ILLINOIS POLLUTION CONTROL BOARD
    December 7,
    1995
    IN THE
    MATTER
    OF:
    )
    )
    PETITION OF THE METROPOLITAN WATER
    )
    R95-14
    RECLAMATION DISTRICT OF GREATER
    )
    (Site-Specific
    CHICAGO FOR SITE-SPECIFIC WATER
    )
    Rulemaking
    -
    Water)
    QUALITY REGULATION FOR CYANIDE
    )
    (Amendments to 35 Ill.
    Adm. Code
    )
    303 and 304)
    )
    Proposed Rule.
    Second Notice.
    OPINION
    AND
    ORDER OF THE BOARD
    (by R.C.
    Fleinal):
    This matter comes before the Board upon a proposal to amend
    the Board’s water quality regulations for cyanide filed by the
    Metropolitan Water Reclamation District of Greater Chicago
    (District).
    The District requests that the existing General Use
    chronic standard (CS) for weak acid dissociable
    (WAD)
    cyanide be
    changed from 5.2 ~g/L to 10 ~ig/Las applied to the West Branch of
    the DuPage River, Higgins Creek,
    Salt Creek, and the Des Plaines
    River within Cook County.
    The Board’s responsibility in this matter arises from the
    Environmental Protection Act
    (Act)
    (415 ILCS 5/1 et seq.
    (1994)).
    The Board is charged therein to “determine, define and implement
    the environmental control standards applicable in the State of
    Illinois”
    (415 ILCS 5/5(b)).
    More generally,
    the Board’s
    rulemaking charge is based on the system of checks and balances
    integral to Illinois environmental governance:
    the Board bears
    responsibility for the rulemaking and principal adjudicatory
    functions; the Illinois Environmental Protection Agency (Agency)
    has primary responsibility for administration of the Act and the
    Board’s regulations, including today’s proposed regulation.
    By today’s action the Board adopts the proposed amendments
    with modifications for the purpose of second notice, pursuant to
    the Illinois Administrative Procedure Act (5 ILCS 100/1—1 et
    seq.
    (1994)).
    This matter will now be filed with the Joint Committee
    on Administrative Rules
    (JCAR)
    for consideration by that body.
    PROCEDURAL HISTORY
    The District filed its proposal on April 28,
    1995.
    By order
    of May 4,
    1995 the Board accepted the proposal for hearing.

    —2—
    A public hearing was held before hearing officer Audrey
    Lozuk—Lawless in Chicago on June 30,
    1995.
    The District
    presented the testimony of Dr. Cecil Lue-Hing, Director of
    Research and Development at the District;
    Dr. Richard G. Luthy,
    Professor and Head of the Department of Civil and Environmental
    Engineering at Carnegie Mellon University; and Dr. Herbert Allen,
    Professor of Environmental Engineering at the University of
    Delaware.
    Dr. Lue—Hing presented an overview of the District’s
    petition, including discussion of the existing WAD cyanide
    standard and studies the District has undertaken of that
    standard.
    Dr. Lue-Hing additionally addressed the economic
    impact to the District and the water quality of the rivers
    impacted by the proposed new standard.
    Dr. Luthy addressed the methodology for WAD cyanide
    analysis,
    including the precision and accuracy of the WAD cyanide
    test.
    Dr. Allen addressed the methodologies for determining a
    WAD cyanide CS.
    Four public comments
    (PC) were filed prior to first notice:
    Chicago Metal Finishers Institute (PC #1), Illinois Association
    of Wastewater Agencies
    (PC #2), the District (PC #3), and the
    Agency
    (PC #4).
    All comments support adoption of the District’s
    proposal.
    By order of August 24,
    1995 the Board adopted the District’s
    proposal’ for first notice.
    First notice publication occurred at
    19
    Illinois Register
    12583
    (September
    8,
    1995).
    Three public comments have been filed subsequent to first
    notice: PC #5 and #7 by the District and PC #6 by the Agency.
    PC
    #5 consists of a list of the 595 facilities that constitute
    significant industrial users
    (SIU5)
    of the District’s wastewater
    treatment facilities.
    In PC #6 the Agency repeats its support of
    the proposal and makes additional suggestions for improving the
    language of the proposal (see following).
    PC #7 is an analysis
    of the budgetary and economic effects of the proposal.
    BACKGROUND
    The District is a unit of government with jurisdiction
    within part of Cook County,
    Illinois.
    Among the duties of the
    District is operation of water reclamation plants
    (WRPs),
    which,
    ~ The proposal as adopted for first notice contained several
    modifications relative to the proposal as originally filed with
    the Board.
    The basis for making these modifications is discussed
    in the Board’s first notice opinion of August 24 at p. 7—8.

