closed position or reinstall the
cover, as applicable, to the surface impoundment.
ii)
To remove accumulated sludge or other residues
from the bottom of surface impoundment.
B)
Opening of a safety device, as defined in 35 Ill. Adm.
Code 725.981, is allowed at any time conditions require
doing so to avoid an unsafe condition.
3)
The owner or operator shall inspect and monitor the air emission
control equipment in accordance with the following procedures:
A)
The surface impoundment cover and its closure devices
shall be visually inspected by the owner or operator to
check for defects that could result in air pollutant
emissions. Defects include, but are not limited to, visible
cracks, holes, or gaps in the cover section seams or
between the interface of the cover edge and its foundation
mountings; broken, cracked, or otherwise damaged seals
or gaskets on closure devices; and broken or missing
hatches, access covers, caps, or other closure devices.
B)
The closed-vent system and control device must be
inspected and monitored by the owner or operator in
accordance with the procedures specified in Section
724.987.
C)
The owner or operator shall perform an initial inspection
of the air emission control equipment on or before the
date that the surface impoundment becomes subject to this
Section. Thereafter, the owner or operator shall perform
the inspections at least once every year except for the
special conditions provided for in subsection (g) of this
Section.
D)
In the event that a defect is detected, the owner or
operator shall repair the defect in accordance with the
requirements of subsection (f) of this Section.
E)
The owner or operator shall maintain a record of the
inspection in accordance with the requirements specified
in Section 724.989(c).
259
e)
The owner or operator shall transfer hazardous waste to a surface
impoundment subject to this Section in accordance with the following
requirements:
1)
Transfer of hazardous waste, except as provided in subsection
(e)(2) of this Section, to the surface impoundment from another
surface impoundment subject to this Section or from a tank
subject to Section 724.984 must be conducted using continuous
hard-piping or another closed system that does not allow
exposure of the waste to the atmosphere. For the purpose of
complying with this provision, an individual drain system is
considered to be a closed system when it meets the requirements
of 40 CFR 63, Subpart RR, “National Emission Standards for
Individual Drain Systems”, incorporated by reference in 35 Ill.
Adm. Code 720.111.
2)
The requirements of subsection (e)(1) of this Section do not apply
when transferring a hazardous waste to the surface impoundment
under either of the following conditions:
A)
The hazardous waste meets the average VO concentration
conditions specified in Section 724.982(c)(1) at the point
of waste origination.
B)
The hazardous waste has been treated by an organic
destruction or removal process to meet the requirements in
Section 724.982(c)(2).
f)
The owner or operator shall repair each defect detected during an
inspection performed in accordance with the requirements of subsection
(c)(3) or (d)(3) of this Section as follows:
1)
The owner or operator shall make first efforts at repair of the
defect no later than five calendar days after detection and repair
must be completed as soon as possible but no later than 45
calendar days after detection except as provided in subsection
(f)(2) of this Section.
2)
Repair of a defect may be delayed beyond 45 calendar days if the
owner or operator determines that repair of the defect requires
emptying or temporary removal from service of the surface
impoundment and no alternative capacity is available at the site to
accept the hazardous waste normally managed in the surface
impoundment. In this case, the owner or operator shall repair the
defect the next time the process or unit that is generating the
260
hazardous waste managed in the surface impoundment stops
operation. Repair of the defect must be completed before the
process or unit resumes operation.
g)
Following the initial inspection and monitoring of the cover as required
by the applicable provisions of this Subpart, subsequent inspection and
monitoring may be performed at intervals longer than one year in the
case when inspecting or monitoring the cover would expose a worker to
dangerous, hazardous, or other unsafe conditions. In this case, the
owner or operator may designate the cover as an “unsafe to inspect and
monitor cover” and comply with all of the following requirements:
1)
Prepare a written explanation for the cover stating the reasons
why the cover is unsafe to visually inspect or to monitor, if
required.
2)
Develop and implement a written plan and schedule to inspect
and monitor the cover using the procedures specified in the
applicable Section of this Subpart as frequently as practicable
during those times when a worker can safely access the cover.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 724.986
Standards: Containers
a) This Section applies to the owners and operators of containers having
design capacities greater than 0.1 m
3
(3.5 ft
3
or 26.4 gal) subject to this
Subpart into which any hazardous waste is placed except for a container
in which all hazardous waste entering the container meets the conditions
specified in Section 724.982(c).
b) An owner or operator shall manage hazardous waste in containers using
the following procedures:
1) The owner or operator shall place the hazardous waste into one of
the following containers, except when a container is used for
hazardous waste treatment as required by subsection (b)(2)
below:
A) A container that is equipped with a cover which operates
with no detectable organic emissions when all container
openings (e.g., lids, bungs, hatches, and sampling ports)
are secured in a closed, sealed position. The owner or
operator shall determine that a container operates with no
detectable emissions by testing each opening on the
261
container for leaks in accordance with Method 21 in 40
CFR 60, Appendix A, incorporated by reference in 35 Ill.
Adm. Code 720.111, the first time any portion of the
hazardous waste is placed into the container. If a leak is
detected and cannot be repaired immediately, the
hazardous waste shall be removed from the container and
the container not used to meet the requirements of this
subsection until the leak is repaired and the container is
retested.
B) A container having a design capacity less than or equal to
0.46 m
3
(16.2 ft
3
or 122 gal) that is equipped with a cover
and complies with all applicable Department of
Transportation regulations on packaging hazardous waste
for transport under 49 CFR 178, incorporated by
reference at 35 Ill. Adm. Code 720.111.
i) A container that is managed in accordance with the
requirements of 49 CFR 178, incorporated by
reference at 35 Ill. Adm. Code 720.111, for the
purpose of complying with this Subpart, is not
subject to any exceptions to the 49 CFR 178
regulations, except as noted in subsection
(b)(1)(B)(ii) below.
ii) A lab pack that is managed in accordance with the
requirements of 49 CFR 178, incorporated by
reference at 35 Ill. Adm. Code 720.111, for the
purpose of complying with this Subpart, may
comply with the exceptions for combination
packagings specified in 49 CFR 173.12(b),
incorporated by reference at 35 Ill. Adm. Code
720.111.
C) A container that is attached to or forms a part of any
truck, trailer, or railcar and that has been demonstrated
within the preceding 12 months to be organic vapor tight
when all container openings are in a closed, sealed
position (e.g., the container hatches or lids are gasketed
and latched). For the purpose of meeting the
requirements of this subsection, a container is organic
vapor tight if the container sustains a pressure change of
not more than 0.75 kPa (0.11 psig or 5.6 mm Hg) within
5 minutes after it is pressurized to a minimum of 4.50 kPa
(0.65 psig or 33.7 mm Hg). This condition is to be
262
demonstrated using the pressure test specified in Method
27 of 40 CFR 60, Appendix A, and a pressure
measurement device which has a precision of ±2.5 mm
water and which is capable of measuring above the
pressure at which the container is to be tested for vapor
tightness.
2) An owner or operator treating hazardous waste in a container by
either a waste stabilization process, any process that requires the
addition of heat to the waste, or any process that produces an
exothermic reaction shall meet the following requirements:
A) Whenever it is necessary for the container to be open
during the treatment process, the container shall be
located inside an enclosure that is vented through a
closed-vent system to a control device.
B) The enclosure shall be a structure that is designed and
operated in accordance with the following requirements:
i) The enclosure shall be a structure that is designed
and operated with sufficient airflow into the
structure to capture the organic vapors emitted
from the hazardous waste in the container and vent
the vapors through the closed-vent system to the
control device.
ii) The enclosure may have permanent or temporary
openings to allow worker access, passage of
containers through the enclosure by conveyor or
other mechanical means, entry of permanent
mechanical or electrical equipment, or to direct
airflow into the enclosure. The pressure drop
across each opening in the enclosure shall be
maintained at a pressure below atmospheric
pressure so that whenever an open container is
placed inside the enclosure no organic vapors
released from the container exit the enclosure
through the opening. The owner or operator shall
determine that an enclosure achieves this condition
by measuring the pressure drop across each
opening in the enclosure. If the pressure within
the enclosure is equal to or greater than
atmospheric pressure then the enclosure does not
meet the requirements of this Section.
263
C) The closed-vent system and control device shall be
designed and operated in accordance with the
requirements of Section 724.987.
3) An owner or operator transferring hazardous waste into a
container having a design capacity greater than 0.46 m
3
(16.2 ft
3
or 122 gal) shall meet the following requirements:
A) Hazardous waste transfer by pumping shall be performed
using a conveyance system that uses a tube (e.g., pipe,
hose) to add the waste into the container. During transfer
of the waste into the container, the cover shall remain in
place and all container openings shall be maintained in a
closed, sealed position except for those openings through
which the tube enters the container and as provided for in
subsection (c) below. The tube shall be positioned in a
manner so that:
i) The tube outlet continuously remains submerged
below the waste surface at all times waste is
flowing through the tube;
ii) The lower bottom edge of the tube outlet is located
at a distance no greater than two inside diameters
of the tube or 15.25 cm (6.0 in), whichever
distance is greater, from the bottom of the
container at all times waste is flowing through the
tube; or
iii) The tube is connected to a permanent port mounted
on the bottom of the container so that the lower
edge of the port opening inside the container is
located at a distance equal to or less than 15.25 cm
(6.0 in) from the container bottom.
B) Hazardous waste transferred by a means other than
pumping shall be performed such that during transfer of
the waste into the container, the cover remains in place
and all container openings are maintained in a closed,
sealed position except for those openings through which
the hazardous waste is added and as provided for in
subsection (d) below.
264
c) Each container opening shall be maintained in a closed, sealed position
(e.g., covered by a gasketed lid) at all times that hazardous waste is in
the container except when it is necessary to use the opening to:
1) Add, remove, inspect, or sample the material in the container;
2) Inspect, maintain, repair, or replace equipment located inside the
container; or
3) Vent gases or vapors from a cover located over or enclosing an
open container to a closed-vent system connected to a control
device that is designed and operated in accordance with the
requirements of Section 724.987.
d) One or more safety devices that vent directly to the atmosphere may be
used on the container, cover, enclosure, closed-vent system, or control
device provided each device meets all of the following conditions:
1) The safety device is not used for planned or routine venting of
organic vapors from the container, cover, enclosure, or closed-
vent system connected to a control device; and
2) The safety device remains in a closed, sealed position at all times
except when an unplanned event requires that the device open for
the purpose of preventing physical damage or permanent
deformation of the container, cover, enclosure, closed-vent
system, or control device in accordance with good engineering
and safety practices for handling flammable, combustible,
explosive, or other hazardous materials. An example of an
unplanned event is a sudden power outage.
a)
The provisions of this Section apply to the control of air pollutant
emissions from containers for which Section 724.982(b) references the
use of this Section for such air emission control.
b)
General requirements.
1)
The owner or operator shall control air pollutant emissions from
each container subject to this Section in accordance with the
following requirements, as applicable to the container, except
when the special provisions for waste stabilization processes
specified in subsection (b)(2) of this Section apply to the
container.
265
A)
For a container having a design capacity greater than 0.1
m
3
(26 gal) and less than or equal to 0.46 m
3
(120 gal),
the owner or operator shall control air pollutant emissions
from the container in accordance with the Container Level
1 standards specified in subsection (c) of this Section.
B)
For a container having a design capacity greater than 0.46
m
3
(120 gal) that is not in light material service, the
owner or operator shall control air pollutant emissions
from the container in accordance with the Container Level
1 standards specified in subsection (c) of this Section.
C)
For a container having a design capacity greater than 0.46
m
3
(120 gal) that is in light material service, the owner or
operator shall control air pollutant emissions from the
container in accordance with the Container Level 2
standards specified in subsection (d) of this Section.
2)
When a container having a design capacity greater than 0.1 m
3
(26 gal) is used for treatment of a hazardous waste by a waste
stabilization process, the owner or operator shall control air
pollutant emissions from the container in accordance with the
Container Level 3 standards specified in subsection (e) of this
Section at those times during the waste stabilization process when
the hazardous waste in the container is exposed to the
atmosphere.
c)
Container Level 1 standards.
1)
A container using Container Level 1 controls is one of the
following:
A)
A container that meets the applicable U.S. Department of
Transportation (USDOT) regulations on packaging
hazardous materials for transportation, as specified in
subsection (f) of this Section.
B)
A container equipped with a cover and closure devices
that form a continuous barrier over the container openings
so that when the cover and closure devices are secured in
the closed position there are no visible holes, gaps, or
other open spaces into the interior of the container. The
cover may be a separate cover installed on the container
(e.g., a lid on a drum or a suitably secured tarp on a roll-
off box) or may be an integral part of the container
266
structural design (e.g., a “portable tank” or bulk cargo
container equipped with a screw-type cap).
C)
An open-top container in which an organic-vapor
suppressing barrier is placed on or over the hazardous
waste in the container such that no hazardous waste is
exposed to the atmosphere. One example of such a
barrier is application of a suitable organic-vapor
suppressing foam.
2)
A container used to meet the requirements of subsection (c)(1)(B)
or (c)(1)(C) of this Section must be equipped with covers and
closure devices, as applicable to the container, that are composed
of suitable materials to minimize exposure of the hazardous waste
to the atmosphere and to maintain the equipment integrity for as
long as it is in service. Factors to be considered in selecting the
materials of construction and designing the cover and closure
devices must include the following: the organic vapor
permeability; the effects of contact with the hazardous waste or
its vapor managed in the container; the effects of outdoor
exposure of the closure device or cover material to wind,
moisture, and sunlight; and the operating practices for which the
container is intended to be used.
3)
Whenever a hazardous waste is in a container using Container
Level 1 controls, the owner or operator shall install all covers
and closure devices for the container, as applicable to the
container, and secure and maintain each closure device in the
closed position except as follows:
A)
Opening of a closure device or cover is allowed for the
purpose of adding hazardous waste or other material to the
container as follows:
i)
In the case when the container is filled to the
intended final level in one continuous operation,
the owner or operator shall promptly secure the
closure devices in the closed position and install
the covers, as applicable to the container, upon
conclusion of the filling operation.
ii)
In the case when discrete quantities or batches of
material intermittently are added to the container
over a period of time, the owner or operator shall
promptly secure the closure devices in the closed
267
position and install covers, as applicable to the
container, upon either the container being filled to
the intended final level; the completion of a batch
loading after which no additional material will be
added to the container within 15 minutes; the
person performing the loading operation leaving
the immediate vicinity of the container; or the
shutdown of the process generating the material
being added to the container, whichever condition
occurs first.
B)
Opening of a closure device or cover is allowed for the
purpose of removing hazardous waste from the container
as follows:
i)
For the purpose of meeting the requirements of
this Section, an empty container, as defined in 35
Ill. Adm. Code 721.107(b), may be open to the
atmosphere at any time (i.e., covers and closure
devices are not required to be secured in the closed
position on an empty container).
ii)
In the case when discrete quantities or batches of
material are removed from the container but the
container does not meet the conditions to be an
empty container as defined in 35 Ill. Adm. Code
721.107(b), the owner or operator shall promptly
secure the closure devices in the closed position
and install covers, as applicable to the container,
upon the completion of a batch removal after
which no additional material will be removed from
the container within 15 minutes or the person
performing the unloading operation leaves the
immediate vicinity of the container, whichever
condition occurs first.
C)
Opening of a closure device or cover is allowed when
access inside the container is needed to perform routine
activities other than transfer of hazardous waste.
Examples of such activities include those times when a
worker needs to open a port to measure the depth of or
sample the material in the container, or when a worker
needs to open a manhole hatch to access equipment inside
the container. Following completion of the activity, the
owner or operator shall promptly secure the closure
268
device in the closed position or reinstall the cover, as
applicable to the container.
D)
Opening of a spring-loaded pressure-vacuum relief valve,
conservation vent, or similar type of pressure relief device
which vents to the atmosphere is allowed during normal
operations for the purpose of maintaining the internal
pressure of the container in accordance with the container
design specifications. The device must be designed to
operate with no detectable organic emissions when the
device is secured in the closed position. The settings at
which the device opens must be established such that the
device remains in the closed position whenever the
internal pressure of the container is within the internal
pressure operating range determined by the owner or
operator based on container manufacturer
recommendations, applicable regulations, fire protection
and prevention codes, standard engineering codes and
practices, or other requirements for the safe handling of
flammable, ignitable, explosive, reactive, or hazardous
materials. Examples of normal operating conditions that
may require these devices to open are during those times
when the internal pressure of the container exceeds the
internal pressure operating range for the container as a
result of loading operations or diurnal ambient
temperature fluctuations.
E)
Opening of a safety device, as defined in 35 Ill. Adm.
Code 725.981, is allowed at any time conditions require
doing so to avoid an unsafe condition.
4)
The owner or operator of containers using Container Level 1
controls shall inspect the containers and their covers and closure
devices as follows:
A)
In the case when a hazardous waste already is in the
container at the time the owner or operator first accepts
possession of the container at the facility and the container
is not emptied (i.e., does not meet the conditions for an
empty container as specified in 35 Ill. Adm. Code
721.107(b)) within 24 hours after the container is
accepted at the facility, the owner or operator shall
visually inspect the container and its cover and closure
devices to check for visible cracks, holes, gaps, or other
open spaces into the interior of the container when the
269
cover and closure devices are secured in the closed
position. If a defect is detected, the owner or operator
shall repair the defect in accordance with the requirements
of subsection (c)(4)(C) of this Section.
B)
In the case when a container used for managing hazardous
waste remains at the facility for a period of one year or
more, the owner or operator shall visually inspect the
container and its cover and closure devices initially and
thereafter, at least once every 12 months, to check for
visible cracks, holes, gaps, or other open spaces into the
interior of the container when the cover and closure
devices are secured in the closed position. If a defect is
detected, the owner or operator shall repair the defect in
accordance with the requirements of subsection (c)(4)(C)
of this Section.
C)
When a defect is detected for the container, cover, or
closure devices, the owner or operator shall make first
efforts at repair of the defect no later than 24 hours after
detection and repair must be completed as soon as possible
but no later than five calendar days after detection. If
repair of a defect cannot be completed within five
calendar days, then the hazardous waste must be removed
from the container and the container must not be used to
manage hazardous waste until the defect is repaired.
5)
The owner or operator shall maintain at the facility a copy of the
procedure used to determine that containers with capacity of 0.46
m
3
(120 gal) or greater, which do not meet applicable DOT
regulations, as specified in subsection (f) of this Section, are not
managing hazardous waste in light material service.
d)
Container Level 2 standards.
1)
A container using Container Level 2 controls is one of the
following:
A)
A container that meets the applicable U.S. Department of
Transportation (USDOT) regulations on packaging
hazardous materials for transportation as specified in
subsection (f) of this Section.
B)
A container that operates with no detectable organic
emissions, as defined in 35 Ill. Adm. Code 725.981, and
270
determined in accordance with the procedure specified in
subsection (g) of this Section.
C)
A container that has been demonstrated within the
preceding 12 months to be vapor-tight by using 40 CFR
60, appendix A, Method 27, incorporated by reference in
35 Ill. Adm. Code 720.111, in accordance with the
procedure specified in subsection (h) of this Section.
2)
Transfer of hazardous waste in or out of a container using
Container Level 2 controls must be conducted in such a manner
as to minimize exposure of the hazardous waste to the
atmosphere, to the extent practical, considering the physical
properties of the hazardous waste and good engineering and
safety practices for handling flammable, ignitable, explosive,
reactive, or other hazardous materials. Examples of container
loading procedures that the USEPA considers to meet the
requirements of this subsection (d)(2) include using any one of
the following: a submerged-fill pipe or other submerged-fill
method to load liquids into the container; a vapor-balancing
system or a vapor-recovery system to collect and control the
vapors displaced from the container during filling operations; or a
fitted opening in the top of a container through which the
hazardous waste is filled and subsequently purging the transfer
line before removing it from the container opening.
3)
Whenever a hazardous waste is in a container using Container
Level 2 controls, the owner or operator shall install all covers
and closure devices for the container, and secure and maintain
each closure device in the closed position, except as follows:
A)
Opening of a closure device or cover is allowed for the
purpose of adding hazardous waste or other material to the
container as follows:
i)
In the case when the container is filled to the
intended final level in one continuous operation,
the owner or operator shall promptly secure the
closure devices in the closed position and install
the covers, as applicable to the container, upon
conclusion of the filling operation.
ii)
In the case when discrete quantities or batches of
material intermittently are added to the container
over a period of time, the owner or operator shall
271
promptly secure the closure devices in the closed
position and install covers, as applicable to the
container, upon either the container being filled to
the intended final level; the completion of a batch
loading after which no additional material will be
added to the container within 15 minutes; the
person performing the loading operation leaving
the immediate vicinity of the container; or the
shutdown of the process generating the material
being added to the container, whichever condition
occurs first.
B)
Opening of a closure device or cover is allowed for the
purpose of removing hazardous waste from the container
as follows:
i)
For the purpose of meeting the requirements of
this Section, an empty container as defined in 35
Ill. Adm. Code 721.107(b) may be open to the
atmosphere at any time (i.e., covers and closure
devices are not required to be secured in the closed
position on an empty container).
ii)
In the case when discrete quantities or batches of
material are removed from the container but the
container does not meet the conditions to be an
empty container as defined in 35 Ill. Adm. Code
721.107(b), the owner or operator shall promptly
secure the closure devices in the closed position
and install covers, as applicable to the container,
upon the completion of a batch removal after
which no additional material will be removed from
the container within 15 minutes or the person
performing the unloading operation leaves the
immediate vicinity of the container, whichever
condition occurs first.
C)
Opening of a closure device or cover is allowed when
access inside the container is needed to perform routine
activities other than transfer of hazardous waste.
Examples of such activities include those times when a
worker needs to open a port to measure the depth of or
sample the material in the container, or when a worker
needs to open a manhole hatch to access equipment inside
the container. Following completion of the activity, the
272
owner or operator shall promptly secure the closure
device in the closed position or reinstall the cover, as
applicable to the container.
D)
Opening of a spring-loaded, pressure-vacuum relief valve,
conservation vent, or similar type of pressure relief device
which vents to the atmosphere is allowed during normal
operations for the purpose of maintaining the internal
pressure of the container in accordance with the container
design specifications. The device must be designed to
operate with no detectable organic emission when the
device is secured in the closed position. The settings at
which the device opens must be established such that the
device remains in the closed position whenever the
internal pressure of the container is within the internal
pressure operating range determined by the owner or
operator based on container manufacturer
recommendations, applicable regulations, fire protection
and prevention codes, standard engineering codes and
practices, or other requirements for the safe handling of
flammable, ignitable, explosive, reactive, or hazardous
materials. Examples of normal operating conditions that
may require these devices to open are during those times
when the internal pressure of the container exceeds the
internal pressure operating range for the container as a
result of loading operations or diurnal ambient
temperature fluctuations.
E)
Opening of a safety device, as defined in 35 Ill. Adm.
Code 725.981, is allowed at any time conditions require
doing so to avoid an unsafe condition.
4)
The owner or operator of containers using Container Level 2
controls shall inspect the containers and their covers and closure
devices as follows:
A)
In the case when a hazardous waste already is in the
container at the time the owner or operator first accepts
possession of the container at the facility and the container
is not emptied (i.e., does not meet the conditions for an
empty container as specified in 35 Ill. Adm. Code
721.107(b)) within 24 hours after the container arrives at
the facility, the owner or operator shall visually inspect
the container and its cover and closure devices to check
for visible cracks, holes, gaps, or other open spaces into
273
the interior of the container when the cover and closure
devices are secured in the closed position. If a defect is
detected, the owner or operator shall repair the defect in
accordance with the requirements of subsection (d)(4)(C)
of this Section.
B)
In the case when a container used for managing hazardous
waste remains at the facility for a period of one year or
more, the owner or operator shall visually inspect the
container and its cover and closure devices initially and
thereafter, at least once every 12 months, to check for
visible cracks, holes, gaps, or other open spaces into the
interior of the container when the cover and closure
devices are secured in the closed position. If a defect is
detected, the owner or operator shall repair the defect in
accordance with the requirements of subsection (d)(4)(C)
of this Section.
C)
When a defect is detected for the container, cover, or
closure devices, the owner or operator shall make first
efforts at repair of the defect no later than 24 hours after
detection, and repair must be completed as soon as
possible but no later than five calendar days after
detection. If repair of a defect cannot be completed
within five calendar days, then the hazardous waste must
be removed from the container and the container must not
be used to manage hazardous waste until the defect is
repaired.
e)
Container Level 3 standards.
1)
A container using Container Level 3 controls is one of the
following:
A)
A container that is vented directly through a closed-vent
system to a control device in accordance with the
requirements of subsection (e)(2)(B) of this Section.
B)
A container that is vented inside an enclosure which is
exhausted through a closed-vent system to a control device
in accordance with the requirements of subsections
(e)(2)(A) and (e)(2)(B) of this Section.
274
2)
The owner or operator shall meet the following requirements, as
applicable to the type of air emission control equipment selected
by the owner or operator:
A)
The container enclosure must be designed and operated in
accordance with the criteria for a permanent total
enclosure as specified in “Procedure T--Criteria for and
Verification of a Permanent or Temporary Total
Enclosure” under 40 CFR 52.741, appendix B,
incorporated by reference in 35 Ill. Adm. Code 720.111.
The enclosure may have permanent or temporary openings
to allow worker access; passage of containers through the
enclosure by conveyor or other mechanical means; entry
of permanent mechanical or electrical equipment; or direct
airflow into the enclosure. The owner or operator shall
perform the verification procedure for the enclosure as
specified in Section 5.0 to “Procedure T--Criteria for and
Verification of a Permanent or Temporary Total
Enclosure” initially when the enclosure is first installed
and, thereafter, annually.
B)
The closed-vent system and control device must be
designed and operated in accordance with the
requirements of Section 724.987.
3)
Safety devices, as defined in 35 Ill. Adm. Code 725.981, may be
installed and operated as necessary on any container, enclosure,
closed-vent system, or control device used to comply with the
requirements of subsection (e)(1) of this Section.
4)
Owners and operators using Container Level 3 controls in
accordance with the provisions of this Subpart shall inspect and
monitor the closed-vent systems and control devices as specified
in Section 724.987.
5)
Owners and operators that use Container Level 3 controls in
accordance with the provisions of this Subpart shall prepare and
maintain the records specified in Section 724.989(d).
f)
For the purpose of compliance with subsection (c)(1)(A) or (d)(1)(A) of
this Section, containers must be used that meet the applicable U.S.
Department of Transportation (USDOT) regulations on packaging
hazardous materials for transportation as follows:
275
1)
The container meets the applicable requirements specified in 49
CFR 178, “Specifications for Packaging”, or 49 CFR 179,
“Specifications for Tank Cars”, both incorporated by reference in
35 Ill. Adm. Code 720.111.
2)
Hazardous waste is managed in the container in accordance with
the applicable requirements specified in 49 CFR 107, Subpart B,
“Exemptions”; 49 CFR 172, “Hazardous Materials Table,
Special Provisions, Hazardous Materials Communications,
Emergency Response Information, and Training Requirements”;
49 CFR 173, “Shippers--General Requirements for Shipments
and Packages”; and 49 CFR 180, “Continuing Qualification and
Maintenance of Packagings”, each incorporated by reference in
35 Ill. Adm. Code 720.111.
3)
For the purpose of complying with this Subpart, no exceptions to
the 49 CFR 178 or 179 regulations are allowed, except as
provided for in subsection (f)(4) of this Section.
4)
For a lab pack that is managed in accordance with the
requirements of 49 CFR 178, incorporated by reference in 35 Ill.
Adm. Code 720.111, for the purpose of complying with this
Subpart, an owner or operator may comply with the exceptions
for combination packagings specified in 49 CFR 173.12(b).
g)
The owner or operator shall use the procedure specified in Section
724.983(d) for determining a container operates with no detectable
organic emissions for the purpose of complying with subsection (d)(1)(B)
of this Section.
1)
Each potential leak interface (i.e., a location where organic vapor
leakage could occur) on the container, its cover, and associated
closure devices, as applicable to the container, must be checked.
Potential leak interfaces that are associated with containers
include, but are not limited to, the following: the interface of the
cover rim and the container wall; the periphery of any opening
on the container or container cover and its associated closure
device; and the sealing seat interface on a spring-loaded pressure-
relief valve.
2)
The test must be performed when the container is filled with a
material having a volatile organic concentration representative of
the range of volatile organic concentrations for the hazardous
wastes expected to be managed in this type of container. During
276
the test, the container cover and closure devices must be secured
in the closed position.
h)
Procedure for determining a container to be vapor-tight using Method 27
of 40 CFR 60, appendix A for the purpose of complying with subsection
(d)(1)(C) of this Section.
1)
The test must be performed in accordance with Method 27 of 40
CFR 60, appendix A, incorporated by reference in 35 Ill. Adm.
Code 720.111.
2)
A pressure measurement device must be used that has a precision
of ± 2.5 mm (0.098 in) water and that is capable of measuring
above the pressure at which the container is to be tested for vapor
tightness.
3)
If the test results determined by Method 27 indicate that the
container sustains a pressure change less than or equal to 750
Pascals (0.11 psig) within five minutes after it is pressurized to a
minimum of 4,500 Pascals (0.65 psig), then the container is
determined to be vapor-tight.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 724.987
Standards: Closed-vent Systems and Control Devices
a)
This Section applies to each closed-vent system and control device
installed and operated by the owner or operator to control air emissions
in accordance with standards of this Subpart.
b)
The closed-vent system shall meet the following requirements:
1)
The closed-vent system shall route the gases, vapors, and fumes
emitted from the hazardous waste in the waste management unit
to a control device that meets the requirements specified in
subsection (c) belowof this Section.
2)
The closed-vent system shall be designed and operated in
accordance with the requirements specified in Section
724.933(k).
3) If the closed-vent system contains one or more bypass devices
that could be used to divert all or a portion of the gases, vapors,
or fumes from entering the control device, the owner or operator
shall meet the following requirements:
277
A) For each bypass device, except as provided for in
subsection (b)(3)(B) below, the owner or operator shall
either:
i) Install, calibrate, maintain, and operate a flow
indicator at the inlet to the bypass device that
indicates at least once every 15 minutes whether
gas, vapor, or fume flow is present in the bypass
device; or
ii) Secure a valve installed at the inlet to the bypass
device in the closed position using a car-seal or a
lock-and-key type configuration. The owner or
operator shall visually inspect the seal or closure
mechanism at least once every month to verify that
the valve is maintained in the closed position.
B) Low leg drains, high point bleeds, analyzer vents, open-
ended valves or lines, and safety devices are not subject to
the requirements of subsection (b)(3)(A) above.
3)
When the closed-vent system includes bypass devices that could
be used to divert the gas or vapor stream to the atmosphere
before entering the control device, each bypass device must be
equipped with either a flow indicator, as specified in subsection
(b)(3)(A) of this Section, or a seal or locking device, as specified
in subsection (b)(3)(B) of this Section. For the purpose of
complying with this subsection, low leg drains, high point bleeds,
analyzer vents, open-ended valves or lines, spring-loaded
pressure-relief valves, and other fittings used for safety purposes
are not considered to be bypass devices.
A)
If a flow indicator is used to comply with this subsection
(b)(3), the indicator must be installed at the inlet to the
bypass line used to divert gases and vapors from the
closed-vent system to the atmosphere at a point upstream
of the control device inlet. For the purposes of this
subsection, a flow indicator means a device that indicates
the presence of either gas or vapor flow in the bypass
line.
B)
If a seal or locking device is used to comply with
subsection (b)(3) of this Section, the device must be
placed on the mechanism by which the bypass device
278
position is controlled (e.g., valve handle or damper lever)
when the bypass device is in the closed position such that
the bypass device cannot be opened without breaking the
seal or removing the lock. Examples of such devices
include, but are not limited to, a car-seal or a lock-and-
key configuration valve. The owner or operator shall
visually inspect the seal or closure mechanism at least
once every month to verify that the bypass mechanism is
maintained in the closed position.
4)
The closed-vent system must be inspected and monitored by the
owner or operator in accordance with the procedure specified in
Section 724.933(l).
c)
The control device shall meet the following requirements:
1)
The control device shall be one of the following devices:
A)
A control device designed and operated to reduce the total
organic content of the inlet vapor stream vented to the
control device by at least 95 percent% by weight;
B)
An enclosed combustion device designed and operated in
accordance with the requirements of Section 724.933(c);
or
C)
A flare designed and operated in accordance with the
requirements of Section 724.933(d).
2) The control device shall be operating at all times when gases,
vapors, or fumes are vented from the waste management unit
through the closed-vent system to the control device.
2)
The owner or operator that elects to use a closed-vent system and
control device to comply with the requirements of this Section
shall comply with the requirements specified in subsections
(c)(2)(A) through (c)(2)(F) of this Section.
A)
Periods of planned routine maintenance of the control
device, during which the control device does not meet the
specifications of subsections (c)(1)(A), (c)(1)(B), or
(c)(1)(C) of this Section, as applicable, must not exceed
240 hours per year.
279
B)
The specifications and requirements in subsections
(c)(1)(A), (c)(1)(B), and (c)(1)(C) of this Section for
control devices do not apply during periods of planned
routine maintenance.
C)
The specifications and requirements in subsections
(c)(1)(A), (c)(1)(B), and (c)(1)(C) of this Section for
control devices do not apply during a control device
system malfunction.
D)
The owner or operator shall demonstrate compliance with
the requirements of subsection (c)(2)(A) of this Section
(i.e., planned routine maintenance of a control device,
during which the control device does not meet the
specifications of subsections (c)(1)(A), (c)(1)(B), or
(c)(1)(C) of this Section, as applicable, must not exceed
240 hours per year) by recording the information specified
in Section 724.989(e)(1)(E).
E)
The owner or operator shall correct control device system
malfunctions as soon as practicable after their occurrence
in order to minimize excess emissions of air pollutants.
F)
The owner or operator shall operate the closed-vent
system so that gases, vapors, or fumes are not actively
vented to the control device during periods of planned
maintenance or control device system malfunction (i.e.,
periods when the control device is not operating or not
operating normally), except in cases when it is necessary
to vent the gases, vapors, or fumes to avoid an unsafe
condition or to implement malfunction corrective actions
or planned maintenance actions.
3)
The owner or operator using a carbon adsorption system to
comply with subsection (c)(1) aboveof this Section shall operate
and maintain the control device in accordance with the following
requirements:
A)
Following the initial startup of the control device, all
activated carbon in the control device shall be replaced
with fresh carbon on a regular basis in accordance with
the requirements of Section 724.933(g) or Section
724.933(h).
280
B)
All carbon removed from the control device shall be
managed in accordance with the requirements of Section
724.933(mn).
4)
An owner or operator using a control device other than a thermal
vapor incinerator, flare, boiler, process heater, condenser, or
carbon adsorption system to comply with subsection (c)(1)
aboveof this Section shall operate and maintain the control device
in accordance with the requirements of Section 724.933(j).
5)
The owner or operator shall demonstrate that a control device
achieves the performance requirements of subsection (c)(1)
aboveof this Section, as follows:
A)
An owner or operator shall demonstrate using either a
performance test, as specified in subsection (c)(5)(C)
belowof this Section, or a design analysis, as specified in
subsection (c)(5)(D) belowof this Section, the
performance of each control device except for the
following:
i)
A flare;
ii)
A boiler or process heater with a design heat input
capacity of 44 megawatts or greater;
iii)
A boiler or process heater into which the vent
stream is introduced with the primary fuel;
iv)
A boiler or process heaterindustrial furnace
burning hazardous waste for which the owner or
operator has been issued a final permit under 35
Ill. Adm. Code 702, 703, and 705 and designshas
designed and operates the unit in accordance with
the interim status requirements of 35 Ill. Adm.
Code 726.Subpart H; or
v)
A boiler or process heaterindustrial furnace
burning hazardous waste for which that the owner
or operator has certified compliancedesigned and
operates in accordance with the interim status
requirements of 35 Ill. Adm. Code 726.Subpart H.
281
B)
An owner or operator shall demonstrate the performance
of each flare in accordance with the requirements
specified in Section 724.933(e).
C)
For a performance test conducted to meet the
requirements of subsection (c)(5)(A) aboveof this Section,
the owner or operator shall use the test methods and
procedures specified in Section 724.934(c)(1) through
(c)(4).
D)
For a design analysis conducted to meet the requirements
of subsection (c)(5)(A) aboveof this Section, the design
analysis shall meet the requirements specified in Section
724.935(b)(4)(C).
E)
The owner or operator shall demonstrate that a carbon
adsorption system achieves the performance requirements
of subsection (c)(1) aboveof this Section based on the total
quantity of organics vented to the atmosphere from all
carbon adsorption system equipment that is used for
organic adsorption, organic desorption or carbon
regeneration, organic recovery, and carbon disposal.
6)
If the owner or operator and the Agency do not agree on a
demonstration of control device performance using a design
analysis then the disagreement shall be resolved using the results
of a performance test performed by the owner or operator in
accordance with the requirements of subsection (c)(5)(C) aboveof
this Section. The Agency may choose to have an authorized
representative observe the performance test.
7)
The control device must be inspected and monitored by the owner
or operator in accordance with the procedures specified in Section
724.933(f)(2) and (l). The readings from each monitoring device
required by Section 724.933(f)(2) must be inspected at least once
each operating day to check control device operation. Any
necessary corrective measures must be immediately implemented
to ensure the control device is operated in compliance with the
requirements of this Section.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 724.988
Inspection and Monitoring Requirements
282
a) This Section applies to an owner or operator using air emission controls
in accordance with the requirements of Sections 724.984 through
724.987.
b) Each cover used in accordance with requirements of Section 724.984
through 724.986 shall be visually inspected and monitored for detectable
organic emissions by the owner or operator using the procedure specified
in 35 Ill. Adm. Code 725.989(f)(1) through (f)(7), except as follows:
1) An owner or operator is exempted from performing the cover
inspection and monitoring requirements specified in 35 Ill. Adm.
Code 725.989(f)(1) through (f)(7) for the following tank covers:
A) A tank internal floating roof that is inspected and
monitored in accordance with the requirements of Section
724.991; or
B) A tank external floating roof that is inspected and
monitored in accordance with the requirements of Section
724.991.
2) If a tank is buried partially or entirely underground, an owner or
operator is required to perform the cover inspection and
monitoring requirements specified in 35 Ill. Adm. Code
725.989(f)(1) through (f)(7) only for those portions of the tank
cover and those connections to the tank cover or tank body (e.g.,
fill ports, access hatches, gauge wells, etc.) that extend to or
above the ground surface and can be opened to the atmosphere.
3) An owner or operator is exempted from performing the cover
inspection and monitoring requirements specified in 35 Ill. Adm.
Code 725.989(f)(1) through (f)(7) for a container that meets all
requirements specified in either Section 724.986(b)(1)(B) or
(b)(1)(C).
4) An owner or operator is exempted from performing the cover
inspection and monitoring requirements specified in 35 Ill. Adm.
Code 725.989(f)(1) through (f)(7) for an enclosure used to
control air emissions from containers in accordance with the
requirements of Section 724.986(b)(2).
c) Each closed-vent system used in accordance with the requirements of
Section 724.987 shall be inspected and monitored by the owner or
operator in accordance with the procedure specified in Section
724.933(k).
283
d) Each control device used in accordance with the requirements of Section
724.987 shall be inspected and monitored by the owner or operator in
accordance with the procedures specified in Sections 724.933(f)(2) and
724.933(i). The readings from each monitoring device required by
Section 724.933(f)(2) shall be inspected at least once each operating day
to check control device operation. Any necessary corrective measures
should be immediately implemented to ensure the control device is
operated in compliance with the requirements of Section 264.987.
e) The owner or operator shall develop and implement a written plan and
schedule to perform all inspection and monitoring requirements of this
section. The owner or operator shall incorporate this plan and schedule
into the facility inspection plan required under Section 724.115.
a)
The owner or operator shall inspect and monitor air emission control
equipment used to comply with this Subpart in accordance with the
applicable requirements specified in Section 724.984 through Section
724.987.
b)
The owner or operator shall develop and implement a written plan and
schedule to perform the inspections and monitoring required by
subsection (a) of this Section. The owner or operator shall incorporate
this plan and schedule into the facility inspection plan required under 35
Ill. Adm. Code 724.115.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 724.989
Recordkeeping Requirements
a) Each owner or operator of a facility subject to requirements in this
Subpart shall record and maintain the following information as
applicable:
1) Documentation for each cover installed on a tank in accordance
with the requirements of Section 724.984(b)(2) or (b)(3) that
includes information prepared by the owner or operator or
provided by the cover manufacturer or vendor describing the
cover design, and certification by the owner or operator that the
cover meets the applicable design specifications as listed in 35 Ill.
Adm. Code 725.991(c).
2) Documentation for each floating membrane cover installed on a
surface impoundment in accordance with the requirements of
Section 724.985(c) that includes information prepared by the
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owner or operator or provided by the cover manufacturer or
vendor describing the cover design, and certification by the
owner or operator that the cover meets the specifications listed in
35 Ill. Adm. Code 725.986(e).
3) Documentation for each enclosure used to control air emissions
from containers in accordance with the requirements of Section
724.986(b)(2)(A) that includes information prepared by the
owner or operator or provided by the manufacturer or vendor
describing the enclosure design, and certification by the owner or
operator that the enclosure meets the specifications listed in
Section 724.986(b)(2)(B).
4) Documentation for each closed-vent system and control device
installed in accordance with the requirements of Section 724.987
that includes:
A) Certification that is signed and dated by the owner or
operator stating that the control device is designed to
operate at the performance level documented by a design
analysis as specified in subsection (a)(4)(B) below or by
performance tests as specified in subsection (a)(4)(C)
below when the tank, surface impoundment, or container
is or would be operating at capacity or the highest level
reasonably expected to occur.
B) If a design analysis is used, then design documentation as
specified in Section 724.935(b)(4). The documentation
shall include information prepared by the owner or
operator or provided by the control device manufacturer
or vendor that describes the control device design in
accordance with Section 724.935(b)(4)(C) and
certification by the owner or operator that the control
equipment meets the applicable specifications.
C) If performance tests are used, then a performance test plan
as specified in Section 724.935(b)(3) and all test results.
D) Information as required by Section 724.935(c)(1) and
(c)(2).
5) Records for all Method 27 tests performed by the owner or
operator for each container used to meet the requirements of
Section 724.986(b)(1)(C).
285
6) Records for all visual inspections conducted in accordance with
the requirements of Section 724.988.
7) Records for all monitoring for detectable organic emissions
conducted in accordance with the requirements of Section
724.988.
8) Records of the date of each attempt to repair a leak, repair
methods applied, and the date of successful repair.
9) Records for all continuous monitoring conducted in accordance
with the requirements of Section 724.988.
10) Records of the management of carbon removed from a carbon
adsorption system conducted in accordance with Section
724.987(c)(3)(B).
11) Records for all inspections of each cover installed on a tank in
accordance with the requirements of Section 724.984(b)(2) or
(b)(3) that includes information as listed in 35 Ill. Adm. Code
725.991(c).
b) An owner or operator electing to use air emission controls for a tank in
accordance with the conditions specified in Section 724.984(c) shall
record the following information:
1) Date and time each waste sample is collected for direct
measurement of maximum organic vapor pressure in accordance
with Section 724.983(c).
2) Results of each determination of the maximum organic vapor
pressure of the waste in a tank performed in accordance with
Section 724.983(c).
3) Records specifying the tank dimensions and design capacity.
c) An owner or operator electing to use air emission controls for a tank in
accordance with the requirements of Section 724.991 shall record the
information required by Section 724.991(c).
d) An owner or operator electing not to use air emission controls for a
particular tank, surface impoundment, or container subject to this
Subpart in accordance with the conditions specified in Section
724.982(c) shall record the information used by the owner or operator
for each waste determination (e.g., test results, measurements,
286
calculations, and other documentation) in the facility operating log. If
analysis results for waste samples are used for the waste determination,
then the owner or operator shall record the date, time, and location that
each waste sample is collected in accordance with applicable
requirements of Section 724.983.
e) An owner or operator electing to comply with requirements in
accordance with Section 724.982(c)(2)(E) or Section 724.982(c)(2)(F)
shall record the identification number for the incinerator, boiler, or
industrial furnace in which the hazardous waste is treated.
f) An owner or operator designating a cover as unsafe to inspect and
monitor pursuant to 35 Ill. Adm. Code 725.989(f)(5) or difficult to
inspect and monitor pursuant to 35 Ill. Adm. Code 725.989(f)(6) shall
record in a log that is kept in the facility operating record the following
information:
1) A list of identification numbers for tanks with covers that are
designated as unsafe to inspect and monitor in accordance with
the requirements of 35 Ill. Adm. Code 725.989(f)(5), an
explanation for each cover stating why the cover is unsafe to
inspect and monitor, and the plan and schedule for inspecting and
monitoring each cover.
2) A list of identification numbers for tanks with covers that are
designated as difficult to inspect and monitor in accordance with
the requirements of 35 Ill. Adm. Code 725.989(f)(6), an
explanation for each cover stating why the cover is difficult to
inspect and monitor, and the plan and schedule for inspecting and
monitoring each cover.
g) All records required by subsections (a) through (f) above, except as
required in subsections (a)(1) through (a)(4), shall be maintained in the
operating record for a minimum of 3 years. All records required by
subsections (a)(1) through (a)(4) above shall be maintained in the
operating record until the air emission control equipment is replaced or
otherwise no longer in service.
a)
Each owner or operator of a facility subject to requirements in this
Subpart shall record and maintain the information specified in
subsections (b) through (i) of this Section, as applicable to the facility.
Except for air emission control equipment design documentation and
information required by subsection (i) of this Section, records required
by this Section must be maintained in the operating record for a
minimum of three years. Air emission control equipment design
287
documentation must be maintained in the operating record until the air
emission control equipment is replaced or is otherwise no longer in
service. Information required by subsection (i) of this Section must be
maintained in the operating record for as long as the tank or container is
not using air emission controls specified in Sections 724.984 through
724.987, in accordance with the conditions specified in Section
724.984(d).
b)
The owner or operator of a tank using air emission controls in
accordance with the requirements of Section 724.984 shall prepare and
maintain records for the tank that include the following information:
1)
For each tank using air emission controls in accordance with the
requirements of Section 724.984, the owner or operator shall
record:
A)
A tank identification number (or other unique
identification description as selected by the owner or
operator).
B)
A record for each inspection required by Section 724.984
that includes the following information:
i)
Date inspection was conducted.
ii)
For each defect detected during the inspection, the
following information: the location of the defect,
a description of the defect, the date of detection,
and corrective action taken to repair the defect. In
the event that repair of the defect is delayed in
accordance with the provisions of Section 724.984,
the owner or operator shall also record the reason
for the delay and the date that completion of repair
of the defect is expected.
2)
In addition to the information required by subsection (b)(1) of
this Section, the owner or operator shall record the following
information, as applicable to the tank:
A)
The owner or operator using a fixed roof to comply with
the Tank Level 1 control requirements specified in Section
724.984(c) shall prepare and maintain records for each
determination for the maximum organic vapor pressure of
the hazardous waste in the tank performed in accordance
with the requirements of Section 724.984(c). The records
288
must include the date and time the samples were collected,
the analysis method used, and the analysis results.
B)
The owner or operator using an internal floating roof to
comply with the Tank Level 2 control requirements
specified in Section 724.984(e) shall prepare and maintain
documentation describing the floating roof design.
C)
Owners and operators using an external floating roof to
comply with the Tank Level 2 control requirements
specified in Section 724.984(f) shall prepare and maintain
the following records:
i)
Documentation describing the floating roof design
and the dimensions of the tank.
ii)
Records for each seal gap inspection required by
Section 724.984(f)(3) describing the results of the
seal gap measurements. The records must include
the date that the measurements were performed,
the raw data obtained for the measurements, and
the calculations of the total gap surface area. In
the event that the seal gap measurements do not
conform to the specifications in Section
724.984(f)(1), the records must include a
description of the repairs that were made, the date
the repairs were made, and the date the tank was
emptied, if necessary.
D)
Each owner or operator using an enclosure to comply with
the Tank Level 2 control requirements specified in Section
724.984(i) shall prepare and maintain the following
records:
i)
Records for the most recent set of calculations and
measurements performed by the owner or operator
to verify that the enclosure meets the criteria of a
permanent total enclosure as specified in
“Procedure T--Criteria for and Verification of a
Permanent or Temporary Total Enclosure” under
40 CFR 52.741, appendix B, incorporated by
reference in 35 Ill. Adm. Code 720.111.
289
ii)
Records required for the closed-vent system and
control device in accordance with the requirements
of subsection (e) of this Section.
c)
The owner or operator of a surface impoundment using air emission
controls in accordance with the requirements of Section 724.985 shall
prepare and maintain records for the surface impoundment that include
the following information:
1)
A surface impoundment identification number (or other unique
identification description as selected by the owner or operator).
2)
Documentation describing the floating membrane cover or cover
design, as applicable to the surface impoundment, that includes
information prepared by the owner or operator or provided by the
cover manufacturer or vendor describing the cover design, and
certification by the owner or operator that the cover meets the
specifications listed in Section 724.985(c).
3)
A record for each inspection required by Section 724.985 that
includes the following information:
A)
Date inspection was conducted.
B)
For each defect detected during the inspection the
following information: the location of the defect, a
description of the defect, the date of detection, and
corrective action taken to repair the defect. In the event
that repair of the defect is delayed in accordance with the
provisions of Section 724.985(f), the owner or operator
shall also record the reason for the delay and the date that
completion of repair of the defect is expected.
4)
For a surface impoundment equipped with a cover and vented
through a closed-vent system to a control device, the owner or
operator shall prepare and maintain the records specified in
subsection (e).
d)
The owner or operator of containers using Container Level 3 air
emission controls in accordance with the requirements of Section
724.986 shall prepare and maintain records that include the following
information:
1)
Records for the most recent set of calculations and measurements
performed by the owner or operator to verify that the enclosure
290
meets the criteria of a permanent total enclosure as specified in
“Procedure T--Criteria for and Verification of a Permanent or
Temporary Total Enclosure” under 40 CFR 52.741, appendix B,
incorporated by reference in 35 Ill. Adm. Code 720.111.
2)
Records required for the closed-vent system and control device in
accordance with the requirements of subsection (e) of this
Section.
e)
The owner or operator using a closed-vent system and control device in
accordance with the requirements of Section 724.987 shall prepare and
maintain records that include the following information:
1)
Documentation for the closed-vent system and control device that
includes:
A)
Certification that is signed and dated by the owner or
operator stating that the control device is designed to
operate at the performance level documented by a design
analysis as specified in subsection (e)(1)(B) of this Section
or by performance tests as specified in subsection
(e)(1)(C) of this Section when the tank, surface
impoundment, or container is or would be operating at
capacity or the highest level reasonably expected to occur.
B)
If a design analysis is used, then design documentation, as
specified in Section 724.935(b)(4). The documentation
must include information prepared by the owner or
operator or provided by the control device manufacturer
or vendor that describes the control device design in
accordance with Section 724.935(b)(4)(C) and
certification by the owner or operator that the control
equipment meets the applicable specifications.
C)
If performance tests are used, then a performance test plan
as specified in Section 724.935(b)(3) and all test results.
D)
Information as required by Section 724.935(c)(1) and
Section 724.935(c)(2), as applicable.
E)
An owner or operator shall record, on a semiannual basis,
the information specified in subsections (e)(1)(E)(i) and
(e)(1)(E)(ii) of this Section for those planned routine
maintenance operations that would require the control
device not to meet the requirements of Section
291
724.987(c)(1)(A), (c)(1)(B), or (c)(1)(C) of this Section,
as applicable.
i)
A description of the planned routine maintenance
that is anticipated to be performed for the control
device during the next six-month period. This
description must include the type of maintenance
necessary, planned frequency of maintenance, and
lengths of maintenance periods.
ii)
A description of the planned routine maintenance
that was performed for the control device during
the previous six-month period. This description
must include the type of maintenance performed
and the total number of hours during those six
months that the control device did not meet the
requirements of Section 724.987(c)(1)(A),
(c)(1)(B), or (c)(1)(C), as applicable, due to
planned routine maintenance.
F)
An owner or operator shall record the information
specified in subsections (e)(1)(F)(i) through (e)(1)(F)(iii)
of this Section for those unexpected control device system
malfunctions that would require the control device not to
meet the requirements of Section 724.987 (c)(1)(A),
(c)(1)(B), or (c)(1)(C) of this Section, as applicable.
i)
The occurrence and duration of each malfunction
of the control device system.
ii)
The duration of each period during a malfunction
when gases, vapors, or fumes are vented from the
waste management unit through the closed-vent
system to the control device while the control
device is not properly functioning.
iii)
Actions taken during periods of malfunction to
restore a malfunctioning control device to its
normal or usual manner of operation.
G)
Records of the management of carbon removed from a
carbon adsorption system conducted in accordance with
Section 724.987(c)(3)(B).
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f)
The owner or operator of a tank, surface impoundment, or container
exempted from standards in accordance with the provisions of Section
724.982(c) shall prepare and maintain the following records, as
applicable:
1)
For tanks, surface impoundments, or containers exempted under
the hazardous waste organic concentration conditions specified in
Section 724.982(c)(1) or (c)(2), the owner or operator shall
record the information used for each waste determination (e.g.,
test results, measurements, calculations, and other
documentation) in the facility operating log. If analysis results
for waste samples are used for the waste determination, then the
owner or operator shall record the date, time, and location that
each waste sample is collected in accordance with applicable
requirements of Section 724.983.
2)
For tanks, surface impoundments, or containers exempted under
the provisions of Section 724.982(c)(2)(G) or (c)(2)(H), the
owner or operator shall record the identification number for the
incinerator, boiler, or industrial furnace in which the hazardous
waste is treated.
g)
An owner or operator designating a cover as “unsafe to inspect and
monitor” pursuant to Section 724.984(l) or Section 724.985(g) shall
record in a log that is kept in the facility operating record the following
information: the identification numbers for waste management units
with covers that are designated as “unsafe to inspect and monitor”, the
explanation for each cover stating why the cover is unsafe to inspect and
monitor, and the plan and schedule for inspecting and monitoring each
cover.
h)
The owner or operator of a facility that is subject to this Subpart and to
the control device standards in 40 CFR 60, Subpart VV or 40 CFR 61,
Subpart V, incorporated by reference in 35 Ill. Adm. Code 720.111,
may elect to demonstrate compliance with the applicable Sections of this
Subpart by documentation either pursuant to this Subpart, or pursuant to
the provisions of 40 CFR 60, Subpart VV or 40 CFR 61, Subpart V, to
the extent that the documentation required by 40 CFR 60 or 61
duplicates the documentation required by this Section.
i)
For each tank or container not using air emission controls specified in
Sections 724.984 through 724.987 in accordance with the conditions
specified in Section 724.980(d), the owner or operator shall record and
maintain the following information:
293
1)
A list of the individual organic peroxide compounds
manufactured at the facility that meet the conditions specified in
Section 724.980(d)(1).
2)
A description of how the hazardous waste containing the organic
peroxide compounds identified pursuant to subsection (i)(1) of
this Section are managed at the facility in tanks and containers.
This description must include the following information:
A)
For the tanks used at the facility to manage this hazardous
waste, sufficient information must be provided to describe
the following for each tank: a facility identification
number for the tank, the purpose and placement of this
tank in the management train of this hazardous waste, and
the procedures used to ultimately dispose of the hazardous
waste managed in the tanks.
B)
For containers used at the facility to manage this
hazardous waste, sufficient information must be provided
to describe each tank: a facility identification number for
the container or group of containers, the purpose and
placement of this container or group of containers in the
management train of this hazardous waste, and the
procedures used to ultimately dispose of the hazardous
waste managed in the containers.
3)
An explanation of why managing the hazardous waste containing
the organic peroxide compounds identified pursuant to subsection
(i)(1) aboveof this Section in the tanks or containers identified
pursuant to subsection (i)(2) aboveof this Section would create an
undue safety hazard if the air emission controls specified in
Sections 724.984 through 724.987 were installed and operated on
these waste management units. This explanation must include the
following information:
A)
For tanks used at the facility to manage this hazardous
waste, sufficient information must be provided to explain
the following: how use of the required air emission
controls on the tanks would affect the tank design features
and facility operating procedures currently used to prevent
an undue safety hazard during management of this
hazardous waste in the tanks; and why installation of
safety devices on the required air emission controls, as
allowed under Section 724.984(g)this Subpart, would not
address those situations in which evacuation of tanks
294
equipped with these air emission controls is necessary and
consistent with good engineering and safety practices for
handling organic peroxides.
B)
For containers used at the facility to manage this
hazardous waste, sufficient information must be provided
to explain the following: how use of the required air
emission controls on the tanks would affect the container
design features and handling procedures currently used to
prevent an undue safety hazard during management of this
hazardous waste in the containers; and why installation of
safety devices on the required air emission controls, as
allowed under Section 724.986(d)this Subpart, would not
address those situations in which evacuation of containers
equipped with these air emission controls is necessary and
consistent with good engineering and safety practices for
handling organic peroxides.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 724.990
Reporting Requirements
a)
Each owner or operator managing hazardous waste in a tank, surface
impoundment, or container exempted from using air emission controls
under the provisions of Section 724.982(c) shall report to the Agency
each occurrence when hazardous waste is placed in the waste
management unit in noncompliance with the conditions specified in
Section 724.982(c)(1) or (c)(2), as applicable. Examples of such
occurrences include placing in the waste management unit a hazardous
waste having an average VO concentration equal to or greater than
100500 ppmw at the point of waste origination or placing in the waste
management unit a treated hazardous waste that fails to meet the
applicable conditions specified in Section 724.982(c)(2)(A) through
(c)(2)(EF). The owner or operator shall submit a written report within
15 calendar days of the time that the owner or operator becomes aware
of the occurrence. The written report shall contain the U.S. EPA
identification number, the facility name and address, a description of the
noncompliance event and the cause, the dates of the noncompliance, and
the actions taken to correct the noncompliance and prevent reoccurrence
of the noncompliance. The report shall be signed and dated by an
authorized representative of the owner or operator.
b)
Each owner or operator using air emission controls on a tank in
accordance with the requirements Section 724.984(c) shall report to the
Agency each occurrence when hazardous waste is managed in the tank in
295
noncompliance with the conditions specified in Section 724.984(c)(1)
through (c)(4)(b). The owner or operator shall submit a written report
within 15 calendar days of the time that the owner or operator becomes
aware of the occurrence. The written report shall contain the U.S. EPA
identification number, the facility name and address, a description of the
noncompliance event and the cause, the dates of the noncompliance, and
the actions taken to correct the noncompliance and prevent reoccurrence
of the noncompliance. The report shall be signed and dated by an
authorized representative of the owner or operator.
c)
Each owner or operator using a control device in accordance with the
requirements of Section 724.987 shall submit a semiannual written report
to the Agency excepted as provided for in subsection (d) belowof this
Section. The report shall describe each occurrence during the previous
6-month period when either of the two following events occurs: a
control device is operated continuously for 24 hours or longer in
noncompliance with the applicable operating values defined in Section
724.935(c)(4) or when a flare is operated with visible emissions for five
minutes or longer in a two-hour period, as defined in Section
724.933(d). The written report shall include the U. S. EPA
identification number, the facility name and address, and an explanation
why the control device could not be returned to compliance within 24
hours, and actions taken to correct the noncompliance. The report shall
be signed and dated by an authorized representative of the owner or
operator.
d)
A report to the Agency in accordance with the requirements of
subsection (c) aboveof this Section is not required for a 6-month period
during which all control devices subject to this Subpart are operated by
the owner or operator so that both of the following conditions result:
during no period of 24 hours or longer did a control device operate
continuously in noncompliance with the applicable operating values
defined in Section 724.935(c)(4) orand ano flare was operated with
visible emissions for five minutes or longer in a two-hour period, as
defined in Section 724.933(d).
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 724.991
Alternative Control Requirements for Tanks (Repealed)
a) This Section applies to owners and operators of tanks that elect to
comply with Section 724.984(b)(2) or Section 724.984(b)(3).
1) The owner or operator that elects to comply with Section
724.984(b)(2) shall design, install, operate, and maintain a fixed
296
roof and internal floating roof that meet the requirements
specified in 35 Ill. Adm. Code 725.991(a)(1)(A) through
(a)(1)(I).
2) The owner or operator that elects to comply with Section
724.984(b)(3) shall design, install, operate, and maintain an
external floating roof that meets the requirements specified in 35
Ill. Adm. Code 725.991(a)(2)(A) through (a)(2)(C).
3) The owner or operator may elect to comply with Section
264.984(b)(2) or (b)(3) using an alternative means of emission
limitation as specified in 35 Ill. Adm. Code 725.991(a)(3).
b) The owner or operator shall inspect and monitor the control equipment
in accordance with the following requirements:
1) For a tank equipped with a fixed roof and internal floating roof in
accordance with the requirements of subsection (a)(1) above, the
owner or operator shall perform the inspection and monitoring
requirements specified in 35 Ill. Adm. Code 725.991(b)(1).
2) For a tank equipped with an external floating roof in accordance
with the requirements of subsection (a)(2) above, the owner or
operator shall perform the inspection and monitoring
requirements specified in 35 Ill. Adm. Code 725.991(b)(2).
c) The owner or operator shall record the following information in the
operating record in accordance with the requirements of Section
724.989(a)(1) and (a)(11):
1) For a tank equipped with a fixed roof and internal floating roof in
accordance with the requirements of subsection (a)(1) above, the
owner or operator shall record the information listed in 35 Ill.
Adm. Code 725.991(c)(1).
2) For a tank equipped with an external floating roof in accordance
with the requirements of subsection (a)(1) above, the owner or
operator shall record the information listed in 35 Ill. Adm. Code
725.991(c)(2).
(Source: Repealed at 21 Ill. Reg. ________, effective ____________________)
TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE G: WASTE DISPOSAL
297
CHAPTER I: POLLUTION CONTROL BOARD
SUBCHAPTER c: HAZARDOUS WASTE OPERATING
REQUIREMENTS
PART 725
INTERIM STATUS STANDARDS FOR OWNERS AND
OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE,
AND DISPOSAL FACILITIES
SUBPART A: GENERAL PROVISIONS
Section
725.101
Purpose, Scope and Applicability
725.104
Imminent Hazard Action
SUBPART B: GENERAL FACILITY STANDARDS
Section
725.110
Applicability
725.111
USEPA Identification Number
725.112
Required Notices
725.113
General Waste Analysis
725.114
Security
725.115
General Inspection Requirements
725.116
Personnel Training
725.117
General Requirements for Ignitable, Reactive, or Incompatible Wastes
725.118
Location Standards
725.119
Construction Quality Assurance Program
SUBPART C: PREPAREDNESS AND PREVENTION
Section
725.130
Applicability
725.131
Maintenance and Operation of Facility
725.132
Required Equipment
725.133
Testing and Maintenance of Equipment
725.134
Access to Communications or Alarm System
725.135
Required Aisle Space
725.137
Arrangements with Local Authorities
SUBPART D: CONTINGENCY PLAN AND EMERGENCY
PROCEDURES
Section
725.150
Applicability
725.151
Purpose and Implementation of Contingency Plan
725.152
Content of Contingency Plan
725.153
Copies of Contingency Plan
725.154
Amendment of Contingency Plan
298
725.155
Emergency Coordinator
725.156
Emergency Procedures
SUBPART E: MANIFEST SYSTEM, RECORDKEEPING AND
REPORTING
Section
725.170
Applicability
725.171
Use of Manifest System
725.172
Manifest Discrepancies
725.173
Operating Record
725.174
Availability, Retention and Disposition of Records
725.175
Annual Report
725.176
Unmanifested Waste Report
725.177
Additional Reports
SUBPART F: GROUNDWATER MONITORING
Section
725.190
Applicability
725.191
Groundwater Monitoring System
725.192
Sampling and Analysis
725.193
Preparation, Evaluation and Response
725.194
Recordkeeping and Reporting
SUBPART G: CLOSURE AND POST-CLOSURE
Section
725.210
Applicability
725.211
Closure Performance Standard
725.212
Closure Plan; Amendment of Plan
725.213
Closure; Time Allowed for Closure
725.214
Disposal or Decontamination of Equipment, Structures and Soils
725.215
Certification of Closure
725.216
Survey Plat
725.217
Post-closure Care and Use of Property
725.218
Post-closure Plan; Amendment of Plan
725.219
Post-Closure Notices
725.220
Certification of Completion of Post-Closure Care
SUBPART H: FINANCIAL REQUIREMENTS
Section
725.240
Applicability
725.241
Definitions of Terms as Used in this Subpart
725.242
Cost Estimate for Closure
725.243
Financial Assurance for Closure
725.244
Cost Estimate for Post-closure Care
725.245
Financial Assurance for Post-closure Monitoring and Maintenance
299
725.246
Use of a Mechanism for Financial Assurance of Both Closure and Post-
closure Care
725.247
Liability Requirements
725.248
Incapacity of Owners or Operators, Guarantors or Financial Institutions
725.251
Promulgation of Forms (Repealed)
SUBPART I: USE AND MANAGEMENT OF CONTAINERS
Section
725.270
Applicability
725.271
Condition of Containers
725.272
Compatibility of Waste with Container
725.273
Management of Containers
725.274
Inspections
725.276
Special Requirements for Ignitable or Reactive Waste
725.277
Special Requirements for Incompatible Wastes
725.278
Air Emission Standards
SUBPART J: TANK SYSTEMS
Section
725.290
Applicability
725.291
Assessment of Existing Tank System’s Integrity
725.292
Design and Installation of New Tank Systems or Components
725.293
Containment and Detection of Releases
725.294
General Operating Requirements
725.295
Inspections
725.296
Response to leaks or spills and disposition of Tank Systems
725.297
Closure and Post-Closure Care
725.298
Special Requirements for Ignitable or Reactive Waste
725.299
Special Requirements for Incompatible Wastes
725.300
Waste Analysis and Trial Tests
725.301
Generators of 100 to 1000 kg/mo
725.302
Air Emission Standards
SUBPART K: SURFACE IMPOUNDMENTS
Section
725.320
Applicability
725.321
Design and Operating Requirements
725.322
Action Leakage Rate
725.323
Response Actions
725.324
Containment System
725.325
Waste Analysis and Trial Tests
725.326
Monitoring and Inspections
725.328
Closure and Post-Closure Care
725.329
Special Requirements for Ignitable or Reactive Waste
725.330
Special Requirements for Incompatible Wastes
300
725.331
Air Emission Standards
SUBPART L: WASTE PILES
Section
725.350
Applicability
725.351
Protection from Wind
725.352
Waste Analysis
725.353
Containment
725.354
Design and Operating Requirements
725.355
Action Leakage Rates
725.356
Special Requirements for Ignitable or Reactive Waste
725.357
Special Requirements for Incompatible Wastes
725.358
Closure and Post-Closure Care
725.359
Response Actions
725.360
Monitoring and Inspection
SUBPART M: LAND TREATMENT
Section
725.370
Applicability
725.372
General Operating Requirements
725.373
Waste Analysis
725.376
Food Chain Crops
725.378
Unsaturated Zone (Zone of Aeration) Monitoring
725.379
Recordkeeping
725.380
Closure and Post-closure
725.381
Special Requirements for Ignitable or Reactive Waste
725.382
Special Requirements for Incompatible Wastes
SUBPART N: LANDFILLS
Section
725.400
Applicability
725.401
Design Requirements
725.402
Action Leakage Rate
725.403
Response Actions
725.404
Monitoring and Inspection
725.409
Surveying and Recordkeeping
725.410
Closure and Post-Closure
725.412
Special Requirements for Ignitable or Reactive Waste
725.413
Special Requirements for Incompatible Wastes
725.414
Special Requirements for Liquid Wastes
725.415
Special Requirements for Containers
725.416
Disposal of Small Containers of Hazardous Waste in Overpacked Drums
(Lab Packs)
SUBPART O: INCINERATORS
301
Section
725.440
Applicability
725.441
Waste Analysis
725.445
General Operating Requirements
725.447
Monitoring and Inspection
725.451
Closure
725.452
Interim Status Incinerators Burning Particular Hazardous Wastes
SUBPART P: THERMAL TREATMENT
Section
725.470
Other Thermal Treatment
725.473
General Operating Requirements
725.475
Waste Analysis
725.477
Monitoring and Inspections
725.481
Closure
725.482
Open Burning; Waste Explosives
725.483
Interim Status Thermal Treatment Devices Burning Particular Hazardous
Waste
SUBPART Q: CHEMICAL, PHYSICAL AND BIOLOGICAL
TREATMENT
Section
725.500
Applicability
725.501
General Operating Requirements
725.502
Waste Analysis and Trial Tests
725.503
Inspections
725.504
Closure
725.505
Special Requirements for Ignitable or Reactive Waste
725.506
Special Requirements for Incompatible Wastes
SUBPART R: UNDERGROUND INJECTION
Section
725.530
Applicability
SUBPART W: DRIP PADS
Section
725.540
Applicability
725.541
Assessment of existing drip pad integrity
725.542
Design and installation of new drip pads
725.543
Design and operating requirements
725.544
Inspections
725.545
Closure
SUBPART AA: AIR EMISSION STANDARDS FOR PROCESS
VENTS
302
Section
725.930
Applicability
725.931
Definitions
725.932
Standards: Process Vents
725.933
Standards: Closed-vent Systems and Control Devices
725.934
Test methods and procedures
725.935
Recordkeeping Requirements
SUBPART BB: AIR EMISSION STANDARDS FOR EQUIPMENT
LEAKS
Section
725.950
Applicability
725.951
Definitions
725.952
Standards: Pumps in Light Liquid Service
725.953
Standards: Compressors
725.954
Standards: Pressure Relief Devices in Gas/Vapor Service
725.955
Standards: Sampling Connecting Systems
725.956
Standards: Open-ended Valves or Lines
725.957
Standards: Valves in Gas/Vapor or Light Liquid Service
725.958
Standards: Pumps, Valves, Pressure Relief Devices, Flanges and Other
Connectors
725.959
Standards: Delay of Repair
725.960
Standards: Closed-vent Systems and Control Devices
725.961
Percent Leakage Alternative for Valves
725.962
Skip Period Alternative for Valves
725.963
Test Methods and Procedures
725.964
Recordkeeping Requirements
SUBPART CC: AIR EMISSION STANDARDS FOR TANKS,
SURFACE IMPOUNDMENTS, AND CONTAINERS
Section
725.980
Applicability
725.981
Definitions
725.982
Schedule for Implementation of Air Emission Standards
725.983
Standards: General
725.984
Waste Determination Procedures
725.985
Standards: Tanks
725.986
Standards: Surface Impoundments
725.987
Standards: Containers
725.988
Standards: Closed-vent Systems and Control Devices
725.989
Inspection and Monitoring Requirements
725.990
Recordkeeping Requirements
725.991
Alternative Tank Emission Control Requirements (Repealed)
SUBPART DD: CONTAINMENT BUILDINGS
303
Section
725.1100
Applicability
725.1101
Design and operating standards
725.1102
Closure and Post Closure-Care
725.Appendix A
Recordkeeping Instructions
725.Appendix B
EPA Report Form and Instructions (Repealed)
725.Appendix C
EPA Interim Primary Drinking Water Standards
725.Appendix D
Tests for Significance
725.Appendix E
Examples of Potentially Incompatible Waste
725.Appendix F Compounds With Henry’s Law Constant Less Than 0.1 Y/X (at
25°C)
AUTHORITY: Implementing Section 22.4 and authorized by Section 27 of the
Environmental Protection Act [415 ILCS 5/22.4 and 27].
SOURCE: Adopted in R81-22, 43 PCB 427, at 5 Ill. Reg. 9781, effective May 17,
1982; amended and codified in R81-22, 45 PCB 317, at 6 Ill. Reg. 4828, effective
May 17, 1982; amended in R82-18, 51 PCB 831, at 7 Ill. Reg. 2518, effective
February 22, 1983; amended in R82-19, 53 PCB 131, at 7 Ill. Reg. 14034, effective
October 12, 1983; amended in R84-9, at 9 Ill. Reg. 11869, effective July 24, 1985;
amended in R85-22 at 10 Ill. Reg. 1085, effective January 2, 1986; amended in R86-1
at 10 Ill. Reg. 14069, effective August 12, 1986; amended in R86-28 at 11 Ill. Reg.
6044, effective March 24, 1987; amended in R86-46 at 11 Ill. Reg. 13489, effective
August 4, 1987; amended in R87-5 at 11 Ill. Reg. 19338, effective November 10,
1987; amended in R87-26 at 12 Ill. Reg. 2485, effective January 15, 1988; amended in
R87-39 at 12 Ill. Reg. 13027, effective July 29, 1988; amended in R88-16 at 13 Ill.
Reg. 437, effective December 28, 1988; amended in R89-1 at 13 Ill. Reg. 18354,
effective November 13, 1989; amended in R90-2 at 14 Ill. Reg. 14447, effective
August 22, 1990; amended in R90-10 at 14 Ill. Reg. 16498, effective September 25,
1990; amended in R90-11 at 15 Ill. Reg. 9398, effective June 17, 1991; amended in
R91-1 at 15 Ill. Reg. 14534, effective October 1, 1991; amended in R91-13 at 16 Ill.
Reg. 9578, effective June 9, 1992; amended in R92-1 at 16 Ill. Reg. 17672, effective
November 6, 1992; amended in R92-10 at 17 Ill. Reg. 5681, effective March 26,
1993; amended in R93-4 at 17 Ill. Reg. 20620, effective November 22, 1993; amended
in R93-16 at 18 Ill. Reg. 6771, effective April 26, 1994; amended in R94-7 at 18 Ill.
Reg. 12190, effective July 29, 1994; amended in R94-17 at 18 Ill. Reg. 17548,
effective November 23, 1994; amended in R95-6 at 19 Ill. Reg. 9566, effective June
27, 1995; amended in R95-20 at 20 Ill. Reg. 11078, effective August 1, 1996;
amended in R96-10/R97-3/R97-5 at 21 Ill. Reg. ________, effective
____________________.
SUBPART B: GENERAL FACILITY STANDARDS
304
Section 725.112
Required Notices
a)
Receipt from a foreign source.
1)
The owner or operator of a facility that has arranged to receive
hazardous waste from a foreign source must notify the Regional
Administrator in writing at least four weeks in advance of the
date the waste is expected to arrive at the facility. Notice of
subsequent shipments of the same waste from the same foreign
source is not required.
2)
The owner or operator of a recovery facility that has arranged to
receive hazardous waste subject to 35 Ill. Adm. Code
722.Subpart H must provide a copy of the tracking document
bearing all required signatures to the notifier, to the Office of
Enforcement and Compliance Assurance, Office of Compliance,
Enforcement Planning, Targeting and Data Division (2222A),
Environmental Protection Agency, 401 M St., SW, Washington,
DC 20460; to the Bureau of Land, Division of Land Pollution
Control, Illinois Environmental Protection Agency, P.O. Box
19276, Springfield, IL 62794-9276; and to the competent
authorities of all other concerned countries within three working
days of receipt of the shipment. The original of the signed
tracking document must be maintained at the facility for at least
three years.
b)
Before transferring ownership or operation of a facility during its
operating life, or of a disposal facility during the post-closure care
period, the owner or operator must notify the new owner or operator in
writing of the requirements of this Part and 35 Ill. Adm. Code 702 and
703 (Also see 40 35 Ill. Adm. Code 703.155.
BOARD NOTE: An owner’s or operator’s failure to notify the new
owner or operator of the requirements of this Part in no way relieves the
new owner or operator of his obligation to comply with all applicable
requirements.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 725.113
General Waste Analysis
a)
Waste analysis:
1)
Before an owner or operator treats, stores, or disposes of any
hazardous wastes, or non-hazardous wastes if applicable under
305
Section 725.213(d), the owner or operator shall obtain a detailed
chemical and physical analysis of a representative sample of the
wastes. At a minimum, the analysis must contain all the
information that must be known to treat, store, or dispose of the
waste in accordance with this Part and 35 Ill. Adm. Code 728.
2)
The analysis may include data developed under 35 Ill. Adm.
Code 721 and existing published or documented data on the
hazardous waste or on waste generated from similar processes.
BOARD NOTE: For example, the facility’s record of analyses
performed on the waste before the effective date of these
regulations or studies conducted on hazardous waste generated
from processes similar to that which generated the waste to be
managed at the facility may be included in the data base required
to comply with subsection (a)(1) aboveof this Section, except as
otherwise specified in 35 Ill. Adm. Code 728.107(b) and (c).
The owner or operator of an off-site facility may arrange for the
generator of the hazardous waste to supply part or all of the
information required by subsection (a)(1) aboveof this Section. If
the generator does not supply the information and the owner or
operator chooses to accept a hazardous waste, the owner or
operator is responsible for obtaining the information required to
comply with this Section.
3)
The analysis must be repeated as necessary to ensure that it is
accurate and up to date. At a minimum, the analysis must be
repeated:
A)
When the owner or operator is notified or has reason to
believe that the process or operation generating the
hazardous waste, or non-hazardous waste if applicable
under Section 725.213(d), has changed; and
B)
For off-site facilities, when the results of the inspection
required in subsection (a)(4) belowof this Section indicate
that the hazardous waste received at the facility does not
match the waste designated on the accompanying manifest
or shipping paper.
4)
The owner or operator of an off-site facility shall inspect and, if
necessary, analyze each hazardous waste movement received at
the facility to determine whether it matches the identity of the
waste specified on the accompanying manifest or shipping paper.
306
b)
The owner or operator shall develop and follow a written waste analysis
plan that describes the procedures that the owner or operator will carry
out to comply with subsection (a) aboveof this Section. The owner or
operator shall keep this plan at the facility. At a minimum, the plan
must specify:
1)
The parameters for which each hazardous waste, or non-
hazardous waste if applicable under Section 725.213(d), will be
analyzed and the rationale for the selection of these parameters
(i.e., how analysis for these parameters will provide sufficient
information on the waste’s properties to comply with subsection
(a) aboveof this Section.
2)
The test methods that will be used to test for these parameters.