    —3—
    as part of their normal activities, produce discharges to local
    waterways.
    The Board has established water quality standards for the
    streams of the State,
    including streams within the area served by
    the District.
    Among these standards are two standards for
    cyanide2 that apply to the General Use Waterways to which the
    District discharges.
    These are a chronic standard (CS) with a
    value of 5.2 ~g/L and an acute standard
    (AS) of 22 ~g\L.
    The
    parameter to be measured in both cases is WAD cyanide, identified
    by the STORET number 00718.
    At issue in the instant proceedings are three of the
    District’s seven
    WRPs
    and the General Use Water Quality streams
    to which they discharge.
    These are:
    WRP
    Receiving Stream
    ADF*
    Hanover Park
    West Branch DuPage River
    8.87
    John E. Egan
    Salt Creek
    24.5
    James C. Kirie
    Higgins Creek
    31.8
    =
    Average 1994 daily flow in million gallons per day)
    Each of the three receiving streams has a 7—day,
    10—year low
    flow of zero at the point of discharge.
    The three receiving
    streams are tributary to a fourth stream of interest, the Des
    Plaines River.
    In 1993 the Agency issued renewed National Pollutant
    Discharge Elimination System
    (NPDES) permits for the Hanover Park
    and James C. Kirie WRP5.
    In these permits the Agency for the
    first time included numerical effluent limits based on the
    cyanide water quality standards3.
    These effluent limits for the
    two plants are 5.2 and 5.0 ~g/L, respectively, measured as
    monthly average
    WAD
    cyanide, and 22 pg/L measured as daily
    maximum WAD cyanide.
    The NPDES cyanide limits were set equal to the cyanide CS,
    in keeping with the permit-writing practice applicable to streams
    that have 7—day,
    10—year low flows of zero.
    Prior to the 1993 issuance of the NPDES permits at issue,
    the District had not conducted routine analysis of effluent
    2
    These standards are found at 35 Ill. Adm. Code 302.208 (d).
    They were adopted in Board proceeding R88-21(A)
    (In the matter
    of: Amendments to Title 35. Subtitle C
    (Toxics Control)),
    effective February 13,
    1990.
    ~ Upon petition from the District the Agency has set the
    effective date for the cyanide limits to October
    1,
    1996.

    —4—
    cyanide.
    However, analyses conducted subsequently at both the
    Hanover Park and James C.
    Kirie WRP5 have suggested to the
    District that a
    5 ~g\L monthly average4 of
    WAD
    cyanide would
    often be equaled or exceeded.
    In this circumstance the District
    believes that compliance with the monthly averages currently
    expressed in the permits is problematic.
    The District believes
    that the solution lies in examination of the rationale for the
    cyanide General Use CS, and bases the instant petition on that
    examination.
    JUSTIFICATION FOR PROPOSED AMENDMENTS
    The District has identified four factors that it believes
    give technical justification for a CS standard of 10 ~&g/L5.
    These are:
    1.
    The indigenous species used in calculating
    fish toxicities are not applicable to the
    waterways named in the District’s proposal.
    2.
    Use of WAD cyanide for determining water
    quality standards is not directly related to
    toxicity as compared to use of free cyanide.
    3.
    Chlorine interferes with the WAD cyanide
    test.
    4.
    The regulatory limits are at or below the
    limit of detection.
    The Board will address each of these in turn.
    Use of Indigenous Species
    Determination of AS and CS water qualit1 standards is
    accomplished by a well-established procedure that involves
    ~ The District believes that it would have no difficulty
    complying with the 22 j~g/Ldaily limits.
    ~ This value is expressed in the record both as
    10 ~~g/Land
    10.0 j~g/L. The Agency recommends
    (PC #4 at ¶6), and the Board
    agrees, that in view of concerns regarding precision of WAD
    cyanide analyses,
    10
    Jhg/L is the preferred form.
    6
    The procedures are given in Guidelines for Deriving
    Numerical National Water Ouality Criteria for the Protection of
    Aquatic Organisms and Their Uses, NTIS PB85—227049.
    Similar
    procedures are present in the Board’s regulations at 35 Ill.
    Adin.
    Code 302.Subpart F: Procedures for Determining Water Quality

    —5—
    consideration of the toxicity of the substance in question to a
    range of aquatic organisms.
    In fresh—water environments such as
    under concern here,
    the procedures and cyanide data base are such
    that the four fish species most sensitive to cyanide determine
    the calculated standards7.
    The current CS cyanide standard of 5.2 ~g/L was established
    based upon a calculation that included toxicities to rainbow
    trout, brook trout, yellow perch,
    and bluegill as the four
    species in question.
    However, the District observes that rainbow
    trout, which is the most sensitive of the four species to
    cyanide, are not indigenous to the District’s waterways.
    The District notes that rainbow trout have never been
    observed in any of the extensive fish collections made by the
    District.
    (Proposal at p.
    45-51:
    Tr. at 25.)
    Moveover, the
    District observes that rainbow trout, which are a coldwater fish
    species, are intolerant of the warmwater environments at issue
    here.
    (Proposal at p.
    50-54.)
    If rainbow trout are not included in the cyanide CS
    calculation, the four most sensitive species become the four
    fishes: brook trout8, yellow perch, bluegill, and black crappie.
    When these four species are used, the calculated CS value for
    cyanide becomes 9.799 ~g/L.
    (Tr. at 41-42; Exh.
    2 at 6.)
    The
    District recommends that this value, rounded to 10 ~g/L, be the
    CS applicable in the District’s waterways.
    The Agency agrees that rainbow trout are not a species
    indigenous to the District’s waterways.
    (Tr. at 62-63.)
    The
    Agency further observes that excluding rainbow trout from the CS
    calculation for the streams at issue is consistent with federal
    guidance and that the resultant cyanide CS of 10 ,~tg/Lis
    protective of existing and expected aquatic life.
    (PC #4 at ¶2.)
    Criteria.
    ~ Application of the procedures, including selection of data
    and calculations using the data to produce the CS values
    discussed herein,
    is detailed in the testimony of Dr. Allen at
    Pr.
    35-42 and Exh.
    2.
    The Agency has independently undertaken
    the analysis, and confirms the results obtained by Dr. Allen.
    (Tr. at 54.)
    8
    At hearing it was noted that brook trout do not occur in the
    waterways at issue, and that yellow perch are rare (Tr. at 51-54).
    Nevertheless, no suggestion has been made that these species also
    be excluded from the CS calculation; if brook trout are excluded,
    the calculated CS would be 10.9 /Lg/L
    (Tr. at 54).

    —6—
    WAD Cyanide Toxicity
    Cyanide occurs in natural aquatic environments in a number
    of forms.
    Among these are HCN, CN, and complexes of cyanide
    with metals
    (e.g.,
    ferrocyanide).
    The
    WAD
    cyanide measurement
    procedure measures all three of these forms.
    However,
    it is
    generally recognized that only the first two forms, HCN and CN
    (collectively called free cyanide),
    significantly contribute to
    the toxicity of cyanide.
    (Tr. at 44,)
    Thus, analyses of WAD
    cyanide overestimates the toxicity of the cyanide in direct
    proportion to the amount of inetallocyanide complexes present in
    any sample.
    This problem would be eliminated if free cyanide could be
    measured directly.
    However, there currently is no approved
    method for analysis of free cyanide in natural samples.
    (Tr. at
    29,
    45;
    Exh.
    3 at 2.)
    Thus,
    analysis of WAD cyanide must be used
    in default.
    The District observes that for these reasons, WAD cyanide is
    a conservative measure of cyanide toxicity.
    (Tr. at 29.)
    Nevertheless, at the low levels of metals and cyanide in the
    District’s effluent, there should be little difference between
    the expected free cyanide concentrations and measured WAD cyanide
    concentrations.
    (Tr. at 59.)
    Chlorine Interference
    The District has completed 16½ months of detailed WAD
    cyanide sampling and analysis in effluents from the Hanover Park
    and James C. Kirie WRP5.
    In both data sets the District observes
    that measured
    WAD
    cyanide concentrations were higher during the
    months of May through October than in November through April9.
    The only consistent difference in inflow or operational
    parameters between these two time periods is that during May
    through October both WRPs employ chlorination/dechlorination
    procedures.
    The District observes that during the summer of 1994, when
    the correlation between chlorination/dechlorination was becoming
    evident,
    it undertook a study of the fate of WAD cyanide
    concentrations during the treatment process, including sampling
    ~At the Hanover Park WRP, the WAD cyanide concentrations on
    the final effluent were 1.0 to 2.0 ~g/L during November through
    April, versus 4.0 to 6.0 ~Lg/Lduring Nay through October.
    (Exh.
    1 at Table 1.)
    At the James C. Kirie WRP
    WAD
    cyanide
    concentrations were 1.0 to 2.0 pg/L during November through
    April, versus 3.0 to 4.0 ~g/L during May through October.
    (Exh.
    1 at Table 2.)