3)
The sampling method that will be used to obtain a representative
sample of the waste to be analyzed. A representative sample may
be obtained using either:
A)
One of the sampling methods described in 35 Ill. Adm.
Code 721.Appendix A, or
B)
An equivalent sampling method.
BOARD NOTE: See 35 Ill. Adm. Code 720.120(c) for
related discussion.
4)
The frequency with which the initial analysis of the waste will be
reviewed or repeated to ensure that the analysis is accurate and
up-to-date.
5)
For off-site facilities, the waste analyses that hazardous waste
generators have agreed to supply.
6)
Where applicable, the methods that will be used to meet the
additional waste analysis requirements for specific waste
management methods, as specified in Sections 725.300, 725.325,
725.352, 725.373, 725.414, 725.441, 725.475, 725.502,
725.934(d), 725.963(d), and 725.984, and 35 Ill. Adm. Code
728.107.
7)
For surface impoundments exempted from land disposal
restrictions under 35 Ill. Adm. Code 728.104(a), the procedures
and schedules for:
307
A)
The sampling of impoundment contents;
B)
The analysis of test data; and
C)
The annual removal of residues that are not delisted under
35 Ill. Adm. Code 720.122 or that exhibit a characteristic
of hazardous waste and either:
i)
Do not meet the applicable treatment standards of
35 Ill. Adm. Code 728.Subpart D, or
ii)
Where no treatment standards have been
established: Such residues are prohibited from
land disposal under 35 Ill. Adm. Code 728.132 or
728.139.
8)
For owners and operators seeking an exemption to the air
emission standards of 724.Subpart CC of this part in accordance
with Section 725.983:
A)
TIf direct measurement is used for the waste
determination, the procedures and schedules for waste
sampling and analysis, and the analysis of test data to
verify the exemption.
B)
Each generator’s notice and certification of the volatile
organic concentration in the waste if the waste is received
from offsiteIf knowledge of the waste is used for the
waste determination, any information prepared by the
facility owner or operator, or by the generator of the
waste if the waste is received form off-site, that is used as
the basis for knowledge of the waste.
c)
For off-site facilities, the waste analysis plan required in subsection (b)
aboveof this Section must also specify the procedures that will be used to
inspect and, if necessary, analyze each movement of hazardous waste
received at the facility to ensure that it matches the identity of the waste
designated on the accompanying manifest or shipping paper. At a
minimum, the plan must describe:
1)
The procedures that will be used to determine the identity of each
movement of waste managed at the facility; and
308
2)
The sampling method that will be used to obtain a representative
sample of the waste to be identified if the identification method
includes sampling.
3)
The procedures that the owner or operator of an off-site landfill
receiving containerized hazardous waste will use to determine
whether a hazardous waste generator or treater has added a
biodegradable sorbent to the waste in the container.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
SUBPART E: MANIFEST SYSTEM, RECORDKEEPING AND
REPORTING
Section 725.171
Use of Manifest System
a)
If a facility receives hazardous waste accompanied by a manifest, the
owner or operator or his agent must:
1)
Sign and date each copy of the manifest to certify that the
hazardous waste covered by the manifest was received;
2)
Note any significant discrepancies in the manifest, as defined in
Section 725.172(a), on each copy of the manifest;
BOARD NOTE: An owner or operator of a facility whose
procedures under Section 725.113(c) include waste analysis need
not perform that analysis before signing the manifest and giving it
to the transporter. Section 725.172(b), however, requires the
owner or operator to report any unreconciled discrepancy
discovered during later analysis.
3)
Immediately give the transporter at least one copy of the signed
manifest;
4)
Send a copy of the manifest to each of the generator and the
Agency within 30 days of the date of delivery; and
5)
Retain at the facility a copy of each manifest for at least three
years from the date of delivery.
b)
If a facility receives from a rail or water (bulk shipment) transporter
hazardous waste that is accompanied by a shipping paper containing all
the information required on the manifest (excluding the U.S. EPA
309
identification numbers, generator’s certification and signatures), the
owner or operator or its agent must:
1)
Sign and date each copy of the manifest or shipping paper (if the
manifest has not been received) to certify that the hazardous
waste covered by the manifest or shipping paper was received;
2)
Note any significant discrepancies, as defined in Section
725.172(a), in the manifest or shipping paper (if the manifest has
not been received) on each copy of the manifest or shipping
paper;
BOARD NOTE: The owner or operator of a facility whose
procedures under Section 725.113(c) include waste analysis need
not perform that analysis before signing the shipping paper and
giving it to the transporter. Section 725.172(b), however,
requires reporting an unreconciled discrepancy discovered during
later analysis.
3)
Immediately give the rail or water (bulk shipment) transporter at
least one copy of the manifest or shipping paper (if the manifest
has not been received);
4)
Send a copy of the signed and dated manifest to the generator and
to the Agency within 30 days after the delivery; however, if the
manifest has not been received within 30 days after delivery, the
owner or operator, or his agent, must send a copy of the shipping
paper signed and dated to the generator; and
BOARD NOTE: 35 Ill. Adm. Code 722.123(c) requires the
generator to send three copies of the manifest to the facility when
hazardous waste is sent by rail or water (bulk shipment).
5)
Retain at the facility a copy of the manifest and shipping paper (if
signed in lieu of the manifest at the time of delivery) for at least
three years from the date of delivery.
c)
Whenever a shipment of hazardous waste is initiated from a facility, the
owner or operator of that facility must comply with the requirements of
35 Ill. Adm. Code 722.
BOARD NOTE: The provisions of 35 Ill. Adm. Code 722.134 are
applicable to the on-site accumulation of hazardous wastes by generators.
Therefore, the provisions of 35 Ill. Adm. Code 722.134 apply only to
310
owners or operators that are shipping hazardous waste that they
generated at that facility.
d)
Within three working days of the receipt of a shipment subject to 35 Ill.
Adm. Code 722.Subpart H, the owner or operator of the facility must
provide a copy of the tracking document bearing all required signatures
to the notifier; to the Office of Enforcement and Compliance Assurance,
Office of Compliance, Enforcement Planning, Targeting and Data
Division (2222A), Environmental Protection Agency, 401 M St., SW,
Washington, DC 20460; to the Bureau of Land, Division of Land
Pollution Control, Illinois Environmental Protection Agency, P.O. Box
19276, Springfield, IL 62794-9276; and to competent authorities of all
other concerned countries. The original copy of the tracking document
must be maintained at the facility for at least three years from the date of
signature.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
SUBPART I: USE AND MANAGEMENT OF CONTAINERS
Section 725.278
Air Emission Standards
The owner or operator shall manage all hazardous waste placed in a container in
accordance with the requirements of 724.Subparts AA, BB, and CC.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
SUBPART K: SURFACE IMPOUNDMENTS
Section 725.331
Air Emission Standards
The owner or operator shall manage all hazardous waste placed in a surface
impoundment in accordance with the requirements of 724.Subparts BB and CC.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
SUBPART N: LANDFILLS
Section 725.414
Special Requirements for Liquid Wastes
a)
This subsection corresponds with 40 CFR 265.314(a), which pertains to
the placement of bulk or non-containerized liquid waste or waste
311
containing free liquids in a landfill prior to May 8, 1985. This statement
maintains structural consistency with U.S. EPA rules.
b)
The placement of bulk or non-containerized liquid hazardous waste or
hazardous waste containing free liquids (whether or not sorbents have
been added) in any landfill is prohibited.
c)
Containers holding free liquids must not be placed in a landfill unless;:
1)
All free-standing liquid:
A)
has been removed by decanting or other methods;
B)
has been mixed with sorbent or solidified so that free-
standing liquid is no longer observed; or
C)
has been otherwise eliminated; or
2)
The container is very small, such as an ampule; or
3)
The container is designed to hold free liquids for use other than
storage, such as a battery or capacitor; or
4)
The container is a lab pack as defined in Section 724.416 and is
disposed of in accordance with Section 724.416.
d)
To demonstrate the absence or presence of free liquids in either a
containerized or a bulk waste, the following test must be used: Method
9095 (Paint Filter Liquids Test), as described in “Test Methods for
Evaluating Solid Wastes, Physical/Chemical Methods”, U.S. EPA
Publication No. SW-846, incorporated by reference in 35 Ill. Adm.
Code 720.111.
e)
The placement of any liquids that is not a hazardous waste in a landfill is
prohibited (35 Ill. Adm. Code 729.311).
f)
Sorbents used to treat free liquids to be disposed of in landfills must be
nonbiodegradable. Nonbiodegradable sorbents are: materials listed or
described in subsection (f)(1) belowof this Section; materials that pass
one of the tests in subsection (f)(2) belowof this Section; or materials
that are determined by Board to be nonbiodegradable through the 35 Ill.
Adm. Code 106 adjusted standard process.
1)
Nonbiodegradable sorbents are:
312
A)
Inorganic minerals, other inorganic materials, and
elemental carbon (e.g., aluminosilicates, clays, smectites,
Fuller’s earth, bentonite, calcium bentonite,
montmorillonite, calcined montmorillonite, kaolinite,
micas (illite), vermiculites, zeolites; calcium carbonate
(organic free limestone); oxides/hydroxides, alumina,
lime, silica (sand), diatomaceous earth; perlite (volcanic
glass); expanded volcanic rock; volcanic ash; cement kiln
dust; fly ash; rice hull ash; activated charcoal/activated
carbon); or
B)
High molecular weight synthetic polymers (e.g.,
polyethylene, high density polyethylene (HDPE),
polypropylene, polystyrene, polyurethane, polyacrylate,
polynorborene, polyisobutylene, ground synthetic rubber,
cross-linked allylstyrene and tertiary butyl copolymers).
This does not include polymers derived from biological
material or polymers specifically designed to be
degradable; or
C)
Mixtures of these nonbiodegradable materials.
2)
Tests for nonbiodegradable sorbents.
A)
The sorbent material is determined to be nonbiodegradable
under ASTM Method G21-70 (1984a)--”Standard Practice
for Determining Resistance of Synthetic Polymer
Materials to Fungi”, incorporated by reference in 35 Ill.
Adm. Code 720.111; or
B)
The sorbent material is determined to be nonbiodegradable
under ASTM Method G22-76 (1984b)--”Standard Practice
for Determining Resistance of Plastics to Bacteria”,
incorporated by reference in 35 Ill. Adm. Code 720.111;
or
C)
The sorbent material is determined to be non-
biodegradable under OECD test 301B (CO
2
Evolution
(Modified Sturm Test)), incorporated by reference in 35
Ill. Adm. Code 720.111.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
313
SUBPART AA: AIR EMISSION STANDARDS FOR PROCESS
VENTS
Section 725.930
Applicability
a)
This Subpart applies to owners and operators of facilities that treat, store
or dispose of hazardous wastes (except as provided in Section 725.101).
b)
Except for Sections 725.934(d) and 725.935(e), this Subpart applies to
process vents associated with distillation, fractionation, thin-film
evaporation, solvent extraction, or air or steam stripping operations that
manage hazardous wastes with organic concentrations of at least 10
ppmw (parts per million by weight), if these operations are conducted in
one of the following:
1)
UA units that areis subject to the permitting requirements of 35
Ill. Adm. Code 702, 703, and 705; or
2)
HA unit (including a hazardous waste recycling units) that areis
not exempt from permitting under the provisions of 35 Ill. Adm.
Code 262.34(a) (i.e., a hazardous waste recycling unit that is not
a 90-day tank or container) and that is located on a hazardous
waste management facilitiesfacility otherwise subject to the
permitting requirements of 35 Ill. Adm. Code 702, 703, and 705.
BOARD NOTE: The requirements of Sections 725.932 through
725.936 apply to process vents on hazardous waste recycling
units previously exempt under 35 Ill. Adm. Code 721.106(c)(1).
Other exemptions under 35 Ill. Adm. Code 721.104, 722.134
and 725.101(c) are not affected by these requirements.
c)
Agency decisions pursuant to this Part must be made in writing, are in
the nature of permit decisions pursuant to Section 39 of the
Environmental Protection Act and may be appealed to the Board
pursuant to 35 Ill. Adm. Code 105.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 725.933
Standards: Closed-vent Systems and Control Devices
a)
Compliance Required.
1)
Owners or operators of closed-vent systems and control devices
used to comply with provisions of this Part shall comply with the
provisions of this Section.
314
2)
The owner or operator of an existing facility that cannot install a
closed-vent system and control device to comply with the
provisions of this Subpart on the effective date that the facility
becomes subject to the provisions of this Subpart shall prepare an
implementation schedule that includes dates by which the closed-
vent system and control device will be installed and in operation.
The controls must be installed as soon as possible, but the
implementation schedule may allow up to 1830 months after the
effective date that the facility becomes subject to this Subpart for
installation and startup. All units that begin operation after
December 21, 1990, must comply with the rules immediately
(i.e., must have control devices installed and operating on startup
of the affected unit); the 2-year implementation schedule does not
apply to these units.
b)
A control device involving vapor recovery (e.g., a condenser or
adsorber) must be designed and operated to recover the organic vapors
vented to it with an efficiency of 95 weight percent or greater unless the
total organic emission limits of Section 725.932(a)(1) for all affected
process vents is attained at an efficiency less than 95 weight percent.
c)
An enclosed combustion device (e.g., a vapor incinerator, boiler, or
process heater) must be designed and operated to reduce the organic
emissions vented to it by 95 weight percent or greater; to achieve a total
organic compound concentration of 20 ppmv, expressed as the sum of
the actual compounds, not carbon equivalents, on a dry basis corrected
to 3three percent oxygen; or to provide a minimum residence time of
0.50 seconds at a minimum temperature of 760° C. If a boiler or
process heater is used as the control device, then the vent stream must be
introduced into the flame combustion zone of the boiler or process
heater.
d)
Flares
1)
A flare must be designed for and operated with no visible
emissions as determined by the methods specified in subsection
(e)(1) belowof this Section except for periods not to exceed a
total of 5 minutes during any 2 consecutive hours.
2)
A flare must be operated with a flame present at all times, as
determined by the methods specified in subsection (f)(2)(c)
belowof this Section.
315
3)
A flare must be used only if the net heating value of the gas
being combusted is 11.2 MJ/scm (300 Btu/scf) or greater if the
flare is steam-assisted or air-assisted, or if the net heating value
of the gas being combusted is 7.45 MJ/scm (200 Btu/scf) or
greater if the flare is nonassisted. The net heating value of the
gas being combusted must be determined by the methods
specified in subsection (e)(2) belowof this Section.
4)
Exit Velocity.
A)
A steam-assisted or nonassisted flare must be designed for
and operated with an exit velocity, as determined by the
methods specified in subsection (e)(3) belowof this
Section, less than 18.3 m/s (60 ft/s), except as provided in
subsections (d)(4)(B) and (d)(4)(C) belowof this Section.
B)
A steam-assisted or nonassisted flare designed for and
operated with an exit velocity, as determined by the
methods specified in subsection (e)(3) belowof this
Section, equal to or greater than 18.3 m/s (60 ft/s) but
less than 122 m/s (400 ft/s) is allowed if the net heating
value of the gas being combusted is greater than 37.3
MJ/scm (1000 Btu/scf).
C)
A steam-assisted or nonassisted flare designed for and
operated with an exit velocity, as determined by the
methods specified in subsection (e)(3) belowof this
Section, less than the velocity, V as determined by the
method specified in subsection (e)(4) and less than 122
m/s (400 ft/s) is allowed.
5)
An air-assisted flare must be designed and operated with an exit
velocity less than the velocity, V as determined by the method
specified in subsection (e)(5) belowof this Section.
6)
A flare used to comply with this Section must be steam-assisted,
air-assisted, or nonassisted.
e)
Compliance determination and equations.
1)
Reference Method 22 in 40 CFR 60, incorporated by reference in
35 Ill. Adm. Code 720.111, must be used to determine the
compliance of a flare with the visible emission provisions of this
Subpart. The observation period is 2 hours and must be used
according to Method 22.
316
2)
The net heating value of the gas being combusted in a flare must
be calculated using the following equation:
Where:
H
T
is the net heating value of the sample in MJ/scm;
where the net enthalpy per mole of offgas is based on
combustion at 25° C and 760 mm Hg, but the standard
temperature for determining the volume corrersponding to
1 mole is 20° C.
K = 1.74
×
10
-7
(1/ppm)(g mol/scm)(MJ/kcal) where
standard temperature for (g mol/scm) 20° C.
SX
i
means the sum of the values of X for each component
i, from i=1 to n.
C
i
is the concentration of sample component i in ppm on a
wet basis, as measured for organics by Reference Method
18 in 40 CFR 60, and for carbon monoxide, by ASTM D
1946-90, incorporated by reference in 35 Ill. Adm. Code
720.111.
H
i
is the net heat of combustion of sample component i,
kcal/gmol at 25° C and 760 mm Hg. The heats of
combustion must be determined using ASTM D 2382-88,
incorporated by reference in 35 Ill. Adm. Code 720.111,
if published values are not available or cannot be
calculated.
3)
The actual exit velocity of a flare must be determined by dividing
the volumetric flow rate (in units of standard temperature and
pressure), as determined by Reference Methods 2, 2A, 2C, or 2D
in 40 CFR 60, incorporated by reference in 35 Ill. Adm. Code
720.111, as appropriate, by the unobstructed (free) cross-
sectional area of the flare tip.
T
i
i
H
= K
i
n
C
H
×
=
∑
×
1
317
4)
The maximum allowed velocity in m/s, V for a flare complying
with subsection (d)(4)(C) aboveof this Section must be
determined by the following equation:
Where:
Log
10
means logarithm to the base 10
H
T
is the net heating value as determined in subsection
(e)(2) aboveof this Section.
5)
The maximum allowed velocity in m/s, V for an air-assisted flare
must be determined by the following equation:
Where:
H
T
is the net heating value as determined in subsection
(e)(2) aboveof this Section.
f)
The owner or operator shall monitor and inspect each control device
required to comply with this Section to ensure proper operation and
maintenance of the control device by implementing the following
requirements:
1)
Install, calibrate, maintain, and operate according to the
manufacturer’s specifications a flow indicator that provides a
record of vent stream flow from each affected process vent to the
control device at least once every hour. The flow indicator
sensor must be installed in the vent stream at the nearest feasible
point to the control device inlet but before being combined with
other vent streams.
log
.
.
max
10
288
317
V
H
T
=
+
(
)
log
.
.
max
10
28 8
317
V
H
T
=
+
V = 8.706 +0.7084 H
T
318
2)
Install, calibrate, maintain, and operate according to the
manufacturer’s specifications a device to continuously monitor
control device operation as specified below:
A)
For a thermal vapor incinerator, a temperature monitoring
device equipped with a continuous recorder. The device
must have accuracy of ± 1 percent ±1% of the
temperature being monitored in ° C or ± 0.5° C,
whichever is greater. The temperature sensor must be
installed at a location in the combustion chamber
downstream of the combustion zone.
B)
For a catalytic vapor incinerator, a temperature
monitoring device equipped with a continuous recorder.
The device must be capable of monitoring temperature at
two locations and have an accuracy of ± 1 percent ±1%
of the temperature being monitored in ° C or ± 0.5° C,
whichever is greater. One temperature sensor must be
installed in the vent stream at the nearest feasible point to
the catalyst bed inlet and a second temperature sensor
must be installed in the vent stream at the nearest feasible
point to the catalyst bed outlet.
C)
For a flare, a heat sensing monitoring device equipped
with a continuous recorder that indicates the continuous
ignition of the pilot flame.
D)
For a boiler or process heater having a design heat input
capacity less than 44 MW, a temperature monitoring
device equipped with a continuous recorder. The device
must have an accuracy of ± 1 percent ±1% of the
temperature being monitored in ° C or ± 0.5° C,
whichever is greater. The temperature sensor must be
installed at a location in the furnace downstream of the
combustion zone.
E)
For a boiler or process heater having a design heat input
capacity greater than or equal to 44 MW, a monitoring
device equipped with a continuous recorder to measure
parameters that indicates good combustion operating
practices are being used.
F)
For a condenser, either:
319
i)
A monitoring device equipped with a continuous
recorder to measure the concentration level of the
organic compounds in the exhaust vent stream
from the condenser; or
ii)
A temperature monitoring device equipped with a
continuous recorder. The device must be capable
of monitoring temperature at two locations and
havewith an accuracy of ± 1 percent ±1% of the
temperature being monitored in degrees Celsius (°
C) or ±0.5° C, whichever is greater. OneThe
temperature sensor must be installed at a location
in the exhaust vent stream from the condenser, and
a second temperature sensor must be installed at a
location in the coolant fluid exiting the condenser
exit (i.e., product side).
G)
For a carbon adsorption system such as a fixed-bed carbon
adsorber that regenerates the carbon bed directly in the
control device, either:
i)
A monitoring device equipped with a continuous
recorder to measure the concentration level of the
organic compounds in the exhaust vent stream
from the carbon bed; or
ii)
A monitoring device equipped with a continuous
recorder to measure a parameter that indicates the
carbon bed is regenerated on a regular,
predetermined time cycle.
3)
Inspect the readings from each monitoring device required by
subsections (f)(1) and (f)(2) aboveof this Section at least once
each operating day to check control device operation and, if
necessary, immediately implement the corrective measures
necessary to ensure the control device operates in compliance
with the requirements of this Section.
g)
An owner or operator using a carbon adsorption system such as a fixed-
bed carbon adsorber that regenerates the carbon bed directly onsite in the
control device shall replace the existing carbon in the control device with
fresh carbon at a regular, predetermined time interval that is no longer
than the carbon service life established as a requirement of Section
725.935(b)(4)(C)(vi).
320
h)
An owner or operator using a carbon adsorption system, such as a
carbon canister, that does not regenerate the carbon bed directly onsite in
the control device shall replace the existing carbon in the control device
with fresh carbon on a regular basis by using one of the following
procedures:
1)
Monitor the concentration level of the organic compounds in the
exhaust vent stream from the carbon adsorption system on a
regular schedule, and replace the existing carbon with fresh
carbon immediately when carbon breakthrough is indicated. The
monitoring frequency must be daily or at an interval no greater
than 20 percent% of the time required to consume the total
carbon working capacity established as a requirement of Section
725.935(b)(4)(C)(vii), whichever is longer.
2)
Replace the existing carbon with fresh carbon at a regular,
predetermined time interval that is less than the design carbon
replacement interval established as a requirement of Section
725.935(b)(4)(C)(vii).
i)
An owner or operator of an affected facility seeking to comply with the
provisions of this Part by using a control device other than a thermal
vapor incinerator, catalytic vapor incinerator, flare, boiler, process
heater, condenser, or carbon adsorption system is required to develop
documentation including sufficient information to describe the control
device operation and identify the process parameter or parameters that
indicate proper operation and maintenance of the control device.
j)
Closed vent systems.A closed vent system must meet either of the
following design requirements:
1)
CA closed-vent systems must be designed for andto operated with
no detectable emissions, as indicated by an instrument reading of
less than 500 ppmv above background and by visual inspections,
as determined by the methods specified at Section 725.934(b).,
and by visual inspections; or
2)
Closed-vent systems must be monitored to determine compliance
with this Section during the initial leak detection monitoring,
which must be conducted by the date that the facility becomes
subject to the provisions of this Section annually, and at other
times as specified by the Agency pursuant to Section 725.930(c).
For the annual leak detection monitoring after the initial leak
detection monitoring, the owner or operator is not required to
monitor those closed-vent system components that continuously
321
operate in vacuum service or those closed-vent system joints,
seams, or other connections that are permanently or semi-
permanently sealed (e.g., a welded joint between two sections of
metal pipe or a bolted and gasketed pipe flange).A closed-vent
system must be designed to operate at a pressure below
atmospheric pressure. The system must be equipped with at least
one pressure gauge or other pressure measurement device that can
be read from a readily accessible location to verify that negative
pressure is being maintained in the closed-vent system when the
control device is operating.
3) Detectable emissions, as indicated by an instrument reading
greater than 500 ppm and visual inspections, must be controlled
as soon as practicable, but not later than 15 calendar days after
the emission is detected.
4) A first attempt at repair must be made no later than 5 calendar
days after the emission is detected.
k)
The owner or operator shall monitor and inspect each closed-vent system
required to comply with this Section to ensure proper operation and
maintenance of the closed-vent system by implementing the following
requirements:
1)
Each closed-vent system that is used to comply with subsection
(j)(1) of this Section shall be inspected and monitored in
accordance with the following requirements:
A)
An initial leak detection monitoring of the closed-vent
system shall be conducted by the owner or operator on or
before the date that the system becomes subject to this
Section. The owner or operator shall monitor the closed-
vent system components and connections using the
procedures specified in Section 725.934(b) to demonstrate
that the closed-vent system operates with no detectable
emissions, as indicated by an instrument reading of less
than 500 ppmv above background.
B)
After initial leak detection monitoring required in
subsection (k)(1)(A) of this Section, the owner or operator
shall inspect and monitor the closed-vent system as
follows:
i)
Closed-vent system joints, seams, or other
connections that are permanently or semi-
322
permanently sealed (e.g., a welded joint between
two sections of hard piping or a bolted and
gasketed ducting flange) must be visually inspected
at least once per year to check for defects that
could result in air pollutant emissions. The owner
or operator shall monitor a component or
connection using the procedures specified in
Section 725.934(b) to demonstrate that it operates
with no detectable emissions following any time
the component is repaired or replaced (e.g., a
section of damaged hard piping is replaced with
new hard piping) or the connection is unsealed
(e.g., a flange is unbolted).
ii)
Closed-vent system components or connections
other than those specified in subsection (k)(1)(B)(i)
of this Section must be monitored annually and at
other times as requested by the Regional
Administrator, except as provided for in subsection
(n) of this Section, using the procedures specified
in Section 725.934(b) to demonstrate that the
components or connections operate with no
detectable emissions.
C)
In the event that a defect or leak is detected, the owner or
operator shall repair the defect or leak in accordance with
the requirements of subsection (k)(3) of this Section.
D)
The owner or operator shall maintain a record of the
inspection and monitoring in accordance with the
requirements specified in Section 725.935.
2)
Each closed-vent system that is used to comply with subsection
(j)(2) of this Section must be inspected and monitored in
accordance with the following requirements:
A)
The closed-vent system must be visually inspected by the
owner or operator to check for defects that could result in
air pollutant emissions. Defects include, but are not
limited to, visible cracks, holes, or gaps in ductwork or
piping or loose connections.
B)
The owner or operator shall perform an initial inspection
of the closed-vent system on or before the date that the
system becomes subject to this Section. Thereafter, the
323
owner or operator shall perform the inspections at least
once every year.
C)
In the event that a defect or leak is detected, the owner or
operator shall repair the defect in accordance with the
requirements of subsection (k)(3) of this Section.
D)
The owner or operator shall maintain a record of the
inspection and monitoring in accordance with the
requirements specified in Section 725.935.
3)
The owner or operator shall repair all detected defects as follows:
A)
Detectable emissions, as indicated by visual inspection or
by an instrument reading greater than 500 ppmv above
background, must be controlled as soon as practicable, but
not later than 15 calendar days after the emission is
detected, except as provided for in subsection (k)(3)(C) of
this Section.
B)
A first attempt at repair must be made no later than five
calendar days after the emission is detected.
C)
Delay of repair of a closed-vent system for which leaks
have been detected is allowed if the repair is technically
infeasible without a process unit shutdown, or if the
owner or operator determines that emissions resulting
from immediate repair would be greater than the fugitive
emissions likely to result from delay of repair. Repair of
such equipment must be completed by the end of the next
process unit shutdown.
D)
The owner or operator shall maintain a record of the
defect repair in accordance with the requirements
specified in Section 725.935.
kl)
CA closed-vent systems andor control devices used to comply with
provisions of this Subpart must be operated at all times when emissions
may be vented to themit.
lm)
The owner or operator using a carbon adsorption system to control air
pollutant emissions shall document that all carbon removed that is a
hazardous waste and that is removed from the control device is managed
in one of the following manners, regardless of the volatile organic
concentration of the carbon:
324
1)
It is regenerated or reactivated in a thermal treatment unit that is
permitted under 35 Ill. Adm. Code 724.Subpart X or
725.Subpart P,meets one of the following:
A)
The owner or operator of the unit has been issued a final
permit under 35 Ill. Adm. Code 702, 703, and 705 that
implements the requirements of 35 Ill. Adm. Code
724.Subpart X; or
B)
The unit is equipped with and operating air emission
controls in accordance with the applicable requirements of
725.Subparts AA and CC or 35 Ill. Adm. Code 724; or
C)
The unit is equipped with and operating air emission
controls in accordance with a national emission standard
for hazardous air pollutants under 40 CFR 61 or 40 CFR
63.
2)
It is incinerated by a process that is permitted under 35 Ill. Adm.
Code 724.Subpart O or 725.Subpart O, orin a hazardous waste
incinerator for which the owner or operator has done either of the
following:
A)
The owner or operator has been issued a final permit
under 35 Ill. Adm. Code 702, 703, and 705 that
implements the requirements of 35 Ill. Adm. Code
724.Subpart O, or
B)
The owner or operator has designed and operates the
incinerator in accordance with the interim status
requirements of 725.Subpart O.
3)
It is burned in a boiler or industrial furnace that is permitted
under 35 Ill. Adm. Code 726.Subpart H.for which the owner or
operator has done either of the following:
A)
The owner or operator has been issued a final permit
under 35 Ill. Adm. Code 702, 703, and 705 that
implements the requirements of 35 Ill. Adm. Code
726.Subpart H, or
B)
The owner or operator has designed and operates the
boiler or industrial furnace in accordance with the interim
status requirements of 35 Ill. Adm. Code 726.Subpart H.
325
n)
Any components of a closed-vent system that are designated, as
described in Section 725.935(c)(9), as unsafe to monitor are exempt
from the requirements of subsection (k)(1)(B)(ii) of this Section if both
of the following conditions are fulfilled:
1)
The owner or operator of the closed-vent system has determined
that the components of the closed-vent system are unsafe to
monitor because monitoring personnel would be exposed to an
immediate danger as a consequence of complying with subsection
(k)(1)(B)(ii) of this Section; and
2)
The owner or operator of the closed-vent system adheres to a
written plan that requires monitoring the closed-vent system
components using the procedure specified in subsection
(k)(1)(B)(ii) of this Section as frequently as practicable during
safe-to-monitor times.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 725.934
Test Methods and Procedures
a)
Each owner or operator subject to the provisions of this Subpart shall
comply with the test methods and procedures requirements provided in
this Section
b)
When a closed-vent system is tested for compliance with no detectable
emissions, as required in Section 725.933(jk), the test must comply with
the following requirements:
1)
Monitoring must comply with Reference Method 21 in 40 CFR
60, incorporated by reference in 35 Ill. Adm. Code 720.111.
2)
The detection instrument must meet the performance criteria of
Reference Method 21.
3)
The instrument must be calibrated before use on each day of its
use by the procedures specified in Reference Method 21.
4)
Calibration gases must be:
A)
Zero air (less than 10 ppm of hydrocarbon in air).
326
B)
A mixture of methane or n-hexane and air at a
concentration of approximately, but less than, 10,000 ppm
methane or n-hexane.
5)
The background level must be determined as set forth in
Reference Method 21.
6)
The instrument probe must be traversed around all potential leak
interfaces as close to the interface as possible, as described in
Reference Method 21.
7)
The arithmetic difference between the maximum concentration
indicated by the instrument and the background level is compared
with 500 ppm for determining compliance.
c)
Performance tests to determine compliance with Section 725.932(a) and
with the total organic compound concentration limit of Section
725.933(c) must comply with the following:
1)
Performance tests to determine total organic compound
concentrations and mass flow rates entering and exiting control
devices must be conducted and data reduced in accordance with
the following reference methods and calculation procedures:
A)
Method 2 in 40 CFR 60 for velocity and volumetric flow
rate.
B)
Method 18 in 40 CFR 60 for organic content.
C)
Each performance test must consist of three separate runs,
each run conducted for at least 1 hour under the
conditions that exist when the hazardous waste
management unit is operating at the highest load or
capacity level reasonably expected to occur. For the
purpose of determining total organic compound
concentrations and mass flow rates, the average of results
of all runs applies. The average must be computed on a
time-weighed basis.
D)
Total organic mass flow rates must be determined by the
following equation:
F = K * Q * SUM(Ci * MWi)
Where:
327
F is the total organic mass flow rate, kg/h.
K = 4.16 E -8, conversion factor for molar
volume, kg-mol/cubic m, at 293 K and 760 mm
Hg.
Q = volumetric flow rate of gases entering or
exiting control device, dscm/h, as determined by
Method 2 in 40 CFR 60, incorporated by reference
in 35 Ill. Adm. Code 720.111.
SUM(Xi) means the sum of the values of X for
each component i, from i=1 to n.
n = number of organic compounds in the vent gas.
Ci is the organic concentration in ppm, dry basis,
of compound i in the vent gas, as determined by
Method 18 in 40 CFR 60.
MWi is the molecular weight of organic compound
i in the vent gas, kg/kg-mol.
h
2sd
i
i
-6
E
= Q
x(
n
i = 1
C
x MW
)x0.0416x10
∑
Where:
E
h
= The total organic mass flow rate, kg/h.
Q
2sd
= The volumetric flow rate of gases entering
or exiting control device, dscm/h, as determined
by Method 2 in 40 CFR 60, incorporated by
reference in 35 Ill. Adm. Code 720.111.
n = The number of organic compounds in the vent
gas.
C
i
= The organic concentration in ppm, dry basis,
of compound i in the vent gas, as determined by
Method 18 in 40 CFR 60.
328
MW
i
= The molecular weight of organic
compound i in the vent gas, kg/kg-mol.
0.0416 = The conversion factor for molar
volume, kg-mol/m
3
, at 293 K and 760 mm Hg.
10
6
= The conversion factor from ppm.
E)
The annual total organic emission rate must be determined
by the following equation:
A = F *
×
HOURS
Where:
A is total organic emission rate, kg/y.
F is the total organic mass flow rate, kg/h, as
calculated in subsection (c)(1)(D) of this Section.
HOURS is the total annual hours of operation for
the affected unit.
F)
Total organic emissions from all affected process vents at
the facility must be determined by summing the hourly
total organic mass emissions rates (F as determined in
subsection (c)(1)(D) of this Section) and by summing the
annual total organic mass emission rates (A as determined
in subsection (c)(1)(E) of this Section) for all affected
process vents at the facility.
2)
The owner or operator shall record such process information as is
necessary to determine the conditions of the performance tests.
Operations during periods of startup, shutdown and malfunction
do not constitute representative conditions for the purpose of a
performance test.
3)
The owner or operator of an affected facility shall provide, or
cause to be provided, performance testing facilities as follows:
A)
Sampling ports adequate for the test methods specified in
subsection (c)(1) of this Section.
329
B)
Safe sampling platform(s).
C)
Safe access to sampling platform(s).
D)
Utilities for sampling and testing equipment.
4)
For the purpose of making compliance determinations, the time-
weighted average of the results of the three runs must apply. In
the event that a sample is accidentally lost or conditions occur in
which one of the three runs must be discontinued because of
forced shutdown, failure of an irreplaceable portion of the sample
train, extreme meteorological conditions or other circumstances
beyond the owner or operator’s control, compliance may, upon
the Agency’s approval, be determined using the average of the
results of the two other runs.
d)
To show that a process vent associated with a hazardous waste
distillation, fractionation, thin-film evaporation, solvent extraction, or
air or steam stripping operation is not subject to the requirements of this
Subpart, the owner or operator shall make an initial determination that
the time-weighted, annual average total organic concentration of the
waste managed by the waste management unit is less than 10 ppmw
using one of the following two methods:
1)
Direct measurement of the organic concentration of the waste
using the following procedures:
A)
The owner or operator shall take a minimum of four grab
samples of waste for each wastestream managed in the
affected unit under process conditions expected to cause
the maximum waste organic concentration.
B)
For waste generated onsite, the grab samples must be
collected at a point before the waste is exposed to the
atmosphere such as in an enclosed pipe or other closed
system that is used to transfer the waste after generation to
the first affected distillation, fractionation, thin-film
evaporation, solvent extraction, or air or steam stripping
operation. For waste generated offsite, the grab samples
must be collected at the inlet to the first waste
management unit that receives the waste provided the
waste has been transferred to the facility in a closed
system such as a tank truck and the waste is not diluted or
mixed with other waste.
330
C)
Each sample must be analyzed and the total organic
concentration of the sample must be computed using
Method 9060 or 8240 of SW-846, (incorporated by
reference under 35 Ill. Adm. Code 720.111.
D)
The arithmetic mean of the results of the analyses of the
four samples apply for each wastestream managed in the
unit in determining the time-weighted, annual average
total organic concentration of the waste. The time-
weighted average is to be calculated using the annual
quantity of each waste stream processed and the mean
organic concentration of each wastestream managed in the
unit.
2)
Using knowledge of the waste to determine that its total organic
concentration is less than 10 ppmw. Documentation of the waste
determination is required. Examples of documentation that must
be used to support a determination under this subsection (d)(2)
include:
A)
Production process information documenting that no
organic compounds are used.;
B)
Information that the waste is generated by a process that is
identical to a process at the same or another facility that
has previously been demonstrated by direct measurement
to generate a wastestream having a total organic content
less than 10 ppmw,; or
C)
Prior speciation analysis results on the same wastestream
where it is documented that no process changes have
occurred since that analysis that could affect the waste
total organic concentration.
e)
The determination that distillation, fractionation, thin-film evaporation,
solvent extraction, or air or steam stripping operations which manage
hazardous wastes with time-weighted, annual average total organic
concentrations less than 10 ppmw must be made as follows:
1)
By the effective date that the facility becomes subject to the
provisions of this Subpart or by the date when the waste is first
managed in a waste management unit, whichever is later; and
2)
For continuously generated waste, annually; or
331
3)
Whenever there is a change in the waste being managed or a
change in the process that generates or treats the waste.
f)
When an owner or operator and the Agency do not agree on whether a
distillation, fractionation, thin-film evaporation, solvent extraction, or
air or steam stripping operation manages a hazardous waste with organic
concentrations of at least 10 ppmw based on knowledge of the waste, the
procedures in Method 8240 in SW-846, incorporated by reference in 35
Ill. Adm. Code 720.111, must be used to resolve the dispute.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 725.935
Recordkeeping Requirements
a)
Compliance Required.
1)
Each owner or operator subject to the provisions of this Subpart
shall comply with the recordkeeping requirements of this Section.
2)
An owner or operator of more than one hazardous waste
management unit subject to the provisions of this Subpart may
comply with the recordkeeping requirements for these hazardous
waste management units in one recordkeeping system if the
system identifies each record by each hazardous waste
management unit.
b)
Owners and operators shall record the following information in the
facility operating record:
1)
For facilities that comply with the provisions of Section
725.933(a)(2), an implementation schedule that includes dates by
which the closed-vent system and control device will be installed
and in operation. The schedule must also include a rationale of
why the installation cannot be completed at an earlier date. The
implementation schedule must be in the facility operating record
by the effective date that the facility becomes subject to the
provisions of this Subpart.
2)
Up-to-date documentation of compliance with the process vent
standards in Section 725.932, including:
A)
Information and data identifying all affected process
vents, annual throughput and operating hours of each
affected unit, estimated emission rates for each affected
vent and for the overall facility (i.e., the total emissions
332
for all affected vents at the facility), and the approximate
location within the facility of each affected unit (e.g.,
identify the hazardous waste management units on a
facility plot plan).
B)
Information and data supporting determination of vent
emissions and emission reductions achieved by add-on
control devices based on engineering calculations or
source tests. For the purpose of determining compliance,
determinations of vent emissions and emission reductions
must be made using operating parameter values (e.g.,
temperatures, flow rates, or vent stream organic
compounds and concentrations) that represent the
conditions that result in maximum organic emissions, such
as when the waste management unit is operating at the
highest load or capacity level reasonably expected to
occur. If the owner or operator takes any action (e.g.,
managing a waste of different composition or increasing
operating hours of affected waste management units) that
would result in an increase in total organic emissions from
affected process vents at the facility, then a new
determination is required.
3)
Where an owner or operator chooses to use test date to determine
the organic removal efficiency or total organic compound
concentration achieved by the control device, a performance test
plan. The test plan must include:
A)
A description of how it is determined that the planned test
is going to be conducted when the hazardous waste
management unit is operating at the highest load or
capacity level reasonably expected to occur. This must
include the estimated or design flow rate and organic
content of each vent stream and define the acceptable
operating ranges of key process and control device
parameters during the test program.
B)
A detailed engineering description of the closed-vent
system and control device including:
i)
Manufacturer’s name and model number of control
device.
ii)
Type of control device.
333
iii)
Dimensions of the control device.
iv)
Capacity.
v)
Construction materials.
C)
A detailed description of sampling and monitoring
procedures, including sampling and monitoring locations
in the system, the equipment to be used, sampling and
monitoring frequency, and planned analytical procedures
for sample analysis.
4)
Documentation of compliance with Section 725.933 must include
the following information:
A)
A list of all information references and sources used in
preparing the documentation.
B)
Records, including the dates of each compliance test
required by Section 725.933(j).
C)
If engineering calculations are used, a design analysis,
specifications, drawings, schematics, and piping and
instrumentation diagrams based on the appropriate
sections of APTI Course 415 (incorporated by reference
in 35 Ill. Adm. Code 720.111) or other engineering texts,
approved by the Agency, that present basic control device
design information. Documentation provided by the
control device manufacturer or vendor that describes the
control device design in accordance with subsections
(b)(4)(C)(i) through (vii), belowof this Section, may be
used to comply with this requirement. The design
analysis must address the vent stream characteristics and
control device operation parameters as specified below.
i)
For a thermal vapor incinerator, the design
analysis must consider the vent stream
composition, constituent concentrations and flow
rate. The design analysis must also establish the
design minimum and average temperature in the
combustion zone and the combustion zone
residence time.
ii)
For a catalytic vapor incinerator, the design
analysis must consider the vent stream
334
composition, constituent concentrations, and flow
rate. The design analysis must also establish the
design minimum and average temperatures across
the catalyst bed inlet and outlet.
iii)
For a boiler or process heater, the design analysis
must consider the vent stream composition,
constituent concentrations and flow rate. The
design analysis must also establish the design
minimum and average flame zone temperatures,
combustion zone residence time and description of
method and location where the vent stream is
introduced into the combustion zone.
iv)
For a flare, the design analysis must consider the
vent stream composition, constituent
concentrations, and flow rate. The design analysis
must also consider the requirements specified in
Section 725.933(d).
v)
For a condenser, the design analysis must consider
the vent stream composition, constituent
concentrations, flow rate, relative humidity and
temperature. The design analysis must also
establish the design outlet organic compound
concentration level, design average temperature of
the condenser exhaust vent stream and design
average temperatures of the coolant fluid at the
condenser inlet and outlet.
vi)
For a carbon adsorption system such as a fixed-bed
adsorber that regenerates the carbon bed directly
onsite in the control device, the design analysis
must consider the vent stream composition,
constituent concentrations, flow rate, relative
humidity and temperature. The design analysis
must also establish the design exhaust vent stream
organic compound concentration level, number and
capacity of carbon beds, type and working capacity
of activated carbon used for carbon beds, design
total steam flow over the period of each complete
carbon bed regeneration cycle, duration of the
carbon bed steaming and cooling/drying cycles,
design carbon bed temperature after regeneration,
335
design carbon bed regeneration time and design
service life of carbon.
vii)
For a carbon adsorption system such as a carbon
canister that does not regenerate the carbon bed
directly onsite in the control device, the design
analysis must consider the vent stream
composition, constituent concentrations, flow rate,
relative humidity and temperature. The design
analysis must also establish the design outlet
organic concentration level, capacity of carbon
bed, type and working capacity of activated carbon
used for carbon bed and design carbon replacement
interval based on the total carbon working capacity
of the control device and source operating
schedule.
D)
A statement signed and dated by the owner or operator
certifying that the operating parameters used in the design
analysis reasonably represent the conditions that exist
when the hazardous waste management unit is or would
be operating at the highest load or capacity level
reasonably expected to occur.
E)
A statement signed and dated by the owner or operator
certifying that the control device is designed to operate at
an efficiency of 95 percent% or greater unless the total
organic concentration limit of Section 725.932(a) is
achieved at an efficiency less than 95 weight percent or
the total organic emission limits of Section 725.932(a) for
affected process vents at the facility are attained by a
control device involving vapor recovery at an efficiency
less than 95 weight percent. A statement provided by the
control device manufacturer or vendor certifying that the
control equipment meets the design specifications may be
used to comply with this requirement.
F)
If performance tests are used to demonstrate compliance,
all test results.
c)
Design documentation and monitoring operating and inspection
information for each closed-vent system and control device required to
comply with the provisions of this Part must be recorded and kept up-to-
date in the facility operating record. The information must include:
336
1)
Description and date of each modification that is made to the
closed-vent system or control device design.
2)
Identification of operating parameter, description of monitoring
device, and diagram of monitoring sensor location or locations
used to comply with Section 725.933(f)(1) and (2).
3)
Monitoring, operating and inspection information required by
Section 725.933(f) through (k).
4)
Date, time and duration of each period that occurs while the
control device is operating when any monitored parameter
exceeds the value established in the control device design analysis
as specified below:
A)
For a thermal vapor incinerator designed to operate with a
minimum residence time of 0.50 second at a minimum
temperature of 760
°
C, any period when the combustion
temperature is below 760
°
C.
B)
For a thermal vapor incinerator designed to operate with
an organic emission reduction efficiency of 95 percent%
or greater, any period when the combustion zone
temperature is more than 28° C below the design average
combustion zone temperature established as a requirement
of subsection (b)(4)(C)(i), aboveof this Section.
C)
For a catalytic vapor incinerator, any period when:
i)
Temperature of the vent stream at the catalyst bed
inlet is more than 28° C below the average
temperature of the inlet vent stream established as
a requirement of subsection (b)(4)(C)(ii), aboveof
this Section; or
ii)
Temperature difference across the catalyst bed is
less than 80 percent% of the design average
temperature difference established as a requirement
of subsection (b)(4)(C)(ii), aboveof this Section.
D)
For a boiler or process heater, any period when:
i)
Flame zone temperature is more than 28° C below
the design average flame zone temperature
337
established as a requirement of subsection
(b)(4)(C)(iii), aboveof this Section; or
ii)
Position changes where the vent stream is
introduced to the combustion zone from the
location established as a requirement of subsection
(b)(4)(C)(iii), aboveof this Section.
E)
For a flare, period when the pilot flame is not ignited.
F)
For a condenser that complies with Section
725.933(f)(2)(F)(i), any period when the organic
compound concentration level or readings of organic
compounds in the exhaust vent stream from the condenser
are more than 20 percent% greater than the design outlet
organic compound concentration level established as a
requirement of subsection (b)(4)(C)(v), aboveof this
Section.
G)
For a condenser that complies with Section
725.933(f)(2)(F)(ii), any period when:
i)
Temperature of the exhaust vent stream from the
condenser is more than 6° C above the design
average exhaust vent stream temperature
established as a requirement of subsection
(b)(4)(C)(v), aboveof this Section.
ii)
Temperature of the coolant fluid exiting the
condenser is more than 6° C above the design
average coolant fluid temperature at the condenser
outlet established as a requirement of subsection
(b)(4)(C)(v), aboveof this Section.
H)
For a carbon adsorption system such as a fixed-bed carbon
adsorber that regenerates the carbon bed directly onsite in
the control device and complies with Section
725.933(f)(2)(G)(i), any period when the organic
compound concentration level or readings of organic
compounds in the exhaust vent stream from the carbon
bed are more than 20 percent% greater than the design
exhaust vent stream organic compound concentration level
established as a requirement of subsection (b)(4)(C)(vi),
aboveof this Section.
338
I)
For a carbon adsorption system such as a fixed-bed carbon
adsorber that regenerates the carbon bed directly onsite in
the control device and complies with Section
725.933(f)(2)(G)(ii), any period when the vent stream
continues to flow through the control device beyond the
predetermined carbon bed regeneration time established as
a requirement of subsection (b)(4)(C)(vi), aboveof this
Section.
5)
Explanation for each period recorded under subsection (c)(4),
above,of this Section of the cause for control device operating
parameter exceeding the design value and the measures
implemented to correct the control device operation.
6)
For carbon adsorption systems operated subject to requirements
specified in Section 725.933(g) or (h)(2), any date when existing
carbon in the control device is replaced with fresh carbon.
7)
For carbon adsorption systems operated subject to requirements
specified in Section 725.933(h)(1), a log that records:
A)
Date and time when control device is monitored for
carbon breakthrough and the monitoring device reading.
B)
Date when existing carbon in the control device is
replaced with fresh carbon.
8)
Date of each control device startup and shutdown.
9)
An owner or operator designating any components of a closed-
vent system as unsafe to monitor pursuant to Section 725.933(n)
shall record in a log that is kept in the facility operating record
the identification of closed-vent system components that are
designated as unsafe to monitor in accordance with the
requirements of Section 725.933(n), an explanation for each
closed-vent system component stating why the closed-vent system
component is unsafe to monitor, and the plan for monitoring each
closed-vent system component.
10)
When each leak is detected as specified in Section 725.933(k),
the following information must be recorded:
A)
The instrument identification number, the closed-vent
system component identification number, and the operator
name, initials, or identification number.
339
B)
The date the leak was detected and the date of first
attempt to repair the leak.
C)
The date of successful repair of the leak.
D)
Maximum instrument reading measured by Method 21 of
40 CFR 60, appendix A, incorporated by reference in 35
Ill. Adm. Code 720.111, after it is successfully repaired
or determined to be nonrepairable.
E)
“Repair delayed” and the reason for the delay if a leak is
not repaired within 15 calendar days after discovery of the
leak.
i)
The owner or operator may develop a written
procedure that identifies the conditions that justify
a delay of repair. In such cases, reasons for delay
of repair may be documented by citing the relevant
sections of the written procedure.
ii)
If delay of repair was caused by depletion of
stocked parts, there must be documentation that the
spare parts were sufficiently stocked on-site before
depletion and the reason for depletion.
d)
Records of the monitoring, operating and inspection information
required by subsections (c)(3) through (810), aboveof this Section, need
be kept only 3must be maintained by the owner or operator for at least
three years following the date of each occurrence, measurement,
corrective action, or record.
e)
For a control device other than a thermal vapor incinerator, catalytic
vapor incinerator, flare, boiler, process heater, condenser or carbon
adsorption system, monitoring and inspection information indicating
proper operation and maintenance of the control device must be recorded
in the facility operating record.
f)
Up-to-date information and data used to determine whether or not a
process vent is subject to the requirements in Section 725.932, including
supporting documentation as required by Section 725.934(d)(2), when
application of the knowledge of the nature of the hazardous wastestream
or the process by which it was produced is used, must be recorded in a
log that is kept in the facility operating record.
340
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
SUBPART BB: AIR EMISSION STANDARDS FOR EQUIPMENT
LEAKS
Section 725.950
Applicability
a)
The regulations in this Subpart apply to owners and operators of
facilities that treat, store, or dispose of hazardous wastes (except as
provided in Section 725.101).
b)
Except as provided in Section 725.964(jk), this Subpart applies to
equipment that contains or contacts hazardous wastes with organic
concentrations of at least 10 percent% by weight that are managed in one
of the following:
1)
UA units that areis subject to the RCRA permitting requirements
of 35 Ill. Adm. Code 702, 703, and 705, or;
2)
HA unit (including a hazardous waste recycling units) that areis
not exempt from permitting under the provisions of 35 Ill. Adm.
Code 722.134(a) (i.e., a hazardous waste recycling unit that is
not a “90-day” tank or container) and that is located onat a
hazardous waste management facilitiesy otherwise subject to the
permitting requirements of 35 Ill. Adm. Code 702, 703, and
705.; or
3)
A unit that is exempt from permitting under the provisions of 35
Ill. Adm. Code 722.134(a) (i.e., a “90-day” tank or container).
c)
Each piece of equipment to which this Subpart applies must be marked
in such a manner that it can be distinguished readily from other pieces of
equipment.
d)
Equipment that is in vacuum service is excluded from the requirements
of Sections 725.952 to 725.960, if it is identified as required in Section
725.964(g)(5).
e)
Equipment that contains or contacts hazardous waste with an organic
concentration of at least 10% by weight for a period of less than 300
hours per calendar year is excluded from the requirements of Sections
265.952 through 265.960 if it is identified as required in Section
725.964(g)(6).
341
BOARD NOTE: The requirements of Sections 725.952 through
725.964 apply to equipment associated with hazardous waste recycling
units previously exempt under 35 Ill. Adm. Code 721.106(c)(1). Other
exemptions under 35 Ill. Adm. Code 721.104, 722.134 and 725.101(e)
are not affected by these requirements.
ef)
Agency decisions pursuant to this Part must be made in writing, are in
the nature of permit decisions pursuant to Section 39 of the
Environmental Protection Act and may be appealed to the Board
pursuant to 35 Ill. Adm. Code 105.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 725.955
Standards: Sampling Connecting Systems
a)
Each sampling connection system must be equipped with a closed-purge,
closed-loop, system or closed-vent system. This system must collect the
sample purge for return to the process or for routing to the appropriate
treatment system. Gases displaced during filling of the sample container
are not required to be collected or captured.
b)
Each closed-purge, closed-loop, system or closed-vent system as
required in subsection (a) of this Section must meet one of the following
requirements:
1)
Return the purged hazardous waste streamprocess fluid directly to
the hazardous waste management process line with no detectable
emissions to atmosphere; or
2)
Collect and recycle the purged hazardous waste stream with no
detectable emissions to atmosphereprocess fluid; or
3)
Be designed and operated to capture and transport all the purged
hazardous wastestreamprocess fluid to a waste management unit
that complies with the applicable requirements of Sections
725.985 through 725.987 or a control device that complies with
the requirements of Section 725.960.
c)
In-situ sampling systems and sampling systems without purges are
exempt from the requirements of subsections (a) and (b) of this Section.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 725.958
Standards: Pumps, Valves, Pressure Relief Devices, Flanges and
other Connectors
342
a)
Pumps and valves in heavy liquid service, pressure relief devices in light
liquid or heavy liquid service and flanges and other connectors must be
monitored within 5 days by the method specified in Section 725.963(b),
if evidence of a potential leak is found by visual, audible, olfactory, or
any other detection method.
b)
If an instrument reading of 10,000 ppm or greater is measured, a leak is
detected.
c)
Repairs
1)
When a leak is detected, it must be repaired as soon as
practicable, but not later than 15 calendar days after it is
detected, except as provided in Section 725.959.
2)
The first attempt at repair must be made no later than 5five
calendar days after each leak is detected.
d)
First attempts at repair include, but are not limited to, the best practices
described under Section 725.957(e).
e)
Any connector that is inaccessible or is ceramic or ceramic-lined (e.g.,
porcelain, glass, or glass-lined) is exempt from the monitoring
requirements of subsection (a) of this Section and from the
recordkeeping requirements of Section 725.964.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 725.964
Recordkeeping Requirements
a)
Lumping Units
1)
Each owner or operator subject to the provisions of this Subpart
shall comply with the recordkeeping requirements of this Section.
2)
An owner or operator of more than one hazardous waste
management unit subject to the provisions of this Subpart may
comply with the recordkeeping requirements for these hazardous
waste management units in one recordkeeping system if the
system identifies each record by each hazardous waste
management unit.
b)
Owners and operators shall record the following information in the
facility operating record:
343
1)
For each piece of equipment to which this Subpart applies:
A)
Equipment identification number and hazardous waste
management unit identification.
B)
Approximate locations within the facility (e.g., identify
the hazardous waste management unit on a facility plot
plan).
C)
Type of equipment (e.g., a pump or pipeline valve).
D)
Percent-by-weight total organics in the hazardous
wastestream at the equipment.
E)
Hazardous waste state at the equipment (e.g. gas/vapor or
liquid).
F)
Method of compliance with the standard (e.g. “monthly
leak detection and repair” or “equipped with dual
mechanical seals”).
2)
fFor facilities than than comply with the provisions of Section
725.933(a)(2), an implementation schedule as specified in that
Section.
3)
Where an owner or operator chooses to use test data to
demonstrate the organic removal efficiency or total organic
compound concentration achieved by the control device, a
performance test plan as specified in Section 725.935(b)(3).
4)
Documentation of compliance with Section 725.960, including
the detailed design documentation or performance test results
specified in Section 725.935(b)(4).
c)
When each leak is detected as specified in Sections 725.952, 725.953,
725.957 or 725.958, the following requirements apply:
1)
A weatherproof and readily visible identification, marked with
the equipment identification number, the date evidence of a
potential leak was found in accordance with Section 725.958(a),
and the date the leak was detected, must be attached to the
leaking equipment.
344
2)
The identification on equipment except on a valve, may be
removed after it has been repaired.
3)
The identification on a valve may be removed after it has been
monitored for 2 successive months as specified in Section
725.957(c) and no leak has been detected during those 2 months.
d)
When each leak is detected as specified in Sections 725.952, 725.953,
725.957 or 725.958, the following information must be recorded in an
inspection log and must be kept in the facility operating record:
1)
The instrument and operator identification numbers and the
equipment identification number.
2)
The date evidence of a potential leak was found in accordance
with Section 725.958(a).
3)
The date the leak was detected and the dates of each attempt to
repair the leak.
4)
Repair methods applied in each attempt to repair the leak.
5)
“Above 10,000”, if the maximum instrument reading measured
by the methods specified in Section 725.963(b) after each repair
attempt is equal to or greater than 10,000 ppm.
6)
“Repair delayed” and the reason for the delay if a leak is not
repaired within 15 calendar days after discovery of the leak.
7)
Documentation supporting the delay of repair of a valve in
compliance with Section 725.959(c).
8)
The signature of the owner or operator (or designate) whose
decision it was that repair could not be effected without a
hazardous waste management unit shutdown.
9)
The expected date of successful repair of the leak if a leak is not
repaired within 15 calendar days.
10)
The date of successful repair of the leak.
e)
Design documentation and monitoring, operating and inspection
information for each closed-vent system and control device required to
comply with the provisions of Section 725.960 must be recorded and
kept up-to-date in the facility operating record as specified in Section
345
725.935(c)(1) and (c)(2), and monitoring, operating and inspection
information in Section 725.935(c)(3) through (c)(8).
f)
For a control device other than a thermal vapor incinerator, catalytic
vapor incinerator, flare, boiler, process heater, condenser, or carbon
adsorption system, monitoring and inspection information indicating
proper operation and maintenance of the control device must be recorded
in the facility operating record.
g)
The following information pertaining to all equipment subject to the
requirements in Sections 725.952 through 725.960 must be recorded in a
log that is kept in the facility operating record:
1)
A list of identification numbers for equipment (except welded
fittings) subject to the requirements of this Subpart.
2)
List of Equipment
A)
A list of identification numbers for equipment that the
owner or operator elects to designate for no detectable
emissions, as indicated by an instrument reading of less
than 500 ppm above background, under the provisions of
Sections 725.952(e), 725.953(i) and 725.957(f).
B)
The designation of this equipment as subject to the
requirements of Sections 725.952(e), 725.953(i) or
725.957(f) must be signed by the owner or operator.
3)
A list of equipment identification numbers for pressure relief
devices required to comply with Section 725.954(a).
4)
Compliance tests.
A)
The dates of each compliance test required in Sections
725.952(e), 725.953(i), 725.954, and 725.957(f).
B)
The background level measured during each compliance
test.
C)
The maximum instrument reading measured at the
equipment during each compliance test.
5)
A list of identification numbers for equipment in vacuum service.
346
6)
Identification, either by list or location (area or group) of
equipment that contains or contacts hazardous waste with an
organic concentration of at least 10% by weight for a period of
less than 300 hours per year.
h)
The following information pertaining to all valves subject to the
requirements of Section 725.957(g) and (h) must be recorded in a log
that is kept in the facility operating record:
1)
A list of identification numbers for valves that are designated as
unsafe to monitor, an explanation for each valve stating why the
valve is unsafe to monitor, and the plan for monitoring each
valve.
2)
A list of identification numbers for valves that are designated as
difficult to monitor, an explanation for each valve stating why the
valve is difficult to monitor, and the planned schedule for
monitoring each valve.
i)
The following information must be recorded in the facility operating
record for valves complying with Section 725.962:
1)
A schedule of monitoring.
2)
The percent of valves found leaking during each monitoring
period.
j)
The following information must be recorded in a log that is kept in the
facility operating record:
1)
Criteria required in Section 725.952(d)(5)(B) and 725.953(e)(2)
and an explanation of the criteria.
2)
Any changes to these criteria and the reasons for the changes.
k)
The following information must be recorded in a log that is kept in the
facility operating record for use in determining exemptions as provided
in Section 725.950 and other specific Subparts:
1)
An analysis determining the design capacity of the hazardous
waste management unit.
2)
A statement listing the hazardous waste influent to and effluent
from each hazardous waste management unit subject to the
347
requirements in Sections 725.960 and an analysis determining
whether these hazardous wastes are heavy liquids.
3)
An up-to-date analysis and the supporting information and data
used to determine whether or not equipment is subject to the
requirements in Sections 725.952 through 725.960. The record
must include supporting documentation as required by Section
725.963(d)(3) when application of the knowledge of the nature of
the hazardous wastestream or the process by which it was
produced is used. If the owner or operator takes any action
(e.g., changing the process that produced the waste) that could
result in an increase in the total organic content of the waste
contained in or contacted by equipment determined not to be
subject to the requirements in Sections 725.952 through 725.960,
then a new determination is required.
l)
Records of the equipment leak information required by subsection (d) of
this Section and the operating information required by subsection (e) of
this Section need be kept only 3three years.
m)
The owner or operator of any facility that is subject to this Subpart and
to regulations at 40 CFR 60, Subpart VV, or 40 CFR 61, Subpart V,
incorporated by reference in 35 Ill. Adm. Code 720.111, may elect to
determine compliance with this Subpart by documentation either
pursuant to Section 725.964, or pursuant to those provisions of 40 CFR
60 or 61, to the extent that the documentation under the regulation at 40
CFR 60 or 61 duplicates the documentation required under this Subpart.
The documentation under the regulation at 40 CFR 60 or 61 must be
kept with or made readily available with the facility operating record.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
SUBPART CC: AIR EMISSION STANDARDS FOR TANKS,
SURFACE IMPOUNDMENTS, AND CONTAINERS
Section 725.980
Applicability
a)
The requirements of this Subpart apply, effective October 6, 1996, to
owners and operators of all facilities that treat, store, or dispose of
hazardous waste in tanks, surface impoundments, or containers that are
subject to 725.Subpart I, J, or K, except as Section 725.101 and
subsection (b) belowof this Section provide otherwise.
348
BOARD NOTE: USEPA adopted these regulations at 59 Fed. Reg.
62896 (Dec. 6, 1994), effective June 6, 1995. At 60 Fed. Reg. 26828
(May 19, 1995), 60 Fed. Reg. 56952 (Nov. 13, 1995), and 61 Fed.
Reg. 28508 (June 5, 1996), USEPA delayed the effective date until
October 6, 1996. If action by USEPA or a decision of a federal court
changes the effectiveness of these regulations, the Board does not intend
that 725.Subpart CC be enforceable to the extent that it becomes more
stringent that the federal regulations upon which they are based.
b)
The requirements of this Subpart do not apply to the following waste
management units at the facility:
1)
A waste management unit that holds hazardous waste placed in
the unit before October 6, 1996 and in which no hazardous waste
is added to the unit on or after this date.
2)
A container that has a design capacity less than or equal to 0.1 m
3
(3.5 ft
3
or 26.4 gal).
3)
A tank in which an owner or operator has stopped adding
hazardous waste and the owner or operator has begun
implementing or completed closure pursuant to an approved
closure plan.
4)
A surface impoundment in which an owner or operator has
stopped adding hazardous waste (except to implement an
approved closure plan) and the owner or operator has begun
implementing or completed closure pursuant to an approved
closure plan.
5)
A waste management unit that is used solely for on-site treatment
or storage of hazardous waste that is generated as the result of
implementing remedial activities required pursuant to the Act or
Board regulations or under the corrective action authorities of
RCRA sections 3004(u), 3004(v) or 3008(h); CERCLA
authorities; or similar federal or state authorities.
6)
A waste management unit that is used solely for the management
of radioactive mixed waste in accordance with all applicable
regulations under the authority of the Atomic Energy Act (42
U.S.C. 2011 et seq.) and the Nuclear Waste Policy Act.
7)
A hazardous waste management unit that the owner or operator
certifies is equipped with and operating air emission controls in
accordance with the requirements of an applicable federal Clean
349
Air Act regulation codified under 40 CFR 60, 61, or 63. For the
purpose of complying with this subsection (b)(7), a tank for
which the air emission control includes an enclosure, as opposed
to a cover, must be in compliance with the enclosure and control
device requirements of Section 725.985(i), except as provided in
Section 725.983(c)(5).
8)
A tank that has a process vent, as defined in 35 Ill. Adm. Code
725.931.
c)
For the owner and operator of a facility subject to this Subpart whothat
has received a final RCRA permit prior to October 6, 1996, the
following requirements apply:
1)
The requirements of 35 Ill. Adm. Code 724.Subpart CC must be
incorporated into the permit when the permit is reissued,
renewed, or modified in accordance with the requirements of 35
Ill. Adm. Code 703 and 705.
2)
Until the date when the permit is reissued, renewed, or modified
in accordance with the requirements of 35 Ill. Adm. Code 703
and 705, the owner and operator is subject to the requirements of
this Subpart.
d)
The requirements of this Subpart, except for the recordkeeping
requirements specified in Section 725.990(i), are stayed for a tank or
container used for the management of hazardous waste generated by
organic peroxide manufacturing and its associated laboratory operations,
when the owner or operator of the unit meets all of the following
conditions:
1)
The owner or operator identifies that the tank or container
receives hazardous waste generated by an organic peroxide
manufacturing process producing more than one functional family
of organic peroxides or multiple organic peroxides within one
functional family, that one or more of these organic peroxides
could potentially undergo self-accelerating thermal decomposition
at or below ambient temperatures, and that organic peroxides are
the predominant products manufactured by the process. For the
purposes of this subsection, “organic peroxide” means an organic
compound that contains the bivalent -O-O- structure and which
may be considered to be a sturctural structural derivative of
hydrogen peroxide where one or both of the hydrogen atoms has
been replaced by an organic radical.
350
2)
The owner or operator prepares documentation, in accordance
with Section 725.990(i), explaining why an undue safety hazard
would be created if air emission controls specified in Sections
725.985 through 725.988 are installed and operated on the tanks
and containers used at the facility to manage the hazardous waste
generated by the organic peroxide manufacturing process or
processes meeting the conditions of subsection (d)(1) aboveof this
Section.
3)
The owner or operator notifies the Agency in writing that
hazardous waste generated by an organic peroxide manufacturing
process or processes meeting the conditions of subsection (d)(1)
aboveof this Section are managed at the facility in tanks or
containers meeting the conditions of subsection (d)(2) aboveof
this Section. The notification must state the name and address of
the facility and be signed and dated by an authorized
representative of the facility owner or operator.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 725.981
Definitions
As used in this Subpart and in 35 Ill. Adm. Code 724, all terms not defined herein
shall have the meaning given to them in the Act and 35 Ill. Adm. Code 720 through
726.
“Average volatile organic concentration” or “average VO concentration”
means the mass-weighted average volatile organic concentration of a
hazardous waste, as determined in accordance with the requirements of
Section 725.984.
“Closure device” means a cap, hatch, lid, plug, seal, valve, or other
type of fitting that blocks an opening in a cover so that when the device
is secured in the closed position it prevents or reduces air pollutant
emissions to the atmosphere. Closure devices include devices that are
detachable from the cover (e.g., a sampling port cap), manually operated
(e.g., a hinged access lid or hatch), or automatically operated (e.g., a
spring-loaded pressure relief valve).
“Continuous seal” means a seal that forms a continuous closure that
completely covers the space between the edge of the floating roof and
the wall of a tank. A continuous seal may be a vapor-mounted seal,
liquid-mounted seal, or metallic shoe seal. A continuous seal may be
constructed of fastened segments so as to form a continuous seal.
351
“Cover” means a device or system that is placed on orprovides a
continuous barrier over athe hazardous waste such that the entire
hazardous waste surface area is enclosed and sealedmanaged in a unit to
prevent or reduce air emissions to the atmosphere. A cover may have
openings (such as access hatches, sampling ports, and gauge wells) that
are necessary for operation, inspection, maintenance, or repair of the
unit on which the cover is installed provided that each opening is closed
and sealed when not in used. Examples of covers include a fixed roof
installed on a tank, a floating membrane cover installed on a surface
impoundment, a lid installed on a drum, or an enclosure in which an
open container is placed during waste treatment.A cover may be a
separate piece of equipment which can be detached and removed from
the unit or a cover may be formed by structural features permanently
integrated into the design of the unit.
“Enclosure” means a structure that surrounds a tank or container,
captures organic vapors emitted from the tank or container, and vents the
captured vapors through a closed-vent system to a control device.
“External floating roof” means a pontoon-type or double-deck type
floating roofcover that rests on the surface of a hazardous waste being
managed in a tank that haswith no fixed roof.
“Fixed roof” means a rigid cover that is installedmounted on a unit in a
stationary position so that itand does not move with fluctuations in the
level of the hazardous waste placedmaterial managed in a tankthe unit.
“Floating membrane cover” means a cover consisting of a synthetic
flexible membrane material that rests upon and is supported by the
hazardous waste being managed in a surface impoundment.
“Floating roof” means a pontoon-type or double-deck-typecover
consisting of a double-deck, pontoon single-deck, or internal floating
cover that rests upon and is supported by the hazardous wastematerial
being managed in a tankcontained, and is equipped with a
closurecontinuous seal or seals to close the space between the cover edge
and the tank wall.
“Hard-piping” means pipe or tubing that is manufactured and properly
installed in accordance with relevant standards and good engineering
practices.
“In light material service” means the container is used to manage a
material for which both of the following conditions apply: the vapor
pressure of one or more of the organic constituents in the material is
352
greater than 0.3 kilopascals (kPa) at 20°C (1.2 inches H
2
O at 68°F); and
the total concentration of the pure organic constituents having a vapor
pressure greater than 0.3 kPa at 20°C (1.2 inches H
2
O at 68°F) is equal
to or greater than 20% by weight.
“Internal floating roof” means a floating roofcover that rests or floats on
the material surface (but not necessarily in complete contact with it) of a
hazardous waste being managed inside a tank that has a fixed roof.
“Liquid-mounted seal” means a foam or liquid-filled primary seal
mounted in contact with the hazardous waste between the tank wall and
the floating roof, continuously around the circumference of the tank.
“Malfunction” means any sudden, infrequent, and not reasonably
preventable failure of air pollution control equipment, process
equipment, or a process to operate in a normal or usual manner. A
failure that is caused in part by poor maintenance or careless operation is
not a malfunction.
“Maximum organic vapor pressure” means the equilibrium partial
pressure exerted by the hazardous waste contained in a tank, determined
at the temperature equal to either:
The local maximum monthly average temperature as reported by
the National Weather Service, when the hazardous waste is stored
or treated at ambient temperature, or
The highest calendar-month average temperature of the hazardous
waste, when the hazardous waste is stored at temperatures above
the ambient temperature or when the hazardous waste is stored or
treated at temperatures below the ambient temperature.
“Maximum organic vapor pressure” means the sum of the individual
organic constituent partial pressures exerted by the material contained in
a tank at the maximum vapor pressure-causing conditions (i.e.,
temperature, agitation, pH effects of combining wastes, etc.) reasonably
expected to occur in the tank. For the purpose of this Subpart,
maximum organic vapor pressure is determined using the procedures
specified in Section 725.984(c).
“Metallic shoe seal” means a continuous seal that is constructed of metal
sheets that are held vertically against the wall of the tank by springs,
weighted levers, or other mechanisms and which is connected to the
floating roof by braces or other means. A flexible coated fabric
353
(envelope) spans the annular space between the metal sheet and the
floating roof.
“No detectable organic emissions” means no escape of organics from a
device or system to the atmosphere, as determined: using the procedure
specified in Section 725.984(d).
By an instrument reading less than 500 parts per million by
volume (ppmv) above the background level at each joint, fitting,
and seal, when measured in accordance with the requirements of
Method 21 in 40 CFR 60, Appendix A, and
By no visible openings or defects in the device or system such as
rips, tears, or gaps.
“Point of waste origination” means as follows:
When the facility owner or operator is the generator of the
hazardous waste, the “point of waste origination” means the
point where a solid waste produced by a system, process, or
waste management unit is determined to be a hazardous waste, as
defined in 35 Ill. Adm. Code 721.
BOARD NOTE: In this case, this term is being used in a manner
similar to the use of the term “point of generation” in air
standards established for waste management operations under
authority of the federal Clean Air Act in 40 CFR 60, 61, and 63.
When the facility owner and operator are not the generator of the
hazardous waste, “point of waste origination” means the point
where the owner or operator accepts delivery or takes possession
of the hazardous waste.
“Point of waste treatment” means the point where a hazardous waste to
be treated in accordance with Section 725.983(c)(2) exits a waste
management unit used to destroy, degrade, or remove organics in the
hazardous waste the treatment process. Any waste determination must
be made before the waste is conveyed, handled, or otherwise managed in
a manner that allows the waste to volatilize to the atmosphere.
“Safety device” means a closure device, such as a pressure relief valve,
frangible disc, fusible plug, or any other type of device, which functions
exclusively to prevent physical damage or permanent deformation to a
unit or its air emission control equipment by venting gases or vapors
directly to the atmosphere during unsafe conditions resulting from an
354
unplanned, accidental, or emergency event. For the purpose of this
Subpart, a safety device is not used for routine venting of gases or
vapors from the vapor headspace underneath a cover such as during
filling of the unit or to adjust the pressure in this vapor headspace in
response to normal daily diurnal ambient temperature fluctuations. A
safety device is designed to remain in a closed position during normal
operations and open only when the internal pressure, or another relevant
parameter, exceeds the device threshold setting applicable to the air
emission control equipment as determined by the owner or operator
based on manufacturer recommendations, applicable regulations, fire
protection and prevention codes, standard engineering codes and
practices, or other requirements for the safe handling of flammable,
ignitable, explosive, reactive, or hazardous materials.
“Single-seal system” means a floating roof having one continuous seal.
This seal may be vapor-mounted, liquid-mounted, or a metallic shoe
seal.
“Vapor-mounted seal” means a foam-filled primary seal mounted
continuously around the circumference of the tank so that there is an
annular seal that is mounted so that there is a vapor space
underneathbetween the hazardous waste in the unit and the bottom of the
seal. The annular vapor space is bounded by the bottom of the primary
seal, the tank wall, the hazardous waste surface, and the floating roof.
“Volatile organic concentration” or “VO concentration” means the
fraction by weight of organic compounds contained in a hazardous waste
expressed in terms of parts per million (ppmw), as determined by direct
measurement, using Method 25D, or by knowledge of the waste, in
accordance with the requirements of Section 725.984. For the purpose
of determining the VO concentration of a hazardous waste, organic
compounds with a Henry’s law constant value of at least 0.1 mole-
fraction-in-the-gas-phase/mole-fraction-in the liquid-phase (0.1 Y/X)
(which can also be expressed as 1.8
×
10
-6
atmospheres/gram-mole/m
3
) at
25° C (77° F) must be included. Section 725.Appendix F presents a list
of compounds known to have a Henry’s law constant value less than the
cutoff level.
“Waste determination” means performing all applicable procedures in
accordance with the requirements of Section 725.984 to determine
whether a hazardous waste meets standards specified in this Subpart.
Examples of a waste determination include performing the procedures in
accordance with the requirements of Section 725.984 to determine the
average VO concentration of a hazardous waste at the point of waste
355
origination, determining the average VO concentration of a hazardous
waste at the point of waste treatment and comparing the results to the
exit concentration limit specified for the process used to treat the
hazardous waste, determining the organic reduction efficiency and the
organic biodegradation efficiency for a biological process used to treat a
hazardous waste and comparing the results to the applicable standards, or
determining the maximum volatile organic vapor pressure for a
hazardous waste in a tank and comparing the results to the applicable
standards.
“Waste stabilization process” means any physical or chemical process
used to either reduce the mobility of hazardous constituents in a
hazardous waste or eliminate free liquids as determined by Test Method
9095 (Paint Filter Liquids Test) in “Test Methods for Evaluating Solid
Waste, Physical/Chemical Methods”, incorporated by reference in
Section 720.111. A waste stabilization process includes mixing the
hazardous waste with binders or other materials and curing the resulting
hazardous waste and binder mixture. Other synonymous terms used to
refer to this process are “waste fixation” or “waste solidification”. This
does not include the addition of absorbent materials to the surface of a
waste to absorb free liquid without mixing, agitation, or subsequent
curing.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 725.983
Standards: General
a)
This Section applies to the management of hazardous waste in tanks,
surface impoundments, and containers subject to this Subpart.
b)
The owner or operator shall control air emissions from each waste
management unit in accordance with standards specified in Sections
725.985 through Section 725.988, as applicable to the waste
management unit, except as provided for in subsection (c) belowof this
Section.
c)
A waste management unittank, surface impoundment, or container is
exempted from standards specified in Sections 725.985 through Section
725.988, provided that all hazardous waste placed in the waste
management unit is determined by the owner or operator to meet
eitherone of the following conditions:
1)
The average VO concentration of theA tank, surface
impoundment, or container for which all hazardous waste
entering the unit has an average VO concentration at the point of
356
waste origination isof less than 100500 parts per million by
weight (ppmw). The average VO concentration must be
determined by the procedures specified in Section 725.984(a).
The owner or operator shall review and update, as necessary, this
determination at least once every 12 months following the date of
the initial determination for the hazardous waste streams entering
the unit.
2)
TA tank, surface impoundment, or container for which the
organic content of all the hazardous waste entering the waste
management unit has been reduced by an organic destruction or
removal process that achieves any one of the following
conditions:
A)
The process removes or destroys the organics contained in
the hazardous waste to such a level that the average VO
concentration of the hazardous waste at the point of waste
treatment is less than the exit concentration limit (C
t
)
established for the process. The average VO
concentration of the hazardous waste at the point of waste
treatment and the exit concentration limit for the process
must be determined using the procedures specified in
Section 725.984(b).