    —7—
    prior to and after chlorination.
    (Tr. at 31-32;
    Exh.
    1 at 11.)
    The results verified that chlorination causes an increase in the
    reported WAD cyanide concentrations
    (a.),
    although it remains
    uncertain whether the increase is caused by an analytical
    interference or by a chemical reaction that produces new cyanide
    (Pr. at 55—57).
    Detection Limit
    The District observes that Standard Methods for the
    Examination of Water and Wastewater,
    18th edition,
    lists the
    limit of detection for WAD cyanide as 5 to 20
    ,~Lg/L, depending
    upon the sample matrix.
    (Proposal at 57.)
    The District
    observes, accordingly, that a standard at 5.2 ~tg/Llies at the
    threshold of and “perhaps beyond the limits of existing
    laboratory analytical methodology”
    (u.).
    In addition, Dr. Luthy, who chairs the task group that
    prepared the section on cyanide for the current edition of
    Standard Methods, notes that the single operator precision for
    the determination of WAD cyanide is about
    8 ~g/L for samples in
    the range 5-10
    Jhg/L.
    (Pr. at 47;
    Exh.
    3 at 3.)
    He concludes
    that considerable variation should be expected in such low—level
    samples, and that “it would be improper to ascribe great
    significance to sample analyses in this range”
    (Id.).
    ECONOMICS
    The District has calculated the cost of replacing the
    chlorination/dechlorination system at the Hanover Park and James
    C. Kirie WRPs.
    (Proposal at 24, Attachment 7.)
    The District
    calculated estimates of replacing the existing system with
    ultraviolet radiation
    (UV) and ozone disinfection.
    The
    calculations indicate that ozonation would be the least costly
    replacement alternative.
    The District’s total cost to replace
    the current chlorination/dechlorination system with an ozonation
    system would be $5,699,728 in construction costs, with an annual
    operating cost of $164,200.
    (~~)
    The total annualized capital
    plus operating cost for both
    WRPs
    would be $830,097.
    (~~)
    These expenses do not include any costs for replacing the
    existing chlorination/dechlorination system at the John E. Egan
    WRP.
    The District notes that even with this expenditure, there is
    no guarantee that an ozonation system would not produce increases
    in
    WAD
    cyanide as observed during chlorination/dechlorination.

    —8—
    AGENCY’S RECOMMENDED TEXTURAL MODIFICATIONS
    At ¶s
    9 and 10 of PC #6 the Agency comments on two possible
    modifications to the regulatory text as proposed for first
    notice.
    Neither of these modifications would change the relief
    requested.
    The District has not responded to the Agency’s
    observations.
    The principal modification is with respect to the District’s
    request to add a new subsection at 35 Ill. Adm. Code 304.201(d).
    That subsection would establish an effluent standard of
    10 ~g/L
    (as a monthly average concentration subject to the averaging
    provisions of Section 304.104(a))
    explicitly for the Egan,
    Hanover Park,
    and Kirie WRPs’°.
    As the Agency observes, the proposed subsection
    (d)
    is
    unnecessary for the purposes of establishing an NPDES permit
    limit for cyanide for the three WRPs,
    inasmuch as standard
    permit—writing procedures already serve this purpose.
    If fact,
    the Hanover Park and Kirie
    WRPs
    already have in their NPDES
    permits a cyanide limit of
    22 ~g/L, expressed as a daily maximum
    concentration (see above).
    The value of 22 ~g/L, according to
    standard procedures,
    is equal to the 22 ~g/L acute water quality
    standard for cyanide.
    If, however, the language of subsection
    (d) were to be
    adopted as proposed, the standard NPDES permit-writing procedures
    would could cause the daily maximum permit limit for cyanide to
    be 20 ,~g/L(twice the monthly average of 10 ~g/L).
    This limit is
    more stringent than currently exists by 2 ~g/L.
    The Agency
    concludes that it “would have no objection if the proposed
    addition of 35 Ill. Adm. Code 304.201(d) was withdrawn”
    (PC #6 at
    ¶10).
    The Board believes that 35 Ill. Adm. Code 304.201(d) as
    proposed for first notice is unnecessary, and accordingly today
    deletes it from further consideration.
    10
    The full text,
    as proposed for first notice,
    was:
    ~
    John
    E.
    Egan,
    Hanover Park.
    and James
    C.
    Kirie Water
    Reclamation Plants
    The discharges of the John
    E.
    Egan,
    Hanover Park,
    and
    James C. Kirie Water Reclamation Plants must meet a weak
    acid dissociable cyanide (STORET 00718) effluent standard
    of
    10
    ug/L,
    sub-ject to the averaging rule of Section
    304.104(a)

    —9—
    The Agency’s second consideration for modification concerns
    35 Ill. Adm. Code 304.201(c).
    At first notice the subsection was
    proposed to be modified only to the extent of changing the name
    of the District from Metropolitan Sanitary District to
    Metropolitan Water Reclamation District.
    Now, however, the
    Agency observes that the substance of the subsection is a
    requirement that the District submit a water quality report at a
    date past.
    On this basis the Agency believes the subsection is
    “obsolete” and therefore that it can be deleted rather than
    simply amended.
    The Board accepts the Agency recommendation that subsection
    304.201(C) be deleted,
    and accordingly today adopts that change.
    STATE-WIDE APPLICABILITY
    In the first notice opinion and order in this matter the
    Board observed that the Agency at hearing had postulated that the
    cyanide CS standard might be better amended to 10 ~~g/Las a
    state-wide rule than as a site-specific rule.
    (Tr. at 62—63.)
    It was also observed that the justification presented by the
    District might apply not only to the waters to which the District
    discharges, but to all General Use waters within the State
    excluding Lake Michigan, and that accordingly it might be most
    administratively economical to amend the cyanide standard
    generally, rather than in piecemeal site—specific fashion.
    Prior to first notice the Agency indicated that it was
    pursuing these thoughts by engaging in discussions with
    interested persons regarding a state-wide proposal,
    “after which
    a proposal may be filed”
    (PC #4 at ¶9).
    More recently, the
    Agency “repeats its intent to develop and propose a general
    rulemaking”
    (PC #6 at ¶6), but nevertheless urges that the Board
    “not delay in reaching a decision on the merits of the site
    specific proposal of the District” (J~.at ¶7).
    CONCLUSION
    The Board believes that the District has presented evidence
    warranting the adoption of the proposed amendments, modified as
    discussed herein,
    for the purpose of second notice.
    ORDER
    The Board hereby directs that second notice of the following
    proposed amendments be submitted to the Joint Committee on
    Administrative Rules.

    —10-•
    TITLE 35:
    ENVIRONMENTAL PROTECTION
    SUBTITLE C:
    WATER POLLUTION
    CHAPTER I:
    POLLUTION CONTROL BOARD
    PART 303
    WATER USE DESIGNATIONS
    AND
    SITE SPECIFIC
    WATER QUALITY STANDARDS
    SUBPART A:
    GENERAL PROVISIONS
    Section
    303.100
    303.101
    303.102
    Section
    303.200
    303.201
    303.202
    303.203
    303.204
    Scope and Applicability
    Multiple Designations
    Rulemaking Required
    SUBPART B:
    NONSPECIFIC WATER USE DESIGNATIONS
    Scope and Applicability
    General Use Waters
    Public and Food Processing Water Supplies
    Underground Waters
    Secondary Contact and Indigenous Aquatic Life Waters
    SUBPART C:
    SPECIFIC USE DESIGNATIONS
    AND
    SITE SPECIFIC
    WATER QUALITY STANDARDS
    Section
    303
    300
    303.301
    303
    311
    303
    312
    303.321
    303
    322
    303
    323
    303
    331
    303.341
    303.351
    303.352
    303
    353
    303.361
    303.400
    303.430
    303.431
    303.441
    303.442
    303.443
    303 .444
    Scope and Applicability
    Organization
    Ohio River Temperature
    Waters Receiving Fluorspar Mine Drainage
    Wabash River Temperature
    Unnamed Tributary of the Vermilion River
    Sugar Creek and Its Unnamed Tributary
    Mississippi River North Temperature
    Mississippi River North Central Temperature
    Mississippi River South Central Temperature
    Unnamed Tributary of Wood River Creek
    Schoenberger Creek; Unnamed Tributary of Cahokia Canal
    Mississippi River South Temperature
    Bankline Disposal Along the Illinois Waterway Rivers
    Unnamed Tributary to Dutch Creek
    Long Point Slough and Its Unnamed Tributary
    Secondary Contact Waters
    Waters Not Designated for Public Water Supply
    Lake Michigan
    Salt Creek, Higgins Creek, West Branch of the DuPage
    River. Des Plaines River