B)
The process removes or destroys the organics contained in
the hazardous waste to such a level that the organic
reduction efficiency (R) for the process is equal to or
greater than 95 percent%, and the average VO
concentration of the hazardous waste at the point of waste
treatment is less than 50100 ppmw. The organic
reduction efficiency for the process and the average VO
concentration of the hazardous waste at the point of waste
treatment must be determined using the procedures
specified in Section 725.984(b).
C)
The process removes or destroys the organics contained in
the hazardous waste to such a level that the actual organic
mass removal rate (MR) for the process is equal to or
greater than the required organic mass removal rate
(RMR) established for the process. The required organic
mass removal rate and the actual organic mass removal
rate for the process must be determined using the
procedures specified in Section 725.984(b).
357
D)
The process is a biological process that destroys or
degrades the organics contained in the hazardous waste so
that either of the following conditions is met:
i)
The organic reduction efficiency (R) for the
process is equal to or greater than 95 percent%,
and the organic biodegradation efficiency (R
bio
) for
the process is equal to or greater than 95
percent%. The organic reduction efficiency and
the organic biodegradation efficiency for the
process must be determined in accordance
withusing the procedures specified in Section
725.984(b).
ii)
The total actual organic mass biodegradation rate
(MR
bio
) for all hazardous waste treated by the
process is equal to or greater than the required
organic mass removal rate (RMR). The required
organic mass removal rate and the actual organic
mass biodegradation rate for the process must be
determined using the procedures specified in
Section 725.984(b).
E)
The process is one that removes or destroys the organics
contained in the hazardous waste and meets all of the
following conditions:
i) All of the materials entering the process are
hazardous wastes.
ii)
From the point of waste origination through the
point where the hazardous waste enters the
treatment process, the hazardous waste is
continuously managed in waste management units
that use air emission controls in accordance with
the standards specified in Section 725.985 through
Section 725.988, as applicable to the waste
management unit.
ii)
From the point of waste origination through the
point where the hazardous waste enters the
treatment process, any transfer of the hazardous
waste is accomplished through continuous hard-
piping or other closed system transfer that does not
allow exposure of the waste to the atmosphere.
358
BOARD NOTE: The USEPA considers a drain
system that meets the requirements of 40 CFR 63,
subpart RR, “National Emission Standards for
Individual Drain Systems”, to be a closed system.
iii)
The average VO concentration of the hazardous
waste at the point of waste treatment is less than
the lowest average VO concentration at the point
of waste origination determined for each of the
individual hazardous waste streams entering the
process or 100500 ppmw, whichever value is
lower. The average VO concentration of each
individual hazardous waste stream at the point of
waste origination must be determined using the
procedures specified in Section 725.984(a). The
average VO concentration of the hazardous waste
at the point of waste treatment must be determined
using the procedures specified in Section
725.984(b).
F)
A process that removes or destroys the organics contained
in the hazardous waste to a level such that the organic
reduction efficiency (R) for the process is equal to or
greater than 95% and the owner or operator certifies that
the average VO concentration at the point of waste
origination for each of the individual waste streams
entering the process is less than 10,000 ppmw. The
organic reduction efficiency for the process and the
average VO concentration of the hazardous waste at the
point of waste origination shall be determined using the
procedures specified in Section 724.983(b) and Section
724.983(a), respectively.
FG)
A hazardous waste incinerator for which either of the
owner or operator has eitherfollowing conditions is true:
i)
BThe owner or operator has been issued a final
permit under 35 Ill. Adm. Code 702, 703, and
705, and the owner or operator designs and
operates the unit in accordance with that
implements the requirements of 35 Ill. Adm. Code
724.Subpart O; or
359
ii)
The owner or operator has certified compliance for
the unitdesigned and operates the incinerator in
accordance with the interim status requirements of
725.Subpart O.
GH)
A boiler or industrial furnace for which either of the
owner or operator has eitherfollowing conditions is true:
i)
BThe owner or operator has been issued a final
permit under 35 Ill. Adm. Code 702, 703, and
705, and and the owner or operator designs and
operates the unit in accordance with that
implements the requirements of 35 Ill. Adm. Code
726.Subpart H,; or
ii)
The owner or operator has certified compliance for
the unitdesigned and operates the industrial furnace
or incinerator in accordance with the interim status
requirements of 35 Ill. Adm. Code 726.Subpart H.
I)
For the purpose of determining the performance of an
organic destruction or removal process in accordance with
the conditions in each of subsections (c)(2)(A) through
(c)(2)(F) of this Section, the owner or operator shall
account for VO concentrations determined to be below the
limit of detection of the analytical method by using the
following VO concentration:
i)
If Method 25D in 40 CFR 60, appendix A,
incorporated by reference in 35 Ill. Adm. Code
720.111, is used for the analysis, one-half the
blank value determined in the method.
ii)
If any other analytical method is used, one-half the
limit of detection established for the method.
3)
A tank used for biological treatment of hazardous waste in
accordance with the requirements of subsection (c)(2)(D) of this
Section.
4)
A tank, surface impoundment, or container for which all
hazardous waste placed in the unit fulfills either of the following
two conditions:
360
A)
It meets the numerical concentration limits for organic
hazardous constituents, applicable to the hazardous waste,
as specified in 35 Ill. Adm. Code 728.Table T; or
B)
It has been treated by the treatment technology established
by USEPA for the waste in 35 Ill. Adm. Code
728.142(a), or treated by an equivalent method of
treatment approved by the Agency pursuant to 35 Ill.
Adm. Code 728.142(b).
5)
A tank used for bulk feed of hazardous waste to a waste
incinerator and all of the following conditions are met:
A)
The tank is located inside an enclosure vented to a control
device that is designed and operated in accordance with all
applicable requirements specified under 40 CFR 61,
subpart FF, “National Emission Standards for Benzene
Waste Operations”, incorporated by reference in 35 Ill.
Adm. Code 720.111, for a facility at which the total
annual benzene quantity from the facility waste is equal to
or greater than 10 megagrams (11 tons) per year;
B)
The enclosure and control device serving the tank were
installed and began operation prior to November 25,
1996; and
C)
The enclosure is designed and operated in accordance with
the criteria for a permanent total enclosure as specified in
“Procedure T--Criteria for and Verification of a
Permanent or Temporary Total Enclosure” under 40 CFR
52.741, appendix B, incorporated by reference in 35 Ill.
Adm. Code 720.111. The enclosure may have permanent
or temporary openings to allow worker access; passage of
material into or out of the enclosure by conveyor,
vehicles, or other mechanical or electrical equipment; or
to direct air flow into the enclosure. The owner or
operator shall perform the verification procedure for the
enclosure as specified in Section 5.0 to “Procedure T--
Criteria for and Verification of a Permanent or Temporary
Total Enclosure” annually.
d) When a process is used for the purpose of treating a hazardous waste to
meet one of the sets of conditions specified in subsections (c)(2)(A)
through (c)(2)(E) above, each material removed from or exiting the
process that is not a hazardous waste but which has an average VO
361
concentration equal to or greater than 100 ppmw must be managed in a
waste management unit in accordance with the requirements of
subsection (b) above.
ed)
The Agency may at any time perform or request that the owner or
operator perform a waste determination for a hazardous waste managed
in a tank, surface impoundment, or container that is exempted from
using air emission controls under the provisions of this Section as
follows:
1)
The waste determination for average VO concentration of a
hazardous waste at the point of waste origination must be
performed using direct measurement in accordance with the
applicable requirements of Section 725.984(a). The waste
determination for a hazardous waste at the point of waste
treatment must be performed in accordance with the applicable
requirements of Section 725.984(b).
2)
In performing a waste determination pursuant to subsection (d)(1)
of this Section, the sample preparation and analysis shall be
conducted as follows:
A)
In accordance with the method used by the owner or
operator to perform the waste analysis, except in the case
specified in subsection (d)(2)(B) of this Section.
B)
If the Agency determines that the method used by the
owner or operator was not appropriate for the hazardous
waste managed in the tank, surface impoundment, or
container, then the Agency may choose an appropriate
method.
23)
Where the owner or operator is requested to perform the waste
determination, the Agency may elect to have an authorized
representative observe the collection of the hazardous waste
samples used for the analysis.
34)
Where the results of the waste determination performed or
requested by the Agency do not agree with the results of a waste
determination performed by the owner or operator using
knowledge of the waste, then the results of the waste
determination performed in accordance with the requirements of
subsection (ed)(1) aboveof this Section must be used to establish
compliance with the requirements of this Subpart.
362
45)
Where the owner or operator has used an averaging period
greater than one hour for determining the average VO
concentration of a hazardous waste at the point of waste
origination, the Agency may elect to establish compliance with
this Subpart by performing or requesting that the owner or
operator perform a waste determination using direct
measurement, based on waste samples collected within a 1-hour
period as follows:
A)
The average VO concentration of the hazardous waste at
the point of waste origination must be determined by
direct measurement in accordance with the requirements
of Section 725.984(a).
B)
Results of the waste determination performed or requested
by the Agency showing that the average VO concentration
of the hazardous waste at the point of waste origination is
equal to or greater than 100500 ppmw shall constitute
noncompliance with this Subpart, except in a case as
provided for in subsection (ed)(4)(C) belowof this
Section.
C)
Where the average VO concentration of the hazardous
waste at the point of waste origination previously has been
determined by the owner or operator using an averaging
period greater than one hour to be less than 100500 ppmw
but because of normal operating process variations the VO
concentration of the hazardous waste determined by direct
measurement for any given 1-hour period may be equal to
or greater than 100500 ppmw, information that was used
by the owner or operator to determine the average VO
concentration of the hazardous waste (e.g., test results,
measurements, calculations, and other documentation) and
recorded in the facility records in accordance with the
requirements of Sections 725.984(a) and 725.990 must be
considered by the Agency together with the results of the
waste determination performed or requested by the
Agency in establishing compliance with this Subpart.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 725.984
Waste Determination Procedures
a)
Waste determination procedure for volatile organic (VO) concentration
of a hazardous waste at the point of waste origination.
363
1)
An owner or operator shall determine the average VO
concentration at the point of waste origination for each hazardous
waste placed in a waste management unit exempted under the
provisions of Section 725.983(c)(1) from using air emission
controls in accordance with standards specified in Section
725.985 through Section 725.988, as applicable to the waste
management unit.
2)
When the facility owner or operator is the generator of the
hazardous waste, tThe owner or operator shall determine the
average VO concentration of thea hazardous waste at the point of
waste origination must be determined using either direct
measurement, as specified in subsection (a)(53) below,of this
Section or by knowledge of the waste, as specified in subsection
(a)(64) belowof this Section, for each hazardous waste generated
as follows:.
A) When the hazardous waste is generated as part of a
continuous process, the owner or operator shall:
i) Perform an initial waste determination of the
average VO concentration of the waste stream
before the first time any portion of the material in
the waste stream is placed in a waste management
unit subject to this Subpart and thereafter update
the information used for the waste determination at
least once every 12 months following the date of
the initial waste determination; and
ii) Perform a new waste determination whenever
changes to the source generating the waste stream
are reasonably likely to cause the average VO
concentration of the hazardous waste to increase to
a level that is equal to or greater than the
applicable VO concentration limits specified in
Section 725.983.
B) When the hazardous waste is generated as part of a batch
process that is performed repeatedly but not necessarily
continuously, the owner or operator shall:
i) Perform an initial waste determination of the
average VO concentration for one or more
representative waste batches generated by the
364
process, before the first time any portion of the
material in the batches is placed in a waste
management unit subject to this Subpart, and
thereafter update the information used for the
waste determination at least once every 12 months
following the date of the initial waste
determination; and
ii) Perform a new waste determination whenever
changes to the process generating the waste batches
are reasonably likely to cause the average VO
concentration of the hazardous waste to increase to
a level that is equal to or greater than the
applicable VO concentration limits specified in
Section 725.983.
3) When the facility owner and operator is not the generator of the
hazardous waste, the owner or operator shall determine the
average VO concentration of the hazardous waste using either
direct measurement, as specified in subsection (a)(5) below, or
knowledge of the waste, as specified in subsection (a)(6) below,
for each hazardous waste entering the facility as follows:
A) When the hazardous waste enters the facility as a
continuous flow of material through a pipeline or other
means (e.g., wastewater stream), the owner or operator
shall:
i) Perform an initial waste determination of the waste
stream before the first time any portion of the
material in the waste stream is placed in a waste
management unit subject to this Subpart, and
thereafter update the information used for the
waste determination at least once every 12 months
following the date of the initial waste
determination; and
ii) Perform a new waste determination whenever
changes to the source generating the waste stream
are reasonably likely to cause the average VO
concentration of the hazardous waste to increase to
a level that is equal to or greater than the
applicable VO concentration limits specified in
Section 725.983.
365
B) When the hazardous waste enters the facility in a
container, the owner or operator shall perform a waste
determination for the material held in each container.
4) Where the average VO concentration of the hazardous waste is
determined by the owner or operator to be less than 100 ppmw,
but because of normal operating variations in the source or
process generating the hazardous waste the VO concentration of
the hazardous waste may be equal to or greater than 100 ppmw at
any given time during the averaging period, the owner or
operator shall prepare and enter in the facility operating record
information that specifies the following:
A) The maximum and minimum VO concentration values for
the hazardous waste that occur during that averaging
period used for the waste determination;
B) The operating conditions or circumstances under which
the VO concentration of the hazardous waste will be equal
to or greater than 100 ppmw; and
C) The information and calculations used by the owner or
operator to determine the average VO concentration of the
hazardous waste.
53)
Procedure for using dDirect measurement to determine average
VO concentration of a hazardous waste at the point of waste
origination.
A)
Identification. The owner or operator shall identify and
record the point of waste origination for the hazardous
waste. All waste samples used to determine the average
VO concentration of the hazardous waste must be
collected at this point.
B) The owner or operator shall designate and record the
averaging period to be used for determining the average
VO concentration for the hazardous waste. The averaging
period must not exceed one year. An initial waste
determination must be performed for each averaging
period.
B)
Sampling. Samples of the hazardous waste stream must
be collected at the point of waste origination in a manner
such that volatilization of organics contained in the waste
366
and in the subsequent sample is minimized and an
adequately representative sample is collected and
maintained for analysis by the selected method.
i)
The averaging period to be used for determining
the average VO concentration for the hazardous
waste stream on a mass-weighted average basis
must be designated and recorded. The averaging
period can represent any time interval that the
owner or operator determines is appropriate for the
hazardous waste stream but must not exceed one
year.
ii)
A sufficient number of samples, but no less than
four samples, must be collected for the hazardous
waste stream to represent the complete range of
compositions and quantities that occur during the
entire averaging period due to normal variations in
the operating conditions for the source or process
generating the hazardous waste stream. Examples
of such normal variations are seasonal variations in
waste quantity or fluctuations in ambient
temperature.
iii)
All samples must be collected and handled in
accordance with written procedures prepared by
the owner or operator and documented in a site
sampling plan. This plan must describe the
procedure by which representative samples of the
hazardous waste stream are collected such that a
minimum loss of organics occurs throughout the
sample collection and handling process, and by
which sample integrity is maintained. A copy of
the written sampling plan must be maintained on-
site in the facility operating records. An example
of an acceptable sampling plan includes a plan
incorporating sample collection and handling
procedures in accordance with the requirements
specified in “Test Methods for Evaluating Solid
Waste, Physical/Chemical Methods,” USEPA
Publication SW-846, incorporated by reference in
35 Ill. Adm. Code 720.111, or in Method 25D in
40 CFR 60, appendix A, incorporated by reference
in 35 Ill. Adm. Code 720.111.
367
C) The owner or operator shall identify each discrete quantity
of the material composing the hazardous waste
represented by the averaging period designated in
subsection (a)(5)(B) above. An example of a discrete
quantity of material composing a hazardous waste
generated as part of a continuous process is the quantity of
material generated during a process operating mode
defined by a specific set of operating conditions that are
normal for the process. An example of a discrete quantity
of material composing a hazardous waste generated as part
of a batch process that is performed repeatedly but not
necessarily continuously is the total quantity of material
composing a single batch generated by the process. An
example of a discrete quantity of material composing a
hazardous waste delivered to a facility in a container is the
total quantity of material held in the container.
C)
Analysis. Each collected sample must be prepared and
analyzed in accordance with one or more of the methods
listed in subsections (a)(3)(C)(i) through (a)(3)(C)(ix),
including appropriate quality assurance and quality control
(QA/QC) checks and use of target compounds for
calibration. If Method 25D in 40 CFR 60, appendix A,
incorporated by reference in 35 Ill. Adm. Code 720.111
is not used, then one or more methods should be chosen
that are appropriate to ensure that the waste determination
accounts for and reflects all organic compounds in the
waste with Henry’s law constant values at least 0.1 mole-
fraction-in-the-gas-phase/mole-fraction-in-the-liquid-phase
(0.1 Y/X) [which can also be expressed as 1.8
×
10
-6
atmospheres/gram-mole/m
3
] at 25° C (77° F). Each of the
analytical methods listed in subsections (a)(3)(C)(ii)
through (a)(3)(C)(vii) of this Section has an associated list
of approved chemical compounds, for which USEPA
considers the method appropriate for measurement. If an
owner or operator uses USEPA Method 624, 625, 1624,
or 1625 in 40 CFR 136, appendix A, incorporated by
reference in 35 Ill. Adm. Code 720.111, to analyze one
or more compounds that are not on that method’s
published list, the Alternative Test Procedure contained in
40 CFR 136.4 and 136.5, incorporated by reference in 35
Ill. Adm. Code 720.111, must be followed. If an owner
or operator uses USEPA Method 8260(B) or 8270(C) in
“Test Methods for Evaluating Solid Waste,
368
Physical/Chemical Methods”, USEPA Publication SW-
846, incorporated by reference in 35 Ill. Adm. Code
720.111, to analyze one or more compounds that are not
on that method’s published list, the procedures in
subsection (a)(3)(C)(viii) of this Section must be
followed. At the owner’s or operator’s discretion, the
concentration of each individual chemical constituent
measured in the waste by a method other than Method
25D may be corrected to the concentration had it been
measured using Method 25D by multiplying the measured
concentration by the constituent-specific adjustment factor
(f
m25D
), as specified in subsection (a)(4)(C) of this Section.
Constituent-specific adjustment factors (f
m25D
) can be
obtained by contacting the USEPA, Waste and Chemical
Processes Group, Office of Air Quality Planning and
Standards, Research Triangle Park, NC 27711.
i)
Method 25D in 40 CFR 60, appendix A,
incorporated by reference in 35 Ill. Adm. Code
720.111.
ii)
Method 624 in 40 CFR 136, appendix A,
incorporated by reference in 35 Ill. Adm. Code
720.111.
iii)
Method 625 in 40 CFR 136, appendix A,
incorporated by reference in 35 Ill. Adm. Code
720.111. Perform corrections to the compounds
for which the analysis is being conducted based on
the “accuracy as recovery” using the factors in
Table 7 of the method.
iv)
Method 1624 in 40 CFR 136, appendix A,
incorporated by reference in 35 Ill. Adm. Code
720.111.
v)
Method 1625 in 40 CFR 136, appendix A,
incorporated by reference in 35 Ill. Adm. Code
720.111.
vi)
Method 8260(B) in “Test Methods for Evaluating
Solid Waste, Physical/Chemical Methods”,
USEPA Publication SW-846, incorporated by
reference in 35 Ill. Adm. Code 720.111. Maintain
a formal quality assurance program consistent with
369
the requirements of Method 8260(B). The quality
assurance program must include the elements set
forth in subsection (a)(3)(E) of this Section.
vii)
Method 8270(C) in “Test Methods for Evaluating
Solid Waste, Physical/Chemical Methods”,
USEPA Publication SW-846, incorporated by
reference in 35 Ill. Adm. Code 720.111. Maintain
a formal quality assurance program consistent with
the requirements of Method 8270(C). The quality
assurance program must include the elements set
forth in subsection (a)(3)(E) of this Section.
viii)
Any other USEPA standard method that has been
validated in accordance with “Alternative
Validation Procedure for USEPA Waste and
Wastewater Methods”, 40 CFR 63, appendix D,
incorporated by reference in 35 Ill. Adm. Code
720.111. As an alternative, other USEPA
standard methods may be validated by the
procedure specified in subsection (a)(3)(C)(ix) of
this Section.
ix)
Any other analysis method that has been validated
in accordance with the procedures specified in
Section 5.1 or Section 5.3, and the corresponding
calculations in Section 6.1 or Section 6.3, of
Method 301 in 40 CFR 63, appendix A,
incorporated by reference in 35 Ill. Adm. Code
720.111. The data are acceptable if they meet the
criteria specified in Section 6.1.5 or Section 6.3.3
of Method 301. If correction is required under
Section 6.3.3 of Method 301, the data are
acceptable if the correction factor is within the
range 0.7 to 1.30. Other Sections of Method 301
are not required.
D) The following procedure must be used measure the VO
concentration for each discrete quantity of material
identified in subsection (a)(5)(C) above:
i) A sufficient number of samples, but in no case
fewer than four, must be collected to represent the
organic composition for the entire discrete quantity
of hazardous waste being tested. All of the
370
samples must be collected within a 1-hour period.
Sufficient information must be prepared and
recorded to document the waste quantity
represented by the samples and, as applicable, the
operating conditions for the source or process
generating the hazardous waste represented by the
samples.
ii) Each sample must be collected in accordance with
the requirements specified in “Test Methods for
Evaluating Solid Waste, Physical/Chemical
Methods”, incorporated by reference in Section
720.111.
iii) Each collected sample must be prepared and
analyzed in accordance with the requirements of
Method 25D in 40 CFR 60, Appendix A,
incorporated by reference in 35 Ill. Adm. Code
720.111.
iv) The measured VO concentration for the discrete
quantity of hazardous waste must be determined by
using the results for all samples analyzed in
accordance with subsection (a)(5)(D)(iii) above
and the following equation:
C =
1
n
x
n
i = 1
C
i
∑
Where:
C = Measured VO concentration of the
discrete quantity of hazardous waste, in
ppmw.
i = Individual sample “i” of the
hazardous waste collected in accordance
with the requirements of SW-846.
n = Total number of samples of
hazardous waste collected (at least 4) within
a 1-hour period.
371
C
i
= VO concentration measured by
Method 25D for sample “i”, in ppmw.
E) The average VO concentration of the hazardous waste
must be determined using the following procedure:
i) When the facility owner or operator is the
generator of the hazardous waste, a sufficient
number of VO concentration measurements for the
hazardous waste must be performed in accordance
with the requirements of subsection (a)(5)(D)
above to represent the complete range of hazardous
waste organic compositions and quantities that
occur during the entire averaging period due to
normal variations in the operating conditions for
each process operating mode identified for the
source or process generating the hazardous waste.
ii) When the facility owner or operator is not the
generator of the hazardous waste, a sufficient
number of VO concentration measurements for the
hazardous waste must be performed in accordance
with the requirements of subsection (a)(5)(D)
above to represent the complete range of hazardous
waste organic compositions and quantities that
occur in the hazardous waste as received at the
facility during the entire averaging period.
iiiD)
Calculations. The average VO concentration of the
hazardous waste at the point of waste origination(
C
) on a
mass-weighted basis must be calculated by using the
results for all VO measurements performedsamples
analyzed in accordance with subsection (a)(53)(DC)
aboveof this Section and the following equation:
=
T
j
j
C
1
Q
x
m
j = 1
( Q
x C
)
∑
C =
1
Q
x
n
i = 1
( Q
x C )
T
i
i
∑
372
Where:
C
ave
C
=
Average VO concentration of the
hazardous waste at the point of waste
origination on a mass-weighted basis, in
ppmw.
ji =
Individual discrete quantitysample “ji” of
the hazardous waste for which a VO
concentration measurement is determined in
accordance with the requirements of
subsection (a)(5)(D) above.
mn =
Total number of VO concentration
measurements determined in accordance
with the requirements of subsection
(a)(5)(D) abovesamples of the hazardous
waste collected (at least four) for the
averaging period (not to exceed one year).
Q
j
Q
i
=Mass of the discrete quantityquantity of the
hazardous waste stream represented by
C
j
C
i
, in kg/hr.
Q
T
=
Total mass quantity of the hazardous waste
forduring the averaging period, in kg/hr.
C
j
C
i
=Measured VO concentration of discrete
quantitysample “ji”, as for the hazardous
waste determined in accordance with the
requirements of subsection (a)(53)(DC)
aboveof this Section, in ppmw.
E)
The quality assurance program elements required under
subsections (a)(3)(C)(vi) and (a)(3)(C)(vii) of this Section
are as follows:
i)
Documentation of site-specific procedures to
minimize the loss of compounds due to
volatilization, biodegradation, reaction, or sorption
during the sample collection, storage, preparation,
introduction, and analysis steps.
373
ii)
Measurement of the overall accuracy and precision
of the specific procedures.
BOARD NOTE: Subsections (a)(3)(E)(i) and
(a)(3)(E)(ii) correspond with 40 CFR
265.984(a)(3)(iii)(F)(1), (a)(3)(iii)(F)(2),
(a)(3)(iii)(G)(1), and (a)(3)(iii)(G)(2), which the
Board has codified here to comport with Illinois
Administrative Code format requirements.
6) Procedure for using knowledge of the waste to determine the
average VO concentration of a hazardous waste at the point of
waste origination.
A) The owner or operator shall identify and record the point
of waste origination for the hazardous waste. All
information used to determine the average VO
concentration of the hazardous waste must be based on the
hazardous waste composition at this point.
B) The owner or operator shall designate and record the
averaging period to be used for determining the average
VO concentration for the hazardous waste. The averaging
period must not exceed one year. An initial waste
determination must be performed for each averaging
period.
C) The owner or operator shall prepare and record sufficient
information that documents the average VO concentration
for the hazardous waste. Information may be used that is
prepared by either the facility owner or operator or by the
generator of the hazardous waste. Examples of
information that may be used as the basis for knowledge
of the waste include: organic material balances for the
source or process generating the waste; VO concentration
measurements for the same type of waste performed in
accordance with the procedure specified in subsection
(a)(5)(D) above; previous individual organic constituent
test data for the waste that are still applicable to the
current waste management practices; documentation that
the waste is generated by a process for which no organics-
containing materials are used; previous test data for other
locations managing the same type of waste; or other
knowledge based on manifests, shipping papers, or waste
certification notices.
374
D) If test data other than VO concentration measurements
performed in accordance with the procedure specified in
subsection (a)(5)(D) above are used as the basis for
knowledge of the waste, then the owner or operator shall
document the test method, sampling protocol, and the
means by which sampling variability and analytical
variability are accounted for in the determination of the
average VO concentration. For example, an owner or
operator may use individual organic constituent
concentration test data that are validated in accordance
with Method 301 in 40 CFR 63, Appendix A,
incorporated by reference in 35 Ill. Adm. Code 720.111,
as the basis for knowledge of the waste.
4)
Use of owner or operator knowledge to determine average VO
concentration of a hazardous waste at the point of waste
origination.
A)
Documentation must be prepared that presents the
information used as the basis for the owner’s or operator’s
knowledge of the hazardous waste stream’s average VO
concentration. Examples of information that may be used
as the basis for knowledge include the following: material
balances for the source or process generating the
hazardous waste stream; constituent-specific chemical test
data for the hazardous waste stream from previous testing
that are still applicable to the current waste stream;
previous test data for other locations managing the same
type of waste stream; or other knowledge based on
information included in manifests, shipping papers, or
waste certification notices.
B)
If test data are used as the basis for knowledge, then the
owner or operator shall document the test method,
sampling protocol, and the means by which sampling
variability and analytical variability are accounted for in
the determination of the average VO concentration. For
example, an owner or operator may use organic
concentration test data for the hazardous waste stream that
are validated in accordance with Method 301 in 40 CFR
63, appendix A, incorporated by reference in 35 Ill. Adm.
Code 720.111, as the basis for knowledge of the waste.
375
C)
An owner or operator using chemical constituent-specific
concentration test data as the basis for knowledge of the
hazardous waste may adjust the test data to the
corresponding average VO concentration value which
would have been obtained had the waste samples been
analyzed using Method 25D in 40 CFR 60, appendix A,
incorporated by reference in 35 Ill. Adm. Code 720.111.
To adjust these data, the measured concentration for each
individual chemical constituent contained in the waste is
multiplied by the appropriate constituent-specific
adjustment factor (f
m25D
).
D)
In the event that the Agency and the owner or operator
disagree on a determination of the average VO
concentration for a hazardous waste stream using
knowledge, then the results from a determination of
average VO concentration using direct measurement as
specified in subsection (a)(3) of this Section must be used
to establish compliance with the applicable requirements
of this Subpart. The Agency may perform or request that
the owner or operator perform this determination using
direct measurement.
b)
Waste determination procedures for treated hazardous waste.
1)
An owner or operator shall perform the applicable waste
determination for each treated hazardous waste placed in a waste
management unit exempted under the provisions of Section
725.983(c)(2) from using air emission controls in accordance
with standards specified in Sections 725.985 through Section
725.988, as applicable to the waste management unit.
2) The owner or operator shall perform a waste determination for
each discrete quantity of treated hazardous waste as follows:
A) When the hazardous waste is treated by a continuous
process, the owner or operator shall:
i) Perform an initial waste determination for the
treated waste stream before the first time any
portion of the material in the waste stream is
placed in a waste management unit subject to this
Subpart, and thereafter update the information
used for the waste determination at least once
376
every 12 months following the date of the initial
waste determination; and
ii) Perform a new waste determination whenever
changes to the hazardous waste streams fed to the
process are reasonably likely to cause the
characteristics of the hazardous waste at the point
of waste treatment to change to levels that fail to
achieve the applicable conditions specified in
Section 725.983(c)(2).
B) When the hazardous waste is treated by a batch process
that is performed repeatedly but not necessarily
continuously, the owner or operator shall:
i) Perform an initial waste determination for the
treated hazardous waste in one or more
representative batches treated by the process, and
thereafter update the information used for the
waste determination at least once every 12 months
following the date of the initial waste
determination; and
ii) Perform a new waste determination whenever
changes to the hazardous waste treated by the
process are reasonably likely to cause the
characteristics of the hazardous waste at the point
of waste treatment to change to levels that fail to
achieve the applicable conditions specified in
Section 725.983(c)(2).
32)
The owner or operator shall designate and record the specific
provision in Section 725.983(c)(2) forunder which the waste
determination is being performed. The waste determination for
the treated hazardous waste must be performed using the
applicable procedures specified in subsections (b)(43) through
(b)(109) belowof this Section.
43)
Procedure to determine the average VO concentration of a
hazardous waste at the point of waste treatment.
A)
Identification. The owner or operator shall identify and
record the point of waste treatment for the hazardous
waste. All waste samples used to determine the average
377
VO concentration of the hazardous waste must be
collected at this point.
B) The owner or operator shall designate and record the
averaging period to be used for determining the average
VO concentration for the hazardous waste. The averaging
period must not exceed one year. An initial waste
determination must be performed for each averaging
period.
C) The owner or operator shall identify each discrete quantity
of the material composing the hazardous waste
represented by the averaging period designated in
subsection (b)(4)(B) above.
D) The following procedure shall be used to measure the VO
concentration for each discrete quantity of material
identified in subsection (b)(4)(C) above:
i) A sufficient number of samples, but in no case
fewer than four samples, must be collected to
represent the organic composition for the entire
discrete quantity of hazardous waste being tested.
All of the samples must be collected within a 1-
hour period. Sufficient information must be
prepared and recorded to document the waste
quantity represented by the samples and, as
applicable, the operating conditions for the process
treating the hazardous waste represented by the
samples.
ii) Each sample must be collected in accordance with
the requirements specified in “Test Methods for
Evaluating Solid Waste, Physical/Chemical
Methods”, incorporated by reference in 35 Ill.
Adm. Code 720.111.
iii) Each collected sample must be prepared and
analyzed in accordance with the requirements of
Method 25D in 40 CFR 60, Appendix A,
incorporated by reference in 35 Ill. Adm. Code
720.111.
iv) The measured VO concentration for the discrete
quantity of hazardous waste must be determined by
378
using the results for all samples analyzed in
accordance with subsection (a)(5)(D)(iii) above
and the following equation:
C =
1
n
x
n
i = 1
C
i
∑
Where:
C = Measured VO concentration of the
discrete quantity of hazardous
waste, in ppmw.
i = Individual sample “i” of the
hazardous waste collected in
accordance with the requirements of
SW-846.
n = Total number of samples of
hazardous waste collected (at least
4) within a 1-hour period.
C
i
= VO concentration measured by
Method 25D for sample “i”, in
ppmw.
B)
Sampling. Samples of the hazardous waste stream must
be collected at the point of waste treatment in a manner
such that volatilization of organics contained in the waste
and in the subsequent sample is minimized and an
adequately representative sample is collected and
maintained for analysis by the selected method.
i)
The averaging period to be used for determining
the average VO concentration for the hazardous
waste stream on a mass-weighted average basis
must be designated and recorded. The averaging
period can represent any time interval that the
owner or operator determines is appropriate for the
hazardous waste stream but must not exceed one
year.
379
ii)
A sufficient number of samples, but no less than
four samples, must be collected for the hazardous
waste stream to represent the complete range of
compositions and quantities that occur during the
entire averaging period due to normal variations in
the operating conditions for the process treating the
hazardous waste stream. Examples of such normal
variations are seasonal variations in waste quantity
or fluctuations in ambient temperature.
iii)
All samples must be collected and handled in
accordance with written procedures prepared by
the owner or operator and documented in a site
sampling plan. This plan must describe the
procedure by which representative samples of the
hazardous waste stream are collected such that a
minimum loss of organics occurs throughout the
sample collection and handling process, and by
which sample integrity is maintained. A copy of
the written sampling plan must be maintained on-
site in the facility operating records. An example
of an acceptable sampling plan includes a plan
incorporating sample collection and handling
procedures in accordance with the requirements
specified in “Test Methods for Evaluating Solid
Waste, Physical/Chemical Methods,” USEPA
Publication No. SW-846, incorporated by
reference in 35 Ill. Adm. Code 720.111, or in
Method 25D in 40 CFR 60, appendix A,
incorporated by reference in 35 Ill. Adm. Code
720.111.
C)
Analysis. Each collected sample must be prepared and
analyzed in accordance with one or more of the methods
listed in subsections (b)(3)(C)(i) through (b)(3)(C)(ix) of
this Section, including appropriate quality assurance and
quality control (QA/QC) checks and use of target
compounds for calibration. If Method 25D in 40 CFR
60, appendix A is not used, then one or more methods
should be chosen that are appropriate to ensure that the
waste determination accounts for and reflects all organic
compounds in the waste with Henry’s law constant values
at least 0.1 mole-fraction-in-the-gas-phase/mole-fraction-
in-the-liquid-phase (0.1 Y/X) [which can also be
380
expressed as 1.8
×
10
-6
atmospheres/gram-mole/m
3
] at 25
degrees Celsius. Each of the analytical methods listed in
subsections (b)(3)(C)(ii) through (b)(3)(C)(vi) of this
Section has an associated list of approved chemical
compounds, for which USEPA considers the method
appropriate for measurement. If an owner or operator
uses USEPA Method 624, 625, 1624, or 1625 in 40 CFR
136, appendix A, incorporated by reference in 35 Ill.
Adm. Code 720.111, to analyze one or more compounds
that are not on that method’s published list, the
Alternative Test Procedure contained in 40 CFR 136.4
and 136.5, incorporated by reference in 35 Ill. Adm.
Code 720.111, must be followed. If an owner or operator
uses USEPA Method 8260(B) or 8270(C) in “Test
Methods for Evaluating Solid Waste, Physical/Chemical
Methods”, USEPA Publication SW-846, incorporated by
reference in 35 Ill. Adm. Code 720.111, to analyze one
or more compounds that are not on that method’s
published list, the procedures in subsection (b)(3)(C)(viii)
of this Section must be followed. At the owner’s or
operator’s discretion, the concentration of each individual
chemical constituent measured in the waste by a method
other than Method 25D may be corrected to the
concentration had it been measured using Method 25D by
multiplying the measured concentration by the constituent-
specific adjustment factor (f
m25D
) as specified in subsection
(a)(4)(C) of this Section. Constituent-specific adjustment
factors (f
m25D
) can be obtained by contacting the USEPA,
Waste and Chemical Processes Group, Office of Air
Quality Planning and Standards, Research Triangle Park,
NC 27711.
i)
Method 25D in 40 CFR 60, appendix A,
incorporated by reference in 35 Ill. Adm. Code
720.111.
ii)
Method 624 in 40 CFR 136, appendix A,
incorporated by reference in 35 Ill. Adm. Code
720.111.
iii)
Method 625 in 40 CFR 136, appendix A,
incorporated by reference in 35 Ill. Adm. Code
720.111. Perform corrections to the compounds
for which the analysis is being conducted based on
381
the “accuracy as recovery” using the factors in
Table 7 of the method.
iv)
Method 1624 in 40 CFR 136, appendix A,
incorporated by reference in 35 Ill. Adm. Code
720.111.
v)
Method 1625 in 40 CFR 136, appendix A,
incorporated by reference in 35 Ill. Adm. Code
720.111.
vi)
Method 8260(B) in “Test Methods for Evaluating
Solid Waste, Physical/Chemical Methods”,
USEPA Publication SW-846, incorporated by
reference in 35 Ill. Adm. Code 720.111. Maintain
a formal quality assurance program consistent with
the requirements of Method 8260(B). The quality
assurance program must include the elements set
forth in subsection (b)(3)(E) of this Section.
vii)
Method 8270(C) in “Test Methods for Evaluating
Solid Waste, Physical/Chemical Methods”,
USEPA Publication SW-846, incorporated by
reference in 35 Ill. Adm. Code 720.111. Maintain
a formal quality assurance program consistent with
the requirements of Method 8270(C). The quality
assurance program must include the elements set
forth in subsection (b)(3)(E) of this Section.
viii)
Any other USEPA standard method that has been
validated in accordance with “Alternative
Validation Procedure for EPA Waste and
Wastewater Methods”, 40 CFR 63, appendix D,
incorporated by reference in 35 Ill. Adm. Code
720.111. As an alternative, other USEPA
standard methods may be validated by the
procedure specified in subsection (b)(3)(C)(ix) of
this Section.
ix)
Any other analysis method that has been validated
in accordance with the procedures specified in
Section 5.1 or Section 5.3, and the corresponding
calculations in Section 6.1 or Section 6.3, of
Method 301 in 40 CFR 63, appendix A. The data
are acceptable if they meet the criteria specified in
382
Section 6.1.5 or Section 6.3.3 of Method 301. If
correction is required under Section 6.3.3 of
Method 301, the data are acceptable if the
correction factor is within the range 0.7 to 1.30.
Other Sections of Method 301 are not required.
E) The average VO concentration of the hazardous waste at
the point of waste treatment must be determined using the
following procedure:
i) When the facility owner or operator is the
generator of the hazardous waste, a sufficient
number of VO concentration measurements for the
hazardous waste must be performed in accordance
with the requirements of subsection (b)(4)(D)
above to represent the complete range of hazardous
waste organic compositions and quantities treated
by the process during the entire averaging period.
iiD)
Calculations. The average VO concentration of the
hazardous waste at the point of waste treatment(
C
) on a
mass-weighted basis must be calculated by using the
results for all VO measurements performedsamples
analyzed in accordance with subsection (b)(43)(DC)
aboveof this Section and the following equation:
ave
T
j
j
C
=
1
Q
x
m
j = 1
( Q
x C
)
∑
C =
1
Q
x
n
i = 1
( Q
x C )
T
i
i
∑
Where:
C
ave
C
=
Average VO concentration of the
hazardous waste at the point of waste
originationtreatment on a mass-weighted
basis, in ppmw.
ji =
Individual discrete quantitysample “ji” of
the hazardous waste for which a VO
concentration measurement is determined in
383
accordance with the requirements of
subsection (b)(4)(D) above.
mn =
Total number of VO concentration
measurements determined in accordance
with the requirements of subsection
(b)(4)(D) abovesamples of the hazardous
waste collected (at least 4) for the
averaging period (not to exceed 1 year).
Q
j
Q
i
=Mass of the discrete quantity of the
hazardous waste stream represented by
C
j
C
i
, in kg/hr.
Q
T
=
Total mass quantity of the hazardous waste
forduring the averaging period, in kg/hr.
C
j
C
i
=Measured VO concentration of discrete
quantitysample “ji”, as for the hazardous
waste determined in accordance with the
requirements of subsection (b)(43)(DC)
aboveof this Section, in ppmw.
54)
Procedure to determine the exit concentration limit (C
t
) for a
treated hazardous waste.
A)
The point of waste origination for each hazardous waste
treated by the process at the same time must be identified.
B)
If a single hazardous waste stream is identified in
subsection (b)(54)(A) aboveof this Section, then the exit
concentration limit (C
t
) must be 100500 ppmw.
C)
If more than one hazardous waste stream is identified in
subsection (b)(54)(A) aboveof this Section, then the
average VO concentration of each hazardous waste stream
at the point of waste origination must be determined in
accordance with the requirements of subsection (a)
aboveof this Section. The exit concentration limit (C
t
)
must be calculated by using the results determined for
each individual hazardous waste stream and the following
equation:
384
t
x
x
y
x
y
C
=
m
x = 1
(Q
x C
)+
n
y = 1
( Q
x100ppmw)
m
x = 1
Q
+
n
y = 1
Q
∑
∑
∑
∑
t
x
x
y
x
y
C
=
m
x = 1
( Q
x C
)+
n
y = 1
(Q
x
00ppmw)
m
x = 1
Q
+
n
y = 1
Q
∑
∑
∑
∑
5
Where:
C
t
=
Exit concentration limit for treated
hazardous waste, in ppmw.
x =
Individual hazardous waste stream “x” that
has an average VO concentration less than
100500 ppmw at the point of waste
origination, as determined in accordance
with the requirements of Section
725.984subsection (a) of this Section.
y =
Individual hazardous waste stream “y” that
has an average VO concentration equal to
or greater than 100500 ppmw at the point
of waste origination, as determined in
accordance with the requirements of
Section 725.984subsection (a) of this
Section.
m =
Total number of “x” hazardous waste
streams treated by process.
n =
Total number of “y” hazardous waste
streams treated by process.
Q
x
=
Annual mass quantity of hazardous waste
stream “x”, in kg/yr.
385
Q
y
=
Annual mass quantity of hazardous waste
stream “y”, in kg/yr.
C
x
= Average VO concentration of hazardous
waste stream “x” at the point of waste
origination, as determined in accordance
with the requirements of Section
725.984subsection (a) of this Section, in
ppmw.
65)
Procedure to determine the organic reduction efficiency (R) for a
treated hazardous waste.
A)
The organic reduction efficiency (R) for a treatment
process must be determined based on results for a
minimum of three consecutive runs. The sampling time
for each run must be one hour.
B)
The point of eachAll hazardous waste streams entering the
process and eachall hazardous waste streams exiting the
treatment process that is to be included in the calculation
of the organic reduction efficiency for the process must be
identified. The owner or operator shall prepare a
sampling plan for measuring these streams that accurately
reflects the retention time of the hazardous waste in the
process.
C)
For each run, the following information must be
determined for each hazardous waste stream identified in
subsection (b)(65)(B) aboveof this Section, using the
following procedures:
i)
The mass quantity of each hazardous waste stream
entering the process (Q
b
) and the mass quantity of
each hazardous waste stream exiting the process
(Q
a
) must be determined.
ii)
The average VO concentration at the point of
waste origination of each hazardous waste stream
entering the process (C
b
C
b
) during the run must be
measureddetermined in accordance with the
requirements of subsections (a)(53)(D)(i) through
(a)(5)(D)(iv) belowof this Section. The average
386
VO concentration at the point of waste treatment
of each hazardous waste stream exiting the process
(C
a
C
a
) during the run must be determined in
accordance with the requirements of subsection
(b)(43)(D) belowof this Section. Samples must be
collected as follows: For a continuous process, the
samples of the hazardous waste entering and
samples of the hazardous waste exiting the process
must be collected concurrently. For a batch
process, the samples of the hazardous waste
entering the process must be collected at the time
that the hazardous waste is placed in the process.
The samples of the hazardous waste exiting the
process must be collected as soon as practicable
after the time when the process stops operation or
the final treatment cycle ends.
D)
The waste volatile organic mass flow entering the process
(E
b
) and the waste volatile organic mass flow exiting the
process (E
a
) must be calculated by using the results
determined in accordance with subsection (b)(65)(C)
aboveof this Section and the following equations:
b
6
bj
bj
E
=
1
10
m
j = 1
( Q
x C
)
∑
a
6
aj
aj
E
=
1
10
m
j = 1
(Q
x C
)
∑
b
6
bj
bj
E
=
1
10
m
j = 1
(Q
xC
)
∑
a
6
aj
aj
E
=
1
10
m
j = 1
( Q
xC
)
∑
Where:
387
E
a
=
Waste volatile organic mass flow exiting
the process, in kg/hr.
E
b
=
Waste volatile organic mass flow entering
the process, in kg/hr.
m =
Total number of runs (at least 3)
j =
Individual run “j”
Q
bj
=
Mass quantity of hazardous waste entering
the process during run “j”, in kg/hr.
Q
aj
=
Average mass quantity of waste exiting the
process during run “j”, in kg/hr.
C
aj
aj
C
=
Measured Average VO
concentration of hazardous waste exiting
the process during run “j”, as determined
in accordance with the requirements of
Section 725.984subsection (b)(43)(D) of
this Section, in ppmw.
C
bj
bj
C
=
Measured Average VO
concentration of hazardous waste entering
the process during run “j”, as determined
in accordance with the requirements of
Section 725.984subsection 725.984
(a)(53)(D)(i) through (a)(5)(D)(iv) of this
Section, in ppmw.
E)
The organic reduction efficiency of the process must be
calculated by using the results determined in accordance
with subsection (b)(65)(D) aboveof this Section and the
following equation:
R =
E
- E
E
x100%
b
a
b
Where:
R =
Organic reduction efficiency, in percent.
388
E
b
=
Waste volatile organic mass flow entering
the process as determined in accordance
with the requirements of subsection
(b)(65)(D) aboveof this Section, in kg/hr.
E
a
=
Waste volatile organic mass flow exiting
the process as determined in accordance
with the requirements of subsection
(b)(65)(D) aboveof this Section, in kg/hr.
76)
Procedure to determine the organic biodegradation efficiency
(R
bio
) for a treated hazardous waste.
A)
The fraction of organics biodegraded (F
bio
) must be
determined using the procedure specified in 40 CFR 63,
Appendix C, incorporated by reference in 35 Ill. Adm.
Code 720.111.
B)
The organic biodegradation efficiency (R
bio
) must be
calculated by using the following equation:
bio
bio
R
= F
x100%
Where
R
bio
= Organic biodegradation efficiency, in
percent.
F
bio
=
Fraction of organic biodegraded, as
determined in accordance with the
requirements of subsection (b)(76)(A)
aboveof this Section.
87)
Procedure to determine the required organic mass removal rate
(RMR) for a treated hazardous waste.
A)
The point of waste origination for eachAll of the
hazardous waste treated bystreams entering the treatment
process at the same time must be identified.
B)
For each hazardous waste stream identified in subsection
(b)(8)(A) above, theThe average VO concentration of the
hazardous waste stream at the point of waste origination
389
must be determined in accordance with the requirements
of subsection (a) aboveof this Section.
C)
For each individual hazardous waste stream that has an
average volatile organic concentration equal to or greater
than 100500 ppmw at the point of waste origination as
determined in accordance with the requirements of
subsection (b)(8)(B) above, the average volumetric flow
rate of hazardous waste and the density of the hazardous
waste stream at the point of waste origination and the
density of the hazardous waste stream must be
determined.
D)
The required organic mass removal rate (RMR) for the
hazardous waste must be calculated by using the results
determined for each individual hazardous waste stream in
accordance with the requirements of subsections (b)(8)(B)
and (b)(8)(C) aboveaverage VO concentration, average
volumetric flow rate, and density determined for each
individual hazardous waste stream, and the following
equation:
RMR =
n
y = 1
V
x k
x
( C
-100ppmw)
10
y
y
y
6
∑
RMR =
n
y = 1
V
x k
x
( C
- 500ppmw)
10
y
y
y
6
∑
Where:
RMR =
Required organic mass removal rate, in
kg/hr.
y =
Individual hazardous waste stream “y” that has an
average volatile organic (VO) concentration equal
to or greater than 100500 ppmw at the point of
waste origination, as determined in accordance
with the requirements of Section
725.984subsection (a) of this Section.
390
n =
Total number of “y” hazardous waste streams
treated by process.
V
y
=
Average volumetric flow rate of hazardous waste
stream “y” at the point of waste origination, in
m
3
/hr.
k
y
=
Density of hazardous waste stream “y”, in kg/m
3
C
y
= Average VO concentration of hazardous waste
stream “y” at the point of waste origination, as
determined in accordance with the requirements of
Section 725.984subsection (a) of this Section, in
ppmw.
98)
Procedure to determine the actual organic mass removal rate
(MR) for a treated hazardous waste.
A)
The actual organic mass removal rate (MR) must be
determined based on results for a minimum of three
consecutive runs. The sampling time for each run must be
one hour.
B)
The waste volatile organic mass flow entering the process
(E
b
) and the waste volatile organic mass flow exiting the
process (E
a
) must be determined in accordance with the
requirements of subsection (b)(65)(D) aboveof this
Section.
C)
The actual organic mass removal rate (MR) must be
calculated by using the resultsmass flow rate determined
in accordance with the requirements of subsection
(b)(98)(B) aboveof this Section and the following
equation:
MR = E
- E
b
a
Where:
MR = Actual organic mass removal rate, in kg/hr.
E
b
=
Waste volatile organic mass flow entering
process, as determined in accordance with
391
the requirements of subsection (b)(65)(D)
aboveof this Section, in kg/hr.
E
a
=
Waste volatile organic mass flow exiting
process, as determined in accordance with
the requirements of subsection (b)(65)(D)
aboveof this Section, in kg/hr.
109)
Procedure to determine the actual organic mass biodegradation
rate (MR
bio
) for a treated hazardous waste.
A)
The actual organic mass biodegradation rate (MR
bio
) must
be determined based on results for a minimum of three
consecutive runs. The sampling time for each run must
be one hour.
B)
The waste organic mass flow entering the process (E
b
)
must be determined in accordance with the requirements
of subsection (b)(65)(D) aboveof this Section.
C)
The fraction of organic biodegraded (F
bio
) must be
determined using the procedure specified in 40 CFR 63,
Appendix C, incorporated by reference in 35 Ill. Adm.
Code 720.111.
D)
The actual organic mass biodegradation rate (MR
bio
) must
be calculated by using the mass flow rates and fraction of
organic biodegraded determined in accordance with the
requirements of subsections (b)(109)(B) and (b)(109)(C)
aboveof this Section and the following equation:
bio
b
bio
MR
= E
x F
Where:
MR
bio
=
Actual organic mass biodegradation
rate, in kg/hr.
E
b
=
Waste organic mass flow entering the
process, as determined in accordance with
the requirements of subsection (b)(65)(D)
aboveof this Section, in kg/hr.
392
F
bio
=
Fraction of organic biodegraded, as
determined in accordance with the
requirements of subsection (b)(109)(C)
aboveof this Section.
c)
Procedure to determine the maximum organic vapor pressure of a
hazardous waste in a tank.
1)
An owner or operator shall determine the maximum organic
vapor pressure for each hazardous waste placed in a tank using
air emissionTank Level 1 controls in accordance with standards
specified in Section 725.985(c).
2)
An owner or operator shall use either direct measurement, as
specified in subsection (c)(3) aboveof this Section, or knowledge
of the waste, as specified by subsection (c)(4) aboveof this
Section, to determine the maximum organic vapor pressure that is
representative of the hazardous waste composition stored or
treated in the tank.
3)
To determine the maximum organic vapor pressure of the
hazardous waste by direct measurement, the following procedure
must be used:Direct measurement to determine the maximum
organic vapor pressure of a hazardous waste.
A)
RepresentativeSampling. A sufficient number of samples
of the waste contained in the tank must be collected to be
representative of the waste contained in the tank.
SamplingAll samples must be conducted and handled in
accordance with written procedures prepared by the owner
or operator and documented in a site sampling plan. This
plan must describe the procedure by which representative
samples of the hazardous waste are collected such that a
minimum loss of organics occurs throughout the sample
collection and handling process and by which sample
integrity is maintained. A copy of the written sampling
plan must be maintained on-site in the facility operating
records. An example of an acceptable sampling plan
includes a plan incorporating sample collection and
handling procedures in accordance with the requirements
specified in “Test Methods for Evaluating Solid Waste,
Physical/Chemical Methods”, USEPA Publication No.
SW-846, incorporated by reference in 35 Ill. Adm. Code
720.111, or in Method 25D in 40 CFR 60, appendix A,
incorporated by reference in 35 Ill. Adm. Code 720.111.
393
B)
Analysis. Any appropriate one of the following methods
may be used to analyze the samples and compute the
maximum organic vapor pressure of the hazardous waste,
as appropriate:
i)
Method 25E in 40 CFR 60, Appendix A,
incorporated by reference in 35 Ill. Adm. Code
720.111;
ii)
Methods described in American Petroleum
Institute Publication 2517, incorporated by
reference in 35 Ill. Adm. Code 720.111;
iii)
Methods obtained from standard reference texts;
iv)
ASTM Method D 2879-92, incorporated by
reference in 35 Ill. Adm. Code 720.111); or
v)
Any other method approved by the Agency for this
use by the owner or operator.
4) To determine the maximum organic vapor pressure of the
hazardous waste by knowledge, sufficient information must be
prepared and recorded that documents the maximum organic
vapor pressure of the hazardous waste in the tank. Examples of
information that may be used include: documentation that the
waste is generated by a process for which no organics-containing
materials are used or that the waste is generated by a process for
which at other locations it previously has been determined by
direct measurement that the waste maximum organic vapor
pressure is less than the maximum vapor pressure limit for the
appropriate design capacity category specified for the tank.
4)
Use of knowledge to determine the maximum organic vapor
pressure of the hazardous waste. Documentation must be
prepared and recorded that presents the information used as the
basis for the owner’s or operator’s knowledge that the maximum
organic vapor pressure of the hazardous waste is less than the
maximum vapor pressure limit listed in Section 725.985(b)(1)(A)
for the applicable tank design capacity category. An example of
information that may be used is documentation that the hazardous
waste is generated by a process for which at other locations it
previously has been determined by direct measurement that the
waste maximum organic vapor pressure is less than the maximum
394
vapor pressure limit for the appropriate tank design capacity
category.
d)
Procedure for determining no detectable organic emissions for the
purpose of complying with this Subpart:
1)
The test must be conducted in accordance with the procedures
specified in Method 21 of 40 CFR 60, appendix A, incorporated
by reference in 35 Ill. Adm. Code 720.111. Each potential leak
interface (i.e., a location where organic vapor leakage could
occur) on the cover and associated closure devices must be
checked. Potential leak interfaces that are associated with covers
and closure devices include, but are not limited to any of the
following: the interface of the cover and its foundation
mounting, the periphery of any opening on the cover and its
associated closure device, and the sealing seat interface on a
spring-loaded pressure relief valve.
2)
The test must be performed when the unit contains a hazardous
waste having an organic concentration representative of the range
of concentrations for the hazardous waste expected to be managed
in the unit. During the test, the cover and closure devices must
be secured in the closed position.
3)
The detection instrument must meet the performance criteria of
Method 21 of 40 CFR 60, appendix A, incorporated by reference
in 35 Ill. Adm. Code 720.111, except the instrument response
factor criteria in Section 3.1.2(a) of Method 21 must be for the
average composition of the organic constituents in the hazardous
waste placed in the waste management unit, not for each
individual organic constituent.
4)
The detection instrument must be calibrated before use on each
day of its use by the procedures specified in Method 21 of 40
CFR 60, appendix A, incorporated by reference in 35 Ill. Adm.
Code 720.111.
5)
Calibration gases must be as follows:
A)
Zero air (less than 10 ppmv hydrocarbon in air), and
B)
A mixture of methane in air at a concentration of
approximately, but less than, 10,000 ppmv.
395
6)
The background level must be determined according to the
procedures in Method 21 of 40 CFR 60, appendix A,
incorporated by reference in 35 Ill. Adm. Code 720.111.
7)
Each potential leak interface must be checked by traversing the
instrument probe around the potential leak interface as close to
the interface as possible, as described in Method 21 of 40 CFR
60, appendix A, incorporated by reference in 35 Ill. Adm. Code
720.111. In the case when the configuration of the cover or
closure device prevents a complete traverse of the interface, all
accessible portions of the interface must be sampled. In the case
when the configuration of the closure device prevents any
sampling at the interface and the device is equipped with an
enclosed extension or horn (e.g., some pressure relief devices),
the instrument probe inlet must be placed at approximately the
center of the exhaust area to the atmosphere.
8)
The arithmetic difference between the maximum organic
concentration indicated by the instrument and the background
level must be compared with the value of 500 ppmv except when
monitoring a seal around a rotating shaft that passes through a
cover opening, in which case the comparison must be as specified
in subsection (d)(9) of this Section. If the difference is less than
500 ppmv, then the potential leak interface is determined to
operate with no detectable organic emissions.
9)
For the seals around a rotating shaft that passes through a cover
opening, the arithmetic difference between the maximum organic
concentration indicated by the instrument and the background
level must be compared with the value of 10,000 ppmw. If the
difference is less than 10,000 ppmw, then the potential leak
interface is determined to operate with no detectable organic
emissions.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 725.985
Standards: Tanks
a) This Section applies to owners and operators of tanks subject to this
Subpart into which any hazardous waste is placed except for the
following tanks:
1) A tank in which all hazardous waste entering the tank meets the
conditions specified in Section 725.983(c); or
396
2) A tank used for biological treatment of hazardous waste in
accordance with the requirements of Section 725.983(c)(2)(D).
a)
The provisions of this Section apply to the control of air pollutant
emissions from tanks for which Section 725.983(b) references the use of
this Section for such air emission control.
b)
The owner or operator shall place the hazardous waste into one of the
following tankscontrol air pollutant emissions from each tank subject to
this Section in accordance with the following requirements, as
applicable:
1) A tank equipped with a cover (e.g., a fixed roof) that is vented
through a closed-vent system to a control device in accordance
with the requirements specified in subsection (d) below;
2) A tank equipped with a fixed roof and internal floating roof in
accordance with the requirements of Section 725.991;
3) A tank equipped with an external floating roof in accordance with
the requirements of Section 725.991; or
4) A pressure tank that is designed to operate as a closed system
such that the tank operates with no detectable organic emissions
at all times that hazardous waste is in the tank except as provided
for in subsection (g) below.
c) As an alternative to complying with subsection (b) above, an owner or
operator may place hazardous waste in a tank equipped with a cover
(e.g., a fixed roof) meeting the requirements specified in subsection
(d)(1) below when the hazardous waste is determined to meet all of the
following conditions:
1) The hazardous waste is neither mixed, stirred, agitated, nor
circulated within the tank by the owner or operator using a
process that results in splashing, frothing, or visible turbulent
flow on the waste surface during normal process operations;
2) The hazardous waste in the tank is not heated by the owner or
operator except during conditions requiring that the waste be
heated to prevent the waste from freezing or to maintain adequate
waste flow conditions for continuing normal process operations;
397
3) The hazardous waste in the tank is not treated by the owner or
operator using a waste stabilization process or a process that
produces an exothermic reaction; and
4) The maximum organic vapor pressure of the hazardous waste in
the tank as determined using the procedure specified in Section
725.984(c) is less than the following applicable value:
1)
For a tank that manages hazardous waste which meets all of the
conditions specified in subsections (b)(1)(A) through (b)(1)(C) of
this Section, the owner or operator shall control air pollutant
emissions from the tank in accordance with the Tank Level 1
controls specified in subsection (c) of this Section or the Tank
Level 2 controls specified in subsection (d) of this Section.
A)
The hazardous waste in the tank has a maximum organic
vapor pressure that is less than the maximum organic
vapor pressure limit for the tank’s design capacity
category, as follows:
Ai)
If theFor a tank design capacity is equal to or
greater than 151 m
3
(5333 ft
3
or 39,887 gal), then
the maximum organic vapor pressure must be less
thanlimit for the tank is 5.2 kPa (0.75 psia or 39
mm Hg);
Bii)
If theFor a tank design capacity is equal to or
greater than 75 m
3
(2649 ft
3
or 19,810 gal) but less
than 151 m
3
(5333 ft
3
or 39,887 gal), then the
maximum organic vapor pressure must be less
thanlimit for the tank is 27.6 kPa (4.0 psia or 207
mm Hg); or
Ciii)
If theFor a tank design capacity is less than 75 m
3
(2649 ft
3
or 19,810 gal), then the maximum
organic vapor pressure then the maximum organic
vapor pressure must be less thanlimit for the tank
is 76.6 kPa (11.1 psia or 574 mm Hg).
d) To comply with subsection (b)(1) above, the owner or operator shall
design, install, operate, and maintain a cover that vents the organic
vapors emitted from hazardous waste in the tank through a closed-vent
system connected to a control device.
398
1) The cover must be designed and operated to meet the following
requirements:
A) The cover and all cover openings (e.g., access hatches,
sampling ports, and gauge wells) must be designed to
operate with no detectable organic emissions when all
cover openings are secured in a closed, sealed position.
B) Each cover opening must be secured in a closed, sealed
position (e.g., covered by a gasketed lid or cap) at all
times that hazardous waste is in the tank except as
provided for in subsection (f) below.
2) The closed-vent system and control device must be designed and
operated in accordance with the requirements of Section 725.988.
e) The owner and operator shall install, operate, and maintain enclosed
pipes or other closed systems for the transfer of hazardous waste as
described in subsection (e)(1) or (e)(2) below.
BOARD NOTE: U.S. EPA considers a drain system that meets the
requirements of 40 CFR 61.346(a)(1) or (b)(1) through (b)(3) to be a
“closed-system”. The Board intends that this meaning be included in the
use of that term for the purposes of this Subpart.
1) Transfer all hazardous waste to the tank from another tank,
surface impoundment, or container subject to this Subpart, except
for those hazardous wastes that meet the conditions specified in
Section 725.983(c); and
2) Transfer all hazardous waste from the tank to another tank,
surface impoundment, or container subject to this Subpart, except
for those hazardous wastes that meet the conditions specified in
Section 725.983(c).
f) Each cover opening must be secured in a closed, sealed position (e.g.,
covered by a gasketed lid) at all times that hazardous waste is in the tank
except when it is necessary to use the cover opening to:
1) Add, remove, inspect, or sample the material in the tank;
2) Inspect, maintain, repair, or replace equipment located inside the
tank; or
399
3) Vent gases or vapors from the tank to a closed-vent system
connected to a control device that is designed and operated in
accordance with the requirements of Section 725.988.
g) One or more safety devices that vent directly to the atmosphere may be
used on the tank, cover, closed-vent system, or control device provided
each safety device meets all of the following conditions:
1) The safety device is not used for planned or routine venting of
organic vapors from the tank or the closed-vent system connected
to a control device; and
2) The safety device remains in a closed, sealed position at all times
except when an unplanned event requires that the device open for
the purpose of preventing physical damage or permanent
deformation of the tank, cover, closed-vent system, or control
device in accordance with good engineering and safety practices
for handling flammable, combustible, explosive, or other
hazardous materials. An example of an unplanned event is a
sudden power outage.
B)
The hazardous waste in the tank is not heated by the
owner or operator to a temperature that is greater than the
temperature at which the maximum organic vapor
pressure of the hazardous waste is determined for the
purpose of complying with subsection (b)(1)(A) of this
Section.
C)
The hazardous waste in the tank is not treated by the
owner or operator using a waste stabilization process, as
defined in Section 725.981.
2)
For a tank that manages hazardous waste that does not meet all of
the conditions specified in subsections (b)(1)(A) through
(b)(1)(C) of this Section, the owner or operator shall control air
pollutant emissions from the tank by using Tank Level 2 controls
in accordance with the requirements of subsection (d) of this
Section. Examples of tanks required to use Tank Level 2
controls include the following: a tank used for a waste
stabilization process and a tank for which the hazardous waste in
the tank has a maximum organic vapor pressure that is equal to or
greater than the maximum organic vapor pressure limit for the
tank’s design capacity category, as specified in subsection
(b)(1)(A) of this Section.
400
c)
Owners and operators controlling air pollutant emissions from a tank
using Tank Level 1 controls shall meet the requirements specified in
subsections (c)(1) through (c)(4) of this Section:
1)
The owner or operator shall determine the maximum organic
vapor pressure for a hazardous waste to be managed in the tank
using Tank Level 1 controls before the first time the hazardous
waste is placed in the tank. The maximum organic vapor
pressure must be determined using the procedures specified in
Section 725.984(c). Thereafter, the owner or operator shall
perform a new determination whenever changes to the hazardous
waste managed in the tank could potentially cause the maximum
organic vapor pressure to increase to a level that is equal to or
greater than the maximum organic vapor pressure limit for the
tank design capacity category specified in subsection (b)(1)(A) of
this Section, as applicable to the tank.
2)
The tank must be equipped with a fixed roof designed to meet the
following specifications:
A)
The fixed roof and its closure devices must be designed to
form a continuous barrier over the entire surface area of
the hazardous waste in the tank. The fixed roof may be a
separate cover installed on the tank (e.g., a removable
cover mounted on an open-top tank) or may be an integral
part of the tank structural design (e.g., a horizontal
cylindrical tank equipped with a hatch).
B)
The fixed roof must be installed in a manner such that
there are no visible cracks, holes, gaps, or other open
spaces between roof Section joints or between the
interface of the roof edge and the tank wall.
C)
Each opening in the fixed roof must be either:
i)
Equipped with a closure device designed to operate
such that when the closure device is secured in the
closed position there are no visible cracks, holes,
gaps, or other open spaces in the closure device or
between the perimeter of the opening and the
closure device; or
ii)
Connected by a closed-vent system that is vented
to a control device. The control device must
remove or destroy organics in the vent stream, and
401
it must be operating whenever hazardous waste is
managed in the tank.
D)
The fixed roof and its closure devices must be made of
suitable materials that will minimize exposure of the
hazardous waste to the atmosphere, to the extent practical,
and which will maintain the integrity of the fixed roof and
closure devices throughout their intended service life.
Factors to be considered when selecting the materials for
and designing the fixed roof and closure devices must
include the following: organic vapor permeability; the
effects of any contact with the hazardous waste or its
vapors managed in the tank; the effects of outdoor
exposure to wind, moisture, and sunlight; and the
operating practices used for the tank on which the fixed
roof is installed.
3)
Whenever a hazardous waste is in the tank, the fixed roof must
be installed with each closure device secured in the closed
position, except as follows:
A)
Opening of closure devices or removal of the fixed roof is
allowed at the following times:
i)
To provide access to the tank for performing
routine inspection, maintenance, or other activities
needed for normal operations. Examples of such
activities include those times when a worker needs
to open a port to sample the liquid in the tank, or
when a worker needs to open a hatch to maintain
or repair equipment. Following completion of the
activity, the owner or operator shall promptly
secure the closure device in the closed position or
reinstall the cover, as applicable, to the tank.
ii)
To remove accumulated sludge or other residues
from the bottom of tank.
B)
Opening of a spring-loaded pressure-vacuum relief valve,
conservation vent, or similar type of pressure relief device
which vents to the atmosphere is allowed during normal
operations for the purpose of maintaining the tank internal
pressure in accordance with the tank design specifications.
The device must be designed to operate with no detectable
organic emissions when the device is secured in the closed
402
position. The settings at which the device opens must be
established such that the device remains in the closed
position whenever the tank internal pressure is within the
internal pressure operating range determined by the owner
or operator based on the tank manufacturer
recommendations; applicable regulations; fire protection
and prevention codes; standard engineering codes and
practices; or other requirements for the safe handling of
flammable, ignitable, explosive, reactive, or hazardous
materials. Examples of normal operating conditions that
may require these devices to open are during those times
when the tank internal pressure exceeds the internal
pressure operating range for the tank as a result of loading
operations or diurnal ambient temperature fluctuations.
C)
Opening of a safety device, as defined in Section 725.981,
is allowed at any time conditions require doing so to avoid
an unsafe condition.
4)
The owner or operator shall inspect the air emission control
equipment in accordance with the following requirements.
A)
The fixed roof and its closure devices must be visually
inspected by the owner or operator to check for defects
that could result in air pollutant emissions. Defects
include, but are not limited to, visible cracks, holes, or
gaps in the roof Sections or between the roof and the tank
wall; broken, cracked, or otherwise damaged seals or
gaskets on closure devices; and broken or missing
hatches, access covers, caps, or other closure devices.
B)
The owner or operator shall perform an initial inspection
of the fixed roof and its closure devices on or before the
date that the tank becomes subject to this Section.
Thereafter, the owner or operator shall perform the
inspections at least once every year, except under the
special conditions provided for in subsection (l) of this
Section.
C)
In the event that a defect is detected, the owner or
operator shall repair the defect in accordance with the
requirements of subsection (k) of this Section.
403
D)
The owner or operator shall maintain a record of the
inspection in accordance with the requirements specified
in Section 725.990(b).
d)
Owners and operators controlling air pollutant emissions from a tank
using Tank Level 2 controls shall use one of the following tanks:
1)
A fixed-roof tank equipped with an internal floating roof in
accordance with the requirements specified in subsection (e) of
this Section;
2)
A tank equipped with an external floating roof in accordance with
the requirements specified in subsection (f) of this Section;
3)
A tank vented through a closed-vent system to a control device in
accordance with the requirements specified in subsection (g) of
this Section;
4)
A pressure tank designed and operated in accordance with the
requirements specified in subsection (h) of this Section; or
5)
A tank located inside an enclosure that is vented through a
closed-vent system to an enclosed combustion control device in
accordance with the requirements specified in subsection (i) of
this Section.
e)
The owner or operator that controls air pollutant emissions from a tank
using a fixed-roof with an internal floating roof shall meet the
requirements specified in subsections (e)(1) through (e)(3) of this
Section.
1)
The tank must be equipped with a fixed roof and an internal
floating roof in accordance with the following requirements:
A)
The internal floating roof must be designed to float on the
liquid surface except when the floating roof must be
supported by the leg supports.
B)
The internal floating roof must be equipped with a
continuous seal between the wall of the tank and the
floating roof edge that meets either of the following
requirements:
404
i)
A single continuous seal that is either a liquid-
mounted seal or a metallic shoe seal, as defined in
Section 725.981; or
ii)
Two continuous seals mounted one of this Section
the other. The lower seal may be a vapor-mounted
seal.
C)
The internal floating roof must meet the following
specifications:
i)
Each opening in a noncontact internal floating roof
except for automatic bleeder vents (vacuum
breaker vents) and the rim space vents is to
provide a projection below the liquid surface.
ii)
Each opening in the internal floating roof must be
equipped with a gasketed cover or a gasketed lid
except for leg sleeves, automatic bleeder vents,
rim space vents, column wells, ladder wells,
sample wells, and stub drains.
iii)
Each penetration of the internal floating roof for
the purpose of sampling must have a slit fabric
cover that covers at least 90% of the opening.
iv)
Each automatic bleeder vent and rim space vent
must be gasketed.
v)
Each penetration of the internal floating roof that
allows for passage of a ladder must have a
gasketed sliding cover.
vi)
Each penetration of the internal floating roof that
allows for passage of a column supporting the
fixed roof must have a flexible fabric sleeve seal
or a gasketed sliding cover.
2)
The owner or operator shall operate the tank in accordance with
the following requirements:
A)
When the floating roof is resting on the leg supports, the
process of filling, emptying, or refilling must be
continuous and must be completed as soon as practical.
405
B)
Automatic bleeder vents are to be set closed at all times
when the roof is floating, except when the roof is being
floated off or is being landed on the leg supports.
C)
Prior to filling the tank, each cover, access hatch, gauge
float well or lid on any opening in the internal floating
roof must be bolted or fastened closed (i.e., no visible
gaps). Rim space vents are to be set to open only when
the internal floating roof is not floating or when the
pressure beneath the rim exceeds the manufacturer’s
recommended setting.
3)
The owner or operator shall inspect the internal floating roof in
accordance with the procedures specified as follows:
A)
The floating roof and its closure devices must be visually
inspected by the owner or operator to check for defects
that could result in air pollutant emissions. Defects
include, but are not limited to, the following: when the
internal floating roof is not floating on the surface of the
liquid inside the tank; when liquid has accumulated on top
of the internal floating roof; when any portion of the roof
seals have detached from the roof rim; when holes, tears,
or other openings are visible in the seal fabric; when the
gaskets no longer close off the hazardous waste surface
from the atmosphere; or when the slotted membrane has
more than 10% open area.
B)
The owner or operator shall inspect the internal floating
roof components as follows, except as provided in
subsection (e)(3)(C) of this Section:
i)
Visually inspect the internal floating roof
components through openings on the fixed-roof
(e.g., manholes and roof hatches) at least once
every 12 months after initial fill, and
ii)
Visually inspect the internal floating roof, primary
seal, secondary seal (if one is in service), gaskets,
slotted membranes, and sleeve seals (if any) each
time the tank is emptied and degassed and at least
once every 10 years.
C)
As an alternative to performing the inspections specified
in subsection (e)(3)(B) of this Section for an internal
406
floating roof equipped with two continuous seals mounted
one above the other, the owner or operator may visually
inspect the internal floating roof, primary and secondary
seals, gaskets, slotted membranes, and sleeve seals (if
any) each time the tank is emptied and degassed and at
least every five years.
D)
Prior to each inspection required by subsection (e)(3)(B)
or (e)(3)(C) of this Section, the owner or operator shall
notify the Agency in advance of each inspection to
provide the Agency with the opportunity to have an
observer present during the inspection. The owner or
operator shall notify the Agency of the date and location
of the inspection as follows:
i)
Prior to each visual inspection of an internal
floating roof in a tank that has been emptied and
degassed, written notification must be prepared
and sent by the owner or operator so that it is
received by the Agency at least 30 calendar days
before refilling the tank, except when an
inspection is not planned, as provided for in
subsection (e)(3)(D)(ii) of this Section.
ii)
When a visual inspection is not planned and the
owner or operator could not have known about the
inspection 30 calendar days before refilling the
tank, the owner or operator shall notify the
Agency as soon as possible, but no later than seven
calendar days before refilling of the tank. This
notification may be made by telephone and
immediately followed by a written explanation for
why the inspection is unplanned. Alternatively,
written notification, including the explanation for
the unplanned inspection, may be sent so that it is
received by the Regional Administrator at least
seven calendar days before refilling the tank.
E)
In the event that a defect is detected, the owner or
operator shall repair the defect in accordance with the
requirements of subsection (k) of this Section.
F)
The owner or operator shall maintain a record of the
inspection in accordance with the requirements specified
in Section 725.990(b).
407
f)
The owner or operator that controls air pollutant emissions from a tank
using an external floating roof shall meet the requirements specified in
subsections (f)(1) through (f)(3) of this Section.
1)
The owner or operator shall design the external floating roof in
accordance with the following requirements:
A)
The external floating roof must be designed to float on the
liquid surface except when the floating roof must be
supported by the leg supports.
B)
The floating roof must be equipped with two continuous
seals, one above the other, between the wall of the tank
and the roof edge. The lower seal is referred to as the
primary seal, and the upper seal is referred to as the
secondary seal.
i)
The primary seal must be a liquid-mounted seal or
a metallic shoe seal, as defined in Section
725.981. The total area of the gaps between the
tank wall and the primary seal must not exceed
212 square centimeters (cm
2
) per meter (10.0 in
2
per foot) of tank diameter, and the width of any
portion of these gaps must not exceed 3.8
centimeters (cm) (1.5 inches). If a metallic shoe
seal is used for the primary seal, the metallic shoe
seal must be designed so that one end extends into
the liquid in the tank and the other end extends a
vertical distance of at least 61 centimeters above
the liquid surface.
ii)
The secondary seal must be mounted above the
primary seal and cover the annular space between
the floating roof and the wall of the tank. The total
area of the gaps between the tank wall and the
secondary seal must not exceed 21.2 cm
2
per meter
(1.0 in
2
per foot) of tank diameter, and the width
of any portion of these gaps must not exceed 1.3
cm (0.5 inch).
C)
The external floating roof must meet the following
specifications:
408
i)
Except for automatic bleeder vents (vacuum
breaker vents) and rim space vents, each opening
in a noncontact external floating roof must provide
a projection below the liquid surface.
ii)
Except for automatic bleeder vents, rim space
vents, roof drains, and leg sleeves, each opening
in the roof must be equipped with a gasketed
cover, seal, or lid.
iii)
Each access hatch and each gauge float well must
be equipped with a cover designed to be bolted or
fastened when the cover is secured in the closed
position.
iv)
Each automatic bleeder vent and each rim space
vent must be equipped with a gasket.
v)
Each roof drain that empties into the liquid
managed in the tank must be equipped with a
slotted membrane fabric cover that covers at least
90% of the area of the opening.
vi)
Each unslotted and slotted guide pole well must be
equipped with a gasketed sliding cover or a
flexible fabric sleeve seal.
vii)
Each unslotted guide pole must be equipped with a
gasketed cap on the end of the pole.
viii)
Each slotted guide pole must be equipped with a
gasketed float or other device which closes off the
liquid surface from the atmosphere.
ix)
Each gauge hatch and each sample well must be
equipped with a gasketed cover.
2)
The owner or operator shall operate the tank in accordance with
the following requirements:
A)
When the floating roof is resting on the leg supports, the
process of filling, emptying, or refilling must be
continuous and must be completed as soon as practical.
409
B)
Except for automatic bleeder vents, rim space vents, roof
drains, and leg sleeves, each opening in the roof must be
secured and maintained in a closed position at all times
except when the closure device must be open for access.