    —11—
    SUBPART D:
    THERMAL DISCHARGES
    Section
    303.500
    Scope and Applicability
    303.502
    Lake Sangchris Thermal Discharges
    303.Appendix A References to Previous Rules
    303.Appendix B Sources of Codified Sections
    AUTHORITY:
    Implementing Section 13 and authorized by Section 27
    of the Environmental Protection Act (415 ILCS 5/13 and 27).
    SOURCE:
    Filed with the Secretary of State January
    1,
    1978;
    amended at
    2
    Ill. Reg.
    27,
    p.
    221, effective July 5,
    1978;
    amended at
    3 Ill.
    Reg.
    20,
    p.
    95, effective May 17,
    1979; amended
    at 5 Ill. Reg.
    11592, effective October 19,
    1981; codified at 6
    Ill. Reg.
    7818; amended at 6 Ill. Reg.
    11161, effective September
    7,
    1982; amended at 7 Ill. Reg.
    8111, effective June 23,
    1983;
    amended in R87—27 at 12 Ill. Reg.
    9917, effective May 27,
    1988;
    amended in R87—2 at 13 Ill. Reg. 15649, effective September 22,
    1989; amended in R87-36 at 14 Ill. Reg.
    9460, effective May 31,
    1990;
    amended in R86-14 at 14 Ill. Reg. 20724, effective December
    18,
    1990;
    amended in R89—14(C) at 16 Ill. Reg.
    14684, effective
    September 10,
    1992; amended in R92—17 at 18 Ill.
    Reg. at 2981
    effective February 14,
    1994; amended in R91—23 at 18
    Ill. Reg.
    13457, effective August
    19,
    1994; amended in R93—13 at 19 Ill.
    Reg. 1310 effective January 30,
    1995; amended in R95-14 at 19
    Ill. Reg.
    ______________
    effective
    _______________
    SUBPART C: SPECIFIC USE DESIGNATIONS
    AND
    SITE SPECIFIC WATER
    QUALITY
    STANDARDS
    Section
    303.444
    Salt
    Creek,
    Higgins
    Creek,
    West
    Branch
    of
    the
    DuPage River, Des Plaines River
    The General Use chronic water quality standard for cyanide
    (STORET number 00718) contained in Section 302.208 does not apply
    to Salt Creek, Higgins Creek, the West Branch of the DuPage
    River.
    and the Des Plaines River in Cook County,
    Illinois.
    Instead, for these waters the chronic cyanide standard is
    10
    ug/L.
    (Source:
    Amended at 19 Ill. Reg.
    _________,
    effective
    ______________________________________________________________________________________________ )
    TITLE 35:
    ENVIRONMENTAL
    PROTECTION
    SUBTITLE C:
    WATER POLLUTION
    CHAPTER I:
    POLLUTION CONTROL BOARD

    —12—
    PART 304
    EFFLUENT
    STANDARDS
    SUBPART
    A:
    GENERAL
    EFFLUENT
    STANDARDS
    Section
    304.101
    304.102
    304
    103
    304.104
    304.105
    304.106
    304
    120
    304.121
    304.122
    304.123
    304.124
    304.125
    304.126
    304.140
    304.141
    304.142
    Section
    304.201
    304
    202
    304.203
    304.204
    304.205
    304.206
    304.207
    304.208
    304.209
    304.210
    304.211
    304.212
    304.213
    304.214
    304.215
    304.216
    304.218
    304
    219
    Preamble
    Dilution
    Background Concentrations
    Averaging
    Violation of Water Quality Standards
    Offensive Discharges
    Deoxygenating Wastes
    Bacteria
    Nitrogen
    (STORET number 00610)
    Phosphorus
    (STORET number 00665)
    Additional Contaminants
    pH
    Mercury
    Delays in Upgrading (Repealed)
    NPDES Effluent Standards
    New Source Performance Standards
    (Repealed)
    SUBPART B:
    SITE
    SPECIFIC
    RULES
    AND
    EXCEPTIONS NOT OF
    GENERAL
    APPLICABILITY
    Wastewater Treatment Plant Discharges of the
    Metropolitan Sanitary Water Reclamation District of
    Greater Chicago
    Chior-alkali Mercury Discharges in St. Clair County
    Copper Discharges by Olin Corporation
    Schoenberger Creek:
    Groundwater Discharges
    John Deere Foundry Discharges
    Alton Water Company Treatment Plant Discharges
    Galesburg Sanitary District Deoxygenating Wastes
    Discharges
    City of Lockport Treatment Plant Discharges
    Wood River Station Total Suspended Solids Discharges
    Alton Wastewater Treatment Plant Discharges
    Discharges From Borden Chemicals and Plastics Operating
    Limited Partnership Into an Unnamed Tributary of Long
    Point Slough
    Sanitary District of Decatur Discharges
    UNO-VEN Refinery Ammonia Discharge
    Mobil Oil Refinery Ammonia Discharge
    City of Tuscola Wastewater Treatment Facility
    Discharges
    Newton Station Suspended Solids Discharges
    City of Pana Phosphorus Discharge
    North Shore Sanitary District Phosphorus Discharges

    —13—
    304.220
    East St. Louis Treatment Facility,
    Illinois-American
    Water Company
    304.221
    Ringwood Drive Manufacturing Facility in McHenry County
    304.222
    Intermittent Discharge of TRC
    SUBPART C:
    TEMPORARY EFFLUENT STANDARDS
    Section
    304.301
    Exception for Ammonia Nitrogen Water Quality Violations
    304.302
    City of Joliet East Side Wastewater Treatment Plant
    304.303
    Amerock Corporation, Rockford Facility
    Appendix A
    References to Previous Rules
    AUTHORITY:
    Implementing Section 13 and authorized by Section 27
    of the Environmental Protection Act (415 ILCS 5/13 and 27).
    SOURCE:
    Filed with the Secretary of State January
    1,
    1978;
    amended at 2 Ill. Reg.
    30,
    p.
    343, effective July 27,
    1978;
    amended at 2 Ill. Reg.
    44,
    p.
    151, effective November 2,
    1978;
    amended at 3 Ill. Reg.
    20,
    p.
    95, effective May 17,
    1979; amended
    at
    3 Ill. Reg.
    25,
    p.
    190, effective June 21,
    1979;
    amended at 4
    Ill. Reg.
    20,
    p.
    53 effective May 7,
    1980; amended at 6 Ill. Req.
    563, effective December 24,
    1981; codified at
    6 Ill. Reg.
    7818:
    amended at 6 Ill. Reg.
    11161,
    effective September 7,
    1982;
    amended at 6 Ill. Reg.
    13750,
    effective October 26,
    1982; amended
    at 7 Ill. Req.
    3020, effective March 4,
    1983; amended at 7 Ill.
    Reg. 8111,
    effective June 23,
    1983; amended at 7 Ill. Reg.
    14515,
    effective October 14,
    1983; amended at 7 Ill. Reg.
    14910,
    effective November 14,
    1983; amended at 7 Ill. Req. 14910,
    effective November 14,
    1983; amended at 8 Ill. Reg.
    1600,
    effective January 18,
    1984;
    amended at
    8 Ill. Reg.
    3687,
    effective March 14,
    1984; amended at 8 Ill. Reg.
    8237, effective
    June 8,
    1984; amended at 9 Ill. Reg.
    1379, effective January 21,
    1985; amended at
    9 Ill.
    Reg.
    4510, effective March 22,
    1985;
    peremptory amendment at 10 Ill. Reg.
    456, effective December 23,
    1985; amended at 11 Ill. Reg.
    3117, effective January 28,
    1987;
    amended in R84—l3 at 11 Ill. Reg. 7291 effective April
    3,
    1987;
    amended in R86—17(A) at 11 Ill. Req. 14748, effective August 24,
    1987; amended in R84—16 at 12
    Ill.
    Reg.
    2445, effective January
    15,
    1988; amended in R83—23 at 12
    Ill.
    Req.
    8658, effective May
    10,
    1988; amended in R87—27 at 12
    Ill.
    Req.
    9905, effective May
    27,
    1988; amended in R82—7
    at 12
    Ill. Req.
    10712, effective June
    9,
    1988;
    amended in R85—29 at 12
    Ill. Reg.
    12064, effective July
    12,
    1988; amended in R87—22 at 12 Ill. Reg.
    13966, effective
    August
    23,
    1988; amended in R86—3 at 12 Ill. Reg.
    20126,
    effective November 16,
    1988;
    amended in R84—20 at 13 Ill. Reg.
    851, effective January 9,
    1989;
    amended in R85—11 at
    13 Ill. Req.
    2060, effective February 6,
    1989; amended in R88—1 at 13 Ill.
    Req. 5976, effective April 18,
    1989; amended in R86—17B at 13
    Ill. Reg.
    7754, effective May 4,
    1989; amended in R88—22 at 13
    Ill. Req. 8880, effective May 26,
    1989; amended in R87-6 at 14