C)
Covers on each access hatch and each gauge float well
must be bolted or fastened when secured in the closed
position.
D)
Automatic bleeder vents must be set closed at all times
when the roof is floating, except when the roof is being
floated off or is being landed on the leg supports.
E)
Rim space vents must be set to open only at those times
that the roof is being floated off the roof leg supports or
when the pressure beneath the rim seal exceeds the
manufacturer’s recommended setting.
F)
The cap on the end of each unslotted guide pole must be
secured in the closed position at all times except when
measuring the level or collecting samples of the liquid in
the tank.
G)
The cover on each gauge hatch or sample well must be
secured in the closed position at all times except when the
hatch or well must be opened for access.
H)
Both the primary seal and the secondary seal must
completely cover the annular space between the external
floating roof and the wall of the tank in a continuous
fashion except during inspections.
3)
The owner or operator shall inspect the external floating roof in
accordance with the procedures specified as follows:
A)
The owner or operator shall measure the external floating
roof seal gaps in accordance with the following
requirements:
i)
The owner or operator shall perform measurements
of gaps between the tank wall and the primary seal
within 60 calendar days after initial operation of
the tank following installation of the floating roof
and, thereafter, at least once every five years.
410
ii)
The owner or operator shall perform measurements
of gaps between the tank wall and the secondary
seal within 60 calendar days after initial operation
of the tank following installation of the floating
roof and, thereafter, at least once every year.
iii)
If a tank ceases to hold hazardous waste for a
period of one year or more, subsequent
introduction of hazardous waste into the tank must
be considered an initial operation for the purposes
of subsections (f)(3)(A)(i) and (f)(3)(A)(ii) of this
Section.
iv)
The owner or operator shall determine the total
surface area of gaps in the primary seal and in the
secondary seal individually using the procedure set
forth in subsection (f)(4)(D) of this Section.
v)
In the event that the seal gap measurements do not
conform to the specifications in subsection
(f)(1)(B) of this Section, the owner or operator
must repair the defect in accordance with the
requirements of subsection (k) of this Section.
vi)
The owner or operator shall maintain a record of
the inspection in accordance with the requirements
specified in Section 725.990(b).
B)
The owner or operator shall visually inspect the external
floating roof in accordance with the following
requirements:
i)
The floating roof and its closure devices must be
visually inspected by the owner or operator to
check for defects that could result in air pollutant
emissions. Defects include, but are not limited to
any of the following: holes, tears, or other
openings in the rim seal or seal fabric of the
floating roof; a rim seal detached from the floating
roof; all or a portion of the floating roof deck
being submerged of this Section the surface of the
liquid in the tank; broken, cracked, or otherwise
damaged seals or gaskets on closure devices; and
broken or missing hatches, access covers, caps, or
other closure devices.
411
ii)
The owner or operator shall perform an initial
inspection of the external floating roof and its
closure devices on or before the date that the tank
becomes subject to this Section. Thereafter, the
owner or operator shall perform the inspections at
least once every year except for the special
conditions provided for in subsection (l) of this
Section.
iii)
In the event that a defect is detected, the owner or
operator shall repair the defect in accordance with
the requirements of subsection (k) of this Section.
iv)
The owner or operator shall maintain a record of
the inspection in accordance with the requirements
specified in Section 725.990(b).
C)
Prior to each inspection required by subsection (f)(3)(A)
or (f)(3)(B) of this Section, the owner or operator shall
notify the Agency in advance of each inspection to
provide the Agency with the opportunity to have an
observer present during the inspection. The owner or
operator shall notify the Agency of the date and location
of the inspection as follows:
i)
Prior to each inspection to measure external
floating roof seal gaps as required under subsection
(f)(3)(A) of this Section, written notification must
be prepared and sent by the owner or operator so
that it is received by the Agency at least 30
calendar days before the date the measurements are
scheduled to be performed.
ii)
Prior to each visual inspection of an external
floating roof in a tank that has been emptied and
degassed, written notification must be prepared
and sent by the owner or operator so that it is
received by the Agency at least 30 calendar days
before refilling the tank except when an inspection
is not planned, as provided for in subsection
(f)(3)(C)(iii) of this Section.
iii)
When a visual inspection is not planned and the
owner or operator could not have known about the
412
inspection 30 calendar days before refilling the
tank, the owner or operator shall notify the
Agency as soon as possible, but no later than seven
calendar days before refilling of the tank. This
notification may be made by telephone and
immediately followed by a written explanation for
why the inspection is unplanned. Alternatively,
written notification, including the explanation for
the unplanned inspection, may be sent so that it is
received by the Regional Administrator at least
seven calendar days before refilling the tank.
D)
Procedure for determining gaps in the primary seal and in
the secondary seal for the purposes of subsection
(f)(3)(A)(iv) of this Section:
i)
The seal gap measurements must be performed at
one or more floating roof levels when the roof is
floating off the roof supports.
ii)
Seal gaps, if any, must be measured around the
entire perimeter of the floating roof in each place
where a 0.32-cm (_-inch) diameter uniform probe
passes freely (without forcing or binding against
the seal) between the seal and the wall of the tank
and measure the circumferential distance of each
such location.
iii)
For a seal gap measured under this subsection
(f)(3), the gap surface area must be determined by
using probes of various widths to measure
accurately the actual distance from the tank wall to
the seal and multiplying each such width by its
respective circumferential distance.
iv)
The total gap area must be calculated by adding
the gap surface areas determined for each
identified gap location for the primary seal and the
secondary seal individually, and then dividing the
sum for each seal type by the nominal perimeter of
the tank. These total gap areas for the primary
seal and secondary seal are then are compared to
the respective standards for the seal type, as
specified in subsection (f)(1)(B) of this Section.
413
BOARD NOTE: Subsections (f)(3)(D)(i) through
(f)(3)(D)(iv) correspond with 40 CFR
265.1085(f)(3)(i)(D)(1) through (f)(3)(i)(D)(4),
which the Board has codified here to comport with
Illinois Administrative Code format requirements.
g)
The owner or operator that controls air pollutant emissions from a tank
by venting the tank to a control device shall meet the requirements
specified in subsections (g)(1) through (g)(3) of this Section.
1)
The tank must be covered by a fixed roof and vented directly
through a closed-vent system to a control device in accordance
with the following requirements:
A)
The fixed roof and its closure devices must be designed to
form a continuous barrier over the entire surface area of
the liquid in the tank.
B)
Each opening in the fixed roof not vented to the control
device must be equipped with a closure device. If the
pressure in the vapor headspace underneath the fixed roof
is less than atmospheric pressure when the control device
is operating, the closure devices must be designed to
operate such that when the closure device is secured in the
closed position there are no visible cracks, holes, gaps, or
other open spaces in the closure device or between the
perimeter of the cover opening and the closure device. If
the pressure in the vapor headspace underneath the fixed
roof is equal to or greater than atmospheric pressure when
the control device is operating, the closure device must be
designed to operate with no detectable organic emissions.
C)
The fixed roof and its closure devices must be made of
suitable materials that will minimize exposure of the
hazardous waste to the atmosphere, to the extent practical,
and will maintain the integrity of the fixed roof and
closure devices throughout their intended service life.
Factors to be considered when selecting the materials for
and designing the fixed roof and closure devices must
include the following: organic vapor permeability; the
effects of any contact with the liquid and its vapor
managed in the tank; the effects of outdoor exposure to
wind, moisture, and sunlight; and the operating practices
used for the tank on which the fixed roof is installed.
414
D)
The closed-vent system and control device must be
designed and operated in accordance with the
requirements of Section 725.988.
2)
Whenever a hazardous waste is in the tank, the fixed roof must
be installed with each closure device secured in the closed
position and the vapor headspace underneath the fixed roof
vented to the control device except as follows:
A)
Venting to the control device is not required, and opening
of closure devices or removal of the fixed roof is allowed
at the following times:
i)
To provide access to the tank for performing
routine inspection, maintenance, or other activities
needed for normal operations. Examples of such
activities include those times when a worker needs
to open a port to sample liquid in the tank, or
when a worker needs to open a hatch to maintain
or repair equipment. Following completion of the
activity, the owner or operator shall promptly
secure the closure device in the closed position or
reinstall the cover, as applicable, to the tank.
ii)
To remove accumulated sludge or other residues
from the bottom of a tank.
B)
Opening of a safety device, as defined in Section 725.981,
is allowed at any time conditions require doing so to avoid
an unsafe condition.
3)
The owner or operator shall inspect and monitor the air emission
control equipment in accordance with the following procedures:
A)
The fixed roof and its closure devices must be visually
inspected by the owner or operator to check for defects
that could result in air pollutant emissions. Defects
include, but are not limited to any of the following:
visible cracks, holes, or gaps in the roof sections or
between the roof and the tank wall; broken, cracked, or
otherwise damaged seals or gaskets on closure devices;
and broken or missing hatches, access covers, caps, or
other closure devices.
415
B)
The closed-vent system and control device must be
inspected and monitored by the owner or operator in
accordance with the procedures specified in Section
725.988.
C)
The owner or operator shall perform an initial inspection
of the air emission control equipment on or before the
date that the tank becomes subject to this Section.
Thereafter, the owner or operator shall perform the
inspections at least once every year except for the special
conditions provided for in subsection (l) of this Section.
D)
In the event that a defect is detected, the owner or
operator shall repair the defect in accordance with the
requirements of subsection (k) of this Section.
E)
The owner or operator shall maintain a record of the
inspection in accordance with the requirements specified
in Section 725.990(b).
h)
The owner or operator that controls air pollutant emissions by using a
pressure tank must meet the following requirements.
1)
The tank shall be designed not to vent to the atmosphere as a
result of compression of the vapor headspace in the tank during
filling of the tank to its design capacity.
2)
All tank openings must be equipped with closure devices
designed to operate with no detectable organic emissions as
determined using the procedure specified in Section 725.984(d).
3)
Whenever a hazardous waste is in the tank, the tank must be
operated as a closed system that does not vent to the atmosphere
except in the event that a safety device, as defined in Section
725.981, is required to open to avoid an unsafe condition.
i)
The owner or operator that controls air pollutant emissions by using an
enclosure vented through a closed-vent system to an enclosed combustion
control device shall meet the requirements specified in subsections (i)(1)
through (i)(4) of this Section.
1)
The tank must be located inside an enclosure. The enclosure
must be designed and operated in accordance with the criteria for
a permanent total enclosure, as specified in “Procedure T--
Criteria for and Verification of a Permanent or Temporary Total
416
Enclosure” under 40 CFR 52.741, appendix B, incorporated by
reference in 35 Ill. Adm. Code 720.111. The enclosure may
have permanent or temporary openings to allow worker access;
passage of material into or out of the enclosure by conveyor,
vehicles, or other mechanical means; entry of permanent
mechanical or electrical equipment; or direct airflow into the
enclosure. The owner or operator shall perform the verification
procedure for the enclosure as specified in Section 5.0 to
“Procedure T--Criteria for and Verification of a Permanent or
Temporary Total Enclosure” initially when the enclosure is first
installed and, thereafter, annually.
2)
The enclosure must be vented through a closed-vent system to an
enclosed combustion control device that is designed and operated
in accordance with the standards for either a vapor incinerator,
boiler, or process heater specified in Section 725.988.
3)
Safety devices, as defined in Section 725.981, may be installed
and operated as necessary on any enclosure, closed-vent system,
or control device used to comply with the requirements of
subsections (i)(1) and (i)(2) of this Section.
4)
The owner or operator shall inspect and monitor the closed-vent
system and control device, as specified in Section 725.988.
j)
The owner or operator shall transfer hazardous waste to a tank subject to
this Section in accordance with the following requirements:
1)
Transfer of hazardous waste, except as provided in subsection
(j)(2) of this Section, to the tank from another tank subject to this
Section or from a surface impoundment subject to Section
725.986 must be conducted using continuous hard-piping or
another closed system that does not allow exposure of the
hazardous waste to the atmosphere. For the purpose of
complying with this provision, an individual drain system is
considered to be a closed system when it meets the requirements
of 40 CFR 63, subpart RR, “National Emission Standards for
Individual Drain Systems”, incorporated by reference in 35 Ill.
Adm. Code 720.111.
2)
The requirements of subsection (j)(1) of this Section do not apply
when transferring a hazardous waste to the tank under any of the
following conditions:
417
A)
The hazardous waste meets the average VO concentration
conditions specified in Section 725.983(c)(1) at the point
of waste origination.
B)
The hazardous waste has been treated by an organic
destruction or removal process to meet the requirements in
Section 725.983(c)(2).
k)
The owner or operator shall repair each defect detected during an
inspection performed in accordance with the requirements of subsections
(c)(4), (e)(3), (f)(3), or (g)(3) of this Section as follows:
1)
The owner or operator shall make first efforts at repair of the
defect no later than five calendar days after detection, and repair
shall be completed as soon as possible but no later than 45
calendar days after detection except as provided in subsection
(k)(2) of this Section.
2)
Repair of a defect may be delayed beyond 45 calendar days if the
owner or operator determines that repair of the defect requires
emptying or temporary removal from service of the tank and no
alternative tank capacity is available at the site to accept the
hazardous waste normally managed in the tank. In this case, the
owner or operator shall repair the defect the next time the process
or unit that is generating the hazardous waste managed in the tank
stops operation. Repair of the defect must be completed before
the process or unit resumes operation.
l)
Following the initial inspection and monitoring of the cover as required
by the applicable provisions of this Subpart, subsequent inspection and
monitoring may be performed at intervals longer than one year under the
following special conditions:
1)
Where inspecting or monitoring the cover would expose a worker
to dangerous, hazardous, or other unsafe conditions, then the
owner or operator may designate a cover as an “unsafe to inspect
and monitor cover” and comply with all of the following
requirements:
A)
Prepare a written explanation for the cover stating the
reasons why the cover is unsafe to visually inspect or to
monitor, if required.
B)
Develop and implement a written plan and schedule to
inspect and monitor the cover, using the procedures
418
specified in the applicable Section of this Subpart, as
frequently as practicable during those times when a
worker can safely access the cover.
2)
In the case when a tank is buried partially or entirely
underground, an owner or operator is required to inspect and
monitor, as required by the applicable provisions of this Section,
only those portions of the tank cover and those connections to the
tank (e.g., fill ports, access hatches, gauge wells, etc.) that are
located on or above the ground surface.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 725.986
Standards: Surface Impoundments
a)
The provisions of this Section appliesy to owners and operators ofthe
control of air pollutant emissions from surface impoundments subject to
this Subpart into which any hazardous waste is placed except for the
following surface impoundments:for which Section 725.983(b) of this
Subpart references the use of this Section for such air emission control.
1) A surface impoundment in which all hazardous waste entering the
surface impoundment meets the conditions specified in Section
725.983(c); or
2) A surface impoundment used for biological treatment of
hazardous waste in accordance with the requirements of Section
725.983(c)(2)(iv).
b)
The owner or operator shall place the hazardous waste into a surface
impoundment equipped with a cover (e.g., an air-supported structure or
a rigid cover) that is vented through a closed-vent system to a control
device meeting the requirements specified in subsection (d)
below.control air pollutant emissions from the surface impoundment by
installing and operating either of the following:
1)
A floating membrane cover in accordance with the provisions
specified in subsection (c) of this Section; or
2)
A cover that is vented through a closed-vent system to a control
device in accordance with the provisions specified in subsection
(d) of this Section.
c) As an alternative to complying with subsection (b) above, an owner or
operator may place hazardous waste in a surface impoundment equipped
419
with a floating membrane cover meeting the requirements specified in
subsection (e) below when the hazardous waste is determined to meet all
of the following conditions:
1) The hazardous waste is neither mixed, stirred, agitated, nor
circulated within the surface impoundment by the owner or
operator using a process that results in splashing, frothing, or
visible turbulent flow on the waste surface during normal process
operations;
2) The hazardous waste in the surface impoundment is not heated by
the owner or operator; and
3) The hazardous waste in the surface impoundment is not treated
by the owner or operator using a waste stabilization process or a
process that produces an exothermic reaction.
d) To comply with subsection (b)(1) above, the owner or operator shall
design, install, operate, and maintain a cover that vents the organic
vapors emitted from hazardous waste in the surface impoundment
through a closed-vent system connected to a control device.
1) The cover must be designed, installed, operated, and maintained
to meet the following requirements:
A) The cover and all cover openings (e.g., access hatches,
sampling ports, and gauge wells) must be designed to
operate with no detectable organic emissions when all
cover openings are secured in a closed, sealed position.
B) Each cover opening must be secured in the closed, sealed
position (e.g., covered by a gasketed lid or cap) at all
times that hazardous waste is in the surface impoundment,
except as provided for in subsection (g) below.
C) The closed-vent system and control device must be
designed and operated in accordance with Section
725.988.
e) To comply with subsection (c) above, the owner or operator shall
design, install, operate, and maintain a floating membrane cover that
meets all of the following requirements:
1) The floating membrane cover must be designed, installed, and
operated such that at all times when hazardous waste is in the
420
surface impoundment, the entire surface area of the hazardous
waste is enclosed by the cover, and any air spaces underneath the
cover are not vented to the atmosphere except during conditions
specified in subsection (h) below.
2) The floating membrane cover and all cover openings (e.g., access
hatches, sampling ports, and gauge wells) must be designed to
operate with no detectable organic emissions when all cover
openings are secured in a closed, sealed position.
3) Each cover opening must be secured in a closed, sealed position
(e.g., covered by a gasketed lid or cap) at all times that
hazardous waste is in the surface impoundment except as
provided for in subsections (g)(1) through (g)(3) below.
4) The synthetic membrane material used for the floating membrane
cover must be either:
A) High density polyethylene with a thickness no less than
2.5 mm; or
B) A material or a composite of different materials
determined to have the following properties:
i) Organic permeability properties that are equivalent
to those of the material specified in subsection
(e)(4)(A) above; and
ii) Chemical and physical properties that maintain the
material integrity for as long as the cover is in use.
Factors that must be considered in selecting the
material include: the effects of contact with the
waste managed in the impoundment, weather
exposure, and cover installation and operation
practices.
f) The owner or operator shall install, operate, and maintain enclosed pipes
or other closed systems for the transfer of hazardous waste as described
in subsection (f)(1) or (f)(2) below.
BOARD NOTE: U.S. EPA considers a drain system that meets the
requirements of 40 CFR 61.346(a)(1) or (b)(1) through (b)(3) to be a
“closed-system”. The Board intends that this meaning be included in the
use of that term for the purposes of this Subpart.
421
1) Transfer all hazardous waste to the surface impoundment from
another tank, surface impoundment, or container subject to this
Subpart, except for those hazardous wastes that meet the
conditions specified in Section 725.983(c); and
2) Transfer all hazardous waste from the surface impoundment to
another tank, surface impoundment, or container subject to this
Subpart, except for those hazardous wastes that meet the
conditions specified in Section 725.983(c).
g) Each cover opening must be secured in the closed, sealed position (e.g.,
covered by a gasketed lid or cap) at all times that hazardous waste is in
the surface impoundment except when it is necessary to use the cover
opening to:
1) Add, remove, inspect, or sample the material in the surface
impoundment;
2) Inspect, maintain, repair, or replace equipment located
underneath the cover;
3) Remove treatment residues from the surface impoundment in
accordance with the requirements of 35 Ill. Adm. Code 728.104;
or
4) Vent gases or vapors from the surface impoundment to a closed-
vent system connected to a control device that is designed and
operated in accordance with the requirements of Section 725.988.
h) One or more safety devices that vent directly to the atmosphere may be
installed on the cover, closed-vent system, or control device provided
each device meets all of the following conditions:
1) The safety device is not used for planned or routine venting of
organic vapors from the surface impoundment or the closed-vent
system connected to a control device; and
2) The safety device remains in a closed, sealed position at all times
except when an unplanned event requires that the device open for
the purpose of preventing physical damage or permanent
deformation of the cover, closed-vent system, or control device
in accordance with good engineering and safety practices for
handling flammable, combustible, explosive, or other hazardous
materials. An example of an unplanned event is a sudden power
outage.
422
c)
The owner or operator that controls air pollutant emissions from a
surface impoundment using a floating membrane cover must meet the
requirements specified in subsections (c)(1) through (c)(3) of this
Section.
1)
The surface impoundment must be equipped with a floating
membrane cover designed to meet the following specifications:
A)
The floating membrane cover must be designed to float on
the liquid surface during normal operations and form a
continuous barrier over the entire surface area of the
liquid.
B)
The cover must be fabricated from a synthetic membrane
material that is either:
i)
High density polyethylene (HDPE) with a
thickness no less than 2.5 millimeters (mm) (0.10
inch); or
ii)
A material or a composite of different materials
determined to have both organic permeability
properties that are equivalent to those of the
material listed in subsection (c)(1)(B)(i) of this
Section and chemical and physical properties that
maintain the material integrity for the intended
service life of the material.
C)
The cover must be installed in a manner such that there
are no visible cracks, holes, gaps, or other open spaces
between cover section seams or between the interface of
the cover edge and its foundation mountings.
D)
Except as provided for in subsection (c)(1)(E) of this
Section, each opening in the floating membrane cover
must be equipped with a closure device so designed as to
operate when that the closure device is secured in the
closed position there are no visible cracks, holes, gaps, or
other open spaces in the closure device or between the
perimeter of the cover opening and the closure device.
E)
The floating membrane cover may be equipped with one
or more emergency cover drains for removal of
stormwater. Each emergency cover drain must be
423
equipped with a slotted membrane fabric cover that covers
at least 90% of the area of the opening or a flexible fabric
sleeve seal.
F)
The closure devices must be made of suitable materials
that will minimize exposure of the hazardous waste to the
atmosphere, to the extent practical, and will maintain the
integrity of the closure devices throughout their intended
service life. Factors to be considered when selecting the
materials of construction and designing the cover and
closure devices must include the following: the organic
vapor permeability; the effects of any contact with the
liquid and its vapor managed in the surface impoundment;
the effects of outdoor exposure to wind, moisture, and
sunlight; and the operating practices used for the surface
impoundment on which the floating membrane cover is
installed.
2)
Whenever a hazardous waste is in the surface impoundment, the
floating membrane cover must float on the liquid and each
closure device must be secured in the closed position except as
follows:
A)
Opening of closure devices or removal of the cover is
allowed at the following times:
i)
To provide access to the surface impoundment for
performing routine inspection, maintenance, or
other activities needed for normal operations.
Examples of such activities include those times
when a worker needs to open a port to sample the
liquid in the surface impoundment, or when a
worker needs to open a hatch to maintain or repair
equipment. Following completion of the activity,
the owner or operator shall promptly replace the
cover and secure the closure device in the closed
position, as applicable.
ii)
To remove accumulated sludge or other residues
from the bottom of surface impoundment.
B)
Opening of a safety device, as defined in Section 725.981,
is allowed at any time conditions require doing so to avoid
an unsafe condition.
424
3)
The owner or operator shall inspect the floating membrane cover
in accordance with the following procedures:
A)
The floating membrane cover and its closure devices must
be visually inspected by the owner or operator to check
for defects that could result in air pollutant emissions.
Defects include, but are not limited to, visible cracks,
holes, or gaps in the cover section seams or between the
interface of the cover edge and its foundation mountings;
broken, cracked, or otherwise damaged seals or gaskets
on closure devices; and broken or missing hatches, access
covers, caps, or other closure devices.
B)
The owner or operator shall perform an initial inspection
of the floating membrane cover and its closure devices on
or before the date that the surface impoundment becomes
subject to this Section. Thereafter, the owner or operator
shall perform the inspections at least once every year
except for the special conditions provided for in
subsection (g) of this Section.
C)
In the event that a defect is detected, the owner or
operator shall repair the defect in accordance with the
requirements of subsection (f) of this Section.
D)
The owner or operator shall maintain a record of the
inspection in accordance with the requirements specified
in Section 725.990(c).
d)
The owner or operator that controls air pollutant emissions from a
surface impoundment using a cover vented to a control device shall meet
the requirements specified in subsections (d)(1) through (d)(3) of this
Section.
1)
The surface impoundment must be covered by a cover and vented
directly through a closed-vent system to a control device in
accordance with the following requirements:
A)
The cover and its closure devices must be designed to
form a continuous barrier over the entire surface area of
the liquid in the surface impoundment.
B)
Each opening in the cover not vented to the control device
must be equipped with a closure device. If the pressure in
the vapor headspace underneath the cover is less than
425
atmospheric pressure when the control device is operating,
the closure devices must be designed to operate such that
when the closure device is secured in the closed position
there are no visible cracks, holes, gaps, or other open
spaces in the closure device or between the perimeter of
the cover opening and the closure device. If the pressure
in the vapor headspace underneath the cover is equal to or
greater than atmospheric pressure when the control device
is operating, the closure device must be designed to
operate with no detectable organic emissions using the
procedure specified in Section 725.984(d).
C)
The cover and its closure devices must be made of
suitable materials that will minimize exposure of the
hazardous waste to the atmosphere, to the extent practical,
and will maintain the integrity of the cover and closure
devices throughout their intended service life. Factors to
be considered when selecting the materials for and
designing the cover and closure devices must include the
following: the organic vapor permeability; the effects of
any contact with the liquid or its vapors managed in the
surface impoundment; the effects of outdoor exposure to
wind, moisture, and sunlight; and the operating practices
used for the surface impoundment on which the cover is
installed.
D)
The closed-vent system and control device must be
designed and operated in accordance with the
requirements of Section 725.988.
2)
Whenever a hazardous waste is in the surface impoundment, the
cover must be installed with each closure device secured in the
closed position and the vapor headspace underneath the cover
vented to the control device except as follows:
A)
Venting to the control device is not required, and opening
of closure devices or removal of the cover is allowed at
the following times:
i)
To provide access to the surface impoundment for
performing routine inspection, maintenance, or
other activities needed for normal operations.
Examples of such activities include those times
when a worker needs to open a port to sample
liquid in the surface impoundment, or when a
426
worker needs to open a hatch to maintain or repair
equipment. Following completion of the activity,
the owner or operator shall promptly secure the
closure device in the closed position or reinstall the
cover, as applicable, to the surface impoundment.
ii)
To remove accumulated sludge or other residues
from the bottom of surface impoundment.
B)
Opening of a safety device, as defined in Section 725.981,
is allowed at any time conditions require doing so to avoid
an unsafe condition.
3)
The owner or operator shall inspect and monitor the air emission
control equipment in accordance with the following procedures:
A)
The surface impoundment cover and its closure devices
must be visually inspected by the owner or operator to
check for defects that could result in air pollutant
emissions. Defects include, but are not limited to, visible
cracks, holes, or gaps in the cover section seams or
between the interface of the cover edge and its foundation
mountings; broken, cracked, or otherwise damaged seals
or gaskets on closure devices; and broken or missing
hatches, access covers, caps, or other closure devices.
B)
The closed-vent system and control device must be
inspected and monitored by the owner or operator in
accordance with the procedures specified in Section
725.988.
C)
The owner or operator shall perform an initial inspection
of the air emission control equipment on or before the
date that the surface impoundment becomes subject to this
Section. Thereafter, the owner or operator shall perform
the inspections at least once every year except for the
special conditions provided for in subsection (g) of this
Section.
D)
In the event that a defect is detected, the owner or
operator shall repair the defect in accordance with the
requirements of subsection (f) of this Section.
427
E)
The owner or operator shall maintain a record of the
inspection in accordance with the requirements specified
in Section 725.990(c).
e)
The owner or operator shall transfer hazardous waste to a surface
impoundment subject to this Section in accordance with the following
requirements:
1)
Transfer of hazardous waste, except as provided in subsection
(e)(2) of this Section, to the surface impoundment from another
surface impoundment subject to this Section or from a tank
subject to Section 725.985 must be conducted using continuous
hard-piping or another closed system that does not allow
exposure of the waste to the atmosphere. For the purpose of
complying with this provision, an individual drain system is
considered to be a closed system when it meets the requirements
of 40 CFR 63, Subpart RR, “National Emission Standards for
Individual Drain Systems”, incorporated by reference in 35 Ill.
Adm. Code 720.111.
2)
The requirements of subsection (e)(1) of this Section do not apply
when transferring a hazardous waste to the surface impoundment
under either of the following conditions:
A)
The hazardous waste meets the average VO concentration
conditions specified in Section 725.983(c)(1) at the point
of waste origination.
B)
The hazardous waste has been treated by an organic
destruction or removal process to meet the requirements in
Section 725.983(c)(2).
f)
The owner or operator shall repair each defect detected during an
inspection performed in accordance with the requirements of subsection
(c)(3) or (d)(3) of this Section as follows:
1)
The owner or operator shall make first efforts at repair of the
defect no later than five calendar days after detection, and repair
must be completed as soon as possible but no later than 45
calendar days after detection except as provided in subsection
(f)(2) of this Section.
2)
Repair of a defect may be delayed beyond 45 calendar days if the
owner or operator determines that repair of the defect requires
emptying or temporary removal from service of the surface
428
impoundment and no alternative capacity is available at the site to
accept the hazardous waste normally managed in the surface
impoundment. In this case, the owner or operator shall repair the
defect the next time the process or unit that is generating the
hazardous waste managed in the tank stops operation. Repair of
the defect must be completed before the process or unit resumes
operation.
g)
Following the initial inspection and monitoring of the cover as required
by the applicable provisions of this Subpart, subsequent inspection and
monitoring may be performed at intervals longer than one year in the
case when inspecting or monitoring the cover would expose a worker to
dangerous, hazardous, or other unsafe conditions. In this case, the
owner or operator may designate the cover as an “unsafe to inspect and
monitor cover” and comply with all of the following requirements:
1)
Prepare a written explanation for the cover stating the reasons
why the cover is unsafe to visually inspect or to monitor, if
required.
2)
Develop and implement a written plan and schedule to inspect
and monitor the cover using the procedures specified in the
applicable Section of this Subpart as frequently as practicable
during those times when a worker can safely access the cover.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 725.987
Standards: Containers
a)
The provisions of this Section appliesy to the owners and operators
ofcontrol of air pollutant emissions from containers having design
capacities greater than 0.1 m
3
(3.5 ft
3
or 26.4 gal) subject to this Subpart
into which any hazardous waste is placed, except for a container in
which all hazardous waste entering the container meets the conditions
specified in Section 725.983(c).for which Section 725.983(b) references
the use of this Section for such air emission control.
b) An owner or operator shall manage hazardous waste in containers using
the following procedures:
1) The owner or operator shall place the hazardous waste into one of
the following containers, except when a container is used for
hazardous waste treatment as required by subsection (b)(2)
below:
429
A) A container that is equipped with a cover that operates
with no detectable organic emissions when all container
openings (e.g., lids, bungs, hatches, and sampling ports)
are secured in a closed, sealed position. The owner or
operator shall determine that a container operates with no
detectable emissions by testing each opening on the
container for leaks in accordance with Method 21 in 40
CFR 60, Appendix A, incorporated by reference in 35 Ill.
Adm. Code 720.111, the first time any portion of the
hazardous waste is placed into the container. If a leak is
detected and cannot be repaired immediately, the
hazardous waste must be removed from the container and
the container not used to meet the requirements of this
subsection until the leak is repaired and the container is
retested.
B) A container having a design capacity less than or equal to
0.46 m
3
(16.2 ft
3
or 121.5 gal) that is equipped with a
cover and complies with all applicable U.S. Department
of Transportation regulations on packaging hazardous
waste for transport under 49 CFR 178, incorporated by
reference in 35 Ill. Adm. Code 720.111.
i) A container that is managed in accordance with the
requirements of 49 CFR 178 for the purpose of
complying with this Subpart is not subject to any
exceptions to the 49 CFR 178 regulations, except
as noted in subsection (b)(1)(B)(ii) above.
ii) A lab pack that is managed in accordance with the
requirements of 49 CFR 178 for the purpose of
complying with this Subpart may comply with the
exceptions for combination packagings specified in
49 CFR 173.12(b).
C) A container that is attached to or forms a part of any
truck, trailer, or railcar and that has been demonstrated
within the preceding 12 months to be organic vapor tight
when all container openings are in a closed, sealed
position (e.g., the container hatches or lids are gasketed
and latched). For the purpose of meeting the
requirements of this subsection, a container is organic
vapor tight if the container sustains a pressure change of
not more than 0.75 kPa (0.11 psig or 5.6 mm Hg) within
5 minutes after it is pressurized to a minimum of 4.5 kPa
430
(0.65 psig or 33.7 mm Hg). This condition is to be
demonstrated using the pressure test specified in Method
27 of 40 CFR 60, Appendix A, incorporated by reference
in 35 Ill. Adm. Code 720.111, and a pressure
measurement device that has a precision of ± 2.5 mm
water and that is capable of measuring above the pressure
at which the container is to be tested for vapor tightness.
2) An owner or operator treating hazardous waste in a container by
either a waste stabilization process, any process that requires the
addition of heat to the waste, or any process that produces an
exothermic reaction must meet the following requirements:
A) Whenever it is necessary for the container to be open
during the treatment process, the container must be
located inside an enclosure that is vented through a
closed-vent system to a control device.
B) The enclosure must be a structure that is designed and
operated in accordance with the following requirements:
i) The enclosure must be a structure that is designed
and operated with sufficient airflow into the
structure to capture the organic vapors emitted
from the hazardous waste in the container and vent
the vapors through the closed-vent system to the
control device.
ii) The enclosure may have permanent or temporary
openings to allow worker access, passage of
containers through the enclosure by conveyor or
other mechanical means, entry of permanent
mechanical or electrical equipment, or to direct
airflow into the enclosure. The pressure drop
across each opening in the enclosure must be
maintained at a pressure below atmospheric
pressure such that whenever an open container is
placed inside the enclosure no organic vapors
released from the container exit the enclosure
through the opening. The owner or operator shall
determine that an enclosure achieves this condition
by measuring the pressure drop across each
opening in the enclosure. If the pressure within
the enclosure is equal to or greater than
431
atmospheric pressure then the enclosure does not
meet the requirements of this Section.
C) The closed-vent system and control device must be
designed and operated in accordance with the
requirements of Section 725.988.
3) An owner or operator transferring hazardous waste into a
container having a design capacity greater than 0.46 m
3
(16.2 ft
3
or 121.5 gal) shall meet the following requirements:
A) Hazardous waste transfer by pumping must be performed
using a conveyance system that uses a tube (e.g., pipe,
hose) to add the waste into the container. During transfer
of the waste into the container, the cover must remain in
place and all container openings must be maintained in a
closed, sealed position except for those openings through
which the tube enters the container and as provided for in
subsection (c) below. The tube must be positioned in a
manner such that either the:
i) Tube outlet continuously remains submerged
below the waste surface at all times waste is
flowing through the tube;
ii) Lower bottom edge of the tube outlet is located at
a distance no greater than two inside diameters of
the tube or 15.25 cm (0.50 ft or 6.0 in), whichever
distance is greater, from the bottom of the
container at all times waste is flowing through the
tube; or
iii) Tube is connected to a permanent port mounted on
the bottom of the container so that the lower edge
of the port opening inside the container is located
at a distance equal to or less than 15.25 cm (0.50
ft or 6.0 in) from the container bottom.
B) Hazardous waste transferred by a means other than
pumping must be performed such that during transfer of
the waste into the container, the cover remains in place
and all container openings are maintained in a closed,
sealed position except for those openings through which
the hazardous waste is added and as provided for in
subsection (d) below.
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c) Each container opening must be maintained in a closed, sealed position
(e.g., covered by a gasketed lid) at all times that hazardous waste is in
the container except when it is necessary to use the opening to:
1) Add, remove, inspect, or sample the material in the container;
2) Inspect, maintain, repair, or replace equipment located inside the
container; or
3) Vent gases or vapors from a cover located over or enclosing an
open container to a closed-vent system connected to a control
device that is designed and operated in accordance with the
requirements of Section 725.988.
d) One or more safety devices that vent directly to the atmosphere may be
used on the container, cover, enclosure, closed-vent system, or control
device provided each device meets all of the following conditions:
1) The safety device is not used for planned or routine venting of
organic vapors from the container, cover, enclosure, or closed-
vent system connected to a control device; and
2) The safety device remains in a closed, sealed position at all times
except when an unplanned event requires that the device open for
the purpose of preventing physical damage or permanent
deformation of the container, cover, enclosure, closed-vent
system, or control device in accordance with good engineering
and safety practices for handling flammable, combustible,
explosive, or other hazardous materials. An example of an
unplanned event is a sudden power outage.
b)
General requirements.
1)
The owner or operator shall control air pollutant emissions from
each container subject to this Section in accordance with the
following requirements, as applicable to the container, except
when the special provisions for waste stabilization processes
specified in subsection (b)(2) of this Section apply to the
container.
A)
For a container having a design capacity greater than 0.1
m
3
(26 gal) and less than or equal to 0.46 m
3
(120 gal),
the owner or operator shall control air pollutant emissions
433
from the container in accordance with the Container Level
1 standards specified in subsection (c) of this Section.
B)
For a container having a design capacity greater than 0.46
m
3
(120 gal) that is not in light material service, the
owner or operator shall control air pollutant emissions
from the container in accordance with the Container Level
1 standards specified in subsection (c) of this Section.
C)
For a container having a design capacity greater than 0.46
m
3
(120 gal) that is in light material service, the owner or
operator shall control air pollutant emissions from the
container in accordance with the Container Level 2
standards specified in subsection (d) of this Section.
2)
When a container having a design capacity greater than 0.1 m
3
(26 gal) is used for treatment of a hazardous waste by a waste
stabilization process, the owner or operator shall control air
pollutant emissions from the container in accordance with the
Container Level 3 standards specified in subsection (e) of this
Section at those times during the waste stabilization process when
the hazardous waste in the container is exposed to the
atmosphere.
c)
Container Level 1 standards.
1)
A container using Container Level 1 controls is one of the
following:
A)
A container that meets the applicable U.S. Department of
Transportation (DOT) regulations on packaging hazardous
materials for transportation, as specified in subsection (f)
of this Section.
B)
A container equipped with a cover and closure devices
that form a continuous barrier over the container openings
so that when the cover and closure devices are secured in
the closed position there are no visible holes, gaps, or
other open spaces into the interior of the container. The
cover may be a separate cover installed on the container
(e.g., a lid on a drum or a suitably secured tarp on a roll-
off box) or may be an integral part of the container
structural design (e.g., a “portable tank” or bulk cargo
container equipped with a screw-type cap).
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C)
An open-top container in which an organic-vapor
suppressing barrier is placed on or over the hazardous
waste in the container such that no hazardous waste is
exposed to the atmosphere. One example of such a
barrier is application of a suitable organic-vapor
suppressing foam.
2)
A container used to meet the requirements of subsection (c)(1)(B)
or (c)(1)(C) of this Section must be equipped with covers and
closure devices, as applicable to the container, that are composed
of suitable materials to minimize exposure of the hazardous waste
to the atmosphere and to maintain the equipment integrity for as
long as it is in service. Factors to be considered in selecting the
materials of construction and designing the cover and closure
devices must include the following: the organic vapor
permeability, the effects of contact with the hazardous waste or
its vapor managed in the container; the effects of outdoor
exposure of the closure device or cover material to wind,
moisture, and sunlight; and the operating practices for which the
container is intended to be used.
3)
Whenever a hazardous waste is in a container using Container
Level 1 controls, the owner or operator shall install all covers
and closure devices for the container, as applicable to the
container, and secure and maintain each closure device in the
closed position except as follows:
A)
Opening of a closure device or cover is allowed for the
purpose of adding hazardous waste or other material to the
container as follows:
i)
In the case when the container is filled to the
intended final level in one continuous operation,
the owner or operator shall promptly secure the
closure devices in the closed position and install
the covers, as applicable to the container, upon
conclusion of the filling operation.
ii)
In the case when discrete quantities or batches of
material intermittently are added to the container
over a period of time, the owner or operator shall
promptly secure the closure devices in the closed
position and install covers, as applicable to the
container, upon either the container being filled to
the intended final level; the completion of a batch
435
loading after which no additional material will be
added to the container within 15 minutes; the
person performing the loading operation leaving
the immediate vicinity of the container; or the
shutdown of the process generating the material
being added to the container, whichever condition
occurs first.
B)
Opening of a closure device or cover is allowed for the
purpose of removing hazardous waste from the container
as follows:
i)
For the purpose of meeting the requirements of
this Section, an empty container, as defined in 35
Ill. Adm. Code 721.107(b), may be open to the
atmosphere at any time (i.e., covers and closure
devices are not required to be secured in the closed
position on an empty container).
ii)
In the case when discrete quantities or batches of
material are removed from the container but the
container does not meet the conditions to be an
empty container, as defined in 35 Ill. Adm. Code
721.107(b), the owner or operator shall promptly
secure the closure devices in the closed position
and install covers, as applicable to the container,
upon the completion of a batch removal after
which no additional material will be removed from
the container within 15 minutes or the person
performing the unloading operation leaves the
immediate vicinity of the container, whichever
condition occurs first.
C)
Opening of a closure device or cover is allowed when
access inside the container is needed to perform routine
activities other than transfer of hazardous waste.
Examples of such activities include those times when a
worker needs to open a port to measure the depth of or
sample the material in the container, or when a worker
needs to open a manhole hatch to access equipment inside
the container. Following completion of the activity, the
owner or operator shall promptly secure the closure
device in the closed position or reinstall the cover, as
applicable to the container.
436
D)
Opening of a spring-loaded, pressure-vacuum relief valve,
conservation vent, or similar type of pressure relief device
which vents to the atmosphere is allowed during normal
operations for the purpose of maintaining the container
internal pressure in accordance with the design
specifications of the container. The device must be
designed to operate with no detectable organic emissions
when the device is secured in the closed position. The
settings at which the device opens must be established
such that the device remains in the closed position
whenever the internal pressure of the container is within
the internal pressure operating range determined by the
owner or operator based on container manufacturer
recommendations, applicable regulations, fire protection
and prevention codes, standard engineering codes and
practices, or other requirements for the safe handling of
flammable, ignitable, explosive, reactive, or hazardous
materials. Examples of normal operating conditions that
may require these devices to open are during those times
when the internal pressure of the container exceeds the
internal pressure operating range for the container as a
result of loading operations or diurnal ambient
temperature fluctuations.
E)
Opening of a safety device, as defined in Section 725.981,
is allowed at any time conditions require doing so to avoid
an unsafe condition.
4)
The owner or operator of containers using Container Level 1
controls must inspect the containers and their covers and closure
devices as follows:
A)
In the case when a hazardous waste already is in the
container at the time the owner or operator first accepts
possession of the container at the facility and the container
is not emptied (i.e., does not meet the conditions for an
empty container as specified in 35 Ill. Adm. Code
721.107(b)) within 24 hours after the container is
accepted at the facility, the owner or operator shall
visually inspect the container and its cover and closure
devices to check for visible cracks, holes, gaps, or other
open spaces into the interior of the container when the
cover and closure devices are secured in the closed
position. If a defect is detected, the owner or operator
437
shall repair the defect in accordance with the requirements
of subsection (c)(4)(C) of this Section.
B)
In the case when a container used for managing hazardous
waste remains at the facility for a period of one year or
more, the owner or operator shall visually inspect the
container and its cover and closure devices initially and
thereafter, at least once every 12 months, to check for
visible cracks, holes, gaps, or other open spaces into the
interior of the container when the cover and closure
devices are secured in the closed position. If a defect is
detected, the owner or operator shall repair the defect in
accordance with the requirements of subsection (c)(4)(C)
of this Section.
C)
When a defect is detected for the container, cover, or
closure devices, the owner or operator shall make first
efforts at repair of the defect no later than 24 hours after
detection, and repair must be completed as soon as
possible but no later than five calendar days after
detection. If repair of a defect cannot be completed
within five calendar days, then the hazardous waste must
be removed from the container and the container must not
be used to manage hazardous waste until the defect is
repaired.
5)
The owner or operator shall maintain at the facility a copy of the
procedure used to determine that containers with capacity of 0.46
m
3
(120 gal) or greater, which do not meet applicable USDOT
regulations as specified in subsection (f) of this Section, are not
managing hazardous waste in light material service.
d)
Container Level 2 standards.
1)
A container using Container Level 2 controls is one of the
following:
A)
A container that meets the applicable U.S. Department of
Transportation (USDOT) regulations on packaging
hazardous materials for transportation as specified in
subsection (f) of this Section.
B)
A container that operates with no detectable organic
emissions, as defined in Section 725.981, and determined
438
in accordance with the procedure specified in subsection
(g) of this Section.
C)
A container that has been demonstrated within the
preceding 12 months to be vapor-tight by using 40 CFR
60, appendix A, Method 27, incorporated by reference in
35 Ill. Adm. Code 720.111, in accordance with the
procedure specified in subsection (h) of this Section.
2)
Transfer of hazardous waste in or out of a container using
Container Level 2 controls must be conducted in such a manner
as to minimize exposure of the hazardous waste to the
atmosphere, to the extent practical, considering the physical
properties of the hazardous waste and good engineering and
safety practices for handling flammable, ignitable, explosive,
reactive or other hazardous materials. Examples of container
loading procedures that the USEPA considers to meet the
requirements of this subsection (d)(2) include using any one of
the following: a submerged-fill pipe or other submerged-fill
method to load liquids into the container; a vapor-balancing
system or a vapor-recovery system to collect and control the
vapors displaced from the container during filling operations; or a
fitted opening in the top of a container through which the
hazardous waste is filled and subsequently purging the transfer
line before removing it from the container opening.
3)
Whenever a hazardous waste is in a container using Container
Level 2 controls, the owner or operator shall install all covers
and closure devices for the container, and secure and maintain
each closure device in the closed position except as follows:
A)
Opening of a closure device or cover is allowed for the
purpose of adding hazardous waste or other material to the
container as follows:
i)
In the case when the container is filled to the
intended final level in one continuous operation,
the owner or operator shall promptly secure the
closure devices in the closed position and install
the covers, as applicable to the container, upon
conclusion of the filling operation.
ii)
In the case when discrete quantities or batches of
material intermittently are added to the container
over a period of time, the owner or operator shall
439
promptly secure the closure devices in the closed
position and install covers, as applicable to the
container, upon either the container being filled to
the intended final level; the completion of a batch
loading after which no additional material will be
added to the container within 15 minutes; the
person performing the loading operation leaving
the immediate vicinity of the container; or the
shutdown of the process generating the material
being added to the container, whichever condition
occurs first.
B)
Opening of a closure device or cover is allowed for the
purpose of removing hazardous waste from the container
as follows:
i)
For the purpose of meeting the requirements of
this Section, an empty container as defined in 35
Ill. Adm. Code 721.107(b) may be open to the
atmosphere at any time (i.e., covers and closure
devices are not required to be secured in the closed
position on an empty container).
ii)
In the case when discrete quantities or batches of
material are removed from the container but the
container does not meet the conditions to be an
empty container as defined in 35 Ill. Adm. Code
721.107(b), the owner or operator shall promptly
secure the closure devices in the closed position
and install covers, as applicable to the container,
upon the completion of a batch removal after
which no additional material will be removed from
the container within 15 minutes or the person
performing the unloading operation leaves the
immediate vicinity of the container, whichever
condition occurs first.
C)
Opening of a closure device or cover is allowed when
access inside the container is needed to perform routine
activities other than transfer of hazardous waste.
Examples of such activities include those times when a
worker needs to open a port to measure the depth of or
sample the material in the container, or when a worker
needs to open a manhole hatch to access equipment inside
the container. Following completion of the activity, the
440
owner or operator shall promptly secure the closure
device in the closed position or reinstall the cover, as
applicable to the container.
D)
Opening of a spring-loaded, pressure-vacuum relief valve,
conservation vent, or similar type of pressure relief device
which vents to the atmosphere is allowed during normal
operations for the purpose of maintaining the internal
pressure of the container in accordance with the container
design specifications. The device must be designed to
operate with no detectable organic emission when the
device is secured in the closed position. The settings at
which the device opens must be established such that the
device remains in the closed position whenever the
internal pressure of the container is within the internal
pressure operating range determined by the owner or
operator based on container manufacturer
recommendations, applicable regulations, fire protection
and prevention codes, standard engineering codes and
practices, or other requirements for the safe handling of
flammable, ignitable, explosive, reactive, or hazardous
materials. Examples of normal operating conditions that
may require these devices to open are during those times
when the internal pressure of the container exceeds the
internal pressure operating range for the container as a
result of loading operations or diurnal ambient
temperature fluctuations.
E)
Opening of a safety device, as defined in Section 725.981,
is allowed at any time conditions require doing so to avoid
an unsafe condition.
4)
The owner or operator of containers using Container Level 2
controls shall inspect the containers and their covers and closure
devices as follows:
A)
In the case when a hazardous waste already is in the
container at the time the owner or operator first accepts
possession of the container at the facility and the container
is not emptied (i.e., does not meet the conditions for an
empty container as specified in 35 Ill. Adm. Code
721.107(b)) within 24 hours after the container arrives at
the facility, the owner or operator shall visually inspect
the container and its cover and closure devices to check
for visible cracks, holes, gaps, or other open spaces into
441
the interior of the container when the cover and closure
devices are secured in the closed position. If a defect is
detected, the owner or operator shall repair the defect in
accordance with the requirements of subsection (d)(4)(C)
of this Section.
B)
In the case when a container used for managing hazardous
waste remains at the facility for a period of one year or
more, the owner or operator shall visually inspect the
container and its cover and closure devices initially and
thereafter, at least once every 12 months, to check for
visible cracks, holes, gaps, or other open spaces into the
interior of the container when the cover and closure
devices are secured in the closed position. If a defect is
detected, the owner or operator shall repair the defect in
accordance with the requirements of subsection (d)(4)(C)
of this Section.
C)
When a defect is detected for the container, cover, or
closure devices, the owner or operator shall make first
efforts at repair of the defect no later than 24 hours after
detection, and repair must be completed as soon as
possible but no later than five calendar days after
detection. If repair of a defect cannot be completed
within five calendar days, then the hazardous waste must
be removed from the container and the container must not
be used to manage hazardous waste until the defect is
repaired.
e)
Container Level 3 standards.
1)
A container using Container Level 3 controls is one of the
following:
A)
A container that is vented directly through a closed-vent
system to a control device in accordance with the
requirements of subsection (e)(2)(B) of this Section.
B)
A container that is vented inside an enclosure which is
exhausted through a closed-vent system to a control device
in accordance with the requirements of subsections
(e)(2)(A) and (e)(2)(B) of this Section.
442
2)
The owner or operator shall meet the following requirements, as
applicable to the type of air emission control equipment selected
by the owner or operator:
A)
The container enclosure must be designed and operated in
accordance with the criteria for a permanent total
enclosure as specified in “Procedure T--Criteria for and
Verification of a Permanent or Temporary Total
Enclosure” under 40 CFR 52.741, appendix B,
incorporated by reference in 35 Ill. Adm. Code 720.111.
The enclosure may have permanent or temporary openings
to allow worker access; passage of containers through the
enclosure by conveyor or other mechanical means; entry
of permanent mechanical or electrical equipment; or direct
airflow into the enclosure. The owner or operator shall
perform the verification procedure for the enclosure as
specified in Section 5.0 to “Procedure T--Criteria for and
Verification of a Permanent or Temporary Total
Enclosure” initially when the enclosure is first installed
and, thereafter, annually.
B)
The closed-vent system and control device must be
designed and operated in accordance with the
requirements of Section 725.988.
3)
Safety devices, as defined in Section 725.981, may be installed
and operated as necessary on any container, enclosure, closed-
vent system, or control device used to comply with the
requirements of subsection (e)(1) of this Section.
4)
Owners and operators using Container Level 3 controls in
accordance with the provisions of this Subpart shall inspect and
monitor the closed-vent systems and control devices, as specified
in Section 725.988.
5)
Owners and operators that use Container Level 3 controls in
accordance with the provisions of this Subpart shall prepare and
maintain the records specified in Section 725.990(d).
f)
For the purpose of compliance with subsection (c)(1)(A) or (d)(1)(A) of
this Section, containers must be used that meet the applicable U.S.
Department of Transportation (USDOT) regulations on packaging
hazardous materials for transportation as follows:
443
1)
The container meets the applicable requirements specified in 49
CFR 178, “Specifications for Packaging”, or 49 CFR 179,
“Specifications for Tank Cars”, both incorporated by reference in
35 Ill. Adm. Code 720.111.
2)
Hazardous waste is managed in the container in accordance with
the applicable requirements specified in 49 CFR 107, subpart B,
“Exemptions”; 49 CFR 172, “Hazardous Materials Table,
Special Provisions, Hazardous Materials Communications,
Emergency Response Information, and Training Requirements”;
49 CFR 173, “Shippers--General Requirements for Shipments
and Packages”; and 49 CFR 180, “Continuing Qualification and
Maintenance of Packagings”, each incorporated by reference in
35 Ill. Adm. Code 720.111.
3)
For the purpose of complying with this Subpart, no exceptions to
the 49 CFR 178 or 179 regulations are allowed, except as
provided for in subsection (f)(4) of this Section.
4)
For a lab pack that is managed in accordance with the
requirements of 49 CFR 178 for the purpose of complying with
this Subpart, an owner or operator may comply with the
exceptions for combination packagings specified in 49 CFR
173.12(b), incorporated by reference in 35 Ill. Adm. Code
720.111.
g)
The owner or operator shall use the procedure specified in Section
725.984(d) for determining a container operates with no detectable
organic emissions for the purpose of complying with subsection (d)(1)(B)
of this Section.
1)
Each potential leak interface (i.e., a location where organic vapor
leakage could occur) on the container, its cover, and associated
closure devices, as applicable to the container, must be checked.
Potential leak interfaces that are associated with containers
include, but are not limited to: the interface of the cover rim and
the container wall; the periphery of any opening on the container
or container cover and its associated closure device; and the
sealing seat interface on a spring-loaded pressure-relief valve.
2)
The test must be performed when the container is filled with a
material having a volatile organic concentration representative of
the range of volatile organic concentrations for the hazardous
wastes expected to be managed in this type of container. During
444
the test, the container cover and closure devices must be secured
in the closed position.
h)
Procedure for determining a container to be vapor-tight using Method 27
of 40 CFR 60, appendix A for the purpose of complying with subsection
(d)(1)(C) of this Section.
1)
The test must be performed in accordance with Method 27 of 40
CFR 60, appendix A, incorporated by reference in 35 Ill. Adm.
Code 720.111.
2)
A pressure measurement device must be used that has a precision
of ±2.5 mm (0.10 inch) water and that is capable of measuring
above the pressure at which the container is to be tested for vapor
tightness.
3)
If the test results determined by Method 27 indicate that the
container sustains a pressure change less than or equal to 750
Pascals (0.11 psig) within five minutes after it is pressurized to a
minimum of 4,500 Pascals (0.65 psig), then the container is
determined to be vapor-tight.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 725.988
Standards: Closed-vent Systems and Control Devices
a)
This Section applies to each closed-vent system and control device
installed and operated by the owner or operator to control air emissions
in accordance with standards of this Subpart.
b)
The closed-vent system must meet the following requirements:
1)
The closed-vent system must route the gases, vapors, and fumes
emitted from the hazardous waste in the waste management unit
to a control device that meets the requirements specified in
subsection (c) belowof this Section.
2)
The closed-vent system must be designed and operated in
accordance with the requirements specified in Section 725.933(j).
3)
IfWhen the closed-vent system contains one or moreincludes
bypass devices that could be used to divert all or a portion of the
gases, or vapors, or fumes from entering the control device, the
owner or operator shall meet the following requirements:stream
to the atmosphere before entering the control device, each bypass
445
device must be equipped with either a flow indicator as specified
in subsection (b)(3)(A) of this Section or a seal or locking device
as specified in subsection (b)(3)(B) of this Section. For the
purpose of complying with this subsection, low leg drains, high
point bleeds, analyzer vents, open-ended valves or lines, spring-
loaded pressure relief valves, and other fittings used for safety
purposes are not considered to be bypass devices.
A) For each bypass device except as provided for in
subsection (b)(3)(B) below, the owner or operator shall
either:
i) Install, calibrate, maintain, and operate a flow
indicator at the inlet to the bypass device that
indicates at least once every 15 minutes whether
gas, vapor, or fume flow is present in the bypass
device; or
ii) Secure the valve installed at the inlet to the bypass
device in the closed position using a car-seal or a
lock-and-key type configuration. The owner or
operator shall visually inspect the seal or closure
mechanism at least once every month to verify that
the valve is maintained in the closed position.
B) Low leg drains, high point bleeds, analyzer vents, open-
ended valves or lines, and safety devices are not subject to
the requirements of subsection (b)(3)(A) above.
A)
If a flow indicator is used to comply with this subsection
(b)(3), the indicator must be installed at the inlet to the
bypass line used to divert gases and vapors from the
closed-vent system to the atmosphere at a point upstream
of the control device inlet. For the purposes of this
subsection, a flow indicator means a device which
indicates the presence of either gas or vapor flow in the
bypass line.
B)
If a seal or locking device is used to comply with this
subsection (b)(3), the device must be placed on the
mechanism by which the bypass device position is
controlled (e.g., valve handle or damper lever) when the
bypass device is in the closed position such that the bypass
device cannot be opened without breaking the seal or
removing the lock. Examples of such devices include, but
446
are not limited to, a car-seal or a lock-and-key
configuration valve. The owner or operator shall visually
inspect the seal or closure mechanism at least once every
month to verify that the bypass mechanism is maintained
in the closed position.
4)
The closed-vent system must be inspected and monitored by the
owner or operator in accordance with the procedure specified in
Section 725.933(k).
c)
The control device must meet the following requirements:
1)
The control device must be one of the following devices:
A)
A control device designed and operated to reduce the total
organic content of the inlet vapor stream vented to the
control device by at least 95 percent% by weight;
B)
An enclosed combustion device designed and operated in
accordance with the requirements of Section 725.933(c);
or
C)
A flare designed and operated in accordance with the
requirements of Section 725.933(d).
2) The control device must be operating at all times when gases,
vapors, or fumes are vented from the waste management unit
through the closed-vent system to the control device.
2)
The owner or operator that elects to use a closed-vent system and
control device to comply with the requirements of this Section
shall comply with the requirements specified in subsections
(c)(2)(A) through (c)(2)(G) of this Section.
A)
Periods of planned routine maintenance of the control
device, during which the control device does not meet the
specifications of subsections (c)(1)(A), (c)(1)(B), or
(c)(1)(C) of this Section, as applicable, must not exceed
240 hours per year.
B)
The specifications and requirements in subsections
(c)(1)(A), (c)(1)(B), and (c)(1)(C) of this Section for
control devices do not apply during periods of planned
routine maintenance.
447
C)
The specifications and requirements in subsections
(c)(1)(A), (c)(1)(B), and (c)(1)(C) of this Section for
control devices do not apply during a control device
system malfunction.
D)
The owner or operator shall demonstrate compliance with
the requirements of subsection (c)(2)(A) of this Section
(i.e., planned routine maintenance of a control device,
during which the control device does not meet the
specifications of subsections (c)(1)(A), (c)(1)(B), or
(c)(1)(C) of this Section, as applicable, must not exceed
240 hours per year) by recording the information specified
in Section 725.990(e)(1)(E).
E)
The owner or operator shall correct control device system
malfunctions as soon as practicable after their occurrence
in order to minimize excess emissions of air pollutants.
F)
The owner or operator shall operate the closed-vent
system so that gases, vapors, or fumes are not actively
vented to the control device during periods of planned
maintenance or control device system malfunction (i.e.,
periods when the control device is not operating or not
operating normally), except in cases when it is necessary
to vent the gases, vapors, or fumes to avoid an unsafe
condition or to implement malfunction corrective actions
or planned maintenance actions.
3)
The owner or operator using a carbon adsorption system to
comply with subsection (c)(1) aboveof this Section shall operate
and maintain the control device in accordance with the following
requirements:
A)
Following the initial startup of the control device, all
activated carbon in the control device must be replaced
with fresh carbon on a regular basis in accordance with
the requirements of Section 725.933(g) or 725.933(h).
B)
All carbon removed from the control device must be
managed in accordance with the requirements of Section
725.933(lm).
4)
An owner or operator using a control device other than a thermal
vapor incinerator, flare, boiler, process heater, condenser, or
carbon adsorption system to comply with subsection (c)(1)
448
aboveof this Section shall operate and maintain the control device
in accordance with the requirements of Section 725.933(i).
5)
The owner or operator shall demonstrate that a control device
achieves the performance requirements of subsection (c)(1)
aboveof this Section as follows:
A)
An owner or operator shall demonstrate using either a
performance test, as specified in subsection (c)(5)(C)
belowof this Section, or a design analysis, as specified in
subsection (c)(5)(D) belowof this Section, the
performance of each control device except for the
following:
i)
A flare;
ii)
A boiler or process heater with a design heat input
capacity of 44 megawatts or greater;
iii)
A boiler or process heater into which the vent
stream is introduced with the primary fuel;
iv)
A boiler or process heaterindustrial furnace
burning hazardous waste for which the owner or
operator has been issued a final permit under 35
Ill. Adm. Code 702, 703, and 705 and that ishas
designed and operatedoperates in accordance with
the requirements of 35 Ill. Adm. Code
726.Subpart H; or
v)
A boiler or process heaterindustrial furnace
burning hazardous waste for which the owner or
operator has certified compliancedesigned and
operates in accordance with the interim status
requirements of 35 Ill. Adm. Code 726.Subpart H.
B)
An owner or operator shall demonstrate the performance
of each flare in accordance with the requirements
specified in Section 725.933(e).
C)
For a performance test conducted to meet the
requirements of subsection (c)(5)(A) aboveof this Section,
the owner or operator shall use the test methods and
procedures specified in Section 725.934(c)(1) through
(c)(4).
449
D)
For a design analysis conducted to meet the requirements
of subsection (c)(5)(A) aboveof this Section, the design
analysis must meet the requirements specified in Section
725.935(b)(4)(C).
E)
The owner or operator shall demonstrate that a carbon
adsorption system achieves the performance requirements
of subsection (c)(1) aboveof this Section based on the total
quantity of organics vented to the atmosphere from all
carbon adsorption system equipment that is used for
organic adsorption, organic desorption or carbon
regeneration, organic recovery, and carbon disposal.
6)
If the owner or operator and the Agency do not agree on a
demonstration of control device performance using a design
analysis, then the disagreement must be resolved using the results
of a performance test performed by the owner or operator in
accordance with the requirements of subsection (c)(5)(C) aboveof
this Section. The Agency may choose to have an authorized
representative observe the performance test.
7)
The control device must be inspected and monitored by the owner
or operator in accordance with the procedures specified in Section
725.1033(f)(2) and (k). The readings from each monitoring
device required by Section 725.1033(f)(2) must be inspected at
least once each operating day to check control device operation.
Any necessary corrective measures must be immediately
implemented to ensure the control device is operated in
compliance with the requirements of this Section.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 725.989
Inspection and Monitoring Requirements
a)
This Section applies to anThe owner or operator usingshall inspect and
monitor air emission controls equipment used to comply with this
Subpart in accordance with the requirements ofspecified in Sections
725.985 through 725.988.
b) Each cover used in accordance with requirements of Sections 725.985
through 725.987 must be visually inspected and monitored for detectable
organic emissions by the owner or operator using the procedure specified
in subsection (f) below, except as follows:
450
1) An owner or operator is exempted from performing the cover
inspection and monitoring requirements specified in subsection (f)
below for the following tank covers:
A) A tank internal floating roof that is inspected and
monitored in accordance with the requirements of Section
725.991; or
B) A tank external floating roof that is inspected and
monitored in accordance with the requirements of Section
725.991.
2) If a tank is buried partially or entirely underground, an owner or
operator is required to perform the cover inspection and
monitoring requirements specified in subsection (f) below only
for those portions of the tank cover and those connections to the
tank cover or tank body (e.g., fill ports, access hatches, gauge
wells, etc.) that extend to or above the ground surface and can be
opened to the atmosphere.
3) An owner or operator is exempted from performing the cover
inspection and monitoring requirements specified in subsection (f)
below for a container that meets all requirements specified in
either Section 725.987(b)(1)(B) or (b)(1)(C).
4) An owner or operator is exempted from performing the cover
inspection and monitoring requirements specified in subsection (f)
below for an enclosure used to control air emissions from
containers in accordance with the requirements of Section
725.987(b)(2).
b)
The owner or operator shall develop and implement a written plan and
schedule to perform the inspections and monitoring required by
subsection (a) of this Section. The owner or operator shall incorporate
this plan and schedule into the facility inspection plan required under
Section 265.115.
c) Each closed-vent system used in accordance with the requirements of
Section 725.988 must be inspected and monitored by the owner or
operator in accordance with the procedure specified in Section
725.933(j).
d) Each control device used in accordance with the requirements of Section
725.988 must be inspected and monitored by the owner or operator in
accordance with the procedure specified in Section 725.933(f).
451
e) The owner or operator shall develop and implement a written plan and
schedule to perform all inspection and monitoring requirements of this
section. The owner or operator shall incorporate this plan and schedule
into the facility inspection plan required under 35 Ill. Adm. Code
725.115.
f) Inspection and monitoring of a cover in accordance with the
requirements of subsection (b) above must be performed as follows:
1) The cover and all cover openings must be initially visually
inspected and monitored for detectable organic emissions on or
before the date that the tank, surface impoundment, or container
using the cover becomes subject to the provisions of this Subpart
and at other times as requested by the Agency.
2) At least once every 6 months following the initial visual
inspection and monitoring for detectable organic emissions
required under subsection (f)(1) above, the owner and operator
shall visually inspect and monitor the cover and each cover
opening except for following cover openings:
A) A cover opening that has continuously remained in a
closed, sealed position for the entire period since the last
time the cover opening was visually inspected and
monitored for detectable emissions;
B) A cover opening that is designated as unsafe to inspect
and monitor in accordance with subsection (f)(5) below;
C) A cover opening on a cover installed and placed in
operation before December 6, 1994 that is designated as
difficult to inspect and monitor in accordance with
subsection (f)(6) below.
3) To visually inspect a cover, the owner or operator shall view the
entire cover surface and each cover opening in a closed, sealed
position for evidence of any defect that may affect the ability of
the cover or cover opening to continue to operate with no
detectable organic emissions. A visible hole, gap, tear, or split
in the cover surface or a cover opening is defined as a leak that
must be repaired in accordance with subsection (f)(7) below.
4) To monitor a cover for detectable organic emissions, the owner
or operator shall use the following procedure:
452
A) Method 21 in 40 CFR 60, appendix A, incorporated by
reference in 35 Ill. Adm. Code 720.111, to test each
cover seal and cover connection for detectable organic
emissions. Seals on floating membrane covers must be
monitored around the entire perimeter of the cover at
locations spaced no greater than 3 meters apart.
B) For all cover connections and seals except for the seals
around a rotating shaft that passes through a cover
opening, if the monitoring instrument indicates detectable
organic emissions (i.e., an instrument concentration
reading greater than 500 ppmv plus the background level),
then a leak is detected. Each detected leak must be
repaired in accordance with subsection (f)(7) below.
C) For the seals around a rotating shaft that passes through a
cover opening, if the monitoring instrument indicates a
concentration reading greater than 10,000 ppmv, then a
leak is detected. Each detected leak must be repaired in
accordance with subsection (f)(7) below.
5) An owner or operator may designate a cover as an unsafe to
inspect and monitor cover if all of the following conditions are
met:
A) The owner or operator determines that inspection or
monitoring of the cover would expose a worker to
dangerous, hazardous, or other unsafe conditions.
B) The owner or operator develops and implements a written
plan and schedule to inspect the cover using the procedure
specified in subsection (f)(3) above and monitor the cover
using the procedure specified in subsection (f)(4) below as
frequently as practicable during those times when a
worker can safely access the cover.
6) An owner or operator may designate a cover installed and placed
in operation before December 6, 1994, as a difficult to inspect
and monitor cover if all of the following conditions are met:
A) The owner or operator determines that inspection or
monitoring the cover requires elevating a worker to a
height greater than 2 meters (6.6 ft) above a support
surface; and
453
B) The owner and operator develops and implements a
written plan and schedule to inspect the cover using the
procedure specified in subsection (f)(3) above, and to
monitor the cover using the procedure specified in
subsection (f)(4) above at least once per calendar year.
7) When a leak is detected by either of the methods specified in
subsection (f)(3) or (f)(4) above, the owner or operator shall
repair the leak in the following manner:
A) The owner or operator shall make a first attempt at
repairing the leak no later than 5 calendar days after the
leak is detected. Repair of the leak must be completed as
soon as practicable, but no later than 15 calendar days
after the leak is detected. If repair of the leak cannot be
completed within the 15-day period, except as provided in
subsection (f)(7)(B) below, then the owner or operator
shall not add hazardous waste to the tank, surface
impoundment, or container on which the cover is installed
until the repair of the leak is completed.
B) Repair of a leak detected on a cover installed on a tank or
surface impoundment may be delayed beyond 15 calendar
days if the owner or operator determines that both of the
following conditions occur:
i) Repair of the leak requires first emptying the
contents of the tank or surface impoundment; and
ii) Temporary removal of the tank or surface
impoundment from service will result in the
unscheduled cessation of production from the
process unit or operation of the waste management
unit that is generating the hazardous waste
managed in the tank or surface impoundment.
C) Repair of a leak determined by the owner or operator to
meet the conditions specified in subsection (f)(7)(B) above
must be performed at the next time the process, system,
or waste management unit that is generating the hazardous
waste managed in the tank or surface impoundment stops
operation for any reason.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
454
Section 725.990
Recordkeeping Requirements
a)
Each owner or operator of a facility subject to requirements in this
Subpart shall record and maintain the following information specified in
subsections (b) through (i) of this Section, as applicable: to the facility.
Except for air emission control equipment design documentation and
information required by subsection (i) of this Section, records required
by this Section must be maintained in the operating record for a
minimum of three years. Air emission control equipment design
documentation must be maintained in the operating record until the air
emission control equipment is replaced or is otherwise no longer in
service. Information required by subsection (i) of this Section must be
maintained in the operating record for as long as the tank or container is
not using air emission controls specified in Sections 264.984 through
264.987, in accordance with the conditions specified in Section
724.984(d).
1) Documentation for each cover installed on a tank in accordance
with the requirements of Section 725.985(b)(2) or (b)(3) that
includes information prepared by the owner or operator or
provided by the cover manufacturer or vendor describing the
cover design, and certification by the owner or operator that the
cover meets the applicable design specifications as listed in
Section 725.991(c).
2) Documentation for each floating membrane cover installed on a
surface impoundment in accordance with the requirements of
Section 725.986(c) that includes information prepared by the
owner or operator or provided by the cover manufacturer or
vendor describing the cover design, and certification by the
owner or operator that the cover meets the specifications listed in
Section 725.986(e).
3) Documentation for each enclosure used to control air emissions
from containers in accordance with the requirements of Section
725.987(b)(2)(A) that includes information prepared by the
owner or operator or provided by the manufacturer or vendor
describing the enclosure design, and certification by the owner or
operator that the enclosure meets the specifications listed in
Section 725.987(b)(2)(B).
4) Documentation for each closed-vent system and control device
installed in accordance with the requirements of Section 725.988
that includes:
455
A) Certification that is signed and dated by the owner or
operator stating that the control device is designed to
operate at the performance level documented by a design
analysis, as specified in subsection (a)(4)(B) below, or by
performance tests, as specified in subsection (a)(4)(C)
below, when the tank, surface impoundment, or container
is or would be operating at capacity or the highest level
reasonably expected to occur.
B) If a design analysis is used, then design documentation as
specified in Section 725.935(b)(4). The documentation
must include information prepared by the owner or
operator or provided by the control device manufacturer
or vendor that describes the control device design in
accordance with Section 725.935(b)(4)(C) and
certification by the owner or operator that the control
equipment meets the applicable specifications.
C) If performance tests are used, then a performance test plan
as specified in Section 725.935(b)(3) and all test results.
D) Information as required by Sections 725.935(c)(1) and
725.935(c)(2).
5) Records for all Method 27 tests performed by the owner or
operator for each container used to meet the requirements of
Section 725.987(b)(1)(C).
6) Records for all visual inspections conducted in accordance with
the requirements of Section 725.989.
7) Records for all monitoring for detectable organic emissions
conducted in accordance with the requirements of Section
725.989.
8) Records of the date of each attempt to repair a leak, repair
methods applied, and the date of successful repair.
9) Records for all continuous monitoring conducted in accordance
with the requirements of Section 725.989.
10) Records of the management of carbon removed from a carbon
adsorption system conducted in accordance with Section
725.988(c)(3)(B).
456
11) Records for all inspections of each cover installed on a tank in
accordance with the requirements of Section 725.985(b)(2) or
(b)(3) that includes information as listed in Section 725.991(c).
b)
AnThe owner or operator electing to useof a tank using air emission
controls for a tank in accordance with the conditions specified
inrequirements of Section 725.985(c) shall recordprepare and maintain
records for the tank that include the following information:
1) The date and time each waste sample is collected for direct
measurement of maximum organic vapor pressure in accordance
with Section 725.984(c).
1)
For each tank using air emission controls in accordance with the
requirements of Section 725.985 of this Subpart, the owner or
operator shall record:
A)
A tank identification number (or other unique
identification description as selected by the owner or
operator).
B)
A record for each inspection required by Section 725.985
that includes the following information:
i)
Date inspection was conducted.
ii)
For each defect detected during the inspection, the
following information: the location of the defect,
a description of the defect, the date of detection,
and corrective action taken to repair the defect. In
the event that repair of the defect is delayed in
accordance with the provisions of Section 725.985,
the owner or operator shall also record the reason
for the delay and the date that completion of repair
of the defect is expected.
2) The results of each determination for the maximum organic vapor
pressure of the waste in the tank performed in accordance with
Section 725.984(c).
2)
In addition to the information required by subsection (b)(1) of
this Section, the owner or operator shall record the following
information, as applicable to the tank:
457
A)
The owner or operator using a fixed roof to comply with
the Tank Level 1 control requirements specified in Section
725.985(c) shall prepare and maintain records for each
determination for the maximum organic vapor pressure of
the hazardous waste in the tank performed in accordance
with the requirements of Section 725.985(c). The records
must include the date and time the samples were collected,
the analysis method used, and the analysis results.
B)
The owner or operator using an internal floating roof to
comply with the Tank Level 2 control requirements
specified in Section 725.985(e) shall prepare and maintain
documentation describing the floating roof design.
C)
Owners and operators using an external floating roof to
comply with the Tank Level 2 control requirements
specified in Section 725.985(f) shall prepare and maintain
the following records:
i)
Documentation describing the floating roof design
and the dimensions of the tank.
ii)
Records for each seal gap inspection required by
Section 725.985(f)(3) describing the results of the
seal gap measurements. The records must include
the date that the measurements were performed,
the raw data obtained for the measurements, and
the calculations of the total gap surface area. In
the event that the seal gap measurements do not
conform to the specifications in Section
725.985(f)(1), the records must include a
description of the repairs that were made, the date
the repairs were made, and the date the tank was
emptied, if necessary.
D)
Each owner or operator using an enclosure to comply with
the Tank Level 2 control requirements specified in Section
725.985(i) shall prepare and maintain the following
records:
i)
Records for the most recent set of calculations and
measurements performed by the owner or operator
to verify that the enclosure meets the criteria of a
permanent total enclosure as specified in
“Procedure T--Criteria for and Verification of a
458
Permanent or Temporary Total Enclosure” under
40 CFR 52.741, appendix B, incorporated by
reference in 35 Ill. Adm. Code 720.111.
ii)
Records required for the closed-vent system and
control device in accordance with the requirements
of subsection (e) of this Section.
3) The records specifying the tank dimensions and design capacity.
c) An owner or operator electing to use air emission controls for a tank in
accordance with the requirements of Section 725.991 shall record the
information required by Section 725.991(c).
c)
The owner or operator of a surface impoundment using air emission
controls in accordance with the requirements of Section 725.986 shall
prepare and maintain records for the surface impoundment that include
the following information:
1)
A surface impoundment identification number (or other unique
identification description as selected by the owner or operator).
2)
Documentation describing the floating membrane cover or cover
design, as applicable to the surface impoundment, that includes
information prepared by the owner or operator or provided by the
cover manufacturer or vendor describing the cover design, and
certification by the owner or operator that the cover meets the
specifications listed in Section 725.986(c).
3)
A record for each inspection required by Section 725.986 that
includes the following information:
A)
Date inspection was conducted.
B)
For each defect detected during the inspection the
following information: the location of the defect, a
description of the defect, the date of detection, and
corrective action taken to repair the defect. In the event
that repair of the defect is delayed in accordance with the
provisions of Section 725.986(f), the owner or operator
shall also record the reason for the delay and the date that
completion of repair of the defect is expected.
4)
For a surface impoundment equipped with a cover and vented
through a closed-vent system to a control device, the owner or
459
operator shall prepare and maintain the records specified in
subsection (e) of this Section.
d) An owner or operator electing not to use air emission controls for a
particular tank, surface impoundment, or container subject to this
Subpart in accordance with the conditions specified in Section
725.983(c) shall record the information used by the owner or operator
for each waste determination (e.g., test results, measurements,
calculations, and other documentation) in the facility operating log. If
analysis results for waste samples are used for the waste determination,
then the owner or operator shall record the date, time, and location that
each waste sample is collected in accordance with applicable
requirements of Section 725.984.
d)
The owner or operator of containers using Container Level 3 air
emission controls in accordance with the requirements of Section
725.987 shall prepare and maintain records that include the following
information:
1)
Records for the most recent set of calculations and measurements
performed by the owner or operator to verify that the enclosure
meets the criteria of a permanent total enclosure as specified in
“Procedure T--Criteria for and Verification of a Permanent or
Temporary Total Enclosure” under 40 CFR 52.741, appendix B,
incorporated by reference in 35 Ill. Adm. Code 720.111.
2)
Records required for the closed-vent system and control device in
accordance with the requirements of subsection (e) of this
Section.
e) An owner or operator electing to comply with requirements in
accordance with Section 725.983(c)(2)(E) or (c)(2)(F) shall record the
identification number for the incinerator, boiler, or industrial furnace in
which the hazardous waste is treated.
e)
The owner or operator using a closed-vent system and control device in
accordance with the requirements of Section 725.988 shall prepare and
maintain records that include the following information:
1)
Documentation for the closed-vent system and control device that
includes:
A)
Certification that is signed and dated by the owner or
operator stating that the control device is designed to
operate at the performance level documented by a design
460
analysis as specified in subsection (e)(1)(B) of this Section
or by performance tests as specified in subsection
(e)(1)(C) of this Section when the tank, surface
impoundment, or container is or would be operating at
capacity or the highest level reasonably expected to occur.
B)
If a design analysis is used, then design documentation, as
specified in Section 725.1035(b)(4). The documentation
must include information prepared by the owner or
operator or provided by the control device manufacturer
or vendor that describes the control device design in
accordance with Section 725.1035(b)(4)(C) and
certification by the owner or operator that the control
equipment meets the applicable specifications.
C)
If performance tests are used, then a performance test plan
as specified in Section 265.935(b)(3) and all test results.
D)
Information as required by 40 CFR 265.1035(c)(1) and
Section 725.935(c)(2), as applicable.
E)
An owner or operator shall record, on a semiannual basis,
the information specified in subsections (e)(1)(E)(i) and
(e)(1)(E)(ii) of this Section for those planned routine
maintenance operations that would require the control
device not to meet the requirements of Section
725.988(c)(1)(A), (c)(1)(B), or (c)(1)(C), as applicable.
i)
A description of the planned routine maintenance
that is anticipated to be performed for the control
device during the next six-month period. This
description must include the type of maintenance
necessary, planned frequency of maintenance, and
lengths of maintenance periods.
ii)
A description of the planned routine maintenance
that was performed for the control device during
the previous six-month period. This description
must include the type of maintenance performed
and the total number of hours during those six
months that the control device did not meet the
requirements of Section 725.988(c)(1)(A),
(c)(1)(B), or (c)(1)(C), as applicable, due to
planned routine maintenance.
461
F)
An owner or operator shall record the information
specified in subsections (e)(1)(F)(i) through (e)(1)(F)(iii)
of this Section for those unexpected control device system
malfunctions that would require the control device not to
meet the requirements of Section 725.988(c)(1)(A),
(c)(1)(B), or (c)(1)(C), as applicable.
i)
The occurrence and duration of each malfunction
of the control device system.
ii)
The duration of each period during a malfunction
when gases, vapors, or fumes are vented from the
waste management unit through the closed-vent
system to the control device while the control
device is not properly functioning.
iii)
Actions taken during periods of malfunction to
restore a malfunctioning control device to its
normal or usual manner of operation.
G)
Records of the management of carbon removed from a
carbon adsorption system conducted in accordance with
Section 725.988(c)(3)(B).
f)
The owner or operator of a tank, surface impoundment, or container
exempted from standards in accordance with the provisions of Section
725.983(c) of this Subpart shall prepare and maintain the following
records, as applicable:
1)
For tanks, surface impoundments, or containers exempted under
the hazardous waste organic concentration conditions specified in
Section 725.983 (c)(1) or (c)(2) of this Subpart, the owner or
operator shall record the information used for each waste
determination (e.g., test results, measurements, calculations, and
other documentation) in the facility operating log. If analysis
results for waste samples are used for the waste determination,
then the owner or operator shall record the date, time, and
location that each waste sample is collected in accordance with
applicable requirements of Section 725.984 of this Subpart.
2)
For tanks, surface impoundments, or containers exempted under
the provisions of Section 725.983(c)(2)(vii) or Section
725.983(c)(2)(viii) of this Subpart, the owner or operator shall
record the identification number for the incinerator, boiler, or
industrial furnace in which the hazardous waste is treated.
462
fg)
An owner or operator designating a cover as “unsafe to inspect and
monitor” pursuant to Section 725.989(f)(5)725.985(l) or difficult to
inspect and monitor pursuant to Section 725.989(f)(6) shall record in a
log that is kept in the facility operating record the following information:
the identification numbers for waste management units with covers that
are designated as “unsafe to inspect and monitor”, the explanation for
each cover stating why the cover is unsafe to inspect and monitor, and
the plan and schedule for inspecting and monitoring each cover.
1) A list of identification numbers for tanks with covers that are
designated as unsafe to inspect and monitor in accordance with
the requirements of Section 725.989(f)(5), an explanation for
each cover stating why the cover is unsafe to inspect and
monitor, and the plan and schedule for inspecting and monitoring
each cover.
2) A list of identification numbers for tanks with covers that are
designated as difficult to inspect and monitor in accordance with
the requirements of Section 725.989(f)(6), an explanation for
each cover stating why the cover is difficult to inspect and
monitor, and the plan and schedule for inspecting and monitoring
each cover.
g) All records required by subsections (a) through (f) above, except as
required in subsections (a)(1) through (a)(4) above, must be maintained
in the operating record for a minimum of 3 years. All records required
by subsections (a)(1) through (a)(4) above must be maintained in the
operating record until the air emission control equipment is replaced or
otherwise no longer in service.
h)
The owner or operator of a facility that is subject to this Subpart and to
the control device standards in 40 CFR 60, Subpart VV, or 40 CFR 61,
Subpart V, incorporated by reference in 35 Ill. Adm. Code 270.111,
may elect to demonstrate compliance with the applicable Sections of this
Subpart by documentation either pursuant to this Subpart, or pursuant to
the provisions of 40 CFR 60, Subpart VV or 40 CFR 61, Subpart V, to
the extent that the documentation required by 40 CFR 60 or 61
duplicates the documentation required by this Section.
i)
For each tank or container not using air emission controls specified in
Sections 725.985 through 725.988 in accordance with the conditions
specified in Section 725.980(d), the owner or operator shall record and
maintain the following information:
463
1)
A list of the individual organic peroxide compounds
manufactured at the facility that meet the conditions specified in
Section 725.980(d)(1).
2)
A description of how the hazardous waste containing the organic
peroxide compounds identified pursuant to subsection (i)(1) are
managed at the facility in tanks and containers. This description
must include the following information:
A)
For the tanks used at the facility to manage this hazardous
waste, sufficient information must be provided to describe
each tank: a facility identification number for the tank,
the purpose and placement of this tank in the management
train of this hazardous waste, and the procedures used to
ultimately dispose of the hazardous waste managed in the
tanks.
B)
For containers used at the facility to manage this
hazardous waste, sufficient information must be provided
to describe the following for each tankcontainer: a
facility identification number for the container or group of
containers,; the purpose and placement of this container
or group of containers in the management train of this
hazardous waste,; and the procedures used to ultimately
dispose of the hazardous waste managed handled in the
containers.
3)
An explanation of why managing the hazardous waste containing
the organic peroxide compounds identified pursuant to subsection
(i)(1) aboveof this Section in the tanks or containers identified
pursuant to subsection (i)(2) aboveof this Section would create an
undue safety hazard if the air emission controls specified in
Sections 725.985 through 725.988 were installed and operated on
these waste management units. This explanation must include the
following information:
A)
For tanks used at the facility to manage this hazardous
waste, sufficient information must be provided to explain:
how use of the required air emission controls on the tanks
would affect the tank design features and facility operating
procedures currently used to prevent an undue safety
hazard during the management of this hazardous waste in
the tanks; and why installation of safety devices on the
required air emission controls, as allowed under Section
725.985(g)this Subpart, would not address those situations
464
in which evacuation of tanks equipped with these air
emission controls is necessary and consistent with good
engineering and safety practices for handling organic
peroxides.
B)
For containers used at the facility to manage this
hazardous waste, sufficient information must be provided
to explain: how use of the required air emission controls
on the tankscontainers would affect the container design
features and handling procedures currently used to prevent
an undue safety hazard during management of this
hazardous waste in the containers; and why installation of
safety devices on the required air emission controls, as
allowed under Section 725.987(d)this Subpart, would not
address those situations in which evacuation of containers
equipped with these air emission controls is necessary and
consistent with good engineering and safety practices for
handling organic peroxides.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 725.991
Alternative Tank Emission Control Requirements (Repealed)
a) This Section applies to owners and operators of tanks electing to comply
with Section 725.985(b)(2) or (b)(3).
1) The owner or operator electing to comply with Section
725.985(b)(2) shall design, install, operate, and maintain a fixed
roof and internal floating roof that meet the following
requirements.
A) The fixed roof must comply with the requirements of
Section 725.985(d)(1). The internal floating roof must
rest or float on the waste surface (but not necessarily in
complete contact with it) inside a tank that has a fixed
roof. The internal floating roof must be floating on the
waste surface at all times, except during initial fill and
during those intervals when the tank is completely
emptied or subsequently emptied and refilled. When the
roof is resting on the leg supports, the process of filling,
emptying, or refilling must be as continuous as possible,
based on the amount of waste and the nature of the waste
handling operation, and must be accomplished as rapidly
as possible.
465
B) Each internal floating roof must be equipped with one of
the following closure devices between the wall of the tank
and the edge of the internal floating roof:
i) A foam- or liquid-filled seal mounted in contact
with the waste (liquid-mounted seal). A liquid-
mounted seal means a foam- or liquid-filled seal
mounted in contact with the waste between the
wall of the tank and the floating roof continuously
around the circumference of the tank.
ii) Two seals mounted one above the other so that
each forms a continuous closure that completely
covers the space between the wall of the tank and
the edge of the internal floating roof. The lower
seal may be vapor-mounted, but both must be
continuous.
iii) A mechanical shoe seal. A mechanical shoe seal is
a metal sheet held vertically against the wall of the
tank by springs or weighted levers and is
connected by braces to the floating roof. A
flexible coated fabric (envelope) spans the annular
space between the metal sheet and the floating
roof.
C) Each opening in a noncontact internal floating roof except
for automatic bleeder vents (vacuum breaker vents) and
the rim space vents is to provide a projection below the
waste surface.
D) Each opening in the internal floating roof except for leg
sleeves, automatic bleeder vents, rim space vents, column
wells, ladder wells, sample wells, and stub drains is to be
equipped with a cover or lid that is to be maintained in a
closed position at all times (i.e., no visible gap), except
when the device is in actual use. The cover or lid must be
equipped with a gasket. Covers on each access hatch and
automatic gauge float well must be bolted, except when
they are in use.
E) Automatic bleeder vents must be equipped with a gasket
and are to be closed at all times when the roof is floating,
except when the roof is being floated off or is being
landed on the roof leg supports.
466
F) Rim space vents must be equipped with a gasket and are
to be set to open only when the internal floating roof is
not floating or at the manufacturer’s recommended
setting.
G) Each penetration of the internal floating roof for the
purpose of sampling must be a sample well. The sample
well must have a slit fabric cover that covers at least 90
percent of the opening.
H) Each penetration of the internal floating roof that allows
for passage of a column supporting the fixed roof must
have a flexible fabric sleeve seal or a gasketed sliding
cover.
I) Each penetration of the internal floating roof that allows
for passage of a ladder must have a gasketed sliding
cover.
2) The owner or operator electing to comply with Section
725.985(b)(3) shall design, install, operate, and maintain an
external floating roof that meets the following requirements:
A) Each external floating roof must be equipped with a
closure device between the wall of the tank and the roof
edge. The closure device is to consist of two seals, one
above the other. The lower seal is referred to as the
primary seal, and the upper seal is referred to as the
secondary seal.
i) The primary seal must be either a mechanical shoe
seal or a liquid-mounted seal. Except as provided
in subsection (b)(2)(D) below, the seal must
completely cover the annular space between the
edge of the floating roof and tank wall.
ii) The secondary seal must completely cover the
annular space between the external floating roof
and the wall of the tank in a continuous fashion
except as allowed in subsection (b)(2)(D) below.
B) Except for automatic bleeder vents and rim space vents,
each opening in a noncontact external floating roof must
provide a projection below the waste surface. Except for
467
automatic bleeder vents, rim space vents, roof drains, and
leg sleeves, each opening in the roof is to be equipped
with a gasketed cover, seal, or lid that is to be maintained
in a closed position at all times (i.e., no visible gap),
except when the device is in actual use. Automatic
bleeder vents are to be closed at all times when the roof is
floating, except when the roof is being floated off or is
being landed on the roof leg supports. Rim vents are to
be set to open when the roof is being floated off the roof
leg supports or at the manufacturer’s recommended
setting. Automatic bleeder vents and rim space vents are
to be gasketed. Each emergency roof drain is to be
provided with a slotted membrane fabric cover that covers
at least 90 percent of the area of the opening.
C) The roof must be floating on the waste at all times (i.e.,
off the roof leg supports), except during initial fill until
the roof is lifted off leg supports and when the tank is
completely emptied and subsequently refilled. The
process of filling, emptying, or refilling when the roof is
resting on the leg supports must be continuous and must
be accomplished as rapidly as possible.
3) The owner or operator may elect to comply with Section
725.985(b)(2) or (b)(3) using an alternative means of emission
limitation for which U.S. EPA has published a Federal Register
notice in accordance with the requirements of 40 CFR 60.114b
permitting its use as an alternative means for the purpose of
compliance with 40 CFR 60.112b.
b) Monitoring and inspection of the control equipment described in
subsection (a) above must be conducted as follows:
1) After installation, owners and operators of internal floating roofs
shall:
A) Visually inspect the internal floating roof, the primary
seal, and the secondary seal (if one is in service), prior to
filling the tank with waste. If there are holes, tears, or
other openings in the primary seal, the secondary seal, or
the seal fabric, or defects in the internal floating roof, or
both, the owner or operator shall repair the items before
filling the tank.
468
B) For tanks equipped with a liquid-mounted or mechanical
shoe primary seal, visually inspect the internal floating
roof and the primary seal or the secondary seal (if one is
in service) through manholes and roof hatches on the
fixed roof at least once every 12 months after initial fill.
If the internal floating roof is not resting on the surface of
the waste inside the tank, or there is liquid accumulated
on the roof, or the seal is detached, or there are holes or
tears in the seal fabric, the owner or operator shall repair
the items or empty and remove the tank from service
within 45 days. If a failure that is detected during
inspections required in this subsection cannot be repaired
within 45 days and if the tank cannot be emptied within
45 days, the Agency may grant the owner or operator a
provisional variance pursuant to Section 35(b) of the Act
that extends this time for up to 30 days. Such a request
for an extension must comply with 35 Ill. Adm. Code
180, and it must document that alternate capacity is
unavailable and specify a schedule of actions the owner or
operator will take that will assure that the control
equipment will be repaired or the tank will be emptied as
soon as possible.
C) For tanks equipped with a double-seal system as specified
in subsection (a)(1)(A)(ii) above:
i) Visually inspect the tank, as specified in subsection
(b)(1)(D) below, at least every 5 years; or
ii) Visually inspect the tank as specified in subsection
(b)(1)(B) above.
D) Visually inspect the internal floating roof, the primary
seal, the secondary seal (if one is in service), gaskets,
slotted membranes, and sleeve seals (if any) each time the
tank is emptied and degassed. If the internal floating roof
has defects; the primary seal has holes, tears, or other
openings in the seal or the seal fabric; the secondary seal
has holes, tears, or other openings in the seal or the seal
fabric; the gaskets no longer close off the waste surfaces
from the atmosphere; or the slotted membrane has more
than 10 percent open area, the owner or operator shall
repair the items as necessary, so that none of the
conditions specified in this subsection exist before refilling
the tank with waste. In no event may inspections
469
conducted in accordance with this provision occur at
intervals greater than 10 years, in the case of tanks
conducting the annual visual inspection as specified in
subsection (b)(1)(B) above, or at intervals no greater than
5 years, in the case of tanks specified in subsection
(b)(1)(C) above.
E) Notify the Agency in writing at least 30 days prior to the
filling or refilling of each tank for which an inspection is
required by subsections (b)(1)(A) and (b)(1)(D) above, to
afford the Agency the opportunity to have an observer
present. If the inspection required by subsection (b)(1)(D)
above is not planned and the owner or operator could not
have known about the inspection 30 days in advance of
refilling the tank, the owner or operator shall notify the
Agency at least 7 days prior to the refilling of the tank.
Notification must be made by telephone immediately
followed by written documentation demonstrating why the
inspection was unplanned. Alternatively, this notification,
including the written documentation, may be made in
writing and sent by express mail so that it is received by
the Agency at least 7 days prior to the refilling.
2) After installation, the owner or operator of an external floating
roof shall:
A) Determine the gap areas and maximum gap widths
between the primary seal and the wall of the tank and
between the secondary seal and the wall of the tank
according to the following frequency:
i) Measurements of gaps between the tank wall and
the primary seal (seal gaps) must be performed
during the hydrostatic testing of the tank or within
60 days of the initial fill with waste and at least
once every five years thereafter.
ii) Measurements of gaps between the tank wall and
the secondary seal must be performed within 60
days of the initial fill with waste and at least once
per year thereafter.
iii) If any tank ceases to hold waste for a period of one
year or more, subsequent introduction of waste
into the tank must be considered an initial fill for
470
the purposes of subsections (b)(2)(A)(i) and
(b)(2)(A)(ii) above.
B) Determine the gap widths and areas in the primary and
secondary seals individually by the following procedures:
i) Measure seal gaps, if any, at one or more floating
roof levels when the roof is floating off the roof
leg supports.
ii) Measure seal gaps around the entire circumference
of the tank in each place where a 0.32-cm diameter
uniform probe passes freely (without forcing or
binding against the seal) between the seal and the
wall of the tank and measure the circumferential
distance of each such location.
iii) Determine the total surface area of each gap
described in subsection (b)(2)(B)(ii) above by
using probes of various widths to measure
accurately the actual distance from the tank wall to
the seal and multiplying each such width by its
respective circumferential distance.
C) Add the gap surface area of each gap location for the
primary seal and the secondary seal individually and
divide the sum for each seal by the nominal diameter of
the tank and compare each ratio to the respective
standards in subsection (b)(2)(D) below.
D) Make necessary repairs or empty the tank within 45 days
of identification in any inspection for seals not meeting
the following requirements:
i) The accumulated area of gaps between the tank
wall and the mechanical shoe or liquid-mounted
primary seal must not exceed 212 cm
2
per meter
(10.0 in
2
per foot) of tank diameter, and the width
of any portion of any gap must not exceed 3.81 cm
(1.50 in). One end of the mechanical shoe is to
extend into the waste contained in the tank, and the
other end is to extend a minimum vertical distance
of 61 cm (24.0 in) above the waste surface. There
are to be no holes, tears, or other openings in the
shoe, seal fabric, or seal envelope.
471
ii) The secondary seal is to meet the following
requirements: The secondary seal is to be installed
above the primary seal so that it completely covers
the space between the roof edge and the tank wall
except as provided in subsection (b)(2)(B)(iii)
above. The accumulated area of gaps between the
tank wall and the secondary seal must not exceed
21.2 cm
2
per meter (1.00 in
2
per foot) of tank
diameter, and the width of any portion of any gap
must not exceed 1.27 cm (0.500 in). There are to
be no holes, tears, or other openings in the seal or
seal fabric.
E) If a failure that is detected during inspections required in
subsection (b)(2)(A) above cannot be repaired within 45
days and if the tank cannot be emptied within 45 days, the
Agency may grant the owner or operator a provisional
variance pursuant to Section 35(b) of the Act that extends
this time for up to 30 days. Such a request for an
extension must comply with 35 Ill. Adm. Code 180, and
it must include a demonstration of the unavailability of
alternate capacity and a specification of a schedule that
will assure that the control equipment will be repaired or
the tank will be emptied as soon as possible.
F) Notify the Agency 30 days in advance of any gap
measurements required by subsection (b)(2)(A) above, to
afford the Agency the opportunity to have an observer
present.
G) Visually inspect the external floating roof, the primary
seal, secondary seal, and fittings each time the vessel is
emptied and degassed.
i) If the external floating roof has defects, the
primary seal has holes, tears, or other openings in
the seal or the seal fabric, or the secondary seal
has holes, tears, or other openings in the seal or
the seal fabric, the owner or operator shall repair
the items as necessary so that none of the
conditions specified in this subsection exist before
filling or refilling the tank with waste.
472
ii) For all the inspections required by subsection
(b)(2)(G), the owner or operator shall notify the
Agency in writing at least 30 days prior to the
filling or refilling of each tank to afford the
Agency the opportunity to inspect the tank prior to
refilling. If the inspection required by this
subsection is not planned and the owner or
operator could not have known about the
inspection 30 days in advance of refilling the tank,
the owner or operator shall notify the Agency at
least seven days prior to the refilling of the tank.
Notification must be made by telephone
immediately followed by written documentation
demonstrating why the inspection was unplanned.
Alternatively, this notification, including the
written documentation, may be made in writing
and sent by express mail so that it is received by
the Agency at least seven days prior to the
refilling.
c) Owners and operators that elect to install and operate the control
equipment in subsection (a) above shall include the following
information in the operating record in accordance with the requirements
of Section 725.990(a)(1) and (a)(11):
1) Internal floating roof.
A) Documentation that describes the control equipment
design and certifies that the control equipment meets the
specifications of subsections (a)(1) and (b)(1) above.
B) Records of each inspection performed as required by
subsections (b)(1)(A) through (b)(1)(D) above. Each
record must identify the tank on which the inspection was
performed and must contain the date the tank was
inspected and the observed condition of each component
of the control equipment (seals, internal floating roof, and
fittings).
C) If any of the conditions described in subsection (b)(1)(B)
above are detected during the annual visual inspection
required by subsection (b)(1)(B) above, the records must
identify the tank, the nature of the defects, and the date
the tank was emptied or the nature of and date the repair
was made.
473
D) After each inspection required by subsection (b)(1)(C)
above that finds holes or tears in the seal or seal fabric, or
defects in the internal floating roof, or other control
equipment defects listed in subsection (b)(1)(B) above, the
records must identify the tank and the reason it did not
meet the specifications of subsection (a)(1) or (b)(1)(C)
above and describe each repair made.
2) External floating roof.
A) Documentation that describes the control equipment
design and certifies that the control equipment meets the
specifications of subsections (a)(2) and (b)(2)(B) through
(b)(2)(D) above.
B) Records of each gap measurement performed as required
by subsection (b)(2) above. Each record must identify the
tank in which the measurement was performed, the date
of measurement, the raw data obtained in the
measurement, and the calculations described in
subsections (b)(2)(B) and (b)(2)(C) above.
C) Records for each seal gap measurement that detects gaps
exceeding the limitations specified by subsection (b)(2)(D)
above that identifies the tank, the date the tank was
emptied or the repairs made, and the nature of the repair.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 725.Appendix F Compounds With Henry’s Law Constant Less Than 0.1
Y/X (at 25
°
C)
Compound name
CAS No.
Acetaldol
107-89-1
Acetamide
60-35-5
2-Acetylaminofluorene
53-96-3
3-Acetyl-5-hydroxypiperidine
1-Acetyl-2-thiourea
591-08-2
3-Acetylpiperidine
618-42-8
Acrylamide
79-06-1
Acrylic acid
79-10-7
474
Adenine
73-24-5
Adipic acid
124-04-9
Adiponitrile
111-69-3
Alachlor
15972-60
Aldicarb
116-06-3
Ametryn
4-Aminobiphenyl
92-67-1
4-Aminopyridine
504-24-5
Aniline
62-53-3
o-Anisidine
90-04-0
Anthraquinone
84-65-1
Atrazine
1912-24-9
Benzenearsonic acid
98-05-5
Benzenesulfonic acid
98-11-3
Benzidine
92-87-5
Benzo(a)anthracene
56-55-3
Benzo(a)pyrene
50-32-8
Benzo(ghi)perylene
191-24-2
Benzo(k)fluoranthene
207-08-9
Benzoic acid
65-85-0
Benzyl alcohol
100-51-6
gamma-BHC
58-89-9
bis(2-Ethylhexyl)phthalate
117-81-7
Bromochloromethyl acetate
Bromoxynil
Butyric acid
107-92-6
Caprolactam (hexahydro-2H-azepin-2-one)
105-60-2
Catechol
120-80-9
Cell wall
Cellulose (carboxymethylcellulose)
9000-11-7
2-Chloracetophenone
93-76-5
3-Chloro-2,5-diketopyrrolidine
Chloro-1,2-ethane diol
p-Chloro-m-cresol
59-50-7
Chloroacetic acid
79-11-8
p-Chloroaniline
106-47-8
p-Chlorobenzophenone
134-85-0
Chlorobenzylate
510-15-6
Chlorhydrin (3-Chloro-1,2-propanediol)
96-24-2
4-Chlorophenol
106-48-9
Chlorophenol polymers
1-(o-Chlorophenyl)thiourea
5344-82-1
Chrysene
218-01-9
Citric acid
77-92-9
Creosote
8001-58-
475
Cresol (mixed isomers)
1319-77-3
m-Cresol
108-39-4
o-Cresol
95-48-7
p-Cresol
106-44-5
4-Cumylphenol
27576-86
Cyanide
57-12-5
4-Cyanomethyl benzoate
Diazinon
Dibenzo(a,h)anthracene
53-70-3
3,5-Dibromo-4-hydroxybenzonitrile
1689-84-5
Dibutylphthalate
84-74-2
2,6-Dichloro-4-nitroaniline
99-30-9
2,5-Dichloroaniline (N,N-dichloroaniline)
95-82-9
2,6-Dichlorobenzonitrile
1194-65-6
2,5-Dichlorophenol
3,4-Dichlorotetrahydrofuran
3511-19
Dichlorvos
Diethanolamine
N,N-Diethylaniline
91-66-7
Diethyl phosphorothioate
126-75-0
N,N-Diethylpropionamide
15299-99
Diethylene glycol
111-46-6
Diethylene glycol dimethyl ether (dimethyl Carbitol)
Diethylene glycol monobutyl ether (butyl Carbitol)
112-34-5
Diethylene glycol monoethyl ether acetate (Carbitol acetate)
112-15-2
Diethylene glycol monoethyl ether (Carbitol Cellosolve)
111-90-0
Diethylene glycol monomethyl ether (methyl Carbitol)
111-77-3
N,N-Diethylhydrazine
Diethyl(4-methylumbelliferyl)thionophosphate
299-45-6
Dimethoate
60-51-5
2,3-Dimethoxystrychnidin-10-one
357-57-3
Dimethylcarbamoyl chloride
Dimethyl disulfide
624-92-0
Dimethylformamide
68-12-2
Dimethylphthalate
131-11-3
4-Dimethylaminoazobenzene
60-11-7
7,12-Dimethylbenz(a)anthracene
57-97-6
3,3-Dimethylbenzidine
119-93-7
1,1-Dimethylhydrazine
57-14-7
Dimethylsulfone
Dimethylsulfoxide
67-68-5
4,6-Dinitro-o-cresol
534-52-1
1,2-Diphenylhydrazine
122-66-7
Dipropylene glycol (1,1'-oxydi-2-propanol)
110-98-5
Endrin
72-20-8
476
Epinephrine
51-43-4
mono-Ethanolamine
141-43-5
Ethyl carbamate (urethane)
5-17-96
Ethyl morpholine (ethyl diethylene oxime)
Ethylene glycol
107-21-1
Ethylene glycol monobutyl ether (butyl Cellosolve)
111-76-2
Ethylene glycol monoethyl ether (Cellosolve)
110-80-5
Ethylene glycol monoethyl ether acetate (Cellosolve acetate)
111-15-9
Ethylene glycol monomethyl ether (methyl Cellosolve)
109-86-4
Ethylene glycol monophenyl ether (phenyl Cellosolve)
122-99-6
Ethylene glycol monopropyl ether (propyl Cellosolve)
2807-30-9
Ethylene thiourea (2-imidazolidinethione)
9-64-57
3-Ethylphenol
620-17-7
Fluoroacetic acid, sodium salt
62-74-8
Formaldehyde
50-00-0
Formamide
7-51-27
Formic acid
64-18-6
Fumaric acid
110-17-8
Glutaric acid
110-94-1
Glycerin (Glycerol)
56-81-5
Glycinamide
598-41-4
Glyphosate
1071-83-6
Guthion
Gylcidol
556-52-5
Hexamethylene-1,6-diisocyanate (1,6-diisocyanatohexane)
822-06-0
Hexamethyl phosphoramide
680-31-9
Hexanoic acid
142-62-1
Hydrazine
302-01-2
Hydrocyanic acid
74-90-8
Hydroquinone
123-31-9
Hydroxy-2-propionitrile
109-78-4
Indeno(1,2,3-cd)pyrene
193-39-5
Lead acetate
301-04-2
Lead subacetate (lead acetate, monobasic)
1335-32-6
Leucine
61-90-5
Malathion
121-75-5
Maleic acid
110-16-7
Maleic anhydride
108-31-6
Mesityl oxide
141-79-7
Methane sulfonic acid
75-75-2
Methomyl
16752-77
p-Methoxyphenol
150-76-5
1-Methyl-2-methoxyaziridine
Methylacrylate
96-33-3
4,4'-Methylene-bis-(2-chloroaniline)
101-14-4
477
Methylene diphenyl diisocyanate (diphenyl methane diisocyanate)
101-68-8
4,4-Methylenedianiline
101-77-9
Methylene diphenylamine (MDA)
5-Methylfurfural
620-02-0
Methylhydrazine
60-34-4
Methyliminoacetic acid
Methylparathion
298-00-0
Methyl sulfuric acid
77-78-1
4-Methylthiophenol
106-45-6
Monomethyl formamide (n-methylformamide)
123-39-7
Nabam
alpha-Naphthol
90-15-3
beta-Naphthol
135-19-3
alpha-Naphthylamine
134-32-7
beta-Naphthylamine
91-59-8
Neopentyl glycol
126-30-7
Niacinamide
98-92-0
o-Nitroaniline
88-74-4
Nitroglycerin
55-63-0
2-Nitrophenol
88-75-5
4-Nitrophenol
100-02-7
N-Nitroso-n-methylurea
684-93-5
N-Nitrosodimethylamine
62-75-9
Nitrosoguanidine
674-81-7
N-Nitrosomorpholine (4-nitrosomorpholine)
59-89-2
Oxalic acid
144-62-7
Parathion
56-38-2
Pentaerythritol
115-77-5
Phenacetin
62-44-2
Phenol
108-95-2
Phenyl mercuric acetate
62-38-4
Phenylacetic acid
103-82-2
m-Phenylene diamine
108-45-2
o-Phenylene diamine
95-54-5
p-Phenylene diamine
106-50-3
Phorate
298-02-2
Phthalic anhydride
85-44-9
alpha-Picoline (2-methyl pyridine)
109-06-8
1,3-Propane sulfone
1120-71-4
beta-Propiolactone
57-57-8
Proporur (Baygon)
Propylene glycol
57-55-6
Pyrene
129-00-0
Pyridinium bromide
Quinoline
91-22-5
478
Quinone (p-benzoquinone)
106-51-4
Resorcinol
108-46-3
Simazine
122-34-9
Sodium acetate
127-09-3
Sodium formate
141-53-7
Strychnine
57-24-9
Succinic acid
110-15-6
Succinimide
123-56-8
Sulfanilic acid
121-47-1
Terephthalic acid
100-21-0
Tetraethyldithiopyrophosphate
3689-24-5
Tetraethylenepentamine
112-57-2
Thiofanox
39196-18
Thiosemicarbazide
79-19-6
2,4-Toluene diamine
95-80-7
2,4-Toluene diisocyanate
584-84-9
2,6-Toluenediamine
823-40-5
3,4-Toluenediamine
496-72-0
p-Toluic acid
99-94-5
m-Toluidine
108-44-1
1,1,2-Trichloro-1,2,2-trifluoroethane
76-13-1
Triethanolamine
102-71-6
Triethylene glycol dimethyl ether
Tripropylene glycol
24800-44-0
Warfarin
81-81-2
3,4-Xylenol (3,4-dimethylphenol)
95-65-8
(Source: Added at 21 Ill. Reg. ________, effective ____________________)
TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE G: WASTE DISPOSAL
CHAPTER I: POLLUTION CONTROL BOARD
SUBCHAPTER c: HAZARDOUS WASTE OPERATING
REQUIREMENTS
PART 726
STANDARDS FOR THE MANAGEMENT OF SPECIFIC
HAZARDOUS WASTE AND SPECIFIC TYPES OF HAZARDOUS
WASTE MANAGEMENT FACILITIES
SUBPART C: RECYCLABLE MATERIALS USED IN A MANNER
CONSTITUTING DISPOSAL
Section
726.120
Applicability
479
726.121
Standards applicable to generators and transporters of materials used in a
manner that constitutes disposal
726.122
Standards applicable to storers, who are not the ultimate users, of
materials that are to be used in a manner that constitutes disposal
726.123
Standards Applicable to Users of Materials that are Used in a Manner
that Constitutes Disposal
SUBPART D: HAZARDOUS WASTE BURNED FOR ENERGY
RECOVERY
Section
726.130
Applicability (Repealed)
726.131
Prohibitions (Repealed)
726.132
Standards applicable to generators of hazardous waste fuel (Repealed)
726.133
Standards applicable to transporters of hazardous waste fuel (Repealed)
726.134
Standards applicable to marketers of hazardous waste fuel (Repealed)
726.135
Standards applicable to burners of hazardous waste fuel (Repealed)
726.136
Conditional exemption for spent materials and by-products exhibiting a
characteristic of hazardous waste (Repealed)
SUBPART E: USED OIL BURNED FOR ENERGY RECOVERY
(Repealed)
Section
726.140
Applicability (Repealed)
726.141
Prohibitions (Repealed)
726.142
Standards applicable to generators of used oil burned for energy
recovery (Repealed)
726.143
Standards applicable to marketers of used oil burned for energy recovery
(Repealed)
726.144
Standards applicable to burners of used oil burned for energy recovery
(Repealed)
SUBPART F: RECYCLABLE MATERIALS UTILIZED FOR
PRECIOUS METAL RECOVERY
Section
726.170
Applicability and requirements
SUBPART G: SPENT LEAD-ACID BATTERIES BEING
RECLAIMED
Section
726.180
Applicability and requirements
SUBPART H: HAZARDOUS WASTE BURNED IN BOILERS AND
INDUSTRIAL FURNACES
Section
726.200
Applicability
480
726.201
Management prior to Burning
726.202
Permit standards for Burners
726.203
Interim Status Standards for Burners
726.204
Standards to Control Organic Emissions
726.205
Standards to control PM
726.206
Standards to Control Metals Emissions
726.207
Standards to control HCl and Chlorine Gas Emissions
726.208
Small quantity On-site Burner Exemption
726.209
Low risk waste Exemption
726.210
Waiver of DRE trial burn for Boilers
726.211
Standards for direct Transfer
726.212
Regulation of Residues
726.219
Extensions of Time
726.Appendix A
Tier I and Tier II Feed Rate and Emissions Screening Limits for
Metals
726.Appendix B
Tier I Feed Rate Screening Limits for Total Chlorine
726.Appendix C
Tier II Emission Rate Screening Limits for Free Chlorine and
Hydrogen Chloride
726.Appendix D
Reference Air Concentrations
726.Appendix E
Risk Specific Doses
726.Appendix F
Stack Plume Rise
726.Appendix G
Health-Based Limits for Exclusion of Waste-Derived Residues
726.Appendix H
Potential PICs for Determination of Exclusion of Waste-Derived
Residues
726.Appendix I
Methods Manual for Compliance with BIF Regulations
726.Appendix J
Guideline on Air Quality Models
726.Appendix K
Lead-Bearing Materials That May be Processed in Exempt Lead
Smelters
726.Appendix L
Nickel or Chromium-Bearing Materials that may be Processed in
Exempt Nickel-Chromium Recovery Furnaces
726.Appendix M
Mercury-Bearing Wastes That May Be Processed in Exempt
Mercury Recovery Units
726.Table A
Exempt Quantities for Small Quantity Burner Exemption
AUTHORITY: Implementing Section 22.4 and authorized by Section 27 of the
Environmental Protection Act [415 ILCS 5/22.4 and 27].
SOURCE: Adopted in R85-22 at 10 Ill. Reg. 1162, effective January 2, 1986;
amended in R86-1 at 10 Ill. Reg. 14156, effective August 12, 1986; amended in R87-
26 at 12 Ill. Reg. 2900, effective January 15, 1988; amended in R89-1 at 13 Ill. Reg.
18606, effective November 13, 1989; amended in R90-2 at 14 Ill. Reg. 14533,
effective August 22, 1990; amended in R90-11 at 15 Ill. Reg. 9727, effective June 17,
1991; amended in R91-13 at 16 Ill. Reg. 9858, effective June 9, 1992; amended in
R92-10 at 17 Ill. Reg. 5865, effective March 26, 1993; amended in R93-4 at 17 Ill.
481
Reg. 20904, effective November 22, 1993; amended in R94-7 at 18 Ill. Reg. 12500,
effective July 29, 1994; amended in R95-6 at 19 Ill. Reg. 10006, effective June 27,
1995; amended in R95-20 at 20 Ill. Reg. 11263, effective August 1, 1996; amended in
R96-10/R97-3/R97-5 at 21 Ill. Reg. ________, effective ____________________.
SUBPART F: RECYCLABLE MATERIALS UTILIZED FOR
PRECIOUS METAL RECOVERY
Section 726.170
Applicability and requirements
a)
The regulations of this subpart apply to recyclable materials that are
reclaimed to recover economically significant amounts of gold, silver,
platinum, palladium, irraidium, osmium, rhodium, ruthenium, or any
combination of these.
b)
Persons whothat generate, transport or store recyclable materials that are
regulated under this Subpart are subject to the following requirements:
1)
Notification requirements under Section 3010 of the Resource
Conservation and Recovery Act;
2)
35 Ill. Adm. Code 722.Subpart B (for generators), 35 Ill. Adm.
Code 723.120 and 121 (for transporters), and 35 Ill. Adm. Code
725.171 and 725.172 (for persons whothat store).; and
3)
For precious metals exported to or imported from designated
OECD member countries for recovery, 35 Ill. Adm. Code
722.Subpart H and 725.112(a)(2). For precious metals exported
to or imported from non-OECD countries for recovery, 35 Ill.
Adm. Code 722.Subparts E and F.
c)
Persons whothat store recycled materials that are regulated under this
Subpart shall keep the following records to document that they are not
accumulating these materials speculatively (as defined in 35 Ill. Adm.
Code 721.101(c));
1)
Records showing the volume of these materials stored at the
beginning of the calendar year;
2)
The amount of these materials generated or received during the
calendar year; and
3)
The amount of materials remaining at the end of the calendar
year.
482
d)
Recyclable materials that are regulated under this Subpart that are
accumulated speculatively (as defined in 35 Ill. Adm. Code 721.101(c))
are subject to all applicable provisions of 35 Ill. Adm. Code 722 through
725, and 35 Ill. Adm. Code 702, 703 and 705.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE G: WASTE DISPOSAL
CHAPTER I: POLLUTION CONTROL BOARD
SUBCHAPTER c: HAZARDOUS WASTE OPERATING
REQUIREMENTS
PART 728
LAND DISPOSAL RESTRICTIONS
SUBPART A: GENERAL
Section
728.101
Purpose, Scope and Applicability
728.102
Definitions
728.103
Dilution Prohibited as a Substitute for Treatment
728.104
Treatment Surface Impoundment Exemption
728.105
Procedures for case-by-case Extensions to an Effective Date
728.106
Petitions to Allow Land Disposal of a Waste Prohibited under Subpart C
728.107
Waste Analysis and Recordkeeping
728.108
Landfill and Surface Impoundment Disposal Restrictions (Repealed)
728.109
Special Rules for Characteristic Wastes
SUBPART B: SCHEDULE FOR LAND DISPOSAL PROHIBITION
AND ESTABLISHMENT OF TREATMENT STANDARDS
Section
728.110
First Third (Repealed)
728.111
Second Third (Repealed)
728.112
Third Third (Repealed)
728.113
Newly Listed Wastes
728.114
Surface Impoundment exemptions
SUBPART C: PROHIBITION ON LAND DISPOSAL
Section
728.130
Waste Specific Prohibitions -- Solvent Wastes
728.131
Waste Specific Prohibitions -- Dioxin-Containing Wastes
728.132
Waste Specific Prohibitions -- California List Wastes
728.133
Waste Specific Prohibitions: First Third Wastes
483
728.134
Waste Specific Prohibitions -- Second Third Wastes
728.135
Waste Specific Prohibitions -- Third Third Wastes
728.136
Waste Specific Prohibitions -- Newly Listed Wastes
728.137
Waste Specific Prohibitions -- Ignitable and Corrosive Characteristic
Wastes Whose Treatment Standards Were Vacated
728.138
Waste-Specific Prohibitions: Newly-Identified Organic Toxicity
Characteristic Wastes and Newly-Listed Coke By-Product and
Chlorotoluene Production Wastes
728.139
Statutory ProhibitionsWaste-Specific Prohibitions: End-of-pipe CWA,
CWA-Equivalent, and Class I Nonhazardous Waste Injection Well
Treatment Standards; Spent Aluminum Potliners; and Carbamate Wastes
SUBPART D: TREATMENT STANDARDS
Section
728.140
Applicability of Treatment Standards
728.141
Treatment Standards Expressed as Concentrations in Waste Extract
728.142
Treatment Standards Expressed as Specified Technologies
728.143
Treatment Standards Expressed as Waste Concentrations
728.144
Adjustment of Treatment Standard
728.145
Treatment Standards for Hazardous Debris
728.146
Alternative Treatment Standards Based on HTMR
728.148
Universal Treatment Standards
SUBPART E: PROHIBITIONS ON STORAGE
Section
728.150
Prohibitions on Storage of Restricted Wastes
728.Appendix A
Toxicity Characteristic Leaching Procedure (TCLP)
728.Appendix B
Treatment Standards (As concentrations in the Treatment
Residual Extract)
728.Appendix C
List of Halogenated Organic Compounds
728.Appendix D
Wastes Excluded from Lab Packs
728.Appendix E
Organic Lab Packs (Repealed)
728.Appendix F
Technologies to Achieve Deactivation of Characteristics
728.Appendix G
Federal Effective Dates
728.Appendix H
National Capacity LDR Variances for UIC Wastes
728.Appendix I
EP Toxicity Test Method and Structural Integrity Test
728.Appendix J
Recordkeeping, Notification, and Certification Requirements
728.Appendix K
Metal Bearing Wastes Prohibited From Dilution in a Combustion
Unit According to Section 728.103(c)
728.Table A
Constituent Concentrations in Waste Extract (CCWE)
728.Table B
Constituent Concentrations in Wastes (CCW)
728.Table C
Technology Codes and Description of Technology-Based Standards
728.Table D
Technology-Based Standards by RCRA Waste Code
484
728.Table E
Standards for Radioactive Mixed Waste
728.Table F
Alternative Treatment Standards for Hazardous Debris
728.Table G
Alternative Treatment Standards Based on HMTR
728.Table H
Wastes Excluded from CCW Treatment Standards
728.Table T
Treatment Standards for Hazardous Wastes
728.Table U
Universal Treatment Standards (UTS)
AUTHORITY: Implementing Section 22.4 and authorized by Section 27 of the
Environmental Protection Act [415 ILCS 5/22.4 and 27].
SOURCE: Adopted in R87-5 at 11 Ill. Reg. 19354, effective November 12, 1987;
amended in R87-39 at 12 Ill. Reg. 13046, effective July 29, 1988; amended in R89-1
at 13 Ill. Reg. 18403, effective November 13, 1989; amended in R89-9 at 14 Ill. Reg.
6232, effective April 16, 1990; amended in R90-2 at 14 Ill. Reg. 14470, effective
August 22, 1990; amended in R90-10 at 14 Ill. Reg. 16508, effective September 25,
1990; amended in R90-11 at 15 Ill. Reg. 9462, effective June 17, 1991; amendment
withdrawn at 15 Ill. Reg. 14716, October 11, 1991; amended in R91-13 at 16 Ill. Reg.
9619, effective June 9, 1992; amended in R92-10 at 17 Ill. Reg. 5727, effective March
26, 1993; amended in R93-4 at 17 Ill. Reg. 20692, effective November 22, 1993;
amended in R93-16 at 18 Ill. Reg. 6799, effective April 26, 1994; amended in R94-7
at 18 Ill. Reg. 12203, effective July 29, 1994; amended in R94-17 at 18 Ill. Reg.
17563, effective November 23, 1994; amended in R95-6 at 19 Ill. Reg. 9660, effective
June 27, 1995; amended in R95-20 at 20 Ill. Reg. 11100, August 1, 1996; amended in
R96-10/R97-3/R97-5 at 21 Ill. Reg. ________, effective ______________________.
SUBPART A: GENERAL
Section 728.101
Purpose, Scope and Applicability
a)
This Part identifies hazardous wastes that are restricted from land
disposal and defines those limited circumstances under which an
otherwise prohibited waste may continue to be land disposed.
b)
Except as specifically provided otherwise in this Part or 35 Ill. Adm.
Code 721, the requirements of this Part apply to persons that generate or
transport hazardous waste and to owners and operators of hazardous
waste treatment, storage, and disposal facilities.
c)
Restricted wastes may continue to be land disposed as follows:
1)
Where persons have been granted an extension to the effective
date of a prohibition under Subpart C or pursuant to Section
728.105, with respect to those wastes covered by the extension;
485
2)
Where persons have been granted an exemption from a
prohibition pursuant to a petition under Section 728.106, with
respect to those wastes and units covered by the petition;
3)
WA wastes that areis hazardous only because theyit exhibits a
hazardous characteristic of hazardous waste and that areis
otherwise prohibited from land disposal under this Part areis not
prohibited from land disposal if the wastes:
A)
Are Is disposed into a nonhazardous or hazardous waste
injection well, as defined in 35 Ill. Adm. Code
704.106(a); and
B)
Does not exhibit any prohibited characteristic of
hazardous waste identified in 35 Ill. Adm. Code
721.Subpart C at the point of injection; and.
C) If, at the point of generation, the injected wastes include
D001 High TOC subcategory wastes or D012-D017
pesticide wastes that are prohibited under Section
728.117(c), those wastes have been treated to meet the
treatment standards of Section 728.140 prior to injection.
4)
A waste that is hazardous only because it exhibits a characteristic
of hazardous waste and which is otherwise prohibited under this
Part is not prohibited if the waste meets any of the following
criteria, unless the waste is subject to a specified method of
treatment other than DEACT in Section 728.140 or is D003
reactive cyanide:
A)
The waste is managed in a treatment system which
subsequently discharges to waters of the U.S. pursuant to
a permit issued under 35 Ill. Adm. Code 309; or
B)
The waste is treated for purposes of the pretreatment
requirements of 35 Ill. Adm. Code 307 and 310; or
C)
The waste is managed in a zero discharge system engaged
in Clean Water Act-equivalent treatment, as defined in
Section 728.137(a); and
D)
The waste no longer exhibits a prohibited characteristic of
hazardous waste at the point of land disposal (i.e.,
placement in a surface impoundment).
486
d)
This Part does not affect the availability of a waiver under Section
121(d)(4) of the Comprehensive Environmental Response,
Compensation, and Liability Act of 1980 (CERCLA) (42 U.S.C.
§§ 9601 et seq.).
e)
The following hazardous wastes are not subject to any provision of this
Part:
1)
Wastes generated by small quantity generators of less than 100 kg
of non-acute hazardous waste or less than 1 kg of acute hazardous
waste per month, as defined in 35 Ill. Adm. Code 721.105;
2)
Waste pesticides that a farmer disposes of pursuant to 35 Ill.
Adm. Code 722.170;
3)
Wastes identified or listed as hazardous after November 8, 1984,
for which USEPA has not promulgated land disposal prohibitions
or treatment standards; or
4)
De minimis losses of waste that exhibits a characteristic of
hazardous waste to wastewaters treatment systems of commercial
chemical product or chemical intermediates that are ignitable
(D001) or corrosive (D002) or that are organic constituents that
exhibit the characteristic of toxicity (D012-D043) and that
contain underlying hazardous constituents, as defined in Section
728.102 of this Part, are not considered to be prohibited wastes
and are defined as follows:. “De minimis” is defined as l
A)
Losses from normal material handling operations (e.g.,
spills from the unloading or transfer of materials from
bins or other containers or leaks from pipes, valves, or
other devices used to transfer materials); minor leaks of
process equipment, storage tanks, or containers; leaks
from well-maintained pump packings and seals; sample
purgings; relief device discharges; discharges from safety
showers and rinsing and cleaning of personal safety
equipment; and rinsate from empty containers or from
containers that are rendered empty by that rinsing; and
laboratory waste that does not exceed one per cent of the
total flow of wastewater into the facility’s headworks on
an annual basis, or with a combined annualized average
concentration not exceeding one part per million (ppm) in
the headworks of the facility’s wastewater treatment or
pretreatment facility; or
487
B)
Decharacterized waste that is injected into Class I
nonhazardous wells in which the decharacterized waste’s
combined volume is less than one per cent of the total
flow at the wellhead on an annualized basis and no greater
than 10,000 gallons per day, and in which any underlying
hazardous constituents in the characteristic waste are
present at the point of generation at levels less than 10
times the treatment standards found at Section 728.148.
5)
Land disposal prohibitions for hazardous characteristic wastes do
not apply to laboratory wastes displaying the characteristic of
ignitability (D001), corrosivity (D002), or organic toxicity (D012
through D043) that are mixed with other plant wastewaters at
facilities whose ultimate discharge is subject to regulation under
the CWA (including wastewaters at facilities that have eliminated
the discharge of wastewater), provided that the annualized flow
of laboratory wastewater into the facility’s headwork does not
exceed one percent or that the laboratory wastes’ combined
annualized average concentration does not exceed one part per
million in the facility’s headworks.
f)
A universal waste handler or universal waste transporter (as defined in
35 Ill. Adm. Code 720.110) is exempt from Sections 728.107 and
268.150 for the hazardous wastes listed below. Such a handler or
transporter is subject to regulation under 35 Ill. Adm. Code 733.
1)
Batteries, as described in 35 Ill. Adm. Code 733.102;
2)
Pesticides, as described in 35 Ill. Adm. Code 733.103; and
3)
Thermostats, as described in 35 Ill. Adm. Code 733.104.
g)
This Part is cumulative with the land disposal restrictions of 35 Ill.
Adm. Code 729. The Environmental Protection Agency (Agency) shall
not issue a wastestream authorization pursuant to 35 Ill. Adm. Code 709
or Sections 22.6 or 39(h) of the Environmental Protection Act [415
ILCS 5/22.6 or 39(h)] unless the waste meets the requirements of this
Part as well as 35 Ill. Adm. Code 729.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 728.102
Definitions
488
When used in this Part, the following terms have the meanings given below. All other
terms have the meanings given under 35 Ill. Adm. Code 702.110, 720.102720.110, or
721.103721.102 through 721.104.
“Agency” means the Illinois Environmental Protection Agency.
“Board” means the Illinois Pollution Control Board.
“CERCLA” means the Comprehensive Environmental Response,
Compensation, and Liability Act of 1980 (42 U.S.C. 9601 et seq.)
“Debris” means solid material exceeding a 60 mm particle size that is
intended for disposal and that is: a manufactured object; plant or animal
matter; or natural geologic material. However, the following materials
are not debris: any material for which a specific treatment standard is
provided in 728.Subpart D of this Part, namely lead acid batteries,
cadmium batteries, and radioactive lead solids; process residuals, such as
smelter slag and residues from the treatment of waste, wastewater,
sludges, or air emission residues; and intact containers of hazardous
waste that are not ruptured and that retain at least 75% of their original
volume. A mixture of debris that has not been treated to the standards
provided by Section 728.145 of this Part and other material is subject to
regulation as debris if the mixture is comprised primarily of debris, by
volume, based on visual inspection.
“End-of-pipe” refers to the point where effluent is discharged to the
environment.
“Halogenated organic compounds” or “HOCs” means those compounds
having a carbon-halogen bond that are listed under Section
728.Appendix C.
“Hazardous constituent or constituents” means those constituents listed
in 35 Ill. Adm. Code 721.Appendix H.
“Hazardous debris” means debris that contains a hazardous waste listed
in 35 Ill. Adm. Code 721.Subpart D or that exhibits a characteristic of
hazardous waste identified in 35 Ill. Adm. Code 721.Subpart C.
“Inorganic metal-bearing waste” is one for which USEPA has
established treatment standards for metal hazardous constituents that does
not otherwise contain significant organic or cyanide content, as described
in Section 728.103(b)(1), and which is specifically listed in Section
728.Appendix K.
489
“Inorganic Ssolid Ddebris” are nonfriable inorganic solids that are
incapable of passing through a 9.5 mm standard sieve and that require
cutting or crushing and grinding in mechanical sizing equipment prior to
stabilization, limited to the following inorganic or metal materials:
Metal slags (either dross or scoria).
Glassified slag.
Glass.
Concrete (excluding cementitious or pozzolanic stabilized
hazardous wastes).
Masonry and refractory bricks.
Metal cans, containers, drums, or tanks.
Metal nuts, bolts, pipes, pumps, valves, appliances, or industrial
equipment.
Scrap metal, as defined in 35 Ill. Adm. Code 721.101(c)(6).
“Land disposal” means placement in or on the land, except in a
corrective action management unit, and includes, but is not limited to,
placement in a landfill, surface impoundment, waste pile, injection well,
land treatment facility, salt dome formation, salt bed formation,
underground mine, or cave or placement in a concrete vault or bunker
intended for disposal purposes.
“Nonwastewaters” are wastes that do not meet the criteria for
“wastewaters” in this Section.
“Polychlorinated biphenyls” or “PCBs” are halogenated organic
compounds defined in accordance with 40 CFR 761.3, incorporated by
reference in 35 Ill. Adm. Code 720.111.
“ppm” means parts per million.
“RCRA corrective action” means corrective action taken under 35 Ill.
Adm. Code 724.200 or 725.193, 40 CFR 264.100 or 265.93 (199496),
or similar regulations in other States with RCRA programs authorized by
U.S. EPA pursuant to 40 CFR 271 (199496).
490
“Stormwater impoundments” are surface impoundments that receive wet
weather flow and which receive process waste only during wet weather
events.
“Underlying hazardous constituent” means any regulated constituent
listed in Section 728.Table U, “Universal Treatment Standards (UTS)”,
except fluoride, vanadium, and zinc, that can reasonably be expected to
be present, at the point of generation of the hazardous waste, at a
concentration above the constituent-specific UTS treatment standard.
“U.S. EPA” or “USEPA” means the United States Environmental
Protection Agency.
“Wastewaters” are wastes that contain less than 1% by weight total
organic carbon (TOC) and less than 1% by weight total suspended solids
(TSS), with the following exceptions:.
F001, F002, F003, F004, and F005 solvent-water mixtures that
contain less than 1% by weight TOC or less than 1% by weight
total F001, F002, F003, F004, and F005 solvent constituents
listed in Table A.
K011, K013, and K014 wastewaters (as generated) that contain
less than 5% by weight TOC and less than 1% by weight TSS.
K103 and K104 wastewaters that contain less than 4% by weight
TOC and less than 1% by weight TSS.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 728.103
Dilution Prohibited as a Substitute for Treatment
a)
Except as provided in subsection (b) belowof this Section, no generator,
transporter, handler, or owner or operator of a treatment, storage, or
disposal facility shall in any way dilute a restricted waste or the residual
from treatment of a restricted waste as a substitute for adequate treatment
to achieve compliance with Subpart D of this Part, to circumvent the
effective date of a prohibition in Subpart C of this Part, to otherwise
avoid a prohibition in Subpart C of this Part, or to circumvent a land
disposal restriction imposed by RCRA section 3004.
b)
Dilution of wastes that areis hazardous only because theyit exhibits a
characteristic of hazardous waste in a treatment system whichthat treats
wastes subsequently discharged to a water of the State pursuant to an
NPDES permit issued under 35 Ill. Adm. Code 309, that treats wastes in
491
a CWA-equivalent treatment system, or whichthat treats wastes for
purposes of pretreatment requirements under 35 Ill. Adm. Code 310 is
not impermissible dilution for purposes of this Section unless a method
other than DEACT has been specified in Section 728.140 as the
treatment standard in Section 728.142, or unless the waste is a D003
reactive cyanide wastewater or nonwastewater.
c)
Combustion of waste designated by any of the USEPA hazardous waste
codes listed in Section 728.Appendix J is prohibited, unless the waste
can be demonstrated to comply with one or more of the following
criteria at the point of generation or after any bona fide treatment, such
as cyanide destruction prior to combustion (unless otherwise specifically
prohibited from combustion):
1)
The waste contains hazardous organic constituents or cyanide at
levels exceeding the constituent-specific treatment standard found
in Section 728.148;
2)
The waste consists of organic, debris-like materials (e.g., wood,
paper, plastic, or cloth) contaminated with an inorganic metal-
bearing hazardous waste;
3)
The waste has reasonable heating value, such as greater than or
equal to 5000 BTU per pound, at the point of generation;
4)
The waste is co-generated with wastes for which combustion is a
required method of treatment;
5)
The waste is subject to any federal or state requirements
necessitating reduction of organics (including biological agents);
or
6)
The waste contains greater than one percent Total Organic
Carbon (TOC).
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 728.107
Waste Analysis and Recordkeeping
a)
Except as specified in Section 728.132, where a generator’s waste is
listed in 35 Ill. Adm. Code 721.Subpart D or if the waste exhibits one or
more of the characteristics set out at 35 Ill. Adm. Code 721.Subpart C,
the generator shall test its waste, or test an extract using the Toxicity
Characteristic Leaching Procedure, Method 1311, in “Test Methods for
Evaluating Solid Waste, Physical/Chemical Methods”, U.S. EPA
492
Publication SW-846, as incorporated by reference in 35 Ill. Adm. Code
720.111, or use knowledge of the waste to determine if the waste is
restricted from land disposal under this Part. If the generator determines
that its waste displays the characteristic of ignitability (D001) (and is not
in the High TOC Ignitable Liquids Subcategory or is not treated by
CMBST or RORGS of Section 728.Table C of this Part), or the waste
displays the characteristic of corrosivity (D002), reactivity (D003), or
organic toxicity (D012 through D043), and the waste is prohibited under
Sections 728.137, or the waste displays the characteristic of organic
toxicity (D012-D043) and is prohibited under Section 728.138, and
728.139, the generator shall determine what underlying hazardous
constituents (as defined in Section 728.102), are reasonably expected to
be present in the D001, D002, D003, or D012 through D043 waste.
1)
If a generator determines that it is managing a restricted waste
under this Part and the waste does not meet the applicable
treatment standards set forth in 728.Subpart D of this Part or
exceeds the applicable prohibition levels set forth in Section
728.132 or 728.139, the generator shall notify thesend a one-time
written notice to each treatment or storage facility in writing with
eachthe initial shipment of waste. No further notification is
necessary until such time that the waste or facility change, in
which case a new notification must be sent and a copy placed in
the generator’s file. The notice must include the following
information:
A)
U.S. EPA hazardous waste number;
B)
The waste constituents that the treater will monitor, if
monitoring will not include all regulated constituents, for
wastes F001 through F005, F039, D001, D002, D003,
and D012 through D043, and wastes prohibited pursuant
to Section 728.132 or Section 3004(d) of the Resource
Conservation and Recovery Act, referenced in Section
728.139. The generator must also include whether the
waste is a nonwastewater or wastewater (as defined in
Section 728.102 (d) and (f)) and indicate the subcategory
of the waste (such as “D003 reactive cyanide”) if
applicable;
C)
The manifest number associated with the shipment of
waste;
D)
For hazardous debris, the contaminants subject to
treatment, as provided by Section 728.145(b), and the
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following statement: “This hazardous debris is subject to
the alternative treatment standards of 35 Ill. Adm. Code
728.145”; and
E)
Waste analysis data, where available; and.
F) The date on which the waste is subject to the prohibitions.
2)
If a generator determines that it is managing a restricted waste
under this Part and determines that the waste can be land
disposed without further treatment, with eachthe initial shipment
of waste the generator shall submit a one-time written notice and
a certification to theeach treatment, storage, or land disposal
facility stating that the waste meets the applicable treatment
standards set forth in 728.Subpart D of this Part and setting forth
the applicable prohibition levels set forth in Section 728.132 or
RCRA Section 3004(d), referenced in Section 728.139. A
generator of hazardous debris that is excluded from the definition
of hazardous waste under 35 Ill. Adm. Code 721.103(e)(2), 35
Ill. Adm. Code 728.103(f)(2), or 35 Ill. Adm. Code 720.122
(i.e. debris that is delisted), however, is not subject to these
notification and certififcation certification requirements. If the
waste changes, the generator shall send a new notice and
certification to the receiving facility, and place a copy in its files.
A)
The notice must include the following information:
i)
U.S. EPA hazardous waste number;
ii)
The waste constituents that the treater will
monitor, if monitoring will not include all
regulated constituents, for wastes F001 through
F005, F039, D001, D002, D003, and D012
through D043, and wastes prohibited pursuant to
Section 728.132 or Section 3004(d) of the
Resource Conservation and Recovery Act,
referenced in Section 728.139. The generator
must also include whether the waste is a
wastewater or nonwastewater (as defined in
Section 728.102 (d) and (f)), and indicate the
subcategory of the waste (such as “D003, reactive
cyanide”), if applicable;
iii)
The manifest number associated with the shipment
of waste; and
494
iv)
Waste analysis data, where available.
B)
The certification must be signed by an authorized
representative and must state the following:
I certify under penalty of law that I personally have
examined and am familiar with the waste through analysis
and testing or through knowledge of the waste to support
this certification that the waste complies with the
treatment standards specified in 35 Ill. Adm. Code
728.Subpart D of this Part and all applicable prohibitions
set forth in 35 Ill. Adm. Code 728.132, 728.139, or
Section 3004(d) of the Resource Conservation and
Recovery Act. I believe that the information I submitted
is true, accurate, and complete. I am aware that there are
significant penalties for submitting a false certification,
including the possibility of a fine and imprisonment.
3)
If a generator’s waste is subject to an exemption from a
prohibition on the type of land disposal method utilized for the
waste (such as, but not limited to, a case-by-case extension under
Section 728.105, an exemption under Section 728.106, an
extension under Section 728.101(c)(3), or a nationwide capacity
variance under 40 CFR 268.Subpart C (199496)), the generator
shall submit a one-time written notice with eachthe initial
shipment of the waste to theeach facility receiving the generator’s
waste stating that the waste is not prohibited from land disposal.
If the waste changes, the generator shall send a new notice and
certification to the receiving facility, and place a copy in its files.
The notice must include the following information:
A)
U.S. EPA hazardous waste number;
B)
The waste constituents that the treater will monitor, if
monitoring will not include all regulated constituents, for
wastes F001 through F005, F039, D001, D002, D003,
and D012 through D043. The generator must also include
whether the waste is a nonwastewater or wastewater (as
defined in Section 728.102 (d) and (f)), and indicate the
subcategory of the waste (such as “D003 reactive
cyanide”), if applicable;
C)
The manifest number associated with the shipment
of waste;
495
D)
Waste analysis data, where available;
E)
For hazardous debris, when using the alternative treatment
technologies provided by Section 728.145:
i)
The contaminants subject to treatment, as provided
by Section 728.145(b);
ii)
An indication that these contaminants are being
treated to comply with Section 728.145;
F)
For hazardous debris when using the treatment standards
for the contaminating waste(s) in Section 728.140: the
requirements described in subsections (a)(3)(A) through
(a)(3)(D) above and subsection (a)(3)(G) belowof this
Section; and,
G)
The date on which the waste is subject to the prohibitions.
4)
If a generator is managing a prohibited waste in tanks,
containers, or containment buildings regulated under 35 Ill. Adm.
Code 722.134 and is treating such waste in tanks, containers, or
containment buildings to meet applicable treatment standards
under 728.Subpart D of this Part, the generator shall develop and
follow a written waste analysis plan that describes the procedures
the generator will carry out to comply with the treatment
standards. (A generator treating hazardous debris under the
alternative treatment standards of Section 728.Table F, however,
is not subject to these waste analysis requirements.) The plan
must be kept on-site in the generator’s records, and the following
requirements must be met:
A)
The waste analysis plan must be based on a detailed
chemical and physical analysis of a representative sample
of the prohibited wastes being treated, and it must contain
all information necessary to treat the wastes in accordance
with the requirements of this Part, including the selected
testing frequency.
B)
Such plan must be filed with the Agency a minimum of 30
days prior to the treatment activity, with delivery verified.
496
C)
Wastes shipped off-site pursuant to this subsection must
comply with the notification requirements of Section
728.107(a)(2).
5)
If a generator determines whether the waste is restricted based
solely on the generator’s knowledge of the waste, the generator
shall retain all supporting data used to make this determination
on-site in the generator’s files. If a generator determines whether
the waste is restricted based on testing the waste or an extract
developed using the test method described in Section
728.Appendix A, the generator shall retain all waste analysis data
on site in its files.
6)
If a generator determines, subsequent to the time of generation,
that it is managing a restricted waste that is excluded from the
definition of hazardous or solid waste or exempt from regulation
as a RCRA hazardous waste under 35 Ill. Adm. Code 721.102
through 721.106, the generator shall place, in the facility’s file, a
one-time notice stating such generation, the subsequent exclusion
from the definition of hazardous or solid waste or exemption
from regulation as a RCRA hazardous waste, and the disposition
of the waste.
7)
A generator shall retain on-site a copy of all notices,
certifications, demonstrations, waste analysis data, and other
documentation produced pursuant to this Section for at least five
years from the date that the waste that is the subject of such
documentation was last sent to on-site or off-site treatment,
storage, or disposal. The five year record retention period is
automatically extended during the course of any unresolved
enforcement action regarding the regulated activity, or as
requested by the Agency. The requirements of this subsection
apply to solid wastes even when the hazardous characteristic is
removed prior to disposal, when the waste is excluded from the
definition of hazardous or solid waste under 35 Ill. Adm. Code
721.102 through 721.106, or when the waste is exempted from
regulation as a RCRA hazardous waste subsequent to the point of
generation.
8)
If a generator is managing a lab pack that contains wastes
identified in Section 728.Appendix D and wishes to use the
alternative treatment standard under Section 728.142(c), with
each shipment of waste the generator shall submit a notice to the
treatment facility in accordance with subsection (a)(1) aboveof
this Section, except that underlying hazardous constituents need
497
not be determined. The generator shall also comply with the
requirements in subsections (a)(5) and (a)(6) aboveof this Section
and shall submit the following certification, which must be signed
by an authorized representative:
I certify under penalty of law that I personally have
examined and am familiar with the waste and that the lab
pack does not contain any of the wastes identified in 35
Ill. Adm. Code 728.Appendix D. I am aware that there
are significant penalties for submitting a false
certification, including the possibility of fine or
imprisonment.
9)
This subsection corresponds with 40 CFR 268.7(a)(9), marked
“reserved” by U.S. EPA at 59 Fed. Reg. 48045 (Sept. 19,
1994). This statement maintains structural consistency with
federal regulations.
10)
Small quantity generators with tolling agreements pursuant to 35
Ill. Adm. Code 722.120(e) shall comply with the applicable
notification and certification requirements of subsection (a)
aboveof this Section for the initial shipment of the waste subject
to the agreement. Such generators shall retain on-site a copy of
the notification and certification, together with the tolling
agreement, for at least three years after termination or expiration
of the agreement. The three-year record retention period is
automatically extended following notification pursuant to Section
31(d) of the Environmental Protection Act until either any
subsequent enforcement action is resolved or until the Agency
notifies the generator documents need not be retained.
b)
Treatment facilities shall test their wastes according to the frequency
specified in their waste analysis plans, as required by 35 Ill. Adm. Code
724.113 or 725.113. Such testing must be performed as provided in
subsections (b)(1), (b)(2), and (b)(3) belowof this Section.
1)
For wastes with treatment standards expressed as concentrations
in the waste extract (Section 728.141), the owner or operator of
the treatment facility shall test the treatment residues or an extract
of such residues developed using the test method described in
Section 728.Appendix A to assure that the treatment residues or
extract meet the applicable treatment standards.
2)
For wastes prohibited under Section 728.132 or 728.139 that are
not subject to any treatment standards under 728.Subpart D of
498
this Part, the owner or operator of the treatment facility shall test
the treatment residues according to the generator testing
requirements specified in Section 728.132 to assure that the
treatment residues comply with the applicable prohibitions.
3)
For wastes with treatment standards expressed as concentrations
in the waste (Section 728.143), the owner or operator of the
treatment facility shall test the treatment residues (not an extract
of such residues) to assure that the treatment residues meet the
applicable treatment standards.
4)
A notice must be sent with eachthe initial waste shipment to
theeach land disposal facility that includes the following
information, except that debris excluded from the definition of
the hazardous waste under 35 Ill. Adm. Code 721.103(e) (i.e.,
debris treated by an extraction or destruction technology provided
by Section 728.Table F, and debris that is delisted) is subject to
the notififcation and certification requirements of subsection (d)
belowof this Section rather than these notification requirements:.
No further notification is necessary until such time that the waste
or receiving facility change, in which case a new notice must be
sent and a copy placed in the treatment facility’s file.
A)
U.S. EPA hazardous waste number;
B)
The waste constituents to be monitoredthat the treater will
monitor, if monitoring will not include all regulated
constituents, for wastes F001 through F005, F039, D001,
D002, D003, and D012 through D043, and wastes
prohibited pursuant to Section 728.132 or Section 3004(d)
of the Resource Conservation and Recovery Act,
referenced in Section 728.139. The generator must also
include whether the waste is a nonwastewater or
wastewater (as defined in Section 728.102 (d) and (f)),
and indicate the subcategory of the waste (such as “D003
reactive cyanides”), if applicable;
C)
The manifest number associated with the shipment of
waste; and
D)
Waste analysis data, where available.
5)
The treatment facility owner or operator shall submit a
certification with each shipment of waste or treatment residue of
a restricted waste to the land disposal facility stating that the
499
waste or treatment residue has been treated in compliance with
the treatment standards specified in 728.Subpart D of this Part
and the applicable prohibitions set forth in Section 728.132 or
728.139. Debris excluded from the definition of hazardous waste
under 35 Ill. Adm. Code 721.103(e) (i.e., debris treated by an
extraction or destruction technology provided by Section
728.Table F, and debris that is delisted), however, is subject to
the notififcation and certification requirements of subsection (d)
belowof this Section rather than the certification requirements of
this subsection.
A)
For wastes with treatment standards expressed as
concentrations in the waste extract or in the waste
(Sections 728.141 or 728.143), or for wastes prohibited
under Section 728.132 or 728.139 that are not subject to
any treatment standards under 728.Subpart D of this Part,
the certification must be signed by an authorized
representative and must state the following:
I certify under penalty of law that I have
personally examined and am familiar with the
treatment technology and operation of the
treatment process used to support this certification
and that, based on my inquiry of those individuals
immediately responsible for obtaining this
information, I believe that the treatment process
has been operated and maintained properly, so as
to comply with the performance levels specified in
35 Ill. Adm. Code 728.Subpart D of this Part and
all applicable prohibitions set forth in 35 Ill. Adm.
Code 728.132 or 728.139 or Section 3004(d) of
the Resource Conservation and Recovery Act
without impermissible dilution of the prohibited
waste. I am aware that there are significant
penalties for submitting a false certification,
including the possibility of fine and imprisonment.
B)
For wastes with treatment standards expressed as
technologies (Section 728.142), the certification must be
signed by an authorized representative and must state the
following:
I certify under penalty of law that the waste has
been treated in accordance with the requirements
of 35 Ill. Adm. Code 728.142. I am aware that
500
there are significant penalties for submitting a false
certification, including the possibility of fine and
imprisonment.
C)
For wastes with treatment standards expressed as
concentrations in the waste pursuant to Section 728.143,
if compliance with the treatment standards in 728.Subpart
D of this Part is based in part or in whole on the
analytical detection limit alternative specified in Section
728.143(c), the certification also must state the following:
I certify under penalty of law that I have
personally examined and am familiar with the
treatment technology and operation of the
treatment process used to support this certification
and that, based on my inquiry of those individuals
immediately responsible for obtaining this
information, I believe that the nonwastewater
organic constituents have been treated by
incineration in units operated in accordance with
35 Ill. Adm. Code 724.Subpart O or 35 Ill. Adm.
Code 725.Subpart O, or by combustion in fuel
substitution units operating in accordance with
applicable technical requirements, and I have been
unable to detect the nonwastewater organic
constituents despite having used best good faith
efforts to analyze for such constituents. I am
aware that there are significant penalties for
submitting a false certification, including the
possibility of fine and imprisonment.
D)
For characteristic wastes D001, D002, D003, and D012
through D043 that are subject to the treatment standards in
Section 728.140 (other than those expressed as a required
method of treatment), that are reasonably expected to
contain underlying hazardous constituents (as defined in
Section 728.102(i)), that are treated on-site to remove the
hazardous characteristic, and that are then sent off-site for
treatment of underlying hazardous constituents, the
certification must state the following:
I certify under penalty of law that the waste has
been treated in accordance with the requirements
of 35 Ill. Adm. Code 728.140 to remove the
hazardous characteristic. This decharacterized
501
waste contains underlying hazardous constituents
that require further treatment to meet universal
treatment standards. I am aware that there are
significant penalties for submitting a false
certification, including the possibility of fine and
imprisonment.
E)
For characteristic wastes D001, D002, D003, and D012
through D043 that contain underlying hazardous
constituents, as defined in Section 728.102(i), and which
are treated on-site to remove the hazardous characteristic
and to treat underlying hazardous constituents to levels set
forth in the Sections 728.148 and 728.Table U Universal
Treatment Standards, the certification must state the
following:
I certify under penalty of law that the waste has
been treated in accordance with the requirements
of 35 Ill. Adm. Code 728.140 to remove the
hazardous characteristic, and that underlying
hazardous constituents, as defined in Section
728.102, have been treated on-site to meet the
Sections 728.148 and 728.Table U Universal
Treatment Standards. I am aware that there are
significant penalties for submitting a false
certification, including the possibility of fine and
imprisonment.
6)
If the waste or treatment residue will be further managed at a
different treatment or storage facility, the treatment, storage, or
disposal facility sending the waste or treatment residue off-site
must comply with the notice and certification requirements
applicable to generators under this Section.
7)
Where the wastes are recyclable materials used in a manner
constituting disposal subject to the provisions of 35 Ill. Adm.
Code 726.120(b), regarding treatment standards and prohibition
levels, the owner or operator of a treatment facility (i.e. the
recycler) is not required to notify the receiving facility pursuant
to subsection (b)(4) aboveof this Section. With each shipment of
such wastes the owner or operator of the recycling facility shall
submit a certification described in subsection (b)(5) aboveof this
Section and a notice that includes the information listed in
subsection (b)(4) aboveof this Section (except the manifest
number) to the Agency. The recycling facility also shall keep
502
records of the name and location of each entity receiving the
hazardous waste-derived product.
c)
Except where the owner or operator is disposing of any waste that is a
recyclable material used in a manner constituting disposal pursuant to 35
Ill. Adm. Code 726.120(b), the owner or operator of any land disposal
facility disposing any waste subject to restrictions under this Part shall:
1)
Have copies of the notice and certification specified in subsection
(a) or (b) aboveof this Section and the certification specified in
Section 728.108, if applicable.
2)
Test the waste, or an extract of the waste or treatment residue
developed using the test method described in Section
728.Appendix A or using any methods required by generators
under Section 728.132, to assure that the waste or treatment
residue is in compliance with the applicable treatment standards
set forth in 728.Subpart D of this Part and all applicable
prohibitions set forth in Sections 728.132 or 728.139. Such
testing must be performed according to the frequency specified in
the facility’s waste analysis plan as required by 35 Ill. Adm.
Code 724.113 or 725.113.
3)
Where the owner or operator is disposing of any waste that is
subject to the prohibitions under Section 728.133(f) but not
subject to the prohibitions set forth in Section 728.132, the owner
or operator shall ensure that such waste is the subject of a
certification according to the requirements of Section 728.108
prior to disposal in a landfill or surface impoundment unit, and
that such disposal is in accordance with the requirements of
Section 728.105(h)(2). The same requirement applies to any
waste that is subject to the prohibitions under Section 728.133(f)
and also is subject to the statutory prohibitions in the codified
prohibitions in Section 728.139 or Section 728.132.
4)
Where the owner or operator is disposing of any waste that is a
recyclable material used in a manner constituting disposal subject
to the provisions of 35 Ill. Adm. Code 726.120(b), the owner or
operator is not subject to subsections (c)(1) through (c)(3)
aboveof this Section with respect to such waste.
d)
A generator or treater that first claims that hazardous debris is excluded
from the definition of hazardous waste under 35 Ill. Adm. Code
721.103(e) (i.e., debris treated by an extraction or destruction
technology provided by Section 728.Table F, and debris that has been
503
delisted) is subject to the following notification and certification
requirements:
1)
A one-time notification must be submitted to the Agency
including the following information:
A)
The name and address of the RCRA Subtitle D (municipal
solid waste landfill) facility receiving the treated debris;
B)
A description of the hazardous debris as initially
generated, including the applicable U.S. EPA hazardous
waste numbers; and
C)
For debris excluded under 35 Ill. Adm. Code
728.103(f)(2)721.103(e)(1), the technology from Section
728.Table F used to treat the debris.
2)
The notification must be updated if the debris is shipped to a
different facility and, for debris excluded 35 Ill. Adm. Code
721.2(d)(1), if a different type of debris is treated or if a different
technology is used to treat the debris.
3)
For debris excluded under 35 Ill. Adm. Code
728.103(f)(2)721.103(e)(1), the owner or operator of the
treatment facility shall document and certify compliance with the
treatment standards of Section 728.Table F, as follows:
A)
Records must be kept of all inspections, evaluations, and
analyses of treated debris that are made to determine
compliance with the treatment standards;
B)
Records must be kept of any data or information the
treater obtains during treatment of the debris that
identifies key operating parameters of the treatment unit;
and
C)
For each shipment of treated debris, a certification of
compliance with the treatment standards must be signed
by an authorized representative and placed in the facility’s
files. The certification must state the following: “I
certify under penalty of law that the debris has been
treated in accordance with the requirements of 35 Ill.
Adm. Code 728.145. I am aware that there are
significant penalties for making a false certification,
including the possibility of fine and imprisonment.”