    —14—
    Ill.
    Reg.
    6777,
    effective
    April
    24,
    1990; amended in R87—36 at 14
    Ill.
    Reg.
    9437,
    effective
    May
    31,
    1990;
    amended
    in
    R88-21(B)
    at
    14 Ill. Reg.
    12538, effective July 18,
    1990; amended in R84—44 at
    14 Ill. Reg.
    20719, effective December 11,
    1990; amended in R86—
    14 at 15 Ill.
    Req. 241,
    effective December 18,
    1990; amended in
    R87—33 at 18 Ill. Req.
    11574, effective July 7,
    1994; amended in
    R94—1 at 19 Ill.
    Reg.
    _______,
    effective ________________________
    ____________________________;
    amended
    in
    R95—14
    at
    19
    Ill.
    Req.
    _______________,.
    effective
    ______________
    BOARD
    NOTE:
    This
    Part
    implements
    the
    Illinois
    Environmental
    Protection
    Act
    as
    of
    July
    1,
    1994.
    SUBPART
    B:
    SITE
    SPECIFIC
    RULES
    AND
    EXCEPTIONS
    NOT
    OF
    GENERAL
    APPLICABILITY
    Section 304.201
    Wastewater Treatment Plant Discharges of The
    Metropolitan
    Canitary
    Water
    Reclamation
    District of Greater Chicago
    a)
    Calumet Treatment Plant Cyanide Discharges:
    The effluent standards of Section 304.124 as applied to
    cyanide discharges,
    Sections 304.120(b) and
    (c) and Section
    304.122
    do
    not
    apply
    to
    BOD5,
    total
    suspended
    solids,
    cyanide, and ammonia—nitrogen discharged from the Calumet
    Sewage Treatment Works of The Metropolitan Sanitary Water
    Reclamation District of Greater Chicago.
    Instead,
    it must
    meet the following effluent standard, subject to the
    averaging
    rule
    of
    Section
    304.104(a),
    effective
    July
    1,
    1988:
    STORET
    CONCENTRATION
    CONSTITUENT
    NUMBER
    (mpll)
    CBOD5
    80082
    24
    SS
    00530
    28
    Ammonia
    Nitrogen
    00610
    13
    (as N)
    Cyanide
    00720
    0.15
    b)
    North Side Sewage Treatment Works
    The effluent standards of Sections 304.120(b)
    and
    (c) and
    304.122 do not apply to BOD5, total suspended solids, and
    ammonia—nitrogen discharged from the North Side Sewage
    Treatment Works of The Metropolitan Sanitary Water
    Reclamation District of Greater Chicago.
    Instead, it must

    —15—
    meet the following standard, subject to the averaging rule
    of Section
    304.104(a)
    effective July 1,
    1988:
    STORET
    CONCENTRATION
    CONSTITUENT
    NUMBER
    (mg/l)
    CBOD5
    80082
    12
    SS
    00530
    20
    Ammonia Nitrogen
    (as N)
    April—October
    00610
    2.5
    November-March
    00610
    4.0
    waccr~J3y~vuiu~Lion
    ‘rho Metropolitan Canitary District of Creator Chicago ohall
    complete and oubmit to the Board a comprehenclivo water
    quality-evaluation of the Chicago Watcrway CyQtom and
    itL3
    influence on thc lower De3 Plainea and Uppcr Illinois Rivcrs
    by January 15, 1~2.
    Such evaluation ohall include
    asoccamcnt
    of pcrformancc lcvcls for North Side,
    Calumet and
    Ctickncy waotcwatcr reclamation plants and the extent of
    sewer ovcrflow reduction through The Metropolitan Sanitary
    District of Crcater Chicago’s -Tunnel and Reservoir Plan.
    (Source:
    Amended at 19 Ill. Req.
    __________,
    effective
    __________
    )
    IT IS SO ORDERED.
    I, Dorothy M. Gunn, Clerk of the Illinois Pollution Control
    Board,
    hereby
    certify
    that
    the above opinion and order was
    adoptçd
    on
    the
    7~
    day
    of-e-,-~~&~
    ,
    1995,
    by a vote
    of
    (~
    -0.
    ~.
    Dorothy
    M. ~4inn, Clerk
    Illinois P~lutionControl Board

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