504
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 728.109
Special Rules for Characteristic Wastes
a)
The initial generator of a solid waste shall determine each U.S. EPA
hazardous waste number (waste code) applicable to the waste in order to
determine the applicable treatment standards under 728.Subpart D of this
Part. For purposes of this Part, the waste must carry the waste code for
any applicable listing under 35 Ill. Adm. Code 721.Subpart D. In
addition, the waste must carry one or more of the waste codes under 35
Ill. Adm. Code 721.Subpart C where the waste exhibits a characteristic,
except in the case when the treatment standard for the waste code listed
in 35 Ill. Adm. Code 721.Subpart D operates in lieu of the standard for
the waste code under 35 Ill. Adm. Code 721.Subpart C, as specified in
subsection (b) belowof this Section. If the generator determines that its
waste displays thea characteristic of ignitability (D001)hazardous waste
(and the waste is not in thea D004 through D011 waste, a High TOC
Ignitable Liquids SubcategoryD001 waste, orand is not treated by
CMBST or RORGS, as described in Section 728.Table C), that its waste
displays the characteristic of corrosivity (D002) and is prohibited under
Section 728.137, or that its waste displays the characteristic of toxicity
(D012 through D043) and is prohibited under Section 728.138, the
generator shall determine what underlying hazardous constituents (as
defined in Section 728.102) are reasonably expected to be present in the
D001, D002, or D012 through D043 wasteabove the universal treatment
standards set forth in Sections 728.148 and 728.Table U.
b)
Where a prohibited waste is both listed under 35 Ill. Adm. Code
721.Subpart D and exhibits a characteristic under 35 Ill. Adm. Code
721.Subpart C, the treatment standard for the waste code listed in 35 Ill.
Adm. Code 721.Subpart D will operate in lieu of the standard for the
waste code under 35 Ill. Adm. Code 721.Subpart C, provided that the
treatment standard for the listed waste includes a treatment standard for
the constituent that causes the waste to exhibit the characteristic.
Otherwise, the waste must meet the treatment standards for all applicable
listed and characteristic waste codes.
c)
In addition to any applicable standards determined from the initial point
of generation, no prohibited waste that exhibits a characteristic under 35
Ill. Adm. Code 721.Subpart C shall be land disposed unless the waste
complies with the treatment standards under 728.Subpart D of this Part.
d)
A wastes that exhibits a characteristic is also subject to Section 728.107
requirements, except that once the waste is no longer hazardous, a one
505
timeone-time notification and certification must be placed in the
generator’s or treater’s files and sent to the Agency, except for those
facilities described in subsection (f) below. The notification and
certification that is placed in the generator’s or treater’s files must be
updated if the process or operation generating the waste changes or if the
subtitle D facility receiving the waste changes. However, the generator
or treater need only notify the Agency on an annual basis if such changes
occur. Such notification and certification should be sent to the Agency
by the end of the year, but no later than December 31.
1)
The notification must include the following information:
A)
TFor a characteristic waste other than one managed on
site in a wastewater treatment system subject to the federal
Clean Water Act (CWA), a zero-discharger engaged in
CWA-equivalent treatment, or a Class I nonhazardous
waste injection well, the name and address of the RCRA
Subtitle D (municipal solid waste landfill) facility
receiving the waste shipment; and
B)
AFor a waste that exhibits a characteristic of hazardous
waste, a description of the waste as initially generated,
including the applicable U.S. EPA hazardous waste
numbers, the treatability group(s), and the underlying
hazardous constituents (as defined in Section 728.102(i))
in D001 and D002 wastes prohibited under Section
728.137 or D012 through D043 wastes prohibited under
Section 728.138.
2)
The certification must be signed by an authorized representative
and must state the language found in Section 728.107(b)(5)(A).
If treatment removes the characteristic but does not treat
underlying hazardous constituents, then the certification found in
Section 728.107(b)(5)(D) applies.
3)
For a characteristic waste whose ultimate disposal will be into a
Class I nonhazardous waste injection well, and for which
compliance with the treatment standards set forth in Sections
728.148 and 728.Table U for underlying hazardous constituents
is achieved through pollution prevention that meets the criteria set
forth at 35 Ill. Adm. Code 738.101(d), the following information
must also be included:
A)
A description of the pollution prevention mechanism and
when it was implemented if already complete;
506
B)
The mass of each underlying hazardous constituent before
pollution prevention;
C)
The mass of each underlying hazardous constituent that
must be removed, adjusted to reflect variations in mass
due to normal operating conditions; and
D)
The mass reduction of each underlying hazardous
constituent that is achieved.
e)
For a decharacterized waste managed on-site in a wastewater treatment
system subject to the federal Clean Water Act (CWA) or zero-
dischargers engaged in CWA-equivalent treatment, compliance with the
treatment standards set forth in Sections 728.148 and 728.Table D must
be monitored quarterly, unless the treatment is aggressive biological
treatment, in which case compliance must be monitored annually.
Monitoring results must be kept in on-site files for 5 years.
f)
For a decharacterized waste managed on-site in a wastewater treatment
system subject to the federal Clean Water Act (CWA) for which all
underlying hazardous constituents (as defined in Section 728.102) are
addressed by a CWA permit, this compliance must be documented and
this documentation must be kept in on-site files.
g)
For a characteristic waste whose ultimate disposal will be into a Class I
nonhazardous waste injection well that qualifies for the de minimis
exclusion described in Section 728.101, information supporting that
qualification must be kept in on-site files.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
SUBPART B: SCHEDULE FOR LAND DISPOSAL PROHIBITION
AND ESTABLISHMENT OF TREATMENT STANDARDS
Section 728.110
First Third (Repealed)
The Board incorporates by reference 40 CFR 268.10 (1991). This Section incorporates
no later editions or amendments.
(Source: Repealed at 21 Ill. Reg. ________, effective ____________________)
Section 728.111
Second Third (Repealed)
507
The Board incorporates by reference 40 CFR 268.11 (1991). This Section incorporates
no later editions or amendments.
(Source: Repealed at 21 Ill. Reg. ________, effective ____________________)
Section 728.112
Third Third (Repealed)
The Board incorporates by reference 40 CFR 268.12 (1991). This Section incorporates
no later editions or amendments.
(Source: Repealed at 21 Ill. Reg. ________, effective ____________________)
SUBPART C: PROHIBITION ON LAND DISPOSAL
Section 728.139
Statutory ProhibitionsWaste-Specific Prohibitions: End-of-pipe
CWA, CWA-Equivalent, and Class I Nonhazardous Waste
Injection Well Treatment Standards; Spent Aluminum Potliners;
and Carbamate Wastes
No person shall cause, threaten or allow the land disposal of any waste in violation of
Section 3004 of the Resource Conservation and Recovery Act, incorporated by
reference in 35 Ill. Adm. Code 720.111.
a)
The wastes specified in 35 Ill. Adm. Code 721.132 as USEPA
Hazardous Waste numbers K156-K159 and K161; and in 35 Ill. Adm.
Code 721.133 as USEPA hazardous waste numbers P127, P128, P185,
P188 through P192, P194, P196 through P199, P201 through P205,
U271, U278 through U280, U364, U367, U372, U373, U387, U389,
U394, U395, U404, and U409 through U411 are prohibited from land
disposal. In addition, soil and debris contaminated with these wastes are
prohibited from land disposal.
b)
The wastes identified in 35 Ill. Adm. Code 721.123 as USEPA
hazardous waste number D003 are prohibited from land disposal, other
than those that are managed in a system whose discharge is regulated
under 35 Ill. Adm. Code:Subtitle C, one that injects hazardous waste in
Class I waste injection well regulated under 35 Ill. Adm. Code 702, 704,
and 730, or one that is a zero discharger that engages in federal Clean
Water Act (CWA)-equivalent treatment before ultimate land disposal.
This prohibition does not apply to unexploded ordnance and other
explosive devices that have been the subject of an emergency response.
(Such D003 wastes are prohibited unless they meet the treatment
standard of DEACT before land disposal (see Section 728.140)).
508
c)
The wastes specified in 35 Ill. Adm. Code 721.132 as USEPA hazardous
waste number K088 are prohibited from land disposal. In addition, soil
and debris contaminated with these wastes are prohibited from land
disposal.
d)
Effective April 8, 1998, radioactive wastes mixed with waste designated
by any of USEPA hazardous waste numbers K088, K156 through K159,
K161, P127, P128, P185, P188 through P192, P194, P196 through
P199, P201 through P205, U271, U278 through U280, U364, U367,
U372, U373, U387, U389, U394, U395, U404, and U409 through
U411 are prohibited from land disposal. In addition, soil and debris
contaminated with these radioactive mixed wastes are prohibited from
land disposal.
e)
Until April 8, 1998, the wastes included in subsections (a), (b), (c), and
(d) of this Section may be disposed in a landfill or surface impoundment
only if such unit complies with the requirements of Section
728.105(h)(2).
f)
The requirements of subsections (a), (b), (c), and (d) of this Section do
not apply if:
1)
The wastes meet the applicable treatment standards specified in
Subpart D of this Part;
2)
The person conducting the disposal has been granted an
exemption from a prohibition under a petition pursuant to Section
728.106, with respect to those wastes and units covered by the
petition;
3)
The wastes meet the applicable alternative treatment standards
established pursuant to a petition granted under Section 728.144;
or
4)
The person conducting the disposal has been granted an extension
to the effective date of a prohibition pursuant to Section 728.105,
with respect to those wastes covered by the extension.
g)
To determine whether a hazardous waste identified in this Section
exceeds the applicable treatment standards set forth in Section 728.140,
the initial generator must test a sample of the waste extract or the entire
waste, depending on whether the treatment standards are expressed as
concentrations in the waste extract or in the waste, or the generator may
use knowledge of the waste. If a waste contains constituents in excess of
the applicable 728.Subpart D levels, the waste is prohibited from land
509
disposal and all requirements of this Part are applicable to the waste,
except as otherwise specified.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
SUBPART D: TREATMENT STANDARDS
Section 728.140
Applicability of Treatment Standards
a)
A prohibited waste identified in Section 728.Table T, “Treatment
Standards for Hazardous Wastes”, may be land disposed only if it meets
the requirements found in that Section. For each waste, Section
728.Table T identifies one of three types of treatment standard
requirements:
1)
All hazardous constituents in the waste or in the treatment residue
must be at or below the values found in that Section for that
waste (“total waste standards”);
2)
The hazardous constituents in the extract of the waste or in the
extract of the treatment residue must be at or below the values
found in that Section (“waste extract standards”); or
3)
The waste must be treated using the technology specified in that
Section (“technology standard”), which is described in detail in
Section 728.Table C, “Technology Codes and Description of
Technology-Based Standards”.
b)
For wastewaters, compliance with concentration level standards is based
on maximums for any one day, except for D004 through D011 wastes
for which the previously promulgated treatment standards based on grab
samples remain in effect. For all nonwastewaters, compliance with
concentration level standards is based on grab sampling. For wastes
covered by the waste extract standards, the test Method 1311, the
Toxicity Characteristic Leaching Procedure, found in “Test Methods for
Evaluating Solid Waste, Physical/Chemical Methods”, U.S. EPA
Publication SW-846, incorporated by reference in Section 720.111, must
be used to measure compliance. An exception is made for D004 and
D008, for which either of two test methods may be used: Method 1311
or Method 1310, the Extraction Procedure Toxicity Test, found in “Test
Methods for Evaluating Solid Waste, Physical/Chemical Methods”, U.S.
EPA Publication SW-846, incorporated by reference in Section 720.111.
For wastes covered by a technology standard, the wastes may be land
disposed after being treated using that specified technology or an
510
equivalent treatment technology approved by the Agency pursuant to
Section 728.142(b).
c)
When wastes with differing treatment standards for a constituent of
concern are combined for purposes of treatment, the treatment residue
must meet the lowest treatment standard for the constituent of concern.
d)
Notwithstanding the prohibitions specified in subsection (a) aboveof this
Section, treatment and disposal facilities may demonstrate (and certify
pursuant to 35 Ill. Adm. Code 728.107(b)(5)) compliance with the
treatment standards for organic constituents specified by a footnote in
Section 728.Table T, provided the following conditions are satisfied:
1)
The treatment standards for the organic constituents were
established based on incineration in units operated in accordance
with the technical requirements of 35 Ill. Adm. Code
724.Subpart O, or based on combustion in fuel substitution units
operating in accordance with applicable technical requirements;
2)
The treatment or disposal facility has used the methods
referenced in subsection (d)(1) aboveof this Section to treat the
organic constituents; and
3)
The treatment or disposal facility may demonstrate compliance
with organic constituents if good-faith analytical efforts achieve
detection limits for the regulated organic constituents that do not
exceed the treatment standards specified in this Section and
Section 728.Table T by an order of magnitude.
e)
For characteristic wastes (U.S. EPA hazardous waste numbers D001,
D002, and D012 through D003 and D018 through D043) that are subject
to treatment standards set forth in Section 728.Table T, “Treatment
Standards for Hazardous Wastes”, all underlying hazardous constituents
(as defined in Section 728.102(i)) must meet the universal treatment
standards, foundset forth in Sections 728.148 and 728.Table U prior to
land disposal, as defined in Section 728.102(c).
f)
The treatment standards for U.S. EPA hazardous waste numbers F001
through F005 nonwastewater constituents carbon disulfide,
cyclohexanone, or methanol apply to wastes that contain only one, two,
or three of these constituents. Compliance is measured for these
constituents in the waste extract from test Method 1311, the Toxicity
Characteristic Leaching Procedure found in “Test Methods for
Evaluating Solid Waste, Physical/Chemical Methods”, U.S. EPA
Publication SW-846, incorporated by reference in Section 720.111. If
511
the waste contains any of these three constituents along with any of the
other 25 constituents found in U.S. EPA hazardous waste numbers F001
through F005, then compliance with treatment standards for carbon
disulfide, cyclohexanone, or methanol are not required.
g)
This subsection corresponds with 40 CFR 268.40(g), added at 61 Fed.
Reg. 43927 (Aug. 26, 1996), which has expired. This statement
maintains structural consistency with the federal rules.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 728.144
Adjustment of Treatment Standard
a)
Where the treatment standard is expressed as a concentration in a waste
or waste extract and a waste cannot be treated to the specified level, or
where the treatment technology is not appropriate to the waste, the
generator or treatment facility may petition to the Board for an adjusted
treatment standard. As justification, the petitioner shall demonstrate
that, because the physical or chemical properties of the waste differ
significantly from wastes analyzed in developing the treatment standard,
the waste cannot be treated to specified levels or by the specified
methods.
BOARD NOTE: 40 CFR 268.44 refers to these as “treatability
variances”. The Board has not used this term in its rules to avoid
confusion with the Board variances under Title IX of the Environmental
Protection Act. The equivalent Board procedures are an “adjusted
treatment standard” pursuant to subsections (a) through (l), or a
“treatability exception” adopted pursuant to subsections (m) et seq.
While the latter is adopted by “identical in substance” rulemaking
following a USEPA action, the former is an original Board action which
will be the only mechanism following authorization to the State of this
component of the RCRA program.
b)
Each petition must be submitted in accordance with the procedures in 35
Ill. Adm. Code 106.Subpart G.
c)
Each petition must include the following statement signed by the
petitioner or an authorized representative:
I certify under penalty of law that I have personally examined
and am familiar with the information submitted in this petition
and all attached documents, and that, based on my inquiry of
those individuals immediately responsible for obtaining the
information, I believe that the submitted information is true,
512
accurate and complete. I am aware that there are significant
penalties for submitting false information, including the
possibility of fine and imprisonment.
d)
After receiving a petition for an adjusted treatment standard, the Board
may request any additional information or samples which are necessary
to evaluate the petition.
e)
The Board will give public notice and provide an opportunity for public
comment, as provided in 35 Ill. Adm. Code 106. In conjunction with
any updating of the RCRA regulations, the Board will maintain, in this
Part, a listing of all adjusted treatment standards granted by the Board
pursuant to this Section. A LISTING OF ALL ADJUSTED
STANDARDS GRANTED PURSUANT TO THIS SECTION WILL BE
PUBLISHED IN THE ILLINOIS REGISTER AND
ENVIRONMENTAL REGISTER AT THE END OF EACH FISCAL
YEAR. (Section 28.1(d)(3) of the Environmental Protection Act.)
f)
A generator, treatment facility or disposal facility that is managing a
waste covered by an adjusted treatment standard shall comply with the
waste analysis requirements for restricted wastes found under Section
728.107.
g)
During the petition review process, the applicant is required to comply
with all restrictions on land disposal under this Part once the effective
date for the waste has been reached.
h)
Where the treatment standard is expressed as a concentration in a waste
or waste extract and a waste generated under conditions specific to only
one site cannot be treated to the specified level, or where treatment
technology is not appropriate to the waste, the generator or treatment
facility may petition the Board for a site-specific adjusted treatment
standard. The petitioner shall demonstrate that, because the physical or
chemical properties of the waste differs significantly from the waste
analyzed in developing the treatment standard, the waste cannot be
treated to specified levels or by the specified methods.
i)
Each petition for a site-specific adjusted treatment standard must include
the information in 35 Ill. Adm. Code 720.120(b)(1) through (4).
j)
After receiving a petition for a site-specific adjusted treatment standard,
the Board may request any additional information or samples which the
Board determines are necessary to evaluate the petition.
513
k)
A generator, treatment facility or disposal facility which is managing a
waste covered by a site-specific adjusted treatment standard shall comply
with the waste analysis requirements for restricted wastes in Section
728.107.
l)
During the petition review process, the petitioner for a site-specific
adjusted treatment standard shall comply with all restrictions on land
disposal under this Part once the effective date for the waste has been
reached.
m)
If USEPA grants a treatability exception by regulatory action pursuant to
40 CFR 268.44 (199196) and a person demonstrates that the treatability
exception needs to be adopted as part of the Illinois RCRA program
because the waste is generated or managed in Illinois, the Board will
adopt the treatability exception by identical in substance rulemaking
pursuant to Section 22.4(a) of the Environmental Protection Act.
BOARD NOTE: The Board will adopt the treatability exception during
a RCRA update Docket if a timely demonstration is made. Otherwise,
the Board will assign the matter to a separate Docket.
o)
The facilities listed in Table H are excluded from the treatment standard
under Section 728.143(a) and Table B, and are subject to the constituent
concentrations listed in Table H.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 728.148
Universal Treatment Standards
Section 728.Table U, “Universal Treatment Standards (UTS)”, identifies the hazardous
constituents, along with the nonwastewater and wastewater treatment standard levels,
that are used to regulate most prohibited hazardous wastes with numerical limits. For
determining compliance with treatment standards for underlying hazardous constituents,
as defined in Section 728.102(i), these treatment standards may not be exceeded.
Compliance with these treatment standards is measured by an analysis of grab samples,
unless otherwise noted in Section 728.Table U.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 728.Appendix K Metal Bearing Wastes Prohibited From Dilution in a
Combustion Unit According to Section 728.103(c)
BOARD NOTE: A combustion unit is defined as any thermal technology subject to 35
Ill. Adm. Code 724.Subpart O, 725.Subpart O, or 726.Subpart H.
514
Waste code
Waste description
D004
Toxicity Characteristic for Arsenic.
D005
Toxicity Characteristic for Barium.
D006
Toxicity Characteristic for Cadmium.
D007
Toxicity Characteristic for Chromium.
D008
Toxicity Characteristic for Lead.
D009
Toxicity Characteristic for Mercury.
D010
Toxicity Characteristic for Selenium.
D011
Toxicity Characteristic for Silver.
F006
Wastewater treatment sludges from electroplating operations except from
the following processes: (1) sulfuric acid anodizing of aluminum; (2) tin
plating carbon steel; (3) zinc plating basis on carbon steel; (4) aluminum
or zinc-plating on carbon steel; (5) cleaning/stripping associated with tin,
zinc and aluminum plating on carbon steel; and (6) chemical etching and
milling of aluminum.
F007
Spent cyanide plating bath solutions from electroplating operations.
F008
Plating bath residues from the bottom of plating baths from
electroplating operations where cyanides are used in the process.
F009
Spent stripping and cleaning bath solutions from electroplating
operations where cyanides are used in the process.
F010
Quenching bath residues from oil baths from metal treating operations
where cyanides are used in the process.
F011
Spent cyanide solutions from salt bath pot cleaning from metal heat
treating operations.
F012
Quenching waste water treatment sludges from metal heat treating
operations where cyanides are used in the process.
515
F019
Wastewater treatment sludges from the chemical conversion coating of
aluminum except from zirconium phosphating in aluminum car washing
when such phosphating is an exclusive conversion coating process.
K002
Wastewater treatment sludge from the production of chrome yellow and
orange pigments.
K003
Wastewater treatment sludge from the production of molybdate orange
pigments.
K004
Wastewater treatment sludge from the production of zinc yellow
pigments.
K005
Wastewater treatment sludge from the production of chrome green
pigments.
K006
Wastewater treatment sludge from the production of chrome oxide green
pigments (anhydrous and hydrated).
K007
Wastewater treatment sludge from the production of iron blue pigments.
K008
Oven residue from the production of chrome oxide green pigments.
K061
Emission control dust/sludge from the primary production of steel in
electric furnaces.
K069
Emission control dust/sludge from secondary lead smelting.
K071
Brine purification muds from the mercury cell processes in chlorine
production, where separately prepurified brine is not used.
K100
Waste leaching solution from acid leaching of emission control
dust/sludge from secondary lead smelting.
K106
Sludges from the mercury cell processes for making chlorine.
P010
Arsenic acid H
3
AsO
4
.
P011
Arsenic oxide As
2
O
5
.
P012
Arsenic trioxide.
P013
Barium cyanide.
P015
Beryllium.
516
P029
Copper (I) cyanide Cu(CN).
P074
Nickel (II) cyanide Ni(CN)
2
.
P087
Osmium (VIII) tetroxide OsO
4
.
P099
Potassium silver cyanide KAg(CN)
2
.
P104
Silver cyanide AgCN.
P113
Thallic (III) oxide Tl
2
O
3
.
P114
Thallium (I) selenite Tl
2
SeO
3
.
P115
Thallium (I) sulfate Tl
2
SO
4
.
P119
Ammonium (V) vanadate NH
3
VO
3
.
P120
Vanadium (V) oxide V
2
O
5
.
P121
Zinc cyanide ZnCN.
U032
Calcium chromate CaCrO
4
.
U145
Lead phosphate.
U151
Mercury.
U204
Selenous acid H
2
SeO
3
.
U205
Selenium (IV) disulfide SeS
2
.
U216
Thallium (I) chloride TlCl.
U217
Thallium (I) nitrate TlNO
3
.
(Source: Added at 21 Ill. Reg. ________, effective ____________________)
Section 728.Table C
Technology Codes and Description of Technology-Based
Standards
Technology
code
Description of technology-based standard
517
ADGAS
Venting of compressed gases into an absorbing or reacting media (i.e.,
solid or liquid)--venting can be accomplished through physical release
utilizing valves or piping; physical penetration of the container; or
penetration through detonation.
AMLGM
Amalgamation of liquid, elemental mercury contaminated with
radioactive materials utilizing inorganic reagents such as copper, zinc,
nickel, gold, and sulfur that result in a nonliquid, semi-solid amalgam
and thereby reducing potential emissions of elemental mercury vapors to
the air.
BIODG
Biodegradation of organics or non-metallic inorganics (i.e., degradable
inorganics that contain the elements of phosphorus, nitrogen, and sulfur)
in units operated under either aerobic or anaerobic conditions such that a
surrogate compound or indicator parameter has been substantially
reduced in concentration in the residuals (e.g., total organic carbon
(TOC) can often be used as an indicator parameter for the biodegrada-
tion of many organic constituents that cannot be directly analyzed in
wastewater residues).
CARBN
Carbon adsorption (granulated or powdered) of non-metallic inorganics,
organo-metallics, or organic constituents, operated so that a surrogate
compound or indicator parameter has not undergone breakthrough (e.g.,
total organic carbon (TOC) can often be used as an indicator parameter
for the adsorption of many organic constituents that cannot be directly
analyzed in wastewater residues). Breakthrough occurs when the carbon
has become saturated with the constituent (or indicator parameter) and
substantial change in adsorption rate associated with that constituent
occurs.
CHOXD
Chemical or electrolytic oxidation utilizing the following oxidation
reagents (or waste reagents) or combinations or reagents:
1)
hypochlorite (e.g., bleach);
2)
chlorine;
3)
chlorine dioxide;
4)
ozone or UV (ultraviolet light) assisted ozone;
5)
peroxides;
6)
persulfates;
518
7)
perchlorates;
8)
permanganates; or
9)
other oxidizing reagents of equivalent efficiency, performed in units
operated so that a surrogate compound or indicator parameter has been
substantially reduced in concentration in the residuals (e.g., total organic
carbon (TOC) can often be used as an indicator parameter for the
oxidation of many organic constituents that cannot be directly analyzed
in wastewater residues). Chemical oxidation specifically includes what
is commonly referred to as alkaline chlorination.
CHRED
Chemical reduction utilizing the following reducing reagents (or waste
reagents) or combinations of reagents:
1)
sulfur dioxide;
2)
sodium, potassium, or alkali salts of sulfites, bisulfites, metabisulfites,
and polyethylene glycols (e.g., NaPEG and KPEG);
3)
sodium hydrosulfide;
4)
ferrous salts; or
5)
other reducing reagents of equivalent efficiency, performed in units
operated such that a surrogate compound or indicator parameter has been
substantially reduced in concentration in the residuals (e.g., total organic
halogens (TOX) can often be used as an indicator parameter for the
reduction of many halogenated organic constituents that cannot be
directly analyzed in wastewater residues). Chemical reduction is
commonly used for the reduction of hexavalent chromium to the trivalent
state.
CMBST
Combustion in incinerators, boilers, or industrial furnaces operated in
accordance with the applicable requirements of 35 Ill. Adm. Code
724.Subpart O, 725.Subpart O, or 35 Ill. Adm. Code 726.Subpart H.
DEACT
Deactivation to remove the hazardous characteristics of a waste due to its
ignitability, corrosivity, or reactivity.
FSUBS
Fuel substitution in units operated in accordance with applicable
technical operating requirements.
519
HLVIT
Vitrification of high level mixed radioactive wastes in units in
compliance with all applicable radioactive protection requirements under
control of the federal Nuclear Regulatory Commission.
IMERC
Incineration of wastes containing organics and mercury in units operated
in accordance with the technical operating requirements of 35 Ill. Adm.
Code 724.Subpart O or 725.Subpart O. All wastewater and
nonwastewater residues derived from this process must then comply with
the corresponding treatment standards per waste code with consideration
of any applicable subcategories (e.g., high or low mercury sub-
categories).
INCIN
Incineration in units operated in accordance with the technical
operating requirements of 35 Ill. Adm. Code 724.Subpart O or
725.Subpart O.
LLEXT
Liquid-liquid extraction (often referred to as solvent extraction) of
organics from liquid wastes into an immiscible solvent for which the
hazardous constituents have a greater solvent affinity, resulting in an
extract high in organics that must undergo either incineration, reuse as a
fuel, or other recovery or reuse and a raffinate (extracted liquid waste)
proportionately low in organics that must undergo further treatment as
specified in the standard.
MACRO
Macroencapsulation with surface coating materials such as polymeric
organics (e.g., resins and plastics) or with a jacket of inert inorganic
materials to substantially reduce surface exposure to potential leaching
media. Macroencapsulation specifically does not include any material
that would be classified as a tank or container according to 35 Ill. Adm.
Code 720.110.
NEUTR
Neutralization with the following reagents (or waste reagents) or
combinations of reagents:
1)
acids;
2)
bases; or
3)
water (including wastewaters) resulting in a pH greater than 2 but less
than 12.5 as measured in the aqueous residuals.
NLDBR
No land disposal based on recycling.
PRECP
Chemical precipitation of metals and other inorganics as insoluble
precipitates of oxides, hydroxides, carbonates, sulfides, sulfates,
520
chlorides, fluorides, or phosphates. The following reagents (or waste
reagents) are typically used alone or in combination:
1)
lime (i.e., containing oxides or hydroxides of calcium or magnesium;
2)
caustic (i.e., sodium or potassium hydroxides;
3)
soda ash (i.e., sodium carbonate);
4)
sodium sulfide;
5)
ferric sulfate or ferric chloride;
6)
alum; or
7)
sodium sulfate. Additional flocculating, coagulation, or similar reagents
or processes that enhance sludge dewatering characteristics are not
precluded from use.
RBERY
Thermal recovery of beryllium.
RCGAS
Recovery or reuse of compressed gases including techniques such as
reprocessing of the gases for reuse or resale; filtering or adsorption of
impurities; remixing for direct reuse or resale; and use of the gas as a
fuel source.
RCORR
Recovery of acids or bases utilizing one or more of the following
recovery technologies:
1)
distillation (i.e., thermal concentration);
2)
ion exchange;
3)
resin or solid adsorption;
4)
reverse osmosis; or
5)
incineration for the recovery of acid--
Note: this does not preclude the use of other physical phase separation or
concentration techniques such as decantation, filtration (including
ultrafiltration), and centrifugation, when used in conjunction with the
above listed recovery technologies.
RLEAD
Thermal recovery of lead in secondary lead smelters.
521
RMERC
Retorting or roasting in a thermal processing unit capable of volatilizing
mercury and subsequently condensing the volatilized mercury for
recovery. The retorting or roasting unit (or facility) must be subject to
one or more of the following:
a)
A national emissions standard for hazardous air pollutants (NESHAP)
for mercury (40 CFR 61, Subpart E);
b)
A best available control technology (BACT) or a lowest achievable
emission rate (LAER) standard for mercury imposed pursuant to a
prevention of significant deterioration (PSD) permit (including 35 Ill.
Adm. Code 201 through 203); or
c)
A state permit that establishes emission limitations (within meaning of
Section 302 of the Clean Air Act) for mercury, including a permit issued
pursuant to 35 Ill. Adm. Code 201. All wastewater and nonwastewater
residues derived from this process must then comply with the
corresponding treatment standards per waste code with consideration of
any applicable subcategories (e.g., high or low mercury subcategories).
RMETL
Recovery of metals or inorganics utilizing one or more of the following
direct physical or removal technologies:
1)
ion exchange;
2)
resin or solid (i.e., zeolites) adsorption;
3)
reverse osmosis;
4)
chelation or solvent extraction;
5)
freeze crystallization;
6)
ultrafiltration; or
7)
simple precipitation (i.e., crystallization)
Note: this does not preclude the use of other physical phase separation or
concentration techniques such as decantation, filtration (including
ultrafiltration), and centrifugation, when used in conjunction with the
above listed recovery technologies.
RORGS
Recovery of organics utilizing one or more of the following technolo-
gies:
522
1)
Distillation;
2)
thin film evaporation;
3)
steam stripping;
4)
carbon adsorption;
5)
critical fluid extraction;
6)
liquid-liquid extraction;
7)
precipitation or crystallization (including freeze crystallization); or
8)
chemical phase separation techniques (i.e., addition of acids, bases,
demulsifiers, or similar chemicals).
Note: This does not preclude the use of other physical phase separation
techniques such as decantation, filtration (including ultrafiltration), and
centrifugation, when used in conjunction with the above listed recovery
technologies.
RTHRM
Thermal recovery of metals or inorganics from nonwastewaters in units
defined as cement kilns, blast furnaces, smelting, melting and refining
furnaces, combustion devices used to recover sulfur values from spent
sulfuric acid and “other devices” determined by the Agency pursuant to
35 Ill. Adm. Code 720.110, the definition of “industrial furnace”.
RZINC
Resmelting in high temperature metal recovery units for the purpose of
recovery of zinc.
STABL
Stabilization with the following reagents (or waste reagents) or
combinations of reagents:
1)
Portland cement; or
2)
lime or pozzolans (e.g., fly ash and cement kiln dust)--this does not
preclude the addition of reagents (e.g., iron salts, silicates, and clays)
designed to enhance the set or cure time or compressive strength, or to
overall reduce the leachability of the metal or inorganic.
SSTRP
Steam stripping of organics from liquid wastes utilizing direct
application of steam to the wastes operated such that liquid and vapor
flow rates, as well as, temperature and pressure ranges have been
523
optimized, monitored, and maintained. These operating parameters are
dependent upon the design parameters of the unit such as, the number of
separation stages and the internal column design. Thus, resulting in a
condensed extract high in organics that must undergo either incineration,
reuse as a fuel, or other recovery or reuse and an extracted wastewater
that must undergo further treatment as specified in the standard.
WETOX
Wet air oxidation performed in units operated such that a surrogate
compound or indicator parameter has been substantially reduced in
concentration in the residuals (e.g., total organic carbon (TOC) can often
be used as an indicator parameter for the oxidation of many organic
constituents that cannot be directly analyzed in wastewater residues).
WTRRX
Controlled reaction with water for highly reactive inorganic or organic
chemicals with precautionary controls for protection of workers from
potential violent reactions as well as precautionary controls for potential
emissions of toxic or ignitable levels of gases released during the
reaction.
Note 1:
When a combination of these technologies (i.e., a treatment train) is
specified as a single treatment standard, the order of application is
specified in Section 728.Table T by indicating the five letter technology
code that must be applied first, then the designation “fb.” (an
abbreviation for “followed by”), then the five letter technology code for
the technology that must be applied next, and so on.
Note 2:
When more than one technology (or treatment train) are specified as
alternative treatment standards, the five letter technology codes (or the
treatment trains) are separated by a semicolon (;) with the last
technology preceded by the word “OR”. This indicates that any one of
these BDAT technologies or treatment trains can be used for compliance
with the standard.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 728.Table T
Treatment Standards for Hazardous Wastes
Note: The treatment standards that heretofore appeared in tables in Sections 728.141,
728.142, and 728.143 have been consolidated into this table.
Waste Code
Waste Description and Treatment or Regulatory Subcategory
1
Regulated Hazardous Constituent
Wastewaters
Nonwastewaters
524
Common Name
CAS
2
Number
Concentration in
mg/l
3
; or Tech-
nology Code
4
Concentration in
mg/kg
35
unless
noted as “mg/l
TCLP”; or
Technology
Code
4
D001
9
Ignitable Characteristic Wastes, except for the Section 35 Ill. Adm. Code 721.121(a)(1)
High TOC Subcategory, that are managed in non-CWA or non-CWA-equivalent or
non-Class I SDWA systems.
NA
NA
DEACT and
meet Section
728.148
standards;
8
or
RORGS; or
CMBST
DEACT and
meet Section
728.148
standards;
8
or
RORGS; or
CMBST
D001
Ignitable Characteristic Wastes, except for the Section 721.121(a)(1) High TOC
Subcategory, that are managed in CWA or CWA-equivalent or Class I SDWA systems
NA
NA
DEACT
DEACT
D001
9
High TOC Ignitable Characteristic Liquids Subcategory based on 35 Ill. Adm. Code
721.121(a)(1) - Greater than or equal to 10% total organic carbon.
(Note: This subcategory consists of nonwastewaters only.)
NA
NA
NA
RORGS; or
CMBST
D002
9
Corrosive Characteristic Wastes that are managed in non-CWA or non-CWA equivalent
or non-Class I SDWA systems.
NA
NA
DEACT and
meet Section
728.148
standards
8
DEACT and
meet Section
728.148
standards
8
D002
Corrosive Characteristic Wastes that are managed in CWA, CWA equivalent, or Class
I SDWA systems.
NA
NA
DEACT
DEACT
D002, D004, D005, D006, D007, D008, D009, D010, D011
Radioactive high level wastes generated during the reprocessing of fuel rods.
525
(Note: This subcategory consists of nonwastewaters only.)
Corrosivity (pH)
NA
NA
HLVIT
Arsenic
7440-38-2
NA
HLVIT
Barium
7440-39-3
NA
HLVIT
Cadmium
7440-43-9
NA
HLVIT
Chromium (Total)
7440-47-3
NA
HLVIT
Lead
7439-92-1
NA
HLVIT
Mercury
7439-97-6
NA
HLVIT
Selenium
7782-49-2
NA
HLVIT
Silver
7440-22-4
NA
HLVIT
D003
9
Reactive Sulfides Subcategory based on 35 Ill. Adm. Code 721.123(a)(5).
NA
NA
DEACT
DEACT
D003
9
Explosive subcategory based on 35 Ill. Adm. Code 721.123(a)(6), (a)(7), and (a)(8).
NA
NA
DEACT and
meet Section
728.148
standards
8
DEACT and
meet Section
728.148
standards
8
D003
9
Unexploded ordnance and other explosive devices that have been the subject of an
emergency response.
NA
NA
DEACT
DEACT
D003
9
Other Reactives Subcategory based on 35 Ill. Adm. Code 721.123(a)(1).
NA
NA
DEACT and
meet Section
728.148
standards
8
DEACT and
meet Section
728.148
standards
8
D003
9
Water Reactive Subcategory based on 35 Ill. Adm. Code 721.123(a)(2), (a)(3), and
(a)(4).
(Note: This subcategory consists of nonwastewaters only.)
NA
NA
NA
DEACT and
meet Section
728.148
standards
8
D003
9
Reactive Cyanides Subcategory based on 35 Ill. Adm. Code 721.123(a)(5).
526
Cyanides (Total)
7
57-12-5
--
590
Cyanides (Amenable)
7
57-12-5
0.86
30
D004
Wastes that exhibit, or are expected to exhibit, the characteristic of toxicity for arsenic
based on the extraction procedure (EP) in SW-846 Method 1310.
Arsenic
7440-38-2
5.0
5.0 mg/l EP
Arsenic; alternative
6
standard
for nonwastewaters only.
7440-38-2
NA
5.0 mg/l TCLP
D005
Wastes that exhibit, or are expected to exhibit, the characteristic of toxicity for barium
based on the extraction procedure (EP) in SW-846 Method 1310.
Barium
7440-39-3
100
100 mg/l TCLP
D006
Wastes that exhibit, or are expected to exhibit, the characteristic of toxicity for
cadmium based on the extraction procedure (EP) in SW-846 Method 1310.
Cadmium
7440-43-9
1.0
1.0 mg/l TCLP
D006
Cadmium -Containing Batteries Subcategory
(Note: This subcategory consists of nonwastewaters only.)
Cadmium
7440-43-9
NA
RTHRM
D007
Wastes that exhibit, or are expected to exhibit, the characteristic of toxicity for
chromium based on the extraction procedure (EP) in SW-846 Method 1310.
Chromium (Total)
7440-47-3
5.0
5.0 mg/l TCLP
D008
Wastes that exhibit, or are expected to exhibit, the characteristic of toxicity for lead
based on the extraction procedure (EP) in SW-846 Method 1310.
Lead
7439-92-1
5.0
5.0 mg/l EP
Lead; alternative
6
standard
for nonwastewaters only
7439-92-1
NA
5.0 mg/l TCLP
D008
Lead Acid Batteries Subcategory
(Note: This standard only applies to lead acid batteries that are identified as RCRA
hazardous wastes and that are not excluded elsewhere from regulation under the land
disposal restrictions of this Part or exempted under other regulations (see 35 Ill. Adm.
Code 726.180). This subcategory consists of nonwastewaters only.)
(Note: This subcategory consists of nonwastewaters only.)
Lead
7439-92-1
NA
RLEAD
527
D008
Radioactive Lead Solids Subcategory
(Note: These lead solids include, but are not limited to, all forms of lead shielding and
other elemental forms of lead. These lead solids do not include treatment residuals
such as hydroxide sludges, other wastewater treatment residuals, or incinerator ashes
that can undergo conventional pozzolanic stabilization, nor do they include organo-lead
materials that can be incinerated and stabilized as ash. This subcategory consists of
nonwastewaters only.)
(Note: This subcategory consists of nonwastewaters only.)
Lead
7439-92-1
NA
MACRO
D009
Nonwastewaters that exhibit, or are expected to exhibit, the characteristic of toxicity
for mercury based on the extraction procedure (EP) in SW-846 Method 1310; and
contain greater than or equal to 260 mg/kg total mercury that also contain organics and
are not incinerator residues. (High Mercury-Organic Subcategory)
(High Mercury-Organic Subcategory)
Mercury
7439-97-6
NA
IMERC; or
RMERC
D009
Nonwastewaters that exhibit, or are expected to exhibit, the characteristic of toxicity
for mercury based on the extraction procedure (EP) in SW-846 Method 1310; and
contain greater than or equal to 260 mg/kg total mercury that are inorganic, including
incinerator residues and residues from RMERC. (High Mercury-Inorganic
Subcategory)
(High Mercury-Inorganic Subcategory)
Mercury
7439-97-6
NA
RMERC
D009
Nonwastewaters that exhibit, or are expected to exhibit, the characteristic of toxicity
for mercury based on the extraction procedure (EP) in SW-846 Method 1310; and
contain less than 260 mg/kg total mercury. (Low Mercury Subcategory)
(Low Mercury Subcategory)
Mercury
7439-97-6
NA
0.20 mg/l TCLP
All D009 wastewaters.
Mercury
7439-97-6
0.20
NA
D009
Elemental mercury contaminated with radioactive materials.
(Note: This subcategory consists of nonwastewaters only.)
Mercury
7439-97-6
NA
AMLGM
528
D009
Hydraulic oil contaminated with Mercury Radioactive Materials Subcategory.
(Note: This subcategory consists of nonwastewaters only.)
Mercury
7439-97-6
NA
IMERC
D010
Wastes that exhibit, or are expected to exhibit, the characteristic orof toxicity for
selenium based on the extraction procedure (EP) in SW-846 Method 1310.
Selenium
7782-49-2
1.0
5.7 mg/l TCLP
D011
Wastes that exhibit, or are expected to exhibit, the characteristic of toxicity for silver
based on the extraction procedure (EP) in SW-846 Method 1310.
Silver
7440-22-4
5.0
5.0 mg/l TCLP
D012
9
Wastes that are TC for Endrin based on the TCLP in SW-846 Method 1311.
Endrin
72-20-8
BIODG; or
INCINCMBST
0.13 and meet
Section 728.148
standards
8
Endrin aldehyde
7421-93-4
BIODG; or
INCINCMBST
0.13 and meet
Section 728.148
standards
8
D013
9
Wastes that are TC for Lindane based on the TCLP in SW-846 Method 1311.
alpha-BHC
319-84-6
CARBN; or
INCINCMBST
0.066 and meet
Section 728.148
standards
8
beta-BHC
319-85-7
CARBN; or
INCINCMBST
0.066 and meet
Section 728.148
standards
8
delta-BHC
319-86-8
CARBN; or
INCINCMBST
0.066 and meet
Section 728.148
standards
8
gamma-BHC (Lindane)
58-89-9
CARBN; or
INCINCMBST
0.066 and meet
Section 728.148
standards
8
D014
9
Wastes that are TC for Methoxychlor based on the TCLP in SW-846 Method 1311.
Methoxychlor
72-43-5
WETOX or
INCINCMBST
0.18 and meet
Section 728.148
standards
8
529
D015
9
Wastes that are TC for Toxaphene based on the TCLP in SW-846 Method 1311.
Toxaphene
8001-35-2
BIODG or
INCINCMBST
2.6 and meet
Section 728.148
standards
8
D016
9
Wastes that are TC for 2,4-D (2,4-Dichlorophenoxyacetic acid) based on the TCLP in
SW-846 Method 1311.
2,4-D (2,4-Dichloro-
phenoxyacetic acid)
94-75-7
CHOXD,;
BIODG,; or
INCINCMBST
10 and meet
Section 728.148
standards
8
D017
9
Wastes that are TC for 2,4,5-TP (Silvex) based on the TCLP in SW-846 Method 1311.
2,4,5-TP (Silvex)
93-72-1
CHOXD or
INCINCMBST
7.9 and meet
Section 728.148
standards
8
D018
9
Wastes that are TC for Benzene based on the TCLP in SW-846 Method 1311 and that
are managed in non-CWA or non-CWA equivalent or non-Class I SDWA systems only.
Benzene
71-43-2
0.14 and meet
Section 728.148
standards
8
10 and meet
Section 728.148
standards
8
D019
9
Wastes that are TC for Carbon tetrachloride based on the TCLP in SW-846 Method
1311 and that are managed in non-CWA or non-CWA equivalent or non-Class I SDWA
systems only.
Carbon tetrachloride
56-23-5
0.057 and meet
Section 728.148
standards
8
6.0 and meet
Section 728.148
standards
8
D020
9
Wastes that are TC for Chlordane based on the TCLP in SW-846 Method 1311 and that
are managed in non-CWA or non-CWA equivalent or non-Class I SDWA systems only.
Chlordane (alpha and gamma
isomers)
57-74-9
0.0033 and meet
Section 728.148
standards
8
0.26 and meet
Section 728.148
standards
8
D021
9
Wastes that are TC for Chlorobenzene based on the TCLP in SW-846 Method 1311
and that are managed in non-CWA or non-CWA equivalent or non-Class I SDWA
systems only.
530
Chlorobenzene
108-90-7
0.057 and meet
Section 728.148
standards
8
6.0 and meet
Section 728.148
standards
8
D022
9
Wastes that are TC for Chloroform based on the TCLP in SW-846 Method 1311 and
that are managed in non-CWA or non-CWA equivalent or non-Class I SDWA systems
only.
Chloroform
67-66-3
0.046 and meet
Section 728.148
standards
8
6.0 and meet
Section 728.148
standards
8
D023
9
Wastes that are TC for o-Cresol based on the TCLP in SW-846 Method 1311 and that
are managed in non-CWA or non-CWA equivalent or non-Class I SDWA systems only.
o-Cresol`
95-48-7
0.11 and meet
Section 728.148
standards
8
5.6 and meet
Section 728.148
standards
8
D024
9
Wastes that are TC for m-Cresol based on the TCLP in SW-846 Method 1311 and that
are managed in non-CWA or non-CWA equivalent or non-Class I SDWA systems only.
m-Cresol
(difficult to distinguish from
p-cresol)
108-39-4
0.77 and meet
Section 728.148
standards
8
5.6 and meet
Section 728.148
standards
8
D025
9
Wastes that are TC for p-Cresol based on the TCLP in SW-846 Method 1311 and that
are managed in non-CWA or non-CWA equivalent or non-Class I SDWA systems only.
p-Cresol
(difficult to distinguish from
m-cresol)
106-44-5
0.77 and meet
Section 728.148
standards
8
5.6 and meet
Section 728.148
standards
8
D026
9
Wastes that are TC for Cresols (Total) based on the TCLP in SW-846 Method 1311
and that are managed in non-CWA or non-CWA equivalent or non-Class I SDWA
systems only.
Cresol-mixed isomers
(Cresylic acid)
(sum of o-, m-, and p-cresol
concentrations)
1319-77-3
0.88 and meet
Section 728.148
standards
8
11.2 and meet
Section 728.148
standards
8
D027
9
531
Wastes that are TC for p-Dichlorobenzene based on the TCLP in SW-846 Method 1311
and that are managed in non-CWA or non-CWA equivalent or non-Class I SDWA
systems only.
p-Dichlorobenzene (1,4-
Dichlorobenzene)
106-46-7
0.090 and meet
Section 728.148
standards
8
6.0 and meet
Section 728.148
standards
8
D028
9
Wastes that are TC for 1,2-Dichloroethane based on the TCLP in SW-846 Method
1311 and that are managed in non-CWA or non-CWA equivalent or non-Class I SDWA
systems only.
1,2-Dichloroethane
107-06-2
0.21 and meet
Section 728.148
standards
8
6.0 and meet
Section 728.148
standards
8
D029
9
Wastes that are TC for 1,1-Dichloroethylene based on the TCLP in SW-846 Method
1311 and that are managed in non-CWA or non-CWA equivalent or non-Class I SDWA
systems only.
1,1-Dichloroethylene
75-35-4
0.025 and meet
Section 728.148
standards
8
6.0 and meet
Section 728.148
standards
8
D030
9
Wastes that are TC for 2,4-Dinitrotoluene based on the TCLP in SW-846 Method 1311
and that are managed in non-CWA or non-CWA equivalent or non-Class I SDWA
systems only.
2,4-Dinitrotoluene
121-14-2
0.32 and meet
Section 728.148
standards
8
140 and meet
Section 728.148
standards
8
D031
9
Wastes that are TC for Heptachlor based on the TCLP in SW-846 Method 1311 and
that are managed in non-CWA or non-CWA equivalent or non-Class I SDWA systems
only.
Heptachlor
76-44-8
0.0012 and meet
Section 728.148
standards
8
0.066 and meet
Section 728.148
standards
8
Heptachlor epoxide
1024-57-3
0.016 and meet
Section 728.148
standards
8
0.066 and meet
Section 728.148
standards
8
D032
9
532
Wastes that are TC for Hexachlorobenzene based on the TCLP in SW-846 Method
1311 and that are managed in non-CWA or non-CWA equivalent or non-Class I SDWA
systems only.
Hexachlorobenzene
118-74-1
0.055 and meet
Section 728.148
standards
8
10 and meet
Section 728.148
standards
8
D033
9
Wastes that are TC for Hexachlorobutadiene based on the TCLP in SW-846 Method
1311 and that are managed in non-CWA or non-CWA equivalent or non-Class I SDWA
systems only.
Hexachlorobutadiene
87-68-3
0.055 and meet
Section 728.148
standards
8
5.6 and meet
Section 728.148
standards
8
D034
9
Wastes that are TC for Hexachloroethane based on the TCLP in SW-846 Method 1311
and that are managed in non-CWA or non-CWA equivalent or non-Class I SDWA
systems only.
Hexachloroethane
67-72-1
0.055 and meet
Section 728.148
standards
8
30 and meet
Section 728.148
standards
8
D035
9
Wastes that are TC for Methyl ethyl ketone based on the TCLP in SW-846 Method
1311 and that are managed in non-CWA or non-CWA equivalent or non-Class I SDWA
systems only.
Methyl ethyl ketone
78-93-3
0.28 and meet
Section 728.148
standards
8
36 and meet
Section 728.148
standards
8
D036
9
Wastes that are TC for Nitrobenzene based on the TCLP in SW-846 Method 1311 and
that are managed in non-CWA or non-CWA equivalent or non-Class I SDWA systems
only.
Nitrobenzene
98-95-3
0.068 and meet
Section 728.148
standards
8
14 and meet
Section 728.148
standards
8
D037
9
Wastes that are TC for Pentachlorophenol based on the TCLP in SW-846 Method 1311
and that are managed in non-CWA or non-CWA equivalent or non-Class I SDWA
systems only.
Pentachlorophenol
87-86-5
0.089 and meet
Section 728.148
7.4 and meet
Section 728.148
533
standards
8
standards
8
D038
9
Wastes that are TC for Pyridine based on the TCLP in SW-846 Method 1311 and that
are managed in non-CWA or non-CWA equivalent or non-Class I SDWA systems only.
Pyridine
110-86-1
0.014 and meet
Section 728.148
standards
8
16 and meet
Section 728.148
standards
8
D039
9
Wastes that are TC for Tetrachloroethylene based on the TCLP in SW-846 Method
1311 and that are managed in non-CWA or non-CWA equivalent or non-Class I SDWA
systems only.
Tetrachloroethylene
127-18-4
0.056 and meet
Section 728.148
standards
8
6.0 and meet
Section 728.148
standards
8
D040
9
Wastes that are TC for Trichloroethylene based on the TCLP in SW-846 Method 1311
and that are managed in non-CWA or non-CWA equivalent or non-Class I SDWA
systems only.
Trichloroethylene
79-01-6
0.054 and meet
Section 728.148
standards
8
6.0 and meet
Section 728.148
standards
8
D041
9
Wastes that are TC for 2,4,5-Trichlorophenol based on the TCLP in SW-846 Method
1311 and that are managed in non-CWA or non-CWA equivalent or non-Class I SDWA
systems only.
2,4,5-Trichlorophenol
95-95-4
0.18 and meet
Section 728.148
standards
8
7.4 and meet
Section 728.148
standards
8
D042
9
Wastes that are TC for 2,4,6-Trichlorophenol based on the TCLP in SW-846 Method
1311 and that are managed in non-CWA or non-CWA equivalent or non-Class I SDWA
systems only.
2,4,6-Trichlorophenol
88-06-2
0.035 and meet
Section 728.148
standards
8
7.4 and meet
Section 728.148
standards
8
D043
9
Wastes that are TC for Vinyl chloride based on the TCLP in SW-846 Method 1311 and
that are managed in non-CWA or non-CWA equivalent or non-Class I SDWA systems
only.
534
Vinyl chloride
75-01-4
0.27 and meet
Section 728.148
standards
8
6.0 and meet
Section 728.148
standards
8
F001, F002, F003, F004 & F005
F001, F002, F003, F004, or F005 solvent wastes that contain any combination of one
or more of the following spent solvents: acetone, benzene, n-butyl alcohol, carbon
disulfide, carbon tetrachloride, chlorinated fluorocarbons, chlorobenzene, o-cresol, m-
cresol, p-cresol, cyclohexanone, o-dichlorobenzene, 2-ethoxyethanol, ethyl acetate,
ethyl benzene, ethyl ether, isobutyl alcohol, methanol, methylene chloride, methyl
ethyl ketone, methyl isobutyl ketone, nitrobenzene, 2-nitropropane, pyridine, tetra-
chloroethylene, toluene, 1,1,1-trichloroethane, 1,1,2-trichloroethane, 1,1,2-trichloro-
1,2,2-trifluoroethane, trichloroethylene, trichloromonofluoromethane, or xylenes
(except as specifically noted in other subcategories). See further details of these
listings in 35 Ill. Adm. Code 721.131
Acetone
67-64-1
0.28
160
Benzene
71-43-2
0.14
10
n-Butyl alcohol
71-36-3
5.6
2.6
Carbon disulfide
75-15-0
3.8
NA
Carbon tetrachloride
56-23-5
0.057
6.0
Chlorobenzene
108-90-7
0.057
6.0
o-Cresol
95-48-7
0.11
5.6
m-Cresol
(difficult to distinguish from
p-cresol)
108-39-4
0.77
5.6
p-Cresol
(difficult to distinguish from
m-cresol)
106-44-5
0.77
5.6
Cresol-mixed isomers
(Cresylic acid)
(sum of o-, m-, and p-cresol
concentrations)
1319-77-3
0.88
11.2
Cyclohexanone
108-94-1
0.36
NA
o-Dichlorobenzene
95-50-1
0.088
6.0
Ethyl acetate
141-78-6
0.34
33
Ethyl benzene
100-41-4
0.057
10
Ethyl ether
60-29-7
0.12
160
Isobutyl alcohol
78-83-1
5.6
170
Methanol
67-56-1
5.6
NA
Methylene chloride
75-9-2
0.089
30
Methyl ethyl ketone
78-93-3
0.28
36
Methyl isobutyl ketone
108-10-1
0.14
33
Nitrobenzene
98-95-3
0.068
14
Pyridine
110-86-1
0.014
16
Tetrachloroethylene
127-18-4
0.056
6.0
535
Toluene
108-88-3
0.080
10
1,1,1-Trichloroethane
71-55-6
0.054
6.0
1,1,2-Trichloroethane
79-00-5
0.054
6.0
1,1,2-Trichloro-1,2,2-
trifluoroethane
76-13-1
0.057
30
Trichloroethylene
79-01-6
0.054
6.0
Trichloromonofluoromethane
75-69-4
0.020
30
Xylenes-mixed isomers
(sum of o-, m-, and p-xylene
concentrations)
1330-20-7
0.32
30
F001, F002, F003, F004 & F005
F003 and F005 solvent wastes that contain any combination of one or more of the
following three solvents as the only listed F001 through F005 solvents: carbon
disulfide, cyclohexanone, or methanol. (Formerly Section 728.141(c))
Carbon disulfide
75-15-0
3.8
4.8 mg/l TCLP
Cyclohexanone
108-94-1
0.36
0.75 mg/l TCLP
Methanol
67-56-1
5.6
0.75 mg/l TCLP
F001, F002, F003, F004 & F005
F005 solvent waste containing 2-Nitropropane as the only listed F001 through F005
solvent.
2-Nitropropane
79-46-9
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
F001, F002, F003, F004 & F005
F005 solvent waste containing 2-Ethoxyethanol as the only listed F001 through F005
solvent.
2-Ethoxyethanol
110-80-5
BIODG; or
INCINCMBST
INCINCMBST
F006
Wastewater treatment sludges from electroplating operations except from the following
processes: (1) Sulfuric acid anodizing of aluminum; (2) tin plating on carbon steel; (3)
zinc plating (segregated basis) on carbon steel; (4) aluminum or zinc-aluminum plating
on carbon steel; (5) cleaning or stripping associated with tin, zinc, and aluminum
plating on carbon steel; and (6) chemical etching and milling of aluminum.
Cadmium
7440-43-9
0.69
0.19 mg/l TCLP
Chromium (Total)
7440-47-3
2.77
0.86 mg/l TCLP
Cyanides (Total)
7
57-12-5
1.2
590
Cyanides (Amenable)
7
57-12-5
0.86
30
Lead
7439-92-1
0.69
0.37 mg/l TCLP
Nickel
7440-02-0
3.98
5.0 mg/l TCLP
536
Silver
7440-22-4
NA
0.30 mg/l TCLP
F007
Spent cyanide plating bath solutions from electroplating operations.
Cadmium
7440-43-9
NA
0.19 mg/l TCLP
Chromium (Total)
7440-47-3
2.77
0.86 mg/l TCLP
Cyanides (Total)
7
57-12-5
1.2
590
Cyanides (Amenable)
7
57-12-5
0.86
30
Lead
7439-92-1
0.69
0.37 mg/l TCLP
Nickel
7440-02-0
3.98
5.0 mg/l TCLP
Silver
7440-22-4
NA
0.30 mg/l TCLP
F008
Plating bath residues from the bottom of plating baths from electroplating operations
where cyanides are used in the process.
Cadmium
7440-43-9
NA
0.19 mg/l TCLP
Chromium (Total)
7440-47-3
2.77
0.86 mg/l TCLP
Cyanides (Total)
7
57-12-5
1.2
590
Cyanides (Amenable)
7
57-12-5
0.86
30
Lead
7439-92-1
0.69
0.37 mg/l TCLP
Nickel
7440-02-0
3.98
5.0 mg/l TCLP
Silver
7440-22-4
NA
0.30 mg/l TCLP
F009
Spent stripping and cleaning bath solutions from electroplating operations where
cyanides are used in the process.
Cadmium
7440-43-9
NA
0.19 mg/l TCLP
Chromium (Total)
7440-47-3
2.77
0.86 mg/l TCLP
Cyanides (Total)
7
57-12-5
1.2
590
Cyanides (Amenable)
7
57-12-5
0.86
30
Lead
7439-92-1
0.69
0.37 mg/l TCLP
Nickel
7440-02-0
3.98
5.0 mg/l TCLP
Silver
7440-22-4
NA
0.30 mg/l TCLP
F010
Quenching bath residues from oil baths from metal heat treating operations where
cyanides are used in the process.
Cyanides (Total)
7
57-12-5
1.2
590
Cyanides (Amenable)
7
57-12-5
0.880.86
NA
F011
Spent cyanide solutions from salt bath pot cleaning from metal heat treating operations.
Cadmium
7440-43-9
NA
0.19 mg/l TCLP
Chromium (Total)
7440-47-3
2.77
0.86 mg/l TCLP
Cyanides (Total)
7
57-12-5
1.2
590
537
Cyanides (Amenable)
7
57-12-5
0.86
30
Lead
7439-92-1
0.69
0.37 mg/l TCLP
Nickel
7440-02-0
3.98
5.0 mg/l TCLP
Silver
7440-22-4
NA
0.30 mg/l TCLP
F012
Quenching wastewater treatment sludges from metal heat treating operations where
cyanides are used in the process.
Cadmium
7440-43-9
NA
0.19 mg/l TCLP
Chromium (Total)
7440-47-3
2.77
0.86 mg/l TCLP
Cyanides (Total)
7
57-12-5
1.2
590
Cyanides (Amenable)
7
57-12-5
0.86
30
Lead
7439-92-1
0.69
0.37 mg/l TCLP
Nickel
7440-02-0
3.98
5.0 mg/l TCLP
Silver
7440-22-4
NA
0.30 mg/l TCLP
F019
Wastewater treatment sludges from the chemical conversion coating of aluminum
except from zirconium phosphating in aluminum can washing when such phosphating is
an exclusive conversion coating process.
Chromium (Total)
7440-47-3
2.77
0.86 mg/l TCLP
Cyanides (Total)
7
57-12-5
1.2
590
Cyanides (Amenable)
7
57-12-5
0.86
30
F020, F021, F022, F023, F026
Wastes (except wastewater and spent carbon from hydrogen chloride purification) from
the production or manufacturing use (as a reactant, chemical intermediate, or
component in a formulating process) of: (1) tri- or tetrachlorophenol, or of
intermediates used to produce their pesticide derivatives, excluding wastes from the
production of Hexachlorophene from highly purified 2,4,5-trichlorophenol (i.e., F020);
(2) pentachlorophenol, or of intermediates used to produce its derivatives (i.e., F021);
(3) tetra-, penta-, or hexachlorobenzenes under alkaline conditions (i.e., F022).
and Wwastes (except wastewater and spent carbon from hydrogen chloride
purification) from the production of materials on equipment previously used for the
production or manufacturing use (as a reactant, chemical intermediate, or component in
a formulating process) of: (1) tri- or tetrachlorophenols, excluding wastes from
equipment used only for the production of Hexachlorophene from highly purified
2,4,5-trichlorophenol (F023); or (2) tetra-, penta-, or hexachlorobenzenes under
alkaline conditions (i.e., F026).
HxCDDs (All Hexachloro-
dibenzo-p-dioxins)
NA
0.000063
0.001
HxCDFs (All Hexachloro-
dibenzofurans)
NA
0.000063
0.001
PeCDDs (All Pentachloro-
dibenzo-p-dioxins)
NA
0.000063
0.001
538
PeCDFs (All Pentachloro-
dibenzofurans)
NA
0.000035
0.001
Pentachlorophenol
87-86-5
0.089
7.4
TCDDs (All Tetrachloro-
dibenzo-p-dioxins)
NA
0.000063
0.001
TCDFs (All Tetrachloro-
dibenzofurans)
NA
0.000063
0.001
2,4,5-Trichlorophenol
95-95-4
0.18
7.4
2,4,6-Trichlorophenol
88-06-2
0.035
7.4
2,3,4,6-Tetrachlorophenol
58-90-2
0.030
7.4
Pentachlorophenol
87-86-5
0.089
7.4
F024
Process wastes, including but not limited to, distillation residues, heavy ends, tars, and
reactor clean-out wastes, from the production of certain chlorinated aliphatic
hydrocarbons by free radical catalyzed processes. These chlorinated aliphatic
hydrocarbons are those having carbon chain lengths ranging from one to and including
five, with varying amounts and positions of chlorine substitution. (This listing does not
include wastewaters, wastewater treatment sludges, spent catalysts, and wastes listed in
35 Ill. Adm. Code 721.131 or 721.132.)
All F024 wastes
NA
CMBST
CMBST
2-Chloro-1,3-butadiene
126-99-8
0.057
0.28
3-Chloropropylene
107-05-1
0.036
30
1,1-Dichloroethane
75-34-3
0.059
6.0
1,2-Dichloroethane
107-06-2
0.21
6.0
1,2-Dichloropropane
78-87-5
0.85
18
cis-1,3-Dichloropropylene
10061-01-5
0.036
18
trans-1,3-Dichloropropylene
10061-02-6
0.036
18
bis(2-Ethylhexyl)phthalate
117-81-7
0.28
28
Hexachloroethane
67-72-1
0.055
30
Chromium (Total)
7440-47-3
2.77
0.86 mg/l TCLP
Nickel
7440-02-0
3.98
5.0 mg/l TCLP
F025
Condensed light ends from the production of certain chlorinated aliphatic hydrocarbons
by free radical catalyzed processes. These chlorinated aliphatic hydrocarbons are those
having carbon chain lengths ranging from one up to and including five, with varying
amounts and positions of chlorine substitution. F025--Light Ends Subcategory.
Carbon tetrachloride
56-23-5
0.057
6.0
Chloroform
67-66-3
0.046
6.0
1,2-Dichloroethane
107-06-2
0.21
6.0
1,1-Dichloroethylene
75-35-4
0.025
6.0
Methylene chloride
75-9-2
0.089
30
1,1,2-Trichloroethane
79-00-5
0.054
6.0
539
Trichloroethylene
79-01-6
0.054
6.0
Vinyl chloride
75-01-4
0.27
6.0
F025
Spent filters and filter aids, and spent desiccant wastes from the production of certain
chlorinated aliphatic hydrocarbons by free radical catalyzed processes. These
chlorinated aliphatic hydrocarbons are those having carbon chain lengths ranging from
one to and including five, with varying amounts and positions of chlorine substitution.
F025--Spent Filters/Aids and Desiccants Subcategory.
Carbon tetrachloride
56-23-5
0.057
6.0
Chloroform
67-66-3
0.046
6.0
Hexachlorobenzene
118-74-1
0.055
10
Hexachlorobutadiene
87-68-3
0.055
5.6
Hexachloroethane
67-72-1
0.055
30
Methylene chloride
75-9-2
0.089
30
1,1,2-Trichloroethane
79-00-5
0.054
6.0
Trichloroethylene
79-01-6
0.054
6.0
Vinyl chloride
75-01-4
0.27
6.0
F027
Discarded unused formulations contianing tri-, tetra-, or pentachlorophenol or
discarded unused formulations containing compounds derived from these chloro-
phenols. (This listing does not include formulations containing hexachlorophene
synthesized from prepurified 2,4,5-trichlorophenol as the sole component.)
HxCDDs (All Hexachloro-
dibenzo-p-dioxins)
NA
0.000063
0.001
HxCDFs (All Hexachloro-
dibenzofurans)
NA
0.000063
0.001
PeCDDs (All Pentachloro-
dibenzo-p-dioxins)
NA
0.000063
0.001
PeCDFs (All Pentachloro-
dibenzofurans)
NA
0.000035
0.001
Pentachlorophenol
87-86-5
0.089
7.4
TCDDs (All Tetrachloro-
dibenzo-p-dioxins)
NA
0.000063
0.001
TCDFs (All Tetrachloro-
dibenzofurans)
NA
0.000063
0.001
2,4,5-Trichlorophenol
95-95-4
0.18
7.4
2,4,6-Trichlorophenol
88-06-2
0.035
7.4
2,3,4,6-Tetrachlorophenol
58-90-2
0.030
7.4
Pentachlorophenol
87-86-5
0.089
7.4
F028
Residues resulting from the incineration or thermal treatment of soil contaminated with
USEPA hazardous waste numbers F020, F021, F023, F026, and F027.
540
HxCDDs (All Hexachloro-
dibenzo-p-dioxins)
NA
0.000063
0.001
HxCDFs (All Hexachloro-
dibenzofurans)
NA
0.000063
0.001
PeCDDs (All Pentachloro-
dibenzo-p-dioxins)
NA
0.000063
0.001
PeCDFs (All Pentachloro-
dibenzofurans)
NA
0.000035
0.001
Pentachlorophenol
87-86-5
0.089
7.4
TCDDs (All Tetrachloro-
dibenzo-p-dioxins)
NA
0.000063
0.001
TCDFs (All Tetrachloro-
dibenzofurans)
NA
0.000063
0.001
2,4,5-Trichlorophenol
95-95-4
0.18
7.4
2,4,6-Trichlorophenol
88-06-2
0.035
7.4
2,3,4,6-Tetrachlorophenol
58-90-2
0.030
7.4
Pentachlorophenol
87-86-5
0.089
7.4
F024
Process wastes, including but not limited to, distillation residues, heavy ends, tars, and
reactor clean-out wastes, from the production of certain chlorinated aliphatic hydro-
carbons by free radical catalyzed processes. These chlorinated aliphatic hydrocarbons
are those having carbon chain lengths ranging from one to and including five, with
varying amounts and positions of chlorine substitution. (This listing does not include
wastewaters, wastewater treatment sludges, spent catalysts, and wastes listed in 35 Ill.
Adm. Code 721.131 or 721.132.)
All F024 wastes
NA
INCIN
INCIN
2-Chloro-1,3-butadiene
126-99-8
0.057
0.28
3-Chloropropylene
107-05-1
0.036
30
1,1-Dichloroethane
75-34-3
0.059
6.0
1,2-Dichloroethane
107-06-2
0.21
6.0
1,2-Dichloropropane
78-87-5
0.85
18
cis-1,3-Dichloropropylene
10061-01-5
0.036
18
trans-1,3-Dichloropropylene
10061-02-6
0.036
18
bis(2-Ethylhexyl) phthalate
117-81-7
0.28
28
Hexachloroethane
67-72-1
0.055
30
Chromium (Total)
7440-47-3
2.77
0.86 mg/l TCLP
Nickel
7440-02-0
3.98
5.0 mg/l TCLP
F025
Condensed light ends from the production of certain chlorinated aliphatic hydro-
carbons, by free radical catalyzed processes. These chlorinated aliphatic hydrocarbons
are those having carbon chain lengths ranging from one to and including five, with
varying amounts and positions of chlorine substitution.
F025 - Light Ends Subcategory
541
Carbon tetrachloride
56-23-6
0.057
6.0
Chloroform
67-66-3
0.046
6.0
1,2-Dichloroethane
107-06-2
0.21
6.0
1,1-Dichloroethylene
75-35-4
0.025
6.0
Methylene chloride
75-9-2
0.089
30
1,1,2-Trichloroethane
79-00-5
0.054
6.0
Trichloroethylene
79-01-6
0.054
6.0
Vinyl chloride
75-01-4
0.27
6.0
F025
Spent filters and filter aids, and spent desiccant wastes from the production of certain
chlorinated aliphatic hydrocarbons, by free radical catalyzed processes. These
chlorinated aliphatic hydrocarbons are those having carbon chain lengths ranging from
one to and including five, with varying amounts and positions of chlorine substitution.
F025 - Spent Filters or Aids and Desiccants Subcategory
Carbon tetrachloride
56-23-5
0.067
6.0
Chloroform
67-66-3
0.046
6.0
Hexachlorobenzene
118-74-1
0.055
10
Hexachlorobutadiene
87-68-3
0.055
5.6
Hexachloroethane
67-72-1
0.055
30
Methylene chloride
75-9-2
0.089
30
1,1,2-Trichloroethane
79-00-5
0.054
6.0
Trichloroethylene
79-01-6
0.054
6.0
Vinyl chloride
75-01-4
0.27
6.0
F037
Petroleum refinery primary oil/water/solids separation sludge--Any sludge generated
from the gravitational separation of oil/water/solids during the storage or treatment of
process wastewaters and oily cooling wastewaters from petroleum refineries. Such
sludges include, but are not limited to, those generated in: oil/water/solids separators;
tanks and impoundments; ditches and other conveyances; sumps; and stormwater units
receiving dry weather flow. Sludge generated in stormwater units that do not receive
dry weather flow, sludges generated from non-contact once-through cooling waters
segregated for treatment from other process or oily cooling waters, sludges generated in
agressive biological treatment units as defined in 35 Ill. Adm. Code 721.131(b)(2)
(including sludges generated in one or more additional units after wastewaters have
been treated in agressive biological treatment units) and K051 wastes are not included
in this listing.
Acenaphthene
83-32-9
0.059
NA
Anthracene
120-12-7
0.059
3.4
Benzene
71-43-2
0.14
10
Benz(a)anthracene
56-55-3
0.059
3.4
Benzo(a)pyrene
50-32-8
0.061
3.4
bis(2-Ethylhexyl) phthalate
117-81-7
0.28
28
Chrysene
218-01-9
0.059
3.4
542
Di-n-butyl phthalate
84-74-2
0.057
28
Ethylbenzene
100-41-4
0.057
10
Fluorene
86-73-7
0.059
NA
Naphthalene
91-20-3
0.059
5.6
Phenanthrene
85-01-8
0.059
5.6
Phenol
108-95-2
0.039
6.2
Pyrene
129-00-0
0.067
8.2
Toluene
108-88-3
0.080
10
Xylenes-mixed isomers
(sum of o-, m-, and p-xylene
concentrations)
1330-20-7
0.32
30
Chromium (Total)
7440-47-3
2.77
0.86 mg/l TCLP
Cyanides (Total)
7
57-12-5
1.2
590
Lead
7439-92-1
0.69
NA
Nickel
7440-02-0
NA
5.0 mg/l TCLP
F038
Petroleum refinery secondary (emulsified) oil/water/solids separation sludge or float
generated from the physical or chemical separation of oil/water/solids in process
wastewaters and oily cooling wastewaters from petroleum refineries. Such wastes
include, but are not limited to, all sludges and floats generated in: induced air
floatation (IAF) units, tanks and impoundments, and all sludges generated in DAF
units. Sludges generated in stormwater units that do not receive dry weather flow,
sludges generated from non-contact once-through cooling waters segregated for
treatment from other process or oily cooling waters, sludges and floats generated in
agressive biological treatment units as defined in 35 Ill. Adm. Code 721.131(b)(2)
(including sludges and floats generated in one or more additional units after
wastewaters have been treated in agressive biological units) and F037, K048, and K051
are not included in this listing.
Benzene
71-43-2
0.14
10
Benzo(a)pyrene
50-32-8
0.061
3.4
bis(2-Ethylhexyl) phthalate
117-81-7
0.28
28
Chrysene
218-01-9
0.059
3.4
Di-n-butyl phthalate
84-74-2
0.057
28
Ethylbenzene
100-41-4
0.057
10
Fluorene
86-73-7
0.059
NA
Naphthalene
91-20-3
0.059
5.6
Phenanthrene
85-01-8
0.059
5.6
Phenol
108-95-2
0.039
6.2
Pyrene
129-00-0
0.067
8.2
Toluene
108-88-3
0.080
10
Xylenes-mixed isomers
(sum of o-, m-, and p-xylene
concentrations)
1330-20-7
0.32
30
Chromium (Total)
7440-47-3
2.77
0.86 mg/l TCLP
543
Cyanides (Total)
7
57-12-5
1.2
590
Lead
7439-92-1
0.69
NA
Nickel
7440-02-0
NA
5.0 mg/l TCLP
F039
Leachate (liquids that have percolated through land disposed wastes) resulting from the
disposal of more than one restricted waste classified as hazardous under 728.Subpart D
of this Part. (Leachate resulting from the disposal of one or more of the following
USEPA hazardous wastes and no other hazardous wastes retains its USEPA hazardous
waste numbers: F020, F021, F022, F026, F027, or F028.).
Acenaphthylene
208-96-8
0.059
3.4
Acenaphthene
83-32-9
0.059
3.4
Acetone
67-64-1
0.28
160
Acetonitrile
75-05-8
5.6
NA
Acetophenone
96-86-2
0.010
9.7
2-Acetylaminofluorene
53-96-3
0.059
140
Acrolein
107-02-8
0.29
NA
Acrylonitrile
107-13-1
0.24
84
Aldrin
309-00-2
0.021
0.066
4-Aminobiphenyl
92-67-1
0.13
NA
Aniline
62-53-3
0.81
14
Anthracene
120-12-7
0.059
3.4
Aramite
140-57-8
0.36
NA
alpha-BHC
319-84-6
0.00014
0.066
beta-BHC
319-85-7
0.00014
0.066
delta-BHC
319-86-8
0.023
0.066
gamma-BHC
58-89-9
0.0017
0.066
Benzene
71-43-2
0.14
10
Benz(a)anthracene
56-55-3
0.059
3.4
Benzo(b)fluoranthene
(difficult to distinguish from
benzo(k)fluoranthene)
205-99-2
0.11
6.8
Benzo(k)fluoranthene
(difficult to distinguish from
benzo(b)fluoranthene)
207-08-9
0.11
6.8
Benzo(g,h,i)perylene
191-24-2
0.0055
1.8
Benzo(a)pyrene
50-32-8
0.061
3.4
Bromodichloromethane
75-27-4
0.35
15
Methyl bromide (Bromo-
methane)
74-83-9
0.11
15
4-Bromophenyl phenyl ether
101-55-3
0.055
15
n-Butyl alcohol
71-36-3
5.6
2.6
Butyl benzyl phthalate
85-68-7
0.017
28
2-sec-Butyl-4,6-dinitro-
phenol (Dinoseb)
88-85-7
0.066
2.5
544
Carbon disulfide
75-15-0
3.8
NA
Carbon tetrachloride
56-23-5
0.057
6.0
Chlordane (alpha and gamma
isomers)
57-74-9
0.0033
0.26
p-Chloroaniline
106-47-8
0.46
16
Chlorobenzene
108-90-7
0.057
6.0
Chlorobenzilate
510-15-6
0.10
NA
2-Chloro-1,3-butadiene
126-99-8
0.057
NA
Chlorodibromomethane
124-48-1
0.057
15
Chloroethane
75-00-3
0.27
6.0
bis(2-Chloroethoxy)methane
111-91-1
0.036
7.2
bis(2-Chloroethyl)ether
111-44-4
0.033
6.0
Chloroform
67-66-3
0.046
6.0
bis(2-Chloroisopropyl)ether
108-60-139638-
32-9
0.055
7.2
p-Chloro-m-cresol
59-50-7
0.018
14
Chloromethane (Methyl
chloride)
74-87-3
0.19
30
2-Chloronaphthalene
91-58-7
0.055
5.6
2-Chlorophenol
95-57-8
0.044
5.7
3-Chloropropylene
107-05-1
0.036
30
Chrysene
218-01-9
0.059
3.4
o-Cresol
95-48-7
0.11
5.6
m-Cresol
(difficult to distinguish from
p-cresol)
108-39-4
0.77
5.6
p-Cresol
(difficult to distinguish from
m-cresol)
106-44-5
0.77
5.6
Cyclohexanone
108-94-1
0.36
NA
1,2-Dibromo-3-chloro-
propane
96-12-8
0.11
15
Ethylene dibromide (1,2-
Dibromoethane)
106-93-4
0.028
15
Dibromomethane
74-95-3
0.11
15
2,4-D (2,4-Dichloro-
phenoxyacetic acid)
94-75-7
0.72
10
o,p'-DDD
53-19-0
0.023
0.087
p,p'-DDD
72-54-8
0.023
0.087
o,p'-DDE
3424-82-6
0.031
0.087
p,p'-DDE
72-55-9
0.031
0.087
o,p'-DDT
789-02-6
0.0039
0.087
p,p'-DDT
50-29-3
0.0039
0.087
Dibenz(a,h)anthracene
53-70-3
0.055
8.2
Dibenz(a,e)pyrene
192-65-4
0.061
NA
545
m-Dichlorobenzene
541-73-1
0.036
6.0
o-Dichlorobenzene
95-50-1
0.088
6.0
p-Dichlorobenzene
106-46-7
0.090
6.0
Dichlorodifluoromethane
75-71-8
0.23
7.2
1,1-Dichloroethane
75-34-3
0.059
6.0
1,2-Dichloroethane
107-06-2
0.21
6.0
1,1-Dichloroethylene
75-35-4
0.025
6.0
trans-1,2-Dichloroethylene
156-60-5
0.054
30
2,4-Dichlorophenol
120-83-2
0.044
14
2,6-Dichlorophenol
87-65-0
0.044
14
1,2-Dichloropropane
78-87-5
0.85
18
cis-1,3-Dichloropropylene
10061-01-5
0.036
18
trans-1,3-Dichloropropylene
10061-02-6
0.036
18
Dieldrin
60-57-1
0.017
0.13
Diethyl phthalate
84-66-2
0.20
28
2-4-Dimethyl phenol
105-67-9
0.036
14
Dimethyl phthalate
131-11-3
0.047
28
Di-n-butyl phthalate
84-74-2
0.057
28
1,4-Dinitrobenzene
100-25-4
0.32
2.3
4,6-Dinitro-o-cresol
534-52-1
0.28
160
2,4-Dinitrophenol
51-28-5
0.12
160
2,4-Dinitrotoluene
121-14-2
0.32
140
2,6-Dinitrotoluene
606-20-2
0.55
28
Di-n-octyl phthalate
117-84-0
0.017
28
Di-n-propylnitrosamine
621-64-7
0.40
14
1,4-Dioxane
123-91-1
NA12.0
170
Diphenylamine (difficult to
distinguish from diphenyl-
nitrosamine)
122-39-4
0.92
13NA
Diphenylnitrosamine
(difficult to distinguish from
diphenylamine)
86-30-6
0.92
NA
1,2-Diphenylhydrazine
122-66-7
0.087
NA
Disulfoton
298-04-4
0.017
6.2
Endosulfan I
939-98-8
0.023
0.066
Endosulfan II
33213-6-5
0.029
0.13
Endosulfan sulfate
1-31-07-81031-
07-8
0.029
0.13
Endrin
72-20-8
0.0028
0.13
Endrin aldehyde
7421-93-4
0.025
0.13
Ethyl acetate
141-78-6
0.34
33
Ethyl cyanide (Propane-
nitrile)
107-12-0
0.24
360
Ethyl benzene
100-41-4
0.057
10
Ethyl ether
60-29-7
0.12
160
546
bis(2-Ethylhexyl) phthalate
117-81-7
0.28
28
Ethyl methacrylate
97-63-2
0.14
160
Ethylene oxide
75-21-8
0.12
NA
Famphur
52-85-7
0.017
15
Fluoranthene
206-44-0
0.068
3.4
Fluorene
86-73-7
0.059
3.4
Heptachlor
76-44-8
0.0012
0.066
Heptachlor epoxide
1024-57-3
0.016
0.066
Hexachlorobenzene
118-74-1
0.055
10
Hexachlorobutadiene
87-68-3
0.055
5.6
Hexachlorocyclopentadiene
77-47-4
0.057
2.4
HxCDDs (All Hexachloro-
dibenzo-p-dioxins)
NA
0.000063
0.001
HxCDFs (All Hexachloro-
dibenzofurans)
NA
0.000063
0.001
Hexachloroethane
67-72-1
0.055
30
Hexachloropropylene
1888-71-7
0.035
30
Indeno (1,2,3-c,d) pyrene
193-39-5
0.0055
3.4
Iodomethane
74-88-4
0.19
65
Isobutyl alcohol
78-83-1
5.6
170
Isodrin
465-73-6
0.021
0.066
Isosafrole
120-58-1
0.081
2.6
Kepone
143-50-8
0.0011
0.13
Methacrylonitrile
126-98-7
0.24
84
Methanol
67-56-1
5.6
NA
Methapyrilene
91-80-5
0.081
1.5
Methoxychlor
72-43-5
0.25
0.18
3-Methylcholanthrene
56-49-5
0.0055
15
4,4-Methylene bis(2-chloro-
aniline)
101-14-4
0.50
30
Methylene chloride
75-09-2
0.089
30
Methyl ethyl ketone
78-93-3
0.28
36
Methyl isobutyl ketone
108-10-1
0.14
33
Methyl methacrylate
80-62-6
0.14
160
Methyl methansulfonate
66-27-3
0.018
NA
Methyl parathion
298-00-0
0.014
4.6
Naphthalene
91-20-3
0.059
5.6
2-Naphthylamine
91-59-8
0.52
NA
p-Nitroaniline
100-01-6
0.028
28
Nitrobenzene
98-95-3
0.068
14
5-Nitro-o-toluidine
99-55-8
0.32
28
p-Nitrophenol
100-02-7
0.12
29
N-Nitrosodiethylamine
55-18-5
0.40
28
N-Nitrosodimethylamine
62-75-9
0.40
NA
N-Nitroso-di-n-butylamine
924-16-3
0.40
17
547
N-Nitrosomethylethylamine
10595-95-6
0.40
2.3
N-Nitrosomorpholine
59-89-2
0.40
2.3
N-Nitrosopiperidine
100-75-4
0.013
35
N-Nitrosopyrrolidine
930-55-2
0.013
35
Parathion
56-38-2
0.014
4.6
Total PCBs
(sum of all PCB isomers, or
all Aroclors)
1336-36-3
0.10
10
Pentachlorobenzene
608-93-5
0.055
10
PeCDDs (All Pentachloro-
dibenzo-p-dioxins)
NA
0.000063
0.001
PcCDFsPeCDFs (All Penta-
chlorodibenzofurans)
NA
0.000035
0.001
Pentachloronitrobenzene
82-68-8
0.055
4.8
Pentachlorophenol
87-86-5
0.089
7.4
Phenacetin
62-44-2
0.081
16
Phenanthrene
85-01-8
0.059
5.6
Phenol
108-95-2
0.039
6.2
Phorate
298-02-2
0.021
4.6
Phthalic anhydride
85-44-9
0.055
NA
Pronamide
23950-58-5
0.093
1.5
Pyrene
129-00-0
0.067
8.2
Pyridine
110-86-1
0.014
16
Safrole
94-59-7
0.081
22
Silvex (2,4,5-TP)
93-72-1
0.72
7.9
2,4,5-T
93-76-5
0.72
7.9
1,2,4,5-Tetrachlorobenzene
95-94-3
0.055
14
TCDDs (All Tetrachloro-
dibenzo-p-dioxins)
NA
0.000063
0.001
TCDFs (All Tetrachloro-
dibenzofurans)
NA
0.000063
0.001
1,1,1,2-Tetrachloroethane
630-20-6
0.057
6.0
1,1,2,2-Tetrachloroethane
79-34-6
0.057
6.0
Tetrachloroethylene
127-18-4
0.056
6.0
2,3,4,6-Tetrachlorophenol
58-90-2
0.030
7.4
Toluene
108-88-3
0.080
10
Toxaphene
8001-35-2
0.0095
2.6
Bromoform (Tribromo-
methane)
75-25-2
0.63
15
1,2,4-Trichlorobenzene
120-82-1
0.055
19
1,1,1-Trichloroethane
71-55-6
0.054
6.0
1,1,2-Trichloroethane
79-00-5
0.054
6.0
Trichloroethylene
79-01-6
0.054
6.0
Trichloromonofluoromethane
75-69-4
0.020
30
2,4,5-Trichlorophenol
95-95-4
0.18
7.4
548
2,4,6-Trichlorophenol
88-06-2
0.035
7.4
1,2,3-Trichloropropane
96-18-4
0.85
30
1,1,2-Trichloro-1,2,2-
trifluoroethane
76-13-1
0.057
30
tris(2,3-Dibromopropyl)
phosphate
126-72-7
0.11
NA
Vinyl chloride
75-01-4
0.27
6.0
Xylenes-mixed isomers
(sum or o-, m-, and p-xylene
concentrations)
1330-20-7
0.32
30
Antimony
7440-36-0
1.9
2.1 mg/l TCLP
Arsenic
7440-38-2
1.4
5.0 mg/l TCLP
Barium
7440-39-3
1.2
7.6 mg/l TCLP
Beryllium
7440-41-7
0.82
NA
Cadmium
7440-43-9
0.69
0.19 mg/l TCLP
Chromium (Total)
7440-47-3
2.77
0.86 mg/l TCLP
Cyanides (Total)
7
57-12-5
1.2
590
Cyanides (Amenable)
7
57-12-5
0.86
NA
Fluoride
16964-48-8
35
NA
Lead
7439-92-1
0.69
0.37 mg/l TCLP
Mercury
7439-97-6
0.15
0.025 mg/l
TCLP
Nickel
7440-02-0
3.98
5.0 mg/l TCLP
Selenium
7782-49-2
0.82
0.16 mg/l TCLP
Silver
7440-22-4
0.43
0.30 mg/l TCLP
Sulfide
8496-25-8
14
NA
Thallium
7440-28-0
1.4
NA
Vanadium
7440-62-2
4.3
NA
K001
Bottom sediment sludge from the treatment of wastewaters from wood preserving
processes that use creosote or pentachlorophenol.
Naphthalene
91-20-3
0.059
5.6
Pentachlorophenol
87-86-5
0.089
7.4
Phenanthrene
85-01-8
0.059
5.6
Pyrene
129-00-0
0.067
8.2
Toluene
108-88-3
0.080
10
Xylenes-mixed isomers
(sum of o-, m-, and p-xylene
concentrations)
1330-20-7
0.32
30
Lead
7439-92-1
0.690.37 mg/l
TCLP
0.37 mg/l TCLP
K002
549
Wastewater treatment sludge from the production of chrome yellow and orange
pigments.
Chromium (Total)
7440-47-3
2.77
0.86 mg/l TCLP
Lead
7439-92-1
0.69
0.37 mg/l TCLP
K003
Wastewater treatment sludge from the production of molybdate orange pigments.
Chromium (Total)
7440-47-3
2.77
0.86 mg/l TCLP
Lead
7439-92-1
0.69
0.37 mg/l TCLP
K004
Wastewater treatment sludge from the production of zinc yellow pigments.
Chromium (Total)
7440-47-3
2.77
0.86 mg/l TCLP
Lead
7439-92-1
0.69
0.37 mg/l TCLP
K005
Wastewater treatment sludge from the production of chrome green pigments.
Chromium (Total)
7440-47-3
2.77
0.86 mg/l TCLP
Lead
7439-92-1
0.69
0.37 mg/l TCLP
Cyanides (Total)
7
57-12-5
1.25
590
K006
Wastewater treatment sludge from the production of chrome oxide green pigments
(anhydrous).
Chromium (Total)
7440-47-3
2.77
0.86 mg/l TCLP
Lead
7439-92-1
0.69
0.37 mg/l TCLP
K006
Wastewater treatment sludge from the production of chrome oxide green pigments
(hydrated).
Chromium (Total)
7440-47-3
2.77
0.86 mg/l TCLP
Lead
7439-92-1
0.69
NA
K007
Wastewater treatment sludge from the production of iron blue pigments.
Chromium (Total)
7440-47-3
2.77
0.86 mg/l TCLP
Lead
7439-92-1
0.69
0.37 mg/l TCLP
Cyanides (Total)
7
57-12-5
1.25
590
K008
Oven residue from the production of chrome oxide green pigments.
Chromium (Total)
7440-47-3
2.77
0.86 mg/l TCLP
Lead
7439-92-1
0.69
0.37 mg/l TCLP
K009
550
Distillation bottoms from the production of acetaldehyde from ethylene.
Chloroform
67-66-3
0.046
6.0
K010
Distillation side cuts from the production of acetaldehyde from ethylene.
Chloroform
67-66-3
0.046
6.0
K011
Bottom stream from the wastewater stripper in the production of acrylonitrile.
Acetonitrile
75-05-8
5.6
1.838
Acrylonitrile
107-13-1
0.24
84
Acrylamide
79-06-1
19
23
Benzene
71-43-2
0.14
10
Cyanide (Total)
57-12-5
1.2
590
K013
Bottom stream from the acetonitrile column in the production of acrylonitrile.
Acetonitrile
75-05-8
5.6
1.838
Acrylonitrile
107-13-1
0.24
84
Acrylamide
79-06-1
19
23
Benzene
71-43-2
0.14
10
Cyanide (Total)
57-12-5
1.2
590
K014
Bottoms from the acetonitrile purification column in the production of acrylonitrile.
Acetonitrile
75-05-8
5.6
1.838
Acrylonitrile
107-13-1
0.24
84
Acrylamide
79-06-1
19
23
Benzene
71-43-2
0.14
10
Cyanide (Total)
57-12-5
1.2
590
K015
Still bottoms from the distillation of benzyl chloride.
Anthracene
120-12-7
0.059
3.4
Benzal chloride
98-87-3
0.055
6.0
Benzo(b)fluoranthene
(difficult to distinguish from
benzo(k)fluoranthene)
205-99-2
0.11
6.8
Benzo(k)fluoranthene
(difficult to distinguish from
benzo(b)fluoranthene)
207-08-9
0.11
6.8
Phenanthrene
85-01-8
0.059
5.6
Toluene
108-88-3
0.080
10
Chromium (Total)
7440-47-3
2.77
0.86 mg/l TCLP
Nickel
7440-02-0
3.98
85.0 mg/l TCLP
551
K016
Heavy ends or distillation residues from the production of carbon tetrachloride.
Hexachlorobenzene
118-74-1
0.055
10
Hexachlorobutadiene
87-68-3
0.055
5.6
Hexachlorocyclopentadiene
77-47-4
0.057
2.4
Hexachloroethane
67-72-1
0.055
30
Tetrachloroethylene
127-18-4
0.056
6.0
K017
Heavy ends (still bottoms) from the purification column in the production of epichloro-
hydrin.
bis(2-Chloroethyl)ether
111-44-4
0.033
6.0
1,2-Dichloropropane
78-87-5
0.85
18
1,2,3-Trichloropropane
96-18-4
0.85
30
K018
Heavy ends from the fractionation column in ethyl chloride production.
Chloroethane
75-00-3
0.27
6.0
Chloromethane
74-87-3
0.19
NA
1,1-Dichloroethane
75-34-3
0.059
6.0
1,2-Dichloroethane
107-06-2
0.21
6.0
Hexachlorobenzene
118-74-1
0.055
10
Hexachlorobutadiene
87-68-3
0.055
5.6
Hexachloroethane
67-72-1
0.055
30
Pentachloroethane
76-01-7
NA
6.0
1,1,1-Trichloroethane
71-55-6
0.054
6.0
K019
Heavy ends from the distillation of ethylene dichloride in ethylene dichloride
production.
bis(2-Chloroethyl)ether
111-44-4
0.033
6.0
Chlorobenzene
108-90-7
0.057
6.0
Chloroform
67-66-3
0.046
6.0
p-Dichlorobenzene
106-46-7
0.090
NA
1,2-Dichloroethane
107-06-2
0.21
6.0
Fluorene
86-73-7
0.059
NA
Hexachloroethane
67-72-1
0.055
30
Naphthalene
91-20-3
0.059
5.6
Phenanthrene
85-01-8
0.059
5.6
1,2,4,5-Tetrachlorobenzene
95-94-3
0.055
NA
Tetrachloroethylene
127-18-4
0.056
6.0
1,2,4-Trichlorobenzene
120-82-1
0.055
19
1,1,1-Trichloroethane
71-55-6
0.054
6.0
K020
552
Heavy ends from the distillation of vinyl chloride in vinyl chloride monomer
production.
1,2-Dichloroethane
107-06-2
0.21
6.0
1,1,2,2-Tetrachloroethane
79-34-6
0.057
6.0
Tetrachloroethylene
127-18-4
0.056
6.0
K021
Aqueous spent antimony catalyst waste from fluoromethanes production.
Carbon tetrachloride
56-23-5
0.057
6.0
Chloroform
67-66-3
0.046
6.0
Antimony
7440-36-0
1.9
2.1 mg/l TCLP
K021
Aqueous spent antimony catalyst waste from fluoromethanes production.
Carbon tetrachloride
56-23-5
0.057
6.0
Chloroform
67-66-3
0.046
6.0
Antimony
7440-36-0
1.9
2.1 mg/l TCLP
K022
Distillation bottom tars from the production of phenol or acetone from cumene.
Toluene
108-88-3
0.080
10
Acetophenone
96-86-2
0.010
9.7
Diphenylamine (difficult to
distinguish from diphenyl-
nitrosamine)
122-39-4
0.92
13
Diphenylnitrosamine
(difficult to distinguish from
diphenylamine)
86-30-6
0.92
13
Phenol
108-95-2
0.039
6.2
Chromium (Total)
7440-47-3
2.77
0.86 mg/l TCLP
Nickel
7440-02-0
3.98
5.0 mg/l TCLP
K023
Distillation light ends from the production of phthalic anhydride from naphthalene.
Phthalic anhydride
(measured as Phthalic acid
or Terephthalic acid)
100-21-0
0.055
28
Phthalic anhydride
(measured as Phthalic acid
or Terephthalic acid)
85-44-9
0.055
28
K024
Distillation bottoms from the production of phthalic anhydride from naphthalene.
Phthalic anhydride
(measured as Phthalic acid
100-21-0
0.055
28
553
or Terephthalic acid)
Phthalic anhydride
(measured as Phthalic acid
or Terephthalic acid)
85-44-9
0.055
28
K025
Distillation bottoms from the production of nitrobenzene by the nitration of benzene.
NA
NA
LLEXT fb
SSTRP fb
CARBN; or
INCINCMBST
INCINCMBST
K026
Stripping still tails from the production of methyl ethyl pyridines.
NA
NA
INCINCMBST
INCINCMBST
K027
Centrifuge and distillation residues from the toluene diisocyanate production.
NA
NA
CARBN; or
INCINCMBST
CMBST
K028
Spent catalyst from the hydrochlorinator reactor in the production of 1,1,1-trichloro-
ethane.
1,1-Dichloroethane
75-34-3
0.059
6.0
trans-1,2-Dichloroethylene
156-60-5
0.054
30
Hexachlorobutadiene
87-68-3
0.055
5.6
Hexachloroethane
67-72-1
0.055
30
Pentachloroethane
76-01-7
NA
6.0
1,1,1,2-Tetrachloroethane
630-20-6
0.057
6.0
1,1,2,2-Tetrachloroethane
79-34-6
0.057
6.0
Tetrachloroethylene
127-18-4
0.056
6.0
1,1,1-Trichloroethane
71-55-6
0.054
6.0
1,1,2-Trichloroethane
79-00-5
0.054
6.0
Cadmium
7440-43-9
0.69
NA
Chromium(Total)
7440-47-3
2.77
0.86 mg/l TCLP
Lead
7439-92-1
0.69
0.37 mg/l TCLP
Nickel
7440-02-0
3.98
5.0 mg/l TCLP
K029
Waste from the product steam stripper in the production of 1,1,1-trichloroethane.
Chloroform
67-66-3
0.046
6.0
1,2-Dichloroethane
107-06-2
0.21
6.0
1,1-Dichloroethylene
75-35-4
0.025
6.0
1,1,1-Trichloroethane
71-55-6
0.054
6.0
554
Vinyl chloride
75-01-4
0.27
6.0
K030
Column bodies or heavy ends from the combined production of trichloroethylene and
perchloroethylene.
o-Dichlorobenzene
95-50-1
0.088
NA
p-Dichlorobenzene
106-46-7
0.090
NA
Hexachlorobutadiene
87-68-3
0.055
5.6
Hexachloroethane
67-72-1
0.055
30
Hexachloropropylene
1888-71-7
NA
30
Pentachlorobenzene
608-93-5
NA
10
Pentachloroethane
76-01-7
NA
6.0
1,2,4,5-Tetrachlorobenzene
95-94-3
0.055
14
Tetrachloroethylene
127-18-4
0.056
6.0
1,2,4-Trichlorobenzene
120-82-1
0.055
19
K031
By-product salts generated in the production of MSMA and cacodylic acid.
Arsenic
7440-38-2
1.4
5.0 mg/l TCLP
K032
Wastewater treatment sludge from the production of chlordane.
Hexachlorocyclopentadiene
77-47-4
0.057
2.4
Chlordane (alpha and gamma
isomers)
57-74-9
0.0033
0.26
Heptachlor
76-44-8
0.0012
0.066
Heptachlor epoxide
1024-57-3
0.016
0.066
K033
Wastewater and scrub water from the chlorination of cyclopentadiene in the production
of chlordane.
Hexachlorocyclopentadiene
77-47-4
0.057
2.4
K034
Filter solids from the filtration of hexachlorocyclopentadiene in the production of
chlordane.
Hexachlorocyclopentadiene
77-47-4
0.057
2.4
K035
Wastewater treatment sludges generated in the production of creosote.
Acenaphthene
83-32-9
NA
3.4
Anthracene
120-12-7
NA
3.4
Benz(a)anthracene
56-55-3
0.059
3.4
Benzo(a)pyrene
50-32-8
0.061
3.4
Chrysene
218-01-9
0.059
3.4
555
o-Cresol
95-48-7
0.11
5.6
m-Cresol
(difficult to distinguish from
p-cresol)
108-39-4
0.77
5.6
p-Cresol
(difficult to distinguish from
m-cresol)
106-44-5
0.77
5.6
Dibenz(a,h)anthracene
53-70-3
NA
8.2
Fluoranthene
206-44-0
0.068
3.4
Fluorene
86-73-7
NA
3.4
Indeno(1,2,3-cd)pyrene
193-39-5
NA
3.4
Naphthalene
91-20-3
0.059
5.6
Phenanthrene
85-01-8
0.059
5.6
Phenol
108-95-2
0.039
6.2
Pyrene
129-00-0
0.067
8.2
K036
Still bottoms from toluene reclamation distillaiton in the production of disulfoton.
Disulfoton
298-04-4
0.017
6.2
K037
Wastewater treatment sludges from the production of disulfoton.
Disulfoton
298-04-4
0.017
6.2
Toluene
108-88-3
0.080
10
K038
Wastewater from the washing and stripping of phorate production.
Phorate
298-02-2
0.021
4.6
K039
Filter cake from the filtration of diethylphosphorodithioic acid in the production of
phorate.
NA
NA
CARBN; or
INCINCMBST
CMBST
K040
Wastewater treatment sludge from the production of phorate.
Phorate
298-02-2
0.021
4.6
K041
Wastewater treatment sludge from the production of toxaphene.
Toxaphene
8001-35-2
0.0095
2.6
K042
556
Heavy ends or distillation residues from the distillation of tetrachlorobenzene in the
production of 2,4,5-T.
o-Dichlorobenzene
95-50-1
0.088
6.0
p-Dichlorobenzene
106-46-7
0.090
6.0
Pentachlorobenzene
608-93-5
0.055
10
1,2,4,5-Tetrachlorobenzene
95-94-3
0.055
14
1,2,4-Trichlorobenzene
120-82-1
0.055
19
K043
2,6-Dichlorophenol waste from the production of 2,4-D.
2,4-Dichlorophenol
120-83-2
0.044
14
2,6-Dichlorophenol
187-65-0
0.044
14
2,4,5-Trichlorophenol
95-95-4
0.18
7.4
2,4,6-Trichlorophenol
88-06-2
0.035
7.4
2,3,4,6-Tetrachlorophenol
58-90-2
0.030
7.4
Pentachlorophenol
87-86-5
0.089
7.4
Tetrachloroethylene
127-18-4
0.056
6.0
HxCDDs (All Hexachloro-
dibenzo-p-dioxins)
NA
0.000063
0.001
HxCDFs (All Hexachloro-
dibenzofurans)
NA
0.000063
0.001
PeCDDs (All Pentachloro-
dibenzo-p-dioxins)
NA
0.000063
0.001
PeCDFs (All Pentachloro-
dibenzofurans)
NA
0.000035
0.001
TCDDs (All Tetrachloro-
dibenzo-p-dioxins)
NA
0.000063
0.001
TCDFs (All Tetrachloro-
dibenzofurans)
NA
0.000063
0.001
K044
Wastewater treatment sludges from the manufacturing and processing of explosives.
NA
NA
DEACT
DEACT
K045
Spent carbon from the treatment of wastewater containing explosives.
NA
NA
DEACT
DEACT
K046
Wastewater treatment sludges from the manufacturing, formulation and loading of lead-
based initiating compounds.
Lead
7439-92-1
0.69
0.37 mg/l TCLP
K047
Pink or red water from TNT operations.
557
NA
NA
DEACT
DEACT
K048
Dissolved air flotation (DAF) float from the petroleum refining industry.
Benzene
71-43-2
0.14
10
Benzo(a)pyrene
50-32-8
0.061
3.4
bis(2-Ethylhexyl) phthalate
117-81-7
0.28
28
Chrysene
218-01-9
0.059
3.4
Di-n-butyl phthalate
84-74-2
0.057
28
Ethylbenzene
100-41-4
0.057
10
Fluorene
86-73-7
0.059
NA
Naphthalene
91-20-3
0.059
5.6
Phenanthrene
85-01-8
0.059
5.6
Phenol
108-95-2
0.039
6.2
Pyrene
129-00-0
0.067
8.2
Toluene
108-88-33
0.080
10
Xylenes-mixed isomers
(sum of o-, m-, and p-xylene
concentrations)
1330-20-7
0.32
30
Chromium (Total)
7440-47-3
2.77
0.86 mg/l TCLP
Cyanides (Total)
7
57-12-5
1.2
590
Lead
7439-92-1
0.69
NA
Nickel
7440-02-0
NA
5.0 mg/l TCLP
K049
Slop oil emulsion solids from the petroleum refining industry.
Anthracene
120-12-7
0.059
3.4
Benzene
71-43-2
0.14
10
Benzo(a)pyrene
50-32-8
0.061
3.4
bis(2-Ethylhexyl) phthalate
117-81-7
0.28
28
Carbon disulfide
75-15-0
3.8
NA
Chrysene
2218-01-9
0.059
3.4
2,4-Dimethylphenol
105-67-9
0.036
NA
Ethylbenzene
100-41-4
0.057
10
Naphthalene
91-20-3
0.059
5.6
Phenanthrene
85-01-8
0.059
5.6
Phenol
108-95-2
0.039
6.2
Pyrene
129-00-0
0.067
8.2
Toluene
108-88-3
0.080
10
Xylenes-mixed isomers
(sum of o-, m-, and p-xylene
concentrations)
1330-20-7
0.32
30
Cyanides (Total)
7
57-12-5
1.2
590
Chromium (Total)
7440-47-3
2.77
0.86 mg/l TCLP
Lead
7439-92-1
0.69
NA
558
Nickel
7440-02-0
NA
5.0 mg/l TCLP
K050
Heat exchanger bundle cleaning sludge from the petroleum refining industry.
Benzo(a)pyrene
50-32-8
0.061
3.4
Phenol
108-95-2
0.039
6.2
Cyanides (Total)
7
57-12-5
1.2
590
Chromium (Total)
7440-47-3
2.77
0.86 mg/l TCLP
Lead
7439-92-1
0.69
NA
Nickel
7440-02-0
NA
5.0 mg/l TCLP
K051
API separator sludge from the petroleum refining industry.
Acenaphthene
83-32-9
0.059
NA
Anthracene
120-12-7
0.059
3.4
Benz(a)anthracene
56-55-3
0.059
3.4
Benzene
71-43-2
0.14
10
Benzo(a)pyrene
50-32-8
0.061
3.4
bis(2-Ethylhexyl) phthalate
117-81-7
0.28
28
Chrysene
2218-01-9
0.059
3.4
Di-n-butyl phthalate
105-67-9
0.057
28
Ethylbenzene
100-41-4
0.057
10
Fluorene
86-73-7
0.059
NA
Naphthalene
91-20-3
0.059
5.6
Phenanthrene
85-01-8
0.059
5.6
Phenol
108-95-2
0.039
6.2
Pyrene
129-00-0
0.067
8.2
Toluene
108-88-3
0.08
10
Xylenes-mixed isomers
(sum of o-, m-, and p-xylene
concentrations)
1330-20-7
0.32
30
Cyanides (Total)
7
57-12-5
1.2
590
Chromium (Total)
7440-47-3
2.77
0.86 mg/l TCLP
Lead
7439-92-1
0.69
NA
Nickel
7440-02-0
NA
5.0 mg/l TCLP
K052
Tank bottoms (leaded) from the petroleum refining industry.
Benzene
71-43-2
0.14
10
Benzo(a)pyrene
50-32-8
0.061
3.4
o-Cresol
95-48-7
0.11
5.6
m-Cresol
(difficult to distinguish from
p-cresol)
108-39-4
0.77
5.6
p-Cresol
106-44-5
0.77
5.6
559
(difficult to distinguish from
m-cresol)
2,4-Dimethylphenol
105-67-9
0.036
NA
Ethylbenzene
100-41-4
0.057
10
Naphthalene
91-20-3
0.059
5.6
Phenanthrene
85-01-8
0.059
5.6
Phenol
108-95-2
0.039
6.2
Toluene
108-88-3
0.08
10
Xylenes-mixed isomers
(sum of o-, m-, and p-xylene
concentrations)
1330-20-7
0.32
30
Chromium (Total)
7440-47-3
2.77
0.86 mg/l TCLP
Cyanides (Total)
7
57-12-5
1.2
590
Lead
7439-92-1
0.69
NA
Nickel
7440-02-0
NA
5.0 mg/l TCLP
K060
Ammonia still lime sludge from coking operations.
Benzene
71-43-2
0.14
10
Benzo(a)pyrene
50-32-8
0.061
3.4
Naphthalene
91-20-3
0.059
5.6
Phenol
108-95-2
0.039
6.2
Cyanides (Total)
7
57-12-5
1.2
590
K061
Emission control dust or sludge from the primary production of steel in electric
furnaces.
Antimony
7440-36-0
NA
2.1 mg/l TCLP
Arsenic
7440-38-2
NA
5.0 mg/l TCLP
Barium
7440-39-3
NA
7.6 mg/l TCLP
Beryllium
7440-41-7
NA
0.014 mg/l
TCLP
Cadmium
7440-43-9
0.69
0.19 mg/l TCLP
Chromium (Total)
7440-47-3
2.77
0.86 mg/l TCLP
Lead
7439-92-1
0.69
0.37 mg/l TCLP
Mercury
7439-97-6
NA
0.025 mg/l
TCLP
Nickel
7440-02-0
3.98
5.0 mg/l TCLP
Selenium
7782-49-2
NA
0.16 mg/l TCLP
Silver
7440-22-4
NA
0.30 mg/l TCLP
Thallium
NA7440-28-0
NA
0.078 mg/l
TCLP
Zinc
7440-66-6
NA
5.3 mg/l TCLP
K062
560
Spent pickle liquor generated by steel finishing operations of facilities within the iron
and steel industry (SIC Codes 331 and 332).
Chromium (Total)
7440-47-3
2.77
0.86 mg/l TCLP
Lead
7439-92-1
0.69
0.37 mg/l TCLP
Nickel
7440-02-0
3.98
NA
K069
Emission control dust or sludge from secondary lead smelting. - Calcium sulfate (Low
Lead) Subcategory
Cadmium
7440-43-9
0.69
0.19 mg/l TCLP
Lead
7439-92-1
0.69
0.37 mg/l TCLP
K069
Emission control dust or sludge from secondary lead smelting. - Non-Calcium sulfate
(High Lead) Subcategory
NA
NA
NA
RLEAD
K071
K071 (Brine purification muds from the mercury cell process in chlorine production,
where separately prepurified brine is not used) nonwastewaters that are residues from
RMERC.
Mercury
7439-97-6
NA
0.20 mg/l TCLP
K071
K071 (Brine purification muds from the mercury cell process in chlorine production,
where separately prepurified brine is not used) nonwastewaters that are not residues
from RMERC.
Mercury
7439-97-6
NA
0.025 mg/l
TCLP
K071
All K071 wastewaters.
Mercury
7439-97-6
0.15
NA
K073
Chlorinated hydrocarbon waste from the purification step of the diaphragm cell process
using graphite anodes in chlorine production.
Carbon tetrachloride
56-23-5
0.057
6.0
Chloroform
67-66-3
0.046
6.0
Hexachloroethane
67-72-1
0.055
30
Tetrachloroethylene
127-18-4
0.0580.056
6.0
1,1,1-Trichloroethane
71-55-6
0.054
6.0
K083
Distillation bottoms from aniline production.
561
Aniline
62-53-3
0.81
14
Benzene
71-43-2
0.14
10
Cyclohexanone
108-94-1
0.36
NA
Diphenylamine
(difficult to distinguish from
diphenylnitrosamine)
122-39-4
0.92
13
Diphenylnitrosamine
(difficult to distinguish from
diphenylamine)
86-30-6
0.92
13
Nitrobenzene
98-95-3
0.068
14
Phenol
108-95-2
0.039
6.2
Nickel
7440-02-0
3.98
5.0 mg/l TCLP
K084
Wastewater treatment sludges generated during the production of veterinary
pharmaceuticals from arsenic or organo-arsenic compounds.
Arsenic
7440-38-2
1.4
5.0 mg/l TCLP
K085
Distillation or fractionation column bottoms from the production of chlorobenzenes.
Benzene
71-43-2
0.14
10
Chlorobenzene
108-90-7
0.057
6.0
m-Dichlorobenzene
541-73-1
0.036
6.0
o-Dichlorobenzene
95-50-1
0.088
6.0
p-Dichlorobenzene
106-46-7
0.090
6.0
Hexachlorobenzene
118-74-1
0.055
10
Total PCBs
(sum of all PCB isomers, or
all Aroclors)
1336-36-3
0.10
10
Pentachlorobenzene
608-93-5
0.055
10
1,2,4,5-Tetrachlorobenzene
95-94-3
0.055
14
1,2,4-Trichlorobenzene
120-82-1
0.055
19
K086
Solvent wastes and sludges, caustic washes and sludges, or water washes and sludges
from cleaning tubs and equipment used in the formulation of ink from pigments, driers,
soaps, and stabilizers containing chromium and lead.
Acetone
67-64-1
0.28
160
Acetophenone
96-86-2
0.010
9.7
bis(2-Ethylhexyl) phthalate
117-81-7
0.28
28
n-Butyl alcohol
71-36-3
5.6
2.6
Butylbenzyl phthalate
85-68-7
0.017
28
Cyclohexanone
108-94-1
0.36
NA
o-Dichlorobenzene
95-50-1
0.088
6.0
Diethyl phthalate
84-66-2
0.20
28
562
Dimethyl phthalate
131-11-3
0.047
28
Di-n-butyl phthalate
84-74-2
0.057
28
Di-n-octyl phthalate
117-84-0
0.017
28
Ethyl acetate
141-78-6
0.34
33
Ethylbenzene
100-41-4
0.057
10
Methanol
67-56-1
5.6
NA
Methyl ethyl ketone
78-93-3
0.28
36
Methyl isobutyl ketone
108-10-1
0.14
33
Methylene chloride
75-09-2
0.089
30
Naphthalene
91-20-3
0.059
5.6
Nitrobenzene
98-95-3
0.068
14
Toluene
108-88-3
0.080
10
1,1,1-Trichloroethane
71-55-6
0.054
6.0
Trichloroethylene
79-01-6
0.054
6.0
Xylenes-mixed isomers
(sum of o-, m-, and p-xylene
concentrations)
1330-20-7
0.32
30
Chromium (Total)
7440-47-3
2.77
0.86 mg/l TCLP
Cyanides (Total)
7
57-12-5
1.2
590
Lead
7439-92-1
0.69
0.37 mg/l TCLP
K087
Decanter tank tar sludge from coking operations.
Acenaphthylene
208-96-8
0.059
3.4
Benzene
71-43-2
0.14
10
Chrysene
218-01-9
0.059
3.4
Fluoranthene
206-44-0
0.068
3.4
Indenol(1,2,3-cd)pyrene
193-39-5
0.0055
3.4
Naphthalene
91-20-3
0.059
5.6
Phenanthrene
85-01-8
0.059
5.6
Toluene
108-88-3
0.080
10
Xylenes-mixed isomers
(sum of o-, m-, and p-xylene
concentrations)
1330-20-7
0.32
30
Lead
7439-92-1
0.69
0.37 mg/l TCLP
K088
Spent potliners from primary aluminum reduction.
Acenaphthene
83-32-9
0.059
3.4
Anthracene
120-12-7
0.059
3.4
Benz(a)anthracene
56-55-3
0.059
3.4
Benzo(a)pyrene
50-32-8
0.061
3.4
Benzo(b)fluoranthene
205-99-2
0.11
6.8
Benzo(k)fluoranthene
207-08-9
0.11
6.8
Benzo(g,h,i)perylene
191-24-2
0.0055
1.8
563
Chrysene
218-01-9
0.059
3.4
Dibenz(a,h)anthracene
53-70-3
0.055
8.2
Fluoranthene
206-44-0
0.068
3.4
Indeno(1,2,3-c,d)pyrene
193-39-5
0.0055
3.4
Phenanthrene
85-01-8
0.059
5.6
Pyrene
129-00-0
0.067
8.2
Antimony
7440-36-0
1.9
2.1 mg/l TCLP
Arsenic
7440-38-2
1.4
5.0 mg/l TCLP
Barium
7440-39-3
1.2
7.6 mg/l TCLP
Beryllium
7440-41-7
0.82
0.014 mg/l
TCLP
Cadmium
7440-43-9
0.69
0.19 mg/l TCLP
Chromium (Total)
7440-47-3
2.77
0.86 mg/l TCLP
Lead
7439-92-1
0.69
0.37 mg/l TCLP
Mercury
7439-97-6
0.15
0.025 mg/l
TCLP
Nickel
7440-02-0
3.98
5.0 mg/l TCLP
Selenium
7782-49-2
0.82
0.16 mg/l TCLP
Silver
7440-22-4
0.43
0.30 mg/l TCLP
Cyanide (Total)
7
57-12-5
1.2
590
Cyanide (Amenable)
7
57-12-5
0.86
30
Fluoride
16984-48-8
35
48 mg/l TCLP
K093
Distillation light ends from the production of phthalic anhydride from ortho-xylene.
Phthalic anhydride
(measured as Phthalic acid
or Terephthalic acid)
100-21-0
0.055
28
Phthalic anhydride
(measured as Phthalic acid
or Terephthalic acid)
85-44-9
0.055
28
K094
Distillation bottoms from the production of phthalic anhydride from ortho-xylene.
Phthalic anhydride
(measured as Phthalic acid
or Terephthalic acid)
100-21-0
0.055
28
Phthalic anhydride
(measured as Phthalic acid
or Terephthalic acid)
85-44-9
0.055
28
K095
Distillation bottoms from the production of 1,1,1-trichloroethane.
Hexachloroethane
67-72-1
0.055
30
Pentachloroethane
76-01-7
0.055
6.0
564
1,1,1,2-Tetrachloroethane
630-20-6
0.057
6.0
1,1,2,2-Tetrachloroethane
79-34-6
0.057
6.0
Tetrachloroethylene
127-18-4
0.056
6.0
1,1,2-Trichloroethane
79-00-5
0.054
6.0
Trichloroethylene
79-01-6
0.054
6.0
K096
Heavy ends from the heavy ends column from the production of 1,1,1-trichloroethane.
m-Dichlorobenzene
541-73-1
0.036
6.0
Pentachloroethane
76-01-7
0.055
6.0
1,1,1,2-Tetrachloroethane
630-20-6
0.057
6.0
1,1,2,2-Tetrachloroethane
79-34-6
0.057
6.0
Tetrachloroethylene
127-18-4
0.056
6.0
1,2,4-Trichlorobenzene
120-82-1
0.055
19
1,1,2-Trichloroethane
79-00-5
0.054
6.0
Trichloroethylene
79-01-6
0.054
6.0
K097
Vacuum stripper discharge from the chlordane chlorinator in the production of
chlordane.
Chlordane (alpha and gamma
isomers)
57-74-9
0.0033
0.26
Heptachlor
76-44-8
0.0012
0.066
Heptachlor epoxide
1024-57-3
0.016
0.0680.066
Hexachlorocyclopentadiene
77-47-4
0.057
2.4
K098
Untreated process wastewater from the production of toxaphene.
Toxaphene
8001-35-2
0.0095
2.6
K099
Untreated wastewater from the production of 2,4-D.
2,4-Dichlorophenoxyacetic
acid
94-75-7
0.72
10
HxCDDs (All Hexachloro-
dibenzo-p-dioxins)
NA
0.000063
0.001
HxCDFs (All Hexachloro-
dibenzofurans)
NA
0.000063
0.001
PeCDDs (All Pentachloro-
dibenzo-p-dioxins)
NA
0.000063
0.001
PeCDFs (All Pentachloro-
dibenzofurans)
NA
0.000035
0.001
TCDDs (All Tetrachloro-
dibenzo-p-dioxins)
NA
0.000063
0.001
TCDFs (All Tetrachloro-
NA
0.000063
0.001
565
dibenzofurans)
K100
Waste leaching solution from acid leaching of emission control dust or sludge from
secondary lead smelting.
Cadmium
7440-43-9
0.69
0.19 mg/l TCLP
Chromium (Total)
7440-47-3
2.77
0.86 mg/l TCLP
Lead
7439-92-1
0.69
0.37 mg/l TCLP
K101
Distillation tar residues from the distillation of aniline-based compounds in the
production of veterinary pharmaceuticals from arsenic or organo-arsenic compounds.
o-Nitroaniline
88-74-4
0.27
14
Arsenic
7440-38-2
1.4
5.0 mg/l TCLP
Cadmium
7440-43-9
0.69
NA
Lead
7439-92-1
0.69
NA
Mercury
7439-97-6
0.15
NA
K102
Residue from the use of activated carbon for decolorization in the production of
veterinary pharmaceuticals from arsenic or organo-arsenic compounds.
o-Nitrophenol
88-75-5
0.028
13
Arsenic
7440-38-2
1.4
5.0 mg/l TCLP
Cadmium
7440-43-9
0.69
NA
Lead
7439-92-1
0.69
NA
Mercury
7439-97-6
0.15
NA
K103
Process residues from aniline extraction from the production of aniline.
Aniline
62-53-3
0.81
14
Benzene
71-43-2
0.14
10
2,4-Dinitrophenol
51-28-5
0.12
160
Nitrobenzene
98-95-3
0.068
14
Phenol
108-95-2
0.039
6.2
K104
Combined wastewater streams generated from nitrobenzene or aniline production.
Aniline
62-53-3
0.81
14
Benzene
71-43-2
0.14
10
2,4-Dinitrophenol
51-28-5
0.12
160
Nitrobenzene
98-95-3
0.068
14
Phenol
108-95-2
0.039
6.2
Cyanides (Total)
7
57-12-5
1.2
590
K105
566
Separated aqueous stream from the reactor product washing step in the production of
chlorobenzenes.
Benzene
71-43-2
0.14
10
Chlorobenzene
108-90-7
0.057
6.0
2-Chlorophenol
95-57-8
0.044
5.7
o-Dichlorobenzene
95-50-1
0.088
6.0
p-Dichlorobenzene
106-46-7
0.090
6.0
Phenol
108-95-2
0.039
6.2
2,4,5-Trichlorophenol
95-95-4
0.18
7.4
2,4,6-Trichlorophenol
88-06-2
0.035
7.4
K106
K106 (wastewater treatment sludge from the mercury cell process in chlorine
production) nonwastewaters that contain greater than or equal to 260 mg/kg total
mercury.
Mercury
7439-97-6
NA
RMERC
K106
K106 (wastewater treatment sludge from the mercury cell process in chlorine
production) nonwastewaters that contain less than 260 mg/kg total mercury that are
residues from RMERC.
Mercury
7439-97-6
NA
0.20 mg/l TCLP
K106
Other K106 nonwastewaters that contain less than 260 mg/kg total mercury and are not
residues from RMERC.
Mercury
7439-97-6
NA
0.025 mg/l
TCLP
K106
All K106 wastewaters.
Mercury
7439-97-6
0.15
NA
K107
Column bottoms from product separation from the production of 1,1-dimethylhydrazine
(UDMH) from carboxylic acid hydrazides.
NA
NA
INCINCMBST;
or CHOXD fb
CARBN; or
BIODG fb
CARBN
INCINCMBST
K108
567
Condensed column overheads from product separation and condensed reactor vent gases
from the production of 1,1-dimethylhydrazine (UDMH) from carboxylic acid
hydrazides.
NA
NA
INCINCMBST;
or CHOXD fb
CARBN; or
BIODG fb
CARBN
INCINCMBST
K109
Spent filter cartridges from product purification from the production of 1,1-dimethyl-
hydrazine (UDMH) from carboxylic acid hydrazides.
NA
NA
INCINCMBST;
or CHOXD fb
CARBN; or
BIODG fb
CARBN
INCINCMBST
K110
Condensed column overheads from intermediate separation from the production of 1,1-
dimethylhydrazine (UDMH) from carboxylic acid hydrazides.
NA
NA
INCINCMBST;
or CHOXD fb
CARBN; or
BIODG fb
CARBN
INCINCMBST
K111
Product washwaters from the production of dinitrotoluene via nitration of toluene
2,4-Dinitrotoluene
121-1-1
0.32
140
2,6-Dinitrotoluene
606-20-2
0.55
28
K112
Reaction by-product water from the drying column in the production of toluenediamine
via hydrogenation of dinitrotoluene.
NA
NA
INCINCMBST;
or CHOXD fb
CARBN; or
BIODG fb
CARBN
INCINCMBST
K113
Condensed liquid light ends from the purification of toluenediamine in the production
of toluenediamine via hydrogenation of dinitrotoluene.
NA
NA
CARBN; or
CMBST
568
INCINCMBST
K114
Vicinals from the purification of toluenediamine in the production of toluenediamine
via hydrogenation of dinitrotoluene.
NA
NA
CARBN; or
INCINCMBST
CMBST
K115
Heavy ends from the purification of toluenediamine in the production of toluenediamine
via hydrogenation of dinitrotoluene.
Nickel
7440-02-0
3.98
5.0 mg/l TCLP
NA
NA
CARBN; or
INCINCMBST
CMBST
K116
Organic condensate from the solvent recovery column in the production of toluene
diisocyanate via phosgenation of toluenediamine.
NA
NA
CARBN; or
INCINCMBST
CMBST
K117
Wastewater from the reactor vent gas scrubber in the production of ethylene dibromide
via bromination of ethene.
Methyl bromide (Bromo-
methane)
74-83-9
0.11
15
Chloroform
67-66-3
0.046
6.0
Ethylene dibromide (1,2-
Dibromoethane)
106-93-4
0.028
15
K118
Spent absorbent solids from purification of ethylene dibromide in the production of
ethylene dibromide via bromination of ethene.
Methyl bromide (Bromo-
methane)
74-83-9
0.11
15
Chloroform
67-66-3
0.046
6.0
Ethylene dibromide (1,2-
Dibromoethane)
106-93-4
0.028
15
K123
Process wastewater (including supernates, filtrates, and washwaters) from the
production of ethylenebisdithiocarbamic acid and its salts.
NA
NA
INCINCMBST;
or CHOXD fb
(BIODG or
INCINCMBST
569
CARBN)
K124
Reactor vent scrubber water from the production of ethylenebisdithiocarbamic acid and
its salts.
NA
NA
INCINCMBST;
or CHOXD fb
(BIODG or
CARBN)
INCINCMBST
K125
Filtration, evaporation, and centrifugation solids from the production of ethylenebis-
dithiocarbamic acid and its salts.
NA
NA
INCINCMBST;
or CHOXD fb
(BIODG or
CARBN)
INCINCMBST
K126
Baghouse dust and floor sweepings in milling and packaging operations from the
production or formulation of ethylenebisdithiocarbamic acid and its salts.
NA
NA
INCINCMBST;
or CHOXD fb
(BIODG or
CARBN)
INCINCMBST
K131
Wastewater from the reactor and spent sulfuric acid from the acid dryer from the
production of methyl bromide.
Methyl bromide (Bromo-
methane)
74-83-9
0.11
15
K132
Spent absorbent and wastewater separator solids from the production of methyl
bromide.
Methyl bromide (Bromo-
methane)
74-83-9
0.11
15
K136
Still bottoms from the purification of ethylene dibromide in the production of ethylene
dibromide via bromination of ethene.
Methyl bromide (Bromo-
methane)
74-83-9
0.11
15
Chloroform
67-66-3
0.046
6.0
Ethylene dibromide (1,2-
Dibromoethane)
106-93-4
0.028
15
570
K141
Process residues from the recovery of coal tar, including, but not limited to, collecting
sump residues from the production of coke or the recovery of coke by-products
produced from coal. This listing does not include K087 (decanter tank tar sludge from
coking operations).
Benzene
71-43-2
0.14
10
Benz(a)anthracene
56-55-3
0.059
3.4
Benzo(a)pyrene
50-2-8
0.061
3.4
Benzo(b)fluoranthene
(difficult to distinguish from
benzo(k)fluoranthene)
205-99-2
0.11
6.8
Benzo(k)fluoranthene
(difficult to distinguish from
benzo(b)fluoranthene)
207-08-9
0.11
6.8
Chrysene
218-01-9
0.059
3.4
Dibenz(a,h)anthracene
53-70-3
0.055
8.2
Indeno(1,2,3-cd)pyrene
193-39-5
0.0055
3.4
K142
Tar storage tank residues from the production of coke from coal or from the recovery
of coke by-products produced from coal.
Benzene
71-43-2
0.14
10
Benz(a)anthracene
56-55-3
0.059
3.4
Benzo(a)pyrene
50-32-8
0.061
3.4
Benzo(b)fluoranthene
(difficult to distinguish from
benzo(k)fluoranthene)
205-99-2
0.11
6.8
Benzo(k)fluoranthene
(difficult to distinguish from
benzo(b)fluoranthene)
207-08-9
0.11
6.8
Chrysene
218-01-9
0.059
3.4
Dibenz(a,h)anthracene
53-70-3
0.055
8.2
Ideno(1,2,3-cd)pyrene
193-39-5
0.0055
3.4
K143
Process residues from the recovery of light oil, including, but not limited to, those
generated in stills, decanters, and wash oil recovery units from the recovery of coke
by-products produced from coal.
Benzene
71-43-2
0.14
10
Benz(a)anthracene
56-55-3
0.059
3.4
Benzo(a)pyrene
50-32-8
0.061
3.4
Benzo(b)fluoranthene
(difficult to distinguish from
benzo(k)fluoranthene)
205-99-2
0.11
6.8
571
Benzo(k)fluoranthene
(difficult to distinguish from
benzo(b)fluoranthene)
207-08-9
0.11
6.8
Chrysene
218-01-9
0.059
3.4
K144
Wastewater sump residues from light oil refining, including, but not limited to,
intercepting or contamination sump sludges from the recovery of coke by-products
produced from coal.
Benzene
71-43-2
0.14
10
Benz(a)anthracene
56-55-3
0.059
3.4
Benzo(a)pyrene
50-32-8
0.061
3.4
Benzo(b)fluoranthene
(difficult to distinguish from
benzo(k)fluoranthene)
205-99-2
0.11
6.8
Benzo(k)fluoranthene
(difficult to distinguish from
benzo(b)fluoranthene)
207-08-9
0.11
6.8
Chrysene
218-01-9
0.059
3.4
Dibenz(a,h)anthracene
53-70-3
0.055
8.2
K145
Residues from naphthalene collection and recovery operations from the recovery of
coke by-products produced from coal.
Benzene
71-43-2
0.14
10
Benz(a)anthracene
56-55-3
0.059
3.4
Benzo(a)pyrene
50-32-8
0.061
3.4
Chrysene
218-01-9
0.059
3.4
Dibenz(a,h)anthracene
53-70-3
0.055
6.28.2
Naphthalene
91-20-3
0.059
5.6
K147
Tar storage tank residues from coal tar refining.
Benzene
71-43-2
0.14
10
Benz(a)anthracene
56-55-3
0.059
3.4
Benzo(a)pyrene
50-32-8
0.061
3.4
Benzo(b)fluoranthene
(difficult to distinguish from
benzo(k)fluoranthene)
205-99-2
0.11
6.8
Benzo(k)fluoranthene
(difficult to distinguish from
benzo(b)fluoranthene)
207-08-9
0.11
6.8
Chrysene
218-01-9
0.059
3.4
Dibenz(a,h)anthracene
53-70-3
0.055
8.2
Indeno(1,2,3-cd)pyrene
193-39-5
0.0055
3.4
572
K148
Residues from coal tar distillation, including, but not limited to, still bottoms.
Benz(a)anthracene
56-55-3
0.059
3.4
Benzo(a)pyrene
50-32-8
0.061
3.4
Benzo(b)fluoranthene
(difficult to distinguish from
benzo(k)fluoranthene)
205-99-2
0.11
6.8
Benzo(k)fluoranthene
(difficult to distinguish from
benzo(b)fluoranthene)
207-08-9
0.11
6.8
Chrysene
218-01-9
0.059
3.4
Dibenz(a,h)anthracene
53-70-3
0.055
8.2
Indeno(1,2,3-cd)pyrene
193-39-5
0.0055
3.4
K149
Distillation bottoms from the production of alpha- (or methyl-) chlorinated toluenes,
ring-chlorinated toluenes, benzoyl chlorides, and compounds with mixtures of these
functional groups. (This waste does not include still bottoms from the distillations of
benzyl chloride.)
Chlorobenzene
108-90-7
0.057
6.0
Chloroform
67-66-3
0.046
6.0
Chloromethane
74-87-3
0.19
30
p-Dichlorobenzene
106-46-7
0.090
6.0
Hexachlorobenzene
118-74-1
0.055
10
Pentachlorobenzene
608-93-5
0.055
10
1,2,4,5-Tetrachlorobenzene
95-94-3
0.055
14
Toluene
108-88-3
0.080
10
K150
Organic residuals, excluding spent carbon adsorbent, from the spent chlorine gas and
hydrochloric acid recovery processes associated with the production of alpha- (or
methyl-) chlorinated toluenes, ring-chlorinated toluenes, benzoyl chlorides, and
compounds with mixtures of these functional groups.
Carbon tetrachloride
56-23-5
0.057
6.0
Chloroform
67-66-3
0.046
6.0
Chloromethane
74-87-3
0.19
30
p-Dichlorobenzene
106-46-7
0.090
6.0
Hexachlorobenzene
118-74-1
0.055
10
Pentachlorobenzene
608-93-5
0.055
10
1,2,4,5-Tetrachlorobenzene
95-94-3
0.055
14
1,1,2,2- Tetrachloroethane
79-34-5
0.057
6.0
Tetrachloroethylene
127-18-4
0.056
6.0
1,2,4-Trichlorobenzene
120-82-1
0.055
19
573
K151
Wastewater treatment sludges, excluding neutralization and biological sludges,
generated during the treatment of wastewaters from the production of alpha- (or
methyl-) chlorinated toluenes, ring-chlorinated toluenes, benzoyl chlorides, and
compounds with mixtures of these functional groups.
Benzene
71-43-2
0.14
10
Carbon tetrachloride
56-23-5
0.057
6.0
Chloroform
67-66-3
0.046
6.0
Hexachlorobenzene
118-74-1
0.055
10
Pentachlorobenzene
608-93-5
0.055
10
1,2,4,5-Tetrachlorobenzene
95-94-3
0.055
14
Tetrachloroethylene
127-18-4
0.056
6.0
Toluene
108-88-3
0.080
10
K156
Organic waste (including heavy ends, still bottoms, light ends, spent solvents, filtrates,
and decantates) from the production of carbamates and carbamoyl oximes. (This listing
does not apply to wastes generated from the manufacture of 3-iodo-2-propyl-n-
butylcarbamate.)
10
Acetonitrile
75-05-8
5.6
38
Acetophenone
96-86-2
0.010
9.7
Aniline
62-53-3
0.81
14
Benomyl
17804-35-2
0.056
1.4
Benzene
71-43-2
0.14
10
Carbaryl
63-25-21
0.006
0.14
Carbenzadim
10605-21-7
0.056
1.4
Carbofuran
1563-66-2
0.006
0.14
Carbosulfan
55285-14-8
0.028
1.4
Chlorobenzene
108-90-7
0.057
6.0
Chloroform
67-66-3
0.046
6.0
o-Dichlorobenzene
95-50-1
0.088
6.0
Methomyl
16752-77-5
0.028
0.14
Methylene chloride
75-09-2
0.089
30
Methyl ethyl ketone
78-93-3
0.28
36
Naphthalene
91-20-3
0.059
5.6
Phenol
108-95-2
0.039
6.2
Pyridine
110-86-1
0.014
16
Toluene
108-88-3
0.080
10
Triethylamine
121-44-8
0.081
1.5
K157
Wastewaters (including scrubber waters, condenser waters, washwaters, and separation
waters) from the production of carbamates and carbamoyl oximes. (This listing does
not apply to wastes generated from the manufacture of 3-iodo-2-propyl-n-
butylcarbamate.)
10
574
Carbon tetrachloride
56-23-5
0.057
6.0
Chloroform
67-66-3
0.046
6.0
Chloromethane
74-87-3
0.19
30
Methomyl
16752-77-5
0.028
0.14
Methylene chloride
75-09-2
0.089
30
Methyl ethyl ketone
78-93-3
0.28
36
o-Phenylenediamine
95-54-5
0.056
5.6
Pyridine
110-86-1
0.014
16
Triethylamine
121-44-8
0.081
1.5
K158
Baghouse dusts and filter/separation solids from the production of carbamates and
carbamoyl oximes. (This listing does not apply to wastes generated from the
manufacture of 3-iodo-2-propyl-n-butylcarbamate.)
10
Benomyl
17804-35-2
0.056
1.4
Benzene
71-43-2
0.14
10
Carbenzadim
10605-21-7
0.056
1.4
Carbofuran
1563-66-2
0.006
0.14
Carbosulfan
55285-14-8
0.028
1.4
Chloroform
67-66-3
0.046
6.0
Methylene chloride
75-09-2
0.089
30
Phenol
108-95-2
0.039
6.2
K159
Organics from the treatment of thiocarbamate wastes.
10
Benzene
71-43-2
0.14
10
Butylate
2008-41-5
0.042
1.4
EPTC (Eptam)
759-94-4
0.042
1.4
Molinate
2212-67-1
0.042
1.4
Pebulate
1114-71-2
0.042
1.4
Vernolate
1929-77-7
0.042
1.4
K161
Purification solids (including filtration, evaporation, and centrifugation solids),
baghouse dust and floor sweepings from the production of dithiocarbamate acids and
their salts.
10
Antimony
7440-36-0
1.9
2.1 mg/l TCLP
Arsenic
7440-38-2
1.9
5.0 mg/l TCLP
Carbon disulfide
75-15-0
3.8
4.8 mg/l TCLP
Dithiocarbamates (total)
NA
0.028
28
Lead
7439-92-1
0.69
0.37 mg/l TCLP
Nickel
7440-02-0
3.98
5.0 mg/l TCLP
Selenium
7782-49-2
0.82
0.16 mg/l TCLP
P001
Warfarin, & salts, when present at concentrations greater than 0.3%
575
Warfarin
81-81-2
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
CMBST
P002
1-Acetyl-2-thiourea
1-Acetyl-2-thiourea
591-08-2
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
P003
Acrolein
Acrolein
107-02-6107-02-
8
0.29
CMBST
P004
Aldrin
Aldrin
309-00-2
0.021
0.0680.066
P005
Allyl alcohol
Allyl alcohol
107-18-6
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
CMBST
P006
Aluminum phosphide
Aluminum phosphide
20859-73-
620859-73-8
CHOXD;
CHRED; or
INCINCMBST
CHOXD;
CHRED; or
INCINCMBST
P007
5-Aminomethyl-3-isoxazolol
5-Aminomethyl-3-isoxazolol
2763-96-4
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
P008
4-Aminopyridine
4-Aminopyridine
504-24-5
(WETOX or
CHOXD) fb
INCINCMBST
576
CARBN; or
INCINCMBST
P009
Ammonium picrate
Ammonium picrate
131-74-8
CHOXD;
CHRED;
CARBN;
BIODG; or
INCINCMBST
CHOXD;
CHRED; or
CMBST
P010
Arsenic acid
Arsenic
7440-38-2
1.4
5.0 mg/l TCLP
P011
Arsenic pentoxide
Arsenic
7440-38-2
1.4
5.0 mg/l TCLP
P012
Arsenic trioxide
Arsenic
7440-38-2
1.4
5.0 mg/l TCLP
P013
Barium cyanide
Barium
7440-39-3
NA
7.6 mg/l TCLP
Cyanides (Total)
7
57-12-5
1.2
590
Cyanides (Amenable)
7
57-12-5
0.86
30
P014
Thiophenol (Benzene thiol)
Thiophenol (Benzene thiol)
108-98-5
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
P015
Beryllium dust
Beryllium
7440-41-7
RMETL;or
RTHRM
RMETL; or
RTHRM
P016
Dichloromethyl ether (Bis(chloromethyl)ether)
Dichloromethyl ether
542-88-1
(WETOX or
CHOXD) fb
INCINCMBST
577
CARBN; or
INCINCMBST
P017
Bromoacetone
Bromoacetone
598-31-2
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
P018
Brucine
Brucine
357-57-3
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
P020
2-sec-Butyl-4,6-dinitrophenol (Dinoseb)
2-sec-Butyl-4,6-dinitro-
phenol (Dinoseb)
88-85-7
0.066
2.5
P021
Calcium cyanide
Cyanides (Total)
7
57-12-5
1.2
590
Cyanides (Amenable)
7
57-12-5
0.86
30
P022
Carbon disulfide
Carbon disulfide
75-15-0
3.8
INCINCMBST
Carbon disulfide; alternate
6
standard for nonwastewaters
only
75-15-0
NA
4.8 mg/l TCLP
P023
Chloroacetaldehyde
Chloroacetaldehyde
107-20-0
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
P024
p-Chloroaniline
p-Chloroaniline
106-47-8
0.46
16
578
P026
1-(o-Chlorophenyl)thiourea
1-(o-Chlorophenyl)thiourea
5344-82-1
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
P027
3-Chloropropionitrile
3-Chloropropionitrile
542-76-7
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
P028
Benzyl chloride
Benzyl chloride
100-44-7
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
P029
Copper cyanide
Cyanides (Total)
7
57-12-5
1.2
590
Cyanides (Amenable)
7
57-12-5
0.86
30
P030
Cyanides (soluble salts and complexes)
Cyanides (Total)
7
57-12-5
1.2
590
Cyanides (Amenable)
7
57-12-5
0.86
30
P031
Cyanogen
Cyanogen
460-19-5
CHOXD;
WETOX; or
INCINCMBST
CHOXD;
WETOX; or
INCINCMBST
P033
Cyanogen chloride
Cyanogen chloride
506-77-4
CHOXD;
WETOX; or
INCINCMBST
CHOXD;
WETOX; or
INCINCMBST
P034
2-Cyclohexyl-4,6-dinitrophenol
579
2-Cyclohexyl-4,6-dinitro-
phenol
131-89-5
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
P036
Dichlorophenylarsine
Arsenic
7440-38-2
1.4
5.0 mg/l TCLP
P037
Dieldrin
Dieldrin
60-57-1
0.017
0.13
P038
Diethylarsine
Arsenic
7440-38-2
1.4
5.0 mg/l TCLP
P039
Disulfoton
Disulfoton
298-04-4
0.017
6.2
P040
O,O-Diethyl-O-pyrazinyl-phosphorothioate
O,O-Diethyl-O-pyrazinyl-
phosphorothioate
297-97-2
CARBN; or
INCINCMBST
CMBST
P041
Diethyl-p-nitrophenyl phosphate
Diethyl-p-nitrophenyl
phosphate
311-45-5
CARBN; or
INCINCMBST
CMBST
P042
Epinephrine
Epinephrine
51-43-4
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
P043
Diisopropylfluorophosphate (DFP)
Diisopropylfluorophosphate
(DFP)
55-91-4
CARBN; or
INCINCMBST
CMBST
P044
Dimethoate
580
Dimethoate
60-51-5
CARBN; or
INCINCMBST
CMBST
P045
Thiofanox
Thiofanox
39196-18-4
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
P046
alpha,alpha-Dimethylphenethylamine
alpha,alpha-Dimethyl-
phenethylamine
122-09-8
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
P047
4,6-Dinitro-o-cresol
4,6-Dinitro-o-cresol
543-52-1
0.28
160
P047
4,6-Dinitro-o-cresol salts
NA
NA
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
P048
2,4-Dinitrophenol
2,4-Dinitrophenol
51-28-5
0.12
160
P049
Dithiobiuret
Dithiobiuret
541-53-7
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
P050
Endosulfan
Endosulfan I
939-98-8
0.023
0.066
Endosulfan II
33213-6-5
0.029
0.13
Endosulfan sulfate
1031-07-8
0.029
0.13
581
P051
Endrin
Endrin
72-20-8
0.0028
0.13
Endrin aldehyde
7421-93-4
0.025
0.13
P054
Aziridine
Aziridine
151-56-4
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
P056
Fluorine
Fluoride (measured in
wastewaters only)
16964-48-8
35
ADGAS fb
NEUTR
P057
Fluoroacetamide
Fluoroacetamide
640-19-7
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
P058
Fluoroacetic acid, sodium salt
Fluoroacetic acid, sodium
salt
62-74-8
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
P059
Heptachlor
Heptachlor
76-44-8
0.0012
0.066
Heptachlor epoxide
1024-57-3
0.016
0.066
P060
Isodrin
Isodrin
465-73-6
0.021
0.066
P062
Hexaethyl tetraphosphate
Hexaethyl tetraphosphate
757-58-4
CARBN; or
INCINCMBST
CMBST
582
P063
Hydrogen cyanide
Cyanides (Total)
7
57-12-5
1.2
590
Cyanides (Amenable)
7
57-12-5
0.86
30
P064
Isocyanic acid, ethyl ester
Isocyanic acid, ethyl ester
624-83-9
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
P065
P065 (mercury fulminate) nonwastewaters, regardless of their total mercury
contantcontent, that are not incinerator residues or are not residues from RMERC.
Mercury
7439-97-6
NA
IMERC
P065
P065 (mercury fulminate) nonwastewaters that are either incinerator residues or are
residues from RMERC; and contain greater than or equal to 260 mg/kg total mercury.
Mercury
7339-97-6
NA
RMERC
P065
P065 (mercury fulminate) nonwastewaters that are residues from RMERC and contain
less than 260 mg/kg total mercury.
Mercury
7439-97-6
NA
0.20 mg/l TCLP
P065
P065 (mercury fulminate) nonwastewaters that are incinerator residues and contain less
than 260 mg/kg total mercury.
Mercury
7439-97-6
NA
0.025 mg/l
TCLP
P065
All P065 (mercury fulminate) wastewaters.
Mercury
7439-97-6
0.15
NA
P066
Methomyl
Methomyl
16752-77-5
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
P067
583
2-Methyl-aziridine
2-Methyl-aziridine
75-55-8
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
P068
Methyl hydrazine
Methyl hydrazine
60-34-4
CHOXD;
CHRED;
CARBN;
BIODG; or
INCINCMBST
CHOXD;
CHRED, or
CMBST
P069
2-Methyllactonitrile
2-Methyllactonitrile
75-86-5
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
P070
Aldicarb
Aldicarb
116-06-3
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
P071
Methyl parathion
Methyl parathion
298-00-0
0.014
4.6
P072
1-Naphthyl-2-thiourea
1-Naphthyl-2-thiourea
86-88-4
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
P073
Nickel carbonyl
Nickel
7440-02-0
3.98
5.0 mg/l TCLP
P074
Nickel cyanide
584
Cyanides (Total)
7
57-12-5
1.2
590
Cyanides (Amenable)
7
57-12-5
0.86
30
Nickel
7440-02-0
3.98
5.0 mg/l TCLP
P075
Nicotine and salts
Nicotine and salts
54-11-5
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
P076
Nitric oxide
Nitric oxide
10102-43-9
ADGAS
ADGAS
P077
p-Nitroaniline
p-Nitroaniline
100-01-6
0.028
28
P078
Nitrogen dioxide
Nitrogen dioxide
10102-44-0
ADGAS
ADGAS
P081
Nitroglycerin
Nitroglycerin
55-63-0
CHOXD;
CHRED;
CARBN; BIODG
or
INCINCMBST
CHOXD;
CHRED; or
CMBST
P082
N-Nitrosodimethylamine
N-Nitrosodimethylamine
62-75-9
0.40
2.3
P084
N-Nitrosomethylvinylamine
N-Nitrosomethylvinylamine
4549-40-0
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
P085
Octamethylpyrophosphoramide
Octamethylpyrophosphor-
152-16-9
CARBN; or
CMBST
585
amide
INCINCMBST
P087
Osmium tetroxide
Osmium tetroxide
20816-12-0
RMETL; or
RTHRM
RMETL; or
RTHRM
P088
Endothall
Endothall
145-73-3
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
CMBST
P089
Parathion
Parathion
56-38-2
0.014
4.6
P092
P092 (phenyl mercuric acetate) nonwastewaters, regardless of their total mercury
content, that are not incinerator residues or are not residues from RMERC.
Mercury
7439-97-6
NA
IMERC; or
RMERC
P092
P092 (phenyl mercuric acetate) nonwastewaters that are either incinerator residues or
are residues from RMERC; and still contain greater than or equal to 260 mg/kg total
mercury.
Mercury
7439-97-6
NA
RMERC
P092
P092 (phenyl mercuric acetate) nonwastewaters that are residues from RMERC and
contain less than 260 mg/kg total mercury.
Mercury
7439-97-6
NA
0.20 mg/l TCLP
P092
P092 (phenyl mercuric acetate) nonwastewaters that are incinerator residues and contain
less than 260 mg/kg total mercury.
Mercury
7439-97-6
NA
0.025 mg/l
TCLP
P092
All P092 (phenyl mercuric acetate) wastewaters.
Mercury
7439-97-6
0.15
NA
586
P093
Phenylthiourea
Phenylthiourea
103-85-5
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
P094
Phorate
Phorate
298-02-2
0.021
4.6
P095
Phosgene
Phosgene
75-44-5
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
P096
Phosphine
Phosphine
7803-51-2
CHOXD;
CHRED; or
INCINCMBST
CHOXD;
CHRED; or
INCINCMBST
P097
Famphur
Famphur
52-85-7
0.017
15
P098
Potassium cyanide.
Cyanides (Total)
7
57-12-5
1.2
590
Cyanides (Amenable)
7
57-12-5
0.86
30
P099
Potassium silver cyanide
Cyanides (Total)
7
57-12-5
1.2
590
Cyanides (Amenable)
7
57-12-5
0.86
30
Silver
7440-22-4
0.43
0.30 mg/l TCLP
P101
Ethyl cyanide (Propanenitrile)
Ethyl cyanide
(Propanenitrile)
107-12-0
0.24
360
P102
587
Propargyl alcohol
Propargyl alcohol
107-19-7
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
CMBST
P103
Selenourea
Selenium
7782-49-2
0.82
0.16 mg/l TCLP
P104
Silver cyanide
Cyanides (Total)
7
57-12-5
1.2
590
Cyanides (Amenable)
7
57-12-5
0.86
30
Silver
7440-22-4
0.43
0.30 mg/l TCLP
P105
Sodium azide
Sodium azide
26628-22-8
CHOXD;
CHRED;
CARBN;
BIODG; or
INCINCMBST
CHOXD;
CHRED; or
CMBST
P106
Sodium cyanide
Cyanides (Total)
7
57-12-5
1.2
590
Cyanides (Amenable)
7
57-12-5
0.86
30
P108
Strychnine and salts
Strychnine and salts
57-24-9
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
P109
Tetraethyldithiopyrophosphate
Tetraethyldithiopyro-
phosphate
3689-24-5
CARBN; or
INCINCMBST
CMBST
P110
Tetraethyl lead
leadLead
7439-92-1
0.69
0.37 mg/l TCLP
588
P111
Tetraethylpyrophosphate
Tetraethylpyrophosphate
107-49-3
CARBN; or
INCINCMBST
CMBST
P112
Tetranitromethane
Tetranitromethane
509-14-8
CHOXD;
CHRED;
CARBN;
BIODG; or
INCINCMBST
CHOXD;
CHRED; or
CMBST
P113
Thallic oxide
Thallium (measured in
wastewaters only)
7440-28-0
1.4
RTHRM; or
STABL
P114
Thallium selenite
Selenium
7782-49-2
0.82
0.16 mg/l TCLP
P115
Thallium (I) sulfate
Thallium (measured in
wastewaters only)
7440-28-0
1.4
RTHRM; or
STABL
P116
Thiosemicarbazide
Thiosemicarbazide
79-19-6
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
P118
Trichloromethanethiol
Trichloromethanethiol
75-70-7
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
P119
Ammonium vanadate
Vanadium (measured in
wastewaters only)
7440-62-2
4.3
STABL
589
P120
Vanadium pentoxide
Vanadium (measured in
wastewaters only)
7440-62-2
4.3
STABL
P121
Zinc cyanide
Cyanides (Total)
7
57-12-5
1.2
590
Cyanides (Amenable)
7
57-12-5
0.86
30
P122
Zinc phosphide Zn
3
P
2
, when present at concentrations greater than 10%
Zinc Phosphide
1314-84-7
CHOXD;
CHRED; or
INCINCMBST
CHOXD;
CHRED; or
INCINCMBST
P123
Toxaphene
Toxaphene
8001-35-2
0.0095
2.6
P127
Carbofuran
10
Carbofuran
1563-66-2
0.006
0.14
P128
Mexacarbate
10
Mexacarbate
315-18-4
0.056
1.4
P185
Tirpate
10
Tirpate
26419-73-8
0.056
0.28
P188
Physostigimine salicylate
10
Physostigmine salicylate
57-64-7
0.056
1.4
P189
Carbosulfan
10
Carbosulfan
55285-14-8
0.028
1.4
P190
Metolcarb
10
Metolcarb
1129-41-5
0.056
1.4
P191
590
Dimetilan
10
Dimetilan
644-64-4
0.056
1.4
P192
Isolan
10
Isolan
119-38-0
0.056
1.4
P194
Oxamyl
10
Oxamyl
23135-22-0
0.056
0.28
P196
Manganese dimethyldithiocarbamates (total)
10
Dithiocarbamates (total)
NA
0.028
28
P197
Formparanate
10
Formparanate
17702-57-7
0.056
1.4
P198
Formetanate hydrochloride
10
Formetanate hydrochloride
23422-53-9
0.056
1.4
P199
Methiocarb
10
Methiocarb
2032-65-7
0.056
1.4
P201
Promecarb
10
Promecarb
2631-37-0
0.056
1.4
P202
m-Cumenyl methylcarbamate
10
m-Cumenyl methylcarbamate
64-00-6
0.056
1.4
P203
Aldicarb sulfone
10
Aldicarb sulfone
1646-88-4
0.056
0.28
P204
Physostigmine
10
Physostigmine
57-47-6
0.056
1.4
P205
Ziram
10
591
Dithiocarbamates (total)
NA
0.028
28
U001
Acetaldehyde
Acetaldehyde
75-07-0
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
CMBST
U002
Acetone
Acetone
67-64-1
0.28
160
U003
Acetonitrile
Acetonitrile
75-05-8
5.6
INCINCMBST
Acetonitrile; alternate
6
standard for nonwastewaters
only
75-05-8
NA
1.838
U004
Acetophenone
Acetophenone
98-86-2
0.010
9.7
U005
2-Acetylaminofluorene
2-Acetylaminofluorene
53-96-3
0.059
140
U006
Acetyl chloride
Acetyl chloride
75-36-5
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U007
Acrylamide
Acrylamide
79-06-1
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U008
Acrylic acid
Acrylic acid
79-10-7
(WETOX or
CMBST
592
CHOXD) fb
CARBN; or
INCINCMBST
U009
Acrylonitrile
Acrylonitrile
107-13-1
0.24
84
U010
Mitomycin C
Mitomycin C
50-07-7
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U011
Amitrole
Amitrole
61-82-5
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U012
Aniline
Aniline
62-53-3
0.81
14
U014
Auramine
Auramine
492-80-8
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U015
Azaserine
Azaserine
115-02-6
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U016
Benz(c)acridine
Benz(c)acridine
225-51-4
(WETOX or
CHOXD) fb
CARBN; or
CMBST
593
INCINCMBST
U017
Benzal chloride
Benzal chloride
98-87-3
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U018
Benz(a)anthracene
Benz(a)anthracene
56-55-3
0.059
3.4
U019
Benzene
Benzene
71-43-2
0.14
10
U020
Benzenesulfonyl chloride
Benzenesulfonyl chloride
98-09-9
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U021
Benzidine
Benzidine
92-87-5
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U022
Benzo(a)pyrene
Benzo(a)pyrene
50-32-8
0.061
3.4
U023
Benzotrichloride
Benzotrichloride
98-07-7
CHOXD;
CHRED;
CARBN;
BIODG; or
INCINCMBST
CHOXD;
CHRED; or
CMBST
U024
bis(2-Chloroethoxy)methane
594
bis(2-Chloroethoxy)methane
111-91-1
0.036
7.2
U025
bis(2-Chloroethyl)ether
bis(2-Chloroethyl)ether
111-44-4
0.033
6.0
U026
Chlornaphazine
Chlornaphazine
494-03-1
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U027
bis(2-Chloroisopropyl)ether
bis(2-Chloroisopropyl)ether
108-60-139638-
32-9
0.055
7.2
U028
bis(2-Ethylhexyl)phthalate
bis(2-Ethylhexyl)phthalate
117-81-7
0.28
28
U029
Methyl bromide (Bromomethane)
Methyl bromide (Bromo-
methane)
74-83-9
0.11
15
U030
4-Bromophenyl phenyl ether
4-Bromophenyl phenyl ether
101-55-3
0.055
15
U031
n-Butyl alcohol
n-Butyl alcohol
71-36-3
5.6
2.6
U032
Calcium chromate
Chromium (Total)
7440-47-3
2.77
0.86 mg/l TCLP
U033
Carbon oxyfluoride
Carbon oxyfluoride
353-50-4
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
595
U034
Trichloroacetaldehyde (Chloral)
Trichloroacetaldehyde
(Chloral)
75-87-6
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U035
Chlorambucil
Chlorambucil
305-03-3
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U036
Chlordane
Chlordane (alpha and gamma
isomers)
57-74-9
0.0033
0.26
U037
Chlorobenzene
Chlorobenzene
108-90-7
0.057
6.0
U038
Chlorobenzilate
Chlorobenzilate
510-15-6
0.10
INCINCMBST
U039
p-Chloro-m-cresol
p-Chloro-m-cresol
59-50-7
0.018
14
U041
Epichlorohydrin (1-Chloro-2,3-epoxypropane)
Epichlorohydrin (1-Chloro-
2,3-epoxypropane)
106-89-8
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U042
2-Chloroethyl vinyl ether
2-Chloroethyl vinyl ether
110-75-8
0.062
INCINCMBST
U043
Vinyl chloride
Vinyl chloride
75-01-4
0.27
6.0
596
U044
Chloroform
Chloroform
67-66-3
0.046
6.0
U045
Chloromethane (Methyl chloride)
Chloromethane (Methyl
chloride)
74-87-3
0.19
30
U046
Chloromethyl methyl ether
Chloromethyl methyl ether
107-30-2
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U047
2-Chloronaphthalene
2-Chloronaphthalene
91-58-7
0.055
5.6
U048
2-Chlorophenol
2-Chlorophenol
95-57-8
0.044
5.7
U049
4-Chloro-o-toluidine hydrochloride
4-Chloro-o-toluidine hydro-
chloride
3165-93-3
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U050
Chrysene
Chrysene
218-01-9
0.059
3.4
U051
Creosote
Naphthalene
91-20-3
0.059
5.6
Pentachlorophenol
87-86-5
0.089
7.4
Phenanthrene
85-01-8
0.059
5.6
Pyrene
129-00-0
0.067
8.2
Toluene
108-88-3
0.080
10
Xylenes-mixed isomers
(sum of o-, m-, and p-xylene
1330-20-7
0.32
30
597
concentrations)
Lead
7439-92-1
0.69
0.37 mg/l TCLP
U052
Cresols (Cresylic acid)
o-Cresol
95-48-7
0.11
5.6
m-Cresol (difficult to
distinguish from p-cresol)
108-39-4
0.77
5.6
p-Cresol (difficult to
distinguish from m-cresol)
106-44-5
0.77
5.6
Cresol-mixed isomers
(Cresylic acid)
(sum of o-, m-, and p-cresol
concentrations)
1319-77-3
0.88
11.2
U053
Crotonaldehyde
Crotonaldehyde
4170-30-3
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
CMBST
U055
Cumene
Cumene
98-82-8
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
CMBST
U056
Cyclohexane
Cyclohexane
110-82-7
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
CMBST
U057
Cyclohexanone
Cyclohexanone
108-94-1
0.36
CMBST
Cyclohexanone; alternate
6
standard for nonwastewaters
only
108-94-1
NA
0.75 mg/l TCLP
U058
Cyclophosphamide
Cyclophosphamide
50-18-0
CARBN; or
CMBST
598
INCINCMBST
U059
Daunomycin
Daunomycin
20830-81-3
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U060
DDD
o,p'-DDD
53-19-0
0.023
0.087
p,p'-DDD
72-54-8
0.023
0.087
U061
DDT
o,p'-DDT
789-02-6
0.0039
0.087
p,p'-DDT
50-29-3
0.0039
0.087
o,p'-DDD
53-19-0
0.023
0.087
p,p'-DDD
72-54-8
0.023
0.087
o,p'-DDE
3424-82-6
0.031
0.087
p,p'-DDE
72-55-9
0.031
0.087
U062
Diallate
Diallate
2303-16-4
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U063
Dibenz(a,h)anthracene
Dibenz(a,h)anthracene
53-70-3
0.055
8.2
U064
Dibenz(a,i)pyrene
Dibenz(a,i)pyrene
189-55-9
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
CMBST
U066
1,2-Dibromo-3-chloropropane
1,2-Dibromo-3-chloro-
propane
96-12-8
0.11
15
599
U067
Ethylene dibromide (1,2-Dibromoethane)
Ethylene dibromide (1,2-
Dibromoethane)
106-93-4
0.028
15
U068
Dibromomethane
Dibromomethane
74-95-3
0.11
15
U069
Di-n-butyl phthalate
Di-n-butyl phthalate
84-74-2
0.057
28
U070
o-Dichlorobenzene
o-Dichlorobenzene
95-50-1
0.088
6.0
U071
m-Dichlorobenzene
m-Dichlorobenzene
541-73-1
0.036
6.0
U072
p-Dichlorobenzene
p-Dichlorobenzene
106-46-7
0.090
6.0
U073
3,3'-Dichlorobenzidine
3,3'-Dichlorobenzidine
91-94-1
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U074
1,4-Dichloro-2-butene
cis-1,4-Dichloro-2-butene
1476-11-5
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
trans-1,4-Dichloro-2-butene
764-41-0
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U075
600
Dichlorodifluoromethane
Dichlorodifluoromethane
75-71-8
0.23
7.2
U076
1,1-Dichloroethane
1,1-Dichloroethane
75-34-3
0.059
6.0
U077
1,2-Dichloroethane
1,2-Dichloroethane
107-06-2
0.21
6.0
U078
1,1-Dichloroethylene
1,1-Dichloroethylene
75-35-4
0.025
6.0
U079
1,2-Dichloroethylene
trans-1,2-Dichloroethylene
156-60-5
0.054
30
U080
Methylene chloride
Methylene chloride
75-09-2
0.089
30
U081
2,4-Dichlorophenol
2,4-Dichlorophenol
120-83-2
0.044
14
U082
2,6-Dichlorophenol
2,6-Dichlorophenol
87-65-0
0.044
14
U083
1,2-Dichloropropane
1,2-Dichloropropane
78-87-5
0.85
18
U084
1,3-Dichloropropylene
cis-1,3-Dichloropropylene
10061-01-5
0.036
18
trans-1,3-Dichloropropylene
10061-02-6
0.036
18
U085
1,2:3,4-Diepoxybutane
1,2:3,4-Diepoxybutane
1464-53-5
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
CMBST
601
U086
N,N'-Diethylhydrazine
N,N'-Diethylhydrazine
1615-80-1
CHOXD;
CHRED;
CARBN;
BIODG; or
INCINCMBST
CHOXD;
CHRED; or
CMBST
U087
O,O-Diethyl-S-methyldithiophosphate
O,O-Diethyl-S-methyldithio-
phosphate
3288-58-2
CARBN; or
INCINCMBST
CMBST
U088
Diethyl phthalate
Diethyl phthalate
84-66-2
0.20
28
U089
Diethyl stilbestrol
Diethyl stilbestrol
56-53-1
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
CMBST
U090
Dihydrosafrole
Dihydrosafrole
94-58-6
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
CMBST
U091
3,3'-Dimethoxybenzidine
3,3'-Dimethoxybenzidine
119-90-4
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U092
Dimethylamine
Dimethylamine
124-40-3
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
602
U093
p-Dimethylaminoazobenzene
p-Dimethylaminoazobenzene
60-11-7
0.13
INCINCMBST
U094
7,12-Dimethylbenz(a)anthracene
7,12-Dimethylbenz(a)-
anthracene
57-97-6
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
CMBST
U095
3,3'-Dimethylbenzidine
3,3'-Dimethylbenzidine
119-93-7
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U096
alpha, alpha-Dimethyl benzyl hydroperoxide
alpha, alpha-Dimethyl
benzyl hydroperoxide
80-15-9
CHOXD;
CHRED;
CARBN;
BIODG; or
INCINCMBST
CHOXD;
CHRED; or
CMBST
U097
Dimethylcarbamoyl chloride
Dimethylcarbamoyl chloride
79-44-7
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U098
1,1-Dimethylhydrazine
1,1-Dimethylhydrazine
57-14-7
CHOXD;
CHRED;
CARBN;
BIODG; or
INCINCMBST
CHOXD;
CHRED; or
CMBST
U099
1,2-Dimethylhydrazine
1,2-Dimethylhydrazine
540-73-8
CHOXD;
CHOXD;
603
CHRED;
CARBN;
BIODG; or
INCINCMBST
CHRED; or
CMBST
U101
2,4-Dimethylphenol
2,4-Dimethylphenol
105-67-9
0.036
14
U102
Dimethyl phthalate
Dimethyl phthalate
131-11-3
0.047
28
U103
Dimethyl sulfate
Dimethyl sulfate
77-78-1
CHOXD;
CHRED;
CARBN;
BIODG; or
INCINCMBST
CHOXD;
CHRED; or
CMBST
U105
2,4-Dinitrotoluene
2,4-Dinitrotoluene
121-14-2
0.32
140
U106
2,6-Dinitrotoluene
2,6-Dinitrotoluene
606-20-2
0.55
28
U107
Di-n-octyl phthalate
Di-n-octyl phthalate
117-84-0
0.017
28
U108
1,4-Dioxane
1,4-Dioxane
123-91-1
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
CMBST
1,4-Dioxane; alternate
6
standard for nonwastewaters
only
123-91-1
NA
170
U109
1,2-Diphenylhydrazine
604
1,2-Diphenylhydrazine
122-66-7
CHOXD;
CHRED;
CARBN;
BIODG; or
INCINCMBST
CHOXD;
CHRED; or
CMBST
1,2-Diphenylhydrazine;
alternate
6
standard for
wastewaters only
122-66-7
0.087
NA
U110
Dipropylamine
Dipropylamine
142-84-7
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U111
Di-n-propylnitrosamine
Di-n-propylnitrosamine
621-64-7
0.40
14
U112
Ethyl acetate
Ethyl acetate
141-78-8141-78-
6
0.34
33
U113
Ethyl acrylate
Ethyl acrylate
140-88-5
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
CMBST
U114
Ethylenebisdithiocarbamic acid salts and esters
Ethylenebisdithiocarbamic
acid
111-54-6
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U115
Ethylene oxide
Ethylene oxide
75-21-8
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
CHOXD; or
INCINCMBST
605
Ethylene oxide; alternate
6
standard for wastewaters
only
75-21-8
0.12
NA
U116
Ethylene thiourea
Ethylene thiourea
96-45-7
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U117
Ethyl ether
Ethyl ether
60-29-7
0.12
160
U118
Ethyl methacrylate
Ethyl methacrylate
97-63-2
0.14
160
U119
Ethyl methane sulfonate
Ethyl methane sulfonate
62-50-0
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U120
Fluoranthene
Fluoranthene
206-44-0
0.068
3.4
U121
Trichloromonofluoromethane
Trichloromonofluoromethane
75-69-4
0.020
30
U122
Formaldehyde
Formaldehyde
50-00-0
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
CMBST
U123
Formic acid
Formic acid
64-18-6
(WETOX or
CHOXD) fb
CMBST
606
CARBN; or
INCINCMBST
U124
Furan
Furan
110-00-9
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
CMBST
U125
Furfural
Furfural
98-01-1
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
CMBST
U126
Glycidylaldehyde
Glycidylaldehyde
765-34-4
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
CMBST
U127
Hexachlorobenzene
Hexachlorobenzene
118-74-1
0.055
10
U128
Hexachlorobutadiene
Hexachlorobutadiene
87-68-3
0.055
5.6
U129
Lindane
alpha-BHC
319-84-6
0.00014
0.066
beta-BHC
319-85-7
0.00014
0.066
delta-BHC
319-86-8
0.023
0.066
gamma-BHC (Lindane)
58-89-9
0.0017
0.066
U130
Hexachlorocyclopentadiene
Hexachlorocyclopentadiene
77-47-4
0.057
2.4
U131
Hexachloroethane
607
Hexachloroethane
67-72-1
0.055
30
U132
Hexachlorophene
Hexachlorophene
70-30-4
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U133
Hydrazine
Hydrazine
302-01-2
CHOXD;
CHRED;
CARBN;
BIODG; or
INCINCMBST
CHOXD;
CHRED; or
CMBST
U134
Hydrogen fluoride
Fluoride (measured in
wastewaters only)
16964-48-8
35
ADGAS fb
NEUTR; or
NEUTR
U135
Hydrogen sulfide
Hydrogen sulfide
7783-06-4
CHOXD;
CHRED; or
INCINCMBST
CHOXD;
CHRED; or
INCINCMBST
U136
Cacodylic acid
Arsenic
7440-38-2
1.4
5.0 mg/l TCLP
U137
Indeno(1,2,3-c,d)pyrene
Indeno(1,2,3-c,d)pyrene
193-39-5
0.0055
3.4
U138
Iodomethane
Iodomethane
74-88-4
0.19
65
U140
Isobutyl alcohol
Isobutyl alcohol
78-83-1
5.6
170
608
U141
Isosafrole
Isosafrole
120-58-1
0.081
2.6
U142
Kepone
Kepone
143-50-8
0.0011
0.13
U143
Lasiocarpine
Lasiocarpine
303-34-4
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U144
Lead acetate
Lead
7439-92-1
0.69
0.37 mg/l TCLP
U145
Lead phosphate
Lead
7439-92-1
0.69
0.37 mg/l TCLP
U146
Lead subacetate
Lead
7439-92-1
0.69
0.37 mg/l TCLP
U147
Maleic anhydride
Maleic anhydride
108-31-6
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
CMBST
U148
Maleic hydrazide
Maleic hydrazide
123-33-1
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U149
Malononitrile
Malononitrile
109-77-3
(WETOX or
CHOXD) fb
INCINCMBST
609
CARBN; or
INCINCMBST
U150
Melphalan
Melphalan
148-82-3
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U151
U151 (mercury) nonwastewaters that contain greater than or equal to 260 mg/kg total
mercury.
Mercury
7439-97-6
NA
RMERC
U151
U151 (mercury) nonwastewaters that contain less than 260 mg/kg total mercury and
that are residues from RMERC only.
Mercury
7439-97-6
NA
0.20 mg/l TCLP
U151
U151 (mercury) nonwastewaters that contain less than 260 mg/kg total mercury and
that are not residues from RMERC only.
Mercury
7439-97-6
NA
0.025 mg/l
TCLP
U151
All U151 (mercury) wastewater.
Mercury
7439-97-6
0.15
NA
U151
Element Mercury Contaminated with Radioactive Materials
Mercury
7439-97-6
NA
AMLGM
U152
Methacrylonitrile
Methacrylonitrile
126-98-7
0.24
84
U153
Methanethiol
Methanethiol
74-93-1
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
610
U154
Methanol
Methanol
67-56-1
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
CMBST
Methanol; alternate
6
set of
standards for both
wastewaters and
nonwastewaters
67-56-1
5.6
0.75 mg/l TCLP
U155
Methapyrilene
Methapyrilene
91-80-5
0.081
1.5
U156
Methyl chlorocarbonate
Methyl chlorocarbonate
79-22-1
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U157
3-Methylcholanthrene
3-Methylcholanthrene
56-49-5
0.0055
15
U158
4,4'-Methylene bis(2-chloroaniline)
4,4'-Methylene bis(2-chloro-
aniline)
101-14-4
0.50
30
U159
Methyl ethyl ketone
Methyl ethyl ketone
78-93-3
0.28
36
U160
Methyl ethyl ketone peroxide
Methyl ethyl ketone peroxide
1338-23-4
CHOXD;
CHRED;
CARBN;
BIODG; or
INCINCMBST
CHOXD;
CHRED; or
CMBST
U161
Methyl isobutyl ketone
611
Methyl isobutyl ketone
108-10-1
0.14
33
U162
Methyl methacrylate
Methyl methacrylate
80-62-6
0.14
160
U163
N-Methyl-N'-nitro-N-nitrosoguanidine
N-Methyl-N'-nitro-N-
nitrosoguanidine
70-25-7
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U164
Methylthiouracil
Methylthiouracil
56-04-2
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U165
Naphthalene
Naphthalene
91-20-3
0.059
5.6
U166
1,4-Naphthoquinone
1,4-Naphthoquinone
130-15-4
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
CMBST
U167
1-Naphthylamine
1-Naphthylamine
134-32-7
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U168
2-Naphthylamine
2-Naphthylamine
91-59-8
0.52
INCINCMBST
U169
Nitrobenzene
Nitrobenzene
98-95-3
0.068
14
612
U170
p-Nitrophenol
p-Nitrophenol
100-02-7
0.12
29
U171
2-Nitropropane
2-Nitropropane
79-46-9
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U172
N-Nitrosodi-n-butylamine
N-Nitrosodi-n-butylamine
924-16-3
0.40
17
U173
N-Nitrosodiethanolamine
N-Nitrosodiethanolamine
1116-54-7
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U174
N-Nitrosodiethylamine
N-Nitrosodiethylamine
55-18-5
0.40
28
U176
N-Nitroso-N-ethylurea
N-Nitroso-N-ethylurea
759-73-9
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U177
N-Nitroso-N-methylurea
N-Nitroso-N-methylurea
684-93-5
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U178
N-Nitroso-N-methylurethane
N-Nitroso-N-methylurethane
615-53-2
(WETOX or
CHOXD) fb
INCINCMBST
613
CARBN; or
INCINCMBST
U179
N-Nitrosopiperidine
N-Nitrosopiperidine
100-75-4
0.013
35
U180
N-Nitrosopyrrolidine
N-Nitrosopyrrolidine
930-55-2
0.013
35
U181
5-Nitro-o-toluidine
5-Nitro-o-toluidine
99-55-8
0.32
28
U182
Paraldehyde
Paraldehyde
123-63-7
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
CMBST
U183
Pentachlorobenzene
Pentachlorobenzene
608-93-5
0.055
10
U184
Pentachloroethane
Pentachloroethane
76-01-7
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
Pentachloroethane; alternate
6
standards for both
wastewaters and
nonwastewaters
76-01-7
0.055
6.0
U185
Pentachloronitrobenzene
Pentachloronitrobenzene
82-68-8
0.055
4.8
U186
1,3-Pentadiene
1,3-Pentadiene
504-60-9
(WETOX or
CHOXD) fb
CMBST
614
CARBN; or
INCINCMBST
U187
Phenacetin
Phenacetin
62-44-2
0.081
16
U188
Phenol
Phenol
108-95-2
0.039
6.2
U189
Phosphorus sulfide
Phosphorus sulfide
1314-80-3
CHOXD;
CHRED; or
INCINCMBST
CHOXD;
CHRED; or
INCINCMBST
U190
Phthalic anhydride
Phthalic anhydride
(measured as Phthalic acid
or Terephthalic acid)
100-21-0
0.055
28
Phthalic anhydride
(measured as Phthalic acid
or Terephthalic acid)
85-44-9
0.055
28
U191
2-Picoline
2-Picoline
109-06-8
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U192
Pronamide
Pronamide
23950-58-5
0.093
1.5
U193
1,3-Propane sultone
1,3-Propane sultone
1120-71-4
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U194
615
n-Propylamine
n-Propylamine
107-10-8
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U196
Pyridine
Pyridine
110-86-1
0.014
16
U197
p-Benzoquinone
p-Benzoquinone
106-51-4
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
CMBST
U200
Reserpine
Reserpine
50-55-5
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U201
Resorcinol
Resorcinol
108-46-3
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
CMBST
U202
Saccharin and salts
Saccharin
81-07-2
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U203
Safrole
Safrole
94-59-7
0.081
22
U204
Selenium dioxide
Selenium
7782-49-2
0.82
0.16 mg/l TCLP
616
U205
Selenium sulfide
Selenium
7782-49-2
0.82
0.16 mg/l TCLP
U206
Streptozotocin
Streptozotocin
18883-66-4
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U207
1,2,4,5-Tetrachlorobenzene
1,2,4,5-Tetrachlorobenzene
95-94-3
0.055
14
U208
1,1,1,2-Tetrachloroethane
1,1,1,2-Tetrachloroethane
630-20-6
0.057
6.0
U209
1,1,2,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
79-34-5
0.057
6.0
U210
Tetrachloroethylene
Tetrachloroethylene
127-18-4
0.056
6.0
U211
Carbon tetrachloride
Carbon tetrachloride
56-23-5
0.057
6.0
U213
Tetrahydrofuran
Tetrahydrofuran
109-99-9
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
CMBST
U214
Thallium (I) acetate
Thallium (measured in
wastewaters only)
7440-28-0
1.4
RTHRM; or
STABL
U215
617
Thallium (I) carbonate
Thallium (measured in
wastewaters only)
7440-28-0
1.4
RTHRM; or
STABL
U216
Thallium (I) chloride
Thallium (measured in
wastewaters only)
7440-28-0
1.4
RTHRM; or
STABL
U217
Thallium (I) nitrate
Thallium (measured in
wastewaters only)
7440-28-0
1.4
RTHRM; or
STABL
U218
Thioacetamide
Thioacetamide
62-55-5
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U219
Thiourea
Thiourea
62-56-6
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U220
Toluene
Toluene
108-88-3
0.080
10
U221
Toluenediamine
Toluenediamine
25376-45-8
CARBN; or
INCINCMBST
CMBST
U222
o-Toluidine hydrochloride
o-Toluidine hydrochloride
636-21-5
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U223
618
Toluene diisocyanate
Toluene diisocyanate
26471-62-5
CARBN; or
INCINCMBST
CMBST
U225
Bromoform (Tribromomethane)
Bromoform (Tribromo-
methane)
75-25-2
0.63
15
U226
1,1,1-Trichloroethane
1,1,1-Trichloroethane
71-55-6
0.054
6.0
U227
1,1,2-Tricloroethane
1,1,2-Tricloroethane
79-00-5
0.054
6.0
U228
Trichloroethylene
Trichloroethylene
79-01-6
0.054
6.0
U234
1,3,5-Trinitrobenzene
1,3,5-Trinitrobenzene
99-35-4
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U235
tris-(2,3-Dibromopropyl)-phosphate
tris-(2,3-Dibromopropyl)-
phosphate
126-72-7
0.11
0.10
U236
Trypan Blue
Trypan Blue
72-57-1
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U237
Uracil mustard
Uracil mustard
66-75-1
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
619
INCINCMBST
U238
Urethane (Ethyl carbamate)
Urethane (Ethyl carbamate)
51-79-6
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U239
Xylenes
Xylenes-mixed isomers
(sum of o-, m-, and p-xylene
concentrations)
1330-20-7
0.32
30
U240
2,4-D (2,4-Dichlorophenoxyacetic acid)
2,4-D (2,4-Dichloro-
phenoxyacetic acid)
94-75-7
0.72
10
2,4-D (2,4-Dichloro-
phenoxyacetic acid) salts and
esters
NA
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U243
Hexachloropropylene
Hexachloropropylene
1888-71-7
0.035
30
U244
Thiram
Thiram
137-26-8
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
INCINCMBST
U246
Cyanogen bromide
Cyanogen bromide
506-68-3
CHOXD;
WETOX; or
INCINCMBST
CHOXD;
WETOX; or
INCINCMBST
U247
Methoxychlor
Methoxychlor
72-43-5
0.25
0.18
620
U248
Warfarin, & salts, when present at concentrations of 0.3% or less
Warfarin
81-81-2
(WETOX or
CHOXD) fb
CARBN; or
INCINCMBST
CMBST
U249
Zinc phosphide, Zn
3
P
2
, when present at concentrations of 10% or less
Zinc Phosphide
1314-84-7
CHOXD;
CHRED; or
INCINCMBST
CHOXD;
CHRED; or
INCINCMBST
U271
Benomyl
10
Benomyl
17804-35-2
0.056
1.4
U278
Bendiocarb
10
Bendiocarb
22781-23-3
0.056
1.4
U279
Carbaryl
10
Carbaryl
63-25-2
0.006
0.14
U280
Barban
10
Barban
101-27-9
0.056
1.4
U328
o-Toluidine
o-Toluidine
95-53-4
INCINCMBST;
or CHOXD fb
(BIODG or
CARBN); or
BIODG fb
CARBN
INCINCMBST;
or Thermal
Destruction
U353
p-Toluidine
p-Toluidine
106-49-0
INCINCMBST;
or CHOXD fb
(BIODG or
CARBN); or
BIODG fb
INCINCMBST;
or Thermal
Destruction
621
CARBN
U359
2-Ethoxyethanol
2-Ethoxyethanol
110-80-5
INCINCMBST;
or CHOXD fb
(BIODG or
CARBN); or
BIODG fb
CARBN
CMBST
U364
Bendiocarb phenol
10
Bendiocarb phenol
22961-82-6
0.056
1.4
U367
Carbofuran phenol
10
Carbofuran phenol
1563-38-8
0.056
1.4
U372
Carbendazim
10
Carbendazim
10605-21-7
0.056
1.4
U373
Propham
10
Propham
122-42-9
0.056
1.4
U387
Prosulfocarb
10
Prosulfocarb
52888-80-9
0.042
1.4
U389
Triallate
10
Triallate
2303-17-5
0.042
1.4
U394
A2213
10
A2213
30558-43-1
0.042
1.4
U395
Diethylene glycol, dicarbamate
10
Diethylene glycol,
dicarbamate
5952-26-1
0.056
1.4
U404
622
Triethylamine
10
Triethylamine
101-44-8
0.081
1.5
U409
Thiophanate-methyl
10
Thiophanate-methyl
23564-05-8
0.056
1.4
U410
Thiodicarb
10
Thiodicarb
59669-26-0
0.019
1.4
U411
Propoxur
10
Propoxur
114-26-1
0.056
1.4
Notes:
1
The waste descriptions provided in this table do not replace waste descriptions
in 35 Ill. Adm. Code 721. Descriptions of Treatment or Regulatory
Subcategories are provided, as needed, to distinguish between applicability of
different standards.
2
CAS means Chemical Abstract Services. When the waste code or regulated
constituents are described as a combination of a chemical with its salts or esters,
the CAS number is given for the parent compound only.
3
Concentration standards for wastewaters are expressed in mg/l and are based on
analysis of composite samples.
4
All treatment standards expressed as a Technology Code or combination of
Technology Codes are explained in detail in 35 Ill. Adm. Code 728.Table C,
“Technology Codes and Descriptions of Technology-Based Standards”. “fb”
inserted between waste codes denotes “followed by”, so that the first-listed
treatment is followed by the second-listed treatment. “;” separates alternative
treatement schemes.
5
Except for Metals (EP or TCLP) and Cyanides (Total and Amenable) the
nonwastewater treatment standards expressed as a concentration were
established, in part, based upon incineration in units operated in accordance
with the technical requirements of 35 Ill. Adm. Code 724.Subpart O or 35 Ill.
Adm. Code 725.Subpart O, or based upon combustion in fuel substitution units
operating in accordance with applicable technical requirements. A facility may
comply with these treatment standards according to provisions in 35 Ill. Adm.
Code 728.140(d). All concentration standards for nonwastewaters are based on
analysis of grab samples.
623
6
Where an alternate treatment standard or set of alternate standards has been
indicated, a facility may comply with this alternate standard, but only for the
Treatment or Regulatory Subcategory or physical form (i.e., wastewater or
nonwastewater) specified for that alternate standard.
7
Both Cyanides (Total) and Cyanides (Amenable) for nonwastewaters are to be
analyzed using Method 9010 or 9012, found in “Test Methods for Evaluating
Solid Waste, Physical or Chemical Methods”, USEPA Publication SW-846, as
incorporated by reference in 35 Ill. Adm. Code 720.111, with a sample size of
10 grams and a distillation time of one hour and 15 minutes.
8
These wastes, when rendered nonhazardous and then subsequently managed in
CWA or CWA-equivalent systems, are not subject to treatment standards. (See
Section 728.101(c)(3) and (c)(4).)
9
These wastes, when rendered nonhazardous and then subsequently injected in a
Class I SDWA well, are not subject to treatment standards. (See 35 Ill. Adm.
Code 738.101(d).)
10
This footnote corresponds with note 10 to the table to 40 CFR 268.40, which
has already expired by its own terms. This statement maintains structural
consistency with the federal regulations.
NA
means not applicable.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 728.Table U
Universal Treatment Standards (UTS)
Regulated Constituent-
Common Name
CAS
1
No.
Wastewater
Standard
Concentration (in
mg/l
2
)
Nonwastewater
Standard
Concentration (in
mg/kg
3
unless
noted as “mg/l
TCLP”)
A2213
6
30558-43-1
0.042
1.4
Acenaphthylene
208-96-8
0.059
3.4
Acenaphthene
83-32-9
0.059
3.4
Acetone
67-64-1
0.28
160
624
Acetonitrile
75-05-8
5.6
1.838
Acetophenone
96-86-2
0.010
9.7
2-Acetylaminofluorene
53-96-3
0.059
140
Acrolein
107-02-8
0.29
NA
Acrylamide
79-06-1
19
23
Acrylonitrile
107-13-1
0.24
84
Aldicarb sulfone
6
1646-88-4
0.056
0.28
Aldrin
309-00-2
0.021
0.066
4-Aminobiphenyl
92-67-1
0.13
NA
Aniline
62-53-3
0.81
14
Anthracene
120-12-7
0.059
3.4
Aramite
140-57-8
0.36
NA
alpha-BHC
319-84-6
0.00014
0.066
beta-BHC
319-85-7
0.00014
0.066
delta-BHC
319-86-8
0.023
0.066
gamma-BHC
58-89-9
0.0017
0.066
Barban
6
101-27-9
0.056
1.4
Bendiocarb
6
22781-23-3
0.056
1.4
Bendiocarb phenol
6
22961-82-6
0.056
1.4
Benomyl
6
17804-35-2
0.056
1.4
Benzene
71-43-2
0.14
10
Benz(a)anthracene
56-55-3
0.059
3.4
Benzal chloride
98-87-3
0.055
6.0
625
Benzene
71-43-2
0.14
10
Benzo(b)fluoranthene
(difficult to distinguish from
benzo(k)fluoranthene)
205-99-2
0.11
6.8
Benzo(k)fluoranthene
(difficult to distinguish from
benzo(b)fluoranthene)
207-08-9
0.11
6.8
Benzo(g,h,i)perylene
191-24-2
0.0055
1.8
Benzo(a)pyrene
50-32-8
0.061
3.4
Bromodichloromethane
75-27-4
0.35
15
Methyl bromide (Bromo-
methane)
74-83-9
0.11
15
4-Bromophenyl phenyl ether
101-55-3
0.055
15
n-Butyl alcohol
71-36-3
5.6
2.6
Butylate
6
2008-41-5
0.042
1.4
Butyl benzyl phthalate
85-68-7
0.017
28
2-sec-Butyl-4,6-dinitro-
phenol (Dinoseb)
88-85-7
0.066
2.5
Carbaryl
6
63-25-2
0.006
0.14
Carbenzadim
6
10605-21-7
0.056
1.4
Carbofuran
6
1563-66-2
0.006
0.14
Carbofuran phenol
6
1563-38-8
0.056
1.4
Carbon disulfide
75-15-0
3.8
4.8 mg/l TCLP
Carbon tetrachloride
56-23-5
0.057
6.0
Carbosulfan
6
55285-14-8
0.028
1.4
Chlordane (alpha and gamma
57-74-9
0.0033
0.26
626
isomers)
p-Chloroaniline
106-47-8
0.46
16
Chlorobenzene
108-90-7
0.057
6.0
Chlorobenzilate
510-15-6
0.10
NA
2-Chloro-1,3-butadiene
126-99-8
0.057
0.28
Chlorodibromomethane
124-48-1
0.057
15
Chloroethane
75-00-3
0.27
6.0
bis(2-Chloroethoxy)methane
111-91-1
0.036
7.2
bis(2-Chloroethyl)ether
111-44-4
0.033
6.0
2-Chloroethyl vinyl ether
110-75-8
0.062
NA
Chloroform
67-66-3
0.046
6.0
bis(2-Chloroisopropyl)ether
108-60-139638-
32-9
0.055
7.2
p-Chloro-m-cresol
59-50-7
0.018
14
2-Chloroethyl vinyl ether
110-75-8
0.062
NA
Chloromethane (Methyl
chloride)
74-87-3
0.19
30
2-Chloronaphthalene
91-58-7
0.055
5.6
2-Chlorophenol
95-57-8
0.044
5.7
3-Chloropropylene
107-05-1
0.036
30
Chrysene
218-01-9
0.059
3.4
o-Cresol
95-48-7
0.11
5.6
m-Cresol (difficult to
distinguish from p-cresol)
108-39-4
0.77
5.6
627
p-Cresol (difficult to
distinguish from m-cresol)
106-44-5
0.77
5.6
m-Cumenyl methyl
-
carbamate
6
64-00-6
0.056
1.4
Cyclohexanone
108-94-1
0.36
0.75 mg/l TCLP
1,2-Dibromo-3-chloro-
propane
96-12-8
0.11
15
Ethylene dibromide (1,2-
Dibromoethane)
106-93-4
0.028
15
Dibromomethane
74-95-3
0.11
15
2,4-D (2,4-Dichloro-
phenoxyacetic acid)
94-75-7
0.72
10
o,p'-DDD
53-19-0
0.023
0.087
p,p'-DDD
72-54-8
0.023
0.087
o,p'-DDE
3424-82-6
0.031
0.087
p,p'-DDE
72-55-9
0.031
0.087
o,p'-DDT
789-02-6
0.0039
0.087
p,p'-DDT
50-29-3
0.0039
0.087
Dibenz(a,h)anthracene
53-70-3
0.055
8.2
Dibenz(a,e)pyrene
192-65-4
0.061
NA
1,2-Dibromo-3-chloro-
propane
96-12-8
0.11
15
1,2-Dibromoethane/Ethylene
dibromide
106-93-4
0.028
15
Dibromomethane
74-95-3
0.11
15
m-Dichlorobenzene
541-73-1
0.036
6.0
628
o-Dichlorobenzene
95-50-1
0.088
6.0
p-Dichlorobenzene
106-46-7
0.090
6.0
Dichlorodifluoromethane
75-71-8
0.23
7.2
1,1-Dichloroethane
75-34-3
0.059
6.0
1,2-Dichloroethane
107-06-2
0.21
6.0
1,1-Dichloroethylene
75-35-4
0.025
6.0
trans-1,2-Dichloroethylene
156-60-5
0.054
30
2,4-Dichlorophenol
120-83-2
0.044
14
2,6-Dichlorophenol
87-65-0
0.044
14
2,4-Dichlorophenoxyacetic
acid/2,4-D
94-75-7
0.72
10
1,2-Dichloropropane
78-87-5
0.85
18
cis-1,3-Dichloropropylene
10061-01-5
0.036
18
trans-1,3-Dichloropropylene
10061-02-6
0.036
18
Dieldrin
60-57-1
0.017
0.13
Diethylene glycol,
dicarbamate
6
5952-26-1
0.056
1.4
Diethyl phthalate
84-66-2
0.20
28
p-Dimethylaminoazobenzene
60-11-7
0.13
NA
2,4-Dimethyl phenol
105-67-9
0.036
14
Dimethyl phthalate
131-11-3
0.047
28
Dimetilan
6
644-64-4
0.056
1.4
Di-n-butyl phthalate
84-74-2
0.057
28
1,4-Dinitrobenzene
100-25-4
0.32
2.3
629
4,6-Dinitro-o-cresol
534-52-1
0.28
160
2,4-Dinitrophenol
51-28-5
0.12
160
2,4-Dinitrotoluene
121-14-2
0.32
140
2,6-Dinitrotoluene
606-20-2
0.55
28
Di-n-octyl phthalate
117-84-0
0.017
28
p-Dimethylaminoazobenzene
60-11-7
0.13
NA
Di-n-propylnitrosamine
621-64-7
0.40
14
1,4-Dioxane
123-91-1
NA12.0
170
Diphenylamine (difficult to
distinguish from
diphenylnitrosamine)
122-39-4
0.92
13
Diphenylnitrosamine
(difficult to distinguish from
diphenylamine)
86-30-6
0.92
13
1,2-Diphenylhydrazine
122-66-7
0.087
NA
Disulfoton
298-04-4
0.017
6.2
Dithiocarbamates (total)
6
137-30-4
0.028
28
Endosulfan I
939-98-8959-98-8
0.023
0.066
Endosulfan II
33213-6-533213-
65-9
0.029
0.13
Endosulfan sulfate
1-31-07-81031-07-
8
0.029
0.13
Endrin
72-20-8
0.0028
0.13
Endrin aldehyde
7421-93-4
0.025
0.13
EPTC
6
759-94-4
0.042
1.4
Ethyl acetate
141-78-6
0.34
33
630
Ethyl cyanide
(Propanenitrile)
107-12-0
0.24
360
Ethyl benzene
100-41-4
0.057
10
Ethyl cyanide
(Propanenitrile)
107-12-0
0.24
360
Ethyl ether
60-29-7
0.12
160
bis(2-Ethylhexyl) phthalate
117-81-7
0.28
28
Ethyl methacrylate
97-63-2
0.14
160
Ethylene oxide
75-21-8
0.12
NA
bis(2-Ethylhexyl) phthalate
117-81-7
0.28
28
Famphur
52-85-7
0.017
15
Fluoranthene
206-44-0
0.068
3.4
Fluorene
86-73-7
0.059
3.4
Formetanate hydrochloride
6
23422-53-9
0.056
1.4
Formparanate
6
17702-57-7
0.056
1.4
Heptachlor
76-44-8
0.0012
0.066
Heptachlor epoxide
1024-57-3
0.016
0.066
Hexachlorobenzene
118-74-1
0.055
10
Hexachlorobutadiene
87-68-3
0.055
5.6
Hexachlorocyclopentadiene
77-47-4
0.057
2.4
HxCDDs (All Hexachloro-
dibenzo-p-dioxins)
NA
0.000063
0.001
HxCDFs (All Hexachloro-
dibenzofurans)
NA
0.000063
0.001
631
Hexachloroethane
67-72-1
0.055
30
Hexachloropropylene
1888-71-7
0.035
30
Indeno (1,2,3-c,d) pyrene
193-39-5
0.0055
3.4
Iodomethane
74-88-4
0.19
65
Isobutyl alcohol
78-83-1
5.6
170
Isodrin
465-73-6
0.021
0.066
Isolan
6
119-38-0
0.056
1.4
Isosafrole
120-58-1
0.081
2.6
Kepone
143-50-8143-50-0
0.0011
0.13
Methacrylonitrile
126-98-7
0.24
84
Methanol
67-56-1
5.6
0.75 mg/l TCLP
Methapyrilene
91-80-5
0.081
1.5
Methiocarb
6
2032-65-7
0.056
1.4
Methomyl
6
16752-77-5
0.028
0.14
Methoxychlor
72-43-5
0.25
0.18
3-Methylcholanthrene
56-49-5
0.0055
15
4,4-Methylene bis(2-chloro-
aniline)
101-14-4
0.50
30
Methylene chloride
75-09-2
0.089
30
Methyl ethyl ketone
78-93-3
0.28
36
Methyl isobutyl ketone
108-10-1
0.14
33
Methyl methacrylate
80-62-6
0.14
160
Methyl methansulfonate
66-27-3
0.018
NA
Methyl parathion
298-00-0
0.014
4.6
632
Metolcarb
6
1129-41-5
0.056
1.4
Mexacarbate
6
315-18-4
0.056
1.4
Molinate
6
2212-67-1
0.042
1.4
Naphthalene
91-20-3
0.059
5.6
2-Naphthylamine
91-59-8
0.52
NA
o-Nitroaniline
88-74-4
0.27
14
p-Nitroaniline
100-01-6
0.028
28
Nitrobenzene
98-95-3
0.068
14
5-Nitro-o-toluidine
99-55-8
0.32
28
o-Nitrophenol
88-75-5
0.028
13
p-Nitrophenol
100-02-7
0.12
29
N-Nitrosodiethylamine
55-18-5
0.40
28
N-Nitrosodimethylamine
62-75-9
0.40
2.3
N-Nitroso-di-n-butylamine
924-16-3
0.40
17
N-Nitrosomethylethylamine
10595-95-6
0.40
2.3
N-Nitrosomorpholine
59-89-2
0.40
2.3
N-Nitrosopiperidine
100-75-4
0.013
35
N-Nitrosopyrrolidine
930-55-2
0.013
35
Oxamyl
6
23135-22-0
0.056
0.28
Parathion
56-38-2
0.014
4.6
Total PCBs (sum of all PCB
isomers, or all Aroclors)
1336-36-3
0.10
10
Pebulate
6
1114-71-2
0.042
1.4
633
Pentachlorobenzene
608-93-5
0.055
10
PeCDDs (All Pentachloro-
dibenzo-p-dioxins)
NA
0.000063
0.001
PeCDFs (All Pentachloro-
dibenzofurans)
NA
0.000035
0.001
Pentachloroethane
76-01-7
0.055
6.0
Pentachloronitrobenzene
82-68-8
0.055
4.8
Pentachlorophenol
87-86-5
0.089
7.4
Phenacetin
62-44-2
0.081
16
Phenanthrene
85-01-8
0.059
5.6
Phenol
108-95-2
0.039
6.2
o-Phenylenediamine
6
95-54-5
0.056
5.6
Phorate
298-02-2
0.021
4.6
Phthalic acid
100-21-0
0.055
28
Phthalic anhydride
85-44-9
0.055
28
Physostigmine
6
57-47-6
0.056
1.4
Physostigmine salicylate
6
57-64-7
0.056
1.4
Promecarb
6
2631-37-0
0.056
1.4
Pronamide
23950-58-5
0.093
1.5
Propham
6
122-42-9
0.056
1.4
Propoxur
6
114-26-1
0.056
1.4
Prosulfocarb
6
52888-80-9
0.042
1.4
Pyrene
129-00-0
0.067
8.2
634
Pyridine
110-86-1
0.014
16
Safrole
94-59-7
0.081
22
Silvex (2,4,5-TP)
93-72-1
0.72
7.9
2,4,5-T (2,4,5-Trichloro-
phenoxyacetic acid)
93-76-5
0.72
7.9
1,2,4,5-Tetrachlorobenzene
95-94-3
0.055
14
TCDDs (All Tetrachloro-
dibenzo-p-dioxins)
NA
0.000063
0.001
TCDFs (All Tetrachloro-
dibenzofurans)
NA
0.000063
0.001
1,1,1,2-Tetrachloroethane
630-20-6
0.057
6.0
1,1,2,2-Tetrachloroethane
79-34-679-34-5
0.057
6.0
Tetrachloroethylene
127-18-4
0.056
6.0
2,3,4,6-Tetrachlorophenol
58-90-2
0.030
7.4
Thiodicarb
6
59669-26-0
0.019
1.4
Thiophanate-methyl
6
23564-05-8
0.056
1.4
Tirpate
6
26419-73-8
0.056
0.28
Toluene
108-88-3
0.080
10
Toxaphene
8001-35-2
0.0095
2.6
Triallate
6
2303-17-5
0.042
1.4
Bromoform (Tribromo-
methane (Bromoform)
75-25-2
0.63
15
1,2,4-Trichlorobenzene
120-82-1
0.055
19
1,1,1-Trichloroethane
71-55-6
0.054
6.0
1,1,2-Trichloroethane
79-00-5
0.054
6.0
635
Trichloroethylene
79-01-6
0.054
6.0
Trichloromonofluoromethane
75-69-4
0.020
30
2,4,5-Trichlorophenol
95-95-4
0.18
7.4
2,4,6-Trichlorophenol
88-06-2
0.035
7.4
2,4,5-Trichlorophenoxy-
acetic acid/2,4,5-T
93-76-5
0.72
7.9
1,2,3-Trichloropropane
96-18-4
0.85
30
1,1,2-Trichloro-1,2,2-
trifluoroethane
76-13-1
0.057
30
Triethylamine
6
101-44-8
0.081
1.5
tris-(2,3-Dibromopropyl)
phosphate
126-72-7
0.11
0.10
Vernolate
6
1929-77-7
0.042
1.4
Vinyl chloride
75-01-4
0.27
6.0
Xylenes-mixed isomers (sum
of o-, m-, and p-xylene
concentrations)
1330-20-7
0.32
30
Antimony
7440-36-0
1.9
2.1 mg/l TCLP
Arsenic
7440-38-2
1.4
5.0 mg/l TCLP
Barium
7440-39-3
1.2
7.6 mg/l TCLP
Beryllium
7440-41-7
0.82
0.014 mg/l TCLP
Cadmium
7440-43-9
0.69
0.19 mg/l TCLP
Chromium (Total)
7440-47-3
2.77
0.86 mg/l TCLP
Cyanides (Total)
4
57-12-5
1.2
590
Cyanides (Amenable)
4
57-12-5
0.86
30
636
Fluoride
5
16964-48-816984-
48-8
35
NA
Lead
7439-92-1
0.69
0.37 mg/l TCLP
Mercury-Nonwastewater
from Retort
7439-97-6
NA
0.20 mg/l TCLP
Mercury-All Others
7439-97-6
0.15
0.025 mg/l TCLP
Nickel
7440-02-0
3.98
5.0 mg/l TCLP
Selenium
7782-49-2
0.82
0.16 mg/l TCLP
Silver
7440-22-4
0.43
0.30 mg/l TCLP
Sulfide
8496-25-818496-
25-8
14
NA
Thallium
7440-28-0
1.4
0.078 mg/l TCLP
Vanadium
5
7440-62-2
4.3
0.23 mg/l TCLP
Zinc
5
7440-66-6
2.61
5.3 mg/l TCLP
1
CAS means Chemical Abstract Services. When the waste code or regulated
constituents are described as a combination of a chemical with its salts or esters,
the CAS number is given for the parent compound only.
2
Concentration standards for wastewaters are expressed in mg/l are based on
analysis of composite samples.
3
Except for metals (EP or TCLP) and cyanides (total and amenable), the
nonwastewater treatment standards expressed as a concentration were
established, in part, based on incineration in units operated in accordance with
the technical requirements of 35 Ill. Adm. Code 724.Subpart O or 35 Ill. Adm.
Code 725.Subpart O or on combustion in fuel substitution units operating in
accordance with applicable technical requirements. A facility may comply with
these treatment standards according to provisions in 40 CFR 268.40(d). All
concentration standards for nonwastewaters are based on analysis of grab
samples.
4
Both Cyanides (Total) and Cyanides (Amenable) for nonwastewaters are to be
analyzed using Method 9010 or 9012, found in “Test Methods for Evaluating
Solid Waste, Physical/Chemical Methods”, USEPA Publication SW-846,
637
incorporated by reference in 35 Ill. Adm. Code 720.111, with a sample size of
10 grams and a distillation time of one hour and 15 minutes.
5
Vanadium and zincThese constituents are not “underlying hazardous
constituents” in characteristic wastes, according to the definition at Section
728.102(i).
6
This footnote corresponds with note 6 to the table to 40 CFR 268.48(a), which
has already expired by its own terms. This statement maintains structural
consistency with the federal regulations.
Note: NA means not applicable.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE G: WASTE DISPOSAL
CHAPTER I: POLLUTION CONTROL BOARD
SUBCHAPTER c: HAZARDOUS WASTE OPERATING REQUIREMENTS
PART 733
STANDARDS FOR UNIVERSAL WASTE MANAGEMENT
SUBPART A: GENERAL
Section
733.101
Scope
733.102
Applicability--Batteries
733.103
Applicability--Pesticides
733.104
Applicability--Mercury Thermostats
733.105
Applicability--Household and Conditionally Exempt Small Quantity
Generator Waste
733.106
Definitions
SUBPART B: STANDARDS FOR SMALL QUANTITY HANDLERS
Section
733.110
Applicability
733.111
Prohibitions
733.112
Notification
733.113
Waste Management
733.114
Labeling and Marking
733.115
Accumulation Time Limits
733.116
Employee Training
733.117
Response to Releases
733.118
Off-Site Shipments
638
733.119
Tracking Universal Waste Shipments
733.120
Exports
SUBPART C: STANDARDS FOR LARGE QUANTITY HANDLERS
Section
733.130
Applicability
733.131
Prohibitions
733.132
Notification
733.133
Waste Management
733.134
Labeling and Marking
733.135
Accumulation Time Limits
733.136
Employee Training
733.137
Response to Releases
733.138
Off-Site Shipments
733.139
Tracking Universal Waste Shipments
733.140
Exports
SUBPART D: STANDARDS FOR UNIVERSAL WASTE
TRANSPORTERS
Section
733.150
Applicability
733.151
Prohibitions
733.152
Waste Management
733.153
Accumulation Time Limits
733.154
Response to Releases
733.155
Off-site Shipments
733.156
Exports
SUBPART E: STANDARDS FOR DESTINATION FACILITIES
Section
733.160
Applicability
733.161
Off-Site Shipments
733.162
Tracking Universal Waste Shipments
SUBPART F: IMPORT REQUIREMENTS
Section
733.170
Imports
SUBPART G: PETITIONS TO INCLUDE OTHER WASTES
Section
733.180
General
733.181
Factors for Petitions to Include Other Wastes
AUTHORITY: Implementing Section 22.4 and authorized by Section 27 of the
Environmental Protection Act [415 ILCS 5/22.4 and 27].
639
SOURCE: Adopted in R95-20 at 20 Ill. Reg. 11291, effective August 1, 1996;
amended in R96-10/R97-3/R97-5 at 21 Ill. Reg. ________, effective
____________________.
SUBPART B: STANDARDS FOR SMALL QUANTITY HANDLERS
Section 733.120
Exports
A small quantity handler of universal waste that sends universal waste to a foreign
destination other than to those OECD countries specified in 35 Ill. Adm. Code
722.158(a)(1) (in which case the handler is subject to the requirements of 35 Ill. Adm.
Code 722.Subpart H) shall:
a)
Comply with the requirements applicable to a primary exporter in 35 Ill.
Adm. Code 722.153; 722.156(a)(1) through (a)(4), (a)(6), and (b); and
722.157;
b)
Export such universal waste only upon consent of the receiving country
and in conformance with the USEPA Acknowledgement of Consent, as
defined in 35 Ill. Adm. Code 722.Subpart E; and
c)
Provide a copy of the USEPA Acknowledgment of Consent for the
shipment to the transporter transporting the shipment for export.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
SUBPART C: STANDARDS FOR LARGE QUANTITY HANDLERS
Section 733.140
Exports
A large quantity handler of universal waste that sends universal waste to a foreign
destination other than to those OECD countries specified in 35 Ill. Adm. Code
722.158(a)(1) (in which case the handler is subject to the requirements of 35 Ill. Adm.
Code 722.Subpart H) shall:
a)
Comply with the requirements applicable to a primary exporter in 35 Ill.
Adm. Code 722.153; 722.156(a)(1) through (a)(4), (a)(6), and (b); and
722.157;
b)
Export such universal waste only upon consent of the receiving country
and in conformance with the USEPA Acknowledgement of Consent as
defined in 35 Ill. Adm. Code 722.Subpart E; and
640
c)
Provide a copy of the USEPA Acknowledgement of Consent for the
shipment to the transporter transporting the shipment for export.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
SUBPART D: STANDARDS FOR UNIVERSAL WASTE
TRANSPORTERS
Section 733.156
Exports
A universal waste transporter transporting a shipment of universal waste to a foreign
destination other than to those OECD countries specified in 35 Ill. Adm. Code
722.158(a)(1) (in which case the transporter is subject to the requirements of 35 Ill.
Adm. Code 722.Subpart H) may not accept a shipment if the transporter knows the
shipment does not conform to the USEPA Acknowledgment of Consent. In addition
the transporter shall ensure the following:
a)
A copy of the USEPA Acknowledgment of Consent accompanies the
shipment; and
b)
The shipment is delivered to the facility designated by the person
initiating the shipment.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
SUBPART F: IMPORT REQUIREMENTS
Section 733.170
Imports
Persons managing universal waste that is imported from a foreign country into the
United States are subject to the applicable requirements of this Part immediately after
the waste enters the United States, as followsindicated in subsections (a) through (c)
below:
a)
A universal waste transporter is subject to the universal waste transporter
requirements of 733.Subpart D of this Part.
b)
A universal waste handler is subject to the small or large quantity
handler of universal waste requirements of 733.Subpart B or C of this
Part, as applicable.
641
c)
An owner or operator of a destination facility is subject to the destination
facility requirements of 733.Subpart E of this Part.
d)
Persons managing universal waste that is imported from an OECD
country as specified in 35 Ill. Adm. Code 722.158(a)(1) are subject to
subsections (a) through (c) of this Section, in addition to the
requirements of 35 Ill. Adm. Code 722.Subpart H.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
SUBTITLE G: WASTE DISPOSAL
CHAPTER I: POLLUTION CONTROL BOARD
SUBCHAPTER d: UNDERGROUND INJECTION CONTROL AND
UNDERGROUND
STORAGE TANK PROGRAMS
PART 738
HAZARDOUS WASTE INJECTION RESTRICTIONS
SUBPART A: GENERAL
Section
738.101
Purpose Scope and Applicability
738.102
Definitions
738.103
Dilution Prohibited as a Substitute for Treatment
738.104
Case-by-Case Extensions of an Effective Date
738.105
Waste Analysis
SUBPART B: PROHIBITIONS ON INJECTION
Section
738.110
Waste Specific Prohibitions - Solvent Wastes
738.111
Waste Specific Prohibitions - Dioxin-Containing Wastes
738.112
Waste Specific Prohibitions - California List Wastes
738.114
Waste Specific Prohibitions - First Third Wastes
738.115
Waste Specific Prohibitions - Second Third Wastes
738.116
Waste Specific Prohibitions - Third Third Wastes
738.117
Waste-Specific Prohibitions - Newly-Listed Wastes
738.118
Waste-Specific Prohibitions - Newly Identified Wastes
SUBPART C: PETITION STANDARDS AND PROCEDURES
Section
738.120
Petitions to Allow Injection of a Prohibited Waste
738.121
Required Information to Support Petitions
738.122
Submission, Review and Approval or Denial of Petitions
738.123
Review of Adjusted Standards
642
738.124
Termination of Adjusted Standards
AUTHORITY: Implementing Sections 13 and 22.4 and authorized by Section 27 of
the Environmental Protection Act [415 ILCS 5/13, 22.4 and 27].
SOURCE: Adopted in R89-2 at 14 Ill. Reg. 3059, effective February 20, 1990;
amended in R89-11 at 14 Ill. Reg. 11948, effective July 9, 1990; amended in R90-14
at 15 Ill. Reg. 11425, effective July 24, 1991; amended in R92-13 at 17 Ill. Reg. 6190,
effective April 5, 1993; amended in R93-6 at 17 Ill. Reg. 15641, effective September
14, 1993; amended in R95-4 at 19 Ill. Reg. 9501, effective June 27, 1995; amended in
R96-10/R97-3/R97-5 at 21 Ill. Reg. ________, effective ____________________.
SUBPART A: GENERAL
Section 738.101
Purpose Scope and Applicability
a)
This Part identifies hazardous wastes that are restricted from disposal
into Class I hazardous waste injection wells and defines those
circumstances under which a waste, otherwise prohibited from injection,
may be injected.
b)
The requirements of this Part apply to owners or operators of the
following Class I wells:
1)
hHazardous waste injection wells that are used to inject hazardous
waste; and
2)
Injection wells that are used to inject wastes which once exhibited
a prohibited characteristic of hazardous waste identified in 35 Ill.
Adm. Code 721.Subpart C, at the point of generation, and which
no longer exhibit the characteristic at the point of injection.
c)
Wastes otherwise prohibited from injection may continue to be injected:
1)
If an extension from the effective date of a prohibition has been
granted pursuant to Section 738.104; or
2)
If an adjusted standard has been granted in response to a petition
filed under Section 738.120; or
3)
If the waste is generated by a conditionally exempt small quantity
generator, as defined in 35 Ill. Adm. Code 721.105.
643
d)
WA wastes that areis hazardous only because theyit exhibits a hazardous
characteristic, and which of hazardous waste and which areis otherwise
prohibited from injection under this Part or 35 Ill. Adm. Code 728, areis
not prohibited from injection if the following is true of the wastes:
1)
AreIt is disposed into a Class I non-hazardous waste injection
well or a Class I hazardous waste injection well that receives only
non-prohibited hazardous wastes, as such are defined under 35
Ill. Adm. Code 730.106(a); and
2)
DoIt does not exhibit any prohibited characteristic of hazardous
waste identified in 35 Ill. Adm. Code 721.Subpart C at the point
of injection.
BOARD NOTE: The exemption for injection of diluted
hazardous waste in this subsection was the subject of litigation in
Chemical Waste Management et al. v. USEPA, 976 F.2d 2
(D.C. Cir. 1992). The USEPA response to the mandate in this
litigation may result in the repeal or modification of 40 CFR
148.1(d), from which this subsection is derived. USEPA
responded to the remand by issuing an interim final rule on May
24, 1993, at 58 Fed. Reg. 29860, but that action did not directly
affect 40 CFR 148.1. The Board views any federal court
decision on the effectiveness or enforceability of the USEPA rule
as binding on this subsection.
BOARD NOTE: Derived from 40 CFR 148.1 (19926), as
amended at 57 Fed. Reg. 31963 (July 20, 1992).
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 738.103
Dilution Prohibited as a Substitute for Treatment
The prohibition of 35 Ill. Adm. Code 728.103 shall apply to owners or operators of
Class I hazardous waste injection wells.
a)
The provisions of 35 Ill. Adm. Code 728.103 shall apply to owners or
operators of Class I wells used to inject a waste that is hazardous at the
point of generation whether or not the waste is hazardous at the point of
injection.
b)
Owners or operators of Class I nonhazardous waste injection wells that
inject waste formerly exhibiting a hazardous characteristic which has
been removed by dilution may address underlying hazardous constituents
by treating the hazardous waste, obtaining an exemption pursuant to a
644
petition filed under Section 738.120, or complying with the provisions
set forth in 35 Ill. Adm. Code 728.109.
BOARD NOTE: Derived from 40 CFR 148.3 (198896), as added at 53 Fed. Reg.
28155, July 26, 1988.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 738.104
Case-by-Case Extensions of an Effective Date
The owner or operator of a Class I hazardous or nonhazardous waste injection well may
submit an application to USEPA for an extension of the effective date of any applicable
prohibition established under Subpart B. (See 35 Ill. Adm. Code 728.105.)
BOARD NOTE: Derived from 40 CFR 148.4 (198896), as added at 53 Fed. Reg.
28155, July 26, 1988.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
SUBPART B: PROHIBITIONS ON INJECTION
Section 738.117
Waste-Specific Prohibitions - Newly-Listed Wastes
a)
The wastes specified in 35 Ill. Adm. Code 721.Subpart D by the
following U.S. EPA hazardous waste numbers are prohibited from
underground injection:
F037
F038
K107
K108
K109
K110
K111
K112
K117
K118
K123
K124
K125
K126
K131
K136
U328
645
U353
U359
b)
The wastes specified in 35 Ill. Adm. Code 721.Subpart D by the
following U.S. EPA hazardous waste numbers are prohibited from
underground injection:
K141
K142
K143
K144
K145
K147
K148
K149
K150
K151
c) Effective September 19, 1995, the wastes specified in 35 Ill. Adm. Code
721.Subpart C by the following U.S. EPA hazardous waste numbers are
prohibited from underground injection:
D001 (high TOC subcategory, as specified at 35 Ill. Adm. Code
728.140)
D012
D013
D014
D015
D016
D017
c)
This subsection corresponds with 40 CFR 148.17(c), removed and
marked “reserved” by USEPA at 61 Fed. Reg. 15662 (April 8, 1996).
This statement maintains structural consistency with USEPA rules.
d)
Effective June 30, 1995, the wastes specified in 35 Ill. Adm. Code
721.Subpart D by the following U.S. EPA hazardous waste numbers are
prohibited from underground injection:
K117
K118
K131
K132
646
e)
The requirements of subsections (a) and (b) aboveof this Section do not
apply:
1)
If the wastes meet or are treated to meet the applicable standards
specified in 35 Ill. Adm. Code 728.Subpart D; or
2)
If an adjusted standard has been granted in response to a petition
under 738.Subpart C of this Part; or
3)
During the period of extension of the applicable effective date, if
an extension is granted under Section 738.104.
BOARD NOTE: Derived from 40 CFR 148.17, as added at 57
Fed. Reg. 37263 (Aug. 18, 1992) (1996).
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
Section 738.118 Waste-Specific Prohibitions - Newly Identified Wastes
a)
The wastes specified in 35 Ill. Adm. Code 721.132 as having the
following USEPA hazardous waste numbers are prohibited from
underground injection:
K156
K157
K158
K159
K160
K161
P127
P128
P185
P188
P189
P190
P191
P192
P194
P196
P197
P198
P199
P201
P202
P203
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P204
P205
U271
U277
U278
U279
U280
U364
U365
U366
U367
U372
U373
U375
U376
U377
U378
U379
U381
U382
U383
U384
U385
U386
U387
U389
U390
U391
U392
U393
U394
U395
U396
U400
U401
U402
U403
U404
U407
U409
U410
U411
b)
The wastes specified in 35 Ill. Adm. Code 721.132 as USEPA hazardous
waste number K088 is prohibited from underground injection.
648
c)
On April 8, 1998, the wastes specified in 35 Ill. Adm. Code 721 as
having the following USEPA hazardous waste numbers and Mixed
TC/Radioactive wastes are prohibited from underground injection:
D018
D019
D020
D021
D022
D023
D024
D025
D026
D027
D028
D029
D030
D031
D032
D033
D034
D035
D036
D037
D038
D039
D040
D041
D042
D043
d)
On April 8, 1998, the wastes specified in 35 Ill. Adm. Code 721 as
having the following USEPA hazardous waste numbers are prohibited
from underground injection:
D001
D002
D003
(Source: Added at 21 Ill. Reg. ________, effective ______________________)
SUBPART C: PETITION STANDARDS AND PROCEDURES
649
Section 738.120
Petitions to Allow Injection of a Prohibited Waste
a)
Any person seeking an exemption from a prohibition under Subpart B
for the injection of a restricted hazardous waste into an injection well or
wells, including a hazardous waste that exhibits a characteristic of
hazardous waste and which contains underlying hazardous constituents at
the point of generation, but which no longer exhibits a characteristic of
hazardous waste when injected into a Class I injection well or wells,
shall submit a petition for an adjusted standard to the Board, pursuant to
35 Ill. Adm. Code 106.Subpart G, demonstrating that, to a reasonable
degree of certainty, there will be no migration of hazardous constituents
from the injection zone for as long as the waste remains hazardous. This
demonstration requires a showing that:
1)
The hydrogeological and geochemical conditions at the site(s) and
the physiochemical nature of the waste stream(s) are such that
reliable predictions can be made that:
A)
Fluid movement conditions are such that the injected
fluids will not migrate within 10,000 years:
i)
Vertically upward out of the injection zone; or
ii)
Laterally within the injection zone to a point of
discharge or interface with an Underground Source
of Drinking Water (USDW) as defined in 35 Ill.
Adm. Code 730; or
B)
Before the injected fluids migrate out of the injection zone
or to a point of discharge or interface with USDW, the
fluid will no longer be hazardous because of attenuation,
transformation, or immobilization of hazardous
constituents within the injection zone by hydrolysis,
chemical interactions or other means; and
2)
For each well the petition has:
A)
Demonstrated that the injection well’s area of review
complies with the substantive requirements of 35 Ill.
Adm. Code 730.163;
B)
Located, identified, and ascertained the condition of all
wells within the injection well’s area of review (as
specified in 35 Ill. Adm. Code 730.163) that penetrate the
injection zone or the confining zone by use of a protocol
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acceptable to the Board that meets the substantive
requirements of 35 Ill. Adm. Code 730.164;
C)
Submitted a corrective action plan that meets the
substantive requirements of 35 Ill. Adm. Code 730.164,
the implementation of which shall become a condition of
any adjusted standard granted; and
D)
Submitted the results of pressure and radioactive tracer
tests performed within one year prior to submission of the
petition demonstrating the mechanical integrity of the
well’s long string casing, injection tube, annular seal, and
bottom hole cement. In cases where the petition has not
been approved or denied within one year after the initial
demonstration of mechanical integrity, the Board may
require the owner or operator to perform the tests again
and submit the results of the new tests.
BOARD NOTE: The requirements of subsection (a)(2)
need not be incorporated in a permit at the time the Board
grants an adjusted standard.
b)
A demonstration under subsection (a)(1)(A) must identify the strata
within the injection zone which will confine fluid movement above the
injection interval and include a showing that this strata is free of known
transmissive faults of fractures and that there is a confining zone above
the injection zone.
c)
A demonstration under subsection (a)(1)(B) must identify the strata
within the injection zone where waste transformation will be
accomplished and include a showing that this strata is free of known
transmissive faults or fractures and that there is a confining zone above
the injection zone.
d)
A demonstration may include a showing that:
1)
Treatment methods that reduce the toxicity or mobility of the
wastes, the implementation of which will become a condition of
any adjusted standard, must be utilized; or
2)
A monitoring plan, the implementation of which will become a
condition of any adjusted standard, must be utilized to enhance
confidence in one or more aspects of the demonstration.
651
e)
Any person whothat has been granted an adjusted standard pursuant to
this Section may submit a petition for reissuance of the adjusted standard
to include an additional restricted waste or wastes or to modify any
conditions placed on that adjusted standard by the Board. The Board
will reissue the adjusted standard if the petitioner complies with
subsections (a), (b) and (c).
f)
Any person whothat has been granted an adjusted standard pursuant to
this Section may submit a petition to modify that adjusted standard to
include an additional (hazardous) waste or wastes. The Board may grant
the modification if it determines, to a reasonable degree of certainty, that
the additional waste or wastes will behave hydraulically and chemically
in a manner similar to previously included wastes and that it will not
interfere with the containment capability of the injection zone.
BOARD NOTE: Derived from 40 CFR 148.20 (198896), as added at
53 Fed. Reg. 28155, July 26, 1988.
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE G: WASTE DISPOSAL
CHAPTER I: POLLUTION CONTROL BOARD
SUBCHAPTER c: HAZARDOUS WASTE OPERATING
REQUIREMENTS
PART 739
STANDARDS FOR THE MANAGEMENT OF USED OIL
SUBPART A: DEFINITIONS
Section
739.100
Definitions
SUBPART B: APPLICABILITY
Section
739.110
Applicability
739.111
Used oil specifications
739.112
Prohibitions
SUBPART C: STANDARDS FOR USED OIL GENERATORS
Section
739.120
Applicability
739.121
Hazardous waste mixing
739.122
Used oil storage
652
739.123
On-site burning in space heaters
739.124
Off-site shipments
SUBPART D: STANDARDS FOR USED OIL COLLECTION
CENTERS AND AGGREGATION POINTS
Section
739.130
Do-it-yourselfer used oil collection centers
739.131
Used oil collection centers
739.132
Used oil aggregate points owned by the generator
SUBPART E: STANDARDS FOR USED OIL TRANSPORTER AND
TRANSFER FACILITIES
Section
739.140
Applicability
739.141
Restrictions on transporters that are not also processors
739.142
Notification
739.143
Used oil transportation
739.144
Rebuttable presumption for used oil
739.145
Used oil storage at transfer facilities
739.146
Tracking
739.147
Management of residues
SUBPART F: STANDARDS FOR USED OIL PROCESSORS
Section
739.150
Applicability
739.151
Notification
739.152
General facility standards
739.153
Rebuttable presumption for used oil
739.154
Used oil management
739.155
Analysis plan
739.156
Tracking
739.157
Operating record and reporting
739.158
Off-site shipments of used oil
739.159
Management of residues
SUBPART G: STANDARDS FOR USED OIL BURNERS THAT
BURN OFF-SPECIFICATION USED OIL FOR ENERGY
RECOVERY
Section
739.160
Applicability
739.161
Restriction on burning
739.162
Notification
739.163
Rebuttable presumption for used oil
739.164
Used oil storage
739.165
Tracking
653
739.166
Notices
739.167
Management of residues
SUBPART H: STANDARDS FOR USED OIL FUEL MARKETERS
Section
739.170
Applicability
739.171
Prohibitions
739.172
On-specification used oil fuel
739.173
Notification
739.174
Tracking
739.175
Notices
SUBPART I: STANDARDS FOR USE AS A DUST SUPPRESSANT
DISPOSAL OF USED OIL
Section
739.180
Applicability
739.181
Disposal
739.182
Use as a dust suppressant
AUTHORITY: Implementing Section 22.4 and authorized by Section 27 of the
Environmental Protection Act [415 ILCS 5/22.4 and 27].
SOURCE: Adopted in R93-4 at 17 Ill. Reg. 20954, effective November 22, 1993;
amended in R93-16 at 18 Ill. Reg. 6931, effective April 26, 1994; amended in R94-17
at 18 Ill. Reg. 17616, effective November 23, 1994; amended in R95-6 at 19 Ill. Reg.
10036, effective June 27, 1995; amended in R96-10/R97-3/R97-5 at 21 Ill. Reg.
________, effective ____________________.
SUBPART B: APPLICABILITY
Section 739.110
Applicability
This Section identifies those materials which are subject to regulation as used oil under
this Part. This Section also identifies some materials that are not subject to regulation
as used oil under this Part, and indicates whether these materials may be subject to
regulation as hazardous waste under Parts35 Ill. Adm. Code 702, 703, 720 through
726, and 728.
a)
Used oil. U.S. EPA presumes that used oil is to be recycled unless a
used oil handler disposes of used oil, or sends used oil for disposal.
Except as provided in Section 739.111, the regulations of this Part apply
to used oil, and to materials identified in this Section as being subject to
regulation as used oil, whether or not the used oil or material exhibits
654
any characteristics of hazardous waste identified in 35 Ill. Adm. Code
721.Subpart C.
b)
Mixtures of used oil and hazardous waste.
1)
Listed hazardous waste.
A)
A mixture of used oil and hazardous waste that is listed in
35 Ill. Adm. Code 721.Subpart D is subject to regulation
as hazardous waste under 35 Ill. Adm. Code 703, 720
through 726, and 728, rather than as used oil under this
Part.
B)
Rebuttable presumption for used oil. Used oil containing
more than 1,000 ppm total halogens is presumed to be a
hazardous waste because it has been mixed with
halogenated hazardous waste listed in 35 Ill. Adm. Code
721.Subpart D. Persons may rebut this presumption by
demonstrating that the used oil does not contain hazardous
waste (for example, by using an analytical method from
SW-846, Edition III, to show that the used oil does not
contain significant concentrations of halogenated
hazardous constituents listed in 35 Ill. Adm. Code
721.Appendix H). U.S. EPA Publication SW-846, Third
Edition, is available from the Government Printing
Office, Superintendent of Documents, P.O. Box 371954,
Pittsburgh, PA 15250-7954, (202) 783-3238 (document
number 955-001-00000-1).
i)
The rebuttable presumption does not apply to
metalworking oils or fluids containing chlorinated
paraffins, if they are processed, through a tolling
arrangement as described in Section 739.124(c), to
reclaim metalworking oils or fluids. The
presumption does apply to metalworking oils or
fluids if such oils or fluids are recycled in any
other manner, or disposed.
ii)
The rebuttable presumption does not apply to used
oils contaminated with chlorofluorocarbons (CFCs)
removed from refrigeration units where the CFCs
are destined for reclamation. The rebuttable
presumption does apply to used oils contaminated
with CFCs that have been mixed with used oil
from sources other than refrigeration units.
655
2)
Characteristic hazardous waste. A mixture of used oil and
hazardous waste that exhibits a hazardous waste characteristic
identified in 35 Ill. Adm. Code 721.Subpart C and a mixture of
used oil and hazardous waste that is listed in Subpart D of this
Part solely because it exhibits one or more of the characteristics
of hazardous waste identified in 35 Ill. Adm. Code 721.Subpart
C is subject to:
A)
Except as provided in subsection (b)(2)(C) of this Section,
regulation as hazardous waste under 35 Ill. Adm. Code
703, 720 through 726, and 728 rather than as used oil
under this Part, if the resultant mixture exhibits any
characteristics of hazardous waste identified in 35 Ill.
Adm. Code 721.Subpart C; or
B)
Except as provided in subsection (b)(2)(C) of this Section,
regulation as used oil under this Part, if the resultant
mixture does not exhibit any characteristics of hazardous
waste identified under 35 Ill. Adm. Code 721.Subpart C.
C)
Regulation as used oil under this Part, if the mixture is of
used oil and a waste which is hazardous solely because it
exhibits the characteristic of ignitability (e.g., ignitable-
only mineral spirits), provided that the resultant mixture
does not exhibit the characteristic of ignitability under 35
Ill. Adm. Code 721.121.
3)
Conditionally exempt small quantity generator hazardous waste.
A mixture of used oil and conditionally exempt small quantity
generator hazardous waste regulated under 35 Ill. Adm. Code
721.105 is subject to regulation as used oil under this Part.
c)
Materials containing or otherwise contaminated with used oil.
1)
Except as provided in subsection (c)(2) of this Section, a material
containing or otherwise contaminated with used oil from which
the used oil has been properly drained or removed to the extent
possible such that no visible signs of free-flowing oil remain in or
on the material:
A)
Is not used oil, and thus, it is not subject to this Part, and
656
B)
If applicable, is subject to the hazardous waste regulations
of 35 Ill. Adm. Code 703, 705, 720 through 726, and
728.
2)
A material containing or otherwise contaminated with used oil
that is burned for energy recovery is subject to regulation as used
oil under this Part.
3)
Used oil drained or removed from materials containing or
otherwise contaminated with used oil is subject to regulation as
used oil under this Part.
d)
Mixtures of used oil with products.
1)
Except as provided in subsection (d)(2) belowof this Section,
mixtures of used oil and fuels or other fuel products are subject
to regulation as used oil under this Part.
2)
Mixtures of used oil and diesel fuel mixed on-site by the
generator of the used oil for use in the generator’s own vehicles
are not subject to this Part once the used oil and diesel fuel have
been mixed. Prior to mixing, the used oil is subject to the
requirements of Subpart C of this Part.
e)
Materials derived from used oil.
1)
Materials that are reclaimed from used oil that are used
beneficially and are not burned for energy recovery or used in a
manner constituting disposal (e.g., re-refined lubricants) are:
A)
Not used oil and thus are not subject to this Part, and
B)
Not solid wastes and are thus not subject to the hazardous
waste regulations of Parts 35 Ill. Adm. Code 703, 720
through 726, and 728 as provided in 35 Ill. Adm. Code
721.103(e)(1).
2)
Materials produced from used oil that are burned for energy
recovery (e.g., used oil fuels) are subject to regulation as used oil
under this Part.
3)
Except as provided in subsection (e)(4) belowof this Section,
materials derived from used oil that are disposed of or used in a
manner constituting disposal are:
657
A)
Not used oil and thus are not subject to this Part, and
B)
Are solid wastes and thus are subject to the hazardous
waste regulations of 35 Ill. Adm. Code 703, 720 through
726, and 728 if the materials are listed or identified as
hazardous waste.
4)
Used oil re-refining distillation bottoms that are used as feedstock
to manufacture asphalt products are not subject to this Part.
f)
Wastewater. Wastewater, the discharge of which is subject to regulation
under either Section 402 or Section 307(b) of the Clean Water Act
(including wastewaters at facilities which have eliminated the discharge
of wastewater), contaminated with de minimis quantities of used oil are
not subject to the requirements of this Part. For purposes of this
subsection, “de minimis” quantities of used oils are defined as small
spills, leaks, or drippings from pumps, machinery, pipes, and other
similar equipment during normal operations or small amounts of oil lost
to the wastewater treatment system during washing or draining
operations. This exception will not apply if the used oil is discarded as a
result of abnormal manufacturing operations resulting in substantial
leaks, spills, or other releases, or to used oil recovered from
wastewaters.
g)
Used oil introduced into crude oil pipelines or a petroleum refining
facility.
1)
Used oil mixed with crude oil or natural gas liquids (e.g., in a
production separator or crude oil stock tank) for insertion into a
crude oil pipeline is exempt from the requirements of this Part.
The used oil is subject to the requirements of this Part prior to
the mixing of used oil with crude oil or natural gas liquids.
2)
Mixtures of used oil and crude oil or natural gas liquids
containing less than 1% used oil that are being stored or
transported to a crude oil pipeline or petroleum refining facility
for insertion into the refining process at a point prior to crude
distillation or catalytic cracking are exempt from the
requirements of this Part.
3)
Used oil that is inserted into the petroleum refining process
before crude distillation or catalytic cracking without prior
mixing with crude oil is exempt from the requirements of this
Part, provided that the used oil contains less than 1% of the crude
oil feed to any petroleum refining facility process unit at any
658
given time. Prior to insertion into the petroleum refining
process, the used oil is subject to the requirements of this Part.
4)
Except as provided in subsection (g)(5) belowof this Section,
used oil that is introduced into a petroleum refining facility
process after crude distillation or catalytic cracking is exempt
from the requirements of this Part only if the used oil meets the
specification of Section 739.111. Prior to insertion into the
petroleum refining facility process, the used oil is subject to the
requirements of this Part.
5)
Used oil that is incidentally captured by a hydrocarbon recovery
system or wastewater treatment system as part of routine process
operations at a petroleum refining facility and inserted into the
petroleum refining facility process is exempt from the
requirements of this Part. This exemption does not extend to
used oil that is intentionally introduced into a hydrocarbon
recovery system (e.g., by pouring collected used oil into the
wastewater treatment system).
6)
Tank bottoms from stock tanks containing exempt mixtures of
used oil and crude oil or natural gas liquids are exempt from the
requirements of this Part.
h)
Used oil on vessels. Used oil produced on vessels from normal
shipboard operations is not subject to this Part until it is transported
ashore.
i)
Used oil containing PCBs. In addition to the requirements of this Part, a
marketer or burner of used oil that markets used oil containing any
quantifiable level of PCBs is subject to the requirements of 40 CFR
761.20(e).
(Source: Amended at 21 Ill. Reg. ________, effective ____________________)
